WS-2480_3596_CA_MRP_20150220

February 2015 Semiannual
Groundwater Sampling Report
Highland Industries/Takada
Incident #3596
Kernersville, North Carolina
February 20, 2015

Prepared For

Highland Industries/Takada
Kernersville, North Carolina

Prepared By

Waters Edge Environmental, LLC
Raleigh, North Carolina

WATERS EDGE ENVIRONMENTAL, LLC
4901 WATERS EDGE DRIVE, SUITE 201  RALEIGH, NC 27606  PHONE [phone]  FAX [phone]

February 20, 2015

Mr. Michael Rogers
North Carolina Department of Environment and Natural Resources
Division of Water Quality
Groundwater Section
450 Haynes Mill Road
Winston-Salem, NC 27105

Reference: February 2015 Semiannual Groundwater Sampling Results
Highland Industries/Takada
Kernersville, North Carolina
Waters Edge Job No. R1-06

Dear Mr. Rogers:

Waters Edge Environmental, LLC (Waters Edge) is pleased to submit this report
summarizing the most recent semiannual sampling event conducted on February 2, 2015
at the Kernersville site. The monitoring wells were sampled as specified in our revised
November 14, 2005 CAP required by the NCDENR; Division of Water Quality permit
number WQ0006751.

Current results indicate that total VOCs are ND in all perimeter monitoring wells for the
first time since the project began in the early 1990s. These results are considered
significant in that the plume has now shrunk within the Subject Property and the
remaining plume is centered around the extraction well. Since the influent to the system
still has elevated total VOCs, we would still conclude that the system needs to continue to
operate until the influent total VOC concentrations approach NCGSs.
At present, Waters Edge recommends continued semiannual sampling of groundwater
monitoring wells MW-1, MWR-6s, MWR-7 and MW-10 as well as influent to the
treatment system and the effluent from the treatment system on a quarterly basis. We are
currently scheduled to return to the site to conduct the next semiannual sampling event in
July 2015.
February 2015 Semiannual Groundwater Sampling Report
Highland Industries/Takada Site
Kernersville, NC
February 20, 2015
Page 2 of 2

If you have any questions or comments regarding this report, please contact Phillip L.
Rahn at 919.859.9987 or [e-mail].

Sincerely,

WATERS EDGE ENVIRONMENTAL, LLC.

Phillip L. Rahn, P.G.
President

15-017/PLR/aht

cc: Mr. Brian Roan– Highland Industries/Takada

iii

Table of Contents

1 Background 1
2 Groundwater Sampling Activities 2
2.1 Water Table Conditions 2
2.3 Groundwater Sampling 2
2.3 Influent/Effluent Sampling 2
3 Analytical Results 3
3.1 Monitoring Well Resultss 3
3.2 Remediation System Status 3
4 Conclusions and Recommendations 3

iv
Figures

Figure No. Title

1 Site Location Map
2 February 2015 Groundwater Contour Map

Tables

Table No. Title

1 Groundwater Elevation Data
2 Groundwater Analytical Results

Appendices

Appendix Title

A Laboratory Analytical Results
B GW-59 Forms

Acronym List
AFVR Aggressive Fluid Vapor Recovery

AOC area of concern

Aquaterra Aquaterra Engineering, Inc.

AS Air Sparging

BGS below ground surface

Burlington Burlington Resolution Trust

CAP Corrective Action Plan

DWQ Division of Water Quality

Ft/ft Foot per foot

GPD Gallons per Day

mg/kg milligrams per kilograms or parts per million

NCGS North Carolina Groundwater Standards

ND Non-Detect

MSL Mean Sea Level

NCDENR North Carolina Department of Environmental and Natural
Resources

NCGS North Carolina Groundwater Standards

O&M Operations & Maintenance

SVE Soil Vacuum Extraction

USEPA United States Environmental Protection Agency

UST Underground Storage Tank

VOCs volatile organic compounds

Waters Edge Waters Edge Environmental, LLC

Page 1 of 4
February 2015 Semiannual
Groundwater Sampling Results
Former Burlington Resolution Trust Site
Kernersville, North Carolina
February 20, 2015

1 Background

On behalf of Highland Industries/Takada (Highland), Waters Edge Environmental, LLC
(Waters Edge) is pleased to present the February 2015 Semiannual Groundwater Sampling
Results for the former Burlington Industries Facility located in Kernersville, North
Carolina. The site location map is shown as Figure 1.

Burlington formerly owned and operated a textile finishing plant located in Kernersville,
North Carolina (see Figure 1). Soil and groundwater assessment activities conducted in
1988 by Aquaterra revealed that a toluene release had occurred from at least one toluene
UST at the site. Eleven shallow groundwater monitoring wells were installed in 1988 to
determine the horizontal extent of toluene contamination (see Figure 2). In addition, two
intermediate monitoring wells and one deep-bedrock monitoring well were installed in the
intermediate vicinity of the toluene release to determine the vertical extent of
contamination.

In March 1990, groundwater extraction was initiated at well EW-6. During December
1990, the PVC well screens in wells EW-6, MW-6s, and MW-7 failed. These wells have
since been replaced with wells EWR-6, MWR-6s, and MWR-7, respectively. In May
1991, groundwater extraction at EWR-6 was initiated to reverse the migration of dissolved
toluene in the shallow groundwater.

Extracted groundwater is being treated by air stripping with activated carbon polishing
prior to discharge to an infiltration trench. The effluent discharge rate is limited to 8,640
gallons per day in accordance to the requirements of the non-discharge permit number
WQ0006751 as issued by the NCDENR, DWQ.

Air sparging and vapor extraction units were installed outside of the plant in early 1994.
These units were installed to assist the groundwater extraction system in remediating
groundwater impacted by the toluene release.

Three shallow monitoring wells (MW-12, MW-13, and MW-14) were installed in the
manufacturing plant in June 1998 and first sampled on January 13, 1998. The results of
the January 1998 sampling showed that MW-13 detected 380,000 g/L of toluene and
MW-14 detected 97,000 g/L of toluene. The August/September 1999 sampling event
detected free product in MW-13 and 460,000 g/L of toluene in MW-14.

In addition, AFVR was started in 1999 on MW-13 to recover the free-phase toluene.
Three AFVR events occurred before the well collapsed in December 1999 due to
February 2015 Semiannual Groundwater Sampling Report
Highland Industries/Takada
Kernersville, NC
February 20, 2015
15-017

Page 2 of 4
interaction between the PVC well material and the free-phase toluene present in the
groundwater.

In December 1999, Aquaterra installed five AS and SVE points inside the building in the
vicinity of monitoring wells MW-12, MW-13, and MW-14. In addition, three AS/SVE
points were also installed between the building and the railroad tracks to the northeast.

In December 2000, Waters Edge installed a replacement well in close proximity to the
collapsed well MW-13. This well, designated MWR-13, is comprised of 2” stainless-steel
screen and riser to provide resistance against interaction with the high concentrations of
toluene present in the area. MWR-13 was initially sampled during the January 2001
sampling event, demonstrating a toluene concentration of 360,000 g/L.

Three AFVR events have been conducted at this location, resulting in the elimination of
the free-phased toluene previously present in MWR-13. The thin film of free product
detected in MWR-7 during 2008 was not present during this sample event.

Below, we have described the field sampling procedures, laboratory analytical results
along with our conclusions and recommendations for the site.

2 Groundwater Sampling Activities

2.1 Water Table Conditions

During the February 2nd, 2015 groundwater sampling event, depth to water measurements
were collected from monitoring wells on and off-site (see Table 1). Water level data were
used to generate a shallow groundwater contour map (see Figure 2). Based on the
collected data, shallow groundwater appears to be migrating in a northeasterly direction in
response to a hydraulic gradient of 0.0071 foot/foot.

2.3 Groundwater Sampling

On February 2nd, 2015, Waters Edge representatives sampled wells MW-1, MW-6s,
MWR-7 and MW-10 in accordance with EPA-accepted procedures. These groundwater
samples were transported to Pace Analytical (Pace) located in Huntersville, North Carolina
and analyzed for VOCs according to EPA Method 6200B (see Table 2 and Appendix A).

February 2015 Semiannual Groundwater Sampling Report
Highland Industries/Takada
Kernersville, NC
February 20, 2015
15-017

Page 3 of 4
2.3 Influent/Effluent Sampling

On February 2nd, 2015, the influent and the effluent were sampled according to EPA-
accepted procedures. These water samples were transported to Pace Analytical (Pace)
located in Huntersville, North Carolina and analyzed for VOCs according to EPA Method
6200B. As specified in the permit, we have included Form GW-59 in Appendix B.

3 Analytical Results

3.1 Monitoring Well Results

For the second time since October 5, 2000, MWR-7 was below NCGS and was also ND.
Monitoring wells MW-1, MW-6s, and MW-10 were also ND indicating the plume is well
defined horizontally and coupled and shrinking closer to the groundwater extraction wells.
Based on these total ND VOC levels, a shallow total VOC contour map is not required.

3.2 Remediation System Status

The influent sample detected 21,730 g/L toluene and the effluent sample detected 120
g/L toluene which represents a 99.99% reduction which is above the specifications in the
permit (95% reduction) and the effluent results are below NCGS. The recent O&M
performed on the system appears to have been successful. Based on the totalizer readings,
the system is pumping approximately 3,313 GPD.

4 Conclusions and Recommendations

Based on the field activities, the static water level data, and laboratory analytical results,
we conclude the following:

 Toluene concentrations in monitoring well MWR-7 were below the NCGS
for toluene for the second time since October 5, 2000 and are also ND
which is very encouraging.
 VOC concentrations in wells MW-1, MW-6s, and MW-10 were ND. This
is considered significant in that this is the first time all perimeter wells are
now below NCGSs and we can conclude that the plume has now shrunk and
would now be considered to exist only inside the Subject Property near the
extraction well. Even though all perimeter monitoring wells are now below
NCGSs, the system should still continue to operate since the influent
sample is still detecting elevated total VOC concentrations.
February 2015 Semiannual Groundwater Sampling Report
Highland Industries/Takada
Kernersville, NC
February 20, 2015
15-017

Page 4 of 4
 The remediation system is achieving a 99.99% reduction which is within
the specifications in the permit (95% reduction) and effluent results are
below NCGS. The remediation system is pumping approximately 3,313
GPD.
 Based on the above, Waters Edge recommends continued semiannual
sampling in wells MW-1, MW-6s, MWR-7 and MW-10 as well as the
quarterly sampling of the influent and effluent from the treatment system.

Figures
AuthorDrawing LayersDateTitleR1-06.xls3/4/2003Job No. Revision Figure ScaleR1-06 11/3/2005 1 as shownKernersville, North CarolinaHighland Industries, Inc.Project Location MapWATERS EDGE ENVIRONMENTAL, LLCProjectSITE

Tables
Table 1
Static Water Level Elevations Data
Takada / Former Highland Industries
Kernersville, NC
Well No. Top of Casing Depth to Water Groundwater Elevation
MW-1 997.58 15.35 982.23
MW-2I 997.47 NM NC
MWR-6s 1006.14 25.29 980.85
MW-6I 1006.68 NM NC
MWR-7 1013.26 32.65 980.61
MW-9 1008.19 NM NC
MW-10 1013.63 36.37 977.26
MW-11 1012.77 NM NC
MW-12 1008.97 NM NC
MWR-13 NM NM NC
MW-14 1008.88 NM NC
February 2, 2015
All units in feet.
NM - Not Measured
NC - Not Calcuable
Waters Edge Job No. R1-06
Takata.xlsx.xls, GW Elev Calc
Table 2. Groundwater Analytical Results, Takada/Former Highland Industries, Inc., Kernersville, NCMW-1Compound NCGS 2/7/1991 5/22/1991 8/20/1991 11/14/1991 2/11/1992 7/17/1992 10/6/1992 12/14/1992Benzene 1........Ethylbenzene 600 15.45.......Toluene 600 2,300 320 1,500 1,500 3,300 1,500 14 74Xylenes 500 25.......Chloroform 70 NA NA NA NA NA NA NA NATetrachloroethene 0.7 33 NA NA NA NA NA NA NATotal VOCs2,400 320 1,500 1,500 3,300 1,500 14 7436.48 Compound NCGS 3/8/1993 9/1/1993 1/13/1994 5/3/1994 7/27/1994 10/24/1994 1/17/1995 7/13/1995Benzene 1........Ethylbenzene 600........Toluene 600 1 . . 8 . 5 . .Xylenes 500........Chloroform 70 NA NA NA NA NA NA NA NATetrachloroethene 0.7 NA NA NA NA NA NA NA NATotal VOCs1. .8 .5 . . Compound NCGS 1/22/1996 1/12/1998 7/13/1998 2/4/1999 9/17/1999 12/20/1999 3/20/2000 7/24/2000Benzene 1 . . ...NS.NSEthylbenzene 600 . . ...NS.NSToluene 600 . . ..2.1 NS 1.7 NSXylenes 500 . . ...NS.NSChloroform 70 NA NA NA..NS.NSTetrachloroethene 0.7 NA NA NA..NS.NSTotal VOCs....2.1 NS 1.7 NSAll units in ug/L. Blank cells indicate Below Quantitation Limits (BQL).VOCs - Volatile Organic CompoundsNCSG - NC Groun Water StandardNA - Not AnalyzedNS - Not Sampled* - Duplicate Sample
Table 2. Groundwater Analytical Results, Takada/Former Highland Industries, Inc., Kernersville, NCMW-1 (continued)Compound NCGS 10/5/2000 1/4/2001 3/23/2001 5/31/2001 8/23/2001 12/11/2001 3/13/2002 6/25/2002Benzene 1........Ethylbenzene 600........Toluene 600 24.......Xylenes 500........Chloroform 70........Tetrachloroethene 0.7........Total VOCs24.......Compound NCGS 9/16/2002 12/31/2002 3/19/2004 6/14/2004 9/16/2004 1/21/2005 3/24/2005 11/2/2005Benzene 1........Ethylbenzene 600........Toluene 600........Xylenes 500........Chloroform 70........Tetrachloroethene 0.7........Total VOCs........ Compound NCGS 5/24/2007 1/28/2008 1/26/2009 7/31/2009 1/27/2010 7/28/2010 1/19/2011 7/18/2011Benzene 1........Ethylbenzene 600........Toluene 600........Xylenes 500........Chloroform 70........Tetrachloroethene 0.7........Total VOCs........All units in ug/L. Blank cells indicate Below Quantitation Limits (BQL).VOCs - Volatile Organic CompoundsNCSG - NC Groun Water StandardNA - Not AnalyzedNS - Not Sampled* - Duplicate Sample
Table 2. Groundwater Analytical Results, Takada/Former Highland Industries, Inc., Kernersville, NCMW-1 (continued)Compound NCGS 1/24/2012 7/26/2012 1/31/2013 7/31/2013 1/31/2014 8/4/2014 2/2/2015Benzene 1.......Ethylbenzene 600.......MTBE 20 . . . 0.64 . 0.84 .Toluene 600.......Xylenes 500.......Chloroform 70.......Tetrachloroethene 0.7.......Total VOCs.....0.84 .All units in ug/L. Blank cells indicate Below Quantitation Limits (BQL).VOCs - Volatile Organic CompoundsNCSG - NC Groun Water StandardNA - Not AnalyzedNS - Not Sampled* - Duplicate Sample
Table 2. Groundwater Analytical Results, Takada/Former Highland Industries, Inc., Kernersville, NCMW-6sCompound NCGS 5/22/1991 8/20/1991 11/14/1991 2/11/1992 7/17/1992 10/6/1992 12/14/1992 3/8/1993Benzene 1.....9,900 . .1,2-Dichlorobenzene2015.......1,3-Dichlorobenzene200........1,4-Dichlorobenzene625.......Ethylbenzene 600........Toluene 600 33 340,000 490,000 410,000 420,000 390,000 490,000 1,600,000Xylenes 500.......110,000Total VOCs36 340,000 490,000 410,000 420,000 399,900 490,000 1,710,000Compound NCGS 9/1/1993 1/13/1994 5/3/1994 7/27/1994 10/24/1994 1/17/1995 7/13/1995 1/22/1996Benzene 1.......940,0001,2-Dichlorobenzene20........1,3-Dichlorobenzene200........1,4-Dichlorobenzene6........Ethylbenzene 600.......980,000Toluene 600 251,000 580,000 33,000 2,000,000 500,000 900,000 640,000 2,000,000Xylenes 500.......2,800,000Total VOCs251,000 580,000 33,000 2,000,000 500,000 900,000 640,000 6,720,000Compound NCGS 7/11/1996 7/13/1998 1/28/1999 8/12/1999 12/20/1999 3/20/2000 7/24/2000 10/5/2000Benzene 1 14,000 . . 1.9 5.1 . . NS1,2-Dichlorobenzene20.......NS1,3-Dichlorobenzene200.......NS1,4-Dichlorobenzene6.......NSEthylbenzene 600 30,000 . . 7.6 14 33 . NSToluene 600 330,000 9.6 240,000 58,000 120,000 140,000 45,000 NSXylenes 500 25,000 . . 9 16.8 . . NSTotal VOCs399,000 9.6 240,000 58,018.5 120,036 140,033 45,000 NSAll units in ug/L. Blank cells indicate Below Quantitation Limits (BQL).VOCs - Volatile Organic CompoundsNCSG - NC Groun Water StandardNA - Not AnalyzedNS - Not Sampled* - Duplicate Sample
Table 2. Groundwater Analytical Results, Takada/Former Highland Industries, Inc., Kernersville, NCMWR-6s (continued)Compound NCGS 1/4/2001 3/23/2001 5/31/2001 8/23/2001 12/12/2001 3/13/2002 6/25/2002 9/16/2002Benzene 1.......NA1,2-Dichlorobenzene20......NANA1,3-Dichlorobenzene200......NANA1,4-Dichlorobenzene6......NANAEthylbenzene 600......38NAToluene 600 20,000 280 2,400 100,000 210,000 19 24,000 60,000Xylenes 500 3.3.....41.6 NATotal VOCs20,003 280 2,400 100,000 210,000 19 24,080 60,000Compound NCGS 12/31/2002 6/9/2003 9/16/2004 1/21/2005 3/24/2005 11/2/2005 5/24/2007 1/28/2008Benzene 1........1,2-Dichlorobenzene20........1,3-Dichlorobenzene200........1,4-Dichlorobenzene6........Ethylbenzene 600.......1.2Toluene 600 6,200 . . 60 . . 4.81,100Xylenes 500........Total VOCs6,200 . . 60 0 0 4.8 1,101.2Compound NCGS 1/26/2009 7/31/2009 1/27/2010 7/28/2010 1/19/2011 7/18/2011 1/24/2012 7/26/2012Benzene 1........1,2-Dichlorobenzene20........1,3-Dichlorobenzene200........1,4-Dichlorobenzene6........Ethylbenzene 600 . 11.....34.3Naphthalene 6.......2.4Toluene 600162,000 23,90098 1226,900 32,70013873,600Xylenes 500 . 15 15....57.1Total VOCs162,000 23,926 113 12 26,900 32,700 138 73,693.841,851All units in ug/L. Blank cells indicate Below Quantitation Limits (BQL).VOCs - Volatile Organic CompoundsNCSG - NC Groun Water StandardNA - Not AnalyzedNS - Not Sampled* - Duplicate Sample
Table 2. Groundwater Analytical Results, Takada/Former Highland Industries, Inc., Kernersville, NCMWR-6s (continued)Compound NCGS 1/31/2013 7/31/2013 1/31/2014 8/4/2014 2/2/2015Benzene 1.....1,2-Dichlorobenzene20.....1,3-Dichlorobenzene200.....1,4-Dichlorobenzene6.....Ethylbenzene 600.....Naphthalene 6.....Toluene 60019,20017...Xylenes 500.....Total VOCs19,200 17 . . .All units in ug/L. Blank cells indicate Below Quantitation Limits (BQL).VOCs - Volatile Organic CompoundsNCSG - NC Groun Water StandardNA - Not AnalyzedNS - Not Sampled* - Duplicate Sample
Table 2. Groundwater Analytical Results, Takada/Former Highland Industries, Inc., Kernersville, NCMWR-7*Compound NCGS 5/22/1991 8/20/1991 8/20/1991 11/14/1991 7/17/1992 10/6/1992 12/14/1992Benzene 1....NS..1,2-Dichlorobenzene20 15 . . . NS . .1,3-Dichlorobenzene200....NS..1,4-Dichlorobenzene625...NS..Ethylbenzene 600....NS..Toluene 60033 89,000 75,000 400,000NS100,000 76,000Xylenes 500....NS.2,000Total VOCs36 89,000 75,000 400,000 NS 100,000 78,000Compound NCGS 3/8/1993 9/1/1993 1/13/1994 5/3/1994 10/24/1994 1/24/1995 7/13/1995Benzene 1.......1,2-Dichlorobenzene20.......1,3-Dichlorobenzene200.......1,4-Dichlorobenzene6.......Ethylbenzene 600.......Toluene 600200,000 102,000 150,000 45,000 14,000 . 240,000Xylenes 500.......Total VOCs200,000 102,000 150,000 45,000 14,000 . 240,000*Compound NCGS 1/22/1996 7/15/1997 1/12/1998 7/13/1998 1/28/1999 8/12/1999 12/20/1999Benzene 1 . . . NS . . .1,2-Dichlorobenzene20...NS...1,3-Dichlorobenzene200...NS...1,4-Dichlorobenzene6...NS...Ethylbenzene 600 . . 31 NS 15 39 2Toluene 600640,0002631,000NS3,500 47,00044Xylenes 500 . . 27 NS 11 39.8 .Total VOCs640,000 26 31,058 NS 3,526 47,078.8 46All units in ug/L. Blank cells indicate Below Quantitation Limits (BQL).VOCs - Volatile Organic CompoundsNCSG - NC Groun Water StandardNA - Not AnalyzedNS - Not Sampled* - Duplicate Sample
Table 2. Groundwater Analytical Results, Takada/Former Highland Industries, Inc., Kernersville, NCMWR-7 (continued)Compound NCGS 3/20/2000 7/25/2000 10/5/2000 1/3/2001 5/31/2001 8/23/2001 12/11/2001Benzene 1....2.9..1,2-Dichlorobenzene20.......1,3-Dichlorobenzene200.......1,4-Dichlorobenzene6.......Ethylbenzene 600 . . . 8.4 17 . .Toluene 600 .8,200 . 22,000 38,000 120,000 150,000Xylenes 500 . . . 8 26 . .Total VOCs. 8,200 . 22,016 38,046 120,000 150,000Compound NCGS 3/13/2002 6/26/2002 12/1/2003 3/19/2004 9/16/2004 1/20/2005 3/24/2005Benzene 1 .6.6.....1,2-Dichlorobenzene20.NA.....1,3-Dichlorobenzene200.NA.....1,4-Dichlorobenzene6.NA.....Ethylbenzene 600 . 70.....Toluene 600190,000 210,000 35,000 130,000 160,000 370,000 310,000Xylenes 500 . 72.2.....Total VOCs190,000 210,149 35,000 130,000 160,000 370,000 310,000Compound NCGS 11/2/2005 5/24/2007 2/1/2008 1/26/2009 1/27/2010 7/28/2010 1/19/2011Benzene 1.......1,2-Dichlorobenzene20.......1,3-Dichlorobenzene200.......1,4-Dichlorobenzene6.......Ethylbenzene 600 . 4.9 . . 24 . .Toluene 60055,000 30,000 44,900 226,000 37,700 38,100 1,700Xylenes 500 . 3.0 . . 21 . 20Total VOCs55,000 30,007.9 44,900.0 226,000 37,745 38,100 1,720All units in ug/L. Blank cells indicate Below Quantitation Limits (BQL).VOCs - Volatile Organic CompoundsNCSG - NC Groun Water StandardNA - Not AnalyzedNS - Not Sampled* - Duplicate Sample
Table 2. Groundwater Analytical Results, Takada/Former Highland Industries, Inc., Kernersville, NCMWR-7 (continued)Compound NCGS 7/18/2011 1/24/2012 7/26/2012 1/31/2013 1/31/2014 8/4/2014 2/2/2015Benzene 1.......1,2-Dichlorobenzene20.......1,3-Dichlorobenzene200.......1,4-Dichlorobenzene6.......Ethylbenzene 600....6.7..Naphthalene 6 . . .555...Toluene 6005,250 3,800 42,000 42,100 69890 .Xylenes 500....10.5 . .Total VOCs5,250 3,800 42,000 42,655 715.2 90 .All units in ug/L. Blank cells indicate Below Quantitation Limits (BQL).VOCs - Volatile Organic CompoundsNCSG - NC Groun Water StandardNA - Not AnalyzedNS - Not Sampled* - Duplicate Sample
Table 2. Groundwater Analytical Results, Takada/Former Highland Industries, Inc., Kernersville, NCMW-10 **Compound NCGW 2/7/1991 2/7/1991 5/22/1991 8/2/1991 11/14/1991 2/11/1992 2/11/1992 7/17/1992Benzene 1........1,2-Dichlorobenzene 20 15.......1,3-Dichlorobenzene 200........1,4-Dichlorobenzene 6 25.......Ethylbenzene600........Toluene 600 33 . 13 . 71 . 3 .Xylenes500........Total VOCs36 . 13 . 71 . 3 .Compound NCGW 10/6/1992 12/14/1992 3/8/1993 9/1/1993 1/13/1994 5/3/1994 7/27/1994 10/24/1994Benzene 1 . . . NS . NS NS NS1,2-Dichlorobenzene 20 . . . NS . NS NS NS1,3-Dichlorobenzene 200 . . . NS . NS NS NS1,4-Dichlorobenzene 6 . . . NS . NS NS NSEthylbenzene600 . . . NS . NS NS NSToluene 600 . . . NS . NS NS NSXylenes500 . . . NS . NS NS NSTotal VOCs. . . NS . NSNSNSCompound NCGW 1/24/1995 1/2/1997 7/15/1997 1/12/1998 7/13/1998 1/28/1999 9/20/1999 12/20/1999Benzene 1 . . NS . NS . ..1,2-Dichlorobenzene 20 . . NS . NS . ..1,3-Dichlorobenzene 200 . . NS . NS . ..1,4-Dichlorobenzene 6 . . NS . NS . ..Ethylbenzene600 . . NS . NS . ..Toluene 600 . . NS . NS . ..Xylenes500 . . NS . NS . ..Total VOCs. . NS . NS . ..All units in ug/L. Blank cells indicate Below Quantitation Limits (BQL).VOCs - Volatile Organic CompoundsNCSG - NC Groun Water StandardNA - Not AnalyzedNS - Not Sampled* - Duplicate Sample
Table 2. Groundwater Analytical Results, Takada/Former Highland Industries, Inc., Kernersville, NCMW-10 (Continued)Compound NCGW 3/20/2000 7/24/2000 10/5/2000 1/3/2001 5/31/2001 12/12/2001 6/26/2002 1/20/2003Benzene 1 NS NS NS.....1,2-Dichlorobenzene 20 NS NS NS . . . NA .1,3-Dichlorobenzene 200 NS NS NS . . . NA .1,4-Dichlorobenzene 6 NS NS NS . . . NA .Ethylbenzene600NSNSNS.....Toluene 600 NS NS NS . . . 6.3 .Xylenes500NSNSNS.....Total VOCsNS NS NS . . . 6.3 .Compound NCGW 6/10/2003 12/1/2003 5/24/2007 8/2/2011 7/26/2012 1/31/2013 7/31/2013 1/31/2014Benzene 1........1,2-Dichlorobenzene 20........1,3-Dichlorobenzene 200........1,4-Dichlorobenzene 6........Ethylbenzene600........Toluene 600........Xylenes500........Total VOCs........MW-10 (Continued)Compound NCGW 8/4/2014 2/2/2015Benzene 1 . .1,2-Dichlorobenzene 20 . .1,3-Dichlorobenzene 200 . .1,4-Dichlorobenzene 6 . .Ethylbenzene 600 . .Toluene 600 . .Xylenes 500 . .Total VOCs..All units in ug/L. Blank cells indicate Below Quantitation Limits (BQL).VOCs - Volatile Organic CompoundsNCSG - NC Groun Water StandardNA - Not AnalyzedNS - Not Sampled* - Duplicate Sample
Table 2. Groundwater Analytical Results, Takada/Former Highland Industries, Inc., Kernersville, NCInfluentCompound NCGW 4/14/08 7/30/08 10/21/08 1/26/09 4/30/09 7/31/09 1/27/10 4/21/10Benzene 1 . .2.7..1,2-Dichlorobenzene 20 15 . . .1,3-Dichlorobenzene 200 . . . .1,4-Dichlorobenzene 6 25 . . .Ethylbenzene600 . . 18 . .Naphthalene 6 33 4.0 . .Toluene 60065,900 117,000 111,000 32,500 67,800 145,000 117,000 37,600Xylenes500 36 . 22 . .Total VOCs66,010 117,000 111,000 32,500 67,800 145,046.7 117,000 37,600Compound NCGW 7/28/10 1/19/11 7/18/11 1/24/12 7/26/12 1/31/13 7/31/13 1/31/14Benzene 1........1,2-Dichlorobenzene 20........1,3-Dichlorobenzene 200........1,4-Dichlorobenzene 6........Ethylbenzene600........Naphthalene 6........Toluene 60073,100 91,400 66,600 127,000 41,400 43,300 38,500 59,900Xylenes500........Total VOCs73,100 91,400 66,600 127,000 41,400 43,300 38,500 59,900Compound NCGW 8/4/14 2/2/15Benzene 1 .1401,2-Dichlorobenzene 20 . .1,3-Dichlorobenzene 200 . .1,4-Dichlorobenzene 6 . .Ethylbenzene 600 . .Naphthalene 6 . .Toluene 60029,600 21,300Xylenes 500 . 290Total VOCs29,600 21,730All units in ug/L. Blank cells indicate Below Quantitation Limits (BQL).VOCs - Volatile Organic CompoundsNCSG - NC Groun Water StandardNA - Not AnalyzedNS - Not Sampled* - Duplicate Sample
Table 2. Groundwater Analytical Results, Takada/Former Highland Industries, Inc., Kernersville, NCEffluentCompound NCGS 5/24/07 1/28/08 2/14/08 4/14/08 7/30/08 10/21/08 1/26/09 4/30/09Benzene 1........1,2-Dichlorobenzene 20 15.......1,3-Dichlorobenzene 200........1,4-Dichlorobenzene 6 25.......Ethylbenzene 600........Methyl-tert-butyl ether 20 33.......Toluene 60086 2,000 1,800 990 2,300 27,500 1,400 2,800Xylenes 500 36.......Total VOCs196 2,000 1,800 990 2,300 27,500 1,400 2,800Compound NCGS 7/31/09 1/27/10 4/21/10 7/28/10 1/19/11 7/18/11 1/24/12 7/26/12Benzene 1 0.8841......1,2-Dichlorobenzene 20........1,3-Dichlorobenzene 200........1,4-Dichlorobenzene 6........Ethylbenzene 600 0.53 10......Methyl-tert-butyl ether 20 .69......Toluene 6005,300 8,500 3,100. 54 6.7 45.3 40.6Xylenes 500 . 41......Total VOCs5,301.41 8,661 3,100 0 54 6.7 45.3 40.6All units in ug/L. Blank cells indicate Below Quantitation Limits (BQL).VOCs - Volatile Organic CompoundsNCSG - NC Groun Water StandardNA - Not AnalyzedNS - Not Sampled* - Duplicate Sample
Table 2. Groundwater Analytical Results, Takada/Former Highland Industries, Inc., Kernersville, NCEffluent (continued)Compound NCGS 1/31/13 7/31/13 1/31/14 8/4/14 2/2/15Benzene 1 . 0.84 . . .1,2-Dichlorobenzene 20.....1,3-Dichlorobenzene 200.....1,4-Dichlorobenzene 6.....Ethylbenzene 600.....Methyl-tert-butyl ether 20.....Toluene 600 1872,40047.3 550 120Xylenes 500.....Total VOCs187 2,401 47.3 550 120All units in ug/L. Blank cells indicate Below Quantitation Limits (BQL).VOCs - Volatile Organic CompoundsNCSG - NC Groun Water StandardNA - Not AnalyzedNS - Not Sampled* - Duplicate Sample

Appendix A
#=CL#
February 17, 2015
LIMS USE: FR - PHIL RAHN
LIMS OBJECT ID: 92235949
92235949
Project:
Pace Project No.:
RE:
Mr. Phil Rahn
Waters Edge Environmental
4901 Water's Edge Drive
Suite 201
Raleigh, NC 27606
BI-KERNERSVILLE R1-06
Dear Mr. Rahn:
Enclosed are the analytical results for sample(s) received by the laboratory on February 03, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Terri Page
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 1 of 16
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92235949
BI-KERNERSVILLE R1-06
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Page 2 of 16
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92235949
BI-KERNERSVILLE R1-06
Lab ID Sample ID Matrix Date Collected Date Received
92235949001 MW-1 Water 02/02/15 10:00 02/03/15 09:05
92235949002 MW-6S Water 02/02/15 12:00 02/03/15 09:05
92235949003 MW-7 Water 02/02/15 13:30 02/03/15 09:05
92235949004 MW-10 Water 02/02/15 14:30 02/03/15 09:05
92235949005 INFLUENT Water 02/02/15 10:30 02/03/15 09:05
92235949006 EFFLUENT Water 02/02/15 11:00 02/03/15 09:05
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 3 of 16
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92235949
BI-KERNERSVILLE R1-06
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92235949001 MW-1 SM 6200B 17 PASI-CCAH
92235949002 MW-6S SM 6200B 17 PASI-CCAH
92235949003 MW-7 SM 6200B 17 PASI-CCAH
92235949004 MW-10 SM 6200B 17 PASI-CCAH
92235949005 INFLUENT SM 6200B 17 PASI-CCAH
92235949006 EFFLUENT SM 6200B 17 PASI-CCAH
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 4 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92235949
BI-KERNERSVILLE R1-06
Sample:MW-1 Lab ID:92235949001 Collected:02/02/15 10:00 Received:02/03/15 09:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Benzene ND mg/L 02/14/15 13:47 71-43-20.00050 0.00025 1
Chlorobenzene ND mg/L 02/14/15 13:47 108-90-70.00050 0.00025 1
1,2-Dichlorobenzene ND mg/L 02/14/15 13:47 95-50-10.00050 0.00025 1
1,3-Dichlorobenzene ND mg/L 02/14/15 13:47 541-73-10.00050 0.00025 1
1,4-Dichlorobenzene ND mg/L 02/14/15 13:47 106-46-70.00050 0.00025 1
Diisopropyl ether ND mg/L 02/14/15 13:47 108-20-30.00050 0.00025 1
Ethylbenzene ND mg/L 02/14/15 13:47 100-41-40.00050 0.00025 1
Isopropylbenzene (Cumene)ND mg/L 02/14/15 13:47 98-82-80.00050 0.00025 1
Methyl-tert-butyl ether ND mg/L 02/14/15 13:47 1634-04-40.00050 0.00025 1
Naphthalene ND mg/L 02/14/15 13:47 91-20-30.0020 0.0010 1
Toluene ND mg/L 02/14/15 13:47 108-88-30.00050 0.00025 1
Xylene (Total)ND mg/L 02/14/15 13:47 1330-20-70.0010 0.00050 1
m&p-Xylene ND mg/L 02/14/15 13:47 179601-23-10.0010 0.00050 1
o-Xylene ND mg/L 02/14/15 13:47 95-47-60.00050 0.00025 1
Surrogates
1,2-Dichloroethane-d4 (S)96 %02/14/15 13:47 17060-07-070-130 1
4-Bromofluorobenzene (S)103 %02/14/15 13:47 460-00-470-130 1
Toluene-d8 (S)98 %02/14/15 13:47 2037-26-570-130 1
Sample:MW-6S Lab ID:92235949002 Collected:02/02/15 12:00 Received:02/03/15 09:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Benzene ND mg/L 02/14/15 14:04 71-43-20.00050 0.00025 1
Chlorobenzene ND mg/L 02/14/15 14:04 108-90-70.00050 0.00025 1
1,2-Dichlorobenzene ND mg/L 02/14/15 14:04 95-50-10.00050 0.00025 1
1,3-Dichlorobenzene ND mg/L 02/14/15 14:04 541-73-10.00050 0.00025 1
1,4-Dichlorobenzene ND mg/L 02/14/15 14:04 106-46-70.00050 0.00025 1
Diisopropyl ether ND mg/L 02/14/15 14:04 108-20-30.00050 0.00025 1
Ethylbenzene ND mg/L 02/14/15 14:04 100-41-40.00050 0.00025 1
Isopropylbenzene (Cumene)ND mg/L 02/14/15 14:04 98-82-80.00050 0.00025 1
Methyl-tert-butyl ether ND mg/L 02/14/15 14:04 1634-04-40.00050 0.00025 1
Naphthalene ND mg/L 02/14/15 14:04 91-20-30.0020 0.0010 1
Toluene ND mg/L 02/14/15 14:04 108-88-30.00050 0.00025 1
Xylene (Total)ND mg/L 02/14/15 14:04 1330-20-70.0010 0.00050 1
m&p-Xylene ND mg/L 02/14/15 14:04 179601-23-10.0010 0.00050 1
o-Xylene ND mg/L 02/14/15 14:04 95-47-60.00050 0.00025 1
Surrogates
1,2-Dichloroethane-d4 (S)97 %02/14/15 14:04 17060-07-070-130 1
4-Bromofluorobenzene (S)102 %02/14/15 14:04 460-00-470-130 1
Toluene-d8 (S)98 %02/14/15 14:04 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/17/2015 12:37 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 5 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92235949
BI-KERNERSVILLE R1-06
Sample:MW-7 Lab ID:92235949003 Collected:02/02/15 13:30 Received:02/03/15 09:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Benzene ND mg/L 02/14/15 14:37 71-43-20.00050 0.00025 1
Chlorobenzene ND mg/L 02/14/15 14:37 108-90-70.00050 0.00025 1
1,2-Dichlorobenzene ND mg/L 02/14/15 14:37 95-50-10.00050 0.00025 1
1,3-Dichlorobenzene ND mg/L 02/14/15 14:37 541-73-10.00050 0.00025 1
1,4-Dichlorobenzene ND mg/L 02/14/15 14:37 106-46-70.00050 0.00025 1
Diisopropyl ether ND mg/L 02/14/15 14:37 108-20-30.00050 0.00025 1
Ethylbenzene ND mg/L 02/14/15 14:37 100-41-40.00050 0.00025 1
Isopropylbenzene (Cumene)ND mg/L 02/14/15 14:37 98-82-80.00050 0.00025 1
Methyl-tert-butyl ether ND mg/L 02/14/15 14:37 1634-04-40.00050 0.00025 1
Naphthalene ND mg/L 02/14/15 14:37 91-20-30.0020 0.0010 1
Toluene ND mg/L 02/14/15 14:37 108-88-30.00050 0.00025 1
Xylene (Total)ND mg/L 02/14/15 14:37 1330-20-70.0010 0.00050 1
m&p-Xylene ND mg/L 02/14/15 14:37 179601-23-10.0010 0.00050 1
o-Xylene ND mg/L 02/14/15 14:37 95-47-60.00050 0.00025 1
Surrogates
1,2-Dichloroethane-d4 (S)97 %02/14/15 14:37 17060-07-070-130 1
4-Bromofluorobenzene (S)104 %02/14/15 14:37 460-00-470-130 1
Toluene-d8 (S)100 %02/14/15 14:37 2037-26-570-130 1
Sample:MW-10 Lab ID:92235949004 Collected:02/02/15 14:30 Received:02/03/15 09:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Benzene ND mg/L 02/14/15 14:20 71-43-20.00050 0.00025 1
Chlorobenzene ND mg/L 02/14/15 14:20 108-90-70.00050 0.00025 1
1,2-Dichlorobenzene ND mg/L 02/14/15 14:20 95-50-10.00050 0.00025 1
1,3-Dichlorobenzene ND mg/L 02/14/15 14:20 541-73-10.00050 0.00025 1
1,4-Dichlorobenzene ND mg/L 02/14/15 14:20 106-46-70.00050 0.00025 1
Diisopropyl ether ND mg/L 02/14/15 14:20 108-20-30.00050 0.00025 1
Ethylbenzene ND mg/L 02/14/15 14:20 100-41-40.00050 0.00025 1
Isopropylbenzene (Cumene)ND mg/L 02/14/15 14:20 98-82-80.00050 0.00025 1
Methyl-tert-butyl ether ND mg/L 02/14/15 14:20 1634-04-40.00050 0.00025 1
Naphthalene ND mg/L 02/14/15 14:20 91-20-30.0020 0.0010 1
Toluene ND mg/L 02/14/15 14:20 108-88-30.00050 0.00025 1
Xylene (Total)ND mg/L 02/14/15 14:20 1330-20-70.0010 0.00050 1
m&p-Xylene ND mg/L 02/14/15 14:20 179601-23-10.0010 0.00050 1
o-Xylene ND mg/L 02/14/15 14:20 95-47-60.00050 0.00025 1
Surrogates
1,2-Dichloroethane-d4 (S)96 %02/14/15 14:20 17060-07-070-130 1
4-Bromofluorobenzene (S)102 %02/14/15 14:20 460-00-470-130 1
Toluene-d8 (S)99 %02/14/15 14:20 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/17/2015 12:37 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 6 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92235949
BI-KERNERSVILLE R1-06
Sample:INFLUENT Lab ID:92235949005 Collected:02/02/15 10:30 Received:02/03/15 09:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Benzene 0.14 mg/L 02/14/15 16:52 71-43-20.12 0.062 250
Chlorobenzene ND mg/L 02/14/15 16:52 108-90-70.12 0.062 250
1,2-Dichlorobenzene ND mg/L 02/14/15 16:52 95-50-10.12 0.062 250
1,3-Dichlorobenzene ND mg/L 02/14/15 16:52 541-73-10.12 0.062 250
1,4-Dichlorobenzene ND mg/L 02/14/15 16:52 106-46-70.12 0.062 250
Diisopropyl ether ND mg/L 02/14/15 16:52 108-20-30.12 0.062 250
Ethylbenzene ND mg/L 02/14/15 16:52 100-41-40.12 0.062 250
Isopropylbenzene (Cumene)ND mg/L 02/14/15 16:52 98-82-80.12 0.062 250
Methyl-tert-butyl ether ND mg/L 02/14/15 16:52 1634-04-40.12 0.062 250
Naphthalene ND mg/L 02/14/15 16:52 91-20-30.50 0.25 250
Toluene 21.3 mg/L 02/14/15 16:52 108-88-30.12 0.062 250
Xylene (Total)0.29 mg/L 02/14/15 16:52 1330-20-70.25 0.12 250
m&p-Xylene 0.29 mg/L 02/14/15 16:52 179601-23-10.25 0.12 250
o-Xylene ND mg/L 02/14/15 16:52 95-47-60.12 0.062 250
Surrogates
1,2-Dichloroethane-d4 (S)92 %02/14/15 16:52 17060-07-070-130 250
4-Bromofluorobenzene (S)101 %02/14/15 16:52 460-00-470-130 250
Toluene-d8 (S)99 %02/14/15 16:52 2037-26-570-130 250
Sample:EFFLUENT Lab ID:92235949006 Collected:02/02/15 11:00 Received:02/03/15 09:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Benzene ND mg/L 02/14/15 22:30 71-43-20.00050 0.00025 1
Chlorobenzene ND mg/L 02/14/15 22:30 108-90-70.00050 0.00025 1
1,2-Dichlorobenzene ND mg/L 02/14/15 22:30 95-50-10.00050 0.00025 1
1,3-Dichlorobenzene ND mg/L 02/14/15 22:30 541-73-10.00050 0.00025 1
1,4-Dichlorobenzene ND mg/L 02/14/15 22:30 106-46-70.00050 0.00025 1
Diisopropyl ether ND mg/L 02/14/15 22:30 108-20-30.00050 0.00025 1
Ethylbenzene ND mg/L 02/14/15 22:30 100-41-40.00050 0.00025 1
Isopropylbenzene (Cumene)ND mg/L 02/14/15 22:30 98-82-80.00050 0.00025 1
Methyl-tert-butyl ether ND mg/L 02/14/15 22:30 1634-04-40.00050 0.00025 1
Naphthalene ND mg/L 02/14/15 22:30 91-20-30.0020 0.0010 1
Toluene 0.12 mg/L 02/14/15 22:30 108-88-30.00050 0.00025 1
Xylene (Total)ND mg/L 02/14/15 22:30 1330-20-70.0010 0.00050 1
m&p-Xylene ND mg/L 02/14/15 22:30 179601-23-10.0010 0.00050 1
o-Xylene ND mg/L 02/14/15 22:30 95-47-60.00050 0.00025 1
Surrogates
1,2-Dichloroethane-d4 (S)97 %02/14/15 22:30 17060-07-070-130 1
4-Bromofluorobenzene (S)104 %02/14/15 22:30 460-00-470-130 1
Toluene-d8 (S)99 %02/14/15 22:30 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/17/2015 12:37 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 7 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92235949
BI-KERNERSVILLE R1-06
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/30337
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92235949001, 92235949002, 92235949003, 92235949004, 92235949005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1391851
Associated Lab Samples:92235949001, 92235949002, 92235949003, 92235949004, 92235949005
Matrix:Water
Analyzed
1,2-Dichlorobenzene mg/L ND 0.00050 02/14/15 11:48
1,3-Dichlorobenzene mg/L ND 0.00050 02/14/15 11:48
1,4-Dichlorobenzene mg/L ND 0.00050 02/14/15 11:48
Benzene mg/L ND 0.00050 02/14/15 11:48
Chlorobenzene mg/L ND 0.00050 02/14/15 11:48
Diisopropyl ether mg/L ND 0.00050 02/14/15 11:48
Ethylbenzene mg/L ND 0.00050 02/14/15 11:48
Isopropylbenzene (Cumene)mg/L ND 0.00050 02/14/15 11:48
m&p-Xylene mg/L ND 0.0010 02/14/15 11:48
Methyl-tert-butyl ether mg/L ND 0.00050 02/14/15 11:48
Naphthalene mg/L ND 0.0020 02/14/15 11:48
o-Xylene mg/L ND 0.00050 02/14/15 11:48
Toluene mg/L ND 0.00050 02/14/15 11:48
Xylene (Total)mg/L ND 0.0010 02/14/15 11:48
1,2-Dichloroethane-d4 (S)%95 70-130 02/14/15 11:48
4-Bromofluorobenzene (S)%102 70-130 02/14/15 11:48
Toluene-d8 (S)%99 70-130 02/14/15 11:48
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1391852LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichlorobenzene mg/L 0.048.05 96 60-140
1,3-Dichlorobenzene mg/L 0.047.05 94 60-140
1,4-Dichlorobenzene mg/L 0.047.05 94 60-140
Benzene mg/L 0.047.05 93 60-140
Chlorobenzene mg/L 0.047.05 94 60-140
Diisopropyl ether mg/L 0.044.05 88 60-140
Ethylbenzene mg/L 0.047.05 94 60-140
Isopropylbenzene (Cumene)mg/L 0.050.05 99 60-140
m&p-Xylene mg/L 0.093.1 93 60-140
Methyl-tert-butyl ether mg/L 0.044.05 88 60-140
Naphthalene mg/L 0.058.05 115 60-140
o-Xylene mg/L 0.046.05 93 60-140
Toluene mg/L 0.044.05 88 60-140
Xylene (Total)mg/L 0.14.15 93 60-140
1,2-Dichloroethane-d4 (S)%91 70-130
4-Bromofluorobenzene (S)%107 70-130
Toluene-d8 (S)%101 70-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 02/17/2015 12:37 PM
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205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 8 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92235949
BI-KERNERSVILLE R1-06
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1391853MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92236648001
1391854
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,2-Dichlorobenzene mg/L .02 100 60-140102 2 30.02ND 0.020 0.020
1,3-Dichlorobenzene mg/L .02 98 60-140100 1 30.02ND 0.020 0.020
1,4-Dichlorobenzene mg/L .02 98 60-140103 4 30.02ND 0.020 0.021
Benzene mg/L .02 107 60-140107 0 30.02ND 0.021 0.021
Chlorobenzene mg/L .02 102 60-140104 1 30.02ND 0.020 0.021
Diisopropyl ether mg/L .02 89 60-14092 4 30.02ND 0.018 0.018
Ethylbenzene mg/L .02 112 60-140105 6 30.02ND 0.022 0.021
Isopropylbenzene (Cumene)mg/L .02 108 60-140110 2 30.02ND 0.022 0.022
m&p-Xylene mg/L .04 119 60-140107 10 30.04ND 0.048 0.043
Methyl-tert-butyl ether mg/L .02 89 60-14093 4 30.02ND 0.018 0.019
Naphthalene mg/L M0.02 165 60-140124 28 30.02ND 0.033 0.025
o-Xylene mg/L .02 112 60-140105 6 30.02ND 0.022 0.021
Toluene mg/L .02 100 60-14098 1 30.02ND 0.020 0.020
1,2-Dichloroethane-d4 (S)%91 70-13092
4-Bromofluorobenzene (S)%109 70-130109
Toluene-d8 (S)%100 70-130100
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 02/17/2015 12:37 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 9 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92235949
BI-KERNERSVILLE R1-06
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/30345
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92235949006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1392283
Associated Lab Samples:92235949006
Matrix:Water
Analyzed
1,2-Dichlorobenzene mg/L ND 0.00050 02/14/15 19:07
1,3-Dichlorobenzene mg/L ND 0.00050 02/14/15 19:07
1,4-Dichlorobenzene mg/L ND 0.00050 02/14/15 19:07
Benzene mg/L ND 0.00050 02/14/15 19:07
Chlorobenzene mg/L ND 0.00050 02/14/15 19:07
Diisopropyl ether mg/L ND 0.00050 02/14/15 19:07
Ethylbenzene mg/L ND 0.00050 02/14/15 19:07
Isopropylbenzene (Cumene)mg/L ND 0.00050 02/14/15 19:07
m&p-Xylene mg/L ND 0.0010 02/14/15 19:07
Methyl-tert-butyl ether mg/L ND 0.00050 02/14/15 19:07
Naphthalene mg/L ND 0.0020 02/14/15 19:07
o-Xylene mg/L ND 0.00050 02/14/15 19:07
Toluene mg/L ND 0.00050 02/14/15 19:07
Xylene (Total)mg/L ND 0.0010 02/14/15 19:07
1,2-Dichloroethane-d4 (S)%92 70-130 02/14/15 19:07
4-Bromofluorobenzene (S)%104 70-130 02/14/15 19:07
Toluene-d8 (S)%100 70-130 02/14/15 19:07
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1392284LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichlorobenzene mg/L 0.051.05 102 60-140
1,3-Dichlorobenzene mg/L 0.050.05 100 60-140
1,4-Dichlorobenzene mg/L 0.051.05 102 60-140
Benzene mg/L 0.050.05 101 60-140
Chlorobenzene mg/L 0.050.05 101 60-140
Diisopropyl ether mg/L 0.044.05 88 60-140
Ethylbenzene mg/L 0.051.05 101 60-140
Isopropylbenzene (Cumene)mg/L 0.053.05 106 60-140
m&p-Xylene mg/L 0.10.1 100 60-140
Methyl-tert-butyl ether mg/L 0.045.05 89 60-140
Naphthalene mg/L 0.060.05 121 60-140
o-Xylene mg/L 0.049.05 99 60-140
Toluene mg/L 0.047.05 94 60-140
Xylene (Total)mg/L 0.15.15 100 60-140
1,2-Dichloroethane-d4 (S)%88 70-130
4-Bromofluorobenzene (S)%108 70-130
Toluene-d8 (S)%100 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/17/2015 12:37 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 10 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92235949
BI-KERNERSVILLE R1-06
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1392285MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92236811001
1392286
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,2-Dichlorobenzene mg/L .02 106 60-140107 2 30.02<0.50 ug/L 0.021 0.021
1,3-Dichlorobenzene mg/L .02 104 60-140104 1 30.02<0.50 ug/L 0.021 0.021
1,4-Dichlorobenzene mg/L .02 106 60-140108 2 30.02<0.50 ug/L 0.021 0.022
Benzene mg/L .02 109 60-140110 2 30.02<0.50 ug/L 0.022 0.022
Chlorobenzene mg/L .02 107 60-140107 1 30.02<0.50 ug/L 0.021 0.021
Diisopropyl ether mg/L .02 94 60-14096 2 30.02<0.50 ug/L 0.019 0.019
Ethylbenzene mg/L .02 106 60-140109 2 30.02<0.50 ug/L 0.021 0.022
Isopropylbenzene (Cumene)mg/L .02 114 60-140114 0 30.02<0.50 ug/L 0.023 0.023
m&p-Xylene mg/L .04 106 60-140107 1 30.04<1.0 ug/L 0.043 0.043
Methyl-tert-butyl ether mg/L .02 94 60-14096 2 30.02<0.50 ug/L 0.019 0.019
Naphthalene mg/L .02 123 60-140120 2 30.02<2.0 ug/L 0.025 0.024
o-Xylene mg/L .02 105 60-140106 1 30.02<0.50 ug/L 0.021 0.021
Toluene mg/L .02 100 60-140102 1 30.02<0.50 ug/L 0.020 0.020
1,2-Dichloroethane-d4 (S)%92 70-13089
4-Bromofluorobenzene (S)%106 70-130107
Toluene-d8 (S)%99 70-130100
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 02/17/2015 12:37 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 11 of 16
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92235949
BI-KERNERSVILLE R1-06
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 02/17/2015 12:37 PM
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 12 of 16
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92235949
BI-KERNERSVILLE R1-06
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92235949001 MSV/30337MW-1 SM 6200B
92235949002 MSV/30337MW-6S SM 6200B
92235949003 MSV/30337MW-7 SM 6200B
92235949004 MSV/30337MW-10 SM 6200B
92235949005 MSV/30337INFLUENTSM 6200B
92235949006 MSV/30345EFFLUENTSM 6200B
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 02/17/2015 12:37 PM
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205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 13 of 16
Page 14 of 16
Page 15 of 16
Page 16 of 16

Appendix B
GW-59 Re GROCOMFACILIT Facility Permit NFacility Ke (CityContactWell Lo Well IdeWell DeScreeneDepth toMeasurGallonsField an PARAMCOD ColiformColiform(Note: UDissolvepH (wheTOC ChlorideArsenicGrease Phenol Sulfate SpecificTotal AmTKN as I certify producefalse infev. 4/98 UNDWATER MPLIANCE RETY INFORMATION Name: HighName (if different): Address: 215 D(Strernersville y) t Person: Briaocation/Site Name: entification Number epth: N/A ed Interval: N/Ao Water Level: ring Point is s of water pumped/banalysis: pH Temp. METERS (Samples fo m: MF Fecal m: MF Total Use MPN method for hied Solids: Total en analyzed) e c and Oils c Conductance mmonia s N that, to the best oed using approved formation, includingQUALITY MOEPORT FORMland Industries/Taka Drummond Street et) NC 272(State) (Zan Roan (from Permit): ft. Well DiaA ft. to N/A N/A ft. below meN/A ft. above lanailed before samplin , Specific CC, Odor or metals were colleighly turbid samples) of my knowledge amethods of analysg the possibility of fiONITORING:M Pleaseada 284 Countyip) Teleph No. of W meter: N/A in. ft. easuring point. nd surface.ng: ---Conductance Appeected unfiltered mg/l Nit /100ml Nit /100ml Ph Ort mg/l Al – units Ba mg/l Ca mg/l Cd mg/l Ch mg/l Cu mg/l Fe mg/l HG uMhos K – mg/l Mg mg/l Mn and belief, the infosis by a North Caroines and imprisonmSUBMIT FORM Oe Print Clearly or Tyy Forsythone #: (336) 992-1Wells to be SampledFor Groundwater TreCheck One: Influent Effluent uMhos earance YES rite (NO2) as N rate (NO3) as N osphorous: Total asthophosphate – Aluminum – Barium a – Calcium – Cadmium romium: Total – Copper – Iron G – Mercury – Potassium g – Magnesium n – Manganese ormation submitted olina DWQ (formerment for knowing vioPhillip RahPermittee (or Signature of PON YELLOW PAMype 1460 d: 1 (from Permit) NDLCeatment Systems (98) t (99) NO as P in this report is trrly DEM) certified lolations. n – President, WateAuthorized Agent) NamPermittee (or AuthorizedAPER ONLY Mail Original to:DW16RNOTE: Values shocolloidal coDate sample collected: Laboratory Name: Certification No. and field acidified mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l rue, accurate, and laboratory. I am aers Edge Environmenme and Title – Please prind Agent) PERMIT #: Non-Discharge NPDES TYPE OF PERM Lagoon Spray F Rotary Other:DEPARTMENT OF ENVIWATER QUALITY DIVIS636 MAIL SERVICE CERALEIGH, NC 27699-16ould reflect dissolvencentrations. 2.2.15 DatePace AnalyticalNC # 37706 YES Ni – Nickel PB – Lead Zn – Zinc Ammonia NitrogeOther (Specify CoToluene 21,300 uBenzene 140 ug/LXylenes 290 ug/L ORGANICS: (GC(Specify test and Report Attached?VOC complete, and thaaware that there arntal, LLC nt or type WQ0006751ITTED OPERATIONn XField y Distributor IRONMENT AND NATUSION, GROUNDWATERENTER 636 Phed and e sample analyzed: 2 NO) n ompounds and Concg/L L C, GC/MS, HPLC) method #. Attach la Yes (1): method # = : method # = : method # = at the laboratory anre significant penalEXPIRATION DAT UIC N BEING MONITOR Remediation: In Remediation: Land ApplicationURAL RESOURCES R SECTION hone: [phone] .14.15 mg/l mg/l mg/l mg/l centration Units) ab report.) No X (0) 6200B nalytical data was ties for submitting 2.20.15 (Date) TE: 1.31.17 RED nfiltration Gallery n of Sludge
GW-59 Re GROCOMFACILIT Facility Permit NFacility Ke (CityContactWell Lo Well IdeWell DeScreeneDepth toMeasurGallonsField an PARAMCOD ColiformColiform(Note: UDissolvepH (wheTOC ChlorideArsenicGrease Phenol Sulfate SpecificTotal AmTKN as I certify producefalse infev. 4/98 UNDWATER MPLIANCE RETY INFORMATION Name: HighName (if different): Address: 215(Strernersville y) t Person: Briaocation/Site Name: entification Number epth: N/A ed Interval: N/Ao Water Level: ring Point is s of water pumped/banalysis: pH Temp. METERS (Samples fo m: MF Fecal m: MF Total Use MPN method for hied Solids: Total en analyzed) e c and Oils c Conductance mmonia s N that, to the best oed using approved formation, includingQUALITY MOEPORT FORMland Industries/Taka 5 Drummond Street et) NC 272(State) (Zan Roan (from Permit): ft. Well DiaA ft. to N/A N/A ft. below meN/A ft. above lanailed before samplin , Specific CC, Odor or metals were colleighly turbid samples) of my knowledge amethods of analysg the possibility of fiONITORING:M Pleaseada 284 Countyip) Teleph No. of W meter: N/A in. ft. easuring point. nd surface.ng: ---Conductance Appeected unfiltered mg/l Nit /100ml Nit /100ml Ph Ort mg/l Al – units Ba mg/l Ca mg/l Cd mg/l Ch mg/l Cu mg/l Fe mg/l HG uMhos K – mg/l Mg mg/l Mn and belief, the infosis by a North Caroines and imprisonmSUBMIT FORM Oe Print Clearly or Tyy Forsythone #: (336) 992-1Wells to be SampledFor Groundwater TreCheck One: Influent Effluent uMhos earance YES rite (NO2) as N rate (NO3) as N osphorous: Total asthophosphate – Aluminum – Barium a – Calcium – Cadmium romium: Total – Copper – Iron G – Mercury – Potassium g – Magnesium n – Manganese ormation submitted olina DWQ (formerment for knowing vioPhillip RahPermittee (or Signature of PON YELLOW PAMype 1460 d: 1 (from Permit) NDLCeatment Systems (98) t (99) NO as P in this report is trrly DEM) certified lolations. n – President, WateAuthorized Agent) NamPermittee (or AuthorizedAPER ONLY Mail Original to:DW16RNOTE: Values shocolloidal coDate sample collected: Laboratory Name: Certification No. and field acidified mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l rue, accurate, and laboratory. I am aers Edge Environmenme and Title – Please prind Agent) PERMIT #: Non-Discharge NPDES TYPE OF PERM Lagoon Spray F Rotary Other:DEPARTMENT OF ENVIWATER QUALITY DIVIS636 MAIL SERVICE CERALEIGH, NC 27699-16ould reflect dissolvencentrations. 2.2.15 DatPace AnalyticalNC # 37706 YES Ni – Nickel PB – Lead Zn – Zinc Ammonia NitrogeOther (Specify Co120 ug/L toluene ORGANICS: (GC(Specify test and Report Attached?VOC complete, and thaaware that there arntal, LLC nt or type WQ0006751ITTED OPERATIONn XField y Distributor IRONMENT AND NATUSION, GROUNDWATERENTER 636 Phed and te sample analyzed: NO) n ompounds and ConcC, GC/MS, HPLC) method #. Attach la Yes (1): method # = : method # = : method # = at the laboratory anre significant penalEXPIRATION DAT UIC N BEING MONITOR Remediation: In Remediation: Land ApplicationURAL RESOURCES R SECTION hone: [phone] 2.14.15 mg/l mg/l mg/l mg/l centration Units) ab report.) No X (0) 6200B nalytical data was ties for submitting 2.20.15 (Date) TE: 1/31/2017 RED nfiltration Gallery n of Sludge