AS-4431_41488_CA_RMR_20221118

REMEDIAL ACTION PROGRESS REPORT
GROUNDWATER EXTRACTION AND TREATMENT SYSTEM

July 2022 through September 2022

CROWN FOOD MART
272 RODNEY ORR BYPASS
ROBBINSVILLE, NORTH CAROLINA 28771

NCDEQ INCIDENT NO. 41488
MSGS PROJECT NUMBER: CF20-03

Prepared by:

John F. Kouba, PE
2952 Goldfinch Circle
Marietta, Georgia 30066
[phone]

Martin&Slagle GeoSciences, PA
173 Sloan Road
Franklin, North Carolina 28734
[phone]

November 18, 2022

MARTIN&SLAGLE
GeoSciences, PA
REMEDIAL ACTION PROGRESS REPORT
GROUNDWATER EXTRACTION AND TREATMENT SYSTEM
July through September 2022
CROWN FOOD MART
272 RODNEY ORR BYPASS
ROBBINSVILLE, NORTH CAROLI NA 2877 1
NCDEQ INCIDENT NO. 4I488
MSGS PROJECT NUMBER: CF?O-O?
Prepared by:
John F. Kouba, PE
2952 Goldfinch Circle
Marietta, Georgia 30066
(4L417O4-eO2s
Mnnrr N dSul<=le GeoScr eNces,
173 Sloan Road
Franklin, North Carolina 2glg4
a-a-_3:a-a-,t .s\.' -'s hzL
I hereby certify that this report was
prepared by me or under my direct
supervision and that I am a duly
licensed Professional Engineer
under the laws of the State of North
Carolina.
NC Licensed Ceologist NC-3gl
l, Robert L. Martin, a Licensed
Geologist for Martin & Slagle,
CeoSciences, PA, do certify that the
information contained in this repoft
is correct and accurate to the best of
my knowledge.
11lrll!ft1
H CAfi
,;EdSr'6
SEAL
I2844
I
hn F. Koub). PE
License # P.E.- 12844
Robert L. Martin, LG
11/18/22

i

REMEDIAL ACTION PROGRESS REPORT
GROUNDWATER EXTRACTION AND TREATMENT SYSTEM

CROWN FOOD MART
272 RODNEY ORR BYPASS
ROBBINSVILLE, NORTH CAROLINA 28771

TABLE OF CONTENTS

1.0 INTRODUCTION ................................................................................................................................ 1

2.0 OPERATION AND MAINTENANCE ................................................................................................... 2

3.0 PERFORMANCE ................................................................................................................................ 3

4.0 QUALITY ASSURANCE/QUALITY CONTROL ..................................................................................... 6

FIGURES

Figure 1-Site Location Map
Figure 2-Site Map
Figure 3-Surface Water Sample Location Map

TABLES

Table 1 – Monitoring Well Construction and Water Level Data
Table 2 – Summary of Surface Water Analytical Results
Table 3 - Summary of Wastewater Discharge Analytical Results
Table 4 - Summary of Extraction Well Analytical Results

APPENDIX

Laboratory Reports

REMEDIAL ACTION PROGRESS REPORT
JULY THROUGH SEPTEMBER 2022
GROUNDWATER EXTRACTION AND TREATMENT SYSTEM

Crown Food Mart
272 Rodney Orr Bypass
Robbinsville, NC 28771

1.0 INTRODUCTION
This report documents the operation and effectiveness of the groundwater treatment system installed to
control, capture, and treat impacted groundwater resulting from a release of gasoline in 2016. Soil and
groundwater at the Crown Food Mart and adjacent downgradient properties were impacted by the
release of approximately 8,000 gallons of premium gasoline. The gasoline release was first discovered on
August 16, 2016 when free product was observed discharging from the southwest bank of Tulula Creek
approximately 600 feet northeast of the Crown Food Mart. The release from a gasoline underground
storage tank (UST) was reported to the North Carolina Department of Environmental Quality (NCDEQ)
Asheville Regional Office on this date. Emergency response efforts following the release reduced the
discharge to Tulula Creek from free product to dissolved constituents. Approximately 2,000 gallons of free
product were recovered and disposed of.

Crown Food Mart is located within the town limits of Robbinsville, NC approximately 600 feet southwest
of Tulula Creek at 272 Rodney Orr Bypass (US Highway 129) near its intersection with State Highway 143,
Sweetwater Road (Figure 1). Crown Food Mart was originally built in the 1960s.

The horizontal limits of groundwater contamination are depicted on Figure 2 based on May 17, 2022
groundwater sampling results.

This remedial action progress report (RAPR) was prepared by Martin & Slagle GeoSciences, PA (MSGS) and
John F. Kouba, PE on behalf of Crown Food Mart. The RAPR provides information on operations activities
and monitoring for the pump and treat system during the period of July 2022 through September 2022.

REMEDIAL ACTION PROGRESS REPORT
GROUNDWATER EXTRACTION AND TREATMENT SYSTEM
_____________________________________________________________________________________________

2

2.0 OPERATION AND MAINTENANCE

Operation
The groundwater treatment system includes five (5) groundwater extraction wells, all screened at the
same depth from the ground surface, and one (1) treatment unit inside of a 20-foot-long shipping
container. The treatment unit consists of an oil-water separator (OWS), OWS transfer pump, two bag
filters (50 micron and 5 micron), one shallow tray air stripping tower (AST) with centrifugal blower, and
one AST effluent pump. Treated groundwater is pumped by the AST pump to a nearby city sanitary sewer
manhole. Flow is measured at several points in the treatment system including pumped groundwater
from each extraction well, combined influent to the OWS, OWS transfer to the bag filters and AST, and
treated groundwater to the manhole. Discharge to the manhole is regulated by a sewer discharge permit
issued by the Town of Robbinsville. The treatment system is designed to operate 24 hours per day, seven
days per week and to treat up to a maximum of 38,800 gallons per day (gpd). The system, however, as a
requirement of the Town of Robbinsville sewer discharge permit, is controlled to allow no more than
24,900 gallons per day to be discharged to the Publicly Owned Treatment Works (POTW).

The groundwater treatment system was placed into operation in March 2019. Shortly after start-up there
were issues with the flow sensors being coated, the bag filters clogging every two days, sediment
accumulating in the OWS effluent tank and in the AST wet well and clogging of the AST effluent pump.
This was determined to be caused by precipitation of dissolved iron in groundwater due to introduction
of air during the groundwater pumping and stripping process. One well, EW-01, was taken out of service
at the instruction of NCDEQ in July 2020 due to fouling by iron precipitate coating.

A chemical feed pump was installed after startup to add a sequestrant to the influent to the OWS to
control iron precipitation taking place during treatment operations. Results of a successful pilot test
addressing iron issues at this site conducted from October 2019 through May 2020 are included in Iron
Sequestrant Pilot Study Report submitted to NCDEQ July 23, 2020.
Maintenance
System maintenance includes bag filter replacement, cleaning of flow meter sensors, breakdown of the
system to clean iron solids from the inside of the treatment tanks, valves and pumps, and replenishment
of sequestrant to control iron precipitation.
REMEDIAL ACTION PROGRESS REPORT
GROUNDWATER EXTRACTION AND TREATMENT SYSTEM
_____________________________________________________________________________________________

3

The introduction of the iron sequestrant into the treatment process significantly reduced the frequency
of bag filter replacement and cleaning of equipment downstream of the chemical injection point (just
prior to the OWS). The bag filter change-out occurs weekly. The downstream flow meter sensors and
pump screens still become coated and are cleaned once per week. Cleaning of the deposited material in
the OWS holding tank and AST sump is conducted once per month.

Sampling results indicated that the northwestern lateral limit of the plume has continued to contract
toward EW-02 (Figure 2). As a result, the submersible pump in Well #1 remains out of service. This has
eliminated one source of fouling by iron precipitate and bacteria coating.

A planned temporary shutdown of the system is currently underway to determine if the system can be
shutdown permanently. MSGS prepared a plan and schedule for the shutdown which was approved by
NCDEQ. The Town of Robbinsville and the Graham County Health Department were informed in advance
of the system shutdown. The process of shutting down the system began on October 25, 2022 and will
continue until mid-December 2022. Groundwater and surface water elevations are being monitored
weekly during the shutdown period. Groundwater and surface water are being sampled and analyzed to
monitor for significant increases of petroleum related contaminants that may require the system to be
restarted before the full six-week shutdown period.

Leading up to the shutdown, maintenance continued for weekly bag filter replacement and pump screen
cleaning, and monthly cleaning of the treatment system instrumentation and equipment. Iron sequestrant
chemical usage was approximately 50 gallons per month. This application rate appears to adequately
control TSS generation. Results of effluent (EF-14) sampling for this monitoring period indicated that the
TSS concentration was less than 2.5 mg/l, below the permitted discharge limit of 10 mg/l. The system will
be turned on at the end of the shutdown period and maintenance activities will continue thereafter until
a final disposition of system operation is determined.

REMEDIAL ACTION PROGRESS REPORT
GROUNDWATER EXTRACTION AND TREATMENT SYSTEM
_____________________________________________________________________________________________

4

3.0 PERFORMANCE

Plume Capture
The well array was designed based on the 2018 pump test analysis to capture the contaminant plume as
defined in the Comprehensive Site Assessment (CSA). The five extraction wells (EW-01 through EW-05)
were set on approximately 95-foot spacings with the capture zone extending beyond the lateral limits of
the plume. A groundwater sampling event was conducted May 17-18, 2022 which included all 18
monitoring wells, five extraction wells, and four surface water locations along the south bank of Tulula
Creek. Results of this sampling event were summarized in the Groundwater Monitoring Report submitted
to NCDEQ on July 18, 2022.

Water levels in all monitoring wells were measured during the groundwater monitoring event on May 17-
18, 2022.

Water levels measured over the monitoring period in the monitoring wells adjacent to the extraction wells
indicate that groundwater water elevations remained consistent within the zone of influence surrounding
the extraction wells during system operation. Operation of the pumping system appears to have
depressed the aquifer surface to a steady state condition in the vicinity of the extraction wells. Figure 2
shows the capture zone and plume limits. Groundwater elevation data is summarized in Table 1.

Water quality is monitored in Tulula Creek downgradient of the petroleum hydrocarbon plume (Figure 3).
Surface water samples are collected from four locations along the south bank of Tulula Creek (the side
closest to the contamination plume) and analyzed for volatile organic compounds (VOCs) twice per
month. Surface water sampling has been conducted since August 2016. Sample results over the
monitoring period indicate that the extraction system is beneficially affecting contaminant discharges into
Tulula Creek. Until August 2019 concentrations of ethylbenzene and total xylenes were detected
downgradient of the extraction well array at concentrations up to 1.4 ug/l for ethylbenzene and 6.2 ug/l
for xylenes, well below the 15A NCAC 2B Surface Water Standards. Following February 2020,
concentrations have gradually dropped.

REMEDIAL ACTION PROGRESS REPORT
GROUNDWATER EXTRACTION AND TREATMENT SYSTEM
_____________________________________________________________________________________________

5

During this monitoring period ethylbenzene, naphthalene, toluene, and xylene were not detected above
the method detection limit in samples directly downstream of the treatment system at the end of Patton
Street. N-propyl benzene, 1,2,4-trimethylbenzene and 1,3,5-trimethylbenze were detected at low
concentrations below the 15A NCAC 2B Surface Water Standards. Toluene, the most critical analyte with
respect to surface water due to its low regulatory limit, has a surface water quality limit of 0.36 ug/l for
Trout Waters of the state. Toluene was not detected above the method detection limit of 0.22 ug/l during
the monitoring period. Samples SW-12 and SW-13 collected by NC Division of Water Quality (DWR) on
April 25, 2022 from discrete groundwater seepages along the stream bank directly downgradient of the
treatment system extraction wells EW-02 and EW-03 show elevated levels of several analytes which
exceed NC 2B Surface Water Standards. However, MSGS surface water samples collected at locations up
and downstream of groundwater seeps were consistent with previous sampling results which indicate no
surface water standard exceedances. Table 2 summarizes surface water quality analytical data.

The groundwater monitoring report of the May 17-18, 2022 was submitted to NCDEQ on July 18, 2022.
Concentrations of petroleum-related contaminants in groundwater have declined significantly but still
exceed groundwater remediation goals for several compounds including benzene, n-butylbenzene,
ethylbenzene, and toluene.

A comprehensive sampling event will be conducted following a trial treatment system shutdown in
November through December 2022. All monitoring wells, extraction wells, and surface waters will be
sampled during this event. The system will be shut down for six weeks with samples collected from select
wells and surface water locations during and after the shutdown to assess the potential for rebound of
contaminant concentrations and determination if the system should be shut down permanently.

Groundwater Treatment and Discharge
Influent (untreated) and effluent (treated) groundwater samples as well as samples from extraction wells
EW-2, EW-3, EW-4, and EW-5 were collected October 12, 2022 to monitor the system treatment
effectiveness removing regulated petroleum hydrocarbons from site groundwater. The treatment system
successfully removed VOCs and TSS to below the limits established in the Town of Robbinsville POTW
Discharge Permit. The effluent pH was measured at 7.4, within the permitted discharge range. Table 3
summarizes the analytical results for the treatment system discharge. Table 4 summarizes analytical
REMEDIAL ACTION PROGRESS REPORT
GROUNDWATER EXTRACTION AND TREATMENT SYSTEM
_____________________________________________________________________________________________

6

results for operating extraction wells for the monitoring period. The laboratory reports are included in the
Appendix.

The Discharge Permit limits the Daily Maximum Flow to 24,900 gallons per day (gpd). The treated
groundwater is metered prior to discharge to the permitted sewer manhole. Flow is monitored and data
is tabulated by the treatment system’s programable logic controller which shuts the system down if the
daily flow reaches the daily discharge limit. Over the monitoring period a maximum daily discharge of
18,429 gallons was recorded on August 10, 2022. A total of 838,429 gallons of treated groundwater was
discharged over the monitoring period.

4.0 QUALITY ASSURANCE / QUALITY CONTROL

During the reporting period, samples of influent groundwater and treated effluent were collected and
submitted to Pace Analytical Laboratories, LLC (Pace) in Asheville, NC for analysis of VOCs, TSS and total
iron. Blind duplicate quality control samples were collected to evaluate laboratory performance. Samples
were transported to the laboratory under proper chain-of-custody procedures. No deviations from QA/QC
protocols established for the USEPA standard methods were noted in the laboratory reports. Pace is a
North Carolina certified laboratory.

Samples were collected in laboratory-supplied containers which were placed on ice following sample
collection. Sample cooler temperatures reported by the laboratory were compliant with USEPA method
preservation requirements.

PREPARED FOR: Crown Food Mart
DATE: 8/20/20
DR: RLM
CHK:CES
SITE LOCATION MAP
Crown Food Mart
272 Rodney Orr Bypass
Robbinsville, NC
MARTIN&SLAGLE
GeoSciences, PA
PO Box 1023
Black Mountain, NC 28711828.669.3929 828.669.5289
Source Location
Approx. Scale: As Shown FIGURE 1
Santeetlah Lake
Water Treatment Plant Intake
GW Treatment System
G ARLA ND/BACO NDB. 283PD. 1291990
1989
198 5
1
9
8
3 19821981
1981
1
9
8
319851990
1995199519901985851
9
84
1985198319821981 1983
1984
1
9
8
0
198219
9
01985199119911990198619871 986
1987
19811 9 8 1
1984
19
7
6
1981
1
9
8
2
198919901985
1984
1
9
8
5
1
9
80
1
97
5
19 8 3198819801983
1984
1984
19891991
GA
S PUMP AWNI
NGFFFF
F
F
F
FFF
2" PVC
2" PVC2" PVCGA
GA
Z:1980.95
Z:1980.46
Z:1984.55
Z:1984.12
Z:1983.46
Z:1985.42
Z:1982.38
12" D.I. F
1
2" D.I. FORCE MAIN
2 " P V C
MW-1
MW-17A
MW-12
MW-2
MW-3
MW-4
MW-5
MW-7
MW-16
MW-10
MW-18
36" MAPLE
WL:1970.25
WL:1971.69
WL:1972.26
WL:1972.61
WL:1972.74
WL:1972.92
WL:1973.0
CODY/ADAMS
DB. 345, PG. 370PID #566008030023(CROWN FOOD MART)HOLDERDB. 303, PG. 142PID #566008030031GARLAN DDB. 187, PG. 91PID # 566008030007AMEND EZDB. 306, PG . 473PID # 566008030029PERKINSDB. 316, PG . 226PID # 566008030028W ALDR OU PD B. 150, PG. 363PID # 566008030020SH ULERDB. 275, PG. 194McDONALDS USA LLCDB. 253, PG. 828PID # 566008030020A
PHILLIPS REAL ESTATE LLCDB. 215, PG. 734
PID # 566008030011A
DB. 76, PG. 496PID # 566008030027JOR DAN
PID # 566008030024A 4 HOM E CENTERDB. 97, PG. 689PID # 566008030002GRINDSTAFFDB. 349, PG. 233PID # 566008030026MW-8
MW-13
MW-14
MW-15
MW-11
EW-03
EW-02
EW-01
MW-9
MW-6
87
86
88
85
84
83
LEGEND
EW-01
MW-11
POTENTIOMETRIC LINE
MONITORING WELL
EXTRACTION WELL
87.47
88.96
87.89
88.26
87.18
86.91
84.99
83.71
86.05
82.79
82.34
82.14
82.52
82.69
81.72
88.72
83.60
N
84.46
80.35
EW-04
EW-05
71.67
76.59
73.21
PLUME EXTENT
SOURCE AREA
SLAGLEGeoSciences, PA
Franklin, NC 28734
828.634.7741
MARTIN&
173 Sloan Road
POTENTIOMETRIC MAP5/17/22
CROWN FOOD MART272 RODNEY ORR BLVDROBBINSVILLE, NC 28771
REV: 1
SCALE: 1": 100'
DR: JB
CHK: RM
DATE: 10/25/224
3
2
1 2
FIGURE
PREPARED FOR: Crown Food Mart
DATE: 8-25-16
DR: RLM
CHK:CES
SURFACE WATER
SAMPLE LOCATION MAP
Crown Food Mart
272 Rodney Orr Bypass
Robbinsville, NC
MARTIN&SLAGLE
GeoSciences, PA
PO Box 1023
Black Mountain, NC 28711
828.669.3929 828.669.5289
Sample Location 2
Sample Location 1
Approx. Scale: As Shown”FIGURE 3
Sample Location 3
Sample Location 4
Santeetlah Lake
Source Location
TABLE 1
Monitoring Well Construction and Water Level Data
CROWN FOOD MART
ROBBINSVILLE, NC
2016-2022
Well
Number
Date of
Installation
Well
Diameter
Top Casing
Elevation Top Screen Well Depth
Depth to Free
Product
12/01/16
Depth to Water
12/01/16
Water Surface
Elevation
12/01/16
Depth to
Free
Product
12/19/16
Depth to
Water
12/19/16
Water Surface
Elevation
12/19/16
Depth to
Water
3/14/17
Water Surface
Elevation
3/14/17
MW-1 11/14/16 2"98.86 91.86 17.00 NFP 11.24 87.62 NFP 9.58 89.28 9.54 89.32
MW-2 11/16/16 2"98.52 89.52 19.00 NFP 11.60 86.92 NFP 9.94 88.58 10.02 88.50
MW-3 11/15/16 2"98.55 59.55 49.00 NFP 11.50 87.05 NFP 10.34 88.21 9.95 88.60
MW-4 11/14/16 2"96.65 87.05 19.60 NFP 10.33 86.32 NFP 8.39 88.26 8.56 88.09
MW-5 11/14/16 2"96.49 89.49 17.00 NFP 10.27 86.22 NFP 8.71 87.78 8.82 87.67
MW-6 11/15/16 2"89.22 82.63 16.59 -4.53 84.69 Trace 4.04 85.18 3.54 85.68MW-7 11/15/16 2"91.05 84.05 17.00 NFP 5.04 86.01 NFP 4.00 87.05 3.60 87.45
MW-8 11/15/16 2"88.10 81.10 17.00 NFP 4.35 83.75 NFP 4.12 83.98 3.49 84.61
MW-9 11/15/16 2"91.87 84.89 16.98 NFP 9.43 82.44 NFP 8.26 83.61 8.32 83.55
MW-10 11/16/16 2"89.96 83.96 16.00 NFP 5.00 84.96 NFP NL NL 3.75 86.21
MW-11 11/16/16 2"90.88 83.88 17.00 NFP 7.52 83.36 NFP 6.61 84.27 6.80 84.08
MW-12 2/20/17 2"99.37 94.87 19.50 ------9.58 89.79
MW-13 2/20/17 2"88.77 85.47 13.30 ------4.79 83.98
MW-14 2/21/17 2"90.57 87.07 13.50 ------6.97 83.60
MW-15 2/21/17 2"91.47 87.14 14.33 ------7.98 83.49
MW-16 2/21/17 2"89.46 85.13 14.33 ------5.05 84.41
MW-17A 4/28/17 2"97.55 90.55 17.00 --------
MW-18 4/28/17 2"90.20 83.20 17.00 --------
Transducer
Elevation
EW-1 11/8/18 4"------
EW-2 11/8/18 4"91.45 70.45 ------
EW-3 11/9/18 4"89.17 68.17 ------
EW-41 2/20/18 4"89.09 73.09 25.00 ------
EW-5 11/10/18 4"89.81 68.81 ------
Note: EW-4 was installed as RW-01 and used for pump testing. It was renamed EW-4 to be consistent with the extraction well nomenclature.
NL - No water level data collected
NA - Not applicable
NFP - No Free Product
TABLE 1
Monitoring Well Construction and Water Level Data
CROWN FOOD MART
ROBBINSVILLE, NC
2016-2022
Well
Number
MW-1
MW-2
MW-3
MW-4
MW-5
MW-6
MW-7
MW-8
MW-9
MW-10
MW-11
MW-12
MW-13
MW-14
MW-15
MW-16
MW-17A
MW-18
EW-1
EW-2
EW-3
EW-41
EW-5
Depth to
Water
2/18/19
Water Surface
Elevation
2/18/19
Depth to
Water
6/25/19
Water
Surface
Elevation
6/25/19
Depth to
Water
5/21/20
Water
Surface
Elevation
5/21/20
Water Surface
Elevation
6/16/20
Depth to
Water
7/29/20
Water Surface
Elevation
7/29/20
Depth to
Water
9/10/20
Water Surface
Elevation
9/10/20
Depth to
Water
9/24/20
Water Surface
Elevation
9/24/20
7.04 91.82 ----------
8.55 89.97 ----------
8.68 89.87 ----------
6.84 89.81 ----------
7.21 89.28 ----------
0.89 88.33 4.00 85.22 --------1.75 89.30 ---------
1.09 87.01 3.90 84.20 4.27 83.83 83.45 4.85 83.25 4.71 83.39 4.66 83.44
6.39 85.48 8.61 83.26 8.93 82.94 82.72 9.17 82.70 8.93 82.94 9.01 82.86
2.10 87.86 -4.26 85.70 85.28 4.79 85.17 4.56 85.40 4.57 85.39
4.90 85.98 ----------
7.29 92.08 ----------
2.21 86.56 ----------
4.31 86.26 7.22 83.35 7.49 83.08 82.74 7.93 82.64 7.74 82.83 7.82 82.75
6.42 85.05 8.26 83.21 -
3.02 86.44 5.05 84.41 3.02 86.44 83.85 5.76 83.70 5.52 83.94 5.66 83.80
7.61 89.94 -----------
6.39 83.81 -------
--------
-----9.35 79.80 9.20 79.65 9.30 79.75
-----8.92 77.09 19.50 87.67 17.10 85.27
-----14.14 87.23 13.80 86.89 13.40 86.49
-----15.55 84.36 15.22 84.03 16.50 85.31
Note: EW-4 was installed as RW-01 and used for pump testing. It was renamed EW-4 to be consistent with the extraction well nomenclature.
NL - No water level data collected
NA - Not applicable
NFP - No Free Product
TABLE 1
Monitoring Well Construction and Water Level Data
CROWN FOOD MART
ROBBINSVILLE, NC
2016-2022
Well
Number
MW-1
MW-2
MW-3
MW-4
MW-5
MW-6
MW-7
MW-8
MW-9
MW-10
MW-11
MW-12
MW-13
MW-14
MW-15
MW-16
MW-17A
MW-18
EW-1
EW-2
EW-3
EW-41
EW-5
Depth to
Water
10/8/20
Water Surface
Elevation
10/8/20
Depth to
Water
10/22/20
Water Surface
Elevation
10/22/20
Depth to
Water
11/5/20
Water Surface
Elevation
11/5/20
Depth to
Water
11/19/20
Water Surface
Elevation
11/19/20
Depth to
Water
12/3/20
Water Surface
Elevation
12/3/20
Depth to
Water
12/17/20
Water Surface
Elevation
12/17/20
------------
------------
------------
------------
------------
------------------------
4.53 83.57 4.61 83.49 4.16 83.94 4.76 83.34 4.76 83.34 3.62 84.48
8.81 83.06 8.80 83.07 8.53 83.34 9.02 82.85 9.03 82.84 8.11 83.76
4.40 85.56 4.54 85.42 4.19 85.77 4.70 85.26 4.68 85.28 3.74 86.22
------------
------------
------------
7.62 82.95 7.68 82.89 7.56 83.01 7.85 82.72 7.86 82.71 6.76 83.81
-
5.44 84.02 5.51 83.95 5.25 84.21 5.62 83.84 5.62 83.84 4.89 84.57
------------
-----------
-----------
11.90 82.35 12.10 82.55 12.22 82.67 11.90 82.35 11.60 82.05 12.60 83.05
5.60 73.77 12.40 80.57 4.30 72.47 5.00 73.17 5.40 73.57 2.60 70.77
6.90 79.99 15.20 88.29 7.30 80.39 6.60 79.69 6.10 79.19 7.00 80.09
3.50 72.31 12.80 81.61 4.90 73.71 2.70 71.51 3.30 72.11 4.30 73.11
Note: EW-4 was installed as RW-01 and used for pump testing. It was renamed EW-4 to be consistent with the extraction well nomenclature.
NL - No water level data collected
NA - Not applicable
NFP - No Free Product
TABLE 1
Monitoring Well Construction and Water Level Data
CROWN FOOD MART
ROBBINSVILLE, NC
2016-2022
Well
Number
MW-1
MW-2
MW-3
MW-4
MW-5
MW-6
MW-7
MW-8
MW-9
MW-10
MW-11
MW-12
MW-13
MW-14
MW-15
MW-16
MW-17A
MW-18
EW-1
EW-2
EW-3
EW-41
EW-5
Depth to
Water
1/12/21
Water Surface
Elevation
1/12/21
Depth to
Water
1/28/21
Water Surface
Elevation
1/28/21
Depth to
Water
2/24/21
Water Surface
Elevation
2/24/21
Depth to
Water
3/24/21
Water Surface
Elevation
3/24/21
Depth to
Water
4/21/21
Water Surface
Elevation
4/21/21
Depth to
Water
5/19/21
Water Surface
Elevation
5/19/21
9.20 89.66 ----------
10.19 88.33 ----------
9.86 88.69 ----------
8.82 87.83 ----------
9.17 87.32 ----------
------------------------
3.98 84.12 4.03 84.07 3.51 84.59 3.72 84.38 3.80 84.30 4.40 83.70
8.61 83.26 8.65 83.22 8.10 83.77 8.27 83.60 8.33 83.54 8.75 83.12
4.20 85.76 4.14 85.82 3.59 86.37 3.90 86.06 3.92 86.04 4.44 85.52
6.55 84.33 ----------
9.46 89.91 ----------
5.13 83.64 ----------
7.25 83.32 7.25 83.32 6.68 83.89 6.87 83.70 6.92 83.65 7.49 83.08
8.26 83.21 ----------
5.28 84.18 5.31 84.15 4.75 84.71 4.94 84.52 4.92 84.54 5.42 84.04
9.42 88.13 ----------
7.99 82.21 ----------
------------
12.60 83.05 11.70 82.15 12.30 82.75 12.10 82.55 11.40 81.85 11.70 82.15
2.60 70.77 3.50 71.67 5.30 73.47 4.30 72.47 2.90 71.07 3.60 71.77
7.00 80.09 5.60 78.69 5.70 78.79 5.70 78.79 5.60 78.69 5.70 78.79
4.30 73.11 2.70 71.51 6.50 75.31 4.60 73.41 5.70 74.51 6.90 75.71
Note: EW-4 was installed as RW-01 and used for pump testing. It was renamed EW-4 to be consistent with the extraction well nomenclature.
NL - No water level data collected
NA - Not applicable
NFP - No Free Product
TABLE 1
Monitoring Well Construction and Water Level Data
CROWN FOOD MART
ROBBINSVILLE, NC
2016-2022
Well
Number
MW-1
MW-2
MW-3
MW-4
MW-5
MW-6
MW-7
MW-8
MW-9
MW-10
MW-11
MW-12
MW-13
MW-14
MW-15
MW-16
MW-17A
MW-18
EW-1
EW-2
EW-3
EW-41
EW-5
Depth to
Water
6/17/21
Water Surface
Elevation
6/17/21
Depth to
Water
7/14/21
Water Surface
Elevation
7/14/21
Depth to
Water
8/9/21
Water Surface
Elevation
8/9/21
Depth to
Water
9/16/21
Water Surface
Elevation
9/16/21
Depth to
Water
10/13/21
Water Surface
Elevation
10/13/21
Depth to
Water
11/11/21
Water Surface
Elevation
11/11/21
------------
------------
------------
------------
------------
------------------------
4.95 83.15 4.00 84.10 4.55 83.55 4.95 83.15 4.95 83.15 5.12 82.98
9.20 82.67 8.79 83.08 9.00 82.87 9.2 82.67 9.2 82.67 9.36 82.51
4.50 85.46 4.50 85.46 4.80 85.16 4.5 85.46 4.5 85.46 5.18 84.78
----------
----------
----------
8.02 82.55 7.36 83.21 7.30 83.27 8.02 82.55 8.02 82.55 8.23 82.34
-----
5.82 83.64 5.49 83.97 5.56 83.90 5.82 83.64 5.82 83.64 6.1 83.36
----------
----------
-----------
10.70 81.15 12.20 82.65 11.60 82.05 12 82.45 12.3 82.75 11.5 81.95
2.40 70.57 1.10 69.27 4.40 72.57 4.2 72.37 4 72.17 2.3 70.47
6.00 79.09 13.00 86.09 15.40 88.49 15.3 88.39 15.9 88.99 14.8 87.89
2.10 70.91 6.20 75.01 2.10 70.91 4.5 73.31 3.8 72.61 5.4 74.21
Note: EW-4 was installed as RW-01 and used for pump testing. It was renamed EW-4 to be consistent with the extraction well nomenclature.
NL - No water level data collected
NA - Not applicable
NFP - No Free Product
TABLE 1
Monitoring Well Construction and Water Level Data
CROWN FOOD MART
ROBBINSVILLE, NC
2016-2022
Well
Number
MW-1
MW-2
MW-3
MW-4
MW-5
MW-6
MW-7
MW-8
MW-9
MW-10
MW-11
MW-12
MW-13
MW-14
MW-15
MW-16
MW-17A
MW-18
EW-1
EW-2
EW-3
EW-41
EW-5
Depth to
Water
12/21/21
Water Surface
Elevation
12/21/21
Depth to
Water
1/19/22
Water Surface
Elevation
1/19/22
Depth to
Water
2/16/22
Water Surface
Elevation
2/16/22
Depth to
Water
3/15/22
Water Surface
Elevation
3/15/22
Depth to
Water
4/12/22
Water Surface
Elevation
4/12/22
Depth to
Water
5/17/22
Water Surface
Elevation
5/17/22
--------10.14 88.72
--------10.63 87.89
--------10.29 88.26
--------9.47 87.18
--------9.58 86.91
--------4.76 84.46--------5.00 86.05
3.85 84.25 3.59 84.51 4.01 84.09 88.10 4.08 84.02 5.96 82.14
8.57 83.3 8.23 83.64 8.6 83.27 91.87 8.6 83.27 9.35 82.52
4.19 85.77 3.82 86.14 4.23 85.73 89.96 4.97 84.99
7.17 83.71
10.41 88.96
5.98 82.79
7.15 83.42 6.88 83.69 7.25 83.32 90.57 7.26 83.31 8.23 82.34
8.78 82.69
5.19 84.27 4.61 84.85 5.29 84.17 89.46 5.36 84.10 5.86 83.60
97.55 10.08 87.47
90.2 90.2 8.48 81.72
-----
12.3 82.75 12.9 83.35 10.30 80.75
5.9 74.07 4.5 72.67 4.40 72.57
16 89.09 16.2 89.29 6.65 79.74
15.1 83.91 16 84.81 4.40 73.21
Note: EW-4 was installed as RW-01 and used for pump testing. It was renamed EW-4 to be consistent with the extraction well nomenclature.
NL - No water level data collected
NA - Not applicable
NFP - No Free Product
TABLE 1
Monitoring Well Construction and Water Level Data
CROWN FOOD MART
ROBBINSVILLE, NC
2016-2022
Well
Number
MW-1
MW-2
MW-3
MW-4
MW-5
MW-6
MW-7
MW-8
MW-9
MW-10
MW-11
MW-12
MW-13
MW-14
MW-15
MW-16
MW-17A
MW-18
EW-1
EW-2
EW-3
EW-41
EW-5
Depth to
Water
8/18/22
Water Surface
Elevation
8/18/22
Depth to
Water
9/1/22
Water Surface
Elevation
9/1/22
Depth to
Water
9/15/22
Water Surface
Elevation
9/15/22
Depth to
Water
9/29/22
Water Surface
Elevation
9/29/22
--------
--------
--------
--------
--------
----------------
4.68 83.42 5.21 82.89 5.06 83.04 6.21 81.89
9.00 82.87 9.46 82.41 9.32 82.55 9.75 82.12
4.49 85.47 5.00 84.96 4.89 85.07 5.45 84.51
--------
--------
5.67 83.10 6.20 82.57 6.02 82.75 6.64 82.13
7.89 82.68 8.39 82.18 8.23 82.34 8.82 81.75
--------
5.57 83.89 6.10 83.36 5.86 83.6 6.43 83.03
--------
--------
----
10.71 81.16 10.3 80.75 9.9 80.35 -
6.25 74.42 3.5 71.67 3.5 71.67 -
5.6 78.69 6.65 79.74 3.5 76.59 -
2.15 70.96 4.4 73.21 4.4 73.21 -
Note: EW-4 was installed as RW-01 and used for pump testing. It was renamed EW-4 to be consistent with the extraction well nomenclature.
NL - No water level data collected
NA - Not applicable
NFP - No Free Product
TABLE 2
SUMMARY OF SURFACE WATER ANALYTICAL RESULTS
CROWN FOOD MARTROBBINSVILLE, NC
JUNE 2019- SEPTEMBER 2022
Constituent 15A NCAC 02B Stds1 Units SW-01-119 SW-01-120 SW-01 179 SW-02-100 SW-02-103 SW-02-105 SW-02-108 SW-02-109 SW-02-110 SW-02-111 SW-02-112 SW-02-113 SW-02-115 SW-02-117 SW-02-118
03/26/19 04/08/19 08/04/22 08/15/19 08/06/19 09/12/19 10/23/19 11/07/19 11/21/19 12/05/19 12/19/19 01/02/20 01/30/20 02/26/20 03/12/20
Ethylbenzene 97 (Aquatic Life and Secondary Recreation)µg/L BDL BDL 0.25 BDL 1.4 1.3 1.6 1.0 1.4 BDL BDL 1.1 0.68 J 0.62 J 0.38 J
Naphthalene
12 (Aquatic Life and
Secondary Recreation)µg/L 0.36 J 0.96 J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL
n-Propyl Benzene
12 (Aquatic Life and Secondary Recreation)µg/L 0.21
Toluene 0.36 (Trout Waters)µg/L BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL
1,2,4-Trimethylbenzene
390 (Aquatic Life and Secondary Recreation)µg/L 1.2
1,3,5-Trimethylbenzene 130 (Water Supply)µg/L BDL BDL 0.30 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL
Total Xylenes
130 (Aquatic Life and
Secondary Recreation)µg/L BDL BDL 0.25 2.6 6.2 BDL 4.8 BDL 5.7 3.3 2 3.3 BDL 1.72J 0.97 J
BDL- Below detection limitug/l- Micrograms per literConcentrations in Bold exceed permit limits 1- North Carolina Surface Water Standards
Gaps in the sample number sequences indicates BDL for all petroleum related analytes.
ND-Not Detected
TABLE 2
SUMMARY OF SURFACE WATER ANALYTICAL RESULTS
CROWN FOOD MARTROBBINSVILLE, NC
JUNE 2019- SEPTEMBER 2022
Constituent 15A NCAC 02B Stds1 Units
Ethylbenzene 97 (Aquatic Life and Secondary Recreation)µg/L
Naphthalene
12 (Aquatic Life and
Secondary Recreation)µg/L
n-Propyl Benzene
12 (Aquatic Life and Secondary Recreation)µg/L
Toluene 0.36 (Trout Waters)µg/L
1,2,4-Trimethylbenzene
390 (Aquatic Life and Secondary Recreation)µg/L
1,3,5-Trimethylbenzene 130 (Water Supply)µg/L
Total Xylenes
130 (Aquatic Life and
Secondary Recreation)µg/L
BDL- Below detection limitug/l- Micrograms per literConcentrations in Bold exceed permit limits 1- North Carolina Surface Water Standards
Gaps in the sample number sequences indicates BDL for all petroleum rel
ND-Not Detected
SW-02-119 SW-02-120 SW-02-121 SW-02-122 SW-02-123 SW-02-124 SW-02-125 SW-02-126 SW-02-127 SW-02-129 SW-02-130 SW-02-131 SW-02-132 SW-02-134 SW-02-135
03/26/20 04/08/20 04/28/20 05/07/20 05/20/20 06/04/20 06/17/20 07/01/20 07/16/20 08/13/20 08/26/20 09/10/20 09/24/20 10/23/20 11/06/20
0.39 J BDL 0.46 J 0.48 J BDL 0.69 J 0.73 J 0.46 J 0.48 J 0.47J 0.44J 0.34J 0.61J 0.67J 0.61J
BDL 0.36 J BDL BDL BDL BDL BDL BDL BDL BDL 0.43J BDL BDL BDL BDL
0.29 J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL
BDL BDL BDL BDL 0.36 J BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL
1.21 J BDL 1.24 J 1.0 J BDL 1.9 J 2.2 1.1 J 1.5 J BDL 1.2J BDL 0.77J 1.4J 1.6J
TABLE 2
SUMMARY OF SURFACE WATER ANALYTICAL RESULTS
CROWN FOOD MARTROBBINSVILLE, NC
JUNE 2019- SEPTEMBER 2022
Constituent 15A NCAC 02B Stds1 Units
Ethylbenzene 97 (Aquatic Life and Secondary Recreation)µg/L
Naphthalene
12 (Aquatic Life and
Secondary Recreation)µg/L
n-Propyl Benzene
12 (Aquatic Life and Secondary Recreation)µg/L
Toluene 0.36 (Trout Waters)µg/L
1,2,4-Trimethylbenzene
390 (Aquatic Life and Secondary Recreation)µg/L
1,3,5-Trimethylbenzene 130 (Water Supply)µg/L
Total Xylenes
130 (Aquatic Life and
Secondary Recreation)µg/L
BDL- Below detection limitug/l- Micrograms per literConcentrations in Bold exceed permit limits 1- North Carolina Surface Water Standards
Gaps in the sample number sequences indicates BDL for all petroleum rel
ND-Not Detected
SW-02-136 SW-02-137 SW-02-138 SW-02-139 SW-02-140 SW-02-141 SW-02-142 SW-02-144 SW-02-145 SW-02-146 SW-02-147 SW-02-149 SW-02-152 SW-02-153 SW-02-154
11/06/20 12/03/20 12/17/20 12/30/20 01/12/21 01/28/21 02/11/21 03/11/21 03/24/21 04/06/21 04/21/21 05/19/21 07/06/21 07/14/21 07/29/21
0.43J 0.38J 0.50J 0.46J 0.52J BDL 0.37J 0.31J 0.34J 0.31J 0.31J 0.34J 0.38J BDL 0.31J
BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL
BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL
BDL BDL BDL
BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.91 BDL
0.73J 0.97J 1.1J 0.93J 1.3J 1.7 2 1.3J 1.3J 1.3J 1.3J 1.3J BDL BDL 1.44
TABLE 2
SUMMARY OF SURFACE WATER ANALYTICAL RESULTS
CROWN FOOD MARTROBBINSVILLE, NC
JUNE 2019- SEPTEMBER 2022
Constituent 15A NCAC 02B Stds1 Units
Ethylbenzene 97 (Aquatic Life and Secondary Recreation)µg/L
Naphthalene
12 (Aquatic Life and
Secondary Recreation)µg/L
n-Propyl Benzene
12 (Aquatic Life and Secondary Recreation)µg/L
Toluene 0.36 (Trout Waters)µg/L
1,2,4-Trimethylbenzene
390 (Aquatic Life and Secondary Recreation)µg/L
1,3,5-Trimethylbenzene 130 (Water Supply)µg/L
Total Xylenes
130 (Aquatic Life and
Secondary Recreation)µg/L
BDL- Below detection limitug/l- Micrograms per literConcentrations in Bold exceed permit limits 1- North Carolina Surface Water Standards
Gaps in the sample number sequences indicates BDL for all petroleum rel
ND-Not Detected
SW-02-155 SW-02-156 SW-02-157 SW-02-159 SW-02-160 SW-02-165 SW-02-166 SW-02-167 SW-02-168 SW-02-169 SW-02-170 SW-02-171 SW-02-172 SW-02-173 SW-02-174 SW-02-175
08/08/21 08/30/21 09/16/21 10/13/21 10/27/21 01/06/22 01/19/22 02/02/22 02/16/22 03/01/22 03/15/22 03/29/22 04/12/22 04/28/22 05/17/22 06/09/22
0.39J 0.37
Arrived late at
Lab. Exceeded Temp.0.33J 0.32J 0.2J 0.27J 0.24J 0.24J ND ND ND ND ND ND ND
BDL BDL BDL BDL ND ND ND ND ND ND ND ND ND ND ND
0.15J 0.2 0.18J 0.19J 0.14J 0.18J 0.17J 0.15J 0.14J ND 0.13J
BDL BDL BDL BDL ND ND ND ND ND ND ND ND ND ND ND
BDL BDL BDL 1.4 1 1.3 1.2 1.3 0.79J 1.1J 1.0J 0.97J 0.83J 0.62J 0.75J
BDL BDL BDL 0.43J 0.25J 0.34J 0.34J 0.32J 0.21J 0.26J 0.29J 0.28J 0.24J 0.20J 0.19J
1.78 1.58 BDL 0.72J 0.33J 0.49J 0.51J ND ND ND ND ND ND ND ND
TABLE 2
SUMMARY OF SURFACE WATER ANALYTICAL RESULTS
CROWN FOOD MARTROBBINSVILLE, NC
JUNE 2019- SEPTEMBER 2022
Constituent 15A NCAC 02B Stds1 Units
Ethylbenzene 97 (Aquatic Life and Secondary Recreation)µg/L
Naphthalene
12 (Aquatic Life and
Secondary Recreation)µg/L
n-Propyl Benzene
12 (Aquatic Life and Secondary Recreation)µg/L
Toluene 0.36 (Trout Waters)µg/L
1,2,4-Trimethylbenzene
390 (Aquatic Life and Secondary Recreation)µg/L
1,3,5-Trimethylbenzene 130 (Water Supply)µg/L
Total Xylenes
130 (Aquatic Life and
Secondary Recreation)µg/L
BDL- Below detection limitug/l- Micrograms per literConcentrations in Bold exceed permit limits 1- North Carolina Surface Water Standards
Gaps in the sample number sequences indicates BDL for all petroleum rel
ND-Not Detected
SW-02-176 SW-02-177 SW-02-178 SW-02-180 SW-02-181 SW-02-182 SW-02-183 SW-03-124 SW-03-160 SW-03-165 SW-03-166 SW-03-167 SW-03-168 SW-03-169 SW-03-170
06/23/22 07/07/22 07/21/22 08/18/22 09/01/22 09/15/22 09/29/22 06/04/20 10/27/21 01/06/22 01/24/22 02/02/22 12/16/22 03/01/22 03/15/22
ND ND ND ND ND ND ND 0.68J ND ND 0.10J ND ND ND ND
ND ND ND ND ND ND ND BDL ND ND ND ND ND ND ND
0.14J 0.15 ND 0.16 0.12 0.13 ND BDL ND ND ND ND ND ND ND
ND ND ND ND <0.22 <0.22 ND BDL ND ND ND ND ND ND ND
0.84J 1 0.47 0.99 0.79 0.83 0.57 BDL 0.63J 0.38J 0.50J 0.5J 0.46J 0.31J 0.37J
0.25J 0.29 0.12 ND 0.2 0.24 0.16 BDL ND ND 0.13J 0.12J 0.12J ND ND
ND ND ND ND ND ND ND BDL ND ND 0.19J ND ND ND ND
TABLE 2
SUMMARY OF SURFACE WATER ANALYTICAL RESULTS
CROWN FOOD MARTROBBINSVILLE, NC
JUNE 2019- SEPTEMBER 2022
Constituent 15A NCAC 02B Stds1 Units
Ethylbenzene 97 (Aquatic Life and Secondary Recreation)µg/L
Naphthalene
12 (Aquatic Life and
Secondary Recreation)µg/L
n-Propyl Benzene
12 (Aquatic Life and Secondary Recreation)µg/L
Toluene 0.36 (Trout Waters)µg/L
1,2,4-Trimethylbenzene
390 (Aquatic Life and Secondary Recreation)µg/L
1,3,5-Trimethylbenzene 130 (Water Supply)µg/L
Total Xylenes
130 (Aquatic Life and
Secondary Recreation)µg/L
BDL- Below detection limitug/l- Micrograms per literConcentrations in Bold exceed permit limits 1- North Carolina Surface Water Standards
Gaps in the sample number sequences indicates BDL for all petroleum rel
ND-Not Detected
SW-03-171 SW-03-172 SW-03-173 SW-03-175 SW-03-176 SW-03-177 SW-03-178 SW-03-179 SW-03-180 SW-03-181 SW-03-182 SW-03-183 SW-04-165 SW-04-166 SW-04-174
03/29/22 04/12/22 04/28/22 06/09/22 06/23/22 07/07/22 07/21/22 08/04/22 08/18/22 09/01/22 09/15/22 92/29/22 01/06/22 01/24/22 05/17/22
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
0.24J 0.39J 0.32J 0.29J 0.34J 0.36 0.22 0.42 0.34 0.32 0.31 0.23 0.12J 0.16J 0.26J
ND ND ND ND ND ND ND 0.12 ND ND ND ND ND ND ND
ND ND ND ND ND ND ND 0.46 ND ND ND ND ND ND ND
Table 3Summary of Wastewater Discharge Analytical Results
Crown Food Mart
Robbinsville, NC
Constituent Discharge Limit Units EF-01 EF-02 EF-06 EF-07 EF-07 R EF-08 EF-09 EF-10 EF-11 EF-11R EF-12 EF-13 EF-14 Duplicate
Jun-19 Aug-19 Jun-20 Sep-20 Nov-20 Jan-21 Apr-21 Jul-21 Nov-21 Dec-21 Mar-22 Jun-22 Oct-22 Oct-22
Benzene 51 µg/L 2.6 NA 2.0 2.1 NA 4.7 2.0 0.68 <0.34 NA <0.34 1.5 1.3 0.86
Ethylbenzene 97 µg/L 7.3 NA 9.3 4.1 NA 8.6 5.0 0.32J <0.30 NA <0.30 6.8 3.4 2.7
Toluene 610 µg/L 7.8 NA 2.9 1.7 NA 2.3 0.89 <0.48 <0.48 NA <0.48 <0.48 0.44J 0.28J
Total Xylenes 488 µg/L 64.9 NA 49.9 48.4 NA 26.8 38.5 12.4 <0.34 NA 1.87 17.2 11.1 8.6
Methyl Tert-Butyl Ether (MTBE)1500 µg/L 0.65 NA <0.5 0.74 NA 1.8 0.79 0.43J <0.42 NA <0.42 <0.42 0.43J <0.42
Total Lead Monitor Only µg/L <5.0 NA <5.0 NA NA NA NA NA NA NA NA NA NA NA
1,2-Dichloroethane (1,2-DCA)37 µg/L <0.50 NA <0.5 <0.5 NA <0.50 <0.50 <0.32 <0.32 NA <0.32 <0.32 <0.32 <0.32
TSS (mg/L)10 mg/l 28.6 21.5 <2.7 24.1 <3.2 <2.5 3.1 <2.7 22.5 <12.5 7.6 <2.5 <2.5 NA
pH 6.0-9.0 SU 7.3 NA 6.8 7.1 7.9 7.6 8.5 7.9 7.8 NA 6.8 6.2 7.4 7.4
Iron (total)NRL ug/l 15,400 11,600 NA 23,400 NA 24,200 NA NA NA NA NA NA 16,300 18,300
NRL - No Regulatory Limit
NA - Not AnalyzedConcentrations in Bold exceed permit limits
R- After sample designation indicates RESAMPLING of effluentHighlighted columns are current analytical results.EF- Effluent Sample
INF- Influent Sample
POTW- Publically Owned Treatment Works
GROUNDWATER TREATMENT SYSTEM
Table 3Summary of Wastewater Discharge Analytical Results
Crown Food Mart
Robbinsville, NC
Constituent Discharge Limit Units
Benzene 51 µg/L
Ethylbenzene 97 µg/L
Toluene 610 µg/L
Total Xylenes 488 µg/L
Methyl Tert-Butyl Ether (MTBE)1500 µg/L
Total Lead Monitor Only µg/L
1,2-Dichloroethane (1,2-DCA)37 µg/L
TSS (mg/L)10 mg/l
pH 6.0-9.0 SU
Iron (total)NRL ug/l
NRL - No Regulatory Limit
NA - Not AnalyzedConcentrations in Bold exceed permit limits
R- After sample designation indicates RESAMPLING of effluentHighlighted columns are current analytical results.EF- Effluent Sample
INF- Influent Sample
POTW- Publically Owned Treatment Works
INF-01 INF-02 INF-06 INF-07 INF-08 INF-09 INF-10 INF-11 INF-12 INF-13 INF-14 POTW-EF-01 POTW-EF-06 POTW-EF-07
Jun-19 Jul-19 Jun-20 Sep-20 Jan-21 Apr-21 Jul-21 Nov-21 Mar-22 Jun-22 Oct-22 Jun-19 Jun-20 Sep-20
122 NA 35.7 59.7 58 36.6 25.9 0.81J 4.9 <1.9 13.4 <0.50 <0.50 <0.50
560 NA 246 245 241 171 137 9.3 13.1 87.9 48.1 <0.50 <0.50 <0.50
263 NA 47.8 92.4 24.5 14.1 <1.3 3.0 1.0 3.1 2.9 <0.50 <0.50 <0.50
2710 NA 1,320 1,215 739 627 365.6 10.4 58.9 149 103.5 <1.0 <0.50 <1.0
<5.0 NA <2.5 3.5 <2.5 <2.5 2.0J <0.84 0.57 <1.7 1.6 <0.50 <0.50 <0.50
NA NA <5.0 NA NA NA NA NA NA NA NA <2.5 <5.0 NA
<5.0 NA <2.5 <2.5 <2.5 <2.5 <1.3 <0.64 0.32 <1.3 <0.64 <0.50 <0.50 <0.50
NA 17.0 2.9 4.9 <2.5 <2.5 5.8 21.8 13.9 NA 5.8 <2.5 <2.5 2.8
NA NA 6.3 6.4 6.9 7.9 7.2 7.0 7.1 NA NA 6.9 6.3 7.2
69.5 19,200 NA 16,500 21,800 NA NA NA NA NA 28,200 <50.00 NA NA
TOWN POTWGROUNDWATER TREATMENT SYSTEM
Table 3Summary of Wastewater Discharge Analytical Results
Crown Food Mart
Robbinsville, NC
Constituent Discharge Limit Units
Benzene 51 µg/L
Ethylbenzene 97 µg/L
Toluene 610 µg/L
Total Xylenes 488 µg/L
Methyl Tert-Butyl Ether (MTBE)1500 µg/L
Total Lead Monitor Only µg/L
1,2-Dichloroethane (1,2-DCA)37 µg/L
TSS (mg/L)10 mg/l
pH 6.0-9.0 SU
Iron (total)NRL ug/l
NRL - No Regulatory Limit
NA - Not AnalyzedConcentrations in Bold exceed permit limits
R- After sample designation indicates RESAMPLING of effluentHighlighted columns are current analytical results.EF- Effluent Sample
INF- Influent Sample
POTW- Publically Owned Treatment Works
POTW-EF-08 POTW-EF-09 POTW-EF-10 POTW-EF-11 POTW-EF-12 POTW-EF-13 POTW-EF-14 POTW-INF-07 POTW-INF-10 POTW-INF-11 POTW-INF-12 POTW-INF-13 POTW-INF-14
Jan-21 Apr-21 Jul-21 Nov-21 Mar-22 Jun-22 Oct-22 Sep-20 Jul-21 Nov-21 Mar-22 Jun-22 Oct-22
<0.50 <0.50 <0.50 <0.34 <0.34 <0.34 <0.34 <0.50 0.68 <0.34 <0.34 <0.34 <0.34
<0.50 <0.50 <0.50 <0.30 <0.30 <0.30 <0.30 <0.50 2.6 <0.31 0.37J 0.61 0.67
<0.50 <0.50 <0.50 <0.48 <0.48 <0.48 <0.48 <0.50 <0.48 5.2 <0.48 1.8 1.1
<1.0 <1.0 <1.0 <0.71 <1.0 <0.71 <0.71 <1.0 11.4 <0.71 1.0J 1.4 3.4
<0.50 <0.50 <0.50 <0.42 <0.42 <0.42 <0.42 <0.50 0.43J <0.42 <0.42 <0.42 <0.42
NA NA NA NA NA NA NA NA NA NA NA NA NA
<0.50 <0.50 <0.50 <0.32 <0.32 <0.32 <0.32 <0.50 <0.32 <0.32 <0.32 <0.32 <0.32
NA NA NA NA NA NA <2.5 50.9 <2.7 NA NA NA 231
7.5 7.5 NA 7.1 NA NA NA NA NA NA NA NA NA
NA NA NA NA NA NA NA NA NA NA NA NA NA
TOWN POTW
TABLE 4
EXTRACTION WELL ANALYTICAL RESULTS
Crown Food Mart
2022
Constituent EW-1 EW-2 EW-2 EW-3 EW-3 EW-4 EW-4 EW-5 EW-5
Date 5/18/22 5/18/22 10/12/22 5/18/22 10/12/22 5/18/22 10/12/22 5/18/22 10/12/22
Analytical Method 6200B 8260D 8260D 6200B 8260D 6200B 8260D 6200B 8260D 6200B
Benzene <0.20 1.7 J 3.2 5.1 5.9 27 21.2 11 7.9
2-Butanone (MEK)<1.6 23 J NR <1.6 NR 77J NR 52J NR
n-Butylbenzene <0.15 17 <0.98 7.5 <0.49 23 <2.4 14 <0.49
sec-Butylbenzene <0.11 6.9 <0.80 1.3 <0.40 9.0J <2.0 6 <0.40
tert-Butylbenzene <0.13 <0.52 <0.65 <0.13 <0.32 <1.3 <0.16 <0.64 <0.32
Diisopropyl ether <0.50 <0.51 <0.62 2.1 2.4 <1.3 4.1 1.8 3.5
Ethylbenzene <0.21 70 29.3 20 5.4 150 66.2 65 14.4
Isopropylbenzene <0.11 18 11.6 5 4.2 43 24.9 18 7.6
p-Isopropyltoluene (p-Cymene)<0.097 4.2 NR 3 NR 6.1J NR 4.6J NR
Methyl tert-butyl ether (MTBE)<0.17 <0.69 <0.84 <0.17 1.1 <1.7 2.7 <0.86 4.6
Naphthalene <0.24 14 10.3 17 7.0 35 28.7 17 15.7
n-Propylbenzene <0.086 51 31.7 6.8 6.3 99 61.0 41 11.4
Toluene <0.22 6.3 4.5 1.4 0.85 8.0J 1.7J 5.2 0.79
1,2,4-Trimethylbenzene <0.20 310 194 170 47.8 650 486 310 153
1,3,5-Trimethylbenzene <0.11 75 36.9 93 12.4 220 136 91 49.2
m,p-Xylenes <0.46 130 78.0 140 19.9 240 104 150 56.1
o-Xylene <0.23 15 16.7 18 9.3 58 11.5 26 15.4
Total Xylenes 145 158 298 176
Total Iron

NS - No Sample
NR - Not reportedHighlighted columns indicate the most recent sampling event
#=CL#
July 18, 2022
LIMS USE: FR - ROBERT MARTIN
LIMS OBJECT ID: 92613670
92613670
Project:
Pace Project No.:
RE:
Mr. Robert Martin
Martin and Slagle
24 Lookout Terrace
Black Mountain, NC 28711
CROWN FOOD MART 7/7/22
Dear Mr. Martin:
Enclosed are the analytical results for sample(s) received by the laboratory on July 08, 2022. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lorri Patton
[e-mail]
Project Manager
1(828)254-7176
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 1 of 30
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92613670
CROWN FOOD MART 7/7/22
Lab ID Sample ID Matrix Date Collected Date Received
92613670001 SW 01 177 Water 07/07/22 11:20 07/08/22 10:40
92613670002 SW 02 177 Water 07/07/22 12:00 07/08/22 10:40
92613670003 SW 03 177 Water 07/07/22 12:30 07/08/22 10:40
92613670004 SW 04 177 Water 07/07/22 13:00 07/08/22 10:40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 2 of 30
Page 3 of 30
Page 4 of 30
Page 5 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
July 15, 2022
Lorri Patton
Pace Analytical Services - NC
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Project Location: Crown Food Mart
Client Job Number:
Project Number: 92613670
Laboratory Work Order Number: 22G0561
Enclosed are results of analyses for samples as received by the laboratory on July 12, 2022. If you have any questions
concerning this report, please feel free to contact me.
Sincerely,
Kerry K. McGee
Project Manager
Page 1 of 25
Table of Contents
Page 6 of 30
Table of Contents
Sample Summary 3
Case Narrative 4
Sample Results 5
22G0561-01 5
22G0561-02 7
22G0561-03 9
22G0561-04 11
Sample Preparation Information 13
QC Data 14
Volatile Organic Compounds by GC/MS 14
B312859 14
Flag/Qualifier Summary 19
Certifications 20
Chain of Custody/Sample Receipt 23
Page 2 of 25
Table of Contents
Page 7 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYTICAL SUMMARY
7/15/2022
Pace Analytical Services - NC
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
ATTN: Lorri Patton
92613670
22G0561
The results of analyses performed on the following samples submitted to CON-TEST, a Pace Analytical Laboratory, are found in this report.
PROJECT LOCATION:
PURCHASE ORDER NUMBER:
PROJECT NUMBER:
REPORT DATE:
WORK ORDER NUMBER:
FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB
Crown Food Mart
SW 01 177 22G0561-01 Water SW-846 8260D
SW 02 177 22G0561-02 Water SW-846 8260D
SW 03 177 22G0561-03 Water SW-846 8260D
SW 04 177 22G0561-04 Water SW-846 8260D
[TOC_1]Sample Summary[TOC]
Page 3 of 25
Table of Contents
Page 8 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CASE NARRATIVE SUMMARY
All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report.
[TOC_1]Case Narrative[TOC]
SW-846 8260D
Qualifications:
Continuing calibration verification (CCV) did not meet method specifications and was biased on the low side for this compound.
Analyte & Samples(s) Qualified:
V-05
Naphthalene
22G0561-01[SW 01 177], 22G0561-02[SW 02 177], 22G0561-03[SW 03 177], 22G0561-04[SW 04 177], B312859-BLK1, B312859-BS1, B312859-BSD1, S073905-CCV1
tert-Butyl Alcohol (TBA)
22G0561-01[SW 01 177], 22G0561-02[SW 02 177], 22G0561-03[SW 03 177], 22G0561-04[SW 04 177], B312859-BLK1, B312859-BS1, B312859-BSD1, S073905-CCV1
Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side. Data validation is not affected
since sample result was "not detected" for this compound.
Analyte & Samples(s) Qualified:
V-20
Chloromethane
B312859-BS1, B312859-BSD1, S073905-CCV1
The results of analyses reported only relate to samples submitted to Con-Test, a Pace Analytical Laboratory, for testing.
I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed
in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the
best of my knowledge and belief, accurate and complete.
Lisa A. Worthington
Technical Representative
Page 4 of 25
Table of Contents
Page 9 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/12/2022
Work Order: 22G0561Sample Description:Project Location: Crown Food Mart
Sample ID: 22G0561-01
Field Sample #: SW 01 177
Sample Matrix: Water
Sampled: 7/7/2022 11:20
[TOC_2]22G0561-01[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 7/13/22 15:51 MFFg/L2.0 7/13/22SW-846 8260D1Acetone
ND 5.0 7/13/22 15:51 MFFg/L0.55 7/13/22SW-846 8260D1Acrylonitrile
ND 0.50 7/13/22 15:51 MFFg/L0.14 7/13/22SW-846 8260D1tert-Amyl Methyl Ether (TAME)
ND 1.0 7/13/22 15:51 MFFg/L0.20 7/13/22SW-846 8260D1Benzene
ND 1.0 7/13/22 15:51 MFFg/L0.15 7/13/22SW-846 8260D1Bromobenzene
ND 1.0 7/13/22 15:51 MFFg/L0.31 7/13/22SW-846 8260D1Bromochloromethane
ND 0.50 7/13/22 15:51 MFFg/L0.18 7/13/22SW-846 8260D1Bromodichloromethane
ND 1.0 7/13/22 15:51 MFFg/L0.38 7/13/22SW-846 8260D1Bromoform
ND 2.0 7/13/22 15:51 MFFg/L1.5 7/13/22SW-846 8260D1Bromomethane
ND 20 7/13/22 15:51 MFFg/L1.6 7/13/22SW-846 8260D12-Butanone (MEK)
ND 20 7/13/22 15:51 MFFg/L4.7 7/13/22SW-846 8260D1V-05tert-Butyl Alcohol (TBA)
ND 1.0 7/13/22 15:51 MFFg/L0.15 7/13/22SW-846 8260D1n-Butylbenzene
ND 1.0 7/13/22 15:51 MFFg/L0.11 7/13/22SW-846 8260D1sec-Butylbenzene
ND 1.0 7/13/22 15:51 MFFg/L0.13 7/13/22SW-846 8260D1tert-Butylbenzene
ND 0.50 7/13/22 15:51 MFFg/L0.15 7/13/22SW-846 8260D1tert-Butyl Ethyl Ether (TBEE)
ND 5.0 7/13/22 15:51 MFFg/L1.4 7/13/22SW-846 8260D1Carbon Disulfide
ND 1.0 7/13/22 15:51 MFFg/L0.16 7/13/22SW-846 8260D1Carbon Tetrachloride
ND 1.0 7/13/22 15:51 MFFg/L0.11 7/13/22SW-846 8260D1Chlorobenzene
ND 0.50 7/13/22 15:51 MFFg/L0.22 7/13/22SW-846 8260D1Chlorodibromomethane
ND 2.0 7/13/22 15:51 MFFg/L0.32 7/13/22SW-846 8260D1Chloroethane
ND 2.0 7/13/22 15:51 MFFg/L0.17 7/13/22SW-846 8260D1Chloroform
ND 2.0 7/13/22 15:51 MFFg/L0.52 7/13/22SW-846 8260D1Chloromethane
ND 1.0 7/13/22 15:51 MFFg/L0.11 7/13/22SW-846 8260D12-Chlorotoluene
ND 1.0 7/13/22 15:51 MFFg/L0.12 7/13/22SW-846 8260D14-Chlorotoluene
ND 5.0 7/13/22 15:51 MFFg/L0.80 7/13/22SW-846 8260D11,2-Dibromo-3-chloropropane (DBCP)
ND 0.50 7/13/22 15:51 MFFg/L0.17 7/13/22SW-846 8260D11,2-Dibromoethane (EDB)
ND 1.0 7/13/22 15:51 MFFg/L0.35 7/13/22SW-846 8260D1Dibromomethane
ND 1.0 7/13/22 15:51 MFFg/L0.12 7/13/22SW-846 8260D11,2-Dichlorobenzene
ND 1.0 7/13/22 15:51 MFFg/L0.12 7/13/22SW-846 8260D11,3-Dichlorobenzene
ND 1.0 7/13/22 15:51 MFFg/L0.13 7/13/22SW-846 8260D11,4-Dichlorobenzene
ND 2.0 7/13/22 15:51 MFFg/L1.6 7/13/22SW-846 8260D1trans-1,4-Dichloro-2-butene
ND 2.0 7/13/22 15:51 MFFg/L0.19 7/13/22SW-846 8260D1Dichlorodifluoromethane (Freon 12)
ND 1.0 7/13/22 15:51 MFFg/L0.14 7/13/22SW-846 8260D11,1-Dichloroethane
ND 1.0 7/13/22 15:51 MFFg/L0.31 7/13/22SW-846 8260D11,2-Dichloroethane
ND 1.0 7/13/22 15:51 MFFg/L0.14 7/13/22SW-846 8260D11,1-Dichloroethylene
ND 1.0 7/13/22 15:51 MFFg/L0.15 7/13/22SW-846 8260D1cis-1,2-Dichloroethylene
ND 1.0 7/13/22 15:51 MFFg/L0.17 7/13/22SW-846 8260D1trans-1,2-Dichloroethylene
ND 1.0 7/13/22 15:51 MFFg/L0.18 7/13/22SW-846 8260D11,2-Dichloropropane
ND 0.50 7/13/22 15:51 MFFg/L0.13 7/13/22SW-846 8260D11,3-Dichloropropane
ND 1.0 7/13/22 15:51 MFFg/L0.33 7/13/22SW-846 8260D12,2-Dichloropropane
ND 2.0 7/13/22 15:51 MFFg/L0.15 7/13/22SW-846 8260D11,1-Dichloropropene
ND 0.50 7/13/22 15:51 MFFg/L0.16 7/13/22SW-846 8260D1cis-1,3-Dichloropropene
ND 0.50 7/13/22 15:51 MFFg/L0.17 7/13/22SW-846 8260D1trans-1,3-Dichloropropene
ND 2.0 7/13/22 15:51 MFFg/L0.18 7/13/22SW-846 8260D1Diethyl Ether
[TOC_1]Sample Results[TOC]
Page 5 of 25
Table of Contents
Page 10 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/12/2022
Work Order: 22G0561Sample Description:Project Location: Crown Food Mart
Sample ID: 22G0561-01
Field Sample #: SW 01 177
Sample Matrix: Water
Sampled: 7/7/2022 11:20
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 7/13/22 15:51 MFFg/L0.13 7/13/22SW-846 8260D1Diisopropyl Ether (DIPE)
ND 50 7/13/22 15:51 MFFg/L21 7/13/22SW-846 8260D11,4-Dioxane
ND 1.0 7/13/22 15:51 MFFg/L0.21 7/13/22SW-846 8260D1Ethylbenzene
ND 0.60 7/13/22 15:51 MFFg/L0.46 7/13/22SW-846 8260D1Hexachlorobutadiene
ND 10 7/13/22 15:51 MFFg/L1.1 7/13/22SW-846 8260D12-Hexanone (MBK)
ND 1.0 7/13/22 15:51 MFFg/L0.11 7/13/22SW-846 8260D1Isopropylbenzene (Cumene)
ND 1.0 7/13/22 15:51 MFFg/L0.097 7/13/22SW-846 8260D1p-Isopropyltoluene (p-Cymene)
ND 1.0 7/13/22 15:51 MFFg/L0.17 7/13/22SW-846 8260D1Methyl tert-Butyl Ether (MTBE)
ND 5.0 7/13/22 15:51 MFFg/L0.23 7/13/22SW-846 8260D1Methylene Chloride
ND 10 7/13/22 15:51 MFFg/L1.3 7/13/22SW-846 8260D14-Methyl-2-pentanone (MIBK)
ND 2.0 7/13/22 15:51 MFFg/L0.24 7/13/22SW-846 8260D1V-05Naphthalene
ND 1.0 7/13/22 15:51 MFFg/L0.086 7/13/22SW-846 8260D1n-Propylbenzene
ND 1.0 7/13/22 15:51 MFFg/L0.11 7/13/22SW-846 8260D1Styrene
ND 1.0 7/13/22 15:51 MFFg/L0.18 7/13/22SW-846 8260D11,1,1,2-Tetrachloroethane
ND 0.50 7/13/22 15:51 MFFg/L0.13 7/13/22SW-846 8260D11,1,2,2-Tetrachloroethane
ND 1.0 7/13/22 15:51 MFFg/L0.19 7/13/22SW-846 8260D1Tetrachloroethylene
ND 10 7/13/22 15:51 MFFg/L0.49 7/13/22SW-846 8260D1Tetrahydrofuran
ND 1.0 7/13/22 15:51 MFFg/L0.22 7/13/22SW-846 8260D1Toluene
ND 5.0 7/13/22 15:51 MFFg/L0.30 7/13/22SW-846 8260D11,2,3-Trichlorobenzene
ND 1.0 7/13/22 15:51 MFFg/L0.25 7/13/22SW-846 8260D11,2,4-Trichlorobenzene
ND 1.0 7/13/22 15:51 MFFg/L0.21 7/13/22SW-846 8260D11,3,5-Trichlorobenzene
ND 1.0 7/13/22 15:51 MFFg/L0.17 7/13/22SW-846 8260D11,1,1-Trichloroethane
ND 1.0 7/13/22 15:51 MFFg/L0.18 7/13/22SW-846 8260D11,1,2-Trichloroethane
ND 1.0 7/13/22 15:51 MFFg/L0.19 7/13/22SW-846 8260D1Trichloroethylene
ND 2.0 7/13/22 15:51 MFFg/L0.18 7/13/22SW-846 8260D1Trichlorofluoromethane (Freon 11)
ND 2.0 7/13/22 15:51 MFFg/L0.28 7/13/22SW-846 8260D11,2,3-Trichloropropane
ND 1.0 7/13/22 15:51 MFFg/L0.23 7/13/22SW-846 8260D11,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
ND 1.0 7/13/22 15:51 MFFg/L0.20 7/13/22SW-846 8260D11,2,4-Trimethylbenzene
ND 1.0 7/13/22 15:51 MFFg/L0.11 7/13/22SW-846 8260D11,3,5-Trimethylbenzene
ND 2.0 7/13/22 15:51 MFFg/L0.21 7/13/22SW-846 8260D1Vinyl Chloride
ND 2.0 7/13/22 15:51 MFFg/L0.46 7/13/22SW-846 8260D1m+p Xylene
ND 1.0 7/13/22 15:51 MFFg/L0.23 7/13/22SW-846 8260D1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 98.2 7/13/22 15:5170-130
Toluene-d8 100 7/13/22 15:5170-130
4-Bromofluorobenzene 97.1 7/13/22 15:5170-130
Page 6 of 25
Table of Contents
Page 11 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/12/2022
Work Order: 22G0561Sample Description:Project Location: Crown Food Mart
Sample ID: 22G0561-02
Field Sample #: SW 02 177
Sample Matrix: Water
Sampled: 7/7/2022 12:00
[TOC_2]22G0561-02[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 7/13/22 16:16 MFFg/L2.0 7/13/22SW-846 8260D1Acetone
ND 5.0 7/13/22 16:16 MFFg/L0.55 7/13/22SW-846 8260D1Acrylonitrile
ND 0.50 7/13/22 16:16 MFFg/L0.14 7/13/22SW-846 8260D1tert-Amyl Methyl Ether (TAME)
ND 1.0 7/13/22 16:16 MFFg/L0.20 7/13/22SW-846 8260D1Benzene
ND 1.0 7/13/22 16:16 MFFg/L0.15 7/13/22SW-846 8260D1Bromobenzene
ND 1.0 7/13/22 16:16 MFFg/L0.31 7/13/22SW-846 8260D1Bromochloromethane
ND 0.50 7/13/22 16:16 MFFg/L0.18 7/13/22SW-846 8260D1Bromodichloromethane
ND 1.0 7/13/22 16:16 MFFg/L0.38 7/13/22SW-846 8260D1Bromoform
ND 2.0 7/13/22 16:16 MFFg/L1.5 7/13/22SW-846 8260D1Bromomethane
ND 20 7/13/22 16:16 MFFg/L1.6 7/13/22SW-846 8260D12-Butanone (MEK)
ND 20 7/13/22 16:16 MFFg/L4.7 7/13/22SW-846 8260D1V-05tert-Butyl Alcohol (TBA)
ND 1.0 7/13/22 16:16 MFFg/L0.15 7/13/22SW-846 8260D1n-Butylbenzene
ND 1.0 7/13/22 16:16 MFFg/L0.11 7/13/22SW-846 8260D1sec-Butylbenzene
ND 1.0 7/13/22 16:16 MFFg/L0.13 7/13/22SW-846 8260D1tert-Butylbenzene
ND 0.50 7/13/22 16:16 MFFg/L0.15 7/13/22SW-846 8260D1tert-Butyl Ethyl Ether (TBEE)
ND 5.0 7/13/22 16:16 MFFg/L1.4 7/13/22SW-846 8260D1Carbon Disulfide
ND 1.0 7/13/22 16:16 MFFg/L0.16 7/13/22SW-846 8260D1Carbon Tetrachloride
ND 1.0 7/13/22 16:16 MFFg/L0.11 7/13/22SW-846 8260D1Chlorobenzene
ND 0.50 7/13/22 16:16 MFFg/L0.22 7/13/22SW-846 8260D1Chlorodibromomethane
ND 2.0 7/13/22 16:16 MFFg/L0.32 7/13/22SW-846 8260D1Chloroethane
ND 2.0 7/13/22 16:16 MFFg/L0.17 7/13/22SW-846 8260D1Chloroform
ND 2.0 7/13/22 16:16 MFFg/L0.52 7/13/22SW-846 8260D1Chloromethane
ND 1.0 7/13/22 16:16 MFFg/L0.11 7/13/22SW-846 8260D12-Chlorotoluene
ND 1.0 7/13/22 16:16 MFFg/L0.12 7/13/22SW-846 8260D14-Chlorotoluene
ND 5.0 7/13/22 16:16 MFFg/L0.80 7/13/22SW-846 8260D11,2-Dibromo-3-chloropropane (DBCP)
ND 0.50 7/13/22 16:16 MFFg/L0.17 7/13/22SW-846 8260D11,2-Dibromoethane (EDB)
ND 1.0 7/13/22 16:16 MFFg/L0.35 7/13/22SW-846 8260D1Dibromomethane
ND 1.0 7/13/22 16:16 MFFg/L0.12 7/13/22SW-846 8260D11,2-Dichlorobenzene
ND 1.0 7/13/22 16:16 MFFg/L0.12 7/13/22SW-846 8260D11,3-Dichlorobenzene
ND 1.0 7/13/22 16:16 MFFg/L0.13 7/13/22SW-846 8260D11,4-Dichlorobenzene
ND 2.0 7/13/22 16:16 MFFg/L1.6 7/13/22SW-846 8260D1trans-1,4-Dichloro-2-butene
ND 2.0 7/13/22 16:16 MFFg/L0.19 7/13/22SW-846 8260D1Dichlorodifluoromethane (Freon 12)
ND 1.0 7/13/22 16:16 MFFg/L0.14 7/13/22SW-846 8260D11,1-Dichloroethane
ND 1.0 7/13/22 16:16 MFFg/L0.31 7/13/22SW-846 8260D11,2-Dichloroethane
ND 1.0 7/13/22 16:16 MFFg/L0.14 7/13/22SW-846 8260D11,1-Dichloroethylene
ND 1.0 7/13/22 16:16 MFFg/L0.15 7/13/22SW-846 8260D1cis-1,2-Dichloroethylene
ND 1.0 7/13/22 16:16 MFFg/L0.17 7/13/22SW-846 8260D1trans-1,2-Dichloroethylene
ND 1.0 7/13/22 16:16 MFFg/L0.18 7/13/22SW-846 8260D11,2-Dichloropropane
ND 0.50 7/13/22 16:16 MFFg/L0.13 7/13/22SW-846 8260D11,3-Dichloropropane
ND 1.0 7/13/22 16:16 MFFg/L0.33 7/13/22SW-846 8260D12,2-Dichloropropane
ND 2.0 7/13/22 16:16 MFFg/L0.15 7/13/22SW-846 8260D11,1-Dichloropropene
ND 0.50 7/13/22 16:16 MFFg/L0.16 7/13/22SW-846 8260D1cis-1,3-Dichloropropene
ND 0.50 7/13/22 16:16 MFFg/L0.17 7/13/22SW-846 8260D1trans-1,3-Dichloropropene
ND 2.0 7/13/22 16:16 MFFg/L0.18 7/13/22SW-846 8260D1Diethyl Ether
Page 7 of 25
Table of Contents
Page 12 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/12/2022
Work Order: 22G0561Sample Description:Project Location: Crown Food Mart
Sample ID: 22G0561-02
Field Sample #: SW 02 177
Sample Matrix: Water
Sampled: 7/7/2022 12:00
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 7/13/22 16:16 MFFg/L0.13 7/13/22SW-846 8260D1Diisopropyl Ether (DIPE)
ND 50 7/13/22 16:16 MFFg/L21 7/13/22SW-846 8260D11,4-Dioxane
ND 1.0 7/13/22 16:16 MFFg/L0.21 7/13/22SW-846 8260D1Ethylbenzene
ND 0.60 7/13/22 16:16 MFFg/L0.46 7/13/22SW-846 8260D1Hexachlorobutadiene
ND 10 7/13/22 16:16 MFFg/L1.1 7/13/22SW-846 8260D12-Hexanone (MBK)
ND 1.0 7/13/22 16:16 MFFg/L0.11 7/13/22SW-846 8260D1Isopropylbenzene (Cumene)
ND 1.0 7/13/22 16:16 MFFg/L0.097 7/13/22SW-846 8260D1p-Isopropyltoluene (p-Cymene)
ND 1.0 7/13/22 16:16 MFFg/L0.17 7/13/22SW-846 8260D1Methyl tert-Butyl Ether (MTBE)
ND 5.0 7/13/22 16:16 MFFg/L0.23 7/13/22SW-846 8260D1Methylene Chloride
ND 10 7/13/22 16:16 MFFg/L1.3 7/13/22SW-846 8260D14-Methyl-2-pentanone (MIBK)
ND 2.0 7/13/22 16:16 MFFg/L0.24 7/13/22SW-846 8260D1V-05Naphthalene
0.15 1.0 7/13/22 16:16 MFFg/L0.086 7/13/22SW-846 8260D1Jn-Propylbenzene
ND 1.0 7/13/22 16:16 MFFg/L0.11 7/13/22SW-846 8260D1Styrene
ND 1.0 7/13/22 16:16 MFFg/L0.18 7/13/22SW-846 8260D11,1,1,2-Tetrachloroethane
ND 0.50 7/13/22 16:16 MFFg/L0.13 7/13/22SW-846 8260D11,1,2,2-Tetrachloroethane
ND 1.0 7/13/22 16:16 MFFg/L0.19 7/13/22SW-846 8260D1Tetrachloroethylene
ND 10 7/13/22 16:16 MFFg/L0.49 7/13/22SW-846 8260D1Tetrahydrofuran
ND 1.0 7/13/22 16:16 MFFg/L0.22 7/13/22SW-846 8260D1Toluene
ND 5.0 7/13/22 16:16 MFFg/L0.30 7/13/22SW-846 8260D11,2,3-Trichlorobenzene
ND 1.0 7/13/22 16:16 MFFg/L0.25 7/13/22SW-846 8260D11,2,4-Trichlorobenzene
ND 1.0 7/13/22 16:16 MFFg/L0.21 7/13/22SW-846 8260D11,3,5-Trichlorobenzene
ND 1.0 7/13/22 16:16 MFFg/L0.17 7/13/22SW-846 8260D11,1,1-Trichloroethane
ND 1.0 7/13/22 16:16 MFFg/L0.18 7/13/22SW-846 8260D11,1,2-Trichloroethane
ND 1.0 7/13/22 16:16 MFFg/L0.19 7/13/22SW-846 8260D1Trichloroethylene
ND 2.0 7/13/22 16:16 MFFg/L0.18 7/13/22SW-846 8260D1Trichlorofluoromethane (Freon 11)
ND 2.0 7/13/22 16:16 MFFg/L0.28 7/13/22SW-846 8260D11,2,3-Trichloropropane
ND 1.0 7/13/22 16:16 MFFg/L0.23 7/13/22SW-846 8260D11,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
1.0 1.0 7/13/22 16:16 MFFg/L0.20 7/13/22SW-846 8260D11,2,4-Trimethylbenzene
0.29 1.0 7/13/22 16:16 MFFg/L0.11 7/13/22SW-846 8260D1J1,3,5-Trimethylbenzene
ND 2.0 7/13/22 16:16 MFFg/L0.21 7/13/22SW-846 8260D1Vinyl Chloride
ND 2.0 7/13/22 16:16 MFFg/L0.46 7/13/22SW-846 8260D1m+p Xylene
ND 1.0 7/13/22 16:16 MFFg/L0.23 7/13/22SW-846 8260D1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 98.4 7/13/22 16:1670-130
Toluene-d8 101 7/13/22 16:1670-130
4-Bromofluorobenzene 96.1 7/13/22 16:1670-130
Page 8 of 25
Table of Contents
Page 13 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/12/2022
Work Order: 22G0561Sample Description:Project Location: Crown Food Mart
Sample ID: 22G0561-03
Field Sample #: SW 03 177
Sample Matrix: Water
Sampled: 7/7/2022 12:30
[TOC_2]22G0561-03[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 7/13/22 16:40 MFFg/L2.0 7/13/22SW-846 8260D1Acetone
ND 5.0 7/13/22 16:40 MFFg/L0.55 7/13/22SW-846 8260D1Acrylonitrile
ND 0.50 7/13/22 16:40 MFFg/L0.14 7/13/22SW-846 8260D1tert-Amyl Methyl Ether (TAME)
ND 1.0 7/13/22 16:40 MFFg/L0.20 7/13/22SW-846 8260D1Benzene
ND 1.0 7/13/22 16:40 MFFg/L0.15 7/13/22SW-846 8260D1Bromobenzene
ND 1.0 7/13/22 16:40 MFFg/L0.31 7/13/22SW-846 8260D1Bromochloromethane
ND 0.50 7/13/22 16:40 MFFg/L0.18 7/13/22SW-846 8260D1Bromodichloromethane
ND 1.0 7/13/22 16:40 MFFg/L0.38 7/13/22SW-846 8260D1Bromoform
ND 2.0 7/13/22 16:40 MFFg/L1.5 7/13/22SW-846 8260D1Bromomethane
ND 20 7/13/22 16:40 MFFg/L1.6 7/13/22SW-846 8260D12-Butanone (MEK)
ND 20 7/13/22 16:40 MFFg/L4.7 7/13/22SW-846 8260D1V-05tert-Butyl Alcohol (TBA)
ND 1.0 7/13/22 16:40 MFFg/L0.15 7/13/22SW-846 8260D1n-Butylbenzene
ND 1.0 7/13/22 16:40 MFFg/L0.11 7/13/22SW-846 8260D1sec-Butylbenzene
ND 1.0 7/13/22 16:40 MFFg/L0.13 7/13/22SW-846 8260D1tert-Butylbenzene
ND 0.50 7/13/22 16:40 MFFg/L0.15 7/13/22SW-846 8260D1tert-Butyl Ethyl Ether (TBEE)
ND 5.0 7/13/22 16:40 MFFg/L1.4 7/13/22SW-846 8260D1Carbon Disulfide
ND 1.0 7/13/22 16:40 MFFg/L0.16 7/13/22SW-846 8260D1Carbon Tetrachloride
ND 1.0 7/13/22 16:40 MFFg/L0.11 7/13/22SW-846 8260D1Chlorobenzene
ND 0.50 7/13/22 16:40 MFFg/L0.22 7/13/22SW-846 8260D1Chlorodibromomethane
ND 2.0 7/13/22 16:40 MFFg/L0.32 7/13/22SW-846 8260D1Chloroethane
ND 2.0 7/13/22 16:40 MFFg/L0.17 7/13/22SW-846 8260D1Chloroform
ND 2.0 7/13/22 16:40 MFFg/L0.52 7/13/22SW-846 8260D1Chloromethane
ND 1.0 7/13/22 16:40 MFFg/L0.11 7/13/22SW-846 8260D12-Chlorotoluene
ND 1.0 7/13/22 16:40 MFFg/L0.12 7/13/22SW-846 8260D14-Chlorotoluene
ND 5.0 7/13/22 16:40 MFFg/L0.80 7/13/22SW-846 8260D11,2-Dibromo-3-chloropropane (DBCP)
ND 0.50 7/13/22 16:40 MFFg/L0.17 7/13/22SW-846 8260D11,2-Dibromoethane (EDB)
ND 1.0 7/13/22 16:40 MFFg/L0.35 7/13/22SW-846 8260D1Dibromomethane
ND 1.0 7/13/22 16:40 MFFg/L0.12 7/13/22SW-846 8260D11,2-Dichlorobenzene
ND 1.0 7/13/22 16:40 MFFg/L0.12 7/13/22SW-846 8260D11,3-Dichlorobenzene
ND 1.0 7/13/22 16:40 MFFg/L0.13 7/13/22SW-846 8260D11,4-Dichlorobenzene
ND 2.0 7/13/22 16:40 MFFg/L1.6 7/13/22SW-846 8260D1trans-1,4-Dichloro-2-butene
ND 2.0 7/13/22 16:40 MFFg/L0.19 7/13/22SW-846 8260D1Dichlorodifluoromethane (Freon 12)
ND 1.0 7/13/22 16:40 MFFg/L0.14 7/13/22SW-846 8260D11,1-Dichloroethane
ND 1.0 7/13/22 16:40 MFFg/L0.31 7/13/22SW-846 8260D11,2-Dichloroethane
ND 1.0 7/13/22 16:40 MFFg/L0.14 7/13/22SW-846 8260D11,1-Dichloroethylene
ND 1.0 7/13/22 16:40 MFFg/L0.15 7/13/22SW-846 8260D1cis-1,2-Dichloroethylene
ND 1.0 7/13/22 16:40 MFFg/L0.17 7/13/22SW-846 8260D1trans-1,2-Dichloroethylene
ND 1.0 7/13/22 16:40 MFFg/L0.18 7/13/22SW-846 8260D11,2-Dichloropropane
ND 0.50 7/13/22 16:40 MFFg/L0.13 7/13/22SW-846 8260D11,3-Dichloropropane
ND 1.0 7/13/22 16:40 MFFg/L0.33 7/13/22SW-846 8260D12,2-Dichloropropane
ND 2.0 7/13/22 16:40 MFFg/L0.15 7/13/22SW-846 8260D11,1-Dichloropropene
ND 0.50 7/13/22 16:40 MFFg/L0.16 7/13/22SW-846 8260D1cis-1,3-Dichloropropene
ND 0.50 7/13/22 16:40 MFFg/L0.17 7/13/22SW-846 8260D1trans-1,3-Dichloropropene
ND 2.0 7/13/22 16:40 MFFg/L0.18 7/13/22SW-846 8260D1Diethyl Ether
Page 9 of 25
Table of Contents
Page 14 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/12/2022
Work Order: 22G0561Sample Description:Project Location: Crown Food Mart
Sample ID: 22G0561-03
Field Sample #: SW 03 177
Sample Matrix: Water
Sampled: 7/7/2022 12:30
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 7/13/22 16:40 MFFg/L0.13 7/13/22SW-846 8260D1Diisopropyl Ether (DIPE)
ND 50 7/13/22 16:40 MFFg/L21 7/13/22SW-846 8260D11,4-Dioxane
ND 1.0 7/13/22 16:40 MFFg/L0.21 7/13/22SW-846 8260D1Ethylbenzene
ND 0.60 7/13/22 16:40 MFFg/L0.46 7/13/22SW-846 8260D1Hexachlorobutadiene
ND 10 7/13/22 16:40 MFFg/L1.1 7/13/22SW-846 8260D12-Hexanone (MBK)
ND 1.0 7/13/22 16:40 MFFg/L0.11 7/13/22SW-846 8260D1Isopropylbenzene (Cumene)
ND 1.0 7/13/22 16:40 MFFg/L0.097 7/13/22SW-846 8260D1p-Isopropyltoluene (p-Cymene)
ND 1.0 7/13/22 16:40 MFFg/L0.17 7/13/22SW-846 8260D1Methyl tert-Butyl Ether (MTBE)
ND 5.0 7/13/22 16:40 MFFg/L0.23 7/13/22SW-846 8260D1Methylene Chloride
ND 10 7/13/22 16:40 MFFg/L1.3 7/13/22SW-846 8260D14-Methyl-2-pentanone (MIBK)
ND 2.0 7/13/22 16:40 MFFg/L0.24 7/13/22SW-846 8260D1V-05Naphthalene
ND 1.0 7/13/22 16:40 MFFg/L0.086 7/13/22SW-846 8260D1n-Propylbenzene
ND 1.0 7/13/22 16:40 MFFg/L0.11 7/13/22SW-846 8260D1Styrene
ND 1.0 7/13/22 16:40 MFFg/L0.18 7/13/22SW-846 8260D11,1,1,2-Tetrachloroethane
ND 0.50 7/13/22 16:40 MFFg/L0.13 7/13/22SW-846 8260D11,1,2,2-Tetrachloroethane
ND 1.0 7/13/22 16:40 MFFg/L0.19 7/13/22SW-846 8260D1Tetrachloroethylene
ND 10 7/13/22 16:40 MFFg/L0.49 7/13/22SW-846 8260D1Tetrahydrofuran
ND 1.0 7/13/22 16:40 MFFg/L0.22 7/13/22SW-846 8260D1Toluene
ND 5.0 7/13/22 16:40 MFFg/L0.30 7/13/22SW-846 8260D11,2,3-Trichlorobenzene
ND 1.0 7/13/22 16:40 MFFg/L0.25 7/13/22SW-846 8260D11,2,4-Trichlorobenzene
ND 1.0 7/13/22 16:40 MFFg/L0.21 7/13/22SW-846 8260D11,3,5-Trichlorobenzene
ND 1.0 7/13/22 16:40 MFFg/L0.17 7/13/22SW-846 8260D11,1,1-Trichloroethane
ND 1.0 7/13/22 16:40 MFFg/L0.18 7/13/22SW-846 8260D11,1,2-Trichloroethane
ND 1.0 7/13/22 16:40 MFFg/L0.19 7/13/22SW-846 8260D1Trichloroethylene
ND 2.0 7/13/22 16:40 MFFg/L0.18 7/13/22SW-846 8260D1Trichlorofluoromethane (Freon 11)
ND 2.0 7/13/22 16:40 MFFg/L0.28 7/13/22SW-846 8260D11,2,3-Trichloropropane
ND 1.0 7/13/22 16:40 MFFg/L0.23 7/13/22SW-846 8260D11,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
0.36 1.0 7/13/22 16:40 MFFg/L0.20 7/13/22SW-846 8260D1J1,2,4-Trimethylbenzene
ND 1.0 7/13/22 16:40 MFFg/L0.11 7/13/22SW-846 8260D11,3,5-Trimethylbenzene
ND 2.0 7/13/22 16:40 MFFg/L0.21 7/13/22SW-846 8260D1Vinyl Chloride
ND 2.0 7/13/22 16:40 MFFg/L0.46 7/13/22SW-846 8260D1m+p Xylene
ND 1.0 7/13/22 16:40 MFFg/L0.23 7/13/22SW-846 8260D1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 97.5 7/13/22 16:4070-130
Toluene-d8 101 7/13/22 16:4070-130
4-Bromofluorobenzene 97.6 7/13/22 16:4070-130
Page 10 of 25
Table of Contents
Page 15 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/12/2022
Work Order: 22G0561Sample Description:Project Location: Crown Food Mart
Sample ID: 22G0561-04
Field Sample #: SW 04 177
Sample Matrix: Water
Sampled: 7/7/2022 13:00
[TOC_2]22G0561-04[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 7/13/22 17:04 MFFg/L2.0 7/13/22SW-846 8260D1Acetone
ND 5.0 7/13/22 17:04 MFFg/L0.55 7/13/22SW-846 8260D1Acrylonitrile
ND 0.50 7/13/22 17:04 MFFg/L0.14 7/13/22SW-846 8260D1tert-Amyl Methyl Ether (TAME)
ND 1.0 7/13/22 17:04 MFFg/L0.20 7/13/22SW-846 8260D1Benzene
ND 1.0 7/13/22 17:04 MFFg/L0.15 7/13/22SW-846 8260D1Bromobenzene
ND 1.0 7/13/22 17:04 MFFg/L0.31 7/13/22SW-846 8260D1Bromochloromethane
ND 0.50 7/13/22 17:04 MFFg/L0.18 7/13/22SW-846 8260D1Bromodichloromethane
ND 1.0 7/13/22 17:04 MFFg/L0.38 7/13/22SW-846 8260D1Bromoform
ND 2.0 7/13/22 17:04 MFFg/L1.5 7/13/22SW-846 8260D1Bromomethane
ND 20 7/13/22 17:04 MFFg/L1.6 7/13/22SW-846 8260D12-Butanone (MEK)
ND 20 7/13/22 17:04 MFFg/L4.7 7/13/22SW-846 8260D1V-05tert-Butyl Alcohol (TBA)
ND 1.0 7/13/22 17:04 MFFg/L0.15 7/13/22SW-846 8260D1n-Butylbenzene
ND 1.0 7/13/22 17:04 MFFg/L0.11 7/13/22SW-846 8260D1sec-Butylbenzene
ND 1.0 7/13/22 17:04 MFFg/L0.13 7/13/22SW-846 8260D1tert-Butylbenzene
ND 0.50 7/13/22 17:04 MFFg/L0.15 7/13/22SW-846 8260D1tert-Butyl Ethyl Ether (TBEE)
ND 5.0 7/13/22 17:04 MFFg/L1.4 7/13/22SW-846 8260D1Carbon Disulfide
ND 1.0 7/13/22 17:04 MFFg/L0.16 7/13/22SW-846 8260D1Carbon Tetrachloride
ND 1.0 7/13/22 17:04 MFFg/L0.11 7/13/22SW-846 8260D1Chlorobenzene
ND 0.50 7/13/22 17:04 MFFg/L0.22 7/13/22SW-846 8260D1Chlorodibromomethane
ND 2.0 7/13/22 17:04 MFFg/L0.32 7/13/22SW-846 8260D1Chloroethane
ND 2.0 7/13/22 17:04 MFFg/L0.17 7/13/22SW-846 8260D1Chloroform
ND 2.0 7/13/22 17:04 MFFg/L0.52 7/13/22SW-846 8260D1Chloromethane
ND 1.0 7/13/22 17:04 MFFg/L0.11 7/13/22SW-846 8260D12-Chlorotoluene
ND 1.0 7/13/22 17:04 MFFg/L0.12 7/13/22SW-846 8260D14-Chlorotoluene
ND 5.0 7/13/22 17:04 MFFg/L0.80 7/13/22SW-846 8260D11,2-Dibromo-3-chloropropane (DBCP)
ND 0.50 7/13/22 17:04 MFFg/L0.17 7/13/22SW-846 8260D11,2-Dibromoethane (EDB)
ND 1.0 7/13/22 17:04 MFFg/L0.35 7/13/22SW-846 8260D1Dibromomethane
ND 1.0 7/13/22 17:04 MFFg/L0.12 7/13/22SW-846 8260D11,2-Dichlorobenzene
ND 1.0 7/13/22 17:04 MFFg/L0.12 7/13/22SW-846 8260D11,3-Dichlorobenzene
ND 1.0 7/13/22 17:04 MFFg/L0.13 7/13/22SW-846 8260D11,4-Dichlorobenzene
ND 2.0 7/13/22 17:04 MFFg/L1.6 7/13/22SW-846 8260D1trans-1,4-Dichloro-2-butene
ND 2.0 7/13/22 17:04 MFFg/L0.19 7/13/22SW-846 8260D1Dichlorodifluoromethane (Freon 12)
ND 1.0 7/13/22 17:04 MFFg/L0.14 7/13/22SW-846 8260D11,1-Dichloroethane
ND 1.0 7/13/22 17:04 MFFg/L0.31 7/13/22SW-846 8260D11,2-Dichloroethane
ND 1.0 7/13/22 17:04 MFFg/L0.14 7/13/22SW-846 8260D11,1-Dichloroethylene
ND 1.0 7/13/22 17:04 MFFg/L0.15 7/13/22SW-846 8260D1cis-1,2-Dichloroethylene
ND 1.0 7/13/22 17:04 MFFg/L0.17 7/13/22SW-846 8260D1trans-1,2-Dichloroethylene
ND 1.0 7/13/22 17:04 MFFg/L0.18 7/13/22SW-846 8260D11,2-Dichloropropane
ND 0.50 7/13/22 17:04 MFFg/L0.13 7/13/22SW-846 8260D11,3-Dichloropropane
ND 1.0 7/13/22 17:04 MFFg/L0.33 7/13/22SW-846 8260D12,2-Dichloropropane
ND 2.0 7/13/22 17:04 MFFg/L0.15 7/13/22SW-846 8260D11,1-Dichloropropene
ND 0.50 7/13/22 17:04 MFFg/L0.16 7/13/22SW-846 8260D1cis-1,3-Dichloropropene
ND 0.50 7/13/22 17:04 MFFg/L0.17 7/13/22SW-846 8260D1trans-1,3-Dichloropropene
ND 2.0 7/13/22 17:04 MFFg/L0.18 7/13/22SW-846 8260D1Diethyl Ether
Page 11 of 25
Table of Contents
Page 16 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/12/2022
Work Order: 22G0561Sample Description:Project Location: Crown Food Mart
Sample ID: 22G0561-04
Field Sample #: SW 04 177
Sample Matrix: Water
Sampled: 7/7/2022 13:00
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 7/13/22 17:04 MFFg/L0.13 7/13/22SW-846 8260D1Diisopropyl Ether (DIPE)
ND 50 7/13/22 17:04 MFFg/L21 7/13/22SW-846 8260D11,4-Dioxane
ND 1.0 7/13/22 17:04 MFFg/L0.21 7/13/22SW-846 8260D1Ethylbenzene
ND 0.60 7/13/22 17:04 MFFg/L0.46 7/13/22SW-846 8260D1Hexachlorobutadiene
ND 10 7/13/22 17:04 MFFg/L1.1 7/13/22SW-846 8260D12-Hexanone (MBK)
ND 1.0 7/13/22 17:04 MFFg/L0.11 7/13/22SW-846 8260D1Isopropylbenzene (Cumene)
ND 1.0 7/13/22 17:04 MFFg/L0.097 7/13/22SW-846 8260D1p-Isopropyltoluene (p-Cymene)
ND 1.0 7/13/22 17:04 MFFg/L0.17 7/13/22SW-846 8260D1Methyl tert-Butyl Ether (MTBE)
ND 5.0 7/13/22 17:04 MFFg/L0.23 7/13/22SW-846 8260D1Methylene Chloride
ND 10 7/13/22 17:04 MFFg/L1.3 7/13/22SW-846 8260D14-Methyl-2-pentanone (MIBK)
ND 2.0 7/13/22 17:04 MFFg/L0.24 7/13/22SW-846 8260D1V-05Naphthalene
ND 1.0 7/13/22 17:04 MFFg/L0.086 7/13/22SW-846 8260D1n-Propylbenzene
ND 1.0 7/13/22 17:04 MFFg/L0.11 7/13/22SW-846 8260D1Styrene
ND 1.0 7/13/22 17:04 MFFg/L0.18 7/13/22SW-846 8260D11,1,1,2-Tetrachloroethane
ND 0.50 7/13/22 17:04 MFFg/L0.13 7/13/22SW-846 8260D11,1,2,2-Tetrachloroethane
ND 1.0 7/13/22 17:04 MFFg/L0.19 7/13/22SW-846 8260D1Tetrachloroethylene
ND 10 7/13/22 17:04 MFFg/L0.49 7/13/22SW-846 8260D1Tetrahydrofuran
ND 1.0 7/13/22 17:04 MFFg/L0.22 7/13/22SW-846 8260D1Toluene
ND 5.0 7/13/22 17:04 MFFg/L0.30 7/13/22SW-846 8260D11,2,3-Trichlorobenzene
ND 1.0 7/13/22 17:04 MFFg/L0.25 7/13/22SW-846 8260D11,2,4-Trichlorobenzene
ND 1.0 7/13/22 17:04 MFFg/L0.21 7/13/22SW-846 8260D11,3,5-Trichlorobenzene
ND 1.0 7/13/22 17:04 MFFg/L0.17 7/13/22SW-846 8260D11,1,1-Trichloroethane
ND 1.0 7/13/22 17:04 MFFg/L0.18 7/13/22SW-846 8260D11,1,2-Trichloroethane
ND 1.0 7/13/22 17:04 MFFg/L0.19 7/13/22SW-846 8260D1Trichloroethylene
ND 2.0 7/13/22 17:04 MFFg/L0.18 7/13/22SW-846 8260D1Trichlorofluoromethane (Freon 11)
ND 2.0 7/13/22 17:04 MFFg/L0.28 7/13/22SW-846 8260D11,2,3-Trichloropropane
ND 1.0 7/13/22 17:04 MFFg/L0.23 7/13/22SW-846 8260D11,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
ND 1.0 7/13/22 17:04 MFFg/L0.20 7/13/22SW-846 8260D11,2,4-Trimethylbenzene
ND 1.0 7/13/22 17:04 MFFg/L0.11 7/13/22SW-846 8260D11,3,5-Trimethylbenzene
ND 2.0 7/13/22 17:04 MFFg/L0.21 7/13/22SW-846 8260D1Vinyl Chloride
ND 2.0 7/13/22 17:04 MFFg/L0.46 7/13/22SW-846 8260D1m+p Xylene
ND 1.0 7/13/22 17:04 MFFg/L0.23 7/13/22SW-846 8260D1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 98.6 7/13/22 17:0470-130
Toluene-d8 99.8 7/13/22 17:0470-130
4-Bromofluorobenzene 97.8 7/13/22 17:0470-130
Page 12 of 25
Table of Contents
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Sample Extraction Data
Prep Method: SW-846 5030B Analytical Method: SW-846 8260D
Lab Number [Field ID]Batch DateInitial [mL]Final [mL]
B312859 07/13/225 5.0022G0561-01 [SW 01 177]
B312859 07/13/225 5.0022G0561-02 [SW 02 177]
B312859 07/13/225 5.0022G0561-03 [SW 03 177]
B312859 07/13/225 5.0022G0561-04 [SW 04 177]
[TOC_1]Sample Preparation Information[TOC]
Page 13 of 25
Table of Contents
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
[TOC_2]Volatile Organic Compounds by GC/MS[TOC]
Batch B312859 - SW-846 5030B
[TOC_3]B312859[TOC]
Blank (B312859-BLK1) Prepared & Analyzed: 07/13/22
Acetone g/L50ND
Acrylonitrile g/L5.0ND
tert-Amyl Methyl Ether (TAME)g/L0.50ND
Benzene g/L1.0ND
Bromobenzene g/L1.0ND
Bromochloromethane g/L1.0ND
Bromodichloromethane g/L0.50ND
Bromoform g/L1.0ND
Bromomethane g/L2.0ND
2-Butanone (MEK)g/L20ND
tert-Butyl Alcohol (TBA)g/L20 V-05ND
n-Butylbenzene g/L1.0ND
sec-Butylbenzene g/L1.0ND
tert-Butylbenzene g/L1.0ND
tert-Butyl Ethyl Ether (TBEE)g/L0.50ND
Carbon Disulfide g/L5.0ND
Carbon Tetrachloride g/L1.0ND
Chlorobenzene g/L1.0ND
Chlorodibromomethane g/L0.50ND
Chloroethane g/L2.0ND
Chloroform g/L2.0ND
Chloromethane g/L2.0ND
2-Chlorotoluene g/L1.0ND
4-Chlorotoluene g/L1.0ND
1,2-Dibromo-3-chloropropane (DBCP)g/L5.0ND
1,2-Dibromoethane (EDB)g/L0.50ND
Dibromomethane g/L1.0ND
1,2-Dichlorobenzene g/L1.0ND
1,3-Dichlorobenzene g/L1.0ND
1,4-Dichlorobenzene g/L1.0ND
trans-1,4-Dichloro-2-butene g/L2.0ND
Dichlorodifluoromethane (Freon 12)g/L2.0ND
1,1-Dichloroethane g/L1.0ND
1,2-Dichloroethane g/L1.0ND
1,1-Dichloroethylene g/L1.0ND
cis-1,2-Dichloroethylene g/L1.0ND
trans-1,2-Dichloroethylene g/L1.0ND
1,2-Dichloropropane g/L1.0ND
1,3-Dichloropropane g/L0.50ND
2,2-Dichloropropane g/L1.0ND
1,1-Dichloropropene g/L2.0ND
cis-1,3-Dichloropropene g/L0.50ND
trans-1,3-Dichloropropene g/L0.50ND
Diethyl Ether g/L2.0ND
Diisopropyl Ether (DIPE)g/L0.50ND
1,4-Dioxane g/L50ND
Ethylbenzene g/L1.0ND
Hexachlorobutadiene g/L0.60ND
2-Hexanone (MBK)g/L10ND
Isopropylbenzene (Cumene)g/L1.0ND
p-Isopropyltoluene (p-Cymene)g/L1.0ND
Methyl tert-Butyl Ether (MTBE)g/L1.0ND
[TOC_1]QC Data[TOC]
Page 14 of 25
Table of Contents
Page 19 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B312859 - SW-846 5030B
Blank (B312859-BLK1) Prepared & Analyzed: 07/13/22
Methylene Chloride g/L5.0ND
4-Methyl-2-pentanone (MIBK)g/L10ND
Naphthalene g/L2.0 V-05ND
n-Propylbenzene g/L1.0ND
Styrene g/L1.0ND
1,1,1,2-Tetrachloroethane g/L1.0ND
1,1,2,2-Tetrachloroethane g/L0.50ND
Tetrachloroethylene g/L0.50ND
Tetrahydrofuran g/L10ND
Toluene g/L1.0ND
1,2,3-Trichlorobenzene g/L5.0ND
1,2,4-Trichlorobenzene g/L1.0ND
1,3,5-Trichlorobenzene g/L1.0ND
1,1,1-Trichloroethane g/L1.0ND
1,1,2-Trichloroethane g/L1.0ND
Trichloroethylene g/L1.0ND
Trichlorofluoromethane (Freon 11)g/L2.0ND
1,2,3-Trichloropropane g/L2.0ND
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon
113)
g/L1.0ND
1,2,4-Trimethylbenzene g/L1.0ND
1,3,5-Trimethylbenzene g/L1.0ND
Vinyl Acetate g/L20ND
Vinyl Chloride g/L2.0ND
m+p Xylene g/L2.0ND
o-Xylene g/L1.0ND
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 97.924.5
g/L 25.0 70-130Surrogate: Toluene-d8 98.424.6
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 95.023.7
LCS (B312859-BS1) Prepared & Analyzed: 07/13/22
Acetone g/L50 100 70-16076.576.5
Acrylonitrile g/L5.0 10.0 70-13078.37.83
tert-Amyl Methyl Ether (TAME)g/L0.50 10.0 70-13085.48.54
Benzene g/L1.0 10.0 70-13010110.1
Bromobenzene g/L1.0 10.0 70-13010310.3
Bromochloromethane g/L1.0 10.0 70-13011211.2
Bromodichloromethane g/L0.50 10.0 70-13011011.0
Bromoform g/L1.0 10.0 70-13010110.1
Bromomethane g/L2.0 10.0 40-16011311.3
2-Butanone (MEK)g/L20 100 40-16077.477.4
tert-Butyl Alcohol (TBA)g/L20 100 V-0540-16070.770.7
n-Butylbenzene g/L1.0 10.0 70-13086.18.61
sec-Butylbenzene g/L1.0 10.0 70-13010010.0
tert-Butylbenzene g/L1.0 10.0 70-13010410.4
tert-Butyl Ethyl Ether (TBEE)g/L0.50 10.0 70-13088.88.88
Carbon Disulfide g/L5.0 100 70-130105105
Carbon Tetrachloride g/L1.0 10.0 70-13011111.1
Chlorobenzene g/L1.0 10.0 70-13010910.9
Chlorodibromomethane g/L0.50 10.0 70-13010810.8
Chloroethane g/L2.0 10.0 70-13011711.7
Chloroform g/L2.0 10.0 70-13010410.4
Chloromethane g/L2.0 10.0 V-2040-16012612.6
Page 15 of 25
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Page 20 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B312859 - SW-846 5030B
LCS (B312859-BS1) Prepared & Analyzed: 07/13/22
2-Chlorotoluene g/L1.0 10.0 70-13010410.4
4-Chlorotoluene g/L1.0 10.0 70-13010410.4
1,2-Dibromo-3-chloropropane (DBCP)g/L5.0 10.0 70-13078.27.82
1,2-Dibromoethane (EDB)g/L0.50 10.0 70-13010410.4
Dibromomethane g/L1.0 10.0 70-13010410.4
1,2-Dichlorobenzene g/L1.0 10.0 70-13010510.5
1,3-Dichlorobenzene g/L1.0 10.0 70-13010610.6
1,4-Dichlorobenzene g/L1.0 10.0 70-13010110.1
trans-1,4-Dichloro-2-butene g/L2.0 10.0 70-13082.78.27
Dichlorodifluoromethane (Freon 12)g/L2.0 10.0 40-16010710.7
1,1-Dichloroethane g/L1.0 10.0 70-13010310.3
1,2-Dichloroethane g/L1.0 10.0 70-13010810.8
1,1-Dichloroethylene g/L1.0 10.0 70-13010610.6
cis-1,2-Dichloroethylene g/L1.0 10.0 70-13010510.5
trans-1,2-Dichloroethylene g/L1.0 10.0 70-13099.29.92
1,2-Dichloropropane g/L1.0 10.0 70-13010710.7
1,3-Dichloropropane g/L0.50 10.0 70-13010410.4
2,2-Dichloropropane g/L1.0 10.0 40-13010310.3
1,1-Dichloropropene g/L2.0 10.0 70-13010410.4
cis-1,3-Dichloropropene g/L0.50 10.0 70-13010410.4
trans-1,3-Dichloropropene g/L0.50 10.0 70-13094.19.41
Diethyl Ether g/L2.0 10.0 70-13095.09.50
Diisopropyl Ether (DIPE)g/L0.50 10.0 70-13010410.4
1,4-Dioxane g/L50 100 40-13072.172.1
Ethylbenzene g/L1.0 10.0 70-13010510.5
Hexachlorobutadiene g/L0.60 10.0 70-13011211.2
2-Hexanone (MBK)g/L10 100 70-16078.078.0
Isopropylbenzene (Cumene)g/L1.0 10.0 70-13010710.7
p-Isopropyltoluene (p-Cymene)g/L1.0 10.0 70-13093.69.36
Methyl tert-Butyl Ether (MTBE)g/L1.0 10.0 70-13096.59.65
Methylene Chloride g/L5.0 10.0 70-13099.39.93
4-Methyl-2-pentanone (MIBK)g/L10 100 70-16088.188.1
Naphthalene g/L2.0 10.0 V-0540-13056.75.67
n-Propylbenzene g/L1.0 10.0 70-13010110.1
Styrene g/L1.0 10.0 70-13010410.4
1,1,1,2-Tetrachloroethane g/L1.0 10.0 70-13011011.0
1,1,2,2-Tetrachloroethane g/L0.50 10.0 70-13098.19.81
Tetrachloroethylene g/L0.50 10.0 70-13011811.8
Tetrahydrofuran g/L10 10.0 J70-13086.18.61
Toluene g/L1.0 10.0 70-13010710.7
1,2,3-Trichlorobenzene g/L5.0 10.0 70-13075.57.55
1,2,4-Trichlorobenzene g/L1.0 10.0 70-13078.27.82
1,3,5-Trichlorobenzene g/L1.0 10.0 70-13094.59.45
1,1,1-Trichloroethane g/L1.0 10.0 70-13010810.8
1,1,2-Trichloroethane g/L1.0 10.0 70-13010610.6
Trichloroethylene g/L1.0 10.0 70-13011211.2
Trichlorofluoromethane (Freon 11)g/L2.0 10.0 70-13010410.4
1,2,3-Trichloropropane g/L2.0 10.0 70-13087.88.78
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon
113)
g/L1.0 10.0 70-13011511.5
1,2,4-Trimethylbenzene g/L1.0 10.0 70-13091.19.11
1,3,5-Trimethylbenzene g/L1.0 10.0 70-13010110.1
Page 16 of 25
Table of Contents
Page 21 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B312859 - SW-846 5030B
LCS (B312859-BS1) Prepared & Analyzed: 07/13/22
Vinyl Acetate g/L20 100 70-13093.693.6
Vinyl Chloride g/L2.0 10.0 40-16011311.3
m+p Xylene g/L2.0 20.0 70-13010721.4
o-Xylene g/L1.0 10.0 70-13011011.0
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 95.523.9
g/L 25.0 70-130Surrogate: Toluene-d8 10125.1
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 98.224.5
LCS Dup (B312859-BSD1) Prepared & Analyzed: 07/13/22
Acetone g/L50 100 2570-16078.8 2.9678.8
Acrylonitrile g/L5.0 10.0 2570-13083.7 6.678.37
tert-Amyl Methyl Ether (TAME)g/L0.50 10.0 2570-13093.2 8.739.32
Benzene g/L1.0 10.0 2570-130100 0.59710.0
Bromobenzene g/L1.0 10.0 2570-130100 2.4710.0
Bromochloromethane g/L1.0 10.0 2570-130111 1.0811.1
Bromodichloromethane g/L0.50 10.0 2570-130110 0.45411.0
Bromoform g/L1.0 10.0 2570-130107 5.5710.7
Bromomethane g/L2.0 10.0 2540-160122 7.4112.2
2-Butanone (MEK)g/L20 100 2540-16079.7 2.8579.7
tert-Butyl Alcohol (TBA)g/L20 100 25 V-0540-16074.4 5.0674.4
n-Butylbenzene g/L1.0 10.0 2570-13091.0 5.539.10
sec-Butylbenzene g/L1.0 10.0 2570-130101 0.59810.1
tert-Butylbenzene g/L1.0 10.0 2570-130104 0.48010.4
tert-Butyl Ethyl Ether (TBEE)g/L0.50 10.0 2570-13091.1 2.569.11
Carbon Disulfide g/L5.0 100 2570-130106 0.969106
Carbon Tetrachloride g/L1.0 10.0 2570-130111 0.090411.1
Chlorobenzene g/L1.0 10.0 2570-130110 1.1811.0
Chlorodibromomethane g/L0.50 10.0 2570-130107 0.74310.7
Chloroethane g/L2.0 10.0 2570-130113 3.4811.3
Chloroform g/L2.0 10.0 2570-130104 0.38410.4
Chloromethane g/L2.0 10.0 25 V-2040-160138 8.8013.8
2-Chlorotoluene g/L1.0 10.0 2570-130104 0.38510.4
4-Chlorotoluene g/L1.0 10.0 2570-130101 2.1510.1
1,2-Dibromo-3-chloropropane (DBCP)g/L5.0 10.0 2570-13086.1 9.628.61
1,2-Dibromoethane (EDB)g/L0.50 10.0 2570-130102 1.5610.2
Dibromomethane g/L1.0 10.0 2570-13099.9 3.839.99
1,2-Dichlorobenzene g/L1.0 10.0 2570-130108 2.7210.8
1,3-Dichlorobenzene g/L1.0 10.0 2570-130104 1.5310.4
1,4-Dichlorobenzene g/L1.0 10.0 2570-130106 4.8410.6
trans-1,4-Dichloro-2-butene g/L2.0 10.0 2570-13080.9 2.208.09
Dichlorodifluoromethane (Freon 12)g/L2.0 10.0 2540-160111 3.6811.1
1,1-Dichloroethane g/L1.0 10.0 2570-130101 1.6710.1
1,2-Dichloroethane g/L1.0 10.0 2570-130109 0.83010.9
1,1-Dichloroethylene g/L1.0 10.0 2570-130107 1.0410.7
cis-1,2-Dichloroethylene g/L1.0 10.0 2570-130106 1.5210.6
trans-1,2-Dichloroethylene g/L1.0 10.0 2570-130104 4.5310.4
1,2-Dichloropropane g/L1.0 10.0 2570-130107 0.18710.7
1,3-Dichloropropane g/L0.50 10.0 2570-130103 0.67710.3
2,2-Dichloropropane g/L1.0 10.0 2540-130104 1.3510.4
1,1-Dichloropropene g/L2.0 10.0 2570-130108 4.4310.8
cis-1,3-Dichloropropene g/L0.50 10.0 2570-130104 0.67310.4
trans-1,3-Dichloropropene g/L0.50 10.0 2570-13094.2 0.1069.42
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Table of Contents
Page 22 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B312859 - SW-846 5030B
LCS Dup (B312859-BSD1) Prepared & Analyzed: 07/13/22
Diethyl Ether g/L2.0 10.0 2570-13094.9 0.1059.49
Diisopropyl Ether (DIPE)g/L0.50 10.0 2570-130101 3.0310.1
1,4-Dioxane g/L50 100 5040-13080.4 10.980.4
Ethylbenzene g/L1.0 10.0 2570-130105 0.47610.5
Hexachlorobutadiene g/L0.60 10.0 2570-130115 2.5611.5
2-Hexanone (MBK)g/L10 100 2570-16083.0 6.2983.0
Isopropylbenzene (Cumene)g/L1.0 10.0 2570-130109 1.9510.9
p-Isopropyltoluene (p-Cymene)g/L1.0 10.0 2570-13094.3 0.7459.43
Methyl tert-Butyl Ether (MTBE)g/L1.0 10.0 2570-130102 5.4410.2
Methylene Chloride g/L5.0 10.0 2570-13099.6 0.3029.96
4-Methyl-2-pentanone (MIBK)g/L10 100 2570-16090.6 2.8190.6
Naphthalene g/L2.0 10.0 25 V-0540-13057.1 0.7035.71
n-Propylbenzene g/L1.0 10.0 2570-130103 1.8610.3
Styrene g/L1.0 10.0 2570-130106 1.7110.6
1,1,1,2-Tetrachloroethane g/L1.0 10.0 2570-130111 1.0811.1
1,1,2,2-Tetrachloroethane g/L0.50 10.0 2570-13099.0 0.9139.90
Tetrachloroethylene g/L0.50 10.0 2570-130118 0.16911.8
Tetrahydrofuran g/L10 10.0 25 J70-13093.7 8.459.37
Toluene g/L1.0 10.0 2570-130108 1.1210.8
1,2,3-Trichlorobenzene g/L5.0 10.0 2570-13079.6 5.297.96
1,2,4-Trichlorobenzene g/L1.0 10.0 2570-13080.9 3.398.09
1,3,5-Trichlorobenzene g/L1.0 10.0 2570-13096.8 2.409.68
1,1,1-Trichloroethane g/L1.0 10.0 2570-130110 1.8311.0
1,1,2-Trichloroethane g/L1.0 10.0 2570-130104 2.1810.4
Trichloroethylene g/L1.0 10.0 2570-130112 0.26711.2
Trichlorofluoromethane (Freon 11)g/L2.0 10.0 2570-130107 2.7510.7
1,2,3-Trichloropropane g/L2.0 10.0 2570-13091.5 4.139.15
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon
113)
g/L1.0 10.0 2570-130112 2.2911.2
1,2,4-Trimethylbenzene g/L1.0 10.0 2570-13091.3 0.2199.13
1,3,5-Trimethylbenzene g/L1.0 10.0 2570-130101 0.0010.1
Vinyl Acetate g/L20 100 2570-13092.0 1.7192.0
Vinyl Chloride g/L2.0 10.0 2540-160114 0.96511.4
m+p Xylene g/L2.0 20.0 2570-130106 1.5021.1
o-Xylene g/L1.0 10.0 2570-130108 1.5610.8
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 95.223.8
g/L 25.0 70-130Surrogate: Toluene-d8 10025.1
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 99.925.0
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Table of Contents
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
FLAG/QUALIFIER SUMMARY
*QC result is outside of established limits.
Wide recovery limits established for difficult compound.
Wide RPD limits established for difficult compound.
#Data exceeded client recommended or regulatory level
Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the
calculation which have not been rounded.
No results have been blank subtracted unless specified in the case narrative section.
RL Reporting Limit is at the level of quantitation (LOQ)
DL Detection Limit is the lower limit of detection determined by the MDL study
MCL Maximum Contaminant Level
ND Not Detected
Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated
concentration (CLP J-Flag).
J
Continuing calibration verification (CCV) did not meet method specifications and was biased on the low side for
this compound.
V-05
Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side.
Data validation is not affected since sample result was "not detected" for this compound.
V-20
[TOC_1]Flag/Qualifier Summary[TOC]
Page 19 of 25
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
SW-846 8260D in Water
NCAcetone
NCAcrylonitrile
NCtert-Amyl Methyl Ether (TAME)
NCBenzene
NCBromobenzene
NCBromochloromethane
NCBromodichloromethane
NCBromoform
NCBromomethane
NC2-Butanone (MEK)
NCtert-Butyl Alcohol (TBA)
NCn-Butylbenzene
NCsec-Butylbenzene
NCtert-Butylbenzene
NCtert-Butyl Ethyl Ether (TBEE)
NCCarbon Disulfide
NCCarbon Tetrachloride
NCChlorobenzene
NCChlorodibromomethane
NCChloroethane
NCChloroform
NCChloromethane
NC2-Chlorotoluene
NC4-Chlorotoluene
NC1,2-Dibromo-3-chloropropane (DBCP)
NC1,2-Dibromoethane (EDB)
NCDibromomethane
NC1,2-Dichlorobenzene
NC1,3-Dichlorobenzene
NC1,4-Dichlorobenzene
NCtrans-1,4-Dichloro-2-butene
NCDichlorodifluoromethane (Freon 12)
NC1,1-Dichloroethane
NC1,2-Dichloroethane
NC1,1-Dichloroethylene
NCcis-1,2-Dichloroethylene
NCtrans-1,2-Dichloroethylene
NC1,2-Dichloropropane
NC1,3-Dichloropropane
NC2,2-Dichloropropane
NC1,1-Dichloropropene
NCcis-1,3-Dichloropropene
NCtrans-1,3-Dichloropropene
NCDiethyl Ether
NCDiisopropyl Ether (DIPE)
NC1,4-Dioxane
NCEthylbenzene
[TOC_1]Certifications[TOC]
Page 20 of 25
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
SW-846 8260D in Water
NCHexachlorobutadiene
NC2-Hexanone (MBK)
NCIsopropylbenzene (Cumene)
NCp-Isopropyltoluene (p-Cymene)
NCMethyl tert-Butyl Ether (MTBE)
NCMethylene Chloride
NC4-Methyl-2-pentanone (MIBK)
NCNaphthalene
NCn-Propylbenzene
NCStyrene
NC1,1,1,2-Tetrachloroethane
NC1,1,2,2-Tetrachloroethane
NCTetrachloroethylene
NCTetrahydrofuran
NCToluene
NC1,2,3-Trichlorobenzene
NC1,2,4-Trichlorobenzene
NC1,3,5-Trichlorobenzene
NC1,1,1-Trichloroethane
NC1,1,2-Trichloroethane
NCTrichloroethylene
NCTrichlorofluoromethane (Freon 11)
NC1,2,3-Trichloropropane
NC1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)
NC1,2,4-Trimethylbenzene
NC1,3,5-Trimethylbenzene
NCVinyl Chloride
NCm+p Xylene
NCo-Xylene
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Con-Test, a Pace Environmental Laboratory, operates under the following certifications and accreditations:
Code Description Number Expires
100033AIHA-LAP, LLC - ISO17025:2017AIHA 03/1/2024
M-MA100Massachusetts DEPMA 06/30/2023
PH-0165Connecticut Department of Publilc HealthCT 12/31/2022
10899 NELAPNew York State Department of HealthNY 04/1/2023
2516 NELAPNew Hampshire Environmental LabNH-S 02/5/2023
LAO00373Rhode Island Department of HealthRI 12/30/2022
652North Carolina Div. of Water QualityNC 12/31/2022
MA007 NELAPNew Jersey DEPNJ 06/30/2023
E871027 NELAPFlorida Department of HealthFL 06/30/2023
LL720741Vermont Department of Health Lead LaboratoryVT 07/30/2023
MA00100State of MaineME 06/9/2023
460217Commonwealth of VirginiaVA 12/14/2022
2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2022
VT-255716Vermont Department of Health Drinking WaterVT-DW 06/12/2023
25703North Carolina Department of HealthNC-DW 07/31/2022
68-05812Commonwealth of Pennsylvania DEPPA 06/30/2023
9100Dept. of Env, Great Lakes, and EnergyMI 09/6/2022
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#=CL#
July 30, 2022
LIMS USE: FR - ROBERT MARTIN
LIMS OBJECT ID: 92616250
92616250
Project:
Pace Project No.:
RE:
Mr. Robert Martin
Martin and Slagle
24 Lookout Terrace
Black Mountain, NC 28711
Crown Food Mart 7/21
Dear Mr. Martin:
Enclosed are the analytical results for sample(s) received by the laboratory on July 22, 2022. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lorri Patton
[e-mail]
Project Manager
1(828)254-7176
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 1 of 36
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92616250
Crown Food Mart 7/21
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 2 of 36
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92616250
Crown Food Mart 7/21
Lab ID Sample ID Matrix Date Collected Date Received
92616250001 EF-13R Water 07/21/22 11:00 07/22/22 10:20
92616250002 SW 01 178 Water 07/21/22 11:00 07/22/22 10:20
92616250003 SW 02 178 Water 07/21/22 11:00 07/22/22 10:20
92616250004 SW 03 178 Water 07/21/22 11:00 07/22/22 10:20
92616250005 SW 04 178 Water 07/21/22 11:00 07/22/22 10:20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 3 of 36
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92616250
Crown Food Mart 7/21
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92616250001 EF-13R SM 2540D-2015 1 PASI-AJMH1
PASI-A = Pace Analytical Services - Asheville
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 4 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92616250
Crown Food Mart 7/21
Sample:EF-13R Lab ID:92616250001 Collected:07/21/22 11:00 Received:07/22/22 10:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 2540D-2015
Pace Analytical Services - Asheville
2540D Total Suspended Solids
Total Suspended Solids 8.8 mg/L 07/27/22 12:306.2 6.2 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/30/2022 05:49 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 5 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92616250
Crown Food Mart 7/21
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
712924
SM 2540D-2015
SM 2540D-2015
2540D Total Suspended Solids
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92616250001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3717353
Associated Lab Samples:92616250001
Matrix:Water
AnalyzedMDL
Total Suspended Solids mg/L ND 2.5 07/27/22 12:282.5
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3717354LABORATORY CONTROL SAMPLE:
LCSSpike
Total Suspended Solids mg/L 248251 99 90-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92615643005
3718535SAMPLE DUPLICATE:
Total Suspended Solids mg/L 37.7 2 2536.9
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92616170001
3718539SAMPLE DUPLICATE:
Total Suspended Solids mg/L 84.6 22 2567.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/30/2022 05:49 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 6 of 36
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92616250
Crown Food Mart 7/21
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/30/2022 05:49 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 7 of 36
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92616250
Crown Food Mart 7/21
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92616250001 712924EF-13R SM 2540D-2015
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/30/2022 05:49 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 8 of 36
Page 9 of 36
Page 10 of 36
Page 11 of 36
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
July 29, 2022
Lorri Patton
Pace Analytical Services - NC
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Project Location: Crown Food Mart 7/21
Client Job Number:
Project Number: 92616250
Laboratory Work Order Number: 22G1343
Enclosed are results of analyses for samples as received by the laboratory on July 23, 2022. If you have any questions
concerning this report, please feel free to contact me.
Sincerely,
Kerry K. McGee
Project Manager
Page 1 of 25
Table of Contents
Page 12 of 36
Table of Contents
Sample Summary 3
Case Narrative 4
Sample Results 5
22G1343-01 5
22G1343-02 7
22G1343-03 9
22G1343-04 11
Sample Preparation Information 13
QC Data 14
Volatile Organic Compounds by GC/MS 14
B313711 14
Flag/Qualifier Summary 19
Certifications 20
Chain of Custody/Sample Receipt 23
Page 2 of 25
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Page 13 of 36
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYTICAL SUMMARY
7/29/2022
Pace Analytical Services - NC
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
ATTN: Lorri Patton
92616250
22G1343
The results of analyses performed on the following samples submitted to CON-TEST, a Pace Analytical Laboratory, are found in this report.
PROJECT LOCATION:
PURCHASE ORDER NUMBER:
PROJECT NUMBER:
REPORT DATE:
WORK ORDER NUMBER:
FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB
Crown Food Mart 7/21
SW 01 178 22G1343-01 Water SW-846 8260D
SW 02 178 22G1343-02 Water SW-846 8260D
SW 03 178 22G1343-03 Water SW-846 8260D
SW 04 178 22G1343-04 Water SW-846 8260D
[TOC_1]Sample Summary[TOC]
Page 3 of 25
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CASE NARRATIVE SUMMARY
All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report.
[TOC_1]Case Narrative[TOC]
SW-846 8260D
Qualifications:
Either laboratory fortified blank/laboratory control sample or duplicate recovery is outside of control limits, but the other is within limits. RPD
between the two LFB/LCS results is within method specified criteria.
Analyte & Samples(s) Qualified:
L-07
Chloromethane
B313711-BS1
Continuing calibration verification (CCV) did not meet method specifications and was biased on the low side for this compound.
Analyte & Samples(s) Qualified:
V-05
1,2-Dibromo-3-chloropropane (DBCP)
22G1343-01[SW 01 178], 22G1343-02[SW 02 178], 22G1343-03[SW 03 178], 22G1343-04[SW 04 178], B313711-BLK1, B313711-BS1, B313711-BSD1, S074408-CCV1
Chloromethane
22G1343-01[SW 01 178], 22G1343-02[SW 02 178], 22G1343-03[SW 03 178], 22G1343-04[SW 04 178], B313711-BLK1, B313711-BS1, B313711-BSD1, S074408-CCV1
Naphthalene
22G1343-01[SW 01 178], 22G1343-02[SW 02 178], 22G1343-03[SW 03 178], 22G1343-04[SW 04 178], B313711-BLK1, B313711-BS1, B313711-BSD1, S074408-CCV1
Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side. Data validation is not affected
since sample result was "not detected" for this compound.
Analyte & Samples(s) Qualified:
V-20
Bromochloromethane
B313711-BS1, B313711-BSD1, S074408-CCV1
Bromomethane
B313711-BS1, B313711-BSD1, S074408-CCV1
Initial calibration verification (ICV) did not meet method specifications and was biased on the low side for this compound. Reported result is
estimated.
Analyte & Samples(s) Qualified:
V-34
Bromomethane
22G1343-01[SW 01 178], 22G1343-02[SW 02 178], 22G1343-03[SW 03 178], 22G1343-04[SW 04 178], B313711-BLK1, B313711-BS1, B313711-BSD1, S074408-CCV1
Chloromethane
22G1343-01[SW 01 178], 22G1343-02[SW 02 178], 22G1343-03[SW 03 178], 22G1343-04[SW 04 178], B313711-BLK1, B313711-BS1, B313711-BSD1, S074408-CCV1
The results of analyses reported only relate to samples submitted to Con-Test, a Pace Analytical Laboratory, for testing.
I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed
in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the
best of my knowledge and belief, accurate and complete.
Lisa A. Worthington
Technical Representative
Page 4 of 25
Table of Contents
Page 15 of 36
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/23/2022
Work Order: 22G1343Sample Description:Project Location: Crown Food Mart 7/21
Sample ID: 22G1343-01
Field Sample #: SW 01 178
Sample Matrix: Water
Sampled: 7/21/2022 11:00
[TOC_2]22G1343-01[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 7/25/22 20:05 LBDg/L2.0 7/25/22SW-846 8260D1Acetone
ND 5.0 7/25/22 20:05 LBDg/L0.55 7/25/22SW-846 8260D1Acrylonitrile
ND 0.50 7/25/22 20:05 LBDg/L0.14 7/25/22SW-846 8260D1tert-Amyl Methyl Ether (TAME)
ND 1.0 7/25/22 20:05 LBDg/L0.20 7/25/22SW-846 8260D1Benzene
ND 1.0 7/25/22 20:05 LBDg/L0.15 7/25/22SW-846 8260D1Bromobenzene
ND 1.0 7/25/22 20:05 LBDg/L0.31 7/25/22SW-846 8260D1Bromochloromethane
ND 0.50 7/25/22 20:05 LBDg/L0.18 7/25/22SW-846 8260D1Bromodichloromethane
ND 1.0 7/25/22 20:05 LBDg/L0.38 7/25/22SW-846 8260D1Bromoform
ND 5.0 7/25/22 20:05 LBDg/L1.5 7/25/22SW-846 8260D1V-34Bromomethane
ND 20 7/25/22 20:05 LBDg/L1.6 7/25/22SW-846 8260D12-Butanone (MEK)
ND 20 7/25/22 20:05 LBDg/L4.7 7/25/22SW-846 8260D1tert-Butyl Alcohol (TBA)
ND 1.0 7/25/22 20:05 LBDg/L0.15 7/25/22SW-846 8260D1n-Butylbenzene
ND 1.0 7/25/22 20:05 LBDg/L0.11 7/25/22SW-846 8260D1sec-Butylbenzene
ND 1.0 7/25/22 20:05 LBDg/L0.13 7/25/22SW-846 8260D1tert-Butylbenzene
ND 0.50 7/25/22 20:05 LBDg/L0.15 7/25/22SW-846 8260D1tert-Butyl Ethyl Ether (TBEE)
ND 5.0 7/25/22 20:05 LBDg/L1.4 7/25/22SW-846 8260D1Carbon Disulfide
ND 1.0 7/25/22 20:05 LBDg/L0.16 7/25/22SW-846 8260D1Carbon Tetrachloride
ND 1.0 7/25/22 20:05 LBDg/L0.11 7/25/22SW-846 8260D1Chlorobenzene
ND 0.50 7/25/22 20:05 LBDg/L0.22 7/25/22SW-846 8260D1Chlorodibromomethane
ND 2.0 7/25/22 20:05 LBDg/L0.32 7/25/22SW-846 8260D1Chloroethane
ND 2.0 7/25/22 20:05 LBDg/L0.17 7/25/22SW-846 8260D1Chloroform
ND 2.0 7/25/22 20:05 LBDg/L0.52 7/25/22SW-846 8260D1V-05, V-34Chloromethane
ND 1.0 7/25/22 20:05 LBDg/L0.11 7/25/22SW-846 8260D12-Chlorotoluene
ND 1.0 7/25/22 20:05 LBDg/L0.12 7/25/22SW-846 8260D14-Chlorotoluene
ND 5.0 7/25/22 20:05 LBDg/L0.80 7/25/22SW-846 8260D1V-051,2-Dibromo-3-chloropropane (DBCP)
ND 0.50 7/25/22 20:05 LBDg/L0.17 7/25/22SW-846 8260D11,2-Dibromoethane (EDB)
ND 1.0 7/25/22 20:05 LBDg/L0.35 7/25/22SW-846 8260D1Dibromomethane
ND 1.0 7/25/22 20:05 LBDg/L0.12 7/25/22SW-846 8260D11,2-Dichlorobenzene
ND 1.0 7/25/22 20:05 LBDg/L0.12 7/25/22SW-846 8260D11,3-Dichlorobenzene
ND 1.0 7/25/22 20:05 LBDg/L0.13 7/25/22SW-846 8260D11,4-Dichlorobenzene
ND 2.0 7/25/22 20:05 LBDg/L1.6 7/25/22SW-846 8260D1trans-1,4-Dichloro-2-butene
ND 2.0 7/25/22 20:05 LBDg/L0.19 7/25/22SW-846 8260D1Dichlorodifluoromethane (Freon 12)
ND 1.0 7/25/22 20:05 LBDg/L0.14 7/25/22SW-846 8260D11,1-Dichloroethane
ND 1.0 7/25/22 20:05 LBDg/L0.31 7/25/22SW-846 8260D11,2-Dichloroethane
ND 1.0 7/25/22 20:05 LBDg/L0.14 7/25/22SW-846 8260D11,1-Dichloroethylene
ND 1.0 7/25/22 20:05 LBDg/L0.15 7/25/22SW-846 8260D1cis-1,2-Dichloroethylene
ND 1.0 7/25/22 20:05 LBDg/L0.17 7/25/22SW-846 8260D1trans-1,2-Dichloroethylene
ND 1.0 7/25/22 20:05 LBDg/L0.18 7/25/22SW-846 8260D11,2-Dichloropropane
ND 0.50 7/25/22 20:05 LBDg/L0.13 7/25/22SW-846 8260D11,3-Dichloropropane
ND 1.0 7/25/22 20:05 LBDg/L0.33 7/25/22SW-846 8260D12,2-Dichloropropane
ND 2.0 7/25/22 20:05 LBDg/L0.15 7/25/22SW-846 8260D11,1-Dichloropropene
ND 0.50 7/25/22 20:05 LBDg/L0.16 7/25/22SW-846 8260D1cis-1,3-Dichloropropene
ND 0.50 7/25/22 20:05 LBDg/L0.17 7/25/22SW-846 8260D1trans-1,3-Dichloropropene
ND 2.0 7/25/22 20:05 LBDg/L0.18 7/25/22SW-846 8260D1Diethyl Ether
[TOC_1]Sample Results[TOC]
Page 5 of 25
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Page 16 of 36
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/23/2022
Work Order: 22G1343Sample Description:Project Location: Crown Food Mart 7/21
Sample ID: 22G1343-01
Field Sample #: SW 01 178
Sample Matrix: Water
Sampled: 7/21/2022 11:00
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 7/25/22 20:05 LBDg/L0.13 7/25/22SW-846 8260D1Diisopropyl Ether (DIPE)
ND 50 7/25/22 20:05 LBDg/L21 7/25/22SW-846 8260D11,4-Dioxane
ND 1.0 7/25/22 20:05 LBDg/L0.21 7/25/22SW-846 8260D1Ethylbenzene
ND 0.60 7/25/22 20:05 LBDg/L0.46 7/25/22SW-846 8260D1Hexachlorobutadiene
ND 10 7/25/22 20:05 LBDg/L1.1 7/25/22SW-846 8260D12-Hexanone (MBK)
ND 1.0 7/25/22 20:05 LBDg/L0.11 7/25/22SW-846 8260D1Isopropylbenzene (Cumene)
ND 1.0 7/25/22 20:05 LBDg/L0.097 7/25/22SW-846 8260D1p-Isopropyltoluene (p-Cymene)
ND 1.0 7/25/22 20:05 LBDg/L0.17 7/25/22SW-846 8260D1Methyl tert-Butyl Ether (MTBE)
ND 5.0 7/25/22 20:05 LBDg/L0.23 7/25/22SW-846 8260D1Methylene Chloride
ND 10 7/25/22 20:05 LBDg/L1.3 7/25/22SW-846 8260D14-Methyl-2-pentanone (MIBK)
ND 2.0 7/25/22 20:05 LBDg/L0.24 7/25/22SW-846 8260D1V-05Naphthalene
ND 1.0 7/25/22 20:05 LBDg/L0.086 7/25/22SW-846 8260D1n-Propylbenzene
ND 1.0 7/25/22 20:05 LBDg/L0.11 7/25/22SW-846 8260D1Styrene
ND 1.0 7/25/22 20:05 LBDg/L0.18 7/25/22SW-846 8260D11,1,1,2-Tetrachloroethane
ND 0.50 7/25/22 20:05 LBDg/L0.13 7/25/22SW-846 8260D11,1,2,2-Tetrachloroethane
ND 1.0 7/25/22 20:05 LBDg/L0.19 7/25/22SW-846 8260D1Tetrachloroethylene
ND 10 7/25/22 20:05 LBDg/L0.49 7/25/22SW-846 8260D1Tetrahydrofuran
ND 1.0 7/25/22 20:05 LBDg/L0.22 7/25/22SW-846 8260D1Toluene
ND 5.0 7/25/22 20:05 LBDg/L0.30 7/25/22SW-846 8260D11,2,3-Trichlorobenzene
ND 1.0 7/25/22 20:05 LBDg/L0.25 7/25/22SW-846 8260D11,2,4-Trichlorobenzene
ND 1.0 7/25/22 20:05 LBDg/L0.21 7/25/22SW-846 8260D11,3,5-Trichlorobenzene
ND 1.0 7/25/22 20:05 LBDg/L0.17 7/25/22SW-846 8260D11,1,1-Trichloroethane
ND 1.0 7/25/22 20:05 LBDg/L0.18 7/25/22SW-846 8260D11,1,2-Trichloroethane
ND 1.0 7/25/22 20:05 LBDg/L0.19 7/25/22SW-846 8260D1Trichloroethylene
ND 2.0 7/25/22 20:05 LBDg/L0.18 7/25/22SW-846 8260D1Trichlorofluoromethane (Freon 11)
ND 2.0 7/25/22 20:05 LBDg/L0.28 7/25/22SW-846 8260D11,2,3-Trichloropropane
ND 1.0 7/25/22 20:05 LBDg/L0.23 7/25/22SW-846 8260D11,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
ND 1.0 7/25/22 20:05 LBDg/L0.20 7/25/22SW-846 8260D11,2,4-Trimethylbenzene
ND 1.0 7/25/22 20:05 LBDg/L0.11 7/25/22SW-846 8260D11,3,5-Trimethylbenzene
ND 2.0 7/25/22 20:05 LBDg/L0.21 7/25/22SW-846 8260D1Vinyl Chloride
ND 2.0 7/25/22 20:05 LBDg/L0.46 7/25/22SW-846 8260D1m+p Xylene
ND 1.0 7/25/22 20:05 LBDg/L0.23 7/25/22SW-846 8260D1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 82.0 7/25/22 20:0570-130
Toluene-d8 95.9 7/25/22 20:0570-130
4-Bromofluorobenzene 100 7/25/22 20:0570-130
Page 6 of 25
Table of Contents
Page 17 of 36
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/23/2022
Work Order: 22G1343Sample Description:Project Location: Crown Food Mart 7/21
Sample ID: 22G1343-02
Field Sample #: SW 02 178
Sample Matrix: Water
Sampled: 7/21/2022 11:00
[TOC_2]22G1343-02[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 7/25/22 20:31 LBDg/L2.0 7/25/22SW-846 8260D1Acetone
ND 5.0 7/25/22 20:31 LBDg/L0.55 7/25/22SW-846 8260D1Acrylonitrile
ND 0.50 7/25/22 20:31 LBDg/L0.14 7/25/22SW-846 8260D1tert-Amyl Methyl Ether (TAME)
ND 1.0 7/25/22 20:31 LBDg/L0.20 7/25/22SW-846 8260D1Benzene
ND 1.0 7/25/22 20:31 LBDg/L0.15 7/25/22SW-846 8260D1Bromobenzene
ND 1.0 7/25/22 20:31 LBDg/L0.31 7/25/22SW-846 8260D1Bromochloromethane
ND 0.50 7/25/22 20:31 LBDg/L0.18 7/25/22SW-846 8260D1Bromodichloromethane
ND 1.0 7/25/22 20:31 LBDg/L0.38 7/25/22SW-846 8260D1Bromoform
ND 5.0 7/25/22 20:31 LBDg/L1.5 7/25/22SW-846 8260D1V-34Bromomethane
ND 20 7/25/22 20:31 LBDg/L1.6 7/25/22SW-846 8260D12-Butanone (MEK)
ND 20 7/25/22 20:31 LBDg/L4.7 7/25/22SW-846 8260D1tert-Butyl Alcohol (TBA)
ND 1.0 7/25/22 20:31 LBDg/L0.15 7/25/22SW-846 8260D1n-Butylbenzene
ND 1.0 7/25/22 20:31 LBDg/L0.11 7/25/22SW-846 8260D1sec-Butylbenzene
ND 1.0 7/25/22 20:31 LBDg/L0.13 7/25/22SW-846 8260D1tert-Butylbenzene
ND 0.50 7/25/22 20:31 LBDg/L0.15 7/25/22SW-846 8260D1tert-Butyl Ethyl Ether (TBEE)
ND 5.0 7/25/22 20:31 LBDg/L1.4 7/25/22SW-846 8260D1Carbon Disulfide
ND 1.0 7/25/22 20:31 LBDg/L0.16 7/25/22SW-846 8260D1Carbon Tetrachloride
ND 1.0 7/25/22 20:31 LBDg/L0.11 7/25/22SW-846 8260D1Chlorobenzene
ND 0.50 7/25/22 20:31 LBDg/L0.22 7/25/22SW-846 8260D1Chlorodibromomethane
ND 2.0 7/25/22 20:31 LBDg/L0.32 7/25/22SW-846 8260D1Chloroethane
ND 2.0 7/25/22 20:31 LBDg/L0.17 7/25/22SW-846 8260D1Chloroform
ND 2.0 7/25/22 20:31 LBDg/L0.52 7/25/22SW-846 8260D1V-05, V-34Chloromethane
ND 1.0 7/25/22 20:31 LBDg/L0.11 7/25/22SW-846 8260D12-Chlorotoluene
ND 1.0 7/25/22 20:31 LBDg/L0.12 7/25/22SW-846 8260D14-Chlorotoluene
ND 5.0 7/25/22 20:31 LBDg/L0.80 7/25/22SW-846 8260D1V-051,2-Dibromo-3-chloropropane (DBCP)
ND 0.50 7/25/22 20:31 LBDg/L0.17 7/25/22SW-846 8260D11,2-Dibromoethane (EDB)
ND 1.0 7/25/22 20:31 LBDg/L0.35 7/25/22SW-846 8260D1Dibromomethane
ND 1.0 7/25/22 20:31 LBDg/L0.12 7/25/22SW-846 8260D11,2-Dichlorobenzene
ND 1.0 7/25/22 20:31 LBDg/L0.12 7/25/22SW-846 8260D11,3-Dichlorobenzene
ND 1.0 7/25/22 20:31 LBDg/L0.13 7/25/22SW-846 8260D11,4-Dichlorobenzene
ND 2.0 7/25/22 20:31 LBDg/L1.6 7/25/22SW-846 8260D1trans-1,4-Dichloro-2-butene
ND 2.0 7/25/22 20:31 LBDg/L0.19 7/25/22SW-846 8260D1Dichlorodifluoromethane (Freon 12)
ND 1.0 7/25/22 20:31 LBDg/L0.14 7/25/22SW-846 8260D11,1-Dichloroethane
ND 1.0 7/25/22 20:31 LBDg/L0.31 7/25/22SW-846 8260D11,2-Dichloroethane
ND 1.0 7/25/22 20:31 LBDg/L0.14 7/25/22SW-846 8260D11,1-Dichloroethylene
ND 1.0 7/25/22 20:31 LBDg/L0.15 7/25/22SW-846 8260D1cis-1,2-Dichloroethylene
ND 1.0 7/25/22 20:31 LBDg/L0.17 7/25/22SW-846 8260D1trans-1,2-Dichloroethylene
ND 1.0 7/25/22 20:31 LBDg/L0.18 7/25/22SW-846 8260D11,2-Dichloropropane
ND 0.50 7/25/22 20:31 LBDg/L0.13 7/25/22SW-846 8260D11,3-Dichloropropane
ND 1.0 7/25/22 20:31 LBDg/L0.33 7/25/22SW-846 8260D12,2-Dichloropropane
ND 2.0 7/25/22 20:31 LBDg/L0.15 7/25/22SW-846 8260D11,1-Dichloropropene
ND 0.50 7/25/22 20:31 LBDg/L0.16 7/25/22SW-846 8260D1cis-1,3-Dichloropropene
ND 0.50 7/25/22 20:31 LBDg/L0.17 7/25/22SW-846 8260D1trans-1,3-Dichloropropene
ND 2.0 7/25/22 20:31 LBDg/L0.18 7/25/22SW-846 8260D1Diethyl Ether
Page 7 of 25
Table of Contents
Page 18 of 36
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/23/2022
Work Order: 22G1343Sample Description:Project Location: Crown Food Mart 7/21
Sample ID: 22G1343-02
Field Sample #: SW 02 178
Sample Matrix: Water
Sampled: 7/21/2022 11:00
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 7/25/22 20:31 LBDg/L0.13 7/25/22SW-846 8260D1Diisopropyl Ether (DIPE)
ND 50 7/25/22 20:31 LBDg/L21 7/25/22SW-846 8260D11,4-Dioxane
ND 1.0 7/25/22 20:31 LBDg/L0.21 7/25/22SW-846 8260D1Ethylbenzene
ND 0.60 7/25/22 20:31 LBDg/L0.46 7/25/22SW-846 8260D1Hexachlorobutadiene
ND 10 7/25/22 20:31 LBDg/L1.1 7/25/22SW-846 8260D12-Hexanone (MBK)
ND 1.0 7/25/22 20:31 LBDg/L0.11 7/25/22SW-846 8260D1Isopropylbenzene (Cumene)
ND 1.0 7/25/22 20:31 LBDg/L0.097 7/25/22SW-846 8260D1p-Isopropyltoluene (p-Cymene)
ND 1.0 7/25/22 20:31 LBDg/L0.17 7/25/22SW-846 8260D1Methyl tert-Butyl Ether (MTBE)
ND 5.0 7/25/22 20:31 LBDg/L0.23 7/25/22SW-846 8260D1Methylene Chloride
ND 10 7/25/22 20:31 LBDg/L1.3 7/25/22SW-846 8260D14-Methyl-2-pentanone (MIBK)
ND 2.0 7/25/22 20:31 LBDg/L0.24 7/25/22SW-846 8260D1V-05Naphthalene
ND 1.0 7/25/22 20:31 LBDg/L0.086 7/25/22SW-846 8260D1n-Propylbenzene
ND 1.0 7/25/22 20:31 LBDg/L0.11 7/25/22SW-846 8260D1Styrene
ND 1.0 7/25/22 20:31 LBDg/L0.18 7/25/22SW-846 8260D11,1,1,2-Tetrachloroethane
ND 0.50 7/25/22 20:31 LBDg/L0.13 7/25/22SW-846 8260D11,1,2,2-Tetrachloroethane
ND 1.0 7/25/22 20:31 LBDg/L0.19 7/25/22SW-846 8260D1Tetrachloroethylene
ND 10 7/25/22 20:31 LBDg/L0.49 7/25/22SW-846 8260D1Tetrahydrofuran
ND 1.0 7/25/22 20:31 LBDg/L0.22 7/25/22SW-846 8260D1Toluene
ND 5.0 7/25/22 20:31 LBDg/L0.30 7/25/22SW-846 8260D11,2,3-Trichlorobenzene
ND 1.0 7/25/22 20:31 LBDg/L0.25 7/25/22SW-846 8260D11,2,4-Trichlorobenzene
ND 1.0 7/25/22 20:31 LBDg/L0.21 7/25/22SW-846 8260D11,3,5-Trichlorobenzene
ND 1.0 7/25/22 20:31 LBDg/L0.17 7/25/22SW-846 8260D11,1,1-Trichloroethane
ND 1.0 7/25/22 20:31 LBDg/L0.18 7/25/22SW-846 8260D11,1,2-Trichloroethane
ND 1.0 7/25/22 20:31 LBDg/L0.19 7/25/22SW-846 8260D1Trichloroethylene
ND 2.0 7/25/22 20:31 LBDg/L0.18 7/25/22SW-846 8260D1Trichlorofluoromethane (Freon 11)
ND 2.0 7/25/22 20:31 LBDg/L0.28 7/25/22SW-846 8260D11,2,3-Trichloropropane
ND 1.0 7/25/22 20:31 LBDg/L0.23 7/25/22SW-846 8260D11,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
0.47 1.0 7/25/22 20:31 LBDg/L0.20 7/25/22SW-846 8260D1J1,2,4-Trimethylbenzene
0.12 1.0 7/25/22 20:31 LBDg/L0.11 7/25/22SW-846 8260D1J1,3,5-Trimethylbenzene
ND 2.0 7/25/22 20:31 LBDg/L0.21 7/25/22SW-846 8260D1Vinyl Chloride
ND 2.0 7/25/22 20:31 LBDg/L0.46 7/25/22SW-846 8260D1m+p Xylene
ND 1.0 7/25/22 20:31 LBDg/L0.23 7/25/22SW-846 8260D1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 89.5 7/25/22 20:3170-130
Toluene-d8 101 7/25/22 20:3170-130
4-Bromofluorobenzene 99.5 7/25/22 20:3170-130
Page 8 of 25
Table of Contents
Page 19 of 36
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/23/2022
Work Order: 22G1343Sample Description:Project Location: Crown Food Mart 7/21
Sample ID: 22G1343-03
Field Sample #: SW 03 178
Sample Matrix: Water
Sampled: 7/21/2022 11:00
[TOC_2]22G1343-03[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 7/25/22 20:58 LBDg/L2.0 7/25/22SW-846 8260D1Acetone
ND 5.0 7/25/22 20:58 LBDg/L0.55 7/25/22SW-846 8260D1Acrylonitrile
ND 0.50 7/25/22 20:58 LBDg/L0.14 7/25/22SW-846 8260D1tert-Amyl Methyl Ether (TAME)
ND 1.0 7/25/22 20:58 LBDg/L0.20 7/25/22SW-846 8260D1Benzene
ND 1.0 7/25/22 20:58 LBDg/L0.15 7/25/22SW-846 8260D1Bromobenzene
ND 1.0 7/25/22 20:58 LBDg/L0.31 7/25/22SW-846 8260D1Bromochloromethane
ND 0.50 7/25/22 20:58 LBDg/L0.18 7/25/22SW-846 8260D1Bromodichloromethane
ND 1.0 7/25/22 20:58 LBDg/L0.38 7/25/22SW-846 8260D1Bromoform
ND 5.0 7/25/22 20:58 LBDg/L1.5 7/25/22SW-846 8260D1V-34Bromomethane
ND 20 7/25/22 20:58 LBDg/L1.6 7/25/22SW-846 8260D12-Butanone (MEK)
ND 20 7/25/22 20:58 LBDg/L4.7 7/25/22SW-846 8260D1tert-Butyl Alcohol (TBA)
ND 1.0 7/25/22 20:58 LBDg/L0.15 7/25/22SW-846 8260D1n-Butylbenzene
ND 1.0 7/25/22 20:58 LBDg/L0.11 7/25/22SW-846 8260D1sec-Butylbenzene
ND 1.0 7/25/22 20:58 LBDg/L0.13 7/25/22SW-846 8260D1tert-Butylbenzene
ND 0.50 7/25/22 20:58 LBDg/L0.15 7/25/22SW-846 8260D1tert-Butyl Ethyl Ether (TBEE)
ND 5.0 7/25/22 20:58 LBDg/L1.4 7/25/22SW-846 8260D1Carbon Disulfide
ND 1.0 7/25/22 20:58 LBDg/L0.16 7/25/22SW-846 8260D1Carbon Tetrachloride
ND 1.0 7/25/22 20:58 LBDg/L0.11 7/25/22SW-846 8260D1Chlorobenzene
ND 0.50 7/25/22 20:58 LBDg/L0.22 7/25/22SW-846 8260D1Chlorodibromomethane
ND 2.0 7/25/22 20:58 LBDg/L0.32 7/25/22SW-846 8260D1Chloroethane
ND 2.0 7/25/22 20:58 LBDg/L0.17 7/25/22SW-846 8260D1Chloroform
ND 2.0 7/25/22 20:58 LBDg/L0.52 7/25/22SW-846 8260D1V-05, V-34Chloromethane
ND 1.0 7/25/22 20:58 LBDg/L0.11 7/25/22SW-846 8260D12-Chlorotoluene
ND 1.0 7/25/22 20:58 LBDg/L0.12 7/25/22SW-846 8260D14-Chlorotoluene
ND 5.0 7/25/22 20:58 LBDg/L0.80 7/25/22SW-846 8260D1V-051,2-Dibromo-3-chloropropane (DBCP)
ND 0.50 7/25/22 20:58 LBDg/L0.17 7/25/22SW-846 8260D11,2-Dibromoethane (EDB)
ND 1.0 7/25/22 20:58 LBDg/L0.35 7/25/22SW-846 8260D1Dibromomethane
ND 1.0 7/25/22 20:58 LBDg/L0.12 7/25/22SW-846 8260D11,2-Dichlorobenzene
ND 1.0 7/25/22 20:58 LBDg/L0.12 7/25/22SW-846 8260D11,3-Dichlorobenzene
ND 1.0 7/25/22 20:58 LBDg/L0.13 7/25/22SW-846 8260D11,4-Dichlorobenzene
ND 2.0 7/25/22 20:58 LBDg/L1.6 7/25/22SW-846 8260D1trans-1,4-Dichloro-2-butene
ND 2.0 7/25/22 20:58 LBDg/L0.19 7/25/22SW-846 8260D1Dichlorodifluoromethane (Freon 12)
ND 1.0 7/25/22 20:58 LBDg/L0.14 7/25/22SW-846 8260D11,1-Dichloroethane
ND 1.0 7/25/22 20:58 LBDg/L0.31 7/25/22SW-846 8260D11,2-Dichloroethane
ND 1.0 7/25/22 20:58 LBDg/L0.14 7/25/22SW-846 8260D11,1-Dichloroethylene
ND 1.0 7/25/22 20:58 LBDg/L0.15 7/25/22SW-846 8260D1cis-1,2-Dichloroethylene
ND 1.0 7/25/22 20:58 LBDg/L0.17 7/25/22SW-846 8260D1trans-1,2-Dichloroethylene
ND 1.0 7/25/22 20:58 LBDg/L0.18 7/25/22SW-846 8260D11,2-Dichloropropane
ND 0.50 7/25/22 20:58 LBDg/L0.13 7/25/22SW-846 8260D11,3-Dichloropropane
ND 1.0 7/25/22 20:58 LBDg/L0.33 7/25/22SW-846 8260D12,2-Dichloropropane
ND 2.0 7/25/22 20:58 LBDg/L0.15 7/25/22SW-846 8260D11,1-Dichloropropene
ND 0.50 7/25/22 20:58 LBDg/L0.16 7/25/22SW-846 8260D1cis-1,3-Dichloropropene
ND 0.50 7/25/22 20:58 LBDg/L0.17 7/25/22SW-846 8260D1trans-1,3-Dichloropropene
ND 2.0 7/25/22 20:58 LBDg/L0.18 7/25/22SW-846 8260D1Diethyl Ether
Page 9 of 25
Table of Contents
Page 20 of 36
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/23/2022
Work Order: 22G1343Sample Description:Project Location: Crown Food Mart 7/21
Sample ID: 22G1343-03
Field Sample #: SW 03 178
Sample Matrix: Water
Sampled: 7/21/2022 11:00
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 7/25/22 20:58 LBDg/L0.13 7/25/22SW-846 8260D1Diisopropyl Ether (DIPE)
ND 50 7/25/22 20:58 LBDg/L21 7/25/22SW-846 8260D11,4-Dioxane
ND 1.0 7/25/22 20:58 LBDg/L0.21 7/25/22SW-846 8260D1Ethylbenzene
ND 0.60 7/25/22 20:58 LBDg/L0.46 7/25/22SW-846 8260D1Hexachlorobutadiene
ND 10 7/25/22 20:58 LBDg/L1.1 7/25/22SW-846 8260D12-Hexanone (MBK)
ND 1.0 7/25/22 20:58 LBDg/L0.11 7/25/22SW-846 8260D1Isopropylbenzene (Cumene)
ND 1.0 7/25/22 20:58 LBDg/L0.097 7/25/22SW-846 8260D1p-Isopropyltoluene (p-Cymene)
ND 1.0 7/25/22 20:58 LBDg/L0.17 7/25/22SW-846 8260D1Methyl tert-Butyl Ether (MTBE)
ND 5.0 7/25/22 20:58 LBDg/L0.23 7/25/22SW-846 8260D1Methylene Chloride
ND 10 7/25/22 20:58 LBDg/L1.3 7/25/22SW-846 8260D14-Methyl-2-pentanone (MIBK)
ND 2.0 7/25/22 20:58 LBDg/L0.24 7/25/22SW-846 8260D1V-05Naphthalene
ND 1.0 7/25/22 20:58 LBDg/L0.086 7/25/22SW-846 8260D1n-Propylbenzene
ND 1.0 7/25/22 20:58 LBDg/L0.11 7/25/22SW-846 8260D1Styrene
ND 1.0 7/25/22 20:58 LBDg/L0.18 7/25/22SW-846 8260D11,1,1,2-Tetrachloroethane
ND 0.50 7/25/22 20:58 LBDg/L0.13 7/25/22SW-846 8260D11,1,2,2-Tetrachloroethane
ND 1.0 7/25/22 20:58 LBDg/L0.19 7/25/22SW-846 8260D1Tetrachloroethylene
ND 10 7/25/22 20:58 LBDg/L0.49 7/25/22SW-846 8260D1Tetrahydrofuran
ND 1.0 7/25/22 20:58 LBDg/L0.22 7/25/22SW-846 8260D1Toluene
ND 5.0 7/25/22 20:58 LBDg/L0.30 7/25/22SW-846 8260D11,2,3-Trichlorobenzene
ND 1.0 7/25/22 20:58 LBDg/L0.25 7/25/22SW-846 8260D11,2,4-Trichlorobenzene
ND 1.0 7/25/22 20:58 LBDg/L0.21 7/25/22SW-846 8260D11,3,5-Trichlorobenzene
ND 1.0 7/25/22 20:58 LBDg/L0.17 7/25/22SW-846 8260D11,1,1-Trichloroethane
ND 1.0 7/25/22 20:58 LBDg/L0.18 7/25/22SW-846 8260D11,1,2-Trichloroethane
ND 1.0 7/25/22 20:58 LBDg/L0.19 7/25/22SW-846 8260D1Trichloroethylene
ND 2.0 7/25/22 20:58 LBDg/L0.18 7/25/22SW-846 8260D1Trichlorofluoromethane (Freon 11)
ND 2.0 7/25/22 20:58 LBDg/L0.28 7/25/22SW-846 8260D11,2,3-Trichloropropane
ND 1.0 7/25/22 20:58 LBDg/L0.23 7/25/22SW-846 8260D11,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
0.22 1.0 7/25/22 20:58 LBDg/L0.20 7/25/22SW-846 8260D1J1,2,4-Trimethylbenzene
ND 1.0 7/25/22 20:58 LBDg/L0.11 7/25/22SW-846 8260D11,3,5-Trimethylbenzene
ND 2.0 7/25/22 20:58 LBDg/L0.21 7/25/22SW-846 8260D1Vinyl Chloride
ND 2.0 7/25/22 20:58 LBDg/L0.46 7/25/22SW-846 8260D1m+p Xylene
ND 1.0 7/25/22 20:58 LBDg/L0.23 7/25/22SW-846 8260D1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 88.1 7/25/22 20:5870-130
Toluene-d8 102 7/25/22 20:5870-130
4-Bromofluorobenzene 97.8 7/25/22 20:5870-130
Page 10 of 25
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Page 21 of 36
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/23/2022
Work Order: 22G1343Sample Description:Project Location: Crown Food Mart 7/21
Sample ID: 22G1343-04
Field Sample #: SW 04 178
Sample Matrix: Water
Sampled: 7/21/2022 11:00
[TOC_2]22G1343-04[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 7/25/22 21:24 LBDg/L2.0 7/25/22SW-846 8260D1Acetone
ND 5.0 7/25/22 21:24 LBDg/L0.55 7/25/22SW-846 8260D1Acrylonitrile
ND 0.50 7/25/22 21:24 LBDg/L0.14 7/25/22SW-846 8260D1tert-Amyl Methyl Ether (TAME)
ND 1.0 7/25/22 21:24 LBDg/L0.20 7/25/22SW-846 8260D1Benzene
ND 1.0 7/25/22 21:24 LBDg/L0.15 7/25/22SW-846 8260D1Bromobenzene
ND 1.0 7/25/22 21:24 LBDg/L0.31 7/25/22SW-846 8260D1Bromochloromethane
ND 0.50 7/25/22 21:24 LBDg/L0.18 7/25/22SW-846 8260D1Bromodichloromethane
ND 1.0 7/25/22 21:24 LBDg/L0.38 7/25/22SW-846 8260D1Bromoform
ND 5.0 7/25/22 21:24 LBDg/L1.5 7/25/22SW-846 8260D1V-34Bromomethane
ND 20 7/25/22 21:24 LBDg/L1.6 7/25/22SW-846 8260D12-Butanone (MEK)
ND 20 7/25/22 21:24 LBDg/L4.7 7/25/22SW-846 8260D1tert-Butyl Alcohol (TBA)
ND 1.0 7/25/22 21:24 LBDg/L0.15 7/25/22SW-846 8260D1n-Butylbenzene
ND 1.0 7/25/22 21:24 LBDg/L0.11 7/25/22SW-846 8260D1sec-Butylbenzene
ND 1.0 7/25/22 21:24 LBDg/L0.13 7/25/22SW-846 8260D1tert-Butylbenzene
ND 0.50 7/25/22 21:24 LBDg/L0.15 7/25/22SW-846 8260D1tert-Butyl Ethyl Ether (TBEE)
ND 5.0 7/25/22 21:24 LBDg/L1.4 7/25/22SW-846 8260D1Carbon Disulfide
ND 1.0 7/25/22 21:24 LBDg/L0.16 7/25/22SW-846 8260D1Carbon Tetrachloride
ND 1.0 7/25/22 21:24 LBDg/L0.11 7/25/22SW-846 8260D1Chlorobenzene
ND 0.50 7/25/22 21:24 LBDg/L0.22 7/25/22SW-846 8260D1Chlorodibromomethane
ND 2.0 7/25/22 21:24 LBDg/L0.32 7/25/22SW-846 8260D1Chloroethane
ND 2.0 7/25/22 21:24 LBDg/L0.17 7/25/22SW-846 8260D1Chloroform
ND 2.0 7/25/22 21:24 LBDg/L0.52 7/25/22SW-846 8260D1V-05, V-34Chloromethane
ND 1.0 7/25/22 21:24 LBDg/L0.11 7/25/22SW-846 8260D12-Chlorotoluene
ND 1.0 7/25/22 21:24 LBDg/L0.12 7/25/22SW-846 8260D14-Chlorotoluene
ND 5.0 7/25/22 21:24 LBDg/L0.80 7/25/22SW-846 8260D1V-051,2-Dibromo-3-chloropropane (DBCP)
ND 0.50 7/25/22 21:24 LBDg/L0.17 7/25/22SW-846 8260D11,2-Dibromoethane (EDB)
ND 1.0 7/25/22 21:24 LBDg/L0.35 7/25/22SW-846 8260D1Dibromomethane
ND 1.0 7/25/22 21:24 LBDg/L0.12 7/25/22SW-846 8260D11,2-Dichlorobenzene
ND 1.0 7/25/22 21:24 LBDg/L0.12 7/25/22SW-846 8260D11,3-Dichlorobenzene
ND 1.0 7/25/22 21:24 LBDg/L0.13 7/25/22SW-846 8260D11,4-Dichlorobenzene
ND 2.0 7/25/22 21:24 LBDg/L1.6 7/25/22SW-846 8260D1trans-1,4-Dichloro-2-butene
ND 2.0 7/25/22 21:24 LBDg/L0.19 7/25/22SW-846 8260D1Dichlorodifluoromethane (Freon 12)
ND 1.0 7/25/22 21:24 LBDg/L0.14 7/25/22SW-846 8260D11,1-Dichloroethane
ND 1.0 7/25/22 21:24 LBDg/L0.31 7/25/22SW-846 8260D11,2-Dichloroethane
ND 1.0 7/25/22 21:24 LBDg/L0.14 7/25/22SW-846 8260D11,1-Dichloroethylene
ND 1.0 7/25/22 21:24 LBDg/L0.15 7/25/22SW-846 8260D1cis-1,2-Dichloroethylene
ND 1.0 7/25/22 21:24 LBDg/L0.17 7/25/22SW-846 8260D1trans-1,2-Dichloroethylene
ND 1.0 7/25/22 21:24 LBDg/L0.18 7/25/22SW-846 8260D11,2-Dichloropropane
ND 0.50 7/25/22 21:24 LBDg/L0.13 7/25/22SW-846 8260D11,3-Dichloropropane
ND 1.0 7/25/22 21:24 LBDg/L0.33 7/25/22SW-846 8260D12,2-Dichloropropane
ND 2.0 7/25/22 21:24 LBDg/L0.15 7/25/22SW-846 8260D11,1-Dichloropropene
ND 0.50 7/25/22 21:24 LBDg/L0.16 7/25/22SW-846 8260D1cis-1,3-Dichloropropene
ND 0.50 7/25/22 21:24 LBDg/L0.17 7/25/22SW-846 8260D1trans-1,3-Dichloropropene
ND 2.0 7/25/22 21:24 LBDg/L0.18 7/25/22SW-846 8260D1Diethyl Ether
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Page 22 of 36
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 7/23/2022
Work Order: 22G1343Sample Description:Project Location: Crown Food Mart 7/21
Sample ID: 22G1343-04
Field Sample #: SW 04 178
Sample Matrix: Water
Sampled: 7/21/2022 11:00
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 7/25/22 21:24 LBDg/L0.13 7/25/22SW-846 8260D1Diisopropyl Ether (DIPE)
ND 50 7/25/22 21:24 LBDg/L21 7/25/22SW-846 8260D11,4-Dioxane
ND 1.0 7/25/22 21:24 LBDg/L0.21 7/25/22SW-846 8260D1Ethylbenzene
ND 0.60 7/25/22 21:24 LBDg/L0.46 7/25/22SW-846 8260D1Hexachlorobutadiene
ND 10 7/25/22 21:24 LBDg/L1.1 7/25/22SW-846 8260D12-Hexanone (MBK)
ND 1.0 7/25/22 21:24 LBDg/L0.11 7/25/22SW-846 8260D1Isopropylbenzene (Cumene)
ND 1.0 7/25/22 21:24 LBDg/L0.097 7/25/22SW-846 8260D1p-Isopropyltoluene (p-Cymene)
ND 1.0 7/25/22 21:24 LBDg/L0.17 7/25/22SW-846 8260D1Methyl tert-Butyl Ether (MTBE)
ND 5.0 7/25/22 21:24 LBDg/L0.23 7/25/22SW-846 8260D1Methylene Chloride
ND 10 7/25/22 21:24 LBDg/L1.3 7/25/22SW-846 8260D14-Methyl-2-pentanone (MIBK)
ND 2.0 7/25/22 21:24 LBDg/L0.24 7/25/22SW-846 8260D1V-05Naphthalene
ND 1.0 7/25/22 21:24 LBDg/L0.086 7/25/22SW-846 8260D1n-Propylbenzene
ND 1.0 7/25/22 21:24 LBDg/L0.11 7/25/22SW-846 8260D1Styrene
ND 1.0 7/25/22 21:24 LBDg/L0.18 7/25/22SW-846 8260D11,1,1,2-Tetrachloroethane
ND 0.50 7/25/22 21:24 LBDg/L0.13 7/25/22SW-846 8260D11,1,2,2-Tetrachloroethane
ND 1.0 7/25/22 21:24 LBDg/L0.19 7/25/22SW-846 8260D1Tetrachloroethylene
ND 10 7/25/22 21:24 LBDg/L0.49 7/25/22SW-846 8260D1Tetrahydrofuran
ND 1.0 7/25/22 21:24 LBDg/L0.22 7/25/22SW-846 8260D1Toluene
ND 5.0 7/25/22 21:24 LBDg/L0.30 7/25/22SW-846 8260D11,2,3-Trichlorobenzene
ND 1.0 7/25/22 21:24 LBDg/L0.25 7/25/22SW-846 8260D11,2,4-Trichlorobenzene
ND 1.0 7/25/22 21:24 LBDg/L0.21 7/25/22SW-846 8260D11,3,5-Trichlorobenzene
ND 1.0 7/25/22 21:24 LBDg/L0.17 7/25/22SW-846 8260D11,1,1-Trichloroethane
ND 1.0 7/25/22 21:24 LBDg/L0.18 7/25/22SW-846 8260D11,1,2-Trichloroethane
ND 1.0 7/25/22 21:24 LBDg/L0.19 7/25/22SW-846 8260D1Trichloroethylene
ND 2.0 7/25/22 21:24 LBDg/L0.18 7/25/22SW-846 8260D1Trichlorofluoromethane (Freon 11)
ND 2.0 7/25/22 21:24 LBDg/L0.28 7/25/22SW-846 8260D11,2,3-Trichloropropane
ND 1.0 7/25/22 21:24 LBDg/L0.23 7/25/22SW-846 8260D11,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
ND 1.0 7/25/22 21:24 LBDg/L0.20 7/25/22SW-846 8260D11,2,4-Trimethylbenzene
ND 1.0 7/25/22 21:24 LBDg/L0.11 7/25/22SW-846 8260D11,3,5-Trimethylbenzene
ND 2.0 7/25/22 21:24 LBDg/L0.21 7/25/22SW-846 8260D1Vinyl Chloride
ND 2.0 7/25/22 21:24 LBDg/L0.46 7/25/22SW-846 8260D1m+p Xylene
ND 1.0 7/25/22 21:24 LBDg/L0.23 7/25/22SW-846 8260D1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 85.0 7/25/22 21:2470-130
Toluene-d8 94.5 7/25/22 21:2470-130
4-Bromofluorobenzene 98.6 7/25/22 21:2470-130
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Sample Extraction Data
Prep Method: SW-846 5030B Analytical Method: SW-846 8260D
Lab Number [Field ID]Batch DateInitial [mL]Final [mL]
B313711 07/25/225 5.0022G1343-01 [SW 01 178]
B313711 07/25/225 5.0022G1343-02 [SW 02 178]
B313711 07/25/225 5.0022G1343-03 [SW 03 178]
B313711 07/25/225 5.0022G1343-04 [SW 04 178]
[TOC_1]Sample Preparation Information[TOC]
Page 13 of 25
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
[TOC_2]Volatile Organic Compounds by GC/MS[TOC]
Batch B313711 - SW-846 5030B
[TOC_3]B313711[TOC]
Blank (B313711-BLK1) Prepared & Analyzed: 07/25/22
Acetone g/L50ND
Acrylonitrile g/L5.0ND
tert-Amyl Methyl Ether (TAME)g/L0.50ND
Benzene g/L1.0ND
Bromobenzene g/L1.0ND
Bromochloromethane g/L1.0ND
Bromodichloromethane g/L0.50ND
Bromoform g/L1.0ND
Bromomethane g/L2.0 V-34ND
2-Butanone (MEK)g/L20ND
tert-Butyl Alcohol (TBA)g/L20ND
n-Butylbenzene g/L1.0ND
sec-Butylbenzene g/L1.0ND
tert-Butylbenzene g/L1.0ND
tert-Butyl Ethyl Ether (TBEE)g/L0.50ND
Carbon Disulfide g/L5.0ND
Carbon Tetrachloride g/L1.0ND
Chlorobenzene g/L1.0ND
Chlorodibromomethane g/L0.50ND
Chloroethane g/L2.0ND
Chloroform g/L2.0ND
Chloromethane g/L2.0 V-05, V-34ND
2-Chlorotoluene g/L1.0ND
4-Chlorotoluene g/L1.0ND
1,2-Dibromo-3-chloropropane (DBCP)g/L5.0 V-05ND
1,2-Dibromoethane (EDB)g/L0.50ND
Dibromomethane g/L1.0ND
1,2-Dichlorobenzene g/L1.0ND
1,3-Dichlorobenzene g/L1.0ND
1,4-Dichlorobenzene g/L1.0ND
trans-1,4-Dichloro-2-butene g/L2.0ND
Dichlorodifluoromethane (Freon 12)g/L2.0ND
1,1-Dichloroethane g/L1.0ND
1,2-Dichloroethane g/L1.0ND
1,1-Dichloroethylene g/L1.0ND
cis-1,2-Dichloroethylene g/L1.0ND
trans-1,2-Dichloroethylene g/L1.0ND
1,2-Dichloropropane g/L1.0ND
1,3-Dichloropropane g/L0.50ND
2,2-Dichloropropane g/L1.0ND
1,1-Dichloropropene g/L2.0ND
cis-1,3-Dichloropropene g/L0.50ND
trans-1,3-Dichloropropene g/L0.50ND
Diethyl Ether g/L2.0ND
Diisopropyl Ether (DIPE)g/L0.50ND
1,4-Dioxane g/L50ND
Ethylbenzene g/L1.0ND
Hexachlorobutadiene g/L0.60ND
2-Hexanone (MBK)g/L10ND
Isopropylbenzene (Cumene)g/L1.0ND
p-Isopropyltoluene (p-Cymene)g/L1.0ND
Methyl tert-Butyl Ether (MTBE)g/L1.0ND
[TOC_1]QC Data[TOC]
Page 14 of 25
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B313711 - SW-846 5030B
Blank (B313711-BLK1) Prepared & Analyzed: 07/25/22
Methylene Chloride g/L5.0ND
4-Methyl-2-pentanone (MIBK)g/L10ND
Naphthalene g/L2.0 V-05ND
n-Propylbenzene g/L1.0ND
Styrene g/L1.0ND
1,1,1,2-Tetrachloroethane g/L1.0ND
1,1,2,2-Tetrachloroethane g/L0.50ND
Tetrachloroethylene g/L1.0ND
Tetrahydrofuran g/L10ND
Toluene g/L1.0ND
1,2,3-Trichlorobenzene g/L5.0ND
1,2,4-Trichlorobenzene g/L1.0ND
1,3,5-Trichlorobenzene g/L1.0ND
1,1,1-Trichloroethane g/L1.0ND
1,1,2-Trichloroethane g/L1.0ND
Trichloroethylene g/L1.0ND
Trichlorofluoromethane (Freon 11)g/L2.0ND
1,2,3-Trichloropropane g/L2.0ND
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon
113)
g/L1.0ND
1,2,4-Trimethylbenzene g/L1.0ND
1,3,5-Trimethylbenzene g/L1.0ND
Vinyl Chloride g/L2.0ND
m+p Xylene g/L2.0ND
o-Xylene g/L1.0ND
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 85.421.4
g/L 25.0 70-130Surrogate: Toluene-d8 97.724.4
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 10426.1
LCS (B313711-BS1) Prepared & Analyzed: 07/25/22
Acetone g/L50 100 70-16094.094.0
Acrylonitrile g/L5.0 10.0 70-13011411.4
tert-Amyl Methyl Ether (TAME)g/L0.50 10.0 70-13010910.9
Benzene g/L1.0 10.0 70-13010310.3
Bromobenzene g/L1.0 10.0 70-13010210.2
Bromochloromethane g/L1.0 10.0 V-2070-13012612.6
Bromodichloromethane g/L0.50 10.0 70-13010410.4
Bromoform g/L1.0 10.0 70-13010110.1
Bromomethane g/L2.0 10.0 V-20, V-3440-16013313.3
2-Butanone (MEK)g/L20 100 40-16089.989.9
tert-Butyl Alcohol (TBA)g/L20 100 40-160102102
n-Butylbenzene g/L1.0 10.0 70-13091.29.12
sec-Butylbenzene g/L1.0 10.0 70-13096.29.62
tert-Butylbenzene g/L1.0 10.0 70-13010510.5
tert-Butyl Ethyl Ether (TBEE)g/L0.50 10.0 70-13010510.5
Carbon Disulfide g/L5.0 100 70-13096.796.7
Carbon Tetrachloride g/L1.0 10.0 70-13098.99.89
Chlorobenzene g/L1.0 10.0 70-13010610.6
Chlorodibromomethane g/L0.50 10.0 70-13011111.1
Chloroethane g/L2.0 10.0 70-13010410.4
Chloroform g/L2.0 10.0 70-13010410.4
Chloromethane g/L2.0 10.0 L-07, V-05, V-3440-16038.8 *3.88
2-Chlorotoluene g/L1.0 10.0 70-13097.39.73
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B313711 - SW-846 5030B
LCS (B313711-BS1) Prepared & Analyzed: 07/25/22
4-Chlorotoluene g/L1.0 10.0 70-13098.79.87
1,2-Dibromo-3-chloropropane (DBCP)g/L5.0 10.0 V-0570-13087.48.74
1,2-Dibromoethane (EDB)g/L0.50 10.0 70-13011211.2
Dibromomethane g/L1.0 10.0 70-13010410.4
1,2-Dichlorobenzene g/L1.0 10.0 70-13099.19.91
1,3-Dichlorobenzene g/L1.0 10.0 70-13010110.1
1,4-Dichlorobenzene g/L1.0 10.0 70-13010010.0
trans-1,4-Dichloro-2-butene g/L2.0 10.0 70-13011311.3
Dichlorodifluoromethane (Freon 12)g/L2.0 10.0 40-16082.18.21
1,1-Dichloroethane g/L1.0 10.0 70-13010910.9
1,2-Dichloroethane g/L1.0 10.0 70-13010210.2
1,1-Dichloroethylene g/L1.0 10.0 70-13010210.2
cis-1,2-Dichloroethylene g/L1.0 10.0 70-13010710.7
trans-1,2-Dichloroethylene g/L1.0 10.0 70-13011211.2
1,2-Dichloropropane g/L1.0 10.0 70-13011211.2
1,3-Dichloropropane g/L0.50 10.0 70-13011111.1
2,2-Dichloropropane g/L1.0 10.0 40-13010010.0
1,1-Dichloropropene g/L2.0 10.0 70-13010610.6
cis-1,3-Dichloropropene g/L0.50 10.0 70-13010210.2
trans-1,3-Dichloropropene g/L0.50 10.0 70-13099.29.92
Diethyl Ether g/L2.0 10.0 70-13010410.4
Diisopropyl Ether (DIPE)g/L0.50 10.0 70-13010310.3
1,4-Dioxane g/L50 100 40-130113113
Ethylbenzene g/L1.0 10.0 70-13099.79.97
Hexachlorobutadiene g/L0.60 10.0 70-13099.69.96
2-Hexanone (MBK)g/L10 100 70-16094.094.0
Isopropylbenzene (Cumene)g/L1.0 10.0 70-13010110.1
p-Isopropyltoluene (p-Cymene)g/L1.0 10.0 70-13010310.3
Methyl tert-Butyl Ether (MTBE)g/L1.0 10.0 70-13011111.1
Methylene Chloride g/L5.0 10.0 70-13010510.5
4-Methyl-2-pentanone (MIBK)g/L10 100 70-16097.497.4
Naphthalene g/L2.0 10.0 V-0540-13078.17.81
n-Propylbenzene g/L1.0 10.0 70-13096.49.64
Styrene g/L1.0 10.0 70-13010310.3
1,1,1,2-Tetrachloroethane g/L1.0 10.0 70-13011111.1
1,1,2,2-Tetrachloroethane g/L0.50 10.0 70-13010410.4
Tetrachloroethylene g/L1.0 10.0 70-13011811.8
Tetrahydrofuran g/L10 10.0 70-13010410.4
Toluene g/L1.0 10.0 70-13010310.3
1,2,3-Trichlorobenzene g/L5.0 10.0 70-13087.78.77
1,2,4-Trichlorobenzene g/L1.0 10.0 70-13097.79.77
1,3,5-Trichlorobenzene g/L1.0 10.0 70-13010210.2
1,1,1-Trichloroethane g/L1.0 10.0 70-13010310.3
1,1,2-Trichloroethane g/L1.0 10.0 70-13011311.3
Trichloroethylene g/L1.0 10.0 70-13011111.1
Trichlorofluoromethane (Freon 11)g/L2.0 10.0 70-13086.28.62
1,2,3-Trichloropropane g/L2.0 10.0 70-13011411.4
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon
113)
g/L1.0 10.0 70-13011111.1
1,2,4-Trimethylbenzene g/L1.0 10.0 70-13098.29.82
1,3,5-Trimethylbenzene g/L1.0 10.0 70-13098.79.87
Vinyl Chloride g/L2.0 10.0 40-16094.39.43
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Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B313711 - SW-846 5030B
LCS (B313711-BS1) Prepared & Analyzed: 07/25/22
m+p Xylene g/L2.0 20.0 70-13010320.7
o-Xylene g/L1.0 10.0 70-13098.49.84
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 83.120.8
g/L 25.0 70-130Surrogate: Toluene-d8 10125.1
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 99.324.8
LCS Dup (B313711-BSD1) Prepared & Analyzed: 07/25/22
Acetone g/L50 100 2570-16086.2 8.7686.2
Acrylonitrile g/L5.0 10.0 2570-130114 0.26411.4
tert-Amyl Methyl Ether (TAME)g/L0.50 10.0 2570-130109 0.36710.9
Benzene g/L1.0 10.0 2570-130107 3.5210.7
Bromobenzene g/L1.0 10.0 2570-130109 7.3110.9
Bromochloromethane g/L1.0 10.0 25 V-2070-130130 3.2013.0
Bromodichloromethane g/L0.50 10.0 2570-130109 4.6010.9
Bromoform g/L1.0 10.0 2570-130102 0.29610.2
Bromomethane g/L2.0 10.0 25 V-20, V-3440-160140 5.2014.0
2-Butanone (MEK)g/L20 100 2540-16091.2 1.4091.2
tert-Butyl Alcohol (TBA)g/L20 100 2540-16099.8 2.3299.8
n-Butylbenzene g/L1.0 10.0 2570-13091.8 0.6569.18
sec-Butylbenzene g/L1.0 10.0 2570-13097.2 1.039.72
tert-Butylbenzene g/L1.0 10.0 2570-130109 3.0810.9
tert-Butyl Ethyl Ether (TBEE)g/L0.50 10.0 2570-130108 2.8210.8
Carbon Disulfide g/L5.0 100 2570-130104 7.57104
Carbon Tetrachloride g/L1.0 10.0 2570-130103 3.6710.3
Chlorobenzene g/L1.0 10.0 2570-130108 2.0610.8
Chlorodibromomethane g/L0.50 10.0 2570-130111 0.54111.1
Chloroethane g/L2.0 10.0 2570-130106 1.7210.6
Chloroform g/L2.0 10.0 2570-130109 4.0410.9
Chloromethane g/L2.0 10.0 25 V-05, V-3440-16041.4 6.484.14
2-Chlorotoluene g/L1.0 10.0 2570-130105 7.4210.5
4-Chlorotoluene g/L1.0 10.0 2570-130106 7.2310.6
1,2-Dibromo-3-chloropropane (DBCP)g/L5.0 10.0 25 V-0570-13084.2 3.738.42
1,2-Dibromoethane (EDB)g/L0.50 10.0 2570-130117 3.6711.7
Dibromomethane g/L1.0 10.0 2570-130108 3.6810.8
1,2-Dichlorobenzene g/L1.0 10.0 2570-130101 2.1010.1
1,3-Dichlorobenzene g/L1.0 10.0 2570-130104 2.1510.4
1,4-Dichlorobenzene g/L1.0 10.0 2570-130103 2.5610.3
trans-1,4-Dichloro-2-butene g/L2.0 10.0 2570-130118 4.1511.8
Dichlorodifluoromethane (Freon 12)g/L2.0 10.0 2540-16090.0 9.189.00
1,1-Dichloroethane g/L1.0 10.0 2570-130112 2.4511.2
1,2-Dichloroethane g/L1.0 10.0 2570-130108 5.4310.8
1,1-Dichloroethylene g/L1.0 10.0 2570-130108 5.4210.8
cis-1,2-Dichloroethylene g/L1.0 10.0 2570-130112 4.8411.2
trans-1,2-Dichloroethylene g/L1.0 10.0 2570-130112 0.089111.2
1,2-Dichloropropane g/L1.0 10.0 2570-130113 0.97611.3
1,3-Dichloropropane g/L0.50 10.0 2570-130112 0.80511.2
2,2-Dichloropropane g/L1.0 10.0 2540-130109 8.2310.9
1,1-Dichloropropene g/L2.0 10.0 2570-130112 5.6911.2
cis-1,3-Dichloropropene g/L0.50 10.0 2570-130104 2.5310.4
trans-1,3-Dichloropropene g/L0.50 10.0 2570-130102 2.9810.2
Diethyl Ether g/L2.0 10.0 2570-130102 2.7210.2
Diisopropyl Ether (DIPE)g/L0.50 10.0 2570-130104 0.87210.4
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B313711 - SW-846 5030B
LCS Dup (B313711-BSD1) Prepared & Analyzed: 07/25/22
1,4-Dioxane g/L50 100 5040-130108 4.64108
Ethylbenzene g/L1.0 10.0 2570-130103 2.8710.3
Hexachlorobutadiene g/L0.60 10.0 2570-13097.7 1.939.77
2-Hexanone (MBK)g/L10 100 2570-160100 6.25100
Isopropylbenzene (Cumene)g/L1.0 10.0 2570-130107 5.9610.7
p-Isopropyltoluene (p-Cymene)g/L1.0 10.0 2570-130107 3.6110.7
Methyl tert-Butyl Ether (MTBE)g/L1.0 10.0 2570-130110 0.72611.0
Methylene Chloride g/L5.0 10.0 2570-130103 2.1110.3
4-Methyl-2-pentanone (MIBK)g/L10 100 2570-160104 6.36104
Naphthalene g/L2.0 10.0 25 V-0540-13075.4 3.527.54
n-Propylbenzene g/L1.0 10.0 2570-130104 7.9710.4
Styrene g/L1.0 10.0 2570-130106 2.8610.6
1,1,1,2-Tetrachloroethane g/L1.0 10.0 2570-130113 2.1511.3
1,1,2,2-Tetrachloroethane g/L0.50 10.0 2570-130108 3.6710.8
Tetrachloroethylene g/L1.0 10.0 2570-130125 5.9212.5
Tetrahydrofuran g/L10 10.0 2570-130104 0.48110.4
Toluene g/L1.0 10.0 2570-130107 4.0910.7
1,2,3-Trichlorobenzene g/L5.0 10.0 2570-13083.3 5.158.33
1,2,4-Trichlorobenzene g/L1.0 10.0 2570-13096.5 1.249.65
1,3,5-Trichlorobenzene g/L1.0 10.0 2570-130102 0.58810.2
1,1,1-Trichloroethane g/L1.0 10.0 2570-130107 3.6110.7
1,1,2-Trichloroethane g/L1.0 10.0 2570-130113 0.17711.3
Trichloroethylene g/L1.0 10.0 2570-130120 8.4812.0
Trichlorofluoromethane (Freon 11)g/L2.0 10.0 2570-13089.0 3.208.90
1,2,3-Trichloropropane g/L2.0 10.0 2570-130116 1.2211.6
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon
113)
g/L1.0 10.0 2570-130117 5.2511.7
1,2,4-Trimethylbenzene g/L1.0 10.0 2570-130100 2.2210.0
1,3,5-Trimethylbenzene g/L1.0 10.0 2570-130106 7.6010.6
Vinyl Chloride g/L2.0 10.0 2540-16097.6 3.449.76
m+p Xylene g/L2.0 20.0 2570-130106 2.2021.1
o-Xylene g/L1.0 10.0 2570-130103 4.2810.3
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 82.720.7
g/L 25.0 70-130Surrogate: Toluene-d8 10125.3
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 10025.1
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
FLAG/QUALIFIER SUMMARY
*QC result is outside of established limits.
Wide recovery limits established for difficult compound.
Wide RPD limits established for difficult compound.
#Data exceeded client recommended or regulatory level
Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the
calculation which have not been rounded.
No results have been blank subtracted unless specified in the case narrative section.
RL Reporting Limit is at the level of quantitation (LOQ)
DL Detection Limit is the lower limit of detection determined by the MDL study
MCL Maximum Contaminant Level
ND Not Detected
Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated
concentration (CLP J-Flag).
J
Either laboratory fortified blank/laboratory control sample or duplicate recovery is outside of control limits, but
the other is within limits. RPD between the two LFB/LCS results is within method specified criteria.
L-07
Continuing calibration verification (CCV) did not meet method specifications and was biased on the low side for
this compound.
V-05
Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side.
Data validation is not affected since sample result was "not detected" for this compound.
V-20
Initial calibration verification (ICV) did not meet method specifications and was biased on the low side for this
compound. Reported result is estimated.
V-34
[TOC_1]Flag/Qualifier Summary[TOC]
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
SW-846 8260D in Water
NCAcetone
NCAcrylonitrile
NCtert-Amyl Methyl Ether (TAME)
NCBenzene
NCBromobenzene
NCBromochloromethane
NCBromodichloromethane
NCBromoform
NCBromomethane
NC2-Butanone (MEK)
NCtert-Butyl Alcohol (TBA)
NCn-Butylbenzene
NCsec-Butylbenzene
NCtert-Butylbenzene
NCtert-Butyl Ethyl Ether (TBEE)
NCCarbon Disulfide
NCCarbon Tetrachloride
NCChlorobenzene
NCChlorodibromomethane
NCChloroethane
NCChloroform
NCChloromethane
NC2-Chlorotoluene
NC4-Chlorotoluene
NC1,2-Dibromo-3-chloropropane (DBCP)
NC1,2-Dibromoethane (EDB)
NCDibromomethane
NC1,2-Dichlorobenzene
NC1,3-Dichlorobenzene
NC1,4-Dichlorobenzene
NCtrans-1,4-Dichloro-2-butene
NCDichlorodifluoromethane (Freon 12)
NC1,1-Dichloroethane
NC1,2-Dichloroethane
NC1,1-Dichloroethylene
NCcis-1,2-Dichloroethylene
NCtrans-1,2-Dichloroethylene
NC1,2-Dichloropropane
NC1,3-Dichloropropane
NC2,2-Dichloropropane
NC1,1-Dichloropropene
NCcis-1,3-Dichloropropene
NCtrans-1,3-Dichloropropene
NCDiethyl Ether
NCDiisopropyl Ether (DIPE)
NC1,4-Dioxane
NCEthylbenzene
[TOC_1]Certifications[TOC]
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
SW-846 8260D in Water
NCHexachlorobutadiene
NC2-Hexanone (MBK)
NCIsopropylbenzene (Cumene)
NCp-Isopropyltoluene (p-Cymene)
NCMethyl tert-Butyl Ether (MTBE)
NCMethylene Chloride
NC4-Methyl-2-pentanone (MIBK)
NCNaphthalene
NCn-Propylbenzene
NCStyrene
NC1,1,1,2-Tetrachloroethane
NC1,1,2,2-Tetrachloroethane
NCTetrachloroethylene
NCTetrahydrofuran
NCToluene
NC1,2,3-Trichlorobenzene
NC1,2,4-Trichlorobenzene
NC1,3,5-Trichlorobenzene
NC1,1,1-Trichloroethane
NC1,1,2-Trichloroethane
NCTrichloroethylene
NCTrichlorofluoromethane (Freon 11)
NC1,2,3-Trichloropropane
NC1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)
NC1,2,4-Trimethylbenzene
NC1,3,5-Trimethylbenzene
NCVinyl Chloride
NCm+p Xylene
NCo-Xylene
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Con-Test, a Pace Environmental Laboratory, operates under the following certifications and accreditations:
Code Description Number Expires
100033AIHA-LAP, LLC - ISO 17025:2017AIHA 03/1/2024
M-MA100Massachusetts DEPMA 06/30/2023
PH-0165Connecticut Department of Public HealthCT 12/31/2022
10899 NELAPNew York State Department of HealthNY 04/1/2023
2516 NELAPNew Hampshire Environmental LabNH 02/5/2023
LAO00373Rhode Island Department of HealthRI 12/30/2022
652North Carolina Div. of Water QualityNC 12/31/2022
MA007 NELAPNew Jersey DEPNJ 06/30/2023
E871027 NELAPFlorida Department of HealthFL 06/30/2023
LL720741Vermont Department of Health Lead LaboratoryVT 07/30/2023
VT-255716Vermont Department of Health Drinking WaterVT-DW 06/12/2023
MA00100State of MaineME 06/9/2023
460217Commonwealth of VirginiaVA 12/14/2022
2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2022
25703North Carolina Department of Health and Human ServicesNC-DW 07/31/2023
68-05812Commonwealth of Pennsylvania DEPPA 06/30/2023
9100Dept. of Env, Great Lakes, and EnergyMI 09/6/2022
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#=CL#
August 17, 2022
LIMS USE: FR - ROBERT MARTIN
LIMS OBJECT ID: 92618890
92618890
Project:
Pace Project No.:
RE:
Mr. Robert Martin
Martin and Slagle
24 Lookout Terrace
Black Mountain, NC 28711
Crown Food Mart
Dear Mr. Martin:
Enclosed are the analytical results for sample(s) received by the laboratory on August 05, 2022. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lorri Patton
[e-mail]
Project Manager
1(828)254-7176
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 1 of 29
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92618890
Crown Food Mart
Lab ID Sample ID Matrix Date Collected Date Received
92618890001 SW01 179 Water 08/04/22 11:15 08/05/22 12:45
92618890002 SW02 179 Water 08/04/22 12:15 08/05/22 12:45
92618890003 SW03 179 Water 08/04/22 12:25 08/05/22 12:45
92618890004 SW04 179 Water 08/04/22 12:45 08/05/22 12:45
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 2 of 29
Page 3 of 29
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
August 12, 2022
Lorri Patton
Pace Analytical Services - NC
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Project Location: Crown Food Mart
Client Job Number:
Project Number: 92618890
Laboratory Work Order Number: 22H0366
Enclosed are results of analyses for samples as received by the laboratory on August 6, 2022. If you have any questions
concerning this report, please feel free to contact me.
Sincerely,
Kerry K. McGee
Project Manager
Page 1 of 24
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Table of Contents
Sample Summary 3
Case Narrative 4
Sample Results 5
22H0366-01 5
22H0366-02 7
22H0366-03 9
22H0366-04 11
QC Data 13
Volatile Organic Compounds by GC/MS 13
B314680 13
Flag/Qualifier Summary 18
Certifications 19
Chain of Custody/Sample Receipt 22
Page 2 of 24
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYTICAL SUMMARY
8/12/2022
Pace Analytical Services - NC
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
ATTN: Lorri Patton
92618890
22H0366
The results of analyses performed on the following samples submitted to CON-TEST, a Pace Analytical Laboratory, are found in this report.
PROJECT LOCATION:
PURCHASE ORDER NUMBER:
PROJECT NUMBER:
REPORT DATE:
WORK ORDER NUMBER:
FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB
Crown Food Mart
SW01 179 22H0366-01 Water SW-846 8260D
SW02 179 22H0366-02 Water SW-846 8260D
SW03 179 22H0366-03 Water SW-846 8260D
SW04 179 22H0366-04 Water SW-846 8260D
[TOC_1]Sample Summary[TOC]
Page 3 of 24
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CASE NARRATIVE SUMMARY
All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report.
[TOC_1]Case Narrative[TOC]
SW-846 8260D
Qualifications:
Laboratory fortified blank/laboratory control sample recovery and duplicate recoveries outside of control limits. Data validation is not
affected since all results are "not detected" for associated samples in this batch and bias is on the high side.
Analyte & Samples(s) Qualified:
L-02
Carbon Disulfide
B314680-BS1, B314680-BSD1, S075003-CCV1
Vinyl Chloride
B314680-BS1, B314680-BSD1, S075003-CCV1
Either laboratory fortified blank/laboratory control sample or duplicate recovery is outside of control limits, but the other is within limits. RPD
between the two LFB/LCS results is within method specified criteria.
Analyte & Samples(s) Qualified:
L-07
Hexachlorobutadiene
B314680-BS1
Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side. Data validation is not affected
since sample result was "not detected" for this compound.
Analyte & Samples(s) Qualified:
V-20
Carbon Disulfide
B314680-BS1, B314680-BSD1, S075003-CCV1
Hexachlorobutadiene
B314680-BS1, B314680-BSD1, S075003-CCV1
Vinyl Chloride
B314680-BS1, B314680-BSD1, S075003-CCV1
The results of analyses reported only relate to samples submitted to Con-Test, a Pace Analytical Laboratory, for testing.
I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed
in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the
best of my knowledge and belief, accurate and complete.
Lisa A. Worthington
Technical Representative
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Date Received: 8/6/2022
Work Order: 22H0366Sample Description:Project Location: Crown Food Mart
Sample ID: 22H0366-01
Field Sample #: SW01 179
Sample Matrix: Water
Sampled: 8/4/2022 11:15
[TOC_2]22H0366-01[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 8/8/22 13:17 EEHg/L2.0 8/8/22SW-846 8260D1Acetone
ND 5.0 8/8/22 13:17 EEHg/L0.55 8/8/22SW-846 8260D1Acrylonitrile
ND 0.50 8/8/22 13:17 EEHg/L0.14 8/8/22SW-846 8260D1tert-Amyl Methyl Ether (TAME)
ND 1.0 8/8/22 13:17 EEHg/L0.20 8/8/22SW-846 8260D1Benzene
ND 1.0 8/8/22 13:17 EEHg/L0.15 8/8/22SW-846 8260D1Bromobenzene
ND 1.0 8/8/22 13:17 EEHg/L0.31 8/8/22SW-846 8260D1Bromochloromethane
ND 0.50 8/8/22 13:17 EEHg/L0.18 8/8/22SW-846 8260D1Bromodichloromethane
ND 2.0 8/8/22 13:17 EEHg/L0.38 8/8/22SW-846 8260D1Bromoform
ND 2.0 8/8/22 13:17 EEHg/L1.5 8/8/22SW-846 8260D1Bromomethane
ND 20 8/8/22 13:17 EEHg/L1.6 8/8/22SW-846 8260D12-Butanone (MEK)
ND 20 8/8/22 13:17 EEHg/L4.7 8/8/22SW-846 8260D1tert-Butyl Alcohol (TBA)
ND 1.0 8/8/22 13:17 EEHg/L0.15 8/8/22SW-846 8260D1n-Butylbenzene
ND 1.0 8/8/22 13:17 EEHg/L0.11 8/8/22SW-846 8260D1sec-Butylbenzene
ND 1.0 8/8/22 13:17 EEHg/L0.13 8/8/22SW-846 8260D1tert-Butylbenzene
ND 0.50 8/8/22 13:17 EEHg/L0.15 8/8/22SW-846 8260D1tert-Butyl Ethyl Ether (TBEE)
ND 5.0 8/8/22 13:17 EEHg/L1.4 8/8/22SW-846 8260D1Carbon Disulfide
ND 1.0 8/8/22 13:17 EEHg/L0.16 8/8/22SW-846 8260D1Carbon Tetrachloride
ND 1.0 8/8/22 13:17 EEHg/L0.11 8/8/22SW-846 8260D1Chlorobenzene
ND 0.50 8/8/22 13:17 EEHg/L0.22 8/8/22SW-846 8260D1Chlorodibromomethane
ND 2.0 8/8/22 13:17 EEHg/L0.32 8/8/22SW-846 8260D1Chloroethane
ND 2.0 8/8/22 13:17 EEHg/L0.17 8/8/22SW-846 8260D1Chloroform
ND 2.0 8/8/22 13:17 EEHg/L0.52 8/8/22SW-846 8260D1Chloromethane
ND 1.0 8/8/22 13:17 EEHg/L0.11 8/8/22SW-846 8260D12-Chlorotoluene
ND 1.0 8/8/22 13:17 EEHg/L0.12 8/8/22SW-846 8260D14-Chlorotoluene
ND 5.0 8/8/22 13:17 EEHg/L0.80 8/8/22SW-846 8260D11,2-Dibromo-3-chloropropane (DBCP)
ND 0.50 8/8/22 13:17 EEHg/L0.17 8/8/22SW-846 8260D11,2-Dibromoethane (EDB)
ND 1.0 8/8/22 13:17 EEHg/L0.35 8/8/22SW-846 8260D1Dibromomethane
ND 1.0 8/8/22 13:17 EEHg/L0.12 8/8/22SW-846 8260D11,2-Dichlorobenzene
ND 1.0 8/8/22 13:17 EEHg/L0.12 8/8/22SW-846 8260D11,3-Dichlorobenzene
ND 1.0 8/8/22 13:17 EEHg/L0.13 8/8/22SW-846 8260D11,4-Dichlorobenzene
ND 2.0 8/8/22 13:17 EEHg/L1.6 8/8/22SW-846 8260D1trans-1,4-Dichloro-2-butene
ND 2.0 8/8/22 13:17 EEHg/L0.19 8/8/22SW-846 8260D1Dichlorodifluoromethane (Freon 12)
ND 1.0 8/8/22 13:17 EEHg/L0.14 8/8/22SW-846 8260D11,1-Dichloroethane
ND 1.0 8/8/22 13:17 EEHg/L0.31 8/8/22SW-846 8260D11,2-Dichloroethane
ND 1.0 8/8/22 13:17 EEHg/L0.14 8/8/22SW-846 8260D11,1-Dichloroethylene
ND 1.0 8/8/22 13:17 EEHg/L0.15 8/8/22SW-846 8260D1cis-1,2-Dichloroethylene
ND 1.0 8/8/22 13:17 EEHg/L0.17 8/8/22SW-846 8260D1trans-1,2-Dichloroethylene
ND 1.0 8/8/22 13:17 EEHg/L0.18 8/8/22SW-846 8260D11,2-Dichloropropane
ND 0.50 8/8/22 13:17 EEHg/L0.13 8/8/22SW-846 8260D11,3-Dichloropropane
ND 1.0 8/8/22 13:17 EEHg/L0.33 8/8/22SW-846 8260D12,2-Dichloropropane
ND 2.0 8/8/22 13:17 EEHg/L0.15 8/8/22SW-846 8260D11,1-Dichloropropene
ND 0.50 8/8/22 13:17 EEHg/L0.16 8/8/22SW-846 8260D1cis-1,3-Dichloropropene
ND 0.50 8/8/22 13:17 EEHg/L0.17 8/8/22SW-846 8260D1trans-1,3-Dichloropropene
ND 2.0 8/8/22 13:17 EEHg/L0.18 8/8/22SW-846 8260D1Diethyl Ether
[TOC_1]Sample Results[TOC]
Page 5 of 24
Table of Contents
Page 10 of 29
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/6/2022
Work Order: 22H0366Sample Description:Project Location: Crown Food Mart
Sample ID: 22H0366-01
Field Sample #: SW01 179
Sample Matrix: Water
Sampled: 8/4/2022 11:15
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 8/8/22 13:17 EEHg/L0.13 8/8/22SW-846 8260D1Diisopropyl Ether (DIPE)
ND 50 8/8/22 13:17 EEHg/L21 8/8/22SW-846 8260D11,4-Dioxane
0.25 1.0 8/8/22 13:17 EEHg/L0.21 8/8/22SW-846 8260D1JEthylbenzene
ND 0.60 8/8/22 13:17 EEHg/L0.46 8/8/22SW-846 8260D1Hexachlorobutadiene
ND 10 8/8/22 13:17 EEHg/L1.1 8/8/22SW-846 8260D12-Hexanone (MBK)
ND 1.0 8/8/22 13:17 EEHg/L0.11 8/8/22SW-846 8260D1Isopropylbenzene (Cumene)
ND 1.0 8/8/22 13:17 EEHg/L0.097 8/8/22SW-846 8260D1p-Isopropyltoluene (p-Cymene)
ND 1.0 8/8/22 13:17 EEHg/L0.17 8/8/22SW-846 8260D1Methyl tert-Butyl Ether (MTBE)
0.29 5.0 8/8/22 13:17 EEHg/L0.23 8/8/22SW-846 8260D1JMethylene Chloride
ND 10 8/8/22 13:17 EEHg/L1.3 8/8/22SW-846 8260D14-Methyl-2-pentanone (MIBK)
ND 2.0 8/8/22 13:17 EEHg/L0.24 8/8/22SW-846 8260D1Naphthalene
0.21 1.0 8/8/22 13:17 EEHg/L0.086 8/8/22SW-846 8260D1Jn-Propylbenzene
ND 1.0 8/8/22 13:17 EEHg/L0.11 8/8/22SW-846 8260D1Styrene
ND 1.0 8/8/22 13:17 EEHg/L0.18 8/8/22SW-846 8260D11,1,1,2-Tetrachloroethane
ND 0.50 8/8/22 13:17 EEHg/L0.13 8/8/22SW-846 8260D11,1,2,2-Tetrachloroethane
ND 1.0 8/8/22 13:17 EEHg/L0.19 8/8/22SW-846 8260D1Tetrachloroethylene
ND 10 8/8/22 13:17 EEHg/L0.49 8/8/22SW-846 8260D1Tetrahydrofuran
ND 1.0 8/8/22 13:17 EEHg/L0.22 8/8/22SW-846 8260D1Toluene
ND 5.0 8/8/22 13:17 EEHg/L0.30 8/8/22SW-846 8260D11,2,3-Trichlorobenzene
ND 1.0 8/8/22 13:17 EEHg/L0.25 8/8/22SW-846 8260D11,2,4-Trichlorobenzene
ND 1.0 8/8/22 13:17 EEHg/L0.21 8/8/22SW-846 8260D11,3,5-Trichlorobenzene
ND 1.0 8/8/22 13:17 EEHg/L0.17 8/8/22SW-846 8260D11,1,1-Trichloroethane
ND 1.0 8/8/22 13:17 EEHg/L0.18 8/8/22SW-846 8260D11,1,2-Trichloroethane
ND 1.0 8/8/22 13:17 EEHg/L0.19 8/8/22SW-846 8260D1Trichloroethylene
ND 2.0 8/8/22 13:17 EEHg/L0.18 8/8/22SW-846 8260D1Trichlorofluoromethane (Freon 11)
ND 2.0 8/8/22 13:17 EEHg/L0.28 8/8/22SW-846 8260D11,2,3-Trichloropropane
ND 2.0 8/8/22 13:17 EEHg/L0.23 8/8/22SW-846 8260D11,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
1.2 1.0 8/8/22 13:17 EEHg/L0.20 8/8/22SW-846 8260D11,2,4-Trimethylbenzene
0.30 1.0 8/8/22 13:17 EEHg/L0.11 8/8/22SW-846 8260D1J1,3,5-Trimethylbenzene
ND 2.0 8/8/22 13:17 EEHg/L0.21 8/8/22SW-846 8260D1Vinyl Chloride
0.57 2.0 8/8/22 13:17 EEHg/L0.46 8/8/22SW-846 8260D1Jm+p Xylene
ND 1.0 8/8/22 13:17 EEHg/L0.23 8/8/22SW-846 8260D1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 99.5 8/8/22 13:1770-130
Toluene-d8 98.1 8/8/22 13:1770-130
4-Bromofluorobenzene 98.2 8/8/22 13:1770-130
Page 6 of 24
Table of Contents
Page 11 of 29
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/6/2022
Work Order: 22H0366Sample Description:Project Location: Crown Food Mart
Sample ID: 22H0366-02
Field Sample #: SW02 179
Sample Matrix: Water
Sampled: 8/4/2022 12:15
[TOC_2]22H0366-02[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 8/8/22 13:44 EEHg/L2.0 8/8/22SW-846 8260D1Acetone
ND 5.0 8/8/22 13:44 EEHg/L0.55 8/8/22SW-846 8260D1Acrylonitrile
ND 0.50 8/8/22 13:44 EEHg/L0.14 8/8/22SW-846 8260D1tert-Amyl Methyl Ether (TAME)
ND 1.0 8/8/22 13:44 EEHg/L0.20 8/8/22SW-846 8260D1Benzene
ND 1.0 8/8/22 13:44 EEHg/L0.15 8/8/22SW-846 8260D1Bromobenzene
ND 1.0 8/8/22 13:44 EEHg/L0.31 8/8/22SW-846 8260D1Bromochloromethane
ND 0.50 8/8/22 13:44 EEHg/L0.18 8/8/22SW-846 8260D1Bromodichloromethane
ND 2.0 8/8/22 13:44 EEHg/L0.38 8/8/22SW-846 8260D1Bromoform
ND 2.0 8/8/22 13:44 EEHg/L1.5 8/8/22SW-846 8260D1Bromomethane
ND 20 8/8/22 13:44 EEHg/L1.6 8/8/22SW-846 8260D12-Butanone (MEK)
ND 20 8/8/22 13:44 EEHg/L4.7 8/8/22SW-846 8260D1tert-Butyl Alcohol (TBA)
ND 1.0 8/8/22 13:44 EEHg/L0.15 8/8/22SW-846 8260D1n-Butylbenzene
ND 1.0 8/8/22 13:44 EEHg/L0.11 8/8/22SW-846 8260D1sec-Butylbenzene
ND 1.0 8/8/22 13:44 EEHg/L0.13 8/8/22SW-846 8260D1tert-Butylbenzene
ND 0.50 8/8/22 13:44 EEHg/L0.15 8/8/22SW-846 8260D1tert-Butyl Ethyl Ether (TBEE)
ND 5.0 8/8/22 13:44 EEHg/L1.4 8/8/22SW-846 8260D1Carbon Disulfide
ND 1.0 8/8/22 13:44 EEHg/L0.16 8/8/22SW-846 8260D1Carbon Tetrachloride
ND 1.0 8/8/22 13:44 EEHg/L0.11 8/8/22SW-846 8260D1Chlorobenzene
ND 0.50 8/8/22 13:44 EEHg/L0.22 8/8/22SW-846 8260D1Chlorodibromomethane
ND 2.0 8/8/22 13:44 EEHg/L0.32 8/8/22SW-846 8260D1Chloroethane
ND 2.0 8/8/22 13:44 EEHg/L0.17 8/8/22SW-846 8260D1Chloroform
ND 2.0 8/8/22 13:44 EEHg/L0.52 8/8/22SW-846 8260D1Chloromethane
ND 1.0 8/8/22 13:44 EEHg/L0.11 8/8/22SW-846 8260D12-Chlorotoluene
ND 1.0 8/8/22 13:44 EEHg/L0.12 8/8/22SW-846 8260D14-Chlorotoluene
ND 5.0 8/8/22 13:44 EEHg/L0.80 8/8/22SW-846 8260D11,2-Dibromo-3-chloropropane (DBCP)
ND 0.50 8/8/22 13:44 EEHg/L0.17 8/8/22SW-846 8260D11,2-Dibromoethane (EDB)
ND 1.0 8/8/22 13:44 EEHg/L0.35 8/8/22SW-846 8260D1Dibromomethane
ND 1.0 8/8/22 13:44 EEHg/L0.12 8/8/22SW-846 8260D11,2-Dichlorobenzene
ND 1.0 8/8/22 13:44 EEHg/L0.12 8/8/22SW-846 8260D11,3-Dichlorobenzene
ND 1.0 8/8/22 13:44 EEHg/L0.13 8/8/22SW-846 8260D11,4-Dichlorobenzene
ND 2.0 8/8/22 13:44 EEHg/L1.6 8/8/22SW-846 8260D1trans-1,4-Dichloro-2-butene
ND 2.0 8/8/22 13:44 EEHg/L0.19 8/8/22SW-846 8260D1Dichlorodifluoromethane (Freon 12)
ND 1.0 8/8/22 13:44 EEHg/L0.14 8/8/22SW-846 8260D11,1-Dichloroethane
ND 1.0 8/8/22 13:44 EEHg/L0.31 8/8/22SW-846 8260D11,2-Dichloroethane
ND 1.0 8/8/22 13:44 EEHg/L0.14 8/8/22SW-846 8260D11,1-Dichloroethylene
ND 1.0 8/8/22 13:44 EEHg/L0.15 8/8/22SW-846 8260D1cis-1,2-Dichloroethylene
ND 1.0 8/8/22 13:44 EEHg/L0.17 8/8/22SW-846 8260D1trans-1,2-Dichloroethylene
ND 1.0 8/8/22 13:44 EEHg/L0.18 8/8/22SW-846 8260D11,2-Dichloropropane
ND 0.50 8/8/22 13:44 EEHg/L0.13 8/8/22SW-846 8260D11,3-Dichloropropane
ND 1.0 8/8/22 13:44 EEHg/L0.33 8/8/22SW-846 8260D12,2-Dichloropropane
ND 2.0 8/8/22 13:44 EEHg/L0.15 8/8/22SW-846 8260D11,1-Dichloropropene
ND 0.50 8/8/22 13:44 EEHg/L0.16 8/8/22SW-846 8260D1cis-1,3-Dichloropropene
ND 0.50 8/8/22 13:44 EEHg/L0.17 8/8/22SW-846 8260D1trans-1,3-Dichloropropene
ND 2.0 8/8/22 13:44 EEHg/L0.18 8/8/22SW-846 8260D1Diethyl Ether
Page 7 of 24
Table of Contents
Page 12 of 29
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/6/2022
Work Order: 22H0366Sample Description:Project Location: Crown Food Mart
Sample ID: 22H0366-02
Field Sample #: SW02 179
Sample Matrix: Water
Sampled: 8/4/2022 12:15
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 8/8/22 13:44 EEHg/L0.13 8/8/22SW-846 8260D1Diisopropyl Ether (DIPE)
ND 50 8/8/22 13:44 EEHg/L21 8/8/22SW-846 8260D11,4-Dioxane
ND 1.0 8/8/22 13:44 EEHg/L0.21 8/8/22SW-846 8260D1Ethylbenzene
ND 0.60 8/8/22 13:44 EEHg/L0.46 8/8/22SW-846 8260D1Hexachlorobutadiene
ND 10 8/8/22 13:44 EEHg/L1.1 8/8/22SW-846 8260D12-Hexanone (MBK)
ND 1.0 8/8/22 13:44 EEHg/L0.11 8/8/22SW-846 8260D1Isopropylbenzene (Cumene)
ND 1.0 8/8/22 13:44 EEHg/L0.097 8/8/22SW-846 8260D1p-Isopropyltoluene (p-Cymene)
ND 1.0 8/8/22 13:44 EEHg/L0.17 8/8/22SW-846 8260D1Methyl tert-Butyl Ether (MTBE)
0.41 5.0 8/8/22 13:44 EEHg/L0.23 8/8/22SW-846 8260D1JMethylene Chloride
ND 10 8/8/22 13:44 EEHg/L1.3 8/8/22SW-846 8260D14-Methyl-2-pentanone (MIBK)
ND 2.0 8/8/22 13:44 EEHg/L0.24 8/8/22SW-846 8260D1Naphthalene
ND 1.0 8/8/22 13:44 EEHg/L0.086 8/8/22SW-846 8260D1n-Propylbenzene
ND 1.0 8/8/22 13:44 EEHg/L0.11 8/8/22SW-846 8260D1Styrene
ND 1.0 8/8/22 13:44 EEHg/L0.18 8/8/22SW-846 8260D11,1,1,2-Tetrachloroethane
ND 0.50 8/8/22 13:44 EEHg/L0.13 8/8/22SW-846 8260D11,1,2,2-Tetrachloroethane
ND 1.0 8/8/22 13:44 EEHg/L0.19 8/8/22SW-846 8260D1Tetrachloroethylene
ND 10 8/8/22 13:44 EEHg/L0.49 8/8/22SW-846 8260D1Tetrahydrofuran
ND 1.0 8/8/22 13:44 EEHg/L0.22 8/8/22SW-846 8260D1Toluene
ND 5.0 8/8/22 13:44 EEHg/L0.30 8/8/22SW-846 8260D11,2,3-Trichlorobenzene
ND 1.0 8/8/22 13:44 EEHg/L0.25 8/8/22SW-846 8260D11,2,4-Trichlorobenzene
ND 1.0 8/8/22 13:44 EEHg/L0.21 8/8/22SW-846 8260D11,3,5-Trichlorobenzene
ND 1.0 8/8/22 13:44 EEHg/L0.17 8/8/22SW-846 8260D11,1,1-Trichloroethane
ND 1.0 8/8/22 13:44 EEHg/L0.18 8/8/22SW-846 8260D11,1,2-Trichloroethane
ND 1.0 8/8/22 13:44 EEHg/L0.19 8/8/22SW-846 8260D1Trichloroethylene
ND 2.0 8/8/22 13:44 EEHg/L0.18 8/8/22SW-846 8260D1Trichlorofluoromethane (Freon 11)
ND 2.0 8/8/22 13:44 EEHg/L0.28 8/8/22SW-846 8260D11,2,3-Trichloropropane
ND 2.0 8/8/22 13:44 EEHg/L0.23 8/8/22SW-846 8260D11,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
ND 1.0 8/8/22 13:44 EEHg/L0.20 8/8/22SW-846 8260D11,2,4-Trimethylbenzene
ND 1.0 8/8/22 13:44 EEHg/L0.11 8/8/22SW-846 8260D11,3,5-Trimethylbenzene
ND 2.0 8/8/22 13:44 EEHg/L0.21 8/8/22SW-846 8260D1Vinyl Chloride
ND 2.0 8/8/22 13:44 EEHg/L0.46 8/8/22SW-846 8260D1m+p Xylene
ND 1.0 8/8/22 13:44 EEHg/L0.23 8/8/22SW-846 8260D1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 100 8/8/22 13:4470-130
Toluene-d8 98.5 8/8/22 13:4470-130
4-Bromofluorobenzene 98.9 8/8/22 13:4470-130
Page 8 of 24
Table of Contents
Page 13 of 29
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/6/2022
Work Order: 22H0366Sample Description:Project Location: Crown Food Mart
Sample ID: 22H0366-03
Field Sample #: SW03 179
Sample Matrix: Water
Sampled: 8/4/2022 12:25
[TOC_2]22H0366-03[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 8/8/22 14:11 EEHg/L2.0 8/8/22SW-846 8260D1Acetone
ND 5.0 8/8/22 14:11 EEHg/L0.55 8/8/22SW-846 8260D1Acrylonitrile
ND 0.50 8/8/22 14:11 EEHg/L0.14 8/8/22SW-846 8260D1tert-Amyl Methyl Ether (TAME)
ND 1.0 8/8/22 14:11 EEHg/L0.20 8/8/22SW-846 8260D1Benzene
ND 1.0 8/8/22 14:11 EEHg/L0.15 8/8/22SW-846 8260D1Bromobenzene
ND 1.0 8/8/22 14:11 EEHg/L0.31 8/8/22SW-846 8260D1Bromochloromethane
ND 0.50 8/8/22 14:11 EEHg/L0.18 8/8/22SW-846 8260D1Bromodichloromethane
ND 2.0 8/8/22 14:11 EEHg/L0.38 8/8/22SW-846 8260D1Bromoform
ND 2.0 8/8/22 14:11 EEHg/L1.5 8/8/22SW-846 8260D1Bromomethane
ND 20 8/8/22 14:11 EEHg/L1.6 8/8/22SW-846 8260D12-Butanone (MEK)
ND 20 8/8/22 14:11 EEHg/L4.7 8/8/22SW-846 8260D1tert-Butyl Alcohol (TBA)
ND 1.0 8/8/22 14:11 EEHg/L0.15 8/8/22SW-846 8260D1n-Butylbenzene
ND 1.0 8/8/22 14:11 EEHg/L0.11 8/8/22SW-846 8260D1sec-Butylbenzene
ND 1.0 8/8/22 14:11 EEHg/L0.13 8/8/22SW-846 8260D1tert-Butylbenzene
ND 0.50 8/8/22 14:11 EEHg/L0.15 8/8/22SW-846 8260D1tert-Butyl Ethyl Ether (TBEE)
ND 5.0 8/8/22 14:11 EEHg/L1.4 8/8/22SW-846 8260D1Carbon Disulfide
ND 1.0 8/8/22 14:11 EEHg/L0.16 8/8/22SW-846 8260D1Carbon Tetrachloride
ND 1.0 8/8/22 14:11 EEHg/L0.11 8/8/22SW-846 8260D1Chlorobenzene
ND 0.50 8/8/22 14:11 EEHg/L0.22 8/8/22SW-846 8260D1Chlorodibromomethane
ND 2.0 8/8/22 14:11 EEHg/L0.32 8/8/22SW-846 8260D1Chloroethane
ND 2.0 8/8/22 14:11 EEHg/L0.17 8/8/22SW-846 8260D1Chloroform
ND 2.0 8/8/22 14:11 EEHg/L0.52 8/8/22SW-846 8260D1Chloromethane
ND 1.0 8/8/22 14:11 EEHg/L0.11 8/8/22SW-846 8260D12-Chlorotoluene
ND 1.0 8/8/22 14:11 EEHg/L0.12 8/8/22SW-846 8260D14-Chlorotoluene
ND 5.0 8/8/22 14:11 EEHg/L0.80 8/8/22SW-846 8260D11,2-Dibromo-3-chloropropane (DBCP)
ND 0.50 8/8/22 14:11 EEHg/L0.17 8/8/22SW-846 8260D11,2-Dibromoethane (EDB)
ND 1.0 8/8/22 14:11 EEHg/L0.35 8/8/22SW-846 8260D1Dibromomethane
ND 1.0 8/8/22 14:11 EEHg/L0.12 8/8/22SW-846 8260D11,2-Dichlorobenzene
ND 1.0 8/8/22 14:11 EEHg/L0.12 8/8/22SW-846 8260D11,3-Dichlorobenzene
ND 1.0 8/8/22 14:11 EEHg/L0.13 8/8/22SW-846 8260D11,4-Dichlorobenzene
ND 2.0 8/8/22 14:11 EEHg/L1.6 8/8/22SW-846 8260D1trans-1,4-Dichloro-2-butene
ND 2.0 8/8/22 14:11 EEHg/L0.19 8/8/22SW-846 8260D1Dichlorodifluoromethane (Freon 12)
ND 1.0 8/8/22 14:11 EEHg/L0.14 8/8/22SW-846 8260D11,1-Dichloroethane
ND 1.0 8/8/22 14:11 EEHg/L0.31 8/8/22SW-846 8260D11,2-Dichloroethane
ND 1.0 8/8/22 14:11 EEHg/L0.14 8/8/22SW-846 8260D11,1-Dichloroethylene
ND 1.0 8/8/22 14:11 EEHg/L0.15 8/8/22SW-846 8260D1cis-1,2-Dichloroethylene
ND 1.0 8/8/22 14:11 EEHg/L0.17 8/8/22SW-846 8260D1trans-1,2-Dichloroethylene
ND 1.0 8/8/22 14:11 EEHg/L0.18 8/8/22SW-846 8260D11,2-Dichloropropane
ND 0.50 8/8/22 14:11 EEHg/L0.13 8/8/22SW-846 8260D11,3-Dichloropropane
ND 1.0 8/8/22 14:11 EEHg/L0.33 8/8/22SW-846 8260D12,2-Dichloropropane
ND 2.0 8/8/22 14:11 EEHg/L0.15 8/8/22SW-846 8260D11,1-Dichloropropene
ND 0.50 8/8/22 14:11 EEHg/L0.16 8/8/22SW-846 8260D1cis-1,3-Dichloropropene
ND 0.50 8/8/22 14:11 EEHg/L0.17 8/8/22SW-846 8260D1trans-1,3-Dichloropropene
ND 2.0 8/8/22 14:11 EEHg/L0.18 8/8/22SW-846 8260D1Diethyl Ether
Page 9 of 24
Table of Contents
Page 14 of 29
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/6/2022
Work Order: 22H0366Sample Description:Project Location: Crown Food Mart
Sample ID: 22H0366-03
Field Sample #: SW03 179
Sample Matrix: Water
Sampled: 8/4/2022 12:25
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 8/8/22 14:11 EEHg/L0.13 8/8/22SW-846 8260D1Diisopropyl Ether (DIPE)
ND 50 8/8/22 14:11 EEHg/L21 8/8/22SW-846 8260D11,4-Dioxane
ND 1.0 8/8/22 14:11 EEHg/L0.21 8/8/22SW-846 8260D1Ethylbenzene
ND 0.60 8/8/22 14:11 EEHg/L0.46 8/8/22SW-846 8260D1Hexachlorobutadiene
ND 10 8/8/22 14:11 EEHg/L1.1 8/8/22SW-846 8260D12-Hexanone (MBK)
ND 1.0 8/8/22 14:11 EEHg/L0.11 8/8/22SW-846 8260D1Isopropylbenzene (Cumene)
ND 1.0 8/8/22 14:11 EEHg/L0.097 8/8/22SW-846 8260D1p-Isopropyltoluene (p-Cymene)
ND 1.0 8/8/22 14:11 EEHg/L0.17 8/8/22SW-846 8260D1Methyl tert-Butyl Ether (MTBE)
0.24 5.0 8/8/22 14:11 EEHg/L0.23 8/8/22SW-846 8260D1JMethylene Chloride
ND 10 8/8/22 14:11 EEHg/L1.3 8/8/22SW-846 8260D14-Methyl-2-pentanone (MIBK)
ND 2.0 8/8/22 14:11 EEHg/L0.24 8/8/22SW-846 8260D1Naphthalene
ND 1.0 8/8/22 14:11 EEHg/L0.086 8/8/22SW-846 8260D1n-Propylbenzene
ND 1.0 8/8/22 14:11 EEHg/L0.11 8/8/22SW-846 8260D1Styrene
ND 1.0 8/8/22 14:11 EEHg/L0.18 8/8/22SW-846 8260D11,1,1,2-Tetrachloroethane
ND 0.50 8/8/22 14:11 EEHg/L0.13 8/8/22SW-846 8260D11,1,2,2-Tetrachloroethane
ND 1.0 8/8/22 14:11 EEHg/L0.19 8/8/22SW-846 8260D1Tetrachloroethylene
ND 10 8/8/22 14:11 EEHg/L0.49 8/8/22SW-846 8260D1Tetrahydrofuran
ND 1.0 8/8/22 14:11 EEHg/L0.22 8/8/22SW-846 8260D1Toluene
ND 5.0 8/8/22 14:11 EEHg/L0.30 8/8/22SW-846 8260D11,2,3-Trichlorobenzene
ND 1.0 8/8/22 14:11 EEHg/L0.25 8/8/22SW-846 8260D11,2,4-Trichlorobenzene
ND 1.0 8/8/22 14:11 EEHg/L0.21 8/8/22SW-846 8260D11,3,5-Trichlorobenzene
ND 1.0 8/8/22 14:11 EEHg/L0.17 8/8/22SW-846 8260D11,1,1-Trichloroethane
ND 1.0 8/8/22 14:11 EEHg/L0.18 8/8/22SW-846 8260D11,1,2-Trichloroethane
ND 1.0 8/8/22 14:11 EEHg/L0.19 8/8/22SW-846 8260D1Trichloroethylene
ND 2.0 8/8/22 14:11 EEHg/L0.18 8/8/22SW-846 8260D1Trichlorofluoromethane (Freon 11)
ND 2.0 8/8/22 14:11 EEHg/L0.28 8/8/22SW-846 8260D11,2,3-Trichloropropane
ND 2.0 8/8/22 14:11 EEHg/L0.23 8/8/22SW-846 8260D11,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
0.42 1.0 8/8/22 14:11 EEHg/L0.20 8/8/22SW-846 8260D1J1,2,4-Trimethylbenzene
0.12 1.0 8/8/22 14:11 EEHg/L0.11 8/8/22SW-846 8260D1J1,3,5-Trimethylbenzene
ND 2.0 8/8/22 14:11 EEHg/L0.21 8/8/22SW-846 8260D1Vinyl Chloride
0.46 2.0 8/8/22 14:11 EEHg/L0.46 8/8/22SW-846 8260D1Jm+p Xylene
ND 1.0 8/8/22 14:11 EEHg/L0.23 8/8/22SW-846 8260D1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 100 8/8/22 14:1170-130
Toluene-d8 98.0 8/8/22 14:1170-130
4-Bromofluorobenzene 101 8/8/22 14:1170-130
Page 10 of 24
Table of Contents
Page 15 of 29
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/6/2022
Work Order: 22H0366Sample Description:Project Location: Crown Food Mart
Sample ID: 22H0366-04
Field Sample #: SW04 179
Sample Matrix: Water
Sampled: 8/4/2022 12:45
[TOC_2]22H0366-04[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 8/8/22 14:39 EEHg/L2.0 8/8/22SW-846 8260D1Acetone
ND 5.0 8/8/22 14:39 EEHg/L0.55 8/8/22SW-846 8260D1Acrylonitrile
ND 0.50 8/8/22 14:39 EEHg/L0.14 8/8/22SW-846 8260D1tert-Amyl Methyl Ether (TAME)
ND 1.0 8/8/22 14:39 EEHg/L0.20 8/8/22SW-846 8260D1Benzene
ND 1.0 8/8/22 14:39 EEHg/L0.15 8/8/22SW-846 8260D1Bromobenzene
ND 1.0 8/8/22 14:39 EEHg/L0.31 8/8/22SW-846 8260D1Bromochloromethane
ND 0.50 8/8/22 14:39 EEHg/L0.18 8/8/22SW-846 8260D1Bromodichloromethane
ND 2.0 8/8/22 14:39 EEHg/L0.38 8/8/22SW-846 8260D1Bromoform
ND 2.0 8/8/22 14:39 EEHg/L1.5 8/8/22SW-846 8260D1Bromomethane
ND 20 8/8/22 14:39 EEHg/L1.6 8/8/22SW-846 8260D12-Butanone (MEK)
ND 20 8/8/22 14:39 EEHg/L4.7 8/8/22SW-846 8260D1tert-Butyl Alcohol (TBA)
ND 1.0 8/8/22 14:39 EEHg/L0.15 8/8/22SW-846 8260D1n-Butylbenzene
ND 1.0 8/8/22 14:39 EEHg/L0.11 8/8/22SW-846 8260D1sec-Butylbenzene
ND 1.0 8/8/22 14:39 EEHg/L0.13 8/8/22SW-846 8260D1tert-Butylbenzene
ND 0.50 8/8/22 14:39 EEHg/L0.15 8/8/22SW-846 8260D1tert-Butyl Ethyl Ether (TBEE)
ND 5.0 8/8/22 14:39 EEHg/L1.4 8/8/22SW-846 8260D1Carbon Disulfide
ND 1.0 8/8/22 14:39 EEHg/L0.16 8/8/22SW-846 8260D1Carbon Tetrachloride
ND 1.0 8/8/22 14:39 EEHg/L0.11 8/8/22SW-846 8260D1Chlorobenzene
ND 0.50 8/8/22 14:39 EEHg/L0.22 8/8/22SW-846 8260D1Chlorodibromomethane
ND 2.0 8/8/22 14:39 EEHg/L0.32 8/8/22SW-846 8260D1Chloroethane
ND 2.0 8/8/22 14:39 EEHg/L0.17 8/8/22SW-846 8260D1Chloroform
ND 2.0 8/8/22 14:39 EEHg/L0.52 8/8/22SW-846 8260D1Chloromethane
ND 1.0 8/8/22 14:39 EEHg/L0.11 8/8/22SW-846 8260D12-Chlorotoluene
ND 1.0 8/8/22 14:39 EEHg/L0.12 8/8/22SW-846 8260D14-Chlorotoluene
ND 5.0 8/8/22 14:39 EEHg/L0.80 8/8/22SW-846 8260D11,2-Dibromo-3-chloropropane (DBCP)
ND 0.50 8/8/22 14:39 EEHg/L0.17 8/8/22SW-846 8260D11,2-Dibromoethane (EDB)
ND 1.0 8/8/22 14:39 EEHg/L0.35 8/8/22SW-846 8260D1Dibromomethane
ND 1.0 8/8/22 14:39 EEHg/L0.12 8/8/22SW-846 8260D11,2-Dichlorobenzene
ND 1.0 8/8/22 14:39 EEHg/L0.12 8/8/22SW-846 8260D11,3-Dichlorobenzene
ND 1.0 8/8/22 14:39 EEHg/L0.13 8/8/22SW-846 8260D11,4-Dichlorobenzene
ND 2.0 8/8/22 14:39 EEHg/L1.6 8/8/22SW-846 8260D1trans-1,4-Dichloro-2-butene
ND 2.0 8/8/22 14:39 EEHg/L0.19 8/8/22SW-846 8260D1Dichlorodifluoromethane (Freon 12)
ND 1.0 8/8/22 14:39 EEHg/L0.14 8/8/22SW-846 8260D11,1-Dichloroethane
ND 1.0 8/8/22 14:39 EEHg/L0.31 8/8/22SW-846 8260D11,2-Dichloroethane
ND 1.0 8/8/22 14:39 EEHg/L0.14 8/8/22SW-846 8260D11,1-Dichloroethylene
ND 1.0 8/8/22 14:39 EEHg/L0.15 8/8/22SW-846 8260D1cis-1,2-Dichloroethylene
ND 1.0 8/8/22 14:39 EEHg/L0.17 8/8/22SW-846 8260D1trans-1,2-Dichloroethylene
ND 1.0 8/8/22 14:39 EEHg/L0.18 8/8/22SW-846 8260D11,2-Dichloropropane
ND 0.50 8/8/22 14:39 EEHg/L0.13 8/8/22SW-846 8260D11,3-Dichloropropane
ND 1.0 8/8/22 14:39 EEHg/L0.33 8/8/22SW-846 8260D12,2-Dichloropropane
ND 2.0 8/8/22 14:39 EEHg/L0.15 8/8/22SW-846 8260D11,1-Dichloropropene
ND 0.50 8/8/22 14:39 EEHg/L0.16 8/8/22SW-846 8260D1cis-1,3-Dichloropropene
ND 0.50 8/8/22 14:39 EEHg/L0.17 8/8/22SW-846 8260D1trans-1,3-Dichloropropene
ND 2.0 8/8/22 14:39 EEHg/L0.18 8/8/22SW-846 8260D1Diethyl Ether
Page 11 of 24
Table of Contents
Page 16 of 29
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/6/2022
Work Order: 22H0366Sample Description:Project Location: Crown Food Mart
Sample ID: 22H0366-04
Field Sample #: SW04 179
Sample Matrix: Water
Sampled: 8/4/2022 12:45
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 8/8/22 14:39 EEHg/L0.13 8/8/22SW-846 8260D1Diisopropyl Ether (DIPE)
ND 50 8/8/22 14:39 EEHg/L21 8/8/22SW-846 8260D11,4-Dioxane
ND 1.0 8/8/22 14:39 EEHg/L0.21 8/8/22SW-846 8260D1Ethylbenzene
ND 0.60 8/8/22 14:39 EEHg/L0.46 8/8/22SW-846 8260D1Hexachlorobutadiene
ND 10 8/8/22 14:39 EEHg/L1.1 8/8/22SW-846 8260D12-Hexanone (MBK)
ND 1.0 8/8/22 14:39 EEHg/L0.11 8/8/22SW-846 8260D1Isopropylbenzene (Cumene)
ND 1.0 8/8/22 14:39 EEHg/L0.097 8/8/22SW-846 8260D1p-Isopropyltoluene (p-Cymene)
ND 1.0 8/8/22 14:39 EEHg/L0.17 8/8/22SW-846 8260D1Methyl tert-Butyl Ether (MTBE)
ND 5.0 8/8/22 14:39 EEHg/L0.23 8/8/22SW-846 8260D1Methylene Chloride
ND 10 8/8/22 14:39 EEHg/L1.3 8/8/22SW-846 8260D14-Methyl-2-pentanone (MIBK)
ND 2.0 8/8/22 14:39 EEHg/L0.24 8/8/22SW-846 8260D1Naphthalene
ND 1.0 8/8/22 14:39 EEHg/L0.086 8/8/22SW-846 8260D1n-Propylbenzene
ND 1.0 8/8/22 14:39 EEHg/L0.11 8/8/22SW-846 8260D1Styrene
ND 1.0 8/8/22 14:39 EEHg/L0.18 8/8/22SW-846 8260D11,1,1,2-Tetrachloroethane
ND 0.50 8/8/22 14:39 EEHg/L0.13 8/8/22SW-846 8260D11,1,2,2-Tetrachloroethane
ND 1.0 8/8/22 14:39 EEHg/L0.19 8/8/22SW-846 8260D1Tetrachloroethylene
ND 10 8/8/22 14:39 EEHg/L0.49 8/8/22SW-846 8260D1Tetrahydrofuran
ND 1.0 8/8/22 14:39 EEHg/L0.22 8/8/22SW-846 8260D1Toluene
ND 5.0 8/8/22 14:39 EEHg/L0.30 8/8/22SW-846 8260D11,2,3-Trichlorobenzene
ND 1.0 8/8/22 14:39 EEHg/L0.25 8/8/22SW-846 8260D11,2,4-Trichlorobenzene
ND 1.0 8/8/22 14:39 EEHg/L0.21 8/8/22SW-846 8260D11,3,5-Trichlorobenzene
ND 1.0 8/8/22 14:39 EEHg/L0.17 8/8/22SW-846 8260D11,1,1-Trichloroethane
ND 1.0 8/8/22 14:39 EEHg/L0.18 8/8/22SW-846 8260D11,1,2-Trichloroethane
ND 1.0 8/8/22 14:39 EEHg/L0.19 8/8/22SW-846 8260D1Trichloroethylene
ND 2.0 8/8/22 14:39 EEHg/L0.18 8/8/22SW-846 8260D1Trichlorofluoromethane (Freon 11)
ND 2.0 8/8/22 14:39 EEHg/L0.28 8/8/22SW-846 8260D11,2,3-Trichloropropane
ND 2.0 8/8/22 14:39 EEHg/L0.23 8/8/22SW-846 8260D11,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
ND 1.0 8/8/22 14:39 EEHg/L0.20 8/8/22SW-846 8260D11,2,4-Trimethylbenzene
ND 1.0 8/8/22 14:39 EEHg/L0.11 8/8/22SW-846 8260D11,3,5-Trimethylbenzene
ND 2.0 8/8/22 14:39 EEHg/L0.21 8/8/22SW-846 8260D1Vinyl Chloride
ND 2.0 8/8/22 14:39 EEHg/L0.46 8/8/22SW-846 8260D1m+p Xylene
ND 1.0 8/8/22 14:39 EEHg/L0.23 8/8/22SW-846 8260D1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 100 8/8/22 14:3970-130
Toluene-d8 98.9 8/8/22 14:3970-130
4-Bromofluorobenzene 101 8/8/22 14:3970-130
Page 12 of 24
Table of Contents
Page 17 of 29
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
[TOC_2]Volatile Organic Compounds by GC/MS[TOC]
Batch B314680 - SW-846 5030B
[TOC_3]B314680[TOC]
Blank (B314680-BLK1) Prepared & Analyzed: 08/08/22
Acetone g/L50ND
Acrylonitrile g/L5.0ND
tert-Amyl Methyl Ether (TAME)g/L0.50ND
Benzene g/L1.0ND
Bromobenzene g/L1.0ND
Bromochloromethane g/L1.0ND
Bromodichloromethane g/L0.50ND
Bromoform g/L1.0ND
Bromomethane g/L2.0ND
2-Butanone (MEK)g/L20ND
tert-Butyl Alcohol (TBA)g/L20ND
n-Butylbenzene g/L1.0ND
sec-Butylbenzene g/L1.0ND
tert-Butylbenzene g/L1.0ND
tert-Butyl Ethyl Ether (TBEE)g/L0.50ND
Carbon Disulfide g/L5.0ND
Carbon Tetrachloride g/L1.0ND
Chlorobenzene g/L1.0ND
Chlorodibromomethane g/L0.50ND
Chloroethane g/L2.0ND
Chloroform g/L2.0ND
Chloromethane g/L2.0ND
2-Chlorotoluene g/L1.0ND
4-Chlorotoluene g/L1.0ND
1,2-Dibromo-3-chloropropane (DBCP)g/L5.0ND
1,2-Dibromoethane (EDB)g/L0.50ND
Dibromomethane g/L1.0ND
1,2-Dichlorobenzene g/L1.0ND
1,3-Dichlorobenzene g/L1.0ND
1,4-Dichlorobenzene g/L1.0ND
trans-1,4-Dichloro-2-butene g/L2.0ND
Dichlorodifluoromethane (Freon 12)g/L2.0ND
1,1-Dichloroethane g/L1.0ND
1,2-Dichloroethane g/L1.0ND
1,1-Dichloroethylene g/L1.0ND
cis-1,2-Dichloroethylene g/L1.0ND
trans-1,2-Dichloroethylene g/L1.0ND
1,2-Dichloropropane g/L1.0ND
1,3-Dichloropropane g/L0.50ND
2,2-Dichloropropane g/L1.0ND
1,1-Dichloropropene g/L2.0ND
cis-1,3-Dichloropropene g/L0.50ND
trans-1,3-Dichloropropene g/L0.50ND
Diethyl Ether g/L2.0ND
Diisopropyl Ether (DIPE)g/L0.50ND
1,4-Dioxane g/L50ND
Ethylbenzene g/L1.0ND
Hexachlorobutadiene g/L0.60ND
2-Hexanone (MBK)g/L10ND
Isopropylbenzene (Cumene)g/L1.0ND
p-Isopropyltoluene (p-Cymene)g/L1.0ND
Methyl tert-Butyl Ether (MTBE)g/L1.0ND
[TOC_1]QC Data[TOC]
Page 13 of 24
Table of Contents
Page 18 of 29
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B314680 - SW-846 5030B
Blank (B314680-BLK1) Prepared & Analyzed: 08/08/22
Methylene Chloride g/L5.0ND
4-Methyl-2-pentanone (MIBK)g/L10ND
Naphthalene g/L2.0ND
n-Propylbenzene g/L1.0ND
Styrene g/L1.0ND
1,1,1,2-Tetrachloroethane g/L1.0ND
1,1,2,2-Tetrachloroethane g/L0.50ND
Tetrachloroethylene g/L1.0ND
Tetrahydrofuran g/L10ND
Toluene g/L1.0ND
1,2,3-Trichlorobenzene g/L5.0ND
1,2,4-Trichlorobenzene g/L1.0ND
1,3,5-Trichlorobenzene g/L1.0ND
1,1,1-Trichloroethane g/L1.0ND
1,1,2-Trichloroethane g/L1.0ND
Trichloroethylene g/L1.0ND
Trichlorofluoromethane (Freon 11)g/L2.0ND
1,2,3-Trichloropropane g/L2.0ND
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon
113)
g/L1.0ND
1,2,4-Trimethylbenzene g/L1.0ND
1,3,5-Trimethylbenzene g/L1.0ND
Vinyl Chloride g/L2.0ND
m+p Xylene g/L2.0ND
o-Xylene g/L1.0ND
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 99.825.0
g/L 25.0 70-130Surrogate: Toluene-d8 97.524.4
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 10025.1
LCS (B314680-BS1) Prepared & Analyzed: 08/08/22
Acetone g/L50 100 70-16098.798.7
Acrylonitrile g/L5.0 10.0 70-13010510.5
tert-Amyl Methyl Ether (TAME)g/L0.50 10.0 70-13010810.8
Benzene g/L1.0 10.0 70-13010710.7
Bromobenzene g/L1.0 10.0 70-13012112.1
Bromochloromethane g/L1.0 10.0 70-13012212.2
Bromodichloromethane g/L0.50 10.0 70-13011411.4
Bromoform g/L1.0 10.0 70-13011711.7
Bromomethane g/L2.0 10.0 40-16012412.4
2-Butanone (MEK)g/L20 100 40-160108108
tert-Butyl Alcohol (TBA)g/L20 100 40-160106106
n-Butylbenzene g/L1.0 10.0 70-13011211.2
sec-Butylbenzene g/L1.0 10.0 70-13011111.1
tert-Butylbenzene g/L1.0 10.0 70-13011311.3
tert-Butyl Ethyl Ether (TBEE)g/L0.50 10.0 70-13011411.4
Carbon Disulfide g/L5.0 100 L-02, V-2070-130142*142
Carbon Tetrachloride g/L1.0 10.0 70-13011511.5
Chlorobenzene g/L1.0 10.0 70-13011211.2
Chlorodibromomethane g/L0.50 10.0 70-13011511.5
Chloroethane g/L2.0 10.0 70-13012112.1
Chloroform g/L2.0 10.0 70-13011011.0
Chloromethane g/L2.0 10.0 40-16013013.0
2-Chlorotoluene g/L1.0 10.0 70-13010910.9
Page 14 of 24
Table of Contents
Page 19 of 29
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B314680 - SW-846 5030B
LCS (B314680-BS1) Prepared & Analyzed: 08/08/22
4-Chlorotoluene g/L1.0 10.0 70-13011711.7
1,2-Dibromo-3-chloropropane (DBCP)g/L5.0 10.0 70-13010810.8
1,2-Dibromoethane (EDB)g/L0.50 10.0 70-13011111.1
Dibromomethane g/L1.0 10.0 70-13011211.2
1,2-Dichlorobenzene g/L1.0 10.0 70-13011311.3
1,3-Dichlorobenzene g/L1.0 10.0 70-13011211.2
1,4-Dichlorobenzene g/L1.0 10.0 70-13011211.2
trans-1,4-Dichloro-2-butene g/L2.0 10.0 70-13011311.3
Dichlorodifluoromethane (Freon 12)g/L2.0 10.0 40-16011311.3
1,1-Dichloroethane g/L1.0 10.0 70-13011311.3
1,2-Dichloroethane g/L1.0 10.0 70-13010810.8
1,1-Dichloroethylene g/L1.0 10.0 70-13010910.9
cis-1,2-Dichloroethylene g/L1.0 10.0 70-13011011.0
trans-1,2-Dichloroethylene g/L1.0 10.0 70-13010810.8
1,2-Dichloropropane g/L1.0 10.0 70-13011711.7
1,3-Dichloropropane g/L0.50 10.0 70-13011811.8
2,2-Dichloropropane g/L1.0 10.0 40-13011211.2
1,1-Dichloropropene g/L2.0 10.0 70-13011311.3
cis-1,3-Dichloropropene g/L0.50 10.0 70-13011511.5
trans-1,3-Dichloropropene g/L0.50 10.0 70-13011411.4
Diethyl Ether g/L2.0 10.0 70-13011211.2
Diisopropyl Ether (DIPE)g/L0.50 10.0 70-13011811.8
1,4-Dioxane g/L50 100 40-130104104
Ethylbenzene g/L1.0 10.0 70-13011911.9
Hexachlorobutadiene g/L0.60 10.0 L-07, V-2070-130132*13.2
2-Hexanone (MBK)g/L10 100 70-160117117
Isopropylbenzene (Cumene)g/L1.0 10.0 70-13011611.6
p-Isopropyltoluene (p-Cymene)g/L1.0 10.0 70-13010910.9
Methyl tert-Butyl Ether (MTBE)g/L1.0 10.0 70-13011211.2
Methylene Chloride g/L5.0 10.0 70-13011611.6
4-Methyl-2-pentanone (MIBK)g/L10 100 70-160119119
Naphthalene g/L2.0 10.0 40-13010910.9
n-Propylbenzene g/L1.0 10.0 70-13011711.7
Styrene g/L1.0 10.0 70-13011411.4
1,1,1,2-Tetrachloroethane g/L1.0 10.0 70-13011711.7
1,1,2,2-Tetrachloroethane g/L0.50 10.0 70-13011411.4
Tetrachloroethylene g/L1.0 10.0 70-13011911.9
Tetrahydrofuran g/L10 10.0 70-13011411.4
Toluene g/L1.0 10.0 70-13011211.2
1,2,3-Trichlorobenzene g/L5.0 10.0 70-13012912.9
1,2,4-Trichlorobenzene g/L1.0 10.0 70-13012112.1
1,3,5-Trichlorobenzene g/L1.0 10.0 70-13011211.2
1,1,1-Trichloroethane g/L1.0 10.0 70-13011511.5
1,1,2-Trichloroethane g/L1.0 10.0 70-13011811.8
Trichloroethylene g/L1.0 10.0 70-13011811.8
Trichlorofluoromethane (Freon 11)g/L2.0 10.0 70-13010410.4
1,2,3-Trichloropropane g/L2.0 10.0 70-13011311.3
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon
113)
g/L1.0 10.0 70-13012012.0
1,2,4-Trimethylbenzene g/L1.0 10.0 70-13011111.1
1,3,5-Trimethylbenzene g/L1.0 10.0 70-13011711.7
Vinyl Chloride g/L2.0 10.0 L-02, V-2040-160298*29.8
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Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B314680 - SW-846 5030B
LCS (B314680-BS1) Prepared & Analyzed: 08/08/22
m+p Xylene g/L2.0 20.0 70-13011823.7
o-Xylene g/L1.0 10.0 70-13012012.0
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 10125.2
g/L 25.0 70-130Surrogate: Toluene-d8 97.624.4
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 10425.9
LCS Dup (B314680-BSD1) Prepared & Analyzed: 08/08/22
Acetone g/L50 100 2570-16087.7 11.787.7
Acrylonitrile g/L5.0 10.0 2570-13098.1 6.609.81
tert-Amyl Methyl Ether (TAME)g/L0.50 10.0 2570-130107 1.3010.7
Benzene g/L1.0 10.0 2570-130103 3.5210.3
Bromobenzene g/L1.0 10.0 2570-130117 3.2811.7
Bromochloromethane g/L1.0 10.0 2570-130120 2.1512.0
Bromodichloromethane g/L0.50 10.0 2570-130108 5.6910.8
Bromoform g/L1.0 10.0 2570-130117 0.17111.7
Bromomethane g/L2.0 10.0 2540-160125 1.0512.5
2-Butanone (MEK)g/L20 100 2540-160107 1.40107
tert-Butyl Alcohol (TBA)g/L20 100 2540-160103 2.75103
n-Butylbenzene g/L1.0 10.0 2570-130111 0.72011.1
sec-Butylbenzene g/L1.0 10.0 2570-130110 1.1811.0
tert-Butylbenzene g/L1.0 10.0 2570-130112 0.89211.2
tert-Butyl Ethyl Ether (TBEE)g/L0.50 10.0 2570-130113 1.3211.3
Carbon Disulfide g/L5.0 100 25 L-02, V-2070-130147 3.25*147
Carbon Tetrachloride g/L1.0 10.0 2570-130109 5.8110.9
Chlorobenzene g/L1.0 10.0 2570-130110 2.0711.0
Chlorodibromomethane g/L0.50 10.0 2570-130116 0.17311.6
Chloroethane g/L2.0 10.0 2570-130120 0.49712.0
Chloroform g/L2.0 10.0 2570-130106 4.0710.6
Chloromethane g/L2.0 10.0 2540-160138 5.6713.8
2-Chlorotoluene g/L1.0 10.0 2570-130104 4.0410.4
4-Chlorotoluene g/L1.0 10.0 2570-130115 1.9011.5
1,2-Dibromo-3-chloropropane (DBCP)g/L5.0 10.0 2570-130106 1.5810.6
1,2-Dibromoethane (EDB)g/L0.50 10.0 2570-130108 3.0210.8
Dibromomethane g/L1.0 10.0 2570-130112 0.0011.2
1,2-Dichlorobenzene g/L1.0 10.0 2570-130113 0.26611.3
1,3-Dichlorobenzene g/L1.0 10.0 2570-130114 1.0611.4
1,4-Dichlorobenzene g/L1.0 10.0 2570-130113 1.1611.3
trans-1,4-Dichloro-2-butene g/L2.0 10.0 2570-130108 4.7110.8
Dichlorodifluoromethane (Freon 12)g/L2.0 10.0 2540-160104 7.5610.4
1,1-Dichloroethane g/L1.0 10.0 2570-130110 2.8711.0
1,2-Dichloroethane g/L1.0 10.0 2570-130103 4.8110.3
1,1-Dichloroethylene g/L1.0 10.0 2570-130103 5.3710.3
cis-1,2-Dichloroethylene g/L1.0 10.0 2570-130110 0.54511.0
trans-1,2-Dichloroethylene g/L1.0 10.0 2570-130103 4.6510.3
1,2-Dichloropropane g/L1.0 10.0 2570-130114 2.6911.4
1,3-Dichloropropane g/L0.50 10.0 2570-130112 4.7011.2
2,2-Dichloropropane g/L1.0 10.0 2540-130105 6.5410.5
1,1-Dichloropropene g/L2.0 10.0 2570-130108 5.2510.8
cis-1,3-Dichloropropene g/L0.50 10.0 2570-130109 5.0810.9
trans-1,3-Dichloropropene g/L0.50 10.0 2570-130112 1.0611.2
Diethyl Ether g/L2.0 10.0 2570-130101 10.610.1
Diisopropyl Ether (DIPE)g/L0.50 10.0 2570-130117 1.1911.7
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Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B314680 - SW-846 5030B
LCS Dup (B314680-BSD1) Prepared & Analyzed: 08/08/22
1,4-Dioxane g/L50 100 5040-13096.8 6.8296.8
Ethylbenzene g/L1.0 10.0 2570-130114 4.3811.4
Hexachlorobutadiene g/L0.60 10.0 25 V-2070-130127 4.2512.7
2-Hexanone (MBK)g/L10 100 2570-160116 1.02116
Isopropylbenzene (Cumene)g/L1.0 10.0 2570-130110 4.7911.0
p-Isopropyltoluene (p-Cymene)g/L1.0 10.0 2570-130112 2.9811.2
Methyl tert-Butyl Ether (MTBE)g/L1.0 10.0 2570-130109 2.9910.9
Methylene Chloride g/L5.0 10.0 2570-130107 7.7210.7
4-Methyl-2-pentanone (MIBK)g/L10 100 2570-160114 4.17114
Naphthalene g/L2.0 10.0 2540-130108 0.64710.8
n-Propylbenzene g/L1.0 10.0 2570-130112 4.8911.2
Styrene g/L1.0 10.0 2570-130109 3.9510.9
1,1,1,2-Tetrachloroethane g/L1.0 10.0 2570-130116 0.94211.6
1,1,2,2-Tetrachloroethane g/L0.50 10.0 2570-130113 0.87811.3
Tetrachloroethylene g/L1.0 10.0 2570-130119 0.083911.9
Tetrahydrofuran g/L10 10.0 2570-130107 5.6210.7
Toluene g/L1.0 10.0 2570-130108 3.5510.8
1,2,3-Trichlorobenzene g/L5.0 10.0 2570-130125 3.5412.5
1,2,4-Trichlorobenzene g/L1.0 10.0 2570-130115 5.1711.5
1,3,5-Trichlorobenzene g/L1.0 10.0 2570-130113 0.70911.3
1,1,1-Trichloroethane g/L1.0 10.0 2570-130110 4.1711.0
1,1,2-Trichloroethane g/L1.0 10.0 2570-130117 0.42611.7
Trichloroethylene g/L1.0 10.0 2570-130112 4.7911.2
Trichlorofluoromethane (Freon 11)g/L2.0 10.0 2570-13099.0 4.839.90
1,2,3-Trichloropropane g/L2.0 10.0 2570-130110 2.6011.0
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon
113)
g/L1.0 10.0 2570-130122 1.2412.2
1,2,4-Trimethylbenzene g/L1.0 10.0 2570-130110 0.99211.0
1,3,5-Trimethylbenzene g/L1.0 10.0 2570-130113 3.5611.3
Vinyl Chloride g/L2.0 10.0 25 L-02, V-2040-160294 1.08*29.4
m+p Xylene g/L2.0 20.0 2570-130114 3.4322.9
o-Xylene g/L1.0 10.0 2570-130114 5.0311.4
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 10225.6
g/L 25.0 70-130Surrogate: Toluene-d8 98.024.5
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 10225.4
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FLAG/QUALIFIER SUMMARY
*QC result is outside of established limits.
Wide recovery limits established for difficult compound.
Wide RPD limits established for difficult compound.
#Data exceeded client recommended or regulatory level
Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the
calculation which have not been rounded.
No results have been blank subtracted unless specified in the case narrative section.
RL Reporting Limit is at the level of quantitation (LOQ)
DL Detection Limit is the lower limit of detection determined by the MDL study
MCL Maximum Contaminant Level
ND Not Detected
Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated
concentration (CLP J-Flag).
J
Laboratory fortified blank/laboratory control sample recovery and duplicate recoveries outside of control limits.
Data validation is not affected since all results are "not detected" for associated samples in this batch and bias is
on the high side.
L-02
Either laboratory fortified blank/laboratory control sample or duplicate recovery is outside of control limits, but
the other is within limits. RPD between the two LFB/LCS results is within method specified criteria.
L-07
Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side.
Data validation is not affected since sample result was "not detected" for this compound.
V-20
[TOC_1]Flag/Qualifier Summary[TOC]
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CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
SW-846 8260D in Water
NCAcetone
NCAcrylonitrile
NCtert-Amyl Methyl Ether (TAME)
NCBenzene
NCBromobenzene
NCBromochloromethane
NCBromodichloromethane
NCBromoform
NCBromomethane
NC2-Butanone (MEK)
NCtert-Butyl Alcohol (TBA)
NCn-Butylbenzene
NCsec-Butylbenzene
NCtert-Butylbenzene
NCtert-Butyl Ethyl Ether (TBEE)
NCCarbon Disulfide
NCCarbon Tetrachloride
NCChlorobenzene
NCChlorodibromomethane
NCChloroethane
NCChloroform
NCChloromethane
NC2-Chlorotoluene
NC4-Chlorotoluene
NC1,2-Dibromo-3-chloropropane (DBCP)
NC1,2-Dibromoethane (EDB)
NCDibromomethane
NC1,2-Dichlorobenzene
NC1,3-Dichlorobenzene
NC1,4-Dichlorobenzene
NCtrans-1,4-Dichloro-2-butene
NCDichlorodifluoromethane (Freon 12)
NC1,1-Dichloroethane
NC1,2-Dichloroethane
NC1,1-Dichloroethylene
NCcis-1,2-Dichloroethylene
NCtrans-1,2-Dichloroethylene
NC1,2-Dichloropropane
NC1,3-Dichloropropane
NC2,2-Dichloropropane
NC1,1-Dichloropropene
NCcis-1,3-Dichloropropene
NCtrans-1,3-Dichloropropene
NCDiethyl Ether
NCDiisopropyl Ether (DIPE)
NC1,4-Dioxane
NCEthylbenzene
[TOC_1]Certifications[TOC]
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CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
SW-846 8260D in Water
NCHexachlorobutadiene
NC2-Hexanone (MBK)
NCIsopropylbenzene (Cumene)
NCp-Isopropyltoluene (p-Cymene)
NCMethyl tert-Butyl Ether (MTBE)
NCMethylene Chloride
NC4-Methyl-2-pentanone (MIBK)
NCNaphthalene
NCn-Propylbenzene
NCStyrene
NC1,1,1,2-Tetrachloroethane
NC1,1,2,2-Tetrachloroethane
NCTetrachloroethylene
NCTetrahydrofuran
NCToluene
NC1,2,3-Trichlorobenzene
NC1,2,4-Trichlorobenzene
NC1,3,5-Trichlorobenzene
NC1,1,1-Trichloroethane
NC1,1,2-Trichloroethane
NCTrichloroethylene
NCTrichlorofluoromethane (Freon 11)
NC1,2,3-Trichloropropane
NC1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)
NC1,2,4-Trimethylbenzene
NC1,3,5-Trimethylbenzene
NCVinyl Chloride
NCm+p Xylene
NCo-Xylene
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Con-Test, a Pace Environmental Laboratory, operates under the following certifications and accreditations:
Code Description Number Expires
100033AIHA-LAP, LLC - ISO 17025:2017AIHA 03/1/2024
M-MA100Massachusetts DEPMA 06/30/2023
PH-0165Connecticut Department of Public HealthCT 12/31/2022
10899 NELAPNew York State Department of HealthNY 04/1/2023
2516 NELAPNew Hampshire Environmental LabNH 02/5/2023
LAO00373Rhode Island Department of HealthRI 12/30/2022
652North Carolina Div. of Water QualityNC 12/31/2022
MA007 NELAPNew Jersey DEPNJ 06/30/2023
E871027 NELAPFlorida Department of HealthFL 06/30/2023
LL720741Vermont Department of Health Lead LaboratoryVT 07/30/2023
VT-255716Vermont Department of Health Drinking WaterVT-DW 06/12/2023
MA00100State of MaineME 06/9/2023
460217Commonwealth of VirginiaVA 12/14/2022
2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2022
25703North Carolina Department of Health and Human ServicesNC-DW 07/31/2023
68-05812Commonwealth of Pennsylvania DEPPA 06/30/2023
9100Dept. of Env, Great Lakes, and EnergyMI 09/6/2022
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#=CL#
August 31, 2022
LIMS USE: FR - ROBERT MARTIN
LIMS OBJECT ID: 92621480
92621480
Project:
Pace Project No.:
RE:
Mr. Robert Martin
Martin and Slagle
24 Lookout Terrace
Black Mountain, NC 28711
CROWN FOOD MART 8/18/22
Dear Mr. Martin:
Enclosed are the analytical results for sample(s) received by the laboratory on August 19, 2022. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lorri Patton
[e-mail]
Project Manager
1(828)254-7176
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 1 of 30
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92621480
CROWN FOOD MART 8/18/22
Lab ID Sample ID Matrix Date Collected Date Received
92621480001 SW 01 180 Water 08/18/22 11:45 08/19/22 10:30
92621480002 SW 02 180 Water 08/18/22 12:30 08/19/22 10:30
92621480003 SW 03 180 Water 08/18/22 12:45 08/19/22 10:30
92621480004 SW 04 180 Water 08/18/22 13:00 08/19/22 10:30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 2 of 30
Page 3 of 30
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
August 30, 2022
Lorri Patton
Pace Analytical Services - NC
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Project Location: Crown Food Mart 8/18/22
Client Job Number:
Project Number: 92621480
Laboratory Work Order Number: 22H1227
Enclosed are results of analyses for samples as received by the laboratory on August 20, 2022. If you have any questions
concerning this report, please feel free to contact me.
Sincerely,
Kerry K. McGee
Project Manager
Page 1 of 25
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Table of Contents
Sample Summary 3
Case Narrative 4
Sample Results 5
22H1227-01 5
22H1227-02 7
22H1227-03 9
22H1227-04 11
Sample Preparation Information 13
QC Data 14
Volatile Organic Compounds by GC/MS 14
B315693 14
Flag/Qualifier Summary 19
Certifications 20
Chain of Custody/Sample Receipt 23
Page 2 of 25
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ANALYTICAL SUMMARY
8/30/2022
Pace Analytical Services - NC
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
ATTN: Lorri Patton
92621480
22H1227
The results of analyses performed on the following samples submitted to CON-TEST, a Pace Analytical Laboratory, are found in this report.
PROJECT LOCATION:
PURCHASE ORDER NUMBER:
PROJECT NUMBER:
REPORT DATE:
WORK ORDER NUMBER:
FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB
Crown Food Mart 8/18/22
SW 01 180 22H1227-01 Water SW-846 8260D
SW 02 180 22H1227-02 Water SW-846 8260D
SW 03 180 22H1227-03 Water SW-846 8260D
SW 04 180 22H1227-04 Water SW-846 8260D
[TOC_1]Sample Summary[TOC]
Page 3 of 25
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CASE NARRATIVE SUMMARY
All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report.
[TOC_1]Case Narrative[TOC]
SW-846 8260D
Qualifications:
Continuing calibration verification (CCV) did not meet method specifications and was biased on the low side for this compound.
Analyte & Samples(s) Qualified:
V-05
Acetone
22H1227-01[SW 01 180], 22H1227-02[SW 02 180], 22H1227-03[SW 03 180], 22H1227-04[SW 04 180], B315693-BLK1, B315693-BS1, B315693-BSD1, S075679-CCV1
Naphthalene
22H1227-01[SW 01 180], 22H1227-02[SW 02 180], 22H1227-03[SW 03 180], 22H1227-04[SW 04 180], B315693-BLK1, B315693-BS1, B315693-BSD1, S075679-CCV1
tert-Butyl Alcohol (TBA)
22H1227-01[SW 01 180], 22H1227-02[SW 02 180], 22H1227-03[SW 03 180], 22H1227-04[SW 04 180], B315693-BLK1, B315693-BS1, B315693-BSD1, S075679-CCV1
trans-1,4-Dichloro-2-butene
22H1227-01[SW 01 180], 22H1227-02[SW 02 180], 22H1227-03[SW 03 180], 22H1227-04[SW 04 180], B315693-BLK1, B315693-BS1, B315693-BSD1, S075679-CCV1
Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side. Data validation is not affected
since sample result was "not detected" for this compound.
Analyte & Samples(s) Qualified:
V-20
Hexachlorobutadiene
B315693-BS1, B315693-BSD1, S075679-CCV1
The results of analyses reported only relate to samples submitted to Con-Test, a Pace Analytical Laboratory, for testing.
I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed
in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the
best of my knowledge and belief, accurate and complete.
Tod E. Kopyscinski
Laboratory Director
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Date Received: 8/20/2022
Work Order: 22H1227Sample Description:Project Location: Crown Food Mart 8/18/22
Sample ID: 22H1227-01
Field Sample #: SW 01 180
Sample Matrix: Water
Sampled: 8/18/2022 11:45
[TOC_2]22H1227-01[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 8/23/22 16:06 MFFg/L2.0 8/23/22SW-846 8260D1V-05Acetone
ND 5.0 8/23/22 16:06 MFFg/L0.55 8/23/22SW-846 8260D1Acrylonitrile
ND 0.50 8/23/22 16:06 MFFg/L0.14 8/23/22SW-846 8260D1tert-Amyl Methyl Ether (TAME)
ND 1.0 8/23/22 16:06 MFFg/L0.20 8/23/22SW-846 8260D1Benzene
ND 1.0 8/23/22 16:06 MFFg/L0.15 8/23/22SW-846 8260D1Bromobenzene
ND 1.0 8/23/22 16:06 MFFg/L0.31 8/23/22SW-846 8260D1Bromochloromethane
ND 0.50 8/23/22 16:06 MFFg/L0.18 8/23/22SW-846 8260D1Bromodichloromethane
ND 1.0 8/23/22 16:06 MFFg/L0.38 8/23/22SW-846 8260D1Bromoform
ND 2.0 8/23/22 16:06 MFFg/L1.5 8/23/22SW-846 8260D1Bromomethane
ND 20 8/23/22 16:06 MFFg/L1.6 8/23/22SW-846 8260D12-Butanone (MEK)
ND 20 8/23/22 16:06 MFFg/L4.7 8/23/22SW-846 8260D1V-05tert-Butyl Alcohol (TBA)
ND 1.0 8/23/22 16:06 MFFg/L0.15 8/23/22SW-846 8260D1n-Butylbenzene
ND 1.0 8/23/22 16:06 MFFg/L0.11 8/23/22SW-846 8260D1sec-Butylbenzene
ND 1.0 8/23/22 16:06 MFFg/L0.13 8/23/22SW-846 8260D1tert-Butylbenzene
ND 0.50 8/23/22 16:06 MFFg/L0.15 8/23/22SW-846 8260D1tert-Butyl Ethyl Ether (TBEE)
ND 5.0 8/23/22 16:06 MFFg/L1.4 8/23/22SW-846 8260D1Carbon Disulfide
ND 1.0 8/23/22 16:06 MFFg/L0.16 8/23/22SW-846 8260D1Carbon Tetrachloride
ND 1.0 8/23/22 16:06 MFFg/L0.11 8/23/22SW-846 8260D1Chlorobenzene
ND 0.50 8/23/22 16:06 MFFg/L0.22 8/23/22SW-846 8260D1Chlorodibromomethane
ND 2.0 8/23/22 16:06 MFFg/L0.32 8/23/22SW-846 8260D1Chloroethane
ND 2.0 8/23/22 16:06 MFFg/L0.17 8/23/22SW-846 8260D1Chloroform
ND 2.0 8/23/22 16:06 MFFg/L0.52 8/23/22SW-846 8260D1Chloromethane
ND 1.0 8/23/22 16:06 MFFg/L0.11 8/23/22SW-846 8260D12-Chlorotoluene
ND 1.0 8/23/22 16:06 MFFg/L0.12 8/23/22SW-846 8260D14-Chlorotoluene
ND 5.0 8/23/22 16:06 MFFg/L0.80 8/23/22SW-846 8260D11,2-Dibromo-3-chloropropane (DBCP)
ND 0.50 8/23/22 16:06 MFFg/L0.17 8/23/22SW-846 8260D11,2-Dibromoethane (EDB)
ND 1.0 8/23/22 16:06 MFFg/L0.35 8/23/22SW-846 8260D1Dibromomethane
ND 1.0 8/23/22 16:06 MFFg/L0.12 8/23/22SW-846 8260D11,2-Dichlorobenzene
ND 1.0 8/23/22 16:06 MFFg/L0.12 8/23/22SW-846 8260D11,3-Dichlorobenzene
ND 1.0 8/23/22 16:06 MFFg/L0.13 8/23/22SW-846 8260D11,4-Dichlorobenzene
ND 2.0 8/23/22 16:06 MFFg/L1.6 8/23/22SW-846 8260D1V-05trans-1,4-Dichloro-2-butene
ND 2.0 8/23/22 16:06 MFFg/L0.19 8/23/22SW-846 8260D1Dichlorodifluoromethane (Freon 12)
ND 1.0 8/23/22 16:06 MFFg/L0.14 8/23/22SW-846 8260D11,1-Dichloroethane
ND 1.0 8/23/22 16:06 MFFg/L0.31 8/23/22SW-846 8260D11,2-Dichloroethane
ND 1.0 8/23/22 16:06 MFFg/L0.14 8/23/22SW-846 8260D11,1-Dichloroethylene
ND 1.0 8/23/22 16:06 MFFg/L0.15 8/23/22SW-846 8260D1cis-1,2-Dichloroethylene
ND 1.0 8/23/22 16:06 MFFg/L0.17 8/23/22SW-846 8260D1trans-1,2-Dichloroethylene
ND 1.0 8/23/22 16:06 MFFg/L0.18 8/23/22SW-846 8260D11,2-Dichloropropane
ND 0.50 8/23/22 16:06 MFFg/L0.13 8/23/22SW-846 8260D11,3-Dichloropropane
ND 1.0 8/23/22 16:06 MFFg/L0.33 8/23/22SW-846 8260D12,2-Dichloropropane
ND 2.0 8/23/22 16:06 MFFg/L0.15 8/23/22SW-846 8260D11,1-Dichloropropene
ND 0.50 8/23/22 16:06 MFFg/L0.16 8/23/22SW-846 8260D1cis-1,3-Dichloropropene
ND 0.50 8/23/22 16:06 MFFg/L0.17 8/23/22SW-846 8260D1trans-1,3-Dichloropropene
ND 2.0 8/23/22 16:06 MFFg/L0.18 8/23/22SW-846 8260D1Diethyl Ether
[TOC_1]Sample Results[TOC]
Page 5 of 25
Table of Contents
Page 10 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/20/2022
Work Order: 22H1227Sample Description:Project Location: Crown Food Mart 8/18/22
Sample ID: 22H1227-01
Field Sample #: SW 01 180
Sample Matrix: Water
Sampled: 8/18/2022 11:45
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 8/23/22 16:06 MFFg/L0.13 8/23/22SW-846 8260D1Diisopropyl Ether (DIPE)
ND 50 8/23/22 16:06 MFFg/L21 8/23/22SW-846 8260D11,4-Dioxane
ND 1.0 8/23/22 16:06 MFFg/L0.21 8/23/22SW-846 8260D1Ethylbenzene
ND 0.60 8/23/22 16:06 MFFg/L0.46 8/23/22SW-846 8260D1Hexachlorobutadiene
ND 10 8/23/22 16:06 MFFg/L1.1 8/23/22SW-846 8260D12-Hexanone (MBK)
ND 1.0 8/23/22 16:06 MFFg/L0.11 8/23/22SW-846 8260D1Isopropylbenzene (Cumene)
ND 1.0 8/23/22 16:06 MFFg/L0.097 8/23/22SW-846 8260D1p-Isopropyltoluene (p-Cymene)
ND 1.0 8/23/22 16:06 MFFg/L0.17 8/23/22SW-846 8260D1Methyl tert-Butyl Ether (MTBE)
ND 5.0 8/23/22 16:06 MFFg/L0.23 8/23/22SW-846 8260D1Methylene Chloride
ND 10 8/23/22 16:06 MFFg/L1.3 8/23/22SW-846 8260D14-Methyl-2-pentanone (MIBK)
ND 2.0 8/23/22 16:06 MFFg/L0.24 8/23/22SW-846 8260D1V-05Naphthalene
ND 1.0 8/23/22 16:06 MFFg/L0.086 8/23/22SW-846 8260D1n-Propylbenzene
ND 1.0 8/23/22 16:06 MFFg/L0.11 8/23/22SW-846 8260D1Styrene
ND 1.0 8/23/22 16:06 MFFg/L0.18 8/23/22SW-846 8260D11,1,1,2-Tetrachloroethane
ND 0.50 8/23/22 16:06 MFFg/L0.13 8/23/22SW-846 8260D11,1,2,2-Tetrachloroethane
ND 1.0 8/23/22 16:06 MFFg/L0.19 8/23/22SW-846 8260D1Tetrachloroethylene
ND 10 8/23/22 16:06 MFFg/L0.49 8/23/22SW-846 8260D1Tetrahydrofuran
ND 1.0 8/23/22 16:06 MFFg/L0.22 8/23/22SW-846 8260D1Toluene
ND 5.0 8/23/22 16:06 MFFg/L0.30 8/23/22SW-846 8260D11,2,3-Trichlorobenzene
ND 1.0 8/23/22 16:06 MFFg/L0.25 8/23/22SW-846 8260D11,2,4-Trichlorobenzene
ND 1.0 8/23/22 16:06 MFFg/L0.21 8/23/22SW-846 8260D11,3,5-Trichlorobenzene
ND 1.0 8/23/22 16:06 MFFg/L0.17 8/23/22SW-846 8260D11,1,1-Trichloroethane
ND 1.0 8/23/22 16:06 MFFg/L0.18 8/23/22SW-846 8260D11,1,2-Trichloroethane
ND 1.0 8/23/22 16:06 MFFg/L0.19 8/23/22SW-846 8260D1Trichloroethylene
ND 2.0 8/23/22 16:06 MFFg/L0.18 8/23/22SW-846 8260D1Trichlorofluoromethane (Freon 11)
ND 2.0 8/23/22 16:06 MFFg/L0.28 8/23/22SW-846 8260D11,2,3-Trichloropropane
ND 1.0 8/23/22 16:06 MFFg/L0.23 8/23/22SW-846 8260D11,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
ND 1.0 8/23/22 16:06 MFFg/L0.20 8/23/22SW-846 8260D11,2,4-Trimethylbenzene
ND 1.0 8/23/22 16:06 MFFg/L0.11 8/23/22SW-846 8260D11,3,5-Trimethylbenzene
ND 2.0 8/23/22 16:06 MFFg/L0.21 8/23/22SW-846 8260D1Vinyl Chloride
ND 2.0 8/23/22 16:06 MFFg/L0.46 8/23/22SW-846 8260D1m+p Xylene
ND 1.0 8/23/22 16:06 MFFg/L0.23 8/23/22SW-846 8260D1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 96.6 8/23/22 16:0670-130
Toluene-d8 96.5 8/23/22 16:0670-130
4-Bromofluorobenzene 100 8/23/22 16:0670-130
Page 6 of 25
Table of Contents
Page 11 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/20/2022
Work Order: 22H1227Sample Description:Project Location: Crown Food Mart 8/18/22
Sample ID: 22H1227-02
Field Sample #: SW 02 180
Sample Matrix: Water
Sampled: 8/18/2022 12:30
[TOC_2]22H1227-02[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 8/23/22 16:30 MFFg/L2.0 8/23/22SW-846 8260D1V-05Acetone
ND 5.0 8/23/22 16:30 MFFg/L0.55 8/23/22SW-846 8260D1Acrylonitrile
ND 0.50 8/23/22 16:30 MFFg/L0.14 8/23/22SW-846 8260D1tert-Amyl Methyl Ether (TAME)
ND 1.0 8/23/22 16:30 MFFg/L0.20 8/23/22SW-846 8260D1Benzene
ND 1.0 8/23/22 16:30 MFFg/L0.15 8/23/22SW-846 8260D1Bromobenzene
ND 1.0 8/23/22 16:30 MFFg/L0.31 8/23/22SW-846 8260D1Bromochloromethane
ND 0.50 8/23/22 16:30 MFFg/L0.18 8/23/22SW-846 8260D1Bromodichloromethane
ND 1.0 8/23/22 16:30 MFFg/L0.38 8/23/22SW-846 8260D1Bromoform
ND 2.0 8/23/22 16:30 MFFg/L1.5 8/23/22SW-846 8260D1Bromomethane
ND 20 8/23/22 16:30 MFFg/L1.6 8/23/22SW-846 8260D12-Butanone (MEK)
ND 20 8/23/22 16:30 MFFg/L4.7 8/23/22SW-846 8260D1V-05tert-Butyl Alcohol (TBA)
ND 1.0 8/23/22 16:30 MFFg/L0.15 8/23/22SW-846 8260D1n-Butylbenzene
ND 1.0 8/23/22 16:30 MFFg/L0.11 8/23/22SW-846 8260D1sec-Butylbenzene
ND 1.0 8/23/22 16:30 MFFg/L0.13 8/23/22SW-846 8260D1tert-Butylbenzene
ND 0.50 8/23/22 16:30 MFFg/L0.15 8/23/22SW-846 8260D1tert-Butyl Ethyl Ether (TBEE)
ND 5.0 8/23/22 16:30 MFFg/L1.4 8/23/22SW-846 8260D1Carbon Disulfide
ND 1.0 8/23/22 16:30 MFFg/L0.16 8/23/22SW-846 8260D1Carbon Tetrachloride
ND 1.0 8/23/22 16:30 MFFg/L0.11 8/23/22SW-846 8260D1Chlorobenzene
ND 0.50 8/23/22 16:30 MFFg/L0.22 8/23/22SW-846 8260D1Chlorodibromomethane
ND 2.0 8/23/22 16:30 MFFg/L0.32 8/23/22SW-846 8260D1Chloroethane
ND 2.0 8/23/22 16:30 MFFg/L0.17 8/23/22SW-846 8260D1Chloroform
ND 2.0 8/23/22 16:30 MFFg/L0.52 8/23/22SW-846 8260D1Chloromethane
ND 1.0 8/23/22 16:30 MFFg/L0.11 8/23/22SW-846 8260D12-Chlorotoluene
ND 1.0 8/23/22 16:30 MFFg/L0.12 8/23/22SW-846 8260D14-Chlorotoluene
ND 5.0 8/23/22 16:30 MFFg/L0.80 8/23/22SW-846 8260D11,2-Dibromo-3-chloropropane (DBCP)
ND 0.50 8/23/22 16:30 MFFg/L0.17 8/23/22SW-846 8260D11,2-Dibromoethane (EDB)
ND 1.0 8/23/22 16:30 MFFg/L0.35 8/23/22SW-846 8260D1Dibromomethane
ND 1.0 8/23/22 16:30 MFFg/L0.12 8/23/22SW-846 8260D11,2-Dichlorobenzene
ND 1.0 8/23/22 16:30 MFFg/L0.12 8/23/22SW-846 8260D11,3-Dichlorobenzene
ND 1.0 8/23/22 16:30 MFFg/L0.13 8/23/22SW-846 8260D11,4-Dichlorobenzene
ND 2.0 8/23/22 16:30 MFFg/L1.6 8/23/22SW-846 8260D1V-05trans-1,4-Dichloro-2-butene
ND 2.0 8/23/22 16:30 MFFg/L0.19 8/23/22SW-846 8260D1Dichlorodifluoromethane (Freon 12)
ND 1.0 8/23/22 16:30 MFFg/L0.14 8/23/22SW-846 8260D11,1-Dichloroethane
ND 1.0 8/23/22 16:30 MFFg/L0.31 8/23/22SW-846 8260D11,2-Dichloroethane
ND 1.0 8/23/22 16:30 MFFg/L0.14 8/23/22SW-846 8260D11,1-Dichloroethylene
ND 1.0 8/23/22 16:30 MFFg/L0.15 8/23/22SW-846 8260D1cis-1,2-Dichloroethylene
ND 1.0 8/23/22 16:30 MFFg/L0.17 8/23/22SW-846 8260D1trans-1,2-Dichloroethylene
ND 1.0 8/23/22 16:30 MFFg/L0.18 8/23/22SW-846 8260D11,2-Dichloropropane
ND 0.50 8/23/22 16:30 MFFg/L0.13 8/23/22SW-846 8260D11,3-Dichloropropane
ND 1.0 8/23/22 16:30 MFFg/L0.33 8/23/22SW-846 8260D12,2-Dichloropropane
ND 2.0 8/23/22 16:30 MFFg/L0.15 8/23/22SW-846 8260D11,1-Dichloropropene
ND 0.50 8/23/22 16:30 MFFg/L0.16 8/23/22SW-846 8260D1cis-1,3-Dichloropropene
ND 0.50 8/23/22 16:30 MFFg/L0.17 8/23/22SW-846 8260D1trans-1,3-Dichloropropene
ND 2.0 8/23/22 16:30 MFFg/L0.18 8/23/22SW-846 8260D1Diethyl Ether
Page 7 of 25
Table of Contents
Page 12 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/20/2022
Work Order: 22H1227Sample Description:Project Location: Crown Food Mart 8/18/22
Sample ID: 22H1227-02
Field Sample #: SW 02 180
Sample Matrix: Water
Sampled: 8/18/2022 12:30
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 8/23/22 16:30 MFFg/L0.13 8/23/22SW-846 8260D1Diisopropyl Ether (DIPE)
ND 50 8/23/22 16:30 MFFg/L21 8/23/22SW-846 8260D11,4-Dioxane
ND 1.0 8/23/22 16:30 MFFg/L0.21 8/23/22SW-846 8260D1Ethylbenzene
ND 0.60 8/23/22 16:30 MFFg/L0.46 8/23/22SW-846 8260D1Hexachlorobutadiene
ND 10 8/23/22 16:30 MFFg/L1.1 8/23/22SW-846 8260D12-Hexanone (MBK)
ND 1.0 8/23/22 16:30 MFFg/L0.11 8/23/22SW-846 8260D1Isopropylbenzene (Cumene)
ND 1.0 8/23/22 16:30 MFFg/L0.097 8/23/22SW-846 8260D1p-Isopropyltoluene (p-Cymene)
ND 1.0 8/23/22 16:30 MFFg/L0.17 8/23/22SW-846 8260D1Methyl tert-Butyl Ether (MTBE)
ND 5.0 8/23/22 16:30 MFFg/L0.23 8/23/22SW-846 8260D1Methylene Chloride
ND 10 8/23/22 16:30 MFFg/L1.3 8/23/22SW-846 8260D14-Methyl-2-pentanone (MIBK)
ND 2.0 8/23/22 16:30 MFFg/L0.24 8/23/22SW-846 8260D1V-05Naphthalene
0.16 1.0 8/23/22 16:30 MFFg/L0.086 8/23/22SW-846 8260D1Jn-Propylbenzene
ND 1.0 8/23/22 16:30 MFFg/L0.11 8/23/22SW-846 8260D1Styrene
ND 1.0 8/23/22 16:30 MFFg/L0.18 8/23/22SW-846 8260D11,1,1,2-Tetrachloroethane
ND 0.50 8/23/22 16:30 MFFg/L0.13 8/23/22SW-846 8260D11,1,2,2-Tetrachloroethane
ND 1.0 8/23/22 16:30 MFFg/L0.19 8/23/22SW-846 8260D1Tetrachloroethylene
ND 10 8/23/22 16:30 MFFg/L0.49 8/23/22SW-846 8260D1Tetrahydrofuran
ND 1.0 8/23/22 16:30 MFFg/L0.22 8/23/22SW-846 8260D1Toluene
ND 5.0 8/23/22 16:30 MFFg/L0.30 8/23/22SW-846 8260D11,2,3-Trichlorobenzene
ND 1.0 8/23/22 16:30 MFFg/L0.25 8/23/22SW-846 8260D11,2,4-Trichlorobenzene
ND 1.0 8/23/22 16:30 MFFg/L0.21 8/23/22SW-846 8260D11,3,5-Trichlorobenzene
ND 1.0 8/23/22 16:30 MFFg/L0.17 8/23/22SW-846 8260D11,1,1-Trichloroethane
ND 1.0 8/23/22 16:30 MFFg/L0.18 8/23/22SW-846 8260D11,1,2-Trichloroethane
ND 1.0 8/23/22 16:30 MFFg/L0.19 8/23/22SW-846 8260D1Trichloroethylene
ND 2.0 8/23/22 16:30 MFFg/L0.18 8/23/22SW-846 8260D1Trichlorofluoromethane (Freon 11)
ND 2.0 8/23/22 16:30 MFFg/L0.28 8/23/22SW-846 8260D11,2,3-Trichloropropane
ND 1.0 8/23/22 16:30 MFFg/L0.23 8/23/22SW-846 8260D11,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
0.99 1.0 8/23/22 16:30 MFFg/L0.20 8/23/22SW-846 8260D1J1,2,4-Trimethylbenzene
ND 1.0 8/23/22 16:30 MFFg/L0.11 8/23/22SW-846 8260D11,3,5-Trimethylbenzene
ND 2.0 8/23/22 16:30 MFFg/L0.21 8/23/22SW-846 8260D1Vinyl Chloride
ND 2.0 8/23/22 16:30 MFFg/L0.46 8/23/22SW-846 8260D1m+p Xylene
ND 1.0 8/23/22 16:30 MFFg/L0.23 8/23/22SW-846 8260D1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 97.5 8/23/22 16:3070-130
Toluene-d8 97.5 8/23/22 16:3070-130
4-Bromofluorobenzene 99.9 8/23/22 16:3070-130
Page 8 of 25
Table of Contents
Page 13 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/20/2022
Work Order: 22H1227Sample Description:Project Location: Crown Food Mart 8/18/22
Sample ID: 22H1227-03
Field Sample #: SW 03 180
Sample Matrix: Water
Sampled: 8/18/2022 12:45
[TOC_2]22H1227-03[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 8/23/22 16:54 MFFg/L2.0 8/23/22SW-846 8260D1V-05Acetone
ND 5.0 8/23/22 16:54 MFFg/L0.55 8/23/22SW-846 8260D1Acrylonitrile
ND 0.50 8/23/22 16:54 MFFg/L0.14 8/23/22SW-846 8260D1tert-Amyl Methyl Ether (TAME)
ND 1.0 8/23/22 16:54 MFFg/L0.20 8/23/22SW-846 8260D1Benzene
ND 1.0 8/23/22 16:54 MFFg/L0.15 8/23/22SW-846 8260D1Bromobenzene
ND 1.0 8/23/22 16:54 MFFg/L0.31 8/23/22SW-846 8260D1Bromochloromethane
ND 0.50 8/23/22 16:54 MFFg/L0.18 8/23/22SW-846 8260D1Bromodichloromethane
ND 1.0 8/23/22 16:54 MFFg/L0.38 8/23/22SW-846 8260D1Bromoform
ND 2.0 8/23/22 16:54 MFFg/L1.5 8/23/22SW-846 8260D1Bromomethane
ND 20 8/23/22 16:54 MFFg/L1.6 8/23/22SW-846 8260D12-Butanone (MEK)
ND 20 8/23/22 16:54 MFFg/L4.7 8/23/22SW-846 8260D1V-05tert-Butyl Alcohol (TBA)
ND 1.0 8/23/22 16:54 MFFg/L0.15 8/23/22SW-846 8260D1n-Butylbenzene
ND 1.0 8/23/22 16:54 MFFg/L0.11 8/23/22SW-846 8260D1sec-Butylbenzene
ND 1.0 8/23/22 16:54 MFFg/L0.13 8/23/22SW-846 8260D1tert-Butylbenzene
ND 0.50 8/23/22 16:54 MFFg/L0.15 8/23/22SW-846 8260D1tert-Butyl Ethyl Ether (TBEE)
ND 5.0 8/23/22 16:54 MFFg/L1.4 8/23/22SW-846 8260D1Carbon Disulfide
ND 1.0 8/23/22 16:54 MFFg/L0.16 8/23/22SW-846 8260D1Carbon Tetrachloride
ND 1.0 8/23/22 16:54 MFFg/L0.11 8/23/22SW-846 8260D1Chlorobenzene
ND 0.50 8/23/22 16:54 MFFg/L0.22 8/23/22SW-846 8260D1Chlorodibromomethane
ND 2.0 8/23/22 16:54 MFFg/L0.32 8/23/22SW-846 8260D1Chloroethane
ND 2.0 8/23/22 16:54 MFFg/L0.17 8/23/22SW-846 8260D1Chloroform
ND 2.0 8/23/22 16:54 MFFg/L0.52 8/23/22SW-846 8260D1Chloromethane
ND 1.0 8/23/22 16:54 MFFg/L0.11 8/23/22SW-846 8260D12-Chlorotoluene
ND 1.0 8/23/22 16:54 MFFg/L0.12 8/23/22SW-846 8260D14-Chlorotoluene
ND 5.0 8/23/22 16:54 MFFg/L0.80 8/23/22SW-846 8260D11,2-Dibromo-3-chloropropane (DBCP)
ND 0.50 8/23/22 16:54 MFFg/L0.17 8/23/22SW-846 8260D11,2-Dibromoethane (EDB)
ND 1.0 8/23/22 16:54 MFFg/L0.35 8/23/22SW-846 8260D1Dibromomethane
ND 1.0 8/23/22 16:54 MFFg/L0.12 8/23/22SW-846 8260D11,2-Dichlorobenzene
ND 1.0 8/23/22 16:54 MFFg/L0.12 8/23/22SW-846 8260D11,3-Dichlorobenzene
ND 1.0 8/23/22 16:54 MFFg/L0.13 8/23/22SW-846 8260D11,4-Dichlorobenzene
ND 2.0 8/23/22 16:54 MFFg/L1.6 8/23/22SW-846 8260D1V-05trans-1,4-Dichloro-2-butene
ND 2.0 8/23/22 16:54 MFFg/L0.19 8/23/22SW-846 8260D1Dichlorodifluoromethane (Freon 12)
ND 1.0 8/23/22 16:54 MFFg/L0.14 8/23/22SW-846 8260D11,1-Dichloroethane
ND 1.0 8/23/22 16:54 MFFg/L0.31 8/23/22SW-846 8260D11,2-Dichloroethane
ND 1.0 8/23/22 16:54 MFFg/L0.14 8/23/22SW-846 8260D11,1-Dichloroethylene
ND 1.0 8/23/22 16:54 MFFg/L0.15 8/23/22SW-846 8260D1cis-1,2-Dichloroethylene
ND 1.0 8/23/22 16:54 MFFg/L0.17 8/23/22SW-846 8260D1trans-1,2-Dichloroethylene
ND 1.0 8/23/22 16:54 MFFg/L0.18 8/23/22SW-846 8260D11,2-Dichloropropane
ND 0.50 8/23/22 16:54 MFFg/L0.13 8/23/22SW-846 8260D11,3-Dichloropropane
ND 1.0 8/23/22 16:54 MFFg/L0.33 8/23/22SW-846 8260D12,2-Dichloropropane
ND 2.0 8/23/22 16:54 MFFg/L0.15 8/23/22SW-846 8260D11,1-Dichloropropene
ND 0.50 8/23/22 16:54 MFFg/L0.16 8/23/22SW-846 8260D1cis-1,3-Dichloropropene
ND 0.50 8/23/22 16:54 MFFg/L0.17 8/23/22SW-846 8260D1trans-1,3-Dichloropropene
ND 2.0 8/23/22 16:54 MFFg/L0.18 8/23/22SW-846 8260D1Diethyl Ether
Page 9 of 25
Table of Contents
Page 14 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/20/2022
Work Order: 22H1227Sample Description:Project Location: Crown Food Mart 8/18/22
Sample ID: 22H1227-03
Field Sample #: SW 03 180
Sample Matrix: Water
Sampled: 8/18/2022 12:45
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 8/23/22 16:54 MFFg/L0.13 8/23/22SW-846 8260D1Diisopropyl Ether (DIPE)
ND 50 8/23/22 16:54 MFFg/L21 8/23/22SW-846 8260D11,4-Dioxane
ND 1.0 8/23/22 16:54 MFFg/L0.21 8/23/22SW-846 8260D1Ethylbenzene
ND 0.60 8/23/22 16:54 MFFg/L0.46 8/23/22SW-846 8260D1Hexachlorobutadiene
ND 10 8/23/22 16:54 MFFg/L1.1 8/23/22SW-846 8260D12-Hexanone (MBK)
ND 1.0 8/23/22 16:54 MFFg/L0.11 8/23/22SW-846 8260D1Isopropylbenzene (Cumene)
ND 1.0 8/23/22 16:54 MFFg/L0.097 8/23/22SW-846 8260D1p-Isopropyltoluene (p-Cymene)
ND 1.0 8/23/22 16:54 MFFg/L0.17 8/23/22SW-846 8260D1Methyl tert-Butyl Ether (MTBE)
ND 5.0 8/23/22 16:54 MFFg/L0.23 8/23/22SW-846 8260D1Methylene Chloride
ND 10 8/23/22 16:54 MFFg/L1.3 8/23/22SW-846 8260D14-Methyl-2-pentanone (MIBK)
ND 2.0 8/23/22 16:54 MFFg/L0.24 8/23/22SW-846 8260D1V-05Naphthalene
ND 1.0 8/23/22 16:54 MFFg/L0.086 8/23/22SW-846 8260D1n-Propylbenzene
ND 1.0 8/23/22 16:54 MFFg/L0.11 8/23/22SW-846 8260D1Styrene
ND 1.0 8/23/22 16:54 MFFg/L0.18 8/23/22SW-846 8260D11,1,1,2-Tetrachloroethane
ND 0.50 8/23/22 16:54 MFFg/L0.13 8/23/22SW-846 8260D11,1,2,2-Tetrachloroethane
ND 1.0 8/23/22 16:54 MFFg/L0.19 8/23/22SW-846 8260D1Tetrachloroethylene
ND 10 8/23/22 16:54 MFFg/L0.49 8/23/22SW-846 8260D1Tetrahydrofuran
ND 1.0 8/23/22 16:54 MFFg/L0.22 8/23/22SW-846 8260D1Toluene
ND 5.0 8/23/22 16:54 MFFg/L0.30 8/23/22SW-846 8260D11,2,3-Trichlorobenzene
ND 1.0 8/23/22 16:54 MFFg/L0.25 8/23/22SW-846 8260D11,2,4-Trichlorobenzene
ND 1.0 8/23/22 16:54 MFFg/L0.21 8/23/22SW-846 8260D11,3,5-Trichlorobenzene
ND 1.0 8/23/22 16:54 MFFg/L0.17 8/23/22SW-846 8260D11,1,1-Trichloroethane
ND 1.0 8/23/22 16:54 MFFg/L0.18 8/23/22SW-846 8260D11,1,2-Trichloroethane
ND 1.0 8/23/22 16:54 MFFg/L0.19 8/23/22SW-846 8260D1Trichloroethylene
ND 2.0 8/23/22 16:54 MFFg/L0.18 8/23/22SW-846 8260D1Trichlorofluoromethane (Freon 11)
ND 2.0 8/23/22 16:54 MFFg/L0.28 8/23/22SW-846 8260D11,2,3-Trichloropropane
ND 1.0 8/23/22 16:54 MFFg/L0.23 8/23/22SW-846 8260D11,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
0.34 1.0 8/23/22 16:54 MFFg/L0.20 8/23/22SW-846 8260D1J1,2,4-Trimethylbenzene
ND 1.0 8/23/22 16:54 MFFg/L0.11 8/23/22SW-846 8260D11,3,5-Trimethylbenzene
ND 2.0 8/23/22 16:54 MFFg/L0.21 8/23/22SW-846 8260D1Vinyl Chloride
ND 2.0 8/23/22 16:54 MFFg/L0.46 8/23/22SW-846 8260D1m+p Xylene
ND 1.0 8/23/22 16:54 MFFg/L0.23 8/23/22SW-846 8260D1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 98.0 8/23/22 16:5470-130
Toluene-d8 99.0 8/23/22 16:5470-130
4-Bromofluorobenzene 101 8/23/22 16:5470-130
Page 10 of 25
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Page 15 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/20/2022
Work Order: 22H1227Sample Description:Project Location: Crown Food Mart 8/18/22
Sample ID: 22H1227-04
Field Sample #: SW 04 180
Sample Matrix: Water
Sampled: 8/18/2022 13:00
[TOC_2]22H1227-04[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 8/23/22 17:18 MFFg/L2.0 8/23/22SW-846 8260D1V-05Acetone
ND 5.0 8/23/22 17:18 MFFg/L0.55 8/23/22SW-846 8260D1Acrylonitrile
ND 0.50 8/23/22 17:18 MFFg/L0.14 8/23/22SW-846 8260D1tert-Amyl Methyl Ether (TAME)
ND 1.0 8/23/22 17:18 MFFg/L0.20 8/23/22SW-846 8260D1Benzene
ND 1.0 8/23/22 17:18 MFFg/L0.15 8/23/22SW-846 8260D1Bromobenzene
ND 1.0 8/23/22 17:18 MFFg/L0.31 8/23/22SW-846 8260D1Bromochloromethane
ND 0.50 8/23/22 17:18 MFFg/L0.18 8/23/22SW-846 8260D1Bromodichloromethane
ND 1.0 8/23/22 17:18 MFFg/L0.38 8/23/22SW-846 8260D1Bromoform
ND 2.0 8/23/22 17:18 MFFg/L1.5 8/23/22SW-846 8260D1Bromomethane
ND 20 8/23/22 17:18 MFFg/L1.6 8/23/22SW-846 8260D12-Butanone (MEK)
ND 20 8/23/22 17:18 MFFg/L4.7 8/23/22SW-846 8260D1V-05tert-Butyl Alcohol (TBA)
ND 1.0 8/23/22 17:18 MFFg/L0.15 8/23/22SW-846 8260D1n-Butylbenzene
ND 1.0 8/23/22 17:18 MFFg/L0.11 8/23/22SW-846 8260D1sec-Butylbenzene
ND 1.0 8/23/22 17:18 MFFg/L0.13 8/23/22SW-846 8260D1tert-Butylbenzene
ND 0.50 8/23/22 17:18 MFFg/L0.15 8/23/22SW-846 8260D1tert-Butyl Ethyl Ether (TBEE)
ND 5.0 8/23/22 17:18 MFFg/L1.4 8/23/22SW-846 8260D1Carbon Disulfide
ND 1.0 8/23/22 17:18 MFFg/L0.16 8/23/22SW-846 8260D1Carbon Tetrachloride
ND 1.0 8/23/22 17:18 MFFg/L0.11 8/23/22SW-846 8260D1Chlorobenzene
ND 0.50 8/23/22 17:18 MFFg/L0.22 8/23/22SW-846 8260D1Chlorodibromomethane
ND 2.0 8/23/22 17:18 MFFg/L0.32 8/23/22SW-846 8260D1Chloroethane
ND 2.0 8/23/22 17:18 MFFg/L0.17 8/23/22SW-846 8260D1Chloroform
ND 2.0 8/23/22 17:18 MFFg/L0.52 8/23/22SW-846 8260D1Chloromethane
ND 1.0 8/23/22 17:18 MFFg/L0.11 8/23/22SW-846 8260D12-Chlorotoluene
ND 1.0 8/23/22 17:18 MFFg/L0.12 8/23/22SW-846 8260D14-Chlorotoluene
ND 5.0 8/23/22 17:18 MFFg/L0.80 8/23/22SW-846 8260D11,2-Dibromo-3-chloropropane (DBCP)
ND 0.50 8/23/22 17:18 MFFg/L0.17 8/23/22SW-846 8260D11,2-Dibromoethane (EDB)
ND 1.0 8/23/22 17:18 MFFg/L0.35 8/23/22SW-846 8260D1Dibromomethane
ND 1.0 8/23/22 17:18 MFFg/L0.12 8/23/22SW-846 8260D11,2-Dichlorobenzene
ND 1.0 8/23/22 17:18 MFFg/L0.12 8/23/22SW-846 8260D11,3-Dichlorobenzene
ND 1.0 8/23/22 17:18 MFFg/L0.13 8/23/22SW-846 8260D11,4-Dichlorobenzene
ND 2.0 8/23/22 17:18 MFFg/L1.6 8/23/22SW-846 8260D1V-05trans-1,4-Dichloro-2-butene
ND 2.0 8/23/22 17:18 MFFg/L0.19 8/23/22SW-846 8260D1Dichlorodifluoromethane (Freon 12)
ND 1.0 8/23/22 17:18 MFFg/L0.14 8/23/22SW-846 8260D11,1-Dichloroethane
ND 1.0 8/23/22 17:18 MFFg/L0.31 8/23/22SW-846 8260D11,2-Dichloroethane
ND 1.0 8/23/22 17:18 MFFg/L0.14 8/23/22SW-846 8260D11,1-Dichloroethylene
ND 1.0 8/23/22 17:18 MFFg/L0.15 8/23/22SW-846 8260D1cis-1,2-Dichloroethylene
ND 1.0 8/23/22 17:18 MFFg/L0.17 8/23/22SW-846 8260D1trans-1,2-Dichloroethylene
ND 1.0 8/23/22 17:18 MFFg/L0.18 8/23/22SW-846 8260D11,2-Dichloropropane
ND 0.50 8/23/22 17:18 MFFg/L0.13 8/23/22SW-846 8260D11,3-Dichloropropane
ND 1.0 8/23/22 17:18 MFFg/L0.33 8/23/22SW-846 8260D12,2-Dichloropropane
ND 2.0 8/23/22 17:18 MFFg/L0.15 8/23/22SW-846 8260D11,1-Dichloropropene
ND 0.50 8/23/22 17:18 MFFg/L0.16 8/23/22SW-846 8260D1cis-1,3-Dichloropropene
ND 0.50 8/23/22 17:18 MFFg/L0.17 8/23/22SW-846 8260D1trans-1,3-Dichloropropene
ND 2.0 8/23/22 17:18 MFFg/L0.18 8/23/22SW-846 8260D1Diethyl Ether
Page 11 of 25
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Page 16 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 8/20/2022
Work Order: 22H1227Sample Description:Project Location: Crown Food Mart 8/18/22
Sample ID: 22H1227-04
Field Sample #: SW 04 180
Sample Matrix: Water
Sampled: 8/18/2022 13:00
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 8/23/22 17:18 MFFg/L0.13 8/23/22SW-846 8260D1Diisopropyl Ether (DIPE)
ND 50 8/23/22 17:18 MFFg/L21 8/23/22SW-846 8260D11,4-Dioxane
ND 1.0 8/23/22 17:18 MFFg/L0.21 8/23/22SW-846 8260D1Ethylbenzene
ND 0.60 8/23/22 17:18 MFFg/L0.46 8/23/22SW-846 8260D1Hexachlorobutadiene
ND 10 8/23/22 17:18 MFFg/L1.1 8/23/22SW-846 8260D12-Hexanone (MBK)
ND 1.0 8/23/22 17:18 MFFg/L0.11 8/23/22SW-846 8260D1Isopropylbenzene (Cumene)
ND 1.0 8/23/22 17:18 MFFg/L0.097 8/23/22SW-846 8260D1p-Isopropyltoluene (p-Cymene)
ND 1.0 8/23/22 17:18 MFFg/L0.17 8/23/22SW-846 8260D1Methyl tert-Butyl Ether (MTBE)
ND 5.0 8/23/22 17:18 MFFg/L0.23 8/23/22SW-846 8260D1Methylene Chloride
ND 10 8/23/22 17:18 MFFg/L1.3 8/23/22SW-846 8260D14-Methyl-2-pentanone (MIBK)
ND 2.0 8/23/22 17:18 MFFg/L0.24 8/23/22SW-846 8260D1V-05Naphthalene
ND 1.0 8/23/22 17:18 MFFg/L0.086 8/23/22SW-846 8260D1n-Propylbenzene
ND 1.0 8/23/22 17:18 MFFg/L0.11 8/23/22SW-846 8260D1Styrene
ND 1.0 8/23/22 17:18 MFFg/L0.18 8/23/22SW-846 8260D11,1,1,2-Tetrachloroethane
ND 0.50 8/23/22 17:18 MFFg/L0.13 8/23/22SW-846 8260D11,1,2,2-Tetrachloroethane
ND 1.0 8/23/22 17:18 MFFg/L0.19 8/23/22SW-846 8260D1Tetrachloroethylene
ND 10 8/23/22 17:18 MFFg/L0.49 8/23/22SW-846 8260D1Tetrahydrofuran
ND 1.0 8/23/22 17:18 MFFg/L0.22 8/23/22SW-846 8260D1Toluene
ND 5.0 8/23/22 17:18 MFFg/L0.30 8/23/22SW-846 8260D11,2,3-Trichlorobenzene
ND 1.0 8/23/22 17:18 MFFg/L0.25 8/23/22SW-846 8260D11,2,4-Trichlorobenzene
ND 1.0 8/23/22 17:18 MFFg/L0.21 8/23/22SW-846 8260D11,3,5-Trichlorobenzene
ND 1.0 8/23/22 17:18 MFFg/L0.17 8/23/22SW-846 8260D11,1,1-Trichloroethane
ND 1.0 8/23/22 17:18 MFFg/L0.18 8/23/22SW-846 8260D11,1,2-Trichloroethane
ND 1.0 8/23/22 17:18 MFFg/L0.19 8/23/22SW-846 8260D1Trichloroethylene
ND 2.0 8/23/22 17:18 MFFg/L0.18 8/23/22SW-846 8260D1Trichlorofluoromethane (Freon 11)
ND 2.0 8/23/22 17:18 MFFg/L0.28 8/23/22SW-846 8260D11,2,3-Trichloropropane
ND 1.0 8/23/22 17:18 MFFg/L0.23 8/23/22SW-846 8260D11,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
ND 1.0 8/23/22 17:18 MFFg/L0.20 8/23/22SW-846 8260D11,2,4-Trimethylbenzene
ND 1.0 8/23/22 17:18 MFFg/L0.11 8/23/22SW-846 8260D11,3,5-Trimethylbenzene
ND 2.0 8/23/22 17:18 MFFg/L0.21 8/23/22SW-846 8260D1Vinyl Chloride
ND 2.0 8/23/22 17:18 MFFg/L0.46 8/23/22SW-846 8260D1m+p Xylene
ND 1.0 8/23/22 17:18 MFFg/L0.23 8/23/22SW-846 8260D1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 96.3 8/23/22 17:1870-130
Toluene-d8 99.6 8/23/22 17:1870-130
4-Bromofluorobenzene 99.0 8/23/22 17:1870-130
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Table of Contents
Page 17 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Sample Extraction Data
Prep Method: SW-846 5035 Analytical Method: SW-846 8260D
Lab Number [Field ID]Batch DateInitial [mL]Final [mL]
B315693 08/23/225 5.0022H1227-01 [SW 01 180]
B315693 08/23/225 5.0022H1227-02 [SW 02 180]
B315693 08/23/225 5.0022H1227-03 [SW 03 180]
B315693 08/23/225 5.0022H1227-04 [SW 04 180]
[TOC_1]Sample Preparation Information[TOC]
Page 13 of 25
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Page 18 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
[TOC_2]Volatile Organic Compounds by GC/MS[TOC]
Batch B315693 - SW-846 5035
[TOC_3]B315693[TOC]
Blank (B315693-BLK1) Prepared & Analyzed: 08/23/22
Acetone g/L50 V-05ND
Acrylonitrile g/L5.0ND
tert-Amyl Methyl Ether (TAME)g/L0.50ND
Benzene g/L1.0ND
Bromobenzene g/L1.0ND
Bromochloromethane g/L1.0ND
Bromodichloromethane g/L0.50ND
Bromoform g/L1.0ND
Bromomethane g/L2.0ND
2-Butanone (MEK)g/L20ND
tert-Butyl Alcohol (TBA)g/L20 V-05ND
n-Butylbenzene g/L1.0ND
sec-Butylbenzene g/L1.0ND
tert-Butylbenzene g/L1.0ND
tert-Butyl Ethyl Ether (TBEE)g/L0.50ND
Carbon Disulfide g/L5.0ND
Carbon Tetrachloride g/L1.0ND
Chlorobenzene g/L1.0ND
Chlorodibromomethane g/L0.50ND
Chloroethane g/L2.0ND
Chloroform g/L2.0ND
Chloromethane g/L2.0ND
2-Chlorotoluene g/L1.0ND
4-Chlorotoluene g/L1.0ND
1,2-Dibromo-3-chloropropane (DBCP)g/L5.0ND
1,2-Dibromoethane (EDB)g/L0.50ND
Dibromomethane g/L1.0ND
1,2-Dichlorobenzene g/L1.0ND
1,3-Dichlorobenzene g/L1.0ND
1,4-Dichlorobenzene g/L1.0ND
trans-1,4-Dichloro-2-butene g/L2.0 V-05ND
Dichlorodifluoromethane (Freon 12)g/L2.0ND
1,1-Dichloroethane g/L1.0ND
1,2-Dichloroethane g/L1.0ND
1,1-Dichloroethylene g/L1.0ND
cis-1,2-Dichloroethylene g/L1.0ND
trans-1,2-Dichloroethylene g/L1.0ND
1,2-Dichloropropane g/L1.0ND
1,3-Dichloropropane g/L0.50ND
2,2-Dichloropropane g/L1.0ND
1,1-Dichloropropene g/L2.0ND
cis-1,3-Dichloropropene g/L0.50ND
trans-1,3-Dichloropropene g/L0.50ND
Diethyl Ether g/L2.0ND
Diisopropyl Ether (DIPE)g/L0.50ND
1,4-Dioxane g/L50ND
Ethylbenzene g/L1.0ND
Hexachlorobutadiene g/L0.60ND
2-Hexanone (MBK)g/L10ND
Isopropylbenzene (Cumene)g/L1.0ND
p-Isopropyltoluene (p-Cymene)g/L1.0ND
Methyl tert-Butyl Ether (MTBE)g/L1.0ND
[TOC_1]QC Data[TOC]
Page 14 of 25
Table of Contents
Page 19 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B315693 - SW-846 5035
Blank (B315693-BLK1) Prepared & Analyzed: 08/23/22
Methylene Chloride g/L5.0ND
4-Methyl-2-pentanone (MIBK)g/L10ND
Naphthalene g/L2.0 V-05ND
n-Propylbenzene g/L1.0ND
Styrene g/L1.0ND
1,1,1,2-Tetrachloroethane g/L1.0ND
1,1,2,2-Tetrachloroethane g/L0.50ND
Tetrachloroethylene g/L1.0ND
Tetrahydrofuran g/L10ND
Toluene g/L1.0ND
1,2,3-Trichlorobenzene g/L5.0ND
1,2,4-Trichlorobenzene g/L1.0ND
1,3,5-Trichlorobenzene g/L1.0ND
1,1,1-Trichloroethane g/L1.0ND
1,1,2-Trichloroethane g/L1.0ND
Trichloroethylene g/L1.0ND
Trichlorofluoromethane (Freon 11)g/L2.0ND
1,2,3-Trichloropropane g/L2.0ND
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon
113)
g/L1.0ND
1,2,4-Trimethylbenzene g/L1.0ND
1,3,5-Trimethylbenzene g/L1.0ND
Vinyl Chloride g/L2.0ND
m+p Xylene g/L2.0ND
o-Xylene g/L1.0ND
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 95.423.8
g/L 25.0 70-130Surrogate: Toluene-d8 98.924.7
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 99.824.9
LCS (B315693-BS1) Prepared & Analyzed: 08/23/22
Acetone g/L50 100 V-0570-16078.578.5
Acrylonitrile g/L5.0 10.0 70-13088.38.83
tert-Amyl Methyl Ether (TAME)g/L0.50 10.0 70-13098.09.80
Benzene g/L1.0 10.0 70-13010410.4
Bromobenzene g/L1.0 10.0 70-13099.89.98
Bromochloromethane g/L1.0 10.0 70-13011011.0
Bromodichloromethane g/L0.50 10.0 70-13010010.0
Bromoform g/L1.0 10.0 70-13091.89.18
Bromomethane g/L2.0 10.0 40-16010610.6
2-Butanone (MEK)g/L20 100 40-16088.988.9
tert-Butyl Alcohol (TBA)g/L20 100 V-0540-16075.475.4
n-Butylbenzene g/L1.0 10.0 70-13010810.8
sec-Butylbenzene g/L1.0 10.0 70-13010810.8
tert-Butylbenzene g/L1.0 10.0 70-13010510.5
tert-Butyl Ethyl Ether (TBEE)g/L0.50 10.0 70-13099.69.96
Carbon Disulfide g/L5.0 100 70-130104104
Carbon Tetrachloride g/L1.0 10.0 70-13010710.7
Chlorobenzene g/L1.0 10.0 70-13010410.4
Chlorodibromomethane g/L0.50 10.0 70-13095.19.51
Chloroethane g/L2.0 10.0 70-13099.79.97
Chloroform g/L2.0 10.0 70-13010210.2
Chloromethane g/L2.0 10.0 40-16093.79.37
2-Chlorotoluene g/L1.0 10.0 70-13010210.2
Page 15 of 25
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Page 20 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B315693 - SW-846 5035
LCS (B315693-BS1) Prepared & Analyzed: 08/23/22
4-Chlorotoluene g/L1.0 10.0 70-13010510.5
1,2-Dibromo-3-chloropropane (DBCP)g/L5.0 10.0 70-13079.17.91
1,2-Dibromoethane (EDB)g/L0.50 10.0 70-13010010.0
Dibromomethane g/L1.0 10.0 70-13098.59.85
1,2-Dichlorobenzene g/L1.0 10.0 70-13010410.4
1,3-Dichlorobenzene g/L1.0 10.0 70-13010610.6
1,4-Dichlorobenzene g/L1.0 10.0 70-13098.69.86
trans-1,4-Dichloro-2-butene g/L2.0 10.0 V-0570-13081.78.17
Dichlorodifluoromethane (Freon 12)g/L2.0 10.0 40-16012112.1
1,1-Dichloroethane g/L1.0 10.0 70-13010410.4
1,2-Dichloroethane g/L1.0 10.0 70-13095.79.57
1,1-Dichloroethylene g/L1.0 10.0 70-13010110.1
cis-1,2-Dichloroethylene g/L1.0 10.0 70-13010210.2
trans-1,2-Dichloroethylene g/L1.0 10.0 70-13010010.0
1,2-Dichloropropane g/L1.0 10.0 70-13099.59.95
1,3-Dichloropropane g/L0.50 10.0 70-13099.29.92
2,2-Dichloropropane g/L1.0 10.0 40-13010610.6
1,1-Dichloropropene g/L2.0 10.0 70-13010810.8
cis-1,3-Dichloropropene g/L0.50 10.0 70-13098.79.87
trans-1,3-Dichloropropene g/L0.50 10.0 70-13097.69.76
Diethyl Ether g/L2.0 10.0 70-13097.59.75
Diisopropyl Ether (DIPE)g/L0.50 10.0 70-13010210.2
1,4-Dioxane g/L50 100 40-13080.980.9
Ethylbenzene g/L1.0 10.0 70-13010710.7
Hexachlorobutadiene g/L0.60 10.0 V-2070-13012212.2
2-Hexanone (MBK)g/L10 100 70-16081.681.6
Isopropylbenzene (Cumene)g/L1.0 10.0 70-13010810.8
p-Isopropyltoluene (p-Cymene)g/L1.0 10.0 70-13010710.7
Methyl tert-Butyl Ether (MTBE)g/L1.0 10.0 70-13095.49.54
Methylene Chloride g/L5.0 10.0 70-13095.09.50
4-Methyl-2-pentanone (MIBK)g/L10 100 70-16086.586.5
Naphthalene g/L2.0 10.0 V-0540-13066.46.64
n-Propylbenzene g/L1.0 10.0 70-13010910.9
Styrene g/L1.0 10.0 70-13010610.6
1,1,1,2-Tetrachloroethane g/L1.0 10.0 70-13010410.4
1,1,2,2-Tetrachloroethane g/L0.50 10.0 70-13096.69.66
Tetrachloroethylene g/L1.0 10.0 70-13011211.2
Tetrahydrofuran g/L10 10.0 J70-13089.78.97
Toluene g/L1.0 10.0 70-13010310.3
1,2,3-Trichlorobenzene g/L5.0 10.0 70-13086.68.66
1,2,4-Trichlorobenzene g/L1.0 10.0 70-13094.89.48
1,3,5-Trichlorobenzene g/L1.0 10.0 70-13010910.9
1,1,1-Trichloroethane g/L1.0 10.0 70-13010610.6
1,1,2-Trichloroethane g/L1.0 10.0 70-13099.79.97
Trichloroethylene g/L1.0 10.0 70-13010610.6
Trichlorofluoromethane (Freon 11)g/L2.0 10.0 70-13010610.6
1,2,3-Trichloropropane g/L2.0 10.0 70-13083.98.39
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon
113)
g/L1.0 10.0 70-13010810.8
1,2,4-Trimethylbenzene g/L1.0 10.0 70-13010210.2
1,3,5-Trimethylbenzene g/L1.0 10.0 70-13010310.3
Vinyl Chloride g/L2.0 10.0 40-16011211.2
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Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B315693 - SW-846 5035
LCS (B315693-BS1) Prepared & Analyzed: 08/23/22
m+p Xylene g/L2.0 20.0 70-13010621.1
o-Xylene g/L1.0 10.0 70-13010410.4
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 97.024.2
g/L 25.0 70-130Surrogate: Toluene-d8 99.925.0
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 10025.1
LCS Dup (B315693-BSD1) Prepared & Analyzed: 08/23/22
Acetone g/L50 100 25 V-0570-16083.0 5.6183.0
Acrylonitrile g/L5.0 10.0 2570-13095.8 8.159.58
tert-Amyl Methyl Ether (TAME)g/L0.50 10.0 2570-130101 3.2110.1
Benzene g/L1.0 10.0 2570-130104 0.28710.4
Bromobenzene g/L1.0 10.0 2570-130102 1.6910.2
Bromochloromethane g/L1.0 10.0 2570-130112 2.0811.2
Bromodichloromethane g/L0.50 10.0 2570-130103 3.3410.3
Bromoform g/L1.0 10.0 2570-13096.1 4.589.61
Bromomethane g/L2.0 10.0 2540-160109 3.3510.9
2-Butanone (MEK)g/L20 100 2540-16093.8 5.3993.8
tert-Butyl Alcohol (TBA)g/L20 100 25 V-0540-16079.4 5.1979.4
n-Butylbenzene g/L1.0 10.0 2570-130111 3.1111.1
sec-Butylbenzene g/L1.0 10.0 2570-130111 2.8311.1
tert-Butylbenzene g/L1.0 10.0 2570-130107 1.4210.7
tert-Butyl Ethyl Ether (TBEE)g/L0.50 10.0 2570-130103 3.0610.3
Carbon Disulfide g/L5.0 100 2570-130105 0.335105
Carbon Tetrachloride g/L1.0 10.0 2570-130108 1.3910.8
Chlorobenzene g/L1.0 10.0 2570-130107 2.2710.7
Chlorodibromomethane g/L0.50 10.0 2570-13099.9 4.929.99
Chloroethane g/L2.0 10.0 2570-13096.4 3.379.64
Chloroform g/L2.0 10.0 2570-130104 2.3210.4
Chloromethane g/L2.0 10.0 2540-16092.1 1.729.21
2-Chlorotoluene g/L1.0 10.0 2570-130106 3.7410.6
4-Chlorotoluene g/L1.0 10.0 2570-130106 0.94810.6
1,2-Dibromo-3-chloropropane (DBCP)g/L5.0 10.0 2570-13084.4 6.488.44
1,2-Dibromoethane (EDB)g/L0.50 10.0 2570-130106 5.3410.6
Dibromomethane g/L1.0 10.0 2570-130106 6.8610.6
1,2-Dichlorobenzene g/L1.0 10.0 2570-130105 0.95810.5
1,3-Dichlorobenzene g/L1.0 10.0 2570-130108 1.9710.8
1,4-Dichlorobenzene g/L1.0 10.0 2570-130102 3.7810.2
trans-1,4-Dichloro-2-butene g/L2.0 10.0 25 V-0570-13085.2 4.198.52
Dichlorodifluoromethane (Freon 12)g/L2.0 10.0 2540-160120 0.41412.0
1,1-Dichloroethane g/L1.0 10.0 2570-130103 0.096710.3
1,2-Dichloroethane g/L1.0 10.0 2570-130102 6.4710.2
1,1-Dichloroethylene g/L1.0 10.0 2570-130102 0.39410.2
cis-1,2-Dichloroethylene g/L1.0 10.0 2570-130103 0.58510.3
trans-1,2-Dichloroethylene g/L1.0 10.0 2570-13099.6 0.4019.96
1,2-Dichloropropane g/L1.0 10.0 2570-130107 7.5410.7
1,3-Dichloropropane g/L0.50 10.0 2570-130104 5.1110.4
2,2-Dichloropropane g/L1.0 10.0 2540-130105 1.5210.5
1,1-Dichloropropene g/L2.0 10.0 2570-130107 0.93410.7
cis-1,3-Dichloropropene g/L0.50 10.0 2570-130103 4.6510.3
trans-1,3-Dichloropropene g/L0.50 10.0 2570-13099.2 1.639.92
Diethyl Ether g/L2.0 10.0 2570-13099.5 2.039.95
Diisopropyl Ether (DIPE)g/L0.50 10.0 2570-130104 1.4610.4
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Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B315693 - SW-846 5035
LCS Dup (B315693-BSD1) Prepared & Analyzed: 08/23/22
1,4-Dioxane g/L50 100 5040-13082.4 1.7582.4
Ethylbenzene g/L1.0 10.0 2570-130109 1.6610.9
Hexachlorobutadiene g/L0.60 10.0 25 V-2070-130123 0.49012.3
2-Hexanone (MBK)g/L10 100 2570-16087.4 6.8887.4
Isopropylbenzene (Cumene)g/L1.0 10.0 2570-130108 0.092510.8
p-Isopropyltoluene (p-Cymene)g/L1.0 10.0 2570-130111 3.3011.1
Methyl tert-Butyl Ether (MTBE)g/L1.0 10.0 2570-13096.9 1.569.69
Methylene Chloride g/L5.0 10.0 2570-13097.1 2.199.71
4-Methyl-2-pentanone (MIBK)g/L10 100 2570-16091.5 5.5891.5
Naphthalene g/L2.0 10.0 25 V-0540-13071.4 7.267.14
n-Propylbenzene g/L1.0 10.0 2570-130109 0.092010.9
Styrene g/L1.0 10.0 2570-130105 0.28410.5
1,1,1,2-Tetrachloroethane g/L1.0 10.0 2570-130105 1.0510.5
1,1,2,2-Tetrachloroethane g/L0.50 10.0 2570-13098.2 1.649.82
Tetrachloroethylene g/L1.0 10.0 2570-130113 1.1511.3
Tetrahydrofuran g/L10 10.0 25 J70-13092.8 3.409.28
Toluene g/L1.0 10.0 2570-130104 1.1610.4
1,2,3-Trichlorobenzene g/L5.0 10.0 2570-13089.0 2.738.90
1,2,4-Trichlorobenzene g/L1.0 10.0 2570-13097.0 2.299.70
1,3,5-Trichlorobenzene g/L1.0 10.0 2570-130109 0.092010.9
1,1,1-Trichloroethane g/L1.0 10.0 2570-130106 0.47310.6
1,1,2-Trichloroethane g/L1.0 10.0 2570-130106 5.7510.6
Trichloroethylene g/L1.0 10.0 2570-130107 1.6910.7
Trichlorofluoromethane (Freon 11)g/L2.0 10.0 2570-130106 0.66110.6
1,2,3-Trichloropropane g/L2.0 10.0 2570-13089.2 6.128.92
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon
113)
g/L1.0 10.0 2570-130107 0.83810.7
1,2,4-Trimethylbenzene g/L1.0 10.0 2570-130104 1.5510.4
1,3,5-Trimethylbenzene g/L1.0 10.0 2570-130105 1.8210.5
Vinyl Chloride g/L2.0 10.0 2540-160110 1.8111.0
m+p Xylene g/L2.0 20.0 2570-130106 0.66121.2
o-Xylene g/L1.0 10.0 2570-130104 0.48010.4
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 93.523.4
g/L 25.0 70-130Surrogate: Toluene-d8 99.024.7
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 99.424.9
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FLAG/QUALIFIER SUMMARY
*QC result is outside of established limits.
Wide recovery limits established for difficult compound.
Wide RPD limits established for difficult compound.
#Data exceeded client recommended or regulatory level
Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the
calculation which have not been rounded.
No results have been blank subtracted unless specified in the case narrative section.
RL Reporting Limit is at the level of quantitation (LOQ)
DL Detection Limit is the lower limit of detection determined by the MDL study
MCL Maximum Contaminant Level
ND Not Detected
Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated
concentration (CLP J-Flag).
J
Continuing calibration verification (CCV) did not meet method specifications and was biased on the low side for
this compound.
V-05
Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side.
Data validation is not affected since sample result was "not detected" for this compound.
V-20
[TOC_1]Flag/Qualifier Summary[TOC]
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CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
SW-846 8260D in Water
NCAcetone
NCAcrylonitrile
NCtert-Amyl Methyl Ether (TAME)
NCBenzene
NCBromobenzene
NCBromochloromethane
NCBromodichloromethane
NCBromoform
NCBromomethane
NC2-Butanone (MEK)
NCtert-Butyl Alcohol (TBA)
NCn-Butylbenzene
NCsec-Butylbenzene
NCtert-Butylbenzene
NCtert-Butyl Ethyl Ether (TBEE)
NCCarbon Disulfide
NCCarbon Tetrachloride
NCChlorobenzene
NCChlorodibromomethane
NCChloroethane
NCChloroform
NCChloromethane
NC2-Chlorotoluene
NC4-Chlorotoluene
NC1,2-Dibromo-3-chloropropane (DBCP)
NC1,2-Dibromoethane (EDB)
NCDibromomethane
NC1,2-Dichlorobenzene
NC1,3-Dichlorobenzene
NC1,4-Dichlorobenzene
NCtrans-1,4-Dichloro-2-butene
NCDichlorodifluoromethane (Freon 12)
NC1,1-Dichloroethane
NC1,2-Dichloroethane
NC1,1-Dichloroethylene
NCcis-1,2-Dichloroethylene
NCtrans-1,2-Dichloroethylene
NC1,2-Dichloropropane
NC1,3-Dichloropropane
NC2,2-Dichloropropane
NC1,1-Dichloropropene
NCcis-1,3-Dichloropropene
NCtrans-1,3-Dichloropropene
NCDiethyl Ether
NCDiisopropyl Ether (DIPE)
NC1,4-Dioxane
NCEthylbenzene
[TOC_1]Certifications[TOC]
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CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
SW-846 8260D in Water
NCHexachlorobutadiene
NC2-Hexanone (MBK)
NCIsopropylbenzene (Cumene)
NCp-Isopropyltoluene (p-Cymene)
NCMethyl tert-Butyl Ether (MTBE)
NCMethylene Chloride
NC4-Methyl-2-pentanone (MIBK)
NCNaphthalene
NCn-Propylbenzene
NCStyrene
NC1,1,1,2-Tetrachloroethane
NC1,1,2,2-Tetrachloroethane
NCTetrachloroethylene
NCTetrahydrofuran
NCToluene
NC1,2,3-Trichlorobenzene
NC1,2,4-Trichlorobenzene
NC1,3,5-Trichlorobenzene
NC1,1,1-Trichloroethane
NC1,1,2-Trichloroethane
NCTrichloroethylene
NCTrichlorofluoromethane (Freon 11)
NC1,2,3-Trichloropropane
NC1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)
NC1,2,4-Trimethylbenzene
NC1,3,5-Trimethylbenzene
NCVinyl Chloride
NCm+p Xylene
NCo-Xylene
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Con-Test, a Pace Environmental Laboratory, operates under the following certifications and accreditations:
Code Description Number Expires
100033AIHA-LAP, LLC - ISO 17025:2017AIHA 03/1/2024
M-MA100Massachusetts DEPMA 06/30/2023
PH-0165Connecticut Department of Public HealthCT 12/31/2022
10899 NELAPNew York State Department of HealthNY 04/1/2023
2516 NELAPNew Hampshire Environmental LabNH 02/5/2023
LAO00373Rhode Island Department of HealthRI 12/30/2022
652North Carolina Div. of Water QualityNC 12/31/2022
MA007 NELAPNew Jersey DEPNJ 06/30/2023
E871027 NELAPFlorida Department of HealthFL 06/30/2023
LL720741Vermont Department of Health Lead LaboratoryVT 07/30/2023
VT-255716Vermont Department of Health Drinking WaterVT-DW 06/12/2023
MA00100State of MaineME 06/9/2023
460217Commonwealth of VirginiaVA 12/14/2022
2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2022
25703North Carolina Department of Health and Human ServicesNC-DW 07/31/2023
68-05812Commonwealth of Pennsylvania DEPPA 06/30/2023
9100Dept. of Env, Great Lakes, and EnergyMI 09/6/2022
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#=CL#
September 20, 2022
LIMS USE: FR - ROBERT MARTIN
LIMS OBJECT ID: 92623587
92623587
Project:
Pace Project No.:
RE:
Mr. Robert Martin
Martin and Slagle
24 Lookout Terrace
Black Mountain, NC 28711
CROWN FOOD MART 9/1/22
Dear Mr. Martin:
Enclosed are the analytical results for sample(s) received by the laboratory on September 02, 2022. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lorri Patton
[e-mail]
Project Manager
1(828)254-7176
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 1 of 31
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92623587
CROWN FOOD MART 9/1/22
Lab ID Sample ID Matrix Date Collected Date Received
92623587001 SW 01 181 Water 09/01/22 09:45 09/02/22 10:15
92623587002 SW 02 181 Water 09/01/22 10:25 09/02/22 10:15
92623587003 SW 03 181 Water 09/01/22 10:45 09/02/22 10:15
92623587004 SW 04 181 Water 09/01/22 11:05 09/02/22 10:15
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 2 of 31
Page 3 of 31
Page 4 of 31
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
September 8, 2022
Lorri Patton
Pace Analytical Services - NC
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Project Location: Crown Food Mart 9/1/22
Client Job Number:
Project Number: 92623587
Laboratory Work Order Number: 22I0195
Enclosed are results of analyses for samples as received by the laboratory on September 3, 2022. If you have any questions
concerning this report, please feel free to contact me.
Sincerely,
Kerry K. McGee
Project Manager
Page 1 of 26
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Table of Contents
Sample Summary 3
Case Narrative 4
Sample Results 6
22I0195-01 6
22I0195-02 8
22I0195-03 10
22I0195-04 12
Sample Preparation Information 14
QC Data 15
Volatile Organic Compounds by GC/MS 15
B316550 15
Flag/Qualifier Summary 20
Certifications 21
Chain of Custody/Sample Receipt 24
Page 2 of 26
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ANALYTICAL SUMMARY
9/8/2022
Pace Analytical Services - NC
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
ATTN: Lorri Patton
92623587
22I0195
The results of analyses performed on the following samples submitted to CON-TEST, a Pace Analytical Laboratory, are found in this report.
PROJECT LOCATION:
PURCHASE ORDER NUMBER:
PROJECT NUMBER:
REPORT DATE:
WORK ORDER NUMBER:
FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB
Crown Food Mart 9/1/22
SW 01 181 22I0195-01 Water SW-846 8260D
SW 02 181 22I0195-02 Water SW-846 8260D
SW 03 181 22I0195-03 Water SW-846 8260D
SW 04 181 22I0195-04 Water SW-846 8260D
[TOC_1]Sample Summary[TOC]
Page 3 of 26
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CASE NARRATIVE SUMMARY
All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report.
[TOC_1]Case Narrative[TOC]
SW-846 8260D
Qualifications:
Laboratory fortified blank/laboratory control sample recovery and duplicate recoveries outside of control limits. Data validation is not
affected since all results are "not detected" for associated samples in this batch and bias is on the high side.
Analyte & Samples(s) Qualified:
L-02
Hexachlorobutadiene
B316550-BS1, B316550-BSD1
trans-1,4-Dichloro-2-butene
B316550-BS1, B316550-BSD1
Vinyl Chloride
B316550-BS1, B316550-BSD1
Either laboratory fortified blank/laboratory control sample or duplicate recovery is outside of control limits, but the other is within limits. RPD
between the two LFB/LCS results is within method specified criteria.
Analyte & Samples(s) Qualified:
L-07
Tetrahydrofuran
B316550-BS1
Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side for this compound.
Analyte & Samples(s) Qualified:
V-06
2-Butanone (MEK)
B316550-BS1, B316550-BSD1, S076239-CCV1
Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side. Data validation is not affected
since sample result was "not detected" for this compound.
Analyte & Samples(s) Qualified:
V-20
2-Hexanone (MBK)
B316550-BS1, B316550-BSD1, S076239-CCV1
4-Methyl-2-pentanone (MIBK)
B316550-BS1, B316550-BSD1, S076239-CCV1
Carbon Disulfide
B316550-BS1, B316550-BSD1, S076239-CCV1
Diisopropyl Ether (DIPE)
B316550-BS1, B316550-BSD1, S076239-CCV1
Hexachlorobutadiene
B316550-BS1, B316550-BSD1, S076239-CCV1
Tetrahydrofuran
B316550-BS1, B316550-BSD1, S076239-CCV1
trans-1,4-Dichloro-2-butene
B316550-BS1, B316550-BSD1, S076239-CCV1
Vinyl Acetate
B316550-BS1, B316550-BSD1, S076239-CCV1
Vinyl Chloride
B316550-BS1, B316550-BSD1, S076239-CCV1
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The results of analyses reported only relate to samples submitted to Con-Test, a Pace Analytical Laboratory, for testing.
I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed
in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the
best of my knowledge and belief, accurate and complete.
Meghan E. Kelley
Project Management Supervisor
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Date Received: 9/3/2022
Work Order: 22I0195Sample Description:Project Location: Crown Food Mart 9/1/22
Sample ID: 22I0195-01
Field Sample #: SW 01 181
Sample Matrix: Water
Sampled: 9/1/2022 09:45
[TOC_2]22I0195-01[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 9/6/22 14:16 EEHg/L2.0 9/6/22SW-846 8260D1Acetone
ND 5.0 9/6/22 14:16 EEHg/L0.55 9/6/22SW-846 8260D1Acrylonitrile
ND 0.50 9/6/22 14:16 EEHg/L0.14 9/6/22SW-846 8260D1tert-Amyl Methyl Ether (TAME)
ND 1.0 9/6/22 14:16 EEHg/L0.20 9/6/22SW-846 8260D1Benzene
ND 1.0 9/6/22 14:16 EEHg/L0.15 9/6/22SW-846 8260D1Bromobenzene
ND 1.0 9/6/22 14:16 EEHg/L0.31 9/6/22SW-846 8260D1Bromochloromethane
ND 0.50 9/6/22 14:16 EEHg/L0.18 9/6/22SW-846 8260D1Bromodichloromethane
ND 2.0 9/6/22 14:16 EEHg/L0.38 9/6/22SW-846 8260D1Bromoform
ND 2.0 9/6/22 14:16 EEHg/L1.5 9/6/22SW-846 8260D1Bromomethane
ND 20 9/6/22 14:16 EEHg/L1.6 9/6/22SW-846 8260D12-Butanone (MEK)
ND 20 9/6/22 14:16 EEHg/L4.7 9/6/22SW-846 8260D1tert-Butyl Alcohol (TBA)
ND 1.0 9/6/22 14:16 EEHg/L0.15 9/6/22SW-846 8260D1n-Butylbenzene
ND 1.0 9/6/22 14:16 EEHg/L0.11 9/6/22SW-846 8260D1sec-Butylbenzene
ND 1.0 9/6/22 14:16 EEHg/L0.13 9/6/22SW-846 8260D1tert-Butylbenzene
ND 0.50 9/6/22 14:16 EEHg/L0.15 9/6/22SW-846 8260D1tert-Butyl Ethyl Ether (TBEE)
ND 5.0 9/6/22 14:16 EEHg/L1.4 9/6/22SW-846 8260D1Carbon Disulfide
ND 1.0 9/6/22 14:16 EEHg/L0.16 9/6/22SW-846 8260D1Carbon Tetrachloride
ND 1.0 9/6/22 14:16 EEHg/L0.11 9/6/22SW-846 8260D1Chlorobenzene
ND 0.50 9/6/22 14:16 EEHg/L0.22 9/6/22SW-846 8260D1Chlorodibromomethane
ND 2.0 9/6/22 14:16 EEHg/L0.32 9/6/22SW-846 8260D1Chloroethane
ND 2.0 9/6/22 14:16 EEHg/L0.17 9/6/22SW-846 8260D1Chloroform
ND 2.0 9/6/22 14:16 EEHg/L0.52 9/6/22SW-846 8260D1Chloromethane
ND 1.0 9/6/22 14:16 EEHg/L0.11 9/6/22SW-846 8260D12-Chlorotoluene
ND 1.0 9/6/22 14:16 EEHg/L0.12 9/6/22SW-846 8260D14-Chlorotoluene
ND 5.0 9/6/22 14:16 EEHg/L0.80 9/6/22SW-846 8260D11,2-Dibromo-3-chloropropane (DBCP)
ND 0.50 9/6/22 14:16 EEHg/L0.17 9/6/22SW-846 8260D11,2-Dibromoethane (EDB)
ND 1.0 9/6/22 14:16 EEHg/L0.35 9/6/22SW-846 8260D1Dibromomethane
ND 1.0 9/6/22 14:16 EEHg/L0.12 9/6/22SW-846 8260D11,2-Dichlorobenzene
ND 1.0 9/6/22 14:16 EEHg/L0.12 9/6/22SW-846 8260D11,3-Dichlorobenzene
ND 1.0 9/6/22 14:16 EEHg/L0.13 9/6/22SW-846 8260D11,4-Dichlorobenzene
ND 2.0 9/6/22 14:16 EEHg/L1.6 9/6/22SW-846 8260D1trans-1,4-Dichloro-2-butene
ND 2.0 9/6/22 14:16 EEHg/L0.19 9/6/22SW-846 8260D1Dichlorodifluoromethane (Freon 12)
ND 1.0 9/6/22 14:16 EEHg/L0.14 9/6/22SW-846 8260D11,1-Dichloroethane
ND 1.0 9/6/22 14:16 EEHg/L0.31 9/6/22SW-846 8260D11,2-Dichloroethane
ND 1.0 9/6/22 14:16 EEHg/L0.14 9/6/22SW-846 8260D11,1-Dichloroethylene
ND 1.0 9/6/22 14:16 EEHg/L0.15 9/6/22SW-846 8260D1cis-1,2-Dichloroethylene
ND 1.0 9/6/22 14:16 EEHg/L0.17 9/6/22SW-846 8260D1trans-1,2-Dichloroethylene
ND 1.0 9/6/22 14:16 EEHg/L0.18 9/6/22SW-846 8260D11,2-Dichloropropane
ND 0.50 9/6/22 14:16 EEHg/L0.13 9/6/22SW-846 8260D11,3-Dichloropropane
ND 1.0 9/6/22 14:16 EEHg/L0.33 9/6/22SW-846 8260D12,2-Dichloropropane
ND 2.0 9/6/22 14:16 EEHg/L0.15 9/6/22SW-846 8260D11,1-Dichloropropene
ND 0.50 9/6/22 14:16 EEHg/L0.16 9/6/22SW-846 8260D1cis-1,3-Dichloropropene
ND 0.50 9/6/22 14:16 EEHg/L0.17 9/6/22SW-846 8260D1trans-1,3-Dichloropropene
ND 2.0 9/6/22 14:16 EEHg/L0.18 9/6/22SW-846 8260D1Diethyl Ether
[TOC_1]Sample Results[TOC]
Page 6 of 26
Table of Contents
Page 11 of 31
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 9/3/2022
Work Order: 22I0195Sample Description:Project Location: Crown Food Mart 9/1/22
Sample ID: 22I0195-01
Field Sample #: SW 01 181
Sample Matrix: Water
Sampled: 9/1/2022 09:45
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 9/6/22 14:16 EEHg/L0.13 9/6/22SW-846 8260D1Diisopropyl Ether (DIPE)
ND 50 9/6/22 14:16 EEHg/L21 9/6/22SW-846 8260D11,4-Dioxane
ND 1.0 9/6/22 14:16 EEHg/L0.21 9/6/22SW-846 8260D1Ethylbenzene
ND 0.60 9/6/22 14:16 EEHg/L0.46 9/6/22SW-846 8260D1Hexachlorobutadiene
ND 10 9/6/22 14:16 EEHg/L1.1 9/6/22SW-846 8260D12-Hexanone (MBK)
ND 1.0 9/6/22 14:16 EEHg/L0.11 9/6/22SW-846 8260D1Isopropylbenzene (Cumene)
ND 1.0 9/6/22 14:16 EEHg/L0.097 9/6/22SW-846 8260D1p-Isopropyltoluene (p-Cymene)
ND 1.0 9/6/22 14:16 EEHg/L0.17 9/6/22SW-846 8260D1Methyl tert-Butyl Ether (MTBE)
ND 5.0 9/6/22 14:16 EEHg/L0.23 9/6/22SW-846 8260D1Methylene Chloride
ND 10 9/6/22 14:16 EEHg/L1.3 9/6/22SW-846 8260D14-Methyl-2-pentanone (MIBK)
ND 2.0 9/6/22 14:16 EEHg/L0.24 9/6/22SW-846 8260D1Naphthalene
ND 1.0 9/6/22 14:16 EEHg/L0.086 9/6/22SW-846 8260D1n-Propylbenzene
ND 1.0 9/6/22 14:16 EEHg/L0.11 9/6/22SW-846 8260D1Styrene
ND 1.0 9/6/22 14:16 EEHg/L0.18 9/6/22SW-846 8260D11,1,1,2-Tetrachloroethane
ND 0.50 9/6/22 14:16 EEHg/L0.13 9/6/22SW-846 8260D11,1,2,2-Tetrachloroethane
ND 1.0 9/6/22 14:16 EEHg/L0.19 9/6/22SW-846 8260D1Tetrachloroethylene
ND 10 9/6/22 14:16 EEHg/L0.49 9/6/22SW-846 8260D1Tetrahydrofuran
ND 1.0 9/6/22 14:16 EEHg/L0.22 9/6/22SW-846 8260D1Toluene
ND 5.0 9/6/22 14:16 EEHg/L0.30 9/6/22SW-846 8260D11,2,3-Trichlorobenzene
ND 1.0 9/6/22 14:16 EEHg/L0.25 9/6/22SW-846 8260D11,2,4-Trichlorobenzene
ND 1.0 9/6/22 14:16 EEHg/L0.21 9/6/22SW-846 8260D11,3,5-Trichlorobenzene
ND 1.0 9/6/22 14:16 EEHg/L0.17 9/6/22SW-846 8260D11,1,1-Trichloroethane
ND 1.0 9/6/22 14:16 EEHg/L0.18 9/6/22SW-846 8260D11,1,2-Trichloroethane
ND 1.0 9/6/22 14:16 EEHg/L0.19 9/6/22SW-846 8260D1Trichloroethylene
ND 2.0 9/6/22 14:16 EEHg/L0.18 9/6/22SW-846 8260D1Trichlorofluoromethane (Freon 11)
ND 2.0 9/6/22 14:16 EEHg/L0.28 9/6/22SW-846 8260D11,2,3-Trichloropropane
ND 2.0 9/6/22 14:16 EEHg/L0.23 9/6/22SW-846 8260D11,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
ND 1.0 9/6/22 14:16 EEHg/L0.20 9/6/22SW-846 8260D11,2,4-Trimethylbenzene
ND 1.0 9/6/22 14:16 EEHg/L0.11 9/6/22SW-846 8260D11,3,5-Trimethylbenzene
ND 2.0 9/6/22 14:16 EEHg/L0.21 9/6/22SW-846 8260D1Vinyl Chloride
ND 2.0 9/6/22 14:16 EEHg/L0.46 9/6/22SW-846 8260D1m+p Xylene
ND 1.0 9/6/22 14:16 EEHg/L0.23 9/6/22SW-846 8260D1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 101 9/6/22 14:1670-130
Toluene-d8 101 9/6/22 14:1670-130
4-Bromofluorobenzene 104 9/6/22 14:1670-130
Page 7 of 26
Table of Contents
Page 12 of 31
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 9/3/2022
Work Order: 22I0195Sample Description:Project Location: Crown Food Mart 9/1/22
Sample ID: 22I0195-02
Field Sample #: SW 02 181
Sample Matrix: Water
Sampled: 9/1/2022 10:25
[TOC_2]22I0195-02[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 9/6/22 14:44 EEHg/L2.0 9/6/22SW-846 8260D1Acetone
ND 5.0 9/6/22 14:44 EEHg/L0.55 9/6/22SW-846 8260D1Acrylonitrile
ND 0.50 9/6/22 14:44 EEHg/L0.14 9/6/22SW-846 8260D1tert-Amyl Methyl Ether (TAME)
ND 1.0 9/6/22 14:44 EEHg/L0.20 9/6/22SW-846 8260D1Benzene
ND 1.0 9/6/22 14:44 EEHg/L0.15 9/6/22SW-846 8260D1Bromobenzene
ND 1.0 9/6/22 14:44 EEHg/L0.31 9/6/22SW-846 8260D1Bromochloromethane
ND 0.50 9/6/22 14:44 EEHg/L0.18 9/6/22SW-846 8260D1Bromodichloromethane
ND 2.0 9/6/22 14:44 EEHg/L0.38 9/6/22SW-846 8260D1Bromoform
ND 2.0 9/6/22 14:44 EEHg/L1.5 9/6/22SW-846 8260D1Bromomethane
ND 20 9/6/22 14:44 EEHg/L1.6 9/6/22SW-846 8260D12-Butanone (MEK)
ND 20 9/6/22 14:44 EEHg/L4.7 9/6/22SW-846 8260D1tert-Butyl Alcohol (TBA)
ND 1.0 9/6/22 14:44 EEHg/L0.15 9/6/22SW-846 8260D1n-Butylbenzene
ND 1.0 9/6/22 14:44 EEHg/L0.11 9/6/22SW-846 8260D1sec-Butylbenzene
ND 1.0 9/6/22 14:44 EEHg/L0.13 9/6/22SW-846 8260D1tert-Butylbenzene
ND 0.50 9/6/22 14:44 EEHg/L0.15 9/6/22SW-846 8260D1tert-Butyl Ethyl Ether (TBEE)
ND 5.0 9/6/22 14:44 EEHg/L1.4 9/6/22SW-846 8260D1Carbon Disulfide
ND 1.0 9/6/22 14:44 EEHg/L0.16 9/6/22SW-846 8260D1Carbon Tetrachloride
ND 1.0 9/6/22 14:44 EEHg/L0.11 9/6/22SW-846 8260D1Chlorobenzene
ND 0.50 9/6/22 14:44 EEHg/L0.22 9/6/22SW-846 8260D1Chlorodibromomethane
ND 2.0 9/6/22 14:44 EEHg/L0.32 9/6/22SW-846 8260D1Chloroethane
ND 2.0 9/6/22 14:44 EEHg/L0.17 9/6/22SW-846 8260D1Chloroform
ND 2.0 9/6/22 14:44 EEHg/L0.52 9/6/22SW-846 8260D1Chloromethane
ND 1.0 9/6/22 14:44 EEHg/L0.11 9/6/22SW-846 8260D12-Chlorotoluene
ND 1.0 9/6/22 14:44 EEHg/L0.12 9/6/22SW-846 8260D14-Chlorotoluene
ND 5.0 9/6/22 14:44 EEHg/L0.80 9/6/22SW-846 8260D11,2-Dibromo-3-chloropropane (DBCP)
ND 0.50 9/6/22 14:44 EEHg/L0.17 9/6/22SW-846 8260D11,2-Dibromoethane (EDB)
ND 1.0 9/6/22 14:44 EEHg/L0.35 9/6/22SW-846 8260D1Dibromomethane
ND 1.0 9/6/22 14:44 EEHg/L0.12 9/6/22SW-846 8260D11,2-Dichlorobenzene
ND 1.0 9/6/22 14:44 EEHg/L0.12 9/6/22SW-846 8260D11,3-Dichlorobenzene
ND 1.0 9/6/22 14:44 EEHg/L0.13 9/6/22SW-846 8260D11,4-Dichlorobenzene
ND 2.0 9/6/22 14:44 EEHg/L1.6 9/6/22SW-846 8260D1trans-1,4-Dichloro-2-butene
ND 2.0 9/6/22 14:44 EEHg/L0.19 9/6/22SW-846 8260D1Dichlorodifluoromethane (Freon 12)
ND 1.0 9/6/22 14:44 EEHg/L0.14 9/6/22SW-846 8260D11,1-Dichloroethane
ND 1.0 9/6/22 14:44 EEHg/L0.31 9/6/22SW-846 8260D11,2-Dichloroethane
ND 1.0 9/6/22 14:44 EEHg/L0.14 9/6/22SW-846 8260D11,1-Dichloroethylene
ND 1.0 9/6/22 14:44 EEHg/L0.15 9/6/22SW-846 8260D1cis-1,2-Dichloroethylene
ND 1.0 9/6/22 14:44 EEHg/L0.17 9/6/22SW-846 8260D1trans-1,2-Dichloroethylene
ND 1.0 9/6/22 14:44 EEHg/L0.18 9/6/22SW-846 8260D11,2-Dichloropropane
ND 0.50 9/6/22 14:44 EEHg/L0.13 9/6/22SW-846 8260D11,3-Dichloropropane
ND 1.0 9/6/22 14:44 EEHg/L0.33 9/6/22SW-846 8260D12,2-Dichloropropane
ND 2.0 9/6/22 14:44 EEHg/L0.15 9/6/22SW-846 8260D11,1-Dichloropropene
ND 0.50 9/6/22 14:44 EEHg/L0.16 9/6/22SW-846 8260D1cis-1,3-Dichloropropene
ND 0.50 9/6/22 14:44 EEHg/L0.17 9/6/22SW-846 8260D1trans-1,3-Dichloropropene
ND 2.0 9/6/22 14:44 EEHg/L0.18 9/6/22SW-846 8260D1Diethyl Ether
Page 8 of 26
Table of Contents
Page 13 of 31
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 9/3/2022
Work Order: 22I0195Sample Description:Project Location: Crown Food Mart 9/1/22
Sample ID: 22I0195-02
Field Sample #: SW 02 181
Sample Matrix: Water
Sampled: 9/1/2022 10:25
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 9/6/22 14:44 EEHg/L0.13 9/6/22SW-846 8260D1Diisopropyl Ether (DIPE)
ND 50 9/6/22 14:44 EEHg/L21 9/6/22SW-846 8260D11,4-Dioxane
ND 1.0 9/6/22 14:44 EEHg/L0.21 9/6/22SW-846 8260D1Ethylbenzene
ND 0.60 9/6/22 14:44 EEHg/L0.46 9/6/22SW-846 8260D1Hexachlorobutadiene
ND 10 9/6/22 14:44 EEHg/L1.1 9/6/22SW-846 8260D12-Hexanone (MBK)
ND 1.0 9/6/22 14:44 EEHg/L0.11 9/6/22SW-846 8260D1Isopropylbenzene (Cumene)
ND 1.0 9/6/22 14:44 EEHg/L0.097 9/6/22SW-846 8260D1p-Isopropyltoluene (p-Cymene)
ND 1.0 9/6/22 14:44 EEHg/L0.17 9/6/22SW-846 8260D1Methyl tert-Butyl Ether (MTBE)
0.24 5.0 9/6/22 14:44 EEHg/L0.23 9/6/22SW-846 8260D1JMethylene Chloride
ND 10 9/6/22 14:44 EEHg/L1.3 9/6/22SW-846 8260D14-Methyl-2-pentanone (MIBK)
ND 2.0 9/6/22 14:44 EEHg/L0.24 9/6/22SW-846 8260D1Naphthalene
0.12 1.0 9/6/22 14:44 EEHg/L0.086 9/6/22SW-846 8260D1Jn-Propylbenzene
ND 1.0 9/6/22 14:44 EEHg/L0.11 9/6/22SW-846 8260D1Styrene
ND 1.0 9/6/22 14:44 EEHg/L0.18 9/6/22SW-846 8260D11,1,1,2-Tetrachloroethane
ND 0.50 9/6/22 14:44 EEHg/L0.13 9/6/22SW-846 8260D11,1,2,2-Tetrachloroethane
ND 1.0 9/6/22 14:44 EEHg/L0.19 9/6/22SW-846 8260D1Tetrachloroethylene
ND 10 9/6/22 14:44 EEHg/L0.49 9/6/22SW-846 8260D1Tetrahydrofuran
ND 1.0 9/6/22 14:44 EEHg/L0.22 9/6/22SW-846 8260D1Toluene
ND 5.0 9/6/22 14:44 EEHg/L0.30 9/6/22SW-846 8260D11,2,3-Trichlorobenzene
ND 1.0 9/6/22 14:44 EEHg/L0.25 9/6/22SW-846 8260D11,2,4-Trichlorobenzene
ND 1.0 9/6/22 14:44 EEHg/L0.21 9/6/22SW-846 8260D11,3,5-Trichlorobenzene
ND 1.0 9/6/22 14:44 EEHg/L0.17 9/6/22SW-846 8260D11,1,1-Trichloroethane
ND 1.0 9/6/22 14:44 EEHg/L0.18 9/6/22SW-846 8260D11,1,2-Trichloroethane
ND 1.0 9/6/22 14:44 EEHg/L0.19 9/6/22SW-846 8260D1Trichloroethylene
ND 2.0 9/6/22 14:44 EEHg/L0.18 9/6/22SW-846 8260D1Trichlorofluoromethane (Freon 11)
ND 2.0 9/6/22 14:44 EEHg/L0.28 9/6/22SW-846 8260D11,2,3-Trichloropropane
ND 2.0 9/6/22 14:44 EEHg/L0.23 9/6/22SW-846 8260D11,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
0.79 1.0 9/6/22 14:44 EEHg/L0.20 9/6/22SW-846 8260D1J1,2,4-Trimethylbenzene
0.20 1.0 9/6/22 14:44 EEHg/L0.11 9/6/22SW-846 8260D1J1,3,5-Trimethylbenzene
ND 2.0 9/6/22 14:44 EEHg/L0.21 9/6/22SW-846 8260D1Vinyl Chloride
ND 2.0 9/6/22 14:44 EEHg/L0.46 9/6/22SW-846 8260D1m+p Xylene
ND 1.0 9/6/22 14:44 EEHg/L0.23 9/6/22SW-846 8260D1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 98.6 9/6/22 14:4470-130
Toluene-d8 100 9/6/22 14:4470-130
4-Bromofluorobenzene 102 9/6/22 14:4470-130
Page 9 of 26
Table of Contents
Page 14 of 31
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 9/3/2022
Work Order: 22I0195Sample Description:Project Location: Crown Food Mart 9/1/22
Sample ID: 22I0195-03
Field Sample #: SW 03 181
Sample Matrix: Water
Sampled: 9/1/2022 10:45
[TOC_2]22I0195-03[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 9/6/22 15:12 EEHg/L2.0 9/6/22SW-846 8260D1Acetone
ND 5.0 9/6/22 15:12 EEHg/L0.55 9/6/22SW-846 8260D1Acrylonitrile
ND 0.50 9/6/22 15:12 EEHg/L0.14 9/6/22SW-846 8260D1tert-Amyl Methyl Ether (TAME)
ND 1.0 9/6/22 15:12 EEHg/L0.20 9/6/22SW-846 8260D1Benzene
ND 1.0 9/6/22 15:12 EEHg/L0.15 9/6/22SW-846 8260D1Bromobenzene
ND 1.0 9/6/22 15:12 EEHg/L0.31 9/6/22SW-846 8260D1Bromochloromethane
ND 0.50 9/6/22 15:12 EEHg/L0.18 9/6/22SW-846 8260D1Bromodichloromethane
ND 2.0 9/6/22 15:12 EEHg/L0.38 9/6/22SW-846 8260D1Bromoform
ND 2.0 9/6/22 15:12 EEHg/L1.5 9/6/22SW-846 8260D1Bromomethane
ND 20 9/6/22 15:12 EEHg/L1.6 9/6/22SW-846 8260D12-Butanone (MEK)
ND 20 9/6/22 15:12 EEHg/L4.7 9/6/22SW-846 8260D1tert-Butyl Alcohol (TBA)
ND 1.0 9/6/22 15:12 EEHg/L0.15 9/6/22SW-846 8260D1n-Butylbenzene
ND 1.0 9/6/22 15:12 EEHg/L0.11 9/6/22SW-846 8260D1sec-Butylbenzene
ND 1.0 9/6/22 15:12 EEHg/L0.13 9/6/22SW-846 8260D1tert-Butylbenzene
ND 0.50 9/6/22 15:12 EEHg/L0.15 9/6/22SW-846 8260D1tert-Butyl Ethyl Ether (TBEE)
ND 5.0 9/6/22 15:12 EEHg/L1.4 9/6/22SW-846 8260D1Carbon Disulfide
ND 1.0 9/6/22 15:12 EEHg/L0.16 9/6/22SW-846 8260D1Carbon Tetrachloride
ND 1.0 9/6/22 15:12 EEHg/L0.11 9/6/22SW-846 8260D1Chlorobenzene
ND 0.50 9/6/22 15:12 EEHg/L0.22 9/6/22SW-846 8260D1Chlorodibromomethane
ND 2.0 9/6/22 15:12 EEHg/L0.32 9/6/22SW-846 8260D1Chloroethane
ND 2.0 9/6/22 15:12 EEHg/L0.17 9/6/22SW-846 8260D1Chloroform
ND 2.0 9/6/22 15:12 EEHg/L0.52 9/6/22SW-846 8260D1Chloromethane
ND 1.0 9/6/22 15:12 EEHg/L0.11 9/6/22SW-846 8260D12-Chlorotoluene
ND 1.0 9/6/22 15:12 EEHg/L0.12 9/6/22SW-846 8260D14-Chlorotoluene
ND 5.0 9/6/22 15:12 EEHg/L0.80 9/6/22SW-846 8260D11,2-Dibromo-3-chloropropane (DBCP)
ND 0.50 9/6/22 15:12 EEHg/L0.17 9/6/22SW-846 8260D11,2-Dibromoethane (EDB)
ND 1.0 9/6/22 15:12 EEHg/L0.35 9/6/22SW-846 8260D1Dibromomethane
ND 1.0 9/6/22 15:12 EEHg/L0.12 9/6/22SW-846 8260D11,2-Dichlorobenzene
ND 1.0 9/6/22 15:12 EEHg/L0.12 9/6/22SW-846 8260D11,3-Dichlorobenzene
ND 1.0 9/6/22 15:12 EEHg/L0.13 9/6/22SW-846 8260D11,4-Dichlorobenzene
ND 2.0 9/6/22 15:12 EEHg/L1.6 9/6/22SW-846 8260D1trans-1,4-Dichloro-2-butene
ND 2.0 9/6/22 15:12 EEHg/L0.19 9/6/22SW-846 8260D1Dichlorodifluoromethane (Freon 12)
ND 1.0 9/6/22 15:12 EEHg/L0.14 9/6/22SW-846 8260D11,1-Dichloroethane
ND 1.0 9/6/22 15:12 EEHg/L0.31 9/6/22SW-846 8260D11,2-Dichloroethane
ND 1.0 9/6/22 15:12 EEHg/L0.14 9/6/22SW-846 8260D11,1-Dichloroethylene
ND 1.0 9/6/22 15:12 EEHg/L0.15 9/6/22SW-846 8260D1cis-1,2-Dichloroethylene
ND 1.0 9/6/22 15:12 EEHg/L0.17 9/6/22SW-846 8260D1trans-1,2-Dichloroethylene
ND 1.0 9/6/22 15:12 EEHg/L0.18 9/6/22SW-846 8260D11,2-Dichloropropane
ND 0.50 9/6/22 15:12 EEHg/L0.13 9/6/22SW-846 8260D11,3-Dichloropropane
ND 1.0 9/6/22 15:12 EEHg/L0.33 9/6/22SW-846 8260D12,2-Dichloropropane
ND 2.0 9/6/22 15:12 EEHg/L0.15 9/6/22SW-846 8260D11,1-Dichloropropene
ND 0.50 9/6/22 15:12 EEHg/L0.16 9/6/22SW-846 8260D1cis-1,3-Dichloropropene
ND 0.50 9/6/22 15:12 EEHg/L0.17 9/6/22SW-846 8260D1trans-1,3-Dichloropropene
ND 2.0 9/6/22 15:12 EEHg/L0.18 9/6/22SW-846 8260D1Diethyl Ether
Page 10 of 26
Table of Contents
Page 15 of 31
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 9/3/2022
Work Order: 22I0195Sample Description:Project Location: Crown Food Mart 9/1/22
Sample ID: 22I0195-03
Field Sample #: SW 03 181
Sample Matrix: Water
Sampled: 9/1/2022 10:45
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 9/6/22 15:12 EEHg/L0.13 9/6/22SW-846 8260D1Diisopropyl Ether (DIPE)
ND 50 9/6/22 15:12 EEHg/L21 9/6/22SW-846 8260D11,4-Dioxane
ND 1.0 9/6/22 15:12 EEHg/L0.21 9/6/22SW-846 8260D1Ethylbenzene
ND 0.60 9/6/22 15:12 EEHg/L0.46 9/6/22SW-846 8260D1Hexachlorobutadiene
ND 10 9/6/22 15:12 EEHg/L1.1 9/6/22SW-846 8260D12-Hexanone (MBK)
ND 1.0 9/6/22 15:12 EEHg/L0.11 9/6/22SW-846 8260D1Isopropylbenzene (Cumene)
ND 1.0 9/6/22 15:12 EEHg/L0.097 9/6/22SW-846 8260D1p-Isopropyltoluene (p-Cymene)
ND 1.0 9/6/22 15:12 EEHg/L0.17 9/6/22SW-846 8260D1Methyl tert-Butyl Ether (MTBE)
0.29 5.0 9/6/22 15:12 EEHg/L0.23 9/6/22SW-846 8260D1JMethylene Chloride
ND 10 9/6/22 15:12 EEHg/L1.3 9/6/22SW-846 8260D14-Methyl-2-pentanone (MIBK)
ND 2.0 9/6/22 15:12 EEHg/L0.24 9/6/22SW-846 8260D1Naphthalene
ND 1.0 9/6/22 15:12 EEHg/L0.086 9/6/22SW-846 8260D1n-Propylbenzene
ND 1.0 9/6/22 15:12 EEHg/L0.11 9/6/22SW-846 8260D1Styrene
ND 1.0 9/6/22 15:12 EEHg/L0.18 9/6/22SW-846 8260D11,1,1,2-Tetrachloroethane
ND 0.50 9/6/22 15:12 EEHg/L0.13 9/6/22SW-846 8260D11,1,2,2-Tetrachloroethane
ND 1.0 9/6/22 15:12 EEHg/L0.19 9/6/22SW-846 8260D1Tetrachloroethylene
ND 10 9/6/22 15:12 EEHg/L0.49 9/6/22SW-846 8260D1Tetrahydrofuran
ND 1.0 9/6/22 15:12 EEHg/L0.22 9/6/22SW-846 8260D1Toluene
ND 5.0 9/6/22 15:12 EEHg/L0.30 9/6/22SW-846 8260D11,2,3-Trichlorobenzene
ND 1.0 9/6/22 15:12 EEHg/L0.25 9/6/22SW-846 8260D11,2,4-Trichlorobenzene
ND 1.0 9/6/22 15:12 EEHg/L0.21 9/6/22SW-846 8260D11,3,5-Trichlorobenzene
ND 1.0 9/6/22 15:12 EEHg/L0.17 9/6/22SW-846 8260D11,1,1-Trichloroethane
ND 1.0 9/6/22 15:12 EEHg/L0.18 9/6/22SW-846 8260D11,1,2-Trichloroethane
ND 1.0 9/6/22 15:12 EEHg/L0.19 9/6/22SW-846 8260D1Trichloroethylene
ND 2.0 9/6/22 15:12 EEHg/L0.18 9/6/22SW-846 8260D1Trichlorofluoromethane (Freon 11)
ND 2.0 9/6/22 15:12 EEHg/L0.28 9/6/22SW-846 8260D11,2,3-Trichloropropane
ND 2.0 9/6/22 15:12 EEHg/L0.23 9/6/22SW-846 8260D11,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
0.32 1.0 9/6/22 15:12 EEHg/L0.20 9/6/22SW-846 8260D1J1,2,4-Trimethylbenzene
ND 1.0 9/6/22 15:12 EEHg/L0.11 9/6/22SW-846 8260D11,3,5-Trimethylbenzene
ND 2.0 9/6/22 15:12 EEHg/L0.21 9/6/22SW-846 8260D1Vinyl Chloride
ND 2.0 9/6/22 15:12 EEHg/L0.46 9/6/22SW-846 8260D1m+p Xylene
ND 1.0 9/6/22 15:12 EEHg/L0.23 9/6/22SW-846 8260D1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 100 9/6/22 15:1270-130
Toluene-d8 101 9/6/22 15:1270-130
4-Bromofluorobenzene 102 9/6/22 15:1270-130
Page 11 of 26
Table of Contents
Page 16 of 31
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 9/3/2022
Work Order: 22I0195Sample Description:Project Location: Crown Food Mart 9/1/22
Sample ID: 22I0195-04
Field Sample #: SW 04 181
Sample Matrix: Water
Sampled: 9/1/2022 11:05
[TOC_2]22I0195-04[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 9/6/22 15:40 EEHg/L2.0 9/6/22SW-846 8260D1Acetone
ND 5.0 9/6/22 15:40 EEHg/L0.55 9/6/22SW-846 8260D1Acrylonitrile
ND 0.50 9/6/22 15:40 EEHg/L0.14 9/6/22SW-846 8260D1tert-Amyl Methyl Ether (TAME)
ND 1.0 9/6/22 15:40 EEHg/L0.20 9/6/22SW-846 8260D1Benzene
ND 1.0 9/6/22 15:40 EEHg/L0.15 9/6/22SW-846 8260D1Bromobenzene
ND 1.0 9/6/22 15:40 EEHg/L0.31 9/6/22SW-846 8260D1Bromochloromethane
ND 0.50 9/6/22 15:40 EEHg/L0.18 9/6/22SW-846 8260D1Bromodichloromethane
ND 2.0 9/6/22 15:40 EEHg/L0.38 9/6/22SW-846 8260D1Bromoform
ND 2.0 9/6/22 15:40 EEHg/L1.5 9/6/22SW-846 8260D1Bromomethane
ND 20 9/6/22 15:40 EEHg/L1.6 9/6/22SW-846 8260D12-Butanone (MEK)
ND 20 9/6/22 15:40 EEHg/L4.7 9/6/22SW-846 8260D1tert-Butyl Alcohol (TBA)
ND 1.0 9/6/22 15:40 EEHg/L0.15 9/6/22SW-846 8260D1n-Butylbenzene
ND 1.0 9/6/22 15:40 EEHg/L0.11 9/6/22SW-846 8260D1sec-Butylbenzene
ND 1.0 9/6/22 15:40 EEHg/L0.13 9/6/22SW-846 8260D1tert-Butylbenzene
ND 0.50 9/6/22 15:40 EEHg/L0.15 9/6/22SW-846 8260D1tert-Butyl Ethyl Ether (TBEE)
ND 5.0 9/6/22 15:40 EEHg/L1.4 9/6/22SW-846 8260D1Carbon Disulfide
ND 1.0 9/6/22 15:40 EEHg/L0.16 9/6/22SW-846 8260D1Carbon Tetrachloride
ND 1.0 9/6/22 15:40 EEHg/L0.11 9/6/22SW-846 8260D1Chlorobenzene
ND 0.50 9/6/22 15:40 EEHg/L0.22 9/6/22SW-846 8260D1Chlorodibromomethane
ND 2.0 9/6/22 15:40 EEHg/L0.32 9/6/22SW-846 8260D1Chloroethane
ND 2.0 9/6/22 15:40 EEHg/L0.17 9/6/22SW-846 8260D1Chloroform
ND 2.0 9/6/22 15:40 EEHg/L0.52 9/6/22SW-846 8260D1Chloromethane
ND 1.0 9/6/22 15:40 EEHg/L0.11 9/6/22SW-846 8260D12-Chlorotoluene
ND 1.0 9/6/22 15:40 EEHg/L0.12 9/6/22SW-846 8260D14-Chlorotoluene
ND 5.0 9/6/22 15:40 EEHg/L0.80 9/6/22SW-846 8260D11,2-Dibromo-3-chloropropane (DBCP)
ND 0.50 9/6/22 15:40 EEHg/L0.17 9/6/22SW-846 8260D11,2-Dibromoethane (EDB)
ND 1.0 9/6/22 15:40 EEHg/L0.35 9/6/22SW-846 8260D1Dibromomethane
ND 1.0 9/6/22 15:40 EEHg/L0.12 9/6/22SW-846 8260D11,2-Dichlorobenzene
ND 1.0 9/6/22 15:40 EEHg/L0.12 9/6/22SW-846 8260D11,3-Dichlorobenzene
ND 1.0 9/6/22 15:40 EEHg/L0.13 9/6/22SW-846 8260D11,4-Dichlorobenzene
ND 2.0 9/6/22 15:40 EEHg/L1.6 9/6/22SW-846 8260D1trans-1,4-Dichloro-2-butene
ND 2.0 9/6/22 15:40 EEHg/L0.19 9/6/22SW-846 8260D1Dichlorodifluoromethane (Freon 12)
ND 1.0 9/6/22 15:40 EEHg/L0.14 9/6/22SW-846 8260D11,1-Dichloroethane
ND 1.0 9/6/22 15:40 EEHg/L0.31 9/6/22SW-846 8260D11,2-Dichloroethane
ND 1.0 9/6/22 15:40 EEHg/L0.14 9/6/22SW-846 8260D11,1-Dichloroethylene
ND 1.0 9/6/22 15:40 EEHg/L0.15 9/6/22SW-846 8260D1cis-1,2-Dichloroethylene
ND 1.0 9/6/22 15:40 EEHg/L0.17 9/6/22SW-846 8260D1trans-1,2-Dichloroethylene
ND 1.0 9/6/22 15:40 EEHg/L0.18 9/6/22SW-846 8260D11,2-Dichloropropane
ND 0.50 9/6/22 15:40 EEHg/L0.13 9/6/22SW-846 8260D11,3-Dichloropropane
ND 1.0 9/6/22 15:40 EEHg/L0.33 9/6/22SW-846 8260D12,2-Dichloropropane
ND 2.0 9/6/22 15:40 EEHg/L0.15 9/6/22SW-846 8260D11,1-Dichloropropene
ND 0.50 9/6/22 15:40 EEHg/L0.16 9/6/22SW-846 8260D1cis-1,3-Dichloropropene
ND 0.50 9/6/22 15:40 EEHg/L0.17 9/6/22SW-846 8260D1trans-1,3-Dichloropropene
ND 2.0 9/6/22 15:40 EEHg/L0.18 9/6/22SW-846 8260D1Diethyl Ether
Page 12 of 26
Table of Contents
Page 17 of 31
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 9/3/2022
Work Order: 22I0195Sample Description:Project Location: Crown Food Mart 9/1/22
Sample ID: 22I0195-04
Field Sample #: SW 04 181
Sample Matrix: Water
Sampled: 9/1/2022 11:05
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 9/6/22 15:40 EEHg/L0.13 9/6/22SW-846 8260D1Diisopropyl Ether (DIPE)
ND 50 9/6/22 15:40 EEHg/L21 9/6/22SW-846 8260D11,4-Dioxane
ND 1.0 9/6/22 15:40 EEHg/L0.21 9/6/22SW-846 8260D1Ethylbenzene
ND 0.60 9/6/22 15:40 EEHg/L0.46 9/6/22SW-846 8260D1Hexachlorobutadiene
ND 10 9/6/22 15:40 EEHg/L1.1 9/6/22SW-846 8260D12-Hexanone (MBK)
ND 1.0 9/6/22 15:40 EEHg/L0.11 9/6/22SW-846 8260D1Isopropylbenzene (Cumene)
ND 1.0 9/6/22 15:40 EEHg/L0.097 9/6/22SW-846 8260D1p-Isopropyltoluene (p-Cymene)
ND 1.0 9/6/22 15:40 EEHg/L0.17 9/6/22SW-846 8260D1Methyl tert-Butyl Ether (MTBE)
0.25 5.0 9/6/22 15:40 EEHg/L0.23 9/6/22SW-846 8260D1JMethylene Chloride
ND 10 9/6/22 15:40 EEHg/L1.3 9/6/22SW-846 8260D14-Methyl-2-pentanone (MIBK)
ND 2.0 9/6/22 15:40 EEHg/L0.24 9/6/22SW-846 8260D1Naphthalene
ND 1.0 9/6/22 15:40 EEHg/L0.086 9/6/22SW-846 8260D1n-Propylbenzene
ND 1.0 9/6/22 15:40 EEHg/L0.11 9/6/22SW-846 8260D1Styrene
ND 1.0 9/6/22 15:40 EEHg/L0.18 9/6/22SW-846 8260D11,1,1,2-Tetrachloroethane
ND 0.50 9/6/22 15:40 EEHg/L0.13 9/6/22SW-846 8260D11,1,2,2-Tetrachloroethane
ND 1.0 9/6/22 15:40 EEHg/L0.19 9/6/22SW-846 8260D1Tetrachloroethylene
ND 10 9/6/22 15:40 EEHg/L0.49 9/6/22SW-846 8260D1Tetrahydrofuran
ND 1.0 9/6/22 15:40 EEHg/L0.22 9/6/22SW-846 8260D1Toluene
ND 5.0 9/6/22 15:40 EEHg/L0.30 9/6/22SW-846 8260D11,2,3-Trichlorobenzene
ND 1.0 9/6/22 15:40 EEHg/L0.25 9/6/22SW-846 8260D11,2,4-Trichlorobenzene
ND 1.0 9/6/22 15:40 EEHg/L0.21 9/6/22SW-846 8260D11,3,5-Trichlorobenzene
ND 1.0 9/6/22 15:40 EEHg/L0.17 9/6/22SW-846 8260D11,1,1-Trichloroethane
ND 1.0 9/6/22 15:40 EEHg/L0.18 9/6/22SW-846 8260D11,1,2-Trichloroethane
ND 1.0 9/6/22 15:40 EEHg/L0.19 9/6/22SW-846 8260D1Trichloroethylene
ND 2.0 9/6/22 15:40 EEHg/L0.18 9/6/22SW-846 8260D1Trichlorofluoromethane (Freon 11)
ND 2.0 9/6/22 15:40 EEHg/L0.28 9/6/22SW-846 8260D11,2,3-Trichloropropane
ND 2.0 9/6/22 15:40 EEHg/L0.23 9/6/22SW-846 8260D11,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
ND 1.0 9/6/22 15:40 EEHg/L0.20 9/6/22SW-846 8260D11,2,4-Trimethylbenzene
ND 1.0 9/6/22 15:40 EEHg/L0.11 9/6/22SW-846 8260D11,3,5-Trimethylbenzene
ND 2.0 9/6/22 15:40 EEHg/L0.21 9/6/22SW-846 8260D1Vinyl Chloride
ND 2.0 9/6/22 15:40 EEHg/L0.46 9/6/22SW-846 8260D1m+p Xylene
ND 1.0 9/6/22 15:40 EEHg/L0.23 9/6/22SW-846 8260D1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 100 9/6/22 15:4070-130
Toluene-d8 99.9 9/6/22 15:4070-130
4-Bromofluorobenzene 103 9/6/22 15:4070-130
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Page 18 of 31
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Sample Extraction Data
Prep Method: SW-846 5030B Analytical Method: SW-846 8260D
Lab Number [Field ID]Batch DateInitial [mL]Final [mL]
B316550 09/06/225 5.0022I0195-01 [SW 01 181]
B316550 09/06/225 5.0022I0195-02 [SW 02 181]
B316550 09/06/225 5.0022I0195-03 [SW 03 181]
B316550 09/06/225 5.0022I0195-04 [SW 04 181]
[TOC_1]Sample Preparation Information[TOC]
Page 14 of 26
Table of Contents
Page 19 of 31
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
[TOC_2]Volatile Organic Compounds by GC/MS[TOC]
Batch B316550 - SW-846 5030B
[TOC_3]B316550[TOC]
Blank (B316550-BLK1) Prepared & Analyzed: 09/06/22
Acetone g/L50ND
Acrylonitrile g/L5.0ND
tert-Amyl Methyl Ether (TAME)g/L0.50ND
Benzene g/L1.0ND
Bromobenzene g/L1.0ND
Bromochloromethane g/L1.0ND
Bromodichloromethane g/L0.50ND
Bromoform g/L1.0ND
Bromomethane g/L2.0ND
2-Butanone (MEK)g/L20ND
tert-Butyl Alcohol (TBA)g/L20ND
n-Butylbenzene g/L1.0ND
sec-Butylbenzene g/L1.0ND
tert-Butylbenzene g/L1.0ND
tert-Butyl Ethyl Ether (TBEE)g/L0.50ND
Carbon Disulfide g/L5.0ND
Carbon Tetrachloride g/L1.0ND
Chlorobenzene g/L1.0ND
Chlorodibromomethane g/L0.50ND
Chloroethane g/L2.0ND
Chloroform g/L2.0ND
Chloromethane g/L2.0ND
2-Chlorotoluene g/L1.0ND
4-Chlorotoluene g/L1.0ND
1,2-Dibromo-3-chloropropane (DBCP)g/L5.0ND
1,2-Dibromoethane (EDB)g/L0.50ND
Dibromomethane g/L1.0ND
1,2-Dichlorobenzene g/L1.0ND
1,3-Dichlorobenzene g/L1.0ND
1,4-Dichlorobenzene g/L1.0ND
trans-1,4-Dichloro-2-butene g/L2.0ND
Dichlorodifluoromethane (Freon 12)g/L2.0ND
1,1-Dichloroethane g/L1.0ND
1,2-Dichloroethane g/L1.0ND
1,1-Dichloroethylene g/L1.0ND
cis-1,2-Dichloroethylene g/L1.0ND
trans-1,2-Dichloroethylene g/L1.0ND
1,2-Dichloropropane g/L1.0ND
1,3-Dichloropropane g/L0.50ND
2,2-Dichloropropane g/L1.0ND
1,1-Dichloropropene g/L2.0ND
cis-1,3-Dichloropropene g/L0.50ND
trans-1,3-Dichloropropene g/L0.50ND
Diethyl Ether g/L2.0ND
Diisopropyl Ether (DIPE)g/L0.50ND
1,4-Dioxane g/L50ND
Ethylbenzene g/L1.0ND
Hexachlorobutadiene g/L0.60ND
2-Hexanone (MBK)g/L10ND
Isopropylbenzene (Cumene)g/L1.0ND
p-Isopropyltoluene (p-Cymene)g/L1.0ND
Methyl tert-Butyl Ether (MTBE)g/L1.0ND
[TOC_1]QC Data[TOC]
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B316550 - SW-846 5030B
Blank (B316550-BLK1) Prepared & Analyzed: 09/06/22
Methylene Chloride g/L5.0ND
4-Methyl-2-pentanone (MIBK)g/L10ND
Naphthalene g/L2.0ND
n-Propylbenzene g/L1.0ND
Styrene g/L1.0ND
1,1,1,2-Tetrachloroethane g/L1.0ND
1,1,2,2-Tetrachloroethane g/L0.50ND
Tetrachloroethylene g/L1.0ND
Tetrahydrofuran g/L10ND
Toluene g/L1.0ND
1,2,3-Trichlorobenzene g/L5.0ND
1,2,4-Trichlorobenzene g/L1.0ND
1,3,5-Trichlorobenzene g/L1.0ND
1,1,1-Trichloroethane g/L1.0ND
1,1,2-Trichloroethane g/L1.0ND
Trichloroethylene g/L1.0ND
Trichlorofluoromethane (Freon 11)g/L2.0ND
1,2,3-Trichloropropane g/L2.0ND
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon
113)
g/L1.0ND
1,2,4-Trimethylbenzene g/L1.0ND
1,3,5-Trimethylbenzene g/L1.0ND
Vinyl Acetate g/L20ND
Vinyl Chloride g/L2.0ND
m+p Xylene g/L2.0ND
o-Xylene g/L1.0ND
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 10225.4
g/L 25.0 70-130Surrogate: Toluene-d8 10125.2
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 10225.6
LCS (B316550-BS1) Prepared & Analyzed: 09/06/22
Acetone g/L50 100 70-160118118
Acrylonitrile g/L5.0 10.0 70-13011411.4
tert-Amyl Methyl Ether (TAME)g/L0.50 10.0 70-13010810.8
Benzene g/L1.0 10.0 70-13091.99.19
Bromobenzene g/L1.0 10.0 70-13011211.2
Bromochloromethane g/L1.0 10.0 70-13012012.0
Bromodichloromethane g/L0.50 10.0 70-13011211.2
Bromoform g/L1.0 10.0 70-13011611.6
Bromomethane g/L2.0 10.0 40-16010810.8
2-Butanone (MEK)g/L20 100 V-0640-160126126
tert-Butyl Alcohol (TBA)g/L20 100 40-160111111
n-Butylbenzene g/L1.0 10.0 70-13011011.0
sec-Butylbenzene g/L1.0 10.0 70-13010910.9
tert-Butylbenzene g/L1.0 10.0 70-13011111.1
tert-Butyl Ethyl Ether (TBEE)g/L0.50 10.0 70-13011411.4
Carbon Disulfide g/L5.0 100 V-2070-130119119
Carbon Tetrachloride g/L1.0 10.0 70-13010510.5
Chlorobenzene g/L1.0 10.0 70-13010110.1
Chlorodibromomethane g/L0.50 10.0 70-13011311.3
Chloroethane g/L2.0 10.0 70-13012012.0
Chloroform g/L2.0 10.0 70-13010210.2
Chloromethane g/L2.0 10.0 40-16013913.9
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B316550 - SW-846 5030B
LCS (B316550-BS1) Prepared & Analyzed: 09/06/22
2-Chlorotoluene g/L1.0 10.0 70-13098.49.84
4-Chlorotoluene g/L1.0 10.0 70-13010810.8
1,2-Dibromo-3-chloropropane (DBCP)g/L5.0 10.0 70-13011411.4
1,2-Dibromoethane (EDB)g/L0.50 10.0 70-13010310.3
Dibromomethane g/L1.0 10.0 70-13010510.5
1,2-Dichlorobenzene g/L1.0 10.0 70-13010610.6
1,3-Dichlorobenzene g/L1.0 10.0 70-13010610.6
1,4-Dichlorobenzene g/L1.0 10.0 70-13010310.3
trans-1,4-Dichloro-2-butene g/L2.0 10.0 L-02, V-2070-130132*13.2
Dichlorodifluoromethane (Freon 12)g/L2.0 10.0 40-16091.79.17
1,1-Dichloroethane g/L1.0 10.0 70-13010510.5
1,2-Dichloroethane g/L1.0 10.0 70-13010310.3
1,1-Dichloroethylene g/L1.0 10.0 70-13098.49.84
cis-1,2-Dichloroethylene g/L1.0 10.0 70-13010710.7
trans-1,2-Dichloroethylene g/L1.0 10.0 70-13010210.2
1,2-Dichloropropane g/L1.0 10.0 70-13011411.4
1,3-Dichloropropane g/L0.50 10.0 70-13010710.7
2,2-Dichloropropane g/L1.0 10.0 40-13011111.1
1,1-Dichloropropene g/L2.0 10.0 70-13010310.3
cis-1,3-Dichloropropene g/L0.50 10.0 70-13011411.4
trans-1,3-Dichloropropene g/L0.50 10.0 70-13011611.6
Diethyl Ether g/L2.0 10.0 70-13011011.0
Diisopropyl Ether (DIPE)g/L0.50 10.0 V-2070-13012412.4
1,4-Dioxane g/L50 100 40-130106106
Ethylbenzene g/L1.0 10.0 70-13010510.5
Hexachlorobutadiene g/L0.60 10.0 L-02, V-2070-130133*13.3
2-Hexanone (MBK)g/L10 100 V-2070-160133133
Isopropylbenzene (Cumene)g/L1.0 10.0 70-13010610.6
p-Isopropyltoluene (p-Cymene)g/L1.0 10.0 70-13011311.3
Methyl tert-Butyl Ether (MTBE)g/L1.0 10.0 70-13011211.2
Methylene Chloride g/L5.0 10.0 70-13011711.7
4-Methyl-2-pentanone (MIBK)g/L10 100 V-2070-160133133
Naphthalene g/L2.0 10.0 40-13012012.0
n-Propylbenzene g/L1.0 10.0 70-13011111.1
Styrene g/L1.0 10.0 70-13010710.7
1,1,1,2-Tetrachloroethane g/L1.0 10.0 70-13010610.6
1,1,2,2-Tetrachloroethane g/L0.50 10.0 70-13010910.9
Tetrachloroethylene g/L1.0 10.0 70-13010910.9
Tetrahydrofuran g/L10 10.0 L-07, V-2070-130132*13.2
Toluene g/L1.0 10.0 70-13097.89.78
1,2,3-Trichlorobenzene g/L5.0 10.0 70-13012312.3
1,2,4-Trichlorobenzene g/L1.0 10.0 70-13011611.6
1,3,5-Trichlorobenzene g/L1.0 10.0 70-13011611.6
1,1,1-Trichloroethane g/L1.0 10.0 70-13010610.6
1,1,2-Trichloroethane g/L1.0 10.0 70-13010810.8
Trichloroethylene g/L1.0 10.0 70-13010710.7
Trichlorofluoromethane (Freon 11)g/L2.0 10.0 70-13098.89.88
1,2,3-Trichloropropane g/L2.0 10.0 70-13011111.1
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon
113)
g/L1.0 10.0 70-13011611.6
1,2,4-Trimethylbenzene g/L1.0 10.0 70-13010510.5
1,3,5-Trimethylbenzene g/L1.0 10.0 70-13010910.9
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Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B316550 - SW-846 5030B
LCS (B316550-BS1) Prepared & Analyzed: 09/06/22
Vinyl Acetate g/L20 100 V-2070-130123123
Vinyl Chloride g/L2.0 10.0 L-02, V-2040-160319*31.9
m+p Xylene g/L2.0 20.0 70-13010420.8
o-Xylene g/L1.0 10.0 70-13010710.7
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 99.024.8
g/L 25.0 70-130Surrogate: Toluene-d8 99.224.8
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 10425.9
LCS Dup (B316550-BSD1) Prepared & Analyzed: 09/06/22
Acetone g/L50 100 2570-160122 3.80122
Acrylonitrile g/L5.0 10.0 2570-130120 5.3812.0
tert-Amyl Methyl Ether (TAME)g/L0.50 10.0 2570-130109 1.2010.9
Benzene g/L1.0 10.0 2570-13095.7 4.059.57
Bromobenzene g/L1.0 10.0 2570-130119 6.2411.9
Bromochloromethane g/L1.0 10.0 2570-130125 4.1012.5
Bromodichloromethane g/L0.50 10.0 2570-130112 0.17911.2
Bromoform g/L1.0 10.0 2570-130123 6.2012.3
Bromomethane g/L2.0 10.0 2540-160120 10.112.0
2-Butanone (MEK)g/L20 100 25 V-0640-160119 5.50119
tert-Butyl Alcohol (TBA)g/L20 100 2540-160120 7.96120
n-Butylbenzene g/L1.0 10.0 2570-130114 3.5911.4
sec-Butylbenzene g/L1.0 10.0 2570-130111 2.0011.1
tert-Butylbenzene g/L1.0 10.0 2570-130112 0.98711.2
tert-Butyl Ethyl Ether (TBEE)g/L0.50 10.0 2570-130121 5.7712.1
Carbon Disulfide g/L5.0 100 25 V-2070-130126 5.49126
Carbon Tetrachloride g/L1.0 10.0 2570-130109 3.7410.9
Chlorobenzene g/L1.0 10.0 2570-130106 5.3210.6
Chlorodibromomethane g/L0.50 10.0 2570-130116 2.7111.6
Chloroethane g/L2.0 10.0 2570-130130 7.4313.0
Chloroform g/L2.0 10.0 2570-130106 3.9310.6
Chloromethane g/L2.0 10.0 2540-160138 0.72213.8
2-Chlorotoluene g/L1.0 10.0 2570-130102 3.7910.2
4-Chlorotoluene g/L1.0 10.0 2570-130113 4.6011.3
1,2-Dibromo-3-chloropropane (DBCP)g/L5.0 10.0 2570-130117 2.8611.7
1,2-Dibromoethane (EDB)g/L0.50 10.0 2570-130107 4.0910.7
Dibromomethane g/L1.0 10.0 2570-130112 5.9011.2
1,2-Dichlorobenzene g/L1.0 10.0 2570-130110 3.2411.0
1,3-Dichlorobenzene g/L1.0 10.0 2570-130109 2.4110.9
1,4-Dichlorobenzene g/L1.0 10.0 2570-130106 2.1110.6
trans-1,4-Dichloro-2-butene g/L2.0 10.0 25 L-02, V-2070-130134 1.35*13.4
Dichlorodifluoromethane (Freon 12)g/L2.0 10.0 2540-16095.7 4.279.57
1,1-Dichloroethane g/L1.0 10.0 2570-130112 5.7111.2
1,2-Dichloroethane g/L1.0 10.0 2570-130108 4.9210.8
1,1-Dichloroethylene g/L1.0 10.0 2570-130109 9.9510.9
cis-1,2-Dichloroethylene g/L1.0 10.0 2570-130112 4.7511.2
trans-1,2-Dichloroethylene g/L1.0 10.0 2570-130106 3.4610.6
1,2-Dichloropropane g/L1.0 10.0 2570-130117 2.6011.7
1,3-Dichloropropane g/L0.50 10.0 2570-130114 6.7911.4
2,2-Dichloropropane g/L1.0 10.0 2540-130113 1.7011.3
1,1-Dichloropropene g/L2.0 10.0 2570-130105 2.1210.5
cis-1,3-Dichloropropene g/L0.50 10.0 2570-130117 2.9411.7
trans-1,3-Dichloropropene g/L0.50 10.0 2570-130122 4.5412.2
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Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B316550 - SW-846 5030B
LCS Dup (B316550-BSD1) Prepared & Analyzed: 09/06/22
Diethyl Ether g/L2.0 10.0 2570-130116 5.1411.6
Diisopropyl Ether (DIPE)g/L0.50 10.0 25 V-2070-130127 2.0712.7
1,4-Dioxane g/L50 100 5040-130117 10.7117
Ethylbenzene g/L1.0 10.0 2570-130110 4.7511.0
Hexachlorobutadiene g/L0.60 10.0 25 L-02, V-2070-130136 2.75*13.6
2-Hexanone (MBK)g/L10 100 25 V-2070-160132 0.446132
Isopropylbenzene (Cumene)g/L1.0 10.0 2570-130111 4.1511.1
p-Isopropyltoluene (p-Cymene)g/L1.0 10.0 2570-130114 1.2411.4
Methyl tert-Butyl Ether (MTBE)g/L1.0 10.0 2570-130114 2.0411.4
Methylene Chloride g/L5.0 10.0 2570-130124 5.9612.4
4-Methyl-2-pentanone (MIBK)g/L10 100 25 V-2070-160136 1.89136
Naphthalene g/L2.0 10.0 2540-130119 0.92311.9
n-Propylbenzene g/L1.0 10.0 2570-130114 2.5811.4
Styrene g/L1.0 10.0 2570-130111 2.9411.1
1,1,1,2-Tetrachloroethane g/L1.0 10.0 2570-130114 7.4311.4
1,1,2,2-Tetrachloroethane g/L0.50 10.0 2570-130112 2.1711.2
Tetrachloroethylene g/L1.0 10.0 2570-130111 2.0011.1
Tetrahydrofuran g/L10 10.0 25 V-2070-130121 8.1512.1
Toluene g/L1.0 10.0 2570-130103 4.7910.3
1,2,3-Trichlorobenzene g/L5.0 10.0 2570-130124 0.64912.4
1,2,4-Trichlorobenzene g/L1.0 10.0 2570-130115 0.34711.5
1,3,5-Trichlorobenzene g/L1.0 10.0 2570-130112 3.1611.2
1,1,1-Trichloroethane g/L1.0 10.0 2570-130111 4.8811.1
1,1,2-Trichloroethane g/L1.0 10.0 2570-130111 3.3811.1
Trichloroethylene g/L1.0 10.0 2570-130111 3.6711.1
Trichlorofluoromethane (Freon 11)g/L2.0 10.0 2570-130103 3.8710.3
1,2,3-Trichloropropane g/L2.0 10.0 2570-130114 2.6611.4
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon
113)
g/L1.0 10.0 2570-130124 6.8612.4
1,2,4-Trimethylbenzene g/L1.0 10.0 2570-130107 1.7010.7
1,3,5-Trimethylbenzene g/L1.0 10.0 2570-130111 2.2711.1
Vinyl Acetate g/L20 100 25 V-2070-130126 2.71126
Vinyl Chloride g/L2.0 10.0 25 L-02, V-2040-160343 7.31*34.3
m+p Xylene g/L2.0 20.0 2570-130108 4.3321.7
o-Xylene g/L1.0 10.0 2570-130111 4.3111.1
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 99.624.9
g/L 25.0 70-130Surrogate: Toluene-d8 99.724.9
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 10526.4
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FLAG/QUALIFIER SUMMARY
*QC result is outside of established limits.
Wide recovery limits established for difficult compound.
Wide RPD limits established for difficult compound.
#Data exceeded client recommended or regulatory level
Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the
calculation which have not been rounded.
No results have been blank subtracted unless specified in the case narrative section.
RL Reporting Limit is at the level of quantitation (LOQ)
DL Detection Limit is the lower limit of detection determined by the MDL study
MCL Maximum Contaminant Level
ND Not Detected
Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated
concentration (CLP J-Flag).
J
Laboratory fortified blank/laboratory control sample recovery and duplicate recoveries outside of control limits.
Data validation is not affected since all results are "not detected" for associated samples in this batch and bias is
on the high side.
L-02
Either laboratory fortified blank/laboratory control sample or duplicate recovery is outside of control limits, but
the other is within limits. RPD between the two LFB/LCS results is within method specified criteria.
L-07
Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side for
this compound.
V-06
Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side.
Data validation is not affected since sample result was "not detected" for this compound.
V-20
[TOC_1]Flag/Qualifier Summary[TOC]
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CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
SW-846 8260D in Water
NCAcetone
NCAcrylonitrile
NCtert-Amyl Methyl Ether (TAME)
NCBenzene
NCBromobenzene
NCBromochloromethane
NCBromodichloromethane
NCBromoform
NCBromomethane
NC2-Butanone (MEK)
NCtert-Butyl Alcohol (TBA)
NCn-Butylbenzene
NCsec-Butylbenzene
NCtert-Butylbenzene
NCtert-Butyl Ethyl Ether (TBEE)
NCCarbon Disulfide
NCCarbon Tetrachloride
NCChlorobenzene
NCChlorodibromomethane
NCChloroethane
NCChloroform
NCChloromethane
NC2-Chlorotoluene
NC4-Chlorotoluene
NC1,2-Dibromo-3-chloropropane (DBCP)
NC1,2-Dibromoethane (EDB)
NCDibromomethane
NC1,2-Dichlorobenzene
NC1,3-Dichlorobenzene
NC1,4-Dichlorobenzene
NCtrans-1,4-Dichloro-2-butene
NCDichlorodifluoromethane (Freon 12)
NC1,1-Dichloroethane
NC1,2-Dichloroethane
NC1,1-Dichloroethylene
NCcis-1,2-Dichloroethylene
NCtrans-1,2-Dichloroethylene
NC1,2-Dichloropropane
NC1,3-Dichloropropane
NC2,2-Dichloropropane
NC1,1-Dichloropropene
NCcis-1,3-Dichloropropene
NCtrans-1,3-Dichloropropene
NCDiethyl Ether
NCDiisopropyl Ether (DIPE)
NC1,4-Dioxane
NCEthylbenzene
[TOC_1]Certifications[TOC]
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CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
SW-846 8260D in Water
NCHexachlorobutadiene
NC2-Hexanone (MBK)
NCIsopropylbenzene (Cumene)
NCp-Isopropyltoluene (p-Cymene)
NCMethyl tert-Butyl Ether (MTBE)
NCMethylene Chloride
NC4-Methyl-2-pentanone (MIBK)
NCNaphthalene
NCn-Propylbenzene
NCStyrene
NC1,1,1,2-Tetrachloroethane
NC1,1,2,2-Tetrachloroethane
NCTetrachloroethylene
NCTetrahydrofuran
NCToluene
NC1,2,3-Trichlorobenzene
NC1,2,4-Trichlorobenzene
NC1,3,5-Trichlorobenzene
NC1,1,1-Trichloroethane
NC1,1,2-Trichloroethane
NCTrichloroethylene
NCTrichlorofluoromethane (Freon 11)
NC1,2,3-Trichloropropane
NC1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)
NC1,2,4-Trimethylbenzene
NC1,3,5-Trimethylbenzene
NCVinyl Chloride
NCm+p Xylene
NCo-Xylene
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Con-Test, a Pace Environmental Laboratory, operates under the following certifications and accreditations:
Code Description Number Expires
100033AIHA-LAP, LLC - ISO 17025:2017AIHA 03/1/2024
M-MA100Massachusetts DEPMA 06/30/2023
PH-0165Connecticut Department of Public HealthCT 12/31/2022
10899 NELAPNew York State Department of HealthNY 04/1/2023
2516 NELAPNew Hampshire Environmental LabNH 02/5/2023
LAO00373Rhode Island Department of HealthRI 12/30/2022
652North Carolina Div. of Water QualityNC 12/31/2022
MA007 NELAPNew Jersey DEPNJ 06/30/2023
E871027 NELAPFlorida Department of HealthFL 06/30/2023
LL720741Vermont Department of Health Lead LaboratoryVT 07/30/2023
VT-255716Vermont Department of Health Drinking WaterVT-DW 06/12/2023
MA00100State of MaineME 06/9/2023
460217Commonwealth of VirginiaVA 12/14/2022
2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2023
25703North Carolina Department of Health and Human ServicesNC-DW 07/31/2023
68-05812Commonwealth of Pennsylvania DEPPA 06/30/2023
9100Dept. of Env, Great Lakes, and EnergyMI 09/6/2022
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#=CL#
September 26, 2022
LIMS USE: FR - ROBERT MARTIN
LIMS OBJECT ID: 92626123
92626123
Project:
Pace Project No.:
RE:
Mr. Robert Martin
Martin and Slagle
24 Lookout Terrace
Black Mountain, NC 28711
Crown food Mart 9/15
Dear Mr. Martin:
Enclosed are the analytical results for sample(s) received by the laboratory on September 16, 2022. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lorri Patton
[e-mail]
Project Manager
1(828)254-7176
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 1 of 30
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92626123
Crown food Mart 9/15
Lab ID Sample ID Matrix Date Collected Date Received
92626123001 SW 01 182 Water 09/15/22 11:10 09/16/22 10:45
92626123002 SW 02 182 Water 09/15/22 11:45 09/16/22 10:45
92626123003 SW 03 182 Water 09/15/22 12:00 09/16/22 10:45
92626123004 SW 04 182 Water 09/15/22 12:20 09/16/22 10:45
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 2 of 30
Page 3 of 30
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
September 26, 2022
Lorri Patton
Pace Analytical Services - NC
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Project Location: Crown Food Mart 9/15
Client Job Number:
Project Number: 92626123
Laboratory Work Order Number: 22I1020
Enclosed are results of analyses for samples as received by the laboratory on September 17, 2022. If you have any questions
concerning this report, please feel free to contact me.
Sincerely,
Kerry K. McGee
Project Manager
Page 1 of 25
Table of Contents
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Table of Contents
Sample Summary 3
Case Narrative 4
Sample Results 5
22I1020-01 5
22I1020-02 7
22I1020-03 9
22I1020-04 11
Sample Preparation Information 13
QC Data 14
Volatile Organic Compounds by GC/MS 14
B317807 14
Flag/Qualifier Summary 19
Certifications 20
Chain of Custody/Sample Receipt 23
Page 2 of 25
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ANALYTICAL SUMMARY
9/26/2022
Pace Analytical Services - NC
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
ATTN: Lorri Patton
92626123
22I1020
The results of analyses performed on the following samples submitted to CON-TEST, a Pace Analytical Laboratory, are found in this report.
PROJECT LOCATION:
PURCHASE ORDER NUMBER:
PROJECT NUMBER:
REPORT DATE:
WORK ORDER NUMBER:
FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB
Crown Food Mart 9/15
SW 01 182 22I1020-01 Water SW-846 8260D
SW 02 182 22I1020-02 Water SW-846 8260D
SW 03 182 22I1020-03 Water SW-846 8260D
SW 04 182 22I1020-04 Water SW-846 8260D
[TOC_1]Sample Summary[TOC]
Page 3 of 25
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CASE NARRATIVE SUMMARY
All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report.
[TOC_1]Case Narrative[TOC]
SW-846 8260D
Qualifications:
Either laboratory fortified blank/laboratory control sample or duplicate recovery is outside of control limits, but the other is within limits. RPD
between the two LFB/LCS results is within method specified criteria.
Analyte & Samples(s) Qualified:
L-07
Carbon Disulfide
B317807-BS1
trans-1,2-Dichloroethylene
B317807-BSD1
Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side. Data validation is not affected
since sample result was "not detected" for this compound.
Analyte & Samples(s) Qualified:
V-20
Bromomethane
B317807-BS1, B317807-BSD1, S076893-CCV1
Carbon Disulfide
B317807-BS1, B317807-BSD1, S076893-CCV1
trans-1,2-Dichloroethylene
B317807-BS1, B317807-BSD1, S076893-CCV1
The results of analyses reported only relate to samples submitted to Con-Test, a Pace Analytical Laboratory, for testing.
I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed
in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the
best of my knowledge and belief, accurate and complete.
Lisa A. Worthington
Technical Representative
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Date Received: 9/17/2022
Work Order: 22I1020Sample Description:Project Location: Crown Food Mart 9/15
Sample ID: 22I1020-01
Field Sample #: SW 01 182
Sample Matrix: Water
Sampled: 9/15/2022 11:10
[TOC_2]22I1020-01[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 9/22/22 17:15 EEHg/L2.0 9/22/22SW-846 8260D1Acetone
ND 5.0 9/22/22 17:15 EEHg/L0.55 9/22/22SW-846 8260D1Acrylonitrile
ND 0.50 9/22/22 17:15 EEHg/L0.14 9/22/22SW-846 8260D1tert-Amyl Methyl Ether (TAME)
ND 1.0 9/22/22 17:15 EEHg/L0.20 9/22/22SW-846 8260D1Benzene
ND 1.0 9/22/22 17:15 EEHg/L0.15 9/22/22SW-846 8260D1Bromobenzene
ND 1.0 9/22/22 17:15 EEHg/L0.31 9/22/22SW-846 8260D1Bromochloromethane
ND 0.50 9/22/22 17:15 EEHg/L0.18 9/22/22SW-846 8260D1Bromodichloromethane
ND 2.0 9/22/22 17:15 EEHg/L0.38 9/22/22SW-846 8260D1Bromoform
ND 2.0 9/22/22 17:15 EEHg/L1.5 9/22/22SW-846 8260D1Bromomethane
ND 20 9/22/22 17:15 EEHg/L1.6 9/22/22SW-846 8260D12-Butanone (MEK)
ND 20 9/22/22 17:15 EEHg/L4.7 9/22/22SW-846 8260D1tert-Butyl Alcohol (TBA)
ND 1.0 9/22/22 17:15 EEHg/L0.15 9/22/22SW-846 8260D1n-Butylbenzene
ND 1.0 9/22/22 17:15 EEHg/L0.11 9/22/22SW-846 8260D1sec-Butylbenzene
ND 1.0 9/22/22 17:15 EEHg/L0.13 9/22/22SW-846 8260D1tert-Butylbenzene
ND 0.50 9/22/22 17:15 EEHg/L0.15 9/22/22SW-846 8260D1tert-Butyl Ethyl Ether (TBEE)
ND 5.0 9/22/22 17:15 EEHg/L1.4 9/22/22SW-846 8260D1Carbon Disulfide
ND 1.0 9/22/22 17:15 EEHg/L0.16 9/22/22SW-846 8260D1Carbon Tetrachloride
ND 1.0 9/22/22 17:15 EEHg/L0.11 9/22/22SW-846 8260D1Chlorobenzene
ND 0.50 9/22/22 17:15 EEHg/L0.22 9/22/22SW-846 8260D1Chlorodibromomethane
ND 2.0 9/22/22 17:15 EEHg/L0.32 9/22/22SW-846 8260D1Chloroethane
ND 2.0 9/22/22 17:15 EEHg/L0.17 9/22/22SW-846 8260D1Chloroform
ND 2.0 9/22/22 17:15 EEHg/L0.52 9/22/22SW-846 8260D1Chloromethane
ND 1.0 9/22/22 17:15 EEHg/L0.11 9/22/22SW-846 8260D12-Chlorotoluene
ND 1.0 9/22/22 17:15 EEHg/L0.12 9/22/22SW-846 8260D14-Chlorotoluene
ND 5.0 9/22/22 17:15 EEHg/L0.80 9/22/22SW-846 8260D11,2-Dibromo-3-chloropropane (DBCP)
ND 0.50 9/22/22 17:15 EEHg/L0.17 9/22/22SW-846 8260D11,2-Dibromoethane (EDB)
ND 1.0 9/22/22 17:15 EEHg/L0.35 9/22/22SW-846 8260D1Dibromomethane
ND 1.0 9/22/22 17:15 EEHg/L0.12 9/22/22SW-846 8260D11,2-Dichlorobenzene
ND 1.0 9/22/22 17:15 EEHg/L0.12 9/22/22SW-846 8260D11,3-Dichlorobenzene
ND 1.0 9/22/22 17:15 EEHg/L0.13 9/22/22SW-846 8260D11,4-Dichlorobenzene
ND 2.0 9/22/22 17:15 EEHg/L1.6 9/22/22SW-846 8260D1trans-1,4-Dichloro-2-butene
ND 2.0 9/22/22 17:15 EEHg/L0.19 9/22/22SW-846 8260D1Dichlorodifluoromethane (Freon 12)
ND 1.0 9/22/22 17:15 EEHg/L0.14 9/22/22SW-846 8260D11,1-Dichloroethane
ND 1.0 9/22/22 17:15 EEHg/L0.31 9/22/22SW-846 8260D11,2-Dichloroethane
ND 1.0 9/22/22 17:15 EEHg/L0.14 9/22/22SW-846 8260D11,1-Dichloroethylene
ND 1.0 9/22/22 17:15 EEHg/L0.15 9/22/22SW-846 8260D1cis-1,2-Dichloroethylene
ND 1.0 9/22/22 17:15 EEHg/L0.17 9/22/22SW-846 8260D1trans-1,2-Dichloroethylene
ND 1.0 9/22/22 17:15 EEHg/L0.18 9/22/22SW-846 8260D11,2-Dichloropropane
ND 0.50 9/22/22 17:15 EEHg/L0.13 9/22/22SW-846 8260D11,3-Dichloropropane
ND 1.0 9/22/22 17:15 EEHg/L0.33 9/22/22SW-846 8260D12,2-Dichloropropane
ND 2.0 9/22/22 17:15 EEHg/L0.15 9/22/22SW-846 8260D11,1-Dichloropropene
ND 0.50 9/22/22 17:15 EEHg/L0.16 9/22/22SW-846 8260D1cis-1,3-Dichloropropene
ND 0.50 9/22/22 17:15 EEHg/L0.17 9/22/22SW-846 8260D1trans-1,3-Dichloropropene
ND 2.0 9/22/22 17:15 EEHg/L0.18 9/22/22SW-846 8260D1Diethyl Ether
[TOC_1]Sample Results[TOC]
Page 5 of 25
Table of Contents
Page 10 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 9/17/2022
Work Order: 22I1020Sample Description:Project Location: Crown Food Mart 9/15
Sample ID: 22I1020-01
Field Sample #: SW 01 182
Sample Matrix: Water
Sampled: 9/15/2022 11:10
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 9/22/22 17:15 EEHg/L0.13 9/22/22SW-846 8260D1Diisopropyl Ether (DIPE)
ND 50 9/22/22 17:15 EEHg/L21 9/22/22SW-846 8260D11,4-Dioxane
ND 1.0 9/22/22 17:15 EEHg/L0.21 9/22/22SW-846 8260D1Ethylbenzene
ND 0.60 9/22/22 17:15 EEHg/L0.46 9/22/22SW-846 8260D1Hexachlorobutadiene
ND 10 9/22/22 17:15 EEHg/L1.1 9/22/22SW-846 8260D12-Hexanone (MBK)
ND 1.0 9/22/22 17:15 EEHg/L0.11 9/22/22SW-846 8260D1Isopropylbenzene (Cumene)
ND 1.0 9/22/22 17:15 EEHg/L0.097 9/22/22SW-846 8260D1p-Isopropyltoluene (p-Cymene)
ND 1.0 9/22/22 17:15 EEHg/L0.17 9/22/22SW-846 8260D1Methyl tert-Butyl Ether (MTBE)
ND 5.0 9/22/22 17:15 EEHg/L0.23 9/22/22SW-846 8260D1Methylene Chloride
ND 10 9/22/22 17:15 EEHg/L1.3 9/22/22SW-846 8260D14-Methyl-2-pentanone (MIBK)
ND 2.0 9/22/22 17:15 EEHg/L0.24 9/22/22SW-846 8260D1Naphthalene
ND 1.0 9/22/22 17:15 EEHg/L0.086 9/22/22SW-846 8260D1n-Propylbenzene
ND 1.0 9/22/22 17:15 EEHg/L0.11 9/22/22SW-846 8260D1Styrene
ND 1.0 9/22/22 17:15 EEHg/L0.18 9/22/22SW-846 8260D11,1,1,2-Tetrachloroethane
ND 0.50 9/22/22 17:15 EEHg/L0.13 9/22/22SW-846 8260D11,1,2,2-Tetrachloroethane
ND 1.0 9/22/22 17:15 EEHg/L0.19 9/22/22SW-846 8260D1Tetrachloroethylene
ND 10 9/22/22 17:15 EEHg/L0.49 9/22/22SW-846 8260D1Tetrahydrofuran
ND 1.0 9/22/22 17:15 EEHg/L0.22 9/22/22SW-846 8260D1Toluene
ND 5.0 9/22/22 17:15 EEHg/L0.30 9/22/22SW-846 8260D11,2,3-Trichlorobenzene
ND 1.0 9/22/22 17:15 EEHg/L0.25 9/22/22SW-846 8260D11,2,4-Trichlorobenzene
ND 1.0 9/22/22 17:15 EEHg/L0.21 9/22/22SW-846 8260D11,3,5-Trichlorobenzene
ND 1.0 9/22/22 17:15 EEHg/L0.17 9/22/22SW-846 8260D11,1,1-Trichloroethane
ND 1.0 9/22/22 17:15 EEHg/L0.18 9/22/22SW-846 8260D11,1,2-Trichloroethane
ND 1.0 9/22/22 17:15 EEHg/L0.19 9/22/22SW-846 8260D1Trichloroethylene
ND 2.0 9/22/22 17:15 EEHg/L0.18 9/22/22SW-846 8260D1Trichlorofluoromethane (Freon 11)
ND 2.0 9/22/22 17:15 EEHg/L0.28 9/22/22SW-846 8260D11,2,3-Trichloropropane
ND 2.0 9/22/22 17:15 EEHg/L0.23 9/22/22SW-846 8260D11,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
ND 1.0 9/22/22 17:15 EEHg/L0.20 9/22/22SW-846 8260D11,2,4-Trimethylbenzene
ND 1.0 9/22/22 17:15 EEHg/L0.11 9/22/22SW-846 8260D11,3,5-Trimethylbenzene
ND 2.0 9/22/22 17:15 EEHg/L0.21 9/22/22SW-846 8260D1Vinyl Chloride
ND 2.0 9/22/22 17:15 EEHg/L0.46 9/22/22SW-846 8260D1m+p Xylene
ND 1.0 9/22/22 17:15 EEHg/L0.23 9/22/22SW-846 8260D1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 92.0 9/22/22 17:1570-130
Toluene-d8 103 9/22/22 17:1570-130
4-Bromofluorobenzene 101 9/22/22 17:1570-130
Page 6 of 25
Table of Contents
Page 11 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 9/17/2022
Work Order: 22I1020Sample Description:Project Location: Crown Food Mart 9/15
Sample ID: 22I1020-02
Field Sample #: SW 02 182
Sample Matrix: Water
Sampled: 9/15/2022 11:45
[TOC_2]22I1020-02[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 9/22/22 17:43 EEHg/L2.0 9/22/22SW-846 8260D1Acetone
ND 5.0 9/22/22 17:43 EEHg/L0.55 9/22/22SW-846 8260D1Acrylonitrile
ND 0.50 9/22/22 17:43 EEHg/L0.14 9/22/22SW-846 8260D1tert-Amyl Methyl Ether (TAME)
ND 1.0 9/22/22 17:43 EEHg/L0.20 9/22/22SW-846 8260D1Benzene
ND 1.0 9/22/22 17:43 EEHg/L0.15 9/22/22SW-846 8260D1Bromobenzene
ND 1.0 9/22/22 17:43 EEHg/L0.31 9/22/22SW-846 8260D1Bromochloromethane
ND 0.50 9/22/22 17:43 EEHg/L0.18 9/22/22SW-846 8260D1Bromodichloromethane
ND 2.0 9/22/22 17:43 EEHg/L0.38 9/22/22SW-846 8260D1Bromoform
ND 2.0 9/22/22 17:43 EEHg/L1.5 9/22/22SW-846 8260D1Bromomethane
ND 20 9/22/22 17:43 EEHg/L1.6 9/22/22SW-846 8260D12-Butanone (MEK)
ND 20 9/22/22 17:43 EEHg/L4.7 9/22/22SW-846 8260D1tert-Butyl Alcohol (TBA)
ND 1.0 9/22/22 17:43 EEHg/L0.15 9/22/22SW-846 8260D1n-Butylbenzene
ND 1.0 9/22/22 17:43 EEHg/L0.11 9/22/22SW-846 8260D1sec-Butylbenzene
ND 1.0 9/22/22 17:43 EEHg/L0.13 9/22/22SW-846 8260D1tert-Butylbenzene
ND 0.50 9/22/22 17:43 EEHg/L0.15 9/22/22SW-846 8260D1tert-Butyl Ethyl Ether (TBEE)
ND 5.0 9/22/22 17:43 EEHg/L1.4 9/22/22SW-846 8260D1Carbon Disulfide
ND 1.0 9/22/22 17:43 EEHg/L0.16 9/22/22SW-846 8260D1Carbon Tetrachloride
ND 1.0 9/22/22 17:43 EEHg/L0.11 9/22/22SW-846 8260D1Chlorobenzene
ND 0.50 9/22/22 17:43 EEHg/L0.22 9/22/22SW-846 8260D1Chlorodibromomethane
ND 2.0 9/22/22 17:43 EEHg/L0.32 9/22/22SW-846 8260D1Chloroethane
ND 2.0 9/22/22 17:43 EEHg/L0.17 9/22/22SW-846 8260D1Chloroform
ND 2.0 9/22/22 17:43 EEHg/L0.52 9/22/22SW-846 8260D1Chloromethane
ND 1.0 9/22/22 17:43 EEHg/L0.11 9/22/22SW-846 8260D12-Chlorotoluene
ND 1.0 9/22/22 17:43 EEHg/L0.12 9/22/22SW-846 8260D14-Chlorotoluene
ND 5.0 9/22/22 17:43 EEHg/L0.80 9/22/22SW-846 8260D11,2-Dibromo-3-chloropropane (DBCP)
ND 0.50 9/22/22 17:43 EEHg/L0.17 9/22/22SW-846 8260D11,2-Dibromoethane (EDB)
ND 1.0 9/22/22 17:43 EEHg/L0.35 9/22/22SW-846 8260D1Dibromomethane
ND 1.0 9/22/22 17:43 EEHg/L0.12 9/22/22SW-846 8260D11,2-Dichlorobenzene
ND 1.0 9/22/22 17:43 EEHg/L0.12 9/22/22SW-846 8260D11,3-Dichlorobenzene
ND 1.0 9/22/22 17:43 EEHg/L0.13 9/22/22SW-846 8260D11,4-Dichlorobenzene
ND 2.0 9/22/22 17:43 EEHg/L1.6 9/22/22SW-846 8260D1trans-1,4-Dichloro-2-butene
ND 2.0 9/22/22 17:43 EEHg/L0.19 9/22/22SW-846 8260D1Dichlorodifluoromethane (Freon 12)
ND 1.0 9/22/22 17:43 EEHg/L0.14 9/22/22SW-846 8260D11,1-Dichloroethane
ND 1.0 9/22/22 17:43 EEHg/L0.31 9/22/22SW-846 8260D11,2-Dichloroethane
ND 1.0 9/22/22 17:43 EEHg/L0.14 9/22/22SW-846 8260D11,1-Dichloroethylene
ND 1.0 9/22/22 17:43 EEHg/L0.15 9/22/22SW-846 8260D1cis-1,2-Dichloroethylene
ND 1.0 9/22/22 17:43 EEHg/L0.17 9/22/22SW-846 8260D1trans-1,2-Dichloroethylene
ND 1.0 9/22/22 17:43 EEHg/L0.18 9/22/22SW-846 8260D11,2-Dichloropropane
ND 0.50 9/22/22 17:43 EEHg/L0.13 9/22/22SW-846 8260D11,3-Dichloropropane
ND 1.0 9/22/22 17:43 EEHg/L0.33 9/22/22SW-846 8260D12,2-Dichloropropane
ND 2.0 9/22/22 17:43 EEHg/L0.15 9/22/22SW-846 8260D11,1-Dichloropropene
ND 0.50 9/22/22 17:43 EEHg/L0.16 9/22/22SW-846 8260D1cis-1,3-Dichloropropene
ND 0.50 9/22/22 17:43 EEHg/L0.17 9/22/22SW-846 8260D1trans-1,3-Dichloropropene
ND 2.0 9/22/22 17:43 EEHg/L0.18 9/22/22SW-846 8260D1Diethyl Ether
Page 7 of 25
Table of Contents
Page 12 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 9/17/2022
Work Order: 22I1020Sample Description:Project Location: Crown Food Mart 9/15
Sample ID: 22I1020-02
Field Sample #: SW 02 182
Sample Matrix: Water
Sampled: 9/15/2022 11:45
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 9/22/22 17:43 EEHg/L0.13 9/22/22SW-846 8260D1Diisopropyl Ether (DIPE)
ND 50 9/22/22 17:43 EEHg/L21 9/22/22SW-846 8260D11,4-Dioxane
ND 1.0 9/22/22 17:43 EEHg/L0.21 9/22/22SW-846 8260D1Ethylbenzene
ND 0.60 9/22/22 17:43 EEHg/L0.46 9/22/22SW-846 8260D1Hexachlorobutadiene
ND 10 9/22/22 17:43 EEHg/L1.1 9/22/22SW-846 8260D12-Hexanone (MBK)
ND 1.0 9/22/22 17:43 EEHg/L0.11 9/22/22SW-846 8260D1Isopropylbenzene (Cumene)
ND 1.0 9/22/22 17:43 EEHg/L0.097 9/22/22SW-846 8260D1p-Isopropyltoluene (p-Cymene)
ND 1.0 9/22/22 17:43 EEHg/L0.17 9/22/22SW-846 8260D1Methyl tert-Butyl Ether (MTBE)
ND 5.0 9/22/22 17:43 EEHg/L0.23 9/22/22SW-846 8260D1Methylene Chloride
ND 10 9/22/22 17:43 EEHg/L1.3 9/22/22SW-846 8260D14-Methyl-2-pentanone (MIBK)
ND 2.0 9/22/22 17:43 EEHg/L0.24 9/22/22SW-846 8260D1Naphthalene
0.13 1.0 9/22/22 17:43 EEHg/L0.086 9/22/22SW-846 8260D1Jn-Propylbenzene
ND 1.0 9/22/22 17:43 EEHg/L0.11 9/22/22SW-846 8260D1Styrene
ND 1.0 9/22/22 17:43 EEHg/L0.18 9/22/22SW-846 8260D11,1,1,2-Tetrachloroethane
ND 0.50 9/22/22 17:43 EEHg/L0.13 9/22/22SW-846 8260D11,1,2,2-Tetrachloroethane
ND 1.0 9/22/22 17:43 EEHg/L0.19 9/22/22SW-846 8260D1Tetrachloroethylene
ND 10 9/22/22 17:43 EEHg/L0.49 9/22/22SW-846 8260D1Tetrahydrofuran
ND 1.0 9/22/22 17:43 EEHg/L0.22 9/22/22SW-846 8260D1Toluene
ND 5.0 9/22/22 17:43 EEHg/L0.30 9/22/22SW-846 8260D11,2,3-Trichlorobenzene
ND 1.0 9/22/22 17:43 EEHg/L0.25 9/22/22SW-846 8260D11,2,4-Trichlorobenzene
ND 1.0 9/22/22 17:43 EEHg/L0.21 9/22/22SW-846 8260D11,3,5-Trichlorobenzene
ND 1.0 9/22/22 17:43 EEHg/L0.17 9/22/22SW-846 8260D11,1,1-Trichloroethane
ND 1.0 9/22/22 17:43 EEHg/L0.18 9/22/22SW-846 8260D11,1,2-Trichloroethane
ND 1.0 9/22/22 17:43 EEHg/L0.19 9/22/22SW-846 8260D1Trichloroethylene
ND 2.0 9/22/22 17:43 EEHg/L0.18 9/22/22SW-846 8260D1Trichlorofluoromethane (Freon 11)
ND 2.0 9/22/22 17:43 EEHg/L0.28 9/22/22SW-846 8260D11,2,3-Trichloropropane
ND 2.0 9/22/22 17:43 EEHg/L0.23 9/22/22SW-846 8260D11,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
0.83 1.0 9/22/22 17:43 EEHg/L0.20 9/22/22SW-846 8260D1J1,2,4-Trimethylbenzene
0.24 1.0 9/22/22 17:43 EEHg/L0.11 9/22/22SW-846 8260D1J1,3,5-Trimethylbenzene
ND 2.0 9/22/22 17:43 EEHg/L0.21 9/22/22SW-846 8260D1Vinyl Chloride
ND 2.0 9/22/22 17:43 EEHg/L0.46 9/22/22SW-846 8260D1m+p Xylene
ND 1.0 9/22/22 17:43 EEHg/L0.23 9/22/22SW-846 8260D1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 92.9 9/22/22 17:4370-130
Toluene-d8 103 9/22/22 17:4370-130
4-Bromofluorobenzene 99.2 9/22/22 17:4370-130
Page 8 of 25
Table of Contents
Page 13 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 9/17/2022
Work Order: 22I1020Sample Description:Project Location: Crown Food Mart 9/15
Sample ID: 22I1020-03
Field Sample #: SW 03 182
Sample Matrix: Water
Sampled: 9/15/2022 12:00
[TOC_2]22I1020-03[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 9/22/22 18:10 EEHg/L2.0 9/22/22SW-846 8260D1Acetone
ND 5.0 9/22/22 18:10 EEHg/L0.55 9/22/22SW-846 8260D1Acrylonitrile
ND 0.50 9/22/22 18:10 EEHg/L0.14 9/22/22SW-846 8260D1tert-Amyl Methyl Ether (TAME)
ND 1.0 9/22/22 18:10 EEHg/L0.20 9/22/22SW-846 8260D1Benzene
ND 1.0 9/22/22 18:10 EEHg/L0.15 9/22/22SW-846 8260D1Bromobenzene
ND 1.0 9/22/22 18:10 EEHg/L0.31 9/22/22SW-846 8260D1Bromochloromethane
ND 0.50 9/22/22 18:10 EEHg/L0.18 9/22/22SW-846 8260D1Bromodichloromethane
ND 2.0 9/22/22 18:10 EEHg/L0.38 9/22/22SW-846 8260D1Bromoform
ND 2.0 9/22/22 18:10 EEHg/L1.5 9/22/22SW-846 8260D1Bromomethane
ND 20 9/22/22 18:10 EEHg/L1.6 9/22/22SW-846 8260D12-Butanone (MEK)
ND 20 9/22/22 18:10 EEHg/L4.7 9/22/22SW-846 8260D1tert-Butyl Alcohol (TBA)
ND 1.0 9/22/22 18:10 EEHg/L0.15 9/22/22SW-846 8260D1n-Butylbenzene
ND 1.0 9/22/22 18:10 EEHg/L0.11 9/22/22SW-846 8260D1sec-Butylbenzene
ND 1.0 9/22/22 18:10 EEHg/L0.13 9/22/22SW-846 8260D1tert-Butylbenzene
ND 0.50 9/22/22 18:10 EEHg/L0.15 9/22/22SW-846 8260D1tert-Butyl Ethyl Ether (TBEE)
ND 5.0 9/22/22 18:10 EEHg/L1.4 9/22/22SW-846 8260D1Carbon Disulfide
ND 1.0 9/22/22 18:10 EEHg/L0.16 9/22/22SW-846 8260D1Carbon Tetrachloride
ND 1.0 9/22/22 18:10 EEHg/L0.11 9/22/22SW-846 8260D1Chlorobenzene
ND 0.50 9/22/22 18:10 EEHg/L0.22 9/22/22SW-846 8260D1Chlorodibromomethane
ND 2.0 9/22/22 18:10 EEHg/L0.32 9/22/22SW-846 8260D1Chloroethane
ND 2.0 9/22/22 18:10 EEHg/L0.17 9/22/22SW-846 8260D1Chloroform
ND 2.0 9/22/22 18:10 EEHg/L0.52 9/22/22SW-846 8260D1Chloromethane
ND 1.0 9/22/22 18:10 EEHg/L0.11 9/22/22SW-846 8260D12-Chlorotoluene
ND 1.0 9/22/22 18:10 EEHg/L0.12 9/22/22SW-846 8260D14-Chlorotoluene
ND 5.0 9/22/22 18:10 EEHg/L0.80 9/22/22SW-846 8260D11,2-Dibromo-3-chloropropane (DBCP)
ND 0.50 9/22/22 18:10 EEHg/L0.17 9/22/22SW-846 8260D11,2-Dibromoethane (EDB)
ND 1.0 9/22/22 18:10 EEHg/L0.35 9/22/22SW-846 8260D1Dibromomethane
ND 1.0 9/22/22 18:10 EEHg/L0.12 9/22/22SW-846 8260D11,2-Dichlorobenzene
ND 1.0 9/22/22 18:10 EEHg/L0.12 9/22/22SW-846 8260D11,3-Dichlorobenzene
ND 1.0 9/22/22 18:10 EEHg/L0.13 9/22/22SW-846 8260D11,4-Dichlorobenzene
ND 2.0 9/22/22 18:10 EEHg/L1.6 9/22/22SW-846 8260D1trans-1,4-Dichloro-2-butene
ND 2.0 9/22/22 18:10 EEHg/L0.19 9/22/22SW-846 8260D1Dichlorodifluoromethane (Freon 12)
ND 1.0 9/22/22 18:10 EEHg/L0.14 9/22/22SW-846 8260D11,1-Dichloroethane
ND 1.0 9/22/22 18:10 EEHg/L0.31 9/22/22SW-846 8260D11,2-Dichloroethane
ND 1.0 9/22/22 18:10 EEHg/L0.14 9/22/22SW-846 8260D11,1-Dichloroethylene
ND 1.0 9/22/22 18:10 EEHg/L0.15 9/22/22SW-846 8260D1cis-1,2-Dichloroethylene
ND 1.0 9/22/22 18:10 EEHg/L0.17 9/22/22SW-846 8260D1trans-1,2-Dichloroethylene
ND 1.0 9/22/22 18:10 EEHg/L0.18 9/22/22SW-846 8260D11,2-Dichloropropane
ND 0.50 9/22/22 18:10 EEHg/L0.13 9/22/22SW-846 8260D11,3-Dichloropropane
ND 1.0 9/22/22 18:10 EEHg/L0.33 9/22/22SW-846 8260D12,2-Dichloropropane
ND 2.0 9/22/22 18:10 EEHg/L0.15 9/22/22SW-846 8260D11,1-Dichloropropene
ND 0.50 9/22/22 18:10 EEHg/L0.16 9/22/22SW-846 8260D1cis-1,3-Dichloropropene
ND 0.50 9/22/22 18:10 EEHg/L0.17 9/22/22SW-846 8260D1trans-1,3-Dichloropropene
ND 2.0 9/22/22 18:10 EEHg/L0.18 9/22/22SW-846 8260D1Diethyl Ether
Page 9 of 25
Table of Contents
Page 14 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 9/17/2022
Work Order: 22I1020Sample Description:Project Location: Crown Food Mart 9/15
Sample ID: 22I1020-03
Field Sample #: SW 03 182
Sample Matrix: Water
Sampled: 9/15/2022 12:00
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 9/22/22 18:10 EEHg/L0.13 9/22/22SW-846 8260D1Diisopropyl Ether (DIPE)
ND 50 9/22/22 18:10 EEHg/L21 9/22/22SW-846 8260D11,4-Dioxane
ND 1.0 9/22/22 18:10 EEHg/L0.21 9/22/22SW-846 8260D1Ethylbenzene
ND 0.60 9/22/22 18:10 EEHg/L0.46 9/22/22SW-846 8260D1Hexachlorobutadiene
ND 10 9/22/22 18:10 EEHg/L1.1 9/22/22SW-846 8260D12-Hexanone (MBK)
ND 1.0 9/22/22 18:10 EEHg/L0.11 9/22/22SW-846 8260D1Isopropylbenzene (Cumene)
ND 1.0 9/22/22 18:10 EEHg/L0.097 9/22/22SW-846 8260D1p-Isopropyltoluene (p-Cymene)
ND 1.0 9/22/22 18:10 EEHg/L0.17 9/22/22SW-846 8260D1Methyl tert-Butyl Ether (MTBE)
ND 5.0 9/22/22 18:10 EEHg/L0.23 9/22/22SW-846 8260D1Methylene Chloride
ND 10 9/22/22 18:10 EEHg/L1.3 9/22/22SW-846 8260D14-Methyl-2-pentanone (MIBK)
ND 2.0 9/22/22 18:10 EEHg/L0.24 9/22/22SW-846 8260D1Naphthalene
ND 1.0 9/22/22 18:10 EEHg/L0.086 9/22/22SW-846 8260D1n-Propylbenzene
ND 1.0 9/22/22 18:10 EEHg/L0.11 9/22/22SW-846 8260D1Styrene
ND 1.0 9/22/22 18:10 EEHg/L0.18 9/22/22SW-846 8260D11,1,1,2-Tetrachloroethane
ND 0.50 9/22/22 18:10 EEHg/L0.13 9/22/22SW-846 8260D11,1,2,2-Tetrachloroethane
ND 1.0 9/22/22 18:10 EEHg/L0.19 9/22/22SW-846 8260D1Tetrachloroethylene
ND 10 9/22/22 18:10 EEHg/L0.49 9/22/22SW-846 8260D1Tetrahydrofuran
ND 1.0 9/22/22 18:10 EEHg/L0.22 9/22/22SW-846 8260D1Toluene
ND 5.0 9/22/22 18:10 EEHg/L0.30 9/22/22SW-846 8260D11,2,3-Trichlorobenzene
ND 1.0 9/22/22 18:10 EEHg/L0.25 9/22/22SW-846 8260D11,2,4-Trichlorobenzene
ND 1.0 9/22/22 18:10 EEHg/L0.21 9/22/22SW-846 8260D11,3,5-Trichlorobenzene
ND 1.0 9/22/22 18:10 EEHg/L0.17 9/22/22SW-846 8260D11,1,1-Trichloroethane
ND 1.0 9/22/22 18:10 EEHg/L0.18 9/22/22SW-846 8260D11,1,2-Trichloroethane
ND 1.0 9/22/22 18:10 EEHg/L0.19 9/22/22SW-846 8260D1Trichloroethylene
ND 2.0 9/22/22 18:10 EEHg/L0.18 9/22/22SW-846 8260D1Trichlorofluoromethane (Freon 11)
ND 2.0 9/22/22 18:10 EEHg/L0.28 9/22/22SW-846 8260D11,2,3-Trichloropropane
ND 2.0 9/22/22 18:10 EEHg/L0.23 9/22/22SW-846 8260D11,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
0.31 1.0 9/22/22 18:10 EEHg/L0.20 9/22/22SW-846 8260D1J1,2,4-Trimethylbenzene
ND 1.0 9/22/22 18:10 EEHg/L0.11 9/22/22SW-846 8260D11,3,5-Trimethylbenzene
ND 2.0 9/22/22 18:10 EEHg/L0.21 9/22/22SW-846 8260D1Vinyl Chloride
ND 2.0 9/22/22 18:10 EEHg/L0.46 9/22/22SW-846 8260D1m+p Xylene
ND 1.0 9/22/22 18:10 EEHg/L0.23 9/22/22SW-846 8260D1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 92.8 9/22/22 18:1070-130
Toluene-d8 104 9/22/22 18:1070-130
4-Bromofluorobenzene 97.0 9/22/22 18:1070-130
Page 10 of 25
Table of Contents
Page 15 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 9/17/2022
Work Order: 22I1020Sample Description:Project Location: Crown Food Mart 9/15
Sample ID: 22I1020-04
Field Sample #: SW 04 182
Sample Matrix: Water
Sampled: 9/15/2022 12:20
[TOC_2]22I1020-04[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 9/22/22 18:38 EEHg/L2.0 9/22/22SW-846 8260D1Acetone
ND 5.0 9/22/22 18:38 EEHg/L0.55 9/22/22SW-846 8260D1Acrylonitrile
ND 0.50 9/22/22 18:38 EEHg/L0.14 9/22/22SW-846 8260D1tert-Amyl Methyl Ether (TAME)
ND 1.0 9/22/22 18:38 EEHg/L0.20 9/22/22SW-846 8260D1Benzene
ND 1.0 9/22/22 18:38 EEHg/L0.15 9/22/22SW-846 8260D1Bromobenzene
ND 1.0 9/22/22 18:38 EEHg/L0.31 9/22/22SW-846 8260D1Bromochloromethane
ND 0.50 9/22/22 18:38 EEHg/L0.18 9/22/22SW-846 8260D1Bromodichloromethane
ND 2.0 9/22/22 18:38 EEHg/L0.38 9/22/22SW-846 8260D1Bromoform
ND 2.0 9/22/22 18:38 EEHg/L1.5 9/22/22SW-846 8260D1Bromomethane
ND 20 9/22/22 18:38 EEHg/L1.6 9/22/22SW-846 8260D12-Butanone (MEK)
ND 20 9/22/22 18:38 EEHg/L4.7 9/22/22SW-846 8260D1tert-Butyl Alcohol (TBA)
ND 1.0 9/22/22 18:38 EEHg/L0.15 9/22/22SW-846 8260D1n-Butylbenzene
ND 1.0 9/22/22 18:38 EEHg/L0.11 9/22/22SW-846 8260D1sec-Butylbenzene
ND 1.0 9/22/22 18:38 EEHg/L0.13 9/22/22SW-846 8260D1tert-Butylbenzene
ND 0.50 9/22/22 18:38 EEHg/L0.15 9/22/22SW-846 8260D1tert-Butyl Ethyl Ether (TBEE)
ND 5.0 9/22/22 18:38 EEHg/L1.4 9/22/22SW-846 8260D1Carbon Disulfide
ND 1.0 9/22/22 18:38 EEHg/L0.16 9/22/22SW-846 8260D1Carbon Tetrachloride
ND 1.0 9/22/22 18:38 EEHg/L0.11 9/22/22SW-846 8260D1Chlorobenzene
ND 0.50 9/22/22 18:38 EEHg/L0.22 9/22/22SW-846 8260D1Chlorodibromomethane
ND 2.0 9/22/22 18:38 EEHg/L0.32 9/22/22SW-846 8260D1Chloroethane
ND 2.0 9/22/22 18:38 EEHg/L0.17 9/22/22SW-846 8260D1Chloroform
ND 2.0 9/22/22 18:38 EEHg/L0.52 9/22/22SW-846 8260D1Chloromethane
ND 1.0 9/22/22 18:38 EEHg/L0.11 9/22/22SW-846 8260D12-Chlorotoluene
ND 1.0 9/22/22 18:38 EEHg/L0.12 9/22/22SW-846 8260D14-Chlorotoluene
ND 5.0 9/22/22 18:38 EEHg/L0.80 9/22/22SW-846 8260D11,2-Dibromo-3-chloropropane (DBCP)
ND 0.50 9/22/22 18:38 EEHg/L0.17 9/22/22SW-846 8260D11,2-Dibromoethane (EDB)
ND 1.0 9/22/22 18:38 EEHg/L0.35 9/22/22SW-846 8260D1Dibromomethane
ND 1.0 9/22/22 18:38 EEHg/L0.12 9/22/22SW-846 8260D11,2-Dichlorobenzene
ND 1.0 9/22/22 18:38 EEHg/L0.12 9/22/22SW-846 8260D11,3-Dichlorobenzene
ND 1.0 9/22/22 18:38 EEHg/L0.13 9/22/22SW-846 8260D11,4-Dichlorobenzene
ND 2.0 9/22/22 18:38 EEHg/L1.6 9/22/22SW-846 8260D1trans-1,4-Dichloro-2-butene
ND 2.0 9/22/22 18:38 EEHg/L0.19 9/22/22SW-846 8260D1Dichlorodifluoromethane (Freon 12)
ND 1.0 9/22/22 18:38 EEHg/L0.14 9/22/22SW-846 8260D11,1-Dichloroethane
ND 1.0 9/22/22 18:38 EEHg/L0.31 9/22/22SW-846 8260D11,2-Dichloroethane
ND 1.0 9/22/22 18:38 EEHg/L0.14 9/22/22SW-846 8260D11,1-Dichloroethylene
ND 1.0 9/22/22 18:38 EEHg/L0.15 9/22/22SW-846 8260D1cis-1,2-Dichloroethylene
ND 1.0 9/22/22 18:38 EEHg/L0.17 9/22/22SW-846 8260D1trans-1,2-Dichloroethylene
ND 1.0 9/22/22 18:38 EEHg/L0.18 9/22/22SW-846 8260D11,2-Dichloropropane
ND 0.50 9/22/22 18:38 EEHg/L0.13 9/22/22SW-846 8260D11,3-Dichloropropane
ND 1.0 9/22/22 18:38 EEHg/L0.33 9/22/22SW-846 8260D12,2-Dichloropropane
ND 2.0 9/22/22 18:38 EEHg/L0.15 9/22/22SW-846 8260D11,1-Dichloropropene
ND 0.50 9/22/22 18:38 EEHg/L0.16 9/22/22SW-846 8260D1cis-1,3-Dichloropropene
ND 0.50 9/22/22 18:38 EEHg/L0.17 9/22/22SW-846 8260D1trans-1,3-Dichloropropene
ND 2.0 9/22/22 18:38 EEHg/L0.18 9/22/22SW-846 8260D1Diethyl Ether
Page 11 of 25
Table of Contents
Page 16 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 9/17/2022
Work Order: 22I1020Sample Description:Project Location: Crown Food Mart 9/15
Sample ID: 22I1020-04
Field Sample #: SW 04 182
Sample Matrix: Water
Sampled: 9/15/2022 12:20
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 9/22/22 18:38 EEHg/L0.13 9/22/22SW-846 8260D1Diisopropyl Ether (DIPE)
ND 50 9/22/22 18:38 EEHg/L21 9/22/22SW-846 8260D11,4-Dioxane
ND 1.0 9/22/22 18:38 EEHg/L0.21 9/22/22SW-846 8260D1Ethylbenzene
ND 0.60 9/22/22 18:38 EEHg/L0.46 9/22/22SW-846 8260D1Hexachlorobutadiene
ND 10 9/22/22 18:38 EEHg/L1.1 9/22/22SW-846 8260D12-Hexanone (MBK)
ND 1.0 9/22/22 18:38 EEHg/L0.11 9/22/22SW-846 8260D1Isopropylbenzene (Cumene)
ND 1.0 9/22/22 18:38 EEHg/L0.097 9/22/22SW-846 8260D1p-Isopropyltoluene (p-Cymene)
ND 1.0 9/22/22 18:38 EEHg/L0.17 9/22/22SW-846 8260D1Methyl tert-Butyl Ether (MTBE)
ND 5.0 9/22/22 18:38 EEHg/L0.23 9/22/22SW-846 8260D1Methylene Chloride
ND 10 9/22/22 18:38 EEHg/L1.3 9/22/22SW-846 8260D14-Methyl-2-pentanone (MIBK)
ND 2.0 9/22/22 18:38 EEHg/L0.24 9/22/22SW-846 8260D1Naphthalene
ND 1.0 9/22/22 18:38 EEHg/L0.086 9/22/22SW-846 8260D1n-Propylbenzene
ND 1.0 9/22/22 18:38 EEHg/L0.11 9/22/22SW-846 8260D1Styrene
ND 1.0 9/22/22 18:38 EEHg/L0.18 9/22/22SW-846 8260D11,1,1,2-Tetrachloroethane
ND 0.50 9/22/22 18:38 EEHg/L0.13 9/22/22SW-846 8260D11,1,2,2-Tetrachloroethane
ND 1.0 9/22/22 18:38 EEHg/L0.19 9/22/22SW-846 8260D1Tetrachloroethylene
ND 10 9/22/22 18:38 EEHg/L0.49 9/22/22SW-846 8260D1Tetrahydrofuran
ND 1.0 9/22/22 18:38 EEHg/L0.22 9/22/22SW-846 8260D1Toluene
ND 5.0 9/22/22 18:38 EEHg/L0.30 9/22/22SW-846 8260D11,2,3-Trichlorobenzene
ND 1.0 9/22/22 18:38 EEHg/L0.25 9/22/22SW-846 8260D11,2,4-Trichlorobenzene
ND 1.0 9/22/22 18:38 EEHg/L0.21 9/22/22SW-846 8260D11,3,5-Trichlorobenzene
ND 1.0 9/22/22 18:38 EEHg/L0.17 9/22/22SW-846 8260D11,1,1-Trichloroethane
ND 1.0 9/22/22 18:38 EEHg/L0.18 9/22/22SW-846 8260D11,1,2-Trichloroethane
ND 1.0 9/22/22 18:38 EEHg/L0.19 9/22/22SW-846 8260D1Trichloroethylene
ND 2.0 9/22/22 18:38 EEHg/L0.18 9/22/22SW-846 8260D1Trichlorofluoromethane (Freon 11)
ND 2.0 9/22/22 18:38 EEHg/L0.28 9/22/22SW-846 8260D11,2,3-Trichloropropane
ND 2.0 9/22/22 18:38 EEHg/L0.23 9/22/22SW-846 8260D11,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
ND 1.0 9/22/22 18:38 EEHg/L0.20 9/22/22SW-846 8260D11,2,4-Trimethylbenzene
ND 1.0 9/22/22 18:38 EEHg/L0.11 9/22/22SW-846 8260D11,3,5-Trimethylbenzene
ND 2.0 9/22/22 18:38 EEHg/L0.21 9/22/22SW-846 8260D1Vinyl Chloride
ND 2.0 9/22/22 18:38 EEHg/L0.46 9/22/22SW-846 8260D1m+p Xylene
ND 1.0 9/22/22 18:38 EEHg/L0.23 9/22/22SW-846 8260D1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 90.6 9/22/22 18:3870-130
Toluene-d8 102 9/22/22 18:3870-130
4-Bromofluorobenzene 98.4 9/22/22 18:3870-130
Page 12 of 25
Table of Contents
Page 17 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Sample Extraction Data
Prep Method: SW-846 5030B Analytical Method: SW-846 8260D
Lab Number [Field ID]Batch DateInitial [mL]Final [mL]
B317807 09/22/225 5.0022I1020-01 [SW 01 182]
B317807 09/22/225 5.0022I1020-02 [SW 02 182]
B317807 09/22/225 5.0022I1020-03 [SW 03 182]
B317807 09/22/225 5.0022I1020-04 [SW 04 182]
[TOC_1]Sample Preparation Information[TOC]
Page 13 of 25
Table of Contents
Page 18 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
[TOC_2]Volatile Organic Compounds by GC/MS[TOC]
Batch B317807 - SW-846 5030B
[TOC_3]B317807[TOC]
Blank (B317807-BLK1) Prepared & Analyzed: 09/22/22
Acetone g/L50ND
Acrylonitrile g/L5.0ND
tert-Amyl Methyl Ether (TAME)g/L0.50ND
Benzene g/L1.0ND
Bromobenzene g/L1.0ND
Bromochloromethane g/L1.0ND
Bromodichloromethane g/L0.50ND
Bromoform g/L1.0ND
Bromomethane g/L2.0ND
2-Butanone (MEK)g/L20ND
tert-Butyl Alcohol (TBA)g/L20ND
n-Butylbenzene g/L1.0ND
sec-Butylbenzene g/L1.0ND
tert-Butylbenzene g/L1.0ND
tert-Butyl Ethyl Ether (TBEE)g/L0.50ND
Carbon Disulfide g/L5.0ND
Carbon Tetrachloride g/L1.0ND
Chlorobenzene g/L1.0ND
Chlorodibromomethane g/L0.50ND
Chloroethane g/L2.0ND
Chloroform g/L2.0ND
Chloromethane g/L2.0ND
2-Chlorotoluene g/L1.0ND
4-Chlorotoluene g/L1.0ND
1,2-Dibromo-3-chloropropane (DBCP)g/L5.0ND
1,2-Dibromoethane (EDB)g/L0.50ND
Dibromomethane g/L1.0ND
1,2-Dichlorobenzene g/L1.0ND
1,3-Dichlorobenzene g/L1.0ND
1,4-Dichlorobenzene g/L1.0ND
trans-1,4-Dichloro-2-butene g/L2.0ND
Dichlorodifluoromethane (Freon 12)g/L2.0ND
1,1-Dichloroethane g/L1.0ND
1,2-Dichloroethane g/L1.0ND
1,1-Dichloroethylene g/L1.0ND
cis-1,2-Dichloroethylene g/L1.0ND
trans-1,2-Dichloroethylene g/L1.0ND
1,2-Dichloropropane g/L1.0ND
1,3-Dichloropropane g/L0.50ND
2,2-Dichloropropane g/L1.0ND
1,1-Dichloropropene g/L2.0ND
cis-1,3-Dichloropropene g/L0.50ND
trans-1,3-Dichloropropene g/L0.50ND
Diethyl Ether g/L2.0ND
Diisopropyl Ether (DIPE)g/L0.50ND
1,4-Dioxane g/L50ND
Ethylbenzene g/L1.0ND
Hexachlorobutadiene g/L0.60ND
2-Hexanone (MBK)g/L10ND
Isopropylbenzene (Cumene)g/L1.0ND
p-Isopropyltoluene (p-Cymene)g/L1.0ND
Methyl tert-Butyl Ether (MTBE)g/L1.0ND
[TOC_1]QC Data[TOC]
Page 14 of 25
Table of Contents
Page 19 of 30
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B317807 - SW-846 5030B
Blank (B317807-BLK1) Prepared & Analyzed: 09/22/22
Methylene Chloride g/L5.0ND
4-Methyl-2-pentanone (MIBK)g/L10ND
Naphthalene g/L2.0ND
n-Propylbenzene g/L1.0ND
Styrene g/L1.0ND
1,1,1,2-Tetrachloroethane g/L1.0ND
1,1,2,2-Tetrachloroethane g/L0.50ND
Tetrachloroethylene g/L1.0ND
Tetrahydrofuran g/L10ND
Toluene g/L1.0ND
1,2,3-Trichlorobenzene g/L5.0ND
1,2,4-Trichlorobenzene g/L1.0ND
1,3,5-Trichlorobenzene g/L1.0ND
1,1,1-Trichloroethane g/L1.0ND
1,1,2-Trichloroethane g/L1.0ND
Trichloroethylene g/L1.0ND
Trichlorofluoromethane (Freon 11)g/L2.0ND
1,2,3-Trichloropropane g/L2.0ND
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon
113)
g/L1.0ND
1,2,4-Trimethylbenzene g/L1.0ND
1,3,5-Trimethylbenzene g/L1.0ND
Vinyl Acetate g/L20ND
Vinyl Chloride g/L2.0ND
m+p Xylene g/L2.0ND
o-Xylene g/L1.0ND
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 93.023.2
g/L 25.0 70-130Surrogate: Toluene-d8 10325.7
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 99.324.8
LCS (B317807-BS1) Prepared & Analyzed: 09/22/22
Acetone g/L50 100 70-16091.791.7
Acrylonitrile g/L5.0 10.0 70-13010210.2
tert-Amyl Methyl Ether (TAME)g/L0.50 10.0 70-13099.89.98
Benzene g/L1.0 10.0 70-13092.09.20
Bromobenzene g/L1.0 10.0 70-13010210.2
Bromochloromethane g/L1.0 10.0 70-13010110.1
Bromodichloromethane g/L0.50 10.0 70-13096.39.63
Bromoform g/L1.0 10.0 70-13093.69.36
Bromomethane g/L2.0 10.0 V-2040-16011911.9
2-Butanone (MEK)g/L20 100 40-160119119
tert-Butyl Alcohol (TBA)g/L20 100 40-160102102
n-Butylbenzene g/L1.0 10.0 70-13098.69.86
sec-Butylbenzene g/L1.0 10.0 70-13093.39.33
tert-Butylbenzene g/L1.0 10.0 70-13095.09.50
tert-Butyl Ethyl Ether (TBEE)g/L0.50 10.0 70-13010710.7
Carbon Disulfide g/L5.0 100 L-07, V-2070-130131*131
Carbon Tetrachloride g/L1.0 10.0 70-13092.89.28
Chlorobenzene g/L1.0 10.0 70-13094.09.40
Chlorodibromomethane g/L0.50 10.0 70-13096.09.60
Chloroethane g/L2.0 10.0 70-13011711.7
Chloroform g/L2.0 10.0 70-13095.69.56
Chloromethane g/L2.0 10.0 40-16014014.0
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B317807 - SW-846 5030B
LCS (B317807-BS1) Prepared & Analyzed: 09/22/22
2-Chlorotoluene g/L1.0 10.0 70-13091.79.17
4-Chlorotoluene g/L1.0 10.0 70-13095.09.50
1,2-Dibromo-3-chloropropane (DBCP)g/L5.0 10.0 70-13090.79.07
1,2-Dibromoethane (EDB)g/L0.50 10.0 70-13099.09.90
Dibromomethane g/L1.0 10.0 70-13096.09.60
1,2-Dichlorobenzene g/L1.0 10.0 70-13093.79.37
1,3-Dichlorobenzene g/L1.0 10.0 70-13093.99.39
1,4-Dichlorobenzene g/L1.0 10.0 70-13092.19.21
trans-1,4-Dichloro-2-butene g/L2.0 10.0 70-13098.99.89
Dichlorodifluoromethane (Freon 12)g/L2.0 10.0 40-16079.57.95
1,1-Dichloroethane g/L1.0 10.0 70-13098.19.81
1,2-Dichloroethane g/L1.0 10.0 70-13094.99.49
1,1-Dichloroethylene g/L1.0 10.0 70-13093.59.35
cis-1,2-Dichloroethylene g/L1.0 10.0 70-13010210.2
trans-1,2-Dichloroethylene g/L1.0 10.0 V-2070-13012012.0
1,2-Dichloropropane g/L1.0 10.0 70-13010410.4
1,3-Dichloropropane g/L0.50 10.0 70-13010510.5
2,2-Dichloropropane g/L1.0 10.0 40-13098.49.84
1,1-Dichloropropene g/L2.0 10.0 70-13098.99.89
cis-1,3-Dichloropropene g/L0.50 10.0 70-13010210.2
trans-1,3-Dichloropropene g/L0.50 10.0 70-13099.29.92
Diethyl Ether g/L2.0 10.0 70-13010610.6
Diisopropyl Ether (DIPE)g/L0.50 10.0 70-13011411.4
1,4-Dioxane g/L50 100 40-130103103
Ethylbenzene g/L1.0 10.0 70-13099.39.93
Hexachlorobutadiene g/L0.60 10.0 70-13011611.6
2-Hexanone (MBK)g/L10 100 70-160120120
Isopropylbenzene (Cumene)g/L1.0 10.0 70-13097.39.73
p-Isopropyltoluene (p-Cymene)g/L1.0 10.0 70-13097.69.76
Methyl tert-Butyl Ether (MTBE)g/L1.0 10.0 70-13010610.6
Methylene Chloride g/L5.0 10.0 70-13098.29.82
4-Methyl-2-pentanone (MIBK)g/L10 100 70-160119119
Naphthalene g/L2.0 10.0 40-13095.59.55
n-Propylbenzene g/L1.0 10.0 70-13096.69.66
Styrene g/L1.0 10.0 70-13095.39.53
1,1,1,2-Tetrachloroethane g/L1.0 10.0 70-13096.79.67
1,1,2,2-Tetrachloroethane g/L0.50 10.0 70-13099.59.95
Tetrachloroethylene g/L1.0 10.0 70-13010610.6
Tetrahydrofuran g/L10 10.0 70-13011111.1
Toluene g/L1.0 10.0 70-13099.99.99
1,2,3-Trichlorobenzene g/L5.0 10.0 70-13010510.5
1,2,4-Trichlorobenzene g/L1.0 10.0 70-13010110.1
1,3,5-Trichlorobenzene g/L1.0 10.0 70-13010410.4
1,1,1-Trichloroethane g/L1.0 10.0 70-13095.09.50
1,1,2-Trichloroethane g/L1.0 10.0 70-13010410.4
Trichloroethylene g/L1.0 10.0 70-13010210.2
Trichlorofluoromethane (Freon 11)g/L2.0 10.0 70-13087.68.76
1,2,3-Trichloropropane g/L2.0 10.0 70-13010110.1
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon
113)
g/L1.0 10.0 70-13011811.8
1,2,4-Trimethylbenzene g/L1.0 10.0 70-13093.39.33
1,3,5-Trimethylbenzene g/L1.0 10.0 70-13095.79.57
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B317807 - SW-846 5030B
LCS (B317807-BS1) Prepared & Analyzed: 09/22/22
Vinyl Acetate g/L20 100 70-130111111
Vinyl Chloride g/L2.0 10.0 40-16011711.7
m+p Xylene g/L2.0 20.0 70-13099.820.0
o-Xylene g/L1.0 10.0 70-13099.99.99
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 96.024.0
g/L 25.0 70-130Surrogate: Toluene-d8 10225.4
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 10626.4
LCS Dup (B317807-BSD1) Prepared & Analyzed: 09/22/22
Acetone g/L50 100 2570-16095.5 4.1295.5
Acrylonitrile g/L5.0 10.0 2570-130107 4.6810.7
tert-Amyl Methyl Ether (TAME)g/L0.50 10.0 2570-130102 1.6910.2
Benzene g/L1.0 10.0 2570-13097.0 5.299.70
Bromobenzene g/L1.0 10.0 2570-130107 4.3910.7
Bromochloromethane g/L1.0 10.0 2570-130107 5.9510.7
Bromodichloromethane g/L0.50 10.0 2570-130100 4.1710.0
Bromoform g/L1.0 10.0 2570-13095.7 2.229.57
Bromomethane g/L2.0 10.0 25 V-2040-160119 0.084011.9
2-Butanone (MEK)g/L20 100 2540-160118 0.945118
tert-Butyl Alcohol (TBA)g/L20 100 2540-160103 1.08103
n-Butylbenzene g/L1.0 10.0 2570-13098.0 0.6109.80
sec-Butylbenzene g/L1.0 10.0 2570-13094.8 1.599.48
tert-Butylbenzene g/L1.0 10.0 2570-13095.8 0.8399.58
tert-Butyl Ethyl Ether (TBEE)g/L0.50 10.0 2570-130112 4.8411.2
Carbon Disulfide g/L5.0 100 25 V-2070-130129 1.48129
Carbon Tetrachloride g/L1.0 10.0 2570-13094.1 1.399.41
Chlorobenzene g/L1.0 10.0 2570-13096.2 2.319.62
Chlorodibromomethane g/L0.50 10.0 2570-13098.9 2.989.89
Chloroethane g/L2.0 10.0 2570-130111 5.2611.1
Chloroform g/L2.0 10.0 2570-13094.8 0.8409.48
Chloromethane g/L2.0 10.0 2540-160128 9.0612.8
2-Chlorotoluene g/L1.0 10.0 2570-13092.2 0.5449.22
4-Chlorotoluene g/L1.0 10.0 2570-13098.5 3.629.85
1,2-Dibromo-3-chloropropane (DBCP)g/L5.0 10.0 2570-13094.1 3.689.41
1,2-Dibromoethane (EDB)g/L0.50 10.0 2570-130100 1.5010.0
Dibromomethane g/L1.0 10.0 2570-13096.0 0.009.60
1,2-Dichlorobenzene g/L1.0 10.0 2570-13097.2 3.679.72
1,3-Dichlorobenzene g/L1.0 10.0 2570-13097.3 3.569.73
1,4-Dichlorobenzene g/L1.0 10.0 2570-13093.7 1.729.37
trans-1,4-Dichloro-2-butene g/L2.0 10.0 2570-13098.8 0.1019.88
Dichlorodifluoromethane (Freon 12)g/L2.0 10.0 2540-16076.1 4.377.61
1,1-Dichloroethane g/L1.0 10.0 2570-130100 2.2210.0
1,2-Dichloroethane g/L1.0 10.0 2570-130101 6.0310.1
1,1-Dichloroethylene g/L1.0 10.0 2570-13092.4 1.189.24
cis-1,2-Dichloroethylene g/L1.0 10.0 2570-130104 1.5510.4
trans-1,2-Dichloroethylene g/L1.0 10.0 25 L-07, V-2070-130135 12.2*13.5
1,2-Dichloropropane g/L1.0 10.0 2570-130106 1.8210.6
1,3-Dichloropropane g/L0.50 10.0 2570-130107 2.1710.7
2,2-Dichloropropane g/L1.0 10.0 2540-130100 1.9110.0
1,1-Dichloropropene g/L2.0 10.0 2570-13099.3 0.4049.93
cis-1,3-Dichloropropene g/L0.50 10.0 2570-130104 2.0510.4
trans-1,3-Dichloropropene g/L0.50 10.0 2570-130102 3.2710.2
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B317807 - SW-846 5030B
LCS Dup (B317807-BSD1) Prepared & Analyzed: 09/22/22
Diethyl Ether g/L2.0 10.0 2570-130106 0.56610.6
Diisopropyl Ether (DIPE)g/L0.50 10.0 2570-130118 3.5411.8
1,4-Dioxane g/L50 100 5040-130109 6.02109
Ethylbenzene g/L1.0 10.0 2570-130102 2.8810.2
Hexachlorobutadiene g/L0.60 10.0 2570-130116 0.60411.6
2-Hexanone (MBK)g/L10 100 2570-160121 0.866121
Isopropylbenzene (Cumene)g/L1.0 10.0 2570-13097.7 0.4109.77
p-Isopropyltoluene (p-Cymene)g/L1.0 10.0 2570-13098.0 0.4099.80
Methyl tert-Butyl Ether (MTBE)g/L1.0 10.0 2570-130111 5.1711.1
Methylene Chloride g/L5.0 10.0 2570-13098.1 0.1029.81
4-Methyl-2-pentanone (MIBK)g/L10 100 2570-160120 0.693120
Naphthalene g/L2.0 10.0 2540-13093.1 2.559.31
n-Propylbenzene g/L1.0 10.0 2570-13098.8 2.259.88
Styrene g/L1.0 10.0 2570-13098.8 3.619.88
1,1,1,2-Tetrachloroethane g/L1.0 10.0 2570-13097.1 0.4139.71
1,1,2,2-Tetrachloroethane g/L0.50 10.0 2570-130102 2.2910.2
Tetrachloroethylene g/L1.0 10.0 2570-130106 0.28210.6
Tetrahydrofuran g/L10 10.0 2570-130110 0.90611.0
Toluene g/L1.0 10.0 2570-130104 4.3110.4
1,2,3-Trichlorobenzene g/L5.0 10.0 2570-130101 3.9710.1
1,2,4-Trichlorobenzene g/L1.0 10.0 2570-13098.1 2.919.81
1,3,5-Trichlorobenzene g/L1.0 10.0 2570-130104 0.57610.4
1,1,1-Trichloroethane g/L1.0 10.0 2570-13095.9 0.9439.59
1,1,2-Trichloroethane g/L1.0 10.0 2570-130107 3.3210.7
Trichloroethylene g/L1.0 10.0 2570-130100 1.3910.0
Trichlorofluoromethane (Freon 11)g/L2.0 10.0 2570-13088.2 0.6838.82
1,2,3-Trichloropropane g/L2.0 10.0 2570-130101 0.49610.1
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon
113)
g/L1.0 10.0 2570-130117 0.93311.7
1,2,4-Trimethylbenzene g/L1.0 10.0 2570-13096.1 2.969.61
1,3,5-Trimethylbenzene g/L1.0 10.0 2570-13098.7 3.099.87
Vinyl Acetate g/L20 100 2570-130113 2.18113
Vinyl Chloride g/L2.0 10.0 2540-160124 5.9812.4
m+p Xylene g/L2.0 20.0 2570-130102 2.0320.4
o-Xylene g/L1.0 10.0 2570-130106 5.5510.6
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 96.624.1
g/L 25.0 70-130Surrogate: Toluene-d8 10225.4
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 10526.2
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
FLAG/QUALIFIER SUMMARY
*QC result is outside of established limits.
Wide recovery limits established for difficult compound.
Wide RPD limits established for difficult compound.
#Data exceeded client recommended or regulatory level
Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the
calculation which have not been rounded.
No results have been blank subtracted unless specified in the case narrative section.
RL Reporting Limit is at the level of quantitation (LOQ)
DL Detection Limit is the lower limit of detection determined by the MDL study
MCL Maximum Contaminant Level
ND Not Detected
Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated
concentration (CLP J-Flag).
J
Either laboratory fortified blank/laboratory control sample or duplicate recovery is outside of control limits, but
the other is within limits. RPD between the two LFB/LCS results is within method specified criteria.
L-07
Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side.
Data validation is not affected since sample result was "not detected" for this compound.
V-20
[TOC_1]Flag/Qualifier Summary[TOC]
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
SW-846 8260D in Water
NCAcetone
NCAcrylonitrile
NCtert-Amyl Methyl Ether (TAME)
NCBenzene
NCBromobenzene
NCBromochloromethane
NCBromodichloromethane
NCBromoform
NCBromomethane
NC2-Butanone (MEK)
NCtert-Butyl Alcohol (TBA)
NCn-Butylbenzene
NCsec-Butylbenzene
NCtert-Butylbenzene
NCtert-Butyl Ethyl Ether (TBEE)
NCCarbon Disulfide
NCCarbon Tetrachloride
NCChlorobenzene
NCChlorodibromomethane
NCChloroethane
NCChloroform
NCChloromethane
NC2-Chlorotoluene
NC4-Chlorotoluene
NC1,2-Dibromo-3-chloropropane (DBCP)
NC1,2-Dibromoethane (EDB)
NCDibromomethane
NC1,2-Dichlorobenzene
NC1,3-Dichlorobenzene
NC1,4-Dichlorobenzene
NCtrans-1,4-Dichloro-2-butene
NCDichlorodifluoromethane (Freon 12)
NC1,1-Dichloroethane
NC1,2-Dichloroethane
NC1,1-Dichloroethylene
NCcis-1,2-Dichloroethylene
NCtrans-1,2-Dichloroethylene
NC1,2-Dichloropropane
NC1,3-Dichloropropane
NC2,2-Dichloropropane
NC1,1-Dichloropropene
NCcis-1,3-Dichloropropene
NCtrans-1,3-Dichloropropene
NCDiethyl Ether
NCDiisopropyl Ether (DIPE)
NC1,4-Dioxane
NCEthylbenzene
[TOC_1]Certifications[TOC]
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
SW-846 8260D in Water
NCHexachlorobutadiene
NC2-Hexanone (MBK)
NCIsopropylbenzene (Cumene)
NCp-Isopropyltoluene (p-Cymene)
NCMethyl tert-Butyl Ether (MTBE)
NCMethylene Chloride
NC4-Methyl-2-pentanone (MIBK)
NCNaphthalene
NCn-Propylbenzene
NCStyrene
NC1,1,1,2-Tetrachloroethane
NC1,1,2,2-Tetrachloroethane
NCTetrachloroethylene
NCTetrahydrofuran
NCToluene
NC1,2,3-Trichlorobenzene
NC1,2,4-Trichlorobenzene
NC1,3,5-Trichlorobenzene
NC1,1,1-Trichloroethane
NC1,1,2-Trichloroethane
NCTrichloroethylene
NCTrichlorofluoromethane (Freon 11)
NC1,2,3-Trichloropropane
NC1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)
NC1,2,4-Trimethylbenzene
NC1,3,5-Trimethylbenzene
NCVinyl Chloride
NCm+p Xylene
NCo-Xylene
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Con-Test, a Pace Environmental Laboratory, operates under the following certifications and accreditations:
Code Description Number Expires
100033AIHA-LAP, LLC - ISO 17025:2017AIHA 03/1/2024
M-MA100Massachusetts DEPMA 06/30/2023
PH-0165Connecticut Department of Public HealthCT 12/31/2022
10899 NELAPNew York State Department of HealthNY 04/1/2023
2516 NELAPNew Hampshire Environmental LabNH 02/5/2023
LAO00373Rhode Island Department of HealthRI 12/30/2022
652North Carolina Div. of Water QualityNC 12/31/2022
MA007 NELAPNew Jersey DEPNJ 06/30/2023
E871027 NELAPFlorida Department of HealthFL 06/30/2023
LL720741Vermont Department of Health Lead LaboratoryVT 07/30/2023
VT-255716Vermont Department of Health Drinking WaterVT-DW 06/12/2023
MA00100State of MaineME 06/9/2023
460217Commonwealth of VirginiaVA 12/14/2022
2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2023
25703North Carolina Department of Health and Human ServicesNC-DW 07/31/2023
68-05812Commonwealth of Pennsylvania DEPPA 06/30/2023
9100Dept. of Env, Great Lakes, and EnergyMI 09/6/2023
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#=CL#
October 06, 2022
LIMS USE: FR - ROBERT MARTIN
LIMS OBJECT ID: 92628455
92628455
Project:
Pace Project No.:
RE:
Mr. Robert Martin
Martin and Slagle
24 Lookout Terrace
Black Mountain, NC 28711
Crown Food Mart 9/29
Dear Mr. Martin:
Enclosed are the analytical results for sample(s) received by the laboratory on September 30, 2022. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lorri Patton
[e-mail]
Project Manager
1(828)254-7176
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 1 of 32
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92628455
Crown Food Mart 9/29
Lab ID Sample ID Matrix Date Collected Date Received
92628455001 SW 01 183 Water 09/29/22 11:05 09/30/22 10:30
92628455002 SW 02 183 Water 09/29/22 12:00 09/30/22 10:30
92628455003 SW 03 183 Water 09/29/22 12:45 09/30/22 10:30
92628455004 SW 04 183 Water 09/29/22 13:10 09/30/22 10:30
92628455005 DUPLICATE Water 09/29/22 12:15 09/30/22 10:30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 2 of 32
Page 3 of 32
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Page 5 of 32
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
October 5, 2022
Lorri Patton
Pace Analytical Services - NC
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Project Location: Crown Food Mart 9/29
Client Job Number:
Project Number: 92628455
Laboratory Work Order Number: 22J0010
Enclosed are results of analyses for samples as received by the laboratory on October 1, 2022. If you have any questions
concerning this report, please feel free to contact me.
Sincerely,
Kerry K. McGee
Project Manager
Page 1 of 27
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Table of Contents
Sample Summary 3
Case Narrative 4
Sample Results 5
22J0010-01 5
22J0010-02 7
22J0010-03 9
22J0010-04 11
22J0010-05 13
Sample Preparation Information 15
QC Data 16
Volatile Organic Compounds by GC/MS 16
B318677 16
Flag/Qualifier Summary 21
Certifications 22
Chain of Custody/Sample Receipt 25
Page 2 of 27
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYTICAL SUMMARY
10/5/2022
Pace Analytical Services - NC
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
ATTN: Lorri Patton
92628455
22J0010
The results of analyses performed on the following samples submitted to CON-TEST, a Pace Analytical Laboratory, are found in this report.
PROJECT LOCATION:
PURCHASE ORDER NUMBER:
PROJECT NUMBER:
REPORT DATE:
WORK ORDER NUMBER:
FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB
Crown Food Mart 9/29
SW 01 183 22J0010-01 Water SW-846 8260D
SW 02 183 22J0010-02 Water SW-846 8260D
SW 03 183 22J0010-03 Water SW-846 8260D
SW 04 183 22J0010-04 Water SW-846 8260D
Duplicate 22J0010-05 Water SW-846 8260D
[TOC_1]Sample Summary[TOC]
Page 3 of 27
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CASE NARRATIVE SUMMARY
All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report.
[TOC_1]Case Narrative[TOC]
SW-846 8260D
Qualifications:
Continuing calibration verification (CCV) did not meet method specifications and was biased on the low side for this compound.
Analyte & Samples(s) Qualified:
V-05
trans-1,4-Dichloro-2-butene
22J0010-01[SW 01 183], 22J0010-02[SW 02 183], 22J0010-03[SW 03 183], 22J0010-04[SW 04 183], 22J0010-05[Duplicate], B318677-BLK1, B318677-BS1,
B318677-BSD1, S077387-CCV1
Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side. Data validation is not affected
since sample result was "not detected" for this compound.
Analyte & Samples(s) Qualified:
V-20
Chloroethane
B318677-BS1, B318677-BSD1, S077387-CCV1
Trichlorofluoromethane (Freon 11)
B318677-BS1, B318677-BSD1, S077387-CCV1
The results of analyses reported only relate to samples submitted to Con-Test, a Pace Analytical Laboratory, for testing.
I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed
in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the
best of my knowledge and belief, accurate and complete.
Meghan E. Kelley
Reporting Specialist
Page 4 of 27
Table of Contents
Page 9 of 32
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 10/1/2022
Work Order: 22J0010Sample Description:Project Location: Crown Food Mart 9/29
Sample ID: 22J0010-01
Field Sample #: SW 01 183
Sample Matrix: Water
Sampled: 9/29/2022 11:05
[TOC_2]22J0010-01[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 10/3/22 22:36 MFFg/L2.0 10/3/22SW-846 8260D1Acetone
ND 5.0 10/3/22 22:36 MFFg/L0.55 10/3/22SW-846 8260D1Acrylonitrile
ND 0.50 10/3/22 22:36 MFFg/L0.14 10/3/22SW-846 8260D1tert-Amyl Methyl Ether (TAME)
ND 1.0 10/3/22 22:36 MFFg/L0.20 10/3/22SW-846 8260D1Benzene
ND 1.0 10/3/22 22:36 MFFg/L0.15 10/3/22SW-846 8260D1Bromobenzene
ND 1.0 10/3/22 22:36 MFFg/L0.31 10/3/22SW-846 8260D1Bromochloromethane
ND 0.50 10/3/22 22:36 MFFg/L0.18 10/3/22SW-846 8260D1Bromodichloromethane
ND 1.0 10/3/22 22:36 MFFg/L0.38 10/3/22SW-846 8260D1Bromoform
ND 2.0 10/3/22 22:36 MFFg/L1.5 10/3/22SW-846 8260D1Bromomethane
ND 20 10/3/22 22:36 MFFg/L1.6 10/3/22SW-846 8260D12-Butanone (MEK)
ND 20 10/3/22 22:36 MFFg/L4.7 10/3/22SW-846 8260D1tert-Butyl Alcohol (TBA)
ND 1.0 10/3/22 22:36 MFFg/L0.15 10/3/22SW-846 8260D1n-Butylbenzene
ND 1.0 10/3/22 22:36 MFFg/L0.11 10/3/22SW-846 8260D1sec-Butylbenzene
ND 1.0 10/3/22 22:36 MFFg/L0.13 10/3/22SW-846 8260D1tert-Butylbenzene
ND 0.50 10/3/22 22:36 MFFg/L0.15 10/3/22SW-846 8260D1tert-Butyl Ethyl Ether (TBEE)
ND 5.0 10/3/22 22:36 MFFg/L1.4 10/3/22SW-846 8260D1Carbon Disulfide
ND 1.0 10/3/22 22:36 MFFg/L0.16 10/3/22SW-846 8260D1Carbon Tetrachloride
ND 1.0 10/3/22 22:36 MFFg/L0.11 10/3/22SW-846 8260D1Chlorobenzene
ND 0.50 10/3/22 22:36 MFFg/L0.22 10/3/22SW-846 8260D1Chlorodibromomethane
ND 2.0 10/3/22 22:36 MFFg/L0.32 10/3/22SW-846 8260D1Chloroethane
ND 2.0 10/3/22 22:36 MFFg/L0.17 10/3/22SW-846 8260D1Chloroform
ND 2.0 10/3/22 22:36 MFFg/L0.52 10/3/22SW-846 8260D1Chloromethane
ND 1.0 10/3/22 22:36 MFFg/L0.11 10/3/22SW-846 8260D12-Chlorotoluene
ND 1.0 10/3/22 22:36 MFFg/L0.12 10/3/22SW-846 8260D14-Chlorotoluene
ND 5.0 10/3/22 22:36 MFFg/L0.80 10/3/22SW-846 8260D11,2-Dibromo-3-chloropropane (DBCP)
ND 0.50 10/3/22 22:36 MFFg/L0.17 10/3/22SW-846 8260D11,2-Dibromoethane (EDB)
ND 1.0 10/3/22 22:36 MFFg/L0.35 10/3/22SW-846 8260D1Dibromomethane
ND 1.0 10/3/22 22:36 MFFg/L0.12 10/3/22SW-846 8260D11,2-Dichlorobenzene
ND 1.0 10/3/22 22:36 MFFg/L0.12 10/3/22SW-846 8260D11,3-Dichlorobenzene
ND 1.0 10/3/22 22:36 MFFg/L0.13 10/3/22SW-846 8260D11,4-Dichlorobenzene
ND 2.0 10/3/22 22:36 MFFg/L1.6 10/3/22SW-846 8260D1V-05trans-1,4-Dichloro-2-butene
ND 2.0 10/3/22 22:36 MFFg/L0.19 10/3/22SW-846 8260D1Dichlorodifluoromethane (Freon 12)
ND 1.0 10/3/22 22:36 MFFg/L0.14 10/3/22SW-846 8260D11,1-Dichloroethane
ND 1.0 10/3/22 22:36 MFFg/L0.31 10/3/22SW-846 8260D11,2-Dichloroethane
ND 1.0 10/3/22 22:36 MFFg/L0.14 10/3/22SW-846 8260D11,1-Dichloroethylene
ND 1.0 10/3/22 22:36 MFFg/L0.15 10/3/22SW-846 8260D1cis-1,2-Dichloroethylene
ND 1.0 10/3/22 22:36 MFFg/L0.17 10/3/22SW-846 8260D1trans-1,2-Dichloroethylene
ND 1.0 10/3/22 22:36 MFFg/L0.18 10/3/22SW-846 8260D11,2-Dichloropropane
ND 0.50 10/3/22 22:36 MFFg/L0.13 10/3/22SW-846 8260D11,3-Dichloropropane
ND 1.0 10/3/22 22:36 MFFg/L0.33 10/3/22SW-846 8260D12,2-Dichloropropane
ND 2.0 10/3/22 22:36 MFFg/L0.15 10/3/22SW-846 8260D11,1-Dichloropropene
ND 0.50 10/3/22 22:36 MFFg/L0.16 10/3/22SW-846 8260D1cis-1,3-Dichloropropene
ND 0.50 10/3/22 22:36 MFFg/L0.17 10/3/22SW-846 8260D1trans-1,3-Dichloropropene
ND 2.0 10/3/22 22:36 MFFg/L0.18 10/3/22SW-846 8260D1Diethyl Ether
[TOC_1]Sample Results[TOC]
Page 5 of 27
Table of Contents
Page 10 of 32
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 10/1/2022
Work Order: 22J0010Sample Description:Project Location: Crown Food Mart 9/29
Sample ID: 22J0010-01
Field Sample #: SW 01 183
Sample Matrix: Water
Sampled: 9/29/2022 11:05
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 10/3/22 22:36 MFFg/L0.13 10/3/22SW-846 8260D1Diisopropyl Ether (DIPE)
ND 50 10/3/22 22:36 MFFg/L21 10/3/22SW-846 8260D11,4-Dioxane
ND 1.0 10/3/22 22:36 MFFg/L0.21 10/3/22SW-846 8260D1Ethylbenzene
ND 0.60 10/3/22 22:36 MFFg/L0.46 10/3/22SW-846 8260D1Hexachlorobutadiene
ND 10 10/3/22 22:36 MFFg/L1.1 10/3/22SW-846 8260D12-Hexanone (MBK)
ND 1.0 10/3/22 22:36 MFFg/L0.11 10/3/22SW-846 8260D1Isopropylbenzene (Cumene)
ND 1.0 10/3/22 22:36 MFFg/L0.097 10/3/22SW-846 8260D1p-Isopropyltoluene (p-Cymene)
ND 1.0 10/3/22 22:36 MFFg/L0.17 10/3/22SW-846 8260D1Methyl tert-Butyl Ether (MTBE)
ND 5.0 10/3/22 22:36 MFFg/L0.23 10/3/22SW-846 8260D1Methylene Chloride
ND 10 10/3/22 22:36 MFFg/L1.3 10/3/22SW-846 8260D14-Methyl-2-pentanone (MIBK)
ND 2.0 10/3/22 22:36 MFFg/L0.24 10/3/22SW-846 8260D1Naphthalene
ND 1.0 10/3/22 22:36 MFFg/L0.086 10/3/22SW-846 8260D1n-Propylbenzene
ND 1.0 10/3/22 22:36 MFFg/L0.11 10/3/22SW-846 8260D1Styrene
ND 1.0 10/3/22 22:36 MFFg/L0.18 10/3/22SW-846 8260D11,1,1,2-Tetrachloroethane
ND 0.50 10/3/22 22:36 MFFg/L0.13 10/3/22SW-846 8260D11,1,2,2-Tetrachloroethane
ND 1.0 10/3/22 22:36 MFFg/L0.19 10/3/22SW-846 8260D1Tetrachloroethylene
ND 10 10/3/22 22:36 MFFg/L0.49 10/3/22SW-846 8260D1Tetrahydrofuran
ND 1.0 10/3/22 22:36 MFFg/L0.22 10/3/22SW-846 8260D1Toluene
ND 5.0 10/3/22 22:36 MFFg/L0.30 10/3/22SW-846 8260D11,2,3-Trichlorobenzene
ND 1.0 10/3/22 22:36 MFFg/L0.25 10/3/22SW-846 8260D11,2,4-Trichlorobenzene
ND 1.0 10/3/22 22:36 MFFg/L0.21 10/3/22SW-846 8260D11,3,5-Trichlorobenzene
ND 1.0 10/3/22 22:36 MFFg/L0.17 10/3/22SW-846 8260D11,1,1-Trichloroethane
ND 1.0 10/3/22 22:36 MFFg/L0.18 10/3/22SW-846 8260D11,1,2-Trichloroethane
ND 1.0 10/3/22 22:36 MFFg/L0.19 10/3/22SW-846 8260D1Trichloroethylene
ND 2.0 10/3/22 22:36 MFFg/L0.18 10/3/22SW-846 8260D1Trichlorofluoromethane (Freon 11)
ND 2.0 10/3/22 22:36 MFFg/L0.28 10/3/22SW-846 8260D11,2,3-Trichloropropane
ND 1.0 10/3/22 22:36 MFFg/L0.23 10/3/22SW-846 8260D11,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
ND 1.0 10/3/22 22:36 MFFg/L0.20 10/3/22SW-846 8260D11,2,4-Trimethylbenzene
ND 1.0 10/3/22 22:36 MFFg/L0.11 10/3/22SW-846 8260D11,3,5-Trimethylbenzene
ND 2.0 10/3/22 22:36 MFFg/L0.21 10/3/22SW-846 8260D1Vinyl Chloride
ND 2.0 10/3/22 22:36 MFFg/L0.46 10/3/22SW-846 8260D1m+p Xylene
ND 1.0 10/3/22 22:36 MFFg/L0.23 10/3/22SW-846 8260D1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 102 10/3/22 22:3670-130
Toluene-d8 100 10/3/22 22:3670-130
4-Bromofluorobenzene 97.6 10/3/22 22:3670-130
Page 6 of 27
Table of Contents
Page 11 of 32
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 10/1/2022
Work Order: 22J0010Sample Description:Project Location: Crown Food Mart 9/29
Sample ID: 22J0010-02
Field Sample #: SW 02 183
Sample Matrix: Water
Sampled: 9/29/2022 12:00
[TOC_2]22J0010-02[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 10/3/22 23:02 MFFg/L2.0 10/3/22SW-846 8260D1Acetone
ND 5.0 10/3/22 23:02 MFFg/L0.55 10/3/22SW-846 8260D1Acrylonitrile
ND 0.50 10/3/22 23:02 MFFg/L0.14 10/3/22SW-846 8260D1tert-Amyl Methyl Ether (TAME)
ND 1.0 10/3/22 23:02 MFFg/L0.20 10/3/22SW-846 8260D1Benzene
ND 1.0 10/3/22 23:02 MFFg/L0.15 10/3/22SW-846 8260D1Bromobenzene
ND 1.0 10/3/22 23:02 MFFg/L0.31 10/3/22SW-846 8260D1Bromochloromethane
ND 0.50 10/3/22 23:02 MFFg/L0.18 10/3/22SW-846 8260D1Bromodichloromethane
ND 1.0 10/3/22 23:02 MFFg/L0.38 10/3/22SW-846 8260D1Bromoform
ND 2.0 10/3/22 23:02 MFFg/L1.5 10/3/22SW-846 8260D1Bromomethane
ND 20 10/3/22 23:02 MFFg/L1.6 10/3/22SW-846 8260D12-Butanone (MEK)
ND 20 10/3/22 23:02 MFFg/L4.7 10/3/22SW-846 8260D1tert-Butyl Alcohol (TBA)
ND 1.0 10/3/22 23:02 MFFg/L0.15 10/3/22SW-846 8260D1n-Butylbenzene
ND 1.0 10/3/22 23:02 MFFg/L0.11 10/3/22SW-846 8260D1sec-Butylbenzene
ND 1.0 10/3/22 23:02 MFFg/L0.13 10/3/22SW-846 8260D1tert-Butylbenzene
ND 0.50 10/3/22 23:02 MFFg/L0.15 10/3/22SW-846 8260D1tert-Butyl Ethyl Ether (TBEE)
ND 5.0 10/3/22 23:02 MFFg/L1.4 10/3/22SW-846 8260D1Carbon Disulfide
ND 1.0 10/3/22 23:02 MFFg/L0.16 10/3/22SW-846 8260D1Carbon Tetrachloride
ND 1.0 10/3/22 23:02 MFFg/L0.11 10/3/22SW-846 8260D1Chlorobenzene
ND 0.50 10/3/22 23:02 MFFg/L0.22 10/3/22SW-846 8260D1Chlorodibromomethane
ND 2.0 10/3/22 23:02 MFFg/L0.32 10/3/22SW-846 8260D1Chloroethane
ND 2.0 10/3/22 23:02 MFFg/L0.17 10/3/22SW-846 8260D1Chloroform
ND 2.0 10/3/22 23:02 MFFg/L0.52 10/3/22SW-846 8260D1Chloromethane
ND 1.0 10/3/22 23:02 MFFg/L0.11 10/3/22SW-846 8260D12-Chlorotoluene
ND 1.0 10/3/22 23:02 MFFg/L0.12 10/3/22SW-846 8260D14-Chlorotoluene
ND 5.0 10/3/22 23:02 MFFg/L0.80 10/3/22SW-846 8260D11,2-Dibromo-3-chloropropane (DBCP)
ND 0.50 10/3/22 23:02 MFFg/L0.17 10/3/22SW-846 8260D11,2-Dibromoethane (EDB)
ND 1.0 10/3/22 23:02 MFFg/L0.35 10/3/22SW-846 8260D1Dibromomethane
ND 1.0 10/3/22 23:02 MFFg/L0.12 10/3/22SW-846 8260D11,2-Dichlorobenzene
ND 1.0 10/3/22 23:02 MFFg/L0.12 10/3/22SW-846 8260D11,3-Dichlorobenzene
ND 1.0 10/3/22 23:02 MFFg/L0.13 10/3/22SW-846 8260D11,4-Dichlorobenzene
ND 2.0 10/3/22 23:02 MFFg/L1.6 10/3/22SW-846 8260D1V-05trans-1,4-Dichloro-2-butene
ND 2.0 10/3/22 23:02 MFFg/L0.19 10/3/22SW-846 8260D1Dichlorodifluoromethane (Freon 12)
ND 1.0 10/3/22 23:02 MFFg/L0.14 10/3/22SW-846 8260D11,1-Dichloroethane
ND 1.0 10/3/22 23:02 MFFg/L0.31 10/3/22SW-846 8260D11,2-Dichloroethane
ND 1.0 10/3/22 23:02 MFFg/L0.14 10/3/22SW-846 8260D11,1-Dichloroethylene
ND 1.0 10/3/22 23:02 MFFg/L0.15 10/3/22SW-846 8260D1cis-1,2-Dichloroethylene
ND 1.0 10/3/22 23:02 MFFg/L0.17 10/3/22SW-846 8260D1trans-1,2-Dichloroethylene
ND 1.0 10/3/22 23:02 MFFg/L0.18 10/3/22SW-846 8260D11,2-Dichloropropane
ND 0.50 10/3/22 23:02 MFFg/L0.13 10/3/22SW-846 8260D11,3-Dichloropropane
ND 1.0 10/3/22 23:02 MFFg/L0.33 10/3/22SW-846 8260D12,2-Dichloropropane
ND 2.0 10/3/22 23:02 MFFg/L0.15 10/3/22SW-846 8260D11,1-Dichloropropene
ND 0.50 10/3/22 23:02 MFFg/L0.16 10/3/22SW-846 8260D1cis-1,3-Dichloropropene
ND 0.50 10/3/22 23:02 MFFg/L0.17 10/3/22SW-846 8260D1trans-1,3-Dichloropropene
ND 2.0 10/3/22 23:02 MFFg/L0.18 10/3/22SW-846 8260D1Diethyl Ether
Page 7 of 27
Table of Contents
Page 12 of 32
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 10/1/2022
Work Order: 22J0010Sample Description:Project Location: Crown Food Mart 9/29
Sample ID: 22J0010-02
Field Sample #: SW 02 183
Sample Matrix: Water
Sampled: 9/29/2022 12:00
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 10/3/22 23:02 MFFg/L0.13 10/3/22SW-846 8260D1Diisopropyl Ether (DIPE)
ND 50 10/3/22 23:02 MFFg/L21 10/3/22SW-846 8260D11,4-Dioxane
ND 1.0 10/3/22 23:02 MFFg/L0.21 10/3/22SW-846 8260D1Ethylbenzene
ND 0.60 10/3/22 23:02 MFFg/L0.46 10/3/22SW-846 8260D1Hexachlorobutadiene
ND 10 10/3/22 23:02 MFFg/L1.1 10/3/22SW-846 8260D12-Hexanone (MBK)
ND 1.0 10/3/22 23:02 MFFg/L0.11 10/3/22SW-846 8260D1Isopropylbenzene (Cumene)
ND 1.0 10/3/22 23:02 MFFg/L0.097 10/3/22SW-846 8260D1p-Isopropyltoluene (p-Cymene)
ND 1.0 10/3/22 23:02 MFFg/L0.17 10/3/22SW-846 8260D1Methyl tert-Butyl Ether (MTBE)
ND 5.0 10/3/22 23:02 MFFg/L0.23 10/3/22SW-846 8260D1Methylene Chloride
ND 10 10/3/22 23:02 MFFg/L1.3 10/3/22SW-846 8260D14-Methyl-2-pentanone (MIBK)
ND 2.0 10/3/22 23:02 MFFg/L0.24 10/3/22SW-846 8260D1Naphthalene
ND 1.0 10/3/22 23:02 MFFg/L0.086 10/3/22SW-846 8260D1n-Propylbenzene
ND 1.0 10/3/22 23:02 MFFg/L0.11 10/3/22SW-846 8260D1Styrene
ND 1.0 10/3/22 23:02 MFFg/L0.18 10/3/22SW-846 8260D11,1,1,2-Tetrachloroethane
ND 0.50 10/3/22 23:02 MFFg/L0.13 10/3/22SW-846 8260D11,1,2,2-Tetrachloroethane
ND 1.0 10/3/22 23:02 MFFg/L0.19 10/3/22SW-846 8260D1Tetrachloroethylene
ND 10 10/3/22 23:02 MFFg/L0.49 10/3/22SW-846 8260D1Tetrahydrofuran
ND 1.0 10/3/22 23:02 MFFg/L0.22 10/3/22SW-846 8260D1Toluene
ND 5.0 10/3/22 23:02 MFFg/L0.30 10/3/22SW-846 8260D11,2,3-Trichlorobenzene
ND 1.0 10/3/22 23:02 MFFg/L0.25 10/3/22SW-846 8260D11,2,4-Trichlorobenzene
ND 1.0 10/3/22 23:02 MFFg/L0.21 10/3/22SW-846 8260D11,3,5-Trichlorobenzene
ND 1.0 10/3/22 23:02 MFFg/L0.17 10/3/22SW-846 8260D11,1,1-Trichloroethane
ND 1.0 10/3/22 23:02 MFFg/L0.18 10/3/22SW-846 8260D11,1,2-Trichloroethane
ND 1.0 10/3/22 23:02 MFFg/L0.19 10/3/22SW-846 8260D1Trichloroethylene
ND 2.0 10/3/22 23:02 MFFg/L0.18 10/3/22SW-846 8260D1Trichlorofluoromethane (Freon 11)
ND 2.0 10/3/22 23:02 MFFg/L0.28 10/3/22SW-846 8260D11,2,3-Trichloropropane
ND 1.0 10/3/22 23:02 MFFg/L0.23 10/3/22SW-846 8260D11,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
0.57 1.0 10/3/22 23:02 MFFg/L0.20 10/3/22SW-846 8260D1J1,2,4-Trimethylbenzene
0.16 1.0 10/3/22 23:02 MFFg/L0.11 10/3/22SW-846 8260D1J1,3,5-Trimethylbenzene
ND 2.0 10/3/22 23:02 MFFg/L0.21 10/3/22SW-846 8260D1Vinyl Chloride
ND 2.0 10/3/22 23:02 MFFg/L0.46 10/3/22SW-846 8260D1m+p Xylene
ND 1.0 10/3/22 23:02 MFFg/L0.23 10/3/22SW-846 8260D1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 100 10/3/22 23:0270-130
Toluene-d8 100 10/3/22 23:0270-130
4-Bromofluorobenzene 98.0 10/3/22 23:0270-130
Page 8 of 27
Table of Contents
Page 13 of 32
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 10/1/2022
Work Order: 22J0010Sample Description:Project Location: Crown Food Mart 9/29
Sample ID: 22J0010-03
Field Sample #: SW 03 183
Sample Matrix: Water
Sampled: 9/29/2022 12:45
[TOC_2]22J0010-03[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 10/3/22 23:29 MFFg/L2.0 10/3/22SW-846 8260D1Acetone
ND 5.0 10/3/22 23:29 MFFg/L0.55 10/3/22SW-846 8260D1Acrylonitrile
ND 0.50 10/3/22 23:29 MFFg/L0.14 10/3/22SW-846 8260D1tert-Amyl Methyl Ether (TAME)
ND 1.0 10/3/22 23:29 MFFg/L0.20 10/3/22SW-846 8260D1Benzene
ND 1.0 10/3/22 23:29 MFFg/L0.15 10/3/22SW-846 8260D1Bromobenzene
ND 1.0 10/3/22 23:29 MFFg/L0.31 10/3/22SW-846 8260D1Bromochloromethane
ND 0.50 10/3/22 23:29 MFFg/L0.18 10/3/22SW-846 8260D1Bromodichloromethane
ND 1.0 10/3/22 23:29 MFFg/L0.38 10/3/22SW-846 8260D1Bromoform
ND 2.0 10/3/22 23:29 MFFg/L1.5 10/3/22SW-846 8260D1Bromomethane
ND 20 10/3/22 23:29 MFFg/L1.6 10/3/22SW-846 8260D12-Butanone (MEK)
ND 20 10/3/22 23:29 MFFg/L4.7 10/3/22SW-846 8260D1tert-Butyl Alcohol (TBA)
ND 1.0 10/3/22 23:29 MFFg/L0.15 10/3/22SW-846 8260D1n-Butylbenzene
ND 1.0 10/3/22 23:29 MFFg/L0.11 10/3/22SW-846 8260D1sec-Butylbenzene
ND 1.0 10/3/22 23:29 MFFg/L0.13 10/3/22SW-846 8260D1tert-Butylbenzene
ND 0.50 10/3/22 23:29 MFFg/L0.15 10/3/22SW-846 8260D1tert-Butyl Ethyl Ether (TBEE)
ND 5.0 10/3/22 23:29 MFFg/L1.4 10/3/22SW-846 8260D1Carbon Disulfide
ND 1.0 10/3/22 23:29 MFFg/L0.16 10/3/22SW-846 8260D1Carbon Tetrachloride
ND 1.0 10/3/22 23:29 MFFg/L0.11 10/3/22SW-846 8260D1Chlorobenzene
ND 0.50 10/3/22 23:29 MFFg/L0.22 10/3/22SW-846 8260D1Chlorodibromomethane
ND 2.0 10/3/22 23:29 MFFg/L0.32 10/3/22SW-846 8260D1Chloroethane
ND 2.0 10/3/22 23:29 MFFg/L0.17 10/3/22SW-846 8260D1Chloroform
ND 2.0 10/3/22 23:29 MFFg/L0.52 10/3/22SW-846 8260D1Chloromethane
ND 1.0 10/3/22 23:29 MFFg/L0.11 10/3/22SW-846 8260D12-Chlorotoluene
ND 1.0 10/3/22 23:29 MFFg/L0.12 10/3/22SW-846 8260D14-Chlorotoluene
ND 5.0 10/3/22 23:29 MFFg/L0.80 10/3/22SW-846 8260D11,2-Dibromo-3-chloropropane (DBCP)
ND 0.50 10/3/22 23:29 MFFg/L0.17 10/3/22SW-846 8260D11,2-Dibromoethane (EDB)
ND 1.0 10/3/22 23:29 MFFg/L0.35 10/3/22SW-846 8260D1Dibromomethane
ND 1.0 10/3/22 23:29 MFFg/L0.12 10/3/22SW-846 8260D11,2-Dichlorobenzene
ND 1.0 10/3/22 23:29 MFFg/L0.12 10/3/22SW-846 8260D11,3-Dichlorobenzene
ND 1.0 10/3/22 23:29 MFFg/L0.13 10/3/22SW-846 8260D11,4-Dichlorobenzene
ND 2.0 10/3/22 23:29 MFFg/L1.6 10/3/22SW-846 8260D1V-05trans-1,4-Dichloro-2-butene
ND 2.0 10/3/22 23:29 MFFg/L0.19 10/3/22SW-846 8260D1Dichlorodifluoromethane (Freon 12)
ND 1.0 10/3/22 23:29 MFFg/L0.14 10/3/22SW-846 8260D11,1-Dichloroethane
ND 1.0 10/3/22 23:29 MFFg/L0.31 10/3/22SW-846 8260D11,2-Dichloroethane
ND 1.0 10/3/22 23:29 MFFg/L0.14 10/3/22SW-846 8260D11,1-Dichloroethylene
ND 1.0 10/3/22 23:29 MFFg/L0.15 10/3/22SW-846 8260D1cis-1,2-Dichloroethylene
ND 1.0 10/3/22 23:29 MFFg/L0.17 10/3/22SW-846 8260D1trans-1,2-Dichloroethylene
ND 1.0 10/3/22 23:29 MFFg/L0.18 10/3/22SW-846 8260D11,2-Dichloropropane
ND 0.50 10/3/22 23:29 MFFg/L0.13 10/3/22SW-846 8260D11,3-Dichloropropane
ND 1.0 10/3/22 23:29 MFFg/L0.33 10/3/22SW-846 8260D12,2-Dichloropropane
ND 2.0 10/3/22 23:29 MFFg/L0.15 10/3/22SW-846 8260D11,1-Dichloropropene
ND 0.50 10/3/22 23:29 MFFg/L0.16 10/3/22SW-846 8260D1cis-1,3-Dichloropropene
ND 0.50 10/3/22 23:29 MFFg/L0.17 10/3/22SW-846 8260D1trans-1,3-Dichloropropene
ND 2.0 10/3/22 23:29 MFFg/L0.18 10/3/22SW-846 8260D1Diethyl Ether
Page 9 of 27
Table of Contents
Page 14 of 32
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 10/1/2022
Work Order: 22J0010Sample Description:Project Location: Crown Food Mart 9/29
Sample ID: 22J0010-03
Field Sample #: SW 03 183
Sample Matrix: Water
Sampled: 9/29/2022 12:45
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 10/3/22 23:29 MFFg/L0.13 10/3/22SW-846 8260D1Diisopropyl Ether (DIPE)
ND 50 10/3/22 23:29 MFFg/L21 10/3/22SW-846 8260D11,4-Dioxane
ND 1.0 10/3/22 23:29 MFFg/L0.21 10/3/22SW-846 8260D1Ethylbenzene
ND 0.60 10/3/22 23:29 MFFg/L0.46 10/3/22SW-846 8260D1Hexachlorobutadiene
ND 10 10/3/22 23:29 MFFg/L1.1 10/3/22SW-846 8260D12-Hexanone (MBK)
ND 1.0 10/3/22 23:29 MFFg/L0.11 10/3/22SW-846 8260D1Isopropylbenzene (Cumene)
ND 1.0 10/3/22 23:29 MFFg/L0.097 10/3/22SW-846 8260D1p-Isopropyltoluene (p-Cymene)
ND 1.0 10/3/22 23:29 MFFg/L0.17 10/3/22SW-846 8260D1Methyl tert-Butyl Ether (MTBE)
ND 5.0 10/3/22 23:29 MFFg/L0.23 10/3/22SW-846 8260D1Methylene Chloride
ND 10 10/3/22 23:29 MFFg/L1.3 10/3/22SW-846 8260D14-Methyl-2-pentanone (MIBK)
ND 2.0 10/3/22 23:29 MFFg/L0.24 10/3/22SW-846 8260D1Naphthalene
ND 1.0 10/3/22 23:29 MFFg/L0.086 10/3/22SW-846 8260D1n-Propylbenzene
ND 1.0 10/3/22 23:29 MFFg/L0.11 10/3/22SW-846 8260D1Styrene
ND 1.0 10/3/22 23:29 MFFg/L0.18 10/3/22SW-846 8260D11,1,1,2-Tetrachloroethane
ND 0.50 10/3/22 23:29 MFFg/L0.13 10/3/22SW-846 8260D11,1,2,2-Tetrachloroethane
ND 1.0 10/3/22 23:29 MFFg/L0.19 10/3/22SW-846 8260D1Tetrachloroethylene
ND 10 10/3/22 23:29 MFFg/L0.49 10/3/22SW-846 8260D1Tetrahydrofuran
ND 1.0 10/3/22 23:29 MFFg/L0.22 10/3/22SW-846 8260D1Toluene
ND 5.0 10/3/22 23:29 MFFg/L0.30 10/3/22SW-846 8260D11,2,3-Trichlorobenzene
ND 1.0 10/3/22 23:29 MFFg/L0.25 10/3/22SW-846 8260D11,2,4-Trichlorobenzene
ND 1.0 10/3/22 23:29 MFFg/L0.21 10/3/22SW-846 8260D11,3,5-Trichlorobenzene
ND 1.0 10/3/22 23:29 MFFg/L0.17 10/3/22SW-846 8260D11,1,1-Trichloroethane
ND 1.0 10/3/22 23:29 MFFg/L0.18 10/3/22SW-846 8260D11,1,2-Trichloroethane
ND 1.0 10/3/22 23:29 MFFg/L0.19 10/3/22SW-846 8260D1Trichloroethylene
ND 2.0 10/3/22 23:29 MFFg/L0.18 10/3/22SW-846 8260D1Trichlorofluoromethane (Freon 11)
ND 2.0 10/3/22 23:29 MFFg/L0.28 10/3/22SW-846 8260D11,2,3-Trichloropropane
ND 1.0 10/3/22 23:29 MFFg/L0.23 10/3/22SW-846 8260D11,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
0.23 1.0 10/3/22 23:29 MFFg/L0.20 10/3/22SW-846 8260D1J1,2,4-Trimethylbenzene
ND 1.0 10/3/22 23:29 MFFg/L0.11 10/3/22SW-846 8260D11,3,5-Trimethylbenzene
ND 2.0 10/3/22 23:29 MFFg/L0.21 10/3/22SW-846 8260D1Vinyl Chloride
ND 2.0 10/3/22 23:29 MFFg/L0.46 10/3/22SW-846 8260D1m+p Xylene
ND 1.0 10/3/22 23:29 MFFg/L0.23 10/3/22SW-846 8260D1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 105 10/3/22 23:2970-130
Toluene-d8 101 10/3/22 23:2970-130
4-Bromofluorobenzene 100 10/3/22 23:2970-130
Page 10 of 27
Table of Contents
Page 15 of 32
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 10/1/2022
Work Order: 22J0010Sample Description:Project Location: Crown Food Mart 9/29
Sample ID: 22J0010-04
Field Sample #: SW 04 183
Sample Matrix: Water
Sampled: 9/29/2022 13:10
[TOC_2]22J0010-04[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 10/3/22 23:55 MFFg/L2.0 10/3/22SW-846 8260D1Acetone
ND 5.0 10/3/22 23:55 MFFg/L0.55 10/3/22SW-846 8260D1Acrylonitrile
ND 0.50 10/3/22 23:55 MFFg/L0.14 10/3/22SW-846 8260D1tert-Amyl Methyl Ether (TAME)
ND 1.0 10/3/22 23:55 MFFg/L0.20 10/3/22SW-846 8260D1Benzene
ND 1.0 10/3/22 23:55 MFFg/L0.15 10/3/22SW-846 8260D1Bromobenzene
ND 1.0 10/3/22 23:55 MFFg/L0.31 10/3/22SW-846 8260D1Bromochloromethane
ND 0.50 10/3/22 23:55 MFFg/L0.18 10/3/22SW-846 8260D1Bromodichloromethane
ND 1.0 10/3/22 23:55 MFFg/L0.38 10/3/22SW-846 8260D1Bromoform
ND 2.0 10/3/22 23:55 MFFg/L1.5 10/3/22SW-846 8260D1Bromomethane
ND 20 10/3/22 23:55 MFFg/L1.6 10/3/22SW-846 8260D12-Butanone (MEK)
ND 20 10/3/22 23:55 MFFg/L4.7 10/3/22SW-846 8260D1tert-Butyl Alcohol (TBA)
ND 1.0 10/3/22 23:55 MFFg/L0.15 10/3/22SW-846 8260D1n-Butylbenzene
ND 1.0 10/3/22 23:55 MFFg/L0.11 10/3/22SW-846 8260D1sec-Butylbenzene
ND 1.0 10/3/22 23:55 MFFg/L0.13 10/3/22SW-846 8260D1tert-Butylbenzene
ND 0.50 10/3/22 23:55 MFFg/L0.15 10/3/22SW-846 8260D1tert-Butyl Ethyl Ether (TBEE)
ND 5.0 10/3/22 23:55 MFFg/L1.4 10/3/22SW-846 8260D1Carbon Disulfide
ND 1.0 10/3/22 23:55 MFFg/L0.16 10/3/22SW-846 8260D1Carbon Tetrachloride
ND 1.0 10/3/22 23:55 MFFg/L0.11 10/3/22SW-846 8260D1Chlorobenzene
ND 0.50 10/3/22 23:55 MFFg/L0.22 10/3/22SW-846 8260D1Chlorodibromomethane
ND 2.0 10/3/22 23:55 MFFg/L0.32 10/3/22SW-846 8260D1Chloroethane
ND 2.0 10/3/22 23:55 MFFg/L0.17 10/3/22SW-846 8260D1Chloroform
ND 2.0 10/3/22 23:55 MFFg/L0.52 10/3/22SW-846 8260D1Chloromethane
ND 1.0 10/3/22 23:55 MFFg/L0.11 10/3/22SW-846 8260D12-Chlorotoluene
ND 1.0 10/3/22 23:55 MFFg/L0.12 10/3/22SW-846 8260D14-Chlorotoluene
ND 5.0 10/3/22 23:55 MFFg/L0.80 10/3/22SW-846 8260D11,2-Dibromo-3-chloropropane (DBCP)
ND 0.50 10/3/22 23:55 MFFg/L0.17 10/3/22SW-846 8260D11,2-Dibromoethane (EDB)
ND 1.0 10/3/22 23:55 MFFg/L0.35 10/3/22SW-846 8260D1Dibromomethane
ND 1.0 10/3/22 23:55 MFFg/L0.12 10/3/22SW-846 8260D11,2-Dichlorobenzene
ND 1.0 10/3/22 23:55 MFFg/L0.12 10/3/22SW-846 8260D11,3-Dichlorobenzene
ND 1.0 10/3/22 23:55 MFFg/L0.13 10/3/22SW-846 8260D11,4-Dichlorobenzene
ND 2.0 10/3/22 23:55 MFFg/L1.6 10/3/22SW-846 8260D1V-05trans-1,4-Dichloro-2-butene
ND 2.0 10/3/22 23:55 MFFg/L0.19 10/3/22SW-846 8260D1Dichlorodifluoromethane (Freon 12)
ND 1.0 10/3/22 23:55 MFFg/L0.14 10/3/22SW-846 8260D11,1-Dichloroethane
ND 1.0 10/3/22 23:55 MFFg/L0.31 10/3/22SW-846 8260D11,2-Dichloroethane
ND 1.0 10/3/22 23:55 MFFg/L0.14 10/3/22SW-846 8260D11,1-Dichloroethylene
ND 1.0 10/3/22 23:55 MFFg/L0.15 10/3/22SW-846 8260D1cis-1,2-Dichloroethylene
ND 1.0 10/3/22 23:55 MFFg/L0.17 10/3/22SW-846 8260D1trans-1,2-Dichloroethylene
ND 1.0 10/3/22 23:55 MFFg/L0.18 10/3/22SW-846 8260D11,2-Dichloropropane
ND 0.50 10/3/22 23:55 MFFg/L0.13 10/3/22SW-846 8260D11,3-Dichloropropane
ND 1.0 10/3/22 23:55 MFFg/L0.33 10/3/22SW-846 8260D12,2-Dichloropropane
ND 2.0 10/3/22 23:55 MFFg/L0.15 10/3/22SW-846 8260D11,1-Dichloropropene
ND 0.50 10/3/22 23:55 MFFg/L0.16 10/3/22SW-846 8260D1cis-1,3-Dichloropropene
ND 0.50 10/3/22 23:55 MFFg/L0.17 10/3/22SW-846 8260D1trans-1,3-Dichloropropene
ND 2.0 10/3/22 23:55 MFFg/L0.18 10/3/22SW-846 8260D1Diethyl Ether
Page 11 of 27
Table of Contents
Page 16 of 32
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 10/1/2022
Work Order: 22J0010Sample Description:Project Location: Crown Food Mart 9/29
Sample ID: 22J0010-04
Field Sample #: SW 04 183
Sample Matrix: Water
Sampled: 9/29/2022 13:10
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 10/3/22 23:55 MFFg/L0.13 10/3/22SW-846 8260D1Diisopropyl Ether (DIPE)
ND 50 10/3/22 23:55 MFFg/L21 10/3/22SW-846 8260D11,4-Dioxane
ND 1.0 10/3/22 23:55 MFFg/L0.21 10/3/22SW-846 8260D1Ethylbenzene
ND 0.60 10/3/22 23:55 MFFg/L0.46 10/3/22SW-846 8260D1Hexachlorobutadiene
ND 10 10/3/22 23:55 MFFg/L1.1 10/3/22SW-846 8260D12-Hexanone (MBK)
ND 1.0 10/3/22 23:55 MFFg/L0.11 10/3/22SW-846 8260D1Isopropylbenzene (Cumene)
ND 1.0 10/3/22 23:55 MFFg/L0.097 10/3/22SW-846 8260D1p-Isopropyltoluene (p-Cymene)
ND 1.0 10/3/22 23:55 MFFg/L0.17 10/3/22SW-846 8260D1Methyl tert-Butyl Ether (MTBE)
ND 5.0 10/3/22 23:55 MFFg/L0.23 10/3/22SW-846 8260D1Methylene Chloride
ND 10 10/3/22 23:55 MFFg/L1.3 10/3/22SW-846 8260D14-Methyl-2-pentanone (MIBK)
ND 2.0 10/3/22 23:55 MFFg/L0.24 10/3/22SW-846 8260D1Naphthalene
ND 1.0 10/3/22 23:55 MFFg/L0.086 10/3/22SW-846 8260D1n-Propylbenzene
ND 1.0 10/3/22 23:55 MFFg/L0.11 10/3/22SW-846 8260D1Styrene
ND 1.0 10/3/22 23:55 MFFg/L0.18 10/3/22SW-846 8260D11,1,1,2-Tetrachloroethane
ND 0.50 10/3/22 23:55 MFFg/L0.13 10/3/22SW-846 8260D11,1,2,2-Tetrachloroethane
ND 1.0 10/3/22 23:55 MFFg/L0.19 10/3/22SW-846 8260D1Tetrachloroethylene
ND 10 10/3/22 23:55 MFFg/L0.49 10/3/22SW-846 8260D1Tetrahydrofuran
ND 1.0 10/3/22 23:55 MFFg/L0.22 10/3/22SW-846 8260D1Toluene
ND 5.0 10/3/22 23:55 MFFg/L0.30 10/3/22SW-846 8260D11,2,3-Trichlorobenzene
ND 1.0 10/3/22 23:55 MFFg/L0.25 10/3/22SW-846 8260D11,2,4-Trichlorobenzene
ND 1.0 10/3/22 23:55 MFFg/L0.21 10/3/22SW-846 8260D11,3,5-Trichlorobenzene
ND 1.0 10/3/22 23:55 MFFg/L0.17 10/3/22SW-846 8260D11,1,1-Trichloroethane
ND 1.0 10/3/22 23:55 MFFg/L0.18 10/3/22SW-846 8260D11,1,2-Trichloroethane
ND 1.0 10/3/22 23:55 MFFg/L0.19 10/3/22SW-846 8260D1Trichloroethylene
ND 2.0 10/3/22 23:55 MFFg/L0.18 10/3/22SW-846 8260D1Trichlorofluoromethane (Freon 11)
ND 2.0 10/3/22 23:55 MFFg/L0.28 10/3/22SW-846 8260D11,2,3-Trichloropropane
ND 1.0 10/3/22 23:55 MFFg/L0.23 10/3/22SW-846 8260D11,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
ND 1.0 10/3/22 23:55 MFFg/L0.20 10/3/22SW-846 8260D11,2,4-Trimethylbenzene
ND 1.0 10/3/22 23:55 MFFg/L0.11 10/3/22SW-846 8260D11,3,5-Trimethylbenzene
ND 2.0 10/3/22 23:55 MFFg/L0.21 10/3/22SW-846 8260D1Vinyl Chloride
ND 2.0 10/3/22 23:55 MFFg/L0.46 10/3/22SW-846 8260D1m+p Xylene
ND 1.0 10/3/22 23:55 MFFg/L0.23 10/3/22SW-846 8260D1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 101 10/3/22 23:5570-130
Toluene-d8 101 10/3/22 23:5570-130
4-Bromofluorobenzene 98.6 10/3/22 23:5570-130
Page 12 of 27
Table of Contents
Page 17 of 32
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 10/1/2022
Work Order: 22J0010Sample Description:Project Location: Crown Food Mart 9/29
Sample ID: 22J0010-05
Field Sample #: Duplicate
Sample Matrix: Water
Sampled: 9/29/2022 12:15
[TOC_2]22J0010-05[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 50 10/4/22 0:21 MFFg/L2.0 10/3/22SW-846 8260D1Acetone
ND 5.0 10/4/22 0:21 MFFg/L0.55 10/3/22SW-846 8260D1Acrylonitrile
ND 0.50 10/4/22 0:21 MFFg/L0.14 10/3/22SW-846 8260D1tert-Amyl Methyl Ether (TAME)
ND 1.0 10/4/22 0:21 MFFg/L0.20 10/3/22SW-846 8260D1Benzene
ND 1.0 10/4/22 0:21 MFFg/L0.15 10/3/22SW-846 8260D1Bromobenzene
ND 1.0 10/4/22 0:21 MFFg/L0.31 10/3/22SW-846 8260D1Bromochloromethane
ND 0.50 10/4/22 0:21 MFFg/L0.18 10/3/22SW-846 8260D1Bromodichloromethane
ND 1.0 10/4/22 0:21 MFFg/L0.38 10/3/22SW-846 8260D1Bromoform
ND 2.0 10/4/22 0:21 MFFg/L1.5 10/3/22SW-846 8260D1Bromomethane
ND 20 10/4/22 0:21 MFFg/L1.6 10/3/22SW-846 8260D12-Butanone (MEK)
ND 20 10/4/22 0:21 MFFg/L4.7 10/3/22SW-846 8260D1tert-Butyl Alcohol (TBA)
ND 1.0 10/4/22 0:21 MFFg/L0.15 10/3/22SW-846 8260D1n-Butylbenzene
ND 1.0 10/4/22 0:21 MFFg/L0.11 10/3/22SW-846 8260D1sec-Butylbenzene
ND 1.0 10/4/22 0:21 MFFg/L0.13 10/3/22SW-846 8260D1tert-Butylbenzene
ND 0.50 10/4/22 0:21 MFFg/L0.15 10/3/22SW-846 8260D1tert-Butyl Ethyl Ether (TBEE)
ND 5.0 10/4/22 0:21 MFFg/L1.4 10/3/22SW-846 8260D1Carbon Disulfide
ND 1.0 10/4/22 0:21 MFFg/L0.16 10/3/22SW-846 8260D1Carbon Tetrachloride
ND 1.0 10/4/22 0:21 MFFg/L0.11 10/3/22SW-846 8260D1Chlorobenzene
ND 0.50 10/4/22 0:21 MFFg/L0.22 10/3/22SW-846 8260D1Chlorodibromomethane
ND 2.0 10/4/22 0:21 MFFg/L0.32 10/3/22SW-846 8260D1Chloroethane
ND 2.0 10/4/22 0:21 MFFg/L0.17 10/3/22SW-846 8260D1Chloroform
ND 2.0 10/4/22 0:21 MFFg/L0.52 10/3/22SW-846 8260D1Chloromethane
ND 1.0 10/4/22 0:21 MFFg/L0.11 10/3/22SW-846 8260D12-Chlorotoluene
ND 1.0 10/4/22 0:21 MFFg/L0.12 10/3/22SW-846 8260D14-Chlorotoluene
ND 5.0 10/4/22 0:21 MFFg/L0.80 10/3/22SW-846 8260D11,2-Dibromo-3-chloropropane (DBCP)
ND 0.50 10/4/22 0:21 MFFg/L0.17 10/3/22SW-846 8260D11,2-Dibromoethane (EDB)
ND 1.0 10/4/22 0:21 MFFg/L0.35 10/3/22SW-846 8260D1Dibromomethane
ND 1.0 10/4/22 0:21 MFFg/L0.12 10/3/22SW-846 8260D11,2-Dichlorobenzene
ND 1.0 10/4/22 0:21 MFFg/L0.12 10/3/22SW-846 8260D11,3-Dichlorobenzene
ND 1.0 10/4/22 0:21 MFFg/L0.13 10/3/22SW-846 8260D11,4-Dichlorobenzene
ND 2.0 10/4/22 0:21 MFFg/L1.6 10/3/22SW-846 8260D1V-05trans-1,4-Dichloro-2-butene
ND 2.0 10/4/22 0:21 MFFg/L0.19 10/3/22SW-846 8260D1Dichlorodifluoromethane (Freon 12)
ND 1.0 10/4/22 0:21 MFFg/L0.14 10/3/22SW-846 8260D11,1-Dichloroethane
ND 1.0 10/4/22 0:21 MFFg/L0.31 10/3/22SW-846 8260D11,2-Dichloroethane
ND 1.0 10/4/22 0:21 MFFg/L0.14 10/3/22SW-846 8260D11,1-Dichloroethylene
ND 1.0 10/4/22 0:21 MFFg/L0.15 10/3/22SW-846 8260D1cis-1,2-Dichloroethylene
ND 1.0 10/4/22 0:21 MFFg/L0.17 10/3/22SW-846 8260D1trans-1,2-Dichloroethylene
ND 1.0 10/4/22 0:21 MFFg/L0.18 10/3/22SW-846 8260D11,2-Dichloropropane
ND 0.50 10/4/22 0:21 MFFg/L0.13 10/3/22SW-846 8260D11,3-Dichloropropane
ND 1.0 10/4/22 0:21 MFFg/L0.33 10/3/22SW-846 8260D12,2-Dichloropropane
ND 2.0 10/4/22 0:21 MFFg/L0.15 10/3/22SW-846 8260D11,1-Dichloropropene
ND 0.50 10/4/22 0:21 MFFg/L0.16 10/3/22SW-846 8260D1cis-1,3-Dichloropropene
ND 0.50 10/4/22 0:21 MFFg/L0.17 10/3/22SW-846 8260D1trans-1,3-Dichloropropene
ND 2.0 10/4/22 0:21 MFFg/L0.18 10/3/22SW-846 8260D1Diethyl Ether
Page 13 of 27
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Page 18 of 32
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 10/1/2022
Work Order: 22J0010Sample Description:Project Location: Crown Food Mart 9/29
Sample ID: 22J0010-05
Field Sample #: Duplicate
Sample Matrix: Water
Sampled: 9/29/2022 12:15
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Volatile Organic Compounds by GC/MS
ND 0.50 10/4/22 0:21 MFFg/L0.13 10/3/22SW-846 8260D1Diisopropyl Ether (DIPE)
ND 50 10/4/22 0:21 MFFg/L21 10/3/22SW-846 8260D11,4-Dioxane
ND 1.0 10/4/22 0:21 MFFg/L0.21 10/3/22SW-846 8260D1Ethylbenzene
ND 0.60 10/4/22 0:21 MFFg/L0.46 10/3/22SW-846 8260D1Hexachlorobutadiene
ND 10 10/4/22 0:21 MFFg/L1.1 10/3/22SW-846 8260D12-Hexanone (MBK)
ND 1.0 10/4/22 0:21 MFFg/L0.11 10/3/22SW-846 8260D1Isopropylbenzene (Cumene)
ND 1.0 10/4/22 0:21 MFFg/L0.097 10/3/22SW-846 8260D1p-Isopropyltoluene (p-Cymene)
ND 1.0 10/4/22 0:21 MFFg/L0.17 10/3/22SW-846 8260D1Methyl tert-Butyl Ether (MTBE)
ND 5.0 10/4/22 0:21 MFFg/L0.23 10/3/22SW-846 8260D1Methylene Chloride
ND 10 10/4/22 0:21 MFFg/L1.3 10/3/22SW-846 8260D14-Methyl-2-pentanone (MIBK)
ND 2.0 10/4/22 0:21 MFFg/L0.24 10/3/22SW-846 8260D1Naphthalene
ND 1.0 10/4/22 0:21 MFFg/L0.086 10/3/22SW-846 8260D1n-Propylbenzene
ND 1.0 10/4/22 0:21 MFFg/L0.11 10/3/22SW-846 8260D1Styrene
ND 1.0 10/4/22 0:21 MFFg/L0.18 10/3/22SW-846 8260D11,1,1,2-Tetrachloroethane
ND 0.50 10/4/22 0:21 MFFg/L0.13 10/3/22SW-846 8260D11,1,2,2-Tetrachloroethane
ND 1.0 10/4/22 0:21 MFFg/L0.19 10/3/22SW-846 8260D1Tetrachloroethylene
ND 10 10/4/22 0:21 MFFg/L0.49 10/3/22SW-846 8260D1Tetrahydrofuran
ND 1.0 10/4/22 0:21 MFFg/L0.22 10/3/22SW-846 8260D1Toluene
ND 5.0 10/4/22 0:21 MFFg/L0.30 10/3/22SW-846 8260D11,2,3-Trichlorobenzene
ND 1.0 10/4/22 0:21 MFFg/L0.25 10/3/22SW-846 8260D11,2,4-Trichlorobenzene
ND 1.0 10/4/22 0:21 MFFg/L0.21 10/3/22SW-846 8260D11,3,5-Trichlorobenzene
ND 1.0 10/4/22 0:21 MFFg/L0.17 10/3/22SW-846 8260D11,1,1-Trichloroethane
ND 1.0 10/4/22 0:21 MFFg/L0.18 10/3/22SW-846 8260D11,1,2-Trichloroethane
ND 1.0 10/4/22 0:21 MFFg/L0.19 10/3/22SW-846 8260D1Trichloroethylene
ND 2.0 10/4/22 0:21 MFFg/L0.18 10/3/22SW-846 8260D1Trichlorofluoromethane (Freon 11)
ND 2.0 10/4/22 0:21 MFFg/L0.28 10/3/22SW-846 8260D11,2,3-Trichloropropane
ND 1.0 10/4/22 0:21 MFFg/L0.23 10/3/22SW-846 8260D11,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
0.55 1.0 10/4/22 0:21 MFFg/L0.20 10/3/22SW-846 8260D1J1,2,4-Trimethylbenzene
0.15 1.0 10/4/22 0:21 MFFg/L0.11 10/3/22SW-846 8260D1J1,3,5-Trimethylbenzene
ND 2.0 10/4/22 0:21 MFFg/L0.21 10/3/22SW-846 8260D1Vinyl Chloride
ND 2.0 10/4/22 0:21 MFFg/L0.46 10/3/22SW-846 8260D1m+p Xylene
ND 1.0 10/4/22 0:21 MFFg/L0.23 10/3/22SW-846 8260D1o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 101 10/4/22 0:2170-130
Toluene-d8 102 10/4/22 0:2170-130
4-Bromofluorobenzene 97.9 10/4/22 0:2170-130
Page 14 of 27
Table of Contents
Page 19 of 32
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Sample Extraction Data
Prep Method: SW-846 5030B Analytical Method: SW-846 8260D
Lab Number [Field ID]Batch DateInitial [mL]Final [mL]
B318677 10/03/225 5.0022J0010-01 [SW 01 183]
B318677 10/03/225 5.0022J0010-02 [SW 02 183]
B318677 10/03/225 5.0022J0010-03 [SW 03 183]
B318677 10/03/225 5.0022J0010-04 [SW 04 183]
B318677 10/03/225 5.0022J0010-05 [Duplicate]
[TOC_1]Sample Preparation Information[TOC]
Page 15 of 27
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Page 20 of 32
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
[TOC_2]Volatile Organic Compounds by GC/MS[TOC]
Batch B318677 - SW-846 5030B
[TOC_3]B318677[TOC]
Blank (B318677-BLK1) Prepared & Analyzed: 10/03/22
Acetone g/L50ND
Acrylonitrile g/L5.0ND
tert-Amyl Methyl Ether (TAME)g/L0.50ND
Benzene g/L1.0ND
Bromobenzene g/L1.0ND
Bromochloromethane g/L1.0ND
Bromodichloromethane g/L0.50ND
Bromoform g/L1.0ND
Bromomethane g/L2.0ND
2-Butanone (MEK)g/L20ND
tert-Butyl Alcohol (TBA)g/L20ND
n-Butylbenzene g/L1.0ND
sec-Butylbenzene g/L1.0ND
tert-Butylbenzene g/L1.0ND
tert-Butyl Ethyl Ether (TBEE)g/L0.50ND
Carbon Disulfide g/L5.0ND
Carbon Tetrachloride g/L1.0ND
Chlorobenzene g/L1.0ND
Chlorodibromomethane g/L0.50ND
Chloroethane g/L2.0ND
Chloroform g/L2.0ND
Chloromethane g/L2.0ND
2-Chlorotoluene g/L1.0ND
4-Chlorotoluene g/L1.0ND
1,2-Dibromo-3-chloropropane (DBCP)g/L5.0ND
1,2-Dibromoethane (EDB)g/L0.50ND
Dibromomethane g/L1.0ND
1,2-Dichlorobenzene g/L1.0ND
1,3-Dichlorobenzene g/L1.0ND
1,4-Dichlorobenzene g/L1.0ND
trans-1,4-Dichloro-2-butene g/L2.0 V-05ND
Dichlorodifluoromethane (Freon 12)g/L2.0ND
1,1-Dichloroethane g/L1.0ND
1,2-Dichloroethane g/L1.0ND
1,1-Dichloroethylene g/L1.0ND
cis-1,2-Dichloroethylene g/L1.0ND
trans-1,2-Dichloroethylene g/L1.0ND
1,2-Dichloropropane g/L1.0ND
1,3-Dichloropropane g/L0.50ND
2,2-Dichloropropane g/L1.0ND
1,1-Dichloropropene g/L2.0ND
cis-1,3-Dichloropropene g/L0.50ND
trans-1,3-Dichloropropene g/L0.50ND
Diethyl Ether g/L2.0ND
Diisopropyl Ether (DIPE)g/L0.50ND
1,4-Dioxane g/L50ND
Ethylbenzene g/L1.0ND
Hexachlorobutadiene g/L0.60ND
2-Hexanone (MBK)g/L10ND
Isopropylbenzene (Cumene)g/L1.0ND
p-Isopropyltoluene (p-Cymene)g/L1.0ND
Methyl tert-Butyl Ether (MTBE)g/L1.0ND
[TOC_1]QC Data[TOC]
Page 16 of 27
Table of Contents
Page 21 of 32
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B318677 - SW-846 5030B
Blank (B318677-BLK1) Prepared & Analyzed: 10/03/22
Methylene Chloride g/L5.0ND
4-Methyl-2-pentanone (MIBK)g/L10ND
Naphthalene g/L2.0ND
n-Propylbenzene g/L1.0ND
Styrene g/L1.0ND
1,1,1,2-Tetrachloroethane g/L1.0ND
1,1,2,2-Tetrachloroethane g/L0.50ND
Tetrachloroethylene g/L1.0ND
Tetrahydrofuran g/L10ND
Toluene g/L1.0ND
1,2,3-Trichlorobenzene g/L5.0ND
1,2,4-Trichlorobenzene g/L1.0ND
1,3,5-Trichlorobenzene g/L1.0ND
1,1,1-Trichloroethane g/L1.0ND
1,1,2-Trichloroethane g/L1.0ND
Trichloroethylene g/L1.0ND
Trichlorofluoromethane (Freon 11)g/L2.0ND
1,2,3-Trichloropropane g/L2.0ND
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon
113)
g/L1.0ND
1,2,4-Trimethylbenzene g/L1.0ND
1,3,5-Trimethylbenzene g/L1.0ND
Vinyl Chloride g/L2.0ND
m+p Xylene g/L2.0ND
o-Xylene g/L1.0ND
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 10225.4
g/L 25.0 70-130Surrogate: Toluene-d8 10125.2
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 97.524.4
LCS (B318677-BS1) Prepared & Analyzed: 10/03/22
Acetone g/L50 100 70-160117117
Acrylonitrile g/L5.0 10.0 70-13010410.4
tert-Amyl Methyl Ether (TAME)g/L0.50 10.0 70-13011011.0
Benzene g/L1.0 10.0 70-13011411.4
Bromobenzene g/L1.0 10.0 70-13010310.3
Bromochloromethane g/L1.0 10.0 70-13012012.0
Bromodichloromethane g/L0.50 10.0 70-13010610.6
Bromoform g/L1.0 10.0 70-13095.79.57
Bromomethane g/L2.0 10.0 40-16010610.6
2-Butanone (MEK)g/L20 100 40-160115115
tert-Butyl Alcohol (TBA)g/L20 100 40-160107107
n-Butylbenzene g/L1.0 10.0 70-13098.99.89
sec-Butylbenzene g/L1.0 10.0 70-13099.79.97
tert-Butylbenzene g/L1.0 10.0 70-13010110.1
tert-Butyl Ethyl Ether (TBEE)g/L0.50 10.0 70-13011011.0
Carbon Disulfide g/L5.0 100 70-130122122
Carbon Tetrachloride g/L1.0 10.0 70-13010810.8
Chlorobenzene g/L1.0 10.0 70-13010610.6
Chlorodibromomethane g/L0.50 10.0 70-13010110.1
Chloroethane g/L2.0 10.0 V-2070-13012712.7
Chloroform g/L2.0 10.0 70-13010910.9
Chloromethane g/L2.0 10.0 40-16010410.4
2-Chlorotoluene g/L1.0 10.0 70-13010410.4
Page 17 of 27
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Page 22 of 32
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B318677 - SW-846 5030B
LCS (B318677-BS1) Prepared & Analyzed: 10/03/22
4-Chlorotoluene g/L1.0 10.0 70-13010610.6
1,2-Dibromo-3-chloropropane (DBCP)g/L5.0 10.0 70-13090.39.03
1,2-Dibromoethane (EDB)g/L0.50 10.0 70-13010810.8
Dibromomethane g/L1.0 10.0 70-13011211.2
1,2-Dichlorobenzene g/L1.0 10.0 70-13010110.1
1,3-Dichlorobenzene g/L1.0 10.0 70-13099.79.97
1,4-Dichlorobenzene g/L1.0 10.0 70-13010210.2
trans-1,4-Dichloro-2-butene g/L2.0 10.0 V-0570-13081.48.14
Dichlorodifluoromethane (Freon 12)g/L2.0 10.0 40-16011611.6
1,1-Dichloroethane g/L1.0 10.0 70-13011611.6
1,2-Dichloroethane g/L1.0 10.0 70-13010610.6
1,1-Dichloroethylene g/L1.0 10.0 70-13012112.1
cis-1,2-Dichloroethylene g/L1.0 10.0 70-13011411.4
trans-1,2-Dichloroethylene g/L1.0 10.0 70-13011411.4
1,2-Dichloropropane g/L1.0 10.0 70-13011111.1
1,3-Dichloropropane g/L0.50 10.0 70-13011411.4
2,2-Dichloropropane g/L1.0 10.0 40-13010110.1
1,1-Dichloropropene g/L2.0 10.0 70-13011511.5
cis-1,3-Dichloropropene g/L0.50 10.0 70-13010510.5
trans-1,3-Dichloropropene g/L0.50 10.0 70-13010610.6
Diethyl Ether g/L2.0 10.0 70-13011611.6
Diisopropyl Ether (DIPE)g/L0.50 10.0 70-13011211.2
1,4-Dioxane g/L50 100 40-13092.692.6
Ethylbenzene g/L1.0 10.0 70-13010710.7
Hexachlorobutadiene g/L0.60 10.0 70-13086.88.68
2-Hexanone (MBK)g/L10 100 70-160107107
Isopropylbenzene (Cumene)g/L1.0 10.0 70-13010410.4
p-Isopropyltoluene (p-Cymene)g/L1.0 10.0 70-13010010.0
Methyl tert-Butyl Ether (MTBE)g/L1.0 10.0 70-13010710.7
Methylene Chloride g/L5.0 10.0 70-13011111.1
4-Methyl-2-pentanone (MIBK)g/L10 100 70-160108108
Naphthalene g/L2.0 10.0 40-13097.79.77
n-Propylbenzene g/L1.0 10.0 70-13010510.5
Styrene g/L1.0 10.0 70-13010810.8
1,1,1,2-Tetrachloroethane g/L1.0 10.0 70-13010210.2
1,1,2,2-Tetrachloroethane g/L0.50 10.0 70-13010310.3
Tetrachloroethylene g/L1.0 10.0 70-13011311.3
Tetrahydrofuran g/L10 10.0 70-13010310.3
Toluene g/L1.0 10.0 70-13011211.2
1,2,3-Trichlorobenzene g/L5.0 10.0 70-13096.39.63
1,2,4-Trichlorobenzene g/L1.0 10.0 70-13096.79.67
1,3,5-Trichlorobenzene g/L1.0 10.0 70-13096.39.63
1,1,1-Trichloroethane g/L1.0 10.0 70-13011211.2
1,1,2-Trichloroethane g/L1.0 10.0 70-13010910.9
Trichloroethylene g/L1.0 10.0 70-13011611.6
Trichlorofluoromethane (Freon 11)g/L2.0 10.0 V-2070-13012012.0
1,2,3-Trichloropropane g/L2.0 10.0 70-13010710.7
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon
113)
g/L1.0 10.0 70-13012412.4
1,2,4-Trimethylbenzene g/L1.0 10.0 70-13010210.2
1,3,5-Trimethylbenzene g/L1.0 10.0 70-13010510.5
Vinyl Chloride g/L2.0 10.0 40-16012212.2
Page 18 of 27
Table of Contents
Page 23 of 32
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B318677 - SW-846 5030B
LCS (B318677-BS1) Prepared & Analyzed: 10/03/22
m+p Xylene g/L2.0 20.0 70-13010621.1
o-Xylene g/L1.0 10.0 70-13010410.4
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 99.624.9
g/L 25.0 70-130Surrogate: Toluene-d8 10325.9
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 99.825.0
LCS Dup (B318677-BSD1) Prepared & Analyzed: 10/03/22
Acetone g/L50 100 2570-160123 4.79123
Acrylonitrile g/L5.0 10.0 2570-130106 1.3310.6
tert-Amyl Methyl Ether (TAME)g/L0.50 10.0 2570-130109 0.82010.9
Benzene g/L1.0 10.0 2570-130113 0.96711.3
Bromobenzene g/L1.0 10.0 2570-13099.3 3.569.93
Bromochloromethane g/L1.0 10.0 2570-130117 1.8611.7
Bromodichloromethane g/L0.50 10.0 2570-130102 4.6210.2
Bromoform g/L1.0 10.0 2570-13093.7 2.119.37
Bromomethane g/L2.0 10.0 2540-160103 2.9610.3
2-Butanone (MEK)g/L20 100 2540-160116 0.518116
tert-Butyl Alcohol (TBA)g/L20 100 2540-160112 4.24112
n-Butylbenzene g/L1.0 10.0 2570-13097.5 1.439.75
sec-Butylbenzene g/L1.0 10.0 2570-130100 0.60010.0
tert-Butylbenzene g/L1.0 10.0 2570-13098.9 1.709.89
tert-Butyl Ethyl Ether (TBEE)g/L0.50 10.0 2570-130108 1.4710.8
Carbon Disulfide g/L5.0 100 2570-130121 0.914121
Carbon Tetrachloride g/L1.0 10.0 2570-130108 0.27910.8
Chlorobenzene g/L1.0 10.0 2570-130103 2.1110.3
Chlorodibromomethane g/L0.50 10.0 2570-13099.6 1.699.96
Chloroethane g/L2.0 10.0 25 V-2070-130125 1.8212.5
Chloroform g/L2.0 10.0 2570-130108 0.55410.8
Chloromethane g/L2.0 10.0 2540-160102 1.3610.2
2-Chlorotoluene g/L1.0 10.0 2570-130100 3.5410.0
4-Chlorotoluene g/L1.0 10.0 2570-130102 3.4610.2
1,2-Dibromo-3-chloropropane (DBCP)g/L5.0 10.0 2570-13095.0 5.079.50
1,2-Dibromoethane (EDB)g/L0.50 10.0 2570-130108 0.18510.8
Dibromomethane g/L1.0 10.0 2570-130110 2.3411.0
1,2-Dichlorobenzene g/L1.0 10.0 2570-13099.3 2.099.93
1,3-Dichlorobenzene g/L1.0 10.0 2570-13098.0 1.729.80
1,4-Dichlorobenzene g/L1.0 10.0 2570-13099.1 2.499.91
trans-1,4-Dichloro-2-butene g/L2.0 10.0 25 V-0570-13078.9 3.127.89
Dichlorodifluoromethane (Freon 12)g/L2.0 10.0 2540-160113 2.7011.3
1,1-Dichloroethane g/L1.0 10.0 2570-130114 2.0011.4
1,2-Dichloroethane g/L1.0 10.0 2570-130106 0.28310.6
1,1-Dichloroethylene g/L1.0 10.0 2570-130114 5.7111.4
cis-1,2-Dichloroethylene g/L1.0 10.0 2570-130113 1.2311.3
trans-1,2-Dichloroethylene g/L1.0 10.0 2570-130115 0.087311.5
1,2-Dichloropropane g/L1.0 10.0 2570-130108 2.4610.8
1,3-Dichloropropane g/L0.50 10.0 2570-130110 3.4811.0
2,2-Dichloropropane g/L1.0 10.0 2540-13099.9 1.109.99
1,1-Dichloropropene g/L2.0 10.0 2570-130110 4.1711.0
cis-1,3-Dichloropropene g/L0.50 10.0 2570-13099.2 5.979.92
trans-1,3-Dichloropropene g/L0.50 10.0 2570-13099.5 6.049.95
Diethyl Ether g/L2.0 10.0 2570-130114 1.6511.4
Diisopropyl Ether (DIPE)g/L0.50 10.0 2570-130111 0.44911.1
Page 19 of 27
Table of Contents
Page 24 of 32
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B318677 - SW-846 5030B
LCS Dup (B318677-BSD1) Prepared & Analyzed: 10/03/22
1,4-Dioxane g/L50 100 5040-13095.7 3.3795.7
Ethylbenzene g/L1.0 10.0 2570-130104 3.5110.4
Hexachlorobutadiene g/L0.60 10.0 2570-13086.0 0.9268.60
2-Hexanone (MBK)g/L10 100 2570-160107 0.364107
Isopropylbenzene (Cumene)g/L1.0 10.0 2570-130102 2.4210.2
p-Isopropyltoluene (p-Cymene)g/L1.0 10.0 2570-13096.9 3.259.69
Methyl tert-Butyl Ether (MTBE)g/L1.0 10.0 2570-130110 2.3011.0
Methylene Chloride g/L5.0 10.0 2570-130112 1.1711.2
4-Methyl-2-pentanone (MIBK)g/L10 100 2570-160107 1.01107
Naphthalene g/L2.0 10.0 2540-13097.3 0.4109.73
n-Propylbenzene g/L1.0 10.0 2570-130102 2.8110.2
Styrene g/L1.0 10.0 2570-130104 3.7810.4
1,1,1,2-Tetrachloroethane g/L1.0 10.0 2570-13099.7 2.389.97
1,1,2,2-Tetrachloroethane g/L0.50 10.0 2570-130102 0.97610.2
Tetrachloroethylene g/L1.0 10.0 2570-130110 2.7911.0
Tetrahydrofuran g/L10 10.0 2570-130109 4.9110.9
Toluene g/L1.0 10.0 2570-130107 4.7610.7
1,2,3-Trichlorobenzene g/L5.0 10.0 2570-13097.2 0.9309.72
1,2,4-Trichlorobenzene g/L1.0 10.0 2570-13095.4 1.359.54
1,3,5-Trichlorobenzene g/L1.0 10.0 2570-13095.1 1.259.51
1,1,1-Trichloroethane g/L1.0 10.0 2570-130111 1.1611.1
1,1,2-Trichloroethane g/L1.0 10.0 2570-130105 4.0210.5
Trichloroethylene g/L1.0 10.0 2570-130110 5.6511.0
Trichlorofluoromethane (Freon 11)g/L2.0 10.0 25 V-2070-130113 5.8511.3
1,2,3-Trichloropropane g/L2.0 10.0 2570-130103 3.6210.3
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon
113)
g/L1.0 10.0 2570-130122 2.1212.2
1,2,4-Trimethylbenzene g/L1.0 10.0 2570-13098.8 3.589.88
1,3,5-Trimethylbenzene g/L1.0 10.0 2570-130101 4.1810.1
Vinyl Chloride g/L2.0 10.0 2540-160118 4.0011.8
m+p Xylene g/L2.0 20.0 2570-130102 3.5220.4
o-Xylene g/L1.0 10.0 2570-130102 2.0410.2
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 10125.3
g/L 25.0 70-130Surrogate: Toluene-d8 10225.5
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 98.224.6
Page 20 of 27
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Page 25 of 32
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
FLAG/QUALIFIER SUMMARY
*QC result is outside of established limits.
Wide recovery limits established for difficult compound.
Wide RPD limits established for difficult compound.
#Data exceeded client recommended or regulatory level
Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the
calculation which have not been rounded.
No results have been blank subtracted unless specified in the case narrative section.
RL Reporting Limit is at the level of quantitation (LOQ)
DL Detection Limit is the lower limit of detection determined by the MDL study
MCL Maximum Contaminant Level
ND Not Detected
Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated
concentration (CLP J-Flag).
J
Continuing calibration verification (CCV) did not meet method specifications and was biased on the low side for
this compound.
V-05
Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side.
Data validation is not affected since sample result was "not detected" for this compound.
V-20
[TOC_1]Flag/Qualifier Summary[TOC]
Page 21 of 27
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Page 26 of 32
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
SW-846 8260D in Water
NCAcetone
NCAcrylonitrile
NCtert-Amyl Methyl Ether (TAME)
NCBenzene
NCBromobenzene
NCBromochloromethane
NCBromodichloromethane
NCBromoform
NCBromomethane
NC2-Butanone (MEK)
NCtert-Butyl Alcohol (TBA)
NCn-Butylbenzene
NCsec-Butylbenzene
NCtert-Butylbenzene
NCtert-Butyl Ethyl Ether (TBEE)
NCCarbon Disulfide
NCCarbon Tetrachloride
NCChlorobenzene
NCChlorodibromomethane
NCChloroethane
NCChloroform
NCChloromethane
NC2-Chlorotoluene
NC4-Chlorotoluene
NC1,2-Dibromo-3-chloropropane (DBCP)
NC1,2-Dibromoethane (EDB)
NCDibromomethane
NC1,2-Dichlorobenzene
NC1,3-Dichlorobenzene
NC1,4-Dichlorobenzene
NCtrans-1,4-Dichloro-2-butene
NCDichlorodifluoromethane (Freon 12)
NC1,1-Dichloroethane
NC1,2-Dichloroethane
NC1,1-Dichloroethylene
NCcis-1,2-Dichloroethylene
NCtrans-1,2-Dichloroethylene
NC1,2-Dichloropropane
NC1,3-Dichloropropane
NC2,2-Dichloropropane
NC1,1-Dichloropropene
NCcis-1,3-Dichloropropene
NCtrans-1,3-Dichloropropene
NCDiethyl Ether
NCDiisopropyl Ether (DIPE)
NC1,4-Dioxane
NCEthylbenzene
[TOC_1]Certifications[TOC]
Page 22 of 27
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Page 27 of 32
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
SW-846 8260D in Water
NCHexachlorobutadiene
NC2-Hexanone (MBK)
NCIsopropylbenzene (Cumene)
NCp-Isopropyltoluene (p-Cymene)
NCMethyl tert-Butyl Ether (MTBE)
NCMethylene Chloride
NC4-Methyl-2-pentanone (MIBK)
NCNaphthalene
NCn-Propylbenzene
NCStyrene
NC1,1,1,2-Tetrachloroethane
NC1,1,2,2-Tetrachloroethane
NCTetrachloroethylene
NCTetrahydrofuran
NCToluene
NC1,2,3-Trichlorobenzene
NC1,2,4-Trichlorobenzene
NC1,3,5-Trichlorobenzene
NC1,1,1-Trichloroethane
NC1,1,2-Trichloroethane
NCTrichloroethylene
NCTrichlorofluoromethane (Freon 11)
NC1,2,3-Trichloropropane
NC1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)
NC1,2,4-Trimethylbenzene
NC1,3,5-Trimethylbenzene
NCVinyl Chloride
NCm+p Xylene
NCo-Xylene
Page 23 of 27
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Page 28 of 32
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Con-Test, a Pace Environmental Laboratory, operates under the following certifications and accreditations:
Code Description Number Expires
100033AIHA-LAP, LLC - ISO 17025:2017AIHA 03/1/2024
M-MA100Massachusetts DEPMA 06/30/2023
PH-0165Connecticut Department of Public HealthCT 12/31/2022
10899 NELAPNew York State Department of HealthNY 04/1/2023
2516 NELAPNew Hampshire Environmental LabNH 02/5/2023
LAO00373Rhode Island Department of HealthRI 12/30/2022
652North Carolina Div. of Water QualityNC 12/31/2022
MA007 NELAPNew Jersey DEPNJ 06/30/2023
E871027 NELAPFlorida Department of HealthFL 06/30/2023
LL720741Vermont Department of Health Lead LaboratoryVT 07/30/2023
VT-255716Vermont Department of Health Drinking WaterVT-DW 06/12/2023
MA00100State of MaineME 06/9/2023
460217Commonwealth of VirginiaVA 12/14/2022
2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2023
25703North Carolina Department of Health and Human ServicesNC-DW 07/31/2023
68-05812Commonwealth of Pennsylvania DEPPA 06/30/2023
9100Dept. of Env, Great Lakes, and EnergyMI 06/30/2023
PH-0554Connecticut Department of Public HealthNB-CT 09/30/2023
NY015 NELAPNew Jersey DEPNB-NJ 06/30/2023
10142 NELAPNew York State Department of HealthNB-NY 04/1/2023
Page 24 of 27
Table of Contents
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#=CL#
October 21, 2022
LIMS USE: FR - ROBERT MARTIN
LIMS OBJECT ID: 92630913
92630913
Project:
Pace Project No.:
RE:
Mr. Robert Martin
Martin and Slagle
24 Lookout Terrace
Black Mountain, NC 28711
Crown Food Mart 10/12
Dear Mr. Martin:
Enclosed are the analytical results for sample(s) received by the laboratory on October 13, 2022. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lorri Patton
[e-mail]
Project Manager
1(828)254-7176
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 1 of 38
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 2 of 38
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Lab ID Sample ID Matrix Date Collected Date Received
92630913001 EF-14 Water 10/12/22 11:34 10/13/22 10:30
92630913002 INF-14 Water 10/12/22 11:42 10/13/22 10:30
92630913003 EW-2 Water 10/12/22 12:01 10/13/22 10:30
92630913004 EW-3 Water 10/12/22 12:16 10/13/22 10:30
92630913005 EW-4 Water 10/12/22 12:34 10/13/22 10:30
92630913006 EW-5 Water 10/12/22 12:51 10/13/22 10:30
92630913007 DUP (VOC)Water 10/12/22 00:00 10/13/22 10:30
92630913008 DUP (Fe)Water 10/12/22 00:00 10/13/22 10:30
92630913009 POTW-INF-14 Water 10/12/22 13:07 10/13/22 10:30
92630913010 POTW-EF-14 Water 10/12/22 13:19 10/13/22 10:30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 3 of 38
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92630913001 EF-14 EPA 200.7 Rev 4.4 1994 1 PASI-ADEC
SM 6200B 63 PASI-CSAS
SM 2540D-2015 1 PASI-ACS1
92630913002 INF-14 EPA 200.7 Rev 4.4 1994 1 PASI-ADEC
SM 6200B 63 PASI-CSAS
SM 2540D-2015 1 PASI-ACS1
92630913003 EW-2 EPA 200.7 Rev 4.4 1994 1 PASI-ADEC
SM 6200B 63 PASI-CSAS
92630913004 EW-3 EPA 200.7 Rev 4.4 1994 1 PASI-ADEC
SM 6200B 63 PASI-CSAS
92630913005 EW-4 EPA 200.7 Rev 4.4 1994 1 PASI-ADEC
SM 6200B 63 PASI-CSAS
92630913006 EW-5 EPA 200.7 Rev 4.4 1994 1 PASI-ADEC
SM 6200B 63 PASI-CSAS
92630913007 DUP (VOC)SM 6200B 63 PASI-CSAS
92630913008 DUP (Fe)EPA 200.7 Rev 4.4 1994 1 PASI-ADEC
92630913009 POTW-INF-14 SM 6200B 63 PASI-CSAS
SM 2540D-2015 1 PASI-AJMH1
92630913010 POTW-EF-14 SM 6200B 63 PASI-CSAS
SM 2540D-2015 1 PASI-AJMH1
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 4 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Sample:EF-14 Lab ID:92630913001 Collected:10/12/22 11:34 Received:10/13/22 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Iron 16300 ug/L 10/19/22 16:21 7439-89-610/18/22 15:4850.0 41.5 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene 1.3 ug/L 10/17/22 19:02 71-43-20.50 0.34 1
Bromobenzene ND ug/L 10/17/22 19:02 108-86-10.50 0.29 1
Bromochloromethane ND ug/L 10/17/22 19:02 74-97-50.50 0.47 1
Bromodichloromethane ND ug/L 10/17/22 19:02 75-27-40.50 0.31 1
Bromoform ND ug/L 10/17/22 19:02 75-25-20.50 0.34 1
Bromomethane ND ug/L 10/17/22 19:02 74-83-95.0 1.7 1
n-Butylbenzene ND ug/L 10/17/22 19:02 104-51-80.50 0.49 1
sec-Butylbenzene ND ug/L 10/17/22 19:02 135-98-80.50 0.40 1
tert-Butylbenzene ND ug/L 10/17/22 19:02 98-06-60.50 0.32 1
Carbon tetrachloride ND ug/L 10/17/22 19:02 56-23-50.50 0.33 1
Chlorobenzene ND ug/L 10/17/22 19:02 108-90-70.50 0.28 1
Chloroethane ND ug/L 10/17/22 19:02 75-00-31.0 0.65 1
Chloroform ND ug/L 10/17/22 19:02 67-66-30.50 0.43 1
Chloromethane ND ug/L 10/17/22 19:02 74-87-31.0 0.54 1
2-Chlorotoluene ND ug/L 10/17/22 19:02 95-49-80.50 0.32 1
4-Chlorotoluene ND ug/L 10/17/22 19:02 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane ND ug/L 10/17/22 19:02 96-12-81.0 0.34 1
Dibromochloromethane ND ug/L 10/17/22 19:02 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)ND ug/L 10/17/22 19:02 106-93-40.50 0.27 1
Dibromomethane ND ug/L 10/17/22 19:02 74-95-30.50 0.39 1
1,2-Dichlorobenzene ND ug/L 10/17/22 19:02 95-50-10.50 0.34 1
1,3-Dichlorobenzene ND ug/L 10/17/22 19:02 541-73-10.50 0.34 1
1,4-Dichlorobenzene ND ug/L 10/17/22 19:02 106-46-70.50 0.33 1
Dichlorodifluoromethane ND ug/L 10/17/22 19:02 75-71-80.50 0.35 1
1,1-Dichloroethane ND ug/L 10/17/22 19:02 75-34-30.50 0.37 1
1,2-Dichloroethane ND ug/L 10/17/22 19:02 107-06-20.50 0.32 1
1,1-Dichloroethene ND ug/L 10/17/22 19:02 75-35-40.50 0.35 1
cis-1,2-Dichloroethene ND ug/L 10/17/22 19:02 156-59-20.50 0.38 1
trans-1,2-Dichloroethene ND ug/L 10/17/22 19:02 156-60-50.50 0.40 1
1,2-Dichloropropane ND ug/L 10/17/22 19:02 78-87-50.50 0.36 1
1,3-Dichloropropane ND ug/L 10/17/22 19:02 142-28-90.50 0.28 1
2,2-Dichloropropane ND ug/L 10/17/22 19:02 594-20-70.50 0.39 1
1,1-Dichloropropene ND ug/L 10/17/22 19:02 563-58-60.50 0.43 1
cis-1,3-Dichloropropene ND ug/L 10/17/22 19:02 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/17/22 19:02 10061-02-60.50 0.36 1
Diisopropyl ether 0.44J ug/L 10/17/22 19:02 108-20-30.50 0.31 1
Ethylbenzene 3.4 ug/L 10/17/22 19:02 100-41-40.50 0.30 1
Hexachloro-1,3-butadiene ND ug/L 10/17/22 19:02 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)1.2 ug/L 10/17/22 19:02 98-82-80.50 0.33 1
Methylene Chloride ND ug/L 10/17/22 19:02 75-09-22.0 2.0 1
Methyl-tert-butyl ether 0.43J ug/L 10/17/22 19:02 1634-04-40.50 0.42 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 5 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Sample:EF-14 Lab ID:92630913001 Collected:10/12/22 11:34 Received:10/13/22 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Naphthalene 6.2 ug/L 10/17/22 19:02 91-20-32.0 0.64 1
n-Propylbenzene 2.6 ug/L 10/17/22 19:02 103-65-10.50 0.34 1
Styrene ND ug/L 10/17/22 19:02 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 10/17/22 19:02 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 10/17/22 19:02 79-34-50.50 0.22 1
Tetrachloroethene ND ug/L 10/17/22 19:02 127-18-40.50 0.29 1
Toluene 0.44J ug/L 10/17/22 19:02 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene ND ug/L 10/17/22 19:02 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene ND ug/L 10/17/22 19:02 120-82-12.0 0.64 1
1,1,1-Trichloroethane ND ug/L 10/17/22 19:02 71-55-60.50 0.33 1
1,1,2-Trichloroethane ND ug/L 10/17/22 19:02 79-00-50.50 0.32 1
Trichloroethene ND ug/L 10/17/22 19:02 79-01-60.50 0.38 1
Trichlorofluoromethane ND ug/L 10/17/22 19:02 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 10/17/22 19:02 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene 33.5 ug/L 10/17/22 19:02 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene 8.3 ug/L 10/17/22 19:02 108-67-80.50 0.33 1
Vinyl chloride ND ug/L 10/17/22 19:02 75-01-41.0 0.39 1
m&p-Xylene 8.9 ug/L 10/17/22 19:02 179601-23-11.0 0.71 1
o-Xylene 2.2 ug/L 10/17/22 19:02 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)99 %10/17/22 19:02 17060-07-070-130 1
4-Bromofluorobenzene (S)95 %10/17/22 19:02 460-00-470-130 1
Toluene-d8 (S)108 %10/17/22 19:02 2037-26-570-130 1
Analytical Method: SM 2540D-2015
Pace Analytical Services - Asheville
2540D Total Suspended Solids
Total Suspended Solids ND mg/L 10/14/22 13:362.5 2.5 1
Sample:INF-14 Lab ID:92630913002 Collected:10/12/22 11:42 Received:10/13/22 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Iron 28200 ug/L 10/19/22 16:32 7439-89-610/18/22 15:4850.0 41.5 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene 13.4 ug/L 10/21/22 05:35 71-43-21.0 0.69 2
Bromobenzene ND ug/L 10/21/22 05:35 108-86-11.0 0.58 2
Bromochloromethane ND ug/L 10/21/22 05:35 74-97-51.0 0.94 2
Bromodichloromethane ND ug/L 10/21/22 05:35 75-27-41.0 0.61 2
Bromoform ND ug/L 10/21/22 05:35 75-25-21.0 0.68 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 6 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Sample:INF-14 Lab ID:92630913002 Collected:10/12/22 11:42 Received:10/13/22 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Bromomethane ND ug/L 10/21/22 05:35 74-83-910.0 3.3 2
n-Butylbenzene 10 ug/L 10/21/22 05:35 104-51-81.0 0.98 2
sec-Butylbenzene ND ug/L 10/21/22 05:35 135-98-81.0 0.80 2
tert-Butylbenzene ND ug/L 10/21/22 05:35 98-06-61.0 0.65 2
Carbon tetrachloride ND ug/L 10/21/22 05:35 56-23-51.0 0.67 2
Chlorobenzene ND ug/L 10/21/22 05:35 108-90-71.0 0.57 2
Chloroethane ND ug/L 10/21/22 05:35 75-00-32.0 1.3 2
Chloroform ND ug/L 10/21/22 05:35 67-66-31.0 0.86 2
Chloromethane ND ug/L 10/21/22 05:35 74-87-32.0 1.1 2
2-Chlorotoluene ND ug/L 10/21/22 05:35 95-49-81.0 0.64 2
4-Chlorotoluene ND ug/L 10/21/22 05:35 106-43-41.0 0.65 2
1,2-Dibromo-3-chloropropane ND ug/L 10/21/22 05:35 96-12-82.0 0.68 2
Dibromochloromethane ND ug/L 10/21/22 05:35 124-48-11.0 0.72 2
1,2-Dibromoethane (EDB)ND ug/L 10/21/22 05:35 106-93-41.0 0.54 2
Dibromomethane ND ug/L 10/21/22 05:35 74-95-31.0 0.79 2
1,2-Dichlorobenzene ND ug/L 10/21/22 05:35 95-50-11.0 0.68 2
1,3-Dichlorobenzene ND ug/L 10/21/22 05:35 541-73-11.0 0.68 2
1,4-Dichlorobenzene ND ug/L 10/21/22 05:35 106-46-71.0 0.67 2
Dichlorodifluoromethane ND ug/L 10/21/22 05:35 75-71-81.0 0.69 2
1,1-Dichloroethane ND ug/L 10/21/22 05:35 75-34-31.0 0.73 2
1,2-Dichloroethane ND ug/L 10/21/22 05:35 107-06-21.0 0.64 2
1,1-Dichloroethene ND ug/L 10/21/22 05:35 75-35-41.0 0.70 2
cis-1,2-Dichloroethene ND ug/L 10/21/22 05:35 156-59-21.0 0.77 2
trans-1,2-Dichloroethene ND ug/L 10/21/22 05:35 156-60-51.0 0.79 2
1,2-Dichloropropane ND ug/L 10/21/22 05:35 78-87-51.0 0.71 2
1,3-Dichloropropane ND ug/L 10/21/22 05:35 142-28-91.0 0.57 2
2,2-Dichloropropane ND ug/L 10/21/22 05:35 594-20-71.0 0.78 2
1,1-Dichloropropene ND ug/L 10/21/22 05:35 563-58-61.0 0.85 2
cis-1,3-Dichloropropene ND ug/L 10/21/22 05:35 10061-01-51.0 0.73 2
trans-1,3-Dichloropropene ND ug/L 10/21/22 05:35 10061-02-61.0 0.73 2
Diisopropyl ether 2.5 ug/L 10/21/22 05:35 108-20-31.0 0.62 2
Ethylbenzene 48.1 ug/L 10/21/22 05:35 100-41-41.0 0.61 2
Hexachloro-1,3-butadiene ND ug/L 10/21/22 05:35 87-68-34.0 3.1 2
Isopropylbenzene (Cumene)18.6 ug/L 10/21/22 05:35 98-82-81.0 0.67 2
Methylene Chloride ND ug/L 10/21/22 05:35 75-09-24.0 3.9 2
Methyl-tert-butyl ether 1.6 ug/L 10/21/22 05:35 1634-04-41.0 0.84 2
Naphthalene 19.7 ug/L 10/21/22 05:35 91-20-34.0 1.3 2
n-Propylbenzene 47.6 ug/L 10/21/22 05:35 103-65-11.0 0.68 2
Styrene ND ug/L 10/21/22 05:35 100-42-51.0 0.58 2
1,1,1,2-Tetrachloroethane ND ug/L 10/21/22 05:35 630-20-61.0 0.62 2
1,1,2,2-Tetrachloroethane ND ug/L 10/21/22 05:35 79-34-51.0 0.45 2
Tetrachloroethene ND ug/L 10/21/22 05:35 127-18-41.0 0.58 2
Toluene 2.9 ug/L 10/21/22 05:35 108-88-31.0 0.48 2
1,2,3-Trichlorobenzene ND ug/L 10/21/22 05:35 87-61-64.0 1.6 2
1,2,4-Trichlorobenzene ND ug/L 10/21/22 05:35 120-82-14.0 1.3 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 7 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Sample:INF-14 Lab ID:92630913002 Collected:10/12/22 11:42 Received:10/13/22 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1,1-Trichloroethane ND ug/L 10/21/22 05:35 71-55-61.0 0.66 2
1,1,2-Trichloroethane ND ug/L 10/21/22 05:35 79-00-51.0 0.65 2
Trichloroethene ND ug/L 10/21/22 05:35 79-01-61.0 0.77 2
Trichlorofluoromethane ND ug/L 10/21/22 05:35 75-69-42.0 0.60 2
1,2,3-Trichloropropane ND ug/L 10/21/22 05:35 96-18-41.0 0.52 2
1,2,4-Trimethylbenzene 350 ug/L 10/21/22 05:35 95-63-61.0 0.99 2
1,3,5-Trimethylbenzene 88.0 ug/L 10/21/22 05:35 108-67-81.0 0.66 2
Vinyl chloride ND ug/L 10/21/22 05:35 75-01-42.0 0.77 2
m&p-Xylene 89.8 ug/L 10/21/22 05:35 179601-23-12.0 1.4 2
o-Xylene 13.7 ug/L 10/21/22 05:35 95-47-61.0 0.68 2
Surrogates
1,2-Dichloroethane-d4 (S)95 %10/21/22 05:35 17060-07-070-130 2
4-Bromofluorobenzene (S)94 %10/21/22 05:35 460-00-470-130 2
Toluene-d8 (S)96 %10/21/22 05:35 2037-26-570-130 2
Analytical Method: SM 2540D-2015
Pace Analytical Services - Asheville
2540D Total Suspended Solids
Total Suspended Solids 5.8 mg/L 10/14/22 13:372.5 2.5 1
Sample:EW-2 Lab ID:92630913003 Collected:10/12/22 12:01 Received:10/13/22 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Iron 19500 ug/L 10/19/22 16:35 7439-89-610/18/22 15:4850.0 41.5 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene 3.7 ug/L 10/17/22 16:03 71-43-21.0 0.69 2
Bromobenzene ND ug/L 10/17/22 16:03 108-86-11.0 0.58 2
Bromochloromethane ND ug/L 10/17/22 16:03 74-97-51.0 0.94 2
Bromodichloromethane ND ug/L 10/17/22 16:03 75-27-41.0 0.61 2
Bromoform ND ug/L 10/17/22 16:03 75-25-21.0 0.68 2
Bromomethane ND ug/L 10/17/22 16:03 74-83-910.0 3.3 2
n-Butylbenzene ND ug/L 10/17/22 16:03 104-51-81.0 0.98 2
sec-Butylbenzene ND ug/L 10/17/22 16:03 135-98-81.0 0.80 2
tert-Butylbenzene ND ug/L 10/17/22 16:03 98-06-61.0 0.65 2
Carbon tetrachloride ND ug/L 10/17/22 16:03 56-23-51.0 0.67 2
Chlorobenzene ND ug/L 10/17/22 16:03 108-90-71.0 0.57 2
Chloroethane ND ug/L 10/17/22 16:03 75-00-32.0 1.3 2
Chloroform ND ug/L 10/17/22 16:03 67-66-31.0 0.86 2
Chloromethane ND ug/L 10/17/22 16:03 74-87-32.0 1.1 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 8 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Sample:EW-2 Lab ID:92630913003 Collected:10/12/22 12:01 Received:10/13/22 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
2-Chlorotoluene ND ug/L 10/17/22 16:03 95-49-81.0 0.64 2
4-Chlorotoluene ND ug/L 10/17/22 16:03 106-43-41.0 0.65 2
1,2-Dibromo-3-chloropropane ND ug/L 10/17/22 16:03 96-12-82.0 0.68 2
Dibromochloromethane ND ug/L 10/17/22 16:03 124-48-11.0 0.72 2
1,2-Dibromoethane (EDB)ND ug/L 10/17/22 16:03 106-93-41.0 0.54 2
Dibromomethane ND ug/L 10/17/22 16:03 74-95-31.0 0.79 2
1,2-Dichlorobenzene ND ug/L 10/17/22 16:03 95-50-11.0 0.68 2
1,3-Dichlorobenzene ND ug/L 10/17/22 16:03 541-73-11.0 0.68 2
1,4-Dichlorobenzene ND ug/L 10/17/22 16:03 106-46-71.0 0.67 2
Dichlorodifluoromethane ND ug/L 10/17/22 16:03 75-71-81.0 0.69 2
1,1-Dichloroethane ND ug/L 10/17/22 16:03 75-34-31.0 0.73 2
1,2-Dichloroethane ND ug/L 10/17/22 16:03 107-06-21.0 0.64 2
1,1-Dichloroethene ND ug/L 10/17/22 16:03 75-35-41.0 0.70 2
cis-1,2-Dichloroethene ND ug/L 10/17/22 16:03 156-59-21.0 0.77 2
trans-1,2-Dichloroethene ND ug/L 10/17/22 16:03 156-60-51.0 0.79 2
1,2-Dichloropropane ND ug/L 10/17/22 16:03 78-87-51.0 0.71 2
1,3-Dichloropropane ND ug/L 10/17/22 16:03 142-28-91.0 0.57 2
2,2-Dichloropropane ND ug/L 10/17/22 16:03 594-20-71.0 0.78 2
1,1-Dichloropropene ND ug/L 10/17/22 16:03 563-58-61.0 0.85 2
cis-1,3-Dichloropropene ND ug/L 10/17/22 16:03 10061-01-51.0 0.73 2
trans-1,3-Dichloropropene ND ug/L 10/17/22 16:03 10061-02-61.0 0.73 2
Diisopropyl ether ND ug/L 10/17/22 16:03 108-20-31.0 0.62 2
Ethylbenzene 29.3 ug/L 10/17/22 16:03 100-41-41.0 0.61 2
Hexachloro-1,3-butadiene ND ug/L 10/17/22 16:03 87-68-34.0 3.1 2
Isopropylbenzene (Cumene)11.6 ug/L 10/17/22 16:03 98-82-81.0 0.67 2
Methylene Chloride ND ug/L 10/17/22 16:03 75-09-24.0 3.9 2
Methyl-tert-butyl ether ND ug/L 10/17/22 16:03 1634-04-41.0 0.84 2
Naphthalene 10.3 ug/L 10/17/22 16:03 91-20-34.0 1.3 2
n-Propylbenzene 31.7 ug/L 10/17/22 16:03 103-65-11.0 0.68 2
Styrene ND ug/L 10/17/22 16:03 100-42-51.0 0.58 2
1,1,1,2-Tetrachloroethane ND ug/L 10/17/22 16:03 630-20-61.0 0.62 2
1,1,2,2-Tetrachloroethane ND ug/L 10/17/22 16:03 79-34-51.0 0.45 2
Tetrachloroethene ND ug/L 10/17/22 16:03 127-18-41.0 0.58 2
Toluene 4.5 ug/L 10/17/22 16:03 108-88-31.0 0.48 2
1,2,3-Trichlorobenzene ND ug/L 10/17/22 16:03 87-61-64.0 1.6 2
1,2,4-Trichlorobenzene ND ug/L 10/17/22 16:03 120-82-14.0 1.3 2
1,1,1-Trichloroethane ND ug/L 10/17/22 16:03 71-55-61.0 0.66 2
1,1,2-Trichloroethane ND ug/L 10/17/22 16:03 79-00-51.0 0.65 2
Trichloroethene ND ug/L 10/17/22 16:03 79-01-61.0 0.77 2
Trichlorofluoromethane ND ug/L 10/17/22 16:03 75-69-42.0 0.60 2
1,2,3-Trichloropropane ND ug/L 10/17/22 16:03 96-18-41.0 0.52 2
1,2,4-Trimethylbenzene 194 ug/L 10/17/22 16:03 95-63-61.0 0.99 2
1,3,5-Trimethylbenzene 36.9 ug/L 10/17/22 16:03 108-67-81.0 0.66 2
Vinyl chloride ND ug/L 10/17/22 16:03 75-01-42.0 0.77 2
m&p-Xylene 78.0 ug/L 10/17/22 16:03 179601-23-12.0 1.4 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 9 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Sample:EW-2 Lab ID:92630913003 Collected:10/12/22 12:01 Received:10/13/22 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
o-Xylene 16.7 ug/L 10/17/22 16:03 95-47-61.0 0.68 2
Surrogates
1,2-Dichloroethane-d4 (S)99 %10/17/22 16:03 17060-07-070-130 2
4-Bromofluorobenzene (S)101 %10/17/22 16:03 460-00-470-130 2
Toluene-d8 (S)101 %10/17/22 16:03 2037-26-570-130 2
Sample:EW-3 Lab ID:92630913004 Collected:10/12/22 12:16 Received:10/13/22 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Iron 1600 ug/L 10/19/22 16:46 7439-89-610/18/22 15:4850.0 41.5 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene 5.9 ug/L 10/17/22 19:20 71-43-20.50 0.34 1
Bromobenzene ND ug/L 10/17/22 19:20 108-86-10.50 0.29 1
Bromochloromethane ND ug/L 10/17/22 19:20 74-97-50.50 0.47 1
Bromodichloromethane ND ug/L 10/17/22 19:20 75-27-40.50 0.31 1
Bromoform ND ug/L 10/17/22 19:20 75-25-20.50 0.34 1
Bromomethane ND ug/L 10/17/22 19:20 74-83-95.0 1.7 1
n-Butylbenzene ND ug/L 10/17/22 19:20 104-51-80.50 0.49 1
sec-Butylbenzene ND ug/L 10/17/22 19:20 135-98-80.50 0.40 1
tert-Butylbenzene ND ug/L 10/17/22 19:20 98-06-60.50 0.32 1
Carbon tetrachloride ND ug/L 10/17/22 19:20 56-23-50.50 0.33 1
Chlorobenzene ND ug/L 10/17/22 19:20 108-90-70.50 0.28 1
Chloroethane ND ug/L 10/17/22 19:20 75-00-31.0 0.65 1
Chloroform ND ug/L 10/17/22 19:20 67-66-30.50 0.43 1
Chloromethane ND ug/L 10/17/22 19:20 74-87-31.0 0.54 1
2-Chlorotoluene ND ug/L 10/17/22 19:20 95-49-80.50 0.32 1
4-Chlorotoluene ND ug/L 10/17/22 19:20 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane ND ug/L 10/17/22 19:20 96-12-81.0 0.34 1
Dibromochloromethane ND ug/L 10/17/22 19:20 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)ND ug/L 10/17/22 19:20 106-93-40.50 0.27 1
Dibromomethane ND ug/L 10/17/22 19:20 74-95-30.50 0.39 1
1,2-Dichlorobenzene ND ug/L 10/17/22 19:20 95-50-10.50 0.34 1
1,3-Dichlorobenzene ND ug/L 10/17/22 19:20 541-73-10.50 0.34 1
1,4-Dichlorobenzene ND ug/L 10/17/22 19:20 106-46-70.50 0.33 1
Dichlorodifluoromethane ND ug/L 10/17/22 19:20 75-71-80.50 0.35 1
1,1-Dichloroethane ND ug/L 10/17/22 19:20 75-34-30.50 0.37 1
1,2-Dichloroethane ND ug/L 10/17/22 19:20 107-06-20.50 0.32 1
1,1-Dichloroethene ND ug/L 10/17/22 19:20 75-35-40.50 0.35 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 10 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Sample:EW-3 Lab ID:92630913004 Collected:10/12/22 12:16 Received:10/13/22 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
cis-1,2-Dichloroethene ND ug/L 10/17/22 19:20 156-59-20.50 0.38 1
trans-1,2-Dichloroethene ND ug/L 10/17/22 19:20 156-60-50.50 0.40 1
1,2-Dichloropropane ND ug/L 10/17/22 19:20 78-87-50.50 0.36 1
1,3-Dichloropropane ND ug/L 10/17/22 19:20 142-28-90.50 0.28 1
2,2-Dichloropropane ND ug/L 10/17/22 19:20 594-20-70.50 0.39 1
1,1-Dichloropropene ND ug/L 10/17/22 19:20 563-58-60.50 0.43 1
cis-1,3-Dichloropropene ND ug/L 10/17/22 19:20 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/17/22 19:20 10061-02-60.50 0.36 1
Diisopropyl ether 2.4 ug/L 10/17/22 19:20 108-20-30.50 0.31 1
Ethylbenzene 5.4 ug/L 10/17/22 19:20 100-41-40.50 0.30 1
Hexachloro-1,3-butadiene ND ug/L 10/17/22 19:20 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)4.2 ug/L 10/17/22 19:20 98-82-80.50 0.33 1
Methylene Chloride ND ug/L 10/17/22 19:20 75-09-22.0 2.0 1
Methyl-tert-butyl ether 1.1 ug/L 10/17/22 19:20 1634-04-40.50 0.42 1
Naphthalene 7.0 ug/L 10/17/22 19:20 91-20-32.0 0.64 1
n-Propylbenzene 6.3 ug/L 10/17/22 19:20 103-65-10.50 0.34 1
Styrene ND ug/L 10/17/22 19:20 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 10/17/22 19:20 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 10/17/22 19:20 79-34-50.50 0.22 1
Tetrachloroethene ND ug/L 10/17/22 19:20 127-18-40.50 0.29 1
Toluene 0.85 ug/L 10/17/22 19:20 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene ND ug/L 10/17/22 19:20 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene ND ug/L 10/17/22 19:20 120-82-12.0 0.64 1
1,1,1-Trichloroethane ND ug/L 10/17/22 19:20 71-55-60.50 0.33 1
1,1,2-Trichloroethane ND ug/L 10/17/22 19:20 79-00-50.50 0.32 1
Trichloroethene ND ug/L 10/17/22 19:20 79-01-60.50 0.38 1
Trichlorofluoromethane ND ug/L 10/17/22 19:20 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 10/17/22 19:20 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene 47.8 ug/L 10/17/22 19:20 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene 12.4 ug/L 10/17/22 19:20 108-67-80.50 0.33 1
Vinyl chloride ND ug/L 10/17/22 19:20 75-01-41.0 0.39 1
m&p-Xylene 19.9 ug/L 10/17/22 19:20 179601-23-11.0 0.71 1
o-Xylene 9.3 ug/L 10/17/22 19:20 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)93 %10/17/22 19:20 17060-07-070-130 1
4-Bromofluorobenzene (S)99 %10/17/22 19:20 460-00-470-130 1
Toluene-d8 (S)97 %10/17/22 19:20 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 11 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Sample:EW-4 Lab ID:92630913005 Collected:10/12/22 12:34 Received:10/13/22 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Iron 17800 ug/L 10/19/22 16:49 7439-89-610/18/22 15:4850.0 41.5 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene 21.2 ug/L 10/21/22 06:46 71-43-22.5 1.7 5
Bromobenzene ND ug/L 10/21/22 06:46 108-86-12.5 1.4 5
Bromochloromethane ND ug/L 10/21/22 06:46 74-97-52.5 2.3 5
Bromodichloromethane ND ug/L 10/21/22 06:46 75-27-42.5 1.5 5
Bromoform ND ug/L 10/21/22 06:46 75-25-22.5 1.7 5
Bromomethane ND ug/L 10/21/22 06:46 74-83-925.0 8.3 5
n-Butylbenzene ND ug/L 10/21/22 06:46 104-51-82.5 2.4 5
sec-Butylbenzene ND ug/L 10/21/22 06:46 135-98-82.5 2.0 5
tert-Butylbenzene ND ug/L 10/21/22 06:46 98-06-62.5 1.6 5
Carbon tetrachloride ND ug/L 10/21/22 06:46 56-23-52.5 1.7 5
Chlorobenzene ND ug/L 10/21/22 06:46 108-90-72.5 1.4 5
Chloroethane ND ug/L 10/21/22 06:46 75-00-35.0 3.2 5
Chloroform ND ug/L 10/21/22 06:46 67-66-32.5 2.2 5
Chloromethane ND ug/L 10/21/22 06:46 74-87-35.0 2.7 5
2-Chlorotoluene ND ug/L 10/21/22 06:46 95-49-82.5 1.6 5
4-Chlorotoluene ND ug/L 10/21/22 06:46 106-43-42.5 1.6 5
1,2-Dibromo-3-chloropropane ND ug/L 10/21/22 06:46 96-12-85.0 1.7 5
Dibromochloromethane ND ug/L 10/21/22 06:46 124-48-12.5 1.8 5
1,2-Dibromoethane (EDB)ND ug/L 10/21/22 06:46 106-93-42.5 1.4 5
Dibromomethane ND ug/L 10/21/22 06:46 74-95-32.5 2.0 5
1,2-Dichlorobenzene ND ug/L 10/21/22 06:46 95-50-12.5 1.7 5
1,3-Dichlorobenzene ND ug/L 10/21/22 06:46 541-73-12.5 1.7 5
1,4-Dichlorobenzene ND ug/L 10/21/22 06:46 106-46-72.5 1.7 5
Dichlorodifluoromethane ND ug/L 10/21/22 06:46 75-71-82.5 1.7 5
1,1-Dichloroethane ND ug/L 10/21/22 06:46 75-34-32.5 1.8 5
1,2-Dichloroethane ND ug/L 10/21/22 06:46 107-06-22.5 1.6 5
1,1-Dichloroethene ND ug/L 10/21/22 06:46 75-35-42.5 1.7 5
cis-1,2-Dichloroethene ND ug/L 10/21/22 06:46 156-59-22.5 1.9 5
trans-1,2-Dichloroethene ND ug/L 10/21/22 06:46 156-60-52.5 2.0 5
1,2-Dichloropropane ND ug/L 10/21/22 06:46 78-87-52.5 1.8 5
1,3-Dichloropropane ND ug/L 10/21/22 06:46 142-28-92.5 1.4 5
2,2-Dichloropropane ND ug/L 10/21/22 06:46 594-20-72.5 1.9 5
1,1-Dichloropropene ND ug/L 10/21/22 06:46 563-58-62.5 2.1 5
cis-1,3-Dichloropropene ND ug/L 10/21/22 06:46 10061-01-52.5 1.8 5
trans-1,3-Dichloropropene ND ug/L 10/21/22 06:46 10061-02-62.5 1.8 5
Diisopropyl ether 4.1 ug/L 10/21/22 06:46 108-20-32.5 1.5 5
Ethylbenzene 66.2 ug/L 10/21/22 06:46 100-41-42.5 1.5 5
Hexachloro-1,3-butadiene ND ug/L 10/21/22 06:46 87-68-310.0 7.6 5
Isopropylbenzene (Cumene)24.9 ug/L 10/21/22 06:46 98-82-82.5 1.7 5
Methylene Chloride ND ug/L 10/21/22 06:46 75-09-210.0 9.8 5
Methyl-tert-butyl ether 2.7 ug/L 10/21/22 06:46 1634-04-42.5 2.1 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 12 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Sample:EW-4 Lab ID:92630913005 Collected:10/12/22 12:34 Received:10/13/22 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Naphthalene 28.7 ug/L 10/21/22 06:46 91-20-310.0 3.2 5
n-Propylbenzene 61.0 ug/L 10/21/22 06:46 103-65-12.5 1.7 5
Styrene ND ug/L 10/21/22 06:46 100-42-52.5 1.5 5
1,1,1,2-Tetrachloroethane ND ug/L 10/21/22 06:46 630-20-62.5 1.6 5
1,1,2,2-Tetrachloroethane ND ug/L 10/21/22 06:46 79-34-52.5 1.1 5
Tetrachloroethene ND ug/L 10/21/22 06:46 127-18-42.5 1.5 5
Toluene 1.7J ug/L 10/21/22 06:46 108-88-32.5 1.2 5
1,2,3-Trichlorobenzene ND ug/L 10/21/22 06:46 87-61-610.0 4.0 5
1,2,4-Trichlorobenzene ND ug/L 10/21/22 06:46 120-82-110.0 3.2 5
1,1,1-Trichloroethane ND ug/L 10/21/22 06:46 71-55-62.5 1.7 5
1,1,2-Trichloroethane ND ug/L 10/21/22 06:46 79-00-52.5 1.6 5
Trichloroethene ND ug/L 10/21/22 06:46 79-01-62.5 1.9 5
Trichlorofluoromethane ND ug/L 10/21/22 06:46 75-69-45.0 1.5 5
1,2,3-Trichloropropane ND ug/L 10/21/22 06:46 96-18-42.5 1.3 5
1,2,4-Trimethylbenzene 486 ug/L 10/21/22 06:46 95-63-62.5 2.5 5
1,3,5-Trimethylbenzene 136 ug/L 10/21/22 06:46 108-67-82.5 1.7 5
Vinyl chloride ND ug/L 10/21/22 06:46 75-01-45.0 1.9 5
m&p-Xylene 104 ug/L 10/21/22 06:46 179601-23-15.0 3.5 5
o-Xylene 11.5 ug/L 10/21/22 06:46 95-47-62.5 1.7 5
Surrogates
1,2-Dichloroethane-d4 (S)91 %10/21/22 06:46 17060-07-0 D370-130 5
4-Bromofluorobenzene (S)97 %10/21/22 06:46 460-00-470-130 5
Toluene-d8 (S)98 %10/21/22 06:46 2037-26-570-130 5
Sample:EW-5 Lab ID:92630913006 Collected:10/12/22 12:51 Received:10/13/22 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Iron 2770 ug/L 10/19/22 16:53 7439-89-610/18/22 15:4850.0 41.5 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene 7.9 ug/L 10/21/22 04:59 71-43-20.50 0.34 1
Bromobenzene ND ug/L 10/21/22 04:59 108-86-10.50 0.29 1
Bromochloromethane ND ug/L 10/21/22 04:59 74-97-50.50 0.47 1
Bromodichloromethane ND ug/L 10/21/22 04:59 75-27-40.50 0.31 1
Bromoform ND ug/L 10/21/22 04:59 75-25-20.50 0.34 1
Bromomethane ND ug/L 10/21/22 04:59 74-83-95.0 1.7 1
n-Butylbenzene ND ug/L 10/21/22 04:59 104-51-80.50 0.49 1
sec-Butylbenzene ND ug/L 10/21/22 04:59 135-98-80.50 0.40 1
tert-Butylbenzene ND ug/L 10/21/22 04:59 98-06-60.50 0.32 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 13 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Sample:EW-5 Lab ID:92630913006 Collected:10/12/22 12:51 Received:10/13/22 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Carbon tetrachloride ND ug/L 10/21/22 04:59 56-23-50.50 0.33 1
Chlorobenzene ND ug/L 10/21/22 04:59 108-90-70.50 0.28 1
Chloroethane ND ug/L 10/21/22 04:59 75-00-31.0 0.65 1
Chloroform ND ug/L 10/21/22 04:59 67-66-30.50 0.43 1
Chloromethane ND ug/L 10/21/22 04:59 74-87-31.0 0.54 1
2-Chlorotoluene ND ug/L 10/21/22 04:59 95-49-80.50 0.32 1
4-Chlorotoluene ND ug/L 10/21/22 04:59 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane ND ug/L 10/21/22 04:59 96-12-81.0 0.34 1
Dibromochloromethane ND ug/L 10/21/22 04:59 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)ND ug/L 10/21/22 04:59 106-93-40.50 0.27 1
Dibromomethane ND ug/L 10/21/22 04:59 74-95-30.50 0.39 1
1,2-Dichlorobenzene ND ug/L 10/21/22 04:59 95-50-10.50 0.34 1
1,3-Dichlorobenzene ND ug/L 10/21/22 04:59 541-73-10.50 0.34 1
1,4-Dichlorobenzene ND ug/L 10/21/22 04:59 106-46-70.50 0.33 1
Dichlorodifluoromethane ND ug/L 10/21/22 04:59 75-71-80.50 0.35 1
1,1-Dichloroethane ND ug/L 10/21/22 04:59 75-34-30.50 0.37 1
1,2-Dichloroethane ND ug/L 10/21/22 04:59 107-06-20.50 0.32 1
1,1-Dichloroethene ND ug/L 10/21/22 04:59 75-35-40.50 0.35 1
cis-1,2-Dichloroethene ND ug/L 10/21/22 04:59 156-59-20.50 0.38 1
trans-1,2-Dichloroethene ND ug/L 10/21/22 04:59 156-60-50.50 0.40 1
1,2-Dichloropropane ND ug/L 10/21/22 04:59 78-87-50.50 0.36 1
1,3-Dichloropropane ND ug/L 10/21/22 04:59 142-28-90.50 0.28 1
2,2-Dichloropropane ND ug/L 10/21/22 04:59 594-20-70.50 0.39 1
1,1-Dichloropropene ND ug/L 10/21/22 04:59 563-58-60.50 0.43 1
cis-1,3-Dichloropropene ND ug/L 10/21/22 04:59 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/21/22 04:59 10061-02-60.50 0.36 1
Diisopropyl ether 3.5 ug/L 10/21/22 04:59 108-20-30.50 0.31 1
Ethylbenzene 14.4 ug/L 10/21/22 04:59 100-41-40.50 0.30 1
Hexachloro-1,3-butadiene ND ug/L 10/21/22 04:59 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)7.6 ug/L 10/21/22 04:59 98-82-80.50 0.33 1
Methylene Chloride ND ug/L 10/21/22 04:59 75-09-22.0 2.0 1
Methyl-tert-butyl ether 4.6 ug/L 10/21/22 04:59 1634-04-40.50 0.42 1
Naphthalene 15.7 ug/L 10/21/22 04:59 91-20-32.0 0.64 1
n-Propylbenzene 11.4 ug/L 10/21/22 04:59 103-65-10.50 0.34 1
Styrene ND ug/L 10/21/22 04:59 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 10/21/22 04:59 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 10/21/22 04:59 79-34-50.50 0.22 1
Tetrachloroethene ND ug/L 10/21/22 04:59 127-18-40.50 0.29 1
Toluene 0.79 ug/L 10/21/22 04:59 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene ND ug/L 10/21/22 04:59 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene ND ug/L 10/21/22 04:59 120-82-12.0 0.64 1
1,1,1-Trichloroethane ND ug/L 10/21/22 04:59 71-55-60.50 0.33 1
1,1,2-Trichloroethane ND ug/L 10/21/22 04:59 79-00-50.50 0.32 1
Trichloroethene ND ug/L 10/21/22 04:59 79-01-60.50 0.38 1
Trichlorofluoromethane ND ug/L 10/21/22 04:59 75-69-41.0 0.30 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 14 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Sample:EW-5 Lab ID:92630913006 Collected:10/12/22 12:51 Received:10/13/22 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,2,3-Trichloropropane ND ug/L 10/21/22 04:59 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene 153 ug/L 10/21/22 04:59 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene 49.2 ug/L 10/21/22 04:59 108-67-80.50 0.33 1
Vinyl chloride ND ug/L 10/21/22 04:59 75-01-41.0 0.39 1
m&p-Xylene 56.1 ug/L 10/21/22 04:59 179601-23-11.0 0.71 1
o-Xylene 15.4 ug/L 10/21/22 04:59 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)94 %10/21/22 04:59 17060-07-070-130 1
4-Bromofluorobenzene (S)98 %10/21/22 04:59 460-00-470-130 1
Toluene-d8 (S)98 %10/21/22 04:59 2037-26-570-130 1
Sample:DUP (VOC)Lab ID:92630913007 Collected:10/12/22 00:00 Received:10/13/22 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene 0.86 ug/L 10/21/22 02:53 71-43-20.50 0.34 1
Bromobenzene ND ug/L 10/21/22 02:53 108-86-10.50 0.29 1
Bromochloromethane ND ug/L 10/21/22 02:53 74-97-50.50 0.47 1
Bromodichloromethane ND ug/L 10/21/22 02:53 75-27-40.50 0.31 1
Bromoform ND ug/L 10/21/22 02:53 75-25-20.50 0.34 1
Bromomethane ND ug/L 10/21/22 02:53 74-83-95.0 1.7 1
n-Butylbenzene ND ug/L 10/21/22 02:53 104-51-80.50 0.49 1
sec-Butylbenzene ND ug/L 10/21/22 02:53 135-98-80.50 0.40 1
tert-Butylbenzene ND ug/L 10/21/22 02:53 98-06-60.50 0.32 1
Carbon tetrachloride ND ug/L 10/21/22 02:53 56-23-50.50 0.33 1
Chlorobenzene ND ug/L 10/21/22 02:53 108-90-70.50 0.28 1
Chloroethane ND ug/L 10/21/22 02:53 75-00-31.0 0.65 1
Chloroform ND ug/L 10/21/22 02:53 67-66-30.50 0.43 1
Chloromethane ND ug/L 10/21/22 02:53 74-87-31.0 0.54 1
2-Chlorotoluene ND ug/L 10/21/22 02:53 95-49-80.50 0.32 1
4-Chlorotoluene ND ug/L 10/21/22 02:53 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane ND ug/L 10/21/22 02:53 96-12-81.0 0.34 1
Dibromochloromethane ND ug/L 10/21/22 02:53 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)ND ug/L 10/21/22 02:53 106-93-40.50 0.27 1
Dibromomethane ND ug/L 10/21/22 02:53 74-95-30.50 0.39 1
1,2-Dichlorobenzene ND ug/L 10/21/22 02:53 95-50-10.50 0.34 1
1,3-Dichlorobenzene ND ug/L 10/21/22 02:53 541-73-10.50 0.34 1
1,4-Dichlorobenzene ND ug/L 10/21/22 02:53 106-46-70.50 0.33 1
Dichlorodifluoromethane ND ug/L 10/21/22 02:53 75-71-80.50 0.35 1
1,1-Dichloroethane ND ug/L 10/21/22 02:53 75-34-30.50 0.37 1
1,2-Dichloroethane ND ug/L 10/21/22 02:53 107-06-20.50 0.32 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 15 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Sample:DUP (VOC)Lab ID:92630913007 Collected:10/12/22 00:00 Received:10/13/22 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1-Dichloroethene ND ug/L 10/21/22 02:53 75-35-40.50 0.35 1
cis-1,2-Dichloroethene ND ug/L 10/21/22 02:53 156-59-20.50 0.38 1
trans-1,2-Dichloroethene ND ug/L 10/21/22 02:53 156-60-50.50 0.40 1
1,2-Dichloropropane ND ug/L 10/21/22 02:53 78-87-50.50 0.36 1
1,3-Dichloropropane ND ug/L 10/21/22 02:53 142-28-90.50 0.28 1
2,2-Dichloropropane ND ug/L 10/21/22 02:53 594-20-70.50 0.39 1
1,1-Dichloropropene ND ug/L 10/21/22 02:53 563-58-60.50 0.43 1
cis-1,3-Dichloropropene ND ug/L 10/21/22 02:53 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/21/22 02:53 10061-02-60.50 0.36 1
Diisopropyl ether 0.35J ug/L 10/21/22 02:53 108-20-30.50 0.31 1
Ethylbenzene 2.7 ug/L 10/21/22 02:53 100-41-40.50 0.30 1
Hexachloro-1,3-butadiene ND ug/L 10/21/22 02:53 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)0.94 ug/L 10/21/22 02:53 98-82-80.50 0.33 1
Methylene Chloride ND ug/L 10/21/22 02:53 75-09-22.0 2.0 1
Methyl-tert-butyl ether ND ug/L 10/21/22 02:53 1634-04-40.50 0.42 1
Naphthalene 4.9 ug/L 10/21/22 02:53 91-20-32.0 0.64 1
n-Propylbenzene 2.1 ug/L 10/21/22 02:53 103-65-10.50 0.34 1
Styrene ND ug/L 10/21/22 02:53 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 10/21/22 02:53 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 10/21/22 02:53 79-34-50.50 0.22 1
Tetrachloroethene ND ug/L 10/21/22 02:53 127-18-40.50 0.29 1
Toluene 0.28J ug/L 10/21/22 02:53 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene ND ug/L 10/21/22 02:53 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene ND ug/L 10/21/22 02:53 120-82-12.0 0.64 1
1,1,1-Trichloroethane ND ug/L 10/21/22 02:53 71-55-60.50 0.33 1
1,1,2-Trichloroethane ND ug/L 10/21/22 02:53 79-00-50.50 0.32 1
Trichloroethene ND ug/L 10/21/22 02:53 79-01-60.50 0.38 1
Trichlorofluoromethane ND ug/L 10/21/22 02:53 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 10/21/22 02:53 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene 26.0 ug/L 10/21/22 02:53 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene 6.9 ug/L 10/21/22 02:53 108-67-80.50 0.33 1
Vinyl chloride ND ug/L 10/21/22 02:53 75-01-41.0 0.39 1
m&p-Xylene 6.9 ug/L 10/21/22 02:53 179601-23-11.0 0.71 1
o-Xylene 1.7 ug/L 10/21/22 02:53 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)94 %10/21/22 02:53 17060-07-070-130 1
4-Bromofluorobenzene (S)94 %10/21/22 02:53 460-00-470-130 1
Toluene-d8 (S)105 %10/21/22 02:53 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 16 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Sample:DUP (Fe)Lab ID:92630913008 Collected:10/12/22 00:00 Received:10/13/22 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Iron 18300 ug/L 10/19/22 16:56 7439-89-610/18/22 15:4850.0 41.5 1
Sample:POTW-INF-14 Lab ID:92630913009 Collected:10/12/22 13:07 Received:10/13/22 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 10/17/22 15:09 71-43-20.50 0.34 1
Bromobenzene ND ug/L 10/17/22 15:09 108-86-10.50 0.29 1
Bromochloromethane ND ug/L 10/17/22 15:09 74-97-50.50 0.47 1
Bromodichloromethane ND ug/L 10/17/22 15:09 75-27-40.50 0.31 1
Bromoform ND ug/L 10/17/22 15:09 75-25-20.50 0.34 1
Bromomethane ND ug/L 10/17/22 15:09 74-83-95.0 1.7 1
n-Butylbenzene ND ug/L 10/17/22 15:09 104-51-80.50 0.49 1
sec-Butylbenzene ND ug/L 10/17/22 15:09 135-98-80.50 0.40 1
tert-Butylbenzene ND ug/L 10/17/22 15:09 98-06-60.50 0.32 1
Carbon tetrachloride ND ug/L 10/17/22 15:09 56-23-50.50 0.33 1
Chlorobenzene ND ug/L 10/17/22 15:09 108-90-70.50 0.28 1
Chloroethane ND ug/L 10/17/22 15:09 75-00-31.0 0.65 1
Chloroform 2.2 ug/L 10/17/22 15:09 67-66-30.50 0.43 1
Chloromethane ND ug/L 10/17/22 15:09 74-87-31.0 0.54 1
2-Chlorotoluene ND ug/L 10/17/22 15:09 95-49-80.50 0.32 1
4-Chlorotoluene ND ug/L 10/17/22 15:09 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane ND ug/L 10/17/22 15:09 96-12-81.0 0.34 1
Dibromochloromethane ND ug/L 10/17/22 15:09 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)ND ug/L 10/17/22 15:09 106-93-40.50 0.27 1
Dibromomethane ND ug/L 10/17/22 15:09 74-95-30.50 0.39 1
1,2-Dichlorobenzene ND ug/L 10/17/22 15:09 95-50-10.50 0.34 1
1,3-Dichlorobenzene ND ug/L 10/17/22 15:09 541-73-10.50 0.34 1
1,4-Dichlorobenzene ND ug/L 10/17/22 15:09 106-46-70.50 0.33 1
Dichlorodifluoromethane ND ug/L 10/17/22 15:09 75-71-80.50 0.35 1
1,1-Dichloroethane ND ug/L 10/17/22 15:09 75-34-30.50 0.37 1
1,2-Dichloroethane ND ug/L 10/17/22 15:09 107-06-20.50 0.32 1
1,1-Dichloroethene ND ug/L 10/17/22 15:09 75-35-40.50 0.35 1
cis-1,2-Dichloroethene ND ug/L 10/17/22 15:09 156-59-20.50 0.38 1
trans-1,2-Dichloroethene ND ug/L 10/17/22 15:09 156-60-50.50 0.40 1
1,2-Dichloropropane ND ug/L 10/17/22 15:09 78-87-50.50 0.36 1
1,3-Dichloropropane ND ug/L 10/17/22 15:09 142-28-90.50 0.28 1
2,2-Dichloropropane ND ug/L 10/17/22 15:09 594-20-70.50 0.39 1
1,1-Dichloropropene ND ug/L 10/17/22 15:09 563-58-60.50 0.43 1
cis-1,3-Dichloropropene ND ug/L 10/17/22 15:09 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/17/22 15:09 10061-02-60.50 0.36 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 17 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Sample:POTW-INF-14 Lab ID:92630913009 Collected:10/12/22 13:07 Received:10/13/22 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Diisopropyl ether ND ug/L 10/17/22 15:09 108-20-30.50 0.31 1
Ethylbenzene 0.67 ug/L 10/17/22 15:09 100-41-40.50 0.30 1
Hexachloro-1,3-butadiene ND ug/L 10/17/22 15:09 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)0.72 ug/L 10/17/22 15:09 98-82-80.50 0.33 1
Methylene Chloride ND ug/L 10/17/22 15:09 75-09-22.0 2.0 1
Methyl-tert-butyl ether ND ug/L 10/17/22 15:09 1634-04-40.50 0.42 1
Naphthalene ND ug/L 10/17/22 15:09 91-20-32.0 0.64 1
n-Propylbenzene 2.5 ug/L 10/17/22 15:09 103-65-10.50 0.34 1
Styrene ND ug/L 10/17/22 15:09 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 10/17/22 15:09 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 10/17/22 15:09 79-34-50.50 0.22 1
Tetrachloroethene ND ug/L 10/17/22 15:09 127-18-40.50 0.29 1
Toluene 1.1 ug/L 10/17/22 15:09 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene ND ug/L 10/17/22 15:09 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene ND ug/L 10/17/22 15:09 120-82-12.0 0.64 1
1,1,1-Trichloroethane ND ug/L 10/17/22 15:09 71-55-60.50 0.33 1
1,1,2-Trichloroethane ND ug/L 10/17/22 15:09 79-00-50.50 0.32 1
Trichloroethene ND ug/L 10/17/22 15:09 79-01-60.50 0.38 1
Trichlorofluoromethane ND ug/L 10/17/22 15:09 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 10/17/22 15:09 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene 13.3 ug/L 10/17/22 15:09 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene 3.8 ug/L 10/17/22 15:09 108-67-80.50 0.33 1
Vinyl chloride ND ug/L 10/17/22 15:09 75-01-41.0 0.39 1
m&p-Xylene 1.9 ug/L 10/17/22 15:09 179601-23-11.0 0.71 1
o-Xylene 1.5 ug/L 10/17/22 15:09 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)98 %10/17/22 15:09 17060-07-070-130 1
4-Bromofluorobenzene (S)99 %10/17/22 15:09 460-00-470-130 1
Toluene-d8 (S)104 %10/17/22 15:09 2037-26-570-130 1
Analytical Method: SM 2540D-2015
Pace Analytical Services - Asheville
2540D Total Suspended Solids
Total Suspended Solids 231 mg/L 10/15/22 17:0438.5 38.5 1
Sample:POTW-EF-14 Lab ID:92630913010 Collected:10/12/22 13:19 Received:10/13/22 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 10/17/22 14:15 71-43-20.50 0.34 1
Bromobenzene ND ug/L 10/17/22 14:15 108-86-10.50 0.29 1
Bromochloromethane ND ug/L 10/17/22 14:15 74-97-50.50 0.47 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 18 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Sample:POTW-EF-14 Lab ID:92630913010 Collected:10/12/22 13:19 Received:10/13/22 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Bromodichloromethane ND ug/L 10/17/22 14:15 75-27-40.50 0.31 1
Bromoform ND ug/L 10/17/22 14:15 75-25-20.50 0.34 1
Bromomethane ND ug/L 10/17/22 14:15 74-83-95.0 1.7 1
n-Butylbenzene ND ug/L 10/17/22 14:15 104-51-80.50 0.49 1
sec-Butylbenzene ND ug/L 10/17/22 14:15 135-98-80.50 0.40 1
tert-Butylbenzene ND ug/L 10/17/22 14:15 98-06-60.50 0.32 1
Carbon tetrachloride ND ug/L 10/17/22 14:15 56-23-50.50 0.33 1
Chlorobenzene ND ug/L 10/17/22 14:15 108-90-70.50 0.28 1
Chloroethane ND ug/L 10/17/22 14:15 75-00-31.0 0.65 1
Chloroform ND ug/L 10/17/22 14:15 67-66-30.50 0.43 1
Chloromethane ND ug/L 10/17/22 14:15 74-87-31.0 0.54 1
2-Chlorotoluene ND ug/L 10/17/22 14:15 95-49-80.50 0.32 1
4-Chlorotoluene ND ug/L 10/17/22 14:15 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane ND ug/L 10/17/22 14:15 96-12-81.0 0.34 1
Dibromochloromethane ND ug/L 10/17/22 14:15 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)ND ug/L 10/17/22 14:15 106-93-40.50 0.27 1
Dibromomethane ND ug/L 10/17/22 14:15 74-95-30.50 0.39 1
1,2-Dichlorobenzene ND ug/L 10/17/22 14:15 95-50-10.50 0.34 1
1,3-Dichlorobenzene ND ug/L 10/17/22 14:15 541-73-10.50 0.34 1
1,4-Dichlorobenzene ND ug/L 10/17/22 14:15 106-46-70.50 0.33 1
Dichlorodifluoromethane ND ug/L 10/17/22 14:15 75-71-80.50 0.35 1
1,1-Dichloroethane ND ug/L 10/17/22 14:15 75-34-30.50 0.37 1
1,2-Dichloroethane ND ug/L 10/17/22 14:15 107-06-20.50 0.32 1
1,1-Dichloroethene ND ug/L 10/17/22 14:15 75-35-40.50 0.35 1
cis-1,2-Dichloroethene ND ug/L 10/17/22 14:15 156-59-20.50 0.38 1
trans-1,2-Dichloroethene ND ug/L 10/17/22 14:15 156-60-50.50 0.40 1
1,2-Dichloropropane ND ug/L 10/17/22 14:15 78-87-50.50 0.36 1
1,3-Dichloropropane ND ug/L 10/17/22 14:15 142-28-90.50 0.28 1
2,2-Dichloropropane ND ug/L 10/17/22 14:15 594-20-70.50 0.39 1
1,1-Dichloropropene ND ug/L 10/17/22 14:15 563-58-60.50 0.43 1
cis-1,3-Dichloropropene ND ug/L 10/17/22 14:15 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/17/22 14:15 10061-02-60.50 0.36 1
Diisopropyl ether ND ug/L 10/17/22 14:15 108-20-30.50 0.31 1
Ethylbenzene ND ug/L 10/17/22 14:15 100-41-40.50 0.30 1
Hexachloro-1,3-butadiene ND ug/L 10/17/22 14:15 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)ND ug/L 10/17/22 14:15 98-82-80.50 0.33 1
Methylene Chloride ND ug/L 10/17/22 14:15 75-09-22.0 2.0 1
Methyl-tert-butyl ether ND ug/L 10/17/22 14:15 1634-04-40.50 0.42 1
Naphthalene ND ug/L 10/17/22 14:15 91-20-32.0 0.64 1
n-Propylbenzene ND ug/L 10/17/22 14:15 103-65-10.50 0.34 1
Styrene ND ug/L 10/17/22 14:15 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 10/17/22 14:15 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 10/17/22 14:15 79-34-50.50 0.22 1
Tetrachloroethene ND ug/L 10/17/22 14:15 127-18-40.50 0.29 1
Toluene ND ug/L 10/17/22 14:15 108-88-30.50 0.24 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 19 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Sample:POTW-EF-14 Lab ID:92630913010 Collected:10/12/22 13:19 Received:10/13/22 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,2,3-Trichlorobenzene ND ug/L 10/17/22 14:15 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene ND ug/L 10/17/22 14:15 120-82-12.0 0.64 1
1,1,1-Trichloroethane ND ug/L 10/17/22 14:15 71-55-60.50 0.33 1
1,1,2-Trichloroethane ND ug/L 10/17/22 14:15 79-00-50.50 0.32 1
Trichloroethene ND ug/L 10/17/22 14:15 79-01-60.50 0.38 1
Trichlorofluoromethane ND ug/L 10/17/22 14:15 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 10/17/22 14:15 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene ND ug/L 10/17/22 14:15 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene ND ug/L 10/17/22 14:15 108-67-80.50 0.33 1
Vinyl chloride ND ug/L 10/17/22 14:15 75-01-41.0 0.39 1
m&p-Xylene ND ug/L 10/17/22 14:15 179601-23-11.0 0.71 1
o-Xylene ND ug/L 10/17/22 14:15 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)99 %10/17/22 14:15 17060-07-070-130 1
4-Bromofluorobenzene (S)97 %10/17/22 14:15 460-00-470-130 1
Toluene-d8 (S)105 %10/17/22 14:15 2037-26-570-130 1
Analytical Method: SM 2540D-2015
Pace Analytical Services - Asheville
2540D Total Suspended Solids
Total Suspended Solids ND mg/L 10/15/22 17:052.5 2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 20 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
730956
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
200.7 MET
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92630913001, 92630913002, 92630913003, 92630913004, 92630913005, 92630913006, 92630913008
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3805629
Associated Lab Samples:92630913001, 92630913002, 92630913003, 92630913004, 92630913005, 92630913006, 92630913008
Matrix:Water
AnalyzedMDL
Iron ug/L ND 50.0 10/19/22 16:1441.5
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3805630LABORATORY CONTROL SAMPLE:
LCSSpike
Iron ug/L 49505000 99 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3805631MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92630913001
3805632
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Iron ug/L 5000 95 70-13094 0 205000163002110021000
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 21 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
730313
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92630913001, 92630913003, 92630913004, 92630913009, 92630913010
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3802711
Associated Lab Samples:92630913001, 92630913003, 92630913004, 92630913009, 92630913010
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 0.50 10/17/22 12:090.31
1,1,1-Trichloroethane ug/L ND 0.50 10/17/22 12:090.33
1,1,2,2-Tetrachloroethane ug/L ND 0.50 10/17/22 12:090.22
1,1,2-Trichloroethane ug/L ND 0.50 10/17/22 12:090.32
1,1-Dichloroethane ug/L ND 0.50 10/17/22 12:090.37
1,1-Dichloroethene ug/L ND 0.50 10/17/22 12:090.35
1,1-Dichloropropene ug/L ND 0.50 10/17/22 12:090.43
1,2,3-Trichlorobenzene ug/L ND 2.0 10/17/22 12:090.81
1,2,3-Trichloropropane ug/L ND 0.50 10/17/22 12:090.26
1,2,4-Trichlorobenzene ug/L ND 2.0 10/17/22 12:090.64
1,2,4-Trimethylbenzene ug/L ND 0.50 10/17/22 12:090.50
1,2-Dibromo-3-chloropropane ug/L ND 1.0 10/17/22 12:090.34
1,2-Dibromoethane (EDB)ug/L ND 0.50 10/17/22 12:090.27
1,2-Dichlorobenzene ug/L ND 0.50 10/17/22 12:090.34
1,2-Dichloroethane ug/L ND 0.50 10/17/22 12:090.32
1,2-Dichloropropane ug/L ND 0.50 10/17/22 12:090.36
1,3,5-Trimethylbenzene ug/L ND 0.50 10/17/22 12:090.33
1,3-Dichlorobenzene ug/L ND 0.50 10/17/22 12:090.34
1,3-Dichloropropane ug/L ND 0.50 10/17/22 12:090.28
1,4-Dichlorobenzene ug/L ND 0.50 10/17/22 12:090.33
2,2-Dichloropropane ug/L ND 0.50 10/17/22 12:090.39
2-Chlorotoluene ug/L ND 0.50 10/17/22 12:090.32
4-Chlorotoluene ug/L ND 0.50 10/17/22 12:090.32
Benzene ug/L ND 0.50 10/17/22 12:090.34
Bromobenzene ug/L ND 0.50 10/17/22 12:090.29
Bromochloromethane ug/L ND 0.50 10/17/22 12:090.47
Bromodichloromethane ug/L ND 0.50 10/17/22 12:090.31
Bromoform ug/L ND 0.50 10/17/22 12:090.34
Bromomethane ug/L ND 5.0 10/17/22 12:091.7
Carbon tetrachloride ug/L ND 0.50 10/17/22 12:090.33
Chlorobenzene ug/L ND 0.50 10/17/22 12:090.28
Chloroethane ug/L ND 1.0 10/17/22 12:090.65
Chloroform ug/L ND 0.50 10/17/22 12:090.43
Chloromethane ug/L ND 1.0 10/17/22 12:090.54
cis-1,2-Dichloroethene ug/L ND 0.50 10/17/22 12:090.38
cis-1,3-Dichloropropene ug/L ND 0.50 10/17/22 12:090.36
Dibromochloromethane ug/L ND 0.50 10/17/22 12:090.36
Dibromomethane ug/L ND 0.50 10/17/22 12:090.39
Dichlorodifluoromethane ug/L ND 0.50 10/17/22 12:090.35
Diisopropyl ether ug/L ND 0.50 10/17/22 12:090.31
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 22 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3802711
Associated Lab Samples:92630913001, 92630913003, 92630913004, 92630913009, 92630913010
Matrix:Water
AnalyzedMDL
Ethylbenzene ug/L ND 0.50 10/17/22 12:090.30
Hexachloro-1,3-butadiene ug/L ND 2.0 10/17/22 12:091.5
Isopropylbenzene (Cumene)ug/L ND 0.50 10/17/22 12:090.33
m&p-Xylene ug/L ND 1.0 10/17/22 12:090.71
Methyl-tert-butyl ether ug/L ND 0.50 10/17/22 12:090.42
Methylene Chloride ug/L ND 2.0 10/17/22 12:092.0
n-Butylbenzene ug/L ND 0.50 10/17/22 12:090.49
n-Propylbenzene ug/L ND 0.50 10/17/22 12:090.34
Naphthalene ug/L ND 2.0 10/17/22 12:090.64
o-Xylene ug/L ND 0.50 10/17/22 12:090.34
sec-Butylbenzene ug/L ND 0.50 10/17/22 12:090.40
Styrene ug/L ND 0.50 10/17/22 12:090.29
tert-Butylbenzene ug/L ND 0.50 10/17/22 12:090.32
Tetrachloroethene ug/L ND 0.50 10/17/22 12:090.29
Toluene ug/L ND 0.50 10/17/22 12:090.24
trans-1,2-Dichloroethene ug/L ND 0.50 10/17/22 12:090.40
trans-1,3-Dichloropropene ug/L ND 0.50 10/17/22 12:090.36
Trichloroethene ug/L ND 0.50 10/17/22 12:090.38
Trichlorofluoromethane ug/L ND 1.0 10/17/22 12:090.30
Vinyl chloride ug/L ND 1.0 10/17/22 12:090.39
1,2-Dichloroethane-d4 (S)%97 70-130 10/17/22 12:09
4-Bromofluorobenzene (S)%99 70-130 10/17/22 12:09
Toluene-d8 (S)%105 70-130 10/17/22 12:09
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3802712LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 52.950 106 60-140
1,1,1-Trichloroethane ug/L 44.250 88 60-140
1,1,2,2-Tetrachloroethane ug/L 47.750 95 60-140
1,1,2-Trichloroethane ug/L 45.550 91 60-140
1,1-Dichloroethane ug/L 42.750 85 60-140
1,1-Dichloroethene ug/L 43.850 88 60-140
1,1-Dichloropropene ug/L 48.450 97 60-140
1,2,3-Trichlorobenzene ug/L 55.850 112 60-140
1,2,3-Trichloropropane ug/L 49.650 99 60-140
1,2,4-Trichlorobenzene ug/L 50.050 100 60-140
1,2,4-Trimethylbenzene ug/L 47.950 96 60-140
1,2-Dibromo-3-chloropropane ug/L 51.650 103 60-140
1,2-Dibromoethane (EDB)ug/L 50.250 100 60-140
1,2-Dichlorobenzene ug/L 48.850 98 60-140
1,2-Dichloroethane ug/L 43.850 88 60-140
1,2-Dichloropropane ug/L 48.350 97 60-140
1,3,5-Trimethylbenzene ug/L 46.050 92 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 23 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3802712LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichlorobenzene ug/L 46.850 94 60-140
1,3-Dichloropropane ug/L 49.450 99 60-140
1,4-Dichlorobenzene ug/L 46.250 92 60-140
2,2-Dichloropropane ug/L 46.250 92 60-140
2-Chlorotoluene ug/L 41.050 82 60-140
4-Chlorotoluene ug/L 41.050 82 60-140
Benzene ug/L 43.450 87 60-140
Bromobenzene ug/L 46.250 92 60-140
Bromochloromethane ug/L 45.750 91 60-140
Bromodichloromethane ug/L 48.650 97 60-140
Bromoform ug/L 57.350 115 60-140
Bromomethane ug/L 42.450 85 60-140
Carbon tetrachloride ug/L 50.050 100 60-140
Chlorobenzene ug/L 47.650 95 60-140
Chloroethane ug/L 52.650 105 60-140
Chloroform ug/L 42.250 84 60-140
Chloromethane ug/L 43.250 86 60-140
cis-1,2-Dichloroethene ug/L 45.150 90 60-140
cis-1,3-Dichloropropene ug/L 50.750 101 60-140
Dibromochloromethane ug/L 52.650 105 60-140
Dibromomethane ug/L 48.650 97 60-140
Dichlorodifluoromethane ug/L 41.450 83 60-140
Diisopropyl ether ug/L 50.750 101 60-140
Ethylbenzene ug/L 46.450 93 60-140
Hexachloro-1,3-butadiene ug/L 51.250 102 60-140
Isopropylbenzene (Cumene)ug/L 47.750 95 60-140
m&p-Xylene ug/L 96.4100 96 60-140
Methyl-tert-butyl ether ug/L 50.350 101 60-140
Methylene Chloride ug/L 50.950 102 60-140
n-Butylbenzene ug/L 48.350 97 60-140
n-Propylbenzene ug/L 46.250 92 60-140
Naphthalene ug/L 52.250 104 60-140
o-Xylene ug/L 49.150 98 60-140
sec-Butylbenzene ug/L 45.850 92 60-140
Styrene ug/L 49.250 98 60-140
tert-Butylbenzene ug/L 39.250 78 60-140
Tetrachloroethene ug/L 48.850 98 60-140
Toluene ug/L 44.050 88 60-140
trans-1,2-Dichloroethene ug/L 43.350 87 60-140
trans-1,3-Dichloropropene ug/L 51.150 102 60-140
Trichloroethene ug/L 47.950 96 60-140
Trichlorofluoromethane ug/L 45.850 92 60-140
Vinyl chloride ug/L 43.350 87 60-140
1,2-Dichloroethane-d4 (S)%92 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%95 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 24 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3802713MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92630766001
3802714
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 400 116 60-140120 3 30400ND463478
1,1,1-Trichloroethane ug/L 400 107 60-140115 7 30400ND428461
1,1,2,2-Tetrachloroethane ug/L 400 105 60-140105 0 30400ND422421
1,1,2-Trichloroethane ug/L 400 101 60-140104 2 30400ND406415
1,1-Dichloroethane ug/L 400 107 60-140111 3 30400ND429444
1,1-Dichloroethene ug/L 400 109 60-140117 7 30400ND438469
1,1-Dichloropropene ug/L 400 117 60-140127 8 30400ND468507
1,2,3-Trichlorobenzene ug/L 400 98 60-140118 18 30400ND392472
1,2,3-Trichloropropane ug/L 400 97 60-140103 6 30400ND387411
1,2,4-Trichlorobenzene ug/L 400 97 60-140108 11 30400ND388431
1,2,4-Trimethylbenzene ug/L 400 123 60-140123 0 30400121017001700
1,2-Dibromo-3-
chloropropane ug/L 400 102 60-140112 9 30400ND408446
1,2-Dibromoethane (EDB)ug/L 400 106 60-140113 6 30400ND424450
1,2-Dichlorobenzene ug/L 400 105 60-140112 6 30400ND421447
1,2-Dichloroethane ug/L 400 103 60-140110 6 30400ND412439
1,2-Dichloropropane ug/L 400 111 60-140112 1 30400ND446449
1,3,5-Trimethylbenzene ug/L 400 111 60-140124 6 30400351797847
1,3-Dichlorobenzene ug/L 400 101 60-140107 6 30400ND402429
1,3-Dichloropropane ug/L 400 107 60-140111 3 30400ND430444
1,4-Dichlorobenzene ug/L 400 98 60-140105 7 30400ND392420
2,2-Dichloropropane ug/L 400 63 60-14065 3 30400ND252259
2-Chlorotoluene ug/L 400 114 60-140107 6 30400ND454430
4-Chlorotoluene ug/L 400 114 60-140107 6 30400ND454430
Benzene ug/L 400 102 60-140105 2 30400121528540
Bromobenzene ug/L 400 105 60-140108 2 30400ND421431
Bromochloromethane ug/L 400 115 60-140119 4 30400ND458478
Bromodichloromethane ug/L 400 111 60-140110 1 30400ND446441
Bromoform ug/L 400 115 60-140118 3 30400ND461473
Bromomethane ug/L 400 88 60-140103 16 30400ND351410
Carbon tetrachloride ug/L 400 116 60-140119 2 30400ND465475
Chlorobenzene ug/L 400 105 60-140112 6 30400ND421447
Chloroethane ug/L 400 117 60-140121 3 30400ND467483
Chloroform ug/L 400 104 60-140107 3 30400ND417428
Chloromethane ug/L 400 108 60-140122 12 30400ND432488
cis-1,2-Dichloroethene ug/L 400 113 60-140117 4 30400ND451469
cis-1,3-Dichloropropene ug/L 400 98 60-140100 2 30400ND392399
Dibromochloromethane ug/L 400 112 60-140118 5 30400ND448473
Dibromomethane ug/L 400 112 60-140113 1 30400ND447452
Dichlorodifluoromethane ug/L 400 95 60-140101 6 30400ND380403
Diisopropyl ether ug/L 400 110 60-140116 5 30400ND444469
Ethylbenzene ug/L 400 117 60-140131 4 30400102014901550
Hexachloro-1,3-butadiene ug/L 400 101 60-140115 13 30400ND404459
Isopropylbenzene(Cumene)ug/L 400 108 60-140112 3 30400103536553
m&p-Xylene ug/L M180013860-140148 2 30800342045204600
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 25 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3802713MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92630766001
3802714
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Methyl-tert-butyl ether ug/L 400 107 60-140114 6 30400ND435463
Methylene Chloride ug/L 400 112 60-140122 8 3040077.9 524 566
n-Butylbenzene ug/L 400 108 60-140115 6 30400ND432459
n-Propylbenzene ug/L 400 108 60-140113 3 30400224655677
Naphthalene ug/L 400 97 60-140123 15 30400273660767
o-Xylene ug/L 400 119 60-140137 4 30400145019302000
sec-Butylbenzene ug/L 400 105 60-140110 5 30400ND420442
Styrene ug/L 400 107 60-140113 5 30400ND428451
tert-Butylbenzene ug/L 400 91 60-14092 2 30400ND363369
Tetrachloroethene ug/L 400 103 60-140114 9 30400ND414454
Toluene ug/L 400 100 60-140101 1 3040029.6 428 432
trans-1,2-Dichloroethene ug/L 400 107 60-140116 9 30400ND427466
trans-1,3-Dichloropropene ug/L 400 96 60-14099 3 30400ND384396
Trichloroethene ug/L 400 110 60-140112 1 30400ND442448
Trichlorofluoromethane ug/L 400 105 60-140115 9 30400ND420458
Vinyl chloride ug/L 400 115 60-140119 3 30400ND460475
1,2-Dichloroethane-d4 (S)%93 70-13098
4-Bromofluorobenzene (S)%100 70-130101
Toluene-d8 (S)%95 70-13096
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 26 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
731239
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92630913002, 92630913005, 92630913006, 92630913007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3806704
Associated Lab Samples:92630913002, 92630913005, 92630913006, 92630913007
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 0.50 10/21/22 01:420.31
1,1,1-Trichloroethane ug/L ND 0.50 10/21/22 01:420.33
1,1,2,2-Tetrachloroethane ug/L ND 0.50 10/21/22 01:420.22
1,1,2-Trichloroethane ug/L ND 0.50 10/21/22 01:420.32
1,1-Dichloroethane ug/L ND 0.50 10/21/22 01:420.37
1,1-Dichloroethene ug/L ND 0.50 10/21/22 01:420.35
1,1-Dichloropropene ug/L ND 0.50 10/21/22 01:420.43
1,2,3-Trichlorobenzene ug/L ND 2.0 10/21/22 01:420.81
1,2,3-Trichloropropane ug/L ND 0.50 10/21/22 01:420.26
1,2,4-Trichlorobenzene ug/L ND 2.0 10/21/22 01:420.64
1,2,4-Trimethylbenzene ug/L ND 0.50 10/21/22 01:420.50
1,2-Dibromo-3-chloropropane ug/L ND 1.0 10/21/22 01:420.34
1,2-Dibromoethane (EDB)ug/L ND 0.50 10/21/22 01:420.27
1,2-Dichlorobenzene ug/L ND 0.50 10/21/22 01:420.34
1,2-Dichloroethane ug/L ND 0.50 10/21/22 01:420.32
1,2-Dichloropropane ug/L ND 0.50 10/21/22 01:420.36
1,3,5-Trimethylbenzene ug/L ND 0.50 10/21/22 01:420.33
1,3-Dichlorobenzene ug/L ND 0.50 10/21/22 01:420.34
1,3-Dichloropropane ug/L ND 0.50 10/21/22 01:420.28
1,4-Dichlorobenzene ug/L ND 0.50 10/21/22 01:420.33
2,2-Dichloropropane ug/L ND 0.50 10/21/22 01:420.39
2-Chlorotoluene ug/L ND 0.50 10/21/22 01:420.32
4-Chlorotoluene ug/L ND 0.50 10/21/22 01:420.32
Benzene ug/L ND 0.50 10/21/22 01:420.34
Bromobenzene ug/L ND 0.50 10/21/22 01:420.29
Bromochloromethane ug/L ND 0.50 10/21/22 01:420.47
Bromodichloromethane ug/L ND 0.50 10/21/22 01:420.31
Bromoform ug/L ND 0.50 10/21/22 01:420.34
Bromomethane ug/L ND 5.0 10/21/22 01:421.7
Carbon tetrachloride ug/L ND 0.50 10/21/22 01:420.33
Chlorobenzene ug/L ND 0.50 10/21/22 01:420.28
Chloroethane ug/L ND 1.0 10/21/22 01:420.65
Chloroform ug/L ND 0.50 10/21/22 01:420.43
Chloromethane ug/L ND 1.0 10/21/22 01:420.54
cis-1,2-Dichloroethene ug/L ND 0.50 10/21/22 01:420.38
cis-1,3-Dichloropropene ug/L ND 0.50 10/21/22 01:420.36
Dibromochloromethane ug/L ND 0.50 10/21/22 01:420.36
Dibromomethane ug/L ND 0.50 10/21/22 01:420.39
Dichlorodifluoromethane ug/L ND 0.50 10/21/22 01:420.35
Diisopropyl ether ug/L ND 0.50 10/21/22 01:420.31
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 27 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3806704
Associated Lab Samples:92630913002, 92630913005, 92630913006, 92630913007
Matrix:Water
AnalyzedMDL
Ethylbenzene ug/L ND 0.50 10/21/22 01:420.30
Hexachloro-1,3-butadiene ug/L ND 2.0 10/21/22 01:421.5
Isopropylbenzene (Cumene)ug/L ND 0.50 10/21/22 01:420.33
m&p-Xylene ug/L ND 1.0 10/21/22 01:420.71
Methyl-tert-butyl ether ug/L ND 0.50 10/21/22 01:420.42
Methylene Chloride ug/L ND 2.0 10/21/22 01:422.0
n-Butylbenzene ug/L ND 0.50 10/21/22 01:420.49
n-Propylbenzene ug/L ND 0.50 10/21/22 01:420.34
Naphthalene ug/L ND 2.0 10/21/22 01:420.64
o-Xylene ug/L ND 0.50 10/21/22 01:420.34
sec-Butylbenzene ug/L ND 0.50 10/21/22 01:420.40
Styrene ug/L ND 0.50 10/21/22 01:420.29
tert-Butylbenzene ug/L ND 0.50 10/21/22 01:420.32
Tetrachloroethene ug/L ND 0.50 10/21/22 01:420.29
Toluene ug/L ND 0.50 10/21/22 01:420.24
trans-1,2-Dichloroethene ug/L ND 0.50 10/21/22 01:420.40
trans-1,3-Dichloropropene ug/L ND 0.50 10/21/22 01:420.36
Trichloroethene ug/L ND 0.50 10/21/22 01:420.38
Trichlorofluoromethane ug/L ND 1.0 10/21/22 01:420.30
Vinyl chloride ug/L ND 1.0 10/21/22 01:420.39
1,2-Dichloroethane-d4 (S)%90 70-130 10/21/22 01:42
4-Bromofluorobenzene (S)%95 70-130 10/21/22 01:42
Toluene-d8 (S)%105 70-130 10/21/22 01:42
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3806705LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 57.850 116 60-140
1,1,1-Trichloroethane ug/L 43.950 88 60-140
1,1,2,2-Tetrachloroethane ug/L 51.750 103 60-140
1,1,2-Trichloroethane ug/L 49.350 99 60-140
1,1-Dichloroethane ug/L 43.850 88 60-140
1,1-Dichloroethene ug/L 46.050 92 60-140
1,1-Dichloropropene ug/L 50.150 100 60-140
1,2,3-Trichlorobenzene ug/L 63.050 126 60-140
1,2,3-Trichloropropane ug/L 54.650 109 60-140
1,2,4-Trichlorobenzene ug/L 57.750 115 60-140
1,2,4-Trimethylbenzene ug/L 51.650 103 60-140
1,2-Dibromo-3-chloropropane ug/L 56.850 114 60-140
1,2-Dibromoethane (EDB)ug/L 53.150 106 60-140
1,2-Dichlorobenzene ug/L 53.150 106 60-140
1,2-Dichloroethane ug/L 44.350 89 60-140
1,2-Dichloropropane ug/L 52.050 104 60-140
1,3,5-Trimethylbenzene ug/L 50.550 101 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 28 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3806705LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichlorobenzene ug/L 52.250 104 60-140
1,3-Dichloropropane ug/L 51.450 103 60-140
1,4-Dichlorobenzene ug/L 50.550 101 60-140
2,2-Dichloropropane ug/L 47.850 96 60-140
2-Chlorotoluene ug/L 44.350 89 60-140
4-Chlorotoluene ug/L 44.350 89 60-140
Benzene ug/L 46.950 94 60-140
Bromobenzene ug/L 51.750 103 60-140
Bromochloromethane ug/L 45.350 91 60-140
Bromodichloromethane ug/L 50.050 100 60-140
Bromoform ug/L 61.550 123 60-140
Bromomethane ug/L 37.750 75 60-140
Carbon tetrachloride ug/L 52.550 105 60-140
Chlorobenzene ug/L 51.950 104 60-140
Chloroethane ug/L 54.550 109 60-140
Chloroform ug/L 43.150 86 60-140
Chloromethane ug/L 43.650 87 60-140
cis-1,2-Dichloroethene ug/L 45.450 91 60-140
cis-1,3-Dichloropropene ug/L 53.550 107 60-140
Dibromochloromethane ug/L 55.650 111 60-140
Dibromomethane ug/L 55.850 112 60-140
Dichlorodifluoromethane ug/L 44.450 89 60-140
Diisopropyl ether ug/L 51.350 103 60-140
Ethylbenzene ug/L 50.450 101 60-140
Hexachloro-1,3-butadiene ug/L 62.150 124 60-140
Isopropylbenzene (Cumene)ug/L 52.550 105 60-140
m&p-Xylene ug/L 103100 103 60-140
Methyl-tert-butyl ether ug/L 49.650 99 60-140
Methylene Chloride ug/L 48.650 97 60-140
n-Butylbenzene ug/L 52.550 105 60-140
n-Propylbenzene ug/L 50.950 102 60-140
Naphthalene ug/L 57.450 115 60-140
o-Xylene ug/L 52.850 106 60-140
sec-Butylbenzene ug/L 50.950 102 60-140
Styrene ug/L 53.650 107 60-140
tert-Butylbenzene ug/L 43.850 88 60-140
Tetrachloroethene ug/L 57.650 115 60-140
Toluene ug/L 48.350 97 60-140
trans-1,2-Dichloroethene ug/L 46.050 92 60-140
trans-1,3-Dichloropropene ug/L 53.750 107 60-140
Trichloroethene ug/L 53.350 107 60-140
Trichlorofluoromethane ug/L 50.650 101 60-140
Vinyl chloride ug/L 46.550 93 60-140
1,2-Dichloroethane-d4 (S)%84 70-130
4-Bromofluorobenzene (S)%97 70-130
Toluene-d8 (S)%96 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 29 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3806706MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92631219002
3806707
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L R150006160-140115 62 305000ND30305760
1,1,1-Trichloroethane ug/L M1,R150005460-140102 62 305000ND26805090
1,1,2,2-Tetrachloroethane ug/L R150006060-140107 56 305000ND30105350
1,1,2-Trichloroethane ug/L M1,R150005960-140108 58 305000ND29505380
1,1-Dichloroethane ug/L M1,R150005460-140103 62 305000ND27105130
1,1-Dichloroethene ug/L M1,R150005760-140104 58 305000ND28705200
1,1-Dichloropropene ug/L R150006160-140113 61 305000ND30305660
1,2,3-Trichlorobenzene ug/L M1,R150005560-140115 71 305000ND27405740
1,2,3-Trichloropropane ug/L M1,R150005960-140103 54 305000ND29705150
1,2,4-Trichlorobenzene ug/L M1,R150005360-140109 70 305000ND26305450
1,2,4-Trimethylbenzene ug/L M1,R150003660-140105 64 305000185036507090
1,2-Dibromo-3-
chloropropane ug/L R150006660-140105 46 305000ND32805240
1,2-Dibromoethane (EDB)ug/L M1,R150005460-140114 54 305000142041007130
1,2-Dichlorobenzene ug/L M1,R150005360-140110 69 305000ND26705500
1,2-Dichloroethane ug/L M1,R150004860-140104 53 305000143038506640
1,2-Dichloropropane ug/L R150006260-140115 59 305000ND31205730
1,3,5-Trimethylbenzene ug/L M1,R150004560-140103 69 30500050227705670
1,3-Dichlorobenzene ug/L M1,R150005260-140106 67 305000ND26205290
1,3-Dichloropropane ug/L M1,R150005960-140109 60 305000ND29305440
1,4-Dichlorobenzene ug/L M1,R150005360-140100 62 305000ND26305010
2,2-Dichloropropane ug/L M1,R150005260-14099 62 305000ND25904930
2-Chlorotoluene ug/L M1,R150005060-140100 66 305000ND25104990
4-Chlorotoluene ug/L M1,R150005060-140100 66 305000ND25104990
Benzene ug/L M1,R15000-228 60-14085 56 305000313002000035600
Bromobenzene ug/L M1,R150005460-140104 63 305000ND26905180
Bromochloromethane ug/L R150006160-140105 53 305000ND30505240
Bromodichloromethane ug/L M1,R150005860-140114 65 305000ND28805690
Bromoform ug/L R150006660-140123 60 305000ND32906140
Bromomethane ug/L M1,R150003460-14075 75 305000ND16903730
Carbon tetrachloride ug/L R150006260-140117 61 305000ND31105860
Chlorobenzene ug/L M1,R150005860-140110 62 305000ND29105510
Chloroethane ug/L R150006160-140109 56 305000ND30705470
Chloroform ug/L M1,R150005360-14099 60 305000ND26604970
Chloromethane ug/L M1,R150005360-14097 59 305000ND26404860
cis-1,2-Dichloroethene ug/L M1,R150005760-140106 61 305000ND28405320
cis-1,3-Dichloropropene ug/L R150006060-140116 64 305000ND29905790
Dibromochloromethane ug/L M1,R150005860-140112 63 305000ND29105610
Dibromomethane ug/L R150006860-140118 54 305000ND33805910
Dichlorodifluoromethane ug/L M1,R150005160-14097 61 305000ND25704860
Diisopropyl ether ug/L M1,R150001960-140122 60 3050004970595011100
Ethylbenzene ug/L M1,R150003060-140109 64 305000264041608070
Hexachloro-1,3-butadiene ug/L M1,R150005760-140118 69 305000ND28705890
Isopropylbenzene(Cumene)ug/L M1,R150005660-140116 70 305000ND27905790
m&p-Xylene ug/L M1,R1100001260-140111 63 301000095901080020700
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 30 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3806706MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92631219002
3806707
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Methyl-tert-butyl ether ug/L R150006160-140112 58 305000ND30905640
Methylene Chloride ug/L R150006260-140116 60 305000ND31005790
n-Butylbenzene ug/L M1,R150005260-140103 66 305000ND25905130
n-Propylbenzene ug/L M1,R150005060-140103 65 30500022827405370
Naphthalene ug/L M1,R150004860-140108 63 30500079532006170
o-Xylene ug/L M1,R150001460-140114 64 3050004560528010200
sec-Butylbenzene ug/L M1,R150005260-140104 67 305000ND25805180
Styrene ug/L M1,R150005260-140112 67 30500033729605920
tert-Butylbenzene ug/L M1,R150004560-14090 67 305000ND22604510
Tetrachloroethene ug/L R150006060-140117 64 305000ND29905830
Toluene ug/L M1,R15000-288 60-14072 56 305000373002290040900
trans-1,2-Dichloroethene ug/L M1,R150005660-140106 61 305000ND28105290
trans-1,3-Dichloropropene ug/L M1,R150005860-140112 63 305000ND28905580
Trichloroethene ug/L R150006160-140118 64 305000ND30405920
Trichlorofluoromethane ug/L R150006060-140108 58 305000ND29805410
Vinyl chloride ug/L M1,R150005660-140106 62 305000ND28005290
1,2-Dichloroethane-d4 (S)%96 70-13094
4-Bromofluorobenzene (S)%98 70-130101
Toluene-d8 (S)%96 70-13097
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 31 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
730311
SM 2540D-2015
SM 2540D-2015
2540D Total Suspended Solids
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92630913001, 92630913002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3802703
Associated Lab Samples:92630913001, 92630913002
Matrix:Water
AnalyzedMDL
Total Suspended Solids mg/L ND 2.5 10/14/22 13:292.5
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3802704LABORATORY CONTROL SAMPLE:
LCSSpike
Total Suspended Solids mg/L 238250 95 90-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92631117001
3803054SAMPLE DUPLICATE:
Total Suspended Solids mg/L 322 9 25294
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92630797002
3803055SAMPLE DUPLICATE:
Total Suspended Solids mg/L 1080 1 251100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 32 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
730557
SM 2540D-2015
SM 2540D-2015
2540D Total Suspended Solids
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92630913009, 92630913010
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3803920
Associated Lab Samples:92630913009, 92630913010
Matrix:Water
AnalyzedMDL
Total Suspended Solids mg/L ND 2.5 10/15/22 17:012.5
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3803921LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
3803924
Total Suspended Solids mg/L 256250 102 90-110104260 2 25
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92630913009
3803925SAMPLE DUPLICATE:
Total Suspended Solids mg/L 198 15 25231
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 34 of 38
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92630913
Crown Food Mart 10/12
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92630913001 730956 731076EF-14 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92630913002 730956 731076INF-14 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92630913003 730956 731076EW-2 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92630913004 730956 731076EW-3 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92630913005 730956 731076EW-4 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92630913006 730956 731076EW-5 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92630913008 730956 731076DUP (Fe)EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92630913001 730313EF-14 SM 6200B
92630913002 731239INF-14 SM 6200B
92630913003 730313EW-2 SM 6200B
92630913004 730313EW-3 SM 6200B
92630913005 731239EW-4 SM 6200B
92630913006 731239EW-5 SM 6200B
92630913007 731239DUP (VOC)SM 6200B
92630913009 730313POTW-INF-14 SM 6200B
92630913010 730313POTW-EF-14 SM 6200B
92630913001 730311EF-14 SM 2540D-2015
92630913002 730311INF-14 SM 2540D-2015
92630913009 730557POTW-INF-14 SM 2540D-2015
92630913010 730557POTW-EF-14 SM 2540D-2015
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/21/2022 05:31 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
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