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HomeMy WebLinkAbout24001 REEP-LRC II Additional Assessment Report_20210603#C-1269 Engineering #C-245 Geology Additional Brownfields Assessment Report REEP-LRC II 1900 & 1942 Continental Boulevard Charlotte, Mecklenburg County, North Carolina Brownfields Project No. 24001-20-060 H&H Job No. SSP-001 June 3, 2021 6/3/21 i Additional Brownfields Assessment Report REEP-LRC II 1900 & 1942 Continental Boulevard Charlotte, North Carolina Brownfields Project No. 24001-20-060 H&H Job No. SSP-001 Table of Contents 1.0 Introduction .............................................................................................................................1 2.0 Historical Assessment Activities (PIN 20308301) .................................................................3 3.0 Sub-Slab Vapor Assessment Activities .................................................................................5 3.1 Sub-Slab Vapor Sampling Methodology ...............................................................................5 3.2 Sub-Slab Vapor Sampling Analytical Results .......................................................................7 3.3 DEQ DWM Risk Calculations ..............................................................................................7 4.0 Summary and Conclusions.....................................................................................................9 List of Tables Table 1 Summary of Sub-Slab Vapor Analytical Data List of Figures Figure 1 Site Location Map Figure 2 Sample Location Map List of Appendices Appendix A Sub-Slab Vapor QA/QC Field Forms Appendix B Laboratory Analytical Report Appendix C DEQ Risk Calculator (January 2021) 1 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Somerset Properties (SSP)/Continental Tire (SSP-001)/Brownfields Assessment/Report/final to DEQ/Additional Assessment Report_REEP-LRC II.doc Additional Brownfields Assessment Report REEP-LRC II 1900 & 1942 Continental Boulevard Charlotte, North Carolina Brownfields Project No. 24001-20-060 H&H Job No. SSP-001 1.0 Introduction Hart & Hickman, PC (H&H) has prepared this Additional Brownfields Assessment Report on behalf of SPWF-Continental Warehouse, LLC for the REEP-LRC II Brownfields property (Brownfields Project No. 24001-20-060). The Brownfields property is located at 1900 and 1942 Continental Boulevard in Charlotte, Mecklenburg County, North Carolina (Site) and consists of four parcels of land that total approximately 118.74 acres. Specifically, the Site is located at 1900 Continental Boulevard (Mecklenburg County Parcel Identification Number [PIN] 20308301), a parcel east of 1900 Continental Boulevard with no established address (PIN 20308305), 1942 Continental Boulevard (PIN 20308306), and a parcel east of Interstate I-485 with no established address (PIN 20302139). A Brownfields agreement for Site PIN 20308305 between the North Carolina Department of Environmental Quality (DEQ) and the former PD was executed on July 24, 2020 under Brownfields Project No. 17047-13-060. A Site location map is provided as Figure 1. The Brownfields property and surrounding area was formerly occupied by the United States Navy from approximately 1949 through 1967. Former use of the Site as a Naval Ammunitions Depot (NAD) included operations consisting of numerous buildings surrounded by protective soil berms based on a 1950 aerial photograph and a 1950 map of the former NAD. Following NAD operations, the Site was occupied by Continental Tire and used for tire manufacturing from 1967 through 2013. Proposed redevelopment for the Brownfields property includes installation of a pre-fabricated fire pump house in the southwestern portion of the Site (PIN 20308301), renovations to the northwestern portion of the existing warehouse building (PIN 20308301), installation of a new road that will circulate existing structures on PIN 20308301 and allow access to future 2 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Somerset Properties (SSP)/Continental Tire (SSP-001)/Brownfields Assessment/Report/final to DEQ/Additional Assessment Report_REEP-LRC II.doc development on PIN 20308305, and installation of an approximately 333,000 square foot (sq ft) building with associated parking, access drives, and a stormwater retention pond (PIN 20308305). The existing warehouse building located on PIN 20308301 is currently divided into four tenant spaces. The northern tenant space is currently vacant. The central portion of the building is occupied by Snyder’s Lance, Inc. and utilized for warehousing and distribution of food products. The southeastern portion of the building is occupied by Deufol Charlotte, LLC (Deufol) and is utilized for the manufacturing and distribution of packaging and shipping materials. The southwestern portion of the building is occupied by SnapAV an electronics manufacturer and distributor. There are no current redevelopment plans for PINs 20308306 and 20302139. A Site location map is provided as Figure 1, and the Site and redevelopment plans are shown on Figure 2. SPWF-Continental Warehouse, LLC received eligibility into the DEQ Brownfields Program via a Letter of Eligibility dated February 27, 2020. On September 24, 2020, H&H, the PD, and the PD’s legal counsel participated in a conference call with DEQ Brownfields personnel to discuss Site history, areas of potential environmental concern, proposed redevelopment plans, potential data gaps, and the scope of Brownfields assessment activities needed to address the data gaps. To address DEQ’s request for additional assessment on PINs 20308301 and 20302139, H&H submitted an Additional Brownfields Assessment Work Plan (Work Plan) dated November 19, 2020, and revised on February 4, 2021. The Work Plan was approved by DEQ Brownfields in an email dated February 19, 2021. This report documents vapor intrusion assessment activities conducted within the existing warehouse building located on PIN 20308301. Assessment activities proposed for PIN 20302139 will be conducted at a later date and documented under separate cover. A summary of historical assessment activities conducted on PIN 20308301 and recently completed vapor intrusion assessment activities for PIN 20308301 are provided in the following sections. 3 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Somerset Properties (SSP)/Continental Tire (SSP-001)/Brownfields Assessment/Report/final to DEQ/Additional Assessment Report_REEP-LRC II.doc 2.0 Historical Assessment Activities (PIN 20308301) Multiple phases of environmental assessments have been conducted at the Brownfields property since 2007. The assessments were conducted under the purview of the DEQ Underground Storage Tank (UST) Section, Inactive Hazardous Sites Branch (IHSB), and the Brownfields Program. Known releases associated with PIN 20308301 include the former Wash Rack area (UST Section No Further Action status in June 2010), the former Boiler Day Tanks area (UST Section No Further Action status in June 2010), the former Naphtha UST area (UST Section Conditional No Further Action status and Notice of Residual Petroleum filed in 2003), the former Rail Off-Loading Area (UST Section Conditional No Further Action status in January 2020), and the former Buffing Dust Shed (active IHSB incident). H&H understands that Continental Tire is identified by DEQ as the responsible party for the active Buffing Dust Shed IHSB incident, and that ongoing off-Site vapor intrusion assessment activities are currently underway. Historical soil assessment activities completed on PIN 20308301 in 2009 to assess conditions associated with the former Buffing Dust Shed indicate low levels of several volatile organic compounds (VOCs) were detected in surficial soil samples at concentrations above laboratory detection limits, but below the DEQ Industrial/Commercial Preliminary Soil Remediation Goals (PSRGs). In addition, low levels of several metals were detected at concentrations above the laboratory method detection limits, but aside from arsenic (up to 5.5 milligrams per kilogram [mg/kg]), no metals were detected at concentrations above the DEQ Industrial/Commercial PSRGs. Concentrations of arsenic and other metals are consistent with published background ranges in the Site region. Historical groundwater assessment activities conducted on PIN 20308301 dating back to 2009 have identified the presence of multiple compounds at concentrations above the DEQ 15A North Carolina Administrative Code (NCAC) 02L .0202 Groundwater Quality Standards (2L Standards). Compounds detected above 2L Standards include, but are not limited to, iron and manganese, polycyclic aromatic hydrocarbons (PAHs), and VOCs benzene, 1,1-dichloroethane, 1,2-dichloroethane, carbon tetrachloride, tetrachloroethylene (PCE), trichloroethylene (TCE), 4 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Somerset Properties (SSP)/Continental Tire (SSP-001)/Brownfields Assessment/Report/final to DEQ/Additional Assessment Report_REEP-LRC II.doc and vinyl chloride. As part of property transaction due diligence conducted on PIN 20308301 in November 2019, H&H performed sampling activities to assess potential structural vapor intrusion into the existing warehouse building. Specifically, the vapor intrusion assessment activities included installation and sampling of nine sub-slab vapor points in the Deufol tenant space (SS-6 through SS-9) and a vacant tenant space (SS-3 through SS-5) due to their proximity to documented soil and groundwater impacts associated with the aforementioned UST and IHSB incidents. Two sub- slab vapor points (SS-1 and SS-2) were also installed in the northwestern portion of the warehouse building where former tire sealant operations were conducted. The vapor intrusion assessment activities were conducted in accordance with DEQ Division of Waste Management (DWM) Vapor Intrusion Guidance (VI Guidance) dated March 2018. Laboratory analytical results indicated that low levels of VOCs were detected above laboratory method detection limits in each sub-slab vapor sample. Of the compounds detected, 1,1- dichloroethane was detected at a concentration that exceeds the January 2021 Non-Residential Sub-Slab and Exterior Soil Gas Screening Level (SGSL) of 770 micrograms per cubic meter (µg/m3) in sub-slab vapor sample SS-9 (2,200 µg/m3) in the administrative office area. No other compounds were detected above Non-Residential SGSLs. In addition, DEQ risk calculator results indicated calculated cumulative risks for a non-residential worker are within the acceptable carcinogenic risk of less than 1 x 10-4 and less than a hazard index of 1. H&H further evaluated the potential for vapor intrusion utilizing groundwater data from monitoring wells installed under or within 100 ft of the Site building. Based on comparison of groundwater analytical data to the February 2018 DEQ Non-Residential Ground Water Screening Levels (GWSLs), no exceedances were identified except for a concentration of cyclohexane (2,000 micrograms per liter [µg/L]) detected in MW002 in March 2015. The cyclohexane concentration was above its DWM Non-Residential GWSL of 860 µg/L. However, cyclohexane was not detected above laboratory reporting limits in any of the nine sub-slab vapor samples. As such, cyclohexane in groundwater does not appear to pose a vapor intrusion risk. 5 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Somerset Properties (SSP)/Continental Tire (SSP-001)/Brownfields Assessment/Report/final to DEQ/Additional Assessment Report_REEP-LRC II.doc 3.0 Sub-Slab Vapor Assessment Activities On March 9, 2021, H&H completed sub-slab vapor sampling activities at the Site to further evaluate the potential for structural vapor intrusion into the warehouse building on PIN 20308301. During the event, three (3) temporary sub-slab vapor monitoring points (SS-10 through SS-12) were installed and sampled in the loading dock area of the Deufol tenant space. The sub-slab vapor sample locations (denoted by SS nomenclature) are shown in Figure 2. Details of the sub-slab vapor assessment activities and results are provided in the following sections. 3.1 Sub-Slab Vapor Sampling Methodology The sub-slab vapor monitoring points were installed by utilizing a hammer drill and 1½-inch diameter drill bit to advance a pilot hole into the concrete slab to a depth of approximately 1¾ inches below the surface. A drill guide was then placed in the pilot hole, and a 5/8-inch diameter drill bit was utilized to advance the boring through the concrete slab. Following concrete borehole advancement, loose concrete cuttings were removed from the boring using a bottlebrush and vacuum with a high efficiency particulate air (HEPA) filter. A Cox-Colvin Vapor Pin™ (vapor pin) assembly (brass sampling point and silicone sleeve) was seated in the borehole using an installation/extraction tool and hammer. Once the vapor pin assembly was secured in the pilot hole, ¼-inch diameter Teflon® sample tubing was attached to the vapor pin assembly sample port barb. Prior to sampling, sub-slab vapor monitoring points were allowed to equilibrate for at least two hours following installation. As part of sub-slab vapor sample collections procedures, “shut-in” tests and leak checks were performed at each sub-slab vapor monitoring point. The purpose of the shut-in test and helium leak check is to ensure that short circuiting with ambient air does not occur during sampling. A description of the shut-in test and helium leak testing procedures is provided below. The shut-in test was conducted by connecting an in-line airflow controller with a vacuum gauge to a laboratory supplied batch-certified 1-liter stainless steel Summa® canister and sealing the flow regulator with a laboratory provided brass nut and ferrule assembly to form an air-tight seal. 6 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Somerset Properties (SSP)/Continental Tire (SSP-001)/Brownfields Assessment/Report/final to DEQ/Additional Assessment Report_REEP-LRC II.doc The airflow regulator was pre-set by the laboratory to regulate the sub-slab vapor intake rate to approximately 200 milliliters per minute. Once the sampling train was “closed”, the sample valve on the Summa® canister was opened and the reading on the vacuum gauge was recorded. The Summa® canister sample valve was then closed, and the vacuum gauge was observed to ensure no vacuum loss occurs. Because the vacuum readings remained the same before and after closure of the canister sample valve, the shut-in tests were considered successful for each sub- slab vapor point. Following successful shut-in tests, leak checks were conducted by constructing a shroud around the sample train at each sampling point and flooding the air with helium gas. Helium concentrations inside the shroud were measured using a calibrated helium gas detector and maintained at concentrations of approximately 15% to 30% for the duration of the leak check. Using a syringe and three-way valve, a helium sample was collected from the Teflon® sample tubing outside the shroud and into a Tedlar bag. The helium sample was analyzed using the helium gas detector to ensure that helium concentrations were less than 10% of the helium concentrations measure within the shroud. All of the sub-slab vapor monitoring points passed the leak check. Following a successful leak check, the intake valve on the Summa® canister was fully opened to begin collection of the sub-slab vapor sample. Vacuum readings on the Summa® canister were recorded prior to and following the sampling period to ensure adequate sample volume was collected. Per laboratory standard operating procedures, a vacuum of between approximately three and seven inches of mercury was maintained on the sample canister until the conclusion of the sampling event. Laboratory provided vacuum gauges used for collection of field measurements are intended for qualitative field use. As such, field measured pre- and post- sampling vacuum readings are not expected to impact laboratory analytical results based on other considerations such as sub-slab vapor sampling procedures (i.e., shut-in tests and leak checks) and post-sampling canister pressures measured by the laboratory. Therefore, H&H concludes that field and laboratory data generally meet project objectives and are usable for the intended purpose. 7 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Somerset Properties (SSP)/Continental Tire (SSP-001)/Brownfields Assessment/Report/final to DEQ/Additional Assessment Report_REEP-LRC II.doc After sample collection, the Summa® canister sample valves were closed prior to disassembly of the sampling train. The Summa® canisters were then placed in laboratory supplied shipping containers, properly labeled, and shipped under standard chain-of-custody protocols to Con-test for analysis of VOCs by EPA Method TO-15. For quality assurance/quality control (QA/QC) purposes, a duplicate sub-slab vapor sample (SS-DUP) was collected from sub-slab vapor monitoring point SS-10. Upon receipt of the samples, the laboratory recorded the final received vacuum pressure for each Summa canister. The initial, post-sampling, and lab receipt canister vacuum pressures are indicated on the sub-slab vapor QA/QC field forms in Appendix A and in the laboratory analytical reports included in Appendix B. Upon completion of the final sampling event, the sub-slab vapor sampling point locations were estimated in the field using known benchmarks (i.e., walls, doors, etc.) and then abandoned to match surrounding surface conditions. 3.2 Sub-Slab Vapor Sampling Analytical Results A tabular summary of the November 2019 and March 2021 sub-slab vapor sample analytical results is presented in Table 1. The laboratory analytical report and chain of custody record for the March 2021 are provided in Appendix B. Sub-slab vapor sample analytical results were compared to the January 2021 DEQ Non-Residential SGSLs. Laboratory analytical results indicate that low levels of VOCs were detected above laboratory method detection limits, but below Non-Residential SGSLs, in each sub-slab vapor sample. In addition, 1,1-dichloroethane, a compound that was previously detected at a concentration above the Non-Residential SGSL, was not detected above laboratory method detection limits during the March 2021 sampling event. 3.3 DEQ DWM Risk Calculations The DEQ DWM SGSLs are conservative and based on a lifetime incremental cancer risk (LICR) for potential carcinogenic risks of 1 x 10-6 and a non-carcinogenic hazard quotient (HQ) of 0.2 8 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Somerset Properties (SSP)/Continental Tire (SSP-001)/Brownfields Assessment/Report/final to DEQ/Additional Assessment Report_REEP-LRC II.doc for potential non-carcinogenic risks. The DEQ acceptable risk level for potential carcinogenic risks is 1 x 10-4 or less and the acceptable level for non-carcinogenic risks is a hazard index (HI) less than 1. H&H utilized the January 2021 DEQ risk calculator and a non-residential land use scenario (based on the current and future use in the warehouse at the Site) to evaluate calculated cumulative risks for the soil gas (i.e., sub-slab vapor) to indoor air vapor intrusion pathway in the Deufol tenant space. H&H calculated cumulative risks using the highest concentrations of compounds detected in any sub-slab vapor sample collected during the November 2019 and/or March 2021 sampling events to check a hypothetical worst-case scenario. Results of the risk calculations are provided in Table 1, summarized below, and included in Appendix C. Sub-Slab Vapor Sample Location Non-Residential Worker Carcinogenic Risk Hazard Index Deufol Tenant Space 4.5 x 10-6 0.28 As shown in the table above, calculated cumulative risks for a non-residential worker are within the acceptable carcinogenic risk of less than 1 x 10-4 and less than a hazard index of 1. 9 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Somerset Properties (SSP)/Continental Tire (SSP-001)/Brownfields Assessment/Report/final to DEQ/Additional Assessment Report_REEP-LRC II.doc 4.0 Summary and Conclusions H&H has completed vapor intrusion assessment activities for the warehouse building (PIN 20308301) of the REEP-LRC II Brownfields property located in Charlotte, North Carolina. The assessment activities were conducted to further evaluate potential structural vapor intrusion into the Deufol tenant space as requested by DEQ Brownfields. Results of sub-slab vapor assessment activities indicate that calculated cumulative risk values for the soil gas to indoor air vapor intrusion pathway are within the acceptable carcinogenic risk of less than 1 x 10-4 and less than a hazard index of 1. In summary, results of soil vapor intrusion assessment activities indicate that structural vapor intrusion into the Deufol tenant space does not pose a significant risk for typical commercial or industrial uses (i.e., those without sensitive populations). Based on the results of the sub-slab vapor samples, risk calculations, and previous groundwater data review, H&H does not recommend mitigation measures or further assessment for the Deufol tenant space at this time. Table 1 Summary of Sub-Slab Vapor Analytical Data REEP-LRC II 1900 1942 Continental Blvd. Charlotte, North Carolina H&H Job No. SSP-001 SS-5 SS-DUP SS-10 SS-DUP Sample Date 11/1/2019 11/1/2019 11/1/2019 11/1/2019 11/1/2019 11/1/2019 11/1/2019 11/1/2019 11/1/2019 11/1/2019 3/9/2021 3/9/2021 3/9/2021 3/9/2021 Former Mixing and Application Area Former Bulk Chemical Storage Area Administrative Office Area Bulk Storage Area Bulk Storage Area Climate Controlled Storage Area Bulk Storage Area Administrative Office Area Acetone 2,700,000 190 26 26 300 <66 <66 51 30 580 81 67 78 370 820 Benzene 160 0.32 J <0.26 0.31 J 4.5 <2.6 <2.6 <0.26 0.27 J 3.3 2.9 0.98 <0.19 <0.19 2.2 Carbon disulfide 61,000 1.2 J <0.43 4.7 J 8.4 <4.3 <4.3 <0.43 4.6 J 4.9 J 6.4 <1.6 <1.6 <1.6 <1.6 Chloroform 53 <0.36 <0.36 0.51 J <0.36 <3.6 <3.6 <0.36 <0.36 <0.36 2.3 4.4 5.1 7.1 4.2 Dichlorodifluoromethane (Freon 12) 8,800 2.7 2.8 2.7 <0.43 <4.3 <4.3 2.7 2.7 <0.43 2.9 <0.31 <0.31 <0.31 <0.31 1,1-Dichloroethane 770 <0.25 <0.25 4.3 <0.25 <2.5 <2.5 <0.25 <0.25 <0.25 2,200 <0.25 <0.25 <0.25 <0.25 1,1-Dichloroethylene 18,000 <0.43 <0.43 3.8 <0.43 160 170 <0.43 <0.43 <0.43 2,200 <0.43 <0.43 <0.43 <0.43 cis-1,2-Dichloroethylene NE <0.32 <0.32 20 <0.32 <3.2 <3.2 <0.32 <0.32 <0.32 <0.32 <0.27 <0.27 <0.27 6.9 trans-1,2-Dichloroethylene 3,500 <0.32 <0.32 0.76 J <0.32 <3.2 <3.2 <0.32 <0.32 <0.32 <0.32 <0.23 <0.23 <0.23 <0.23 1,4-Dioxane 250 25 <4.6 <4.6 <4.6 <46 <46 <4.6 <4.6 <4.6 7.0 J <2.0 <2.0 16 14 Ethanol NE 240 790 250 330 130 J 140 J 160 170 210 2,000 350 430 810 1,200 Ethyl Acetate 6,100 <0.54 <0.54 <0.54 <0.54 <5.4 <5.4 <0.54 <0.54 <0.54 2.9 <4.3 <4.3 <4.3 <4.3 Ethylbenzene 490 <0.50 <0.50 <0.50 1.4 <5.0 <5.0 <0.50 0.71 J 30 0.83 J 4.5 5.5 5.9 4.0 4-Ethyltoluene NE <0.60 <0.60 <0.60 0.90 J <6.0 <6.0 <0.60 <0.60 4.5 3.1 2.2 <0.30 <0.30 <0.30 Heptane 35,000 <0.48 <0.48 <0.48 5.5 <4.8 <4.8 <0.48 <0.48 <0.48 0.70 J <0.35 <0.35 <0.35 <0.35 Hexane 61,000 <1.2 <1.2 <1.2 2.1 J <12 <12 <1.2 <1.2 <1.2 <1.2 <1.3 5.0 J <1.3 <1.3 2-Hexanone (Methyl butyl ketone) 2,600 <0.49 <0.49 <0.49 5.4 <4.9 <4.9 <0.49 <0.49 <0.49 <0.49 <0.46 <0.46 <0.46 <0.46 Isopropanol 18,000 13 J 7.6 J 7.1 J 40 <9.0 <9.0 13 J 10 J <0.90 140 58 40 130 74 Methyl ethyl ketone (2-Butanone) 440,000 3.9 J 5.9 J 5.5 J 33 <11 <11 4.9 J 4.2 J 21 J 8.4 J <2.0 6.8 J 20 J 45 4-Methyl-2-pentanone (MIBK) 260,000 3.8 6.2 <0.43 7.8 <4.3 <4.3 <0.43 1.9 14 <0.43 <0.43 <0.43 <0.43 <0.43 Naphthalene 36 0.88 J <0.80 <0.80 <0.80 <8.0 <8.0 <0.80 <0.80 18 <0.80 <0.59 <0.59 <0.59 11 Styrene 88,000 <0.53 <0.53 <0.53 0.72 J <5.3 <5.3 <0.53 <0.53 <0.53 <0.53 <0.24 <0.24 <0.24 <0.24 Tetrachloroethylene 3,500 11 12 6.1 25 280 310 64 16 2,500 52 50 55 1,500 240 Tetrahydrofuran 180,000 1.8 J <0.59 <0.59 <0.59 <5.9 <5.9 <0.59 <0.59 <0.59 2.5 <1.5 <1.5 <1.5 <1.5 Toluene 440,000 0.78 <0.39 0.50 J 7.9 <3.9 <3.9 <0.39 0.56 J 73 3.7 7.4 7.8 16 8.2 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 440,000 <1.2 <1.2 <1.2 <1.2 <12 <12 <1.2 1.7 J 3.6 J 7.7 <1.2 <1.2 <1.2 <1.2 1,1,1-Trichloroethane 440,000 0.50 J 1.1 0.46 J 2.6 15,000 15,000 0.68 J <0.41 12 2.2 <0.36 <0.36 6.5 7.4 Trichloroethylene 180 4.3 <0.43 12 1.6 <4.3 <4.3 1.1 J 4.5 23 20 <0.40 <0.40 4.4 69 Trichlorofluoromethane (Freon 11) NE 5.3 13 9.1 26 100 120 3.7 J 2.5 J 11 1.7 J 8.5 9.4 13 3.9 J 1,2,4-Trimethylbenzene 5,300 <0.63 <0.63 <0.63 <0.63 <6.3 <6.3 <0.63 <0.63 17 <0.63 9.6 11 4.1 6.4 1,3,5-Trimethylbenzene 5,300 <0.62 <0.62 <0.62 1.0 <6.2 <6.2 <0.62 <0.62 5.2 6.4 4.9 5.7 1.0 1.7 Vinyl chloride 280 <0.32 <0.32 <0.32 <0.32 <3.2 <3.2 <0.32 <0.32 <0.32 1.5 <0.29 <0.29 <0.29 <0.29 m-/p-Xylenes 8,800 1.4 J <1.0 <1.0 2.7 <10 <10 <1.0 2.8 99 2.5 25 28 18 12 o-Xylene 8,800 <0.54 <0.54 <0.54 1.4 <5.4 <5.4 <0.54 1.0 30 1.0 10 11 5.9 4.7 Risk Evaluation (Soil Gas to Indoor Air)(2) Non-Residential Carcinogenic Risk -- Non-Residential Hazard Index -- Notes: Bold and underlined concentrations and yellow highlighting indicates concentration exceeds Non-Residential SGSLs (January 2021). VOCs (TO-15) (µg/m3) Non-Residential SGSLs1 SS-11 SS-12Sample ID Sample Location (PIN 20308301) Former Continental Tire North America Vacant Tenant Space Deufol Tenant Space J = compound was detected above the laboratory method detection limit but below the laboratory reporting limit resulting in an estimated concentration. Only compounds with at least one detection above laboratory method detection limits limits are shown on this table. Compound concentrations are reported in micrograms per cubic meter (μg/m3). Laboratory analytical method is shown in parentheses. VOCs = volatile organic compounds; NE= Not Established; < = less than laboratory method detection limits; -- = Not Applicable 2) Risk evaluation performed using the January 2021 DEQ Risk Calculator for the soil gas to indoor air vapor intrusion pathway. 1) NC Department of Environmental Quality Sub-Slab and Exterior Soil Gas Screening Levels (SGSLs) (January 2021). SS-10SS-1 SS-2 SS-3 SS-4 SS-6 SS-7 SS-8 SS-9 SS-5 Forklift Maintenance Area 4.5E-06 0.28 Loading Dock Area https://harthick.sharepoint.com/sites/MasterFiles‐1/Shared Documents/AAA‐Master Projects/Somerset Properties (SSP)/Continental Tire (SSP‐001)/Brownfields Assessment/Tables/MASTER TABLE 2021‐03.xlsx 6/3/2021 Table 1 (Page 1 of 1) Hart & Hickman, PC Copyright:© 2013 National Geographic Society, i-cubed SITE LOCATION MAP REEP-LRC II1900 CONTINENTAL BOULEVARD CHARLOTTE, NORTH CAROLINA DATE: 5-21-20 JOB NO: SSP-001 REVISION NO: 0 FIGURE NO: 1 2923 South Tryon Street - Suite 100Charlotte, North Carolina 28203704-586-0007 (p) 704-586-0373 (f)License # C-1269 / # C-245 Geology TITLE PROJECT 0 2,000 4,000 SCALE IN FEET SITE Pa t h : S : \ A A A - M a s t e r P r o j e c t s \ S o m e r s e t P r o p e r t i e s ( S S P ) \ C o n t i n e n t a l T i r e ( S S P - 0 0 1 ) \ B r o w n f i e l d s A p p l i c a t i o n \ F i g u r e s \ F i g u r e - 1 . m x d N U.S.G.S. QUADRANGLE MAP CHARLOTTE WEST, NORTH CAROLINA 2013 QUADRANGLE7.5 MINUTE SERIES (TOPOGRAPHIC) SS-1 SS-2 SS-3 SS-4 SS-5 SS-6 SS-7 SS-8 SS-9 SB-10 SB-2/ VMP-2 SB-1/ VMP-1 SB-3/ VMP-3 SB-5/ VMP-5 SB-4/ VMP-4 SB-6/ VMP-6 SB-7/ VMP-7 SB-8/ VMP-8 SB-9 TMW-1 TMW-2 TMW-3 TMW-4 ASH-1 MW001 MW001D MW002MW EW2 MW002D MW EW1 MW005 MW006 MW007 MW004 MW008 MW009 MW003 S-5 S-7 S-4 S-6 S-1 S-3 S-2 S-8 S-9 BASE-3 BASE-2 BASE-1 SS-12 SS-11 SS-10 REVISION NO. 0 LEGEND REEP-LRC BROWNFIELDS PROPERTY BOUNDARY RAILROAD SPURS SURFACE WATER FEATURE APPROXIMATE LOCATION OF FORMER RELEASE/ IMPACTED AREA PROPOSED REDEVELOPMENT PROJECT PROPOSED CIRCULATION ROAD PERMANENT MONITORING WELL LOCATION (INSTALLED / SAMPLED BY OTHERS) TEMPORARY MONITORING WELL LOCATION (H&H, 2016 & 2018) SOIL BORING LOCATION (H&H, 2016 & 2018) WASTE AND SURFACE SOIL SAMPLE LOCATIONS (H&H, 2015) WASTE AND CONFIRMATION SOIL SAMPLE LOCATIONS (H&H, 2016 & 2018) CO-LOCATED SOIL BORING / SUB-SLAB VAPOR SAMPLE LOCATION (H&H, 2016 & 2018) SUB-SLAB VAPOR SAMPLE LOCATION (H&H, 2019 & 2021) JOB NO. SSP-001 DATE: 4-1-21 FIGURE NO. 2 REEP-LRC II 1900 CONTINENTAL BOULEVARD CHARLOTTE, NORTH CAROLINA SAMPLE LOCATION MAP NOTES: 1. AERIAL IMAGERY OBTAINED FROM MECKLENBURG COUNTY GIS (2020). 2. NFA = NO FURTHER ACTION 3. PIN = MECKLENBURG COUNTY PARCEL IDENTIFICATION NUMBER 4. * INDICATES ADDITIONAL BURIED WASTE PRESENT THAT WAS NOT REMOVED. 5. SOIL SAMPLES S-2 AND S-3 REMOVED DURING EXCAVATION ACTIVITIES COMPLETED IN 2016. PIONEER AVENUE CO N T I N E N T A L B O U L E V A R D II N T E R S T A T E - 4 8 5 DUKE ENERGY PROPERTY FORMER WASH RACKS (NFA 6/24/10) PETROLEUM FREE PRODUCT IN MW-2 (2013)FORMER BOILER DAY TANKS (NFA 6/24/10) FORMER BUFFING DUST SHED- CHLORINATED VOCs IN SOIL & GROUNDWATER FORMER RAIL OFF-LOADING- CHLORINATED VOCs IN GROUNDWATER; IMPACTED SOIL MOSTLY REMOVED (CONDITIONAL NFA 1/27/20) FORMER NAPHTHA UST NFA - NORP (SOIL & GROUNDWATER 2003) FORMER CONTINENTAL TIRE NORTH AMERICA VACANT SNAP A.V. DEUFOL CHARLOTTE, LLC OFFICES OFFICE CLIMATE CONTROLLED STORAGE AREA 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology PIN 20308306 (1942 CONTINENTAL BOULEVARD) PIN 20308301 (1900 CONTINENTAL BOULEVARD) PIN 20308305 (NO ESTABLISHED ADDRESS) PIN 20302139 (NO ESTABLISHED ADDRESS) FORMER NO. 6 FUEL AST (NFA 12/14/09) LOCATION OF WASTE DRUMS (REMOVED)* LOCATION OF ADDITIONAL DEBRIS REMOVAL ZINC / BURNED RUBBER LOCATION (REMOVED) LOADING DOCK PROJECT FIRE LINE PROJECT PREMIER REDEVELOPMENT PROJECT BUILDING FOOTPRINT FORMER TIRE SEALANT MIXING AND APPLICATION FORMER TIRE SEALANT BULK CHEMICAL STORAGE PROPOSED STORMWATER POND FORMER ROAD LOCATION OF BERMED AREA FOUND DURING 2018 SITE RECON SU G A R C R E E K COF F E Y C R E E K U:\ A A A - M a s t e r P r o j e c t s \ L R C P a t r i o t ( L R C ) \ L R C - 0 0 8 V I A s s e s s m e n t \ R e p o r t \ F i g u r e s \ S S P . 0 0 1 _ 2 0 2 1 0 4 0 1 . d w g , F I G 2 , 4 / 1 / 2 0 2 1 6 : 4 8 : 1 2 A M , s h a y n e s Appendix A Sub-Slab Vapor QA/QC Field Forms Appendix B Laboratory Analytical Reports 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 March 19, 2021 Jeffrey Ollison Hart & Hickman - Charlotte, NC 2923 South Tryon Street, Suite 100 Charlotte, NC 28203 Project Location: 1900 Continental Blvd, Charlotte, NC Client Job Number: Project Number: SSP-001 Laboratory Work Order Number: 21C0636 Enclosed are results of analyses for samples received by the laboratory on March 11, 2021. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kerry K. McGee Project Manager QA Officer Katherine Allen Laboratory Manager Daren Damboragian Page 1 of 26 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL SUMMARY 3/19/2021Hart & Hickman - Charlotte, NC 2923 South Tryon Street, Suite 100 Charlotte, NC 28203 ATTN: Jeffrey Ollison SSP-001 21C0636 The results of analyses performed on the following samples submitted to Con-Test, a Pace Analytical Laboratory, are found in this report. PROJECT LOCATION: PURCHASE ORDER NUMBER: PROJECT NUMBER: REPORT DATE: WORK ORDER NUMBER: FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB 1900 Continental Blvd, Charlotte, NC SSP-001 SS-10 21C0636-01 Sub Slab EPA TO-15 SS-11 21C0636-02 Sub Slab EPA TO-15 SS-12 21C0636-03 Sub Slab EPA TO-15 SS-Dup 21C0636-04 Sub Slab EPA TO-15 Page 2 of 26 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CASE NARRATIVE SUMMARY All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report. EPA TO-15 Qualifications: Laboratory fortified blank/laboratory control sample recovery is outside of control limits. Reported value for this compound is likely to be biased on the high side. Analyte & Samples(s) Qualified: 2-Hexanone (MBK) B278375-BS1 Continuing calibration verification (CCV) did not meet method specifications and was biased on the low side for this compound. Analyte & Samples(s) Qualified: 1,2,4-Trichlorobenzene, Naphthalene 21C0636-01[SS-10], 21C0636-02[SS-11], 21C0636-03[SS-12], 21C0636-04[SS-Dup], B278375-BLK1, B278375-BS1, S057919-CCV1 Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side for this compound. Analyte & Samples(s) Qualified: 2-Hexanone (MBK) B278375-BS1, S057919-CCV1 Initial calibration verification (ICV) did not meet method specifications and was biased on the low side for this compound. Reported result is estimated. Analyte & Samples(s) Qualified: 1,2,4-Trichlorobenzene 21C0636-01[SS-10], 21C0636-02[SS-11], 21C0636-03[SS-12], 21C0636-04[SS-Dup], B278375-BLK1, B278375-BS1, S057919-CCV1 The results of analyses reported only relate to samples submitted to Con-Test, a Pace Analytical Laboratory, for testing. I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. Lisa A. Worthington Technical Representative Page 3 of 26 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 3/11/2021 Work Order: 21C0636Sample Description/Location: Field Sample #: SS-10 Sample ID: 21C0636-01 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -6.6 Sampled: 3/9/2021 13:00 Canister ID: 2106 Flow Controller ID: 4038 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 28 8.0 3/18/21 21:50 BRF67 4194.8 11 Benzene 0.31 0.20 3/18/21 21:50 BRF0.98 40.640.058 0.19 Benzyl chloride ND 0.20 3/18/21 21:50 BRFND41.00.090 0.47 Bromodichloromethane ND 0.20 3/18/21 21:50 BRFND41.30.056 0.37 Bromoform ND 0.20 3/18/21 21:50 BRFND42.10.069 0.71 Bromomethane ND 0.20 3/18/21 21:50 BRFND40.780.11 0.41 1,3-Butadiene ND 0.20 3/18/21 21:50 BRFND40.440.15 0.32 2-Butanone (MEK)ND 8.0 3/18/21 21:50 BRFND4240.66 2.0 Carbon Disulfide ND 2.0 3/18/21 21:50 BRFND46.20.51 1.6 Carbon Tetrachloride ND 0.20 3/18/21 21:50 BRFND41.30.053 0.33 Chlorobenzene ND 0.20 3/18/21 21:50 BRFND40.920.048 0.22 Chloroethane ND 0.20 3/18/21 21:50 BRFND40.530.20 0.52 Chloroform 0.89 0.20 3/18/21 21:50 BRF4.4 40.980.048 0.24 Chloromethane ND 0.40 3/18/21 21:50 BRFND40.830.15 0.32 Cyclohexane ND 0.20 3/18/21 21:50 BRFND40.690.098 0.34 Dibromochloromethane ND 0.20 3/18/21 21:50 BRFND41.70.067 0.57 1,2-Dibromoethane (EDB)ND 0.20 3/18/21 21:50 BRFND41.50.052 0.40 1,2-Dichlorobenzene ND 0.20 3/18/21 21:50 BRFND41.20.074 0.44 1,3-Dichlorobenzene ND 0.20 3/18/21 21:50 BRFND41.20.073 0.44 1,4-Dichlorobenzene ND 0.20 3/18/21 21:50 BRFND41.20.045 0.27 Dichlorodifluoromethane (Freon 12)ND 0.20 3/18/21 21:50 BRFND40.990.063 0.31 1,1-Dichloroethane ND 0.20 3/18/21 21:50 BRFND40.810.063 0.25 1,2-Dichloroethane ND 0.20 3/18/21 21:50 BRFND40.810.073 0.30 1,1-Dichloroethylene ND 0.20 3/18/21 21:50 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene ND 0.20 3/18/21 21:50 BRFND40.790.068 0.27 trans-1,2-Dichloroethylene ND 0.20 3/18/21 21:50 BRFND40.790.059 0.23 1,2-Dichloropropane ND 0.20 3/18/21 21:50 BRFND40.920.072 0.33 cis-1,3-Dichloropropene ND 0.20 3/18/21 21:50 BRFND40.910.093 0.42 trans-1,3-Dichloropropene ND 0.20 3/18/21 21:50 BRFND40.910.067 0.30 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 3/18/21 21:50 BRFND41.40.11 0.79 1,4-Dioxane ND 2.0 3/18/21 21:50 BRFND47.20.56 2.0 Ethanol 190 20 3/19/21 8:08 BRF350 10386.1 11 Ethyl Acetate ND 2.0 3/18/21 21:50 BRFND47.21.2 4.3 Ethylbenzene 1.0 0.20 3/18/21 21:50 BRF4.5 40.870.042 0.18 4-Ethyltoluene 0.46 0.20 3/18/21 21:50 BRF2.2 40.980.062 0.30 Heptane ND 0.20 3/18/21 21:50 BRFND40.820.086 0.35 Hexachlorobutadiene ND 0.20 3/18/21 21:50 BRFND42.10.088 0.94 Hexane ND 8.0 3/18/21 21:50 BRFND4280.36 1.3 2-Hexanone (MBK)ND 0.40 3/18/21 21:50 BRFND41.60.11 0.46 Isopropanol 23 8.0 3/18/21 21:50 BRF58 4201.8 4.5 Methyl tert-Butyl Ether (MTBE)ND 0.20 3/18/21 21:50 BRFND40.720.080 0.29 Methylene Chloride ND 2.0 3/18/21 21:50 BRFND46.90.46 1.6 4-Methyl-2-pentanone (MIBK)ND 0.20 3/18/21 21:50 BRFND40.820.10 0.43 Naphthalene ND 0.20 3/18/21 21:50 BRFV-05 ND 41.00.11 0.59 Propene ND 8.0 3/18/21 21:50 BRFND4140.67 1.2 Styrene ND 0.20 3/18/21 21:50 BRFND40.850.057 0.24 1,1,2,2-Tetrachloroethane ND 0.20 3/18/21 21:50 BRFND41.40.053 0.37 Page 4 of 26 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 3/11/2021 Work Order: 21C0636Sample Description/Location: Field Sample #: SS-10 Sample ID: 21C0636-01 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -6.6 Sampled: 3/9/2021 13:00 Canister ID: 2106 Flow Controller ID: 4038 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 7.4 0.20 3/18/21 21:50 BRF50 41.40.065 0.44 Tetrahydrofuran ND 2.0 3/18/21 21:50 BRFND45.90.49 1.5 Toluene 2.0 0.20 3/18/21 21:50 BRF7.4 40.750.058 0.22 1,2,4-Trichlorobenzene ND 0.20 3/18/21 21:50 BRFV-05, V-34 ND 41.50.12 0.91 1,1,1-Trichloroethane ND 0.20 3/18/21 21:50 BRFND41.10.065 0.36 1,1,2-Trichloroethane ND 0.20 3/18/21 21:50 BRFND41.10.073 0.40 Trichloroethylene ND 0.20 3/18/21 21:50 BRFND41.10.074 0.40 Trichlorofluoromethane (Freon 11)1.5 0.80 3/18/21 21:50 BRF8.5 44.50.15 0.85 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 3/18/21 21:50 BRFND46.10.15 1.2 1,2,4-Trimethylbenzene 2.0 0.20 3/18/21 21:50 BRF9.6 40.980.046 0.22 1,3,5-Trimethylbenzene 0.99 0.20 3/18/21 21:50 BRF4.9 40.980.052 0.26 Vinyl Acetate ND 4.0 3/18/21 21:50 BRFND4140.56 2.0 Vinyl Chloride ND 0.20 3/18/21 21:50 BRFND40.510.11 0.29 m&p-Xylene 5.7 0.40 3/18/21 21:50 BRF25 41.70.070 0.30 o-Xylene 2.3 0.20 3/18/21 21:50 BRF10 40.870.054 0.23 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)93.7 3/19/21 8:0870-130 4-Bromofluorobenzene (1)98.5 3/18/21 21:5070-130 Page 5 of 26 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 3/11/2021 Work Order: 21C0636Sample Description/Location: Field Sample #: SS-11 Sample ID: 21C0636-02 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -3.5 Receipt Vacuum(in Hg): -4.9 Sampled: 3/9/2021 12:34 Canister ID: 2235 Flow Controller ID: 4332 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 160 8.0 3/18/21 22:14 BRF370 4194.8 11 Benzene ND 0.20 3/18/21 22:14 BRFND40.640.058 0.19 Benzyl chloride ND 0.20 3/18/21 22:14 BRFND41.00.090 0.47 Bromodichloromethane ND 0.20 3/18/21 22:14 BRFND41.30.056 0.37 Bromoform ND 0.20 3/18/21 22:14 BRFND42.10.069 0.71 Bromomethane ND 0.20 3/18/21 22:14 BRFND40.780.11 0.41 1,3-Butadiene ND 0.20 3/18/21 22:14 BRFND40.440.15 0.32 2-Butanone (MEK)6.8 8.0 3/18/21 22:14 BRFJ20 4240.66 2.0 Carbon Disulfide ND 2.0 3/18/21 22:14 BRFND46.20.51 1.6 Carbon Tetrachloride ND 0.20 3/18/21 22:14 BRFND41.30.053 0.33 Chlorobenzene ND 0.20 3/18/21 22:14 BRFND40.920.048 0.22 Chloroethane ND 0.20 3/18/21 22:14 BRFND40.530.20 0.52 Chloroform 1.5 0.20 3/18/21 22:14 BRF7.1 40.980.048 0.24 Chloromethane ND 0.40 3/18/21 22:14 BRFND40.830.15 0.32 Cyclohexane ND 0.20 3/18/21 22:14 BRFND40.690.098 0.34 Dibromochloromethane ND 0.20 3/18/21 22:14 BRFND41.70.067 0.57 1,2-Dibromoethane (EDB)ND 0.20 3/18/21 22:14 BRFND41.50.052 0.40 1,2-Dichlorobenzene ND 0.20 3/18/21 22:14 BRFND41.20.074 0.44 1,3-Dichlorobenzene ND 0.20 3/18/21 22:14 BRFND41.20.073 0.44 1,4-Dichlorobenzene ND 0.20 3/18/21 22:14 BRFND41.20.045 0.27 Dichlorodifluoromethane (Freon 12)ND 0.20 3/18/21 22:14 BRFND40.990.063 0.31 1,1-Dichloroethane ND 0.20 3/18/21 22:14 BRFND40.810.063 0.25 1,2-Dichloroethane ND 0.20 3/18/21 22:14 BRFND40.810.073 0.30 1,1-Dichloroethylene ND 0.20 3/18/21 22:14 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene ND 0.20 3/18/21 22:14 BRFND40.790.068 0.27 trans-1,2-Dichloroethylene ND 0.20 3/18/21 22:14 BRFND40.790.059 0.23 1,2-Dichloropropane ND 0.20 3/18/21 22:14 BRFND40.920.072 0.33 cis-1,3-Dichloropropene ND 0.20 3/18/21 22:14 BRFND40.910.093 0.42 trans-1,3-Dichloropropene ND 0.20 3/18/21 22:14 BRFND40.910.067 0.30 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 3/18/21 22:14 BRFND41.40.11 0.79 1,4-Dioxane 4.5 2.0 3/18/21 22:14 BRF16 47.20.56 2.0 Ethanol 430 40 3/18/21 22:39 BRF810 20751223 Ethyl Acetate ND 2.0 3/18/21 22:14 BRFND47.21.2 4.3 Ethylbenzene 1.4 0.20 3/18/21 22:14 BRF5.9 40.870.042 0.18 4-Ethyltoluene ND 0.20 3/18/21 22:14 BRFND40.980.062 0.30 Heptane ND 0.20 3/18/21 22:14 BRFND40.820.086 0.35 Hexachlorobutadiene ND 0.20 3/18/21 22:14 BRFND42.10.088 0.94 Hexane ND 8.0 3/18/21 22:14 BRFND4280.36 1.3 2-Hexanone (MBK)ND 0.40 3/18/21 22:14 BRFND41.60.11 0.46 Isopropanol 51 8.0 3/18/21 22:14 BRF130 4201.8 4.5 Methyl tert-Butyl Ether (MTBE)ND 0.20 3/18/21 22:14 BRFND40.720.080 0.29 Methylene Chloride ND 2.0 3/18/21 22:14 BRFND46.90.46 1.6 4-Methyl-2-pentanone (MIBK)ND 0.20 3/18/21 22:14 BRFND40.820.10 0.43 Naphthalene ND 0.20 3/18/21 22:14 BRFV-05 ND 41.00.11 0.59 Propene ND 8.0 3/18/21 22:14 BRFND4140.67 1.2 Styrene ND 0.20 3/18/21 22:14 BRFND40.850.057 0.24 1,1,2,2-Tetrachloroethane ND 0.20 3/18/21 22:14 BRFND41.40.053 0.37 Page 6 of 26 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 3/11/2021 Work Order: 21C0636Sample Description/Location: Field Sample #: SS-11 Sample ID: 21C0636-02 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -3.5 Receipt Vacuum(in Hg): -4.9 Sampled: 3/9/2021 12:34 Canister ID: 2235 Flow Controller ID: 4332 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 220 1.0 3/18/21 22:39 BRF1500 206.80.33 2.2 Tetrahydrofuran ND 2.0 3/18/21 22:14 BRFND45.90.49 1.5 Toluene 4.2 0.20 3/18/21 22:14 BRF16 40.750.058 0.22 1,2,4-Trichlorobenzene ND 0.20 3/18/21 22:14 BRFV-05, V-34 ND 41.50.12 0.91 1,1,1-Trichloroethane 1.2 0.20 3/18/21 22:14 BRF6.5 41.10.065 0.36 1,1,2-Trichloroethane ND 0.20 3/18/21 22:14 BRFND41.10.073 0.40 Trichloroethylene 0.83 0.20 3/18/21 22:14 BRF4.4 41.10.074 0.40 Trichlorofluoromethane (Freon 11)2.3 0.80 3/18/21 22:14 BRF13 44.50.15 0.85 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 3/18/21 22:14 BRFND46.10.15 1.2 1,2,4-Trimethylbenzene 0.84 0.20 3/18/21 22:14 BRF4.1 40.980.046 0.22 1,3,5-Trimethylbenzene 0.20 0.20 3/18/21 22:14 BRF1.0 40.980.052 0.26 Vinyl Acetate ND 4.0 3/18/21 22:14 BRFND4140.56 2.0 Vinyl Chloride ND 0.20 3/18/21 22:14 BRFND40.510.11 0.29 m&p-Xylene 4.1 0.40 3/18/21 22:14 BRF18 41.70.070 0.30 o-Xylene 1.4 0.20 3/18/21 22:14 BRF5.9 40.870.054 0.23 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)94.6 3/18/21 22:3970-130 4-Bromofluorobenzene (1)98.5 3/18/21 22:1470-130 Page 7 of 26 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 3/11/2021 Work Order: 21C0636Sample Description/Location: Field Sample #: SS-12 Sample ID: 21C0636-03 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -28.5 Final Vacuum(in Hg): -3.5 Receipt Vacuum(in Hg): -4.6 Sampled: 3/9/2021 11:50 Canister ID: 2256 Flow Controller ID: 4333 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 350 40 3/19/21 8:32 BRF820 20952457 Benzene 0.70 0.20 3/18/21 23:04 BRF2.2 40.640.058 0.19 Benzyl chloride ND 0.20 3/18/21 23:04 BRFND41.00.090 0.47 Bromodichloromethane ND 0.20 3/18/21 23:04 BRFND41.30.056 0.37 Bromoform ND 0.20 3/18/21 23:04 BRFND42.10.069 0.71 Bromomethane ND 0.20 3/18/21 23:04 BRFND40.780.11 0.41 1,3-Butadiene ND 0.20 3/18/21 23:04 BRFND40.440.15 0.32 2-Butanone (MEK)15 8.0 3/18/21 23:04 BRF45 4240.66 2.0 Carbon Disulfide ND 2.0 3/18/21 23:04 BRFND46.20.51 1.6 Carbon Tetrachloride ND 0.20 3/18/21 23:04 BRFND41.30.053 0.33 Chlorobenzene ND 0.20 3/18/21 23:04 BRFND40.920.048 0.22 Chloroethane ND 0.20 3/18/21 23:04 BRFND40.530.20 0.52 Chloroform 0.85 0.20 3/18/21 23:04 BRF4.2 40.980.048 0.24 Chloromethane ND 0.40 3/18/21 23:04 BRFND40.830.15 0.32 Cyclohexane ND 0.20 3/18/21 23:04 BRFND40.690.098 0.34 Dibromochloromethane ND 0.20 3/18/21 23:04 BRFND41.70.067 0.57 1,2-Dibromoethane (EDB)ND 0.20 3/18/21 23:04 BRFND41.50.052 0.40 1,2-Dichlorobenzene ND 0.20 3/18/21 23:04 BRFND41.20.074 0.44 1,3-Dichlorobenzene ND 0.20 3/18/21 23:04 BRFND41.20.073 0.44 1,4-Dichlorobenzene ND 0.20 3/18/21 23:04 BRFND41.20.045 0.27 Dichlorodifluoromethane (Freon 12)ND 0.20 3/18/21 23:04 BRFND40.990.063 0.31 1,1-Dichloroethane ND 0.20 3/18/21 23:04 BRFND40.810.063 0.25 1,2-Dichloroethane ND 0.20 3/18/21 23:04 BRFND40.810.073 0.30 1,1-Dichloroethylene ND 0.20 3/18/21 23:04 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene 1.8 0.20 3/18/21 23:04 BRF6.9 40.790.068 0.27 trans-1,2-Dichloroethylene ND 0.20 3/18/21 23:04 BRFND40.790.059 0.23 1,2-Dichloropropane ND 0.20 3/18/21 23:04 BRFND40.920.072 0.33 cis-1,3-Dichloropropene ND 0.20 3/18/21 23:04 BRFND40.910.093 0.42 trans-1,3-Dichloropropene ND 0.20 3/18/21 23:04 BRFND40.910.067 0.30 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 3/18/21 23:04 BRFND41.40.11 0.79 1,4-Dioxane 4.0 2.0 3/18/21 23:04 BRF14 47.20.56 2.0 Ethanol 630 40 3/19/21 8:32 BRF1200 20751223 Ethyl Acetate ND 2.0 3/18/21 23:04 BRFND47.21.2 4.3 Ethylbenzene 0.93 0.20 3/18/21 23:04 BRF4.0 40.870.042 0.18 4-Ethyltoluene ND 0.20 3/18/21 23:04 BRFND40.980.062 0.30 Heptane ND 0.20 3/18/21 23:04 BRFND40.820.086 0.35 Hexachlorobutadiene ND 0.20 3/18/21 23:04 BRFND42.10.088 0.94 Hexane ND 8.0 3/18/21 23:04 BRFND4280.36 1.3 2-Hexanone (MBK)ND 0.40 3/18/21 23:04 BRFND41.60.11 0.46 Isopropanol 30 8.0 3/18/21 23:04 BRF74 4201.8 4.5 Methyl tert-Butyl Ether (MTBE)ND 0.20 3/18/21 23:04 BRFND40.720.080 0.29 Methylene Chloride ND 2.0 3/18/21 23:04 BRFND46.90.46 1.6 4-Methyl-2-pentanone (MIBK)ND 0.20 3/18/21 23:04 BRFND40.820.10 0.43 Naphthalene 2.2 0.20 3/18/21 23:04 BRFV-05 11 41.00.11 0.59 Propene ND 8.0 3/18/21 23:04 BRFND4140.67 1.2 Styrene ND 0.20 3/18/21 23:04 BRFND40.850.057 0.24 1,1,2,2-Tetrachloroethane ND 0.20 3/18/21 23:04 BRFND41.40.053 0.37 Page 8 of 26 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 3/11/2021 Work Order: 21C0636Sample Description/Location: Field Sample #: SS-12 Sample ID: 21C0636-03 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -28.5 Final Vacuum(in Hg): -3.5 Receipt Vacuum(in Hg): -4.6 Sampled: 3/9/2021 11:50 Canister ID: 2256 Flow Controller ID: 4333 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 35 0.20 3/18/21 23:04 BRF240 41.40.065 0.44 Tetrahydrofuran ND 2.0 3/18/21 23:04 BRFND45.90.49 1.5 Toluene 2.2 0.20 3/18/21 23:04 BRF8.2 40.750.058 0.22 1,2,4-Trichlorobenzene ND 0.20 3/18/21 23:04 BRFV-05, V-34 ND 41.50.12 0.91 1,1,1-Trichloroethane 1.4 0.20 3/18/21 23:04 BRF7.4 41.10.065 0.36 1,1,2-Trichloroethane ND 0.20 3/18/21 23:04 BRFND41.10.073 0.40 Trichloroethylene 13 0.20 3/18/21 23:04 BRF69 41.10.074 0.40 Trichlorofluoromethane (Freon 11)0.70 0.80 3/18/21 23:04 BRFJ3.9 44.50.15 0.85 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 3/18/21 23:04 BRFND46.10.15 1.2 1,2,4-Trimethylbenzene 1.3 0.20 3/18/21 23:04 BRF6.4 40.980.046 0.22 1,3,5-Trimethylbenzene 0.35 0.20 3/18/21 23:04 BRF1.7 40.980.052 0.26 Vinyl Acetate ND 4.0 3/18/21 23:04 BRFND4140.56 2.0 Vinyl Chloride ND 0.20 3/18/21 23:04 BRFND40.510.11 0.29 m&p-Xylene 2.7 0.40 3/18/21 23:04 BRF12 41.70.070 0.30 o-Xylene 1.1 0.20 3/18/21 23:04 BRF4.7 40.870.054 0.23 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)94.9 3/19/21 8:3270-130 4-Bromofluorobenzene (1)99.4 3/18/21 23:0470-130 Page 9 of 26 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 3/11/2021 Work Order: 21C0636Sample Description/Location: Field Sample #: SS-Dup Sample ID: 21C0636-04 Sample Matrix: Sub Slab Initial Vacuum(in Hg): Final Vacuum(in Hg): Receipt Vacuum(in Hg): -6.6 Sampled: 3/9/2021 00:00 Canister ID: 2303 Flow Controller ID: 4038 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 33 8.0 3/18/21 23:55 BRF78 4194.8 11 Benzene ND 0.20 3/18/21 23:55 BRFND40.640.058 0.19 Benzyl chloride ND 0.20 3/18/21 23:55 BRFND41.00.090 0.47 Bromodichloromethane ND 0.20 3/18/21 23:55 BRFND41.30.056 0.37 Bromoform ND 0.20 3/18/21 23:55 BRFND42.10.069 0.71 Bromomethane ND 0.20 3/18/21 23:55 BRFND40.780.11 0.41 1,3-Butadiene ND 0.20 3/18/21 23:55 BRFND40.440.15 0.32 2-Butanone (MEK)2.3 8.0 3/18/21 23:55 BRFJ6.8 4240.66 2.0 Carbon Disulfide ND 2.0 3/18/21 23:55 BRFND46.20.51 1.6 Carbon Tetrachloride ND 0.20 3/18/21 23:55 BRFND41.30.053 0.33 Chlorobenzene ND 0.20 3/18/21 23:55 BRFND40.920.048 0.22 Chloroethane ND 0.20 3/18/21 23:55 BRFND40.530.20 0.52 Chloroform 1.0 0.20 3/18/21 23:55 BRF5.1 40.980.048 0.24 Chloromethane ND 0.40 3/18/21 23:55 BRFND40.830.15 0.32 Cyclohexane ND 0.20 3/18/21 23:55 BRFND40.690.098 0.34 Dibromochloromethane ND 0.20 3/18/21 23:55 BRFND41.70.067 0.57 1,2-Dibromoethane (EDB)ND 0.20 3/18/21 23:55 BRFND41.50.052 0.40 1,2-Dichlorobenzene ND 0.20 3/18/21 23:55 BRFND41.20.074 0.44 1,3-Dichlorobenzene ND 0.20 3/18/21 23:55 BRFND41.20.073 0.44 1,4-Dichlorobenzene ND 0.20 3/18/21 23:55 BRFND41.20.045 0.27 Dichlorodifluoromethane (Freon 12)ND 0.20 3/18/21 23:55 BRFND40.990.063 0.31 1,1-Dichloroethane ND 0.20 3/18/21 23:55 BRFND40.810.063 0.25 1,2-Dichloroethane ND 0.20 3/18/21 23:55 BRFND40.810.073 0.30 1,1-Dichloroethylene ND 0.20 3/18/21 23:55 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene ND 0.20 3/18/21 23:55 BRFND40.790.068 0.27 trans-1,2-Dichloroethylene ND 0.20 3/18/21 23:55 BRFND40.790.059 0.23 1,2-Dichloropropane ND 0.20 3/18/21 23:55 BRFND40.920.072 0.33 cis-1,3-Dichloropropene ND 0.20 3/18/21 23:55 BRFND40.910.093 0.42 trans-1,3-Dichloropropene ND 0.20 3/18/21 23:55 BRFND40.910.067 0.30 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 3/18/21 23:55 BRFND41.40.11 0.79 1,4-Dioxane ND 2.0 3/18/21 23:55 BRFND47.20.56 2.0 Ethanol 230 20 3/19/21 8:58 BRF430 10386.1 11 Ethyl Acetate ND 2.0 3/18/21 23:55 BRFND47.21.2 4.3 Ethylbenzene 1.3 0.20 3/18/21 23:55 BRF5.5 40.870.042 0.18 4-Ethyltoluene ND 0.20 3/18/21 23:55 BRFND40.980.062 0.30 Heptane ND 0.20 3/18/21 23:55 BRFND40.820.086 0.35 Hexachlorobutadiene ND 0.20 3/18/21 23:55 BRFND42.10.088 0.94 Hexane 1.4 8.0 3/18/21 23:55 BRFJ5.0 4280.36 1.3 2-Hexanone (MBK)ND 0.40 3/18/21 23:55 BRFND41.60.11 0.46 Isopropanol 16 8.0 3/18/21 23:55 BRF40 4201.8 4.5 Methyl tert-Butyl Ether (MTBE)ND 0.20 3/18/21 23:55 BRFND40.720.080 0.29 Methylene Chloride ND 2.0 3/18/21 23:55 BRFND46.90.46 1.6 4-Methyl-2-pentanone (MIBK)ND 0.20 3/18/21 23:55 BRFND40.820.10 0.43 Naphthalene ND 0.20 3/18/21 23:55 BRFV-05 ND 41.00.11 0.59 Propene ND 8.0 3/18/21 23:55 BRFND4140.67 1.2 Styrene ND 0.20 3/18/21 23:55 BRFND40.850.057 0.24 1,1,2,2-Tetrachloroethane ND 0.20 3/18/21 23:55 BRFND41.40.053 0.37 Page 10 of 26 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 3/11/2021 Work Order: 21C0636Sample Description/Location: Field Sample #: SS-Dup Sample ID: 21C0636-04 Sample Matrix: Sub Slab Initial Vacuum(in Hg): Final Vacuum(in Hg): Receipt Vacuum(in Hg): -6.6 Sampled: 3/9/2021 00:00 Canister ID: 2303 Flow Controller ID: 4038 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 8.1 0.20 3/18/21 23:55 BRF55 41.40.065 0.44 Tetrahydrofuran ND 2.0 3/18/21 23:55 BRFND45.90.49 1.5 Toluene 2.1 0.20 3/18/21 23:55 BRF7.8 40.750.058 0.22 1,2,4-Trichlorobenzene ND 0.20 3/18/21 23:55 BRFV-05, V-34 ND 41.50.12 0.91 1,1,1-Trichloroethane ND 0.20 3/18/21 23:55 BRFND41.10.065 0.36 1,1,2-Trichloroethane ND 0.20 3/18/21 23:55 BRFND41.10.073 0.40 Trichloroethylene ND 0.20 3/18/21 23:55 BRFND41.10.074 0.40 Trichlorofluoromethane (Freon 11)1.7 0.80 3/18/21 23:55 BRF9.4 44.50.15 0.85 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 3/18/21 23:55 BRFND46.10.15 1.2 1,2,4-Trimethylbenzene 2.2 0.20 3/18/21 23:55 BRF11 40.980.046 0.22 1,3,5-Trimethylbenzene 1.2 0.20 3/18/21 23:55 BRF5.7 40.980.052 0.26 Vinyl Acetate ND 4.0 3/18/21 23:55 BRFND4140.56 2.0 Vinyl Chloride ND 0.20 3/18/21 23:55 BRFND40.510.11 0.29 m&p-Xylene 6.5 0.40 3/18/21 23:55 BRF28 41.70.070 0.30 o-Xylene 2.6 0.20 3/18/21 23:55 BRF11 40.870.054 0.23 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)94.5 3/19/21 8:5870-130 4-Bromofluorobenzene (1)97.8 3/18/21 23:5570-130 Page 11 of 26 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Sample Extraction Data Prep Method: TO-15 Prep-EPA TO-15 Lab Number [Field ID]Batch Date Pressure Dilution Pre Dilution Pre-Dil Initial mL Pre-Dil Final mL Default Injection mL Actual Injection mL 21C0636-01 [SS-10]B278375 1.5 1 N/A 1000 200 75 03/18/21 21C0636-01RE1 [SS-10]B278375 1.5 1 N/A 1000 200 30 03/18/21 21C0636-02 [SS-11]B278375 1.5 1 N/A 1000 200 75 03/18/21 21C0636-02RE1 [SS-11]B278375 1.5 1 N/A 1000 200 15 03/18/21 21C0636-03 [SS-12]B278375 1.5 1 N/A 1000 200 75 03/18/21 21C0636-03RE1 [SS-12]B278375 1.5 1 N/A 1000 200 15 03/18/21 21C0636-04 [SS-Dup]B278375 1.5 1 N/A 1000 200 75 03/18/21 21C0636-04RE1 [SS-Dup]B278375 1.5 1 N/A 1000 200 30 03/18/21 Page 12 of 26 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B278375 - TO-15 Prep Blank (B278375-BLK1)Prepared & Analyzed: 03/18/21 0.80NDAcetone 0.020NDBenzene 0.020NDBenzyl chloride 0.020NDBromodichloromethane 0.020NDBromoform 0.020NDBromomethane 0.020ND1,3-Butadiene 0.80ND2-Butanone (MEK) 0.20NDCarbon Disulfide 0.020NDCarbon Tetrachloride 0.020NDChlorobenzene 0.020NDChloroethane 0.020NDChloroform 0.040NDChloromethane 0.020NDCyclohexane 0.020NDDibromochloromethane 0.020ND1,2-Dibromoethane (EDB) 0.020ND1,2-Dichlorobenzene 0.020ND1,3-Dichlorobenzene 0.020ND1,4-Dichlorobenzene 0.020NDDichlorodifluoromethane (Freon 12) 0.020ND1,1-Dichloroethane 0.020ND1,2-Dichloroethane 0.020ND1,1-Dichloroethylene 0.020NDcis-1,2-Dichloroethylene 0.020NDtrans-1,2-Dichloroethylene 0.020ND1,2-Dichloropropane 0.020NDcis-1,3-Dichloropropene 0.020NDtrans-1,3-Dichloropropene 0.020ND1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 0.20ND1,4-Dioxane 0.80NDEthanol 0.20NDEthyl Acetate 0.020NDEthylbenzene 0.020ND4-Ethyltoluene 0.020NDHeptane 0.020NDHexachlorobutadiene 0.80NDHexane 0.020ND2-Hexanone (MBK) 0.80NDIsopropanol 0.020NDMethyl tert-Butyl Ether (MTBE) 0.20NDMethylene Chloride 0.020ND4-Methyl-2-pentanone (MIBK) 0.020 V-05NDNaphthalene 0.80NDPropene 0.020NDStyrene Page 13 of 26 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B278375 - TO-15 Prep Blank (B278375-BLK1)Prepared & Analyzed: 03/18/21 0.020ND1,1,2,2-Tetrachloroethane 0.020NDTetrachloroethylene 0.20NDTetrahydrofuran 0.020NDToluene 0.020 V-05, V-34 ND1,2,4-Trichlorobenzene 0.020ND1,1,1-Trichloroethane 0.020ND1,1,2-Trichloroethane 0.020NDTrichloroethylene 0.080NDTrichlorofluoromethane (Freon 11) 0.080ND1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 0.020ND1,2,4-Trimethylbenzene 0.020ND1,3,5-Trimethylbenzene 0.40NDVinyl Acetate 0.020NDVinyl Chloride 0.040NDm&p-Xylene 0.020NDo-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)97.17.77 LCS (B278375-BS1)Prepared & Analyzed: 03/18/21 5.00 70-1301045.20Acetone 5.00 70-13096.54.82Benzene 5.00 70-13083.64.18Benzyl chloride 5.00 70-1301105.51Bromodichloromethane 5.00 70-1301035.14Bromoform 5.00 70-13073.73.69Bromomethane 5.00 70-13078.83.941,3-Butadiene 5.00 70-13091.94.602-Butanone (MEK) 5.00 70-13074.73.73Carbon Disulfide 5.00 70-13099.84.99Carbon Tetrachloride 5.00 70-13092.74.63Chlorobenzene 5.00 70-13082.04.10Chloroethane 5.00 70-13079.23.96Chloroform 5.00 70-13088.04.40Chloromethane 5.00 70-13094.94.75Cyclohexane 5.00 70-13096.64.83Dibromochloromethane 5.00 70-1301015.041,2-Dibromoethane (EDB) 5.00 70-1301035.131,2-Dichlorobenzene 5.00 70-1301045.191,3-Dichlorobenzene 5.00 70-1301005.001,4-Dichlorobenzene 5.00 70-13080.74.04Dichlorodifluoromethane (Freon 12) 5.00 70-13083.44.171,1-Dichloroethane 5.00 70-13090.44.521,2-Dichloroethane 5.00 70-13088.64.431,1-Dichloroethylene 5.00 70-13084.04.20cis-1,2-Dichloroethylene 5.00 70-13083.64.18trans-1,2-Dichloroethylene Page 14 of 26 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B278375 - TO-15 Prep LCS (B278375-BS1)Prepared & Analyzed: 03/18/21 5.00 70-1301025.091,2-Dichloropropane 5.00 70-13098.74.93cis-1,3-Dichloropropene 5.00 70-1301015.04trans-1,3-Dichloropropene 5.00 70-13073.83.691,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 5.00 70-1301015.051,4-Dioxane 5.00 70-13090.74.54Ethanol 5.00 70-13082.44.12Ethyl Acetate 5.00 70-13097.14.85Ethylbenzene 5.00 70-13097.14.854-Ethyltoluene 5.00 70-1301075.35Heptane 5.00 70-13091.84.59Hexachlorobutadiene 5.00 70-1301045.20Hexane 5.00 V-06, L-0570-1301376.872-Hexanone (MBK)* 5.00 70-13098.94.94Isopropanol 5.00 70-13072.93.65Methyl tert-Butyl Ether (MTBE) 5.00 70-1301005.02Methylene Chloride 5.00 70-1301125.624-Methyl-2-pentanone (MIBK) 5.00 V-0570-13070.83.54Naphthalene 5.00 70-13087.84.39Propene 5.00 70-13092.74.64Styrene 5.00 70-1301055.261,1,2,2-Tetrachloroethane 5.00 70-13095.24.76Tetrachloroethylene 5.00 70-13098.44.92Tetrahydrofuran 5.00 70-13095.34.77Toluene 5.00 V-05, V-34 70-13080.84.041,2,4-Trichlorobenzene 5.00 70-13096.94.841,1,1-Trichloroethane 5.00 70-13097.54.881,1,2-Trichloroethane 5.00 70-1301025.08Trichloroethylene 5.00 70-13081.74.09Trichlorofluoromethane (Freon 11) 5.00 70-13073.83.691,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 5.00 70-13099.34.971,2,4-Trimethylbenzene 5.00 70-13096.84.841,3,5-Trimethylbenzene 5.00 70-13086.84.34Vinyl Acetate 5.00 70-13082.44.12Vinyl Chloride 10.0 70-13010410.4m&p-Xylene 5.00 70-1301005.00o-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1028.16 Page 15 of 26 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Note: Blank Subtraction is not performed unless otherwise noted *QC result is outside of established limits. †Wide recovery limits established for difficult compound. ‡Wide RPD limits established for difficult compound. #Data exceeded client recommended or regulatory level RL Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference LCS Laboratory Control Sample Laboratory Control SampleLCS Dup Duplicate Laboratory Control Sample MS Matrix Spike Sample MS Dup Duplicate Matrix Spike Sample REC Recovery QC Quality Control ppbv Parts per billion volume EPA United States Environmental Protection Agency Percent Recovery% REC ND Not Detected Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the calculation which have not been rounded. Not ApplicableN/A DL Detection Limit Not CalculatedNC LFB/LCS Lab Fortified Blank/Lab Control Sample ORP Oxidation-Reduction Potential Not dry weight correctedwet Percent weight% wt KilogramKg Gramg Milligrammg Microgramµg Nanogramng LiterL MillilitermL Microliter L Cubic Meterm3 Extractable Petroleum HydrocarbonsEPH Volatile Petroleum HydrocarbonsVPH Air Petroleum HydrocarbonsAPH Flame Ionization DetectorFID Photo Ionization DetectorPID FLAG/QUALIFIER SUMMARY Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated concentration (CLP J-Flag). J Laboratory fortified blank/laboratory control sample recovery is outside of control limits. Reported value for this compound is likely to be biased on the high side. L-05 Continuing calibration verification (CCV) did not meet method specifications and was biased on the low side for this compound. V-05 Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side for this compound. V-06 Initial calibration verification (ICV) did not meet method specifications and was biased on the low side for this compound. Reported result is estimated. V-34 Page 16 of 26 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYST Thomas P. HniteckiTPH Raisa A. PetraitisRAP PDF Management StationSTATION Kerry K. McGeeKKM Brittany R. FiskBRF Page 17 of 26 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q Initial Cal Check (S052381-ICV1 )Lab File ID: J2025821.D Analyzed: 09/14/20 23:22 Bromochloromethane (1)159501 2.873 155833 2.873 60 - 140102 0.0000 +/-0.50 1,4-Difluorobenzene (1)756714 3.475 745760 3.475 60 - 140101 0.0000 +/-0.50 Chlorobenzene-d5 (1)686740 5.06 671608 5.057 60 - 140102 0.0030 +/-0.50 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q Calibration Check (S057919-CCV1 )Lab File ID: J2107704.D Analyzed: 03/18/21 13:04 Bromochloromethane (1)151406 2.873 155833 2.873 60 - 14097 0.0000 +/-0.50 1,4-Difluorobenzene (1)546633 3.478 745760 3.475 60 - 14073 0.0030 +/-0.50 Chlorobenzene-d5 (1)488699 5.056 671608 5.057 60 - 14073 -0.0010 +/-0.50 LCS (B278375-BS1 )Lab File ID: J2107705.D Analyzed: 03/18/21 13:29 Bromochloromethane (1)152112 2.873 151406 2.873 60 - 140100 0.0000 +/-0.50 1,4-Difluorobenzene (1)544843 3.475 546633 3.478 60 - 140100 -0.0030 +/-0.50 Chlorobenzene-d5 (1)482666 5.057 488699 5.056 60 - 14099 0.0010 +/-0.50 Blank (B278375-BLK1 )Lab File ID: J2107707.D Analyzed: 03/18/21 14:25 Bromochloromethane (1)155439 2.86 151406 2.873 60 - 140103 -0.0130 +/-0.50 1,4-Difluorobenzene (1)523875 3.468 546633 3.478 60 - 14096 -0.0100 +/-0.50 Chlorobenzene-d5 (1)458830 5.054 488699 5.056 60 - 14094 -0.0020 +/-0.50 SS-10 (21C0636-01 )Lab File ID: J2107724.D Analyzed: 03/18/21 21:50 Bromochloromethane (1)155673 2.87 151406 2.873 60 - 140103 -0.0030 +/-0.50 1,4-Difluorobenzene (1)534724 3.475 546633 3.478 60 - 14098 -0.0030 +/-0.50 Chlorobenzene-d5 (1)481269 5.057 488699 5.056 60 - 14098 0.0010 +/-0.50 SS-11 (21C0636-02 )Lab File ID: J2107725.D Analyzed: 03/18/21 22:14 Bromochloromethane (1)154473 2.863 151406 2.873 60 - 140102 -0.0100 +/-0.50 1,4-Difluorobenzene (1)542941 3.471 546633 3.478 60 - 14099 -0.0070 +/-0.50 Chlorobenzene-d5 (1)476620 5.056 488699 5.056 60 - 14098 0.0000 +/-0.50 SS-11 (21C0636-02RE1 )Lab File ID: J2107726.D Analyzed: 03/18/21 22:39 Bromochloromethane (1)157442 2.866 151406 2.873 60 - 140104 -0.0070 +/-0.50 1,4-Difluorobenzene (1)538060 3.472 546633 3.478 60 - 14098 -0.0060 +/-0.50 Chlorobenzene-d5 (1)472988 5.057 488699 5.056 60 - 14097 0.0010 +/-0.50 SS-12 (21C0636-03 )Lab File ID: J2107727.D Analyzed: 03/18/21 23:04 Bromochloromethane (1)159826 2.866 151406 2.873 60 - 140106 -0.0070 +/-0.50 1,4-Difluorobenzene (1)547660 3.472 546633 3.478 60 - 140100 -0.0060 +/-0.50 Chlorobenzene-d5 (1)480287 5.057 488699 5.056 60 - 14098 0.0010 +/-0.50 Page 18 of 26 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q SS-Dup (21C0636-04 )Lab File ID: J2107729.D Analyzed: 03/18/21 23:55 Bromochloromethane (1)154209 2.869 151406 2.873 60 - 140102 -0.0040 +/-0.50 1,4-Difluorobenzene (1)545484 3.474 546633 3.478 60 - 140100 -0.0040 +/-0.50 Chlorobenzene-d5 (1)486915 5.056 488699 5.056 60 - 140100 0.0000 +/-0.50 SS-10 (21C0636-01RE1 )Lab File ID: J2107734.D Analyzed: 03/19/21 08:08 Bromochloromethane (1)154914 2.863 151406 2.873 60 - 140102 -0.0100 +/-0.50 1,4-Difluorobenzene (1)535436 3.472 546633 3.478 60 - 14098 -0.0060 +/-0.50 Chlorobenzene-d5 (1)471388 5.054 488699 5.056 60 - 14096 -0.0020 +/-0.50 SS-12 (21C0636-03RE1 )Lab File ID: J2107735.D Analyzed: 03/19/21 08:32 Bromochloromethane (1)159713 2.863 151406 2.873 60 - 140105 -0.0100 +/-0.50 1,4-Difluorobenzene (1)536782 3.469 546633 3.478 60 - 14098 -0.0090 +/-0.50 Chlorobenzene-d5 (1)463103 5.054 488699 5.056 60 - 14095 -0.0020 +/-0.50 SS-Dup (21C0636-04RE1 )Lab File ID: J2107736.D Analyzed: 03/19/21 08:58 Bromochloromethane (1)155699 2.863 151406 2.873 60 - 140103 -0.0100 +/-0.50 1,4-Difluorobenzene (1)531251 3.468 546633 3.478 60 - 14097 -0.0100 +/-0.50 Chlorobenzene-d5 (1)465137 5.054 488699 5.056 60 - 14095 -0.0020 +/-0.50 Page 19 of 26 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CONTINUING CALIBRATION CHECK EPA TO-15 S057919-CCV1 COMPOUND TYPE CCV MIN (#)CCV LIMIT (#)CCV ICAL CONC. (ppbv)% DIFF / DRIFTRESPONSE FACTOR STD 0.9338917A 2.6 305.13 0.91031545.00Acetone 0.6441294A -2.5 304.88 0.66060255.00Benzene 0.5038684A -15.5 304.22 0.59657625.00Benzyl chloride 0.5048155A 11.2 305.56 0.45379535.00Bromodichloromethane 0.7063718A 7.0 305.35 0.66009985.00Bromoform 0.73912A -26.2 303.69 1.0011775.00Bromomethane 0.5013698A -19.7 304.01 0.62469025.001,3-Butadiene 1.230789A -5.9 304.71 1.307495.002-Butanone (MEK) 1.805466A -26.8 303.66 2.4664695.00Carbon Disulfide 0.5191578A 2.5 305.12 0.50647525.00Carbon Tetrachloride 0.729889A -5.8 304.71 0.77512965.00Chlorobenzene 0.3926185A -21.5 303.92 0.50014425.00Chloroethane 1.600687A -20.7 303.96 2.0187795.00Chloroform 0.5561946A -9.4 304.53 0.61414915.00Chloromethane 0.2725778A -4.3 304.78 0.28493445.00Cyclohexane 0.6289516A -2.2 304.89 0.64296155.00Dibromochloromethane 0.4931297A 1.9 305.09 0.48410195.001,2-Dibromoethane (EDB) 0.6793351A -0.8 304.96 0.68463135.001,2-Dichlorobenzene 0.7490058A 3.8 305.19 0.72159925.001,3-Dichlorobenzene 0.7072591A -0.9 304.96 0.71348965.001,4-Dichlorobenzene 1.990473A -20.6 303.97 2.5070915.00Dichlorodifluoromethane (Freon 12) 1.267775A -18.0 304.10 1.5453035.001,1-Dichloroethane 0.9612406A -9.2 304.54 1.0588055.001,2-Dichloroethane 1.069083A -7.9 304.61 1.1602875.001,1-Dichloroethylene 0.9357516A -16.0 304.20 1.1142685.00cis-1,2-Dichloroethylene 1.016763A -15.4 304.23 1.2019085.00trans-1,2-Dichloroethylene 0.2336778A 4.7 305.24 0.22311345.001,2-Dichloropropane 0.3783423A 4.3 305.21 0.36288985.00cis-1,3-Dichloropropene 0.3173552A 3.9 305.19 0.30554635.00trans-1,3-Dichloropropene 2.04273A -22.9 303.85 2.6500555.001,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 0.1381783A -0.9 304.96 0.1393875.001,4-Dioxane 0.1471857A -13.5 304.32 0.17021655.00Ethanol 0.2101793A -7.8 304.61 0.22801885.00Ethyl Acetate 1.12766A -2.9 304.86 1.1613955.00Ethylbenzene 1.255726A -0.6 304.97 1.2628175.004-Ethyltoluene 0.1876828A 11.2 305.56 0.16884545.00Heptane 0.5837245A -15.6 304.22 0.69182945.00Hexachlorobutadiene 0.6579079L 1.4 305.07 0.65316035.00Hexane Page 20 of 26 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CONTINUING CALIBRATION CHECK EPA TO-15 S057919-CCV1 COMPOUND TYPE CCV MIN (#)CCV LIMIT (#)CCV ICAL CONC. (ppbv)% DIFF / DRIFTRESPONSE FACTOR STD 0.3669498A 31.0 *306.55 0.2800655.002-Hexanone (MBK) 1.090937A 8.9 305.44 1.0019815.00Isopropanol 1.868639A -25.6 303.72 2.5125355.00Methyl tert-Butyl Ether (MTBE) 0.668243A 0.9 305.05 0.66218265.00Methylene Chloride 0.1678055A 9.6 305.48 0.15311145.004-Methyl-2-pentanone (MIBK) 0.6900902A -36.5 *303.17 1.0869325.00Naphthalene 0.428876A -7.6 304.62 0.46417495.00Propene 0.6754522A -4.3 304.79 0.70564885.00Styrene 0.6691006A 4.8 305.24 0.6385835.001,1,2,2-Tetrachloroethane 0.5392866A -2.8 304.86 0.55467945.00Tetrachloroethylene 0.6513243A -8.8 304.56 0.71430445.00Tetrahydrofuran 0.8618802A -7.8 304.61 0.93450115.00Toluene 0.2932292A -31.2 *303.44 0.42602845.001,2,4-Trichlorobenzene 0.4647828A 3.4 305.17 0.44961335.001,1,1-Trichloroethane 0.3208683A -2.2 304.89 0.32813735.001,1,2-Trichloroethane 0.305852A 2.7 305.13 0.29794695.00Trichloroethylene 2.044368A -19.4 304.03 2.5368415.00Trichlorofluoromethane (Freon 11) 1.491333A -23.8 303.81 1.9577355.001,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 1.019252A -0.7 304.96 1.0267445.001,2,4-Trimethylbenzene 1.083052A 0.2 305.01 1.0809785.001,3,5-Trimethylbenzene 1.165735A -16.8 304.16 1.4009655.00Vinyl Acetate 0.7111158A -16.9 304.16 0.85546345.00Vinyl Chloride 0.9654777A 5.1 3010.5 0.918504310.0m&p-Xylene 0.9058402A 0.7 305.03 0.8997865.00o-Xylene * Values outside of QC limits # Column to be used to flag Response Factor and %Diff/Drift values with an asterisk Page 21 of 26 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report EPA TO-15 in Air AIHA,NY,ME,NHAcetone AIHA,FL,NJ,NY,ME,NH,VABenzene AIHA,FL,NJ,NY,ME,NH,VABenzyl chloride AIHA,NJ,NY,ME,NH,VABromodichloromethane AIHA,NJ,NY,ME,NH,VABromoform AIHA,FL,NJ,NY,ME,NHBromomethane AIHA,NJ,NY,ME,NH,VA1,3-Butadiene AIHA,FL,NJ,NY,ME,NH,VA2-Butanone (MEK) AIHA,NJ,NY,ME,NH,VACarbon Disulfide AIHA,FL,NJ,NY,ME,NH,VACarbon Tetrachloride AIHA,FL,NJ,NY,ME,NH,VAChlorobenzene AIHA,FL,NJ,NY,ME,NH,VAChloroethane AIHA,FL,NJ,NY,ME,NH,VAChloroform AIHA,FL,NJ,NY,ME,NH,VAChloromethane AIHA,NJ,NY,ME,NH,VACyclohexane AIHA,NY,ME,NHDibromochloromethane AIHA,NJ,NY,ME,NH1,2-Dibromoethane (EDB) AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichlorobenzene AIHA,NJ,NY,ME,NH1,3-Dichlorobenzene AIHA,FL,NJ,NY,ME,NH,VA1,4-Dichlorobenzene AIHA,NY,ME,NHDichlorodifluoromethane (Freon 12) AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethylene AIHA,FL,NY,ME,NH,VAcis-1,2-Dichloroethylene AIHA,NJ,NY,ME,NH,VAtrans-1,2-Dichloroethylene AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichloropropane AIHA,FL,NJ,NY,ME,NH,VAcis-1,3-Dichloropropene AIHA,NY,ME,NHtrans-1,3-Dichloropropene AIHA,NJ,NY,ME,NH,VA1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) AIHA,NJ,NY,ME,NH,VA1,4-Dioxane AIHAEthanol AIHAEthyl Acetate AIHA,FL,NJ,NY,ME,NH,VAEthylbenzene AIHA,NJ4-Ethyltoluene AIHA,NJ,NY,ME,NH,VAHeptane AIHA,NJ,NY,ME,NH,VAHexachlorobutadiene AIHA,FL,NJ,NY,ME,NH,VAHexane AIHA2-Hexanone (MBK) AIHA,NY,ME,NHIsopropanol AIHA,FL,NJ,NY,ME,NH,VAMethyl tert-Butyl Ether (MTBE) AIHA,FL,NJ,NY,ME,NH,VAMethylene Chloride AIHA,FL,NJ,NY,ME,NH4-Methyl-2-pentanone (MIBK) NY,ME,NHNaphthalene AIHAPropene AIHA,FL,NJ,NY,ME,NH,VAStyrene AIHA,FL,NJ,NY,ME,NH,VA1,1,2,2-Tetrachloroethane Page 22 of 26 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report EPA TO-15 in Air AIHA,FL,NJ,NY,ME,NH,VATetrachloroethylene AIHATetrahydrofuran AIHA,FL,NJ,NY,ME,NH,VAToluene AIHA,NJ,NY,ME,NH,VA1,2,4-Trichlorobenzene AIHA,FL,NJ,NY,ME,NH,VA1,1,1-Trichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1,2-Trichloroethane AIHA,FL,NJ,NY,ME,NH,VATrichloroethylene AIHA,NY,ME,NHTrichlorofluoromethane (Freon 11) AIHA,NJ,NY,ME,NH,VA1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) AIHA,NJ,NY,ME,NH1,2,4-Trimethylbenzene AIHA,NJ,NY,ME,NH1,3,5-Trimethylbenzene AIHA,FL,NJ,NY,ME,NH,VAVinyl Acetate AIHA,FL,NJ,NY,ME,NH,VAVinyl Chloride AIHA,FL,NJ,NY,ME,NH,VAm&p-Xylene AIHA,FL,NJ,NY,ME,NH,VAo-Xylene Con-Test, a Pace Environmental Laboratory, operates under the following certifications and accreditations: Code Description Number Expires 100033AIHA-LAP, LLC - ISO17025:2017AIHA 03/1/2022 M-MA100Massachusetts DEPMA 06/30/2021 PH-0165Connecticut Department of Publilc HealthCT 12/31/2022 10899 NELAPNew York State Department of HealthNY 04/1/2021 2516 NELAPNew Hampshire Environmental LabNH-S 02/5/2022 LAO00112Rhode Island Department of HealthRI 12/30/2021 652North Carolina Div. of Water QualityNC 12/31/2021 MA007 NELAPNew Jersey DEPNJ 06/30/2021 E871027 NELAPFlorida Department of HealthFL 06/30/2021 LL720741Vermont Department of Health Lead LaboratoryVT 07/30/2021 MA00100State of MaineME 06/9/2021 460217Commonwealth of VirginiaVA 12/14/2021 2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2021 VT-255716Vermont Department of Health Drinking WaterVT-DW 06/12/2021 25703North Carolina Department of HealthNC-DW 07/31/2021 68-05812Commonwealth of Pennsylvania DEPPA 06/30/2021 9100Dept. of Env, Great Lakes, and EnergyMI 09/6/2021 Page 23 of 26 Page 24 of 26 Page 25 of 26 Page 26 of 26 Appendix C DEQ Risk Calculator (January 2021) Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Worst Case Scenario North Carolina Department of Environmental Quality Risk Calculator REEP-LRC II 1900&1942 Continental Boulevard Charlotte, Mecklenburg County Brownfields Program 24001-20-060 January 2021 November 2020 EPA RSL Table Prepared By:Hart & Hickman, PC 3921 Sunset Ridge Road, Suite 301, Raleigh, North Carolina North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24001-20-060 Exposure Unit ID: Worst Case Scenario Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Point ConcentrationsVersion Date: January 2021Basis: November 2020 EPA RSL TableSite ID: 24001-20-060 Exposure Unit ID: Worst Case Scenario Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier)Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 820 67-64-1 Acetone ug/m3 4.5 71-43-2 Benzene ug/m3 8.4 75-15-0 Carbon Disulfide ug/m3 7.1 67-66-3 Chloroform ug/m3 2.9 75-71-8 Dichlorodifluoromethane ug/m3 2200 75-34-3 Dichloroethane, 1,1-ug/m3 2200 75-35-4 Dichloroethylene, 1,1-ug/m3 20 156-59-2 Dichloroethylene, cis-1,2-ug/m3 0.76 156-60-5 Dichloroethylene, trans-1,2-ug/m3 25 123-91-1 Dioxane, 1,4-ug/m3 2.9 141-78-6 Ethyl Acetate ug/m3 30 100-41-4 Ethylbenzene ug/m3 2.5 109-99-9 ~Tetrahydrofuran ug/m3 5.5 142-82-5 Heptane, N-ug/m3 5 110-54-3 Hexane, N-ug/m3 5.4 591-78-6 Hexanone, 2-ug/m3 140 67-63-0 Isopropanol ug/m3 45 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 14 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 18 91-20-3 ~Naphthalene ug/m3 0.72 100-42-5 Styrene ug/m3 2500 127-18-4 Tetrachloroethylene ug/m3 73 108-88-3 Toluene ug/m3 7.7 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-ug/m3 15000 71-55-6 Trichloroethane, 1,1,1-ug/m3 69 79-01-6 Trichloroethylene ug/m3 120 75-69-4 Trichlorofluoromethane ug/m3 17 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 6.4 108-67-8 Trimethylbenzene, 1,3,5-ug/m3 1.5 75-01-4 Vinyl Chloride ug/m3 129 1330-20-7 Xylenes ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Data reflects the highest concentration for each compound detected in SS-1 through SS-12. Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24001-20-060 Exposure Unit ID: Worst Case Scenario Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 4.5E-06 2.8E-01 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24001-20-060 Exposure Unit ID: Worst Case Scenario CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 820 8.2 -2.7E+04 6.0E-05 71-43-2 Benzene 4.5 0.045 1.6E+00 2.6E+01 2.9E-08 3.4E-04 75-15-0 Carbon Disulfide 8.4 0.084 -6.1E+02 2.7E-05 67-66-3 Chloroform 7.1 0.071 5.3E-01 8.6E+01 1.3E-07 1.7E-04 75-71-8 Dichlorodifluoromethane 2.9 0.029 -8.8E+01 6.6E-05 75-34-3 Dichloroethane, 1,1-2200 22 7.7E+00 -2.9E-0675-35-4 Dichloroethylene, 1,1-2200 22 -1.8E+02 2.5E-02156-59-2 Dichloroethylene, cis-1,2-20 0.2 --156-60-5 Dichloroethylene, trans-1,2-0.76 0.0076 -3.5E+01 4.3E-05123-91-1 Dioxane, 1,4-25 0.25 2.5E+00 2.6E+01 1.0E-07 1.9E-03 141-78-6 Ethyl Acetate 2.9 0.029 -6.1E+01 9.5E-05 100-41-4 Ethylbenzene 30 0.3 4.9E+00 8.8E+02 6.1E-08 6.8E-05 109-99-9 ~Tetrahydrofuran 2.5 0.025 -1.8E+03 2.9E-06 142-82-5 Heptane, N-5.5 0.055 -3.5E+02 3.1E-05 110-54-3 Hexane, N-5 0.05 -6.1E+02 1.6E-05591-78-6 Hexanone, 2-5.4 0.054 -2.6E+01 4.1E-0467-63-0 Isopropanol 140 1.4 -1.8E+02 1.6E-0378-93-3 Methyl Ethyl Ketone (2-Butanone)45 0.45 -4.4E+03 2.1E-05 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)14 0.14 -2.6E+03 1.1E-05 91-20-3 ~Naphthalene 18 0.18 3.6E-01 2.6E+00 5.0E-07 1.4E-02 100-42-5 Styrene 0.72 0.0072 -8.8E+02 1.6E-06 127-18-4 Tetrachloroethylene 2500 25 4.7E+01 3.5E+01 5.3E-07 1.4E-01 108-88-3 Toluene 73 0.73 -4.4E+03 3.3E-05 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-7.7 0.077 -4.4E+03 3.5E-0671-55-6 Trichloroethane, 1,1,1-15000 150 -4.4E+03 6.8E-0379-01-6 Trichloroethylene 69 0.69 3.0E+00 1.8E+00 2.3E-07 7.9E-02 75-69-4 Trichlorofluoromethane 120 1.2 -- 95-63-6 Trimethylbenzene, 1,2,4-17 0.17 -5.3E+01 6.5E-04 108-67-8 Trimethylbenzene, 1,3,5-6.4 0.064 -5.3E+01 2.4E-04 75-01-4 Vinyl Chloride 1.5 0.015 2.8E+00 8.8E+01 5.4E-09 3.4E-05 1330-20-7 Xylenes 129 1.29 -8.8E+01 2.9E-03 Cumulative:4.5E-06 2.8E-01 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator