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HomeMy WebLinkAboutWI-29608_48855_CA_IAR_20230107 Initial Assessment Report Penn Tank Lines- Jet Fuel Release Incident Page 2 B. Background and Initial Response Activities On October 26, 2022, during filling operations of an underground storage tank (UST), a discharge line from a fueling truck (operated by Penn Tank Lines) ruptured, releasing approximately 100 gallons of jet fuel. The released product leaked onto the graveled-covered ground surface at an Air Wilmington remote aircraft fueling facility. The aboveground release occurred near Building #1925, at 1817 Aviation Drive, Wilmington International Airport, in Wilmington, New Hanover County, North Carolina. The approximate location of the site is graphically presented on Figure 1 and Figure 2 (included in Appendix A) and is situated at approximate coordinates 34.272407 N and -77.909702 W. A map of the area impacted is included as Figure 3. Penn Tank Lines contracted with A-C-T Environmental & Infrastructure , Inc. (A-C-T), who hired First Call Environmental (FCE) to provide emergency response and soil remedial services. On October 27, 2022, FCE contracted Highlands Environmental Solutions, Inc. (HES) to provide environmental oversight and sampling services. A site-specific health and safety plan (HASP) was developed by HES for these site activities. A copy of the HASP is included in Appendix B. FCE also contacted the North Carolina 811 service to locate and identify any potential underground utilities at the site. C. Free Product Investigation and Recovery On the day of the incident, representatives of Penn Tank Lines and/or the airport personnel deployed dry granular absorbents to the impacted areas of gravel. The spent absorbents were placed into three 55- gallon steel drums for disposal. During the soil excavation activities described below, the spent absorbents were emptied into a roll off box for final disposal. D. Groundwater and Surface Water Investigation The released jet fuel did not migrate beyond the localized area of impact. The closest surface water body is a perennial stream located approximately 640 feet North of the release location. Groundwater was not encountered during remediation activities; therefore, a groundwater investigation was not performed during site activities. E. Initial Response and Abatement Activities. Abatement activities included the application of dry absorbents as described in Section C. F. Excavation of Petroleum Impacted Soil On October 28, 2022, personnel from HES and FCE mobilized to the site and conducted soil excavation activities. Select photographs of the site and remediation activities are included in Appendix C. FCE utilized a track-mounted mini-excavator to excavate impacted soils. During excavation, HES utilized field indicators (i.e., staining, and/or odor) and collected random soil samples from excavated areas to field screen for organic vapors using a photoionization detector (PID – Mini Rae 3000). To field screen the samples, an aliquot of soil was placed in a clean, labeled, zip-lock bag and allowed to volatilize for approximately 10 minutes. At the end of the volatilization period, the sampling probe for the PID was inserted into the bag to screen for the presence of organic vapors. Utilizing these techniques, HES determined the estimated final limits of the horizontal extent of the excavation. The resulting excavation measured approximately 38 feet in length, by various widths of 8.0 to 18.0 feet in width, ranging from 0.5 to 1.5 feet in depth. Underground utilities were present in the area, which limited the depth of the excavation. Following completion of the excavation, HES personnel collected six post-excavation confirmation soil samples (“CS-1” thru “CS-6”) for laboratory analysis. A diagram depicting the excavation and sample collection locations is included as Figure 4. Upon collection, the post excavation soil samples were split into two aliquots. The first aliquot was placed in a clean zip-lock bag and field screened for organic vapors using the previously described methodology. For the second aliquot, a Terracore sampler was used to obtain a soil core for laboratory analysis. The Initial Assessment Report Penn Tank Lines- Jet Fuel Release Incident Page 3 soil core was placed in a labelled, laboratory-supplied container, and hand delivered to RedLab, LLC in Wilmington, North Carolina. The samples were analyzed for gasoline and diesel range organics (GRO and DRO, respectively) using RedLab’s UVF technology, which is approved by the North Carolina Department of Environmental Quality (NCDEQ). At the completion of the soil excavation activities, approximately 13.96 tons of impacted soil and gravel were placed into a roll off box. The waste soil was transported to J&R Farms, LLC, in Fair Bluff, NC for disposal. J&R Farms, LLC is a permitted disposal facility for petroleum-impacted soil (i.e., land farm). A copy of the waste disposal documentation is included in Appendix D. Laboratory analysis of the soil samples resulted in the detection of GRO in each of the six samples at concentrations ranging from 0.85 mg/kg to 485.1 mg/kg. GRO concentrations in samples CS-1, CS-3, CS-5 and CS-6 exceeded the NCDEQ State Action Limit of 50 mg/kg. Laboratory analysis of the soil samples resulted in the detection of DRO in each of the six samples at concentrations ranging from 11.1 mg/kg to 2,113 mg/kg. DRO concentrations in samples CS-1, CS-3, CS-5 and CS-6 exceeded the NCDEQ State Action Limit of 100 mg/kg. Personnel from HES and RedLab reviewed the UVF fingerprints for the post-excavation soil samples. The UVF fingerprints for samples CS-1, CS-5, and CS-6 indicated the presence of “fresh” petroleum (jet fuel), while the UVF fingerprints for samples CS-2, CS-3, and CS-4 exhibited a “degraded” petroleum fingerprint. A summary of the soil analytical data is presented in Table 1 and included as Appendix E. The complete laboratory analytical data reports and chain-of-custody records for the samples are included as Appendix F. G. Conclusions and Recommendations On October 26, 2022, during filling operations of an underground storage tank (UST), a discharge line from a fueling truck (operated by Penn Tank Lines) ruptured, releasing approximately 100 gallons of jet fuel. The released product leaked onto the graveled covered ground surface at an Air Wilmington remote aircraft fueling facility. The aboveground release occurred near Building #1925, at 1817 Aviation Drive, Wilmington International Airport, in Wilmington, New Hanover County, North Carolina. On October 28, 2022, personnel from HES and FCE mobilized to the site and conducted soil excavation activities. Soil excavation activities were limited due to the presence of underground utilities in the subsurface. As a result of these activities, approximately 24 tons of impacted soil was placed into a roll off box for future disposal. Following completion of the excavation, HES personnel collected six post-excavation confirmation soil samples (“CS-1” thru “CS-6”) for laboratory analytical testing purposes. Laboratory analysis of post excavation confirmation soil samples resulted in the detection of residual GRO and DRO in all six samples. Previous petroleum release incidents have been documented at the site. Evaluation of the UVF fingerprints for the post-excavation soil samples indicate the presence of both “fresh” and “degraded” petroleum in the samples. Fresh petroleum-related impacts at concentrations greater than the State Action Limit were detected in three of the post-excavation soil samples. Degraded petroleum- related impacts were detected in three of the post-excavation soil samples. Based on the analytical data, HES concludes that degraded petroleum-related impacts detected at the site are not related to the subject release incident that occurred on October 26, 2022. However, for the samples that exhibited fresh UVF fingerprints, it is reasonable to conclude that these detections are reflective of residual petroleum-related impacts from the subject release incident that occurred on October 26, 2022. Based on the results of this investigation, HES concludes that petroleum-impacted soil with concentrations greater than State Action Limits remains at the site. HES recommends the performance of a Phase I Limited Site Assessment (LSA) be performed at the site. The scope of work for the LSA should be modified to include additional soil assessment activities. The additional soil assessment activities are recommended to (1) complete the delineation of petroleum-impacted soil at the site and (2) Initial Assessment Report Penn Tank Lines- Jet Fuel Release Incident Page 4 differentiate between areas of residual petroleum impacted soil that are related to the subject release, and those that are related to previously documented petroleum releases at the site. APPENDIX A Drawing / Project Name Client Project # Date N Base diagram from Bing Maps Site Location Diagram Air Wilmington Jet Fuel Release Incident Wilmington, North Carolina First Call Environmental / Penn Tank Lines Site Location DB Fig. Scale 340051 Not to Scale December 2022 1 PM PG JB PE JB JB Drawing / Project Name Client Project # Date N Base diagram from USGS Topographic Quadrangle; Castle Hayne, North Carolina Topographic Location Diagram Air Wilmington Jet Fuel Release Incident Wilmington, North Carolina First Call Environmental / Penn Tank Lines Site Location DB Fig. Scale 340051 Not to Scale December 2022 2 PM PG JB PE JB JB Drawing / Project Name Client Project # Date N Base diagram from Google Earth Area Diagram Air Wilmington Jet Fuel Spill Incident Wilmington, NC First Call Environmental /Penn Tank Lines Incident Location DB Fig. Scale 340051 As Shown December 2022 3 PM PG RS PE JB JB    feet  Approximate Scale 0 760 1520 Concrete TaxiwayGrassCS-6Jet Fuel Piping and PumpsCS-1CS-3CS-2CS-4CS-5Dirt/GrassShedGravelLimits of Excavation38' x 17' x 0.5-1.5'PG:DB:Project Number:Date:Scale:PE:PM:Drawing NameSite / Client NameFig.LegendApproximate Scale020 40NfeetSoil Sample LocationExcavation and Sample Location DiagramJet Fuel Release IncidentWilmington, NCFirst Call Environmental / Penn Tank LinesJBRS340051December 2022As Shown4JB APPENDIX B Highlands Environmental Solutions, Inc. HEALTH AND SAFETY PLAN For Site Activities at: Jet Fuel Release Air Wilmington, near Building #1925 1817 Aviation Drive, Wilmington International Airport Wilmington, NC December 2022 Minimum Level of Protection at this site is Level D Contaminants of Concern are Petroleum Hydrocarbons Robert Shaut Project Manager The information in this HASP is provided solely for the protection of the health and safety of Highlands Environmental Solutions employees and subcontractors working under the direct supervision and control of Highlands Environmental Solutions on this project. Highlands Environmental Solutions assumes no liability for, or responsibility to, any other parties for the accuracy or completeness of the information contained herein for any use or reliance upon this HASP by any other party. Health and Safety Plan Diesel Fuel Release; Burlington, NC Page 2 IN THE EVENT OF ANY EMERGENCY, CONTACT PROJECT MANAGER OR HEALTH AND SAFETY REPRESENTATIVE SITE EMERGENCY FORM Contaminants of Concern: Petroleum Hydrocarbons Minimum Level of Protection: Level D Do not endanger your life. Survey the situation before taking any action. Highlands Environmental Solutions Office Telephone: (919) 848-3155 Site Location Address: 1817 Aviation Drive, Wilmington International Airport, near Building #1925, Wilmington, NC Telephone Located at: HES Personnel (cellular phone) EMERGENCY PHONE NUMBERS Ambulance: 911 Fire: 911 Police: 911 Hospital Name: Cone Health Hospital Phone: 336-538-7000 Project Manager: Robert Shaut (984-289-9992) Health and Safety Specialist: Joe Beaman (919-414-7081) Client Contact: Taylor Hartman (First Call) (804-305-1171) Poison Control: (800) 848-6946 State Agency: NCDEQ (WSRO) 336-771-5000 UTILITY MARKER EMERGENCY TELEPHONE NUMBERS Utility Color Code Telephone Number Water Gas Electric Telephone Cable Sewer Blue Yellow Red Orange Orange Green (800) 632-4949 (800) 632-4949 (800) 632-4949 (800) 632-4949 (800) 632-4949 (800) 632-4949 Dig Safe Telephone Number: (800) 632-4949 Health and Safety Plan Diesel Fuel Release; Burlington, NC Page 3 HOSPITAL LOCATION MAP Directions: Head northeast on Airport Blvd 3 min (0.8 mi) Continue on N 23rd St. Take N 16th St to Ambulance Dr in Wilmington 11 min (4.8 mi) Continue on Ambulance Dr to your destination 2 min (0.3 mi) New Hanover Regional Medical Center Hospital Information: Name: New Hanover Regional Medical Address: 2131 S, 17th St., City, State: Wilmington, NC Phone: 910-667-7000 Health and Safety Plan Jet Fuel Release; Wilmington, NC Page 4 FIRST AID FOR PETROLEUM HYDROCARBON EMERGENCIES Ingestion: DO NOT INDUCE VOMITING. Call Poison Control; follow instructions. Administer cardiopulmonary resuscitation (CPR), if necessary. Seek medical attention. Inhalation: Remove person from contaminated environment. DO NOT ENTER A CONFINED SPACE TO RESCUE SOMEONE WHO HAS BEEN OVERCOME UNLESS PROPERLY EQUIPPED AND A STANDBY PERSON IS PRESENT. Administer CPR if necessary. Seek medical attention. Skin Contact: Brush off dry material, remove wet or contaminated clothing. Flush skin thoroughly with water. Seek medical attention if irritation persists. Eye Contact: Flush eyes with water for 15 minutes. Seek medical attention. Exposure Symptoms: Headache, dizziness, nausea, drowsiness, irritation of eyes, nose, throat, breathing difficulties. Contingency Plan: Report incident to Project Manager (PM) after emergency procedures have been implemented. RESPONDER MUST HAVE A CURRENT CERTIFICATE TO ADMINISTER FIRST AID OR CPR 1. Survey the situation. Do not endanger your own life. DO NOT ENTER A CONFINED SPACE TO RESCUE SOMEONE WHO HAS BEEN OVERCOME UNLESS PROPERLY EQUIPPED AND A STANDBY PERSON IS PRESENT. 2. Call 911 (if available) or the fire department IMMEDIATELY. Explain the physical injury, chemical exposure, fire, or release. 3. Decontaminate the victim without delaying life-saving procedures. 4. If the victim's condition appears to be noncritical, but seems to be more severe than minor cuts, he/she should be transported to the nearest hospital by trained Emergency Medical Services (EMS) personnel: let the doctor assume the responsibility for determining the severity of the injury. If the condition is obviously serious, EMS must transport the victim. 5. Notify the PM. Health and Safety Plan Jet Fuel Release; Wilmington, NC Page 5 EMERGENCY FIRST AID PROCEDURES To Stop Bleeding CPR 1. Give medical statement. 2. Assure airway, breathing, and circulation. 3. Use DIRECT PRESSURE over the wound with clean dressing or your hand (use nonpermeable gloves). Direct pressure will control most bleeding. 4. Bleeding from an artery or several injury sites may require DIRECT PRESSURE on a PRESSURE POINT. Use pressure points for 30 - 60 seconds to help control severe bleeding. 5. Continue primary care and seek medical aid as needed. 1. Call for help. 2. Arousal: check for consciousness. 3. Open airway with chin-lift. 4. Look, listen, and feel for breathing. 5. If breathing is absent, give 2 slow, full rescue breaths. 6. Check the pulse for 5 to 10 seconds. 7. If pulse is present, continue rescue breathing: 1 breath every 5 seconds 8. If pulse is absent, start CPR: 15 compressions, 2 breaths (1 man) Health and Safety Plan Jet Fuel Release; Wilmington, NC Page 6 Project and Health and Safety Information HES will be performing an environmental remediation at the subject site for First Call Environmental. All work will comply with the Occupational Safety and Health Act (OSHA) standard, "Hazardous Waste Operations and Emergency Response," (29 CFR 1910.120), and other federal, state and local procedures that require the development and implementation of a HASP. Generation of this document certifies that the workplace has been evaluated for the hazards as described. A hazard assessment has been performed and the adequacy of the personal protective equipment (PPE) selected is hereby certified per 29 CFR 1910.132(d) and is duly noted by the signature(s) and date appearing on the cover page of this document. If any site conditions are encountered that are different from typical retail petroleum operations, the field investigator is to stop work immediately and notify the Project Manager. This plan addresses the safety issues associated environmental investigation and assessment activities performed at retail petroleum operations. For this project, site investigation activities will involve the following (checked items): Phase I Environmental Site Assessment Phase II Environmental Site Assessment x Spill Response and Abatement x Soil sampling (hand auger) Soil sampling (drilling) Monitoring well installation UST removal (requires full HASP) x Soil excavation Groundwater sampling/monitoring Groundwater remediation Drum removal Site surveying Soil Gas / VI assessment/survey Pump/Slug testing All activities of this project will be carried out under Level D or Modified Level D. At a minimum, all personnel will wear the following PPE based on the task to be performed at the site (checked items): x Hard Hat x Safety Vest x Steel Toe Boots Chemical Boots x Nitrile gloves (sampling gloves) Heavy Nitrile gloves x Safety glasses Ear plugs/ear muffs (sound suppression) White Tyvek Yellow (polycoated) Tyvek Site is on an interstate highway and work will be performed at night. Use caution. Health and Safety Plan Jet Fuel Release; Wilmington, NC Page 7 HAZARD IDENTIFICATION AND CONTROL Precautions must be taken to prevent injuries and exposures to the following potential hazards. . Potential Hazards and Control Potential Hazard Control Exposure to Petroleum Products 1. Stand up-wind of petroleum products whenever possible. 2. Minimize contact and contact time with petroleum products. 3. Avoid walking through discolored areas, puddles, leaning on drums, or contacting anything that is likely to be contaminated. 4. Do not eat, drink, smoke and/or apply cosmetics in the hot or warm zones. 5. Wear gloves when in contact with contaminated surfaces. 6. Safety glasses must be worn at a minimum. 7. Splash goggles must be worn when working with liquids. 8. >25 ppm organic vapors in breathing zone requires upgrade to Level C. 9. >250 ppm organic vapors in breathing zone requires upgrade from Level C to Level B. 10. If unknown materials are encountered, call the HSS. Vehicular Traffic 1. Wear traffic safety vest when vehicle hazard exists. 2. Use cones, flags, barricades, and caution tape to define work area. 3. Use vehicle to block work area. 4. Engage police detail for high-traffic situations. Vault Entry 1. HES Personnel do not perform Confined Space Entry. Utility Lines Contact 1. Contact Dig Safe to have utility lines marked prior to excavation/trenching. 2. Refer to site drawings or customer interviews if on private property for utility locations. 3. Hand dig 3 to 5 feet down and 5 feet each side of utility marker to avoid breaking utility lines. Inclement Weather 1. Stop outdoor work during electrical storms and other extreme weather conditions such as extreme heat or cold temperatures. 2. Take cover indoors or in vehicle. 3. Listen to local forecasts for warnings about specific weather hazards such as tornados, hurricanes, and flash floods. Noise 1. Wear hearing protection when equipment such as a drill rig, jackhammer, cut saw, air compressor, blower or other heavy equipment is operating on the site. 2. Wear hearing protection whenever you need to raise your voice above normal conversational speech due to a loud noise source; this much noise indicates the need for protection. Health and Safety Plan Jet Fuel Release; Wilmington, NC Page 8 Potential Hazard Control Electric Shock 1. Maintain appropriate distance from overhead utilities; 20-foot minimum clearance from power lines required; 10-foot minimum clearance from shielded power lines. 2. Use ground-fault circuit interrupters as required. 3. Perform lockout/tagout procedures (Appendix C). 4. Use three-pronged plugs and extension cords. 5. Contact your local underground utility-locating service. 6. Follow code requirements for electrical installations in hazardous locations. Physical Injury 1. Wear hard hats and safety glasses when on-site. 2. Maintain visual contact with the equipment operator and wear orange safety vest when heavy equipment is used on-site. 3. Avoid loose-fitting clothing (driller and driller's helper). 4. Prevent slips, trips and falls; keep work area uncluttered. 5. Keep your hands away from moving parts (i.e., augers). 6. Test the emergency shutoff switch on the drill rig daily. Back Injury 1. Use a mechanical lifting device or a lifting aid where appropriate. 2. If you must lift, plan the lift before doing it. 3. Check your route for clearance. 4. Bend at the knees and use leg muscles when lifting. 5. Use the buddy system when lifting heavy or awkward objects. 6. Do not twist your body while lifting. Heat Stress 1. Increase water intake while working. 2. Increase number of rest breaks and/or rotate workers in shorter work shifts. 3. Watch for signs and symptoms of heat exhaustion and fatigue. 4. Plan work for early morning or evening during hot months. 5. Use ice vests when necessary. 6. Rest in cool, dry areas. 7. In the event of heat stroke, bring the victim to a cool environment and initiate first aid procedures. Cold Stress 1. Take breaks in heated shelters when working in extremely cold temperatures . 2. Remove the outer layer of clothing and loosen other layers to promote evaporation of perspiration, upon entering the shelter. 3. Drink warm liquids to reduce the susceptibility to cold stress. High Crime Areas 1. Be aware of surroundings. 2. Use the buddy system. 3. Request police detail when appropriate. Insects 1. Tuck pants into socks. 2. Wear long sleeves. 3. Use insect repellent. Health and Safety Plan Jet Fuel Release; Wilmington, NC Page 9 Potential Hazard Control Poisonous Plants (Such as Poison Ivy, Oak, etc.) 1. Don't enter areas infested with poisonous plants. 2. Immediately wash any areas that come into contact with poisonous plants. Ladders 1. Make sure ladder rungs are sturdy and free of cracks. 2. Use ladders with secure safety feet. 3. Pitch ladders at a 4:1 ratio. 4. Secure ladders at the top when possible. 5. Do not use ladders for access to air stripper towers. 6. Use non-conductive ladders near electrical wires. Fire Control 1. Smoke only in designated areas. 2. Keep flammable liquids in closed containers. 3. Keep site clean; avoid accumulating combustible debris such as paper. 4. Follow Hot Work Safety Procedures when welding or performing other activities requiring an open flame. 5. Isolate flammable and combustible materials from ignition sources. 6. Ensure fire safety integrity of equipment installations according to Hazard Classification Diagram (Appendix G). Static Electricity 1. Do not create static discharge in flammable atmospheres. 2. Electrically bond and ground pumps transfer vessels, tanks, drums, bailers and probes, when moving liquids. 3. Electrically bond and ground vacuum trucks and the tanks they are emptying. 4. Do not splash fill containers with flammable liquids. Drilling/Boring Operations 1. Driller and helper must be present during all active operations. 2. Driller helper and other site personnel must know location of emergency shut off switch. 3. Unauthorized personnel must be kept clear of drilling rig. 4. Area of drilling operation must be cordoned off/barricaded. 5. When hazardous conditions are deemed present, operation must be shut down. Well Installation, Well Development, Well Gauging, Well Bailing, Soil/Ground- water Sampling 1. Wear appropriate PPE to avoid skin, eye, and inhalation contact with contaminated groundwater and/or soil. 2. Stand upwind when conducting tasks and minimize possible inhalation exposure; especially when first opening monitoring wells. 3. Conduct air monitoring to determine level of respiratory protection. 4. Utilize engineering controls such as portable venturi air movers to draw away or blow away chemical vapors. Welding, Cutting, Brazing 1. Before conducting welding at a project site, contact the Project Manager.. Cleaning Equipment 1. Wear appropriate PPE to avoid skin and eye contact with isopropyl alcohol, alconox, or other cleaning materials. 2. Stand upwind to minimize any potential inhalation exposure. 3. Dispose of spent cleaning solutions and rinses accordingly. Health and Safety Plan Jet Fuel Release; Wilmington, NC Page 10 Potential Hazard Control First aid kit, emergency eye wash station, fire extinguisher, and absorbent pads will be located on-site in the vehicle or site remediation system. Health and Safety Plan Diesel Fuel Release; Burlington, NC Page 11 Signature Sheet All persons entering the work zone, or visiting the subject site for the purposes associated with the subject investigation(s), or activities associated with the subject investigation(s) are required to notify the HES representative on-site immediately upon arrival. All persons entering the work zone, or visiting the subject site for the purposes associated with the subject investigation(s), or activities associated with the subject investigation(s) are required to review appropriate health and safety procedures, and provide a signature documenting they have been properly briefed on health and safety policies and procedures to be followed while on-site. HES will not be responsible for personal injuries or death resulting from personal actions that are considered negligent, or that result from personal activities that are contrary to this health and safety plan. By my signature, I acknowledge that I have been briefed on site specific health and safety procedures, that I am familiar with said health and safety procedures, and that I will follow all indicated health and safety procedures while on-site. Name Signature APPENDIX C Photograph Number 1: Jet fuel release incident location, near Building #1925, at Wilmington International Airport, NC, prior to abatement (10-28-22), looking Northwest. Photograph Number 2: Jet fuel release incident location, near Building #1925, at Wilmington International Airport, NC, prior to abatement (10-28-22), looking East. Photograph Number 3: Excavation activities (10-28-22), looking East. Photograph Number 4: Excavation activities (10-28-22), looking Northwest. Photograph Number 5: Excavation activities (10-28-22). Photograph Number 6: Impacted soils were loaded onto a roll off box for disposal (10-28-22) Photograph Number 7: Final limits of excavation activities (10-28-2022). Photograph Number 8: Final limits of excavation (10-28-22). Photograph Number 7: Backfill activities (10-28-22). Photograph Number 8: Repaired site (10-28-22). APPENDIX D APPENDIX E FieldCollection DateSample Depth (feet BGS)CS-1 10/28/2022 0.5 171.3205.5 1,205CS-2 10/28/2022 1.0 33.1 0.85 57CS-3 10/28/2022 1.0 228.9485.1 385.3CS-4 10/28/2022 1.5 21.6 8.5 11.1CS-5 10/28/2022 1.0 212.3411.5 2,113CS-6 10/28/2022 0.5 65.978.9 418.250 100Notes:Bold denotes concentration greater than State Action Limits. Table 1First Call Environmental / Penn Tank LinesJet Fuel Release Incident - Wilmington International Airport; Wilmington, NCHES Project #340051Summary of Analytical Data Gasoline Range Organics (GRO) (Soil Samples)Constituent of ConcernAnalytical Method (e.g., VOC by EPA 8260B)Sample ID NumberPID Screening (ppm)Diesel Range Organics (DRO)8015B (mg/Kg)NCDEQ State Action Limit (mg/kg) APPENDIX F Hydrocarbon Analysis Results Client:HIGHLANDS ENVIRONMENTAL Samples taken Friday, October 28, 2022 Address:8410-D FALLS OF NEUSE Samples extracted Friday, October 28, 2022 Samples analysed Monday, October 31, 2022 Contact:ROB SHAUT Operator MAX MOYER Project:#340051 8 H09382 Matrix Sample ID Dilution used BTEX (C6 - C9) GRO (C5 - C10) DRO (C10 - C35) TPH (C5 - C35) Total Aromatics (C10-C35) 16 EPA PAHs BaP HC Fingerprint Match % light % mid % heavy s CS-1 325.0 <8.1 205.5 1205 1411 50.3 <2.6 <0.33 99 0.7 0.3 Deg.Kerosene 89.5%,(FCM) s CS-2 22.0 <0.55 0.85 57 57.9 32.4 1.6 0.05 2.6 75.7 21.7 V.Deg.PHC 90.3%,(FCM),(BO) s CS-3 319.0 <8 485.1 385.3 870.4 376.9 19.2 <0.32 60.4 36.3 3.3 Deg.Fuel 87.7%,(FCM) s CS-4 21.0 <0.52 8.5 11.1 19.6 3 <0.17 <0.021 91.8 6.3 1.9 No Match found s CS-5 291.0 <7.3 411.5 2113 2525 84.7 3.3 <0.29 99.2 0.7 0.1 Deg.Kerosene 90.6%,(FCM) s CS-6 22.4 4.6 78.9 418.2 497.1 42.5 1.7 <0.022 97.4 2 0.6 Deg.Kerosene 69.7%,(FCM) Initial Calibrator QC check OK Final FCM QC Check OK 100 % Results generated by a QED HC-1 analyser. Concentration values in mg/kg for soil samples and mg/L for water samples. Soil values are not corrected for moisture or stone content Fingerprints provide a tentative hydrocarbon identification. The abbreviations are:- FCM = Results calculated using Fundamental Calibration Mode : % = confidence for sample fingerprint match to library (SBS) or (LBS) = Site Specific or Library Background Subtraction applied to result : (PFM) = Poor Fingerprint Match : (T) = Turbid : (P) = Particulate present Ratios QED Hydrocarbon Fingerprints Project:#340051 ################## 3541 CS-1 : Deg.Kerosene 89.5%,(FCM) 53997 CS-2 : V.Deg.PHC 90.3%,(FCM),(BO) 43877 CS-3 : Deg.Fuel 87.7%,(FCM) 4074 CS-4 : No Match found 6916 CS-5 : Deg.Kerosene 90.6%,(FCM) 20246 CS-6 : Deg.Kerosene 69.7%,(FCM)