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HomeMy WebLinkAbout24001 REEP-LRC II VI Assessment Report_20230310#C-1269 Engineering #C-245 Geology Vapor Intrusion Assessment Report REEP-LRC(RN) 1900 Continental Boulevard Charlotte, Mecklenburg County, North Carolina Brownfields Project No. 24001-20-060 H&H Job No. SSP-001 September 13, 2022 9/13/22 i Vapor Intrusion Assessment Report REEP-LRC(RN) 1900 Continental Boulevard Charlotte, North Carolina Brownfields Project No. 24001-20-060 UUH&H Job No. SSP-001 Table of Contents 1.0 Introduction .............................................................................................................................1 2.0 Historical Use Information – PIN 20308301 .........................................................................4 2.0 Sub-Slab Vapor Assessment Activities .................................................................................7 2.1 Sub-Slab Vapor Sampling Methodology ...............................................................................7 2.2 Sub-Slab Vapor Sampling Analytical Results .......................................................................9 2.3 DEQ DWM Risk Calculations ............................................................................................10 3.0 Indoor Air Assessment Activities ........................................................................................12 3.1 Indoor Air Sampling Methodology .....................................................................................12 3.2 Indoor Air Sampling Analytical Results .............................................................................13 3.3 DEQ DWM Risk Calculations ............................................................................................13 4.0 Summary and Conclusions...................................................................................................15 List of Tables Table 1 Summary of Sub-Slab Vapor Analytical Data Table 2 Summary of Indoor Air Analytical Data ii List of Figures Figure 1 Site Location Map Figure 2 Site Map Figure 3 Sample Location Map List of Appendices Appendix A Sub-Slab Vapor and Indoor Air Sampling Forms Appendix B Laboratory Analytical Reports Appendix C DEQ Risk Calculators (July 2022) Appendix D Indoor Air Survey Forms 1 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Somerset Properties (SSP)/Continental Tire (SSP-001)/Brownfields Assessment/Additional VI Assessment/Final Report/VI Assessment Report_REEP-LRC(RN).doc Vapor Intrusion Assessment Report REEP-LRC(RN) 1900 & 1942 Continental Boulevard Charlotte, North Carolina Brownfields Project No. 24001-20-060 UUH&H Job No. SSP-001 1.0 Introduction Hart & Hickman, PC (H&H) has prepared this Vapor Intrusion Assessment Report on behalf of SPWF-Continental Warehouse, LLC (Prospective Developer or PD) for the REEP-LRC(RN) Brownfields property (Brownfields Project No. 24001-20-060). The Brownfields property is located at 1900 Continental Boulevard in Charlotte, Mecklenburg County, North Carolina (Site) and consists of two parcels of land that total approximately 85.2 acres. Specifically, the Site is located at 1900 Continental Boulevard (Mecklenburg County Parcel Identification Number [PIN] 20308301) and a parcel east of Interstate I-485 with no established address (PIN 20302139). The Site is developed with an approximately 1,370,000 square foot (sq ft) warehouse building located to the west of Interstate I-485. The Site building is currently used for warehousing, manufacturing, and distribution. Site PIN 20302139 is currently vacant wooded land. A Site location map is provided as Figure 1. The Brownfields property and surrounding area were formerly occupied by the United States Navy from approximately 1949 through 1967. Former use of the Site as a Naval Ammunitions Depot (NAD) included operations consisting of numerous buildings surrounded by protective soil berms based on a 1950 aerial photograph and a 1950 map of the former NAD. Following NAD operations, the Site was occupied by Continental Tire and used for tire manufacturing from 1967 through 2013. The Site received updated eligibility (following execution of the Brownfields Agreement for the REEP-LRC Brownfields property [Brownfields Project No. 17047-13-060]) into the North Carolina Department of Environmental Quality (DEQ) Brownfields Program via a Letter of Eligibility dated February 27, 2020. Redevelopment activities for the Brownfields property have been conducted in accordance with an Environmental Management Plan (EMP) approved by 2 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Somerset Properties (SSP)/Continental Tire (SSP-001)/Brownfields Assessment/Additional VI Assessment/Final Report/VI Assessment Report_REEP-LRC(RN).doc DEQ on June 3, 2021. These activities have included the installation of a pre-fabricated fire pump house in the southwestern portion of the Site, renovations to the northwestern portion of the existing warehouse building, installation of a new road that circulates existing structures and will allow access for future development on the adjacent REEP-LRC Brownfields property, and temporary off-Site stockpiling of soil on the REEP-LRC Brownfields property (PIN 20308305) for later beneficial reuse. The Site and surrounding area are shown on Figure 2. The existing warehouse building located on PIN 20308301 is divided into the following tenant spaces, which are identified on Figure 2: • Suites A, G, and H – Spirit Halloween • Suite B – Professional Builders Supply • Suite C – Harris Tire • Suite D – Darnell • Suites E and F – Synders Lance • Suite I – United States Postal Service (USPS) • Suite J – Siemens/ Deufol Charlotte, LLC • Suite K – SnapAV On September 24, 2020, H&H, the PD, and the PD’s legal counsel participated in a conference call with DEQ Brownfields personnel to discuss Site history, areas of potential environmental concern, proposed redevelopment plans, potential data gaps, and the scope of Brownfields assessment activities needed to address the data gaps. To address DEQ’s request for additional assessment on Site PINs 20308301 and 20302139, H&H submitted an Additional Brownfields Assessment Work Plan (Work Plan) dated November 19, 2020, and revised on February 4, 2021. The Work Plan was approved by DEQ Brownfields in an email dated February 19, 2021. As part of property transaction due diligence conducted on PIN 20308301 and Brownfields assessment activities conducted in November 2019 and March 2021 (post-approval of the aforementioned Work Plan), respectively, H&H performed sampling activities to assess potential 3 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Somerset Properties (SSP)/Continental Tire (SSP-001)/Brownfields Assessment/Additional VI Assessment/Final Report/VI Assessment Report_REEP-LRC(RN).doc structural vapor intrusion into the existing warehouse building. Results of sub-slab vapor assessment activities indicate that calculated cumulative risk values for the soil gas to indoor air vapor intrusion pathway were within acceptable risk levels for potential carcinogenic risks (1 x 10-4) and non-carcinogenic risks (1.0). Based on the presence of trichloroethylene (TCE) in sub-slab vapor samples collected during the 2019 and 2021 sampling events, DEQ Brownfields requested additional vapor intrusion assessment for the warehouse building in an email dated June 9, 2022. In the email, DEQ stated that the February 2021 Work Plan and procedures provided in subsequent email correspondence from H&H could be used to execute the requested scope of work. In accordance with the Work Plan and approved scope of work, vapor intrusion assessment activities were conducted by H&H within the existing warehouse building located on PIN 20308301. A summary of historical assessment activities conducted on PIN 20308301 and recently completed vapor intrusion assessment activities for PIN 20308301 are provided in the following sections. 4 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Somerset Properties (SSP)/Continental Tire (SSP-001)/Brownfields Assessment/Additional VI Assessment/Final Report/VI Assessment Report_REEP-LRC(RN).doc 2.0 Historical Use Information – PIN 20308301 Multiple phases of environmental assessments have been conducted at the Brownfields property since 2007. The assessments were conducted under the purview of the DEQ Underground Storage Tank (UST) Section, Inactive Hazardous Sites Branch (IHSB), and the Brownfields Program. Known releases associated with PIN 20308301 include the former Wash Rack area (UST Section No Further Action status in June 2010), the former Boiler Day Tanks area (UST Section No Further Action status in June 2010), the former Naphtha UST area (UST Section Conditional No Further Action status and Notice of Residual Petroleum filed in 2003), the former Rail Off-Loading Area (UST Section Conditional No Further Action status in January 2020), and the former Buffing Dust Shed (active IHSB incident). H&H understands that Continental Tire is identified by DEQ as the responsible party for the active Buffing Dust Shed IHSB incident, and that ongoing off-Site vapor intrusion assessment activities are currently underway. Historical soil assessment activities completed on PIN 20308301 in 2009 to assess conditions associated with the former Buffing Dust Shed indicate low levels of several volatile organic compounds (VOCs) were detected in surficial soil samples at concentrations above laboratory detection limits, but below the DEQ Industrial/Commercial Preliminary Soil Remediation Goals (PSRGs). In addition, low levels of several metals were detected at concentrations above the laboratory method detection limits, but aside from arsenic (up to 5.5 milligrams per kilogram [mg/kg]), no metals were detected at concentrations above the DEQ Industrial/Commercial PSRGs. Concentrations of arsenic and other metals are consistent with published background ranges in the Site region. Historical groundwater assessment activities conducted on PIN 20308301 dating back to 2009 have identified the presence of multiple compounds at concentrations above the DEQ 15A North Carolina Administrative Code (NCAC) 02L .0202 Groundwater Quality Standards (2L Standards). Compounds detected above 2L Standards include, but are not limited to, iron and manganese, polycyclic aromatic hydrocarbons (PAHs), and VOCs benzene, 1,1-dichloroethane, 1,2-dichloroethane, carbon tetrachloride, tetrachloroethylene (PCE), trichloroethylene (TCE), 5 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Somerset Properties (SSP)/Continental Tire (SSP-001)/Brownfields Assessment/Additional VI Assessment/Final Report/VI Assessment Report_REEP-LRC(RN).doc and vinyl chloride. As part of property transaction due diligence conducted on PIN 20308301 in November 2019, H&H performed sampling activities to assess potential structural vapor intrusion into the existing warehouse building. Specifically, the vapor intrusion assessment activities included installation and sampling of nine sub-slab vapor points in the Deufol tenant space (SS-6 through SS-9) and a vacant tenant space (SS-3 through SS-5) due to their proximity to documented soil and groundwater impacts associated with the aforementioned UST and IHSB incidents. Two sub- slab vapor points (SS-1 and SS-2) were also installed in the northwestern portion of the warehouse building where former tire sealant operations were conducted. The vapor intrusion assessment activities were conducted in accordance with DEQ Division of Waste Management (DWM) Vapor Intrusion Guidance (VI Guidance) dated March 2018. Laboratory analytical results indicated that low levels of VOCs were detected above laboratory method detection limits in each sub-slab vapor sample. Of the compounds detected, 1,1- dichloroethane was detected at a concentration that exceeds the January 2021 Non-Residential Sub-Slab and Exterior Soil Gas Screening Level (SGSL) of 770 micrograms per cubic meter (µg/mPP 3 PP) in sub-slab vapor sample SS-9 (2,200 µg/mPP 3 PP) in the administrative office area. No other compounds were detected above Non-Residential SGSLs. In addition, DEQ risk calculator results indicated calculated cumulative risks for a non-residential worker are within the acceptable carcinogenic risk of less than 1 x 10PP -4 PP and less than a hazard index of 1. In March 2021, three additional sub-slab vapor samples were installed and sampled in the loading dock area of the Deufol tenant space (SS-10 through SS-12) to further evaluate the potential for structural vapor intrusion into the warehouse building on PIN 20308301 as requested by DEQ Brownfields. Laboratory analytical results indicated that low levels of VOCs were detected above laboratory method detection limits in the sub-slab vapor samples but below Non-Residential SGSLs. In addition, 1,1-dichloroethane, a compound that was previously detected at a concentration above the Non-Residential SGSL, was not detected above laboratory method detection limits during the March 2021 sampling event. H&H calculated cumulative risks using the highest concentrations of compounds detected in any sub-slab vapor sample 6 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Somerset Properties (SSP)/Continental Tire (SSP-001)/Brownfields Assessment/Additional VI Assessment/Final Report/VI Assessment Report_REEP-LRC(RN).doc collected during the November 2019 and/or March 2021 sampling events to check a hypothetical worst-case scenario. Results of sub-slab vapor assessment activities indicated that calculated cumulative risk values for the soil gas to indoor air vapor intrusion pathway were within the acceptable carcinogenic risk of less than 1 x 10PP -4 PP and less than a hazard index of 1. H&H further evaluated the potential for vapor intrusion utilizing groundwater data from monitoring wells installed under or within 100 ft of the Site building. Based on comparison of groundwater analytical data to the February 2018 DEQ Non-Residential Ground Water Screening Levels (GWSLs), no exceedances were identified except for a concentration of cyclohexane (2,000 micrograms per liter [µg/L]) detected in MW002 in March 2015. The cyclohexane concentration was above its DWM Non-Residential GWSL of 860 µg/L. However, cyclohexane was not detected above laboratory reporting limits in any of the sub-slab vapor samples. As such, cyclohexane in groundwater does not appear to pose a vapor intrusion risk. 7 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Somerset Properties (SSP)/Continental Tire (SSP-001)/Brownfields Assessment/Additional VI Assessment/Final Report/VI Assessment Report_REEP-LRC(RN).doc 2.0 Sub-Slab Vapor Assessment Activities Between July 19 and 20, 2022, H&H collected 10 sub-slab vapor samples (SS-13 through SS-22) from several tenant spaces to further evaluate the potential for structural vapor intrusion into tenant spaces associated with the 1900 Continental Building (PIN 20308301). The sub-slab vapor sample locations were collected in combination with co-located indoor air samples (see Section 3.0 for indoor air assessment activities). The sub-slab vapor sample locations (denoted by SS nomenclature) and indoor air sample locations (denoted by IAS nomenclature) are shown on Figure 3. Details of the sub-slab vapor assessment activities and results are provided in the following sections. 2.1 Sub-Slab Vapor Sampling Methodology The sub-slab vapor monitoring points were installed by utilizing a hammer drill and 1½-inch diameter drill bit to advance a pilot hole into the concrete slab to a depth of approximately 1¾ inches below the surface. A drill guide was then placed in the pilot hole, and a 5/8-inch diameter drill bit was utilized to advance the boring through the concrete slab. Following concrete borehole advancement, loose concrete cuttings were removed from the boring using a bottlebrush and vacuum with a high efficiency particulate air (HEPA) filter. A Cox-Colvin Vapor Pin™ (vapor pin) assembly (brass sampling point and silicone sleeve) was seated in the borehole using an installation/extraction tool and hammer. Once the vapor pin assembly was secured in the pilot hole, ¼-inch diameter TeflonPP ® PP sample tubing was attached to the vapor pin assembly sample port barb. Prior to sampling, sub-slab vapor monitoring points were allowed to equilibrate for at least two hours following installation. As part of sub-slab vapor sample collections procedures, “shut-in” tests and leak checks were performed at each sub-slab vapor monitoring point. The purpose of the shut-in test and helium leak check is to ensure that short circuiting with ambient air does not occur during sampling. A description of the shut-in test and helium leak testing procedures is provided below. The shut-in test was conducted by connecting an in-line airflow controller with a vacuum gauge to a laboratory supplied batch-certified 1-liter stainless steel SummaPP ® PP canister and sealing the 8 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Somerset Properties (SSP)/Continental Tire (SSP-001)/Brownfields Assessment/Additional VI Assessment/Final Report/VI Assessment Report_REEP-LRC(RN).doc flow regulator with a laboratory provided brass nut and ferrule assembly to form an air-tight seal. The airflow regulator was pre-set by the laboratory to regulate the sub-slab vapor intake rate to approximately 200 milliliters per minute. Once the sampling train was “closed”, the sample valve on the SummaPP ® PP canister was opened and the reading on the vacuum gauge was recorded. The SummaPP ® PP canister sample valve was then closed, and the vacuum gauge was observed to ensure no vacuum loss occurs. Because the vacuum readings remained the same before and after closure of the canister sample valve, the shut-in tests were considered successful for each sub- slab vapor point. Following successful shut-in tests, leak checks were conducted by constructing a shroud around the sample train at each sampling point and flooding the air with helium gas. Helium concentrations inside the shroud were measured using a calibrated helium gas detector and maintained at concentrations of approximately 10% to 20% for the duration of the leak check. Using a syringe and three-way valve, a helium sample was collected from the TeflonPP ® PP sample tubing outside the shroud and into a Tedlar bag. The helium sample was analyzed using the helium gas detector to ensure that helium concentrations were less than 10% of the helium concentrations measure within the shroud. All of the sub-slab vapor monitoring points passed the leak check. Following a successful leak check, the intake valve on the SummaPP ® PP canister was fully opened to begin collection of the sub-slab vapor sample. Vacuum readings on the SummaPP ® PP canister were recorded prior to and following the sampling period to ensure adequate sample volume was collected. Per laboratory standard operating procedures, a vacuum of between approximately three and seven inches of mercury was maintained on the sample canisters until the conclusion of the sampling event. Laboratory provided vacuum gauges used for collection of field measurements are intended for qualitative field use. As such, field measured pre- and post- sampling vacuum readings are not expected to impact laboratory analytical results based on other considerations such as sub-slab vapor sampling procedures (i.e., shut-in tests and leak checks) and post-sampling canister pressures measured by the laboratory. Therefore, H&H concludes that field and laboratory data generally meet project objectives and are usable for the intended purpose. 9 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Somerset Properties (SSP)/Continental Tire (SSP-001)/Brownfields Assessment/Additional VI Assessment/Final Report/VI Assessment Report_REEP-LRC(RN).doc After sample collection, the SummaPP ® PP canister sample valves were closed prior to disassembly of the sampling train. The SummaPP ® PP canisters were then placed in laboratory supplied shipping containers, properly labeled, and shipped under standard chain-of-custody protocols to Con-test for analysis of VOCs by EPA Method TO-15. For quality assurance/quality control (QA/QC) purposes, a duplicate sub-slab vapor sample (SS-DUP) was collected from sub-slab vapor monitoring point SS-21. Upon receipt of the samples, the laboratory recorded the final received vacuum pressure for each Summa canister. The initial, post-sampling, and lab receipt canister vacuum pressures are indicated on the sub-slab vapor QA/QC field forms in Appendix A and in the laboratory analytical reports included in Appendix B. Upon completion of the final sampling event, the sub-slab vapor sampling point locations were estimated in the field using known benchmarks (i.e., walls, doors, etc.) and then abandoned to match surrounding surface conditions. 2.2 Sub-Slab Vapor Sampling Analytical Results A tabular summary of sub-slab vapor sample analytical results is presented in Table 1, and the laboratory analytical reports and chain of custody records are provided in Appendix B. Sub-slab vapor sample analytical results were compared to the July 2022 DEQ Non-Residential Sub-Slab and Exterior Soil Gas Screening Levels (SGSLs). Laboratory analytical results indicated that low levels of VOCs were detected above laboratory method detection limits in each sub-slab vapor sample. Of the compounds detected, 1,1- dichloroethane was detected at a concentration above the Non-Residential SGSL of 770 micrograms per cubic meter (µg/m3) in sub-slab vapor sample SS-19 (3,700 µg/m3) in the Siemens/Deufol tenant space (Suite J). Additionally, TCE was detected at a concentration of 1,200 µg/m3 in sub-slab vapor sample SS-21 (and associated duplicate sample [SS-DUP]) in the USPS tenant space, which is above the Non-Residential SGSL. TCE was not detected above the Non-Residential SGSL in any other sub-slab vapor sample collected in July 2022. No other compounds were detected above Non-Residential SGSLs. 10 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Somerset Properties (SSP)/Continental Tire (SSP-001)/Brownfields Assessment/Additional VI Assessment/Final Report/VI Assessment Report_REEP-LRC(RN).doc 2.3 DEQ DWM Risk Calculations The DEQ DWM SGSLs are conservative and based on a lifetime incremental cancer risk (LICR) for potential carcinogenic risks of 1 x 10-6 and a non-carcinogenic hazard quotient (HQ) of 0.2 for potential non-carcinogenic risks. The DEQ acceptable risk level for potential carcinogenic risks is 1 x 10-4 or less and the acceptable level for non-carcinogenic risks is a hazard index (HI) less than 1.0. H&H utilized the July 2022 DEQ risk calculator assuming a non-residential land use scenario (based on the current Site use) to evaluate calculated cumulative risks for the soil gas (i.e., sub- slab vapor) to indoor air vapor intrusion pathway in the tenant spaces evaluated. H&H initially calculated cumulative risk using the highest concentrations of compounds detected in any sub- slab vapor samples collected for each tenant space to check a hypothetical worst-case scenario (1). In addition, H&H calculated cumulative risk using the highest concentrations of compounds detected in any sub-slab vapor samples sans SS-21 (due to TCE) to check a hypothetical worst- case scenario (2) for all tenant spaces excluding USPS. Results of the risk calculations are summarized below and included in Appendix C. Sub-Slab Vapor Sample Location Non-Residential Worker Carcinogenic Risk Hazard Index Worst-Case Scenario 1 (with SS-21) 1.0 x 10-5 1.5 Worst-Case Scenario 2 (without SS-21) 6.5 x 10-6 0.13 Value in bold exceeds acceptable risk levels. As shown in the table above, the results of the calculated cumulative risks for a non-residential worker exceed acceptable levels (calculated cumulative carcinogenic risks below 1 x 10-4 and HI >1.0) under Worst-Case Scenario 1. Calculated cumulative risks for a non-residential worker under Worst-Case Scenario 2 are within the acceptable carcinogenic risk of less than 1 x 10-4 and less than a hazard index of 1.0. After further review of the worst-case scenario risk calculations, the driver of the cumulative HI 11 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Somerset Properties (SSP)/Continental Tire (SSP-001)/Brownfields Assessment/Additional VI Assessment/Final Report/VI Assessment Report_REEP-LRC(RN).doc is TCE with an individual HI of 1.4. As discussed in Section 3.3, co-located indoor air samples were collected to further evaluate the attenuation factor of the concrete slab within the Site building and the potential vapor intrusion pathway. 12 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Somerset Properties (SSP)/Continental Tire (SSP-001)/Brownfields Assessment/Additional VI Assessment/Final Report/VI Assessment Report_REEP-LRC(RN).doc 3.0 Indoor Air Assessment Activities On July 18, 2022, H&H collected 10 indoor air samples (IAS-1 through IA-10) from tenant spaces within the Site building. The indoor air sample locations (denoted by IAS nomenclature) were co-located with sub-slab vapor monitoring points (denoted by SS nomenclature), as shown on Figure 3. Details of the indoor air assessment activities and results are provided in the following sections. 3.1 Indoor Air Sampling Methodology Prior to indoor air sample collection, H&H conducted a survey within each tenant space evaluated to identify materials within the space that could potentially influence indoor air testing. No obvious chemicals of concern were identified. The indoor air survey forms for each tenant space are provided in Appendix D. Indoor air samples were collected with the windows and doors of the tenant spaces closed and ingress and egress activities minimized to the extent practical. Bay doors were intermittently opened during indoor air sampling in the Professional Builder’s Supply (Suite B) and Snap AV (Suite K) while briefly loading and unloading of trucks was performed. The samples were collected while the HVAC systems were running normally in each of the tenant spaces. The indoor air samples were collected using individually-certified 6-liter stainless steel SummaPP ®PP canisters connected to in-line flow controllers with a vacuum gauge. The flow controllers were set so that the samples were collected over an approximate 8-hour period. A 3-foot-long sampling cane was connected to the flow controller so that the sample intake point was positioned approximately 5 ft above grade (typical breathing zone height) when the sample canister is set on its base. Exterior wind speed and direction, indoor and outdoor temperature, and indoor/outdoor air differential pressure were measured near the start, middle, and end of the sampling period. At the end of the 8-hour sample period, the sample canister’s valves were closed to stop sample collection. An Indoor Air Sampling Form which includes field measurements of temperature, differential pressure, wind direction, and wind speed is included in Appendix A. 13 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Somerset Properties (SSP)/Continental Tire (SSP-001)/Brownfields Assessment/Additional VI Assessment/Final Report/VI Assessment Report_REEP-LRC(RN).doc Prior to and after the indoor air samples were collected, vacuum in the canisters was measured using the laboratory-supplied vacuum gauge and recorded on the chain-of-custody by sampling personnel. The sample canisters were then labeled and shipped under standard chain-of-custody protocols to Con-test for analysis of select VOCs by EPA Method TO-15. For quality control purposes, one duplicate indoor air sample (IAS-DUP) was collected from the IAS-5 sample location and submitted for the same analysis. 3.2 Indoor Air Sampling Analytical Results Results of indoor air analysis are summarized in Table 2. The laboratory analytical report and chain of custody record are provided in Appendix B. Indoor air analytical results were compared to the July 2022 DEQ Non-Residential Indoor Air Screening Levels (IASLs) which are based on a LICR for potential carcinogenic risks of 1 x 10-6 and a non-carcinogenic HQ of 0.2. Laboratory analytical results indicated that low levels of VOCs were detected above laboratory method detection limits in each indoor air sample. Of the compounds detected, ethylbenzene and naphthalene were detected at concentrations above the Non-Residential IASLs. Specifically, ethylbenzene was detected at concentrations ranging from 5.0 to 15 µg/m3 in indoor air samples IAS-1, IAS-5, and IAS-10. Additionally, naphthalene was detected at concentrations ranging from 0.37 to 1.4 µg/m3 in indoor air samples IAS-4, IAS-5, IAS-6, IAS-9, and IAS-10. slightly above the Non-Residential IASL of 0.36 µg/m3 at five sampling locations with concentrations ranging from 0.37 to 1.4 µg/m3. No other compounds were detected above Non-Residential IASLs. It should be further noted that TCE was detected in only two indoor air samples at concentrations well below the Non-Residential IASL of 1.8 µg/m3. Of the detections of TCE in indoor air, neither were associated with samples collected from the USPS tenant space. 3.3 DEQ DWM Risk Calculations H&H utilized the July 2022 DEQ risk calculator assuming a non-residential land use scenario to evaluate calculated cumulative risks for the indoor air vapor intrusion pathway in each sampled tenant space. H&H calculated cumulative risk using the highest concentrations of compounds 14 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Somerset Properties (SSP)/Continental Tire (SSP-001)/Brownfields Assessment/Additional VI Assessment/Final Report/VI Assessment Report_REEP-LRC(RN).doc detected in each indoor air sample collected during the July 2022 sampling event to evaluate each of tenant spaces. Results of the risk calculations are summarized below and included in Appendix C. Indoor Air Sample Location Non-Residential Worker Carcinogenic Risk Hazard Index IAS-1 3.5 x 10-6 0.16 IAS-2 1.7 x 10-6 0.089 IAS-3 1.8 x 10-6 0.095 IAS-4 2.3 x 10-6 0.14 IAS-5/IAS-DUP 4.5 x 10-6 0.26 IAS-6 4.4 x 10-6 0.30 IAS-7 2.2 x 10-6 0.063 IAS-8 1.1 x 10-6 0.066 IAS-9 2.6 x 10-6 0.087 IAS-10 1.3 x 10-5 0.89 As shown in the table above, calculated cumulative risks for a non-residential worker scenario are within the acceptable carcinogenic risk of less than 1 x 10-4 and less than a hazard index of 1.0. Based on the evaluation of the July 2022 DEQ risk calculator results, there is no evidence of a significant vapor intrusion concern for non-residential workers and therefore mitigation measures to protect non-residential workers do not appear warranted. 15 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Somerset Properties (SSP)/Continental Tire (SSP-001)/Brownfields Assessment/Additional VI Assessment/Final Report/VI Assessment Report_REEP-LRC(RN).doc 4.0 Summary and Conclusions H&H has completed vapor intrusion assessment activities for the warehouse building on the REEP-LRC II Brownfields property located in Charlotte, North Carolina. Brownfields assessment activities included collection of sub-slab vapor and indoor air samples to further evaluate potential structural vapor intrusion. A brief summary of the Brownfields assessment activities is provided below. • Results of sub-slab vapor assessment activities indicate that 1,1-dichloroethane and TCE were detected above the Non-Residential SGSLs in at least one of the sub-slab vapor samples. Calculated cumulative risk values for the soil gas to indoor air vapor intrusion pathway for a non-residential worker exceed acceptable risk limits in the USPS tenant space. • Results of indoor air assessment activities indicate that ethylbenzene and naphthalene were detected above the Non-Residential SGSLs in at least one of the indoor air samples. Calculated cumulative risk values for the indoor vapor intrusion pathway air for a non- residential worker are within the acceptable carcinogenic risk of less than 1 x 10-4 and less than a hazard index of 1.0. In summary, results of vapor intrusion assessment activities indicate that structural vapor intrusion into the warehouse building does not pose a significant risk for typical commercial and/or industrial uses (i.e., those without sensitive populations). Based upon the results, additional assessment does not appear warranted, and impacted media or media disturbed during future redevelopment activities can be managed in accordance with the DEQ-approved EMP and/or land use restrictions as outlined in a negotiated Brownfields Agreement. Table 1 Summary of Sub-Slab Vapor Analytical Data REEP-LRC(RN) 1900 Continental Blvd. Charlotte, North Carolina H&H Job No. SSP-001 SS-5 SS-DUP 11/1/2019 11/1/2019 11/1/2019 11/1/2019 11/1/2019 11/1/2019 VOCs (TO-15) (µg/m3)Non-Residential SGSLs1 Acetone NE 190 26 26 300 <66 <66 Benzene 160 0.32 J <0.26 0.31 J 4.5 <2.6 <2.6 Carbon disulfide 8,800 1.2 J <0.43 4.7 J 8.4 <4.3 <4.3 Chloroform 53 <0.36 <0.36 0.51 J <0.36 <3.6 <3.6 Chloromethane 7,900 <0.28 <0.28 <0.28 <0.28 <0.28 <0.28 Cyclohexane 530,000 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 1,3-Dichlorobenzene NE <0.62 <0.62 <0.62 <0.62 <0.62 <0.62 Dichlorodifluoromethane (Freon 12) 8,800 2.7 2.8 2.7 <0.43 <4.3 <4.3 1,1-Dichloroethane 770 <0.25 <0.25 4.3 <0.25 <2.5 <2.5 1,1-Dichloroethylene 18,000 <0.43 <0.43 3.8 <0.43 160 170 cis-1,2-Dichloroethylene NE <0.32 <0.32 20 <0.32 <3.2 <3.2 trans-1,2-Dichloroethylene 3,500 <0.32 <0.32 0.76 J <0.32 <3.2 <3.2 1,4-Dioxane 250 25 <4.6 <4.6 <4.6 <46 <46 Ethanol NE 240 790 250 330 130 J 140 J Ethyl Acetate 6,100 <0.54 <0.54 <0.54 <0.54 <5.4 <5.4 Ethylbenzene 490 <0.50 <0.50 <0.50 1.4 <5.0 <5.0 4-Ethyltoluene NE <0.60 <0.60 <0.60 0.90 J <6.0 <6.0 Heptane 35,000 <0.48 <0.48 <0.48 5.5 <4.8 <4.8 Hexane 61,000 <1.2 <1.2 <1.2 2.1 J <12 <12 2-Hexanone (Methyl butyl ketone) 2,600 <0.49 <0.49 <0.49 5.4 <4.9 <4.9 Isopropanol 18,000 13 J 7.6 J 7.1 J 40 <9.0 <9.0 Methyl ethyl ketone (2-Butanone) 440,000 3.9 J 5.9 J 5.5 J 33 <11 <11 4-Methyl-2-pentanone (MIBK) 260,000 3.8 6.2 <0.43 7.8 <4.3 <4.3 Naphthalene 36 0.88 J <0.80 <0.80 <0.80 <8.0 <8.0 Propene 260,000 <0.64 <0.64 <0.64 <0.64 <0.64 <0.64 Styrene 88,000 <0.53 <0.53 <0.53 0.72 J <5.3 <5.3 Tetrachloroethylene 3,500 11 12 6.1 25 280 310 Tetrahydrofuran 180,000 1.8 J <0.59 <0.59 <0.59 <5.9 <5.9 Toluene 440,000 0.78 <0.39 0.50 J 7.9 <3.9 <3.9 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 440,000 <1.2 <1.2 <1.2 <1.2 <12 <12 1,1,1-Trichloroethane 440,000 0.50 J 1.1 0.46 J 2.6 15,000 15,000 Trichloroethylene 180 4.3 <0.43 12 1.6 <4.3 <4.3 Trichlorofluoromethane (Freon 11) NE 5.3 13 9.1 26 100 120 1,2,4-Trimethylbenzene 5,300 <0.63 <0.63 <0.63 <0.63 <6.3 <6.3 1,3,5-Trimethylbenzene 5,300 <0.62 <0.62 <0.62 1.0 <6.2 <6.2 Vinyl chloride 280 <0.32 <0.32 <0.32 <0.32 <3.2 <3.2 m-/p-Xylenes 8,800 1.4 J <1.0 <1.0 2.7 <10 <10 o-Xylene 8,800 <0.54 <0.54 <0.54 1.4 <5.4 <5.4 Former Continental Tire North America Vacant Tenant Space Sample Date Sample Location (Unit)2 SS-1 SS-2 SS-3 SS-4 SS-5Sample ID https://harthick.sharepoint.com/sites/MasterFiles‐1/Shared Documents/AAA‐Master Projects/Somerset Properties (SSP)/Continental Tire (SSP‐001)/Brownfields Assessment/Additional VI Assessment/VI MASTER TABLE 2021‐03_Updated 08312022 9/9/2022 Table 1 (Page 1 of 3) Hart & Hickman, PC Table 1 Summary of Sub-Slab Vapor Analytical Data REEP-LRC(RN) 1900 Continental Blvd. Charlotte, North Carolina H&H Job No. SSP-001 VOCs (TO-15) (µg/m3)Non-Residential SGSLs1 Acetone NE Benzene 160 Carbon disulfide 8,800 Chloroform 53 Chloromethane 7,900 Cyclohexane 530,000 1,3-Dichlorobenzene NE Dichlorodifluoromethane (Freon 12) 8,800 1,1-Dichloroethane 770 1,1-Dichloroethylene 18,000 cis-1,2-Dichloroethylene NE trans-1,2-Dichloroethylene 3,500 1,4-Dioxane 250 Ethanol NE Ethyl Acetate 6,100 Ethylbenzene 490 4-Ethyltoluene NE Heptane 35,000 Hexane 61,000 2-Hexanone (Methyl butyl ketone) 2,600 Isopropanol 18,000 Methyl ethyl ketone (2-Butanone) 440,000 4-Methyl-2-pentanone (MIBK) 260,000 Naphthalene 36 Propene 260,000 Styrene 88,000 Tetrachloroethylene 3,500 Tetrahydrofuran 180,000 Toluene 440,000 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 440,000 1,1,1-Trichloroethane 440,000 Trichloroethylene 180 Trichlorofluoromethane (Freon 11) NE 1,2,4-Trimethylbenzene 5,300 1,3,5-Trimethylbenzene 5,300 Vinyl chloride 280 m-/p-Xylenes 8,800 o-Xylene 8,800 Sample Date Sample Location (Unit)2 Sample ID SS-10 SS-DUP 11/1/2019 11/1/2019 11/1/2019 11/1/2019 3/9/2021 3/9/2021 3/9/2021 3/9/2021 51 30 580 81 67 78 370 820 <0.26 0.27 J 3.3 2.9 0.98 <0.19 <0.19 2.2 <0.43 4.6 J 4.9 J 6.4 <1.6 <1.6 <1.6 <1.6 <0.36 <0.36 <0.36 2.3 4.4 5.1 7.1 4.2 <0.28 <0.28 <0.28 <0.28 <0.32 <0.32 <0.32 <0.32 <0.49 <0.49 <0.49 <0.49 <0.34 <0.34 <0.34 <0.34 <0.62 <0.62 <0.62 <0.62 <0.44 <0.44 <0.44 <0.44 2.7 2.7 <0.43 2.9 <0.31 <0.31 <0.31 <0.31 <0.25 <0.25 <0.25 2,200 <0.25 <0.25 <0.25 <0.25 <0.43 <0.43 <0.43 2,200 <0.43 <0.43 <0.43 <0.43 <0.32 <0.32 <0.32 <0.32 <0.27 <0.27 <0.27 6.9 <0.32 <0.32 <0.32 <0.32 <0.23 <0.23 <0.23 <0.23 <4.6 <4.6 <4.6 7.0 J <2.0 <2.0 16 14 160 170 210 2,000 350 430 810 1,200 <0.54 <0.54 <0.54 2.9 <4.3 <4.3 <4.3 <4.3 <0.50 0.71 J 30 0.83 J 4.5 5.5 5.9 4.0 <0.60 <0.60 4.5 3.1 2.2 <0.30 <0.30 <0.30 <0.48 <0.48 <0.48 0.70 J <0.35 <0.35 <0.35 <0.35 <1.2 <1.2 <1.2 <1.2 <1.3 5.0 J <1.3 <1.3 <0.49 <0.49 <0.49 <0.49 <0.46 <0.46 <0.46 <0.46 13 J 10 J <0.90 140 58 40 130 74 4.9 J 4.2 J 21 J 8.4 J <2.0 6.8 J 20 J 45 <0.43 1.9 14 <0.43 <0.43 <0.43 <0.43 <0.43 <0.80 <0.80 18 <0.80 <0.59 <0.59 <0.59 11 <0.64 <0.64 <0.64 <0.64 <1.2 <1.2 <1.2 <1.2 <0.53 <0.53 <0.53 <0.53 <0.24 <0.24 <0.24 <0.24 64 16 2,500 52 50 55 1,500 240 <0.59 <0.59 <0.59 2.5 <1.5 <1.5 <1.5 <1.5 <0.39 0.56 J 73 3.7 7.4 7.8 16 8.2 <1.2 1.7 J 3.6 J 7.7 <1.2 <1.2 <1.2 <1.2 0.68 J <0.41 12 2.2 <0.36 <0.36 6.5 7.4 1.1 J 4.5 23 20 <0.40 <0.40 4.4 69 3.7 J 2.5 J 11 1.7 J 8.5 9.4 13 3.9 J <0.63 <0.63 17 <0.63 9.6 11 4.1 6.4 <0.62 <0.62 5.2 6.4 4.9 5.7 1.0 1.7 <0.32 <0.32 <0.32 1.5 <0.29 <0.29 <0.29 <0.29 <1.0 2.8 99 2.5 25 28 18 12 <0.54 1.0 30 1.0 10 11 5.9 4.7 Deufol Tenant Space SS-6 SS-7 SS-8 SS-9 SS-10 SS-11 SS-12 https://harthick.sharepoint.com/sites/MasterFiles‐1/Shared Documents/AAA‐Master Projects/Somerset Properties (SSP)/Continental Tire (SSP‐001)/Brownfields Assessment/Additional VI Assessment/VI MASTER TABLE 2021‐03_Updated 08312022 9/9/2022 Table 1 (Page 2 of 3) Hart & Hickman, PC Table 1 Summary of Sub-Slab Vapor Analytical Data REEP-LRC(RN) 1900 Continental Blvd. Charlotte, North Carolina H&H Job No. SSP-001 VOCs (TO-15) (µg/m3)Non-Residential SGSLs1 Acetone NE Benzene 160 Carbon disulfide 8,800 Chloroform 53 Chloromethane 7,900 Cyclohexane 530,000 1,3-Dichlorobenzene NE Dichlorodifluoromethane (Freon 12) 8,800 1,1-Dichloroethane 770 1,1-Dichloroethylene 18,000 cis-1,2-Dichloroethylene NE trans-1,2-Dichloroethylene 3,500 1,4-Dioxane 250 Ethanol NE Ethyl Acetate 6,100 Ethylbenzene 490 4-Ethyltoluene NE Heptane 35,000 Hexane 61,000 2-Hexanone (Methyl butyl ketone) 2,600 Isopropanol 18,000 Methyl ethyl ketone (2-Butanone) 440,000 4-Methyl-2-pentanone (MIBK) 260,000 Naphthalene 36 Propene 260,000 Styrene 88,000 Tetrachloroethylene 3,500 Tetrahydrofuran 180,000 Toluene 440,000 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 440,000 1,1,1-Trichloroethane 440,000 Trichloroethylene 180 Trichlorofluoromethane (Freon 11) NE 1,2,4-Trimethylbenzene 5,300 1,3,5-Trimethylbenzene 5,300 Vinyl chloride 280 m-/p-Xylenes 8,800 o-Xylene 8,800 Sample Date Sample Location (Unit)2 Sample ID SS-21 SS-DUP 7/19/2022 7/19/2022 7/19/2022 7/19/2022 7/20/2022 7/20/2022 7/20/2022 7/20/2022 7/20/2022 7/20/2022 7/20/2022 Spirit Halloween Darnell Builders Supply (Area of SS-1) Builders Supply (Area of SS-2) Siemens/Deufol (Area of SS-9) Siements/Deufol (Area of SS-12) 450 190 140 130 99 4100 230 180 92 79 88 0.74 0.61 J 0.75 0.72 0.82 9.9 10 0.95 2.1 2.1 <0.48 2.5 J 2.8 J 1.2 J 1.3 J 1.7 J 7.5 7.9 2.8 J 1.3 J 1.6 J 1.7 J <0.93 <0.93 <0.93 2.9 <0.93 <0.93 5.6 <0.93 <0.93 <0.93 <0.93 1.1 0.74 J 0.61 J <0.33 0.72 J <0.33 <0.33 0.78 J <0.33 <0.33 <0.33 4.5 3.1 5.7 3.8 3.0 <0.42 3.5 4.2 4.7 3.6 <0.42 71 46 84 78 45 71 24 58 64 63 <0.67 2.6 2.6 2.0 2.7 4.3 2.4 2.8 2.5 2.7 2.6 2.4 <0.71 <0.71 <0.71 <0.71 <0.71 <0.71 3,700 <0.71 58 56 <0.71 <0.60 <0.60 <0.60 <0.60 <0.60 <0.60 3,500 <0.60 3.4 3.4 <0.60 <0.58 <0.58 <0.58 <0.58 <0.58 <0.58 <0.58 <0.58 350 340 <0.58 <0.62 <0.62 <0.62 <0.62 <0.62 <0.62 <0.62 <0.62 49 48 <0.62 <0.60 <0.60 130 <0.60 <0.60 16 8.0 10 2.9 J <0.60 <0.60 460 680 630 830 370 880 370 7.6 J 300 290 300 10 <3.6 5.3 J 6.5 J 78 <3.6 <3.6 4.0 J <3.6 <3.6 <3.6 3.1 1.2 1.6 2.1 1.5 64 1.1 3.8 2.8 2.6 0.99 1.7 <0.60 0.77 J 0.88 J <0.60 22 <0.60 1.0 0.92 J 0.88 J <0.60 1.7 1.3 2.3 2.1 2.0 3.2 0.90 2.2 3.4 3.8 1.2 10 J 7.5 J 9.3 J 8.0 J 9.5 J 11 J 7.2 J 8.1 J 11 J 11 J 6.1 J <0.41 <0.41 <0.41 <0.41 <0.41 95 <0.41 <0.41 <0.41 <0.41 <0.41 65 56 100 150 73 760 84 49 71 65 41 11 J 19 J 28 37 12 J 180 23 J 12 J 11 J 9.6 J 9.5 J 20 13 6.2 3.4 3.2 160 6.7 5.8 <0.44 3.1 2.4 5.3 0.82 J 1.6 <0.79 <0.79 1.5 25 0.92 J <0.79 <0.79 <0.79 <3.0 <3.0 <3.0 <3.0 <3.0 6.0 J <3.0 <3.0 <3.0 <3.0 <3.0 1.7 1.7 2.5 2.8 2.4 4.6 1.6 2.9 4.5 4.2 1.7 29 6.8 45 3.6 130 170 200 30 170 170 29 <0.97 <0.97 7.6 2.6 J <0.97 <0.97 <0.97 <0.97 <0.97 <0.97 <0.97 17 16 23 22 20 14 5.9 17 9.6 10 4.0 <1.7 <1.7 <1.7 <1.7 <1.7 <1.7 25 <1.7 <1.7 <1.7 <1.7 <0.86 <0.86 5.2 <0.86 1.6 13 6.4 1.6 <0.86 <0.86 7.2 1.1 <0.72 <0.72 <0.72 3.2 12 20 3.2 1,200 1,200 14 49 38 8.9 26 7.8 11 2.4 J 3.1 J 1.9 J 1.9 J 12 12 <0.43 <0.43 <0.43 <0.43 81 <0.43 4.5 <0.43 <0.43 <0.43 3.4 <0.52 0.90 J 0.81 J <0.52 23 0.57 J 1.6 1.1 1.0 <0.52 <0.46 <0.46 <0.46 <0.46 <0.46 <0.46 0.83 <0.46 0.85 0.91 <0.46 14 4 13 6.1 4.1 190 3.0 14 9.0 9.2 3.2 8.9 2.4 3.9 4.6 2.7 51 1.9 8.4 5.2 5.0 2.3 Notes: 1) NC Department of Environmental Quality Sub-Slab and Exterior Soil Gas Screening Levels (SGSLs) (July 2022). 2) Sample location descriptions are representative of the tenant space at the time of sampling. Only compounds with at least one detection above laboratory method detection limits limits are shown on this table. Compound concentrations are reported in micrograms per cubic meter (μg/m3). Bold and underlined concentrations and yellow highlighting indicates concentration exceeds Non-Residential SGSLs (July 2022). Laboratory analytical method is shown in parentheses. VOCs = volatile organic compounds; NE= Not Established; < = less than laboratory method detection limits; -- = Not Applicable J = compound was detected above the laboratory method detection limit but below the laboratory reporting limit resulting in an estimated concentration. USPSSnap AV SS-17 SS-18 SS-19 SS-20 SS-21 (Area of SS-3) SS-22SS-13 SS-14 SS-15 SS-16 https://harthick.sharepoint.com/sites/MasterFiles‐1/Shared Documents/AAA‐Master Projects/Somerset Properties (SSP)/Continental Tire (SSP‐001)/Brownfields Assessment/Additional VI Assessment/VI MASTER TABLE 2021‐03_Updated 08312022 9/9/2022 Table 1 (Page 3 of 3) Hart & Hickman, PC Table 2 Summary of Indoor Air Analytical Data REEP-LRC(RN) 1900 Continental Blvd. Charlotte, North Carolina H&H Job No. SSP-001 IAS-5 IAS-DUP 7/18/2022 7/18/2022 7/18/2022 7/18/2022 7/18/2022 7/18/2022 7/18/2022 7/18/2022 7/18/2022 7/18/2022 7/18/2022 Darnell Spirit Halloween VOCs (TO-15) (µg/m3)Non-Residential IASLs1 Acetone NE 13 14 32 110 42 38 37 30 23 30 120 Benzene 1.6 0.23 0.27 0.23 0.47 0.26 0.24 0.36 0.19 0.26 0.57 0.25 Bromomethane 4.4 <0.091 0.27 <0.091 <0.091 <0.091 <0.091 <0.091 <0.091 <0.091 <0.091 <0.10 Carbon Disulfide 610 0.36 J 0.23 J 0.13 J 0.31 J 0.47 J 0.50 J 0.45 J <0.10 <0.10 0.40 J 0.74 J Carbon Tetrachloride 2.0 0.31 0.34 0.34 0.30 0.36 0.37 0.35 0.36 0.37 0.35 0.38 Chloroform 0.53 0.17 <0.16 0.37 <0.16 0.18 0.19 0.19 0.53 <0.16 0.19 0.36 Chloromethane 79 1.5 1.5 1.6 2.0 1.6 1.7 1.6 1.4 1.3 1.7 1.5 Dichlorodifluoromethane (Freon 12) 88 1.1 0.96 1.2 0.96 1.0 0.99 1.1 1.1 1.1 1.1 0.99 1,1-Dichloroethane 7.7 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.12 <0.14 1,2-Dichloroethane 0.47 0.40 <0.13 <0.13 <0.13 0.31 0.33 0.30 <0.13 <0.13 <0.13 2.2 1,1-Dichloroethylene 180 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.11 <0.12 cis-1,2-Dichloroethylene NE <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.12 trans-1,2-Dichloroethylene 35 <0.11 <0.11 <0.11 <0.11 0.12 J 0.12 J <0.11 <0.11 <0.11 <0.11 <0.12 1,2-Dichloropropane 3.3 <0.088 <0.088 <0.088 0.17 0.63 0.63 0.59 <0.088 <0.088 <0.088 1.2 1,4-Dioxane 2.5 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.12 Ethanol NE 42 33 290 170 110 110 120 12 17 40 38 Ethyl Acetate 61 8.3 3.0 7.3 5.1 7.5 4.3 23 1.7 7.3 2.9 3.5 Ethylbenzene 4.9 5.7 3.1 0.39 3.9 5.0 5.0 4.5 0.48 0.25 1.1 15 4-Ethyltoluene NE 0.11 J <0.11 <0.11 0.54 0.31 0.30 0.28 <0.11 <0.11 0.17 1.7 Heptane 350 0.40 0.31 0.29 0.99 0.61 0.52 0.58 0.25 0.32 0.39 0.98 Hexane 610 1.8 J 1.6 J 1.2 J 2.0 J 1.8 J 1.6 J 1.9 J 1.1 J 2.3 J 1.1 J 2.3 J 2-Hexanone (Methyl butyl ketone) 26 <0.072 <0.072 <0.072 <0.072 0.81 0.82 0.75 0.64 0.56 <0.072 1.5 Isopropanol 180 5.1 3.1 J 30 9.7 48 47 52 2.6 J 3.6 3.2 J 6.3 Methyl ethyl ketone (2-Butanone) 4400 15 9.0 2.4 J 7.7 8.5 8.6 8.2 11 6.2 4.3 7.3 4-Methyl-2-pentanone (MIBK) 2600 0.49 0.31 0.19 0.87 0.84 0.81 0.79 0.40 0.27 13 1.3 Methylene Chloride 530 0.73 J <0.57 <0.57 0.59 J 7.0 7.0 5.9 <0.57 <0.57 <0.57 0.94 J Naphthalene 0.36 0.29 0.26 0.26 0.37 0.62 0.66 0.68 0.26 0.25 0.55 1.4 Styrene 880 10 5.2 0.33 1.4 7.5 7.8 6.9 5.6 6.0 30 9.5 Tetrachloroethylene 35 <0.18 <0.18 <0.18 <0.18 0.30 0.30 0.28 2.0 <0.18 <0.18 0.39 Tetrahydrofuran 1800 <0.17 <0.17 0.34 J <0.17 0.19 J 0.18 J <0.17 0.41 J <0.17 <0.17 0.25 J Toluene 4400 27 15 7.3 8.4 16 16 16 1.4 2.3 1.8 37 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 4400 0.51 J 0.51 J 0.51 J 0.56 J 0.53 J 0.77 0.56 J 0.52 J 0.51 J 0.52 J 0.52 J 1,1,1-Trichloroethane 4400 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.17 1,1,2-Trichloroethane 0.18 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.31 Trichloroethylene 1.8 0.14 J <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.22 Trichlorofluoromethane (Freon 11) NE 9.5 5.9 1.6 2.7 16 16 15 1.4 2.3 120 28 1,2,4-Trimethylbenzene 53 0.28 0.19 0.26 1.5 0.97 0.98 0.90 0.36 0.31 0.36 5.0 1,3,5-Trimethylbenzene 53 0.10 J <0.091 <0.091 0.42 0.29 0.29 0.28 0.093 J <0.091 0.11 J 1.7 Vinyl chloride 2.8 <0.081 <0.081 <0.081 <0.081 <0.081 <0.081 <0.081 <0.081 <0.081 <0.081 <0.092 m-/p-Xylenes 88 17 9.3 1.4 16 15 15 13 1.6 0.72 3.2 48 o-Xylene 88 6.9 3.9 0.51 5.3 6.6 6.6 6.1 0.55 0.34 0.71 33 Risk Evaluation (Indoor Air)(2)Acceptable Risk Levels Non-Residential Carcinogenic Risk <1.0 x 10-4 3.5E-06 1.7E-06 1.8E-06 2.3E-06 4.4E-06 2.2E-06 1.1E-06 2.6E-06 1.3E-05 Non-Residential Hazard Index <1.0 0.16 0.089 0.095 0.14 0.30 0.063 0.066 0.087 0.89 Notes: Bold and underlined concentrations and yellow highlighting indicates concentration exceeds Non-Residential SGSLs (July 2022). J = compound was detected above the laboratory method detection limit but below the laboratory reporting limit resulting in an estimated concentration. IAS-5 Compound concentrations are reported in micrograms per cubic meter (μg/m3). Laboratory analytical method is shown in parentheses. VOCs = volatile organic compounds; NE= Not Established; < = less than laboratory method detection limits 1) NC Department of Environmental Quality Indoor Air Screening Levels(IASLs) (July 2022). 2) Risk evaluation performed using the July 2022 DEQ Risk Calculator for the Indoor Air Sampling. Only compounds with at least one detection above laboratory method detection limits limits are shown on this table. IAS-8IAS-2 IAS-3 IAS-4 Co-Located with SS-13 IAS-10 Sample Location (Unit) Sample ID IAS-6 IAS-7IAS-1 Sample Date IAS-9 Snap AV Siemens/Deufol USPS Builders Supply 4.5E-06 0.26 Sample Location Relative to Sub-Slab Vapor Co-Located with SS-21 Co-Located with SS-21 Co-Located with SS-20 Co-Located with SS-19 Co-Located with SS-18 Co-Located with SS-17 Co-Located with SS-14 Co-Located with SS-16 Co-Located with SS-15 Co-Located with SS-22 https://harthick.sharepoint.com/sites/MasterFiles‐1/Shared Documents/AAA‐Master Projects/Somerset Properties (SSP)/Continental Tire (SSP‐001)/Brownfields Assessment/Additional VI Assessment/VI MASTER TABLE 2021‐03_Updated 08312022 9/9/2022 Table 2 (Page 1 of 1) Hart & Hickman, PC USGS The National Map: National Boundaries Dataset, 3DEP ElevationProgram, Geographic Names Information System, National HydrographyDataset, National Land Cover Database, National Structures Dataset, andNational Transportation Dataset; USGS Global Ecosystems; U.S. Census Bureau TIGER/Line data; USFS Road Data; Natural Earth Data; U.S.Department of State Humanitarian Information Unit; and NOAA NationalCenters for Environmental Information, U.S. Coastal Relief Model. Datarefreshed June, 2022. SITE LOCATION MAP REEP-LRC (RN)1900 CONTINENTAL BOULEVARDCHARLOTTE, NORTH CAROLINA DATE: 9-9-22 JOB NO: SSP-001 REVISION NO: 0 FIGURE NO: 1 TITLE PROJECT 0 2,000 4,000 SCALE IN FEET SITE Path: C:\Users\sperry\OneDrive - Hart & Hickman\My Documents\ArcGIS\PROJECTS\SSP-001\Figure 1 - Site Location Map.mxd N U.S.G.S. QUADRANGLE MAP CHARLOTTE WEST, NORTH CAROLINA 2019 QUADRANGLE7.5 MINUTE SERIES (TOPOGRAPHIC) SITE 2923 South Tryon Street - Suite 100Charlotte, North Carolina 28203704-586-0007 (p) 704-586-0373 (f)License # C-1269 / # C-245 Geology REVISION NO. 0 JOB NO. SSP-001 DATE: 9-12-22 FIGURE NO. 2 REEP-LRC (RN) 1900 CONTINENTAL BOULEVARD CHARLOTTE, NORTH CAROLINA SITE MAP NOTES: 1.AERIAL IMAGERY OBTAINED FROM MECKLENBURG COUNTY GIS (2020). 2.NFA = NO FURTHER ACTION 3.PIN = MECKLENBURG COUNTY PARCEL IDENTIFICATION NUMBER 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology OFFICE OFFICES FORMER NAPHTHA UST NFA - NORP (SOIL & GROUNDWATER 2003) FORMER RAIL OFF-LOADING- CHLORINATED VOCs IN GROUNDWATER; IMPACTED SOIL MOSTLY REMOVED (CONDITIONAL NFA 1/27/20) FORMER BUFFING DUST SHED- CHLORINATED VOCs IN SOIL & GROUNDWATER FORMER BOILER DAY TANKS (NFA 6/24/10) FORMER WASH RACKS (NFA 6/24/10) DUKE ENERGY PROPERTY II N T E R S T A T E - 4 8 5 CO N T I N E N T A L B O U L E V A R D PIONEER AVENUE PIN 20308306 (1942 CONTINENTAL BOULEVARD) PIN 20308301 (1900 CONTINENTAL BOULEVARD) PIN 20308305 (NO ESTABLISHED ADDRESS) PIN 20302139 (NO ESTABLISHED ADDRESS) FORMER ROAD LOCATION OF BERMED AREA FOUND DURING 2018 SITE RECON SU G A R C R E E K CO F F E Y C R E E K SUITE C - HARRIS TIRE SUITE D - DARNELL SUITE E - SYNDERS LANCE SUITE F - SYNDERS LANCE SUITE G - SPIRIT SUITE H - SPIRIT SUITE A - SPIRIT SUITE B - PROF. BUILDERS SUPPLY NEW OFFICE SPACE NEW WAREHOUSE ADDITION SUITE I - USPS SUITE K - SNAP AV SUITE J - SIEMENS/ DUEFOL LEGEND REEP-LRC (RN) BROWNFIELDS PROPERTY BOUNDARY REEP-LRC BROWNFIELDS PROPERTY BOUNDARY RAILROAD SPURS SURFACE WATER FEATURE APPROXIMATE LOCATION OF FORMER RELEASE/ IMPACTED AREA CIRCULATION ROAD DIRECTION OF SURFACE WATER FLOW S: \ A A A - M a s t e r P r o j e c t s \ S o m e r s e t P r o p e r t i e s ( S S P ) \ C o n t i n e n t a l T i r e ( S S P - 0 0 1 ) \ B r o w n f i e l d s A s s e s s m e n t \ A d d i t i o n a l V I A s s e s s m e n t \ F i g u r e s \ S S P . 0 0 1 _ 2 0 2 2 0 8 3 0 . d w g , F I G 2 9 - 9 - 2 2 , 9 / 1 2 / 2 0 2 2 1 1 : 2 0 : 3 0 A M , s p e r r y IAS-9/ SS-14 SS-2 SS-3 SS-4 SS-5SS-6 SS-7 SS-8 SS-9 SS-12 SS-11 SS-10 SS-1 IAS-8/ SS-16 IAS-7/ SS-15 IAS-10/ SS-13 IAS-6/ SS-22 IAS-2/ SS-18 IAS-1/ SS-17 IAS-4/ SS-20 IAS-3/ SS-19 IAS-5/IAS-DUP SS-21/SS-DUP REVISION NO. 0 LEGEND REEP-LRC (RN) BROWNFIELDS PROPERTY BOUNDARY REEP-LRC BROWNFIELDS PROPERTY BOUNDARY RAILROAD SPURS SURFACE WATER FEATURE APPROXIMATE LOCATION OF FORMER RELEASE/ IMPACTED AREA CIRCULATION ROAD SUB-SLAB VAPOR SAMPLE LOCATION (H&H, 2019 & 2021) CO-LOCATED SUB-SLAB VAPOR AND INDOOR AIR SAMPLE LOCATION (H&H, 2022) DIRECTION OF SURFACE WATER FLOW JOB NO. SSP-001 DATE: 9-12-22 FIGURE NO. 3 REEP-LRC (RN) 1900 CONTINENTAL BOULEVARD CHARLOTTE, NORTH CAROLINA SAMPLE LOCATION MAP NOTES: 1.AERIAL IMAGERY OBTAINED FROM MECKLENBURG COUNTY GIS (2020). 2.NFA = NO FURTHER ACTION 3.PIN = MECKLENBURG COUNTY PARCEL IDENTIFICATION NUMBER PIONEER AVENUE CO N T I N E N T A L B O U L E V A R D II N T E R S T A T E - 4 8 5 DUKE ENERGY PROPERTY FORMER BUFFING DUST SHED- CHLORINATED VOCs IN SOIL & GROUNDWATER SUITE C - HARRIS TIRE 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology PIN 20308306 (1942 CONTINENTAL BOULEVARD) PIN 20308305 (NO ESTABLISHED ADDRESS) PIN 20302139 (NO ESTABLISHED ADDRESS) FORMER ROAD LOCATION OF BERMED AREA FOUND DURING 2018 SITE RECON SU G A R C R E E K CO F F E Y C R E E K SUITE D - DARNELL SUITE E - SYNDERS LANCE SUITE F - SYNDERS LANCE SUITE G - SPIRIT SUITE H - SPIRIT SUITE A - SPIRIT SUITE B - PROF. BUILDERS SUPPLY NEW OFFICE SPACE NEW WAREHOUSE ADDITION SUITE I - USPS SUITE K - SNAP AV SUITE J - SIEMENS/ DUEFOL PIN 20308301 (1900 CONTINENTAL BOULEVARD) S: \ A A A - M a s t e r P r o j e c t s \ S o m e r s e t P r o p e r t i e s ( S S P ) \ C o n t i n e n t a l T i r e ( S S P - 0 0 1 ) \ B r o w n f i e l d s A s s e s s m e n t \ A d d i t i o n a l V I A s s e s s m e n t \ F i g u r e s \ S S P . 0 0 1 _ 2 0 2 2 0 8 3 0 . d w g , F I G 3 , 9 / 1 2 / 2 0 2 2 1 1 : 2 5 : 0 3 A M , s p e r r y Appendix A Sub-Slab Vapor and Indoor Air Sampling Forms Form ST·l Summa Canister Shut-in Test Field Form Project No.:_ 5 J f. 00 Sampler: __»q vl .,//<:;/.., Summa Pressure Check Shut-in Test Shut-in Retest (ii needed) Date Initial Pass? Canister Regulator Canister Sample ID Pressure ( >-25.0 " Hg) Time Pass? "Zero" Time Pressure Pass? Notes Test Peiod Pressure Pressure mm/dd/yy .. Hg Yes/No 24-hr "Hg Yes/No .. Hg 24-hr .. Hg Yes/No C 2,77] Start 2.0:'-l 3 ~21 /L 5V,1J fYl-'i I R 'i;l.3~ -rjtr/22... -J.i Yt;; Middle 2.:o:4 f' -2),,,-'(r, 0 End .;io:5"3 -2.J..r C: (9.7 '( 3 Start 2.,: '-I? ,.,.i_.lc, RL/ir, .--2,_Y 1<5 Middle 2t1:'1.Y ·l.S.> 'l"t5 End Jo:·o -is.< 0 C J3:J I" Start ~:--1> -21,, R 1--/J.8"( -oZ.f Yt.5 Middle ~o:'-{~ -2J. End o?->:O -2.-1,. tt5 D C: c,?rt-\6 Start1., .----. '-----~1 /Jo Middle__. -----R 41b7 - End cJ\\8 Start 2,o:'io --J..~ -i, Yt5 Middle 'lo: 't ~,.... -}.."1,J R: 'iJLtS' End )..-.:,~SI> -1--7.J,,-- C J IJ.l Start ~o:37 -2,.""l -3o Yt5 Middle -i.o:12--Z-7 J RY/Y2.. End 2-.,; i.., -2,i \ C = canister ID: R = regulator ID; " Hg = inches of mercury Last updated. 6/18/2020 Notes: Shut·ln Test should be performed with matching canister with regulator as listed by laboratory on canister tag, and should last for a duration of at least 5 minutes. hart hickman SMARTER ENVIRONMENTAL SOWTIONS L , _____ .. _______ , .. , Regulator "Zero" Pressure= pressure of regulator detached from Summa (if not O" Hg, then this needs to be accounted for during sampling). Summa Initial Pressure= pressure of Summa immedietely after closing valve (pressure likely to decrease slighlty once valve is closed). Sub-Slab/ Soil Gas Sampling Shut-in Test Field Form Hart & Hickman, PC I FormST-1 Summa Canister Shut-in Test Field Form Project No.: S,F/J, de ( Sampl~n-!dive(/4L Summa Pressure Check ShuUn Test Shut-in Retest (if needed) Date Initial Pass? Canister Regulator Canister Sample ID Pressure ( >-25.0 " Hg) Time Pass? "Zero" Time Pressure Pass? Notes Pressure Test Peiod Pressure mm/ddlyy .. Hg Yes/No 24-hr "Hg Yes/No "Hg 24-hr .. Hg Yes/No C 2,\ 2._~ 1 /w)iz. Start Jo:31' -~ .. -,.r R l-1 I S-b -~g-.( Y<5 Middle 2-..~'{ 2.. -1.--r '(,q -0 End z..c:1-\1 -Z.1 C 2(,.>'7 -J~ Start Jo::J~ -Zt:f RL/J.bl -t'Jff ieS Middle ~: I\<: r 2, "/ 'it5 D End Z.:i·. -(} -u, C Jhi.t( Start ~o~Jr -~7 -). y '1t5 Middle 2-,: 'fo -2-7 '(l's R "Ill I '2.0 ~'1S,--0 End -i, C ~~1..\1 Start i(o:'>.f" ---2, R LJ~37 -J&' (tS Middle 2,.c,: 'f 0 -'},b.> Yes 0 End 2.0:"(J' -u-s--- c-cQf d~ Start 20:3'( -~Y-.r -ars Yis Middle 20: 31 -7 ~ '(-t,) R 113«) End 2-0:'f "I. -2i' 0 - I/ Start C: -~' Middle R: End C ::; canister ID: R == regulator JO; " Hg = inches of mercury Last updated: 6/1812020 Notes: Shut-In Test should be performed with matching canister with regulator as listed by laboratory on canister tag, and should last for a duration of at least 5 minutes. hart hickman SMARfER ENVIRONMENTAL SOLlJTIONS t \u,....,...,,..""•\D<""loe•\vou,.,\fo,m (d t<V-"0-~WW•w S.m91tlf I01T11,_Vi.O Regulator "Zero" Pressure= pressure of regulator detached from Summa (if not O" Hg, then this needs to be accounted for during sampling). Summa Initial Pressure = pressure of Summa lmmedietely after closing valve (pressure likely to decrease slighlty once valve is closed). Sub-Slab/ Soil Gas Sampling Shut-in Test Field Form Hart & Hickmon, PC David Kahn/ Matt Yankech SS-13 2118 SS Temp.Conc.Full 82 Syringe 0.4 Yes 4345 SS-14 2124 4156 SS-15 2127 SS-16 2641 4111 SS-17 4261 SS-18 2524 4321 David Kahn / Matt Yankech SS-19 2773 SS Temp Conc Full 82 Syringe 0.4 Yes 4232 SS-20 2247 4337 SS-21 2338 SS-DUP 2783 4281 SS-22 4541 SSP.001 Partly Cloudy 76OF-90OF 1L 10 100 ml/min 13:25 13:28 13:20 13:58 10 14:03 14:07 10 14:52 15:071L 10 15:17 10:331L10 1L 10:58 10 11:07 SSP.001 David Kahn / Matt Yankech Sunny 76OF-90OF 1L 10 100 ml/min 11:35 11:40 11:30 11:52 10 11:57 12:02 10 15:55 15:451L 10 15:55 15:391L10 Sunny 74OF - 89OF IAS-1 6L1137 13:50 -14 84 .0094 l/min 16:32 -6 84 IAS-2 08:33 -29 746L IAS-3 1863 14:03 -13 72 IAS-4 2144 IAS-5 2213 IAS-DUP 2015 09:00 13:00 30.05 29.99 NE NE 3 7 Sunny 74OF -89OF IAS-6 6L2216 7/18/2022 14:07 -14 82 .0094 l/min 17:16 -5 82 IAS-7 09:52 -30 776L IAS-8 1963 14:19 -17 84 IAS-9 1997 7/18/2022 IAS-10 2157 09:00 13:00 30.05 29.99 NE NE 3 7 Appendix B Laboratory Analytical Reports 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 August 3, 2022 Justin Ballard Hart & Hickman - Charlotte, NC 2923 South Tryon Street, Suite 100 Charlotte, NC 28203 Project Location: 1900 Continental Blvd, Charlotte, NC Client Job Number: Project Number: SSP-001 Laboratory Work Order Number: 22G1207 Enclosed are results of analyses for samples as received by the laboratory on July 22, 2022. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kerry K. McGee Project Manager QA Officer Katherine Allen Laboratory Manager Daren Damboragian Page 1 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL SUMMARY The results of analyses performed on the following samples submitted to Con-Test, a Pace Analytical Laboratory, are found in this report. PROJECT LOCATION: PURCHASE ORDER NUMBER: PROJECT NUMBER: REPORT DATE: WORK ORDER NUMBER: FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB Page 2 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CASE NARRATIVE SUMMARY All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report. EPA TO-15 Qualifications: Laboratory fortified blank/laboratory control sample recovery outside of control limits. Data validation is not affected since all results are "not detected" for all samples in this batch for this compound and bias is on the high side. Analyte & Samples(s) Qualified: L-01 Benzyl chloride B314267-BS1 Laboratory fortified blank/laboratory control sample recovery is outside of control limits. Reported value for this compound is likely to be biased on the low side. Analyte & Samples(s) Qualified: L-03 Vinyl Acetate 22G1207-01[SS-13], 22G1207-02[SS-14], 22G1207-03[SS-15], 22G1207-04[SS-16], 22G1207-05[SS-17], 22G1207-06[SS-18], 22G1207-07[SS-19], 22G1207-08[SS-20], 22G1207-09[SS-21], 22G1207-10[SS-Dup], B314267-BLK1, B314267-BS1 Continuing calibration verification (CCV) did not meet method specifications and was biased on the low side for this compound. Analyte & Samples(s) Qualified: V-05 Vinyl Acetate 22G1207-01[SS-13], 22G1207-02[SS-14], 22G1207-03[SS-15], 22G1207-04[SS-16], 22G1207-05[SS-17], 22G1207-06[SS-18], 22G1207-07[SS-19], 22G1207-08[SS-20], 22G1207-09[SS-21], 22G1207-10[SS-Dup], B314267-BLK1, B314267-BS1, S074611-CCV1 Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side. Data validation is not affected since sample result was "not detected" for this compound. Analyte & Samples(s) Qualified: V-20 Benzyl chloride B314267-BS1, S074611-CCV1 Initial calibration verification (ICV) did not meet method specifications and was biased on the high side. Data validation is not affected since sample result was "not detected" for this compound. Analyte & Samples(s) Qualified: V-36 1,2,4-Trichlorobenzene, Benzyl chloride B314267-BS1, S074611-CCV1 Page 3 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 The results of analyses reported only relate to samples submitted to Con-Test, a Pace Analytical Laboratory, for testing. I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. Lisa A. Worthington Technical Representative Page 4 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1207Sample Description/Location: Field Sample #: SS-13 Sample ID: 22G1207-01 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -27 Final Vacuum(in Hg): -4 Receipt Vacuum(in Hg): -6.1 Sampled: 7/19/2022 13:28 Canister ID: 2118 Flow Controller ID: 4345 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 190 40 8/1/22 13:26 BRF450 20952457 Benzene 0.23 0.20 7/29/22 22:26 BRF0.74 40.640.15 0.48 Benzyl chloride ND 0.40 7/29/22 22:26 BRFND42.10.18 0.91 Bromodichloromethane ND 0.20 7/29/22 22:26 BRFND41.30.14 0.94 Bromoform ND 0.20 7/29/22 22:26 BRFND42.10.14 1.4 Bromomethane ND 0.20 7/29/22 22:26 BRFND40.780.13 0.52 1,3-Butadiene ND 0.20 7/29/22 22:26 BRFND40.440.17 0.37 2-Butanone (MEK)3.8 8.0 7/29/22 22:26 BRFJ11 4242.1 6.3 Carbon Disulfide 0.80 2.0 7/29/22 22:26 BRFJ2.5 46.20.18 0.58 Carbon Tetrachloride ND 0.20 7/29/22 22:26 BRFND41.30.16 1.0 Chlorobenzene ND 0.20 7/29/22 22:26 BRFND40.920.13 0.61 Chloroethane ND 0.20 7/29/22 22:26 BRFND40.530.18 0.47 Chloroform ND 0.20 7/29/22 22:26 BRFND40.980.19 0.93 Chloromethane 0.55 0.40 7/29/22 22:26 BRF1.1 40.830.16 0.33 Cyclohexane 1.3 0.20 7/29/22 22:26 BRF4.5 40.690.12 0.42 Dibromochloromethane ND 0.20 7/29/22 22:26 BRFND41.70.13 1.1 1,2-Dibromoethane (EDB)ND 0.20 7/29/22 22:26 BRFND41.50.12 0.93 1,2-Dichlorobenzene ND 0.20 7/29/22 22:26 BRFND41.20.11 0.69 1,3-Dichlorobenzene 12 0.20 7/29/22 22:26 BRF71 41.20.11 0.67 1,4-Dichlorobenzene ND 0.20 7/29/22 22:26 BRFND41.20.13 0.79 Dichlorodifluoromethane (Freon 12)0.53 0.20 7/29/22 22:26 BRF2.6 40.990.20 0.97 1,1-Dichloroethane ND 0.20 7/29/22 22:26 BRFND40.810.17 0.71 1,2-Dichloroethane ND 0.20 7/29/22 22:26 BRFND40.810.18 0.73 1,1-Dichloroethylene ND 0.20 7/29/22 22:26 BRFND40.790.15 0.60 cis-1,2-Dichloroethylene ND 0.20 7/29/22 22:26 BRFND40.790.15 0.58 trans-1,2-Dichloroethylene ND 0.20 7/29/22 22:26 BRFND40.790.16 0.62 1,2-Dichloropropane ND 0.20 7/29/22 22:26 BRFND40.920.11 0.50 cis-1,3-Dichloropropene ND 0.20 7/29/22 22:26 BRFND40.910.10 0.47 trans-1,3-Dichloropropene ND 0.20 7/29/22 22:26 BRFND40.910.10 0.46 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 7/29/22 22:26 BRFND41.40.20 1.4 1,4-Dioxane ND 2.0 7/29/22 22:26 BRFND47.20.17 0.60 Ethanol 240 40 8/1/22 13:26 BRF460 20751833 Ethyl Acetate 2.8 2.0 7/29/22 22:26 BRF10 47.21.0 3.6 Ethylbenzene 0.71 0.20 7/29/22 22:26 BRF3.1 40.870.12 0.51 4-Ethyltoluene 0.34 0.20 7/29/22 22:26 BRF1.7 40.980.12 0.60 Heptane 0.42 0.20 7/29/22 22:26 BRF1.7 40.820.13 0.52 Hexachlorobutadiene ND 0.20 7/29/22 22:26 BRFND42.10.16 1.8 Hexane 2.9 8.0 7/29/22 22:26 BRFJ10 4281.0 3.7 2-Hexanone (MBK)ND 0.20 7/29/22 22:26 BRFND40.820.10 0.41 Isopropanol 26 8.0 7/29/22 22:26 BRF65 4201.4 3.4 Methyl tert-Butyl Ether (MTBE)ND 0.20 7/29/22 22:26 BRFND40.720.15 0.56 Methylene Chloride ND 2.0 7/29/22 22:26 BRFND46.90.93 3.2 4-Methyl-2-pentanone (MIBK)4.8 0.20 7/29/22 22:26 BRF20 40.820.11 0.44 Naphthalene 1.0 0.20 7/29/22 22:26 BRF5.3 41.00.15 0.79 Propene ND 8.0 7/29/22 22:26 BRFND4141.8 3.0 Styrene 0.40 0.20 7/29/22 22:26 BRF1.7 40.850.11 0.45 1,1,2,2-Tetrachloroethane ND 0.20 7/29/22 22:26 BRFND41.40.11 0.74 Page 5 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1207Sample Description/Location: Field Sample #: SS-13 Sample ID: 22G1207-01 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -27 Final Vacuum(in Hg): -4 Receipt Vacuum(in Hg): -6.1 Sampled: 7/19/2022 13:28 Canister ID: 2118 Flow Controller ID: 4345 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 4.3 0.20 7/29/22 22:26 BRF29 41.40.15 1.0 Tetrahydrofuran ND 2.0 7/29/22 22:26 BRFND45.90.33 0.97 Toluene 4.6 0.20 7/29/22 22:26 BRF17 40.750.11 0.43 1,2,4-Trichlorobenzene ND 0.20 7/29/22 22:26 BRFND41.50.19 1.4 1,1,1-Trichloroethane ND 0.20 7/29/22 22:26 BRFND41.10.16 0.86 1,1,2-Trichloroethane ND 0.20 7/29/22 22:26 BRFND41.10.14 0.77 Trichloroethylene 0.21 0.20 7/29/22 22:26 BRF1.1 41.10.13 0.72 Trichlorofluoromethane (Freon 11)8.8 0.80 7/29/22 22:26 BRF49 44.50.24 1.3 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 7/29/22 22:26 BRFND46.10.22 1.7 1,2,4-Trimethylbenzene 2.4 0.20 7/29/22 22:26 BRF12 40.980.088 0.43 1,3,5-Trimethylbenzene 0.70 0.20 7/29/22 22:26 BRF3.4 40.980.11 0.52 Vinyl Acetate ND 4.0 7/29/22 22:26 BRFV-05, L-03 ND 4141.1 3.8 Vinyl Chloride ND 0.20 7/29/22 22:26 BRFND40.510.18 0.46 m&p-Xylene 3.2 0.40 7/29/22 22:26 BRF14 41.70.22 0.97 o-Xylene 2.0 0.20 7/29/22 22:26 BRF8.9 40.870.10 0.44 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)77.7 8/1/22 13:2670-130 4-Bromofluorobenzene (1)96.9 7/29/22 22:2670-130 Page 6 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1207Sample Description/Location: Field Sample #: SS-14 Sample ID: 22G1207-02 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -27 Final Vacuum(in Hg): -4 Receipt Vacuum(in Hg): -5.9 Sampled: 7/19/2022 14:07 Canister ID: 2124 Flow Controller ID: 4156 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 79 8.0 7/29/22 22:54 BRF190 4194.8 11 Benzene 0.19 0.20 7/29/22 22:54 BRFJ0.61 40.640.15 0.48 Benzyl chloride ND 0.40 7/29/22 22:54 BRFND42.10.18 0.91 Bromodichloromethane ND 0.20 7/29/22 22:54 BRFND41.30.14 0.94 Bromoform ND 0.20 7/29/22 22:54 BRFND42.10.14 1.4 Bromomethane ND 0.20 7/29/22 22:54 BRFND40.780.13 0.52 1,3-Butadiene ND 0.20 7/29/22 22:54 BRFND40.440.17 0.37 2-Butanone (MEK)6.5 8.0 7/29/22 22:54 BRFJ19 4242.1 6.3 Carbon Disulfide 0.89 2.0 7/29/22 22:54 BRFJ2.8 46.20.18 0.58 Carbon Tetrachloride ND 0.20 7/29/22 22:54 BRFND41.30.16 1.0 Chlorobenzene ND 0.20 7/29/22 22:54 BRFND40.920.13 0.61 Chloroethane ND 0.20 7/29/22 22:54 BRFND40.530.18 0.47 Chloroform ND 0.20 7/29/22 22:54 BRFND40.980.19 0.93 Chloromethane 0.36 0.40 7/29/22 22:54 BRFJ0.74 40.830.16 0.33 Cyclohexane 0.89 0.20 7/29/22 22:54 BRF3.1 40.690.12 0.42 Dibromochloromethane ND 0.20 7/29/22 22:54 BRFND41.70.13 1.1 1,2-Dibromoethane (EDB)ND 0.20 7/29/22 22:54 BRFND41.50.12 0.93 1,2-Dichlorobenzene ND 0.20 7/29/22 22:54 BRFND41.20.11 0.69 1,3-Dichlorobenzene 7.6 0.20 7/29/22 22:54 BRF46 41.20.11 0.67 1,4-Dichlorobenzene ND 0.20 7/29/22 22:54 BRFND41.20.13 0.79 Dichlorodifluoromethane (Freon 12)0.52 0.20 7/29/22 22:54 BRF2.6 40.990.20 0.97 1,1-Dichloroethane ND 0.20 7/29/22 22:54 BRFND40.810.17 0.71 1,2-Dichloroethane ND 0.20 7/29/22 22:54 BRFND40.810.18 0.73 1,1-Dichloroethylene ND 0.20 7/29/22 22:54 BRFND40.790.15 0.60 cis-1,2-Dichloroethylene ND 0.20 7/29/22 22:54 BRFND40.790.15 0.58 trans-1,2-Dichloroethylene ND 0.20 7/29/22 22:54 BRFND40.790.16 0.62 1,2-Dichloropropane ND 0.20 7/29/22 22:54 BRFND40.920.11 0.50 cis-1,3-Dichloropropene ND 0.20 7/29/22 22:54 BRFND40.910.10 0.47 trans-1,3-Dichloropropene ND 0.20 7/29/22 22:54 BRFND40.910.10 0.46 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 7/29/22 22:54 BRFND41.40.20 1.4 1,4-Dioxane ND 2.0 7/29/22 22:54 BRFND47.20.17 0.60 Ethanol 360 40 8/1/22 13:51 BRF680 20751833 Ethyl Acetate ND 2.0 7/29/22 22:54 BRFND47.21.0 3.6 Ethylbenzene 0.27 0.20 7/29/22 22:54 BRF1.2 40.870.12 0.51 4-Ethyltoluene ND 0.20 7/29/22 22:54 BRFND40.980.12 0.60 Heptane 0.32 0.20 7/29/22 22:54 BRF1.3 40.820.13 0.52 Hexachlorobutadiene ND 0.20 7/29/22 22:54 BRFND42.10.16 1.8 Hexane 2.1 8.0 7/29/22 22:54 BRFJ7.5 4281.0 3.7 2-Hexanone (MBK)ND 0.20 7/29/22 22:54 BRFND40.820.10 0.41 Isopropanol 23 8.0 7/29/22 22:54 BRF56 4201.4 3.4 Methyl tert-Butyl Ether (MTBE)ND 0.20 7/29/22 22:54 BRFND40.720.15 0.56 Methylene Chloride ND 2.0 7/29/22 22:54 BRFND46.90.93 3.2 4-Methyl-2-pentanone (MIBK)3.1 0.20 7/29/22 22:54 BRF13 40.820.11 0.44 Naphthalene 0.16 0.20 7/29/22 22:54 BRFJ0.82 41.00.15 0.79 Propene ND 8.0 7/29/22 22:54 BRFND4141.8 3.0 Styrene 0.39 0.20 7/29/22 22:54 BRF1.7 40.850.11 0.45 1,1,2,2-Tetrachloroethane ND 0.20 7/29/22 22:54 BRFND41.40.11 0.74 Page 7 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1207Sample Description/Location: Field Sample #: SS-14 Sample ID: 22G1207-02 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -27 Final Vacuum(in Hg): -4 Receipt Vacuum(in Hg): -5.9 Sampled: 7/19/2022 14:07 Canister ID: 2124 Flow Controller ID: 4156 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 1.0 0.20 7/29/22 22:54 BRF6.8 41.40.15 1.0 Tetrahydrofuran ND 2.0 7/29/22 22:54 BRFND45.90.33 0.97 Toluene 4.2 0.20 7/29/22 22:54 BRF16 40.750.11 0.43 1,2,4-Trichlorobenzene ND 0.20 7/29/22 22:54 BRFND41.50.19 1.4 1,1,1-Trichloroethane ND 0.20 7/29/22 22:54 BRFND41.10.16 0.86 1,1,2-Trichloroethane ND 0.20 7/29/22 22:54 BRFND41.10.14 0.77 Trichloroethylene ND 0.20 7/29/22 22:54 BRFND41.10.13 0.72 Trichlorofluoromethane (Freon 11)6.8 0.80 7/29/22 22:54 BRF38 44.50.24 1.3 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 7/29/22 22:54 BRFND46.10.22 1.7 1,2,4-Trimethylbenzene ND 0.20 7/29/22 22:54 BRFND40.980.088 0.43 1,3,5-Trimethylbenzene ND 0.20 7/29/22 22:54 BRFND40.980.11 0.52 Vinyl Acetate ND 4.0 7/29/22 22:54 BRFL-03, V-05 ND 4141.1 3.8 Vinyl Chloride ND 0.20 7/29/22 22:54 BRFND40.510.18 0.46 m&p-Xylene 0.92 0.40 7/29/22 22:54 BRF4.0 41.70.22 0.97 o-Xylene 0.54 0.20 7/29/22 22:54 BRF2.4 40.870.10 0.44 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)86.1 8/1/22 13:5170-130 4-Bromofluorobenzene (1)96.0 7/29/22 22:5470-130 Page 8 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1207Sample Description/Location: Field Sample #: SS-15 Sample ID: 22G1207-03 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -4.5 Receipt Vacuum(in Hg): -4.9 Sampled: 7/19/2022 14:52 Canister ID: 2127 Flow Controller ID: 4142 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 58 8.0 7/29/22 23:23 BRF140 4194.8 11 Benzene 0.24 0.20 7/29/22 23:23 BRF0.75 40.640.15 0.48 Benzyl chloride ND 0.40 7/29/22 23:23 BRFND42.10.18 0.91 Bromodichloromethane ND 0.20 7/29/22 23:23 BRFND41.30.14 0.94 Bromoform ND 0.20 7/29/22 23:23 BRFND42.10.14 1.4 Bromomethane ND 0.20 7/29/22 23:23 BRFND40.780.13 0.52 1,3-Butadiene ND 0.20 7/29/22 23:23 BRFND40.440.17 0.37 2-Butanone (MEK)9.6 8.0 7/29/22 23:23 BRF28 4242.1 6.3 Carbon Disulfide 0.38 2.0 7/29/22 23:23 BRFJ1.2 46.20.18 0.58 Carbon Tetrachloride ND 0.20 7/29/22 23:23 BRFND41.30.16 1.0 Chlorobenzene ND 0.20 7/29/22 23:23 BRFND40.920.13 0.61 Chloroethane ND 0.20 7/29/22 23:23 BRFND40.530.18 0.47 Chloroform ND 0.20 7/29/22 23:23 BRFND40.980.19 0.93 Chloromethane 0.30 0.40 7/29/22 23:23 BRFJ0.61 40.830.16 0.33 Cyclohexane 1.7 0.20 7/29/22 23:23 BRF5.7 40.690.12 0.42 Dibromochloromethane ND 0.20 7/29/22 23:23 BRFND41.70.13 1.1 1,2-Dibromoethane (EDB)ND 0.20 7/29/22 23:23 BRFND41.50.12 0.93 1,2-Dichlorobenzene ND 0.20 7/29/22 23:23 BRFND41.20.11 0.69 1,3-Dichlorobenzene 14 0.20 7/29/22 23:23 BRF84 41.20.11 0.67 1,4-Dichlorobenzene ND 0.20 7/29/22 23:23 BRFND41.20.13 0.79 Dichlorodifluoromethane (Freon 12)0.41 0.20 7/29/22 23:23 BRF2.0 40.990.20 0.97 1,1-Dichloroethane ND 0.20 7/29/22 23:23 BRFND40.810.17 0.71 1,2-Dichloroethane ND 0.20 7/29/22 23:23 BRFND40.810.18 0.73 1,1-Dichloroethylene ND 0.20 7/29/22 23:23 BRFND40.790.15 0.60 cis-1,2-Dichloroethylene ND 0.20 7/29/22 23:23 BRFND40.790.15 0.58 trans-1,2-Dichloroethylene ND 0.20 7/29/22 23:23 BRFND40.790.16 0.62 1,2-Dichloropropane ND 0.20 7/29/22 23:23 BRFND40.920.11 0.50 cis-1,3-Dichloropropene ND 0.20 7/29/22 23:23 BRFND40.910.10 0.47 trans-1,3-Dichloropropene ND 0.20 7/29/22 23:23 BRFND40.910.10 0.46 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 7/29/22 23:23 BRFND41.40.20 1.4 1,4-Dioxane 35 2.0 7/29/22 23:23 BRF130 47.20.17 0.60 Ethanol 330 40 8/1/22 14:16 BRF630 20751833 Ethyl Acetate 1.5 2.0 7/29/22 23:23 BRFJ5.3 47.21.0 3.6 Ethylbenzene 0.38 0.20 7/29/22 23:23 BRF1.6 40.870.12 0.51 4-Ethyltoluene 0.16 0.20 7/29/22 23:23 BRFJ0.77 40.980.12 0.60 Heptane 0.57 0.20 7/29/22 23:23 BRF2.3 40.820.13 0.52 Hexachlorobutadiene ND 0.20 7/29/22 23:23 BRFND42.10.16 1.8 Hexane 2.6 8.0 7/29/22 23:23 BRFJ9.3 4281.0 3.7 2-Hexanone (MBK)ND 0.20 7/29/22 23:23 BRFND40.820.10 0.41 Isopropanol 41 8.0 7/29/22 23:23 BRF100 4201.4 3.4 Methyl tert-Butyl Ether (MTBE)ND 0.20 7/29/22 23:23 BRFND40.720.15 0.56 Methylene Chloride ND 2.0 7/29/22 23:23 BRFND46.90.93 3.2 4-Methyl-2-pentanone (MIBK)1.5 0.20 7/29/22 23:23 BRF6.2 40.820.11 0.44 Naphthalene 0.31 0.20 7/29/22 23:23 BRF1.6 41.00.15 0.79 Propene ND 8.0 7/29/22 23:23 BRFND4141.8 3.0 Styrene 0.58 0.20 7/29/22 23:23 BRF2.5 40.850.11 0.45 1,1,2,2-Tetrachloroethane ND 0.20 7/29/22 23:23 BRFND41.40.11 0.74 Page 9 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1207Sample Description/Location: Field Sample #: SS-15 Sample ID: 22G1207-03 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -4.5 Receipt Vacuum(in Hg): -4.9 Sampled: 7/19/2022 14:52 Canister ID: 2127 Flow Controller ID: 4142 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 6.7 0.20 7/29/22 23:23 BRF45 41.40.15 1.0 Tetrahydrofuran 2.6 2.0 7/29/22 23:23 BRF7.6 45.90.33 0.97 Toluene 6.1 0.20 7/29/22 23:23 BRF23 40.750.11 0.43 1,2,4-Trichlorobenzene ND 0.20 7/29/22 23:23 BRFND41.50.19 1.4 1,1,1-Trichloroethane 0.95 0.20 7/29/22 23:23 BRF5.2 41.10.16 0.86 1,1,2-Trichloroethane ND 0.20 7/29/22 23:23 BRFND41.10.14 0.77 Trichloroethylene ND 0.20 7/29/22 23:23 BRFND41.10.13 0.72 Trichlorofluoromethane (Freon 11)1.6 0.80 7/29/22 23:23 BRF8.9 44.50.24 1.3 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 7/29/22 23:23 BRFND46.10.22 1.7 1,2,4-Trimethylbenzene ND 0.20 7/29/22 23:23 BRFND40.980.088 0.43 1,3,5-Trimethylbenzene 0.18 0.20 7/29/22 23:23 BRFJ0.90 40.980.11 0.52 Vinyl Acetate ND 4.0 7/29/22 23:23 BRFL-03, V-05 ND 4141.1 3.8 Vinyl Chloride ND 0.20 7/29/22 23:23 BRFND40.510.18 0.46 m&p-Xylene 3.0 0.40 7/29/22 23:23 BRF13 41.70.22 0.97 o-Xylene 0.90 0.20 7/29/22 23:23 BRF3.9 40.870.10 0.44 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)84.4 8/1/22 14:1670-130 4-Bromofluorobenzene (1)96.4 7/29/22 23:2370-130 Page 10 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1207Sample Description/Location: Field Sample #: SS-16 Sample ID: 22G1207-04 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -6.4 Sampled: 7/19/2022 15:17 Canister ID: 2641 Flow Controller ID: 411 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 55 8.0 7/29/22 23:51 BRF130 4194.8 11 Benzene 0.22 0.20 7/29/22 23:51 BRF0.72 40.640.15 0.48 Benzyl chloride ND 0.40 7/29/22 23:51 BRFND42.10.18 0.91 Bromodichloromethane ND 0.20 7/29/22 23:51 BRFND41.30.14 0.94 Bromoform ND 0.20 7/29/22 23:51 BRFND42.10.14 1.4 Bromomethane ND 0.20 7/29/22 23:51 BRFND40.780.13 0.52 1,3-Butadiene ND 0.20 7/29/22 23:51 BRFND40.440.17 0.37 2-Butanone (MEK)12 8.0 7/29/22 23:51 BRF37 4242.1 6.3 Carbon Disulfide 0.42 2.0 7/29/22 23:51 BRFJ1.3 46.20.18 0.58 Carbon Tetrachloride ND 0.20 7/29/22 23:51 BRFND41.30.16 1.0 Chlorobenzene ND 0.20 7/29/22 23:51 BRFND40.920.13 0.61 Chloroethane ND 0.20 7/29/22 23:51 BRFND40.530.18 0.47 Chloroform 0.58 0.20 7/29/22 23:51 BRF2.9 40.980.19 0.93 Chloromethane ND 0.40 7/29/22 23:51 BRFND40.830.16 0.33 Cyclohexane 1.1 0.20 7/29/22 23:51 BRF3.8 40.690.12 0.42 Dibromochloromethane ND 0.20 7/29/22 23:51 BRFND41.70.13 1.1 1,2-Dibromoethane (EDB)ND 0.20 7/29/22 23:51 BRFND41.50.12 0.93 1,2-Dichlorobenzene ND 0.20 7/29/22 23:51 BRFND41.20.11 0.69 1,3-Dichlorobenzene 13 0.20 7/29/22 23:51 BRF78 41.20.11 0.67 1,4-Dichlorobenzene ND 0.20 7/29/22 23:51 BRFND41.20.13 0.79 Dichlorodifluoromethane (Freon 12)0.55 0.20 7/29/22 23:51 BRF2.7 40.990.20 0.97 1,1-Dichloroethane ND 0.20 7/29/22 23:51 BRFND40.810.17 0.71 1,2-Dichloroethane ND 0.20 7/29/22 23:51 BRFND40.810.18 0.73 1,1-Dichloroethylene ND 0.20 7/29/22 23:51 BRFND40.790.15 0.60 cis-1,2-Dichloroethylene ND 0.20 7/29/22 23:51 BRFND40.790.15 0.58 trans-1,2-Dichloroethylene ND 0.20 7/29/22 23:51 BRFND40.790.16 0.62 1,2-Dichloropropane ND 0.20 7/29/22 23:51 BRFND40.920.11 0.50 cis-1,3-Dichloropropene ND 0.20 7/29/22 23:51 BRFND40.910.10 0.47 trans-1,3-Dichloropropene ND 0.20 7/29/22 23:51 BRFND40.910.10 0.46 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 7/29/22 23:51 BRFND41.40.20 1.4 1,4-Dioxane ND 2.0 7/29/22 23:51 BRFND47.20.17 0.60 Ethanol 440 60 8/1/22 15:04 BRF830 301102650 Ethyl Acetate 1.8 2.0 7/29/22 23:51 BRFJ6.5 47.21.0 3.6 Ethylbenzene 0.49 0.20 7/29/22 23:51 BRF2.1 40.870.12 0.51 4-Ethyltoluene 0.18 0.20 7/29/22 23:51 BRFJ0.88 40.980.12 0.60 Heptane 0.51 0.20 7/29/22 23:51 BRF2.1 40.820.13 0.52 Hexachlorobutadiene ND 0.20 7/29/22 23:51 BRFND42.10.16 1.8 Hexane 2.3 8.0 7/29/22 23:51 BRFJ8.0 4281.0 3.7 2-Hexanone (MBK)ND 0.20 7/29/22 23:51 BRFND40.820.10 0.41 Isopropanol 61 8.0 7/29/22 23:51 BRF150 4201.4 3.4 Methyl tert-Butyl Ether (MTBE)ND 0.20 7/29/22 23:51 BRFND40.720.15 0.56 Methylene Chloride ND 2.0 7/29/22 23:51 BRFND46.90.93 3.2 4-Methyl-2-pentanone (MIBK)0.84 0.20 7/29/22 23:51 BRF3.4 40.820.11 0.44 Naphthalene ND 0.20 7/29/22 23:51 BRFND41.00.15 0.79 Propene ND 8.0 7/29/22 23:51 BRFND4141.8 3.0 Styrene 0.65 0.20 7/29/22 23:51 BRF2.8 40.850.11 0.45 1,1,2,2-Tetrachloroethane ND 0.20 7/29/22 23:51 BRFND41.40.11 0.74 Page 11 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1207Sample Description/Location: Field Sample #: SS-16 Sample ID: 22G1207-04 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -6.4 Sampled: 7/19/2022 15:17 Canister ID: 2641 Flow Controller ID: 411 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 0.53 0.20 7/29/22 23:51 BRF3.6 41.40.15 1.0 Tetrahydrofuran 0.90 2.0 7/29/22 23:51 BRFJ2.6 45.90.33 0.97 Toluene 5.7 0.20 7/29/22 23:51 BRF22 40.750.11 0.43 1,2,4-Trichlorobenzene ND 0.20 7/29/22 23:51 BRFND41.50.19 1.4 1,1,1-Trichloroethane ND 0.20 7/29/22 23:51 BRFND41.10.16 0.86 1,1,2-Trichloroethane ND 0.20 7/29/22 23:51 BRFND41.10.14 0.77 Trichloroethylene ND 0.20 7/29/22 23:51 BRFND41.10.13 0.72 Trichlorofluoromethane (Freon 11)4.7 0.80 7/29/22 23:51 BRF26 44.50.24 1.3 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 7/29/22 23:51 BRFND46.10.22 1.7 1,2,4-Trimethylbenzene ND 0.20 7/29/22 23:51 BRFND40.980.088 0.43 1,3,5-Trimethylbenzene 0.16 0.20 7/29/22 23:51 BRFJ0.81 40.980.11 0.52 Vinyl Acetate ND 4.0 7/29/22 23:51 BRFL-03, V-05 ND 4141.1 3.8 Vinyl Chloride ND 0.20 7/29/22 23:51 BRFND40.510.18 0.46 m&p-Xylene 1.4 0.40 7/29/22 23:51 BRF6.1 41.70.22 0.97 o-Xylene 1.1 0.20 7/29/22 23:51 BRF4.6 40.870.10 0.44 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)78.6 8/1/22 15:0470-130 4-Bromofluorobenzene (1)96.2 7/29/22 23:5170-130 Page 12 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1207Sample Description/Location: Field Sample #: SS-17 Sample ID: 22G1207-05 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -2.5 Sampled: 7/20/2022 10:42 Canister ID: 2654 Flow Controller ID: 4261 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 42 8.0 7/30/22 0:19 BRF99 4194.8 11 Benzene 0.26 0.20 7/30/22 0:19 BRF0.82 40.640.15 0.48 Benzyl chloride ND 0.40 7/30/22 0:19 BRFND42.10.18 0.91 Bromodichloromethane ND 0.20 7/30/22 0:19 BRFND41.30.14 0.94 Bromoform ND 0.20 7/30/22 0:19 BRFND42.10.14 1.4 Bromomethane ND 0.20 7/30/22 0:19 BRFND40.780.13 0.52 1,3-Butadiene ND 0.20 7/30/22 0:19 BRFND40.440.17 0.37 2-Butanone (MEK)4.0 8.0 7/30/22 0:19 BRFJ12 4242.1 6.3 Carbon Disulfide 0.54 2.0 7/30/22 0:19 BRFJ1.7 46.20.18 0.58 Carbon Tetrachloride ND 0.20 7/30/22 0:19 BRFND41.30.16 1.0 Chlorobenzene ND 0.20 7/30/22 0:19 BRFND40.920.13 0.61 Chloroethane ND 0.20 7/30/22 0:19 BRFND40.530.18 0.47 Chloroform ND 0.20 7/30/22 0:19 BRFND40.980.19 0.93 Chloromethane 0.35 0.40 7/30/22 0:19 BRFJ0.72 40.830.16 0.33 Cyclohexane 0.88 0.20 7/30/22 0:19 BRF3.0 40.690.12 0.42 Dibromochloromethane ND 0.20 7/30/22 0:19 BRFND41.70.13 1.1 1,2-Dibromoethane (EDB)ND 0.20 7/30/22 0:19 BRFND41.50.12 0.93 1,2-Dichlorobenzene ND 0.20 7/30/22 0:19 BRFND41.20.11 0.69 1,3-Dichlorobenzene 7.5 0.20 7/30/22 0:19 BRF45 41.20.11 0.67 1,4-Dichlorobenzene ND 0.20 7/30/22 0:19 BRFND41.20.13 0.79 Dichlorodifluoromethane (Freon 12)0.86 0.20 7/30/22 0:19 BRF4.3 40.990.20 0.97 1,1-Dichloroethane ND 0.20 7/30/22 0:19 BRFND40.810.17 0.71 1,2-Dichloroethane ND 0.20 7/30/22 0:19 BRFND40.810.18 0.73 1,1-Dichloroethylene ND 0.20 7/30/22 0:19 BRFND40.790.15 0.60 cis-1,2-Dichloroethylene ND 0.20 7/30/22 0:19 BRFND40.790.15 0.58 trans-1,2-Dichloroethylene ND 0.20 7/30/22 0:19 BRFND40.790.16 0.62 1,2-Dichloropropane ND 0.20 7/30/22 0:19 BRFND40.920.11 0.50 cis-1,3-Dichloropropene ND 0.20 7/30/22 0:19 BRFND40.910.10 0.47 trans-1,3-Dichloropropene ND 0.20 7/30/22 0:19 BRFND40.910.10 0.46 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 7/30/22 0:19 BRFND41.40.20 1.4 1,4-Dioxane ND 2.0 7/30/22 0:19 BRFND47.20.17 0.60 Ethanol 200 20 8/1/22 15:30 BRF370 10388.8 17 Ethyl Acetate 22 2.0 7/30/22 0:19 BRF78 47.21.0 3.6 Ethylbenzene 0.34 0.20 7/30/22 0:19 BRF1.5 40.870.12 0.51 4-Ethyltoluene ND 0.20 7/30/22 0:19 BRFND40.980.12 0.60 Heptane 0.48 0.20 7/30/22 0:19 BRF2.0 40.820.13 0.52 Hexachlorobutadiene ND 0.20 7/30/22 0:19 BRFND42.10.16 1.8 Hexane 2.7 8.0 7/30/22 0:19 BRFJ9.5 4281.0 3.7 2-Hexanone (MBK)ND 0.20 7/30/22 0:19 BRFND40.820.10 0.41 Isopropanol 30 8.0 7/30/22 0:19 BRF73 4201.4 3.4 Methyl tert-Butyl Ether (MTBE)ND 0.20 7/30/22 0:19 BRFND40.720.15 0.56 Methylene Chloride ND 2.0 7/30/22 0:19 BRFND46.90.93 3.2 4-Methyl-2-pentanone (MIBK)0.78 0.20 7/30/22 0:19 BRF3.2 40.820.11 0.44 Naphthalene ND 0.20 7/30/22 0:19 BRFND41.00.15 0.79 Propene ND 8.0 7/30/22 0:19 BRFND4141.8 3.0 Styrene 0.56 0.20 7/30/22 0:19 BRF2.4 40.850.11 0.45 1,1,2,2-Tetrachloroethane ND 0.20 7/30/22 0:19 BRFND41.40.11 0.74 Page 13 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1207Sample Description/Location: Field Sample #: SS-17 Sample ID: 22G1207-05 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -2.5 Sampled: 7/20/2022 10:42 Canister ID: 2654 Flow Controller ID: 4261 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 19 0.20 7/30/22 0:19 BRF130 41.40.15 1.0 Tetrahydrofuran ND 2.0 7/30/22 0:19 BRFND45.90.33 0.97 Toluene 5.2 0.20 7/30/22 0:19 BRF20 40.750.11 0.43 1,2,4-Trichlorobenzene ND 0.20 7/30/22 0:19 BRFND41.50.19 1.4 1,1,1-Trichloroethane 0.30 0.20 7/30/22 0:19 BRF1.6 41.10.16 0.86 1,1,2-Trichloroethane ND 0.20 7/30/22 0:19 BRFND41.10.14 0.77 Trichloroethylene 0.59 0.20 7/30/22 0:19 BRF3.2 41.10.13 0.72 Trichlorofluoromethane (Freon 11)1.4 0.80 7/30/22 0:19 BRF7.8 44.50.24 1.3 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 7/30/22 0:19 BRFND46.10.22 1.7 1,2,4-Trimethylbenzene ND 0.20 7/30/22 0:19 BRFND40.980.088 0.43 1,3,5-Trimethylbenzene ND 0.20 7/30/22 0:19 BRFND40.980.11 0.52 Vinyl Acetate ND 4.0 7/30/22 0:19 BRFL-03, V-05 ND 4141.1 3.8 Vinyl Chloride ND 0.20 7/30/22 0:19 BRFND40.510.18 0.46 m&p-Xylene 0.94 0.40 7/30/22 0:19 BRF4.1 41.70.22 0.97 o-Xylene 0.61 0.20 7/30/22 0:19 BRF2.7 40.870.10 0.44 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)86.3 8/1/22 15:3070-130 4-Bromofluorobenzene (1)96.3 7/30/22 0:1970-130 Page 14 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1207Sample Description/Location: Field Sample #: SS-18 Sample ID: 22G1207-06 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -29.5 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -5.4 Sampled: 7/20/2022 11:07 Canister ID: 2524 Flow Controller ID: 4321 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 1700 600 8/1/22 15:57 BRF4100 3001400360860 Benzene 3.1 0.20 7/30/22 0:47 BRF9.9 40.640.15 0.48 Benzyl chloride ND 0.40 7/30/22 0:47 BRFND42.10.18 0.91 Bromodichloromethane ND 0.20 7/30/22 0:47 BRFND41.30.14 0.94 Bromoform ND 0.20 7/30/22 0:47 BRFND42.10.14 1.4 Bromomethane ND 0.20 7/30/22 0:47 BRFND40.780.13 0.52 1,3-Butadiene ND 0.20 7/30/22 0:47 BRFND40.440.17 0.37 2-Butanone (MEK)61 8.0 7/30/22 0:47 BRF180 4242.1 6.3 Carbon Disulfide 2.4 2.0 7/30/22 0:47 BRF7.5 46.20.18 0.58 Carbon Tetrachloride ND 0.20 7/30/22 0:47 BRFND41.30.16 1.0 Chlorobenzene ND 0.20 7/30/22 0:47 BRFND40.920.13 0.61 Chloroethane ND 0.20 7/30/22 0:47 BRFND40.530.18 0.47 Chloroform ND 0.20 7/30/22 0:47 BRFND40.980.19 0.93 Chloromethane ND 0.40 7/30/22 0:47 BRFND40.830.16 0.33 Cyclohexane ND 0.20 7/30/22 0:47 BRFND40.690.12 0.42 Dibromochloromethane ND 0.20 7/30/22 0:47 BRFND41.70.13 1.1 1,2-Dibromoethane (EDB)ND 0.20 7/30/22 0:47 BRFND41.50.12 0.93 1,2-Dichlorobenzene ND 0.20 7/30/22 0:47 BRFND41.20.11 0.69 1,3-Dichlorobenzene 12 0.20 7/30/22 0:47 BRF71 41.20.11 0.67 1,4-Dichlorobenzene ND 0.20 7/30/22 0:47 BRFND41.20.13 0.79 Dichlorodifluoromethane (Freon 12)0.49 0.20 7/30/22 0:47 BRF2.4 40.990.20 0.97 1,1-Dichloroethane ND 0.20 7/30/22 0:47 BRFND40.810.17 0.71 1,2-Dichloroethane ND 0.20 7/30/22 0:47 BRFND40.810.18 0.73 1,1-Dichloroethylene ND 0.20 7/30/22 0:47 BRFND40.790.15 0.60 cis-1,2-Dichloroethylene ND 0.20 7/30/22 0:47 BRFND40.790.15 0.58 trans-1,2-Dichloroethylene ND 0.20 7/30/22 0:47 BRFND40.790.16 0.62 1,2-Dichloropropane ND 0.20 7/30/22 0:47 BRFND40.920.11 0.50 cis-1,3-Dichloropropene ND 0.20 7/30/22 0:47 BRFND40.910.10 0.47 trans-1,3-Dichloropropene ND 0.20 7/30/22 0:47 BRFND40.910.10 0.46 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 7/30/22 0:47 BRFND41.40.20 1.4 1,4-Dioxane 4.5 2.0 7/30/22 0:47 BRF16 47.20.17 0.60 Ethanol 470 60 7/30/22 1:16 BRF880 301102650 Ethyl Acetate ND 2.0 7/30/22 0:47 BRFND47.21.0 3.6 Ethylbenzene 15 0.20 7/30/22 0:47 BRF64 40.870.12 0.51 4-Ethyltoluene 4.4 0.20 7/30/22 0:47 BRF22 40.980.12 0.60 Heptane 0.79 0.20 7/30/22 0:47 BRF3.2 40.820.13 0.52 Hexachlorobutadiene ND 0.20 7/30/22 0:47 BRFND42.10.16 1.8 Hexane 3.0 8.0 7/30/22 0:47 BRFJ11 4281.0 3.7 2-Hexanone (MBK)23 0.20 7/30/22 0:47 BRF95 40.820.10 0.41 Isopropanol 310 60 7/30/22 1:16 BRF760 301501025 Methyl tert-Butyl Ether (MTBE)ND 0.20 7/30/22 0:47 BRFND40.720.15 0.56 Methylene Chloride ND 2.0 7/30/22 0:47 BRFND46.90.93 3.2 4-Methyl-2-pentanone (MIBK)40 0.20 7/30/22 0:47 BRF160 40.820.11 0.44 Naphthalene 0.28 0.20 7/30/22 0:47 BRF1.5 41.00.15 0.79 Propene 3.5 8.0 7/30/22 0:47 BRFJ6.0 4141.8 3.0 Styrene 1.1 0.20 7/30/22 0:47 BRF4.6 40.850.11 0.45 1,1,2,2-Tetrachloroethane ND 0.20 7/30/22 0:47 BRFND41.40.11 0.74 Page 15 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1207Sample Description/Location: Field Sample #: SS-18 Sample ID: 22G1207-06 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -29.5 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -5.4 Sampled: 7/20/2022 11:07 Canister ID: 2524 Flow Controller ID: 4321 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 25 0.20 7/30/22 0:47 BRF170 41.40.15 1.0 Tetrahydrofuran ND 2.0 7/30/22 0:47 BRFND45.90.33 0.97 Toluene 3.8 0.20 7/30/22 0:47 BRF14 40.750.11 0.43 1,2,4-Trichlorobenzene ND 0.20 7/30/22 0:47 BRFND41.50.19 1.4 1,1,1-Trichloroethane 2.3 0.20 7/30/22 0:47 BRF13 41.10.16 0.86 1,1,2-Trichloroethane ND 0.20 7/30/22 0:47 BRFND41.10.14 0.77 Trichloroethylene 2.2 0.20 7/30/22 0:47 BRF12 41.10.13 0.72 Trichlorofluoromethane (Freon 11)2.0 0.80 7/30/22 0:47 BRF11 44.50.24 1.3 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 7/30/22 0:47 BRFND46.10.22 1.7 1,2,4-Trimethylbenzene 17 0.20 7/30/22 0:47 BRF81 40.980.088 0.43 1,3,5-Trimethylbenzene 4.7 0.20 7/30/22 0:47 BRF23 40.980.11 0.52 Vinyl Acetate ND 4.0 7/30/22 0:47 BRFL-03, V-05 ND 4141.1 3.8 Vinyl Chloride ND 0.20 7/30/22 0:47 BRFND40.510.18 0.46 m&p-Xylene 43 0.40 7/30/22 0:47 BRF190 41.70.22 0.97 o-Xylene 12 0.20 7/30/22 0:47 BRF51 40.870.10 0.44 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)96.7 7/30/22 1:1670-130 4-Bromofluorobenzene (1)88.2 8/1/22 15:5770-130 4-Bromofluorobenzene (1)103 7/30/22 0:4770-130 Page 16 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1207Sample Description/Location: Field Sample #: SS-19 Sample ID: 22G1207-07 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -6.1 Sampled: 7/20/2022 11:40 Canister ID: 2773 Flow Controller ID: 4232 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 98 8.0 7/30/22 1:44 BRF230 4194.8 11 Benzene 3.3 0.20 7/30/22 1:44 BRF10 40.640.15 0.48 Benzyl chloride ND 0.40 7/30/22 1:44 BRFND42.10.18 0.91 Bromodichloromethane ND 0.20 7/30/22 1:44 BRFND41.30.14 0.94 Bromoform ND 0.20 7/30/22 1:44 BRFND42.10.14 1.4 Bromomethane ND 0.20 7/30/22 1:44 BRFND40.780.13 0.52 1,3-Butadiene ND 0.20 7/30/22 1:44 BRFND40.440.17 0.37 2-Butanone (MEK)7.9 8.0 7/30/22 1:44 BRFJ23 4242.1 6.3 Carbon Disulfide 2.5 2.0 7/30/22 1:44 BRF7.9 46.20.18 0.58 Carbon Tetrachloride ND 0.20 7/30/22 1:44 BRFND41.30.16 1.0 Chlorobenzene ND 0.20 7/30/22 1:44 BRFND40.920.13 0.61 Chloroethane ND 0.20 7/30/22 1:44 BRFND40.530.18 0.47 Chloroform 1.1 0.20 7/30/22 1:44 BRF5.6 40.980.19 0.93 Chloromethane ND 0.40 7/30/22 1:44 BRFND40.830.16 0.33 Cyclohexane 1.0 0.20 7/30/22 1:44 BRF3.5 40.690.12 0.42 Dibromochloromethane ND 0.20 7/30/22 1:44 BRFND41.70.13 1.1 1,2-Dibromoethane (EDB)ND 0.20 7/30/22 1:44 BRFND41.50.12 0.93 1,2-Dichlorobenzene ND 0.20 7/30/22 1:44 BRFND41.20.11 0.69 1,3-Dichlorobenzene 4.0 0.20 7/30/22 1:44 BRF24 41.20.11 0.67 1,4-Dichlorobenzene ND 0.20 7/30/22 1:44 BRFND41.20.13 0.79 Dichlorodifluoromethane (Freon 12)0.56 0.20 7/30/22 1:44 BRF2.8 40.990.20 0.97 1,1-Dichloroethane 920 1.5 7/30/22 2:13 BRF3700 306.11.3 5.3 1,2-Dichloroethane ND 0.20 7/30/22 1:44 BRFND40.810.18 0.73 1,1-Dichloroethylene 880 1.5 7/30/22 2:13 BRF3500 305.91.1 4.5 cis-1,2-Dichloroethylene ND 0.20 7/30/22 1:44 BRFND40.790.15 0.58 trans-1,2-Dichloroethylene ND 0.20 7/30/22 1:44 BRFND40.790.16 0.62 1,2-Dichloropropane ND 0.20 7/30/22 1:44 BRFND40.920.11 0.50 cis-1,3-Dichloropropene ND 0.20 7/30/22 1:44 BRFND40.910.10 0.47 trans-1,3-Dichloropropene ND 0.20 7/30/22 1:44 BRFND40.910.10 0.46 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 7/30/22 1:44 BRFND41.40.20 1.4 1,4-Dioxane 2.2 2.0 7/30/22 1:44 BRF8.0 47.20.17 0.60 Ethanol 200 8.0 7/30/22 1:44 BRF370 4153.5 6.6 Ethyl Acetate ND 2.0 7/30/22 1:44 BRFND47.21.0 3.6 Ethylbenzene 0.25 0.20 7/30/22 1:44 BRF1.1 40.870.12 0.51 4-Ethyltoluene ND 0.20 7/30/22 1:44 BRFND40.980.12 0.60 Heptane 0.22 0.20 7/30/22 1:44 BRF0.90 40.820.13 0.52 Hexachlorobutadiene ND 0.20 7/30/22 1:44 BRFND42.10.16 1.8 Hexane 2.1 8.0 7/30/22 1:44 BRFJ7.2 4281.0 3.7 2-Hexanone (MBK)ND 0.20 7/30/22 1:44 BRFND40.820.10 0.41 Isopropanol 34 8.0 7/30/22 1:44 BRF84 4201.4 3.4 Methyl tert-Butyl Ether (MTBE)ND 0.20 7/30/22 1:44 BRFND40.720.15 0.56 Methylene Chloride ND 2.0 7/30/22 1:44 BRFND46.90.93 3.2 4-Methyl-2-pentanone (MIBK)1.6 0.20 7/30/22 1:44 BRF6.7 40.820.11 0.44 Naphthalene 4.7 0.20 7/30/22 1:44 BRF25 41.00.15 0.79 Propene ND 8.0 7/30/22 1:44 BRFND4141.8 3.0 Styrene 0.38 0.20 7/30/22 1:44 BRF1.6 40.850.11 0.45 1,1,2,2-Tetrachloroethane ND 0.20 7/30/22 1:44 BRFND41.40.11 0.74 Page 17 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1207Sample Description/Location: Field Sample #: SS-19 Sample ID: 22G1207-07 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -6.1 Sampled: 7/20/2022 11:40 Canister ID: 2773 Flow Controller ID: 4232 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 29 0.20 7/30/22 1:44 BRF200 41.40.15 1.0 Tetrahydrofuran ND 2.0 7/30/22 1:44 BRFND45.90.33 0.97 Toluene 1.6 0.20 7/30/22 1:44 BRF5.9 40.750.11 0.43 1,2,4-Trichlorobenzene ND 0.20 7/30/22 1:44 BRFND41.50.19 1.4 1,1,1-Trichloroethane 1.2 0.20 7/30/22 1:44 BRF6.4 41.10.16 0.86 1,1,2-Trichloroethane ND 0.20 7/30/22 1:44 BRFND41.10.14 0.77 Trichloroethylene 3.6 0.20 7/30/22 1:44 BRF20 41.10.13 0.72 Trichlorofluoromethane (Freon 11)0.44 0.80 7/30/22 1:44 BRFJ2.4 44.50.24 1.3 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)3.3 0.80 7/30/22 1:44 BRF25 46.10.22 1.7 1,2,4-Trimethylbenzene ND 0.20 7/30/22 1:44 BRFND40.980.088 0.43 1,3,5-Trimethylbenzene 0.12 0.20 7/30/22 1:44 BRFJ0.57 40.980.11 0.52 Vinyl Acetate ND 4.0 7/30/22 1:44 BRFL-03, V-05 ND 4141.1 3.8 Vinyl Chloride 0.32 0.20 7/30/22 1:44 BRF0.83 40.510.18 0.46 m&p-Xylene 0.68 0.40 7/30/22 1:44 BRF3.0 41.70.22 0.97 o-Xylene 0.43 0.20 7/30/22 1:44 BRF1.9 40.870.10 0.44 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)99.2 7/30/22 1:4470-130 4-Bromofluorobenzene (1)93.9 7/30/22 2:1370-130 Page 18 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1207Sample Description/Location: Field Sample #: SS-20 Sample ID: 22G1207-08 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -5.7 Sampled: 7/20/2022 12:02 Canister ID: 2247 Flow Controller ID: 4337 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 78 8.0 7/30/22 2:44 BRF180 4194.8 11 Benzene 0.30 0.20 7/30/22 2:44 BRF0.95 40.640.15 0.48 Benzyl chloride ND 0.40 7/30/22 2:44 BRFND42.10.18 0.91 Bromodichloromethane ND 0.20 7/30/22 2:44 BRFND41.30.14 0.94 Bromoform ND 0.20 7/30/22 2:44 BRFND42.10.14 1.4 Bromomethane ND 0.20 7/30/22 2:44 BRFND40.780.13 0.52 1,3-Butadiene ND 0.20 7/30/22 2:44 BRFND40.440.17 0.37 2-Butanone (MEK)4.2 8.0 7/30/22 2:44 BRFJ12 4242.1 6.3 Carbon Disulfide 0.91 2.0 7/30/22 2:44 BRFJ2.8 46.20.18 0.58 Carbon Tetrachloride ND 0.20 7/30/22 2:44 BRFND41.30.16 1.0 Chlorobenzene ND 0.20 7/30/22 2:44 BRFND40.920.13 0.61 Chloroethane ND 0.20 7/30/22 2:44 BRFND40.530.18 0.47 Chloroform ND 0.20 7/30/22 2:44 BRFND40.980.19 0.93 Chloromethane 0.38 0.40 7/30/22 2:44 BRFJ0.78 40.830.16 0.33 Cyclohexane 1.2 0.20 7/30/22 2:44 BRF4.2 40.690.12 0.42 Dibromochloromethane ND 0.20 7/30/22 2:44 BRFND41.70.13 1.1 1,2-Dibromoethane (EDB)ND 0.20 7/30/22 2:44 BRFND41.50.12 0.93 1,2-Dichlorobenzene ND 0.20 7/30/22 2:44 BRFND41.20.11 0.69 1,3-Dichlorobenzene 9.6 0.20 7/30/22 2:44 BRF58 41.20.11 0.67 1,4-Dichlorobenzene ND 0.20 7/30/22 2:44 BRFND41.20.13 0.79 Dichlorodifluoromethane (Freon 12)0.50 0.20 7/30/22 2:44 BRF2.5 40.990.20 0.97 1,1-Dichloroethane ND 0.20 7/30/22 2:44 BRFND40.810.17 0.71 1,2-Dichloroethane ND 0.20 7/30/22 2:44 BRFND40.810.18 0.73 1,1-Dichloroethylene ND 0.20 7/30/22 2:44 BRFND40.790.15 0.60 cis-1,2-Dichloroethylene ND 0.20 7/30/22 2:44 BRFND40.790.15 0.58 trans-1,2-Dichloroethylene ND 0.20 7/30/22 2:44 BRFND40.790.16 0.62 1,2-Dichloropropane ND 0.20 7/30/22 2:44 BRFND40.920.11 0.50 cis-1,3-Dichloropropene ND 0.20 7/30/22 2:44 BRFND40.910.10 0.47 trans-1,3-Dichloropropene ND 0.20 7/30/22 2:44 BRFND40.910.10 0.46 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 7/30/22 2:44 BRFND41.40.20 1.4 1,4-Dioxane 2.9 2.0 7/30/22 2:44 BRF10 47.20.17 0.60 Ethanol 4.0 8.0 7/30/22 2:44 BRFJ7.6 4153.5 6.6 Ethyl Acetate 1.1 2.0 7/30/22 2:44 BRFJ4.0 47.21.0 3.6 Ethylbenzene 0.86 0.20 7/30/22 2:44 BRF3.8 40.870.12 0.51 4-Ethyltoluene 0.21 0.20 7/30/22 2:44 BRF1.0 40.980.12 0.60 Heptane 0.54 0.20 7/30/22 2:44 BRF2.2 40.820.13 0.52 Hexachlorobutadiene ND 0.20 7/30/22 2:44 BRFND42.10.16 1.8 Hexane 2.3 8.0 7/30/22 2:44 BRFJ8.1 4281.0 3.7 2-Hexanone (MBK)ND 0.20 7/30/22 2:44 BRFND40.820.10 0.41 Isopropanol 20 8.0 7/30/22 2:44 BRF49 4201.4 3.4 Methyl tert-Butyl Ether (MTBE)ND 0.20 7/30/22 2:44 BRFND40.720.15 0.56 Methylene Chloride ND 2.0 7/30/22 2:44 BRFND46.90.93 3.2 4-Methyl-2-pentanone (MIBK)1.4 0.20 7/30/22 2:44 BRF5.8 40.820.11 0.44 Naphthalene 0.18 0.20 7/30/22 2:44 BRFJ0.92 41.00.15 0.79 Propene ND 8.0 7/30/22 2:44 BRFND4141.8 3.0 Styrene 0.69 0.20 7/30/22 2:44 BRF2.9 40.850.11 0.45 1,1,2,2-Tetrachloroethane ND 0.20 7/30/22 2:44 BRFND41.40.11 0.74 Page 19 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1207Sample Description/Location: Field Sample #: SS-20 Sample ID: 22G1207-08 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -5.7 Sampled: 7/20/2022 12:02 Canister ID: 2247 Flow Controller ID: 4337 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 4.4 0.20 7/30/22 2:44 BRF30 41.40.15 1.0 Tetrahydrofuran ND 2.0 7/30/22 2:44 BRFND45.90.33 0.97 Toluene 4.4 0.20 7/30/22 2:44 BRF17 40.750.11 0.43 1,2,4-Trichlorobenzene ND 0.20 7/30/22 2:44 BRFND41.50.19 1.4 1,1,1-Trichloroethane 0.29 0.20 7/30/22 2:44 BRF1.6 41.10.16 0.86 1,1,2-Trichloroethane ND 0.20 7/30/22 2:44 BRFND41.10.14 0.77 Trichloroethylene 0.60 0.20 7/30/22 2:44 BRF3.2 41.10.13 0.72 Trichlorofluoromethane (Freon 11)0.55 0.80 7/30/22 2:44 BRFJ3.1 44.50.24 1.3 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 7/30/22 2:44 BRFND46.10.22 1.7 1,2,4-Trimethylbenzene 0.92 0.20 7/30/22 2:44 BRF4.5 40.980.088 0.43 1,3,5-Trimethylbenzene 0.32 0.20 7/30/22 2:44 BRF1.6 40.980.11 0.52 Vinyl Acetate ND 4.0 7/30/22 2:44 BRFL-03, V-05 ND 4141.1 3.8 Vinyl Chloride ND 0.20 7/30/22 2:44 BRFND40.510.18 0.46 m&p-Xylene 3.2 0.40 7/30/22 2:44 BRF14 41.70.22 0.97 o-Xylene 1.9 0.20 7/30/22 2:44 BRF8.4 40.870.10 0.44 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)97.3 7/30/22 2:4470-130 Page 20 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1207Sample Description/Location: Field Sample #: SS-21 Sample ID: 22G1207-09 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -6.4 Sampled: 7/20/2022 15:55 Canister ID: 2338 Flow Controller ID: 4281 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 39 8.0 7/30/22 3:12 BRF92 4194.8 11 Benzene 0.67 0.20 7/30/22 3:12 BRF2.1 40.640.15 0.48 Benzyl chloride ND 0.40 7/30/22 3:12 BRFND42.10.18 0.91 Bromodichloromethane ND 0.20 7/30/22 3:12 BRFND41.30.14 0.94 Bromoform ND 0.20 7/30/22 3:12 BRFND42.10.14 1.4 Bromomethane ND 0.20 7/30/22 3:12 BRFND40.780.13 0.52 1,3-Butadiene ND 0.20 7/30/22 3:12 BRFND40.440.17 0.37 2-Butanone (MEK)3.9 8.0 7/30/22 3:12 BRFJ11 4242.1 6.3 Carbon Disulfide 0.42 2.0 7/30/22 3:12 BRFJ1.3 46.20.18 0.58 Carbon Tetrachloride ND 0.20 7/30/22 3:12 BRFND41.30.16 1.0 Chlorobenzene ND 0.20 7/30/22 3:12 BRFND40.920.13 0.61 Chloroethane ND 0.20 7/30/22 3:12 BRFND40.530.18 0.47 Chloroform ND 0.20 7/30/22 3:12 BRFND40.980.19 0.93 Chloromethane ND 0.40 7/30/22 3:12 BRFND40.830.16 0.33 Cyclohexane 1.4 0.20 7/30/22 3:12 BRF4.7 40.690.12 0.42 Dibromochloromethane ND 0.20 7/30/22 3:12 BRFND41.70.13 1.1 1,2-Dibromoethane (EDB)ND 0.20 7/30/22 3:12 BRFND41.50.12 0.93 1,2-Dichlorobenzene ND 0.20 7/30/22 3:12 BRFND41.20.11 0.69 1,3-Dichlorobenzene 11 0.20 7/30/22 3:12 BRF64 41.20.11 0.67 1,4-Dichlorobenzene ND 0.20 7/30/22 3:12 BRFND41.20.13 0.79 Dichlorodifluoromethane (Freon 12)0.54 0.20 7/30/22 3:12 BRF2.7 40.990.20 0.97 1,1-Dichloroethane 14 0.20 7/30/22 3:12 BRF58 40.810.17 0.71 1,2-Dichloroethane ND 0.20 7/30/22 3:12 BRFND40.810.18 0.73 1,1-Dichloroethylene 0.86 0.20 7/30/22 3:12 BRF3.4 40.790.15 0.60 cis-1,2-Dichloroethylene 87 0.20 7/30/22 3:12 BRF350 40.790.15 0.58 trans-1,2-Dichloroethylene 12 0.20 7/30/22 3:12 BRF49 40.790.16 0.62 1,2-Dichloropropane ND 0.20 7/30/22 3:12 BRFND40.920.11 0.50 cis-1,3-Dichloropropene ND 0.20 7/30/22 3:12 BRFND40.910.10 0.47 trans-1,3-Dichloropropene ND 0.20 7/30/22 3:12 BRFND40.910.10 0.46 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 7/30/22 3:12 BRFND41.40.20 1.4 1,4-Dioxane 0.81 2.0 7/30/22 3:12 BRFJ2.9 47.20.17 0.60 Ethanol 160 8.0 7/30/22 3:12 BRF300 4153.5 6.6 Ethyl Acetate ND 2.0 7/30/22 3:12 BRFND47.21.0 3.6 Ethylbenzene 0.66 0.20 7/30/22 3:12 BRF2.8 40.870.12 0.51 4-Ethyltoluene 0.19 0.20 7/30/22 3:12 BRFJ0.92 40.980.12 0.60 Heptane 0.82 0.20 7/30/22 3:12 BRF3.4 40.820.13 0.52 Hexachlorobutadiene ND 0.20 7/30/22 3:12 BRFND42.10.16 1.8 Hexane 3.2 8.0 7/30/22 3:12 BRFJ11 4281.0 3.7 2-Hexanone (MBK)ND 0.20 7/30/22 3:12 BRFND40.820.10 0.41 Isopropanol 29 8.0 7/30/22 3:12 BRF71 4201.4 3.4 Methyl tert-Butyl Ether (MTBE)ND 0.20 7/30/22 3:12 BRFND40.720.15 0.56 Methylene Chloride ND 2.0 7/30/22 3:12 BRFND46.90.93 3.2 4-Methyl-2-pentanone (MIBK)ND 0.20 7/30/22 3:12 BRFND40.820.11 0.44 Naphthalene ND 0.20 7/30/22 3:12 BRFND41.00.15 0.79 Propene ND 8.0 7/30/22 3:12 BRFND4141.8 3.0 Styrene 1.1 0.20 7/30/22 3:12 BRF4.5 40.850.11 0.45 1,1,2,2-Tetrachloroethane ND 0.20 7/30/22 3:12 BRFND41.40.11 0.74 Page 21 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1207Sample Description/Location: Field Sample #: SS-21 Sample ID: 22G1207-09 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -6.4 Sampled: 7/20/2022 15:55 Canister ID: 2338 Flow Controller ID: 4281 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 25 0.20 7/30/22 3:12 BRF170 41.40.15 1.0 Tetrahydrofuran ND 2.0 7/30/22 3:12 BRFND45.90.33 0.97 Toluene 2.5 0.20 7/30/22 3:12 BRF9.6 40.750.11 0.43 1,2,4-Trichlorobenzene ND 0.20 7/30/22 3:12 BRFND41.50.19 1.4 1,1,1-Trichloroethane ND 0.20 7/30/22 3:12 BRFND41.10.16 0.86 1,1,2-Trichloroethane ND 0.20 7/30/22 3:12 BRFND41.10.14 0.77 Trichloroethylene 220 0.50 8/1/22 16:22 BRF1200 102.70.34 1.8 Trichlorofluoromethane (Freon 11)0.34 0.80 7/30/22 3:12 BRFJ1.9 44.50.24 1.3 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 7/30/22 3:12 BRFND46.10.22 1.7 1,2,4-Trimethylbenzene ND 0.20 7/30/22 3:12 BRFND40.980.088 0.43 1,3,5-Trimethylbenzene 0.22 0.20 7/30/22 3:12 BRF1.1 40.980.11 0.52 Vinyl Acetate ND 4.0 7/30/22 3:12 BRFL-03, V-05 ND 4141.1 3.8 Vinyl Chloride 0.33 0.20 7/30/22 3:12 BRF0.85 40.510.18 0.46 m&p-Xylene 2.1 0.40 7/30/22 3:12 BRF9.0 41.70.22 0.97 o-Xylene 1.2 0.20 7/30/22 3:12 BRF5.2 40.870.10 0.44 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)83.1 8/1/22 16:2270-130 4-Bromofluorobenzene (1)98.2 7/30/22 3:1270-130 Page 22 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1207Sample Description/Location: Field Sample #: SS-Dup Sample ID: 22G1207-10 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -6.5 Sampled: 7/20/2022 00:00 Canister ID: 2783 Flow Controller ID: 4281 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 33 8.0 7/30/22 3:42 BRF79 4194.8 11 Benzene 0.66 0.20 7/30/22 3:42 BRF2.1 40.640.15 0.48 Benzyl chloride ND 0.40 7/30/22 3:42 BRFND42.10.18 0.91 Bromodichloromethane ND 0.20 7/30/22 3:42 BRFND41.30.14 0.94 Bromoform ND 0.20 7/30/22 3:42 BRFND42.10.14 1.4 Bromomethane ND 0.20 7/30/22 3:42 BRFND40.780.13 0.52 1,3-Butadiene ND 0.20 7/30/22 3:42 BRFND40.440.17 0.37 2-Butanone (MEK)3.2 8.0 7/30/22 3:42 BRFJ9.6 4242.1 6.3 Carbon Disulfide 0.51 2.0 7/30/22 3:42 BRFJ1.6 46.20.18 0.58 Carbon Tetrachloride ND 0.20 7/30/22 3:42 BRFND41.30.16 1.0 Chlorobenzene ND 0.20 7/30/22 3:42 BRFND40.920.13 0.61 Chloroethane ND 0.20 7/30/22 3:42 BRFND40.530.18 0.47 Chloroform ND 0.20 7/30/22 3:42 BRFND40.980.19 0.93 Chloromethane ND 0.40 7/30/22 3:42 BRFND40.830.16 0.33 Cyclohexane 1.1 0.20 7/30/22 3:42 BRF3.6 40.690.12 0.42 Dibromochloromethane ND 0.20 7/30/22 3:42 BRFND41.70.13 1.1 1,2-Dibromoethane (EDB)ND 0.20 7/30/22 3:42 BRFND41.50.12 0.93 1,2-Dichlorobenzene ND 0.20 7/30/22 3:42 BRFND41.20.11 0.69 1,3-Dichlorobenzene 10 0.20 7/30/22 3:42 BRF63 41.20.11 0.67 1,4-Dichlorobenzene ND 0.20 7/30/22 3:42 BRFND41.20.13 0.79 Dichlorodifluoromethane (Freon 12)0.52 0.20 7/30/22 3:42 BRF2.6 40.990.20 0.97 1,1-Dichloroethane 14 0.20 7/30/22 3:42 BRF56 40.810.17 0.71 1,2-Dichloroethane ND 0.20 7/30/22 3:42 BRFND40.810.18 0.73 1,1-Dichloroethylene 0.86 0.20 7/30/22 3:42 BRF3.4 40.790.15 0.60 cis-1,2-Dichloroethylene 86 0.20 7/30/22 3:42 BRF340 40.790.15 0.58 trans-1,2-Dichloroethylene 12 0.20 7/30/22 3:42 BRF48 40.790.16 0.62 1,2-Dichloropropane ND 0.20 7/30/22 3:42 BRFND40.920.11 0.50 cis-1,3-Dichloropropene ND 0.20 7/30/22 3:42 BRFND40.910.10 0.47 trans-1,3-Dichloropropene ND 0.20 7/30/22 3:42 BRFND40.910.10 0.46 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 7/30/22 3:42 BRFND41.40.20 1.4 1,4-Dioxane ND 2.0 7/30/22 3:42 BRFND47.20.17 0.60 Ethanol 150 8.0 7/30/22 3:42 BRF290 4153.5 6.6 Ethyl Acetate ND 2.0 7/30/22 3:42 BRFND47.21.0 3.6 Ethylbenzene 0.61 0.20 7/30/22 3:42 BRF2.6 40.870.12 0.51 4-Ethyltoluene 0.18 0.20 7/30/22 3:42 BRFJ0.88 40.980.12 0.60 Heptane 0.92 0.20 7/30/22 3:42 BRF3.8 40.820.13 0.52 Hexachlorobutadiene ND 0.20 7/30/22 3:42 BRFND42.10.16 1.8 Hexane 3.2 8.0 7/30/22 3:42 BRFJ11 4281.0 3.7 2-Hexanone (MBK)ND 0.20 7/30/22 3:42 BRFND40.820.10 0.41 Isopropanol 26 8.0 7/30/22 3:42 BRF65 4201.4 3.4 Methyl tert-Butyl Ether (MTBE)ND 0.20 7/30/22 3:42 BRFND40.720.15 0.56 Methylene Chloride ND 2.0 7/30/22 3:42 BRFND46.90.93 3.2 4-Methyl-2-pentanone (MIBK)0.76 0.20 7/30/22 3:42 BRF3.1 40.820.11 0.44 Naphthalene ND 0.20 7/30/22 3:42 BRFND41.00.15 0.79 Propene ND 8.0 7/30/22 3:42 BRFND4141.8 3.0 Styrene 0.98 0.20 7/30/22 3:42 BRF4.2 40.850.11 0.45 1,1,2,2-Tetrachloroethane ND 0.20 7/30/22 3:42 BRFND41.40.11 0.74 Page 23 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1207Sample Description/Location: Field Sample #: SS-Dup Sample ID: 22G1207-10 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -6.5 Sampled: 7/20/2022 00:00 Canister ID: 2783 Flow Controller ID: 4281 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 25 0.20 7/30/22 3:42 BRF170 41.40.15 1.0 Tetrahydrofuran ND 2.0 7/30/22 3:42 BRFND45.90.33 0.97 Toluene 2.8 0.20 7/30/22 3:42 BRF10 40.750.11 0.43 1,2,4-Trichlorobenzene ND 0.20 7/30/22 3:42 BRFND41.50.19 1.4 1,1,1-Trichloroethane ND 0.20 7/30/22 3:42 BRFND41.10.16 0.86 1,1,2-Trichloroethane ND 0.20 7/30/22 3:42 BRFND41.10.14 0.77 Trichloroethylene 230 0.50 8/1/22 16:48 BRF1200 102.70.34 1.8 Trichlorofluoromethane (Freon 11)0.34 0.80 7/30/22 3:42 BRFJ1.9 44.50.24 1.3 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 7/30/22 3:42 BRFND46.10.22 1.7 1,2,4-Trimethylbenzene ND 0.20 7/30/22 3:42 BRFND40.980.088 0.43 1,3,5-Trimethylbenzene 0.21 0.20 7/30/22 3:42 BRF1.0 40.980.11 0.52 Vinyl Acetate ND 4.0 7/30/22 3:42 BRFL-03, V-05 ND 4141.1 3.8 Vinyl Chloride 0.36 0.20 7/30/22 3:42 BRF0.91 40.510.18 0.46 m&p-Xylene 2.1 0.40 7/30/22 3:42 BRF9.2 41.70.22 0.97 o-Xylene 1.1 0.20 7/30/22 3:42 BRF5.0 40.870.10 0.44 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)82.8 8/1/22 16:4870-130 4-Bromofluorobenzene (1)97.4 7/30/22 3:4270-130 Page 24 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B314267 - TO-15 Prep Blank (B314267-BLK1)Prepared & Analyzed: 07/29/22 0.80NDAcetone 0.020NDBenzene 0.020NDBenzyl chloride 0.020NDBromodichloromethane 0.020NDBromoform 0.020NDBromomethane 0.020ND1,3-Butadiene 0.80ND2-Butanone (MEK) 0.20NDCarbon Disulfide 0.020NDCarbon Tetrachloride 0.020NDChlorobenzene 0.020NDChloroethane 0.020NDChloroform 0.040NDChloromethane 0.020NDCyclohexane 0.020NDDibromochloromethane 0.020ND1,2-Dibromoethane (EDB) 0.020ND1,2-Dichlorobenzene 0.020ND1,3-Dichlorobenzene 0.020ND1,4-Dichlorobenzene 0.020NDDichlorodifluoromethane (Freon 12) 0.020ND1,1-Dichloroethane 0.020ND1,2-Dichloroethane 0.020ND1,1-Dichloroethylene 0.020NDcis-1,2-Dichloroethylene 0.020NDtrans-1,2-Dichloroethylene 0.020ND1,2-Dichloropropane 0.020NDcis-1,3-Dichloropropene 0.020NDtrans-1,3-Dichloropropene 0.020ND1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 0.20ND1,4-Dioxane 0.80NDEthanol 0.20NDEthyl Acetate 0.020NDEthylbenzene 0.020ND4-Ethyltoluene 0.020NDHeptane 0.020NDHexachlorobutadiene 0.80NDHexane 0.020ND2-Hexanone (MBK) 0.80NDIsopropanol 0.020NDMethyl tert-Butyl Ether (MTBE) 0.20NDMethylene Chloride 0.020ND4-Methyl-2-pentanone (MIBK) 0.020NDNaphthalene 0.80NDPropene 0.020NDStyrene Page 25 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B314267 - TO-15 Prep Blank (B314267-BLK1)Prepared & Analyzed: 07/29/22 0.020ND1,1,2,2-Tetrachloroethane 0.020NDTetrachloroethylene 0.20NDTetrahydrofuran 0.020NDToluene 0.020ND1,2,4-Trichlorobenzene 0.020ND1,1,1-Trichloroethane 0.020ND1,1,2-Trichloroethane 0.020NDTrichloroethylene 0.080NDTrichlorofluoromethane (Freon 11) 0.080ND1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 0.020ND1,2,4-Trimethylbenzene 0.020ND1,3,5-Trimethylbenzene 0.40 L-03, V-05NDVinyl Acetate 0.020NDVinyl Chloride 0.040NDm&p-Xylene 0.020NDo-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)96.87.74 LCS (B314267-BS1)Prepared & Analyzed: 07/29/22 5.00 70-1301065.30Acetone 5.00 70-1301015.04Benzene 5.00 L-01, V-20, 70-1301638.15Benzyl chloride * 5.00 70-13099.34.96Bromodichloromethane 5.00 70-1301035.14Bromoform 5.00 70-1301075.34Bromomethane 5.00 70-1301075.351,3-Butadiene 5.00 70-13093.44.672-Butanone (MEK) 5.00 70-1301035.16Carbon Disulfide 5.00 70-1301015.05Carbon Tetrachloride 5.00 70-13099.74.98Chlorobenzene 5.00 70-1301075.34Chloroethane 5.00 70-1301065.28Chloroform 5.00 70-1301035.13Chloromethane 5.00 70-1301065.32Cyclohexane 5.00 70-1301025.11Dibromochloromethane 5.00 70-1301045.181,2-Dibromoethane (EDB) 5.00 70-1301105.501,2-Dichlorobenzene 5.00 70-1301105.521,3-Dichlorobenzene 5.00 70-1301266.321,4-Dichlorobenzene 5.00 70-1301075.36Dichlorodifluoromethane (Freon 12) 5.00 70-1301035.151,1-Dichloroethane 5.00 70-1301035.131,2-Dichloroethane 5.00 70-1301055.241,1-Dichloroethylene 5.00 70-1301025.12cis-1,2-Dichloroethylene 5.00 70-1301015.06trans-1,2-Dichloroethylene Page 26 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B314267 - TO-15 Prep LCS (B314267-BS1)Prepared & Analyzed: 07/29/22 5.00 70-13098.54.921,2-Dichloropropane 5.00 70-13099.84.99cis-1,3-Dichloropropene 5.00 70-1301065.29trans-1,3-Dichloropropene 5.00 70-13099.94.991,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 5.00 70-1301105.521,4-Dioxane 5.00 70-1301015.06Ethanol 5.00 70-1301065.28Ethyl Acetate 5.00 70-1301065.28Ethylbenzene 5.00 70-1301135.654-Ethyltoluene 5.00 70-1301015.03Heptane 5.00 70-13086.44.32Hexachlorobutadiene 5.00 70-1301055.23Hexane 5.00 70-1301065.322-Hexanone (MBK) 5.00 70-13093.14.66Isopropanol 5.00 70-1301236.13Methyl tert-Butyl Ether (MTBE) 5.00 70-13096.44.82Methylene Chloride 5.00 70-1301005.024-Methyl-2-pentanone (MIBK) 5.00 70-13098.14.91Naphthalene 5.00 70-1301055.25Propene 5.00 70-1301125.61Styrene 5.00 70-1301015.031,1,2,2-Tetrachloroethane 5.00 70-13097.94.89Tetrachloroethylene 5.00 70-1301055.25Tetrahydrofuran 5.00 70-1301045.18Toluene 5.00 V-3670-1301045.191,2,4-Trichlorobenzene 5.00 70-1301035.141,1,1-Trichloroethane 5.00 70-1301035.161,1,2-Trichloroethane 5.00 70-1301005.01Trichloroethylene 5.00 70-1301075.36Trichlorofluoromethane (Freon 11) 5.00 70-1301115.531,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 5.00 70-1301105.521,2,4-Trimethylbenzene 5.00 70-1301125.591,3,5-Trimethylbenzene 5.00 L-03, V-0570-13059.32.96Vinyl Acetate * 5.00 70-1301085.42Vinyl Chloride 10.0 70-13010410.4m&p-Xylene 5.00 70-1301085.41o-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1018.11 Page 27 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B314341 - TO-15 Prep Blank (B314341-BLK1)Prepared & Analyzed: 08/01/22 0.80NDAcetone 0.80NDEthanol 0.020NDTrichloroethylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)89.17.13 LCS (B314341-BS1)Prepared & Analyzed: 08/01/22 5.00 70-13088.94.45Acetone 5.00 70-13084.64.23Ethanol 5.00 70-13095.74.79Trichloroethylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)96.17.69 Duplicate (B314341-DUP1)Prepared & Analyzed: 08/01/22 Source: 22G1207-03RE1 40 330 254.47350Ethanol75660 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)76.16.09 Page 28 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Note: Blank Subtraction is not performed unless otherwise noted *QC result is outside of established limits. †Wide recovery limits established for difficult compound. ‡Wide RPD limits established for difficult compound. #Data exceeded client recommended or regulatory level RL Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference LCS Laboratory Control Sample Laboratory Control SampleLCS Dup Duplicate Laboratory Control Sample MS Matrix Spike Sample MS Dup Duplicate Matrix Spike Sample REC Recovery QC Quality Control ppbv Parts per billion volume EPA United States Environmental Protection Agency Percent Recovery% REC ND Not Detected Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the calculation which have not been rounded. Not ApplicableN/A DL Detection Limit Not CalculatedNC LFB/LCS Lab Fortified Blank/Lab Control Sample ORP Oxidation-Reduction Potential Not dry weight correctedwet Percent weight% wt KilogramKg Gramg Milligrammg Microgramµg Nanogramng LiterL MillilitermL Microliter L Cubic Meterm3 Extractable Petroleum HydrocarbonsEPH Volatile Petroleum HydrocarbonsVPH Air Petroleum HydrocarbonsAPH Flame Ionization DetectorFID Photo Ionization DetectorPID FLAG/QUALIFIER SUMMARY Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated concentration (CLP J-Flag). J Laboratory fortified blank/laboratory control sample recovery outside of control limits. Data validation is not affected since all results are "not detected" for all samples in this batch for this compound and bias is on the high side. L-01 Laboratory fortified blank/laboratory control sample recovery is outside of control limits. Reported value for this compound is likely to be biased on the low side. L-03 Continuing calibration verification (CCV) did not meet method specifications and was biased on the low side for this compound. V-05 Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side. Data validation is not affected since sample result was "not detected" for this compound. V-20 Initial calibration verification (ICV) did not meet method specifications and was biased on the high side. Data validation is not affected since sample result was "not detected" for this compound. V-36 Page 29 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYST Thomas P. HniteckiTPH Rebecca FaustRLF Raisa A. PetraitisRAP PDF Management StationSTATION Kerry K. McGeeKKM Brittany R. FiskBRF Page 30 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q Initial Cal Check (S069304-ICV1 )Lab File ID: K22A075019.D Analyzed: 03/16/22 23:55 Bromochloromethane (1)104138 2.987 104138 2.987 60 - 140100 0.0000 +/-0.50 1,4-Difluorobenzene (1)315817 3.584 315817 3.584 60 - 140100 0.0000 +/-0.50 Chlorobenzene-d5 (1)233658 5.159 233658 5.159 60 - 140100 0.0000 +/-0.50 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q Initial Cal Check (S072768-ICV1 )Lab File ID: J22A0165021.D Analyzed: 06/14/22 17:07 Bromochloromethane (1)126885 2.827 126885 2.827 60 - 140100 0.0000 +/-0.50 1,4-Difluorobenzene (1)579074 3.445 579074 3.445 60 - 140100 0.0000 +/-0.50 Chlorobenzene-d5 (1)531253 5.048 531253 5.048 60 - 140100 0.0000 +/-0.50 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q LCS (B314267-BS1 )Lab File ID: K22A210005.D Analyzed: 07/29/22 10:24 Bromochloromethane (1)116140 3.001 102745 2.987 60 - 140113 0.0140 +/-0.50 1,4-Difluorobenzene (1)355389 3.588 303801 3.579 60 - 140117 0.0090 +/-0.50 Chlorobenzene-d5 (1)260279 5.163 223280 5.159 60 - 140117 0.0040 +/-0.50 Blank (B314267-BLK1 )Lab File ID: K22A210008.D Analyzed: 07/29/22 12:05 Bromochloromethane (1)115126 3.001 102745 2.987 60 - 140112 0.0140 +/-0.50 1,4-Difluorobenzene (1)339293 3.588 303801 3.579 60 - 140112 0.0090 +/-0.50 Chlorobenzene-d5 (1)247140 5.163 223280 5.159 60 - 140111 0.0040 +/-0.50 Calibration Check (S074611-CCV1 )Lab File ID: K22A210009.D Analyzed: 07/29/22 14:03 Bromochloromethane (1)115438 3.001 115438 3.001 60 - 140100 0.0000 +/-0.50 1,4-Difluorobenzene (1)351715 3.588 351715 3.588 60 - 140100 0.0000 +/-0.50 Chlorobenzene-d5 (1)262458 5.163 262458 5.163 60 - 140100 0.0000 +/-0.50 SS-13 (22G1207-01 )Lab File ID: K22A210025.D Analyzed: 07/29/22 22:26 Bromochloromethane (1)114169 3.001 115438 3.001 60 - 14099 0.0000 +/-0.50 1,4-Difluorobenzene (1)341454 3.593 351715 3.588 60 - 14097 0.0050 +/-0.50 Chlorobenzene-d5 (1)255875 5.163 262458 5.163 60 - 14097 0.0000 +/-0.50 SS-14 (22G1207-02 )Lab File ID: K22A210026.D Analyzed: 07/29/22 22:54 Bromochloromethane (1)114554 3.005 115438 3.001 60 - 14099 0.0040 +/-0.50 1,4-Difluorobenzene (1)345717 3.592 351715 3.588 60 - 14098 0.0040 +/-0.50 Chlorobenzene-d5 (1)258427 5.163 262458 5.163 60 - 14098 0.0000 +/-0.50 Page 31 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q SS-15 (22G1207-03 )Lab File ID: K22A210027.D Analyzed: 07/29/22 23:23 Bromochloromethane (1)115250 3.001 115438 3.001 60 - 140100 0.0000 +/-0.50 1,4-Difluorobenzene (1)355067 3.588 351715 3.588 60 - 140101 0.0000 +/-0.50 Chlorobenzene-d5 (1)264442 5.163 262458 5.163 60 - 140101 0.0000 +/-0.50 SS-16 (22G1207-04 )Lab File ID: K22A210028.D Analyzed: 07/29/22 23:51 Bromochloromethane (1)111165 3.001 115438 3.001 60 - 14096 0.0000 +/-0.50 1,4-Difluorobenzene (1)343904 3.593 351715 3.588 60 - 14098 0.0050 +/-0.50 Chlorobenzene-d5 (1)257421 5.163 262458 5.163 60 - 14098 0.0000 +/-0.50 SS-17 (22G1207-05 )Lab File ID: K22A210029.D Analyzed: 07/30/22 00:19 Bromochloromethane (1)115041 3.005 115438 3.001 60 - 140100 0.0040 +/-0.50 1,4-Difluorobenzene (1)342380 3.593 351715 3.588 60 - 14097 0.0050 +/-0.50 Chlorobenzene-d5 (1)263000 5.163 262458 5.163 60 - 140100 0.0000 +/-0.50 SS-18 (22G1207-06 )Lab File ID: K22A210030.D Analyzed: 07/30/22 00:47 Bromochloromethane (1)111697 3.001 115438 3.001 60 - 14097 0.0000 +/-0.50 1,4-Difluorobenzene (1)360504 3.593 351715 3.588 60 - 140102 0.0050 +/-0.50 Chlorobenzene-d5 (1)265110 5.163 262458 5.163 60 - 140101 0.0000 +/-0.50 SS-18 (22G1207-06RE1 )Lab File ID: K22A210031.D Analyzed: 07/30/22 01:16 Bromochloromethane (1)109381 3.001 115438 3.001 60 - 14095 0.0000 +/-0.50 1,4-Difluorobenzene (1)350481 3.593 351715 3.588 60 - 140100 0.0050 +/-0.50 Chlorobenzene-d5 (1)251588 5.163 262458 5.163 60 - 14096 0.0000 +/-0.50 SS-19 (22G1207-07 )Lab File ID: K22A210032.D Analyzed: 07/30/22 01:44 Bromochloromethane (1)108792 3.005 115438 3.001 60 - 14094 0.0040 +/-0.50 1,4-Difluorobenzene (1)345571 3.592 351715 3.588 60 - 14098 0.0040 +/-0.50 Chlorobenzene-d5 (1)253522 5.163 262458 5.163 60 - 14097 0.0000 +/-0.50 SS-19 (22G1207-07RE1 )Lab File ID: K22A210033.D Analyzed: 07/30/22 02:13 Bromochloromethane (1)116075 3.001 115438 3.001 60 - 140101 0.0000 +/-0.50 1,4-Difluorobenzene (1)363953 3.593 351715 3.588 60 - 140103 0.0050 +/-0.50 Chlorobenzene-d5 (1)268140 5.163 262458 5.163 60 - 140102 0.0000 +/-0.50 SS-20 (22G1207-08 )Lab File ID: K22A210034.D Analyzed: 07/30/22 02:44 Bromochloromethane (1)120741 3 115438 3.001 60 - 140105 -0.0010 +/-0.50 1,4-Difluorobenzene (1)376759 3.592 351715 3.588 60 - 140107 0.0040 +/-0.50 Chlorobenzene-d5 (1)278483 5.163 262458 5.163 60 - 140106 0.0000 +/-0.50 SS-21 (22G1207-09 )Lab File ID: K22A210035.D Analyzed: 07/30/22 03:12 Bromochloromethane (1)119944 3.01 115438 3.001 60 - 140104 0.0090 +/-0.50 1,4-Difluorobenzene (1)350043 3.597 351715 3.588 60 - 140100 0.0090 +/-0.50 Chlorobenzene-d5 (1)282371 5.163 262458 5.163 60 - 140108 0.0000 +/-0.50 Page 32 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q SS-Dup (22G1207-10 )Lab File ID: K22A210036.D Analyzed: 07/30/22 03:42 Bromochloromethane (1)119699 3.005 115438 3.001 60 - 140104 0.0040 +/-0.50 1,4-Difluorobenzene (1)348722 3.597 351715 3.588 60 - 14099 0.0090 +/-0.50 Chlorobenzene-d5 (1)278027 5.163 262458 5.163 60 - 140106 0.0000 +/-0.50 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q Calibration Check (S074676-CCV1 )Lab File ID: J22A213004.D Analyzed: 08/01/22 10:05 Bromochloromethane (1)144882 2.805 144882 2.805 60 - 140100 0.0000 +/-0.50 1,4-Difluorobenzene (1)573967 3.433 573967 3.433 60 - 140100 0.0000 +/-0.50 Chlorobenzene-d5 (1)504418 5.045 504418 5.045 60 - 140100 0.0000 +/-0.50 LCS (B314341-BS1 )Lab File ID: J22A213005.D Analyzed: 08/01/22 10:30 Bromochloromethane (1)147235 2.808 144882 2.805 60 - 140102 0.0030 +/-0.50 1,4-Difluorobenzene (1)582029 3.433 573967 3.433 60 - 140101 0.0000 +/-0.50 Chlorobenzene-d5 (1)504056 5.045 504418 5.045 60 - 140100 0.0000 +/-0.50 Blank (B314341-BLK1 )Lab File ID: J22A213008.D Analyzed: 08/01/22 11:59 Bromochloromethane (1)161521 2.791 144882 2.805 60 - 140111 -0.0140 +/-0.50 1,4-Difluorobenzene (1)511132 3.423 573967 3.433 60 - 14089 -0.0100 +/-0.50 Chlorobenzene-d5 (1)466355 5.041 504418 5.045 60 - 14092 -0.0040 +/-0.50 SS-13 (22G1207-01RE1 )Lab File ID: J22A213009.D Analyzed: 08/01/22 13:26 Bromochloromethane (1)156518 2.794 144882 2.805 60 - 140108 -0.0110 +/-0.50 1,4-Difluorobenzene (1)508201 3.423 573967 3.433 60 - 14089 -0.0100 +/-0.50 Chlorobenzene-d5 (1)511013 5.038 504418 5.045 60 - 140101 -0.0070 +/-0.50 SS-14 (22G1207-02RE1 )Lab File ID: J22A213010.D Analyzed: 08/01/22 13:51 Bromochloromethane (1)160654 2.795 144882 2.805 60 - 140111 -0.0100 +/-0.50 1,4-Difluorobenzene (1)519635 3.423 573967 3.433 60 - 14091 -0.0100 +/-0.50 Chlorobenzene-d5 (1)462488 5.042 504418 5.045 60 - 14092 -0.0030 +/-0.50 SS-15 (22G1207-03RE1 )Lab File ID: J22A213011.D Analyzed: 08/01/22 14:16 Bromochloromethane (1)160153 2.792 144882 2.805 60 - 140111 -0.0130 +/-0.50 1,4-Difluorobenzene (1)542999 3.424 573967 3.433 60 - 14095 -0.0090 +/-0.50 Chlorobenzene-d5 (1)472030 5.042 504418 5.045 60 - 14094 -0.0030 +/-0.50 Duplicate (B314341-DUP1 )Lab File ID: J22A213012.D Analyzed: 08/01/22 14:40 Bromochloromethane (1)157851 2.792 144882 2.805 60 - 140109 -0.0130 +/-0.50 1,4-Difluorobenzene (1)525986 3.424 573967 3.433 60 - 14092 -0.0090 +/-0.50 Chlorobenzene-d5 (1)516891 5.042 504418 5.045 60 - 140102 -0.0030 +/-0.50 Page 33 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q SS-16 (22G1207-04RE1 )Lab File ID: J22A213013.D Analyzed: 08/01/22 15:04 Bromochloromethane (1)158355 2.792 144882 2.805 60 - 140109 -0.0130 +/-0.50 1,4-Difluorobenzene (1)508559 3.424 573967 3.433 60 - 14089 -0.0090 +/-0.50 Chlorobenzene-d5 (1)467487 5.042 504418 5.045 60 - 14093 -0.0030 +/-0.50 SS-17 (22G1207-05RE1 )Lab File ID: J22A213014.D Analyzed: 08/01/22 15:30 Bromochloromethane (1)163977 2.798 144882 2.805 60 - 140113 -0.0070 +/-0.50 1,4-Difluorobenzene (1)528080 3.427 573967 3.433 60 - 14092 -0.0060 +/-0.50 Chlorobenzene-d5 (1)484385 5.042 504418 5.045 60 - 14096 -0.0030 +/-0.50 SS-18 (22G1207-06RE2 )Lab File ID: J22A213015.D Analyzed: 08/01/22 15:57 Bromochloromethane (1)159683 2.791 144882 2.805 60 - 140110 -0.0140 +/-0.50 1,4-Difluorobenzene (1)522158 3.423 573967 3.433 60 - 14091 -0.0100 +/-0.50 Chlorobenzene-d5 (1)473702 5.041 504418 5.045 60 - 14094 -0.0040 +/-0.50 SS-21 (22G1207-09RE1 )Lab File ID: J22A213016.D Analyzed: 08/01/22 16:22 Bromochloromethane (1)159284 2.801 144882 2.805 60 - 140110 -0.0040 +/-0.50 1,4-Difluorobenzene (1)559364 3.433 573967 3.433 60 - 14097 0.0000 +/-0.50 Chlorobenzene-d5 (1)535852 5.042 504418 5.045 60 - 140106 -0.0030 +/-0.50 SS-Dup (22G1207-10RE1 )Lab File ID: J22A213017.D Analyzed: 08/01/22 16:48 Bromochloromethane (1)159192 2.802 144882 2.805 60 - 140110 -0.0030 +/-0.50 1,4-Difluorobenzene (1)566831 3.433 573967 3.433 60 - 14099 0.0000 +/-0.50 Chlorobenzene-d5 (1)544486 5.042 504418 5.045 60 - 140108 -0.0030 +/-0.50 Page 34 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CONTINUING CALIBRATION CHECK EPA TO-15 S074611-CCV1 COMPOUND TYPE CCV MIN (#)CCV LIMIT (#)CCV ICAL CONC. (ppbv)% DIFF / DRIFTRESPONSE FACTOR STD 1.029457A 2.8 305.14 1.0015045.00Acetone 0.6490664A 2.4 305.12 0.6337045.00Benzene 0.7814248A 76.7 *308.84 0.44210815.00Benzyl chloride 0.453681A 1.2 305.06 0.44847425.00Bromodichloromethane 0.5567916A 4.8 305.24 0.53136085.00Bromoform 0.6188049A 8.9 305.44 0.568465.00Bromomethane 0.5596355A 13.3 305.66 0.49412945.001,3-Butadiene 1.038147A -9.2 304.54 1.1433395.002-Butanone (MEK) 2.145581A 2.1 305.11 2.1010975.00Carbon Disulfide 0.371196A 3.6 305.18 0.35837935.00Carbon Tetrachloride 0.7417507A 1.5 305.08 0.73073575.00Chlorobenzene 0.4054679A 8.7 305.44 0.37289695.00Chloroethane 1.306371A 8.3 305.42 1.2059735.00Chloroform 0.6273705A 7.4 305.37 0.58435035.00Chloromethane 0.2626854A 6.2 305.31 0.24743965.00Cyclohexane 0.5521828A 2.9 305.15 0.53656275.00Dibromochloromethane 0.4996579A 6.4 305.32 0.46964285.001,2-Dibromoethane (EDB) 0.6205641A 14.4 305.72 0.54254115.001,2-Dichlorobenzene 0.6568243A 17.8 305.89 0.55776855.001,3-Dichlorobenzene 0.6113649A 26.3 306.31 0.48416785.001,4-Dichlorobenzene 1.548662A 7.7 305.39 1.4373685.00Dichlorodifluoromethane (Freon 12) 1.021418A 2.8 305.14 0.99331175.001,1-Dichloroethane 0.786209A 3.4 305.17 0.76049545.001,2-Dichloroethane 1.07751A 5.1 305.25 1.0254175.001,1-Dichloroethylene 0.8669034A 6.1 305.30 0.81743615.00cis-1,2-Dichloroethylene 0.8445746A 2.2 305.11 0.82655715.00trans-1,2-Dichloroethylene 0.2485831A -1.6 304.92 0.25255515.001,2-Dichloropropane 0.4239342A 4.9 305.24 0.40422685.00cis-1,3-Dichloropropene 0.3095688A 9.7 305.48 0.28217545.00trans-1,3-Dichloropropene 1.695774A 7.9 305.40 1.5711765.001,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 0.1323435A 5.7 305.28 0.12523265.001,4-Dioxane 0.2457423A 4.7 305.23 0.23481145.00Ethanol 0.2116738A 17.7 305.89 0.17977625.00Ethyl Acetate 1.237483A 6.1 305.31 1.1661035.00Ethylbenzene 1.244408A 14.0 305.70 1.0915375.004-Ethyltoluene 0.2554159A 7.7 305.39 0.23709755.00Heptane 0.3735455A -2.9 304.86 0.38469915.00Hexachlorobutadiene 0.6651536L 5.5 305.27 0.61173145.00Hexane Page 35 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CONTINUING CALIBRATION CHECK EPA TO-15 S074611-CCV1 COMPOUND TYPE CCV MIN (#)CCV LIMIT (#)CCV ICAL CONC. (ppbv)% DIFF / DRIFTRESPONSE FACTOR STD 0.5278406A -0.3 304.99 0.52934325.002-Hexanone (MBK) 1.376628A 11.6 305.58 1.2331515.00Isopropanol 1.748125A 24.5 306.23 1.4039195.00Methyl tert-Butyl Ether (MTBE) 0.7755782A 0.08 305.00 0.77496645.00Methylene Chloride 9.325278E-02A -10.1 304.50 0.10367325.004-Methyl-2-pentanone (MIBK) 0.8703442A -4.0 304.80 0.90672085.00Naphthalene 0.5231137A 9.9 305.50 0.47577555.00Propene 0.7180974A 15.9 305.80 0.61955725.00Styrene 0.7917823A 3.5 305.18 0.76495215.001,1,2,2-Tetrachloroethane 0.3994544A -0.8 304.96 0.40254575.00Tetrachloroethylene 0.6634488A 7.1 305.36 0.61923625.00Tetrahydrofuran 0.9923416A 3.5 305.18 0.95887535.00Toluene 0.306481A 6.1 305.30 0.28885585.001,2,4-Trichlorobenzene 0.4299754A 7.4 305.37 0.40050755.001,1,1-Trichloroethane 0.3402541A 1.9 305.09 0.3339565.001,1,2-Trichloroethane 0.2753548A 3.2 305.16 0.26692125.00Trichloroethylene 1.486942A 9.1 305.46 1.3627485.00Trichlorofluoromethane (Freon 11) 1.444031A 10.1 305.51 1.3112435.001,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 1.04789A 15.1 305.76 0.91012065.001,2,4-Trimethylbenzene 1.07675A 15.7 305.78 0.93057165.001,3,5-Trimethylbenzene 0.9663923A -33.7 *303.32 1.4567695.00Vinyl Acetate 0.7256259A 8.3 305.42 0.67006745.00Vinyl Chloride 1.160628A 17.2 3011.7 0.990172810.0m&p-Xylene 0.9859284A 9.5 305.47 0.90063785.00o-Xylene * Values outside of QC limits # Column to be used to flag Response Factor and %Diff/Drift values with an asterisk Page 36 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CONTINUING CALIBRATION CHECK EPA TO-15 S074676-CCV1 COMPOUND TYPE CCV MIN (#)CCV LIMIT (#)CCV ICAL CONC. (ppbv)% DIFF / DRIFTRESPONSE FACTOR STD 1.014917A -0.2 304.99 1.0165395.00Acetone 0.2146298A 10.4 305.52 0.19441525.00Ethanol 0.312949A 7.5 305.38 0.29108365.00Trichloroethylene * Values outside of QC limits # Column to be used to flag Response Factor and %Diff/Drift values with an asterisk Page 37 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report EPA TO-15 in Air AIHA,NY,ME,NHAcetone AIHA,FL,NJ,NY,ME,NH,VABenzene AIHA,FL,NJ,NY,ME,NH,VABenzyl chloride AIHA,NJ,NY,ME,NH,VABromodichloromethane AIHA,NJ,NY,ME,NH,VABromoform AIHA,FL,NJ,NY,ME,NHBromomethane AIHA,NJ,NY,ME,NH,VA1,3-Butadiene AIHA,FL,NJ,NY,ME,NH,VA2-Butanone (MEK) AIHA,NJ,NY,ME,NH,VACarbon Disulfide AIHA,FL,NJ,NY,ME,NH,VACarbon Tetrachloride AIHA,FL,NJ,NY,ME,NH,VAChlorobenzene AIHA,FL,NJ,NY,ME,NH,VAChloroethane AIHA,FL,NJ,NY,ME,NH,VAChloroform AIHA,FL,NJ,NY,ME,NH,VAChloromethane AIHA,NJ,NY,ME,NH,VACyclohexane AIHA,NY,ME,NHDibromochloromethane AIHA,NJ,NY,ME,NH1,2-Dibromoethane (EDB) AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichlorobenzene AIHA,NJ,NY,ME,NH1,3-Dichlorobenzene AIHA,FL,NJ,NY,ME,NH,VA1,4-Dichlorobenzene AIHA,NY,ME,NHDichlorodifluoromethane (Freon 12) AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethylene AIHA,FL,NY,ME,NH,VAcis-1,2-Dichloroethylene AIHA,NJ,NY,ME,NH,VAtrans-1,2-Dichloroethylene AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichloropropane AIHA,FL,NJ,NY,ME,NH,VAcis-1,3-Dichloropropene AIHA,NY,ME,NHtrans-1,3-Dichloropropene AIHA,NJ,NY,ME,NH,VA1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) AIHA,NJ,NY,ME,NH,VA1,4-Dioxane AIHAEthanol AIHAEthyl Acetate AIHA,FL,NJ,NY,ME,NH,VAEthylbenzene AIHA,NJ4-Ethyltoluene AIHA,NJ,NY,ME,NH,VAHeptane AIHA,NJ,NY,ME,NH,VAHexachlorobutadiene AIHA,FL,NJ,NY,ME,NH,VAHexane AIHA2-Hexanone (MBK) AIHA,NY,ME,NHIsopropanol AIHA,FL,NJ,NY,ME,NH,VAMethyl tert-Butyl Ether (MTBE) AIHA,FL,NJ,NY,ME,NH,VAMethylene Chloride AIHA,FL,NJ,NY,ME,NH4-Methyl-2-pentanone (MIBK) NY,ME,NHNaphthalene AIHAPropene AIHA,FL,NJ,NY,ME,NH,VAStyrene AIHA,FL,NJ,NY,ME,NH,VA1,1,2,2-Tetrachloroethane Page 38 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report EPA TO-15 in Air AIHA,FL,NJ,NY,ME,NH,VATetrachloroethylene AIHATetrahydrofuran AIHA,FL,NJ,NY,ME,NH,VAToluene AIHA,NJ,NY,ME,NH,VA1,2,4-Trichlorobenzene AIHA,FL,NJ,NY,ME,NH,VA1,1,1-Trichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1,2-Trichloroethane AIHA,FL,NJ,NY,ME,NH,VATrichloroethylene AIHA,NY,ME,NHTrichlorofluoromethane (Freon 11) AIHA,NJ,NY,ME,NH,VA1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) AIHA,NJ,NY,ME,NH1,2,4-Trimethylbenzene AIHA,NJ,NY,ME,NH1,3,5-Trimethylbenzene AIHA,FL,NJ,NY,ME,NH,VAVinyl Acetate AIHA,FL,NJ,NY,ME,NH,VAVinyl Chloride AIHA,FL,NJ,NY,ME,NH,VAm&p-Xylene AIHA,FL,NJ,NY,ME,NH,VAo-Xylene Con-Test, a Pace Environmental Laboratory, operates under the following certifications and accreditations: Code Description Number Expires 100033AIHA-LAP, LLC - ISO 17025:2017AIHA 03/1/2024 M-MA100Massachusetts DEPMA 06/30/2023 PH-0165Connecticut Department of Public HealthCT 12/31/2022 10899 NELAPNew York State Department of HealthNY 04/1/2023 2516 NELAPNew Hampshire Environmental LabNH 02/5/2023 LAO00373Rhode Island Department of HealthRI 12/30/2022 652North Carolina Div. of Water QualityNC 12/31/2022 MA007 NELAPNew Jersey DEPNJ 06/30/2023 E871027 NELAPFlorida Department of HealthFL 06/30/2023 LL720741Vermont Department of Health Lead LaboratoryVT 07/30/2023 VT-255716Vermont Department of Health Drinking WaterVT-DW 06/12/2023 MA00100State of MaineME 06/9/2023 460217Commonwealth of VirginiaVA 12/14/2022 2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2022 25703North Carolina Department of Health and Human ServicesNC-DW 07/31/2023 68-05812Commonwealth of Pennsylvania DEPPA 06/30/2023 9100Dept. of Env, Great Lakes, and EnergyMI 09/6/2022 Page 39 of 43 Page 40 of 43 Page 41 of 43 Page 42 of 43 Page 43 of 43 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 August 1, 2022 Justin Ballard Hart & Hickman - Charlotte, NC 2923 South Tryon Street, Suite 100 Charlotte, NC 28203 Project Location: 1900 Continental Blvd, Charlotte, NC Client Job Number: Project Number: SSP-001 Laboratory Work Order Number: 22G1362 Enclosed are results of analyses for samples as received by the laboratory on July 23, 2022. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kerry K. McGee Project Manager QA Officer Katherine Allen Laboratory Manager Daren Damboragian Page 1 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL SUMMARY 8/1/2022Hart & Hickman - Charlotte, NC 2923 South Tryon Street, Suite 100 Charlotte, NC 28203 ATTN: Justin Ballard SSP-001 22G1362 The results of analyses performed on the following samples submitted to Con-Test, a Pace Analytical Laboratory, are found in this report. PROJECT LOCATION: PURCHASE ORDER NUMBER: PROJECT NUMBER: REPORT DATE: WORK ORDER NUMBER: FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB 1900 Continental Blvd, Charlotte, NC SSP-001 SS-22 22G1362-01 Sub Slab EPA TO-15 Page 2 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CASE NARRATIVE SUMMARY All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report. EPA TO-15 Qualifications: Laboratory fortified blank/laboratory control sample recovery outside of control limits. Data validation is not affected since all results are "not detected" for all samples in this batch for this compound and bias is on the high side. Analyte & Samples(s) Qualified: L-01 Benzyl chloride B314267-BS1 Laboratory fortified blank/laboratory control sample recovery is outside of control limits. Reported value for this compound is likely to be biased on the low side. Analyte & Samples(s) Qualified: L-03 Vinyl Acetate 22G1362-01[SS-22], B314267-BLK1, B314267-BS1 Continuing calibration verification (CCV) did not meet method specifications and was biased on the low side for this compound. Analyte & Samples(s) Qualified: V-05 Vinyl Acetate 22G1362-01[SS-22], B314267-BLK1, B314267-BS1, S074611-CCV1 Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side. Data validation is not affected since sample result was "not detected" for this compound. Analyte & Samples(s) Qualified: V-20 Benzyl chloride B314267-BS1, S074611-CCV1 Initial calibration verification (ICV) did not meet method specifications and was biased on the high side. Data validation is not affected since sample result was "not detected" for this compound. Analyte & Samples(s) Qualified: V-36 1,2,4-Trichlorobenzene, Benzyl chloride B314267-BS1, S074611-CCV1 Page 3 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 The results of analyses reported only relate to samples submitted to Con-Test, a Pace Analytical Laboratory, for testing. I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. Lisa A. Worthington Technical Representative Page 4 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/23/2022 Work Order: 22G1362Sample Description/Location: Field Sample #: SS-22 Sample ID: 22G1362-01 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -4.4 Sampled: 7/21/2022 15:51 Canister ID: 2301 Flow Controller ID: 4541 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 37 8.0 7/29/22 19:35 BRF88 4194.8 11 Benzene ND 0.20 7/29/22 19:35 BRFND40.640.15 0.48 Benzyl chloride ND 0.40 7/29/22 19:35 BRFND42.10.18 0.91 Bromodichloromethane ND 0.20 7/29/22 19:35 BRFND41.30.14 0.94 Bromoform ND 0.20 7/29/22 19:35 BRFND42.10.14 1.4 Bromomethane ND 0.20 7/29/22 19:35 BRFND40.780.13 0.52 1,3-Butadiene ND 0.20 7/29/22 19:35 BRFND40.440.17 0.37 2-Butanone (MEK)3.2 8.0 7/29/22 19:35 BRFJ9.5 4242.1 6.3 Carbon Disulfide 0.55 2.0 7/29/22 19:35 BRFJ1.7 46.20.18 0.58 Carbon Tetrachloride ND 0.20 7/29/22 19:35 BRFND41.30.16 1.0 Chlorobenzene ND 0.20 7/29/22 19:35 BRFND40.920.13 0.61 Chloroethane ND 0.20 7/29/22 19:35 BRFND40.530.18 0.47 Chloroform ND 0.20 7/29/22 19:35 BRFND40.980.19 0.93 Chloromethane ND 0.40 7/29/22 19:35 BRFND40.830.16 0.33 Cyclohexane ND 0.20 7/29/22 19:35 BRFND40.690.12 0.42 Dibromochloromethane ND 0.20 7/29/22 19:35 BRFND41.70.13 1.1 1,2-Dibromoethane (EDB)ND 0.20 7/29/22 19:35 BRFND41.50.12 0.93 1,2-Dichlorobenzene ND 0.20 7/29/22 19:35 BRFND41.20.11 0.69 1,3-Dichlorobenzene ND 0.20 7/29/22 19:35 BRFND41.20.11 0.67 1,4-Dichlorobenzene ND 0.20 7/29/22 19:35 BRFND41.20.13 0.79 Dichlorodifluoromethane (Freon 12)0.48 0.20 7/29/22 19:35 BRF2.4 40.990.20 0.97 1,1-Dichloroethane ND 0.20 7/29/22 19:35 BRFND40.810.17 0.71 1,2-Dichloroethane ND 0.20 7/29/22 19:35 BRFND40.810.18 0.73 1,1-Dichloroethylene ND 0.20 7/29/22 19:35 BRFND40.790.15 0.60 cis-1,2-Dichloroethylene ND 0.20 7/29/22 19:35 BRFND40.790.15 0.58 trans-1,2-Dichloroethylene ND 0.20 7/29/22 19:35 BRFND40.790.16 0.62 1,2-Dichloropropane ND 0.20 7/29/22 19:35 BRFND40.920.11 0.50 cis-1,3-Dichloropropene ND 0.20 7/29/22 19:35 BRFND40.910.10 0.47 trans-1,3-Dichloropropene ND 0.20 7/29/22 19:35 BRFND40.910.10 0.46 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.20 7/29/22 19:35 BRFND41.40.20 1.4 1,4-Dioxane ND 2.0 7/29/22 19:35 BRFND47.20.17 0.60 Ethanol 160 8.0 7/29/22 19:35 BRF300 4153.5 6.6 Ethyl Acetate ND 2.0 7/29/22 19:35 BRFND47.21.0 3.6 Ethylbenzene 0.23 0.20 7/29/22 19:35 BRF0.99 40.870.12 0.51 4-Ethyltoluene ND 0.20 7/29/22 19:35 BRFND40.980.12 0.60 Heptane 0.30 0.20 7/29/22 19:35 BRF1.2 40.820.13 0.52 Hexachlorobutadiene ND 0.20 7/29/22 19:35 BRFND42.10.16 1.8 Hexane 1.7 8.0 7/29/22 19:35 BRFJ6.1 4281.0 3.7 2-Hexanone (MBK)ND 0.20 7/29/22 19:35 BRFND40.820.10 0.41 Isopropanol 17 8.0 7/29/22 19:35 BRF41 4201.4 3.4 Methyl tert-Butyl Ether (MTBE)ND 0.20 7/29/22 19:35 BRFND40.720.15 0.56 Methylene Chloride ND 2.0 7/29/22 19:35 BRFND46.90.93 3.2 4-Methyl-2-pentanone (MIBK)0.59 0.20 7/29/22 19:35 BRF2.4 40.820.11 0.44 Naphthalene ND 0.20 7/29/22 19:35 BRFND41.00.15 0.79 Propene ND 8.0 7/29/22 19:35 BRFND4141.8 3.0 Styrene 0.40 0.20 7/29/22 19:35 BRF1.7 40.850.11 0.45 1,1,2,2-Tetrachloroethane ND 0.20 7/29/22 19:35 BRFND41.40.11 0.74 Page 5 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/23/2022 Work Order: 22G1362Sample Description/Location: Field Sample #: SS-22 Sample ID: 22G1362-01 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -4.4 Sampled: 7/21/2022 15:51 Canister ID: 2301 Flow Controller ID: 4541 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 4.3 0.20 7/29/22 19:35 BRF29 41.40.15 1.0 Tetrahydrofuran ND 2.0 7/29/22 19:35 BRFND45.90.33 0.97 Toluene 1.1 0.20 7/29/22 19:35 BRF4.0 40.750.11 0.43 1,2,4-Trichlorobenzene ND 0.20 7/29/22 19:35 BRFND41.50.19 1.4 1,1,1-Trichloroethane 1.3 0.20 7/29/22 19:35 BRF7.2 41.10.16 0.86 1,1,2-Trichloroethane ND 0.20 7/29/22 19:35 BRFND41.10.14 0.77 Trichloroethylene 2.6 0.20 7/29/22 19:35 BRF14 41.10.13 0.72 Trichlorofluoromethane (Freon 11)2.1 0.80 7/29/22 19:35 BRF12 44.50.24 1.3 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)ND 0.80 7/29/22 19:35 BRFND46.10.22 1.7 1,2,4-Trimethylbenzene ND 0.20 7/29/22 19:35 BRFND40.980.088 0.43 1,3,5-Trimethylbenzene ND 0.20 7/29/22 19:35 BRFND40.980.11 0.52 Vinyl Acetate ND 4.0 7/29/22 19:35 BRFV-05, L-03 ND 4141.1 3.8 Vinyl Chloride ND 0.20 7/29/22 19:35 BRFND40.510.18 0.46 m&p-Xylene 0.74 0.40 7/29/22 19:35 BRF3.2 41.70.22 0.97 o-Xylene 0.53 0.20 7/29/22 19:35 BRF2.3 40.870.10 0.44 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)94.2 7/29/22 19:3570-130 Page 6 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Sample Extraction Data Prep Method: TO-15 Prep-EPA TO-15 Lab Number [Field ID]Batch Date Pressure Dilution Pre Dilution Pre-Dil Initial mL Pre-Dil Final mL Default Injection mL Actual Injection mL 22G1362-01 [SS-22]B314267 1.5 1 N/A 1000 200 75 07/29/22 Page 7 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B314267 - TO-15 Prep Blank (B314267-BLK1)Prepared & Analyzed: 07/29/22 0.80NDAcetone 0.020NDBenzene 0.020NDBenzyl chloride 0.020NDBromodichloromethane 0.020NDBromoform 0.020NDBromomethane 0.020ND1,3-Butadiene 0.80ND2-Butanone (MEK) 0.20NDCarbon Disulfide 0.020NDCarbon Tetrachloride 0.020NDChlorobenzene 0.020NDChloroethane 0.020NDChloroform 0.040NDChloromethane 0.020NDCyclohexane 0.020NDDibromochloromethane 0.020ND1,2-Dibromoethane (EDB) 0.020ND1,2-Dichlorobenzene 0.020ND1,3-Dichlorobenzene 0.020ND1,4-Dichlorobenzene 0.020NDDichlorodifluoromethane (Freon 12) 0.020ND1,1-Dichloroethane 0.020ND1,2-Dichloroethane 0.020ND1,1-Dichloroethylene 0.020NDcis-1,2-Dichloroethylene 0.020NDtrans-1,2-Dichloroethylene 0.020ND1,2-Dichloropropane 0.020NDcis-1,3-Dichloropropene 0.020NDtrans-1,3-Dichloropropene 0.020ND1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 0.20ND1,4-Dioxane 0.80NDEthanol 0.20NDEthyl Acetate 0.020NDEthylbenzene 0.020ND4-Ethyltoluene 0.020NDHeptane 0.020NDHexachlorobutadiene 0.80NDHexane 0.020ND2-Hexanone (MBK) 0.80NDIsopropanol 0.020NDMethyl tert-Butyl Ether (MTBE) 0.20NDMethylene Chloride 0.020ND4-Methyl-2-pentanone (MIBK) 0.020NDNaphthalene 0.80NDPropene 0.020NDStyrene Page 8 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B314267 - TO-15 Prep Blank (B314267-BLK1)Prepared & Analyzed: 07/29/22 0.020ND1,1,2,2-Tetrachloroethane 0.020NDTetrachloroethylene 0.20NDTetrahydrofuran 0.020NDToluene 0.020ND1,2,4-Trichlorobenzene 0.020ND1,1,1-Trichloroethane 0.020ND1,1,2-Trichloroethane 0.020NDTrichloroethylene 0.080NDTrichlorofluoromethane (Freon 11) 0.080ND1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 0.020ND1,2,4-Trimethylbenzene 0.020ND1,3,5-Trimethylbenzene 0.40 L-03, V-05NDVinyl Acetate 0.020NDVinyl Chloride 0.040NDm&p-Xylene 0.020NDo-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)96.87.74 LCS (B314267-BS1)Prepared & Analyzed: 07/29/22 5.00 70-1301065.30Acetone 5.00 70-1301015.04Benzene 5.00 L-01, V-20, 70-1301638.15Benzyl chloride * 5.00 70-13099.34.96Bromodichloromethane 5.00 70-1301035.14Bromoform 5.00 70-1301075.34Bromomethane 5.00 70-1301075.351,3-Butadiene 5.00 70-13093.44.672-Butanone (MEK) 5.00 70-1301035.16Carbon Disulfide 5.00 70-1301015.05Carbon Tetrachloride 5.00 70-13099.74.98Chlorobenzene 5.00 70-1301075.34Chloroethane 5.00 70-1301065.28Chloroform 5.00 70-1301035.13Chloromethane 5.00 70-1301065.32Cyclohexane 5.00 70-1301025.11Dibromochloromethane 5.00 70-1301045.181,2-Dibromoethane (EDB) 5.00 70-1301105.501,2-Dichlorobenzene 5.00 70-1301105.521,3-Dichlorobenzene 5.00 70-1301266.321,4-Dichlorobenzene 5.00 70-1301075.36Dichlorodifluoromethane (Freon 12) 5.00 70-1301035.151,1-Dichloroethane 5.00 70-1301035.131,2-Dichloroethane 5.00 70-1301055.241,1-Dichloroethylene 5.00 70-1301025.12cis-1,2-Dichloroethylene 5.00 70-1301015.06trans-1,2-Dichloroethylene Page 9 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B314267 - TO-15 Prep LCS (B314267-BS1)Prepared & Analyzed: 07/29/22 5.00 70-13098.54.921,2-Dichloropropane 5.00 70-13099.84.99cis-1,3-Dichloropropene 5.00 70-1301065.29trans-1,3-Dichloropropene 5.00 70-13099.94.991,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 5.00 70-1301105.521,4-Dioxane 5.00 70-1301015.06Ethanol 5.00 70-1301065.28Ethyl Acetate 5.00 70-1301065.28Ethylbenzene 5.00 70-1301135.654-Ethyltoluene 5.00 70-1301015.03Heptane 5.00 70-13086.44.32Hexachlorobutadiene 5.00 70-1301055.23Hexane 5.00 70-1301065.322-Hexanone (MBK) 5.00 70-13093.14.66Isopropanol 5.00 70-1301236.13Methyl tert-Butyl Ether (MTBE) 5.00 70-13096.44.82Methylene Chloride 5.00 70-1301005.024-Methyl-2-pentanone (MIBK) 5.00 70-13098.14.91Naphthalene 5.00 70-1301055.25Propene 5.00 70-1301125.61Styrene 5.00 70-1301015.031,1,2,2-Tetrachloroethane 5.00 70-13097.94.89Tetrachloroethylene 5.00 70-1301055.25Tetrahydrofuran 5.00 70-1301045.18Toluene 5.00 V-3670-1301045.191,2,4-Trichlorobenzene 5.00 70-1301035.141,1,1-Trichloroethane 5.00 70-1301035.161,1,2-Trichloroethane 5.00 70-1301005.01Trichloroethylene 5.00 70-1301075.36Trichlorofluoromethane (Freon 11) 5.00 70-1301115.531,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 5.00 70-1301105.521,2,4-Trimethylbenzene 5.00 70-1301125.591,3,5-Trimethylbenzene 5.00 L-03, V-0570-13059.32.96Vinyl Acetate * 5.00 70-1301085.42Vinyl Chloride 10.0 70-13010410.4m&p-Xylene 5.00 70-1301085.41o-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1018.11 Page 10 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Note: Blank Subtraction is not performed unless otherwise noted *QC result is outside of established limits. †Wide recovery limits established for difficult compound. ‡Wide RPD limits established for difficult compound. #Data exceeded client recommended or regulatory level RL Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference LCS Laboratory Control Sample Laboratory Control SampleLCS Dup Duplicate Laboratory Control Sample MS Matrix Spike Sample MS Dup Duplicate Matrix Spike Sample REC Recovery QC Quality Control ppbv Parts per billion volume EPA United States Environmental Protection Agency Percent Recovery% REC ND Not Detected Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the calculation which have not been rounded. Not ApplicableN/A DL Detection Limit Not CalculatedNC LFB/LCS Lab Fortified Blank/Lab Control Sample ORP Oxidation-Reduction Potential Not dry weight correctedwet Percent weight% wt KilogramKg Gramg Milligrammg Microgramµg Nanogramng LiterL MillilitermL Microliter L Cubic Meterm3 Extractable Petroleum HydrocarbonsEPH Volatile Petroleum HydrocarbonsVPH Air Petroleum HydrocarbonsAPH Flame Ionization DetectorFID Photo Ionization DetectorPID FLAG/QUALIFIER SUMMARY Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated concentration (CLP J-Flag). J Laboratory fortified blank/laboratory control sample recovery outside of control limits. Data validation is not affected since all results are "not detected" for all samples in this batch for this compound and bias is on the high side. L-01 Laboratory fortified blank/laboratory control sample recovery is outside of control limits. Reported value for this compound is likely to be biased on the low side. L-03 Continuing calibration verification (CCV) did not meet method specifications and was biased on the low side for this compound. V-05 Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side. Data validation is not affected since sample result was "not detected" for this compound. V-20 Initial calibration verification (ICV) did not meet method specifications and was biased on the high side. Data validation is not affected since sample result was "not detected" for this compound. V-36 Page 11 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYST Thomas P. HniteckiTPH Raisa A. PetraitisRAP PDF Management StationSTATION Kerry K. McGeeKKM Brittany R. FiskBRF Page 12 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q Initial Cal Check (S069304-ICV1 )Lab File ID: K22A075019.D Analyzed: 03/16/22 23:55 Bromochloromethane (1)104138 2.987 104138 2.987 60 - 140100 0.0000 +/-0.50 1,4-Difluorobenzene (1)315817 3.584 315817 3.584 60 - 140100 0.0000 +/-0.50 Chlorobenzene-d5 (1)233658 5.159 233658 5.159 60 - 140100 0.0000 +/-0.50 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q LCS (B314267-BS1 )Lab File ID: K22A210005.D Analyzed: 07/29/22 10:24 Bromochloromethane (1)116140 3.001 102745 2.987 60 - 140113 0.0140 +/-0.50 1,4-Difluorobenzene (1)355389 3.588 303801 3.579 60 - 140117 0.0090 +/-0.50 Chlorobenzene-d5 (1)260279 5.163 223280 5.159 60 - 140117 0.0040 +/-0.50 Blank (B314267-BLK1 )Lab File ID: K22A210008.D Analyzed: 07/29/22 12:05 Bromochloromethane (1)115126 3.001 102745 2.987 60 - 140112 0.0140 +/-0.50 1,4-Difluorobenzene (1)339293 3.588 303801 3.579 60 - 140112 0.0090 +/-0.50 Chlorobenzene-d5 (1)247140 5.163 223280 5.159 60 - 140111 0.0040 +/-0.50 Calibration Check (S074611-CCV1 )Lab File ID: K22A210009.D Analyzed: 07/29/22 14:03 Bromochloromethane (1)115438 3.001 115438 3.001 60 - 140100 0.0000 +/-0.50 1,4-Difluorobenzene (1)351715 3.588 351715 3.588 60 - 140100 0.0000 +/-0.50 Chlorobenzene-d5 (1)262458 5.163 262458 5.163 60 - 140100 0.0000 +/-0.50 SS-22 (22G1362-01 )Lab File ID: K22A210019.D Analyzed: 07/29/22 19:35 Bromochloromethane (1)115243 3.001 115438 3.001 60 - 140100 0.0000 +/-0.50 1,4-Difluorobenzene (1)338983 3.588 351715 3.588 60 - 14096 0.0000 +/-0.50 Chlorobenzene-d5 (1)256140 5.163 262458 5.163 60 - 14098 0.0000 +/-0.50 Page 13 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CONTINUING CALIBRATION CHECK EPA TO-15 S074611-CCV1 COMPOUND TYPE CCV MIN (#)CCV LIMIT (#)CCV ICAL CONC. (ppbv)% DIFF / DRIFTRESPONSE FACTOR STD 1.029457A 2.8 305.14 1.0015045.00Acetone 0.6490664A 2.4 305.12 0.6337045.00Benzene 0.7814248A 76.7 *308.84 0.44210815.00Benzyl chloride 0.453681A 1.2 305.06 0.44847425.00Bromodichloromethane 0.5567916A 4.8 305.24 0.53136085.00Bromoform 0.6188049A 8.9 305.44 0.568465.00Bromomethane 0.5596355A 13.3 305.66 0.49412945.001,3-Butadiene 1.038147A -9.2 304.54 1.1433395.002-Butanone (MEK) 2.145581A 2.1 305.11 2.1010975.00Carbon Disulfide 0.371196A 3.6 305.18 0.35837935.00Carbon Tetrachloride 0.7417507A 1.5 305.08 0.73073575.00Chlorobenzene 0.4054679A 8.7 305.44 0.37289695.00Chloroethane 1.306371A 8.3 305.42 1.2059735.00Chloroform 0.6273705A 7.4 305.37 0.58435035.00Chloromethane 0.2626854A 6.2 305.31 0.24743965.00Cyclohexane 0.5521828A 2.9 305.15 0.53656275.00Dibromochloromethane 0.4996579A 6.4 305.32 0.46964285.001,2-Dibromoethane (EDB) 0.6205641A 14.4 305.72 0.54254115.001,2-Dichlorobenzene 0.6568243A 17.8 305.89 0.55776855.001,3-Dichlorobenzene 0.6113649A 26.3 306.31 0.48416785.001,4-Dichlorobenzene 1.548662A 7.7 305.39 1.4373685.00Dichlorodifluoromethane (Freon 12) 1.021418A 2.8 305.14 0.99331175.001,1-Dichloroethane 0.786209A 3.4 305.17 0.76049545.001,2-Dichloroethane 1.07751A 5.1 305.25 1.0254175.001,1-Dichloroethylene 0.8669034A 6.1 305.30 0.81743615.00cis-1,2-Dichloroethylene 0.8445746A 2.2 305.11 0.82655715.00trans-1,2-Dichloroethylene 0.2485831A -1.6 304.92 0.25255515.001,2-Dichloropropane 0.4239342A 4.9 305.24 0.40422685.00cis-1,3-Dichloropropene 0.3095688A 9.7 305.48 0.28217545.00trans-1,3-Dichloropropene 1.695774A 7.9 305.40 1.5711765.001,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 0.1323435A 5.7 305.28 0.12523265.001,4-Dioxane 0.2457423A 4.7 305.23 0.23481145.00Ethanol 0.2116738A 17.7 305.89 0.17977625.00Ethyl Acetate 1.237483A 6.1 305.31 1.1661035.00Ethylbenzene 1.244408A 14.0 305.70 1.0915375.004-Ethyltoluene 0.2554159A 7.7 305.39 0.23709755.00Heptane 0.3735455A -2.9 304.86 0.38469915.00Hexachlorobutadiene 0.6651536L 5.5 305.27 0.61173145.00Hexane Page 14 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CONTINUING CALIBRATION CHECK EPA TO-15 S074611-CCV1 COMPOUND TYPE CCV MIN (#)CCV LIMIT (#)CCV ICAL CONC. (ppbv)% DIFF / DRIFTRESPONSE FACTOR STD 0.5278406A -0.3 304.99 0.52934325.002-Hexanone (MBK) 1.376628A 11.6 305.58 1.2331515.00Isopropanol 1.748125A 24.5 306.23 1.4039195.00Methyl tert-Butyl Ether (MTBE) 0.7755782A 0.08 305.00 0.77496645.00Methylene Chloride 9.325278E-02A -10.1 304.50 0.10367325.004-Methyl-2-pentanone (MIBK) 0.8703442A -4.0 304.80 0.90672085.00Naphthalene 0.5231137A 9.9 305.50 0.47577555.00Propene 0.7180974A 15.9 305.80 0.61955725.00Styrene 0.7917823A 3.5 305.18 0.76495215.001,1,2,2-Tetrachloroethane 0.3994544A -0.8 304.96 0.40254575.00Tetrachloroethylene 0.6634488A 7.1 305.36 0.61923625.00Tetrahydrofuran 0.9923416A 3.5 305.18 0.95887535.00Toluene 0.306481A 6.1 305.30 0.28885585.001,2,4-Trichlorobenzene 0.4299754A 7.4 305.37 0.40050755.001,1,1-Trichloroethane 0.3402541A 1.9 305.09 0.3339565.001,1,2-Trichloroethane 0.2753548A 3.2 305.16 0.26692125.00Trichloroethylene 1.486942A 9.1 305.46 1.3627485.00Trichlorofluoromethane (Freon 11) 1.444031A 10.1 305.51 1.3112435.001,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 1.04789A 15.1 305.76 0.91012065.001,2,4-Trimethylbenzene 1.07675A 15.7 305.78 0.93057165.001,3,5-Trimethylbenzene 0.9663923A -33.7 *303.32 1.4567695.00Vinyl Acetate 0.7256259A 8.3 305.42 0.67006745.00Vinyl Chloride 1.160628A 17.2 3011.7 0.990172810.0m&p-Xylene 0.9859284A 9.5 305.47 0.90063785.00o-Xylene * Values outside of QC limits # Column to be used to flag Response Factor and %Diff/Drift values with an asterisk Page 15 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report EPA TO-15 in Air AIHA,NY,ME,NHAcetone AIHA,FL,NJ,NY,ME,NH,VABenzene AIHA,FL,NJ,NY,ME,NH,VABenzyl chloride AIHA,NJ,NY,ME,NH,VABromodichloromethane AIHA,NJ,NY,ME,NH,VABromoform AIHA,FL,NJ,NY,ME,NHBromomethane AIHA,NJ,NY,ME,NH,VA1,3-Butadiene AIHA,FL,NJ,NY,ME,NH,VA2-Butanone (MEK) AIHA,NJ,NY,ME,NH,VACarbon Disulfide AIHA,FL,NJ,NY,ME,NH,VACarbon Tetrachloride AIHA,FL,NJ,NY,ME,NH,VAChlorobenzene AIHA,FL,NJ,NY,ME,NH,VAChloroethane AIHA,FL,NJ,NY,ME,NH,VAChloroform AIHA,FL,NJ,NY,ME,NH,VAChloromethane AIHA,NJ,NY,ME,NH,VACyclohexane AIHA,NY,ME,NHDibromochloromethane AIHA,NJ,NY,ME,NH1,2-Dibromoethane (EDB) AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichlorobenzene AIHA,NJ,NY,ME,NH1,3-Dichlorobenzene AIHA,FL,NJ,NY,ME,NH,VA1,4-Dichlorobenzene AIHA,NY,ME,NHDichlorodifluoromethane (Freon 12) AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethylene AIHA,FL,NY,ME,NH,VAcis-1,2-Dichloroethylene AIHA,NJ,NY,ME,NH,VAtrans-1,2-Dichloroethylene AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichloropropane AIHA,FL,NJ,NY,ME,NH,VAcis-1,3-Dichloropropene AIHA,NY,ME,NHtrans-1,3-Dichloropropene AIHA,NJ,NY,ME,NH,VA1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) AIHA,NJ,NY,ME,NH,VA1,4-Dioxane AIHAEthanol AIHAEthyl Acetate AIHA,FL,NJ,NY,ME,NH,VAEthylbenzene AIHA,NJ4-Ethyltoluene AIHA,NJ,NY,ME,NH,VAHeptane AIHA,NJ,NY,ME,NH,VAHexachlorobutadiene AIHA,FL,NJ,NY,ME,NH,VAHexane AIHA2-Hexanone (MBK) AIHA,NY,ME,NHIsopropanol AIHA,FL,NJ,NY,ME,NH,VAMethyl tert-Butyl Ether (MTBE) AIHA,FL,NJ,NY,ME,NH,VAMethylene Chloride AIHA,FL,NJ,NY,ME,NH4-Methyl-2-pentanone (MIBK) NY,ME,NHNaphthalene AIHAPropene AIHA,FL,NJ,NY,ME,NH,VAStyrene AIHA,FL,NJ,NY,ME,NH,VA1,1,2,2-Tetrachloroethane Page 16 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report EPA TO-15 in Air AIHA,FL,NJ,NY,ME,NH,VATetrachloroethylene AIHATetrahydrofuran AIHA,FL,NJ,NY,ME,NH,VAToluene AIHA,NJ,NY,ME,NH,VA1,2,4-Trichlorobenzene AIHA,FL,NJ,NY,ME,NH,VA1,1,1-Trichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1,2-Trichloroethane AIHA,FL,NJ,NY,ME,NH,VATrichloroethylene AIHA,NY,ME,NHTrichlorofluoromethane (Freon 11) AIHA,NJ,NY,ME,NH,VA1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) AIHA,NJ,NY,ME,NH1,2,4-Trimethylbenzene AIHA,NJ,NY,ME,NH1,3,5-Trimethylbenzene AIHA,FL,NJ,NY,ME,NH,VAVinyl Acetate AIHA,FL,NJ,NY,ME,NH,VAVinyl Chloride AIHA,FL,NJ,NY,ME,NH,VAm&p-Xylene AIHA,FL,NJ,NY,ME,NH,VAo-Xylene Con-Test, a Pace Environmental Laboratory, operates under the following certifications and accreditations: Code Description Number Expires 100033AIHA-LAP, LLC - ISO 17025:2017AIHA 03/1/2024 M-MA100Massachusetts DEPMA 06/30/2023 PH-0165Connecticut Department of Public HealthCT 12/31/2022 10899 NELAPNew York State Department of HealthNY 04/1/2023 2516 NELAPNew Hampshire Environmental LabNH 02/5/2023 LAO00373Rhode Island Department of HealthRI 12/30/2022 652North Carolina Div. of Water QualityNC 12/31/2022 MA007 NELAPNew Jersey DEPNJ 06/30/2023 E871027 NELAPFlorida Department of HealthFL 06/30/2023 LL720741Vermont Department of Health Lead LaboratoryVT 07/30/2023 VT-255716Vermont Department of Health Drinking WaterVT-DW 06/12/2023 MA00100State of MaineME 06/9/2023 460217Commonwealth of VirginiaVA 12/14/2022 2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2022 25703North Carolina Department of Health and Human ServicesNC-DW 07/31/2023 68-05812Commonwealth of Pennsylvania DEPPA 06/30/2023 9100Dept. of Env, Great Lakes, and EnergyMI 09/6/2022 Page 17 of 20 Page 18 of 20 Page 19 of 20 Page 20 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 August 4, 2022 Justin Ballard Hart & Hickman - Charlotte, NC 2923 South Tryon Street, Suite 100 Charlotte, NC 28203 Project Location: 1900 Continental Blvd, Charlotte, NC Client Job Number: Project Number: SSP-001 Laboratory Work Order Number: 22G1209 Enclosed are results of analyses for samples as received by the laboratory on July 22, 2022. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kerry K. McGee Project Manager QA Officer Katherine Allen Laboratory Manager Daren Damboragian Page 1 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL SUMMARY The results of analyses performed on the following samples submitted to Con-Test, a Pace Analytical Laboratory, are found in this report. PROJECT LOCATION: PURCHASE ORDER NUMBER: PROJECT NUMBER: REPORT DATE: WORK ORDER NUMBER: FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB Page 2 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CASE NARRATIVE SUMMARY All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report. The results of analyses reported only relate to samples submitted to Con-Test, a Pace Analytical Laboratory, for testing. I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. Lisa A. Worthington Technical Representative Page 3 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1209Sample Description/Location: Field Sample #: IAS-1 Sample ID: 22G1209-01 Sample Matrix: Indoor air Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -6 Receipt Vacuum(in Hg): -7.7 Sampled: 7/18/2022 16:32 Canister ID: 1137 Flow Controller ID: 3220 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 8 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 5.4 1.4 8/1/22 15:44 BRF13 0.7023.30.85 2.0 Benzene 0.073 0.035 8/1/22 15:44 BRF0.23 0.7020.110.027 0.085 Benzyl chloride ND 0.035 8/1/22 15:44 BRFND0.7020.180.031 0.16 Bromodichloromethane ND 0.035 8/1/22 15:44 BRFND0.7020.240.025 0.16 Bromoform ND 0.035 8/1/22 15:44 BRFND0.7020.360.024 0.25 Bromomethane ND 0.035 8/1/22 15:44 BRFND0.7020.140.023 0.091 1,3-Butadiene ND 0.035 8/1/22 15:44 BRFND0.7020.0780.029 0.065 2-Butanone (MEK)5.0 1.4 8/1/22 15:44 BRF15 0.7024.10.37 1.1 Carbon Disulfide 0.12 0.35 8/1/22 15:44 BRFJ0.36 0.7021.10.032 0.10 Carbon Tetrachloride 0.050 0.035 8/1/22 15:44 BRF0.31 0.7020.220.028 0.18 Chlorobenzene ND 0.035 8/1/22 15:44 BRFND0.7020.160.023 0.11 Chloroethane ND 0.035 8/1/22 15:44 BRFND0.7020.0930.031 0.082 Chloroform 0.035 0.035 8/1/22 15:44 BRF0.17 0.7020.170.033 0.16 Chloromethane 0.72 0.070 8/1/22 15:44 BRF1.5 0.7020.140.028 0.058 Cyclohexane ND 0.035 8/1/22 15:44 BRFND0.7020.120.021 0.073 Dibromochloromethane ND 0.035 8/1/22 15:44 BRFND0.7020.300.023 0.20 1,2-Dibromoethane (EDB)ND 0.035 8/1/22 15:44 BRFND0.7020.270.021 0.16 1,2-Dichlorobenzene ND 0.035 8/1/22 15:44 BRFND0.7020.210.020 0.12 1,3-Dichlorobenzene ND 0.035 8/1/22 15:44 BRFND0.7020.210.019 0.12 1,4-Dichlorobenzene ND 0.035 8/1/22 15:44 BRFND0.7020.210.023 0.14 Dichlorodifluoromethane (Freon 12)0.21 0.035 8/1/22 15:44 BRF1.1 0.7020.170.034 0.17 1,1-Dichloroethane ND 0.035 8/1/22 15:44 BRFND0.7020.140.031 0.12 1,2-Dichloroethane 0.10 0.035 8/1/22 15:44 BRF0.40 0.7020.140.032 0.13 1,1-Dichloroethylene ND 0.035 8/1/22 15:44 BRFND0.7020.140.027 0.11 cis-1,2-Dichloroethylene ND 0.035 8/1/22 15:44 BRFND0.7020.140.026 0.10 trans-1,2-Dichloroethylene ND 0.035 8/1/22 15:44 BRFND0.7020.140.028 0.11 1,2-Dichloropropane ND 0.035 8/1/22 15:44 BRFND0.7020.160.019 0.088 cis-1,3-Dichloropropene ND 0.035 8/1/22 15:44 BRFND0.7020.160.018 0.082 trans-1,3-Dichloropropene ND 0.035 8/1/22 15:44 BRFND0.7020.160.018 0.082 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.035 8/1/22 15:44 BRFND0.7020.250.035 0.24 1,4-Dioxane ND 0.35 8/1/22 15:44 BRFND0.7021.30.029 0.10 Ethanol 22 1.4 8/1/22 15:44 BRF42 0.7022.60.62 1.2 Ethyl Acetate 2.3 0.35 8/1/22 15:44 BRF8.3 0.7021.30.18 0.64 Ethylbenzene 1.3 0.035 8/1/22 15:44 BRF5.7 0.7020.150.020 0.089 4-Ethyltoluene 0.022 0.035 8/1/22 15:44 BRFJ0.11 0.7020.170.022 0.11 Heptane 0.097 0.035 8/1/22 15:44 BRF0.40 0.7020.140.022 0.092 Hexachlorobutadiene ND 0.035 8/1/22 15:44 BRFND0.7020.370.029 0.31 Hexane 0.51 1.4 8/1/22 15:44 BRFJ1.8 0.7024.90.18 0.64 2-Hexanone (MBK)ND 0.035 8/1/22 15:44 BRFND0.7020.140.018 0.072 Isopropanol 2.1 1.4 8/1/22 15:44 BRF5.1 0.7023.40.24 0.60 Methyl tert-Butyl Ether (MTBE)ND 0.035 8/1/22 15:44 BRFND0.7020.130.027 0.098 Methylene Chloride 0.21 0.35 8/1/22 15:44 BRFJ0.73 0.7021.20.16 0.57 4-Methyl-2-pentanone (MIBK)0.12 0.035 8/1/22 15:44 BRF0.49 0.7020.140.019 0.077 Naphthalene 0.055 0.035 8/1/22 15:44 BRF0.29 0.7020.180.026 0.14 Propene ND 1.4 8/1/22 15:44 BRFND0.7022.40.31 0.53 Styrene 2.4 0.035 8/1/22 15:44 BRF10 0.7020.150.018 0.079 1,1,2,2-Tetrachloroethane ND 0.035 8/1/22 15:44 BRFND0.7020.240.019 0.13 Page 4 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1209Sample Description/Location: Field Sample #: IAS-1 Sample ID: 22G1209-01 Sample Matrix: Indoor air Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -6 Receipt Vacuum(in Hg): -7.7 Sampled: 7/18/2022 16:32 Canister ID: 1137 Flow Controller ID: 3220 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 8 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene ND 0.035 8/1/22 15:44 BRFND0.7020.240.027 0.18 Tetrahydrofuran ND 0.35 8/1/22 15:44 BRFND0.7021.00.058 0.17 Toluene 7.2 0.035 8/1/22 15:44 BRF27 0.7020.130.020 0.076 1,2,4-Trichlorobenzene ND 0.035 8/1/22 15:44 BRFND0.7020.260.033 0.24 1,1,1-Trichloroethane ND 0.035 8/1/22 15:44 BRFND0.7020.190.028 0.15 1,1,2-Trichloroethane ND 0.035 8/1/22 15:44 BRFND0.7020.190.025 0.13 Trichloroethylene 0.025 0.035 8/1/22 15:44 BRFJ0.14 0.7020.190.024 0.13 Trichlorofluoromethane (Freon 11)1.7 0.14 8/1/22 15:44 BRF9.5 0.7020.790.041 0.23 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)0.066 0.14 8/1/22 15:44 BRFJ0.51 0.7021.10.039 0.30 1,2,4-Trimethylbenzene 0.058 0.035 8/1/22 15:44 BRF0.28 0.7020.170.016 0.076 1,3,5-Trimethylbenzene 0.020 0.035 8/1/22 15:44 BRFJ0.10 0.7020.170.019 0.091 Vinyl Acetate ND 0.70 8/1/22 15:44 BRFND0.7022.50.19 0.66 Vinyl Chloride ND 0.035 8/1/22 15:44 BRFND0.7020.0900.032 0.081 m&p-Xylene 3.9 0.070 8/1/22 15:44 BRF17 0.7020.300.039 0.17 o-Xylene 1.6 0.035 8/1/22 15:44 BRF6.9 0.7020.150.018 0.078 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)106 8/1/22 15:4470-130 Page 5 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1209Sample Description/Location: Field Sample #: IAS-2 Sample ID: 22G1209-02 Sample Matrix: Indoor air Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -7 Receipt Vacuum(in Hg): -9.2 Sampled: 7/18/2022 16:35 Canister ID: 1998 Flow Controller ID: 3588 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 8 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 6.1 1.4 8/1/22 16:31 BRF14 0.7023.30.85 2.0 Benzene 0.084 0.035 8/1/22 16:31 BRF0.27 0.7020.110.027 0.085 Benzyl chloride ND 0.035 8/1/22 16:31 BRFND0.7020.180.031 0.16 Bromodichloromethane ND 0.035 8/1/22 16:31 BRFND0.7020.240.025 0.16 Bromoform ND 0.035 8/1/22 16:31 BRFND0.7020.360.024 0.25 Bromomethane 0.070 0.035 8/1/22 16:31 BRF0.27 0.7020.140.023 0.091 1,3-Butadiene ND 0.035 8/1/22 16:31 BRFND0.7020.0780.029 0.065 2-Butanone (MEK)3.0 1.4 8/1/22 16:31 BRF9.0 0.7024.10.37 1.1 Carbon Disulfide 0.074 0.35 8/1/22 16:31 BRFJ0.23 0.7021.10.032 0.10 Carbon Tetrachloride 0.055 0.035 8/1/22 16:31 BRF0.34 0.7020.220.028 0.18 Chlorobenzene ND 0.035 8/1/22 16:31 BRFND0.7020.160.023 0.11 Chloroethane ND 0.035 8/1/22 16:31 BRFND0.7020.0930.031 0.082 Chloroform ND 0.035 8/1/22 16:31 BRFND0.7020.170.033 0.16 Chloromethane 0.71 0.070 8/1/22 16:31 BRF1.5 0.7020.140.028 0.058 Cyclohexane ND 0.035 8/1/22 16:31 BRFND0.7020.120.021 0.073 Dibromochloromethane ND 0.035 8/1/22 16:31 BRFND0.7020.300.023 0.20 1,2-Dibromoethane (EDB)ND 0.035 8/1/22 16:31 BRFND0.7020.270.021 0.16 1,2-Dichlorobenzene ND 0.035 8/1/22 16:31 BRFND0.7020.210.020 0.12 1,3-Dichlorobenzene ND 0.035 8/1/22 16:31 BRFND0.7020.210.019 0.12 1,4-Dichlorobenzene ND 0.035 8/1/22 16:31 BRFND0.7020.210.023 0.14 Dichlorodifluoromethane (Freon 12)0.20 0.035 8/1/22 16:31 BRF0.96 0.7020.170.034 0.17 1,1-Dichloroethane ND 0.035 8/1/22 16:31 BRFND0.7020.140.031 0.12 1,2-Dichloroethane ND 0.035 8/1/22 16:31 BRFND0.7020.140.032 0.13 1,1-Dichloroethylene ND 0.035 8/1/22 16:31 BRFND0.7020.140.027 0.11 cis-1,2-Dichloroethylene ND 0.035 8/1/22 16:31 BRFND0.7020.140.026 0.10 trans-1,2-Dichloroethylene ND 0.035 8/1/22 16:31 BRFND0.7020.140.028 0.11 1,2-Dichloropropane ND 0.035 8/1/22 16:31 BRFND0.7020.160.019 0.088 cis-1,3-Dichloropropene ND 0.035 8/1/22 16:31 BRFND0.7020.160.018 0.082 trans-1,3-Dichloropropene ND 0.035 8/1/22 16:31 BRFND0.7020.160.018 0.082 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.035 8/1/22 16:31 BRFND0.7020.250.035 0.24 1,4-Dioxane ND 0.35 8/1/22 16:31 BRFND0.7021.30.029 0.10 Ethanol 18 1.4 8/1/22 16:31 BRF33 0.7022.60.62 1.2 Ethyl Acetate 0.83 0.35 8/1/22 16:31 BRF3.0 0.7021.30.18 0.64 Ethylbenzene 0.72 0.035 8/1/22 16:31 BRF3.1 0.7020.150.020 0.089 4-Ethyltoluene ND 0.035 8/1/22 16:31 BRFND0.7020.170.022 0.11 Heptane 0.076 0.035 8/1/22 16:31 BRF0.31 0.7020.140.022 0.092 Hexachlorobutadiene ND 0.035 8/1/22 16:31 BRFND0.7020.370.029 0.31 Hexane 0.44 1.4 8/1/22 16:31 BRFJ1.6 0.7024.90.18 0.64 2-Hexanone (MBK)ND 0.035 8/1/22 16:31 BRFND0.7020.140.018 0.072 Isopropanol 1.3 1.4 8/1/22 16:31 BRFJ3.1 0.7023.40.24 0.60 Methyl tert-Butyl Ether (MTBE)ND 0.035 8/1/22 16:31 BRFND0.7020.130.027 0.098 Methylene Chloride ND 0.35 8/1/22 16:31 BRFND0.7021.20.16 0.57 4-Methyl-2-pentanone (MIBK)0.076 0.035 8/1/22 16:31 BRF0.31 0.7020.140.019 0.077 Naphthalene 0.050 0.035 8/1/22 16:31 BRF0.26 0.7020.180.026 0.14 Propene ND 1.4 8/1/22 16:31 BRFND0.7022.40.31 0.53 Styrene 1.2 0.035 8/1/22 16:31 BRF5.2 0.7020.150.018 0.079 1,1,2,2-Tetrachloroethane ND 0.035 8/1/22 16:31 BRFND0.7020.240.019 0.13 Page 6 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1209Sample Description/Location: Field Sample #: IAS-2 Sample ID: 22G1209-02 Sample Matrix: Indoor air Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -7 Receipt Vacuum(in Hg): -9.2 Sampled: 7/18/2022 16:35 Canister ID: 1998 Flow Controller ID: 3588 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 8 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene ND 0.035 8/1/22 16:31 BRFND0.7020.240.027 0.18 Tetrahydrofuran ND 0.35 8/1/22 16:31 BRFND0.7021.00.058 0.17 Toluene 4.0 0.035 8/1/22 16:31 BRF15 0.7020.130.020 0.076 1,2,4-Trichlorobenzene ND 0.035 8/1/22 16:31 BRFND0.7020.260.033 0.24 1,1,1-Trichloroethane ND 0.035 8/1/22 16:31 BRFND0.7020.190.028 0.15 1,1,2-Trichloroethane ND 0.035 8/1/22 16:31 BRFND0.7020.190.025 0.13 Trichloroethylene ND 0.035 8/1/22 16:31 BRFND0.7020.190.024 0.13 Trichlorofluoromethane (Freon 11)1.1 0.14 8/1/22 16:31 BRF5.9 0.7020.790.041 0.23 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)0.066 0.14 8/1/22 16:31 BRFJ0.51 0.7021.10.039 0.30 1,2,4-Trimethylbenzene 0.039 0.035 8/1/22 16:31 BRF0.19 0.7020.170.016 0.076 1,3,5-Trimethylbenzene ND 0.035 8/1/22 16:31 BRFND0.7020.170.019 0.091 Vinyl Acetate ND 0.70 8/1/22 16:31 BRFND0.7022.50.19 0.66 Vinyl Chloride ND 0.035 8/1/22 16:31 BRFND0.7020.0900.032 0.081 m&p-Xylene 2.2 0.070 8/1/22 16:31 BRF9.3 0.7020.300.039 0.17 o-Xylene 0.90 0.035 8/1/22 16:31 BRF3.9 0.7020.150.018 0.078 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)104 8/1/22 16:3170-130 Page 7 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1209Sample Description/Location: Field Sample #: IAS-3 Sample ID: 22G1209-03 Sample Matrix: Indoor air Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -5.5 Receipt Vacuum(in Hg): -6 Sampled: 7/18/2022 16:50 Canister ID: 1863 Flow Controller ID: 3235 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 8 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 14 1.4 8/1/22 18:07 BRF32 0.7023.30.85 2.0 Benzene 0.071 0.035 8/1/22 18:07 BRF0.23 0.7020.110.027 0.085 Benzyl chloride ND 0.035 8/1/22 18:07 BRFND0.7020.180.031 0.16 Bromodichloromethane ND 0.035 8/1/22 18:07 BRFND0.7020.240.025 0.16 Bromoform ND 0.035 8/1/22 18:07 BRFND0.7020.360.024 0.25 Bromomethane ND 0.035 8/1/22 18:07 BRFND0.7020.140.023 0.091 1,3-Butadiene ND 0.035 8/1/22 18:07 BRFND0.7020.0780.029 0.065 2-Butanone (MEK)0.81 1.4 8/1/22 18:07 BRFJ2.4 0.7024.10.37 1.1 Carbon Disulfide 0.043 0.35 8/1/22 18:07 BRFJ0.13 0.7021.10.032 0.10 Carbon Tetrachloride 0.054 0.035 8/1/22 18:07 BRF0.34 0.7020.220.028 0.18 Chlorobenzene ND 0.035 8/1/22 18:07 BRFND0.7020.160.023 0.11 Chloroethane ND 0.035 8/1/22 18:07 BRFND0.7020.0930.031 0.082 Chloroform 0.075 0.035 8/1/22 18:07 BRF0.37 0.7020.170.033 0.16 Chloromethane 0.79 0.070 8/1/22 18:07 BRF1.6 0.7020.140.028 0.058 Cyclohexane ND 0.035 8/1/22 18:07 BRFND0.7020.120.021 0.073 Dibromochloromethane ND 0.035 8/1/22 18:07 BRFND0.7020.300.023 0.20 1,2-Dibromoethane (EDB)ND 0.035 8/1/22 18:07 BRFND0.7020.270.021 0.16 1,2-Dichlorobenzene ND 0.035 8/1/22 18:07 BRFND0.7020.210.020 0.12 1,3-Dichlorobenzene ND 0.035 8/1/22 18:07 BRFND0.7020.210.019 0.12 1,4-Dichlorobenzene ND 0.035 8/1/22 18:07 BRFND0.7020.210.023 0.14 Dichlorodifluoromethane (Freon 12)0.24 0.035 8/1/22 18:07 BRF1.2 0.7020.170.034 0.17 1,1-Dichloroethane ND 0.035 8/1/22 18:07 BRFND0.7020.140.031 0.12 1,2-Dichloroethane ND 0.035 8/1/22 18:07 BRFND0.7020.140.032 0.13 1,1-Dichloroethylene ND 0.035 8/1/22 18:07 BRFND0.7020.140.027 0.11 cis-1,2-Dichloroethylene ND 0.035 8/1/22 18:07 BRFND0.7020.140.026 0.10 trans-1,2-Dichloroethylene ND 0.035 8/1/22 18:07 BRFND0.7020.140.028 0.11 1,2-Dichloropropane ND 0.035 8/1/22 18:07 BRFND0.7020.160.019 0.088 cis-1,3-Dichloropropene ND 0.035 8/1/22 18:07 BRFND0.7020.160.018 0.082 trans-1,3-Dichloropropene ND 0.035 8/1/22 18:07 BRFND0.7020.160.018 0.082 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.035 8/1/22 18:07 BRFND0.7020.250.035 0.24 1,4-Dioxane ND 0.35 8/1/22 18:07 BRFND0.7021.30.029 0.10 Ethanol 150 20 8/2/22 7:03 BRF290 10388.8 17 Ethyl Acetate 2.0 0.35 8/1/22 18:07 BRF7.3 0.7021.30.18 0.64 Ethylbenzene 0.090 0.035 8/1/22 18:07 BRF0.39 0.7020.150.020 0.089 4-Ethyltoluene ND 0.035 8/1/22 18:07 BRFND0.7020.170.022 0.11 Heptane 0.070 0.035 8/1/22 18:07 BRF0.29 0.7020.140.022 0.092 Hexachlorobutadiene ND 0.035 8/1/22 18:07 BRFND0.7020.370.029 0.31 Hexane 0.35 1.4 8/1/22 18:07 BRFJ1.2 0.7024.90.18 0.64 2-Hexanone (MBK)ND 0.035 8/1/22 18:07 BRFND0.7020.140.018 0.072 Isopropanol 12 1.4 8/1/22 18:07 BRF30 0.7023.40.24 0.60 Methyl tert-Butyl Ether (MTBE)ND 0.035 8/1/22 18:07 BRFND0.7020.130.027 0.098 Methylene Chloride ND 0.35 8/1/22 18:07 BRFND0.7021.20.16 0.57 4-Methyl-2-pentanone (MIBK)0.046 0.035 8/1/22 18:07 BRF0.19 0.7020.140.019 0.077 Naphthalene 0.049 0.035 8/1/22 18:07 BRF0.26 0.7020.180.026 0.14 Propene ND 1.4 8/1/22 18:07 BRFND0.7022.40.31 0.53 Styrene 0.078 0.035 8/1/22 18:07 BRF0.33 0.7020.150.018 0.079 1,1,2,2-Tetrachloroethane ND 0.035 8/1/22 18:07 BRFND0.7020.240.019 0.13 Page 8 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1209Sample Description/Location: Field Sample #: IAS-3 Sample ID: 22G1209-03 Sample Matrix: Indoor air Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -5.5 Receipt Vacuum(in Hg): -6 Sampled: 7/18/2022 16:50 Canister ID: 1863 Flow Controller ID: 3235 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 8 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene ND 0.035 8/1/22 18:07 BRFND0.7020.240.027 0.18 Tetrahydrofuran 0.12 0.35 8/1/22 18:07 BRFJ0.34 0.7021.00.058 0.17 Toluene 1.9 0.035 8/1/22 18:07 BRF7.3 0.7020.130.020 0.076 1,2,4-Trichlorobenzene ND 0.035 8/1/22 18:07 BRFND0.7020.260.033 0.24 1,1,1-Trichloroethane ND 0.035 8/1/22 18:07 BRFND0.7020.190.028 0.15 1,1,2-Trichloroethane ND 0.035 8/1/22 18:07 BRFND0.7020.190.025 0.13 Trichloroethylene ND 0.035 8/1/22 18:07 BRFND0.7020.190.024 0.13 Trichlorofluoromethane (Freon 11)0.28 0.14 8/1/22 18:07 BRF1.6 0.7020.790.041 0.23 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)0.066 0.14 8/1/22 18:07 BRFJ0.51 0.7021.10.039 0.30 1,2,4-Trimethylbenzene 0.053 0.035 8/1/22 18:07 BRF0.26 0.7020.170.016 0.076 1,3,5-Trimethylbenzene ND 0.035 8/1/22 18:07 BRFND0.7020.170.019 0.091 Vinyl Acetate ND 0.70 8/1/22 18:07 BRFND0.7022.50.19 0.66 Vinyl Chloride ND 0.035 8/1/22 18:07 BRFND0.7020.0900.032 0.081 m&p-Xylene 0.33 0.070 8/1/22 18:07 BRF1.4 0.7020.300.039 0.17 o-Xylene 0.12 0.035 8/1/22 18:07 BRF0.51 0.7020.150.018 0.078 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)105 8/2/22 7:0370-130 4-Bromofluorobenzene (1)104 8/1/22 18:0770-130 Page 9 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1209Sample Description/Location: Field Sample #: IAS-4 Sample ID: 22G1209-04 Sample Matrix: Indoor air Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -7 Receipt Vacuum(in Hg): -8.5 Sampled: 7/18/2022 17:05 Canister ID: 2144 Flow Controller ID: 3577 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 8 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 48 4.0 8/2/22 7:45 BRF110 29.52.4 5.7 Benzene 0.15 0.035 8/1/22 18:54 BRF0.47 0.7020.110.027 0.085 Benzyl chloride ND 0.035 8/1/22 18:54 BRFND0.7020.180.031 0.16 Bromodichloromethane ND 0.035 8/1/22 18:54 BRFND0.7020.240.025 0.16 Bromoform ND 0.035 8/1/22 18:54 BRFND0.7020.360.024 0.25 Bromomethane ND 0.035 8/1/22 18:54 BRFND0.7020.140.023 0.091 1,3-Butadiene ND 0.035 8/1/22 18:54 BRFND0.7020.0780.029 0.065 2-Butanone (MEK)2.6 1.4 8/1/22 18:54 BRF7.7 0.7024.10.37 1.1 Carbon Disulfide 0.10 0.35 8/1/22 18:54 BRFJ0.31 0.7021.10.032 0.10 Carbon Tetrachloride 0.048 0.035 8/1/22 18:54 BRF0.30 0.7020.220.028 0.18 Chlorobenzene ND 0.035 8/1/22 18:54 BRFND0.7020.160.023 0.11 Chloroethane ND 0.035 8/1/22 18:54 BRFND0.7020.0930.031 0.082 Chloroform ND 0.035 8/1/22 18:54 BRFND0.7020.170.033 0.16 Chloromethane 0.96 0.070 8/1/22 18:54 BRF2.0 0.7020.140.028 0.058 Cyclohexane ND 0.035 8/1/22 18:54 BRFND0.7020.120.021 0.073 Dibromochloromethane ND 0.035 8/1/22 18:54 BRFND0.7020.300.023 0.20 1,2-Dibromoethane (EDB)ND 0.035 8/1/22 18:54 BRFND0.7020.270.021 0.16 1,2-Dichlorobenzene ND 0.035 8/1/22 18:54 BRFND0.7020.210.020 0.12 1,3-Dichlorobenzene ND 0.035 8/1/22 18:54 BRFND0.7020.210.019 0.12 1,4-Dichlorobenzene ND 0.035 8/1/22 18:54 BRFND0.7020.210.023 0.14 Dichlorodifluoromethane (Freon 12)0.19 0.035 8/1/22 18:54 BRF0.96 0.7020.170.034 0.17 1,1-Dichloroethane ND 0.035 8/1/22 18:54 BRFND0.7020.140.031 0.12 1,2-Dichloroethane ND 0.035 8/1/22 18:54 BRFND0.7020.140.032 0.13 1,1-Dichloroethylene ND 0.035 8/1/22 18:54 BRFND0.7020.140.027 0.11 cis-1,2-Dichloroethylene ND 0.035 8/1/22 18:54 BRFND0.7020.140.026 0.10 trans-1,2-Dichloroethylene ND 0.035 8/1/22 18:54 BRFND0.7020.140.028 0.11 1,2-Dichloropropane 0.036 0.035 8/1/22 18:54 BRF0.17 0.7020.160.019 0.088 cis-1,3-Dichloropropene ND 0.035 8/1/22 18:54 BRFND0.7020.160.018 0.082 trans-1,3-Dichloropropene ND 0.035 8/1/22 18:54 BRFND0.7020.160.018 0.082 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.035 8/1/22 18:54 BRFND0.7020.250.035 0.24 1,4-Dioxane ND 0.35 8/1/22 18:54 BRFND0.7021.30.029 0.10 Ethanol 90 4.0 8/2/22 7:45 BRF170 27.51.8 3.3 Ethyl Acetate 1.4 0.35 8/1/22 18:54 BRF5.1 0.7021.30.18 0.64 Ethylbenzene 0.89 0.035 8/1/22 18:54 BRF3.9 0.7020.150.020 0.089 4-Ethyltoluene 0.11 0.035 8/1/22 18:54 BRF0.54 0.7020.170.022 0.11 Heptane 0.24 0.035 8/1/22 18:54 BRF0.99 0.7020.140.022 0.092 Hexachlorobutadiene ND 0.035 8/1/22 18:54 BRFND0.7020.370.029 0.31 Hexane 0.56 1.4 8/1/22 18:54 BRFJ2.0 0.7024.90.18 0.64 2-Hexanone (MBK)ND 0.035 8/1/22 18:54 BRFND0.7020.140.018 0.072 Isopropanol 3.9 1.4 8/1/22 18:54 BRF9.7 0.7023.40.24 0.60 Methyl tert-Butyl Ether (MTBE)ND 0.035 8/1/22 18:54 BRFND0.7020.130.027 0.098 Methylene Chloride 0.17 0.35 8/1/22 18:54 BRFJ0.59 0.7021.20.16 0.57 4-Methyl-2-pentanone (MIBK)0.21 0.035 8/1/22 18:54 BRF0.87 0.7020.140.019 0.077 Naphthalene 0.070 0.035 8/1/22 18:54 BRF0.37 0.7020.180.026 0.14 Propene ND 1.4 8/1/22 18:54 BRFND0.7022.40.31 0.53 Styrene 0.33 0.035 8/1/22 18:54 BRF1.4 0.7020.150.018 0.079 1,1,2,2-Tetrachloroethane ND 0.035 8/1/22 18:54 BRFND0.7020.240.019 0.13 Page 10 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1209Sample Description/Location: Field Sample #: IAS-4 Sample ID: 22G1209-04 Sample Matrix: Indoor air Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -7 Receipt Vacuum(in Hg): -8.5 Sampled: 7/18/2022 17:05 Canister ID: 2144 Flow Controller ID: 3577 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 8 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene ND 0.035 8/1/22 18:54 BRFND0.7020.240.027 0.18 Tetrahydrofuran ND 0.35 8/1/22 18:54 BRFND0.7021.00.058 0.17 Toluene 2.2 0.035 8/1/22 18:54 BRF8.4 0.7020.130.020 0.076 1,2,4-Trichlorobenzene ND 0.035 8/1/22 18:54 BRFND0.7020.260.033 0.24 1,1,1-Trichloroethane ND 0.035 8/1/22 18:54 BRFND0.7020.190.028 0.15 1,1,2-Trichloroethane ND 0.035 8/1/22 18:54 BRFND0.7020.190.025 0.13 Trichloroethylene ND 0.035 8/1/22 18:54 BRFND0.7020.190.024 0.13 Trichlorofluoromethane (Freon 11)0.48 0.14 8/1/22 18:54 BRF2.7 0.7020.790.041 0.23 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)0.073 0.14 8/1/22 18:54 BRFJ0.56 0.7021.10.039 0.30 1,2,4-Trimethylbenzene 0.31 0.035 8/1/22 18:54 BRF1.5 0.7020.170.016 0.076 1,3,5-Trimethylbenzene 0.085 0.035 8/1/22 18:54 BRF0.42 0.7020.170.019 0.091 Vinyl Acetate ND 0.70 8/1/22 18:54 BRFND0.7022.50.19 0.66 Vinyl Chloride ND 0.035 8/1/22 18:54 BRFND0.7020.0900.032 0.081 m&p-Xylene 3.7 0.070 8/1/22 18:54 BRF16 0.7020.300.039 0.17 o-Xylene 1.2 0.035 8/1/22 18:54 BRF5.3 0.7020.150.018 0.078 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)105 8/2/22 7:4570-130 4-Bromofluorobenzene (1)107 8/1/22 18:5470-130 Page 11 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1209Sample Description/Location: Field Sample #: IAS-5 Sample ID: 22G1209-05 Sample Matrix: Indoor air Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -7 Receipt Vacuum(in Hg): -8.7 Sampled: 7/18/2022 17:20 Canister ID: 2213 Flow Controller ID: 4632 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 8 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 18 1.4 8/1/22 19:42 BRF42 0.7023.30.85 2.0 Benzene 0.083 0.035 8/1/22 19:42 BRF0.26 0.7020.110.027 0.085 Benzyl chloride ND 0.035 8/1/22 19:42 BRFND0.7020.180.031 0.16 Bromodichloromethane ND 0.035 8/1/22 19:42 BRFND0.7020.240.025 0.16 Bromoform ND 0.035 8/1/22 19:42 BRFND0.7020.360.024 0.25 Bromomethane ND 0.035 8/1/22 19:42 BRFND0.7020.140.023 0.091 1,3-Butadiene ND 0.035 8/1/22 19:42 BRFND0.7020.0780.029 0.065 2-Butanone (MEK)2.9 1.4 8/1/22 19:42 BRF8.5 0.7024.10.37 1.1 Carbon Disulfide 0.15 0.35 8/1/22 19:42 BRFJ0.47 0.7021.10.032 0.10 Carbon Tetrachloride 0.057 0.035 8/1/22 19:42 BRF0.36 0.7020.220.028 0.18 Chlorobenzene ND 0.035 8/1/22 19:42 BRFND0.7020.160.023 0.11 Chloroethane ND 0.035 8/1/22 19:42 BRFND0.7020.0930.031 0.082 Chloroform 0.036 0.035 8/1/22 19:42 BRF0.18 0.7020.170.033 0.16 Chloromethane 0.80 0.070 8/1/22 19:42 BRF1.6 0.7020.140.028 0.058 Cyclohexane ND 0.035 8/1/22 19:42 BRFND0.7020.120.021 0.073 Dibromochloromethane ND 0.035 8/1/22 19:42 BRFND0.7020.300.023 0.20 1,2-Dibromoethane (EDB)ND 0.035 8/1/22 19:42 BRFND0.7020.270.021 0.16 1,2-Dichlorobenzene ND 0.035 8/1/22 19:42 BRFND0.7020.210.020 0.12 1,3-Dichlorobenzene ND 0.035 8/1/22 19:42 BRFND0.7020.210.019 0.12 1,4-Dichlorobenzene ND 0.035 8/1/22 19:42 BRFND0.7020.210.023 0.14 Dichlorodifluoromethane (Freon 12)0.21 0.035 8/1/22 19:42 BRF1.0 0.7020.170.034 0.17 1,1-Dichloroethane ND 0.035 8/1/22 19:42 BRFND0.7020.140.031 0.12 1,2-Dichloroethane 0.076 0.035 8/1/22 19:42 BRF0.31 0.7020.140.032 0.13 1,1-Dichloroethylene ND 0.035 8/1/22 19:42 BRFND0.7020.140.027 0.11 cis-1,2-Dichloroethylene ND 0.035 8/1/22 19:42 BRFND0.7020.140.026 0.10 trans-1,2-Dichloroethylene 0.031 0.035 8/1/22 19:42 BRFJ0.12 0.7020.140.028 0.11 1,2-Dichloropropane 0.14 0.035 8/1/22 19:42 BRF0.63 0.7020.160.019 0.088 cis-1,3-Dichloropropene ND 0.035 8/1/22 19:42 BRFND0.7020.160.018 0.082 trans-1,3-Dichloropropene ND 0.035 8/1/22 19:42 BRFND0.7020.160.018 0.082 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.035 8/1/22 19:42 BRFND0.7020.250.035 0.24 1,4-Dioxane ND 0.35 8/1/22 19:42 BRFND0.7021.30.029 0.10 Ethanol 57 4.0 8/2/22 8:27 BRF110 27.51.8 3.3 Ethyl Acetate 2.1 0.35 8/1/22 19:42 BRF7.5 0.7021.30.18 0.64 Ethylbenzene 1.1 0.035 8/1/22 19:42 BRF5.0 0.7020.150.020 0.089 4-Ethyltoluene 0.062 0.035 8/1/22 19:42 BRF0.31 0.7020.170.022 0.11 Heptane 0.15 0.035 8/1/22 19:42 BRF0.61 0.7020.140.022 0.092 Hexachlorobutadiene ND 0.035 8/1/22 19:42 BRFND0.7020.370.029 0.31 Hexane 0.52 1.4 8/1/22 19:42 BRFJ1.8 0.7024.90.18 0.64 2-Hexanone (MBK)0.20 0.035 8/1/22 19:42 BRF0.81 0.7020.140.018 0.072 Isopropanol 20 1.4 8/1/22 19:42 BRF48 0.7023.40.24 0.60 Methyl tert-Butyl Ether (MTBE)ND 0.035 8/1/22 19:42 BRFND0.7020.130.027 0.098 Methylene Chloride 2.0 0.35 8/1/22 19:42 BRF7.0 0.7021.20.16 0.57 4-Methyl-2-pentanone (MIBK)0.20 0.035 8/1/22 19:42 BRF0.84 0.7020.140.019 0.077 Naphthalene 0.12 0.035 8/1/22 19:42 BRF0.62 0.7020.180.026 0.14 Propene ND 1.4 8/1/22 19:42 BRFND0.7022.40.31 0.53 Styrene 1.8 0.035 8/1/22 19:42 BRF7.5 0.7020.150.018 0.079 1,1,2,2-Tetrachloroethane ND 0.035 8/1/22 19:42 BRFND0.7020.240.019 0.13 Page 12 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1209Sample Description/Location: Field Sample #: IAS-5 Sample ID: 22G1209-05 Sample Matrix: Indoor air Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -7 Receipt Vacuum(in Hg): -8.7 Sampled: 7/18/2022 17:20 Canister ID: 2213 Flow Controller ID: 4632 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 8 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 0.044 0.035 8/1/22 19:42 BRF0.30 0.7020.240.027 0.18 Tetrahydrofuran 0.065 0.35 8/1/22 19:42 BRFJ0.19 0.7021.00.058 0.17 Toluene 4.4 0.035 8/1/22 19:42 BRF16 0.7020.130.020 0.076 1,2,4-Trichlorobenzene ND 0.035 8/1/22 19:42 BRFND0.7020.260.033 0.24 1,1,1-Trichloroethane ND 0.035 8/1/22 19:42 BRFND0.7020.190.028 0.15 1,1,2-Trichloroethane ND 0.035 8/1/22 19:42 BRFND0.7020.190.025 0.13 Trichloroethylene ND 0.035 8/1/22 19:42 BRFND0.7020.190.024 0.13 Trichlorofluoromethane (Freon 11)2.8 0.14 8/1/22 19:42 BRF16 0.7020.790.041 0.23 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)0.069 0.14 8/1/22 19:42 BRFJ0.53 0.7021.10.039 0.30 1,2,4-Trimethylbenzene 0.20 0.035 8/1/22 19:42 BRF0.97 0.7020.170.016 0.076 1,3,5-Trimethylbenzene 0.060 0.035 8/1/22 19:42 BRF0.29 0.7020.170.019 0.091 Vinyl Acetate ND 0.70 8/1/22 19:42 BRFND0.7022.50.19 0.66 Vinyl Chloride ND 0.035 8/1/22 19:42 BRFND0.7020.0900.032 0.081 m&p-Xylene 3.4 0.070 8/1/22 19:42 BRF15 0.7020.300.039 0.17 o-Xylene 1.5 0.035 8/1/22 19:42 BRF6.6 0.7020.150.018 0.078 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)96.5 8/2/22 8:2770-130 4-Bromofluorobenzene (1)106 8/1/22 19:4270-130 Page 13 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1209Sample Description/Location: Field Sample #: IAS-6 Sample ID: 22G1209-06 Sample Matrix: Indoor air Initial Vacuum(in Hg): -28.5 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -5.8 Sampled: 7/18/2022 17:16 Canister ID: 2216 Flow Controller ID: 3410 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 8 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 16 1.4 8/1/22 20:29 BRF37 0.7023.30.85 2.0 Benzene 0.11 0.035 8/1/22 20:29 BRF0.36 0.7020.110.027 0.085 Benzyl chloride ND 0.035 8/1/22 20:29 BRFND0.7020.180.031 0.16 Bromodichloromethane ND 0.035 8/1/22 20:29 BRFND0.7020.240.025 0.16 Bromoform ND 0.035 8/1/22 20:29 BRFND0.7020.360.024 0.25 Bromomethane ND 0.035 8/1/22 20:29 BRFND0.7020.140.023 0.091 1,3-Butadiene ND 0.035 8/1/22 20:29 BRFND0.7020.0780.029 0.065 2-Butanone (MEK)2.8 1.4 8/1/22 20:29 BRF8.2 0.7024.10.37 1.1 Carbon Disulfide 0.15 0.35 8/1/22 20:29 BRFJ0.45 0.7021.10.032 0.10 Carbon Tetrachloride 0.055 0.035 8/1/22 20:29 BRF0.35 0.7020.220.028 0.18 Chlorobenzene ND 0.035 8/1/22 20:29 BRFND0.7020.160.023 0.11 Chloroethane ND 0.035 8/1/22 20:29 BRFND0.7020.0930.031 0.082 Chloroform 0.039 0.035 8/1/22 20:29 BRF0.19 0.7020.170.033 0.16 Chloromethane 0.78 0.070 8/1/22 20:29 BRF1.6 0.7020.140.028 0.058 Cyclohexane ND 0.035 8/1/22 20:29 BRFND0.7020.120.021 0.073 Dibromochloromethane ND 0.035 8/1/22 20:29 BRFND0.7020.300.023 0.20 1,2-Dibromoethane (EDB)ND 0.035 8/1/22 20:29 BRFND0.7020.270.021 0.16 1,2-Dichlorobenzene ND 0.035 8/1/22 20:29 BRFND0.7020.210.020 0.12 1,3-Dichlorobenzene ND 0.035 8/1/22 20:29 BRFND0.7020.210.019 0.12 1,4-Dichlorobenzene ND 0.035 8/1/22 20:29 BRFND0.7020.210.023 0.14 Dichlorodifluoromethane (Freon 12)0.23 0.035 8/1/22 20:29 BRF1.1 0.7020.170.034 0.17 1,1-Dichloroethane ND 0.035 8/1/22 20:29 BRFND0.7020.140.031 0.12 1,2-Dichloroethane 0.074 0.035 8/1/22 20:29 BRF0.30 0.7020.140.032 0.13 1,1-Dichloroethylene ND 0.035 8/1/22 20:29 BRFND0.7020.140.027 0.11 cis-1,2-Dichloroethylene ND 0.035 8/1/22 20:29 BRFND0.7020.140.026 0.10 trans-1,2-Dichloroethylene ND 0.035 8/1/22 20:29 BRFND0.7020.140.028 0.11 1,2-Dichloropropane 0.13 0.035 8/1/22 20:29 BRF0.59 0.7020.160.019 0.088 cis-1,3-Dichloropropene ND 0.035 8/1/22 20:29 BRFND0.7020.160.018 0.082 trans-1,3-Dichloropropene ND 0.035 8/1/22 20:29 BRFND0.7020.160.018 0.082 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.035 8/1/22 20:29 BRFND0.7020.250.035 0.24 1,4-Dioxane ND 0.35 8/1/22 20:29 BRFND0.7021.30.029 0.10 Ethanol 61 4.0 8/2/22 9:09 BRF110 27.51.8 3.3 Ethyl Acetate 6.4 0.35 8/1/22 20:29 BRF23 0.7021.30.18 0.64 Ethylbenzene 1.0 0.035 8/1/22 20:29 BRF4.5 0.7020.150.020 0.089 4-Ethyltoluene 0.056 0.035 8/1/22 20:29 BRF0.28 0.7020.170.022 0.11 Heptane 0.14 0.035 8/1/22 20:29 BRF0.58 0.7020.140.022 0.092 Hexachlorobutadiene ND 0.035 8/1/22 20:29 BRFND0.7020.370.029 0.31 Hexane 0.53 1.4 8/1/22 20:29 BRFJ1.9 0.7024.90.18 0.64 2-Hexanone (MBK)0.18 0.035 8/1/22 20:29 BRF0.75 0.7020.140.018 0.072 Isopropanol 21 1.4 8/1/22 20:29 BRF52 0.7023.40.24 0.60 Methyl tert-Butyl Ether (MTBE)ND 0.035 8/1/22 20:29 BRFND0.7020.130.027 0.098 Methylene Chloride 1.7 0.35 8/1/22 20:29 BRF5.9 0.7021.20.16 0.57 4-Methyl-2-pentanone (MIBK)0.19 0.035 8/1/22 20:29 BRF0.79 0.7020.140.019 0.077 Naphthalene 0.13 0.035 8/1/22 20:29 BRF0.68 0.7020.180.026 0.14 Propene ND 1.4 8/1/22 20:29 BRFND0.7022.40.31 0.53 Styrene 1.6 0.035 8/1/22 20:29 BRF6.9 0.7020.150.018 0.079 1,1,2,2-Tetrachloroethane ND 0.035 8/1/22 20:29 BRFND0.7020.240.019 0.13 Page 14 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1209Sample Description/Location: Field Sample #: IAS-6 Sample ID: 22G1209-06 Sample Matrix: Indoor air Initial Vacuum(in Hg): -28.5 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -5.8 Sampled: 7/18/2022 17:16 Canister ID: 2216 Flow Controller ID: 3410 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 8 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 0.041 0.035 8/1/22 20:29 BRF0.28 0.7020.240.027 0.18 Tetrahydrofuran ND 0.35 8/1/22 20:29 BRFND0.7021.00.058 0.17 Toluene 4.3 0.035 8/1/22 20:29 BRF16 0.7020.130.020 0.076 1,2,4-Trichlorobenzene ND 0.035 8/1/22 20:29 BRFND0.7020.260.033 0.24 1,1,1-Trichloroethane ND 0.035 8/1/22 20:29 BRFND0.7020.190.028 0.15 1,1,2-Trichloroethane ND 0.035 8/1/22 20:29 BRFND0.7020.190.025 0.13 Trichloroethylene ND 0.035 8/1/22 20:29 BRFND0.7020.190.024 0.13 Trichlorofluoromethane (Freon 11)2.7 0.14 8/1/22 20:29 BRF15 0.7020.790.041 0.23 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)0.073 0.14 8/1/22 20:29 BRFJ0.56 0.7021.10.039 0.30 1,2,4-Trimethylbenzene 0.18 0.035 8/1/22 20:29 BRF0.90 0.7020.170.016 0.076 1,3,5-Trimethylbenzene 0.056 0.035 8/1/22 20:29 BRF0.28 0.7020.170.019 0.091 Vinyl Acetate ND 0.70 8/1/22 20:29 BRFND0.7022.50.19 0.66 Vinyl Chloride ND 0.035 8/1/22 20:29 BRFND0.7020.0900.032 0.081 m&p-Xylene 3.1 0.070 8/1/22 20:29 BRF13 0.7020.300.039 0.17 o-Xylene 1.4 0.035 8/1/22 20:29 BRF6.1 0.7020.150.018 0.078 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)106 8/1/22 20:2970-130 4-Bromofluorobenzene (1)98.7 8/2/22 9:0970-130 Page 15 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1209Sample Description/Location: Field Sample #: IAS-7 Sample ID: 22G1209-07 Sample Matrix: Indoor air Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -6.5 Receipt Vacuum(in Hg): -7.5 Sampled: 7/18/2022 17:55 Canister ID: 2229 Flow Controller ID: 3087 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 8 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 12 1.4 8/1/22 21:16 BRF30 0.7023.30.85 2.0 Benzene 0.060 0.035 8/1/22 21:16 BRF0.19 0.7020.110.027 0.085 Benzyl chloride ND 0.035 8/1/22 21:16 BRFND0.7020.180.031 0.16 Bromodichloromethane ND 0.035 8/1/22 21:16 BRFND0.7020.240.025 0.16 Bromoform ND 0.035 8/1/22 21:16 BRFND0.7020.360.024 0.25 Bromomethane ND 0.035 8/1/22 21:16 BRFND0.7020.140.023 0.091 1,3-Butadiene ND 0.035 8/1/22 21:16 BRFND0.7020.0780.029 0.065 2-Butanone (MEK)3.9 1.4 8/1/22 21:16 BRF11 0.7024.10.37 1.1 Carbon Disulfide ND 0.35 8/1/22 21:16 BRFND0.7021.10.032 0.10 Carbon Tetrachloride 0.058 0.035 8/1/22 21:16 BRF0.36 0.7020.220.028 0.18 Chlorobenzene ND 0.035 8/1/22 21:16 BRFND0.7020.160.023 0.11 Chloroethane ND 0.035 8/1/22 21:16 BRFND0.7020.0930.031 0.082 Chloroform 0.11 0.035 8/1/22 21:16 BRF0.53 0.7020.170.033 0.16 Chloromethane 0.66 0.070 8/1/22 21:16 BRF1.4 0.7020.140.028 0.058 Cyclohexane ND 0.035 8/1/22 21:16 BRFND0.7020.120.021 0.073 Dibromochloromethane ND 0.035 8/1/22 21:16 BRFND0.7020.300.023 0.20 1,2-Dibromoethane (EDB)ND 0.035 8/1/22 21:16 BRFND0.7020.270.021 0.16 1,2-Dichlorobenzene ND 0.035 8/1/22 21:16 BRFND0.7020.210.020 0.12 1,3-Dichlorobenzene ND 0.035 8/1/22 21:16 BRFND0.7020.210.019 0.12 1,4-Dichlorobenzene ND 0.035 8/1/22 21:16 BRFND0.7020.210.023 0.14 Dichlorodifluoromethane (Freon 12)0.22 0.035 8/1/22 21:16 BRF1.1 0.7020.170.034 0.17 1,1-Dichloroethane ND 0.035 8/1/22 21:16 BRFND0.7020.140.031 0.12 1,2-Dichloroethane ND 0.035 8/1/22 21:16 BRFND0.7020.140.032 0.13 1,1-Dichloroethylene ND 0.035 8/1/22 21:16 BRFND0.7020.140.027 0.11 cis-1,2-Dichloroethylene ND 0.035 8/1/22 21:16 BRFND0.7020.140.026 0.10 trans-1,2-Dichloroethylene ND 0.035 8/1/22 21:16 BRFND0.7020.140.028 0.11 1,2-Dichloropropane ND 0.035 8/1/22 21:16 BRFND0.7020.160.019 0.088 cis-1,3-Dichloropropene ND 0.035 8/1/22 21:16 BRFND0.7020.160.018 0.082 trans-1,3-Dichloropropene ND 0.035 8/1/22 21:16 BRFND0.7020.160.018 0.082 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.035 8/1/22 21:16 BRFND0.7020.250.035 0.24 1,4-Dioxane ND 0.35 8/1/22 21:16 BRFND0.7021.30.029 0.10 Ethanol 6.1 1.4 8/1/22 21:16 BRF12 0.7022.60.62 1.2 Ethyl Acetate 0.47 0.35 8/1/22 21:16 BRF1.7 0.7021.30.18 0.64 Ethylbenzene 0.11 0.035 8/1/22 21:16 BRF0.48 0.7020.150.020 0.089 4-Ethyltoluene ND 0.035 8/1/22 21:16 BRFND0.7020.170.022 0.11 Heptane 0.060 0.035 8/1/22 21:16 BRF0.25 0.7020.140.022 0.092 Hexachlorobutadiene ND 0.035 8/1/22 21:16 BRFND0.7020.370.029 0.31 Hexane 0.30 1.4 8/1/22 21:16 BRFJ1.1 0.7024.90.18 0.64 2-Hexanone (MBK)0.16 0.035 8/1/22 21:16 BRF0.64 0.7020.140.018 0.072 Isopropanol 1.1 1.4 8/1/22 21:16 BRFJ2.6 0.7023.40.24 0.60 Methyl tert-Butyl Ether (MTBE)ND 0.035 8/1/22 21:16 BRFND0.7020.130.027 0.098 Methylene Chloride ND 0.35 8/1/22 21:16 BRFND0.7021.20.16 0.57 4-Methyl-2-pentanone (MIBK)0.098 0.035 8/1/22 21:16 BRF0.40 0.7020.140.019 0.077 Naphthalene 0.051 0.035 8/1/22 21:16 BRF0.26 0.7020.180.026 0.14 Propene ND 1.4 8/1/22 21:16 BRFND0.7022.40.31 0.53 Styrene 1.3 0.035 8/1/22 21:16 BRF5.6 0.7020.150.018 0.079 1,1,2,2-Tetrachloroethane ND 0.035 8/1/22 21:16 BRFND0.7020.240.019 0.13 Page 16 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1209Sample Description/Location: Field Sample #: IAS-7 Sample ID: 22G1209-07 Sample Matrix: Indoor air Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -6.5 Receipt Vacuum(in Hg): -7.5 Sampled: 7/18/2022 17:55 Canister ID: 2229 Flow Controller ID: 3087 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 8 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 0.30 0.035 8/1/22 21:16 BRF2.0 0.7020.240.027 0.18 Tetrahydrofuran 0.14 0.35 8/1/22 21:16 BRFJ0.41 0.7021.00.058 0.17 Toluene 0.37 0.035 8/1/22 21:16 BRF1.4 0.7020.130.020 0.076 1,2,4-Trichlorobenzene ND 0.035 8/1/22 21:16 BRFND0.7020.260.033 0.24 1,1,1-Trichloroethane ND 0.035 8/1/22 21:16 BRFND0.7020.190.028 0.15 1,1,2-Trichloroethane ND 0.035 8/1/22 21:16 BRFND0.7020.190.025 0.13 Trichloroethylene ND 0.035 8/1/22 21:16 BRFND0.7020.190.024 0.13 Trichlorofluoromethane (Freon 11)0.26 0.14 8/1/22 21:16 BRF1.4 0.7020.790.041 0.23 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)0.067 0.14 8/1/22 21:16 BRFJ0.52 0.7021.10.039 0.30 1,2,4-Trimethylbenzene 0.072 0.035 8/1/22 21:16 BRF0.36 0.7020.170.016 0.076 1,3,5-Trimethylbenzene 0.019 0.035 8/1/22 21:16 BRFJ0.093 0.7020.170.019 0.091 Vinyl Acetate ND 0.70 8/1/22 21:16 BRFND0.7022.50.19 0.66 Vinyl Chloride ND 0.035 8/1/22 21:16 BRFND0.7020.0900.032 0.081 m&p-Xylene 0.36 0.070 8/1/22 21:16 BRF1.6 0.7020.300.039 0.17 o-Xylene 0.13 0.035 8/1/22 21:16 BRF0.55 0.7020.150.018 0.078 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)105 8/1/22 21:1670-130 Page 17 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1209Sample Description/Location: Field Sample #: IAS-8 Sample ID: 22G1209-08 Sample Matrix: Indoor air Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -6 Receipt Vacuum(in Hg): -8 Sampled: 7/18/2022 17:53 Canister ID: 1963 Flow Controller ID: 3102 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 8 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 9.6 1.4 8/1/22 22:04 BRF23 0.7023.30.85 2.0 Benzene 0.080 0.035 8/1/22 22:04 BRF0.26 0.7020.110.027 0.085 Benzyl chloride ND 0.035 8/1/22 22:04 BRFND0.7020.180.031 0.16 Bromodichloromethane ND 0.035 8/1/22 22:04 BRFND0.7020.240.025 0.16 Bromoform ND 0.035 8/1/22 22:04 BRFND0.7020.360.024 0.25 Bromomethane ND 0.035 8/1/22 22:04 BRFND0.7020.140.023 0.091 1,3-Butadiene ND 0.035 8/1/22 22:04 BRFND0.7020.0780.029 0.065 2-Butanone (MEK)2.1 1.4 8/1/22 22:04 BRF6.2 0.7024.10.37 1.1 Carbon Disulfide ND 0.35 8/1/22 22:04 BRFND0.7021.10.032 0.10 Carbon Tetrachloride 0.058 0.035 8/1/22 22:04 BRF0.37 0.7020.220.028 0.18 Chlorobenzene ND 0.035 8/1/22 22:04 BRFND0.7020.160.023 0.11 Chloroethane ND 0.035 8/1/22 22:04 BRFND0.7020.0930.031 0.082 Chloroform ND 0.035 8/1/22 22:04 BRFND0.7020.170.033 0.16 Chloromethane 0.63 0.070 8/1/22 22:04 BRF1.3 0.7020.140.028 0.058 Cyclohexane ND 0.035 8/1/22 22:04 BRFND0.7020.120.021 0.073 Dibromochloromethane ND 0.035 8/1/22 22:04 BRFND0.7020.300.023 0.20 1,2-Dibromoethane (EDB)ND 0.035 8/1/22 22:04 BRFND0.7020.270.021 0.16 1,2-Dichlorobenzene ND 0.035 8/1/22 22:04 BRFND0.7020.210.020 0.12 1,3-Dichlorobenzene ND 0.035 8/1/22 22:04 BRFND0.7020.210.019 0.12 1,4-Dichlorobenzene ND 0.035 8/1/22 22:04 BRFND0.7020.210.023 0.14 Dichlorodifluoromethane (Freon 12)0.22 0.035 8/1/22 22:04 BRF1.1 0.7020.170.034 0.17 1,1-Dichloroethane ND 0.035 8/1/22 22:04 BRFND0.7020.140.031 0.12 1,2-Dichloroethane ND 0.035 8/1/22 22:04 BRFND0.7020.140.032 0.13 1,1-Dichloroethylene ND 0.035 8/1/22 22:04 BRFND0.7020.140.027 0.11 cis-1,2-Dichloroethylene ND 0.035 8/1/22 22:04 BRFND0.7020.140.026 0.10 trans-1,2-Dichloroethylene ND 0.035 8/1/22 22:04 BRFND0.7020.140.028 0.11 1,2-Dichloropropane ND 0.035 8/1/22 22:04 BRFND0.7020.160.019 0.088 cis-1,3-Dichloropropene ND 0.035 8/1/22 22:04 BRFND0.7020.160.018 0.082 trans-1,3-Dichloropropene ND 0.035 8/1/22 22:04 BRFND0.7020.160.018 0.082 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.035 8/1/22 22:04 BRFND0.7020.250.035 0.24 1,4-Dioxane ND 0.35 8/1/22 22:04 BRFND0.7021.30.029 0.10 Ethanol 8.8 1.4 8/1/22 22:04 BRF17 0.7022.60.62 1.2 Ethyl Acetate 2.0 0.35 8/1/22 22:04 BRF7.3 0.7021.30.18 0.64 Ethylbenzene 0.057 0.035 8/1/22 22:04 BRF0.25 0.7020.150.020 0.089 4-Ethyltoluene ND 0.035 8/1/22 22:04 BRFND0.7020.170.022 0.11 Heptane 0.079 0.035 8/1/22 22:04 BRF0.32 0.7020.140.022 0.092 Hexachlorobutadiene ND 0.035 8/1/22 22:04 BRFND0.7020.370.029 0.31 Hexane 0.64 1.4 8/1/22 22:04 BRFJ2.3 0.7024.90.18 0.64 2-Hexanone (MBK)0.14 0.035 8/1/22 22:04 BRF0.56 0.7020.140.018 0.072 Isopropanol 1.5 1.4 8/1/22 22:04 BRF3.6 0.7023.40.24 0.60 Methyl tert-Butyl Ether (MTBE)ND 0.035 8/1/22 22:04 BRFND0.7020.130.027 0.098 Methylene Chloride ND 0.35 8/1/22 22:04 BRFND0.7021.20.16 0.57 4-Methyl-2-pentanone (MIBK)0.065 0.035 8/1/22 22:04 BRF0.27 0.7020.140.019 0.077 Naphthalene 0.047 0.035 8/1/22 22:04 BRF0.25 0.7020.180.026 0.14 Propene ND 1.4 8/1/22 22:04 BRFND0.7022.40.31 0.53 Styrene 1.4 0.035 8/1/22 22:04 BRF6.0 0.7020.150.018 0.079 1,1,2,2-Tetrachloroethane ND 0.035 8/1/22 22:04 BRFND0.7020.240.019 0.13 Page 18 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1209Sample Description/Location: Field Sample #: IAS-8 Sample ID: 22G1209-08 Sample Matrix: Indoor air Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -6 Receipt Vacuum(in Hg): -8 Sampled: 7/18/2022 17:53 Canister ID: 1963 Flow Controller ID: 3102 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 8 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene ND 0.035 8/1/22 22:04 BRFND0.7020.240.027 0.18 Tetrahydrofuran ND 0.35 8/1/22 22:04 BRFND0.7021.00.058 0.17 Toluene 0.61 0.035 8/1/22 22:04 BRF2.3 0.7020.130.020 0.076 1,2,4-Trichlorobenzene ND 0.035 8/1/22 22:04 BRFND0.7020.260.033 0.24 1,1,1-Trichloroethane ND 0.035 8/1/22 22:04 BRFND0.7020.190.028 0.15 1,1,2-Trichloroethane ND 0.035 8/1/22 22:04 BRFND0.7020.190.025 0.13 Trichloroethylene ND 0.035 8/1/22 22:04 BRFND0.7020.190.024 0.13 Trichlorofluoromethane (Freon 11)0.40 0.14 8/1/22 22:04 BRF2.3 0.7020.790.041 0.23 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)0.067 0.14 8/1/22 22:04 BRFJ0.51 0.7021.10.039 0.30 1,2,4-Trimethylbenzene 0.062 0.035 8/1/22 22:04 BRF0.31 0.7020.170.016 0.076 1,3,5-Trimethylbenzene ND 0.035 8/1/22 22:04 BRFND0.7020.170.019 0.091 Vinyl Acetate ND 0.70 8/1/22 22:04 BRFND0.7022.50.19 0.66 Vinyl Chloride ND 0.035 8/1/22 22:04 BRFND0.7020.0900.032 0.081 m&p-Xylene 0.16 0.070 8/1/22 22:04 BRF0.72 0.7020.300.039 0.17 o-Xylene 0.078 0.035 8/1/22 22:04 BRF0.34 0.7020.150.018 0.078 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)102 8/1/22 22:0470-130 Page 19 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1209Sample Description/Location: Field Sample #: IAS-9 Sample ID: 22G1209-09 Sample Matrix: Indoor air Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -6 Receipt Vacuum(in Hg): -6.9 Sampled: 7/18/2022 18:30 Canister ID: 1997 Flow Controller ID: 3050 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 8 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 13 1.4 8/1/22 23:32 BRF30 0.7023.30.85 2.0 Benzene 0.18 0.035 8/1/22 23:32 BRF0.57 0.7020.110.027 0.085 Benzyl chloride ND 0.035 8/1/22 23:32 BRFND0.7020.180.031 0.16 Bromodichloromethane ND 0.035 8/1/22 23:32 BRFND0.7020.240.025 0.16 Bromoform ND 0.035 8/1/22 23:32 BRFND0.7020.360.024 0.25 Bromomethane ND 0.035 8/1/22 23:32 BRFND0.7020.140.023 0.091 1,3-Butadiene ND 0.035 8/1/22 23:32 BRFND0.7020.0780.029 0.065 2-Butanone (MEK)1.4 1.4 8/1/22 23:32 BRF4.3 0.7024.10.37 1.1 Carbon Disulfide 0.13 0.35 8/1/22 23:32 BRFJ0.40 0.7021.10.032 0.10 Carbon Tetrachloride 0.055 0.035 8/1/22 23:32 BRF0.35 0.7020.220.028 0.18 Chlorobenzene ND 0.035 8/1/22 23:32 BRFND0.7020.160.023 0.11 Chloroethane ND 0.035 8/1/22 23:32 BRFND0.7020.0930.031 0.082 Chloroform 0.039 0.035 8/1/22 23:32 BRF0.19 0.7020.170.033 0.16 Chloromethane 0.80 0.070 8/1/22 23:32 BRF1.7 0.7020.140.028 0.058 Cyclohexane ND 0.035 8/1/22 23:32 BRFND0.7020.120.021 0.073 Dibromochloromethane ND 0.035 8/1/22 23:32 BRFND0.7020.300.023 0.20 1,2-Dibromoethane (EDB)ND 0.035 8/1/22 23:32 BRFND0.7020.270.021 0.16 1,2-Dichlorobenzene ND 0.035 8/1/22 23:32 BRFND0.7020.210.020 0.12 1,3-Dichlorobenzene ND 0.035 8/1/22 23:32 BRFND0.7020.210.019 0.12 1,4-Dichlorobenzene ND 0.035 8/1/22 23:32 BRFND0.7020.210.023 0.14 Dichlorodifluoromethane (Freon 12)0.22 0.035 8/1/22 23:32 BRF1.1 0.7020.170.034 0.17 1,1-Dichloroethane ND 0.035 8/1/22 23:32 BRFND0.7020.140.031 0.12 1,2-Dichloroethane ND 0.035 8/1/22 23:32 BRFND0.7020.140.032 0.13 1,1-Dichloroethylene ND 0.035 8/1/22 23:32 BRFND0.7020.140.027 0.11 cis-1,2-Dichloroethylene ND 0.035 8/1/22 23:32 BRFND0.7020.140.026 0.10 trans-1,2-Dichloroethylene ND 0.035 8/1/22 23:32 BRFND0.7020.140.028 0.11 1,2-Dichloropropane ND 0.035 8/1/22 23:32 BRFND0.7020.160.019 0.088 cis-1,3-Dichloropropene ND 0.035 8/1/22 23:32 BRFND0.7020.160.018 0.082 trans-1,3-Dichloropropene ND 0.035 8/1/22 23:32 BRFND0.7020.160.018 0.082 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.035 8/1/22 23:32 BRFND0.7020.250.035 0.24 1,4-Dioxane ND 0.35 8/1/22 23:32 BRFND0.7021.30.029 0.10 Ethanol 21 1.4 8/1/22 23:32 BRF40 0.7022.60.62 1.2 Ethyl Acetate 0.79 0.35 8/1/22 23:32 BRF2.9 0.7021.30.18 0.64 Ethylbenzene 0.24 0.035 8/1/22 23:32 BRF1.1 0.7020.150.020 0.089 4-Ethyltoluene 0.035 0.035 8/1/22 23:32 BRF0.17 0.7020.170.022 0.11 Heptane 0.094 0.035 8/1/22 23:32 BRF0.39 0.7020.140.022 0.092 Hexachlorobutadiene ND 0.035 8/1/22 23:32 BRFND0.7020.370.029 0.31 Hexane 0.31 1.4 8/1/22 23:32 BRFJ1.1 0.7024.90.18 0.64 2-Hexanone (MBK)ND 0.035 8/1/22 23:32 BRFND0.7020.140.018 0.072 Isopropanol 1.3 1.4 8/1/22 23:32 BRFJ3.2 0.7023.40.24 0.60 Methyl tert-Butyl Ether (MTBE)ND 0.035 8/1/22 23:32 BRFND0.7020.130.027 0.098 Methylene Chloride ND 0.35 8/1/22 23:32 BRFND0.7021.20.16 0.57 4-Methyl-2-pentanone (MIBK)3.2 0.035 8/1/22 23:32 BRF13 0.7020.140.019 0.077 Naphthalene 0.10 0.035 8/1/22 23:32 BRF0.55 0.7020.180.026 0.14 Propene ND 1.4 8/1/22 23:32 BRFND0.7022.40.31 0.53 Styrene 7.0 0.035 8/1/22 23:32 BRF30 0.7020.150.018 0.079 1,1,2,2-Tetrachloroethane ND 0.035 8/1/22 23:32 BRFND0.7020.240.019 0.13 Page 20 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1209Sample Description/Location: Field Sample #: IAS-9 Sample ID: 22G1209-09 Sample Matrix: Indoor air Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -6 Receipt Vacuum(in Hg): -6.9 Sampled: 7/18/2022 18:30 Canister ID: 1997 Flow Controller ID: 3050 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 8 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene ND 0.035 8/1/22 23:32 BRFND0.7020.240.027 0.18 Tetrahydrofuran ND 0.35 8/1/22 23:32 BRFND0.7021.00.058 0.17 Toluene 0.48 0.035 8/1/22 23:32 BRF1.8 0.7020.130.020 0.076 1,2,4-Trichlorobenzene ND 0.035 8/1/22 23:32 BRFND0.7020.260.033 0.24 1,1,1-Trichloroethane ND 0.035 8/1/22 23:32 BRFND0.7020.190.028 0.15 1,1,2-Trichloroethane ND 0.035 8/1/22 23:32 BRFND0.7020.190.025 0.13 Trichloroethylene ND 0.035 8/1/22 23:32 BRFND0.7020.190.024 0.13 Trichlorofluoromethane (Freon 11)21 0.14 8/1/22 23:32 BRF120 0.7020.790.041 0.23 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)0.067 0.14 8/1/22 23:32 BRFJ0.52 0.7021.10.039 0.30 1,2,4-Trimethylbenzene 0.072 0.035 8/1/22 23:32 BRF0.36 0.7020.170.016 0.076 1,3,5-Trimethylbenzene 0.023 0.035 8/1/22 23:32 BRFJ0.11 0.7020.170.019 0.091 Vinyl Acetate ND 0.70 8/1/22 23:32 BRFND0.7022.50.19 0.66 Vinyl Chloride ND 0.035 8/1/22 23:32 BRFND0.7020.0900.032 0.081 m&p-Xylene 0.74 0.070 8/1/22 23:32 BRF3.2 0.7020.300.039 0.17 o-Xylene 0.16 0.035 8/1/22 23:32 BRF0.71 0.7020.150.018 0.078 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)106 8/1/22 23:3270-130 Page 21 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1209Sample Description/Location: Field Sample #: IAS-10 Sample ID: 22G1209-10 Sample Matrix: Indoor air Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -10.5 Receipt Vacuum(in Hg): -12.5 Sampled: 7/18/2022 17:00 Canister ID: 2157 Flow Controller ID: 3174 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 8 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 51 4.0 8/2/22 8:47 BRF120 29.52.4 5.7 Benzene 0.078 0.040 8/2/22 0:23 BRF0.25 0.80.130.030 0.097 Benzyl chloride ND 0.040 8/2/22 0:23 BRFND0.80.210.035 0.18 Bromodichloromethane ND 0.040 8/2/22 0:23 BRFND0.80.270.028 0.19 Bromoform ND 0.040 8/2/22 0:23 BRFND0.80.410.027 0.28 Bromomethane ND 0.040 8/2/22 0:23 BRFND0.80.160.027 0.10 1,3-Butadiene ND 0.040 8/2/22 0:23 BRFND0.80.0880.034 0.074 2-Butanone (MEK)2.5 1.6 8/2/22 0:23 BRF7.3 0.84.70.43 1.3 Carbon Disulfide 0.24 0.40 8/2/22 0:23 BRFJ0.74 0.81.20.037 0.12 Carbon Tetrachloride 0.060 0.040 8/2/22 0:23 BRF0.38 0.80.250.032 0.20 Chlorobenzene ND 0.040 8/2/22 0:23 BRFND0.80.180.027 0.12 Chloroethane ND 0.040 8/2/22 0:23 BRFND0.80.110.035 0.094 Chloroform 0.074 0.040 8/2/22 0:23 BRF0.36 0.80.200.038 0.19 Chloromethane 0.73 0.080 8/2/22 0:23 BRF1.5 0.80.170.032 0.066 Cyclohexane ND 0.040 8/2/22 0:23 BRFND0.80.140.024 0.083 Dibromochloromethane ND 0.040 8/2/22 0:23 BRFND0.80.340.026 0.23 1,2-Dibromoethane (EDB)ND 0.040 8/2/22 0:23 BRFND0.80.310.024 0.19 1,2-Dichlorobenzene ND 0.040 8/2/22 0:23 BRFND0.80.240.023 0.14 1,3-Dichlorobenzene ND 0.040 8/2/22 0:23 BRFND0.80.240.022 0.13 1,4-Dichlorobenzene ND 0.040 8/2/22 0:23 BRFND0.80.240.026 0.16 Dichlorodifluoromethane (Freon 12)0.20 0.040 8/2/22 0:23 BRF0.99 0.80.200.039 0.19 1,1-Dichloroethane ND 0.040 8/2/22 0:23 BRFND0.80.160.035 0.14 1,2-Dichloroethane 0.54 0.040 8/2/22 0:23 BRF2.2 0.80.160.036 0.15 1,1-Dichloroethylene ND 0.040 8/2/22 0:23 BRFND0.80.160.030 0.12 cis-1,2-Dichloroethylene ND 0.040 8/2/22 0:23 BRFND0.80.160.029 0.12 trans-1,2-Dichloroethylene ND 0.040 8/2/22 0:23 BRFND0.80.160.031 0.12 1,2-Dichloropropane 0.25 0.040 8/2/22 0:23 BRF1.2 0.80.180.022 0.10 cis-1,3-Dichloropropene ND 0.040 8/2/22 0:23 BRFND0.80.180.021 0.094 trans-1,3-Dichloropropene ND 0.040 8/2/22 0:23 BRFND0.80.180.020 0.093 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.040 8/2/22 0:23 BRFND0.80.280.039 0.28 1,4-Dioxane ND 0.40 8/2/22 0:23 BRFND0.81.40.033 0.12 Ethanol 20 1.6 8/2/22 0:23 BRF38 0.83.00.71 1.3 Ethyl Acetate 0.98 0.40 8/2/22 0:23 BRF3.5 0.81.40.20 0.73 Ethylbenzene 3.4 0.040 8/2/22 0:23 BRF15 0.80.170.023 0.10 4-Ethyltoluene 0.34 0.040 8/2/22 0:23 BRF1.7 0.80.200.025 0.12 Heptane 0.24 0.040 8/2/22 0:23 BRF0.98 0.80.160.026 0.10 Hexachlorobutadiene ND 0.040 8/2/22 0:23 BRFND0.80.430.033 0.35 Hexane 0.66 1.6 8/2/22 0:23 BRFJ2.3 0.85.60.21 0.73 2-Hexanone (MBK)0.37 0.040 8/2/22 0:23 BRF1.5 0.80.160.020 0.082 Isopropanol 2.6 1.6 8/2/22 0:23 BRF6.3 0.83.90.28 0.68 Methyl tert-Butyl Ether (MTBE)ND 0.040 8/2/22 0:23 BRFND0.80.140.031 0.11 Methylene Chloride 0.27 0.40 8/2/22 0:23 BRFJ0.94 0.81.40.19 0.64 4-Methyl-2-pentanone (MIBK)0.31 0.040 8/2/22 0:23 BRF1.3 0.80.160.021 0.088 Naphthalene 0.27 0.040 8/2/22 0:23 BRF1.4 0.80.210.030 0.16 Propene ND 1.6 8/2/22 0:23 BRFND0.82.80.35 0.61 Styrene 2.2 0.040 8/2/22 0:23 BRF9.5 0.80.170.021 0.090 1,1,2,2-Tetrachloroethane ND 0.040 8/2/22 0:23 BRFND0.80.270.022 0.15 Page 22 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1209Sample Description/Location: Field Sample #: IAS-10 Sample ID: 22G1209-10 Sample Matrix: Indoor air Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -10.5 Receipt Vacuum(in Hg): -12.5 Sampled: 7/18/2022 17:00 Canister ID: 2157 Flow Controller ID: 3174 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 8 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 0.057 0.040 8/2/22 0:23 BRF0.39 0.80.270.031 0.21 Tetrahydrofuran 0.084 0.40 8/2/22 0:23 BRFJ0.25 0.81.20.066 0.19 Toluene 9.7 0.040 8/2/22 0:23 BRF37 0.80.150.023 0.086 1,2,4-Trichlorobenzene ND 0.040 8/2/22 0:23 BRFND0.80.300.037 0.27 1,1,1-Trichloroethane ND 0.040 8/2/22 0:23 BRFND0.80.220.031 0.17 1,1,2-Trichloroethane 0.058 0.040 8/2/22 0:23 BRF0.31 0.80.220.028 0.15 Trichloroethylene 0.041 0.040 8/2/22 0:23 BRF0.22 0.80.210.027 0.14 Trichlorofluoromethane (Freon 11)5.0 0.16 8/2/22 0:23 BRF28 0.80.900.047 0.27 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)0.068 0.16 8/2/22 0:23 BRFJ0.52 0.81.20.044 0.34 1,2,4-Trimethylbenzene 1.0 0.040 8/2/22 0:23 BRF5.0 0.80.200.018 0.087 1,3,5-Trimethylbenzene 0.35 0.040 8/2/22 0:23 BRF1.7 0.80.200.021 0.10 Vinyl Acetate ND 0.80 8/2/22 0:23 BRFND0.82.80.21 0.76 Vinyl Chloride ND 0.040 8/2/22 0:23 BRFND0.80.100.036 0.092 m&p-Xylene 11 0.080 8/2/22 0:23 BRF48 0.80.350.045 0.19 o-Xylene 7.6 0.040 8/2/22 0:23 BRF33 0.80.170.020 0.089 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)100 8/2/22 8:4770-130 4-Bromofluorobenzene (1)107 8/2/22 0:2370-130 Page 23 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1209Sample Description/Location: Field Sample #: IAS-Dup Sample ID: 22G1209-11 Sample Matrix: Indoor air Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -7 Receipt Vacuum(in Hg): -8.8 Sampled: 7/18/2022 00:00 Canister ID: 2015 Flow Controller ID: 4623 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 8 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 16 1.4 8/2/22 1:11 BRF38 0.7023.30.85 2.0 Benzene 0.076 0.035 8/2/22 1:11 BRF0.24 0.7020.110.027 0.085 Benzyl chloride ND 0.035 8/2/22 1:11 BRFND0.7020.180.031 0.16 Bromodichloromethane ND 0.035 8/2/22 1:11 BRFND0.7020.240.025 0.16 Bromoform ND 0.035 8/2/22 1:11 BRFND0.7020.360.024 0.25 Bromomethane ND 0.035 8/2/22 1:11 BRFND0.7020.140.023 0.091 1,3-Butadiene ND 0.035 8/2/22 1:11 BRFND0.7020.0780.029 0.065 2-Butanone (MEK)2.9 1.4 8/2/22 1:11 BRF8.6 0.7024.10.37 1.1 Carbon Disulfide 0.16 0.35 8/2/22 1:11 BRFJ0.50 0.7021.10.032 0.10 Carbon Tetrachloride 0.058 0.035 8/2/22 1:11 BRF0.37 0.7020.220.028 0.18 Chlorobenzene ND 0.035 8/2/22 1:11 BRFND0.7020.160.023 0.11 Chloroethane ND 0.035 8/2/22 1:11 BRFND0.7020.0930.031 0.082 Chloroform 0.039 0.035 8/2/22 1:11 BRF0.19 0.7020.170.033 0.16 Chloromethane 0.82 0.070 8/2/22 1:11 BRF1.7 0.7020.140.028 0.058 Cyclohexane ND 0.035 8/2/22 1:11 BRFND0.7020.120.021 0.073 Dibromochloromethane ND 0.035 8/2/22 1:11 BRFND0.7020.300.023 0.20 1,2-Dibromoethane (EDB)ND 0.035 8/2/22 1:11 BRFND0.7020.270.021 0.16 1,2-Dichlorobenzene ND 0.035 8/2/22 1:11 BRFND0.7020.210.020 0.12 1,3-Dichlorobenzene ND 0.035 8/2/22 1:11 BRFND0.7020.210.019 0.12 1,4-Dichlorobenzene ND 0.035 8/2/22 1:11 BRFND0.7020.210.023 0.14 Dichlorodifluoromethane (Freon 12)0.20 0.035 8/2/22 1:11 BRF0.99 0.7020.170.034 0.17 1,1-Dichloroethane ND 0.035 8/2/22 1:11 BRFND0.7020.140.031 0.12 1,2-Dichloroethane 0.082 0.035 8/2/22 1:11 BRF0.33 0.7020.140.032 0.13 1,1-Dichloroethylene ND 0.035 8/2/22 1:11 BRFND0.7020.140.027 0.11 cis-1,2-Dichloroethylene ND 0.035 8/2/22 1:11 BRFND0.7020.140.026 0.10 trans-1,2-Dichloroethylene 0.030 0.035 8/2/22 1:11 BRFJ0.12 0.7020.140.028 0.11 1,2-Dichloropropane 0.14 0.035 8/2/22 1:11 BRF0.63 0.7020.160.019 0.088 cis-1,3-Dichloropropene ND 0.035 8/2/22 1:11 BRFND0.7020.160.018 0.082 trans-1,3-Dichloropropene ND 0.035 8/2/22 1:11 BRFND0.7020.160.018 0.082 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114)ND 0.035 8/2/22 1:11 BRFND0.7020.250.035 0.24 1,4-Dioxane ND 0.35 8/2/22 1:11 BRFND0.7021.30.029 0.10 Ethanol 56 4.0 8/2/22 9:18 BRF110 27.51.8 3.3 Ethyl Acetate 1.2 0.35 8/2/22 1:11 BRF4.3 0.7021.30.18 0.64 Ethylbenzene 1.1 0.035 8/2/22 1:11 BRF5.0 0.7020.150.020 0.089 4-Ethyltoluene 0.061 0.035 8/2/22 1:11 BRF0.30 0.7020.170.022 0.11 Heptane 0.13 0.035 8/2/22 1:11 BRF0.52 0.7020.140.022 0.092 Hexachlorobutadiene ND 0.035 8/2/22 1:11 BRFND0.7020.370.029 0.31 Hexane 0.46 1.4 8/2/22 1:11 BRFJ1.6 0.7024.90.18 0.64 2-Hexanone (MBK)0.20 0.035 8/2/22 1:11 BRF0.82 0.7020.140.018 0.072 Isopropanol 19 1.4 8/2/22 1:11 BRF47 0.7023.40.24 0.60 Methyl tert-Butyl Ether (MTBE)ND 0.035 8/2/22 1:11 BRFND0.7020.130.027 0.098 Methylene Chloride 2.0 0.35 8/2/22 1:11 BRF7.0 0.7021.20.16 0.57 4-Methyl-2-pentanone (MIBK)0.20 0.035 8/2/22 1:11 BRF0.81 0.7020.140.019 0.077 Naphthalene 0.13 0.035 8/2/22 1:11 BRF0.66 0.7020.180.026 0.14 Propene ND 1.4 8/2/22 1:11 BRFND0.7022.40.31 0.53 Styrene 1.8 0.035 8/2/22 1:11 BRF7.8 0.7020.150.018 0.079 1,1,2,2-Tetrachloroethane ND 0.035 8/2/22 1:11 BRFND0.7020.240.019 0.13 Page 24 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: 1900 Continental Blvd, Charlotte Date Received: 7/22/2022 Work Order: 22G1209Sample Description/Location: Field Sample #: IAS-Dup Sample ID: 22G1209-11 Sample Matrix: Indoor air Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -7 Receipt Vacuum(in Hg): -8.8 Sampled: 7/18/2022 00:00 Canister ID: 2015 Flow Controller ID: 4623 Sub Description/Location: Canister Size: 6 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 8 hr RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Tetrachloroethylene 0.044 0.035 8/2/22 1:11 BRF0.30 0.7020.240.027 0.18 Tetrahydrofuran 0.060 0.35 8/2/22 1:11 BRFJ0.18 0.7021.00.058 0.17 Toluene 4.2 0.035 8/2/22 1:11 BRF16 0.7020.130.020 0.076 1,2,4-Trichlorobenzene ND 0.035 8/2/22 1:11 BRFND0.7020.260.033 0.24 1,1,1-Trichloroethane ND 0.035 8/2/22 1:11 BRFND0.7020.190.028 0.15 1,1,2-Trichloroethane ND 0.035 8/2/22 1:11 BRFND0.7020.190.025 0.13 Trichloroethylene ND 0.035 8/2/22 1:11 BRFND0.7020.190.024 0.13 Trichlorofluoromethane (Freon 11)2.8 0.14 8/2/22 1:11 BRF16 0.7020.790.041 0.23 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)0.10 0.14 8/2/22 1:11 BRFJ0.77 0.7021.10.039 0.30 1,2,4-Trimethylbenzene 0.20 0.035 8/2/22 1:11 BRF0.98 0.7020.170.016 0.076 1,3,5-Trimethylbenzene 0.060 0.035 8/2/22 1:11 BRF0.29 0.7020.170.019 0.091 Vinyl Acetate ND 0.70 8/2/22 1:11 BRFND0.7022.50.19 0.66 Vinyl Chloride ND 0.035 8/2/22 1:11 BRFND0.7020.0900.032 0.081 m&p-Xylene 3.4 0.070 8/2/22 1:11 BRF15 0.7020.300.039 0.17 o-Xylene 1.5 0.035 8/2/22 1:11 BRF6.6 0.7020.150.018 0.078 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)97.2 8/2/22 9:1870-130 4-Bromofluorobenzene (1)107 8/2/22 1:1170-130 Page 25 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B314355 - TO-15 Prep Blank (B314355-BLK1)Prepared & Analyzed: 08/01/22 0.80NDAcetone 0.80NDEthanol 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)97.97.83 LCS (B314355-BS1)Prepared & Analyzed: 08/01/22 5.00 70-1301075.36Acetone 5.00 70-1301055.27Ethanol 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1028.14 Batch B314360 - TO-15 Prep Blank (B314360-BLK1)Prepared & Analyzed: 08/01/22 1.4NDAcetone 0.035NDBenzene 0.035NDBenzyl chloride 0.035NDBromodichloromethane 0.035NDBromoform 0.035NDBromomethane 0.035ND1,3-Butadiene 1.4ND2-Butanone (MEK) 0.35NDCarbon Disulfide 0.035NDCarbon Tetrachloride 0.035NDChlorobenzene 0.035NDChloroethane 0.035NDChloroform 0.070NDChloromethane 0.035NDCyclohexane 0.035NDDibromochloromethane 0.035ND1,2-Dibromoethane (EDB) 0.035ND1,2-Dichlorobenzene 0.035ND1,3-Dichlorobenzene 0.035ND1,4-Dichlorobenzene 0.035NDDichlorodifluoromethane (Freon 12) 0.035ND1,1-Dichloroethane 0.035ND1,2-Dichloroethane 0.035ND1,1-Dichloroethylene 0.035NDcis-1,2-Dichloroethylene 0.035NDtrans-1,2-Dichloroethylene 0.035ND1,2-Dichloropropane 0.035NDcis-1,3-Dichloropropene 0.035NDtrans-1,3-Dichloropropene 0.035ND1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 0.35ND1,4-Dioxane 1.4NDEthanol 0.35NDEthyl Acetate 0.035NDEthylbenzene Page 26 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B314360 - TO-15 Prep Blank (B314360-BLK1)Prepared & Analyzed: 08/01/22 0.035ND4-Ethyltoluene 0.035NDHeptane 0.035NDHexachlorobutadiene 1.4NDHexane 0.035ND2-Hexanone (MBK) 1.4NDIsopropanol 0.035NDMethyl tert-Butyl Ether (MTBE) 0.35NDMethylene Chloride 0.035ND4-Methyl-2-pentanone (MIBK) 0.035NDNaphthalene 1.4NDPropene 0.035NDStyrene 0.035ND1,1,2,2-Tetrachloroethane 0.035NDTetrachloroethylene 0.35NDTetrahydrofuran 0.035NDToluene 0.035ND1,2,4-Trichlorobenzene 0.035ND1,1,1-Trichloroethane 0.035ND1,1,2-Trichloroethane 0.035NDTrichloroethylene 0.14NDTrichlorofluoromethane (Freon 11) 0.14ND1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 0.035ND1,2,4-Trimethylbenzene 0.035ND1,3,5-Trimethylbenzene 0.70NDVinyl Acetate 0.035NDVinyl Chloride 0.070NDm&p-Xylene 0.035NDo-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1028.13 Page 27 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B314360 - TO-15 Prep LCS (B314360-BS1)Prepared & Analyzed: 08/01/22 5.00 70-13095.64.78Acetone 5.00 70-13097.34.86Benzene 5.00 70-13085.24.26Benzyl chloride 5.00 70-13095.84.79Bromodichloromethane 5.00 70-13099.84.99Bromoform 5.00 70-1301195.93Bromomethane 5.00 70-1301075.341,3-Butadiene 5.00 70-13098.44.922-Butanone (MEK) 5.00 70-1301065.31Carbon Disulfide 5.00 70-13089.74.48Carbon Tetrachloride 5.00 70-13098.34.91Chlorobenzene 5.00 70-1301155.73Chloroethane 5.00 70-1301025.12Chloroform 5.00 70-1301045.22Chloromethane 5.00 70-13096.54.82Cyclohexane 5.00 70-13095.34.76Dibromochloromethane 5.00 70-13099.44.971,2-Dibromoethane (EDB) 5.00 70-1301025.081,2-Dichlorobenzene 5.00 70-1301045.221,3-Dichlorobenzene 5.00 70-1301035.171,4-Dichlorobenzene 5.00 70-1301115.54Dichlorodifluoromethane (Freon 12) 5.00 70-1301015.051,1-Dichloroethane 5.00 70-1301035.161,2-Dichloroethane 5.00 70-1301065.281,1-Dichloroethylene 5.00 70-1301025.09cis-1,2-Dichloroethylene 5.00 70-1301035.16trans-1,2-Dichloroethylene 5.00 70-13094.94.741,2-Dichloropropane 5.00 70-13091.34.57cis-1,3-Dichloropropene 5.00 70-13092.64.63trans-1,3-Dichloropropene 5.00 70-1301085.401,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 5.00 70-13098.74.941,4-Dioxane 5.00 70-1301195.96Ethanol 5.00 70-13097.64.88Ethyl Acetate 5.00 70-13096.94.85Ethylbenzene 5.00 70-1301015.054-Ethyltoluene 5.00 70-13093.04.65Heptane 5.00 70-1301035.16Hexachlorobutadiene 5.00 70-13096.34.82Hexane 5.00 70-13090.74.542-Hexanone (MBK) 5.00 70-13093.34.66Isopropanol 5.00 70-1301005.01Methyl tert-Butyl Ether (MTBE) 5.00 70-13089.74.49Methylene Chloride 5.00 70-13094.04.704-Methyl-2-pentanone (MIBK) 5.00 70-1301065.30Naphthalene 5.00 70-13081.14.06Propene 5.00 70-1301015.06Styrene Page 28 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B314360 - TO-15 Prep LCS (B314360-BS1)Prepared & Analyzed: 08/01/22 5.00 70-13098.14.911,1,2,2-Tetrachloroethane 5.00 70-13097.34.87Tetrachloroethylene 5.00 70-13096.34.82Tetrahydrofuran 5.00 70-13096.54.82Toluene 5.00 70-1301055.251,2,4-Trichlorobenzene 5.00 70-13090.04.501,1,1-Trichloroethane 5.00 70-13099.34.961,1,2-Trichloroethane 5.00 70-13096.24.81Trichloroethylene 5.00 70-1301226.10Trichlorofluoromethane (Freon 11) 5.00 70-1301075.341,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 5.00 70-13099.64.981,2,4-Trimethylbenzene 5.00 70-1301015.031,3,5-Trimethylbenzene 5.00 70-13081.54.08Vinyl Acetate 5.00 70-1301085.40Vinyl Chloride 10.0 70-13096.69.66m&p-Xylene 5.00 70-13097.74.88o-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1058.43 Duplicate (B314360-DUP1)Prepared & Analyzed: 08/01/22 Source: 22G1209-02 1.4 6.1 253.775.8Acetone 3.314 0.035 0.084 253.310.086Benzene 0.110.28 0.035 ND 25NDBenzyl chloride 0.18ND 0.035 ND 25NDBromodichloromethane0.24ND 0.035 ND 25NDBromoform0.36ND 0.035 0.070 255.830.074Bromomethane 0.140.29 0.035 ND 25ND1,3-Butadiene 0.078ND 1.4 3.0 250.2773.02-Butanone (MEK)4.19.0 0.35 0.074 25 J1.890.075Carbon Disulfide 1.10.23 0.035 0.055 251.270.055Carbon Tetrachloride 0.220.35 0.035 ND 25NDChlorobenzene0.16ND 0.035 ND 25NDChloroethane0.093ND 0.035 ND 25NDChloroform0.17ND 0.070 0.71 253.200.69Chloromethane 0.141.4 0.035 ND 25NDCyclohexane0.12ND 0.035 ND 25NDDibromochloromethane0.30ND 0.035 ND 25ND1,2-Dibromoethane (EDB)0.27ND 0.035 ND 25ND1,2-Dichlorobenzene 0.21ND 0.035 ND 25ND1,3-Dichlorobenzene 0.21ND 0.035 ND 25ND1,4-Dichlorobenzene 0.21ND 0.035 0.20 2516.30.17Dichlorodifluoromethane (Freon 12)0.170.82 0.035 ND 25ND1,1-Dichloroethane 0.14ND 0.035 ND 25ND1,2-Dichloroethane 0.14ND 0.035 ND 25ND1,1-Dichloroethylene 0.14ND 0.035 ND 25NDcis-1,2-Dichloroethylene 0.14ND 0.035 ND 25NDtrans-1,2-Dichloroethylene 0.14ND 0.035 ND 25ND1,2-Dichloropropane 0.16ND Page 29 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B314360 - TO-15 Prep Duplicate (B314360-DUP1)Prepared & Analyzed: 08/01/22 Source: 22G1209-02 0.035 ND 25NDcis-1,3-Dichloropropene 0.16ND 0.035 ND 25NDtrans-1,3-Dichloropropene 0.16ND 0.035 ND 25ND1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 0.25ND 0.35 ND 25ND1,4-Dioxane 1.3ND 1.4 18 250.56918Ethanol2.634 0.35 0.83 250.5080.83Ethyl Acetate 1.33.0 0.035 0.72 251.440.73Ethylbenzene 0.153.2 0.035 ND 25ND4-Ethyltoluene 0.17ND 0.035 0.076 2510.50.084Heptane 0.140.35 0.035 ND 25NDHexachlorobutadiene0.37ND 1.4 0.44 25 J0.7880.45Hexane 4.91.6 0.035 ND 25ND2-Hexanone (MBK)0.14ND 1.4 1.3 25 J0.8761.3Isopropanol 3.43.2 0.035 ND 25NDMethyl tert-Butyl Ether (MTBE)0.13ND 0.35 ND 25NDMethylene Chloride 1.2ND 0.035 0.076 2511.30.0864-Methyl-2-pentanone (MIBK)0.140.35 0.035 0.050 252.780.051Naphthalene 0.180.27 1.4 ND 25NDPropene2.4ND 0.035 1.2 250.7451.2Styrene 0.155.2 0.035 ND 25ND1,1,2,2-Tetrachloroethane 0.24ND 0.035 ND 25NDTetrachloroethylene0.24ND 0.35 ND 25NDTetrahydrofuran1.0ND 0.035 4.0 251.244.0Toluene 0.1315 0.035 ND 25ND1,2,4-Trichlorobenzene 0.26ND 0.035 ND 25ND1,1,1-Trichloroethane 0.19ND 0.035 ND 25ND1,1,2-Trichloroethane 0.19ND 0.035 ND 25NDTrichloroethylene0.19ND 0.14 1.1 257.770.97Trichlorofluoromethane (Freon 11)0.795.5 0.14 0.066 25 J3.240.0641,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 1.10.49 0.035 0.039 253.570.0401,2,4-Trimethylbenzene 0.170.20 0.035 ND 25ND1,3,5-Trimethylbenzene 0.17ND 0.70 ND 25NDVinyl Acetate 2.5ND 0.035 ND 25NDVinyl Chloride 0.090ND 0.070 2.2 252.162.2m&p-Xylene 0.309.5 0.035 0.90 252.230.92o-Xylene 0.154.0 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1018.09 Page 30 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Note: Blank Subtraction is not performed unless otherwise noted *QC result is outside of established limits. †Wide recovery limits established for difficult compound. ‡Wide RPD limits established for difficult compound. #Data exceeded client recommended or regulatory level RL Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference LCS Laboratory Control Sample Laboratory Control SampleLCS Dup Duplicate Laboratory Control Sample MS Matrix Spike Sample MS Dup Duplicate Matrix Spike Sample REC Recovery QC Quality Control ppbv Parts per billion volume EPA United States Environmental Protection Agency Percent Recovery% REC ND Not Detected Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the calculation which have not been rounded. Not ApplicableN/A DL Detection Limit Not CalculatedNC LFB/LCS Lab Fortified Blank/Lab Control Sample ORP Oxidation-Reduction Potential Not dry weight correctedwet Percent weight% wt KilogramKg Gramg Milligrammg Microgramµg Nanogramng LiterL MillilitermL Microliter L Cubic Meterm3 Extractable Petroleum HydrocarbonsEPH Volatile Petroleum HydrocarbonsVPH Air Petroleum HydrocarbonsAPH Flame Ionization DetectorFID Photo Ionization DetectorPID FLAG/QUALIFIER SUMMARY Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated concentration (CLP J-Flag). J ANALYST Thomas P. HniteckiTPH Rebecca FaustRLF Raisa A. PetraitisRAP PDF Management StationSTATION Kerry K. McGeeKKM Brittany R. FiskBRF Page 31 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q Initial Cal Check (S069304-ICV1 )Lab File ID: K22A075019.D Analyzed: 03/16/22 23:55 Bromochloromethane (1)104138 2.987 104138 2.987 60 - 140100 0.0000 +/-0.50 1,4-Difluorobenzene (1)315817 3.584 315817 3.584 60 - 140100 0.0000 +/-0.50 Chlorobenzene-d5 (1)233658 5.159 233658 5.159 60 - 140100 0.0000 +/-0.50 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q Initial Cal Check (S074615-ICV1 )Lab File ID: G22A210019.D Analyzed: 07/30/22 00:36 Bromochloromethane (1)1239190 8.307 1239190 8.307 60 - 140100 0.0000 +/-0.50 1,4-Difluorobenzene (1)2932256 10.081 2932256 10.081 60 - 140100 0.0000 +/-0.50 Chlorobenzene-d5 (1)2672882 14.452 2672882 14.452 60 - 140100 0.0000 +/-0.50 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q Calibration Check (S074691-CCV1 )Lab File ID: K22A213004.D Analyzed: 08/01/22 09:56 Bromochloromethane (1)112645 2.996 112645 2.996 60 - 140100 0.0000 +/-0.50 1,4-Difluorobenzene (1)360029 3.588 360029 3.588 60 - 140100 0.0000 +/-0.50 Chlorobenzene-d5 (1)256539 5.163 256539 5.163 60 - 140100 0.0000 +/-0.50 LCS (B314355-BS1 )Lab File ID: K22A213005.D Analyzed: 08/01/22 10:24 Bromochloromethane (1)113638 2.996 112645 2.996 60 - 140101 0.0000 +/-0.50 1,4-Difluorobenzene (1)360160 3.588 360029 3.588 60 - 140100 0.0000 +/-0.50 Chlorobenzene-d5 (1)263672 5.163 256539 5.163 60 - 140103 0.0000 +/-0.50 Blank (B314355-BLK1 )Lab File ID: K22A213008.D Analyzed: 08/01/22 12:04 Bromochloromethane (1)112253 2.996 112645 2.996 60 - 140100 0.0000 +/-0.50 1,4-Difluorobenzene (1)339911 3.588 360029 3.588 60 - 14094 0.0000 +/-0.50 Chlorobenzene-d5 (1)247248 5.163 256539 5.163 60 - 14096 0.0000 +/-0.50 IAS-10 (22G1209-10RE1 )Lab File ID: K22A213028.D Analyzed: 08/02/22 08:47 Bromochloromethane (1)110007 3.001 112645 2.996 60 - 14098 0.0050 +/-0.50 1,4-Difluorobenzene (1)328129 3.588 360029 3.588 60 - 14091 0.0000 +/-0.50 Chlorobenzene-d5 (1)244577 5.163 256539 5.163 60 - 14095 0.0000 +/-0.50 IAS-Dup (22G1209-11RE1 )Lab File ID: K22A213029.D Analyzed: 08/02/22 09:18 Bromochloromethane (1)110855 3.001 112645 2.996 60 - 14098 0.0050 +/-0.50 1,4-Difluorobenzene (1)326124 3.593 360029 3.588 60 - 14091 0.0050 +/-0.50 Chlorobenzene-d5 (1)248237 5.163 256539 5.163 60 - 14097 0.0000 +/-0.50 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 Page 32 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q Calibration Check (S074704-CCV1 )Lab File ID: G22A213004.D Analyzed: 08/01/22 10:30 Bromochloromethane (1)1232054 8.307 1232054 8.307 60 - 140100 0.0000 +/-0.50 1,4-Difluorobenzene (1)2979530 10.081 2979530 10.081 60 - 140100 0.0000 +/-0.50 Chlorobenzene-d5 (1)2715403 14.452 2715403 14.452 60 - 140100 0.0000 +/-0.50 LCS (B314360-BS1 )Lab File ID: G22A213005.D Analyzed: 08/01/22 11:09 Bromochloromethane (1)1224491 8.313 1232054 8.307 60 - 14099 0.0060 +/-0.50 1,4-Difluorobenzene (1)3008227 10.087 2979530 10.081 60 - 140101 0.0060 +/-0.50 Chlorobenzene-d5 (1)2738005 14.452 2715403 14.452 60 - 140101 0.0000 +/-0.50 Blank (B314360-BLK1 )Lab File ID: G22A213008.D Analyzed: 08/01/22 13:18 Bromochloromethane (1)1091296 8.313 1232054 8.307 60 - 14089 0.0060 +/-0.50 1,4-Difluorobenzene (1)2580939 10.081 2979530 10.081 60 - 14087 0.0000 +/-0.50 Chlorobenzene-d5 (1)2332887 14.452 2715403 14.452 60 - 14086 0.0000 +/-0.50 IAS-1 (22G1209-01 )Lab File ID: G22A213011.D Analyzed: 08/01/22 15:44 Bromochloromethane (1)1180123 8.307 1232054 8.307 60 - 14096 0.0000 +/-0.50 1,4-Difluorobenzene (1)2926910 10.081 2979530 10.081 60 - 14098 0.0000 +/-0.50 Chlorobenzene-d5 (1)2663263 14.452 2715403 14.452 60 - 14098 0.0000 +/-0.50 IAS-2 (22G1209-02 )Lab File ID: G22A213012.D Analyzed: 08/01/22 16:31 Bromochloromethane (1)1121098 8.307 1232054 8.307 60 - 14091 0.0000 +/-0.50 1,4-Difluorobenzene (1)2680675 10.081 2979530 10.081 60 - 14090 0.0000 +/-0.50 Chlorobenzene-d5 (1)2444504 14.452 2715403 14.452 60 - 14090 0.0000 +/-0.50 Duplicate (B314360-DUP1 )Lab File ID: G22A213013.D Analyzed: 08/01/22 17:20 Bromochloromethane (1)1043196 8.307 1232054 8.307 60 - 14085 0.0000 +/-0.50 1,4-Difluorobenzene (1)2392875 10.081 2979530 10.081 60 - 14080 0.0000 +/-0.50 Chlorobenzene-d5 (1)2185275 14.452 2715403 14.452 60 - 14080 0.0000 +/-0.50 IAS-3 (22G1209-03 )Lab File ID: G22A213014.D Analyzed: 08/01/22 18:07 Bromochloromethane (1)1143201 8.307 1232054 8.307 60 - 14093 0.0000 +/-0.50 1,4-Difluorobenzene (1)2767377 10.081 2979530 10.081 60 - 14093 0.0000 +/-0.50 Chlorobenzene-d5 (1)2528710 14.452 2715403 14.452 60 - 14093 0.0000 +/-0.50 IAS-4 (22G1209-04 )Lab File ID: G22A213015.D Analyzed: 08/01/22 18:54 Bromochloromethane (1)1207768 8.307 1232054 8.307 60 - 14098 0.0000 +/-0.50 1,4-Difluorobenzene (1)2975586 10.081 2979530 10.081 60 - 140100 0.0000 +/-0.50 Chlorobenzene-d5 (1)2728855 14.452 2715403 14.452 60 - 140100 0.0000 +/-0.50 IAS-5 (22G1209-05 )Lab File ID: G22A213016.D Analyzed: 08/01/22 19:42 Bromochloromethane (1)1144569 8.307 1232054 8.307 60 - 14093 0.0000 +/-0.50 1,4-Difluorobenzene (1)2786066 10.081 2979530 10.081 60 - 14094 0.0000 +/-0.50 Chlorobenzene-d5 (1)2565994 14.452 2715403 14.452 60 - 14094 0.0000 +/-0.50 Page 33 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q IAS-6 (22G1209-06 )Lab File ID: G22A213017.D Analyzed: 08/01/22 20:29 Bromochloromethane (1)1181909 8.307 1232054 8.307 60 - 14096 0.0000 +/-0.50 1,4-Difluorobenzene (1)2896676 10.081 2979530 10.081 60 - 14097 0.0000 +/-0.50 Chlorobenzene-d5 (1)2666010 14.452 2715403 14.452 60 - 14098 0.0000 +/-0.50 IAS-7 (22G1209-07 )Lab File ID: G22A213018.D Analyzed: 08/01/22 21:16 Bromochloromethane (1)1147308 8.307 1232054 8.307 60 - 14093 0.0000 +/-0.50 1,4-Difluorobenzene (1)2812764 10.081 2979530 10.081 60 - 14094 0.0000 +/-0.50 Chlorobenzene-d5 (1)2570713 14.446 2715403 14.452 60 - 14095 -0.0060 +/-0.50 IAS-8 (22G1209-08 )Lab File ID: G22A213019.D Analyzed: 08/01/22 22:04 Bromochloromethane (1)1054652 8.307 1232054 8.307 60 - 14086 0.0000 +/-0.50 1,4-Difluorobenzene (1)2442239 10.081 2979530 10.081 60 - 14082 0.0000 +/-0.50 Chlorobenzene-d5 (1)2238671 14.446 2715403 14.452 60 - 14082 -0.0060 +/-0.50 IAS-9 (22G1209-09 )Lab File ID: G22A213021.D Analyzed: 08/01/22 23:32 Bromochloromethane (1)1095184 8.307 1232054 8.307 60 - 14089 0.0000 +/-0.50 1,4-Difluorobenzene (1)2588487 10.081 2979530 10.081 60 - 14087 0.0000 +/-0.50 Chlorobenzene-d5 (1)2447842 14.446 2715403 14.452 60 - 14090 -0.0060 +/-0.50 IAS-10 (22G1209-10 )Lab File ID: G22A213022.D Analyzed: 08/02/22 00:23 Bromochloromethane (1)1066222 8.307 1232054 8.307 60 - 14087 0.0000 +/-0.50 1,4-Difluorobenzene (1)2499372 10.081 2979530 10.081 60 - 14084 0.0000 +/-0.50 Chlorobenzene-d5 (1)2294922 14.446 2715403 14.452 60 - 14085 -0.0060 +/-0.50 IAS-Dup (22G1209-11 )Lab File ID: G22A213023.D Analyzed: 08/02/22 01:11 Bromochloromethane (1)1165857 8.307 1232054 8.307 60 - 14095 0.0000 +/-0.50 1,4-Difluorobenzene (1)2927112 10.081 2979530 10.081 60 - 14098 0.0000 +/-0.50 Chlorobenzene-d5 (1)2688414 14.446 2715403 14.452 60 - 14099 -0.0060 +/-0.50 IAS-3 (22G1209-03RE1 )Lab File ID: G22A213024.D Analyzed: 08/02/22 07:03 Bromochloromethane (1)1136088 8.307 1232054 8.307 60 - 14092 0.0000 +/-0.50 1,4-Difluorobenzene (1)2810584 10.081 2979530 10.081 60 - 14094 0.0000 +/-0.50 Chlorobenzene-d5 (1)2540383 14.446 2715403 14.452 60 - 14094 -0.0060 +/-0.50 IAS-4 (22G1209-04RE1 )Lab File ID: G22A213025.D Analyzed: 08/02/22 07:45 Bromochloromethane (1)1113101 8.307 1232054 8.307 60 - 14090 0.0000 +/-0.50 1,4-Difluorobenzene (1)2678578 10.081 2979530 10.081 60 - 14090 0.0000 +/-0.50 Chlorobenzene-d5 (1)2427552 14.446 2715403 14.452 60 - 14089 -0.0060 +/-0.50 IAS-5 (22G1209-05RE1 )Lab File ID: G22A213026.D Analyzed: 08/02/22 08:27 Bromochloromethane (1)1029147 8.307 1232054 8.307 60 - 14084 0.0000 +/-0.50 1,4-Difluorobenzene (1)2367380 10.081 2979530 10.081 60 - 14079 0.0000 +/-0.50 Chlorobenzene-d5 (1)1969959 14.452 2715403 14.452 60 - 14073 0.0000 +/-0.50 Page 34 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 INTERNAL STANDARD AREA AND RT SUMMARY EPA TO-15 RTResponseInternal Standard Area %RT DiffResponse Reference RT Reference Area % Limits RT Diff Limit Q IAS-6 (22G1209-06RE1 )Lab File ID: G22A213027.D Analyzed: 08/02/22 09:09 Bromochloromethane (1)999778 8.307 1232054 8.307 60 - 14081 0.0000 +/-0.50 1,4-Difluorobenzene (1)2227826 10.081 2979530 10.081 60 - 14075 0.0000 +/-0.50 Chlorobenzene-d5 (1)1905157 14.452 2715403 14.452 60 - 14070 0.0000 +/-0.50 Page 35 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CONTINUING CALIBRATION CHECK EPA TO-15 S074691-CCV1 COMPOUND TYPE CCV MIN (#)CCV LIMIT (#)CCV ICAL CONC. (ppbv)% DIFF / DRIFTRESPONSE FACTOR STD 1.047439A 4.6 305.23 1.0015045.00Acetone 0.2450033A 4.3 305.22 0.23481145.00Ethanol * Values outside of QC limits # Column to be used to flag Response Factor and %Diff/Drift values with an asterisk Page 36 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CONTINUING CALIBRATION CHECK EPA TO-15 S074704-CCV1 COMPOUND TYPE CCV MIN (#)CCV LIMIT (#)CCV ICAL CONC. (ppbv)% DIFF / DRIFTRESPONSE FACTOR STD 1.17358A -7.7 304.62 1.2708475.00Acetone 0.8353602A -3.6 304.82 0.86662195.00Benzene 0.8683205A -16.2 304.19 1.0362725.00Benzyl chloride 0.6122131A -4.5 304.77 0.64114175.00Bromodichloromethane 0.5204861A -0.6 304.97 0.52342195.00Bromoform 0.5815148A 19.9 305.99 0.4851555.00Bromomethane 0.5435866A 7.8 305.39 0.5040795.001,3-Butadiene 1.338572A -5.6 304.72 1.4181885.002-Butanone (MEK) 1.792064A 0.03 305.00 1.7914825.00Carbon Disulfide 0.4385041A -11.8 304.41 0.49731335.00Carbon Tetrachloride 0.78414A -1.4 304.93 0.79541945.00Chlorobenzene 0.3425356A 10.5 305.53 0.30990335.00Chloroethane 1.439668A 0.7 305.04 1.4292475.00Chloroform 0.6070734A 3.9 305.19 0.58446715.00Chloromethane 0.3387401A -5.9 304.71 0.35979655.00Cyclohexane 0.5365839A -5.2 304.74 0.56612935.00Dibromochloromethane 0.5679098A -0.2 304.99 0.56903245.001,2-Dibromoethane (EDB) 0.6622263A 0.8 305.04 0.65700675.001,2-Dichlorobenzene 0.727493A 4.8 305.24 0.69423665.001,3-Dichlorobenzene 0.7089134A 2.4 305.12 0.69222745.001,4-Dichlorobenzene 1.56043A 2.1 305.10 1.5289655.00Dichlorodifluoromethane (Freon 12) 1.208143A -2.1 304.89 1.2346255.001,1-Dichloroethane 0.945504A 0.3 305.02 0.94242875.001,2-Dichloroethane 1.149807A 3.2 305.16 1.1145815.001,1-Dichloroethylene 0.9074511A -0.2 304.99 0.90947635.00cis-1,2-Dichloroethylene 0.9368862A 0.4 305.02 0.93347655.00trans-1,2-Dichloroethylene 0.3197347A -5.6 304.72 0.33882665.001,2-Dichloropropane 0.4752352A -6.2 304.69 0.50677845.00cis-1,3-Dichloropropene 0.4157697A -8.6 304.57 0.45481725.00trans-1,3-Dichloropropene 1.775478A 12.6 305.63 1.5766275.001,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) 0.170849A -8.9 304.56 0.18751595.001,4-Dioxane 0.2426829A -2.1 304.90 0.24788095.00Ethanol 0.1976251A -7.9 304.61 0.21453665.00Ethyl Acetate 1.415156A -2.0 304.90 1.4445685.00Ethylbenzene 1.430253A 0.3 305.01 1.4265675.004-Ethyltoluene 0.2622228A -6.0 304.70 0.27889925.00Heptane 0.4969664A -0.5 304.97 0.49962795.00Hexachlorobutadiene 0.8275559A -6.7 304.66 0.87430965.00Hexane Page 37 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CONTINUING CALIBRATION CHECK EPA TO-15 S074704-CCV1 COMPOUND TYPE CCV MIN (#)CCV LIMIT (#)CCV ICAL CONC. (ppbv)% DIFF / DRIFTRESPONSE FACTOR STD 0.7213886A -10.4 304.48 0.80535565.002-Hexanone (MBK) 1.443269A 2.8 305.14 1.4042165.00Isopropanol 1.777186A -1.8 304.91 1.8101875.00Methyl tert-Butyl Ether (MTBE) 0.7957729A -11.5 304.42 0.89931975.00Methylene Chloride 0.7038017A -5.2 304.74 0.74237715.004-Methyl-2-pentanone (MIBK) 0.998144A -0.9 304.96 1.0071655.00Naphthalene 0.478631A -17.5 304.12 0.58020455.00Propene 0.8101256A 2.0 305.10 0.79433815.00Styrene 0.8812847A -0.4 304.98 0.88478825.001,1,2,2-Tetrachloroethane 0.4582651A -2.9 304.86 0.47184165.00Tetrachloroethylene 0.2951793A -4.7 304.76 0.30987365.00Tetrahydrofuran 1.092651A -4.0 304.80 1.1384785.00Toluene 0.5176755A 1.0 305.05 0.512725.001,2,4-Trichlorobenzene 0.517258A -8.0 304.60 0.56223785.001,1,1-Trichloroethane 0.3703471A -2.6 304.87 0.38022255.001,1,2-Trichloroethane 0.3616189A -4.7 304.76 0.37950795.00Trichloroethylene 1.454464A 18.1 305.91 1.2313255.00Trichlorofluoromethane (Freon 11) 1.307745A 3.8 305.19 1.2594145.001,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 1.170537A -0.09 305.00 1.1715845.001,2,4-Trimethylbenzene 1.184246A 0.4 305.02 1.178995.001,3,5-Trimethylbenzene 1.555051A -17.7 304.11 1.8897935.00Vinyl Acetate 0.699433A 5.1 305.26 0.6653875.00Vinyl Chloride 1.122337A -2.5 309.75 1.15087910.0m&p-Xylene 1.123755A -2.4 304.88 1.1513845.00o-Xylene * Values outside of QC limits # Column to be used to flag Response Factor and %Diff/Drift values with an asterisk Page 38 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report EPA TO-15 in Air AIHA,NY,ME,NHAcetone AIHA,FL,NJ,NY,ME,NH,VABenzene AIHA,FL,NJ,NY,ME,NH,VABenzyl chloride AIHA,NJ,NY,ME,NH,VABromodichloromethane AIHA,NJ,NY,ME,NH,VABromoform AIHA,FL,NJ,NY,ME,NHBromomethane AIHA,NJ,NY,ME,NH,VA1,3-Butadiene AIHA,FL,NJ,NY,ME,NH,VA2-Butanone (MEK) AIHA,NJ,NY,ME,NH,VACarbon Disulfide AIHA,FL,NJ,NY,ME,NH,VACarbon Tetrachloride AIHA,FL,NJ,NY,ME,NH,VAChlorobenzene AIHA,FL,NJ,NY,ME,NH,VAChloroethane AIHA,FL,NJ,NY,ME,NH,VAChloroform AIHA,FL,NJ,NY,ME,NH,VAChloromethane AIHA,NJ,NY,ME,NH,VACyclohexane AIHA,NY,ME,NHDibromochloromethane AIHA,NJ,NY,ME,NH1,2-Dibromoethane (EDB) AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichlorobenzene AIHA,NJ,NY,ME,NH1,3-Dichlorobenzene AIHA,FL,NJ,NY,ME,NH,VA1,4-Dichlorobenzene AIHA,NY,ME,NHDichlorodifluoromethane (Freon 12) AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethylene AIHA,FL,NY,ME,NH,VAcis-1,2-Dichloroethylene AIHA,NJ,NY,ME,NH,VAtrans-1,2-Dichloroethylene AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichloropropane AIHA,FL,NJ,NY,ME,NH,VAcis-1,3-Dichloropropene AIHA,NY,ME,NHtrans-1,3-Dichloropropene AIHA,NJ,NY,ME,NH,VA1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon 114) AIHA,NJ,NY,ME,NH,VA1,4-Dioxane AIHAEthanol AIHAEthyl Acetate AIHA,FL,NJ,NY,ME,NH,VAEthylbenzene AIHA,NJ4-Ethyltoluene AIHA,NJ,NY,ME,NH,VAHeptane AIHA,NJ,NY,ME,NH,VAHexachlorobutadiene AIHA,FL,NJ,NY,ME,NH,VAHexane AIHA2-Hexanone (MBK) AIHA,NY,ME,NHIsopropanol AIHA,FL,NJ,NY,ME,NH,VAMethyl tert-Butyl Ether (MTBE) AIHA,FL,NJ,NY,ME,NH,VAMethylene Chloride AIHA,FL,NJ,NY,ME,NH4-Methyl-2-pentanone (MIBK) NY,ME,NHNaphthalene AIHAPropene AIHA,FL,NJ,NY,ME,NH,VAStyrene AIHA,FL,NJ,NY,ME,NH,VA1,1,2,2-Tetrachloroethane Page 39 of 44 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report EPA TO-15 in Air AIHA,FL,NJ,NY,ME,NH,VATetrachloroethylene AIHATetrahydrofuran AIHA,FL,NJ,NY,ME,NH,VAToluene AIHA,NJ,NY,ME,NH,VA1,2,4-Trichlorobenzene AIHA,FL,NJ,NY,ME,NH,VA1,1,1-Trichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1,2-Trichloroethane AIHA,FL,NJ,NY,ME,NH,VATrichloroethylene AIHA,NY,ME,NHTrichlorofluoromethane (Freon 11) AIHA,NJ,NY,ME,NH,VA1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) AIHA,NJ,NY,ME,NH1,2,4-Trimethylbenzene AIHA,NJ,NY,ME,NH1,3,5-Trimethylbenzene AIHA,FL,NJ,NY,ME,NH,VAVinyl Acetate AIHA,FL,NJ,NY,ME,NH,VAVinyl Chloride AIHA,FL,NJ,NY,ME,NH,VAm&p-Xylene AIHA,FL,NJ,NY,ME,NH,VAo-Xylene Con-Test, a Pace Environmental Laboratory, operates under the following certifications and accreditations: Code Description Number Expires 100033AIHA-LAP, LLC - ISO 17025:2017AIHA 03/1/2024 M-MA100Massachusetts DEPMA 06/30/2023 PH-0165Connecticut Department of Public HealthCT 12/31/2022 10899 NELAPNew York State Department of HealthNY 04/1/2023 2516 NELAPNew Hampshire Environmental LabNH 02/5/2023 LAO00373Rhode Island Department of HealthRI 12/30/2022 652North Carolina Div. of Water QualityNC 12/31/2022 MA007 NELAPNew Jersey DEPNJ 06/30/2023 E871027 NELAPFlorida Department of HealthFL 06/30/2023 LL720741Vermont Department of Health Lead LaboratoryVT 07/30/2023 VT-255716Vermont Department of Health Drinking WaterVT-DW 06/12/2023 MA00100State of MaineME 06/9/2023 460217Commonwealth of VirginiaVA 12/14/2022 2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2022 25703North Carolina Department of Health and Human ServicesNC-DW 07/31/2023 68-05812Commonwealth of Pennsylvania DEPPA 06/30/2023 9100Dept. of Env, Great Lakes, and EnergyMI 09/6/2022 Page 40 of 44 Page 41 of 44 Page 42 of 44 Page 43 of 44 Page 44 of 44 Appendix C DEQ Risk Calculators (July 2022) Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Sub-Slab Worst Case North Carolina Department of Environmental Quality Risk Calculator REEP LRC(RN) 1900 Continental Boulevard, Charlotte, NC DEQ DWM Brownfields 17047-13-060 July 2022 May 2022 EPA RSL Table Prepared By:Hart & Hickman 3921 Sunset Ridge Road, Suite 301, Raleigh, NC 27607 North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: Sub-Slab Worst Case Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: Sub-Slab Worst Case Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes: CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 4100 SS-18 67-64-1 Acetone ug/m3 10 SS-19 71-43-2 Benzene ug/m3 7.9 SS-19 75-15-0 Carbon Disulfide ug/m3 5.6 SS-19 67-66-3 Chloroform ug/m3 1.1 SS-13 74-87-3 Chloromethane ug/m3 5.7 SS-15 110-82-7 Cyclohexane ug/m3 4.3 SS-17 75-71-8 Dichlorodifluoromethane ug/m3 3700 SS-19 75-34-3 Dichloroethane, 1,1-ug/m3 3500 SS-19 75-35-4 Dichloroethylene, 1,1-ug/m3 350 SS-21 156-59-2 Dichloroethylene, cis-1,2-ug/m3 49 SS-21 156-60-5 Dichloroethylene, trans-1,2-ug/m3 130 SS-15 123-91-1 Dioxane, 1,4-ug/m3 78 SS-17 141-78-6 Ethyl Acetate ug/m3 64 SS-18 100-41-4 Ethylbenzene ug/m3 7.6 SS-15 109-99-9 ~Tetrahydrofuran ug/m3 3.8 SS-DUP 142-82-5 Heptane, N-ug/m3 11 SS-18 110-54-3 Hexane, N-ug/m3 95 SS-18 591-78-6 Hexanone, 2-ug/m3 760 SS-18 67-63-0 Isopropanol ug/m3 180 SS-18 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 160 SS-18 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 25 SS-19 91-20-3 ~Naphthalene ug/m3 6 SS-18 115-07-1 Propylene ug/m3 4.6 SS-18 100-42-5 Styrene ug/m3 200 SS-19 127-18-4 Tetrachloroethylene ug/m3 23 SS-15 108-88-3 Toluene ug/m3 25 SS-19 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-ug/m3 13 SS-18 71-55-6 Trichloroethane, 1,1,1-ug/m3 1200 SS-21 / SS-DUP 79-01-6 Trichloroethylene ug/m3 49 SS-13 75-69-4 Trichlorofluoromethane ug/m3 81 SS-18 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 23 SS-18 108-67-8 Trimethylbenzene, 1,3,5-ug/m3 0.91 SS-DUP 75-01-4 Vinyl Chloride ug/m3 190 SS-18 108-38-3 Xylene, m-ug/m3 51 SS-18 95-47-6 Xylene, o-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: Sub-Slab Worst Case Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.0E-05 1.5E+00 YES Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1.If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: Sub-Slab Worst Case CAS # Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 4100 41 - - 71-43-2 Benzene 10 0.1 1.6E+00 2.6E+01 6.4E-08 7.6E-04 75-15-0 Carbon Disulfide 7.9 0.079 - 6.1E+02 2.6E-05 67-66-3 Chloroform 5.6 0.056 5.3E-01 8.6E+01 1.1E-07 1.3E-04 74-87-3 Chloromethane 1.1 0.011 - 7.9E+01 2.8E-05 110-82-7 Cyclohexane 5.7 0.057 - 5.3E+03 2.2E-06 75-71-8 Dichlorodifluoromethane 4.3 0.043 - 8.8E+01 9.8E-05 75-34-3 Dichloroethane, 1,1- 3700 37 7.7E+00 -4.8E-06 75-35-4 Dichloroethylene, 1,1- 3500 35 - 1.8E+02 4.0E-02 156-59-2 Dichloroethylene, cis-1,2- 350 3.5 - - 156-60-5 Dichloroethylene, trans-1,2- 49 0.49 - 3.5E+01 2.8E-03 123-91-1 Dioxane, 1,4- 130 1.3 2.5E+00 2.6E+01 5.3E-07 9.9E-03 141-78-6 Ethyl Acetate 78 0.78 - 6.1E+01 2.5E-03 100-41-4 Ethylbenzene 64 0.64 4.9E+00 8.8E+02 1.3E-07 1.5E-04 109-99-9 ~Tetrahydrofuran 7.6 0.076 - 1.8E+03 8.7E-06 142-82-5 Heptane, N- 3.8 0.038 - 3.5E+02 2.2E-05 110-54-3 Hexane, N- 11 0.11 - 6.1E+02 3.6E-05 591-78-6 Hexanone, 2- 95 0.95 - 2.6E+01 7.2E-03 67-63-0 Isopropanol 760 7.6 - 1.8E+02 8.7E-03 78-93-3 Methyl Ethyl Ketone (2-Butanone) 180 1.8 - 4.4E+03 8.2E-05 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone) 160 1.6 - 2.6E+03 1.2E-04 91-20-3 ~Naphthalene 25 0.25 3.6E-01 2.6E+00 6.9E-07 1.9E-02 115-07-1 Propylene 6 0.06 - 2.6E+03 4.6E-06 100-42-5 Styrene 4.6 0.046 - 8.8E+02 1.1E-05 127-18-4 Tetrachloroethylene 200 2 4.7E+01 3.5E+01 4.2E-08 1.1E-02 108-88-3 Toluene 23 0.23 - 4.4E+03 1.1E-05 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2- 25 0.25 - 4.4E+03 1.1E-05 71-55-6 Trichloroethane, 1,1,1- 13 0.13 - 4.4E+03 5.9E-06 79-01-6 Trichloroethylene 1200 12 3.0E+00 1.8E+00 4.0E-06 1.4E+00 75-69-4 Trichlorofluoromethane 49 0.49 - - 95-63-6 Trimethylbenzene, 1,2,4- 81 0.81 - 5.3E+01 3.1E-03 108-67-8 Trimethylbenzene, 1,3,5- 23 0.23 - 5.3E+01 8.8E-04 75-01-4 Vinyl Chloride 0.91 0.0091 2.8E+00 7.0E+01 3.3E-09 2.6E-05 108-38-3 Xylene, m- 190 1.9 - 8.8E+01 4.3E-03 95-47-6 Xylene, o- 51 0.51 - 8.8E+01 1.2E-03 Cumulative: 1.0E-05 1.5E+00 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Sub-Slab Worst Case (without SS-21) North Carolina Department of Environmental Quality Risk Calculator REEP LRC(RN) 1900 Continental Boulevard, Charlotte, NC DEQ DWM Brownfields 17047-13-060 July 2022 May 2022 EPA RSL Table Prepared By:Hart & Hickman 3921 Sunset Ridge Road, Suite 301, Raleigh, NC 27607 North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: Sub-Slab Worst Case (without SS-21) Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: Sub-Slab Worst Case (without SS-21) Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes: CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 4100 SS-18 67-64-1 Acetone ug/m3 10 SS-19 71-43-2 Benzene ug/m3 7.9 SS-19 75-15-0 Carbon Disulfide ug/m3 5.6 SS-19 67-66-3 Chloroform ug/m3 1.1 SS-13 74-87-3 Chloromethane ug/m3 5.7 SS-15 110-82-7 Cyclohexane ug/m3 4.3 SS-17 75-71-8 Dichlorodifluoromethane ug/m3 3700 SS-19 75-34-3 Dichloroethane, 1,1-ug/m3 3500 SS-19 75-35-4 Dichloroethylene, 1,1-ug/m3 130 SS-15 123-91-1 Dioxane, 1,4-ug/m3 78 SS-17 141-78-6 Ethyl Acetate ug/m3 64 SS-18 100-41-4 Ethylbenzene ug/m3 7.6 SS-15 109-99-9 ~Tetrahydrofuran ug/m3 3.2 SS-18 142-82-5 Heptane, N-ug/m3 11 SS-18 110-54-3 Hexane, N-ug/m3 95 SS-18 591-78-6 Hexanone, 2-ug/m3 760 SS-18 67-63-0 Isopropanol ug/m3 180 SS-18 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 160 SS-18 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 25 SS-19 91-20-3 ~Naphthalene ug/m3 6 SS-18 115-07-1 Propylene ug/m3 4.6 SS-18 100-42-5 Styrene ug/m3 200 SS-19 127-18-4 Tetrachloroethylene ug/m3 23 SS-15 108-88-3 Toluene ug/m3 25 SS-19 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-ug/m3 13 SS-18 71-55-6 Trichloroethane, 1,1,1-ug/m3 20 SS-19 79-01-6 Trichloroethylene ug/m3 49 SS-13 75-69-4 Trichlorofluoromethane ug/m3 81 SS-18 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 23 SS-18 108-67-8 Trimethylbenzene, 1,3,5-ug/m3 0.83 SS-19 75-01-4 Vinyl Chloride ug/m3 190 SS-18 108-38-3 Xylene, m-ug/m3 51 SS-18 95-47-6 Xylene, o-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: Sub-Slab Worst Case (without SS-21) Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 6.5E-06 1.3E-01 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1.If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: Sub-Slab Worst Case (without SS-21) CAS # Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 4100 41 - - 71-43-2 Benzene 10 0.1 1.6E+00 2.6E+01 6.4E-08 7.6E-04 75-15-0 Carbon Disulfide 7.9 0.079 - 6.1E+02 2.6E-05 67-66-3 Chloroform 5.6 0.056 5.3E-01 8.6E+01 1.1E-07 1.3E-04 74-87-3 Chloromethane 1.1 0.011 - 7.9E+01 2.8E-05 110-82-7 Cyclohexane 5.7 0.057 - 5.3E+03 2.2E-06 75-71-8 Dichlorodifluoromethane 4.3 0.043 - 8.8E+01 9.8E-05 75-34-3 Dichloroethane, 1,1- 3700 37 7.7E+00 -4.8E-06 75-35-4 Dichloroethylene, 1,1- 3500 35 - 1.8E+02 4.0E-02 156-59-2 Dichloroethylene, cis-1,2- - - 156-60-5 Dichloroethylene, trans-1,2- - 3.5E+01 123-91-1 Dioxane, 1,4- 130 1.3 2.5E+00 2.6E+01 5.3E-07 9.9E-03 141-78-6 Ethyl Acetate 78 0.78 - 6.1E+01 2.5E-03 100-41-4 Ethylbenzene 64 0.64 4.9E+00 8.8E+02 1.3E-07 1.5E-04 109-99-9 ~Tetrahydrofuran 7.6 0.076 - 1.8E+03 8.7E-06 142-82-5 Heptane, N- 3.2 0.032 - 3.5E+02 1.8E-05 110-54-3 Hexane, N- 11 0.11 - 6.1E+02 3.6E-05 591-78-6 Hexanone, 2- 95 0.95 - 2.6E+01 7.2E-03 67-63-0 Isopropanol 760 7.6 - 1.8E+02 8.7E-03 78-93-3 Methyl Ethyl Ketone (2-Butanone) 180 1.8 - 4.4E+03 8.2E-05 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone) 160 1.6 - 2.6E+03 1.2E-04 91-20-3 ~Naphthalene 25 0.25 3.6E-01 2.6E+00 6.9E-07 1.9E-02 115-07-1 Propylene 6 0.06 - 2.6E+03 4.6E-06 100-42-5 Styrene 4.6 0.046 - 8.8E+02 1.1E-05 127-18-4 Tetrachloroethylene 200 2 4.7E+01 3.5E+01 4.2E-08 1.1E-02 108-88-3 Toluene 23 0.23 - 4.4E+03 1.1E-05 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2- 25 0.25 - 4.4E+03 1.1E-05 71-55-6 Trichloroethane, 1,1,1- 13 0.13 - 4.4E+03 5.9E-06 79-01-6 Trichloroethylene 20 0.2 3.0E+00 1.8E+00 6.7E-08 2.3E-02 75-69-4 Trichlorofluoromethane 49 0.49 - - 95-63-6 Trimethylbenzene, 1,2,4- 81 0.81 - 5.3E+01 3.1E-03 108-67-8 Trimethylbenzene, 1,3,5- 23 0.23 - 5.3E+01 8.8E-04 75-01-4 Vinyl Chloride 0.83 0.0083 2.8E+00 7.0E+01 3.0E-09 2.4E-05 108-38-3 Xylene, m- 190 1.9 - 8.8E+01 4.3E-03 95-47-6 Xylene, o- 51 0.51 - 8.8E+01 1.2E-03 Cumulative: 6.5E-06 1.3E-01 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Prepared By:Hart & Hickman 3921 Sunset Ridge Road, Suite 301, Raleigh, NC 27607 IAS-1 North Carolina Department of Environmental Quality Risk Calculator REEP LRC(RN) 1900 Continental Boulevard, Charlotte, NC DEQ DWM Brownfields 17047-13-060 July 2022 May 2022 EPA RSL Table North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-1 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-1 Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes: CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 13 67-64-1 Acetone ug/m3 0.23 71-43-2 Benzene ug/m3 0.36 75-15-0 Carbon Disulfide ug/m3 0.31 56-23-5 Carbon Tetrachloride ug/m3 0.17 67-66-3 Chloroform ug/m3 1.5 74-87-3 Chloromethane ug/m3 1.1 75-71-8 Dichlorodifluoromethane ug/m3 0.4 107-06-2 Dichloroethane, 1,2-ug/m3 8.3 141-78-6 Ethyl Acetate ug/m3 5.7 100-41-4 Ethylbenzene ug/m3 0.4 142-82-5 Heptane, N-ug/m3 1.8 110-54-3 Hexane, N-ug/m3 5.1 67-63-0 Isopropanol ug/m3 15 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 0.49 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 0.73 75-09-2 Methylene Chloride ug/m3 0.29 91-20-3 ~Naphthalene ug/m3 10 100-42-5 Styrene ug/m3 27 108-88-3 Toluene ug/m3 0.51 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-ug/m3 0.14 79-01-6 Trichloroethylene ug/m3 9.5 75-69-4 Trichlorofluoromethane ug/m3 0.28 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 0.1 108-67-8 Trimethylbenzene, 1,3,5-ug/m3 17 108-38-3 Xylene, m-ug/m3 6.9 95-47-6 Xylene, o-ug/m3 Input Form 2E Indoor Air Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-1 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air 3.5E-06 1.6E-01 NO Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1.If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Indoor Air Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-1 CAS # Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 13 - - 71-43-2 Benzene 0.23 1.6E+00 2.6E+01 1.5E-07 1.8E-03 74-83-9 Bromomethane - 4.4E+00 75-15-0 Carbon Disulfide 0.36 - 6.1E+02 1.2E-04 56-23-5 Carbon Tetrachloride 0.31 2.0E+00 8.8E+01 1.5E-07 7.1E-04 67-66-3 Chloroform 0.17 5.3E-01 8.6E+01 3.2E-07 4.0E-04 74-87-3 Chloromethane 1.5 - 7.9E+01 3.8E-03 75-71-8 Dichlorodifluoromethane 1.1 - 8.8E+01 2.5E-03 107-06-2 Dichloroethane, 1,2- 0.4 4.7E-01 6.1E+00 8.5E-07 1.3E-02 156-60-5 Dichloroethylene, trans-1,2- - 3.5E+01 78-87-5 Dichloropropane, 1,2- 3.3E+00 3.5E+00 141-78-6 Ethyl Acetate 8.3 - 6.1E+01 2.7E-02 100-41-4 Ethylbenzene 5.7 4.9E+00 8.8E+02 1.2E-06 1.3E-03 109-99-9 ~Tetrahydrofuran - 1.8E+03 142-82-5 Heptane, N- 0.4 - 3.5E+02 2.3E-04 110-54-3 Hexane, N- 1.8 - 6.1E+02 5.9E-04 591-78-6 Hexanone, 2- - 2.6E+01 67-63-0 Isopropanol 5.1 - 1.8E+02 5.8E-03 78-93-3 Methyl Ethyl Ketone (2-Butanone) 15 - 4.4E+03 6.8E-04 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone) 0.49 - 2.6E+03 3.7E-05 75-09-2 Methylene Chloride 0.73 1.2E+03 5.3E+02 6.0E-10 2.8E-04 91-20-3 ~Naphthalene 0.29 3.6E-01 2.6E+00 8.0E-07 2.2E-02 100-42-5 Styrene 10 - 8.8E+02 2.3E-03 127-18-4 Tetrachloroethylene 4.7E+01 3.5E+01 108-88-3 Toluene 27 - 4.4E+03 1.2E-03 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2- 0.51 - 4.4E+03 2.3E-05 79-00-5 Trichloroethane, 1,1,2- 7.7E-01 1.8E-01 79-01-6 Trichloroethylene 0.14 3.0E+00 1.8E+00 4.7E-08 1.6E-02 75-69-4 Trichlorofluoromethane 9.5 - - 95-63-6 Trimethylbenzene, 1,2,4- 0.28 - 5.3E+01 1.1E-03 108-67-8 Trimethylbenzene, 1,3,5- 0.1 - 5.3E+01 3.8E-04 108-38-3 Xylene, m- 17 - 8.8E+01 3.9E-02 95-47-6 Xylene, o- 6.9 - 8.8E+01 1.6E-02 Cumulative: 3.5E-06 1.6E-01 All concentrations are in ug/m3 Output Form 3F ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: IAS-2 North Carolina Department of Environmental Quality Risk Calculator REEP LRC(RN) 1900 Continental Boulevard, Charlotte, NC DEQ DWM Brownfields 17047-13-060 July 2022 May 2022 EPA RSL Table Prepared By:Hart & Hickman 3921 Sunset Ridge Road, Suite 301, Raleigh, NC 27607 North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-2 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-2 Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes: CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 14 67-64-1 Acetone ug/m3 0.27 71-43-2 Benzene ug/m3 0.27 74-83-9 Bromomethane ug/m3 0.23 75-15-0 Carbon Disulfide ug/m3 0.34 56-23-5 Carbon Tetrachloride ug/m3 1.5 74-87-3 Chloromethane ug/m3 0.96 75-71-8 Dichlorodifluoromethane ug/m3 3 141-78-6 Ethyl Acetate ug/m3 3.1 100-41-4 Ethylbenzene ug/m3 0.31 142-82-5 Heptane, N-ug/m3 1.6 110-54-3 Hexane, N-ug/m3 3.1 67-63-0 Isopropanol ug/m3 9 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 0.31 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 0.26 91-20-3 ~Naphthalene ug/m3 5.2 100-42-5 Styrene ug/m3 15 108-88-3 Toluene ug/m3 0.51 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-ug/m3 5.9 75-69-4 Trichlorofluoromethane ug/m3 0.19 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 9.3 108-38-3 Xylene, m-ug/m3 3.9 95-47-6 Xylene, o-ug/m3 Input Form 2E Indoor Air Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-2 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air 1.7E-06 8.9E-02 NO Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1.If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Indoor Air Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-2 CAS # Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 14 - - 71-43-2 Benzene 0.27 1.6E+00 2.6E+01 1.7E-07 2.1E-03 74-83-9 Bromomethane 0.27 - 4.4E+00 1.2E-02 75-15-0 Carbon Disulfide 0.23 - 6.1E+02 7.5E-05 56-23-5 Carbon Tetrachloride 0.34 2.0E+00 8.8E+01 1.7E-07 7.8E-04 67-66-3 Chloroform 5.3E-01 8.6E+01 74-87-3 Chloromethane 1.5 - 7.9E+01 3.8E-03 75-71-8 Dichlorodifluoromethane 0.96 - 8.8E+01 2.2E-03 107-06-2 Dichloroethane, 1,2- 4.7E-01 6.1E+00 156-60-5 Dichloroethylene, trans-1,2- - 3.5E+01 78-87-5 Dichloropropane, 1,2- 3.3E+00 3.5E+00 141-78-6 Ethyl Acetate 3 - 6.1E+01 9.8E-03 100-41-4 Ethylbenzene 3.1 4.9E+00 8.8E+02 6.3E-07 7.1E-04 109-99-9 ~Tetrahydrofuran - 1.8E+03 142-82-5 Heptane, N- 0.31 - 3.5E+02 1.8E-04 110-54-3 Hexane, N- 1.6 - 6.1E+02 5.2E-04 591-78-6 Hexanone, 2- - 2.6E+01 67-63-0 Isopropanol 3.1 - 1.8E+02 3.5E-03 78-93-3 Methyl Ethyl Ketone (2-Butanone) 9 - 4.4E+03 4.1E-04 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone) 0.31 - 2.6E+03 2.4E-05 75-09-2 Methylene Chloride 1.2E+03 5.3E+02 91-20-3 ~Naphthalene 0.26 3.6E-01 2.6E+00 7.2E-07 2.0E-02 100-42-5 Styrene 5.2 - 8.8E+02 1.2E-03 127-18-4 Tetrachloroethylene 4.7E+01 3.5E+01 108-88-3 Toluene 15 - 4.4E+03 6.8E-04 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2- 0.51 - 4.4E+03 2.3E-05 79-00-5 Trichloroethane, 1,1,2- 7.7E-01 1.8E-01 79-01-6 Trichloroethylene 3.0E+00 1.8E+00 75-69-4 Trichlorofluoromethane 5.9 - - 95-63-6 Trimethylbenzene, 1,2,4- 0.19 - 5.3E+01 7.2E-04 108-67-8 Trimethylbenzene, 1,3,5- - 5.3E+01 108-38-3 Xylene, m- 9.3 - 8.8E+01 2.1E-02 95-47-6 Xylene, o- 3.9 - 8.8E+01 8.9E-03 Cumulative: 1.7E-06 8.9E-02 All concentrations are in ug/m3 Output Form 3F ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Prepared By:Hart & Hickman 3921 Sunset Ridge Road, Suite 301, Raleigh, NC 27607 IAS-3 North Carolina Department of Environmental Quality Risk Calculator REEP LRC(RN) 1900 Continental Boulevard, Charlotte, NC DEQ DWM Brownfields 17047-13-060 July 2022 May 2022 EPA RSL Table North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-3 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-3 Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes: CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 32 67-64-1 Acetone ug/m3 0.23 71-43-2 Benzene ug/m3 0.13 75-15-0 Carbon Disulfide ug/m3 0.34 56-23-5 Carbon Tetrachloride ug/m3 0.37 67-66-3 Chloroform ug/m3 1.6 74-87-3 Chloromethane ug/m3 1.2 75-71-8 Dichlorodifluoromethane ug/m3 7.3 141-78-6 Ethyl Acetate ug/m3 0.39 100-41-4 Ethylbenzene ug/m3 0.34 109-99-9 ~Tetrahydrofuran ug/m3 0.29 142-82-5 Heptane, N-ug/m3 1.2 110-54-3 Hexane, N-ug/m3 30 67-63-0 Isopropanol ug/m3 2.4 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 0.19 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 0.26 91-20-3 ~Naphthalene ug/m3 0.33 100-42-5 Styrene ug/m3 7.3 108-88-3 Toluene ug/m3 0.51 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-ug/m3 1.6 75-69-4 Trichlorofluoromethane ug/m3 0.26 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 1.4 108-38-3 Xylene, m-ug/m3 0.51 95-47-6 Xylene, o-ug/m3 Input Form 2E Indoor Air Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-3 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air 1.8E-06 9.5E-02 NO Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1.If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Indoor Air Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-3 CAS # Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 32 - - 71-43-2 Benzene 0.23 1.6E+00 2.6E+01 1.5E-07 1.8E-03 74-83-9 Bromomethane - 4.4E+00 75-15-0 Carbon Disulfide 0.13 - 6.1E+02 4.2E-05 56-23-5 Carbon Tetrachloride 0.34 2.0E+00 8.8E+01 1.7E-07 7.8E-04 67-66-3 Chloroform 0.37 5.3E-01 8.6E+01 6.9E-07 8.6E-04 74-87-3 Chloromethane 1.6 - 7.9E+01 4.1E-03 75-71-8 Dichlorodifluoromethane 1.2 - 8.8E+01 2.7E-03 107-06-2 Dichloroethane, 1,2- 4.7E-01 6.1E+00 156-60-5 Dichloroethylene, trans-1,2- - 3.5E+01 78-87-5 Dichloropropane, 1,2- 3.3E+00 3.5E+00 141-78-6 Ethyl Acetate 7.3 - 6.1E+01 2.4E-02 100-41-4 Ethylbenzene 0.39 4.9E+00 8.8E+02 8.0E-08 8.9E-05 109-99-9 ~Tetrahydrofuran 0.34 - 1.8E+03 3.9E-05 142-82-5 Heptane, N- 0.29 - 3.5E+02 1.7E-04 110-54-3 Hexane, N- 1.2 - 6.1E+02 3.9E-04 591-78-6 Hexanone, 2- - 2.6E+01 67-63-0 Isopropanol 30 - 1.8E+02 3.4E-02 78-93-3 Methyl Ethyl Ketone (2-Butanone) 2.4 - 4.4E+03 1.1E-04 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone) 0.19 - 2.6E+03 1.4E-05 75-09-2 Methylene Chloride 1.2E+03 5.3E+02 91-20-3 ~Naphthalene 0.26 3.6E-01 2.6E+00 7.2E-07 2.0E-02 100-42-5 Styrene 0.33 - 8.8E+02 7.5E-05 127-18-4 Tetrachloroethylene 4.7E+01 3.5E+01 108-88-3 Toluene 7.3 - 4.4E+03 3.3E-04 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2- 0.51 - 4.4E+03 2.3E-05 79-00-5 Trichloroethane, 1,1,2- 7.7E-01 1.8E-01 79-01-6 Trichloroethylene 3.0E+00 1.8E+00 75-69-4 Trichlorofluoromethane 1.6 - - 95-63-6 Trimethylbenzene, 1,2,4- 0.26 - 5.3E+01 9.9E-04 108-67-8 Trimethylbenzene, 1,3,5- - 5.3E+01 108-38-3 Xylene, m- 1.4 - 8.8E+01 3.2E-03 95-47-6 Xylene, o- 0.51 - 8.8E+01 1.2E-03 Cumulative: 1.8E-06 9.5E-02 All concentrations are in ug/m3 Output Form 3F ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Prepared By:Hart & Hickman 3921 Sunset Ridge Road, Suite 301, Raleigh, NC 27607 IAS-4 North Carolina Department of Environmental Quality Risk Calculator REEP LRC(RN) 1900 Continental Boulevard, Charlotte, NC DEQ DWM Brownfields 17047-13-060 July 2022 May 2022 EPA RSL Table North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-4 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-4 Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes: CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 110 67-64-1 Acetone ug/m3 0.47 71-43-2 Benzene ug/m3 0.31 75-15-0 Carbon Disulfide ug/m3 0.3 56-23-5 Carbon Tetrachloride ug/m3 2 74-87-3 Chloromethane ug/m3 0.96 75-71-8 Dichlorodifluoromethane ug/m3 0.17 78-87-5 Dichloropropane, 1,2-ug/m3 5.1 141-78-6 Ethyl Acetate ug/m3 3.9 100-41-4 Ethylbenzene ug/m3 0.99 142-82-5 Heptane, N-ug/m3 2 110-54-3 Hexane, N-ug/m3 9.7 67-63-0 Isopropanol ug/m3 7.7 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 0.87 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 0.59 75-09-2 Methylene Chloride ug/m3 0.37 91-20-3 ~Naphthalene ug/m3 1.4 100-42-5 Styrene ug/m3 8.4 108-88-3 Toluene ug/m3 0.56 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-ug/m3 2.7 75-69-4 Trichlorofluoromethane ug/m3 1.5 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 0.42 108-67-8 Trimethylbenzene, 1,3,5-ug/m3 16 108-38-3 Xylene, m-ug/m3 5.3 95-47-6 Xylene, o-ug/m3 Input Form 2E Indoor Air Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-4 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air 2.3E-06 1.4E-01 NO Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1.If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Indoor Air Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-4 CAS # Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 110 - - 71-43-2 Benzene 0.47 1.6E+00 2.6E+01 3.0E-07 3.6E-03 74-83-9 Bromomethane - 4.4E+00 75-15-0 Carbon Disulfide 0.31 - 6.1E+02 1.0E-04 56-23-5 Carbon Tetrachloride 0.3 2.0E+00 8.8E+01 1.5E-07 6.8E-04 67-66-3 Chloroform 5.3E-01 8.6E+01 74-87-3 Chloromethane 2 - 7.9E+01 5.1E-03 75-71-8 Dichlorodifluoromethane 0.96 - 8.8E+01 2.2E-03 107-06-2 Dichloroethane, 1,2- 4.7E-01 6.1E+00 156-60-5 Dichloroethylene, trans-1,2- - 3.5E+01 78-87-5 Dichloropropane, 1,2- 0.17 3.3E+00 3.5E+00 5.1E-08 9.7E-03 141-78-6 Ethyl Acetate 5.1 - 6.1E+01 1.7E-02 100-41-4 Ethylbenzene 3.9 4.9E+00 8.8E+02 8.0E-07 8.9E-04 109-99-9 ~Tetrahydrofuran - 1.8E+03 142-82-5 Heptane, N- 0.99 - 3.5E+02 5.7E-04 110-54-3 Hexane, N- 2 - 6.1E+02 6.5E-04 591-78-6 Hexanone, 2- - 2.6E+01 67-63-0 Isopropanol 9.7 - 1.8E+02 1.1E-02 78-93-3 Methyl Ethyl Ketone (2-Butanone) 7.7 - 4.4E+03 3.5E-04 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone) 0.87 - 2.6E+03 6.6E-05 75-09-2 Methylene Chloride 0.59 1.2E+03 5.3E+02 4.8E-10 2.2E-04 91-20-3 ~Naphthalene 0.37 3.6E-01 2.6E+00 1.0E-06 2.8E-02 100-42-5 Styrene 1.4 - 8.8E+02 3.2E-04 127-18-4 Tetrachloroethylene 4.7E+01 3.5E+01 108-88-3 Toluene 8.4 - 4.4E+03 3.8E-04 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2- 0.56 - 4.4E+03 2.6E-05 79-00-5 Trichloroethane, 1,1,2- 7.7E-01 1.8E-01 79-01-6 Trichloroethylene 3.0E+00 1.8E+00 75-69-4 Trichlorofluoromethane 2.7 - - 95-63-6 Trimethylbenzene, 1,2,4- 1.5 - 5.3E+01 5.7E-03 108-67-8 Trimethylbenzene, 1,3,5- 0.42 - 5.3E+01 1.6E-03 108-38-3 Xylene, m- 16 - 8.8E+01 3.7E-02 95-47-6 Xylene, o- 5.3 - 8.8E+01 1.2E-02 Cumulative: 2.3E-06 1.4E-01 All concentrations are in ug/m3 Output Form 3F ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: IAS-5 North Carolina Department of Environmental Quality Risk Calculator REEP LRC(RN) 1900 Continental Boulevard, Charlotte, NC DEQ DWM Brownfields 17047-13-060 July 2022 May 2022 EPA RSL Table Prepared By:Hart & Hickman 3921 Sunset Ridge Road, Suite 301, Raleigh, NC 27607 North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-5 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-5 Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes: CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 42 67-64-1 Acetone ug/m3 0.26 71-43-2 Benzene ug/m3 0.5 75-15-0 Carbon Disulfide ug/m3 0.37 56-23-5 Carbon Tetrachloride ug/m3 0.19 67-66-3 Chloroform ug/m3 1.7 74-87-3 Chloromethane ug/m3 1 75-71-8 Dichlorodifluoromethane ug/m3 0.33 107-06-2 Dichloroethane, 1,2-ug/m3 0.12 156-60-5 Dichloroethylene, trans-1,2-ug/m3 0.63 78-87-5 Dichloropropane, 1,2-ug/m3 7.5 141-78-6 Ethyl Acetate ug/m3 5 100-41-4 Ethylbenzene ug/m3 0.19 109-99-9 ~Tetrahydrofuran ug/m3 0.61 142-82-5 Heptane, N-ug/m3 1.8 110-54-3 Hexane, N-ug/m3 0.82 591-78-6 Hexanone, 2-ug/m3 48 67-63-0 Isopropanol ug/m3 8.6 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 0.84 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 7 75-09-2 Methylene Chloride ug/m3 0.66 91-20-3 ~Naphthalene ug/m3 7.8 100-42-5 Styrene ug/m3 0.3 127-18-4 Tetrachloroethylene ug/m3 16 108-88-3 Toluene ug/m3 0.77 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-ug/m3 16 75-69-4 Trichlorofluoromethane ug/m3 0.98 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 0.29 108-67-8 Trimethylbenzene, 1,3,5-ug/m3 15 108-38-3 Xylene, m-ug/m3 6.6 95-47-6 Xylene, o-ug/m3 Input Form 2E Indoor Air Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-5 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air 4.5E-06 2.6E-01 NO Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1.If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Indoor Air Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-5 CAS # Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 42 - - 71-43-2 Benzene 0.26 1.6E+00 2.6E+01 1.7E-07 2.0E-03 74-83-9 Bromomethane - 4.4E+00 75-15-0 Carbon Disulfide 0.5 - 6.1E+02 1.6E-04 56-23-5 Carbon Tetrachloride 0.37 2.0E+00 8.8E+01 1.8E-07 8.4E-04 67-66-3 Chloroform 0.19 5.3E-01 8.6E+01 3.6E-07 4.4E-04 74-87-3 Chloromethane 1.7 - 7.9E+01 4.3E-03 75-71-8 Dichlorodifluoromethane 1 - 8.8E+01 2.3E-03 107-06-2 Dichloroethane, 1,2- 0.33 4.7E-01 6.1E+00 7.0E-07 1.1E-02 156-60-5 Dichloroethylene, trans-1,2- 0.12 - 3.5E+01 6.8E-04 78-87-5 Dichloropropane, 1,2- 0.63 3.3E+00 3.5E+00 1.9E-07 3.6E-02 141-78-6 Ethyl Acetate 7.5 - 6.1E+01 2.4E-02 100-41-4 Ethylbenzene 5 4.9E+00 8.8E+02 1.0E-06 1.1E-03 109-99-9 ~Tetrahydrofuran 0.19 - 1.8E+03 2.2E-05 142-82-5 Heptane, N- 0.61 - 3.5E+02 3.5E-04 110-54-3 Hexane, N- 1.8 - 6.1E+02 5.9E-04 591-78-6 Hexanone, 2- 0.82 - 2.6E+01 6.2E-03 67-63-0 Isopropanol 48 - 1.8E+02 5.5E-02 78-93-3 Methyl Ethyl Ketone (2-Butanone) 8.6 - 4.4E+03 3.9E-04 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone) 0.84 - 2.6E+03 6.4E-05 75-09-2 Methylene Chloride 7 1.2E+03 5.3E+02 5.7E-09 2.7E-03 91-20-3 ~Naphthalene 0.66 3.6E-01 2.6E+00 1.8E-06 5.0E-02 100-42-5 Styrene 7.8 - 8.8E+02 1.8E-03 127-18-4 Tetrachloroethylene 0.3 4.7E+01 3.5E+01 6.4E-09 1.7E-03 108-88-3 Toluene 16 - 4.4E+03 7.3E-04 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2- 0.77 - 4.4E+03 3.5E-05 79-00-5 Trichloroethane, 1,1,2- 7.7E-01 1.8E-01 79-01-6 Trichloroethylene 3.0E+00 1.8E+00 75-69-4 Trichlorofluoromethane 16 - - 95-63-6 Trimethylbenzene, 1,2,4- 0.98 - 5.3E+01 3.7E-03 108-67-8 Trimethylbenzene, 1,3,5- 0.29 - 5.3E+01 1.1E-03 108-38-3 Xylene, m- 15 - 8.8E+01 3.4E-02 95-47-6 Xylene, o- 6.6 - 8.8E+01 1.5E-02 Cumulative: 4.5E-06 2.6E-01 All concentrations are in ug/m3 Output Form 3F ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Prepared By:Hart & Hickman 3921 Sunset Ridge Road, Suite 301, Raleigh, NC 27607 IAS-6 North Carolina Department of Environmental Quality Risk Calculator REEP LRC(RN) 1900 Continental Boulevard, Charlotte, NC DEQ DWM Brownfields 17047-13-060 July 2022 May 2022 EPA RSL Table North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-6 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-6 Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes: CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 37 67-64-1 Acetone ug/m3 0.36 71-43-2 Benzene ug/m3 0.45 75-15-0 Carbon Disulfide ug/m3 0.35 56-23-5 Carbon Tetrachloride ug/m3 0.19 67-66-3 Chloroform ug/m3 1.6 74-87-3 Chloromethane ug/m3 1.1 75-71-8 Dichlorodifluoromethane ug/m3 0.3 107-06-2 Dichloroethane, 1,2-ug/m3 0.59 78-87-5 Dichloropropane, 1,2-ug/m3 23 141-78-6 Ethyl Acetate ug/m3 4.5 100-41-4 Ethylbenzene ug/m3 0.58 142-82-5 Heptane, N-ug/m3 1.9 110-54-3 Hexane, N-ug/m3 0.75 591-78-6 Hexanone, 2-ug/m3 52 67-63-0 Isopropanol ug/m3 8.2 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 0.79 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 5.9 75-09-2 Methylene Chloride ug/m3 0.68 91-20-3 ~Naphthalene ug/m3 6.9 100-42-5 Styrene ug/m3 0.28 127-18-4 Tetrachloroethylene ug/m3 16 108-88-3 Toluene ug/m3 0.56 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-ug/m3 15 75-69-4 Trichlorofluoromethane ug/m3 0.9 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 0.28 108-67-8 Trimethylbenzene, 1,3,5-ug/m3 13 108-38-3 Xylene, m-ug/m3 6.1 95-47-6 Xylene, o-ug/m3 Input Form 2E Indoor Air Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-6 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air 4.4E-06 3.0E-01 NO Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1.If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Indoor Air Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-6 CAS # Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 37 - - 71-43-2 Benzene 0.36 1.6E+00 2.6E+01 2.3E-07 2.7E-03 74-83-9 Bromomethane - 4.4E+00 75-15-0 Carbon Disulfide 0.45 - 6.1E+02 1.5E-04 56-23-5 Carbon Tetrachloride 0.35 2.0E+00 8.8E+01 1.7E-07 8.0E-04 67-66-3 Chloroform 0.19 5.3E-01 8.6E+01 3.6E-07 4.4E-04 74-87-3 Chloromethane 1.6 - 7.9E+01 4.1E-03 75-71-8 Dichlorodifluoromethane 1.1 - 8.8E+01 2.5E-03 107-06-2 Dichloroethane, 1,2- 0.3 4.7E-01 6.1E+00 6.4E-07 9.8E-03 156-60-5 Dichloroethylene, trans-1,2- - 3.5E+01 78-87-5 Dichloropropane, 1,2- 0.59 3.3E+00 3.5E+00 1.8E-07 3.4E-02 141-78-6 Ethyl Acetate 23 - 6.1E+01 7.5E-02 100-41-4 Ethylbenzene 4.5 4.9E+00 8.8E+02 9.2E-07 1.0E-03 109-99-9 ~Tetrahydrofuran - 1.8E+03 142-82-5 Heptane, N- 0.58 - 3.5E+02 3.3E-04 110-54-3 Hexane, N- 1.9 - 6.1E+02 6.2E-04 591-78-6 Hexanone, 2- 0.75 - 2.6E+01 5.7E-03 67-63-0 Isopropanol 52 - 1.8E+02 5.9E-02 78-93-3 Methyl Ethyl Ketone (2-Butanone) 8.2 - 4.4E+03 3.7E-04 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone) 0.79 - 2.6E+03 6.0E-05 75-09-2 Methylene Chloride 5.9 1.2E+03 5.3E+02 4.8E-09 2.2E-03 91-20-3 ~Naphthalene 0.68 3.6E-01 2.6E+00 1.9E-06 5.2E-02 100-42-5 Styrene 6.9 - 8.8E+02 1.6E-03 127-18-4 Tetrachloroethylene 0.28 4.7E+01 3.5E+01 5.9E-09 1.6E-03 108-88-3 Toluene 16 - 4.4E+03 7.3E-04 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2- 0.56 - 4.4E+03 2.6E-05 79-00-5 Trichloroethane, 1,1,2- 7.7E-01 1.8E-01 79-01-6 Trichloroethylene 3.0E+00 1.8E+00 75-69-4 Trichlorofluoromethane 15 - - 95-63-6 Trimethylbenzene, 1,2,4- 0.9 - 5.3E+01 3.4E-03 108-67-8 Trimethylbenzene, 1,3,5- 0.28 - 5.3E+01 1.1E-03 108-38-3 Xylene, m- 13 - 8.8E+01 3.0E-02 95-47-6 Xylene, o- 6.1 - 8.8E+01 1.4E-02 Cumulative: 4.4E-06 3.0E-01 All concentrations are in ug/m3 Output Form 3F ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Prepared By:Hart & Hickman 3921 Sunset Ridge Road, Suite 301, Raleigh, NC 27607 IAS-7 North Carolina Department of Environmental Quality Risk Calculator REEP LRC(RN) 1900 Continental Boulevard, Charlotte, NC DEQ DWM Brownfields 17047-13-060 July 2022 May 2022 EPA RSL Table North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-7 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-7 Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes: CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 30 67-64-1 Acetone ug/m3 0.19 71-43-2 Benzene ug/m3 0.36 56-23-5 Carbon Tetrachloride ug/m3 0.53 67-66-3 Chloroform ug/m3 1.4 74-87-3 Chloromethane ug/m3 1.1 75-71-8 Dichlorodifluoromethane ug/m3 1.7 141-78-6 Ethyl Acetate ug/m3 0.48 100-41-4 Ethylbenzene ug/m3 0.41 109-99-9 ~Tetrahydrofuran ug/m3 0.25 142-82-5 Heptane, N-ug/m3 1.1 110-54-3 Hexane, N-ug/m3 0.64 591-78-6 Hexanone, 2-ug/m3 2.6 67-63-0 Isopropanol ug/m3 11 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 0.4 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 0.26 91-20-3 ~Naphthalene ug/m3 5.6 100-42-5 Styrene ug/m3 2 127-18-4 Tetrachloroethylene ug/m3 1.4 108-88-3 Toluene ug/m3 0.52 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-ug/m3 1.4 75-69-4 Trichlorofluoromethane ug/m3 0.36 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 0.093 108-67-8 Trimethylbenzene, 1,3,5-ug/m3 1.6 108-38-3 Xylene, m-ug/m3 0.55 95-47-6 Xylene, o-ug/m3 Input Form 2E Indoor Air Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-7 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air 2.2E-06 6.3E-02 NO Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1.If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Indoor Air Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-7 CAS # Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 30 - - 71-43-2 Benzene 0.19 1.6E+00 2.6E+01 1.2E-07 1.4E-03 74-83-9 Bromomethane - 4.4E+00 75-15-0 Carbon Disulfide - 6.1E+02 56-23-5 Carbon Tetrachloride 0.36 2.0E+00 8.8E+01 1.8E-07 8.2E-04 67-66-3 Chloroform 0.53 5.3E-01 8.6E+01 9.9E-07 1.2E-03 74-87-3 Chloromethane 1.4 - 7.9E+01 3.6E-03 75-71-8 Dichlorodifluoromethane 1.1 - 8.8E+01 2.5E-03 107-06-2 Dichloroethane, 1,2- 4.7E-01 6.1E+00 156-60-5 Dichloroethylene, trans-1,2- - 3.5E+01 78-87-5 Dichloropropane, 1,2- 3.3E+00 3.5E+00 141-78-6 Ethyl Acetate 1.7 - 6.1E+01 5.5E-03 100-41-4 Ethylbenzene 0.48 4.9E+00 8.8E+02 9.8E-08 1.1E-04 109-99-9 ~Tetrahydrofuran 0.41 - 1.8E+03 4.7E-05 142-82-5 Heptane, N- 0.25 - 3.5E+02 1.4E-04 110-54-3 Hexane, N- 1.1 - 6.1E+02 3.6E-04 591-78-6 Hexanone, 2- 0.64 - 2.6E+01 4.9E-03 67-63-0 Isopropanol 2.6 - 1.8E+02 3.0E-03 78-93-3 Methyl Ethyl Ketone (2-Butanone) 11 - 4.4E+03 5.0E-04 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone) 0.4 - 2.6E+03 3.0E-05 75-09-2 Methylene Chloride 1.2E+03 5.3E+02 91-20-3 ~Naphthalene 0.26 3.6E-01 2.6E+00 7.2E-07 2.0E-02 100-42-5 Styrene 5.6 - 8.8E+02 1.3E-03 127-18-4 Tetrachloroethylene 2 4.7E+01 3.5E+01 4.2E-08 1.1E-02 108-88-3 Toluene 1.4 - 4.4E+03 6.4E-05 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2- 0.52 - 4.4E+03 2.4E-05 79-00-5 Trichloroethane, 1,1,2- 7.7E-01 1.8E-01 79-01-6 Trichloroethylene 3.0E+00 1.8E+00 75-69-4 Trichlorofluoromethane 1.4 - - 95-63-6 Trimethylbenzene, 1,2,4- 0.36 - 5.3E+01 1.4E-03 108-67-8 Trimethylbenzene, 1,3,5- 0.093 - 5.3E+01 3.5E-04 108-38-3 Xylene, m- 1.6 - 8.8E+01 3.7E-03 95-47-6 Xylene, o- 0.55 - 8.8E+01 1.3E-03 Cumulative: 2.2E-06 6.3E-02 All concentrations are in ug/m3 Output Form 3F ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Prepared By:Hart & Hickman 3921 Sunset Ridge Road, Suite 301, Raleigh, NC 27607 IAS-8 North Carolina Department of Environmental Quality Risk Calculator REEP LRC(RN) 1900 Continental Boulevard, Charlotte, NC DEQ DWM Brownfields 17047-13-060 July 2022 May 2022 EPA RSL Table North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-8 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-8 Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes: CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 23 67-64-1 Acetone ug/m3 0.26 71-43-2 Benzene ug/m3 0.37 56-23-5 Carbon Tetrachloride ug/m3 1.3 74-87-3 Chloromethane ug/m3 1.1 75-71-8 Dichlorodifluoromethane ug/m3 7.3 141-78-6 Ethyl Acetate ug/m3 0.25 100-41-4 Ethylbenzene ug/m3 0.32 142-82-5 Heptane, N-ug/m3 2.3 110-54-3 Hexane, N-ug/m3 0.56 591-78-6 Hexanone, 2-ug/m3 3.6 67-63-0 Isopropanol ug/m3 6.2 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 0.27 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 0.25 91-20-3 ~Naphthalene ug/m3 6 100-42-5 Styrene ug/m3 2.3 108-88-3 Toluene ug/m3 0.51 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-ug/m3 2.3 75-69-4 Trichlorofluoromethane ug/m3 0.31 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 0.72 108-38-3 Xylene, m-ug/m3 0.34 95-47-6 Xylene, o-ug/m3 Input Form 2E Indoor Air Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-8 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air 1.1E-06 6.6E-02 NO Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1.If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Indoor Air Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-8 CAS # Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 23 - - 71-43-2 Benzene 0.26 1.6E+00 2.6E+01 1.7E-07 2.0E-03 74-83-9 Bromomethane - 4.4E+00 75-15-0 Carbon Disulfide - 6.1E+02 56-23-5 Carbon Tetrachloride 0.37 2.0E+00 8.8E+01 1.8E-07 8.4E-04 67-66-3 Chloroform 5.3E-01 8.6E+01 74-87-3 Chloromethane 1.3 - 7.9E+01 3.3E-03 75-71-8 Dichlorodifluoromethane 1.1 - 8.8E+01 2.5E-03 107-06-2 Dichloroethane, 1,2- 4.7E-01 6.1E+00 156-60-5 Dichloroethylene, trans-1,2- - 3.5E+01 78-87-5 Dichloropropane, 1,2- 3.3E+00 3.5E+00 141-78-6 Ethyl Acetate 7.3 - 6.1E+01 2.4E-02 100-41-4 Ethylbenzene 0.25 4.9E+00 8.8E+02 5.1E-08 5.7E-05 109-99-9 ~Tetrahydrofuran - 1.8E+03 142-82-5 Heptane, N- 0.32 - 3.5E+02 1.8E-04 110-54-3 Hexane, N- 2.3 - 6.1E+02 7.5E-04 591-78-6 Hexanone, 2- 0.56 - 2.6E+01 4.3E-03 67-63-0 Isopropanol 3.6 - 1.8E+02 4.1E-03 78-93-3 Methyl Ethyl Ketone (2-Butanone) 6.2 - 4.4E+03 2.8E-04 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone) 0.27 - 2.6E+03 2.1E-05 75-09-2 Methylene Chloride 1.2E+03 5.3E+02 91-20-3 ~Naphthalene 0.25 3.6E-01 2.6E+00 6.9E-07 1.9E-02 100-42-5 Styrene 6 - 8.8E+02 1.4E-03 127-18-4 Tetrachloroethylene 4.7E+01 3.5E+01 108-88-3 Toluene 2.3 - 4.4E+03 1.1E-04 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2- 0.51 - 4.4E+03 2.3E-05 79-00-5 Trichloroethane, 1,1,2- 7.7E-01 1.8E-01 79-01-6 Trichloroethylene 3.0E+00 1.8E+00 75-69-4 Trichlorofluoromethane 2.3 - - 95-63-6 Trimethylbenzene, 1,2,4- 0.31 - 5.3E+01 1.2E-03 108-67-8 Trimethylbenzene, 1,3,5- - 5.3E+01 108-38-3 Xylene, m- 0.72 - 8.8E+01 1.6E-03 95-47-6 Xylene, o- 0.34 - 8.8E+01 7.8E-04 Cumulative: 1.1E-06 6.6E-02 All concentrations are in ug/m3 Output Form 3F ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: IAS-9 North Carolina Department of Environmental Quality Risk Calculator REEP LRC(RN) 1900 Continental Boulevard, Charlotte, NC DEQ DWM Brownfields 17047-13-060 July 2022 May 2022 EPA RSL Table Prepared By:Hart & Hickman 3921 Sunset Ridge Road, Suite 301, Raleigh, NC 27607 North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-9 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-9 Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes: CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 30 67-64-1 Acetone ug/m3 0.57 71-43-2 Benzene ug/m3 0.4 75-15-0 Carbon Disulfide ug/m3 0.35 56-23-5 Carbon Tetrachloride ug/m3 0.19 67-66-3 Chloroform ug/m3 1.7 74-87-3 Chloromethane ug/m3 1.1 75-71-8 Dichlorodifluoromethane ug/m3 2.9 141-78-6 Ethyl Acetate ug/m3 1.1 100-41-4 Ethylbenzene ug/m3 0.39 142-82-5 Heptane, N-ug/m3 1.1 110-54-3 Hexane, N-ug/m3 3.2 67-63-0 Isopropanol ug/m3 4.3 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 13 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 0.55 91-20-3 ~Naphthalene ug/m3 30 100-42-5 Styrene ug/m3 1.8 108-88-3 Toluene ug/m3 0.52 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-ug/m3 120 75-69-4 Trichlorofluoromethane ug/m3 0.36 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 0.11 108-67-8 Trimethylbenzene, 1,3,5-ug/m3 3.2 108-38-3 Xylene, m-ug/m3 0.71 95-47-6 Xylene, o-ug/m3 Input Form 2E Indoor Air Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-9 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air 2.6E-06 8.7E-02 NO Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1.If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Indoor Air Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-9 CAS # Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 30 - - 71-43-2 Benzene 0.57 1.6E+00 2.6E+01 3.6E-07 4.3E-03 74-83-9 Bromomethane - 4.4E+00 75-15-0 Carbon Disulfide 0.4 - 6.1E+02 1.3E-04 56-23-5 Carbon Tetrachloride 0.35 2.0E+00 8.8E+01 1.7E-07 8.0E-04 67-66-3 Chloroform 0.19 5.3E-01 8.6E+01 3.6E-07 4.4E-04 74-87-3 Chloromethane 1.7 - 7.9E+01 4.3E-03 75-71-8 Dichlorodifluoromethane 1.1 - 8.8E+01 2.5E-03 107-06-2 Dichloroethane, 1,2- 4.7E-01 6.1E+00 156-60-5 Dichloroethylene, trans-1,2- - 3.5E+01 78-87-5 Dichloropropane, 1,2- 3.3E+00 3.5E+00 141-78-6 Ethyl Acetate 2.9 - 6.1E+01 9.5E-03 100-41-4 Ethylbenzene 1.1 4.9E+00 8.8E+02 2.2E-07 2.5E-04 109-99-9 ~Tetrahydrofuran - 1.8E+03 142-82-5 Heptane, N- 0.39 - 3.5E+02 2.2E-04 110-54-3 Hexane, N- 1.1 - 6.1E+02 3.6E-04 591-78-6 Hexanone, 2- - 2.6E+01 67-63-0 Isopropanol 3.2 - 1.8E+02 3.7E-03 78-93-3 Methyl Ethyl Ketone (2-Butanone) 4.3 - 4.4E+03 2.0E-04 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone) 13 - 2.6E+03 9.9E-04 75-09-2 Methylene Chloride 1.2E+03 5.3E+02 91-20-3 ~Naphthalene 0.55 3.6E-01 2.6E+00 1.5E-06 4.2E-02 100-42-5 Styrene 30 - 8.8E+02 6.8E-03 127-18-4 Tetrachloroethylene 4.7E+01 3.5E+01 108-88-3 Toluene 1.8 - 4.4E+03 8.2E-05 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2- 0.52 - 4.4E+03 2.4E-05 79-00-5 Trichloroethane, 1,1,2- 7.7E-01 1.8E-01 79-01-6 Trichloroethylene 3.0E+00 1.8E+00 75-69-4 Trichlorofluoromethane 120 - - 95-63-6 Trimethylbenzene, 1,2,4- 0.36 - 5.3E+01 1.4E-03 108-67-8 Trimethylbenzene, 1,3,5- 0.11 - 5.3E+01 4.2E-04 108-38-3 Xylene, m- 3.2 - 8.8E+01 7.3E-03 95-47-6 Xylene, o- 0.71 - 8.8E+01 1.6E-03 Cumulative: 2.6E-06 8.7E-02 All concentrations are in ug/m3 Output Form 3F ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: IAS-10 North Carolina Department of Environmental Quality Risk Calculator REEP LRC(RN) 1900 Continental Boulevard, Charlotte, NC DEQ DWM Brownfields 17047-13-060 July 2022 May 2022 EPA RSL Table Prepared By:Hart & Hickman 3921 Sunset Ridge Road, Suite 301, Raleigh, NC 27607 North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-10 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-10 Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes: CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 120 67-64-1 Acetone ug/m3 0.25 71-43-2 Benzene ug/m3 0.74 75-15-0 Carbon Disulfide ug/m3 0.38 56-23-5 Carbon Tetrachloride ug/m3 0.36 67-66-3 Chloroform ug/m3 1.5 74-87-3 Chloromethane ug/m3 0.99 75-71-8 Dichlorodifluoromethane ug/m3 2.2 107-06-2 Dichloroethane, 1,2-ug/m3 1.2 78-87-5 Dichloropropane, 1,2-ug/m3 3.5 141-78-6 Ethyl Acetate ug/m3 15 100-41-4 Ethylbenzene ug/m3 0.25 109-99-9 ~Tetrahydrofuran ug/m3 0.98 142-82-5 Heptane, N-ug/m3 2.3 110-54-3 Hexane, N-ug/m3 1.5 591-78-6 Hexanone, 2-ug/m3 6.3 67-63-0 Isopropanol ug/m3 7.3 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 1.3 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 0.94 75-09-2 Methylene Chloride ug/m3 1.4 91-20-3 ~Naphthalene ug/m3 9.5 100-42-5 Styrene ug/m3 0.39 127-18-4 Tetrachloroethylene ug/m3 37 108-88-3 Toluene ug/m3 0.52 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-ug/m3 0.31 79-00-5 Trichloroethane, 1,1,2-ug/m3 0.22 79-01-6 Trichloroethylene ug/m3 28 75-69-4 Trichlorofluoromethane ug/m3 5 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 1.7 108-67-8 Trimethylbenzene, 1,3,5-ug/m3 48 108-38-3 Xylene, m-ug/m3 33 95-47-6 Xylene, o-ug/m3 Input Form 2E Indoor Air Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-10 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air 1.3E-05 8.9E-01 NO Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1.If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Indoor Air Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 17047-13-060 Exposure Unit ID: IAS-10 CAS # Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 120 - - 71-43-2 Benzene 0.25 1.6E+00 2.6E+01 1.6E-07 1.9E-03 74-83-9 Bromomethane - 4.4E+00 75-15-0 Carbon Disulfide 0.74 - 6.1E+02 2.4E-04 56-23-5 Carbon Tetrachloride 0.38 2.0E+00 8.8E+01 1.9E-07 8.7E-04 67-66-3 Chloroform 0.36 5.3E-01 8.6E+01 6.8E-07 8.4E-04 74-87-3 Chloromethane 1.5 - 7.9E+01 3.8E-03 75-71-8 Dichlorodifluoromethane 0.99 - 8.8E+01 2.3E-03 107-06-2 Dichloroethane, 1,2- 2.2 4.7E-01 6.1E+00 4.7E-06 7.2E-02 156-60-5 Dichloroethylene, trans-1,2- - 3.5E+01 78-87-5 Dichloropropane, 1,2- 1.2 3.3E+00 3.5E+00 3.6E-07 6.8E-02 141-78-6 Ethyl Acetate 3.5 - 6.1E+01 1.1E-02 100-41-4 Ethylbenzene 15 4.9E+00 8.8E+02 3.1E-06 3.4E-03 109-99-9 ~Tetrahydrofuran 0.25 - 1.8E+03 2.9E-05 142-82-5 Heptane, N- 0.98 - 3.5E+02 5.6E-04 110-54-3 Hexane, N- 2.3 - 6.1E+02 7.5E-04 591-78-6 Hexanone, 2- 1.5 - 2.6E+01 1.1E-02 67-63-0 Isopropanol 6.3 - 1.8E+02 7.2E-03 78-93-3 Methyl Ethyl Ketone (2-Butanone) 7.3 - 4.4E+03 3.3E-04 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone) 1.3 - 2.6E+03 9.9E-05 75-09-2 Methylene Chloride 0.94 1.2E+03 5.3E+02 7.7E-10 3.6E-04 91-20-3 ~Naphthalene 1.4 3.6E-01 2.6E+00 3.9E-06 1.1E-01 100-42-5 Styrene 9.5 - 8.8E+02 2.2E-03 127-18-4 Tetrachloroethylene 0.39 4.7E+01 3.5E+01 8.3E-09 2.2E-03 108-88-3 Toluene 37 - 4.4E+03 1.7E-03 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2- 0.52 - 4.4E+03 2.4E-05 79-00-5 Trichloroethane, 1,1,2- 0.31 7.7E-01 1.8E-01 4.0E-07 3.5E-01 79-01-6 Trichloroethylene 0.22 3.0E+00 1.8E+00 7.4E-08 2.5E-02 75-69-4 Trichlorofluoromethane 28 - - 95-63-6 Trimethylbenzene, 1,2,4- 5 - 5.3E+01 1.9E-02 108-67-8 Trimethylbenzene, 1,3,5- 1.7 - 5.3E+01 6.5E-03 108-38-3 Xylene, m- 48 - 8.8E+01 1.1E-01 95-47-6 Xylene, o- 33 - 8.8E+01 7.5E-02 Cumulative: 1.3E-05 8.9E-01 All concentrations are in ug/m3 Output Form 3F ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator Appendix D Indoor Air Survey Forms INDOOR AIR BUILDING SURVEY and SAMPLING FORM Site Name: ____________________________________ DSCAID#: ______________________ Preparer’s name: ________________________________ Date: __________________________ Preparer’s affiliation: ____________________________ Phone #: _______________________ Part I - Occupants Building Address: ____________________________________________________________________ Property Contact: _______________________________ Owner / Renter / other: ______________ Contact’s Phone: home ( )__________ work ( )______________ cell ( )____________ # of Building occupants: Children under age 13 _____ Children age 13-18 ______ Adults _____ Part II – Building Characteristics Building type: residential / multi-family residential / office / strip mall / commercial / industrial Describe building: ________________________________________ Year constructed: _________ Sensitive population: day care / nursing home / hospital / school / other (specify): _______________ Number of floors below grade: ______ (full basement / crawl space / slab on grade) Number of floors at or above grade: ______ Depth of basement below grade surface: ______ ft. Basement size: _______ ft 2 Basement floor construction: concrete / dirt / floating / stone / other (specify): ________________ Foundation walls: poured concrete / cinder blocks / stone / other (specify) ________________ Basement sump present?Yes / No Sump pump?Yes / No Water in sump?Yes / No Type of heating system (circle all that apply): hot air circulation hot air radiation wood steam radiation heat pump hot water radiation kerosene heater electric baseboard other (specify): ________________________ Type of ventilation system (circle all that apply): central air conditioning mechanical fans bathroom ventilation fans individual air conditioning units kitchen range hood fan outside air intake other (specify): _________________ Type of fuel utilized (circle all that apply): Natural gas / electric / fuel oil / wood / coal / solar / kerosene Are the basement walls or floor sealed with waterproof paint or epoxy coatings? Yes / No Is there a whole house fan? Septic system? Irrigation/private well? Yes / No Yes / Yes (but not used) / No Yes / Yes (but not used) / No Type of ground cover outside of building: grass / concrete / asphalt / other (specify) _____________ Existing subsurface depressurization (radon) system in place?Yes / No active / passive Sub-slab vapor/moisture barrier in place?Yes / No Type of barrier: ____________________________ Part III - Outside Contaminant Sources Other stationary sources nearby (gas stations, emission stacks, etc.): _____________________________ Heavy vehicular traffic nearby (or other mobile sources): ______________________________________ Part IV – Indoor Contaminant Sources Identify all potential indoor sources found in the building (including attached garages), the location of the source (floor and room), and whether the item was removed from the building 48 hours prior to indoor air sampling event. Any ventilation implemented after removal of the items should be completed at least 24 hours prior to the commencement of the indoor air sampling event. Potential Sources Location(s)Removed (Yes / No / NA) Gasoline storage cans Gas-powered equipment Kerosene storage cans Paints / thinners / strippers Cleaning solvents Oven cleaners Carpet / upholstery cleaners Other house cleaning products Moth balls Polishes / waxes Insecticides Furniture / floor polish Nail polish / polish remover Hairspray Cologne / perfume Air fresheners Fuel tank (inside building) Wood stove or fireplace New furniture / upholstery New carpeting / flooring Hobbies - glues, paints, etc. Part V – Miscellaneous Items Do any occupants of the building smoke? Yes / No How often? ______________ Last time someone smoked in the building? ____________ hours / days ago Does the building have an attached garage directly connected to living space?Yes / No If so, is a car usually parked in the garage?Yes / No Are gas-powered equipment or cans of gasoline/fuels stored in the garage?Yes / No Do the occupants of the building have their clothes dry cleaned?Yes / No If yes, how often? weekly / monthly / 3-4 times a year Do any of the occupants use solvents in work?Yes / No If yes, what types of solvents are used? _______________________________________ If yes, are their clothes washed at work?Yes / No Have any pesticides/herbicides been applied around the building or in the yard?Yes / No If so, when and which chemicals? _________________________________________________ Has there ever been a fire in the building? Yes / No If yes, when? _____________ Has painting or staining been done in the building in the last 6 months? Yes / No If yes, when __________________ and where? ____________________________ Part VI – Sampling Information Sample Technician: ____________________________ Phone number: ( ) _______ - __________ Sample Source: Indoor Air / Crawlspace Air / Sub-Slab / Near Slab Soil Gas / Exterior Soil Gas Sampler Type: Tedlar bag / Sorbent / Stainless Steel Canister / Other (specify): _________________ Cert. Laboratory:Analytical Method: TO-15 / TO-17 / other: _____________ Sample locations (floor, room): Field ID # _____ - ________________________ Field ID # _____ - __________________________ Field ID # _____ - ________________________ Field ID # _____ - __________________________ Were “Instructions for Occupants” followed?Yes / No f not, describe modifications: _____________________________________________ Floor in Warehouse Provide Drawing of Sample Location(s) in Building Part VII - Meteorological Conditions Was there significant precipitation within 12 hours prior to (or during) the sampling event? Yes / No Describe the general weather conditions: _________________________________________________ _____________________________________________________________________________________ Part VIII – General Observations Provide any information that may be pertinent to the sampling event and may assist in the data interpretation process (e.g., observed that drycleaner operated with door or windows propped open for ventilation). (Adapted from the NJDEP Vapor Intrusion Guidance, October 2005) INDOOR AIR BUILDING SURVEY and SAMPLING FORM Site Name: ____________________________________ DSCAID#: ______________________ Preparer’s name: ________________________________ Date: __________________________ Preparer’s affiliation: ____________________________ Phone #: _______________________ Part I - Occupants Building Address: ____________________________________________________________________ Property Contact: _______________________________ Owner / Renter / other: ______________ Contact’s Phone: home ( )__________ work ( )______________ cell ( )____________ # of Building occupants: Children under age 13 _____ Children age 13-18 ______ Adults _____ Part II – Building Characteristics Building type: residential / multi-family residential / office / strip mall / commercial / industrial Describe building: ________________________________________ Year constructed: _________ Sensitive population: day care / nursing home / hospital / school / other (specify): _______________ Number of floors below grade: ______ (full basement / crawl space / slab on grade) Number of floors at or above grade: ______ Depth of basement below grade surface: ______ ft. Basement size: _______ ft 2 Basement floor construction: concrete / dirt / floating / stone / other (specify): ________________ Foundation walls: poured concrete / cinder blocks / stone / other (specify) ________________ Basement sump present?Yes / No Sump pump?Yes / No Water in sump? Yes / No Type of heating system (circle all that apply): hot air circulation hot air radiation wood steam radiation heat pump hot water radiation kerosene heater electric baseboard other (specify): ________________________ Type of ventilation system (circle all that apply): central air conditioning mechanical fans bathroom ventilation fans individual air conditioning units kitchen range hood fan outside air intake other (specify): _________________ Type of fuel utilized (circle all that apply): Natural gas / electric / fuel oil / wood / coal / solar / kerosene Are the basement walls or floor sealed with waterproof paint or epoxy coatings? Yes / No Is there a whole house fan? Septic system? Irrigation/private well? Yes / No Yes / Yes (but not used) / No Yes / Yes (but not used) / No Type of ground cover outside of building: grass / concrete / asphalt / other (specify) _____________ Existing subsurface depressurization (radon) system in place?Yes / No active / passive Sub-slab vapor/moisture barrier in place?Yes / No Type of barrier: ____________________________ Part III - Outside Contaminant Sources Other stationary sources nearby (gas stations, emission stacks, etc.): _____________________________ Heavy vehicular traffic nearby (or other mobile sources): ______________________________________ Part IV – Indoor Contaminant Sources Identify all potential indoor sources found in the building (including attached garages), the location of the source (floor and room), and whether the item was removed from the building 48 hours prior to indoor air sampling event. Any ventilation implemented after removal of the items should be completed at least 24 hours prior to the commencement of the indoor air sampling event. Potential Sources Location(s)Removed (Yes / No / NA) Gasoline storage cans Gas-powered equipment Kerosene storage cans Paints / thinners / strippers Cleaning solvents Oven cleaners Carpet / upholstery cleaners Other house cleaning products Moth balls Polishes / waxes Insecticides Furniture / floor polish Nail polish / polish remover Hairspray Cologne / perfume Air fresheners Fuel tank (inside building) Wood stove or fireplace New furniture / upholstery New carpeting / flooring Hobbies - glues, paints, etc. Part V – Miscellaneous Items Do any occupants of the building smoke? Yes / No How often? ______________ Last time someone smoked in the building? ____________ hours / days ago Does the building have an attached garage directly connected to living space?Yes / No If so, is a car usually parked in the garage?Yes / No Are gas-powered equipment or cans of gasoline/fuels stored in the garage?Yes / No Do the occupants of the building have their clothes dry cleaned?Yes / No If yes, how often? weekly / monthly / 3-4 times a year Do any of the occupants use solvents in work?Yes / No If yes, what types of solvents are used? _______________________________________ If yes, are their clothes washed at work?Yes / No Have any pesticides/herbicides been applied around the building or in the yard?Yes / No If so, when and which chemicals? _________________________________________________ Has there ever been a fire in the building? Yes / No If yes, when? _____________ Has painting or staining been done in the building in the last 6 months? Yes / No If yes, when __________________ and where? ____________________________ Part VI – Sampling Information Sample Technician: ____________________________ Phone number: ( ) _______ - __________ Sample Source: Indoor Air / Crawlspace Air / Sub-Slab / Near Slab Soil Gas / Exterior Soil Gas Sampler Type: Tedlar bag / Sorbent / Stainless Steel Canister / Other (specify): _________________ Cert. Laboratory:Analytical Method: TO-15 / TO-17 / other: _____________ Sample locations (floor, room): Field ID # _____ - ________________________ Field ID # _____ - __________________________ Field ID # _____ - ________________________ Field ID # _____ - __________________________ Were “Instructions for Occupants” followed? Yes / No f not, describe modifications: _____________________________________________ Floor in Warehouse Provide Drawing of Sample Location(s) in Building Part VII - Meteorological Conditions Was there significant precipitation within 12 hours prior to (or during) the sampling event? Yes / No Describe the general weather conditions: _________________________________________________ _____________________________________________________________________________________ Part VIII – General Observations Provide any information that may be pertinent to the sampling event and may assist in the data interpretation process (e.g., observed that drycleaner operated with door or windows propped open for ventilation). (Adapted from the NJDEP Vapor Intrusion Guidance, October 2005) INDOOR AIR BUILDING SURVEY and SAMPLING FORM Site Name: ____________________________________ DSCAID#: ______________________ Preparer’s name: ________________________________ Date: __________________________ Preparer’s affiliation: ____________________________ Phone #: _______________________ Part I - Occupants Building Address: ____________________________________________________________________ Property Contact: _______________________________ Owner / Renter / other: ______________ Contact’s Phone: home ( )__________ work ( )______________ cell ( )____________ # of Building occupants: Children under age 13 _____ Children age 13-18 ______ Adults _____ Part II – Building Characteristics Building type: residential / multi-family residential / office / strip mall / commercial / industrial Describe building: ________________________________________ Year constructed: _________ Sensitive population: day care / nursing home / hospital / school / other (specify): _______________ Number of floors below grade: ______ (full basement / crawl space / slab on grade) Number of floors at or above grade: ______ Depth of basement below grade surface: ______ ft. Basement size: _______ ft 2 Basement floor construction: concrete / dirt / floating / stone / other (specify): ________________ Foundation walls: poured concrete / cinder blocks / stone / other (specify) ________________ Basement sump present?Yes / No Sump pump?Yes / No Water in sump? Yes / No Type of heating system (circle all that apply): hot air circulation hot air radiation wood steam radiation heat pump hot water radiation kerosene heater electric baseboard other (specify): ________________________ Type of ventilation system (circle all that apply): central air conditioning mechanical fans bathroom ventilation fans individual air conditioning units kitchen range hood fan outside air intake other (specify): _________________ Type of fuel utilized (circle all that apply): Natural gas / electric / fuel oil / wood / coal / solar / kerosene Are the basement walls or floor sealed with waterproof paint or epoxy coatings? Yes / No Is there a whole house fan? Septic system? Irrigation/private well? Yes / No Yes / Yes (but not used) / No Yes / Yes (but not used) / No Type of ground cover outside of building: grass / concrete / asphalt / other (specify) _____________ Existing subsurface depressurization (radon) system in place?Yes / No active / passive Sub-slab vapor/moisture barrier in place?Yes / No Type of barrier: ____________________________ Part III - Outside Contaminant Sources Other stationary sources nearby (gas stations, emission stacks, etc.): _____________________________ Heavy vehicular traffic nearby (or other mobile sources): ______________________________________ Part IV – Indoor Contaminant Sources Identify all potential indoor sources found in the building (including attached garages), the location of the source (floor and room), and whether the item was removed from the building 48 hours prior to indoor air sampling event. Any ventilation implemented after removal of the items should be completed at least 24 hours prior to the commencement of the indoor air sampling event. Potential Sources Location(s)Removed (Yes / No / NA) Gasoline storage cans Gas-powered equipment Kerosene storage cans Paints / thinners / strippers Cleaning solvents Oven cleaners Carpet / upholstery cleaners Other house cleaning products Moth balls Polishes / waxes Insecticides Furniture / floor polish Nail polish / polish remover Hairspray Cologne / perfume Air fresheners Fuel tank (inside building) Wood stove or fireplace New furniture / upholstery New carpeting / flooring Hobbies - glues, paints, etc. Part V – Miscellaneous Items Do any occupants of the building smoke? Yes / No How often? ______________ Last time someone smoked in the building? ____________ hours / days ago Does the building have an attached garage directly connected to living space?Yes / No If so, is a car usually parked in the garage?Yes / No Are gas-powered equipment or cans of gasoline/fuels stored in the garage?Yes / No Do the occupants of the building have their clothes dry cleaned?Yes / No If yes, how often? weekly / monthly / 3-4 times a year Do any of the occupants use solvents in work?Yes / No If yes, what types of solvents are used? _______________________________________ If yes, are their clothes washed at work?Yes / No Have any pesticides/herbicides been applied around the building or in the yard?Yes / No If so, when and which chemicals? _________________________________________________ Has there ever been a fire in the building? Yes / No If yes, when? _____________ Has painting or staining been done in the building in the last 6 months? Yes / No If yes, when __________________ and where? ____________________________ Part VI – Sampling Information Sample Technician: ____________________________ Phone number: ( ) _______ - __________ Sample Source: Indoor Air / Crawlspace Air / Sub-Slab / Near Slab Soil Gas / Exterior Soil Gas Sampler Type: Tedlar bag / Sorbent / Stainless Steel Canister / Other (specify): _________________ Cert. Laboratory:Analytical Method: TO-15 / TO-17 / other: _____________ Sample locations (floor, room): Field ID # _____ - ________________________ Field ID # _____ - __________________________ Field ID # _____ - ________________________ Field ID # _____ - __________________________ Were “Instructions for Occupants” followed? Yes / No f not, describe modifications: _____________________________________________ Floor in Warehouse Provide Drawing of Sample Location(s) in Building Part VII - Meteorological Conditions Was there significant precipitation within 12 hours prior to (or during) the sampling event? Yes / No Describe the general weather conditions: _________________________________________________ _____________________________________________________________________________________ Part VIII – General Observations Provide any information that may be pertinent to the sampling event and may assist in the data interpretation process (e.g., observed that drycleaner operated with door or windows propped open for ventilation). (Adapted from the NJDEP Vapor Intrusion Guidance, October 2005) INDOOR AIR BUILDING SURVEY and SAMPLING FORM Site Name: ____________________________________ DSCAID#: ______________________ Preparer’s name: ________________________________ Date: __________________________ Preparer’s affiliation: ____________________________ Phone #: _______________________ Part I - Occupants Building Address: ____________________________________________________________________ Property Contact: _______________________________ Owner / Renter / other: ______________ Contact’s Phone: home ( )__________ work ( )______________ cell ( )____________ # of Building occupants: Children under age 13 _____ Children age 13-18 ______ Adults _____ Part II – Building Characteristics Building type: residential / multi-family residential / office / strip mall / commercial / industrial Describe building: ________________________________________ Year constructed: _________ Sensitive population: day care / nursing home / hospital / school / other (specify): _______________ Number of floors below grade: ______ (full basement / crawl space / slab on grade) Number of floors at or above grade: ______ Depth of basement below grade surface: ______ ft. Basement size: _______ ft 2 Basement floor construction: concrete / dirt / floating / stone / other (specify): ________________ Foundation walls: poured concrete / cinder blocks / stone / other (specify) ________________ Basement sump present?Yes / No Sump pump?Yes / No Water in sump? Yes / No Type of heating system (circle all that apply): hot air circulation hot air radiation wood steam radiation heat pump hot water radiation kerosene heater electric baseboard other (specify): ________________________ Type of ventilation system (circle all that apply): central air conditioning mechanical fans bathroom ventilation fans individual air conditioning units kitchen range hood fan outside air intake other (specify): _________________ Type of fuel utilized (circle all that apply): Natural gas / electric / fuel oil / wood / coal / solar / kerosene Are the basement walls or floor sealed with waterproof paint or epoxy coatings? Yes / No Is there a whole house fan? Septic system? Irrigation/private well? Yes / No Yes / Yes (but not used) / No Yes / Yes (but not used) / No Type of ground cover outside of building: grass / concrete / asphalt / other (specify) _____________ Existing subsurface depressurization (radon) system in place?Yes / No active / passive Sub-slab vapor/moisture barrier in place?Yes / No Type of barrier: ____________________________ Part III - Outside Contaminant Sources Other stationary sources nearby (gas stations, emission stacks, etc.): _____________________________ Heavy vehicular traffic nearby (or other mobile sources): ______________________________________ Part IV – Indoor Contaminant Sources Identify all potential indoor sources found in the building (including attached garages), the location of the source (floor and room), and whether the item was removed from the building 48 hours prior to indoor air sampling event. Any ventilation implemented after removal of the items should be completed at least 24 hours prior to the commencement of the indoor air sampling event. Potential Sources Location(s)Removed (Yes / No / NA) Gasoline storage cans Gas-powered equipment Kerosene storage cans Paints / thinners / strippers Cleaning solvents Oven cleaners Carpet / upholstery cleaners Other house cleaning products Moth balls Polishes / waxes Insecticides Furniture / floor polish Nail polish / polish remover Hairspray Cologne / perfume Air fresheners Fuel tank (inside building) Wood stove or fireplace New furniture / upholstery New carpeting / flooring Hobbies - glues, paints, etc. Part V – Miscellaneous Items Do any occupants of the building smoke? Yes / No How often? ______________ Last time someone smoked in the building? ____________ hours / days ago Does the building have an attached garage directly connected to living space?Yes / No If so, is a car usually parked in the garage?Yes / No Are gas-powered equipment or cans of gasoline/fuels stored in the garage?Yes / No Do the occupants of the building have their clothes dry cleaned?Yes / No If yes, how often? weekly / monthly / 3-4 times a year Do any of the occupants use solvents in work?Yes / No If yes, what types of solvents are used? _______________________________________ If yes, are their clothes washed at work?Yes / No Have any pesticides/herbicides been applied around the building or in the yard?Yes / No If so, when and which chemicals? _________________________________________________ Has there ever been a fire in the building? Yes / No If yes, when? _____________ Has painting or staining been done in the building in the last 6 months? Yes / No If yes, when __________________ and where? ____________________________ Part VI – Sampling Information Sample Technician: ____________________________ Phone number: ( ) _______ - __________ Sample Source: Indoor Air / Crawlspace Air / Sub-Slab / Near Slab Soil Gas / Exterior Soil Gas Sampler Type: Tedlar bag / Sorbent / Stainless Steel Canister / Other (specify): _________________ Cert. Laboratory:Analytical Method: TO-15 / TO-17 / other: _____________ Sample locations (floor, room): Field ID # _____ - ________________________ Field ID # _____ - __________________________ Field ID # _____ - ________________________ Field ID # _____ - __________________________ Were “Instructions for Occupants” followed? Yes / No f not, describe modifications: _____________________________________________ Floor in Warehouse Provide Drawing of Sample Location(s) in Building Part VII - Meteorological Conditions Was there significant precipitation within 12 hours prior to (or during) the sampling event? Yes / No Describe the general weather conditions: _________________________________________________ _____________________________________________________________________________________ Part VIII – General Observations Provide any information that may be pertinent to the sampling event and may assist in the data interpretation process (e.g., observed that drycleaner operated with door or windows propped open for ventilation). (Adapted from the NJDEP Vapor Intrusion Guidance, October 2005) IAS-5 SS-21 IAS-6 SS-22 INDOOR AIR BUILDING SURVEY and SAMPLING FORM Site Name: ____________________________________ DSCAID#: ______________________ Preparer’s name: ________________________________ Date: __________________________ Preparer’s affiliation: ____________________________ Phone #: _______________________ Part I - Occupants Building Address: ____________________________________________________________________ Property Contact: _______________________________ Owner / Renter / other: ______________ Contact’s Phone: home ( )__________ work ( )______________ cell ( )____________ # of Building occupants: Children under age 13 _____ Children age 13-18 ______ Adults _____ Part II – Building Characteristics Building type: residential / multi-family residential / office / strip mall / commercial / industrial Describe building: ________________________________________ Year constructed: _________ Sensitive population: day care / nursing home / hospital / school / other (specify): _______________ Number of floors below grade: ______ (full basement / crawl space / slab on grade) Number of floors at or above grade: ______ Depth of basement below grade surface: ______ ft. Basement size: _______ ft 2 Basement floor construction: concrete / dirt / floating / stone / other (specify): ________________ Foundation walls: poured concrete / cinder blocks / stone / other (specify) ________________ Basement sump present?Yes / No Sump pump?Yes / No Water in sump? Yes / No Type of heating system (circle all that apply): hot air circulation hot air radiation wood steam radiation heat pump hot water radiation kerosene heater electric baseboard other (specify): ________________________ Type of ventilation system (circle all that apply): central air conditioning mechanical fans bathroom ventilation fans individual air conditioning units kitchen range hood fan outside air intake other (specify): _________________ Type of fuel utilized (circle all that apply): Natural gas / electric / fuel oil / wood / coal / solar / kerosene Are the basement walls or floor sealed with waterproof paint or epoxy coatings? Yes / No Is there a whole house fan? Septic system? Irrigation/private well? Yes / No Yes / Yes (but not used) / No Yes / Yes (but not used) / No Type of ground cover outside of building: grass / concrete / asphalt / other (specify) _____________ Existing subsurface depressurization (radon) system in place?Yes / No active / passive Sub-slab vapor/moisture barrier in place?Yes / No Type of barrier: ____________________________ Part III - Outside Contaminant Sources Other stationary sources nearby (gas stations, emission stacks, etc.): _____________________________ Heavy vehicular traffic nearby (or other mobile sources): ______________________________________ Part IV – Indoor Contaminant Sources Identify all potential indoor sources found in the building (including attached garages), the location of the source (floor and room), and whether the item was removed from the building 48 hours prior to indoor air sampling event. Any ventilation implemented after removal of the items should be completed at least 24 hours prior to the commencement of the indoor air sampling event. Potential Sources Location(s)Removed (Yes / No / NA) Gasoline storage cans Gas-powered equipment Kerosene storage cans Paints / thinners / strippers Cleaning solvents Oven cleaners Carpet / upholstery cleaners Other house cleaning products Moth balls Polishes / waxes Insecticides Furniture / floor polish Nail polish / polish remover Hairspray Cologne / perfume Air fresheners Fuel tank (inside building) Wood stove or fireplace New furniture / upholstery New carpeting / flooring Hobbies - glues, paints, etc. Part V – Miscellaneous Items Do any occupants of the building smoke? Yes / No How often? ______________ Last time someone smoked in the building? ____________ hours / days ago Does the building have an attached garage directly connected to living space?Yes / No If so, is a car usually parked in the garage?Yes / No Are gas-powered equipment or cans of gasoline/fuels stored in the garage?Yes / No Do the occupants of the building have their clothes dry cleaned?Yes / No If yes, how often? weekly / monthly / 3-4 times a year Do any of the occupants use solvents in work?Yes / No If yes, what types of solvents are used? _______________________________________ If yes, are their clothes washed at work?Yes / No Have any pesticides/herbicides been applied around the building or in the yard?Yes / No If so, when and which chemicals? _________________________________________________ Has there ever been a fire in the building? Yes / No If yes, when? _____________ Has painting or staining been done in the building in the last 6 months? Yes / No If yes, when __________________ and where? ____________________________ Part VI – Sampling Information Sample Technician: ____________________________ Phone number: ( ) _______ - __________ Sample Source: Indoor Air / Crawlspace Air / Sub-Slab / Near Slab Soil Gas / Exterior Soil Gas Sampler Type: Tedlar bag / Sorbent / Stainless Steel Canister / Other (specify): _________________ Cert. Laboratory:Analytical Method: TO-15 / TO-17 / other: _____________ Sample locations (floor, room): Field ID # _____ - ________________________ Field ID # _____ - __________________________ Field ID # _____ - ________________________ Field ID # _____ - __________________________ Were “Instructions for Occupants” followed? Yes / No f not, describe modifications: _____________________________________________ Floor in Warehouse Provide Drawing of Sample Location(s) in Building Part VII - Meteorological Conditions Was there significant precipitation within 12 hours prior to (or during) the sampling event? Yes / No Describe the general weather conditions: _________________________________________________ _____________________________________________________________________________________ Part VIII – General Observations Provide any information that may be pertinent to the sampling event and may assist in the data interpretation process (e.g., observed that drycleaner operated with door or windows propped open for ventilation). (Adapted from the NJDEP Vapor Intrusion Guidance, October 2005) IAS-4 SS-20 IAS-3 SS-19 INDOOR AIR BUILDING SURVEY and SAMPLING FORM Site Name: ____________________________________ DSCAID#: ______________________ Preparer’s name: ________________________________ Date: __________________________ Preparer’s affiliation: ____________________________ Phone #: _______________________ Part I - Occupants Building Address: ____________________________________________________________________ Property Contact: _______________________________ Owner / Renter / other: ______________ Contact’s Phone: home ( )__________ work ( )______________ cell ( )____________ # of Building occupants: Children under age 13 _____ Children age 13-18 ______ Adults _____ Part II – Building Characteristics Building type: residential / multi-family residential / office / strip mall / commercial / industrial Describe building: ________________________________________ Year constructed: _________ Sensitive population: day care / nursing home / hospital / school / other (specify): _______________ Number of floors below grade: ______ (full basement / crawl space / slab on grade) Number of floors at or above grade: ______ Depth of basement below grade surface: ______ ft. Basement size: _______ ft 2 Basement floor construction: concrete / dirt / floating / stone / other (specify): ________________ Foundation walls: poured concrete / cinder blocks / stone / other (specify) ________________ Basement sump present?Yes / No Sump pump?Yes / No Water in sump? Yes / No Type of heating system (circle all that apply): hot air circulation hot air radiation wood steam radiation heat pump hot water radiation kerosene heater electric baseboard other (specify): ________________________ Type of ventilation system (circle all that apply): central air conditioning mechanical fans bathroom ventilation fans individual air conditioning units kitchen range hood fan outside air intake other (specify): _________________ Type of fuel utilized (circle all that apply): Natural gas / electric / fuel oil / wood / coal / solar / kerosene Are the basement walls or floor sealed with waterproof paint or epoxy coatings? Yes / No Is there a whole house fan? Septic system? Irrigation/private well? Yes / No Yes / Yes (but not used) / No Yes / Yes (but not used) / No Type of ground cover outside of building: grass / concrete / asphalt / other (specify) _____________ Existing subsurface depressurization (radon) system in place?Yes / No active / passive Sub-slab vapor/moisture barrier in place?Yes / No Type of barrier: ____________________________ Part III - Outside Contaminant Sources Other stationary sources nearby (gas stations, emission stacks, etc.): _____________________________ Heavy vehicular traffic nearby (or other mobile sources): ______________________________________ Part IV – Indoor Contaminant Sources Identify all potential indoor sources found in the building (including attached garages), the location of the source (floor and room), and whether the item was removed from the building 48 hours prior to indoor air sampling event. Any ventilation implemented after removal of the items should be completed at least 24 hours prior to the commencement of the indoor air sampling event. Potential Sources Location(s)Removed (Yes / No / NA) Gasoline storage cans Gas-powered equipment Kerosene storage cans Paints / thinners / strippers Cleaning solvents Oven cleaners Carpet / upholstery cleaners Other house cleaning products Moth balls Polishes / waxes Insecticides Furniture / floor polish Nail polish / polish remover Hairspray Cologne / perfume Air fresheners Fuel tank (inside building) Wood stove or fireplace New furniture / upholstery New carpeting / flooring Hobbies - glues, paints, etc. Part V – Miscellaneous Items Do any occupants of the building smoke? Yes / No How often? ______________ Last time someone smoked in the building? ____________ hours / days ago Does the building have an attached garage directly connected to living space?Yes / No If so, is a car usually parked in the garage?Yes / No Are gas-powered equipment or cans of gasoline/fuels stored in the garage?Yes / No Do the occupants of the building have their clothes dry cleaned?Yes / No If yes, how often? weekly / monthly / 3-4 times a year Do any of the occupants use solvents in work?Yes / No If yes, what types of solvents are used? _______________________________________ If yes, are their clothes washed at work?Yes / No Have any pesticides/herbicides been applied around the building or in the yard?Yes / No If so, when and which chemicals? _________________________________________________ Has there ever been a fire in the building? Yes / No If yes, when? _____________ Has painting or staining been done in the building in the last 6 months? Yes / No If yes, when __________________ and where? ____________________________ Part VI – Sampling Information Sample Technician: ____________________________ Phone number: ( ) _______ - __________ Sample Source: Indoor Air / Crawlspace Air / Sub-Slab / Near Slab Soil Gas / Exterior Soil Gas Sampler Type: Tedlar bag / Sorbent / Stainless Steel Canister / Other (specify): _________________ Cert. Laboratory:Analytical Method: TO-15 / TO-17 / other: _____________ Sample locations (floor, room): Field ID # _____ - ________________________ Field ID # _____ - __________________________ Field ID # _____ - ________________________ Field ID # _____ - __________________________ Were “Instructions for Occupants” followed? Yes / No f not, describe modifications: _____________________________________________ Floor in Warehouse Provide Drawing of Sample Location(s) in Building Part VII - Meteorological Conditions Was there significant precipitation within 12 hours prior to (or during) the sampling event? Yes / No Describe the general weather conditions: _________________________________________________ _____________________________________________________________________________________ Part VIII – General Observations Provide any information that may be pertinent to the sampling event and may assist in the data interpretation process (e.g., observed that drycleaner operated with door or windows propped open for ventilation). (Adapted from the NJDEP Vapor Intrusion Guidance, October 2005)