RA-29248_48419_CA_SCH_20220502_LimitedSiteCheckReport

Murphy USA
Limited Site Check Report
Murphy Express #8570
800 Retail Way
Louisburg, NC 27549

May 2, 2022

Limited Site Check Report Murphy Express #8570 800 Retail Way, Louisburg, NC 27549

Page i

Limited Site Check Report
Murphy Express #8570 800 Retail Way Louisburg, NC 27549
Prepared for: Murphy USA 200 E. Peach Street PO Box 7300 El Dorado, AR 71731
Prepared by: Groundwater & Environmental Services, Inc. 104 Corporate Boulevard - Suite 411 West Columbia, SC 29169 TEL: [phone] www.gesonline.com
GES Project: 2701919
Date: May 2, 2022

Daniel Dabkowski Senior Project Manager This document is intended only for the use or the
individual or entity for which it was prepared and may
contain information that is privileged, confidential, and
exempt from disclosure under applicable law. Any
dissemination, distribution, or copying of this document is strictly prohibited.

Limited Site Check Report Murphy Express #8570 800 Retail Way, Louisburg, NC 27549

Page ii

Figures
Attached Figures:
Figure 1 – Site Location Map Figure 2 – Site Map Figure 3 – Soil Analytical Results Summary Map Figure 4 – Groundwater Analytical Results Summary Map

Tables
Table 1 – Summary of Analytical Results – TPH-DRO/GRO Table 2 – Summary of Analytical Results – Volatiles (Soil) Table 3 – Summary of Analytical Results – PAHs (Soil) Table 4 – Summary of Analytical Results – Volatiles (Water) Table 5 – Summary of Analytical Results – PAHs (Water)
Appendices
Appendix A – Analytical Laboratory Report
Appendix B - Soil Boring Logs

Limited Site Check Report Murphy Express #8570 800 Retail Way, Louisburg, NC 27549

Page 1

Groundwater and Environmental Services, Inc. (GES), on behalf of Murphy USA (MUSA) is
pleased to provide this summary of site assessment activities completed at Murphy USA Store
#8570 located at 800 Retail Way, Louisburg, NC 27549. A Site Location Map is included as Figure
1. A map of the site is included as Figure 2.
Site assessment activities were performed in response to all three UST Sumps failing hydrostatic
testing. On March 22, 2022, GES personnel arrived onsite with a licensed well drilling contractor,
Versatile Environmental Resources Company, Inc. (VERCO), to collect soil samples in the
immediate vicinity of the UST sumps. GES also retained Taylor Wiseman & Taylor, Inc. (TWT) to
perform a private utility locate in the vicinity of the UST system and proposed boring locations.
GES collected groundwater and soil samples after sump repair activities were previously
completed onsite (one diesel and two unleaded) on behalf of MUSA.
Three (3) soil borings (SB-1, SB-2 and SB-3) were placed as close as reasonably possible to the
subject sumps within the UST system. In general, the soil borings were located within concrete
surfacing along the outer perimeter of the UST pit and advanced into native material. The soil
borings were progressed via a hand auger through gravel backfill until native soil was reached
(approximately 3.5 - 4.5 feet below ground surface (BGS)) at each boring location. The hand
auger was used to advance each boring to 8 feet BGS for utility clearance purposes. A
Geoprobe® was used to advance the soil borings through native soil greater than 8 feet BGS to
approximately 15 feet BGS. Soil from each boring was collected for classification, field screening,
and laboratory analysis.
Recovered soils were split for field screening and laboratory analysis. The portion utilized for field
screening was placed in a sealable air-tight bag with head space and allowed to volatilize for
approximately 15-minutes at an ambient temperature of approximately 68 degrees Fahrenheit
(°F). Field screening was accomplished by using a Honeywell MiniRAE 3000+ photo-ionization
detector (PID) calibrated to a 100-parts per million (ppm) isobutylene standard. The tip of the PID
was used to pierce the bag and the maximum response was recorded as the headspace was
withdrawn.
GES personnel collected soil samples along the perimeter of the UST system for confirmatory
laboratory analysis (SB-1 through SB-3). Groundwater samples (SB-2 Water) were collected
through a 2-foot stainless steel screen point sampler after soil boring SB-2 was advanced to 32-
feet BGS. The soil and groundwater samples were placed on ice and submitted to Pace Analytical
Services, LLC for analysis by Environmental Protection Agency (EPA) Method 8015C for Total
Petroleum Hydrocarbons – Diesel Range Organics (TPH–DRO) and Gasoline Range Organics
(TPH-GRO), EPA Method 8260 for Volatile Organic Compounds (VOCs), and EPA Method 8270
for Semi-Volatile Organic Compounds (SVOCs).
A summary of field data is provided below; elevated PID readings (>50 ppm) were not detected.

Boring/Sample
ID
Depth (feet) PID (ppm) Soil Type Sample
Date/Time
SB-1 10.0-12.0 0.0 Silty Sand 3/22/22 – 1:10
SB-2 10.0-12.0 1.0 Silty Sand 3/22/22 – 2:10
Limited Site Check Report Murphy Express #8570 800 Retail Way, Louisburg, NC 27549
Page 2
SB-2 (water) 30.0-32.0 N/A N/A 3/22/22 – 2:40
SB-3 10.0-12.0 2.0 Silty Sand 3/22/22 – 3:55
The native soil type encountered was silty sand. Soil samples were retained from soil borings SB-
1, SB-2 and SB-3 at a depth interval of 10-feet BGS to 12-feet BGS for laboratory analysis.
Groundwater was not encountered within the borings except for SB-2 when extended to 32-feet
BGS for the purpose of collecting groundwater samples. Soil borings were backfilled and
abandoned with Portland cement grout and the concrete cored surface repaired to original
condition.
Soil samples did not have any exceedances of the North Carolina Department of Environmental
Quality (NCDEQ) Maximum Soil Contaminant Concentration (MSCC) Levels. For the VOC
analysis, reporting limits for 1,2-Dichloroethane (EDB) were above the NCDEQ MSCCs for each
soil sample but there were non-detect results for all samples. For the semi-volatiles analysis,
reporting limits for Benzo(a)anthracene, Benzo(a)pyrene, Dibenz(a,h)anthracene, 1-
Methylnaphthalene and Naphthalene were above the NCDEQ MSCCS for each soil sample but
there were non-detect results for all samples also.
Groundwater samples collected from the SB-2 boring location did not have any exceedances of
the NCDEQ 2L Standards. For the VOC analysis, reporting limits for EDB were above the
NCDEQ 2L Standards but the result was non-detect. For the semi-volatiles analysis, reporting
limits for Benzo(a)anthracene, Benzo(a)pyrene and Dibenz(a,h)anthracene were above the
NCDEQ 2L Standards but the results were non-detect also. A summary of the analytical results
can be found on Table 1 through Table 5, and are depicted in Figure 3 and Figure 4. The
Laboratory Analytical Report is included as Appendix A. The Soil Boring Logs are included as
Appendix B.
Based on analytical results being below the NCDEQ MSCCs for soil and below the NCDEQ 2L
Standards for groundwater, GES recommends no additional work to be conducted. Please
contact me at [phone] extension 4523 if you have any questions or concerns.
Sincerely,
Groundwater and Environmental Services, Inc.
Daniel Dabkowski
Senior Project Manager
Limited Site Check Report Murphy Express #8570 800 Retail Way, Louisburg, NC 27549

Page 3

1 Site Information
1.1 Site Identification
Date of Report: Notification of Discharge dated March 22, 2022
Facility I.D.: 00-0-0000037083
Site Name: Murphy Express #8570
Risk Classification: Not Assigned
Land Use Classification: Commercial
Address: 800 Retail Way, Louisburg, NC 27549
State: North Carolina
County: Franklin
Latitude: 36.08473º (For Official Use Only)
Longitude: -78.317996º (For Official Use Only)
1.2 Contact Information Associated with the Release
Site Contact:
Jose Rios Cortes
Sr. Manager Environmental Strategy
200 E Peach Street
PO Box 7300
El Dorado, AR 71731
870-875-7723
Tank Owner:
Murphy Oil, Inc.
200 E. Peach Street
PO Box 7300
El Dorado, AR 71731
870-875-7600
Limited Site Check Report Murphy Express #8570 800 Retail Way, Louisburg, NC 27549

Figures

Murphy USA Station #8570
800 Retail Way
Louisburg, South Carolina
Site Location Map
Quadrangle Location
SITE
Source:
USGS 7.5 Minute Series
Topographic Quadrangle,
Louisburg, North Carolina
Contour Interval =
1984
10'
North Carolina
Designed
Approved
Scale In Feet
0 2000
W.G.S.
Drawn
N
Figure
4/1/22
Date
Groundwater & Environmental Services, Inc.M:\Graphics\2700-Columbia\MISC\Murphy Oil USA\8570 Louisburg\8570 Louisburg SLM.dwg, SLM, WShea1
2
3
4
Limited Site Check Report Murphy Express #8570 800 Retail Way, Louisburg, NC 27549

Tables

Limited Site Check Report
Murphy Express #8570
800 Retail Way, Louisburg, NC 27549
Privileged and Confidential Page 1 of 1
(mg/kg)(mg/kg)
100 50
SB-1 10-12'3/22/2022 Soil <6.3 <14.7
SB-2 10-12'3/22/2022 Soil <6.4 <14.9
SB-3 10-12'3/22/2022 Soil <6.3 <16.2
SB-2 Water 30-32'3/22/2022 Water NA NA
<#= Less than the reporting limit of #
NA = Not Available or Not Analyzed for that specific compoundTPH= Total petroleum hydrocarbons
DRO = Diesel range organics
GRO = Gasoline range organics
Table 1
Summary of Analytical Results - TPH-DRO/GRO
NCDEQ Action Level
Sample ID
Contaminant of
Concern
→C10-C28
TPH-DRO
C6-C10
TPH-GRO
Depth
(feet)
Sample
Date
Matrix
Limited Site Check Report
Murphy Express #8570
800 Retail Way, Louisburg, NC 27549
Privileged and Confidential Page 1 of 1
Benzene Toluene Ethylbenzene Total Xylenes Naphthalene
Methyl-tert-
butyl ether
(MTBE)
1,2-Dichloro
ethane
(EDB)
1,2,4-Tri
methyl
benzene
1,3,5-Tri
methyl
benzene
(µg/kg)(µg/kg)(µg/kg)(µg/kg)(µg/kg)(µg/kg)(µg/kg)(µg/kg)(µg/kg)
7.2 5,400 8,000 6,000 200 85 1.9 6,600 6,600
SB-1 3/22/2022 <13.5 <13.5 <13.5 <26.9 <13.5 <13.5 <13.5 <13.5 <13.5
SB-2 3/22/2022 <13.7 <13.7 7.3 J 27.7 <13.7 <13.7 <13.7 <13.7 <13.7
SB-3 3/22/2022 <12.3 <12.3 7.4 J 10.5 J <12.3 <12.3 <12.3 <12.3 <12.3
NOTES:
Bold typeface indicates concentration is greater than action level
µg/kg = microgram per kilogram
MSCCs = Maximum Soil Contaminant Concentration Levels
Sample ID Date
NCDEQ MSCCs (µg/kg)
Table 2
Summary of Analytical Results - Volatiles (Soil)
Limited Site Check Report
Murphy Express #8570800 Retail Way, Louisburg, NC 27549
Privileged and Confidential Page 1 of 1
Acenapthene Acenaphthylene Anthracene
Benzo(a)
anthracene
Benzo(a)
pyrene
Benzo(b)
fluoranthene
Benzo(g,h,i)
perylene
Benzo(k)
fluoranthene Chrysene
Dibenz(a,h)
anthracene Fluoranthene Fluorene
Indeno
(1,2,3-cd)
pyrene
1-Methyl
naphthalene
2-Methyl
naphthalene Naphthalene Phenathrene Pyrene
(µg/kg)(µg/kg)(µg/kg)(µg/kg)(µg/kg)(µg/kg)(µg/kg)(µg/kg)(µg/kg)(µg/kg)(µg/kg)(µg/kg)(µg/kg)(µg/kg)(µg/kg)(µg/kg)(µg/kg)(µg/kg)
8,300 20,000 640,000 170 58 600 7,600,000 5,800 18,000 190 330,000 55,000 1,900 54 1,500 200 64,000 210,000
SB-1 3/22/2022 <418 <418 <418 <418 <418 <418 <418 <418 <418 <418 <418 <418 <418 <418 <418 <418 <418 <418
SB-2 3/22/2022 <414 <414 <414 <414 <414 <414 <414 <414 <414 <414 <414 <414 <414 <414 <414 <414 <414 <414
SB-3 3/22/2022 <411 <411 <411 <411 <411 <411 <411 <411 <411 <411 <411 <411 <411 <411 <411 <411 <411 <411
NOTES:
Bold typeface indicates concentration is greater than action level
µg/kg = microgram per kilogram
MSCCs = Maximum Soil Contaminant Concentration Levels
Sample ID Date
NCDEQ MSCC (µg/kg)
Table 3
Summary of Analytical Results - PAHs (Soil)
Limited Site Check Report
Murphy Express #8570
800 Retail Way, Louisburg, NC 27549
Privileged and Confidential Page 1 of 1
Benzene Toluene Ethylbenzene Total Xylenes Naphthalene
Methyl-tert-
butyl ether
(MTBE)
1,2-Dichloro
ethane
(EDB)
(µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L)
1 600 600 500 6 20 0.4
SB-2 Water 3/22/2022 <1.0 <1.0 <1.0 <3.0 0.88 J <1.0 <0.50
NOTES:
Bold typeface indicates concentration is greater than the 2L Standards.
µg/L = microgram per liter
NCDEQ 2L Standards (µg/L)
Sample ID Date
Table 4
Summary of Analytical Results - Volatiles (Water)
Limited Site Check ReportMurphy Express #8570800 Retail Way, Louisburg, NC 27549
Privileged and Confidential Page 1 of 1
Acenaphthene Acenaphthylene Anthracene Benzo(a)antracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Chrysene Dibenz(a,h)anthracene Fluoranthene Fluorene
Indeno(1,2,3-cd)pyrene 1-Methylnaphthalene 2-Methylnaphthalene Naphthlene Phenathrene Phenol Pyrene(µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L)(µg/L)80 200 2,000 0.05 0.005 0.05 200 0.5 5 0.005 300 300 0.05 -30 6 200 30 200SB-2 Water 3/22/2022 <4.5 <4.5 <4.5 <4.5 <4.5 <4.5 <4.5 <4.5 <4.5 <4.5 <4.5 <4.5 <4.5 NA NA <4.5 <4.5 2.0 J <4.5
NOTES:Bold typeface indicates concentration is greater than the 2L Standards.µg/L = microgram per liter
Sample ID Date
NCDEQ 2L Standards (µg/L)
Table 5
Summary of Analytical Results - PAHs (Water)
Limited Site Check Report Murphy Express #8570 800 Retail Way, Louisburg, NC 27549

Appendix A – Laboratory Analytical Report

#=CL#
April 06, 2022
LIMS USE: FR - DANIEL DABKOWSKI
LIMS OBJECT ID: 92595144
92595144
Project:
Pace Project No.:
RE:
Daniel Dabkowski
GES
104 Corporate Blvd
Suite 411
West Columbia, SC 29169
MURPHY #8570
Dear Daniel Dabkowski:
Enclosed are the analytical results for sample(s) received by the laboratory on March 23, 2022. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 68
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92595144
MURPHY #8570
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 68
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92595144
MURPHY #8570
Lab ID Sample ID Matrix Date Collected Date Received
92595144001 SB-1 (10-12)Solid 03/22/22 13:10 03/23/22 13:05
92595144002 SB-2 (10-12)Solid 03/22/22 14:10 03/23/22 13:05
92595144003 SB-3 (10-12)Solid 03/22/22 15:55 03/23/22 13:05
92595144004 SB-2 Water 03/22/22 14:40 03/23/22 13:05
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 68
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92595144
MURPHY #8570
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92595144001 SB-1 (10-12)EPA 8015C 2 PASI-CAP2
EPA 8015C 2 PASI-CMAD
EPA 8270E 75 PASI-CBPJ
EPA 8260D 70 PASI-CCL
SW-846 1 PASI-CKDF
92595144002 SB-2 (10-12)EPA 8015C 2 PASI-CAP2
EPA 8015C 2 PASI-CMAD
EPA 8270E 75 PASI-CBPJ
EPA 8260D 70 PASI-CCL
SW-846 1 PASI-CKDF
92595144003 SB-3 (10-12)EPA 8015C 2 PASI-CAP2
EPA 8015C 2 PASI-CMAD
EPA 8270E 75 PASI-CBPJ
EPA 8260D 70 PASI-CCL
SW-846 1 PASI-CKDF
92595144004 SB-2 MADEP VPH 5 PASI-CMAD
EPA 625.1 62 PASI-CPKS
SM 6200B 16 PASI-CSAS
SM 6200B 63 PASI-CSAS
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92595144
MURPHY #8570
Sample:SB-1 (10-12)Lab ID:92595144001 Collected:03/22/22 13:10 Received:03/23/22 13:05 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8015C Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8015 GCS THC-Diesel
Diesel Range Organics(C10-
C28)ND mg/kg 03/25/22 10:5803/24/22 13:166.3 4.4 1
Surrogates
n-Pentacosane (S)52 %03/25/22 10:58 629-99-203/24/22 13:1632-130 1
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 03/25/22 12:2203/25/22 11:1014.7 3.7 1
Surrogates
4-Bromofluorobenzene (S)84 %03/25/22 12:22 460-00-403/25/22 11:1066-131 1
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
Acenaphthene ND ug/kg 03/25/22 17:18 83-32-903/24/22 15:454181471
Acenaphthylene ND ug/kg 03/25/22 17:18 208-96-803/24/22 15:454181471
Aniline ND ug/kg 03/25/22 17:18 62-53-303/24/22 15:454181631
Anthracene ND ug/kg 03/25/22 17:18 120-12-703/24/22 15:454181371
Benzo(a)anthracene ND ug/kg 03/25/22 17:18 56-55-303/24/22 15:454181391
Benzo(a)pyrene ND ug/kg 03/25/22 17:18 50-32-803/24/22 15:454181441
Benzo(b)fluoranthene ND ug/kg 03/25/22 17:18 205-99-203/24/22 15:454181391
Benzo(g,h,i)perylene ND ug/kg 03/25/22 17:18 191-24-203/24/22 15:454181621
Benzo(k)fluoranthene ND ug/kg 03/25/22 17:18 207-08-903/24/22 15:454181471
Benzoic Acid ND ug/kg 03/25/22 17:18 65-85-003/24/22 15:4520908971
Benzyl alcohol ND ug/kg 03/25/22 17:18 100-51-603/24/22 15:458353161
4-Bromophenylphenyl ether ND ug/kg 03/25/22 17:18 101-55-303/24/22 15:454181611
Butylbenzylphthalate ND ug/kg 03/25/22 17:18 85-68-703/24/22 15:454181761
4-Chloro-3-methylphenol ND ug/kg 03/25/22 17:18 59-50-703/24/22 15:458352941
4-Chloroaniline ND ug/kg 03/25/22 17:18 106-47-803/24/22 15:458353281
bis(2-Chloroethoxy)methane ND ug/kg 03/25/22 17:18 111-91-103/24/22 15:454181731
bis(2-Chloroethyl) ether ND ug/kg 03/25/22 17:18 111-44-403/24/22 15:454181571
2-Chloronaphthalene ND ug/kg 03/25/22 17:18 91-58-703/24/22 15:454181661
2-Chlorophenol ND ug/kg 03/25/22 17:18 95-57-803/24/22 15:454181571
4-Chlorophenylphenyl ether ND ug/kg 03/25/22 17:18 7005-72-303/24/22 15:454181561
Chrysene ND ug/kg 03/25/22 17:18 218-01-903/24/22 15:454181521
Dibenz(a,h)anthracene ND ug/kg 03/25/22 17:18 53-70-303/24/22 15:454181611
Dibenzofuran ND ug/kg 03/25/22 17:18 132-64-903/24/22 15:454181511
1,2-Dichlorobenzene ND ug/kg 03/25/22 17:18 95-50-103/24/22 15:454181511
1,3-Dichlorobenzene ND ug/kg 03/25/22 17:18 541-73-103/24/22 15:454181481
1,4-Dichlorobenzene ND ug/kg 03/25/22 17:18 106-46-703/24/22 15:454181591
3,3'-Dichlorobenzidine ND ug/kg 03/25/22 17:18 91-94-1 IL03/24/22 15:458352821
2,4-Dichlorophenol ND ug/kg 03/25/22 17:18 120-83-203/24/22 15:454181631
Diethylphthalate ND ug/kg 03/25/22 17:18 84-66-203/24/22 15:454181531
2,4-Dimethylphenol ND ug/kg 03/25/22 17:18 105-67-903/24/22 15:454181731
Dimethylphthalate ND ug/kg 03/25/22 17:18 131-11-303/24/22 15:454181521
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92595144
MURPHY #8570
Sample:SB-1 (10-12)Lab ID:92595144001 Collected:03/22/22 13:10 Received:03/23/22 13:05 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
Di-n-butylphthalate ND ug/kg 03/25/22 17:18 84-74-203/24/22 15:454181401
4,6-Dinitro-2-methylphenol ND ug/kg 03/25/22 17:18 534-52-103/24/22 15:458353901
2,4-Dinitrophenol ND ug/kg 03/25/22 17:18 51-28-503/24/22 15:45209012901
2,4-Dinitrotoluene ND ug/kg 03/25/22 17:18 121-14-203/24/22 15:454181611
2,6-Dinitrotoluene ND ug/kg 03/25/22 17:18 606-20-203/24/22 15:454181531
Di-n-octylphthalate ND ug/kg 03/25/22 17:18 117-84-003/24/22 15:454181641
bis(2-Ethylhexyl)phthalate ND ug/kg 03/25/22 17:18 117-81-703/24/22 15:454181621
Fluoranthene ND ug/kg 03/25/22 17:18 206-44-003/24/22 15:454181431
Fluorene ND ug/kg 03/25/22 17:18 86-73-703/24/22 15:454181471
Hexachloro-1,3-butadiene ND ug/kg 03/25/22 17:18 87-68-303/24/22 15:454181811
Hexachlorobenzene ND ug/kg 03/25/22 17:18 118-74-103/24/22 15:454181631
Hexachlorocyclopentadiene ND ug/kg 03/25/22 17:18 77-47-403/24/22 15:454182391
Hexachloroethane ND ug/kg 03/25/22 17:18 67-72-103/24/22 15:454181591
Indeno(1,2,3-cd)pyrene ND ug/kg 03/25/22 17:18 193-39-503/24/22 15:454181641
Isophorone ND ug/kg 03/25/22 17:18 78-59-103/24/22 15:454181861
1-Methylnaphthalene ND ug/kg 03/25/22 17:18 90-12-003/24/22 15:454181471
2-Methylnaphthalene ND ug/kg 03/25/22 17:18 91-57-603/24/22 15:454181671
2-Methylphenol(o-Cresol)ND ug/kg 03/25/22 17:18 95-48-703/24/22 15:454181711
3&4-Methylphenol(m&p Cresol)ND ug/kg 03/25/22 17:18 15831-10-403/24/22 15:454181681
Naphthalene ND ug/kg 03/25/22 17:18 91-20-303/24/22 15:454181421
2-Nitroaniline ND ug/kg 03/25/22 17:18 88-74-403/24/22 15:4520903421
3-Nitroaniline ND ug/kg 03/25/22 17:18 99-09-2 IL03/24/22 15:4520903281
4-Nitroaniline ND ug/kg 03/25/22 17:18 100-01-6 IL03/24/22 15:458353181
Nitrobenzene ND ug/kg 03/25/22 17:18 98-95-303/24/22 15:454181941
2-Nitrophenol ND ug/kg 03/25/22 17:18 88-75-503/24/22 15:454181811
4-Nitrophenol ND ug/kg 03/25/22 17:18 100-02-703/24/22 15:4520908071
N-Nitrosodimethylamine ND ug/kg 03/25/22 17:18 62-75-903/24/22 15:454181401
N-Nitroso-di-n-propylamine ND ug/kg 03/25/22 17:18 621-64-703/24/22 15:454181571
N-Nitrosodiphenylamine ND ug/kg 03/25/22 17:18 86-30-603/24/22 15:454181481
2,2'-Oxybis(1-chloropropane)ND ug/kg 03/25/22 17:18 108-60-103/24/22 15:454181991
Pentachlorophenol ND ug/kg 03/25/22 17:18 87-86-503/24/22 15:458354091
Phenanthrene ND ug/kg 03/25/22 17:18 85-01-803/24/22 15:454181371
Phenol ND ug/kg 03/25/22 17:18 108-95-203/24/22 15:454181861
Pyrene ND ug/kg 03/25/22 17:18 129-00-003/24/22 15:454181701
Pyridine ND ug/kg 03/25/22 17:18 110-86-103/24/22 15:454181321
1,2,4-Trichlorobenzene ND ug/kg 03/25/22 17:18 120-82-103/24/22 15:454181641
2,4,5-Trichlorophenol ND ug/kg 03/25/22 17:18 95-95-403/24/22 15:454181911
2,4,6-Trichlorophenol ND ug/kg 03/25/22 17:18 88-06-203/24/22 15:454181721
Surrogates
Nitrobenzene-d5 (S)64 %03/25/22 17:18 4165-60-003/24/22 15:4521-130 1
2-Fluorobiphenyl (S)65 %03/25/22 17:18 321-60-803/24/22 15:4519-130 1
Terphenyl-d14 (S)74 %03/25/22 17:18 1718-51-003/24/22 15:4515-130 1
Phenol-d6 (S)63 %03/25/22 17:18 13127-88-303/24/22 15:4518-130 1
2-Fluorophenol (S)62 %03/25/22 17:18 367-12-403/24/22 15:4518-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92595144
MURPHY #8570
Sample:SB-1 (10-12)Lab ID:92595144001 Collected:03/22/22 13:10 Received:03/23/22 13:05 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
Surrogates
2,4,6-Tribromophenol (S)78 %03/25/22 17:18 118-79-603/24/22 15:4518-130 1
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Acetone ND ug/kg 03/26/22 05:50 67-64-103/25/22 15:2526986.5 1
Benzene ND ug/kg 03/26/22 05:50 71-43-203/25/22 15:2513.5 5.4 1
Bromobenzene ND ug/kg 03/26/22 05:50 108-86-103/25/22 15:2513.5 4.4 1
Bromochloromethane ND ug/kg 03/26/22 05:50 74-97-503/25/22 15:2513.5 4.0 1
Bromodichloromethane ND ug/kg 03/26/22 05:50 75-27-403/25/22 15:2513.5 5.2 1
Bromoform ND ug/kg 03/26/22 05:50 75-25-203/25/22 15:2513.5 4.7 1
Bromomethane 49.6 ug/kg 03/26/22 05:50 74-83-9 C703/25/22 15:2526.9 21.3 1
2-Butanone (MEK)ND ug/kg 03/26/22 05:50 78-93-303/25/22 15:2526964.6 1
n-Butylbenzene ND ug/kg 03/26/22 05:50 104-51-803/25/22 15:2513.5 6.4 1
sec-Butylbenzene ND ug/kg 03/26/22 05:50 135-98-803/25/22 15:2513.5 5.9 1
tert-Butylbenzene ND ug/kg 03/26/22 05:50 98-06-603/25/22 15:2513.5 4.8 1
Carbon tetrachloride ND ug/kg 03/26/22 05:50 56-23-503/25/22 15:2513.5 5.0 1
Chlorobenzene 8.6J ug/kg 03/26/22 05:50 108-90-703/25/22 15:2513.5 2.6 1
Chloroethane ND ug/kg 03/26/22 05:50 75-00-303/25/22 15:2526.9 10.4 1
Chloroform ND ug/kg 03/26/22 05:50 67-66-303/25/22 15:2513.5 8.2 1
Chloromethane ND ug/kg 03/26/22 05:50 74-87-303/25/22 15:2526.9 11.3 1
2-Chlorotoluene ND ug/kg 03/26/22 05:50 95-49-803/25/22 15:2513.5 4.8 1
4-Chlorotoluene ND ug/kg 03/26/22 05:50 106-43-403/25/22 15:2513.5 2.4 1
1,2-Dibromo-3-chloropropane ND ug/kg 03/26/22 05:50 96-12-803/25/22 15:2513.5 5.2 1
Dibromochloromethane ND ug/kg 03/26/22 05:50 124-48-103/25/22 15:2513.5 7.6 1
1,2-Dibromoethane (EDB)ND ug/kg 03/26/22 05:50 106-93-403/25/22 15:2513.5 5.9 1
Dibromomethane ND ug/kg 03/26/22 05:50 74-95-303/25/22 15:2513.5 2.9 1
1,2-Dichlorobenzene ND ug/kg 03/26/22 05:50 95-50-103/25/22 15:2513.5 4.8 1
1,3-Dichlorobenzene ND ug/kg 03/26/22 05:50 541-73-103/25/22 15:2513.5 4.2 1
1,4-Dichlorobenzene ND ug/kg 03/26/22 05:50 106-46-703/25/22 15:2513.5 3.5 1
Dichlorodifluoromethane ND ug/kg 03/26/22 05:50 75-71-8 IH,v103/25/22 15:2526.9 5.8 1
1,1-Dichloroethane ND ug/kg 03/26/22 05:50 75-34-303/25/22 15:2513.5 5.5 1
1,2-Dichloroethane ND ug/kg 03/26/22 05:50 107-06-203/25/22 15:2513.5 8.9 1
1,1-Dichloroethene ND ug/kg 03/26/22 05:50 75-35-403/25/22 15:2513.5 5.5 1
cis-1,2-Dichloroethene ND ug/kg 03/26/22 05:50 156-59-203/25/22 15:2513.5 4.6 1
trans-1,2-Dichloroethene ND ug/kg 03/26/22 05:50 156-60-503/25/22 15:2513.5 4.7 1
1,2-Dichloropropane ND ug/kg 03/26/22 05:50 78-87-503/25/22 15:2513.5 4.0 1
1,3-Dichloropropane ND ug/kg 03/26/22 05:50 142-28-903/25/22 15:2513.5 4.2 1
2,2-Dichloropropane ND ug/kg 03/26/22 05:50 594-20-703/25/22 15:2513.5 4.4 1
1,1-Dichloropropene ND ug/kg 03/26/22 05:50 563-58-603/25/22 15:2513.5 6.5 1
cis-1,3-Dichloropropene ND ug/kg 03/26/22 05:50 10061-01-503/25/22 15:2513.5 3.7 1
trans-1,3-Dichloropropene ND ug/kg 03/26/22 05:50 10061-02-603/25/22 15:2513.5 4.6 1
Diisopropyl ether ND ug/kg 03/26/22 05:50 108-20-303/25/22 15:2513.5 3.6 1
Ethylbenzene ND ug/kg 03/26/22 05:50 100-41-403/25/22 15:2513.5 6.3 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92595144
MURPHY #8570
Sample:SB-1 (10-12)Lab ID:92595144001 Collected:03/22/22 13:10 Received:03/23/22 13:05 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Hexachloro-1,3-butadiene ND ug/kg 03/26/22 05:50 87-68-303/25/22 15:2526.9 22.0 1
2-Hexanone ND ug/kg 03/26/22 05:50 591-78-603/25/22 15:2513513.0 1
Isopropylbenzene (Cumene)ND ug/kg 03/26/22 05:50 98-82-803/25/22 15:2513.5 4.6 1
p-Isopropyltoluene ND ug/kg 03/26/22 05:50 99-87-603/25/22 15:2513.5 6.6 1
Methylene Chloride ND ug/kg 03/26/22 05:50 75-09-203/25/22 15:2553.9 36.9 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 03/26/22 05:50 108-10-103/25/22 15:2513513.0 1
Methyl-tert-butyl ether ND ug/kg 03/26/22 05:50 1634-04-403/25/22 15:2513.5 5.0 1
Naphthalene ND ug/kg 03/26/22 05:50 91-20-303/25/22 15:2513.5 7.1 1
n-Propylbenzene ND ug/kg 03/26/22 05:50 103-65-103/25/22 15:2513.5 4.8 1
Styrene ND ug/kg 03/26/22 05:50 100-42-503/25/22 15:2513.5 3.6 1
1,1,1,2-Tetrachloroethane ND ug/kg 03/26/22 05:50 630-20-603/25/22 15:2513.5 5.2 1
1,1,2,2-Tetrachloroethane ND ug/kg 03/26/22 05:50 79-34-503/25/22 15:2513.5 3.6 1
Tetrachloroethene ND ug/kg 03/26/22 05:50 127-18-403/25/22 15:2513.5 4.3 1
Toluene ND ug/kg 03/26/22 05:50 108-88-303/25/22 15:2513.5 3.8 1
1,2,3-Trichlorobenzene ND ug/kg 03/26/22 05:50 87-61-603/25/22 15:2513.5 10.9 1
1,2,4-Trichlorobenzene ND ug/kg 03/26/22 05:50 120-82-103/25/22 15:2513.5 11.3 1
1,1,1-Trichloroethane ND ug/kg 03/26/22 05:50 71-55-603/25/22 15:2513.5 7.0 1
1,1,2-Trichloroethane ND ug/kg 03/26/22 05:50 79-00-503/25/22 15:2513.5 4.5 1
Trichloroethene ND ug/kg 03/26/22 05:50 79-01-603/25/22 15:2513.5 3.5 1
Trichlorofluoromethane ND ug/kg 03/26/22 05:50 75-69-403/25/22 15:2513.5 7.4 1
1,2,3-Trichloropropane ND ug/kg 03/26/22 05:50 96-18-403/25/22 15:2513.5 6.8 1
1,2,4-Trimethylbenzene ND ug/kg 03/26/22 05:50 95-63-603/25/22 15:2513.5 3.7 1
1,3,5-Trimethylbenzene ND ug/kg 03/26/22 05:50 108-67-803/25/22 15:2513.5 4.5 1
Vinyl acetate ND ug/kg 03/26/22 05:50 108-05-403/25/22 15:251359.8 1
Vinyl chloride ND ug/kg 03/26/22 05:50 75-01-403/25/22 15:2526.9 6.8 1
Xylene (Total)ND ug/kg 03/26/22 05:50 1330-20-703/25/22 15:2526.9 7.7 1
m&p-Xylene ND ug/kg 03/26/22 05:50 179601-23-103/25/22 15:2526.9 9.2 1
o-Xylene ND ug/kg 03/26/22 05:50 95-47-603/25/22 15:2513.5 6.0 1
Surrogates
Toluene-d8 (S)101 %03/26/22 05:50 2037-26-503/25/22 15:2570-130 1
4-Bromofluorobenzene (S)100 %03/26/22 05:50 460-00-403/25/22 15:2569-134 1
1,2-Dichloroethane-d4 (S)100 %03/26/22 05:50 17060-07-003/25/22 15:2570-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 19.6 %03/25/22 17:37 N20.10 0.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92595144
MURPHY #8570
Sample:SB-2 (10-12)Lab ID:92595144002 Collected:03/22/22 14:10 Received:03/23/22 13:05 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8015C Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8015 GCS THC-Diesel
Diesel Range Organics(C10-
C28)ND mg/kg 03/25/22 11:1503/24/22 13:166.4 4.6 1
Surrogates
n-Pentacosane (S)69 %03/25/22 11:15 629-99-203/24/22 13:1632-130 1
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 03/25/22 13:1803/25/22 11:1014.9 3.8 1
Surrogates
4-Bromofluorobenzene (S)81 %03/25/22 13:18 460-00-403/25/22 11:1066-131 1
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
Acenaphthene ND ug/kg 03/25/22 17:45 83-32-903/24/22 15:454141451
Acenaphthylene ND ug/kg 03/25/22 17:45 208-96-803/24/22 15:454141451
Aniline ND ug/kg 03/25/22 17:45 62-53-303/24/22 15:454141621
Anthracene ND ug/kg 03/25/22 17:45 120-12-703/24/22 15:454141351
Benzo(a)anthracene ND ug/kg 03/25/22 17:45 56-55-303/24/22 15:454141381
Benzo(a)pyrene ND ug/kg 03/25/22 17:45 50-32-803/24/22 15:454141431
Benzo(b)fluoranthene ND ug/kg 03/25/22 17:45 205-99-203/24/22 15:454141381
Benzo(g,h,i)perylene ND ug/kg 03/25/22 17:45 191-24-203/24/22 15:454141611
Benzo(k)fluoranthene ND ug/kg 03/25/22 17:45 207-08-903/24/22 15:454141451
Benzoic Acid ND ug/kg 03/25/22 17:45 65-85-003/24/22 15:4520708891
Benzyl alcohol ND ug/kg 03/25/22 17:45 100-51-603/24/22 15:458283141
4-Bromophenylphenyl ether ND ug/kg 03/25/22 17:45 101-55-303/24/22 15:454141591
Butylbenzylphthalate ND ug/kg 03/25/22 17:45 85-68-703/24/22 15:454141741
4-Chloro-3-methylphenol ND ug/kg 03/25/22 17:45 59-50-703/24/22 15:458282911
4-Chloroaniline ND ug/kg 03/25/22 17:45 106-47-803/24/22 15:458283251
bis(2-Chloroethoxy)methane ND ug/kg 03/25/22 17:45 111-91-103/24/22 15:454141721
bis(2-Chloroethyl) ether ND ug/kg 03/25/22 17:45 111-44-403/24/22 15:454141561
2-Chloronaphthalene ND ug/kg 03/25/22 17:45 91-58-703/24/22 15:454141641
2-Chlorophenol ND ug/kg 03/25/22 17:45 95-57-803/24/22 15:454141561
4-Chlorophenylphenyl ether ND ug/kg 03/25/22 17:45 7005-72-303/24/22 15:454141541
Chrysene ND ug/kg 03/25/22 17:45 218-01-903/24/22 15:454141501
Dibenz(a,h)anthracene ND ug/kg 03/25/22 17:45 53-70-303/24/22 15:454141591
Dibenzofuran ND ug/kg 03/25/22 17:45 132-64-903/24/22 15:454141491
1,2-Dichlorobenzene ND ug/kg 03/25/22 17:45 95-50-103/24/22 15:454141491
1,3-Dichlorobenzene ND ug/kg 03/25/22 17:45 541-73-103/24/22 15:454141471
1,4-Dichlorobenzene ND ug/kg 03/25/22 17:45 106-46-703/24/22 15:454141581
3,3'-Dichlorobenzidine ND ug/kg 03/25/22 17:45 91-94-1 IL03/24/22 15:458282801
2,4-Dichlorophenol ND ug/kg 03/25/22 17:45 120-83-203/24/22 15:454141621
Diethylphthalate ND ug/kg 03/25/22 17:45 84-66-203/24/22 15:454141521
2,4-Dimethylphenol ND ug/kg 03/25/22 17:45 105-67-903/24/22 15:454141721
Dimethylphthalate ND ug/kg 03/25/22 17:45 131-11-303/24/22 15:454141501
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92595144
MURPHY #8570
Sample:SB-2 (10-12)Lab ID:92595144002 Collected:03/22/22 14:10 Received:03/23/22 13:05 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
Di-n-butylphthalate ND ug/kg 03/25/22 17:45 84-74-203/24/22 15:454141391
4,6-Dinitro-2-methylphenol ND ug/kg 03/25/22 17:45 534-52-103/24/22 15:458283861
2,4-Dinitrophenol ND ug/kg 03/25/22 17:45 51-28-503/24/22 15:45207012801
2,4-Dinitrotoluene ND ug/kg 03/25/22 17:45 121-14-203/24/22 15:454141591
2,6-Dinitrotoluene ND ug/kg 03/25/22 17:45 606-20-203/24/22 15:454141521
Di-n-octylphthalate ND ug/kg 03/25/22 17:45 117-84-003/24/22 15:454141631
bis(2-Ethylhexyl)phthalate ND ug/kg 03/25/22 17:45 117-81-703/24/22 15:454141611
Fluoranthene ND ug/kg 03/25/22 17:45 206-44-003/24/22 15:454141421
Fluorene ND ug/kg 03/25/22 17:45 86-73-703/24/22 15:454141451
Hexachloro-1,3-butadiene ND ug/kg 03/25/22 17:45 87-68-303/24/22 15:454141791
Hexachlorobenzene ND ug/kg 03/25/22 17:45 118-74-103/24/22 15:454141621
Hexachlorocyclopentadiene ND ug/kg 03/25/22 17:45 77-47-403/24/22 15:454142371
Hexachloroethane ND ug/kg 03/25/22 17:45 67-72-103/24/22 15:454141581
Indeno(1,2,3-cd)pyrene ND ug/kg 03/25/22 17:45 193-39-503/24/22 15:454141631
Isophorone ND ug/kg 03/25/22 17:45 78-59-103/24/22 15:454141841
1-Methylnaphthalene ND ug/kg 03/25/22 17:45 90-12-003/24/22 15:454141451
2-Methylnaphthalene ND ug/kg 03/25/22 17:45 91-57-603/24/22 15:454141661
2-Methylphenol(o-Cresol)ND ug/kg 03/25/22 17:45 95-48-703/24/22 15:454141691
3&4-Methylphenol(m&p Cresol)ND ug/kg 03/25/22 17:45 15831-10-403/24/22 15:454141671
Naphthalene ND ug/kg 03/25/22 17:45 91-20-303/24/22 15:454141401
2-Nitroaniline ND ug/kg 03/25/22 17:45 88-74-403/24/22 15:4520703391
3-Nitroaniline ND ug/kg 03/25/22 17:45 99-09-2 IL03/24/22 15:4520703251
4-Nitroaniline ND ug/kg 03/25/22 17:45 100-01-6 IL03/24/22 15:458283151
Nitrobenzene ND ug/kg 03/25/22 17:45 98-95-303/24/22 15:454141921
2-Nitrophenol ND ug/kg 03/25/22 17:45 88-75-503/24/22 15:454141791
4-Nitrophenol ND ug/kg 03/25/22 17:45 100-02-703/24/22 15:4520708001
N-Nitrosodimethylamine ND ug/kg 03/25/22 17:45 62-75-903/24/22 15:454141391
N-Nitroso-di-n-propylamine ND ug/kg 03/25/22 17:45 621-64-703/24/22 15:454141561
N-Nitrosodiphenylamine ND ug/kg 03/25/22 17:45 86-30-603/24/22 15:454141471
2,2'-Oxybis(1-chloropropane)ND ug/kg 03/25/22 17:45 108-60-103/24/22 15:454141971
Pentachlorophenol ND ug/kg 03/25/22 17:45 87-86-503/24/22 15:458284051
Phenanthrene ND ug/kg 03/25/22 17:45 85-01-803/24/22 15:454141351
Phenol ND ug/kg 03/25/22 17:45 108-95-203/24/22 15:454141841
Pyrene ND ug/kg 03/25/22 17:45 129-00-003/24/22 15:454141681
Pyridine ND ug/kg 03/25/22 17:45 110-86-103/24/22 15:454141301
1,2,4-Trichlorobenzene ND ug/kg 03/25/22 17:45 120-82-103/24/22 15:454141631
2,4,5-Trichlorophenol ND ug/kg 03/25/22 17:45 95-95-403/24/22 15:454141891
2,4,6-Trichlorophenol ND ug/kg 03/25/22 17:45 88-06-203/24/22 15:454141711
Surrogates
Nitrobenzene-d5 (S)63 %03/25/22 17:45 4165-60-003/24/22 15:4521-130 1
2-Fluorobiphenyl (S)66 %03/25/22 17:45 321-60-803/24/22 15:4519-130 1
Terphenyl-d14 (S)72 %03/25/22 17:45 1718-51-003/24/22 15:4515-130 1
Phenol-d6 (S)61 %03/25/22 17:45 13127-88-303/24/22 15:4518-130 1
2-Fluorophenol (S)62 %03/25/22 17:45 367-12-403/24/22 15:4518-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92595144
MURPHY #8570
Sample:SB-2 (10-12)Lab ID:92595144002 Collected:03/22/22 14:10 Received:03/23/22 13:05 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
Surrogates
2,4,6-Tribromophenol (S)74 %03/25/22 17:45 118-79-603/24/22 15:4518-130 1
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Acetone ND ug/kg 03/26/22 06:09 67-64-103/25/22 15:2527487.9 1
Benzene ND ug/kg 03/26/22 06:09 71-43-203/25/22 15:2513.7 5.4 1
Bromobenzene ND ug/kg 03/26/22 06:09 108-86-103/25/22 15:2513.7 4.5 1
Bromochloromethane ND ug/kg 03/26/22 06:09 74-97-503/25/22 15:2513.7 4.1 1
Bromodichloromethane ND ug/kg 03/26/22 06:09 75-27-403/25/22 15:2513.7 5.3 1
Bromoform ND ug/kg 03/26/22 06:09 75-25-203/25/22 15:2513.7 4.8 1
Bromomethane 44.4 ug/kg 03/26/22 06:09 74-83-9 C703/25/22 15:2527.4 21.6 1
2-Butanone (MEK)73.6J ug/kg 03/26/22 06:09 78-93-3 C703/25/22 15:2527465.7 1
n-Butylbenzene ND ug/kg 03/26/22 06:09 104-51-803/25/22 15:2513.7 6.5 1
sec-Butylbenzene ND ug/kg 03/26/22 06:09 135-98-803/25/22 15:2513.7 6.0 1
tert-Butylbenzene ND ug/kg 03/26/22 06:09 98-06-603/25/22 15:2513.7 4.9 1
Carbon tetrachloride ND ug/kg 03/26/22 06:09 56-23-503/25/22 15:2513.7 5.1 1
Chlorobenzene 9.4J ug/kg 03/26/22 06:09 108-90-703/25/22 15:2513.7 2.6 1
Chloroethane ND ug/kg 03/26/22 06:09 75-00-303/25/22 15:2527.4 10.6 1
Chloroform ND ug/kg 03/26/22 06:09 67-66-303/25/22 15:2513.7 8.3 1
Chloromethane ND ug/kg 03/26/22 06:09 74-87-303/25/22 15:2527.4 11.5 1
2-Chlorotoluene ND ug/kg 03/26/22 06:09 95-49-803/25/22 15:2513.7 4.8 1
4-Chlorotoluene ND ug/kg 03/26/22 06:09 106-43-403/25/22 15:2513.7 2.4 1
1,2-Dibromo-3-chloropropane ND ug/kg 03/26/22 06:09 96-12-803/25/22 15:2513.7 5.3 1
Dibromochloromethane ND ug/kg 03/26/22 06:09 124-48-103/25/22 15:2513.7 7.7 1
1,2-Dibromoethane (EDB)ND ug/kg 03/26/22 06:09 106-93-403/25/22 15:2513.7 6.0 1
Dibromomethane ND ug/kg 03/26/22 06:09 74-95-303/25/22 15:2513.7 2.9 1
1,2-Dichlorobenzene ND ug/kg 03/26/22 06:09 95-50-103/25/22 15:2513.7 4.9 1
1,3-Dichlorobenzene ND ug/kg 03/26/22 06:09 541-73-103/25/22 15:2513.7 4.2 1
1,4-Dichlorobenzene ND ug/kg 03/26/22 06:09 106-46-703/25/22 15:2513.7 3.6 1
Dichlorodifluoromethane ND ug/kg 03/26/22 06:09 75-71-8 IH,v103/25/22 15:2527.4 5.9 1
1,1-Dichloroethane ND ug/kg 03/26/22 06:09 75-34-303/25/22 15:2513.7 5.6 1
1,2-Dichloroethane ND ug/kg 03/26/22 06:09 107-06-203/25/22 15:2513.7 9.1 1
1,1-Dichloroethene ND ug/kg 03/26/22 06:09 75-35-403/25/22 15:2513.7 5.6 1
cis-1,2-Dichloroethene ND ug/kg 03/26/22 06:09 156-59-203/25/22 15:2513.7 4.7 1
trans-1,2-Dichloroethene ND ug/kg 03/26/22 06:09 156-60-503/25/22 15:2513.7 4.8 1
1,2-Dichloropropane ND ug/kg 03/26/22 06:09 78-87-503/25/22 15:2513.7 4.1 1
1,3-Dichloropropane ND ug/kg 03/26/22 06:09 142-28-903/25/22 15:2513.7 4.3 1
2,2-Dichloropropane ND ug/kg 03/26/22 06:09 594-20-703/25/22 15:2513.7 4.5 1
1,1-Dichloropropene ND ug/kg 03/26/22 06:09 563-58-603/25/22 15:2513.7 6.6 1
cis-1,3-Dichloropropene ND ug/kg 03/26/22 06:09 10061-01-503/25/22 15:2513.7 3.7 1
trans-1,3-Dichloropropene ND ug/kg 03/26/22 06:09 10061-02-603/25/22 15:2513.7 4.7 1
Diisopropyl ether ND ug/kg 03/26/22 06:09 108-20-303/25/22 15:2513.7 3.7 1
Ethylbenzene 7.3J ug/kg 03/26/22 06:09 100-41-403/25/22 15:2513.7 6.4 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92595144
MURPHY #8570
Sample:SB-2 (10-12)Lab ID:92595144002 Collected:03/22/22 14:10 Received:03/23/22 13:05 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Hexachloro-1,3-butadiene ND ug/kg 03/26/22 06:09 87-68-303/25/22 15:2527.4 22.4 1
2-Hexanone ND ug/kg 03/26/22 06:09 591-78-603/25/22 15:2513713.2 1
Isopropylbenzene (Cumene)ND ug/kg 03/26/22 06:09 98-82-803/25/22 15:2513.7 4.7 1
p-Isopropyltoluene ND ug/kg 03/26/22 06:09 99-87-603/25/22 15:2513.7 6.7 1
Methylene Chloride ND ug/kg 03/26/22 06:09 75-09-203/25/22 15:2554.8 37.5 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 03/26/22 06:09 108-10-103/25/22 15:2513713.2 1
Methyl-tert-butyl ether ND ug/kg 03/26/22 06:09 1634-04-403/25/22 15:2513.7 5.1 1
Naphthalene ND ug/kg 03/26/22 06:09 91-20-303/25/22 15:2513.7 7.2 1
n-Propylbenzene ND ug/kg 03/26/22 06:09 103-65-103/25/22 15:2513.7 4.9 1
Styrene ND ug/kg 03/26/22 06:09 100-42-503/25/22 15:2513.7 3.6 1
1,1,1,2-Tetrachloroethane ND ug/kg 03/26/22 06:09 630-20-603/25/22 15:2513.7 5.3 1
1,1,2,2-Tetrachloroethane ND ug/kg 03/26/22 06:09 79-34-503/25/22 15:2513.7 3.6 1
Tetrachloroethene ND ug/kg 03/26/22 06:09 127-18-403/25/22 15:2513.7 4.3 1
Toluene ND ug/kg 03/26/22 06:09 108-88-303/25/22 15:2513.7 3.9 1
1,2,3-Trichlorobenzene ND ug/kg 03/26/22 06:09 87-61-603/25/22 15:2513.7 11.1 1
1,2,4-Trichlorobenzene ND ug/kg 03/26/22 06:09 120-82-103/25/22 15:2513.7 11.5 1
1,1,1-Trichloroethane ND ug/kg 03/26/22 06:09 71-55-603/25/22 15:2513.7 7.1 1
1,1,2-Trichloroethane ND ug/kg 03/26/22 06:09 79-00-503/25/22 15:2513.7 4.5 1
Trichloroethene ND ug/kg 03/26/22 06:09 79-01-603/25/22 15:2513.7 3.5 1
Trichlorofluoromethane ND ug/kg 03/26/22 06:09 75-69-403/25/22 15:2513.7 7.5 1
1,2,3-Trichloropropane ND ug/kg 03/26/22 06:09 96-18-403/25/22 15:2513.7 6.9 1
1,2,4-Trimethylbenzene ND ug/kg 03/26/22 06:09 95-63-603/25/22 15:2513.7 3.8 1
1,3,5-Trimethylbenzene ND ug/kg 03/26/22 06:09 108-67-803/25/22 15:2513.7 4.6 1
Vinyl acetate ND ug/kg 03/26/22 06:09 108-05-403/25/22 15:25137101
Vinyl chloride ND ug/kg 03/26/22 06:09 75-01-403/25/22 15:2527.4 7.0 1
Xylene (Total)27.7 ug/kg 03/26/22 06:09 1330-20-703/25/22 15:2527.4 7.8 1
m&p-Xylene 14.0J ug/kg 03/26/22 06:09 179601-23-103/25/22 15:2527.4 9.4 1
o-Xylene 13.7 ug/kg 03/26/22 06:09 95-47-603/25/22 15:2513.7 6.1 1
Surrogates
Toluene-d8 (S)101 %03/26/22 06:09 2037-26-503/25/22 15:2570-130 1
4-Bromofluorobenzene (S)100 %03/26/22 06:09 460-00-403/25/22 15:2569-134 1
1,2-Dichloroethane-d4 (S)98 %03/26/22 06:09 17060-07-003/25/22 15:2570-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 21.3 %03/28/22 15:28 N20.10 0.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92595144
MURPHY #8570
Sample:SB-3 (10-12)Lab ID:92595144003 Collected:03/22/22 15:55 Received:03/23/22 13:05 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8015C Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8015 GCS THC-Diesel
Diesel Range Organics(C10-
C28)ND mg/kg 03/25/22 11:1503/24/22 13:166.3 4.4 1
Surrogates
n-Pentacosane (S)47 %03/25/22 11:15 629-99-203/24/22 13:1632-130 1
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 03/25/22 13:4603/25/22 11:1016.2 4.1 1
Surrogates
4-Bromofluorobenzene (S)85 %03/25/22 13:46 460-00-403/25/22 11:1066-131 1
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
Acenaphthene ND ug/kg 03/25/22 18:12 83-32-903/24/22 15:454111441
Acenaphthylene ND ug/kg 03/25/22 18:12 208-96-803/24/22 15:454111441
Aniline ND ug/kg 03/25/22 18:12 62-53-303/24/22 15:454111611
Anthracene ND ug/kg 03/25/22 18:12 120-12-703/24/22 15:454111341
Benzo(a)anthracene ND ug/kg 03/25/22 18:12 56-55-303/24/22 15:454111371
Benzo(a)pyrene ND ug/kg 03/25/22 18:12 50-32-803/24/22 15:454111421
Benzo(b)fluoranthene ND ug/kg 03/25/22 18:12 205-99-203/24/22 15:454111371
Benzo(g,h,i)perylene ND ug/kg 03/25/22 18:12 191-24-203/24/22 15:454111591
Benzo(k)fluoranthene ND ug/kg 03/25/22 18:12 207-08-903/24/22 15:454111441
Benzoic Acid ND ug/kg 03/25/22 18:12 65-85-003/24/22 15:4520508831
Benzyl alcohol ND ug/kg 03/25/22 18:12 100-51-603/24/22 15:458223111
4-Bromophenylphenyl ether ND ug/kg 03/25/22 18:12 101-55-303/24/22 15:454111581
Butylbenzylphthalate ND ug/kg 03/25/22 18:12 85-68-703/24/22 15:454111731
4-Chloro-3-methylphenol ND ug/kg 03/25/22 18:12 59-50-703/24/22 15:458222891
4-Chloroaniline ND ug/kg 03/25/22 18:12 106-47-803/24/22 15:458223221
bis(2-Chloroethoxy)methane ND ug/kg 03/25/22 18:12 111-91-103/24/22 15:454111711
bis(2-Chloroethyl) ether ND ug/kg 03/25/22 18:12 111-44-403/24/22 15:454111541
2-Chloronaphthalene ND ug/kg 03/25/22 18:12 91-58-703/24/22 15:454111631
2-Chlorophenol ND ug/kg 03/25/22 18:12 95-57-803/24/22 15:454111541
4-Chlorophenylphenyl ether ND ug/kg 03/25/22 18:12 7005-72-303/24/22 15:454111531
Chrysene ND ug/kg 03/25/22 18:12 218-01-903/24/22 15:454111491
Dibenz(a,h)anthracene ND ug/kg 03/25/22 18:12 53-70-303/24/22 15:454111581
Dibenzofuran ND ug/kg 03/25/22 18:12 132-64-903/24/22 15:454111481
1,2-Dichlorobenzene ND ug/kg 03/25/22 18:12 95-50-103/24/22 15:454111481
1,3-Dichlorobenzene ND ug/kg 03/25/22 18:12 541-73-103/24/22 15:454111461
1,4-Dichlorobenzene ND ug/kg 03/25/22 18:12 106-46-703/24/22 15:454111571
3,3'-Dichlorobenzidine ND ug/kg 03/25/22 18:12 91-94-1 IL03/24/22 15:458222781
2,4-Dichlorophenol ND ug/kg 03/25/22 18:12 120-83-203/24/22 15:454111611
Diethylphthalate ND ug/kg 03/25/22 18:12 84-66-203/24/22 15:454111511
2,4-Dimethylphenol ND ug/kg 03/25/22 18:12 105-67-903/24/22 15:454111711
Dimethylphthalate ND ug/kg 03/25/22 18:12 131-11-303/24/22 15:454111491
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92595144
MURPHY #8570
Sample:SB-3 (10-12)Lab ID:92595144003 Collected:03/22/22 15:55 Received:03/23/22 13:05 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
Di-n-butylphthalate ND ug/kg 03/25/22 18:12 84-74-203/24/22 15:454111381
4,6-Dinitro-2-methylphenol ND ug/kg 03/25/22 18:12 534-52-103/24/22 15:458223831
2,4-Dinitrophenol ND ug/kg 03/25/22 18:12 51-28-503/24/22 15:45205012701
2,4-Dinitrotoluene ND ug/kg 03/25/22 18:12 121-14-203/24/22 15:454111581
2,6-Dinitrotoluene ND ug/kg 03/25/22 18:12 606-20-203/24/22 15:454111511
Di-n-octylphthalate ND ug/kg 03/25/22 18:12 117-84-003/24/22 15:454111621
bis(2-Ethylhexyl)phthalate ND ug/kg 03/25/22 18:12 117-81-703/24/22 15:454111591
Fluoranthene ND ug/kg 03/25/22 18:12 206-44-003/24/22 15:454111411
Fluorene ND ug/kg 03/25/22 18:12 86-73-703/24/22 15:454111441
Hexachloro-1,3-butadiene ND ug/kg 03/25/22 18:12 87-68-303/24/22 15:454111781
Hexachlorobenzene ND ug/kg 03/25/22 18:12 118-74-103/24/22 15:454111611
Hexachlorocyclopentadiene ND ug/kg 03/25/22 18:12 77-47-403/24/22 15:454112351
Hexachloroethane ND ug/kg 03/25/22 18:12 67-72-103/24/22 15:454111571
Indeno(1,2,3-cd)pyrene ND ug/kg 03/25/22 18:12 193-39-503/24/22 15:454111621
Isophorone ND ug/kg 03/25/22 18:12 78-59-103/24/22 15:454111831
1-Methylnaphthalene ND ug/kg 03/25/22 18:12 90-12-003/24/22 15:454111441
2-Methylnaphthalene ND ug/kg 03/25/22 18:12 91-57-603/24/22 15:454111641
2-Methylphenol(o-Cresol)ND ug/kg 03/25/22 18:12 95-48-703/24/22 15:454111681
3&4-Methylphenol(m&p Cresol)ND ug/kg 03/25/22 18:12 15831-10-403/24/22 15:454111661
Naphthalene ND ug/kg 03/25/22 18:12 91-20-303/24/22 15:454111391
2-Nitroaniline ND ug/kg 03/25/22 18:12 88-74-403/24/22 15:4520503361
3-Nitroaniline ND ug/kg 03/25/22 18:12 99-09-2 IL03/24/22 15:4520503221
4-Nitroaniline ND ug/kg 03/25/22 18:12 100-01-6 IL03/24/22 15:458223121
Nitrobenzene ND ug/kg 03/25/22 18:12 98-95-303/24/22 15:454111901
2-Nitrophenol ND ug/kg 03/25/22 18:12 88-75-503/24/22 15:454111781
4-Nitrophenol ND ug/kg 03/25/22 18:12 100-02-703/24/22 15:4520507941
N-Nitrosodimethylamine ND ug/kg 03/25/22 18:12 62-75-903/24/22 15:454111381
N-Nitroso-di-n-propylamine ND ug/kg 03/25/22 18:12 621-64-703/24/22 15:454111541
N-Nitrosodiphenylamine ND ug/kg 03/25/22 18:12 86-30-603/24/22 15:454111461
2,2'-Oxybis(1-chloropropane)ND ug/kg 03/25/22 18:12 108-60-103/24/22 15:454111951
Pentachlorophenol ND ug/kg 03/25/22 18:12 87-86-503/24/22 15:458224021
Phenanthrene ND ug/kg 03/25/22 18:12 85-01-803/24/22 15:454111341
Phenol ND ug/kg 03/25/22 18:12 108-95-203/24/22 15:454111831
Pyrene ND ug/kg 03/25/22 18:12 129-00-003/24/22 15:454111671
Pyridine ND ug/kg 03/25/22 18:12 110-86-103/24/22 15:454111291
1,2,4-Trichlorobenzene ND ug/kg 03/25/22 18:12 120-82-103/24/22 15:454111621
2,4,5-Trichlorophenol ND ug/kg 03/25/22 18:12 95-95-403/24/22 15:454111881
2,4,6-Trichlorophenol ND ug/kg 03/25/22 18:12 88-06-203/24/22 15:454111691
Surrogates
Nitrobenzene-d5 (S)55 %03/25/22 18:12 4165-60-003/24/22 15:4521-130 1
2-Fluorobiphenyl (S)58 %03/25/22 18:12 321-60-803/24/22 15:4519-130 1
Terphenyl-d14 (S)63 %03/25/22 18:12 1718-51-003/24/22 15:4515-130 1
Phenol-d6 (S)54 %03/25/22 18:12 13127-88-303/24/22 15:4518-130 1
2-Fluorophenol (S)56 %03/25/22 18:12 367-12-403/24/22 15:4518-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92595144
MURPHY #8570
Sample:SB-3 (10-12)Lab ID:92595144003 Collected:03/22/22 15:55 Received:03/23/22 13:05 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
Surrogates
2,4,6-Tribromophenol (S)66 %03/25/22 18:12 118-79-603/24/22 15:4518-130 1
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Acetone ND ug/kg 03/26/22 06:28 67-64-103/25/22 15:2524679.1 1
Benzene ND ug/kg 03/26/22 06:28 71-43-203/25/22 15:2512.3 4.9 1
Bromobenzene ND ug/kg 03/26/22 06:28 108-86-103/25/22 15:2512.3 4.0 1
Bromochloromethane ND ug/kg 03/26/22 06:28 74-97-503/25/22 15:2512.3 3.6 1
Bromodichloromethane ND ug/kg 03/26/22 06:28 75-27-403/25/22 15:2512.3 4.8 1
Bromoform ND ug/kg 03/26/22 06:28 75-25-203/25/22 15:2512.3 4.3 1
Bromomethane 39.1 ug/kg 03/26/22 06:28 74-83-9 C703/25/22 15:2524.6 19.5 1
2-Butanone (MEK)ND ug/kg 03/26/22 06:28 78-93-303/25/22 15:2524659.1 1
n-Butylbenzene ND ug/kg 03/26/22 06:28 104-51-803/25/22 15:2512.3 5.8 1
sec-Butylbenzene ND ug/kg 03/26/22 06:28 135-98-803/25/22 15:2512.3 5.4 1
tert-Butylbenzene ND ug/kg 03/26/22 06:28 98-06-603/25/22 15:2512.3 4.4 1
Carbon tetrachloride ND ug/kg 03/26/22 06:28 56-23-503/25/22 15:2512.3 4.6 1
Chlorobenzene 6.3J ug/kg 03/26/22 06:28 108-90-703/25/22 15:2512.3 2.4 1
Chloroethane ND ug/kg 03/26/22 06:28 75-00-303/25/22 15:2524.6 9.5 1
Chloroform ND ug/kg 03/26/22 06:28 67-66-303/25/22 15:2512.3 7.5 1
Chloromethane ND ug/kg 03/26/22 06:28 74-87-303/25/22 15:2524.6 10.4 1
2-Chlorotoluene ND ug/kg 03/26/22 06:28 95-49-803/25/22 15:2512.3 4.4 1
4-Chlorotoluene ND ug/kg 03/26/22 06:28 106-43-403/25/22 15:2512.3 2.2 1
1,2-Dibromo-3-chloropropane ND ug/kg 03/26/22 06:28 96-12-803/25/22 15:2512.3 4.8 1
Dibromochloromethane ND ug/kg 03/26/22 06:28 124-48-103/25/22 15:2512.3 6.9 1
1,2-Dibromoethane (EDB)ND ug/kg 03/26/22 06:28 106-93-403/25/22 15:2512.3 5.4 1
Dibromomethane ND ug/kg 03/26/22 06:28 74-95-303/25/22 15:2512.3 2.6 1
1,2-Dichlorobenzene ND ug/kg 03/26/22 06:28 95-50-103/25/22 15:2512.3 4.4 1
1,3-Dichlorobenzene ND ug/kg 03/26/22 06:28 541-73-103/25/22 15:2512.3 3.8 1
1,4-Dichlorobenzene ND ug/kg 03/26/22 06:28 106-46-703/25/22 15:2512.3 3.2 1
Dichlorodifluoromethane ND ug/kg 03/26/22 06:28 75-71-8 IH,v103/25/22 15:2524.6 5.3 1
1,1-Dichloroethane ND ug/kg 03/26/22 06:28 75-34-303/25/22 15:2512.3 5.1 1
1,2-Dichloroethane ND ug/kg 03/26/22 06:28 107-06-203/25/22 15:2512.3 8.2 1
1,1-Dichloroethene ND ug/kg 03/26/22 06:28 75-35-403/25/22 15:2512.3 5.1 1
cis-1,2-Dichloroethene ND ug/kg 03/26/22 06:28 156-59-203/25/22 15:2512.3 4.2 1
trans-1,2-Dichloroethene ND ug/kg 03/26/22 06:28 156-60-503/25/22 15:2512.3 4.3 1
1,2-Dichloropropane ND ug/kg 03/26/22 06:28 78-87-503/25/22 15:2512.3 3.7 1
1,3-Dichloropropane ND ug/kg 03/26/22 06:28 142-28-903/25/22 15:2512.3 3.8 1
2,2-Dichloropropane ND ug/kg 03/26/22 06:28 594-20-703/25/22 15:2512.3 4.0 1
1,1-Dichloropropene ND ug/kg 03/26/22 06:28 563-58-603/25/22 15:2512.3 5.9 1
cis-1,3-Dichloropropene ND ug/kg 03/26/22 06:28 10061-01-503/25/22 15:2512.3 3.4 1
trans-1,3-Dichloropropene ND ug/kg 03/26/22 06:28 10061-02-603/25/22 15:2512.3 4.2 1
Diisopropyl ether ND ug/kg 03/26/22 06:28 108-20-303/25/22 15:2512.3 3.3 1
Ethylbenzene 7.4J ug/kg 03/26/22 06:28 100-41-403/25/22 15:2512.3 5.7 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92595144
MURPHY #8570
Sample:SB-3 (10-12)Lab ID:92595144003 Collected:03/22/22 15:55 Received:03/23/22 13:05 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Hexachloro-1,3-butadiene ND ug/kg 03/26/22 06:28 87-68-303/25/22 15:2524.6 20.2 1
2-Hexanone ND ug/kg 03/26/22 06:28 591-78-603/25/22 15:2512311.9 1
Isopropylbenzene (Cumene)ND ug/kg 03/26/22 06:28 98-82-803/25/22 15:2512.3 4.2 1
p-Isopropyltoluene ND ug/kg 03/26/22 06:28 99-87-603/25/22 15:2512.3 6.1 1
Methylene Chloride ND ug/kg 03/26/22 06:28 75-09-203/25/22 15:2549.3 33.8 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 03/26/22 06:28 108-10-103/25/22 15:2512311.9 1
Methyl-tert-butyl ether ND ug/kg 03/26/22 06:28 1634-04-403/25/22 15:2512.3 4.6 1
Naphthalene ND ug/kg 03/26/22 06:28 91-20-303/25/22 15:2512.3 6.5 1
n-Propylbenzene ND ug/kg 03/26/22 06:28 103-65-103/25/22 15:2512.3 4.4 1
Styrene ND ug/kg 03/26/22 06:28 100-42-503/25/22 15:2512.3 3.3 1
1,1,1,2-Tetrachloroethane ND ug/kg 03/26/22 06:28 630-20-603/25/22 15:2512.3 4.7 1
1,1,2,2-Tetrachloroethane ND ug/kg 03/26/22 06:28 79-34-503/25/22 15:2512.3 3.3 1
Tetrachloroethene ND ug/kg 03/26/22 06:28 127-18-403/25/22 15:2512.3 3.9 1
Toluene ND ug/kg 03/26/22 06:28 108-88-303/25/22 15:2512.3 3.5 1
1,2,3-Trichlorobenzene ND ug/kg 03/26/22 06:28 87-61-603/25/22 15:2512.3 10 1
1,2,4-Trichlorobenzene ND ug/kg 03/26/22 06:28 120-82-103/25/22 15:2512.3 10.4 1
1,1,1-Trichloroethane ND ug/kg 03/26/22 06:28 71-55-603/25/22 15:2512.3 6.4 1
1,1,2-Trichloroethane ND ug/kg 03/26/22 06:28 79-00-503/25/22 15:2512.3 4.1 1
Trichloroethene ND ug/kg 03/26/22 06:28 79-01-603/25/22 15:2512.3 3.2 1
Trichlorofluoromethane ND ug/kg 03/26/22 06:28 75-69-403/25/22 15:2512.3 6.8 1
1,2,3-Trichloropropane ND ug/kg 03/26/22 06:28 96-18-403/25/22 15:2512.3 6.2 1
1,2,4-Trimethylbenzene ND ug/kg 03/26/22 06:28 95-63-603/25/22 15:2512.3 3.4 1
1,3,5-Trimethylbenzene ND ug/kg 03/26/22 06:28 108-67-803/25/22 15:2512.3 4.1 1
Vinyl acetate ND ug/kg 03/26/22 06:28 108-05-403/25/22 15:251239.0 1
Vinyl chloride ND ug/kg 03/26/22 06:28 75-01-403/25/22 15:2524.6 6.3 1
Xylene (Total)10.5J ug/kg 03/26/22 06:28 1330-20-703/25/22 15:2524.6 7.0 1
m&p-Xylene ND ug/kg 03/26/22 06:28 179601-23-103/25/22 15:2524.6 8.4 1
o-Xylene 10.5J ug/kg 03/26/22 06:28 95-47-603/25/22 15:2512.3 5.4 1
Surrogates
Toluene-d8 (S)101 %03/26/22 06:28 2037-26-503/25/22 15:2570-130 1
4-Bromofluorobenzene (S)99 %03/26/22 06:28 460-00-403/25/22 15:2569-134 1
1,2-Dichloroethane-d4 (S)99 %03/26/22 06:28 17060-07-003/25/22 15:2570-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 19.4 %03/25/22 17:37 N20.10 0.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92595144
MURPHY #8570
Sample:SB-2 Lab ID:92595144004 Collected:03/22/22 14:40 Received:03/23/22 13:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: MADEP VPH
Pace Analytical Services - Charlotte
VPH NC Water
Aliphatic (C05-C08)ND ug/L 03/25/22 16:33 N250.0 50.0 1
Aliphatic(C09-C12) Adjusted ND ug/L 03/25/22 16:33 N250.0 50.0 1
Aromatic (C09-C10)ND ug/L 03/25/22 16:33 N250.0 50.0 1
Surrogates
4-Bromofluorobenzene (FID) (S)99 %03/25/22 16:33 460-00-470-130 1
4-Bromofluorobenzene (PID) (S)84 %03/25/22 16:33 460-00-470-130 1
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
Acenaphthene ND ug/L 03/29/22 23:01 83-32-903/29/22 05:394.5 1.8 1
Acenaphthylene ND ug/L 03/29/22 23:01 208-96-803/29/22 05:394.5 1.8 1
Anthracene ND ug/L 03/29/22 23:01 120-12-703/29/22 05:394.5 2.1 1
Benzo(a)anthracene ND ug/L 03/29/22 23:01 56-55-303/29/22 05:394.5 2.4 1
Benzo(a)pyrene ND ug/L 03/29/22 23:01 50-32-803/29/22 05:394.5 2.5 1
Benzo(b)fluoranthene ND ug/L 03/29/22 23:01 205-99-203/29/22 05:394.5 2.4 1
Benzo(g,h,i)perylene ND ug/L 03/29/22 23:01 191-24-203/29/22 05:394.5 2.6 1
Benzo(k)fluoranthene ND ug/L 03/29/22 23:01 207-08-903/29/22 05:394.5 2.5 1
4-Bromophenylphenyl ether ND ug/L 03/29/22 23:01 101-55-303/29/22 05:394.5 1.6 1
Butylbenzylphthalate ND ug/L 03/29/22 23:01 85-68-703/29/22 05:394.5 2.9 1
4-Chloro-3-methylphenol ND ug/L 03/29/22 23:01 59-50-703/29/22 05:394.5 3.0 1
bis(2-Chloroethoxy)methane ND ug/L 03/29/22 23:01 111-91-103/29/22 05:399.1 1.7 1
bis(2-Chloroethyl) ether ND ug/L 03/29/22 23:01 111-44-403/29/22 05:394.5 1.7 1
2-Chloronaphthalene ND ug/L 03/29/22 23:01 91-58-703/29/22 05:394.5 1.6 1
2-Chlorophenol ND ug/L 03/29/22 23:01 95-57-803/29/22 05:394.5 1.1 1
4-Chlorophenylphenyl ether ND ug/L 03/29/22 23:01 7005-72-303/29/22 05:394.5 1.8 1
Chrysene ND ug/L 03/29/22 23:01 218-01-903/29/22 05:394.5 2.5 1
Dibenz(a,h)anthracene ND ug/L 03/29/22 23:01 53-70-303/29/22 05:394.5 2.7 1
3,3'-Dichlorobenzidine ND ug/L 03/29/22 23:01 91-94-103/29/22 05:399.1 7.4 1
2,4-Dichlorophenol ND ug/L 03/29/22 23:01 120-83-203/29/22 05:394.5 1.3 1
Diethylphthalate ND ug/L 03/29/22 23:01 84-66-203/29/22 05:394.5 1.9 1
2,4-Dimethylphenol ND ug/L 03/29/22 23:01 105-67-903/29/22 05:399.1 1.5 1
Dimethylphthalate ND ug/L 03/29/22 23:01 131-11-303/29/22 05:394.5 1.9 1
Di-n-butylphthalate ND ug/L 03/29/22 23:01 84-74-203/29/22 05:394.5 2.0 1
4,6-Dinitro-2-methylphenol ND ug/L 03/29/22 23:01 534-52-103/29/22 05:399.1 3.1 1
2,4-Dinitrophenol ND ug/L 03/29/22 23:01 51-28-503/29/22 05:3945.5 23.6 1
2,4-Dinitrotoluene ND ug/L 03/29/22 23:01 121-14-203/29/22 05:394.5 1.5 1
2,6-Dinitrotoluene ND ug/L 03/29/22 23:01 606-20-203/29/22 05:394.5 1.6 1
Di-n-octylphthalate ND ug/L 03/29/22 23:01 117-84-003/29/22 05:394.5 3.6 1
bis(2-Ethylhexyl)phthalate ND ug/L 03/29/22 23:01 117-81-703/29/22 05:394.5 3.4 1
Fluoranthene ND ug/L 03/29/22 23:01 206-44-003/29/22 05:394.5 2.0 1
Fluorene ND ug/L 03/29/22 23:01 86-73-703/29/22 05:394.5 1.9 1
Hexachloro-1,3-butadiene ND ug/L 03/29/22 23:01 87-68-303/29/22 05:394.5 1.6 1
Hexachlorobenzene ND ug/L 03/29/22 23:01 118-74-103/29/22 05:394.5 2.0 1
Hexachlorocyclopentadiene ND ug/L 03/29/22 23:01 77-47-403/29/22 05:399.1 1.4 1
Hexachloroethane ND ug/L 03/29/22 23:01 67-72-103/29/22 05:394.5 1.3 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92595144
MURPHY #8570
Sample:SB-2 Lab ID:92595144004 Collected:03/22/22 14:40 Received:03/23/22 13:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
Indeno(1,2,3-cd)pyrene ND ug/L 03/29/22 23:01 193-39-503/29/22 05:394.5 2.6 1
Isophorone ND ug/L 03/29/22 23:01 78-59-103/29/22 05:399.1 1.5 1
Naphthalene ND ug/L 03/29/22 23:01 91-20-303/29/22 05:394.5 1.9 1
Nitrobenzene ND ug/L 03/29/22 23:01 98-95-303/29/22 05:394.5 1.7 1
2-Nitrophenol ND ug/L 03/29/22 23:01 88-75-503/29/22 05:394.5 1.3 1
4-Nitrophenol ND ug/L 03/29/22 23:01 100-02-703/29/22 05:399.1 6.0 1
N-Nitrosodimethylamine ND ug/L 03/29/22 23:01 62-75-903/29/22 05:394.5 1.7 1
N-Nitroso-di-n-propylamine ND ug/L 03/29/22 23:01 621-64-703/29/22 05:394.5 1.2 1
N-Nitrosodiphenylamine ND ug/L 03/29/22 23:01 86-30-603/29/22 05:399.1 2.7 1
2,2'-Oxybis(1-chloropropane)ND ug/L 03/29/22 23:01 108-60-103/29/22 05:394.5 1.0 1
Pentachlorophenol ND ug/L 03/29/22 23:01 87-86-503/29/22 05:399.1 3.4 1
Phenanthrene ND ug/L 03/29/22 23:01 85-01-803/29/22 05:394.5 1.8 1
Phenol 2.0J ug/L 03/29/22 23:01 108-95-2 C803/29/22 05:394.5 1.2 1
Pyrene ND ug/L 03/29/22 23:01 129-00-003/29/22 05:394.5 2.0 1
1,2,4-Trichlorobenzene ND ug/L 03/29/22 23:01 120-82-103/29/22 05:394.5 1.6 1
2,4,6-Trichlorophenol ND ug/L 03/29/22 23:01 88-06-203/29/22 05:399.1 1.4 1
Surrogates
Nitrobenzene-d5 (S)65 %03/29/22 23:01 4165-60-003/29/22 05:3910-120 1
2-Fluorobiphenyl (S)62 %03/29/22 23:01 321-60-803/29/22 05:3915-120 1
Terphenyl-d14 (S)86 %03/29/22 23:01 1718-51-003/29/22 05:3911-131 1
Phenol-d6 (S)38 %03/29/22 23:01 13127-88-303/29/22 05:3910-120 1
2-Fluorophenol (S)51 %03/29/22 23:01 367-12-403/29/22 05:3910-120 1
2,4,6-Tribromophenol (S)94 %03/29/22 23:01 118-79-603/29/22 05:3910-137 1
Tentatively Identified Compounds
Unknown 12.6J ug/L 03/29/22 23:0103/29/22 05:391
Unknown 5.2J ug/L 03/29/22 23:0103/29/22 05:391
Cyclopentasiloxane, deca 4.9J ug/L 03/29/22 23:01 541-02-6 N03/29/22 05:391
Unknown 22.5J ug/L 03/29/22 23:0103/29/22 05:391
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
602 Volatiles by Method 6200
Benzene ND ug/L 03/24/22 17:03 71-43-21.0 0.34 1
Chlorobenzene ND ug/L 03/24/22 17:03 108-90-71.0 0.28 1
1,2-Dichlorobenzene ND ug/L 03/24/22 17:03 95-50-11.0 0.34 1
1,3-Dichlorobenzene ND ug/L 03/24/22 17:03 541-73-11.0 0.34 1
1,4-Dichlorobenzene ND ug/L 03/24/22 17:03 106-46-71.0 0.33 1
Diisopropyl ether ND ug/L 03/24/22 17:03 108-20-31.0 0.31 1
Ethylbenzene ND ug/L 03/24/22 17:03 100-41-41.0 0.30 1
Isopropylbenzene (Cumene)ND ug/L 03/24/22 17:03 98-82-81.0 0.33 1
Methyl-tert-butyl ether ND ug/L 03/24/22 17:03 1634-04-41.0 0.42 1
Naphthalene 0.88J ug/L 03/24/22 17:03 91-20-32.0 0.64 1
Toluene ND ug/L 03/24/22 17:03 108-88-31.0 0.48 1
m&p-Xylene ND ug/L 03/24/22 17:03 179601-23-12.0 0.71 1
o-Xylene ND ug/L 03/24/22 17:03 95-47-61.0 0.34 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92595144
MURPHY #8570
Sample:SB-2 Lab ID:92595144004 Collected:03/22/22 14:40 Received:03/23/22 13:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
602 Volatiles by Method 6200
Surrogates
4-Bromofluorobenzene (S)103 %03/24/22 17:03 460-00-470-130 1
1,2-Dichloroethane-d4 (S)104 %03/24/22 17:03 17060-07-070-130 1
Toluene-d8 (S)104 %03/24/22 17:03 2037-26-570-130 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 03/26/22 01:58 71-43-20.50 0.34 1
Bromobenzene ND ug/L 03/26/22 01:58 108-86-10.50 0.29 1
Bromochloromethane ND ug/L 03/26/22 01:58 74-97-50.50 0.47 1
Bromodichloromethane ND ug/L 03/26/22 01:58 75-27-40.50 0.31 1
Bromoform ND ug/L 03/26/22 01:58 75-25-20.50 0.34 1
Bromomethane ND ug/L 03/26/22 01:58 74-83-9 M15.0 1.7 1
n-Butylbenzene ND ug/L 03/26/22 01:58 104-51-80.50 0.49 1
sec-Butylbenzene ND ug/L 03/26/22 01:58 135-98-80.50 0.40 1
tert-Butylbenzene ND ug/L 03/26/22 01:58 98-06-60.50 0.32 1
Carbon tetrachloride ND ug/L 03/26/22 01:58 56-23-50.50 0.33 1
Chlorobenzene ND ug/L 03/26/22 01:58 108-90-70.50 0.28 1
Chloroethane ND ug/L 03/26/22 01:58 75-00-3 M11.0 0.65 1
Chloroform ND ug/L 03/26/22 01:58 67-66-30.50 0.35 1
Chloromethane ND ug/L 03/26/22 01:58 74-87-31.0 0.54 1
2-Chlorotoluene ND ug/L 03/26/22 01:58 95-49-80.50 0.32 1
4-Chlorotoluene ND ug/L 03/26/22 01:58 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane ND ug/L 03/26/22 01:58 96-12-81.0 0.34 1
Dibromochloromethane ND ug/L 03/26/22 01:58 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)ND ug/L 03/26/22 01:58 106-93-40.50 0.27 1
Dibromomethane ND ug/L 03/26/22 01:58 74-95-30.50 0.39 1
1,2-Dichlorobenzene ND ug/L 03/26/22 01:58 95-50-10.50 0.34 1
1,3-Dichlorobenzene ND ug/L 03/26/22 01:58 541-73-10.50 0.34 1
1,4-Dichlorobenzene ND ug/L 03/26/22 01:58 106-46-70.50 0.33 1
Dichlorodifluoromethane ND ug/L 03/26/22 01:58 75-71-80.50 0.35 1
1,1-Dichloroethane ND ug/L 03/26/22 01:58 75-34-30.50 0.37 1
1,2-Dichloroethane ND ug/L 03/26/22 01:58 107-06-20.50 0.32 1
1,1-Dichloroethene ND ug/L 03/26/22 01:58 75-35-40.50 0.35 1
cis-1,2-Dichloroethene ND ug/L 03/26/22 01:58 156-59-20.50 0.38 1
trans-1,2-Dichloroethene ND ug/L 03/26/22 01:58 156-60-50.50 0.40 1
1,2-Dichloropropane ND ug/L 03/26/22 01:58 78-87-50.50 0.36 1
1,3-Dichloropropane ND ug/L 03/26/22 01:58 142-28-90.50 0.28 1
2,2-Dichloropropane ND ug/L 03/26/22 01:58 594-20-70.50 0.39 1
1,1-Dichloropropene ND ug/L 03/26/22 01:58 563-58-60.50 0.43 1
cis-1,3-Dichloropropene ND ug/L 03/26/22 01:58 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 03/26/22 01:58 10061-02-60.50 0.36 1
Diisopropyl ether ND ug/L 03/26/22 01:58 108-20-30.50 0.31 1
Ethylbenzene ND ug/L 03/26/22 01:58 100-41-40.50 0.30 1
Hexachloro-1,3-butadiene ND ug/L 03/26/22 01:58 87-68-32.0 1.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92595144
MURPHY #8570
Sample:SB-2 Lab ID:92595144004 Collected:03/22/22 14:40 Received:03/23/22 13:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Isopropylbenzene (Cumene)ND ug/L 03/26/22 01:58 98-82-80.50 0.33 1
Methylene Chloride ND ug/L 03/26/22 01:58 75-09-22.0 2.0 1
Methyl-tert-butyl ether ND ug/L 03/26/22 01:58 1634-04-40.50 0.42 1
Naphthalene ND ug/L 03/26/22 01:58 91-20-32.0 0.64 1
n-Propylbenzene ND ug/L 03/26/22 01:58 103-65-10.50 0.34 1
Styrene ND ug/L 03/26/22 01:58 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 03/26/22 01:58 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 03/26/22 01:58 79-34-50.50 0.22 1
Tetrachloroethene ND ug/L 03/26/22 01:58 127-18-40.50 0.29 1
Toluene ND ug/L 03/26/22 01:58 108-88-30.50 0.48 1
1,2,3-Trichlorobenzene ND ug/L 03/26/22 01:58 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene ND ug/L 03/26/22 01:58 120-82-12.0 0.64 1
1,1,1-Trichloroethane ND ug/L 03/26/22 01:58 71-55-60.50 0.33 1
1,1,2-Trichloroethane ND ug/L 03/26/22 01:58 79-00-50.50 0.32 1
Trichloroethene ND ug/L 03/26/22 01:58 79-01-60.50 0.38 1
Trichlorofluoromethane ND ug/L 03/26/22 01:58 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 03/26/22 01:58 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene ND ug/L 03/26/22 01:58 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene ND ug/L 03/26/22 01:58 108-67-80.50 0.33 1
Vinyl chloride ND ug/L 03/26/22 01:58 75-01-41.0 0.39 1
m&p-Xylene ND ug/L 03/26/22 01:58 179601-23-11.0 0.71 1
o-Xylene ND ug/L 03/26/22 01:58 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)103 %03/26/22 01:58 17060-07-070-130 1
4-Bromofluorobenzene (S)109 %03/26/22 01:58 460-00-470-130 1
Toluene-d8 (S)108 %03/26/22 01:58 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92595144
MURPHY #8570
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
687327
EPA 5030B
EPA 8015C
Gasoline Range Organics
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92595144001, 92595144002, 92595144003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3592842
Associated Lab Samples:92595144001, 92595144002, 92595144003
Matrix:Solid
AnalyzedMDL
Gas Range Organics (C6-C10)mg/kg ND 6.0 03/25/22 11:531.5
4-Bromofluorobenzene (S)%84 66-131 03/25/22 11:53
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3592843LABORATORY CONTROL SAMPLE:
LCSSpike
Gas Range Organics (C6-C10)mg/kg 47.150.1 94 70-130
4-Bromofluorobenzene (S)%85 66-131
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3592845MATRIX SPIKE SAMPLE:
MSSpike
Result
92595144002
Gas Range Organics (C6-C10)mg/kg 135124 108 70-145ND
4-Bromofluorobenzene (S)%87 66-131
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92595144001
3592844SAMPLE DUPLICATE:
Gas Range Organics (C6-C10)mg/kg ND 30ND
4-Bromofluorobenzene (S)%8384
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92595144
MURPHY #8570
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
687335
MADEP VPH
MADEP VPH
VPH NC Water
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92595144004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3592879
Associated Lab Samples:92595144004
Matrix:Water
AnalyzedMDL
Aliphatic (C05-C08)ug/L ND 50.0 N203/25/22 13:3750.0
Aromatic (C09-C10)ug/L ND 50.0 N203/25/22 13:3750.0
4-Bromofluorobenzene (FID) (S)%97 70-130 03/25/22 13:37
4-Bromofluorobenzene (PID) (S)%83 70-130 03/25/22 13:37
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3592880LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
3592881
Aliphatic (C05-C08)ug/L 264 N23008870-13091273 4 25
Aromatic (C09-C10)ug/L 91.5 N21009270-1309393.0 2 25
4-Bromofluorobenzene (FID) (S)%96 70-130100
4-Bromofluorobenzene (PID) (S)%83 70-13086
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92595144
MURPHY #8570
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
687023
SM 6200B
SM 6200B
602 by 6200B
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92595144004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3591244
Associated Lab Samples:92595144004
Matrix:Water
AnalyzedMDL
1,2-Dichlorobenzene ug/L ND 1.0 03/24/22 12:540.34
1,3-Dichlorobenzene ug/L ND 1.0 03/24/22 12:540.34
1,4-Dichlorobenzene ug/L ND 1.0 03/24/22 12:540.33
Benzene ug/L ND 1.0 03/24/22 12:540.34
Chlorobenzene ug/L ND 1.0 03/24/22 12:540.28
Diisopropyl ether ug/L ND 1.0 03/24/22 12:540.31
Ethylbenzene ug/L ND 1.0 03/24/22 12:540.30
Isopropylbenzene (Cumene)ug/L ND 1.0 03/24/22 12:540.33
m&p-Xylene ug/L ND 2.0 03/24/22 12:540.71
Methyl-tert-butyl ether ug/L ND 1.0 03/24/22 12:540.42
Naphthalene ug/L ND 2.0 03/24/22 12:540.64
o-Xylene ug/L ND 1.0 03/24/22 12:540.34
Toluene ug/L ND 1.0 03/24/22 12:540.48
1,2-Dichloroethane-d4 (S)%106 70-130 03/24/22 12:54
4-Bromofluorobenzene (S)%105 70-130 03/24/22 12:54
Toluene-d8 (S)%102 70-130 03/24/22 12:54
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3591245LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichlorobenzene ug/L 44.650 89 60-140
1,3-Dichlorobenzene ug/L 44.150 88 60-140
1,4-Dichlorobenzene ug/L 43.850 88 60-140
Benzene ug/L 48.550 97 60-140
Chlorobenzene ug/L 45.250 90 60-140
Diisopropyl ether ug/L 51.950 104 60-140
Ethylbenzene ug/L 46.850 94 60-140
Isopropylbenzene (Cumene)ug/L 49.450 99 60-140
m&p-Xylene ug/L 94.1100 94 60-140
Methyl-tert-butyl ether ug/L 57.250 114 60-140
Naphthalene ug/L 45.950 92 60-140
o-Xylene ug/L 45.050 90 60-140
Toluene ug/L 45.750 91 60-140
1,2-Dichloroethane-d4 (S)%113 70-130
4-Bromofluorobenzene (S)%106 70-130
Toluene-d8 (S)%98 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92595144
MURPHY #8570
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3591246MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92595033003
3591247
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,2-Dichlorobenzene ug/L 1000 112 60-140117 4 301000ND11201170
1,3-Dichlorobenzene ug/L 1000 113 60-140118 5 301000ND11301180
1,4-Dichlorobenzene ug/L 1000 108 60-140115 6 301000ND10801150
Benzene ug/L M11000-25 60-14048 12 301000612058606590
Chlorobenzene ug/L 1000 110 60-140115 4 301000ND11001150
Diisopropyl ether ug/L 1000 105 60-140105 0 301000ND10501050
Ethylbenzene ug/L 1000 108 60-140114 4 30100059716701740
Isopropylbenzene
(Cumene)ug/L 1000 121 60-140118 2 301000ND12601230
m&p-Xylene ug/L 2000 113 60-140122 4 302000204043004470
Methyl-tert-butyl ether ug/L 1000 102 60-140104 1 301000ND10401050
Naphthalene ug/L 1000 112 60-140114 2 30100013112501280
o-Xylene ug/L 1000 117 60-140131 6 301000121023802530
Toluene ug/L M11000-3 60-14057 9 301000645064207020
1,2-Dichloroethane-d4 (S)%108 70-130102
4-Bromofluorobenzene (S)%102 70-13097
Toluene-d8 (S)%99 70-130101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92595144
MURPHY #8570
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
687418
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92595144004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3593304
Associated Lab Samples:92595144004
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 0.50 03/26/22 00:290.31
1,1,1-Trichloroethane ug/L ND 0.50 03/26/22 00:290.33
1,1,2,2-Tetrachloroethane ug/L ND 0.50 03/26/22 00:290.22
1,1,2-Trichloroethane ug/L ND 0.50 03/26/22 00:290.32
1,1-Dichloroethane ug/L ND 0.50 03/26/22 00:290.37
1,1-Dichloroethene ug/L ND 0.50 03/26/22 00:290.35
1,1-Dichloropropene ug/L ND 0.50 03/26/22 00:290.43
1,2,3-Trichlorobenzene ug/L ND 2.0 03/26/22 00:290.81
1,2,3-Trichloropropane ug/L ND 0.50 03/26/22 00:290.26
1,2,4-Trichlorobenzene ug/L ND 2.0 03/26/22 00:290.64
1,2,4-Trimethylbenzene ug/L ND 0.50 03/26/22 00:290.50
1,2-Dibromo-3-chloropropane ug/L ND 1.0 03/26/22 00:290.34
1,2-Dibromoethane (EDB)ug/L ND 0.50 03/26/22 00:290.27
1,2-Dichlorobenzene ug/L ND 0.50 03/26/22 00:290.34
1,2-Dichloroethane ug/L ND 0.50 03/26/22 00:290.32
1,2-Dichloropropane ug/L ND 0.50 03/26/22 00:290.36
1,3,5-Trimethylbenzene ug/L ND 0.50 03/26/22 00:290.33
1,3-Dichlorobenzene ug/L ND 0.50 03/26/22 00:290.34
1,3-Dichloropropane ug/L ND 0.50 03/26/22 00:290.28
1,4-Dichlorobenzene ug/L ND 0.50 03/26/22 00:290.33
2,2-Dichloropropane ug/L ND 0.50 03/26/22 00:290.39
2-Chlorotoluene ug/L ND 0.50 03/26/22 00:290.32
4-Chlorotoluene ug/L ND 0.50 03/26/22 00:290.32
Benzene ug/L ND 0.50 03/26/22 00:290.34
Bromobenzene ug/L ND 0.50 03/26/22 00:290.29
Bromochloromethane ug/L ND 0.50 03/26/22 00:290.47
Bromodichloromethane ug/L ND 0.50 03/26/22 00:290.31
Bromoform ug/L ND 0.50 03/26/22 00:290.34
Bromomethane ug/L ND 5.0 03/26/22 00:291.7
Carbon tetrachloride ug/L ND 0.50 03/26/22 00:290.33
Chlorobenzene ug/L ND 0.50 03/26/22 00:290.28
Chloroethane ug/L ND 1.0 03/26/22 00:290.65
Chloroform ug/L ND 0.50 03/26/22 00:290.35
Chloromethane ug/L ND 1.0 03/26/22 00:290.54
cis-1,2-Dichloroethene ug/L ND 0.50 03/26/22 00:290.38
cis-1,3-Dichloropropene ug/L ND 0.50 03/26/22 00:290.36
Dibromochloromethane ug/L ND 0.50 03/26/22 00:290.36
Dibromomethane ug/L ND 0.50 03/26/22 00:290.39
Dichlorodifluoromethane ug/L ND 0.50 03/26/22 00:290.35
Diisopropyl ether ug/L ND 0.50 03/26/22 00:290.31
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92595144
MURPHY #8570
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3593304
Associated Lab Samples:92595144004
Matrix:Water
AnalyzedMDL
Ethylbenzene ug/L ND 0.50 03/26/22 00:290.30
Hexachloro-1,3-butadiene ug/L ND 2.0 03/26/22 00:291.5
Isopropylbenzene (Cumene)ug/L ND 0.50 03/26/22 00:290.33
m&p-Xylene ug/L ND 1.0 03/26/22 00:290.71
Methyl-tert-butyl ether ug/L ND 0.50 03/26/22 00:290.42
Methylene Chloride ug/L ND 2.0 03/26/22 00:292.0
n-Butylbenzene ug/L ND 0.50 03/26/22 00:290.49
n-Propylbenzene ug/L ND 0.50 03/26/22 00:290.34
Naphthalene ug/L ND 2.0 03/26/22 00:290.64
o-Xylene ug/L ND 0.50 03/26/22 00:290.34
sec-Butylbenzene ug/L ND 0.50 03/26/22 00:290.40
Styrene ug/L ND 0.50 03/26/22 00:290.29
tert-Butylbenzene ug/L ND 0.50 03/26/22 00:290.32
Tetrachloroethene ug/L ND 0.50 03/26/22 00:290.29
Toluene ug/L ND 0.50 03/26/22 00:290.48
trans-1,2-Dichloroethene ug/L ND 0.50 03/26/22 00:290.40
trans-1,3-Dichloropropene ug/L ND 0.50 03/26/22 00:290.36
Trichloroethene ug/L ND 0.50 03/26/22 00:290.38
Trichlorofluoromethane ug/L ND 1.0 03/26/22 00:290.30
Vinyl chloride ug/L ND 1.0 03/26/22 00:290.39
1,2-Dichloroethane-d4 (S)%111 70-130 03/26/22 00:29
4-Bromofluorobenzene (S)%103 70-130 03/26/22 00:29
Toluene-d8 (S)%106 70-130 03/26/22 00:29
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3593305LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 47.850 96 60-140
1,1,1-Trichloroethane ug/L 61.750 123 60-140
1,1,2,2-Tetrachloroethane ug/L 46.350 93 60-140
1,1,2-Trichloroethane ug/L 48.850 98 60-140
1,1-Dichloroethane ug/L 55.850 112 60-140
1,1-Dichloroethene ug/L 57.050 114 60-140
1,1-Dichloropropene ug/L 62.450 125 60-140
1,2,3-Trichlorobenzene ug/L 47.050 94 60-140
1,2,3-Trichloropropane ug/L 45.750 91 60-140
1,2,4-Trichlorobenzene ug/L 47.050 94 60-140
1,2,4-Trimethylbenzene ug/L 45.450 91 60-140
1,2-Dibromo-3-chloropropane ug/L 44.150 88 60-140
1,2-Dibromoethane (EDB)ug/L 49.250 98 60-140
1,2-Dichlorobenzene ug/L 46.050 92 60-140
1,2-Dichloroethane ug/L 59.450 119 60-140
1,2-Dichloropropane ug/L 52.450 105 60-140
1,3,5-Trimethylbenzene ug/L 46.750 93 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92595144
MURPHY #8570
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3593305LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichlorobenzene ug/L 46.550 93 60-140
1,3-Dichloropropane ug/L 49.450 99 60-140
1,4-Dichlorobenzene ug/L 45.850 92 60-140
2,2-Dichloropropane ug/L 57.550 115 60-140
2-Chlorotoluene ug/L 47.150 94 60-140
4-Chlorotoluene ug/L 44.850 90 60-140
Benzene ug/L 50.250 100 60-140
Bromobenzene ug/L 45.350 91 60-140
Bromochloromethane ug/L 51.250 102 60-140
Bromodichloromethane ug/L 51.350 103 60-140
Bromoform ug/L 42.750 85 60-140
Bromomethane ug/L 58.950 118 60-140
Carbon tetrachloride ug/L 55.350 111 60-140
Chlorobenzene ug/L 46.350 93 60-140
Chloroethane ug/L 69.950 140 60-140
Chloroform ug/L 56.350 113 60-140
Chloromethane ug/L 47.850 96 60-140
cis-1,2-Dichloroethene ug/L 56.950 114 60-140
cis-1,3-Dichloropropene ug/L 51.550 103 60-140
Dibromochloromethane ug/L 46.450 93 60-140
Dibromomethane ug/L 50.250 100 60-140
Dichlorodifluoromethane ug/L 49.950 100 60-140
Diisopropyl ether ug/L 59.250 118 60-140
Ethylbenzene ug/L 48.650 97 60-140
Hexachloro-1,3-butadiene ug/L 47.750 95 60-140
Isopropylbenzene (Cumene)ug/L 47.750 95 60-140
m&p-Xylene ug/L 95.6100 96 60-140
Methyl-tert-butyl ether ug/L 64.850 130 60-140
Methylene Chloride ug/L 54.750 109 60-140
n-Butylbenzene ug/L 47.050 94 60-140
n-Propylbenzene ug/L 47.550 95 60-140
Naphthalene ug/L 48.750 97 60-140
o-Xylene ug/L 44.550 89 60-140
sec-Butylbenzene ug/L 47.150 94 60-140
Styrene ug/L 45.850 92 60-140
tert-Butylbenzene ug/L 40.550 81 60-140
Tetrachloroethene ug/L 46.850 94 60-140
Toluene ug/L 47.750 95 60-140
trans-1,2-Dichloroethene ug/L 57.950 116 60-140
trans-1,3-Dichloropropene ug/L 52.650 105 60-140
Trichloroethene ug/L 50.750 101 60-140
Trichlorofluoromethane ug/L 63.150 126 60-140
Vinyl chloride ug/L 52.150 104 60-140
1,2-Dichloroethane-d4 (S)%112 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%98 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92595144
MURPHY #8570
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3593306MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92595144004
3593307
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 89 60-14094 5 3020ND17.8 18.7
1,1,1-Trichloroethane ug/L 20 120 60-140130 8 3020ND24.0 26.0
1,1,2,2-Tetrachloroethane ug/L 20 97 60-14099 2 3020ND19.4 19.8
1,1,2-Trichloroethane ug/L 20 104 60-140109 4 3020ND20.9 21.7
1,1-Dichloroethane ug/L 20 110 60-140121 10 3020ND22.0 24.2
1,1-Dichloroethene ug/L 20 112 60-140123 10 3020ND22.3 24.6
1,1-Dichloropropene ug/L 20 122 60-140131 7 3020ND24.4 26.2
1,2,3-Trichlorobenzene ug/L 20 100 60-14091 10 3020ND20.1 18.2
1,2,3-Trichloropropane ug/L 20 92 60-14095 3 3020ND18.4 19.0
1,2,4-Trichlorobenzene ug/L 20 106 60-14098 8 3020ND21.3 19.6
1,2,4-Trimethylbenzene ug/L 20 92 60-14091 0 3020ND18.3 18.3
1,2-Dibromo-3-
chloropropane ug/L 20 92 60-14081 13 3020ND18.4 16.2
1,2-Dibromoethane (EDB)ug/L 20 97 60-140102 5 3020ND19.4 20.5
1,2-Dichlorobenzene ug/L 20 96 60-14095 1 3020ND19.2 19.0
1,2-Dichloroethane ug/L 20 109 60-140119 8 3020ND21.8 23.7
1,2-Dichloropropane ug/L 20 106 60-140115 8 3020ND21.2 23.1
1,3,5-Trimethylbenzene ug/L 20 94 60-14093 1 3020ND18.9 18.7
1,3-Dichlorobenzene ug/L 20 96 60-14093 3 3020ND19.2 18.7
1,3-Dichloropropane ug/L 20 96 60-140103 7 3020ND19.2 20.7
1,4-Dichlorobenzene ug/L 20 92 60-14090 2 3020ND18.5 18.0
2,2-Dichloropropane ug/L 20 115 60-140127 9 3020ND23.0 25.3
2-Chlorotoluene ug/L 20 99 60-14098 1 3020ND19.8 19.6
4-Chlorotoluene ug/L 20 93 60-14091 2 3020ND18.6 18.1
Benzene ug/L 20 108 60-140111 2 3020ND21.7 22.1
Bromobenzene ug/L 20 97 60-14097 1 3020ND19.5 19.3
Bromochloromethane ug/L 20 110 60-140113 3 3020ND22.0 22.6
Bromodichloromethane ug/L 20 103 60-140105 2 3020ND20.6 21.0
Bromoform ug/L 20 85 60-14092 8 3020ND17.0 18.4
Bromomethane ug/L M12011860-140144 19 3020ND23.7 28.7
Carbon tetrachloride ug/L 20 111 60-140114 3 3020ND22.2 22.8
Chlorobenzene ug/L 20 97 60-14099 1 3020ND19.4 19.7
Chloroethane ug/L M12011560-140141 20 3020ND23.0 28.1
Chloroform ug/L 20 108 60-140118 9 3020ND21.7 23.7
Chloromethane ug/L 20 91 60-14095 4 3020ND18.2 19.0
cis-1,2-Dichloroethene ug/L 20 110 60-140121 10 3020ND22.0 24.3
cis-1,3-Dichloropropene ug/L 20 103 60-140110 6 3020ND20.7 22.0
Dibromochloromethane ug/L 20 87 60-14091 5 3020ND17.4 18.2
Dibromomethane ug/L 20 109 60-140115 5 3020ND21.8 22.9
Dichlorodifluoromethane ug/L 20 87 60-14096 10 3020ND17.4 19.2
Diisopropyl ether ug/L 20 101 60-140115 13 3020ND20.3 23.1
Ethylbenzene ug/L 20 101 60-140103 2 3020ND20.1 20.5
Hexachloro-1,3-butadiene ug/L 20 121 60-140104 16 3020ND24.2 20.7
Isopropylbenzene(Cumene)ug/L 20 99 60-140104 5 3020ND19.9 20.8
m&p-Xylene ug/L 40 98 60-140103 5 3040ND39.2 41.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92595144
MURPHY #8570
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3593306MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92595144004
3593307
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Methyl-tert-butyl ether ug/L 20 114 60-140124 8 3020ND22.9 24.8
Methylene Chloride ug/L 20 102 60-140115 12 3020ND20.5 23.1
n-Butylbenzene ug/L 20 98 60-14098 0 3020ND19.6 19.6
n-Propylbenzene ug/L 20 100 60-140101 1 3020ND20.0 20.1
Naphthalene ug/L 20 93 60-14090 3 3020ND18.7 18.1
o-Xylene ug/L 20 91 60-14099 9 3020ND18.2 19.9
sec-Butylbenzene ug/L 20 98 60-14098 0 3020ND19.5 19.6
Styrene ug/L 20 93 60-14099 6 3020ND18.6 19.7
tert-Butylbenzene ug/L 20 81 60-14083 2 3020ND16.1 16.5
Tetrachloroethene ug/L 20 97 60-140102 4 3020ND19.5 20.4
Toluene ug/L 20 104 60-140108 4 3020ND20.8 21.7
trans-1,2-Dichloroethene ug/L 20 113 60-140125 10 3020ND22.6 25.0
trans-1,3-Dichloropropene ug/L 20 105 60-140108 3 3020ND21.1 21.7
Trichloroethene ug/L 20 106 60-140110 4 3020ND21.2 22.0
Trichlorofluoromethane ug/L 20 108 60-140129 17 3020ND21.6 25.7
Vinyl chloride ug/L 20 105 60-140115 9 3020ND21.0 22.9
1,2-Dichloroethane-d4 (S)%98 70-130103
4-Bromofluorobenzene (S)%100 70-130102
Toluene-d8 (S)%99 70-130102
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92595144
MURPHY #8570
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
687424
EPA 5035A/5030B
EPA 8260D
8260D 5035A 5030B
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92595144001, 92595144002, 92595144003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3593351
Associated Lab Samples:92595144001, 92595144002, 92595144003
Matrix:Solid
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/kg ND 5.0 03/25/22 21:071.9
1,1,1-Trichloroethane ug/kg ND 5.0 03/25/22 21:072.6
1,1,2,2-Tetrachloroethane ug/kg ND 5.0 03/25/22 21:071.3
1,1,2-Trichloroethane ug/kg ND 5.0 03/25/22 21:071.7
1,1-Dichloroethane ug/kg ND 5.0 03/25/22 21:072.1
1,1-Dichloroethene ug/kg ND 5.0 03/25/22 21:072.1
1,1-Dichloropropene ug/kg ND 5.0 03/25/22 21:072.4
1,2,3-Trichlorobenzene ug/kg ND 5.0 03/25/22 21:074.0
1,2,3-Trichloropropane ug/kg ND 5.0 03/25/22 21:072.5
1,2,4-Trichlorobenzene ug/kg ND 5.0 03/25/22 21:074.2
1,2,4-Trimethylbenzene ug/kg ND 5.0 03/25/22 21:071.4
1,2-Dibromo-3-chloropropane ug/kg ND 5.0 03/25/22 21:071.9
1,2-Dibromoethane (EDB)ug/kg ND 5.0 03/25/22 21:072.2
1,2-Dichlorobenzene ug/kg ND 5.0 03/25/22 21:071.8
1,2-Dichloroethane ug/kg ND 5.0 03/25/22 21:073.3
1,2-Dichloropropane ug/kg ND 5.0 03/25/22 21:071.5
1,3,5-Trimethylbenzene ug/kg ND 5.0 03/25/22 21:071.7
1,3-Dichlorobenzene ug/kg ND 5.0 03/25/22 21:071.6
1,3-Dichloropropane ug/kg ND 5.0 03/25/22 21:071.6
1,4-Dichlorobenzene ug/kg ND 5.0 03/25/22 21:071.3
2,2-Dichloropropane ug/kg ND 5.0 03/25/22 21:071.6
2-Butanone (MEK)ug/kg ND 100 03/25/22 21:0724.0
2-Chlorotoluene ug/kg ND 5.0 03/25/22 21:071.8
2-Hexanone ug/kg ND 50.0 03/25/22 21:074.8
4-Chlorotoluene ug/kg ND 5.0 03/25/22 21:070.88
4-Methyl-2-pentanone (MIBK)ug/kg ND 50.0 03/25/22 21:074.8
Acetone ug/kg 41.4J 100 03/25/22 21:0732.1
Benzene ug/kg ND 5.0 03/25/22 21:072.0
Bromobenzene ug/kg ND 5.0 03/25/22 21:071.6
Bromochloromethane ug/kg ND 5.0 03/25/22 21:071.5
Bromodichloromethane ug/kg ND 5.0 03/25/22 21:071.9
Bromoform ug/kg ND 5.0 03/25/22 21:071.8
Bromomethane ug/kg ND 10.0 03/25/22 21:077.9
Carbon tetrachloride ug/kg ND 5.0 03/25/22 21:071.9
Chlorobenzene ug/kg ND 5.0 03/25/22 21:070.96
Chloroethane ug/kg ND 10.0 03/25/22 21:073.9
Chloroform ug/kg ND 5.0 03/25/22 21:073.0
Chloromethane ug/kg ND 10.0 03/25/22 21:074.2
cis-1,2-Dichloroethene ug/kg ND 5.0 03/25/22 21:071.7
cis-1,3-Dichloropropene ug/kg ND 5.0 03/25/22 21:071.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92595144
MURPHY #8570
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3593351
Associated Lab Samples:92595144001, 92595144002, 92595144003
Matrix:Solid
AnalyzedMDL
Dibromochloromethane ug/kg ND 5.0 03/25/22 21:072.8
Dibromomethane ug/kg ND 5.0 03/25/22 21:071.1
Dichlorodifluoromethane ug/kg ND 10.0 IH,v103/25/22 21:072.2
Diisopropyl ether ug/kg ND 5.0 03/25/22 21:071.4
Ethylbenzene ug/kg ND 5.0 03/25/22 21:072.3
Hexachloro-1,3-butadiene ug/kg ND 10.0 03/25/22 21:078.2
Isopropylbenzene (Cumene)ug/kg ND 5.0 03/25/22 21:071.7
m&p-Xylene ug/kg ND 10.0 03/25/22 21:073.4
Methyl-tert-butyl ether ug/kg ND 5.0 03/25/22 21:071.9
Methylene Chloride ug/kg ND 20.0 03/25/22 21:0713.7
n-Butylbenzene ug/kg ND 5.0 03/25/22 21:072.4
n-Propylbenzene ug/kg ND 5.0 03/25/22 21:071.8
Naphthalene ug/kg ND 5.0 03/25/22 21:072.6
o-Xylene ug/kg ND 5.0 03/25/22 21:072.2
p-Isopropyltoluene ug/kg ND 5.0 03/25/22 21:072.5
sec-Butylbenzene ug/kg ND 5.0 03/25/22 21:072.2
Styrene ug/kg ND 5.0 03/25/22 21:071.3
tert-Butylbenzene ug/kg ND 5.0 03/25/22 21:071.8
Tetrachloroethene ug/kg ND 5.0 03/25/22 21:071.6
Toluene ug/kg ND 5.0 03/25/22 21:071.4
trans-1,2-Dichloroethene ug/kg ND 5.0 03/25/22 21:071.8
trans-1,3-Dichloropropene ug/kg ND 5.0 03/25/22 21:071.7
Trichloroethene ug/kg ND 5.0 03/25/22 21:071.3
Trichlorofluoromethane ug/kg ND 5.0 03/25/22 21:072.8
Vinyl acetate ug/kg ND 50.0 03/25/22 21:073.6
Vinyl chloride ug/kg ND 10.0 03/25/22 21:072.5
Xylene (Total)ug/kg ND 10.0 03/25/22 21:072.8
1,2-Dichloroethane-d4 (S)%97 70-130 03/25/22 21:07
4-Bromofluorobenzene (S)%101 69-134 03/25/22 21:07
Toluene-d8 (S)%98 70-130 03/25/22 21:07
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3593352LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/kg 11501250 92 70-130
1,1,1-Trichloroethane ug/kg 12001250 96 70-130
1,1,2,2-Tetrachloroethane ug/kg 10901250 87 70-130
1,1,2-Trichloroethane ug/kg 11601250 92 70-130
1,1-Dichloroethane ug/kg 11701250 94 70-130
1,1-Dichloroethene ug/kg 13101250 105 70-130
1,1-Dichloropropene ug/kg 13301250 106 70-130
1,2,3-Trichlorobenzene ug/kg 12401250 99 65-130
1,2,3-Trichloropropane ug/kg 11501250 92 70-130
1,2,4-Trichlorobenzene ug/kg 12501250 100 68-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92595144
MURPHY #8570
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3593352LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trimethylbenzene ug/kg 12901250 103 70-130
1,2-Dibromo-3-chloropropane ug/kg 13301250 106 70-130
1,2-Dibromoethane (EDB)ug/kg 11701250 94 70-130
1,2-Dichlorobenzene ug/kg 12001250 96 70-130
1,2-Dichloroethane ug/kg 11401250 91 63-130
1,2-Dichloropropane ug/kg 12101250 97 70-130
1,3,5-Trimethylbenzene ug/kg 13301250 107 70-130
1,3-Dichlorobenzene ug/kg 12201250 97 70-130
1,3-Dichloropropane ug/kg 11601250 93 70-130
1,4-Dichlorobenzene ug/kg 11601250 93 70-130
2,2-Dichloropropane ug/kg 12401250 99 66-130
2-Butanone (MEK)ug/kg 23202500 93 70-130
2-Chlorotoluene ug/kg 12501250 100 70-130
2-Hexanone ug/kg 23302500 93 70-130
4-Chlorotoluene ug/kg 12001250 96 70-130
4-Methyl-2-pentanone (MIBK)ug/kg 23202500 93 70-130
Acetone ug/kg 22202500 89 69-130
Benzene ug/kg 11601250 93 70-130
Bromobenzene ug/kg 12501250 100 70-130
Bromochloromethane ug/kg 12001250 96 70-130
Bromodichloromethane ug/kg 11701250 93 69-130
Bromoform ug/kg 12001250 96 70-130
Bromomethane ug/kg 12401250 99 52-130
Carbon tetrachloride ug/kg 12401250 99 70-130
Chlorobenzene ug/kg 11801250 95 70-130
Chloroethane ug/kg 15101250 121 65-130
Chloroform ug/kg 12101250 97 70-130
Chloromethane ug/kg 13901250 111 55-130
cis-1,2-Dichloroethene ug/kg 12301250 98 70-130
cis-1,3-Dichloropropene ug/kg 12501250 100 70-130
Dibromochloromethane ug/kg 12101250 97 70-130
Dibromomethane ug/kg 12601250 101 70-130
Dichlorodifluoromethane ug/kg 1920 IH,v1125015445-156
Diisopropyl ether ug/kg 11701250 93 70-130
Ethylbenzene ug/kg 11501250 92 70-130
Hexachloro-1,3-butadiene ug/kg 13201250 105 66-130
Isopropylbenzene (Cumene)ug/kg 12501250 100 70-130
m&p-Xylene ug/kg 24902500 99 70-130
Methyl-tert-butyl ether ug/kg 11701250 94 70-130
Methylene Chloride ug/kg 11301250 91 65-130
n-Butylbenzene ug/kg 13401250 107 67-130
n-Propylbenzene ug/kg 12601250 101 70-130
Naphthalene ug/kg 13201250 105 70-130
o-Xylene ug/kg 12501250 100 70-130
p-Isopropyltoluene ug/kg 13801250 110 67-130
sec-Butylbenzene ug/kg 13201250 106 69-130
Styrene ug/kg 13001250 104 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92595144
MURPHY #8570
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3593352LABORATORY CONTROL SAMPLE:
LCSSpike
tert-Butylbenzene ug/kg 13201250 105 67-130
Tetrachloroethene ug/kg 11201250 89 70-130
Toluene ug/kg 11601250 93 70-130
trans-1,2-Dichloroethene ug/kg 12601250 101 70-130
trans-1,3-Dichloropropene ug/kg 11901250 95 68-130
Trichloroethene ug/kg 12301250 98 70-130
Trichlorofluoromethane ug/kg 14101250 113 70-130
Vinyl acetate ug/kg 25502500 102 70-130
Vinyl chloride ug/kg 15101250 121 61-130
Xylene (Total)ug/kg 37403750 100 70-130
1,2-Dichloroethane-d4 (S)%84 70-130
4-Bromofluorobenzene (S)%97 69-134
Toluene-d8 (S)%98 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3593353MATRIX SPIKE SAMPLE:
MSSpike
Result
92595346001
1,1,1,2-Tetrachloroethane ug/kg 673806 84 70-131ND
1,1,1-Trichloroethane ug/kg 734806 91 65-133ND
1,1,2,2-Tetrachloroethane ug/kg 656806 81 66-130ND
1,1,2-Trichloroethane ug/kg 680806 84 66-133ND
1,1-Dichloroethane ug/kg 708806 88 65-130ND
1,1-Dichloroethene ug/kg 742806 92 10-158ND
1,1-Dichloropropene ug/kg 760806 94 68-133ND
1,2,3-Trichlorobenzene ug/kg 641806 80 27-138ND
1,2,3-Trichloropropane ug/kg 608806 76 67-130ND
1,2,4-Trichlorobenzene ug/kg 618806 77 51-134ND
1,2,4-Trimethylbenzene ug/kg 674806 84 63-136ND
1,2-Dibromo-3-chloropropane ug/kg 644806 80 32-130ND
1,2-Dibromoethane (EDB)ug/kg 700806 87 70-130ND
1,2-Dichlorobenzene ug/kg 650806 81 69-130ND
1,2-Dichloroethane ug/kg 704806 87 59-130ND
1,2-Dichloropropane ug/kg 721806 90 70-130ND
1,3,5-Trimethylbenzene ug/kg 690806 86 65-137ND
1,3-Dichlorobenzene ug/kg 628806 78 70-130ND
1,3-Dichloropropane ug/kg 699806 87 70-130ND
1,4-Dichlorobenzene ug/kg 633806 79 68-130ND
2,2-Dichloropropane ug/kg 346806 43 32-130ND
2-Butanone (MEK)ug/kg 13401610 81 10-136ND
2-Chlorotoluene ug/kg 652806 81 69-141ND
2-Hexanone ug/kg 12901610 80 10-144ND
4-Chlorotoluene ug/kg 636806 79 70-132ND
4-Methyl-2-pentanone (MIBK)ug/kg 13301610 82 25-143ND
Acetone ug/kg 12901610 80 10-130ND
Benzene ug/kg 706806 88 67-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92595144
MURPHY #8570
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3593353MATRIX SPIKE SAMPLE:
MSSpike
Result
92595346001
Bromobenzene ug/kg 686806 85 70-130ND
Bromochloromethane ug/kg 703806 87 69-134ND
Bromodichloromethane ug/kg 648806 80 64-130ND
Bromoform ug/kg 569806 71 62-130ND
Bromomethane ug/kg 424806 50 20-1760.023 mg/kg
Carbon tetrachloride ug/kg 680806 84 65-140ND
Chlorobenzene ug/kg 713806 89 70-130ND
Chloroethane ug/kg 337806 42 10-130ND
Chloroform ug/kg 728806 90 63-130ND
Chloromethane ug/kg 874806 109 58-130ND
cis-1,2-Dichloroethene ug/kg 748806 93 66-130ND
cis-1,3-Dichloropropene ug/kg 591806 73 67-130ND
Dibromochloromethane ug/kg 600806 74 67-130ND
Dibromomethane ug/kg 678806 84 63-131ND
Dichlorodifluoromethane ug/kg 1040806 129 44-180ND
Diisopropyl ether ug/kg 704806 87 63-130ND
Ethylbenzene ug/kg 679806 84 66-130ND
Hexachloro-1,3-butadiene ug/kg 570806 71 64-150ND
Isopropylbenzene (Cumene)ug/kg 713806 88 69-135ND
m&p-Xylene ug/kg 14201610 88 60-133ND
Methyl-tert-butyl ether ug/kg 683806 85 65-130ND
Methylene Chloride ug/kg 667806 83 61-130ND
n-Butylbenzene ug/kg 582806 72 65-140ND
n-Propylbenzene ug/kg 641806 80 67-140ND
Naphthalene ug/kg 694806 86 15-145ND
o-Xylene ug/kg 721806 89 66-133ND
p-Isopropyltoluene ug/kg 655806 81 56-147ND
sec-Butylbenzene ug/kg 665806 83 65-139ND
Styrene ug/kg 723806 90 70-132ND
tert-Butylbenzene ug/kg 652806 81 62-135ND
Tetrachloroethene ug/kg 599806 74 70-135ND
Toluene ug/kg 698806 87 67-130ND
trans-1,2-Dichloroethene ug/kg 710806 88 69-130ND
trans-1,3-Dichloropropene ug/kg 558806 69 62-130ND
Trichloroethene ug/kg 713806 89 70-135ND
Trichlorofluoromethane ug/kg 337806 42 10-130ND
Vinyl acetate ug/kg 13301610 82 53-130ND
Vinyl chloride ug/kg 886806 110 61-148ND
Xylene (Total)ug/kg 21402420 89 63-132ND
1,2-Dichloroethane-d4 (S)%104 70-130
4-Bromofluorobenzene (S)%100 69-134
Toluene-d8 (S)%100 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92595144
MURPHY #8570
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92595346002
3593354SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/kg ND 30ND
1,1,1-Trichloroethane ug/kg ND 30ND
1,1,2,2-Tetrachloroethane ug/kg ND 30ND
1,1,2-Trichloroethane ug/kg ND 30ND
1,1-Dichloroethane ug/kg ND 30ND
1,1-Dichloroethene ug/kg ND 30ND
1,1-Dichloropropene ug/kg ND 30ND
1,2,3-Trichlorobenzene ug/kg ND 30ND
1,2,3-Trichloropropane ug/kg ND 30ND
1,2,4-Trichlorobenzene ug/kg ND 30ND
1,2,4-Trimethylbenzene ug/kg ND 30ND
1,2-Dibromo-3-chloropropane ug/kg ND 30ND
1,2-Dibromoethane (EDB)ug/kg ND 30ND
1,2-Dichlorobenzene ug/kg ND 30ND
1,2-Dichloroethane ug/kg ND 30ND
1,2-Dichloropropane ug/kg ND 30ND
1,3,5-Trimethylbenzene ug/kg ND 30ND
1,3-Dichlorobenzene ug/kg ND 30ND
1,3-Dichloropropane ug/kg ND 30ND
1,4-Dichlorobenzene ug/kg ND 30ND
2,2-Dichloropropane ug/kg ND 30ND
2-Butanone (MEK)ug/kg ND 30ND
2-Chlorotoluene ug/kg ND 30ND
2-Hexanone ug/kg ND 30ND
4-Chlorotoluene ug/kg ND 30ND
4-Methyl-2-pentanone (MIBK)ug/kg ND 30ND
Acetone ug/kg ND 30ND
Benzene ug/kg ND 30ND
Bromobenzene ug/kg ND 30ND
Bromochloromethane ug/kg ND 30ND
Bromodichloromethane ug/kg ND 30ND
Bromoform ug/kg ND 30ND
Bromomethane ug/kg 15.8 C713300.018 mg/kg
Carbon tetrachloride ug/kg ND 30ND
Chlorobenzene ug/kg ND 30ND
Chloroethane ug/kg ND 30ND
Chloroform ug/kg ND 30ND
Chloromethane ug/kg ND 30ND
cis-1,2-Dichloroethene ug/kg ND 30ND
cis-1,3-Dichloropropene ug/kg ND 30ND
Dibromochloromethane ug/kg ND 30ND
Dibromomethane ug/kg ND 30ND
Dichlorodifluoromethane ug/kg ND IH30ND
Diisopropyl ether ug/kg ND 30ND
Ethylbenzene ug/kg ND 30ND
Hexachloro-1,3-butadiene ug/kg ND 30ND
Isopropylbenzene (Cumene)ug/kg ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92595144
MURPHY #8570
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92595346002
3593354SAMPLE DUPLICATE:
m&p-Xylene ug/kg ND 30ND
Methyl-tert-butyl ether ug/kg ND 30ND
Methylene Chloride ug/kg ND 30ND
n-Butylbenzene ug/kg ND 30ND
n-Propylbenzene ug/kg ND 30ND
Naphthalene ug/kg ND 30ND
o-Xylene ug/kg ND 30ND
p-Isopropyltoluene ug/kg ND 30ND
sec-Butylbenzene ug/kg ND 30ND
Styrene ug/kg ND 30ND
tert-Butylbenzene ug/kg ND 30ND
Tetrachloroethene ug/kg ND 30ND
Toluene ug/kg ND 30ND
trans-1,2-Dichloroethene ug/kg ND 30ND
trans-1,3-Dichloropropene ug/kg ND 30ND
Trichloroethene ug/kg ND 30ND
Trichlorofluoromethane ug/kg ND 30ND
Vinyl acetate ug/kg ND 30ND
Vinyl chloride ug/kg ND 30ND
Xylene (Total)ug/kg ND 30ND
1,2-Dichloroethane-d4 (S)%105103
4-Bromofluorobenzene (S)%99101
Toluene-d8 (S)%101102
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92595144
MURPHY #8570
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
687821
EPA 625.1
EPA 625.1
625 MSS
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92595144004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3595140
Associated Lab Samples:92595144004
Matrix:Water
AnalyzedMDL
1,2,4-Trichlorobenzene ug/L ND 5.0 03/29/22 13:581.7
2,2'-Oxybis(1-chloropropane)ug/L ND 5.0 03/29/22 13:581.2
2,4,6-Trichlorophenol ug/L ND 10.0 03/29/22 13:581.6
2,4-Dichlorophenol ug/L ND 5.0 03/29/22 13:581.4
2,4-Dimethylphenol ug/L ND 10.0 03/29/22 13:581.7
2,4-Dinitrophenol ug/L ND 50.0 03/29/22 13:5826.0
2,4-Dinitrotoluene ug/L ND 5.0 03/29/22 13:581.6
2,6-Dinitrotoluene ug/L ND 5.0 03/29/22 13:581.7
2-Chloronaphthalene ug/L ND 5.0 03/29/22 13:581.7
2-Chlorophenol ug/L ND 5.0 03/29/22 13:581.2
2-Nitrophenol ug/L ND 5.0 03/29/22 13:581.4
3,3'-Dichlorobenzidine ug/L ND 10.0 03/29/22 13:588.1
4,6-Dinitro-2-methylphenol ug/L ND 10.0 03/29/22 13:583.4
4-Bromophenylphenyl ether ug/L ND 5.0 03/29/22 13:581.8
4-Chloro-3-methylphenol ug/L ND 5.0 03/29/22 13:583.3
4-Chlorophenylphenyl ether ug/L ND 5.0 03/29/22 13:582.0
4-Nitrophenol ug/L ND 10.0 03/29/22 13:586.6
Acenaphthene ug/L ND 5.0 03/29/22 13:582.0
Acenaphthylene ug/L ND 5.0 03/29/22 13:582.0
Anthracene ug/L ND 5.0 03/29/22 13:582.3
Benzo(a)anthracene ug/L ND 5.0 03/29/22 13:582.7
Benzo(a)pyrene ug/L ND 5.0 03/29/22 13:582.8
Benzo(b)fluoranthene ug/L ND 5.0 03/29/22 13:582.6
Benzo(g,h,i)perylene ug/L ND 5.0 03/29/22 13:582.8
Benzo(k)fluoranthene ug/L ND 5.0 03/29/22 13:582.7
bis(2-Chloroethoxy)methane ug/L ND 10.0 03/29/22 13:581.8
bis(2-Chloroethyl) ether ug/L ND 5.0 03/29/22 13:581.9
bis(2-Ethylhexyl)phthalate ug/L ND 5.0 03/29/22 13:583.7
Butylbenzylphthalate ug/L ND 5.0 03/29/22 13:583.1
Chrysene ug/L ND 5.0 03/29/22 13:582.8
Di-n-butylphthalate ug/L ND 5.0 03/29/22 13:582.2
Di-n-octylphthalate ug/L ND 5.0 03/29/22 13:583.9
Dibenz(a,h)anthracene ug/L ND 5.0 03/29/22 13:583.0
Diethylphthalate ug/L ND 5.0 03/29/22 13:582.0
Dimethylphthalate ug/L ND 5.0 03/29/22 13:582.1
Fluoranthene ug/L ND 5.0 03/29/22 13:582.2
Fluorene ug/L ND 5.0 03/29/22 13:582.1
Hexachloro-1,3-butadiene ug/L ND 5.0 03/29/22 13:581.8
Hexachlorobenzene ug/L ND 5.0 03/29/22 13:582.2
Hexachlorocyclopentadiene ug/L ND 10.0 03/29/22 13:581.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92595144
MURPHY #8570
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3595140
Associated Lab Samples:92595144004
Matrix:Water
AnalyzedMDL
Hexachloroethane ug/L ND 5.0 03/29/22 13:581.4
Indeno(1,2,3-cd)pyrene ug/L ND 5.0 03/29/22 13:582.9
Isophorone ug/L ND 10.0 03/29/22 13:581.7
N-Nitroso-di-n-propylamine ug/L ND 5.0 03/29/22 13:581.3
N-Nitrosodimethylamine ug/L ND 5.0 03/29/22 13:581.9
N-Nitrosodiphenylamine ug/L ND 10.0 03/29/22 13:583.0
Naphthalene ug/L ND 5.0 03/29/22 13:582.1
Nitrobenzene ug/L ND 5.0 03/29/22 13:581.9
Pentachlorophenol ug/L ND 10.0 03/29/22 13:583.8
Phenanthrene ug/L ND 5.0 03/29/22 13:582.0
Phenol ug/L ND 5.0 03/29/22 13:581.4
Pyrene ug/L ND 5.0 03/29/22 13:582.2
2,4,6-Tribromophenol (S)%118 10-137 03/29/22 13:58
2-Fluorobiphenyl (S)%93 15-120 03/29/22 13:58
2-Fluorophenol (S)%71 10-120 03/29/22 13:58
Nitrobenzene-d5 (S)%96 10-120 03/29/22 13:58
Phenol-d6 (S)%60 10-120 03/29/22 13:58
Terphenyl-d14 (S)%121 11-131 03/29/22 13:58
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3595141LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/L 36.450 73 44-142
2,2'-Oxybis(1-chloropropane)ug/L 43.150 86 36-166
2,4,6-Trichlorophenol ug/L 55.750 111 37-144
2,4-Dichlorophenol ug/L 53.950 108 1-191
2,4-Dimethylphenol ug/L 53.350 107 32-119
2,4-Dinitrophenol ug/L 264250 106 1-181
2,4-Dinitrotoluene ug/L 52.750 105 39-139
2,6-Dinitrotoluene ug/L 52.150 104 50-158
2-Chloronaphthalene ug/L 39.650 79 60-118
2-Chlorophenol ug/L 45.050 90 23-134
2-Nitrophenol ug/L 50.050 100 29-182
3,3'-Dichlorobenzidine ug/L 100100 100 1-262
4,6-Dinitro-2-methylphenol ug/L 104100 104 1-181
4-Bromophenylphenyl ether ug/L 53.650 107 53-127
4-Chloro-3-methylphenol ug/L 103100 103 22-147
4-Chlorophenylphenyl ether ug/L 51.650 103 25-158
4-Nitrophenol ug/L 163250 65 1-132
Acenaphthene ug/L 43.250 86 47-145
Acenaphthylene ug/L 46.550 93 33-145
Anthracene ug/L 50.650 101 1-166
Benzo(a)anthracene ug/L 54.050 108 33-143
Benzo(a)pyrene ug/L 57.050 114 17-163
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92595144
MURPHY #8570
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3595141LABORATORY CONTROL SAMPLE:
LCSSpike
Benzo(b)fluoranthene ug/L 55.550 111 24-159
Benzo(g,h,i)perylene ug/L 56.650 113 1-219
Benzo(k)fluoranthene ug/L 56.550 113 11-162
bis(2-Chloroethoxy)methane ug/L 52.350 105 33-184
bis(2-Chloroethyl) ether ug/L 52.550 105 12-158
bis(2-Ethylhexyl)phthalate ug/L 54.150 108 8-158
Butylbenzylphthalate ug/L 55.750 111 1-152
Chrysene ug/L 53.050 106 17-168
Di-n-butylphthalate ug/L 54.550 109 1-118
Di-n-octylphthalate ug/L 58.150 116 4-146
Dibenz(a,h)anthracene ug/L 57.050 114 1-227
Diethylphthalate ug/L 51.650 103 1-114
Dimethylphthalate ug/L 52.050 104 1-112
Fluoranthene ug/L 56.450 113 26-137
Fluorene ug/L 49.450 99 59-121
Hexachloro-1,3-butadiene ug/L 36.050 72 24-116
Hexachlorobenzene ug/L 50.350 101 1-152
Hexachlorocyclopentadiene ug/L 34.850 70 25-150
Hexachloroethane ug/L 33.750 67 40-113
Indeno(1,2,3-cd)pyrene ug/L 56.450 113 1-171
Isophorone ug/L 49.050 98 21-196
N-Nitroso-di-n-propylamine ug/L 48.250 96 1-230
N-Nitrosodimethylamine ug/L 42.750 85 25-150
N-Nitrosodiphenylamine ug/L 50.250 100 25-150
Naphthalene ug/L 39.150 78 21-133
Nitrobenzene ug/L 47.050 94 35-180
Pentachlorophenol ug/L 103100 103 14-176
Phenanthrene ug/L 50.750 101 54-120
Phenol ug/L 32.050 64 5-112
Pyrene ug/L 53.950 108 52-115
2,4,6-Tribromophenol (S)%126 10-137
2-Fluorobiphenyl (S)%102 15-120
2-Fluorophenol (S)%81 10-120
Nitrobenzene-d5 (S)%110 10-120
Phenol-d6 (S)%71 10-120
Terphenyl-d14 (S)%118 11-131
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3595142MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35705651001
3595143
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,2,4-Trichlorobenzene ug/L M1,R1502744-14242 43 30501.7U 13.5 20.8
2,2'-Oxybis(1-
chloropropane)ug/L 50 46 36-16648 6 30501.2U 22.8 24.1
2,4,6-Trichlorophenol ug/L M1,R1502037-14452 88 30501.6U 10.2 26.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 39 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92595144
MURPHY #8570
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3595142MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35705651001
3595143
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
2,4-Dichlorophenol ug/L R150461-19167 38 30501.4U 22.9 33.7
2,4-Dimethylphenol ug/L 50 59 32-11965 9 30501.7U 29.7 32.5
2,4-Dinitrophenol ug/L M125001-1810 3025026.0U ND ND
2,4-Dinitrotoluene ug/L 50 68 39-13978 14 30501.6U 33.9 38.9
2,6-Dinitrotoluene ug/L 50 64 50-15877 19 30501.7U 32.1 38.7
2-Chloronaphthalene ug/L M1504760-11855 15 30501.7U 23.7 27.4
2-Chlorophenol ug/L 50 41 23-13449 20 30501.2U 20.3 24.7
2-Nitrophenol ug/L 50 41 29-18253 24 30501.4U 20.7 26.3
3,3'-Dichlorobenzidine ug/L R1100321-26222 35 301008.1U 32.0 22.4
4,6-Dinitro-2-methylphenol ug/L 100 6 1-18110 301003.4U 6.4J 10.3
4-Bromophenylphenyl ether ug/L 50 68 53-12781 18 30501.8U 33.9 40.7
4-Chloro-3-methylphenol ug/L 100 71 22-14787 20 301003.3U 70.6 86.6
4-Chlorophenylphenyl ether ug/L 50 62 25-15876 21 30502.0U 31.0 38.1
4-Nitrophenol ug/L 250 3 1-1325 302506.6U 7.0J 12.7
Acenaphthene ug/L 50 52 47-14561 17 30502.0U 26.0 30.7
Acenaphthylene ug/L 50 55 33-14565 16 30502.0U 27.5 32.3
Anthracene ug/L 50 73 1-16682 12 30502.3U 36.3 41.0
Benzo(a)anthracene ug/L 50 85 33-14399 15 30502.7U 42.6 49.3
Benzo(a)pyrene ug/L 50 88 17-163104 16 30502.8U 44.1 52.0
Benzo(b)fluoranthene ug/L 50 88 24-159103 16 30502.6U 43.8 51.7
Benzo(g,h,i)perylene ug/L 50 91 1-219108 17 30502.8U 45.6 54.0
Benzo(k)fluoranthene ug/L 50 85 11-162101 18 30502.7U 42.5 50.7
bis(2-
Chloroethoxy)methane ug/L 50 54 33-18456 4 30501.8U 27.2 28.2
bis(2-Chloroethyl) ether ug/L 50 56 12-15860 7 30501.9U 27.9 29.8
bis(2-Ethylhexyl)phthalate ug/L 50 85 8-158102 18 30503.7U 42.4 51.0
Butylbenzylphthalate ug/L 50 89 1-152105 17 30503.1U 44.4 52.4
Chrysene ug/L 50 84 17-16897 15 30502.8U 41.8 48.5
Di-n-butylphthalate ug/L 50 85 1-11899 15 30502.2U 42.6 49.6
Di-n-octylphthalate ug/L 50 91 4-146111 20 30503.9U 45.6 55.6
Dibenz(a,h)anthracene ug/L 50 90 1-227107 18 30503.0U 45.0 53.7
Diethylphthalate ug/L 50 67 1-11478 15 30502.0U 33.5 39.0
Dimethylphthalate ug/L 50 58 1-11270 19 30502.1U 29.2 35.2
Fluoranthene ug/L 50 90 26-137103 13 30502.2U 45.2 51.6
Fluorene ug/L 50 59 59-12172 21 30502.1U 29.3 36.0
Hexachloro-1,3-butadiene ug/L M1,R1502224-11639 57 30501.8U 10.9 19.5
Hexachlorobenzene ug/L 50 63 1-15276 20 30502.2U 31.3 38.2
Hexachlorocyclopentadiene ug/L 50 25 25-15031 24 30501.6U 12.3 15.6
Hexachloroethane ug/L M1,R1502040-11335 56 30501.4U 9.8 17.5
Indeno(1,2,3-cd)pyrene ug/L 50 89 1-171105 16 30502.9U 44.5 52.4
Isophorone ug/L 50 50 21-19654 6 30501.7U 25.2 26.8
N-Nitroso-di-n-propylamine ug/L 50 50 1-23053 6 30501.3U 25.0 26.4
N-Nitrosodimethylamine ug/L 50 46 25-15045 1 30501.9U 22.8 22.6
N-Nitrosodiphenylamine ug/L 50 73 25-15083 13 30503.0U 36.5 41.5
Naphthalene ug/L R1503321-13345 31 30502.1U 16.4 22.4
Nitrobenzene ug/L 50 73 35-18077 6 30501.9U 36.4 38.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 40 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92595144
MURPHY #8570
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3595142MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35705651001
3595143
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Pentachlorophenol ug/L M1100014-17622 301003.8U ND 22.3
Phenanthrene ug/L 50 73 54-12083 13 30502.0U 36.7 41.7
Phenol ug/L 50 36 5-11240 9 30501.4U 18.1 19.9
Pyrene ug/L 50 86 52-11599 14 30502.2U 42.9 49.5
2,4,6-Tribromophenol (S)%41 10-13793
2-Fluorobiphenyl (S)%55 15-12061
2-Fluorophenol (S)%23 10-12035
Nitrobenzene-d5 (S)%58 10-12063
Phenol-d6 (S)%39 10-12043
Terphenyl-d14 (S)%89 11-131106
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 41 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92595144
MURPHY #8570
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
687013
EPA 3546
EPA 8015C
8015 Solid GCSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92595144001, 92595144002, 92595144003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3591210
Associated Lab Samples:92595144001, 92595144002, 92595144003
Matrix:Solid
AnalyzedMDL
Diesel Range Organics(C10-C28)mg/kg ND 5.0 03/25/22 09:433.5
n-Pentacosane (S)%64 32-130 03/25/22 09:43
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3591211LABORATORY CONTROL SAMPLE:
LCSSpike
Diesel Range Organics(C10-C28)mg/kg 56.167.8 83 47-130
n-Pentacosane (S)%78 32-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3591212MATRIX SPIKE SAMPLE:
MSSpike
Result
92594304006
Diesel Range Organics(C10-C28)mg/kg 87.670.4 66 10-13341.0
n-Pentacosane (S)%67 32-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92594562005
3591213SAMPLE DUPLICATE:
Diesel Range Organics(C10-C28)mg/kg 14.4 D6373020.8
n-Pentacosane (S)%7962
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 42 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92595144
MURPHY #8570
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
687077
EPA 3546
EPA 8270E
8270E Solid MSSV Microwave
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92595144001, 92595144002, 92595144003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3591638
Associated Lab Samples:92595144001, 92595144002, 92595144003
Matrix:Solid
AnalyzedMDL
1,2,4-Trichlorobenzene ug/kg ND 325 03/25/22 09:10128
1,2-Dichlorobenzene ug/kg ND 325 03/25/22 09:10117
1,3-Dichlorobenzene ug/kg ND 325 03/25/22 09:10115
1,4-Dichlorobenzene ug/kg ND 325 03/25/22 09:10124
1-Methylnaphthalene ug/kg ND 325 03/25/22 09:10114
2,2'-Oxybis(1-chloropropane)ug/kg ND 325 03/25/22 09:10154
2,4,5-Trichlorophenol ug/kg ND 325 03/25/22 09:10149
2,4,6-Trichlorophenol ug/kg ND 325 03/25/22 09:10134
2,4-Dichlorophenol ug/kg ND 325 03/25/22 09:10127
2,4-Dimethylphenol ug/kg ND 325 03/25/22 09:10135
2,4-Dinitrophenol ug/kg ND 1620 03/25/22 09:101000
2,4-Dinitrotoluene ug/kg ND 325 03/25/22 09:10125
2,6-Dinitrotoluene ug/kg ND 325 03/25/22 09:10119
2-Chloronaphthalene ug/kg ND 325 03/25/22 09:10129
2-Chlorophenol ug/kg ND 325 03/25/22 09:10122
2-Methylnaphthalene ug/kg ND 325 03/25/22 09:10130
2-Methylphenol(o-Cresol)ug/kg ND 325 03/25/22 09:10133
2-Nitroaniline ug/kg ND 1620 03/25/22 09:10266
2-Nitrophenol ug/kg ND 325 03/25/22 09:10141
3&4-Methylphenol(m&p Cresol)ug/kg ND 325 03/25/22 09:10131
3,3'-Dichlorobenzidine ug/kg ND 649 IL03/25/22 09:10219
3-Nitroaniline ug/kg ND 1620 IL03/25/22 09:10255
4,6-Dinitro-2-methylphenol ug/kg ND 649 03/25/22 09:10303
4-Bromophenylphenyl ether ug/kg ND 325 03/25/22 09:10125
4-Chloro-3-methylphenol ug/kg ND 649 03/25/22 09:10228
4-Chloroaniline ug/kg ND 649 03/25/22 09:10255
4-Chlorophenylphenyl ether ug/kg ND 325 03/25/22 09:10121
4-Nitroaniline ug/kg ND 649 IL03/25/22 09:10247
4-Nitrophenol ug/kg ND 1620 03/25/22 09:10628
Acenaphthene ug/kg ND 325 03/25/22 09:10114
Acenaphthylene ug/kg ND 325 03/25/22 09:10114
Aniline ug/kg ND 325 03/25/22 09:10127
Anthracene ug/kg ND 325 03/25/22 09:10106
Benzo(a)anthracene ug/kg ND 325 03/25/22 09:10108
Benzo(a)pyrene ug/kg ND 325 03/25/22 09:10112
Benzo(b)fluoranthene ug/kg ND 325 03/25/22 09:10108
Benzo(g,h,i)perylene ug/kg ND 325 03/25/22 09:10126
Benzo(k)fluoranthene ug/kg ND 325 03/25/22 09:10114
Benzoic Acid ug/kg ND 1620 03/25/22 09:10697
Benzyl alcohol ug/kg ND 649 03/25/22 09:10246
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 43 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92595144
MURPHY #8570
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3591638
Associated Lab Samples:92595144001, 92595144002, 92595144003
Matrix:Solid
AnalyzedMDL
bis(2-Chloroethoxy)methane ug/kg ND 325 03/25/22 09:10135
bis(2-Chloroethyl) ether ug/kg ND 325 03/25/22 09:10122
bis(2-Ethylhexyl)phthalate ug/kg ND 325 03/25/22 09:10126
Butylbenzylphthalate ug/kg ND 325 03/25/22 09:10137
Chrysene ug/kg ND 325 03/25/22 09:10118
Di-n-butylphthalate ug/kg ND 325 03/25/22 09:10109
Di-n-octylphthalate ug/kg ND 325 03/25/22 09:10128
Dibenz(a,h)anthracene ug/kg ND 325 03/25/22 09:10125
Dibenzofuran ug/kg ND 325 03/25/22 09:10117
Diethylphthalate ug/kg ND 325 03/25/22 09:10119
Dimethylphthalate ug/kg ND 325 03/25/22 09:10118
Fluoranthene ug/kg ND 325 03/25/22 09:10111
Fluorene ug/kg ND 325 03/25/22 09:10114
Hexachloro-1,3-butadiene ug/kg ND 325 03/25/22 09:10141
Hexachlorobenzene ug/kg ND 325 03/25/22 09:10127
Hexachlorocyclopentadiene ug/kg ND 325 03/25/22 09:10186
Hexachloroethane ug/kg ND 325 03/25/22 09:10124
Indeno(1,2,3-cd)pyrene ug/kg ND 325 03/25/22 09:10128
Isophorone ug/kg ND 325 03/25/22 09:10145
N-Nitroso-di-n-propylamine ug/kg ND 325 03/25/22 09:10122
N-Nitrosodimethylamine ug/kg ND 325 03/25/22 09:10109
N-Nitrosodiphenylamine ug/kg ND 325 03/25/22 09:10115
Naphthalene ug/kg ND 325 03/25/22 09:10110
Nitrobenzene ug/kg ND 325 03/25/22 09:10150
Pentachlorophenol ug/kg ND 649 03/25/22 09:10318
Phenanthrene ug/kg ND 325 03/25/22 09:10106
Phenol ug/kg ND 325 03/25/22 09:10145
Pyrene ug/kg ND 325 03/25/22 09:10132
Pyridine ug/kg ND 325 03/25/22 09:10102
2,4,6-Tribromophenol (S)%88 18-130 03/25/22 09:10
2-Fluorobiphenyl (S)%75 19-130 03/25/22 09:10
2-Fluorophenol (S)%72 18-130 03/25/22 09:10
Nitrobenzene-d5 (S)%72 21-130 03/25/22 09:10
Phenol-d6 (S)%72 18-130 03/25/22 09:10
Terphenyl-d14 (S)%88 15-130 03/25/22 09:10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3591639LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/kg 12101640 73 47-130
1,2-Dichlorobenzene ug/kg 12001640 73 49-130
1,3-Dichlorobenzene ug/kg 12001640 73 48-130
1,4-Dichlorobenzene ug/kg 12001640 73 49-130
1-Methylnaphthalene ug/kg 12501640 76 54-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 44 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92595144
MURPHY #8570
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3591639LABORATORY CONTROL SAMPLE:
LCSSpike
2,2'-Oxybis(1-chloropropane)ug/kg 10801640 66 38-130
2,4,5-Trichlorophenol ug/kg 13801640 84 49-130
2,4,6-Trichlorophenol ug/kg 14001640 85 50-130
2,4-Dichlorophenol ug/kg 13201640 80 51-130
2,4-Dimethylphenol ug/kg 12601640 77 53-130
2,4-Dinitrophenol ug/kg 64408220 78 39-130
2,4-Dinitrotoluene ug/kg 13901640 84 53-130
2,6-Dinitrotoluene ug/kg 14501640 88 55-130
2-Chloronaphthalene ug/kg 12801640 78 48-130
2-Chlorophenol ug/kg 12301640 75 54-130
2-Methylnaphthalene ug/kg 12701640 77 57-130
2-Methylphenol(o-Cresol)ug/kg 12201640 74 50-130
2-Nitroaniline ug/kg 23503290 71 49-130
2-Nitrophenol ug/kg 14501640 88 50-130
3&4-Methylphenol(m&p Cresol)ug/kg 11901640 72 50-130
3,3'-Dichlorobenzidine ug/kg 2380 IL32907247-130
3-Nitroaniline ug/kg 2340 IL32907145-130
4,6-Dinitro-2-methylphenol ug/kg 26503290 81 50-142
4-Bromophenylphenyl ether ug/kg 14001640 85 55-130
4-Chloro-3-methylphenol ug/kg 24903290 76 52-130
4-Chloroaniline ug/kg 22603290 69 49-130
4-Chlorophenylphenyl ether ug/kg 13101640 79 53-130
4-Nitroaniline ug/kg 2420 IL32907451-130
4-Nitrophenol ug/kg 63708220 78 40-130
Acenaphthene ug/kg 13101640 80 56-130
Acenaphthylene ug/kg 13201640 80 58-130
Aniline ug/kg 10901640 66 44-130
Anthracene ug/kg 12801640 78 60-130
Benzo(a)anthracene ug/kg 13301640 81 59-130
Benzo(a)pyrene ug/kg 13001640 79 57-130
Benzo(b)fluoranthene ug/kg 13001640 79 54-130
Benzo(g,h,i)perylene ug/kg 13401640 82 59-130
Benzo(k)fluoranthene ug/kg 13101640 80 54-130
Benzoic Acid ug/kg 40708220 49 19-130
Benzyl alcohol ug/kg 23203290 70 50-130
bis(2-Chloroethoxy)methane ug/kg 11901640 72 55-130
bis(2-Chloroethyl) ether ug/kg 11401640 69 53-130
bis(2-Ethylhexyl)phthalate ug/kg 13601640 83 58-130
Butylbenzylphthalate ug/kg 15101640 92 46-138
Chrysene ug/kg 13001640 79 57-130
Di-n-butylphthalate ug/kg 13001640 79 57-130
Di-n-octylphthalate ug/kg 14301640 87 57-130
Dibenz(a,h)anthracene ug/kg 13301640 81 60-130
Dibenzofuran ug/kg 13001640 79 54-130
Diethylphthalate ug/kg 12701640 77 55-130
Dimethylphthalate ug/kg 13001640 79 57-130
Fluoranthene ug/kg 12801640 78 57-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 45 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92595144
MURPHY #8570
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3591639LABORATORY CONTROL SAMPLE:
LCSSpike
Fluorene ug/kg 13301640 81 56-130
Hexachloro-1,3-butadiene ug/kg 12401640 76 41-130
Hexachlorobenzene ug/kg 13601640 83 53-130
Hexachlorocyclopentadiene ug/kg 11601640 71 23-130
Hexachloroethane ug/kg 11901640 72 48-130
Indeno(1,2,3-cd)pyrene ug/kg 12801640 78 61-130
Isophorone ug/kg 11401640 69 49-130
N-Nitroso-di-n-propylamine ug/kg 11101640 68 52-130
N-Nitrosodimethylamine ug/kg 10901640 66 45-130
N-Nitrosodiphenylamine ug/kg 13101640 80 56-130
Naphthalene ug/kg 12601640 77 56-130
Nitrobenzene ug/kg 11701640 71 50-130
Pentachlorophenol ug/kg 28203290 86 33-130
Phenanthrene ug/kg 13501640 82 60-130
Phenol ug/kg 13301640 81 54-130
Pyrene ug/kg 15401640 93 61-130
Pyridine ug/kg 9321640 57 35-130
2,4,6-Tribromophenol (S)%97 18-130
2-Fluorobiphenyl (S)%78 19-130
2-Fluorophenol (S)%77 18-130
Nitrobenzene-d5 (S)%75 21-130
Phenol-d6 (S)%76 18-130
Terphenyl-d14 (S)%88 15-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3591640MATRIX SPIKE SAMPLE:
MSSpike
Result
92594897001
1,2,4-Trichlorobenzene ug/kg 14601970 74 22-130ND
1,2-Dichlorobenzene ug/kg 15201970 77 23-130ND
1,3-Dichlorobenzene ug/kg 15201970 77 26-130ND
1,4-Dichlorobenzene ug/kg 14901970 75 27-130ND
1-Methylnaphthalene ug/kg 16201970 80 30-130ND
2,2'-Oxybis(1-chloropropane)ug/kg 19301970 97 30-130ND
2,4,5-Trichlorophenol ug/kg 14801970 75 26-130ND
2,4,6-Trichlorophenol ug/kg 15401970 78 23-130ND
2,4-Dichlorophenol ug/kg 16401970 83 29-130ND
2,4-Dimethylphenol ug/kg 14401970 73 13-130ND
2,4-Dinitrophenol ug/kg ND M19870010-131ND
2,4-Dinitrotoluene ug/kg 15801970 80 28-130ND
2,6-Dinitrotoluene ug/kg 15501970 79 36-130ND
2-Chloronaphthalene ug/kg 15001970 76 27-130ND
2-Chlorophenol ug/kg 15501970 79 29-130ND
2-Methylnaphthalene ug/kg 16801970 82 29-130ND
2-Methylphenol(o-Cresol)ug/kg 15501970 78 20-130ND
2-Nitroaniline ug/kg 29303950 74 29-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 46 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92595144
MURPHY #8570
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3591640MATRIX SPIKE SAMPLE:
MSSpike
Result
92594897001
2-Nitrophenol ug/kg 17601970 89 26-130ND
3&4-Methylphenol(m&p Cresol)ug/kg 15701970 80 10-176ND
3,3'-Dichlorobenzidine ug/kg 776J3950 20 15-130ND
3-Nitroaniline ug/kg 31903950 81 28-130ND
4,6-Dinitro-2-methylphenol ug/kg 11803950 30 15-132ND
4-Bromophenylphenyl ether ug/kg 13401970 68 35-130ND
4-Chloro-3-methylphenol ug/kg 31403950 79 30-130ND
4-Chloroaniline ug/kg 20103950 51 28-130ND
4-Chlorophenylphenyl ether ug/kg 13101970 66 32-130ND
4-Nitroaniline ug/kg 25503950 65 30-130ND
4-Nitrophenol ug/kg 68909870 70 17-130ND
Acenaphthene ug/kg 15901970 80 29-130ND
Acenaphthylene ug/kg 39101970 102 31-1301.9 mg/kg
Aniline ug/kg 7921970 40 10-130ND
Anthracene ug/kg 26401970 88 33-1300.89 mg/kg
Benzo(a)anthracene ug/kg 6070 M119702832-1305.5 mg/kg
Benzo(a)pyrene ug/kg 49401970 66 32-1303.6 mg/kg
Benzo(b)fluoranthene ug/kg 61701970 46 33-1305.3 mg/kg
Benzo(g,h,i)perylene ug/kg 3770 M119702328-1303.3 mg/kg
Benzo(k)fluoranthene ug/kg 31001970 79 31-1301.5 mg/kg
Benzoic Acid ug/kg ND M19870610-130ND
Benzyl alcohol ug/kg 30503950 77 31-130ND
bis(2-Chloroethoxy)methane ug/kg 15201970 77 30-130ND
bis(2-Chloroethyl) ether ug/kg 17701970 90 68-130ND
bis(2-Ethylhexyl)phthalate ug/kg 2500 v1197012640-130ND
Butylbenzylphthalate ug/kg 1860 v119709440-130ND
Chrysene ug/kg 59801970 68 30-1304.6 mg/kg
Di-n-butylphthalate ug/kg 15601970 79 41-130ND
Di-n-octylphthalate ug/kg 2160 v1197010942-130ND
Dibenz(a,h)anthracene ug/kg 18101970 65 27-1300.53 mg/kg
Dibenzofuran ug/kg 15001970 76 32-130ND
Diethylphthalate ug/kg 15001970 76 40-130ND
Dimethylphthalate ug/kg 14901970 76 37-130ND
Fluoranthene ug/kg 7280 M11970-23 26-1307.7 mg/kg
Fluorene ug/kg 16801970 76 31-130ND
Hexachloro-1,3-butadiene ug/kg 12001970 61 20-130ND
Hexachlorobenzene ug/kg 13701970 69 29-130ND
Hexachlorocyclopentadiene ug/kg ND M1,v31970710-130ND
Hexachloroethane ug/kg 16701970 84 21-130ND
Indeno(1,2,3-cd)pyrene ug/kg 32501970 47 28-1302.3 mg/kg
Isophorone ug/kg 14601970 74 32-130ND
N-Nitroso-di-n-propylamine ug/kg 14901970 75 31-130ND
N-Nitrosodimethylamine ug/kg 14301970 72 20-130ND
N-Nitrosodiphenylamine ug/kg 15101970 77 32-130ND
Naphthalene ug/kg 16801970 85 30-130ND
Nitrobenzene ug/kg 15501970 78 25-130ND
Pentachlorophenol ug/kg 27703950 70 10-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 47 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92595144
MURPHY #8570
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3591640MATRIX SPIKE SAMPLE:
MSSpike
Result
92594897001
Phenanthrene ug/kg 3300 M119702134-1302.9 mg/kg
Phenol ug/kg 15901970 81 14-130ND
Pyrene ug/kg 13100 IL,M11970-172 31-13016.5 mg/kg
Pyridine ug/kg 13301970 67 10-130ND
2,4,6-Tribromophenol (S)%82 18-130
2-Fluorobiphenyl (S)%64 19-130
2-Fluorophenol (S)%76 18-130
Nitrobenzene-d5 (S)%75 21-130
Phenol-d6 (S)%76 18-130
Terphenyl-d14 (S)%66 15-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 48 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92595144
MURPHY #8570
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
687452
SW-846
SW-846
Dry Weight/Percent Moisture
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92595144001, 92595144003
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92593863002
3593615SAMPLE DUPLICATE:
Percent Moisture %52.5 N202552.5
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92594633002
3593616SAMPLE DUPLICATE:
Percent Moisture %38.6 N232540.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 49 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92595144
MURPHY #8570
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
687716
SW-846
SW-846
Dry Weight/Percent Moisture
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92595144002
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92595227001
3594802SAMPLE DUPLICATE:
Percent Moisture %14.6 N202514.6
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92595489002
3595725SAMPLE DUPLICATE:
Percent Moisture %93.6 N202593.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 50 of 68
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92595144
MURPHY #8570
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Analyte is a possible laboratory contaminant (not present in method blank).C7
Result may be biased high due to carryover from previously analyzed sample.C8
The precision between the sample and sample duplicate exceeded laboratory control limits.D6
This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be
considered an estimated value.IH
This analyte exceeded secondary source verification criteria low for the initial calibration. The reported results should be
considered an estimated value.IL
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The reported TIC has an 85% or higher match on a mass spectral library search.N
The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.N2
RPD value was outside control limits.R1
The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.v1
The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.v3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 51 of 68
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92595144
MURPHY #8570
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92595144001 687013 687284SB-1 (10-12)EPA 3546 EPA 8015C
92595144002 687013 687284SB-2 (10-12)EPA 3546 EPA 8015C
92595144003 687013 687284SB-3 (10-12)EPA 3546 EPA 8015C
92595144001 687327 687345SB-1 (10-12)EPA 5030B EPA 8015C
92595144002 687327 687345SB-2 (10-12)EPA 5030B EPA 8015C
92595144003 687327 687345SB-3 (10-12)EPA 5030B EPA 8015C
92595144004 687335SB-2 MADEP VPH
92595144004 687821 688000SB-2 EPA 625.1 EPA 625.1
92595144001 687077 687234SB-1 (10-12)EPA 3546 EPA 8270E
92595144002 687077 687234SB-2 (10-12)EPA 3546 EPA 8270E
92595144003 687077 687234SB-3 (10-12)EPA 3546 EPA 8270E
92595144004 687023SB-2 SM 6200B
92595144004 687418SB-2 SM 6200B
92595144001 687424 687637SB-1 (10-12)EPA 5035A/5030B EPA 8260D
92595144002 687424 687637SB-2 (10-12)EPA 5035A/5030B EPA 8260D
92595144003 687424 687637SB-3 (10-12)EPA 5035A/5030B EPA 8260D
92595144001 687452SB-1 (10-12)SW-846
92595144002 687716SB-2 (10-12)SW-846
92595144003 687452SB-3 (10-12)SW-846
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/06/2022 07:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 52 of 68
Page 53 of 68
Page 54 of 68
Page 55 of 68
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
April 6, 2022
Angela Baioni
Pace Analytical Services - NC
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Project Location: Murphy #8570
Client Job Number:
Project Number: 92595144
Laboratory Work Order Number: 22C1691
Enclosed are results of analyses for samples as received by the laboratory on March 25, 2022. If you have any questions
concerning this report, please feel free to contact me.
Sincerely,
Raymond J. McCarthy
Project Manager
Page 1 of 13
Table of Contents
Page 56 of 68
Table of Contents
Sample Summary 3
Case Narrative 4
Sample Results 5
22C1691-01 5
Sample Preparation Information 6
QC Data 7
Petroleum Hydrocarbons Analyses - EPH 7
B304272 7
Flag/Qualifier Summary 9
Certifications 10
Chain of Custody/Sample Receipt 11
Page 2 of 13
Table of Contents
Page 57 of 68
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYTICAL SUMMARY
4/6/2022
Pace Analytical Services - NC
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
ATTN: Angela Baioni
92595144
22C1691
The results of analyses performed on the following samples submitted to CON-TEST, a Pace Analytical Laboratory, are found in this report.
PROJECT LOCATION:
PURCHASE ORDER NUMBER:
PROJECT NUMBER:
REPORT DATE:
WORK ORDER NUMBER:
FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB
Murphy #8570
SB-2 22C1691-01 Water MADEP EPH rev 2.1
[TOC_1]Sample Summary[TOC]
Page 3 of 13
Table of Contents
Page 58 of 68
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CASE NARRATIVE SUMMARY
All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report.
For method MA EPH, only hydrocarbon ranges were requested and reported.
[TOC_1]Case Narrative[TOC]
The results of analyses reported only relate to samples submitted to Con-Test, a Pace Analytical Laboratory, for testing.
I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed
in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the
best of my knowledge and belief, accurate and complete.
Lisa A. Worthington
Technical Representative
Page 4 of 13
Table of Contents
Page 59 of 68
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 3/25/2022
Work Order: 22C1691Sample Description:Project Location: Murphy #8570
Sample ID: 22C1691-01
Field Sample #: SB-2
Sample Matrix: Water
Sampled: 3/22/2022 14:40
[TOC_2]22C1691-01[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
Units
Date
PreparedMethod
Petroleum Hydrocarbons Analyses - EPH
ND 95 4/5/22 19:16 TYHg/L 3/28/22MADEP EPH rev 2.11C9-C18 Aliphatics
ND 95 4/5/22 19:16 TYHg/L 3/28/22MADEP EPH rev 2.11C19-C36 Aliphatics
ND 95 4/5/22 19:16 TYHg/L 3/28/22MADEP EPH rev 2.11Unadjusted C11-C22 Aromatics
ND 95 4/5/22 19:16 TYHg/L 3/28/22MADEP EPH rev 2.11C11-C22 Aromatics
Surrogates % Recovery Recovery Limits Flag/Qual
Chlorooctadecane (COD)75.2 4/5/22 19:1640-140
o-Terphenyl (OTP)75.4 4/5/22 19:1640-140
2-Bromonaphthalene 107 4/5/22 19:1640-140
2-Fluorobiphenyl 105 4/5/22 19:1640-140
[TOC_1]Sample Results[TOC]
Page 5 of 13
Table of Contents
Page 60 of 68
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Sample Extraction Data
Prep Method: SW-846 3510C Analytical Method: MADEP EPH rev 2.1
Lab Number [Field ID]Batch DateInitial [mL]Final [mL]
B304272 03/28/221050 2.0022C1691-01 [SB-2]
[TOC_1]Sample Preparation Information[TOC]
Page 6 of 13
Table of Contents
Page 61 of 68
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Petroleum Hydrocarbons Analyses - EPH - Quality Control
QUALITY CONTROL
[TOC_2]Petroleum Hydrocarbons Analyses - EPH[TOC]
Batch B304272 - SW-846 3510C
[TOC_3]B304272[TOC]
Blank (B304272-BLK1) Prepared: 03/28/22 Analyzed: 03/30/22
C9-C18 Aliphatics g/L100ND
C19-C36 Aliphatics g/L100ND
Unadjusted C11-C22 Aromatics g/L100ND
C11-C22 Aromatics g/L100ND
Acenaphthene g/L2.0ND
Acenaphthylene g/L2.0ND
Anthracene g/L2.0ND
Benzo(a)anthracene g/L2.0ND
Benzo(a)pyrene g/L2.0ND
Benzo(b)fluoranthene g/L2.0ND
Benzo(g,h,i)perylene g/L2.0ND
Benzo(k)fluoranthene g/L2.0ND
Chrysene g/L2.0ND
Dibenz(a,h)anthracene g/L2.0ND
Fluoranthene g/L2.0ND
Fluorene g/L2.0ND
Indeno(1,2,3-cd)pyrene g/L2.0ND
2-Methylnaphthalene g/L2.0ND
Naphthalene g/L2.0ND
Phenanthrene g/L2.0ND
Pyrene g/L2.0ND
Naphthalene-aliphatic fraction g/L2.0ND
2-Methylnaphthalene-aliphatic fraction g/L2.0ND
g/L 100 40-140Surrogate: Chlorooctadecane (COD)84.484.4
g/L 100 40-140Surrogate: o-Terphenyl (OTP)80.580.5
g/L 100 40-140Surrogate: 2-Bromonaphthalene 107107
g/L 100 40-140Surrogate: 2-Fluorobiphenyl 107107
LCS (B304272-BS1) Prepared: 03/28/22 Analyzed: 03/30/22
C9-C18 Aliphatics g/L100 600 40-14073.0438
C19-C36 Aliphatics g/L100 800 40-14097.8782
Unadjusted C11-C22 Aromatics g/L100 1700 40-14082.41400
Acenaphthene g/L2.0 100 40-14075.175.1
Acenaphthylene g/L2.0 100 40-14070.570.5
Anthracene g/L2.0 100 40-14081.681.6
Benzo(a)anthracene g/L2.0 100 40-14086.586.5
Benzo(a)pyrene g/L2.0 100 40-14078.778.7
Benzo(b)fluoranthene g/L2.0 100 40-14080.980.9
Benzo(g,h,i)perylene g/L2.0 100 40-14071.271.2
Benzo(k)fluoranthene g/L2.0 100 40-14072.872.8
Chrysene g/L2.0 100 40-14081.881.8
Dibenz(a,h)anthracene g/L2.0 100 40-14076.876.8
Fluoranthene g/L2.0 100 40-14082.782.7
Fluorene g/L2.0 100 40-14079.779.7
Indeno(1,2,3-cd)pyrene g/L2.0 100 40-14073.873.8
2-Methylnaphthalene g/L2.0 100 40-14068.668.6
Naphthalene g/L2.0 100 40-14062.362.3
Phenanthrene g/L2.0 100 40-14082.982.9
Pyrene g/L2.0 100 40-14083.783.7
Naphthalene-aliphatic fraction g/L2.0 100 0-5ND
2-Methylnaphthalene-aliphatic fraction g/L2.0 100 0-5ND
g/L 100 40-140Surrogate: Chlorooctadecane (COD)86.886.8
[TOC_1]QC Data[TOC]
Page 7 of 13
Table of Contents
Page 62 of 68
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Petroleum Hydrocarbons Analyses - EPH - Quality Control
QUALITY CONTROL
Batch B304272 - SW-846 3510C
LCS (B304272-BS1) Prepared: 03/28/22 Analyzed: 03/30/22
g/L 100 40-140Surrogate: o-Terphenyl (OTP)82.682.6
g/L 100 40-140Surrogate: 2-Bromonaphthalene 103103
g/L 100 40-140Surrogate: 2-Fluorobiphenyl 103103
LCS Dup (B304272-BSD1) Prepared: 03/28/22 Analyzed: 03/30/22
C9-C18 Aliphatics g/L100 600 2540-14073.0 0.0456438
C19-C36 Aliphatics g/L100 800 2540-14097.1 0.728776
Unadjusted C11-C22 Aromatics g/L100 1700 2540-14084.2 2.151430
Acenaphthene g/L2.0 100 2540-14079.4 5.5479.4
Acenaphthylene g/L2.0 100 2540-14074.6 5.5974.6
Anthracene g/L2.0 100 2540-14083.4 2.1383.4
Benzo(a)anthracene g/L2.0 100 2540-14087.7 1.2887.7
Benzo(a)pyrene g/L2.0 100 2540-14079.6 1.1979.6
Benzo(b)fluoranthene g/L2.0 100 2540-14081.9 1.1481.9
Benzo(g,h,i)perylene g/L2.0 100 2540-14072.1 1.1472.1
Benzo(k)fluoranthene g/L2.0 100 2540-14073.6 1.0873.6
Chrysene g/L2.0 100 2540-14082.7 1.1382.7
Dibenz(a,h)anthracene g/L2.0 100 2540-14077.6 1.0077.6
Fluoranthene g/L2.0 100 2540-14083.9 1.3983.9
Fluorene g/L2.0 100 2540-14083.4 4.5383.4
Indeno(1,2,3-cd)pyrene g/L2.0 100 2540-14074.9 1.4674.9
2-Methylnaphthalene g/L2.0 100 2540-14071.8 4.5171.8
Naphthalene g/L2.0 100 2540-14064.4 3.3964.4
Phenanthrene g/L2.0 100 2540-14085.1 2.6385.1
Pyrene g/L2.0 100 2540-14084.9 1.4684.9
Naphthalene-aliphatic fraction g/L2.0 100 0-5ND
2-Methylnaphthalene-aliphatic fraction g/L2.0 100 0-5ND
g/L 100 40-140Surrogate: Chlorooctadecane (COD)86.086.0
g/L 100 40-140Surrogate: o-Terphenyl (OTP)84.084.0
g/L 100 40-140Surrogate: 2-Bromonaphthalene 104104
g/L 100 40-140Surrogate: 2-Fluorobiphenyl 104104
Page 8 of 13
Table of Contents
Page 63 of 68
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
FLAG/QUALIFIER SUMMARY
*QC result is outside of established limits.
Wide recovery limits established for difficult compound.
Wide RPD limits established for difficult compound.
#Data exceeded client recommended or regulatory level
Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the
calculation which have not been rounded.
No results have been blank subtracted unless specified in the case narrative section.
RL Reporting Limit is at the level of quantitation (LOQ)
DL Detection Limit is the lower limit of detection determined by the MDL study
MCL Maximum Contaminant Level
ND Not Detected
[TOC_1]Flag/Qualifier Summary[TOC]
Page 9 of 13
Table of Contents
Page 64 of 68
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
MADEP EPH rev 2.1 in Water
CT,NC,ME,NH-PC9-C18 Aliphatics
CT,NC,ME,NH-PC19-C36 Aliphatics
CT,NC,ME,NH-PUnadjusted C11-C22 Aromatics
CT,NC,ME,NH-PC11-C22 Aromatics
[TOC_1]Certifications[TOC]
Con-Test, a Pace Environmental Laboratory, operates under the following certifications and accreditations:
Code Description Number Expires
100033AIHA-LAP, LLC - ISO17025:2017AIHA 03/1/2024
M-MA100Massachusetts DEPMA 06/30/2022
PH-0165Connecticut Department of Publilc HealthCT 12/31/2022
10899 NELAPNew York State Department of HealthNY 04/1/2023
2516 NELAPNew Hampshire Environmental LabNH-S 02/5/2023
LAO00373Rhode Island Department of HealthRI 12/30/2022
652North Carolina Div. of Water QualityNC 12/31/2022
MA007 NELAPNew Jersey DEPNJ 06/30/2022
E871027 NELAPFlorida Department of HealthFL 06/30/2022
LL720741Vermont Department of Health Lead LaboratoryVT 07/30/2022
MA00100State of MaineME 06/9/2023
460217Commonwealth of VirginiaVA 12/14/2022
2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2022
VT-255716Vermont Department of Health Drinking WaterVT-DW 06/12/2022
25703North Carolina Department of HealthNC-DW 07/31/2022
68-05812Commonwealth of Pennsylvania DEPPA 06/30/2022
9100Dept. of Env, Great Lakes, and EnergyMI 09/6/2022
Page 10 of 13
Table of Contents
Page 65 of 68
Page 11 of 13
Table of Contents
Page 66 of 68
Page 12 of 13
Table of Contents
Page 67 of 68
Page 13 of 13
Table of Contents
Page 68 of 68
Limited Site Check Report Murphy Express #8570 800 Retail Way, Louisburg, NC 27549

Appendix B – Soil Boring Logs