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HomeMy WebLinkAbout25063 - Simpson Texaco_VIMP Addendum 20230327 Via Email March 27, 2023 North Carolina Department of Environmental Quality Division of Waste Management – Brownfields Program 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Attn: Mr. Bill Schmithorst, PG Re: Vapor Intrusion Mitigation Plan Addendum Simpson’s Texaco Service South Boulevard and Scaleybark Road Charlotte, North Carolina Brownfields Project No. 25063-21-060 H&H Job No. EMB-002 Dear Bill: 1.0 Introduction Hart & Hickman, PC (H&H) has prepared this Vapor Intrusion Mitigation Plan Addendum (VIMP Addendum) on behalf of Embrey Partners, LLC and its single purpose entity Scaleybark CLT, LLC (Prospective Developer or PD) for the Simpson’s Texaco Service Brownfields property (Brownfields Project No. 25063-21-060) located at 4001 South Boulevard, at the intersection of South Boulevard and Scaleybark Road in Charlotte, Mecklenburg County, North Carolina (Site or subject Site). The proposed Site redevelopment includes construction of an approximately 28,100 square foot (sq ft) high-density multifamily residential apartment complex with amenity spaces and a multi-level parking garage. A Site Location Map is provided as Figure 1. Mr. Bill Schmithorst #C-1269 Engineering March 27, 2023 Page 2 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Embrey (EMB)/EMB.002 South Boulevard Assembly/VIMP/Addendum/25063 - Simpson Texaco_VIMP Addendum.doc To address potential vapor intrusion concerns for the building, H&H prepared a VIMP and revisions to the VIMP based on DEQ comments. In a letter dated October 21, 2022, the DEQ Brownfields Program provided approval of the revised VIMP dated August 26, 2022. The VIMP included installation of a vapor intrusion mitigation system (VIMS) designed to minimize potential vapor intrusion into the Site building using passive sub-slab venting. The passive sub-slab venting system includes a network of horizontal piping installed beneath the slab of the building with passive turbine ventilators installed on the discharge end of the vertical riser exhaust piping above the building roofline to further promote air exhaust from the risers. In addition to the sub-slab depressurization system, the VIMS includes Raven Industries VaporBlock Plus 20 (VBP20) vapor barrier installed under the ground floor of the residential apartment building. The VIMP specified installation of vapor barrier beneath the base slab and along the exterior of the vertical sidewalls of the elevator pit. However, the elevator pits at two elevator locations, Elevators E100 and E300, were poured without installation of the vapor barrier along the base and sides of the pit. Based on conversations with the general contractor, it is our understanding that the specified vapor barrier was not installed along the exterior walls and base of the elevator pit, however the pit was lined along the exterior with a waterproofing barrier. Because the vapor barrier specified in the VIMP was not installed, the PD is proposing to install Retro-Coat™ vapor barrier system to further protect against potential vapor intrusion in the elevator pit. For consistency in the VIMS installation, the PD has proposed to install the Retro-Coat vapor barrier system in all four elevators (E100 through E400). The locations of the elevator pits are shown on the design sheet (VM-ADD) in Appendix A. Mr. Bill Schmithorst #C-1269 Engineering March 27, 2023 Page 3 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Embrey (EMB)/EMB.002 South Boulevard Assembly/VIMP/Addendum/25063 - Simpson Texaco_VIMP Addendum.doc 2.0 Proposed VIMS Activities The proposed VIMS activities include application of Retro-Coat in the elevator pits, as further described below. The locations of the elevator pits and details showing the installation modification is included on Sheet VM-ADD in Attachment A. Retro-Coat specifications and installation instructions are included in Attachment B. Retro-Coat Application in Elevator Pit Retro-Coat is a volatile organic compound rated engineered vapor barrier, similar in function to MonoShield®, which includes a Retro-Coat Primer layer and the final Retro-Coat layer. According to manufacturer installation instructions, the Retro-Coat PRIMER should be installed at a thickness of approximately 6-mil and allowed to dry prior to application of the Retro-Coat layer. The Retro-Coat layer is a mixture of Retro-Coat “A”, a modified epoxy, and Retro-Coat “B”, a blend of hardeners. Retro-Coat “A” and Retro-Coat “B” should be mixed in the field in accordance with the installation instructions and following completion of mixing, the Retro-Coat is applied over the Retro-Coat PRIMER at a minimum thickness of 20-mil. The concrete surface on the elevator pit interior will be properly prepared in accordance with the manufacturer instructions prior to the application of the Retro-Coat PRIMER and Retro-Coat. As discussed above, the waterproofing for the elevator pit was installed to the exterior of the elevator pit. Based on information provided by the construction contractor, the installed waterproofing system is the Polyguard Waterproofing System. Product specifications for the installed waterproofing system are included in Attachment C. Inspections The Retro-Coat barrier system shall be installed by a certified Retro-Coat Applicator in accordance with manufacturer recommendations and specifications. For quality assurance and quality control (QA/QC) purposes, periodic inspections will be conducted during installation of the Retro-Coat™ vapor barrier. The inspections will be performed by, or under the direction of, a North Carolina licensed professional engineer. DEQ will be notified 48 hours prior to the start of the Retro-Coat installation activities. Copyright:© 2013 National Geographic Society, i-cubed SITE LOCATION MAP SIMPSON'S TEXACO SERVICESOUTH BOULEVARD & SCALEYBARK ROAD CHARLOTTE, NORTH CAROLINA DATE: 3-17-23 JOB NO: EMB-002 REVISION NO: 0 FIGURE NO: 1 2923 South Tryon Street - Suite 100Charlotte, North Carolina 28203704-586-0007 (p) 704-586-0373 (f)License # C-1269 / # C-245 Geology TITLE PROJECT 0 2,000 4,000 SCALE IN FEET SITE Path: S:\AAA-Master Projects\Embrey\South Boulevard Assembly\Figures\Figure-1.mxdN U.S.G.S. QUADRANGLE MAP CHARLOTTE WEST, NORTH CAROLINA 2013CHARLOTTE EAST, NORTH CAROLINA 2013 QUADRANGLE7.5 MINUTE SERIES (TOPOGRAPHIC) Attachment A VIMP Addendum Design Sheets 4.6% UP 751.00' 750.50' 740.50' 742.00' 742.00' 2.6% UP 751.00' 8. 0% UP 8. 0% U P 8. 0% U P 744.00' 12.0% UP 751.00' 12.0% UP 751.00' 749.00' 750.00'751.00'7.1% UP 744.00' 2. 8% U P 750.00' 8. 0% U P 750.00' 750.00' 750.00' 748.00' 748.00' 747.00' 746.00' 0.9% UP 750.00' 750.00' 750.00'750.00' 746.00' 748.75'750.00' 5.4% UP 743.25'742.00' 746.00' 744.00' 746.00' 744.00' 5.5% UP 5.5% UP 6.8% DN7.8% DN 751.00' 5.5% UP 3.8% UP8.1%747.00' 749.00' 749.42'748.84' 742.00' 744.00' UNIT A1SSHEET A4.11S UNIT A1SSHEET A4.11S UNIT A1SSHEET A4.11S UNIT A2S-ASHEET A4.43ANSI TYPE 'A' UNIT S4MSHEET A4.04P UNIT S2.1MSHEET A4.02P UNIT B1.1S-ASHEET A4.44ANSI TYPE 'A' UNIT B1.1SSHEET A4.31P UNIT B1.1S-ASHEET A4.44ANSI TYPE 'A'UNIT A5MSHEET A4.33P UNIT A1.3SSHEET A4.11P UNIT A1.3SSHEET A4.11P UNIT S1.1MSHEET A4.01P E100 E200 E300 ST100 ST200 ST300 ST400 ST500 FW PUMP RM DW PUMP RM MAINT. ELEC RM 1 PET SPA E400 LOADING DOCKT/R RM 2 T/R RM 1 ELEC RM 2 LOBBY LOBBY UNIT A1SSHEET A4.11S UNIT A1SSHEET A4.11S UNIT A1.2MSHEET A4.11P UNIT B1.1SSHEET A4.31P UNIT B1.1SSHEET A4.31P UNIT A6MSHEET A4.16P MECH DOG PARK 3,801 SF STOR.BIKE STORAGE 1 MECH LOBBY MECH ERRCSERRCS E-2 E-5 E-6 E-4 E-3 E-7 E-8 E-1 E-9 MP-1 MP-2 MP-4 MP-3 MP-5 MP-7 MP-8 MP-10 MP-9 MP-11 MP-13 MP-12 MP-6 VIMS BELOW ELEVATOR PIT NTS 1 SUMP PIT VM-ADD ELEVATOR PIT VAPORBLOCK PLUS 20 VAPOR BARRIER SEALED TO TOP OF ELEVATOR WALL PER MANUFACTURERINSTRUCTIONS RETROCOAT SYSTEMAPPLIED ABOVE TOP OFELEVATOR WALL CRYSTALLINE WATERPROOFINGRETROCOAT PRIMER RETROCOAT SEE DETAIL 2/VM-ADD 2 VM-ADD SOIL BACKFILL RETRO-COAT (20-MIL) RETRO-COAT PRIMER (6-MIL) CONCRETE NTS VIMS AT ELEVATOR PIT - WATERPROOFING DETAIL (TYP) CRYSTALLINE WATERPROOFING MEMBRANE ADHERED TO CONCRETE ELEVATOR PITINTERIOR H&H NO. EMB-002 VAPOR MITIGATION PLANPREPARED BY: 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology VAPOR INTRUSION MITIGATION SYSTEM VIMS AT ELEVATOR PIT MODIFICATION LEVEL 1LOSO EPL4001 SOUTH BOULEVARDCHARLOTTE, NORTH CAROLINABROWNFIELDS PROJECT NO. 25063-21-060VM-ADD PROFESSIONAL APPROVAL LEGEND SLAB GRADE CHANGE COLUMN AND FOOTING OUTDOOR OR OPEN AIR SPACE PROPOSED TOP OF SLAB ELEVATION. REFER TO STRUCTURAL CONSTRUCTIONDRAWINGS FOR FINAL ELEVATIONS. EXTENT OF VAPOR LINER HORIZONTAL COLLECTION PIPING OR SOIL GAS COLLECTOR MAT 3" DIA SCH 40 SOLID PVC PIPE 4" DIA SCH 40 SOLID PVC VERTICAL RISER WITH EXHAUST IDENTIFICATION NUMBER 2" DIA SOLID PVC PRESSURE MONITORING POINT WITH FLUSH-MOUNTED COVER ELEVATOR PIT WITH VAPOR BARRIER SYSTEM APPLIED TO INTERIOR OF PIT E-7 MP-4 XXX.XX NOTES: 1.MONITORING POINTS LOCATED ON CORRIDOR WALLS MUST EXTEND INTO TENANT UNIT SPACE (≈6 FT FROM CORRIDOR WALL). 2.THE INTAKE OF MONITORING POINTS SHALL BE A MINIMUM 5 FT FROM EXTERIOR WALLS / FOOTINGS. DEVELOPER: EMBREY PARTNERS 1020 NE INTERSTATE 410 LOOP #700 SAN ANTONIO, TEXAS DATE: 3-27-23 REVISIONS REV DATE DESCRIPTION 0 6/21/22 DEQ SUBMITTAL 1 8/26/22 DEQ COMMENTS ADD 3/27/23 VIMP ADDENDUM 1/2 VMADD 1/2 VMADD 1/2 VMADD 1/2 VMADD S:\AAA-Master Projects\Embrey (EMB)\EMB.002 South Boulevard Assembly\VIMP\Figures\VIMS Design_R0.dwg, VM-ADD-3, 3/27/2023 4:07:58 PM, amckenzie Attachment B Retro-Coat Specifications and Installation Instructions © 2012 Land Science Technologies www.landsciencetech.com (949) 481-8118. 4/12 Chemical Resistance Vapor Intrusion Coating System for Existing Structures Product Description The Retro-Coat™ (patent pending) Vapor Intrusion Coating System is a complete product line that consists of chemically resistant materials to properly protect existing structures from the threat of contaminant vapor intrusion without the need for additional concrete protection. Developed by the R&D team of Land Science Technologies™, the Retro-Coat system has been subjected to rigorous testing procedures to prove its ability to combat the most aggressive chemical vapors. The main component of the Retro-Coat system is the Retro-Coat coating which is a two part, odorless, no VOC, 100% solids coating. Retro-Coat finishes to a high gloss, easy-to-clean surface that is impervious to vapor and moisture transmission. Available in a variety of colors, Retro-Coat can be applied on damp as well as dry concrete, concrete masonry units, tile, brick and metal. For enhanced slip resistance, a suitable aggregate can be added. In addition, other additives or materials can be utilized to achieve a desired performance or aesthetic look. Typical Application Retro-Coat is suitable as a barrier to block contaminated vapors from entering existing structures. Particular uses include coating the horizontal surfaces of existing structures where contamination under, or adjacent to, a structure can potentially migrate inside the structure and create a vapor encroachment condition. This condition is most commonly found when the existing structure was operated as a dry cleaner, gas station, manufacturing facility or located in close proximity to any structure where carcinogenic chemicals were utilized. A typical application consists of a minimum 20 mil thick system; consisting of two 10 mil coats of Retro-Coat at 160 SF/gallon per coat and is recommended along with a 6 mil coat of Retro-Coat PRIMER. The typical 20 mil application can withstand forklift traffic, other machinery and even act as secondary containment. However, if Retro-Coat may be exposed to more harsh conditions over a longer period of time, thicker applications ranging from 60 mil to ¼ -inch may be more suitable. In either application, Retro-Coat is a traffic bearing surface and does not need a protective course placed over it. Retro-Coat Advantages • Our R&D team developed all of the Retro-Coat system components specifically for vapor intrusion protection in existing structures • Retro-Coat is resistant to both TCE and PCE, the vast majority of coatings cringe at such aggressive chemicals • Retro-Coat is a wearing surface, meaning no additional concrete protection is necessary • No odor and fast cure time reduce building downtime • Carpet, tile, linoleum or other floor coverings can be applied directly over Retro-Coat, if desired • Eliminates the need to remove the existing slab and when combined with in-situ treatment, lowers overall remediation cost • Retro-Coat can increase the performance of an existing active sub- slab depressurization system • Retro-Coat can aid in the retiring of existing active systems • Available and installed by Land Science Technologies certified contractors © 2012 Land Science Technologies www.landsciencetech.com (949) 481-8118. 4/12 Installation Particular care must be taken to follow those instructions precisely to assure proper installation. These instructions pertain to a standard 20 mil application; please contact us if the desired application is different. 1. New concrete should be allowed to cure a minimum of 28 days and/or be checked with a rubber mat or plastic sheet to ensure adequate curing time has occurred. 2. All surfaces to be covered should be power washed, shot blasted, acid etched, scarified or sanded to present a clean, sound substrate to which to bond to. The prepared surface should have a ph of 7. 3. Any bugholes and cracks wider than 1/8” should be filled with Retro-Coat PREP and allowed to dry before coating. More severely damaged concrete or other special conditions will require the proper Retro-Coat product. 4. When installing the standard 20 mil application of Retro-Coat, apply a 6 mil coat of Retro-Coat PRIMER and allow to dry prior to applying the initial coat of Retro-Coat. Priming may not be necessary when Retro-Coat is applied to a thickness greater than 20 mils. On new concrete or old concrete with an open porosity and on wood surfaces apply Retro-Coat PRIMER and allow to dry. 5. The two Retro-Coat ingredients should be mixed in the prescribed ratios, using a low speed “jiffy-style” mixer, (maximum 750 rpm). Mix Part A for about 1 minute then, add Part B and mix until uniform in color and consistency (at least one additional minute.) 6. Do not mix less than the prescribed amount of any ingredient or add any solvent to the mix. 7. Apply the mixed Retro-Coat material with a short nap roller, a squeegee or a brush. Apply approximately 160 SF per gallon per coat to achieve 10 mils of coating. 8. Apply a second coat while the first coat is still tacky if using spike shoes or dry enough to walk on, but before 7 hours at 75oF. If the first coat has set and is no longer tacky then the first coat should be sanded before recoating. 9. A suitable aggregate may be broadcast onto the surface after backrolling to provide more anti-slip profile to the finished surface. It is advisable to test various types and sizes of aggregate to achieve the desired finished profile. Product Specification The specified area shall receive an application of Retro-Coat as manufactured by Land Science Technologies, San Clemente, California. The material shall be installed by precisely following the manufacturer’s published recommendations pertaining to surface preparation, mixing and application. The material shall be a low odor, two part, solvent free 100% solids, high gloss flexibilized system with good resilience to resist thermal and mechanical shock. It should be able to be roller applied at a minimum of 10 mils thickness per coat on vertical surfaces without sagging (at ambient conditions). The system must adhere to damp as well as dry concrete, wood, metal tile, terrazzo and sound existing epoxy and urethane coatings. It shall have tensile elongation of at least 6.0% when tested under ASTM-638. Its bond strength to quarry tile shall exceed 1000 psi when tested with an Elcometer pull test. Its hardness shall not exceed 83, as measured on the Shore D scale. The system shall be unaffected by oils and greases and shall withstand chemical attack for at least 72 hours against 98% sulfuric, 50% hydrofluoric acid, glacial acetic acid and acrylonitrile. Application of Retro-Coat SEALANT to a 20 mil total thickness Completed surface preparation consisting of shot blasting, Retro-Coat PREP to fill joints and cracks and a 6 mil application of Retro-Coat PRIMER © 2012 Land Science Technologies www.landsciencetech.com (949) 481-8118. 4/12 Precautions 1. This is a fast reacting product; immediately pour onto floor after mixing and spread with notched squeegee. Recoat window without sanding at 70oF: 8 hours 2. A severe skin and eye irritant; check MSDS before use 3. Do not apply below 50oF Note: Failure to follow the above instruction, unless expressly authorized by a Land Science Technologies Representative, will void our material warranty. Chemical Resistance Retro-Coat™ is considered chemically resistant to neat concentrated acids, caustics and solvents. For permeation or diffusion coefficients please contact Land Science Technologies. Physical Properties Tensile Strength (ASTM D-638) : 9800 psi Bond Strength to Quarry Tile : >1000 psi Tensile Elongation (D-638) : 6.0% Vapor Transmission Rate (E-96) : .027 perms Flexural Strength (D-790) : 7035 psi Water Absorption (D-570) : 0.2% in 24hrs. Hardness, Shore D (D-2240) : 83 Taber Abrasion (D-1044) : 86 mg loss. Gardner Impact Strength (D-2794) : 80 in. lbs. 60o Gloss : 100 Physical Characteristics Density, lbs/gal. Mixing Ratios By Volume By Weight Pt. A : 11.0 Pt. A : Pt. B 2:1 2.3:1 Pt. B : 8.9 A&B Mixed : 9.3 Curing Times @ 50o F 77oF 90oF Viscosity @ 77oF, cps Pot Life 35 min. 30 min. 20 min. Pt. A : 18,400 Working Times 20 min. 20 min. 15 min. Pt. B : 500 Hard, Foot Traffic 14 hrs. 7 hrs. 3 ½ hrs. A&B Mixed : 4800 Maximum hardness and chemical resistance are achieved after 7 days at 77oF Color Availability Packaging and Coverage Rates (for 20 mil coverage) Standard colors: beige, black, blue, dark gray, 4 Gallon Kit : 320 SF green, gray, red, white, yellow 20 Gallon Kit : 1600 SF Shelf Life: 1 Year at 77oF in unopened containers 100 Gallon Kit : 8,000 SF The data, statements and recommendations set forth in this product information sheet are based on testing, research and other development work which has been carefully conducted by Land Science Technologies, and we believe such data, statements and recommendations will serve as reliable guidelines. However, this product is subject to numerable uses under varying conditions over which we have no control, and accordingly, we do NOT warrant that this product is suitable for any particular use. Users are advised to test the product in advance to make certain it is suitable for their particular production conditions and particular use or uses. WARRANTY – All products manufactured by us are warranted to be first class material and free from defects in material and workmanship. Liability under this warranty is limited to the net purchase price of any such products proven defective or, at our option, to the repair or replacement of said products upon their return to us transportation prepaid. All claims hereunder on defective products must be made in writing within 30 days after the receipt of such products in your plant and prior to further processing or combining with other materials and products. WE MAKE NO WARRANTY, EXPRESS OR IMPLIED, AS TO THE SUITABILITY OF ANY OF OUR PRODUCTS FOR ANY PARTICULAR USE, AND WE SHALL NOT BE SUBJECT TO LIABILITY FROM ANY DAMAGES RESULTING FROM THEIR USE IN OPERATIONS NOT UNDER OUR DIRECT CONTROL. THIS WARRANTY IS EXCLUSIVE OF ALL OTHER WARRANTIES, EXPRESS OR IMPLIED, AND NO REPRESENTATIVE OF OURS OR ANY OTHER PERSON IS AUTHORIZED TO ASSUME FOR US ANY OTHER LIABILITY IN CONNECTION WITH THE SALE OF OUR PRODUCTS. © 2012 Land Science Technologies www.landsciencetech.com (949) 481-8118. 4/12 Chemical Resistance Vapor Intrusion Coating System for Existing Structures Product Description The Retro-Coat™ (patent pending) Vapor Intrusion Coating System is a complete product line that consists of chemically resistant materials to properly protect existing structures from the threat of contaminant vapor intrusion without the need for additional concrete protection. Developed by the R&D team of Land Science Technologies™, the Retro-Coat system has been subjected to rigorous testing procedures to prove its ability to combat the most aggressive chemical vapors. The main component of the Retro-Coat system is the Retro-Coat coating which is a two part, odorless, no VOC, 100% solids coating. Retro-Coat finishes to a high gloss, easy-to-clean surface that is impervious to vapor and moisture transmission. Available in a variety of colors, Retro-Coat can be applied on damp as well as dry concrete, concrete masonry units, tile, brick and metal. For enhanced slip resistance, a suitable aggregate can be added. In addition, other additives or materials can be utilized to achieve a desired performance or aesthetic look. Typical Application Retro-Coat is suitable as a barrier to block contaminated vapors from entering existing structures. Particular uses include coating the horizontal surfaces of existing structures where contamination under, or adjacent to, a structure can potentially migrate inside the structure and create a vapor encroachment condition. This condition is most commonly found when the existing structure was operated as a dry cleaner, gas station, manufacturing facility or located in close proximity to any structure where carcinogenic chemicals were utilized. A typical application consists of a minimum 20 mil thick system; consisting of two 10 mil coats of Retro-Coat at 160 SF/gallon per coat and is recommended along with a 6 mil coat of Retro-Coat PRIMER. The typical 20 mil application can withstand forklift traffic, other machinery and even act as secondary containment. However, if Retro-Coat may be exposed to more harsh conditions over a longer period of time, thicker applications ranging from 60 mil to ¼ -inch may be more suitable. In either application, Retro-Coat is a traffic bearing surface and does not need a protective course placed over it. Retro-Coat Advantages • Our R&D team developed all of the Retro-Coat system components specifically for vapor intrusion protection in existing structures • Retro-Coat is resistant to both TCE and PCE, the vast majority of coatings cringe at such aggressive chemicals • Retro-Coat is a wearing surface, meaning no additional concrete protection is necessary • No odor and fast cure time reduce building downtime • Carpet, tile, linoleum or other floor coverings can be applied directly over Retro-Coat, if desired • Eliminates the need to remove the existing slab and when combined with in-situ treatment, lowers overall remediation cost • Retro-Coat can increase the performance of an existing active sub- slab depressurization system • Retro-Coat can aid in the retiring of existing active systems • Available and installed by Land Science Technologies certified contractors © 2012 Land Science Technologies www.landsciencetech.com (949) 481-8118. 4/12 Installation Particular care must be taken to follow those instructions precisely to assure proper installation. These instructions pertain to a standard 20 mil application; please contact us if the desired application is different. 1. New concrete should be allowed to cure a minimum of 28 days and/or be checked with a rubber mat or plastic sheet to ensure adequate curing time has occurred. 2. All surfaces to be covered should be power washed, shot blasted, acid etched, scarified or sanded to present a clean, sound substrate to which to bond to. The prepared surface should have a ph of 7. 3. Any bugholes and cracks wider than 1/8” should be filled with Retro-Coat PREP and allowed to dry before coating. More severely damaged concrete or other special conditions will require the proper Retro-Coat product. 4. When installing the standard 20 mil application of Retro-Coat, apply a 6 mil coat of Retro-Coat PRIMER and allow to dry prior to applying the initial coat of Retro-Coat. Priming may not be necessary when Retro-Coat is applied to a thickness greater than 20 mils. On new concrete or old concrete with an open porosity and on wood surfaces apply Retro-Coat PRIMER and allow to dry. 5. The two Retro-Coat ingredients should be mixed in the prescribed ratios, using a low speed “jiffy-style” mixer, (maximum 750 rpm). Mix Part A for about 1 minute then, add Part B and mix until uniform in color and consistency (at least one additional minute.) 6. Do not mix less than the prescribed amount of any ingredient or add any solvent to the mix. 7. Apply the mixed Retro-Coat material with a short nap roller, a squeegee or a brush. Apply approximately 160 SF per gallon per coat to achieve 10 mils of coating. 8. Apply a second coat while the first coat is still tacky if using spike shoes or dry enough to walk on, but before 7 hours at 75oF. If the first coat has set and is no longer tacky then the first coat should be sanded before recoating. 9. A suitable aggregate may be broadcast onto the surface after backrolling to provide more anti-slip profile to the finished surface. It is advisable to test various types and sizes of aggregate to achieve the desired finished profile. Product Specification The specified area shall receive an application of Retro-Coat as manufactured by Land Science Technologies, San Clemente, California. The material shall be installed by precisely following the manufacturer’s published recommendations pertaining to surface preparation, mixing and application. The material shall be a low odor, two part, solvent free 100% solids, high gloss flexibilized system with good resilience to resist thermal and mechanical shock. It should be able to be roller applied at a minimum of 10 mils thickness per coat on vertical surfaces without sagging (at ambient conditions). The system must adhere to damp as well as dry concrete, wood, metal tile, terrazzo and sound existing epoxy and urethane coatings. It shall have tensile elongation of at least 6.0% when tested under ASTM-638. Its bond strength to quarry tile shall exceed 1000 psi when tested with an Elcometer pull test. Its hardness shall not exceed 83, as measured on the Shore D scale. The system shall be unaffected by oils and greases and shall withstand chemical attack for at least 72 hours against 98% sulfuric, 50% hydrofluoric acid, glacial acetic acid and acrylonitrile. Application of Retro-Coat SEALANT to a 20 mil total thickness Completed surface preparation consisting of shot blasting, Retro-Coat PREP to fill joints and cracks and a 6 mil application of Retro-Coat PRIMER © 2012 Land Science Technologies www.landsciencetech.com (949) 481-8118. 4/12 Precautions 1. This is a fast reacting product; immediately pour onto floor after mixing and spread with notched squeegee. Recoat window without sanding at 70oF: 8 hours 2. A severe skin and eye irritant; check MSDS before use 3. Do not apply below 50oF Note: Failure to follow the above instruction, unless expressly authorized by a Land Science Technologies Representative, will void our material warranty. Chemical Resistance Retro-Coat™ is considered chemically resistant to neat concentrated acids, caustics and solvents. For permeation or diffusion coefficients please contact Land Science Technologies. Physical Properties Tensile Strength (ASTM D-638) : 9800 psi Bond Strength to Quarry Tile : >1000 psi Tensile Elongation (D-638) : 6.0% Vapor Transmission Rate (E-96) : .027 perms Flexural Strength (D-790) : 7035 psi Water Absorption (D-570) : 0.2% in 24hrs. Hardness, Shore D (D-2240) : 83 Taber Abrasion (D-1044) : 86 mg loss. Gardner Impact Strength (D-2794) : 80 in. lbs. 60o Gloss : 100 Physical Characteristics Density, lbs/gal. Mixing Ratios By Volume By Weight Pt. A : 11.0 Pt. A : Pt. B 2:1 2.3:1 Pt. B : 8.9 A&B Mixed : 9.3 Curing Times @ 50o F 77oF 90oF Viscosity @ 77oF, cps Pot Life 35 min. 30 min. 20 min. Pt. A : 18,400 Working Times 20 min. 20 min. 15 min. Pt. B : 500 Hard, Foot Traffic 14 hrs. 7 hrs. 3 ½ hrs. A&B Mixed : 4800 Maximum hardness and chemical resistance are achieved after 7 days at 77oF Color Availability Packaging and Coverage Rates (for 20 mil coverage) Standard colors: beige, black, blue, dark gray, 4 Gallon Kit : 320 SF green, gray, red, white, yellow 20 Gallon Kit : 1600 SF Shelf Life: 1 Year at 77oF in unopened containers 100 Gallon Kit : 8,000 SF The data, statements and recommendations set forth in this product information sheet are based on testing, research and other development work which has been carefully conducted by Land Science Technologies, and we believe such data, statements and recommendations will serve as reliable guidelines. However, this product is subject to numerable uses under varying conditions over which we have no control, and accordingly, we do NOT warrant that this product is suitable for any particular use. Users are advised to test the product in advance to make certain it is suitable for their particular production conditions and particular use or uses. WARRANTY – All products manufactured by us are warranted to be first class material and free from defects in material and workmanship. Liability under this warranty is limited to the net purchase price of any such products proven defective or, at our option, to the repair or replacement of said products upon their return to us transportation prepaid. All claims hereunder on defective products must be made in writing within 30 days after the receipt of such products in your plant and prior to further processing or combining with other materials and products. WE MAKE NO WARRANTY, EXPRESS OR IMPLIED, AS TO THE SUITABILITY OF ANY OF OUR PRODUCTS FOR ANY PARTICULAR USE, AND WE SHALL NOT BE SUBJECT TO LIABILITY FROM ANY DAMAGES RESULTING FROM THEIR USE IN OPERATIONS NOT UNDER OUR DIRECT CONTROL. THIS WARRANTY IS EXCLUSIVE OF ALL OTHER WARRANTIES, EXPRESS OR IMPLIED, AND NO REPRESENTATIVE OF OURS OR ANY OTHER PERSON IS AUTHORIZED TO ASSUME FOR US ANY OTHER LIABILITY IN CONNECTION WITH THE SALE OF OUR PRODUCTS. 1 © 2012 Land Science Technologies Land Science Technologies Specifications for Retro-Coat™ Version 1.0 Part 1 – Scope 1.1 Product and Application This specification describes the application of the Retro-Coat™ System. The minimum thickness of the system is between 25-30 mils, including a 20 mil minimum application of Retro-Coat. 1.2 Acceptable Manufacturers A. Retro-Coat as manufactured by Land Science Technologies San Clemente, CA. 1.3 Performance Criteria A. Retro-Coat as manufactured by Land Science Technologies San Clemente, CA. 1. Diffusion Coefficient (Columbia Labs) PCE: 7.6 x 10-14 m2/s TCE: 8.2 x 10-14 m2/s 2. Tensile Elongation (ASTM D-638) Minimum: 6000 psi 3. Tensile Elongation (ASTM D-638) Minimum: 6 % 4. Flexural Strength (ASTM D-790) Minimum: 7000 psi 5. Hardness, Shore D (ASTM D-2240) Maximum: 85 6. Gardner Impact (ASTM D-2794) Minimum: 80 inch-pounds 7. Bond Strength to Quarry Tile Minimum: 1000 psi 8. Vapor Transmission Rate (ASTM E-96) Maximum: .07 perms 9. Water Absorption (ASTM D-570) Maximum: .02% in 24 hours 10. 60° Gloss Minimum: 100. 1.4 Materials A. Retro-Coat “A” shall be a modified epoxy containing special flexibilizers and specially formulated resins for superior chemical resistance and enhanced resilience. No solvents are allowed. B. Retro-Coat “B” shall be customized blend of hardeners specifically formulated to maximize chemical resistance. No solvents are allowed. 1.5 Applicator A. Applicator must be a certified contractor of Land Science Technologies. 2 © 2012 Land Science Technologies Part 2 – Application 2.1 Surface Preparation A. All existing surfaces that will be covered with the systems specified herein should be mechanically ground, shot blasted or sand blasted to yield a minimum 60 grit surface texture. All loosely adhered coatings will be removed. Any grease and other contaminants found on the concrete must also be removed. B. All open cracks 1/2” and greater should be v-notched to a 3/4” width by 1/2” depth and cleaned of any debris. Such cracks should be filled with Retro-Coat Gel and struck off flush with the surrounding surface. C. Cut back and/or remove any expansion joint backing or filler strips to a minimum of 1 ½” deep. Insert disposable filler in the joints to prevent filling with the overlayment materials and to allow for accurate location of final saw cuts in the overlayment. 2.2 Material Application A. Retro-Coat CAULK 1. Apply Retro-Coat CAULK around the base of all pipe penetrations making sure to fill any gap between the penetration and concrete slab 2. Apply Retro-Coat CAULK to the joint created between horizontal and vertical transitions. The caulking material should be applied and pressed into the joint filling any gaps that might be present. B. Retro-Coat PRIMER 1. Apply Retro-Coat PRIMER to all areas at a thickness of 6 mil and allow to dry tack free. In areas where the concrete surface is in need of slight repair or needs to be leveled, a slurry form of Retro-Coat PRIMER called Retro-Coat PRIMER-S can be applied with a flat squeegee. Retro-Coat PRIMER-S is self priming and does not need to be primed again. C. Retro-Coat 1. Mix Retro-Coat, Part A with a low-speed (<750 rpm) jiffy-style mixer for about 30 seconds, or until uniform in color, then mix in Retro-Coat Coating, Part B for another 30-60 seconds. 2. Dump contents onto floor in a ribbon pattern, squeegee, and then back roll at a coverage rate of 160 SF/gallon to achieve a film thickness of 10 mils. 3. Apply second coat 10 mil coat to achieve a total thickness of 20 mils. Repeat as necessary to achieve specified thickness. 4. If a flooring material will be placed over Retro-Coat after it is applied, or appearance is not a priority, (1) 20 mil coat can be applied. 2.3 Protection of Finished Work A. Prohibit foot traffic on floor for 24 hours after laying (at 70ºF). At 50ºF,this time should be extended to 48 hours. B. Rinse off any chemicals that may come in contact within 7 days of installation with the freshly laid floor immediately. 2.4 Cleanup A. Properly dispose of all unused and waste materials. B. Tools can be washed in warm, soapy water when wet, but after drying, can only be cleaned by grinding or with a paint stripper. C. Unused resin can be set off with proper amount of hardener and disposed of in regular trash bins. 3 © 2012 Land Science Technologies Part 3 – Quality Control 3.1 Warranty A. Installer shall provide a one year warranty against delamination, chemical attack and normal wear and tear. B. Manufacturer will provide a one year material warranty. 3.2 Quality Control A. Installer shall use a notched squeegee to apply Retro-Coat to the specified mil thickness and calculations shall be done to determine if the correct amount of material has been applied. Retro-Coat contains 100% solids at the time of application; therefore no material shrinkage will occur during the curing process. One gallon will cover 80 square feet. B. A wet mil film gauge can be used to spot check the Retro-Coat thickness to make certain the minimum 20 mil thickness has been applied, though some discretion should be used because high points or low points on the underlying surface can adversely affect the thickness measurements. 3.3 Floor Care A. The standard smooth surface of Retro-Coat should be cleaned on a regular basis by damp mopping the floor with conventional commercial cleaners. It is important to first remove any grease or oils by a suitable cleaner, preferably a citrus based cleaner. Rinse with clear water to help eliminate film buildup and then allow to dry. Never use abrasive powder cleaners like Ajax or Comet as they tend to scratch the floor. B. Additional steps can also be taken to prolong the look and life of a seamless floor: 1. Protect the floor during transference of heavy equipment 2. Educate the drivers inside the building the importance of avoiding “jack-rabbit” starts and stops, as well as keeping the metal forks lifted 3. Regular cleaning should take place as to not allow the buildup of abrasive material, such as sand or dirt, on the coating 4. Eliminate all metal wheels 5. Change over to light-colored polyurethane wheels 6. Do not slide heavy metal totes, drums or bins across the floor 7. Immediately hose down chemical spills, especially on newly laid floors. Retro-Coat ™, Part A Material Safety Data Sheet (MSDS) Section 1 – Supplier Information and Material Identification Supplier: 1011 Calle Sombra San Clemente, CA 92673 Telephone: 949.366.8000 Fax: 949.366.8090 E-mail: info@regenesis.com Trade Name: Retro-Coat ™, Part A Product Use: Floor coating, organic vapor barrier (Proprietary) Section 2 – Hazardous Chemical Information CAS No. Chemical 0000101-90-6 Resorcinol diglycidyl ether Section 3 – Physical Data Form: Liquid Color: Amber Odor: Odorless Flammability/Flash Point: >200°F (Pensky Martens Closed Cup) Bulk Density (lbs/gal): 11 Viscosity (cps): 18,400 @ 77°F Percent Volatiles 0 @ 77°F Last Revised: July 14, 2016 Retro-Coat™ Specific Gravity 1.3 @ 77°F Section 4 – Reactivity Data Stability: Conditions to avoid; Excessive heating over long periods of time degrades the resin, increases viscosity, and epoxide equivalent weight. Conditions to Avoid/Incompatibility: Specific materials to avoid; Acids, bases, and amines. Hazardous Decomposition Products: The by-products expected in incomplete pyrolysis or combustion of epoxy resins are mainly phenolics, carbon monoxide and water. The thermal decomposition products of epoxy resins, therefore, should be treated as potentially hazardous substances, and appropriate precautions should be taken. Polymerization Will not occur by itself, but masses of more than one pound of product plus an aliphatic amine may cause irreversible polymerization with considerable heat build- up. Section 5 – Regulations WHMSIS Classification: D2A Section 6 – Protective Measures, Storage and Handling Storage: Keep container tightly closed in a cool, well-ventilated place. Keep away from food, drink and animal feed. Handling: Avoid contact with skin, eyes and clothing. Do not breathe fumes/spray. Handle in well ventilated work space. Other Precautions: Emergency showers and eye wash stations should be readily accessible. Engineering Controls: Good general ventilation should be sufficient for most operations. Respiratory Protection: Inhalation can be harmful. For most conditions, no respiratory protection should be needed; however, in dusty atmospheres, use an approved dust respirator. Eye Protection: Splash goggles or full face shield should be worn. Skin Protection: Impervious protection clothing should be worn. Neoprene Retro-Coat™ coated fabric is recommended. Protection Against Fire & Explosion: Wear positive pressure, self-contained breathing apparatus. Note: High Temperature will cause combustion. Section 7 – Hazards Identification Potential Health Effects Inhalation: Inhalation may cause a severe allergic reaction. Mice and rats in a 2 year study when administered by gavage resulted in an increase in forestomach carcinoma. Eye Contact: This material will cause eye irritation. Skin Contact: This material is a skin irritant and can be an allergic sensitizer. CAUTION: DO NOT ALLOW SKIN CONTACT. This material can cause severe skin irritation. Ingestion: Swallowing will be a health hazard. Section 8 – Measures in Case of Accidents and Fire After Spillage/Leakage: Soak up with absorbent material such as sand and collect in suitable containers. Residual resin can be removed with hot, soapy water. Solvents are not recommended for cleanup unless the recommended exposure guidelines and safe handling practices for the specific solvent are followed. Consult appropriate solvent MSDS for handling information and exposure guidelines. Extinguishing Media: Foam, Dry chemical, Carbon Dioxide (CO2) First Aid Eye Contact: Flush with water immediately. Continue to flush for 30 minutes and obtain emergency medical attention. Inhalation: Remove to fresh air. If breathing is labored administer oxygen. Call a physician. Ingestion: Do not induce vomiting. Get medical attention immediately. Skin Contact: Remove and do not reuse contaminated clothing. Immediately wash exposed areas very thoroughly with soap and water and flush for 15 minutes. It is not recommended to remove resin from skin with solvents. Retro-Coat™ Section 9 – Accidental Release Measures Cleanup Methods: Don proper PPE and avoid contact with material spill. Soak up with absorbent material such as sand and collect in suitable containers. Residual resin can be removed with hot, soapy water. Solvents are not recommended for cleanup unless the recommended exposure guidelines and safe handling practices for the specific solvent are followed. Consult appropriate solvent MSDS for handling information and exposure guidelines. Section 10 – Information on Toxicology Toxicity Data Dermal LD50 (rat): 300-400 mg/kg Section 11 – Information on Ecology Not Applicable Section 12 – Disposal Considerations Waste Disposal Method: Burn in adequate incinerator or bury in an approved landfill in accordance with applicable federal, state and local regulations. Retro-Coat™ Section 13 – Shipping/Transport Information D.O.T. Shipping Name:Environmentally Hazardous Substances, Liquid, NOS (Epoxy Phenol Resin) UN Number: UN 3082 D.O.T. Hazard Classification: 9 Labels:None Packaging Group:III Section 14 – Other Information WHMIS Classification: Class D2A NFPA Health – 3 Reactivity – 0 Flammability – 1 Special - Section 15 – Further Information The information contained in this document is the best available to the supplier at the time of writing, but is provided without warranty of any kind. Some possible hazards have been determined by analogy to similar classes of material. The items in this document are subject to change and clarification as more information become available. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person. Individuals receiving this information must exercise their independent judgment in determining its appropriateness for a particular purpose. Retro-Coat ™, Part B Material Safety Data Sheet (MSDS) Section 1 – Supplier Information and Material Identification Supplier: 1011 Calle Sombra San Clemente, CA 92673 Telephone: 949.366.8000 Fax: 949.366.8090 E-mail: info@regenesis.com Trade Name: Retro-Coat ™, Part B Product Use: Floor coating, organic vapor barrier (Proprietary) Section 2 – Chemical Information/Other Designations CAS No. Chemical Percentage 98-00-0 Furfuyl Alcohol 30-40% Section 3 – Physical Data Form: Liquid Color: Light Straw Color Odor: Fishy Flammability/Flash Point: >200°F (Pensky Martens Closed Cup) Vapor Pressure: < 1mm Hg @ 68°F Bulk Density (lbs/gal): 9.1 @ 77°F Viscosity (cps): 500 @ 77°F Specific Gravity 1.09 @ 77°F Section 4 – Reactivity Data Stability: Can auto-ignite at elevated temperatures. No data available. Last Revised: July 14, 2016 Retro-Coat™ Conditions to Avoid/Incompatibility: Oxidizing agents (i.e. perchlorates, nitrates etc.). Cleaning solutions, such as chromerage (sulfuric acid/dichromate) and aqua regia. A reaction accompanied by large heat release occurs when the product is mixed with acids. Heat generated may be sufficient to cause vigorous boiling creating a hazard due to splashing or splattering of hot material. Hazardous Decomposition Products: Carbon Monoxide in a fire. Carbon Dioxide in a fire. Ammonia when heated. Nitrogen Oxides in a fire. Nitrogen oxide can react with water vapors to form corrosive nitric acid (TLV=2 ppm). Combustion of product under oxygen- starved conditions can be expected to product numerous toxic products including: nitriles, cyanic acid, isocyanides, cyanogens, nitrosamines, amides and carbamates. Polymerization Will not occur. Section 5 – Special Precautions Storage: Keep container tightly closed in a cool, well-ventilated place. Keep away from food, drink and animal feed. Other: Emergency showers and eye wash stations should be readily available. Section 6 – Protective Measures, Storage and Handling Technical Protective Measures Storage: Keep container tightly closed in a cool, well-ventilated place. Keep away from food, drink and animal feed. Handling: Avoid contact with skin, eyes and clothing. Do not breathe fumes/spray. Handle in well ventilated work space. Other Precautions: Emergency showers and eye wash stations should be readily accessible. Respiratory Protection: In poorly ventilated areas, a cartridge mask National Institute for Occupational Safety and Health (NIOSH) approved for organic vapors is recommended under the following conditions: emergency situations; when product vapor concentration is greater than 20 ppm for a period longer than 15 minutes; during repair and cleaning of equipment; during transfer or discharge of the product. Hand Protection: Wear suitable gloves: nitrile rubber gloves and lined clothing. Retro-Coat™ Eye Protection: Full face shield with goggles underneath. Skin Protection: Rubber apron. Rubber boots. Protection Against Fire & Explosion: Use a positive pressure, self-contained breathing apparatus. Wear full protection coating. Note: Will burn under right conditions of heat and oxygen supply. Section 7 – Hazards Identification Potential Health Effects Inhalation: May cause respiratory sensitization in susceptible individuals. Excessive exposure may cause irritation to upper respiratory tract. Eye Contact: Severe eye irritant. Undiluted product can cause burns to eye. Burns may cause blindness. Skin Contact: Severe skin irritant. May cause skin sensitization. A single prolonged exposure may result in the material being absorbed in harmful amounts. The LD50 for skin absorption in rabbits is 2000 mg/kg. Ingestion: Single dose oral toxicity is low. The oral LD50 for rats is between 300-400 mg/kg. Ingestion may cause gastrointestinal irritation or ulceration. Ingestion may cause burns of mouth and throat. Target Organs: Did not cause cancer in long-term animal studies. Results of in vitro (test tube) mutagenicity tests have been negative. Section 8 – Measures in Case of Accidents and Fire After Spillage/Leakage: Large spill-dike up and pump into appropriate containers. Small spill – dilute with water and recover or use noncombustible absorbent material/sand and shovel into suitable containers. Extinguishing Media: Water fog, Alcohol Foam, CO2, Dry Chemical First Aid Eye Contact: Immediate and continuous irrigation with flowing water for at least 15 minutes is imperative. Prompt medical consultation is essential Inhalation: Remove to fresh air if effects occur. Consult a physician. Ingestion: If swallowed, call a physician immediately. Remove stomach contents by gastric suction or Induce vomiting only as directed by medical personnel. Never give anything by mouth to an unconscious person. Skin Contact: In case of contact, immediately flush skin with plenty of Retro-Coat™ water for at least 15 minutes while removing contaminated clothing and shoes. Call a physician if irritation persists. Wash clothing before reuse. Destroy contaminated shoes and other leather items or articles which cannot be decontaminated. Notes to Medical Doctor: May cause tissue destruction leading to stricture. If lavage is performed, suggest endotracheal and/or esophagoscopic control. If burn is present, treat as any thermal burn, after decontamination. No specific antidote. Supportivecare. Treatment based on judgment of the physician in response to reactions of the patient. Excessive exposure may aggravate pre-existing asthma. Section 9 – Accidental Release Measures Cleanup Methods: Wear appropriate PPE. Large spill-dike up and pump into appropriate containers. Small spill – dilute with water and recover or use noncombustible absorbent material/sand and shovel into suitable containers. Section 10 – Information on Toxicology Toxicity Data Oral LD50 (rat): 300-400 mg/kg Dermal LD50 (rabbit): 2000 mg/kg Section 11 – Information on Ecology Not Applicable Section 12 – Disposal Considerations Waste Disposal Method: Product is classified as “corrosive” and as such must be disposed of as hazardous waste according to Federal, State and local regulations. Retro-Coat™ Section 13 – Shipping/Transport Information D.O.T. Shipping Name: Corrosive Liquids, Toxic NOS (Cycloaliphaticamine, Furfuryl Alcohol) UN Number: UN 2922 D.O.T. Hazard Classification: 8(6) Labels: Corrosive, Poison Packaging Group: III Section 14 – Other Information NFPA Health – 3 Reactivity – 0 Flammability – 1 Special - Section 15 – Further Information The information contained in this document is the best available to the supplier at the time of writing, but is provided without warranty of any kind. Some possible hazards have been determined by analogy to similar classes of material. The items in this document are subject to change and clarification as more information become available. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person. Individuals receiving this information must exercise their independent judgment in determining its appropriateness for a particular purpose. Retro-Coat ™ Primer, Part B Material Safety Data Sheet (MSDS) Last Revised: Jan 30, 2012 Section 1 – Supplier Information and Material Identification Supplier: 1011 Calle Sombra San Clemente, CA 92673 Telephone: 949.366.8000 Fax: 949.366.8090 E-mail: info@regenesis.com Trade Name: Retro-Coat ™ Primer, Part B Product Use: Floor coating, organic vapor barrier (Proprietary) Section 2 – Hazardous Chemical Information CAS No. Chemical Percentage Proprietary Modified Polyamines 55% 84852-15-3 Nonylphenol 15% 140-31-8 Aminoethylpiperazine 10% 100-51-6 Benzyl Alcohol 25% Section 3 – Physical Data Form: Liquid Color: Amber Odor: Amine Flammability/Flash Point: >200°F (Setaflash Closed Cup) Vapor Pressure: < 1 mm Hg @ 68°F Bulk Density (lbs/gal): 8.5 @ 77°F Viscosity (cps): 60 @ 77°F Percent Volatiles 0 @ 70°F Retro-Coat™ Specific Gravity 1.0 @ 77°F Section 4 – Reactivity Data Stability: Stable under normal storage conditions. Conditions to Avoid/Incompatibility: Avoid bringing into contact with strong oxidizing agents, and strong Lewis or Mineral acids, bases. Hazardous Decomposition Products: CO (Carbon Monoxide), CO2 (Carbon Monoxide), Acids, Aldehydes Section 5 – Regulations WHMSIS Classification: Class E, Corrosive Section 6 – Protective Measures, Storage and Handling Technical Protective Measures Storage: Keep container tightly closed when not in use. Store in a dry location. Personal Protective Equipment (PPE) Engineering Controls: Local ventilation, except if applied in confined spaces, where adequate respiratory protection is required. Respiratory Protection: Respirator with organic vapor cartridge N/A with local exhaust. Section 6 – Protective Measures, Storage and Handling (cont) Eye Protection: Chemical goggles. Skin Protection: Rubber or plastic gloves. Protection Against Fire & Explosion: Use a positive pressure, self-contained breathing apparatus. Wear full protection coating. Note: Will burn under right conditions of heat and oxygen supply. Retro-Coat™ Section 7 – Hazards Identification Potential Health Effects Inhalation: May cause nasal irritation, central nervous system depression or lung injury. Eye Contact: This product can cause chemical burns to eyes. Eye damage may be irreversible. Skin Contact: May be corrosive or highly irritating to the skin. Repeated contact may cause sensitization and/or dermatitis. Section 8 – Measures in Case of Accidents and Fire After Spillage/Leakage: Using adequate protective equipment, add dry material to absorb spill (if large spill, first dike to contain). Pick up and containerize. Flush area with dilute (5%) acetic acid. Collect rinsate for sewer or disposal. Extinguishing Media: Water fog, Alcohol Foam, CO2, Dry Chemical First Aid Eye Contact: Flush with water for at least 15 minutes. GET MEDICAL ATTENTION. Inhalation: Remove to fresh air if effects occur and administer oxygen if necessary. GET MEDICAL ATTENTION. Ingestion: GET MEDICAL ATTENTION IMMEDIATELY. Do not induce vomiting unless directed by physician. Skin Contact: Wash thoroughly with water. Remove contaminated clothing and shoes. Wash clothing before re-use. Get medical attention if effects such as swelling or reddening occur. Section 9 – Accidental Release Measures Cleanup Methods: Using adequate protective equipment, add dry material to absorb spill (if large spill, first dike to contain). Pick up and containerize. Flush area with dilute (5%) acetic acid. Collect rinsate for sewer or disposal. Retro-Coat™ Section 10 – Information on Toxicology Not Applicable Section 11 – Information on Ecology Not Applicable Section 12 – Disposal Considerations Waste Disposal Method: This product, if disposed as shipped, is a hazardous waste as specified in 40 CFR 261 on the basis of its corrosivity. Consult state or local officials for proper disposal method. Section 13 – Shipping/Transport Information D.O.T. Shipping Name: Amines, Liquids Corrosive, N.O.S. (Polyetheramine) UN Number: UN 2735 D.O.T. Hazard Classification: 8 Labels: Corrosive Packaging Group: III Section 14 – Other Information WHMIS Classification: Class E, Corrosive NFPA Health – 2 Reactivity – 1 Flammability – 1 Special - Section 15 – Further Information Retro-Coat™ The information contained in this document is the best available to the supplier at the time of writing, but is provided without warranty of any kind. Some possible hazards have been determined by analogy to similar classes of material. The items in this document are subject to change and clarification as more information become available. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person. Individuals receiving this information must exercise their independent judgment in determining its appropriateness for a particular purpose. Page 1 of 4 Revision Date: 6/1/2015 SAFETY DATA SHEET 1.0 IDENTIFICATION 1.1 GHS product identifier: Retro-Coat Top WB, Part A 1.2 Other means of identification: Waterborne resin dispersion 1.3 Recommended use of the chemical and restrictions on use: N/A 1.4 Manufactured for: LAND SCIENCE TECHNOLOGIES 1011 CALLE SOMBRA, SUITE 110 SAN CLEMENTE, CA 92673 INFORMATION PHONE NUMBER: 949-366-8090 1.5 Emergency phone number: 1-800-255-3924 2.0 HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture: Acute Toxicity – Dermal 5, Skin Corrosion/Irritant 5, Eye Damage/Irritation 5, Oral 5, Inhalation 5 2.2 GHS label elements: Signal Word: Warning Hazard Statement: May be harmful in contact with skin Prevention: Wear protective gloves/protective clothing. Response: If on skin: wash with plenty of soap and water. Call a poison center or doctor/physician if you feel unwell. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Call a physician if irritation persists. Wash contaminated clothing before reuse. Disposal: Dispose of in accordance with federal, state, and local regulations. Signal Word: Warning Hazard Statement: May cause eye irritation Prevention: Flush eyes thoroughly after eye contact. Response: If in eyes: rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: get medical advice/attention. Signal Word: Warning Hazard Statement: May be harmful if swallowed Prevention: Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Response: If swallowed: Call a poison center or doctor/physician if you feel unwell. Rinse mouth. Disposal: Dispose of in accordance with federal, state, and local regulations. Signal Word: Warning Hazard Statement: May be harmful if inhaled Prevention: Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Response: If inhaled: remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison center or doctor/physician if you feel unwell. 2.3 Other hazards which do not result in classification: N/A 2.4 Hazards Material Information System (United States): Health 1 Flammability 0 Physical Hazard 0 Hazard Codes: 0=Minimal Hazard, 1=Slight Hazard, 2=Moderate Hazard, 3=Serious Hazard, 4=Severe Hazard 3.0 COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Mixtures Chemical Identity CAS No. Concentration water 7732-18-5 40-50% The remaining components are proprietary. Page 2 of 4 Revision Date: 6/1/2015 4.0 FIRST-AID MEASURES 4.1 Description of necessary first-aid measures: Eye Contact: Remove contact lenses at once. Flush eyes with water for at least 15 minutes while holding eyelids apart. Seek medical attention if irritation develops. Skin Contact: Remove contaminated clothing and wash exposed area with soap and water. Inhalation: Remove to fresh air if effects occur. If not breathing, give artificial respiration. Get immediate medical attention. Ingestion: Keep person warm and quiet and get medical attention. Do not induce vomiting. 4.2 Most Important symptoms/effects, acute and delayed: Aggravated Medical Conditions: Overexposure to vapor, dust, or mist may aggravate existing respiratory conditions, such as asthma, bronchitis, and inflammatory or fibrotic respiratory disease. Other Health Effects: Unknown 4.3 Indication of immediate medical attention and special treatment needed, if necessary: Note to Physician: Treatment based on judgment of the physician in response to reactions of the patient. Contact a poison control center for additional treatment information. 5.0 FIRE-FIGHTING MEASURES 5.1 Suitable extinguishing media: Use water spray, dry chemical, foam, or carbon dioxide. Water or foam may cause frothing. Use water to cool fire-exposed containers. If a leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for persons attempting to stop the leak. 5.2 Specific hazards arising from the chemical: Hazardous combustion products may include intense heat, carbon monoxide, carbon dioxide, dense smoke and irritating vapors. 5.3 Special protective actions for fire-fighters: Use a positive pressure self-contained breathing apparatus. 6.0 ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures: Ventilate the area. Avoid breathing vapor. Use self-contained breathing apparatus or supplied air for large spills or confined areas. 6.2 Methods and materials for containment and clean up: Contain spill if possible. Wipe up or absorb on suitable material and pick up with shovels. Prevent entry into sewers and waterways. Dispose of in accordance with federal, state, and local regulations. 7.0 HANDLING AND STORAGE 7.1 Precautions for safe handling: Ground all transfer equipment. Take precautionary measures against static discharge. Handle as an industrial chemical. 7.2 Conditions for safe storage, including any incompatibilities: Keep container tightly closed when not in use. Practice good caution and personal cleanliness to avoid skin and eye contact. Hold bulk storage under nitrogen blanket. Store in a cool, dry place with adequate ventilation. Keep away from open flames and high temperatures. 8.0 EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control parameters Component CAS No. Percent Exposure Limits Source water 7732-18-5 40-50% None established 8.2 Appropriate engineering controls: N/A 8.3 Individual protection measures, such as personal protective equipment: Respiratory Protection: Airborne concentrations should be kept to lowest levels possible. Use in an appropriately ventilated area. Selection of air-purifying or positive-pressure supplied air will depend on the specific operation and the potential airborne concentration of the material. For emergency conditions, use an approved positive-pressure self-contained breathing apparatus. Protective Clothing: Protective clothing such as uniforms, coveralls, or lab coats must be worn. Launder or dry-clean when soiled. Gloves and goggles resistant to chemicals and petroleum distillates required. 9.0 PHYSICAL AND CHEMICAL PROPERTIES 9.1 Appearance (physical state, color, etc.): Light straw colored liquid 9.2 Odor: slight ammonia odor. 9.3 Odor threshold: N/A 9.4 pH: 8-9 9.5 Melting point/freezing point: N/A Page 3 of 4 Revision Date: 6/1/2015 9.6 Initial boiling point and boiling range: >200° C 9.7 Flash Point: >250° F 9.8 Evaporation rate: .07 9.9 Flammability (solid, gas): N/A 9.10 Upper/lower flammability or explosive limits: Not established 9.11 Vapor pressure: 29.33 mm/Hg @ 68° F 9.12 Vapor Density: .569 @ 25° C 9.13 Relative density (specific gravity): 1.06 9.14 Solubility(ies): complete (in water) 9.15 Partition coefficient; n-octanol/water: N/A 9.16 Auto-ignition temperature: N/A 9.17 Decomposition temperature: N/A 9.18 Viscosity: N/A 10.0 STABILITY AND REACTIVITY 10.1 Reactivity: N/A 10.2 Chemical stability: Stable under normal conditions of handling. 10.3 Possibility of hazardous reactions: Will not occur. 10.4 Conditions to avoid: High temperatures over 70°C, freezing temperatures and open flame. 10.5 Incompatible materials: N/A 10.6 Hazardous decomposition products: Carbon monoxide, Carbon dioxide, dense smoke, irritating vapors 11.0 TOXICOLOGICAL INFORMATION 11.1 Likely routes of exposure: N/A 11.2 Symptoms related to the physical, chemical and toxicological characteristics: Eye Contact: May cause eye irritation. Skin Contact: May cause dermal irritation. Inhalation: Excessive inhalation of vapors may cause nasal and respiratory irritation. Ingestion: Can cause gastrointestinal irritation, nausea, vomiting and diarrhea. 11.3 Delayed and immediate effects and also chronic effects from short and long term exposure: N/A 11.4 Numerical measures of toxicity: Ingredient Name CAS No. % Acute Oral LD50 Acute Dermal LD50 Acute Inhalation LC50 water 7732-18-5 40-50% Not established Not established Not established 12.0 ECOLOGICAL INFORMATION 12.1 Ecotoxicity: N/A 12.2 Persistence and degradability: N/A 12.3 Bioaccumulative potential: N/A 12.4 Mobility in soil: N/A 12.5 Other adverse effects: N/A 13.0 DISPOSAL CONSIDERATIONS 13.1 Disposal methods: Dispose of in accordance with federal, state, and local regulations. 14.0 TRANSPORT INFORMATION 14.1 UN number: Not regulated 14.2 UN proper shipping name: N/A 14.3 Transport hazard class(es): N/A 14.4 Packing group, if applicable: N/A 14.5 Environmental hazards: N/A 14.6 Transport in bulk: N/A 14.7 Special precautions for user: N/A Page 4 of 4 Revision Date: 6/1/2015 15.0 REGULATORY INFORMATION 15.1 Safety, health and environmental regulations: Not meant to be all-inclusive. Selected regulations presented. A. SARA Title III Section 311/312: Immediate (eye irritant) B. WHMIS Classification: Residual component(s) are below the concentration threshold listed of the ingredient disclosure list. C. TSCA Status: Listed on TSCA Inventory D. OSHA Hazard Comm. Std.: See Section 2 CA = California Haz. Subst. List; CA65 = California Safe Drinking Water and Toxics Enforcement Act List; CT = Connecticut Tox. Subst. List; FL = Florida Subst. List; IL = Illinois Tox. Subst. List; LA = Louisiana Haz. Subst. List; MA = Massachusetts Subst. List; ME = Maine Haz. Subst. List; MN = Minnesota Haz. Subst. List; NJ = New Jersey Haz. Subst. List; PA = Pennsylvania Haz. Subst. List; RI = Rhode Island Haz. Subst. List. 16.0 OTHER INFORMATION 16.1 Date of Preparation: 6/1/2015 To the best of our knowledge, the information contained herein is accurate. Final determination of the suitability of any material is the sole responsibility of the users. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. Page 1 of 5 Revision Date: 6/1/2015 SAFETY DATA SHEET 1.0 IDENTIFICATION 1.1 GHS product identifier: Retro-Coat Top WB, Part B 1.2 Other means of identification: Hydrophylic Aliphatic Polyisocyanate 1.3 Recommended use of the chemical and restrictions on use: N/A 1.4 Manufactured for: LAND SCIENCE TECHNOLOGIES 1011 CALLE SOMBRA, SUITE 110 SAN CLEMENTE, CA 92673 INFORMATION PHONE NUMBER: 949-366-8090 1.5 Emergency phone number: 1-800-255-3924 2.0 HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture: Acute Toxicity -- Skin Corrosion/Irritation 4, Eye Damage/Irritation 4, Oral 4, Inhalation 4 2.2 GHS label elements: Signal Word: Warning Hazard Statement: Causes skin irritation Prevention: Wash hands thoroughly after handling. Wear protective gloves. Response: If on skin: wash with plenty of soap and water. If skin irritation occurs: get medical advice/attention. Take off contaminated clothing and wash before reuse. Signal Word: Warning Hazard Statement: Causes eye irritation Prevention: Flush eyes thoroughly after eye contact. Response: If in eyes: rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: get medical advice/attention. Signal Word: Warning Hazard Statement: Harmful if swallowed Prevention: Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Response: If swallowed: Call a poison center or doctor/physician if you feel unwell. Rinse mouth. Disposal: Dispose of in accordance with federal, state, and local regulations. Signal Word: Warning Hazard Statement: Harmful if inhaled Prevention: Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well- ventilated area. Response: If inhaled: remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison center or doctor/physician if you feel unwell. 2.3 Other hazards which do not result in classification: N/A 2.4 Hazards Material Information System (United States): Health 2 Flammability 1 Physical Hazard 1 Hazard Codes: 0=Minimal Hazard, 1=Slight Hazard, 2=Moderate Hazard, 3=Serious Hazard, 4=Severe Hazard 3.0 COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Mixtures Homopolymer of Hexamethylene Diisocyanate 28182-81-2 60-100% Hydrophylic Aliphatic Polyisocyanate based on Hexamethylene Diisocyanate trade secret 15-25% Hexamethylene-1,6-Diisocyanate* 822-06-0 < 0.1% *Monomer content is less than 0.1% based on resin solids at the time of manufacture. Page 2 of 5 Revision Date: 6/1/2015 4.0 FIRST-AID MEASURES 4.1 Description of necessary first-aid measures: Eye Contact: Immediately flush eyes with large amounts of water or normal saline for at least 30 minutes. Hold eyelids apart while flushing to rinse entire surface of eye and lids with water. Then remove contact lenses, if easily removable, and continue eye irrigation for not less than 15 minutes. Get medical attention if irritation develops. Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Call a physician if irritation persists. Wash clothing before reuse. Inhalation: Remove victim to fresh air if effects occur. If not breathing, give artificial respiration. Get immediate medical attention. Asthmatic-type symptoms may develop and may be immediate or delayed up to several hours. Ingestion: Do not induce vomiting. If patient is conscious and can swallow, give two cups of water or milk (16 oz.). Get immediate medical attention. Never give anything by mouth to an unconscious or convulsing person. 4.2 Most Important symptoms/effects, acute and delayed: Signs and Symptoms: Irritation as noted above. Skin sensitization (allergy) may be evidenced by blisters, redness, or rashes, especially hives. Aggravated Medical Conditions: Preexisting skin and eye disorders may be aggravated by exposure to this product. Preexisting skin and lung allergies may increase the chance of developing increased allergy symptoms from exposure to this product. Other Health Effects: Based on animal studies, repeated exposure to components of this product may cause damage to respiratory systems. Reports have associated repeated and prolonged occupational exposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. 4.3 Indication of immediate medical attention and special treatment needed, if necessary: Note to Physician: Eyes: Stain for evidence of corneal injury. If cornea is burned, instill antibiotic/steroid preparation frequently. Workplace vapors could produce reversible corneal epithelial edema impairing vision. Skin: This product is a known skin sensitizer. Treat symptomatically as for contact dermatitis or thermal burn. Ingestion: Treat symptomatically. There is no specific antidote. Inducing vomiting is contraindicated because of the irritating nature of the product. Inhalation: This product is a known pulmonary sensitizer. Treatment is essentially symptomatic. An individual having a dermal or pulmonary sensitization reaction to this material must be removed from any further exposure to any isocyanate. Contact a Poison Control Center for additional treatment information. Health studies have shown that many petroleum hydrocarbons pose potential human health risks, which vary from person to person. As a precaution, exposure to liquids, vapors, mists, or fumes should be minimized. 5.0 FIRE-FIGHTING MEASURES 5.1 Suitable extinguishing media: Use foam, dry chemical, water spray, or CO2. 5.2 Specific hazards arising from the chemical: Flash Point is >200°F. Closed containers may explode when exposed to extreme heat or burst when contaminated with water (CO2 evolved). 5.3 Special protective actions for fire-fighters: Full emergency equipment with self-contained breathing apparatus and full protective clothing should be worn by firefighters. During a fire, HDI vapors and other irritating, highly toxic gases may be generated by thermal decomposition. Use water spray to cool fire-exposed surfaces and to protect personnel. Try to cover liquid spills with foam. Solvent vapors are heavier than air and may travel a considerable distance where they may linger and/or find an ignition source and flash back. 6.0 ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures: Evacuate nonessential personnel. Ventilate the area. Avoid breathing vapor. Use self-contained breathing apparatus or supplied air for large spills or confined areas. 6.2 Methods and materials for containment and clean up: Contain spill if possible. Prevent entry into sewers and waterways. Cover spill with sawdust, vermiculite, Fuller’s earth, or other absorbent material. Pour decontamination solution over spill area and allow reacting for at least 10 minutes. Collect material in open containers and add further amounts of decontamination solution. Remove containers to a safe place, cover loosely, and allow to stand for 24 to 48 hours. Wash down spill area with decontamination solutions. Decontamination Solutions: 1. nonionic surfactant Union carbide’s Tergitol TMN-10 (20%) and water (80%) 2. concentrated ammonia (3-8%), detergent (2%), and water (90-95%). Dispose of in accordance with federal, state, and local regulations. Page 3 of 5 Revision Date: 6/1/2015 7.0 HANDLING AND STORAGE 7.1 Precautions for safe handling: Ground all transfer equipment. Take precautionary measures against static discharge. Handle as an industrial chemical. 7.2 Conditions for safe storage, including any incompatibilities: Ground all transfer equipment. Take precautionary measures against static discharge. Handle as an industrial chemical. Keep container tightly closed when not in use to prevent moisture contamination. Do not reseal if contamination is suspected. Practice good caution and personal cleanliness to avoid skin and eye contact. Hold bulk storage under nitrogen blanket. Store in a cool (between 50 and 81°F), dry place with adequate ventilation. Keep away from open flames and high temperatures. At temperatures above 100°F, material may slowly polymerize without hazard. 8.0 EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control parameters Component CAS No. Percent Exposure Limits Source Homopolymer of Hexamethylene Diisocyanate 28182-81-2 60-100% 0.5 mg/m3 (rec. by supplier) TWA 1.0 mg/m3 (rec. by supplier) STEL Hexamethylene-1,6-Diisocyanate 822-06-0 < 0.1% 0.005 ppm TWA 0.02 ppm (rec. by supplier) Ceiling limit ACGIH 8.2 Appropriate engineering controls: N/A 8.3 Individual protection measures, such as personal protective equipment: Respiratory Protection: Provide adequate ventilation. Avoid breathing of vapors or mists. Airborne concentrations should be kept to lowest levels possible. When exposures are not adequately controlled, use a respirator approved for use in isocyanate environments. Selection of air purifying or positive-pressure supplied air will depend on the specific operation and the potential airborne concentration of the material. For emergency conditions, use an approved positive-pressure self-contained breathing apparatus. Protective Clothing: Contact Lenses should not be worn. Precautions should be taken so that persons handling this product do not breathe the vapors or have it contact the eyes or skin. In spray operations, protection must be afforded against exposure to both vapor and spray mist. Protective clothing such as uniforms, coveralls, or lab coats must be worn. Launder or dry-clean when soiled. Gloves and goggles resistant to chemicals and petroleum distillates are required. If skin creams are used, keep the area protected only by the cream to a minimum. When handling large quantities, impervious suits, gloves, and rubber boots must be worn. 9.0 PHYSICAL AND CHEMICAL PROPERTIES 9.1 Appearance (physical state, color, etc.): Clear liquid 9.2 Odor: slight 9.3 Odor threshold: N/A 9.4 pH: N/A 9.5 Melting point/freezing point: N/A 9.6 Initial boiling point and boiling range: Not established 9.7 Flash Point: >200°F 9.8 Evaporation rate: Not established 9.9 Flammability (solid, gas): N/A 9.10 Upper/lower flammability or explosive limits: Not established 9.11 Vapor pressure: Not established 9.12 Vapor Density: Not established 9.13 Relative density (specific gravity): 1.16 9.14 Solubility(ies): Insoluble - reacts slowly with water to liberate CO2 gas. 9.15 Partition coefficient; n-octanol/water: N/A 9.16 Auto-ignition temperature: N/A 9.17 Decomposition temperature: N/A 9.18 Viscosity: N/A Page 4 of 5 Revision Date: 6/1/2015 10.0 STABILITY AND REACTIVITY 10.1 Reactivity: N/A 10.2 Chemical stability: Stable under normal conditions. 10.3 Possibility of hazardous reactions: May occur. Contact with moisture or other materials which react with isocyanates or temperatures over 400F (204C) may cause polymerization. 10.4 Conditions to avoid: Water, amines, strong bases, alcohols, metal compounds and surface-active materials. 10.5 Incompatible materials: N/A 10.6 Hazardous decomposition products: By heat and fire -- carbon monoxide, carbon dioxide, oxides of nitrogen, HCN, HDI. 11.0 TOXICOLOGICAL INFORMATION 11.1 Likely routes of exposure: N/A 11.2 Symptoms related to the physical, chemical and toxicological characteristics: Eye Contact: Irritating and will injure eye tissue if not removed promptly. Prolonged vapor contact may cause conjunctivitis. Skin Contact: Isocyanates react with skin protein and moisture and can cause severe irritation. Has been known to cause allergic skin reaction in humans. Prolonged contact may cause blisters. Cured material is difficult to remove. Inhalation: High vapor concentrations are irritating to the eyes and respiratory tract causing runny nose, sore throat, coughing, chest discomfort, shortness of breath, and reduced lung function (breathing obstruction). The solvent vapors are anesthetic, cause headaches and dizziness and may have other central nervous system effects, including death. As a result of previous repeated overexposures or a single large dose, certain individuals will develop isocyanate sensitization (chemical asthma), which will cause them to react to a later exposure to isocyanate at levels well below the TLV. Sensitization may be either temporary or permanent. Ingestion: Can result in irritation and possible corrosive action in the mouth, stomach tissue, and digestive tract. Vomiting may cause aspiration of the solvent resulting in chemical pneumonitis. 11.3 Delayed and immediate effects and also chronic effects from short and long term exposure: N/A 11.4 Numerical measures of toxicity: Ingredient Name CAS No. % Acute Oral LD50 Acute Dermal LD50 Acute Inhalation LC50 Homopolymer of Hexamethylene Diisocyanate 28182-81-2 60-100% > 5,000 mg/kg (rat) > 5,000 mg/kg (rabbit) 390-453 mg/m3 , aerosol, 4 hrs (rat, male/female) Hexamethylene-1,6- Diisocyanate 822-06-0 < 0.1% Not available Not available Not available 12.0 ECOLOGICAL INFORMATION 12.1 Ecotoxicity: N/A 12.2 Persistence and degradability: N/A 12.3 Bioaccumulative potential: N/A 12.4 Mobility in soil: N/A 12.5 Other adverse effects: N/A 13.0 DISPOSAL CONSIDERATIONS 13.1 Disposal methods: Dispose of in accordance with federal, state, and local regulations. 14.0 TRANSPORT INFORMATION* 14.1 UN number: UN 3082 14.2 UN proper shipping name: Other regulated substances, liquid, n.o.s. (contains Hexamethylene-1,6-Diisocyanate), 9, PG III, UN 3082 14.3 Transport hazard class(es): 9 14.4 Packing group, if applicable: III 14.5 Environmental hazards: N/A 14.6 Transport in bulk: N/A 14.7 Special precautions for user: N/A 14.8 Additional Transportation Information *When in individual containers of less than the Product RQ (45,359 kg), this material ships as non-regulated. Page 5 of 5 Revision Date: 6/1/2015 15.0 REGULATORY INFORMATION 15.1 Safety, health and environmental regulations: Not meant to be all-inclusive. Selected regulations presented. A. SARA Title III Section 311/312 hazards: Immediate health hazard, delayed health hazard, reactive hazard B. TSCA Status: Listed on TSCA Inventory C. OSHA Hazard Comm. Std.: See Section 2 Homopolymer of Hexamethylene Diisocyanate: MA, PA, NJ Hydrophylic Aliphatic Polyisocyanate based on Hexamethylene Diisocyanate: NJ CA = California Haz. Subst. List; CA65 = California Safe Drinking Water and Toxics Enforcement Act List; CT = Connecticut Tox. Subst. List; FL = Florida Subst. List; IL = Illinois Tox. Subst. List; LA = Louisiana Haz. Subst. List; MA = Massachusetts Subst. List; ME = Maine Haz. Subst. List; MN = Minnesota Haz. Subst. List; NJ = New Jersey Haz. Subst. List; NJ2 = New Jersey Other; PA = Pennsylvania Haz. Subst. List; PA2 = Pennsylvania Non-hazardous present at 3% or Greater; RI = Rhode Island Haz. Subst. List. 16.0 OTHER INFORMATION 16.1 Date of Preparation: 6/1/2015 To the best of our knowledge, the information contained herein is accurate. Final determination of the suitability of any material is the sole responsibility of the users. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. © 2012 Land Science Technologies www.landsciencetech.com (949) 481-8118. 4/12 Retro-Coat™ Floor Care Instructions Retro-Coat™ provides the highest level of chemical resistance and vapor intrusion protection available. To maximize the products effectiveness simple care instructions should be followed to ensure Retro-Coat will provide a long-term solution to vapor intrusion. Cleaning and Maintenance of Retro-Coat Overtime the gloss of Retro-Coat will fade and staining may occur when Retro-Coat comes in contact with chemicals spilled on the coating surface. Any change in color or fade in the coatings appearance is due to a PH change on the coatings surface and is not the result of products “breaking down.” The standard smooth surface of Retro-Coat should be cleaned on a regular basis by damp mopping the floor with conventional commercial cleaners. It is important to first remove any grease or oils by a suitable cleaner, preferably a citrus based cleaner. Rinse with clear water to help eliminate film buildup and then allow to dry. Never use abrasive powder cleaners like Ajax or Comet as they tend to scratch the floor. Additional steps can also be taken to prolong the look and life of a seamless floor: 1. Protect the floor during transference of heavy equipment 2. Educate the drivers inside the building the importance of avoiding “jack-rabbit” starts and stops, as well as keeping the metal forks lifted 3. Regular cleaning should take place as to not allow the buildup of abrasive material, such as sand or dirt, on the coating 4. Eliminate all metal wheels 5. Change over the light-colored polyurethane wheels 6. Do not slide heavy metal totes, drums or bins across the floor. Use pallets! 7. Immediately hose down chemical spills, especially on newly laid floors, which normally take a full seven days to fully chemically cure 8. Ask Land Science Technologies the safe window before returning the floor to service. Just because the floor can safely take foot traffic, does not mean it is ready for motor traffic Small Repairs A vital component to floor maintenance is making small repairs to any holes, gouges or cracks that might develop overtime. Such needs occur due to removal of equipment, moving of walls, additions of drains, substrate movement and abnormal wear and tear. Repair to such areas can be done quickly and is recommended to repair such areas before the damaged area increases and results in large-scale repairs and possibly building downtime. Small kits are available for building maintenance personal to make spot repairs as needed. Attachment C Waterproofing Specifications