WI-29212_48384_CA_LSA_20220808

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
August 8, 2022

Mr. Stephen Kay
NCDEQ-UST Section
Wilmington Regional Office
127 Cardinal Drive Extension
Wilmington, NC 28405

Re: Limited Site Assessment Report
Rose Ice and Coal
1202 Market Street
Wilmington, New Hanover County,
North Carolina
Incident Number: 48384
GRI Project Number: 5716

Dear Mr. Kay,

Please find enclosed the referenced report for the above mentioned site.
If you have any questions, please contact Scott Driscoll at 704-845-4010.

Sincerely,
Geological Resources, Inc.

Johanna Moats
AP/AR Coordinator

Enclosure

Cc: Mr. Archie L. Harris, Jr., Rose Ice and Coal Company, file

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Engineering Certification: C-2727 • Geology Certification: C-127
High Risk Limited Site Assessment Report
Rose Ice and Coal
1202 Market Street
Wilmington, New Hanover County, North Carolina

UST Facility ID Number: 00-0-000002143
Incident Number: 48384
GRI Project Number: 5716

Prepared for:

Mr. Archie Harris
Rose Ice and Coal
1202 Market Street
Wilmington, North Carolina 28401

July 29, 2022

Scott Driscoll
Project Manager
Michael S. Mastbaum, P.G.
Project Manager

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: July 29, 2022 Rose Ice and Coal
Project Manager: Scott Driscoll GRI Project No. 5716
i
EXECUTIVE SUMMARY
The Rose Ice and Coal site is located at 1202 Market Street in Wilmington, New Hanover County, North
Carolina. The property contains a closed convenience store that offered petroleum fuels to the public for
resale. The site is covered by asphalt, concrete and grass. There are one 10,000- and two 4,000-gallon
gasoline, one 10,000-gallon diesel fuel, and one 2,000-gallon kerosene USTs and associated piping and
dispensers in use at the site. The UST systems are currently in temporary closure. The surrounding
properties are commercial and residential.

In March 2022, during a Phase II ESA, six (6) temporary monitoring wells were drilled and installed at the
site. Groundwater samples were collected from each temporary well and analyzed for VOCs by EPA
method 6200B. Concentrations of benzene, toluene, ethylbenzene, xylenes, MTBE, naphthalene,
isopropylbenzene, n-propylbenzene, and/or 1,2,4-trimethylbenzene that exceeded the MACs were
reported in the ground water samples collected from three of the six temporary wells. A UST-61 form
was completed and forwarded to NCDEQ on April 8, 2022 at the request of Rose Coal & Ice Company. On
May 12, 2022 a NORR was issued by NCDEQ requesting an LSA be completed.

On June 29, 2022, four (4) monitoring wells (MW-1 through MW-4) were installed adjacent to both tank
beds and the dispenser island area. During the installation of MW-1 through MW-4, soil samples were
collected from the well boreholes at 3 feet bgs (SS-1-3’, SS-2-3’, SS-3-3’, SS-4-3’) and submitted for
laboratory analyses of VOCs by EPA Method 8260, SVOCs by EPA Method 8270, GRO and DRO by EPA
Method 8015C, and/or VPH and EPH by the MADEP Method. All reported contaminant concentrations
were less than the soil-to-water MCCs or RALs for the methods.

On July 7, 2022, ground water samples were collected from MW-1 through MW-4. Concentrations of
benzene, naphthalene, 1,2,4 trimethylbenzene, lead, C5-C8 aliphatics, C9-C12 aliphatics, C9-C10
aromatics, and C11-C22 aromatics reported in the ground water sample from MW-4 exceeded the MACs.
Lead concentrations reported in ground water samples collected from MW-2 and MW-3 also exceeded
the MAC. All reported contaminant concentrations were less than the GCLs. No measurable amounts of
free product were observed.

On July 7, 2022, a sensitive receptor survey was conducted. One non-potable water supply well (WSW-1)
was identified at 1122 Market Street on the adjoining property approximately 225 feet to the west of the
source area. The adjoining property is owned by Mr. Archie Harris of Rose Coal & Ice Company. According
to Mr. Harris, water from this well is used to cool the condensing coils and ice-making equipment while
making ice for the business. The system is reportedly a closed loop and water from the well is not used
to make the final ice product. Public water supplied from the City of Wilmington is used to make the ice
product.

Public water is available to the subject site and to all surrounding properties. No surface water bodies
were identified within a 500-foot radius of the site.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: July 29, 2022 Rose Ice and Coal
Project Manager: Scott Driscoll GRI Project No. 5716
ii

Based on the presence of a water supply well (non-potable) within 250 feet of the source area of this
release, the site should be classified as High Risk and further assessment may be warranted for this
incident.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: July 29, 2022 Rose Ice and Coal
Project Manager: Scott Driscoll GRI Project No. 5716
iii
SITE INFORMATION
1. Site Identification
 Rose Ice and Coal - Facility ID 00-0-000002143)
 Incident Number 48384 – Risk Classification: High Risk
 Location of Source Area: 1202 Market Street (Figure 1)
Wilmington, NC 27401
New Hanover County
34.236139°N, 77.934097°W (Topographical Map)
2. Information about Contacts Associated with the Leaking UST System
UST/AST Owner
Rose Ice and Coal Company
1202 Market Street
Wilmington, NC 28401
[e-mail]
[phone]

UST/AST Operator
Archie Harris Jr.
1202 Market Street
Wilmington, NC 28401
[e-mail]
[phone]

Property Owner
Archie Harris Jr.
1202 Market Street
Wilmington, NC 28401
[e-mail]
[phone]

Property Occupant
Rose Ice and Coal Company
1202 Market Street
Wilmington, NC 28401
[e-mail]
[phone]

Consultant/Contractor
Geological Resources, Inc.
3502 Hayes Road
Monroe, NC 28110
[e-mail]
704-845-4010

Analytical Laboratory
Waypoint Analytical
449 Springbrook Road
Charlotte, NC 28217
NC Cert No. 402/37735
704-529-6364
3. Information about Release
 Release was discovered upon receipt of laboratory results on March 22, 2022.
 An unknown amount of product was released from the operation of a UST System(s).
 One 10,000-gallon and two 4,000-gallon gasoline, one 10,000-gallon diesel fuel, and one 2,000-
gallon kerosene USTs are housed in two tank basins on the site. Currently the USTs at the site are
in temporary closure.

Certification:

I, Michael S. Mastbaum, a Licensed Geologist for Geological Resources, Inc., do certify that the information
contained in this report is correct and accurate to the best of my knowledge.

Geological Resources, Inc. is licensed to practice geology and engineering in North Carolina. The
certification numbers of the corporation are C-127 and C-2727, respectively.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: July 29, 2022 Rose Ice and Coal
Project Manager: Scott Driscoll GRI Project No. 5716
iii
ACRONYMS
ACM: Asbestos Containing Materials
AFVR: Aggressive Fluid-Vapor Recovery
ARR: Acknowledgement of Report Receipt
AS: Air Sparging
AST: Aboveground Storage Tank
ASTM: American Society for Testing and
Materials
BGS: Below Ground Surface
CAP: Corrective Action Plan
CFR: Code of Federal Regulations
CSA: Comprehensive Site Assessment
DPE: Dual Phase Extraction
DRO: Total Petroleum Hydrocarbons Diesel
Range Organics
DWM: Division of Waste Management
DWR: Department of Water Resources
EPA: Environmental Protection Agency
EPH: Extractible Petroleum Hydrocarbons
ESA: Environmental Site Assessment
GCL: Gross Contamination Level
GRI: Geological Resources, Inc.
GRO: Total Petroleum Hydrocarbons
Gasoline Range Organics
LSA: Limited Site Assessment
MAC: Maximum Allowable Concentration as
specified in T15A NCAC 2L.0202
MADEP: Massachusetts Department of
Environmental Protection
MCC: Maximum Contaminant Concentrations
MMPE: Mobile Multi-Phase Extraction
NAPL: Non-Aqueous Phase Liquid, “Free
Product”
NCDEQ: North Carolina Department of
Environmental Quality
NCDOT: North Carolina Department of
Transportation
NFA: Notice of No Further Action
NORR: Notice of Regulatory Requirements
NOV: Notice of Violation
NPDES: National Pollutant Discharge
Elimination System
NRP: Notice of Residual Petroleum
O&M: Operation and Maintenance
PAHs: Polynuclear Aromatic Hydrocarbons
PCA: Pre-Construction Assessment
RAL: Regulatory Action Level
SCLs: Soil Cleanup Level
SPCC: Spill Prevention Control and
Countermeasures
SVE: Soil Vapor Extraction
SVOCs: Semi-Volatile Organic Compounds
SWPPP: Stormwater Pollution Prevention Plan
SWAPR: Source Water Assessment Program
Report
TCLP: Toxicity Characteristic Leaching
Procedure (EPA Method SW-846 1311)
TOC: Top of Casing
TPH: Total Petroleum Hydrocarbons
USGS: United States Geological Survey
UST: Underground Storage Tank
UVF: Ultraviolet Fluorescence
VOCs: Volatile Organic Compounds
VPH: Volatile Petroleum Hydrocarbons

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: July 29, 2022 Rose Ice and Coal
Project Manager: Scott Driscoll GRI Project No. 5716
TABLE OF CONTENTS

EXECUTIVE SUMMARY ....................................................................................................................... i
SITE INFORMATION ........................................................................................................................... iii
ACRONYMS ....................................................................................................................................... iv
1. RISK CHARACTERIZATION .....................................................................................................1
2. RECEPTOR INFORMATION .....................................................................................................3
3. SITE GEOLOGY AND HYDROGEOLOGY ...................................................................................4
4. SITE INVESTIGATION .............................................................................................................5
5. CONCLUSIONS AND RECOMMENDATIONS ............................................................................7
6. LIMITATIONS ........................................................................................................................8

FIGURES
Figure 1: Site Location Map
Figure 2: Site Vicinity/Zoning Map
Figure 3: Site Map
Figure 4: Soil Quality Map
Figure 5: Water Table Surface Map
Figure 6: Ground Water Quality Map

TABLES
Table 1: UST Owner/Operator Information
Table 2: UST System Information
Table 3: Receptor Information
Table 4: Adjacent Property Owner Information
Table 5: Well Construction and Gauging Information
Table 6: Summary of Soil Sample Analytical Results
Table 7: Summary of Ground Water Sample Analytical Results

APPENDICES
Appendix A: New Hanover County Property Cards
Appendix B: Well Construction Record and Subsurface Log
Appendix C: NCDEQ Correspondence
Appendix D: Laboratory Report – Soil
Appendix E: Laboratory Report - Ground Water

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: July 29, 2022 Rose Ice and Coal
Project Manager: Scott Driscoll GRI Project No. 5716
1
1. RISK CHARACTERIZATION
Limited Site Assessment Risk Classification and Land Use Form
Part I – Groundwater/Surface Water/Vapor Impacts
High Risk
1. Has the release contaminated any water supply well including any well used for non-drinking
purposes? NO

2. Is a water supply well used for drinking water located within 1,000 feet of the source area of the
release? NO

3. Is a water supply well not used for drinking water (e.g., irrigation, washing cars, industrial cooling
water, filling swimming pools) located within 250 feet of the source area of the release?
YES

4. Does ground water within 500 feet of the source area of the release have the potential for future
use (there is no other source of water supply other than the groundwater)? NO

Public water is available to the site and surrounding properties.

5. Do vapors from the release pose a threat of explosion because of accumulation of the vapors in a
confined space or pose any other serious threat to public health, public safety or the
environment?
NO

6. Are there any other factors that would cause the release to pose an imminent danger to public
health, public safety, or the environment? NO
If YES, explain:

Intermediate Risk
7. Is a surface water body located within 500 feet of the source area of the release? NO

If YES, does the maximum groundwater contaminant concentration exceed the surface water
quality standards and criteria found in 15A NCAC 2B .0200 by a factor of 10? N/A

8. Is the source area of the release located within an approved or planned wellhead protection area
as defined in 42 USC 300h-7(e)? NO

9. Is the release located in the Coastal Plain physiographic region as designated on a map entitled
“Geology of North Carolina” published by the Department in 1985? YES

10. If YES, is the source area of the release located in an area in which there is recharge to an
unconfined or semi-confined deeper aquifer that is being used or may be used as a source of
drinking water? NO
If YES, describe.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: July 29, 2022 Rose Ice and Coal
Project Manager: Scott Driscoll GRI Project No. 5716
2
11. Do the levels of ground water contamination for any contaminant exceed the gross contamination
levels established by the Department? NO

Part II - Land Use
Property Containing Source Area of Release
The questions below pertain to the property containing the source area of the release.
1. Does the property contain one or more primary or secondary residences (permanent or
temporary)? NO
Explain:

2. Does the property contain a school, daycare center, hospital, playground, park, recreation area,
church, nursing home, or other place of public assembly? NO
Explain:

3. Does the property contain a commercial (e.g., retail, warehouse, office/business space, etc.) or
industrial (e.g., manufacturing, utilities, industrial research and development,
chemical/petroleum bulk storage, etc.) enterprise, an inactive commercial or industrial
enterprise, or is the land undeveloped? YES
Explain:
The subject property is an inactive convenience store which sold petroleum from USTs.

4. Do children visit the property? YES
Explain:
The site is currently inactive, though it is adjacent to a school, children may visit the property.

5. Is access to the property reliably restricted consistent with its use (e.g., by fences, security
personnel or both)? NO
Explain:
The property is easily accessible to pedestrian and vehicular traffic.
6. Do pavement, buildings, or other structures cap the contaminated soil? YES
Explain:
The site is currently covered with concrete and asphalt.

If yes, what mechanisms are in place or can be put into place to ensure that the contaminated soil
will remain capped in the foreseeable future?
The site could be reopened and used as a convenience store and petroleum retail facility, or the
existing structure could be repurposed.
7. What is the zoning status of the property?
According to the New Hanover County GIS webpage, the site is zoned UMX (Urban Mixed Use)
(Figure 2B).

8. Is the use of the property likely to change in the next 20 years? NO

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: July 29, 2022 Rose Ice and Coal
Project Manager: Scott Driscoll GRI Project No. 5716
3
Explain:

The subject property is currently an inactive convenience store and could be repurposed in the
future.
Property Surrounding Source Area of Release
The questions below pertain to the area within 1,500 feet of the source area of the release (excludes
property containing source area of the release):

9. What is the distance from the source area of the release to the nearest primary or secondary
residence (permanent or temporary)?

The closest primary residence is 13 South 12th Street located approximately 200 feet south of the
UST basin.

10. What is the distance from the source area of the release to the nearest school, daycare center,
hospital, playground, park, recreation area, church, nursing home or other place of public
assembly?

New Hanover High School is located at 1307 Market Street, approximately 400 feet northeast of
the source area at the site.

11. What is the zoning status of properties in the surrounding area?
According to the New Hanover County GIS webpage, the surrounding areas are zoned office and
institutional (O&I), urban mixed use (UMX), and residential (R-3, R-5, and R-7).

12. Briefly characterize the use and activities of the land in the surrounding area.

The area surrounding the site is a mixture of commercial and residential. Land use information is
included on Figures 2A and 2B.

2. RECEPTOR INFORMATION
1. Water Supply Wells:

On July 7, 2022, a receptor survey was conducted. One non-potable water supply well was
identified on an adjoining property at 1122 Market Street. Water from the well is used for cooling
the condensing coils/unit during the ice making process of the Rose Coal & Ice business. The well
is located approximately 225 west of the source area. Public water is available to the subject site
and to all surrounding properties. No surface water bodies were identified within a 500-foot
radius of the site. A Site Location Map is provided as Figure 1 and a Site Vicinity Map showing
property boundaries for the site and surrounding properties is included as Figure 2. Water supply
well information is provided in Table 3.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: July 29, 2022 Rose Ice and Coal
Project Manager: Scott Driscoll GRI Project No. 5716
4
2. Public Water Supplies:
Are public water supplies available within 1,500 feet of the source area of the release? YES
If yes, where is the location of the nearest public water lines and the source(s) of the public water
supply. Explain:
Municipal water is available to the site and the surrounding properties. Water lines run along the
public streets in the area. Public water is supplied by the Cape Fear Public Utility Authority or City
of Wilmington.

3. Surface Water:
Identify all surface water bodies (e.g., ditch, pond, stream, lake, river) within 1,500 feet of the
source area of the release. This information must be shown on the USGS topographic map.
No surface water bodies were identified within 1,500 feet of the release.

4. Wellhead Protection Areas:
Identify all planned or approved wellhead protection areas in the vicinity of the source area. This
information must be shown on the USGS topographic map. Wellhead protection areas are defined
in 42 USC 300h-7(e).
On July 28, 2022, GRI personnel accessed the NCDEQ SWAP Program’s website to identify
wellhead protection areas in the vicinity of the subject site. The site is not located within a
wellhead protection area.

5. Deep Aquifers in the Coastal Plain Physiographic Region:
The site is located in the Coastal Plain Physiographic Region. The surficial aquifer in the vicinity of
the site is approximately 19 feet thick and is underlain by the Castle Hayne confining unit (from
approximately 19 to 24 feet bgs) and aquifer (from approximately 24 to 51 feet bgs). The Castle
Hayne aquifer is underlain by the Peedee confining unit (from approximately 51 to 72 feet bgs)
and Peedee aquifer.

6. Subsurface Structures:
No structures with basements were observed in the vicinity of the source area. The water main
and other underground utilities run along Market and 12th Street and several underground utility
lines were observed on the property.

7. Property Owners and Occupants:
The names and addresses of the owners of properties adjacent to the site are presented in Table
4. Property boundaries are shown on Figure 2A. Property cards for the adjacent property owners
are attached as Appendix A.

3. SITE GEOLOGY AND HYDROGEOLOGY
According to the 1985 Geologic Map of North Carolina, the site is underlain by the Peedee Formation.
The formation is generally described as greenish gray to olive black sand, clayey sand, and clay. The

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: July 29, 2022 Rose Ice and Coal
Project Manager: Scott Driscoll GRI Project No. 5716
5
formation is massive, glauconitic, and locally fossiliferous and calcareous. Patches of sandy molluscan-
mold limestone may be present in the upper part.

On June 29, 2022, four Type II monitoring wells (MW-1 through MW-4) were installed at the site. The soil
encountered during monitoring well installation consisted predominantly of tan to brown fine sand
underlain by brown to gray sandy clay and clayey fine sand. The depth to ground water during the June
2022 gauging event ranged from 8.49 to 10.01 feet below the TOC. Copies of the well construction
records and subsurface boring logs are included in Appendix B. A Site Map showing the location of the
monitoring wells is included as Figure 3.

4. SITE INVESTIGATION
In March 2022, during a Phase II ESA, six (6) temporary monitoring wells were drilled and installed at the
site. Groundwater samples were collected from each temporary well and analyzed for VOCs by EPA
Method 6200B. Concentrations of benzene, toluene, ethylbenzene, xylenes, MTBE, naphthalene,
isopropylbenzene, n-propylbenzene, and/or 1,2,4-trimethylbenzene that exceeded the MACs were
reported in the ground water samples collected from three of the temporary wells. A UST-61 form was
completed and forwarded to the NCDEQ on April 8, 2022 at the request of Rose Coal & Ice Company. On
May 12, 2022 a NORR was issued by NCDEQ requesting an LSA be completed. A copy of the NCDEQ
correspondence and registered tank report are included as Appendix C.

On June 29, 2022, four (4) type II ground water monitoring wells (MW-1 through MW-4) were installed
adjacent to both tank beds and adjacent to the dispenser island at site. During the installation of MW-1
through MW-4, four (4) soil samples (SS-1-3’, SS-2-3’, SS-3-3’, SS-4-3’) were collected at 3 feet bgs from
each borehole and submitted for laboratory analyses of VOCs by EPA Method 8260, SVOCs by EPA Method
8270, VPH and EPH by the MADEP Method, and/or GRO and DRO by EPA Method 8015.

On July 7, 2022, ground water samples were collected from MW-1 through MW-4 and submitted for
laboratory analysis of VOCs and oxygenates by EPA Method 6200B, SVOCs by EPA Method 625.1, EDB by
EPA Method 504.1, and VPH and EPH by the MADEP method. Lead analysis was also performed by EPA
Method 6010.

On July 7, 2022, a sensitive receptor survey was also conducted. One non-potable water supply well was
identified on an adjoining property at 1122 Market Street. The well is located approximately 225 west of
the source area across 12th street. The property is owned by Mr. Archie Harris of Rose Coal & Ice Company.
According to Mr. Harris, water from the well is used for cooling the condensing coils/unit during the ice
making process of the Rose Coal & Ice business. It is reportedly a closed loop system and the water from
the well is not used to make the final ice product. Public water supplied from the City of Wilmington is
used to make the ice product. No surface water bodies were identified within a 500-foot radius of the site.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: July 29, 2022 Rose Ice and Coal
Project Manager: Scott Driscoll GRI Project No. 5716
6
4.1 Soil Sampling:
All reported contaminant concentrations were less than laboratory detection limits and/or the soil-to-
water MCCs. A Soil Quality Map is included as Figure 4. A summary of the soil sample analytical results
is presented in Table 5. A copy of the laboratory report from the June 2022 soil sampling event is included
in Appendix D. An abbreviated summary of the current soil sampling data collected during the LSA
activities is shown below:
Sample ID Sample Depth (ft-BGS) Gasoline-Range TPH Diesel-Range TPH Benzene Toluene Ethylbenzene Total Xylenes Methyl-tert-butyl-ether (MTBE) Naphthalene Soil to Water MCC (mg/kg) NE NE 0.0072 5.4 8 6 0.085 0.2
Residential SCLs (mg/kg) NE NE 12 1,250 60.3 3,120 156 5.5
MW-1-3' 3 NR NR <0.0007 <0.0007 <0.0007 <0.0006 <0.0007 <0.001

4.2 Ground Water Sampling:
On July 7, 2022, MW-1 through MW-4 were gauged, purged, and sampled in accordance with NCDEQ
guidelines. Depth to ground water ranged from 8.49 to 10.01 feet below TOC. Ground water elevations
ranged from 88.88 to 91.18 feet relative to an assumed datum of 100.00 for the TOC elevation at MW-1
during the ground water gauging event. No measurable amounts free product was observed in any of the
wells during the gauging or sampling process. Ground water flow was calculated to be toward the east
with a horizontal gradient of 0.02 feet per foot. A Water Table Surface Map is included as Figure 5.
Gauging data from the July 2022 event IS included in Table 6. A summary of the current gauging data is
shown below:

Well ID
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to
Water from
Top of Casing
(ft.)
Groundwater
Elevation
(ft.)
MW-1 5 - 15 15 100.00 9.58 90.42
MW-2 5 - 15 15 100.28 9.51 90.77
MW-3 5 - 15 15 99.67 8.49 91.18
MW-4 5 - 15 15 98.89 10.01 88.88

Ground water samples were collected from MW-1 through MW-4 after the well gauging. Concentrations
of benzene, naphthalene, 1,2,4 trimethylbenzene, lead, C5-C8 aliphatics, C9-C12 aliphatics, C9-C10
aromatics and C11-C22 aromatics reported in the ground water sample from MW-4 exceeded the MACs.
The concentration of lead reported in the ground water samples collected from MW-2 and MW-3 also
exceeded the MAC. None of the reported contaminant concentrations exceeded the GCLs. A Ground
Water quality map is included as Figure 6. A summary of the ground water sample analytical results is
presented in Table 7. A copy of the laboratory report from the July 7, 2022 sampling event is included in
Appendix E. An abbreviated summary of the current ground water sampling data is shown below:

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: July 29, 2022 Rose Ice and Coal
Project Manager: Scott Driscoll GRI Project No. 5716
7
Contaminant of
Concern
 Benzene Toluene Ethylbenzene Xylenes MTBE Naphthalene Well
ID
MAC (µg/l) 1 600 600 500 20 6
GCL (µg/l) 5,000 260,000 80,000 50,000 20,000 6,000
MW-1 0.239 J 0.420 J 0.263 J 1.61 J <0.140 <0.470
MW-2 <0.180 <0.220 <0.170 <0.21 <0.140 <0.470
MW-3 <0.180 <0.220 <0.170 <0.21 <0.140 <0.470
MW-4 1.34 0.693 73.2 174 <0.140 86.0
Trip Blank <0.180 <0.220 <0.170 <0.21 <0.140 <0.470

4.3 Quality Control:
The soil and ground water samples were immediately placed in laboratory-supplied containers during
collection, which were then placed in iced coolers. New disposable bailers were used to sample the
monitoring well and new nitrile gloves were worn during soil and ground water collection. Samples were
logged using proper chain-of-custody procedures. The samples were transported to a North Carolina
certified laboratory for analysis. A laboratory supplied trip blank was included in the sample cooler.

5. CONCLUSIONS AND RECOMMENDATIONS
 The site is an inactive convenience store and UST facility operating under NCDEQ facility ID # 00-
0-0000021463. The USTs at the site are contained in two tank basins and they are currently in
temporary closure. Land use in the area consists of residential, urban mixed use, and office and
institutional properties.
 On June 29, 2022, four (4) type II ground water monitoring wells (MW-1 through MW-4) were
installed adjacent to both tank beds. During the installation of MW-1 through MW-4, soil samples
were collected from each borehole at 3 feet bgs. All reported contaminant concentrations were
less than the soil-to-water MCCs or the RALs in the soil samples collected for analysis.
 On July 7, 2022, ground water samples were collected from MW-1 through MW-4 and submitted
for laboratory analysis. No measurable amounts free product were observed in any of the wells
during the gauging or sampling process. Concentrations of benzene, naphthalene, 1,2,4
trimethylbenzene, lead, C5-C8 aliphatics, C9-C12 aliphatics, C9-C10 aromatics, and C11-C22
aromatics reported in the ground water sample from MW-4 exceeded the MACs. Concentrations
of lead reported in the ground water samples from MW-2 and MW-3 also exceeded the MAC.
None of the reported concentrations exceeded the GCLs.
 One non-potable water supply well was identified on the adjoining property to the west across
12th street. The adjoining property is owned by Mr. Archie Harris of Rose Coal & Ice Company.
According to Mr. Harris, water from the well, located 225 feet from the source area of the release,
is used to cool the condensing coils and ice making equipment while making ice for the business.
It is reportedly a closed loop system and the water from the well is not used to make the final ice

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: July 29, 2022 Rose Ice and Coal
Project Manager: Scott Driscoll GRI Project No. 5716
8
product. Public water supplied from the City of Wilmington is used to make the ice product. No
surface water bodies were identified within a 500-foot radius of the site.
 Ground water and TOC measurements indicate that ground water migration on the site is to the
east under a hydraulic gradient of 0.02 ft/ft, away from the non-potable well located at 1122
Market Street. In addition, laboratory results were reported below laboratory limits for all
analytes from MW-2, the furthest upgradient well installed between the source area and the non-
potable well.
 Based on the presence of a water supply well (non-potable) within 250 feet of the source area of
this release, the site should be classified as High Risk and further assessment may be warranted
for this incident. Removal of the source UST system has been proposed to the property owner.
Once this closure is complete, further well installations inside the tank basins would likely be
necessary as ground water will be encountered during the removal and additional soil and ground
water data will be available. Sampling of the non-potable well could be conducted as an interim
measure.

6. LIMITATIONS
This report has been prepared for the exclusive use of Rose Ice and Cole Company, Inc. for specific
application to the referenced site in New Hanover County, North Carolina. The assessment was conducted
based on the scope of work and level of effort specified by NCDEQ and with resources adequate only for
that scope of work. Our findings have been developed in accordance with generally accepted standards
of geology and hydrogeology practices in the State of North Carolina, available information, and our
professional judgment. No other warranty is expressed or implied.

The data that are presented in this report are indicative of conditions that existed at the precise locations
sampled and at the time the samples were collected. In addition, the data obtained from samples would
be interpreted as being meaningful with respect to parameters indicated in the laboratory report. No
additional information can logically be inferred from these data.

FIGURES
SITE LOCATIONFigure 1 Site LocationRose Ice and Coal Company1202 Market StreetWilmington, North CarolinaNew Hanover CountyIncident No. 48384GRI Project No. 5716500 M2000 FTDate: 06/18/2022 Location: 34.236139° N -77.934097° W Dad
SITE
3127-28-3559.0003127-28-0649.000 3127-28-2668.000
3127-28-2996.0003127-28-0984.000
3127-28-0694.000
3127-28-2920.000
3127-28-2577.000
ANN STREE T
OR ANGE STR EET
D OC K S TREE T
P RI NCE SS S TRE ET
CH ESTNU T ST R EET
16TH STREET17TH STREETMARKE T STR EET
PR IVATE 15TH STREET18TH STREET8TH STREET13TH STREET10TH STREET9TH STREET11TH STREET12TH STREET14TH STREETN UN STREE TGORES ROWPE RRY AVENU EMCRAE STREETJASMINE STREETMEA DO W S TRE E T
19TH STREETCA RO LINA AV EN UE
WALNUT STREET
KENDALL AVENUESARAH ALLEYWRIGHTSVILLE AVENUE
C OYE A LLE Y
7TH STREETMACUMBER ALLEYMAGNOLIA STREETG R AC E STREE TANDERSON STREETSAINT JAMES STREETM A R SD ON AV E N UE
WO LC OT T AVE NUE
RUFF ERT S ALL EY
XING PRIVATE XING ANN S TREE TPRIVATE P RIVATE 19TH STREETP R I VATE 12TH STREET9TH STREETXING 15TH STREETPRIVATE PRIVAT E 18TH STREETPRIVATE 11TH STREETWALNUT STREET
PR IVATE
PRIVATE XING PRIVATE PRIVATE P RI VAT E 10TH STREET8TH STREET14TH STREETPRI
VATE

PRIVATE 13TH STREETPR IVATE
PRIVATE 11TH STREETPRIVATE XING FIGURE 2A: SITE VICINITY MAPROSE ICE AND COAL COMPANY1202 MARKET STREETWILMINGTON, NEW HANOVER COUNTYNORTH CAROLINAINCIDENT NO. 48384GRI PROJECT NO. 5716
PREPARED BY:GEOLOGICAL RESOURCES, INC.JUNE 18, 20221,500-FOOT RADIUS
500-FOOT RADIUS
³
0 300150Feet
1 inch = 300 feet
1,000-FOOT RADIUS
250-FOOT RADIUS
LEGEND
Roads
ncrivers
Hydro2012
Adjacent Properties
Parcels
SITE
ANN STREE T
OR ANGE STR EET
D OC K S TREE T
P RI NCE SS S TRE ET
CH ESTNU T ST R EET
16TH STREET17TH STREETMARKE T STR EET
PR IVATE 15TH STREET18TH STREET8TH STREET13TH STREET10TH STREET9TH STREET11TH STREET12TH STREET14TH STREETN UN STREE TGORES ROWPE RRY AVENU EMCRAE STREETJASMINE STREETMEA DO W S TREE T
19TH STREETCA RO LINA AV EN UE
WALNUT STREET
KENDALL AVENUESARAH ALLEYWRIGHTSVILLE AVENUE
C OYE A LLE Y
7TH STREETMACUMBER ALLEYMAGNOLIA STREETG R AC E STREE TANDERSON STREETSAINT JAMES STREETM A R SD ON AV E N UE
WO LC OT T AVE NUE
RUFF ERT S ALL EY
XING PRIVATE XING ANN S TREE TPRIVATE P RI VATE 19TH STREETP R I VATE 12TH STREET9TH STREETXING 15TH STREETPRIVATE PRIVAT E 18TH STREETPRIVATE 11TH STREETWALNUT STREET
PR IVATE
PRIVATE XING PRIVATE PRIVATE P RI VAT E 10TH STREET8TH STREET14TH STREETPRI
VATE

PRIVATE 13TH STREETPR IVATE
PRIVATE 11TH STREETPRIVATE XING FIGURE 2B: ZONING MAPROSE ICE AND COAL COMPANY1202 MARKET STREETWILMINGTON, NEW HANOVER COUNTYNORTH CAROLINAINCIDENT NO. 48384GRI PROJECT NO. 5716
PREPARED BY:GEOLOGICAL RESOURCES, INC.JUNE 18, 20221,500-FOOT RADIUS
500-FOOT RADIUS
³
0 300150Feet
1 inch = 300 feet
1,000-FOOT RADIUS
250-FOOT RADIUS
LEGEND
Roads
ncrivers
ZONING -R-3(CD)
ZONING - HDR
ZONING - CS
ZONING - MD-17
ZONING - R-7
ZONING - R-3
ZONING - R-5
ZONING - O&I
ZONING - UMX
Hydro2012
Parcels
XXXXXXXXXXXXXXXXX
XXXXXXXXXXXXXXXXX
XXXXXXXXXXXXXXXXX
XXXXXXXXXXXXXXXXX
XXXXXXXXXXXXXXXXX

TABLES
UST ID Number 1-5 Facility ID Number
Owner or Operator?
Owner
UST ID Number 1-5 Facility ID Number
Owner or Operator?
Operator
1202 Market Street, Wilmington, NC 28401 1-800-282-3703
0-0000021463
Name of Owner or Operator Dates of Ownership / Operation
Archie L. Harris, Jr.01/25/2021 - Current
Address Telephone Number
Rose Ice and Coal Co 12/27/1978 - Current
Address Telephone Number
1202 Market Street, Wilmington, NC 28401 1-800-282-3703
Name of Owner or Operator Dates of Ownership / Operation
TABLE 1
UST OWNER/OPERATOR INFORMATION
ROSE ICE & COAL COMPANY (INCIDENT NO. 48384)
0-0000021463
Page 1 of 7
Date: 08/02/2022
Was Release
Associated
with UST
System?
(Yes / No)
1 Gasoline NA 4,000 04/06/1987 Single Wall Steel Unknown DW Flexible
Piping
Temporary
Closure
(5/12/2021)
No
2 Gasoline NA 4,000 04/06/1987 Single Wall Steel Unknown DW Flexible
Piping
Temporary
Closure
(11/29/2017)
Yes
3 Gasoline NA 10,000 04/06/1987 Single Wall Steel Unknown DW Flexible
Piping
Temporary
Closure
(5/12/2021)
Yes
4 Diesel NA 10,000 04/06/1987 Single Wall Steel Unknown DW Flexible
Piping
Temporary
Closure
(5/12/2021)
No
5 Kerosene NA 2,000 04/06/1987 Single Wall Steel Unknown DW Flexible
Piping
Temporary
Closure
(9/30/2011)
No
Tank
Dimensions
Description of
Associated
Product Piping
and
Pumps
Status
of
UST
TABLE 2
UST SYSTEM INFORMATION
ROSE ICE & COAL COMPANY (INCIDENT NO. 48384)
Facility ID #: 0-0000021463
UST
ID
No.
Current
or Most
Recent
Contents
Previous
Contents
Capacity
(gallons)
Date
Installed
Construction
Details
Page 2 of 7
Facility ID # : 0-0000021463
Well ID.Parcel ID No.Well Owner Mailing Address Well Address Well Status
(Active/In-Active)
Well Use
(Potable / Non-
Potable
etc.)
Municpal
Water
Available
Yes/No
Connected
to
Municipal
Water
Yes/No
Distance
from source
area of
release
(ft.)
WSW-1 04818-028-004 Archie L Harris, Jr.Rose Coal & Ice, 1122 Market Street
Wilmington, NC 28401
1122 Market Street
Wilmington, NC 28401 Active Non-Potable Yes Yes ~225' W
Notes:
• Non-potable water supply well WSW-1 is shown on Figure 2A.
• n/a: not applicable.
Unknown
TABLE 3
RECEPTOR INFORMATION
ROSE ICE & COAL COMPANY (INCIDENT NO. 48384)
Date: 08/02/2022
Well Construction Details
(Depth, Screened Interval, Type of Well, ect.)
Page 3 of 7
Date: 08/02/2022 Facility ID #: 0-0000021463
PIN Number Map ID Property Owner Name Property Owner Address
04818-027-001 (site)312705-28-2668 Archie and Sally Ann Harris, Jr.1202 Market Street
Wilmington, NC 28401
04818-027-007 312705-28-0984 New Hanover County Board of
Educuation
6410 Carolina Beach Road
Wilmington, NC 28401
04818-027-002 312705-28-2577 1202 Market Street
Wilmington, NC 28401
04818-028-003 312705-28-0694
04818-028-004 312705-28-0649
04818-020-004 312705-28-2920 Sinclair Station, Inc.1207 Market Street
Wilmington, NC 28401
04818-020-005 312705-28-2996 Moore Property Investments, LLC 1209 Market Street
Wilmington, NC 28401
04818-019-007 312705-28-3559 Hughes Bros, Inc.1121 Market Street
Wilmington, NC 28401
Note:
• Properties are keyed to Figure 2A.
TABLE 4
ADJACENT PROPERTY OWNER INFORMATION
ROSE ICE & COAL COMPANY (INCIDENT NO. 48384)
1122 Market Street
Wilmington, NC 28401
Archie L Harris, Jr.
Page 4 of 7
Date: 07/13/2022 Facility ID #: 0-0000021463
Sample IDDate Collected (mm/dd/yy)Sample Depth(ft-BGS)Gasoline-Range TPHDiesel-Range TPHBenzeneTolueneEthylbenzeneTotal XylenesMethyl-tert-butyl-ether (MTBE)Naphthalene1-Methylnaphthalene2-MethylnaphthaleneC5-C8 AliphaticsC9-C12 AliphaticsC9-C10 AromaticsC9-C18 AliphaticsC19-C36 AliphaticsC11-C22 Aromatics50 100 NE NE NE NE NE NE NE NE NE NE NE NE NE NE
NE NE 0.0072 5.4 8 6 0.085 0.2 0.054 1.5 68 540 31 540 #31
NE NE 12 1,250 60.3 3,120 156 5.5 22.8 62.5 625 1,560 469 1,560 31,200 469
MW-1-3'06/29/22 3 NR NR <0.0007 <0.0007 <0.0007 <0.0006 <0.0007 <0.001 <0.120 <0.113 <1.38 <5.17 <0.707 <19.4 <13.8 <16.1
MW-2-3'06/29/22 3 <2.64 <5.93 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
MW-3-3'06/29/22 3 <2.79 <6.26 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
MW-4-3'06/29/22 3 <2.63 <5.91 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
Notes:
• Results reported in mg/kg (milligrams per kilograms)
• Trip Blank results reported in ug/l (micrograms per liter)
• ft-BGS: feet below ground surface.
• RAL: Regulatory Action Level.
• MCCs: Maximum Contaminant Concentrations (soils).
• SCLs: Soil Cleanup Levels.
• < : Less than the method detection limit specified in the laboratory report
• # : Health based level >100%
• Estimated J concentration of Acetone and MEK below MSCCs. Refer to lab report. All EPA 8260/625/VPH and EPH data below lab limits for soil from MW-1
• Concentrations in bold face type indicate the soil to water MCCs were below the reported concentrations.
• Concentrations in italic type indicate the Residential SCLs were below the report concentrations.
• NE: Not Established
• NR: Not Requested.
MADEP EPHEPA Method 8260D EPA Method 8270E
TABLE 5
SUMMARY OF SOIL SAMPLE ANALYTICAL RESULTS
ROSE ICE & COAL COMPANY (INCIDENT NO. 48384)
Analytical Method →MADEP VPH
RAL (mg/kg)
Soil to Water MCC (mg/kg)
Residential SCLs (mg/kg)
5030/ 8015D
Page 5 of 7
Date: 07/13/2022
Well ID
Date
Installed
(m/dd/yy)
Date Water
Level
Measured
(m/dd/yy)
Well
Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to
Water from
Top of Casing
(feet)
Free Product
Thickness
(ft.)
Ground
Water
Elevation (ft.)
Comments
MW-1 06/29/2022 07/07/22 5 5-15 15 100.00 9.58 ---90.42
MW-2 06/29/2022 07/07/22 5 5-15 15 100.28 9.51 ---90.77
MW-3 06/29/2022 07/07/22 5 5-15 15 99.67 8.49 ---91.18
MW-4 06/29/2022 07/07/22 5 5-15 15 98.89 10.01 ---88.88
Notes:
• Well depths based on field measuurements.
TABLE 6
WELL CONSTRUCTION AND GAUGING INFORMATION
ROSE ICE & COAL COMPANY (INCIDENT NO. 48384)
Facility ID # : 0-0000021463
• ft BGS : feet below ground surface.
• NM : Not measured.
Page 6 of 7
EPA 504.1 SW-6010D
Well
ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 70 70 400 400 0.02 15 400 700 200 700 10,000 200
5,000 260,000 80,000 50,000 20,000 6,000 30,500 26,100 28,500 24,100 50 15,000 NE NE NE NE NE NE
MW-1 07/07/22 0.239 J 0.420 J 0.263 J 1.61 J <0.140 <0.470 <0.180 <0.190 1.02 0.412 J <0.00340 8 <11.5 <25.8 <4.02 95.7 JB <225 <111
MW-2 07/07/22 <0.180 <0.220 <0.170 <0.21 <0.140 <0.470 <0.180 <0.190 <0.190 <0.180 <0.00343 864 <11.5 <25.8 <4.02 88.9 JB <225 <111
MW-3 07/07/22 <0.180 <0.220 <0.170 <0.21 <0.140 <0.470 <0.180 <0.190 <0.190 <0.180 <0.00345 43 <11.5 <25.8 <4.02 49.0 JB <168 <82.7
MW-4 07/07/22 1.34 0.693 73.2 174 <0.140 86.0 22.2 62.2 774 149 <0.00343 137 2,330 2,140 2,370 187 JB <191 404
07/07/22 <0.180 <0.220 <0.170 <0.21 <0.140 <0.470 <0.180 <0.190 <0.190 <0.180 NR NR NR NR NR NR NR NR
Notes:
• Concentrations in bold face type indicate the MACs were below the reported concentrations.
• Concentrations in italics indicate the GCLs were below the reported concentrations.
full report Appendix E for estimated and concentrations below quantitation limits C9-C18 AliphaticsC19-C36 AliphaticsC11-C22 AromaticsMADEP EPH
1,2-Dibromoethane (EDB)• NR: Not requested.
Trip Blank
MADEP VPH
Facility ID # : 0-0000021463
TABLE 7
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
ROSE ICE & COAL COMPANY (INCIDENT NO. 48384)
SM 6200B
• C11-C22 Aromatics detected above the MACs in MW-4 by EPH. See lab report for C9-C12 AliphaticsC9-C10 AromaticsLeadC5-C8 Aliphatics1,2,4-Trimethylbenzene1,3,5-Trimethylbenzenen-PropylbenzeneIsopropylbenzeneTolueneEthylbenzene• J: Estimated value.
• Results reported in µg/l (micrograms per liter)
• MAC: Maximum Allowable Concenration as specified in T15A NCAC 2L.0202.
• GCL: Gross contamination level.
• NE: Standard not established.
• < : Less than the method detection limit specified in the laboratory report.
Date: 07/27/2022
Analytical Method
→XylenesMTBEMACs (μg/l)
GCL (μg/l)NaphthaleneContaminant of Concern
→BenzenePage 7 of 7

APPENDICES

APPENDIX A
New Hanover County Property Cards
7/29/22, 2:19 PM New Hanover County
https://etax.nhcgov.com/pt/Datalets/PrintDatalet.aspx?pin=R04818-027-001-000&gsp=PROFILEALL&taxyear=2022&jur=NH&ownseq=0&card=1&roll=…1/1
PARID: R04818-027-001-000
HARRIS ARCHIE JR SALLY ANN 1202 MARKET ST
Parcel
Alt ID 312705.28.2668.000
Address 1202 MARKET ST
Unit
City WILMINGTON
Zip Code -
Neighborhood CHBM5
Class COM-Commercial
Land Use Code 558-Gas Station/ Service Station
Living Units
Acres
Zoning UMX-URBAN MIXED USE
Legal
Legal Description PT 1/2/3 WILM BLK 163/PT ST
Tax District WM
Owners (On January1st)
Owner HARRIS ARCHIE JR SALLY ANN
City WILMINGTON
State NC
Country
Zip 28401
THE DATA IS FROM 2022
7/29/22, 2:21 PM New Hanover County
https://etax.nhcgov.com/pt/Datalets/PrintDatalet.aspx?pin=R04818-028-003-000&gsp=PROFILEALL&taxyear=2022&jur=NH&ownseq=0&card=1&roll=…1/1
PARID: R04818-028-003-000
HARRIS ARCHIE L JR 1122 MARKET ST
Parcel
Alt ID 312705.28.0694.000
Address 1122 MARKET ST
Unit
City WILMINGTON
Zip Code -
Neighborhood CHBM5
Class COM-Commercial
Land Use Code 730-Office and Professional
Living Units
Acres .18
Zoning UMX-URBAN MIXED USE
Legal
Legal Description PT E END 2/3 BLK 162 / PT MEADOW ST
Tax District WM
Owners (On January1st)
Owner HARRIS ARCHIE L JR
City WILMINGTON
State NC
Country
Zip 28401
THE DATA IS FROM 2022
7/29/22, 2:20 PM New Hanover County
https://etax.nhcgov.com/pt/Datalets/PrintDatalet.aspx?pin=R04818-028-004-000&gsp=PROFILEALL&taxyear=2022&jur=NH&ownseq=0&card=1&roll=…1/1
PARID: R04818-028-004-000
HARRIS ARCHIE L JR 1122 MARKET ST
Parcel
Alt ID 312705.28.0649.000
Address 1122 MARKET ST
Unit
City WILMINGTON
Zip Code -
Neighborhood CHBM5
Class COM-Commercial
Land Use Code 388-Manufacturing
Living Units
Acres .38
Zoning UMX-URBAN MIXED USE
Legal
Legal Description E END 1 PT 2 BLK 162 / PT MEADOW ST
Tax District WM
Owners (On January1st)
Owner HARRIS ARCHIE L JR
City WILMINGTON
State NC
Country
Zip 28401
THE DATA IS FROM 2022
7/29/22, 2:23 PM New Hanover County
https://etax.nhcgov.com/pt/Datalets/PrintDatalet.aspx?pin=R04818-029-007-000&gsp=PROFILEALL&taxyear=2022&jur=NH&ownseq=0&card=1&roll=…1/1
PARID: R04818-029-007-000
HARRIS ARCHIE L JR 6 12TH ST S
Parcel
Alt ID 312705.28.1502.000
Address 6 S 12TH ST
Unit
City WILMINGTON
Zip Code -
Neighborhood CHD01
Class COM-Commercial
Land Use Code 958-Unused Land
Living Units
Acres .41
Zoning UMX-URBAN MIXED USE
Legal
Legal Description E END 5 PT 4 BLK 162 / PT MEADOW ST
Tax District WM
Owners (On January1st)
Owner HARRIS ARCHIE L JR
City WILMINGTON
State NC
Country
Zip 28401
THE DATA IS FROM 2022
7/29/22, 2:25 PM New Hanover County
https://etax.nhcgov.com/pt/Datalets/PrintDatalet.aspx?pin=R04818-019-007-000&gsp=PROFILEALL&taxyear=2022&jur=NH&ownseq=0&card=1&roll=…1/1
PARID: R04818-019-007-000
HUGHES BROS INC 1121 MARKET ST
Parcel
Alt ID 312705.28.0984.000
Address 1121 MARKET ST
Unit
City WILMINGTON
Zip Code -
Neighborhood CHBM5
Class COM-Commercial
Land Use Code 958-Unused Land
Living Units
Acres
Zoning UMX-URBAN MIXED USE
Legal
Legal Description PT E 4/5 PT 3 BLK 175
Tax District WM
Owners (On January1st)
Owner HUGHES BROS INC
City WILMINGTON
State NC
Country
Zip 28401
THE DATA IS FROM 2022
7/29/22, 2:24 PM New Hanover County
https://etax.nhcgov.com/pt/Datalets/PrintDatalet.aspx?pin=R04818-020-004-000&gsp=PROFILEALL&taxyear=2022&jur=NH&ownseq=0&card=1&roll=…1/1
PARID: R04818-020-004-000
SINCLAIR STATION INC 1207 MARKET ST
Parcel
Alt ID 312705.28.2920.000
Address 1207 MARKET ST
Unit
City WILMINGTON
Zip Code -
Neighborhood CHBM5
Class COM-Commercial
Land Use Code 958-Unused Land
Living Units
Acres
Zoning UMX-URBAN MIXED USE
Legal
Legal Description PT LTS 4/5 BLK 176 WILM
Tax District WM
Owners (On January1st)
Owner SINCLAIR STATION INC
City WILMINGTON
State NC
Country
Zip 28405
THE DATA IS FROM 2022
7/29/22, 2:24 PM New Hanover County
https://etax.nhcgov.com/pt/Datalets/PrintDatalet.aspx?pin=R04818-020-005-000&gsp=PROFILEALL&taxyear=2022&jur=NH&ownseq=0&card=1&roll=…1/1
PARID: R04818-020-005-000
MARKET PROPERTY LLC 1209 MARKET ST
Parcel
Alt ID 312705.28.2996.000
Address 1209 MARKET ST
Unit
City WILMINGTON
Zip Code -
Neighborhood CHBM5
Class COM-Commercial
Land Use Code 730-Office and Professional
Living Units
Acres
Zoning UMX-URBAN MIXED USE
Legal
Legal Description PT LTS 3/4/5 BLK 176 WILM
Tax District WM
Owners (On January1st)
Owner MOORE PROPERTY INVESTMENTS LLC
City WILMINGTON
State NC
Country
Zip 28402
THE DATA IS FROM 2022
7/29/22, 2:22 PM New Hanover County
https://etax.nhcgov.com/pt/Datalets/PrintDatalet.aspx?pin=R04818-027-007-000&gsp=PROFILEALL&taxyear=2022&jur=NH&ownseq=0&card=1&roll=…1/1
PARID: R04818-027-007-000
NEW HANOVER COUNTY BOARD OF
EDUCATION N/A
Parcel
Alt ID 312705.28.3559.000
Address
Unit
City
Zip Code -
Neighborhood CHBM5
Class GOV-Exempt Government
Land Use Code 821-School
Living Units
Acres
Zoning O&I-1-OFFICE & INSTITUTION (GENERAL)
Legal
Legal Description 163 PT WM 1/2/3/4/5
Tax District WM
Owners (On January1st)
Owner NEW HANOVER COUNTY BOARD OF EDUCATION
City WILMINGTON
State NC
Country
Zip 28412
THE DATA IS FROM 2022
7/29/22, 2:27 PM New Hanover County
https://etax.nhcgov.com/pt/Datalets/PrintDatalet.aspx?pin=R04818-020-006-000&gsp=PROFILEALL&taxyear=2022&jur=NH&ownseq=0&card=1&roll=…1/1
PARID: R04818-020-006-000
NEW HANOVER COUNTY BOARD OF
EDUCATION 1307 MARKET ST
Parcel
Alt ID 312706.29.5048.000
Address 1307 MARKET ST
Unit
City WILMINGTON
Zip Code -
Neighborhood CHBM5
Class GOV-Exempt Government
Land Use Code 821-School
Living Units
Acres 4.65
Zoning O&I-1-OFFICE & INSTITUTION (GENERAL)
Legal
Legal Description (4.65 ACRES) ALL BLK 482 PT BLK 176 WIL
Tax District WM
Owners (On January1st)
Owner NEW HANOVER COUNTY BOARD OF EDUCATION
City WILMINGTON
State NC
Country
Zip 28412
THE DATA IS FROM 2022
7/29/22, 2:21 PM New Hanover County
https://etax.nhcgov.com/pt/Datalets/PrintDatalet.aspx?pin=R04818-027-002-000&gsp=PROFILEALL&taxyear=2022&jur=NH&ownseq=0&card=1&roll=…1/1
PARID: R04818-027-002-000
HARRIS ARCHIE L JR N/A
Parcel
Alt ID 312705.28.2577.000
Address
Unit
City
Zip Code -
Neighborhood H4D15
Class COM-Commercial
Land Use Code 958-Unused Land
Living Units
Acres
Zoning UMX-URBAN MIXED USE
Legal
Legal Description PT 3/4 BLK 163 WILM / PT ST
Tax District WM
Owners (On January1st)
Owner HARRIS ARCHIE L JR
City WILMINGTON
State NC
Country
Zip 28401
THE DATA IS FROM 2022

APPENDIX B
Well Construction Records and Subsurface Logs
Geological Resources, Inc.Phone:[phone]
3502 Hayes Road Fax:[phone]
Monroe, NC 28110
SUBSURFACE LOG
Project Rose Ice & Coal Company
Address 102 Market Street, Wilmington, NC
Boring Number MW-1 Date Drilled
Sample Method Grab Drilling Method 6" Solid Stem
Completion DetailsWell installed at completion to a total depth of 15 feet with a 10 foot screened interval
Driller Matt Steele (GRI)Log By Kyle Perry
Lab Sample OVADepthSampleInterval(ft)ppm LITHOLOGY
0
2
Sample x
4
6
8
10

12
14
16

18
20
22

24
26
28

30
32
34

36
5' - 7'; Brown sandy clay (saturated)
7' - 9'; Gray sandy clay (saturated)
9' - 15'; Gray clayey fine sand (saturated)
06/29/22
0 - 0.5'; Concrete
0.5' - 2'; Tan/brown fine sand
2' - 5'; Tan/brown fine sand (moist)
Geological Resources, Inc.Phone:[phone]
3502 Hayes Road Fax:[phone]
Monroe, NC 28110
SUBSURFACE LOG
Project Rose Ice & Coal Company
Address 102 Market Street, Wilmington, NC
Boring Number MW-2 Date Drilled
Sample Method Grab Drilling Method 6" Solid Stem
Completion DetailsWell installed at completion to a total depth of 15 feet with a 10 foot screened interval
Driller Matt Steele (GRI)Log By Kyle Perry
Lab Sample OVADepthSampleInterval(ft)ppm LITHOLOGY
0
2
Sample x
4
6
8
10

12
14
16

18
20
22

24
26
28

30
32
34

36
06/29/22
0 - 0.5'; Topsoil
0.5' - 2'; Tan fine sand
2' - 4'; Brown/tan fine sand (moist)
4' - 9'; Gray sandy clay (saturated)
9' - 15'; Gray clayey fine sand (saturated)
Geological Resources, Inc.Phone:[phone]
3502 Hayes Road Fax:[phone]
Monroe, NC 28110
SUBSURFACE LOG
Project Rose Ice & Coal Company
Address 102 Market Street, Wilmington, NC
Boring Number MW-3 Date Drilled
Sample Method Grab Drilling Method 6" Solid Stem
Completion DetailsWell installed at completion to a total depth of 15 feet with a 10 foot screened interval
Driller Matt Steele (GRI)Log By Kyle Perry
Lab Sample OVADepthSampleInterval(ft)ppm LITHOLOGY
0
2
Sample x
4
6
8
10

12
14
16

18
20
22

24
26
28

30
32
34

36
06/29/22
0 - 0.5'; Topsoil
0.5' - 2'; Tan fine sand
2' - 5'; Brown/tan fine sand (moist)
5' - 9'; Gray sandy clay (saturated)
9' - 15'; Gray clayey fine sand (saturated)
Geological Resources, Inc.Phone:[phone]
3502 Hayes Road Fax:[phone]
Monroe, NC 28110
SUBSURFACE LOG
Project Rose Ice & Coal Company
Address 102 Market Street, Wilmington, NC
Boring Number MW-4 Date Drilled
Sample Method Grab Drilling Method 6" Solid Stem
Completion DetailsWell installed at completion to a total depth of 15 feet with a 10 foot screened interval
Driller Matt Steele (GRI)Log By Kyle Perry
Lab Sample OVADepthSampleInterval(ft)ppm LITHOLOGY
0
2
Sample x
4
6
8
10

12
14
16

18
20
22

24
26
28

30
32
34

36
06/29/22
0 - 0.5'; Topsoil
0.5' - 2'; Tan fine sand
2' - 5'; Tan/orange fine sand (moist)
5' - 8'; Gray sandy clay (saturated)
8' - 15'; Gray clayey fine sand (saturated)
WELL CONSTRUCTION RECORD
This form can be used for single or multiple wells
Form GW-1 North Carolina Department of Environment and Natural Resources – Division of Water 5HVRXUFHV Revised AXJXVW 2013
1. Well Contractor Information:

Well Contractor Name

NC Well Contractor Certification Number

Company Name 2. Well Construction Permit #: List all applicable well permits (i.e. County, State, Variance, ,QMHFWLRQetc.) 3. Well Use (check well use): Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared) □Irrigation
Non-Water Supply Well: □Monitoring □Recovery
Injection Well: □Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: ____________ Well ID#______________________ 5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)

Physical Address, City, and Zip
County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W
6. Is (are) the well(s): □Permanent or □Temporary

7. Is this a repair to an existing well: □Yes or □No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
8. Number of wells constructed: For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount:

14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS

22. Certification:
Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells ONLY: In addition to sending the form to the address in
24a above, also submit a copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells:
Also submit one copy of this form within 30 days of completion ofwell construction to the county health department of the county whereconstructed.
For Internal Use ONLY:
WELL CONSTRUCTION RECORD
This form can be used for single or multiple wells
Form GW-1 North Carolina Department of Environment and Natural Resources – Division of Water 5HVRXUFHV Revised AXJXVW 2013
1. Well Contractor Information:

Well Contractor Name

NC Well Contractor Certification Number

Company Name 2. Well Construction Permit #: List all applicable well permits (i.e. County, State, Variance, ,QMHFWLRQetc.) 3. Well Use (check well use): Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared) □Irrigation
Non-Water Supply Well: □Monitoring □Recovery
Injection Well: □Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: ____________ Well ID#______________________ 5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)

Physical Address, City, and Zip
County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W
6. Is (are) the well(s): □Permanent or □Temporary

7. Is this a repair to an existing well: □Yes or □No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
8. Number of wells constructed: For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount:

14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS

22. Certification:
Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells ONLY: In addition to sending the form to the address in
24a above, also submit a copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells:
Also submit one copy of this form within 30 days of completion ofwell construction to the county health department of the county whereconstructed.
For Internal Use ONLY:
WELL CONSTRUCTION RECORD
This form can be used for single or multiple wells
Form GW-1 North Carolina Department of Environment and Natural Resources – Division of Water 5HVRXUFHV Revised AXJXVW 2013
1. Well Contractor Information:

Well Contractor Name

NC Well Contractor Certification Number

Company Name 2. Well Construction Permit #: List all applicable well permits (i.e. County, State, Variance, ,QMHFWLRQetc.) 3. Well Use (check well use): Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared) □Irrigation
Non-Water Supply Well: □Monitoring □Recovery
Injection Well: □Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: ____________ Well ID#______________________ 5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)

Physical Address, City, and Zip
County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W
6. Is (are) the well(s): □Permanent or □Temporary

7. Is this a repair to an existing well: □Yes or □No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
8. Number of wells constructed: For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount:

14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS

22. Certification:
Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells ONLY: In addition to sending the form to the address in
24a above, also submit a copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells:
Also submit one copy of this form within 30 days of completion ofwell construction to the county health department of the county whereconstructed.
For Internal Use ONLY:
WELL CONSTRUCTION RECORD
This form can be used for single or multiple wells
Form GW-1 North Carolina Department of Environment and Natural Resources – Division of Water 5HVRXUFHV Revised AXJXVW 2013
1. Well Contractor Information:

Well Contractor Name

NC Well Contractor Certification Number

Company Name 2. Well Construction Permit #: List all applicable well permits (i.e. County, State, Variance, ,QMHFWLRQetc.) 3. Well Use (check well use): Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared) □Irrigation
Non-Water Supply Well: □Monitoring □Recovery
Injection Well: □Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: ____________ Well ID#______________________ 5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)

Physical Address, City, and Zip
County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W
6. Is (are) the well(s): □Permanent or □Temporary

7. Is this a repair to an existing well: □Yes or □No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
8. Number of wells constructed: For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount:

14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS

22. Certification:
Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells ONLY: In addition to sending the form to the address in
24a above, also submit a copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells:
Also submit one copy of this form within 30 days of completion ofwell construction to the county health department of the county whereconstructed.
For Internal Use ONLY:

APPENDIX C
NCDEQ Correspondence
NCDEQ Registered Tank Report
Facility Name ROSE ICE AND COAL CO.
Facility Id 00-0-0000021463
Address 1202 MARKET STREET
City WILMINGTON State NC
Zip 28401
Tank Owner ROSE ICE AND COAL CO
Address 1202 MARKET STREET
City WILMINGTON
State NC Zip 28401-4330
County New Hanover
Latitude 34.23645 Longitude -77.93374
Tank Information
Tank Id CapacityProduct Name Installation Date Perm Close Date Tank Construction Piping Construction Spill Protection Tank Status OverFill Protection
1 4000Gasoline, Gas Mix 4/6/1987 Single Wall Steel Other Catchment Basin CurrentAuto Shutoff Device
2 4000Gasoline, Gas Mix 4/6/1987 Single Wall Steel Other Catchment Basin CurrentAuto Shutoff Device
3 10000Gasoline, Gas Mix 4/6/1987 Single Wall Steel DW Flexible Piping Catchment Basin CurrentAuto Shutoff Device
4 10000Diesel 4/6/1987 Single Wall Steel DW Flexible Piping Catchment Basin CurrentAuto Shutoff Device
5 2000Kerosene, Kero
Mix
4/6/1987 Single Wall Steel DW Flexible Piping Catchment Basin CurrentAuto Shutoff Device
Thursday, July 28, 2022 Page 1 of 1

APPENDIX D
Laboratory Report – Soil

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

7/11/2022
Geological Resources, Inc. Scott Driscoll
113 W. Firetower Road, Suite G Winterville, NC, 28590
Ref: Analytical Testing
Lab Report Number: 22-182-0013 Client Project Description: Rose Ice & Coal Co.
GRI # 5716
Dear Scott Driscoll:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 7/1/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love Project Manager
Page 1 of 50
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202237735State ProgramNorth Carolina
12/31/2022402State ProgramNorth Carolina
07/31/202299012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Page 1 of 1 00016/22-182-0013
Page 2 of 50
Report Number:
Sample Summary Table
Client Project Description:
22-182-0013
Rose Ice & Coal Co.
GRI # 5716
Lab No Client Sample ID Matrix Date Collected Date Received
06/29/2022 14:25Solids 93366 MW-1-3'07/01/2022 09:15
06/29/2022 08:40Solids 93367 MW-2-3'07/01/2022 09:15
06/29/2022 10:05Solids 93368 MW-3-3'07/01/2022 09:15
06/29/2022 13:05Solids 93369 MW-4-3'07/01/2022 09:15
06/29/2022 08:00Aqueous 93370 TB 07/01/2022 09:15
Page 3 of 50
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-182-0013
Report Limit
Project:Rose Ice & Coal Co.
V 93366MW-1-3'
J0.014 07/07/2022 00:458260DAcetonemg/Kg - dry 0.002
J0.001 07/07/2022 00:458260DMethyl Ethyl Ketone (MEK)mg/Kg - dry 0.0007
11.8 07/06/2022 12:17SW-DRYWT Moisture %
V 93367MW-2-3'
21.6 07/06/2022 12:17SW-DRYWT Moisture %
V 93368MW-3-3'
25.7 07/06/2022 12:17SW-DRYWT Moisture %
V 93369MW-4-3'
21.3 07/06/2022 12:17SW-DRYWT Moisture %
Page 4 of 50

Client: Geological Resources, Inc. CASE NARRATIVE
Project: Rose Ice & Coal Co. Lab Report Number: 22-182-0013
Date: 7/11/2022
Volatile Organic Compounds - GC/MS Method 8260D Analyte: 4-Methyl-2-pentanone QC Batch No: V20967/V20966
CCV result above control limits but within method parameters. Results are reported but considered estimated.
Analyte: Methylene chloride QC Batch No: V20967/V20966
CCV result above control limits but within method parameters. Results are reported but considered estimated. Semivolatile Organic Compounds - GC/MS Method 8270E Analyte: Bis(2-chloroethyl)ether
QC Batch No: V21008/V20976 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.

Page 5 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0013
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI # 5716 Received : 07/01/2022
Rose Ice & Coal Co.
Report Date : 07/11/2022
Sample ID :
Lab No :
Sampled:MW-1-3'
93366 Matrix:
6/29/2022 14:25
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
11.8 %Moisture 1 07/06/22 12:17 SW-DRYWTADC
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 6 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0013
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI # 5716 Received : 07/01/2022
Rose Ice & Coal Co.
Report Date : 07/11/2022
Sample ID :
Lab No :
Sampled:MW-1-3'
93366 Matrix:
6/29/2022 14:25
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 LOW
8260D Prep Batch(es):V20966 07/06/22 08:00
0.014 J mg/Kg - dry 0.002 0.022Acetone 1 07/07/22 00:45 V20967TBL
<0.001 mg/Kg - dry 0.001 0.022Acrolein 1 07/07/22 00:45 V20967TBL
<0.0009 mg/Kg - dry 0.0009 0.022Acrylonitrile 1 07/07/22 00:45 V20967TBL
<0.0007 mg/Kg - dry 0.0007 0.005Benzene 1 07/07/22 00:45 V20967TBL
<0.0006 mg/Kg - dry 0.0006 0.005Bromobenzene 1 07/07/22 00:45 V20967TBL
<0.0009 mg/Kg - dry 0.0009 0.005Bromochloromethane 1 07/07/22 00:45 V20967TBL
<0.001 mg/Kg - dry 0.001 0.005Bromodichloromethane 1 07/07/22 00:45 V20967TBL
<0.001 mg/Kg - dry 0.001 0.005Bromoform 1 07/07/22 00:45 V20967TBL
<0.002 mg/Kg - dry 0.002 0.011
Bromomethane 1 07/07/22 00:45 V20967TBL
<0.0006 mg/Kg - dry 0.0006 0.005n-Butylbenzene 1 07/07/22 00:45 V20967TBL
<0.0006 mg/Kg - dry 0.0006 0.005sec-Butyl benzene 1 07/07/22 00:45 V20967TBL
<0.0006 mg/Kg - dry 0.0006 0.005tert-Butyl benzene 1 07/07/22 00:45 V20967TBL
<0.0007 mg/Kg - dry 0.0007 0.005Carbon Disulfide 1 07/07/22 00:45 V20967TBL
<0.001 mg/Kg - dry 0.001 0.005Carbon Tetrachloride 1 07/07/22 00:45 V20967TBL
<0.0008 mg/Kg - dry 0.0008 0.005Chlorobenzene 1 07/07/22 00:45 V20967TBL
<0.001 mg/Kg - dry 0.001 0.005
Chlorodibromomethane 1 07/07/22 00:45 V20967TBL
<0.001 mg/Kg - dry 0.001 0.011Chloroethane 1 07/07/22 00:45 V20967TBL
<0.001 mg/Kg - dry 0.001 0.005Chloroform 1 07/07/22 00:45 V20967TBL
<0.0007 mg/Kg - dry 0.0007 0.011Chloromethane 1 07/07/22 00:45 V20967TBL
<0.0006 mg/Kg - dry 0.0006 0.0052-Chlorotoluene 1 07/07/22 00:45 V20967TBL
<0.0004 mg/Kg - dry 0.0004 0.0054-Chlorotoluene 1 07/07/22 00:45 V20967TBL
<0.0008 mg/Kg - dry 0.0008 0.005Di-Isopropyl Ether (DIPE)1 07/07/22 00:45 V20967TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 7 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0013
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI # 5716 Received : 07/01/2022
Rose Ice & Coal Co.
Report Date : 07/11/2022
Sample ID :
Lab No :
Sampled:MW-1-3'
93366 Matrix:
6/29/2022 14:25
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 LOW
8260D Prep Batch(es):V20966 07/06/22 08:00
<0.0005 mg/Kg - dry 0.0005 0.0111,2-Dibromo-3-Chloropropane 1 07/07/22 00:45 V20967TBL
<0.0007 mg/Kg - dry 0.0007 0.0051,2-Dibromoethane 1 07/07/22 00:45 V20967TBL
<0.0006 mg/Kg - dry 0.0006 0.005Dibromomethane 1 07/07/22 00:45 V20967TBL
<0.0004 mg/Kg - dry 0.0004 0.0051,2-Dichlorobenzene 1 07/07/22 00:45 V20967TBL
<0.0004 mg/Kg - dry 0.0004 0.0051,3-Dichlorobenzene 1 07/07/22 00:45 V20967TBL
<0.0007 mg/Kg - dry 0.0007 0.0051,4-Dichlorobenzene 1 07/07/22 00:45 V20967TBL
<0.001 mg/Kg - dry 0.001 0.011Dichlorodifluoromethane 1 07/07/22 00:45 V20967TBL
<0.0009 mg/Kg - dry 0.0009 0.0051,1-Dichloroethane 1 07/07/22 00:45 V20967TBL
<0.001 mg/Kg - dry 0.001 0.005
1,2-Dichloroethane 1 07/07/22 00:45 V20967TBL
<0.0008 mg/Kg - dry 0.0008 0.0051,1-Dichloroethene 1 07/07/22 00:45 V20967TBL
<0.0009 mg/Kg - dry 0.0009 0.005cis-1,2-Dichloroethene 1 07/07/22 00:45 V20967TBL
<0.001 mg/Kg - dry 0.001 0.005trans-1,2-Dichloroethene 1 07/07/22 00:45 V20967TBL
<0.0005 mg/Kg - dry 0.0005 0.0051,2-Dichloropropane 1 07/07/22 00:45 V20967TBL
<0.0006 mg/Kg - dry 0.0006 0.0051,3-Dichloropropane 1 07/07/22 00:45 V20967TBL
<0.001 mg/Kg - dry 0.001 0.0052,2-Dichloropropane 1 07/07/22 00:45 V20967TBL
<0.0009 mg/Kg - dry 0.0009 0.005
1,1-Dichloropropene 1 07/07/22 00:45 V20967TBL
<0.0006 mg/Kg - dry 0.0006 0.005cis-1,3-Dichloropropene 1 07/07/22 00:45 V20967TBL
<0.0009 mg/Kg - dry 0.0009 0.005trans-1,3-Dichloropropene 1 07/07/22 00:45 V20967TBL
<0.0007 mg/Kg - dry 0.0007 0.005Ethylbenzene 1 07/07/22 00:45 V20967TBL
<0.0009 mg/Kg - dry 0.0009 0.056Ethyl Tertiary Butyl Ether (ETBE)1 07/07/22 00:45 V20967TBL
<0.0009 mg/Kg - dry 0.0009 0.011Hexachlorobutadiene 1 07/07/22 00:45 V20967TBL
<0.0007 mg/Kg - dry 0.0007 0.011n-Hexane 1 07/07/22 00:45 V20967TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 8 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0013
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI # 5716 Received : 07/01/2022
Rose Ice & Coal Co.
Report Date : 07/11/2022
Sample ID :
Lab No :
Sampled:MW-1-3'
93366 Matrix:
6/29/2022 14:25
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 LOW
8260D Prep Batch(es):V20966 07/06/22 08:00
<0.0007 mg/Kg - dry 0.0007 0.0222-Hexanone 1 07/07/22 00:45 V20967TBL
<0.0005 mg/Kg - dry 0.0005 0.005Isopropylbenzene 1 07/07/22 00:45 V20967TBL
<0.001 mg/Kg - dry 0.001 0.0054-Isopropyl toluene 1 07/07/22 00:45 V20967TBL
0.001 J mg/Kg - dry 0.0007 0.022Methyl Ethyl Ketone (MEK)1 07/07/22 00:45 V20967TBL
<0.0007 mg/Kg - dry 0.0007 0.005Methyl tert-butyl ether (MTBE)1 07/07/22 00:45 V20967TBL
<0.017 mg/Kg - dry 0.017 0.0224-Methyl-2-Pentanone 1 07/07/22 00:45 V20967TBL
<0.001 mg/Kg - dry 0.001 0.011Methylene Chloride 1 07/07/22 00:45 V20967TBL
<0.001 mg/Kg - dry 0.001 0.011Naphthalene 1 07/07/22 00:45 V20967TBL
<0.0006 mg/Kg - dry 0.0006 0.005
n-Propylbenzene 1 07/07/22 00:45 V20967TBL
<0.001 mg/Kg - dry 0.001 0.005Styrene 1 07/07/22 00:45 V20967TBL
<0.001 mg/Kg - dry 0.001 0.0051,1,1,2-Tetrachloroethane 1 07/07/22 00:45 V20967TBL
<0.0004 mg/Kg - dry 0.0004 0.0051,1,2,2-Tetrachloroethane 1 07/07/22 00:45 V20967TBL
<0.001 mg/Kg - dry 0.001 0.005Tetrachloroethene 1 07/07/22 00:45 V20967TBL
<0.0007 mg/Kg - dry 0.0007 0.005Toluene 1 07/07/22 00:45 V20967TBL
<0.0006 mg/Kg - dry 0.0006 0.0111,2,3-Trichlorobenzene 1 07/07/22 00:45 V20967TBL
<0.0007 mg/Kg - dry 0.0007 0.011
1,2,4-Trichlorobenzene 1 07/07/22 00:45 V20967TBL
<0.001 mg/Kg - dry 0.001 0.0051,1,1-Trichloroethane 1 07/07/22 00:45 V20967TBL
<0.0005 mg/Kg - dry 0.0005 0.0051,1,2-Trichloroethane 1 07/07/22 00:45 V20967TBL
<0.001 mg/Kg - dry 0.001 0.005Trichloroethene 1 07/07/22 00:45 V20967TBL
<0.002 mg/Kg - dry 0.002 0.011Trichlorofluoromethane 1 07/07/22 00:45 V20967TBL
<0.0008 mg/Kg - dry 0.0008 0.0051,2,3-Trichloropropane 1 07/07/22 00:45 V20967TBL
<0.0006 mg/Kg - dry 0.0006 0.0051,2,4-Trimethylbenzene 1 07/07/22 00:45 V20967TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 9 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0013
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI # 5716 Received : 07/01/2022
Rose Ice & Coal Co.
Report Date : 07/11/2022
Sample ID :
Lab No :
Sampled:MW-1-3'
93366 Matrix:
6/29/2022 14:25
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 LOW
8260D Prep Batch(es):V20966 07/06/22 08:00
<0.0006 mg/Kg - dry 0.0006 0.0051,3,5-Trimethylbenzene 1 07/07/22 00:45 V20967TBL
<0.0005 mg/Kg - dry 0.0005 0.011Vinyl Acetate 1 07/07/22 00:45 V20967TBL
<0.0005 mg/Kg - dry 0.0005 0.011Vinyl Chloride 1 07/07/22 00:45 V20967TBL
<0.0006 mg/Kg - dry 0.0006 0.005o-Xylene 1 07/07/22 00:45 V20967TBL
<0.001 mg/Kg - dry 0.001 0.011m,p-Xylene 1 07/07/22 00:45 V20967TBL
<0.0006 mg/Kg - dry 0.0006 0.005Xylene (Total)1 07/07/22 00:45 V20967
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%07/07/22 00:451 TBL V20967
Surrogate: Dibromofluoromethane 107 Limits: 84-123%07/07/22 00:451 TBL V20967
Surrogate: Toluene-d8 96.4 Limits: 76-129%07/07/22 00:451 TBL V20967
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V20976 07/07/22 10:00
<0.131 mg/Kg - dry 0.131 0.749Acenaphthene 1 07/07/22 17:27 V21008JMV
<0.119 mg/Kg - dry 0.119 0.749Acenaphthylene 1 07/07/22 17:27 V21008JMV
<0.172 mg/Kg - dry 0.172 0.749Aniline 1 07/07/22 17:27 V21008JMV
<0.162 mg/Kg - dry 0.162 0.749Anthracene 1 07/07/22 17:27 V21008JMV
<0.157 mg/Kg - dry 0.157 0.749Benzo(a)anthracene 1 07/07/22 17:27 V21008JMV
<0.166 mg/Kg - dry 0.166 0.749
Benzo(a)pyrene 1 07/07/22 17:27 V21008JMV
<0.165 mg/Kg - dry 0.165 0.749Benzo(b)fluoranthene 1 07/07/22 17:27 V21008JMV
<0.154 mg/Kg - dry 0.154 0.749Benzo(g,h,i)perylene 1 07/07/22 17:27 V21008JMV
<0.155 mg/Kg - dry 0.155 0.749Benzo(k)fluoranthene 1 07/07/22 17:27 V21008JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 10 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0013
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI # 5716 Received : 07/01/2022
Rose Ice & Coal Co.
Report Date : 07/11/2022
Sample ID :
Lab No :
Sampled:MW-1-3'
93366 Matrix:
6/29/2022 14:25
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V20976 07/07/22 10:00
<0.657 mg/Kg - dry 0.657 2.27Benzoic Acid 1 07/07/22 17:27 V21008JMV
<0.119 mg/Kg - dry 0.119 0.749Benzyl alcohol 1 07/07/22 17:27 V21008JMV
<0.133 mg/Kg - dry 0.133 0.749Bis(2-Chloroethoxy)methane 1 07/07/22 17:27 V21008JMV
<0.121 mg/Kg - dry 0.121 0.749Bis(2-Chloroethyl)ether 1 07/07/22 17:27 V21008JMV
<0.154 mg/Kg - dry 0.154 0.375Bis(2-Chloroisopropyl)ether 1 07/07/22 17:27 V21008JMV
<0.136 mg/Kg - dry 0.136 0.749Bis(2-ethylhexyl)phthalate 1 07/07/22 17:27 V21008JMV
<0.123 mg/Kg - dry 0.123 0.7494-Bromophenyl phenyl ether 1 07/07/22 17:27 V21008JMV
<0.128 mg/Kg - dry 0.128 0.375Butyl benzyl phthalate 1 07/07/22 17:27 V21008JMV
<0.104 mg/Kg - dry 0.104 0.749
4-Chloro-3-methylphenol 1 07/07/22 17:27 V21008JMV
<0.126 mg/Kg - dry 0.126 0.3754-Chloroaniline 1 07/07/22 17:27 V21008JMV
<0.131 mg/Kg - dry 0.131 0.7492-Chloronaphthalene 1 07/07/22 17:27 V21008JMV
<0.111 mg/Kg - dry 0.111 0.7492-Chlorophenol 1 07/07/22 17:27 V21008JMV
<0.142 mg/Kg - dry 0.142 1.134-Chlorophenyl phenyl ether 1 07/07/22 17:27 V21008JMV
<0.160 mg/Kg - dry 0.160 0.749Chrysene 1 07/07/22 17:27 V21008JMV
<0.260 mg/Kg - dry 0.260 0.749Dibenz(a,h)anthracene 1 07/07/22 17:27 V21008JMV
<0.134 mg/Kg - dry 0.134 0.749
Dibenzofuran 1 07/07/22 17:27 V21008JMV
<0.107 mg/Kg - dry 0.107 0.7491,2-Dichlorobenzene 1 07/07/22 17:27 V21008JMV
<0.110 mg/Kg - dry 0.110 0.7491,3-Dichlorobenzene 1 07/07/22 17:27 V21008JMV
<0.110 mg/Kg - dry 0.110 0.3751,4-Dichlorobenzene 1 07/07/22 17:27 V21008JMV
<0.166 mg/Kg - dry 0.166 0.7493,3'-Dichlorobenzidine 1 07/07/22 17:27 V21008JMV
<0.108 mg/Kg - dry 0.108 0.7492,4-Dichlorophenol 1 07/07/22 17:27 V21008JMV
<0.204 mg/Kg - dry 0.204 0.749Diethyl phthalate 1 07/07/22 17:27 V21008JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 11 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0013
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI # 5716 Received : 07/01/2022
Rose Ice & Coal Co.
Report Date : 07/11/2022
Sample ID :
Lab No :
Sampled:MW-1-3'
93366 Matrix:
6/29/2022 14:25
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V20976 07/07/22 10:00
<0.197 mg/Kg - dry 0.197 0.749Dimethyl phthalate 1 07/07/22 17:27 V21008JMV
<0.122 mg/Kg - dry 0.122 0.3752,4-Dimethylphenol 1 07/07/22 17:27 V21008JMV
<0.121 mg/Kg - dry 0.121 0.749Di-n-butyl phthalate 1 07/07/22 17:27 V21008JMV
<0.272 mg/Kg - dry 0.272 1.704,6-Dinitro-2-methylphenol 1 07/07/22 17:27 V21008JMV
<0.589 mg/Kg - dry 0.589 1.702,4-Dinitrophenol 1 07/07/22 17:27 V21008JMV
<0.109 mg/Kg - dry 0.109 0.7492,4-Dinitrotoluene 1 07/07/22 17:27 V21008JMV
<0.122 mg/Kg - dry 0.122 0.7492,6-Dinitrotoluene 1 07/07/22 17:27 V21008JMV
<0.162 mg/Kg - dry 0.162 0.375Di-n-Octyl Phthalate 1 07/07/22 17:27 V21008JMV
<0.139 mg/Kg - dry 0.139 0.749
Fluoranthene 1 07/07/22 17:27 V21008JMV
<0.145 mg/Kg - dry 0.145 0.749Fluorene 1 07/07/22 17:27 V21008JMV
<0.120 mg/Kg - dry 0.120 0.749Hexachlorobenzene 1 07/07/22 17:27 V21008JMV
<0.110 mg/Kg - dry 0.110 0.749Hexachlorobutadiene 1 07/07/22 17:27 V21008JMV
<0.178 mg/Kg - dry 0.178 0.749Hexachlorocyclopentadiene 1 07/07/22 17:27 V21008JMV
<0.089 mg/Kg - dry 0.089 0.749Hexachloroethane 1 07/07/22 17:27 V21008JMV
<0.202 mg/Kg - dry 0.202 0.749Indeno(1,2,3-cd)pyrene 1 07/07/22 17:27 V21008JMV
<0.216 mg/Kg - dry 0.216 0.749
Isophorone 1 07/07/22 17:27 V21008JMV
<0.120 mg/Kg - dry 0.120 0.7491-Methylnaphthalene 1 07/07/22 17:27 V21008JMV
<0.113 mg/Kg - dry 0.113 0.7492-Methylnaphthalene 1 07/07/22 17:27 V21008JMV
<0.110 mg/Kg - dry 0.110 0.7492-Methylphenol 1 07/07/22 17:27 V21008JMV
<0.096 mg/Kg - dry 0.096 0.7493&4 Methylphenol 1 07/07/22 17:27 V21008JMV
<0.163 mg/Kg - dry 0.163 0.749Naphthalene 1 07/07/22 17:27 V21008JMV
<0.109 mg/Kg - dry 0.109 0.7492-Nitroaniline 1 07/07/22 17:27 V21008JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 12 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0013
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI # 5716 Received : 07/01/2022
Rose Ice & Coal Co.
Report Date : 07/11/2022
Sample ID :
Lab No :
Sampled:MW-1-3'
93366 Matrix:
6/29/2022 14:25
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V20976 07/07/22 10:00
<0.136 mg/Kg - dry 0.136 0.7493-Nitroaniline 1 07/07/22 17:27 V21008JMV
<0.106 mg/Kg - dry 0.106 0.3754-Nitroaniline 1 07/07/22 17:27 V21008JMV
<0.131 mg/Kg - dry 0.131 0.375Nitrobenzene 1 07/07/22 17:27 V21008JMV
<0.100 mg/Kg - dry 0.100 0.7492-Nitrophenol 1 07/07/22 17:27 V21008JMV
<0.132 mg/Kg - dry 0.132 0.7494-Nitrophenol 1 07/07/22 17:27 V21008JMV
<0.298 mg/Kg - dry 0.298 0.749N-Nitrosodimethylamine 1 07/07/22 17:27 V21008JMV
<0.205 mg/Kg - dry 0.205 0.749N-Nitrosodiphenylamine 1 07/07/22 17:27 V21008JMV
<0.133 mg/Kg - dry 0.133 0.749N-Nitroso-di-n-propylamine 1 07/07/22 17:27 V21008JMV
<0.393 mg/Kg - dry 0.393 1.13
Pentachlorophenol 1 07/07/22 17:27 V21008JMV
<0.235 mg/Kg - dry 0.235 0.749Phenanthrene 1 07/07/22 17:27 V21008JMV
<0.126 mg/Kg - dry 0.126 0.749Phenol 1 07/07/22 17:27 V21008JMV
<0.151 mg/Kg - dry 0.151 0.749Pyrene 1 07/07/22 17:27 V21008JMV
<0.090 mg/Kg - dry 0.090 0.375Pyridine 1 07/07/22 17:27 V21008JMV
<0.121 mg/Kg - dry 0.121 0.7491,2,4-Trichlorobenzene 1 07/07/22 17:27 V21008JMV
<0.109 mg/Kg - dry 0.109 0.7492,4,5-Trichlorophenol 1 07/07/22 17:27 V21008JMV
<0.109 mg/Kg - dry 0.109 0.749
2,4,6-Trichlorophenol 1 07/07/22 17:27 V21008JMV
8270ESurrogate: Phenol-d5 80.5 Limits: 34-121%07/07/22 17:271 JMV
Surrogate: 2-Fluorobiphenyl 91.0 Limits: 44-115%07/07/22 17:271 JMV V21008
Surrogate: 2-Fluorophenol 82.3 Limits: 35-115%07/07/22 17:271 JMV V21008
Surrogate: Nitrobenzene-d5 74.9 Limits: 37-122%07/07/22 17:271 JMV V21008
Surrogate: 4-Terphenyl-d14 101 Limits: 54-127%07/07/22 17:271 JMV V21008
Surrogate: 2,4,6-Tribromophenol 97.6 Limits: 39-132%07/07/22 17:271 JMV V21008
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 13 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0013
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI # 5716 Received : 07/01/2022
Rose Ice & Coal Co.
Report Date : 07/11/2022
Sample ID :
Lab No :
Sampled:MW-1-3'
93366 Matrix:
6/29/2022 14:25
Solids
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<1.38 mg/Kg - dry 1.38 9.07Aliphatic C5-C8 (Adjusted)1 07/05/22 12:09
<5.17 mg/Kg - dry 5.17 9.07Aliphatics C9-C12 (Adjusted)1 07/05/22 12:09
<0.707 mg/Kg - dry 0.707 9.07Aromatic C9-C10 (Adjusted)100 07/05/22 12:09
<16.1 mg/Kg - dry 16.1 56.7Aromatic C11-C22 (Adjusted)1 07/07/22 00:45
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V20926 07/06/22 11:30
<10.4 mg/Kg - dry 10.4 56.7Aliphatic C9-C18 1 07/07/22 15:21 V21041JLK
<13.8 mg/Kg - dry 13.8 56.7Aliphatic C19-C36 1 07/07/22 15:21 V21041JLK
<16.1 mg/Kg - dry 16.1 56.7Aromatic C11-C22 1 07/07/22 15:21 V21041JLK
MADEP-EPHSurrogate: 2-Bromonaphthalene 81.0 Limits: 40-140%07/07/22 15:211 JLK
MADEP-EPHSurrogate: Chlorooctadecane 71.5 Limits: 40-140%07/07/22 15:211 JLK
MADEP-EPHSurrogate: OTP Surrogate 68.5 Limits: 40-140%07/07/22 15:211 JLK
Surrogate: 2-Fluorobiphenyl 80.8 Limits: 40-140%07/07/22 15:211 JLK V21041
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V20854 07/05/22 08:00
<1.38 mg/Kg - dry 1.38 9.07Aliphatic C5-C8 100 07/05/22 12:09 V20855TBL
<5.17 mg/Kg - dry 5.17 9.07Aliphatic C9-C12 100 07/05/22 12:09 V20855TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 14 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0013
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI # 5716 Received : 07/01/2022
Rose Ice & Coal Co.
Report Date : 07/11/2022
Sample ID :
Lab No :
Sampled:MW-1-3'
93366 Matrix:
6/29/2022 14:25
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V20854 07/05/22 08:00
<0.707 mg/Kg - dry 0.707 9.07Aromatic C9-C10 100 07/05/22 12:09 V20855TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)99.5 Limits: 70-130%07/05/22 12:09100 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)117 Limits: 70-130%07/05/22 12:09100 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 15 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0013
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI # 5716 Received : 07/01/2022
Rose Ice & Coal Co.
Report Date : 07/11/2022
Sample ID :
Lab No :
Sampled:MW-2-3'
93367 Matrix:
6/29/2022 8:40
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
21.6 %Moisture 1 07/06/22 12:17 SW-DRYWTADC
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 16 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0013
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI # 5716 Received : 07/01/2022
Rose Ice & Coal Co.
Report Date : 07/11/2022
Sample ID :
Lab No :
Sampled:MW-2-3'
93367 Matrix:
6/29/2022 8:40
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8015C DRO Prep Batch(es):V21030 07/08/22 09:30
<5.93 mg/Kg - dry 5.93 12.8Diesel Range Organics (C10-C28)1 07/08/22 16:22 V21087JLK
8015C DROSurrogate: OTP Surrogate 91.7 Limits: 31-123%07/08/22 16:221 JLK
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 MED
8015C GRO Prep Batch(es):V20830 07/05/22 08:00
<2.64 mg/Kg - dry 2.64 6.38Gasoline Range Organics (C6-C10)50 07/06/22 07:06 V20831TBL
8015C GROSurrogate: a,a,a-Trifluorotoluene 74.1 Limits: 50-137%07/06/22 07:0650 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 17 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0013
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI # 5716 Received : 07/01/2022
Rose Ice & Coal Co.
Report Date : 07/11/2022
Sample ID :
Lab No :
Sampled:MW-3-3'
93368 Matrix:
6/29/2022 10:05
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
25.7 %Moisture 1 07/06/22 12:17 SW-DRYWTADC
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 18 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0013
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI # 5716 Received : 07/01/2022
Rose Ice & Coal Co.
Report Date : 07/11/2022
Sample ID :
Lab No :
Sampled:MW-3-3'
93368 Matrix:
6/29/2022 10:05
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8015C DRO Prep Batch(es):V21030 07/08/22 09:30
<6.26 mg/Kg - dry 6.26 13.5Diesel Range Organics (C10-C28)1 07/08/22 17:26 V21087JLK
8015C DROSurrogate: OTP Surrogate 88.7 Limits: 31-123%07/08/22 17:261 JLK
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 MED
8015C GRO Prep Batch(es):V20830 07/05/22 08:00
<2.79 mg/Kg - dry 2.79 6.73Gasoline Range Organics (C6-C10)50 07/06/22 07:34 V20831TBL
8015C GROSurrogate: a,a,a-Trifluorotoluene 108 Limits: 50-137%07/06/22 07:3450 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 19 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0013
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI # 5716 Received : 07/01/2022
Rose Ice & Coal Co.
Report Date : 07/11/2022
Sample ID :
Lab No :
Sampled:MW-4-3'
93369 Matrix:
6/29/2022 13:05
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
21.3 %Moisture 1 07/06/22 12:17 SW-DRYWTADC
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 20 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0013
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI # 5716 Received : 07/01/2022
Rose Ice & Coal Co.
Report Date : 07/11/2022
Sample ID :
Lab No :
Sampled:MW-4-3'
93369 Matrix:
6/29/2022 13:05
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8015C DRO Prep Batch(es):V21030 07/08/22 09:30
<5.91 mg/Kg - dry 5.91 12.7Diesel Range Organics (C10-C28)1 07/08/22 17:47 V21087JLK
8015C DROSurrogate: OTP Surrogate 93.3 Limits: 31-123%07/08/22 17:471 JLK
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 MED
8015C GRO Prep Batch(es):V20830 07/05/22 08:00
<2.63 mg/Kg - dry 2.63 6.35Gasoline Range Organics (C6-C10)50 07/06/22 08:02 V20831TBL
8015C GROSurrogate: a,a,a-Trifluorotoluene 111 Limits: 50-137%07/06/22 08:0250 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 21 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0013
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI # 5716 Received : 07/01/2022
Rose Ice & Coal Co.
Report Date : 07/11/2022
Sample ID :
Lab No :
Sampled:TB
93370 Matrix:
6/29/2022 8:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V20963 07/06/22 09:00
<1.80 µg/L 1.80 10.0Acetone 1 07/06/22 13:33 V20964JLB
<0.180 µg/L 0.180 0.500Benzene 1 07/06/22 13:33 V20964JLB
<0.210 µg/L 0.210 0.500Bromobenzene 1 07/06/22 13:33 V20964JLB
<0.420 µg/L 0.420 1.00Bromochloromethane 1 07/06/22 13:33 V20964JLB
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 07/06/22 13:33 V20964JLB
<1.50 µg/L 1.50 5.00Bromoform 1 07/06/22 13:33 V20964JLB
<0.280 µg/L 0.280 1.00Bromomethane 1 07/06/22 13:33 V20964JLB
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 07/06/22 13:33 V20964JLB
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 07/06/22 13:33 V20964JLB
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 07/06/22 13:33 V20964JLB
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 07/06/22 13:33 V20964JLB
<0.190 µg/L 0.190 0.500Chlorobenzene 1 07/06/22 13:33 V20964JLB
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 07/06/22 13:33 V20964JLB
<0.430 µg/L 0.430 1.00Chloroethane 1 07/06/22 13:33 V20964JLB
<0.220 µg/L 0.220 0.500Chloroform 1 07/06/22 13:33 V20964JLB
<0.220 µg/L 0.220 0.500
Chloromethane 1 07/06/22 13:33 V20964JLB
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 07/06/22 13:33 V20964JLB
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 07/06/22 13:33 V20964JLB
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 07/06/22 13:33 V20964JLB
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 07/06/22 13:33 V20964JLB
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 07/06/22 13:33 V20964JLB
<0.230 µg/L 0.230 0.500Dibromomethane 1 07/06/22 13:33 V20964JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 22 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0013
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI # 5716 Received : 07/01/2022
Rose Ice & Coal Co.
Report Date : 07/11/2022
Sample ID :
Lab No :
Sampled:TB
93370 Matrix:
6/29/2022 8:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V20963 07/06/22 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 07/06/22 13:33 V20964JLB
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 07/06/22 13:33 V20964JLB
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 07/06/22 13:33 V20964JLB
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 07/06/22 13:33 V20964JLB
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 07/06/22 13:33 V20964JLB
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 07/06/22 13:33 V20964JLB
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 07/06/22 13:33 V20964JLB
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 07/06/22 13:33 V20964JLB
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 07/06/22 13:33 V20964JLB
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 07/06/22 13:33 V20964JLB
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 07/06/22 13:33 V20964JLB
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 07/06/22 13:33 V20964JLB
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 07/06/22 13:33 V20964JLB
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 07/06/22 13:33 V20964JLB
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 07/06/22 13:33 V20964JLB
<42.0 µg/L 42.0 200
Ethanol 1 07/06/22 13:33 V20964JLB
<0.170 µg/L 0.170 0.500Ethylbenzene 1 07/06/22 13:33 V20964JLB
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 07/06/22 13:33 V20964JLB
<0.380 µg/L 0.380 1.002-Hexanone 1 07/06/22 13:33 V20964JLB
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 07/06/22 13:33 V20964JLB
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 07/06/22 13:33 V20964JLB
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 07/06/22 13:33 V20964JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 23 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0013
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI # 5716 Received : 07/01/2022
Rose Ice & Coal Co.
Report Date : 07/11/2022
Sample ID :
Lab No :
Sampled:TB
93370 Matrix:
6/29/2022 8:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V20963 07/06/22 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 07/06/22 13:33 V20964JLB
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 07/06/22 13:33 V20964JLB
<0.330 µg/L 0.330 2.00Methylene Chloride 1 07/06/22 13:33 V20964JLB
<0.470 µg/L 0.470 1.00Naphthalene 1 07/06/22 13:33 V20964JLB
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 07/06/22 13:33 V20964JLB
<0.220 µg/L 0.220 0.500Styrene 1 07/06/22 13:33 V20964JLB
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 07/06/22 13:33 V20964JLB
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 07/06/22 13:33 V20964JLB
<0.220 µg/L 0.220 0.500
Tetrachloroethene 1 07/06/22 13:33 V20964JLB
<0.220 µg/L 0.220 0.500Toluene 1 07/06/22 13:33 V20964JLB
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 07/06/22 13:33 V20964JLB
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 07/06/22 13:33 V20964JLB
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 07/06/22 13:33 V20964JLB
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 07/06/22 13:33 V20964JLB
<0.180 µg/L 0.180 0.500Trichloroethene 1 07/06/22 13:33 V20964JLB
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 07/06/22 13:33 V20964JLB
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 07/06/22 13:33 V20964JLB
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 07/06/22 13:33 V20964JLB
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 07/06/22 13:33 V20964JLB
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 07/06/22 13:33 V20964JLB
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 07/06/22 13:33 V20964JLB
<0.210 µg/L 0.210 0.500o-Xylene 1 07/06/22 13:33 V20964JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 24 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0013
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI # 5716 Received : 07/01/2022
Rose Ice & Coal Co.
Report Date : 07/11/2022
Sample ID :
Lab No :
Sampled:TB
93370 Matrix:
6/29/2022 8:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V20963 07/06/22 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 07/06/22 13:33 V20964JLB
<0.21 µg/L 0.210 0.500Xylene (Total)1 07/06/22 13:33 V20964
Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%07/06/22 13:331 JLB V20964
Surrogate: Dibromofluoromethane 95.4 Limits: 70-130%07/06/22 13:331 JLB V20964
Surrogate: 1,2-Dichloroethane - d4 102 Limits: 70-130%07/06/22 13:331 JLB V20964
Surrogate: Toluene-d8 107 Limits: 70-130%07/06/22 13:331 JLB V20964
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 25 of 50
Quality Control Data
22-182-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Ice & Coal Co.
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V20964QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V20963
Associated Lab Samples: 93370
LRB-V20963 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/06/22 12:3910.01.80<1.80µg/LAcetone
07/06/22 12:390.5000.180<0.180µg/LBenzene
07/06/22 12:390.5000.210<0.210µg/LBromobenzene
07/06/22 12:391.000.420<0.420µg/LBromochloromethane
07/06/22 12:390.5000.160<0.160µg/LBromodichloromethane
07/06/22 12:395.001.50<1.50µg/LBromoform
07/06/22 12:391.000.280<0.280µg/LBromomethane
07/06/22 12:390.5000.180<0.180µg/Ln-Butylbenzene
07/06/22 12:390.5000.200<0.200µg/Lsec-Butyl benzene
07/06/22 12:392.000.920<0.920µg/Ltert-Butyl benzene
07/06/22 12:390.5000.180<0.180µg/LCarbon Tetrachloride
07/06/22 12:390.5000.190<0.190µg/LChlorobenzene
07/06/22 12:390.5000.190<0.190µg/LChlorodibromomethane
07/06/22 12:391.000.430<0.430µg/LChloroethane
07/06/22 12:390.5000.220<0.220µg/LChloroform
07/06/22 12:390.5000.220<0.220µg/LChloromethane
07/06/22 12:390.5000.200<0.200µg/L2-Chlorotoluene
07/06/22 12:390.5000.200<0.200µg/L4-Chlorotoluene
07/06/22 12:390.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
07/06/22 12:392.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
07/06/22 12:390.5000.200<0.200µg/L1,2-Dibromoethane
07/06/22 12:390.5000.230<0.230µg/LDibromomethane
07/06/22 12:390.5000.220<0.220µg/L1,2-Dichlorobenzene
07/06/22 12:390.5000.190<0.190µg/L1,3-Dichlorobenzene
07/06/22 12:390.5000.210<0.210µg/L1,4-Dichlorobenzene
07/06/22 12:395.001.20<1.20µg/LDichlorodifluoromethane
07/06/22 12:390.5000.240<0.240µg/L1,1-Dichloroethane
Page 1 of 23Date:07/11/2022 06:30 PM
Page 26 of 50
Quality Control Data
22-182-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Ice & Coal Co.
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V20964QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V20963
Associated Lab Samples: 93370
LRB-V20963 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/06/22 12:390.5000.150<0.150µg/L1,2-Dichloroethane
07/06/22 12:390.5000.150<0.150µg/L1,1-Dichloroethene
07/06/22 12:390.5000.200<0.200µg/Lcis-1,2-Dichloroethene
07/06/22 12:390.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
07/06/22 12:390.5000.190<0.190µg/L1,2-Dichloropropane
07/06/22 12:390.5000.130<0.130µg/L1,3-Dichloropropane
07/06/22 12:392.000.210<0.210µg/L2,2-Dichloropropane
07/06/22 12:390.5000.200<0.200µg/L1,1-Dichloropropene
07/06/22 12:390.5000.210<0.210µg/Lcis-1,3-Dichloropropene
07/06/22 12:390.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
07/06/22 12:3920042.0<42.0µg/LEthanol
07/06/22 12:390.5000.170<0.170µg/LEthylbenzene
07/06/22 12:393.000.350<0.350µg/LHexachlorobutadiene
07/06/22 12:391.000.380<0.380µg/L2-Hexanone
07/06/22 12:390.5000.180<0.180µg/LIsopropylbenzene
07/06/22 12:390.5000.089<0.089µg/L4-Isopropyl toluene
07/06/22 12:395.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
07/06/22 12:391.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
07/06/22 12:391.000.078<0.078µg/L4-Methyl-2-Pentanone
07/06/22 12:392.000.330<0.330µg/LMethylene Chloride
07/06/22 12:391.000.470<0.470µg/LNaphthalene
07/06/22 12:390.5000.190<0.190µg/Ln-Propylbenzene
07/06/22 12:390.5000.220<0.220µg/LStyrene
07/06/22 12:390.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
07/06/22 12:390.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
07/06/22 12:390.5000.220<0.220µg/LTetrachloroethene
07/06/22 12:390.5000.220<0.220µg/LToluene
Page 2 of 23Date:07/11/2022 06:30 PM
Page 27 of 50
Quality Control Data
22-182-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Ice & Coal Co.
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V20964QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V20963
Associated Lab Samples: 93370
LRB-V20963 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/06/22 12:390.5000.380<0.380µg/L1,2,3-Trichlorobenzene
07/06/22 12:390.5000.310<0.310µg/L1,2,4-Trichlorobenzene
07/06/22 12:390.5000.160<0.160µg/L1,1,1-Trichloroethane
07/06/22 12:390.5000.096<0.096µg/L1,1,2-Trichloroethane
07/06/22 12:390.5000.180<0.180µg/LTrichloroethene
07/06/22 12:390.5000.180<0.180µg/LTrichlorofluoromethane
07/06/22 12:390.5000.270<0.270µg/L1,2,3-Trichloropropane
07/06/22 12:390.5000.190<0.190µg/L1,2,4-Trimethylbenzene
07/06/22 12:390.5000.180<0.180µg/L1,3,5-Trimethylbenzene
07/06/22 12:395.001.00<1.00µg/LVinyl Acetate
07/06/22 12:390.5000.170<0.170µg/LVinyl Chloride
07/06/22 12:390.5000.210<0.210µg/Lo-Xylene
07/06/22 12:391.000.420<0.420µg/Lm,p-Xylene
07/06/22 12:394-Bromofluorobenzene (S)99.2 70-130
07/06/22 12:39Dibromofluoromethane (S)95.4 70-130
07/06/22 12:391,2-Dichloroethane - d4 (S)104 70-130
07/06/22 12:39Toluene-d8 (S)106 70-130
LCS-V20963 LCSD-V20963Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
33.9 84.781.232.540.0µg/LAcetone 40-160 4.2 20.0
18.8 94.096.519.320.0µg/LBenzene 70-130 2.6 20.0
21.2 10610521.020.0µg/LBromobenzene 70-130 0.9 20.0
19.0 95.089.017.820.0µg/LBromochloromethane 70-130 6.5 20.0
19.4 97.094.018.820.0µg/LBromodichloromethane 70-130 3.1 20.0
Page 3 of 23Date:07/11/2022 06:30 PM
Page 28 of 50
Quality Control Data
22-182-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Ice & Coal Co.
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V20964QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V20963
LCS-V20963 LCSD-V20963Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
23.7 11912124.120.0µg/LBromoform 70-130 1.6 20.0
21.0 10510120.120.0µg/LBromomethane 60-140 4.3 20.0
22.5 11311623.120.0µg/Ln-Butylbenzene 70-130 2.6 20.0
22.7 11411422.820.0µg/Lsec-Butyl benzene 70-130 0.4 20.0
22.5 11311422.820.0µg/Ltert-Butyl benzene 70-130 1.3 20.0
21.1 10698.019.620.0µg/LCarbon Tetrachloride 70-130 7.3 20.0
21.2 10610921.720.0µg/LChlorobenzene 70-130 2.3 20.0
20.1 10110320.520.0µg/LChlorodibromomethane 70-130 1.9 20.0
20.4 10210320.520.0µg/LChloroethane 60-140 0.4 20.0
18.8 94.096.519.320.0µg/LChloroform 70-130 2.6 20.0
15.3 76.580.516.120.0µg/LChloromethane 60-140 5.0 20.0
22.2 11111222.320.0µg/L2-Chlorotoluene 70-130 0.4 20.0
22.1 11111322.520.0µg/L4-Chlorotoluene 70-130 1.7 20.0
18.6 93.094.018.820.0µg/LDi-Isopropyl Ether (DIPE)70-130 1.0 20.0
20.3 10289.017.820.0µg/L1,2-Dibromo-3-Chloropropane 70-130 13.1 20.0
19.1 95.596.519.320.0µg/L1,2-Dibromoethane 70-130 1.0 20.0
17.2 86.087.517.520.0µg/LDibromomethane 70-130 1.7 20.0
22.3 11211222.320.0µg/L1,2-Dichlorobenzene 70-130 0.0 20.0
23.1 11611422.820.0µg/L1,3-Dichlorobenzene 70-130 1.3 20.0
22.9 11511322.620.0µg/L1,4-Dichlorobenzene 70-130 1.3 20.0
23.7 11912224.420.0µg/LDichlorodifluoromethane 60-140 2.9 20.0
19.0 95.098.019.620.0µg/L1,1-Dichloroethane 70-130 3.1 20.0
17.7 88.591.018.220.0µg/L1,2-Dichloroethane 70-130 2.7 20.0
19.8 99.098.519.720.0µg/L1,1-Dichloroethene 70-130 0.5 20.0
18.8 94.092.018.420.0µg/Lcis-1,2-Dichloroethene 70-130 2.1 20.0
18.0 90.091.518.320.0µg/Ltrans-1,2-Dichloroethene 70-130 1.6 20.0
Page 4 of 23Date:07/11/2022 06:30 PM
Page 29 of 50
Quality Control Data
22-182-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Ice & Coal Co.
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V20964QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V20963
LCS-V20963 LCSD-V20963Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
19.1 95.595.519.120.0µg/L1,2-Dichloropropane 70-130 0.0 20.0
20.9 10510320.520.0µg/L1,3-Dichloropropane 70-130 1.9 20.0
19.1 95.595.519.120.0µg/L2,2-Dichloropropane 70-130 0.0 20.0
19.1 95.594.018.820.0µg/L1,1-Dichloropropene 70-130 1.5 20.0
19.2 96.095.519.120.0µg/Lcis-1,3-Dichloropropene 70-130 0.5 20.0
19.2 96.095.519.120.0µg/Ltrans-1,3-Dichloropropene 70-130 0.5 20.0
470 94.094.0470500µg/LEthanol 60-140 0.0 20.0
20.7 10410320.620.0µg/LEthylbenzene 70-130 0.4 20.0
19.9 99.510220.320.0µg/LHexachlorobutadiene 70-130 1.9 20.0
20.0 10091.018.220.0µg/L2-Hexanone 60-140 9.4 20.0
22.3 11211122.220.0µg/LIsopropylbenzene 70-130 0.4 20.0
23.2 11611823.620.0µg/L4-Isopropyl toluene 70-130 1.7 20.0
18.7 93.590.018.020.0µg/LMethyl Ethyl Ketone (MEK)60-140 3.8 20.0
18.8 94.094.518.920.0µg/LMethyl tert-butyl ether (MTBE)70-130 0.5 20.0
18.1 90.589.517.920.0µg/L4-Methyl-2-Pentanone 60-140 1.1 20.0
18.3 91.593.518.720.0µg/LMethylene Chloride 70-130 2.1 20.0
18.8 94.092.518.520.0µg/LNaphthalene 70-130 1.6 20.0
22.4 11211522.920.0µg/Ln-Propylbenzene 70-130 2.2 20.0
21.0 10510621.120.0µg/LStyrene 70-130 0.4 20.0
20.1 10110020.020.0µg/L1,1,1,2-Tetrachloroethane 70-130 0.4 20.0
21.8 10911122.120.0µg/L1,1,2,2-Tetrachloroethane 70-130 1.3 20.0
18.9 94.596.519.320.0µg/LTetrachloroethene 70-130 2.0 20.0
19.0 95.096.519.320.0µg/LToluene 70-130 1.5 20.0
21.8 10910721.420.0µg/L1,2,3-Trichlorobenzene 70-130 1.8 20.0
21.2 10610821.520.0µg/L1,2,4-Trichlorobenzene 70-130 1.4 20.0
18.7 93.593.018.620.0µg/L1,1,1-Trichloroethane 70-130 0.5 20.0
Page 5 of 23Date:07/11/2022 06:30 PM
Page 30 of 50
Quality Control Data
22-182-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Ice & Coal Co.
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V20964QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V20963
LCS-V20963 LCSD-V20963Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
18.0 90.092.518.520.0µg/L1,1,2-Trichloroethane 70-130 2.7 20.0
18.5 92.595.519.120.0µg/LTrichloroethene 70-130 3.1 20.0
25.0 12512525.020.0µg/LTrichlorofluoromethane 60-140 0.0 20.0
22.6 11311322.620.0µg/L1,2,3-Trichloropropane 70-130 0.0 20.0
22.3 11211522.920.0µg/L1,2,4-Trimethylbenzene 70-130 2.6 20.0
22.3 11211122.220.0µg/L1,3,5-Trimethylbenzene 70-130 0.4 20.0
20.4 10210120.120.0µg/LVinyl Acetate 60-140 1.4 20.0
20.6 10310721.420.0µg/LVinyl Chloride 60-140 3.8 20.0
20.8 10410220.420.0µg/Lo-Xylene 70-130 1.9 20.0
42.7 10710843.040.0µg/Lm,p-Xylene 70-130 0.7 20.0
1021024-Bromofluorobenzene (S)70-130
105105Dibromofluoromethane (S)70-130
1031041,2-Dichloroethane - d4 (S)70-130
107107Toluene-d8 (S)70-130
Page 6 of 23Date:07/11/2022 06:30 PM
Page 31 of 50
Quality Control Data
22-182-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Ice & Coal Co.
QC Prep Batch Method:
Total Petroleum Hydrocarbons - Extractable
8015C DRO
V21087QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V21030
Associated Lab Samples: 93367, 93368, 93369
LRB-V21030 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/08/22 15:3910.04.65<4.65mg/KgDiesel Range Organics (C10-C28)
07/08/22 15:39OTP Surrogate (S)96.9 31-123
LCS-V21030Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
94.463.066.7mg/KgDiesel Range Organics (C10-C28)46-126
91.7OTP Surrogate (S)31-123
V 93367-MS-V21030 V 93367-MSD-V21030Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
68.3 10366.466.666.6<4.65mg/KgDiesel Range Organics (C10-C28)99.6 50-117 2.8 24
89.4OTP Surrogate (S)85.7 31-123
Page 7 of 23Date:07/11/2022 06:30 PM
Page 32 of 50
Quality Control Data
22-182-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Ice & Coal Co.
QC Prep Batch Method:
Total Petroleum Hydrocarbons - Volatile
8015C GRO
V20831QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 MED
QC Prep:V20830
Associated Lab Samples: 93367, 93368, 93369
LRB-V20830 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/05/22 12:555.002.07<2.07mg/KgGasoline Range Organics (C6-C10)
07/05/22 12:55a,a,a-Trifluorotoluene (S)119 50-137
LCS-V20830Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
12060.050.0mg/KgGasoline Range Organics (C6-C10)41-138
119a,a,a-Trifluorotoluene (S)50-137
V 93500-MS-V20830 V 93500-MSD-V20830Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
56.9 11447.750.050.0<2.07mg/KgGasoline Range Organics (C6-C10)95.4 41-138 17.5 34
120a,a,a-Trifluorotoluene (S)130 50-137
Page 8 of 23Date:07/11/2022 06:30 PM
Page 33 of 50
Quality Control Data
22-182-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Ice & Coal Co.
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V20967QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 LOW
QC Prep:V20966
Associated Lab Samples: 93366
LRB-V20966 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/07/22 00:170.0200.002<0.002mg/KgAcetone
07/07/22 00:170.0200.001<0.001mg/KgAcrolein
07/07/22 00:170.0200.0008<0.0008mg/KgAcrylonitrile
07/07/22 00:170.0050.0006<0.0006mg/KgBenzene
07/07/22 00:170.0050.0005<0.0005mg/KgBromobenzene
07/07/22 00:170.0050.0008<0.0008mg/KgBromochloromethane
07/07/22 00:170.0050.001<0.001mg/KgBromodichloromethane
07/07/22 00:170.0050.001<0.001mg/KgBromoform
07/07/22 00:170.0100.001<0.001mg/KgBromomethane
07/07/22 00:170.0050.0005<0.0005mg/Kgn-Butylbenzene
07/07/22 00:170.0050.0006<0.0006mg/Kgsec-Butyl benzene
07/07/22 00:170.0050.0005<0.0005mg/Kgtert-Butyl benzene
07/07/22 00:170.0050.0006<0.0006mg/KgCarbon Disulfide
07/07/22 00:170.0050.001<0.001mg/KgCarbon Tetrachloride
07/07/22 00:170.0050.0007<0.0007mg/KgChlorobenzene
07/07/22 00:170.0050.0009<0.0009mg/KgChlorodibromomethane
07/07/22 00:170.0100.0009<0.0009mg/KgChloroethane
07/07/22 00:170.0050.001<0.001mg/KgChloroform
07/07/22 00:170.0100.0006<0.0006mg/KgChloromethane
07/07/22 00:170.0050.0005<0.0005mg/Kg2-Chlorotoluene
07/07/22 00:170.0050.0004<0.0004mg/Kg4-Chlorotoluene
07/07/22 00:170.0050.0007<0.0007mg/KgDi-Isopropyl Ether (DIPE)
07/07/22 00:170.0100.0004<0.0004mg/Kg1,2-Dibromo-3-Chloropropane
07/07/22 00:170.0050.0006<0.0006mg/Kg1,2-Dibromoethane
07/07/22 00:170.0050.0006<0.0006mg/KgDibromomethane
07/07/22 00:170.0050.0003<0.0003mg/Kg1,2-Dichlorobenzene
07/07/22 00:170.0050.0004<0.0004mg/Kg1,3-Dichlorobenzene
Page 9 of 23Date:07/11/2022 06:30 PM
Page 34 of 50
Quality Control Data
22-182-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Ice & Coal Co.
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V20967QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 LOW
QC Prep:V20966
Associated Lab Samples: 93366
LRB-V20966 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/07/22 00:170.0050.0006<0.0006mg/Kg1,4-Dichlorobenzene
07/07/22 00:170.0100.001<0.001mg/KgDichlorodifluoromethane
07/07/22 00:170.0050.0008<0.0008mg/Kg1,1-Dichloroethane
07/07/22 00:170.0050.001<0.001mg/Kg1,2-Dichloroethane
07/07/22 00:170.0050.0007<0.0007mg/Kg1,1-Dichloroethene
07/07/22 00:170.0050.0008<0.0008mg/Kgcis-1,2-Dichloroethene
07/07/22 00:170.0050.001<0.001mg/Kgtrans-1,2-Dichloroethene
07/07/22 00:170.0050.0004<0.0004mg/Kg1,2-Dichloropropane
07/07/22 00:170.0050.0006<0.0006mg/Kg1,3-Dichloropropane
07/07/22 00:170.0050.001<0.001mg/Kg2,2-Dichloropropane
07/07/22 00:170.0050.0008<0.0008mg/Kg1,1-Dichloropropene
07/07/22 00:170.0050.0005<0.0005mg/Kgcis-1,3-Dichloropropene
07/07/22 00:170.0050.0008<0.0008mg/Kgtrans-1,3-Dichloropropene
07/07/22 00:170.0050.0006<0.0006mg/KgEthylbenzene
07/07/22 00:170.0500.0008<0.0008mg/KgEthyl Tertiary Butyl Ether (ETBE)
07/07/22 00:170.0100.0008<0.0008mg/KgHexachlorobutadiene
07/07/22 00:170.0100.0007<0.0007mg/Kgn-Hexane
07/07/22 00:170.0200.0006<0.0006mg/Kg2-Hexanone
07/07/22 00:170.0050.0005<0.0005mg/KgIsopropylbenzene
07/07/22 00:170.0050.001<0.001mg/Kg4-Isopropyl toluene
07/07/22 00:170.0200.0007<0.0007mg/KgMethyl Ethyl Ketone (MEK)
07/07/22 00:170.0050.0006<0.0006mg/KgMethyl tert-butyl ether (MTBE)
07/07/22 00:170.0200.015<0.015mg/Kg4-Methyl-2-Pentanone
07/07/22 00:170.0100.0010.002mg/KgMethylene Chloride
07/07/22 00:170.0100.0010<0.0010mg/KgNaphthalene
07/07/22 00:170.0050.0005<0.0005mg/Kgn-Propylbenzene
07/07/22 00:170.0050.001<0.001mg/KgStyrene
Page 10 of 23Date:07/11/2022 06:30 PM
Page 35 of 50
Quality Control Data
22-182-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Ice & Coal Co.
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V20967QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 LOW
QC Prep:V20966
Associated Lab Samples: 93366
LRB-V20966 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/07/22 00:170.0050.001<0.001mg/Kg1,1,1,2-Tetrachloroethane
07/07/22 00:170.0050.0003<0.0003mg/Kg1,1,2,2-Tetrachloroethane
07/07/22 00:170.0050.0009<0.0009mg/KgTetrachloroethene
07/07/22 00:170.0050.0007<0.0007mg/KgToluene
07/07/22 00:170.0100.0005<0.0005mg/Kg1,2,3-Trichlorobenzene
07/07/22 00:170.0100.0006<0.0006mg/Kg1,2,4-Trichlorobenzene
07/07/22 00:170.0050.001<0.001mg/Kg1,1,1-Trichloroethane
07/07/22 00:170.0050.0005<0.0005mg/Kg1,1,2-Trichloroethane
07/07/22 00:170.0050.0009<0.0009mg/KgTrichloroethene
07/07/22 00:170.0100.002<0.002mg/KgTrichlorofluoromethane
07/07/22 00:170.0050.0007<0.0007mg/Kg1,2,3-Trichloropropane
07/07/22 00:170.0050.0005<0.0005mg/Kg1,2,4-Trimethylbenzene
07/07/22 00:170.0050.0005<0.0005mg/Kg1,3,5-Trimethylbenzene
07/07/22 00:170.0100.0005<0.0005mg/KgVinyl Acetate
07/07/22 00:170.0100.0005<0.0005mg/KgVinyl Chloride
07/07/22 00:170.0050.0005<0.0005mg/Kgo-Xylene
07/07/22 00:170.0100.001<0.001mg/Kgm,p-Xylene
07/07/22 00:174-Bromofluorobenzene (S)102 70-130
07/07/22 00:17Dibromofluoromethane (S)106 84-123
07/07/22 00:17Toluene-d8 (S)98.8 76-129
LCS-V20966 LCSD-V20966Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.108 1081030.1030.100mg/KgAcetone 29-198 4.7 20
0.098 98.098.30.0980.100mg/KgAcrolein 70-130 0.3 20
Page 11 of 23Date:07/11/2022 06:30 PM
Page 36 of 50
Quality Control Data
22-182-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Ice & Coal Co.
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V20967QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 LOW
QC Prep:V20966
LCS-V20966 LCSD-V20966Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.127 1271230.1230.100mg/KgAcrylonitrile 65-134 3.2 20
0.057 1151150.0570.050mg/KgBenzene 74-127 0.3 20
0.053 1061050.0520.050mg/KgBromobenzene 73-125 1.3 20
0.060 1221200.0590.050mg/KgBromochloromethane 72-134 1.6 20
0.059 1181170.0580.050mg/KgBromodichloromethane 75-122 1.5 20
0.053 1071010.0500.050mg/KgBromoform 66-135 5.3 20
0.056 1141200.0590.050mg/KgBromomethane 20-180 4.9 20
0.050 1001000.0500.050mg/Kgn-Butylbenzene 65-135 0.0 20
0.050 1011010.0500.050mg/Kgsec-Butyl benzene 66-131 0.1 20
0.050 1001030.0510.050mg/Kgtert-Butyl benzene 67-132 3.1 20
0.056 1121110.0550.050mg/KgCarbon Disulfide 61-129 0.8 20
0.056 1131150.0570.050mg/KgCarbon Tetrachloride 64-143 1.7 20
0.053 1081060.0530.050mg/KgChlorobenzene 74-118 1.6 20
0.052 1051050.0520.050mg/KgChlorodibromomethane 73-122 0.3 20
0.060 1201200.0600.050mg/KgChloroethane 33-149 0.1 20
0.058 1171170.0580.050mg/KgChloroform 73-127 0.1 20
0.063 1261300.0640.050mg/KgChloromethane 45-143 2.6 20
0.052 1041050.0520.050mg/Kg2-Chlorotoluene 67-124 0.7 20
0.052 1041050.0520.050mg/Kg4-Chlorotoluene 71-126 0.5 20
0.070 1401380.0690.050mg/KgDi-Isopropyl Ether (DIPE)59-159 1.4 20
0.049 98.493.20.0460.050mg/Kg1,2-Dibromo-3-Chloropropane 55-157 5.4 20
0.052 1061040.0510.050mg/Kg1,2-Dibromoethane 70-132 1.9 20
0.059 1191170.0580.050mg/KgDibromomethane 74-133 1.6 20
0.052 1061040.0510.050mg/Kg1,2-Dichlorobenzene 72-123 1.7 20
0.051 1041030.0510.050mg/Kg1,3-Dichlorobenzene 71-120 0.9 20
0.051 1031000.0500.050mg/Kg1,4-Dichlorobenzene 71-123 2.3 20
Page 12 of 23Date:07/11/2022 06:30 PM
Page 37 of 50
Quality Control Data
22-182-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Ice & Coal Co.
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V20967QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 LOW
QC Prep:V20966
LCS-V20966 LCSD-V20966Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.057 1151180.0590.050mg/KgDichlorodifluoromethane 26-146 2.5 20
0.061 1231240.0610.050mg/Kg1,1-Dichloroethane 74-127 0.3 20
0.064 129*1270.0630.050mg/Kg1,2-Dichloroethane 68-128 1.7 20
0.059 1191220.0600.050mg/Kg1,1-Dichloroethene 67-149 2.1 20
0.064 1291260.0630.050mg/Kgcis-1,2-Dichloroethene 76-134 1.7 20
0.061 1231250.0620.050mg/Kgtrans-1,2-Dichloroethene 73-132 1.7 20
0.061 1231220.0600.050mg/Kg1,2-Dichloropropane 73-130 1.3 20
0.055 1111090.0540.050mg/Kg1,3-Dichloropropane 75-124 1.2 20
0.058 1171160.0570.050mg/Kg2,2-Dichloropropane 50-142 1.0 20
0.057 1151150.0570.050mg/Kg1,1-Dichloropropene 71-130 0.1 20
0.060 1201180.0580.050mg/Kgcis-1,3-Dichloropropene 71-125 2.0 20
0.060 1211190.0590.050mg/Kgtrans-1,3-Dichloropropene 68-123 2.0 20
0.052 1041030.0510.050mg/KgEthylbenzene 74-128 0.9 20
0.126 1261250.1250.100mg/KgEthyl Tertiary Butyl Ether (ETBE)70-130 0.7 20
0.049 98.097.20.0480.050mg/KgHexachlorobutadiene 64-125 0.8 20
0.055 1111060.0520.050mg/Kgn-Hexane 70-130 4.8 20
0.059 1181120.0560.050mg/Kg2-Hexanone 61-157 5.0 20
0.047 95.695.20.0470.050mg/KgIsopropylbenzene 68-126 0.4 20
0.050 1011020.0500.050mg/Kg4-Isopropyl toluene 68-129 0.9 20
0.059 1181160.0570.050mg/KgMethyl Ethyl Ketone (MEK)63-149 2.2 20
0.057 1161120.0560.050mg/KgMethyl tert-butyl ether (MTBE)70-130 2.9 20
0.067 1341290.0640.050mg/Kg4-Methyl-2-Pentanone 57-162 4.1 20
0.056 1121130.0560.050mg/KgMethylene Chloride 74-129 0.7 20
0.047 95.292.00.0460.050mg/KgNaphthalene 57-157 3.4 20
0.051 1031030.0510.050mg/Kgn-Propylbenzene 67-130 0.1 20
0.053 1071070.0530.050mg/KgStyrene 77-121 0.1 20
Page 13 of 23* QC Fail Date:07/11/2022 06:30 PM
Page 38 of 50
Quality Control Data
22-182-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Ice & Coal Co.
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V20967QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 LOW
QC Prep:V20966
LCS-V20966 LCSD-V20966Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.055 1101100.0550.050mg/Kg1,1,1,2-Tetrachloroethane 72-115 0.1 20
0.049 99.097.20.0480.050mg/Kg1,1,2,2-Tetrachloroethane 56-126 1.8 20
0.056 1131110.0550.050mg/KgTetrachloroethene 68-130 2.1 20
0.057 1151130.0560.050mg/KgToluene 71-129 2.1 20
0.050 10197.20.0480.050mg/Kg1,2,3-Trichlorobenzene 68-130 3.6 20
0.049 99.295.20.0470.050mg/Kg1,2,4-Trichlorobenzene 66-125 4.1 20
0.056 1141150.0570.050mg/Kg1,1,1-Trichloroethane 67-131 1.5 20
0.051 1021010.0500.050mg/Kg1,1,2-Trichloroethane 70-133 0.9 20
0.058 1161170.0580.050mg/KgTrichloroethene 75-133 0.8 20
0.059 1181220.0610.050mg/KgTrichlorofluoromethane 44-146 3.4 20
0.051 1041010.0500.050mg/Kg1,2,3-Trichloropropane 60-137 2.5 20
0.050 1001000.0500.050mg/Kg1,2,4-Trimethylbenzene 69-129 0.3 20
0.050 1011010.0500.050mg/Kg1,3,5-Trimethylbenzene 69-128 0.0 20
0.051 10298.40.0490.050mg/KgVinyl Acetate 60-140 3.9 20
0.060 1221250.0620.050mg/KgVinyl Chloride 48-147 2.9 20
0.051 1031040.0510.050mg/Kgo-Xylene 74-126 0.1 20
0.103 1031030.1030.100mg/Kgm,p-Xylene 75-124 0.0 20
97.697.64-Bromofluorobenzene (S)70-130
107105Dibromofluoromethane (S)84-123
97.496.8Toluene-d8 (S)76-129
Page 14 of 23Date:07/11/2022 06:30 PM
Page 39 of 50
Quality Control Data
22-182-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Ice & Coal Co.
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V21008QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V20976
Associated Lab Samples: 93366
LRB-V20976 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/07/22 15:580.6600.116<0.116mg/KgAcenaphthene
07/07/22 15:580.6600.105<0.105mg/KgAcenaphthylene
07/07/22 15:580.6600.152<0.152mg/KgAniline
07/07/22 15:580.6600.143<0.143mg/KgAnthracene
07/07/22 15:580.6600.139<0.139mg/KgBenzo(a)anthracene
07/07/22 15:580.6600.147<0.147mg/KgBenzo(a)pyrene
07/07/22 15:580.6600.146<0.146mg/KgBenzo(b)fluoranthene
07/07/22 15:580.6600.136<0.136mg/KgBenzo(g,h,i)perylene
07/07/22 15:580.6600.137<0.137mg/KgBenzo(k)fluoranthene
07/07/22 15:582.000.580<0.580mg/KgBenzoic Acid
07/07/22 15:580.6600.105<0.105mg/KgBenzyl alcohol
07/07/22 15:580.6600.118<0.118mg/KgBis(2-Chloroethoxy)methane
07/07/22 15:580.6600.107<0.107mg/KgBis(2-Chloroethyl)ether
07/07/22 15:580.3300.136<0.136mg/KgBis(2-Chloroisopropyl)ether
07/07/22 15:580.6600.120<0.120mg/KgBis(2-ethylhexyl)phthalate
07/07/22 15:580.6600.109<0.109mg/Kg4-Bromophenyl phenyl ether
07/07/22 15:580.3300.113<0.113mg/KgButyl benzyl phthalate
07/07/22 15:580.6600.092<0.092mg/Kg4-Chloro-3-methylphenol
07/07/22 15:580.3300.112<0.112mg/Kg4-Chloroaniline
07/07/22 15:580.6600.116<0.116mg/Kg2-Chloronaphthalene
07/07/22 15:580.6600.098<0.098mg/Kg2-Chlorophenol
07/07/22 15:581.000.126<0.126mg/Kg4-Chlorophenyl phenyl ether
07/07/22 15:580.6600.142<0.142mg/KgChrysene
07/07/22 15:580.6600.230<0.230mg/KgDibenz(a,h)anthracene
07/07/22 15:580.6600.119<0.119mg/KgDibenzofuran
07/07/22 15:580.6600.094<0.094mg/Kg1,2-Dichlorobenzene
07/07/22 15:580.6600.097<0.097mg/Kg1,3-Dichlorobenzene
Page 15 of 23Date:07/11/2022 06:30 PM
Page 40 of 50
Quality Control Data
22-182-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Ice & Coal Co.
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V21008QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V20976
Associated Lab Samples: 93366
LRB-V20976 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/07/22 15:580.3300.097<0.097mg/Kg1,4-Dichlorobenzene
07/07/22 15:580.6600.147<0.147mg/Kg3,3'-Dichlorobenzidine
07/07/22 15:580.6600.095<0.095mg/Kg2,4-Dichlorophenol
07/07/22 15:580.6600.180<0.180mg/KgDiethyl phthalate
07/07/22 15:580.6600.174<0.174mg/KgDimethyl phthalate
07/07/22 15:580.3300.108<0.108mg/Kg2,4-Dimethylphenol
07/07/22 15:580.6600.107<0.107mg/KgDi-n-butyl phthalate
07/07/22 15:581.500.240<0.240mg/Kg4,6-Dinitro-2-methylphenol
07/07/22 15:581.500.520<0.520mg/Kg2,4-Dinitrophenol
07/07/22 15:580.6600.096<0.096mg/Kg2,4-Dinitrotoluene
07/07/22 15:580.6600.108<0.108mg/Kg2,6-Dinitrotoluene
07/07/22 15:580.3300.143<0.143mg/KgDi-n-Octyl Phthalate
07/07/22 15:580.6600.123<0.123mg/KgFluoranthene
07/07/22 15:580.6600.128<0.128mg/KgFluorene
07/07/22 15:580.6600.106<0.106mg/KgHexachlorobenzene
07/07/22 15:580.6600.097<0.097mg/KgHexachlorobutadiene
07/07/22 15:580.6600.157<0.157mg/KgHexachlorocyclopentadiene
07/07/22 15:580.6600.079<0.079mg/KgHexachloroethane
07/07/22 15:580.6600.179<0.179mg/KgIndeno(1,2,3-cd)pyrene
07/07/22 15:580.6600.191<0.191mg/KgIsophorone
07/07/22 15:580.6600.106<0.106mg/Kg1-Methylnaphthalene
07/07/22 15:580.6600.100<0.100mg/Kg2-Methylnaphthalene
07/07/22 15:580.6600.097<0.097mg/Kg2-Methylphenol
07/07/22 15:580.6600.084<0.084mg/Kg3&4 Methylphenol
07/07/22 15:580.6600.144<0.144mg/KgNaphthalene
07/07/22 15:580.6600.096<0.096mg/Kg2-Nitroaniline
07/07/22 15:580.6600.120<0.120mg/Kg3-Nitroaniline
Page 16 of 23Date:07/11/2022 06:30 PM
Page 41 of 50
Quality Control Data
22-182-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Ice & Coal Co.
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V21008QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V20976
Associated Lab Samples: 93366
LRB-V20976 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/07/22 15:580.3300.093<0.093mg/Kg4-Nitroaniline
07/07/22 15:580.3300.116<0.116mg/KgNitrobenzene
07/07/22 15:580.6600.088<0.088mg/Kg2-Nitrophenol
07/07/22 15:580.6600.117<0.117mg/Kg4-Nitrophenol
07/07/22 15:580.6600.263<0.263mg/KgN-Nitrosodimethylamine
07/07/22 15:580.6600.181<0.181mg/KgN-Nitrosodiphenylamine
07/07/22 15:580.6600.118<0.118mg/KgN-Nitroso-di-n-propylamine
07/07/22 15:581.000.347<0.347mg/KgPentachlorophenol
07/07/22 15:580.6600.208<0.208mg/KgPhenanthrene
07/07/22 15:580.6600.112<0.112mg/KgPhenol
07/07/22 15:580.6600.134<0.134mg/KgPyrene
07/07/22 15:580.3300.079<0.079mg/KgPyridine
07/07/22 15:580.6600.107<0.107mg/Kg1,2,4-Trichlorobenzene
07/07/22 15:580.6600.096<0.096mg/Kg2,4,5-Trichlorophenol
07/07/22 15:580.6600.096<0.096mg/Kg2,4,6-Trichlorophenol
07/07/22 15:582-Fluorobiphenyl (S)92.8 44-115
07/07/22 15:582-Fluorophenol (S)87.6 35-115
07/07/22 15:58Nitrobenzene-d5 (S)76.6 37-122
07/07/22 15:584-Terphenyl-d14 (S)104 54-127
07/07/22 15:582,4,6-Tribromophenol (S)90.9 39-132
07/07/22 15:58Phenol-d5 (S)84.0 34-121
LCS-V20976 LCSD-V20976Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
1.59 95.297.61.631.67mg/KgAcenaphthene 40-123 2.4 20
Page 17 of 23Date:07/11/2022 06:30 PM
Page 42 of 50
Quality Control Data
22-182-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Ice & Coal Co.
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V21008QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V20976
LCS-V20976 LCSD-V20976Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
1.63 97.61011.681.67mg/KgAcenaphthylene 32-132 3.0 20
2.39 1431622.711.67mg/KgAniline 12-197 12.5 20
1.67 1001031.721.67mg/KgAnthracene 47-123 2.9 20
1.64 98.298.81.651.67mg/KgBenzo(a)anthracene 49-126 0.6 20
1.82 1091101.841.67mg/KgBenzo(a)pyrene 45-129 1.0 20
1.62 97.097.01.621.67mg/KgBenzo(b)fluoranthene 45-132 0.0 20
1.55 92.893.41.561.67mg/KgBenzo(g,h,i)perylene 43-134 0.6 20
1.61 96.499.41.661.67mg/KgBenzo(k)fluoranthene 47-132 3.0 20
1.17 70.066.41.111.67mg/KgBenzoic Acid 10-83 5.2 20
1.53 91.693.41.561.67mg/KgBenzyl alcohol 29-122 1.9 20
1.32 79.080.21.341.67mg/KgBis(2-Chloroethoxy)methane 36-121 1.5 20
1.32 79.063.41.061.67mg/KgBis(2-Chloroethyl)ether 31-120 21.8*20
1.33 79.680.81.351.67mg/KgBis(2-Chloroisopropyl)ether 33-131 1.4 20
1.78 1071071.791.67mg/KgBis(2-ethylhexyl)phthalate 51-133 0.5 20
1.72 1031071.781.67mg/Kg4-Bromophenyl phenyl ether 46-124 3.4 20
1.65 98.81001.671.67mg/KgButyl benzyl phthalate 48-132 1.2 20
1.45 86.885.01.421.67mg/Kg4-Chloro-3-methylphenol 45-122 2.0 20
1.41 84.481.41.361.67mg/Kg4-Chloroaniline 17-106 3.6 20
1.61 96.499.41.661.67mg/Kg2-Chloronaphthalene 41-114 3.0 20
1.51 90.491.61.531.67mg/Kg2-Chlorophenol 34-121 1.3 20
1.68 1011001.671.67mg/Kg4-Chlorophenyl phenyl ether 45-121 0.5 20
1.67 1001011.691.67mg/KgChrysene 50-124 1.1 20
1.34 80.280.21.341.67mg/KgDibenz(a,h)anthracene 45-134 0.0 20
1.61 96.498.81.651.67mg/KgDibenzofuran 44-120 2.4 20
1.39 83.286.21.441.67mg/Kg1,2-Dichlorobenzene 33-117 3.5 20
1.36 81.482.01.371.67mg/Kg1,3-Dichlorobenzene 30-115 0.7 20
Page 18 of 23* QC Fail Date:07/11/2022 06:30 PM
Page 43 of 50
Quality Control Data
22-182-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Ice & Coal Co.
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V21008QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V20976
LCS-V20976 LCSD-V20976Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
1.38 82.680.21.341.67mg/Kg1,4-Dichlorobenzene 31-115 2.9 20
1.37 82.075.41.261.67mg/Kg3,3'-Dichlorobenzidine 22-121 8.3 20
1.45 86.888.01.471.67mg/Kg2,4-Dichlorophenol 40-122 1.3 20
1.69 1011031.721.67mg/KgDiethyl phthalate 50-124 1.7 20
1.71 1021021.701.67mg/KgDimethyl phthalate 48-124 0.5 20
1.49 89.291.01.521.67mg/Kg2,4-Dimethylphenol 30-127 1.9 20
1.85 1111111.861.67mg/KgDi-n-butyl phthalate 51-128 0.5 20
1.53 91.691.61.531.67mg/Kg4,6-Dinitro-2-methylphenol 29-132 0.0 20
1.52 91.082.61.381.67mg/Kg2,4-Dinitrophenol 27-129 9.6 20
1.83 1101111.851.67mg/Kg2,4-Dinitrotoluene 48-126 1.0 20
1.84 1101111.851.67mg/Kg2,6-Dinitrotoluene 46-124 0.5 20
1.74 1041051.751.67mg/KgDi-n-Octyl Phthalate 45-140 0.5 20
1.66 99.41021.701.67mg/KgFluoranthene 50-127 2.3 20
1.66 99.41011.681.67mg/KgFluorene 43-125 1.1 20
1.66 99.41011.691.67mg/KgHexachlorobenzene 45-122 1.7 20
1.39 83.284.41.411.67mg/KgHexachlorobutadiene 32-123 1.4 20
1.20 71.874.81.251.67mg/KgHexachlorocyclopentadiene 32-117 4.0 20
1.28 76.676.01.271.67mg/KgHexachloroethane 28-117 0.7 20
1.51 90.492.81.551.67mg/KgIndeno(1,2,3-cd)pyrene 45-133 2.6 20
1.24 74.274.21.241.67mg/KgIsophorone 30-122 0.0 20
1.35 80.882.01.371.67mg/Kg1-Methylnaphthalene 40-119 1.4 20
1.32 79.079.61.331.67mg/Kg2-Methylnaphthalene 38-122 0.7 20
1.54 92.293.41.561.67mg/Kg2-Methylphenol 32-122 1.2 20
1.28 76.678.41.311.67mg/Kg3&4 Methylphenol 34-119 2.3 20
1.30 77.878.41.311.67mg/KgNaphthalene 35-123 0.7 20
1.58 94.694.01.571.67mg/Kg2-Nitroaniline 44-127 0.6 20
Page 19 of 23Date:07/11/2022 06:30 PM
Page 44 of 50
Quality Control Data
22-182-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Ice & Coal Co.
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V21008QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V20976
LCS-V20976 LCSD-V20976Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
1.55 92.892.21.541.67mg/Kg3-Nitroaniline 33-119 0.6 20
1.69 1011001.671.67mg/Kg4-Nitroaniline 63-147 1.1 20
1.24 74.274.81.251.67mg/KgNitrobenzene 34-122 0.8 20
1.38 82.682.61.381.67mg/Kg2-Nitrophenol 36-123 0.0 20
1.66 99.41041.741.67mg/Kg4-Nitrophenol 30-132 4.7 20
1.22 73.071.21.191.67mg/KgN-Nitrosodimethylamine 10-146 2.4 20
2.01 1201232.061.67mg/KgN-Nitrosodiphenylamine 38-127 2.4 20
1.33 79.680.81.351.67mg/KgN-Nitroso-di-n-propylamine 36-120 1.4 20
1.95 1171181.971.67mg/KgPentachlorophenol 25-133 1.0 20
1.67 1001021.701.67mg/KgPhenanthrene 50-121 1.7 20
1.59 95.295.81.601.67mg/KgPhenol 34-121 0.6 20
1.73 1041041.731.67mg/KgPyrene 47-127 0.0 20
0.946 56.657.00.9521.67mg/KgPyridine 10-80 0.6 20
1.35 80.881.41.361.67mg/Kg1,2,4-Trichlorobenzene 34-118 0.7 20
1.63 97.61021.701.67mg/Kg2,4,5-Trichlorophenol 41-124 4.2 20
1.66 99.41011.681.67mg/Kg2,4,6-Trichlorophenol 39-126 1.1 20
95.298.22-Fluorobiphenyl (S)44-115
91.894.22-Fluorophenol (S)35-115
73.072.4Nitrobenzene-d5 (S)37-122
1051084-Terphenyl-d14 (S)54-127
1011012,4,6-Tribromophenol (S)39-132
87.689.1Phenol-d5 (S)34-121
Page 20 of 23Date:07/11/2022 06:30 PM
Page 45 of 50
Quality Control Data
22-182-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Ice & Coal Co.
QC Prep Batch Method:
Massachusetts EPH
MADEP-EPH
V21041QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAEPH (Prep)
QC Prep:V20926
Associated Lab Samples: 93366
LRB-V20926 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/07/22 13:3250.09.20<9.20mg/KgAliphatic C9-C18
07/07/22 13:3250.012.2<12.2mg/KgAliphatic C19-C36
07/07/22 13:3250.014.2<14.2mg/KgAromatic C11-C22
07/07/22 13:322-Fluorobiphenyl (S)85.0 40-140
07/07/22 13:322-Bromonaphthalene (S)90.0 40-140
07/07/22 13:32Chlorooctadecane (S)71.5 40-140
07/07/22 13:32OTP Surrogate (S)79.0 40-140
LCS-V20926 LCSD-V20926Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
44.9 74.969.941.959.9mg/KgAliphatic C9-C18 40-140 6.9 50
64.9 81.375.460.379.9mg/KgAliphatic C19-C36 40-140 7.3 50
161 94.7108183170mg/KgAromatic C11-C22 40-140 12.7 50
79.491.02-Fluorobiphenyl (S)40-140
85.997.72-Bromonaphthalene (S)40-140
75.069.0Chlorooctadecane (S)40-140
71.582.5OTP Surrogate (S)40-140
Page 21 of 23Date:07/11/2022 06:30 PM
Page 46 of 50
Quality Control Data
22-182-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Ice & Coal Co.
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V20855QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V20854
Associated Lab Samples: 93366
LRB-V20854 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/05/22 11:218.001.22<1.22mg/KgAliphatic C5-C8
07/05/22 11:218.004.56<4.56mg/KgAliphatic C9-C12
07/05/22 11:218.000.624<0.624mg/KgAromatic C9-C10
07/05/22 11:212,5-Dibromotoluene (FID) (S)81.5 70-130
07/05/22 11:212,5-Dibromotoluene (PID) (S)80.7 70-130
LCS-V20854 LCSD-V20854Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
27.6 86.285.327.332.0mg/KgAliphatic C5-C8 70-130 1.0 50
32.8 10310332.932.0mg/KgAliphatic C9-C12 70-130 0.3 50
11.2 10510611.310.7mg/KgAromatic C9-C10 70-130 0.8 50
82.375.22,5-Dibromotoluene (FID) (S)70-130
76.976.02,5-Dibromotoluene (PID) (S)70-130
Page 22 of 23Date:07/11/2022 06:30 PM
Page 47 of 50
Quality Control Data
22-182-0013Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Ice & Coal Co.
Dry Weight Determination
SW-DRYWT
V20924QC Analytical Batch:
Analysis Method:
Analysis Description:
V 93369-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 07/06/22 12:172.721.921.3%Moisture
V 93500-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 07/06/22 12:171.39.279.15%Moisture
Page 23 of 23Date:07/11/2022 06:30 PM
Page 48 of 50
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:22-182-0013
Geological Resources, Inc.
00087
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT-15 5.0 C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
ü
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)ü
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Adam Crouch Date & Time:07/01/2022 10:02:25
Special precautions or instructions included?
Comments:
Page 49 of 50
Page 50 of 50

APPENDIX E
Laboratory Report – Ground Water

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

7/26/2022
Geological Resources, Inc. Scott Driscoll
113 W. Firetower Road, Suite G Winterville, NC, 28590
Ref: Analytical Testing
Lab Report Number: 22-189-0052 Client Project Description: Rose Coal & Ice
GRI #5716
Dear Scott Driscoll:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 7/8/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love Project Manager
Page 1 of 91
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202237735State ProgramNorth Carolina
12/31/2022402State ProgramNorth Carolina
07/31/202299012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Page 1 of 1 00016/22-189-0052
Page 2 of 91
Report Number:
Sample Summary Table
Client Project Description:
22-189-0052
Rose Coal & Ice
GRI #5716
Lab No Client Sample ID Matrix Date Collected Date Received
07/07/2022 09:35Aqueous 93944 MW-1 07/08/2022
07/07/2022 09:50Aqueous 93945 MW-2 07/08/2022
07/07/2022 10:05Aqueous 93946 MW-3 07/08/2022
07/07/2022 09:20Aqueous 93947 MW-4 07/08/2022
07/07/2022 07:45Aqueous 93948 TB 07/08/2022
Page 3 of 91
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-189-0052
Report Limit
Project:Rose Coal & Ice
V 93944MW-1
0.008 07/12/2022 17:136010DLeadmg/L 0.002
J4.58 07/15/2022 15:006200BAcetoneµg/L 1.80
J0.239 07/15/2022 15:006200BBenzeneµg/L 0.180
J0.263 07/15/2022 15:006200BEthylbenzeneµg/L 0.170
J0.420 07/15/2022 15:006200BTolueneµg/L 0.220
1.02 07/15/2022 15:006200B1,2,4-Trimethylbenzene µg/L 0.190
J0.412 07/15/2022 15:006200B1,3,5-Trimethylbenzene µg/L 0.180
0.678 07/15/2022 15:006200Bo-Xylene µg/L 0.210
J0.927 07/15/2022 15:006200Bm,p-Xylene µg/L 0.420
J1.61 07/15/2022 15:006200BXylene (Total)µg/L 0.210
JB95.7 07/21/2022 19:20MADEP-EPH Aliphatic C9-C18 µg/L 51.2
V 93945MW-2
0.864 07/12/2022 17:176010DLeadmg/L 0.024
JB88.9 07/22/2022 08:55MADEP-EPH Aliphatic C9-C18 µg/L 51.2
V 93946MW-3
0.043 07/12/2022 17:296010DLeadmg/L 0.002
J2.96 07/15/2022 01:306200BAcetoneµg/L 1.80
JB49.0 07/22/2022 09:31MADEP-EPH Aliphatic C9-C18 µg/L 38.1
V 93947MW-4
0.137 07/12/2022 17:336010DLeadmg/L 0.002
1.34 07/15/2022 18:526200BBenzeneµg/L 0.180
18.9 07/15/2022 18:526200Bn-Butylbenzene µg/L 0.180
11.0 07/15/2022 18:526200Bsec-Butyl benzene µg/L 0.200
73.2 07/15/2022 18:526200BEthylbenzeneµg/L 0.170
8.50 07/15/2022 18:526200B2-Hexanone µg/L 0.380
22.2 07/15/2022 18:526200BIsopropylbenzeneµg/L 0.180
9.21 07/15/2022 18:526200B4-Isopropyl toluene µg/L 0.089
86.0 07/15/2022 18:526200BNaphthaleneµg/L 0.470
62.2 07/15/2022 18:526200Bn-Propylbenzene µg/L 0.190
0.693 07/15/2022 18:526200BTolueneµg/L 0.220
774 07/15/2022 19:316200B1,2,4-Trimethylbenzene µg/L 1.90
149 07/15/2022 19:316200B1,3,5-Trimethylbenzene µg/L 1.80
3.63 07/15/2022 18:526200Bo-Xylene µg/L 0.210
170 07/15/2022 18:526200Bm,p-Xylene µg/L 0.420
174 07/15/2022 18:526200BXylene (Total)µg/L 0.210
Page 4 of 91
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-189-0052
Report Limit
Project:Rose Coal & Ice
V 93947MW-4
14.0 07/13/2022 22:04625.1 Naphthalene µg/L 10.2
2330 07/13/2022 08:29CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 11.5
2370 07/13/2022 08:29CALCULATIONAromatic C9-C10 (Adjusted)µg/L 4.02
M39007/13/2022 22:04CALCULATIONAromatic C11-C22 (Adjusted)µg/L 94.2
JB18707/22/2022 10:07MADEP-EPH Aliphatic C9-C18 µg/L 43.3
404 07/22/2022 10:07MADEP-EPH Aromatic C11-C22 µg/L 94.2
2330 07/13/2022 08:29MADEP-VPH Aliphatic C5-C8 µg/L 11.5
2140 07/13/2022 08:29MADEP-VPH Aliphatic C9-C12 µg/L 25.8
2370 07/13/2022 08:29MADEP-VPH Aromatic C9-C10 µg/L 4.02
V 93948TB
J0.980 07/14/2022 19:036200BMethylene Chloride µg/L 0.330
Page 5 of 91

Client: Geological Resources, Inc. CASE NARRATIVE
Project: Rose Coal & Ice Lab Report Number: 22-189-0052
Date: 7/26/2022
625.1 - Base/Neutrals and Acids by GC/MS Method 625.1 Sample 93944 (MW-1) QC Batch No: V21263/V21203
Surrogate(s) were flagged for recoveries in the associated project sample. During the extraction step, the extraction technician noted that a significant emulsion formed. Method Blank showed surrogate recoveries within
QC limits, indicating that the biased recoveries were due to the sample matrix.
Sample 93945 (MW-2) QC Batch No: V21263/V21203
Surrogate(s) were flagged for recoveries in the associated project sample. During the extraction step, the extraction technician noted that a significant emulsion formed. Method Blank showed surrogate recoveries within
QC limits, indicating that the biased recoveries were due to the sample matrix.
Analyte: 1,2,4-Trichlorobenzene QC Batch No: V21263/V21203
This target analyte was flagged for recoveries outside QC limits in the associated LCS/LCSD. Data for this analyte is flagged "M" to indicate that results should be considered minimum concentration due to the potential for
a low bias.
Analyte: 2-Chloronaphthalene QC Batch No: V21263/V21203 This target analyte was flagged for recoveries outside QC limits in the associated LCS/LCSD. Data for this analyte is flagged "M" to indicate that results should be considered minimum concentration due to the potential for
a low bias.
Sample 93947 (MW-4) Analyte: 2-Fluorobiphenyl
QC Batch No: V21263/V21203 Surrogate(s) were flagged for recoveries in the associated project sample. During the extraction step, the extraction technician noted that a significant emulsion formed. Method Blank showed surrogate recoveries within QC limits, indicating that the biased recoveries were due to the sample matrix.
Analyte: 2,4-Dinitrophenol
QC Batch No: V21263/V21203 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits. Sample 93947 (MW-4) Analyte: 4-Terphenyl-d14 QC Batch No: V21263/V21203
Surrogate(s) were flagged for recoveries in the associated project sample. During the extraction step, the extraction technician noted that a significant emulsion formed. Method Blank showed surrogate recoveries within QC limits, indicating that the biased recoveries were due to the sample matrix.
Page 6 of 91

Analyte: Benzoic Acid
QC Batch No: V21263/V21203 This target analyte was flagged for recoveries outside QC limits in the associated LCS/LCSD. Data for this
analyte is flagged "M" to indicate that results should be considered minimum concentration due to the potential for a low bias.
Analyte: Fluorene
QC Batch No: V21263/V21203 This target analyte was flagged for recoveries outside QC limits in the associated LCS/LCSD. Data for this
analyte is flagged "M" to indicate that results should be considered minimum concentration due to the potential for a low bias.
Analyte: Hexachlorocyclopentadiene
QC Batch No: V21263/V21203 This target analyte was flagged for recoveries outside QC limits in the associated LCS/LCSD. Data for this
analyte is flagged "M" to indicate that results should be considered minimum concentration due to the potential for a low bias.
Analyte: Hexachloroethane
QC Batch No: V21263/V21203 This target analyte was flagged for recoveries outside QC limits in the associated LCS/LCSD. Data for this
analyte is flagged "M" to indicate that results should be considered minimum concentration due to the potential for a low bias. Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Nitrobenzene-d5
QC Batch No: V21263/V21203 Surrogate recovery below range. Sample 93947 (MW-4) Analyte: Nitrobenzene-d5 QC Batch No: V21263/V21203
Surrogate(s) were flagged for recoveries in the associated project sample. During the extraction step, the extraction technician noted that a significant emulsion formed. Method Blank showed surrogate recoveries within
QC limits, indicating that the biased recoveries were due to the sample matrix. Analyte: N-Nitrosodiphenylamine QC Batch No: V21263/V21203 This target analyte was flagged for recoveries outside QC limits in the associated LCS/LCSD. Data for this analyte is flagged "M" to indicate that results should be considered minimum concentration due to the potential for
a low bias. Massachusetts EPH Method MADEP-EPH Sample 93945 (MW-2) Analyte: Chlorooctadecane QC Batch No: V21698/V21273 Surrogate(s) were flagged for recoveries in the associated project sample. During the extraction step, the extraction technician noted that a significant emulsion formed. Method Blank showed surrogate recoveries within QC limits, indicating that the biased recoveries were due to the sample matrix.
Page 7 of 91

Sample 93947 (MW-4)
Analyte: Chlorooctadecane QC Batch No: V21698/V21273
Surrogate(s) were flagged for recoveries in the associated project sample. During the extraction step, the extraction technician noted that a significant emulsion formed. Method Blank showed surrogate recoveries within
QC limits, indicating that the biased recoveries were due to the sample matrix.
Sample 93945 (MW-2) Analyte: o-Terphenyl
QC Batch No: V21698/V21273 Surrogate(s) were flagged for recoveries in the associated project sample. During the extraction step, the
extraction technician noted that a significant emulsion formed. Method Blank showed surrogate recoveries within QC limits, indicating that the biased recoveries were due to the sample matrix.
Volatile Organic Compounds - GC/MS Method 6200B Analyte: tert-Amyl alcohol QC Batch No: V21339/V21408
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits. Acid Digestion of Aqueous samples Method 3005A Sample 93945 (MW-2)
QC Batch No: V21132/V21132 The sample was diluted due to the nature of the sample matrix. Reporting limits have been adjusted accordingly. Metals Analysis Method 6010D Sample 93838 (MW-2-01) QC Batch No: V21392/V21132
The sample was diluted due to the nature of the sample matrix. Reporting limits have been adjusted accordingly.
Page 8 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-1
93944 Matrix:
7/7/2022 9:35
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 07/15/22 15:00 6200BJLB
0.008 mg/L 0.002 0.006Lead 1 07/12/22 17:13 6010DEDV
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 9 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-1
93944 Matrix:
7/7/2022 9:35
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21408 07/15/22 09:00
4.58 J µg/L 1.80 10.0Acetone 1 07/15/22 15:00 V21409JLB
0.239 J µg/L 0.180 0.500Benzene 1 07/15/22 15:00 V21409JLB
<0.210 µg/L 0.210 0.500Bromobenzene 1 07/15/22 15:00 V21409JLB
<0.420 µg/L 0.420 1.00Bromochloromethane 1 07/15/22 15:00 V21409JLB
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 07/15/22 15:00 V21409JLB
<1.50 µg/L 1.50 5.00Bromoform 1 07/15/22 15:00 V21409JLB
<0.280 µg/L 0.280 1.00Bromomethane 1 07/15/22 15:00 V21409JLB
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 07/15/22 15:00 V21409JLB
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 07/15/22 15:00 V21409JLB
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 07/15/22 15:00 V21409JLB
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 07/15/22 15:00 V21409JLB
<0.190 µg/L 0.190 0.500Chlorobenzene 1 07/15/22 15:00 V21409JLB
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 07/15/22 15:00 V21409JLB
<0.430 µg/L 0.430 1.00Chloroethane 1 07/15/22 15:00 V21409JLB
<0.220 µg/L 0.220 0.500Chloroform 1 07/15/22 15:00 V21409JLB
<0.220 µg/L 0.220 0.500
Chloromethane 1 07/15/22 15:00 V21409JLB
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 07/15/22 15:00 V21409JLB
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 07/15/22 15:00 V21409JLB
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 07/15/22 15:00 V21409JLB
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 07/15/22 15:00 V21409JLB
<0.230 µg/L 0.230 0.500Dibromomethane 1 07/15/22 15:00 V21409JLB
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 07/15/22 15:00 V21409JLB
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 10 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-1
93944 Matrix:
7/7/2022 9:35
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21408 07/15/22 09:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 07/15/22 15:00 V21409JLB
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 07/15/22 15:00 V21409JLB
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 07/15/22 15:00 V21409JLB
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 07/15/22 15:00 V21409JLB
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 07/15/22 15:00 V21409JLB
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 07/15/22 15:00 V21409JLB
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 07/15/22 15:00 V21409JLB
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 07/15/22 15:00 V21409JLB
<0.190 µg/L 0.190 0.500
1,2-Dichloropropane 1 07/15/22 15:00 V21409JLB
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 07/15/22 15:00 V21409JLB
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 07/15/22 15:00 V21409JLB
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 07/15/22 15:00 V21409JLB
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 07/15/22 15:00 V21409JLB
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 07/15/22 15:00 V21409JLB
<42.0 µg/L 42.0 200Ethanol 1 07/15/22 15:00 V21409JLB
0.263 J
µg/L 0.170 0.500
Ethylbenzene 1 07/15/22 15:00 V21409JLB
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 07/15/22 15:00 V21409JLB
<0.380 µg/L 0.380 1.002-Hexanone 1 07/15/22 15:00 V21409JLB
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 07/15/22 15:00 V21409JLB
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 07/15/22 15:00 V21409JLB
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 07/15/22 15:00 V21409JLB
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 07/15/22 15:00 V21409JLB
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 11 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-1
93944 Matrix:
7/7/2022 9:35
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21408 07/15/22 09:00
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 07/15/22 15:00 V21409JLB
<0.330 µg/L 0.330 2.00Methylene Chloride 1 07/15/22 15:00 V21409JLB
<0.470 µg/L 0.470 1.00Naphthalene 1 07/15/22 15:00 V21409JLB
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 07/15/22 15:00 V21409JLB
<0.220 µg/L 0.220 0.500Styrene 1 07/15/22 15:00 V21409JLB
<1.60 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 07/15/22 15:00 V21409JLB
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 07/15/22 15:00 V21409JLB
<1.90 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 07/15/22 15:00 V21409JLB
<0.280 µg/L 0.280 10.0
tert-Amyl Methyl Ether (TAME)1 07/15/22 15:00 V21409JLB
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 07/15/22 15:00 V21409JLB
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 07/15/22 15:00 V21409JLB
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 07/15/22 15:00 V21409JLB
0.420 J µg/L 0.220 0.500Toluene 1 07/15/22 15:00 V21409JLB
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 07/15/22 15:00 V21409JLB
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 07/15/22 15:00 V21409JLB
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 07/15/22 15:00 V21409JLB
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 07/15/22 15:00 V21409JLB
<0.180 µg/L 0.180 0.500Trichloroethene 1 07/15/22 15:00 V21409JLB
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 07/15/22 15:00 V21409JLB
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 07/15/22 15:00 V21409JLB
1.02 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 07/15/22 15:00 V21409JLB
0.412 J µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 07/15/22 15:00 V21409JLB
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 12 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-1
93944 Matrix:
7/7/2022 9:35
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21408 07/15/22 09:00
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 07/15/22 15:00 V21409JLB
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 07/15/22 15:00 V21409JLB
0.678 µg/L 0.210 0.500o-Xylene 1 07/15/22 15:00 V21409JLB
0.927 J µg/L 0.420 1.00m,p-Xylene 1 07/15/22 15:00 V21409JLB
1.61 J µg/L 0.210 0.500Xylene (Total)1 07/15/22 15:00 V21409KCC
Surrogate: 4-Bromofluorobenzene 99.6 Limits: 70-130%07/15/22 15:001 JLB V21409
Surrogate: Dibromofluoromethane 95.6 Limits: 70-130%07/15/22 15:001 JLB V21409
Surrogate: 1,2-Dichloroethane - d4 96.6 Limits: 70-130%07/15/22 15:001 JLB V21409
Surrogate: Toluene-d8 99.2 Limits: 70-130%07/15/22 15:001 JLB V21409
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V21203 07/12/22 14:40
<8.76 µg/L 8.76 12.3
Acenaphthene 1 07/13/22 22:26 V21263JMV
<8.57 µg/L 8.57 24.7Acenaphthylene 1 07/13/22 22:26 V21263JMV
<8.08 µg/L 8.08 12.3Anthracene 1 07/13/22 22:26 V21263JMV
<6.25 µg/L 6.25 12.3Benzidine 1 07/13/22 22:26 V21263JMV
<8.18 µg/L 8.18 12.3Benzo(a)anthracene 1 07/13/22 22:26 V21263JMV
<5.74 µg/L 5.74 12.3Benzo(a)pyrene 1 07/13/22 22:26 V21263JMV
<5.56 µg/L 5.56 12.3Benzo(b)fluoranthene 1 07/13/22 22:26 V21263JMV
<5.22 µg/L 5.22 12.3
Benzo(g,h,i)perylene 1 07/13/22 22:26 V21263JMV
<5.98 µg/L 5.98 12.3Benzo(k)fluoranthene 1 07/13/22 22:26 V21263JMV
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 13 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-1
93944 Matrix:
7/7/2022 9:35
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V21203 07/12/22 14:40
<14.2 M µg/L 14.2 61.7Benzoic Acid 1 07/13/22 22:26 V21263JMV
<10.6 µg/L 10.6 12.3Benzyl alcohol 1 07/13/22 22:26 V21263JMV
<6.97 µg/L 6.97 12.3Bis(2-Chloroethoxy)methane 1 07/13/22 22:26 V21263JMV
<8.98 µg/L 8.98 12.3Bis(2-Chloroethyl)ether 1 07/13/22 22:26 V21263JMV
<8.11 µg/L 8.11 12.3Bis(2-Chloroisopropyl)ether 1 07/13/22 22:26 V21263JMV
<10.8 µg/L 10.8 12.3Bis(2-ethylhexyl)phthalate 1 07/13/22 22:26 V21263JMV
<7.73 µg/L 7.73 24.74-Bromophenyl phenyl ether 1 07/13/22 22:26 V21263JMV
<5.57 µg/L 5.57 12.3Butyl benzyl phthalate 1 07/13/22 22:26 V21263JMV
<6.43 µg/L 6.43 12.3
4-Chloro-3-methylphenol 1 07/13/22 22:26 V21263JMV
<9.11 M µg/L 9.11 24.72-Chloronaphthalene 1 07/13/22 22:26 V21263JMV
<8.09 µg/L 8.09 12.32-Chlorophenol 1 07/13/22 22:26 V21263JMV
<8.63 µg/L 8.63 24.74-Chlorophenyl phenyl ether 1 07/13/22 22:26 V21263JMV
<6.62 µg/L 6.62 12.3Chrysene 1 07/13/22 22:26 V21263JMV
<7.42 µg/L 7.42 24.7Dibenz(a,h)anthracene 1 07/13/22 22:26 V21263JMV
<6.27 µg/L 6.27 24.7Dibenzofuran 1 07/13/22 22:26 V21263JMV
<7.27 µg/L 7.27 12.3
1,2-Dichlorobenzene 1 07/13/22 22:26 V21263JMV
<7.17 µg/L 7.17 12.31,3-Dichlorobenzene 1 07/13/22 22:26 V21263JMV
<7.27 µg/L 7.27 12.31,4-Dichlorobenzene 1 07/13/22 22:26 V21263JMV
<8.12 µg/L 8.12 12.33,3'-Dichlorobenzidine 1 07/13/22 22:26 V21263JMV
<6.81 µg/L 6.81 12.32,4-Dichlorophenol 1 07/13/22 22:26 V21263JMV
<11.5 µg/L 11.5 24.7Diethyl phthalate 1 07/13/22 22:26 V21263JMV
<9.62 µg/L 9.62 12.3Dimethyl phthalate 1 07/13/22 22:26 V21263JMV
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 14 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-1
93944 Matrix:
7/7/2022 9:35
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V21203 07/12/22 14:40
<13.5 µg/L 13.5 24.72,4-Dimethylphenol 1 07/13/22 22:26 V21263JMV
<9.04 µg/L 9.04 12.3Di-n-butyl phthalate 1 07/13/22 22:26 V21263JMV
<12.2 µg/L 12.2 37.04,6-Dinitro-2-methylphenol 1 07/13/22 22:26 V21263JMV
<13.1 µg/L 13.1 37.02,4-Dinitrophenol 1 07/13/22 22:26 V21263JMV
<6.40 µg/L 6.40 12.32,4-Dinitrotoluene 1 07/13/22 22:26 V21263JMV
<7.29 µg/L 7.29 24.72,6-Dinitrotoluene 1 07/13/22 22:26 V21263JMV
<6.16 µg/L 6.16 12.3Di-n-Octyl Phthalate 1 07/13/22 22:26 V21263JMV
<7.42 µg/L 7.42 12.3Fluoranthene 1 07/13/22 22:26 V21263JMV
<8.94 M
µg/L 8.94 12.3
Fluorene 1 07/13/22 22:26 V21263JMV
<7.10 µg/L 7.10 24.7Hexachlorobenzene 1 07/13/22 22:26 V21263JMV
<7.26 µg/L 7.26 24.7Hexachlorobutadiene 1 07/13/22 22:26 V21263JMV
<7.29 M µg/L 7.29 24.7Hexachlorocyclopentadiene 1 07/13/22 22:26 V21263JMV
<6.42 M µg/L 6.42 12.3Hexachloroethane 1 07/13/22 22:26 V21263JMV
<7.63 µg/L 7.63 12.3Indeno(1,2,3-cd)pyrene 1 07/13/22 22:26 V21263JMV
<8.25 µg/L 8.25 12.3Isophorone 1 07/13/22 22:26 V21263JMV
<9.69 µg/L 9.69 12.3
Naphthalene 1 07/13/22 22:26 V21263JMV
<9.69 µg/L 9.69 12.3Nitrobenzene 1 07/13/22 22:26 V21263JMV
<6.75 µg/L 6.75 12.32-Nitrophenol 1 07/13/22 22:26 V21263JMV
<3.46 µg/L 3.46 12.34-Nitrophenol 1 07/13/22 22:26 V21263JMV
<13.5 M µg/L 13.5 24.7N-Nitrosodiphenylamine 1 07/13/22 22:26 V21263JMV
<10.0 µg/L 10.0 24.7N-Nitroso-di-n-propylamine 1 07/13/22 22:26 V21263JMV
<12.0 µg/L 12.0 61.7Pentachlorophenol 1 07/13/22 22:26 V21263JMV
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 15 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-1
93944 Matrix:
7/7/2022 9:35
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V21203 07/12/22 14:40
<7.80 µg/L 7.80 12.3Phenanthrene 1 07/13/22 22:26 V21263JMV
<3.52 µg/L 3.52 12.3Phenol 1 07/13/22 22:26 V21263JMV
<6.67 µg/L 6.67 12.3Pyrene 1 07/13/22 22:26 V21263JMV
<7.69 M µg/L 7.69 12.31,2,4-Trichlorobenzene 1 07/13/22 22:26 V21263JMV
<7.77 µg/L 7.77 24.72,4,6-Trichlorophenol 1 07/13/22 22:26 V21263JMV
625.1Surrogate: Phenol-d5 15.4 Limits: 10-63%07/13/22 22:261 JMV
Surrogate: 2-Fluorobiphenyl 14.1 *Limits: 49-118%07/13/22 22:261 JMV V21263
Surrogate: 2-Fluorophenol 19.8 *Limits: 22-84%07/13/22 22:261 JMV V21263
Surrogate: Nitrobenzene-d5 13.6 *Limits: 43-123%07/13/22 22:261 JMV V21263
Surrogate: 4-Terphenyl-d14 14.9 *Limits: 49-151%07/13/22 22:261 JMV V21263
Surrogate: 2,4,6-Tribromophenol 13.7 *Limits: 31-144%07/13/22 22:261 JMV V21263
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):V21593 07/20/22 16:30
<0.00340 µg/L 0.00340 0.02061,2-Dibromoethane 1 07/20/22 23:26 V21719JC1
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 16 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-1
93944 Matrix:
7/7/2022 9:35
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<11.5 µg/L 50.0Aliphatic C5-C8 (Adjusted)1 07/12/22 19:19
<25.8 µg/L 50Aliphatics C9-C12 (Adjusted)1 07/12/22 19:19
<4.02 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 07/12/22 19:19
<111 M µg/L 111 455Aromatic C11-C22 (Adjusted)1 07/13/22 22:26
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V21273 07/14/22 09:16
95.7 JB µg/L 51.2 636Aliphatic C9-C18 1 07/21/22 19:20 V21698JLK
<225 µg/L 225 909Aliphatic C19-C36 1 07/21/22 19:20 V21698JLK
<111 µg/L 111 455Aromatic C11-C22 1 07/21/22 19:20 V21698JLK
MADEP-EPHSurrogate: 2-Bromonaphthalene 85.3 Limits: 40-140%07/21/22 19:201 JLK
MADEP-EPHSurrogate: Chlorooctadecane 45.6 Limits: 40-140%07/21/22 19:201 JLK
MADEP-EPHSurrogate: OTP Surrogate 61.8 Limits: 40-140%07/21/22 19:201 JLK
Surrogate: 2-Fluorobiphenyl 82.3 Limits: 40-140%07/21/22 19:201 JLK V21698
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V21177 07/12/22 08:00
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 1 07/12/22 19:19 V21178TBL
<25.8 µg/L 25.8 50.0Aliphatic C9-C12 1 07/12/22 19:19 V21178TBL
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 17 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-1
93944 Matrix:
7/7/2022 9:35
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V21177 07/12/22 08:00
<4.02 µg/L 4.02 50.0Aromatic C9-C10 1 07/12/22 19:19 V21178TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)80.4 Limits: 70-130%07/12/22 19:191 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)79.0 Limits: 70-130%07/12/22 19:191 TBL
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 18 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-2
93945 Matrix:
7/7/2022 9:50
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 07/15/22 00:52 6200BJLB
0.864 mg/L 0.024 0.060Lead 1 07/12/22 17:17 6010DEDV
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 19 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-2
93945 Matrix:
7/7/2022 9:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21337 07/14/22 09:00
<1.80 µg/L 1.80 10.0Acetone 1 07/15/22 00:52 V21339JLB
<0.180 µg/L 0.180 0.500Benzene 1 07/15/22 00:52 V21339JLB
<0.210 µg/L 0.210 0.500Bromobenzene 1 07/15/22 00:52 V21339JLB
<0.420 µg/L 0.420 1.00Bromochloromethane 1 07/15/22 00:52 V21339JLB
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 07/15/22 00:52 V21339JLB
<1.50 µg/L 1.50 5.00Bromoform 1 07/15/22 00:52 V21339JLB
<0.280 µg/L 0.280 1.00Bromomethane 1 07/15/22 00:52 V21339JLB
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 07/15/22 00:52 V21339JLB
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 07/15/22 00:52 V21339JLB
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 07/15/22 00:52 V21339JLB
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 07/15/22 00:52 V21339JLB
<0.190 µg/L 0.190 0.500Chlorobenzene 1 07/15/22 00:52 V21339JLB
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 07/15/22 00:52 V21339JLB
<0.430 µg/L 0.430 1.00Chloroethane 1 07/15/22 00:52 V21339JLB
<0.220 µg/L 0.220 0.500Chloroform 1 07/15/22 00:52 V21339JLB
<0.220 µg/L 0.220 0.500
Chloromethane 1 07/15/22 00:52 V21339JLB
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 07/15/22 00:52 V21339JLB
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 07/15/22 00:52 V21339JLB
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 07/15/22 00:52 V21339JLB
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 07/15/22 00:52 V21339JLB
<0.230 µg/L 0.230 0.500Dibromomethane 1 07/15/22 00:52 V21339JLB
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 07/15/22 00:52 V21339JLB
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 20 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-2
93945 Matrix:
7/7/2022 9:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21337 07/14/22 09:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 07/15/22 00:52 V21339JLB
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 07/15/22 00:52 V21339JLB
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 07/15/22 00:52 V21339JLB
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 07/15/22 00:52 V21339JLB
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 07/15/22 00:52 V21339JLB
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 07/15/22 00:52 V21339JLB
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 07/15/22 00:52 V21339JLB
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 07/15/22 00:52 V21339JLB
<0.190 µg/L 0.190 0.500
1,2-Dichloropropane 1 07/15/22 00:52 V21339JLB
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 07/15/22 00:52 V21339JLB
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 07/15/22 00:52 V21339JLB
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 07/15/22 00:52 V21339JLB
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 07/15/22 00:52 V21339JLB
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 07/15/22 00:52 V21339JLB
<42.0 µg/L 42.0 200Ethanol 1 07/15/22 00:52 V21339JLB
<0.170 µg/L 0.170 0.500
Ethylbenzene 1 07/15/22 00:52 V21339JLB
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 07/15/22 00:52 V21339JLB
<0.380 µg/L 0.380 1.002-Hexanone 1 07/15/22 00:52 V21339JLB
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 07/15/22 00:52 V21339JLB
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 07/15/22 00:52 V21339JLB
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 07/15/22 00:52 V21339JLB
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 07/15/22 00:52 V21339JLB
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 21 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-2
93945 Matrix:
7/7/2022 9:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21337 07/14/22 09:00
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 07/15/22 00:52 V21339JLB
<0.330 µg/L 0.330 2.00Methylene Chloride 1 07/15/22 00:52 V21339JLB
<0.470 µg/L 0.470 1.00Naphthalene 1 07/15/22 00:52 V21339JLB
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 07/15/22 00:52 V21339JLB
<0.220 µg/L 0.220 0.500Styrene 1 07/15/22 00:52 V21339JLB
<1.60 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 07/15/22 00:52 V21339JLB
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 07/15/22 00:52 V21339JLB
<1.90 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 07/15/22 00:52 V21339JLB
<0.280 µg/L 0.280 10.0
tert-Amyl Methyl Ether (TAME)1 07/15/22 00:52 V21339JLB
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 07/15/22 00:52 V21339JLB
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 07/15/22 00:52 V21339JLB
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 07/15/22 00:52 V21339JLB
<0.220 µg/L 0.220 0.500Toluene 1 07/15/22 00:52 V21339JLB
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 07/15/22 00:52 V21339JLB
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 07/15/22 00:52 V21339JLB
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 07/15/22 00:52 V21339JLB
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 07/15/22 00:52 V21339JLB
<0.180 µg/L 0.180 0.500Trichloroethene 1 07/15/22 00:52 V21339JLB
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 07/15/22 00:52 V21339JLB
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 07/15/22 00:52 V21339JLB
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 07/15/22 00:52 V21339JLB
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 07/15/22 00:52 V21339JLB
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 22 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-2
93945 Matrix:
7/7/2022 9:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21337 07/14/22 09:00
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 07/15/22 00:52 V21339JLB
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 07/15/22 00:52 V21339JLB
<0.210 µg/L 0.210 0.500o-Xylene 1 07/15/22 00:52 V21339JLB
<0.420 µg/L 0.420 1.00m,p-Xylene 1 07/15/22 00:52 V21339JLB
<0.21 µg/L 0.210 0.500Xylene (Total)1 07/15/22 00:52 V21339
Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%07/15/22 00:521 JLB V21339
Surrogate: Dibromofluoromethane 96.6 Limits: 70-130%07/15/22 00:521 JLB V21339
Surrogate: 1,2-Dichloroethane - d4 96.6 Limits: 70-130%07/15/22 00:521 JLB V21339
Surrogate: Toluene-d8 98.6 Limits: 70-130%07/15/22 00:521 JLB V21339
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V21203 07/12/22 14:40
<14.2 µg/L 14.2 20.0
Acenaphthene 1 07/13/22 22:48 V21263JMV
<13.9 µg/L 13.9 40.0Acenaphthylene 1 07/13/22 22:48 V21263JMV
<13.1 µg/L 13.1 20.0Anthracene 1 07/13/22 22:48 V21263JMV
<10.2 µg/L 10.2 20.0Benzidine 1 07/13/22 22:48 V21263JMV
<13.3 µg/L 13.3 20.0Benzo(a)anthracene 1 07/13/22 22:48 V21263JMV
<9.34 µg/L 9.34 20.0Benzo(a)pyrene 1 07/13/22 22:48 V21263JMV
<9.04 µg/L 9.04 20.0Benzo(b)fluoranthene 1 07/13/22 22:48 V21263JMV
<8.48 µg/L 8.48 20.0
Benzo(g,h,i)perylene 1 07/13/22 22:48 V21263JMV
<9.72 µg/L 9.72 20.0Benzo(k)fluoranthene 1 07/13/22 22:48 V21263JMV
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 23 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-2
93945 Matrix:
7/7/2022 9:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V21203 07/12/22 14:40
<23.0 M µg/L 23.0 100Benzoic Acid 1 07/13/22 22:48 V21263JMV
<17.2 µg/L 17.2 20.0Benzyl alcohol 1 07/13/22 22:48 V21263JMV
<11.3 µg/L 11.3 20.0Bis(2-Chloroethoxy)methane 1 07/13/22 22:48 V21263JMV
<14.6 µg/L 14.6 20.0Bis(2-Chloroethyl)ether 1 07/13/22 22:48 V21263JMV
<13.2 µg/L 13.2 20.0Bis(2-Chloroisopropyl)ether 1 07/13/22 22:48 V21263JMV
<17.6 µg/L 17.6 20.0Bis(2-ethylhexyl)phthalate 1 07/13/22 22:48 V21263JMV
<12.5 µg/L 12.5 40.04-Bromophenyl phenyl ether 1 07/13/22 22:48 V21263JMV
<9.06 µg/L 9.06 20.0Butyl benzyl phthalate 1 07/13/22 22:48 V21263JMV
<10.5 µg/L 10.5 20.0
4-Chloro-3-methylphenol 1 07/13/22 22:48 V21263JMV
<14.8 M µg/L 14.8 40.02-Chloronaphthalene 1 07/13/22 22:48 V21263JMV
<13.2 µg/L 13.2 20.02-Chlorophenol 1 07/13/22 22:48 V21263JMV
<14.0 µg/L 14.0 40.04-Chlorophenyl phenyl ether 1 07/13/22 22:48 V21263JMV
<10.8 µg/L 10.8 20.0Chrysene 1 07/13/22 22:48 V21263JMV
<12.0 µg/L 12.0 40.0Dibenz(a,h)anthracene 1 07/13/22 22:48 V21263JMV
<10.2 µg/L 10.2 40.0Dibenzofuran 1 07/13/22 22:48 V21263JMV
<11.8 µg/L 11.8 20.0
1,2-Dichlorobenzene 1 07/13/22 22:48 V21263JMV
<11.7 µg/L 11.7 20.01,3-Dichlorobenzene 1 07/13/22 22:48 V21263JMV
<11.8 µg/L 11.8 20.01,4-Dichlorobenzene 1 07/13/22 22:48 V21263JMV
<13.2 µg/L 13.2 20.03,3'-Dichlorobenzidine 1 07/13/22 22:48 V21263JMV
<11.1 µg/L 11.1 20.02,4-Dichlorophenol 1 07/13/22 22:48 V21263JMV
<18.7 µg/L 18.7 40.0Diethyl phthalate 1 07/13/22 22:48 V21263JMV
<15.6 µg/L 15.6 20.0Dimethyl phthalate 1 07/13/22 22:48 V21263JMV
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 24 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-2
93945 Matrix:
7/7/2022 9:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V21203 07/12/22 14:40
<21.9 µg/L 21.9 40.02,4-Dimethylphenol 1 07/13/22 22:48 V21263JMV
<14.7 µg/L 14.7 20.0Di-n-butyl phthalate 1 07/13/22 22:48 V21263JMV
<19.8 µg/L 19.8 60.04,6-Dinitro-2-methylphenol 1 07/13/22 22:48 V21263JMV
<21.3 µg/L 21.3 60.02,4-Dinitrophenol 1 07/13/22 22:48 V21263JMV
<10.4 µg/L 10.4 20.02,4-Dinitrotoluene 1 07/13/22 22:48 V21263JMV
<11.8 µg/L 11.8 40.02,6-Dinitrotoluene 1 07/13/22 22:48 V21263JMV
<10.0 µg/L 10.0 20.0Di-n-Octyl Phthalate 1 07/13/22 22:48 V21263JMV
<12.1 µg/L 12.1 20.0Fluoranthene 1 07/13/22 22:48 V21263JMV
<14.5 M
µg/L 14.5 20.0
Fluorene 1 07/13/22 22:48 V21263JMV
<11.5 µg/L 11.5 40.0Hexachlorobenzene 1 07/13/22 22:48 V21263JMV
<11.8 µg/L 11.8 40.0Hexachlorobutadiene 1 07/13/22 22:48 V21263JMV
<11.8 M µg/L 11.8 40.0Hexachlorocyclopentadiene 1 07/13/22 22:48 V21263JMV
<10.4 M µg/L 10.4 20.0Hexachloroethane 1 07/13/22 22:48 V21263JMV
<12.4 µg/L 12.4 20.0Indeno(1,2,3-cd)pyrene 1 07/13/22 22:48 V21263JMV
<13.4 µg/L 13.4 20.0Isophorone 1 07/13/22 22:48 V21263JMV
<15.8 µg/L 15.8 20.0
Naphthalene 1 07/13/22 22:48 V21263JMV
<15.8 µg/L 15.8 20.0Nitrobenzene 1 07/13/22 22:48 V21263JMV
<11.0 µg/L 11.0 20.02-Nitrophenol 1 07/13/22 22:48 V21263JMV
<5.62 µg/L 5.62 20.04-Nitrophenol 1 07/13/22 22:48 V21263JMV
<21.9 M µg/L 21.9 40.0N-Nitrosodiphenylamine 1 07/13/22 22:48 V21263JMV
<16.2 µg/L 16.2 40.0N-Nitroso-di-n-propylamine 1 07/13/22 22:48 V21263JMV
<19.5 µg/L 19.5 100Pentachlorophenol 1 07/13/22 22:48 V21263JMV
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 25 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-2
93945 Matrix:
7/7/2022 9:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V21203 07/12/22 14:40
<12.7 µg/L 12.7 20.0Phenanthrene 1 07/13/22 22:48 V21263JMV
<5.72 µg/L 5.72 20.0Phenol 1 07/13/22 22:48 V21263JMV
<10.8 µg/L 10.8 20.0Pyrene 1 07/13/22 22:48 V21263JMV
<12.5 M µg/L 12.5 20.01,2,4-Trichlorobenzene 1 07/13/22 22:48 V21263JMV
<12.6 µg/L 12.6 40.02,4,6-Trichlorophenol 1 07/13/22 22:48 V21263JMV
625.1Surrogate: Phenol-d5 1.89 *Limits: 10-63%07/13/22 22:481 JMV
Surrogate: 2-Fluorobiphenyl 6.85 *Limits: 49-118%07/13/22 22:481 JMV V21263
Surrogate: 2-Fluorophenol 2.21 *Limits: 22-84%07/13/22 22:481 JMV V21263
Surrogate: Nitrobenzene-d5 5.71 *Limits: 43-123%07/13/22 22:481 JMV V21263
Surrogate: 4-Terphenyl-d14 6.70 *Limits: 49-151%07/13/22 22:481 JMV V21263
Surrogate: 2,4,6-Tribromophenol 2.06 *Limits: 31-144%07/13/22 22:481 JMV V21263
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):V21593 07/20/22 16:30
<0.00343 µg/L 0.00343 0.02081,2-Dibromoethane 1 07/20/22 23:44 V21719JC1
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 26 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-2
93945 Matrix:
7/7/2022 9:50
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 07/12/22 18:08
<25.8 µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 07/12/22 18:08
<4.02 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 07/12/22 18:08
<111 M µg/L 111 455Aromatic C11-C22 (Adjusted)1 07/13/22 22:48
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V21273 07/14/22 09:16
88.9 JB µg/L 51.2 636Aliphatic C9-C18 1 07/22/22 08:55 V21698JLK
<225 µg/L 225 909Aliphatic C19-C36 1 07/22/22 08:55 V21698JLK
<111 µg/L 111 455Aromatic C11-C22 1 07/22/22 08:55 V21698JLK
MADEP-EPHSurrogate: 2-Bromonaphthalene 72.6 Limits: 40-140%07/22/22 08:551 JLK
MADEP-EPHSurrogate: Chlorooctadecane 3.87 *Limits: 40-140%07/22/22 08:551 JLK
MADEP-EPHSurrogate: OTP Surrogate 10.3 *Limits: 40-140%07/22/22 08:551 JLK
Surrogate: 2-Fluorobiphenyl 73.5 Limits: 40-140%07/22/22 08:551 JLK V21698
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V21177 07/12/22 08:00
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 1 07/12/22 18:08 V21178TBL
<25.8 µg/L 25.8 50.0Aliphatic C9-C12 1 07/12/22 18:08 V21178TBL
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 27 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-2
93945 Matrix:
7/7/2022 9:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V21177 07/12/22 08:00
<4.02 µg/L 4.02 50.0Aromatic C9-C10 1 07/12/22 18:08 V21178TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)88.9 Limits: 70-130%07/12/22 18:081 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)79.3 Limits: 70-130%07/12/22 18:081 TBL
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 28 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-3
93946 Matrix:
7/7/2022 10:05
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 07/15/22 01:30 6200BJLB
0.043 mg/L 0.002 0.006Lead 1 07/12/22 17:29 6010DEDV
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 29 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-3
93946 Matrix:
7/7/2022 10:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21337 07/14/22 09:00
2.96 J µg/L 1.80 10.0Acetone 1 07/15/22 01:30 V21339JLB
<0.180 µg/L 0.180 0.500Benzene 1 07/15/22 01:30 V21339JLB
<0.210 µg/L 0.210 0.500Bromobenzene 1 07/15/22 01:30 V21339JLB
<0.420 µg/L 0.420 1.00Bromochloromethane 1 07/15/22 01:30 V21339JLB
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 07/15/22 01:30 V21339JLB
<1.50 µg/L 1.50 5.00Bromoform 1 07/15/22 01:30 V21339JLB
<0.280 µg/L 0.280 1.00Bromomethane 1 07/15/22 01:30 V21339JLB
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 07/15/22 01:30 V21339JLB
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 07/15/22 01:30 V21339JLB
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 07/15/22 01:30 V21339JLB
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 07/15/22 01:30 V21339JLB
<0.190 µg/L 0.190 0.500Chlorobenzene 1 07/15/22 01:30 V21339JLB
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 07/15/22 01:30 V21339JLB
<0.430 µg/L 0.430 1.00Chloroethane 1 07/15/22 01:30 V21339JLB
<0.220 µg/L 0.220 0.500Chloroform 1 07/15/22 01:30 V21339JLB
<0.220 µg/L 0.220 0.500
Chloromethane 1 07/15/22 01:30 V21339JLB
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 07/15/22 01:30 V21339JLB
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 07/15/22 01:30 V21339JLB
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 07/15/22 01:30 V21339JLB
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 07/15/22 01:30 V21339JLB
<0.230 µg/L 0.230 0.500Dibromomethane 1 07/15/22 01:30 V21339JLB
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 07/15/22 01:30 V21339JLB
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 30 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-3
93946 Matrix:
7/7/2022 10:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21337 07/14/22 09:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 07/15/22 01:30 V21339JLB
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 07/15/22 01:30 V21339JLB
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 07/15/22 01:30 V21339JLB
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 07/15/22 01:30 V21339JLB
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 07/15/22 01:30 V21339JLB
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 07/15/22 01:30 V21339JLB
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 07/15/22 01:30 V21339JLB
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 07/15/22 01:30 V21339JLB
<0.190 µg/L 0.190 0.500
1,2-Dichloropropane 1 07/15/22 01:30 V21339JLB
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 07/15/22 01:30 V21339JLB
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 07/15/22 01:30 V21339JLB
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 07/15/22 01:30 V21339JLB
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 07/15/22 01:30 V21339JLB
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 07/15/22 01:30 V21339JLB
<42.0 µg/L 42.0 200Ethanol 1 07/15/22 01:30 V21339JLB
<0.170 µg/L 0.170 0.500
Ethylbenzene 1 07/15/22 01:30 V21339JLB
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 07/15/22 01:30 V21339JLB
<0.380 µg/L 0.380 1.002-Hexanone 1 07/15/22 01:30 V21339JLB
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 07/15/22 01:30 V21339JLB
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 07/15/22 01:30 V21339JLB
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 07/15/22 01:30 V21339JLB
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 07/15/22 01:30 V21339JLB
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 31 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-3
93946 Matrix:
7/7/2022 10:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21337 07/14/22 09:00
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 07/15/22 01:30 V21339JLB
<0.330 µg/L 0.330 2.00Methylene Chloride 1 07/15/22 01:30 V21339JLB
<0.470 µg/L 0.470 1.00Naphthalene 1 07/15/22 01:30 V21339JLB
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 07/15/22 01:30 V21339JLB
<0.220 µg/L 0.220 0.500Styrene 1 07/15/22 01:30 V21339JLB
<1.60 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 07/15/22 01:30 V21339JLB
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 07/15/22 01:30 V21339JLB
<1.90 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 07/15/22 01:30 V21339JLB
<0.280 µg/L 0.280 10.0
tert-Amyl Methyl Ether (TAME)1 07/15/22 01:30 V21339JLB
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 07/15/22 01:30 V21339JLB
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 07/15/22 01:30 V21339JLB
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 07/15/22 01:30 V21339JLB
<0.220 µg/L 0.220 0.500Toluene 1 07/15/22 01:30 V21339JLB
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 07/15/22 01:30 V21339JLB
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 07/15/22 01:30 V21339JLB
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 07/15/22 01:30 V21339JLB
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 07/15/22 01:30 V21339JLB
<0.180 µg/L 0.180 0.500Trichloroethene 1 07/15/22 01:30 V21339JLB
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 07/15/22 01:30 V21339JLB
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 07/15/22 01:30 V21339JLB
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 07/15/22 01:30 V21339JLB
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 07/15/22 01:30 V21339JLB
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 32 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-3
93946 Matrix:
7/7/2022 10:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21337 07/14/22 09:00
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 07/15/22 01:30 V21339JLB
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 07/15/22 01:30 V21339JLB
<0.210 µg/L 0.210 0.500o-Xylene 1 07/15/22 01:30 V21339JLB
<0.420 µg/L 0.420 1.00m,p-Xylene 1 07/15/22 01:30 V21339JLB
<0.21 µg/L 0.210 0.500Xylene (Total)1 07/15/22 01:30 V21339
Surrogate: 4-Bromofluorobenzene 99.0 Limits: 70-130%07/15/22 01:301 JLB V21339
Surrogate: Dibromofluoromethane 95.8 Limits: 70-130%07/15/22 01:301 JLB V21339
Surrogate: 1,2-Dichloroethane - d4 96.4 Limits: 70-130%07/15/22 01:301 JLB V21339
Surrogate: Toluene-d8 99.2 Limits: 70-130%07/15/22 01:301 JLB V21339
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V21203 07/12/22 14:40
<10.2 µg/L 10.2 14.3
Acenaphthene 1 07/13/22 23:11 V21263JMV
<9.92 µg/L 9.92 28.6Acenaphthylene 1 07/13/22 23:11 V21263JMV
<9.40 µg/L 9.40 14.3Anthracene 1 07/13/22 23:11 V21263JMV
<7.26 µg/L 7.26 14.3Benzidine 1 07/13/22 23:11 V21263JMV
<9.51 µg/L 9.51 14.3Benzo(a)anthracene 1 07/13/22 23:11 V21263JMV
<6.68 µg/L 6.68 14.3Benzo(a)pyrene 1 07/13/22 23:11 V21263JMV
<6.46 µg/L 6.46 14.3Benzo(b)fluoranthene 1 07/13/22 23:11 V21263JMV
<6.06 µg/L 6.06 14.3
Benzo(g,h,i)perylene 1 07/13/22 23:11 V21263JMV
<6.95 µg/L 6.95 14.3Benzo(k)fluoranthene 1 07/13/22 23:11 V21263JMV
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 33 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-3
93946 Matrix:
7/7/2022 10:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V21203 07/12/22 14:40
<16.4 M µg/L 16.4 71.4Benzoic Acid 1 07/13/22 23:11 V21263JMV
<12.3 µg/L 12.3 14.3Benzyl alcohol 1 07/13/22 23:11 V21263JMV
<8.11 µg/L 8.11 14.3Bis(2-Chloroethoxy)methane 1 07/13/22 23:11 V21263JMV
<10.4 µg/L 10.4 14.3Bis(2-Chloroethyl)ether 1 07/13/22 23:11 V21263JMV
<9.42 µg/L 9.42 14.3Bis(2-Chloroisopropyl)ether 1 07/13/22 23:11 V21263JMV
<12.6 µg/L 12.6 14.3Bis(2-ethylhexyl)phthalate 1 07/13/22 23:11 V21263JMV
<8.95 µg/L 8.95 28.64-Bromophenyl phenyl ether 1 07/13/22 23:11 V21263JMV
<6.48 µg/L 6.48 14.3Butyl benzyl phthalate 1 07/13/22 23:11 V21263JMV
<7.48 µg/L 7.48 14.3
4-Chloro-3-methylphenol 1 07/13/22 23:11 V21263JMV
<10.6 M µg/L 10.6 28.62-Chloronaphthalene 1 07/13/22 23:11 V21263JMV
<9.41 µg/L 9.41 14.32-Chlorophenol 1 07/13/22 23:11 V21263JMV
<10.0 µg/L 10.0 28.64-Chlorophenyl phenyl ether 1 07/13/22 23:11 V21263JMV
<7.69 µg/L 7.69 14.3Chrysene 1 07/13/22 23:11 V21263JMV
<8.59 µg/L 8.59 28.6Dibenz(a,h)anthracene 1 07/13/22 23:11 V21263JMV
<7.26 µg/L 7.26 28.6Dibenzofuran 1 07/13/22 23:11 V21263JMV
<8.45 µg/L 8.45 14.3
1,2-Dichlorobenzene 1 07/13/22 23:11 V21263JMV
<8.34 µg/L 8.34 14.31,3-Dichlorobenzene 1 07/13/22 23:11 V21263JMV
<8.45 µg/L 8.45 14.31,4-Dichlorobenzene 1 07/13/22 23:11 V21263JMV
<9.44 µg/L 9.44 14.33,3'-Dichlorobenzidine 1 07/13/22 23:11 V21263JMV
<7.92 µg/L 7.92 14.32,4-Dichlorophenol 1 07/13/22 23:11 V21263JMV
<13.4 µg/L 13.4 28.6Diethyl phthalate 1 07/13/22 23:11 V21263JMV
<11.2 µg/L 11.2 14.3Dimethyl phthalate 1 07/13/22 23:11 V21263JMV
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 34 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-3
93946 Matrix:
7/7/2022 10:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V21203 07/12/22 14:40
<15.6 µg/L 15.6 28.62,4-Dimethylphenol 1 07/13/22 23:11 V21263JMV
<10.5 µg/L 10.5 14.3Di-n-butyl phthalate 1 07/13/22 23:11 V21263JMV
<14.2 µg/L 14.2 42.94,6-Dinitro-2-methylphenol 1 07/13/22 23:11 V21263JMV
<15.2 µg/L 15.2 42.92,4-Dinitrophenol 1 07/13/22 23:11 V21263JMV
<7.44 µg/L 7.44 14.32,4-Dinitrotoluene 1 07/13/22 23:11 V21263JMV
<8.44 µg/L 8.44 28.62,6-Dinitrotoluene 1 07/13/22 23:11 V21263JMV
<7.16 µg/L 7.16 14.3Di-n-Octyl Phthalate 1 07/13/22 23:11 V21263JMV
<8.62 µg/L 8.62 14.3Fluoranthene 1 07/13/22 23:11 V21263JMV
<10.4 M
µg/L 10.4 14.3
Fluorene 1 07/13/22 23:11 V21263JMV
<8.22 µg/L 8.22 28.6Hexachlorobenzene 1 07/13/22 23:11 V21263JMV
<8.41 µg/L 8.41 28.6Hexachlorobutadiene 1 07/13/22 23:11 V21263JMV
<8.44 M µg/L 8.44 28.6Hexachlorocyclopentadiene 1 07/13/22 23:11 V21263JMV
<7.46 M µg/L 7.46 14.3Hexachloroethane 1 07/13/22 23:11 V21263JMV
<8.87 µg/L 8.87 14.3Indeno(1,2,3-cd)pyrene 1 07/13/22 23:11 V21263JMV
<9.60 µg/L 9.60 14.3Isophorone 1 07/13/22 23:11 V21263JMV
<11.3 µg/L 11.3 14.3
Naphthalene 1 07/13/22 23:11 V21263JMV
<11.3 µg/L 11.3 14.3Nitrobenzene 1 07/13/22 23:11 V21263JMV
<7.85 µg/L 7.85 14.32-Nitrophenol 1 07/13/22 23:11 V21263JMV
<4.02 µg/L 4.02 14.34-Nitrophenol 1 07/13/22 23:11 V21263JMV
<15.6 M µg/L 15.6 28.6N-Nitrosodiphenylamine 1 07/13/22 23:11 V21263JMV
<11.6 µg/L 11.6 28.6N-Nitroso-di-n-propylamine 1 07/13/22 23:11 V21263JMV
<13.9 µg/L 13.9 71.4Pentachlorophenol 1 07/13/22 23:11 V21263JMV
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 35 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-3
93946 Matrix:
7/7/2022 10:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V21203 07/12/22 14:40
<9.07 µg/L 9.07 14.3Phenanthrene 1 07/13/22 23:11 V21263JMV
<4.09 µg/L 4.09 14.3Phenol 1 07/13/22 23:11 V21263JMV
<7.75 µg/L 7.75 14.3Pyrene 1 07/13/22 23:11 V21263JMV
<8.94 M µg/L 8.94 14.31,2,4-Trichlorobenzene 1 07/13/22 23:11 V21263JMV
<8.99 µg/L 8.99 28.62,4,6-Trichlorophenol 1 07/13/22 23:11 V21263JMV
625.1Surrogate: Phenol-d5 33.1 Limits: 10-63%07/13/22 23:111 JMV
Surrogate: 2-Fluorobiphenyl 71.1 Limits: 49-118%07/13/22 23:111 JMV V21263
Surrogate: 2-Fluorophenol 46.6 Limits: 22-84%07/13/22 23:111 JMV V21263
Surrogate: Nitrobenzene-d5 65.3 Limits: 43-123%07/13/22 23:111 JMV V21263
Surrogate: 4-Terphenyl-d14 75.5 Limits: 49-151%07/13/22 23:111 JMV V21263
Surrogate: 2,4,6-Tribromophenol 76.9 Limits: 31-144%07/13/22 23:111 JMV V21263
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):V21593 07/20/22 16:30
<0.00345 µg/L 0.00345 0.02091,2-Dibromoethane 1 07/21/22 00:02 V21719JC1
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 36 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-3
93946 Matrix:
7/7/2022 10:05
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 07/12/22 18:31
<25.8 µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 07/12/22 18:31
<4.02 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 07/12/22 18:31
<82.7 M µg/L 82.7 338Aromatic C11-C22 (Adjusted)1 07/13/22 23:11
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V21273 07/14/22 09:16
49.0 JB µg/L 38.1 473Aliphatic C9-C18 1 07/22/22 09:31 V21698JLK
<168 µg/L 168 676Aliphatic C19-C36 1 07/22/22 09:31 V21698JLK
<82.7 µg/L 82.7 338Aromatic C11-C22 1 07/22/22 09:31 V21698JLK
MADEP-EPHSurrogate: 2-Bromonaphthalene 75.4 Limits: 40-140%07/22/22 09:311 JLK
MADEP-EPHSurrogate: Chlorooctadecane 41.5 Limits: 40-140%07/22/22 09:311 JLK
MADEP-EPHSurrogate: OTP Surrogate 53.3 Limits: 40-140%07/22/22 09:311 JLK
Surrogate: 2-Fluorobiphenyl 71.5 Limits: 40-140%07/22/22 09:311 JLK V21698
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V21177 07/12/22 08:00
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 1 07/12/22 18:31 V21178TBL
<25.8 µg/L 25.8 50.0Aliphatic C9-C12 1 07/12/22 18:31 V21178TBL
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 37 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-3
93946 Matrix:
7/7/2022 10:05
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V21177 07/12/22 08:00
<4.02 µg/L 4.02 50.0Aromatic C9-C10 1 07/12/22 18:31 V21178TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)79.8 Limits: 70-130%07/12/22 18:311 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)77.5 Limits: 70-130%07/12/22 18:311 TBL
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 38 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-4
93947 Matrix:
7/7/2022 9:20
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 07/15/22 18:52 6200BJLB
0.137 mg/L 0.002 0.006Lead 1 07/12/22 17:33 6010DEDV
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 39 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-4
93947 Matrix:
7/7/2022 9:20
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21408 07/15/22 09:00
<1.80 µg/L 1.80 10.0Acetone 1 07/15/22 18:52 V21409JLB
1.34 µg/L 0.180 0.500Benzene 1 07/15/22 18:52 V21409JLB
<0.210 µg/L 0.210 0.500Bromobenzene 1 07/15/22 18:52 V21409JLB
<0.420 µg/L 0.420 1.00Bromochloromethane 1 07/15/22 18:52 V21409JLB
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 07/15/22 18:52 V21409JLB
<1.50 µg/L 1.50 5.00Bromoform 1 07/15/22 18:52 V21409JLB
<0.280 µg/L 0.280 1.00Bromomethane 1 07/15/22 18:52 V21409JLB
18.9 µg/L 0.180 0.500n-Butylbenzene 1 07/15/22 18:52 V21409JLB
11.0 µg/L 0.200 0.500
sec-Butyl benzene 1 07/15/22 18:52 V21409JLB
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 07/15/22 18:52 V21409JLB
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 07/15/22 18:52 V21409JLB
<0.190 µg/L 0.190 0.500Chlorobenzene 1 07/15/22 18:52 V21409JLB
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 07/15/22 18:52 V21409JLB
<0.430 µg/L 0.430 1.00Chloroethane 1 07/15/22 18:52 V21409JLB
<0.220 µg/L 0.220 0.500Chloroform 1 07/15/22 18:52 V21409JLB
<0.220 µg/L 0.220 0.500
Chloromethane 1 07/15/22 18:52 V21409JLB
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 07/15/22 18:52 V21409JLB
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 07/15/22 18:52 V21409JLB
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 07/15/22 18:52 V21409JLB
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 07/15/22 18:52 V21409JLB
<0.230 µg/L 0.230 0.500Dibromomethane 1 07/15/22 18:52 V21409JLB
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 07/15/22 18:52 V21409JLB
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 40 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-4
93947 Matrix:
7/7/2022 9:20
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21408 07/15/22 09:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 07/15/22 18:52 V21409JLB
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 07/15/22 18:52 V21409JLB
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 07/15/22 18:52 V21409JLB
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 07/15/22 18:52 V21409JLB
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 07/15/22 18:52 V21409JLB
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 07/15/22 18:52 V21409JLB
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 07/15/22 18:52 V21409JLB
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 07/15/22 18:52 V21409JLB
<0.190 µg/L 0.190 0.500
1,2-Dichloropropane 1 07/15/22 18:52 V21409JLB
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 07/15/22 18:52 V21409JLB
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 07/15/22 18:52 V21409JLB
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 07/15/22 18:52 V21409JLB
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 07/15/22 18:52 V21409JLB
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 07/15/22 18:52 V21409JLB
<42.0 µg/L 42.0 200Ethanol 1 07/15/22 18:52 V21409JLB
73.2 µg/L 0.170 0.500
Ethylbenzene 1 07/15/22 18:52 V21409JLB
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 07/15/22 18:52 V21409JLB
8.50 µg/L 0.380 1.002-Hexanone 1 07/15/22 18:52 V21409JLB
22.2 µg/L 0.180 0.500Isopropylbenzene 1 07/15/22 18:52 V21409JLB
9.21 µg/L 0.089 0.5004-Isopropyl toluene 1 07/15/22 18:52 V21409JLB
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 07/15/22 18:52 V21409JLB
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 07/15/22 18:52 V21409JLB
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 41 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-4
93947 Matrix:
7/7/2022 9:20
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21408 07/15/22 09:00
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 07/15/22 18:52 V21409JLB
<0.330 µg/L 0.330 2.00Methylene Chloride 1 07/15/22 18:52 V21409JLB
86.0 µg/L 0.470 1.00Naphthalene 1 07/15/22 18:52 V21409JLB
62.2 µg/L 0.190 0.500n-Propylbenzene 1 07/15/22 18:52 V21409JLB
<0.220 µg/L 0.220 0.500Styrene 1 07/15/22 18:52 V21409JLB
<1.60 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 07/15/22 18:52 V21409JLB
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 07/15/22 18:52 V21409JLB
<1.90 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 07/15/22 18:52 V21409JLB
<0.280 µg/L 0.280 10.0
tert-Amyl Methyl Ether (TAME)1 07/15/22 18:52 V21409JLB
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 07/15/22 18:52 V21409JLB
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 07/15/22 18:52 V21409JLB
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 07/15/22 18:52 V21409JLB
0.693 µg/L 0.220 0.500Toluene 1 07/15/22 18:52 V21409JLB
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 07/15/22 18:52 V21409JLB
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 07/15/22 18:52 V21409JLB
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 07/15/22 18:52 V21409JLB
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 07/15/22 18:52 V21409JLB
<0.180 µg/L 0.180 0.500Trichloroethene 1 07/15/22 18:52 V21409JLB
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 07/15/22 18:52 V21409JLB
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 07/15/22 18:52 V21409JLB
774 µg/L 1.90 5.001,2,4-Trimethylbenzene 10 07/15/22 19:31 V21409JLB
149 µg/L 1.80 5.001,3,5-Trimethylbenzene 10 07/15/22 19:31 V21409JLB
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 42 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-4
93947 Matrix:
7/7/2022 9:20
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21408 07/15/22 09:00
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 07/15/22 18:52 V21409JLB
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 07/15/22 18:52 V21409JLB
3.63 µg/L 0.210 0.500o-Xylene 1 07/15/22 18:52 V21409JLB
170 µg/L 0.420 1.00m,p-Xylene 1 07/15/22 18:52 V21409JLB
174 µg/L 0.210 0.500Xylene (Total)1 07/15/22 18:52 V21409KCC
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%07/15/22 18:521 JLB V21409
Surrogate: Dibromofluoromethane 96.4 Limits: 70-130%07/15/22 18:521 JLB V21409
Surrogate: 1,2-Dichloroethane - d4 102 Limits: 70-130%07/15/22 18:521 JLB V21409
Surrogate: Toluene-d8 101 Limits: 70-130%07/15/22 18:521 JLB V21409
Surrogate: 4-Bromofluorobenzene 99.0 Limits: 70-130%07/15/22 19:3110 JLB V21409
Surrogate: Dibromofluoromethane 94.4 Limits: 70-130%07/15/22 19:3110 JLB V21409
Surrogate: 1,2-Dichloroethane - d4 97.8 Limits: 70-130%07/15/22 19:3110 JLB V21409
Surrogate: Toluene-d8 99.6 Limits: 70-130%07/15/22 19:3110 JLB V21409
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V21203 07/12/22 14:40
<9.18 µg/L 9.18 12.9
Acenaphthene 1 07/13/22 22:04 V21263JMV
<8.95 µg/L 8.95 25.8Acenaphthylene 1 07/13/22 22:04 V21263JMV
<8.48 µg/L 8.48 12.9Anthracene 1 07/13/22 22:04 V21263JMV
<6.55 µg/L 6.55 12.9Benzidine 1 07/13/22 22:04 V21263JMV
<8.58 µg/L 8.58 12.9Benzo(a)anthracene 1 07/13/22 22:04 V21263JMV
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 43 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-4
93947 Matrix:
7/7/2022 9:20
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V21203 07/12/22 14:40
<6.02 µg/L 6.02 12.9Benzo(a)pyrene 1 07/13/22 22:04 V21263JMV
<5.83 µg/L 5.83 12.9Benzo(b)fluoranthene 1 07/13/22 22:04 V21263JMV
<5.47 µg/L 5.47 12.9Benzo(g,h,i)perylene 1 07/13/22 22:04 V21263JMV
<6.27 µg/L 6.27 12.9Benzo(k)fluoranthene 1 07/13/22 22:04 V21263JMV
<14.8 M µg/L 14.8 64.5Benzoic Acid 1 07/13/22 22:04 V21263JMV
<11.1 µg/L 11.1 12.9Benzyl alcohol 1 07/13/22 22:04 V21263JMV
<7.31 µg/L 7.31 12.9Bis(2-Chloroethoxy)methane 1 07/13/22 22:04 V21263JMV
<9.42 µg/L 9.42 12.9Bis(2-Chloroethyl)ether 1 07/13/22 22:04 V21263JMV
<8.50 µg/L 8.50 12.9
Bis(2-Chloroisopropyl)ether 1 07/13/22 22:04 V21263JMV
<11.4 µg/L 11.4 12.9Bis(2-ethylhexyl)phthalate 1 07/13/22 22:04 V21263JMV
<8.08 µg/L 8.08 25.84-Bromophenyl phenyl ether 1 07/13/22 22:04 V21263JMV
<5.84 µg/L 5.84 12.9Butyl benzyl phthalate 1 07/13/22 22:04 V21263JMV
<6.75 µg/L 6.75 12.94-Chloro-3-methylphenol 1 07/13/22 22:04 V21263JMV
<9.52 M µg/L 9.52 25.82-Chloronaphthalene 1 07/13/22 22:04 V21263JMV
<8.49 µg/L 8.49 12.92-Chlorophenol 1 07/13/22 22:04 V21263JMV
<9.02 µg/L 9.02 25.8
4-Chlorophenyl phenyl ether 1 07/13/22 22:04 V21263JMV
<6.94 µg/L 6.94 12.9Chrysene 1 07/13/22 22:04 V21263JMV
<7.75 µg/L 7.75 25.8Dibenz(a,h)anthracene 1 07/13/22 22:04 V21263JMV
<6.55 µg/L 6.55 25.8Dibenzofuran 1 07/13/22 22:04 V21263JMV
<7.62 µg/L 7.62 12.91,2-Dichlorobenzene 1 07/13/22 22:04 V21263JMV
<7.52 µg/L 7.52 12.91,3-Dichlorobenzene 1 07/13/22 22:04 V21263JMV
<7.62 µg/L 7.62 12.91,4-Dichlorobenzene 1 07/13/22 22:04 V21263JMV
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 44 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-4
93947 Matrix:
7/7/2022 9:20
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V21203 07/12/22 14:40
<8.51 µg/L 8.51 12.93,3'-Dichlorobenzidine 1 07/13/22 22:04 V21263JMV
<7.15 µg/L 7.15 12.92,4-Dichlorophenol 1 07/13/22 22:04 V21263JMV
<12.1 µg/L 12.1 25.8Diethyl phthalate 1 07/13/22 22:04 V21263JMV
<10.1 µg/L 10.1 12.9Dimethyl phthalate 1 07/13/22 22:04 V21263JMV
<14.1 µg/L 14.1 25.82,4-Dimethylphenol 1 07/13/22 22:04 V21263JMV
<9.48 µg/L 9.48 12.9Di-n-butyl phthalate 1 07/13/22 22:04 V21263JMV
<12.8 µg/L 12.8 38.74,6-Dinitro-2-methylphenol 1 07/13/22 22:04 V21263JMV
<13.7 µg/L 13.7 38.72,4-Dinitrophenol 1 07/13/22 22:04 V21263JMV
<6.71 µg/L 6.71 12.9
2,4-Dinitrotoluene 1 07/13/22 22:04 V21263JMV
<7.61 µg/L 7.61 25.82,6-Dinitrotoluene 1 07/13/22 22:04 V21263JMV
<6.46 µg/L 6.46 12.9Di-n-Octyl Phthalate 1 07/13/22 22:04 V21263JMV
<7.78 µg/L 7.78 12.9Fluoranthene 1 07/13/22 22:04 V21263JMV
<9.38 M µg/L 9.38 12.9Fluorene 1 07/13/22 22:04 V21263JMV
<7.42 µg/L 7.42 25.8Hexachlorobenzene 1 07/13/22 22:04 V21263JMV
<7.59 µg/L 7.59 25.8Hexachlorobutadiene 1 07/13/22 22:04 V21263JMV
<7.61 M
µg/L 7.61 25.8
Hexachlorocyclopentadiene 1 07/13/22 22:04 V21263JMV
<6.73 M µg/L 6.73 12.9Hexachloroethane 1 07/13/22 22:04 V21263JMV
<8.00 µg/L 8.00 12.9Indeno(1,2,3-cd)pyrene 1 07/13/22 22:04 V21263JMV
<8.66 µg/L 8.66 12.9Isophorone 1 07/13/22 22:04 V21263JMV
14.0 µg/L 10.2 12.9Naphthalene 1 07/13/22 22:04 V21263JMV
<10.2 µg/L 10.2 12.9Nitrobenzene 1 07/13/22 22:04 V21263JMV
<7.08 µg/L 7.08 12.92-Nitrophenol 1 07/13/22 22:04 V21263JMV
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 45 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-4
93947 Matrix:
7/7/2022 9:20
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V21203 07/12/22 14:40
<3.62 µg/L 3.62 12.94-Nitrophenol 1 07/13/22 22:04 V21263JMV
<14.1 M µg/L 14.1 25.8N-Nitrosodiphenylamine 1 07/13/22 22:04 V21263JMV
<10.4 µg/L 10.4 25.8N-Nitroso-di-n-propylamine 1 07/13/22 22:04 V21263JMV
<12.6 µg/L 12.6 64.5Pentachlorophenol 1 07/13/22 22:04 V21263JMV
<8.18 µg/L 8.18 12.9Phenanthrene 1 07/13/22 22:04 V21263JMV
<3.69 µg/L 3.69 12.9Phenol 1 07/13/22 22:04 V21263JMV
<6.99 µg/L 6.99 12.9Pyrene 1 07/13/22 22:04 V21263JMV
<8.06 M µg/L 8.06 12.91,2,4-Trichlorobenzene 1 07/13/22 22:04 V21263JMV
<8.11 µg/L 8.11 25.8
2,4,6-Trichlorophenol 1 07/13/22 22:04 V21263JMV
625.1Surrogate: Phenol-d5 17.3 Limits: 10-63%07/13/22 22:041 JMV
Surrogate: 2-Fluorobiphenyl 29.8 *Limits: 49-118%07/13/22 22:041 JMV V21263
Surrogate: 2-Fluorophenol 24.9 Limits: 22-84%07/13/22 22:041 JMV V21263
Surrogate: Nitrobenzene-d5 27.1 *Limits: 43-123%07/13/22 22:041 JMV V21263
Surrogate: 4-Terphenyl-d14 34.0 *Limits: 49-151%07/13/22 22:041 JMV V21263
Surrogate: 2,4,6-Tribromophenol 35.0 Limits: 31-144%07/13/22 22:041 JMV V21263
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):V21593 07/20/22 16:30
<0.00343 µg/L 0.00343 0.0208
1,2-Dibromoethane 1 07/21/22 00:20 V21719JC1
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 46 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-4
93947 Matrix:
7/7/2022 9:20
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
2330 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 07/13/22 08:29
<11.5 µg/L 11.5 50.0Aliphatics C9-C12 (Adjusted)1 07/13/22 08:29
2370 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 07/13/22 08:29
390 M µg/L 94.2 385Aromatic C11-C22 (Adjusted)1 07/13/22 22:04
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V21273 07/14/22 09:16
187 JB µg/L 43.3 538Aliphatic C9-C18 1 07/22/22 10:07 V21698JLK
<191 µg/L 191 769Aliphatic C19-C36 1 07/22/22 10:07 V21698JLK
404 µg/L 94.2 385Aromatic C11-C22 1 07/22/22 10:07 V21698JLK
MADEP-EPHSurrogate: 2-Bromonaphthalene 73.5 Limits: 40-140%07/22/22 10:071 JLK
MADEP-EPHSurrogate: Chlorooctadecane 37.7 *Limits: 40-140%07/22/22 10:071 JLK
MADEP-EPHSurrogate: OTP Surrogate 51.9 Limits: 40-140%07/22/22 10:071 JLK
Surrogate: 2-Fluorobiphenyl 68.5 Limits: 40-140%07/22/22 10:071 JLK V21698
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V21177 07/12/22 08:00
2330 µg/L 11.5 50.0Aliphatic C5-C8 1 07/13/22 08:29 V21178TBL
2140 µg/L 25.8 50.0Aliphatic C9-C12 1 07/13/22 08:29 V21178TBL
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 47 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:MW-4
93947 Matrix:
7/7/2022 9:20
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V21177 07/12/22 08:00
2370 µg/L 4.02 50.0Aromatic C9-C10 1 07/13/22 08:29 V21178TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)80.8 Limits: 70-130%07/13/22 08:291 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)75.2 Limits: 70-130%07/13/22 08:291 TBL
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 48 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:TB
93948 Matrix:
7/7/2022 7:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21337 07/14/22 09:00
<1.80 µg/L 1.80 10.0Acetone 1 07/14/22 19:03 V21339JLB
<0.180 µg/L 0.180 0.500Benzene 1 07/14/22 19:03 V21339JLB
<0.210 µg/L 0.210 0.500Bromobenzene 1 07/14/22 19:03 V21339JLB
<0.420 µg/L 0.420 1.00Bromochloromethane 1 07/14/22 19:03 V21339JLB
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 07/14/22 19:03 V21339JLB
<1.50 µg/L 1.50 5.00Bromoform 1 07/14/22 19:03 V21339JLB
<0.280 µg/L 0.280 1.00Bromomethane 1 07/14/22 19:03 V21339JLB
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 07/14/22 19:03 V21339JLB
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 07/14/22 19:03 V21339JLB
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 07/14/22 19:03 V21339JLB
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 07/14/22 19:03 V21339JLB
<0.190 µg/L 0.190 0.500Chlorobenzene 1 07/14/22 19:03 V21339JLB
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 07/14/22 19:03 V21339JLB
<0.430 µg/L 0.430 1.00Chloroethane 1 07/14/22 19:03 V21339JLB
<0.220 µg/L 0.220 0.500Chloroform 1 07/14/22 19:03 V21339JLB
<0.220 µg/L 0.220 0.500
Chloromethane 1 07/14/22 19:03 V21339JLB
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 07/14/22 19:03 V21339JLB
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 07/14/22 19:03 V21339JLB
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 07/14/22 19:03 V21339JLB
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 07/14/22 19:03 V21339JLB
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 07/14/22 19:03 V21339JLB
<0.230 µg/L 0.230 0.500Dibromomethane 1 07/14/22 19:03 V21339JLB
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 49 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:TB
93948 Matrix:
7/7/2022 7:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21337 07/14/22 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 07/14/22 19:03 V21339JLB
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 07/14/22 19:03 V21339JLB
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 07/14/22 19:03 V21339JLB
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 07/14/22 19:03 V21339JLB
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 07/14/22 19:03 V21339JLB
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 07/14/22 19:03 V21339JLB
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 07/14/22 19:03 V21339JLB
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 07/14/22 19:03 V21339JLB
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 07/14/22 19:03 V21339JLB
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 07/14/22 19:03 V21339JLB
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 07/14/22 19:03 V21339JLB
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 07/14/22 19:03 V21339JLB
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 07/14/22 19:03 V21339JLB
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 07/14/22 19:03 V21339JLB
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 07/14/22 19:03 V21339JLB
<42.0 µg/L 42.0 200
Ethanol 1 07/14/22 19:03 V21339JLB
<0.170 µg/L 0.170 0.500Ethylbenzene 1 07/14/22 19:03 V21339JLB
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 07/14/22 19:03 V21339JLB
<0.380 µg/L 0.380 1.002-Hexanone 1 07/14/22 19:03 V21339JLB
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 07/14/22 19:03 V21339JLB
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 07/14/22 19:03 V21339JLB
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 07/14/22 19:03 V21339JLB
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 50 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:TB
93948 Matrix:
7/7/2022 7:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21337 07/14/22 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 07/14/22 19:03 V21339JLB
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 07/14/22 19:03 V21339JLB
0.980 J µg/L 0.330 2.00Methylene Chloride 1 07/14/22 19:03 V21339JLB
<0.470 µg/L 0.470 1.00Naphthalene 1 07/14/22 19:03 V21339JLB
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 07/14/22 19:03 V21339JLB
<0.220 µg/L 0.220 0.500Styrene 1 07/14/22 19:03 V21339JLB
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 07/14/22 19:03 V21339JLB
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 07/14/22 19:03 V21339JLB
<0.220 µg/L 0.220 0.500
Tetrachloroethene 1 07/14/22 19:03 V21339JLB
<0.220 µg/L 0.220 0.500Toluene 1 07/14/22 19:03 V21339JLB
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 07/14/22 19:03 V21339JLB
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 07/14/22 19:03 V21339JLB
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 07/14/22 19:03 V21339JLB
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 07/14/22 19:03 V21339JLB
<0.180 µg/L 0.180 0.500Trichloroethene 1 07/14/22 19:03 V21339JLB
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 07/14/22 19:03 V21339JLB
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 07/14/22 19:03 V21339JLB
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 07/14/22 19:03 V21339JLB
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 07/14/22 19:03 V21339JLB
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 07/14/22 19:03 V21339JLB
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 07/14/22 19:03 V21339JLB
<0.210 µg/L 0.210 0.500o-Xylene 1 07/14/22 19:03 V21339JLB
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 51 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-189-0052
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5716 Received : 07/08/2022
Rose Coal & Ice
Report Date : 07/26/2022
Sample ID :
Lab No :
Sampled:TB
93948 Matrix:
7/7/2022 7:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21337 07/14/22 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 07/14/22 19:03 V21339JLB
<0.21 µg/L 0.210 0.500Xylene (Total)1 07/14/22 19:03 V21339
Surrogate: 4-Bromofluorobenzene 99.4 Limits: 70-130%07/14/22 19:031 JLB V21339
Surrogate: Dibromofluoromethane 95.2 Limits: 70-130%07/14/22 19:031 JLB V21339
Surrogate: 1,2-Dichloroethane - d4 97.6 Limits: 70-130%07/14/22 19:031 JLB V21339
Surrogate: Toluene-d8 99.4 Limits: 70-130%07/14/22 19:031 JLB V21339
Qualifiers/
Definitions
Analyte detected in blankBOutside QC Limit*
Estimated valueJDilution FactorDF
Method Quantitation LimitMQLMinimum valueM
Page 52 of 91
Sample ID Report Lab NoLRB22‐189‐0052 LRB‐V21203
Paramater Result Units
Dilution 
Factor Method Analysis Date/Time Analyst Batch ID
NO TICS REPORTED 0 ug/L 1 625.1 7/13/2022 20:35 JMV V21263
Sample ID Report Lab NoMW‐1 22‐189‐0052 V 93944
Paramater Result Units
Dilution 
Factor Method Analysis Date/Time Analyst Batch ID
Hexadecanoic Acid 44.9 ug/L 1 625.1 7/13/2022 22:26 JMV V21263
Sample ID Report Lab NoMW‐2 22‐189‐0052 V 93945
Paramater Result Units
Dilution 
Factor Method Analysis Date/Time Analyst Batch ID
Hexadecanoic Acid 66.2 ug/L 1 625.1 7/13/2022 22:48 JMV V21263
Sample ID Report Lab NoMW‐3 22‐189‐0052 V 93946
Paramater Result Units
Dilution 
Factor Method Analysis Date/Time Analyst Batch ID
Hexadecanoic Acid 96.21 ug/L 1 625.1 7/13/2022 23:11 JMV V21263
Octadecanoic Acid 40.5 ug/L 1 625.1 7/13/2022 23:11 JMV V21263
Page 53 of 91
Sample ID Report Lab NoMW‐4 22‐189‐0052 V 93947
Paramater Result Units
Dilution 
Factor Method Analysis Date/Time Analyst Batch ID
Cycloheptetriene 36.91 ug/L 1 625.1 7/13/2022 22:04 JMV V21263
Propyl Benzene 22.7 ug/L 1 625.1 7/13/2022 22:04 JMV V21263
Methyl Ethyl Benzene 21.4 ug/L 1 625.1 7/13/2022 22:04 JMV V21263
Trimethyl Benzene 100 ug/L 1 625.1 7/13/2022 22:04 JMV V21263
Diethyl Benzene 38.3 ug/L 1 625.1 7/13/2022 22:04 JMV V21263
Dimethyl Ethyl Benzene 52.24 ug/L 1 625.1 7/13/2022 22:04 JMV V21263
Dimethyl Ethenyl Benzene 27.8 ug/L 1 625.1 7/13/2022 22:04 JMV V21263
Hexadecanoic Acid 30.4 ug/L 1 625.1 7/13/2022 22:04 JMV V21263
Page 54 of 91
Tentatively Identified Compound (LSC) summary
Data Path : S:\SMS\SMS-F\Data\071322\
Data File : F-071322-17.D
Acq On : 13 Jul 2022 20:35
Operator : JVOGEL
Sample : LRB-V21203
Misc :
ALS Vial : 16 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F071322_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
|--Internal Standard---|
TIC Top Hit name RT EstConc Units Response |# RT Resp Conc|
----------------------------------------------------------------------------
F071322_FL.M Thu Jul 14 13:52:53 2022 Page: 8
NO TICS REPORTED
Page 55 of 91
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\071322\
Data File : F-071322-22.D
Acq On : 13 Jul 2022 22:26
Operator : JVOGEL
Sample : V 93944-V21203
Misc :
ALS Vial : 21 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F071322_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 3 n-Hexadecanoic acid Concentration Rank 1
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
7.886 44.87 ppb 1499070 Phenanthrene-d10 7.422
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 n-Hexadecanoic acid 256 C16H32O2 000057-10-3 99
2 n-Hexadecanoic acid 256 C16H32O2 000057-10-3 97
3 n-Hexadecanoic acid 256 C16H32O2 000057-10-3 96
4 n-Hexadecanoic acid $$ Hexadecan... 256 C16H32O2 000057-10-3 76
5 Tetradecanoic acid 228 C14H28O2 000544-63-8 70
20 40 60 80 100 120 140 160 180 200 220 240 260
0
5000
m/z-->
Abundance Scan 1038 (7.886 min): F-071322-22.D\data.ms (-1033) (-)
73.043.1
129.1
213.2 256.397.1 157.1 185.2
20 40 60 80 100 120 140 160 180 200 220 240 260
0
5000
m/z-->
Abundance #123965: n-Hexadecanoic acid
43.0 73.0
256.0
129.0
213.097.0 157.0 185.0
20 40 60 80 100 120 140 160 180 200 220 240 260
0
5000
m/z-->
Abundance #123966: n-Hexadecanoic acid
73.0
129.0 256.0
43.0
213.0
157.097.0 185.0
20 40 60 80 100 120 140 160 180 200 220 240 260
0
5000
m/z-->
Abundance #123964: n-Hexadecanoic acid
43.0 73.0
129.097.0 213.0 256.0171.0
7.60 7.80 8.00 8.20
m/z 73.05 100.00%
7.60 7.80 8.00 8.20
m/z 43.10 88.76%
7.60 7.80 8.00 8.20
m/z 60.00 85.18%
7.60 7.80 8.00 8.20
m/z 41.05 78.98%
7.60 7.80 8.00 8.20
m/z 55.05 67.89%
F071322_FL.M Thu Jul 14 13:56:02 2022 Page: 7Page 56 of 91
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\071322\
Data File : F-071322-23.D
Acq On : 13 Jul 2022 22:48
Operator : JVOGEL
Sample : V 93945-V21203
Misc :
ALS Vial : 22 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F071322_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 1 n-Hexadecanoic acid Concentration Rank 9
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
7.892 66.22 ppb 2103740 Phenanthrene-d10 7.422
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 n-Hexadecanoic acid 256 C16H32O2 000057-10-3 98
2 n-Hexadecanoic acid 256 C16H32O2 000057-10-3 97
3 n-Hexadecanoic acid $$ Hexadecan... 256 C16H32O2 000057-10-3 95
4 n-Hexadecanoic acid 256 C16H32O2 000057-10-3 93
5 Tetradecanoic acid $$ Myristic a... 228 C14H28O2 000544-63-8 90
20 40 60 80 100 120 140 160 180 200 220 240 260
0
5000
m/z-->
Abundance Scan 1039 (7.892 min): F-071322-23.D\data.ms (-1033) (-)
73.043.0
129.1
256.3213.297.1 185.2157.1
20 40 60 80 100 120 140 160 180 200 220 240 260
0
5000
m/z-->
Abundance #123965: n-Hexadecanoic acid
43.0 73.0
256.0
129.0
213.097.0 157.0 185.0
20 40 60 80 100 120 140 160 180 200 220 240 260
0
5000
m/z-->
Abundance #123966: n-Hexadecanoic acid
73.0
129.0 256.0
43.0
213.0
157.097.0 185.0
20 40 60 80 100 120 140 160 180 200 220 240 260
0
5000
m/z-->
Abundance#57109: n-Hexadecanoic acid $$ Hexadecanoic acid $$ n-Hexadecoic ac
43.0 73.0
129.0 256.097.0 213.0157.0 185.0
7.60 7.80 8.00 8.20
m/z 73.05 100.00%
7.60 7.80 8.00 8.20
m/z 43.05 87.77%
7.60 7.80 8.00 8.20
m/z 60.10 84.44%
7.60 7.80 8.00 8.20
m/z 41.10 77.08%
7.60 7.80 8.00 8.20
m/z 55.10 65.34%
F071322_FL.M Thu Jul 14 13:59:09 2022 Page: 5Page 57 of 91
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\071322\
Data File : F-071322-24.D
Acq On : 13 Jul 2022 23:11
Operator : JVOGEL
Sample : V 93946-V21203
Misc :
ALS Vial : 23 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F071322_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 1 n-Hexadecanoic acid Concentration Rank 2
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
7.892 96.21 ppb 3213840 Phenanthrene-d10 7.422
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 n-Hexadecanoic acid 256 C16H32O2 000057-10-3 99
2 n-Hexadecanoic acid 256 C16H32O2 000057-10-3 97
3 n-Hexadecanoic acid 256 C16H32O2 000057-10-3 96
4 n-Hexadecanoic acid $$ Hexadecan... 256 C16H32O2 000057-10-3 91
5 Tridecanoic acid $$ n-Tridecanoi... 214 C13H26O2 000638-53-9 78
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
5000
m/z-->
Abundance Scan 1039 (7.892 min): F-071322-24.D\data.ms (-1033) (-)
73.043.0
129.1
213.2 256.197.1 171.1
281.1
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
5000
m/z-->
Abundance #123965: n-Hexadecanoic acid
43.0 73.0
256.0
129.0
213.097.0 157.0 185.0
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
5000
m/z-->
Abundance #123966: n-Hexadecanoic acid
73.0
129.0 256.0
43.0
213.0
157.097.0 185.0
20 40 60 80 100 120 140 160 180 200 220 240 260 280
0
5000
m/z-->
Abundance #123964: n-Hexadecanoic acid
43.0 73.0
129.097.0 213.0 256.0171.0
7.60 7.80 8.00 8.20
m/z 73.05 100.00%
7.60 7.80 8.00 8.20
m/z 43.05 87.52%
7.60 7.80 8.00 8.20
m/z 60.10 84.61%
7.60 7.80 8.00 8.20
m/z 41.10 76.24%
7.60 7.80 8.00 8.20
m/z 55.05 65.03%
F071322_FL.M Thu Jul 14 14:00:20 2022 Page: 5Page 58 of 91
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\071322\
Data File : F-071322-24.D
Acq On : 13 Jul 2022 23:11
Operator : JVOGEL
Sample : V 93946-V21203
Misc :
ALS Vial : 23 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F071322_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 2 Octadecanoic acid Concentration Rank 4
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
8.574 40.49 ppb 1352390 Phenanthrene-d10 7.422
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 Octadecanoic acid 284 C18H36O2 000057-11-4 95
2 Octadecanoic acid $$ Stearic aci... 284 C18H36O2 000057-11-4 94
3 Octadecanoic acid 284 C18H36O2 000057-11-4 93
4 Octadecanoic acid 284 C18H36O2 000057-11-4 83
5 n-Hexadecanoic acid 256 C16H32O2 000057-10-3 83
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340
0
5000
m/z-->
Abundance Scan 1155 (8.574 min): F-071322-24.D\data.ms (-1151) (-)
73.143.0
129.0
284.3185.2 241.2
101.1 213.2157.1 341.2
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340
0
5000
m/z-->
Abundance #125233: Octadecanoic acid
43.0 73.0
129.0
284.0241.0185.0101.0 157.0 213.0
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340
0
5000
m/z-->
Abundance#66797: Octadecanoic acid $$ Stearic acid $$ n-Octadecanoic acid $$ H
43.0 73.0
129.0 284.0
185.0 241.0101.0 213.0157.0
20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340
0
5000
m/z-->
Abundance #125236: Octadecanoic acid
73.0
129.0
43.0 284.0
185.0 241.0
101.0 157.0 213.0
8.20 8.40 8.60 8.80 9.00
m/z 73.10 100.00%
8.20 8.40 8.60 8.80 9.00
m/z 43.05 96.35%
8.20 8.40 8.60 8.80 9.00
m/z 60.10 85.45%
8.20 8.40 8.60 8.80 9.00
m/z 41.10 75.79%
8.20 8.40 8.60 8.80 9.00
m/z 55.05 72.56%
F071322_FL.M Thu Jul 14 14:00:21 2022 Page: 6Page 59 of 91
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\071322\
Data File : F-071322-21.D
Acq On : 13 Jul 2022 22:04
Operator : JVOGEL
Sample : V 93947-V21203
Misc :
ALS Vial : 20 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F071322_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 1 1,3,5-Cycloheptatriene Concentration Rank 4
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
2.069 36.91 ppb 768072 1,4-Dichlorobenzene-d4 3.515
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 1,3,5-Cycloheptatriene 92 C7H8 000544-25-2 90
2 1,3,5-Cycloheptatriene $$ Cycloh... 92 C7H8 000544-25-2 87
3 Toluene $$ Benzene, methyl $$ Me... 92 C7H8 000108-88-3 87
4 Toluene 92 C7H8 000108-88-3 81
5 Toluene 92 C7H8 000108-88-3 81
0 102030405060708090100110120
0
5000
m/z-->
Abundance Scan 48 (2.069 min): F-071322-21.D\data.ms (-40) (-)
91.1
65.039.0 51.0 77.0 113.0
0 102030405060708090100110120
0
5000
m/z-->
Abundance #109024: 1,3,5-Cycloheptatriene
91.0
39.0 65.0
51.027.015.0 77.0
0 102030405060708090100110120
0
5000
m/z-->
Abundance#1121: 1,3,5-Cycloheptatriene $$ Cyclohepta-1,3,5-triene $$ Cycloheptat
91.0
39.0 65.0
51.027.0 77.015.02.0 106.0
0 102030405060708090100110120
0
5000
m/z-->
Abundance#1115: Toluene $$ Benzene, methyl $$ Methacide $$ Methylbenzene $$
91.0
65.039.0 51.027.0 77.0
2.00 2.20 2.40
m/z 91.10 100.00%
2.00 2.20 2.40
m/z 92.10 59.48%
2.00 2.20 2.40
m/z 65.05 10.86%
2.00 2.20 2.40
m/z 39.05 8.93%
2.00 2.20 2.40
m/z 63.05 6.81%
F071322_FL.M Thu Jul 14 14:01:25 2022 Page: 5Page 60 of 91
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\071322\
Data File : F-071322-21.D
Acq On : 13 Jul 2022 22:04
Operator : JVOGEL
Sample : V 93947-V21203
Misc :
ALS Vial : 20 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F071322_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 2 Benzene, propyl- Concentration Rank 9
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
3.115 22.71 ppb 472649 1,4-Dichlorobenzene-d4 3.515
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 Benzene, propyl- 120 C9H12 000103-65-1 87
2 Benzene, propyl- $$ n-Propylbenz... 120 C9H12 000103-65-1 81
3 Benzene, propyl- 120 C9H12 000103-65-1 81
4 Ethanol, 2-[(phenylmethyl)amino]- 151 C9H13NO 000104-63-2 64
5 Propanenitrile, 3-[(phenylmethyl... 160 C10H12N2 000706-03-6 64
20 30 40 50 60 70 80 90 100 110 120 130 140
0
5000
m/z-->
Abundance Scan 226 (3.115 min): F-071322-21.D\data.ms (-217) (-)
91.1
120.1
65.039.0 78.051.0 105.0 138.1
20 30 40 50 60 70 80 90 100 110 120 130 140
0
5000
m/z-->
Abundance #111410: Benzene, propyl-
91.0
120.0
65.0 78.039.0 51.0 105.0
20 30 40 50 60 70 80 90 100 110 120 130 140
0
5000
m/z-->
Abundance#4812: Benzene, propyl- $$ n-Propylbenzene $$ Isocumene $$ Propylbe
91.0
120.0
65.039.0 78.051.027.0 105.0
20 30 40 50 60 70 80 90 100 110 120 130 140
0
5000
m/z-->
Abundance #111409: Benzene, propyl-
91.0
120.0
65.039.0 78.051.0 105.027.0
2.80 3.00 3.20 3.40
m/z 91.10 100.00%
2.80 3.00 3.20 3.40
m/z 120.10 26.71%
2.80 3.00 3.20 3.40
m/z 92.10 10.91%
2.80 3.00 3.20 3.40
m/z 65.00 10.00%
2.80 3.00 3.20 3.40
m/z 57.10 7.74%
F071322_FL.M Thu Jul 14 14:01:26 2022 Page: 6Page 61 of 91
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\071322\
Data File : F-071322-21.D
Acq On : 13 Jul 2022 22:04
Operator : JVOGEL
Sample : V 93947-V21203
Misc :
ALS Vial : 20 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F071322_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 3 Benzene, 1-ethyl-2-methyl- Concentration Rank 10
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
3.280 21.40 ppb 445366 1,4-Dichlorobenzene-d4 3.515
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 Benzene, 1-ethyl-2-methyl- 120 C9H12 000611-14-3 95
2 Benzene, 1-ethyl-2-methyl- 120 C9H12 000611-14-3 95
3 Benzene, 1-ethyl-2-methyl- $$ To... 120 C9H12 000611-14-3 94
4 Benzene, 1-ethyl-4-methyl- $$ To... 120 C9H12 000622-96-8 94
5 Benzene, 1-ethyl-2-methyl- 120 C9H12 000611-14-3 94
20 30 40 50 60 70 80 90 100 110 120 130 140
0
5000
m/z-->
Abundance Scan 254 (3.280 min): F-071322-21.D\data.ms (-249) (-)
105.1
120.1
91.077.139.1 65.051.0 141.2
20 30 40 50 60 70 80 90 100 110 120 130 140
0
5000
m/z-->
Abundance #111384: Benzene, 1-ethyl-2-methyl-
105.0
120.0
77.0 91.039.0 51.0 65.027.0
20 30 40 50 60 70 80 90 100 110 120 130 140
0
5000
m/z-->
Abundance #111386: Benzene, 1-ethyl-2-methyl-
105.0
120.0
77.0 91.044.0 65.0
20 30 40 50 60 70 80 90 100 110 120 130 140
0
5000
m/z-->
Abundance#4792: Benzene, 1-ethyl-2-methyl- $$ Toluene, o-ethyl- $$ o-Ethylmethyl
105.0
120.0
39.0 91.077.027.0 51.0 65.0
3.00 3.20 3.40 3.60
m/z 105.05 100.00%
3.00 3.20 3.40 3.60
m/z 120.05 32.30%
3.00 3.20 3.40 3.60
m/z 91.05 11.11%
3.00 3.20 3.40 3.60
m/z 77.10 10.51%
3.00 3.20 3.40 3.60
m/z 103.10 8.97%
F071322_FL.M Thu Jul 14 14:01:27 2022 Page: 7Page 62 of 91
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\071322\
Data File : F-071322-21.D
Acq On : 13 Jul 2022 22:04
Operator : JVOGEL
Sample : V 93947-V21203
Misc :
ALS Vial : 20 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F071322_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 4 Benzene, 1,2,3-trimethyl- Concentration Rank 1
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
3.374 100.07 ppb 2082460 1,4-Dichlorobenzene-d4 3.515
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 Benzene, 1,2,3-trimethyl- 120 C9H12 000526-73-8 95
2 Benzene, 1,2,4-trimethyl- 120 C9H12 000095-63-6 94
3 Benzene, 1,2,4-trimethyl- $$ .ps... 120 C9H12 000095-63-6 94
4 Benzene, 1,2,3-trimethyl- $$ Hem... 120 C9H12 000526-73-8 94
5 Benzene, 1,3,5-trimethyl- 120 C9H12 000108-67-8 94
20 40 60 80 100 120 140 160 180 200
0
5000
m/z-->
Abundance Scan 270 (3.374 min): F-071322-21.D\data.ms (-265) (-)
105.1
77.139.1 57.8 122.0 206.9
20 40 60 80 100 120 140 160 180 200
0
5000
m/z-->
Abundance #111401: Benzene, 1,2,3-trimethyl-
105.0
77.039.0 59.015.0 122.0
20 40 60 80 100 120 140 160 180 200
0
5000
m/z-->
Abundance #111403: Benzene, 1,2,4-trimethyl-
105.0
77.051.027.0
20 40 60 80 100 120 140 160 180 200
0
5000
m/z-->
Abundance#4805: Benzene, 1,2,4-trimethyl- $$ .psi.-Cumene $$ As-Trimethylbenze
105.0
28.0 77.051.0
122.0
3.00 3.20 3.40 3.60 3.80
m/z 105.05 100.00%
3.00 3.20 3.40 3.60 3.80
m/z 120.10 49.64%
3.00 3.20 3.40 3.60 3.80
m/z 119.10 13.21%
3.00 3.20 3.40 3.60 3.80
m/z 77.10 12.27%
3.00 3.20 3.40 3.60 3.80
m/z 91.10 10.51%
F071322_FL.M Thu Jul 14 14:01:28 2022 Page: 8Page 63 of 91
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\071322\
Data File : F-071322-21.D
Acq On : 13 Jul 2022 22:04
Operator : JVOGEL
Sample : V 93947-V21203
Misc :
ALS Vial : 20 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F071322_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 5 Benzene, 1,2-diethyl- Concentration Rank 3
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
3.697 38.34 ppb 797882 1,4-Dichlorobenzene-d4 3.515
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 Benzene, 1,2-diethyl- 134 C10H14 000135-01-3 95
2 Benzene, 1,4-diethyl- 134 C10H14 000105-05-5 94
3 Benzene, 1,4-diethyl- $$ Benzene... 134 C10H14 000105-05-5 94
4 Benzene, 1,3-diethyl- 134 C10H14 000141-93-5 94
5 Benzene, 1,3-diethyl- 134 C10H14 000141-93-5 94
20 40 60 80 100 120 140 160 180 200
0
5000
m/z-->
Abundance Scan 325 (3.697 min): F-071322-21.D\data.ms (-321) (-)
119.1
91.1
57.139.1 74.0 138.0 156.1 207.0
20 40 60 80 100 120 140 160 180 200
0
5000
m/z-->
Abundance #112963: Benzene, 1,2-diethyl-
105.0
134.0
77.039.0 58.0
20 40 60 80 100 120 140 160 180 200
0
5000
m/z-->
Abundance #112960: Benzene, 1,4-diethyl-
119.0
91.0
39.0 65.015.0 136.0
20 40 60 80 100 120 140 160 180 200
0
5000
m/z-->
Abundance#8118: Benzene, 1,4-diethyl- $$ Benzene, p-diethyl- $$ p-Diethylbenzene
119.0
91.0
39.0 65.0 136.0
3.40 3.60 3.80 4.00
m/z 119.10 100.00%
3.40 3.60 3.80 4.00
m/z 105.10 93.94%
3.40 3.60 3.80 4.00
m/z 134.05 49.87%
3.40 3.60 3.80 4.00
m/z 91.10 23.12%
3.40 3.60 3.80 4.00
m/z 77.10 14.66%
F071322_FL.M Thu Jul 14 14:01:28 2022 Page: 9Page 64 of 91
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\071322\
Data File : F-071322-21.D
Acq On : 13 Jul 2022 22:04
Operator : JVOGEL
Sample : V 93947-V21203
Misc :
ALS Vial : 20 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F071322_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 6 Benzene, 4-ethyl-1,2-dimethyl- Concentration Rank 2
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
3.750 52.24 ppb 1087130 1,4-Dichlorobenzene-d4 3.515
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 Benzene, 4-ethyl-1,2-dimethyl- 134 C10H14 000934-80-5 91
2 Benzene, 2-ethyl-1,4-dimethyl- 134 C10H14 001758-88-9 91
3 Benzene, 1,4-diethyl- 134 C10H14 000105-05-5 91
4 Benzene, 1,4-diethyl- $$ Benzene... 134 C10H14 000105-05-5 91
5 Benzene, 1,2,3,4-tetramethyl- 134 C10H14 000488-23-3 91
0 10 20 30 40 50 60 70 80 90 100110120130140150
0
5000
m/z-->
Abundance Scan 334 (3.750 min): F-071322-21.D\data.ms (-331) (-)
119.1
105.1
134.1
91.1
77.139.1 63.0 152.1
0 10 20 30 40 50 60 70 80 90 100110120130140150
0
5000
m/z-->
Abundance #112974: Benzene, 4-ethyl-1,2-dimethyl-
119.0
134.091.0
77.0 105.051.027.0
0 10 20 30 40 50 60 70 80 90 100110120130140150
0
5000
m/z-->
Abundance #112975: Benzene, 2-ethyl-1,4-dimethyl-
119.0
134.0
105.091.077.039.0 53.015.01.0
0 10 20 30 40 50 60 70 80 90 100110120130140150
0
5000
m/z-->
Abundance #112959: Benzene, 1,4-diethyl-
119.0
105.0
134.0
91.027.0 77.051.0
3.40 3.60 3.80 4.00
m/z 119.10 100.00%
3.40 3.60 3.80 4.00
m/z 105.10 58.28%
3.40 3.60 3.80 4.00
m/z 134.05 47.39%
3.40 3.60 3.80 4.00
m/z 91.10 29.76%
3.40 3.60 3.80 4.00
m/z 77.10 13.01%
F071322_FL.M Thu Jul 14 14:01:29 2022 Page: 10Page 65 of 91
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\071322\
Data File : F-071322-21.D
Acq On : 13 Jul 2022 22:04
Operator : JVOGEL
Sample : V 93947-V21203
Misc :
ALS Vial : 20 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F071322_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 8 Benzene, 2-ethenyl-1,4-dime... Concentration Rank 6
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
4.343 27.78 ppb 1392750 Naphthalene-d8 4.572
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 Benzene, 2-ethenyl-1,4-dimethyl-... 132 C10H12 002039-89-6 95
2 Benzene, (1-methyl-1-propenyl)-,... 132 C10H12 000768-00-3 91
3 3-Phenylbut-1-ene $$ 1-Methyl-2-... 132 C10H12 000934-10-1 81
4 Benzene, 2-ethenyl-1,3-dimethyl-... 132 C10H12 002039-90-9 76
5 Benzene, (2-methyl-1-propenyl)- 132 C10H12 000768-49-0 76
10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160
0
5000
m/z-->
Abundance Scan 435 (4.343 min): F-071322-21.D\data.ms (-429) (-)
117.1
132.1
91.1
77.151.137.1 159.9146.8
10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160
0
5000
m/z-->
Abundance#7666: Benzene, 2-ethenyl-1,4-dimethyl- $$ Styrene, 2,5-dimethyl- $$ 1,4
117.0
132.0
91.0
51.0 65.027.0
10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160
0
5000
m/z-->
Abundance#7656: Benzene, (1-methyl-1-propenyl)-, (E)- $$ 2-Butene, 2-phenyl-, (E)
117.0
132.0
91.0
51.0 77.027.0
10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160
0
5000
m/z-->
Abundance #7690: 3-Phenylbut-1-ene $$ 1-Methyl-2-propenyl)-benzene
117.0
132.091.0
39.0 77.063.0
4.00 4.20 4.40 4.60
m/z 117.05 100.00%
4.00 4.20 4.40 4.60
m/z 119.10 42.72%
4.00 4.20 4.40 4.60
m/z 132.05 39.13%
4.00 4.20 4.40 4.60
m/z 115.10 30.71%
4.00 4.20 4.40 4.60
m/z 131.05 19.14%
F071322_FL.M Thu Jul 14 14:01:32 2022 Page: 12Page 66 of 91
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\071322\
Data File : F-071322-21.D
Acq On : 13 Jul 2022 22:04
Operator : JVOGEL
Sample : V 93947-V21203
Misc :
ALS Vial : 20 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F071322_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 10 n-Hexadecanoic acid Concentration Rank 5
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
7.886 30.44 ppb 1061430 Phenanthrene-d10 7.422
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 n-Hexadecanoic acid 256 C16H32O2 000057-10-3 97
2 n-Hexadecanoic acid 256 C16H32O2 000057-10-3 95
3 n-Hexadecanoic acid 256 C16H32O2 000057-10-3 91
4 Tetradecanoic acid 228 C14H28O2 000544-63-8 91
5 Tridecanoic acid 214 C13H26O2 000638-53-9 70
20 40 60 80 100 120 140 160 180 200 220 240 260
0
5000
m/z-->
Abundance Scan 1038 (7.886 min): F-071322-21.D\data.ms (-1028) (-)
73.143.0
129.1
213.2 256.1
97.1 157.1 185.2
236.0
20 40 60 80 100 120 140 160 180 200 220 240 260
0
5000
m/z-->
Abundance #123965: n-Hexadecanoic acid
43.0 73.0
256.0
129.0
213.097.0 157.0 185.0
20 40 60 80 100 120 140 160 180 200 220 240 260
0
5000
m/z-->
Abundance #123964: n-Hexadecanoic acid
43.0 73.0
129.097.0 213.0 256.0171.0
20 40 60 80 100 120 140 160 180 200 220 240 260
0
5000
m/z-->
Abundance #123966: n-Hexadecanoic acid
73.0
129.0 256.0
43.0
213.0
157.097.0 185.0
7.60 7.80 8.00 8.20
m/z 73.10 100.00%
7.60 7.80 8.00 8.20
m/z 43.05 87.07%
7.60 7.80 8.00 8.20
m/z 60.10 82.09%
7.60 7.80 8.00 8.20
m/z 41.10 75.76%
7.60 7.80 8.00 8.20
m/z 55.10 66.73%
F071322_FL.M Thu Jul 14 14:01:33 2022 Page: 14Page 67 of 91
Quality Control Data
22-189-0052Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Coal & Ice
QC Prep Batch Method:
Metals Analysis
6010D
V21636QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3005A
QC Prep:V21132
Associated Lab Samples: 93944, 93945, 93946, 93947
LRB-V21132 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
07/12/22 16:410.0060.002<0.002mg/LLead
LCS-V21132Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
1070.1070.100mg/LLead 80-120
V 93838-MS-V21132 V 93838-MSD-V21132Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
1.01 1011.011.001.00< 0.024mg/LLead 101 75-125 0.0 20.0
V 93838-PDS-V21132Post Digestion Spike
Parameter
Analyzed%
Recovery
PDS
ResultUnits
07/12/22 18:0199.02.48mg/LLead
Page 1 of 22Date:07/26/2022 10:40 AM
Page 68 of 91
Quality Control Data
22-189-0052Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Coal & Ice
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21339QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21337
Associated Lab Samples: 93945, 93946, 93948
LRB-V21337 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/14/22 18:2410.01.80<1.80µg/LAcetone
07/14/22 18:240.5000.180<0.180µg/LBenzene
07/14/22 18:240.5000.210<0.210µg/LBromobenzene
07/14/22 18:241.000.420<0.420µg/LBromochloromethane
07/14/22 18:240.5000.160<0.160µg/LBromodichloromethane
07/14/22 18:245.001.50<1.50µg/LBromoform
07/14/22 18:241.000.280<0.280µg/LBromomethane
07/14/22 18:240.5000.180<0.180µg/Ln-Butylbenzene
07/14/22 18:240.5000.200<0.200µg/Lsec-Butyl benzene
07/14/22 18:242.000.920<0.920µg/Ltert-Butyl benzene
07/14/22 18:240.5000.180<0.180µg/LCarbon Tetrachloride
07/14/22 18:240.5000.190<0.190µg/LChlorobenzene
07/14/22 18:240.5000.190<0.190µg/LChlorodibromomethane
07/14/22 18:241.000.430<0.430µg/LChloroethane
07/14/22 18:240.5000.220<0.220µg/LChloroform
07/14/22 18:240.5000.220<0.220µg/LChloromethane
07/14/22 18:240.5000.200<0.200µg/L2-Chlorotoluene
07/14/22 18:240.5000.200<0.200µg/L4-Chlorotoluene
07/14/22 18:240.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
07/14/22 18:242.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
07/14/22 18:240.5000.200<0.200µg/L1,2-Dibromoethane
07/14/22 18:240.5000.230<0.230µg/LDibromomethane
07/14/22 18:240.5000.220<0.220µg/L1,2-Dichlorobenzene
07/14/22 18:240.5000.190<0.190µg/L1,3-Dichlorobenzene
07/14/22 18:240.5000.210<0.210µg/L1,4-Dichlorobenzene
07/14/22 18:245.001.20<1.20µg/LDichlorodifluoromethane
07/14/22 18:240.5000.240<0.240µg/L1,1-Dichloroethane
Page 2 of 22Date:07/26/2022 10:40 AM
Page 69 of 91
Quality Control Data
22-189-0052Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Coal & Ice
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21339QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21337
Associated Lab Samples: 93945, 93946, 93948
LRB-V21337 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/14/22 18:240.5000.150<0.150µg/L1,2-Dichloroethane
07/14/22 18:240.5000.150<0.150µg/L1,1-Dichloroethene
07/14/22 18:240.5000.200<0.200µg/Lcis-1,2-Dichloroethene
07/14/22 18:240.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
07/14/22 18:240.5000.190<0.190µg/L1,2-Dichloropropane
07/14/22 18:240.5000.130<0.130µg/L1,3-Dichloropropane
07/14/22 18:242.000.210<0.210µg/L2,2-Dichloropropane
07/14/22 18:240.5000.200<0.200µg/L1,1-Dichloropropene
07/14/22 18:240.5000.210<0.210µg/Lcis-1,3-Dichloropropene
07/14/22 18:240.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
07/14/22 18:2420042.0<42.0µg/LEthanol
07/14/22 18:240.5000.170<0.170µg/LEthylbenzene
07/14/22 18:243.000.350<0.350µg/LHexachlorobutadiene
07/14/22 18:241.000.380<0.380µg/L2-Hexanone
07/14/22 18:240.5000.180<0.180µg/LIsopropylbenzene
07/14/22 18:240.5000.089<0.089µg/L4-Isopropyl toluene
07/14/22 18:245.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
07/14/22 18:241.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
07/14/22 18:241.000.078<0.078µg/L4-Methyl-2-Pentanone
07/14/22 18:242.000.330<0.330µg/LMethylene Chloride
07/14/22 18:241.000.470<0.470µg/LNaphthalene
07/14/22 18:240.5000.190<0.190µg/Ln-Propylbenzene
07/14/22 18:240.5000.220<0.220µg/LStyrene
07/14/22 18:2410.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
07/14/22 18:2410.00.350<0.350µg/Ltert-Butyl formate (TBF)
07/14/22 18:2410.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
07/14/22 18:2410.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME)
Page 3 of 22Date:07/26/2022 10:40 AM
Page 70 of 91
Quality Control Data
22-189-0052Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Coal & Ice
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21339QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21337
Associated Lab Samples: 93945, 93946, 93948
LRB-V21337 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/14/22 18:240.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
07/14/22 18:240.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
07/14/22 18:240.5000.220<0.220µg/LTetrachloroethene
07/14/22 18:240.5000.220<0.220µg/LToluene
07/14/22 18:240.5000.380<0.380µg/L1,2,3-Trichlorobenzene
07/14/22 18:240.5000.310<0.310µg/L1,2,4-Trichlorobenzene
07/14/22 18:240.5000.160<0.160µg/L1,1,1-Trichloroethane
07/14/22 18:240.5000.096<0.096µg/L1,1,2-Trichloroethane
07/14/22 18:240.5000.180<0.180µg/LTrichloroethene
07/14/22 18:240.5000.180<0.180µg/LTrichlorofluoromethane
07/14/22 18:240.5000.270<0.270µg/L1,2,3-Trichloropropane
07/14/22 18:240.5000.190<0.190µg/L1,2,4-Trimethylbenzene
07/14/22 18:240.5000.180<0.180µg/L1,3,5-Trimethylbenzene
07/14/22 18:245.001.00<1.00µg/LVinyl Acetate
07/14/22 18:240.5000.170<0.170µg/LVinyl Chloride
07/14/22 18:240.5000.210<0.210µg/Lo-Xylene
07/14/22 18:241.000.420<0.420µg/Lm,p-Xylene
07/14/22 18:2410.01.00<1.00µg/L3,3-Dimethyl-1-butanol
07/14/22 18:244-Bromofluorobenzene (S)99.6 70-130
07/14/22 18:24Dibromofluoromethane (S)98.2 70-130
07/14/22 18:241,2-Dichloroethane - d4 (S)98.0 70-130
07/14/22 18:24Toluene-d8 (S)99.4 70-130
Page 4 of 22Date:07/26/2022 10:40 AM
Page 71 of 91
Quality Control Data
22-189-0052Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Coal & Ice
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21339QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21337
LCS-V21337 LCSD-V21337Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
39.7 99.299.739.940.0µg/LAcetone 40-160 0.5 20.0
19.5 97.510420.720.0µg/LBenzene 70-130 5.9 20.0
19.6 98.010120.220.0µg/LBromobenzene 70-130 3.0 20.0
19.7 98.510220.320.0µg/LBromochloromethane 70-130 3.0 20.0
20.6 10310420.720.0µg/LBromodichloromethane 70-130 0.4 20.0
23.1 11611523.020.0µg/LBromoform 70-130 0.4 20.0
19.5 97.594.018.820.0µg/LBromomethane 60-140 3.6 20.0
19.8 99.010420.720.0µg/Ln-Butylbenzene 70-130 4.4 20.0
19.9 99.510420.720.0µg/Lsec-Butyl benzene 70-130 3.9 20.0
20.2 10110320.620.0µg/Ltert-Butyl benzene 70-130 1.9 20.0
20.5 10310320.520.0µg/LCarbon Tetrachloride 70-130 0.0 20.0
20.4 10210721.320.0µg/LChlorobenzene 70-130 4.3 20.0
21.3 10711422.720.0µg/LChlorodibromomethane 70-130 6.3 20.0
19.0 95.096.519.320.0µg/LChloroethane 60-140 1.5 20.0
20.1 10110521.020.0µg/LChloroform 70-130 4.3 20.0
19.1 95.599.019.820.0µg/LChloromethane 60-140 3.5 20.0
19.9 99.510320.520.0µg/L2-Chlorotoluene 70-130 2.9 20.0
19.8 99.010120.220.0µg/L4-Chlorotoluene 70-130 2.0 20.0
19.9 99.510420.720.0µg/LDi-Isopropyl Ether (DIPE)70-130 3.9 20.0
17.7 88.598.519.720.0µg/L1,2-Dibromo-3-Chloropropane 70-130 10.6 20.0
20.7 10410521.020.0µg/L1,2-Dibromoethane 70-130 1.4 20.0
20.1 10199.519.920.0µg/LDibromomethane 70-130 1.0 20.0
20.9 10510420.820.0µg/L1,2-Dichlorobenzene 70-130 0.4 20.0
19.8 99.010420.720.0µg/L1,3-Dichlorobenzene 70-130 4.4 20.0
19.3 96.510020.020.0µg/L1,4-Dichlorobenzene 70-130 3.5 20.0
20.1 10110821.520.0µg/LDichlorodifluoromethane 60-140 6.7 20.0
Page 5 of 22Date:07/26/2022 10:40 AM
Page 72 of 91
Quality Control Data
22-189-0052Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Coal & Ice
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21339QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21337
LCS-V21337 LCSD-V21337Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
19.9 99.510420.820.0µg/L1,1-Dichloroethane 70-130 4.4 20.0
18.7 93.597.019.420.0µg/L1,2-Dichloroethane 70-130 3.6 20.0
20.0 10010320.520.0µg/L1,1-Dichloroethene 70-130 2.4 20.0
20.2 10110621.220.0µg/Lcis-1,2-Dichloroethene 70-130 4.8 20.0
20.4 10210921.720.0µg/Ltrans-1,2-Dichloroethene 70-130 6.1 20.0
18.8 94.010120.120.0µg/L1,2-Dichloropropane 70-130 6.6 20.0
20.1 10110721.420.0µg/L1,3-Dichloropropane 70-130 6.2 20.0
19.9 99.510621.220.0µg/L2,2-Dichloropropane 70-130 6.3 20.0
19.9 99.510320.520.0µg/L1,1-Dichloropropene 70-130 2.9 20.0
20.3 10210721.420.0µg/Lcis-1,3-Dichloropropene 70-130 5.2 20.0
20.3 10210721.420.0µg/Ltrans-1,3-Dichloropropene 70-130 5.2 20.0
575 115105526500µg/LEthanol 60-140 8.9 20.0
19.8 99.010220.420.0µg/LEthylbenzene 70-130 2.9 20.0
20.5 10310821.620.0µg/LHexachlorobutadiene 70-130 5.2 20.0
19.9 99.510120.220.0µg/L2-Hexanone 60-140 1.4 20.0
19.9 99.510220.320.0µg/LIsopropylbenzene 70-130 1.9 20.0
20.5 10310721.320.0µg/L4-Isopropyl toluene 70-130 3.8 20.0
22.4 11294.518.920.0µg/LMethyl Ethyl Ketone (MEK)60-140 16.9 20.0
20.6 10310521.020.0µg/LMethyl tert-butyl ether (MTBE)70-130 1.9 20.0
19.8 99.010520.920.0µg/L4-Methyl-2-Pentanone 60-140 5.4 20.0
20.0 10010420.720.0µg/LMethylene Chloride 70-130 3.4 20.0
18.2 91.094.518.920.0µg/LNaphthalene 70-130 3.7 20.0
19.8 99.010320.620.0µg/Ln-Propylbenzene 70-130 3.9 20.0
20.7 10410821.520.0µg/LStyrene 70-130 3.7 20.0
42.7 10711445.740.0µg/Ltert-Butyl Alcohol (TBA)40-140 6.7 20.0
49.1 12312248.840.0µg/Ltert-Butyl formate (TBF)40-140 0.6 20.0
Page 6 of 22Date:07/26/2022 10:40 AM
Page 73 of 91
Quality Control Data
22-189-0052Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Coal & Ice
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21339QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21337
LCS-V21337 LCSD-V21337Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
25.7 12991.518.320.0µg/Ltert-Amyl Alcohol (TAA)40-140 33.6*20.0
43.0 10810943.540.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 1.1 20.0
21.0 10510621.220.0µg/L1,1,1,2-Tetrachloroethane 70-130 0.9 20.0
20.8 10410120.220.0µg/L1,1,2,2-Tetrachloroethane 70-130 2.9 20.0
19.8 99.010420.720.0µg/LTetrachloroethene 70-130 4.4 20.0
19.3 96.510020.020.0µg/LToluene 70-130 3.5 20.0
19.5 97.510420.720.0µg/L1,2,3-Trichlorobenzene 70-130 5.9 20.0
19.7 98.510120.220.0µg/L1,2,4-Trichlorobenzene 70-130 2.5 20.0
20.5 10310621.120.0µg/L1,1,1-Trichloroethane 70-130 2.8 20.0
21.0 10510420.820.0µg/L1,1,2-Trichloroethane 70-130 0.9 20.0
19.7 98.510320.520.0µg/LTrichloroethene 70-130 3.9 20.0
20.1 10110621.220.0µg/LTrichlorofluoromethane 60-140 5.3 20.0
19.4 97.010320.520.0µg/L1,2,3-Trichloropropane 70-130 5.5 20.0
19.8 99.010020.020.0µg/L1,2,4-Trimethylbenzene 70-130 1.0 20.0
19.9 99.510420.720.0µg/L1,3,5-Trimethylbenzene 70-130 3.9 20.0
23.6 11812725.320.0µg/LVinyl Acetate 60-140 6.9 20.0
19.0 95.010220.420.0µg/LVinyl Chloride 60-140 7.1 20.0
20.1 10110320.620.0µg/Lo-Xylene 70-130 2.4 20.0
40.7 10210642.340.0µg/Lm,p-Xylene 70-130 3.8 20.0
19.8 99.012023.920.0µg/L3,3-Dimethyl-1-butanol 70-130 18.7 20.0
99.099.44-Bromofluorobenzene (S)70-130
99.8102Dibromofluoromethane (S)70-130
98.498.61,2-Dichloroethane - d4 (S)70-130
99.4101Toluene-d8 (S)70-130
Page 7 of 22* QC Fail Date:07/26/2022 10:40 AM
Page 74 of 91
Quality Control Data
22-189-0052Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Coal & Ice
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21409QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21408
Associated Lab Samples: 93944, 93947
LRB-V21408 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/15/22 13:4310.01.80<1.80µg/LAcetone
07/15/22 13:430.5000.180<0.180µg/LBenzene
07/15/22 13:430.5000.210<0.210µg/LBromobenzene
07/15/22 13:431.000.420<0.420µg/LBromochloromethane
07/15/22 13:430.5000.160<0.160µg/LBromodichloromethane
07/15/22 13:435.001.50<1.50µg/LBromoform
07/15/22 13:431.000.280<0.280µg/LBromomethane
07/15/22 13:430.5000.180<0.180µg/Ln-Butylbenzene
07/15/22 13:430.5000.200<0.200µg/Lsec-Butyl benzene
07/15/22 13:432.000.920<0.920µg/Ltert-Butyl benzene
07/15/22 13:430.5000.180<0.180µg/LCarbon Tetrachloride
07/15/22 13:430.5000.190<0.190µg/LChlorobenzene
07/15/22 13:430.5000.190<0.190µg/LChlorodibromomethane
07/15/22 13:431.000.430<0.430µg/LChloroethane
07/15/22 13:430.5000.220<0.220µg/LChloroform
07/15/22 13:430.5000.220<0.220µg/LChloromethane
07/15/22 13:430.5000.200<0.200µg/L2-Chlorotoluene
07/15/22 13:430.5000.200<0.200µg/L4-Chlorotoluene
07/15/22 13:430.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
07/15/22 13:432.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
07/15/22 13:430.5000.230<0.230µg/LDibromomethane
07/15/22 13:430.5000.220<0.220µg/L1,2-Dichlorobenzene
07/15/22 13:430.5000.190<0.190µg/L1,3-Dichlorobenzene
07/15/22 13:430.5000.210<0.210µg/L1,4-Dichlorobenzene
07/15/22 13:435.001.20<1.20µg/LDichlorodifluoromethane
07/15/22 13:430.5000.240<0.240µg/L1,1-Dichloroethane
07/15/22 13:430.5000.150<0.150µg/L1,2-Dichloroethane
Page 8 of 22Date:07/26/2022 10:40 AM
Page 75 of 91
Quality Control Data
22-189-0052Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Coal & Ice
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21409QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21408
Associated Lab Samples: 93944, 93947
LRB-V21408 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/15/22 13:430.5000.150<0.150µg/L1,1-Dichloroethene
07/15/22 13:430.5000.200<0.200µg/Lcis-1,2-Dichloroethene
07/15/22 13:430.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
07/15/22 13:430.5000.190<0.190µg/L1,2-Dichloropropane
07/15/22 13:430.5000.130<0.130µg/L1,3-Dichloropropane
07/15/22 13:432.000.210<0.210µg/L2,2-Dichloropropane
07/15/22 13:430.5000.200<0.200µg/L1,1-Dichloropropene
07/15/22 13:430.5000.210<0.210µg/Lcis-1,3-Dichloropropene
07/15/22 13:430.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
07/15/22 13:4320042.0<42.0µg/LEthanol
07/15/22 13:430.5000.170<0.170µg/LEthylbenzene
07/15/22 13:433.000.350<0.350µg/LHexachlorobutadiene
07/15/22 13:431.000.380<0.380µg/L2-Hexanone
07/15/22 13:430.5000.180<0.180µg/LIsopropylbenzene
07/15/22 13:430.5000.089<0.089µg/L4-Isopropyl toluene
07/15/22 13:435.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
07/15/22 13:431.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
07/15/22 13:431.000.078<0.078µg/L4-Methyl-2-Pentanone
07/15/22 13:432.000.330<0.330µg/LMethylene Chloride
07/15/22 13:431.000.470<0.470µg/LNaphthalene
07/15/22 13:430.5000.190<0.190µg/Ln-Propylbenzene
07/15/22 13:430.5000.220<0.220µg/LStyrene
07/15/22 13:4310.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
07/15/22 13:4310.00.350<0.350µg/Ltert-Butyl formate (TBF)
07/15/22 13:4310.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
07/15/22 13:4310.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME)
07/15/22 13:430.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
Page 9 of 22Date:07/26/2022 10:40 AM
Page 76 of 91
Quality Control Data
22-189-0052Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Coal & Ice
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21409QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21408
Associated Lab Samples: 93944, 93947
LRB-V21408 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/15/22 13:430.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
07/15/22 13:430.5000.220<0.220µg/LTetrachloroethene
07/15/22 13:430.5000.220<0.220µg/LToluene
07/15/22 13:430.5000.380<0.380µg/L1,2,3-Trichlorobenzene
07/15/22 13:430.5000.310<0.310µg/L1,2,4-Trichlorobenzene
07/15/22 13:430.5000.160<0.160µg/L1,1,1-Trichloroethane
07/15/22 13:430.5000.096<0.096µg/L1,1,2-Trichloroethane
07/15/22 13:430.5000.180<0.180µg/LTrichloroethene
07/15/22 13:430.5000.180<0.180µg/LTrichlorofluoromethane
07/15/22 13:430.5000.270<0.270µg/L1,2,3-Trichloropropane
07/15/22 13:430.5000.190<0.190µg/L1,2,4-Trimethylbenzene
07/15/22 13:430.5000.180<0.180µg/L1,3,5-Trimethylbenzene
07/15/22 13:435.001.00<1.00µg/LVinyl Acetate
07/15/22 13:430.5000.170<0.170µg/LVinyl Chloride
07/15/22 13:430.5000.210<0.210µg/Lo-Xylene
07/15/22 13:431.000.420<0.420µg/Lm,p-Xylene
07/15/22 13:4310.01.00<1.00µg/L3,3-Dimethyl-1-butanol
07/15/22 13:434-Bromofluorobenzene (S)100 70-130
07/15/22 13:43Dibromofluoromethane (S)96.6 70-130
07/15/22 13:431,2-Dichloroethane - d4 (S)98.4 70-130
07/15/22 13:43Toluene-d8 (S)98.8 70-130
LCS-V21408 LCSD-V21408Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
40.1 10099.739.940.0µg/LAcetone 40-160 0.5 20.0
Page 10 of 22Date:07/26/2022 10:40 AM
Page 77 of 91
Quality Control Data
22-189-0052Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Coal & Ice
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21409QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21408
LCS-V21408 LCSD-V21408Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.0 10010020.020.0µg/LBenzene 70-130 0.0 20.0
19.7 98.597.019.420.0µg/LBromobenzene 70-130 1.5 20.0
19.9 99.599.519.920.0µg/LBromochloromethane 70-130 0.0 20.0
20.9 10510521.020.0µg/LBromodichloromethane 70-130 0.4 20.0
22.6 11310921.820.0µg/LBromoform 70-130 3.6 20.0
19.9 99.510220.320.0µg/LBromomethane 60-140 1.9 20.0
20.5 10310320.620.0µg/Ln-Butylbenzene 70-130 0.4 20.0
20.4 10210320.620.0µg/Lsec-Butyl benzene 70-130 0.9 20.0
21.0 10510320.520.0µg/Ltert-Butyl benzene 70-130 2.4 20.0
23.5 11810621.120.0µg/LCarbon Tetrachloride 70-130 10.7 20.0
21.0 10510520.920.0µg/LChlorobenzene 70-130 0.4 20.0
22.3 11210721.420.0µg/LChlorodibromomethane 70-130 4.1 20.0
19.0 95.093.518.720.0µg/LChloroethane 60-140 1.5 20.0
20.9 10510520.920.0µg/LChloroform 70-130 0.0 20.0
19.3 96.597.519.520.0µg/LChloromethane 60-140 1.0 20.0
20.8 10410020.020.0µg/L2-Chlorotoluene 70-130 3.9 20.0
20.9 10510220.420.0µg/L4-Chlorotoluene 70-130 2.4 20.0
20.7 10410220.420.0µg/LDi-Isopropyl Ether (DIPE)70-130 1.4 20.0
20.8 10498.519.720.0µg/L1,2-Dibromo-3-Chloropropane 70-130 5.4 20.0
20.8 10410621.120.0µg/LDibromomethane 70-130 1.4 20.0
21.2 10610521.020.0µg/L1,2-Dichlorobenzene 70-130 0.9 20.0
20.9 10510420.720.0µg/L1,3-Dichlorobenzene 70-130 0.9 20.0
19.9 99.599.019.820.0µg/L1,4-Dichlorobenzene 70-130 0.5 20.0
19.9 99.599.519.920.0µg/LDichlorodifluoromethane 60-140 0.0 20.0
20.0 10010320.520.0µg/L1,1-Dichloroethane 70-130 2.4 20.0
19.3 96.596.019.220.0µg/L1,2-Dichloroethane 70-130 0.5 20.0
Page 11 of 22Date:07/26/2022 10:40 AM
Page 78 of 91
Quality Control Data
22-189-0052Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Coal & Ice
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21409QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21408
LCS-V21408 LCSD-V21408Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.7 10410521.020.0µg/L1,1-Dichloroethene 70-130 1.4 20.0
20.4 10210420.720.0µg/Lcis-1,2-Dichloroethene 70-130 1.4 20.0
21.0 10510520.920.0µg/Ltrans-1,2-Dichloroethene 70-130 0.4 20.0
20.1 10198.019.620.0µg/L1,2-Dichloropropane 70-130 2.5 20.0
21.0 10510220.420.0µg/L1,3-Dichloropropane 70-130 2.8 20.0
19.9 99.510621.220.0µg/L2,2-Dichloropropane 70-130 6.3 20.0
20.1 10110621.220.0µg/L1,1-Dichloropropene 70-130 5.3 20.0
20.8 10410621.220.0µg/Lcis-1,3-Dichloropropene 70-130 1.9 20.0
20.8 10410621.220.0µg/Ltrans-1,3-Dichloropropene 70-130 1.9 20.0
551 110106529500µg/LEthanol 60-140 4.0 20.0
20.2 10110220.420.0µg/LEthylbenzene 70-130 0.9 20.0
20.4 10210020.020.0µg/LHexachlorobutadiene 70-130 1.9 20.0
19.6 98.010020.020.0µg/L2-Hexanone 60-140 2.0 20.0
20.4 10210120.120.0µg/LIsopropylbenzene 70-130 1.4 20.0
21.0 10510721.320.0µg/L4-Isopropyl toluene 70-130 1.4 20.0
20.8 10499.019.820.0µg/LMethyl Ethyl Ketone (MEK)60-140 4.9 20.0
20.8 10410220.420.0µg/LMethyl tert-butyl ether (MTBE)70-130 1.9 20.0
20.2 10199.019.820.0µg/L4-Methyl-2-Pentanone 60-140 2.0 20.0
20.3 10210220.320.0µg/LMethylene Chloride 70-130 0.0 20.0
18.5 92.592.018.420.0µg/LNaphthalene 70-130 0.5 20.0
20.7 10410320.520.0µg/Ln-Propylbenzene 70-130 0.9 20.0
21.1 10610420.720.0µg/LStyrene 70-130 1.9 20.0
43.6 10910642.240.0µg/Ltert-Butyl Alcohol (TBA)40-140 3.2 20.0
47.0 11811847.340.0µg/Ltert-Butyl formate (TBF)40-140 0.6 20.0
19.3 96.511322.520.0µg/Ltert-Amyl Alcohol (TAA)40-140 15.3 20.0
43.7 10910843.340.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 0.9 20.0
Page 12 of 22Date:07/26/2022 10:40 AM
Page 79 of 91
Quality Control Data
22-189-0052Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Coal & Ice
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21409QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21408
LCS-V21408 LCSD-V21408Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
22.1 11110821.520.0µg/L1,1,1,2-Tetrachloroethane 70-130 2.7 20.0
20.0 10010220.420.0µg/L1,1,2,2-Tetrachloroethane 70-130 1.9 20.0
19.7 98.510020.020.0µg/LTetrachloroethene 70-130 1.5 20.0
19.7 98.599.519.920.0µg/LToluene 70-130 1.0 20.0
20.2 10198.519.720.0µg/L1,2,3-Trichlorobenzene 70-130 2.5 20.0
19.2 96.097.519.520.0µg/L1,2,4-Trichlorobenzene 70-130 1.5 20.0
20.7 10410320.520.0µg/L1,1,1-Trichloroethane 70-130 0.9 20.0
21.1 10610821.620.0µg/L1,1,2-Trichloroethane 70-130 2.3 20.0
20.3 10210420.820.0µg/LTrichloroethene 70-130 2.4 20.0
19.4 97.010320.620.0µg/LTrichlorofluoromethane 60-140 6.0 20.0
21.8 10999.519.920.0µg/L1,2,3-Trichloropropane 70-130 9.1 20.0
20.3 10210320.620.0µg/L1,2,4-Trimethylbenzene 70-130 1.4 20.0
20.8 10410220.420.0µg/L1,3,5-Trimethylbenzene 70-130 1.9 20.0
21.9 11011723.420.0µg/LVinyl Acetate 60-140 6.6 20.0
19.6 98.010020.020.0µg/LVinyl Chloride 60-140 2.0 20.0
20.8 10410220.420.0µg/Lo-Xylene 70-130 1.9 20.0
42.1 10510642.240.0µg/Lm,p-Xylene 70-130 0.2 20.0
18.7 93.598.019.620.0µg/L3,3-Dimethyl-1-butanol 70-130 4.6 20.0
98.899.04-Bromofluorobenzene (S)70-130
99.699.8Dibromofluoromethane (S)70-130
99.096.41,2-Dichloroethane - d4 (S)70-130
98.699.2Toluene-d8 (S)70-130
Page 13 of 22Date:07/26/2022 10:40 AM
Page 80 of 91
Quality Control Data
22-189-0052Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Coal & Ice
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V21263QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V21203
Associated Lab Samples: 93944, 93945, 93946, 93947
LRB-V21203 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/13/22 20:3510.07.12<7.12µg/LAcenaphthene
07/13/22 20:3520.06.94<6.94µg/LAcenaphthylene
07/13/22 20:3510.06.57<6.57µg/LAnthracene
07/13/22 20:3510.05.08<5.08µg/LBenzidine
07/13/22 20:3510.06.65<6.65µg/LBenzo(a)anthracene
07/13/22 20:3510.04.67<4.67µg/LBenzo(a)pyrene
07/13/22 20:3510.04.52<4.52µg/LBenzo(b)fluoranthene
07/13/22 20:3510.04.24<4.24µg/LBenzo(g,h,i)perylene
07/13/22 20:3510.04.86<4.86µg/LBenzo(k)fluoranthene
07/13/22 20:3550.011.5<11.5µg/LBenzoic Acid
07/13/22 20:3510.08.60<8.60µg/LBenzyl alcohol
07/13/22 20:3510.05.67<5.67µg/LBis(2-Chloroethoxy)methane
07/13/22 20:3510.07.30<7.30µg/LBis(2-Chloroethyl)ether
07/13/22 20:3510.06.59<6.59µg/LBis(2-Chloroisopropyl)ether
07/13/22 20:3510.08.80<8.80µg/LBis(2-ethylhexyl)phthalate
07/13/22 20:3520.06.26<6.26µg/L4-Bromophenyl phenyl ether
07/13/22 20:3510.04.53<4.53µg/LButyl benzyl phthalate
07/13/22 20:3510.05.23<5.23µg/L4-Chloro-3-methylphenol
07/13/22 20:3520.07.38<7.38µg/L2-Chloronaphthalene
07/13/22 20:3510.06.58<6.58µg/L2-Chlorophenol
07/13/22 20:3520.06.99<6.99µg/L4-Chlorophenyl phenyl ether
07/13/22 20:3510.05.38<5.38µg/LChrysene
07/13/22 20:3520.06.01<6.01µg/LDibenz(a,h)anthracene
07/13/22 20:3520.05.08<5.08µg/LDibenzofuran
07/13/22 20:3510.05.91<5.91µg/L1,2-Dichlorobenzene
07/13/22 20:3510.05.83<5.83µg/L1,3-Dichlorobenzene
07/13/22 20:3510.05.91<5.91µg/L1,4-Dichlorobenzene
Page 14 of 22Date:07/26/2022 10:40 AM
Page 81 of 91
Quality Control Data
22-189-0052Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Coal & Ice
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V21263QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V21203
Associated Lab Samples: 93944, 93945, 93946, 93947
LRB-V21203 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/13/22 20:3510.06.60<6.60µg/L3,3'-Dichlorobenzidine
07/13/22 20:3510.05.54<5.54µg/L2,4-Dichlorophenol
07/13/22 20:3520.09.35<9.35µg/LDiethyl phthalate
07/13/22 20:3510.07.82<7.82µg/LDimethyl phthalate
07/13/22 20:3520.010.9<10.9µg/L2,4-Dimethylphenol
07/13/22 20:3510.07.35<7.35µg/LDi-n-butyl phthalate
07/13/22 20:3530.09.92<9.92µg/L4,6-Dinitro-2-methylphenol
07/13/22 20:3530.010.6<10.6µg/L2,4-Dinitrophenol
07/13/22 20:3510.05.20<5.20µg/L2,4-Dinitrotoluene
07/13/22 20:3520.05.90<5.90µg/L2,6-Dinitrotoluene
07/13/22 20:3510.05.01<5.01µg/LDi-n-Octyl Phthalate
07/13/22 20:3510.06.03<6.03µg/LFluoranthene
07/13/22 20:3510.07.27<7.27µg/LFluorene
07/13/22 20:3520.05.75<5.75µg/LHexachlorobenzene
07/13/22 20:3520.05.88<5.88µg/LHexachlorobutadiene
07/13/22 20:3520.05.90<5.90µg/LHexachlorocyclopentadiene
07/13/22 20:3510.05.22<5.22µg/LHexachloroethane
07/13/22 20:3510.06.20<6.20µg/LIndeno(1,2,3-cd)pyrene
07/13/22 20:3510.06.71<6.71µg/LIsophorone
07/13/22 20:3510.07.88<7.88µg/LNaphthalene
07/13/22 20:3510.07.88<7.88µg/LNitrobenzene
07/13/22 20:3510.05.49<5.49µg/L2-Nitrophenol
07/13/22 20:3510.02.81<2.81µg/L4-Nitrophenol
07/13/22 20:3520.010.9<10.9µg/LN-Nitrosodiphenylamine
07/13/22 20:3520.08.10<8.10µg/LN-Nitroso-di-n-propylamine
07/13/22 20:3550.09.73<9.73µg/LPentachlorophenol
07/13/22 20:3510.06.34<6.34µg/LPhenanthrene
Page 15 of 22Date:07/26/2022 10:40 AM
Page 82 of 91
Quality Control Data
22-189-0052Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Coal & Ice
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V21263QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V21203
Associated Lab Samples: 93944, 93945, 93946, 93947
LRB-V21203 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/13/22 20:3510.02.86<2.86µg/LPhenol
07/13/22 20:3510.05.42<5.42µg/LPyrene
07/13/22 20:3510.06.25<6.25µg/L1,2,4-Trichlorobenzene
07/13/22 20:3520.06.29<6.29µg/L2,4,6-Trichlorophenol
07/13/22 20:352-Fluorobiphenyl (S)60.4 49-118
07/13/22 20:352-Fluorophenol (S)38.4 22-84
07/13/22 20:35Nitrobenzene-d5 (S)60.2 43-123
07/13/22 20:354-Terphenyl-d14 (S)79.6 49-151
07/13/22 20:352,4,6-Tribromophenol (S)70.6 31-144
07/13/22 20:35Phenol-d5 (S)23.9 10-63
LCS-V21203 LCSD-V21203Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
24.3 48.654.627.350.0µg/LAcenaphthene 47-145 11.6 20.0
24.8 49.654.227.150.0µg/LAcenaphthylene 33-145 8.8 20.0
27.4 54.862.031.050.0µg/LAnthracene 27-133 12.3 20.0
21.1 42.246.023.050.0µg/LBenzidine 15-150 8.6 20.0
29.0 58.066.433.250.0µg/LBenzo(a)anthracene 33-143 13.5 20.0
30.9 61.870.235.150.0µg/LBenzo(a)pyrene 17-163 12.7 20.0
33.2 66.475.437.750.0µg/LBenzo(b)fluoranthene 24-159 12.6 20.0
29.6 59.267.233.650.0µg/LBenzo(g,h,i)perylene 10-219 12.6 20.0
32.1 64.273.036.550.0µg/LBenzo(k)fluoranthene 11-162 12.8 20.0
<11.5 0.0*0.0*<11.550.0µg/LBenzoic Acid 10-125 0.0 20.0
22.2 44.449.424.750.0µg/LBenzyl alcohol 16-107 10.6 20.0
22.5 45.048.024.050.0µg/LBis(2-Chloroethoxy)methane 33-184 6.4 20.0
Page 16 of 22* QC Fail Date:07/26/2022 10:40 AM
Page 83 of 91
Quality Control Data
22-189-0052Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Coal & Ice
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V21263QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V21203
LCS-V21203 LCSD-V21203Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.2 40.447.623.850.0µg/LBis(2-Chloroethyl)ether 12-158 16.3 20.0
19.8 39.646.423.250.0µg/LBis(2-Chloroisopropyl)ether 36-166 15.8 20.0
33.9 67.877.838.950.0µg/LBis(2-ethylhexyl)phthalate 10-158 13.7 20.0
27.7 55.458.229.150.0µg/L4-Bromophenyl phenyl ether 53-127 4.9 20.0
32.2 64.475.237.650.0µg/LButyl benzyl phthalate 10-152 15.4 20.0
24.0 48.051.825.950.0µg/L4-Chloro-3-methylphenol 22-147 7.6 20.0
22.7 45.4*51.4*25.750.0µg/L2-Chloronaphthalene 60-118 12.3 20.0
19.4 38.845.022.550.0µg/L2-Chlorophenol 23-134 14.7 20.0
25.7 51.455.427.750.0µg/L4-Chlorophenyl phenyl ether 25-158 7.4 20.0
29.7 59.468.434.250.0µg/LChrysene 17-168 14.0 20.0
27.3 54.662.231.150.0µg/LDibenz(a,h)anthracene 10-227 13.0 20.0
25.0 50.054.227.150.0µg/LDibenzofuran 39-114 8.0 20.0
16.5 33.038.819.450.0µg/L1,2-Dichlorobenzene 32-129 16.1 20.0
15.1 30.235.617.850.0µg/L1,3-Dichlorobenzene 20-124 16.4 20.0
15.1 30.235.617.850.0µg/L1,4-Dichlorobenzene 20-124 16.4 20.0
25.1 50.257.428.750.0µg/L3,3'-Dichlorobenzidine 10-262 13.3 20.0
21.4 42.847.423.750.0µg/L2,4-Dichlorophenol 39-135 10.1 20.0
30.0 60.066.433.250.0µg/LDiethyl phthalate 10-114 10.1 20.0
28.8 57.663.631.850.0µg/LDimethyl phthalate 10-112 9.9 20.0
24.5 49.053.226.650.0µg/L2,4-Dimethylphenol 32-119 8.2 20.0
34.9 69.878.239.150.0µg/LDi-n-butyl phthalate 10-118 11.3 20.0
30.0 60.065.432.750.0µg/L4,6-Dinitro-2-methylphenol 10-181 8.6 20.0
19.7 39.449.424.750.0µg/L2,4-Dinitrophenol 10-191 22.5*20.0
31.1 62.269.434.750.0µg/L2,4-Dinitrotoluene 39-139 10.9 20.0
30.1 60.266.633.350.0µg/L2,6-Dinitrotoluene 50-158 10.0 20.0
30.1 60.269.434.750.0µg/LDi-n-Octyl Phthalate 10-146 14.1 20.0
Page 17 of 22* QC Fail Date:07/26/2022 10:40 AM
Page 84 of 91
Quality Control Data
22-189-0052Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Coal & Ice
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V21263QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V21203
LCS-V21203 LCSD-V21203Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
31.0 62.069.634.850.0µg/LFluoranthene 26-137 11.5 20.0
26.8 53.6*58.6*29.350.0µg/LFluorene 59-121 8.9 20.0
28.0 56.061.030.550.0µg/LHexachlorobenzene 10-152 8.5 20.0
13.3 26.631.815.950.0µg/LHexachlorobutadiene 24-116 17.8 20.0
6.38 12.7*14.5*7.2650.0µg/LHexachlorocyclopentadiene 32-117 12.9 20.0
13.8 27.6*34.0*17.050.0µg/LHexachloroethane 40-113 20.7*20.0
28.8 57.665.432.750.0µg/LIndeno(1,2,3-cd)pyrene 10-171 12.6 20.0
21.9 43.846.423.250.0µg/LIsophorone 21-196 5.7 20.0
18.6 37.242.421.250.0µg/LNaphthalene 21-133 13.0 20.0
19.7 39.443.821.950.0µg/LNitrobenzene 35-180 10.5 20.0
19.5 39.045.222.650.0µg/L2-Nitrophenol 29-182 14.7 20.0
10.3 20.624.012.050.0µg/L4-Nitrophenol 10-132 15.2 20.0
33.1 66.2*71.235.650.0µg/LN-Nitrosodiphenylamine 69-152 7.2 20.0
22.5 45.049.424.750.0µg/LN-Nitroso-di-n-propylamine 10-230 9.3 20.0
34.3 68.676.438.250.0µg/LPentachlorophenol 14-176 10.7 20.0
29.1 58.264.432.250.0µg/LPhenanthrene 54-120 10.1 20.0
8.30 16.619.19.5950.0µg/LPhenol 10-112 14.4 20.0
29.8 59.667.833.950.0µg/LPyrene 52-115 12.8 20.0
16.4 32.8*36.8*18.450.0µg/L1,2,4-Trichlorobenzene 44-142 11.4 20.0
25.1 50.255.227.650.0µg/L2,4,6-Trichlorophenol 37-144 9.4 20.0
44.2*49.82-Fluorobiphenyl (S)49-118
23.227.32-Fluorophenol (S)22-84
38.0*42.6*Nitrobenzene-d5 (S)43-123
60.870.64-Terphenyl-d14 (S)49-151
59.867.62,4,6-Tribromophenol (S)31-144
Page 18 of 22* QC Fail Date:07/26/2022 10:40 AM
Page 85 of 91
Quality Control Data
22-189-0052Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Coal & Ice
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V21263QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V21203
LCS-V21203 LCSD-V21203Laboratory Control Sample & LCSD
LCSD
ResultParameter
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
15.617.8Phenol-d5 (S)10-63
Page 19 of 22Date:07/26/2022 10:40 AM
Page 86 of 91
Quality Control Data
22-189-0052Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Coal & Ice
QC Prep Batch Method:
EDB and DBCP by Microextraction GC/ECD
EPA-504.1
V21719QC Analytical Batch(es):
Analysis Method:
Analysis Description:
EPA-504.1(PREP)
QC Prep:V21593
Associated Lab Samples: 93944, 93945, 93946, 93947
LRB-V21593 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
07/20/22 19:480.02000.00330<0.00330µg/L1,2-Dibromoethane
LCS-V21593 LCSD-V21593Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.235 94.01000.2500.250µg/L1,2-Dibromoethane 70-130 6.1 20.0
V 93936-DUP-V21593Duplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 07/20/22 22:470.0<0.0207< 0.0207µg/L1,2-Dibromoethane
V 93935-MS-V21593Matrix Spike
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
0.230 89.80.256< 0.00338µg/L1,2-Dibromoethane 70-130
Page 20 of 22Date:07/26/2022 10:40 AM
Page 87 of 91
Quality Control Data
22-189-0052Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Coal & Ice
QC Prep Batch Method:
Massachusetts EPH
MADEP-EPH
V21698QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAEPH (Prep)
QC Prep:V21273
Associated Lab Samples: 93944, 93945, 93946, 93947
LRB-V21273 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/21/22 16:5535028.240.2µg/LAliphatic C9-C18
07/21/22 16:55500124<124µg/LAliphatic C19-C36
07/21/22 16:5525061.2<61.2µg/LAromatic C11-C22
07/21/22 16:552-Fluorobiphenyl (S)78.2 40-140
07/21/22 16:552-Bromonaphthalene (S)76.7 40-140
07/21/22 16:55Chlorooctadecane (S)48.2 40-140
07/21/22 16:55OTP Surrogate (S)50.5 40-140
LCS-V21273 LCSD-V21273Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
373 62.157.1343600µg/LAliphatic C9-C18 40-140 8.3 50.0
500 62.555.1441800µg/LAliphatic C19-C36 40-140 12.5 50.0
1490 87.677.013101700µg/LAromatic C11-C22 40-140 12.8 50.0
82.582.72-Fluorobiphenyl (S)40-140
86.568.22-Bromonaphthalene (S)40-140
53.547.8Chlorooctadecane (S)40-140
61.055.5OTP Surrogate (S)40-140
Page 21 of 22Date:07/26/2022 10:40 AM
Page 88 of 91
Quality Control Data
22-189-0052Report No:
Project Description:
Client ID:Geological Resources, Inc.
Rose Coal & Ice
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V21178QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V21177
Associated Lab Samples: 93944, 93945, 93946, 93947
LRB-V21177 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/12/22 16:0950.011.5<11.5µg/LAliphatic C5-C8
07/12/22 16:0950.025.8<25.8µg/LAliphatic C9-C12
07/12/22 16:0950.04.02<4.02µg/LAromatic C9-C10
07/12/22 16:092,5-Dibromotoluene (FID) (S)81.8 70-130
07/12/22 16:092,5-Dibromotoluene (PID) (S)78.0 70-130
LCS-V21177 LCSD-V21177Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
253 84.383.6251300µg/LAliphatic C5-C8 70-130 0.7 50.0
344 115114343300µg/LAliphatic C9-C12 70-130 0.2 50.0
112 112106106100µg/LAromatic C9-C10 70-130 5.5 50.0
82.678.52,5-Dibromotoluene (FID) (S)70-130
83.979.32,5-Dibromotoluene (PID) (S)70-130
Page 22 of 22Date:07/26/2022 10:40 AM
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Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:22-189-0052
Geological Resources, Inc.
00087
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT15 1.0C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Danyale Love Date & Time:07/08/2022 20:05:14
Special precautions or instructions included?
Comments:
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