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HomeMy WebLinkAboutFA-1065_20262_CA_MRP_20230323 ENVIRONMENTAL | CIVIL | GEOTECHNICAL MONITORING REPORT LUMBERTON MOBILE 5105 N. FAYETTEVILLE ROAD LUMBERTON, ROBESON COUNTY, NC NCDEQ INCIDENT NO. 20262 RISK CLASSIFICATION: TBD MARCH 23, 2023 NCDEQ CONTRACT NO. N122019D TASK AUTHORIZATION NO. 04 CATLIN PROJECT NO. 220237 PREPARED FOR: MR. SCOTT RYALS NCDEQ, DWM, UST SECTION 1646 MAIL SERVICE CENTER RALEIGH, NC 27699-1646 PREPARED BY: CATLIN ENGINEERS AND SCIENTISTS 220 OLD DAIRY ROAD WILMINGTON, NC 28405 (910) 452-5861 CORPORATE LICENSURE NO. FOR ENGINEERING SERVICES C-0585 CORPORATE LICENSURE NO. FOR GEOLOGY SERVICES C-118 NCDEQ; 20262_Lumberton Mobile CATLIN Engineers and Scientists CATLIN Project No. 220237 March 2023 TABLE OF CONTENTS PAGE 1.0 SITE INFORMATION 1 2.0 EXECUTIVE SUMMARY 2 3.0 SCOPE OF SERVICES 2 4.0 SITE HISTORY AND CHARACTERIZATION 3 4.1 UST OWNER AND OPERATOR INFORMATION 3 4.2 UST INFORMATION 3 4.3 CONTAMINANT SOURCE INVENTORY 4 4.4 SITE CHARACTERISTICS 4 4.5 OWNERS AND OCCUPANTS OF ADJOINING/NEARBY PROPERTIES AND LAND USE 4 4.6 RECEPTOR INFORMATION 5 4.7 PREVIOUS INVESTIGATIONS AND REMEDIAL ACTIVITIES 5 5.0 REGIONAL AND SITE GEOLOGY AND HYDROGEOLOGY 6 5.1 SOIL AND BEDROCK 6 5.2 HYDROGEOLOGY 7 6.0 SITE ACTIVITIES 7 6.1 LNAPL RECOVERY 7 6.2 GAUGING DATA 8 6.3 SAMPLING DATA 8 6.4 SUMMARY OF GROUNDWATER INFORMATION 9 6.5 EVALUATION OF ASSESSMENT INFORMATION 10 7.0 CONCLUSIONS AND RECOMMENDATIONS 10 8.0 LIMITATIONS 11 9.0 STATEMENTS AND CERTIFICATION 12 10.0 REFERENCES 12 NCDEQ; 20262_Lumberton Mobile CATLIN Engineers and Scientists CATLIN Project No. 220237 March 2023 TABLES TABLE 1 SITE HISTORY – UST AND OTHER RELEASE INFORMATION TABLE 2 PUBLIC AND PRIVATE WATER SUPPLY WELLS AND OTHER RECEPTOR INFORMATION TABLE 3 WELL CONSTRUCTION AND HISTORICAL WATER LEVEL GAUGING DATA TABLE 4 LNAPL RECOVERY INFORMATION TABLE 5 SUMMARY OF CURRENT GROUNDWATER LABORATORY RESULTS – STANDARD METHOD 6200B TABLE 6 SUMMARY OF HISTORICAL GROUNDWATER LABORATORY RESULTS – STANDARD METHOD 6200B FIGURES FIGURE 1 SITE VICINTY MAP FIGURE 2 POTENTIAL RECEPTOR MAP FIGURE 3 SITE MAP FIGURE 4 DEPTH TO WATER – FEBRUARY 14, 2023 FIGURE 5 MONITORING WELL GROUNDWATER SAMPLE ANALYTICAL RESULTS – FEBRUARY 14, 2023 APPENDICES APPENDIX A HISTORICAL DATA APPENDIX B SITE PHOTOGRAPHS APPENDIX C JOB HAZARD ANALYSIS AND FIELD DATA SHEETS APPENDIX D LABORATORY ANALYTICAL REPORT AND CHAIN OF CUSTODY DOCUMENT NCDEQ; 20262_Lumberton Mobile CATLIN Engineers and Scientists CATLIN Project No. 220237 1 March 2023 1.0 SITE INFORMATION Site Identification Date: 03/23/2023 Site Risk/Priority Rank: To Be Determined UST Number: FA-1065 Incident Number: 20262 Site Name: Lumberton Mobile Facility ID: 0-018179 Site Location: 5105 N. Fayetteville Road Nearest City/Town: Lumberton County: Robeson Description of Geographical Data Point: Former UST basin Location Method: Google Earth Latitude (decimal degrees): 34.67206° Longitude (decimal degrees): -79.00800° Contacts Information UST Owner: Exxon Company USA (Lakewood Exxon) Address: P.O. Box 4415 Houston, TX 77210-4415 Phone: Unknown UST Operator: Jewel Bissell (deceased) Address: N/A Phone: N/A Property Owner: San Citi Inc. Address: 5105 N. Fayetteville Road, Lumberton, NC 28360 Phone: Unknown Property Occupant: RJ’s Mini Mart Address: 5105 N. Fayetteville Road, Lumberton, NC 28360 Phone: (910) 738-3061 Consultant: CATLIN Engineers and Scientists Address: 220 Old Dairy Rd., Wilmington, NC 28405 Phone: (910) 452-5861 Corporate Licensure No. For Engineering Services: C-0585 Corporate Geology License No.: C-118 Analytical Laboratory: Con-Test Analytical Laboratory State Certification: NC 652, NC-DW 25703 Address: 39 Spruce St., E. Longmeadow, MA 01028 Phone: (413) 525-2332 Release Information Date Discovered: 11/13/1986 Estimated Quantity of Release: 100 gal. Cause of Release: Broken dispenser valve Source of Release: UST system or associated fitting(s) Sizes and contents of UST system(s) from which the release occurred: • Three 6,000-gallon gasoline USTs NCDEQ; 20262_Lumberton Mobile CATLIN Engineers and Scientists CATLIN Project No. 220237 2 March 2023 2.0 EXECUTIVE SUMMARY The Lumberton Mobile site is located at 5105 N. Fayetteville Road, Lumberton, North Carolina. A surface gasoline spill (approximately 100 gallons) reportedly occurred on November 13, 1986 from one or more gasoline underground storage tanks (USTs). Three 6,000-gallon gasoline USTs and one 550-gallon waste oil UST were registered to the facility. The purpose of this report is to document the latest groundwater monitoring event. On February 14, 2023, CATLIN Engineers and Scientists (CATLIN) personnel measured groundwater at approximately 5.25 feet deep across the site. Light non-aqueous phase liquid (LNAPL; aka free-phase product) was measured in monitoring well B-2 (0.09 feet thick). Groundwater samples from three monitoring wells (B-3, MW-01, and MW-02) were collected. The samples were submitted for laboratory analysis of volatile organic compounds (VOCs) per Standard Method (SM) 6200B [plus ethylene dibromide (EDB), methyl tert-butyl ether (MTBE), and diisopropyl ether (DIPE)]. Laboratory results revealed benzene and/or naphthalene in the B-3 and MW-02 samples at concentrations greater than those established in Title 15A of the North Carolina Administrative Code, Subchapter 2L, Section .0202 Groundwater Quality Standards (2L GWQS), but below the Gross Contaminant Levels (GCL). Only MTBE was above the laboratory reporting limit in the sample from MW-01; however, it was below 2L GWQS. Benzene, toluene, ethylbenzene, and total xylenes (BTEX) concentrations appear to have slightly increased in samples from monitoring well B-3 since the previous monitoring event (December 2021). However, they remain low in comparison to those historically reported. CATLIN recommends to: •Consider well rehabilitation efforts at B-2 in an attempt to improve LNAPL recovery. •Construct additional wells for LNAPL delineation and/or recovery. •Continue LNAPL removal activities. •Install new 4-inch locking cap and lock at B-3. 3.0 SCOPE OF SERVICES The scope of services for this report was performed in general accordance with CATLIN proposal number 220237.4P, dated February 3, 2023. Services were authorized by the North Carolina Department of Environmental Quality’s (NCDEQ’s) Task Authorization (TA) #04, accepted on February 5, 2023, and Contract Number N122019D. NCDEQ; 20262_Lumberton Mobile CATLIN Engineers and Scientists CATLIN Project No. 220237 3 March 2023 The approved scope of services for this Task Authorization included to: •Gauge and collect groundwater samples from four monitoring wells (B-2, B-3, MW-01, and MW-02); •Analyze four groundwater samples and one trip blank via SM 6200B(including EDB, MTBE, and DIPE); and, •Prepare and submit a monitoring report documenting the findings. Measurable LNAPL was present in monitoring well B-2 at the time of field activities; therefore, this well was not sampled. The remaining scope of services was conducted in general accordance with the approved TA. 4.0 SITE HISTORY AND CHARACTERIZATION The Lumberton Mobile site is located at 5105 North Fayetteville Road, Lumberton, North Carolina (Figures 1 and 2). Summarized available historical sampling and gauging data from previous consultants are provided in Appendix A. Recent site photographs are presented in Appendix B. 4.1 UST OWNER AND OPERATOR INFORMATION Lakewood Exxon (Exxon Company, USA) formerly owned the property and a retail fueling station on the site. The tanks were operated by Jewel Bissell. Exxon sold the property sometime around 1986. Mrs. Bissell is deceased, and the site was accepted into the North Carolina UST Section Trust Fund Branch State Lead Program in 2020 (NCDEQ, 2020). Available information regarding UST owners/operators is presented on Table 1. 4.2 UST INFORMATION According to a 1986 Pollution Incident Reporting Form, a total of 30,000 gallons of gasoline were stored at the site at the time of the release (NCDENR, 1986). However, only four tanks are registered in the NCDEQ UST Database: three 6,000-gallon gasoline USTs and one 550-gallon waste oil UST. These tanks were installed in 1978 and reportedly were not used between 1996 and 1998 (NCDENR, 1998). The waste oil UST does not appear to be active at this time (and may have been removed), but the gasoline USTs remain in use. Available UST system information is presented in Table 1 and the approximate former UST system locations are illustrated on Figure 3. NCDEQ; 20262_Lumberton Mobile CATLIN Engineers and Scientists CATLIN Project No. 220237 4 March 2023 4.3 CONTAMINANT SOURCE INVENTORY In December 1986, a Pollution Incident Reporting Form was submitted. The form documents a 100-gallon gasoline spill on November 13, 1986. The spill occurred over the concrete parking lot and reportedly originated from a broken dispenser valve. According to the Pollution Incident Reporting Form, the spill was contained and recovered at the time (NCDENR, 1986). It is likely another incident may have occurred at the Lumberton Mobile site or in the site vicinity. LNAPL was not noted during a ground water assessment conducted in 1986 (CATLIN, 1986). However, a significant amount of LNAPL was measured when CATLIN performed a monitoring event in 2020 (CATLIN, 2021). A Notice of Violation (NOV) was issued to the current petroleum retail facility occupying the site (RJ’s Mini Mart) in 2020 for failing a compliance inspection in 2019. The facility failed another inspection in June 2022, but no indication of a release was documented. 4.4 SITE CHARACTERISTICS The site is an active retail petroleum station operating as RJ’s Mini Mart. The site is a concrete paved lot with a small retail building and canopy over the gasoline dispensers. 4.5 OWNERS AND OCCUPANTS OF ADJOINING/NEARBY PROPERTIES AND LAND USE Properties in the site vicinity are mostly commercial businesses and undeveloped forest/marsh lies to the west. The site is located near the intersection of Highway 301 (aka North Fayetteville Road) and I-95. Surrounding properties are commercial businesses (e.g. hotels and restaurants). Two active petroleum retail facilities are located near the site: Kwik Shop (Facility ID No. 0-033478) adjoins the site to the northwest and Happy Mart 4 (Facility ID No. 0-018669) is located to the northeast across Fayetteville Road. Three UST Incidents are associated with the Happy Mart 4 location: Fina Truck Stop (Incident No. 6389), Happy Mart 4 (Incident No. 47676), and Minute Man 24, aka Former Fina Truck Stop (Incident No. 29104). No Further Action (NFA) notices were issued for the Fina Truck Stop and Happy Mart 4 incidents in 1999 and 2021, respectively. However, the Minute Man 24 incident remains open with an Intermediate Risk ranking. NCDEQ; 20262_Lumberton Mobile CATLIN Engineers and Scientists CATLIN Project No. 220237 5 March 2023 4.6 RECEPTOR INFORMATION Receptor information for properties near the site is not readily available. No historical receptor surveys are included on the NCDEQ’s Electronic Document Management System (Laserfiche). A marshy area with several small creeks is located within 500 feet of the site and a pond is located within 1,500 feet. Potential receptors are illustrated on Figure 2 and receptor information is shown on Table 2. 4.7 PREVIOUS INVESTIGATIONS AND REMEDIAL ACTIVITIES After the reported spill, CATLIN (dba Richard Catlin & Associates, Inc.) prepared a Ground Water Assessment Report, dated December 19, 1986, for Exxon. The purpose of the report was to assess if LNAPL existed at the site. Three monitoring wells (B-1, B-2, and B-3) were installed on December 11, 1986. No LNAPL was encountered, and CATLIN recommended Exxon periodically check the monitoring wells as a part of their normal tank inventory reconciliation program (CATLIN, 1986). In 1995, Environmental Hydrogeological Consultants, Inc. (EHC) prepared a Hydrogeological Site Assessment for the Lumberton Mobile site (referred to as Bissel Mobil therein). EHC installed four temporary wells (TMW-1, TMW-2, TMW-3, and TMW-4) in August 1995. Samples taken from three temporary wells (TMW-1, TMW-2, and TMW-3) and three permanent wells (B-1, B-2, and B-3) were submitted for analysis via Environmental Protection Agency (EPA) Method 602 plus MTBE. Analytical results reported concentrations of several petroleum constituents above their method detection limits in wells B-3, TMW-1, TMW-2, and TMW-4. EHC concluded that areas in the northand east of the site represented the “hot spot,” and it was possible thatcontaminants have migrated off-site (EHC, 1995). No investigations or remedial activity are documented between 1995 and 2020. CATLIN began conducting groundwater monitoring in December 2020. A sample was only collected from monitoring well B-3. Monitoring well B-1 was silted in and B-2 contained LNAPL (7.70 feet thick); therefore, these wells could not be sampled. Laboratory analysis of the B-3 sample revealed multiple petroleum constituents at concentrations above 2L GWQS, but below GCL (CATLIN, 2021). Due to the questionable integrity of the preexisting wells, CATLIN installed two new, Type II monitoring wells (MW-01 and MW-02) in 2021. LNAPL persisted in monitoring well B-2 (6.21 feet thick). Approximately 4.36 gallons NCDEQ; 20262_Lumberton Mobile CATLIN Engineers and Scientists CATLIN Project No. 220237 6 March 2023 of LNAPL were recovered from B-2 via hand-bailing and stored in a 55-gallon drum on-site. Three monitoring well samples (B-3, MW-01, and MW-02) were collected in December 2021. Analytical results reported benzene and/or naphthalene above their respective 2L GWQS in the samples from B-3 and MW-02; however, they were below GCL. MTBE was detected in the MW-01 sample, but it was well below the 2L GWQS (CATLIN, 2022A). CATLIN attempted to perform an aggressive fluid vapor recovery (AFVR) event at monitoring well B-2 in May 2022. Due to a low recovery rate, the event ended after two hours. Approximately 105 gallons of impacted groundwater and LNAPL were recovered (CATLIN, 2022B). A summary of available historical analytical data from previous consultants is presented in Appendix A. 5.0 REGIONAL AND SITE GEOLOGY AND HYDROGEOLOGY 5.1 SOIL AND BEDROCK As defined in the Geologic Map of North Carolina, published by the North Carolina Department of Natural Resources and Community Development (1985), the site lies within the Coastal Plain physiographic province. The North Carolina Coastal Plain is approximately 90 to 150 miles wide from the Atlantic Ocean westward to its boundary with the Piedmont province. Two natural subdivisions of the Coastal Plain were described by Stuckey (1965): the Tidewater region and the Inner Coastal Plain. The project area is located within the Inner Coastal region, which is an area of erosional topography (Horton and Zullo, 1991). The Coastal Plain comprises a wedge-shaped sequence of stratified marine and non-marine sedimentary rocks deposited on crystalline basement. The sedimentary sequences range in age from Recent to lower Cretaceous (Narkunas, 1980). According to historic well logs, the site is underlain by approximately 8-11 feet of sandy clay and clay fill materials. Medium-grained quartz sands are encountered below the sandy clay (CATLIN, 1986). The boring log from the installation of monitoring well MW-02 (provided in CATLIN, 2022A) indicated that sand with silt underlays the site to approximately 5.5 feet below land surface (BLS). Clayey sand with fine sand interlayers was noted from 5.5-8 feet BLS. Brown silty sand was present from 8-10.5 feet BLS, and clayey sand was observed at further depths up to 13feet BLS. NCDEQ; 20262_Lumberton Mobile CATLIN Engineers and Scientists CATLIN Project No. 220237 7 March 2023 5.2 HYDROGEOLOGY Groundwater –The Coastal Plain groundwater system consists of aquifers comprised of permeable sands, gravels, and limestones separated by confining units of less permeable sediment. According to Winner, Jr. and Coble (1989), the surficial aquifer consists primarily of fine sands, clays, shells, peat beds, and scattered deposits of coarse-grained material in the form of relic beach ridges and floodplain alluvium. The areal extent of the surficial aquifer in the Coastal Plain is approximately 25,000 square miles with an average thickness of 35 feet. The average estimated hydraulic conductivity is 29 feet per day (Winner, Jr. and Coble, 1989). Based on the 2020 Visual Hydrogeologic Framework – North Carolina Hydrogeological Database, which identified sufficient boreholes near the site to draw a cross-section, the surficial aquifer may extend to approximately 50 feet deep, underlain by the Black Creek or Upper Cape Fear confining unit and associated aquifer. Surface Water – A marshy area is located ~350 feet east of the site. A few small creeks in the marsh are apparent on satellite imagery within 1,500 feet. A pond is located 1,500 feet of the site. 6.0 SITE ACTIVITIES CATLIN conducted field activities on February 14, 2023 in general accordance with the approved TA and pre-prepared Health and Safety Plan (HASP). Upon arrival at the site, potential hazards were evaluated before beginning field work and are documented on an electronic Job Hazard Analysis (JHA) form. The JHA form is included in Appendix C. Photographs from the site visit are included in Appendix B. CATLIN personnel gauged and collected groundwater samples for laboratory analysis of VOCs per SM 6200B from three monitoring wells (B-3, MW-01, and MW-02). As discussed previously, well B-2 could not be sampled due to the presence of LNAPL. Well locations and site features are shown on Figure 3 and well construction details are presented on Table 3. There was not a lock or cap in place at well B-3. 6.1 LNAPL RECOVERY On February 14, 2023, CATLIN conducted free product recovery via hand bailing from one monitoring well (B-2). LNAPL has been measured in B-2 since December 2020. Prior to recovery, LNAPL was measured in B-2 at 0.09 feet thick. NCDEQ; 20262_Lumberton Mobile CATLIN Engineers and Scientists CATLIN Project No. 220237 8 March 2023 CATLIN personnel utilized a new bailer to remove free product from monitoring well B-2. The bailer was then emptied into a 55-gallon onsite drum. Field personnel observed the product as black and “greasy.” Approximately two gallons of total liquid (water and LNAPL) were recovered, of which an estimated 0.5 gallons was LNAPL. A summary of LNAPL recovery information is presented on Table 4. 6.2 GAUGING DATA During the February 2023 event, CATLIN personnel measured depth to water using an electronic oil/water interface probe. To prevent cross contamination, the probe and cabling were decontaminated according to the manufacturer’s recommendations between use in each well. Gauging data were recorded on an electronic groundwater sampling form using a tablet device. Gauging procedures were performed in general accordance with North Carolina Department of Environmental and Natural Resources (NCDENR) and NCDEQ Guidelines, and Environmental Protection Agency (EPA) Region 4 Operating Procedures. Depth to water ranged from 4.11 feet below top of casing (BTOC) (B-3) to 6.02 feet BTOC (MW-01). LNAPL (0.09 feet thick) was measured in monitoring well B-2. This is a significant reduction from the previous event (December 2021) when it was measured at 6.21 feet thick. Groundwater elevations and flow direction could not be calculated for this site due to a lack of top of casing elevations. Monitoring well gauging results for events conducted by CATLIN are presented in Table 3. Depths to water and historical groundwater flow direction are illustrated on Figure 4. Groundwater sampling forms are provided in Appendix C. 6.3 SAMPLING DATA Following gauging, the monitoring wells were sampled in accordance with NCDENR and NCDEQ Guidelines and EPA Region 4 Operating Procedures. Prior to obtaining representative groundwater samples, the well was purged by removing a minimum of three well volumes using a new, disposable bailer. Groundwater field parameter data were measured at one-minute intervals using an In-Situ Aqua TROLL 600 Multiparameter Sonde (Aqua TROLL). Conductivity, pH, oxidation reduction potential (ORP), dissolved oxygen, turbidity, and temperature measurements were recorded utilizing the VuSitu mobile application (version 1.17.12). The Aqua TROLL was decontaminated according to the manufacturer’s recommendations between use at each monitoring well. Groundwater parameter data were transferred from the NCDEQ; 20262_Lumberton Mobile CATLIN Engineers and Scientists CATLIN Project No. 220237 9 March 2023 VuSitu mobile application to the electronic groundwater sampling forms. Copies of the groundwater sampling forms are available in Appendix C. After a minimum of three well volumes were removed (or the well was bailed dry), groundwater samples were collected from the wells and poured into appropriate laboratory-provided, pre-preserved glassware, labeled, and placed on ice in an insulated cooler. A laboratory-provided trip blank accompanied the samples for the duration of the site activities. The groundwater samples and a laboratory-provided trip blank were submitted to Con-Test Analytical Laboratory (Certification NC 652 and NC-DW 25703) in East Longmeadow, Massachusetts, under proper chain of custody (COC) protocol and analyzed per SM 6200B (including EDB, MTBE, and DIPE). The laboratory analytical data and COC are included in Appendix D. 6.4 SUMMARY OF GROUNDWATER INFORMATION During the previous sampling event conducted by CATLIN (December 2021), the samples from monitoring wells B-3 and MW-02 contained VOCs at concentrations above the 2L GWQS. However, none were above GCL. Summarized available historical sampling and gauging data from previous consultants are provided in Appendix A. The latest groundwater sampling laboratory results for SM 6200B analysis are summarized in Table 5. Historical results for events conducted by CATLIN are in Table 6. Monitoring well sample analytical results are illustrated on Figure 5. A copy of the complete laboratory report and COC documentation are in Appendix D. Monitoring Wells During the February 2023 monitoring event, three monitoring well groundwater samples (B-3, MW-01, and MW-02) were collected and submitted for analysis via SM 6200B (including EDB, MTBE, and DIPE). Laboratory analysis revealed a low concentration of MTBE and an estimated (“J”-value) concentration of acetone (a common laboratory relic) in the sample from MW-01; however, both were well below their respective 2L GWQS. No analyte concentrations were detected above GCL in any of the monitoring well samples. Analytical results reported the following constituents at concentrations above their 2L GWQS in samples B-3 and MW-02: •B-3: benzene and naphthalene; and •MW-02: benzene. NCDEQ; 20262_Lumberton Mobile CATLIN Engineers and Scientists CATLIN Project No. 220237 10 March 2023 Trip Blank One laboratory-provided trip blank sample was submitted for analysis per SM 6200B (including EDB, MTBE, and DIPE). A low concentration of chloroform was detected in the trip blank sample, but it was well below the 2L GWQS. No other targeted analytes were detected. 6.5 EVALUATION OF ASSESSMENT INFORMATION Extent of Contamination Benzene and/or naphthalene were detected above their respective 2L GWQS in samples from B-3 and MW-02. However, no constituents were reported above GCL. LNAPL continues to persist in monitoring well B-2, although the thickness has been greatly reduced. A summary of monitoring well groundwater sample analytical results are illustrated on Figure 5. The highest benzene, toluene, ethylbenzene, and total xylenes (BTEX) concentrations have historically been reported in samples from B-3. The BTEX concentrations in samples from B-3 have slightly increased since the previous monitoring event but remain low in comparison to those historically reported (CATLIN, 2022A). Cleanup Levels Achieved Soil – No soil excavations or sampling activities have been previously documented. Groundwater – Groundwater contaminant concentrations are above 2L GWQS, but below GCL at the site. LNAPL – LNAPL was measured (0.09 feet thick) in B-2 during this monitoring period. LNAPL has been measured in B-2 since December 2020. However, the amount has significantly decreased in comparison to previous events. 7.0 CONCLUSIONS AND RECOMMENDATIONS Groundwater monitoring findings for this period are summarized below: •Approximately 0.5 gallons of LNAPL was recovered from monitoring well B-2via hand bailing and is currently stored on-site in a 55-gallon drum. •Groundwater samples were obtained from three monitoring wells (B-3, MW-01, and MW-02) and analyzed via SM 6200B (including EDB, MTBE,and DIPE). •Benzene was detected above its 2L GWQS in samples from B-3 and MW-02,and naphthalene was also above its 2L GWQS in the B-3 sample. NCDEQ; 20262_Lumberton Mobile CATLIN Engineers and Scientists CATLIN Project No. 220237 11 March 2023 •Contaminant concentrations have slightly increased in monitoring well B-3since the previous sampling event (December 2021) but remain low in comparison to those historically reported. •No contaminant concentrations were detected above GCL. •LNAPL thickness has significantly decreased in monitoring well B-2. CATLIN recommends to: •Consider well rehabilitation efforts at B-2 in an attempt to improve LNAPL recovery. •Construct additional wells for LNAPL delineation and/or recovery. •Continue LNAPL removal activities. •Install new 4-inch locking cap and lock at B-3. 8.0 LIMITATIONS The groundwater sample analyzed as part of this investigation only provides an isolated data point and may not represent conditions at every location in the project area. Analyses and conclusions of this report may not be completely representative of all site conditions. Conclusions and recommendations of this investigation and report are based on the best available data in an effort to comply with current regulatory requirements. NCDEQ; 20262_Lumberton Mobile CATLIN Engineers and Scientists CATLIN Project No. 220237 12 March 2023 9.0 STATEMENTS AND CERTIFICATION 1 Enter the date the monitoring report was due. March 17, 2023 Will this report be submitted after the established due date? YES This report was submitted on March 23, 2023. 2 Was any required information from the above template missing from this report? YES No cross sections are provided. Adequate subsurface information is not available. 3 If applicable, will any of the proposed attenuation milestones under the schedule approved in the Corrective Action Plan not be met? NA No CAP has been submitted for this site. 4 Does any known or suspected source zone soil contamination or free product remain outside of the assessed area that could be inhibiting natural attenuation? NO 5 Has there been an unexpected increase in contaminant mass sufficient to suggest a potential new release from a separate onsite or offsite source? NO 6 Certification: I, Benjamin J. Ashba, a Licensed Geologist for CATLIN Engineers and Scientists, do certify that the information contained in this report is correct and accurate to the best of my knowledge. CATLIN Engineers and Scientists is licensed to practice geology in North Carolina. The certification number of the company or corporation is C-118. 10.0 REFERENCES CATLIN Engineers and Scientists, Ground Water Assessment Report, Exxon Company, U.S.A., Station #46427 at HWY. 301 and I-95, Lumberton, N.C., December 19, 1986. CATLIN Engineers and Scientists, Monitoring Report, Lumberton Mobile, 5105 N Fayetteville Road, Lumberton, Robeson County, North Carolina, NCDEQ Incident No. 20262, Risk Classification: TBD, January 25, 2021. CATLIN Engineers and Scientists, Monitoring Report, Lumberton Mobile, 5105 N Fayetteville Road, Lumberton, Robeson County, North Carolina, NCDEQ Incident No. 20262, Risk Classification: TBD, February 4, 2022(A). CATLIN Engineers and Scientists, Field Notes and Test Results, May 11, 2022(B). Environmental Hydrogeological Consultants, Inc., Hydrogeological Site Assessment, Bissel Mobil (closed), Highway 301 & I-95, Lumberton, North Carolina, August 29, 1995. NCDEQ; 20262_Lumberton Mobile CATLIN Engineers and Scientists CATLIN Project No. 220237 13 March 2023 Horton, J. Wright, Jr. and Victor A. Zullo, An Introduction to the Geology of the Carolinas: The Geology of the Carolinas, pp 1-11. Hydrologic, Inc., Analytical Report, Company Name: Hydrologic-Lumberton, Inc., Company Project Number: EHC710D/Bissell Mobile, August 1995. Narkunas, J., Groundwater Evaluation in the Central Coastal Plain of North Carolina, North Carolina Department of Natural Resources and Community Development, 1980, pp 119. NCDENR, Groundwater Section, North Carolina Department of Environment and Natural Resources, Division of Environmental Management, Pollution Incident Reporting Form, December 1, 1986. NCDENR, Tanks Database, Information for Facility: #4-6427 – Lumberton Mobil, Accessed January 20, 1989. NCDEQ, UST Section, North Carolina Department of Environmental Quality, Division of Waste Management, Guidelines for Assessment and Corrective Action for UST Releases, December 1, 2013. NCDEQ, UST Section, North Carolina Department of Environmental, Division of Waste Management, Guidelines for Sampling, UST Section, North Carolina Department of Environment and Natural Resources, December 1, 2013. NCDEQ, UST Section, North Carolina Department of Environmental Quality, Division of Waste Management, Guidelines for Site Checks, Tank Closure, and Initial Response and Abatement for UST Releases, February 1, 2019. NCDEQ, UST Section, North Carolina Department of Environmental Quality, Division of Waste Management, State-Lead Acceptance, Former Lumberton Mobile, 2105 Fayetteville Road, Lumberton, Robeson County, NC, Incident Number 20262, August 18, 2020. North Carolina Department of Natural Resources and Community Development, Geological Map of North Carolina, 1985. North Carolina Department of Natural Resources and Community Development, Pollution Incident Reporting Form, Lakewood Exxon, December 10, 1986. Stuckey, J.L., North Carolina: Its Geology and Mineral Resources: North Carolina Department, Raleigh, North Carolina, 1965, pp 550. U.S. EPA, Region 4, U.S. Environmental Protection Agency, Science and Ecosystem Support Division, Athens Georgia, Operating Procedure – Field Equipment Cleaning and Decontamination at the FEC, Striggow, B., U.S. EPA Report No. SESDPROC- 206-R3, Effective Date December 18, 2015. U.S. EPA, Region 4, U.S. Environmental Protection Agency, Science and Ecosystem Support Division, Athens Georgia, Operating Procedure – Groundwater Level and Well Depth Measurement, Striggow, B., U.S. EPA Report No. SESDPROC-105-R3, Effective Date November 3, 2016. U.S. EPA, Region 4, U.S. Environmental Protection Agency, Science and Ecosystem Support Division, Athens Georgia, Operating Procedure – Groundwater Sampling, Striggow, B., U.S. EPA Report No. SESDPROC-301-R4, Effective Date April 26, 2017. U.S. EPA, Region 4, U.S. Environmental Protection Agency, Science and Ecosystem Support Division, Athens Georgia, Operating Procedure – In Situ Water Quality Monitoring, Chief, Field Services Branch, U.S. EPA Report No. SESDPROC-111-R4, Effective Date March 14, 2018. Winner, M.D, Jr., and Coble, R.W., Hydrogeologic Framework of the North Carolina Coastal Plain Aquifer System: U.S. Geological Survey Open File Report 87-690, 1989, pp 155. NCDEQ; 20262_Lumberton Mobile CATLIN Engineers and Scientists CATLIN Project No. 220237 March 2023 TABLES Page 1 of 1 TABLE 1 SITE HISTORY — UST AND OTHER RELEASE INFORMATION Incident Name and No.: Lumberton Mobile - 20262 UST ID Number Name of Owner/ Operator Last Contents Previous Contents Capacity (gal) Construction Details Tank Diameter (inches) Installation Date (mm/dd/yy) Date Removed 1 Gasoline (Regular)Gasoline 6,000 Single Wall FRP 89.5 04/05/78 Active 2 Gasoline (Regular)Gasoline 6,000 Single Wall FRP 89.5 04/05/78 Active 3 Gasoline (Premium)Gasoline 6,000 Single Wall FRP 90 04/05/78 Active *4 Waste Oil Waste Oil 550 Single Wall FRP Unknown 04/05/78 Unknown Incident Number Material Released Date Release Discovered (mm/dd/yy) 20262 Gasoline 11/13/86 FRP = Fiberglass Reinforced Plastic * = Tank was not associated with the release. Dates of Ownership/Operation (year) Information obtained from a Pollution Incident Reporting Form (dated December 1986), an annotated printout from the NCDENR Tanks Database (accessed January 1998), and the current NCDEQ RUST Database (accessed November 2021). Description of the Release A 100-gallon gasoline spill reportedly occurred on November 13, 1986, orginating from a broken dispenser valve. Lakewood Exxon / Jewel Bissell 1978 - Unknown 1978 - Present 1978 - Present 1978 - Present NCDEQ; 20262_Lumberton Mobile; T1_Site History CATLIN Project No. 220237 CATLIN Engineers and Scientists March 2023 Page 1 of 1 TABLE 2 Incident Name and No.: Lumberton Mobile - 20262 Well ID Property Address Robeson County PIN Number Owner Name (Last, First MI) Owner Mailing Address Well Use Distance/ Direction from Source Area (ft.) Comment Receptor ID Location Distance/ Direction from Source Area (ft.) Creek West and South of Site 100 / S Pond West of Site 1,275 / W Information obtained from observations on Google Earth. ft. = feet PUBLIC AND PRIVATE WATER SUPPLY WELLS AND OTHER RECEPTOR INFORMATION No water supply well information is available. Pond located in marshy area to the west of site. Creek fed by pond that runs along the southern boundary of the site. Description David J Goode and Susan G Batten 3300 Sharon Rd, Charlotte, NC — Contact NCDEQ; 20262_Lumberton Mobile; T2_Receptor Info CATLIN Project No. 220237 CATLIN Engineers and Scientists March 2023 Page 1 of 1 TABLE 3 WELL CONSTRUCTION AND HISTORICAL WATER LEVEL GAUGING DATA Incident Name and No.: Lumberton Mobile - 20262 Well ID Date Installed (mm/dd/yy)* Date Water Level Measured (mm/dd/yy) Well Diameter (inches) Well Casing Depth (ft. BLS)* Screened Interval (x to y ft. BLS)* Bottom of Well (ft. BLS)* Top of Casing Elevation (ft.) Free-Phase Product Thickness** Depth to Groundwater from Top of Casing (ft.) Groundwater Elevation (ft.)Comments B-1 12/11/86 NM 4.0 3 3-13 13 Unknown Could not access 12/09/20 7.70 NM NM 12/21/21 6.21 6.53 NM 02/14/23 0.09 5.14 NM 12/09/20 NMT 4.20 NM 12/21/21 NMT 4.34 NM 02/14/23 NMT 4.11 NM No well cap 12/21/21 NMT 7.27 NM 02/14/23 NMT 6.02 NM 12/21/21 NMT 6.61 NM 02/14/23 NMT 5.72 NM ft. BLS = feet Below Land Surface NM = Not Measured NMT = No Measurable Thickness * = Data for wells installed prior to 2021 obtained from well construction records by Carolina Drilling (1986). 12/11/86B-3 Unknown133-1334.012/11/86B-2 Unknown Unknown133-133 NM 4.0 ** = if free-phase product is present in a well, ground water elevation should be calculated by : [top of casing elevation - depth to water]+ [free product thickness x specific gravity of the fuel type] Unknown133-1332.012/16/21MW-02 MW-01 11/18/21 2.0 3 3-13 13 NCDEQ; 20262_Lumberton Mobile; T3_Well Construction & Gauging CATLIN Project No. 220237 CATLIN Engineers and Scientists March 2023 Page 1 of 1 TABLE 4 LNAPL RECOVERY INFORMATION Incident Name and No.: Lumberton Mobile - 20262 Date (mm/dd/yy)Well ID # Product Type (gas, diesel, etc.) LNAPL Recovery Method Product Thickness before Recovery (feet) Product Thickness after Recovery (feet) Amount of Petroleum Vapors (equivalent gallons) Amount of Liquid (Water + Product) (gallons) Amount of Liquid Product (gallons) Total Amount of Product Recovered (gallons) Duration of Event (hours) 11/18/21 B-2 Gasoline Bail Down Recovery 6.21 0 Not Applicable ~5 4.36 4.36 3.33 05/11/22 B-2 Gasoline Aggressive Fluid Vapor Recovery Not Measured 0 Not Calculated 105 ~5 5.00 2.00 02/14/23 B-2 Gasoline Bail Down Recovery 0.09 0 Not Applicable ~2 ~0.5 0.5 1.5 LNAPL = Light Non-Aqueous Phase Liquid ~ = Approximate 0.5 5.00 02/14/23 05/11/22 9.86 Date of Recovery Event (mm/dd/yy) Total Volume Recovered from Site During Recovery (gallons) Cumulative Total of Volume Recovered to Date from All Recovery Events (gallons) 11/18/21 4.36 NCDEQ; 20262_Lumberton Mobile; T4_LNAPL Recovery CATLIN Project No. 220237 CATLIN Engineers and Scientists March 2023 Page 1 of 1 TABLE 5 SUMMARY OF CURRENT GROUNDWATER LABORATORY RESULTS — STANDARD METHOD 6200B Incident Name and No.: Lumberton Mobile - 20262 Date Collected (mm/dd/yy) 02/14/23 9.2 J 120 2.9 1.6 <0.17 5.8 26 31 5.9 28 45 2.5 2.3 0.57 4.96 J BMDL 02/14/23 3.7 J <0.20 <0.15 <0.11 <0.17 <0.13 <0.21 <0.11 0.84 <0.24 <0.086 <0.22 <0.20 <0.11 <0.69 BMDL 02/14/23 <2.0 7.0 <0.15 <0.11 0.17 J 0.64 0.84 2.2 1.2 4.4 1.8 <0.22 0.47 J 0.26 J <0.90 J*BMDL 02/14/23 <2.0 <0.20 <0.15 <0.11 0.58 <0.13 <0.21 <0.11 <0.17 <0.24 <0.086 <0.22 <0.20 <0.11 <0.69 BMDL All results in micrograms per liter (µg/L). BMDL = Below Method Detection Limit (refer to analytical report for a complete list of analytes and detection limits) Bold results indicate concentrations above 2L GWQS. GCL = Gross Contaminant Level 2L GWQS = NCAC T15A:02L Groundwater Quality Standards < = Less than method detection limit * = The value represents the sum of the reported practical quantitation limit of one analyte and the detected concentration of the other analyte. J = Detected but below the Reporting Limit (lowest calibration standard); result is an estimated concentration (CLP J-Flag). Trip Blank (TB) 28,500 400 24,100 400 50,000 500 Varies Varies 26,100 70 260,000 600 80,000 600 30,500 70 20,000 20 6,000 6 GCL (µg/L) 2L GWQS (µg/L) 6,000,000 6,000 5,000 1 5,900 70 8,800 70 70,000 70Chloroform 70,000 70 Naphthalene Contaminant of Concern AcetoneBenzenen-Butylbenzenesec-ButylbenzeneDiisopropyl Ether (DIPE)Well/ Sample ID EthylbenzeneIsopropylbenzene (Cumene)Methyl tert-Butyl Ether (MTBE)MW-02 MW-01 B-3 1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneTotal XylenesAll Other SM 6200B Analytesn-PropylbenzeneTolueneNCDEQ; 20262_Lumberton Mobile; T5_GW Results (SM 6200B) CATLIN Project No. 220237 CATLIN Engineers and Scientists March 2023 Page 1 of 1 TABLE 6 SUMMARY OF HISTORICAL GROUNDWATER LABORATORY RESULTS — STANDARD METHOD 6200B Incident Name and No.: Lumberton Mobile - 20262 Date Collected (mm/dd/yy) 12/09/20 BMDL 1,100 6.2 J BMDL BMDL 9.4 J 180 92 15 340 130 17 48 28 <86.4*BMDL 12/21/21 <4.7 43 0.76 J 0.44 J BMDL 10 1.0 10 6.9 11 10 1.6 0.8 J 0.42 J 3.48 J BMDL 02/14/23 9.2 J 120 2.9 1.6 <0.17 5.8 26 31 5.9 28 45 2.5 2.3 0.57 4.96 J BMDL 12/21/21 <4.7 <0.26 <0.28 <0.20 BMDL <0.30 <0.18 <0.20 1.6 <0.30 <0.16 <0.22 0.34 J <0.20 <0.54 BMDL 02/14/23 3.7 J <0.20 <0.15 <0.11 <0.17 <0.13 <0.21 <0.11 0.84 <0.24 <0.086 <0.22 <0.20 <0.11 <0.69 BMDL 12/21/21 <4.7 57 <0.28 <0.20 BMDL 11 0.94 J 3.4 12 4.1 0.36 J 1.1 0.24 <0.20 3.44 J BMDL 02/14/23 <2.0 7.0 <0.15 <0.11 0.17 J 0.64 0.84 2.2 1.2 4.4 1.8 <0.22 0.47 J 0.26 J <0.90 J*BMDL All results in micrograms per liter (µg/L). BMDL = Below Method Detection Limit (refer to analytical report for a complete list of analytes and detection limits) Bold results indicate concentrations above 2L GWQS. GCL = Gross Contaminant Level 2L GWQS = NCAC T15A:02L Groundwater Quality Standards < = Less than method detection limit * = The value represents the sum of the reported practical quantitation limit of one analyte and the detected concentration of the other analyte. J = Detected but below the Reporting Limit (lowest calibration standard); result is an estimated concentration (CLP J-Flag).1,2,4-Trimethylbenzene1,3,5-Trimethylbenzene260,000 600 28,500 400 24,100 400 Total XylenesAll Other SM 6200B AnalytesWell/ Sample ID EthylbenzeneIsopropylbenzene (Cumene)Methyl tert-Butyl Ether (MTBE)Naphthalene n-PropylbenzeneTolueneContaminant of Concern AcetoneBenzenen-Butylbenzenesec-ButylbenzeneDiisopropyl Ether (DIPE)Chloroform 50,000 500 Varies Varies MW-02 MW-01 70,000 70 B-3 26,100 70 8,800 70 70,000 70 80,000 600 30,500 70 20,000 20 6,000 6 GCL (µg/L) 2L GWQS (µg/L) 6,000,000 6,000 5,000 1 5,900 70 NCDEQ; 20262_Lumberton Mobile; T6_Historical GW (SM 6200B) CATLIN Project No. 220237 CATLIN Engineers and Scientists March 2023 NCDEQ; 20262_Lumberton Mobile CATLIN Engineers and Scientists CATLIN Project No. 220237 March 2023 FIGURES FIGUREPROJECTTITLE 1LUMBERTON MOBILE5105 N FAYETTEVILLE RDLUMBERTON, NC SITE VICINITY MAP SITE LOCATION INTERSTATE 95F AYETTEVI L LE RDCopyright:© 2013 National Geographic Society, i-cubed 2,000 0 2,000 4,0001,000 Feet ³ INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY20262220237MARCH 2023 AS SHOWN KMC/BJA FIGUREPROJECTTITLE 2LUMBERTON MOBILE5105 N FAYETTEVILLE RDLUMBERTON, NC POTENTIAL RECEPTOR MAP SITE LOCATIONINTERSTATE 95F A Y E T T E VIL L E R D 1 ,5 0 0 FEET RADIUS 500 F E E T RADIUS POND CREEK Source: Esri, Maxar, Earthstar Geographics, and the GIS User Community 500 0 500 1,000250 Feet ³ NOTE: Information regarding nearby water supply wells was not available. INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY20262220237MARCH 2023 AS SHOWN KMC/BJA FIGUREPROJECTTITLE 3LUMBERTON MOBILE5105 N FAYETTEVILLE RDLUMBERTON, NC SITE MAP !> !> !? !( !> !> F A Y E T T E VIL L E R D B-2 B-3 P-1 B-1 FORMERUST BASIN GASOLINEDISPENSERSMW-01 MW-02 Source: Esri, Maxar, Earthstar Geographics, and the GIS User Community 30 0 30 6015 Feet ³ NOTE: Well and tank locations were obtained from previous reportsprepared by other consultants and are approximate. LEGEND Monitoring Well(Type II)!> Parcel Boundary Approximate Location of UST System Piezometer!( INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY20262220237MARCH 2023 AS SHOWN KMC/BJA Abandoned Monitoring Well (Type II)!? FIGUREPROJECTTITLE 4LUMBERTON MOBILE5105 N FAYETTEVILLE RDLUMBERTON, NC DEPTH TO WATER —FEBRUARY 14, 2023 !> !> !> !><F A Y E T T E VIL L E R D B-2(5.14) B-3(4.11) MW-01 (6.02) MW-02 (5.72) Source: Esri, Maxar, Earthstar Geographics, and the GIS User Community ³ NOTES:1. Well and tank locations were obtained from previous reportsprepared by other consultants and are approximate.2. Historical groundwater information obtained from CATLIN (1986). LEGEND Gauged MonitoringWell (Type II)!> Parcel Boundary Approximate Locationof UST System INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY20262220237MARCH 2023 AS SHOWN KMC/BJA Historical GroundwaterFlow Direction<Depth to Water(Feet)(##) 30 0 30 6015 Feet FIGURETITLE 5LUMBERTON MOBILE5105 N FAYETTEVILLE RDLUMBERTON, NC MONITORING WELLGROUNDWATER SAMPLEANALYTICAL RESULTS —FEBRUARY 14, 2023 !> !> !> !> F A Y E T T E VIL L E R D B-2* B-3 MW-01 MW-02 Source: Esri, Maxar, Earthstar Geographics, and the GIS User Community 30 0 30 6015 Feet ³ INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY20262220237MARCH 2023 AS SHOWN KMC/BJA PROJECT NOTES:1. Well and tank locations were obtained from previous reportsprepared by other consultants and are approximate.2. * = Well not sampled due to the presence of LNAPL3. LNAPL = Light Non-Aqueous Phase Liquid LEGEND Monitoring Well (Type II)!> Parcel Boundary Approximate Locationof UST System Sampled MonitoringWell (Type II)!> NCDEQ; 20262_Lumberton Mobile CATLIN Engineers and Scientists CATLIN Project No. 220237 March 2023 APPENDICES NCDEQ; 20262_Lumberton Mobile CATLIN Engineers and Scientists CATLIN Project No. 220237 March 2023 APPENDIX A HISTORICAL DATA APPENDIX A HISTORICAL DATA (Hydrologic, 1995)NCDEQ; 20262_Lumberton Mobile; AppA CATLIN Project No. 220237CATLIN Engineers and Scientists March 2023 APPENDIX A HISTORICAL DATA (Hydrologic, 1995)NCDEQ; 20262_Lumberton Mobile; AppA CATLIN Project No. 220237CATLIN Engineers and Scientists March 2023 APPENDIX A HISTORICAL DATA (Hydrologic, 1995)NCDEQ; 20262_Lumberton Mobile; AppA CATLIN Project No. 220237CATLIN Engineers and Scientists March 2023 NCDEQ; 20262_Lumberton Mobile CATLIN Engineers and Scientists CATLIN Project No. 220237 March 2023 APPENDIX B SITE PHOTOGRAPHS APPENDIX B SITE PHOTOGRAPHS – FEBRUARY 14, 2023 NCDEQ; 20262_Lumberton Mobile; AppB CATLIN Engineers and Scientists CATLIN Project No. 220237 March 2023 View of site, facing south. View of MW-01, facing northwest. APPENDIX B SITE PHOTOGRAPHS – FEBRUARY 14, 2023 NCDEQ; 20262_Lumberton Mobile; AppB CATLIN Engineers and Scientists CATLIN Project No. 220237 March 2023 View of MW-02, facing southwest. View of B-2, facing southeast. APPENDIX B SITE PHOTOGRAPHS – FEBRUARY 14, 2023 NCDEQ; 20262_Lumberton Mobile; AppB CATLIN Engineers and Scientists CATLIN Project No. 220237 March 2023 View of B-3, facing south. View of product from B-2. APPENDIX B SITE PHOTOGRAPHS – FEBRUARY 14, 2023 NCDEQ; 20262_Lumberton Mobile; AppB CATLIN Engineers and Scientists CATLIN Project No. 220237 March 2023 View of product in bailer from B-2. NCDEQ; 20262_Lumberton Mobile CATLIN Engineers and Scientists CATLIN Project No. 220237 March 2023 APPENDIX C JOB HAZARD ANALYSIS AND FIELD DATA SHEETS Source Exposure Limit Groundwater and/or soil vapor 0.5 ppm TLV-TWA ACGIH Groundwater and/or soil vapor 100 ppm TLV-TWA ACGIH Groundwater and/or soil vapor 20 ppm TLV-TWA ACGIH Groundwater and/or soil vapor 100 ppm TLV-TWA ACGIH Groundwater and/or soil vapor 50 ppm TLV-TWA ACGIH Groundwater and/or soil vapor 10 ppm TLV-TWA ACGIH Source Exposure Limit atmosphere N/A atmosphere N/A surroundings N/A Exposure Potential Likely Unlikely Unlikely Start Stop 8:15 9:15 9:15 10:45 10:45 11:00 11:00 14:15 14:15 15:15 15:45 16:45 Date and Time: 02/14/2023 @ 11:00 Insect bites and stings Cold Weather Operations Unlikely Heat (ambient) Biological Hazards Name of Biological Hazard Source Equipment Used:PPE D/Water Level Indicator/Sampling Supplies/Aqua Troll 600/Bailers Van #59 Mileage: Mob equipment/supplies, discuss jobs and clean out van. Travel to site. On-site safety meeting. Watch for animals and insects in and around well house. Practice safe housekeeping to avoid slips trips and falls. Sandra Miller / CATLIN Unlikely Slips/Trips/Falls Likely surroundings Gauge, sample, and photographed wells B-3, MW-01, and MW-02. Start:End: DAILY TASK Snakes surroundings Poison Plants (Ivy, Oak, and/or Sumac)surroundings Bailed free product and removed sediment from inside well shield for B-2. Product stored in drum on site. Departed site and travel to next site. PERSONNEL ONSITE Name and Company (Print)Signature Chemical Hazards Sunny Mid 60s Site-Specific Job Hazard Analysis Location Where Task/Operation Performed Lumberton Mobile, Lumberton, NC Task/Operation Gauge and Sample Wells/Bail Free Product Employee Certifying this JHA Print Name: Benjamin J. Ashba, P.G.Signature: Operational Phase Monitoring Date(s) this JHA Conducted: 02/14/2023 Weather: Potential Chemicals Concentration BENZENE ppm ETHYL BENZENE ppm TOLUENE ppm XYLENE, ALL ISOMERS ppm METHYL TERT-BUTYL ETHER ppm NAPHTHALENE ppm Physical Hazards Name of Physical Hazard Exposure Level/ Potential * Gas and/or Diesel CATLIN PROJECT: SAMPLED BY: CATLIN PROJECT # : DATE SAMPLED: CLIENT'S NAME: MW-01 6.98 6.02 1.139 NMT 3.417 13 5.696 2 Method:Bailer Purge Start Time:11:32 Required Bails for 3 Well Volumes:15 Purge Stop Time:11:39 Required Bails for 5 Well Volumes:24 Was Well Purged Dry?No Number of Bails Removed:15 Sample Time:11:40 Groundwater Removed (gal):3.6 Equipment Used: Time Specific Cond. (µS/cm) Dissolved Oxygen (mg/L) pH (Standard Units) ORP (mV) Temperature (Co) 11:31 43.31 6.61 12.08 -62.11 27.96 11:32 206.77 2.40 11.90 -45.27 28.01 11:33 205.30 2.03 11.85 -40.25 28.07 11:34 208.75 1.80 11.81 -38.54 28.12 11:35 208.86 1.63 11.77 -37.89 28.28 11:36 196.90 1.46 11.77 -37.21 28.37 11:37 206.56 1.29 11.74 -36.66 28.44 Laboratory: Con-Test Analysis: High turbidity; dark gray. Laboratory Analysis Information 6200B Well Diameter (inches) Purging Information Information Geochemical Parameters Aqua Troll 600 Turbidity and Additional Sampling Notes Depth to Water (ft below TOC) One Well Volume (gal) Depth to Product (ft below TOC)Three Well Volumes (gal) Total Well Depth (ft) Five Well Volumes (gal) NCDEQ-Ryals Monitoring Well Information Well Data Volume of Groundwater in Well Well ID Water Column (ft below TOC) GROUNDWATER SAMPLING FORM Lumberton Mobile Sandy Miller 220237.4 2/14/2023 CATLIN PROJECT: SAMPLED BY: CATLIN PROJECT # : DATE SAMPLED: CLIENT'S NAME: MW-02 7.28 5.72 1.188 NMT 3.564 13 5.940 2 Method:Bailer Purge Start Time:12:05 Required Bails for 3 Well Volumes:15 Purge Stop Time:12 11 Required Bails for 5 Well Volumes:25 Was Well Purged Dry?No Number of Bails Removed:15 Sample Time:12:12 Groundwater Removed (gal):3.6 Equipment Used: Time Specific Cond. (µS/cm) Dissolved Oxygen (mg/L) pH (Standard Units) ORP (mV) Temperature (Co) 12:04 4.83 6.20 11.95 6.89 27.92 12:05 306.86 3.80 12.20 -23.56 25.73 12:06 472.72 2.51 12.18 -10.09 25.51 12:07 311.13 2.46 12.14 -13.69 25.52 12:08 325.20 2.52 12.10 -18.59 25.60 12:09 313.19 2.48 12.07 -25.20 25.67 12:10 315.18 2.48 12.05 -31.44 25.75 Laboratory: Con-Test Analysis: High turbidity; milky medium gray. Laboratory Analysis Information 6200B Well Diameter (inches) Purging Information Information Geochemical Parameters Aqua Troll 600 Turbidity and Additional Sampling Notes Depth to Water (ft below TOC) One Well Volume (gal) Depth to Product (ft below TOC)Three Well Volumes (gal) Total Well Depth (ft) Five Well Volumes (gal) NCDEQ-Ryals Monitoring Well Information Well Data Volume of Groundwater in Well Well ID Water Column (ft below TOC) GROUNDWATER SAMPLING FORM Lumberton Mobile Sandy Miller 220237.4 2/14/2023 CATLIN PROJECT: SAMPLED BY: CATLIN PROJECT # : DATE SAMPLED: CLIENT'S NAME: B-2 7.86 5.14 5.131 5.05 15.393 13 25.655 4 Method:Bailer Purge Start Time: Required Bails for 3 Well Volumes:65 Purge Stop Time: Required Bails for 5 Well Volumes:107 Was Well Purged Dry? Number of Bails Removed: Sample Time: Groundwater Removed (gal):0.0 Equipment Used: Time Specific Cond. (µS/cm) Dissolved Oxygen (mg/L) pH (Standard Units) ORP (mV) Temperature (Co) Laboratory: Con-Test Analysis: Depth to Water (ft below TOC) One Well Volume (gal) GROUNDWATER SAMPLING FORM Lumberton Mobile Sandy Miller 220237.4 2/14/2023 NCDEQ-Ryals Monitoring Well Information Well Data Volume of Groundwater in Well Well ID Water Column (ft below TOC) 6200B Depth to Product (ft below TOC)Three Well Volumes (gal) Total Well Depth (ft) Five Well Volumes (gal) Well Diameter (inches) Purging Information Information Geochemical Parameters Aqua Troll 600 Turbidity and Additional Sampling Notes Bailed product into drum. Dark brown, possibly some type of oil. Laboratory Analysis Information CATLIN PROJECT: SAMPLED BY: CATLIN PROJECT # : DATE SAMPLED: CLIENT'S NAME: B-3 8.89 4.11 5.803 NMT 17.410 13 29.017 4 Method:Bailer Purge Start Time:12:41 Required Bails for 3 Well Volumes:73 Purge Stop Time:15:15 Required Bails for 5 Well Volumes:121 Was Well Purged Dry?No Number of Bails Removed:73 Sample Time:15:16 Groundwater Removed (gal):17.5 Equipment Used: Time Specific Cond. (µS/cm) Dissolved Oxygen (mg/L) pH (Standard Units) ORP (mV) Temperature (Co) 14:56 290.31 2.84 12.03 -74.64 27.20 14:57 302.63 2.86 12.00 -77.34 27.21 14:58 318.79 2.92 12.00 -80.06 27.23 14:59 330.37 2.95 11.99 -82.48 27.26 15:00 339.82 2.90 11.97 -83.82 27.37 15:01 347.57 2.75 11.95 -84.93 27.43 15:02 354.58 2.92 11.99 -84.91 27.49 15:03 343.51 5.36 11.97 -86.96 27.44 15:04 271.33 6.60 12.00 -89.26 27.36 15:05 394.60 5.13 11.90 -90.26 27.34 15:06 396.79 2.63 11.87 -90.08 27.42 15:07 407.67 2.52 11.86 -91.47 27.41 15:08 402.88 2.99 11.85 -90.95 27.52 15:09 0.22 6.95 12.02 -87.97 26.99 15:10 58.88 6.87 12.16 -88.07 27.19 15:11 325.34 6.98 12.04 -89.21 27.27 15:12 405.03 3.93 11.88 -87.21 27.19 15:13 408.42 2.28 11.84 -87.68 27.24 15:14 406.76 2.23 11.86 -88.52 27.33 Laboratory: Con-Test Analysis:6200B Laboratory Analysis Information Geochemical Parameters Depth to Water (ft below TOC) GROUNDWATER SAMPLING FORM Water Column (ft below TOC) One Well Volume (gal) Three Well Volumes (gal) Five Well Volumes (gal) 220237.4 NCDEQ-Ryals Monitoring Well Information Sandy Miller 2/14/2023 Lumberton Mobile Well Diameter (inches) Moderate turbidity with particulates; medium gray. Mild HCO. Well Data Well ID Depth to Product (ft below TOC) Total Well Depth (ft) Purging Information Information Volume of Groundwater in Well Aqua Troll 600 Turbidity and Additional Sampling Notes NCDEQ; 20262_Lumberton Mobile CATLIN Engineers and Scientists CATLIN Project No. 220237 March 2023 APPENDIX D LABORATORY ANALYTICAL REPORT AND CHAIN OF CUSTODY DOCUMENT 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 February 22, 2023 Ben Ashba CATLIN Engineers & Scientists 220 Old Dairy Road Wilmington, NC 28405 Project Location: Lumberton, NY Client Job Number: Project Number: 220237.4 Laboratory Work Order Number: 23B1834 Enclosed are results of analyses for samples as received by the laboratory on February 16, 2023. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kaitlyn A. Feliciano Project Manager Page 1 of 24 Table of Contents Table of Contents Sample Summary 3 Hits Only Report 4 Case Narrative 5 Sample Results 6 23B1834-01 6 23B1834-02 8 23B1834-03 10 23B1834-04 12 Sample Preparation Information 14 QC Data 15 Volatile Organic Compounds by GC/MS 15 B331875 15 Flag/Qualifier Summary 19 Certifications 20 Chain of Custody/Sample Receipt 22 Page 2 of 24 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL SUMMARY 2/22/2023 CATLIN Engineers & Scientists 220 Old Dairy Road Wilmington, NC 28405 ATTN: Ben Ashba 220237.4 23B1834 The results of analyses performed on the following samples submitted to the CON-TEST Analytical Laboratory are found in this report. PROJECT LOCATION: PURCHASE ORDER NUMBER: PROJECT NUMBER: REPORT DATE: WORK ORDER NUMBER: FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB Lumberton, NY 230215-5 MW-01 23B1834-01 Ground Water SM21-23 6200B MW-02 23B1834-02 Ground Water SM21-23 6200B B-3 23B1834-03 Ground Water SM21-23 6200B TB 23B1834-04 Ground Water SM21-23 6200B [TOC_1]Sample Summary[TOC] Page 3 of 24 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 [TOC_1]Hits Only Report[TOC]EXECUTIVE SUMMARY Client ID:Lab ID: Analyte Results/Qual RL Units Method 23B1834-01MW-01 DL Acetone 3.7 50 g/L SM21-23 6200BJ2.0 Methyl tert-Butyl Ether (MTBE)0.84 0.50 g/L SM21-23 6200B0.17 Client ID:Lab ID: Analyte Results/Qual RL Units Method 23B1834-02MW-02 DL 1,2,4-Trimethylbenzene 0.47 0.50 g/L SM21-23 6200BJ0.20 1,3,5-Trimethylbenzene 0.26 0.50 g/L SM21-23 6200BJ0.11 Benzene 7.0 0.50 g/L SM21-23 6200B0.20 Chloroform 0.17 0.50 g/L SM21-23 6200BJ0.17 Diisopropyl Ether (DIPE)0.64 0.50 g/L SM21-23 6200B0.13 Ethylbenzene 0.84 0.50 g/L SM21-23 6200B0.21 Isopropylbenzene (Cumene)2.2 0.50 g/L SM21-23 6200B0.11 m+p Xylene 0.67 1.0 g/L SM21-23 6200BJ0.46 Methyl tert-Butyl Ether (MTBE)1.2 0.50 g/L SM21-23 6200B0.17 Naphthalene 4.4 0.50 g/L SM21-23 6200B0.24 n-Propylbenzene 1.8 0.50 g/L SM21-23 6200B0.086 Client ID:Lab ID: Analyte Results/Qual RL Units Method 23B1834-03B-3 DL 1,2,4-Trimethylbenzene 2.3 0.50 g/L SM21-23 6200B0.20 1,3,5-Trimethylbenzene 0.57 0.50 g/L SM21-23 6200B0.11 Acetone 9.2 50 g/L SM21-23 6200BJ2.0 Benzene 120 0.50 g/L SM21-23 6200B0.20 Diisopropyl Ether (DIPE)5.8 0.50 g/L SM21-23 6200B0.13 Ethylbenzene 26 0.50 g/L SM21-23 6200B0.21 Isopropylbenzene (Cumene)31 0.50 g/L SM21-23 6200B0.11 m+p Xylene 4.5 1.0 g/L SM21-23 6200B0.46 Methyl tert-Butyl Ether (MTBE)5.9 0.50 g/L SM21-23 6200B0.17 Naphthalene 28 0.50 g/L SM21-23 6200B0.24 n-Butylbenzene 2.9 0.50 g/L SM21-23 6200B0.15 n-Propylbenzene 45 0.50 g/L SM21-23 6200B0.086 o-Xylene 0.46 0.50 g/L SM21-23 6200BJ0.23 sec-Butylbenzene 1.6 0.50 g/L SM21-23 6200B0.11 Toluene 2.5 0.50 g/L SM21-23 6200B0.22 Client ID:Lab ID: Analyte Results/Qual RL Units Method 23B1834-04TB DL Chloroform 0.58 0.50 g/L SM21-23 6200B0.17 Con-Test does not accept liability for the consequences of any actions taken solely on the basis of the information provided in the Executive Summary section of this report. Users must review this report in its entirety to determine data usability and assessment. Page 4 of 24 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CASE NARRATIVE SUMMARY All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report. [TOC_1]Case Narrative[TOC] The results of analyses reported only relate to samples submitted to the Con-Test Analytical Laboratory for testing. I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. Meghan E. Kelley Reporting Specialist Page 5 of 24 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 2/16/2023 Work Order: 23B1834Sample Description:Project Location: Lumberton, NY Sample ID: 23B1834-01 Field Sample #: MW-01 Sample Matrix: Ground Water Sampled: 2/14/2023 11:40 [TOC_2]23B1834-01[TOC] AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS 3.7 50 2/17/23 20:23 EEHg/L2.0 2/17/23SM21-23 6200B1JAcetone ND 0.50 2/17/23 20:23 EEHg/L0.20 2/17/23SM21-23 6200B1Benzene ND 0.50 2/17/23 20:23 EEHg/L0.15 2/17/23SM21-23 6200B1Bromobenzene ND 0.50 2/17/23 20:23 EEHg/L0.31 2/17/23SM21-23 6200B1Bromochloromethane ND 0.50 2/17/23 20:23 EEHg/L0.18 2/17/23SM21-23 6200B1Bromodichloromethane ND 0.50 2/17/23 20:23 EEHg/L0.38 2/17/23SM21-23 6200B1Bromoform ND 2.0 2/17/23 20:23 EEHg/L1.5 2/17/23SM21-23 6200B1Bromomethane ND 5.0 2/17/23 20:23 EEHg/L1.6 2/17/23SM21-23 6200B12-Butanone (MEK) ND 0.50 2/17/23 20:23 EEHg/L0.15 2/17/23SM21-23 6200B1n-Butylbenzene ND 0.50 2/17/23 20:23 EEHg/L0.11 2/17/23SM21-23 6200B1sec-Butylbenzene ND 0.50 2/17/23 20:23 EEHg/L0.13 2/17/23SM21-23 6200B1tert-Butylbenzene ND 0.50 2/17/23 20:23 EEHg/L0.16 2/17/23SM21-23 6200B1Carbon Tetrachloride ND 0.50 2/17/23 20:23 EEHg/L0.11 2/17/23SM21-23 6200B1Chlorobenzene ND 50 2/17/23 20:23 EEHg/L26 2/17/23SM21-23 6200B1Ethanol ND 0.50 2/17/23 20:23 EEHg/L0.22 2/17/23SM21-23 6200B1Chlorodibromomethane ND 0.50 2/17/23 20:23 EEHg/L0.32 2/17/23SM21-23 6200B1Chloroethane ND 0.50 2/17/23 20:23 EEHg/L0.17 2/17/23SM21-23 6200B1Chloroform ND 0.60 2/17/23 20:23 EEHg/L0.52 2/17/23SM21-23 6200B1Chloromethane ND 0.50 2/17/23 20:23 EEHg/L0.11 2/17/23SM21-23 6200B12-Chlorotoluene ND 0.50 2/17/23 20:23 EEHg/L0.12 2/17/23SM21-23 6200B14-Chlorotoluene ND 0.50 2/17/23 20:23 EEHg/L0.17 2/17/23SM21-23 6200B11,2-Dibromoethane (EDB) ND 0.50 2/17/23 20:23 EEHg/L0.12 2/17/23SM21-23 6200B11,2-Dichlorobenzene ND 0.50 2/17/23 20:23 EEHg/L0.12 2/17/23SM21-23 6200B11,3-Dichlorobenzene ND 0.50 2/17/23 20:23 EEHg/L0.13 2/17/23SM21-23 6200B11,4-Dichlorobenzene ND 0.50 2/17/23 20:23 EEHg/L0.19 2/17/23SM21-23 6200B1Dichlorodifluoromethane (Freon 12) ND 0.50 2/17/23 20:23 EEHg/L0.14 2/17/23SM21-23 6200B11,1-Dichloroethane ND 0.50 2/17/23 20:23 EEHg/L0.31 2/17/23SM21-23 6200B11,2-Dichloroethane ND 0.50 2/17/23 20:23 EEHg/L0.14 2/17/23SM21-23 6200B11,1-Dichloroethylene ND 0.50 2/17/23 20:23 EEHg/L0.15 2/17/23SM21-23 6200B1cis-1,2-Dichloroethylene ND 0.50 2/17/23 20:23 EEHg/L0.17 2/17/23SM21-23 6200B1trans-1,2-Dichloroethylene ND 0.50 2/17/23 20:23 EEHg/L0.18 2/17/23SM21-23 6200B11,2-Dichloropropane ND 0.50 2/17/23 20:23 EEHg/L0.13 2/17/23SM21-23 6200B11,3-Dichloropropane ND 0.50 2/17/23 20:23 EEHg/L0.33 2/17/23SM21-23 6200B12,2-Dichloropropane ND 0.50 2/17/23 20:23 EEHg/L0.15 2/17/23SM21-23 6200B11,1-Dichloropropene ND 0.50 2/17/23 20:23 EEHg/L0.16 2/17/23SM21-23 6200B1cis-1,3-Dichloropropene ND 0.50 2/17/23 20:23 EEHg/L0.17 2/17/23SM21-23 6200B1trans-1,3-Dichloropropene ND 0.50 2/17/23 20:23 EEHg/L0.13 2/17/23SM21-23 6200B1Diisopropyl Ether (DIPE) ND 0.50 2/17/23 20:23 EEHg/L0.21 2/17/23SM21-23 6200B1Ethylbenzene ND 5.0 2/17/23 20:23 EEHg/L1.1 2/17/23SM21-23 6200B12-Hexanone (MBK) ND 0.50 2/17/23 20:23 EEHg/L0.11 2/17/23SM21-23 6200B1Isopropylbenzene (Cumene) ND 0.50 2/17/23 20:23 EEHg/L0.097 2/17/23SM21-23 6200B1p-Isopropyltoluene (p-Cymene) 0.84 0.50 2/17/23 20:23 EEHg/L0.17 2/17/23SM21-23 6200B1Methyl tert-Butyl Ether (MTBE) ND 5.0 2/17/23 20:23 EEHg/L0.23 2/17/23SM21-23 6200B1Methylene Chloride ND 5.0 2/17/23 20:23 EEHg/L1.3 2/17/23SM21-23 6200B14-Methyl-2-pentanone (MIBK) [TOC_1]Sample Results[TOC] Page 6 of 24 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 2/16/2023 Work Order: 23B1834Sample Description:Project Location: Lumberton, NY Sample ID: 23B1834-01 Field Sample #: MW-01 Sample Matrix: Ground Water Sampled: 2/14/2023 11:40 AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS ND 0.50 2/17/23 20:23 EEHg/L0.24 2/17/23SM21-23 6200B1Naphthalene ND 0.50 2/17/23 20:23 EEHg/L0.086 2/17/23SM21-23 6200B1n-Propylbenzene ND 0.50 2/17/23 20:23 EEHg/L0.11 2/17/23SM21-23 6200B1Styrene ND 0.50 2/17/23 20:23 EEHg/L0.13 2/17/23SM21-23 6200B11,1,2,2-Tetrachloroethane ND 0.50 2/17/23 20:23 EEHg/L0.19 2/17/23SM21-23 6200B1Tetrachloroethylene ND 0.50 2/17/23 20:23 EEHg/L0.22 2/17/23SM21-23 6200B1Toluene ND 1.0 2/17/23 20:23 EEHg/L0.30 2/17/23SM21-23 6200B11,2,3-Trichlorobenzene ND 1.0 2/17/23 20:23 EEHg/L0.25 2/17/23SM21-23 6200B11,2,4-Trichlorobenzene ND 0.50 2/17/23 20:23 EEHg/L0.17 2/17/23SM21-23 6200B11,1,1-Trichloroethane ND 0.50 2/17/23 20:23 EEHg/L0.18 2/17/23SM21-23 6200B11,1,2-Trichloroethane ND 0.50 2/17/23 20:23 EEHg/L0.19 2/17/23SM21-23 6200B1Trichloroethylene ND 0.50 2/17/23 20:23 EEHg/L0.18 2/17/23SM21-23 6200B1Trichlorofluoromethane (Freon 11) ND 0.50 2/17/23 20:23 EEHg/L0.28 2/17/23SM21-23 6200B11,2,3-Trichloropropane ND 0.50 2/17/23 20:23 EEHg/L0.20 2/17/23SM21-23 6200B11,2,4-Trimethylbenzene ND 0.50 2/17/23 20:23 EEHg/L0.11 2/17/23SM21-23 6200B11,3,5-Trimethylbenzene ND 20 2/17/23 20:23 EEHg/L1.5 2/17/23SM21-23 6200B1Vinyl Acetate ND 0.50 2/17/23 20:23 EEHg/L0.21 2/17/23SM21-23 6200B1Vinyl Chloride ND 1.0 2/17/23 20:23 EEHg/L0.46 2/17/23SM21-23 6200B1m+p Xylene ND 0.50 2/17/23 20:23 EEHg/L0.23 2/17/23SM21-23 6200B1o-Xylene Surrogates % Recovery Recovery Limits Flag/Qual 1,2-Dichloroethane-d4 92.6 2/17/23 20:2370-130 Toluene-d8 100 2/17/23 20:2370-130 4-Bromofluorobenzene 96.7 2/17/23 20:2370-130 Page 7 of 24 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 2/16/2023 Work Order: 23B1834Sample Description:Project Location: Lumberton, NY Sample ID: 23B1834-02 Field Sample #: MW-02 Sample Matrix: Ground Water Sampled: 2/14/2023 12:12 [TOC_2]23B1834-02[TOC] AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS ND 50 2/17/23 20:50 EEHg/L2.0 2/17/23SM21-23 6200B1Acetone 7.0 0.50 2/17/23 20:50 EEHg/L0.20 2/17/23SM21-23 6200B1Benzene ND 0.50 2/17/23 20:50 EEHg/L0.15 2/17/23SM21-23 6200B1Bromobenzene ND 0.50 2/17/23 20:50 EEHg/L0.31 2/17/23SM21-23 6200B1Bromochloromethane ND 0.50 2/17/23 20:50 EEHg/L0.18 2/17/23SM21-23 6200B1Bromodichloromethane ND 0.50 2/17/23 20:50 EEHg/L0.38 2/17/23SM21-23 6200B1Bromoform ND 2.0 2/17/23 20:50 EEHg/L1.5 2/17/23SM21-23 6200B1Bromomethane ND 5.0 2/17/23 20:50 EEHg/L1.6 2/17/23SM21-23 6200B12-Butanone (MEK) ND 0.50 2/17/23 20:50 EEHg/L0.15 2/17/23SM21-23 6200B1n-Butylbenzene ND 0.50 2/17/23 20:50 EEHg/L0.11 2/17/23SM21-23 6200B1sec-Butylbenzene ND 0.50 2/17/23 20:50 EEHg/L0.13 2/17/23SM21-23 6200B1tert-Butylbenzene ND 0.50 2/17/23 20:50 EEHg/L0.16 2/17/23SM21-23 6200B1Carbon Tetrachloride ND 0.50 2/17/23 20:50 EEHg/L0.11 2/17/23SM21-23 6200B1Chlorobenzene ND 50 2/17/23 20:50 EEHg/L26 2/17/23SM21-23 6200B1Ethanol ND 0.50 2/17/23 20:50 EEHg/L0.22 2/17/23SM21-23 6200B1Chlorodibromomethane ND 0.50 2/17/23 20:50 EEHg/L0.32 2/17/23SM21-23 6200B1Chloroethane 0.17 0.50 2/17/23 20:50 EEHg/L0.17 2/17/23SM21-23 6200B1JChloroform ND 0.60 2/17/23 20:50 EEHg/L0.52 2/17/23SM21-23 6200B1Chloromethane ND 0.50 2/17/23 20:50 EEHg/L0.11 2/17/23SM21-23 6200B12-Chlorotoluene ND 0.50 2/17/23 20:50 EEHg/L0.12 2/17/23SM21-23 6200B14-Chlorotoluene ND 0.50 2/17/23 20:50 EEHg/L0.17 2/17/23SM21-23 6200B11,2-Dibromoethane (EDB) ND 0.50 2/17/23 20:50 EEHg/L0.12 2/17/23SM21-23 6200B11,2-Dichlorobenzene ND 0.50 2/17/23 20:50 EEHg/L0.12 2/17/23SM21-23 6200B11,3-Dichlorobenzene ND 0.50 2/17/23 20:50 EEHg/L0.13 2/17/23SM21-23 6200B11,4-Dichlorobenzene ND 0.50 2/17/23 20:50 EEHg/L0.19 2/17/23SM21-23 6200B1Dichlorodifluoromethane (Freon 12) ND 0.50 2/17/23 20:50 EEHg/L0.14 2/17/23SM21-23 6200B11,1-Dichloroethane ND 0.50 2/17/23 20:50 EEHg/L0.31 2/17/23SM21-23 6200B11,2-Dichloroethane ND 0.50 2/17/23 20:50 EEHg/L0.14 2/17/23SM21-23 6200B11,1-Dichloroethylene ND 0.50 2/17/23 20:50 EEHg/L0.15 2/17/23SM21-23 6200B1cis-1,2-Dichloroethylene ND 0.50 2/17/23 20:50 EEHg/L0.17 2/17/23SM21-23 6200B1trans-1,2-Dichloroethylene ND 0.50 2/17/23 20:50 EEHg/L0.18 2/17/23SM21-23 6200B11,2-Dichloropropane ND 0.50 2/17/23 20:50 EEHg/L0.13 2/17/23SM21-23 6200B11,3-Dichloropropane ND 0.50 2/17/23 20:50 EEHg/L0.33 2/17/23SM21-23 6200B12,2-Dichloropropane ND 0.50 2/17/23 20:50 EEHg/L0.15 2/17/23SM21-23 6200B11,1-Dichloropropene ND 0.50 2/17/23 20:50 EEHg/L0.16 2/17/23SM21-23 6200B1cis-1,3-Dichloropropene ND 0.50 2/17/23 20:50 EEHg/L0.17 2/17/23SM21-23 6200B1trans-1,3-Dichloropropene 0.64 0.50 2/17/23 20:50 EEHg/L0.13 2/17/23SM21-23 6200B1Diisopropyl Ether (DIPE) 0.84 0.50 2/17/23 20:50 EEHg/L0.21 2/17/23SM21-23 6200B1Ethylbenzene ND 5.0 2/17/23 20:50 EEHg/L1.1 2/17/23SM21-23 6200B12-Hexanone (MBK) 2.2 0.50 2/17/23 20:50 EEHg/L0.11 2/17/23SM21-23 6200B1Isopropylbenzene (Cumene) ND 0.50 2/17/23 20:50 EEHg/L0.097 2/17/23SM21-23 6200B1p-Isopropyltoluene (p-Cymene) 1.2 0.50 2/17/23 20:50 EEHg/L0.17 2/17/23SM21-23 6200B1Methyl tert-Butyl Ether (MTBE) ND 5.0 2/17/23 20:50 EEHg/L0.23 2/17/23SM21-23 6200B1Methylene Chloride ND 5.0 2/17/23 20:50 EEHg/L1.3 2/17/23SM21-23 6200B14-Methyl-2-pentanone (MIBK) Page 8 of 24 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 2/16/2023 Work Order: 23B1834Sample Description:Project Location: Lumberton, NY Sample ID: 23B1834-02 Field Sample #: MW-02 Sample Matrix: Ground Water Sampled: 2/14/2023 12:12 AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS 4.4 0.50 2/17/23 20:50 EEHg/L0.24 2/17/23SM21-23 6200B1Naphthalene 1.8 0.50 2/17/23 20:50 EEHg/L0.086 2/17/23SM21-23 6200B1n-Propylbenzene ND 0.50 2/17/23 20:50 EEHg/L0.11 2/17/23SM21-23 6200B1Styrene ND 0.50 2/17/23 20:50 EEHg/L0.13 2/17/23SM21-23 6200B11,1,2,2-Tetrachloroethane ND 0.50 2/17/23 20:50 EEHg/L0.19 2/17/23SM21-23 6200B1Tetrachloroethylene ND 0.50 2/17/23 20:50 EEHg/L0.22 2/17/23SM21-23 6200B1Toluene ND 1.0 2/17/23 20:50 EEHg/L0.30 2/17/23SM21-23 6200B11,2,3-Trichlorobenzene ND 1.0 2/17/23 20:50 EEHg/L0.25 2/17/23SM21-23 6200B11,2,4-Trichlorobenzene ND 0.50 2/17/23 20:50 EEHg/L0.17 2/17/23SM21-23 6200B11,1,1-Trichloroethane ND 0.50 2/17/23 20:50 EEHg/L0.18 2/17/23SM21-23 6200B11,1,2-Trichloroethane ND 0.50 2/17/23 20:50 EEHg/L0.19 2/17/23SM21-23 6200B1Trichloroethylene ND 0.50 2/17/23 20:50 EEHg/L0.18 2/17/23SM21-23 6200B1Trichlorofluoromethane (Freon 11) ND 0.50 2/17/23 20:50 EEHg/L0.28 2/17/23SM21-23 6200B11,2,3-Trichloropropane 0.47 0.50 2/17/23 20:50 EEHg/L0.20 2/17/23SM21-23 6200B1J1,2,4-Trimethylbenzene 0.26 0.50 2/17/23 20:50 EEHg/L0.11 2/17/23SM21-23 6200B1J1,3,5-Trimethylbenzene ND 20 2/17/23 20:50 EEHg/L1.5 2/17/23SM21-23 6200B1Vinyl Acetate ND 0.50 2/17/23 20:50 EEHg/L0.21 2/17/23SM21-23 6200B1Vinyl Chloride 0.67 1.0 2/17/23 20:50 EEHg/L0.46 2/17/23SM21-23 6200B1Jm+p Xylene ND 0.50 2/17/23 20:50 EEHg/L0.23 2/17/23SM21-23 6200B1o-Xylene Surrogates % Recovery Recovery Limits Flag/Qual 1,2-Dichloroethane-d4 93.7 2/17/23 20:5070-130 Toluene-d8 99.6 2/17/23 20:5070-130 4-Bromofluorobenzene 97.7 2/17/23 20:5070-130 Page 9 of 24 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 2/16/2023 Work Order: 23B1834Sample Description:Project Location: Lumberton, NY Sample ID: 23B1834-03 Field Sample #: B-3 Sample Matrix: Ground Water Sampled: 2/14/2023 15:16 [TOC_2]23B1834-03[TOC] AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS 9.2 50 2/17/23 21:17 EEHg/L2.0 2/17/23SM21-23 6200B1JAcetone 120 0.50 2/17/23 21:17 EEHg/L0.20 2/17/23SM21-23 6200B1Benzene ND 0.50 2/17/23 21:17 EEHg/L0.15 2/17/23SM21-23 6200B1Bromobenzene ND 0.50 2/17/23 21:17 EEHg/L0.31 2/17/23SM21-23 6200B1Bromochloromethane ND 0.50 2/17/23 21:17 EEHg/L0.18 2/17/23SM21-23 6200B1Bromodichloromethane ND 0.50 2/17/23 21:17 EEHg/L0.38 2/17/23SM21-23 6200B1Bromoform ND 2.0 2/17/23 21:17 EEHg/L1.5 2/17/23SM21-23 6200B1Bromomethane ND 5.0 2/17/23 21:17 EEHg/L1.6 2/17/23SM21-23 6200B12-Butanone (MEK) 2.9 0.50 2/17/23 21:17 EEHg/L0.15 2/17/23SM21-23 6200B1n-Butylbenzene 1.6 0.50 2/17/23 21:17 EEHg/L0.11 2/17/23SM21-23 6200B1sec-Butylbenzene ND 0.50 2/17/23 21:17 EEHg/L0.13 2/17/23SM21-23 6200B1tert-Butylbenzene ND 0.50 2/17/23 21:17 EEHg/L0.16 2/17/23SM21-23 6200B1Carbon Tetrachloride ND 0.50 2/17/23 21:17 EEHg/L0.11 2/17/23SM21-23 6200B1Chlorobenzene ND 50 2/17/23 21:17 EEHg/L26 2/17/23SM21-23 6200B1Ethanol ND 0.50 2/17/23 21:17 EEHg/L0.22 2/17/23SM21-23 6200B1Chlorodibromomethane ND 0.50 2/17/23 21:17 EEHg/L0.32 2/17/23SM21-23 6200B1Chloroethane ND 0.50 2/17/23 21:17 EEHg/L0.17 2/17/23SM21-23 6200B1Chloroform ND 0.60 2/17/23 21:17 EEHg/L0.52 2/17/23SM21-23 6200B1Chloromethane ND 0.50 2/17/23 21:17 EEHg/L0.11 2/17/23SM21-23 6200B12-Chlorotoluene ND 0.50 2/17/23 21:17 EEHg/L0.12 2/17/23SM21-23 6200B14-Chlorotoluene ND 0.50 2/17/23 21:17 EEHg/L0.17 2/17/23SM21-23 6200B11,2-Dibromoethane (EDB) ND 0.50 2/17/23 21:17 EEHg/L0.12 2/17/23SM21-23 6200B11,2-Dichlorobenzene ND 0.50 2/17/23 21:17 EEHg/L0.12 2/17/23SM21-23 6200B11,3-Dichlorobenzene ND 0.50 2/17/23 21:17 EEHg/L0.13 2/17/23SM21-23 6200B11,4-Dichlorobenzene ND 0.50 2/17/23 21:17 EEHg/L0.19 2/17/23SM21-23 6200B1Dichlorodifluoromethane (Freon 12) ND 0.50 2/17/23 21:17 EEHg/L0.14 2/17/23SM21-23 6200B11,1-Dichloroethane ND 0.50 2/17/23 21:17 EEHg/L0.31 2/17/23SM21-23 6200B11,2-Dichloroethane ND 0.50 2/17/23 21:17 EEHg/L0.14 2/17/23SM21-23 6200B11,1-Dichloroethylene ND 0.50 2/17/23 21:17 EEHg/L0.15 2/17/23SM21-23 6200B1cis-1,2-Dichloroethylene ND 0.50 2/17/23 21:17 EEHg/L0.17 2/17/23SM21-23 6200B1trans-1,2-Dichloroethylene ND 0.50 2/17/23 21:17 EEHg/L0.18 2/17/23SM21-23 6200B11,2-Dichloropropane ND 0.50 2/17/23 21:17 EEHg/L0.13 2/17/23SM21-23 6200B11,3-Dichloropropane ND 0.50 2/17/23 21:17 EEHg/L0.33 2/17/23SM21-23 6200B12,2-Dichloropropane ND 0.50 2/17/23 21:17 EEHg/L0.15 2/17/23SM21-23 6200B11,1-Dichloropropene ND 0.50 2/17/23 21:17 EEHg/L0.16 2/17/23SM21-23 6200B1cis-1,3-Dichloropropene ND 0.50 2/17/23 21:17 EEHg/L0.17 2/17/23SM21-23 6200B1trans-1,3-Dichloropropene 5.8 0.50 2/17/23 21:17 EEHg/L0.13 2/17/23SM21-23 6200B1Diisopropyl Ether (DIPE) 26 0.50 2/17/23 21:17 EEHg/L0.21 2/17/23SM21-23 6200B1Ethylbenzene ND 5.0 2/17/23 21:17 EEHg/L1.1 2/17/23SM21-23 6200B12-Hexanone (MBK) 31 0.50 2/17/23 21:17 EEHg/L0.11 2/17/23SM21-23 6200B1Isopropylbenzene (Cumene) ND 0.50 2/17/23 21:17 EEHg/L0.097 2/17/23SM21-23 6200B1p-Isopropyltoluene (p-Cymene) 5.9 0.50 2/17/23 21:17 EEHg/L0.17 2/17/23SM21-23 6200B1Methyl tert-Butyl Ether (MTBE) ND 5.0 2/17/23 21:17 EEHg/L0.23 2/17/23SM21-23 6200B1Methylene Chloride ND 5.0 2/17/23 21:17 EEHg/L1.3 2/17/23SM21-23 6200B14-Methyl-2-pentanone (MIBK) Page 10 of 24 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 2/16/2023 Work Order: 23B1834Sample Description:Project Location: Lumberton, NY Sample ID: 23B1834-03 Field Sample #: B-3 Sample Matrix: Ground Water Sampled: 2/14/2023 15:16 AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS 28 0.50 2/17/23 21:17 EEHg/L0.24 2/17/23SM21-23 6200B1Naphthalene 45 0.50 2/17/23 21:17 EEHg/L0.086 2/17/23SM21-23 6200B1n-Propylbenzene ND 0.50 2/17/23 21:17 EEHg/L0.11 2/17/23SM21-23 6200B1Styrene ND 0.50 2/17/23 21:17 EEHg/L0.13 2/17/23SM21-23 6200B11,1,2,2-Tetrachloroethane ND 0.50 2/17/23 21:17 EEHg/L0.19 2/17/23SM21-23 6200B1Tetrachloroethylene 2.5 0.50 2/17/23 21:17 EEHg/L0.22 2/17/23SM21-23 6200B1Toluene ND 1.0 2/17/23 21:17 EEHg/L0.30 2/17/23SM21-23 6200B11,2,3-Trichlorobenzene ND 1.0 2/17/23 21:17 EEHg/L0.25 2/17/23SM21-23 6200B11,2,4-Trichlorobenzene ND 0.50 2/17/23 21:17 EEHg/L0.17 2/17/23SM21-23 6200B11,1,1-Trichloroethane ND 0.50 2/17/23 21:17 EEHg/L0.18 2/17/23SM21-23 6200B11,1,2-Trichloroethane ND 0.50 2/17/23 21:17 EEHg/L0.19 2/17/23SM21-23 6200B1Trichloroethylene ND 0.50 2/17/23 21:17 EEHg/L0.18 2/17/23SM21-23 6200B1Trichlorofluoromethane (Freon 11) ND 0.50 2/17/23 21:17 EEHg/L0.28 2/17/23SM21-23 6200B11,2,3-Trichloropropane 2.3 0.50 2/17/23 21:17 EEHg/L0.20 2/17/23SM21-23 6200B11,2,4-Trimethylbenzene 0.57 0.50 2/17/23 21:17 EEHg/L0.11 2/17/23SM21-23 6200B11,3,5-Trimethylbenzene ND 20 2/17/23 21:17 EEHg/L1.5 2/17/23SM21-23 6200B1Vinyl Acetate ND 0.50 2/17/23 21:17 EEHg/L0.21 2/17/23SM21-23 6200B1Vinyl Chloride 4.5 1.0 2/17/23 21:17 EEHg/L0.46 2/17/23SM21-23 6200B1m+p Xylene 0.46 0.50 2/17/23 21:17 EEHg/L0.23 2/17/23SM21-23 6200B1Jo-Xylene Surrogates % Recovery Recovery Limits Flag/Qual 1,2-Dichloroethane-d4 93.1 2/17/23 21:1770-130 Toluene-d8 100 2/17/23 21:1770-130 4-Bromofluorobenzene 97.4 2/17/23 21:1770-130 Page 11 of 24 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 2/16/2023 Work Order: 23B1834Sample Description:Project Location: Lumberton, NY Sample ID: 23B1834-04 Field Sample #: TB Sample Matrix: Ground Water Sampled: 2/14/2023 00:00 [TOC_2]23B1834-04[TOC] AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS ND 50 2/17/23 16:44 EEHg/L2.0 2/17/23SM21-23 6200B1Acetone ND 0.50 2/17/23 16:44 EEHg/L0.20 2/17/23SM21-23 6200B1Benzene ND 0.50 2/17/23 16:44 EEHg/L0.15 2/17/23SM21-23 6200B1Bromobenzene ND 0.50 2/17/23 16:44 EEHg/L0.31 2/17/23SM21-23 6200B1Bromochloromethane ND 0.50 2/17/23 16:44 EEHg/L0.18 2/17/23SM21-23 6200B1Bromodichloromethane ND 0.50 2/17/23 16:44 EEHg/L0.38 2/17/23SM21-23 6200B1Bromoform ND 2.0 2/17/23 16:44 EEHg/L1.5 2/17/23SM21-23 6200B1Bromomethane ND 5.0 2/17/23 16:44 EEHg/L1.6 2/17/23SM21-23 6200B12-Butanone (MEK) ND 0.50 2/17/23 16:44 EEHg/L0.15 2/17/23SM21-23 6200B1n-Butylbenzene ND 0.50 2/17/23 16:44 EEHg/L0.11 2/17/23SM21-23 6200B1sec-Butylbenzene ND 0.50 2/17/23 16:44 EEHg/L0.13 2/17/23SM21-23 6200B1tert-Butylbenzene ND 0.50 2/17/23 16:44 EEHg/L0.16 2/17/23SM21-23 6200B1Carbon Tetrachloride ND 0.50 2/17/23 16:44 EEHg/L0.11 2/17/23SM21-23 6200B1Chlorobenzene ND 50 2/17/23 16:44 EEHg/L26 2/17/23SM21-23 6200B1Ethanol ND 0.50 2/17/23 16:44 EEHg/L0.22 2/17/23SM21-23 6200B1Chlorodibromomethane ND 0.50 2/17/23 16:44 EEHg/L0.32 2/17/23SM21-23 6200B1Chloroethane 0.58 0.50 2/17/23 16:44 EEHg/L0.17 2/17/23SM21-23 6200B1Chloroform ND 0.60 2/17/23 16:44 EEHg/L0.52 2/17/23SM21-23 6200B1Chloromethane ND 0.50 2/17/23 16:44 EEHg/L0.11 2/17/23SM21-23 6200B12-Chlorotoluene ND 0.50 2/17/23 16:44 EEHg/L0.12 2/17/23SM21-23 6200B14-Chlorotoluene ND 0.50 2/17/23 16:44 EEHg/L0.17 2/17/23SM21-23 6200B11,2-Dibromoethane (EDB) ND 0.50 2/17/23 16:44 EEHg/L0.12 2/17/23SM21-23 6200B11,2-Dichlorobenzene ND 0.50 2/17/23 16:44 EEHg/L0.12 2/17/23SM21-23 6200B11,3-Dichlorobenzene ND 0.50 2/17/23 16:44 EEHg/L0.13 2/17/23SM21-23 6200B11,4-Dichlorobenzene ND 0.50 2/17/23 16:44 EEHg/L0.19 2/17/23SM21-23 6200B1Dichlorodifluoromethane (Freon 12) ND 0.50 2/17/23 16:44 EEHg/L0.14 2/17/23SM21-23 6200B11,1-Dichloroethane ND 0.50 2/17/23 16:44 EEHg/L0.31 2/17/23SM21-23 6200B11,2-Dichloroethane ND 0.50 2/17/23 16:44 EEHg/L0.14 2/17/23SM21-23 6200B11,1-Dichloroethylene ND 0.50 2/17/23 16:44 EEHg/L0.15 2/17/23SM21-23 6200B1cis-1,2-Dichloroethylene ND 0.50 2/17/23 16:44 EEHg/L0.17 2/17/23SM21-23 6200B1trans-1,2-Dichloroethylene ND 0.50 2/17/23 16:44 EEHg/L0.18 2/17/23SM21-23 6200B11,2-Dichloropropane ND 0.50 2/17/23 16:44 EEHg/L0.13 2/17/23SM21-23 6200B11,3-Dichloropropane ND 0.50 2/17/23 16:44 EEHg/L0.33 2/17/23SM21-23 6200B12,2-Dichloropropane ND 0.50 2/17/23 16:44 EEHg/L0.15 2/17/23SM21-23 6200B11,1-Dichloropropene ND 0.50 2/17/23 16:44 EEHg/L0.16 2/17/23SM21-23 6200B1cis-1,3-Dichloropropene ND 0.50 2/17/23 16:44 EEHg/L0.17 2/17/23SM21-23 6200B1trans-1,3-Dichloropropene ND 0.50 2/17/23 16:44 EEHg/L0.13 2/17/23SM21-23 6200B1Diisopropyl Ether (DIPE) ND 0.50 2/17/23 16:44 EEHg/L0.21 2/17/23SM21-23 6200B1Ethylbenzene ND 5.0 2/17/23 16:44 EEHg/L1.1 2/17/23SM21-23 6200B12-Hexanone (MBK) ND 0.50 2/17/23 16:44 EEHg/L0.11 2/17/23SM21-23 6200B1Isopropylbenzene (Cumene) ND 0.50 2/17/23 16:44 EEHg/L0.097 2/17/23SM21-23 6200B1p-Isopropyltoluene (p-Cymene) ND 0.50 2/17/23 16:44 EEHg/L0.17 2/17/23SM21-23 6200B1Methyl tert-Butyl Ether (MTBE) ND 5.0 2/17/23 16:44 EEHg/L0.23 2/17/23SM21-23 6200B1Methylene Chloride ND 5.0 2/17/23 16:44 EEHg/L1.3 2/17/23SM21-23 6200B14-Methyl-2-pentanone (MIBK) Page 12 of 24 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Date Received: 2/16/2023 Work Order: 23B1834Sample Description:Project Location: Lumberton, NY Sample ID: 23B1834-04 Field Sample #: TB Sample Matrix: Ground Water Sampled: 2/14/2023 00:00 AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time DL Units Date PreparedMethod Volatile Organic Compounds by GC/MS ND 0.50 2/17/23 16:44 EEHg/L0.24 2/17/23SM21-23 6200B1Naphthalene ND 0.50 2/17/23 16:44 EEHg/L0.086 2/17/23SM21-23 6200B1n-Propylbenzene ND 0.50 2/17/23 16:44 EEHg/L0.11 2/17/23SM21-23 6200B1Styrene ND 0.50 2/17/23 16:44 EEHg/L0.13 2/17/23SM21-23 6200B11,1,2,2-Tetrachloroethane ND 0.50 2/17/23 16:44 EEHg/L0.19 2/17/23SM21-23 6200B1Tetrachloroethylene ND 0.50 2/17/23 16:44 EEHg/L0.22 2/17/23SM21-23 6200B1Toluene ND 1.0 2/17/23 16:44 EEHg/L0.30 2/17/23SM21-23 6200B11,2,3-Trichlorobenzene ND 1.0 2/17/23 16:44 EEHg/L0.25 2/17/23SM21-23 6200B11,2,4-Trichlorobenzene ND 0.50 2/17/23 16:44 EEHg/L0.17 2/17/23SM21-23 6200B11,1,1-Trichloroethane ND 0.50 2/17/23 16:44 EEHg/L0.18 2/17/23SM21-23 6200B11,1,2-Trichloroethane ND 0.50 2/17/23 16:44 EEHg/L0.19 2/17/23SM21-23 6200B1Trichloroethylene ND 0.50 2/17/23 16:44 EEHg/L0.18 2/17/23SM21-23 6200B1Trichlorofluoromethane (Freon 11) ND 0.50 2/17/23 16:44 EEHg/L0.28 2/17/23SM21-23 6200B11,2,3-Trichloropropane ND 0.50 2/17/23 16:44 EEHg/L0.20 2/17/23SM21-23 6200B11,2,4-Trimethylbenzene ND 0.50 2/17/23 16:44 EEHg/L0.11 2/17/23SM21-23 6200B11,3,5-Trimethylbenzene ND 20 2/17/23 16:44 EEHg/L1.5 2/17/23SM21-23 6200B1Vinyl Acetate ND 0.50 2/17/23 16:44 EEHg/L0.21 2/17/23SM21-23 6200B1Vinyl Chloride ND 1.0 2/17/23 16:44 EEHg/L0.46 2/17/23SM21-23 6200B1m+p Xylene ND 0.50 2/17/23 16:44 EEHg/L0.23 2/17/23SM21-23 6200B1o-Xylene Surrogates % Recovery Recovery Limits Flag/Qual 1,2-Dichloroethane-d4 93.1 2/17/23 16:4470-130 Toluene-d8 99.6 2/17/23 16:4470-130 4-Bromofluorobenzene 97.6 2/17/23 16:4470-130 Page 13 of 24 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Sample Extraction Data Prep Method: SW-846 5030B-SM21-23 6200B Lab Number [Field ID]Batch DateInitial [mL]Final [mL] B331875 02/17/235 5.0023B1834-01 [MW-01] B331875 02/17/235 5.0023B1834-02 [MW-02] B331875 02/17/235 5.0023B1834-03 [B-3] B331875 02/17/235 5.0023B1834-04 [TB] [TOC_1]Sample Preparation Information[TOC] Page 14 of 24 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control QUALITY CONTROL [TOC_2]Volatile Organic Compounds by GC/MS[TOC] Batch B331875 - SW-846 5030B [TOC_3]B331875[TOC] Blank (B331875-BLK1) Prepared & Analyzed: 02/17/23 Acetone g/L50ND Benzene g/L0.50ND Bromobenzene g/L0.50ND Bromochloromethane g/L0.50ND Bromodichloromethane g/L0.50ND Bromoform g/L0.50ND Bromomethane g/L2.0ND 2-Butanone (MEK)g/L5.0ND n-Butylbenzene g/L0.50ND sec-Butylbenzene g/L0.50ND tert-Butylbenzene g/L0.50ND Carbon Tetrachloride g/L0.50ND Chlorobenzene g/L0.50ND Ethanol g/L50ND Chlorodibromomethane g/L0.50ND Chloroethane g/L0.50ND Chloroform g/L0.50ND Chloromethane g/L0.60ND 2-Chlorotoluene g/L0.50ND 4-Chlorotoluene g/L0.50ND 1,2-Dibromoethane (EDB)g/L0.50ND 1,2-Dichlorobenzene g/L0.50ND 1,3-Dichlorobenzene g/L0.50ND 1,4-Dichlorobenzene g/L0.50ND Dichlorodifluoromethane (Freon 12)g/L0.50ND 1,1-Dichloroethane g/L0.50ND 1,2-Dichloroethane g/L0.50ND 1,1-Dichloroethylene g/L0.50ND cis-1,2-Dichloroethylene g/L0.50ND trans-1,2-Dichloroethylene g/L0.50ND 1,2-Dichloropropane g/L0.50ND 1,3-Dichloropropane g/L0.50ND 2,2-Dichloropropane g/L0.50ND 1,1-Dichloropropene g/L0.50ND cis-1,3-Dichloropropene g/L0.50ND trans-1,3-Dichloropropene g/L0.50ND Diisopropyl Ether (DIPE)g/L0.50ND Ethylbenzene g/L0.50ND 2-Hexanone (MBK)g/L5.0ND Isopropylbenzene (Cumene)g/L0.50ND p-Isopropyltoluene (p-Cymene)g/L0.50ND Methyl tert-Butyl Ether (MTBE)g/L0.50ND Methylene Chloride g/L5.0ND 4-Methyl-2-pentanone (MIBK)g/L5.0ND Naphthalene g/L0.50ND n-Propylbenzene g/L0.50ND Styrene g/L0.50ND 1,1,2,2-Tetrachloroethane g/L0.50ND Tetrachloroethylene g/L0.50ND Toluene g/L0.50ND 1,2,3-Trichlorobenzene g/L1.0ND 1,2,4-Trichlorobenzene g/L0.50ND [TOC_1]QC Data[TOC] Page 15 of 24 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control QUALITY CONTROL Batch B331875 - SW-846 5030B Blank (B331875-BLK1) Prepared & Analyzed: 02/17/23 1,1,1-Trichloroethane g/L0.50ND 1,1,2-Trichloroethane g/L0.50ND Trichloroethylene g/L0.50ND Trichlorofluoromethane (Freon 11)g/L0.50ND 1,2,3-Trichloropropane g/L0.50ND 1,2,4-Trimethylbenzene g/L0.50ND 1,3,5-Trimethylbenzene g/L0.50ND Vinyl Acetate g/L20ND Vinyl Chloride g/L0.50ND m+p Xylene g/L1.0ND o-Xylene g/L0.50ND g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 91.222.8 g/L 25.0 70-130Surrogate: Toluene-d8 99.224.8 g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 98.524.6 LCS (B331875-BS1) Prepared & Analyzed: 02/17/23 Acetone g/L50 100 70-13080.180.1 Benzene g/L0.50 10.0 70-13099.79.97 Bromobenzene g/L0.50 10.0 70-13092.19.21 Bromochloromethane g/L0.50 10.0 70-13099.69.96 Bromodichloromethane g/L0.50 10.0 70-13089.28.92 Bromoform g/L0.50 10.0 70-13079.57.95 Bromomethane g/L2.0 10.0 60-14011311.3 2-Butanone (MEK)g/L5.0 100 70-13095.595.5 n-Butylbenzene g/L0.50 10.0 70-13090.79.07 sec-Butylbenzene g/L0.50 10.0 70-13091.59.15 tert-Butylbenzene g/L0.50 10.0 70-13090.99.09 Carbon Tetrachloride g/L0.50 10.0 70-13078.77.87 Chlorobenzene g/L0.50 10.0 70-13096.49.64 Ethanol g/L50 100 70-130124124 Chlorodibromomethane g/L0.50 10.0 70-13080.88.08 Chloroethane g/L0.50 10.0 60-14078.87.88 Chloroform g/L0.50 10.0 70-13090.49.04 Chloromethane g/L0.60 10.0 60-14095.59.55 2-Chlorotoluene g/L0.50 10.0 70-13093.19.31 4-Chlorotoluene g/L0.50 10.0 70-13093.09.30 1,2-Dibromoethane (EDB)g/L0.50 10.0 70-13087.88.78 1,2-Dichlorobenzene g/L0.50 10.0 70-13092.39.23 1,3-Dichlorobenzene g/L0.50 10.0 70-13094.89.48 1,4-Dichlorobenzene g/L0.50 10.0 70-13092.19.21 Dichlorodifluoromethane (Freon 12)g/L0.50 10.0 60-14094.99.49 1,1-Dichloroethane g/L0.50 10.0 70-13091.89.18 1,2-Dichloroethane g/L0.50 10.0 70-13083.38.33 1,1-Dichloroethylene g/L0.50 10.0 70-13086.28.62 cis-1,2-Dichloroethylene g/L0.50 10.0 70-13090.99.09 trans-1,2-Dichloroethylene g/L0.50 10.0 70-13084.18.41 1,2-Dichloropropane g/L0.50 10.0 70-13095.99.59 1,3-Dichloropropane g/L0.50 10.0 70-13094.19.41 2,2-Dichloropropane g/L0.50 10.0 70-13080.08.00 1,1-Dichloropropene g/L0.50 10.0 70-13092.69.26 cis-1,3-Dichloropropene g/L0.50 10.0 70-13087.68.76 trans-1,3-Dichloropropene g/L0.50 10.0 70-13077.27.72 Page 16 of 24 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control QUALITY CONTROL Batch B331875 - SW-846 5030B LCS (B331875-BS1) Prepared & Analyzed: 02/17/23 Diisopropyl Ether (DIPE)g/L0.50 10.0 70-13098.89.88 Ethylbenzene g/L0.50 10.0 70-13096.59.65 2-Hexanone (MBK)g/L5.0 100 70-13081.681.6 Isopropylbenzene (Cumene)g/L0.50 10.0 70-13095.89.58 p-Isopropyltoluene (p-Cymene)g/L0.50 10.0 70-13089.48.94 Methyl tert-Butyl Ether (MTBE)g/L0.50 10.0 70-13083.38.33 Methylene Chloride g/L5.0 10.0 70-13083.88.38 4-Methyl-2-pentanone (MIBK)g/L5.0 100 70-13082.382.3 Naphthalene g/L0.50 10.0 70-13077.37.73 n-Propylbenzene g/L0.50 10.0 70-13094.79.47 Styrene g/L0.50 10.0 70-13096.79.67 1,1,2,2-Tetrachloroethane g/L0.50 10.0 70-13087.18.71 Tetrachloroethylene g/L0.50 10.0 70-13092.59.25 Toluene g/L0.50 10.0 70-13091.29.12 1,2,3-Trichlorobenzene g/L1.0 10.0 70-13086.68.66 1,2,4-Trichlorobenzene g/L0.50 10.0 70-13089.98.99 1,1,1-Trichloroethane g/L0.50 10.0 70-13086.08.60 1,1,2-Trichloroethane g/L0.50 10.0 70-13089.38.93 Trichloroethylene g/L0.50 10.0 70-13095.59.55 Trichlorofluoromethane (Freon 11)g/L0.50 10.0 70-13082.78.27 1,2,3-Trichloropropane g/L0.50 10.0 70-13099.49.94 1,2,4-Trimethylbenzene g/L0.50 10.0 70-13098.29.82 1,3,5-Trimethylbenzene g/L0.50 10.0 70-13092.99.29 Vinyl Acetate g/L20 100 70-13075.175.1 Vinyl Chloride g/L0.50 10.0 60-14010010.0 m+p Xylene g/L1.0 20.0 70-13094.919.0 o-Xylene g/L0.50 10.0 70-13093.39.33 g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 90.422.6 g/L 25.0 70-130Surrogate: Toluene-d8 99.925.0 g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 10025.1 LCS Dup (B331875-BSD1) Prepared & Analyzed: 02/17/23 Acetone g/L50 100 2570-13080.6 0.67280.6 Benzene g/L0.50 10.0 2570-13093.2 6.749.32 Bromobenzene g/L0.50 10.0 2570-13088.3 4.218.83 Bromochloromethane g/L0.50 10.0 2570-13093.8 6.009.38 Bromodichloromethane g/L0.50 10.0 2570-13082.0 8.418.20 Bromoform g/L0.50 10.0 2570-13073.7 7.577.37 Bromomethane g/L2.0 10.0 2560-140102 9.3910.2 2-Butanone (MEK)g/L5.0 100 2570-13095.3 0.26295.3 n-Butylbenzene g/L0.50 10.0 2570-13087.3 3.828.73 sec-Butylbenzene g/L0.50 10.0 2570-13088.3 3.568.83 tert-Butylbenzene g/L0.50 10.0 2570-13089.2 1.898.92 Carbon Tetrachloride g/L0.50 10.0 2570-13074.3 5.757.43 Chlorobenzene g/L0.50 10.0 2570-13089.4 7.538.94 Ethanol g/L50 100 2570-130108 13.7108 Chlorodibromomethane g/L0.50 10.0 2570-13075.4 6.917.54 Chloroethane g/L0.50 10.0 2560-14075.8 3.887.58 Chloroform g/L0.50 10.0 2570-13084.7 6.518.47 Chloromethane g/L0.60 10.0 2560-14092.6 3.089.26 2-Chlorotoluene g/L0.50 10.0 2570-13086.5 7.358.65 4-Chlorotoluene g/L0.50 10.0 2570-13089.5 3.848.95 Page 17 of 24 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control QUALITY CONTROL Batch B331875 - SW-846 5030B LCS Dup (B331875-BSD1) Prepared & Analyzed: 02/17/23 1,2-Dibromoethane (EDB)g/L0.50 10.0 2570-13082.4 6.358.24 1,2-Dichlorobenzene g/L0.50 10.0 2570-13091.3 1.099.13 1,3-Dichlorobenzene g/L0.50 10.0 2570-13092.8 2.139.28 1,4-Dichlorobenzene g/L0.50 10.0 2570-13089.0 3.428.90 Dichlorodifluoromethane (Freon 12)g/L0.50 10.0 2560-14091.8 3.329.18 1,1-Dichloroethane g/L0.50 10.0 2570-13086.7 5.718.67 1,2-Dichloroethane g/L0.50 10.0 2570-13080.2 3.798.02 1,1-Dichloroethylene g/L0.50 10.0 2570-13081.6 5.488.16 cis-1,2-Dichloroethylene g/L0.50 10.0 2570-13086.3 5.198.63 trans-1,2-Dichloroethylene g/L0.50 10.0 2570-13080.2 4.758.02 1,2-Dichloropropane g/L0.50 10.0 2570-13091.6 4.599.16 1,3-Dichloropropane g/L0.50 10.0 2570-13086.8 8.078.68 2,2-Dichloropropane g/L0.50 10.0 2570-13073.3 8.747.33 1,1-Dichloropropene g/L0.50 10.0 2570-13089.6 3.298.96 cis-1,3-Dichloropropene g/L0.50 10.0 2570-13084.2 3.968.42 trans-1,3-Dichloropropene g/L0.50 10.0 2570-13078.1 1.167.81 Diisopropyl Ether (DIPE)g/L0.50 10.0 2570-13093.9 5.099.39 Ethylbenzene g/L0.50 10.0 2570-13091.3 5.549.13 2-Hexanone (MBK)g/L5.0 100 2570-13085.4 4.4885.4 Isopropylbenzene (Cumene)g/L0.50 10.0 2570-13088.9 7.478.89 p-Isopropyltoluene (p-Cymene)g/L0.50 10.0 2570-13086.1 3.768.61 Methyl tert-Butyl Ether (MTBE)g/L0.50 10.0 2570-13082.2 1.338.22 Methylene Chloride g/L5.0 10.0 2570-13080.6 3.898.06 4-Methyl-2-pentanone (MIBK)g/L5.0 100 2570-13082.3 0.012282.3 Naphthalene g/L0.50 10.0 2570-13081.5 5.298.15 n-Propylbenzene g/L0.50 10.0 2570-13088.6 6.668.86 Styrene g/L0.50 10.0 2570-13089.6 7.628.96 1,1,2,2-Tetrachloroethane g/L0.50 10.0 2570-13083.1 4.708.31 Tetrachloroethylene g/L0.50 10.0 2570-13088.3 4.658.83 Toluene g/L0.50 10.0 2570-13087.7 3.918.77 1,2,3-Trichlorobenzene g/L1.0 10.0 2570-13088.5 2.178.85 1,2,4-Trichlorobenzene g/L0.50 10.0 2570-13092.6 2.969.26 1,1,1-Trichloroethane g/L0.50 10.0 2570-13080.7 6.368.07 1,1,2-Trichloroethane g/L0.50 10.0 2570-13089.2 0.1128.92 Trichloroethylene g/L0.50 10.0 2570-13091.9 3.849.19 Trichlorofluoromethane (Freon 11)g/L0.50 10.0 2570-13077.2 6.887.72 1,2,3-Trichloropropane g/L0.50 10.0 2570-13097.1 2.349.71 1,2,4-Trimethylbenzene g/L0.50 10.0 2570-13096.0 2.279.60 1,3,5-Trimethylbenzene g/L0.50 10.0 2570-13088.1 5.308.81 Vinyl Acetate g/L20 100 2570-13074.6 0.76274.6 Vinyl Chloride g/L0.50 10.0 2560-14095.1 5.529.51 m+p Xylene g/L1.0 20.0 2570-13088.2 7.3217.6 o-Xylene g/L0.50 10.0 2570-13087.1 6.878.71 g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 91.222.8 g/L 25.0 70-130Surrogate: Toluene-d8 99.224.8 g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 97.724.4 Page 18 of 24 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 *QC result is outside of established limits. Wide recovery limits established for difficult compound. Wide RPD limits established for difficult compound. #Data exceeded client recommended or regulatory level Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the calculation which have not been rounded. No results have been blank subtracted unless specified in the case narrative section. FLAG/QUALIFIER SUMMARY Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated concentration (CLP J-Flag). J [TOC_1]Flag/Qualifier Summary[TOC] Page 19 of 24 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report SM21-23 6200B in Water NCAcetone NCBenzene NCBromobenzene NCBromochloromethane NCBromodichloromethane NCBromoform NCBromomethane NC2-Butanone (MEK) NCn-Butylbenzene NCsec-Butylbenzene NCtert-Butylbenzene NCCarbon Tetrachloride NCChlorobenzene NCEthanol NCChlorodibromomethane NCChloroethane NCChloroform NCChloromethane NC2-Chlorotoluene NC4-Chlorotoluene NC1,2-Dibromoethane (EDB) NC1,2-Dichlorobenzene NC1,3-Dichlorobenzene NC1,4-Dichlorobenzene NCDichlorodifluoromethane (Freon 12) NC1,1-Dichloroethane NC1,2-Dichloroethane NC1,1-Dichloroethylene NCcis-1,2-Dichloroethylene NCtrans-1,2-Dichloroethylene NC1,2-Dichloropropane NC1,3-Dichloropropane NC2,2-Dichloropropane NC1,1-Dichloropropene NCcis-1,3-Dichloropropene NCtrans-1,3-Dichloropropene NCDiisopropyl Ether (DIPE) NCEthylbenzene NC2-Hexanone (MBK) NCIsopropylbenzene (Cumene) NCp-Isopropyltoluene (p-Cymene) NCMethyl tert-Butyl Ether (MTBE) NCMethylene Chloride NC4-Methyl-2-pentanone (MIBK) NCNaphthalene NCn-Propylbenzene NCStyrene [TOC_1]Certifications[TOC] Page 20 of 24 Table of Contents 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report SM21-23 6200B in Water NC1,1,2,2-Tetrachloroethane NCTetrachloroethylene NCToluene NC1,2,3-Trichlorobenzene NC1,2,4-Trichlorobenzene NC1,1,1-Trichloroethane NC1,1,2-Trichloroethane NCTrichloroethylene NCTrichlorofluoromethane (Freon 11) NC1,2,3-Trichloropropane NC1,2,4-Trimethylbenzene NC1,3,5-Trimethylbenzene NCVinyl Acetate NCVinyl Chloride NCm+p Xylene NCo-Xylene The CON-TEST Environmental Laboratory operates under the following certifications and accreditations: Code Description Number Expires 652North Carolina Div. of Water QualityNC 12/31/2023 Page 21 of 24 Table of Contents Page 22 of 24 Table of Contents Page 23 of 24 Table of Contents Page 24 of 24 Table of Contents