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Home My WebLink About19054_HD Supply_VIMS Annual Sampling Report_2022-11-18 #C1269 – Engineering #C245 – Geology VIMS Annual & Supplemental Sampling Report South Tower HD Supply Brownfields Property 1414 South Tryon Street Charlotte, North Carolina Brownfields Project No. 19054-15-060 H&H Job No. COU-001 November 18, 2022 i S:\AAA-Master Projects\Beacon Partners- BEP or BCP\BCP-064 1414 and 1422 S. Tryon\Brownfields\VIMS Installation Reports\February & March 2021\VIMS Post-Occupancy Sampling Report #1.docx VIMS Annual & Supplemental Sampling Report South Tower HD Supply Brownfields Property 1414 South Tryon Street Charlotte, Mecklenburg County, North Carolina Brownfields Project No. 19054-15-060 H&H Job No. COU-001 Table of Contents Section Page No. 1.0 Introduction ..............................................................................................................................1 1.1 Background ............................................................................................................................1 2.0 Vapor Intrusion Mitigation System Installation ..................................................................4 3.0 Annual Sampling Activities ....................................................................................................5 3.1 Building Survey Activities ....................................................................................................5 3.2 Indoor Air Sampling ..............................................................................................................5 3.3 Indoor Air Sampling Results .................................................................................................7 3.4 Vapor Intrusion Evaluation ...................................................................................................7 4.0 Supplemental Sampling ...........................................................................................................9 4.1 Sampling Methodology .........................................................................................................9 4.2 Sampling Results ..................................................................................................................10 5.0 Summary and Conclusions...................................................................................................12 List of Tables Table 1 Site-Specific Indoor Air VOC List Table 2 Summary of Analytical Results (2022) ii https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Cousins Properties (COU)/COU-001 - RailYard/VIMS Annual IA (May 2022)/Report/VIMS Annual Sampling Report.docx List of Figures Figure 1 Site Location Map Figure 2 Site Map Figure 3 Sample Location Map List of Appendices Appendix A Previous Annual Indoor Air Analytical Data Appendix B VIMS As-Built Drawing (VM-1) Appendix C Field Forms Appendix D Laboratory Analytical Reports Appendix E DEQ Risk Calculators Appendix F Safety Data Sheets (SDSs) 1 S:\AAA-Master Projects\Beacon Partners- BEP or BCP\BCP-064 1414 and 1422 S. Tryon\Brownfields\VIMS Installation Reports\February & March 2021\VIMS Post-Occupancy Sampling Report #1.docx VIMS Annual & Supplemental Sampling Report South Tower HD Supply Brownfields Site 1414 South Tryon Street Charlotte, Mecklenburg County, North Carolina Brownfields Project No. 19054-15-060 H&H Job No. COU-001 1.0 Introduction On behalf of Cousins Railyard LP (Cousins [owner]), Hart & Hickman, PC (H&H) has prepared this report to document vapor intrusion mitigation system (VIMS) annual indoor air and supplemental sub-slab vapor and indoor air sampling activities completed for the south tower at the HD Supply North Carolina Department of Environmental Quality (DEQ) Brownfields property (Brownfields Project No. 19054-15-060). The Brownfields property is located at 1414 South Tryon Street in Charlotte, Mecklenburg County, North Carolina (Site or subject Site). A Site location map is provided as Figure 1. 1.1 Background The Brownfields property was previously comprised of one approximately 3.38-acre parcel of land owned by RailYard, LLC (formerly Beacon MPI, LLC). However, RailYard, LLC sold an approximately 0.74-acre area in the western portion of the Site to Centro RailYard, LLC on November 27, 2018. Currently, the HD Supply Brownfields property is comprised of two parcels. The larger approximately 2.77-acres parcel (Parcel No. 07309204) was developed by RailYard, LLC with two multi-purpose high-rise towers (north tower and south tower) which consist of commercial office and retail spaces and a parking deck. RailYard, LLC subsequently sold the property to Cousins RailYard LP in December 2020. The smaller approximately 0.74-acre parcel (Parcel No. 07309217) was developed by Centro RailYard, LLC with a multi-story building including retail commercial units on the ground floor with multi-family residential apartment units above. Centro RailYard, LLC subsequently sold the smaller parcel and is currently owned by 1425 Winnifred NC Property LLC. A Site map is provided as Figure 2. 2 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Cousins Properties (COU)/COU-001 - RailYard/VIMS Annual IA (May 2022)/Report/VIMS Annual Sampling Report.docx The ground floor of the south tower includes five commercial tenant spaces, a lobby, and amenity spaces. During construction of the building, the ground floor tenant spaces were constructed as pour-back areas, where a concrete slab is not installed until tenants perform upfit activities. Currently, four of the tenant spaces on the ground floor have been upfitted, and concrete slabs have been poured in those spaces. The barbershop, Bishops Haircuts (Bishops), currently occupies an approximately 2,000 square foot (sq ft) space in the south-central portion of the ground floor of the south tower, and the restaurant STIR currently occupies an approximately 4,500 sq ft space in the northeastern portion of the ground floor in the south tower. The Beem Light Sauna currently occupies an approximately 1,000 sq ft space in the southwestern portion of the ground floor in south tower. The southeastern tenant space is currently undergoing upfit and will be occupied by the restaurant called Summerbird upon completion. There is one vacant space (Retail South 160A) remaining located between Beem Light Sauna and Bishops. The occupied spaces, including the lobby and amenity spaces, have an approximately 4-inch thick concrete slab. A concrete slab has not been poured in the vacant space to allow for future tenant upfit. The locations of the tenant spaces are depicted on the sample location map included as Figure 3. Results of previous assessment activities indicated that vapor mitigation was not warranted for the north tower. However, based on the presence of a historical dry-cleaner on the southern portion of the Site, installation of a VIMS below the south tower was warranted. As such, a Vapor Intrusion Mitigation Plan (VIMP) was prepared and submitted to the DEQ on June 20, 2018, for the south tower to address the potential vapor intrusion concern. The VIMP was subsequently approved by DEQ in a letter dated July 18, 2018. VIMS installation activities for the south tower are documented in H&H’s VIMS Progress Report South Tower dated November 6, 2020. As required in the VIMP, annual indoor air sampling events were to be completed for three years in the south tower following occupancy of the building. The first annual sampling event was completed over the course of two different dates to account of the upfit schedule of the commercial spaces (November 4, 2019 and June 22, 2020) as documented in the VIMS Progress Report South Tower. The second annual sampling event was completed over the course of two different dates as well (February 25, 2021 and March 23, 2021) as documented in the VIMS Post-Occupancy Indoor Air Sampling Report South Tower. The third annual sampling event was conducted in May 3 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Cousins Properties (COU)/COU-001 - RailYard/VIMS Annual IA (May 2022)/Report/VIMS Annual Sampling Report.docx 2022. Based on the May 2022 sampling results and per DEQ request, supplemental indoor air samples, along with co-currently located sub-slab soil gas (vapor) samples were collected in August 2022. The May 2022 annual sampling event and the August 2022 supplemental sampling event are described herein. For reference, the annual indoor air sampling data from the previous sampling events is included in Appendix A. A brief summary of the existing VIMS is provided in Section 2.0, a discussion of annual sampling activities is provided in Section 3.0, a discussion of supplement sampling activities is provided in Section 4.0, and summary and conclusions based on the sampling results are provided in Section 5.0. 4 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Cousins Properties (COU)/COU-001 - RailYard/VIMS Annual IA (May 2022)/Report/VIMS Annual Sampling Report.docx 2.0 Vapor Intrusion Mitigation System Installation As detailed in the VIMP, the VIMS consists of a passive sub-slab vapor extraction system. The system is constructed with 3-inch diameter slotted horizontal poly-vinyl chloride (PVC) pipe installed in approximately 5 to 6 inches of high permeability gravel (#57 stone) below the building’s concrete slab. The gravel layer is overlain by the 15-mil Stego Wrap (Stego) vapor barrier manufactured by Stego Industries LLC. The horizontal PVC pipes are connected to seven 3-inch diameter cast iron riser pipes which extend through the building and terminated approximately 3 feet to 5 feet above the roofline. Wind driven turbine ventilators are installed on each of the seven riser pipes to enhance airflow from the risers. While concrete in the vacant tenant space has not been poured, the gravel layer is covered and sealed with the 15-mil Stego vapor barrier. Additional details regarding the VIMS components and specifications were provided in the VIMS Progress Report South Tower. For reference, the VIMS as-built drawings are provided in Appendix B. 5 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Cousins Properties (COU)/COU-001 - RailYard/VIMS Annual IA (May 2022)/Report/VIMS Annual Sampling Report.docx 3.0 Annual Sampling Activities The annual indoor air sampling activities were conducted in accordance with the DEQ-approved VIMP and the DEQ Division of Waste Management (DWM) Vapor Intrusion Guidance (Guidance) dated March 2018. A description of the sampling activities and results is provided below. 3.1 Building Survey Activities Prior to collecting indoor air samples during each sampling event, H&H completed a survey in the building to identify potential sources of compounds of concern. The survey identified the use of cleaning solvents and products in the STIR restaurant space, along with new furniture and finishing materials (carpet, flooring, etc.) in portions of the building. A copy of the indoor air building survey completed during the sampling event is provided in Appendix C. 3.2 Indoor Air Sampling The third post-occupancy annual sampling event was performed by H&H on May 20, 2022. H&H collected five indoor air samples for laboratory analysis from representative common area and completed commercial tenant spaces on the first-floor of the south tower. Samples IAS-1 and IAS-2 were collected in communal spaces on the first floor of the south tower in a recently renovated office space and a fitness center, respectively. IAS-3 was collected in the corridor behind the vacant retail tenant space. Air sample IAS-4 was collected in the kitchen of the STIR restaurant space and IAS-5 was collected in the dining area of STIR. During the sampling event, an upwind exterior background air sample (BAS-1) was collected concurrently with the indoor air samples to evaluate compound concentrations in ambient outdoor air. Additionally, a duplicate indoor air sample (IAS-DUP) was collected with parent indoor air sample IAS-1 utilizing a laboratory supplied stainless-steel sampling “T” which allows for the simultaneous collection of two indoor air samples from a single location. The indoor air samples were collected using laboratory-supplied individually-certified 6-liter stainless steel Summa canisters connected to in-line flow controllers with a vacuum gauge. The 6 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Cousins Properties (COU)/COU-001 - RailYard/VIMS Annual IA (May 2022)/Report/VIMS Annual Sampling Report.docx background air sample was collected using laboratory-supplied batch certified 6-liter stainless steel Summa canister connected to an in-line flow controller with a vacuum gauge. The flow controllers were calibrated by the laboratory to allow for sample collection over an approximately 8-hour period based on the commercial use of the south tower. Summa canisters were placed in positions such that the sample intake point was positioned approximately 5 ft above grade (typical breathing zone height) when the sample canister was set on its base. During the sampling activities, indoor/outdoor air pressure differential was measured near the start, middle, and end of the 8-hour sampling period using a manometer sensitive to 0.001 inches of water. In addition, barometric pressure, exterior wind speed, exterior wind direction, and indoor/outdoor temperature were recorded near the start, middle, and end of the sampling period. A summary of the field measurement data collected at the time of the indoor air sampling event is provided in indoor air sampling forms included as Appendix C. For quality assurance purposes, H&H personnel periodically monitored the sample canisters to prevent tampering or damage during the sampling event. Vacuum was measured in each of the Summa canisters prior to and after sampling activities. Per laboratory standard operating procedures, a vacuum was maintained within the canisters at the conclusion of the sampling event. Upon completion of the indoor air sampling event, the Summa canisters were properly labeled with the sample identification, date, time, starting and ending vacuums, and requested analysis and were placed in a laboratory-supplied shipping container. The samples were shipped under standard chain-of-custody protocols to Waypoint Analytical (Waypoint) for analysis of select volatile organic compounds by Environmental Protection Agency (EPA) Method TO-15 in accordance with the VIMP. The target analyte list for the indoor air samples included each compound that was detected above laboratory reporting limits during previous soil gas sampling completed at the Site. The Site-specific list of VOCs is provided on Table 1. 7 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Cousins Properties (COU)/COU-001 - RailYard/VIMS Annual IA (May 2022)/Report/VIMS Annual Sampling Report.docx 3.3 Indoor Air Sampling Results A tabular summary of the indoor air sampling results from 2022 is provided as Table 2. The indoor air analytical results were compared to the DEQ DWM Non-Residential Vapor Intrusion Indoor Air Screening Levels (IASLs) dated July 2022. Copies of the laboratory analytical reports and chain-of-custody records are provided in Appendix D. Laboratory analytical results from the May 2022 indoor air sampling event indicate the presence of chloroform above the Non-Residential IASL of 0.53 µg/m3 in sample IAS-3 (located in the corridor outside the vacant tenant space), IAS-4 (located in the STIR kitchen), and IAS-5 (location in the STIR dining area) at concentrations of 0.630 J µg/m3, 3.34 µg/m3, and 1.49 J µg/m3, respectively. The J-flag indicates an estimated concentration detected above the laboratory method detection limit (MDL), but the flow the laboratory reporting limit. The compound isopropanol was detected in each sample, but only exceeded the Non-Residential IASL of 180 µg/m3 in sample IAS-3 (997 µg/m3) and IAS-4 (218 J µg/m3). Tetrachloroethene (PCE) was detected above the laboratory MDL in each sample collected, but each detection was below the Non-Residential IASLs. Trichloroethene (TCE) was detected above laboratory MDLs in samples IAS-2 (fitness center) and IAS-4, but below Non-Residential IASLs. Several other VOCs were detected at concentrations above laboratory MDLs, but below Non-Residential IASLs. 3.4 Vapor Intrusion Evaluation The DEQ DWM Vapor Intrusion IASLs used for comparison to the laboratory analytical results are conservative and based upon a target carcinogenic risk (TCR) of 1 x 10-6 and a non- carcinogenic hazard quotient (HQ) of 0.2. DEQ’s acceptable level for potential carcinogenic risks is a cumulative lifetime incremental cancer risk (LICR) of 1 x 10-4 or less and the acceptable level for non-carcinogenic risks is a cumulative hazard index (HI) of 1 or less. The HI is the sum of HQs for each detected target analyte. 8 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Cousins Properties (COU)/COU-001 - RailYard/VIMS Annual IA (May 2022)/Report/VIMS Annual Sampling Report.docx To further evaluate the potential risk associated with the compounds detected in the indoor air samples, H&H used DEQ’s Risk Calculator dated July 2022 to simulate a hypothetical “worst- case” non-residential use scenario. H&H input the highest concentration of each compound that was detected in the May 2022 indoor air samples into the DEQ Risk Calculator. Results of the hypothetical worst-case non-residential use scenario indicate a calculated cumulative LICR of 8.1 x 10-6 and a calculated cumulative HI of 1.5. The LICR is within the DEQ acceptable level of 1 x 10-4 for the cumulative LICR, however, the HI exceeds the DEQ acceptable level of 1.0 for the cumulative HI. The DEQ Risk Calculator output sheets are provided in Appendix E. The compound that primarily contributed to the HI exceedance is isopropanol, or rubbing alcohol. Isopropanol is found in numerous products and is a component of the sanitary wipes in the fitness center, in the hand sanitizer stations that were found throughout the South Tower, and in various cleaning products found in the STIR kitchen. Material safety data sheets (SDSs) for cleaners and chemicals found on Site at the time of the sampling event are included as Appendix F. While the isopropanol detection was likely attributable to indoor air sources from the products listed above, as a conservative measure due to the HI risk exceedance and due to the low-level TCE detections in two of the five samples, a supplemental sampling event was conducted in August 2022 per request of DEQ. The supplemental sampling activities and results are provided in the following sections. 9 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Cousins Properties (COU)/COU-001 - RailYard/VIMS Annual IA (May 2022)/Report/VIMS Annual Sampling Report.docx 4.0 Supplemental Sampling The supplemental sampling event consisted of collection of the indoor air samples and co-located sub-slab vapor samples to evaluate the potential for vapor intrusion or VOC off-gassing from building materials. The supplemental sampling activities and results are described in the following sections. Prior to the supplemental sampling, an indoor air building survey form (see Section 3.1) was completed and similar products were identified in the building as the May 2022 sampling event. 4.1 Sampling Methodology On August 11, 2022, H&H collected two indoor air samples, a background sample, and a duplicate sample. The indoor air samples were collected using the same procedure as previously described in Sections 3.1 and 3.2 from the two indoor air sample locations (IAS-2 and IAS-4) where TCE was detected in May 2022. During the August 2022 sampling event, sample IAS-2 was collected in the fitness center and IAS-4 was collection in the kitchen of the STIR restaurant space. A duplicate indoor air sample (IAS-DUP) was collected for QA/QC purposes from the IAS-2 parent location during the sampling event. Immediately after the indoor air samples were collected, on August 11, 2022, H&H collected two co-located sub-slab samples. The samples were collected from monitoring points OP-5 and OP-10, which were in the vicinity of the indoor air samples. Monitoring point OP-5 is located within the fitness center, and monitoring point OP-10 is located in the STIR kitchen. The sample locations are depicted on Figure 3. To collect the sub-slab soil gas samples, Teflon sample tubing was secured to a 2-inch expandable well cap with a sampling port that was secured onto the 2-inch diameter PVC monitoring point. The tubing was connected to an airflow regulator and laboratory-supplied batch-certified 1-liter stainless steel Summa canister. The air flow regulator was preset by the laboratory to collect a soil gas sample at a flow rate no greater than approximately 100 milliliters per minute. Prior to sample collection, H&H conducted a leak test at each monitoring point by placing a shroud around the monitoring point, expandable well cap, and sampling train including the Summa 10 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Cousins Properties (COU)/COU-001 - RailYard/VIMS Annual IA (May 2022)/Report/VIMS Annual Sampling Report.docx canister. The air within the shroud was flooded with helium gas and concentrations were measured with a calibrated helium detector. Helium concentrations within the shroud were maintained at approximately 12%. A GilAir vacuum pump was connected to the sample tubing outside of the shroud and used to purge a minimum of three volumes (monitoring point and sample train) of soil gas into a Tedlar® bag at each sampling point. The helium gas detector was used to measure helium concentrations within the Tedlar bag sample to confirm helium concentrations in the sample were less than 10% of that measured within the shroud. Results of the helium leak checks indicate that short-circuiting at the monitoring points or within the sampling train was not present. Soil gas sampling field forms completed by sampling personnel are included in Appendix C. Following successful leak checks, the air flow regulators were opened to allow collection of the sub-slab soil gas samples. Vacuum in the Summa canisters was monitored during the sampling event to confirm adequate sample volume was collected at each monitoring point location. Upon completion of sample collection, the air flow regulator was closed to the Summa canister. The canisters were labeled with the sample identification, beginning and ending times, pressure measurements, and the requested analysis. The canisters were then placed in laboratory supplied shipping containers and delivered to Eurofins under standard chain of custody protocols for analysis of select VOCs by EPA Method TO-15. The compound list included the same compounds as the select list for the indoor air samples (Table 1). 4.2 Sampling Results A tabular summary of the indoor air sampling results and sub-slab soil gas data from 2022 is summarized in Table 2. The indoor air and sub-slab soil gas analytical results were compared to the DEQ DWM Non-Residential IASLs and Sub-slab and Exterior Soil Gas Screening Levels (SGSLs), dated July 2022. Copies of the laboratory analytical reports and chain-of-custody records are provided in Appendix D. The indoor air results from August 2022 indicate that several compounds were detected above the laboratory MDLs, but below the Non-Residential IASLs. TCE was detected in each sample at low-level J-flag estimated concentrations ranging from 0.033 µg/m3 to 0.074 J µg/m3, which are all below the Non-Residential IASL. TCE was also detected in the background air sample, BAS- 11 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Cousins Properties (COU)/COU-001 - RailYard/VIMS Annual IA (May 2022)/Report/VIMS Annual Sampling Report.docx 8/11/2022, at a concentration of 0.38 µg/m3, which is a higher concentration than detected in the indoor air samples. Tetrachloroethene was also detected in all samples below the Non-Residential IASLs, including the background sample, ranging from 0.073 µg/m3 to 0.43 µg/m3. The only compound that exceeded its Non-Residential IASL was chloroform in sample IAS-4, located in the STIR Kitchen. Chloroform is commonly found in cleaning products that could be used in a kitchen. Additionally, chloroform was not detected in sub-slab soil gas sample OP-10, indicating that the detection is likely attributable to an above-slab source, such as a building material or product. Note, isopropanol, was detected at relatively low-levels in the August 2022 samples as compared to the May 2022 samples. The sub-slab soil gas sample analytical results indicate that several other compounds were detected at concentrations above MDLs in the samples, but all remained below the Non-Residential SGSLs. Trichloroethene was detected in sample OP-5 at a concentration of 3.4 µg/m3, which is well below the Non-Residential SGSL of 180 µg/m3. Tetrachloroethene was detected in both samples (OP-5 and OP-10) at concentrations of 160 µg/m3 and 2.0 µg/m3, respectively, which are well below the Non-Residential SGSL of 3,500 µg/m3. Risk Evaluation H&H utilized DEQ’s Risk Calculator (dated July 2022) set to simulate a hypothetical “worst-case” non-residential use scenario for both the indoor air data and the sub-slab soil gas data from August 2022 using the highest concentration of any compound detected. The DEQ Risk Calculator results for the indoor air data indicate a calculated cumulative LICR of 4.9 x 10-6 and a cumulative HI of 0.19. The sub-slab soil gas data indicated a cumulative LICR of 9.8 x 10-8 and a cumulative HI of 0.014. The sample results indicate that the supplemental indoor air and sub-slab soil gas risk calculator levels are well within the acceptable DEQ risk levels and thus the analytical data indicates there is not an unacceptable risk to the commercial occupants of the building. 12 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Cousins Properties (COU)/COU-001 - RailYard/VIMS Annual IA (May 2022)/Report/VIMS Annual Sampling Report.docx 5.0 Summary and Conclusions In May 2022, H&H performed the third post-occupancy annual indoor air sampling activities within the south tower of the Railyard commercial building located on the HD Supply Brownfields Property. The annual sampling activities included collection of five indoor air samples across the ground floor of the south tower. Laboratory analytical results indicated the presence of chloroform and isopropanol in select indoor air samples above DEQ DWM’s Non-Residential IASLs. Several VOCs, including PCE and TCE, were detected above laboratory MDLs in several of the samples, but the detections were below the Non-Residential IASLs. Results from the DEQ Risk Calculator hypothetical worst-case non- residential use scenario indicate a calculated cumulative LICR of 8.1 x 10-6 and a cumulative HI of 1.5, exceeding the DEQ acceptable level of 1 for the cumulative HI. The compound largely responsible for the HI exceedance was isopropanol, which could be the result of off-gassing from multiple hand sanitizer stations located around the communal spaces on the first floor of the building in addition to the cleaning products found in the STIR Kitchen. Based on the results of the annual indoor air sampling activities, DEQ requested supplemental indoor air and sub-slab soil gas sampling in select areas. Two indoor air samples were collected (IAS-2 and IAS-4), along with a duplicate sample and background sample in August 2022. In addition, two sub-slab samples (OP-5 and OP-10) were collected concurrently with the indoor air samples. The results of the supplemental sampling activities indicate that acceptable risk levels are present for non-residential use of the Site building. The DEQ Risk Calculator results of the hypothetical worst-case non-residential use scenario indicate a calculated cumulative LICR of 4.9 x 10-6 and a cumulative HI of 0.19 for the indoor air data, and a cumulative LICR of 9.8 x 10-8 and a cumulative HI of 0.014 for the sub-slab soil gas data. Both sets of results are within the DEQ acceptable risk levels. As stated in the DEQ-approved VIMP, a minimum of three annual indoor air sampling events were to be completed, with the third event occurring in May 2022. While the risk levels are acceptable, due to the presence of the remaining vacant space within the south tower and out of caution due to 13 https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Cousins Properties (COU)/COU-001 - RailYard/VIMS Annual IA (May 2022)/Report/VIMS Annual Sampling Report.docx the low-level presence of PCE and TCE in indoor air, H&H recommends performing another Following the 2023 sampling event, H&H will prepare a VIMS Evaluation Report to provide recommendations for termination of future sampling or continued sampling and monitoring of the VIMS for DEQ review and approval. Table 1 Site-Specific Indoor Air VOC List South TowerHD Supply Site 1414 S. Tryon Street Charlotte, North Carolina H&H Job No. COU-001 Select VOCs by TO-15 Acetone Benzene 1,3-Butadiene 2-Butanone Carbon Disulfide Carbon Tetrachloride Chloroethane Chloroform Chloromethane Cyclohexane 1,3-Dichlorobenzene Dichlorodifluoromethane 1,2-Dichloropropane Ethanol Ethyl Acetate Ethylbenzene 4-Ethyltoluene Heptane Hexane Isopropanol Methylene Chloride 4-Methyl-2-pentanone Naphthalene Propene Styrene Tetrachloroethene Toluene Trichloroethene Trichlorofluoromethane 1,1,2-Trichloro-1,2,2-trifluoroethane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl Chloride m&p-Xylene o-Xylene S:\AAA-Master Projects\Cousins Properties (COU)\COU-001 - RailYard\VIMS Annual IA (May 2022) 7/15/2022 Table 1 (Page 1 of 1) Hart & Hickman, PC Table 2Summary of Analytical Data HD Supply SiteCharlotte, North Carolina Brownfields Project No. 19054-15-060 H&H Job No. Project COU-001Sampling EventSample TypeAmbient Air Ambient AirSample IDIAS-2 IAS-3 IAS-4 IAS-5 BAS-1 IAS-4 BAS-8/11/22 OP-5 OP-10DateLocationFitness CenterCorridor Outside Vacant Tenant Space (Unit 160A)STIR Kitchen STIR Dining Background STIR Kitchen Background Fitness Center STIR KitchenVOCs TO-15 (µg/m3)Acetone31.531.619.735.721.218.516.94035150 E145316 JNENEBenzene0.297 J 0.275 J<0.07330.284 J1.46 J0.339 J0.294 J0.260.231.40.35<1.2<1.21.61601,3-Butadiene<0.328<0.328<0.328<0.328<0.328<0.328<0.3280.043 J<0.0300.27 J0.046 J<1.9<1.80.4141Carbon Disulfide0.657 B, J 0.713 B, J 0.529 B, J<0.0608 <0.06080.754 B, J 0.641 B, J<0.63<0.621.8 J<0.65<4.7<4.661061,000Carbon Tetrachloride<0.155<0.155<0.155<0.155<0.155<0.155<0.1550.440.380.450.44<1.3<1.32.0200Chloroethane<0.164<0.164<0.164<0.164<0.164<0.164<0.1640.016 J<0.00980.023 J<0.010<3.8<3.73,500350,000Chloroform<0.864 <0.0864 <0.08640.630 J3.341.49 J<0.08640.250.221.4 0.12 J2.8 J<1.90.5353Chloromethane<0.06730.731 J0.696 J<0.06730.752 J0.708 J<0.06730.95 J0.83 J1.0 J0.95 J<4.7<4.6797,900Cyclohexane<0.161<0.161<0.161<0.161<0.161<0.161<0.161<0.24<0.23<0.23<0.242.4 J<0.625,300530,000Dichlorodifluoromethane2.652.672.662.652.46 J2.692.782.2 J1.9 J2.2 J2.3 J2.7 J2.9 J888,800Ethanol1,0301,0501776153,0203,19025.7160 E140 E1,200 E19NANANENEEthyl Acetate2.492.551.16 J2.086.244.50<0.136<0.32<0.316.7 <0.32<8.7<8.7616,100Ethylbenzene<0.106<0.106<0.106<0.106<0.106<0.106<0.1060.150.140.210.14<1.2<1.24.94901,1,2-Trichloro-1,2,2-trifluoroethane<0.561<0.561<0.561<0.561<0.561<0.5610.621 J0.43 J0.39 J0.49 J0.52 J<1.8<1.84,400440,000Heptane0.471 J0.488 J<0.1430.512 J0.455 J0.369 J0.484 J<0.36<0.350.48 J<0.36<1.8<1.835035,000Hexane0.529 J<0.04720.352 J<0.0472 <0.0472 <0.04720.560 J3.2 2.9 17 0.78 J<1.0<1.0616,100Isopropanol16116250.4997218 J46.73.47 J68 60 17 2.3 J7.7 J41 18018,000Methyl Ethyl Ketone (MEK)2.172.391.753.522.101.681.611.6 J1.6 J2.8 1.4 J33 <3.94,400440,0004-Methyl-2-Pentanone (MIBK)0.901 J0.819 J<0.121<0.121<0.121<0.121<0.1210.25 J<0.200.80 <0.21<1.3<1.22,600260,000Methylene Chloride1.13 J1.15 J0.809 J<0.4890.983 J0.761 J0.785 J<0.56<0.550.67 J0.91 J<5.5<5.453053,000Naphthalene<0.183<0.183<0.183<0.183<0.183<0.183<0.183<0.11<0.110.16 J<0.11<1.4<1.40.3636Propylene<0.242<0.2420.738 J<0.242<0.242<0.242<0.242<0.30<0.305.4 <0.31<1.7<1.72,600260,000Styrene0.439 J0.396 J<0.124<0.124<0.124<0.124<0.1240.24 J0.24 J0.41 J<0.090<1.5<1.588088,000Tetrachloroethylene0.787 B, J 0.719 B, J34.90.563 B, J19.81.67 B, J 1.35 B, J0.11 J0.24 0.43 0.073 J160 20 353,500TetrahydrofuranNANANANANANANANANANANA3302.7 J1,800180,000Toluene5.325.041.53 J1.891.43 J1.44 J1.11 J3.8 3.3 16 1.5 0.86 J0.72 J4,400440,000Trichloroethylene<0.199<0.1990.634 J<0.1990.484 J<0.199<0.1990.058 J0.074 J0.033 J0.38 3.4 J<2.41.8180Trichlorofluoromethane<0.1301.48 J1.67 J<0.130<0.1301.66 J1.82 J1.3 1.1 1.3 1.2 5.0 J2.0 JNENE1,2,4-Trimethylbenzene<0.110<0.110<0.110<0.110<0.110<0.110<0.110<0.21<0.200.46 J0.34 J<2.2<2.2535,300Vinyl Chloride<0.127<0.127<0.127<0.127<0.127<0.127<0.127<0.010 <0.0099 <0.00970.031 J<1.9<1.92.8280o-Xylene0.473 J0.460 J<0.1570.473 J0.404 J<0.157<0.1570.190.180.280.17<1.4<1.4888,800m&p-Xylene0.934 J0.977 J0.664 J1.01 J0.886 J0.695 J0.469 J0.470.500.620.43<1.3<1.3888,800DEQ Cumulative Risk Calculator(3)Carcinogenic Risk (LICR)Non-Carcinogenic Hazard Index (HI)Notes:1) NC Department of Environmental Quality (DEQ) Division of Waste Management (DWM) Indoor Air Screening Levels (IASLs) dated July 2022 and based upon TCR = 1 x 10-6 and THQ = 0.2.2) NC Department of Environmental Quality (DEQ) Division of Waste Management (DWM) Vapor Intrusion Sub-slab and Exterior Soil Gas Screening Levels (SGSLs) dated July 2022 and based upon TCR = 1 x 10-6 and THQ = 0.2.3) NC DEQ DWM Cumulative Risk Calculator dated July 2022.Compound concentrations are reported in micrograms per cubic meter (μg/m3)Compound concentrations are reported to the laboratory method detection limits.Only those compounds detected in at least one sample, and select chlorinated solvents, are shown in the table above.Samples were collected into individually-certified 6-L Summa canisters and analyzed by EPA Method TO-15.Bold indicates compound concentration exceeds Non-Residential IASLs.VOCs = Volatile Organic Compounds; NE = Not Established; NA = Not AnalyzedB = analyte detected in blank; E = Exceeds instrument calibration rangeJ = Compound was detected above the laboratory method detection limit, but below the laboratory reporting limitresulting in a laboratory estimated concentration.TCR = Target Cancer Risk; THQ = Target Hazard Quotient.LICR = Lifetime Incremental Cancer Risk; HI = Hazard Index.Cumulative LICR and HI calculated using the non-residential worst-case scenario for each building and compared to DEQ and EPA acceptable risk levels for carcinogenic and non carcinogenic risks.Annual Indoor Air Sampling EventIAS-1 / IAS-DUPIndoor Air8.1 x 10-61.54.9 x 10-60.198/11/2022Non-Residential Worst CaseIAS-2 / IAS-DUPIndoor AirSupplemental Sampling EventFitness Center<1.0Sub-Slab VaporAcceptable Risk LevelsNon-Residential SGSLs (2)Non-Residential IASLs (1)8/11/20229.8 x 10-8<1 x 10-40.0145/20/2022Office Spacehttps://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Cousins Properties (COU)/COU-001 - RailYard/VIMS Annual IA (May 2022)/Tables/Table 1 - Analytical Data Table10/17/2022Table 2 (Page 1 of 1) Hart & Hickman, PC SITE LOCATION MAP HD SUPPLY 1414 & 1422 SOUTH TRYON STREET CHARLOTTE, NORTH CAROLINA DATE: JOB NO: REVISION NO: FIGURE NO: 6/22/2022 0 1COU-001 0 2000 4000 APPROXIMATE SCALE IN FEET N U.S.G.S. QUADRANGLE MAP 7.5 MINUTE SERIES (TOPOGRAPHIC) 2923 S. Tryon Street, Suite 100Charlotte, NC 28203704.586.0007(p) 704.586.0373(f) CHARLOTTE EAST, NORTH CAROLINA 1991 SITE REVISION NO. 0 JOB NO. COU-001 DATE: 6/22/2022 FIGURE NO. 2 HD SUPPLY BROWNFIELDS SITE RAILYARD - SOUTH TOWER 1414 S. TRYON STREEET CHARLOTTE, NORTH CAROLINA SITE MAP LEGEND SITE PROPERTY BOUNDARY RAILROAD TRACKS RAILYARD - SOUTH TOWER 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 GeologySOUTH TRY O N ST R E ET WIN NIFRE D STREET W E S T B L A N D S T R E E T WIN O N A S T R E E T WE S T S U M M I T A V E N U ESOUTH CHURCH STREETRAILYARD APARTMENTS (CENTRO RAILYARD. LLC) NORTHERN OFFICE TOWER (RAILYARD. LLC) THE RAILYARD (RAILYARD. LLC) SOUTHERN OFFICE TOWER (RAILYARD. LLC) NOTE: 1. AERIAL IMAGERY OBTAINED FROM MECKLENBURG COUNTY GIS, 2019. PARKING DECK (RAILYARD, LLC)S:\AAA-Master Projects\Beacon Partners- BEP or BCP\BCP-064 1414 and 1422 S. Tryon\Brownfields\VIMS Installation Reports\1st Floor - Bishops & Stir - Oct 2020\Figures\Site Plan.dwg, 11/3/2020 12:06:37 PM, DWG To PDF.pc3 EXPANSION JOINT BETWEEN CONNECTOR AND SOUTH TOWERRETAIL SOUTH120GRAND CENTRALSTATION100SOUTH CABOOSEP107SOUTH STOPP109STAIR 3109SERVICEP110FIRE PUMPP106MAIL107U B E R / L Y F T D R O P - O F F RETAIL SOUTH130STAIR 4116CORRIDOR111SOUTH TRASHHANGER112WATER PUMPP108SOUTH JUNCTION108FITNESS115MENS LOCKER113WOMENS LOCKER114RETAIL SOUTH140RETAIL SOUTH150RETAIL SOUTH160RETAIL SOUTH170CONTROL107AELEV NO. 5ELEV NO. 6ELEV NO. 4CORRIDOR118BICYCLE100ACOLUMN FOOTER (TYP)F-1F-3F-4F-5F-6F-7SECURITY107A F-2OP-2OP-1OP-3OP-4OP-5OP-6OP-7OP-8OP-9OP-10OP-11BISHOPSHAIRCUTSSTIR(RESTAURANT)BEEM LIGHTSAUNALOBBY /AMENITYSPACERETAIL SOUTH160ASUMMERBIRD (RESTAURANT)REVISION NO. 0JOB NO. COU-001DATE: 10-17-22FIGURE NO. 3HD SUPPLY BROWNFIELDS SITESOUTH TOWER1414 S. TRYON ST.CHARLOTTE, NORTH CAROLINA SAMPLE LOCATION MAP2923 South Tryon Street-Suite 100Charlotte, North Carolina 28203704-586-0007(p) 704-586-0373(f)License # C-1269 / #C-245 GeologyLEGENDSLOTTED 3" DIA SCHEDULE 40 PVC PIPINGSOLID 3" DIA SCHEDULE 40 PVC PIPINGEXTENT OF VAPOR LINERCOMMERCIAL TENANT SPACE RETAIL AREALOCATION OF VERTICAL RISER AND APPROXIMATE LOCATION OF TURBINE FAN ON ROOFTOPLOCATION OF OBSERVATION POINTINDOOR AIR SAMPLE LOCATIONBACKGROUND AIR SAMPLE LOCATIONAREA OF UNFINISHED SLABBAS-1NOTES:1.LAYOUT OF GROUND FLOOR SHOWN FOR THE SOUTH TOWER ONLY.2.THE SOUTH TOWER 'AREA OF UNFINISHED SLAB" WILL BE UPFITTED AT A FUTURE DATE.3. ANNUAL INDOOR AIR SAMPLES LISTED BELOW WERE COLLECTED ON MAY 20, 2022.a.IAS-1, IAS-2, IAS-3, IAS-4, IAS-5 WITH DUPLICATE SAMPLE COLLECTED FROM PARENT SAMPLE IAS-1 LOCATION.4. SUPPLEMENTAL INDOOR AIR AND SUB-SLAB SOIL GAS SAMPLES LISTED BELOW WERE COLLECTED ON AUGUST 11, 2022.a.INDOOR AIR SAMPLE LOCATIONS: IAS-2 AND IAS-4 WITH DUPLICATE SAMPLED COLLECTED FROM PARENT SAMPLE IAS-2 LOCATION.b.SUB-SLAB SOIL GAS SAMPLE LOCATIONS: OP-5 AND OP-10 IAS-3IAS-4IAS-5IAS-2IAS-1S:\AAA-Master Projects\Cousins Properties (COU)\COU-001 - RailYard\VIMS Annual IA (May 2022)\Figures\CAD\Figure 3.dwg, Figure 3, 6/22/2022 11:33:47 AM, SVincent BAS-8/11/22 Appendix A Previous Annual Indoor Air Analytical Data Table 3 Summary of Indoor Air Analytical Results Bishop and STIR Tenant Spaces HD Supply 1414 South Tryon Street Charlotte, North Carolina H&H Job No. BCP-064 Background Indoor Air Background Sample ID BAS-1 IAS-1 BKG-1 Sample Date 11/4/2019 6/22/2020 6/22/2020 Location Northeast of South Tower Western Portion of Space North of South Tower Acetone 8.2 10.8 5.8 49.6 41.9 40.9 10.4 27,000 Benzene <0.23 0.57 0.36 J <0.20 0.29 J <0.20 <0.21 1.6 1,3-Butadiene <0.19 <0.20 <0.19 <0.16 <0.16 <0.16 <0.16 0.41 2-Butanone (MEK)2.5 J 2.5 J <0.56 8.7 9.0 7.4 2.9 J 4,400 Carbon disulfide <0.33 <0.34 <0.33 <0.16 <0.16 <0.16 <0.17 610 Carbon tetrachloride <0.64 <0.66 <0.65 <0.39 <0.39 <0.39 <0.40 2.0 Chloroethane <0.39 <0.40 <0.40 <0.19 <0.19 <0.19 <0.20 8,800 Chloroform <0.29 <0.30 <0.30 <0.20 <0.20 <0.20 <0.21 0.53 Chloromethane 0.46 J 0.61 J 0.55 J 1.2 1.4 1.1 1.0 79 Cyclohexane <0.53 <0.55 <0.54 10.5 15.4 14.9 <0.23 5,300 1,3-Dichlorobenzene <0.87 <0.90 <0.88 <0.73 <0.73 <0.73 <0.75 NE Dichlorodifluoromethane 2.0 2.0 2.4 2.5 2.7 2.8 2.6 88 1,2-Dichloropropane <0.34 <0.36 <0.35 <0.30 <0.30 <0.30 <0.32 3.3 Ethanol 16.5 17.4 12.0 94.6 92.3 107 15.9 NE Ethyl acetate 1.4 1.5 <0.29 <0.28 <0.28 <0.28 <0.29 61 Ethylbenzene 7.4 7.4 <0.46 3.7 3.9 3.8 2.3 4.9 4-Ethyltoluene <0.85 <0.88 <0.87 <0.65 <0.65 <0.65 <0.68 NE Heptane <0.57 <0.59 <0.58 3.9 5.3 4.5 0.49 J 350 Hexane 1.2 1.3 0.80 J 134 103 96.6 1.1 J 610 Methylene Chloride 3.6 J 4.5 J 4.4 J 3.2 J 1.8 J <1.4 2.6 J 530 4-Methyl-2-pentanone (MIBK)<0.77 <0.80 <0.79 0.70 J 0.56 J 0.78 J <0.28 2,600 Naphthalene <2.0 <2.0 <2.0 <1.9 <1.9 <1.9 <2.0 0.36 2-Propanol 470 506 <1.1 12.8 8.9 9.6 0.84 J 180 Propylene <0.21 <0.22 <0.21 <0.15 <0.15 <0.15 <0.15 2,600 Styrene <0.51 <0.53 <0.52 3.6 3.0 3.3 <0.68 880 Tetrachloroethylene <0.47 1.3 <0.48 0.64 J 0.81 J 0.77 J <0.42 35 Toluene 1.4 1.5 0.69 J 15.3 13.9 15.3 1.3 4,400 Trichloroethene <0.38 <0.39 <0.38 <0.34 <0.34 <0.34 <0.35 1.8 Trichlorofluoromethane 0.95 J 0.98 J 1.1 J 1.4 J 1.3 J 1.4 J 1.5 J NE 1,1,2-Trichloro-1,2,2-trifluoroethane <0.84 <0.87 <0.86 0.48 J 0.46 J 0.43 J 0.43 J 4,400 1,2,4-Trimethylbenzene 1.9 1.9 <0.69 1.3 J 1.2 J 1.2 J <0.49 53 1,3,5-Trimethylbenzene <0.59 <0.62 <0.61 0.82 J <0.38 <0.38 <0.39 53 Vinyl chloride <0.19 <0.20 <0.19 <0.15 <0.15 <0.15 <0.15 2.8 m&p-Xylene 46.5 47.6 <1.1 14.6 14.2 14.3 11.8 88 o-Xylene 18.8 19.2 <0.52 4.4 4.5 4.7 4.1 88 Notes: 1. Division of Waste Management (DWM) Non-Residential Indoor Air Screening Levels (IASLs) based on Target Cancer Risk (TCR) = 1.0E-06 and Target Hazard Quotient (THQ) = 0.2 (February 2018) Constituents included a select list of compounds. Refer to Table 2. Bold indicates concentration abve the Non-Residential IASL µg/m3 = micrograms per cubic meter NE = Not Established Samples were collected into individually-certified 6-L Summa canisters and analyzed by EPA Method TO-15 VOCs = Volatile Organic Compounds Sample Type Non-Residential IASL1 (µg/m3) Bishops Tenant Space STIR Tenant Space Indoor Air Indoor Air IAS-2/DUP-1 6/22/2020 Eastern Portion of Space IAS-1/DUP-1 11/4/2019 First Floor VOCs TO-15 (µg/m3) S:\AAA-Master Projects\Beacon Partners- BEP or BCP\BCP-064 1414 and 1422 S. Tryon\Brownfields\VIMS Installation Reports\1st Floor - Bishops & Stir - Oct 2020\Tables\Table 3 - Analytical Data.xlsx 11/4/2020 Table 3 (Page 1 of 1) Hart & Hickman, PC Table 1 Summary of Indoor Air Analytical Results South Tower HD Supply Site 1414 South Tryon Street Charlotte, North Carolina H&H Job No. BCP-064 Sample ID IAS-2 IAS-3 BAS-1 IAS-5 BAS-2 Sample Date Location Fitness Center Bishops Haircuts Background STIR Dining Background VOCs TO-15 (µg/m3) Acetone 16.4 18.1 13.3 10.2 9.21 31.1 22.0 20.6 13.7 27,000 Benzene 0.811 J 0.792 J 0.856 J 1.11 J <0.160 1.34 J 1.32 J <0.160 <0.160 1.6 1,3-Butadiene <0.195 <0.195 <0.195 <0.195 <0.195 <0.195 <0.195 <0.195 <0.195 0.41 2-Butanone (MEK)2.44 2.49 2.23 2.15 1.68 <0.295 <0.295 <0.295 <0.295 4,400 Carbon disulfide <1.56 <1.56 <1.56 <1.56 <1.56 <1.56 <1.56 <1.56 <1.56 610 Carbon tetrachloride <0.239 <0.239 <0.239 <0.239 <0.239 <0.239 <0.239 <0.239 <0.239 2.0 Chloroethane <0.396 <0.396 <0.396 <0.396 <0.396 <0.396 <0.396 <0.396 <0.396 8,800 Chloroform <0.264 <0.264 <0.264 <0.264 <0.264 1.65 J 1.64 J <0.264 <0.264 0.53 Chloromethane 0.820 J 0.830 J <0.268 0.795 J <0.268 <0.268 <0.268 <0.268 <0.268 79 Cyclohexane <0.861 <0.861 <0.861 <0.861 <0.861 <0.861 <0.861 <0.861 <0.861 5,300 1,3-Dichlorobenzene <0.216 <0.216 <0.216 <0.216 <0.216 <0.217 <0.217 <0.217 <0.217 NE Dichlorodifluoromethane 2.69 2.58 2.67 2.57 2.71 <0.410 <0.410 <0.410 <0.410 88 1,2-Dichloropropane <0.402 <0.402 <0.402 <0.402 <0.402 <0.402 <0.402 <0.402 <0.402 3.3 Ethanol NA NA NA NA NA 2,100 1,620 1,440 47.1 NE Ethyl acetate 1.62 J 1.63 J <0.249 3.24 <0.249 1.70 J 1.94 <0.249 <0.249 61 Ethylbenzene <0.187 <0.187 <0.187 <0.187 <0.187 <0.187 <0.187 <0.187 <0.187 4.9 4-Ethyltoluene <0.266 <0.266 <0.266 <0.266 <0.266 <0.266 <0.266 <0.266 <0.266 NE Heptane 0.893 J 0.865 J <0.193 <0.193 <0.193 <0.193 <0.193 <0.193 <0.193 350 Hexane 0.733 J 0.772 J 0.825 J 0.888 J <0.254 <0.254 <0.254 <0.254 <0.254 610 Methylene Chloride <0.382 0.698 J 0.983 J <0.382 <0.382 <0.383 <0.383 <0.383 <0.383 530 4-Methyl-2-pentanone (MIBK)<0.254 <0.254 <0.254 <0.254 <0.254 <0.254 <0.254 <0.254 <0.254 2,600 Naphthalene <0.386 <0.386 <0.386 5.54 <0.386 <0.386 <0.386 <0.386 <0.386 0.36 2-Propanol 301 302 36.6 45.7 1.12 J 5.70 5.52 4.08 J 1.49 J 180 Propylene <0.139 <0.139 <0.139 <0.139 <0.139 <0.139 <0.139 <0.139 <0.139 2,600 Styrene <0.149 <0.149 <0.149 <0.149 <0.149 <0.149 <0.149 <0.149 <0.149 880 Tetrachloroethene <0.441 <0.441 <0.441 <0.441 <0.441 <0.441 <0.441 <0.441 <0.441 35 Tetrahydrofuran 0.628 J <0.209 1.31 J 0.678 J <0.209 NA NA NA NA 1,800 Toluene 1.93 1.94 2.08 2.46 1.27 J 1.86 J 1.78 J 1.53 J 1.40 J 4,400 Trichloroethene <0.274 <0.274 <0.274 <0.274 <0.274 <0.274 <0.274 <0.274 <0.274 1.8 Trichlorofluoromethane <0.433 <0.433 <0.433 1.37 J 1.41 J <0.433 <0.433 <0.433 <0.433 NE 1,1,2-Trichloro-1,2,2-trifluoroethane <0.529 <0.529 <0.529 <0.529 <0.529 <0.529 <0.529 <0.529 <0.529 4,400 1,2,4-Trimethylbenzene <0.295 <0.295 <0.295 <0.295 <0.295 <0.295 <0.295 <0.295 <0.295 53 1,3,5-Trimethylbenzene <0.261 <0.261 <0.261 <0.261 <0.261 <0.261 <0.261 <0.261 <0.261 53 Vinyl chloride <0.281 <0.281 <0.281 <0.281 <0.281 <0.282 <0.282 <0.282 <0.282 2.8 m&p-Xylene 1.58 J 1.66 J 1.39 J 2.22 J 0.903 J 1.36 J 1.29 J 1.57 J 0.877 J 88 o-Xylene <0.182 <0.182 <0.182 <0.182 <0.182 <0.182 <0.182 <0.182 <0.182 88 Acceptable Risk Levels LICR (Non-residential)<1.0E-4 Non-Carcinogenic HI (Non-residential) <1.0 Notes: 2) NC DEQ DWM Cumulative Risk Calculator dated January 2021. Only compounds included in the select list of compounds or detected in at least one sample are included. Compound concentrations are reported in micrograms per cubic meter (μg/m3). Compound concentrations are reported to the laboratory method detection limits. Samples were collected into individually-certified 6-L Summa canisters and analyzed by EPA Method TO-15 Bold indicates concentration exceeds Non-Residential IASLs. VOCs = Volatile Organic Compounds; NE = Not Established; NA = Not Analyzed TCR = Target Cancer Risk; THQ = Target Hazard Quotient; LICR = Lifetime Incremental Carcinogenic Risk; HI = Hazard Index. Ethanol is not included in the standard TO-15 list used by Waypoint Analytical. Tetrahydrofuran is not included in the select list and was not reported for samples IAS-4, IAS-Dup-032321, IAS-5, and BAS-2. Cumulative LICR and HI calculated using the worst-case scenario and compared to DEQ and EPA acceptable risk levels for carcinogenic and non carcinogenic risks. J = Compound was detected above the laboratory method detection limit, but below the laboratory reporting limit resulting in a laboratory estimated concentration. 1) NC Department of Environmental Quality (DEQ) Division of Waste Management (DWM) Indoor Air Screening Levels (IASLs) dated January 2021 and based upon TCR = 1 x 10-6 and THQ = 0.2. Vacant Retail / Common Area Non-Residential IASLs(1) (µg/m3)2/25/2021 3/23/2021 STIR Kitchen 1.9E-5 0.81 DEQ Worst Case Risk Calculations(2) IAS-1 / IAS-DUP IAS-4 / IAS-Dup-032321 M:\AAA-Master Projects\Beacon Partners- BEP or BCP\BCP-064 1414 and 1422 S. Tryon\Brownfields\VIMS Installation Reports\VIMS Post-Occupancy Sampling (February & March 2021)\Tables\Table 1 - Summary of Indoor Air Analytical Results.xlsx 4/20/2021 Table 1 (Page 1 of 1) Hart & Hickman, PC Appendix B VIMS As-Built Drawings (VM-1) EXPANSION JOINT BETWEEN CONNECTOR AND SOUTH TOWERRETAIL SOUTH120SOUTH CABOOSEP107SOUTH STOPP109STAIR 3109SERVICEP110MAIL107RETAIL SOUTH130STAIR 4116CORRIDOR111SOUTH TRASHHANGER112WATER PUMPP108SOUTH JUNCTION108FITNESS115MENS LOCKER113WOMENS LOCKER114RETAIL SOUTH140RETAIL SOUTH150RETAIL SOUTH160RETAIL SOUTH170CONTROL107AELEV NO. 5ELEV NO. 6ELEV NO. 4CORRIDOR1182VM13" VENT PIPE PROTECTIONSCREEN (TYPICAL AT ENDSOF SLOTTED PIPE)3"x3"x3" PVC TEE3VM12" VENT PIPE PROTECTIONSCREEN (TYPICAL AT ENDSOF OBSERVATION POINTS)1VM1NO VAPOR LINER UNDERSTRUCTURED PARKING DECKVAPOR LINER SEALED TOTURNED DOWN SLAB ATEXPANSION JOINT1VM12VM1COLUMN FOOTER (TYP)4VM14/6VM15VM15VM15VM15VM15VM17VM17VM19VM14/6VM13"x3"x3" SCH 40 PVCTEE (TYPICAL)EDGE OF OPEN AIRSTRUCTURED PARKING DECKF-1F-3F-4F-5F-6F-74/6VM14/6VM11VM1VM185VM15VM15VM1SEAL VAPOR LINER TO TURNEDDOWN SLAB OR FOOTINGVAPOR LINER SEALED TOTURNED DOWN SLAB10VM19VM19VM19VM110VM1OPEN AIR PARKING DECK5VM13"x3" SCH 40 PVC 90DEGREE ELBOWCREATE TURNED-DOWN SLABTO TERMINATE VAPOR LINER TRACER WIRE ALONG ALLSUB-SLAB HORIZONTALPIPE (TYP)TRACER WIRE ALONG ALLSUB-SLAB HORIZONTAL PIPESECURITY107A VAPOR LINER SEALED TOPARKING DECK WALL /TURNED DOWN SLAB5VM1STAIRWELL WITHIN PARKING GARAGE(STAIR 3) CONTAINS DEDICATED HVACSYSTEM THAT DOES NOT EXCHANGEAREA WITH OCCUPIED SPACESVAPOR LINER SEALEDTO PARKING DECK WALL3" PVC 45 DEGREE WYE3" PVC 45 DEGREE WYE3" PVC 45 DEGREE WYE3" SOLID TO 3" SLOTTED PIPECONNECTIONS4" SOLID SCH 40 PVC3" SLOTTED PVC3" PVC 45 DEGREEWYEF-23" SCH 40 PVC ELBOW(TYPICAL)5VM1OP-2OP-1OP-3OP-4OP-5OP-6OP-7OP-8OP-9OP-10OP-11APPROXIMATELY 5,800 SQ FTCOMMERCIAL SPACEBISHOPSHAIRCUTSSTIR(RESTAURANT)VACANTSUMMERBIRD(RESTAURANT)LOBBY /AMENITYSPACETHICKENED SLABBELOW CMU WALLVMS VAPOR LINER AND BASE COURSE (TYP)1VMS SLOTTED COLLECTION PIPE (TYP)2BASE COARSE - CLEAN #57 OR #6 STONE,MIN 5" THICK BENEATH VMS VAPOR LINERVAPOR LINER (SEE SPECIFICATION #1)3" SCH 40 THREADED FLUSH JOINT SLOTTED PVC PIPE(0.020" SLOT WIDTH, 1/8" SLOT SPACING) WITH FILTERSOCK SET WITHIN MIN 5" BASE COURSE. INSTALL BASECOURSE APPROX. 1-INCH ABOVE AND BELOW THECOLLECTION PIPE.VAPOR LINER (SEE SPECIFICATION #1)CONCRETE FLOOR SLABSUB-BASESUBBASENTSNTSVM1VM1VMS TURBINE VENTILATOR FAN & EXHAUST (TYPICAL)6VM1NTSTURBINE FAN(EMPIRE MODEL TV04G)ELECTRICAL JUNCTION BOX FOR POTENTIALFUTURE VACUUM FAN3" CAST-IRON DUCT PIPE THROUGH ROOFFLASHINGROOFTOPVAPOR LINER PENETRATION SEALEDTO PIPE PER MANUFACTURERINSTRUCTIONS3" SOLID TO 3" SLOTTED SCH 40PVC PIPE TRANSITION (SLIPCOUPLING OR THREADED JOINT)MASONRY WALLVAPOR LINERBENEATH THICKENED SLABTOP OF THICKENEDSLAB TURNDOWNBASE COARSE(SEE SPECIFICATION #1)VMS PIPING AT THICKENED SLAB3VM1NTSFLOOR CLEANOUT, ADJUSTABLE,2" DIA ZURN INDUSTRIESMODEL #CO2450-PV2 (OR EQUIVALENT)WITH VANDAL PROOF SCREWSVAPOR LINER PENETRATIONSEALED TO PIPE PERMANUFACTURER INSTRUCTIONS2" PVC 90 DEGREE ELBOW2" VENT PIPEPROTECTION SCREENBASE COARSE(SEE SPECIFICATION #1)VMS OBSERVATION POINT (2")5NTSVM1VMS AT VERTICAL SLAB PENETRATION WITH 90 DEGREE ELBOWNTS3" SCH 40 PVC 90 DEGREE ELBOWSTUD WALL/DEADSPACE/COLUMN3" SERVICE WEIGHT CAST IRON RISER DUCT PIPE(SEE SPECIFICATION #2 AND #4)BASE COARSE(SEE SPECIFICATION #1)SOLID TO SLOTTED 3" SCH 40PVC PIPE TRANSITION (SLIPCOUPLING OR THREADED JOINT)3" SCH 40 PVC (LENGTHVARIES, REFER TO DRAWING)4VM1TENANT WALL(NOT PRESENT IN ALL LOCATIONS)SOLID 2" SCH 40 PVCTYPICAL VMS PIPING ABOVE COLUMN FOOTING DETAIL7NTSVM1TYPICAL VMS LINER AT ELEVATOR PIT8NTSVM1CONCRETE MUD SLABBASE COARSE(SEE SPECIFICATION #1)VAPOR LINER SEALED TO CONCRETEON OUTSIDE OF COLUMN PERMANUFACTURER INSTRUCTIONS3" SCH 40 PVCVMS PIPINGVAPOR LINER SEALED PERMANUFACTURER INSTRUCTIONSVAPOR LINER TERMINATION AT TURNED DOWN SLAB9NTSVM1BASE COARSE(SEE SPECIFICATION #1)VAPOR LINER SEALED TOCONCRETE PER MANUFACTURERINSTRUCTIONSSUB-BASE(CREATE SEPARATION OF GRAVELBASE AT TURNED DOWN SLAB)EXPANSION JOINT BETWEENSOUTH TOWER ANDCONNECTOR BUILDINGSOLID 3" SCH 40 PVCPLACE TRACER WIRE ALONGHORIZONTAL PIPE IN RETAILSOUTH AREASPOLYGUARD 650 MEMBRANEWATERPROOFING INSTALLED PERMANUFACTURER INSTRUCTIONSAPPROXIMATE 4' THICKCONCRETE FOOTERVAPOR LINER SEALED PERMANUFACTURER INSTRUCTIONSPOLYGUARD 650 MEMBRANEWATERPROOFING INSTALLED PERMANUFACTURER INSTRUCTIONSELEVATOR SUMPVAPOR LINER TERMINATION AT FOOTING10NTSVM1BASE COARSE(SEE SPECIFICATION #1)EXTERNAL WALLTOP OF FOOTINGVAPOR LINER SEALED TOCONCRETE PER MANUFACTURERINSTRUCTIONSUPSTAIR 4116STAIR 1101HD SUPPLY BROWNFIELDS SITE 1414 S. TRYON STREET CHARLOTTE, NORTH CAROLINA THE RAILYARD - SOUTH TOWER VAPOR MITIGATION PLAN PREPARED BY2923 South Tryon Street-Suite 100Charlotte, North Carolina 28203704-586-0007(p) 704-586-0373(f)License # C-1269 / #C-245 GeologyH&H NO. BCP-064VAPOR MITIGATIONSYSTEM PLANNOVEMBER 3, 2020VM-1VAPOR MITIGATION SYSTEM LAYOUT - SOUTH TOWER1" = 10'LEGENDSLOTTED 3" DIA SCHEDULE 40 PVC PIPINGSOLID 3" DIA SCHEDULE 40 PVC PIPINGEXTENT OF VAPOR LINERCOMMERCIAL TENANT SPACE RETAIL AREALOCATION OF VERTICAL RISER AND APPROXIMATE LOCATION OF TURBINE FAN ON ROOFTOPLOCATION OF OBSERVATION POINT (OP) (SEE DETAIL 5)NOTES:1. LAYOUT OF GROUND FLOOR SHOWN IN DRAWING. THIS VAPOR MITIGATION SYSTEM IS FOR THESOUTH TOWER ONLY.2. THE SOUTH TOWER VACANT SPACES AREAS WILL BE UPFITTED T AT A FUTURE DATE. THEVACANT SPACES CONTAIN THE INSTALLED VAPOR BARRIER WITHOUT A CONCRETE SLAB.VAPOR MITIGATION SYSTEM (VMS) SPECIFICATIONS1. VMS VAPOR LINER (BARRIER) IS STEGO WRAP 15-MIL VAPOR BARRIER MANUFACTURED BY STEGOINDUSTRIES LLCVAPOR LINER WAS INSTALLED AS SPECIFIED HEREIN AND PER MANUFACTURER INSTALLATIONINSTRUCTIONS TO CREATE A CONTINUOUS LINER BELOW THE GROUND FLOOR SLABS AND VACANT SPACESLOCATED IN THE SOUTH TOWER. A MINIMUM 5-INCH THICK BASE COURSE CONSISTING OF CLEAN #57 ISINSTALLED BENEATH THE VMS VAPOR LINER.2. VMS PIPING SHALL IS TRAPPED AND IS SLOPED A MINIMUM OF 18 UNIT VERTICAL IN 12 UNITS HORIZONTAL(1% SLOPE) TO GRAVITY DRAIN. HORIZONTAL COLLECTION PIPE CONSISTS OF 3" SCH 40 PVC (UNLESSOTHERWISE NOTED IN THE DRAWINGS). PVC PIPE JOINTS ARE CONNECTED USING PVC SOCKET COUPLINGSAND PVC GLUE. SUB-SLAB SLOTTED VAPOR COLLECTION PIPE ISTHREADED FLUSH JOINT 3" SCH 40 PVCPIPE WITH 0.020" SLOT WIDTH AND 18" SLOT SPACING. FABRIC FILTER SOCK IS INSTALLED OVER SLOTTEDPIPE SECTIONS. ACCESSIBLE ABOVE-SLAB RISER DUCT PIPING IS PERMANENTLY IDENTIFIED BY MEANS OFA TAG OR STENCIL WITH "MITIGATION VENT" WITHIN EACH FLOOR LEVEL AND ABOVE THE ROOF LINE ATINTERVALS OF NO GREATER THAN 10 LINEAR FT. 3" ID SERVICE WEIGHT CAST IRON RISER DUCT PIPING ISINSTALLED TO CONNECT EACH SLAB PENETRATION LOCATION TO A ROOFTOP EXHAUST DISCHARGE POINTWITH TURBINE FAN (SEE SPECIFICATION #3). ABOVE-SLAB RISER DUCT PIPE RUNS, THE ROOFTOP EXHAUSTFANS, AND ALL OTHER COMPONENTS OF THIS VMS HAVE BEEN INSTALLED PER APPLICABLE BUILDINGCODES AND AS SPECIFIED IN THE CONSTRUCTION DOCUMENTS AND DRAWINGS.3.RISER DUCT PIPING EXTENDS IN A VERTICAL ORIENTATION THROUGH THE BUILDING ROOF ANDTERMINATES A MINIMUM OF 2 FT ABOVE THE BUILDING ROOF LINE AND NEARBY PARAPET WALLS. A EMPIREMODEL TV04G TURBINE VENTILATOR FAN IS INSTALLED ON THE EXHAUST DISCHARGE END OF EACH RISERDUCT PIPE. AN ADAPTOR COUPLING SHALL BE INSTALLED AT THE DISCHARGE END OF THE 3" RISER DUCTPIPE AND THE FAN SHALL BE SECURED TO THE CAST IRON RISER IN A VERTICAL ORIENTATION. EXHAUSTDISCHARGE LOCATIONS ARE A MINIMUM OF 15 FT FROM ANY OPERABLE OPENING OR AIR INTAKES INTO THEBUILDING.4. RISER DUCT PIPING IS SERVICE WEIGHT 3" DIA CAST IRON PIPING WITH HUBLESS CONNECTIONSINSTALLED WITH STAINLESS STEEL NO-HUB COUPLINGS AND NEOPRENE GASKETS. ALL RISER PIPE WASINSTALLED IN ACCORDANCE WITH THE NORTH CAROLINA STATE PLUMBING CODE.5.THIS VAPOR MITIGATION PLAN IS INTENDED TO BE USED FOR DIRECTION OF VMS COMPONENTINSTALLATION ONLY AND IS NOT INTENDED TO GUIDE CONSTRUCTION OF STRUCTURAL COMPONENTS NOTRELATED TO THE VMS. CONSTRUCTION CONTRACTOR SHALL VERIFY CONSISTENCY OF VMS DETAILS WITHAPPLICABLE STRUCTURAL, ARCHITECTURAL, MECHANICAL, AND PLUMBING PLANS AND RESOLVE ANYINCONSISTENCIES PRIOR TO VMS INSTALLATION.SITE PLAN LAYOUT1" = 40'SOUTH TOWERNORTH TOWEROPEN AIRPARKING DECKWINONA STREETBLAND STREETGENERAL LOCATION OFVAPOR BARRIER ANDEXTENT OF VMSCONNECTORBUILDINGAS-BUILTDRAWING11/03/20S:\AAA-Master Projects\Beacon Partners- BEP or BCP\BCP-064 1414 and 1422 S. Tryon\Brownfields\VIMS Installation Reports\1st Floor - Bishops & Stir - Oct 2020\Figures\AS-BUILT.dwg, 11/4/2020 1:29:24 PM, DWG To PDF.pc3 Appendix C Field Forms INDOOR AIR BUILDING SURVEY and SAMPLING FORM Site Name: ____________________________________ DSCAID#: ______________________ Preparer’s name: ________________________________ Date: __________________________ Preparer’s affiliation: ____________________________ Phone #: _______________________ Part I - Occupants Building Address: ____________________________________________________________________ Property Contact: _______________________________ Owner / Renter / other: ______________ Contact’s Phone: home ( )__________ work ( )______________ cell ( )____________ # of Building occupants: Children under age 13 _____ Children age 13-18 ______ Adults _____ Part II – Building Characteristics Building type: residential / multi-family residential / office / strip mall / commercial / industrial Describe building: ________________________________________ Year constructed: _________ Sensitive population: day care / nursing home / hospital / school / other (specify): _______________ Number of floors below grade: ______ (full basement / crawl space / slab on grade) Number of floors at or above grade: ______ Depth of basement below grade surface: ______ ft. Basement size: _______ ft2 Basement floor construction: concrete / dirt / floating / stone / other (specify): ________________ Foundation walls: poured concrete / cinder blocks / stone / other (specify) ________________ Basement sump present? Yes / No Sump pump? Yes / No Water in sump? Yes / No Type of heating system (circle all that apply): hot air circulation hot air radiation wood steam radiation heat pump hot water radiation kerosene heater electric baseboard other (specify): ________________________ Type of ventilation system (circle all that apply): central air conditioning mechanical fans bathroom ventilation fans individual air conditioning units kitchen range hood fan outside air intake other (specify): _________________ Type of fuel utilized (circle all that apply): Natural gas / electric / fuel oil / wood / coal / solar / kerosene Are the basement walls or floor sealed with waterproof paint or epoxy coatings? Yes / No The Railyard - South Tower N/A Shannon Switch 5/20/22 Hart & Hickman, PC (704) 586-0007 1414 and 1422 South Tryon Street Charlotte, North Carolina Russ Leverman Project Manager 0007 704 350-0876 817 995-7637 Multi-purpose building with multiple commercial 2020 0 8 0 Is there a whole house fan? Yes / No Septic system? Yes / Yes (but not used) / No Irrigation/private well? Yes / Yes (but not used) / No Type of ground cover outside of building: grass / concrete / asphalt / other (specify) _____________ Existing subsurface depressurization (radon) system in place? Yes / No active / passive Sub-slab vapor/moisture barrier in place? Yes / No Type of barrier: ____________________________ Part III - Outside Contaminant Sources Other stationary sources nearby (gas stations, emission stacks, etc.): _____________________________ Heavy vehicular traffic nearby (or other mobile sources): ______________________________________ Part IV – Indoor Contaminant Sources Identify all potential indoor sources found in the building (including attached garages), the location of the source (floor and room), and whether the item was removed from the building 48 hours prior to indoor air sampling event. Any ventilation implemented after removal of the items should be completed at least 24 hours prior to the commencement of the indoor air sampling event. Potential Sources Location(s)Removed (Yes / No / NA) Gasoline storage cans Gas-powered equipment Kerosene storage cans Paints / thinners / strippers Cleaning solvents Oven cleaners Carpet / upholstery cleaners Other house cleaning products Moth balls Polishes / waxes Insecticides Furniture / floor polish Nail polish / polish remover Hairspray Cologne / perfume Air fresheners Fuel tank (inside building)NA Wood stove or fireplace NA New furniture / upholstery New carpeting / flooring NA Hobbies - glues, paints, etc. 15-mil Stego none located Yes - S. Tryon Street None N/A None N/A None N/A None N/A STIR Kitchen, Fitness Center No STIR Kitchen No Office Space No STIR Kitchen No None N/A STIR Kitchen No None N/A STIR Kitchen No None N/A None N/A None N/A None N/A None None Office Space No Office Space None N/A Alchohol based hand sanitizer stations were located throughout the building including the corridors. Part V – Miscellaneous Items Do any occupants of the building smoke? Yes / No How often? ______________ Last time someone smoked in the building? ____________ hours / days ago Does the building have an attached garage directly connected to living space? Yes / No If so, is a car usually parked in the garage? Yes / No Are gas-powered equipment or cans of gasoline/fuels stored in the garage? Yes / No Do the occupants of the building have their clothes dry cleaned? Yes / No If yes, how often? weekly / monthly / 3-4 times a year Do any of the occupants use solvents in work? Yes / No If yes, what types of solvents are used? _______________________________________ If yes, are their clothes washed at work? Yes / No Have any pesticides/herbicides been applied around the building or in the yard? Yes / No If so, when and which chemicals? _________________________________________________ Has there ever been a fire in the building? Yes / No If yes, when? _____________ Has painting or staining been done in the building in the last 6 months? Yes / No If yes, when __________________ and where? ____________________________ Part VI – Sampling Information Sample Technician: ____________________________ Phone number: ( ) _______ - __________ Sample Source: Indoor Air / Crawlspace Air / Sub-Slab / Near Slab Soil Gas / Exterior Soil Gas Sampler Type: Tedlar bag / Sorbent / Stainless Steel Canister / Other (specify): _________________ Analytical Method: TO-15 / TO-17 / other: _________ Cert. Laboratory: _________________ Sample locations (floor, room): Field ID # _____ - ________________________ Field ID # _____ - __________________________ Field ID # _____ - ________________________ Field ID # _____ - __________________________ Were “Instructions for Occupants” followed? Yes / No If not, describe modifications: __________________________________________________________ past month Office space SMS 704 586 0007 Select List Waypoint Analytical IAS 1 / IAS-DUP IAS 3 IAS 2 IAS 4, IAS-5, & BAS-1 Provide Drawing of Sample Location(s) in Building Part VII - Meteorological Conditions Was there significant precipitation within 12 hours prior to (or during) the sampling event? Yes / No Describe the general weather conditions: ___________________________________________________ _____________________________________________________________________________________ Part VIII – General Observations Provide any information that may be pertinent to the sampling event and may assist in the data interpretation process (e.g., observed that drycleaner operated with door or windows propped open for ventilation). 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Basement size: _______ ft2 Basement floor construction: concrete / dirt / floating / stone / other (specify): ________________ Foundation walls: poured concrete / cinder blocks / stone / other (specify) ________________ Basement sump present? Yes / No Sump pump? Yes / No Water in sump? Yes / No Type of heating system (circle all that apply): hot air circulation hot air radiation wood steam radiation heat pump hot water radiation kerosene heater electric baseboard other (specify): ________________________ Type of ventilation system (circle all that apply): central air conditioning mechanical fans bathroom ventilation fans individual air conditioning units kitchen range hood fan outside air intake other (specify): _________________ Type of fuel utilized (circle all that apply): Natural gas / electric / fuel oil / wood / coal / solar / kerosene Are the basement walls or floor sealed with waterproof paint or epoxy coatings? Yes / No The Railyard - South Tower N/A Shannon Switch 8/11/22 Hart & Hickman, PC (704) 586-0007 1414 and 1422 South Tryon Street Charlotte, North Carolina Russ Leverman Project Manager 007 704 350-0876 817 995-7637 Multi-purpose building with multiple commercial 2020 0 8 0 Is there a whole house fan? Yes / No Septic system? Yes / Yes (but not used) / No Irrigation/private well? Yes / Yes (but not used) / No Type of ground cover outside of building: grass / concrete / asphalt / other (specify) _____________ Existing subsurface depressurization (radon) system in place? Yes / No active / passive Sub-slab vapor/moisture barrier in place? Yes / No Type of barrier: ____________________________ Part III - Outside Contaminant Sources Other stationary sources nearby (gas stations, emission stacks, etc.): _____________________________ Heavy vehicular traffic nearby (or other mobile sources): ______________________________________ Part IV – Indoor Contaminant Sources Identify all potential indoor sources found in the building (including attached garages), the location of the source (floor and room), and whether the item was removed from the building 48 hours prior to indoor air sampling event. Any ventilation implemented after removal of the items should be completed at least 24 hours prior to the commencement of the indoor air sampling event. Potential Sources Location(s)Removed (Yes / No / NA) Gasoline storage cans Gas-powered equipment Kerosene storage cans Paints / thinners / strippers Cleaning solvents Oven cleaners Carpet / upholstery cleaners Other house cleaning products Moth balls Polishes / waxes Insecticides Furniture / floor polish Nail polish / polish remover Hairspray Cologne / perfume Air fresheners Fuel tank (inside building) NA Wood stove or fireplace NA New furniture / upholstery New carpeting / flooring NA Hobbies - glues, paints, etc. 15-mil Stego none located Yes - S. Tryon Street None N/A None N/A None N/A None N/A STIR Kitchen, Fitness Center No STIR Kitchen No None N/A STIR Kitchen No None N/A STIR Kitchen No None N/A STIR Kitchen No None N/A None N/A None N/A None N/A None None None N/A None None N/A Part V – Miscellaneous Items Do any occupants of the building smoke? Yes / No How often? ______________ Last time someone smoked in the building? ____________ hours / days ago Does the building have an attached garage directly connected to living space? Yes / No If so, is a car usually parked in the garage? Yes / No Are gas-powered equipment or cans of gasoline/fuels stored in the garage? Yes / No Do the occupants of the building have their clothes dry cleaned? Yes / No If yes, how often? weekly / monthly / 3-4 times a year Do any of the occupants use solvents in work? Yes / No If yes, what types of solvents are used? _______________________________________ If yes, are their clothes washed at work? Yes / No Have any pesticides/herbicides been applied around the building or in the yard? Yes / No If so, when and which chemicals? _________________________________________________ Has there ever been a fire in the building? Yes / No If yes, when? _____________ Has painting or staining been done in the building in the last 6 months? Yes / No If yes, when __________________ and where? ____________________________ Part VI – Sampling Information Sample Technician: ____________________________ Phone number: ( ) _______ - __________ Sample Source: Indoor Air / Crawlspace Air / Sub-Slab / Near Slab Soil Gas / Exterior Soil Gas Sampler Type: Tedlar bag / Sorbent / Stainless Steel Canister / Other (specify): _________________ Analytical Method: TO-15 / TO-17 / other: _________ Cert. Laboratory: _________________ Sample locations (floor, room): Field ID # _____ - ________________________ Field ID # _____ - __________________________ Field ID # _____ - ________________________ Field ID # _____ - __________________________ Were “Instructions for Occupants” followed? Yes / No If not, describe modifications: __________________________________________________________ past month Office space SMS 704 586 007 Select List Eurofins IAS 2 / IAS-DUP BAS 8/11/22 IAS 4 Provide Drawing of Sample Location(s) in Building Part VII - Meteorological Conditions Was there significant precipitation within 12 hours prior to (or during) the sampling event? Yes / No Describe the general weather conditions: ___________________________________________________ _____________________________________________________________________________________ Part VIII – General Observations Provide any information that may be pertinent to the sampling event and may assist in the data interpretation process (e.g., observed that drycleaner operated with door or windows propped open for ventilation). 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Concr. NA Gravel NA Full8/11/22145082 Syringe 2 12.0 0 ppm Yes23755OP-523135SS Perm. Concr. NA Gravel NA Full8/11/22 162085 Syringe 2 12.5 0 ppm Yes1L2401 Appendix D Laboratory Analytical Reports Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. 6/1/2022 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Charlotte, NC, 28203 Ref: Analytical Testing Lab Report Number: 22-141-0016 Client Project Description: The Railyard COU.001 Waypoint Analytical, LLC (Charlotte) received sample(s) on 5/23/2022 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Angela D Overcash Senior Project Manager Page 1 of 28 Certification Summary Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC State Program Lab ID Expiration Date 07/31/202237735State ProgramNorth Carolina 12/31/2022402State ProgramNorth Carolina 07/31/202299012State ProgramSouth Carolina 12/31/202299012State ProgramSouth Carolina Page 1 of 1 00016/22-141-0016 Page 2 of 28 Report Number: Sample Summary Table Client Project Description: 22-141-0016 The Railyard COU.001 Lab No Client Sample ID Matrix Date Collected Date Received 05/20/2022 14:45Air 90573 IAS-1 05/23/2022 14:42 05/20/2022Air 90574 IAS-DUP 05/23/2022 14:42 05/20/2022 17:30Air 90575 IAS-5 05/23/2022 14:42 05/20/2022 17:55Air 90576 IAS-2 05/23/2022 14:42 05/20/2022 17:50Air 90577 IAS-3 05/23/2022 14:42 05/20/2022 17:55Air 90578 IAS-4 05/23/2022 14:42 05/20/2022 17:05Air 90579 BAS-1 05/23/2022 14:42 Page 3 of 28 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 22-141-0016 Report Limit Project:The Railyard V 90573IAS-1 31.5 05/27/2022 16:20TO-15 Acetone µg/m3 0.202 J0.297 05/27/2022 16:20TO-15 Benzene µg/m3 0.0733 JB0.657 05/27/2022 16:20TO-15 Carbon Disulfide µg/m3 0.0608 2.65 05/27/2022 16:20TO-15 Dichlorodifluoromethane µg/m3 0.134 1030 05/30/2022 17:50TO-15 Ethanol µg/m3 4.23 2.49 05/27/2022 16:20TO-15 Ethyl Acetate µg/m3 0.136 J0.471 05/27/2022 16:20TO-15 Heptane µg/m3 0.143 J0.529 05/27/2022 16:20TO-15 n-Hexane µg/m3 0.0472 161 05/30/2022 17:50TO-15 Isopropyl Alchohol µg/m3 3.48 2.17 05/27/2022 16:20TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 J0.901 05/27/2022 16:20TO-15 4-Methyl-2-Pentanone µg/m3 0.121 J1.13 05/27/2022 16:20TO-15 Methylene Chloride µg/m3 0.489 J0.439 05/27/2022 16:20TO-15 Styrene µg/m3 0.124 JB0.787 05/27/2022 16:20TO-15 Tetrachloroethene µg/m3 0.181 5.32 05/27/2022 16:20TO-15 Toluene µg/m3 0.0901 J0.473 05/27/2022 16:20TO-15 o-Xylene µg/m3 0.157 J0.934 05/27/2022 16:20TO-15 m,p-Xylene µg/m3 0.217 V 90574IAS-DUP 31.6 05/27/2022 17:15TO-15 Acetone µg/m3 0.202 J0.275 05/27/2022 17:15TO-15 Benzene µg/m3 0.0733 JB0.713 05/27/2022 17:15TO-15 Carbon Disulfide µg/m3 0.0608 J0.731 05/27/2022 17:15TO-15 Chloromethane µg/m3 0.0673 2.67 05/27/2022 17:15TO-15 Dichlorodifluoromethane µg/m3 0.134 1050 05/30/2022 18:43TO-15 Ethanol µg/m3 4.23 2.55 05/27/2022 17:15TO-15 Ethyl Acetate µg/m3 0.136 J0.488 05/27/2022 17:15TO-15 Heptane µg/m3 0.143 162 05/30/2022 18:43TO-15 Isopropyl Alchohol µg/m3 3.48 2.39 05/27/2022 17:15TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 J0.819 05/27/2022 17:15TO-15 4-Methyl-2-Pentanone µg/m3 0.121 J1.15 05/27/2022 17:15TO-15 Methylene Chloride µg/m3 0.489 J0.396 05/27/2022 17:15TO-15 Styrene µg/m3 0.124 JB0.719 05/27/2022 17:15TO-15 Tetrachloroethene µg/m3 0.181 5.04 05/27/2022 17:15TO-15 Toluene µg/m3 0.0901 J1.48 05/27/2022 17:15TO-15 Trichlorofluoromethane µg/m3 0.130 J0.460 05/27/2022 17:15TO-15 o-Xylene µg/m3 0.157 J0.977 05/27/2022 17:15TO-15 m,p-Xylene µg/m3 0.217 Page 4 of 28 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 22-141-0016 Report Limit Project:The Railyard V 90575IAS-5 18.5 05/27/2022 18:11TO-15 Acetone µg/m3 0.202 J0.339 05/27/2022 18:11TO-15 Benzene µg/m3 0.0733 JB0.754 05/27/2022 18:11TO-15 Carbon Disulfide µg/m3 0.0608 J1.49 05/27/2022 18:11TO-15 Chloroform µg/m3 0.0864 J0.708 05/27/2022 18:11TO-15 Chloromethane µg/m3 0.0673 2.69 05/27/2022 18:11TO-15 Dichlorodifluoromethane µg/m3 0.134 3190 05/30/2022 19:36TO-15 Ethanol µg/m3 8.45 4.50 05/27/2022 18:11TO-15 Ethyl Acetate µg/m3 0.136 J0.369 05/27/2022 18:11TO-15 Heptane µg/m3 0.143 46.7 05/27/2022 18:11TO-15 Isopropyl Alchohol µg/m3 0.139 1.68 05/27/2022 18:11TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 J0.761 05/27/2022 18:11TO-15 Methylene Chloride µg/m3 0.489 JB1.67 05/27/2022 18:11TO-15 Tetrachloroethene µg/m3 0.181 J1.44 05/27/2022 18:11TO-15 Toluene µg/m3 0.0901 J1.66 05/27/2022 18:11TO-15 Trichlorofluoromethane µg/m3 0.130 J0.695 05/27/2022 18:11TO-15 m,p-Xylene µg/m3 0.217 V 90576IAS-2 19.7 05/27/2022 19:07TO-15 Acetone µg/m3 0.202 JB0.529 05/27/2022 19:07TO-15 Carbon Disulfide µg/m3 0.0608 J0.696 05/27/2022 19:07TO-15 Chloromethane µg/m3 0.0673 2.66 05/27/2022 19:07TO-15 Dichlorodifluoromethane µg/m3 0.134 177 05/30/2022 20:31TO-15 Ethanol µg/m3 1.69 J1.16 05/27/2022 19:07TO-15 Ethyl Acetate µg/m3 0.136 J0.352 05/27/2022 19:07TO-15 n-Hexane µg/m3 0.0472 50.4 05/27/2022 19:07TO-15 Isopropyl Alchohol µg/m3 0.139 1.75 05/27/2022 19:07TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 J0.809 05/27/2022 19:07TO-15 Methylene Chloride µg/m3 0.489 J0.738 05/27/2022 19:07TO-15 Propene µg/m3 0.242 34.9 05/27/2022 19:07TO-15 Tetrachloroethene µg/m3 0.181 J1.53 05/27/2022 19:07TO-15 Toluene µg/m3 0.0901 J0.634 05/27/2022 19:07TO-15 Trichloroethene µg/m3 0.199 J1.67 05/27/2022 19:07TO-15 Trichlorofluoromethane µg/m3 0.130 J0.664 05/27/2022 19:07TO-15 m,p-Xylene µg/m3 0.217 V 90577IAS-3 35.7 05/27/2022 20:04TO-15 Acetone µg/m3 0.202 J0.284 05/27/2022 20:04TO-15 Benzene µg/m3 0.0733 Page 5 of 28 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 22-141-0016 Report Limit Project:The Railyard V 90577IAS-3 J0.630 05/27/2022 20:04TO-15 Chloroform µg/m3 0.0864 2.65 05/27/2022 20:04TO-15 Dichlorodifluoromethane µg/m3 0.134 615 05/30/2022 21:26TO-15 Ethanol µg/m3 4.23 2.08 05/27/2022 20:04TO-15 Ethyl Acetate µg/m3 0.136 J0.512 05/27/2022 20:04TO-15 Heptane µg/m3 0.143 997 05/30/2022 21:26TO-15 Isopropyl Alchohol µg/m3 3.48 3.52 05/27/2022 20:04TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 JB0.563 05/27/2022 20:04TO-15 Tetrachloroethene µg/m3 0.181 1.89 05/27/2022 20:04TO-15 Toluene µg/m3 0.0901 J0.473 05/27/2022 20:04TO-15 o-Xylene µg/m3 0.157 J1.01 05/27/2022 20:04TO-15 m,p-Xylene µg/m3 0.217 V 90578IAS-4 21.2 05/27/2022 21:01TO-15 Acetone µg/m3 0.202 J1.46 05/27/2022 21:01TO-15 Benzene µg/m3 0.0733 3.34 05/27/2022 21:01TO-15 Chloroform µg/m3 0.0864 J0.752 05/27/2022 21:01TO-15 Chloromethane µg/m3 0.0673 J2.46 05/27/2022 21:01TO-15 Dichlorodifluoromethane µg/m3 0.134 3020 05/30/2022 22:21TO-15 Ethanol µg/m3 8.45 6.24 05/27/2022 21:01TO-15 Ethyl Acetate µg/m3 0.136 J0.455 05/27/2022 21:01TO-15 Heptane µg/m3 0.143 J21805/30/2022 22:21TO-15 Isopropyl Alchohol µg/m3 6.96 2.10 05/27/2022 21:01TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 J0.983 05/27/2022 21:01TO-15 Methylene Chloride µg/m3 0.489 19.8 05/27/2022 21:01TO-15 Tetrachloroethene µg/m3 0.181 J1.43 05/27/2022 21:01TO-15 Toluene µg/m3 0.0901 J0.484 05/27/2022 21:01TO-15 Trichloroethene µg/m3 0.199 J0.404 05/27/2022 21:01TO-15 o-Xylene µg/m3 0.157 J0.886 05/27/2022 21:01TO-15 m,p-Xylene µg/m3 0.217 V 90579BAS-1 16.9 05/27/2022 22:00TO-15 Acetone µg/m3 0.202 J0.294 05/27/2022 22:00TO-15 Benzene µg/m3 0.0733 JB0.641 05/27/2022 22:00TO-15 Carbon Disulfide µg/m3 0.0608 2.78 05/27/2022 22:00TO-15 Dichlorodifluoromethane µg/m3 0.134 25.7 05/27/2022 22:00TO-15 Ethanol µg/m3 0.169 J0.621 05/27/2022 22:00TO-15 1,1,2-Trichloro-1,2,2-trifluoroethane µg/m3 0.561 J0.484 05/27/2022 22:00TO-15 Heptane µg/m3 0.143 Page 6 of 28 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 22-141-0016 Report Limit Project:The Railyard V 90579BAS-1 J0.560 05/27/2022 22:00TO-15 n-Hexane µg/m3 0.0472 J3.47 05/27/2022 22:00TO-15 Isopropyl Alchohol µg/m3 0.139 1.61 05/27/2022 22:00TO-15 Methyl Ethyl Ketone (MEK)µg/m3 0.224 J0.785 05/27/2022 22:00TO-15 Methylene Chloride µg/m3 0.489 JB1.35 05/27/2022 22:00TO-15 Tetrachloroethene µg/m3 0.181 J1.11 05/27/2022 22:00TO-15 Toluene µg/m3 0.0901 J1.82 05/27/2022 22:00TO-15 Trichlorofluoromethane µg/m3 0.130 J0.469 05/27/2022 22:00TO-15 m,p-Xylene µg/m3 0.217 Page 7 of 28 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 22-141-0016 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Charlotte COU.001 Received : 05/23/2022 The Railyard Report Date : 06/01/2022 Sample ID : Lab No : Sampled:IAS-1 90573 Matrix: 5/20/2022 14:45 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V19299 05/27/22 09:00 V19319 05/30/22 09:00 31.5 µg/m3 0.202 4.75Acetone 1 05/27/22 16:20 V19303ENM 0.297 J µg/m3 0.0733 1.60Benzene 1 05/27/22 16:20 V19303ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 05/27/22 16:20 V19303ENM 0.657 JB µg/m3 0.0608 6.23Carbon Disulfide 1 05/27/22 16:20 V19303ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 05/27/22 16:20 V19303ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 05/27/22 16:20 V19303ENM <0.0864 µg/m3 0.0864 2.44Chloroform 1 05/27/22 16:20 V19303ENM <0.0673 µg/m3 0.0673 1.03Chloromethane 1 05/27/22 16:20 V19303ENM <0.161 µg/m3 0.161 3.44 Cyclohexane 1 05/27/22 16:20 V19303ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 05/27/22 16:20 V19303ENM 2.65 µg/m3 0.134 2.47Dichlorodifluoromethane 1 05/27/22 16:20 V19303ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 05/27/22 16:20 V19303ENM 1030 µg/m3 4.23 125Ethanol 25 05/30/22 17:50 V19327ENM 2.49 µg/m3 0.136 1.80Ethyl Acetate 1 05/27/22 16:20 V19303ENM <0.106 µg/m3 0.106 2.17Ethylbenzene 1 05/27/22 16:20 V19303ENM <0.128 µg/m3 0.128 2.46 4-Ethyltoluene 1 05/27/22 16:20 V19303ENM <0.561 µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 05/27/22 16:20 V19303ENM 0.471 J µg/m3 0.143 2.05Heptane 1 05/27/22 16:20 V19303ENM 0.529 J µg/m3 0.0472 1.76n-Hexane 1 05/27/22 16:20 V19303ENM 161 µg/m3 3.48 123Isopropyl Alchohol 25 05/30/22 17:50 V19327ENM 2.17 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 05/27/22 16:20 V19303ENM 0.901 J µg/m3 0.121 2.054-Methyl-2-Pentanone 1 05/27/22 16:20 V19303ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 8 of 28 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 22-141-0016 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Charlotte COU.001 Received : 05/23/2022 The Railyard Report Date : 06/01/2022 Sample ID : Lab No : Sampled:IAS-1 90573 Matrix: 5/20/2022 14:45 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V19299 05/27/22 09:00 V19319 05/30/22 09:00 1.13 J µg/m3 0.489 1.74Methylene Chloride 1 05/27/22 16:20 V19303ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 05/27/22 16:20 V19303ENM <0.242 µg/m3 0.242 0.861Propene 1 05/27/22 16:20 V19303ENM 0.439 J µg/m3 0.124 2.13Styrene 1 05/27/22 16:20 V19303ENM 0.787 JB µg/m3 0.181 3.39Tetrachloroethene 1 05/27/22 16:20 V19303ENM 5.32 µg/m3 0.0901 1.88Toluene 1 05/27/22 16:20 V19303ENM <0.199 µg/m3 0.199 2.15Trichloroethene 1 05/27/22 16:20 V19303ENM <0.130 µg/m3 0.130 2.81Trichlorofluoromethane 1 05/27/22 16:20 V19303ENM <0.110 µg/m3 0.110 2.46 1,2,4-Trimethylbenzene 1 05/27/22 16:20 V19303ENM <0.236 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 05/27/22 16:20 V19303ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 05/27/22 16:20 V19303ENM 0.473 J µg/m3 0.157 2.17o-Xylene 1 05/27/22 16:20 V19303ENM 0.934 J µg/m3 0.217 5.65m,p-Xylene 1 05/27/22 16:20 V19303ENM Surrogate: 4-Bromofluorobenzene 90.5 Limits: 70-130%05/27/22 16:201 ENM V19303 Surrogate: 4-Bromofluorobenzene 94.4 Limits: 70-130%05/30/22 17:5025 ENM V19327 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 9 of 28 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 22-141-0016 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Charlotte COU.001 Received : 05/23/2022 The Railyard Report Date : 06/01/2022 Sample ID : Lab No : Sampled:IAS-DUP 90574 Matrix: 5/20/2022 0:00 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V19299 05/27/22 09:00 V19319 05/30/22 09:00 31.6 µg/m3 0.202 4.75Acetone 1 05/27/22 17:15 V19303ENM 0.275 J µg/m3 0.0733 1.60Benzene 1 05/27/22 17:15 V19303ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 05/27/22 17:15 V19303ENM 0.713 JB µg/m3 0.0608 6.23Carbon Disulfide 1 05/27/22 17:15 V19303ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 05/27/22 17:15 V19303ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 05/27/22 17:15 V19303ENM <0.0864 µg/m3 0.0864 2.44Chloroform 1 05/27/22 17:15 V19303ENM 0.731 J µg/m3 0.0673 1.03Chloromethane 1 05/27/22 17:15 V19303ENM <0.161 µg/m3 0.161 3.44 Cyclohexane 1 05/27/22 17:15 V19303ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 05/27/22 17:15 V19303ENM 2.67 µg/m3 0.134 2.47Dichlorodifluoromethane 1 05/27/22 17:15 V19303ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 05/27/22 17:15 V19303ENM 1050 µg/m3 4.23 125Ethanol 25 05/30/22 18:43 V19327ENM 2.55 µg/m3 0.136 1.80Ethyl Acetate 1 05/27/22 17:15 V19303ENM <0.106 µg/m3 0.106 2.17Ethylbenzene 1 05/27/22 17:15 V19303ENM <0.128 µg/m3 0.128 2.46 4-Ethyltoluene 1 05/27/22 17:15 V19303ENM <0.561 µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 05/27/22 17:15 V19303ENM 0.488 J µg/m3 0.143 2.05Heptane 1 05/27/22 17:15 V19303ENM <0.0472 µg/m3 0.0472 1.76n-Hexane 1 05/27/22 17:15 V19303ENM 162 µg/m3 3.48 123Isopropyl Alchohol 25 05/30/22 18:43 V19327ENM 2.39 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 05/27/22 17:15 V19303ENM 0.819 J µg/m3 0.121 2.054-Methyl-2-Pentanone 1 05/27/22 17:15 V19303ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 10 of 28 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 22-141-0016 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Charlotte COU.001 Received : 05/23/2022 The Railyard Report Date : 06/01/2022 Sample ID : Lab No : Sampled:IAS-DUP 90574 Matrix: 5/20/2022 0:00 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V19299 05/27/22 09:00 V19319 05/30/22 09:00 1.15 J µg/m3 0.489 1.74Methylene Chloride 1 05/27/22 17:15 V19303ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 05/27/22 17:15 V19303ENM <0.242 µg/m3 0.242 0.861Propene 1 05/27/22 17:15 V19303ENM 0.396 J µg/m3 0.124 2.13Styrene 1 05/27/22 17:15 V19303ENM 0.719 JB µg/m3 0.181 3.39Tetrachloroethene 1 05/27/22 17:15 V19303ENM 5.04 µg/m3 0.0901 1.88Toluene 1 05/27/22 17:15 V19303ENM <0.199 µg/m3 0.199 2.15Trichloroethene 1 05/27/22 17:15 V19303ENM 1.48 J µg/m3 0.130 2.81Trichlorofluoromethane 1 05/27/22 17:15 V19303ENM <0.110 µg/m3 0.110 2.46 1,2,4-Trimethylbenzene 1 05/27/22 17:15 V19303ENM <0.236 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 05/27/22 17:15 V19303ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 05/27/22 17:15 V19303ENM 0.460 J µg/m3 0.157 2.17o-Xylene 1 05/27/22 17:15 V19303ENM 0.977 J µg/m3 0.217 5.65m,p-Xylene 1 05/27/22 17:15 V19303ENM Surrogate: 4-Bromofluorobenzene 91.6 Limits: 70-130%05/27/22 17:151 ENM V19303 Surrogate: 4-Bromofluorobenzene 92.7 Limits: 70-130%05/30/22 18:4325 ENM V19327 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 11 of 28 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 22-141-0016 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Charlotte COU.001 Received : 05/23/2022 The Railyard Report Date : 06/01/2022 Sample ID : Lab No : Sampled:IAS-5 90575 Matrix: 5/20/2022 17:30 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V19299 05/27/22 09:00 V19319 05/30/22 09:00 18.5 µg/m3 0.202 4.75Acetone 1 05/27/22 18:11 V19303ENM 0.339 J µg/m3 0.0733 1.60Benzene 1 05/27/22 18:11 V19303ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 05/27/22 18:11 V19303ENM 0.754 JB µg/m3 0.0608 6.23Carbon Disulfide 1 05/27/22 18:11 V19303ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 05/27/22 18:11 V19303ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 05/27/22 18:11 V19303ENM 1.49 J µg/m3 0.0864 2.44Chloroform 1 05/27/22 18:11 V19303ENM 0.708 J µg/m3 0.0673 1.03Chloromethane 1 05/27/22 18:11 V19303ENM <0.161 µg/m3 0.161 3.44 Cyclohexane 1 05/27/22 18:11 V19303ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 05/27/22 18:11 V19303ENM 2.69 µg/m3 0.134 2.47Dichlorodifluoromethane 1 05/27/22 18:11 V19303ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 05/27/22 18:11 V19303ENM 3190 µg/m3 8.45 250Ethanol 50 05/30/22 19:36 V19327ENM 4.50 µg/m3 0.136 1.80Ethyl Acetate 1 05/27/22 18:11 V19303ENM <0.106 µg/m3 0.106 2.17Ethylbenzene 1 05/27/22 18:11 V19303ENM <0.128 µg/m3 0.128 2.46 4-Ethyltoluene 1 05/27/22 18:11 V19303ENM <0.561 µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 05/27/22 18:11 V19303ENM 0.369 J µg/m3 0.143 2.05Heptane 1 05/27/22 18:11 V19303ENM <0.0472 µg/m3 0.0472 1.76n-Hexane 1 05/27/22 18:11 V19303ENM 46.7 µg/m3 0.139 4.92Isopropyl Alchohol 1 05/27/22 18:11 V19303ENM 1.68 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 05/27/22 18:11 V19303ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 05/27/22 18:11 V19303ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 12 of 28 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 22-141-0016 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Charlotte COU.001 Received : 05/23/2022 The Railyard Report Date : 06/01/2022 Sample ID : Lab No : Sampled:IAS-5 90575 Matrix: 5/20/2022 17:30 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V19299 05/27/22 09:00 V19319 05/30/22 09:00 0.761 J µg/m3 0.489 1.74Methylene Chloride 1 05/27/22 18:11 V19303ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 05/27/22 18:11 V19303ENM <0.242 µg/m3 0.242 0.861Propene 1 05/27/22 18:11 V19303ENM <0.124 µg/m3 0.124 2.13Styrene 1 05/27/22 18:11 V19303ENM 1.67 JB µg/m3 0.181 3.39Tetrachloroethene 1 05/27/22 18:11 V19303ENM 1.44 J µg/m3 0.0901 1.88Toluene 1 05/27/22 18:11 V19303ENM <0.199 µg/m3 0.199 2.15Trichloroethene 1 05/27/22 18:11 V19303ENM 1.66 J µg/m3 0.130 2.81Trichlorofluoromethane 1 05/27/22 18:11 V19303ENM <0.110 µg/m3 0.110 2.46 1,2,4-Trimethylbenzene 1 05/27/22 18:11 V19303ENM <0.236 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 05/27/22 18:11 V19303ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 05/27/22 18:11 V19303ENM <0.157 µg/m3 0.157 2.17o-Xylene 1 05/27/22 18:11 V19303ENM 0.695 J µg/m3 0.217 5.65m,p-Xylene 1 05/27/22 18:11 V19303ENM Surrogate: 4-Bromofluorobenzene 90.5 Limits: 70-130%05/27/22 18:111 ENM V19303 Surrogate: 4-Bromofluorobenzene 94.4 Limits: 70-130%05/30/22 19:3650 ENM V19327 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 13 of 28 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 22-141-0016 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Charlotte COU.001 Received : 05/23/2022 The Railyard Report Date : 06/01/2022 Sample ID : Lab No : Sampled:IAS-2 90576 Matrix: 5/20/2022 17:55 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V19299 05/27/22 09:00 V19319 05/30/22 09:00 19.7 µg/m3 0.202 4.75Acetone 1 05/27/22 19:07 V19303ENM <0.0733 µg/m3 0.0733 1.60Benzene 1 05/27/22 19:07 V19303ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 05/27/22 19:07 V19303ENM 0.529 JB µg/m3 0.0608 6.23Carbon Disulfide 1 05/27/22 19:07 V19303ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 05/27/22 19:07 V19303ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 05/27/22 19:07 V19303ENM <0.0864 µg/m3 0.0864 2.44Chloroform 1 05/27/22 19:07 V19303ENM 0.696 J µg/m3 0.0673 1.03Chloromethane 1 05/27/22 19:07 V19303ENM <0.161 µg/m3 0.161 3.44 Cyclohexane 1 05/27/22 19:07 V19303ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 05/27/22 19:07 V19303ENM 2.66 µg/m3 0.134 2.47Dichlorodifluoromethane 1 05/27/22 19:07 V19303ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 05/27/22 19:07 V19303ENM 177 µg/m3 1.69 50.0Ethanol 10 05/30/22 20:31 V19327ENM 1.16 J µg/m3 0.136 1.80Ethyl Acetate 1 05/27/22 19:07 V19303ENM <0.106 µg/m3 0.106 2.17Ethylbenzene 1 05/27/22 19:07 V19303ENM <0.128 µg/m3 0.128 2.46 4-Ethyltoluene 1 05/27/22 19:07 V19303ENM <0.561 µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 05/27/22 19:07 V19303ENM <0.143 µg/m3 0.143 2.05Heptane 1 05/27/22 19:07 V19303ENM 0.352 J µg/m3 0.0472 1.76n-Hexane 1 05/27/22 19:07 V19303ENM 50.4 µg/m3 0.139 4.92Isopropyl Alchohol 1 05/27/22 19:07 V19303ENM 1.75 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 05/27/22 19:07 V19303ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 05/27/22 19:07 V19303ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 14 of 28 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 22-141-0016 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Charlotte COU.001 Received : 05/23/2022 The Railyard Report Date : 06/01/2022 Sample ID : Lab No : Sampled:IAS-2 90576 Matrix: 5/20/2022 17:55 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V19299 05/27/22 09:00 V19319 05/30/22 09:00 0.809 J µg/m3 0.489 1.74Methylene Chloride 1 05/27/22 19:07 V19303ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 05/27/22 19:07 V19303ENM 0.738 J µg/m3 0.242 0.861Propene 1 05/27/22 19:07 V19303ENM <0.124 µg/m3 0.124 2.13Styrene 1 05/27/22 19:07 V19303ENM 34.9 µg/m3 0.181 3.39Tetrachloroethene 1 05/27/22 19:07 V19303ENM 1.53 J µg/m3 0.0901 1.88Toluene 1 05/27/22 19:07 V19303ENM 0.634 J µg/m3 0.199 2.15Trichloroethene 1 05/27/22 19:07 V19303ENM 1.67 J µg/m3 0.130 2.81Trichlorofluoromethane 1 05/27/22 19:07 V19303ENM <0.110 µg/m3 0.110 2.46 1,2,4-Trimethylbenzene 1 05/27/22 19:07 V19303ENM <0.236 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 05/27/22 19:07 V19303ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 05/27/22 19:07 V19303ENM <0.157 µg/m3 0.157 2.17o-Xylene 1 05/27/22 19:07 V19303ENM 0.664 J µg/m3 0.217 5.65m,p-Xylene 1 05/27/22 19:07 V19303ENM Surrogate: 4-Bromofluorobenzene 90.8 Limits: 70-130%05/27/22 19:071 ENM V19303 Surrogate: 4-Bromofluorobenzene 94.4 Limits: 70-130%05/30/22 20:3110 ENM V19327 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 15 of 28 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 22-141-0016 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Charlotte COU.001 Received : 05/23/2022 The Railyard Report Date : 06/01/2022 Sample ID : Lab No : Sampled:IAS-3 90577 Matrix: 5/20/2022 17:50 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V19299 05/27/22 09:00 V19319 05/30/22 09:00 35.7 µg/m3 0.202 4.75Acetone 1 05/27/22 20:04 V19303ENM 0.284 J µg/m3 0.0733 1.60Benzene 1 05/27/22 20:04 V19303ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 05/27/22 20:04 V19303ENM <0.0608 µg/m3 0.0608 6.23Carbon Disulfide 1 05/27/22 20:04 V19303ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 05/27/22 20:04 V19303ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 05/27/22 20:04 V19303ENM 0.630 J µg/m3 0.0864 2.44Chloroform 1 05/27/22 20:04 V19303ENM <0.0673 µg/m3 0.0673 1.03Chloromethane 1 05/27/22 20:04 V19303ENM <0.161 µg/m3 0.161 3.44 Cyclohexane 1 05/27/22 20:04 V19303ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 05/27/22 20:04 V19303ENM 2.65 µg/m3 0.134 2.47Dichlorodifluoromethane 1 05/27/22 20:04 V19303ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 05/27/22 20:04 V19303ENM 615 µg/m3 4.23 125Ethanol 25 05/30/22 21:26 V19327ENM 2.08 µg/m3 0.136 1.80Ethyl Acetate 1 05/27/22 20:04 V19303ENM <0.106 µg/m3 0.106 2.17Ethylbenzene 1 05/27/22 20:04 V19303ENM <0.128 µg/m3 0.128 2.46 4-Ethyltoluene 1 05/27/22 20:04 V19303ENM <0.561 µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 05/27/22 20:04 V19303ENM 0.512 J µg/m3 0.143 2.05Heptane 1 05/27/22 20:04 V19303ENM <0.0472 µg/m3 0.0472 1.76n-Hexane 1 05/27/22 20:04 V19303ENM 997 µg/m3 3.48 123Isopropyl Alchohol 25 05/30/22 21:26 V19327ENM 3.52 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 05/27/22 20:04 V19303ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 05/27/22 20:04 V19303ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 16 of 28 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 22-141-0016 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Charlotte COU.001 Received : 05/23/2022 The Railyard Report Date : 06/01/2022 Sample ID : Lab No : Sampled:IAS-3 90577 Matrix: 5/20/2022 17:50 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V19299 05/27/22 09:00 V19319 05/30/22 09:00 <0.489 µg/m3 0.489 1.74Methylene Chloride 1 05/27/22 20:04 V19303ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 05/27/22 20:04 V19303ENM <0.242 µg/m3 0.242 0.861Propene 1 05/27/22 20:04 V19303ENM <0.124 µg/m3 0.124 2.13Styrene 1 05/27/22 20:04 V19303ENM 0.563 JB µg/m3 0.181 3.39Tetrachloroethene 1 05/27/22 20:04 V19303ENM 1.89 µg/m3 0.0901 1.88Toluene 1 05/27/22 20:04 V19303ENM <0.199 µg/m3 0.199 2.15Trichloroethene 1 05/27/22 20:04 V19303ENM <0.130 µg/m3 0.130 2.81Trichlorofluoromethane 1 05/27/22 20:04 V19303ENM <0.110 µg/m3 0.110 2.46 1,2,4-Trimethylbenzene 1 05/27/22 20:04 V19303ENM <0.236 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 05/27/22 20:04 V19303ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 05/27/22 20:04 V19303ENM 0.473 J µg/m3 0.157 2.17o-Xylene 1 05/27/22 20:04 V19303ENM 1.01 J µg/m3 0.217 5.65m,p-Xylene 1 05/27/22 20:04 V19303ENM Surrogate: 4-Bromofluorobenzene 91.6 Limits: 70-130%05/27/22 20:041 ENM V19303 Surrogate: 4-Bromofluorobenzene 88.5 Limits: 70-130%05/30/22 21:2625 ENM V19327 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 17 of 28 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 22-141-0016 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Charlotte COU.001 Received : 05/23/2022 The Railyard Report Date : 06/01/2022 Sample ID : Lab No : Sampled:IAS-4 90578 Matrix: 5/20/2022 17:55 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V19299 05/27/22 09:00 V19319 05/30/22 09:00 21.2 µg/m3 0.202 4.75Acetone 1 05/27/22 21:01 V19303ENM 1.46 J µg/m3 0.0733 1.60Benzene 1 05/27/22 21:01 V19303ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 05/27/22 21:01 V19303ENM <0.0608 µg/m3 0.0608 6.23Carbon Disulfide 1 05/27/22 21:01 V19303ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 05/27/22 21:01 V19303ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 05/27/22 21:01 V19303ENM 3.34 µg/m3 0.0864 2.44Chloroform 1 05/27/22 21:01 V19303ENM 0.752 J µg/m3 0.0673 1.03Chloromethane 1 05/27/22 21:01 V19303ENM <0.161 µg/m3 0.161 3.44 Cyclohexane 1 05/27/22 21:01 V19303ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 05/27/22 21:01 V19303ENM 2.46 J µg/m3 0.134 2.47Dichlorodifluoromethane 1 05/27/22 21:01 V19303ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 05/27/22 21:01 V19303ENM 3020 µg/m3 8.45 250Ethanol 50 05/30/22 22:21 V19327ENM 6.24 µg/m3 0.136 1.80Ethyl Acetate 1 05/27/22 21:01 V19303ENM <0.106 µg/m3 0.106 2.17Ethylbenzene 1 05/27/22 21:01 V19303ENM <0.128 µg/m3 0.128 2.46 4-Ethyltoluene 1 05/27/22 21:01 V19303ENM <0.561 µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 05/27/22 21:01 V19303ENM 0.455 J µg/m3 0.143 2.05Heptane 1 05/27/22 21:01 V19303ENM <0.0472 µg/m3 0.0472 1.76n-Hexane 1 05/27/22 21:01 V19303ENM 218 J µg/m3 6.96 246Isopropyl Alchohol 50 05/30/22 22:21 V19327ENM 2.10 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 05/27/22 21:01 V19303ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 05/27/22 21:01 V19303ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 18 of 28 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 22-141-0016 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Charlotte COU.001 Received : 05/23/2022 The Railyard Report Date : 06/01/2022 Sample ID : Lab No : Sampled:IAS-4 90578 Matrix: 5/20/2022 17:55 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V19299 05/27/22 09:00 V19319 05/30/22 09:00 0.983 J µg/m3 0.489 1.74Methylene Chloride 1 05/27/22 21:01 V19303ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 05/27/22 21:01 V19303ENM <0.242 µg/m3 0.242 0.861Propene 1 05/27/22 21:01 V19303ENM <0.124 µg/m3 0.124 2.13Styrene 1 05/27/22 21:01 V19303ENM 19.8 µg/m3 0.181 3.39Tetrachloroethene 1 05/27/22 21:01 V19303ENM 1.43 J µg/m3 0.0901 1.88Toluene 1 05/27/22 21:01 V19303ENM 0.484 J µg/m3 0.199 2.15Trichloroethene 1 05/27/22 21:01 V19303ENM <0.130 µg/m3 0.130 2.81Trichlorofluoromethane 1 05/27/22 21:01 V19303ENM <0.110 µg/m3 0.110 2.46 1,2,4-Trimethylbenzene 1 05/27/22 21:01 V19303ENM <0.236 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 05/27/22 21:01 V19303ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 05/27/22 21:01 V19303ENM 0.404 J µg/m3 0.157 2.17o-Xylene 1 05/27/22 21:01 V19303ENM 0.886 J µg/m3 0.217 5.65m,p-Xylene 1 05/27/22 21:01 V19303ENM Surrogate: 4-Bromofluorobenzene 92.7 Limits: 70-130%05/27/22 21:011 ENM V19303 Surrogate: 4-Bromofluorobenzene 89.7 Limits: 70-130%05/30/22 22:2150 ENM V19327 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 19 of 28 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 22-141-0016 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Charlotte COU.001 Received : 05/23/2022 The Railyard Report Date : 06/01/2022 Sample ID : Lab No : Sampled:BAS-1 90579 Matrix: 5/20/2022 17:05 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V19299 05/27/22 09:00 16.9 µg/m3 0.202 4.75Acetone 1 05/27/22 22:00 V19303ENM 0.294 J µg/m3 0.0733 1.60Benzene 1 05/27/22 22:00 V19303ENM <0.328 µg/m3 0.328 1.111,3-Butadiene 1 05/27/22 22:00 V19303ENM 0.641 JB µg/m3 0.0608 6.23Carbon Disulfide 1 05/27/22 22:00 V19303ENM <0.155 µg/m3 0.155 3.15Carbon Tetrachloride 1 05/27/22 22:00 V19303ENM <0.164 µg/m3 0.164 1.32Chloroethane 1 05/27/22 22:00 V19303ENM <0.0864 µg/m3 0.0864 2.44Chloroform 1 05/27/22 22:00 V19303ENM <0.0673 µg/m3 0.0673 1.03Chloromethane 1 05/27/22 22:00 V19303ENM <0.161 µg/m3 0.161 3.44 Cyclohexane 1 05/27/22 22:00 V19303ENM <0.174 µg/m3 0.174 12.01,3-Dichlorobenzene 1 05/27/22 22:00 V19303ENM 2.78 µg/m3 0.134 2.47Dichlorodifluoromethane 1 05/27/22 22:00 V19303ENM <0.205 µg/m3 0.205 2.311,2-Dichloropropane 1 05/27/22 22:00 V19303ENM 25.7 µg/m3 0.169 5.00Ethanol 1 05/27/22 22:00 V19303ENM <0.136 µg/m3 0.136 1.80Ethyl Acetate 1 05/27/22 22:00 V19303ENM <0.106 µg/m3 0.106 2.17Ethylbenzene 1 05/27/22 22:00 V19303ENM <0.128 µg/m3 0.128 2.46 4-Ethyltoluene 1 05/27/22 22:00 V19303ENM 0.621 J µg/m3 0.561 3.831,1,2-Trichloro-1,2,2-trifluoroethane 1 05/27/22 22:00 V19303ENM 0.484 J µg/m3 0.143 2.05Heptane 1 05/27/22 22:00 V19303ENM 0.560 J µg/m3 0.0472 1.76n-Hexane 1 05/27/22 22:00 V19303ENM 3.47 J µg/m3 0.139 4.92Isopropyl Alchohol 1 05/27/22 22:00 V19303ENM 1.61 µg/m3 0.224 1.47Methyl Ethyl Ketone (MEK)1 05/27/22 22:00 V19303ENM <0.121 µg/m3 0.121 2.054-Methyl-2-Pentanone 1 05/27/22 22:00 V19303ENM Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 20 of 28 , REPORT OF ANALYSISReport Number : Project Information : NC 28203 22-141-0016 01102 Hart & Hickman (Charlotte) 2923 South Tryon St. Ste 100 Charlotte COU.001 Received : 05/23/2022 The Railyard Report Date : 06/01/2022 Sample ID : Lab No : Sampled:BAS-1 90579 Matrix: 5/20/2022 17:05 Air Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF TO-15 Prep TO-15 Prep Batch(es):V19299 05/27/22 09:00 0.785 J µg/m3 0.489 1.74Methylene Chloride 1 05/27/22 22:00 V19303ENM <0.183 µg/m3 0.183 2.62Naphthalene 1 05/27/22 22:00 V19303ENM <0.242 µg/m3 0.242 0.861Propene 1 05/27/22 22:00 V19303ENM <0.124 µg/m3 0.124 2.13Styrene 1 05/27/22 22:00 V19303ENM 1.35 JB µg/m3 0.181 3.39Tetrachloroethene 1 05/27/22 22:00 V19303ENM 1.11 J µg/m3 0.0901 1.88Toluene 1 05/27/22 22:00 V19303ENM <0.199 µg/m3 0.199 2.15Trichloroethene 1 05/27/22 22:00 V19303ENM 1.82 J µg/m3 0.130 2.81Trichlorofluoromethane 1 05/27/22 22:00 V19303ENM <0.110 µg/m3 0.110 2.46 1,2,4-Trimethylbenzene 1 05/27/22 22:00 V19303ENM <0.236 µg/m3 0.236 2.461,3,5-Trimethylbenzene 1 05/27/22 22:00 V19303ENM <0.127 µg/m3 0.127 1.28Vinyl Chloride 1 05/27/22 22:00 V19303ENM <0.157 µg/m3 0.157 2.17o-Xylene 1 05/27/22 22:00 V19303ENM 0.469 J µg/m3 0.217 5.65m,p-Xylene 1 05/27/22 22:00 V19303ENM Surrogate: 4-Bromofluorobenzene 92.5 Limits: 70-130%05/27/22 22:001 ENM V19303 Qualifiers/ Definitions Dilution FactorDFAnalyte detected in blankB Method Quantitation LimitMQLEstimated valueJ Page 21 of 28 Quality Control Data 22-141-0016Report No: Project Description: Client ID:Hart & Hickman (Charlotte) The Railyard QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V19303QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V19299 Associated Lab Samples: 90573, 90574, 90575, 90576, 90577, 90578, 90579 LRB-V19299 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 05/27/22 09:574.750.2020.513µg/m3Acetone 05/27/22 09:571.600.0733<0.0733µg/m3Benzene 05/27/22 09:571.110.328<0.328µg/m31,3-Butadiene 05/27/22 09:576.230.06081.21µg/m3Carbon Disulfide 05/27/22 09:573.150.155<0.155µg/m3Carbon Tetrachloride 05/27/22 09:571.320.164<0.164µg/m3Chloroethane 05/27/22 09:572.440.0864<0.0864µg/m3Chloroform 05/27/22 09:571.030.0673<0.0673µg/m3Chloromethane 05/27/22 09:573.440.161<0.161µg/m3Cyclohexane 05/27/22 09:5712.00.174<0.174µg/m31,3-Dichlorobenzene 05/27/22 09:572.470.134<0.134µg/m3Dichlorodifluoromethane 05/27/22 09:572.310.205<0.205µg/m31,2-Dichloropropane 05/27/22 09:575.000.1690.552µg/m3Ethanol 05/27/22 09:571.800.136<0.136µg/m3Ethyl Acetate 05/27/22 09:572.170.106<0.106µg/m3Ethylbenzene 05/27/22 09:572.460.128<0.128µg/m34-Ethyltoluene 05/27/22 09:573.830.561<0.561µg/m31,1,2-Trichloro-1,2,2-trifluoroethane 05/27/22 09:572.050.143<0.143µg/m3Heptane 05/27/22 09:571.760.0472<0.0472µg/m3n-Hexane 05/27/22 09:574.920.139<0.139µg/m3Isopropyl Alchohol 05/27/22 09:571.470.224<0.224µg/m3Methyl Ethyl Ketone (MEK) 05/27/22 09:572.050.121<0.121µg/m34-Methyl-2-Pentanone 05/27/22 09:571.740.489<0.489µg/m3Methylene Chloride 05/27/22 09:572.620.183<0.183µg/m3Naphthalene 05/27/22 09:570.8610.242<0.242µg/m3Propene 05/27/22 09:572.130.124<0.124µg/m3Styrene 05/27/22 09:573.390.1811.02µg/m3Tetrachloroethene Page 1 of 4Date:06/01/2022 01:29 PM Page 22 of 28 Quality Control Data 22-141-0016Report No: Project Description: Client ID:Hart & Hickman (Charlotte) The Railyard QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V19303QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V19299 Associated Lab Samples: 90573, 90574, 90575, 90576, 90577, 90578, 90579 LRB-V19299 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 05/27/22 09:571.880.0901<0.0901µg/m3Toluene 05/27/22 09:572.150.199<0.199µg/m3Trichloroethene 05/27/22 09:572.810.130<0.130µg/m3Trichlorofluoromethane 05/27/22 09:572.460.110<0.110µg/m31,2,4-Trimethylbenzene 05/27/22 09:572.460.236<0.236µg/m31,3,5-Trimethylbenzene 05/27/22 09:571.280.127<0.127µg/m3Vinyl Chloride 05/27/22 09:572.170.157<0.157µg/m3o-Xylene 05/27/22 09:575.650.217<0.217µg/m3m,p-Xylene 05/27/22 09:574-Bromofluorobenzene (S)96.3 70-130 LCS-V19299Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 10512.511.9µg/m3Acetone 70-130 10516.816.0µg/m3Benzene 70-130 11512.811.1µg/m31,3-Butadiene 70-130 12219.015.6µg/m3Carbon Disulfide 70-130 10733.831.5µg/m3Carbon Tetrachloride 70-130 10614.013.2µg/m3Chloroethane 70-130 10726.124.4µg/m3Chloroform 70-130 11712.110.3µg/m3Chloromethane 70-130 81.314.017.2µg/m3Cyclohexane 70-130 99.329.930.1µg/m31,3-Dichlorobenzene 70-130 11328.024.7µg/m3Dichlorodifluoromethane 70-130 10724.823.1µg/m31,2-Dichloropropane 70-130 88.08.299.42µg/m3Ethanol 70-130 12021.618.0µg/m3Ethyl Acetate 70-130 Page 2 of 4Date:06/01/2022 01:29 PM Page 23 of 28 Quality Control Data 22-141-0016Report No: Project Description: Client ID:Hart & Hickman (Charlotte) The Railyard QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V19303QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V19299 LCS-V19299Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 10522.821.7µg/m3Ethylbenzene 70-130 10525.824.6µg/m34-Ethyltoluene 70-130 10941.838.3µg/m31,1,2-Trichloro-1,2,2-trifluoroethane 70-130 11323.120.5µg/m3Heptane 70-130 11319.917.6µg/m3n-Hexane 70-130 11113.612.3µg/m3Isopropyl Alchohol 70-130 11216.614.8µg/m3Methyl Ethyl Ketone (MEK)70-130 10621.820.5µg/m34-Methyl-2-Pentanone 70-130 10919.017.4µg/m3Methylene Chloride 70-130 11630.426.2µg/m3Naphthalene 70-130 1139.758.61µg/m3Propene 70-130 10522.421.3µg/m3Styrene 70-130 10836.533.9µg/m3Tetrachloroethene 70-130 10720.118.8µg/m3Toluene 70-130 10327.726.9µg/m3Trichloroethene 70-130 11532.328.1µg/m3Trichlorofluoromethane 70-130 10425.724.6µg/m31,2,4-Trimethylbenzene 70-130 10726.324.6µg/m31,3,5-Trimethylbenzene 70-130 11314.512.8µg/m3Vinyl Chloride 70-130 12627.421.7µg/m3o-Xylene 70-130 10746.343.4µg/m3m,p-Xylene 70-130 95.24-Bromofluorobenzene (S)70-130 Page 3 of 4Date:06/01/2022 01:29 PM Page 24 of 28 Quality Control Data 22-141-0016Report No: Project Description: Client ID:Hart & Hickman (Charlotte) The Railyard QC Prep Batch Method: Volatile Organic Compounds in Air- GC/MS TO-15 V19327QC Analytical Batch(es): Analysis Method: Analysis Description: TO-15 Prep QC Prep:V19319 Associated Lab Samples: 90573, 90574, 90575, 90576, 90577, 90578 LRB-V19319 Matrix: AIRLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 05/30/22 14:005.000.1690.430µg/m3Ethanol 05/30/22 14:004.920.1390.511µg/m3Isopropyl Alchohol 05/30/22 14:004-Bromofluorobenzene (S)93.8 70-130 LCS-V19319Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 90.58.539.42µg/m3Ethanol 70-130 11514.112.3µg/m3Isopropyl Alchohol 70-130 95.24-Bromofluorobenzene (S)70-130 Page 4 of 4Date:06/01/2022 01:29 PM Page 25 of 28 Fed Ex UPS US Postal Client Lab Courier Other : Shipment Receipt Form Customer Number: Customer Name: Report Number:22-141-0016 Hart & Hickman (Charlotte) 01102 Shipping Method Shipping container/cooler uncompromised? Thermometer ID:N/A Chain of Custody (COC) present?Yes No Yes No Not Present Yes No Not Present Yes No COC agrees with sample label(s)? Yes No COC properly completed Samples in proper containers? Sample containers intact? Sufficient sample volume for indicated test(s)? All samples received within holding time? Cooler temperature in compliance? Yes No Yes No Yes No Yes No Yes No Yes NoCooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. Yes No Yes No N/A Yes No N/A Yes No N/ASoil VOA method 5035 – compliance criteria met Water - Sample containers properly preserved Water - VOA vials free of headspace Yes No N/A Trip Blanks received with VOAs Low concentration EnCore samplers (48 hr) High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d) High concentration container (48 hr) Custody seals intact on shipping container/cooler? Custody seals intact on sample bottles? Number of coolers/boxes received Yes No 1 Signature:Paula Blakeborough Date & Time:05/23/2022 15:52:15 Special precautions or instructions included? Comments: Page 26 of 28 Page 27 of 28 Page 28 of 28 ANALYTICAL REPORT Eurofins Savannah 5102 LaRoche Avenue Savannah, GA 31404 Tel: (912)354-7858 Laboratory Job ID: 680-220017-2 Client Project/Site: COU-001 Revision: 1 For: Hart & Hickman, PC 2923 S Tryon Street Suite 100 Charlotte, North Carolina 28203 Attn: Andrew Besu Authorized for release by: 8/25/2022 4:41:55 PM David Fuller, Project Manager (770)344-8986 David.Fuller@et.eurofinsus.com The test results in this report meet all 2003 NELAC, 2009 TNI, and 2016 TNI requirements for accredited parameters, exceptions are noted in this report. This report may not be reproduced except in full, and with written approval from the laboratory. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page. This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature. Results relate only to the items tested and the sample(s) as received by the laboratory. 1 2 3 4 5 6 Table of Contents Client: Hart & Hickman, PC Project/Site: COU-001 Laboratory Job ID: 680-220017-2 Page 2 of 26 Eurofins Savannah8/25/2022 (Rev. 1) Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1 Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2 Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3 Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4 Subcontract Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5 Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .26 1 2 3 4 5 6 Case Narrative Client: Hart & Hickman, PC Job ID: 680-220017-2 Project/Site: COU-001 Job ID: 680-220017-2 Laboratory: Eurofins Savannah Narrative Job Narrative 680-220017-2 Revision 1 The report being provided is a revision of the original report sent on 8/23/2022. The report (revision 1) is being revised in order to submit revised Air Toxics report. Receipt The samples were received on 8/16/2022 9:55 AM. Unless otherwise noted below, the samples arrived in good condition. Subcontract Work Method TO-15: This method was subcontracted to Eurofins Air Toxics. The subcontract laboratory certification is different from that of the facility issuing the final report. Eurofins SavannahPage 3 of 26 8/25/2022 (Rev. 1) 1 2 3 4 5 6 Sample Summary Client: Hart & Hickman, PC Job ID: 680-220017-2 Project/Site: COU-001 Lab Sample ID Client Sample ID Matrix Collected Received 680-220017-5 OP-5 Air 08/11/22 16:40 08/16/22 09:55 680-220017-6 OP-10 Air 08/11/22 15:10 08/16/22 09:55 Eurofins SavannahPage 4 of 26 8/25/2022 (Rev. 1) 1 2 3 4 5 6 8/24/2022 Mr. David Fuller Eurofins Test America 5102 LaRoche Savannah GA 31404 Project Name: COU-001 Project #: COU-001 Dear Mr. David Fuller The following report includes the data for the above referenced project for sample(s) received on 8/16/2022 at Eurofins Air Toxics LLC. The data and associated QC analyzed by TO-15 are compliant with the project requirements or laboratory criteria with the exception of the deviations noted in the attached case narrative. Thank you for choosing Eurofins Air Toxics LLC. for your air analysis needs. Eurofins Air Toxics Inc. is committed to providing accurate data of the highest quality. Please feel free to contact the Project Manager: Brian Whittaker at 916-985-1000 if you have any questions regarding the data in this report. Regards, Brian Whittaker Project Manager Workorder #: 2208437BR1 Page 1 of 21 Page 5 of 26 8/25/2022 (Rev. 1) 1 2 3 4 5 6 Mr. David Fuller Eurofins Environment Testing 5102 LaRoche Savannah, GA 31404 WORK ORDER #: 2208437BR1 CLIENT:BILL TO: PHONE: Accounts Payable Eurofins Environment Testing 4104 Shuffel St NW North Canton, OH 44720 912-354-7858 08/16/2022 DATE COMPLETED:08/23/2022 P.O. #680-220017-2 PROJECT #COU-001 COU-001 Work Order Summary FAX: DATE RECEIVED: DATE REISSUED:08/24/2022 CONTACT:Brian Whittaker NAMEFRACTION #TEST VAC./PRES. RECEIPT PRESSURE FINAL 05A OP-5 TO-15 6.1 "Hg 9.8 psi 06A OP-10 TO-15 5.5 "Hg 9.9 psi 07A Lab Blank TO-15 NA NA 08A CCV TO-15 NA NA 09A LCS TO-15 NA NA 09AA LCSD TO-15 NA NA CERTIFIED BY: Technical Director DATE: 08/24/22 Page 2 of 21 Certification numbers: AZ Licensure AZ0775, FL NELAP – E87680, LA NELAP – 02089, NH NELAP - 209221, NJ NELAP - CA016, NY NELAP - 11291, TX NELAP - T104704434-21-17, UT NELAP – CA009332021-13, VA NELAP - 10615, WA NELAP - C935 Name of Accreditation Body: NELAP/ORELAP (Oregon Environmental Laboratory Accreditation Program) Accreditation number: CA300005-015, Effective date: 10/18/2021, Expiration date: 10/17/2022. Eurofins Air Toxics, LLC certifies that the test results contained in this report meet all requirements of the NELAC standards This report shall not be reproduced, except in full, without the written approval of Eurofins Air Toxics, LLC. 180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630 (916) 985-1000 . (800) 985-5955 . FAX (916) 351-8279 Page 6 of 26 8/25/2022 (Rev. 1) 1 2 3 4 5 6 LABORATORY NARRATIVE EPA Method TO-15 Eurofins Test America Workorder# 2208437BR1 Two 1 Liter Summa Canister samples were received on August 16, 2022. The laboratory performed analysis via EPA Method TO-15 using GC/MS in the full scan mode. There were no receiving discrepancies. Receiving Notes As per client project requirements, the laboratory has reported estimated values for target compound hits that are below the Reporting Limit but greater than the Method Detection Limit. Concentrations that are below the level at which the canister was certified may be false positives. All Quality Control Limit exceedances and affected sample results are noted by flags. Each flag is defined at the bottom of this Case Narrative and on each Sample Result Summary page. Target compound non-detects in the samples that are associated with high bias in CCV analyses have not been flagged. Due to an error at the time of project set-up, the workorder was reissued on 08/24/22 to report the additional compounds per project specifications. Analytical Notes Ten qualifiers may have been used on the data analysis sheets and indicates as follows: B - Compound present in laboratory blank greater than reporting limit (background subtraction not performed). J - Estimated value. E - Exceeds instrument calibration range. S - Saturated peak. Q - Exceeds quality control limits. U - Compound analyzed for but not detected above the reporting limit, LOD, or MDL value. See data page for project specific U-flag definition. UJ- Non-detected compound associated with low bias in the CCV N - The identification is based on presumptive evidence. M - Reported value may be biased due to apparent matrix interferences. CN - See Case Narrative. File extensions may have been used on the data analysis sheets and indicates as follows: a-File was requantified b-File was quantified by a second column and detector r1-File was requantified for the purpose of reissue Definition of Data Qualifying Flags Page 3 of 21 Page 7 of 26 8/25/2022 (Rev. 1) 1 2 3 4 5 6 Dilution Factor:Instrument/Filename:8/19/22 03:02 AM2.09msdj.i / j081825r1EPA METHOD TO-15 GC/MS FULL SCAN2208437BR1-05A8/11/22 04:40 PM1 Liter Summa CanisterCOU-001OP-5Date/Time Analyzed:Client ID:Lab ID:Date/Time Collected:Media:(ug/m3)CAS#LODCompound(ug/m3)MDLRpt. Limit(ug/m3)Amount(ug/m3)1,1,1-Trichloroethane71-55-65.71.4Not Detected3.21,1,2,2-Tetrachloroethane79-34-57.21.9Not Detected5.31,1,2-Trichloroethane79-00-55.71.2Not Detected4.21,1-Dichloroethane75-34-34.21.4Not Detected2.41,1-Dichloroethene75-35-44.12.2Not Detected3.11,2,4-Trichlorobenzene120-82-13112Not Detected261,2,4-Trimethylbenzene95-63-65.12.2Not Detected3.81,2-Dibromoethane (EDB)106-93-48.01.7Not Detected5.91,2-Dichlorobenzene95-50-16.31.5Not Detected4.61,2-Dichloroethane107-06-24.21.4Not Detected3.11,2-Dichloropropane78-87-54.81.9Not Detected3.61,3,5-Trimethylbenzene108-67-85.11.6Not Detected3.81,3-Butadiene106-99-02.31.9Not Detected2.11,3-Dichlorobenzene541-73-16.31.7Not Detected4.61,4-Dichlorobenzene106-46-76.31.5Not Detected4.61,4-Dioxane123-91-1151.6Not Detected5.62-Butanone (Methyl Ethyl Ketone)78-93-3124.033102-Hexanone591-78-6178.1Not Detected142-Propanol67-63-0103.57.7 J6.74-Ethyltoluene622-96-85.11.7Not Detected3.84-Methyl-2-pentanone108-10-14.31.3Not Detected3.2Acetone67-64-1255.2538.4alpha-Chlorotoluene100-44-75.41.4Not Detected4.0Benzene71-43-23.31.2Not Detected2.5Page 4 of 21Page 8 of 26 8/25/2022 (Rev. 1) 123456 Dilution Factor:Instrument/Filename:8/19/22 03:02 AM2.09msdj.i / j081825r1EPA METHOD TO-15 GC/MS FULL SCAN2208437BR1-05A8/11/22 04:40 PM1 Liter Summa CanisterCOU-001OP-5Date/Time Analyzed:Client ID:Lab ID:Date/Time Collected:Media:(ug/m3)CAS#LODCompound(ug/m3)MDLRpt. Limit(ug/m3)Amount(ug/m3)Bromodichloromethane75-27-47.02.0Not Detected3.9Bromoform75-25-2112.0Not Detected8.0Bromomethane74-83-9407.2Not Detected14Carbon Disulfide75-15-0134.7Not Detected11Carbon Tetrachloride56-23-56.61.3Not Detected4.9Chlorobenzene108-90-74.80.73Not Detected2.7Chloroethane75-00-3113.8Not Detected9.4Chloroform67-66-35.11.92.8 J2.8Chloromethane74-87-3224.7Not Detected7.3cis-1,2-Dichloroethene156-59-24.11.7Not Detected3.1cis-1,3-Dichloropropene10061-01-54.71.5Not Detected3.5Cyclohexane110-82-73.60.632.4 J2.7Dibromochloromethane124-48-18.91.3Not Detected6.6Ethyl Acetate141-78-6158.7Not DetectedDEthyl Benzene100-41-44.51.2Not Detected3.4Freon 1175-69-45.91.75.0 J4.3Freon 11376-13-18.01.8Not Detected5.9Freon 11476-14-27.32.5Not Detected5.4Freon 1275-71-85.22.02.7 J3.8Heptane142-82-54.31.8Not Detected3.2Hexachlorobutadiene87-68-34414Not Detected38Hexane110-54-33.71.0Not Detected2.7m,p-Xylene108-38-34.51.3Not Detected3.4Methyl tert-butyl ether1634-04-4151.9Not Detected5.6Page 5 of 21Page 9 of 26 8/25/2022 (Rev. 1) 123456 Dilution Factor:Instrument/Filename:8/19/22 03:02 AM2.09msdj.i / j081825r1EPA METHOD TO-15 GC/MS FULL SCAN2208437BR1-05A8/11/22 04:40 PM1 Liter Summa CanisterCOU-001OP-5Date/Time Analyzed:Client ID:Lab ID:Date/Time Collected:Media:(ug/m3)CAS#LODCompound(ug/m3)MDLRpt. Limit(ug/m3)Amount(ug/m3)Methylene Chloride75-09-2365.5Not Detected12Naphthalene91-20-3111.4Not Detected2.2o-Xylene95-47-64.51.4Not Detected3.4Propylene115-07-17.21.7Not Detected6.1Styrene100-42-54.41.6Not Detected3.3Tetrachloroethene127-18-47.11.81605.2Tetrahydrofuran109-99-93.11.33302.3Toluene108-88-33.90.700.86 J2.9Total Xylene1330-20-79.1NANot DetectedDtrans-1,2-Dichloroethene156-60-54.12.0Not Detected3.1trans-1,3-Dichloropropene10061-02-64.71.2Not Detected3.5Trichloroethene79-01-65.62.43.4 J4.2Vinyl Acetate108-05-4155.3Not Detected9.6Vinyl Chloride75-01-42.71.9Not Detected2.0J = Estimated value.D: Analyte not within the DoD scope of accreditation.CAS#SurrogatesLimits %Recovery1,2-Dichloroethane-d417060-07-070-1301244-Bromofluorobenzene460-00-470-130108Toluene-d82037-26-570-130103Page 6 of 21Page 10 of 26 8/25/2022 (Rev. 1) 123456 Dilution Factor:Instrument/Filename:8/19/22 03:35 AM2.05msdj.i / j081826r1EPA METHOD TO-15 GC/MS FULL SCAN2208437BR1-06A8/11/22 03:10 PM1 Liter Summa CanisterCOU-001OP-10Date/Time Analyzed:Client ID:Lab ID:Date/Time Collected:Media:(ug/m3)CAS#LODCompound(ug/m3)MDLRpt. Limit(ug/m3)Amount(ug/m3)1,1,1-Trichloroethane71-55-65.61.4Not Detected3.11,1,2,2-Tetrachloroethane79-34-57.01.8Not Detected5.21,1,2-Trichloroethane79-00-55.61.2Not Detected4.11,1-Dichloroethane75-34-34.11.4Not Detected2.31,1-Dichloroethene75-35-44.12.2Not Detected3.01,2,4-Trichlorobenzene120-82-13012Not Detected261,2,4-Trimethylbenzene95-63-65.02.2Not Detected3.71,2-Dibromoethane (EDB)106-93-47.91.7Not Detected5.81,2-Dichlorobenzene95-50-16.21.5Not Detected4.61,2-Dichloroethane107-06-24.11.4Not Detected3.11,2-Dichloropropane78-87-54.71.8Not Detected3.51,3,5-Trimethylbenzene108-67-85.01.6Not Detected3.71,3-Butadiene106-99-02.31.8Not Detected2.01,3-Dichlorobenzene541-73-16.21.7Not Detected4.61,4-Dichlorobenzene106-46-76.21.5Not Detected4.61,4-Dioxane123-91-1151.6Not Detected5.52-Butanone (Methyl Ethyl Ketone)78-93-3123.9Not Detected102-Hexanone591-78-6178.0Not Detected142-Propanol67-63-0103.4416.54-Ethyltoluene622-96-85.01.7Not Detected3.74-Methyl-2-pentanone108-10-14.21.2Not Detected3.1Acetone67-64-1245.016 J8.3alpha-Chlorotoluene100-44-75.31.3Not Detected3.9Benzene71-43-23.31.2Not Detected2.4Page 7 of 21Page 11 of 26 8/25/2022 (Rev. 1) 123456 Dilution Factor:Instrument/Filename:8/19/22 03:35 AM2.05msdj.i / j081826r1EPA METHOD TO-15 GC/MS FULL SCAN2208437BR1-06A8/11/22 03:10 PM1 Liter Summa CanisterCOU-001OP-10Date/Time Analyzed:Client ID:Lab ID:Date/Time Collected:Media:(ug/m3)CAS#LODCompound(ug/m3)MDLRpt. Limit(ug/m3)Amount(ug/m3)Bromodichloromethane75-27-46.91.9Not Detected3.8Bromoform75-25-2101.9Not Detected7.8Bromomethane74-83-9407.1Not Detected14Carbon Disulfide75-15-0134.6Not Detected11Carbon Tetrachloride56-23-56.41.3Not Detected4.8Chlorobenzene108-90-74.70.72Not Detected2.6Chloroethane75-00-3113.7Not Detected9.2Chloroform67-66-35.01.9Not Detected2.8Chloromethane74-87-3214.6Not Detected7.2cis-1,2-Dichloroethene156-59-24.11.7Not Detected3.0cis-1,3-Dichloropropene10061-01-54.61.4Not Detected3.4Cyclohexane110-82-73.50.62Not Detected2.6Dibromochloromethane124-48-18.71.2Not Detected6.5Ethyl Acetate141-78-6158.5Not DetectedDEthyl Benzene100-41-44.41.2Not Detected3.3Freon 1175-69-45.81.72.0 J4.3Freon 11376-13-17.81.8Not Detected5.8Freon 11476-14-27.22.5Not Detected5.3Freon 1275-71-85.12.02.9 J3.8Heptane142-82-54.21.8Not Detected3.1Hexachlorobutadiene87-68-34414Not Detected37Hexane110-54-33.61.0Not Detected2.7m,p-Xylene108-38-34.41.3Not Detected3.3Methyl tert-butyl ether1634-04-4151.9Not Detected5.5Page 8 of 21Page 12 of 26 8/25/2022 (Rev. 1) 123456 Dilution Factor:Instrument/Filename:8/19/22 03:35 AM2.05msdj.i / j081826r1EPA METHOD TO-15 GC/MS FULL SCAN2208437BR1-06A8/11/22 03:10 PM1 Liter Summa CanisterCOU-001OP-10Date/Time Analyzed:Client ID:Lab ID:Date/Time Collected:Media:(ug/m3)CAS#LODCompound(ug/m3)MDLRpt. Limit(ug/m3)Amount(ug/m3)Methylene Chloride75-09-2365.4Not Detected12Naphthalene91-20-3111.4Not Detected2.1o-Xylene95-47-64.41.4Not Detected3.3Propylene115-07-17.01.7Not Detected6.0Styrene100-42-54.41.6Not Detected3.2Tetrachloroethene127-18-47.01.8205.1Tetrahydrofuran109-99-93.01.32.7 J2.2Toluene108-88-33.90.690.72 J2.8Total Xylene1330-20-78.9NANot DetectedDtrans-1,2-Dichloroethene156-60-54.11.9Not Detected3.0trans-1,3-Dichloropropene10061-02-64.61.1Not Detected3.4Trichloroethene79-01-65.52.4Not Detected4.1Vinyl Acetate108-05-4145.2Not Detected9.4Vinyl Chloride75-01-42.61.9Not Detected1.9J = Estimated value.D: Analyte not within the DoD scope of accreditation.CAS#SurrogatesLimits %Recovery1,2-Dichloroethane-d417060-07-070-1301264-Bromofluorobenzene460-00-470-130102Toluene-d82037-26-570-130106Page 9 of 21Page 13 of 26 8/25/2022 (Rev. 1) 123456 Dilution Factor:Instrument/Filename:8/18/22 12:40 PM1.00msdj.i / j081805cr1EPA METHOD TO-15 GC/MS FULL SCAN2208437BR1-07ANA - Not ApplicableNA - Not ApplicableCOU-001Lab BlankDate/Time Analyzed:Client ID:Lab ID:Date/Time Collected:Media:(ug/m3)CAS#LODCompound(ug/m3)MDLRpt. Limit(ug/m3)Amount(ug/m3)1,1,1-Trichloroethane71-55-62.70.68Not Detected1.51,1,2,2-Tetrachloroethane79-34-53.40.89Not Detected2.51,1,2-Trichloroethane79-00-52.70.59Not Detected2.01,1-Dichloroethane75-34-32.00.68Not Detected1.11,1-Dichloroethene75-35-42.01.0Not Detected1.51,2,4-Trichlorobenzene120-82-1155.9Not Detected131,2,4-Trimethylbenzene95-63-62.41.0Not Detected1.81,2-Dibromoethane (EDB)106-93-43.80.81Not Detected2.81,2-Dichlorobenzene95-50-13.00.72Not Detected2.21,2-Dichloroethane107-06-22.00.68Not Detected1.51,2-Dichloropropane78-87-52.30.89Not Detected1.71,3,5-Trimethylbenzene108-67-82.40.78Not Detected1.81,3-Butadiene106-99-01.10.89Not Detected1.01,3-Dichlorobenzene541-73-13.00.84Not Detected2.21,4-Dichlorobenzene106-46-73.00.73Not Detected2.21,4-Dioxane123-91-17.20.79Not Detected2.72-Butanone (Methyl Ethyl Ketone)78-93-35.91.9Not Detected5.02-Hexanone591-78-68.23.9Not Detected7.02-Propanol67-63-04.91.7Not Detected3.24-Ethyltoluene622-96-82.40.81Not Detected1.84-Methyl-2-pentanone108-10-12.00.61Not Detected1.5Acetone67-64-1122.56.2 J4.0alpha-Chlorotoluene100-44-72.60.66Not Detected1.9Benzene71-43-21.60.56Not Detected1.2Page 10 of 21Page 14 of 26 8/25/2022 (Rev. 1) 123456 Dilution Factor:Instrument/Filename:8/18/22 12:40 PM1.00msdj.i / j081805cr1EPA METHOD TO-15 GC/MS FULL SCAN2208437BR1-07ANA - Not ApplicableNA - Not ApplicableCOU-001Lab BlankDate/Time Analyzed:Client ID:Lab ID:Date/Time Collected:Media:(ug/m3)CAS#LODCompound(ug/m3)MDLRpt. Limit(ug/m3)Amount(ug/m3)Bromodichloromethane75-27-43.40.94Not Detected1.9Bromoform75-25-25.20.94Not Detected3.8Bromomethane74-83-9193.4Not Detected6.6Carbon Disulfide75-15-06.22.2Not Detected5.3Carbon Tetrachloride56-23-53.10.62Not Detected2.3Chlorobenzene108-90-72.30.35Not Detected1.3Chloroethane75-00-35.31.8Not Detected4.5Chloroform67-66-32.40.92Not Detected1.4Chloromethane74-87-3102.2Not Detected3.5cis-1,2-Dichloroethene156-59-22.00.84Not Detected1.5cis-1,3-Dichloropropene10061-01-52.30.70Not Detected1.7Cyclohexane110-82-71.70.30Not Detected1.3Dibromochloromethane124-48-14.20.61Not Detected3.2Ethyl Acetate141-78-67.24.2Not DetectedDEthyl Benzene100-41-42.20.60Not Detected1.6Freon 1175-69-42.80.82Not Detected2.1Freon 11376-13-13.80.87Not Detected2.8Freon 11476-14-23.51.2Not Detected2.6Freon 1275-71-82.50.98Not Detected1.8Heptane142-82-52.00.87Not Detected1.5Hexachlorobutadiene87-68-3216.7Not Detected18Hexane110-54-31.80.49Not Detected1.3m,p-Xylene108-38-32.20.64Not Detected1.6Methyl tert-butyl ether1634-04-47.20.92Not Detected2.7Page 11 of 21Page 15 of 26 8/25/2022 (Rev. 1) 123456 Dilution Factor:Instrument/Filename:8/18/22 12:40 PM1.00msdj.i / j081805cr1EPA METHOD TO-15 GC/MS FULL SCAN2208437BR1-07ANA - Not ApplicableNA - Not ApplicableCOU-001Lab BlankDate/Time Analyzed:Client ID:Lab ID:Date/Time Collected:Media:(ug/m3)CAS#LODCompound(ug/m3)MDLRpt. Limit(ug/m3)Amount(ug/m3)Methylene Chloride75-09-2172.6Not Detected5.9Naphthalene91-20-35.20.66Not Detected1.0o-Xylene95-47-62.20.67Not Detected1.6Propylene115-07-13.40.82Not Detected2.9Styrene100-42-52.10.77Not Detected1.6Tetrachloroethene127-18-43.40.86Not Detected2.5Tetrahydrofuran109-99-91.50.62Not Detected1.1Toluene108-88-31.90.34Not Detected1.4Total Xylene1330-20-74.3NANot DetectedDtrans-1,2-Dichloroethene156-60-52.00.95Not Detected1.5trans-1,3-Dichloropropene10061-02-62.30.55Not Detected1.7Trichloroethene79-01-62.71.2Not Detected2.0Vinyl Acetate108-05-47.02.5Not Detected4.6Vinyl Chloride75-01-41.30.92Not Detected0.94J = Estimated value.D: Analyte not within the DoD scope of accreditation.CAS#SurrogatesLimits %Recovery1,2-Dichloroethane-d417060-07-070-1301194-Bromofluorobenzene460-00-470-13099Toluene-d82037-26-570-130100Page 12 of 21Page 16 of 26 8/25/2022 (Rev. 1) 123456 Dilution Factor:Instrument/Filename:8/18/22 10:55 AM1.00msdj.i / j081802EPA METHOD TO-15 GC/MS FULL SCAN2208437BR1-08ANA - Not ApplicableNA - Not ApplicableCOU-001CCVDate/Time Analyzed:Client ID:Lab ID:Date/Time Collected:Media:CAS#Compound%Recovery1,1,1-Trichloroethane71-55-61201,1,2,2-Tetrachloroethane79-34-5961,1,2-Trichloroethane79-00-5941,1-Dichloroethane75-34-3961,1-Dichloroethene75-35-4971,2,4-Trichlorobenzene120-82-11281,2,4-Trimethylbenzene95-63-6134 Q1,2-Dibromoethane (EDB)106-93-41031,2-Dichlorobenzene95-50-11201,2-Dichloroethane107-06-21121,2-Dichloropropane78-87-5901,3,5-Trimethylbenzene108-67-81241,3-Butadiene106-99-0901,3-Dichlorobenzene541-73-11181,4-Dichlorobenzene106-46-71221,4-Dioxane123-91-11042-Butanone (Methyl Ethyl Ketone)78-93-3982-Hexanone591-78-61052-Propanol67-63-0934-Ethyltoluene622-96-81274-Methyl-2-pentanone108-10-1104Acetone67-64-187alpha-Chlorotoluene100-44-7129Benzene71-43-292Page 13 of 21Page 17 of 26 8/25/2022 (Rev. 1) 123456 Dilution Factor:Instrument/Filename:8/18/22 10:55 AM1.00msdj.i / j081802EPA METHOD TO-15 GC/MS FULL SCAN2208437BR1-08ANA - Not ApplicableNA - Not ApplicableCOU-001CCVDate/Time Analyzed:Client ID:Lab ID:Date/Time Collected:Media:CAS#Compound%RecoveryBromodichloromethane75-27-499Bromoform75-25-2113Bromomethane74-83-9105Carbon Disulfide75-15-097Carbon Tetrachloride56-23-5124Chlorobenzene108-90-799Chloroethane75-00-394Chloroform67-66-3106Chloromethane74-87-392cis-1,2-Dichloroethene156-59-2107cis-1,3-Dichloropropene10061-01-5107Cyclohexane110-82-7110Dibromochloromethane124-48-1107Ethyl Acetate141-78-691Ethyl Benzene100-41-4110Freon 1175-69-4122Freon 11376-13-1109Freon 11476-14-2102Freon 1275-71-8117Heptane142-82-5106Hexachlorobutadiene87-68-3129Hexane110-54-3101m,p-Xylene108-38-3123Methyl tert-butyl ether1634-04-4116Page 14 of 21Page 18 of 26 8/25/2022 (Rev. 1) 123456 Dilution Factor:Instrument/Filename:8/18/22 10:55 AM1.00msdj.i / j081802EPA METHOD TO-15 GC/MS FULL SCAN2208437BR1-08ANA - Not ApplicableNA - Not ApplicableCOU-001CCVDate/Time Analyzed:Client ID:Lab ID:Date/Time Collected:Media:CAS#Compound%RecoveryMethylene Chloride75-09-291Naphthalene91-20-3122o-Xylene95-47-6122Propylene115-07-181Styrene100-42-5130Tetrachloroethene127-18-4109Tetrahydrofuran109-99-992Toluene108-88-3100Total Xylene1330-20-7122trans-1,2-Dichloroethene156-60-5102trans-1,3-Dichloropropene10061-02-6111Trichloroethene79-01-698Vinyl Acetate108-05-4107Vinyl Chloride75-01-497Q = Exceeds Quality Control limits.D: Analyte not within the DoD scope of accreditation.CAS#SurrogatesLimits %Recovery1,2-Dichloroethane-d417060-07-070-1301254-Bromofluorobenzene460-00-470-130110Toluene-d82037-26-570-130101Page 15 of 21Page 19 of 26 8/25/2022 (Rev. 1) 123456 Dilution Factor:Instrument/Filename:8/18/22 11:25 AM1.00msdj.i / j081803EPA METHOD TO-15 GC/MS FULL SCAN2208437BR1-09ANA - Not ApplicableNA - Not ApplicableCOU-001LCSDate/Time Analyzed:Client ID:Lab ID:Date/Time Collected:Media:CAS#Compound%Recovery1,1,1-Trichloroethane71-55-61191,1,2,2-Tetrachloroethane79-34-5951,1,2-Trichloroethane79-00-5971,1-Dichloroethane75-34-3951,1-Dichloroethene75-35-41031,2,4-Trichlorobenzene120-82-11271,2,4-Trimethylbenzene95-63-61261,2-Dibromoethane (EDB)106-93-41021,2-Dichlorobenzene95-50-11131,2-Dichloroethane107-06-21081,2-Dichloropropane78-87-5881,3,5-Trimethylbenzene108-67-81191,3-Butadiene106-99-0951,3-Dichlorobenzene541-73-11111,4-Dichlorobenzene106-46-71141,4-Dioxane123-91-11052-Butanone (Methyl Ethyl Ketone)78-93-31012-Hexanone591-78-61022-Propanol67-63-01014-Ethyltoluene622-96-81214-Methyl-2-pentanone108-10-1103Acetone67-64-189alpha-Chlorotoluene100-44-7122Benzene71-43-292Page 16 of 21* % Recovery is calculated using unrounded analytical results.Page 20 of 26 8/25/2022 (Rev. 1) 123456 Dilution Factor:Instrument/Filename:8/18/22 11:25 AM1.00msdj.i / j081803EPA METHOD TO-15 GC/MS FULL SCAN2208437BR1-09ANA - Not ApplicableNA - Not ApplicableCOU-001LCSDate/Time Analyzed:Client ID:Lab ID:Date/Time Collected:Media:CAS#Compound%RecoveryBromodichloromethane75-27-496Bromoform75-25-2111Bromomethane74-83-9107Carbon Disulfide75-15-099Carbon Tetrachloride56-23-5121Chlorobenzene108-90-796Chloroethane75-00-395Chloroform67-66-3100Chloromethane74-87-395cis-1,2-Dichloroethene156-59-2107cis-1,3-Dichloropropene10061-01-5107Cyclohexane110-82-7113Dibromochloromethane124-48-1104Ethyl Acetate141-78-688Ethyl Benzene100-41-4112Freon 1175-69-4118Freon 11376-13-1109Freon 11476-14-2100Freon 1275-71-8112Heptane142-82-5110Hexachlorobutadiene87-68-3126Hexane110-54-3104m,p-Xylene108-38-3118Methyl tert-butyl ether1634-04-4118Page 17 of 21* % Recovery is calculated using unrounded analytical results.Page 21 of 26 8/25/2022 (Rev. 1) 123456 Dilution Factor:Instrument/Filename:8/18/22 11:25 AM1.00msdj.i / j081803EPA METHOD TO-15 GC/MS FULL SCAN2208437BR1-09ANA - Not ApplicableNA - Not ApplicableCOU-001LCSDate/Time Analyzed:Client ID:Lab ID:Date/Time Collected:Media:CAS#Compound%RecoveryMethylene Chloride75-09-288Naphthalene91-20-3117o-Xylene95-47-6117Propylene115-07-184Styrene100-42-5123Tetrachloroethene127-18-4106Tetrahydrofuran109-99-992Toluene108-88-397Total Xylene1330-20-7118trans-1,2-Dichloroethene156-60-5104trans-1,3-Dichloropropene10061-02-6111Trichloroethene79-01-697Vinyl Acetate108-05-4125Vinyl Chloride75-01-496D: Analyte not within the DoD scope of accreditation.CAS#SurrogatesLimits %Recovery1,2-Dichloroethane-d417060-07-070-1301204-Bromofluorobenzene460-00-470-130106Toluene-d82037-26-570-130100Page 18 of 21* % Recovery is calculated using unrounded analytical results.Page 22 of 26 8/25/2022 (Rev. 1) 123456 Dilution Factor:Instrument/Filename:8/18/22 11:55 AM1.00msdj.i / j081804EPA METHOD TO-15 GC/MS FULL SCAN2208437BR1-09AANA - Not ApplicableNA - Not ApplicableCOU-001LCSDDate/Time Analyzed:Client ID:Lab ID:Date/Time Collected:Media:CAS#Compound%Recovery1,1,1-Trichloroethane71-55-61151,1,2,2-Tetrachloroethane79-34-5941,1,2-Trichloroethane79-00-5971,1-Dichloroethane75-34-3951,1-Dichloroethene75-35-41001,2,4-Trichlorobenzene120-82-11271,2,4-Trimethylbenzene95-63-61251,2-Dibromoethane (EDB)106-93-41021,2-Dichlorobenzene95-50-11121,2-Dichloroethane107-06-21051,2-Dichloropropane78-87-5871,3,5-Trimethylbenzene108-67-81181,3-Butadiene106-99-0951,3-Dichlorobenzene541-73-11101,4-Dichlorobenzene106-46-71131,4-Dioxane123-91-11042-Butanone (Methyl Ethyl Ketone)78-93-31012-Hexanone591-78-61062-Propanol67-63-01014-Ethyltoluene622-96-81204-Methyl-2-pentanone108-10-1102Acetone67-64-189alpha-Chlorotoluene100-44-7122Benzene71-43-290Page 19 of 21* % Recovery is calculated using unrounded analytical results.Page 23 of 26 8/25/2022 (Rev. 1) 123456 Dilution Factor:Instrument/Filename:8/18/22 11:55 AM1.00msdj.i / j081804EPA METHOD TO-15 GC/MS FULL SCAN2208437BR1-09AANA - Not ApplicableNA - Not ApplicableCOU-001LCSDDate/Time Analyzed:Client ID:Lab ID:Date/Time Collected:Media:CAS#Compound%RecoveryBromodichloromethane75-27-493Bromoform75-25-2110Bromomethane74-83-9107Carbon Disulfide75-15-097Carbon Tetrachloride56-23-5116Chlorobenzene108-90-797Chloroethane75-00-396Chloroform67-66-3100Chloromethane74-87-392cis-1,2-Dichloroethene156-59-2105cis-1,3-Dichloropropene10061-01-5106Cyclohexane110-82-7113Dibromochloromethane124-48-1105Ethyl Acetate141-78-688Ethyl Benzene100-41-4110Freon 1175-69-4114Freon 11376-13-1105Freon 11476-14-297Freon 1275-71-8108Heptane142-82-5109Hexachlorobutadiene87-68-3126Hexane110-54-3102m,p-Xylene108-38-3117Methyl tert-butyl ether1634-04-4119Page 20 of 21* % Recovery is calculated using unrounded analytical results.Page 24 of 26 8/25/2022 (Rev. 1) 123456 Dilution Factor:Instrument/Filename:8/18/22 11:55 AM1.00msdj.i / j081804EPA METHOD TO-15 GC/MS FULL SCAN2208437BR1-09AANA - Not ApplicableNA - Not ApplicableCOU-001LCSDDate/Time Analyzed:Client ID:Lab ID:Date/Time Collected:Media:CAS#Compound%RecoveryMethylene Chloride75-09-287Naphthalene91-20-3117o-Xylene95-47-6118Propylene115-07-182Styrene100-42-5123Tetrachloroethene127-18-4107Tetrahydrofuran109-99-990Toluene108-88-394Total Xylene1330-20-7118trans-1,2-Dichloroethene156-60-5103trans-1,3-Dichloropropene10061-02-6112Trichloroethene79-01-695Vinyl Acetate108-05-4131Vinyl Chloride75-01-497D: Analyte not within the DoD scope of accreditation.CAS#SurrogatesLimits %Recovery1,2-Dichloroethane-d417060-07-070-1301174-Bromofluorobenzene460-00-470-130105Toluene-d82037-26-570-13098Page 21 of 21* % Recovery is calculated using unrounded analytical results.Page 25 of 26 8/25/2022 (Rev. 1) 123456 Page 26 of 26 8/25/2022 (Rev. 1) 123456 Appendix E DEQ Risk Calculators Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Prepared By:Hart & Hickman Hart & Hickman Worst Case Risk Calculation North Carolina Department of Environmental Quality Risk Calculator South Tower HD Supply Site, 1414 South Tryon Street, Charlotte, NC DEQ DWM Brownfields 19054-16-060 July 2022 May 2022 EPA RSL Table North Carolina DEQ Risk Calculator Table of Contents Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 19054-16-060 Exposure Unit ID: Worst Case Risk Calculation Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 19054-16-060 Exposure Unit ID: Worst Case Risk Calculation Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Point ConcentrationsVersion Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 19054-16-060 Exposure Unit ID: Worst Case Risk Calculation Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3)Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 35.7 67-64-1 Acetone ug/m3 1.46 71-43-2 Benzene ug/m3 0.754 75-15-0 Carbon Disulfide ug/m3 3.34 67-66-3 Chloroform ug/m3 0.752 74-87-3 Chloromethane ug/m3 2.78 75-71-8 Dichlorodifluoromethane ug/m3 6.24 141-78-6 Ethyl Acetate ug/m3 0.512 142-82-5 Heptane, N-ug/m3 0.56 110-54-3 Hexane, N-ug/m3 997 67-63-0 Isopropanol ug/m3 3.52 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 0.901 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 1.15 75-09-2 Methylene Chloride ug/m3 0.738 115-07-1 Propylene ug/m3 0.439 100-42-5 Styrene ug/m3 34.9 127-18-4 Tetrachloroethylene ug/m3 5.32 108-88-3 Toluene ug/m3 0.621 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-ug/m3 0.634 79-01-6 Trichloroethylene ug/m3 1.82 75-69-4 Trichlorofluoromethane ug/m3 1.01 108-38-3 Xylene, m-ug/m3 0.473 95-47-6 Xylene, o-ug/m3 Input Form 2E Indoor Air Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion.If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Indoor Air Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 19054-16-060 Exposure Unit ID: Worst Case Risk Calculation CAS #Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 35.7 -- 71-43-2 Benzene 1.46 1.6E+00 2.6E+01 9.3E-07 1.1E-02 75-15-0 Carbon Disulfide 0.754 -6.1E+02 2.5E-04 67-66-3 Chloroform 3.34 5.3E-01 8.6E+01 6.3E-06 7.8E-0374-87-3 Chloromethane 0.752 -7.9E+01 1.9E-03 75-71-8 Dichlorodifluoromethane 2.78 -8.8E+01 6.3E-03 141-78-6 Ethyl Acetate 6.24 -6.1E+01 2.0E-02142-82-5 Heptane, N-0.512 -3.5E+02 2.9E-04 110-54-3 Hexane, N-0.56 -6.1E+02 1.8E-04 67-63-0 Isopropanol 997 -1.8E+02 1.1E+00 78-93-3 Methyl Ethyl Ketone (2-Butanone)3.52 -4.4E+03 1.6E-04108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)0.901 -2.6E+03 6.9E-05 75-09-2 Methylene Chloride 1.15 1.2E+03 5.3E+02 9.4E-10 4.4E-04 115-07-1 Propylene 0.738 -2.6E+03 5.6E-05100-42-5 Styrene 0.439 -8.8E+02 1.0E-04 127-18-4 Tetrachloroethylene 34.9 4.7E+01 3.5E+01 7.4E-07 2.0E-01 108-88-3 Toluene 5.32 -4.4E+03 2.4E-04 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-0.621 -4.4E+03 2.8E-05 79-01-6 Trichloroethylene 0.634 3.0E+00 1.8E+00 2.1E-07 7.2E-02 75-69-4 Trichlorofluoromethane 1.82 --108-38-3 Xylene, m-1.01 -8.8E+01 2.3E-03 95-47-6 Xylene, o-0.473 -8.8E+01 1.1E-03 Cumulative:8.1E-06 1.5E+00 All concentrations are in ug/m3 Output Form 3F ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 19054-16-060 Exposure Unit ID: Worst Case Risk Calculation Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air 8.1E-06 1.5E+00 YES Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 8/31/2022 Prepared By:Hart & Hickman Hart & Hickman IA & SS Worst Case Risk Calc North Carolina Department of Environmental Quality Risk Calculator HD Supply Site 1414 S. Tryon Street DWM Brownfields 19054-15-060 July 2022 May 2022 EPA RSL Table North Carolina DEQ Risk Calculator Table of Contents Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 19054-15-060 Exposure Unit ID: IA & SS Worst Case Risk Calc Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 19054-15-060 Exposure Unit ID: IA & SS Worst Case Risk Calc Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 19054-15-060 Exposure Unit ID: IA & SS Worst Case Risk Calc Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 53 OP-5 67-64-1 Acetone ug/m3 2.8 OP-5 67-66-3 Chloroform ug/m3 2.4 OP-5 110-82-7 Cyclohexane ug/m3 2.9 OP-10 75-71-8 Dichlorodifluoromethane ug/m3 330 OP-5 109-99-9 ~Tetrahydrofuran ug/m3 41 OP-10 67-63-0 Isopropanol ug/m3 33 OP-5 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 160 OP-5 127-18-4 Tetrachloroethylene ug/m3 0.86 OP-5 108-88-3 Toluene ug/m3 3.4 OP-5 79-01-6 Trichloroethylene ug/m3 5 OP-5 75-69-4 Trichlorofluoromethane ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 19054-15-060 Exposure Unit ID: IA & SS Worst Case Risk Calc Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier)Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 150 IAS-4 67-64-1 Acetone ug/m3 1.4 IAS-4 71-43-2 Benzene ug/m3 0.27 IAS-4 106-99-0 Butadiene, 1,3-ug/m3 1.8 IAS-4 75-15-0 Carbon Disulfide ug/m3 0.45 IAS-4 56-23-5 Carbon Tetrachloride ug/m3 1.4 IAS-4 67-66-3 Chloroform ug/m3 1 IAS-4 74-87-3 Chloromethane ug/m3 2.2 IAS-4 75-71-8 Dichlorodifluoromethane ug/m3 6.7 IAS-4 141-78-6 Ethyl Acetate ug/m3 0.023 IAS-4 75-00-3 Ethyl Chloride (Chloroethane)ug/m3 0.21 IAS-4 100-41-4 Ethylbenzene ug/m3 0.48 IAS-4 142-82-5 Heptane, N-ug/m3 17 IAS-4 110-54-3 Hexane, N-ug/m3 68 IAS-2 67-63-0 Isopropanol ug/m3 2.8 IAS-4 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 0.8 IAS-4 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 0.67 IAS-4 75-09-2 Methylene Chloride ug/m3 0.16 IAS-4 91-20-3 ~Naphthalene ug/m3 5.4 IAS-4 115-07-1 Propylene ug/m3 0.41 IAS-4 100-42-5 Styrene ug/m3 0.43 IAS-4 127-18-4 Tetrachloroethylene ug/m3 16 IAS-4 108-88-3 Toluene ug/m3 0.49 IAS-4 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-ug/m3 0.074 IAS-DUP 79-01-6 Trichloroethylene ug/m3 1.3 IAS-4 75-69-4 Trichlorofluoromethane ug/m3 0.46 IAS-4 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 0.28 IAS-4 95-47-6 Xylene, o-ug/m3 Input Form 2E Indoor Air Exposure Point Concentration Table Note: Chemicals highlighted in orange are non-volatile chemicals. Risks are calculated for these chemicals if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 19054-15-060 Exposure Unit ID: IA & SS Worst Case Risk Calc Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 9.8E-08 1.4E-02 NO Indoor Air 4.9E-06 1.9E-01 NO Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 19054-15-060 Exposure Unit ID: IA & SS Worst Case Risk Calc CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 53 0.53 -- 67-66-3 Chloroform 2.8 0.028 5.3E-01 8.6E+01 5.3E-08 6.5E-05 110-82-7 Cyclohexane 2.4 0.024 -5.3E+03 9.1E-07 75-71-8 Dichlorodifluoromethane 2.9 0.029 -8.8E+01 6.6E-05 109-99-9 ~Tetrahydrofuran 330 3.3 -1.8E+03 3.8E-04 67-63-0 Isopropanol 41 0.41 -1.8E+02 4.7E-0478-93-3 Methyl Ethyl Ketone (2-Butanone)33 0.33 -4.4E+03 1.5E-05127-18-4 Tetrachloroethylene 160 1.6 4.7E+01 3.5E+01 3.4E-08 9.1E-03108-88-3 Toluene 0.86 0.0086 -4.4E+03 3.9E-0779-01-6 Trichloroethylene 3.4 0.034 3.0E+00 1.8E+00 1.1E-08 3.9E-03 75-69-4 Trichlorofluoromethane 5 0.05 -- Cumulative:9.8E-08 1.4E-02 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Indoor Air Version Date: July 2022 Basis: May 2022 EPA RSL Table Site ID: 19054-15-060 Exposure Unit ID: IA & SS Worst Case Risk Calc CAS #Chemical Name: Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 150 -- 71-43-2 Benzene 1.4 1.6E+00 2.6E+01 8.9E-07 1.1E-02106-99-0 Butadiene, 1,3-0.27 4.1E-01 1.8E+00 6.6E-07 3.1E-02 75-15-0 Carbon Disulfide 1.8 -6.1E+02 5.9E-04 56-23-5 Carbon Tetrachloride 0.45 2.0E+00 8.8E+01 2.2E-07 1.0E-0367-66-3 Chloroform 1.4 5.3E-01 8.6E+01 2.6E-06 3.3E-03 74-87-3 Chloromethane 1 -7.9E+01 2.5E-03 75-71-8 Dichlorodifluoromethane 2.2 -8.8E+01 5.0E-03 141-78-6 Ethyl Acetate 6.7 -6.1E+01 2.2E-0275-00-3 Ethyl Chloride (Chloroethane)0.023 -3.5E+03 1.3E-06 100-41-4 Ethylbenzene 0.21 4.9E+00 8.8E+02 4.3E-08 4.8E-05 142-82-5 Heptane, N-0.48 -3.5E+02 2.7E-04110-54-3 Hexane, N-17 -6.1E+02 5.5E-03 67-63-0 Isopropanol 68 -1.8E+02 7.8E-02 78-93-3 Methyl Ethyl Ketone (2-Butanone)2.8 -4.4E+03 1.3E-04 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)0.8 -2.6E+03 6.1E-0575-09-2 Methylene Chloride 0.67 1.2E+03 5.3E+02 5.5E-10 2.5E-04 91-20-3 ~Naphthalene 0.16 3.6E-01 2.6E+00 4.4E-07 1.2E-02 115-07-1 Propylene 5.4 -2.6E+03 4.1E-04100-42-5 Styrene 0.41 -8.8E+02 9.4E-05 127-18-4 Tetrachloroethylene 0.43 4.7E+01 3.5E+01 9.1E-09 2.5E-03 108-88-3 Toluene 16 -4.4E+03 7.3E-04 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-0.49 -4.4E+03 2.2E-05 79-01-6 Trichloroethylene 0.074 3.0E+00 1.8E+00 2.5E-08 8.4E-03 75-69-4 Trichlorofluoromethane 1.3 --95-63-6 Trimethylbenzene, 1,2,4-0.46 -5.3E+01 1.8E-03 95-47-6 Xylene, o-0.28 -8.8E+01 6.4E-04 Cumulative:4.9E-06 1.9E-01 All concentrations are in ug/m3 Output Form 3F ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 μg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. North Carolina DEQ Risk Calculator Appendix F Safety Data Sheets (SDSs) PSW/SDS/I02 ProSpray™ wipes Page 1 of 10 Revision Date May 2015 3 Recommended Use Supplier Address Company Phone Number(s) Phone: 914-417-6022 Fax: 914-939-1864 24 Hour Emergency Telephone SAFETY DATA SHEET Issue Date May 2015 Revision Date May 2015 Version INFOTRAC: 1-352-323-3500 (International) Progressive Products, LLC. 4 International Drive Rye Brook, NY 10573 www.wipesplus.com Emergency Telephone Number INFOTRAC: 1-800-535-5053 (North America) 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier Details of the Supplier of the Safety Data Sheet Recommended Use of the Chemical and Restrictions on Use Disinfectant Towelettes. Product Name Product Number WipesPlus™ Disinfecting Wipes 37301, 33900, 33711 PSW/SDS/I02 ProSpray™ wipes Page 2 of 10 Revision Date May 2015 EPA: Caution. IF SWALLOWED: Rinse mouth and drink plenty of water. Do not induce vomiting. Never give anything by mouth to a person who is unconscious or convulsing. Call a physician or Poison Control Center immediately. IF IN EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. If irritation persists seek medical attention. comfortable for breathing. If not breathing, give artificial respiration. Immediately call a Poison Control Center or doctor/physician. Keep container tightly closed and store in a dry, cool and well-ventilated place away from incompatible materials. Keep out of the reach of children and pets. Precautionary Statements - Disposal Dispose according to all local, state and federal regulations. IF ON SKIN (or hair): Wash skin with flowing water or shower after use. Precautionary Statements - Storage Precautionary Statements-Prevention Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Do not breathe dust/fumes/gas/mist/vapors/spray. Precautionary Statements-Response IF INHALED: Remove victim to fresh air and keep at rest in a position GHS: Warning. Hazard Statements Causes eye irritation. May cause respiratory irritation. 2. HAZARDS IDENTIFICATION Classification Specific Target Organ Toxicity (Single Exposure)Category 3 Serious Eye Damage / Eye Irritation Category 2B Signal Word May cause drowsiness or dizziness. Appearance Natural Colored Pre-moistened Towelettes. Physical State Pre-moistened Towelettes. Odor Lemon. PSW/SDS/I02 ProSpray™ wipes Page 3 of 10 Revision Date May 2015 Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not Eye Contact Ingestion Skin Contact Symptoms May cause eye irritation. Inhalation may cause respiratory tract irritation. Ingestion may cause mild irritation of the mouth, esophagus and stomach. Note to Physicians 90-43-7 Unsuitable Extinguishing Media 120-32-1 As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 3. COMPOSITION/INFORMATION ON INGREDIENTS breathing, give artificial respiration. Call a physician or Poison Control Center immediately. Weight-% Protective Equipment and Precautions for Firefighters 0.07 Chemical Name o-phenylphenol Not Determined. Specific Hazards Arising from the Chemical None Known. 0.65 Indication of any Immediate Medical Attention and Special Treatment Needed First Aid Measures Most Important Symptoms and Effects, both Acute and Delayed Use water, CO2, dry chemical or foam for extinction. Control Center immediately. Treat symptomatically. Wash skin with flowing water or shower after use. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media o-benzyl-p-chlorophenol CAS No. Isopropyl Alcohol 67-63-0 1 - 6 Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. If irritation persists seek medical attention. by mouth to a person who is unconscious or convulsing. Call a physician or Poison 4. FIRST AID MEASURES Rinse mouth and drink plenty of water. Do not induce vomiting. Never give anything PSW/SDS/I02 ProSpray™ wipes Page 4 of 10 Revision Date May 2015 Conditions for Safe Storage, Including any Incompatibilities Storage Conditions Keep container tightly closed and store in a dry, cool and well-ventilated place away from Keep out of the reach of children and pets. 7. HANDLING AND STORAGE Prevent entry into waterways, sewers, basements or confined areas. Incompatible Materials Keep out of the reach of children and pets. incompatible materials. Do not store below 45°F (7°C). Do not store above 80°F (27°C). Methods for Cleaning Up Handle in accordance with good industrial hygiene and safety practice. Use personal protection recommended in Section 8. Acids. Oxidizing agents. Reducing agents. Restrict access to spill area. Ventilate the area. Environmental Precautions Methods for Containment Prevent further leakage or spillage if safe to do so. The wet, contaminated surface may be slippery. Personal Precautions, Protective Equipment and Emergency Procedures Personal Precautions Use personal protective equipment as recommended in section 8. 6. ACCIDENTAL RELEASE MEASURES See Section 12 for additional ecological information. Methods and Material for Containment and Cleaning Up For Emergency Responders Precautions for Safe Handling Advice on Safe Handling Absorb with inert material. Shovel or sweep spills. Flush remainder with plenty of water. PSW/SDS/I02 ProSpray™ wipes Page 5 of 10 Revision Date May 2015 Information on Basic Physical and Chemical Properties Physical State Appearance Color Natural Color. Odor Lemon. Handle in accordance with good industrial hygiene and safety practices. Eye/Face Protection NIOSH IDLH IDLH: 2000 ppm TWA: 400 ppm TWA: 980mg/m3 STEL: 500 ppm STEL: 1225 mg/m3 TWA: 400 ppm TWA: 980mg/m3 TWA: 400 ppm (Vacated) TWA: 980 mg/m3 (Vacated) STEL: 500 ppm (Vacated) STEL: 1225 mg/m3 (Vacated) OSHA PEL General Hygiene Considerations 9. PHYSICAL AND CHEMICAL PROPERTIES Appropriate Engineering Controls Engineering Controls Chemical resistant, impermeable gloves are not required. Respiratory Protection Under normal conditions a respirator is not normally required. A mask or respirator may be used if vapor concentration is high. 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION Exposure Guidelines STEL: 400 ppm TWA: 200 ppm Chemical Name ACGIH TLV Isopropyl Alcohol 67-63-0 Apply technical measures to comply with the occupational exposure limits. Eyewash stations. Individual Protection Measures, such as Personal Protective Equipment Natural Colored Pre-Moistened Towelettes. Wear goggles, chemical safety glasses or a face protection shield. Skin and Body Protection Pre-Moistened Towelettes. PSW/SDS/I02 ProSpray™ wipes Page 6 of 10 Revision Date May 2015 Property Values Remarks * Method pH 11.0 - 12.0 68°F (20°C) Melting Point / Freezing Point < 32°F / < 0°C Boiling Point / Boiling Range 212°F / 100°C (Approximate) Flash Point Not Flammable. Evaporation Rate < 1 (Butyl acetate = 1) (Approximate) Flammability (Solid/Gas)N/A-Liquid. Flammability Limits In Air Not Flammable. Vapor Pressure Not Determined. Vapor Density > 1 (Air = 1) (Approximate) Specific Gravity 0.99 68°F (20°C) (Water = 1) Water Solubility Completely Soluble. Partition Coefficient See Section 12. Autoignition Temperature Not Flammable. Decomposition Temperature Not Determined. Kinematic Viscosity Not Determined. Dynamic Viscosity Not Determined. Explosive Properties Not Explosive. Oxidizing Properties Not Determined. Reactivity Chemical Stability Possibility of Hazardous Reactions Hazardous Polymerization Conditions to Avoid Incompatible Materials Hazardous Decomposition Products Stable under recommended storage conditions. None known. Hazardous polymerization will not occur. Avoid direct sunlight. Avoid temperatures below 45°F / 7°C. Avoid temperatures above 80°F / 27°C. Acids. Oxidizing agents. Reducing agents. 10. STABILITY AND REACTIVITY Not reactive under normal conditions. None under normal processing. 9. PHYSICAL AND CHEMICAL PROPERTIES (continued) PSW/SDS/I02 ProSpray™ wipes Page 7 of 10 Revision Date May 2015 Information on Likely Routes of Exposure Product Information Inhalation Eye Contact Ingestion Component Information Symptoms Please see section 4 of this SDS for symptoms. ACGIH IARC NTP OSHA STOT - Single Exposure Numerical Measures of Toxicity Not Determined. Not Determined. N/A Delayed and Immediate Effects as well as Chronic Effects from Short and Long-term Exposure Avoid breathing vapors or mists. 11. TOXICOLOGICAL INFORMATION Inhalation LC50 Chemical Name Group 3 - Not Carcinogenic to Humans. 4396 mg/kg ( Rat ) Chemical Name Oral LD50 Dermal LD50 N/A Avoid contact with eyes. o-phenylphenol 90-43-7 IARC (International Agency for Research on Cancer) STOT - Repeated Exposure ACGIH (The American Conference of Governmental Industrial Hygienists) A4 - Not Classifiable as a Human Carcinogen. Not Determined. Isopropyl Alcohol 67-63-0 A4 Group 3 N/A N/A Information on Physical, Chemical and Toxicological Effects Carcinogenicity However, the product as a whole has not been tested. The table below indicates whether each agency has listed any ingredient as a carcinogen. Isopropyl Alcohol 67-63-0 Group 3 12800 mg/kg ( Rat ) Do not taste or swallow. 72.6 mg/L ( Rat ) 4 hr. N/A PSW/SDS/I02 ProSpray™ wipes Page 8 of 10 Revision Date May 2015 Ecotoxicity An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Harmful to aquatic organisms. Note DOT IATA IMDG Other Adverse Effects Toxicity to microorganisms Crustacea Known Toxin Known Toxin No Information Known Toxin Waste Treatment Methods Not Regulated. Not Regulated. Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. Not Determined. Not Determined. Bioaccumulation Not Determined. Disposal of Wastes Contaminated Packaging Dispose according to all local, state and federal regulations. Dispose according to all local, state and federal regulations. Persistence and Degradability 13. DISPOSAL CONSIDERATIONS Not Regulated. 14. TRANSPORT INFORMATION Chemical Name California Hazardous Waste Status Isopropyl Alcohol 67-63-0 Toxic / Ignitable 3.09 Chemical Name Algae/aquatic plants Fish Isopropyl Alcohol 67-63-0 o-phenylphenol 90-43-7 Known Toxin Known Toxin Known Toxin 12. ECOLOGICAL INFORMATION o-phenylphenol 90-43-7 Isopropyl Alcohol 67-63-0 0.05 Mobility Chemical Name Partition Coefficient Known Toxin PSW/SDS/I02 ProSpray™ wipes Page 9 of 10 Revision Date May 2015 Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances SARA 302 SARA 311/312 SARA 313 X X X Isopropyl Alcohol 67-63-0 o-phenylphenol 90-43-7 This product contains the following Proposition 65 chemicals. X EINECS/ELINCS - European Inventory of Existing Chemical Substances/ This material does not contain any chemical components with known CAS numbers that exceed the threshold reporting levels established by SARA Title III. Section 313. X X California Proposition 65 Chemical Name New Jersey Massachusetts Pennsylvania U.S. State Right-to-Know Regulations European List of Notified Chemical Substances US State Regulations 15. REGULATORY INFORMATION This material does not contain any chemical components with known CAS numbers that exceed the threshold reporting levels established by SARA Title III. Section 311/312. US Federal Regulations International Inventories Not Determined. This material does not contain any chemical components with known CAS numbers that exceed the threshold reporting levels established by SARA Title III. Section 302. ·Chemicals known to cause cancer: 90-43-7 biphenyl-2-ol PSW/SDS/I02 ProSpray™ wipes Page 10 of 10 Revision Date May 2015 NFPA HMIS 16. OTHER INFORMATION Health Hazards Flammability Instability Special Hazards 1 0 0 Not Determined. Health Hazards Flammability Physical Hazards Personal Protection Not Determined.Not Determined.Not Determined.Not Determined. End of Safety Data Sheet Issue Date May 2015 Revision Date Revision Note May 2015 New formula update. The information contained herein is furnished without warranty or legal responsibility of any kind. Employers should use this information only as a supplement to other information gathered by them and must make independent determination of suitability and completeness of information from all sources to assure proper use of these materials and the safety and health of employees. Disclaimer SAFETY DATA SHEET Issue date 29-May-2020 Revision Date 26-Jun-2020 Revision Number 2 1. IDENTIFICATION 1.1. Product identifier Product Code(s)FDA NDC Product Code: 74208-370 Product is sold ready to use. Synonyms Hand Sanitizer, Antiseptic hand rub Non-Sterile, IPA hand sanitizer, Isopropanol hand sanitizer Pure substance/mixture Mixture 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended use Hand Sanitizer Uses advised against Human Consumption 1.3. Details of the supplier of the safety data sheet For further information, please contact: E-mail address information@flotekind.com 1.4. Emergency telephone number Emergency telephone +1 405-282-8510 2. HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Regulation (EC) No 1272/2008 Serious eye damage/eye irritation Category 2 Specific target organ toxicity (single exposure)Category 3 2.2. Label elements Product name 70% Isopropyl Alcohol Gel Hand Sanitizer Supplier Flotek Chemistry, LLC 1004 S. Plainsman Road Marlow, OK 73055 Phone +1 (580) 658-6608 Fax +1 (580) 658-3223 Physical hazards Flammable liquids _____________________________________________________________________________________________ Page 1 / 9 Category 2 _____________________________________________________________________________________________ 70% Isopropyl Alcohol Gel Hand Sanitizer undefined Revision Date 26-Jun-2020 Signal word Danger Hazard statements H319 - Causes serious eye irritation H336 - May cause drowsiness or dizziness H225 - Highly flammable liquid and vapor Precautionary Statements - EU (§28, 1272/2008) P370 + P378 - In case of fire: Use dry sodium carbonate to extinguish P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking 2.3. Other hazards 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical name EC No CAS No Weight-%Classification according to Regulation (EC) No. 1272/2008 [CLP] REACH registration number Isopropyl alcohol 200-661-7 67-63-0 ~70 Flam. Liq. 2 (H225) STOT SE 3 (H336) Eye Irrit. 2 (H319) No data available Additional information vol/vol percentages 4. FIRST AID MEASURES Description of first aid measures General advice Show this material safety data sheet to the doctor in attendance. Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Skin contact None under normal use conditions. If severe irritation develops and persists or an allergic reaction occurs, rinse with soap and water and seek medical attention. Ingestion Do NOT induce vomiting. Call a physician or poison control center immediately. Rinse mouth. Never give anything by mouth to an unconscious person. Inhalation Remove to fresh air. If breathing is difficult, give oxygen. If symptoms persist, call a physician. _____________________________________________________________________________________________ Page 2 / 9 _____________________________________________________________________________________________ 70% Isopropyl Alcohol Gel Hand Sanitizer undefined Revision Date 26-Jun-2020 4.2. Most important symptoms and effects, both acute and delayed Main Symptoms Causes central nervous system depression. 4.3. Indication of any immediate medical attention and special treatment needed . Notes to physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES 5.1. Extinguishing media Suitable Extinguishing Media Extinguishing media - small fires. Dry chemical, CO 2, water spray or alcohol-resistant foam. Extinguishing media - large fires. Water spray, fog or alcohol-resistant foam. Extinguishing media which must not be used for safety reasons Do not use water jet. 5.2. Special hazards arising from the substance or mixture Special Hazard Extremely flammable. Will be easily ignited by heat, sparks or flames. Flash back possible over considerable distance. Vapors may form explosive mixtures with air. Cool containers with flooding quantities of water until well after fire is out. 5.3. Advice for firefighters Special protective equipment for fire-fighters As in any fire, wear self-contained breathing apparatus and full protective gear. 6. ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Keep people away from and upwind of spill/leak. Remove all sources of ignition. Stop leak if you can do it without risk. Ensure adequate ventilation. Use personal protective equipment as required. Do not touch or walk through spilled material. All equipment used when handling the product must be grounded. See Section 12 for additional information. 6.2. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary sewer system. Do not allow into any sewer, on the ground or into any body of water. 6.3. Methods and material for containment and cleaning up Dike far ahead of liquid spill for later disposal. Take precautionary measures against static discharges. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. 6.4. Reference to other sections 7. HANDLING AND STORAGE 7.1. Precautions for safe handling Ensure adequate ventilation. When transferring large amounts of the product, metal containers should be grounded. Wear personal protective equipment/face protection. Handle in accordance with good industrial hygiene and safety practice. Take precautionary measures against static discharges. 7.2. Conditions for safe storage, including any incompatibilities Keep containers tightly closed in a cool, well-ventilated place. Keep away from heat and sources of ignition. Store between 15-30C (59-86F). Avoid freezing and excessive heat above 104F. Avoid exposure to sunlight or UV light. _____________________________________________________________________________________________ Page 3 / 9 7.3. Specific end use(s) _____________________________________________________________________________________________ 70% Isopropyl Alcohol Gel Hand Sanitizer undefined Revision Date 26-Jun-2020 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Exposure Guidelines Chemical name ACGIH TLV OSHA PEL NIOSH IDLH Isopropyl alcohol 67-63-0 STEL: 400 ppm TWA: 200 ppm TWA: 400 ppm TWA: 980 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 980 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 1225 mg/m3 IDLH: 2000 ppm TWA: 400 ppm TWA: 980 mg/m3 STEL: 500 ppm STEL: 1225 mg/m3 NIOSH IDLH: Immediately Dangerous to Life or Health Exposure limits Chemical name European Union United Kingdom France Spain Germany Isopropyl alcohol 67-63-0 -STEL: 500 ppm STEL: 1250 mg/m3 TWA: 400 ppm TWA: 999 mg/m3 STEL: 400 ppm STEL: 980 mg/m3 TWA: 200 ppm TWA: 500 mg/m3 STEL: 400 ppm STEL: 1000 mg/m3 TWA: 200 ppm TWA: 500 mg/m3 Ceiling / Peak: 400 ppm Ceiling / Peak: 1000 mg/m3 Component Italy Portugal Netherlands Finland Denmark Isopropyl alcohol 67-63-0 ( ~70 ) TWA: 200 ppm STEL: 400 ppm TWA: 200 ppm 8hr, 500 mg/m3 8hr TWA: 200 ppm TWA: 500 mg/m3 STEL: 250 ppm STEL: 620 mg/m3 TWA: 200 ppm TWA: 490 mg/m3 Chemical name Austria Switzerland Poland Norway Ireland Isopropyl alcohol 67-63-0 STEL 800 ppm STEL 2000 mg/m3 TWA: 200 ppm TWA: 500 mg/m3 STEL: 400 ppm STEL: 1000 mg/m3 TWA: 200 ppm TWA: 500 mg/m3 TWA: 900 mg/m3 STEL: 1200 mg/m3 TWA: 100 ppm TWA: 245 mg/m3 STEL: 125 ppm STEL: 306.25 mg/m3 TWA: 200 ppm STEL: 400 ppm Sk* Derived No Effect Level (DNEL)No information available Predicted No Effect Concentration (PNEC)No information available 8.2. Exposure controls Engineering Measures Ensure that eyewash stations and safety showers are close to the workstation location. Personal protective equipment Eye Protection None under normal use conditions. If splashes are likely to occur, wear: tightly fitting safety goggles or face-shield, as appropriate. Hand Protection None under normal use conditions. If submerged for long periods of time, wear butyl or nitrile rubber gloves. Skin and body protection None under normal use conditions. Wear suitable protective clothing. Respiratory protection None under normal use conditions. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. Hygiene measures Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing before re-use. Environmental Exposure Controls The product should not be allowed to enter drains, water courses or the soil. 9. Physical and chemical properties _____________________________________________________________________________________________ Page 4 / 9 _____________________________________________________________________________________________ 70% Isopropyl Alcohol Gel Hand Sanitizer undefined Revision Date 26-Jun-2020 9.1. Information on basic physical and chemical properties Physical State gel Appearance clear Color colorless Odor Alcohol. Odor Threshold No information available Explosive properties No information available Oxidizing properties No information available 9.2. Other information Softening point No information available Molecular Weight No information available VOC Content (%)No information available Liquid Density 7.04-7.54 lb/gal Bulk density No information available 10. STABILITY AND REACTIVITY 10.1. Reactivity No data available. 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions Heat (temperatures above flash point), sparks, ignition points, flames, static electricity. Strong oxidizing agents. 10.5. Incompatible materials Strong oxidizing agents. Chlorine. Acids. Isocyanates. Acetaldehyde. Ethylene Oxide. Strong reducing agents. Strong bases. Hazardous Decomposition Products None under normal use conditions. 11. TOXICOLOGICAL INFORMATION 11.1. Information on toxicological effects Acute toxicity Product Information Property Values Remarks • Method pH 6.1 - 9.1 neat Melting point / freezing point -28.8 Boiling point / boiling range No data available None known Flash point 22 °C CC (closed cup) Evaporation rate No data available None known Flammability (solid, gas)No data available None known Flammability Limit in Air None known Upper flammability or explosive limits No data available Lower flammability or explosive limits No data available Vapor pressure No data available None known Vapor density No data available None known Relative density 0.844 - 0.904 Water solubility Soluble in water None known Solubility in other solvents No data available None known Partition coefficient: n-octanol/waterNo data available None known Autoignition temperature No data available None known Decomposition temperature No data available None known Kinematic viscosity No data available None known Viscosity, dynamic No data available None known _____________________________________________________________________________________________ Page 5 / 9 _____________________________________________________________________________________________ 70% Isopropyl Alcohol Gel Hand Sanitizer undefined Revision Date 26-Jun-2020 Inhalation None under normal use conditions. Close exposure to large open volumes or huffing vapors may cause adverse effects. Inhalation of vapors is irritating to the respiratory system, may cause throat pain and cough. May cause central nervous system depression with nausea, headache, dizziness, vomiting, and incoordination. Eye contact Avoid contact with eyes. Severely irritating to eyes. Skin contact None under normal use conditions. Substance may cause slight skin irritation. Ingestion None under normal use conditions. Not an expected route of exposure. Harmful if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. May cause adverse cardiac effects. May cause central nervous system depression. May cause drowsiness or dizziness. May cause adverse kidney effects. Chemical name Oral LD50 Dermal LD50 Inhalation LC50 Isopropyl alcohol = 1870 mg/kg ( Rat )12800 mg/kg ( Rat ) 12870 mg/kg ( Rabbit ) 8.00 mL/kg, 6280 mg/kg ( Rabbit ) = 72600 mg/m3 ( Rat ) 4 h Chronic toxicity Sensitization No information available Target organ effects Central nervous system. 12. ECOLOGICAL INFORMATION 12.1. Toxicity Ecotoxicity The environmental impact of this product has not been fully investigated. Low order of toxicity based on components. Chemical name Algae/aquatic plants Fish Toxicity to microorganisms Crustacea Isopropyl alcohol 1000: 72 h Desmodesmus subspicatus mg/L EC50 1000: 96 h Desmodesmus subspicatus mg/L EC50 9640: 96 h Pimephales promelas mg/L LC50 flow-through 11130: 96 h Pimephales promelas mg/L LC50 static 1400000: 96 h Lepomis macrochirus µg/L LC50 -EC50: =13299mg/L (48h, Daphnia magna) 12.2. Persistence and degradability No information available. 12.3. Bioaccumulative potential No information available. Chemical name Partition coefficient Isopropyl alcohol 0.05 12.4. Mobility in soil No information available. 12.5. Results of PBT and vPvB assessment No information available 12.6. Other adverse effects 13. DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste from Residues/Unused Products Dispose of in accordance with local regulations. _____________________________________________________________________________________________ Page 6 / 9 _____________________________________________________________________________________________ 70% Isopropyl Alcohol Gel Hand Sanitizer undefined Revision Date 26-Jun-2020 Contaminated packaging Do not reuse empty containers. EWC Waste Disposal No According to the European Waste Catalog, Waste Codes are not product specific, but application specific Waste codes should be assigned by the user based on the application for which the product was used 14. TRANSPORT INFORMATION DOT Proper shipping name UN1219, Isopropanol Solution, 3, PG ll Hazard class 3 UN/ID no UN1219 Packing Group PG ll 15. REGULATORY INFORMATION International Inventories TSCA Complies EINECS/ELINCS - DSL/NDSL Complies PICCS - ENCS - IECSC - AICS - KECL - Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List PICCS - Philippines Inventory of Chemicals and Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances AICS - Australian Inventory of Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances 15.2. Chemical safety assessment Chemical Safety Report US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical name CAS No Weight-%SARA 313 - Threshold Values % Isopropyl alcohol 67-63-0 ~70 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard Yes Fire hazard Yes _____________________________________________________________________________________________ Page 7 / 9 _____________________________________________________________________________________________ 70% Isopropyl Alcohol Gel Hand Sanitizer undefined Revision Date 26-Jun-2020 Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR Chemical name WHMIS Hazard Class Isopropyl alcohol 1 % B2,D2B Chemical name NPRI Isopropyl alcohol X Legend NPRI - National Pollutant Release Inventory 16. OTHER INFORMATION Full text of H-Statements referred to under sections 2 and 3 H319 - Causes serious eye irritation H336 - May cause drowsiness or dizziness H225 - Highly flammable liquid and vapor Key or legend to abbreviations and acronyms used in the safety data sheet Legend Issue date 29-May-2020 Revision Date 26-Jun-2020 Revision Note Not applicable. This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. US Only: This safety data sheet complies with the requirements of the OSHA Hazard Communication Standard 29 CFR NFPA Health hazards 2 Flammability 3 Stability 0 Physical and chemical properties - HMIS Health hazards 2 Flammability 3 Physical hazards 0 Personal protection -. _____________________________________________________________________________________________ Page 8 / 9 _____________________________________________________________________________________________ 70% Isopropyl Alcohol Gel Hand Sanitizer undefined Revision Date 26-Jun-2020 1910.1200. Disclaimer While the information and data contained herein are presented in good faith and believed to be reliable, nothing herein shall be deemed to constitute a warranty, express or implied, that the information or data is reliable, accurate, or complete or that the products or services described herein are merchantable or fit for a particular purpose or that said information, data, products, or services can be used without infringing the intellectual property rights of third parties. Individuals who receive the products, services, information or data relating to the products or services described herein, must use their own judgment in determining fitness for a particular purpose. Unless otherwise stated, the information or data contained herein relates to the products or services when not used in conjunction with any other products, services, or materials. All express and implied warranties of merchantability, fitness for a particular purpose, and non-infringement are hereby disclaimed. There shall be no liability for (i) any loss or damage that may occur from the use of the products or services described herein, including the use of the products or services in conjunction with other products, services, or materials; or (ii) any loss or damage that may occur from the reliance on the data or information described herein. _____________________________________________________________________________________________ Page 9 / 9 SAFETY DATA SHEET PURELL® Advanced Hand Sanitizer Sanitizing Gel Version 1.0 SDS Number: 400000005869 Revision Date: 04/21/2020 1 / 10 SECTION 1. IDENTIFICATION Product name : PURELL® Advanced Hand Sanitizer Sanitizing Gel Manufacturer or supplier's details Company name of supplier : GOJO Industries, Inc. Address : One GOJO Plaza, Suite 500 Akron, Ohio 44311 Telephone : 1 (330) 255-6000 Emergency telephone number : CHEMTREC 1-800-424-9300 CHEMTREC +1-703-527-3887: Outside USA & CANADA Recommended use of the chemical and restrictions on use Recommended use : Hand Sanitizer Restrictions on use : This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet. SECTION 2. HAZARDS IDENTIFICATION GHS Classification Flammable liquids : Category 3 Eye irritation : Category 2A GHS label elements Hazard pictograms : Signal word : Warning Hazard statements : H226 Flammable liquid and vapour. H319 Causes serious eye irritation. Precautionary statements : Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P233 Keep container tightly closed. SAFETY DATA SHEET PURELL® Advanced Hand Sanitizer Sanitizing Gel Version 1.0 SDS Number: 400000005869 Revision Date: 04/21/2020 2 / 10 P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P280 Wear eye protection/ face protection. Response: P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. Storage: P403 + P235 Store in a well-ventilated place. Keep cool. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components Chemical name CAS-No. Concentration (%) Ethyl Alcohol 64-17-5 >= 60 - < 70 SECTION 4. FIRST AID MEASURES General advice : In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice. If inhaled : If inhaled, remove to fresh air. If symptoms persist, call a physician. In case of skin contact : Wash with water and soap as a precaution. Get medical attention if irritation develops and persists. In case of eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn. Seek medical advice. If swallowed : If swallowed, DO NOT induce vomiting. Rinse mouth with water. Obtain medical attention. Most important symptoms and effects, both acute and delayed : Causes serious eye irritation. Protection of first-aiders : First Aid responders should pay attention to self-protection and use the recommended protective clothing SECTION 5. FIREFIGHTING MEASURES SAFETY DATA SHEET PURELL® Advanced Hand Sanitizer Sanitizing Gel Version 1.0 SDS Number: 400000005869 Revision Date: 04/21/2020 3 / 10 Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Unsuitable extinguishing media : High volume water jet Specific hazards during firefighting : Do not use a solid water stream as it may scatter and spread fire. Cool closed containers exposed to fire with water spray. Flash back possible over considerable distance. May form explosive mixtures in air. Exposure to decomposition products may be a hazard to health. Carbon oxides Hazardous combustion products : Carbon oxides Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Use personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Material can create slippery conditions. Environmental precautions : Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for containment and cleaning up : Non-sparking tools should be used. Soak up with inert absorbent material. Suppress (knock down) gases/vapours/mists with a water spray jet. Keep in suitable, closed containers for disposal. Clean contaminated floors and objects thoroughly while observing environmental regulations. SECTION 7. HANDLING AND STORAGE Advice on safe handling : For personal protection see section 8. Keep away from heat. Use with local exhaust ventilation. Avoid contact with eyes. SAFETY DATA SHEET PURELL® Advanced Hand Sanitizer Sanitizing Gel Version 1.0 SDS Number: 400000005869 Revision Date: 04/21/2020 4 / 10 Conditions for safe storage : Take measures to prevent the build up of electrostatic charge. Keep in properly labelled containers. Keep container tightly closed in a dry and well-ventilated place. Store in accordance with the particular national regulations. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis Ethyl Alcohol 64-17-5 TWA 1,000 ppm 1,900 mg/m3 NIOSH REL TWA 1,000 ppm 1,900 mg/m3 OSHA Z-1 STEL 1,000 ppm ACGIH Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally required. Hand protection Remarks : No special protective equipment required. Eye protection : Wear face-shield and protective suit for abnormal processing problems. Skin and body protection : No special protective equipment required. Protective measures : Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place. Ensure that eye flushing systems and safety showers are located close to the working place. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : gel Colour : clear, colourless, yellow Odour : citrus Odour Threshold : No data available pH : 6.5 - 8.5, (20 °C) Melting point/freezing point : No data available Initial boiling point and boiling range : 70 °C Flash point : 25 °C Evaporation rate : No data available Flammability (solid, gas) : Not applicable Flammability (liquids) : No data available SAFETY DATA SHEET PURELL® Advanced Hand Sanitizer Sanitizing Gel Version 1.0 SDS Number: 400000005869 Revision Date: 04/21/2020 5 / 10 Upper explosion limit : No data available Lower explosion limit : No data available Vapour pressure : No data available Relative vapour density : No data available Density : 0.87 g/cm3 Solubility(ies) Water solubility : soluble Partition coefficient: n- octanol/water : Not applicable Auto-ignition temperature : not determined Thermal decomposition : The substance or mixture is not classified self-reactive. Viscosity Viscosity, kinematic : 3500 - 23000 mm2/s (20 °C) Explosive properties : Not explosive Oxidizing properties : The substance or mixture is not classified as oxidizing. SECTION 10. STABILITY AND REACTIVITY Reactivity : Not classified as a reactivity hazard. Chemical stability : Stable under normal conditions. Possibility of hazardous reactions : Vapours may form explosive mixture with air. Conditions to avoid : Heat, flames and sparks. Incompatible materials : Oxidizing agents Hazardous decomposition products : No hazardous decomposition products are known. SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Eye contact Skin contact Acute toxicity Not classified based on available information. Components: Ethyl Alcohol: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): 124.7 mg/l SAFETY DATA SHEET PURELL® Advanced Hand Sanitizer Sanitizing Gel Version 1.0 SDS Number: 400000005869 Revision Date: 04/21/2020 6 / 10 Exposure time: 4 h Test atmosphere: vapour Skin corrosion/irritation Not classified based on available information. Components: Ethyl Alcohol: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation Serious eye damage/eye irritation Causes serious eye irritation. Components: Ethyl Alcohol: Species: Rabbit Result: Irritation to eyes, reversing within 21 days Method: OECD Test Guideline 405 Respiratory or skin sensitisation Skin sensitisation: Not classified based on available information. Respiratory sensitisation: Not classified based on available information. Components: Ethyl Alcohol: Test Type: Local lymph node assay (LLNA) Exposure routes: Skin contact Species: Mouse Result: negative Germ cell mutagenicity Not classified based on available information. Components: Ethyl Alcohol: Genotoxicity in vitro : Test Type: In vitro mammalian cell gene mutation test Result: negative Genotoxicity in vivo : Test Type: Rodent dominant lethal test (germ cell) (in vivo) Test species: Mouse Application Route: Ingestion Result: negative Carcinogenicity Not classified based on available information. IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential SAFETY DATA SHEET PURELL® Advanced Hand Sanitizer Sanitizing Gel Version 1.0 SDS Number: 400000005869 Revision Date: 04/21/2020 7 / 10 carcinogen by OSHA. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity Not classified based on available information. Components: Ethyl Alcohol: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Mouse Application Route: Ingestion Method: OECD Test Guideline 416 Result: negative STOT - single exposure Not classified based on available information. STOT - repeated exposure Not classified based on available information. Repeated dose toxicity Components: Ethyl Alcohol: Species: Rat NOAEL: 2,400 mg/kg Application Route: Ingestion Exposure time: 2 y Aspiration toxicity Not classified based on available information. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Components: Ethyl Alcohol: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): > 1,000 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 1,000 mg/l Exposure time: 48 h Toxicity to algae : EC50 (Chlorella vulgaris (Fresh water algae)): 275 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Daphnia magna (Water flea)): 9.6 mg/l Exposure time: 9 d SAFETY DATA SHEET PURELL® Advanced Hand Sanitizer Sanitizing Gel Version 1.0 SDS Number: 400000005869 Revision Date: 04/21/2020 8 / 10 Toxicity to bacteria : EC50 (Photobacterium phosphoreum): 32.1 mg/l Exposure time: 0.25 h Persistence and degradability Components: Ethyl Alcohol: Biodegradability : Result: Readily biodegradable. Biodegradation: 84 % Exposure time: 20 d Bioaccumulative potential Components: Ethyl Alcohol: Partition coefficient: n- octanol/water : log Pow: -0.35 Mobility in soil No data available Other adverse effects No data available Product: Regulation 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances Remarks This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of in accordance with local regulations. Contaminated packaging : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. SECTION 14. TRANSPORT INFORMATION International Regulation IATA-DGR UN/ID No. : UN 1170 Proper shipping name : Ethanol solution Class : 3 Packing group : III Packing instruction (cargo aircraft) : 366 Packing instruction (passenger aircraft) : 355 SAFETY DATA SHEET PURELL® Advanced Hand Sanitizer Sanitizing Gel Version 1.0 SDS Number: 400000005869 Revision Date: 04/21/2020 9 / 10 IMDG-Code UN number : UN 1170 Proper shipping name : ETHANOL SOLUTION Class : 3 Packing group : III Labels : 3 EmS Code : F-E, S-D Marine pollutant : no National Regulations 49 CFR UN/ID/NA number : UN 1170 Proper shipping name : Ethanol solutions Class : 3 Packing group : III ERG Code : 127 Marine pollutant : no SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act SARA 311/312 Hazards : Fire Hazard Acute Health Hazard SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Clean Air Act This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489): Ethyl Alcohol 64-17-5 65.2815 % This product does not contain any VOC exemptions listed under the U.S. Clean Air Act Section 450. Clean Water Act This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307 California Prop 65 This product does not require a warning label under California Proposition 65. The components of this product are reported in the following inventories: TSCA : On TSCA Inventory SAFETY DATA SHEET PURELL® Advanced Hand Sanitizer Sanitizing Gel Version 1.0 SDS Number: 400000005869 Revision Date: 04/21/2020 10 / 10 AICS : On the inventory, or in compliance with the inventory DSL : On the inventory, or in compliance with the inventory ENCS : On the inventory, or in compliance with the inventory ISHL : On the inventory, or in compliance with the inventory KECI : On the inventory, or in compliance with the inventory PICCS : On the inventory, or in compliance with the inventory IECSC : On the inventory, or in compliance with the inventory NZIoC : On the inventory, or in compliance with the inventory Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA) SECTION 16. OTHER INFORMATION Further information NFPA: HMIS III: Revision Date : 04/21/2020 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Flammability Health Instability 2 3 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 3 0 2 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic SAFETY DATA SHEET CLEANSHOT STAINLESS STEEL POLISH 914455-01 1 / 8 Section: 1. PRODUCT AND COMPANY IDENTIFICATION Product name : CLEANSHOT STAINLESS STEEL POLISH Other means of identification : Not applicable. Recommended use : Metal polish Restrictions on use : Reserved for industrial and professional use. Product dilution information : Product is sold ready to use. Company : Ecolab New Zealand 2 Daniel Place Te Rapa, Hamilton New Zealand +64 7 958 2319 Emergency telephone number : 0800 243 622 (0800 CHEMCALL) Issuing date : 05.03.2018 Section: 2. HAZARDS IDENTIFICATION HSNO Hazard classification Flammable Liquids : 3.1 D Acute toxicity (Oral) : 6.1 E Specific Target Organ Systemic Toxicity (Single Exposure or Repeated Exposure) (Oral) : 6.9 B Specific Target Organ Systemic Toxicity (Single Exposure or Repeated Exposure) (Inhalation) : 6.9 B Aquatic toxicity (Acute or Chronic) : 9.1 D Ecotoxic to terrestrial invertebrates : 9.4 C GHS Label element Hazard pictograms : Signal Word : Danger Hazard Statements : Combustible liquid May be fatal if swallowed and enters airways. May cause damage to organs if swallowed. May cause damage to organs if inhaled. Toxic to aquatic life. Harmful to terrestrial invertebrates. Precautionary Statements : Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. SAFETY DATA SHEET CLEANSHOT STAINLESS STEEL POLISH 914455-01 2 / 8 Do not breathe dust/fume/gas/mist/vapours/spray. Wash skin thoroughly after handling. Do not eat, drink or smoke when using this product. Avoid release to the environment. Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. IF exposed or if you feel unwell: Call a POISON CENTER or doctor/ physician. Do NOT induce vomiting. Storage: Store in a well-ventilated place. Keep cool. Store locked up. Disposal: Dispose of contents/ container to an approved waste disposal plant. Other hazards : None known. Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS Pure substance/mixture : Mixture Chemical Name CAS-No. Concentration: (%) white mineral oil, petroleum 8042-47-5 30 - 60 naphtha (petroleum), hydrotreated heavy 64742-48-9 30 - 60 Siloxane, dimethyl 63148-62-9 0.1 - 1 Section: 4. FIRST AID MEASURES In case of eye contact : Rinse with plenty of water. In case of skin contact : Rinse with plenty of water. If swallowed : Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Aspiration hazard if swallowed - can enter lungs and cause damage. Get medical attention immediately. If inhaled : Get medical attention if symptoms occur. Protection of first-aiders : No special precautions are necessary for first aid responders. Notes to physician : Treat symptomatically. Most important symptoms and effects, both acute and delayed : See Section 11 for more detailed information on health effects and symptoms. Section: 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media : High volume water jet Specific hazards during firefighting : Fire Hazard Keep away from heat and sources of ignition. Flash back possible over considerable distance. Hazardous combustion : Decomposition products may include the following materials: SAFETY DATA SHEET CLEANSHOT STAINLESS STEEL POLISH 914455-01 3 / 8 products Carbon oxides Special protective equipment for firefighters : Use personal protective equipment. Specific extinguishing methods : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. Section: 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Remove all sources of ignition. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. Environmental precautions : Do not allow contact with soil, surface or ground water. Methods and materials for containment and cleaning up : Eliminate all ignition sources if safe to do so. Stop leak if safe to do so. Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Do not flush into surface water or sanitary sewer system. Emergency Management Trigger Levels The following triger level applies: Emergency Plan : 10,000 L Signage : 10,000 L Section: 7. HANDLING AND STORAGE Advice on safe handling : Keep away from fire, sparks and heated surfaces. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). Wash hands thoroughly after handling. Conditions for safe storage : Keep away from heat and sources of ignition. Keep away from oxidizing agents. Keep out of reach of children. Keep container tightly closed. Store in suitable labeled containers. Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Form of exposure Permissible concentration Basis white mineral oil, petroleum 8042-47-5 WES-TWA (Mist) 5 mg/m3 NZ OEL WES-STEL (Mist) 10 mg/m3 NZ OEL naphtha (petroleum), hydrotreated heavy 64742-48-9 WES-TWA 300 ppm 890 mg/m3 NZ OEL WES-STEL 500 ppm NZ OEL SAFETY DATA SHEET CLEANSHOT STAINLESS STEEL POLISH 914455-01 4 / 8 1,480 mg/m3 Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards. Personal protective equipment Eye protection : Safety goggles Face-shield Hand protection : Wear the following personal protective equipment: Standard glove type. Nitrile Neoprene gloves Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. Skin protection : Personal protective equipment comprising: suitable protective gloves, safety goggles and protective clothing Respiratory protection : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Refer to AS/NZS 1715 and AS/NZS 1716 for selection, use and maintenance of respiratory protective equipment as applicable. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash face, hands and any exposed skin thoroughly after handling. Section: 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Colour : clear, colourless Odour : hydrocarbon-like pH : Not applicable. Flash point : 90 °C closed cup, Sustains combustion Odour Threshold : no data available Melting point/freezing point : no data available Initial boiling point and boiling range : no data available Evaporation rate : no data available Flammability (solid, gas) : no data available Upper explosion limit : no data available Lower explosion limit : no data available Vapour pressure : no data available Relative vapour density : no data available Relative density : 0.8 - 0.81 Water solubility : insoluble Solubility in other solvents : no data available SAFETY DATA SHEET CLEANSHOT STAINLESS STEEL POLISH 914455-01 5 / 8 Partition coefficient: n- octanol/water : no data available Auto-ignition temperature : no data available Thermal decomposition : no data available Viscosity, kinematic : no data available Explosive properties : no data available Oxidizing properties : The substance or mixture is not classified as oxidizing. Molecular weight : no data available VOC : no data available Section: 10. STABILITY AND REACTIVITY Chemical stability : Stable under normal conditions. Possibility of hazardous reactions : No dangerous reaction known under conditions of normal use. Conditions to avoid : Heat, flames and sparks. Incompatible materials : None known. Hazardous decomposition products : Decomposition products may include the following materials: Carbon oxides Section: 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation, Eye contact, Skin contact Potential Health Effects Eyes : Health injuries are not known or expected under normal use. Skin : Health injuries are not known or expected under normal use. Ingestion : May be fatal if swallowed and enters airways. Inhalation : Health injuries are not known or expected under normal use. Chronic Exposure : May cause damage to organs. Experience with human exposure Eye contact : No symptoms known or expected. Skin contact : No symptoms known or expected. Ingestion : Vomiting Inhalation : No symptoms known or expected. Toxicity Product SAFETY DATA SHEET CLEANSHOT STAINLESS STEEL POLISH 914455-01 6 / 8 Acute oral toxicity : no data available Acute inhalation toxicity : 4 h Acute toxicity estimate : > 10 mg/l Test atmosphere: dust/mist Acute dermal toxicity : Acute toxicity estimate : > 5,000 mg/kg Skin corrosion/irritation : no data available Serious eye damage/eye irritation : no data available Respiratory or skin sensitization : no data available Carcinogenicity : no data available Reproductive effects : no data available Germ cell mutagenicity : no data available Teratogenicity : no data available STOT - single exposure : no data available STOT - repeated exposure : no data available Aspiration toxicity : no data available Components Acute oral toxicity : white mineral oil, petroleum LD50 rat: > 5,000 mg/kg naphtha (petroleum), hydrotreated heavy LD50 rat: > 5,000 mg/kg Siloxane, dimethyl LD50 rat: > 5,000 mg/kg Section: 12. ECOLOGICAL INFORMATION Ecotoxicity Environmental Effects : Toxic to aquatic life. Product Toxicity to fish : no data available Toxicity to daphnia and other aquatic invertebrates : no data available Toxicity to algae : no data available Components Toxicity to fish : white mineral oil, petroleum 96 h LC50 Oncorhynchus mykiss (rainbow trout): > 100 mg/l Siloxane, dimethyl 96 h LC50 Fish: 38 mg/l Persistence and degradability Biodegradable Bioaccumulative potential SAFETY DATA SHEET CLEANSHOT STAINLESS STEEL POLISH 914455-01 7 / 8 no data available Mobility in soil no data available Other adverse effects no data available Section: 13. DISPOSAL CONSIDERATIONS Disposal methods : Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. The product should not be allowed to enter drains, water courses or the soil. Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re- use empty containers. Dispose of in accordance with local, state, and federal regulations. Section: 14. TRANSPORT INFORMATION The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (NZ_DG) Not dangerous goods Sea transport (IMDG/IMO) Not dangerous goods Special precautions for user : None Section: 15. REGULATORY INFORMATION HSNO Approval Number : HSR002525 HSNO Group Standard : Cleaning Products (Combustible) Group Standard 2006. The components of this product are reported in the following inventories: United States TSCA Inventory : On the inventory, or in compliance with the inventory Canadian Domestic Substances List (DSL) : All components of this product are on the Canadian DSL. Australia. Industrial Chemical (Notification and Assessment) Act : On the inventory, or in compliance with the inventory New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand : On the inventory, or in compliance with the inventory SAFETY DATA SHEET CLEANSHOT STAINLESS STEEL POLISH 914455-01 8 / 8 Japan. ENCS - Existing and New Chemical Substances Inventory : not determined Korea. Korean Existing Chemicals Inventory (KECI) : On the inventory, or in compliance with the inventory Philippines Inventory of Chemicals and Chemical Substances (PICCS) : On the inventory, or in compliance with the inventory China Inventory of Existing Chemical Substances : On the inventory, or in compliance with the inventory Taiwan Chemical Substance Inventory : On the inventory, or in compliance with the inventory Section: 16. OTHER INFORMATION Issuing date : 05.03.2018 Version : 1.0 Prepared by : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. SAFETY DATA SHEET OASIS 137 ORANGE FORCE 905215 1 / 10 1. SECTION: PRODUCT AND COMPANY IDENTIFICATION Product name : 橘勁 137 OASIS 137 ORANGE FORCE Other means of identification : Not applicable Recommended use : All Purpose Cleaner Restrictions on use : Reserved for industrial and professional use. Product dilution information : 0.0 % - 12.5 % Company : Ecolab Limited 10F., No.172, Sec.4, Chengde Rd., Shilin Dist., Taipei, Taiwan 111 (02) 8978-1234 Emergency telephone : 00801-14-8954 (Taiwan) 1-651-222-5352 (United States) Issuing date : 2022.02.20 2. SECTION: HAZARDS IDENTIFICATION GHS Classification Product AS SOLD Serious eye damage/eye irritation : Category 2B Skin sensitization : Category 1 Short-term (acute) aquatic hazard : Category 3 Long-term (chronic) aquatic hazard : Category 3 Product AT USE DILUTION Short-term (acute) aquatic hazard : Category 3 GHS label elements Product AS SOLD Hazard pictograms : Signal Word : Warning Hazard Statements : May cause an allergic skin reaction. Causes eye irritation. Harmful to aquatic life with long lasting effects. Precautionary Statements : Prevention: Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. Wash skin thoroughly after handling. Contaminated work clothing should not be SAFETY DATA SHEET OASIS 137 ORANGE FORCE 905215 2 / 10 allowed out of the workplace. Avoid release to the environment. Wear protective gloves. Response: IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation or rash occurs: Get medical advice/ attention. Wash contaminated clothing before reuse. Disposal: Dispose of contents/ container to an approved waste disposal plant. Product AT USE DILUTION Hazard Statements : Harmful to aquatic life. Precautionary Statements : Prevention: Avoid release to the environment. Disposal: Dispose of contents/ container to an approved waste disposal plant. Product AS SOLD Other hazards : None known. 3. SECTION: COMPOSITION/INFORMATION ON INGREDIENTS Product AS SOLD Pure substance/mixture : Mixture Chemical name CAS-No. Concentration (%) Dodecylbenzenesulfonic acid, sodium salt 25155-30-0 5 - 10 Alkylphenol ethoxylates 9004-78-8 1 - 5 Sodium poly(oxyethylene) dodecyl ether sulfate 68585-34-2 1 - 5 Dodecylbenzenesulphonic acid, compound with 2,2',2''-nitrilotriethanol (1:1) 27323-41-7 1 - 5 Limonene 5989-27-5 1 - 5 Product AT USE DILUTION No hazardous ingredients 4. SECTION: FIRST AID MEASURES First aid measures for different exposure routes Product AS SOLD In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention. In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention. If swallowed : Rinse mouth. Get medical attention if symptoms occur. If inhaled : Get medical attention if symptoms occur. Protection of first-aiders : If potential for exposure exists refer to Section 8 for specific personal protective equipment. SAFETY DATA SHEET OASIS 137 ORANGE FORCE 905215 3 / 10 Notes to physician : Treat symptomatically. Most important symptoms and effects, both acute and delayed : See Section 11 for more detailed information on health effects and symptoms. Product AT USE DILUTION In case of eye contact : Rinse with plenty of water. In case of skin contact : Rinse with plenty of water. If swallowed : Rinse mouth. Get medical attention if symptoms occur. If inhaled : Get medical attention if symptoms occur. 5. SECTION: FIRE-FIGHTING MEASURES Product AS SOLD Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media : None known. Specific hazards during fire fighting : Not flammable or combustible. Hazardous combustion products : Decomposition products may include the following materials: Carbon oxides Nitrogen oxides (NOx) Sulfur oxides Oxides of phosphorus Special protective equipment for fire-fighters : Use personal protective equipment. Specific extinguishing methods : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. 6. SECTION: ACCIDENTAL RELEASE MEASURES Product AS SOLD Personal precautions, protective equipment and emergency procedures : Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. Environmental precautions : Do not allow contact with soil, surface or ground water. Methods and materials for containment and cleaning up : Stop leak if safe to do so. Contain spillage, and then collect with non- combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Product AT USE DILUTION Personal precautions, : Ensure clean-up is conducted by trained personnel only. Refer to SAFETY DATA SHEET OASIS 137 ORANGE FORCE 905215 4 / 10 protective equipment and emergency procedures protective measures listed in sections 7 and 8. Environmental precautions : Do not allow contact with soil, surface or ground water. Methods and materials for containment and cleaning up : Stop leak if safe to do so. Contain spillage, and then collect with non- combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. 7. SECTION: HANDLING AND STORAGE Product AS SOLD Advice on safe handling : Avoid contact with skin and eyes. Wash hands thoroughly after handling. Do not get in eyes, on skin, or on clothing. In case of mechanical malfunction, or if in contact with unknown dilution of product, wear full Personal Protective Equipment (PPE). Conditions for safe storage : Keep out of reach of children. Keep container tightly closed. Store in suitable labeled containers. Storage temperature : 0 °C to 50 °C Product AT USE DILUTION Advice on safe handling : Wash hands thoroughly after handling. In case of mechanical malfunction, or if in contact with unknown dilution of product, wear full Personal Protective Equipment (PPE). Conditions for safe storage : Keep out of reach of children. Keep container tightly closed. Store in suitable labeled containers. 8. SECTION: EXPOSURE CONTROLS/PERSONAL PROTECTION Product AS SOLD Ingredients with workplace control parameters Contains no substances with occupational exposure limit values. Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards. Personal protective equipment Eye protection : Safety goggles Face-shield Hand protection : Wear the following personal protective equipment: Standard glove type. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. Skin protection : Personal protective equipment comprising: suitable protective gloves, safety goggles and protective clothing Respiratory protection : No personal respiratory protective equipment normally required. Hygiene measures : Handle in accordance with good industrial hygiene and safety SAFETY DATA SHEET OASIS 137 ORANGE FORCE 905215 5 / 10 practice. Remove and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling. Product AT USE DILUTION Engineering measures : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Personal protective equipment Eye protection : No special protective equipment required. Hand protection : No special protective equipment required. Skin protection : No special protective equipment required. Respiratory protection : No personal respiratory protective equipment normally required. 9. SECTION: PHYSICAL AND CHEMICAL PROPERTIES Product AS SOLD Product AT USE DILUTION Appearance : liquid liquid Color : clear, dark orange light orange Odor : citrus citrus pH : 7.2 - 9.0, (100 %) 8.0 - 8.5 Flash point : Not applicable Odor Threshold : No data available Melting point/freezing point : No data available Initial boiling point and boiling range : No data available Evaporation rate : No data available Flammability (solid, gas) : Not applicable Upper explosion limit : No data available Lower explosion limit : No data available Vapor pressure : No data available Relative vapor density : No data available Relative density : 1.006 - 1.036 Water solubility : No data available Solubility in other solvents : No data available Partition coefficient: n- octanol/water : No data available Autoignition temperature : No data available Thermal decomposition : No data available Viscosity, kinematic : No data available Explosive properties : No data available Oxidizing properties : No data available Molecular weight : No data available SAFETY DATA SHEET OASIS 137 ORANGE FORCE 905215 6 / 10 VOC : No data available 10. SECTION: STABILITY AND REACTIVITY Product AS SOLD Reactivity : No dangerous reaction known under conditions of normal use. Chemical stability : Stable under normal conditions. Possibility of hazardous reactions : No dangerous reaction known under conditions of normal use. Conditions to avoid : None known. Incompatible materials : None known. Hazardous decomposition products : In case of fire hazardous decomposition products may be produced such as: Carbon oxides Nitrogen oxides (NOx) Sulfur oxides Oxides of phosphorus 11. SECTION: TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation, Eye contact, Skin contact Potential Health Effects Product AS SOLD Eyes : Causes serious eye irritation. Skin : May cause allergic skin reaction. Ingestion : Health injuries are not known or expected under normal use. Inhalation : Health injuries are not known or expected under normal use. Chronic Exposure : May cause cancer. Product AT USE DILUTION Eyes : Health injuries are not known or expected under normal use. Skin : Health injuries are not known or expected under normal use. Ingestion : Health injuries are not known or expected under normal use. Inhalation : Health injuries are not known or expected under normal use. Chronic Exposure : Health injuries are not known or expected under normal use. Experience with human exposure Product AS SOLD Eye contact : Redness, Pain, Irritation Skin contact : Allergic reactions SAFETY DATA SHEET OASIS 137 ORANGE FORCE 905215 7 / 10 Redness, Irritation, Allergic reactions Ingestion : No symptoms known or expected. Inhalation : No symptoms known or expected. Product AT USE DILUTION Eye contact : No symptoms known or expected. Skin contact : No symptoms known or expected. Ingestion : No symptoms known or expected. Inhalation : No symptoms known or expected. Toxicity Product AS SOLD Product Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg Acute inhalation toxicity : No data available Acute dermal toxicity : No data available Skin corrosion/irritation : No skin irritation Serious eye damage/eye irritation : Mild eye irritation Respiratory or skin sensitization : No data available Carcinogenicity : Not classifiable as a human carcinogen. Reproductive effects : No data available Germ cell mutagenicity : No data available Teratogenicity : No data available STOT-single exposure : No data available STOT-repeated exposure : No data available Aspiration toxicity : No data available Components Acute dermal toxicity : Sodium poly(oxyethylene) dodecyl ether sulfate LD50 Rat: > 2,000 mg/kg Limonene LD50 Rabbit: > 5,000 mg/kg 12. SECTION: ECOLOGICAL INFORMATION Ecotoxicity Product AS SOLD Environmental Effects : Harmful to aquatic life with long lasting effects. Product AT USE DILUTION Environmental Effects : Harmful to aquatic life. SAFETY DATA SHEET OASIS 137 ORANGE FORCE 905215 8 / 10 Product AS SOLD Product Toxicity to fish : 96 h LC50: 31.9 mg/l Toxicity to daphnia and other aquatic invertebrates : No data available Toxicity to algae : No data available Components Toxicity to daphnia and other aquatic invertebrates : Limonene 48 h EC50 Daphnia magna (Water flea): 0.307 mg/l Components Toxicity to algae : Limonene 72 h EC50 Pseudokirchneriella subcapitata (algae): 0.32 mg/l Persistence and degradability Biodegradable Biodegradable Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects No data available 13. SECTION: DISPOSAL CONSIDERATIONS Product AS SOLD Disposal methods : Do not contaminate storm water drains, natural waterways or soil with chemical or used container. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re- use empty containers. Dispose of in accordance with local, state, and federal regulations. Product AT USE DILUTION Disposal methods : Do not contaminate storm water drains, natural waterways or soil with chemical or used container. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re- use empty containers. Dispose of in accordance with local, state, and federal regulations. 14. SECTION: TRANSPORT INFORMATION SAFETY DATA SHEET OASIS 137 ORANGE FORCE 905215 9 / 10 Product AS SOLD The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport Not dangerous goods Sea transport (IMDG/IMO) Not dangerous goods Special precautions for user : None 15. SECTION: REGULATORY INFORMATION National regulatory information Regulations on Labelling and Hazard Communication of Hazardous Chemicals National regulatory information Regulations on Occupational Safety and Health Facilities National regulatory information Standards for the Storage, Cleanup, Handling and Disposal of Industrial Waste National regulatory information Standards of Permissible Exposure Limits in Job Site National regulatory information Regulations on Labelling and Hazard Communication of Hazardous Chemicals National regulatory information Regulations on Occupational Safety and Health Facilities National regulatory information Standards for the Storage, Cleanup, Handling and Disposal of Industrial Waste The ingredients of this product are reported in the following inventories: United States TSCA Inventory : All substances listed as active on the TSCA inventory Canadian Domestic Substances List (DSL) : This product contains one or several components listed in the Canadian NDSL. Australia. Australian Industrial Chemicals Introduction Scheme (AICIS) : not determined New Zealand. Inventory of Chemical Substances : not determined Japan. ENCS - Existing and New Chemical Substances Inventory : not determined Korea. Korean Existing Chemicals Inventory (KECI) : On the inventory, or in compliance with the inventory SAFETY DATA SHEET OASIS 137 ORANGE FORCE 905215 10 / 10 Philippines Inventory of Chemicals and Chemical Substances (PICCS) : On the inventory, or in compliance with the inventory China. Inventory of Existing Chemical Substances in China (IECSC) : On the inventory, or in compliance with the inventory Taiwan Chemical Substance Inventory (TCSI) : not determined 16. SECTION: OTHER INFORMATION Sources of key data used to compile the Safety Data Sheet Globally Harmonized System of Classification and Labeling of Chemicals (GHS) IARC: (International Agency for Research on Cancer) US. National Toxicology Program (NTP) Report on Carcinogens ECHA List of Publishable Substances Registered EU HPVCs (High Production Volume Chemicals) Issuing date : 2022.02.20 Date of first issue : 2020.06.16 Version : 1.6 Prepared by : Regulatory Affairs Local contact : Ecolab Limited Address : 10F., No.172, Sec.4, Chengde Rd., Shilin Dist., Taipei, Taiwan 111 Telephone : (02) 8978-1234 Name : Regulatory Specialist Position : Regulatory Specialist REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. SAFETY DATA SHEET 66 HEAVY DUTY ALKALINE BATHROOM CLEANER AND DISINFECTANT 910772 1 / 11 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : 66 HEAVY DUTY ALKALINE BATHROOM CLEANER AND DISINFECTANT Other means of identification : Not applicable Recommended use : Disinfectant Restrictions on use : Reserved for industrial and professional use. Product dilution information : 0.39 % - 10.94 % Company : Ecolab Inc. 1 Ecolab Place St. Paul, Minnesota USA 55102 1-800-352-5326 Emergency health information : 1-800-328-0026 (US/Canada), 1-651-222-5352 (outside US) Issuing date : 05/09/2019 SECTION 2. HAZARDS IDENTIFICATION GHS Classification Product AS SOLD Acute toxicity (Inhalation) : Category 4 Serious eye damage : Category 1 Product AT USE DILUTION Eye irritation : Category 2B GHS label elements Product AS SOLD Hazard pictograms : Signal Word : Danger Hazard Statements : Causes serious eye damage. Harmful if inhaled. Precautionary Statements : Prevention: Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. Use only outdoors or in a well-ventilated area. Wear eye protection/ face protection. Do not get in eyes, on skin, or on clothing. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. SAFETY DATA SHEET 66 HEAVY DUTY ALKALINE BATHROOM CLEANER AND DISINFECTANT 910772 2 / 11 Product AT USE DILUTION Hazard Statements : Causes eye irritation. Precautionary Statements : Prevention: Wash skin thoroughly after handling. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention. Product AS SOLD Other hazards : None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Product AS SOLD Pure substance/mixture : Mixture Chemical name CAS-No. Concentration (%) ethylenediamine tetraacetate 64-02-8 10 - 30 poly(oxy-1,2-ethanediyl), .alpha.-undecyl-.omega.- hydroxy- 34398-01-1 1 - 5 n-alkyl (C14 50%; C12 40%; C16 10%) dimethyl benzyl ammonium chloride 68424-85-1 2.48 acetic acid, (ethylenedinitrilo)tetra-, trisodium salt 150-38-9 1 - 5 Didecyl Dimethyl Ammonium Chloride 7173-51-5 0.52 Product AT USE DILUTION Chemical name CAS-No. Concentration (%) ethylenediamine tetraacetate 64-02-8 1 - 5 Alkyl (C14, 50%; C12, 40%; C16, 10%) dimethyl benzyl ammonium chloride 68424-85-1 0.2713 Didecyl Dimethyl Ammonium Chloride 7173-51-5 0.0568 SECTION 4. FIRST AID MEASURES Product AS SOLD In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately. In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Get medical attention if irritation develops and persists. If swallowed : Rinse mouth. Get medical attention if symptoms occur. If inhaled : Remove to fresh air. Treat symptomatically. Get medical attention. Protection of first-aiders : If potential for exposure exists refer to Section 8 for specific personal protective equipment. Notes to physician : Treat symptomatically. Most important symptoms and effects, both acute and delayed : See Section 11 for more detailed information on health effects and symptoms. SAFETY DATA SHEET 66 HEAVY DUTY ALKALINE BATHROOM CLEANER AND DISINFECTANT 910772 3 / 11 Product AT USE DILUTION In case of eye contact : Rinse with plenty of water. In case of skin contact : Rinse with plenty of water. If swallowed : Rinse mouth. Get medical attention if symptoms occur. If inhaled : Get medical attention if symptoms occur. SECTION 5. FIRE-FIGHTING MEASURES Product AS SOLD Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media : None known. Specific hazards during fire fighting : Not flammable or combustible. Hazardous combustion products : Decomposition products may include the following materials: Carbon oxides Nitrogen oxides (NOx) Special protective equipment for fire-fighters : Use personal protective equipment. Specific extinguishing methods : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. SECTION 6. ACCIDENTAL RELEASE MEASURES Product AS SOLD Personal precautions, protective equipment and emergency procedures : Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Avoid inhalation, ingestion and contact with skin and eyes. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. Environmental precautions : Do not allow contact with soil, surface or ground water. Methods and materials for containment and cleaning up : Stop leak if safe to do so. Contain spillage, and then collect with non- combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Product AT USE DILUTION Personal precautions, protective equipment and emergency procedures : Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. SAFETY DATA SHEET 66 HEAVY DUTY ALKALINE BATHROOM CLEANER AND DISINFECTANT 910772 4 / 11 Environmental precautions : Do not allow contact with soil, surface or ground water. Methods and materials for containment and cleaning up : Stop leak if safe to do so. Contain spillage, and then collect with non- combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. SECTION 7. HANDLING AND STORAGE Product AS SOLD Advice on safe handling : Do not get in eyes, on skin, or on clothing. Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. Use only with adequate ventilation. Wash hands thoroughly after handling. In case of mechanical malfunction, or if in contact with unknown dilution of product, wear full Personal Protective Equipment (PPE). Conditions for safe storage : Keep out of reach of children. Store in suitable labeled containers. Storage temperature : 0 °C to 50 °C Product AT USE DILUTION Advice on safe handling : Wash hands thoroughly after handling. Conditions for safe storage : Keep out of reach of children. Store in suitable labeled containers. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Product AS SOLD Ingredients with workplace control parameters Contains no substances with occupational exposure limit values. Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards. Personal protective equipment Eye protection : Wear eye protection/ face protection. Hand protection : Wear the following personal protective equipment: Standard glove type. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. Skin protection : No special protective equipment required. Respiratory protection : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash face, hands and any exposed skin thoroughly after handling. Provide suitable facilities for quick drenching or flushing of the eyes and body in case of contact or splash hazard. Product AT USE DILUTION Engineering measures : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. SAFETY DATA SHEET 66 HEAVY DUTY ALKALINE BATHROOM CLEANER AND DISINFECTANT 910772 5 / 11 Personal protective equipment Eye protection : No special protective equipment required. Hand protection : No special protective equipment required. Skin protection : No special protective equipment required. Respiratory protection : No personal respiratory protective equipment normally required. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Product AS SOLD Product AT USE DILUTION Appearance : liquid liquid Color : red light red Odor : Floral Floral pH : 7.5 - 10.5, (100 %) 8.5 - 11.0 Flash point : Not applicable, Does not sustain combustion. Odor Threshold : No data available Melting point/freezing point : No data available Initial boiling point and boiling range : No data available Evaporation rate : No data available Flammability (solid, gas) : No data available Upper explosion limit : No data available Lower explosion limit : No data available Vapor pressure : No data available Relative vapor density : No data available Relative density : 1.102 Water solubility : No data available Solubility in other solvents : No data available Partition coefficient: n- octanol/water : No data available Autoignition temperature : No data available Thermal decomposition : No data available Viscosity, kinematic : No data available Explosive properties : No data available Oxidizing properties : The substance or mixture is not classified as oxidizing. Molecular weight : No data available VOC : No data available SECTION 10. STABILITY AND REACTIVITY Product AS SOLD Reactivity : No dangerous reaction known under conditions of normal use. SAFETY DATA SHEET 66 HEAVY DUTY ALKALINE BATHROOM CLEANER AND DISINFECTANT 910772 6 / 11 Chemical stability : Stable under normal conditions. Possibility of hazardous reactions : No dangerous reaction known under conditions of normal use. Conditions to avoid : None known. Incompatible materials : None known. Hazardous decomposition products : Decomposition products may include the following materials: Carbon oxides Nitrogen oxides (NOx) SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation, Eye contact, Skin contact Potential Health Effects Product AS SOLD Eyes : Causes serious eye damage. Skin : Health injuries are not known or expected under normal use. Ingestion : Health injuries are not known or expected under normal use. Inhalation : Harmful if inhaled. Chronic Exposure : Health injuries are not known or expected under normal use. Product AT USE DILUTION Eyes : Causes eye irritation. Skin : Health injuries are not known or expected under normal use. Ingestion : Health injuries are not known or expected under normal use. Inhalation : Health injuries are not known or expected under normal use. Chronic Exposure : Health injuries are not known or expected under normal use. Experience with human exposure Product AS SOLD Eye contact : Redness, Pain, Corrosion Skin contact : No symptoms known or expected. Ingestion : No symptoms known or expected. Inhalation : No information available. Product AT USE DILUTION Eye contact : Redness, Irritation Skin contact : No symptoms known or expected. SAFETY DATA SHEET 66 HEAVY DUTY ALKALINE BATHROOM CLEANER AND DISINFECTANT 910772 7 / 11 Ingestion : No symptoms known or expected. Inhalation : No symptoms known or expected. Toxicity Product AS SOLD Product Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg Acute inhalation toxicity : Acute toxicity estimate : 1.1 - 5 mg/l Test substance: Product Test atmosphere: dust/mist Acute dermal toxicity : Acute toxicity estimate : > 5,000 mg/kg Skin corrosion/irritation : No skin irritation Test substance:Product Serious eye damage/eye irritation : Irreversible effects on the eye Test substance: Product Respiratory or skin sensitization : No data available Carcinogenicity : No data available Reproductive effects : No data available Germ cell mutagenicity : No data available Teratogenicity : No data available STOT-single exposure : No data available STOT-repeated exposure : No data available Aspiration toxicity : No data available SECTION 12. ECOLOGICAL INFORMATION Product AS SOLD Ecotoxicity Environmental Effects : Very toxic to aquatic life. Harmful to aquatic life with long lasting effects. Product Toxicity to fish : No data available Toxicity to daphnia and other aquatic invertebrates : No data available Toxicity to algae : No data available Components Toxicity to fish : ethylenediamine tetraacetate 96 h LC50 Fish: 121 mg/l poly(oxy-1,2-ethanediyl), .alpha.-undecyl-.omega.-hydroxy- 96 h LC50 Pimephales promelas: 5.5 mg/l Didecyl Dimethyl Ammonium Chloride 96 h LC50 Fish: 1 mg/l Components SAFETY DATA SHEET 66 HEAVY DUTY ALKALINE BATHROOM CLEANER AND DISINFECTANT 910772 8 / 11 Toxicity to daphnia and other aquatic invertebrates : poly(oxy-1,2-ethanediyl), .alpha.-undecyl-.omega.-hydroxy- 48 h EC50 Daphnia magna (Water flea): 5.5 mg/l n-alkyl (C14 50%; C12 40%; C16 10%) dimethyl benzyl ammonium chloride 48 h EC50 Daphnia magna (Water flea): 0.016 mg/l Components Toxicity to algae : poly(oxy-1,2-ethanediyl), .alpha.-undecyl-.omega.-hydroxy- 96 h EC50: 5.5 mg/l Persistence and degradability Product AS SOLD Not applicable - Biocide Product AT USE DILUTION Not applicable - Biocide Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Product AS SOLD Disposal methods : Do not contaminate ponds, waterways or ditches with chemical or used container. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re- use empty containers. Dispose of in accordance with local, state, and federal regulations. Product AT USE DILUTION Disposal methods : Do not contaminate ponds, waterways or ditches with chemical or used container. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re- use empty containers. Dispose of in accordance with local, state, and federal regulations. SECTION 14. TRANSPORT INFORMATION Product AS SOLD SAFETY DATA SHEET 66 HEAVY DUTY ALKALINE BATHROOM CLEANER AND DISINFECTANT 910772 9 / 11 The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (DOT) Not dangerous goods Sea transport (IMDG/IMO) UN number : 3082 Description of the goods : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (quaternary ammonium compound) Class : 9 Packing group : III Marine pollutant : yes SECTION 15. REGULATORY INFORMATION Product AS SOLD EPA Registration number : 1677-202 EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Acute toxicity (any route of exposure) Serious eye damage or eye irritation SARA 302 : This material does not contain any components with a section 302 EHS TPQ. SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. California Prop. 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. California Cleaning Product Right to Know Act of 2017 (SB 258) This regulation applies to this product. Chemical Name CAS-No. Function List(s) water 7732-18-5 Diluent Not Applicable ethylenediamine tetraacetate 64-02-8 Cleaning Agent Not Applicable poly(oxy-1,2-ethanediyl), .alpha.- undecyl-.omega.-hydroxy- 34398-01-1 Cleaning Agent Not Applicable n-alkyl (C14 50%; C12 40%; C16 10%) dimethyl benzyl ammonium chloride 68424-85-1 Biocide Not Applicable Didecyl Dimethyl Ammonium Chloride 7173-51-5 Biocide Not Applicable SAFETY DATA SHEET 66 HEAVY DUTY ALKALINE BATHROOM CLEANER AND DISINFECTANT 910772 10 / 11 Fragrance Ingredient(s) Not Available Fragrance Not Applicable Colorant Withheld Dye Not Applicable Organic salt Withheld Cleaning Agent Not Applicable acetic acid, (ethylenedinitrilo)tetra-, trisodium salt 150-38-9 Cleaning Agent Not Applicable *refer to ecolab.com/sds for electronic links to designated lists The ingredients of this product are reported in the following inventories: Switzerland. New notified substances and declared preparations : The mixture contains substances listed on the Swiss Inventory United States TSCA Inventory : All substances listed as active on the TSCA inventory Canadian Domestic Substances List (DSL) : All components of this product are on the Canadian DSL Australia Inventory of Chemical Substances (AICS) : not determined New Zealand. Inventory of Chemical Substances : not determined Japan. ENCS - Existing and New Chemical Substances Inventory : not determined Korea. Korean Existing Chemicals Inventory (KECI) : not determined Philippines Inventory of Chemicals and Chemical Substances (PICCS) : not determined China. Inventory of Existing Chemical Substances in China (IECSC) : not determined Taiwan Chemical Substance Inventory (TCSI) : not determined SECTION 16. OTHER INFORMATION Product AS SOLD NFPA: HMIS III: Flammability Health Instability 3 0 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 0 0 3 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic SAFETY DATA SHEET 66 HEAVY DUTY ALKALINE BATHROOM CLEANER AND DISINFECTANT 910772 11 / 11 Product AT USE DILUTION NFPA: HMIS III: Issuing date : 05/09/2019 Version : 1.8 Prepared by : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Flammability Health Instability 1 0 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 0 0 1 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic SAFETY DATA SHEET OASIS 146 MULTI-QUAT SANITIZER 910787 1 / 12 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : OASIS 146 MULTI-QUAT SANITIZER Other means of identification : Not applicable Recommended use : Sanitizer Restrictions on use : Reserved for industrial and professional use. Product dilution information : 0.2 % - 3.125 % Company : Ecolab Inc. 1 Ecolab Place St. Paul, Minnesota USA 55102 1-800-352-5326 Emergency health information : 1-800-328-0026 (US/Canada), 1-651-222-5352 (outside US) Issuing date : 02/04/2020 SECTION 2. HAZARDS IDENTIFICATION GHS Classification Product AS SOLD Acute toxicity (Oral) : Category 4 Skin corrosion : Category 1A Serious eye damage : Category 1 Product AT USE DILUTION Eye irritation : Category 2B GHS label elements Product AS SOLD Hazard pictograms : Signal Word : Danger Hazard Statements : Harmful if swallowed. Causes severe skin burns and eye damage. Precautionary Statements : Prevention: Wash skin thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. IF IN EYES: Rinse cautiously with water for SAFETY DATA SHEET OASIS 146 MULTI-QUAT SANITIZER 910787 2 / 12 several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. Wash contaminated clothing before reuse. Storage: Store locked up. Disposal: Dispose of contents/ container to an approved waste disposal plant. Product AT USE DILUTION Signal Word : Warning Hazard Statements : Causes eye irritation. Precautionary Statements : Prevention: Wash skin thoroughly after handling. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention. Product AS SOLD Other hazards : None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Product AS SOLD Pure substance/mixture : Mixture Chemical name CAS-No. Concentration (%) Alkyl (50% C14, 40% C12, 10% C16) dimethyl benzyl ammonium chloride 68424-85-1 3 Octyl decyl dimethyl ammonium chloride 32426-11-2 2.25 ethanol 64-17-5 1 - 5 Didecyl Dimethyl Ammonium Chloride 7173-51-5 1.35 Dioctyl dimethyl ammonium chloride 5538-94-3 0.9 Product AT USE DILUTION Chemical name CAS-No. Concentration (%) Alkyl (50% C14, 40% C12, 10% C16) dimethyl benzyl ammonium chloride 68424-85-1 0.0938 Octyl decyl dimethyl ammonium chloride 32426-11-2 0.0703 Didecyl Dimethyl Ammonium Chloride 7173-51-5 0.0421 Dioctyl dimethyl ammonium chloride 5538-94-3 0.0201 SECTION 4. FIRST AID MEASURES Product AS SOLD In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately. In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately. If swallowed : Rinse mouth with water. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention immediately. SAFETY DATA SHEET OASIS 146 MULTI-QUAT SANITIZER 910787 3 / 12 If inhaled : Remove to fresh air. Treat symptomatically. Get medical attention if symptoms occur. Protection of first-aiders : If potential for exposure exists refer to Section 8 for specific personal protective equipment. Notes to physician : Treat symptomatically. Most important symptoms and effects, both acute and delayed : See Section 11 for more detailed information on health effects and symptoms. Product AT USE DILUTION In case of eye contact : Rinse with plenty of water. In case of skin contact : Rinse with plenty of water. If swallowed : Rinse mouth. Get medical attention if symptoms occur. If inhaled : Get medical attention if symptoms occur. SECTION 5. FIRE-FIGHTING MEASURES Product AS SOLD Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media : None known. Specific hazards during fire fighting : Not flammable or combustible. Hazardous combustion products : Decomposition products may include the following materials: Carbon oxides Nitrogen oxides (NOx) Special protective equipment for fire-fighters : Use personal protective equipment. Specific extinguishing methods : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. SECTION 6. ACCIDENTAL RELEASE MEASURES Product AS SOLD Personal precautions, protective equipment and emergency procedures : Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Avoid inhalation, ingestion and contact with skin and eyes. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. Environmental precautions : Do not allow contact with soil, surface or ground water. SAFETY DATA SHEET OASIS 146 MULTI-QUAT SANITIZER 910787 4 / 12 Methods and materials for containment and cleaning up : Stop leak if safe to do so. Contain spillage, and then collect with non- combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Product AT USE DILUTION Personal precautions, protective equipment and emergency procedures : Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. Environmental precautions : Do not allow contact with soil, surface or ground water. Methods and materials for containment and cleaning up : Stop leak if safe to do so. Contain spillage, and then collect with non- combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. SECTION 7. HANDLING AND STORAGE Product AS SOLD Advice on safe handling : Do not ingest. Do not get in eyes, on skin, or on clothing. Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. Use only with adequate ventilation. Wash hands thoroughly after handling. In case of mechanical malfunction, or if in contact with unknown dilution of product, wear full Personal Protective Equipment (PPE). Conditions for safe storage : Keep out of reach of children. Store in suitable labeled containers. Storage temperature : 0 °C to 50 °C Product AT USE DILUTION Advice on safe handling : Wash hands thoroughly after handling. In case of mechanical malfunction, or if in contact with unknown dilution of product, wear full Personal Protective Equipment (PPE). Conditions for safe storage : Keep out of reach of children. Store in suitable labeled containers. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Product AS SOLD Ingredients with workplace control parameters Components CAS-No. Form of exposure Permissible concentration Basis ethanol 64-17-5 TWA 1,000 ppm 1,900 mg/m3 NIOSH REL TWA 1,000 ppm 1,900 mg/m3 OSHA Z1 Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards. Personal protective equipment SAFETY DATA SHEET OASIS 146 MULTI-QUAT SANITIZER 910787 5 / 12 Eye protection : Wear eye protection/ face protection. Hand protection : Wear the following personal protective equipment: Standard glove type. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. Skin protection : Personal protective equipment comprising: suitable protective gloves, safety goggles and protective clothing Respiratory protection : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling. Provide suitable facilities for quick drenching or flushing of the eyes and body in case of contact or splash hazard. Product AT USE DILUTION Engineering measures : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Personal protective equipment Eye protection : No special protective equipment required. Hand protection : No special protective equipment required. Skin protection : No special protective equipment required. Respiratory protection : No personal respiratory protective equipment normally required. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Product AS SOLD Product AT USE DILUTION Appearance : liquid liquid Color : red light red Odor : Disinfectants Disinfectants pH : 7.7, (100 %) 6.0 - 9.0 Flash point : Not applicable Odor Threshold : No data available Melting point/freezing point : No data available Initial boiling point and boiling range : 100 °C Evaporation rate : No data available Flammability (solid, gas) : Not applicable Upper explosion limit : No data available Lower explosion limit : No data available Vapor pressure : No data available Relative vapor density : No data available SAFETY DATA SHEET OASIS 146 MULTI-QUAT SANITIZER 910787 6 / 12 Relative density : 0.998 Water solubility : soluble Solubility in other solvents : No data available Partition coefficient: n- octanol/water : No data available Autoignition temperature : No data available Thermal decomposition : No data available Viscosity, kinematic : No data available Explosive properties : No data available Oxidizing properties : No data available Molecular weight : No data available VOC : No data available SECTION 10. STABILITY AND REACTIVITY Product AS SOLD Reactivity : No dangerous reaction known under conditions of normal use. Chemical stability : Stable under normal conditions. Possibility of hazardous reactions : No dangerous reaction known under conditions of normal use. Conditions to avoid : None known. Incompatible materials : None known. Hazardous decomposition products : In case of fire hazardous decomposition products may be produced such as: Carbon oxides Nitrogen oxides (NOx) SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation, Eye contact, Skin contact Potential Health Effects Product AS SOLD Eyes : Causes serious eye damage. Skin : Causes severe skin burns. Ingestion : Harmful if swallowed. Causes digestive tract burns. Inhalation : May cause nose, throat, and lung irritation. Chronic Exposure : Health injuries are not known or expected under normal use. Product AT USE DILUTION Eyes : Causes eye irritation. Skin : Health injuries are not known or expected under normal use. SAFETY DATA SHEET OASIS 146 MULTI-QUAT SANITIZER 910787 7 / 12 Ingestion : Health injuries are not known or expected under normal use. Inhalation : Health injuries are not known or expected under normal use. Chronic Exposure : Health injuries are not known or expected under normal use. Experience with human exposure Product AS SOLD Eye contact : Redness, Pain, Corrosion Skin contact : Redness, Pain, Corrosion Ingestion : Corrosion, Abdominal pain Inhalation : Respiratory irritation, Cough Product AT USE DILUTION Eye contact : Redness, Irritation Skin contact : No symptoms known or expected. Ingestion : No symptoms known or expected. Inhalation : No symptoms known or expected. Toxicity Product AS SOLD Product Acute oral toxicity : No data available Acute inhalation toxicity : No data available Acute dermal toxicity : LD50 Rabbit: > 5,000 mg/kg Test substance: Product Skin corrosion/irritation : Corrosive Test substance:Product Serious eye damage/eye irritation : Corrosive Test substance: Product Respiratory or skin sensitization : Not a skin sensitizer. Test substance: Product Carcinogenicity : No data available Reproductive effects : No data available Germ cell mutagenicity : No data available Teratogenicity : No data available STOT-single exposure : No data available STOT-repeated exposure : No data available Aspiration toxicity : No data available Components Acute oral toxicity : Alkyl (50% C14, 40% C12, 10% C16) dimethyl benzyl ammonium chloride LD50 Rat: 344 mg/kg SAFETY DATA SHEET OASIS 146 MULTI-QUAT SANITIZER 910787 8 / 12 Octyl decyl dimethyl ammonium chloride LD50 Rat: 238 mg/kg ethanol LD50 Rat: 10,470 mg/kg Didecyl Dimethyl Ammonium Chloride LD50 Rat: 329 mg/kg Dioctyl dimethyl ammonium chloride LD50 Rat: 238 mg/kg Components Acute inhalation toxicity : Alkyl (50% C14, 40% C12, 10% C16) dimethyl benzyl ammonium chloride 4 h LC50 Rat: 0.054 mg/l Test atmosphere: dust/mist Octyl decyl dimethyl ammonium chloride 4 h LC50 Rat: 0.07 mg/l Test atmosphere: dust/mist ethanol 4 h LC50 Rat: 117 mg/l Test atmosphere: vapor Didecyl Dimethyl Ammonium Chloride 4 h LC50 Rat: 0.07 mg/l Test atmosphere: dust/mist Dioctyl dimethyl ammonium chloride 4 h LD50 Rat: 0.07 mg/l Test atmosphere: dust/mist SECTION 12. ECOLOGICAL INFORMATION Product AS SOLD Ecotoxicity Environmental Effects : Very toxic to aquatic life. Toxic to aquatic life with long lasting effects. Product Toxicity to fish : No data available Toxicity to daphnia and other aquatic invertebrates : No data available Toxicity to algae : No data available Components Toxicity to fish : Octyl decyl dimethyl ammonium chloride 96 h LC50 Fish: 1 mg/l ethanol 96 h LC50 Pimephales promelas: > 100 mg/l Didecyl Dimethyl Ammonium Chloride 96 h LC50 Fish: 1 mg/l SAFETY DATA SHEET OASIS 146 MULTI-QUAT SANITIZER 910787 9 / 12 Dioctyl dimethyl ammonium chloride 96 h LC50 Oncorhynchus mykiss (rainbow trout): 0.35 mg/l Components Toxicity to daphnia and other aquatic invertebrates : Alkyl (50% C14, 40% C12, 10% C16) dimethyl benzyl ammonium chloride 48 h EC50 Daphnia magna (Water flea): 0.016 mg/l Dioctyl dimethyl ammonium chloride 96 h LC50: 0.073 mg/l Components Toxicity to algae : Dioctyl dimethyl ammonium chloride 72 h EC50 Pseudokirchneriella subcapitata (algae): 0.122 mg/l Persistence and degradability Product AS SOLD Not applicable - Biocide Product AT USE DILUTION Not applicable - Biocide Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Product AS SOLD Disposal methods : Do not contaminate ponds, waterways or ditches with chemical or used container. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re- use empty containers. Dispose of in accordance with local, state, and federal regulations. Product AT USE DILUTION Disposal methods : Do not contaminate ponds, waterways or ditches with chemical or used container. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re- use empty containers. Dispose of in accordance with local, state, and federal regulations. SAFETY DATA SHEET OASIS 146 MULTI-QUAT SANITIZER 910787 10 / 12 SECTION 14. TRANSPORT INFORMATION Product AS SOLD The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (DOT) Not dangerous goods Sea transport (IMDG/IMO) UN number : 3082 Description of the goods : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (quaternary ammonium compound) Class : 9 Packing group : III Marine pollutant : yes SECTION 15. REGULATORY INFORMATION Product AS SOLD EPA Registration number : 1677-198 EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Skin corrosion or irritation Serious eye damage or eye irritation Acute toxicity (any route of exposure) SARA 302 : This material does not contain any components with a section 302 EHS TPQ. SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. California Prop. 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. California Cleaning Product Right to Know Act of 2017 (SB 258) This regulation applies to this product. Chemical Name CAS-No. Function List(s) water 7732-18-5 Diluent Not Applicable Alkyl (50% C14, 40% C12, 10% C16) dimethyl benzyl ammonium chloride 68424-85-1 Biocide Not Applicable Octyl decyl dimethyl ammonium 32426-11-2 Biocide Not Applicable SAFETY DATA SHEET OASIS 146 MULTI-QUAT SANITIZER 910787 11 / 12 chloride Didecyl Dimethyl Ammonium Chloride 7173-51-5 Biocide Not Applicable Dioctyl dimethyl ammonium chloride 5538-94-3 Biocide Not Applicable Colorant Withheld Dye Not Applicable *refer to ecolab.com/sds for electronic links to designated lists The ingredients of this product are reported in the following inventories: United States TSCA Inventory : All substances listed as active on the TSCA inventory Canadian Domestic Substances List (DSL) : All components of this product are on the Canadian DSL Australia Inventory of Chemical Substances (AICS) : On the inventory, or in compliance with the inventory New Zealand. Inventory of Chemical Substances : not determined Japan. ENCS - Existing and New Chemical Substances Inventory : not determined Korea. Korean Existing Chemicals Inventory (KECI) : On the inventory, or in compliance with the inventory Philippines Inventory of Chemicals and Chemical Substances (PICCS) : On the inventory, or in compliance with the inventory China. Inventory of Existing Chemical Substances in China (IECSC) : On the inventory, or in compliance with the inventory Taiwan Chemical Substance Inventory (TCSI) : On the inventory, or in compliance with the inventory SECTION 16. OTHER INFORMATION Product AS SOLD NFPA: HMIS III: Product AT USE DILUTION Flammability Health Instability 3 0 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 0 0 3 Special hazard 0 = not significant, 1 = Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic SAFETY DATA SHEET OASIS 146 MULTI-QUAT SANITIZER 910787 12 / 12 NFPA: HMIS III: Issuing date : 02/04/2020 Version : 1.3 Prepared by : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Flammability Health Instability 1 0 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 0 0 1 Special hazard 0 = not significant, 1 = Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic SAFETY DATA SHEET KEYSTONE FRYER & GRILL CLEANER 912224-02 1 / 9 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : KEYSTONE FRYER & GRILL CLEANER Other means of identification : Not applicable Recommended use : Grill Cleaner Restrictions on use : Reserved for industrial and professional use. Product dilution information : Product is sold ready to use. Company : Ecolab Inc. 1 Ecolab Place St. Paul, Minnesota USA 55102 1-800-352-5326 Emergency health information : 1-800-328-0026 (US/Canada), 1-651-222-5352 (outside US) Issuing date : 05/08/2019 SECTION 2. HAZARDS IDENTIFICATION GHS Classification Skin corrosion : Category 1A Serious eye damage : Category 1 GHS label elements Hazard pictograms : Signal Word : Danger Hazard Statements : Causes severe skin burns and eye damage. Precautionary Statements : Prevention: Wash skin thoroughly after handling. Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. Wash contaminated clothing before reuse. Storage: Store locked up. Disposal: Dispose of contents/ container to an approved waste disposal plant. Other hazards : None known. SAFETY DATA SHEET KEYSTONE FRYER & GRILL CLEANER 912224-02 2 / 9 SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Pure substance/mixture : Mixture Chemical name CAS-No. Concentration (%) Sodium hydroxide 1310-73-2 5 - 10 2-(2-butoxyethoxy)ethanol 112-34-5 1 - 5 sodium isononanoate 84501-72-4 1 - 5 SECTION 4. FIRST AID MEASURES In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately. In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately. If swallowed : Rinse mouth with water. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention immediately. If inhaled : Remove to fresh air. Treat symptomatically. Get medical attention if symptoms occur. Protection of first-aiders : If potential for exposure exists refer to Section 8 for specific personal protective equipment. Notes to physician : Treat symptomatically. Most important symptoms and effects, both acute and delayed : See Section 11 for more detailed information on health effects and symptoms. SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media : None known. Specific hazards during fire fighting : Not flammable or combustible. Hazardous combustion products : Decomposition products may include the following materials: Carbon oxides Nitrogen oxides (NOx) Hazardous combustion products : Decomposition products may include the following materials: Carbon oxides Nitrogen oxides (NOx) Sulfur oxides Oxides of phosphorus Special protective equipment for fire-fighters : Use personal protective equipment. SAFETY DATA SHEET KEYSTONE FRYER & GRILL CLEANER 912224-02 3 / 9 Specific extinguishing methods : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Avoid inhalation, ingestion and contact with skin and eyes. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. Environmental precautions : Do not allow contact with soil, surface or ground water. Methods and materials for containment and cleaning up : Stop leak if safe to do so. Contain spillage, and then collect with non- combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. SECTION 7. HANDLING AND STORAGE Advice on safe handling : Do not ingest. Do not get in eyes, on skin, or on clothing. Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. Use only with adequate ventilation. Wash hands thoroughly after handling. Conditions for safe storage : Do not store near acids. Keep out of reach of children. Store in suitable labeled containers. Storage temperature : 0 °C to 50 °C SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Components CAS-No. Form of exposure Permissible concentration Basis sodium hydroxide 1310-73-2 Ceiling 2 mg/m3 ACGIH Ceiling 2 mg/m3 NIOSH REL TWA 2 mg/m3 OSHA Z1 2-(2-butoxyethoxy)ethanol 112-34-5 TWA (Inhalable fraction and vapor) 10 ppm ACGIH Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards. Personal protective equipment Eye protection : Wear eye protection/ face protection. Hand protection : Wear the following personal protective equipment: Standard glove type. SAFETY DATA SHEET KEYSTONE FRYER & GRILL CLEANER 912224-02 4 / 9 Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. Skin protection : Personal protective equipment comprising: suitable protective gloves, safety goggles and protective clothing Respiratory protection : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling. Provide suitable facilities for quick drenching or flushing of the eyes and body in case of contact or splash hazard. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Color : clear, light red Odor : slight pH : 13.3, (100 %) Flash point : 100 °C closed cup, Does not sustain combustion. Odor Threshold : No data available Melting point/freezing point : No data available Initial boiling point and boiling range : 100 °C Evaporation rate : No data available Flammability (solid, gas) : No data available Upper explosion limit : No data available Lower explosion limit : No data available Vapor pressure : No data available Relative vapor density : No data available Relative density : 1.04 - 1.1 Water solubility : soluble Solubility in other solvents : No data available Partition coefficient: n- octanol/water : No data available Autoignition temperature : No data available Thermal decomposition : No data available Viscosity, kinematic : 46.813 mm2/s (40 °C) Explosive properties : No data available Oxidizing properties : The substance or mixture is not classified as oxidizing. Molecular weight : No data available VOC : No data available SECTION 10. STABILITY AND REACTIVITY SAFETY DATA SHEET KEYSTONE FRYER & GRILL CLEANER 912224-02 5 / 9 Reactivity : No dangerous reaction known under conditions of normal use. Chemical stability : Stable under normal conditions. Possibility of hazardous reactions : No dangerous reaction known under conditions of normal use. Conditions to avoid : None known. Incompatible materials : Acids Metals Organic materials Hazardous decomposition products : Decomposition products may include the following materials: Carbon oxides Nitrogen oxides (NOx) In case of fire hazardous decomposition products may be produced such as: Carbon oxides Nitrogen oxides (NOx) Sulfur oxides Oxides of phosphorus SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation, Eye contact, Skin contact Potential Health Effects Eyes : Causes serious eye damage. Skin : Causes severe skin burns. Ingestion : Causes digestive tract burns. Inhalation : May cause nose, throat, and lung irritation. Chronic Exposure : Health injuries are not known or expected under normal use. Experience with human exposure Eye contact : Redness, Pain, Corrosion Skin contact : Redness, Pain, Corrosion Ingestion : Corrosion, Abdominal pain Inhalation : Respiratory irritation, Cough Toxicity Product Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg Acute inhalation toxicity : No data available Acute dermal toxicity : Acute toxicity estimate : > 5,000 mg/kg SAFETY DATA SHEET KEYSTONE FRYER & GRILL CLEANER 912224-02 6 / 9 Skin corrosion/irritation : No data available Serious eye damage/eye irritation : No data available Respiratory or skin sensitization : No data available Carcinogenicity : No data available Reproductive effects : No data available Germ cell mutagenicity : No data available Teratogenicity : No data available STOT-single exposure : No data available STOT-repeated exposure : No data available Aspiration toxicity : No data available SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Environmental Effects : This product has no known ecotoxicological effects. Product Toxicity to fish : No data available Toxicity to daphnia and other aquatic invertebrates : No data available Toxicity to algae : No data available Components Toxicity to fish : 2-(2-butoxyethoxy)ethanol 96 h LC50 Fish: 1,300 mg/l sodium isononanoate 96 h LC50 Fish: 160 mg/l Components Toxicity to daphnia and other aquatic invertebrates : Sodium hydroxide 48 h EC50: 40 mg/l Persistence and degradability Biodegradable Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS SAFETY DATA SHEET KEYSTONE FRYER & GRILL CLEANER 912224-02 7 / 9 Disposal methods : Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re- use empty containers. Dispose of in accordance with local, state, and federal regulations. RCRA - Resource Conservation and Recovery Authorization Act Hazardous waste : D002 (Corrosive) SECTION 14. TRANSPORT INFORMATION The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (DOT) UN number : 1824 Description of the goods : Sodium hydroxide solution Class : 8 Packing group : II Environmentally hazardous : no Sea transport (IMDG/IMO) UN number : 1824 Description of the goods : SODIUM HYDROXIDE SOLUTION Class : 8 Packing group : II Marine pollutant : no SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) Sodium hydroxide 1310-73-2 1000 16600 SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Skin corrosion or irritation Serious eye damage or eye irritation SARA 302 : This material does not contain any components with a section 302 EHS TPQ. SARA 313 : The following components are subject to reporting levels established by SARA Title III, Section 313: 2-(2-butoxyethoxy)ethanol 112-34-5 1 - 5 % SAFETY DATA SHEET KEYSTONE FRYER & GRILL CLEANER 912224-02 8 / 9 California Prop. 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. California Cleaning Product Right to Know Act of 2017 (SB 258) This regulation applies to this product. Chemical Name CAS-No. Function List(s) water 7732-18-5 Diluent Not Applicable Sodium hydroxide 1310-73-2 Cleaning Agent 20 2-(2-butoxyethoxy)ethanol 112-34-5 Solvent Not Applicable Organic acid salt Withheld Cleaning Agent Not Applicable sodium isononanoate 84501-72-4 Cleaning Agent Not Applicable Substituted alkylamine Withheld Solvent Not Applicable Alkyl sulfonate Withheld Cleaning Agent Not Applicable Chelating agent Withheld Cleaning Agent Not Applicable Colorant Withheld Dye Not Applicable *refer to ecolab.com/sds for electronic links to designated lists The ingredients of this product are reported in the following inventories: Switzerland. New notified substances and declared preparations : The mixture contains substances listed on the Swiss Inventory United States TSCA Inventory : On the inventory, or in compliance with the inventory Canadian Domestic Substances List (DSL) : This product contains one or several components listed in the Canadian NDSL. Australia Inventory of Chemical Substances (AICS) : not determined New Zealand. Inventory of Chemical Substances : not determined Japan. ENCS - Existing and New Chemical Substances Inventory : not determined Korea. Korean Existing Chemicals Inventory (KECI) : On the inventory, or in compliance with the inventory Philippines Inventory of Chemicals and Chemical Substances (PICCS) : not determined China. Inventory of Existing Chemical Substances in China (IECSC) : On the inventory, or in compliance with the inventory Taiwan Chemical Substance Inventory (TCSI) : not determined SECTION 16. OTHER INFORMATION SAFETY DATA SHEET KEYSTONE FRYER & GRILL CLEANER 912224-02 9 / 9 NFPA: HMIS III: Issuing date : 05/08/2019 Version : 1.1 Prepared by : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Flammability Health Instability 3 1 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 1 0 3 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic SAFETY DATA SHEET CLEAN & SMOOTH 913996 1 / 7 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : CLEAN & SMOOTH Other means of identification : Not applicable Recommended use : Skin-care Restrictions on use : Reserved for industrial and professional use. Product dilution information : Product is sold ready to use. Company : Ecolab Inc. 1 Ecolab Place St. Paul, Minnesota USA 55102 1-800-352-5326 Emergency health information : 1-800-328-0026 (US/Canada), 1-651-222-5352 (outside US) Issuing date : 09/27/2018 SECTION 2. HAZARDS IDENTIFICATION GHS Classification Eye irritation : Category 2B GHS label elements Signal Word : Warning Hazard Statements : Causes eye irritation. Precautionary Statements : Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention. Other hazards : None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Pure substance/mixture : Mixture Chemical name CAS-No. Concentration (%) sulfuric acid, mono-c10-16-alkyl esters, sodium salts 68585-47-7 1 - 5 C10-16 Polyglycoside 110615-47-9 1 - 5 sodium chloride 7647-14-5 1 - 5 SECTION 4. FIRST AID MEASURES In case of eye contact : Rinse with plenty of water. In case of skin contact : Rinse with plenty of water. If swallowed : Rinse mouth. Get medical attention if symptoms occur. SAFETY DATA SHEET CLEAN & SMOOTH 913996 2 / 7 If inhaled : Get medical attention if symptoms occur. Protection of first-aiders : No special precautions are necessary for first aid responders. Notes to physician : Treat symptomatically. Most important symptoms and effects, both acute and delayed : See Section 11 for more detailed information on health effects and symptoms. SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media : None known. Specific hazards during fire fighting : Not flammable or combustible. Hazardous combustion products : Decomposition products may include the following materials: Carbon oxides Sulfur oxides Special protective equipment for fire-fighters : Use personal protective equipment. Specific extinguishing methods : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. Environmental precautions : Do not allow contact with soil, surface or ground water. Methods and materials for containment and cleaning up : Stop leak if safe to do so. Contain spillage, and then collect with non- combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. SECTION 7. HANDLING AND STORAGE Advice on safe handling : Wash hands thoroughly after handling. Conditions for safe storage : Keep out of reach of children. Store in suitable labeled containers. Storage temperature : 5 °C to 45 °C SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION SAFETY DATA SHEET CLEAN & SMOOTH 913996 3 / 7 Ingredients with workplace control parameters Contains no substances with occupational exposure limit values. Engineering measures : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Personal protective equipment Eye protection : No special protective equipment required. Hand protection : No special protective equipment required. Skin protection : No special protective equipment required. Respiratory protection : No personal respiratory protective equipment normally required. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Color : white Odor : sweet pH : 6.0 - 7.0, (100 %) Flash point : Not applicable Odor Threshold : No data available Melting point/freezing point : No data available Initial boiling point and boiling range : No data available Evaporation rate : No data available Flammability (solid, gas) : No data available Upper explosion limit : No data available Lower explosion limit : No data available Vapor pressure : No data available Relative vapor density : No data available Relative density : 1.025 Water solubility : No data available Solubility in other solvents : No data available Partition coefficient: n- octanol/water : No data available Autoignition temperature : No data available Thermal decomposition : No data available Viscosity, kinematic : No data available Explosive properties : No data available Oxidizing properties : No data available SAFETY DATA SHEET CLEAN & SMOOTH 913996 4 / 7 Molecular weight : No data available VOC : No data available SECTION 10. STABILITY AND REACTIVITY Chemical stability : Stable under normal conditions. Possibility of hazardous reactions : No dangerous reaction known under conditions of normal use. Conditions to avoid : None known. Incompatible materials : None known. Hazardous decomposition products : In case of fire hazardous decomposition products may be produced such as: Carbon oxides Sulfur oxides SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation, Eye contact, Skin contact Potential Health Effects Eyes : Causes eye irritation. Skin : Health injuries are not known or expected under normal use. Ingestion : Health injuries are not known or expected under normal use. Inhalation : Health injuries are not known or expected under normal use. Chronic Exposure : Health injuries are not known or expected under normal use. Experience with human exposure Eye contact : Redness, Irritation Skin contact : No symptoms known or expected. Ingestion : No symptoms known or expected. Inhalation : No symptoms known or expected. Toxicity Product Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg Acute inhalation toxicity : No data available Acute dermal toxicity : No data available Skin corrosion/irritation : No data available SAFETY DATA SHEET CLEAN & SMOOTH 913996 5 / 7 Serious eye damage/eye irritation : Mild eye irritation Respiratory or skin sensitization : No data available Carcinogenicity : No data available Reproductive effects : No data available Germ cell mutagenicity : No data available Teratogenicity : No data available STOT-single exposure : No data available STOT-repeated exposure : No data available Aspiration toxicity : No data available Ingredients Acute dermal toxicity : sodium chloride LD50 Rabbit: > 10,000 mg/kg SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Environmental Effects : Harmful to aquatic life. Product Toxicity to fish : No data available Toxicity to daphnia and other aquatic invertebrates : No data available Toxicity to algae : No data available Ingredients Toxicity to fish : sulfuric acid, mono-c10-16-alkyl esters, sodium salts LC50: > 1.39 mg/l C10-16 Polyglycoside 96 h LC50 Fish: 5 mg/l sodium chloride 96 h LC50 Fish: 5,840 mg/l Ingredients Toxicity to daphnia and other aquatic invertebrates : sulfuric acid, mono-c10-16-alkyl esters, sodium salts 48 h EC50 Ceriodaphnia dubia (Water flea): 1.37 mg/l Persistence and degradability Readily biodegradable. Bioaccumulative potential No data available Mobility in soil No data available SAFETY DATA SHEET CLEAN & SMOOTH 913996 6 / 7 Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods : Do not contaminate ponds, waterways or ditches with chemical or used container. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re- use empty containers. Dispose of in accordance with local, state, and federal regulations. SECTION 14. TRANSPORT INFORMATION The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (DOT) Not dangerous goods Sea transport (IMDG/IMO) Not dangerous goods SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Serious eye damage or eye irritation SARA 302 : This material does not contain any components with a section 302 EHS TPQ. SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. California Prop. 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. The ingredients of this product are reported in the following inventories: Switzerland. New notified substances and declared preparations : not determined SAFETY DATA SHEET CLEAN & SMOOTH 913996 7 / 7 United States TSCA Inventory : On the inventory, or in compliance with the inventory Canadian Domestic Substances List (DSL) : This product contains one or several components listed in the Canadian NDSL. Australia Inventory of Chemical Substances (AICS) : On the inventory, or in compliance with the inventory New Zealand. Inventory of Chemical Substances : On the inventory, or in compliance with the inventory Japan. ENCS - Existing and New Chemical Substances Inventory : not determined Korea. Korean Existing Chemicals Inventory (KECI) : On the inventory, or in compliance with the inventory Philippines Inventory of Chemicals and Chemical Substances (PICCS) : On the inventory, or in compliance with the inventory China. Inventory of Existing Chemical Substances in China (IECSC) : On the inventory, or in compliance with the inventory Taiwan Chemical Substance Inventory (TCSI) : not determined SECTION 16. OTHER INFORMATION NFPA: HMIS III: Issuing date : 09/27/2018 Version : 1.3 Prepared by : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Flammability Health Instability 1 0 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 0 0 1 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic SAFETY DATA SHEET SANITIZING WASH N WALK 914231 1 / 9 22.02.2017 Section: 1. PRODUCT AND COMPANY IDENTIFICATION Product name : SANITIZING WASH N WALK Other means of identification : Not applicable. Recommended use : Floor Cleaner Product dilution information : 1,56 % Company : Ecolab (PTY) LTD 1 Ampere Street Chloorkop, Johannesburg South Africa 1620 +2711578 5000 Emergency telephone number : Spilltech HAZMAT Response: +27 (0)861 000 366 Poisons Information Helpline: +27 (0)861 555 777 Issuing date : 22.02.2017 Section: 2. HAZARDS IDENTIFICATION GHS Classification Product AS SOLD Skin irritation : Category 2 Serious eye damage : Category 1 Specific target organ toxicity - repeated exposure : Category 2 (Kidney) Acute aquatic toxicity : Category 2 Chronic aquatic toxicity : Category 3 Product AT USE DILUTION Acute aquatic toxicity : Category 3 GHS Label element Product AS SOLD Hazard pictograms : Signal Word : Danger Hazard Statements : Causes skin irritation. Causes serious eye damage. May cause damage to organs (Kidney) through prolonged or repeated exposure. Toxic to aquatic life. Harmful to aquatic life with long lasting effects. Precautionary Statements : Prevention: Do not breathe dust/fume/gas/mist/vapours/spray. Wash skin thoroughly after handling. Avoid release to the environment. Wear protective gloves/ eye protection/ face protection. Response: IF ON SKIN: Wash with plenty of water. IF IN EYES: Rinse cautiously SAFETY DATA SHEET SANITIZING WASH N WALK 914231 2 / 9 22.02.2017 with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. Get medical advice/ attention if you feel unwell.If skin irritation or rash occurs: Get medical advice/ attention.Take off contaminated clothing and wash it before reuse. Disposal: Dispose of contents/ container to an approved waste disposal plant. Product AT USE DILUTION Hazard Statements : Harmful to aquatic life. Precautionary Statements : Prevention: Avoid release to the environment. Disposal: Dispose of contents/ container to an approved waste disposal plant. Product AS SOLD Other hazards : Do not mix with bleach or other chlorinated products – will cause chlorine gas. Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS Product AS SOLD Pure substance/mixture : Mixture Chemical Name CAS-No. Concentration: (%) Boric acid 10043-35-3 1 - 5 alcohols, c12-15, ethoxylated 68131-39-5 1 - 5 N,N-Bis(3-aminopropyl)laurylamine 2372-82-9 1 - 5 boric acid (h3bo3), compd. with 2-aminoethanol (1:1) 68586-07-2 1 - 5 Alkylpolyglycosides 110615-47-9 1 - 5 Alkylamineoxides 3332-27-2 0,1 - 1 Lauryl-propylene-diamine 5538-95-4 0,1 - 1 Product AT USE DILUTION Chemical Name CAS-No. Concentration: (%) N,N-Bis(3-aminopropyl)laurylamine 2372-82-9 < 0,1 Section: 4. FIRST AID MEASURES Product AS SOLD In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately. In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention. If swallowed : Rinse mouth. Get medical attention if symptoms occur. If inhaled : Remove to fresh air. Treat symptomatically. Get medical attention. Protection of first-aiders : If potential for exposure exists refer to Section 8 for specific personal protective equipment. Notes to physician : Treat symptomatically. SAFETY DATA SHEET SANITIZING WASH N WALK 914231 3 / 9 22.02.2017 Most important symptoms and effects, both acute and delayed : See Section 11 for more detailed information on health effects and symptoms. Product AT USE DILUTION In case of eye contact : Rinse with plenty of water. In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention. If swallowed : Rinse mouth. Get medical attention if symptoms occur. If inhaled : Remove to fresh air. Treat symptomatically. Get medical attention. Section: 5. FIREFIGHTING MEASURES Product AS SOLD Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media : None known. Specific hazards during firefighting : Not flammable or combustible. Hazardous combustion products : Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) Sulphur oxides Oxides of phosphorus Special protective equipment for firefighters : Use personal protective equipment. Specific extinguishing methods : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Section: 6. ACCIDENTAL RELEASE MEASURES Product AS SOLD Personal precautions, protective equipment and emergency procedures : Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Avoid inhalation, ingestion and contact with skin and eyes. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed. Environmental precautions : Do not allow contact with soil, surface or ground water. Methods and materials for containment and cleaning up : Stop leak if safe to do so. Contain spillage, and then collect with non- combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). For large spills, dike SAFETY DATA SHEET SANITIZING WASH N WALK 914231 4 / 9 22.02.2017 spilled material or otherwise contain material to ensure runoff does not reach a waterway. Product AT USE DILUTION Personal precautions, protective equipment and emergency procedures : Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed. Environmental precautions : Do not allow contact with soil, surface or ground water. Methods and materials for containment and cleaning up : Stop leak if safe to do so. Contain spillage, and then collect with non- combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Section: 7. HANDLING AND STORAGE Product AS SOLD Advice on safe handling : Do not ingest. Avoid contact with skin and eyes. Do not get in eyes, on skin, or on clothing. Do not breathe dust/fume/gas/mist/vapours/spray. Use only with adequate ventilation. Wash hands thoroughly after handling. Do not mix with bleach or other chlorinated products – will cause chlorine gas. Conditions for safe storage : Keep out of reach of children. Keep container tightly closed. Store in suitable labeled containers. Storage temperature : 0 °C to 40 °C Product AT USE DILUTION Advice on safe handling : Do not get in eyes, on skin, or on clothing. Do not breathe dust/fume/gas/mist/vapours/spray. Use only with adequate ventilation. Wash hands thoroughly after handling. Conditions for safe storage : Keep out of reach of children. Store in suitable labeled containers. Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Product AS SOLD Components with workplace control parameters Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards. Personal protective equipment Eye protection : Safety goggles Face-shield Hand protection : Wear the following personal protective equipment: Standard glove type. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. Skin protection : No special protective equipment required. SAFETY DATA SHEET SANITIZING WASH N WALK 914231 5 / 9 22.02.2017 Respiratory protection : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling. Provide suitable facilities for quick drenching or flushing of the eyes and body in case of contact or splash hazard. Product AT USE DILUTION Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards. Personal protective equipment Eye protection : No special protective equipment required. Hand protection : Wear the following personal protective equipment: Standard glove type. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. Skin protection : No special protective equipment required. Respiratory protection : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Section: 9. PHYSICAL AND CHEMICAL PROPERTIES Product AS SOLD Product AT USE DILUTION Appearance : liquid liquid Colour : clear, green light green Odour : Perfumes, fragrances Perfumes, fragrances pH : 7,0 - 9,0, 100 % 6,0 - 9,0 Flash point : closed cupNot applicable. Odour Threshold : no data available Melting point/freezing point : no data available Initial boiling point and boiling range : > 100 °C Evaporation rate : no data available Flammability (solid, gas) : no data available Upper explosion limit : no data available Lower explosion limit : no data available Vapour pressure : no data available Relative vapour density : no data available Relative density : 1,02 - 1,05 Water solubility : no data available Solubility in other solvents : no data available Partition coefficient: n-: no data available SAFETY DATA SHEET SANITIZING WASH N WALK 914231 6 / 9 22.02.2017 octanol/water Auto-ignition temperature : no data available Thermal decomposition : no data available Viscosity, kinematic : no data available Explosive properties : no data available Oxidizing properties : The substance or mixture is not classified as oxidizing. Molecular weight : no data available VOC : no data available Section: 10. STABILITY AND REACTIVITY Product AS SOLD Chemical stability : Stable under normal conditions. Possibility of hazardous reactions : Do not mix with bleach or other chlorinated products – will cause chlorine gas. Conditions to avoid : None known. Incompatible materials : Acids Bases Hazardous decomposition products : Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) Sulphur oxides Oxides of phosphorus Section: 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation, Eye contact, Skin contact Potential Health Effects Product AS SOLD Eyes : Causes serious eye damage. Skin : Causes skin irritation. Ingestion : Health injuries are not known or expected under normal use. Inhalation : Health injuries are not known or expected under normal use. Chronic Exposure : Health injuries are not known or expected under normal use. Product AT USE DILUTION Eyes : Causes eye irritation. Skin : Health injuries are not known or expected under normal use. Ingestion : Health injuries are not known or expected under normal use. Inhalation : Health injuries are not known or expected under normal use. SAFETY DATA SHEET SANITIZING WASH N WALK 914231 7 / 9 22.02.2017 Chronic Exposure : Health injuries are not known or expected under normal use. Experience with human exposure Product AS SOLD Eye contact : Redness, Pain, Corrosion Skin contact : Redness, Irritation Ingestion : No symptoms known or expected. Inhalation : No information available. Product AT USE DILUTION Eye contact : Redness, Irritation Skin contact : No symptoms known or expected. Ingestion : No symptoms known or expected. Inhalation : No information available. Toxicity Product AS SOLD Product Acute oral toxicity : Acute toxicity estimate : > 2.500 mg/kg Skin corrosion/irritation : no data available Respiratory or skin sensitization : no data available Carcinogenicity : no data available Reproductive effects : no data available Germ cell mutagenicity : no data available Teratogenicity : no data available STOT - single exposure : no data available STOT - repeated exposure : no data available Aspiration toxicity : no data available Section: 12. ECOLOGICAL INFORMATION Product AS SOLD Ecotoxicity Environmental Effects : Toxic to aquatic life. Harmful to aquatic life with long lasting effects. Product Toxicity to fish : no data available Toxicity to daphnia and other aquatic invertebrates : no data available Toxicity to algae : no data available Components Toxicity to fish : alcohols, c12-15, ethoxylated SAFETY DATA SHEET SANITIZING WASH N WALK 914231 8 / 9 22.02.2017 96 h LC50 Pimephales promelas (fathead minnow): 1,4 mg/l boric acid (h3bo3), compd. with 2-aminoethanol (1:1) 96 h LC50: 74 mg/l Alkylpolyglycosides 96 h LC50 Fish: 5 mg/l Lauryl-propylene-diamine LC50 Fish: 0,512 mg/l Test substance: Information given is based on data obtained from similar substances. Components Toxicity to algae : N,N-Bis(3-aminopropyl)laurylamine 72 h EC50: 0,014 mg/l Alkylamineoxides 72 h EC50: 0,19 mg/l Persistence and degradability Product AS SOLD Readily biodegradable. Product AT USE DILUTION Biodegradable Bioaccumulative potential no data available Mobility in soil no data available Other adverse effects no data available Section: 13. DISPOSAL CONSIDERATIONS Product AS SOLD Disposal methods : The product should not be allowed to enter drains, water courses or the soil. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re- use empty containers. Dispose of in accordance with local, state, and federal regulations. Product AT USE DILUTION Disposal methods : The product should not be allowed to enter drains, water courses or the soil. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. SAFETY DATA SHEET SANITIZING WASH N WALK 914231 9 / 9 22.02.2017 Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re- use empty containers. Dispose of in accordance with local, state, and federal regulations. Section: 14. TRANSPORT INFORMATION Product AS SOLD The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (ZA DG) Not dangerous goods Air transport (IATA) Not dangerous goods Sea transport (IMDG/IMO) Not dangerous goods Section: 15. REGULATORY INFORMATION For Regulatory information please contact your Ecolab sales representative. Section: 16. OTHER INFORMATION Issuing date : 22.02.2017 Version : 1.0 Prepared by : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.