22063_Liggett Myers_Final Grade Rpt_20230501

"_:V\_1_11
0 Mid Atlantic
May 1, 2023
Ms. Holly Samaha-Smith, PE
NC Brownfields Program
NC Department of Environmental Quality
Division of Waste Management
Mail Service Center 1646
Raleigh, North Carolina 27699-1646
Subject: LETTER REPORT OF FINAL GRADE SOIL SAMPLING RESULTS
LIGGETT & MYERS TOBACCO CO.
311 LIGGETT STREET, 506 & 508 FERNWAY AVENUE
DURHAM, DURHAM COUNTY, NORTH CAROLINA
BROWNFIELDS PROJECT NO.: 22063-18-032
MID -ATLANTIC PE LICENSE: F-0967
MID -ATLANTIC JOB NO. R3225.02
Dear Ms. Samaha-Smith:
409 Rage rs View Court
Raleigh, NC 27610
office 919.250.9918
facsimile 919.250.9950
MAAONLINE.COM
Mid -Atlantic Associates, Inc. (Mid -Atlantic) is pleased to present this letter report summarizing
results of the recent soil sampling activities conducted in association with the above -
referenced site.
INTRODUCTION
The Liggett & Myers Tobacco Co. site consists of four parcels totaling approximately 2.79
acres and is located along Liggett Street, between West Corporation Street and Fernway
Avenue, Durham, North Carolina (Attachment A, Drawing 1). Historically these lots have
been used for residential purposes. In accordance with the February 27, 2020 EMP, final
grade sampling is required for the portion of the site located on 506 and 508 Fernway Avenue
(Attachment A, Drawing 2). The parcels at 506 and 508 Fernway Avenue are adjoining and
are approximately 0.21 acres (9,370 ft2). As a part of the redevelopment project, these parcels
are open green space used primarily as a dog park. Approximately 2,612 ft2 of the site is
covered with concrete and 3,393 ft2 is covered with synthetic turf (within the dog park fence).
Natural turf (grasses) covers 2,337 ft2 and 1,028 ft2 of the area is covered with wood mulch
pathways. Thus, there is approximately 3,365 ft2 of area where exposure to surface soils could
occur.
The requirement for the final grade sampling was established with the Brownfields Program
(now Section) during the development of the EMP. The objective of this assessment is to
— EXPERIENCED CUSTOMER FOCUSED INNOVATIVE —

Letter Report of Final Grade Soil Sampling Results May 1, 2023
Liggett & Myers Tobacco Co. Page 2
Durham, North Carolina
evaluate final grade soil conditions as required by the EMP. This letter report discusses
sampling activities conducted at the Liggett & Myers Tobacco Co. property in accordance
with the Brownfields Redevelopment Section approved Work Plan (dated March 16, 2023).
SUMMARY OF FIELD ACTIVITIES
On April 5, 2023, Mid -Atlantic mobilized to the site to collect soil samples from the future dog
park location at 506 and 508 Fernway Avenue. The site was divided into two areas that
consist of the 3,365 ft2 area covered with grasses and wood mulch pathways and the 3,393
ft2 area covered with synthetic turf. Ten aliquots, five from the area of the site to be covered
with grasses and wood mulch pathways (Dog Park-1) and five from the area of the site to be
covered with synthetic turf (Dog Park-2), were collected from the site using new nitrile gloves
and a decontaminated hand auger. Each aliquot was collected from a depth of zero to six
inches beneath land surface. Each aliquot was screened using a MiniRAE 3000
photoionization detector (PID) for the presence of volatile organic compounds (VOCs). Visual
and olfactory observations made by Mid -Atlantic personnel did not detect evidence of VOCs
in the soils. Mid -Atlantic observed an elevated PID reading at aliquot DP-4 (25.2 ppm) at a
depth of zero to six inches. The soil boring logs, including PID readings, for the ten aliquots
are provided as Attachment B. The field notes from these sampling activities are included
as Attachment C.
One soil sample was collected from each area for a total of two samples (plus one duplicate).
Primary soil samples Dog Park-1 and Dog Park-2 and one duplicate soil sample (Dog Park-
Dup) were collected for laboratory analysis of volatile organic compounds (VOCs), semi-
VOCs (SVOCs), and eight Resource Conservation and Recovery Act (RCRA) metals. For
each area, the VOC sample was collected from one of the aliquots at a depth of six to twelve
inches below land surface. This VOC sample was collected directly from the decontaminated
hand auger bucket, while the SVOC and RCRA metals samples were comprised of soil from
the five aliquots composited in the field.
Upon collection, the samples were placed into laboratory -prepared sampling containers,
packed into an ice -filled cooler, and submitted under proper chain -of -custody control to
Waypoint Analytical of Charlotte, North Carolina (NC Certification Number 402) for laboratory
analysis of VOCs by Method 8260, SVOCs by Method 8270, and RCRA metals by Method
6020/7471. Results from laboratory analysis of the soil samples are summarized in a table
provided as Attachment D. The laboratory analytical report and chain -of -custody record are
provided as Attachment E.
SUMMARY OF LABORATORY ANALYTICAL RESULTS
Chemical constituents detected in the soil samples were compared to the North Carolina
Department of Environmental Quality (NCDEQ) Division of Waste Management (DWM)
Residential and Industrial/Commercial health -based Preliminary Soil Remediation Goals
(PSRGs; January 2023), as well as the Protection of Groundwater PSRGs. As summarized
in the provided data table (Attachment D), arsenic was detected in each of the samples at
ft Mid Atlantic

Getter Report of Final Grade Soil Sampling Results
Liggett & Myers Tobacco Co.
Durham, North Carotina
May 1, 2023
Page 3
concentrations (1.86 milligrams per kilogram (mg/kg) to 2.91 mg/kg) exceeding its residential
PSRG. These concentrations are consistent with arsenic concentrations naturally occurring
in North Carolina soils. No other constituents were detected at concentrations exceeding
PSRGs. The compounds detected in the duplicate sample (Dog Park-Dup) taken with sample
Dog-Park-2 are comparable to the compounds detected in Dog Park-2. The concentrations
of the detected compounds were also comparable. The greatest variation occurred in the
concentrations of detected barium (61.7 mg/kg in Dog Park-2 and 74.3 mg/kg in Dog Park-
Dup). Evaluation of these data suggest that they are representative of site conditions.
The cumulative risk was calculated by entering the maximum concentrations of all
compounds detected at the site into the NCDEQ Risk Calculator (January 2023; see
Attachment F). The DWM allows a maximum cancer risk sum for all carcinogens of 1,0E-04
and a maximum cumulative hazard index of 1.0 for all non -carcinogens. The risk calculations
for the soil direct contact residential pathway resulted in maximum cancer risk sum of 4.3E-
06 and a non -cancer hazard index of 1.1 E-01. The risk calculations for the soil direct contact
non-residential pathway resulted in maximum cancer risk sum of 9.7E-07 and a non -cancer
hazard index of 8.2E-03. The soil direct contact pathway for both residential and non-
residential scenarios did not exceed the established maximum cancer sum and the non -
cancer hazard index. Therefore, site conditions, under both residential and non-residential
scenarios, do not pose unacceptable risk.
CONCLUSIONS
The results of the final grade sampling indicate that use of the site as a dog park poses no
unacceptable risk.
Sincerely,
MID -ATLANTIC ASWQLTES, INC.
CA A 01 A'�%
■
l �
Da 14. Nielsen;{
Pri�i cipal Engineer.,���� 1
,I
Attachments: Figures
Soil Boring Logs
Field Notes
Madeline ook
Staff Scientist
Table
Laboratory Analytical Report and Chain -of -Custody Record
Risk Calculations
ft Mid Atlantic

ATTACHMENT A
FIGURES
10 Mid Atlantic

a
REFERENCES:
1. SOUTHWEST DURHAM, INC & NORTHWEST DURHAM, NC DIGITAL RASTER GRAPHIC, USGS.
SCANNED FROM 1:24,000-SCALE SOUTHWEST DURHAM, NC & NORTHWEST DURHAM, NC
SCALE: :6,000
TOPOGRAPHIC MAPS, PUBLISHED 2022, USGS.
2. INSET MAP DIGITAL DATA FROM 2002 NATIONAL TRANSPORTATION ATLAS,
Feet
BUREAU OF TRANSPORTATION STATISTICS, WASHINGTON, D.C.
3. PROPERTY BOUNDARY DATA FROM DURHAM COUNTY GIS. 0
250 500
1,000
DRAWN
DATE:
BY: KRC
APRIL 2023
Mid AtiantlC
TOPOGRAPHIC SITE MAP
LIGGETT & FERNWAY PARCELS
DRAFT
CHECK: DHN
JOB NO:
R3225.02
Engineering 8 Enviranmen'al5ok�cians
DURHAM, NORTH CAROLINA
ENG.
GIS NO:
CHECK:
03G-R3225.02-1
APPROVAL: DHN
DWG NO: 1

N
�I
n
LEGEND
Subject Property
•
Soil Aliquot Location
Proposed Paved Area
®
Proposed Extent of Synthetic Turf
Parcel Boundaries
1
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L
61
rnwa, Avenue
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REFERENCES:
1. AERIAL IMAGERY AND PROPERTY LINES FROM NC ONEMAP
2. MATERIALS AND FURNISHINGS PLAN FROM STEWART ENGINEERING, INC
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NC Center for Geographic
Information.&,Analysis
u r,
1 inch equals 20 feet
0 20 40 60
Feet
DRAWN DATE:
BY: KRC APRIL 2023
SAMPLE LOCATION MAP DRAFT JOB NO:
Mid Atlantic LIGGETT & MYERS TOBACCO COMPANY CHECK: DHN R3225.02
Atlantic Engineering & Environmenr.al Solunnns LIGETT STREET AND FERNWAY AVENUE ENG. GIS NO:
DURHAM, NORTH CAROLINA CHECK: 03G-R3225.02-2
APPROVAL: DHN DRAWING NO: 2

ATTACHMENT B
SOIL BORING LOGS
10 Mid Atlantic

LOG OF BORING: DP-1
Court
Raleigh, NC
Mid Atlantic 409Rogers°i7610
ft
Ph: 919-250-991
-998
Engineering & Envlrenmenul Solutions
Page: I of 10
Site Name: Liggett & Myers Tobacco Co.
Boring Method: Hand Auger
Project Number: R3225.02
Monitoring Equipment: PID
Location: Durham, NC
Total Boring Depth (ft): 1
Date: 4/5/2023
Field Staff: Maddie Hook
a
g
rn
04
en
rn
SOIL DESCRIPTION (color, texture, moisture, etc.)
w
�
W
A
a
0.4
medium orange, micaceous clay
0.5
0.5
0.1
dark brown,
micaceous, silty clay
1
1
COMM in - indicates inches
ft - indicates depth in feet
ppm - indicates parts per million
ft BLS - indicates feet below land surface
PID - Photo Ionization Detector

LOG OF BORING: DP-2
Court
Raleigh, NC
Mid Atlantic 409Rogers°i7610
-998
Engineering & Envlrenmenul Solutions Ph: 919-250-991
Page: 2 of 10
Site Name: Liggett & Myers Tobacco Co.
Boring Method: Hand Auger
Project Number: R3225.02
Monitoring Equipment: PID
Location: Durham, NC
Total Boring Depth (ft): 1
Date: 4/5/2023
Field Staff: Maddie Hook
a
g
rn
04
en
rn
SOIL DESCRIPTION (color, texture, moisture, etc.)
w
�
W
A
a
0.0
light orange, sandy silt
0.5
0.5
0.0
medium orange/brown, sandy silt
1
1
COMM in - indicates inches
ft - indicates depth in feet
ppm - indicates parts per million
ft BLS - indicates feet below land surface
PID - Photo Ionization Detector

LOG OF BORING: DP-3
Court
Raleigh, NC
Mid Atlantic 409Rogers°i7610
-998
Engineering & Envlrenmenul Solutions Ph: 919-250-991
Page: 3 of 10
Site Name: Liggett & Myers Tobacco Co.
Boring Method: Hand Auger
Project Number: R3225.02
Monitoring Equipment: PID
Location: Durham, NC
Total Boring Depth (ft): 1
Date: 4/5/2023
Field Staff: Maddie Hook
a
g
rn
04
en
rn
SOIL DESCRIPTION (color, texture, moisture, etc.)
w
�
W
A
a
0.6
0.5
light orange,
sandy silt, micaceous
0.5
1.1
1
1
COMM in - indicates inches
ft - indicates depth in feet
ppm - indicates parts per million
ft BLS - indicates feet below land surface
PID - Photo Ionization Detector

LOG OF BORING: DP-4
Court
Raleigh, NC
Mid Atlantic 409Rogers°i7610
-998
Engineering & Envlrenmentel Solutions Ph: 919-250-991
Page: 4 of 10
Site Name: Liggett & Myers Tobacco Co.
Boring Method: Hand Auger
Project Number: R3225.02
Monitoring Equipment: PID
Location: Durham, NC
Total Boring Depth (ft): 1
Date: 4/5/2023
Field Staff: Maddie Hook
a
g
rn
04
en
rn
SOIL DESCRIPTION (color, texture, moisture, etc.)
w
�
W
A
a
25.2
light brown, silty sand
0.5
0.5
*
1.8
light brown, sandy silt
1
1
COMM in - indicates inches
* - VOC grab sample collected from 0.5'-1' depth
ft - indicates depth in feet
ppm - indicates parts per million
ft BLS - indicates feet below land surface
PID - Photo Ionization Detector

LOG OF BORING: DP-5
Court
Raleigh, NC
Mid Atlantic 409Rogers°i7610
-998
Engineering & Envlrenmentel Solutions Ph: 919-250-991
Page: 5 of 10
Site Name: Liggett & Myers Tobacco Co.
Boring Method: Hand Auger
Project Number: R3225.02
Monitoring Equipment: PID
Location: Durham, NC
Total Boring Depth (ft): 1
Date: 4/5/2023
Field Staff: Maddie Hook
a
g
rn
04
en
rn
SOIL DESCRIPTION (color, texture, moisture, etc.)
w
�
W
A
a
0.1
0.5
dark orange/brown, silty clay
0.5
0.0
1
1
COMM in - indicates inches
ft - indicates depth in feet
ppm - indicates parts per million
ft BLS - indicates feet below land surface
PID - Photo Ionization Detector

LOG OF BORING: DP-6
Court
Raleigh, NC
Mid Atlantic 409Rogers°i7610
-998
Engineering & Envlrenmenul Solutions Ph: 919-250-991
Page: 6 of 10
Site Name: Liggett & Myers Tobacco Co.
Boring Method: Hand Auger
Project Number: R3225.02
Monitoring Equipment: PID
Location: Durham, NC
Total Boring Depth (ft): 1
Date: 4/5/2023
Field Staff: Maddie Hook
a
g
rn
04
en
rn
SOIL DESCRIPTION (color, texture, moisture, etc.)
w
�
W
A
a
0.1
0.5
medium brown, silty
clay, slightly micaceous
0.5
*
0.9
1
1
COMM in - indicates inches
* - VOC grab sample collected from 0.5'-1' depth
ft - indicates depth in feet
ppm - indicates parts per million
ft BLS - indicates feet below land surface
PID - Photo Ionization Detector

LOG OF BORING: DP-7
Court
Raleigh, NC
Mid Atlantic 409Rogers°i7610
-998
Engineering & Envlrenmenul Solutions Ph: 919-250-991
Page: % of 10
Site Name: Liggett & Myers Tobacco Co.
Boring Method: Hand Auger
Project Number: R3225.02
Monitoring Equipment: PID
Location: Durham, NC
Total Boring Depth (ft): 1
Date: 4/5/2023
Field Staff: Maddie Hook
a
g
rn
04
en
rn
SOIL DESCRIPTION (color, texture, moisture, etc.)
w
�
W
A
a
0.2
medium orange/brown, silty clay
0.5
0.5
0.2
medium orange, sandy silt, micaceous
1
1
COMM in - indicates inches
ft - indicates depth in feet
ppm - indicates parts per million
ft BLS - indicates feet below land surface
PID - Photo Ionization Detector

LOG OF BORING: DP-8
Court
Raleigh, NC
Mid Atlantic 409Rogers°i7610
-998
Engineering & Envlrenmenul Solutions Ph: 919-250-991
Page: 8 of 10
Site Name: Liggett & Myers Tobacco Co.
Boring Method: Hand Auger
Project Number: R3225.02
Monitoring Equipment: PID
Location: Durham, NC
Total Boring Depth (ft): 1
Date: 4/5/2023
Field Staff: Maddie Hook
a
g
rn
04
en
rn
SOIL DESCRIPTION (color, texture, moisture, etc.)
w
�
W
A
a
0.3
medium orange/brown, silty clay
0.5
0.5
0.2
medium orange/brown, silty clay, micaceous
1
1
COMM in - indicates inches
ft - indicates depth in feet
ppm - indicates parts per million
ft BLS - indicates feet below land surface
PID - Photo Ionization Detector

LOG OF BORING: DP-9
Court
Raleigh, NC
Mid Atlantic 409Rogers°i7610
ft
Ph: 919-250-991
-998
Engineering & Envlrenmenul Solutions
Page: 9 of 10
Site Name: Liggett & Myers Tobacco Co.
Boring Method: Hand Auger
Project Number: R3225.02
Monitoring Equipment: PID
Location: Durham, NC
Total Boring Depth (ft): 1
Date: 4/5/2023
Field Staff: Maddie Hook
a
g
rn
04
en
rn
SOIL DESCRIPTION (color, texture, moisture, etc.)
w
�
w
A
a
4.8
medium
brown, sandy silt
0.5
0.5
0.6
medium brown,
slightly sandy, silty clay
1
1
COMM in - indicates inches
ft - indicates depth in feet
ppm - indicates parts per million
ft BLS - indicates feet below land surface
PID - Photo Ionization Detector

LOG OF BORING: DP-10
M i d Ate anti 409 Rogers View Court
Raleigh, NC
0 ftEngineering
-9918
& Envlrenmend Solutions Ph: 919-250-991
Page: 10 of 10
Site Name: Liggett & Myers Tobacco Co.
Boring Method: Hand Auger
Project Number: R3225.02
Monitoring Equipment: PID
Location: Durham, NC
Total Boring Depth (ft): 1
Date: 4/5/2023
Field Staff: Maddie Hook
a
g
en
rn
SOIL DESCRIPTION
(color, texture, moisture, etc.)
w
�
W
A
a
0.3
medium orange/brown, slightly sandy, silty clay
0.5
0.5
0.2
medium orange, sandy silt, micaceous
1
1
COMM
in - indicates inches
ft - indicates depth in feet
ppm - indicates parts per million
ft BLS - indicates feet below land surface
PID - Photo Ionization Detector

ATTACHMENT C
FIELD NOTES
10 Mid Atlantic

Mid -Atlantic Associates, Inc.
Field Notes
Job Name: ( {t3 j ne.rs 76 6acce Date: 3
Job Number: CZ3 Z22, Technician:
Task Number: 00 Weather: �
Lvca#ion: Arrival: 16 2-0 ❑epature: 13 C D
Notes:
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Equipment 1 Expendables Used:
Page - of
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Signature
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maatieldnotes.xl

Mid -Atlantic Associates, Inc.
Field Notes
Notes: �P — 5 _ V i ti
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Equipment/ Expendables Used:
Page of
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Signature
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meafieldnates-xi

Mid -Atlantic Associates, Inc.
Field Notes
Notes. "DP — `1
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Equipment 1 Expendables Used:
Page 3
maafieldnotes.xl
Signature

ATTACHMENT D
TABLE
0 Mid Atlantic

TABLE 1
SUMMARY OF FINAL GRADE SOIL SAMPLE ANALYSIS AT DOG PARK
506 AND 508 FERNWAY AVENUE
DURHAM, NORTH
CAROLINA
MID -ATLANTIC JOB NO. R3225.02
SAMPLING LOCATION
PRELIMINARY SOIL REMEDIATION GOALS
(PSRGs; January 2023)
PARAMETER
Dog Park - 1
4/5/2023
0' - 0.5'
Dog Park - 2
4/5/2023
0' - 0.5'
Dog Park - Dup
4/5/2023
0' - 0.5'
Residential
(mg/kg)
Industrial/
Commercial
(mg/kg)
Protection of
Groundwater
(mg/kg)
RCRA Metals by Method 6020B/7471B/7199
Arsenic
1.86
2.91
2.44
0.68
3.0
5.8
63.5
61.7
74.3
3100
47000
580
Barium
Cadmium
<0.0296
0.0540J
0.0951J
1.4
20
3.0
Chromium (Total)
24.7
25.6
22.5
23000*
350000*
360000*
13.6
21.8
28.4
400
800
270
Lead
<0.0225
0.0318 J
<0.0256
4.7
70
NE
Mercury
0.915
1.53
1.30
78
1200
2.1
Selenium
Silver
<0.0077
0.0146 J
0.0158 J
78
1200
3.4
VOCs by Method 8260D
Acetone
0.016 J
0.017 J
0.010 J
14000
210000
25
SVOCs by Method 8270E
Not Detected at or above Laboratory Method Detection Limits
NOTES:
All values reported in milligrams per kilogram (mg/kg)
NE = Not Established
VOCs = Volatile Organic Compounds
SVOCs = Semi -Volatile Organic Compounds
RCRA = Resource Conservation and Recovery Act
<0.0007= Not Detected at or above laboratory method detection limits
Bold values exceed Residential PSRGs
Underlined values exceed Protection of Groundwater PSRGs
* = Total Chromium values were compared to Trivalent Chromium PSRGs, which is
the form of Chromium expected to be
found at the site.
J = Concentration was detected between the method detection limit and the reporting limit; value is an estimation.

ATTACHMENT E
LABORATORY ANALYTICAL REPORT AND
CHAIN -OF -CUSTODY RECORD
0 Mid Atlantic

Waypointo
ANALYTICAL
4/19/2023
Mid -Atlantic Associates, Inc. - Raleigh
Madeline Hook
409 Rogers View Court
Raleigh, NC, 27610
449 5pringbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Ref: Analytical Testing
Lab Report Number: 23-097-0101
Client Project Description: Liggett & Myers Tobacco Company
Dear Madeline Hook:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 4/7/2023 for the analyses presented in the
following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136
Method Update Rule May 2021) unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
a'_1
Angela D Overcash
Senior Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 48

Waypoint.
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State
Program
Lab ID
Expiration Date
North Carolina
State Program
37735
07/31/2023
North Carolina
State Program
402
12/31/2023
South Carolina
State Program
99012
07/31/2023
South Carolina
State Program
99012
12/31/2022
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/29/2024
Arkansas
State Program
88-0650
02/07/2024
California
State Program
2904
06/30/2023
Florida
State Program - NELAP
E871157
06/30/2023
Georgia
State Program
C044
11/14/2025
Georgia
State Program
04015
06/30/2023
Illinois
State Program - NELAP
200078
10/10/2023
Kentucky
State Program
80215
06/30/2023
Kentucky
State Program
KY90047
12/31/2023
Louisiana
State Program - NELAP
LA037
12/31/2023
Louisiana
State Program - NELAP
04015
06/30/2023
Mississippi
State Program
MS
11/14/2025
North Carolina
State Program
47701
07/31/2023
North Carolina
State Program
415
12/31/2023
Pennsylvania
State Program - NELAP
68-03195
05/31/2024
South Carolina
State Program
84002
06/30/2023
Tennessee
State Program
02027
11/14/2025
Texas
State Program - NELAP
T104704180
09/30/2023
Virginia
State Program
00106
06/30/2023
Virginia
State Program - NELAP
460181
09/14/2023
Page 1 of 1 00016/23-097-0101
Page 2 of 48

Waypoint. (2) 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointana lytica Isom
Sample Summary Table
Report Number: 23-097-0101
Client Project Description: Liggett & Myers Tobacco Company
Lab No
Client Sample ID
Matrix
Date Collected
Date Received
Method
Lab ID
93210
Dog Park
- 1
Solids
04/05/2023 11:30
04/07/2023
93210
Dog Park
- 1
Solids
04/05/2023 11:30
04/07/2023
6020B
WP MTN
93210
Dog Park
- 1
Solids
04/05/2023 11:30
04/07/2023
7471A
WP MTN
93211
Dog Park
- 2
Solids
04/05/2023 12:30
04/07/2023
93211
Dog Park
- 2
Solids
04/05/2023 12:30
04/07/2023
7471A
WP MTN
93211
Dog Park
- 2
Solids
04/05/2023 12:30
04/07/2023
6020E
WP MTN
93212
Dog Park
- Dup
Solids
04/05/2023 12:40
04/07/2023
93212
Dog Park
- Dup
Solids
04/05/2023 12:40
04/07/2023
7471A
WP MTN
93212
Dog Park
- Dup
Solids
04/05/2023 12:40
04/07/2023
6020E
WP MTN
WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN
Page 3 of 48

(D
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytica Isom
Summary of Detected Analytes
Project: Liggett & Myers Tobacco Company
Report Number: 23-097-0101
Client Sample ID Lab Sample ID
Method Parameters Result Units Report Limit Analyzed Qualifiers
Dog Park - 1
V 93210
6020B
Arsenic
1.86
mg/Kg - dry
0.0977
04/13/2023 17:53
6020E
Barium
63.5
mg/Kg - dry
0.048
04/13/2023 17:53
6020E
Chromium
24.7
mg/Kg - dry
0.132
04/13/2023 17:53
6020E
Lead
13.6
mg/Kg - dry
0.0354
04/13/2023 17:53
6020B
Selenium
0.915
mg/Kg - dry
0.117
04/13/2023 17:53
8260D
Acetone
0.016
mg/Kg - dry
0.002
04/10/2023 18:33
SW-DRYWT
Moisture
12.5
%
04/08/2023 09:30
Dog Park - 2
V 93211
6020B
Arsenic
2.91
mg/Kg - dry
0.103
04/13/2023 17:57
6020E
Barium
61.7
mg/Kg - dry
0.051
04/13/2023 17:57
6020B
Cadmium
0.0540
mg/Kg - dry
0.0311
04/13/2023 17:57
6020E
Chromium
25.6
mg/Kg - dry
0.139
04/13/2023 17:57
6020B
Lead
21.8
mg/Kg - dry
0.0373
04/13/2023 17:57
6020B
Selenium
1.53
mg/Kg - dry
0.123
04/13/2023 17:57
6020B
Silver
0.0146
mg/Kg - dry
0.0081
04/13/2023 17:57
7471A
Mercury (Total)
0.0318
mg/Kg - dry
0.0260
04/12/2023 11:19
8260D
Acetone
0.017
mg/Kg - dry
0.002
04/10/2023 19:01
SW-DRYWT
Moisture
16.9
%
04/08/2023 09:30
Dog Park - Dup
V 93212
6020E
Arsenic
2.44
mg/Kg - dry
0.104
04/13/2023 18:01
6020E
Barium
74.3
mg/Kg - dry
0.051
04/13/2023 18:01
6020E
Cadmium
0.0951
mg/Kg - dry
0.0314
04/13/2023 18:01
6020E
Chromium
22.5
mg/Kg - dry
0.140
04/13/2023 18:01
6020E
Lead
28.4
mg/Kg - dry
0.0376
04/13/2023 18:01
6020E
Selenium
1.30
mg/Kg - dry
0.125
04/13/2023 18:01
6020E
Silver
0.0158
mg/Kg - dry
0.0081
04/13/2023 18:01
8260D
Acetone
0.010
mg/Kg - dry
0.002
04/10/2023 19:28
SW-DRYWT
Moisture
17.6
%
04/08/2023 09:30
J
J
I
0
I
Page 4 of 48

Waypointo
ANALYTICAL
Client: Mid -Atlantic Associates, Inc. - Raleigh
Project: Liggett & Myers Tobacco Company
Lab Report Number: 23-097-0101
Date: 4/19/2023
449 5pringbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
CASE NARRATIVE
Metals Analyses Method 6020B
Sample 93212 (Dog Park - Dup)
Analyte: Barium
QC Batch No: L676145/L675637
The matrix spike, matrix spike duplicate and the dilution test were all outside of the quality control acceptance
ranges. Matrix interference is suspected.
Sample 93212 (Dog Park - Dup)
Analyte: Chromium
QC Batch No: L676145/L675637
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 93212 (Dog Park - Dup)
Analyte: Lead
QC Batch No: L676145/L675637
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 93212 (Dog Park - Dup)
Analyte: Selenium
QC Batch No: L676145/L675637
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Volatile Organic Compounds - GUMS Method 8260D
Analyte: 2-Butanone
QC Batch No: V31834/V31833
CCV result is below control limits but within method parameters. A standard at or below the RL was analzyed and
found acceptable. Results are reported but considered estimated.
Semivolatile Organic Compounds - GC/MS Method 8270E
Analyte: 2-Methylphenol
QC Batch No: V32131/V32073
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the
batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Analyte: Benzoic Acid
QC Batch No: V32131 /V32073
Analyte was flagged for 0% recovery in the LCSD due to the result being below the MQL. The actual result was
7.897 which calculates to a recovery of 16% which is within the acceptable recovery range.
Analyte: Benzoic Acid
Page 5 of 48

Waypointo
ANALYTICAL
449 5pringbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointartalytical.com
QC Batch No: V32131/V32073
Analyte was flagged for 0% recovery in the LCS due to the result being below the MQL. The actual result was
12.357 which calculates to a recovery of 25% which is within the acceptable recovery range.
Analyte: N-Nitrosodiphenylamine
QC Batch No: V32131/V32073
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the
batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Analyte: Pyridine
QC Batch No: V32131/V32073
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Page 6 of 48

Waypoint.
0
449 Springbrook Rd,
Charlotte, NC 28217
Main
704.529.6364
ANALYTICAL
www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh
Project
Liggett &
Myers Tobacco Company
Madeline Hook
Report Date : 04/19/2023
409 Rogers View Court
Information :
Received : 04/07/2023
Raleigh , NC 27610
Report Number : 23-097-0101
REPOR T OF A NA L YSIS
Lab No : 93210
Matrix: Solids
Sample ID : Dog Park - 1
Sampled: 4/5/2023 11:30
Test
Results
Units
MDL
MQL
DF
Date / Time By
Analytical
Analyzed
Method
Moisture
12.5
%
1
04/08/23 09:30 PEB
SW-DRYWT
Arsenic
1.86
mg/Kg - dry
0.0977
0.286
5
04/13/23 17:53 CPW
6020B
Barium
63.5
mg/Kg - dry
0.048
0.285
5
04/13/23 17:53 CPW
6020E
Cadmium <0.0296
mg/Kg - dry
0.0296
0.286
5
04/13/23 17:53 CPW
6020B
Chromium
24.7
mg/Kg - dry
0.132
0.285
5
04/13/23 17:53 CPW
6020B
Lead
13.6
mg/Kg - dry
0.0354
0.286
5
04/13/23 17:53 CPW
6020B
Mercury (Total) <0.0225
mg/Kg - dry
0.0225
0.186
1
04/12/23 11:18 FDS
7471A
Selenium
0.915
mg/Kg - dry
0.117
0.285
5
04/13/23 17:53 CPW
6020B
Silver <0.0077
mg/Kg - dry
0.0077
0.286
5
04/13/23 17:53 CPW
6020B
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
J Estimated value
Page 7 of 48

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project Liggett & Myers Tobacco Company
Madeline Hook Report Date : 04/19/2023
409 Rogers View Court Information : Received : 04/07/2023
Raleigh , NC 27610
Report Number : 23-097-0101 REPOR T OF A NA L YSIS
Lab No : 93210 Matrix: Solids
Sample ID : Dog Park - 1 Sampled: 4/5/2023 11:30
Analytical Method: 8260D Prep Batch(es): V31833 04/10/23 08:00
Prep Method: 5035
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Acetone
0.0163
mg/Kg - dry
0.002
0.022
1
04/10/23 18:33
TBL
V31834
Acrolein
<0.001
mg/Kg - dry
0.001
0.022
1
04/10/23 18:33
TBL
V31834
Acrylonitrile
<0.0009
mg/Kg - dry
0.0009
0.022
1
04/10/23 18:33
TBL
V31834
Benzene
<0.0007
mg/Kg - dry
0.0007
0.005
1
04/10/23 18:33
TBL
V31834
Bromobenzene
<0.0006
mg/Kg - dry
0.0006
0.005
1
04/10/23 18:33
TBL
V31834
Bromochloromethane
<0.0009
mg/Kg - dry
0.0009
0.005
1
04/10/23 18:33
TBL
V31834
Bromodichloromethane
<0.001
mg/Kg - dry
0.001
0.005
1
04/10/23 18:33
TBL
V31834
Bromoform
<0.001
mg/Kg - dry
0.001
0.005
1
04/10/23 18:33
TBL
V31834
Bromomethane
<0.002
mg/Kg - dry
0.002
0.011
1
04/10/23 18:33
TBL
V31834
n-Butylbenzene
<0.0006
mg/Kg - dry
0.0006
0.005
1
04/10/23 18:33
TBL
V31834
sec -Butyl benzene
<0.0006
mg/Kg - dry
0.0006
0.005
1
04/10/23 18:33
TBL
V31834
tert-Butyl benzene
<0.0006
mg/Kg - dry
0.0006
0.005
1
04/10/23 18:33
TBL
V31834
Carbon Disulfide
<0.0007
mg/Kg - dry
0.0007
0.005
1
04/10/23 18:33
TBL
V31834
Carbon Tetrachloride
<0.001
mg/Kg - dry
0.001
0.005
1
04/10/23 18:33
TBL
V31834
Chlorobenzene
<0.0008
mg/Kg - dry
0.0008
0.005
1
04/10/23 18:33
TBL
V31834
Chlorodibromomethane
<0.001
mg/Kg - dry
0.001
0.005
1
04/10/23 18:33
TBL
V31834
Chloroethane
<0.001
mg/Kg - dry
0.001
0.011
1
04/10/23 18:33
TBL
V31834
Chloroform
<0.001
mg/Kg - dry
0.001
0.005
1
04/10/23 18:33
TBL
V31834
Chloromethane
<0.0007
mg/Kg - dry
0.0007
0.011
1
04/10/23 18:33
TBL
V31834
2-Chlorotoluene
<0.0006
mg/Kg - dry
0.0006
0.005
1
04/10/23 18:33
TBL
V31834
4-Chlorotoluene
<0.0004
mg/Kg - dry
0.0004
0.005
1
04/10/23 18:33
TBL
V31834
Di -Isopropyl Ether (DIPE)
<0.0008
mg/Kg - dry
0.0008
0.005
1
04/10/23 18:33
TBL
V31834
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 8 of 48

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project Liggett & Myers Tobacco Company
Madeline Hook Report Date : 04/19/2023
409 Rogers View Court Information : Received : 04/07/2023
Raleigh , NC 27610
Report Number : 23-097-0101 REPOR T OF A NA L YSIS
Lab No : 93210 Matrix: Solids
Sample ID : Dog Park - 1 Sampled: 4/5/2023 11:30
Analytical Method: 8260D Prep Batch(es): V31833 04/10/23 08:00
Prep Method: 5035
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
1,2-Dibromo-3-Chloropropane
<0.0005
mg/Kg - dry
0.0005
0.011
1
04/10/23 18:33
TBL
V31834
1,2-Dibromoethane
<0.0007
mg/Kg - dry
0.0007
0.005
1
04/10/23 18:33
TBL
V31834
Dibromomethane
<0.0006
mg/Kg - dry
0.0006
0.005
1
04/10/23 18:33
TBL
V31834
1,2-Dichlorobenzene
<0.0004
mg/Kg - dry
0.0004
0.005
1
04/10/23 18:33
TBL
V31834
1,3-Dichlorobenzene
<0.0004
mg/Kg - dry
0.0004
0.005
1
04/10/23 18:33
TBL
V31834
1,4-Dichlorobenzene
<0.0007
mg/Kg - dry
0.0007
0.005
1
04/10/23 18:33
TBL
V31834
Dichlorodifluoromethane
<0.001
mg/Kg - dry
0.001
0.011
1
04/10/23 18:33
TBL
V31834
1,1-Dichloroethane
<0.0009
mg/Kg - dry
0.0009
0.005
1
04/10/23 18:33
TBL
V31834
1,2-Dichloroethane
<0.001
mg/Kg - dry
0.001
0.005
1
04/10/23 18:33
TBL
V31834
1,1-Dichloroethene
<0.0008
mg/Kg - dry
0.0008
0.005
1
04/10/23 18:33
TBL
V31834
cis- 1,2-Dich loroethene
<0.0009
mg/Kg - dry
0.0009
0.005
1
04/10/23 18:33
TBL
V31834
trans-1,2-Dichloroethene
<0.001
mg/Kg - dry
0.001
0.005
1
04/10/23 18:33
TBL
V31834
1,2-Dichloropropane
<0.0005
mg/Kg - dry
0.0005
0.005
1
04/10/23 18:33
TBL
V31834
1,3-Dichloropropane
<0.0006
mg/Kg - dry
0.0006
0.005
1
04/10/23 18:33
TBL
V31834
2,2-Dichloropropane
<0.001
mg/Kg - dry
0.001
0.005
1
04/10/23 18:33
TBL
V31834
1,1-Dichloropropene
<0.0009
mg/Kg - dry
0.0009
0.005
1
04/10/23 18:33
TBL
V31834
cis- 1,3-Dich loropropene
<0.0006
mg/Kg - dry
0.0006
0.005
1
04/10/23 18:33
TBL
V31834
trans-1,3-Dichloropropene
<0.0009
mg/Kg - dry
0.0009
0.005
1
04/10/23 18:33
TBL
V31834
Ethylbenzene
<0.0007
mg/Kg - dry
0.0007
0.005
1
04/10/23 18:33
TBL
V31834
Ethyl Tertiary Butyl Ether (ETBE) <0.0009
mg/Kg - dry
0.0009
0.057
1
04/10/23 18:33
TBL
V31834
Hexachlorobutadiene
<0.0009
mg/Kg - dry
0.0009
0.011
1
04/10/23 18:33
TBL
V31834
n-Hexane
<0.0008
mg/Kg - dry
0.0008
0.011
1
04/10/23 18:33
TBL
V31834
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 9 of 48

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project Liggett & Myers Tobacco Company
Madeline Hook Report Date : 04/19/2023
409 Rogers View Court Information : Received : 04/07/2023
Raleigh , NC 27610
Report Number : 23-097-0101 REPOR T OF A NA L YSIS
Lab No : 93210
Matrix: Solids
Sample ID : Dog Park - 1
Sampled:
4/5/2023 11:30
Analytical Method: 8260D
Prep Batch(es):
V31833
04/10/23 08:00
Prep Method: 5035
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
2-Hexanone
<0.0007
mg/Kg - dry
0.0007
0.022
1
04/10/23 18:33
TBL
V31834
Isopropyl benzene
<0.0005
mg/Kg - dry
0.0005
0.005
1
04/10/23 18:33
TBL
V31834
4-Isopropyl toluene
<0.001
mg/Kg - dry
0.001
0.005
1
04/10/23 18:33
TBL
V31834
Methyl Ethyl Ketone (MEK)
<0.0007
mg/Kg - dry
0.0007
0.022
1
04/10/23 18:33
TBL
V31834
Methyl tert-butyl ether (MTBE)
<0.0007
mg/Kg - dry
0.0007
0.005
1
04/10/23 18:33
TBL
V31834
4-Methyl-2-Pentanone
<0.017
mg/Kg - dry
0.017
0.022
1
04/10/23 18:33
TBL
V31834
Methylene Chloride
<0.001
mg/Kg - dry
0.001
0.011
1
04/10/23 18:33
TBL
V31834
Naphthalene
<0.001
mg/Kg - dry
0.001
0.011
1
04/10/23 18:33
TBL
V31834
n-Propylbenzene
<0.0006
mg/Kg - dry
0.0006
0.005
1
04/10/23 18:33
TBL
V31834
Styrene
<0.001
mg/Kg - dry
0.001
0.005
1
04/10/23 18:33
TBL
V31834
1,1,1,2-Tetrachloroethane
<0.001
mg/Kg - dry
0.001
0.005
1
04/10/23 18:33
TBL
V31834
1,1,2,2-Tetrachloroethane
<0.0004
mg/Kg - dry
0.0004
0.005
1
04/10/23 18:33
TBL
V31834
Tetrachloroethene
<0.001
mg/Kg - dry
0.001
0.005
1
04/10/23 18:33
TBL
V31834
Toluene
<0.0008
mg/Kg - dry
0.0008
0.005
1
04/10/23 18:33
TBL
V31834
1,2,3-Trichlorobenzene
<0.0006
mg/Kg - dry
0.0006
0.011
1
04/10/23 18:33
TBL
V31834
1,2,4-Trichlorobenzene
<0.0007
mg/Kg - dry
0.0007
0.011
1
04/10/23 18:33
TBL
V31834
1,1,1-Trichloroethane
<0.001
mg/Kg - dry
0.001
0.005
1
04/10/23 18:33
TBL
V31834
1,1,2-Trichloroethane
<0.0005
mg/Kg - dry
0.0005
0.005
1
04/10/23 18:33
TBL
V31834
Trichloroethene
<0.001
mg/Kg - dry
0.001
0.005
1
04/10/23 18:33
TBL
V31834
Trichlorofluoromethane
<0.002
mg/Kg - dry
0.002
0.011
1
04/10/23 18:33
TBL
V31834
1,2,3-Trichloropropane
<0.0008
mg/Kg - dry
0.0008
0.005
1
04/10/23 18:33
TBL
V31834
1,3,5-Trimethyl benzene
<0.0006
mg/Kg - dry
0.0006
0.005
1
04/10/23 18:33
TBL
V31834
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 10 of 48

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project Liggett & Myers Tobacco Company
Madeline Hook Report Date : 04/19/2023
409 Rogers View Court Information : Received : 04/07/2023
Raleigh , NC 27610
Report Number : 23-097-0101 REPOR T OF A NA L YSIS
Lab No : 93210 Matrix: Solids
Sample ID : Dog Park - 1 Sampled: 4/5/2023 11:30
Analytical Method: 8260D Prep Batch(es): V31833 04/10/23 08:00
Prep Method: 5035
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Vinyl Acetate
<0.0005
mg/Kg - dry
0.0005
0.011
1
04/10/23 18:33
TBL
V31834
Vinyl Chloride
<0.0005
mg/Kg - dry
0.0005
0.011
1
04/10/23 18:33
TBL
V31834
o-Xylene
<0.0006
mg/Kg - dry
0.0006
0.005
1
04/10/23 18:33
TBL
V31834
m,p-Xylene
<0.001
mg/Kg - dry
0.001
0.011
1
04/10/23 18:33
TBL
V31834
Xylene (Total)
<0.0006
mg/Kg - dry
0.0006
0.005
1
04/10/23 18:33
V31834
Surrogate:4-Bromofluorobenzene
101
Limits:70-130%
1 04/10/23 18:33 TBL
V31834
Surrogate: Dibromofluoromethane
102
Limits:
84-123%
1 04/10/23 18:33 TBL
V31834
Surrogate: Toluene-d8
94.9
Limits:
76-129%
1 04/10/23 18:33 TBL
V31834
Analytical Method: 8270E
Prep Batch(es):
V32073
04/17/23 12:00
Prep Method: 3546
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acenaphthene
<0.132
mg/Kg - dry
0.132
0.754
1
04/18/23 21:44
ANG
V32131
Acenaphthylene
<0.120
mg/Kg - dry
0.120
0.754
1
04/18/23 21:44
ANG
V32131
Aniline
<0.173
mg/Kg - dry
0.173
0.754
1
04/18/23 21:44
ANG
V32131
Anthracene
<0.163
mg/Kg - dry
0.163
0.754
1
04/18/23 21:44
ANG
V32131
Benzo(a)anthracene
<0.158
mg/Kg - dry
0.158
0.754
1
04/18/23 21:44
ANG
V32131
Benzo(a)pyrene
<0.168
mg/Kg - dry
0.168
0.754
1
04/18/23 21:44
ANG
V32131
Benzo(b)fluoranthene
<0.166
mg/Kg - dry
0.166
0.754
1
04/18/23 21:44
ANG
V32131
Benzo(g,h,i)perylene
<0.155
mg/Kg - dry
0.155
0.754
1
04/18/23 21:44
ANG
V32131
Benzo(k)fluoranthene
<0.156
mg/Kg - dry
0.156
0.754
1
04/18/23 21:44
ANG
V32131
Benzoic Acid
<0.662
mg/Kg - dry
0.662
2.29
1
04/18/23 21:44
ANG
V32131
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 11 of 48

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project Liggett & Myers Tobacco Company
Madeline Hook Report Date : 04/19/2023
409 Rogers View Court Information : Received : 04/07/2023
Raleigh , NC 27610
Report Number : 23-097-0101 REPOR T OF A NA L YSIS
Lab No : 93210 Matrix: Solids
Sample ID : Dog Park - 1 Sampled: 4/5/2023 11:30
Analytical Method: 8270E Prep Batch(es): V32073 04/17/23 12:00
Prep Method: 3546
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Benzyl alcohol
<0.120
mg/Kg - dry
0.120
0.754
1
04/18/23 21:44
ANG
V32131
Bis(2-Chloroethoxy)methane
<0.134
mg/Kg - dry
0.134
0.754
1
04/18/23 21:44
ANG
V32131
Bis(2-Chloroethyl)ether
<0.122
mg/Kg - dry
0.122
0.754
1
04/18/23 21:44
ANG
V32131
Bis(2-Chloroisopropyl)ether
<0.155
mg/Kg - dry
0.155
0.377
1
04/18/23 21:44
ANG
V32131
Bis(2-ethylhexyl)phthalate
<0.137
mg/Kg - dry
0.137
0.754
1
04/18/23 21:44
ANG
V32131
4-13romophenyl phenyl ether
<0.124
mg/Kg - dry
0.124
0.754
1
04/18/23 21:44
ANG
V32131
Butyl benzyl phthalate
<0.129
mg/Kg - dry
0.129
0.377
1
04/18/23 21:44
ANG
V32131
4-Chloro-3-methylphenol
<0.105
mg/Kg - dry
0.105
0.754
1
04/18/23 21:44
ANG
V32131
4-Chloroaniline
<0.128
mg/Kg - dry
0.128
0.377
1
04/18/23 21:44
ANG
V32131
2-Chloronaphthalene
<0.132
mg/Kg - dry
0.132
0.754
1
04/18/23 21:44
ANG
V32131
2-Chlorophenol
<0.112
mg/Kg - dry
0.112
0.754
1
04/18/23 21:44
ANG
V32131
4-Chlorophenyl phenyl ether
<0.144
mg/Kg - dry
0.144
1.14
1
04/18/23 21:44
ANG
V32131
Chrysene
<0.162
mg/Kg - dry
0.162
0.754
1
04/18/23 21:44
ANG
V32131
Dibenz(a,h)anthracene
<0.262
mg/Kg - dry
0.262
0.754
1
04/18/23 21:44
ANG
V32131
Dibenzofuran
<0.136
mg/Kg - dry
0.136
0.754
1
04/18/23 21:44
ANG
V32131
1,2-Dichlorobenzene
<0.107
mg/Kg - dry
0.107
0.754
1
04/18/23 21:44
ANG
V32131
1,3-Dichlorobenzene
<0.111
mg/Kg - dry
0.111
0.754
1
04/18/23 21:44
ANG
V32131
1,4-Dichlorobenzene
<0.111
mg/Kg - dry
0.111
0.377
1
04/18/23 21:44
ANG
V32131
3,3'-Dichlorobenzidine
<0.168
mg/Kg - dry
0.168
0.754
1
04/18/23 21:44
ANG
V32131
2,4-Dichlorophenol
<0.109
mg/Kg - dry
0.109
0.754
1
04/18/23 21:44
ANG
V32131
Diethyl phthalate
<0.205
mg/Kg - dry
0.205
0.754
1
04/18/23 21:44
ANG
V32131
Dimethyl phthalate
<0.198
mg/Kg - dry
0.198
0.754
1
04/18/23 21:44
ANG
V32131
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 12 of 48

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project Liggett & Myers Tobacco Company
Madeline Hook Report Date : 04/19/2023
409 Rogers View Court Information : Received : 04/07/2023
Raleigh , NC 27610
Report Number : 23-097-0101 REPOR T OF A NA L YSIS
Lab No : 93210
Matrix: Solids
Sample ID : Dog Park - 1
Sampled:
4/5/2023 11:30
Analytical Method: 8270E
Prep Batch(es):
V32073
04/17/23 12:00
Prep Method: 3546
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
2,4-Dimethylphenol
<0.123
mg/Kg - dry
0.123
0.377
1
04/18/23 21:44
ANG
V32131
Di-n-butyl phthalate
<0.122
mg/Kg - dry
0.122
0.754
1
04/18/23 21:44
ANG
V32131
4,6-Dinitro-2- methyl phenol
<0.274
mg/Kg - dry
0.274
1.71
1
04/18/23 21:44
ANG
V32131
2,4-Dinitrophenol
<0.594
mg/Kg - dry
0.594
1.71
1
04/18/23 21:44
ANG
V32131
2,4-Dinitrotoluene
<0.110
mg/Kg - dry
0.110
0.754
1
04/18/23 21:44
ANG
V32131
2,6-Dinitrotoluene
<0.123
mg/Kg - dry
0.123
0.754
1
04/18/23 21:44
ANG
V32131
Di-n-Octyl Phthalate
<0.163
mg/Kg - dry
0.163
0.377
1
04/18/23 21:44
ANG
V32131
Fluoranthene
<0.140
mg/Kg - dry
0.140
0.754
1
04/18/23 21:44
ANG
V32131
Fluorene
<0.146
mg/Kg - dry
0.146
0.754
1
04/18/23 21:44
ANG
V32131
Hexachlorobenzene
<0.121
mg/Kg - dry
0.121
0.754
1
04/18/23 21:44
ANG
V32131
Hexachlorobutadiene
<0.111
mg/Kg - dry
0.111
0.754
1
04/18/23 21:44
ANG
V32131
Hexachlorocyclopentadiene
<0.179
mg/Kg - dry
0.179
0.754
1
04/18/23 21:44
ANG
V32131
Hexachloroethane
<0.090
mg/Kg - dry
0.090
0.754
1
04/18/23 21:44
ANG
V32131
Indeno(1,2,3-cd)pyrene
<0.204
mg/Kg - dry
0.204
0.754
1
04/18/23 21:44
ANG
V32131
Isophorone
<0.218
mg/Kg - dry
0.218
0.754
1
04/18/23 21:44
ANG
V32131
1-Methylnaphthalene
<0.121
mg/Kg - dry
0.121
0.754
1
04/18/23 21:44
ANG
V32131
2-Methylnaphthalene
<0.114
mg/Kg - dry
0.114
0.754
1
04/18/23 21:44
ANG
V32131
2-Methylphenol
<0.110
mg/Kg - dry
0.110
0.754
1
04/18/23 21:44
ANG
V32131
3&4 Methylphenol
<0.097
mg/Kg - dry
0.097
0.754
1
04/18/23 21:44
ANG
V32131
Naphthalene
<0.164
mg/Kg - dry
0.164
0.754
1
04/18/23 21:44
ANG
V32131
2-Nitroaniline
<0.110
mg/Kg - dry
0.110
0.754
1
04/18/23 21:44
ANG
V32131
3-Nitroaniline
<0.137
mg/Kg - dry
0.137
0.754
1
04/18/23 21:44
ANG
V32131
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 13 of 48

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project Liggett & Myers Tobacco Company
Madeline Hook Report Date : 04/19/2023
409 Rogers View Court Information : Received : 04/07/2023
Raleigh , NC 27610
Report Number : 23-097-0101
REPORT OF ANAL YSIS
Lab No : 93210
Matrix: Solids
Sample ID : Dog Park - 1
Sampled: 4/5/2023
11:30
Analytical Method: 8270E
Prep Batch(es):
V32073
04/17/23 12:00
Prep Method: 3546
Test
Results
Units
MDL
MQL
DF
Date / Time By
Analytical
Analyzed
Batch
4-Nitroaniline
<0.106
mg/Kg - dry
0.106
0.377
1
04/18/23 21:44 ANG
V32131
Nitrobenzene
<0.132
mg/Kg - dry
0.132
0.377
1
04/18/23 21:44 ANG
V32131
2-Nitrophenol
<0.101
mg/Kg - dry
0.101
0.754
1
04/18/23 21:44 ANG
V32131
4-Nitrophenol
<0.133
mg/Kg - dry
0.133
0.754
1
04/18/23 21:44 ANG
V32131
N-Nitrosodimethylamine
<0.300
mg/Kg - dry
0.300
0.754
1
04/18/23 21:44 ANG
V32131
N-Nitrosodiphenylamine
<0.206
mg/Kg - dry
0.206
0.754
1
04/18/23 21:44 ANG
V32131
N-Nitroso-di-n-propylamine
<0.134
mg/Kg - dry
0.134
0.754
1
04/18/23 21:44 ANG
V32131
Pentachlorophenol
<0.396
mg/Kg - dry
0.396
1.14
1
04/18/23 21:44 ANG
V32131
Phenanthrene
<0.237
mg/Kg - dry
0.237
0.754
1
04/18/23 21:44 ANG
V32131
Phenol
<0.128
mg/Kg - dry
0.128
0.754
1
04/18/23 21:44 ANG
V32131
Pyrene
<0.153
mg/Kg - dry
0.153
0.754
1
04/18/23 21:44 ANG
V32131
Pyridine
<0.090
mg/Kg - dry
0.090
0.377
1
04/18/23 21:44 ANG
V32131
1,2,4-Trichlorobenzene
<0.122
mg/Kg - dry
0.122
0.754
1
04/18/23 21:44 ANG
V32131
2,4,5-Trichlorophenol
<0.109
mg/Kg - dry
0.109
0.754
1
04/18/23 21:44 ANG
V32131
2,4,6-Trichlorophenol
<0.110
mg/Kg - dry
0.110
0.754
1
04/18/23 21:44 ANG
V32131
Surrogate: Phenol-d5
79.0
Limits:
34-121%
1 04/18/23 21:44 ANG
8270E
Surrogate: 2-Fluorobiphenyl
97.6
Limits:
44-115%
1 04/18/23 21:44 ANG
V32131
Surrogate: 2-Fluorophenol
85.6
Limits:
35-115%
1 04/18/23 21:44 ANG
V32131
Surrogate: Nitrobenzene-d5
87.4
Limits:
37-122%
1 04/18/23 21:44 ANG
V32131
Surrogate: 4-Terphenyl-d14
109
Limits:
54-127%
1 04/18/23 21:44 ANG
V32131
Surrogate: 2,4,6-Tribromophenol
88.3
Limits: 39-132%
1 04/18/23 21:44 ANG
V32131
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 14 of 48

Waypoint.
0
449 Springbrook Rd,
Charlotte, NC 28217
Main
704.529.6364
ANALYTICAL
www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh
Project
Liggett &
Myers Tobacco Company
Madeline Hook
Report Date : 04/19/2023
409 Rogers View Court
Information :
Received : 04/07/2023
Raleigh , NC 27610
Report Number : 23-097-0101
REPOR T OF A NA L YSIS
Lab No : 93211
Matrix: Solids
Sample ID : Dog Park - 2
Sampled: 4/5/2023 12:30
Test
Results
Units
MDL
MQL
DF
Date / Time By
Analytical
Analyzed
Method
Moisture
16.9
%
1
04/08/23 09:30 PEB
SW-DRYWT
Arsenic
2.91
mg/Kg - dry
0.103
0.301
5
04/13/23 17:57 CPW
6020B
Barium
61.7
mg/Kg - dry
0.051
0.300
5
04/13/23 17:57 CPW
6020E
Cadmium 0.0540 3
mg/Kg - dry
0.0311
0.301
5
04/13/23 17:57 CPW
6020B
Chromium
25.6
mg/Kg - dry
0.139
0.300
5
04/13/23 17:57 CPW
6020E
Lead
21.8
mg/Kg - dry
0.0373
0.301
5
04/13/23 17:57 CPW
6020B
Mercury (Total) 0.03183
mg/Kg - dry
0.0260
0.215
1
04/12/23 11:19 FDS
7471A
Selenium
1.53
mg/Kg - dry
0.123
0.300
5
04/13/23 17:57 CPW
6020B
Silver 0.01463
mg/Kg - dry
0.0081
0.301
5
04/13/23 17:57 CPW
6020B
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
J Estimated value
Page 15 of 48

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project Liggett & Myers Tobacco Company
Madeline Hook Report Date : 04/19/2023
409 Rogers View Court Information : Received : 04/07/2023
Raleigh , NC 27610
Report Number : 23-097-0101 REPOR T OF A NA L YSIS
Lab No : 93211
Matrix: Solids
Sample ID : Dog Park - 2
Sampled:
4/5/2023 12:30
Analytical Method: 8260D
Prep Batch(es):
V31833
04/10/23 08:00
Prep Method: 5035
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
0.0173
mg/Kg - dry
0.002
0.024
1
04/10/23 19:01
TBL
V31834
Acrolein
<0.001
mg/Kg - dry
0.001
0.024
1
04/10/23 19:01
TBL
V31834
Acrylonitrile
<0.0009
mg/Kg - dry
0.0009
0.024
1
04/10/23 19:01
TBL
V31834
Benzene
<0.0007
mg/Kg - dry
0.0007
0.006
1
04/10/23 19:01
TBL
V31834
Bromobenzene
<0.0006
mg/Kg - dry
0.0006
0.006
1
04/10/23 19:01
TBL
V31834
Bromochloromethane
<0.0010
mg/Kg - dry
0.0010
0.006
1
04/10/23 19:01
TBL
V31834
Bromodichloromethane
<0.001
mg/Kg - dry
0.001
0.006
1
04/10/23 19:01
TBL
V31834
Bromoform
<0.001
mg/Kg - dry
0.001
0.006
1
04/10/23 19:01
TBL
V31834
Bromomethane
<0.002
mg/Kg - dry
0.002
0.012
1
04/10/23 19:01
TBL
V31834
n-Butylbenzene
<0.0006
mg/Kg - dry
0.0006
0.006
1
04/10/23 19:01
TBL
V31834
sec -Butyl benzene
<0.0007
mg/Kg - dry
0.0007
0.006
1
04/10/23 19:01
TBL
V31834
tert-Butyl benzene
<0.0006
mg/Kg - dry
0.0006
0.006
1
04/10/23 19:01
TBL
V31834
Carbon Disulfide
<0.0008
mg/Kg - dry
0.0008
0.006
1
04/10/23 19:01
TBL
V31834
Carbon Tetrachloride
<0.001
mg/Kg - dry
0.001
0.006
1
04/10/23 19:01
TBL
V31834
Chlorobenzene
<0.0008
mg/Kg - dry
0.0008
0.006
1
04/10/23 19:01
TBL
V31834
Chlorodibromomethane
<0.001
mg/Kg - dry
0.001
0.006
1
04/10/23 19:01
TBL
V31834
Chloroethane
<0.001
mg/Kg - dry
0.001
0.012
1
04/10/23 19:01
TBL
V31834
Chloroform
<0.001
mg/Kg - dry
0.001
0.006
1
04/10/23 19:01
TBL
V31834
Chloromethane
<0.0008
mg/Kg - dry
0.0008
0.012
1
04/10/23 19:01
TBL
V31834
2-Chlorotoluene
<0.0006
mg/Kg - dry
0.0006
0.006
1
04/10/23 19:01
TBL
V31834
4-Chlorotoluene
<0.0005
mg/Kg - dry
0.0005
0.006
1
04/10/23 19:01
TBL
V31834
Di -Isopropyl Ether (DIPE)
<0.0009
mg/Kg - dry
0.0009
0.006
1
04/10/23 19:01
TBL
V31834
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 16 of 48

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project Liggett & Myers Tobacco Company
Madeline Hook Report Date : 04/19/2023
409 Rogers View Court Information : Received : 04/07/2023
Raleigh , NC 27610
Report Number : 23-097-0101 REPOR T OF A NA L YSIS
Lab No : 93211
Matrix: Solids
Sample ID : Dog Park - 2
Sampled:
4/5/2023 12:30
Analytical Method: 8260D
Prep Batch(es):
V31833
04/10/23 08:00
Prep Method: 5035
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,2-Dibromo-3-Chloropropane
<0.0005
mg/Kg - dry
0.0005
0.012
1
04/10/23 19:01
TBL
V31834
1,2-Dibromoethane
<0.0007
mg/Kg - dry
0.0007
0.006
1
04/10/23 19:01
TBL
V31834
Dibromomethane
<0.0007
mg/Kg - dry
0.0007
0.006
1
04/10/23 19:01
TBL
V31834
1,2-Dichlorobenzene
<0.0004
mg/Kg - dry
0.0004
0.006
1
04/10/23 19:01
TBL
V31834
1,3-Dichlorobenzene
<0.0005
mg/Kg - dry
0.0005
0.006
1
04/10/23 19:01
TBL
V31834
1,4-Dichlorobenzene
<0.0007
mg/Kg - dry
0.0007
0.006
1
04/10/23 19:01
TBL
V31834
Dichlorodifluoromethane
<0.001
mg/Kg - dry
0.001
0.012
1
04/10/23 19:01
TBL
V31834
1,1-Dichloroethane
<0.0010
mg/Kg - dry
0.0010
0.006
1
04/10/23 19:01
TBL
V31834
1,2-Dichloroethane
<0.001
mg/Kg - dry
0.001
0.006
1
04/10/23 19:01
TBL
V31834
1,1-Dichloroethene
<0.0009
mg/Kg - dry
0.0009
0.006
1
04/10/23 19:01
TBL
V31834
cis- 1,2-Dich loroethene
<0.0010
mg/Kg - dry
0.0010
0.006
1
04/10/23 19:01
TBL
V31834
trans-1,2-Dichloroethene
<0.001
mg/Kg - dry
0.001
0.006
1
04/10/23 19:01
TBL
V31834
1,2-Dichloropropane
<0.0005
mg/Kg - dry
0.0005
0.006
1
04/10/23 19:01
TBL
V31834
1,3-Dichloropropane
<0.0007
mg/Kg - dry
0.0007
0.006
1
04/10/23 19:01
TBL
V31834
2,2-Dichloropropane
<0.001
mg/Kg - dry
0.001
0.006
1
04/10/23 19:01
TBL
V31834
1,1-Dichloropropene
<0.0009
mg/Kg - dry
0.0009
0.006
1
04/10/23 19:01
TBL
V31834
cis- 1,3-Dich loropropene
<0.0006
mg/Kg - dry
0.0006
0.006
1
04/10/23 19:01
TBL
V31834
trans-1,3-Dichloropropene
<0.0010
mg/Kg - dry
0.0010
0.006
1
04/10/23 19:01
TBL
V31834
Ethylbenzene
<0.0007
mg/Kg - dry
0.0007
0.006
1
04/10/23 19:01
TBL
V31834
Ethyl Tertiary Butyl Ether (ETBE)
<0.0010
mg/Kg - dry
0.0010
0.060
1
04/10/23 19:01
TBL
V31834
Hexachlorobutadiene
<0.0010
mg/Kg - dry
0.0010
0.012
1
04/10/23 19:01
TBL
V31834
n-Hexane
<0.0008
mg/Kg - dry
0.0008
0.012
1
04/10/23 19:01
TBL
V31834
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 17 of 48

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project Liggett & Myers Tobacco Company
Madeline Hook Report Date : 04/19/2023
409 Rogers View Court Information : Received : 04/07/2023
Raleigh , NC 27610
Report Number : 23-097-0101 REPOR T OF A NA L YSIS
Lab No : 93211
Matrix: Solids
Sample ID : Dog Park - 2
Sampled:
4/5/2023 12:30
Analytical Method: 8260D
Prep Batch(es):
V31833
04/10/23 08:00
Prep Method: 5035
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
2-Hexanone
<0.0007
mg/Kg - dry
0.0007
0.024
1
04/10/23 19:01
TBL
V31834
Isopropyl benzene
<0.0006
mg/Kg - dry
0.0006
0.006
1
04/10/23 19:01
TBL
V31834
4-Isopropyl toluene
<0.001
mg/Kg - dry
0.001
0.006
1
04/10/23 19:01
TBL
V31834
Methyl Ethyl Ketone (MEK)
<0.0008
mg/Kg - dry
0.0008
0.024
1
04/10/23 19:01
TBL
V31834
Methyl tert-butyl ether (MTBE)
<0.0007
mg/Kg - dry
0.0007
0.006
1
04/10/23 19:01
TBL
V31834
4-Methyl-2-Pentanone
<0.018
mg/Kg - dry
0.018
0.024
1
04/10/23 19:01
TBL
V31834
Methylene Chloride
<0.001
mg/Kg - dry
0.001
0.012
1
04/10/23 19:01
TBL
V31834
Naphthalene
<0.001
mg/Kg - dry
0.001
0.012
1
04/10/23 19:01
TBL
V31834
n-Propylbenzene
<0.0006
mg/Kg - dry
0.0006
0.006
1
04/10/23 19:01
TBL
V31834
Styrene
<0.001
mg/Kg - dry
0.001
0.006
1
04/10/23 19:01
TBL
V31834
1,1,1,2-Tetrachloroethane
<0.001
mg/Kg - dry
0.001
0.006
1
04/10/23 19:01
TBL
V31834
1,1,2,2-Tetrachloroethane
<0.0004
mg/Kg - dry
0.0004
0.006
1
04/10/23 19:01
TBL
V31834
Tetrachloroethene
<0.001
mg/Kg - dry
0.001
0.006
1
04/10/23 19:01
TBL
V31834
Toluene
<0.0008
mg/Kg - dry
0.0008
0.006
1
04/10/23 19:01
TBL
V31834
1,2,3-Trichlorobenzene
<0.0006
mg/Kg - dry
0.0006
0.012
1
04/10/23 19:01
TBL
V31834
1,2,4-Trichlorobenzene
<0.0008
mg/Kg - dry
0.0008
0.012
1
04/10/23 19:01
TBL
V31834
1,1,1-Trichloroethane
<0.001
mg/Kg - dry
0.001
0.006
1
04/10/23 19:01
TBL
V31834
1,1,2-Trichloroethane
<0.0006
mg/Kg - dry
0.0006
0.006
1
04/10/23 19:01
TBL
V31834
Trichloroethene
<0.001
mg/Kg - dry
0.001
0.006
1
04/10/23 19:01
TBL
V31834
Trichlorofluoromethane
<0.002
mg/Kg - dry
0.002
0.012
1
04/10/23 19:01
TBL
V31834
1,2,3-Trichloropropane
<0.0009
mg/Kg - dry
0.0009
0.006
1
04/10/23 19:01
TBL
V31834
1,3,5-Trimethyl benzene
<0.0006
mg/Kg - dry
0.0006
0.006
1
04/10/23 19:01
TBL
V31834
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 18 of 48

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project Liggett & Myers Tobacco Company
Madeline Hook Report Date : 04/19/2023
409 Rogers View Court Information : Received : 04/07/2023
Raleigh , NC 27610
Report Number : 23-097-0101 REPOR T OF A NA L YSIS
Lab No : 93211 Matrix: Solids
Sample ID : Dog Park - 2 Sampled: 4/5/2023 12:30
Analytical Method: 8260D Prep Batch(es): V31833 04/10/23 08:00
Prep Method: 5035
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Vinyl Acetate
<0.0006
mg/Kg - dry
0.0006
0.012
1
04/10/23 19:01
TBL
V31834
Vinyl Chloride
<0.0006
mg/Kg - dry
0.0006
0.012
1
04/10/23 19:01
TBL
V31834
o-Xylene
<0.0006
mg/Kg - dry
0.0006
0.006
1
04/10/23 19:01
TBL
V31834
m,p-Xylene
<0.001
mg/Kg - dry
0.001
0.012
1
04/10/23 19:01
TBL
V31834
Xylene (Total)
<0.0006
mg/Kg - dry
0.0006
0.006
1
04/10/23 19:01
V31834
Surrogate:4-Bromofluorobenzene
101
Limits:70-130%
1 04/10/23 19:01 TBL
V31834
Surrogate: Dibromofluoromethane
104
Limits:
84-123%
1 04/10/23 19:01 TBL
V31834
Surrogate: Toluene-d8
95.2
Limits:
76-129%
1 04/10/23 19:01 TBL
V31834
Analytical Method: 8270E
Prep Batch(es):
V32073
04/17/23 12:00
Prep Method: 3546
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acenaphthene
<0.139
mg/Kg - dry
0.139
0.795
1
04/18/23 22:07
ANG
V32131
Acenaphthylene
<0.126
mg/Kg - dry
0.126
0.795
1
04/18/23 22:07
ANG
V32131
Aniline
<0.182
mg/Kg - dry
0.182
0.795
1
04/18/23 22:07
ANG
V32131
Anthracene
<0.172
mg/Kg - dry
0.172
0.795
1
04/18/23 22:07
ANG
V32131
Benzo(a)anthracene
<0.167
mg/Kg - dry
0.167
0.795
1
04/18/23 22:07
ANG
V32131
Benzo(a)pyrene
<0.176
mg/Kg - dry
0.176
0.795
1
04/18/23 22:07
ANG
V32131
Benzo(b)fluoranthene
<0.175
mg/Kg - dry
0.175
0.795
1
04/18/23 22:07
ANG
V32131
Benzo(g,h,i)perylene
<0.163
mg/Kg - dry
0.163
0.795
1
04/18/23 22:07
ANG
V32131
Benzo(k)fluoranthene
<0.164
mg/Kg - dry
0.164
0.795
1
04/18/23 22:07
ANG
V32131
Benzoic Acid
<0.697
mg/Kg - dry
0.697
2.41
1
04/18/23 22:07
ANG
V32131
Qualifiers/ DF Dilution Factor
3
Estimated value
Definitions MQL Method Quantitation Limit
Page 19 of 48

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project Liggett & Myers Tobacco Company
Madeline Hook Report Date : 04/19/2023
409 Rogers View Court Information : Received : 04/07/2023
Raleigh , NC 27610
Report Number : 23-097-0101 REPOR T OF A NA L YSIS
Lab No : 93211
Matrix: Solids
Sample ID : Dog Park - 2
Sampled:
4/5/2023 12:30
Analytical Method: 8270E
Prep Batch(es):
V32073
04/17/23 12:00
Prep Method: 3546
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Benzyl alcohol
<0.126
mg/Kg - dry
0.126
0.795
1
04/18/23 22:07
ANG
V32131
Bis(2-Chloroethoxy)methane
<0.141
mg/Kg - dry
0.141
0.795
1
04/18/23 22:07
ANG
V32131
Bis(2-Chloroethyl)ether
<0.128
mg/Kg - dry
0.128
0.795
1
04/18/23 22:07
ANG
V32131
Bis(2-Chloroisopropyl)ether
<0.163
mg/Kg - dry
0.163
0.398
1
04/18/23 22:07
ANG
V32131
Bis(2-ethylhexyl)phthalate
<0.144
mg/Kg - dry
0.144
0.795
1
04/18/23 22:07
ANG
V32131
4-13romophenyl phenyl ether
<0.131
mg/Kg - dry
0.131
0.795
1
04/18/23 22:07
ANG
V32131
Butyl benzyl phthalate
<0.135
mg/Kg - dry
0.135
0.398
1
04/18/23 22:07
ANG
V32131
4-Chloro-3-methylphenol
<0.111
mg/Kg - dry
0.111
0.795
1
04/18/23 22:07
ANG
V32131
4-Chloroaniline
<0.134
mg/Kg - dry
0.134
0.398
1
04/18/23 22:07
ANG
V32131
2-Chloronaphthalene
<0.139
mg/Kg - dry
0.139
0.795
1
04/18/23 22:07
ANG
V32131
2-Chlorophenol
<0.118
mg/Kg - dry
0.118
0.795
1
04/18/23 22:07
ANG
V32131
4-Chlorophenyl phenyl ether
<0.151
mg/Kg - dry
0.151
1.20
1
04/18/23 22:07
ANG
V32131
Chrysene
<0.170
mg/Kg - dry
0.170
0.795
1
04/18/23 22:07
ANG
V32131
Dibenz(a,h)anthracene
<0.276
mg/Kg - dry
0.276
0.795
1
04/18/23 22:07
ANG
V32131
Dibenzofuran
<0.143
mg/Kg - dry
0.143
0.795
1
04/18/23 22:07
ANG
V32131
1,2-Dichlorobenzene
<0.113
mg/Kg - dry
0.113
0.795
1
04/18/23 22:07
ANG
V32131
1,3-Dichlorobenzene
<0.117
mg/Kg - dry
0.117
0.795
1
04/18/23 22:07
ANG
V32131
1,4-Dichlorobenzene
<0.117
mg/Kg - dry
0.117
0.398
1
04/18/23 22:07
ANG
V32131
3,3'-Dichlorobenzidine
<0.176
mg/Kg - dry
0.176
0.795
1
04/18/23 22:07
ANG
V32131
2,4-Dichlorophenol
<0.115
mg/Kg - dry
0.115
0.795
1
04/18/23 22:07
ANG
V32131
Diethyl phthalate
<0.216
mg/Kg - dry
0.216
0.795
1
04/18/23 22:07
ANG
V32131
Dimethyl phthalate
<0.209
mg/Kg - dry
0.209
0.795
1
04/18/23 22:07
ANG
V32131
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 20 of 48

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project Liggett & Myers Tobacco Company
Madeline Hook Report Date : 04/19/2023
409 Rogers View Court Information : Received : 04/07/2023
Raleigh , NC 27610
Report Number : 23-097-0101 REPOR T OF A NA L YSIS
Lab No : 93211
Matrix: Solids
Sample ID : Dog Park - 2
Sampled:
4/5/2023 12:30
Analytical Method: 8270E
Prep Batch(es):
V32073
04/17/23 12:00
Prep Method: 3546
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
2,4-Dimethylphenol
<0.129
mg/Kg - dry
0.129
0.398
1
04/18/23 22:07
ANG
V32131
Di-n-butyl phthalate
<0.128
mg/Kg - dry
0.128
0.795
1
04/18/23 22:07
ANG
V32131
4,6-Dinitro-2- methyl phenol
<0.288
mg/Kg - dry
0.288
1.81
1
04/18/23 22:07
ANG
V32131
2,4-Dinitrophenol
<0.625
mg/Kg - dry
0.625
1.81
1
04/18/23 22:07
ANG
V32131
2,4-Dinitrotoluene
<0.116
mg/Kg - dry
0.116
0.795
1
04/18/23 22:07
ANG
V32131
2,6-Dinitrotoluene
<0.129
mg/Kg - dry
0.129
0.795
1
04/18/23 22:07
ANG
V32131
Di-n-Octyl Phthalate
<0.172
mg/Kg - dry
0.172
0.398
1
04/18/23 22:07
ANG
V32131
Fluoranthene
<0.148
mg/Kg - dry
0.148
0.795
1
04/18/23 22:07
ANG
V32131
Fluorene
<0.154
mg/Kg - dry
0.154
0.795
1
04/18/23 22:07
ANG
V32131
Hexachlorobenzene
<0.127
mg/Kg - dry
0.127
0.795
1
04/18/23 22:07
ANG
V32131
Hexachlorobutadiene
<0.117
mg/Kg - dry
0.117
0.795
1
04/18/23 22:07
ANG
V32131
Hexachlorocyclopentadiene
<0.188
mg/Kg - dry
0.188
0.795
1
04/18/23 22:07
ANG
V32131
Hexachloroethane
<0.095
mg/Kg - dry
0.095
0.795
1
04/18/23 22:07
ANG
V32131
Indeno(1,2,3-cd)pyrene
<0.215
mg/Kg - dry
0.215
0.795
1
04/18/23 22:07
ANG
V32131
Isophorone
<0.229
mg/Kg - dry
0.229
0.795
1
04/18/23 22:07
ANG
V32131
1-Methylnaphthalene
<0.127
mg/Kg - dry
0.127
0.795
1
04/18/23 22:07
ANG
V32131
2-Methylnaphthalene
<0.120
mg/Kg - dry
0.120
0.795
1
04/18/23 22:07
ANG
V32131
2-Methylphenol
<0.116
mg/Kg - dry
0.116
0.795
1
04/18/23 22:07
ANG
V32131
3&4 Methylphenol
<0.102
mg/Kg - dry
0.102
0.795
1
04/18/23 22:07
ANG
V32131
Naphthalene
<0.173
mg/Kg - dry
0.173
0.795
1
04/18/23 22:07
ANG
V32131
2-Nitroaniline
<0.116
mg/Kg - dry
0.116
0.795
1
04/18/23 22:07
ANG
V32131
3-Nitroaniline
<0.144
mg/Kg - dry
0.144
0.795
1
04/18/23 22:07
ANG
V32131
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 21 of 48

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project Liggett & Myers Tobacco Company
Madeline Hook Report Date : 04/19/2023
409 Rogers View Court Information : Received : 04/07/2023
Raleigh , NC 27610
Report Number : 23-097-0101
REPORT OF ANAL YSIS
Lab No : 93211
Matrix: Solids
Sample ID : Dog Park - 2
Sampled: 4/5/2023
12:30
Analytical Method: 8270E
Prep Batch(es):
V32073
04/17/23 12:00
Prep Method: 3546
Test
Results
Units
MDL
MQL
DF
Date / Time By
Analytical
Analyzed
Batch
4-Nitroaniline
<0.112
mg/Kg - dry
0.112
0.398
1
04/18/23 22:07 ANG
V32131
Nitrobenzene
<0.139
mg/Kg - dry
0.139
0.398
1
04/18/23 22:07 ANG
V32131
2-Nitrophenol
<0.106
mg/Kg - dry
0.106
0.795
1
04/18/23 22:07 ANG
V32131
4-Nitrophenol
<0.140
mg/Kg - dry
0.140
0.795
1
04/18/23 22:07 ANG
V32131
N-Nitrosodimethylamine
<0.316
mg/Kg - dry
0.316
0.795
1
04/18/23 22:07 ANG
V32131
N-Nitrosodiphenylamine
<0.217
mg/Kg - dry
0.217
0.795
1
04/18/23 22:07 ANG
V32131
N-Nitroso-di-n-propylamine
<0.141
mg/Kg - dry
0.141
0.795
1
04/18/23 22:07 ANG
V32131
Pentachlorophenol
<0.417
mg/Kg - dry
0.417
1.20
1
04/18/23 22:07 ANG
V32131
Phenanthrene
<0.250
mg/Kg - dry
0.250
0.795
1
04/18/23 22:07 ANG
V32131
Phenol
<0.134
mg/Kg - dry
0.134
0.795
1
04/18/23 22:07 ANG
V32131
Pyrene
<0.161
mg/Kg - dry
0.161
0.795
1
04/18/23 22:07 ANG
V32131
Pyridine
<0.095
mg/Kg - dry
0.095
0.398
1
04/18/23 22:07 ANG
V32131
1,2,4-Trichlorobenzene
<0.128
mg/Kg - dry
0.128
0.795
1
04/18/23 22:07 ANG
V32131
2,4,5-Trichlorophenol
<0.115
mg/Kg - dry
0.115
0.795
1
04/18/23 22:07 ANG
V32131
2,4,6-Trichlorophenol
<0.116
mg/Kg - dry
0.116
0.795
1
04/18/23 22:07 ANG
V32131
Surrogate: Phenol-d5
78.7
Limits:
34-121%
1 04/18/23 22:07 ANG
8270E
Surrogate: 2-Fluorobiphenyl
92.8
Limits:
44-115%
1 04/18/23 22:07 ANG
V32131
Surrogate: 2-Fluorophenol
84.7
Limits:
35-115%
1 04/18/23 22:07 ANG
V32131
Surrogate: Nitrobenzene-d5
88.0
Limits:
37-122%
1 04/18/23 22:07 ANG
V32131
Surrogate: 4-Terphenyl-d14
107
Limits:
54-127%
1 04/18/23 22:07 ANG
V32131
Surrogate: 2,4,6-Tribromophenol
83.8
Limits: 39-132%
1 04/18/23 22:07 ANG
V32131
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 22 of 48

Waypoint.
0
449 Springbrook Rd,
Charlotte, NC 28217
Main
704.529.6364
ANALYTICAL
www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh
Project
Liggett &
Myers Tobacco Company
Madeline Hook
Report Date : 04/19/2023
409 Rogers View Court
Information :
Received : 04/07/2023
Raleigh , NC 27610
Report Number : 23-097-0101
REPOR T OF A NA L YSIS
Lab No : 93212
Matrix: Solids
Sample ID : Dog Park - Dup
Sampled: 4/5/2023 12:40
Test
Results
Units
MDL
MQL
DF
Date / Time By
Analytical
Analyzed
Method
Moisture
17.6
%
1
04/08/23 09:30 PEB
SW-DRYWT
Arsenic
2.44
mg/Kg - dry
0.104
0.303
5
04/13/23 18:01 CPW
6020B
Barium
74.3
mg/Kg - dry
0.051
0.303
5
04/13/23 18:01 CPW
6020E
Cadmium 0.09513
mg/Kg - dry
0.0314
0.303
5
04/13/23 18:01 CPW
6020B
Chromium
22.5
mg/Kg - dry
0.140
0.303
5
04/13/23 18:01 CPW
6020E
Lead
28.4
mg/Kg - dry
0.0376
0.303
5
04/13/23 18:01 CPW
6020B
Mercury (Total) <0.0256
mg/Kg - dry
0.0256
0.212
1
04/12/23 11:21 FDS
7471A
Selenium
1.30
mg/Kg - dry
0.125
0.303
5
04/13/23 18:01 CPW
6020B
Silver 0.01583
mg/Kg - dry
0.0081
0.303
5
04/13/23 18:01 CPW
6020B
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
J Estimated value
Page 23 of 48

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project Liggett & Myers Tobacco Company
Madeline Hook Report Date : 04/19/2023
409 Rogers View Court Information : Received : 04/07/2023
Raleigh , NC 27610
Report Number : 23-097-0101 REPOR T OF A NA L YSIS
Lab No : 93212
Matrix: Solids
Sample ID : Dog Park - Dup
Sampled:
4/5/2023 12:40
Analytical Method: 8260D
Prep Batch(es):
V31833
04/10/23 08:00
Prep Method: 5035
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
0.0103
mg/Kg - dry
0.002
0.024
1
04/10/23 19:28
TBL
V31834
Acrolein
<0.001
mg/Kg - dry
0.001
0.024
1
04/10/23 19:28
TBL
V31834
Acrylonitrile
<0.0009
mg/Kg - dry
0.0009
0.024
1
04/10/23 19:28
TBL
V31834
Benzene
<0.0007
mg/Kg - dry
0.0007
0.006
1
04/10/23 19:28
TBL
V31834
Bromobenzene
<0.0006
mg/Kg - dry
0.0006
0.006
1
04/10/23 19:28
TBL
V31834
Bromochloromethane
<0.0010
mg/Kg - dry
0.0010
0.006
1
04/10/23 19:28
TBL
V31834
Bromodichloromethane
<0.001
mg/Kg - dry
0.001
0.006
1
04/10/23 19:28
TBL
V31834
Bromoform
<0.001
mg/Kg - dry
0.001
0.006
1
04/10/23 19:28
TBL
V31834
Bromomethane
<0.002
mg/Kg - dry
0.002
0.012
1
04/10/23 19:28
TBL
V31834
n-Butylbenzene
<0.0006
mg/Kg - dry
0.0006
0.006
1
04/10/23 19:28
TBL
V31834
sec -Butyl benzene
<0.0007
mg/Kg - dry
0.0007
0.006
1
04/10/23 19:28
TBL
V31834
tert-Butyl benzene
<0.0006
mg/Kg - dry
0.0006
0.006
1
04/10/23 19:28
TBL
V31834
Carbon Disulfide
<0.0008
mg/Kg - dry
0.0008
0.006
1
04/10/23 19:28
TBL
V31834
Carbon Tetrachloride
<0.001
mg/Kg - dry
0.001
0.006
1
04/10/23 19:28
TBL
V31834
Chlorobenzene
<0.0008
mg/Kg - dry
0.0008
0.006
1
04/10/23 19:28
TBL
V31834
Chlorodibromomethane
<0.001
mg/Kg - dry
0.001
0.006
1
04/10/23 19:28
TBL
V31834
Chloroethane
<0.001
mg/Kg - dry
0.001
0.012
1
04/10/23 19:28
TBL
V31834
Chloroform
<0.001
mg/Kg - dry
0.001
0.006
1
04/10/23 19:28
TBL
V31834
Chloromethane
<0.0008
mg/Kg - dry
0.0008
0.012
1
04/10/23 19:28
TBL
V31834
2-Chlorotoluene
<0.0006
mg/Kg - dry
0.0006
0.006
1
04/10/23 19:28
TBL
V31834
4-Chlorotoluene
<0.0005
mg/Kg - dry
0.0005
0.006
1
04/10/23 19:28
TBL
V31834
Di -Isopropyl Ether (DIPE)
<0.0009
mg/Kg - dry
0.0009
0.006
1
04/10/23 19:28
TBL
V31834
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 24 of 48

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project Liggett & Myers Tobacco Company
Madeline Hook Report Date : 04/19/2023
409 Rogers View Court Information : Received : 04/07/2023
Raleigh , NC 27610
Report Number : 23-097-0101 REPOR T OF A NA L YSIS
Lab No : 93212
Matrix: Solids
Sample ID : Dog Park - Dup
Sampled:
4/5/2023 12:40
Analytical Method: 8260D
Prep Batch(es):
V31833
04/10/23 08:00
Prep Method: 5035
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,2-Dibromo-3-Chloropropane
<0.0005
mg/Kg - dry
0.0005
0.012
1
04/10/23 19:28
TBL
V31834
1,2-Dibromoethane
<0.0007
mg/Kg - dry
0.0007
0.006
1
04/10/23 19:28
TBL
V31834
Dibromomethane
<0.0007
mg/Kg - dry
0.0007
0.006
1
04/10/23 19:28
TBL
V31834
1,2-Dichlorobenzene
<0.0004
mg/Kg - dry
0.0004
0.006
1
04/10/23 19:28
TBL
V31834
1,3-Dichlorobenzene
<0.0005
mg/Kg - dry
0.0005
0.006
1
04/10/23 19:28
TBL
V31834
1,4-Dichlorobenzene
<0.0007
mg/Kg - dry
0.0007
0.006
1
04/10/23 19:28
TBL
V31834
Dichlorodifluoromethane
<0.001
mg/Kg - dry
0.001
0.012
1
04/10/23 19:28
TBL
V31834
1,1-Dichloroethane
<0.0010
mg/Kg - dry
0.0010
0.006
1
04/10/23 19:28
TBL
V31834
1,2-Dichloroethane
<0.001
mg/Kg - dry
0.001
0.006
1
04/10/23 19:28
TBL
V31834
1,1-Dichloroethene
<0.0009
mg/Kg - dry
0.0009
0.006
1
04/10/23 19:28
TBL
V31834
cis- 1,2-Dich loroethene
<0.0010
mg/Kg - dry
0.0010
0.006
1
04/10/23 19:28
TBL
V31834
trans-1,2-Dichloroethene
<0.001
mg/Kg - dry
0.001
0.006
1
04/10/23 19:28
TBL
V31834
1,2-Dichloropropane
<0.0005
mg/Kg - dry
0.0005
0.006
1
04/10/23 19:28
TBL
V31834
1,3-Dichloropropane
<0.0007
mg/Kg - dry
0.0007
0.006
1
04/10/23 19:28
TBL
V31834
2,2-Dichloropropane
<0.001
mg/Kg - dry
0.001
0.006
1
04/10/23 19:28
TBL
V31834
1,1-Dichloropropene
<0.0009
mg/Kg - dry
0.0009
0.006
1
04/10/23 19:28
TBL
V31834
cis- 1,3-Dich loropropene
<0.0007
mg/Kg - dry
0.0007
0.006
1
04/10/23 19:28
TBL
V31834
trans-1,3-Dichloropropene
<0.0010
mg/Kg - dry
0.0010
0.006
1
04/10/23 19:28
TBL
V31834
Ethylbenzene
<0.0007
mg/Kg - dry
0.0007
0.006
1
04/10/23 19:28
TBL
V31834
Ethyl Tertiary Butyl Ether (ETBE)
<0.001
mg/Kg - dry
0.001
0.060
1
04/10/23 19:28
TBL
V31834
Hexachlorobutadiene
<0.0010
mg/Kg - dry
0.0010
0.012
1
04/10/23 19:28
TBL
V31834
n-Hexane
<0.0008
mg/Kg - dry
0.0008
0.012
1
04/10/23 19:28
TBL
V31834
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 25 of 48

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project Liggett & Myers Tobacco Company
Madeline Hook Report Date : 04/19/2023
409 Rogers View Court Information : Received : 04/07/2023
Raleigh , NC 27610
Report Number : 23-097-0101 REPOR T OF A NA L YSIS
Lab No : 93212
Matrix: Solids
Sample ID : Dog Park - Dup
Sampled:
4/5/2023 12:40
Analytical Method: 8260D
Prep Batch(es):
V31833
04/10/23 08:00
Prep Method: 5035
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
2-Hexanone
<0.0008
mg/Kg - dry
0.0008
0.024
1
04/10/23 19:28
TBL
V31834
Isopropyl benzene
<0.0006
mg/Kg - dry
0.0006
0.006
1
04/10/23 19:28
TBL
V31834
4-Isopropyl toluene
<0.001
mg/Kg - dry
0.001
0.006
1
04/10/23 19:28
TBL
V31834
Methyl Ethyl Ketone (MEK)
<0.0008
mg/Kg - dry
0.0008
0.024
1
04/10/23 19:28
TBL
V31834
Methyl tert-butyl ether (MTBE)
<0.0008
mg/Kg - dry
0.0008
0.006
1
04/10/23 19:28
TBL
V31834
4-Methyl-2-Pentanone
<0.018
mg/Kg - dry
0.018
0.024
1
04/10/23 19:28
TBL
V31834
Methylene Chloride
<0.001
mg/Kg - dry
0.001
0.012
1
04/10/23 19:28
TBL
V31834
Naphthalene
<0.001
mg/Kg - dry
0.001
0.012
1
04/10/23 19:28
TBL
V31834
n-Propylbenzene
<0.0007
mg/Kg - dry
0.0007
0.006
1
04/10/23 19:28
TBL
V31834
Styrene
<0.001
mg/Kg - dry
0.001
0.006
1
04/10/23 19:28
TBL
V31834
1,1,1,2-Tetrachloroethane
<0.001
mg/Kg - dry
0.001
0.006
1
04/10/23 19:28
TBL
V31834
1,1,2,2-Tetrachloroethane
<0.0004
mg/Kg - dry
0.0004
0.006
1
04/10/23 19:28
TBL
V31834
Tetrachloroethene
<0.001
mg/Kg - dry
0.001
0.006
1
04/10/23 19:28
TBL
V31834
Toluene
<0.0008
mg/Kg - dry
0.0008
0.006
1
04/10/23 19:28
TBL
V31834
1,2,3-Trichlorobenzene
<0.0007
mg/Kg - dry
0.0007
0.012
1
04/10/23 19:28
TBL
V31834
1,2,4-Trichlorobenzene
<0.0008
mg/Kg - dry
0.0008
0.012
1
04/10/23 19:28
TBL
V31834
1,1,1-Trichloroethane
<0.001
mg/Kg - dry
0.001
0.006
1
04/10/23 19:28
TBL
V31834
1,1,2-Trichloroethane
<0.0006
mg/Kg - dry
0.0006
0.006
1
04/10/23 19:28
TBL
V31834
Trichloroethene
<0.001
mg/Kg - dry
0.001
0.006
1
04/10/23 19:28
TBL
V31834
Trichlorofluoromethane
<0.002
mg/Kg - dry
0.002
0.012
1
04/10/23 19:28
TBL
V31834
1,2,3-Trichloropropane
<0.0009
mg/Kg - dry
0.0009
0.006
1
04/10/23 19:28
TBL
V31834
1,3,5-Trimethyl benzene
<0.0007
mg/Kg - dry
0.0007
0.006
1
04/10/23 19:28
TBL
V31834
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 26 of 48

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project Liggett & Myers Tobacco Company
Madeline Hook Report Date : 04/19/2023
409 Rogers View Court Information : Received : 04/07/2023
Raleigh , NC 27610
Report Number : 23-097-0101 REPOR T OF A NA L YSIS
Lab No : 93212 Matrix: Solids
Sample ID : Dog Park - Dup Sampled: 4/5/2023 12:40
Analytical Method: 8260D Prep Batch(es): V31833 04/10/23 08:00
Prep Method: 5035
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Vinyl Acetate
<0.0006
mg/Kg - dry
0.0006
0.012
1
04/10/23 19:28
TBL
V31834
Vinyl Chloride
<0.0006
mg/Kg - dry
0.0006
0.012
1
04/10/23 19:28
TBL
V31834
o-Xylene
<0.0006
mg/Kg - dry
0.0006
0.006
1
04/10/23 19:28
TBL
V31834
m,p-Xylene
<0.001
mg/Kg - dry
0.001
0.012
1
04/10/23 19:28
TBL
V31834
Xylene (Total)
<0.0006
mg/Kg - dry
0.0006
0.006
1
04/10/23 19:28
V31834
Surrogate:4-Bromofluorobenzene
99.6
Limits:70-130%
1 04/10/23 19:28 TBL
V31834
Surrogate: Dibromofluoromethane
103
Limits:
84-123%
1 04/10/23 19:28 TBL
V31834
Surrogate: Toluene-d8
97.0
Limits:
76-129%
1 04/10/23 19:28 TBL
V31834
Analytical Method: 8270E
Prep Batch(es):
V32073
04/17/23 12:00
Prep Method: 3546
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acenaphthene
<0.140
mg/Kg - dry
0.140
0.800
1
04/18/23 22:30
ANG
V32131
Acenaphthylene
<0.127
mg/Kg - dry
0.127
0.800
1
04/18/23 22:30
ANG
V32131
Aniline
<0.184
mg/Kg - dry
0.184
0.800
1
04/18/23 22:30
ANG
V32131
Anthracene
<0.173
mg/Kg - dry
0.173
0.800
1
04/18/23 22:30
ANG
V32131
Benzo(a)anthracene
<0.168
mg/Kg - dry
0.168
0.800
1
04/18/23 22:30
ANG
V32131
Benzo(a)pyrene
<0.178
mg/Kg - dry
0.178
0.800
1
04/18/23 22:30
ANG
V32131
Benzo(b)fluoranthene
<0.177
mg/Kg - dry
0.177
0.800
1
04/18/23 22:30
ANG
V32131
Benzo(g,h,i)perylene
<0.165
mg/Kg - dry
0.165
0.800
1
04/18/23 22:30
ANG
V32131
Benzo(k)fluoranthene
<0.166
mg/Kg - dry
0.166
0.800
1
04/18/23 22:30
ANG
V32131
Benzoic Acid
<0.703
mg/Kg - dry
0.703
2.43
1
04/18/23 22:30
ANG
V32131
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 27 of 48

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project Liggett & Myers Tobacco Company
Madeline Hook Report Date : 04/19/2023
409 Rogers View Court Information : Received : 04/07/2023
Raleigh , NC 27610
Report Number : 23-097-0101 REPOR T OF A NA L YSIS
Lab No : 93212
Matrix: Solids
Sample ID : Dog Park - Dup
Sampled:
4/5/2023 12:40
Analytical Method: 8270E
Prep Batch(es):
V32073
04/17/23 12:00
Prep Method: 3546
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Benzyl alcohol
<0.127
mg/Kg - dry
0.127
0.800
1
04/18/23 22:30
ANG
V32131
Bis(2-Chloroethoxy)methane
<0.143
mg/Kg - dry
0.143
0.800
1
04/18/23 22:30
ANG
V32131
Bis(2-Chloroethyl)ether
<0.129
mg/Kg - dry
0.129
0.800
1
04/18/23 22:30
ANG
V32131
Bis(2-Chloroisopropyl)ether
<0.165
mg/Kg - dry
0.165
0.400
1
04/18/23 22:30
ANG
V32131
Bis(2-ethylhexyl)phthalate
<0.145
mg/Kg - dry
0.145
0.800
1
04/18/23 22:30
ANG
V32131
4-13romophenyl phenyl ether
<0.132
mg/Kg - dry
0.132
0.800
1
04/18/23 22:30
ANG
V32131
Butyl benzyl phthalate
<0.137
mg/Kg - dry
0.137
0.400
1
04/18/23 22:30
ANG
V32131
4-Chloro-3-methylphenol
<0.112
mg/Kg - dry
0.112
0.800
1
04/18/23 22:30
ANG
V32131
4-Chloroaniline
<0.135
mg/Kg - dry
0.135
0.400
1
04/18/23 22:30
ANG
V32131
2-Chloronaphthalene
<0.140
mg/Kg - dry
0.140
0.800
1
04/18/23 22:30
ANG
V32131
2-Chlorophenol
<0.119
mg/Kg - dry
0.119
0.800
1
04/18/23 22:30
ANG
V32131
4-Chlorophenyl phenyl ether
<0.152
mg/Kg - dry
0.152
1.21
1
04/18/23 22:30
ANG
V32131
Chrysene
<0.172
mg/Kg - dry
0.172
0.800
1
04/18/23 22:30
ANG
V32131
Dibenz(a,h)anthracene
<0.279
mg/Kg - dry
0.279
0.800
1
04/18/23 22:30
ANG
V32131
Dibenzofuran
<0.144
mg/Kg - dry
0.144
0.800
1
04/18/23 22:30
ANG
V32131
1,2-Dichlorobenzene
<0.114
mg/Kg - dry
0.114
0.800
1
04/18/23 22:30
ANG
V32131
1,3-Dichlorobenzene
<0.118
mg/Kg - dry
0.118
0.800
1
04/18/23 22:30
ANG
V32131
1,4-Dichlorobenzene
<0.118
mg/Kg - dry
0.118
0.400
1
04/18/23 22:30
ANG
V32131
3,3'-Dichlorobenzidine
<0.178
mg/Kg - dry
0.178
0.800
1
04/18/23 22:30
ANG
V32131
2,4-Dichlorophenol
<0.116
mg/Kg - dry
0.116
0.800
1
04/18/23 22:30
ANG
V32131
Diethyl phthalate
<0.218
mg/Kg - dry
0.218
0.800
1
04/18/23 22:30
ANG
V32131
Dimethyl phthalate
<0.211
mg/Kg - dry
0.211
0.800
1
04/18/23 22:30
ANG
V32131
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 28 of 48

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project Liggett & Myers Tobacco Company
Madeline Hook Report Date : 04/19/2023
409 Rogers View Court Information : Received : 04/07/2023
Raleigh , NC 27610
Report Number : 23-097-0101 REPOR T OF A NA L YSIS
Lab No : 93212
Matrix: Solids
Sample ID : Dog Park - Dup
Sampled:
4/5/2023 12:40
Analytical Method: 8270E
Prep Batch(es):
V32073
04/17/23 12:00
Prep Method: 3546
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
2,4-Dimethylphenol
<0.131
mg/Kg - dry
0.131
0.400
1
04/18/23 22:30
ANG
V32131
Di-n-butyl phthalate
<0.129
mg/Kg - dry
0.129
0.800
1
04/18/23 22:30
ANG
V32131
4,6-Dinitro-2- methyl phenol
<0.291
mg/Kg - dry
0.291
1.82
1
04/18/23 22:30
ANG
V32131
2,4-Dinitrophenol
<0.631
mg/Kg - dry
0.631
1.82
1
04/18/23 22:30
ANG
V32131
2,4-Dinitrotoluene
<0.117
mg/Kg - dry
0.117
0.800
1
04/18/23 22:30
ANG
V32131
2,6-Dinitrotoluene
<0.131
mg/Kg - dry
0.131
0.800
1
04/18/23 22:30
ANG
V32131
Di-n-Octyl Phthalate
<0.173
mg/Kg - dry
0.173
0.400
1
04/18/23 22:30
ANG
V32131
Fluoranthene
<0.149
mg/Kg - dry
0.149
0.800
1
04/18/23 22:30
ANG
V32131
Fluorene
<0.155
mg/Kg - dry
0.155
0.800
1
04/18/23 22:30
ANG
V32131
Hexachlorobenzene
<0.128
mg/Kg - dry
0.128
0.800
1
04/18/23 22:30
ANG
V32131
Hexachlorobutadiene
<0.118
mg/Kg - dry
0.118
0.800
1
04/18/23 22:30
ANG
V32131
Hexachlorocyclopentadiene
<0.190
mg/Kg - dry
0.190
0.800
1
04/18/23 22:30
ANG
V32131
Hexachloroethane
<0.096
mg/Kg - dry
0.096
0.800
1
04/18/23 22:30
ANG
V32131
Indeno(1,2,3-cd)pyrene
<0.217
mg/Kg - dry
0.217
0.800
1
04/18/23 22:30
ANG
V32131
Isophorone
<0.231
mg/Kg - dry
0.231
0.800
1
04/18/23 22:30
ANG
V32131
1-Methylnaphthalene
<0.128
mg/Kg - dry
0.128
0.800
1
04/18/23 22:30
ANG
V32131
2-Methylnaphthalene
<0.121
mg/Kg - dry
0.121
0.800
1
04/18/23 22:30
ANG
V32131
2-Methylphenol
<0.117
mg/Kg - dry
0.117
0.800
1
04/18/23 22:30
ANG
V32131
3&4 Methylphenol
<0.103
mg/Kg - dry
0.103
0.800
1
04/18/23 22:30
ANG
V32131
Naphthalene
<0.174
mg/Kg - dry
0.174
0.800
1
04/18/23 22:30
ANG
V32131
2-Nitroaniline
<0.117
mg/Kg - dry
0.117
0.800
1
04/18/23 22:30
ANG
V32131
3-Nitroaniline
<0.145
mg/Kg - dry
0.145
0.800
1
04/18/23 22:30
ANG
V32131
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 29 of 48

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project Liggett & Myers Tobacco Company
Madeline Hook Report Date : 04/19/2023
409 Rogers View Court Information : Received : 04/07/2023
Raleigh , NC 27610
Report Number : 23-097-0101
REPORT OF ANAL YSIS
Lab No : 93212 Matrix: Solids
Sample ID : Dog Park - Dup Sampled: 4/5/2023 12:40
Analytical Method: 8270E Prep Batch(es): V32073 04/17/23 12:00
Prep Method: 3546
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
4-Nitroaniline
<0.113
mg/Kg - dry
0.113
0.400
1
04/18/23 22:30 ANG
V32131
Nitrobenzene
<0.140
mg/Kg - dry
0.140
0.400
1
04/18/23 22:30 ANG
V32131
2-Nitrophenol
<0.107
mg/Kg - dry
0.107
0.800
1
04/18/23 22:30 ANG
V32131
4-Nitrophenol
<0.141
mg/Kg - dry
0.141
0.800
1
04/18/23 22:30 ANG
V32131
N-Nitrosodimethylamine
<0.319
mg/Kg - dry
0.319
0.800
1
04/18/23 22:30 ANG
V32131
N-Nitrosodiphenylamine
<0.219
mg/Kg - dry
0.219
0.800
1
04/18/23 22:30 ANG
V32131
N-Nitroso-di-n-propylamine
<0.143
mg/Kg - dry
0.143
0.800
1
04/18/23 22:30 ANG
V32131
Pentachlorophenol
<0.421
mg/Kg - dry
0.421
1.21
1
04/18/23 22:30 ANG
V32131
Phenanthrene
<0.252
mg/Kg - dry
0.252
0.800
1
04/18/23 22:30 ANG
V32131
Phenol
<0.135
mg/Kg - dry
0.135
0.800
1
04/18/23 22:30 ANG
V32131
Pyrene
<0.162
mg/Kg - dry
0.162
0.800
1
04/18/23 22:30 ANG
V32131
Pyridine
<0.096
mg/Kg - dry
0.096
0.400
1
04/18/23 22:30 ANG
V32131
1,2,4-Trichlorobenzene
<0.129
mg/Kg - dry
0.129
0.800
1
04/18/23 22:30 ANG
V32131
2,4,5-Trichlorophenol
<0.116
mg/Kg - dry
0.116
0.800
1
04/18/23 22:30 ANG
V32131
2,4,6-Trichlorophenol
<0.117
mg/Kg - dry
0.117
0.800
1
04/18/23 22:30 ANG
V32131
Surrogate: Phenol-d5
75.7
Limits: 34-121%
1 04/18/23 22:30 ANG
8270E
Surrogate: 2-Fluorobiphenyl
90.4
Limits: 44-115%
1 04/18/23 22:30 ANG
V32131
Surrogate: 2-Fluorophenol
81.1
Limits: 35-115%
1 04/18/23 22:30 ANG
V32131
Surrogate: Nitrobenzene-d5
85.6
Limits: 37-122%
1 04/18/23 22:30 ANG
V32131
Surrogate: 4-Terphenyl-d14
108
Limits: 54-127%
1 04/18/23 22:30 ANG
V32131
Surrogate: 2,4,6-Tribromophenol
86.8
Limits: 39-132%
1 04/18/23 22:30 ANG
V32131
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 30 of 48

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Mid -Atlantic Associates, Inc. - Raleigh
Project Description: Liggett & Myers Tobacco Company
Report No: 23-097-0101
QC Prep:
L675637
QC Analytical Batch(es): L676145
QC Prep Batch Method:
3050B
Analysis Method:
6020B
Analysis Description:
Metals Analyses
Lab Reagent Blank
LRB-L675637
Matrix: SOL
Associated Lab Samples:
93210, 93211, 93212
Blank
MDL
MQL
Analyzed
Parameter
Units
Result
Arsenic
mg/Kg
<0.0855
0.0855
0.250
04/13/2317:35
Barium
mg/Kg
<0.042
0.042
0.250
04/13/2317:35
Cadmium
mg/Kg
<0.0259
0.0259
0.250
04/13/2317:35
Chromium
mg/Kg
<0.116
0.116
0.250
04/13/2317:35
Lead
mg/Kg
<0.0310
0.0310
0.250
04/13/2317:35
Selenium
mg/Kg
<0.103
0.103
0.250
04/13/2317:35
Silver
mg/Kg
<0.0067
0.0067
0.250
04/13/2317:35
Laboratory Control Sample
LCS-L675637
Spike
LCS
LCS %Rec
% Rec
Parameter
Units
Conc.
Result
Limits
Arsenic
mg/Kg
2.50
2.35
94.0
80-120
Barium
mg/Kg
5.00
4.46
89.0
80-120
Cadmium
mg/Kg
0.500
0.472
94.0
80-120
Chromium
mg/Kg
5.00
4.77
95.0
80-120
Lead
mg/Kg
2.50
2.32
93.0
80-120
Selenium
mg/Kg
5.00
4.77
95.0
80-120
Silver
mg/Kg
0.500
0.464
93.0
80-120
Matrix Spike & Matrix Spike Duplicate
V 93212-MS-L675637
V 93212-MSD-L675637
MS Spike
MSD
MS Result
MSD
MS
MSD
%Rec
Max
Parameter
Units
Result
Conc.
Spike
Result
%Rec
%Rec
Limits
RPD
RPD
Conc.
Arsenic
mg/Kg
2.01
2.39
2.50
3.92
4.36
80.0
94.0
75-125
10.6
80
Barium
mg/Kg
61.2
4.78
4.99
58.4
66.8
0.0*
112
75-125
13.4
80
Cadmium
mg/Kg
0.0784
0.478
0.499
0.540
0.566
97.0
98.0
75-125
4.7
80
Chromium
mg/Kg
18.5
4.78
4.99
23.0
24.8
94.0
126*
75-125
7.5
80
* QC Fail Date: 04/19/2023 01:19 PM Page 1 of 16
Page 31 of 48

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Mid -Atlantic Associates, Inc. - Raleigh
Project Description:
Liggett & Myers Tobacco Company
Report No:
23-097-0101
QC Prep:
L675637
QC Analytical Batch(es): L676145
QC Prep Batch Method:
3050B
Analysis Method:
6020B
Analysis Description:
Metals Analyses
Matrix Spike & Matrix Spike
Duplicate
V 93212-MS-L675637
V 93212-MSD-L675637
MS Spike
MSD MS Result
MSD MS
MSD %Rec Max
Parameter
Units
Result Conc.
Spike
Result %Rec
%Rec Limits RPD RPD
Conc.
Lead
mg/Kg
23.4 2.39
2.50 29.3
30.0 247*
265* 75-125 2.3 80
Selenium
mg/Kg
1.07 4.78
4.99 4.49
4.76 72.0*
74.0* 75-125 5.8 80
Silver
mg/Kg
0.0131 0.478
0.499 0.439
0.481 89.0
94.0 75-125 9.1 80
Post Digestion Spike
V 93212-PDS-L675637
PDS
%
Analyzed
Parameter
Units
Result Recovery
Arsenic
mg/Kg
1.37
98.0
04/13/2318:12
Barium
mg/Kg
8.47
99.0
04/13/2318:12
Cadmium
mg/Kg
0.242
97.0
04/13/2318:12
Chromium
mg/Kg
4.00
94.0
04/13/2318:12
Lead
mg/Kg
3.29
93.0
04/13/2318:12
Selenium
mg/Kg
2.44
97.0
04/13/2318:12
Silver
mg/Kg
0.232
96.0
04/13/2318:12
* QC Fail Date: 04/19/2023 01:19 PM Page 2 of 16
Page 32 of 48

s
Waypoint.
0
449 SpringttrQok Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL
www.waypoi ntana lytica l.corn
Quality
Control Data
Client ID: Mid -Atlantic Associates,
Inc. - Raleigh
Project Description: Liggett & Myers Tobacco Company
Report No: 23-097-0101
QC Prep: L675263
QC Analytical Batch(es): L675705
QC Prep Batch Method: 7471A
Analysis Method:
7471A
Analysis Description:
Solids Total Mercury Analysis - CVAA
Lab Reagent Blank
LRB-L675263
Matrix: SOL
Associated Lab Samples: 93210, 93211, 93212
Blank MDL
MQL
Analyzed
Parameter Units
Result
Mercury (Total) mg/Kg
<0.0232 0.0232
0.192
04/12/23 11:06
Laboratory Control Sample
LCS-L675263
Spike
LCS
LCS %Rec % Rec
Parameter Units
Conc.
Result
Limits
Mercury (Total) mg/Kg
0.400
0.413
103 80-120
Matrix Spike & Matrix Spike Duplicate
L 94718-MS-L675263
L 94718-MSD-L675263
MS Spike
MSD MS Result
MSD MS MSD %Rec Max
Parameter Units
Result Conc.
Spike
Result %Rec %Rec Limits RPD RPD
Conc.
Mercury (Total) mg/Kg
0.214 0.375
0.337 0.638
0.564 113 104 80-120 12.3 20
Post Digestion Spike
L 94718-PDS-L675263
PDS
%
Analyzed
Parameter Units
Result Recovery
Mercury (Total) mg/Kg
0.544
60.0*
04/12/23 11:32
* QC Fail Date: 04/19/2023 01:19 PM Page 3 of 16
Page 33 of 48

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Mid -Atlantic Associates, Inc. - Raleigh
Project Description: Liggett & Myers Tobacco Company
Report No: 23-097-0101
QC Prep: V31833
QC Prep Batch Method: 5035
Lab Reagent Blank LRB-V31833
Associated Lab Samples: 93210, 93211, 93212
QC Analytical Batch(es): V31834
Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Matrix: SOL
Blank MDL MQL Analyzed % % Rec
Parameter Units Result Recovery Limits
Acetone
mg/Kg
<0.002
0.002
0.020
04/10/23 12:41
Acrolein
mg/Kg
<0.001
0.001
0.020
04/10/23 12:41
Acrylonitrile
mg/Kg
<0.0008
0.0008
0.020
04/10/23 12:41
Benzene
mg/Kg
<0.0006
0.0006
0.005
04/10/23 12:41
Bromobenzene
mg/Kg
<0.0005
0.0005
0.005
04/10/23 12:41
Bromochloromethane
mg/Kg
<0.0008
0.0008
0.005
04/10/23 12:41
Bromodichloromethane
mg/Kg
<0.001
0.001
0.005
04/10/23 12:41
Bromoform
mg/Kg
<0.001
0.001
0.005
04/10/23 12:41
Bromomethane
mg/Kg
<0.001
0.001
0.010
04/10/23 12:41
n-Butylbenzene
mg/Kg
<0.0005
0.0005
0.005
04/10/23 12:41
sec -Butyl benzene
mg/Kg
<0.0006
0.0006
0.005
04/10/23 12:41
tert-Butyl benzene
mg/Kg
<0.0005
0.0005
0.005
04/10/23 12:41
Carbon Disulfide
mg/Kg
<0.0006
0.0006
0.005
04/10/23 12:41
Carbon Tetrachloride
mg/Kg
<0.001
0.001
0.005
04/10/23 12:41
Chlorobenzene
mg/Kg
<0.0007
0.0007
0.005
04/10/23 12:41
Chlorodibromomethane
mg/Kg
<0.0009
0.0009
0.005
04/10/23 12:41
Chloroethane
mg/Kg
<0.0009
0.0009
0.010
04/10/23 12:41
Chloroform
mg/Kg
<0.001
0.001
0.005
04/10/23 12:41
Chloromethane
mg/Kg
<0.0006
0.0006
0.010
04/10/23 12:41
2-Chlorotoluene
mg/Kg
<0.0005
0.0005
0.005
04/10/23 12:41
4-Chlorotoluene
mg/Kg
<0.0004
0.0004
0.005
04/10/23 12:41
Di -Isopropyl Ether (DIPE)
mg/Kg
<0.0007
0.0007
0.005
04/10/23 12:41
1,2-Dibromo-3-Chloropropane
mg/Kg
<0.0004
0.0004
0.010
04/10/23 12:41
1,2-Dibromoethane
mg/Kg
<0.0006
0.0006
0.005
04/10/23 12:41
Dibromomethane
mg/Kg
<0.0006
0.0006
0.005
04/10/23 12:41
1,2-Dichlorobenzene
mg/Kg
<0.0003
0.0003
0.005
04/10/23 12:41
1,3-Dichlorobenzene
mg/Kg
<0.0004
0.0004
0.005
04/10/23 12:41
Date:
04/19/2023 01:19 PM
Page 4 of 16
Page 34 of 48

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Mid -Atlantic Associates, Inc. - Raleigh
Project Description: Liggett & Myers Tobacco Company
Report No: 23-097-0101
QC Prep: V31833
QC Prep Batch Method: 5035
Lab Reagent Blank LRB-V31833
Associated Lab Samples: 93210, 93211, 93212
QC Analytical Batch(es): V31834
Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Matrix: SOL
Blank MDL MQL Analyzed % % Rec
Parameter Units Result Recovery Limits
1,4-Dichlorobenzene
mg/Kg
<0.0006
0.0006
0.005
04/10/23 12:41
Dichlorodifluoromethane
mg/Kg
<0.001
0.001
0.010
04/10/23 12:41
1,1-Dichloroethane
mg/Kg
<0.0008
0.0008
0.005
04/10/23 12:41
1,2-Dichloroethane
mg/Kg
<0.001
0.001
0.005
04/10/23 12:41
1,1-Dichloroethene
mg/Kg
<0.0007
0.0007
0.005
04/10/23 12:41
cis-1,2-Dichloroethene
mg/Kg
<0.0008
0.0008
0.005
04/10/23 12:41
trans-1,2-Dichloroethene
mg/Kg
<0.001
0.001
0.005
04/10/23 12:41
1,2-Dichloropropane
mg/Kg
<0.0004
0.0004
0.005
04/10/23 12:41
1,3-Dichloropropane
mg/Kg
<0.0006
0.0006
0.005
04/10/23 12:41
2,2-Dichloropropane
mg/Kg
<0.001
0.001
0.005
04/10/23 12:41
1,1-Dichloropropene
mg/Kg
<0.0008
0.0008
0.005
04/10/23 12:41
cis-1,3-Dichloropropene
mg/Kg
<0.0005
0.0005
0.005
04/10/23 12:41
trans-1,3-Dichloropropene
mg/Kg
<0.0008
0.0008
0.005
04/10/23 12:41
Ethylbenzene
mg/Kg
<0.0006
0.0006
0.005
04/10/23 12:41
Ethyl Tertiary Butyl Ether (ETBE)
mg/Kg
<0.0008
0.0008
0.050
04/10/23 12:41
Hexachlorobutadiene
mg/Kg
<0.0008
0.0008
0.010
04/10/23 12:41
n-Hexane
mg/Kg
<0.0007
0.0007
0.010
04/10/23 12:41
2-Hexanone
mg/Kg
<0.0006
0.0006
0.020
04/10/23 12:41
Isopropyl benzene
mg/Kg
<0.0005
0.0005
0.005
04/10/23 12:41
4-Isopropyl toluene
mg/Kg
<0.001
0.001
0.005
04/10/23 12:41
Methyl Ethyl Ketone (MEK)
mg/Kg
<0.0007
0.0007
0.020
04/10/23 12:41
Methyl tert-butyl ether (MTBE)
mg/Kg
<0.0006
0.0006
0.005
04/10/23 12:41
4-Methyl-2-Pentanone
mg/Kg
<0.015
0.015
0.020
04/10/23 12:41
Methylene Chloride
mg/Kg
0.001
0.001
0.010
04/10/23 12:41
Naphthalene
mg/Kg
<0.0010
0.0010
0.010
04/10/23 12:41
n-Propylbenzene
mg/Kg
<0.0005
0.0005
0.005
04/10/23 12:41
Styrene
mg/Kg
<0.001
0.001
0.005
04/10/23 12:41
Date:
04/19/2023 01:19 PM
Page 5 of 16
Page 35 of 48

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Mid -Atlantic Associates, Inc. - Raleigh
Project Description: Liggett & Myers Tobacco Company
Report No: 23-097-0101
QC Prep: V31833
QC Prep Batch Method: 5035
Lab Reagent Blank
LRB-V31833
Associated Lab Samples:
93210, 93211, 93212
Blank
MDL
Parameter
Units
Result
1,1,1,2-Tetrachloroethane
mg/Kg
<0.001
0.001
1,1,2,2-Tetrachloroethane
mg/Kg
<0.0003
0.0003
Tetrachloroethene
mg/Kg
<0.0009
0.0009
Toluene
mg/Kg
<0.0007
0.0007
1,2,3-Trichlorobenzene
mg/Kg
<0.0005
0.0005
1,2,4-Trichlorobenzene
mg/Kg
<0.0006
0.0006
1,1,1-Trichloroethane
mg/Kg
<0.001
0.001
1,1,2-Trichloroethane
mg/Kg
<0.0005
0.0005
Trichloroethene
mg/Kg
<0.0009
0.0009
Trichlorofluoromethane
mg/Kg
<0.002
0.002
1,2,3-Trichloropropane
mg/Kg
< 0.0007
0.0007
1,3,5-Trimethyl benzene
mg/Kg
<0.0005
0.0005
Vinyl Acetate
mg/Kg
<0.0005
0.0005
Vinyl Chloride
mg/Kg
<0.0005
0.0005
o-Xylene
mg/Kg
<0.0005
0.0005
m,p-Xylene
mg/Kg
<0.001
0.001
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-d8 (S)
QC Analytical Batch(es): V31834
Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Matrix: SOL
MQL Analyzed % % Rec
Recovery Limits
0.005
04/10/23
12:41
0.005
04/10/23
12:41
0.005
04/10/23
12:41
0.005
04/10/23
12:41
0.010
04/10/23
12:41
0.010
04/10/23
12:41
0.005
04/10/23
12:41
0.005
04/10/23
12:41
0.005
04/10/23
12:41
0.010
04/10/23
12:41
0.005
04/10/23
12:41
0.005
04/10/23
12:41
0.010
04/10/23
12:41
0.010
04/10/23
12:41
0.005
04/10/23
12:41
0.010
04/10/23
12:41
04/10/23
12:41 98.8 70-130
04/10/23
12:41 101 84-123
04/10/23
12:41 97.0 76-129
Laboratory Control Sample & LCSD
LCS-V31833
LCSD-V31833
Spike
LCS
LCSD
LCS
LCSD
% Rec
Parameter Units
Conc.
Result
Result
%Rec
a/o Rec
Limits
RPD
Max
RPD
Acetone mg/Kg
0.100
0.097
0.108
97.6
108
29-198
10.1
20
Acrolein mg/Kg
0.100
0.091
0.097
91.2
97.1
70-130
6.2
20
Acrylonitrile mg/Kg
0.100
0.095
0.098
95.5
98.8
65-134
3.3
20
Date: 04/19/2023 01:19 PM Page 6 of 16
Page 36 of 48

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Mid -Atlantic Associates, Inc. - Raleigh
Project Description: Liggett & Myers Tobacco Company
Report No: 23-097-0101
QC Prep: V31833 QC Analytical Batch(es): V31834
QC Prep Batch Method: 5035 Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Laboratory Control Sample & LCSD LCS-V31833 LCSD-V31833
Parameter
Units
Spike
Conc.
LCS
Result
LCSD
Result
LCS
%Rec
LCSD
% Rec
% Rec
Limits
RPD
Max
RPD
Benzene
mg/Kg
0.050
0.050
0.050
102
101
74-127
0.5
20
Bromobenzene
mg/Kg
0.050
0.049
0.049
99.8
98.0
73-125
1.8
20
Bromochloromethane
mg/Kg
0.050
0.053
0.054
108
108
72-134
0.7
20
Bromodichloromethane
mg/Kg
0.050
0.053
0.052
107
105
75-122
1.8
20
Bromoform
mg/Kg
0.050
0.052
0.056
105
112
66-135
6.2
20
Bromomethane
mg/Kg
0.050
0.052
0.054
104
109
20-180
4.6
20
n-Butylbenzene
mg/Kg
0.050
0.051
0.048
103
97.4
65-135
5.3
20
sec -Butyl benzene
mg/Kg
0.050
0.050
0.048
102
96.8
66-131
4.8
20
tert-Butyl benzene
mg/Kg
0.050
0.050
0.048
101
96.2
67-132
4.4
20
Carbon Disulfide
mg/Kg
0.050
0.052
0.049
105
98.8
61-129
5.8
20
Carbon Tetrachloride
mg/Kg
0.050
0.047
0.050
95.6
102
64-143
6.2
20
Chlorobenzene
mg/Kg
0.050
0.051
0.050
104
101
74-118
2.5
20
Chlorodibromomethane
mg/Kg
0.050
0.052
0.053
104
106
73-122
2.0
20
Chloroethane
mg/Kg
0.050
0.057
0.055
114
111
33-149
2.4
20
Chloroform
mg/Kg
0.050
0.053
0.050
106
101
73-127
5.4
20
Chloromethane
mg/Kg
0.050
0.045
0.048
91.8
97.4
45-143
5.9
20
2-Chlorotoluene
mg/Kg
0.050
0.050
0.048
100
97.0
67-124
3.0
20
4-Chlorotoluene
mg/Kg
0.050
0.050
0.048
100
97.0
71-126
3.0
20
Di -Isopropyl Ether (DIPE)
mg/Kg
0.050
0.051
0.051
103
102
59-159
0.9
20
1,2-Dibromo-3-Chloropropane
mg/Kg
0.050
0.057
0.056
114
113
55-157
0.8
20
1,2-Dibromoethane
mg/Kg
0.050
0.055
0.056
111
113
70-132
1.9
20
Dibromomethane
mg/Kg
0.050
0.051
0.054
103
108
74-133
5.3
20
1,2-Dichlorobenzene
mg/Kg
0.050
0.050
0.051
102
103
72-123
0.7
20
1,3-Dichlorobenzene
mg/Kg
0.050
0.051
0.050
104
100
71-120
3.7
20
1,4-Dichlorobenzene
mg/Kg
0.050
0.050
0.049
102
98.2
71-123
3.6
20
Dichlorodifluoromethane
mg/Kg
0.050
0.046
0.043
93.4
87.4
26-146
6.6
20
Date: 04/19/2023 01:19 PM Page 7 of 16
Page 37 of 48

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Mid -Atlantic Associates, Inc. - Raleigh
Project Description: Liggett & Myers Tobacco Company
Report No: 23-097-0101
QC Prep: V31833 QC Analytical Batch(es): V31834
QC Prep Batch Method: 5035 Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Laboratory Control Sample & LCSD LCS-V31833 LCSD-V31833
Parameter
Units
Spike
Conc.
LCS
Result
LCSD
Result
LCS
%Rec
LCSD
% Rec
% Rec
Limits
RPD
Max
RPD
1,1-Dichloroethane
mg/Kg
0.050
0.051
0.049
104
99.8
74-127
3.7
20
1,2-Dichloroethane
mg/Kg
0.050
0.050
0.050
100
100
68-128
0.0
20
1,1-Dichloroethene
mg/Kg
0.050
0.051
0.048
102
96.2
67-149
5.8
20
cis-1,2-Dichloroethene
mg/Kg
0.050
0.051
0.050
103
100
76-134
2.7
20
trans-1,2-Dichloroethene
mg/Kg
0.050
0.050
0.048
101
97.4
73-132
4.0
20
1,2-Dichloropropane
mg/Kg
0.050
0.052
0.049
106
99.8
73-130
5.8
20
1,3-Dichloropropane
mg/Kg
0.050
0.053
0.054
107
110
75-124
2.0
20
2,2-Dichloropropane
mg/Kg
0.050
0.053
0.049
106
99.2
50-142
6.8
20
1,1-Dichloropropene
mg/Kg
0.050
0.054
0.048
108
97.8
71-130
9.9
20
cis-1,3-Dichloropropene
mg/Kg
0.050
0.053
0.053
107
108
71-125
0.5
20
trans-1,3-Dichloropropene
mg/Kg
0.050
0.054
0.054
108
109
68-123
0.9
20
Ethylbenzene
mg/Kg
0.050
0.051
0.048
102
96.8
74-128
5.2
20
Ethyl Tertiary Butyl Ether (ETBE)
mg/Kg
0.100
0.102
0.104
102
104
70-130
1.9
20
Hexachlorobutadiene
mg/Kg
0.050
0.052
0.049
106
99.8
64-125
5.6
20
n-Hexane
mg/Kg
0.050
0.057
0.054
115
108
70-130
6.0
20
2-Hexanone
mg/Kg
0.050
0.045
0.055
91.2
110
61-157
18.8
20
Isopropyl benzene
mg/Kg
0.050
0.051
0.048
104
97.2
68-126
6.3
20
4-Isopropyl toluene
mg/Kg
0.050
0.051
0.048
104
97.4
68-129
6.3
20
Methyl Ethyl Ketone (MEK)
mg/Kg
0.050
0.033
0.036
67.2
72.0
63-149
6.8
20
Methyl tert-butyl ether (MTBE)
mg/Kg
0.050
0.051
0.052
103
105
70-130
2.3
20
4-Methyl-2-Pentanone
mg/Kg
0.050
0.056
0.060
114
121
57-162
6.1
20
Methylene Chloride
mg/Kg
0.050
0.043
0.044
87.8
89.2
74-129
1.5
20
Naphthalene
mg/Kg
0.050
0.054
0.054
109
109
57-157
0.5
20
n-Propylbenzene
mg/Kg
0.050
0.051
0.047
102
94.0
67-130
8.3
20
Styrene
mg/Kg
0.050
0.053
0.051
107
104
77-121
2.6
20
1,1,1,2-Tetrachloroethane
mg/Kg
0.050
0.051
0.052
103
105
72-115
1.9
20
Date: 04/19/2023 01:19 PM Page 8 of 16
Page 38 of 48

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Mid -Atlantic Associates, Inc. - Raleigh
Project Description:
Liggett & Myers Tobacco Company
Report No:
23-097-0101
QC Prep:
V31833
QC Analytical Batch(es): V31834
QC Prep Batch Method:
5035
Analysis
Method:
8260D
Analysis
Description:
Volatile Organic Compounds - GC/MS
Laboratory Control Sample
& LCSD
LCS-V31833 LCSD-V31833
Spike
LCS
LCSD
LCS
LCSD
% Rec
Parameter
Units
Conc.
Result
Result
%Rec
% Rec
Limits
RPD
Max
RPD
1,1,2,2-Tetrachloroethane
mg/Kg
0.050
0.050
0.052
102
104
56-126
2.3
20
Tetrachloroethene
mg/Kg
0.050
0.053
0.050
106
101
68-130
5.4
20
Toluene
mg/Kg
0.050
0.050
0.048
101
97.0
71-129
4.4
20
1,2,3-Trichlorobenzene
mg/Kg
0.050
0.056
0.055
112
110
68-130
2.1
20
1,2,4-Trichlorobenzene
mg/Kg
0.050
0.054
0.054
109
110
66-125
0.3
20
1,1,1-Trichloroethane
mg/Kg
0.050
0.051
0.050
103
101
67-131
1.5
20
1,1,2-Trichloroethane
mg/Kg
0.050
0.052
0.054
105
108
70-133
3.1
20
Trichloroethene
mg/Kg
0.050
0.051
0.050
104
101
75-133
2.9
20
Trichlorofluoromethane
mg/Kg
0.050
0.051
0.047
102
94.6
44-146
7.9
20
1,2,3-Trichloropropane
mg/Kg
0.050
0.051
0.054
102
110
60-137
7.3
20
1,3,5-Trimethylbenzene
mg/Kg
0.050
0.050
0.048
101
96.6
69-128
4.0
20
Vinyl Acetate
mg/Kg
0.050
0.051
0.050
103
102
60-140
0.9
20
Vinyl Chloride
mg/Kg
0.050
0.050
0.049
102
98.8
48-147
2.9
20
o-Xylene
mg/Kg
0.050
0.051
0.049
103
98.2
74-126
4.5
20
m,p-Xylene
mg/Kg
0.100
0.105
0.098
105
98.7
75-124
6.1
20
4-Bromofluorobenzene (S)
101
99.6
70-130
Dibromofluoromethane (S)
99.2
103
84-123
Toluene-d8(S)
101
98.4
76-129
Date: 04/19/2023 01:19 PM Page 9 of 16
Page 39 of 48

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Mid -Atlantic Associates, Inc. - Raleigh
Project Description: Liggett & Myers Tobacco Company
Report No: 23-097-0101
QC Prep: V32073
QC Prep Batch Method: 3546
Lab Reagent Blank LRB-V32073
Associated Lab Samples: 93210, 93211, 93212
QC Analytical Batch(es): V32131
Analysis Method: 8270E
Analysis Description: Semivolatile Organic Compounds - GC/MS
Matrix: SOL
Blank MDL MQL Analyzed % % Rec
Parameter Units Result Recovery Limits
Acenaphthene
mg/Kg
<0.116
0.116
0.660
04/18/23 17:52
Acenaphthylene
mg/Kg
<0.105
0.105
0.660
04/18/23 17:52
Aniline
mg/Kg
<0.152
0.152
0.660
04/18/23 17:52
Anthracene
mg/Kg
<0.143
0.143
0.660
04/18/23 17:52
Benzo(a)anthracene
mg/Kg
<0.139
0.139
0.660
04/18/23 17:52
Benzo(a)pyrene
mg/Kg
<0.147
0.147
0.660
04/18/23 17:52
Benzo(b)fluoranthene
mg/Kg
<0.146
0.146
0.660
04/18/23 17:52
Benzo(g,h,i)perylene
mg/Kg
<0.136
0.136
0.660
04/18/23 17:52
Benzo(k)fluoranthene
mg/Kg
<0.137
0.137
0.660
04/18/23 17:52
Benzoic Acid
mg/Kg
<0.580
0.580
2.00
04/18/23 17:52
Benzyl alcohol
mg/Kg
<0.105
0.105
0.660
04/18/23 17:52
Bis(2-Chloroethoxy)methane
mg/Kg
<0.118
0.118
0.660
04/18/23 17:52
Bis(2-Chloroethyl)ether
mg/Kg
<0.107
0.107
0.660
04/18/23 17:52
Bis(2-Chloroisopropyl)ether
mg/Kg
<0.136
0.136
0.330
04/18/23 17:52
Bis(2-ethylhexyl)phthalate
mg/Kg
<0.120
0.120
0.660
04/18/23 17:52
4-Bromophenyl phenyl ether
mg/Kg
<0.109
0.109
0.660
04/18/23 17:52
Butyl benzyl phthalate
mg/Kg
<0.113
0.113
0.330
04/18/23 17:52
4-Chloro-3-methylphenol
mg/Kg
<0.092
0.092
0.660
04/18/23 17:52
4-Chloroaniline
mg/Kg
<0.112
0.112
0.330
04/18/23 17:52
2-Chloronaphthalene
mg/Kg
<0.116
0.116
0.660
04/18/23 17:52
2-Chlorophenol
mg/Kg
<0.098
0.098
0.660
04/18/23 17:52
4-Chlorophenyl phenyl ether
mg/Kg
<0.126
0.126
1.00
04/18/23 17:52
Chrysene
mg/Kg
<0.142
0.142
0.660
04/18/23 17:52
Dibenz(a,h)anth racene
mg/Kg
<0.230
0.230
0.660
04/18/23 17:52
Dibenzofuran
mg/Kg
<0.119
0.119
0.660
04/18/23 17:52
1,2-Dichlorobenzene
mg/Kg
<0.094
0.094
0.660
04/18/23 17:52
1,3-Dichlorobenzene
mg/Kg
<0.097
0.097
0.660
04/18/23 17:52
Date:
04/19/2023 01:19 PM
Page 10 of 16
Page 40 of 48

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Mid -Atlantic Associates, Inc. - Raleigh
Project Description: Liggett & Myers Tobacco Company
Report No: 23-097-0101
QC Prep: V32073
QC Prep Batch Method: 3546
Lab Reagent Blank LRB-V32073
Associated Lab Samples: 93210, 93211, 93212
QC Analytical Batch(es): V32131
Analysis Method: 8270E
Analysis Description: Semivolatile Organic Compounds - GC/MS
Matrix: SOL
Blank MDL MQL Analyzed % % Rec
Parameter Units Result Recovery Limits
1,4-Dichlorobenzene
mg/Kg
<0.097
0.097
0.330
04/18/23 17:52
3,3'-Dichlorobenzidine
mg/Kg
<0.147
0.147
0.660
04/18/23 17:52
2,4-Dichlorophenol
mg/Kg
<0.095
0.095
0.660
04/18/23 17:52
Diethyl phthalate
mg/Kg
<0.180
0.180
0.660
04/18/23 17:52
Dimethyl phthalate
mg/Kg
<0.174
0.174
0.660
04/18/23 17:52
2,4-Dimethylphenol
mg/Kg
<0.108
0.108
0.330
04/18/23 17:52
Di-n-butyl phthalate
mg/Kg
<0.107
0.107
0.660
04/18/23 17:52
4,6- Din itro-2-methylphenol
mg/Kg
<0.240
0.240
1.50
04/18/23 17:52
2,4-Dinitrophenol
mg/Kg
<0.520
0.520
1.50
04/18/23 17:52
2,4-Dinitrotoluene
mg/Kg
<0.096
0.096
0.660
04/18/23 17:52
2,6-Dinitrotoluene
mg/Kg
<0.108
0.108
0.660
04/18/23 17:52
Di-n-Octyl Phthalate
mg/Kg
<0.143
0.143
0.330
04/18/23 17:52
Fluoranthene
mg/Kg
<0.123
0.123
0.660
04/18/23 17:52
Fluorene
mg/Kg
<0.128
0.128
0.660
04/18/23 17:52
Hexachlorobenzene
mg/Kg
<0.106
0.106
0.660
04/18/23 17:52
Hexachlorobutadiene
mg/Kg
<0.097
0.097
0.660
04/18/23 17:52
Hexachlorocyclopentadiene
mg/Kg
<0.157
0.157
0.660
04/18/23 17:52
Hexachloroethane
mg/Kg
<0.079
0.079
0.660
04/18/23 17:52
Indeno(1,2,3-cd)pyrene
mg/Kg
<0.179
0.179
0.660
04/18/23 17:52
Isophorone
mg/Kg
<0.191
0.191
0.660
04/18/23 17:52
1-Methylnaphthalene
mg/Kg
<0.106
0.106
0.660
04/18/23 17:52
2-Methylnaphthalene
mg/Kg
<0.100
0.100
0.660
04/18/23 17:52
2-Methylphenol
mg/Kg
<0.097
0.097
0.660
04/18/23 17:52
3&4 Methylphenol
mg/Kg
<0.084
0.084
0.660
04/18/23 17:52
Naphthalene
mg/Kg
<0.144
0.144
0.660
04/18/23 17:52
2-Nitroaniline
mg/Kg
<0.096
0.096
0.660
04/18/23 17:52
3-Nitroaniline
mg/Kg
<0.120
0.120
0.660
04/18/23 17:52
Date:
04/19/2023 01:19 PM
Page 11 of 16
Page 41 of 48

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Mid -Atlantic Associates, Inc. - Raleigh
Project Description: Liggett & Myers Tobacco Company
Report No: 23-097-0101
QC Prep: V32073 QC Analytical Batch(es): V32131
QC Prep Batch Method: 3546 Analysis Method: 8270E
Analysis Description: Semivolatile Organic Compounds - GC/MS
Lab Reagent Blank LRB-V32073 Matrix: SOL
Associated Lab Samples: 93210, 93211, 93212
Blank
MDL
MQL
Analyzed
%
% Rec
Parameter
Units
Result
Recovery
Limits
4-Nitroaniline
mg/Kg
<0.093
0.093
0.330
04/18/23 17:52
Nitrobenzene
mg/Kg
<0.116
0.116
0.330
04/18/23 17:52
2-Nitrophenol
mg/Kg
<0.088
0.088
0.660
04/18/23 17:52
4-Nitrophenol
mg/Kg
<0.117
0.117
0.660
04/18/23 17:52
N-Nitrosodimethylamine
mg/Kg
<0.263
0.263
0.660
04/18/23 17:52
N-Nitrosodiphenylamine
mg/Kg
<0.181
0.181
0.660
04/18/23 17:52
N-Nitroso-di-n-propylamine
mg/Kg
<0.118
0.118
0.660
04/18/23 17:52
Pentachlorophenol
mg/Kg
<0.347
0.347
1.00
04/18/23 17:52
Phenanthrene
mg/Kg
<0.208
0.208
0.660
04/18/23 17:52
Phenol
mg/Kg
<0.112
0.112
0.660
04/18/23 17:52
Pyrene
mg/Kg
<0.134
0.134
0.660
04/18/23 17:52
Pyridine
mg/Kg
<0.079
0.079
0.330
04/18/23 17:52
1,2,4-Trichlorobenzene
mg/Kg
<0.107
0.107
0.660
04/18/23 17:52
2,4,5-Trichlorophenol
mg/Kg
<0.096
0.096
0.660
04/18/23 17:52
2,4,6-Trichlorophenol
mg/Kg
<0.096
0.096
0.660
04/18/23 17:52
2-Fluorobiphenyl (S)
04/18/23 17:52
98.2
44-115
2-Fluorophenol(S)
04/18/23 17:52
84.0
35-115
Nitrobenzene-d5 (S)
04/18/23 17:52
91.0
37-122
4-Terphenyl-d14 (S)
04/18/23 17:52
112
54-127
2,4,6-Tribromophenol(S)
04/18/23 17:52
83.1
39-132
Phenol-d5(S)
04/18/23 17:52
80.1
34-121
Laboratory Control Sample
LCS-V32073
Spike
LCS
LCS %Rec
% Rec
Parameter
Units
Conc.
Result
Limits
2-Methylphenol
mg/Kg
1.67
1.64
98.2
32-122
Date: 04/19/2023 01:19 PM Page 12 of 16
Page 42 of 48

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Mid -Atlantic Associates, Inc. - Raleigh
Project Description: Liggett & Myers Tobacco Company
Report No: 23-097-0101
QC Prep: V32073 QC Analytical Batch(es): V32131
QC Prep Batch Method: 3546 Analysis Method: 8270E
Analysis Description: Semivolatile Organic Compounds - GC/MS
Laboratory Control Sample & LCSD LCS-V32073 LCSD-V32073
Parameter
Units
Spike
Conc.
LCS
Result
LCSD
Result
LCS
%Rec
LCSD
% Rec
% Rec
Limits
RPD
Max
RPD
Acenaphthene
mg/Kg
1.67
1.60
1.64
95.8
98.2
40-123
2.4
20
Acenaphthylene
mg/Kg
1.67
1.64
1.68
98.2
101
32-132
2.4
20
Aniline
mg/Kg
1.67
2.92
2.79
175
167
12-197
4.5
20
Anthracene
mg/Kg
1.67
1.74
1.83
104
110
47-123
5.0
20
Benzo(a)anthracene
mg/Kg
1.67
1.70
1.81
102
108
49-126
6.2
20
Benzo(a)pyrene
mg/Kg
1.67
1.89
2.00
113
120
45-129
5.6
20
Benzo(b)fluoranthene
mg/Kg
1.67
1.76
1.80
105
108
45-132
2.2
20
Benzo(g,h,i)perylene
mg/Kg
1.67
1.65
1.75
98.8
105
43-134
5.8
20
Benzo(k)fluoranthene
mg/Kg
1.67
1.71
1.88
102
113
47-132
9.4
20
Benzoic Acid
mg/Kg
1.67
<0.580
<0.580
0.0*
0.0*
10-83
0.0
20
Benzyl alcohol
mg/Kg
1.67
1.59
1.57
95.2
94.0
29-122
1.2
20
Bis(2-Chloroethoxy)methane
mg/Kg
1.67
1.71
1.68
102
101
36-121
1.7
20
Bis(2-Chloroethyl)ether
mg/Kg
1.67
1.52
1.44
91.0
86.2
31-120
5.4
20
Bis(2-Chloroisopropyl)ether
mg/Kg
1.67
1.73
1.70
104
102
33-131
1.7
20
Bis(2-ethylhexyl)phthalate
mg/Kg
1.67
1.93
2.02
116
121
51-133
4.5
20
4-Bromophenyl phenyl ether
mg/Kg
1.67
1.68
1.75
101
105
46-124
4.0
20
Butyl benzyl phthalate
mg/Kg
1.67
1.85
1.96
111
117
48-132
5.7
20
4-Chloro-3-methyl phenol
mg/Kg
1.67
1.60
1.62
95.8
97.0
45-122
1.2
20
4-Chloroaniline
mg/Kg
1.67
1.71
1.76
102
105
17-106
2.8
20
2-Chloronaphthalene
mg/Kg
1.67
1.64
1.67
98.2
100
41-114
1.8
20
2-Chlorophenol
mg/Kg
1.67
1.60
1.56
95.8
93.4
34-121
2.5
20
4-Chlorophenyl phenyl ether
mg/Kg
1.67
1.58
1.66
94.6
99.4
45-121
4.9
20
Chrysene
mg/Kg
1.67
1.63
1.77
97.6
106
50-124
8.2
20
Dibenz(a,h)anthracene
mg/Kg
1.67
1.65
1.77
98.8
106
45-134
7.0
20
Dibenzofuran
mg/Kg
1.67
1.62
1.66
97.0
99.4
44-120
2.4
20
1,2-Dichlorobenzene
mg/Kg
1.67
1.43
1.40
85.6
83.8
33-117
2.1
20
* QC Fail Date: 04/19/2023 01:19 PM Page 13 of 16
Page 43 of 48

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Mid -Atlantic Associates, Inc. - Raleigh
Project Description: Liggett & Myers Tobacco Company
Report No: 23-097-0101
QC Prep: V32073 QC Analytical Batch(es): V32131
QC Prep Batch Method: 3546 Analysis Method: 8270E
Analysis Description: Semivolatile Organic Compounds - GC/MS
Laboratory Control Sample & LCSD LCS-V32073 LCSD-V32073
Parameter
Units
Spike
Conc.
LCS
Result
LCSD
Result
LCS
%Rec
LCSD
% Rec
% Rec
Limits
RPD
Max
RPD
1,3-Dichlorobenzene
mg/Kg
1.67
1.40
1.34
83.8
80.2
30-115
4.3
20
1,4-Dichlorobenzene
mg/Kg
1.67
1.40
1.35
83.8
80.8
31-115
3.6
20
3,3'-Dichlorobenzidine
mg/Kg
1.67
1.45
1.67
86.8
100
22-121
14.1
20
2,4-Dichlorophenol
mg/Kg
1.67
1.61
1.64
96.4
98.2
40-122
1.8
20
Diethyl phthalate
mg/Kg
1.67
1.70
1.76
102
105
50-124
3.4
20
Dimethyl phthalate
mg/Kg
1.67
1.72
1.74
103
104
48-124
1.1
20
2,4-Dimethylphenol
mg/Kg
1.67
1.80
2.11
108
126
30-127
15.8
20
Di-n-butyl phthalate
mg/Kg
1.67
1.92
2.03
115
122
51-128
5.5
20
4,6- Din itro-2-methylphenol
mg/Kg
1.67
1.20
1.18
71.8
70.6
29-132
1.6
20
2,4-Dinitrophenol
mg/Kg
1.67
0.888
0.802
53.1
48.0
27-129
10.1
20
2,4-Dinitrotoluene
mg/Kg
1.67
1.68
1.79
101
107
48-126
6.3
20
2,6-Dinitrotoluene
mg/Kg
1.67
1.69
1.78
101
107
46-124
5.1
20
Di-n-Octyl Phthalate
mg/Kg
1.67
1.98
2.07
119
124
45-140
4.4
20
Fluoranthene
mg/Kg
1.67
1.54
1.64
92.2
98.2
50-127
6.2
20
Fluorene
mg/Kg
1.67
1.60
1.68
95.8
101
43-125
4.8
20
Hexachlorobenzene
mg/Kg
1.67
1.69
1.77
101
106
45-122
4.6
20
Hexachlorobutadiene
mg/Kg
1.67
1.58
1.55
94.6
92.8
32-123
1.9
20
Hexachlorocyclopentadiene
mg/Kg
1.67
1.21
1.21
72.4
72.4
32-117
0.0
20
Hexachloroethane
mg/Kg
1.67
1.41
1.33
84.4
79.6
28-117
5.8
20
Indeno(1,2,3-cd)pyrene
mg/Kg
1.67
1.73
1.79
104
107
45-133
3.4
20
Isophorone
mg/Kg
1.67
1.48
1.46
88.6
87.4
30-122
1.3
20
1-Methylnaphthalene
mg/Kg
1.67
1.51
1.53
90.4
91.6
40-119
1.3
20
2-Methylnaphthalene
mg/Kg
1.67
1.54
1.51
92.2
90.4
38-122
1.9
20
3&4 Methylphenol
mg/Kg
1.67
1.45
1.46
86.8
87.4
34-119
0.6
20
Naphthalene
mg/Kg
1.67
1.54
1.52
92.2
91.0
35-123
1.3
20
2-Nitroaniline
mg/Kg
1.67
1.57
1.69
94.0
101
44-127
7.3
20
Date: 04/19/2023 01:19 PM Page 14 of 16
Page 44 of 48

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Mid -Atlantic Associates, Inc. - Raleigh
Project Description: Liggett & Myers Tobacco Company
Report No: 23-097-0101
QC Prep: V32073 QC Analytical Batch(es): V32131
QC Prep Batch Method: 3546 Analysis Method: 8270E
Analysis Description: Semivolatile Organic Compounds - GC/MS
Laboratory Control Sample & LCSD LCS-V32073 LCSD-V32073
Spike LCS LCSD LCS LCSD % Rec
Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max
RPD
3-Nitroaniline
mg/Kg
1.67
1.57
1.69
94.0
101
33-119
4-Nitroaniline
mg/Kg
1.67
1.75
1.82
105
109
63-147
Nitrobenzene
mg/Kg
1.67
1.50
1.46
89.8
87.4
34-122
2-Nitrophenol
mg/Kg
1.67
1.62
1.54
97.0
92.2
36-123
4-Nitrophenol
mg/Kg
1.67
1.66
1.79
99.4
107
30-132
N-Nitrosodimethylamine
mg/Kg
1.67
1.25
1.20
74.8
71.8
10-146
N-Nitrosodiphenylamine
mg/Kg
1.67
2.02
2.14
121
128*
38-127
N-Nitroso-di-n-propylamine
mg/Kg
1.67
1.57
1.51
94.0
90.4
36-120
Pentachlorophenol
mg/Kg
1.67
1.40
1.53
83.8
91.6
25-133
Phenanthrene
mg/Kg
1.67
1.65
1.73
98.8
104
50-121
Phenol
mg/Kg
1.67
1.52
1.49
91.0
89.2
34-121
Pyrene
mg/Kg
1.67
1.67
1.78
100
107
47-127
Pyridine
mg/Kg
1.67
0.724
0.575
43.3
34.4
10-80
1,2,4-Trichlorobenzene
mg/Kg
1.67
1.50
1.48
89.8
88.6
34-118
2,4,5-Trichlorophenol
mg/Kg
1.67
1.62
1.67
97.0
100
41-124
2,4,6-Trichlorophenol
mg/Kg
1.67
1.58
1.62
94.6
97.0
39-126
2-Fluorobiphenyl (S)
102
98.8
44-115
2-Fluorophenol (S)
87.0
82.2
35-115
Nitrobenzene-d5 (S)
92.8
88.6
37-122
4-Terphenyl-d14(S)
113
113
54-127
2,4,6-Tribromophenol(S)
92.7
93.0
39-132
Phenol-d5(S)
82.8
79.2
34-121
7.3
3.9
2.7
5.0
7.5
4.0
5.7
3.8
8.8
4.7
1.9
6.3
22.9*
1.3
3.0
2.5
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
* QC Fail Date: 04/19/2023 01:19 PM Page 15 of 16
Page 45 of 48

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypo i nta na lytica l.cam
Quality Control Data
Client ID: Mid -Atlantic Associates, Inc. - Raleigh
Project Description: Liggett & Myers Tobacco Company
Report No: 23-097-0101
QC Analytical Batch: V31771
Analysis Method: SW-DRYWT
Analysis Description: Dry Weight Determination
Duplicate V 93200-DUP
Result DUP
Parameter Units Result
Moisture % 17.7 17.4
Duplicate V 93206-DUP
RPD Max RPD Analyzed
1.7 20.0 04/08/23 09:30
Result DUP RPD Max RPD Analyzed
Parameter Units Result
Moisture % 18.4 19.3 4.7 20.0 04/08/23 09:30
Date: 04/19/2023 01:19 PM Page 16 of 16
Page 46 of 48

WayPAo0nt..
NALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.wa y p of n to na lyti ca I.c om
Shipment Receipt Form
Customer Number: 01139
Customer Name: Mid -Atlantic Associates, Inc. -Raleigh
Report Number: 23-097-0101
Shipping Method
0 Fed Ex 0 US Postal * Lab 0 Other:
0 UPS 0 Client 0 Courier Thermometer ID: IRT 3.6C
Shipping container/cooler uncompromised?
0 Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
* Yes
0 No
COC agrees with sample label(s)?
0 Yes
0 No
COC properly completed
Yes
0 No
Samples in proper containers?
Yes
0 No
Sample containers intact?
0 Yes
0 No
Sufficient sample volume for indicated test(s)?
Yes
0 No
All samples received within holding time?
Yes
0 No
Cooler temperature in compliance?
0 Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes
0 No
Water - Sample containers properly preserved
Yes
0 No
0 N/A
Water - VOA vials free of headspace
Yes
0 No
0 N/A
Trip Blanks received with VOAs Yes 0 No 0 N/A
Soil VOA method 5035 — compliance criteria met Yes 0 No 0 N/A
F High concentration container (48 hr) Low concentration EnCore samplers (48 hr)
High concentration pre -weighed (methanol -14 d) ✓ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes 0 No
Comments:
Signature: Angela D Overcash Date & Time: 04/07/2023 13:54:54
Page 47 of 48

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Page 48 of 48

ATTACHMENT F
RISK CALCULATIONS
10 Mid Atlantic

North Carolina DEC Risk Calculator

North Carolina DEQ Risk Calculator