23080_Almont Shipping II_BAR_20200713

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Gcowttcc Consultants of NC, P.C.
Ms. Caroline Goodwin
Brownfield Program Project Manager
North Carolina Department of Environmental Quality
1646 Mail Service Center
Raleigh, North Carolina 27699-1646
Geosyntec Consultants of NC, P.C.
201 N Front Street, Suite 501
Wilmington, NC 28401
PH 910.726.3652
www.geosyntec.com
13 July 2020
Subject: Brownfields Site Assessment Report
Site: Almont Shipping II
19 & 41 Harnett Street, Wilmington, North Carolina (New Hanover County
Parcels No. R04716-001-026-000 & R04712-002-001-000)
NCBP No. 23080-19-065
Dear Ms. Goodwin:
On behalf of Wilmington Waterfront Property Owner, LLC (the Prospective Developer [PD]),
Geosyntec Consultants of NC, P.C. (Geosyntec) has prepared this Brownfields Site Assessment
Report (Assessment Report) for the above -referenced North Carolina Brownfields Program
(NCBP) property located at 19 and 41 Harnett Street, Wilmington, North Carolina (the "Site").
The North Carolina Department of Environmental Quality (NCDEQ) approved Wilmington
Waterfront Property Owner, LLC's 7 January 2020 Brownfields Property Application (BPA) in an
18 February Letter of Eligibility (LOE). A Work Plan was subsequently submitted to NCBP on 23
March 2020 and approved in a 24 March 2020 email. This Assessment Report presents the results
from soil and groundwater assessment activities completed at the Site pursuant to the Work Plan
to support the issuance of a Brownfields Agreement (BFA) for the Site. We look forward to your
review and approval of this Site Assessment. Please do not hesitate to contact Kaitlyn Rhonehouse
(910-726-3652 or krhonehouseggeosytnec.com)if you have any questions.
Sincerely,
R. Matthew Jenny
Project Engineer
Kaitlyn Rhonehouse, PE (NC, VA, FL)
Principal Engineer
Copies to: Luke Davis, Graham Tyrrell, William Edwards — Kettler Enterprises, Inc.
Mary Katherine Stukes —Moore & Van Allen

Prepared for
Wilmington Waterfront Property Owner, LLC
8255 Greensboro Drive, Suite 200
McLean, Virginia 22102
BROWNFIELDS SITE ASSESSMENT
REPORT
New Hanover County Parcel No. R04716-001-026-000
& R04712-002-001-000
19 & 41 Harnett Street, Wilmington, North Carolina
Brownfields Project: Almont Shipping II
NCBP No. 23080-19-065
Prepared by
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consultants
Geosyntec Consultants of NC, P.C.
Geosyntec Consultants of NC, P.C.
210 N. Front Street, Suite 501
Wilmington, North Carolina 28401
Project Number GN7035
July 2020

PROFESSIONAL ENGINEER SIGNATURE
I, R. Matthew Jenny, a Licensed Engineer for Geosyntec Consultants of NC, P.C., do certify that
the information in this report is correct and accurate to the best of my knowledge.
Geosyntec Consultants of NC, F.C. is licensed to practice engineering in North Carolina. The
certification number (Firm's License Number) is C-3500.
Geosyntec Consultants of NC, P.C. is licensed to practice geology in North Carolina. The
certification number (Firm's License Number) is C-295.
R. Matthew Jenny, PE
Project Engineer
North Carolina P.E. License No. 045603
Expiration Date: 31 December 2020
Geosyntec Consultants of NC, P.C.
2501 Blue Ridge Road, Suite 430
Raleigh, NC 276077
Telephone: [phone]

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TABLE OF CONTENTS
1. INTRODUCTION................................................................................................................... 1
1.1. Site Environmental History.............................................................................................. 1
1.2. Objectives......................................................................................................................... 2
2. SCOPE OF WORK................................................................................................................. 3
3. SAMPLING METHODOLOGY............................................................................................. 4
3.1. Health and Safety Planning and Utility Clearing............................................................. 4
3.2. Soil Sampling................................................................................................................... 4
3.3. Monitoring Well Installation and Groundwater Sampling ............................................... 4
3.4. Decontamination.............................................................................................................. 6
3.5. Soil Boring Locating and Monitoring Well Survey......................................................... 6
3.6. Soil Boring and Monitoring Well Abandonment............................................................. 6
3.7. Investigative Derived Waste............................................................................................ 6
4. RESULTS................................................................................................................................ 7
4.1. Soil Analytical Results..................................................................................................... 7
4.2. Groundwater Analytical Results...................................................................................... 8
4.3. Risk Screening Results..................................................................................................... 9
5. CONCLUSIONS & RECOMMENDATIONS..................................................................... 10
LIST OF TABLES
Table 1 Sampling Locations and Requested Analysis
Table 2 Monitoring Well Construction Details
Table 3 Soil Analytical Results
Table 4 Groundwater Analytical Results
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Figure 1 Site Location
LIST OF FIGURES
Figure 2
Site Layout
Figure 3
Sampling Locations
Figure 4
Groundwater Elevations
Figure 5
Soil Analytical Results
Figure 6
Groundwater Analytical Results
LIST OF APPENDICES
Appendix A Well Logs
Appendix B Field Forms
Appendix C Laboratory Analytical Reports
Appendix D Risk Calculator Results
GN7035 Brownfields Site Assessment Report ii July 2020

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1. INTRODUCTION
Geosyntec Consultants of NC, P.C. (Geosyntec), on behalf of Wilmington Waterfront Property
Owner, LLC (the Prospective Developer [PD), prepared this Brownfields Site Assessment Report
("the Report") for two parcels located at 19 and 41 Harnett Street (New Hanover County parcel
IDs: R04716-001-026-000 and R04712-002-001, respectively), Wilmington, North Carolina
(these two parcels are collectively herein referred to as the "Site", as shown on Figure 1 and
Figure 2). The total acreage of the 19 Harnett Street parcel is approximately 2.02 acres and the
total acreage of the 41 Harnett Street parcel is approximately 0.95 acres, totaling the combined
acreage to 2.97-acres. The 19 Harnett Street parcel and the northwestern portion of 41 Harnett
Street parcel and surrounding area formerly comprised the "Almont Shipping Brownfields
Property" (North Carolina Brownfields Program [NCBP] No. 10040-06-065; referred to herein as
the "Almont Shipping Brownfields Property"). Figure 2 shows the location of the Site and the
Almont Shipping Brownfields Property.
The North Carolina Department of Environmental Quality (NCDEQ) approved Wilmington
Waterfront Property Owner, LLC's 7 January 2020 Brownfields Property Application (BPA) in an
18 February 2020 Letter of Eligibility (LOE; NCBP No. 23080-19-065). Geosyntec has been
retained by Wilmington Waterfront Property Owner, LLC to guide the environmental efforts to
produce a stand-alone Brownfields Agreement (BFA) for the Site that will supersede the existing
BFA for the Site portion of the Almont Shipping Brownfields Property. A Work Plan was
submitted to NCBP on 23 March 2020 to outline proposed assessment activities at the Site; the
Work Plan was subsequently approved by NCBP in a 24 March 2020 email. Geosyntec has
prepared this Report to present the results from groundwater and soil sampling activities at the Site
completed pursuant to the Work Plan. These results are intended to document pre-existing
environmental Site conditions, evaluate Site risk, and support issuance of a new BFA.
1.1. Site Environmental History
The Site and surrounding area operated as the former Almont Shipping terminal from 1870 until
2005. A BFA for the Almont Shipping Brownfields Property (NCBP No. 10040-06-065; the 19
Harnett Street parcel and northwestern portion of the 41 Harnett St. parcel are included in the
existing Brownfields Property) was executed between the NCBP and Riverfront Holdings II, LLC
on 23 June 2008. The BFA was amended in 2014 to include an additional land tract owned by
CSX. The Site, which is the subject of this Report, received eligibility for entry into the NCBP on
18 February 2020 to establish a new, stand-alone BFA for only the two Harnett Street parcels.
Contaminants of concern (COCs) recorded for the greater Almont Shipping Brownfields Property,
which includes the Site, included various volatile organic compounds (VOCs), semi -volatile
organic compounds (SVOCs), pesticides, metals, and inorganics in soil and/or groundwater.
Pursuant to the BFA, land use restrictions (LURs) exist for the Almont Shipping Brownfields
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Property to maintain liability protections and minimize risks to human health and the environment.
These LURs are outlined in the BFA and include restrictions on land, groundwater, and surface
water use, and vapor intrusion mitigation, as applicable (notably, the area subject to the vapor
intrusion mitigation LUR does not include the Site).
The Almont Shipping Brownfields Property parcels are currently owned by various unique entities
and portions of the Brownfields Property have undergone redevelopment. The two Site parcels
were purchased by the PD in June 2019. The western (19 Harnett Street) parcel consists of paved
parking and a stormwater detention pond associated with an adjacent marina and restaurant; this
development was completed prior to Wilmington Waterfront Property Owner, LLC's acquisition.
The eastern (41 Harnett Street) parcel is vacant and undeveloped and has been temporarily used
to store excess soil from the previous 19 Harnett Street development activities. The Site is planned
to be developed for multi -family apartments, retail space, and an associated parking garage. No
development or construction has been completed by the PD to date.
The remainder of this Report provides a summary of the soil and groundwater sampling completed
at the Site in June 2020.
1.2. Objectives
The scope of work for this investigation was completed to meet the following objectives:
• Obtain soil data to evaluate soil quality and management options; and
• Obtain groundwater data to evaluate groundwater quality and depth to groundwater
beneath the Subject Site.
Results from the soil and groundwater assessment provided herein will be used to establish
baseline conditions at the Site and guide selection of applicable land use restrictions for the BFA.
GN7035 Brownfields Site Assessment Report 2 July 2020

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2. SCOPE OF WORK
The scope of work included the assessment of site soil and groundwater. The site soil assessment
effort included the advancement of ten (10) soil borings across the two Site parcels presented in
Table 1 and Figure 3. Soil boring and groundwater assessment methods are described in Section
3 of this Report.
The site groundwater assessment included advancing three (3) borings to first encountered
groundwater, noted between 6 and 11 feet below land surface (ft BLS), and installing Type II
monitoring wells (Figure 3). Please note, four wells were planned to be installed; however,
shallow refusal was encountered throughout much of the southern portion of the western parcel,
as discussed further below. Details of the site groundwater assessment methods are included in
Section 3.3. As shown in Figure 3, the monitoring wells are located to allow characterization of
groundwater conditions across the Site, including off -site sources.
GN7035 Brownfields Site Assessment Report 3 July 2020

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3. SAMPLING METHODOLOGY
3.1. Health and Safety Planning and Utility Clearing
Prior to the start of work, Geosyntec prepared a site -specific Health and Safety Task Hazard
Analysis in general accordance with the Occupation Safety and Health Administration (OSHA)
rules (29 CFR 1910.120). To address potential underground utilities, Geosyntec contacted the
North Carolina 811 one -call system within 72 business hours before beginning the assessment to
notify member utilities of the subsurface work. Because 811 utility locating services only identifies
utilities up to the property boundary, Geosyntec coordinated with a private subsurface utility
exploration (SUE) surveyor to clear sample locations/areas of utilities. Procedures generally
followed the Operating Procedures as determined by the U.S. Environmental Protection Agency
(USEPA) Region IV Science and Ecosystem Support Division (SESD). The most current versions
of these operating procedures can be downloaded at: https://www.epa.gov/qualiiy/qualiiy-system-
and-technical-procedures-sesd-field-branches. Additional media specific procedures are discussed
further below.
3.2. Soil Sampling
Ten (10) borings (SB-1 through SB-10) were advanced to 2 ft BLS using hand augers to allow for
the collection of soil samples. Soil boring locations are shown in Table 1 and Figure 3. Geosyntec
screened each boring with a Photoionization Detector (PID) and documented the soil lithology of
each boring. Soil staining and/or odors were recorded in the field when observed. Soil samples
were composited from ground surface to 2 ft BLS, with the exception of samples analyzed for
VOCs. Soil analyzed for VOCs were grab samples collected from an undisturbed soil sample from
each boring at the depth corresponding to the highest PID reading, but no samples were collected
at depths shallower than 0.5 ft BLS.
Soil samples were sent off -site to a North Carolina -certified laboratory on ice and under chain of
custody procedures. Based upon the known Brownfields Property environmental history, the soil
samples were analyzed for VOCs by EPA Method 8260, SVOCs by EPA Method 8270,
organochlorine pesticides by EPA Method 8081, and the eight (8) RCRA metals by EPA Method
6010, including speciation for hexavalent by EPA Method 7199 (Table 1). One quality control
(QC) duplicate soil sample was collected at SB-06 during this investigation.
3.3. Monitoring Well Installation and Groundwater Sampling
Geosyntec contracted with a North Carolina -licensed driller (Catlin Engineers and Scientists) to
install three monitoring wells using hollow -stem augers. A fourth well planned for installation in
the southern portion of the western parcel was attempted in several locations near SB-3 and SB-4;
GN7035 Brownfields Site Assessment Report 4 July 2020

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however, a monitoring well was unable to be installed in this area due to auger refusal. Two of the
monitoring wells (MW-1 and MW-2) are located at respective soil boring locations (SB-1 and SB-
2). MW-4 was installed within the westernmost parcel near the northern property boundary
(Figure 3).
Type II monitoring wells (MW-1, MW-2, and MW-4) were installed in general accordance with
North Carolina Administrative Code (NCAC) Title 15A Subchapter 02C Well Construction
Standards on 4 and 5 June 2020 using hollow stem auger drilling methods. Boreholes were
converted into Type II monitoring wells set to depths of approximately 17 to 20 ft BLS and were
installed at a maximum of 10 feet below first encountered groundwater. Well construction
information is presented in Table 2 and well logs are included in Appendix A. Each monitoring
well was constructed of 2-inch Schedule 40 polyvinyl chloride (PVC), 10-foot standard 0.010-inch
slotted screen, and 2-inch Schedule 40 PVC riser pipe to surface. The screened interval depth was
determined in the field based on the lithology and was designed to bracket the observed water
table. The annular space around the monitoring well was backfilled with filter pack sand and was
extended to approximately two foot above the top of the well screen. A 2-foot to 4-foot well seal
was installed on top of the filter pack at each monitoring well. The remaining annular space above
the seal was filled with grout to the ground surface with grout thickness ranging from 1 to 6 feet.
Each well was enclosed in a flush -mounted locked manhole cover.
Following installation, each monitoring well was developed by purging three to five well volumes
using a peristaltic pump or submersible pump and dedicated tubing in general accordance with the
Multiple -Volume Purge method referenced in EPA Region 4, Science and Ecosystem Support
Division (SESD), Groundwater Sampling Operative Procedure (SOP) (Effective date 27 April
2017).
Groundwater level measurements relative to the top of the inner PVC well casing (top of casing
[TOC]) were obtained from each monitoring wells prior to sampling. Recorded depth to water
measurement and the associated calculated groundwater elevations are presented in Table 2 and
Figure 4. After groundwater level measurements were obtained, a peristaltic pump and dedicated
polyethylene tubing were used to purge wells in general accordance with low flow purging
methods referenced in EPA Region 4, SESD, Groundwater SOP (effective date 27 April 2017).
Stabilization of water quality parameters was considered acceptable for sampling when the
following parameters were met for at least three consecutive measurements:
• the pH remained constant within 0.1 Standard Unit (SU);
• specific conductance varied no more than 5 percent; and
GN7035 Brownfields Site Assessment Report 5 July 2020

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• turbidity had either stabilized or was below 10 Nephelometric Turbidity Units (NTUs)
(twice the Secondary Drinking Water Standard of 5 NTUs).
Field forms with recorded parameters including, but not limited to pH, dissolved oxygen (DO),
specific conductance, turbidity, oxidation-reduction potential (ORP) and purge information (start
time, measurements, volumes etc.) are presented in Appendix B.
A groundwater sample was collected from each of the three monitoring wells following
stabilization and one QC duplicate groundwater sample was collected from MW-4. Groundwater
samples were analyzed for: (i) VOCs by EPA Method 8260; (ii) SVOCs by EPA Method 8270;
and (iii) RCRA 8 Metals using EPA Method 6010 and 7470A (Table 1). Samples were placed on
ice in dedicated coolers and submitted to a North Carolina -certified laboratory for analysis
following chain of custody procedures (Section 5.2).
3.4. Decontamination
Disposable equipment was used as practical. Non -disposable equipment was decontaminated
using an initial water rinse followed by cleaning with Alconox® and final rinse of deionized water,
as needed.
3.5. Soil Boring Locating and Monitoring Well Survey
A handheld GPS unit was used to collect the approximate coordinates of the soil borings. TOC
elevations and location of each monitoring well were surveyed by a North Carolina Registered
Land Surveyor to establish vertical and horizontal locations.
3.6. Soil Boring and Monitoring Well Abandonment
Following sample collection, soil borings were abandoned using excess soil and bentonite.
Groundwater wells will remain in place as needed. Pending approval/authorization from NCDEQ,
monitoring wells will be abandoned at a future date with bentonite and cement grout in accordance
with procedures for well abandonment outlined in 15A NCAC 02C .0113.
3.7. Investigative Derived Waste
Investigative Derived Waste (IDW) (e.g., excess soil cuttings and development/purge water) were
containerized in 55-gallon steel drums and stored in a designated area of the Site pending disposal
based on laboratory results. IDW will be disposed of in general accordance with 15A NCAC
02T.1503 and 15A NCAC 02H. 0106.
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4. RESULTS
Soil sample analytical results for constituents detected above the laboratory method detection limit
(MDL) in one or more soil samples are presented in Table 3. Constituents detected in soil above
an NCDEQ residential or commercial/industrial Preliminary Soil Remediation Goal (PSRG) are
shown on Figure 5. Groundwater analytical results for constituents detected above the MDL are
summarized in Table 4. Constituents detected in groundwater above Title 15A NCAC 2L
Groundwater Standards (2L Standards) or the Interim Maximum Allowable Concentrations
(IMACs) are shown on Figure 6. Laboratory analytical reports are included in Appendix C.
4.1. Soil Analytical Results
Ten soil samples and one duplicate soil sample were collected between 4 and 5 June 2020. The
primary findings associated with the soil analytical results are as follows:
• VOCs: No VOCs were detected at a concentration above the residential or
commercial/industrial PSRGs. Ten VOCs were detected above an MDL.
• SVOCs: Benzo(a) pyrene was detected at concentrations above the residential PSRG in
nine of the soil samples. No SVOCs were detected at concentrations above their respective
industrial/commercial PSRGs. Several SVOCs were detected above an MDL.
• Metals: Arsenic was detected above the residential and commercial/industrial PSRGs in
each of the soil samples collected. Hexavalent chromium (CrVI) was detected above its
residential PSRG in several samples, as explained further below. No other metals were
detected above residential PSRGs.
o Arsenic was detected above the residential PSRG (0.68 milligrams per kilogram
[mg/kg]) and commercial/industrial PSRG (3 mg/kg) at each sampling location.
Concentration values ranged between 4.2 and 7.8 mg/kg.
o Hexavalent chromium was detected above the residential PSRG (0.31 mg/kg) at
seven of the sampling locations (SB-01, SB-03, SB-04, SB-05, SB-07, SB-08, and
SB-09); CrVI was not detected above the commercial/industrial PSRG (6.5 mg/kg).
The MDL for the non -detect hexavalent chromium values was above the respective
residential PSRG.
• Ogganochlorine Pesticides: Pesticides were not detected above an MDL. The
organochlorine pesticide analytical results are not presented on Table 3.
GN7035 Brownfields Site Assessment Report 7 July 2020

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4.2. Groundwater Analytical Results
Three groundwater samples and a duplicate groundwater sample were collected on 8 June 2020.
The observed depth to groundwater ranged from approximately 6 to 11 feet below the top of the
well casings (ft BTOC) (Table 2). The associated calculated groundwater elevations are also
presented in Table 2 and shown on Figure 4. Given the ambiguity in the groundwater elevation
data, groundwater flow isocontour lines are not presented.
The primary findings associated with the groundwater analytical results are as follows:
• VOCs: Methyl chloride exceeded the 2L Standard (3 microgram per liter [µg/L]) in one
sample (MW-02) at 4.4 µg/L. Methyl chloride was not detected in other groundwater
samples. No other exceedances were observed in the groundwater samples analyzed for
VOCs. Three VOCs were detected in one or more groundwater samples above an MDL.
The single methyl chloride exceedance is below the NCDEQ vapor intrusion screening
level (VISL) for hypothetical future residential occupants.
• SVOCs: No SVOCs were detected above 2L Standards or IMACs. One SVOC (fluorene)
was detected above an MDL at MW-01.
• Metals: Three metals were detected in one or more of the collected groundwater samples.
Arsenic and total chromium were detected at a concentration above the 2L Standard or
IMACs.
o Arsenic was detected above the 2L Standard (10 µg/L) from each of the three wells
with concentrations ranging between 31 and 163 µg/L. Arsenic was not detected in
the parent sample collected at MW-04 (where the MDL was 10 µg/L) but was
detected in the duplicate sample from MW-04 (at 31.9 µg/L). Notably, turbidity
visually increased during sample collection of the duplicate sample, which may be
the cause of the higher arsenic detection in this sample compared to the parent
sample.
o Total chromium was detected slightly above the 2L Standard (10 µg/L) in the
duplicate sample from MW-04 (12.2 µg/L) but was not detected in the parent
sample from MW-04 or in samples from MW-01 or MW-02. As noted above,
turbidity visually increased during sample collection of the duplicate sample at
MW-04, which may be the cause of the higher chromium detection in this sample
compared to the parent sample.
o Lead was not detected above its 2L Standard in the collected groundwater samples.
Lead was detected above the MDL in the parent and duplicate samples collected
from MW-04.
GN7035 Brownfields Site Assessment Report 8 July 2020

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• Ogganochlorine Pesticides: No pesticides were detected above an MDL. The
organochlorine pesticide analytical results are not presented on Table 4.
4.3. Risk Screening Results
Based on the detections of constituents in soil above the PSRGs, Geosyntec conducted a
preliminary risk screening using the December 2019 version of the NCDEQ risk calculator. The
risk evaluation was conducted in accordance with the Revised Technical Guidance for Risk -Based
Environmental Remediation of Sites (Risk -Based Guidance) (NCDEQ, 2020). The highest
detection of each analyte in the eleven (11) collected soil samples was used during the calculation.
Complete risk pathways considered include pathways for residents, non-residential workers,
construction workers, recreators, and trespassers. The risk calculator output table is presented
below. Supporting risk calculator summaries and outputs are included in Appendix D.
Receptor
Pathway
CarcinogenicRisk
Hazard Index
Risk exceeded.
Resident
Soil
4.6E-05
5.7E-01
NO
Non -Residential
Worker
Soil
5.9E-06
8.8E-02
NO
Construction Worker
Soil
1.2E-06
3.9E-01
NO
Recreator
Soil
2.4E-05
1.7E-01
NO
Trespasser
Soil
4.4E-06
3.2E-02
NO
No unacceptable cumulative cancer risks or non -cancer hazards were identified as part of the risk
screening. Acceptable cumulative cancer risk levels are defined as less than 1 in 10,000 (i.e., 1.0E-
4) and acceptable cumulative non -cancer hazards are defined as less than 1.0. The results of the
conservative risk screening indicate that Site soils collected as part of this investigation do not
pose an unacceptable risk to future site occupants.
GN7035 Brownfields Site Assessment Report 9 July 2020

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5. CONCLUSIONS & RECOMMENDATIONS
Soil and groundwater sampling were performed by Geosyntec at the Site in June 2020 to collect
data to establish baseline conditions at the Site and support issuance of a BFA. During this
assessment, ten soil samples and three groundwater samples were collected for laboratory analysis.
One SVOC (benzo(a)pyrene) and two metals (arsenic and hexavalent chromium) were detected in
soil above the Residential PSRGs from one or more samples. Additionally, arsenic exceeded its
commercial/industrial PSRG in each soil sample collected. The arsenic and hexavalent chromium
concentrations in soil have a narrow concentration distribution and appear consistent with naturally
occurring background concentrations in soil. No other VOC, SVOC, or metal detections were
above a PSRG in soil samples and no pesticides were detected above an MDL. A human health
soil risk screening was performed using the NCDEQ risk calculator, the results of which do not
indicate unacceptable cancer or non -cancer risks to hypothetical residents, recreators/trespassers,
non-residential workers, or construction workers due to exposure from Site soils.
Groundwater sampling revealed detections of methyl chloride, arsenic, and chromium above 2L
Standards/IMACs. No other VOCs, SVOCs, or metals exceeded an applicable groundwater
standard, and pesticides were not detected above MDLs. To the extent that the water table will be
encountered during potential future construction, the presence of these constituents should be
accounted for during site redevelopment and construction planning. However, the exceedances of
these constituents are not expected to affect the PD's ability to use the Site for multi -family or
retail use, as land use restrictions prohibiting groundwater use under future redevelopment are
anticipated For this reason, hypothetical exposure risks from exposure to impacted groundwater
were not considered.
The maximum concentration of methyl chloride (a volatile species) was detected below NCDEQ
residential VISLs for potential vapor intrusion considerations. Hypothetical vapor intrusion risks
were therefore not quantified.
Geosyntec concludes that sufficient data exists to evaluate risk at the Site and prepare the BFA,
which we understand would allow for residential use and include a land -use restriction prohibiting
the use of groundwater at the Site. No requirement for mitigation for vapor intrusion has been
identified. We look forward to NCDEQ's review of this report and preparation of a draft BFA for
the Site.
GN7035 Brownfields Site Assessment Report 10 July 2020

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Notes:
I. Aerial imagery provided by ArcMap10.5, ESRI
2. Parcel Boundary obtained from New Hanover County, NC online
GIS database.
-31
Site Location
19 and 41 Harnett Street
New Hanover, NC
Geosyntec°
consultants Figure
G }ranee Coruulronts of Nl�PG.
Raleigh, NC July 2020 1

Area of Potential Vapor Concern
Parcels
Brownfields Boundary
Site Parcels
Notes:
1. Aerial imagery provided by ArcMapl0.5, ESRI
2. Parcel Boundary obtained from New Hanover County, NC online
GIS database.
- 1
R0471�2-002-001-000
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Site Layout
19 and 41 Harnett Street
New Hanover, NC
Geosyntec
consultants Figure
Raleigh, NC P P March 2020 2

MW-4 SB-10
r
MW-2/SB-2
SB-3 � SB-9
0
Legend
June 2020 Co -located Soil & Groundwater Sampling Locations
® June 2020 Soil Sampling Location
June 2020 Attempted Groundwater Well Location
Site Parcel Boundary
Notes:
1. Soil borings and monitoring wells were professionally surveyed on 17 June 2020.
A 2. Aerial imagery provided by ArcMap10.5, ESRI
3. Parcel Boundary obtained from New Hanover County, NC online GIS database.
T�
r '
s S'�
1
t
0 50 100 200
300
Feet
Sampling Locations
19 & 41 Harnett Street
New Hanover, NC
Geosyntec°
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3
NC
July 2020

1
MW-4
MW-2/SB-2
MW-1/SB-1
(227,) -
I
Legend
Groundwater Elevation (ft NGVD)
• Groundwater Monitoring Wells
Site Parcel Boundary
Notes:
1. Depth to water measurements were taken at each monitoring well location on 8
June 2020.
2. Aerial imagery provided by ArcMap10.5, ESRI
3. Parcel Boundary obtained from New Hanover County, NC online GIS database.
t -
0 50 100 200 300
Feet
Groundwater Elevations
19 & 41 Harnett Street
New Hanover, NC
GeosMtec® Figure
consultants
Geosyntec Consultants of NC, P.C.
Raleigh, NC July 2020 4

N
Commercial/
Residential
Analyte
Industrial
PSRG
PSRG
r
t
wolo
Benzo(a)pyrene
0.11
2.1
Arsenic
0.68
3
Chromium (VI) 0.31
6.5
SB-6x
Analyte
Result
Benzo a
ene
0.225 J
Arsenic
5.5 SB-5
Chromium (VI)
0.47 U Analyte
Result
SB-2
Benzo a ene
0.414 J
SB-10
Analyte
Result
Arsenic
4.2
Analyte
Result
Benzo(a)pyrene
0.628 J
Chromium (VI)
0.61
Benzo a ene
0.452 J
Arsenic
6.5
Arsenic
4.6
Chromium (VI)
0.50 U
Chromium (VI)
0.46 Ulip
`
1
SB-I
Analyte
Result
Benzo a ene
0.387 J
■
Arsenic
5.5
#
Chromium (VI)
0.57
O
0
f
SB-7
Analyte
Result
Benzo(a)pyrene
0.300 J
SB-4 SB-3
Arsenic
5.6
Analyte
Re s ult Analyte
Result
Chromium (VI)
1.1
Benzo a ene
0.592 J Benzo a ene
0.299 J
SB-8
Arsenic
5.3 Arsenic
7.8
Analyte
Result
Chromium (VI) 0.81 Chromium (VI) 0.96
Benzo a ene
0.266 J
Arsenic
6.3
t.
SB-9
Chromium (VI)
0.44
' ■
w
Analyte
Result
�
r
Benzo a ene
0.602 J
41
Arsenic
4.8
-
Chromium (VI)
1.1
-
Legend
0
50 100 200 300
June 2020 Co -located Soil & Groundwater Sampling Locations
Feet
June 2020 Soil Sampling Location
v Site Parcel Boundary
Soil Analytical Results
3 Notes:
19 & 41 Harnett Street
t. Soil samples were collected on 4 June and 5 June 2020.
2. Only constituents which exceeded one or more North Carolina Department of Environmental Quality
New Hanover, NC
uResidential or Commercial/Industrial Preliminary Soil Remediation Goals (PSRGs, updated December
2019) are shown.
3. mg/kg indicates milligrams per kilogram.
GeOSYC1teC
0 4. Detections that exceeded the Residential health -based PSRG are highlighted in yellow. Detections that
i exceeded the Industrial health -based PSRG are highlighted in orange.
Figure
- 5. J indicates an estimated value.
consultants
= 6. U indicates analyte was not detected above the method detection limit.
GeosymecGousuttantsofNe,ec.
u 7.. indicates a duplicate sample was analyzed and the highest concentration is shown.
r
a. Aerial imagery provided byArcMap10.5, ESRI.
9. Parcel Boundary obtained from New Hanover County, NC online GIs database.
Rate
g h, NC
July 2020
y

N
2L
Analyte Standard
Methyl Chloride 3
Arsenic 10
Chromium 10
a
M W-0
IV
Analyte
Result
Methyl Chloride
0.50 U
M W-02
Arsenic
85.4
MW-04*
Analyte
Result
Chromium
IOU
Analyte
Result
Methyl Chloride
4.4
Methyl Chloride
0.50 U
Arsenic
163
Arsenic
31.9
Chromium
1- U
r 1
Chromium
12.2
�
'Anne
OF P-�
MM v
1■ .
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J-
i
Am-
E
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o� Tom`
_� �V
E Legend 0 50 100 200 300
Groundwater Monitoring Wells Feet
z Site Parcel Boundary
Groundwater Analytical Results
Notes: 19 & 41 Harnett Street
g 1. Groundwater samples were collected on 8 June 2020.
c 2. Only results exceedancing of the Title 15A North Carolina Administrative Code (NCAC) 2L New Hanover, NC
Groundwater Quality Standards (amended April 2013) and the Interim Maximum Allowable
Concentrations (IMAC) are shown.
3. Concentrations are shown in µg/L indicates micrograms per liter. Geosyntee c'
° 4. Analytes that exceeded the NC 2L Groundwater or IMAC Standards are highlighted in blue. Figure
5. Analyte detections are identified in bold. Consultants
t 6. U indicates analyte was not detected above the method detection limit. Geo:ynteccoasmtant:orNc,ec.
7. ' indicates a duplicate sample was analyzed and the highest concentration is shown. c
p 8. Aerial imagery provided by ArcMap10.5, ESRI. Raleigh, NCi JUI 2020 V
9. Parcel Boundary obtained from New Hanover County, NC online GIS database.Y

TABLES

TABLE 1
SAMPLING LOCATIONS AND REQUESTED ANALYSIS
19 and 41 Harnett Street, Wilmington, North Carolina 28401
ASample
Brownfields Project: Almont Shipping II: NCBP No. 23080-19-065
Sample ID
Type
Easting
Northing
Analytical Method
Objective
Soil: Grab samples VOCs by EPA Method 8260; composite samples SVOCs by EPA
Establish baseline conditions and
Method 8270; composite samples organochloride pesticides by EPA Method 8081; and
evaluate soil quality and
composite samples RCRA 8 metals by EPA Method 6010 (including speciation for
Colocated
hexavalent chromium by EPA Method 7199).
management options
MW-1/SB-1
Groundwater/
2317161.66
182569.05
Soil
Evaluate depth to groundwater and
Groundwater: VOCs by EPA Method 8260; SVOCs by EPA Method 8270C; and RCRA
groundwater quality, including
8 metals using EPA Method 6010B, 7470A.
potential migration from up-
gradient/off-site sources
Soil: Grab samples VOCs by EPA Method 8260; composite samples SVOCs by EPA
Establish baseline conditions and
Method 8270; composite samples organochloride pesticides by EPA Method 8081; and
evaluate soil qualand
composite samples RCRA 8 metals by EPA Method 6010 (including speciation for
COIOCated
hexavalent chromium by EPA Method 7199).
management options
s
MW-2/0-2
Groundwater/
2316960.73
182582.90
Soil
Evaluate depth to groundwater and
Groundwater: VOCs by EPA Method 8260; SVOCs by EPA Method 8270C; and RCRA
groundwater quality, including
8 metals using EPA Method 601013, 7470A.
potential migration from up-
gradient/off-site sources
Evaluate depth to groundwater and
MW-4
Groundwater
2316836.69
1$2626.73
Groundwater: VOCs by EPA Method 8260; SVOCs by EPA Method 8270C; and RCRA
groundwater quality, including
8 metals using EPA Method 6010B, 7470A.
potential migration from up-
gradient/off-site sources
Soil: Grab samples VOCs by EPA Method 8260; composite samples SVOCs by EPA
Establish baseline conditions and
SB-3
Soil
2316919.81
182468.15
Method 8270; composite samples organochloride pesticides by EPA Method 8081; and
evaluate soil quality and
composite samples RCRA 8 metals by EPA Method 6010 (including speciation for
hexavalent chromium by EPA Method 7199).
management options
Soil: Grab samples VOCs by EPA Method 8260; composite samples SVOCs by EPA
Establish baseline conditions and
SB-4
Soil
2316757.81
182410.17
Method 8270; composite samples organochloride pesticides by EPA Method 8081; and
evaluate soil quality and
composite samples RCRA 8 metals by EPA Method 6010 (including speciation for
hexavalent chromium by EPA Method 7199).
management options
Soil: Grab samples VOCs by EPA Method 8260; composite samples SVOCs by EPA
Establish baseline conditions and
SB-5
Soil
231720$.03
182676.52
Method 8270; composite samples organochloride pesticides by EPA Method 8081; and
evaluate soil and
composite samples RCRA 8 metals by EPA Method 6010 (including speciation for
hexavalent chromium by EPA Method 7199).
hexavalent
management option
o
options
Soil: Grab samples VOCs by EPA Method 8260; composite samples SVOCs by EPA
Establish baseline conditions and
SB-6
Soil
2317128.45
182636.1
Method 8270; composite samples organochloride pesticides by EPA Method 8081; and
evaluate soil quality and
composite samples RCRA 8 metals by EPA Method 6010 (including speciation for
hexavalent chromium by EPA Method 7199).
management options
Soil: Grab samples VOCs by EPA Method 8260; composite samples SVOCs by EPA
Establish baseline conditions and
SB-7
Soil
2317251.73
182457.49
Method 8270; composite samples organochloride pesticides by EPA Method 8081; and
evaluate soil quality and
composite samples RCRA 8 metals by EPA Method 6010 (including speciation for
hexavalent chromium by EPA Method 7199).
management options
Soil: Grab samples VOCs by EPA Method 8260; composite samples SVOCs by EPA
Establish baseline conditions and
SB-8
Soil
2317147.59
182458.47
Method 8270, composite samples organochloride pesticides by EPA Method 8081; and
evaluate soil quality and
composite samples RCRA 8 metals by EPA Method 6010 (including speciation for
hexavalent chromium by EPA Method 7199).
management options
Soil: Grab samples VOCs by EPA Method 8260; composite samples SVOCs by EPA
Establish baseline conditions and
SB-9
Soil
2317001.89
1 82477.52
Method 8270; composite samples organochloride pesticides by EPA Method 8081; and
evaluate soil and
composite samples RCRA 8 metals by EPA Method 6010 (including speciation for
hexavalent chromium by EPA Method 7199).
hexavalent
management option
o
options
Soil: Grab samples VOCs by EPA Method 8260; composite samples SVOCs by EPA
Establish baseline conditions and
SB-10
Soil
2316860.74
182626.21
Method 8270; composite samples organochloride pesticides by EPA Method 8081; and
evaluate soil quality and
composite samples RCRA 8 metals by EPA Method 6010 (including speciation for
hexavalent chromium by EPA Method 7199).
management options
Notes:
EPA indicates Environmental Protection Agency
VOCs indicates Volatile Organic Compounds
SVOCs indicates Semi -Volatile Organic Compounds
RCRA 8 metals indicates Resource Conservation Recovery Act Metals
Page 1 of 1

Table 2
Monitoring Well Construction Details
19 and 41 Harnett Street
Wilmington, North Carolina
Top of
Measured
Screen
Groundwater
Casing
Depth toElevation
Well ID
Interval
Elevation
Water
(ft BLS)
(ft NGVD)
(ft NGVD)
(ft BTOC)
MW-01
10-20
13.01
10.74
2.27
MW-02
7-17
10.33
8.70
1.63
MW-04
8-18
9.02
6.25
2.77
Notes:
1. ft NGVD indicates elevation in feet according to the National
Geodetic Vertical Datum (NGVD) of 1929.
2. ft BTOC indicates feet below the top of the well casing.
3. Monitoring wells were installed between 4 June and 5 June 2020.
4. Depth to water measurements were collected on 8 June 2020.
5. Monitoring well coordinates and top of casing elevations were
professionally surveyed on 17 June 2020.
Page 1 of 1

Table 3
Soil Analytical Results
19 and 41 Harnett Street
Wilmington, North Carolina
Analyte
NCDEQ
Residential
PSRG
NCDEQ
CommercaiV
Industrlcal
PSRG
Sample ID
SB-01
SB-02
SB-03
SB-04
SB-05
SB-06
DUP-01
(SB-06)
SB-07
SB-08
SB-09
SB-10
Sample Date
6/4/2020
6/4/2020
1 6/4/2020
6/4/2020
1 6/4/2020
6/4/2020
1 6/4/2020
6/4/2020
1 6/4/2020
6/4/2020
1 6/4/2020
Units
Volatile Organic Compounds (VOCs) by EPA Method 8260D
1,2,3-Trichloropropane
0.0051
0.11
mg/kg
0.0011 U
0.061 U
0.00093 U
0.00085 U
0.0011 U
0.0012 U
0.0012 U
0.0011 U
0.0011 U
0.0010 U
0.00089 U
1,2,4-Trimethylbenzene
63
370
mg/kg
0.0029 J
0.049 U
0.00074 U
0.00068 U
0.00087 U
0.00092 U
0.00094 U
0.00086 U
0.00092 U
0.00080 U
0.0016 J
1,2-Dibromoethane
0.038
0.17
mg/kg
0.00088 U
0.049 U
0.00074 U
0.00068 U
0.00087 U
0.00092 U
0.00094 U
0.00086 U
0.00092 U
0.00080 U
0.00071 U
1,3,5-Trimethylbenzene
56
320
mg/kg
0.00088 U
0.049 U
0.00074 U
0.00068 U
0.00087 U
0.00092 U
0.00094 U
0.00086 U
0.00092 U
0.00080 U
0.0011 J
2-Butanone (MEK)
5,500
40,000
mg/kg
0.035
0.36 U
0.0054 U
0.0049 U
0.0281
0.0067 U
0.0365
0.0087 J
0.0203 J
0.0058 U
0.0241
Acetone
12,000
140,000
mg/kg
0.305
4.9 U
0.0935 J
0.068 U
0.146 J
0.144 J
0.29
0.105 J
0.219
0.0908 J
0.225
Ethylbenzene
6.1
27
mg/kg
0.0014 J
0.049 U
0.00074 U
0.00068 U
0.00087 U
0.00092 U
0.00094 U
0.00086 U
0.00092 U
0.00080 U
0.00071 U
Isopropylbenzene
410
1 2,100
mg/kg
0.00098 J
0.049 U
0.00074 U
0.00068 U
0.00087 U
0.00092 U
0.00094 U
0.00086 U
0.00092 U
0.00080 U
0.0035 J
Naphthalene
4.1
18
mg/kg
0.0101
0.239 J
0.0015 U
0.0014 U
0.0017 U
0.0018 U
0.0019 U
0.0017 U
0.0018 U
0.0016 U
0.0122
p-Isopropyltolume
NA
NA
mg/kg
0.106
0.693
0.00098 J
0.00068 U
0.0027 J
0.0011 J
0.0014 J
0.0036 J
0.0164
0.0177
0.0249
Toluene
990
9,700
mg/kg
0.00" J
0.49 U
0.0074 U
0.0071 J
6.0087 U
0.0103 J
0.0121 J
0.0086 U
0.0092 U
0.0080 U
0.0082 J
Xylene (total)
120
530
mg/kg
0.0057 J
0.10 U
0.0016 U
0.0014 U
0.0018 U
0.0019 U
0,0020 U
0.0018 U
0.0019 U
0.0017 U
0.0035 J
emi-volatile Organic Compounds (SVOCs) by EPA Method 8270E
Acenaphthene
720
9,000
mg/kg
0.098 U
0.350 J
0.22 U
0.11 U
0.24 U
0.20 U
0.20 U
0.22 U
0.19 U
0.12 U
0.285 J
Acenaphthylene
NA
NA
mg(kg
0,092 U
0.10 U
0.20 U
0.10 U
0.23 U
0.19 U
0.19 U
0.20 U
0.18 U
0.11 U
0.19 U
Anthracene
3,600
45,000
mg(kg
0.114 J
0.376 J
0.23 U
0.339 J
0.491 J
0.21 U
0.21 U
0.23 U
0.20 U
0.144 J
0.271 J
Bmzo(a)anthracene
1.1
21
mg(kg
0.338 J
0.767 J
0.292 J
0.508 J
0.458 J
0.225 J
0.198 J
0.303 J
0.232 J
0.462 J
0.511 J
Benzo(a)pyrene
0.11
2.1
mg(kg
0.387 J
0.628 J
0.299 J
0.592 J
0.414 J
0.23 U
0.23 U
0.300 J
0.266 J
0.602 J
0.452 J
Benzo(b)fluoranthene
1.1
21
mg(kg
0.586 J
0.923 J
0.366 J
0.972 J
0.561 J
0.263 J
0.298 J
0.401 J
0.394 J
0.935 J
0.558 J
Benzo(g,h,i)perylene
NA
NA
mg/kg
0.268 J
0.376 J
0.21 U
0.319 J
0.259 J
0.20 U
0.20 U
0.212 J
0.199 J
0.530 J
0.214 J
Benzo(k)fluoranthene
11
210
mg/kg
0.214 J
0.339 J
0.27 U
0.289 J
0.30 U
0.25 U
0.25 U
0.27 U
0.24 U
0.282 J
0.25 U
bis(2-Chlormthyl)ether
0.24
1.1
mg/kg
0.11 U
0.12 U
0.24 U
0.12 U
0.26 U
0.22 U
0.22 U
0.24 U
0.21 U
0.13 U
0.22 U
Chrysene
110
2,100
mg/kg
0.428 J
0.776 J
0.2% J
0.781 J
0.476 J
0.20 U
0.1981
0.327 J
0.322 J
0.591 J
0.522 J
Dibenzo(a,h)anthracene
0.11
2.1
mg/kg
0.12 U
0.13 U
0.26 U
0.13 U
0.28 U
0.24 U
0.24 U
0.26 U
0.22 U
0.14 U
0.24 U
Dibenzofuran
15
210
mg/kg
0.092 U
0.133 J
0.20 U
0.10 U
0.23 U
0.19 U
0.19 U
0.20 U
0.18 U
0.11 U
0.19 U
Fluoranthene
480
6,000
mg/kg
0.602 J
2.14
0.484 J
1.06
0.971 J
0.303 J
0.398 J
0.473 J
0.649 J
0.697 J
1.52 J
Fluorene
480
6,000
mg/kg
0.098 U
0.155 J
0.22 U
0.11 U
0.24 U
0.21 U
0.20 U
0.22 U
0.19 U
0.12 U
0.250 J
Hexachlorobenzene
0.22
0.99
mg/kg
0.094 U
0.10 U
0.21 U
0.10 U
0.23 U
0.20 U
0.19 U
0.21 U
0.18 U
0.11 U
0.19 U
Hexachlorocyclopentadiene
0.38
1.6
mg/kg
0.18 U
0.20U_
0.41 U
0.20 U
0.45 U
0.38 U
0.38 U
0.41 U
0.36 U
0.22 U
0.38 U
Indeno(1,2,3-cd)pyrene
1.1
21
mg(kg
0.409 J
0.534 J
0.250 J
0.518 J
0.310 J
0.23 U
0.23 U
0.264 J
0.237 J
0.713 J
0.23 U
N-Nitros xii-n-propylarnine
i 0.078
0.33
mg(kg
0.092 U
0.10 U
0.20 U
0.10 U
0.23 U
0.19 U
0.19 U
0.20 U
0.18 U
0.11 U
0.19 U
Pentachlorophenol
1
4
mg(kg
0.92 U
1.0 U
2.0 U
1.0 U
2.3 U
1.9 U
1.9 U
2.0 U
1.8 U
1.1 U
1.9 U
Phenanthrene
NA
NA
mg(kg
0.342 J
0.708 J
0.312 J
0.290 J
0.507 J
0.19 U
0.19 U
0.237 J
0.353 J
0.325 J
0.815 J
Pyrene
360
4,500
mg/kg
0.613 J
2.06
0.425 J
1.24
0.790 J
0.293 J
0.354 J
0.413 J
0.517 J
0.739 J
1.57 J
Metals by EPA Methods 747111, 6010D,
and 71"
Arsenic
0.68
3
mg(kg
M 5.5
6.5
7.8
5.3
4.2
5.1
5.5
5.6
6.3
4.8
4.6
Barium
3,100
47,000
mg(kg
42 U
55 U
49
46 U
56 U
40 U
38.1
45 L
60.7
53 U
39 U
Chromium
23,000
350,000
mg(kg
14.4
23.9
31.8
16.2
12.7
14.2
15
17.2
14.6
15
14.6
Chromium (VI)
0.31
6.5
mg(kg
0.57
0.50 U
0.96
0.81
0.61
0.47 U
0.45 U
1.1
0.44
1.1
0.46 U
Lead
400
800
mg/kg
55.8
58.9
52.7
49.4
45.1
52.9
51.2
160
126
29.7
43.5
Mercury
2.3
9.7
mg/kg
0.14
0.15
0.15
0.15
0.095
0.16
0.21
0.33
0.25
0.086
0.082
Notes:
1. NC Soil PSRG indicates December 2019 North Carolina Department of Environmental Quality (NCDEQ)
Preliminary Soil Remedialion Goal.
2. EPA indicates United Stales Environmental Protection Agency.
3. U indicates analyse was not detected above the method detection limit.
4.1 indicates an estimated value.
5. mglkg indicates milligrams per kilogram.
6. NA indicates PSRG not established.
7. Analyte detections are identsed in bold.
8. Analytes that were not detected (i.e. concentrations that were below the laboratory Method Detection Limit
1MDL1 I
. but exceeded a PSRG are identified in italics.
9. Analytes that exceeded the Residential health -based PSRG are highlighted in yellow.
10. Analytes that exceeded the Industrial health -based PSRG are highlighted in orange.
11. Only analytes detected in one or more samples are included in this table;
metal concentrations are believed to be consistent with naturally occuring background
and/or anthmpogenic concentrations. Refer to the Risk Calculator output related to
the overall risk evaluation for detected constituents.
12. If multiple screening criteria are exceeded, the highlight corresponds to the highest value screening
criteria exceedance.
Page 1 of 1

Table 4
Groundwater Analytical Results
19 and 41 Harnett Street
Wilmington, North Carolina
Analyte
Groundwater
Standards
Sample ID
MW-Ol
MW-02
MW-04
DUP-01
(MW-04)
Sample Date
6/8/2020
6/8/2020
6/8/2020
6/8/2020
Screen Interval
(ft BLS)
10-20
7-17
8-18
8-18
Units
Volatile Organic Compounds (VOCs) by EPA Method 8260D
Methyl Chloride
3
1
0.50 U
4.4
0.50 U
0.50 U
Iso ro ltoluene
25
1
0.49 J
1.8
0.21 U
0.21 U
sec -But lbenzene
70
Pg1l
0.37 J
0.24 U
0.24 U
0.24 U
tert-But lbenzene
70
Pg11
0.32 J
0.31 U
0.31 U
0.31 U
Semi -volatile Organic Compounds (SVOCs) by EPA Method 8270E
Fluorene 300 1 µg/1 1 0.78 J 1 0.67 U 0.67 U 7.0 U
Metals by EPA Methods 60I01) and 7074A
Arsenic
pgll
1 85.4
163
IOU
31.9
Chromium
10
µg/I
IOU
IOU
IOU
12.2
Lead
15
Pg1l
5.0 U
5.0 U
5.2
8.4
Notes:
1. Groundwater Standards refer to the Title 15A North Carolina Administrative Code (NCAC) 2L Groundwater Quality
Standards, amended in April 2013, and the Interim Maximum Allowable Concentrations.
2. EPA indicates United States Environmental Protection Agency.
3. ft BLS indicates feet below land surface.
4. U indicates analyte was not detected above the method detection limit.
5. J indicates an estimated value.
6. µg/1 indicates micrograms per liter.
7. Analyte detections are identified in bold.
8. Analytes that exceeded the NC 2L Groundwater or IMAC Standards are highlighted in blue.
9. Only analytes detected in one or more samples are included in this table.
Page 1 of 1

APPENDIX A
WELL LOGS

eosyntec s
c011sultattls
Well Construction Log
Well I.D.: AA W -6 I
Drilling Company: (2-Ir X"
Driller: I S
Geologist/En(yineer: Zr to
Geologic Completion Zone: S i f a c c P I
Well Completion Method:
)EPTH BLS
Height of Vault
1
Height of Cash
Grout Top Del
1
rn
Seal Top Dept
Seal Bottom D
r` Screen
Top Depth
1rAtrAn
"1
Screen
ll
Bottom Depth
I
Cat
Total Well Depth
I
Borehole Depth
Notes
INTERVAL LENGTH
1
%2
>'
Riser Pipe
Length
6
i
{'
"
Seal
Length
I
( 'Z
_l
I
�
1
I
Screen
Length
Filter Pack
Length
Sump
Length
1
I
—Borehole`
Diameter
1. Drawing not to scale
2. Units are in feet unless otherwise specified
Comments:
Site: 0 /Ij q0 3 5
Installation Method: t�lR
Casing Installation Date:
Well Type: 't A II
Well Completion
Bollards: ❑ Yes E211�o Date Completion finished:�w
Surface Pad Size: ?—ft x t—ft x �-1 inches thick
Protective Vault or Cover - ❑ None
Diameter: `' inches
Type: eel ❑ Aluminum ❑
Depth BGS: Weep Hole: ❑ Yes ❑ No
Grout- Date: Q I2:1,.2UZiv
Compo lion/Proportions:
/5 Type I/Type II Cement -Bentonite Mix ❑ Other:
Placement Method: ❑ Pressure Tremie • 3ravity ❑ Other:
Seal - Date: UI Itl19L0
Type: 0/3/8" Bentonite Chips ❑ Morie #00 Sand
❑ Coated Bentonite Pellets -Time: ❑ Other:
Source/Brand: e U �'Iu pW 9
Set-up/Hydration Time: 2 h t
Placement Method: ❑ Pressure Tremie Q,191 avity ❑ Other:
Vol. Fluid Added: ❑ gallons ❑ liters ❑ Other:
Filter Pack
Type: orie #2 Sand or equiv. ❑ Morie #1 Sand or equiv.
❑ Gravel ❑ Other:
Source/Brand: T7T1
Amount Used e['bags ❑ pounds 1 tl-
Placement Method: El� Pressure Tremie Cravity�
❑ Other:
Well Riser Pipe
Material: ❑ Schedule 40 PVC - Flush Threaded Joints
❑ Other:
Casing Inside Diameters: ❑ Nominal 2-inch - 2.047-inch I.D.
❑ Nominal 4-inch - 3.998-inch I.D. ❑ Other:
Screen
Material: E�clhedule 40 PVC - Machine Slotted
❑ Other:_
Casing Inside Diameters: ominal 2-inch - 2.047-inch I.D.
❑ Nominal 4-inch - 3.998-inch I.D. ❑ Other:
Screen Slot Size: ©,0110-inch ❑ 0.020-inch ❑ Other:
Percent Open Area: ❑ 3.25% - 2-inch, 0.010 slot ❑ Other:
Sump or Bottom Cap: Et - es ❑ No Length: $ r
Baekfill Plug ❑ Yes 2'50
Material:.❑ Grout ❑ Bentonite
Placement Method: ❑ Pressure "Tremie ❑ Gravity ❑ Other•----
Set-up/Hydration Time:
Total Water Volume During Construction
Introduced: gallons Recovered: gall
forms/Log. Wei IConstruction

Geosyri tec `
ConsultaiiIs
Well Construction Log
Well I.D.: .�
Drilling Company: Ce--ki my)
Driller: T - Cat (, n;t
Geologist/Engineer: a .
Geologic Completion Zone: 5v r y c. l ? t
Well Completion Method:
EPTH BLS
Height of Vault
1
0 Height of Casing
INTERVAL LENGTH
1
Grout Top Depth
j
j
1
Seal Top Depth
Seal 9
Length
Seal Bottom Depth
Screen
Top Depth
il Tu Screen
f I Bottom Depth
►. __..
I
Riser Pipe
Length
I .q i,
1
1
j
1
... �" Screen
Length
Filter Pack
to,Length
....
__.._.....__ _.._
1
( Sum
�
Length
Total Well Depth
oc
i
1 1
Borehole Depth
Borehole`j
Diameter
Notes:
I. Drawing not to scale
2. Units are in feet unless otherwise specified
Comments:
Site: 6-W 3 57
Installation Method: �
Casing Installation Date:
Well Type: t ja$2 it
Well Completion _
Bollards: ❑ Yes 2"Slo Date Completion finished:
Surface Pad Size: eft x L_ ft x 'l inches thick
Protective Vault or Cover - ❑ None
Diameter: 1-1 inches
Type: teel ❑ Aluminum ❑
Depth BGS: Weep Hole: ❑ Yes ❑ No
Grout —Date: U ! Sj 2C ?d
Composition/Proportions:
ED-�_5/5 Type I/Type 11 Cement— Bentonite Mix ❑ Other:
Placement Method: ❑ Pressure Tremie [D-Gravity ❑ Other:
Seal - Date: (c %/�i _GZG_
Type: U-3/8" Bentonite hips ❑Morie #00 Sand
❑ Coated Bentonite Pellets -Time: ❑ Other:
Source/Brand:
Set-up/1-Iydration "Time:
Placement Method: ❑ Pressure Tremic ❑ Gravity ❑ Other:
Vol. Fluid Added: ❑ gallons ❑ liters ❑ Other:
Filter Pack
Type: EDAorie #2 Sand or equiv. ❑ Morie 41 Sand or equiv.
❑ Gravel ❑ Other:
Source/Brand:
Amount Used [D- ags ❑ pounds lt /
Placement Method: ❑ Pressure Tremie ❑ Gravity
❑ Other:
Well Riser Pi
Material: chedule 40 PVC — Flush Threaded Joints
❑ Other:
Casing Inside Diameters: ominal 2-inch — 2.047-inch I.D.
❑ Nominal 4-inch — 3.998-inch I.D. ❑ Other:
Screen
Material: chedule 40 PVC — Machine Slotted
❑ Other:
Casing Inside Diameters: ❑ Nominal 2-inch — 2.047-inch I.D.
❑ Nominal 4-inch —,3,�998-inch I.D. ❑ Other:
Screen Slot Size: 210.010-inch ❑ 0.020-inch ❑ Other:
Percent Open Area: ❑ 3.25% - 2-inch, 0.010 slot ❑ Other:
Sump or Bottom Cap: ❑ Yes ❑ No Length:
Backfill Plug ❑ Yes a<o
Material: ,❑ Grout ❑ Bentonite
Placement Method: ❑ Pressure Tremie ❑ Gravity ❑ Other:
Set-up/1-lydration 'Time:
Total Water Volume During Construction
Introduced: gallons Recovered: gallons
forms/Log. W el l Construction

Geosytec"
Consultants
Well Construction Log
Well I,D„ M V 2-
Drilling Company:
Driller: Qav : vv. i W-ev 5
Geologist/Engineer: ✓ec 11
Geologic Completion Zone: ., r a c y z• t
Well Completion Method:
PTH BLS
Height of Vault
Height of Casing
V
Grout Top Depth ,;,- y,
�
�i
Seal Top Depth
! 9 1
INTERVALLENGTH
d� 1
Seal i t f
Length
�Y
Seal Bottom Depth "?,:....._...._ �........._....
fq 1( Screen
.1, Top Depth
e cf 1, Screen
�� I Bottom Depth
Total Well Depth
1
Borehole Depth
Borehole
Diameter
Notes:
1. Drawing not to scale
2. Units are in feet unless otherwise specified
Comments:
I
i
Riser Pipe
Length
�t�r<
Site: U N -10 3
Installation Method: 14 S a
Casing Installation Date:
Well Type: T(q it
Well Completion
Bollards: ❑ Yes ©"No Date Completion finished:W's-i" e-C
Surface Pad Sire: 7— ft x 2 ft x �1 inches thick
Protective Vault or Cover - ❑ None
Diameter: I inches
Type: [.Steel ❑ Aluminum ❑
Depth BGS: Weep Hole: ❑ Yes ❑ No
Grout — Date: U f �3[12 i'ZO
Composition/Proportions:
E;4K/5 Type I/Type 11 Cement — Bentonite Mix ❑ Other:
Placement Method: ❑ Pressure Tremie Qfar`avity ❑ Other:
Seal - Date UN I ZoU-
Type: �8 B en o t❑ Morie #00 Sand
❑ Coated Bentonite Pellets -Time: ❑ Other:
Source/Brand: C—nJ � rc .7 ("9
Set-up/Hydration Time: Z inr
Placement Method: ❑ Pressure Tremie ,cavity ❑ Other:
Vol. Fluid Added: ❑ gallons ❑ liters ❑ Other:
Filter Pac
'Type: orie #2 Sand or equiv. ❑ Morie # 1 Sand or equiv.
❑ Gravel ❑ Other:
Source/Brand: 7 5 -S
Amount Used ❑ hags ❑ pounds ' ''<
Placement Method: ❑ Pressure Tremie Qjravity
❑ Other:
Well Riser Pipe
Material: ❑ Schedule 40 PVC — Flush Threaded Joints
❑ Other:
Casing Inside Diameters: ❑ Nominal 2-inch — 2.047-inch LD
❑ Nominal 4-inch — 3.998-inch I.D. ❑ Other:
Screen
Material: chedule 40 PVC — Machine Slotted
❑ Other:
Casing Inside Diameters: ominal 2-inch — 2.047-inch L13.
❑ Nominal 4-inch — 3.998-inch L.D. ❑ Other:
Screen Slot Size: E 0.010-inch ❑ 0.020-inch ❑ Other:
Percent Open Area: ❑ 3.25% - 2-inch, 0.010 slot ❑ Other:
Sump or Bottom Cap: 0-yes ❑ No Length: 3"
Backfill Plug ❑ Yes 2-�o
Material: _❑ Grout ❑ Bentonite
Placement Method: ❑ Pressure Tremie ❑ Gravity ❑ Other:
Set-up/Hydration "Time:
Total Water Volume During Construction
Introduced: gallons Recovered: gallons
forms/Log. WCIICOn StrLICtlo❑

APPENDIX B
FIELD FORMS

Page __Lof 4
Gelosyntec""
Pa
Written by: � �v Date: _//_ Reviewed by: --Date: � /�{ / _
consultants
DID MM YY DD MM YY
s}g q�
Client: C''� � S Project: Project/Proposal No. Task No.
-
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Written by: ' Date;
Reviewed by:
gg,.�
Date: �. / Z 12�
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consultants DIDMIAYY
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DD MM YY
Client: ` l Project:
Project/Proposal No.
Task No.
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consultants
Client: Project:
C bL 44-
64
Date; /_ Reviewed by: Date:5 _/_(P /IC
DD MM YY DD MM YY
Project/Proposal No. Task No.
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Date: _/_/_ Reviewed by:
DD MM YY
Page L of L..
Date: 5-/- (L/
DID MM YY
Client: Project: Project/Proposal No. Task No.
H

Ge®S tec
consultants
Geosyntee Consultants
Pre -Work Safety Brief
Contact Personnel:
Contact Number: �_U C , Q r Lt6
Date: �i (L t) z-,>
Time: 0
Project name:
Lit
Project Number:
Work Location: a �✓,
Scope of Work t
t,stn�o
HASP / THA review t j p c t s i S, S y -d 5
PPE Requirements
k • _ (� ��.4c c a� e4A
Other
Personnel Sign -in List
Printed Name and Company (if not Geosyntec)
Signature
c
q•�r:Ci C CC,

METER CALIBRATION
Project Name: C'7
Project Number:
PIDs
Date:_` 4 Z-
Weather:
Geosyntec'%
consultants
geosyntec.com
Recorded Bye_ V-)I �e�? Page V of
PrimaryActivities: Sa o S
Serial Number
Ambient Air (ppm) I00ppm Isobutylene (ppm)
Initial Time: U`��-tj
3 2--------------------------------------------------------------------------------- `�
Final Time: ---------
Initial Time:
Final Time: ----- -------------------------------------
Ini_tial Time:
------------------------------------------------
----------------------------------------
inalTime: _______
Initial Time:
-------------- ------- -------------------------------------------
-----
mal Time:
GEMs
Serial
Ambient Air
Calibration Gas
Ambient Air
CH4(%) CO,(%) 02(%)
Initial Time:
-------------------------- ---------------
---------------- --------------- -----
----
malTime: --------------- ----------------
Initial Time:
--------------------------- -
-------------- ----------------
FinalTime: ----------------
Initial Time:
ina ime:
---------------- ---------------
---------------- ---------------
Initial Time:
------------------------------
-------------
CH4(%) I CO,(%) I 0a(%)
CH4(%) I COZ(%) I 0z(%)

METER CALIBRATION
Project NameL- I--, �l`)
Project Number:
PIDs
GEMS
Serial
Date:
Weather:
Geosyntec'%
consultants
Q goosyntec.com
Recorded By " i ` ' C Page t of l
PrimaryAetivities• Ste:
Serial Number
Ambient Air (ppm) 100 m Isobu lene m PP tY (PP )
�� � -Initial Time: L �s
------------------------------- - C( �v
° •-
Final Time: ___________________
----------------------
Initial Time:
--------- --- ---- ----
Initial Time:
---------------------------------------- -
------------------------------------------
Initial Time:
-------------------------------------------------------------------------------------------- -------------------------
Final Time:
Ambient Air
Calibration Gas
Ambient Air
CH,(%) CO,(%) oz(%) CH,(%) Coz(%) oz(%) CH,(%) CO,(%) 02M
Initial Time:
----------------------------
--------------- ----------------
---------------- tnalTime: --------------- ----------------
Initial Time:
------------------------------- - -------------- ---------------- Final Time:
--------------- •------------------------------ ----------------
Initial Time:
-------------
-- ----------------
Final Time:
--------------- --------------- ----------------
Initial Time:
--------
---------------- -------------------------------

Geosyntec Consultants
Water Level Form
Site:. Project No..
Date
Weather
Field Personnel 2-S
Equipment Model #
Nntee
Geosyntec '
Consultants
Page t of—k--
Measurement Odor / Product Thickness)
Well ID Well Condition Measurement Location Depth to Water Depth to Bottom / Comments
feet I feet

Geosyntee Consultants Geosyiltec
Groundwater Sampling Log con,;( mlli,
Project Name: _A �) k 3 Location:
t
Project Number: Phase/Task:
Date: (ti e JuZo
Personnel: 0 �0- r vg
Well ID: N1- VQ A 61 Screen Interval (ft) i Q -S I - DTW (ft) / t�
Pump/Tubing Setting (ft) — t 5-1 DTB (ft) 1 q .V-*-I
Well Diameter (in) `` Depth To Product (ft)
Tubing Diameter (in)
Water Quality Meter Model #: 3 Jt6cf Measurement Location: 'Cu C
Specific Purge Rate Sp
Time (mL/min) DTW (ft) pH (S. U) Conductance Temp (°C)
�iS/cns)
Turbidity
(NTU) ORP (n?V) DO (mg/L) Comments
Z- (3(;�7C! a1(46zim-
134wu A Z 7 - i
3,q iY -Cl 3 .4's @ -Cl °j
�aS 'tiyv
S k 6i 1,7- 0cb!�-
Stabilization Criteria EPA Region 4 ASTMD 6771-02
pH 0.1 0.2�lt
Sp. Cond. 5% 3%
Turbitiy 10% or <10 NTU none
DO 10% or 0.2 mg1L 10% or 0.2 mg/L
ORP none 20 mV
Sample ID with Time and Analysis
W
V
Well Volume = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) x WELL CAPACITY
feet - ttq . feet) x 6,10 gallons/foot = gal
Well Capacity (gallons/foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88
Equipment Volume = (TUBING CAPACITY x TUBING LENGTH) + FLOW CELL VOLUME
_ ( gal/ft x ft) +
gallons = gallons
do
Tubing Inside Dia. Capacity (gal/ft): 1/8" = 0.0006; 3/16" = 0.0014; 1/4"
= 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" =

Geosyntec Consultants
Groundwater Sampling Log
Geosyntec
conskillam's
Project Name:_ 6 P -�O 3 S
Project Number:
Location:
Phase/Task:
Date: ut � otcuo,,
Personnel: e Qe ew,
Well ID: 0
/ Screen Interval (ft) Aar- t(A U DTW (ft) 71o'
y�K) -2 Pump/Tubing Setting (ft) 4.,J 7, DTB (11) q Z
Well Diameter (in) Z i( Depth To Product (ft)
Tubing Diameter (in) '41
Water Quality Meter Model #: �Iqq Measurement Location:--tOC
Time
Purge Rate
(mLlmin)
D T W (ft) pH (S. U.)
Spec�fic
Conductance Temp (Q
wv/s/cfn)
Turbidity
(NTU)
ORP(mV) DO(mglL) Comments
Zocy
C-7
C, - ef 7-
S'- 4 2-3-O
S
get, Q
11
J
Z, '5
'31
OYL-�
Stabilization CriteriTaEPA
pH
Sp. Cond.
Turbitiy
DO
ORP
Region 4
0.1
5%
10% or <10 NTU
10% or 0.2 mg1L
none
ASTM D 6771-02
0.2
3%
none
10% or 0.2 mg1L
20mV
Sample ID with Time and Analysis
Z-

Geosyntec Consultants GeosynteC '
Groundwater Sampling Log conmilmnif,
Project Name: �J N —�o 35Location:
Project Number: Phase/Task:
Date: 4.L'd tuU
Personnel: 6 C',
Well ID: �tkw -- 0 't Screen Interval (ft) #'I -a ._ -q DTW (ft) Ua T <5-
Pump/Tubing Setting (ft) i Z r DTB (ft) IT-4 Z
Well Diameter (in) ?— Depth To Product (ft) ,t+..A_
Tubing Diameter (in) 1/t1
Water Quality Meter Model #: !J SCA Measurement Location: t CJ
Purge Rate Specific
Time D T W (ft) pH (S. U.n ) Conductace Temp (°C)
(mLhnin)
PyiS/cm)
Tz(NTU )
ORP (nzV) DO (mg/L) Comments
1 Kir t vc
iutly ZS" 30 ,2 i 1 t Z S,=i
do "2s -"t 0,7,Lo
- 0 i3 ci -Zs 2
•I4
t�6 , fir 1-3
Stabilization Criteria EPA Region 4 ASTMD 6771-02
pH 0.1 0.2
Sp. Cond. 5% 3%
Turbitiy 10% or <10 NTU none
DO 10% or 0.2 mg1L 10% or 0.2 mg1L
ORP none 20 mV
Sample ID with Time and Analysis
r; A vJ •-OLA to �' a r v�
iJ y 6,v,, V lre
5 &m 1 z
�J � e � � `
Well Volume = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) x WELL CAPACITY
feet - (,� Z feet) x0.( gallons/foot = 1 r to gal
Well Capacity (gallons/foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3"
= 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88
Equipment Volume = (TUBING CAPACITY x TUBING LENGTH) + FLOW CELL VOLUME
_ ( gal/ft x ft) +
[Tubing
gallons = gallons
Inside Dia. Capacity (gal/ft): 1/8" = 0.0006; 3/16" = 0.0014; 1/4"
= 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.

SGS North America Inc - Orlando
Rf Chain of Custody
4405 Vineland Road. Suite G15 Orlando-F132R11
SGS - ORLANDO JOB #: PAGE t OF
,WNW 1WENEW
TEL.[phone] FAX: [phone]
ww v 'I"com
SGS - ORLANDO Quote #
SKIFF #
Client / Reporting Information
Project Information
Analytical Information'
Matrix Codes
Company Name: jr
Project Name: /
a
(--
°
nn mg
Water
GW - Ground
Water
WW - Water
SW -Surface
Water
SO -Soil
SL- Sludge
Address: f
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-
Street
City: a >: Zip:
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I State
Pro' ct Conta t: 5 ° Email:
Pro'ect #
Phone #:
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Fax #
j,
OI - oil
LIQ - Other Liquid
Samplers) Name(s)�(Printed)
-
Client Purchase Order #
Ir
Sam ler 1: t"1 a -a- 'C Sam ler 2:
„
rs>
i
AIR - Air
SOL -Other Solid
COLLECTION
CONTAINER
INFORMATION
TOTAL#
F
SGS
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j
Orlando
SAMPLED
OF
M
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0
0
3
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Sample #
Field ID / Point of Collection
DATE
TIME
BY:
MATRIX
BOTTLES
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Turnaround Time ( Business days)
Data Deliverable Information
Comments /
Remarks
16- (Busmes5) Approved By: / Date:
COMMERCIAL A" -'(RESULTS ONLY)
a -tR�- b ( F" - ,
7 —Day—
DG.OMMERCIAL "B" (RESULTS PLUS QC)
F f —
r -
O Av r%vc,
5 Day
[]REDT1 (EPA LEVEL 3)
3 Day RUSH
[]FULLT1 (EPA LEVEL 4)
2 Day RUSH
FIEDD'S
1 Day RUSH
Other
Rush T/A Data Available VIA Email or Lablink
Sample Custody must be documented below each time samples change possession, including courier delive
Relinq d&by Sampler/Affiliation
Date Time:
Received By/Affiliation
Relinquished By/Affiliation
Date Time:
Received By/Affiliation
1 � � �
y
c, j2
3
4
Relingl"iished by/Affiliation
Date Time:
Received By/Affiliation
Relinquished By/Affiliation
Date Time:
Received By/Affiliation
5
6
7
18
Lab Ilse Only : Cooler Temperature (s) Celsius (corrected): http://www.sgs.com/en/terms-and-conditions
0RLD-SMT-0001-03-FORM-COC (4).xls Rev 031318

SGS North America Inc - Orlando
r. R, Chain of Custody
ddni v;-6-1 R—I Cnirr ('-I i r ,1—in F1 ,11ZI I
SGS - ORLANDO JOB #: PAGE I OF I
TEL. [phone] FAX: [phone]
www.sesxom
SGS - ORLANDO Quote #
SKIFF #
Client / Reporting Information
Project Information
Analytical Information
Matrix Codes
Company Name:
47 v? s Yi - s
Project Name: ; - -
�
r
7
Drinking
Water
GW - Ground
Water
WW - Water
SW -Surface
Water
SO - Soil
SL- Sludge
OI - Oil
LIQ - Other Liquid
Address: (�
Street
City: State: Zip:I
State
Rioject Co tact: s, Email:
Project #
Phone #: a 3,
s� k " S0 Rj�
Fax #
Sampler(s) N mr�s) (Printed)
Client Purchase Order #
Sampler 1: �e-- t Sampler 2:
,I,(,.
1
Q
Q3,
AIR - Air
SOL - Other Solid
COLLECTION
CONTAINER
INFORMATION
SAMPLED
TOTAL
OF «
w
=
w
z
=
o
o
O
N
=
0
¢
3
=
0
SGS
Orlando
r-
Sample #
Field ID / Point of Collection
DATE
TIIMM9E
BrY:
MATRIX
BOTTLES
0
�
=y
z
=
i
z
p
�
LAB USE ONLY
yy
l �ii
C.))- m
j M
�)p+—
,y ",e�a!m✓, .'.•'b_O';.1 ,"s'•
^Aj
*S g A `"
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aT X i 4
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3 15
; iRs
g
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g
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—F
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+Comments/
Turnaround Time (Business days)
Data Deliverable Information
Remarks
10 Day (Business) Approved By: / Date:
FICOMMERCIAL "A" (RESULTS ONLY)
7 Day
COMMERCIAL "B" (RESULTS PLUS QC)
C
5 Day
FIREDT1 (EPA LEVEL 3)
3 Day RUSH
Q FULLT1 (EPA LEVEL 4)
2 Day RUSH
EDD'S
1 Day RUSH
Other
Rush T/A Data Available VIA Email or Lablink
Sample Custody must be documented below each time sam les change possession, including courier delivery.
RelinquN ed by Sa pler/Affiliation
Date Time:
Received By/Affiliation
Relinquished By/Affiliation
Date Time:
Received By/Affiliation
60i
2
3
4
Relincluishe-d"bylAffiliation
Date Time:
Received By/Affiliation
Relinquished By/Affiliation
Date Time:
Received By/Affiliation
5
6
7
18
Lab Use Only : Cooler Temperature (s) Celsius (corrected): http://www.sgs.coM/en/terms-and-conditions
ORLD-SMT-0001-03-FORM-COC (4).xls Rev 031318

%I SGS North America Inc - Orlando
R r. I Chain of Custody
SGS - ORLANDO JOB #: PAGE I OF I
TEL.4o7-425-67oo FAX: 407a25-0707
w��wsas.com
SGS - ORLANDO Quote #
SKIFF #
Client / Reporting Information Project Information
Analytical Information
Matrix Codes
Company Name: ",
f oI 4
Project Name: f/' �- { , � �"
s 3' '
Drinking
g
Water
GW - Ground
Water
WW - Water
SW -Surface
Water
L- - Soil
SL- Sludge
OI - Oil
LIQ - Other Liquid
AIR -Air
SOL - Other Solid
Address: ,.,
/,.L: i ' i j'„n" °
Street
City: g State: j\j Zip: ZALaji
ulty State
Pjoject Contact: p Email:
��,�''4. '{, k� fK` +�C ✓� t/} _,c {�.5.. ` , 4ai tet)"�i '%i ,o+M'�L'.=.'
Project #
$' R
Phone #: °
� � ,._� _ j. �, �
Fax #
Sampler(s) Narug(s) (Printed)
Sampler 1:' • ° �- c sT^ Sampler 2:
Client Purchase Order #
SGS
Orlando
Sample #
Field ID / Point of Collection
COLLECTION
CONTAINER
INFORMATION
DATE
fTVOE
SAMPLED
BY:
MATRIX
TOTAL#
OF
BOTTLES
=
~O
z
Oz
=
p
z
O
z
i
N
0
z
to
3
—p
O
LAB USE ONLY
CS
ce,a,
66 ryy
>ty�"�tg,�r
t -
b6A
3
-y�
Turnaround Tune (Business days)
Data Deliverable Information
Comments /
Remarks
w�9 fiat (Business] f Approved By: /Date:
7 Day
5 Day
3 Day RUSH
2 Day RUSH
1 Day RUSH
Other
Rush T/A Data Available VIA Email or Lablink
FIC.�O,�M, MERCIAL "A" (RESULTS ONLY)
[D"OMMERCIAL "B" (RESULTS PLUS QC)
FIREDT1 (EPA LEVEL 3)
F]FULLT1 (EPA LEVEL 4)
FIEDD'S
Sample Custody must be documented below each time samples change possession, including courier delivery.
ish d by S?mpler/ ffiliation
Reli7ZL2
1 I/ tom. ✓ _ -
Date Time:
P I �_ G 0 )mot '
Received By/Affiliation
2
Relinquished By/Affiliation
3
Date Time:
Received By/Affiliation
4
Relingyjstr6d by/Affiliation
5
Date Time:
Received By/Affiliation
6
Relinquished By/Affiliation
7
Date Time:
Received By/Affiliation
8
Lab Use Only : Cooler Temperature (s) Celsius (corrected): http://www.sgs.com/en/terms-and-conditions
URLD-SM l-UUU1-U3-rURM-GUG (4).XIS Rev U3131 H

APPENDIX C
LABORATORY ANALYTICAL
REPORTS

Orlando, FL
The results set forth herein are provided by SGS North America Inc. a-Hl ydcopy 2. 0
Automated Report
Technical Report for
Geosyntec Consultants
31 Harnett, Wilmington, NC
GN 7035
SGS Job Number: FA75651
Sampling Date. 06/04/20
Report to:
Geosyntec Consultants
701 N Franklin St Suite 501
Wilmington, NC 28401
[e-mail]; KRhonehouse@Geosyntec.
TTN: Brendon Peach
Total number of pages in report: 177
/V __C' .
' za'(A�
qe0 0�
Test results contained within this data package meet the requirements Cai tl i n Br I ce, M . S.
of the National Environmental Laboratory Accreditation Program General M anager
and/or state specific certification programs as applicable.
Client Service contact: Jean Dent -Smith 407-425-6700
Certifications: FL(E83510), LA(03051), KS(E-10327), IL(200063), NC(573), NJ(FL002), NY(12022), SC(96038001)
DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177),
AK, AR, IA, KY, MA, MS, ND, NH, NV, OK, OR, UT, WA, WV
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc. • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: [phone] • fax: [phone]
SGS is the sole authority for authorizing edits or modifications to this document. Please share your ideas about
Unauthorized modification of this report is strictly prohibited. how we can serve you better at:
Review standard terms at: http://www.sgs.com/en/terms-and-conditions [e-mail]
1 of 177
FA75651

Sections:
Table of Contents
-I-
Section1: Sample Summary...................................................................................................
3
Section2: Summary of Hits....................................................................................................
4
Section3: Sample Results.......................................................................................................
3.1: FA75651-1: SB-01........................................................................................................
11
3.2: FA75651-2: SB-02........................................................................................................
20
3.3: FA75651-3: SB-03........................................................................................................
29
3.4: FA75651-4: SB-04........................................................................................................
38
3.5: FA75651-5: SB-05........................................................................................................
47
3.6: FA75651-6: SB-06........................................................................................................
56
3.7: FA75651-7: SB-07........................................................................................................
66
3.8: FA75651-8: SB-08........................................................................................................
75
3.9: FA75651-9: SB-09........................................................................................................
84
3.10: FA75651-10: SB-10....................................................................................................
93
3.11: FA75651-11: DUP-01.................................................................................................
102
3.12: FA75651-12: TRIP BLANK.......................................................................................
111
Section4: Misc. Forms............................................................................................................
113
4.1: Chain of Custody...........................................................................................................
114
Section 5: MS Volatiles - QC Data Summaries.....................................................................
116
5.1: Method Blank Summary................................................................................................
117
5.2: Blank Spike Summary...................................................................................................
123
5.3: Matrix Spike/Matrix Spike Duplicate Summary...........................................................
129
Section 6: MS Semi-volatiles - QC Data Summaries............................................................
132
6.1: Method Blank Summary................................................................................................
133
6.2: Blank Spike Summary...................................................................................................
139
6.3: Matrix Spike/Matrix Spike Duplicate Summary...........................................................
145
Section 7: GC/LC Semi-volatiles - QC Data Summaries.....................................................
148
7.1: Method Blank Summary................................................................................................
149
7.2: Blank Spike Summary...................................................................................................
150
7.3: Matrix Spike/Matrix Spike Duplicate Summary...........................................................
152
Section 8: Metals Analysis - QC Data Summaries................................................................
153
8.1: Prep QC MP37368: Hg..................................................................................................
154
8.2: Prep QC MP37382: As,Ba,Cd,Cr,Pb,Se,Ag..................................................................
160
8.3: Prep QC MP37396: Hg..................................................................................................
166
Section 9: Misc. Forms (SGS Dayton, NJ).............................................................................
171
9.1: Chain of Custody...........................................................................................................
172
Section 10: General Chemistry - QC Data (SGS Dayton, NJ) .............................................
174
10.1: Method Blank and Spike Results Summary................................................................
175
10.2: Duplicate Results Summary........................................................................................
176
10.3: Matrix Spike Results Summary...................................................................................
177
01
2 of 177
FA75651

SGS North America Inc.
Sample Summary
Geosyntec Consultants
31 Harnett, Wilmington, NC
Project No: GN7035
Job No: FA75651
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
This report contains results reported as ND = Not detected. The following applies:
Organics ND = Not detected above the MDL
FA75651-1
06/04/20
13:55 BP
06/06/20
SO
Soil
SB-01
FA75651-2
06/04/20
09:10 BP
06/06/20
SO
Soil
SB-02
FA75651-3
06/04/20
11:30 BP
06/06/20
SO
Soil
SB-03
FA75651-4
06/04/20
08:30 BP
06/06/20
SO
Soil
SB-04
FA75651-5
06/04/20
08:30 BP
06/06/20
SO
Soil
SB-05
FA75651-6
06/04/20
16:20 BP
06/06/20
SO
Soil
SB-06
FA75651-7
06/04/20
13:00 BP
06/06/20
SO
Soil
SB-07
FA75651-8
06/04/20
13:30 BP
06/06/20
SO
Soil
SB-08
FA75651-9
06/04/20
11:50 BP
06/06/20
SO
Soil
SB-09
FA75651-10
06/04/20
11:05 BP
06/06/20
SO
Soil
SB-10
FA75651-11
06/04/20
16:30 BP
06/06/20
SO
Soil
DUP-01
FA75651-12
06/04/20
00:00 BP
06/06/20
SO
Trip Blank Soil
TRIP BLANK
Soil samples reported on a dry weight basis unless otherwise indicated on result page.
6 3of177
FA75651

Summary of Hits
Job Number:
FA75651
Account:
Geosyntec Consultants
Project:
31 Harnett, Wilmington, NC
Collected:
06/04/20
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA75651-1 SB-01
Page 1 of 6
Acetone a
305
180
88
ug/kg
SW846 8260D
2-Butanone (MEK) a
35.0
22
6.4
ug/kg
SW846 8260D
Ethylbenzene a
1.4 J
4.4
0.88
ug/kg
SW846 8260D
Isopropylbenzene a
0.98 J
4.4
0.88
ug/kg
SW846 8260D
p-Isopropyltoluene a
106
4.4
0.88
ug/kg
SW846 8260D
Naphthalene a
10.1
4.4
1.8
ug/kg
SW846 8260D
Toluene a
9.9 J
18
8.8
ug/kg
SW846 8260D
1,2,4-Trimethylbenzene a
2.9 J
4.4
0.88
ug/kg
SW846 8260D
m,p-Xylene a
4.1 J
8.8
0.96
ug/kg
SW846 8260D
o-Xylene a
1.6 J
4.4
0.88
ug/kg
SW846 8260D
Xylene (total) a
5.7 J
13
1.8
ug/kg
SW846 8260D
Anthracene b
114 J
920
100
ug/kg
SW846 8270E
Benzo(a)anthracene b
338 J
920
92
ug/kg
SW846 8270E
Benzo(a)pyrene b
387 J
920
110
ug/kg
SW846 8270E
Benzo(b)fluoranthene b
586 J
920
100
ug/kg
SW846 8270E
Benzo(g,h,i)perylene b
268 J
920
95
ug/kg
SW846 8270E
Benzo(k)fluoranthene b
214 J
920
120
ug/kg
SW846 8270E
Chrysene b
428 J
920
94
ug/kg
SW846 8270E
Fluoranthene b
602 J
920
92
ug/kg
SW846 8270E
Indeno(1,2,3-cd)pyrene b
409 J
920
110
ug/kg
SW846 8270E
Phenanthrene b
342 J
920
92
ug/kg
SW846 8270E
Pyrene b
613 J
920
110
ug/kg
SW846 8270E
Arsenic °
5.5
2.1
mg/kg
SW846 6010D
Chromium °
14.4
2.1
mg/kg
SW846 6010D
Lead e
55.8
4.2
mg/kg
SW846 6010D
Mercury
0.14
0.042
mg/kg
SW846 7471B
Chromium, Hexavalent d
0.57
0.46
mg/kg
SW846 3060A/7199
FA75651-2 SB-02
p-Isopropyltoluene e
693
250
49
ug/kg
SW846
8260D
Naphthalene e
239 J
250
98
ug/kg
SW846
8260D
Acenaphthene b
350 J
1000
110
ug/kg
SW846
8270E
Anthracene b
376 J
1000
110
ug/kg
SW846
8270E
Benzo(a)anthracene b
767 J
1000
100
ug/kg
SW846
8270E
Benzo(a)pyrene b
628 J
1000
120
ug/kg
SW846
8270E
Benzo(b)fluoranthene b
923 J
1000
110
ug/kg
SW846
8270E
Benzo(g, h, i)perylene b
376 J
1000
100
ug/kg
SW846
8270E
Benzo(k)fluoranthene b
339 J
1000
130
ug/kg
SW846
8270E
Chrysene b
776 J
1000
100
ug/kg
SW846
8270E
Dibenzofuran b
133 J
1000
100
ug/kg
SW846
8270E
Fluoranthene b
2140
1000
100
ug/kg
SW846
8270E
Fluorene b
155 J
1000
110
ug/kg
SW846
8270E
6 4 of 177
FA75651

Summary of Hits
Job Number:
FA75651
Account:
Geosyntec Consultants
Project:
31 Harnett, Wilmington, NC
Collected:
06/04/20
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
Indeno(1,2,3-cd)pyrene b
534 J
1000 120
ug/kg
SW846 8270E
Phenanthrene b
708 J
1000 100
ug/kg
SW846 8270E
Pyrene b
2060
1000 120
ug/kg
SW846 8270E
Arsenic °
6.5
2.7
mg/kg
SW846 6010D
Chromium °
23.9
2.7
mg/kg
SW846 6010D
Lead °
58.9
5.5
mg/kg
SW846 6010D
Mercury
0.15
0.049
mg/kg
SW846 7471B
FA75651-3 SB-03
Page 2 of 6
Acetone a
93.5 J
150
74
ug/kg
SW846 8260D
p-Isopropyltoluene a
0.98 J
3.7
0.74
ug/kg
SW846 8260D
Benzo(a)anthracene b
292 J
2000
200
ug/kg
SW846 8270E
Benzo(a)pyrene b
299 J
2000
240
ug/kg
SW846 8270E
Benzo(b)fluoranthene b
366 J
2000
220
ug/kg
SW846 8270E
Chrysene b
296 J
2000
210
ug/kg
SW846 8270E
Fluoranthene b
484 J
2000
200
ug/kg
SW846 8270E
Indeno(1,2,3-cd)pyrene b
250 J
2000
250
ug/kg
SW846 8270E
Phenanthrene b
312 J
2000
200
ug/kg
SW846 8270E
Pyrene b
425 J
2000
240
ug/kg
SW846 8270E
Arsenic °
7.8
2.3
mg/kg
SW846 6010D
Barium °
49.0
46
mg/kg
SW846 6010D
Chromium °
31.8
2.3
mg/kg
SW846 6010D
Lead °
52.7
4.6
mg/kg
SW846 6010D
Mercury
0.15
0.046
mg/kg
SW846 7471B
Chromium, Hexavalent d
0.96
0.48
mg/kg
SW846 3060A/7199
FA75651-4 SB-04
Toluene a
7.1 J
14
6.8
ug/kg
SW846 8260D
Anthracene b
339 J
1000
110
ug/kg
SW846 8270E
Benzo(a)anthracene b
508 J
1000
100
ug/kg
SW846 8270E
Benzo(a)pyrene b
592 J
1000
120
ug/kg
SW846 8270E
Benzo(b)fluoranthene b
972 J
1000
110
ug/kg
SW846 8270E
Benzo(g,h,i)perylene b
319 J
1000
100
ug/kg
SW846 8270E
Benzo(k)fluoranthene b
289 J
1000
130
ug/kg
SW846 8270E
Chrysene b
781 J
1000
100
ug/kg
SW846 8270E
Fluoranthene b
1060
1000
100
ug/kg
SW846 8270E
Indeno(1,2,3-cd)pyrene b
518 J
1000
120
ug/kg
SW846 8270E
Phenanthrene b
290 J
1000
100
ug/kg
SW846 8270E
Pyrene b
1240
1000
120
ug/kg
SW846 8270E
Arsenic °
5.3
2.3
mg/kg
SW846 6010D
Chromium °
16.2
2.3
mg/kg
SW846 6010D
Lead °
49.4
4.6
mg/kg
SW846 6010D
Mercury
0.15
0.047
mg/kg
SW846 7471B
6 5 of 177
FA75651

Summary of Hits
Job Number:
FA75651
Account:
Geosyntec Consultants
Project:
31 Harnett, Wilmington, NC
Collected:
06/04/20
:.ab Sample ID Client Sample ID Result/
knalyte Qual RL MDL Units Method
Page 3 of 6
Chromium, Hexavalent d 0.81 0.47 mg/kg SW846 3060A/7199
FA75651-5 SB-05
Acetone a
146 J
170
87
ug/kg
SW846 8260D
2-Butanone (MEK) a
28.1
22
6.3
ug/kg
SW846 8260D
p-Isopropyltoluene a
2.7 J
4.3
0.87
ug/kg
SW846 8260D
Anthracene b
491 J
2300
250
ug/kg
SW846 8270E
Benzo(a)anthracene b
458 J
2300
230
ug/kg
SW846 8270E
Benzo(a)pyrene b
414 J
2300
270
ug/kg
SW846 8270E
Benzo(b)fluoranthene b
561 J
2300
250
ug/kg
SW846 8270E
Benzo(g, h, i)perylene b
259 J
2300
230
ug/kg
SW846 8270E
Chrysene b
476 J
2300
230
ug/kg
SW846 8270E
Fluoranthene b
971 J
2300
230
ug/kg
SW846 8270E
Indeno(1,2,3-cd)pyrene b
310 J
2300
270
ug/kg
SW846 8270E
Phenanthrene b
507 J
2300
230
ug/kg
SW846 8270E
Pyrene b
790 J
2300
260
ug/kg
SW846 8270E
Arsenic °
4.2
2.8
mg/kg
SW846 6010D
Chromium c
12.7
2.8
mg/kg
SW846 6010D
Lead °
45.1
5.6
mg/kg
SW846 6010D
Mercury
0.095
0.053
mg/kg
SW846 7471B
Chromium, Hexavalent d
0.61
0.56
mg/kg
SW846 3060A/7199
FA75651-6 SB-06
Acetone a
144 J
180
92
ug/kg
SW846 8260D
p-Isopropyltoluene a
1.1 J
4.6
0.92
ug/kg
SW846 8260D
Toluene a
10.3 J
18
9.2
ug/kg
SW846 8260D
Benzo(a)anthracene b
225 J
1900
190
ug/kg
SW846 8270E
Benzo(b)fluoranthene b
263 J
1900
210
ug/kg
SW846 8270E
Fluoranthene b
303 J
1900
190
ug/kg
SW846 8270E
Pyrene b
293 J
1900
220
ug/kg
SW846 8270E
Arsenic c
5.1
2.0
mg/kg
SW846 6010D
Chromium c
14.2
2.0
mg/kg
SW846 6010D
Lead °
52.9
4.0
mg/kg
SW846 6010D
Mercury
0.16
0.046
mg/kg
SW846 7471B
FA75651-7 SB-07
Acetone a
105 J
170
86
ug/kg
SW846 8260D
2-Butanone (MEK) a
8.7 J
22
6.3
ug/kg
SW846 8260D
p-Isopropyltoluene a
3.6 J
4.3
0.86
ug/kg
SW846 8260D
Benzo(a)anthracene b
303 J
2000
200
ug/kg
SW846 8270E
Benzo(a)pyrene b
300 J
2000
240
ug/kg
SW846 8270E
Benzo(b)fluoranthene b
401 J
2000
220
ug/kg
SW846 8270E
6 6of177
FA75651

Summary of Hits
Job Number:
FA75651
Account:
Geosyntec Consultants
Project:
31 Harnett, Wilmington, NC
Collected:
06/04/20
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
Page 4 of 6
Benzo(g, h, i)perylene b
212 J
2000
210
ug/kg
SW846 8270E
Chrysene b
327 J
2000
210
ug/kg
SW846 8270E
Fluoranthene b
473 J
2000
200
ug/kg
SW846 8270E
Indeno(1,2,3-cd)pyrene b
264 J
2000
250
ug/kg
SW846 8270E
Phenanthrene b
237 J
2000
200
ug/kg
SW846 8270E
Pyrene b
413 J
2000
240
ug/kg
SW846 8270E
Arsenic °
5.6
2.3
mg/kg
SW846 6010D
Chromium °
17.2
2.3
mg/kg
SW846 6010D
Lead °
160
4.5
mg/kg
SW846 6010D
Mercury
0.33
0.046
mg/kg
SW846 7471B
Chromium, Hexavalent d
1.1
0.50
mg/kg
SW846 3060A/7199
FA75651-8 SB-08
Acetone a
219
180
92
ug/kg
SW846 8260D
2-Butanone (MEK) a
20.3 J
23
6.7
ug/kg
SW846 8260D
p-Isopropyltoluene a
16.4
4.6
0.92
ug/kg
SW846 8260D
Benzo(a)anthracene b
232 J
1800
180
ug/kg
SW846 8270E
Benzo(a)pyrene b
266 J
1800
210
ug/kg
SW846 8270E
Benzo(k)fluoranthene b
394 J
1800
200
ug/kg
SW846 8270E
Benzo(g, h, i)perylene b
199 J
1800
190
ug/kg
SW846 8270E
Chrysene b
322 J
1800
180
ug/kg
SW846 8270E
Fluoranthene b
649 J
1800
180
ug/kg
SW846 8270E
Indeno(1,2,3-cd)pyrene b
237 J
1800
220
ug/kg
SW846 8270E
Phenanthrene b
353 J
1800
180
ug/kg
SW846 8270E
Pyrene b
517 J
1800
210
ug/kg
SW846 8270E
Arsenic °
6.3
2.5
mg/kg
SW846 6010D
Barium c
60.7
50
mg/kg
SW846 6010D
Chromium c
14.6
2.5
mg/kg
SW846 6010D
Lead °
126
5.0
mg/kg
SW846 6010D
Mercury
0.25
0.041
mg/kg
SW846 7471B
Chromium, Hexavalent d
0.44
0.44
mg/kg
SW846 3060A/7199
FA75651-9 SB-09
Acetone a
90.8 J
160
80
ug/kg
SW846
8260D
p-Isopropyltoluene a
17.7
4.0
0.80
ug/kg
SW846
8260D
Anthracene b
144 J
1100
120
ug/kg
SW846
8270E
Benzo(a)anthracene b
462 J
1100
110
ug/kg
SW846
8270E
Benzo(a)pyrene b
602 J
1100
130
ug/kg
SW846
8270E
Benzo(k)fluoranthene b
935 J
1100
120
ug/kg
SW846
8270E
Benzo(g, h, i)perylene b
530 J
1100
110
ug/kg
SW846
8270E
Benzo(k)fluoranthene b
282 J
1100
140
ug/kg
SW846
8270E
Chrysene b
591 J
1100
110
ug/kg
SW846
8270E
Fluoranthene b
697 J
1100
110
ug/kg
SW846
8270E
6 7of177
FA75651

Summary of Hits
Job Number:
FA75651
Account:
Geosyntec Consultants
Project:
31 Harnett, Wilmington, NC
Collected:
06/04/20
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
Page 5 of 6
Indeno(1,2,3-cd)pyrene b
713 J
1100 130
ug/kg
SW846 8270E
Phenanthrene b
325 J
1100 110
ug/kg
SW846 8270E
Pyrene b
739 J
1100 130
ug/kg
SW846 8270E
Arsenic °
4.8
2.7
mg/kg
SW846 6010D
Chromium °
15.0
2.7
mg/kg
SW846 6010D
Lead °
29.7
5.3
mg/kg
SW846 6010D
Mercury
0.086
0.052
mg/kg
SW846 7471B
Chromium, Hexavalent d
1.1
0.51
mg/kg
SW846 3060A/7199
FA75651-10 SB-10
Acetone a
225
140
71
ug/kg
SW846 8260D
2-Butanone (MEK) a
24.1
18
5.2
ug/kg
SW846 8260D
Isopropylbenzene a
3.5 J
3.6
0.71
ug/kg
SW846 8260D
p-Isopropyltoluene a
24.9
3.6
0.71
ug/kg
SW846 8260D
Naphthalene a
12.2
3.6
1.4
ug/kg
SW846 8260D
Toluene a
8.2 J
14
7.1
ug/kg
SW846 8260D
1,2,4-Trimethylbenzene a
1.6 J
3.6
0.71
ug/kg
SW846 8260D
1,3,5-Trimethylbenzene a
1.1 J
3.6
0.71
ug/kg
SW846 8260D
o-Xylene a
2.8 J
3.6
0.71
ug/kg
SW846 8260D
Xylene (total) a
3.5 J
11
1.5
ug/kg
SW846 8260D
Acenaphthene b
285 J
1900
200
ug/kg
SW846 8270E
Anthracene b
271 J
1900
210
ug/kg
SW846 8270E
Benzo(a)anthracene b
511 J
1900
190
ug/kg
SW846 8270E
Benzo(a)pyrene b
452 J
1900
220
ug/kg
SW846 8270E
Benzo(b)fluoranthene b
558 J
1900
210
ug/kg
SW846 8270E
Benzo(g,h,i)perylene b
214 J
1900
190
ug/kg
SW846 8270E
Chrysene b
522 J
1900
190
ug/kg
SW846 8270E
Fluoranthene b
1520 J
1900
190
ug/kg
SW846 8270E
Fluorene b
250 J
1900
200
ug/kg
SW846 8270E
Phenanthrene b
815 J
1900
190
ug/kg
SW846 8270E
Pyrene b
1570 J
1900
220
ug/kg
SW846 8270E
Arsenic c
4.6
1.9
mg/kg
SW846 6010D
Chromium c
14.6
1.9
mg/kg
SW846 6010D
Lead °
43.5
3.9
mg/kg
SW846 6010D
Mercury
0.082
0.046
mg/kg
SW846 7471B
FA75651-11 DUP-01
Acetone a
290
190
94
ug/kg
SW846 8260D
2-Butanone (MEK) a
36.5
23
6.8
ug/kg
SW846 8260D
p-Isopropyltoluene a
1.4 J
4.7
0.94
ug/kg
SW846 8260D
Toluene a
12.1 J
19
9.4
ug/kg
SW846 8260D
Benzo(a)anthracene b
198 J
1900
190
ug/kg
SW846 8270E
Benzo(b)fluoranthene b
298 J
1900
210
ug/kg
SW846 8270E
6 8of177
FA75651

Summary of Hits
Job Number:
FA75651
Account:
Geosyntec Consultants
Project:
31 Harnett, Wilmington, NC
Collected:
06/04/20
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
Chrysene b 198 J
1900 190
ug/kg
SW846 8270E
Fluoranthene b 398 J
1900 190
ug/kg
SW846 8270E
Pyrene b 354 J
1900 220
ug/kg
SW846 8270E
Arsenic ° 5.5
1.8
mg/kg
SW846 6010D
Barium ° 38.1
36
mg/kg
SW846 6010D
Chromium ° 15.0
1.8
mg/kg
SW846 6010D
Lead ° 51.2
3.6
mg/kg
SW846 6010D
Mercury 0.21
0.041
mg/kg
SW846 7471B
FA75651-12 TRIP BLANK
Acetone 166 J
200 100
ug/kg
SW846 8260D
Toluene 99.6
20 10
ug/kg
SW846 8260D
(a) Internal standard response(s) outside method criteria due to sample matrix interference; confirmed by
reanalysis.
(b) Dilution required due to matrix interference; extract was viscous.
(c) Sample dilution required due to difficult matrix.
(d) Analysis performed at SGS Dayton, NJ.
(e) Dilution required due to matrix interference (surrogate standard failure).
Page 6 of 6
6 9 of 177
FA75651

FM
Orlando, FL
Sample Results
Report of Analysis
i
==MAO Section 3
� 10 of 177
FA75651

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: SB-01
Lab Sample ID: FA75651-1 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 90.4
Project: 31 Harnett, Wilmington, NC
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
Run #1 a F0095959.D
1
06/10/20 14:31
SP
n/a
n/a
VF3374
Run #2 b F0095934.1)
1
06/09/20 15:17
SP
n/a
n/a
VF3373
Initial Weight Final Volume
Run # 1 6.31 g 5.0 ml
Run #2 6.38 g 5.0 ml
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
67-64-1
Acetone
305
180
88
ug/kg
71-43-2
Benzene
ND
4.4
1.1
ug/kg
108-86-1
Bromobenzene
ND
4.4
0.88
ug/kg
74-97-5
Bromochloromethane
ND
4.4
1.3
ug/kg
75-27-4
Bromodichloromethane
ND
4.4
0.88
ug/kg
75-25-2
Bromoform
ND
4.4
0.88
ug/kg
78-93-3
2-Butanone (MEK)
35.0
22
6.4
ug/kg
104-51-8
n-Butylbenzene
ND
4.4
0.88
ug/kg
135-98-8
sec-Butylbenzene
ND
4.4
0.88
ug/kg
98-06-6
tert-Butylbenzene
ND
4.4
0.88
ug/kg
56-23-5
Carbon Tetrachloride
ND
4.4
0.89
ug/kg
108-90-7
Chlorobenzene
ND
4.4
0.88
ug/kg
75-00-3
Chloroethane
ND
4.4
1.8
ug/kg
67-66-3
Chloroform
ND
4.4
1.2
ug/kg
95-49-8
o-Chlorotoluene
ND
4.4
0.88
ug/kg
106-43-4
p-Chlorotoluene
ND
4.4
0.88
ug/kg
124-48-1
Dibromochloromethane
ND
4.4
0.88
ug/kg
106-93-4
1,2-Dibromoethane
ND
4.4
0.88
ug/kg
75-71-8
Dichlorodifluoromethane
ND
4.4
1.8
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
4.4
0.88
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
4.4
0.88
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
4.4
1.0
ug/kg
75-34-3
1, 1 -Dichloroethane
ND
4.4
1.6
ug/kg
107-06-2
1,2-Dichloroethane
ND
4.4
0.88
ug/kg
75-35-4
1, 1 -Dichloroethylene
ND
4.4
0.88
ug/kg
156-59-2
cis-1,2-Dichloroethylene
ND
4.4
1.2
ug/kg
156-60-5
trans- 1, 2-Dichloroethylene
ND
4.4
0.88
ug/kg
78-87-5
1,2-Dichloropropane
ND
4.4
0.88
ug/kg
142-28-9
1,3-Dichloropropane
ND
4.4
0.88
ug/kg
594-20-7
2,2-Dichloropropane
ND
4.4
0.88
ug/kg
563-58-6
1, 1 -Dichloropropene
ND
4.4
0.89
ug/kg
10061-01-5
cis- 1, 3 -Dichloropropene
ND
4.4
0.88
ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 11 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-01
Lab Sample ID: FA75651-1 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 90.4
Project: 31 Harnett, Wilmington, NC
VOA List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
10061-02-6
trans- 1, 3-Dichloropropene
ND
4.4
0.88
ug/kg
108-20-3
Di -Isopropyl Ether
ND
4.4
2.0
ug/kg
64-17-5
Ethyl Alcohol
ND
350
66
ug/kg
100-41-4
Ethylbenzene
1.4
4.4
0.88
ug/kg J
591-78-6
2-Hexanone
ND
22
6.6
ug/kg
98-82-8
Isopropylbenzene
0.98
4.4
0.88
ug/kg J
99-87-6
p-Isopropyltoluene
106
4.4
0.88
ug/kg
74-83-9
Methyl Bromide
ND
4.4
1.8
ug/kg
74-87-3
Methyl Chloride
ND
4.4
1.8
ug/kg
75-09-2
Methylene Chloride
ND
18
9.6
ug/kg
108-10-1
4-Methyl-2-pentanone (MIBK) ND
22
6.6
ug/kg
1634-04-4
Methyl Tert Butyl Ether
ND
4.4
0.88
ug/kg
91-20-3
Naphthalene
10.1
4.4
1.8
ug/kg
103-65-1
n-Propylbenzene
ND
4.4
0.88
ug/kg
100-42-5
Styrene
ND
4.4
0.88
ug/kg
630-20-6
1, 1, 1,2-Tetrachloroethane
ND
4.4
0.90
ug/kg
79-34-5
1,1,2,2-Tetrachloroethane
ND
4.4
0.88
ug/kg
127-18-4
Tetrachloroethylene
ND
4.4
1.1
ug/kg
108-88-3
Toluene
9.9
18
8.8
ug/kg J
87-61-6
1,2,3-Trichlorobenzene
ND
4.4
1.2
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
4.4
0.88
ug/kg
71-55-6
1, 1, 1 -Trichloroethane
ND
4.4
0.88
ug/kg
79-00-5
1,1,2-Trichloroethane
ND
4.4
0.88
ug/kg
79-01-6
Trichloroethylene
ND
4.4
0.88
ug/kg
75-69-4
Trichlorofluoromethane
ND
4.4
1.8
ug/kg
96-18-4
1,2,3-Trichloropropane
ND
4.4
1.1
ug/kg
95-63-6
1,2,4-Trimethylbenzene
2.9
4.4
0.88
ug/kg J
108-67-8
1,3,5-Trimethylbenzene
ND
4.4
0.88
ug/kg
108-05-4
Vinyl Acetate
ND
22
14
ug/kg
75-01-4
Vinyl Chloride
ND
4.4
0.88
ug/kg
m,p-Xylene
4.1
8.8
0.96
ug/kg J
95-47-6
o-Xylene
1.6
4.4
0.88
ug/kg J
1330-20-7
Xylene (total)
5.7
13
1.8
ug/kg J
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
1868-53-7
Dibromofluoromethane
103%
104%
75-124%
17060-07-0
1,2-Dichloroethane-D4
101%
105%
72-135%
2037-26-5
Toluene-D8
108%
111%
75-126%
460-00-4
4-Bromofluorobenzene
132%
142% c
71-133%
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 12 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-01
Lab Sample ID: FA75651-1 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 90.4
Project: 31 Harnett, Wilmington, NC
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(a) Internal standard response(s) outside method criteria due to sample matrix interference; confirmed by
reanalysis.
(b) Confirmation run for surrogate recoveries.
(c) Outside control limits due to matrix interference.
Page 3 of 3
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 13 of 177
FA75651

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: SB-01
Lab Sample ID: FA75651-1 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8270E SW846 3550C Percent Solids: 90.4
Project: 31 Harnett, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 a 9I009010.1) 5 06/12/20 22:33 MV 06/08/20 06:39 OP80524 S91334
Run #2
Initial Weight Final Volume
Run #1 30.1 g 1.0 ml
Run #2
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
65-85-0
Benzoic Acid
ND
4600
920
ug/kg
59-50-7
4-Chloro-3-methyl Phenol
ND
920
100
ug/kg
95-57-8
2-Chlorophenol
ND
920
110
ug/kg
120-83-2
2,4-Dichlorophenol
ND
920
110
ug/kg
105-67-9
2,4-Dimethylphenol
ND
920
240
ug/kg
51-28-5
2,4-Dinitrophenol
ND
4600
920
ug/kg
534-52-1
4,6-Dinitro-o-cresol
ND
1800
370
ug/kg
95-48-7
2-Methylphenol
ND
920
110
ug/kg
3&4-Methylphenol
ND
920
150
ug/kg
88-75-5
2-Nitrophenol
ND
920
100
ug/kg
100-02-7
4-Nitrophenol
ND
4600
920
ug/kg
87-86-5
Pentachlorophenol
ND
4600
920
ug/kg
108-95-2
Phenol
ND
920
92
ug/kg
88-06-2
2,4,6-Trichlorophenol
ND
920
110
ug/kg
83-32-9
Acenaphthene
ND
920
98
ug/kg
208-96-8
Acenaphthylene
ND
920
92
ug/kg
120-12-7
Anthracene
114
920
100
ug/kg J
56-55-3
Benzo(a)anthracene
338
920
92
ug/kg J
50-32-8
Benzo(a)pyrene
387
920
110
ug/kg J
205-99-2
Benzo(b)fluoranthene
586
920
100
ug/kg J
191-24-2
Benzo(g, h, i)perylene
268
920
95
ug/kg J
207-08-9
Benzo(k)fluoranthene
214
920
120
ug/kg J
100-51-6
Benzyl Alcohol
ND
920
92
ug/kg
101-55-3
4-13romophenyl phenyl ether
ND
920
95
ug/kg
85-68-7
Butyl benzyl phthalate
ND
920
180
ug/kg
106-47-8
4-Chloroaniline
ND
920
230
ug/kg
111-91-1
bis(2-Chloroethoxy)methane
ND
920
92
ug/kg
111-44-4
bis(2-Chloroethyl)ether
ND
920
110
ug/kg
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
920
120
ug/kg
91-58-7
2-Chloronaphthalene
ND
920
92
ug/kg
7005-72-3
4-Chlorophenyl phenyl ether
ND
920
92
ug/kg
218-01-9
Chrysene
428
920
94
ug/kg J
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 14 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-01
Lab Sample ID: FA75651-1 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8270E SW846 3550C Percent Solids: 90.4
Project: 31 Harnett, Wilmington, NC
ABN List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
53-70-3
Dibenzo(a,h)anthracene
ND
920
120
ug/kg
132-64-9
Dibenzofaran
ND
920
92
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
920
92
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
920
99
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
920
120
ug/kg
91-94-1
3,3'-Dichlorobenzidine
ND
920
220
ug/kg
84-66-2
Diethyl Phthalate
ND
1800
180
ug/kg
131-11-3
Dimethyl Phthalate
ND
920
180
ug/kg
117-84-0
Di-n-octyl Phthalate
ND
920
180
ug/kg
84-74-2
Di-n-butyl Phthalate
ND
1800
370
ug/kg
122-66-7
1,2-Diphenylhydrazine
ND
920
92
ug/kg
117-81-7
bis(2-Ethylhexyl)phthalate
ND
1800
180
ug/kg
206-44-0
Fluoranthene
602
920
92
ug/kg J
86-73-7
Fluorene
ND
920
98
ug/kg
118-74-1
Hexachlorobenzene
ND
920
94
ug/kg
87-68-3
Hexachlorobutadiene
ND
920
93
ug/kg
77-47-4
Hexachlorocyclopentadiene
ND
920
180
ug/kg
67-72-1
Hexachloroethane
ND
920
110
ug/kg
193-39-5
Indeno(1,2,3-cd)pyrene
409
920
110
ug/kg J
78-59-1
Isophorone
ND
920
92
ug/kg
90-12-0
1-Methylnaphthalene
ND
920
92
ug/kg
91-57-6
2-Methylnaphthalene
ND
920
92
ug/kg
91-20-3
Naphthalene
ND
920
92
ug/kg
98-95-3
Nitrobenzene
ND
920
92
ug/kg
621-64-7
N-Nitrosodi-n-propylamine
ND
920
92
ug/kg
86-30-6
N-Nitrosodiphenylamine
ND
920
99
ug/kg
85-01-8
Phenanthrene
342
920
92
ug/kg J
129-00-0
Pyrene
613
920
110
ug/kg J
120-82-1
1,2,4-Trichlorobenzene
ND
920
110
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
367-12-4
2-Fluorophenol
96%
40-102%
4165-62-2
Phenol-d5
108% b
41-100%
118-79-6
2,4,6-Tribromophenol
117% b
42-108%
4165-60-0
Nitrobenzene-d5
93%
40-105%
321-60-8
2-Fluorobiphenyl
98%
43-107%
1718-51-0
Terphenyl-dl4
115%
45-119%
(a) Dilution required due to matrix interference; extract was viscous.
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 15 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-01
Lab Sample ID: FA75651-1 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8270E SW846 3550C Percent Solids: 90.4
Project: 31 Harnett, Wilmington, NC
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(b) Outside control limits.
Page 3 of 3
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 16 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-01
Lab Sample ID: FA75651-1 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8081B SW846 3546 Percent Solids: 90.4
Project: 31 Harnett, Wilmington, NC
Page 1 of 1 j
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 ST147925.1) 1 06/19/20 04:10 WH 06/16/20 08:06 OP80695 GST3550
Run #2
Initial Weight Final Volume
Run # 1 15.1 g 5.0 ml
Run #2
Pesticide TCL List
CAS No.
Compound
Result
RL
MDL
Units Q
309-00-2
Aldrin a
ND
1.8
0.58
ug/kg
319-84-6
alpha-BHC b
ND
1.8
0.58
ug/kg
319-85-7
beta-BHC a
ND
1.8
0.54
ug/kg
319-86-8
delta-BHC a
ND
1.8
0.52
ug/kg
58-89-9
gamma-BHC (Lindane) a
ND
1.8
0.55
ug/kg
5103-71-9
alpha -Chlordane a
ND
1.8
0.57
ug/kg
5103-74-2
gamma -Chlordane a
ND
1.8
0.53
ug/kg
60-57-1
Dieldrin
ND
1.8
0.51
ug/kg
72-54-8
4,4'-DDD
ND
3.7
0.51
ug/kg
72-55-9
4,4'-DDE
ND
3.7
0.67
ug/kg
50-29-3
4,4'-DDT
ND
3.7
0.56
ug/kg
72-20-8
Endrin
ND
3.7
0.93
ug/kg
1031-07-8
Endosulfan sulfate
ND
3.7
0.48
ug/kg
7421-93-4
Endrin aldehyde
ND
3.7
0.42
ug/kg
53494-70-5
Endrin ketone
ND
3.7
0.58
ug/kg
959-98-8
Endosulfan-I a
ND
1.8
0.42
ug/kg
33213-65-9
Endosulfan-II
ND
1.8
0.43
ug/kg
76-44-8
Heptachlor a
ND
1.8
0.54
ug/kg
1024-57-3
Heptachlor epoxide a
ND
1.8
0.54
ug/kg
72-43-5
Methoxychlor
ND
3.7
0.73
ug/kg
8001-35-2
Toxaphene
ND
92
27
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
877-09-8
Tetrachloro-m-xylene
155% °
50-122%
2051-24-3
Decachlorobiphenyl
94%
50-133%
(a) Associated CCV outside of control limits
high, sample
was ND.
(b) Associated BS and CCV outside of control limits high, sample was ND.
(c) Outside control limits. However, Sample was ND.
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 17 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-01
Lab Sample ID: FA75651-1 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Percent Solids: 90.4
Project: 31 Harnett, Wilmington, NC
Page 1 of 1 j
Metals Analysis
Analyte Result RL
Units
DF
Prep
Analyzed
By
Method
Prep Method
Arsenic a 5.5 2.1
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
Barium a < 42 42
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050E 4
Cadmium a < 0.83 0.83
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
Chromium a 14.4 2.1
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
Lead a 55.8 4.2
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050E 4
Mercury 0.14 0.042
mg/kg
1
06/11/20
06/11/20
7c
SW846 7471E 1
SW846 7471B 3
Selenium a < 4.2 4.2
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
Silver a < 2.1 2.1
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
(1) Instrument QC Batch: MA16819
(2) Instrument QC Batch: MA16830
(3) Prep QC Batch: MP37368
(4) Prep QC Batch: MP37382
(a) Sample dilution required due to difficult matrix.
RL = Reporting Limit
6 18 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-01
Lab Sample ID: FA75651-1 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Percent Solids: 90.4
Project: 31 Harnett, Wilmington, NC
General Chemistry
Analyte Result
Chromium, Hexavalent a 0.57
Solids, Percent 90.4
(a) Analysis performed at SGS Dayton, NJ.
RL = Reporting Limit
Page 1 of 1 j
RL Units
DF
Analyzed
By
Method
0.46 mg/kg
1
06/15/2011:00
ANJ
SW846306OA/7199
%
1
06/ 10/20 13:44
cs
SM19 2540G
6 19 of 177
FA75651

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: SB-02
Lab Sample ID: FA75651-2 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 82.6
Project: 31 Harnett, Wilmington, NC
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
Run #1 a F0095970.D
1
06/10/20 19:37
SP
n/a
n/a
VF3374
Run #2 b F0095935.1)
1
06/09/20 15:48
SP
n/a
n/a
VF3373
Run #3 c F0095960.1)
1
06/10/20 15:00
SP
n/a
n/a
VF3374
Initial Weight Final Volume Methanol Aliquot
Run #1 7.85 g 5.0 ml 100 ul
Run #2 8.00 g 5.0 ml
Run #3 8.02 g 5.0 ml
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
67-64-1
Acetone
ND
9800
4900
ug/kg
71-43-2
Benzene
ND
250
60
ug/kg
108-86-1
Bromobenzene
ND
250
49
ug/kg
74-97-5
Bromochloromethane
ND
250
73
ug/kg
75-27-4
Bromodichloromethane
ND
250
49
ug/kg
75-25-2
Bromoform
ND
250
49
ug/kg
78-93-3
2-Butanone (MEK)
ND
1200
360
ug/kg
104-51-8
n-Butylbenzene
ND
250
49
ug/kg
135-98-8
sec-Butylbenzene
ND
250
49
ug/kg
98-06-6
tert-Butylbenzene
ND
250
49
ug/kg
56-23-5
Carbon Tetrachloride
ND
250
50
ug/kg
108-90-7
Chlorobenzene
ND
250
49
ug/kg
75-00-3
Chloroethane
ND
250
98
ug/kg
67-66-3
Chloroform
ND
250
65
ug/kg
95-49-8
o-Chlorotoluene
ND
250
49
ug/kg
106-43-4
p-Chlorotoluene
ND
250
49
ug/kg
124-48-1
Dibromochloromethane
ND
250
49
ug/kg
106-93-4
1,2-Dibromoethane
ND
250
49
ug/kg
75-71-8
Dichlorodifluoromethane
ND
250
98
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
250
49
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
250
49
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
250
56
ug/kg
75-34-3
1, 1 -Dichloroethane
ND
250
87
ug/kg
107-06-2
1,2-Dichloroethane
ND
250
49
ug/kg
75-35-4
1, 1 -Dichloroethylene
ND
250
49
ug/kg
156-59-2
cis-1,2-Dichloroethylene
ND
250
68
ug/kg
156-60-5
trans- 1, 2-Dichloroethylene
ND
250
49
ug/kg
78-87-5
1,2-Dichloropropane
ND
250
49
ug/kg
142-28-9
1,3-Dichloropropane
ND
250
49
ug/kg
594-20-7
2,2-Dichloropropane
ND
250
49
ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 20 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-02
Lab Sample ID: FA75651-2 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 82.6
Project: 31 Harnett, Wilmington, NC
VOA List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
563-58-6
1, 1 -Dichloropropene
ND
250
50
ug/kg
10061-01-5
cis- 1, 3-Dichloropropene
ND
250
49
ug/kg
10061-02-6
trans- 1, 3-Dichloropropene
ND
250
49
ug/kg
108-20-3
Di -Isopropyl Ether
ND
250
110
ug/kg
64-17-5
Ethyl Alcohol
ND
20000
3700
ug/kg
100-41-4
Ethylbenzene
ND
250
49
ug/kg
591-78-6
2-Hexanone
ND
1200
370
ug/kg
98-82-8
Isopropylbenzene
ND
250
49
ug/kg
99-87-6
p-Isopropyltoluene
693
250
49
ug/kg
74-83-9
Methyl Bromide
ND
250
98
ug/kg
74-87-3
Methyl Chloride
ND
250
98
ug/kg
75-09-2
Methylene Chloride
ND
980
540
ug/kg
108-10-1
4-Methyl-2-pentanone (MIBK) ND
1200
370
ug/kg
1634-04-4
Methyl Tert Butyl Ether
ND
250
49
ug/kg
91-20-3
Naphthalene
239
250
98
ug/kg J
103-65-1
n-Propylbenzene
ND
250
49
ug/kg
100-42-5
Styrene
ND
250
49
ug/kg
630-20-6
1, 1, 1,2-Tetrachloroethane
ND
250
51
ug/kg
79-34-5
1,1,2,2-Tetrachloroethane
ND
250
49
ug/kg
127-18-4
Tetrachloroethylene
ND
250
63
ug/kg
108-88-3
Toluene
ND
980
490
ug/kg
87-61-6
1,2,3-Trichlorobenzene
ND
250
69
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
250
49
ug/kg
71-55-6
1, 1, 1 -Trichloroethane
ND
250
49
ug/kg
79-00-5
1,1,2-Trichloroethane
ND
250
49
ug/kg
79-01-6
Trichloroethylene
ND
250
49
ug/kg
75-69-4
Trichlorofluoromethane
ND
250
98
ug/kg
96-18-4
1, 2,3 -Trichloropropane
ND
250
61
ug/kg
95-63-6
1,2,4-Trimethylbenzene
ND
250
49
ug/kg
108-67-8
1,3,5-Trimethylbenzene
ND
250
49
ug/kg
108-05-4
Vinyl Acetate
ND
1200
810
ug/kg
75-01-4
Vinyl Chloride
ND
250
49
ug/kg
m,p-Xylene
ND
490
54
ug/kg
95-47-6
o-Xylene
ND
250
49
ug/kg
1330-20-7
Xylene (total)
ND
740
100
ug/kg
CAS No.
1868-53-7
17060-07-0
Surrogate Recoveries
Dibromofluoromethane
1, 2-Dichloroethane-D4
Run# 1 Run# 2 Run# 3 Limits
104% 104% 100% 75-124%
101% 107% 102% 72-135%
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 21 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-02
Lab Sample ID: FA75651-2 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 82.6
Project: 31 Harnett, Wilmington, NC
Page 3 of 3 N
VOA List for NC, May 2012
CAS No. Surrogate Recoveries Run# 1 Run# 2 Run# 3 Limits
2037-26-5 Toluene-138 99% 106% 111% 75-126%
460-00-4 4-Bromofluorobenzene 100% 123% 137% d 71-133%
(a) Dilution required due to matrix interference (surrogate standard failure).
(b) Soil vials were not received within 48 hours of sampling; results are considered minimum values. Confirmation
run for internal standard areas.
(c) Soil vials were not received within 48 hours of sampling; results are considered minimum values. Confirmation
run for surrogate recoveries.
(d) Outside control limits due to matrix interference.
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 22 of 177
FA75651

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: SB-02
Lab Sample ID: FA75651-2 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8270E SW846 3550C Percent Solids: 82.6
Project: 31 Harnett, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 a 91009011.D 5 06/12/20 22:59 MV 06/08/20 06:39 OP80524 S91334
Run #2
Initial Weight Final Volume
Run #1 30.1 g 1.0 ml
Run #2
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
65-85-0
Benzoic Acid
ND
5000
1000
ug/kg
59-50-7
4-Chloro-3-methyl Phenol
ND
1000
110
ug/kg
95-57-8
2-Chlorophenol
ND
1000
120
ug/kg
120-83-2
2,4-Dichlorophenol
ND
1000
120
ug/kg
105-67-9
2,4-Dimethylphenol
ND
1000
270
ug/kg
51-28-5
2,4-Dinitrophenol
ND
5000
1000
ug/kg
534-52-1
4,6-Dinitro-o-cresol
ND
2000
400
ug/kg
95-48-7
2-Methylphenol
ND
1000
120
ug/kg
3&4-Methylphenol
ND
1000
170
ug/kg
88-75-5
2-Nitrophenol
ND
1000
110
ug/kg
100-02-7
4-Nitrophenol
ND
5000
1000
ug/kg
87-86-5
Pentachlorophenol
ND
5000
1000
ug/kg
108-95-2
Phenol
ND
1000
100
ug/kg
88-06-2
2,4,6-Trichlorophenol
ND
1000
120
ug/kg
83-32-9
Acenaphthene
350
1000
110
ug/kg J
208-96-8
Acenaphthylene
ND
1000
100
ug/kg
120-12-7
Anthracene
376
1000
110
ug/kg J
56-55-3
Benzo(a)anthracene
767
1000
100
ug/kg J
50-32-8
Benzo(a)pyrene
628
1000
120
ug/kg J
205-99-2
Benzo(b)fluoranthene
923
1000
110
ug/kg J
191-24-2
Benzo(g, h, i)perylene
376
1000
100
ug/kg J
207-08-9
Benzo(k)fluoranthene
339
1000
130
ug/kg J
100-51-6
Benzyl Alcohol
ND
1000
100
ug/kg
101-55-3
4-13romophenyl phenyl ether
ND
1000
100
ug/kg
85-68-7
Butyl benzyl phthalate
ND
1000
200
ug/kg
106-47-8
4-Chloroaniline
ND
1000
250
ug/kg
111-91-1
bis(2-Chloroethoxy)methane
ND
1000
100
ug/kg
111-44-4
bis(2-Chloroethyl)ether
ND
1000
120
ug/kg
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
1000
130
ug/kg
91-58-7
2-Chloronaphthalene
ND
1000
100
ug/kg
7005-72-3
4-Chlorophenyl phenyl ether
ND
1000
100
ug/kg
218-01-9
Chrysene
776
1000
100
ug/kg J
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 23 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-02
Lab Sample ID: FA75651-2 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8270E SW846 3550C Percent Solids: 82.6
Project: 31 Harnett, Wilmington, NC
ABN List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
53-70-3
Dibenzo(a,h)anthracene
ND
1000
130
ug/kg
132-64-9
Dibenzofaran
133
1000
100
ug/kg J
95-50-1
1,2-Dichlorobenzene
ND
1000
100
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
1000
110
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
1000
130
ug/kg
91-94-1
3,3'-Dichlorobenzidine
ND
1000
240
ug/kg
84-66-2
Diethyl Phthalate
ND
2000
200
ug/kg
131-11-3
Dimethyl Phthalate
ND
1000
200
ug/kg
117-84-0
Di-n-octyl Phthalate
ND
1000
200
ug/kg
84-74-2
Di-n-butyl Phthalate
ND
2000
400
ug/kg
122-66-7
1,2-Diphenylhydrazine
ND
1000
100
ug/kg
117-81-7
bis(2-Ethylhexyl)phthalate
ND
2000
200
ug/kg
206-44-0
Fluoranthene
2140
1000
100
ug/kg
86-73-7
Fluorene
155
1000
110
ug/kg J
118-74-1
Hexachlorobenzene
ND
1000
100
ug/kg
87-68-3
Hexachlorobutadiene
ND
1000
100
ug/kg
77-47-4
Hexachlorocyclopentadiene
ND
1000
200
ug/kg
67-72-1
Hexachloroethane
ND
1000
120
ug/kg
193-39-5
Indeno(1,2,3-cd)pyrene
534
1000
120
ug/kg J
78-59-1
Isophorone
ND
1000
100
ug/kg
90-12-0
1-Methylnaphthalene
ND
1000
100
ug/kg
91-57-6
2-Methylnaphthalene
ND
1000
100
ug/kg
91-20-3
Naphthalene
ND
1000
100
ug/kg
98-95-3
Nitrobenzene
ND
1000
100
ug/kg
621-64-7
N-Nitrosodi-n-propylamine
ND
1000
100
ug/kg
86-30-6
N-Nitrosodiphenylamine
ND
1000
110
ug/kg
85-01-8
Phenanthrene
708
1000
100
ug/kg J
129-00-0
Pyrene
2060
1000
120
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
1000
120
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
367-12-4
2-Fluorophenol
95%
40-102%
4165-62-2
Phenol-d5
106% b
41-100%
118-79-6
2,4,6-Tribromophenol
100%
42-108%
4165-60-0
Nitrobenzene-d5
95%
40-105%
321-60-8
2-Fluorobiphenyl
97%
43-107%
1718-51-0
Terphenyl-dl4
118%
45-119%
(a) Dilution required due to matrix interference; extract was viscous.
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 24 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-02
Lab Sample ID: FA75651-2 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8270E SW846 3550C Percent Solids: 82.6
Project: 31 Harnett, Wilmington, NC
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(b) Outside control limits.
Page 3 of 3 N
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 25 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-02
Lab Sample ID: FA75651-2 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8081B SW846 3546 Percent Solids: 82.6
Project: 31 Harnett, Wilmington, NC
Page 1 of 1 N
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 ST147926.1) 1 06/19/20 04:28 WH 06/16/20 08:06 OP80695 GST3550
Run #2
Initial Weight Final Volume
Run#1 15.4g 5.0ml
Run #2
Pesticide TCL List
CAS No.
Compound
Result
RL
MDL
Units Q
309-00-2
Aldrin a
ND
2.0
0.62
ug/kg
319-84-6
alpha-BHC b
ND
2.0
0.62
ug/kg
319-85-7
beta-BHC a
ND
2.0
0.58
ug/kg
319-86-8
delta-BHC a
ND
2.0
0.56
ug/kg
58-89-9
gamma-BHC (Lindane) a
ND
2.0
0.59
ug/kg
5103-71-9
alpha -Chlordane a
ND
2.0
0.61
ug/kg
5103-74-2
gamma -Chlordane a
ND
2.0
0.57
ug/kg
60-57-1
Dieldrin
ND
2.0
0.55
ug/kg
72-54-8
4,4'-DDD
ND
3.9
0.54
ug/kg
72-55-9
4,4'-DDE
ND
3.9
0.72
ug/kg
50-29-3
4,4'-DDT
ND
3.9
0.60
ug/kg
72-20-8
Endrin
ND
3.9
0.99
ug/kg
1031-07-8
Endosulfan sulfate
ND
3.9
0.52
ug/kg
7421-93-4
Endrin aldehyde
ND
3.9
0.46
ug/kg
53494-70-5
Endrin ketone
ND
3.9
0.62
ug/kg
959-98-8
Endosulfan-I a
ND
2.0
0.45
ug/kg
33213-65-9
Endosulfan-II
ND
2.0
0.46
ug/kg
76-44-8
Heptachlor a
ND
2.0
0.58
ug/kg
1024-57-3
Heptachlor epoxide a
ND
2.0
0.58
ug/kg
72-43-5
Methoxychlor
ND
3.9
0.79
ug/kg
8001-35-2
Toxaphene
ND
98
29
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
877-09-8
Tetrachloro-m-xylene
151% °
50-122%
2051-24-3
Decachlorobiphenyl
88%
50-133%
(a) Associated CCV outside of control limits
high, sample
was ND.
(b) Associated BS and CCV outside of control limits high, sample was ND.
(c) Outside control limits. However, Sample was ND.
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 26 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-02
Lab Sample ID: FA75651-2 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Percent Solids: 82.6
Project: 31 Harnett, Wilmington, NC
Page 1 of 1 N
Metals Analysis
Analyte Result RL
Units
DF
Prep
Analyzed
By
Method
Prep Method
Arsenic a 6.5 2.7
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
Barium a < 55 55
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
Cadmium a < 1.1 1.1
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050E 4
Chromium a 23.9 2.7
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
Lead a 58.9 5.5
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
Mercury 0.15 0.049
mg/kg
1
06/11/20
06/11/20
7c
SW846 7471E 1
SW846 7471B 3
Selenium a < 5.5 5.5
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
Silver a < 2.7 2.7
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
(1) Instrument QC Batch: MA16819
(2) Instrument QC Batch: MA16830
(3) Prep QC Batch: MP37368
(4) Prep QC Batch: MP37382
(a) Sample dilution required due to difficult matrix.
RL = Reporting Limit
6 27 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-02
Lab Sample ID: FA75651-2 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Percent Solids: 82.6
Project: 31 Harnett, Wilmington, NC
General Chemistry
Analyte Result
Chromium, Hexavalent a < 0.50
Solids, Percent 82.6
(a) Analysis performed at SGS Dayton, NJ.
RL = Reporting Limit
Page 1 of 1 N
RL Units
DF
Analyzed
By
Method
0.50 mg/kg
1
06/15/2012:27
ANJ
SW846306OA/7199
%
1
06/ 10/20 13:44
cs
SM19 2540G
6 28 of 177
FA75651

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: SB-03
Lab Sample ID: FA75651-3 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 80.5
Project: 31 Harnett, Wilmington, NC
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
Run #1 a F0095961.D
1
06/10/20 15:28
SP
n/a
n/a
VF3374
Run #2 b F0095936.1)
1
06/09/20 16:19
SP
n/a
n/a
VF3373
Initial Weight Final Volume
Run #1 8.35 g 5.0 ml
Run #2 8.11 g 5.0 ml
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
67-64-1
Acetone
93.5
150
74
ug/kg J
71-43-2
Benzene
ND
3.7
0.91
ug/kg
108-86-1
Bromobenzene
ND
3.7
0.74
ug/kg
74-97-5
Bromochloromethane
ND
3.7
1.1
ug/kg
75-27-4
Bromodichloromethane
ND
3.7
0.74
ug/kg
75-25-2
Bromoform
ND
3.7
0.74
ug/kg
78-93-3
2-Butanone (MEK)
ND
19
5.4
ug/kg
104-51-8
n-Butylbenzene
ND
3.7
0.74
ug/kg
135-98-8
sec-Butylbenzene
ND
3.7
0.74
ug/kg
98-06-6
tert-Butylbenzene
ND
3.7
0.74
ug/kg
56-23-5
Carbon Tetrachloride
ND
3.7
0.76
ug/kg
108-90-7
Chlorobenzene
ND
3.7
0.74
ug/kg
75-00-3
Chloroethane
ND
3.7
1.5
ug/kg
67-66-3
Chloroform
ND
3.7
0.99
ug/kg
95-49-8
o-Chlorotoluene
ND
3.7
0.74
ug/kg
106-43-4
p-Chlorotoluene
ND
3.7
0.74
ug/kg
124-48-1
Dibromochloromethane
ND
3.7
0.74
ug/kg
106-93-4
1,2-Dibromoethane
ND
3.7
0.74
ug/kg
75-71-8
Dichlorodifluoromethane
ND
3.7
1.5
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
3.7
0.74
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
3.7
0.74
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
3.7
0.86
ug/kg
75-34-3
1, 1 -Dichloroethane
ND
3.7
1.3
ug/kg
107-06-2
1,2-Dichloroethane
ND
3.7
0.74
ug/kg
75-35-4
1, 1 -Dichloroethylene
ND
3.7
0.74
ug/kg
156-59-2
cis-1,2-Dichloroethylene
ND
3.7
1.0
ug/kg
156-60-5
trans- 1, 2-Dichloroethylene
ND
3.7
0.74
ug/kg
78-87-5
1,2-Dichloropropane
ND
3.7
0.74
ug/kg
142-28-9
1,3-Dichloropropane
ND
3.7
0.74
ug/kg
594-20-7
2,2-Dichloropropane
ND
3.7
0.74
ug/kg
563-58-6
1, 1 -Dichloropropene
ND
3.7
0.76
ug/kg
10061-01-5
cis- 1, 3 -Dichloropropene
ND
3.7
0.74
ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 29 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-03
Lab Sample ID: FA75651-3 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 80.5
Project: 31 Harnett, Wilmington, NC
VOA List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
10061-02-6
trans- 1, 3-Dichloropropene
ND
3.7
0.74
ug/kg
108-20-3
Di -Isopropyl Ether
ND
3.7
1.7
ug/kg
64-17-5
Ethyl Alcohol
ND
300
56
ug/kg
100-41-4
Ethylbenzene
ND
3.7
0.74
ug/kg
591-78-6
2-Hexanone
ND
19
5.6
ug/kg
98-82-8
Isopropylbenzene
ND
3.7
0.74
ug/kg
99-87-6
p-Isopropyltoluene
0.98
3.7
0.74
ug/kg J
74-83-9
Methyl Bromide
ND
3.7
1.5
ug/kg
74-87-3
Methyl Chloride
ND
3.7
1.5
ug/kg
75-09-2
Methylene Chloride
ND
15
8.2
ug/kg
108-10-1
4-Methyl-2-pentanone (MIBK) ND
19
5.6
ug/kg
1634-04-4
Methyl Tert Butyl Ether
ND
3.7
0.74
ug/kg
91-20-3
Naphthalene
ND
3.7
1.5
ug/kg
103-65-1
n-Propylbenzene
ND
3.7
0.74
ug/kg
100-42-5
Styrene
ND
3.7
0.74
ug/kg
630-20-6
1, 1, 1,2-Tetrachloroethane
ND
3.7
0.77
ug/kg
79-34-5
1,1,2,2-Tetrachloroethane
ND
3.7
0.74
ug/kg
127-18-4
Tetrachloroethylene
ND
3.7
0.95
ug/kg
108-88-3
Toluene
ND
15
7.4
ug/kg
87-61-6
1,2,3-Trichlorobenzene
ND
3.7
1.0
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
3.7
0.74
ug/kg
71-55-6
1, 1, 1 -Trichloroethane
ND
3.7
0.74
ug/kg
79-00-5
1,1,2-Trichloroethane
ND
3.7
0.74
ug/kg
79-01-6
Trichloroethylene
ND
3.7
0.74
ug/kg
75-69-4
Trichlorofluoromethane
ND
3.7
1.5
ug/kg
96-18-4
1,2,3-Trichloropropane
ND
3.7
0.93
ug/kg
95-63-6
1,2,4-Trimethylbenzene
ND
3.7
0.74
ug/kg
108-67-8
1,3,5-Trimethylbenzene
ND
3.7
0.74
ug/kg
108-05-4
Vinyl Acetate
ND
19
12
ug/kg
75-01-4
Vinyl Chloride
ND
3.7
0.74
ug/kg
m,p-Xylene
ND
7.4
0.82
ug/kg
95-47-6
o-Xylene
ND
3.7
0.74
ug/kg
1330-20-7
Xylene (total)
ND
11
1.6
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
1868-53-7
Dibromofluoromethane
103%
104%
75-124%
17060-07-0
1,2-Dichloroethane-D4
100%
104%
72-135%
2037-26-5
Toluene-D8
111%
113%
75-126%
460-00-4
4-Bromofluorobenzene
131%
140% c
71-133%
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 30 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-03
Lab Sample ID: FA75651-3 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 80.5
Project: 31 Harnett, Wilmington, NC
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(a) Internal standard response(s) outside method criteria due to sample matrix interference; confirmed by
reanalysis.
(b) Confirmation run for surrogate recoveries.
(c) Outside control limits due to matrix interference.
Page 3 of 3 w
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 31 of 177
FA75651

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: SB-03
Lab Sample ID: FA75651-3 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8270E SW846 3550C Percent Solids: 80.5
Project: 31 Harnett, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 a 6F06185.D 10 06/23/20 19:45 MV 06/08/20 06:39 OP80524 S617240
Run #2
Initial Weight Final Volume
Run #1 30.3 g 1.0 ml
Run #2
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
65-85-0
Benzoic Acid
ND
10000
2000
ug/kg
59-50-7
4-Chloro-3-methyl Phenol
ND
2000
230
ug/kg
95-57-8
2-Chlorophenol
ND
2000
250
ug/kg
120-83-2
2,4-Dichlorophenol
ND
2000
240
ug/kg
105-67-9
2,4-Dimethylphenol
ND
2000
550
ug/kg
51-28-5
2,4-Dinitrophenol
ND
10000
2000
ug/kg
534-52-1
4,6-Dinitro-o-cresol
ND
4100
820
ug/kg
95-48-7
2-Methylphenol
ND
2000
250
ug/kg
3&4-Methylphenol
ND
2000
340
ug/kg
88-75-5
2-Nitrophenol
ND
2000
220
ug/kg
100-02-7
4-Nitrophenol
ND
10000
2000
ug/kg
87-86-5
Pentachlorophenolb
ND
10000
2000
ug/kg
108-95-2
Phenol
ND
2000
200
ug/kg
88-06-2
2,4,6-Trichlorophenol
ND
2000
240
ug/kg
83-32-9
Acenaphthene
ND
2000
220
ug/kg
208-96-8
Acenaphthylene
ND
2000
200
ug/kg
120-12-7
Anthracene
ND
2000
230
ug/kg
56-55-3
Benzo(a)anthracene
292
2000
200
ug/kg J
50-32-8
Benzo(a)pyrene
299
2000
240
ug/kg J
205-99-2
Benzo(b)fluoranthene
366
2000
220
ug/kg J
191-24-2
Benzo(g, h, i)perylene
ND
2000
210
ug/kg
207-08-9
Benzo(k)fluoranthene
ND
2000
270
ug/kg
100-51-6
Benzyl Alcohol
ND
2000
200
ug/kg
101-55-3
4-13romophenyl phenyl ether
ND
2000
210
ug/kg
85-68-7
Butyl benzyl phthalate
ND
2000
410
ug/kg
106-47-8
4-Chloroaniline
ND
2000
520
ug/kg
111-91-1
bis(2-Chloroethoxy)methane
ND
2000
200
ug/kg
111-44-4
bis(2-Chloroethyl)ether
ND
2000
240
ug/kg
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
2000
260
ug/kg
91-58-7
2-Chloronaphthalene
ND
2000
200
ug/kg
7005-72-3
4-Chlorophenyl phenyl ether
ND
2000
200
ug/kg
218-01-9
Chrysene
296
2000
210
ug/kg J
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 32 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-03
Lab Sample ID: FA75651-3 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8270E SW846 3550C Percent Solids: 80.5
Project: 31 Harnett, Wilmington, NC
ABN List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
53-70-3
Dibenzo(a,h)anthracene
ND
2000
260
ug/kg
132-64-9
Dibenzofaran
ND
2000
200
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
2000
200
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
2000
220
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
2000
270
ug/kg
91-94-1
3,3'-Dichlorobenzidine
ND
2000
490
ug/kg
84-66-2
Diethyl Phthalate
ND
4100
410
ug/kg
131-11-3
Dimethyl Phthalate
ND
2000
410
ug/kg
117-84-0
Di-n-octyl Phthalate
ND
2000
410
ug/kg
84-74-2
Di-n-butyl Phthalate
ND
4100
820
ug/kg
122-66-7
1,2-Diphenylhydrazine
ND
2000
200
ug/kg
117-81-7
bis(2-Ethylhexyl)phthalate
ND
4100
410
ug/kg
206-44-0
Fluoranthene
484
2000
200
ug/kg J
86-73-7
Fluorene
ND
2000
220
ug/kg
118-74-1
Hexachlorobenzene
ND
2000
210
ug/kg
87-68-3
Hexachlorobutadiene
ND
2000
210
ug/kg
77-47-4
Hexachlorocyclopentadiene
ND
2000
410
ug/kg
67-72-1
Hexachloroethane
ND
2000
240
ug/kg
193-39-5
Indeno(1,2,3-cd)pyrene
250
2000
250
ug/kg J
78-59-1
Isophorone
ND
2000
200
ug/kg
90-12-0
1-Methylnaphthalene
ND
2000
200
ug/kg
91-57-6
2-Methylnaphthalene
ND
2000
200
ug/kg
91-20-3
Naphthalene
ND
2000
200
ug/kg
98-95-3
Nitrobenzene
ND
2000
200
ug/kg
621-64-7
N-Nitrosodi-n-propylamine
ND
2000
200
ug/kg
86-30-6
N-Nitrosodiphenylamine
ND
2000
220
ug/kg
85-01-8
Phenanthrene
312
2000
200
ug/kg J
129-00-0
Pyrene
425
2000
240
ug/kg J
120-82-1
1,2,4-Trichlorobenzene
ND
2000
240
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
367-12-4
2-Fluorophenol
40%
40-102%
4165-62-2
Phenol-d5
45%
41-100%
118-79-6
2,4,6-Tribromophenol
54%
42-108%
4165-60-0
Nitrobenzene-d5
41%
40-105%
321-60-8
2-Fluorobiphenyl
67%
43-107%
1718-51-0
Terphenyl-dl4
48%
45-119%
(a) Dilution required due to matrix interference; extract was viscous.
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 33 of 177
FA75651

SGS North America Inc.
Report of Analysis
Tent Sample ID: SB-03
,ab Sample ID: FA75651-3 Date Sampled: 06/04/20
Ratrix: SO - Soil Date Received: 06/06/20
lthod: SW846 8270E SW846 3550C Percent Solids: 80.5
'roject: 31 Harnett, Wilmington, NC
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(b) Associated ICV outside control limits high, however sample ND.
Page 3 of 3 w
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 34 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-03
Lab Sample ID: FA75651-3 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8081B SW846 3546 Percent Solids: 80.5
Project: 31 Harnett, Wilmington, NC
Page 1 of 1 w
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 ST147927.1) 1 06/19/20 04:45 WH 06/16/20 08:06 OP80695 GST3550
Run #2
Initial Weight Final Volume
Run#1 14.9g 5.0ml
Run #2
Pesticide TCL List
CAS No.
Compound
Result
RL
309-00-2
Aldrin a
ND
2.1
319-84-6
alpha-BHC a
ND
2.1
319-85-7
beta-BHC a
ND
2.1
319-86-8
delta-BHC a
ND
2.1
58-89-9
gamma-BHC (Lindane) a
ND
2.1
5103-71-9
alpha -Chlordane a
ND
2.1
5103-74-2
gamma -Chlordane a
ND
2.1
60-57-1
Dieldrin
ND
2.1
72-54-8
4, 4' -DDD
ND
4.2
72-55-9
4,4'-DDE
ND
4.2
50-29-3
4, 4' -DDT
ND
4.2
72-20-8
Endrin
ND
4.2
1031-07-8
Endosulfan sulfate
ND
4.2
7421-93-4
Endrin aldehyde
ND
4.2
53494-70-5
Endrin ketone
ND
4.2
959-98-8
Endosulfan-I a
ND
2.1
33213-65-9
Endosulfan-II
ND
2.1
76-44-8
Heptachlor a
ND
2.1
1024-57-3
Heptachlor epoxide a
ND
2.1
72-43-5
Methoxychlor
ND
4.2
8001-35-2
Toxaphene
ND
100
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
877-09-8
Tetrachloro-m-xylene
140% b
2051-24-3
Decachlorobiphenyl
80%
(a) Associated CCV outside of control limits
high, sample
was ND.
(b) Outside control limits. However, Sample was ND.
MDL Units Q
0.66
ug/kg
0.66
ug/kg
0.61
ug/kg
0.59
ug/kg
0.63
ug/kg
0.65
ug/kg
0.60
ug/kg
0.58
ug/kg
0.58
ug/kg
0.76
ug/kg
0.64
ug/kg
1.1
ug/kg
0.55
ug/kg
0.48
ug/kg
0.65
ug/kg
0.48
ug/kg
0.49
ug/kg
0.62
ug/kg
0.61
ug/kg
0.83
ug/kg
31
ug/kg
Limits
50-122%
50-133%
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 35 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-03
Lab Sample ID: FA75651-3 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Percent Solids: 80.5
Project: 31 Harnett, Wilmington, NC
Page 1 of 1 w
Metals Analysis
Analyte Result RL
Units
DF
Prep
Analyzed
By
Method
Prep Method
Arsenic a 7.8 2.3
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
Barium a 49.0 46
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
Cadmium a < 0.92 0.92
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050E 4
Chromium a 31.8 2.3
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
Lead a 52.7 4.6
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050E 4
Mercury 0.15 0.046
mg/kg
1
06/11/20
06/11/20
7c
SW846 7471E 1
SW846 7471B 3
Selenium a < 4.6 4.6
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
Silver a < 2.3 2.3
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
(1) Instrument QC Batch: MA16819
(2) Instrument QC Batch: MA16830
(3) Prep QC Batch: MP37368
(4) Prep QC Batch: MP37382
(a) Sample dilution required due to difficult matrix.
RL = Reporting Limit
6 36 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-03
Lab Sample ID: FA75651-3 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Percent Solids: 80.5
Project: 31 Harnett, Wilmington, NC
General Chemistry
Analyte Result
Chromium, Hexavalent a 0.96
Solids, Percent 80.5
(a) Analysis performed at SGS Dayton, NJ.
RL = Reporting Limit
Page 1 of 1 w
RL Units
DF
Analyzed
By
Method
0.48 mg/kg
1
06/15/2012:34
ANJ
SW846306OA/7199
%
1
06/ 10/20 13:44
cs
SM19 2540G
6 37 of 177
FA75651

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: SB-04
Lab Sample ID: FA75651-4 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 83.5
Project: 31 Harnett, Wilmington, NC
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
Run #1 a F0095937.D
1
06/09/20 16:48
SP
n/a
n/a
VF3373
Run #2 b F0095962.1)
1
06/10/20 15:56
SP
n/a
n/a
VF3374
Initial Weight Final Volume
Run #1 8.80 g 5.0 ml
Run #2 8.60 g 5.0 ml
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
67-64-1
Acetone
ND
140
68
ug/kg
71-43-2
Benzene
ND
3.4
0.83
ug/kg
108-86-1
Bromobenzene
ND
3.4
0.68
ug/kg
74-97-5
Bromochloromethane
ND
3.4
1.0
ug/kg
75-27-4
Bromodichloromethane
ND
3.4
0.68
ug/kg
75-25-2
Bromoform
ND
3.4
0.68
ug/kg
78-93-3
2-Butanone (MEK)
ND
17
4.9
ug/kg
104-51-8
n-Butylbenzene
ND
3.4
0.68
ug/kg
135-98-8
sec-Butylbenzene
ND
3.4
0.68
ug/kg
98-06-6
tert-Butylbenzene
ND
3.4
0.68
ug/kg
56-23-5
Carbon Tetrachloride
ND
3.4
0.69
ug/kg
108-90-7
Chlorobenzene
ND
3.4
0.68
ug/kg
75-00-3
Chloroethane
ND
3.4
1.4
ug/kg
67-66-3
Chloroform
ND
3.4
0.91
ug/kg
95-49-8
o-Chlorotoluene
ND
3.4
0.68
ug/kg
106-43-4
p-Chlorotoluene
ND
3.4
0.68
ug/kg
124-48-1
Dibromochloromethane
ND
3.4
0.68
ug/kg
106-93-4
1,2-Dibromoethane
ND
3.4
0.68
ug/kg
75-71-8
Dichlorodifluoromethane
ND
3.4
1.4
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
3.4
0.68
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
3.4
0.68
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
3.4
0.78
ug/kg
75-34-3
1, 1 -Dichloroethane
ND
3.4
1.2
ug/kg
107-06-2
1,2-Dichloroethane
ND
3.4
0.68
ug/kg
75-35-4
1, 1 -Dichloroethylene
ND
3.4
0.68
ug/kg
156-59-2
cis-1,2-Dichloroethylene
ND
3.4
0.94
ug/kg
156-60-5
trans- 1, 2-Dichloroethylene
ND
3.4
0.68
ug/kg
78-87-5
1,2-Dichloropropane
ND
3.4
0.68
ug/kg
142-28-9
1,3-Dichloropropane
ND
3.4
0.68
ug/kg
594-20-7
2,2-Dichloropropane
ND
3.4
0.68
ug/kg
563-58-6
1, 1 -Dichloropropene
ND
3.4
0.69
ug/kg
10061-01-5
cis- 1, 3 -Dichloropropene
ND
3.4
0.68
ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 38 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-04
Lab Sample ID: FA75651-4 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 83.5
Project: 31 Harnett, Wilmington, NC
VOA List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
10061-02-6
trans- 1, 3-Dichloropropene
ND
3.4
0.68
ug/kg
108-20-3
Di -Isopropyl Ether
ND
3.4
1.6
ug/kg
64-17-5
Ethyl Alcohol
ND
270
51
ug/kg
100-41-4
Ethylbenzene
ND
3.4
0.68
ug/kg
591-78-6
2-Hexanone
ND
17
5.1
ug/kg
98-82-8
Isopropylbenzene
ND
3.4
0.68
ug/kg
99-87-6
p-Isopropyltoluene
ND
3.4
0.68
ug/kg
74-83-9
Methyl Bromide
ND
3.4
1.4
ug/kg
74-87-3
Methyl Chloride
ND
3.4
1.4
ug/kg
75-09-2
Methylene Chloride
ND
14
7.5
ug/kg
108-10-1
4-Methyl-2-pentanone (MIBK) ND
17
5.1
ug/kg
1634-04-4
Methyl Tert Butyl Ether
ND
3.4
0.68
ug/kg
91-20-3
Naphthalene
ND
3.4
1.4
ug/kg
103-65-1
n-Propylbenzene
ND
3.4
0.68
ug/kg
100-42-5
Styrene
ND
3.4
0.68
ug/kg
630-20-6
1, 1, 1,2-Tetrachloroethane
ND
3.4
0.70
ug/kg
79-34-5
1,1,2,2-Tetrachloroethane
ND
3.4
0.68
ug/kg
127-18-4
Tetrachloroethylene
ND
3.4
0.87
ug/kg
108-88-3
Toluene
7.1
14
6.8
ug/kg J
87-61-6
1,2,3-Trichlorobenzene
ND
3.4
0.95
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
3.4
0.68
ug/kg
71-55-6
1, 1, 1 -Trichloroethane
ND
3.4
0.68
ug/kg
79-00-5
1,1,2-Trichloroethane
ND
3.4
0.68
ug/kg
79-01-6
Trichloroethylene
ND
3.4
0.68
ug/kg
75-69-4
Trichlorofluoromethane
ND
3.4
1.4
ug/kg
96-18-4
1,2,3-Trichloropropane
ND
3.4
0.85
ug/kg
95-63-6
1,2,4-Trimethylbenzene
ND
3.4
0.68
ug/kg
108-67-8
1,3,5-Trimethylbenzene
ND
3.4
0.68
ug/kg
108-05-4
Vinyl Acetate
ND
17
11
ug/kg
75-01-4
Vinyl Chloride
ND
3.4
0.68
ug/kg
m,p-Xylene
ND
6.8
0.75
ug/kg
95-47-6
o-Xylene
ND
3.4
0.68
ug/kg
1330-20-7
Xylene (total)
ND
10
1.4
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
1868-53-7
Dibromofluoromethane
107%
104%
75-124%
17060-07-0
1,2-Dichloroethane-D4
106%
101%
72-135%
2037-26-5
Toluene-D8
115%
114%
75-126%
460-00-4
4-Bromofluorobenzene
146% c
141% c
71-133%
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 39 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-04
Lab Sample ID: FA75651-4 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 83.5
Project: 31 Harnett, Wilmington, NC
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(a) Internal standard response(s) outside method criteria due to sample matrix interference; confirmed by
reanalysis.
(b) Confirmation run for surrogate recoveries.
(c) Outside control limits due to matrix interference. Confirmed by reanalysis.
Page 3 of 3
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 40 of 177
FA75651

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: SB-04
Lab Sample ID: FA75651-4 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8270E SW846 3550C Percent Solids: 83.5
Project: 31 Harnett, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 a 9I009013.1) 5 06/12/20 23:51 MV 06/08/20 06:39 OP80524 S91334
Run #2
Initial Weight Final Volume
Run # 1 29.8 g 1.0 ml
Run #2
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
65-85-0
Benzoic Acid
ND
5000
1000
ug/kg
59-50-7
4-Chloro-3-methyl Phenol
ND
1000
110
ug/kg
95-57-8
2-Chlorophenol
ND
1000
120
ug/kg
120-83-2
2,4-Dichlorophenol
ND
1000
120
ug/kg
105-67-9
2,4-Dimethylphenol
ND
1000
270
ug/kg
51-28-5
2,4-Dinitrophenol
ND
5000
1000
ug/kg
534-52-1
4,6-Dinitro-o-cresol
ND
2000
400
ug/kg
95-48-7
2-Methylphenol
ND
1000
120
ug/kg
3&4-Methylphenol
ND
1000
170
ug/kg
88-75-5
2-Nitrophenol
ND
1000
110
ug/kg
100-02-7
4-Nitrophenol
ND
5000
1000
ug/kg
87-86-5
Pentachlorophenol
ND
5000
1000
ug/kg
108-95-2
Phenol
ND
1000
100
ug/kg
88-06-2
2,4,6-Trichlorophenol
ND
1000
120
ug/kg
83-32-9
Acenaphthene
ND
1000
110
ug/kg
208-96-8
Acenaphthylene
ND
1000
100
ug/kg
120-12-7
Anthracene
339
1000
110
ug/kg J
56-55-3
Benzo(a)anthracene
508
1000
100
ug/kg J
50-32-8
Benzo(a)pyrene
592
1000
120
ug/kg J
205-99-2
Benzo(b)fluoranthene
972
1000
110
ug/kg J
191-24-2
Benzo(g, h, i)perylene
319
1000
100
ug/kg J
207-08-9
Benzo(k)fluoranthene
289
1000
130
ug/kg J
100-51-6
Benzyl Alcohol
ND
1000
100
ug/kg
101-55-3
4-13romophenyl phenyl ether
ND
1000
100
ug/kg
85-68-7
Butyl benzyl phthalate
ND
1000
200
ug/kg
106-47-8
4-Chloroaniline
ND
1000
250
ug/kg
111-91-1
bis(2-Chloroethoxy)methane
ND
1000
100
ug/kg
111-44-4
bis(2-Chloroethyl)ether
ND
1000
120
ug/kg
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
1000
130
ug/kg
91-58-7
2-Chloronaphthalene
ND
1000
100
ug/kg
7005-72-3
4-Chlorophenyl phenyl ether
ND
1000
100
ug/kg
218-01-9
Chrysene
781
1000
100
ug/kg J
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 41 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-04
Lab Sample ID: FA75651-4 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8270E SW846 3550C Percent Solids: 83.5
Project: 31 Harnett, Wilmington, NC
ABN List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
53-70-3
Dibenzo(a,h)anthracene
ND
1000
130
ug/kg
132-64-9
Dibenzofaran
ND
1000
100
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
1000
100
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
1000
110
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
1000
130
ug/kg
91-94-1
3,3'-Dichlorobenzidine
ND
1000
240
ug/kg
84-66-2
Diethyl Phthalate
ND
2000
200
ug/kg
131-11-3
Dimethyl Phthalate
ND
1000
200
ug/kg
117-84-0
Di-n-octyl Phthalate
ND
1000
200
ug/kg
84-74-2
Di-n-butyl Phthalate
ND
2000
400
ug/kg
122-66-7
1,2-Diphenylhydrazine
ND
1000
100
ug/kg
117-81-7
bis(2-Ethylhexyl)phthalate
ND
2000
200
ug/kg
206-44-0
Fluoranthene
1060
1000
100
ug/kg
86-73-7
Fluorene
ND
1000
110
ug/kg
118-74-1
Hexachlorobenzene
ND
1000
100
ug/kg
87-68-3
Hexachlorobutadiene
ND
1000
100
ug/kg
77-47-4
Hexachlorocyclopentadiene
ND
1000
200
ug/kg
67-72-1
Hexachloroethane
ND
1000
120
ug/kg
193-39-5
Indeno(1,2,3-cd)pyrene
518
1000
120
ug/kg J
78-59-1
Isophorone
ND
1000
100
ug/kg
90-12-0
1-Methylnaphthalene
ND
1000
100
ug/kg
91-57-6
2-Methylnaphthalene
ND
1000
100
ug/kg
91-20-3
Naphthalene
ND
1000
100
ug/kg
98-95-3
Nitrobenzene
ND
1000
100
ug/kg
621-64-7
N-Nitrosodi-n-propylamine
ND
1000
100
ug/kg
86-30-6
N-Nitrosodiphenylamine
ND
1000
110
ug/kg
85-01-8
Phenanthrene
290
1000
100
ug/kg J
129-00-0
Pyrene
1240
1000
120
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
1000
120
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
367-12-4
2-Fluorophenol
93%
40-102%
4165-62-2
Phenol-d5
105% b
41-100%
118-79-6
2,4,6-Tribromophenol
111% b
42-108%
4165-60-0
Nitrobenzene-d5
87%
40-105%
321-60-8
2-Fluorobiphenyl
90%
43-107%
1718-51-0
Terphenyl-dl4
117%
45-119%
(a) Dilution required due to matrix interference; extract was viscous.
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 42 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-04
Lab Sample ID: FA75651-4 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8270E SW846 3550C Percent Solids: 83.5
Project: 31 Harnett, Wilmington, NC
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(b) Outside control limits.
Page 3 of 3
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 43 of 177
FA75651

SGS North America Inc.
Report of Analysis
Tent Sample ID: SB-04
,ab Sample ID: FA75651-4 Date Sampled: 06/04/20
Rtrix: SO - Soil Date Received: 06/06/20
lthod: SW846 8081B SW846 3546 Percent Solids: 83.5
'roject: 31 Harnett, Wilmington, NC
Page 1 of 1 P
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
Run #1 ST147928.1)
1
06/19/20 05:02
WH
06/16/20 08:06
OP80695
GST3550
Run #2 ST147910.1)
10
06/18/20 23:51
WH
06/16/20 08:06
OP80695
GST3550
Initial Weight Final Volume
un#1 15.1 g 5.0ml
.un #2 15.1 g 5.0 ml
Pesticide TCL List
CAS No.
Compound
Result
RL
MDL
Units Q
309-00-2
Aldrin a
ND
2.0
0.63
ug/kg
319-84-6
alpha-BHC a
ND
2.0
0.63
ug/kg
319-85-7
beta-BHC a
ND
2.0
0.58
ug/kg
319-86-8
delta-BHC a
ND
2.0
0.56
ug/kg
58-89-9
gamma-BHC (Lindane) a
ND
2.0
0.59
ug/kg
5103-71-9
alpha -Chlordane b
ND c
20
6.2
ug/kg
5103-74-2
gamma -Chlordane b
ND c
20
5.7
ug/kg
60-57-1
Dieldrin
ND
2.0
0.56
ug/kg
72-54-8
4,4'-DDD b
ND °
40
5.5
ug/kg
72-55-9
4,4'-DDE b
ND °
40
7.2
ug/kg
50-29-3
4,4'-DDT
ND
4.0
0.61
ug/kg
72-20-8
Endrin
ND
4.0
1.0
ug/kg
1031-07-8
Endosulfan sulfate
ND
4.0
0.52
ug/kg
7421-93-4
Endrin aldehyde
ND
4.0
0.46
ug/kg
53494-70-5
Endrin ketone
ND
4.0
0.62
ug/kg
959-98-8
Endosulfan-I a
ND
2.0
0.46
ug/kg
33213-65-9
Endosulfan-II
ND
2.0
0.47
ug/kg
76-44-8
Heptachlor a
ND
2.0
0.59
ug/kg
1024-57-3
Heptachlor epoxide a
ND
2.0
0.58
ug/kg
72-43-5
Methoxychlor
ND
4.0
0.79
ug/kg
8001-35-2
Toxaphene
ND
99
30
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
877-09-8
Tetrachloro-m-xylene
157% e
126% d
50-122%
2051-24-3
Decachlorobiphenyl
87%
105%
50-133%
(a) Associated CCV outside of control limits high, sample was ND.
(b) Dilution required due to matrix interference.
(c) Result is from Run# 2
(d) Outside control limits due to dilution.
(e) Outside control limits. However, Sample was ND.
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 44 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-04
Lab Sample ID: FA75651-4 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Percent Solids: 83.5
Project: 31 Harnett, Wilmington, NC
Page 1 of 1 P
Metals Analysis
Analyte Result RL
Units
DF
Prep
Analyzed
By
Method
Prep Method
Arsenic a 5.3 2.3
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
Barium a < 46 46
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
Cadmium a < 0.91 0.91
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050E 4
Chromium a 16.2 2.3
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
Lead a 49.4 4.6
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
Mercury 0.15 0.047
mg/kg
1
06/11/20
06/11/20
7c
SW846 7471E 1
SW846 7471B 3
Selenium a < 4.6 4.6
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
Silver a < 2.3 2.3
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
(1) Instrument QC Batch: MA16819
(2) Instrument QC Batch: MA16830
(3) Prep QC Batch: MP37368
(4) Prep QC Batch: MP37382
(a) Sample dilution required due to difficult matrix.
RL = Reporting Limit
6 45 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-04
Lab Sample ID: FA75651-4 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Percent Solids: 83.5
Project: 31 Harnett, Wilmington, NC
General Chemistry
Analyte Result
Chromium, Hexavalent a 0.81
Solids, Percent 83.5
(a) Analysis performed at SGS Dayton, NJ.
RL = Reporting Limit
Page 1 of 1 P
RL Units
DF
Analyzed
By
Method
0.47 mg/kg
1
06/15/2013:06
ANJ
SW846306OA/7199
%
1
06/ 10/20 13:44
cs
SM19 2540G
6 46 of 177
FA75651

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: SB-05
Lab Sample ID: FA75651-5 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 74.4
Project: 31 Harnett, Wilmington, NC
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
Run #1 a F0095938.D
1
06/09/20 17:16
SP
n/a
n/a
VF3373
Run #2 b F0095963.1)
1
06/10/20 16:23
SP
n/a
n/a
VF3374
Initial Weight Final Volume
Run #1 7.75 g 5.0 ml
Run #2 8.41 g 5.0 ml
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
67-64-1
Acetone
146
170
87
ug/kg J
71-43-2
Benzene
ND
4.3
1.1
ug/kg
108-86-1
Bromobenzene
ND
4.3
0.87
ug/kg
74-97-5
Bromochloromethane
ND
4.3
1.3
ug/kg
75-27-4
Bromodichloromethane
ND
4.3
0.87
ug/kg
75-25-2
Bromoform
ND
4.3
0.87
ug/kg
78-93-3
2-Butanone (MEK)
28.1
22
6.3
ug/kg
104-51-8
n-Butylbenzene
ND
4.3
0.87
ug/kg
135-98-8
sec-Butylbenzene
ND
4.3
0.87
ug/kg
98-06-6
tert-Butylbenzene
ND
4.3
0.87
ug/kg
56-23-5
Carbon Tetrachloride
ND
4.3
0.88
ug/kg
108-90-7
Chlorobenzene
ND
4.3
0.87
ug/kg
75-00-3
Chloroethane
ND
4.3
1.7
ug/kg
67-66-3
Chloroform
ND
4.3
1.2
ug/kg
95-49-8
o-Chlorotoluene
ND
4.3
0.87
ug/kg
106-43-4
p-Chlorotoluene
ND
4.3
0.87
ug/kg
124-48-1
Dibromochloromethane
ND
4.3
0.87
ug/kg
106-93-4
1,2-Dibromoethane
ND
4.3
0.87
ug/kg
75-71-8
Dichlorodifluoromethane
ND
4.3
1.7
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
4.3
0.87
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
4.3
0.87
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
4.3
1.0
ug/kg
75-34-3
1, 1 -Dichloroethane
ND
4.3
1.5
ug/kg
107-06-2
1,2-Dichloroethane
ND
4.3
0.87
ug/kg
75-35-4
1, 1 -Dichloroethylene
ND
4.3
0.87
ug/kg
156-59-2
cis-1,2-Dichloroethylene
ND
4.3
1.2
ug/kg
156-60-5
trans- 1, 2-Dichloroethylene
ND
4.3
0.87
ug/kg
78-87-5
1,2-Dichloropropane
ND
4.3
0.87
ug/kg
142-28-9
1,3-Dichloropropane
ND
4.3
0.87
ug/kg
594-20-7
2,2-Dichloropropane
ND
4.3
0.87
ug/kg
563-58-6
1, 1 -Dichloropropene
ND
4.3
0.88
ug/kg
10061-01-5
cis- 1, 3 -Dichloropropene
ND
4.3
0.87
ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 47 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-05
Lab Sample ID: FA75651-5 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 74.4
Project: 31 Harnett, Wilmington, NC
VOA List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
10061-02-6
trans- 1, 3-Dichloropropene
ND
4.3
0.87
ug/kg
108-20-3
Di -Isopropyl Ether
ND
4.3
2.0
ug/kg
64-17-5
Ethyl Alcohol
ND
350
65
ug/kg
100-41-4
Ethylbenzene
ND
4.3
0.87
ug/kg
591-78-6
2-Hexanone
ND
22
6.5
ug/kg
98-82-8
Isopropylbenzene
ND
4.3
0.87
ug/kg
99-87-6
p-Isopropyltoluene
2.7
4.3
0.87
ug/kg J
74-83-9
Methyl Bromide
ND
4.3
1.7
ug/kg
74-87-3
Methyl Chloride
ND
4.3
1.7
ug/kg
75-09-2
Methylene Chloride
ND
17
9.5
ug/kg
108-10-1
4-Methyl-2-pentanone (MIBK) ND
22
6.5
ug/kg
1634-04-4
Methyl Tert Butyl Ether
ND
4.3
0.87
ug/kg
91-20-3
Naphthalene
ND
4.3
1.7
ug/kg
103-65-1
n-Propylbenzene
ND
4.3
0.87
ug/kg
100-42-5
Styrene
ND
4.3
0.87
ug/kg
630-20-6
1, 1, 1,2-Tetrachloroethane
ND
4.3
0.89
ug/kg
79-34-5
1,1,2,2-Tetrachloroethane
ND
4.3
0.87
ug/kg
127-18-4
Tetrachloroethylene
ND
4.3
1.1
ug/kg
108-88-3
Toluene
ND
17
8.7
ug/kg
87-61-6
1,2,3-Trichlorobenzene
ND
4.3
1.2
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
4.3
0.87
ug/kg
71-55-6
1, 1, 1 -Trichloroethane
ND
4.3
0.87
ug/kg
79-00-5
1,1,2-Trichloroethane
ND
4.3
0.87
ug/kg
79-01-6
Trichloroethylene
ND
4.3
0.87
ug/kg
75-69-4
Trichlorofluoromethane
ND
4.3
1.7
ug/kg
96-18-4
1,2,3-Trichloropropane
ND
4.3
1.1
ug/kg
95-63-6
1,2,4-Trimethylbenzene
ND
4.3
0.87
ug/kg
108-67-8
1,3,5-Trimethylbenzene
ND
4.3
0.87
ug/kg
108-05-4
Vinyl Acetate
ND
22
14
ug/kg
75-01-4
Vinyl Chloride
ND
4.3
0.87
ug/kg
m,p-Xylene
ND
8.7
0.95
ug/kg
95-47-6
o-Xylene
ND
4.3
0.87
ug/kg
1330-20-7
Xylene (total)
ND
13
1.8
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
1868-53-7
Dibromofluoromethane
111%
112%
75-124%
17060-07-0
1,2-Dichloroethane-D4
109%
104%
72-135%
2037-26-5
Toluene-D8
135% c
131% c
75-126%
460-00-4
4-Bromofluorobenzene
160% c
154% c
71-133%
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 48 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-05
Lab Sample ID: FA75651-5 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 74.4
Project: 31 Harnett, Wilmington, NC
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(a) Internal standard response(s) outside method criteria due to sample matrix interference; confirmed by
reanalysis.
(b) Confirmation run for surrogate recoveries.
(c) Outside control limits due to matrix interference. Confirmed by reanalysis.
Page 3 of 3 P
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 49 of 177
FA75651

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: SB-05
Lab Sample ID: FA75651-5 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8270E SW846 3550C Percent Solids: 74.4
Project: 31 Harnett, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 a 6F06186.D 10 06/23/20 20:11 MV 06/08/20 06:39 OP80524 S617240
Run #2
Initial Weight Final Volume
Run # 1 29.8 g 1.0 ml
Run #2
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
65-85-0
Benzoic Acid
ND
11000
2300
ug/kg
59-50-7
4-Chloro-3-methyl Phenol
ND
2300
250
ug/kg
95-57-8
2-Chlorophenol
ND
2300
280
ug/kg
120-83-2
2,4-Dichlorophenol
ND
2300
260
ug/kg
105-67-9
2,4-Dimethylphenol
ND
2300
600
ug/kg
51-28-5
2,4-Dinitrophenol
ND
11000
2300
ug/kg
534-52-1
4,6-Dinitro-o-cresol
ND
4500
900
ug/kg
95-48-7
2-Methylphenol
ND
2300
270
ug/kg
3&4-Methylphenol
ND
2300
370
ug/kg
88-75-5
2-Nitrophenol
ND
2300
240
ug/kg
100-02-7
4-Nitrophenol
ND
11000
2300
ug/kg
87-86-5
Pentachlorophenolb
ND
11000
2300
ug/kg
108-95-2
Phenol
ND
2300
230
ug/kg
88-06-2
2,4,6-Trichlorophenol
ND
2300
260
ug/kg
83-32-9
Acenaphthene
ND
2300
240
ug/kg
208-96-8
Acenaphthylene
ND
2300
230
ug/kg
120-12-7
Anthracene
491
2300
250
ug/kg J
56-55-3
Benzo(a)anthracene
458
2300
230
ug/kg J
50-32-8
Benzo(a)pyrene
414
2300
270
ug/kg J
205-99-2
Benzo(b)fluoranthene
561
2300
250
ug/kg J
191-24-2
Benzo(g, h, i)perylene
259
2300
230
ug/kg J
207-08-9
Benzo(k)fluoranthene
ND
2300
300
ug/kg
100-51-6
Benzyl Alcohol
ND
2300
230
ug/kg
101-55-3
4-13romophenyl phenyl ether
ND
2300
230
ug/kg
85-68-7
Butyl benzyl phthalate
ND
2300
450
ug/kg
106-47-8
4-Chloroaniline
ND
2300
570
ug/kg
111-91-1
bis(2-Chloroethoxy)methane
ND
2300
230
ug/kg
111-44-4
bis(2-Chloroethyl)ether
ND
2300
260
ug/kg
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
2300
280
ug/kg
91-58-7
2-Chloronaphthalene
ND
2300
230
ug/kg
7005-72-3
4-Chlorophenyl phenyl ether
ND
2300
230
ug/kg
218-01-9
Chrysene
476
2300
230
ug/kg J
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 50 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-05
Lab Sample ID: FA75651-5 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8270E SW846 3550C Percent Solids: 74.4
Project: 31 Harnett, Wilmington, NC
ABN List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
53-70-3
Dibenzo(a,h)anthracene
ND
2300
280
ug/kg
132-64-9
Dibenzofaran
ND
2300
230
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
2300
230
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
2300
240
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
2300
300
ug/kg
91-94-1
3,3'-Dichlorobenzidine
ND
2300
540
ug/kg
84-66-2
Diethyl Phthalate
ND
4500
450
ug/kg
131-11-3
Dimethyl Phthalate
ND
2300
450
ug/kg
117-84-0
Di-n-octyl Phthalate
ND
2300
450
ug/kg
84-74-2
Di-n-butyl Phthalate
ND
4500
900
ug/kg
122-66-7
1,2-Diphenylhydrazine
ND
2300
230
ug/kg
117-81-7
bis(2-Ethylhexyl)phthalate
ND
4500
450
ug/kg
206-44-0
Fluoranthene
971
2300
230
ug/kg J
86-73-7
Fluorene
ND
2300
240
ug/kg
118-74-1
Hexachlorobenzene
ND
2300
230
ug/kg
87-68-3
Hexachlorobutadiene
ND
2300
230
ug/kg
77-47-4
Hexachlorocyclopentadiene
ND
2300
450
ug/kg
67-72-1
Hexachloroethane
ND
2300
270
ug/kg
193-39-5
Indeno(1,2,3-cd)pyrene
310
2300
270
ug/kg J
78-59-1
Isophorone
ND
2300
230
ug/kg
90-12-0
1-Methylnaphthalene
ND
2300
230
ug/kg
91-57-6
2-Methylnaphthalene
ND
2300
230
ug/kg
91-20-3
Naphthalene
ND
2300
230
ug/kg
98-95-3
Nitrobenzene
ND
2300
230
ug/kg
621-64-7
N-Nitrosodi-n-propylamine
ND
2300
230
ug/kg
86-30-6
N-Nitrosodiphenylamine
ND
2300
240
ug/kg
85-01-8
Phenanthrene
507
2300
230
ug/kg J
129-00-0
Pyrene
790
2300
260
ug/kg J
120-82-1
1,2,4-Trichlorobenzene
ND
2300
270
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
367-12-4
2-Fluorophenol
34% °
40-102%
4165-62-2
Phenol-d5
40% °
41-100%
118-79-6
2,4,6-Tribromophenol
52%
42-108%
4165-60-0
Nitrobenzene-d5
37% °
40-105%
321-60-8
2-Fluorobiphenyl
60%
43-107%
1718-51-0
Terphenyl-dl4
45%
45-119%
(a) Dilution required due to matrix interference; extract was viscous.
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 51 of 177
FA75651

SGS North America Inc.
Report of Analysis
Tent Sample ID: SB-05
,ab Sample ID: FA75651-5 Date Sampled: 06/04/20
Ratrix: SO - Soil Date Received: 06/06/20
lthod: SW846 8270E SW846 3550C Percent Solids: 74.4
'roject: 31 Harnett, Wilmington, NC
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(b) Associated ICV outside control limits high, however sample ND.
(c) Outside control limits due to dilution.
Page 3 of 3 P
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 52 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-05
Lab Sample ID: FA75651-5 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8081B SW846 3546 Percent Solids: 74.4
Project: 31 Harnett, Wilmington, NC
Page 1 of 1 P
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 ST147929.1) 1 06/19/20 05:19 WH 06/16/20 08:06 OP80695 GST3550
Run #2
Initial Weight Final Volume
Run#1 15.4g 5.0ml
Run #2
Pesticide TCL List
CAS No.
Compound
Result
RL
MDL
Units Q
309-00-2
Aldrin a
ND
2.2
0.69
ug/kg
319-84-6
alpha-BHC b
ND
2.2
0.69
ug/kg
319-85-7
beta-BHC a
ND
2.2
0.64
ug/kg
319-86-8
delta-BHC a
ND
2.2
0.62
ug/kg
58-89-9
gamma-BHC (Lindane) a
ND
2.2
0.65
ug/kg
5103-71-9
alpha -Chlordane a
ND
2.2
0.68
ug/kg
5103-74-2
gamma -Chlordane a
ND
2.2
0.63
ug/kg
60-57-1
Dieldrin
ND
2.2
0.61
ug/kg
72-54-8
4,4'-DDD
ND
4.4
0.60
ug/kg
72-55-9
4,4'-DDE
ND
4.4
0.79
ug/kg
50-29-3
4,4'-DDT
ND
4.4
0.67
ug/kg
72-20-8
Endrin
ND
4.4
1.1
ug/kg
1031-07-8
Endosulfan sulfate
ND
4.4
0.58
ug/kg
7421-93-4
Endrin aldehyde
ND
4.4
0.51
ug/kg
53494-70-5
Endrin ketone
ND
4.4
0.69
ug/kg
959-98-8
Endosulfan-I a
ND
2.2
0.50
ug/kg
33213-65-9
Endosulfan-II
ND
2.2
0.51
ug/kg
76-44-8
Heptachlor a
ND
2.2
0.65
ug/kg
1024-57-3
Heptachlor epoxide a
ND
2.2
0.64
ug/kg
72-43-5
Methoxychlor
ND
4.4
0.87
ug/kg
8001-35-2
Toxaphene
ND
110
33
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
877-09-8
Tetrachloro-m-xylene
145% °
50-122%
2051-24-3
Decachlorobiphenyl
85%
50-133%
(a) Associated CCV outside of control limits
high, sample
was ND.
(b) Associated BS and CCV outside of control limits high, sample was ND.
(c) Outside control limits. However, Sample was ND.
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 53 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-05
Lab Sample ID: FA75651-5 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Percent Solids: 74.4
Project: 31 Harnett, Wilmington, NC
Page 1 of 1 P
Metals Analysis
Analyte Result RL
Units
DF
Prep
Analyzed
By
Method
Prep Method
Arsenic a 4.2 2.8
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
Barium a < 56 56
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
Cadmium a < 1.1 1.1
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050E 4
Chromium a 12.7 2.8
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
Lead a 45.1 5.6
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050E 4
Mercury 0.095 0.053
mg/kg
1
06/11/20
06/11/20
7c
SW846 7471E 1
SW846 7471B 3
Selenium a < 5.6 5.6
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
Silver a < 2.8 2.8
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
(1) Instrument QC Batch: MA16819
(2) Instrument QC Batch: MA16830
(3) Prep QC Batch: MP37368
(4) Prep QC Batch: MP37382
(a) Sample dilution required due to difficult matrix.
RL = Reporting Limit
6 54 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-05
Lab Sample ID: FA75651-5 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Percent Solids: 74.4
Project: 31 Harnett, Wilmington, NC
General Chemistry
Analyte Result
Chromium, Hexavalent a 0.61
Solids, Percent 74.4
(a) Analysis performed at SGS Dayton, NJ.
RL = Reporting Limit
Page 1 of 1 P
RL Units
DF
Analyzed
By
Method
0.56 mg/kg
1
06/15/2013:31
Ar1J
SW846306OA/7199
%
1
06/ 10/20 13:44
cs
SM19 2540G
6 55 of 177
FA75651

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: SB-06
Lab Sample ID: FA75651-6 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 87.8
Project: 31 Harnett, Wilmington, NC
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
Run #1 a F0095939.D
1
06/09/20 17:45
SP
n/a
n/a
VF3373
Run #2 b F0095964.1)
1
06/10/20 16:51
SP
n/a
n/a
VF3374
Initial Weight Final Volume
Run # 1 6.18 g 5.0 ml
Run #2 7.11 g 5.0 ml
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
67-64-1
Acetone
144
180
92
ug/kg J
71-43-2
Benzene
ND
4.6
1.1
ug/kg
108-86-1
Bromobenzene
ND
4.6
0.92
ug/kg
74-97-5
Bromochloromethane
ND
4.6
1.4
ug/kg
75-27-4
Bromodichloromethane
ND
4.6
0.92
ug/kg
75-25-2
Bromoform
ND
4.6
0.92
ug/kg
78-93-3
2-Butanone (MEK)
ND
23
6.7
ug/kg
104-51-8
n-Butylbenzene
ND
4.6
0.92
ug/kg
135-98-8
sec-Butylbenzene
ND
4.6
0.92
ug/kg
98-06-6
tert-Butylbenzene
ND
4.6
0.92
ug/kg
56-23-5
Carbon Tetrachloride
ND
4.6
0.94
ug/kg
108-90-7
Chlorobenzene
ND
4.6
0.92
ug/kg
75-00-3
Chloroethane
ND
4.6
1.8
ug/kg
67-66-3
Chloroform
ND
4.6
1.2
ug/kg
95-49-8
o-Chlorotoluene
ND
4.6
0.92
ug/kg
106-43-4
p-Chlorotoluene
ND
4.6
0.92
ug/kg
124-48-1
Dibromochloromethane
ND
4.6
0.92
ug/kg
106-93-4
1,2-Dibromoethane
ND
4.6
0.92
ug/kg
75-71-8
Dichlorodifluoromethane
ND
4.6
1.8
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
4.6
0.92
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
4.6
0.92
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
4.6
1.1
ug/kg
75-34-3
1, 1 -Dichloroethane
ND
4.6
1.6
ug/kg
107-06-2
1,2-Dichloroethane
ND
4.6
0.92
ug/kg
75-35-4
1, 1 -Dichloroethylene
ND
4.6
0.92
ug/kg
156-59-2
cis-1,2-Dichloroethylene
ND
4.6
1.3
ug/kg
156-60-5
trans- 1, 2-Dichloroethylene
ND
4.6
0.92
ug/kg
78-87-5
1,2-Dichloropropane
ND
4.6
0.92
ug/kg
142-28-9
1,3-Dichloropropane
ND
4.6
0.92
ug/kg
594-20-7
2,2-Dichloropropane
ND
4.6
0.92
ug/kg
563-58-6
1, 1 -Dichloropropene
ND
4.6
0.94
ug/kg
10061-01-5
cis- 1, 3 -Dichloropropene
ND
4.6
0.92
ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 56 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-06
Lab Sample ID: FA75651-6 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 87.8
Project: 31 Harnett, Wilmington, NC
VOA List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
10061-02-6
trans- 1, 3-Dichloropropene
ND
4.6
0.92
ug/kg
108-20-3
Di -Isopropyl Ether
ND
4.6
2.1
ug/kg
64-17-5
Ethyl Alcohol
ND
370
69
ug/kg
100-41-4
Ethylbenzene
ND
4.6
0.92
ug/kg
591-78-6
2-Hexanone
ND
23
6.9
ug/kg
98-82-8
Isopropylbenzene
ND
4.6
0.92
ug/kg
99-87-6
p-Isopropyltoluene
1.1
4.6
0.92
ug/kg J
74-83-9
Methyl Bromide
ND
4.6
1.8
ug/kg
74-87-3
Methyl Chloride
ND
4.6
1.8
ug/kg
75-09-2
Methylene Chloride
ND
18
10
ug/kg
108-10-1
4-Methyl-2-pentanone (MIBK) ND
23
6.9
ug/kg
1634-04-4
Methyl Tert Butyl Ether
ND
4.6
0.92
ug/kg
91-20-3
Naphthalene
ND
4.6
1.8
ug/kg
103-65-1
n-Propylbenzene
ND
4.6
0.92
ug/kg
100-42-5
Styrene
ND
4.6
0.92
ug/kg
630-20-6
1, 1, 1,2-Tetrachloroethane
ND
4.6
0.95
ug/kg
79-34-5
1,1,2,2-Tetrachloroethane
ND
4.6
0.92
ug/kg
127-18-4
Tetrachloroethylene
ND
4.6
1.2
ug/kg
108-88-3
Toluene
10.3
18
9.2
ug/kg J
87-61-6
1,2,3-Trichlorobenzene
ND
4.6
1.3
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
4.6
0.92
ug/kg
71-55-6
1, 1, 1 -Trichloroethane
ND
4.6
0.92
ug/kg
79-00-5
1,1,2-Trichloroethane
ND
4.6
0.92
ug/kg
79-01-6
Trichloroethylene
ND
4.6
0.92
ug/kg
75-69-4
Trichlorofluoromethane
ND
4.6
1.8
ug/kg
96-18-4
1,2,3-Trichloropropane
ND
4.6
1.2
ug/kg
95-63-6
1,2,4-Trimethylbenzene
ND
4.6
0.92
ug/kg
108-67-8
1,3,5-Trimethylbenzene
ND
4.6
0.92
ug/kg
108-05-4
Vinyl Acetate
ND
23
15
ug/kg
75-01-4
Vinyl Chloride
ND
4.6
0.92
ug/kg
m,p-Xylene
ND
9.2
1.0
ug/kg
95-47-6
o-Xylene
ND
4.6
0.92
ug/kg
1330-20-7
Xylene (total)
ND
14
1.9
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
1868-53-7
Dibromofluoromethane
105%
106%
75-124%
17060-07-0
1,2-Dichloroethane-D4
103%
103%
72-135%
2037-26-5
Toluene-D8
111%
112%
75-126%
460-00-4
4-Bromofluorobenzene
138% c
138% c
71-133%
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 57 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-06
Lab Sample ID: FA75651-6 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 87.8
Project: 31 Harnett, Wilmington, NC
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(a) Internal standard response(s) outside method criteria due to sample matrix interference; confirmed by
reanalysis.
(b) Confirmation run for surrogate recoveries.
(c) Outside control limits due to matrix interference. Confirmed by reanalysis.
Page 3 of 3
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 58 of 177
FA75651

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: SB-06
Lab Sample ID: FA75651-6 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8270E SW846 3550C Percent Solids: 87.8
Project: 31 Harnett, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 a 6F06187.D 10 06/23/20 20:37 MV 06/08/20 06:39 OP80524 S617240
Run #2
Initial Weight Final Volume
Run # 1 29.7 g 1.0 ml
Run #2
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units
65-85-0
Benzoic Acid
ND
9600
1900
ug/kg
59-50-7
4-Chloro-3-methyl Phenol
ND
1900
220
ug/kg
95-57-8
2-Chlorophenol
ND
1900
240
ug/kg
120-83-2
2,4-Dichlorophenol
ND
1900
220
ug/kg
105-67-9
2,4-Dimethylphenol
ND
1900
510
ug/kg
51-28-5
2,4-Dinitrophenol
ND
9600
1900
ug/kg
534-52-1
4,6-Dinitro-o-cresol
ND
3800
770
ug/kg
95-48-7
2-Methylphenol
ND
1900
230
ug/kg
3&4-Methylphenol
ND
1900
320
ug/kg
88-75-5
2-Nitrophenol
ND
1900
210
ug/kg
100-02-7
4-Nitrophenol
ND
9600
1900
ug/kg
87-86-5
Pentachlorophenolb
ND
9600
1900
ug/kg
108-95-2
Phenol
ND
1900
190
ug/kg
88-06-2
2,4,6-Trichlorophenol
ND
1900
220
ug/kg
83-32-9
Acenaphthene
ND
1900
200
ug/kg
208-96-8
Acenaphthylene
ND
1900
190
ug/kg
120-12-7
Anthracene
ND
1900
210
ug/kg
56-55-3
Benzo(a)anthracene
225
1900
190
ug/kg
50-32-8
Benzo(a)pyrene
ND
1900
230
ug/kg
205-99-2
Benzo(b)fluoranthene
263
1900
210
ug/kg
191-24-2
Benzo(g, h, i)perylene
ND
1900
200
ug/kg
207-08-9
Benzo(k)fluoranthene
ND
1900
250
ug/kg
100-51-6
Benzyl Alcohol
ND
1900
190
ug/kg
101-55-3
4-13romophenyl phenyl ether
ND
1900
200
ug/kg
85-68-7
Butyl benzyl phthalate
ND
1900
380
ug/kg
106-47-8
4-Chloroaniline
ND
1900
480
ug/kg
111-91-1
bis(2-Chloroethoxy)methane
ND
1900
190
ug/kg
111-44-4
bis(2-Chloroethyl)ether
ND
1900
220
ug/kg
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
1900
240
ug/kg
91-58-7
2-Chloronaphthalene
ND
1900
190
ug/kg
7005-72-3
4-Chlorophenyl phenyl ether
ND
1900
190
ug/kg
218-01-9
Chrysene
ND
1900
200
ug/kg
J
J
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 59 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-06
Lab Sample ID: FA75651-6 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8270E SW846 3550C Percent Solids: 87.8
Project: 31 Harnett, Wilmington, NC
ABN List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
53-70-3
Dibenzo(a,h)anthracene
ND
1900
240
ug/kg
132-64-9
Dibenzofaran
ND
1900
190
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
1900
190
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
1900
210
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
1900
260
ug/kg
91-94-1
3,3'-Dichlorobenzidine
ND
1900
460
ug/kg
84-66-2
Diethyl Phthalate
ND
3800
380
ug/kg
131-11-3
Dimethyl Phthalate
ND
1900
380
ug/kg
117-84-0
Di-n-octyl Phthalate
ND
1900
380
ug/kg
84-74-2
Di-n-butyl Phthalate
ND
3800
770
ug/kg
122-66-7
1,2-Diphenylhydrazine
ND
1900
190
ug/kg
117-81-7
bis(2-Ethylhexyl)phthalate
ND
3800
380
ug/kg
206-44-0
Fluoranthene
303
1900
190
ug/kg J
86-73-7
Fluorene
ND
1900
210
ug/kg
118-74-1
Hexachlorobenzene
ND
1900
200
ug/kg
87-68-3
Hexachlorobutadiene
ND
1900
190
ug/kg
77-47-4
Hexachlorocyclopentadiene
ND
1900
380
ug/kg
67-72-1
Hexachloroethane
ND
1900
230
ug/kg
193-39-5
Indeno(1,2,3-cd)pyrene
ND
1900
230
ug/kg
78-59-1
Isophorone
ND
1900
190
ug/kg
90-12-0
1-Methylnaphthalene
ND
1900
190
ug/kg
91-57-6
2-Methylnaphthalene
ND
1900
190
ug/kg
91-20-3
Naphthalene
ND
1900
190
ug/kg
98-95-3
Nitrobenzene
ND
1900
190
ug/kg
621-64-7
N-Nitrosodi-n-propylamine
ND
1900
190
ug/kg
86-30-6
N-Nitrosodiphenylamine
ND
1900
210
ug/kg
85-01-8
Phenanthrene
ND
1900
190
ug/kg
129-00-0
Pyrene
293
1900
220
ug/kg J
120-82-1
1,2,4-Trichlorobenzene
ND
1900
230
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
367-12-4
2-Fluorophenol
38% °
40-102%
4165-62-2
Phenol-d5
46%
41-100%
118-79-6
2,4,6-Tribromophenol
60%
42-108%
4165-60-0
Nitrobenzene-d5
43%
40-105%
321-60-8
2-Fluorobiphenyl
68%
43-107%
1718-51-0
Terphenyl-dl4
52%
45-119%
(a) Dilution required due to matrix interference; extract was viscous.
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 60 of 177
FA75651

SGS North America Inc.
Report of Analysis
Tent Sample ID: SB-06
,ab Sample ID: FA75651-6 Date Sampled: 06/04/20
Ratrix: SO - Soil Date Received: 06/06/20
lthod: SW846 8270E SW846 3550C Percent Solids: 87.8
'roject: 31 Harnett, Wilmington, NC
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(b) Associated ICV outside control limits high, however sample ND.
(c) Outside control limits due to dilution.
Page 3 of 3
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 61 of 177
FA75651

SGS North America Inc.
Report of Analysis
Tent Sample ID: SB-06
,ab Sample ID: FA75651-6 Date Sampled: 06/04/20
Rtrix: SO - Soil Date Received: 06/06/20
lthod: SW846 8081B SW846 3546 Percent Solids: 87.8
'roject: 31 Harnett, Wilmington, NC
Page 1 of 2
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
Run #1 ST147930.1)
1
06/19/20 05:36
WH
06/16/20 08:06
OP80695
GST3550
Run #2 ST147914.1)
10
06/19/20 01:00
WH
06/16/20 08:06
OP80695
GST3550
Initial Weight Final Volume
un#1 15.0g 5.0ml
.un #2 15.0 g 5.0 ml
Pesticide TCL List
CAS No.
Compound
Result
RL
MDL
Units Q
309-00-2
Aldrin a
ND
1.9
0.60
ug/kg
319-84-6
alpha-BHC b
ND
1.9
0.60
ug/kg
319-85-7
beta-BHC a
ND
1.9
0.56
ug/kg
319-86-8
delta-BHC a
ND
1.9
0.54
ug/kg
58-89-9
gamma-BHC (Lindane) a
ND
1.9
0.57
ug/kg
5103-71-9
alpha -Chlordane a
ND
1.9
0.59
ug/kg
5103-74-2
gamma -Chlordane a
ND
1.9
0.55
ug/kg
60-57-1
Dieldrin
ND
1.9
0.53
ug/kg
72-54-8
4,4'-DDD e
ND d
38
5.2
ug/kg
72-55-9
4,4'-DDE °
ND d
38
6.9
ug/kg
50-29-3
4,4'-DDT
ND
3.8
0.58
ug/kg
72-20-8
Endrin
ND
3.8
0.96
ug/kg
1031-07-8
Endosulfan sulfate
ND
3.8
0.50
ug/kg
7421-93-4
Endrin aldehyde
ND
3.8
0.44
ug/kg
53494-70-5
Endrin ketone
ND
3.8
0.60
ug/kg
959-98-8
Endosulfan-I a
ND
1.9
0.44
ug/kg
33213-65-9
Endosulfan-II
ND
1.9
0.45
ug/kg
76-44-8
Heptachlor a
ND
1.9
0.56
ug/kg
1024-57-3
Heptachlor epoxide a
ND
1.9
0.56
ug/kg
72-43-5
Methoxychlor
ND
3.8
0.76
ug/kg
8001-35-2
Toxaphene
ND
95
28
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
877-09-8 Tetrachloro-m-xylene 153% f 123% e 50-122%
2051-24-3 Decachlorobiphenyl 85% 111% 50-133%
(a) Associated CCV outside of control limits high, sample was ND.
(b) Associated BS and CCV outside of control limits high, sample was ND.
(c) Dilution required due to matrix interference.
(d) Result is from Run# 2
(e) Outside control limits due to dilution.
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 62 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-06
Lab Sample ID: FA75651-6 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8081B SW846 3546 Percent Solids: 87.8
Project: 31 Harnett, Wilmington, NC
Pesticide TCL List
CAS No. Compound Result RL MDL Units Q
(f) Outside control limits due to matrix interference.
Page 2 of 2
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 63 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-06
Lab Sample ID: FA75651-6 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Percent Solids: 87.8
Project: 31 Harnett, Wilmington, NC
Page 1 of 1
Metals Analysis
Analyte Result RL
Units
DF
Prep
Analyzed
By
Method
Prep Method
Arsenic a 5.1 2.0
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
Barium a < 40 40
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050E 4
Cadmium a < 0.81 0.81
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050E 4
Chromium a 14.2 2.0
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
Lead a 52.9 4.0
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050E 4
Mercury 0.16 0.046
mg/kg
1
06/11/20
06/11/20
7c
SW846 7471E 1
SW846 7471B 3
Selenium a < 4.0 4.0
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
Silver a < 2.0 2.0
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 4
(1) Instrument QC Batch: MA16819
(2) Instrument QC Batch: MA16830
(3) Prep QC Batch: MP37368
(4) Prep QC Batch: MP37382
(a) Sample dilution required due to difficult matrix.
RL = Reporting Limit
6 64 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-06
Lab Sample ID: FA75651-6 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Percent Solids: 87.8
Project: 31 Harnett, Wilmington, NC
General Chemistry
Analyte Result
Chromium, Hexavalent a < 0.47
Solids, Percent 87.8
(a) Analysis performed at SGS Dayton, NJ.
RL = Reporting Limit
Page 1 of 1
RL Units
DF
Analyzed
By
Method
0.47 mg/kg
1
06/15/2013:46
ANJ
SW846306OA/7199
%
1
06/ 10/20 13:44
cs
SM19 2540G
6 65 of 177
FA75651

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: SB-07
Lab Sample ID: FA75651-7 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 82.1
Project: 31 Harnett, Wilmington, NC
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
Run #1 a F0095940.D
1
06/09/20 18:14
SP
n/a
n/a
VF3373
Run #2 b F0095965.1)
1
06/10/20 17:19
SP
n/a
n/a
VF3374
Initial Weight Final Volume
Run # 1 7.05 g 5.0 ml
Run #2 7.40 g 5.0 ml
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
67-64-1
Acetone
105
170
86
ug/kg J
71-43-2
Benzene
ND
4.3
1.1
ug/kg
108-86-1
Bromobenzene
ND
4.3
0.86
ug/kg
74-97-5
Bromochloromethane
ND
4.3
1.3
ug/kg
75-27-4
Bromodichloromethane
ND
4.3
0.86
ug/kg
75-25-2
Bromoform
ND
4.3
0.86
ug/kg
78-93-3
2-Butanone (MEK)
8.7
22
6.3
ug/kg J
104-51-8
n-Butylbenzene
ND
4.3
0.86
ug/kg
135-98-8
sec-Butylbenzene
ND
4.3
0.86
ug/kg
98-06-6
tert-Butylbenzene
ND
4.3
0.86
ug/kg
56-23-5
Carbon Tetrachloride
ND
4.3
0.88
ug/kg
108-90-7
Chlorobenzene
ND
4.3
0.86
ug/kg
75-00-3
Chloroethane
ND
4.3
1.7
ug/kg
67-66-3
Chloroform
ND
4.3
1.1
ug/kg
95-49-8
o-Chlorotoluene
ND
4.3
0.86
ug/kg
106-43-4
p-Chlorotoluene
ND
4.3
0.86
ug/kg
124-48-1
Dibromochloromethane
ND
4.3
0.86
ug/kg
106-93-4
1,2-Dibromoethane
ND
4.3
0.86
ug/kg
75-71-8
Dichlorodifluoromethane
ND
4.3
1.7
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
4.3
0.86
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
4.3
0.86
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
4.3
0.99
ug/kg
75-34-3
1, 1 -Dichloroethane
ND
4.3
1.5
ug/kg
107-06-2
1,2-Dichloroethane
ND
4.3
0.86
ug/kg
75-35-4
1, 1 -Dichloroethylene
ND
4.3
0.86
ug/kg
156-59-2
cis-1,2-Dichloroethylene
ND
4.3
1.2
ug/kg
156-60-5
trans- 1, 2-Dichloroethylene
ND
4.3
0.86
ug/kg
78-87-5
1,2-Dichloropropane
ND
4.3
0.86
ug/kg
142-28-9
1,3-Dichloropropane
ND
4.3
0.86
ug/kg
594-20-7
2,2-Dichloropropane
ND
4.3
0.86
ug/kg
563-58-6
1, 1 -Dichloropropene
ND
4.3
0.88
ug/kg
10061-01-5
cis- 1, 3 -Dichloropropene
ND
4.3
0.86
ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 66 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-07
Lab Sample ID: FA75651-7 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 82.1
Project: 31 Harnett, Wilmington, NC
VOA List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
10061-02-6
trans- 1, 3-Dichloropropene
ND
4.3
0.86
ug/kg
108-20-3
Di -Isopropyl Ether
ND
4.3
2.0
ug/kg
64-17-5
Ethyl Alcohol
ND
350
65
ug/kg
100-41-4
Ethylbenzene
ND
4.3
0.86
ug/kg
591-78-6
2-Hexanone
ND
22
6.5
ug/kg
98-82-8
Isopropylbenzene
ND
4.3
0.86
ug/kg
99-87-6
p-Isopropyltoluene
3.6
4.3
0.86
ug/kg J
74-83-9
Methyl Bromide
ND
4.3
1.7
ug/kg
74-87-3
Methyl Chloride
ND
4.3
1.7
ug/kg
75-09-2
Methylene Chloride
ND
17
9.5
ug/kg
108-10-1
4-Methyl-2-pentanone (MIBK) ND
22
6.5
ug/kg
1634-04-4
Methyl Tert Butyl Ether
ND
4.3
0.86
ug/kg
91-20-3
Naphthalene
ND
4.3
1.7
ug/kg
103-65-1
n-Propylbenzene
ND
4.3
0.86
ug/kg
100-42-5
Styrene
ND
4.3
0.86
ug/kg
630-20-6
1, 1, 1,2-Tetrachloroethane
ND
4.3
0.89
ug/kg
79-34-5
1,1,2,2-Tetrachloroethane
ND
4.3
0.86
ug/kg
127-18-4
Tetrachloroethylene
ND
4.3
1.1
ug/kg
108-88-3
Toluene
ND
17
8.6
ug/kg
87-61-6
1,2,3-Trichlorobenzene
ND
4.3
1.2
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
4.3
0.86
ug/kg
71-55-6
1, 1, 1 -Trichloroethane
ND
4.3
0.86
ug/kg
79-00-5
1,1,2-Trichloroethane
ND
4.3
0.86
ug/kg
79-01-6
Trichloroethylene
ND
4.3
0.86
ug/kg
75-69-4
Trichlorofluoromethane
ND
4.3
1.7
ug/kg
96-18-4
1,2,3-Trichloropropane
ND
4.3
1.1
ug/kg
95-63-6
1,2,4-Trimethylbenzene
ND
4.3
0.86
ug/kg
108-67-8
1,3,5-Trimethylbenzene
ND
4.3
0.86
ug/kg
108-05-4
Vinyl Acetate
ND
22
14
ug/kg
75-01-4
Vinyl Chloride
ND
4.3
0.86
ug/kg
m,p-Xylene
ND
8.6
0.95
ug/kg
95-47-6
o-Xylene
ND
4.3
0.86
ug/kg
1330-20-7
Xylene (total)
ND
13
1.8
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
1868-53-7
Dibromofluoromethane
103%
106%
75-124%
17060-07-0
1,2-Dichloroethane-D4
103%
103%
72-135%
2037-26-5
Toluene-D8
112%
110%
75-126%
460-00-4
4-Bromofluorobenzene
130%
133%
71-133%
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 67 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-07
Lab Sample ID: FA75651-7 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 82.1
Project: 31 Harnett, Wilmington, NC
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(a) Internal standard response(s) outside method criteria due to sample matrix interference; confirmed by
reanalysis.
(b) Confirmation run for internal standard areas.
Page 3 of 3 P
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 68 of 177
FA75651

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: SB-07
Lab Sample ID: FA75651-7 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8270E SW846 3550C Percent Solids: 82.1
Project: 31 Harnett, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 a 6F06188.D 10 06/23/20 21:03 MV 06/08/20 06:39 OP80524 S617240
Run #2
Initial Weight Final Volume
Run # 1 29.8 g 1.0 ml
Run #2
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
65-85-0
Benzoic Acid
ND
10000
2000
ug/kg
59-50-7
4-Chloro-3-methyl Phenol
ND
2000
230
ug/kg
95-57-8
2-Chlorophenol
ND
2000
250
ug/kg
120-83-2
2,4-Dichlorophenol
ND
2000
230
ug/kg
105-67-9
2,4-Dimethylphenol
ND
2000
540
ug/kg
51-28-5
2,4-Dinitrophenol
ND
10000
2000
ug/kg
534-52-1
4,6-Dinitro-o-cresol
ND
4100
820
ug/kg
95-48-7
2-Methylphenol
ND
2000
250
ug/kg
3&4-Methylphenol
ND
2000
340
ug/kg
88-75-5
2-Nitrophenol
ND
2000
220
ug/kg
100-02-7
4-Nitrophenol
ND
10000
2000
ug/kg
87-86-5
Pentachlorophenolb
ND
10000
2000
ug/kg
108-95-2
Phenol
ND
2000
200
ug/kg
88-06-2
2,4,6-Trichlorophenol
ND
2000
240
ug/kg
83-32-9
Acenaphthene
ND
2000
220
ug/kg
208-96-8
Acenaphthylene
ND
2000
200
ug/kg
120-12-7
Anthracene
ND
2000
230
ug/kg
56-55-3
Benzo(a)anthracene
303
2000
200
ug/kg J
50-32-8
Benzo(a)pyrene
300
2000
240
ug/kg J
205-99-2
Benzo(b)fluoranthene
401
2000
220
ug/kg J
191-24-2
Benzo(g, h, i)perylene
212
2000
210
ug/kg J
207-08-9
Benzo(k)fluoranthene
ND
2000
270
ug/kg
100-51-6
Benzyl Alcohol
ND
2000
200
ug/kg
101-55-3
4-13romophenyl phenyl ether
ND
2000
210
ug/kg
85-68-7
Butyl benzyl phthalate
ND
2000
410
ug/kg
106-47-8
4-Chloroaniline
ND
2000
520
ug/kg
111-91-1
bis(2-Chloroethoxy)methane
ND
2000
200
ug/kg
111-44-4
bis(2-Chloroethyl)ether
ND
2000
240
ug/kg
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
2000
260
ug/kg
91-58-7
2-Chloronaphthalene
ND
2000
200
ug/kg
7005-72-3
4-Chlorophenyl phenyl ether
ND
2000
200
ug/kg
218-01-9
Chrysene
327
2000
210
ug/kg J
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 69 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-07
Lab Sample ID: FA75651-7 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8270E SW846 3550C Percent Solids: 82.1
Project: 31 Harnett, Wilmington, NC
ABN List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
53-70-3
Dibenzo(a,h)anthracene
ND
2000
260
ug/kg
132-64-9
Dibenzofaran
ND
2000
200
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
2000
200
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
2000
220
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
2000
270
ug/kg
91-94-1
3,3'-Dichlorobenzidine
ND
2000
490
ug/kg
84-66-2
Diethyl Phthalate
ND
4100
410
ug/kg
131-11-3
Dimethyl Phthalate
ND
2000
410
ug/kg
117-84-0
Di-n-octyl Phthalate
ND
2000
410
ug/kg
84-74-2
Di-n-butyl Phthalate
ND
4100
820
ug/kg
122-66-7
1,2-Diphenylhydrazine
ND
2000
200
ug/kg
117-81-7
bis(2-Ethylhexyl)phthalate
ND
4100
410
ug/kg
206-44-0
Fluoranthene
473
2000
200
ug/kg J
86-73-7
Fluorene
ND
2000
220
ug/kg
118-74-1
Hexachlorobenzene
ND
2000
210
ug/kg
87-68-3
Hexachlorobutadiene
ND
2000
210
ug/kg
77-47-4
Hexachlorocyclopentadiene
ND
2000
410
ug/kg
67-72-1
Hexachloroethane
ND
2000
240
ug/kg
193-39-5
Indeno(1,2,3-cd)pyrene
264
2000
250
ug/kg J
78-59-1
Isophorone
ND
2000
200
ug/kg
90-12-0
1-Methylnaphthalene
ND
2000
200
ug/kg
91-57-6
2-Methylnaphthalene
ND
2000
200
ug/kg
91-20-3
Naphthalene
ND
2000
200
ug/kg
98-95-3
Nitrobenzene
ND
2000
200
ug/kg
621-64-7
N-Nitrosodi-n-propylamine
ND
2000
200
ug/kg
86-30-6
N-Nitrosodiphenylamine
ND
2000
220
ug/kg
85-01-8
Phenanthrene
237
2000
200
ug/kg J
129-00-0
Pyrene
413
2000
240
ug/kg J
120-82-1
1,2,4-Trichlorobenzene
ND
2000
240
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
367-12-4
2-Fluorophenol
45%
40-102%
4165-62-2
Phenol-d5
53%
41-100%
118-79-6
2,4,6-Tribromophenol
68%
42-108%
4165-60-0
Nitrobenzene-d5
51%
40-105%
321-60-8
2-Fluorobiphenyl
79%
43-107%
1718-51-0
Terphenyl-dl4
59%
45-119%
(a) Dilution required due to matrix interference; extract was viscous.
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 70 of 177
FA75651

SGS North America Inc.
Report of Analysis
Tent Sample ID: SB-07
,ab Sample ID: FA75651-7 Date Sampled: 06/04/20
Ratrix: SO - Soil Date Received: 06/06/20
lthod: SW846 8270E SW846 3550C Percent Solids: 82.1
'roject: 31 Harnett, Wilmington, NC
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(b) Associated ICV outside control limits high, however sample ND.
Page 3 of 3 P
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 71 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-07
Lab Sample ID: FA75651-7 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8081B SW846 3546 Percent Solids: 82.1
Project: 31 Harnett, Wilmington, NC
Page 1 of 1 P
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 ST147931.1) 1 06/19/20 05:54 WH 06/16/20 08:06 OP80695 GST3550
Run #2
Initial Weight Final Volume
Run#1 14.9g 5.0ml
Run #2
Pesticide TCL List
CAS No.
Compound
Result
RL
MDL
Units Q
309-00-2
Aldrin a
ND
2.0
0.65
ug/kg
319-84-6
alpha-BHC b
ND
2.0
0.65
ug/kg
319-85-7
beta-BHC a
ND
2.0
0.60
ug/kg
319-86-8
delta-BHC a
ND
2.0
0.58
ug/kg
58-89-9
gamma-BHC (Lindane) a
ND
2.0
0.61
ug/kg
5103-71-9
alpha -Chlordane a
ND
2.0
0.64
ug/kg
5103-74-2
gamma -Chlordane a
ND
2.0
0.59
ug/kg
60-57-1
Dieldrin
ND
2.0
0.57
ug/kg
72-54-8
4,4'-DDD
ND
4.1
0.56
ug/kg
72-55-9
4,4'-DDE
ND
4.1
0.74
ug/kg
50-29-3
4,4'-DDT
ND
4.1
0.63
ug/kg
72-20-8
Endrin
ND
4.1
1.0
ug/kg
1031-07-8
Endosulfan sulfate
ND
4.1
0.54
ug/kg
7421-93-4
Endrin aldehyde
ND
4.1
0.47
ug/kg
53494-70-5
Endrin ketone
ND
4.1
0.64
ug/kg
959-98-8
Endosulfan-I a
ND
2.0
0.47
ug/kg
33213-65-9
Endosulfan-II
ND
2.0
0.48
ug/kg
76-44-8
Heptachlor a
ND
2.0
0.60
ug/kg
1024-57-3
Heptachlor epoxide a
ND
2.0
0.60
ug/kg
72-43-5
Methoxychlor
ND
4.1
0.82
ug/kg
8001-35-2
Toxaphene
ND
100
31
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
877-09-8
Tetrachloro-m-xylene
139% °
50-122%
2051-24-3
Decachlorobiphenyl
80%
50-133%
(a) Associated CCV outside of control limits
high, sample
was ND.
(b) Associated BS and CCV outside of control limits high, sample was ND.
(c) Outside control limits. However, Sample was ND.
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 72 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-07
Lab Sample ID: FA75651-7 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Percent Solids: 82.1
Project: 31 Harnett, Wilmington, NC
Page 1 of 1 P
Metals Analysis
Analyte Result RL
Units
DF
Prep
Analyzed
By
Method
Prep Method
Arsenic a 5.6 2.3
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 3
Barium a < 45 45
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050E 3
Cadmium a < 0.91 0.91
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050E 3
Chromium a 17.2 2.3
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 3
Lead a 160 4.5
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 3
Mercury 0.33 0.046
mg/kg
1
06/16/20
06/16/20
7c
SW846 7471E 1
SW846 7471B 4
Selenium a < 4.5 4.5
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 3
Silver a < 2.3 2.3
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 3
(1) Instrument QC Batch: MA16828
(2) Instrument QC Batch: MA16830
(3) Prep QC Batch: MP37382
(4) Prep QC Batch: MP37396
(a) Sample dilution required due to difficult matrix.
RL = Reporting Limit
6 73 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-07
Lab Sample ID: FA75651-7 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Percent Solids: 82.1
Project: 31 Harnett, Wilmington, NC
General Chemistry
Analyte Result
Chromium, Hexavalent a 1.1
Solids, Percent 82.1
(a) Analysis performed at SGS Dayton, NJ.
RL = Reporting Limit
Page 1 of 1 P
RL Units
DF
Analyzed
By
Method
0.50 mg/kg
1
06/15/2013:54
ANJ
SW846306OA/7199
%
1
06/ 10/20 13:44
cs
SM19 2540G
6 74 of 177
FA75651

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: SB-08
Lab Sample ID: FA75651-8 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 91.5
Project: 31 Harnett, Wilmington, NC
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
Run #1 a F0095966.D
1
06/10/20 17:46
SP
n/a
n/a
VF3374
Run #2 b F0095941.1)
1
06/09/20 18:45
SP
n/a
n/a
VF3373
Initial Weight Final Volume
Run #1 5.95 g 5.0 ml
Run #2 5.75 g 5.0 ml
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
67-64-1
Acetone
219
180
92
ug/kg
71-43-2
Benzene
ND
4.6
1.1
ug/kg
108-86-1
Bromobenzene
ND
4.6
0.92
ug/kg
74-97-5
Bromochloromethane
ND
4.6
1.4
ug/kg
75-27-4
Bromodichloromethane
ND
4.6
0.92
ug/kg
75-25-2
Bromoform
ND
4.6
0.92
ug/kg
78-93-3
2-Butanone (MEK)
20.3
23
6.7
ug/kg J
104-51-8
n-Butylbenzene
ND
4.6
0.92
ug/kg
135-98-8
sec-Butylbenzene
ND
4.6
0.92
ug/kg
98-06-6
tert-Butylbenzene
ND
4.6
0.92
ug/kg
56-23-5
Carbon Tetrachloride
ND
4.6
0.94
ug/kg
108-90-7
Chlorobenzene
ND
4.6
0.92
ug/kg
75-00-3
Chloroethane
ND
4.6
1.8
ug/kg
67-66-3
Chloroform
ND
4.6
1.2
ug/kg
95-49-8
o-Chlorotoluene
ND
4.6
0.92
ug/kg
106-43-4
p-Chlorotoluene
ND
4.6
0.92
ug/kg
124-48-1
Dibromochloromethane
ND
4.6
0.92
ug/kg
106-93-4
1,2-Dibromoethane
ND
4.6
0.92
ug/kg
75-71-8
Dichlorodifluoromethane
ND
4.6
1.8
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
4.6
0.92
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
4.6
0.92
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
4.6
1.1
ug/kg
75-34-3
1, 1 -Dichloroethane
ND
4.6
1.6
ug/kg
107-06-2
1,2-Dichloroethane
ND
4.6
0.92
ug/kg
75-35-4
1, 1 -Dichloroethylene
ND
4.6
0.92
ug/kg
156-59-2
cis-1,2-Dichloroethylene
ND
4.6
1.3
ug/kg
156-60-5
trans- 1, 2-Dichloroethylene
ND
4.6
0.92
ug/kg
78-87-5
1,2-Dichloropropane
ND
4.6
0.92
ug/kg
142-28-9
1,3-Dichloropropane
ND
4.6
0.92
ug/kg
594-20-7
2,2-Dichloropropane
ND
4.6
0.92
ug/kg
563-58-6
1, 1 -Dichloropropene
ND
4.6
0.94
ug/kg
10061-01-5
cis- 1, 3 -Dichloropropene
ND
4.6
0.92
ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
w
00
6 75 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-08
Lab Sample ID: FA75651-8 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 91.5
Project: 31 Harnett, Wilmington, NC
VOA List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
10061-02-6
trans- 1, 3-Dichloropropene
ND
4.6
0.92
ug/kg
108-20-3
Di -Isopropyl Ether
ND
4.6
2.1
ug/kg
64-17-5
Ethyl Alcohol
ND
370
69
ug/kg
100-41-4
Ethylbenzene
ND
4.6
0.92
ug/kg
591-78-6
2-Hexanone
ND
23
6.9
ug/kg
98-82-8
Isopropylbenzene
ND
4.6
0.92
ug/kg
99-87-6
p-Isopropyltoluene
16.4
4.6
0.92
ug/kg
74-83-9
Methyl Bromide
ND
4.6
1.8
ug/kg
74-87-3
Methyl Chloride
ND
4.6
1.8
ug/kg
75-09-2
Methylene Chloride
ND
18
10
ug/kg
108-10-1
4-Methyl-2-pentanone (MIBK) ND
23
6.9
ug/kg
1634-04-4
Methyl Tert Butyl Ether
ND
4.6
0.92
ug/kg
91-20-3
Naphthalene
ND
4.6
1.8
ug/kg
103-65-1
n-Propylbenzene
ND
4.6
0.92
ug/kg
100-42-5
Styrene
ND
4.6
0.92
ug/kg
630-20-6
1, 1, 1,2-Tetrachloroethane
ND
4.6
0.95
ug/kg
79-34-5
1,1,2,2-Tetrachloroethane
ND
4.6
0.92
ug/kg
127-18-4
Tetrachloroethylene
ND
4.6
1.2
ug/kg
108-88-3
Toluene
ND
18
9.2
ug/kg
87-61-6
1,2,3-Trichlorobenzene
ND
4.6
1.3
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
4.6
0.92
ug/kg
71-55-6
1, 1, 1 -Trichloroethane
ND
4.6
0.92
ug/kg
79-00-5
1,1,2-Trichloroethane
ND
4.6
0.92
ug/kg
79-01-6
Trichloroethylene
ND
4.6
0.92
ug/kg
75-69-4
Trichlorofluoromethane
ND
4.6
1.8
ug/kg
96-18-4
1,2,3-Trichloropropane
ND
4.6
1.1
ug/kg
95-63-6
1,2,4-Trimethylbenzene
ND
4.6
0.92
ug/kg
108-67-8
1,3,5-Trimethylbenzene
ND
4.6
0.92
ug/kg
108-05-4
Vinyl Acetate
ND
23
15
ug/kg
75-01-4
Vinyl Chloride
ND
4.6
0.92
ug/kg
m,p-Xylene
ND
9.2
1.0
ug/kg
95-47-6
o-Xylene
ND
4.6
0.92
ug/kg
1330-20-7
Xylene (total)
ND
14
1.9
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
1868-53-7
Dibromofluoromethane
106%
102%
75-124%
17060-07-0
1,2-Dichloroethane-D4
103%
103%
72-135%
2037-26-5
Toluene-D8
108%
115%
75-126%
460-00-4
4-Bromofluorobenzene
133%
144% c
71-133%
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
w
00
6 76 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-08
Lab Sample ID: FA75651-8 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 91.5
Project: 31 Harnett, Wilmington, NC
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(a) Internal standard response(s) outside method criteria due to sample matrix interference; confirmed by
reanalysis.
(b) Confirmation run for surrogate recoveries.
(c) Outside control limits due to matrix interference.
Page 3 of 3 w
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 77 of 177
FA75651

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: SB-08
Lab Sample ID: FA75651-8 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8270E SW846 3550C Percent Solids: 91.5
Project: 31 Harnett, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 a 6F06189.D 10 06/23/20 21:28 MV 06/08/20 06:39 OP80524 S617240
Run #2
Initial Weight Final Volume
Run #1 30.5 g 1.0 ml
Run #2
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
65-85-0
Benzoic Acid
ND
9000
1800
ug/kg
59-50-7
4-Chloro-3-methyl Phenol
ND
1800
200
ug/kg
95-57-8
2-Chlorophenol
ND
1800
220
ug/kg
120-83-2
2,4-Dichlorophenol
ND
1800
210
ug/kg
105-67-9
2,4-Dimethylphenol
ND
1800
480
ug/kg
51-28-5
2,4-Dinitrophenol
ND
9000
1800
ug/kg
534-52-1
4,6-Dinitro-o-cresol
ND
3600
720
ug/kg
95-48-7
2-Methylphenol
ND
1800
220
ug/kg
3&4-Methylphenol
ND
1800
290
ug/kg
88-75-5
2-Nitrophenol
ND
1800
190
ug/kg
100-02-7
4-Nitrophenol
ND
9000
1800
ug/kg
87-86-5
Pentachlorophenolb
ND
9000
1800
ug/kg
108-95-2
Phenol
ND
1800
180
ug/kg
88-06-2
2,4,6-Trichlorophenol
ND
1800
210
ug/kg
83-32-9
Acenaphthene
ND
1800
190
ug/kg
208-96-8
Acenaphthylene
ND
1800
180
ug/kg
120-12-7
Anthracene
ND
1800
200
ug/kg
56-55-3
Benzo(a)anthracene
232
1800
180
ug/kg J
50-32-8
Benzo(a)pyrene
266
1800
210
ug/kg J
205-99-2
Benzo(b)fluoranthene
394
1800
200
ug/kg J
191-24-2
Benzo(g, h, i)perylene
199
1800
190
ug/kg J
207-08-9
Benzo(k)fluoranthene
ND
1800
240
ug/kg
100-51-6
Benzyl Alcohol
ND
1800
180
ug/kg
101-55-3
4-13romophenyl phenyl ether
ND
1800
190
ug/kg
85-68-7
Butyl benzyl phthalate
ND
1800
360
ug/kg
106-47-8
4-Chloroaniline
ND
1800
450
ug/kg
111-91-1
bis(2-Chloroethoxy)methane
ND
1800
180
ug/kg
111-44-4
bis(2-Chloroethyl)ether
ND
1800
210
ug/kg
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
1800
230
ug/kg
91-58-7
2-Chloronaphthalene
ND
1800
180
ug/kg
7005-72-3
4-Chlorophenyl phenyl ether
ND
1800
180
ug/kg
218-01-9
Chrysene
322
1800
180
ug/kg J
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
w
i"
6 78 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-08
Lab Sample ID: FA75651-8 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8270E SW846 3550C Percent Solids: 91.5
Project: 31 Harnett, Wilmington, NC
ABN List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
53-70-3
Dibenzo(a,h)anthracene
ND
1800
220
ug/kg
132-64-9
Dibenzofaran
ND
1800
180
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
1800
180
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
1800
190
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
1800
240
ug/kg
91-94-1
3,3'-Dichlorobenzidine
ND
1800
430
ug/kg
84-66-2
Diethyl Phthalate
ND
3600
360
ug/kg
131-11-3
Dimethyl Phthalate
ND
1800
360
ug/kg
117-84-0
Di-n-octyl Phthalate
ND
1800
360
ug/kg
84-74-2
Di-n-butyl Phthalate
ND
3600
720
ug/kg
122-66-7
1,2-Diphenylhydrazine
ND
1800
180
ug/kg
117-81-7
bis(2-Ethylhexyl)phthalate
ND
3600
360
ug/kg
206-44-0
Fluoranthene
649
1800
180
ug/kg J
86-73-7
Fluorene
ND
1800
190
ug/kg
118-74-1
Hexachlorobenzene
ND
1800
180
ug/kg
87-68-3
Hexachlorobutadiene
ND
1800
180
ug/kg
77-47-4
Hexachlorocyclopentadiene
ND
1800
360
ug/kg
67-72-1
Hexachloroethane
ND
1800
210
ug/kg
193-39-5
Indeno(1,2,3-cd)pyrene
237
1800
220
ug/kg J
78-59-1
Isophorone
ND
1800
180
ug/kg
90-12-0
1-Methylnaphthalene
ND
1800
180
ug/kg
91-57-6
2-Methylnaphthalene
ND
1800
180
ug/kg
91-20-3
Naphthalene
ND
1800
180
ug/kg
98-95-3
Nitrobenzene
ND
1800
180
ug/kg
621-64-7
N-Nitrosodi-n-propylamine
ND
1800
180
ug/kg
86-30-6
N-Nitrosodiphenylamine
ND
1800
190
ug/kg
85-01-8
Phenanthrene
353
1800
180
ug/kg J
129-00-0
Pyrene
517
1800
210
ug/kg J
120-82-1
1,2,4-Trichlorobenzene
ND
1800
210
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
367-12-4
2-Fluorophenol
35% °
40-102%
4165-62-2
Phenol-d5
49%
41-100%
118-79-6
2,4,6-Tribromophenol
65%
42-108%
4165-60-0
Nitrobenzene-d5
43%
40-105%
321-60-8
2-Fluorobiphenyl
73%
43-107%
1718-51-0
Terphenyl-dl4
48%
45-119%
(a) Dilution required due to matrix interference; extract was viscous.
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
w
ib
6 79 of 177
FA75651

SGS North America Inc.
Report of Analysis
Tent Sample ID: SB-08
,ab Sample ID: FA75651-8 Date Sampled: 06/04/20
Ratrix: SO - Soil Date Received: 06/06/20
lthod: SW846 8270E SW846 3550C Percent Solids: 91.5
'roject: 31 Harnett, Wilmington, NC
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(b) Associated ICV outside control limits high, however sample ND.
(c) Outside control limits due to dilution.
Page 3 of 3 w
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 80 of 177
FA75651

SGS North America Inc.
Report of Analysis
Tent Sample ID: SB-08
,ab Sample ID: FA75651-8 Date Sampled: 06/04/20
Rtrix: SO - Soil Date Received: 06/06/20
lthod: SW846 8081B SW846 3546 Percent Solids: 91.5
'roject: 31 Harnett, Wilmington, NC
Page 1 of 1 w
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
Run #1 ST147932.1)
1
06/19/20 06:10
WH
06/16/20 08:06
OP80695
GST3550
Run #2 ST147916.1)
10
06/19/20 01:35
WH
06/16/20 08:06
OP80695
GST3550
Initial Weight Final Volume
un#1 15.1 g 5.0ml
.un #2 15.1 g 5.0 ml
Pesticide TCL List
CAS No.
Compound
Result
RL
MDL
Units Q
309-00-2
Aldrin a
ND
1.8
0.57
ug/kg
319-84-6
alpha-BHC b
ND
1.8
0.57
ug/kg
319-85-7
beta-BHC a
ND
1.8
0.53
ug/kg
319-86-8
delta-BHC a
ND
1.8
0.51
ug/kg
58-89-9
gamma-BHC (Lindane) a
ND
1.8
0.54
ug/kg
5103-71-9
alpha -Chlordane a
ND
1.8
0.56
ug/kg
5103-74-2
gamma -Chlordane a
ND
1.8
0.52
ug/kg
60-57-1
Dieldrin
ND
1.8
0.51
ug/kg
72-54-8
4,4'-DDD °
ND d
36
5.0
ug/kg
72-55-9
4,4'-DDE °
ND d
36
6.6
ug/kg
50-29-3
4,4'-DDT
ND
3.6
0.55
ug/kg
72-20-8
Endrin
ND
3.6
0.92
ug/kg
1031-07-8
Endosulfan sulfate
ND
3.6
0.48
ug/kg
7421-93-4
Endrin aldehyde
ND
3.6
0.42
ug/kg
53494-70-5
Endrin ketone
ND
3.6
0.57
ug/kg
959-98-8
Endosulfan-I a
ND
1.8
0.42
ug/kg
33213-65-9
Endosulfan-II
ND
1.8
0.43
ug/kg
76-44-8
Heptachlor a
ND
1.8
0.54
ug/kg
1024-57-3
Heptachlor epoxide a
ND
1.8
0.53
ug/kg
72-43-5
Methoxychlor
ND
3.6
0.72
ug/kg
8001-35-2
Toxaphene
ND
90
27
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
877-09-8 Tetrachloro-m-xylene 157% e 99% 50-122%
2051-24-3 Decachlorobiphenyl 93% 95% 50-133%
(a) Associated CCV outside of control limits high, sample was ND.
(b) Associated BS and CCV outside of control limits high, sample was ND.
(c) Dilution required due to matrix interference.
(d) Result is from Run# 2
(e) Outside control limits due to matrix interference.
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 81 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-08
Lab Sample ID: FA75651-8 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Percent Solids: 91.5
Project: 31 Harnett, Wilmington, NC
Page 1 of 1 w
Metals Analysis
Analyte Result RL
Units
DF
Prep
Analyzed
By
Method
Prep Method
Arsenic a 6.3 2.5
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 3
Barium a 60.7 50
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 3
Cadmium a < 1.0 1.0
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050E 3
Chromium a 14.6 2.5
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 3
Lead a 126 5.0
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 3
Mercury 0.25 0.041
mg/kg
1
06/16/20
06/16/20
7c
SW846 7471E 1
SW846 7471B 4
Selenium a < 5.0 5.0
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 3
Silver a < 2.5 2.5
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 3
(1) Instrument QC Batch: MA16828
(2) Instrument QC Batch: MA16830
(3) Prep QC Batch: MP37382
(4) Prep QC Batch: MP37396
(a) Sample dilution required due to difficult matrix.
RL = Reporting Limit
6 82 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-08
Lab Sample ID: FA75651-8 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Percent Solids: 91.5
Project: 31 Harnett, Wilmington, NC
General Chemistry
Analyte Result
Chromium, Hexavalent a 0.44
Solids, Percent 91.5
(a) Analysis performed at SGS Dayton, NJ.
RL = Reporting Limit
Page 1 of 1 w
RL Units
DF
Analyzed
By
Method
0.44 mg/kg
1
06/15/2014:18
ANJ
SW846306OA/7199
%
1
06/ 10/20 13:44
cs
SM19 2540G
6 83 of 177
FA75651

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: SB-09
Lab Sample ID: FA75651-9 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 76.5
Project: 31 Harnett, Wilmington, NC
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
Run #1 a F0095967.D
1
06/10/20 18:12
SP
n/a
n/a
VF3374
Run #2 b F0095942.1)
1
06/09/20 19:13
SP
n/a
n/a
VF3373
Initial Weight Final Volume
Run # 1 8.15 g 5.0 ml
Run #2 8.26 g 5.0 ml
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
67-64-1
Acetone
90.8
160
80
ug/kg J
71-43-2
Benzene
ND
4.0
0.98
ug/kg
108-86-1
Bromobenzene
ND
4.0
0.80
ug/kg
74-97-5
Bromochloromethane
ND
4.0
1.2
ug/kg
75-27-4
Bromodichloromethane
ND
4.0
0.80
ug/kg
75-25-2
Bromoform
ND
4.0
0.80
ug/kg
78-93-3
2-Butanone (MEK)
ND
20
5.8
ug/kg
104-51-8
n-Butylbenzene
ND
4.0
0.80
ug/kg
135-98-8
sec-Butylbenzene
ND
4.0
0.80
ug/kg
98-06-6
tert-Butylbenzene
ND
4.0
0.80
ug/kg
56-23-5
Carbon Tetrachloride
ND
4.0
0.82
ug/kg
108-90-7
Chlorobenzene
ND
4.0
0.80
ug/kg
75-00-3
Chloroethane
ND
4.0
1.6
ug/kg
67-66-3
Chloroform
ND
4.0
1.1
ug/kg
95-49-8
o-Chlorotoluene
ND
4.0
0.80
ug/kg
106-43-4
p-Chlorotoluene
ND
4.0
0.80
ug/kg
124-48-1
Dibromochloromethane
ND
4.0
0.80
ug/kg
106-93-4
1,2-Dibromoethane
ND
4.0
0.80
ug/kg
75-71-8
Dichlorodifluoromethane
ND
4.0
1.6
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
4.0
0.80
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
4.0
0.80
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
4.0
0.92
ug/kg
75-34-3
1, 1 -Dichloroethane
ND
4.0
1.4
ug/kg
107-06-2
1,2-Dichloroethane
ND
4.0
0.80
ug/kg
75-35-4
1, 1 -Dichloroethylene
ND
4.0
0.80
ug/kg
156-59-2
cis-1,2-Dichloroethylene
ND
4.0
1.1
ug/kg
156-60-5
trans- 1, 2-Dichloroethylene
ND
4.0
0.80
ug/kg
78-87-5
1,2-Dichloropropane
ND
4.0
0.80
ug/kg
142-28-9
1,3-Dichloropropane
ND
4.0
0.80
ug/kg
594-20-7
2,2-Dichloropropane
ND
4.0
0.80
ug/kg
563-58-6
1, 1 -Dichloropropene
ND
4.0
0.82
ug/kg
10061-01-5
cis- 1, 3 -Dichloropropene
ND
4.0
0.80
ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 84 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-09
Lab Sample ID: FA75651-9 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 76.5
Project: 31 Harnett, Wilmington, NC
VOA List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
10061-02-6
trans- 1, 3-Dichloropropene
ND
4.0
0.80
ug/kg
108-20-3
Di -Isopropyl Ether
ND
4.0
1.9
ug/kg
64-17-5
Ethyl Alcohol
ND
320
60
ug/kg
100-41-4
Ethylbenzene
ND
4.0
0.80
ug/kg
591-78-6
2-Hexanone
ND
20
6.0
ug/kg
98-82-8
Isopropylbenzene
ND
4.0
0.80
ug/kg
99-87-6
p-Isopropyltoluene
17.7
4.0
0.80
ug/kg
74-83-9
Methyl Bromide
ND
4.0
1.6
ug/kg
74-87-3
Methyl Chloride
ND
4.0
1.6
ug/kg
75-09-2
Methylene Chloride
ND
16
8.8
ug/kg
108-10-1
4-Methyl-2-pentanone (MIBK) ND
20
6.0
ug/kg
1634-04-4
Methyl Tert Butyl Ether
ND
4.0
0.80
ug/kg
91-20-3
Naphthalene
ND
4.0
1.6
ug/kg
103-65-1
n-Propylbenzene
ND
4.0
0.80
ug/kg
100-42-5
Styrene
ND
4.0
0.80
ug/kg
630-20-6
1, 1, 1,2-Tetrachloroethane
ND
4.0
0.83
ug/kg
79-34-5
1,1,2,2-Tetrachloroethane
ND
4.0
0.80
ug/kg
127-18-4
Tetrachloroethylene
ND
4.0
1.0
ug/kg
108-88-3
Toluene
ND
16
8.0
ug/kg
87-61-6
1,2,3-Trichlorobenzene
ND
4.0
1.1
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
4.0
0.80
ug/kg
71-55-6
1, 1, 1 -Trichloroethane
ND
4.0
0.80
ug/kg
79-00-5
1,1,2-Trichloroethane
ND
4.0
0.80
ug/kg
79-01-6
Trichloroethylene
ND
4.0
0.80
ug/kg
75-69-4
Trichlorofluoromethane
ND
4.0
1.6
ug/kg
96-18-4
1,2,3-Trichloropropane
ND
4.0
1.0
ug/kg
95-63-6
1,2,4-Trimethylbenzene
ND
4.0
0.80
ug/kg
108-67-8
1,3,5-Trimethylbenzene
ND
4.0
0.80
ug/kg
108-05-4
Vinyl Acetate
ND
20
13
ug/kg
75-01-4
Vinyl Chloride
ND
4.0
0.80
ug/kg
m,p-Xylene
ND
8.0
0.88
ug/kg
95-47-6
o-Xylene
ND
4.0
0.80
ug/kg
1330-20-7
Xylene (total)
ND
12
1.7
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
1868-53-7
Dibromofluoromethane
108%
107%
75-124%
17060-07-0
1,2-Dichloroethane-D4
109%
106%
72-135%
2037-26-5
Toluene-D8
104%
112%
75-126%
460-00-4
4-Bromofluorobenzene
119%
134% c
71-133%
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 85 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-09
Lab Sample ID: FA75651-9 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 76.5
Project: 31 Harnett, Wilmington, NC
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(a) Internal standard response(s) outside method criteria due to sample matrix interference; confirmed by
reanalysis.
(b) Confirmation run for surrogate recoveries.
(c) Outside control limits due to matrix interference.
to
Page 3 of 3 P
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 86 of 177
FA75651

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: SB-09
Lab Sample ID: FA75651-9 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8270E SW846 3550C Percent Solids: 76.5
Project: 31 Harnett, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 a 9I009018.1) 5 06/13/20 01:59 MV 06/08/20 06:39 OP80524 S91334
Run #2
Initial Weight Final Volume
Run #1 30.1 g 1.0 ml
Run #2
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
65-85-0
Benzoic Acid
ND
5400
1100
ug/kg
59-50-7
4-Chloro-3-methyl Phenol
ND
1100
120
ug/kg
95-57-8
2-Chlorophenol
ND
1100
130
ug/kg
120-83-2
2,4-Dichlorophenol
ND
1100
120
ug/kg
105-67-9
2,4-Dimethylphenol
ND
1100
290
ug/kg
51-28-5
2,4-Dinitrophenol
ND
5400
1100
ug/kg
534-52-1
4,6-Dinitro-o-cresol
ND
2200
430
ug/kg
95-48-7
2-Methylphenol
ND
1100
130
ug/kg
3&4-Methylphenol
ND
1100
180
ug/kg
88-75-5
2-Nitrophenol
ND
1100
120
ug/kg
100-02-7
4-Nitrophenol
ND
5400
1100
ug/kg
87-86-5
Pentachlorophenol
ND
5400
1100
ug/kg
108-95-2
Phenol
ND
1100
110
ug/kg
88-06-2
2,4,6-Trichlorophenol
ND
1100
130
ug/kg
83-32-9
Acenaphthene
ND
1100
120
ug/kg
208-96-8
Acenaphthylene
ND
1100
110
ug/kg
120-12-7
Anthracene
144
1100
120
ug/kg J
56-55-3
Benzo(a)anthracene
462
1100
110
ug/kg J
50-32-8
Benzo(a)pyrene
602
1100
130
ug/kg J
205-99-2
Benzo(b)fluoranthene
935
1100
120
ug/kg J
191-24-2
Benzo(g, h, i)perylene
530
1100
110
ug/kg J
207-08-9
Benzo(k)fluoranthene
282
1100
140
ug/kg J
100-51-6
Benzyl Alcohol
ND
1100
110
ug/kg
101-55-3
4-13romophenyl phenyl ether
ND
1100
110
ug/kg
85-68-7
Butyl benzyl phthalate
ND
1100
220
ug/kg
106-47-8
4-Chloroaniline
ND
1100
270
ug/kg
111-91-1
bis(2-Chloroethoxy)methane
ND
1100
110
ug/kg
111-44-4
bis(2-Chloroethyl)ether
ND
1100
130
ug/kg
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
1100
140
ug/kg
91-58-7
2-Chloronaphthalene
ND
1100
110
ug/kg
7005-72-3
4-Chlorophenyl phenyl ether
ND
1100
110
ug/kg
218-01-9
Chrysene
591
1100
110
ug/kg J
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 87 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-09
Lab Sample ID: FA75651-9 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8270E SW846 3550C Percent Solids: 76.5
Project: 31 Harnett, Wilmington, NC
ABN List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
53-70-3
Dibenzo(a,h)anthracene
ND
1100
140
ug/kg
132-64-9
Dibenzofaran
ND
1100
110
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
1100
110
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
1100
120
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
1100
140
ug/kg
91-94-1
3,3'-Dichlorobenzidine
ND
1100
260
ug/kg
84-66-2
Diethyl Phthalate
ND
2200
220
ug/kg
131-11-3
Dimethyl Phthalate
ND
1100
220
ug/kg
117-84-0
Di-n-octyl Phthalate
ND
1100
220
ug/kg
84-74-2
Di-n-butyl Phthalate
ND
2200
430
ug/kg
122-66-7
1,2-Diphenylhydrazine
ND
1100
110
ug/kg
117-81-7
bis(2-Ethylhexyl)phthalate
ND
2200
220
ug/kg
206-44-0
Fluoranthene
697
1100
110
ug/kg J
86-73-7
Fluorene
ND
1100
120
ug/kg
118-74-1
Hexachlorobenzene
ND
1100
110
ug/kg
87-68-3
Hexachlorobutadiene
ND
1100
110
ug/kg
77-47-4
Hexachlorocyclopentadiene
ND
1100
220
ug/kg
67-72-1
Hexachloroethane
ND
1100
130
ug/kg
193-39-5
Indeno(1,2,3-cd)pyrene
713
1100
130
ug/kg J
78-59-1
Isophorone
ND
1100
110
ug/kg
90-12-0
1-Methylnaphthalene
ND
1100
110
ug/kg
91-57-6
2-Methylnaphthalene
ND
1100
110
ug/kg
91-20-3
Naphthalene
ND
1100
110
ug/kg
98-95-3
Nitrobenzene
ND
1100
110
ug/kg
621-64-7
N-Nitrosodi-n-propylamine
ND
1100
110
ug/kg
86-30-6
N-Nitrosodiphenylamine
ND
1100
120
ug/kg
85-01-8
Phenanthrene
325
1100
110
ug/kg J
129-00-0
Pyrene
739
1100
130
ug/kg J
120-82-1
1,2,4-Trichlorobenzene
ND
1100
130
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
367-12-4
2-Fluorophenol
91%
40-102%
4165-62-2
Phenol-d5
103% b
41-100%
118-79-6
2,4,6-Tribromophenol
109% b
42-108%
4165-60-0
Nitrobenzene-d5
89%
40-105%
321-60-8
2-Fluorobiphenyl
88%
43-107%
1718-51-0
Terphenyl-dl4
113%
45-119%
(a) Dilution required due to matrix interference; extract was viscous.
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 88 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-09
Lab Sample ID: FA75651-9 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8270E SW846 3550C Percent Solids: 76.5
Project: 31 Harnett, Wilmington, NC
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(b) Outside control limits.
to
Page 3 of 3 P
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 89 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-09
Lab Sample ID: FA75651-9 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8081B SW846 3546 Percent Solids: 76.5
Project: 31 Harnett, Wilmington, NC
to
Page 1 of 1 P
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 ST147933.1) 1 06/19/20 06:28 WH 06/16/20 08:06 OP80695 GST3550
Run #2
Initial Weight Final Volume
Run # 1 15.1 g 5.0 ml
Run #2
Pesticide TCL List
CAS No.
Compound
Result
RL
MDL
Units Q
309-00-2
Aldrin a
ND
2.2
0.68
ug/kg
319-84-6
alpha-BHC b
ND
2.2
0.68
ug/kg
319-85-7
beta-BHC a
ND
2.2
0.64
ug/kg
319-86-8
delta-BHC a
ND
2.2
0.61
ug/kg
58-89-9
gamma-BHC (Lindane) a
ND
2.2
0.65
ug/kg
5103-71-9
alpha -Chlordane a
ND
2.2
0.68
ug/kg
5103-74-2
gamma -Chlordane a
ND
2.2
0.62
ug/kg
60-57-1
Dieldrin
ND
2.2
0.61
ug/kg
72-54-8
4,4'-DDD
ND
4.3
0.60
ug/kg
72-55-9
4,4'-DDE
ND
4.3
0.79
ug/kg
50-29-3
4,4'-DDT
ND
4.3
0.66
ug/kg
72-20-8
Endrin
ND
4.3
1.1
ug/kg
1031-07-8
Endosulfan sulfate
ND
4.3
0.57
ug/kg
7421-93-4
Endrin aldehyde
ND
4.3
0.50
ug/kg
53494-70-5
Endrin ketone
ND
4.3
0.68
ug/kg
959-98-8
Endosulfan-I a
ND
2.2
0.50
ug/kg
33213-65-9
Endosulfan-II
ND
2.2
0.51
ug/kg
76-44-8
Heptachlor a
ND
2.2
0.64
ug/kg
1024-57-3
Heptachlor epoxide a
ND
2.2
0.64
ug/kg
72-43-5
Methoxychlor
ND
4.3
0.87
ug/kg
8001-35-2
Toxaphene
ND
110
32
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
877-09-8
Tetrachloro-m-xylene
148% °
50-122%
2051-24-3
Decachlorobiphenyl
84%
50-133%
(a) Associated CCV outside of control limits
high, sample
was ND.
(b) Associated BS and CCV outside of control limits high, sample was ND.
(c) Outside control limits. However, Sample was ND.
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 90 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-09
Lab Sample ID: FA75651-9 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Percent Solids: 76.5
Project: 31 Harnett, Wilmington, NC
to
Page 1 of 1 P
Metals Analysis
Analyte Result RL
Units
DF
Prep
Analyzed
By
Method
Prep Method
Arsenic a 4.8 2.7
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 3
Barium a < 53 53
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050E 3
Cadmium a < 1.1 1.1
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050E 3
Chromium a 15.0 2.7
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 3
Lead a 29.7 5.3
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 3
Mercury 0.086 0.052
mg/kg
1
06/16/20
06/16/20
JC
SW846 7471B 1
SW846 7471B 4
Selenium a < 5.3 5.3
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 3
Silver a < 2.7 2.7
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 3
(1) Instrument QC Batch: MA16828
(2) Instrument QC Batch: MA16830
(3) Prep QC Batch: MP37382
(4) Prep QC Batch: MP37396
(a) Sample dilution required due to difficult matrix.
RL = Reporting Limit
6 91 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-09
Lab Sample ID: FA75651-9 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Percent Solids: 76.5
Project: 31 Harnett, Wilmington, NC
General Chemistry
Analyte Result
Chromium, Hexavalent a 1.1
Solids, Percent 76.5
(a) Analysis performed at SGS Dayton, NJ.
RL = Reporting Limit
to
Page 1 of 1 P
RL Units
DF
Analyzed
By
Method
0.51 mg/kg
1
06/15/2014:26
ANJ
SW846306OA/7199
%
1
06/ 10/20 13:44
cs
SM19 2540G
6 92 of 177
FA75651

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: SB-10
Lab Sample ID: FA75651-10 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 89.2
Project: 31 Harnett, Wilmington, NC
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
Run #1 a F0095943.D
1
06/09/20 19:41
SP
n/a
n/a
VF3373
Run #2 b F0095968.1)
1
06/10/20 18:40
SP
n/a
n/a
VF3374
Initial Weight Final Volume
Run #1 7.86 g 5.0 ml
Run #2 7.86 g 5.0 ml
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units
67-64-1
Acetone
225
140
71
ug/kg
71-43-2
Benzene
ND
3.6
0.87
ug/kg
108-86-1
Bromobenzene
ND
3.6
0.71
ug/kg
74-97-5
Bromochloromethane
ND
3.6
1.1
ug/kg
75-27-4
Bromodichloromethane
ND
3.6
0.71
ug/kg
75-25-2
Bromoform
ND
3.6
0.71
ug/kg
78-93-3
2-Butanone (MEK)
24.1
18
5.2
ug/kg
104-51-8
n-Butylbenzene
ND
3.6
0.71
ug/kg
135-98-8
sec-Butylbenzene
ND
3.6
0.71
ug/kg
98-06-6
tert-Butylbenzene
ND
3.6
0.71
ug/kg
56-23-5
Carbon Tetrachloride
ND
3.6
0.73
ug/kg
108-90-7
Chlorobenzene
ND
3.6
0.71
ug/kg
75-00-3
Chloroethane
ND
3.6
1.4
ug/kg
67-66-3
Chloroform
ND
3.6
0.95
ug/kg
95-49-8
o-Chlorotoluene
ND
3.6
0.71
ug/kg
106-43-4
p-Chlorotoluene
ND
3.6
0.71
ug/kg
124-48-1
Dibromochloromethane
ND
3.6
0.71
ug/kg
106-93-4
1,2-Dibromoethane
ND
3.6
0.71
ug/kg
75-71-8
Dichlorodifluoromethane
ND
3.6
1.4
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
3.6
0.71
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
3.6
0.71
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
3.6
0.82
ug/kg
75-34-3
1, 1 -Dichloroethane
ND
3.6
1.3
ug/kg
107-06-2
1,2-Dichloroethane
ND
3.6
0.71
ug/kg
75-35-4
1, 1 -Dichloroethylene
ND
3.6
0.71
ug/kg
156-59-2
cis-1,2-Dichloroethylene
ND
3.6
0.98
ug/kg
156-60-5
trans- 1, 2-Dichloroethylene
ND
3.6
0.71
ug/kg
78-87-5
1,2-Dichloropropane
ND
3.6
0.71
ug/kg
142-28-9
1,3-Dichloropropane
ND
3.6
0.71
ug/kg
594-20-7
2,2-Dichloropropane
ND
3.6
0.71
ug/kg
563-58-6
1, 1 -Dichloropropene
ND
3.6
0.73
ug/kg
10061-01-5
cis- 1, 3 -Dichloropropene
ND
3.6
0.71
ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 93 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-10
Lab Sample ID: FA75651-10 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 89.2
Project: 31 Harnett, Wilmington, NC
VOA List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
10061-02-6
trans- 1, 3-Dichloropropene
ND
3.6
0.71
ug/kg
108-20-3
Di -Isopropyl Ether
ND
3.6
1.7
ug/kg
64-17-5
Ethyl Alcohol
ND
290
53
ug/kg
100-41-4
Ethylbenzene
ND
3.6
0.71
ug/kg
591-78-6
2-Hexanone
ND
18
5.3
ug/kg
98-82-8
Isopropylbenzene
3.5
3.6
0.71
ug/kg J
99-87-6
p-Isopropyltoluene
24.9
3.6
0.71
ug/kg
74-83-9
Methyl Bromide
ND
3.6
1.4
ug/kg
74-87-3
Methyl Chloride
ND
3.6
1.4
ug/kg
75-09-2
Methylene Chloride
ND
14
7.8
ug/kg
108-10-1
4-Methyl-2-pentanone (MIBK) ND
18
5.3
ug/kg
1634-04-4
Methyl Tert Butyl Ether
ND
3.6
0.71
ug/kg
91-20-3
Naphthalene
12.2
3.6
1.4
ug/kg
103-65-1
n-Propylbenzene
ND
3.6
0.71
ug/kg
100-42-5
Styrene
ND
3.6
0.71
ug/kg
630-20-6
1, 1, 1,2-Tetrachloroethane
ND
3.6
0.73
ug/kg
79-34-5
1,1,2,2-Tetrachloroethane
ND
3.6
0.71
ug/kg
127-18-4
Tetrachloroethylene
ND
3.6
0.91
ug/kg
108-88-3
Toluene
8.2
14
7.1
ug/kg J
87-61-6
1,2,3-Trichlorobenzene
ND
3.6
1.0
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
3.6
0.71
ug/kg
71-55-6
1, 1, 1 -Trichloroethane
ND
3.6
0.71
ug/kg
79-00-5
1,1,2-Trichloroethane
ND
3.6
0.71
ug/kg
79-01-6
Trichloroethylene
ND
3.6
0.71
ug/kg
75-69-4
Trichlorofluoromethane
ND
3.6
1.4
ug/kg
96-18-4
1,2,3-Trichloropropane
ND
3.6
0.89
ug/kg
95-63-6
1,2,4-Trimethylbenzene
1.6
3.6
0.71
ug/kg J
108-67-8
1,3,5-Trimethylbenzene
1.1
3.6
0.71
ug/kg J
108-05-4
Vinyl Acetate
ND
18
12
ug/kg
75-01-4
Vinyl Chloride
ND
3.6
0.71
ug/kg
m,p-Xylene
ND
7.1
0.78
ug/kg
95-47-6
o-Xylene
2.8
3.6
0.71
ug/kg J
1330-20-7
Xylene (total)
3.5
11
1.5
ug/kg J
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
1868-53-7
Dibromofluoromethane
105%
104%
75-124%
17060-07-0
1,2-Dichloroethane-D4
101%
101%
72-135%
2037-26-5
Toluene-D8
107%
109%
75-126%
460-00-4
4-Bromofluorobenzene
132%
136% c
71-133%
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 94 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-10
Lab Sample ID: FA75651-10 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 89.2
Project: 31 Harnett, Wilmington, NC
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(a) Internal standard response(s) outside method criteria due to sample matrix interference; confirmed by
reanalysis.
(b) Confirmation run for surrogate recoveries.
(c) Outside control limits due to matrix interference.
Page 3 of 3
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 95 of 177
FA75651

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: SB-10
Lab Sample ID: FA75651-10 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8270E SW846 3550C Percent Solids: 89.2
Project: 31 Harnett, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 a 6F06190.D 10 06/23/20 21:54 MV 06/08/20 06:39 OP80524 S617240
Run #2
Initial Weight Final Volume
Run # 1 29.8 g 1.0 ml
Run #2
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
65-85-0
Benzoic Acid
ND
9400
1900
ug/kg
59-50-7
4-Chloro-3-methyl Phenol
ND
1900
210
ug/kg
95-57-8
2-Chlorophenol
ND
1900
230
ug/kg
120-83-2
2,4-Dichlorophenol
ND
1900
220
ug/kg
105-67-9
2,4-Dimethylphenol
ND
1900
500
ug/kg
51-28-5
2,4-Dinitrophenol
ND
9400
1900
ug/kg
534-52-1
4,6-Dinitro-o-cresol
ND
3800
750
ug/kg
95-48-7
2-Methylphenol
ND
1900
230
ug/kg
3&4-Methylphenol
ND
1900
310
ug/kg
88-75-5
2-Nitrophenol
ND
1900
200
ug/kg
100-02-7
4-Nitrophenol
ND
9400
1900
ug/kg
87-86-5
Pentachlorophenolb
ND
9400
1900
ug/kg
108-95-2
Phenol
ND
1900
190
ug/kg
88-06-2
2,4,6-Trichlorophenol
ND
1900
220
ug/kg
83-32-9
Acenaphthene
285
1900
200
ug/kg J
208-96-8
Acenaphthylene
ND
1900
190
ug/kg
120-12-7
Anthracene
271
1900
210
ug/kg J
56-55-3
Benzo(a)anthracene
511
1900
190
ug/kg J
50-32-8
Benzo(a)pyrene
452
1900
220
ug/kg J
205-99-2
Benzo(b)fluoranthene
558
1900
210
ug/kg J
191-24-2
Benzo(g, h, i)perylene
214
1900
190
ug/kg J
207-08-9
Benzo(k)fluoranthene
ND
1900
250
ug/kg
100-51-6
Benzyl Alcohol
ND
1900
190
ug/kg
101-55-3
4-13romophenyl phenyl ether
ND
1900
200
ug/kg
85-68-7
Butyl benzyl phthalate
ND
1900
380
ug/kg
106-47-8
4-Chloroaniline
ND
1900
470
ug/kg
111-91-1
bis(2-Chloroethoxy)methane
ND
1900
190
ug/kg
111-44-4
bis(2-Chloroethyl)ether
ND
1900
220
ug/kg
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
1900
240
ug/kg
91-58-7
2-Chloronaphthalene
ND
1900
190
ug/kg
7005-72-3
4-Chlorophenyl phenyl ether
ND
1900
190
ug/kg
218-01-9
Chrysene
522
1900
190
ug/kg J
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 96 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-10
Lab Sample ID: FA75651-10 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8270E SW846 3550C Percent Solids: 89.2
Project: 31 Harnett, Wilmington, NC
ABN List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
53-70-3
Dibenzo(a,h)anthracene
ND
1900
240
ug/kg
132-64-9
Dibenzofaran
ND
1900
190
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
1900
190
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
1900
200
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
1900
250
ug/kg
91-94-1
3,3'-Dichlorobenzidine
ND
1900
450
ug/kg
84-66-2
Diethyl Phthalate
ND
3800
380
ug/kg
131-11-3
Dimethyl Phthalate
ND
1900
380
ug/kg
117-84-0
Di-n-octyl Phthalate
ND
1900
380
ug/kg
84-74-2
Di-n-butyl Phthalate
ND
3800
750
ug/kg
122-66-7
1,2-Diphenylhydrazine
ND
1900
190
ug/kg
117-81-7
bis(2-Ethylhexyl)phthalate
ND
3800
380
ug/kg
206-44-0
Fluoranthene
1520
1900
190
ug/kg J
86-73-7
Fluorene
250
1900
200
ug/kg J
118-74-1
Hexachlorobenzene
ND
1900
190
ug/kg
87-68-3
Hexachlorobutadiene
ND
1900
190
ug/kg
77-47-4
Hexachlorocyclopentadiene
ND
1900
380
ug/kg
67-72-1
Hexachloroethane
ND
1900
220
ug/kg
193-39-5
Indeno(1,2,3-cd)pyrene
ND
1900
230
ug/kg
78-59-1
Isophorone
ND
1900
190
ug/kg
90-12-0
1-Methylnaphthalene
ND
1900
190
ug/kg
91-57-6
2-Methylnaphthalene
ND
1900
190
ug/kg
91-20-3
Naphthalene
ND
1900
190
ug/kg
98-95-3
Nitrobenzene
ND
1900
190
ug/kg
621-64-7
N-Nitrosodi-n-propylamine
ND
1900
190
ug/kg
86-30-6
N-Nitrosodiphenylamine
ND
1900
200
ug/kg
85-01-8
Phenanthrene
815
1900
190
ug/kg J
129-00-0
Pyrene
1570
1900
220
ug/kg J
120-82-1
1,2,4-Trichlorobenzene
ND
1900
220
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
367-12-4
2-Fluorophenol
30% °
40-102%
4165-62-2
Phenol-d5
38% °
41-100%
118-79-6
2,4,6-Tribromophenol
58%
42-108%
4165-60-0
Nitrobenzene-d5
36% °
40-105%
321-60-8
2-Fluorobiphenyl
66%
43-107%
1718-51-0
Terphenyl-dl4
70%
45-119%
(a) Dilution required due to matrix interference; extract was viscous.
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 97 of 177
FA75651

SGS North America Inc.
Report of Analysis
Tent Sample ID: SB-10
,ab Sample ID: FA75651-10 Date Sampled: 06/04/20
Ratrix: SO - Soil Date Received: 06/06/20
lthod: SW846 8270E SW846 3550C Percent Solids: 89.2
'roject: 31 Harnett, Wilmington, NC
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(b) Associated ICV outside control limits high, however sample ND.
(c) Outside control limits due to dilution.
Page 3 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
01
98 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-10
Lab Sample ID: FA75651-10 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8081B SW846 3546 Percent Solids: 89.2
Project: 31 Harnett, Wilmington, NC
Page 1 of 1
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
Run #1 ST147934.1)
1
06/19/20 06:44
WH
06/16/20 08:06
OP80695
GST3550
Run #2 ST147918.1)
10
06/19/20 02:09
WH
06/16/20 08:06
OP80695
GST3550
Initial Weight Final Volume
Run#1 15.4g 5.0ml
Run #2 15.4 g 5.0 ml
Pesticide TCL List
CAS No.
Compound
Result
RL
MDL
Units Q
309-00-2
Aldrin a
ND
1.8
0.58
ug/kg
319-84-6
alpha-BHC b
ND
1.8
0.58
ug/kg
319-85-7
beta-BHC a
ND
1.8
0.54
ug/kg
319-86-8
delta-BHC a
ND
1.8
0.52
ug/kg
58-89-9
gamma-BHC (Lindane) a
ND
1.8
0.55
ug/kg
5103-71-9
alpha -Chlordane a
ND
1.8
0.57
ug/kg
5103-74-2
gamma -Chlordane a
ND
1.8
0.52
ug/kg
60-57-1
Dieldrin
ND
1.8
0.51
ug/kg
72-55-9
4,4'-DDE °
ND d
36
6.6
ug/kg
50-29-3
4,4'-DDT
ND
3.6
0.56
ug/kg
72-20-8
Endrin
ND
3.6
0.92
ug/kg
1031-07-8
Endosulfan sulfate
ND
3.6
0.48
ug/kg
7421-93-4
Endrin aldehyde
ND
3.6
0.42
ug/kg
53494-70-5
Endrin ketone
ND
3.6
0.57
ug/kg
959-98-8
Endosulfan-I a
ND
1.8
0.42
ug/kg
33213-65-9
Endosulfan-II
ND
1.8
0.43
ug/kg
76-44-8
Heptachlor a
ND
1.8
0.54
ug/kg
1024-57-3
Heptachlor epoxide a
ND
1.8
0.54
ug/kg
72-43-5
Methoxychlor
ND
3.6
0.73
ug/kg
8001-35-2
Toxaphene
ND
91
27
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
877-09-8
Tetrachloro-m-xylene
156% e
117%
50-122%
2051-24-3
Decachlorobiphenyl
85%
104%
50-133%
(a) Associated CCV outside of control limits
high, sample was ND.
(b) Associated BS and CCV outside of control limits high, sample was ND.
(c) Dilution required due to matrix interference.
(d) Result is
from Run# 2
(e) Outside control limits due to matrix interference.
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 99 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-10
Lab Sample ID: FA75651-10 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Percent Solids: 89.2
Project: 31 Harnett, Wilmington, NC
Page 1 of 1
Metals Analysis
Analyte Result RL
Units
DF
Prep
Analyzed
By
Method
Prep Method
Arsenic a 4.6 1.9
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 3
Barium a < 39 39
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050E 3
Cadmium a < 0.78 0.78
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050E 3
Chromium a 14.6 1.9
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 3
Lead a 43.5 3.9
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 3
Mercury 0.082 0.046
mg/kg
1
06/16/20
06/16/20
7c
SW846 7471E 1
SW846 7471B 4
Selenium a < 3.9 3.9
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 3
Silver a < 1.9 1.9
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 3
(1) Instrument QC Batch: MA16828
(2) Instrument QC Batch: MA16830
(3) Prep QC Batch: MP37382
(4) Prep QC Batch: MP37396
(a) Sample dilution required due to difficult matrix.
RL = Reporting Limit
6 100 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: SB-10
Lab Sample ID: FA75651-10 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Percent Solids: 89.2
Project: 31 Harnett, Wilmington, NC
General Chemistry
Analyte Result
Chromium, Hexavalent a < 0.46
Solids, Percent 89.2
(a) Analysis performed at SGS Dayton, NJ.
RL = Reporting Limit
Page 1 of 1
RL Units
DF
Analyzed
By
Method
0.46 mg/kg
1
06/15/2014:42
ANJ
SW846306OA/7199
%
1
06/ 10/20 13:44
cs
SM19 2540G
6 101 of 177
FA75651

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: DUP-01
Lab Sample ID: FA75651-11 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 87.3
Project: 31 Harnett, Wilmington, NC
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
Run #1 a F0095944.D
1
06/09/20 20:08
SP
n/a
n/a
VF3373
Run #2 b F0095969.1)
1
06/10/20 19:09
SP
n/a
n/a
VF3374
Initial Weight Final Volume
Run # 1 6.12 g 5.0 ml
Run #2 6.95 g 5.0 ml
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
67-64-1
Acetone
290
190
94
ug/kg
71-43-2
Benzene
ND
4.7
1.1
ug/kg
108-86-1
Bromobenzene
ND
4.7
0.94
ug/kg
74-97-5
Bromochloromethane
ND
4.7
1.4
ug/kg
75-27-4
Bromodichloromethane
ND
4.7
0.94
ug/kg
75-25-2
Bromoform
ND
4.7
0.94
ug/kg
78-93-3
2-Butanone (MEK)
36.5
23
6.8
ug/kg
104-51-8
n-Butylbenzene
ND
4.7
0.94
ug/kg
135-98-8
sec-Butylbenzene
ND
4.7
0.94
ug/kg
98-06-6
tert-Butylbenzene
ND
4.7
0.94
ug/kg
56-23-5
Carbon Tetrachloride
ND
4.7
0.95
ug/kg
108-90-7
Chlorobenzene
ND
4.7
0.94
ug/kg
75-00-3
Chloroethane
ND
4.7
1.9
ug/kg
67-66-3
Chloroform
ND
4.7
1.2
ug/kg
95-49-8
o-Chlorotoluene
ND
4.7
0.94
ug/kg
106-43-4
p-Chlorotoluene
ND
4.7
0.94
ug/kg
124-48-1
Dibromochloromethane
ND
4.7
0.94
ug/kg
106-93-4
1,2-Dibromoethane
ND
4.7
0.94
ug/kg
75-71-8
Dichlorodifluoromethane
ND
4.7
1.9
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
4.7
0.94
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
4.7
0.94
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
4.7
1.1
ug/kg
75-34-3
1, 1 -Dichloroethane
ND
4.7
1.7
ug/kg
107-06-2
1,2-Dichloroethane
ND
4.7
0.94
ug/kg
75-35-4
1, 1 -Dichloroethylene
ND
4.7
0.94
ug/kg
156-59-2
cis-1,2-Dichloroethylene
ND
4.7
1.3
ug/kg
156-60-5
trans- 1, 2-Dichloroethylene
ND
4.7
0.94
ug/kg
78-87-5
1,2-Dichloropropane
ND
4.7
0.94
ug/kg
142-28-9
1,3-Dichloropropane
ND
4.7
0.94
ug/kg
594-20-7
2,2-Dichloropropane
ND
4.7
0.94
ug/kg
563-58-6
1, 1 -Dichloropropene
ND
4.7
0.95
ug/kg
10061-01-5
cis- 1, 3 -Dichloropropene
ND
4.7
0.94
ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 102 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: DUP-01
Lab Sample ID: FA75651-11 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 87.3
Project: 31 Harnett, Wilmington, NC
VOA List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
10061-02-6
trans- 1, 3-Dichloropropene
ND
4.7
0.94
ug/kg
108-20-3
Di -Isopropyl Ether
ND
4.7
2.2
ug/kg
64-17-5
Ethyl Alcohol
ND
370
70
ug/kg
100-41-4
Ethylbenzene
ND
4.7
0.94
ug/kg
591-78-6
2-Hexanone
ND
23
7.0
ug/kg
98-82-8
Isopropylbenzene
ND
4.7
0.94
ug/kg
99-87-6
p-Isopropyltoluene
1.4
4.7
0.94
ug/kg J
74-83-9
Methyl Bromide
ND
4.7
1.9
ug/kg
74-87-3
Methyl Chloride
ND
4.7
1.9
ug/kg
75-09-2
Methylene Chloride
ND
19
10
ug/kg
108-10-1
4-Methyl-2-pentanone (MIBK) ND
23
7.0
ug/kg
1634-04-4
Methyl Tert Butyl Ether
ND
4.7
0.94
ug/kg
91-20-3
Naphthalene
ND
4.7
1.9
ug/kg
103-65-1
n-Propylbenzene
ND
4.7
0.94
ug/kg
100-42-5
Styrene
ND
4.7
0.94
ug/kg
630-20-6
1, 1, 1,2-Tetrachloroethane
ND
4.7
0.96
ug/kg
79-34-5
1,1,2,2-Tetrachloroethane
ND
4.7
0.94
ug/kg
127-18-4
Tetrachloroethylene
ND
4.7
1.2
ug/kg
108-88-3
Toluene
12.1
19
9.4
ug/kg J
87-61-6
1,2,3-Trichlorobenzene
ND
4.7
1.3
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
4.7
0.94
ug/kg
71-55-6
1, 1, 1 -Trichloroethane
ND
4.7
0.94
ug/kg
79-00-5
1,1,2-Trichloroethane
ND
4.7
0.94
ug/kg
79-01-6
Trichloroethylene
ND
4.7
0.94
ug/kg
75-69-4
Trichlorofluoromethane
ND
4.7
1.9
ug/kg
96-18-4
1,2,3-Trichloropropane
ND
4.7
1.2
ug/kg
95-63-6
1,2,4-Trimethylbenzene
ND
4.7
0.94
ug/kg
108-67-8
1,3,5-Trimethylbenzene
ND
4.7
0.94
ug/kg
108-05-4
Vinyl Acetate
ND
23
15
ug/kg
75-01-4
Vinyl Chloride
ND
4.7
0.94
ug/kg
m,p-Xylene
ND
9.4
1.0
ug/kg
95-47-6
o-Xylene
ND
4.7
0.94
ug/kg
1330-20-7
Xylene (total)
ND
14
2.0
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
1868-53-7
Dibromofluoromethane
107%
106%
75-124%
17060-07-0
1,2-Dichloroethane-D4
103%
99%
72-135%
2037-26-5
Toluene-D8
111%
110%
75-126%
460-00-4
4-Bromofluorobenzene
134% c
135% c
71-133%
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 103 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: DUP-01
Lab Sample ID: FA75651-11 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: 87.3
Project: 31 Harnett, Wilmington, NC
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(a) Internal standard response(s) outside method criteria due to sample matrix interference; confirmed by
reanalysis.
(b) Confirmation run for surrogate recoveries.
(c) Outside control limits due to matrix interference. Confirmed by reanalysis.
Page 3 of 3
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
6 104 of 177
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SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: DUP-01
Lab Sample ID: FA75651-11 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8270E SW846 3550C Percent Solids: 87.3
Project: 31 Harnett, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 a 6F06191.D 10 06/23/20 22:20 MV 06/08/20 06:39 OP80524 S617240
Run #2
Initial Weight Final Volume
Run#1 30.0g 1.0ml
Run #2
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
65-85-0
Benzoic Acid
ND
9500
1900
ug/kg
59-50-7
4-Chloro-3-methyl Phenol
ND
1900
220
ug/kg
95-57-8
2-Chlorophenol
ND
1900
230
ug/kg
120-83-2
2,4-Dichlorophenol
ND
1900
220
ug/kg
105-67-9
2,4-Dimethylphenol
ND
1900
510
ug/kg
51-28-5
2,4-Dinitrophenol
ND
9500
1900
ug/kg
534-52-1
4,6-Dinitro-o-cresol
ND
3800
760
ug/kg
95-48-7
2-Methylphenol
ND
1900
230
ug/kg
3&4-Methylphenol
ND
1900
310
ug/kg
88-75-5
2-Nitrophenol
ND
1900
210
ug/kg
100-02-7
4-Nitrophenol
ND
9500
1900
ug/kg
87-86-5
Pentachlorophenolb
ND
9500
1900
ug/kg
108-95-2
Phenol
ND
1900
190
ug/kg
88-06-2
2,4,6-Trichlorophenol
ND
1900
220
ug/kg
83-32-9
Acenaphthene
ND
1900
200
ug/kg
208-96-8
Acenaphthylene
ND
1900
190
ug/kg
120-12-7
Anthracene
ND
1900
210
ug/kg
56-55-3
Benzo(a)anthracene
198
1900
190
ug/kg J
50-32-8
Benzo(a)pyrene
ND
1900
230
ug/kg
205-99-2
Benzo(b)fluoranthene
298
1900
210
ug/kg J
191-24-2
Benzo(g, h, i)perylene
ND
1900
200
ug/kg
207-08-9
Benzo(k)fluoranthene
ND
1900
250
ug/kg
100-51-6
Benzyl Alcohol
ND
1900
190
ug/kg
101-55-3
4-13romophenyl phenyl ether
ND
1900
200
ug/kg
85-68-7
Butyl benzyl phthalate
ND
1900
380
ug/kg
106-47-8
4-Chloroaniline
ND
1900
480
ug/kg
111-91-1
bis(2-Chloroethoxy)methane
ND
1900
190
ug/kg
111-44-4
bis(2-Chloroethyl)ether
ND
1900
220
ug/kg
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
1900
240
ug/kg
91-58-7
2-Chloronaphthalene
ND
1900
190
ug/kg
7005-72-3
4-Chlorophenyl phenyl ether
ND
1900
190
ug/kg
218-01-9
Chrysene
198
1900
190
ug/kg J
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 105 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: DUP-01
Lab Sample ID: FA75651-11 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Method: SW846 8270E SW846 3550C Percent Solids: 87.3
Project: 31 Harnett, Wilmington, NC
ABN List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
53-70-3
Dibenzo(a,h)anthracene
ND
1900
240
ug/kg
132-64-9
Dibenzofaran
ND
1900
190
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
1900
190
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
1900
210
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
1900
250
ug/kg
91-94-1
3,3'-Dichlorobenzidine
ND
1900
450
ug/kg
84-66-2
Diethyl Phthalate
ND
3800
380
ug/kg
131-11-3
Dimethyl Phthalate
ND
1900
380
ug/kg
117-84-0
Di-n-octyl Phthalate
ND
1900
380
ug/kg
84-74-2
Di-n-butyl Phthalate
ND
3800
760
ug/kg
122-66-7
1,2-Diphenylhydrazine
ND
1900
190
ug/kg
117-81-7
bis(2-Ethylhexyl)phthalate
ND
3800
380
ug/kg
206-44-0
Fluoranthene
398
1900
190
ug/kg J
86-73-7
Fluorene
ND
1900
200
ug/kg
118-74-1
Hexachlorobenzene
ND
1900
190
ug/kg
87-68-3
Hexachlorobutadiene
ND
1900
190
ug/kg
77-47-4
Hexachlorocyclopentadiene
ND
1900
380
ug/kg
67-72-1
Hexachloroethane
ND
1900
220
ug/kg
193-39-5
Indeno(1,2,3-cd)pyrene
ND
1900
230
ug/kg
78-59-1
Isophorone
ND
1900
190
ug/kg
90-12-0
1-Methylnaphthalene
ND
1900
190
ug/kg
91-57-6
2-Methylnaphthalene
ND
1900
190
ug/kg
91-20-3
Naphthalene
ND
1900
190
ug/kg
98-95-3
Nitrobenzene
ND
1900
190
ug/kg
621-64-7
N-Nitrosodi-n-propylamine
ND
1900
190
ug/kg
86-30-6
N-Nitrosodiphenylamine
ND
1900
210
ug/kg
85-01-8
Phenanthrene
ND
1900
190
ug/kg
129-00-0
Pyrene
354
1900
220
ug/kg J
120-82-1
1,2,4-Trichlorobenzene
ND
1900
220
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
367-12-4
2-Fluorophenol
40%
40-102%
4165-62-2
Phenol-d5
47%
41-100%
118-79-6
2,4,6-Tribromophenol
71%
42-108%
4165-60-0
Nitrobenzene-d5
40%
40-105%
321-60-8
2-Fluorobiphenyl
68%
43-107%
1718-51-0
Terphenyl-dl4
58%
45-119%
(a) Dilution required due to matrix interference; extract was viscous.
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 106 of 177
FA75651

SGS North America Inc.
Report of Analysis
Tent Sample ID: DUP-01
,ab Sample ID: FA75651-11 Date Sampled: 06/04/20
Ratrix: SO - Soil Date Received: 06/06/20
lthod: SW846 8270E SW846 3550C Percent Solids: 87.3
'roject: 31 Harnett, Wilmington, NC
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(b) Associated ICV outside control limits high, however sample ND.
Page 3 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 107 of 177
FA75651

SGS North America Inc.
Report of Analysis
Tent Sample ID: DUP-01
,ab Sample ID: FA75651-11 Date Sampled: 06/04/20
Rtrix: SO - Soil Date Received: 06/06/20
lthod: SW846 8081B SW846 3546 Percent Solids: 87.3
'roject: 31 Harnett, Wilmington, NC
Page 1 of 1
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
Run #1 ST147935.1)
1
06/19/20 07:01
WH
06/16/20 08:06
OP80695
GST3550
Run #2 ST147919.1)
10
06/19/20 02:27
WH
06/16/20 08:06
OP80695
GST3550
Initial Weight Final Volume
un#1 14.8g 5.0ml
.un #2 14.8 g 5.0 ml
Pesticide TCL List
CAS No.
Compound
Result
RL
MDL
Units Q
309-00-2
Aldrin a
ND
1.9
0.61
ug/kg
319-84-6
alpha-BHC b
ND
1.9
0.61
ug/kg
319-85-7
beta-BHC a
ND
1.9
0.57
ug/kg
319-86-8
delta-BHC a
ND
1.9
0.55
ug/kg
58-89-9
gamma-BHC (Lindane) a
ND
1.9
0.58
ug/kg
5103-71-9
alpha -Chlordane a
ND
1.9
0.60
ug/kg
5103-74-2
gamma -Chlordane a
ND
1.9
0.56
ug/kg
60-57-1
Dieldrin
ND
1.9
0.54
ug/kg
72-54-8
4,4'-DDD °
ND d
39
5.3
ug/kg
72-55-9
4,4'-DDE °
ND d
39
7.0
ug/kg
50-29-3
4,4'-DDT
ND
3.9
0.59
ug/kg
72-20-8
Endrin
ND
3.9
0.98
ug/kg
1031-07-8
Endosulfan sulfate
ND
3.9
0.51
ug/kg
7421-93-4
Endrin aldehyde
ND
3.9
0.45
ug/kg
53494-70-5
Endrin ketone
ND
3.9
0.61
ug/kg
959-98-8
Endosulfan-I a
ND
1.9
0.45
ug/kg
33213-65-9
Endosulfan-II
ND
1.9
0.46
ug/kg
76-44-8
Heptachlor a
ND
1.9
0.57
ug/kg
1024-57-3
Heptachlor epoxide a
ND
1.9
0.57
ug/kg
72-43-5
Methoxychlor
ND
3.9
0.77
ug/kg
8001-35-2
Toxaphene
ND
97
29
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
877-09-8 Tetrachloro-m-xylene 154% e 117% 50-122%
2051-24-3 Decachlorobiphenyl 81% 103% 50-133%
(a) Associated CCV outside of control limits high, sample was ND.
(b) Associated BS and CCV outside of control limits high, sample was ND.
(c) Dilution required due to matrix interference.
(d) Result is from Run# 2
(e) Outside control limits due to matrix interference.
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
01
108 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: DUP-0I
Lab Sample ID: FA75651-11 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Percent Solids: 87.3
Project: 31 Harnett, Wilmington, NC
Page 1 of 1
Metals Analysis
Analyte Result RL
Units
DF
Prep
Analyzed
By
Method
Prep Method
Arsenic a 5.5 1.8
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 3
Barium a 38.1 36
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050E 3
Cadmium a < 0.72 0.72
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050E 3
Chromium a 15.0 1.8
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 3
Lead a 51.2 3.6
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 3
Mercury 0.21 0.041
mg/kg
1
06/16/20
06/16/20
7c
SW846 7471E 1
SW846 7471B 4
Selenium a < 3.6 3.6
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 3
Silver a < 1.8 1.8
mg/kg
5
06/15/20
06/17/20
LM
SW846 6010D 2
SW846 3050B 3
(1) Instrument QC Batch: MA16828
(2) Instrument QC Batch: MA16830
(3) Prep QC Batch: MP37382
(4) Prep QC Batch: MP37396
(a) Sample dilution required due to difficult matrix.
RL = Reporting Limit
6 109 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: DUP-01
Lab Sample ID: FA75651-11 Date Sampled: 06/04/20
Matrix: SO - Soil Date Received: 06/06/20
Percent Solids: 87.3
Project: 31 Harnett, Wilmington, NC
General Chemistry
Analyte Result
Chromium, Hexavalent a < 0.45
Solids, Percent 87.3
(a) Analysis performed at SGS Dayton, NJ.
RL = Reporting Limit
Page 1 of 1
RL Units
DF
Analyzed
By
Method
0.45 mg/kg
1
06/15/2015:05
ANJ
SW846306OA/7199
%
1
06/ 10/20 13:44
cs
SM19 2540G
6 110 of 177
FA75651

SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID: TRIP BLANK
Lab Sample ID: FA75651-12 Date Sampled: 06/04/20
Matrix: SO - Trip Blank Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: n/a
Project: 31 Harnett, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 F0095945.D 1 06/09/20 20:35 SP n/a n/a VF3373
Run #2
Initial Weight Final Volume
Run # 1 5.00 g 5.0 ml
Run #2
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
67-64-1
Acetone
166
200
100
ug/kg J
71-43-2
Benzene
ND
5.0
1.2
ug/kg
108-86-1
Bromobenzene
ND
5.0
1.0
ug/kg
74-97-5
Bromochloromethane
ND
5.0
1.5
ug/kg
75-27-4
Bromodichloromethane
ND
5.0
1.0
ug/kg
75-25-2
Bromoform
ND
5.0
1.0
ug/kg
78-93-3
2-Butanone (MEK)
ND
25
7.3
ug/kg
104-51-8
n-Butylbenzene
ND
5.0
1.0
ug/kg
135-98-8
sec-Butylbenzene
ND
5.0
1.0
ug/kg
98-06-6
tert-Butylbenzene
ND
5.0
1.0
ug/kg
56-23-5
Carbon Tetrachloride
ND
5.0
1.0
ug/kg
108-90-7
Chlorobenzene
ND
5.0
1.0
ug/kg
75-00-3
Chloroethane
ND
5.0
2.0
ug/kg
67-66-3
Chloroform
ND
5.0
1.3
ug/kg
95-49-8
o-Chlorotoluene
ND
5.0
1.0
ug/kg
106-43-4
p-Chlorotoluene
ND
5.0
1.0
ug/kg
124-48-1
Dibromochloromethane
ND
5.0
1.0
ug/kg
106-93-4
1,2-Dibromoethane
ND
5.0
1.0
ug/kg
75-71-8
Dichlorodifluoromethane
ND
5.0
2.0
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
5.0
1.0
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
5.0
1.0
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
5.0
1.2
ug/kg
75-34-3
1, 1 -Dichloroethane
ND
5.0
1.8
ug/kg
107-06-2
1,2-Dichloroethane
ND
5.0
1.0
ug/kg
75-35-4
1, 1 -Dichloroethylene
ND
5.0
1.0
ug/kg
156-59-2
cis-1,2-Dichloroethylene
ND
5.0
1.4
ug/kg
156-60-5
trans- 1, 2-Dichloroethylene
ND
5.0
1.0
ug/kg
78-87-5
1,2-Dichloropropane
ND
5.0
1.0
ug/kg
142-28-9
1,3-Dichloropropane
ND
5.0
1.0
ug/kg
594-20-7
2,2-Dichloropropane
ND
5.0
1.0
ug/kg
563-58-6
1, 1 -Dichloropropene
ND
5.0
1.0
ug/kg
10061-01-5
cis- 1, 3 -Dichloropropene
ND
5.0
1.0
ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 111 of 177
FA75651

SGS North America Inc.
Report of Analysis
Client Sample ID: TRIP BLANK
Lab Sample ID: FA75651-12 Date Sampled: 06/04/20
Matrix: SO - Trip Blank Soil Date Received: 06/06/20
Method: SW846 8260D Percent Solids: n/a
Project: 31 Harnett, Wilmington, NC
VOA List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
10061-02-6
trans- 1, 3-Dichloropropene
ND
5.0
1.0
ug/kg
108-20-3
Di -Isopropyl Ether
ND
5.0
2.3
ug/kg
64-17-5
Ethyl Alcohol
ND
400
75
ug/kg
100-41-4
Ethylbenzene
ND
5.0
1.0
ug/kg
591-78-6
2-Hexanone
ND
25
7.5
ug/kg
98-82-8
Isopropylbenzene
ND
5.0
1.0
ug/kg
99-87-6
p-Isopropyltoluene
ND
5.0
1.0
ug/kg
74-83-9
Methyl Bromide
ND
5.0
2.0
ug/kg
74-87-3
Methyl Chloride
ND
5.0
2.0
ug/kg
75-09-2
Methylene Chloride
ND
20
11
ug/kg
108-10-1
4-Methyl-2-pentanone (MIBK) ND
25
7.5
ug/kg
1634-04-4
Methyl Tert Butyl Ether
ND
5.0
1.0
ug/kg
91-20-3
Naphthalene
ND
5.0
2.0
ug/kg
103-65-1
n-Propylbenzene
ND
5.0
1.0
ug/kg
100-42-5
Styrene
ND
5.0
1.0
ug/kg
630-20-6
1, 1, 1,2-Tetrachloroethane
ND
5.0
1.0
ug/kg
79-34-5
1,1,2,2-Tetrachloroethane
ND
5.0
1.0
ug/kg
127-18-4
Tetrachloroethylene
ND
5.0
1.3
ug/kg
108-88-3
Toluene
99.6
20
10
ug/kg
87-61-6
1,2,3-Trichlorobenzene
ND
5.0
1.4
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
5.0
1.0
ug/kg
71-55-6
1, 1, 1 -Trichloroethane
ND
5.0
1.0
ug/kg
79-00-5
1,1,2-Trichloroethane
ND
5.0
1.0
ug/kg
79-01-6
Trichloroethylene
ND
5.0
1.0
ug/kg
75-69-4
Trichlorofluoromethane
ND
5.0
2.0
ug/kg
96-18-4
1,2,3-Trichloropropane
ND
5.0
1.3
ug/kg
95-63-6
1,2,4-Trimethylbenzene
ND
5.0
1.0
ug/kg
108-67-8
1,3,5-Trimethylbenzene
ND
5.0
1.0
ug/kg
108-05-4
Vinyl Acetate
ND
25
16
ug/kg
75-01-4
Vinyl Chloride
ND
5.0
1.0
ug/kg
m,p-Xylene
ND
10
1.1
ug/kg
95-47-6
o-Xylene
ND
5.0
1.0
ug/kg
1330-20-7
Xylene (total)
ND
15
2.1
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
1868-53-7
Dibromofluoromethane
105%
75-124%
17060-07-0
1,2-Dichloroethane-D4
104%
72-135%
2037-26-5
Toluene-138
98%
75-126%
460-00-4
4-Bromofluorobenzene
102%
71-133%
Page 2 of 2
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 112 of 177
FA75651

ffm
Orlando, FL
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
Section 4
Cal
113 of 177
FA75651

SGS North America Inc - Orlando FA-I,%31
Chain of Custody SGS - ORLANDO JOB # : PAGE_ _OF�
_
--------'
_. _.._.--....--.- _..__-,-------
TEL.[phone] FAXe;407A25.0707
SGS-ORLANDO Quote# SKIFF#
�
- Client / Reporting Information -_■.. Project Information
'•*3 -:" s.fi;..
Analytical Information
. .-
Matrix Codes
Company Name:
�C
Project Name:
V
{�
,�
V
9
',£
J
tO
("
eN
03
.�
Q
M
G.)
.7
G
10
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tom)
to
-
- or mg
Water
G -Ground
W W - Water
SW - Surface
Water
so -soil
SL-Sludge
of -oil
LIO - Other Liquid
AIR - Air
SOL-Other Solid
Address: , '
N }.
Street
City: State: Zip:�(r„
v VK i - (iI C 2 (
Y State
Prq� et Contaqqtt� Email:
17.f_ day( �PF 6n h
ProtIec_t #
yL vc .00 rs1
Phone
Si ,?iS-G -ILOL
Fax#
Sampler(s)Na (7,1(Printed)
Sam ler7: Name(
4 Sam Ier Y:
Client Purchase Orders
SGS
Sam la #
Field ID / Point of Collection
OOLL—ION
-
COWMNER
INFORMATION
DATE
TIME
BAMPL�
MATRIX
OF
_Es
qq
°a s
LAB USE ONLY
�y
0Z
L.
to
k
I
21
x
11�-
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WqtZ�
-o
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k
20
1
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K
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SQ-fa
(
K
2l
x
!-ZEL
Turnaround tme Sul i ass days
+ !
i w °
" •, '
Data
Deliverable
Information
:9C
"*
*
/
Remarks
uslne Approved By: l Date:
I,
Day
5 Day
3 Day RUSH
2 Day RUSH
1 Day RUSH
Other
Rush T/A Data Available VIA Email or Lablink
[]COMMERCIAL ONLY)
QQOMMERCIAL "B" (RESULTS PLUS OC)
[]REDT1 (EPALEVEL3)
�FULLTI (EPA LEVEL 4)
EDD'S
:...,. ... ..... �., .....
n�7Comments
l4-
YX.0 �'Ld{� 59 wt b-5 9—
— c ' i V" L/
YC'�Ci�-�- Raleigh,
Service Cen
as »+
Sam le Custo must
documented below each time sam
lea thane possession, Ineludin
courier dative
Re lin Sampler/Affiliation
1
Date Time:
L� O
Received By/A(Blia
Relinquished By/Affiliation
3
Date Time:
Racet Malb
V
4 7.2
RelO.Vi ylAffill.ti.nDate
5
Time:
Received By/Afftltation
6
Relinquished By/Affiliation
7
Date Time:
Received By/Affiliation
8
Lab Use Only : Cooler Temperature (s) Celsius (corrected): .s .crom/en/ - ondido
ORLD-SMT-0001-03-FORM-COC (4).xls Rev 031318
Dr
FA75651: Chain of Custody
Page 1 of 2
6 114 of 177
FA75651

SGS Sample Receipt Summary
Job Number: FA75651 Client: GEOSYNTEC Project: GN7035
Date / Time Received: 6/6/2020 9:30:00 AM
[Therm ID: IR 1; 1
ler Temps (Raw Measured) °C: Cooler 1: (4.9);
Cooler Temps (Corrected) °C: Cooler 1: (4.1);
Cooler Information
Y or N
1. Custody Seals Present
❑.I ❑
2. Custody Seals Intact
❑d ❑
3. Temp criteria achieved
❑d ❑
4. Cooler temp verification
IR Gun
5. Cooler media
Ice(Bag
livery Method: FX Airbill Ws: 4913 8691 3633
;rm CIF: -0.8; # of Coolers: 1
Sample Information
Y
or N N/A
1. Sample labels present on bottles
W
❑
2. Samples preserved properly
❑d
❑
3. Sufficient volume/containers recvd for analysis:
W
❑
4. Condition of sample
Intact
5. Sample recvd within HT
0
❑
6. Dates/Times/IDs on CDC match Sample Label
❑�
❑
Trio Blank Information
Y or
N
N/A
7. VOCs have headspace
❑
❑.i
❑
1. Trip Blank present / cooler
❑d
❑
[
8. Bottles received for unspecified tests
❑
❑d
2. Trip Blank listed on COC
❑d
❑
[
9. Compositing instructions clear
❑
❑
k
10. Voa Soil Kits/Jars received past 48hrs?
❑
❑
❑,/
W or S
N/A
11. % Solids Jar received?
❑
❑
0
3. Type Of TB Received
❑
❑d
❑
12. Residual Chlorine Present?
❑
❑
❑,�
Misc. Information
Number of Encores: 25-Gram
5-Gram
Number of 5035 Field Kits: 12 Number of Lab Filtered
Metals:
Test Strip Lot #s: pH 0-3
230315
pH 10-12 219813A Other: (Specify)
Residual Chlorine Test Strip Lot #:
Comments
shoot Rev. Dale 05/24/17 Technician: PETERH Date: 6/6/2020 9:30:00 AM
Reviewer: Date:
FA75651: Chain of Custody
Page 2 of 2
6 115 of 177
FA75651

ffm
Orlando, FL
MS Volatiles
QC Data Summaries
i
IN
Section 5
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
6 116 of 177
FA75651

Method Blank Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 1 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
VF3373-MB
170095929.1)
1
06/09/20
SP
n/a
n/a
VF3373
The QC reported here applies to the following samples: Method: SW846 8260D
FA75651-4, FA75651-5, FA75651-6, FA75651-7, FA75651-10, FA75651-11, FA75651-12
CAS No. Compound
Result RL MDL Units Q
67-64-1
Acetone
ND
200
100
ug/kg
71-43-2
Benzene
ND
5.0
1.2
ug/kg
108-86-1
Bromobenzene
ND
5.0
1.0
ug/kg
74-97-5
Bromochloromethane
ND
5.0
1.5
ug/kg
75-27-4
Bromodichloromethane
ND
5.0
1.0
ug/kg
75-25-2
Bromoform
ND
5.0
1.0
ug/kg
78-93-3
2-Butanone (MEK)
ND
25
7.3
ug/kg
104-51-8
n-Butylbenzene
ND
5.0
1.0
ug/kg
135-98-8
sec-Butylbenzene
ND
5.0
1.0
ug/kg
98-06-6
tert-Butylbenzene
ND
5.0
1.0
ug/kg
56-23-5
Carbon Tetrachloride
ND
5.0
1.0
ug/kg
108-90-7
Chlorobenzene
ND
5.0
1.0
ug/kg
75-00-3
Chloroethane
ND
5.0
2.0
ug/kg
67-66-3
Chloroform
ND
5.0
1.3
ug/kg
95-49-8
o-Chlorotoluene
ND
5.0
1.0
ug/kg
106-43-4
p-Chlorotoluene
ND
5.0
1.0
ug/kg
124-48-1
Dibromochloromethane
ND
5.0
1.0
ug/kg
106-93-4
1,2-Dibromoethane
ND
5.0
1.0
ug/kg
75-71-8
Dichlorodifluoromethane
ND
5.0
2.0
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
5.0
1.0
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
5.0
1.0
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
5.0
1.2
ug/kg
75-34-3
1, 1 -Dichloroethane
ND
5.0
1.8
ug/kg
107-06-2
1,2-Dichloroethane
ND
5.0
1.0
ug/kg
75-35-4
1, 1 -Dichloroethylene
ND
5.0
1.0
ug/kg
156-59-2
cis- 1, 2-Dichloroethylene
ND
5.0
1.4
ug/kg
156-60-5
trans- 1, 2-Dichloroethylene
ND
5.0
1.0
ug/kg
78-87-5
1,2-Dichloropropane
ND
5.0
1.0
ug/kg
142-28-9
1,3-Dichloropropane
ND
5.0
1.0
ug/kg
594-20-7
2,2-Dichloropropane
ND
5.0
1.0
ug/kg
563-58-6
1, 1 -Dichloropropene
ND
5.0
1.0
ug/kg
10061-01-5 cis- 1, 3-Dichloropropene
ND
5.0
1.0
ug/kg
10061-02-6 trans- 1, 3-Dichloropropene
ND
5.0
1.0
ug/kg
108-20-3
Di -Isopropyl Ether
ND
5.0
2.3
ug/kg
64-17-5
Ethyl Alcohol
ND
400
75
ug/kg
100-41-4
Ethlbenzene
ND
5.0
1.0
ug/kg
6 117 of 177
FA75651

Method Blank Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 2 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
VF3373-MB
F0095929.D
1
06/09/20
SP
n/a
n/a
VF3373
The QC reported here applies to the following samples: Method: SW846 8260D
FA75651-4, FA75651-5, FA75651-6, FA75651-7, FA75651-10, FA75651-11, FA75651-12
CAS No. Compound
Result RL MDL Units Q
591-78-6
2-Hexanone
ND
25
7.5
ug/kg
98-82-8
Isopropylbenzene
ND
5.0
1.0
ug/kg
99-87-6
p-Isopropyltoluene
ND
5.0
1.0
ug/kg
74-83-9
Methyl Bromide
ND
5.0
2.0
ug/kg
74-87-3
Methyl Chloride
ND
5.0
2.0
ug/kg
75-09-2
Methylene Chloride
ND
20
11
ug/kg
108-10-1
4-Methyl-2-pentanone (MIBK) ND
25
7.5
ug/kg
1634-04-4
Methyl Tert Butyl Ether
ND
5.0
1.0
ug/kg
91-20-3
Naphthalene
ND
5.0
2.0
ug/kg
103-65-1
n-Propylbenzene
ND
5.0
1.0
ug/kg
100-42-5
Styrene
ND
5.0
1.0
ug/kg
630-20-6
1, 1, 1, 2-Tetrachloroethane
ND
5.0
1.0
ug/kg
79-34-5
1,1,2,2-Tetrachloroethane
ND
5.0
1.0
ug/kg
127-18-4
Tetrachloroethylene
ND
5.0
1.3
ug/kg
108-88-3
Toluene
ND
20
10
ug/kg
87-61-6
1,2,3-Trichlorobenzene
ND
5.0
1.4
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
5.0
1.0
ug/kg
71-55-6
1, 1, 1 -Trichloroethane
ND
5.0
1.0
ug/kg
79-00-5
1,1,2-Trichloroethane
ND
5.0
1.0
ug/kg
79-01-6
Trichloroethylene
ND
5.0
1.0
ug/kg
75-69-4
Trichlorofluoromethane
ND
5.0
2.0
ug/kg
96-18-4
1, 2,3 -Trichloropropane
ND
5.0
1.3
ug/kg
95-63-6
1,2,4-Trimethylbenzene
ND
5.0
1.0
ug/kg
108-67-8
1,3,5-Trimethylbenzene
ND
5.0
1.0
ug/kg
108-05-4
Vinyl Acetate
ND
25
16
ug/kg
75-01-4
Vinyl Chloride
ND
5.0
1.0
ug/kg
m,p-Xylene
ND
10
1.1
ug/kg
95-47-6
o-Xylene
ND
5.0
1.0
ug/kg
1330-20-7
Xylene (total)
ND
15
2.1
ug/kg
CAS No.
Surrogate Recoveries
Limits
1868-53-7
Dibromofluoromethane
101%
75-124%
17060-07-0
1,2-Dichloroethane-D4
102%
72-135%
2037-26-5
Toluene-D8
101%
75-126%
6 118 of 177
FA75651

Method Blank Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 3 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
VF3373-MB
170095929.1)
1
06/09/20
SP
n/a
n/a
VF3373
The QC reported here applies to the following samples: Method: SW846 8260D
FA75651-4, FA75651-5, FA75651-6, FA75651-7, FA75651-10, FA75651-11, FA75651-12
CAS No. Surrogate Recoveries Limits
460-00-4 4-Bromofluorobenzene 103% 71-133%
6 119 of 177
FA75651

Method Blank Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 1 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
VF3374-MB
170095957.1)
1
06/10/20
SP
n/a
n/a
VF3374
The QC reported here applies to the following samples: Method: SW846 8260D
FA75651-1, FA75651-2, FA75651-3, FA75651-8, FA75651-9
CAS No. Compound
Result RL MDL Units Q
67-64-1
Acetone
ND
200
100
ug/kg
71-43-2
Benzene
ND
5.0
1.2
ug/kg
108-86-1
Bromobenzene
ND
5.0
1.0
ug/kg
74-97-5
Bromochloromethane
ND
5.0
1.5
ug/kg
75-27-4
Bromodichloromethane
ND
5.0
1.0
ug/kg
75-25-2
Bromoform
ND
5.0
1.0
ug/kg
78-93-3
2-Butanone (MEK)
ND
25
7.3
ug/kg
104-51-8
n-Butylbenzene
ND
5.0
1.0
ug/kg
135-98-8
sec-Butylbenzene
ND
5.0
1.0
ug/kg
98-06-6
tert-Butylbenzene
ND
5.0
1.0
ug/kg
56-23-5
Carbon Tetrachloride
ND
5.0
1.0
ug/kg
108-90-7
Chlorobenzene
ND
5.0
1.0
ug/kg
75-00-3
Chloroethane
ND
5.0
2.0
ug/kg
67-66-3
Chloroform
ND
5.0
1.3
ug/kg
95-49-8
o-Chlorotoluene
ND
5.0
1.0
ug/kg
106-43-4
p-Chlorotoluene
ND
5.0
1.0
ug/kg
124-48-1
Dibromochloromethane
ND
5.0
1.0
ug/kg
106-93-4
1,2-Dibromoethane
ND
5.0
1.0
ug/kg
75-71-8
Dichlorodifluoromethane
ND
5.0
2.0
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
5.0
1.0
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
5.0
1.0
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
5.0
1.2
ug/kg
75-34-3
1, 1 -Dichloroethane
ND
5.0
1.8
ug/kg
107-06-2
1,2-Dichloroethane
ND
5.0
1.0
ug/kg
75-35-4
1, 1 -Dichloroethylene
ND
5.0
1.0
ug/kg
156-59-2
cis- 1, 2-Dichloroethylene
ND
5.0
1.4
ug/kg
156-60-5
trans- 1, 2-Dichloroethylene
ND
5.0
1.0
ug/kg
78-87-5
1,2-Dichloropropane
ND
5.0
1.0
ug/kg
142-28-9
1,3-Dichloropropane
ND
5.0
1.0
ug/kg
594-20-7
2,2-Dichloropropane
ND
5.0
1.0
ug/kg
563-58-6
1, 1 -Dichloropropene
ND
5.0
1.0
ug/kg
10061-01-5 cis- 1, 3-Dichloropropene
ND
5.0
1.0
ug/kg
10061-02-6 trans- 1, 3-Dichloropropene
ND
5.0
1.0
ug/kg
108-20-3
Di -Isopropyl Ether
ND
5.0
2.3
ug/kg
64-17-5
Ethyl Alcohol
ND
400
75
ug/kg
100-41-4
Ethlbenzene
ND
5.0
1.0
ug/kg
6 120 of 177
FA75651

Method Blank Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 2 of 3
ample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batcl
TF3374-MB
F0095957.D
1
06/10/20
SP
n/a
n/a
VF3374
The QC reported here applies to the following samples: Method: SW846 8260D
FA75651-1, FA75651-2, FA75651-3, FA75651-8, FA75651-9
CAS No. Compound Result RL MDL Units Q
591-78-6
2-Hexanone
ND
25
7.5
ug/kg
98-82-8
Isopropylbenzene
ND
5.0
1.0
ug/kg
99-87-6
p-Isopropyltoluene
ND
5.0
1.0
ug/kg
74-83-9
Methyl Bromide
ND
5.0
2.0
ug/kg
74-87-3
Methyl Chloride
ND
5.0
2.0
ug/kg
75-09-2
Methylene Chloride
ND
20
11
ug/kg
108-10-1
4-Methyl-2-pentanone (MIBK) ND
25
7.5
ug/kg
1634-04-4
Methyl Tert Butyl Ether
ND
5.0
1.0
ug/kg
91-20-3
Naphthalene
ND
5.0
2.0
ug/kg
103-65-1
n-Propylbenzene
ND
5.0
1.0
ug/kg
100-42-5
Styrene
ND
5.0
1.0
ug/kg
630-20-6
1, 1, 1, 2-Tetrachloroethane
ND
5.0
1.0
ug/kg
79-34-5
1,1,2,2-Tetrachloroethane
ND
5.0
1.0
ug/kg
127-18-4
Tetrachloroethylene
ND
5.0
1.3
ug/kg
108-88-3
Toluene
ND
20
10
ug/kg
87-61-6
1,2,3-Trichlorobenzene
ND
5.0
1.4
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
5.0
1.0
ug/kg
71-55-6
1, 1, 1 -Trichloroethane
ND
5.0
1.0
ug/kg
79-00-5
1,1,2-Trichloroethane
ND
5.0
1.0
ug/kg
79-01-6
Trichloroethylene
ND
5.0
1.0
ug/kg
75-69-4
Trichlorofluoromethane
ND
5.0
2.0
ug/kg
96-18-4
1, 2,3 -Trichloropropane
ND
5.0
1.3
ug/kg
95-63-6
1,2,4-Trimethylbenzene
ND
5.0
1.0
ug/kg
108-67-8
1,3,5-Trimethylbenzene
ND
5.0
1.0
ug/kg
108-05-4
Vinyl Acetate
ND
25
16
ug/kg
75-01-4
Vinyl Chloride
ND
5.0
1.0
ug/kg
m,p-Xylene
ND
10
1.1
ug/kg
95-47-6
o-Xylene
ND
5.0
1.0
ug/kg
1330-20-7
Xylene (total)
ND
15
2.1
ug/kg
CAS No.
Surrogate Recoveries
Limits
1868-53-7
Dibromofluoromethane
103%
75-124%
17060-07-0
1,2-Dichloroethane-D4
102%
72-135%
2037-26-5
Toluene-D8
100%
75-126%
01
121 of 177
FA75651

Method Blank Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 3 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
VF3374-MB
170095957.1)
1
06/10/20
SP
n/a
n/a
VF3374
The QC reported here applies to the following samples: Method: SW846 8260D
FA75651-1, FA75651-2, FA75651-3, FA75651-8, FA75651-9
CAS No. Surrogate Recoveries Limits
460-00-4 4-Bromofluorobenzene 104% 71-133%
6 122 of 177
FA75651

Blank Spike Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 1 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
VF3373-BS a
F0095928.D
1
06/09/20
SP
n/a
n/a
VF3373
The QC reported here applies to the following samples: Method: SW846 8260D
FA75651-4, FA75651-5, FA75651-6, FA75651-7, FA75651-10, FA75651-11, FA75651-12
Spike BSP BSP
CAS No. Compound ug/kg ug/kg % Limits
67-64-1
Acetone
250
279
112
61-152
71-43-2
Benzene
50
49.9
100
76-126
108-86-1
Bromobenzene
50
49.1
98
76-122
74-97-5
Bromochloromethane
50
49.9
100
77-120
75-27-4
Bromodichloromethane
50
51.7
103
74-130
75-25-2
Bromoform
50
50.0
100
76-127
78-93-3
2-Butanone (MEK)
250
267
107
75-137
104-51-8
n-Butylbenzene
50
48.9
98
71-128
135-98-8
sec-Butylbenzene
50
48.9
98
79-135
98-06-6
tert-Butylbenzene
50
46.8
94
77-133
56-23-5
Carbon Tetrachloride
50
46.9
94
78-133
108-90-7
Chlorobenzene
50
50.0
100
81-129
75-00-3
Chloroethane
50
47.3
95
68-133
67-66-3
Chloroform
50
46.7
93
72-123
95-49-8
o-Chlorotoluene
50
48.8
98
77-129
106-43-4
p-Chlorotoluene
50
49.4
99
80-134
124-48-1
Dibromochloromethane
50
49.5
99
76-127
106-93-4
1,2-Dibromoethane
50
49.5
99
77-126
75-71-8
Dichlorodifluoromethane
50
35.4
71
68-168
95-50-1
1,2-Dichlorobenzene
50
49.0
98
80-129
541-73-1
1,3-Dichlorobenzene
50
50.3
101
81-129
106-46-7
1,4-Dichlorobenzene
50
49.2
98
76-130
75-34-3
1, 1 -Dichloroethane
50
48.0
96
73-125
107-06-2
1,2-Dichloroethane
50
50.6
101
74-128
75-35-4
1, 1 -Dichloroethylene
50
43.1
86
81-136
156-59-2
cis- 1, 2-Dichloroethylene
50
47.9
96
74-126
156-60-5
trans- 1, 2-Dichloroethylene
50
45.7
91
70-127
78-87-5
1,2-Dichloropropane
50
50.8
102
74-125
142-28-9
1,3-Dichloropropane
50
48.5
97
76-122
594-20-7
2,2-Dichloropropane
50
43.8
88
77-133
563-58-6
1, 1 -Dichloropropene
50
49.4
99
75-130
10061-01-5 cis- 1, 3-Dichloropropene
50
53.5
107
80-123
10061-02-6 trans- 1, 3-Dichloropropene
50
51.4
103
75-131
108-20-3
Di -Isopropyl Ether
50
50.5
101
75-122
64-17-5
Ethyl Alcohol
1000
1000
100
53-154
100-41-4
Ethlbenzene
50
50.0
100
77-123
* = Outside of Control Limits.
6 123 of 177
FA75651

Blank Spike Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 2 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
VF3373-BS a
F0095928.D
1
06/09/20
SP
n/a
n/a
VF3373
The QC reported here applies to the following samples: Method: SW846 8260D
FA75651-4, FA75651-5, FA75651-6, FA75651-7, FA75651-10, FA75651-11, FA75651-12
Spike
BSP
BSP
CAS No.
Compound
ug/kg
ug/kg
%
Limits
591-78-6
2-Hexanone
250
260
104
72-133
98-82-8
Isopropylbenzene
50
50.7
101
80-136
99-87-6
p-Isopropyltoluene
50
49.9
100
77-131
74-83-9
Methyl Bromide
50
42.5
85
65-139
74-87-3
Methyl Chloride
50
39.6
79
71-144
75-09-2
Methylene Chloride
50
44.6
89
74-137
108-10-1
4-Methyl-2-pentanone (MIBK) 250
256
102
76-132
1634-04-4
Methyl Tert Butyl Ether
50
52.3
105
77-120
91-20-3
Naphthalene
50
49.5
99
79-129
103-65-1
n-Propylbenzene
50
49.1
98
80-135
100-42-5
Styrene
50
51.0
102
78-125
630-20-6
1, 1, 1, 2-Tetrachloroethane
50
49.7
99
78-126
79-34-5
1,1,2,2-Tetrachloroethane
50
49.7
99
71-126
127-18-4
Tetrachloroethylene
50
47.7
95
79-130
108-88-3
Toluene
50
47.4
95
76-124
87-61-6
1,2,3-Trichlorobenzene
50
51.3
103
77-128
120-82-1
1,2,4-Trichlorobenzene
50
51.2
102
78-130
71-55-6
1, 1, 1 -Trichloroethane
50
46.2
92
70-129
79-00-5
1,1,2-Trichloroethane
50
50.7
101
74-124
79-01-6
Trichloroethylene
50
49.4
99
75-128
75-69-4
Trichlorofluoromethane
50
47.2
94
73-145
96-18-4
1, 2,3 -Trichloropropane
50
45.1
90
74-127
95-63-6
1,2,4-Trimethylbenzene
50
47.9
96
74-123
108-67-8
1,3,5-Trimethylbenzene
50
49.8
100
73-122
108-05-4
Vinyl Acetate
250
291
116
48-164
75-01-4
Vinyl Chloride
50
43.2
86
76-141
m,p-Xylene
100
103
103
80-128
95-47-6
o-Xylene
50
50.2
100
80-132
1330-20-7
Xylene (total)
150
154
103
80-129
CAS No.
Surrogate Recoveries
BSP
Limits
1868-53-7
Dibromofluoromethane
101%
75-124%
17060-07-0
1,2-Dichloroethane-D4
105%
72-135%
2037-26-5
Toluene-D8
94%
75-126%
* = Outside of Control Limits.
6 124 of 177
FA75651

Blank Spike Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 3 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
VF3373-BS a
F0095928.D
1
06/09/20
SP
n/a
n/a
VF3373
The QC reported here applies to the following samples: Method: SW846 8260D
FA75651-4, FA75651-5, FA75651-6, FA75651-7, FA75651-10, FA75651-11, FA75651-12
CAS No. Surrogate Recoveries BSP
460-00-4 4-Bromofluorobenzene 97%
(a) No MS/MSD available for this run.
* = Outside of Control Limits.
Limits
71-133%
6 125 of 177
FA75651

Blank Spike Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 1 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
VF3374-BS
170095956.1)
1
06/10/20
SP
n/a
n/a
VF3374
The QC reported here applies to the following samples: Method: SW846 8260D
FA75651-1, FA75651-2, FA75651-3, FA75651-8, FA75651-9
CAS No. Compound
Spike BSP BSP
ug/kg ug/kg % Limits
67-64-1
Acetone
250
303
121
61-152
71-43-2
Benzene
50
51.5
103
76-126
108-86-1
Bromobenzene
50
47.6
95
76-122
74-97-5
Bromochloromethane
50
52.3
105
77-120
75-27-4
Bromodichloromethane
50
52.1
104
74-130
75-25-2
Bromoform
50
50.0
100
76-127
78-93-3
2-Butanone (MEK)
250
280
112
75-137
104-51-8
n-Butylbenzene
50
47.9
96
71-128
135-98-8
sec-Butylbenzene
50
48.4
97
79-135
98-06-6
tert-Butylbenzene
50
45.9
92
77-133
56-23-5
Carbon Tetrachloride
50
48.7
97
78-133
108-90-7
Chlorobenzene
50
51.2
102
81-129
75-00-3
Chloroethane
50
54.3
109
68-133
67-66-3
Chloroform
50
48.6
97
72-123
95-49-8
o-Chlorotoluene
50
49.6
99
77-129
106-43-4
p-Chlorotoluene
50
48.2
96
80-134
124-48-1
Dibromochloromethane
50
50.1
100
76-127
106-93-4
1,2-Dibromoethane
50
49.4
99
77-126
75-71-8
Dichlorodifluoromethane
50
34.7
69
68-168
95-50-1
1,2-Dichlorobenzene
50
46.7
93
80-129
541-73-1
1,3-Dichlorobenzene
50
47.9
96
81-129
106-46-7
1,4-Dichlorobenzene
50
48.8
98
76-130
75-34-3
1, 1 -Dichloroethane
50
49.4
99
73-125
107-06-2
1,2-Dichloroethane
50
51.7
103
74-128
75-35-4
1, 1 -Dichloroethylene
50
44.8
90
81-136
156-59-2
cis- 1, 2-Dichloroethylene
50
49.1
98
74-126
156-60-5
trans- 1, 2-Dichloroethylene
50
47.1
94
70-127
78-87-5
1,2-Dichloropropane
50
52.2
104
74-125
142-28-9
1,3-Dichloropropane
50
48.7
97
76-122
594-20-7
2,2-Dichloropropane
50
45.5
91
77-133
563-58-6
1, 1 -Dichloropropene
50
51.0
102
75-130
10061-01-5 cis- 1, 3-Dichloropropene
50
54.2
108
80-123
10061-02-6 trans- 1, 3-Dichloropropene
50
52.0
104
75-131
108-20-3
Di -Isopropyl Ether
50
51.0
102
75-122
64-17-5
Ethyl Alcohol
1000
1000
100
53-154
100-41-4
Ethlbenzene
50
52.3
105
77-123
* = Outside of Control Limits.
6 126 of 177
FA75651

Blank Spike Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 2 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
VF3374-BS
F0095956.D
1
06/10/20
SP
n/a
n/a
VF3374
The QC reported here applies to the following samples: Method: SW846 8260D
FA75651-1, FA75651-2, FA75651-3, FA75651-8, FA75651-9
CAS No. Compound
Spike BSP BSP
ug/kg ug/kg % Limits
591-78-6
2-Hexanone
250
274
110
72-133
98-82-8
Isopropylbenzene
50
51.2
102
80-136
99-87-6
p-Isopropyltoluene
50
49.0
98
77-131
74-83-9
Methyl Bromide
50
48.9
98
65-139
74-87-3
Methyl Chloride
50
40.8
82
71-144
75-09-2
Methylene Chloride
50
48.2
96
74-137
108-10-1
4-Methyl-2-pentanone (MIBK) 250
272
109
76-132
1634-04-4
Methyl Tert Butyl Ether
50
54.1
108
77-120
91-20-3
Naphthalene
50
47.9
96
79-129
103-65-1
n-Propylbenzene
50
49.1
98
80-135
100-42-5
Styrene
50
51.2
102
78-125
630-20-6
1, 1, 1, 2-Tetrachloroethane
50
49.8
100
78-126
79-34-5
1,1,2,2-Tetrachloroethane
50
49.4
99
71-126
127-18-4
Tetrachloroethylene
50
48.5
97
79-130
108-88-3
Toluene
50
48.7
97
76-124
87-61-6
1,2,3-Trichlorobenzene
50
46.9
94
77-128
120-82-1
1,2,4-Trichlorobenzene
50
47.9
96
78-130
71-55-6
1, 1, 1 -Trichloroethane
50
48.0
96
70-129
79-00-5
1,1,2-Trichloroethane
50
51.0
102
74-124
79-01-6
Trichloroethylene
50
52.4
105
75-128
75-69-4
Trichlorofluoromethane
50
54.0
108
73-145
96-18-4
1, 2,3 -Trichloropropane
50
46.0
92
74-127
95-63-6
1,2,4-Trimethylbenzene
50
48.1
96
74-123
108-67-8
1,3,5-Trimethylbenzene
50
50.1
100
73-122
108-05-4
Vinyl Acetate
250
278
111
48-164
75-01-4
Vinyl Chloride
50
44.7
89
76-141
m,p-Xylene
100
108
108
80-128
95-47-6
o-Xylene
50
50.6
101
80-132
1330-20-7
Xylene (total)
150
159
106
80-129
CAS No.
Surrogate Recoveries
BSP
Limits
1868-53-7
Dibromofluoromethane
103%
75-124%
17060-07-0
1,2-Dichloroethane-D4
106%
72-135%
2037-26-5
Toluene-D8
95%
75-126%
* = Outside of Control Limits.
6 127 of 177
FA75651

Blank Spike Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 3 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
VF3374-BS
170095956.1)
1
06/10/20
SP
n/a
n/a
VF3374
The QC reported here applies to the following samples: Method: SW846 8260D
FA75651-1, FA75651-2, FA75651-3, FA75651-8, FA75651-9
CAS No. Surrogate Recoveries BSP Limits
460-00-4 4-Bromofluorobenzene 94% 71-133%
* = Outside of Control Limits.
6 128 of 177
FA75651

Matrix Spike/Matrix Spike Duplicate Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 1 of 3
Sample
File ID DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
FA75651-4MS
170095971.1) 1
06/10/20
SP
n/a
n/a
VF3374
FA75651-4MSD
F0095972.D 1
06/10/20
SP
n/a
n/a
VF3374
FA75651-4 a
170095962.1) 1
06/10/20
SP
n/a
n/a
VF3374
The QC reported here applies to the following samples:
FA75651-1, FA75651-2, FA75651-3, FA75651-8, FA75651-9
CAS No. Compound
FA75651-4 Spike MS MS
ug/kg Q ug/kg ug/kg %
Method: SW846 8260D
Spike MSD MSD Limits
ug/kg ug/kg % RPD Rec/RPD
67-64-1
Acetone
ND
302
309
102
301
303
101
2
61-152/27
71-43-2
Benzene
ND
60.4
59.0
98
60.2
58.9
98
0
76-126/26
108-86-1
Bromobenzene
ND
60.4
62.8
104
60.2
60.0
100
5
76-122/32
74-97-5
Bromochloromethane
ND
60.4
57.5
95
60.2
56.9
94
1
77-120/24
75-27-4
Bromodichloromethane
ND
60.4
58.1
96
60.2
58.8
98
1
74-130/25
75-25-2
Bromoform
ND
60.4
49.6
82
60.2
48.4
80
2
76-127/26
78-93-3
2-Butanone (MEK)
ND
302
285
94
301
283
94
1
75-137/25
104-51-8
n-Butylbenzene
ND
60.4
44.7
74
60.2
45.8
76
2
71-128/35
135-98-8
sec-Butylbenzene
ND
60.4
55.0
91
60.2
56.7
94
3
79-135/34
98-06-6
tert-Butylbenzene
ND
60.4
58.6
97
60.2
58.4
97
0
77-133/34
56-23-5
Carbon Tetrachloride
ND
60.4
54.1
90
60.2
55.7
92
3
78-133/29
108-90-7
Chlorobenzene
ND
60.4
54.5
90
60.2
53.6
89
2
81-129/29
75-00-3
Chloroethane
ND
60.4
68.0
113
60.2
68.2
113
0
68-133/29
67-66-3
Chloroform
ND
60.4
56.8
94
60.2
57.3
95
1
72-123/26
95-49-8
o-Chlorotoluene
ND
60.4
66.1
110
60.2
64.6
107
2
77-129/33
106-43-4
p-Chlorotoluene
ND
60.4
61.7
102
60.2
59.8
99
3
80-134/33
124-48-1
Dibromochloromethane
ND
60.4
55.3
92
60.2
54.7
91
1
76-127/27
106-93-4
1,2-Dibromoethane
ND
60.4
52.4
87
60.2
51.5
85
2
77-126/26
75-71-8
Dichlorodifluoromethane
ND
60.4
41.2
68
60.2
41.3
69
0
68-168/29
95-50-1
1,2-Dichlorobenzene
ND
60.4
48.8
81
60.2
48.0
80
2
80-129/32
541-73-1
1,3-Dichlorobenzene
ND
60.4
53.3
88
60.2
51.6
86
3
81-129/33
106-46-7
1,4-Dichlorobenzene
ND
60.4
51.6
85
60.2
49.7
83
4
76-130/32
75-34-3
1, 1 -Dichloroethane
ND
60.4
57.7
96
60.2
58.4
97
1
73-125/27
107-06-2
1,2-Dichloroethane
ND
60.4
58.3
97
60.2
58.0
96
1
74-128/23
75-35-4
1, 1 -Dichloroethylene
ND
60.4
52.5
87
60.2
53.0
88
1
81-136/28
156-59-2
cis- 1, 2-Dichloroethylene
ND
60.4
54.2
90
60.2
54.7
91
1
74-126/26
156-60-5
trans- 1, 2-Dichloroethylene
ND
60.4
49.3
82
60.2
50.0
83
1
70-127/27
78-87-5
1,2-Dichloropropane
ND
60.4
59.2
98
60.2
59.8
99
1
74-125/25
142-28-9
1,3-Dichloropropane
ND
60.4
55.6
92
60.2
55.0
91
1
76-122/26
594-20-7
2,2-Dichloropropane
ND
60.4
56.0
93
60.2
56.6
94
1
77-133/28
563-58-6
1, 1 -Dichloropropene
ND
60.4
56.5
94
60.2
56.7
94
0
75-130/28
10061-01-5 cis- 1, 3-Dichloropropene
ND
60.4
52.3
87
60.2
50.4
84
4
80-123/26
10061-02-6 trans- 1, 3-Dichloropropene
ND
60.4
49.9
83
60.2
48.0
80
4
75-131/28
108-20-3
Di -Isopropyl Ether
ND
60.4
59.8
99
60.2
61.3
102
2
75-122/25
64-17-5
Ethyl Alcohol
ND
1210
2090
173*
1200
1890
157*
10
53-154/42
100-41-4
Ethylbenzene
ND
60.4
57.3
95
60.2
58.2
97
2
77-123/31
* = Outside of Control Limits.
6 129 of 177
FA75651

Matrix Spike/Matrix Spike Duplicate Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 2 of 3
Sample
File ID DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
FA75651-4MS
F0095971.D 1
06/10/20
SP
n/a
n/a
VF3374
FA75651-4MSD
F0095972.D 1
06/10/20
SP
n/a
n/a
VF3374
FA75651-4 a
F0095962.D 1
06/10/20
SP
n/a
n/a
VF3374
The QC reported here applies to the following samples:
FA75651-1, FA75651-2, FA75651-3, FA75651-8, FA75651-9
CAS No. Compound
591-78-6
98-82-8
99-87-6
74-83-9
74-87-3
75-09-2
108-10-1
1634-04-4
91-20-3
103-65-1
100-42-5
630-20-6
79-34-5
127-18-4
108-88-3
87-61-6
120-82-1
71-55-6
79-00-5
79-01-6
75-69-4
96-18-4
95-63-6
108-67-8
108-05-4
75-01-4
95-47-6
1330-20-7
CAS No.
FA75651-4 Spike MS MS
ug/kg Q ug/kg ug/kg %
Method: SW846 8260D
Spike MSD MSD Limits
ug/kg ug/kg % RPD Rec/RPD
2-Hexanone
ND
302
264
87
301
261
87
1
72-133/26
Isopropylbenzene
ND
60.4
52.6
87
60.2
54.3
90
3
80-136/32
p-Isopropyltoluene
ND
60.4
55.9
93
60.2
56.6
94
1
77-131/34
Methyl Bromide
ND
60.4
53.3
88
60.2
50.3
83
6
65-139/31
Methyl Chloride
ND
60.4
47.1
78
60.2
46.1
77
2
71-144/27
Methylene Chloride
ND
60.4
58.9
98
60.2
60.8
101
3
74-137/28
4-Methyl-2-pentanone (MIBK) ND
302
301
100
301
303
101
1
76-132/26
Methyl Tert Butyl Ether
ND
60.4
63.3
105
60.2
64.7
107
2
77-120/24
Naphthalene
ND
60.4
25.5
42*
60.2
25.0
41*
2
79-129/33
n-Propylbenzene
ND
60.4
65.6
109
60.2
65.4
109
0
80-135/33
Styrene
ND
60.4
50.5
84
60.2
49.4
82
2
78-125/30
1, 1, 1, 2-Tetrachloroethane
ND
60.4
57.8
96
60.2
59.2
98
2
78-126/27
1,1,2,2-Tetrachloroethane
ND
60.4
68.1
113
60.2
66.2
110
3
71-126/30
Tetrachloroethylene
ND
60.4
54.0
89
60.2
55.5
92
3
79-130/31
Toluene
ND
60.4
58.6
97
60.2
58.7
97
0
76-124/30
1,2,3-Trichlorobenzene
ND
60.4
20.0
33*
60.2
19.6
33*
2
77-128/35
1,2,4-Trichlorobenzene
ND
60.4
26.5
44*
60.2
25.7
43*
3
78-130/34
1, 1, 1 -Trichloroethane
ND
60.4
56.3
93
60.2
57.0
95
1
70-129/27
1,1,2-Trichloroethane
ND
60.4
58.6
97
60.2
59.3
98
1
74-124/28
Trichloroethylene
ND
60.4
55.0
91
60.2
55.4
92
1
75-128/27
Trichlorofluoromethane
ND
60.4
68.3
113
60.2
70.4
117
3
73-145/31
1, 2,3 -Trichloropropane
ND
60.4
67.6
112
60.2
65.2
108
4
74-127/27
1,2,4-Trimethylbenzene
ND
60.4
61.9
103
60.2
60.3
100
3
74-123/34
1, 3,5 -Trimethylbenzene
ND
60.4
65.4
108
60.2
65.3
108
0
73-122/33
Vinyl Acetate
ND
302
ND
0*
301
ND
0*
nc
48-164/37
Vinyl Chloride
ND
60.4
52.5
87
60.2
54.0
90
3
76-141/27
m,p-Xylene
ND
121
119
99
120
120
100
1
80-128/30
o-Xylene
ND
60.4
55.9
93
60.2
56.8
94
2
80-132/30
Xylene (total)
ND
181
175
97
181
177
98
1
80-129/30
Surrogate Recoveries MS
1868-53-7 Dibromofluoromethane 106%
17060-07-0 1,2-Dichloroethane-D4 104%
2037-26-5 Toluene-D8 101%
* = Outside of Control Limits.
MSD FA75651-4 Limits
104% 104% 75-124%
104% 101% 72-135%
101% 114% 75-126%
6 130 of 177
FA75651

Matrix Spike/Matrix Spike Duplicate Summary Page 3 of 3
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Sample
File ID DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
FA75651-4MS
170095971.1) 1
06/10/20
SP
n/a
n/a
VF3374
FA75651-4MSD
F0095972.D 1
06/10/20
SP
n/a
n/a
VF3374
FA75651-4 a
170095962.1) 1
06/10/20
SP
n/a
n/a
VF3374
The QC reported here applies to the following samples:
FA75651-1, FA75651-2, FA75651-3, FA75651-8, FA75651-9
CAS No. Surrogate Recoveries MS MSD FA75651-4 Limits
460-00-4 4-Bromofluorobenzene 120% 117% 141%* b 71-133%
(a) Confirmation run for surrogate recoveries.
(b) Outside control limits due to matrix interference. Confirmed by reanalysis.
* = Outside of Control Limits.
Method: SW846 8260D
6 131 of 177
FA75651

ffm
Orlando, FL
MS Semi-volatiles
QC Data Summaries
;ME
i
Section 6
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
0
6 132 of 177
FA75651

Method Blank Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 1 of 2
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
OP80524-MB
9I008910.1)
1
06/09/20
MV
06/08/20
OP80524
S9I332
The QC reported here applies to the following samples:
Method: SW846 8270E
FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6, FA75651-7, FA75651-8, FA75651-9,
FA75651-10, FA75651-11
CAS No. Compound
Result RL MDL Units Q
65-85-0
Benzoic Acid
ND
830
170
ug/kg
59-50-7
4-Chloro-3-methyl Phenol
ND
170
19
ug/kg
95-57-8
2-Chlorophenol
ND
170
20
ug/kg
120-83-2
2,4-Dichlorophenol
ND
170
19
ug/kg
105-67-9
2,4-Dimethylphenol
ND
170
44
ug/kg
51-28-5
2,4-Dinitrophenol
ND
830
170
ug/kg
534-52-1
4,6-Dinitro-o-cresol
ND
330
67
ug/kg
95-48-7
2-Methylphenol
ND
170
20
ug/kg
3&4-Methylphenol
ND
170
27
ug/kg
88-75-5
2-Nitrophenol
ND
170
18
ug/kg
100-02-7
4-Nitrophenol
ND
830
170
ug/kg
87-86-5
Pentachlorophenol
ND
830
170
ug/kg
108-95-2
Phenol
ND
170
17
ug/kg
88-06-2
2,4,6-Trichlorophenol
ND
170
19
ug/kg
83-32-9
Acenaphthene
ND
170
18
ug/kg
208-96-8
Acenaphthylene
ND
170
17
ug/kg
120-12-7
Anthracene
ND
170
19
ug/kg
56-55-3
Benzo(a)anthracene
ND
170
17
ug/kg
50-32-8
Benzo(a)pyrene
ND
170
20
ug/kg
205-99-2
Benzo(b)fluoranthene
ND
170
18
ug/kg
191-24-2
Benzo(g,h,i)perylene
ND
170
17
ug/kg
207-08-9
Benzo(k)fluoranthene
ND
170
22
ug/kg
100-51-6
Benzyl Alcohol
ND
170
17
ug/kg
101-55-3
4-Bromophenyl phenyl ether
ND
170
17
ug/kg
85-68-7
Butyl benzyl phthalate
ND
170
33
ug/kg
106-47-8
4-Chloroaniline
ND
170
42
ug/kg
111-91-1
bis(2-Chloroethoxy)methane
ND
170
17
ug/kg
111-44-4
bis(2-Chloroethyl)ether
ND
170
19
ug/kg
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
170
21
ug/kg
91-58-7
2-Chloronaphthalene
ND
170
17
ug/kg
7005-72-3
4-Chlorophenyl phenyl ether
ND
170
17
ug/kg
218-01-9
Chrysene
ND
170
17
ug/kg
53-70-3
Dibenzo(a,h)anthracene
ND
170
21
ug/kg
132-64-9
Dibenzofuran
ND
170
17
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
170
17
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
170
18
ug/kg
6 133 of 177
FA75651

Method Blank Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 2 of 2
ample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batcl
)P80524-MB
9I008910.1)
1
06/09/20
MV
06/08/20
OP80524
S9I332
The QC reported here applies to the following samples: Method: SW846 8270E
FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6, FA75651-7, FA75651-8, FA75651-9,
FA75651-10, FA75651-11
CAS No. Compound
106-46-7
1,4-Dichlorobenzene
91-94-1
3, 3'-Dichlorobenzidine
84-66-2
Diethyl Phthalate
131-11-3
Dimethyl Phthalate
117-84-0
Di-n-octyl Phthalate
84-74-2
Di-n-butyl Phthalate
122-66-7
1, 2-Diphenylhydrazine
117-81-7
bis(2-Ethylhexyl)phthalate
206-44-0
Fluoranthene
86-73-7
Fluorene
118-74-1
Hexachlorobenzene
87-68-3
Hexachlorobutadiene
77-47-4
Hexachlorocyclopentadiene
67-72-1
Hexachloroethane
193-39-5
Indeno(1,2,3-cd)pyrene
78-59-1
Isophorone
90-12-0
1-M ethylnaphthalene
91-57-6
2-Methylnaphthalene
91-20-3
Naphthalene
98-95-3
Nitrobenzene
621-64-7
N-Nitrosodi-n-propylamine
86-30-6
N-Nitrosodiphenylamine
85-01-8
Phenanthrene
129-00-0
Pyrene
120-82-1
1,2,4-Trichlorobenzene
CAS No. Surrogate Recoveries
367-12-4 2-Fluorophenol
4165-62-2 Phenol-d5
118-79-6 2,4,6-Tribromophenol
4165-60-0 Nitrobenzene-d5
321-60-8 2-Fluorobiphenyl
1718-51-0 Terphenyl-d14
Result
RL
MDL
Units Q
ND
170
22
ug/kg
ND
170
40
ug/kg
ND
330
33
ug/kg
ND
170
33
ug/kg
ND
170
33
ug/kg
ND
330
67
ug/kg
ND
170
17
ug/kg
ND
330
33
ug/kg
ND
170
17
ug/kg
ND
170
18
ug/kg
ND
170
17
ug/kg
ND
170
17
ug/kg
ND
170
33
ug/kg
ND
170
20
ug/kg
ND
170
20
ug/kg
ND
170
17
ug/kg
ND
170
17
ug/kg
ND
170
17
ug/kg
ND
170
17
ug/kg
ND
170
17
ug/kg
ND
170
17
ug/kg
ND
170
18
ug/kg
ND
170
17
ug/kg
ND
170
19
ug/kg
ND
170
20
ug/kg
Limits
50%
40-102%
67%
41-100%
46%
42-108%
55%
40-105%
56%
43-107%
60%
45-119%
01
134 of 177
FA75651

Method Blank Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 1 of 2
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
OP80524-MB
91008951.D
1
06/10/20
MV
06/08/20
OP80524
S9I333
The QC reported here applies to the following samples:
Method: SW846 8270E
FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6, FA75651-7, FA75651-8, FA75651-9,
FA75651-10, FA75651-11
CAS No. Compound
Result RL MDL Units Q
65-85-0
Benzoic Acid
ND
830
170
ug/kg
59-50-7
4-Chloro-3-methyl Phenol
ND
170
19
ug/kg
95-57-8
2-Chlorophenol
ND
170
20
ug/kg
120-83-2
2,4-Dichlorophenol
ND
170
19
ug/kg
105-67-9
2,4-Dimethylphenol
ND
170
44
ug/kg
51-28-5
2,4-Dinitrophenol
ND
830
170
ug/kg
534-52-1
4,6-Dinitro-o-cresol
ND
330
67
ug/kg
95-48-7
2-Methylphenol
ND
170
20
ug/kg
3&4-Methylphenol
ND
170
27
ug/kg
88-75-5
2-Nitrophenol
ND
170
18
ug/kg
100-02-7
4-Nitrophenol
ND
830
170
ug/kg
87-86-5
Pentachlorophenol
ND
830
170
ug/kg
108-95-2
Phenol
ND
170
17
ug/kg
88-06-2
2,4,6-Trichlorophenol
ND
170
19
ug/kg
83-32-9
Acenaphthene
ND
170
18
ug/kg
208-96-8
Acenaphthylene
ND
170
17
ug/kg
120-12-7
Anthracene
ND
170
19
ug/kg
56-55-3
Benzo(a)anthracene
ND
170
17
ug/kg
50-32-8
Benzo(a)pyrene
ND
170
20
ug/kg
205-99-2
Benzo(b)fluoranthene
ND
170
18
ug/kg
191-24-2
Benzo(g,h,i)perylene
ND
170
17
ug/kg
207-08-9
Benzo(k)fluoranthene
ND
170
22
ug/kg
100-51-6
Benzyl Alcohol
ND
170
17
ug/kg
101-55-3
4-Bromophenyl phenyl ether
ND
170
17
ug/kg
85-68-7
Butyl benzyl phthalate
ND
170
33
ug/kg
106-47-8
4-Chloroaniline
ND
170
42
ug/kg
111-91-1
bis(2-Chloroethoxy)methane
ND
170
17
ug/kg
111-44-4
bis(2-Chloroethyl)ether
ND
170
19
ug/kg
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
170
21
ug/kg
91-58-7
2-Chloronaphthalene
ND
170
17
ug/kg
7005-72-3
4-Chlorophenyl phenyl ether
ND
170
17
ug/kg
218-01-9
Chrysene
ND
170
17
ug/kg
53-70-3
Dibenzo(a,h)anthracene
ND
170
21
ug/kg
132-64-9
Dibenzofuran
ND
170
17
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
170
17
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
170
18
ug/kg
6 135 of 177
FA75651

Method Blank Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 2 of 2
ample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batcl
)P80524-MB
91008951.D
1
06/10/20
MV
06/08/20
OP80524
S9I333
The QC reported here applies to the following samples: Method: SW846 8270E
FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6, FA75651-7, FA75651-8, FA75651-9,
FA75651-10, FA75651-11
CAS No. Compound
106-46-7
1,4-Dichlorobenzene
91-94-1
3, 3'-Dichlorobenzidine
84-66-2
Diethyl Phthalate
131-11-3
Dimethyl Phthalate
117-84-0
Di-n-octyl Phthalate
84-74-2
Di-n-butyl Phthalate
122-66-7
1, 2-Diphenylhydrazine
117-81-7
bis(2-Ethylhexyl)phthalate
206-44-0
Fluoranthene
86-73-7
Fluorene
118-74-1
Hexachlorobenzene
87-68-3
Hexachlorobutadiene
77-47-4
Hexachlorocyclopentadiene
67-72-1
Hexachloroethane
193-39-5
Indeno(1,2,3-cd)pyrene
78-59-1
Isophorone
90-12-0
1-M ethylnaphthalene
91-57-6
2-Methylnaphthalene
91-20-3
Naphthalene
98-95-3
Nitrobenzene
621-64-7
N-Nitrosodi-n-propylamine
86-30-6
N-Nitrosodiphenylamine
85-01-8
Phenanthrene
129-00-0
Pyrene
120-82-1
1,2,4-Trichlorobenzene
CAS No. Surrogate Recoveries
367-12-4 2-Fluorophenol
4165-62-2 Phenol-d5
118-79-6 2,4,6-Tribromophenol
4165-60-0 Nitrobenzene-d5
321-60-8 2-Fluorobiphenyl
1718-51-0 Terphenyl-d14
Result
RL
MDL
Units Q
ND
170
22
ug/kg
ND
170
40
ug/kg
ND
330
33
ug/kg
ND
170
33
ug/kg
ND
170
33
ug/kg
ND
330
67
ug/kg
ND
170
17
ug/kg
ND
330
33
ug/kg
ND
170
17
ug/kg
ND
170
18
ug/kg
ND
170
17
ug/kg
ND
170
17
ug/kg
ND
170
33
ug/kg
ND
170
20
ug/kg
ND
170
20
ug/kg
ND
170
17
ug/kg
ND
170
17
ug/kg
ND
170
17
ug/kg
ND
170
17
ug/kg
ND
170
17
ug/kg
ND
170
17
ug/kg
ND
170
18
ug/kg
ND
170
17
ug/kg
ND
170
19
ug/kg
ND
170
20
ug/kg
Limits
48%
40-102%
64%
41-100%
60%
42-108%
48%
40-105%
55%
43-107%
58%
45-119%
01
136 of 177
FA75651

Method Blank Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 1 of 2
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
OP80524-MB
91009009.D
1
06/12/20
MV
06/08/20
OP80524
S9I334
The QC reported here applies to the following samples:
Method: SW846 8270E
FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6, FA75651-7, FA75651-8, FA75651-9,
FA75651-10, FA75651-11
CAS No. Compound
Result RL MDL Units Q
65-85-0
Benzoic Acid
ND
830
170
ug/kg
59-50-7
4-Chloro-3-methyl Phenol
ND
170
19
ug/kg
95-57-8
2-Chlorophenol
ND
170
20
ug/kg
120-83-2
2,4-Dichlorophenol
ND
170
19
ug/kg
105-67-9
2,4-Dimethylphenol
ND
170
44
ug/kg
51-28-5
2,4-Dinitrophenol
ND
830
170
ug/kg
534-52-1
4,6-Dinitro-o-cresol
ND
330
67
ug/kg
95-48-7
2-Methylphenol
ND
170
20
ug/kg
3&4-Methylphenol
ND
170
27
ug/kg
88-75-5
2-Nitrophenol
ND
170
18
ug/kg
100-02-7
4-Nitrophenol
ND
830
170
ug/kg
87-86-5
Pentachlorophenol
ND
830
170
ug/kg
108-95-2
Phenol
ND
170
17
ug/kg
88-06-2
2,4,6-Trichlorophenol
ND
170
19
ug/kg
83-32-9
Acenaphthene
ND
170
18
ug/kg
208-96-8
Acenaphthylene
ND
170
17
ug/kg
120-12-7
Anthracene
ND
170
19
ug/kg
56-55-3
Benzo(a)anthracene
ND
170
17
ug/kg
50-32-8
Benzo(a)pyrene
ND
170
20
ug/kg
205-99-2
Benzo(b)fluoranthene
ND
170
18
ug/kg
191-24-2
Benzo(g,h,i)perylene
ND
170
17
ug/kg
207-08-9
Benzo(k)fluoranthene
ND
170
22
ug/kg
100-51-6
Benzyl Alcohol
ND
170
17
ug/kg
101-55-3
4-Bromophenyl phenyl ether
ND
170
17
ug/kg
85-68-7
Butyl benzyl phthalate
ND
170
33
ug/kg
106-47-8
4-Chloroaniline
ND
170
42
ug/kg
111-91-1
bis(2-Chloroethoxy)methane
ND
170
17
ug/kg
111-44-4
bis(2-Chloroethyl)ether
ND
170
19
ug/kg
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
170
21
ug/kg
91-58-7
2-Chloronaphthalene
ND
170
17
ug/kg
7005-72-3
4-Chlorophenyl phenyl ether
ND
170
17
ug/kg
218-01-9
Chrysene
ND
170
17
ug/kg
53-70-3
Dibenzo(a,h)anthracene
ND
170
21
ug/kg
132-64-9
Dibenzofuran
ND
170
17
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
170
17
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
170
18
ug/kg
6 137 of 177
FA75651

Method Blank Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 2 of 2
ample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batcl
)P80524-MB
91009009.D
1
06/12/20
MV
06/08/20
OP80524
S9I334
The QC reported here applies to the following samples: Method: SW846 8270E
FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6, FA75651-7, FA75651-8, FA75651-9,
FA75651-10, FA75651-11
CAS No. Compound
106-46-7
1,4-Dichlorobenzene
91-94-1
3, 3'-Dichlorobenzidine
84-66-2
Diethyl Phthalate
131-11-3
Dimethyl Phthalate
117-84-0
Di-n-octyl Phthalate
84-74-2
Di-n-butyl Phthalate
122-66-7
1, 2-Diphenylhydrazine
117-81-7
bis(2-Ethylhexyl)phthalate
206-44-0
Fluoranthene
86-73-7
Fluorene
118-74-1
Hexachlorobenzene
87-68-3
Hexachlorobutadiene
77-47-4
Hexachlorocyclopentadiene
67-72-1
Hexachloroethane
193-39-5
Indeno(1,2,3-cd)pyrene
78-59-1
Isophorone
90-12-0
1-M ethylnaphthalene
91-57-6
2-Methylnaphthalene
91-20-3
Naphthalene
98-95-3
Nitrobenzene
621-64-7
N-Nitrosodi-n-propylamine
86-30-6
N-Nitrosodiphenylamine
85-01-8
Phenanthrene
129-00-0
Pyrene
120-82-1
1,2,4-Trichlorobenzene
CAS No. Surrogate Recoveries
367-12-4 2-Fluorophenol
4165-62-2 Phenol-d5
118-79-6 2,4,6-Tribromophenol
4165-60-0 Nitrobenzene-d5
321-60-8 2-Fluorobiphenyl
1718-51-0 Terphenyl-d14
Result
RL
MDL
Units Q
ND
170
22
ug/kg
ND
170
40
ug/kg
ND
330
33
ug/kg
ND
170
33
ug/kg
ND
170
33
ug/kg
ND
330
67
ug/kg
ND
170
17
ug/kg
ND
330
33
ug/kg
ND
170
17
ug/kg
ND
170
18
ug/kg
ND
170
17
ug/kg
ND
170
17
ug/kg
ND
170
33
ug/kg
ND
170
20
ug/kg
ND
170
20
ug/kg
ND
170
17
ug/kg
ND
170
17
ug/kg
ND
170
17
ug/kg
ND
170
17
ug/kg
ND
170
17
ug/kg
ND
170
17
ug/kg
ND
170
18
ug/kg
ND
170
17
ug/kg
ND
170
19
ug/kg
ND
170
20
ug/kg
Limits
58%
40-102%
65%
41-100%
65%
42-108%
58%
40-105%
60%
43-107%
75%
45-119%
01
138 of 177
FA75651

Blank Spike Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 1 of 2
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
OP80524-BS
91008909.D
1
06/09/20
MV
06/08/20
OP80524
S9I332
The QC reported here applies to the following samples:
Method: SW846 8270E
FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6, FA75651-7, FA75651-8, FA75651-9,
FA75651-10, FA75651-11
Spike
BSP
BSP
CAS No.
Compound
ug/kg
ug/kg
%
Limits
65-85-0
Benzoic Acid
3330
2230
67
36-118
59-50-7
4-Chloro-3-methyl Phenol
1670
1080
65
52-108
95-57-8
2-Chlorophenol
1670
1050
63
48-104
120-83-2
2,4-Dichlorophenol
1670
1190
71
51-105
105-67-9
2,4-Dimethylphenol
1670
1090
65
43-96
51-28-5
2,4-Dinitrophenol
3330
2480
74
40-119
534-52-1
4,6-Dinitro-o-cresol
3330
2460
74
64-121
95-48-7
2-Methylphenol
1670
1030
62
46-107
3&4-Methylphenol
3330
2160
65
44-111
88-75-5
2-Nitrophenol
1670
1100
66
49-104
100-02-7
4-Nitrophenol
3330
2310
69
56-116
87-86-5
Pentachlorophenol
3330
2460
74
61-114
108-95-2
Phenol
1670
1060
64
45-110
88-06-2
2,4,6-Trichlorophenol
1670
924
55*
56-109
83-32-9
Acenaphthene
1670
1110
67
56-109
208-96-8
Acenaphthylene
1670
1150
69
56-106
120-12-7
Anthracene
1670
1150
69
61-110
56-55-3
Benzo(a)anthracene
1670
1180
71
66-111
50-32-8
Benzo(a)pyrene
1670
1220
73
59-104
205-99-2
Benzo(b)fluoranthene
1670
1310
79
67-113
191-24-2
Benzo(g,h,i)perylene
1670
1390
83
67-113
207-08-9
Benzo(k)fluoranthene
1670
1260
76
67-114
100-51-6
Benzyl Alcohol
1670
1050
63
53-108
101-55-3
4-Bromophenyl phenyl ether
1670
1200
72
62-110
85-68-7
Butyl benzyl phthalate
1670
1230
74
65-113
106-47-8
4-Chloroaniline
1670
996
60
30-115
111-91-1
bis(2-Chloroethoxy)methane
1670
1070
64
48-105
111-44-4
bis(2-Chloroethyl)ether
1670
997
60
46-103
108-60-1
2,2'-Oxybis(1-chloropropane)
1670
988
59
40-110
91-58-7
2-Chloronaphthalene
1670
1040
62
53-106
7005-72-3
4-Chlorophenyl phenyl ether
1670
1180
71
58-106
218-01-9
Chrysene
1670
1150
69
65-112
53-70-3
Dibenzo(a,h)anthracene
1670
1370
82
68-115
132-64-9
Dibenzofuran
1670
1120
67
57-108
95-50-1
1,2-Dichlorobenzene
1670
1040
62
44-102
541-73-1
1,3-Dichlorobenzene
1670
1030
62
42-100
* = Outside of Control Limits.
6 139 of 177
FA75651

Blank Spike Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 2 of 2
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
OP80524-BS
91008909.D
1
06/09/20
MV
06/08/20
OP80524
S9I332
The QC reported here applies to the following samples:
Method: SW846 8270E
FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6, FA75651-7, FA75651-8, FA75651-9,
FA75651-10, FA75651-11
Spike BSP BSP
CAS No. Compound ug/kg ug/kg % Limits
106-46-7
1,4-Dichlorobenzene
1670
1020
61
40-106
91-94-1
3,3'-Dichlorobenzidine
1670
1070
64
36-114
84-66-2
Diethyl Phthalate
1670
1200
72
61-109
131-11-3
Dimethyl Phthalate
1670
1130
68
59-108
117-84-0
Di-n-octyl Phthalate
1670
1300
78
64-119
84-74-2
Di-n-butyl Phthalate
1670
1280
77
63-108
122-66-7
1,2-Diphenylhydrazine
1670
1040
62
58-112
117-81-7
bis(2-Ethylhexyl)phthalate
1670
1350
81
64-115
206-44-0
Fluoranthene
1670
1190
71
60-108
86-73-7
Fluorene
1670
1180
71
58-109
118-74-1
Hexachlorobenzene
1670
1150
69
59-111
87-68-3
Hexachlorobutadiene
1670
1100
66
41-108
77-47-4
Hexachlorocyclopentadiene
1670
911
55
49-110
67-72-1
Hexachloroethane
1670
1010
61
40-105
193-39-5
Indeno(1,2,3-cd)pyrene
1670
1380
83
66-116
78-59-1
Isophorone
1670
1030
62
42-89
90-12-0
1-Methylnaphthalene
1670
1010
61
49-106
91-57-6
2-Methylnaphthalene
1670
1020
61
47-106
91-20-3
Naphthalene
1670
1050
63
44-104
98-95-3
Nitrobenzene
1670
1060
64
43-108
621-64-7
N-Nitrosodi-n-propylamine
1670
1030
62
48-108
86-30-6
N-Nitrosodiphenylamine
1670
1140
68
62-110
85-01-8
Phenanthrene
1670
1160
70
63-111
129-00-0
Pyrene
1670
1200
72
65-115
120-82-1
1,2,4-Trichlorobenzene
1670
1090
65
45-100
CAS No.
Surrogate Recoveries
BSP
Limits
367-12-4
2-Fluorophenol
60%
40-102%
4165-62-2
Phenol-d5
71%
41-100%
118-79-6
2,4,6-Tribromophenol
69%
42-108%
4165-60-0
Nitrobenzene-d5
59%
40-105%
321-60-8
2-Fluorobiphenyl
52%
43-107%
1718-51-0
Terphenyl-d14
54%
45-119%
* = Outside of Control Limits.
6 140 of 177
FA75651

Blank Spike Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 1 of 2
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
OP80524-BS
9I008950.1)
1
06/10/20
MV
06/08/20
OP80524
S9I333
The QC reported here applies to the following samples:
Method: SW846 8270E
FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6, FA75651-7, FA75651-8, FA75651-9,
FA75651-10, FA75651-11
Spike
BSP
BSP
CAS No.
Compound
ug/kg
ug/kg
%
Limits
65-85-0
Benzoic Acid
3330
2090
63
36-118
59-50-7
4-Chloro-3-methyl Phenol
1670
1080
65
52-108
95-57-8
2-Chlorophenol
1670
1010
61
48-104
120-83-2
2,4-Dichlorophenol
1670
1130
68
51-105
105-67-9
2,4-Dimethylphenol
1670
1020
61
43-96
51-28-5
2,4-Dinitrophenol
3330
2440
73
40-119
534-52-1
4,6-Dinitro-o-cresol
3330
2350
71
64-121
95-48-7
2-Methylphenol
1670
1050
63
46-107
3&4-Methylphenol
3330
2240
67
44-111
88-75-5
2-Nitrophenol
1670
1010
61
49-104
100-02-7
4-Nitrophenol
3330
2630
79
56-116
87-86-5
Pentachlorophenol
3330
2370
71
61-114
108-95-2
Phenol
1670
1040
62
45-110
88-06-2
2,4,6-Trichlorophenol
1670
1110
67
56-109
83-32-9
Acenaphthene
1670
1150
69
56-109
208-96-8
Acenaphthylene
1670
1180
71
56-106
120-12-7
Anthracene
1670
1180
71
61-110
56-55-3
Benzo(a)anthracene
1670
1200
72
66-111
50-32-8
Benzo(a)pyrene
1670
1260
76
59-104
205-99-2
Benzo(b)fluoranthene
1670
1310
79
67-113
191-24-2
Benzo(g,h,i)perylene
1670
1290
77
67-113
207-08-9
Benzo(k)fluoranthene
1670
1290
77
67-114
100-51-6
Benzyl Alcohol
1670
1050
63
53-108
101-55-3
4-Bromophenyl phenyl ether
1670
1090
65
62-110
85-68-7
Butyl benzyl phthalate
1670
1200
72
65-113
106-47-8
4-Chloroaniline
1670
989
59
30-115
111-91-1
bis(2-Chloroethoxy)methane
1670
993
60
48-105
111-44-4
bis(2-Chloroethyl)ether
1670
924
55
46-103
108-60-1
2,2'-Oxybis(1-chloropropane)
1670
963
58
40-110
91-58-7
2-Chloronaphthalene
1670
1130
68
53-106
7005-72-3
4-Chlorophenyl phenyl ether
1670
1170
70
58-106
218-01-9
Chrysene
1670
1130
68
65-112
53-70-3
Dibenzo(a,h)anthracene
1670
1280
77
68-115
132-64-9
Dibenzofuran
1670
1200
72
57-108
95-50-1
1,2-Dichlorobenzene
1670
1050
63
44-102
541-73-1
1,3-Dichlorobenzene
1670
1010
61
42-100
* = Outside of Control Limits.
6 141 of 177
FA75651

Blank Spike Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 2 of 2
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
OP80524-BS
9I008950.1)
1
06/10/20
MV
06/08/20
OP80524
S9I333
The QC reported here applies to the following samples:
Method: SW846 8270E
FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6, FA75651-7, FA75651-8, FA75651-9,
FA75651-10, FA75651-11
Spike BSP BSP
CAS No. Compound ug/kg ug/kg % Limits
106-46-7
1,4-Dichlorobenzene
1670
1020
61
40-106
91-94-1
3,3'-Dichlorobenzidine
1670
1140
68
36-114
84-66-2
Diethyl Phthalate
1670
1200
72
61-109
131-11-3
Dimethyl Phthalate
1670
1130
68
59-108
117-84-0
Di-n-octyl Phthalate
1670
1460
88
64-119
84-74-2
Di-n-butyl Phthalate
1670
1330
80
63-108
122-66-7
1,2-Diphenylhydrazine
1670
1130
68
58-112
117-81-7
bis(2-Ethylhexyl)phthalate
1670
1300
78
64-115
206-44-0
Fluoranthene
1670
1250
75
60-108
86-73-7
Fluorene
1670
1230
74
58-109
118-74-1
Hexachlorobenzene
1670
1050
63
59-111
87-68-3
Hexachlorobutadiene
1670
1040
62
41-108
77-47-4
Hexachlorocyclopentadiene
1670
916
55
49-110
67-72-1
Hexachloroethane
1670
1080
65
40-105
193-39-5
Indeno(1,2,3-cd)pyrene
1670
1330
80
66-116
78-59-1
Isophorone
1670
936
56
42-89
90-12-0
1-Methylnaphthalene
1670
1110
67
49-106
91-57-6
2-Methylnaphthalene
1670
1100
66
47-106
91-20-3
Naphthalene
1670
1050
63
44-104
98-95-3
Nitrobenzene
1670
963
58
43-108
621-64-7
N-Nitrosodi-n-propylamine
1670
983
59
48-108
86-30-6
N-Nitrosodiphenylamine
1670
1100
66
62-110
85-01-8
Phenanthrene
1670
1210
73
63-111
129-00-0
Pyrene
1670
1040
62*
65-115
120-82-1
1,2,4-Trichlorobenzene
1670
1070
64
45-100
CAS No.
Surrogate Recoveries
BSP
Limits
367-12-4
2-Fluorophenol
58%
40-102%
4165-62-2
Phenol-d5
77%
41-100%
118-79-6
2,4,6-Tribromophenol
65%
42-108%
4165-60-0
Nitrobenzene-d5
55%
40-105%
321-60-8
2-Fluorobiphenyl
61%
43-107%
1718-51-0
Terphenyl-d14
52%
45-119%
* = Outside of Control Limits.
6 142 of 177
FA75651

Blank Spike Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 1 of 2
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
OP80524-BS
91009008.D
1
06/12/20
MV
06/08/20
OP80524
S9I334
The QC reported here applies to the following samples:
Method: SW846 8270E
FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6, FA75651-7, FA75651-8, FA75651-9,
FA75651-10, FA75651-11
Spike
BSP
BSP
CAS No.
Compound
ug/kg
ug/kg
%
Limits
65-85-0
Benzoic Acid
3330
2440
73
36-118
59-50-7
4-Chloro-3-methyl Phenol
1670
1180
71
52-108
95-57-8
2-Chlorophenol
1670
1100
66
48-104
120-83-2
2,4-Dichlorophenol
1670
1140
68
51-105
105-67-9
2,4-Dimethylphenol
1670
1110
67
43-96
51-28-5
2,4-Dinitrophenol
3330
2500
75
40-119
534-52-1
4,6-Dinitro-o-cresol
3330
2520
76
64-121
95-48-7
2-Methylphenol
1670
1160
70
46-107
3&4-Methylphenol
3330
2180
65
44-111
88-75-5
2-Nitrophenol
1670
1110
67
49-104
100-02-7
4-Nitrophenol
3330
2330
70
56-116
87-86-5
Pentachlorophenol
3330
2650
80
61-114
108-95-2
Phenol
1670
1330
80
45-110
88-06-2
2,4,6-Trichlorophenol
1670
1220
73
56-109
83-32-9
Acenaphthene
1670
1160
70
56-109
208-96-8
Acenaphthylene
1670
1180
71
56-106
120-12-7
Anthracene
1670
1170
70
61-110
56-55-3
Benzo(a)anthracene
1670
1280
77
66-111
50-32-8
Benzo(a)pyrene
1670
1300
78
59-104
205-99-2
Benzo(b)fluoranthene
1670
1300
78
67-113
191-24-2
Benzo(g,h,i)perylene
1670
1280
77
67-113
207-08-9
Benzo(k)fluoranthene
1670
1270
76
67-114
100-51-6
Benzyl Alcohol
1670
1200
72
53-108
101-55-3
4-Bromophenyl phenyl ether
1670
1280
77
62-110
85-68-7
Butyl benzyl phthalate
1670
1430
86
65-113
106-47-8
4-Chloroaniline
1670
1040
62
30-115
111-91-1
bis(2-Chloroethoxy)methane
1670
1200
72
48-105
111-44-4
bis(2-Chloroethyl)ether
1670
1120
67
46-103
108-60-1
2,2'-Oxybis(1-chloropropane)
1670
1280
77
40-110
91-58-7
2-Chloronaphthalene
1670
1160
70
53-106
7005-72-3
4-Chlorophenyl phenyl ether
1670
1170
70
58-106
218-01-9
Chrysene
1670
1320
79
65-112
53-70-3
Dibenzo(a,h)anthracene
1670
1340
80
68-115
132-64-9
Dibenzofuran
1670
1170
70
57-108
95-50-1
1,2-Dichlorobenzene
1670
1130
68
44-102
541-73-1
1,3-Dichlorobenzene
1670
1060
64
42-100
* = Outside of Control Limits.
6 143 of 177
FA75651

Blank Spike Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 2 of 2
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
OP80524-BS
91009008.D
1
06/12/20
MV
06/08/20
OP80524
S9I334
The QC reported here applies to the following samples:
Method: SW846 8270E
FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6, FA75651-7, FA75651-8, FA75651-9,
FA75651-10, FA75651-11
Spike BSP BSP
CAS No. Compound ug/kg ug/kg % Limits
106-46-7
1,4-Dichlorobenzene
1670
1040
62
40-106
91-94-1
3,3'-Dichlorobenzidine
1670
1100
66
36-114
84-66-2
Diethyl Phthalate
1670
1250
75
61-109
131-11-3
Dimethyl Phthalate
1670
1220
73
59-108
117-84-0
Di-n-octyl Phthalate
1670
1430
86
64-119
84-74-2
Di-n-butyl Phthalate
1670
1320
79
63-108
122-66-7
1,2-Diphenylhydrazine
1670
1240
74
58-112
117-81-7
bis(2-Ethylhexyl)phthalate
1670
1440
86
64-115
206-44-0
Fluoranthene
1670
1240
74
60-108
86-73-7
Fluorene
1670
1170
70
58-109
118-74-1
Hexachlorobenzene
1670
1160
70
59-111
87-68-3
Hexachlorobutadiene
1670
1100
66
41-108
77-47-4
Hexachlorocyclopentadiene
1670
1040
62
49-110
67-72-1
Hexachloroethane
1670
1040
62
40-105
193-39-5
Indeno(1,2,3-cd)pyrene
1670
1340
80
66-116
78-59-1
Isophorone
1670
1130
68
42-89
90-12-0
1-Methylnaphthalene
1670
1060
64
49-106
91-57-6
2-Methylnaphthalene
1670
1080
65
47-106
91-20-3
Naphthalene
1670
1080
65
44-104
98-95-3
Nitrobenzene
1670
1150
69
43-108
621-64-7
N-Nitrosodi-n-propylamine
1670
1210
73
48-108
86-30-6
N-Nitrosodiphenylamine
1670
1300
78
62-110
85-01-8
Phenanthrene
1670
1220
73
63-111
129-00-0
Pyrene
1670
1340
80
65-115
120-82-1
1,2,4-Trichlorobenzene
1670
1090
65
45-100
CAS No.
Surrogate Recoveries
BSP
Limits
367-12-4
2-Fluorophenol
69%
40-102%
4165-62-2
Phenol-d5
74%
41-100%
118-79-6
2,4,6-Tribromophenol
70%
42-108%
4165-60-0
Nitrobenzene-d5
68%
40-105%
321-60-8
2-Fluorobiphenyl
66%
43-107%
1718-51-0
Terphenyl-d14
70%
45-119%
* = Outside of Control Limits.
6 144 of 177
FA75651

Matrix Spike/Matrix Spike Duplicate Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 1 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
OP80524-MS
91008923.D
1
06/09/20
MV
06/08/20
OP80524
S9I332
OP80524-MSD
91008924.D
1
06/09/20
MV
06/08/20
OP80524
S9I332
FA75651-6 a
6F06187.D
10
06/23/20
MV
06/08/20
OP80524
S6F240
The QC reported here applies to the following samples:
Method: SW846 8270E
FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6, FA75651-7, FA75651-8, FA75651-9,
FA75651-10, FA75651-11
FA75651-6
Spike
MS
MS
Spike
MSD
MSD
Limits
CAS No.
Compound
ug/kg Q
ug/kg
ug/kg
%
ug/kg
ug/kg
%
RPD
Rec/RPD
65-85-0
Benzoic Acid
ND
3800
745
20*
3820
696
18*
7
36-118/41
59-50-7
4-Chloro-3-methyl Phenol
ND
1900
1170
62
1910
1210
63
3
52-108/21
95-57-8
2-Chlorophenol
ND
1900
1030
54
1910
1070
56
4
48-104/26
120-83-2
2,4-Dichlorophenol
ND
1900
1140
60
1910
1170
61
3
51-105/27
105-67-9
2,4-Dimethylphenol
ND
1900
1100
58
1910
1120
59
2
43-96/23
51-28-5
2,4-Dinitrophenol
ND
3800
696
18*
3820
515
13*
30
40-119/32
534-52-1
4,6-Dinitro-o-cresol
ND
3800
1100
29*
3820
879
23*
22
64-121/29
95-48-7
2-Methylphenol
ND
1900
1140
60
1910
1140
60
0
46-107/24
3&4-Methylphenol
ND
3800
2380
63
3820
2460
64
3
44-111/24
88-75-5
2-Nitrophenol
ND
1900
996
52
1910
996
52
0
49-104/27
100-02-7
4-Nitrophenol
ND
3800
2810
74
3820
2920
76
4
56-116/23
87-86-5
Pentachlorophenol
ND
3800
2170
57*
3820
2170
57*
0
61-114/23
108-95-2
Phenol
ND
1900
1120
59
1910
1150
60
3
45-110/24
88-06-2
2,4,6-Trichlorophenol
ND
1900
1150
61
1910
1180
62
3
56-109/25
83-32-9
Acenaphthene
ND
1900
1250
66
1910
1240
65
1
56-109/23
208-96-8
Acenaphthylene
ND
1900
1270
67
1910
1310
69
3
56-106/23
120-12-7
Anthracene
ND
1900
1390
73
1910
1350
71
3
61-110/21
56-55-3
Benzo(a)anthracene
225 J
1900
1530
70
1910
1510
68
1
66-111/23
50-32-8
Benzo(a)pyrene
ND
1900
1620
74
1910
1590
72
2
59-104/23
205-99-2
Benzo(b)fluoranthene
263 J
1900
1840
81
1910
1760
77
4
67-113/24
191-24-2
Benzo(g, h, i)perylene
ND
1900
1510
71
1910
1540
72
2
67-113/21
207-08-9
Benzo(k)fluoranthene
ND
1900
1480
78
1910
1510
79
2
67-114/22
100-51-6
Benzyl Alcohol
ND
1900
1120
59
1910
1150
60
3
53-108/24
101-55-3
4-Bromophenyl phenyl ether
ND
1900
1170
62
1910
1150
60*
2
62-110/21
85-68-7
Butyl benzyl phthalate
ND
1900
1430
75
1910
1540
81
7
65-113/20
106-47-8
4-Chloroaniline
ND
1900
1050
55
1910
1080
57
3
30-115/30
111-91-1
bis(2-Chloroethoxy)methane
ND
1900
1050
55
1910
1060
55
1
48-105/24
111-44-4
bis(2-Chloroethyl)ether
ND
1900
957
50
1910
1010
53
5
46-103/27
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
1900
1120
59
1910
1180
62
5
40-110/25
91-58-7
2-Chloronaphthalene
ND
1900
1170
62
1910
1190
62
2
53-106/23
7005-72-3
4-Chlorophenyl phenyl ether
ND
1900
1220
64
1910
1230
64
1
58-106/21
218-01-9
Chrysene
ND
1900
1490
66
1910
1450
64*
3
65-112/25
53-70-3
Dibenzo(a,h)anthracene
ND
1900
1460
77
1910
1500
78
3
68-115/23
132-64-9
Dibenzofuran
ND
1900
1300
68
1910
1300
68
0
57-108/22
95-50-1
1,2-Dichlorobenzene
ND
1900
1030
54
1910
1080
57
5
44-102/28
541-73-1
1,3-Dichlorobenzene
ND
1900
974
51
1910
1010
53
4
42-100/30
* = Outside of Control Limits.
6 145 of 177
FA75651

Matrix Spike/Matrix Spike Duplicate Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 2 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
OP80524-MS
91008923.D
1
06/09/20
MV
06/08/20
OP80524
S9I332
OP80524-MSD
91008924.D
1
06/09/20
MV
06/08/20
OP80524
S9I332
FA75651-6 a
6F06187.D
10
06/23/20
MV
06/08/20
OP80524
S6F240
The QC reported here applies to the following samples:
Method: SW846 8270E
FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6, FA75651-7, FA75651-8, FA75651-9,
FA75651-10, FA75651-11
FA75651-6
Spike
MS
MS
Spike
MSD
MSD
Limits
CAS No.
Compound
ug/kg Q
ug/kg
ug/kg
%
ug/kg
ug/kg
%
RPD
Rec/RPD
106-46-7
1,4-Dichlorobenzene
ND
1900
977
51
1910
1030
54
5
40-106/29
91-94-1
3,3'-Dichlorobenzidine
ND
1900
866
46
1910
905
47
4
36-114/28
84-66-2
Diethyl Phthalate
ND
1900
1270
67
1910
1320
69
4
61-109/20
131-11-3
Dimethyl Phthalate
ND
1900
1160
61
1910
1180
62
2
59-108/20
117-84-0
Di-n-octyl Phthalate
ND
1900
1830
96
1910
1950
102
6
64-119/21
84-74-2
Di-n-butyl Phthalate
ND
1900
1510
80
1910
1550
81
3
63-108/19
122-66-7
1,2-Diphenylhydrazine
ND
1900
1330
70
1910
1340
70
1
58-112/22
117-81-7
bis(2-Ethylhexyl)phthalate
ND
1900
1590
84
1910
1680
88
6
64-115/23
206-44-0
Fluoranthene
303 J
1900
1900
86
1910
1700
75
11
60-108/25
86-73-7
Fluorene
ND
1900
1340
71
1910
1350
71
1
58-109/21
118-74-1
Hexachlorobenzene
ND
1900
1060
56*
1910
1090
57*
3
59-111/21
87-68-3
Hexachlorobutadiene
ND
1900
1030
54
1910
1020
53
1
41-108/27
77-47-4
Hexachlorocyclopentadiene
ND
1900
417
22*
1910
308
16*
30
49-110/31
67-72-1
Hexachloroethane
ND
1900
998
53
1910
1000
52
0
40-105/32
193-39-5
Indeno(1,2,3-cd)pyrene
ND
1900
1640
74
1910
1630
73
1
66-116/22
78-59-1
Isophorone
ND
1900
1010
53
1910
1030
54
2
42-89/22
90-12-0
1-Methylnaphthalene
ND
1900
1150
61
1910
1140
60
1
49-106/26
91-57-6
2-Methylnaphthalene
ND
1900
1180
62
1910
1170
61
1
47-106/27
91-20-3
Naphthalene
ND
1900
1110
58
1910
1100
58
1
44-104/27
98-95-3
Nitrobenzene
ND
1900
1040
55
1910
1050
55
1
43-108/25
621-64-7
N-Nitrosodi-n-propylamine
ND
1900
1070
56
1910
1110
58
4
48-108/27
86-30-6
N-Nitrosodiphenylamine
ND
1900
1210
64
1910
1230
64
2
62-110/21
85-01-8
Phenanthrene
ND
1900
1580
76
1910
1470
70
7
63-111/22
129-00-0
Pyrene
293 J
1900
1550
64*
1910
1490
61*
4
65-115/25
120-82-1
1,2,4-Trichlorobenzene
ND
1900
1040
55
1910
1050
55
1
45-100/26
CAS No.
Surrogate Recoveries
MS
MSD
FA75651-6
Limits
367-12-4
2-Fluorophenol
52%
53%
38% * b
40-102%
4165-62-2
Phenol-d5
72%
73%
46%
41-100%
118-79-6
2,4,6-Tribromophenol
58%
58%
60%
42-108%
4165-60-0
Nitrobenzene-d5
51%
52%
43%
40-105%
321-60-8
2-Fluorobiphenyl
55%
56%
68%
43-107%
1718-51-0
Terphenyl-d14
52%
54%
52%
45-119%
* = Outside of Control Limits.
6 146 of 177
FA75651

Matrix Spike/Matrix Spike Duplicate Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 3 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
OP80524-MS
91008923.D
1
06/09/20
MV
06/08/20
OP80524
S9I332
OP80524-MSD
91008924.D
1
06/09/20
MV
06/08/20
OP80524
S9I332
FA75651-6 a
6F06187.D
10
06/23/20
MV
06/08/20
OP80524
S6F240
The QC reported here applies to the following samples:
Method: SW846 8270E
FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6, FA75651-7, FA75651-8, FA75651-9,
FA75651-10, FA75651-11
(a) Dilution required due to matrix interference; extract was viscous.
(b) Outside control limits due to dilution.
* = Outside of Control Limits.
6 147 of 177
FA75651

ffm
Orlando, FL
GC/LC Semi-volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
LI
i
Section 7
6 148 of 177
FA75651

Method Blank Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 1 of 1
Sample
File ID DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
OP80695-MB
ST147903.1) 1
06/18/20
WH
06/16/20
OP80695
GST3550
The QC reported here applies to the following samples: Method: SW846 8081B
FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6, FA75651-7, FA75651-8, FA75651-9,
FA75651-10, FA75651-11
CAS No.
Compound
Result
RL
MDL
Units Q
309-00-2
Aldrin
ND
1.7
0.53
ug/kg
319-84-6
alpha-BHC
ND
1.7
0.53
ug/kg
319-85-7
beta-BHC
ND
1.7
0.49
ug/kg
319-86-8
delta-BHC
ND
1.7
0.47
ug/kg
58-89-9
gamma-BHC (Lindane)
ND
1.7
0.50
ug/kg
5103-71-9
alpha -Chlordane
ND
1.7
0.52
ug/kg
5103-74-2
gamma -Chlordane
ND
1.7
0.48
ug/kg
60-57-1
Dieldrin
ND
1.7
0.47
ug/kg
72-54-8
4,4'-DDD
ND
3.3
0.46
ug/kg
72-55-9
4,4'-DDE
ND
3.3
0.61
ug/kg
50-29-3
4,4'-DDT
ND
3.3
0.51
ug/kg
72-20-8
Endrin
ND
3.3
0.84
ug/kg
1031-07-8
Endosulfan sulfate
ND
3.3
0.44
ug/kg
7421-93-4
Endrin aldehyde
ND
3.3
0.39
ug/kg
53494-70-5
Endrin ketone
ND
3.3
0.52
ug/kg
959-98-8
Endosulfan-I
ND
1.7
0.38
ug/kg
33213-65-9 Endosulfan-II
ND
1.7
0.39
ug/kg
76-44-8
Heptachlor
ND
1.7
0.49
ug/kg
1024-57-3
Heptachlor epoxide
ND
1.7
0.49
ug/kg
72-43-5
Methoxychlor
ND
3.3
0.67
ug/kg
8001-35-2
Toxaphene
ND
83
25
ug/kg
CAS No.
Surrogate Recoveries
Limits
877-09-8
Tetrachloro-m-xylene
103%
50-122%
2051-24-3
Decachlorobiphenyl
91%
50-133%
V
6 149 of 177
FA75651

Blank Spike Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 1 of 1
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
OP80695-13S2
ST147902.D
1
06/18/20
WH
06/16/20
OP80695
GST3550
The QC reported here applies to the following samples: Method: SW846 8081B
FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6, FA75651-7, FA75651-8, FA75651-9,
FA75651-10, FA75651-11
CAS No. Compound
8001-35-2 Toxaphene
CAS No.
Surrogate Recoveries
877-09-8
Tetrachloro-m-xylene
2051-24-3
Decachlorobiphenyl
* = Outside of Control Limits.
Spike
BSP BSP
ug/kg
ug/kg % Limits
167
200 120 48-155
BSP
Limits
101%
50-122%
88%
50-133%
V
N
6 150 of 177
FA75651

Blank Spike Summary
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 1 of 1
ample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batcl
)P80695-13S
ST147904.D
1
06/18/20
WH
06/16/20
OP80695
GST3550
The QC reported here applies to the following samples: Method: SW846 8081B
FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6, FA75651-7, FA75651-8, FA75651-9,
FA75651-10, FA75651-11
CAS No. Compound
309-00-2
Aldrin
319-84-6
alpha-BHC
319-85-7
beta-BHC
319-86-8
delta-BHC
58-89-9
gamma-BHC (Lindane)
5103-71-9
alpha -Chlordane
5103-74-2
gamma -Chlordane
60-57-1
Dieldrin
72-54-8
4,4'-DDD
72-55-9
4,4'-DDE
50-29-3
4,4'-DDT
72-20-8
Endrin
1031-07-8
Endosulfan sulfate
7421-93-4
Endrin aldehyde
53494-70-5
Endrin ketone
959-98-8
Endosulfan-I
33213-65-9 Endosulfan-II
76-44-8
Heptachlor
1024-57-3
Heptachlor epoxide
72-43-5
Methoxychlor
CAS No.
Surrogate Recoveries
877-09-8
Tetrachloro-m-xylene
2051-24-3
Decachlorobiphenyl
* = Outside of Control Limits.
Spike BSP
ug/kg ug/kg
16.7 18.7
16.7 19.8
16.7 18.6
16.7 18.3
16.7 19.0
16.7 19.0
16.7 19.9
16.7 18.3
16.7 17.6
16.7 17.8
16.7 15.9
16.7 17.6
16.7 17.0
16.7 16.3
16.7 17.0
16.7 17.8
16.7 16.6
16.7 19.7
16.7 19.4
16.7 15.9
BSP
% Limits
112 57-120
119* 60-117
112 57-125
110 42-126
114 60-123
114 61-122
119 63-122
110 63-125
106 55-135
107 61-129
95 60-136
106 67-138
102 59-119
98 37-110
102 60-128
107 62-122
100 62-122
118 58-123
116 60-122
95 57-133
BSP Limits
112% 50-122%
99% 50-133%
V
N
N
01
151 of 177
FA75651

Matrix Spike/Matrix Spike Duplicate Summary Page I of 1
Job Number: FA75651
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
ample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batcl
)P80695-MS
ST147906.D
10
06/18/20
WH
06/16/20
OP80695
GST3550
)P80695-MSD
ST147907.1)
10
06/18/20
WH
06/16/20
OP80695
GST3550
'A75651-4
ST147928.D
1
06/19/20
WH
06/16/20
OP80695
GST3550
'A75651-4
ST147910.D
10
06/18/20
WH
06/16/20
OP80695
GST3550
The QC reported here applies to the following samples: Method: SW846 8081B
FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6, FA75651-7, FA75651-8, FA75651-9,
FA75651-10, FA75651-11
CAS No. Compound
309-00-2
Aldrin
319-84-6
alpha-BHC
319-85-7
beta-BHC
319-86-8
delta-BHC
58-89-9
gamma-BHC (Lindane)
5103-71-9
alpha -Chlordane
5103-74-2
gamma -Chlordane
60-57-1
Dieldrin
72-54-8
4,4'-DDD
72-55-9
4,4'-DDE
50-29-3
4,4'-DDT
72-20-8
Endrin
1031-07-8
Endosulfan sulfate
7421-93-4
Endrin aldehyde
53494-70-5
Endrin ketone
959-98-8
Endosulfan-I
33213-65-9 Endosulfan-II
76-44-8
Heptachlor
1024-57-3
Heptachlor epoxide
72-43-5
Methoxychlor
FA75651-4
Spike
MS
MS
ug/kg Q
ug/kg
ug/kg
%
ND
20
22.5
113
ND
20
23.4
117
ND
20
24.0
120
ND
20
22.7
114
ND
20
22.4
112
ND a
20
26.3
124*
ND a
20
28.0
131 *
ND
20
20.9
105
ND a
20
27.5
120
ND a
20
24.4
122
ND
20
14.7
74
ND
20
19.4
97
ND
20
19.4
97
ND
20
20.3
102
ND
20
17.4
87
ND
20
24.9
125*
ND
20
18.1
91
ND
20
20.3
102
ND
20
22.4
112
ND
20
15.7
79
CAS No. Surrogate Recoveries MS MSD
877-09-8 Tetrachloro-m-xylene 114% 111 %
2051-24-3 Decachlorobiphenyl 96% 97%
(a) Result is from Run #2.
(b) Outside control limits due to dilution.
(c) Outside control limits. However, Sample was ND.
* = Outside of Control Limits.
Spike
MSD
MSD
ug/kg
ug/kg
%
20.2
22.2
110
20.2
22.5
ill
20.2
22.8
113
20.2
22.1
109
20.2
22.1
109
20.2
26.0
121
20.2
27.5
127*
20.2
20.3
100
20.2
24.8
105
20.2
22.7
112
20.2
11.9
59*
20.2
19.7
97
20.2
19.6
97
20.2
19.7
97
20.2
17.5
87
20.2
24.2
120
20.2
17.9
88
20.2
20.6
102
20.2
22.4
ill
20.2
15.7
78
FA75651-4
FA75651-4
Limits
157%* c
126%* b
50-122%
87%
105%
50-133%
Limits
RPD Rec/RPD
1
4
5
3
1
1
2
3
10
7
21
2
1
3
1
3
1
1
0
0
57-120/28
60-117/24
57-125/26
42-126/24
60-123/29
61-122/26
63-122/28
63-125/29
55-135/31
61-129/31
60-136/39
67-138/28
59-119/28
37-110/25
60-128/24
62-122/29
62-122/31
58-123/30
60-122/33
57-133/31
01
152 of 177
FA75651

ffm
Orlando, FL
Metals Analysis
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Matrix Spike and Duplicate Summaries
• Blank Spike and Lab Control Sample Summaries
• Serial Dilution Summaries
LI
i
Section 8
a
6 153 of 177
FA75651

BLANK RESULTS SUMMARY
Part 2 - Method Blanks
Login Number: FA75651
Account: GSYNNCW - Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
QC Batch ID: MP37368 Methods: SW846 7471B
Matrix Type: SOLID Units: mg/kg
Prep Date:
MB
letal RL IDL MDL raw final
Mercury 0.042 .0025 .0042 0.00098 <0.042
Associated samples MP37368: FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
Page 1
6 154 of 177
FA75651

MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA75651
Account: GSYNNCW - Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
QC Batch ID: MP37368 Methods: SW846 7471B
Matrix Type: SOLID Units: mg/kg
Prep Date:
FA75589-1 QC FA75589-1 QC
letal Original DUP RPD Limits Original DUP RPD Limits
Mercury 0.14 0.13 7.4 0-20 0.14 0.13 7.4 0-20
Associated samples MP37368: FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
00
N
Page 1
6 155 of 177
FA75651

MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA75651
Account: GSYNNCW - Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
QC Batch ID: MP37368 Methods: SW846 7471B
Matrix Type: SOLID Units: mg/kg
Prep Date:
FA75589-1 Spikelot QC
letal Original MS HGFLWSI % Rec Limits
Mercury 0.14 0.26 0.136 88.0 80-120
Associated samples MP37368: FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
00
N
Page 2
6 156 of 177
FA75651

MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA75651
Account: GSYNNCW - Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
QC Batch ID: MP37368 Methods: SW846 7471B
Matrix Type: SOLID Units: mg/kg
Prep Date:
FA75589-1 Spikelot MSD QC
letal Original MSD HGFLWSI % Rec RPD Limit
Mercury 0.14 0.26 0.136 88.0 0.0 20
Associated samples MP37368: FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
00
N
Page 3
6 157 of 177
FA75651

SPIKE BLANK AND LAB CONTROL SAMPLE SUMMARY
Login Number: FA75651
Account: GSYNNCW - Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
QC Batch ID: MP37368 Methods: SW846 7471B
Matrix Type: SOLID Units: mg/kg
Prep Date:
BSP Spikelot QC
letal Result HGFLWSI o Rec Limits
Mercury 0.25 0.25 100.0 80-120
Associated samples MP37368: FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
00
W
Page 1
6 158 of 177
FA75651

SERIAL DILUTION RESULTS SUMMARY
Login Number: FA75651
Account: GSYNNCW - Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
QC Batch ID: MP37368 Methods: SW846 7471B
Matrix Type: SOLID Units: ug/l
Prep Date:
FA75589-1 QC
letal Original SDL 1:5 oDIF Limits
Mercury 2.94 2.69 8.4 0-10
Associated samples MP37368: FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
00
Page 1
6 159 of 177
FA75651

BLANK RESULTS SUMMARY
Part 2 - Method Blanks
Login Number: FA75651
Account: GSYNNCW - Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
QC Batch ID: MP37382 Methods: SW846 6010D
Matrix Type: SOLID Units: mg/kg
Prep Date:
MB
letal RL IDL MDL raw final
Aluminum 10 .7 1.8
Antimony 1.0 .05 .065
Arsenic 0.50 .065 .1 -0.11 <0.50
Barium 10 .05 .05 0.015 <10
Beryllium 0.25 .01 .025
Cadmium 0.20 .01 .025 -0.012 <0.20
Calcium 250 2.5 2.5
Chromium 0.50 .05 .05 0.040 <0.50
Cobalt 2.5 .01 .025
Copper 1.3 .05 .05
Iron 15 .85 .85
Lead 1.0 .05 .05 -0.035 <1.0
Magnesium 250 1.8 1.8
Manganese 0.75 .025 .025
Molybdenum 2.5 .015 .025
Nickel 2.0 .02 .025
Potassium 500 10 10
Selenium 1.0 .12 .12 0.20 <1.0
Silver 0.50 .035 .041 -0.010 <0.50
Sodium 500 25 25
Strontium 0.50 .025 .025
Thallium 0.50 .055 .055
Tin 2.5 .045 .045
Titanium 0.50 .025 .025
Vanadium 2.5 .025 .025
Zinc 1.0 .15 .15
Associated samples MP37382: FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6, FA75651-7,
FA75651-8, FA75651-9, FA75651-10, FA75651-11
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
Page 1
6 160 of 177
FA75651

MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA75651
Account: GSYNNCW - Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
QC Batch ID: MP37382 Methods: SW846 6010D
Matrix Type: SOLID Units: mg/kg
Prep Date:
FA75651-1 QC FA75651-1 Spikelot QC
letal Original DUP RPD Limits Original MS MPFLICP2 % Rec Limits
Aluminum
Antimony
Arsenic 5.5 7.4 (a) 29.5 (b) 0-20 5.5 79.8 (a) 76.3 97.4 80-120
Barium 35.1 34.0 (a) 3.2 0-20 35.1 885 76.3 1114.ONc 80-120
Beryllium
Cadmium 0.0 0.0 (a) NC 0-20 0.0 3.2 (a) 1.91 167.8N(c 80-120
Calcium
Chromium 14.4 15.1 (a) 4.7 0-20 14.4 23.6 (a) 7.63 120.6N(c 80-120
Cobalt
Copper
Iron
Lead 55.8 54.9 (a) 1.6 0-20 55.8 223 (a) 19.1 876.7N(c 80-120
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium 0.53 0.49 (a) 7.8 0-20 0.53 71.3 (a) 76.3 92.8 80-120
Silver 0.0 0.0 (a) NC 0-20 0.0 1.7 (a) 1.91 89.1 80-120
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP37382: FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6, FA75651-7,
FA75651-8, FA75651-9, FA75651-10, FA75651-11
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
(a) Sample dilution required due to difficult matrix.
(b) RPD acceptable due to low duplicate and sample concentrations.
(c) Spike recovery indicates possible matrix interference and/or sample non -homogeneity.
00
N
N
Page 1
6 161 of 177
FA75651

MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA75651
Account: GSYNNCW - Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
QC Batch ID: MP37382 Methods: SW846 6010D
Matrix Type: SOLID Units: mg/kg
Prep Date:
FA75651-1 Spikelot MSD QC
letal Original MSD MPFLICP2 % Rec RPD Limit
Aluminum
Antimony
Arsenic 5.5 92.5 (a) 93 93.6 14.7 20
Barium 35.1 135 (a) 93 107.5 145.8 (b)20
Beryllium
Cadmium 0.0 1.7 (a) 2.32 73.2N(c) 61.2 (b) 20
Calcium
Chromium 14.4 27.9 (a) 9.3 145.2N(c 16.7 20
Cobalt
Copper
Iron
Lead 55.8 85.2 (a) 23.2 126.5N(c 89.4 (b) 20
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium 0.53 83.4 (a) 93 89.1 15.6 20
Silver 0.0 2.1 (a) 2.32 90.4 21.1 (b) 20
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP37382: FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6, FA75651-7,
FA75651-8, FA75651-9, FA75651-10, FA75651-11
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
(a) Sample dilution required due to difficult matrix.
(b) High RPD due to possible sample non -homogeneity.
(c) Spike recovery indicates possible matrix interference and/or sample non -homogeneity.
00
N
N
Page 2
6 162 of 177
FA75651

SPIKE BLANK AND LAB CONTROL SAMPLE SUMMARY
Login Number: FA75651
Account: GSYNNCW - Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
QC Batch ID: MP37382 Methods: SW846 6010D
Matrix Type: SOLID Units: mg/kg
Prep Date:
BSP Spikelot QC
letal Result MPFLICP2 % Rec Limits
Aluminum
Antimony
Arsenic 96.8 100 96.8 80-120
Barium 104 100 104.0 80-120
Beryllium
Cadmium 2.4 2.5 96.0 80-120
Calcium
Chromium 10.4 10 104.0 80-120
Cobalt
Copper
Iron
Lead 23.9 25 95.6 80-120
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium 92.2 100 92.2 80-120
Silver 2.2 2.5 88.0 80-120
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP37382: FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6, FA75651-7,
FA75651-8, FA75651-9, FA75651-10, FA75651-11
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
00
N
W
Page 1
6 163 of 177
FA75651

SERIAL DILUTION RESULTS SUMMARY
Login Number: FA75651
Account: GSYNNCW - Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
QC Batch ID: MP37382 Methods: SW846 6010D
Matrix Type: SOLID Units: ug/l
Prep Date:
FA75651-1 QC
letal Original SDL 5:25 %DIF Limits
Aluminum
Antimony
Arsenic 133 160 20.8 (a) 0-10
Barium 844 858 1.6 0-10
Beryllium
Cadmium 0.00 0.00 NC 0-10
Calcium
Chromium 347 357 2.8 0-10
Cobalt
Copper
Iron
Lead 1340 1310 2.6 0-10
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium 12.7 63.7 401.6(a) 0-10
Silver 0.00 0.00 NC 0-10
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP37382: FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6, FA75651-7,
FA75651-8, FA75651-9, FA75651-10, FA75651-11
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
(a) Percent difference acceptable due to low initial sample concentration (< 50 times IDL).
00
N
Page 1
6 164 of 177
FA75651

POST DIGESTATE SPIKE SUMMARY
Login Number: FA75651
Account: GSYNNCW - Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
QC Batch ID: MP37382 Methods: SW846 6010D
Matrix Type: SOLID Units: ug/l
Prep Date:
Sample Final FA75651-1 PS Spike Spike Spike QC
Metal ml ml Raw Corr.** ug/l ml ug/ml ug/l o Rec Limits
Aluminum
Antimony
Arsenic
9.8
10
132.5
129.85
241.1
0.2
5
100
111.3
80-120
Barium
9.8
10
844.4
827.512
1174
0.2
12.5
250
138.6*(a
80-120
Beryllium
Cadmium
9.8
10
37.95
0.2
2.5
50
75.9*(a)
80-120
Calcium
Chromium
9.8
10
346.9
339.962
421.4
0.2
2.5
50
162.9*(a
80-120
Cobalt
Copper
Iron
Lead
9.8
10
1342
1315.16
1481
0.2
2.5
50
331.7*(a
80-120
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
9.8
10
12.7
12.446
107.4
0.2
5
100
95.0
80-120
Silver
9.8
10
51.2
0.2
2.5
50
102.4
80-120
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated
samples
MP37382:
FA75651-1, FA75651-2,
FA75651-3,
FA75651-4,
FA75651-5,
FA75651-6, FA75651-7,
FA75651-8,
FA75651-9,
FA75651-10,
FA75651-11
Results < IDL
are shown
as zero
for calculation purposes
(*) Outside
of QC limits
(**) Corr.
sample
result =
Raw * (sample
volume /
final
volume)
(anr) Analyte
not requested
(a) Spike recovery
indicates
matrix interference and/or
outside
control limits
due
to high level
in
sample
relative
to spike
amount.
00
N
tJ1
Page 1
6 165 of 177
FA75651

BLANK RESULTS SUMMARY
Part 2 - Method Blanks
Login Number: FA75651
Account: GSYNNCW - Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
QC Batch ID: MP37396 Methods: SW846 7471B
Matrix Type: SOLID Units: mg/kg
Prep Date:
MB
letal RL IDL MDL raw final
Mercury 0.042 .0025 .0042-0.0013 <0.042
Associated samples MP37396: FA75651-7, FA75651-8, FA75651-9, FA75651-10, FA75651-11
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
00
W
Page 1
6 166 of 177
FA75651

MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA75651
Account: GSYNNCW - Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
QC Batch ID: MP37396 Methods: SW846 7471B
Matrix Type: SOLID Units: mg/kg
Prep Date:
FA75873-32 QC FA75873-32 Spikelot QC
etal Original DUP RPD Limits Original MS HGFLWSI % Rec Limits
Mercury 0.018 0.011 48.3 (a) 0-20 0.018 0.27 0.264 95.5 80-120
Associated samples MP37396: FA75651-7, FA75651-8, FA75651-9, FA75651-10, FA75651-11
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
(a) RPD acceptable due to low duplicate and sample concentrations.
00
W
N
Page 1
01
167 of 177
FA75651

MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA75651
Account: GSYNNCW - Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
QC Batch ID: MP37396 Methods: SW846 7471B
Matrix Type: SOLID Units: mg/kg
Prep Date:
FA75873-32 Spikelot MSD QC
letal Original MSD HGFLWSI % Rec RPD Limit
Mercury 0.018 0.27 0.272 92.5 0.0 20
Associated samples MP37396: FA75651-7, FA75651-8, FA75651-9, FA75651-10, FA75651-11
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
00
W
N
Page 2
6 168 of 177
FA75651

SPIKE BLANK AND LAB CONTROL SAMPLE SUMMARY
Login Number: FA75651
Account: GSYNNCW - Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
QC Batch ID: MP37396 Methods: SW846 7471B
Matrix Type: SOLID Units: mg/kg
Prep Date:
BSP Spikelot QC
letal Result HGFLWSI o Rec Limits
Mercury 0.23 0.25 92.0 80-120
Associated samples MP37396: FA75651-7, FA75651-8, FA75651-9, FA75651-10, FA75651-11
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
00
W
W
Page 1
6 169 of 177
FA75651

SERIAL DILUTION RESULTS SUMMARY
Login Number: FA75651
Account: GSYNNCW - Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
QC Batch ID: MP37396 Methods: SW846 7471B
Matrix Type: SOLID Units: ug/l
Prep Date:
FA75873-32 QC
letal Original SDL 1:5 oDIF Limits
Mercury 0.201 0.00 100.0(a) 0-10
Associated samples MP37396: FA75651-7, FA75651-8, FA75651-9, FA75651-10, FA75651-11
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
(a) Percent difference acceptable due to low initial sample concentration (< 50 times IDL).
00
W
Page 1
6 170 of 177
FA75651

ffm
Orlando, FL
Misc. Forms
701LJ
Section 9
Custody Documents and Other Forms
(SGS Dayton, NJ)
Includes the following where applicable:
• Chain of Custody
0
6 171 of 177
FA75651

�7v/l ` e3 &YP"
50 SGS North America Int - Orlando TA- '�-Sb S 1
an-6 Chain of Custody SGS-ORLANDOJOB#: PAGE I OF t
"Od Virrclmd Rod, Sui. G15 01I.Moi M 32811 '
TEL. [phone]N FAX: [phone] SGS - ORLANDO Quote # SKIFF #
Client / Re rt n Information
Pro ect Infortnation
Anal
feel
Information
Matrix Codes
ame: LAC
Project Name:
- -- mg
Water
cw - Ground
waterilo-i
ww-water
SW - Surfacedact:
Waterv1
7A-dd—.:
t brow r 5
street
�/, Sate' L
/n%� Em$ii:
Protect #
K CG (^ 2MeC
WS
S
r�
`
SO - Soil
-Sludge
LIO - Other Lpuid
56l - J, � -i tq S
Fax #
Sampler(a) No (a) (Printed)
Client Purchase Order C
Sam ler 1: T h Sampler 2:
„ l
AIR -Air
SGS
COLIECTMNI
coarNNERMFeeMAnoa
o O
rland
Salm le #
Fieltl ID / Poim of Collection
on7c
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7o7a•
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LAa USE ONLY
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Turnaround Time usiness da
Data Dailverab(e It
Comments / Remarks
Approved By. / Date:
ElCOM ERCIAL "A" (RESULTS ONLY)
7 Day
OMMERCIAL "B" (RESULTS PLUS OC)
5 Day WWG'
QREDT7 (EPA LEVEL 3)
3 Day RUSH
[]FULLT7 (EPA LEVEL 4)
2 Day RUSH �—
�EDD'S
1 Day RUSH
ndnf
Omer
r
Rush T/A Data Available VIA Email or I hu.k
$
Sam a Cust must be documented below each time les thane sasalon includir courier
deliw .
Relin a d by pbr/ ffillatbn
Date Time:
Reeelved By/Af!llMbn ellnqukhetl BylAfflllation
Date e.
Reeelved By/Af lled n
0
2 It OC44 :•C 3
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Data Ti—:
Received By/ARilladon Re11,xi" shed By/Afhllatlon
m ate e.
Received By/A nation
5
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8
Lab Use ORI Coder Temperature tto:/Avww.sos com/en/lerms-entl .orldit'rons
ORLD-SMT-0001-03-FORMr (4).rdS Rev 031318
FA75651: Chain of Custody
Page 1 of 2
SGS Dayton, NJ
3
0
6 172 of 177
FA75651

SGS Sample Receipt Summary
Job Number: FA75651 Client:
Date / Time Received: 6/6/2020 9:30:00 AM
Cooler Temps (Raw Measured) °C: Cooler 1: (3.2);
Cooler Temps (Corrected) °C: Cooler 1: (2.9);
Delivery Method:
Cooler Security Y or N
Y or N
1. Custody Seals Present: ❑�
❑ 3. COC Present:
❑,i ❑
2. Custody Seals Intact: k
❑ 4. Smpl Dates/Time OK
❑d ❑
Cooler Temperature
Y or N
1. Temp criteria achieved:
❑� ❑
2. Cooler temp verification:
IR Gun
3. Cooler media:
Ice (Bag)
4. No. Coolers:
1
Quality Control Preservation
Y or N
N/A
1. Trip Blank present / cooler:
❑ I]
❑
2. Trip Blank listed on COC:
❑ W
❑
3. Samples preserved properly:
❑� ❑
4. VOCs headspace free:
❑ ❑
❑./
Project:
Airbill Ws:
Sample Integrity - Documentation
Y
or N
1. Sample labels present on bottles:
❑
2. Container labeling complete:
❑
3. Sample container label / COC agree:
0
❑
Samole Integrity - Condition
Y
or N
1. Sample recvd within HT:
0
❑
2. All containers accounted for:
❑�
❑
3. Condition of sample:
Intact
Sample Integrity - Instructions
Y
or N N/A
1. Analysis requested is clear:
❑�
❑
2. Bottles received for unspecified tests
❑
❑J
3. Sufficient volume recvd for analysis:
❑-
❑
4. Compositing instructions clear:
❑
❑ ❑d
5. Filtering instructions clear:
❑
❑ W
Test Strip Lot #s: pH 1-12: 229517 pH 12+: 208717 Other: (Specify)
Comments
SM089-03
Rev. Date 12/7/17
FA75651: Chain of Custody
Page 2 of 2
6 173 of 177
FA75651

ffm
Orlando, FL
General Chemistry
QC Data Summaries
(SGS Dayton, NJ)
Includes the following where applicable:
• Method Blank and Blank Spike Summaries
• Duplicate Summaries
• Matrix Spike Summaries
i
Section 10
6 174 of 177
FA75651

METHOD BLANK AND SPIKE RESULTS SUMMARY
GENERAL CHEMISTRY
Login Number: FA75651
Account: ALSE - SGS Orlando, FL
Project: GSYNNCW: 31 Harnett, Wilmington, NC
MB Spike BSP BSP QC
nalyte Batch ID RL Result Units Amount Result %Recov Limits
Chromium, Hexavalent
GP28511/GN8711 0.40
0.0 mg/kg
40
38.9
97.3
80-1200
Chromium, Hexavalent
GP28511/GN8711
mg/kg
1020
938
91.6
80-120%
Chromium, Hexavalent
GP28511/GN8711
mg/kg
135
58.6
43.4
28-78%
Associated Samples:
Batch GP28511: FA75651-1,
FA75651-2, FA75651-3, FA75651-4,
FA75651-5, FA75651-6,
FA75651-7,
FA75651-8,
FA75651-9,
FA75651-
10, FA75651-11
(*) Outside of QC limits
Page 1
6 175 of 177
FA75651

DUPLICATE RESULTS SUMMARY
GENERAL CHEMISTRY
Login Number: FA75651
Account: ALSE - SGS Orlando, FL
Project: GSYNNCW: 31 Harnett, Wilmington, NC
QC Original DUP QC
nalyte Batch ID Sample Units Result Result RPD Limits
Chromium, Hexavalent GP28511/GN8711 FA75651-1 mg/kg 0.57 0.52 9.2 0-20%
Associated Samples:
Batch GP28511: FA75651-1, FA75651-2, FA75651-3, FA75651-9, FA75651-5, FA75651-6, FA75651-7, FA75651-8, FA75651-9, FA75651-
10, FA75651-11
(*) Outside of QC limits
Page 1
6 176 of 177
FA75651

MATRIX SPIKE RESULTS SUMMARY
GENERAL CHEMISTRY
Login Number: FA75651
Account: ALSE - SGS Orlando, FL
Project: GSYNNCW: 31 Harnett, Wilmington, NC
QC Original Spike MS QC
nalyte Batch ID Sample Units Result Amount Result %Rec Limits
Chromium, Hexavalent GP28511/GN8711 FA75651-1 mg/kg 0.57 45 30.0 65.4N(a) 75-125%
Chromium, Hexavalent GP28511/GN8711 FA75651-1 mg/kg 0.57 943 875 92.8(b) 75-125%
Associated Samples:
Batch GP28511: FA75651-1, FA75651-2, FA75651-3, FA75651-4, FA75651-5, FA75651-6, FA75651-7, FA75651-8, FA75651-9, FA75651-
10, FA75651-11
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(a) Soluble XCR matrix spike recovery indicates possible matrix interference. Good post spike recovery (106 a) on this
sample.
(b) Good recovery on insoluble XCR matrix spike. See additional comments on soluble matrix spike recovery.
Page 1
6 177 of 177
FA75651

ffm
Orlando, FL
The results set forth herein are provided by SGS North America Inc. a-Hl ydcopy 2. 0
Automated Report
Technical Report for
Geosyntec Consultants
31 Harnett, Wilmington, NC
GN7035
SGS Job Number: FA75769
Sampling Date: 06/08/20
Report to:
Geosyntec Consultants
701 N Franklin St Suite 501
Wilmington, NC 28401
bpeach@geosyntec. com; KRhonehouse@Geosyntec.
ATTN: Brendon Peach
Total number of pages in report: 62
Ac Fp
Test results contained within this data package meet the requirements Caitlin Brice, M. S.
of the National Environmental Laboratory Accreditation Program General Manager
and/or state specific certification programs as applicable.
Client Service contact: Jean Dent -Smith 407-425-6700
Certifications: FL(E83510), LA(03051), KS(E-10327), IL(200063), NC(573), NJ(FL002), NY(12022), SC(96038001)
DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177),
AK, AR, IA, KY, MA, MS, ND, NH, NV, OK, OR, UT, WA, WV
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc. • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: [phone] • fax: [phone]
SGS is the sole authority for authorizing edits or modifications to this document. Please share your ideas about
Unauthorized modification of this report is strictly prohibited. how we can serve you better at:
Review standard terms at: http://www.sgs.com/en/terms-and-conditions [e-mail]
1 of 62
FA75769

Sections:
Table of Contents
-1-
Section1: Sample Summary...................................................................................................
3
Section2: Summary of Hits....................................................................................................
4
Section3: Sample Results........................................................................................................
5
3.1: FA75769-1: MW-01......................................................................................................
6
3.2: FA75769-2: MW-02......................................................................................................
12
3.3: FA75769-3: MW-04......................................................................................................
18
3.4: FA75769-4: DUP-01.....................................................................................................
24
3.5: FA75769-5: TRIP BLANK...........................................................................................
30
Section4: Misc. Forms............................................................................................................
32
4.1: Chain of Custody...........................................................................................................
33
Section5: MS Volatiles - QC Data Summaries.....................................................................
3'
5.1: Method Blank Summary................................................................................................
36
5.2: Blank Spike Summary...................................................................................................
39
5.3: Matrix Spike/Matrix Spike Duplicate Summary...........................................................
42
Section 6: MS Semi-volatiles - QC Data Summaries............................................................
45
6.1: Method Blank Summary................................................................................................
46
6.2: Blank Spike Summary...................................................................................................
48
Section 7: Metals Analysis - QC Data Summaries................................................................
51
7.1: Prep QC MP37370: Hg..................................................................................................
52
7.2: Prep QC MP37417: As,Ba,Cd,Cr,Pb,Se,Ag..................................................................
57
W,

SGS North America Inc.
Sample Summary
Geosyntec Consultants
31 Harnett, Wilmington, NC
Project No: GN7035
Job No: FA75769
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
This report contains results reported as ND = Not detected. The following applies:
Organics ND = Not detected above the MDL
FA75769-1 06/08/20 13:25 BP 06/10/20 AQ Ground Water MW-01
FA75769-2 06/08/20 13:25 BP 06/10/20 AQ Ground Water M W-02
FA75769-3 06/08/20 11:15 BP 06/10/20 AQ Ground Water MW-04
FA75769-4 06/08/20 11:20 BP 06/10/20 AQ Ground Water DUP-01
FA75769-5 06/08/20 13:00 BP 06/10/20 AQ Trip Blank Water TRIP BLANK
6 3 of 62
FA75769

Summary of Hits
Job Number:
FA75769
Account:
Geosyntec Consultants
Project:
31 Harnett, Wilmington, NC
Collected:
06/08/20
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA75769-1 MW-01
sec-Butylbenzene
0.37 J
1.0
0.24
ug/1
SW846 8260D
tert-Butylbenzene
0.32 J
1.0
0.31
ug/1
SW846 8260D
p-Isopropyltoluene
0.49 J
1.0
0.21
ug/1
SW846 8260D
Fluorene
0.78 J
4.8
0.67
ug/1
SW846 8270E
Arsenic
85.4
10
ug/1
SW846 6010D
FA75769-2 MW-02
p-Isopropyltoluene
1.8
1.0
0.21
ug/1
SW846 8260D
Methyl Chloride
4.4
2.0
0.50
ug/1
SW846 8260D
Arsenic
163
10
ug/1
SW846 6010D
FA75769-3 MW-04
Lead
5.2
5.0
ug/1
SW846 6010D
FA75769-4 DUP-01
Arsenic
31.9
10
ug/1
SW846 6010D
Chromium
12.2
10
ug/1
SW846 6010D
Lead
8.4
5.0
ug/l
SW846 6010D
FA75769-5 TRIP BLANK
Toluene 1.6 1.0 0.30 ug/1 SW846 8260D
Page 1 of l
6 4of62
FA75769

i
SG$
Orlando, FL im
Section 3
Sample Results
Report of Analysis
6 5of62
FA75769

SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID: MW-01
Lab Sample ID: FA75769-1 Date Sampled: 06/08/20
Matrix: AQ - Ground Water Date Received: 06/10/20
Method: SW846 8260D Percent Solids: n/a
Project: 31 Harnett, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 I65756.1) 1 06/20/20 13:04 KB n/a n/a VI2085
Run #2
Purge Volume
Run # 1 5.0 ml
Run #2
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
67-64-1
Acetone
ND
25
10
ug/1
71-43-2
Benzene
ND
1.0
0.31
ug/1
108-86-1
Bromobenzene
ND
1.0
0.37
ug/1
74-97-5
Bromochloromethane
ND
1.0
0.45
ug/1
75-27-4
Bromodichloromethane
ND
1.0
0.24
ug/1
75-25-2
Bromoform
ND
1.0
0.41
ug/1
78-93-3
2-Butanone (MEK)
ND
5.0
2.0
ug/1
104-51-8
n-Butylbenzene
ND
1.0
0.23
ug/1
135-98-8
sec-Butylbenzene
0.37
1.0
0.24
ug/1
98-06-6
tert-Butylbenzene
0.32
1.0
0.31
ug/1
56-23-5
Carbon Tetrachloride
ND
1.0
0.36
ug/1
108-90-7
Chlorobenzene
ND
1.0
0.20
ug/1
75-00-3
Chloroethane
ND
2.0
0.67
ug/1
67-66-3
Chloroform
ND
1.0
0.30
ug/1
95-49-8
o-Chlorotoluene
ND
1.0
0.22
ug/1
106-43-4
p-Chlorotoluene
ND
1.0
0.31
ug/1
124-48-1
Dibromochloromethane
ND
1.0
0.28
ug/1
106-93-4
1,2-Dibromoethane
ND
2.0
0.28
ug/1
75-71-8
Dichlorodifluoromethane
ND
2.0
0.50
ug/1
95-50-1
1,2-Dichlorobenzene
ND
1.0
0.32
ug/1
541-73-1
1,3-Dichlorobenzene
ND
1.0
0.22
ug/1
106-46-7
1,4-Dichlorobenzene
ND
1.0
0.26
ug/1
75-34-3
1, 1 -Dichloroethane
ND
1.0
0.34
ug/1
107-06-2
1,2-Dichloroethane
ND
1.0
0.31
ug/1
75-35-4
1, 1 -Dichloroethylene
ND
1.0
0.32
ug/1
156-59-2
cis-1,2-Dichloroethylene
ND
1.0
0.28
ug/1
156-60-5
trans- 1, 2-Dichloroethylene
ND
1.0
0.22
ug/1
78-87-5
1,2-Dichloropropane
ND
1.0
0.43
ug/1
142-28-9
1,3-Dichloropropane
ND
1.0
0.31
ug/1
594-20-7
2,2-Dichloropropane
ND
1.0
0.24
ug/1
563-58-6
1, 1 -Dichloropropene
ND
1.0
0.34
ug/1
10061-01-5
cis- 1, 3 -Dichloropropene
ND
1.0
0.29
ug/1
J
J
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
01
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FA75769

SGS North America Inc.
Report of Analysis
Client Sample ID: MW-01
Lab Sample ID: FA75769-1 Date Sampled: 06/08/20
Matrix: AQ - Ground Water Date Received: 06/10/20
Method: SW846 8260D Percent Solids: n/a
Project: 31 Harnett, Wilmington, NC
VOA List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
10061-02-6
trans- 1, 3-Dichloropropene
ND
1.0
0.21
ug/1
108-20-3
Di -Isopropyl Ether
ND
1.0
0.24
ug/1
64-17-5
Ethyl Alcohol
ND
200
82
ug/1
100-41-4
Ethylbenzene
ND
1.0
0.36
ug/1
591-78-6
2-Hexanone
ND
10
2.0
ug/1
98-82-8
Isopropylbenzene
ND
1.0
0.22
ug/1
99-87-6
p-Isopropyltoluene
0.49
1.0
0.21
ug/1 J
74-83-9
Methyl Bromide
ND
2.0
0.59
ug/1
74-87-3
Methyl Chloride
ND
2.0
0.50
ug/1
75-09-2
Methylene Chloride
ND
5.0
2.0
ug/1
108-10-1
4-Methyl-2-pentanone (MIBK) ND
5.0
1.0
ug/1
1634-04-4
Methyl Tert Butyl Ether
ND
1.0
0.23
ug/1
91-20-3
Naphthalene
ND
5.0
1.0
ug/1
103-65-1
n-Propylbenzene
ND
1.0
0.29
ug/1
100-42-5
Styrene
ND
1.0
0.22
ug/1
630-20-6
1, 1, 1,2-Tetrachloroethane
ND
1.0
0.28
ug/1
79-34-5
1,1,2,2-Tetrachloroethane
ND
1.0
0.30
ug/1
127-18-4
Tetrachloroethylene
ND
1.0
0.22
ug/1
108-88-3
Toluene
ND
1.0
0.30
ug/1
87-61-6
1,2,3-Trichlorobenzene
ND
2.0
0.61
ug/1
120-82-1
1,2,4-Trichlorobenzene
ND
2.0
0.50
ug/1
71-55-6
1, 1, 1 -Trichloroethane
ND
1.0
0.25
ug/1
79-00-5
1,1,2-Trichloroethane
ND
1.0
0.47
ug/1
79-01-6
Trichloroethylene
ND
1.0
0.35
ug/1
75-69-4
Trichlorofluoromethane
ND
2.0
0.50
ug/1
96-18-4
1,2,3-Trichloropropane
ND
2.0
0.63
ug/1
95-63-6
1,2,4-Trimethylbenzene
ND
1.0
0.32
ug/1
108-67-8
1,3,5-Trimethylbenzene
ND
1.0
0.27
ug/1
108-05-4
Vinyl Acetate
ND
10
2.0
ug/1
75-01-4
Vinyl Chloride
ND
1.0
0.41
ug/1
m,p-Xylene
ND
2.0
0.47
ug/1
95-47-6
o-Xylene
ND
1.0
0.26
ug/1
1330-20-7
Xylene (total)
ND
3.0
0.72
ug/1
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
1868-53-7
Dibromofluoromethane
96%
83-118%
17060-07-0
1,2-Dichloroethane-D4
100%
79-125%
2037-26-5
Toluene-D8
102%
85-112%
460-00-4
4-Bromofluorobenzene
102%
83-118%
Page 2 of 2
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
01
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SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: MW-01
Lab Sample ID: FA75769-1 Date Sampled: 06/08/20
Matrix: AQ - Ground Water Date Received: 06/10/20
Method: SW846 8270E SW846 3510C Percent Solids: n/a
Project: 31 Harnett, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 61706217.1) 1 06/24/20 17:11 MV 06/13/20 10:20 OP80648 S617241
Run #2
Initial Volume Final Volume
Run #1 1050 ml 1.0 ml
Run #2
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
65-85-0
Benzoic Acid
ND
48
9.5
ug/1
59-50-7
4-Chloro-3-methyl Phenol
ND
4.8
0.56
ug/1
95-57-8
2-Chlorophenol
ND
4.8
0.60
ug/1
120-83-2
2,4-Dichlorophenol
ND
4.8
0.80
ug/1
105-67-9
2,4-Dimethylphenol
ND
4.8
0.70
ug/1
51-28-5
2,4-Dinitrophenol
ND
24
4.8
ug/1
534-52-1
4,6-Dinitro-o-cresol
ND
9.5
1.9
ug/1
95-48-7
2-Methylphenol
ND
4.8
0.53
ug/1
3&4-Methylphenol
ND
4.8
0.93
ug/1
88-75-5
2-Nitrophenol
ND
4.8
0.81
ug/1
100-02-7
4-Nitrophenol
ND
24
4.8
ug/1
87-86-5
Pentachlorophenola
ND
24
4.8
ug/1
108-95-2
Phenol
ND
4.8
0.48
ug/1
88-06-2
2, 4, 6-Trichlorophenol
ND
4.8
0.72
ug/1
83-32-9
Acenaphthene
ND
4.8
0.60
ug/1
208-96-8
Acenaphthylene
ND
4.8
0.61
ug/1
120-12-7
Anthracene
ND
4.8
0.76
ug/1
56-55-3
Benzo(a)anthracene
ND
4.8
0.72
ug/1
50-32-8
Benzo(a)pyrene
ND
4.8
0.75
ug/1
205-99-2
Benzo(b)fluoranthene
ND
4.8
0.74
ug/1
191-24-2
Benzo(g, h, i)perylene
ND
4.8
0.78
ug/1
207-08-9
Benzo(k)fluoranthene
ND
4.8
0.82
ug/1
100-51-6
Benzyl Alcohol
ND
4.8
0.58
ug/1
101-55-3
4-13romophenyl Phenyl Ether
ND
4.8
0.81
ug/1
85-68-7
Butyl Benzyl Phthalate b
ND
4.8
0.95
ug/1
106-47-8
4-Chloroaniline
ND
4.8
0.60
ug/1
111-91-1
bis(2-Chloroethoxy)methane
ND
4.8
0.77
ug/1
111-44-4
bis(2-Chloroethyl)ether
ND
4.8
0.70
ug/1
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
4.8
0.72
ug/1
91-58-7
2-Chloronaphthalene
ND
4.8
0.48
ug/1
7005-72-3
4-Chlorophenyl Phenyl Ether
ND
4.8
0.51
ug/1
218-01-9
Chrysene
ND
4.8
0.81
ug/1
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
01
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FA75769

SGS North America Inc.
Report of Analysis
Client Sample ID: MW-01
Lab Sample ID: FA75769-1 Date Sampled: 06/08/20
Matrix: AQ - Ground Water Date Received: 06/10/20
Method: SW846 8270E SW846 3510C Percent Solids: n/a
Project: 31 Harnett, Wilmington, NC
ABN List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
53-70-3
Dibenzo(a,h)anthracene
ND
4.8
0.77
ug/1
132-64-9
Dibenzofaran
ND
4.8
0.57
ug/1
95-50-1
1,2-Dichlorobenzene
ND
4.8
0.48
ug/1
541-73-1
1,3-Dichlorobenzene
ND
4.8
0.48
ug/1
106-46-7
1,4-Dichlorobenzene
ND
4.8
0.48
ug/1
91-94-1
3,3'-Dichlorobenzidine
ND
4.8
0.61
ug/1
84-66-2
Diethyl Phthalate
ND
4.8
0.95
ug/1
131-11-3
Dimethyl Phthalate
ND
4.8
0.95
ug/1
84-74-2
Di-n-butyl Phthalate c
ND
4.8
0.95
ug/1
117-84-0
Di-n-octyl Phthalate
ND
4.8
0.95
ug/1
122-66-7
1,2-Diphenylhydrazine c
ND
4.8
0.72
ug/1
117-81-7
bis(2-Ethylhexyl)phthalate
ND
4.8
0.95
ug/1
206-44-0
Fluoranthene c
ND
4.8
0.53
ug/1
86-73-7
Fluorene
0.78
4.8
0.67
ug/1 J
118-74-1
Hexachlorobenzene
ND
4.8
0.66
ug/1
87-68-3
Hexachlorobutadiene
ND
4.8
0.48
ug/1
77-47-4
Hexachlorocyclopentadiene
ND
4.8
1.7
ug/1
67-72-1
Hexachloroethane
ND
4.8
1.6
ug/1
193-39-5
Indeno(1,2,3-cd)pyrene
ND
4.8
0.68
ug/1
78-59-1
Isophorone
ND
4.8
0.74
ug/1
90-12-0
1-Methylnaphthalene
ND
4.8
0.50
ug/1
91-57-6
2-Methylnaphthalene
ND
4.8
0.57
ug/1
91-20-3
Naphthalene
ND
4.8
0.48
ug/1
98-95-3
Nitrobenzene
ND
4.8
0.89
ug/1
621-64-7
N-Nitrosodi-n-propylamine
ND
4.8
0.64
ug/1
86-30-6
N-Nitrosodiphenylamine °
ND
4.8
0.77
ug/1
85-01-8
Phenanthrene
ND
4.8
0.82
ug/1
129-00-0
Pyrene d
ND
4.8
0.65
ug/1
120-82-1
1,2,4-Trichlorobenzene
ND
4.8
1.0
ug/1
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
367-12-4
2-Fluorophenol
22%
14-67%
4165-62-2
Phenol-d5
15%
10-50%
118-79-6
2,4,6-Tribromophenol
90%
33-118%
4165-60-0
Nitrobenzene-d5
65%
42-108%
321-60-8
2-Fluorobiphenyl
76%
40-106%
1718-51-0
Terphenyl-dl4
78%
39-121%
(a) Associated ICV outside control limits high, however sample ND.
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
01
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FA75769

SGS North America Inc.
Report of Analysis
Tent Sample ID: MW-01
,ab Sample ID: FA75769-1 Date Sampled: 06/08/20
Ratrix: AQ - Ground Water Date Received: 06/10/20
lthod: SW846 8270E SW846 3510C Percent Solids: n/a
'roject: 31 Harnett, Wilmington, NC
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
Page 3 of 3
(b) Associated CCV outside of control limits high, sample was ND.
(c) Associated BS recovery outside control limits low.
(d) Associated BS recovery outside control limits low. Associated CCV outside of control limits high, sample was
ND.
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
01
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FA75769

SGS North America Inc.
Report of Analysis
Client Sample ID: MW-01
Lab Sample ID: FA75769-1 Date Sampled: 06/08/20
Matrix: AQ - Ground Water Date Received: 06/10/20
Percent Solids: n/a
Project: 31 Harnett, Wilmington, NC
Total Metals Analysis
Analyte Result RL
Arsenic 85.4 10
Barium < 200 200
Cadmium < 5.0 5.0
Chromium < 10 10
Lead < 5.0 5.0
Mercury < 0.50 0.50
Selenium < 10 10
Silver < 10 10
(1) Instrument QC Batch: MA16820
(2) Instrument QC Batch: MA16837
(3) Instrument QC Batch: MA16839
(4) Prep QC Batch: MP37370
(5) Prep QC Batch: MP37417
RL = Reporting Limit
Page 1 of 1 j
Units DF Prep Analyzed By Method Prep Method
ug/1
1
06/19/20
06/19/20
LM
SW846 6010D 2
SW846 3010A 5
ug/I
1
06/19/20
06/20/20
LM
SW846 6010D 3
SW846 3010A 5
ug/1
1
06/19/20
06/19/20
LM
SW846 6010D 2
SW846 3010A 5
ug/1
1
06/19/20
06/19/20
LM
SW846 6010D 2
SW846 3010A 5
ug/1
1
06/19/20
06/19/20
LM
SW846 6010D 2
SW846 3010A 5
ug/1
1
06/12/20
06/12/20
JC
SW846 7470A 1
SW846 7470A 4
ug/1
1
06/19/20
06/19/20
LM
SW846 6010D 2
SW846 3010A 5
ug/1
1
06/19/20
06/19/20
LM
SW846 6010D 2
SW846 3010A 5
6 11 of 62
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SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID: MW-02
Lab Sample ID: FA75769-2 Date Sampled: 06/08/20
Matrix: AQ - Ground Water Date Received: 06/10/20
Method: SW846 8260D Percent Solids: n/a
Project: 31 Harnett, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 I65757.1) 1 06/20/20 13:31 KB n/a n/a VI2085
Run #2
Purge Volume
Run # 1 5.0 ml
Run #2
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
67-64-1
Acetone
ND
25
10
ug/1
71-43-2
Benzene
ND
1.0
0.31
ug/1
108-86-1
Bromobenzene
ND
1.0
0.37
ug/1
74-97-5
Bromochloromethane
ND
1.0
0.45
ug/1
75-27-4
Bromodichloromethane
ND
1.0
0.24
ug/1
75-25-2
Bromoform
ND
1.0
0.41
ug/1
78-93-3
2-Butanone (MEK)
ND
5.0
2.0
ug/1
104-51-8
n-Butylbenzene
ND
1.0
0.23
ug/1
135-98-8
sec-Butylbenzene
ND
1.0
0.24
ug/1
98-06-6
tert-Butylbenzene
ND
1.0
0.31
ug/1
56-23-5
Carbon Tetrachloride
ND
1.0
0.36
ug/1
108-90-7
Chlorobenzene
ND
1.0
0.20
ug/1
75-00-3
Chloroethane
ND
2.0
0.67
ug/1
67-66-3
Chloroform
ND
1.0
0.30
ug/1
95-49-8
o-Chlorotoluene
ND
1.0
0.22
ug/1
106-43-4
p-Chlorotoluene
ND
1.0
0.31
ug/1
124-48-1
Dibromochloromethane
ND
1.0
0.28
ug/1
106-93-4
1,2-Dibromoethane
ND
2.0
0.28
ug/1
75-71-8
Dichlorodifluoromethane
ND
2.0
0.50
ug/1
95-50-1
1,2-Dichlorobenzene
ND
1.0
0.32
ug/1
541-73-1
1,3-Dichlorobenzene
ND
1.0
0.22
ug/1
106-46-7
1,4-Dichlorobenzene
ND
1.0
0.26
ug/1
75-34-3
1, 1 -Dichloroethane
ND
1.0
0.34
ug/1
107-06-2
1,2-Dichloroethane
ND
1.0
0.31
ug/1
75-35-4
1, 1 -Dichloroethylene
ND
1.0
0.32
ug/1
156-59-2
cis-1,2-Dichloroethylene
ND
1.0
0.28
ug/1
156-60-5
trans- 1, 2-Dichloroethylene
ND
1.0
0.22
ug/1
78-87-5
1,2-Dichloropropane
ND
1.0
0.43
ug/1
142-28-9
1,3-Dichloropropane
ND
1.0
0.31
ug/1
594-20-7
2,2-Dichloropropane
ND
1.0
0.24
ug/1
563-58-6
1, 1 -Dichloropropene
ND
1.0
0.34
ug/1
10061-01-5
cis- 1, 3 -Dichloropropene
ND
1.0
0.29
ug/1
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
01
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FA75769

SGS North America Inc.
Report of Analysis
Client Sample ID: MW-02
Lab Sample ID: FA75769-2 Date Sampled: 06/08/20
Matrix: AQ - Ground Water Date Received: 06/10/20
Method: SW846 8260D Percent Solids: n/a
Project: 31 Harnett, Wilmington, NC
VOA List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
10061-02-6
trans- 1, 3-Dichloropropene
ND
1.0
0.21
ug/1
108-20-3
Di -Isopropyl Ether
ND
1.0
0.24
ug/1
64-17-5
Ethyl Alcohol
ND
200
82
ug/1
100-41-4
Ethylbenzene
ND
1.0
0.36
ug/1
591-78-6
2-Hexanone
ND
10
2.0
ug/1
98-82-8
Isopropylbenzene
ND
1.0
0.22
ug/1
99-87-6
p-Isopropyltoluene
1.8
1.0
0.21
ug/1
74-83-9
Methyl Bromide
ND
2.0
0.59
ug/1
74-87-3
Methyl Chloride
4.4
2.0
0.50
ug/1
75-09-2
Methylene Chloride
ND
5.0
2.0
ug/1
108-10-1
4-Methyl-2-pentanone (MIBK) ND
5.0
1.0
ug/1
1634-04-4
Methyl Tert Butyl Ether
ND
1.0
0.23
ug/1
91-20-3
Naphthalene
ND
5.0
1.0
ug/1
103-65-1
n-Propylbenzene
ND
1.0
0.29
ug/1
100-42-5
Styrene
ND
1.0
0.22
ug/1
630-20-6
1, 1, 1,2-Tetrachloroethane
ND
1.0
0.28
ug/1
79-34-5
1,1,2,2-Tetrachloroethane
ND
1.0
0.30
ug/1
127-18-4
Tetrachloroethylene
ND
1.0
0.22
ug/1
108-88-3
Toluene
ND
1.0
0.30
ug/1
87-61-6
1,2,3-Trichlorobenzene
ND
2.0
0.61
ug/1
120-82-1
1,2,4-Trichlorobenzene
ND
2.0
0.50
ug/1
71-55-6
1, 1, 1 -Trichloroethane
ND
1.0
0.25
ug/1
79-00-5
1,1,2-Trichloroethane
ND
1.0
0.47
ug/1
79-01-6
Trichloroethylene
ND
1.0
0.35
ug/1
75-69-4
Trichlorofluoromethane
ND
2.0
0.50
ug/1
96-18-4
1,2,3-Trichloropropane
ND
2.0
0.63
ug/1
95-63-6
1,2,4-Trimethylbenzene
ND
1.0
0.32
ug/1
108-67-8
1,3,5-Trimethylbenzene
ND
1.0
0.27
ug/1
108-05-4
Vinyl Acetate
ND
10
2.0
ug/1
75-01-4
Vinyl Chloride
ND
1.0
0.41
ug/1
m,p-Xylene
ND
2.0
0.47
ug/1
95-47-6
o-Xylene
ND
1.0
0.26
ug/1
1330-20-7
Xylene (total)
ND
3.0
0.72
ug/1
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
1868-53-7
Dibromofluoromethane
95%
83-118%
17060-07-0
1,2-Dichloroethane-D4
101%
79-125%
2037-26-5
Toluene-D8
102%
85-112%
460-00-4
4-Bromofluorobenzene
102%
83-118%
Page 2 of 2
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
01
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FA75769

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: MW-02
Lab Sample ID: FA75769-2 Date Sampled: 06/08/20
Matrix: AQ - Ground Water Date Received: 06/10/20
Method: SW846 8270E SW846 3510C Percent Solids: n/a
Project: 31 Harnett, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 61706218.13 1 06/24/20 17:38 MV 06/13/20 10:20 OP80648 S617241
Run #2
Initial Volume Final Volume
Run #1 1050 ml 1.0 ml
Run #2
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
65-85-0
Benzoic Acid
ND
48
9.5
ug/1
59-50-7
4-Chloro-3-methyl Phenol
ND
4.8
0.56
ug/1
95-57-8
2-Chlorophenol
ND
4.8
0.60
ug/1
120-83-2
2,4-Dichlorophenol
ND
4.8
0.80
ug/1
105-67-9
2,4-Dimethylphenol
ND
4.8
0.70
ug/1
51-28-5
2,4-Dinitrophenol
ND
24
4.8
ug/1
534-52-1
4,6-Dinitro-o-cresol
ND
9.5
1.9
ug/1
95-48-7
2-Methylphenol
ND
4.8
0.53
ug/1
3&4-Methylphenol
ND
4.8
0.93
ug/1
88-75-5
2-Nitrophenol
ND
4.8
0.81
ug/1
100-02-7
4-Nitrophenol
ND
24
4.8
ug/1
87-86-5
Pentachlorophenola
ND
24
4.8
ug/1
108-95-2
Phenol
ND
4.8
0.48
ug/1
88-06-2
2, 4, 6-Trichlorophenol
ND
4.8
0.72
ug/1
83-32-9
Acenaphthene
ND
4.8
0.60
ug/1
208-96-8
Acenaphthylene
ND
4.8
0.61
ug/1
120-12-7
Anthracene
ND
4.8
0.76
ug/1
56-55-3
Benzo(a)anthracene
ND
4.8
0.72
ug/1
50-32-8
Benzo(a)pyrene
ND
4.8
0.75
ug/1
205-99-2
Benzo(b)fluoranthene
ND
4.8
0.74
ug/1
191-24-2
Benzo(g, h, i)perylene
ND
4.8
0.78
ug/1
207-08-9
Benzo(k)fluoranthene
ND
4.8
0.82
ug/1
100-51-6
Benzyl Alcohol
ND
4.8
0.58
ug/1
101-55-3
4-13romophenyl Phenyl Ether
ND
4.8
0.81
ug/1
85-68-7
Butyl Benzyl Phthalate b
ND
4.8
0.95
ug/1
106-47-8
4-Chloroaniline
ND
4.8
0.60
ug/1
111-91-1
bis(2-Chloroethoxy)methane
ND
4.8
0.77
ug/1
111-44-4
bis(2-Chloroethyl)ether
ND
4.8
0.70
ug/1
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
4.8
0.72
ug/1
91-58-7
2-Chloronaphthalene
ND
4.8
0.48
ug/1
7005-72-3
4-Chlorophenyl Phenyl Ether
ND
4.8
0.51
ug/1
218-01-9
Chrysene
ND
4.8
0.81
ug/1
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
01
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FA75769

SGS North America Inc.
Report of Analysis
Client Sample ID: MW-02
Lab Sample ID: FA75769-2 Date Sampled: 06/08/20
Matrix: AQ - Ground Water Date Received: 06/10/20
Method: SW846 8270E SW846 3510C Percent Solids: n/a
Project: 31 Harnett, Wilmington, NC
ABN List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
53-70-3
Dibenzo(a,h)anthracene
ND
4.8
0.77
ug/1
132-64-9
Dibenzofaran
ND
4.8
0.57
ug/1
95-50-1
1,2-Dichlorobenzene
ND
4.8
0.48
ug/1
541-73-1
1,3-Dichlorobenzene
ND
4.8
0.48
ug/1
106-46-7
1,4-Dichlorobenzene
ND
4.8
0.48
ug/1
91-94-1
3,3'-Dichlorobenzidine
ND
4.8
0.61
ug/1
84-66-2
Diethyl Phthalate
ND
4.8
0.95
ug/1
131-11-3
Dimethyl Phthalate
ND
4.8
0.95
ug/1
84-74-2
Di-n-butyl Phthalate c
ND
4.8
0.95
ug/1
117-84-0
Di-n-octyl Phthalate
ND
4.8
0.95
ug/1
122-66-7
1,2-Diphenylhydrazine c
ND
4.8
0.72
ug/1
117-81-7
bis(2-Ethylhexyl)phthalate
ND
4.8
0.95
ug/1
206-44-0
Fluoranthene c
ND
4.8
0.53
ug/1
86-73-7
Fluorene
ND
4.8
0.67
ug/1
118-74-1
Hexachlorobenzene
ND
4.8
0.66
ug/1
87-68-3
Hexachlorobutadiene
ND
4.8
0.48
ug/1
77-47-4
Hexachlorocyclopentadiene
ND
4.8
1.7
ug/1
67-72-1
Hexachloroethane
ND
4.8
1.6
ug/1
193-39-5
Indeno(1,2,3-cd)pyrene
ND
4.8
0.68
ug/1
78-59-1
Isophorone
ND
4.8
0.74
ug/1
90-12-0
1-Methylnaphthalene
ND
4.8
0.50
ug/1
91-57-6
2-Methylnaphthalene
ND
4.8
0.57
ug/1
91-20-3
Naphthalene
ND
4.8
0.48
ug/1
98-95-3
Nitrobenzene
ND
4.8
0.89
ug/1
621-64-7
N-Nitrosodi-n-propylamine
ND
4.8
0.64
ug/1
86-30-6
N-Nitrosodiphenylamine °
ND
4.8
0.77
ug/1
85-01-8
Phenanthrene
ND
4.8
0.82
ug/1
129-00-0
Pyrene d
ND
4.8
0.65
ug/1
120-82-1
1,2,4-Trichlorobenzene
ND
4.8
1.0
ug/1
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
367-12-4
2-Fluorophenol
30%
14-67%
4165-62-2
Phenol-d5
27%
10-50%
118-79-6
2,4,6-Tribromophenol
86%
33-118%
4165-60-0
Nitrobenzene-d5
63%
42-108%
321-60-8
2-Fluorobiphenyl
77%
40-106%
1718-51-0
Terphenyl-dl4
69%
39-121%
(a) Associated ICV outside control limits high, however sample ND.
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
01
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FA75769

SGS North America Inc.
Report of Analysis
Tent Sample ID: MW-02
,ab Sample ID: FA75769-2 Date Sampled: 06/08/20
Ratrix: AQ - Ground Water Date Received: 06/10/20
lthod: SW846 8270E SW846 3510C Percent Solids: n/a
'roject: 31 Harnett, Wilmington, NC
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
Page 3 of 3 N
(b) Associated CCV outside of control limits high, sample was ND.
(c) Associated BS recovery outside control limits low.
(d) Associated BS recovery outside control limits low. Associated CCV outside of control limits high, sample was
ND.
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
01
16 of 62
FA75769

SGS North America Inc.
Report of Analysis
Client Sample ID: MW-02
Lab Sample ID: FA75769-2 Date Sampled: 06/08/20
Matrix: AQ - Ground Water Date Received: 06/10/20
Percent Solids: n/a
Project: 31 Harnett, Wilmington, NC
Total Metals Analysis
Analyte Result RL
Arsenic 163 10
Barium < 200 200
Cadmium < 5.0 5.0
Chromium < 10 10
Lead < 5.0 5.0
Mercury < 0.50 0.50
Selenium < 10 10
Silver < 10 10
(1) Instrument QC Batch: MA16820
(2) Instrument QC Batch: MA16837
(3) Instrument QC Batch: MA16839
(4) Prep QC Batch: MP37370
(5) Prep QC Batch: MP37417
RL = Reporting Limit
Page 1 of 1 N
Units DF Prep Analyzed By Method Prep Method
ug/1
1
06/19/20
06/19/20
LM
SW846 6010D 2
SW846 3010A 5
ug/I
1
06/19/20
06/20/20
LM
SW846 6010D 3
SW846 3010A 5
ug/1
1
06/19/20
06/19/20
LM
SW846 6010D 2
SW846 3010A 5
ug/1
1
06/19/20
06/19/20
LM
SW846 6010D 2
SW846 3010A 5
ug/1
1
06/19/20
06/19/20
LM
SW846 6010D 2
SW846 3010A 5
ug/1
1
06/12/20
06/12/20
JC
SW846 7470A 1
SW846 7470A 4
ug/1
1
06/19/20
06/19/20
LM
SW846 6010D 2
SW846 3010A 5
ug/1
1
06/19/20
06/19/20
LM
SW846 6010D 2
SW846 3010A 5
6 17 of 62
FA75769

SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID: MW-04
Lab Sample ID: FA75769-3 Date Sampled: 06/08/20
Matrix: AQ - Ground Water Date Received: 06/10/20
Method: SW846 8260D Percent Solids: n/a
Project: 31 Harnett, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 I65758.1) 1 06/20/20 13:58 KB n/a n/a VI2085
Run #2
Purge Volume
Run # 1 5.0 ml
Run #2
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
67-64-1
Acetone
ND
25
10
ug/1
71-43-2
Benzene
ND
1.0
0.31
ug/1
108-86-1
Bromobenzene
ND
1.0
0.37
ug/1
74-97-5
Bromochloromethane
ND
1.0
0.45
ug/1
75-27-4
Bromodichloromethane
ND
1.0
0.24
ug/1
75-25-2
Bromoform
ND
1.0
0.41
ug/1
78-93-3
2-Butanone (MEK)
ND
5.0
2.0
ug/1
104-51-8
n-Butylbenzene
ND
1.0
0.23
ug/1
135-98-8
sec-Butylbenzene
ND
1.0
0.24
ug/1
98-06-6
tert-Butylbenzene
ND
1.0
0.31
ug/1
56-23-5
Carbon Tetrachloride
ND
1.0
0.36
ug/1
108-90-7
Chlorobenzene
ND
1.0
0.20
ug/1
75-00-3
Chloroethane
ND
2.0
0.67
ug/1
67-66-3
Chloroform
ND
1.0
0.30
ug/1
95-49-8
o-Chlorotoluene
ND
1.0
0.22
ug/1
106-43-4
p-Chlorotoluene
ND
1.0
0.31
ug/1
124-48-1
Dibromochloromethane
ND
1.0
0.28
ug/1
106-93-4
1,2-Dibromoethane
ND
2.0
0.28
ug/1
75-71-8
Dichlorodifluoromethane
ND
2.0
0.50
ug/1
95-50-1
1,2-Dichlorobenzene
ND
1.0
0.32
ug/1
541-73-1
1,3-Dichlorobenzene
ND
1.0
0.22
ug/1
106-46-7
1,4-Dichlorobenzene
ND
1.0
0.26
ug/1
75-34-3
1, 1 -Dichloroethane
ND
1.0
0.34
ug/1
107-06-2
1,2-Dichloroethane
ND
1.0
0.31
ug/1
75-35-4
1, 1 -Dichloroethylene
ND
1.0
0.32
ug/1
156-59-2
cis-1,2-Dichloroethylene
ND
1.0
0.28
ug/1
156-60-5
trans- 1, 2-Dichloroethylene
ND
1.0
0.22
ug/1
78-87-5
1,2-Dichloropropane
ND
1.0
0.43
ug/1
142-28-9
1,3-Dichloropropane
ND
1.0
0.31
ug/1
594-20-7
2,2-Dichloropropane
ND
1.0
0.24
ug/1
563-58-6
1, 1 -Dichloropropene
ND
1.0
0.34
ug/1
10061-01-5
cis- 1, 3 -Dichloropropene
ND
1.0
0.29
ug/1
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
01
18 of 62
FA75769

SGS North America Inc.
Report of Analysis
Client Sample ID: MW-04
Lab Sample ID: FA75769-3 Date Sampled: 06/08/20
Matrix: AQ - Ground Water Date Received: 06/10/20
Method: SW846 8260D Percent Solids: n/a
Project: 31 Harnett, Wilmington, NC
VOA List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
10061-02-6
trans- 1, 3-Dichloropropene
ND
1.0
0.21
ug/1
108-20-3
Di -Isopropyl Ether
ND
1.0
0.24
ug/1
64-17-5
Ethyl Alcohol
ND
200
82
ug/1
100-41-4
Ethylbenzene
ND
1.0
0.36
ug/1
591-78-6
2-Hexanone
ND
10
2.0
ug/1
98-82-8
Isopropylbenzene
ND
1.0
0.22
ug/1
99-87-6
p-Isopropyltoluene
ND
1.0
0.21
ug/1
74-83-9
Methyl Bromide
ND
2.0
0.59
ug/1
74-87-3
Methyl Chloride
ND
2.0
0.50
ug/1
75-09-2
Methylene Chloride
ND
5.0
2.0
ug/1
108-10-1
4-Methyl-2-pentanone (MIBK) ND
5.0
1.0
ug/1
1634-04-4
Methyl Tert Butyl Ether
ND
1.0
0.23
ug/1
91-20-3
Naphthalene
ND
5.0
1.0
ug/1
103-65-1
n-Propylbenzene
ND
1.0
0.29
ug/1
100-42-5
Styrene
ND
1.0
0.22
ug/1
630-20-6
1, 1, 1,2-Tetrachloroethane
ND
1.0
0.28
ug/1
79-34-5
1,1,2,2-Tetrachloroethane
ND
1.0
0.30
ug/1
127-18-4
Tetrachloroethylene
ND
1.0
0.22
ug/1
108-88-3
Toluene
ND
1.0
0.30
ug/1
87-61-6
1,2,3-Trichlorobenzene
ND
2.0
0.61
ug/1
120-82-1
1,2,4-Trichlorobenzene
ND
2.0
0.50
ug/1
71-55-6
1, 1, 1 -Trichloroethane
ND
1.0
0.25
ug/1
79-00-5
1,1,2-Trichloroethane
ND
1.0
0.47
ug/1
79-01-6
Trichloroethylene
ND
1.0
0.35
ug/1
75-69-4
Trichlorofluoromethane
ND
2.0
0.50
ug/1
96-18-4
1,2,3-Trichloropropane
ND
2.0
0.63
ug/1
95-63-6
1,2,4-Trimethylbenzene
ND
1.0
0.32
ug/1
108-67-8
1,3,5-Trimethylbenzene
ND
1.0
0.27
ug/1
108-05-4
Vinyl Acetate
ND
10
2.0
ug/1
75-01-4
Vinyl Chloride
ND
1.0
0.41
ug/1
m,p-Xylene
ND
2.0
0.47
ug/1
95-47-6
o-Xylene
ND
1.0
0.26
ug/1
1330-20-7
Xylene (total)
ND
3.0
0.72
ug/1
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
1868-53-7
Dibromofluoromethane
95%
83-118%
17060-07-0
1,2-Dichloroethane-D4
100%
79-125%
2037-26-5
Toluene-D8
102%
85-112%
460-00-4
4-Bromofluorobenzene
104%
83-118%
Page 2 of 2
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
01
19 of 62
FA75769

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: MW-04
Lab Sample ID: FA75769-3 Date Sampled: 06/08/20
Matrix: AQ - Ground Water Date Received: 06/10/20
Method: SW846 8270E SW846 3510C Percent Solids: n/a
Project: 31 Harnett, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 61706219.13 1 06/24/20 18:05 MV 06/13/20 10:20 OP80648 S617241
Run #2
Initial Volume Final Volume
Run #1 1050 ml 1.0 ml
Run #2
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
65-85-0
Benzoic Acid
ND
48
9.5
ug/1
59-50-7
4-Chloro-3-methyl Phenol
ND
4.8
0.56
ug/1
95-57-8
2-Chlorophenol
ND
4.8
0.60
ug/1
120-83-2
2,4-Dichlorophenol
ND
4.8
0.80
ug/1
105-67-9
2,4-Dimethylphenol
ND
4.8
0.70
ug/1
51-28-5
2,4-Dinitrophenol
ND
24
4.8
ug/1
534-52-1
4,6-Dinitro-o-cresol
ND
9.5
1.9
ug/1
95-48-7
2-Methylphenol
ND
4.8
0.53
ug/1
3&4-Methylphenol
ND
4.8
0.93
ug/1
88-75-5
2-Nitrophenol
ND
4.8
0.81
ug/1
100-02-7
4-Nitrophenol
ND
24
4.8
ug/1
87-86-5
Pentachlorophenola
ND
24
4.8
ug/1
108-95-2
Phenol
ND
4.8
0.48
ug/1
88-06-2
2, 4, 6-Trichlorophenol
ND
4.8
0.72
ug/1
83-32-9
Acenaphthene
ND
4.8
0.60
ug/1
208-96-8
Acenaphthylene
ND
4.8
0.61
ug/1
120-12-7
Anthracene
ND
4.8
0.76
ug/1
56-55-3
Benzo(a)anthracene
ND
4.8
0.72
ug/1
50-32-8
Benzo(a)pyrene
ND
4.8
0.75
ug/1
205-99-2
Benzo(b)fluoranthene
ND
4.8
0.74
ug/1
191-24-2
Benzo(g, h, i)perylene
ND
4.8
0.78
ug/1
207-08-9
Benzo(k)fluoranthene
ND
4.8
0.82
ug/1
100-51-6
Benzyl Alcohol
ND
4.8
0.58
ug/1
101-55-3
4-13romophenyl Phenyl Ether
ND
4.8
0.81
ug/1
85-68-7
Butyl Benzyl Phthalate b
ND
4.8
0.95
ug/1
106-47-8
4-Chloroaniline
ND
4.8
0.60
ug/1
111-91-1
bis(2-Chloroethoxy)methane
ND
4.8
0.77
ug/1
111-44-4
bis(2-Chloroethyl)ether
ND
4.8
0.70
ug/1
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
4.8
0.72
ug/1
91-58-7
2-Chloronaphthalene
ND
4.8
0.48
ug/1
7005-72-3
4-Chlorophenyl Phenyl Ether
ND
4.8
0.51
ug/1
218-01-9
Chrysene
ND
4.8
0.81
ug/1
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
01
20 of 62
FA75769

SGS North America Inc.
Report of Analysis
Client Sample ID: MW-04
Lab Sample ID: FA75769-3 Date Sampled: 06/08/20
Matrix: AQ - Ground Water Date Received: 06/10/20
Method: SW846 8270E SW846 3510C Percent Solids: n/a
Project: 31 Harnett, Wilmington, NC
ABN List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
53-70-3
Dibenzo(a,h)anthracene
ND
4.8
0.77
ug/1
132-64-9
Dibenzofaran
ND
4.8
0.57
ug/1
95-50-1
1,2-Dichlorobenzene
ND
4.8
0.48
ug/1
541-73-1
1,3-Dichlorobenzene
ND
4.8
0.48
ug/1
106-46-7
1,4-Dichlorobenzene
ND
4.8
0.48
ug/1
91-94-1
3,3'-Dichlorobenzidine
ND
4.8
0.61
ug/1
84-66-2
Diethyl Phthalate
ND
4.8
0.95
ug/1
131-11-3
Dimethyl Phthalate
ND
4.8
0.95
ug/1
84-74-2
Di-n-butyl Phthalate c
ND
4.8
0.95
ug/1
117-84-0
Di-n-octyl Phthalate
ND
4.8
0.95
ug/1
122-66-7
1,2-Diphenylhydrazine c
ND
4.8
0.72
ug/1
117-81-7
bis(2-Ethylhexyl)phthalate
ND
4.8
0.95
ug/1
206-44-0
Fluoranthene c
ND
4.8
0.53
ug/1
86-73-7
Fluorene
ND
4.8
0.67
ug/1
118-74-1
Hexachlorobenzene
ND
4.8
0.66
ug/1
87-68-3
Hexachlorobutadiene
ND
4.8
0.48
ug/1
77-47-4
Hexachlorocyclopentadiene
ND
4.8
1.7
ug/1
67-72-1
Hexachloroethane
ND
4.8
1.6
ug/1
193-39-5
Indeno(1,2,3-cd)pyrene
ND
4.8
0.68
ug/1
78-59-1
Isophorone
ND
4.8
0.74
ug/1
90-12-0
1-Methylnaphthalene
ND
4.8
0.50
ug/1
91-57-6
2-Methylnaphthalene
ND
4.8
0.57
ug/1
91-20-3
Naphthalene
ND
4.8
0.48
ug/1
98-95-3
Nitrobenzene
ND
4.8
0.89
ug/1
621-64-7
N-Nitrosodi-n-propylamine
ND
4.8
0.64
ug/1
86-30-6
N-Nitrosodiphenylamine °
ND
4.8
0.77
ug/1
85-01-8
Phenanthrene
ND
4.8
0.82
ug/1
129-00-0
Pyrene d
ND
4.8
0.65
ug/1
120-82-1
1,2,4-Trichlorobenzene
ND
4.8
1.0
ug/1
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
367-12-4
2-Fluorophenol
17%
14-67%
4165-62-2
Phenol-d5
16%
10-50%
118-79-6
2,4,6-Tribromophenol
54%
33-118%
4165-60-0
Nitrobenzene-d5
43%
42-108%
321-60-8
2-Fluorobiphenyl
54%
40-106%
1718-51-0
Terphenyl-dl4
41%
39-121%
(a) Associated ICV outside control limits high, however sample ND.
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
01
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FA75769

SGS North America Inc.
Report of Analysis
Tent Sample ID: MW-04
,ab Sample ID: FA75769-3 Date Sampled: 06/08/20
Ratrix: AQ - Ground Water Date Received: 06/10/20
lthod: SW846 8270E SW846 3510C Percent Solids: n/a
'roject: 31 Harnett, Wilmington, NC
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
Page 3 of 3 w
(b) Associated CCV outside of control limits high, sample was ND.
(c) Associated BS recovery outside control limits low.
(d) Associated BS recovery outside control limits low. Associated CCV outside of control limits high, sample was
ND.
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
01
22 of 62
FA75769

SGS North America Inc.
Report of Analysis
Client Sample ID: MW-04
Lab Sample ID: FA75769-3 Date Sampled: 06/08/20
Matrix: AQ - Ground Water Date Received: 06/10/20
Percent Solids: n/a
Project: 31 Harnett, Wilmington, NC
Total Metals Analysis
Analyte Result RL
Arsenic < 10 10
Barium < 200 200
Cadmium < 5.0 5.0
Chromium < 10 10
Lead 5.2 5.0
Mercury < 0.50 0.50
Selenium < 10 10
Silver < 10 10
(1) Instrument QC Batch: MA16820
(2) Instrument QC Batch: MA16837
(3) Instrument QC Batch: MA16839
(4) Prep QC Batch: MP37370
(5) Prep QC Batch: MP37417
RL = Reporting Limit
Page 1 of 1 w
Units DF Prep Analyzed By Method Prep Method
ug/1
1
06/19/20
06/19/20
LM
SW846 6010D 2
SW846 3010A 5
ug/I
1
06/19/20
06/20/20
LM
SW846 6010D 3
SW846 3010A 5
ug/1
1
06/19/20
06/19/20
LM
SW846 6010D 2
SW846 3010A 5
ug/1
1
06/19/20
06/19/20
LM
SW846 6010D 2
SW846 3010A 5
ug/1
1
06/19/20
06/19/20
LM
SW846 6010D 2
SW846 3010A 5
ug/1
1
06/12/20
06/12/20
JC
SW846 7470A 1
SW846 7470A 4
ug/1
1
06/19/20
06/19/20
LM
SW846 6010D 2
SW846 3010A 5
ug/1
1
06/19/20
06/19/20
LM
SW846 6010D 2
SW846 3010A 5
6 23 of 62
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SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID: DUP-01
Lab Sample ID: FA75769-4 Date Sampled: 06/08/20
Matrix: AQ - Ground Water Date Received: 06/10/20
Method: SW846 8260D Percent Solids: n/a
Project: 31 Harnett, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 I65759.1) 1 06/20/20 14:24 KB n/a n/a VI2085
Run #2
Purge Volume
Run # 1 5.0 ml
Run #2
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
67-64-1
Acetone
ND
25
10
ug/1
71-43-2
Benzene
ND
1.0
0.31
ug/1
108-86-1
Bromobenzene
ND
1.0
0.37
ug/1
74-97-5
Bromochloromethane
ND
1.0
0.45
ug/1
75-27-4
Bromodichloromethane
ND
1.0
0.24
ug/1
75-25-2
Bromoform
ND
1.0
0.41
ug/1
78-93-3
2-Butanone (MEK)
ND
5.0
2.0
ug/1
104-51-8
n-Butylbenzene
ND
1.0
0.23
ug/1
135-98-8
sec-Butylbenzene
ND
1.0
0.24
ug/1
98-06-6
tert-Butylbenzene
ND
1.0
0.31
ug/1
56-23-5
Carbon Tetrachloride
ND
1.0
0.36
ug/1
108-90-7
Chlorobenzene
ND
1.0
0.20
ug/1
75-00-3
Chloroethane
ND
2.0
0.67
ug/1
67-66-3
Chloroform
ND
1.0
0.30
ug/1
95-49-8
o-Chlorotoluene
ND
1.0
0.22
ug/1
106-43-4
p-Chlorotoluene
ND
1.0
0.31
ug/1
124-48-1
Dibromochloromethane
ND
1.0
0.28
ug/1
106-93-4
1,2-Dibromoethane
ND
2.0
0.28
ug/1
75-71-8
Dichlorodifluoromethane
ND
2.0
0.50
ug/1
95-50-1
1,2-Dichlorobenzene
ND
1.0
0.32
ug/1
541-73-1
1,3-Dichlorobenzene
ND
1.0
0.22
ug/1
106-46-7
1,4-Dichlorobenzene
ND
1.0
0.26
ug/1
75-34-3
1, 1 -Dichloroethane
ND
1.0
0.34
ug/1
107-06-2
1,2-Dichloroethane
ND
1.0
0.31
ug/1
75-35-4
1, 1 -Dichloroethylene
ND
1.0
0.32
ug/1
156-59-2
cis-1,2-Dichloroethylene
ND
1.0
0.28
ug/1
156-60-5
trans- 1, 2-Dichloroethylene
ND
1.0
0.22
ug/1
78-87-5
1,2-Dichloropropane
ND
1.0
0.43
ug/1
142-28-9
1,3-Dichloropropane
ND
1.0
0.31
ug/1
594-20-7
2,2-Dichloropropane
ND
1.0
0.24
ug/1
563-58-6
1, 1 -Dichloropropene
ND
1.0
0.34
ug/1
10061-01-5
cis- 1, 3 -Dichloropropene
ND
1.0
0.29
ug/1
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
01
24 of 62
FA75769

SGS North America Inc.
Report of Analysis
Client Sample ID: DUP-0I
Lab Sample ID: FA75769-4 Date Sampled: 06/08/20
Matrix: AQ - Ground Water Date Received: 06/10/20
Method: SW846 8260D Percent Solids: n/a
Project: 31 Harnett, Wilmington, NC
VOA List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
10061-02-6
trans- 1, 3-Dichloropropene
ND
1.0
0.21
ug/1
108-20-3
Di -Isopropyl Ether
ND
1.0
0.24
ug/1
64-17-5
Ethyl Alcohol
ND
200
82
ug/1
100-41-4
Ethylbenzene
ND
1.0
0.36
ug/1
591-78-6
2-Hexanone
ND
10
2.0
ug/1
98-82-8
Isopropylbenzene
ND
1.0
0.22
ug/1
99-87-6
p-Isopropyltoluene
ND
1.0
0.21
ug/1
74-83-9
Methyl Bromide
ND
2.0
0.59
ug/1
74-87-3
Methyl Chloride
ND
2.0
0.50
ug/1
75-09-2
Methylene Chloride
ND
5.0
2.0
ug/1
108-10-1
4-Methyl-2-pentanone (MIBK) ND
5.0
1.0
ug/1
1634-04-4
Methyl Tert Butyl Ether
ND
1.0
0.23
ug/1
91-20-3
Naphthalene
ND
5.0
1.0
ug/1
103-65-1
n-Propylbenzene
ND
1.0
0.29
ug/1
100-42-5
Styrene
ND
1.0
0.22
ug/1
630-20-6
1, 1, 1,2-Tetrachloroethane
ND
1.0
0.28
ug/1
79-34-5
1,1,2,2-Tetrachloroethane
ND
1.0
0.30
ug/1
127-18-4
Tetrachloroethylene
ND
1.0
0.22
ug/1
108-88-3
Toluene
ND
1.0
0.30
ug/1
87-61-6
1,2,3-Trichlorobenzene
ND
2.0
0.61
ug/1
120-82-1
1,2,4-Trichlorobenzene
ND
2.0
0.50
ug/1
71-55-6
1, 1, 1 -Trichloroethane
ND
1.0
0.25
ug/1
79-00-5
1,1,2-Trichloroethane
ND
1.0
0.47
ug/1
79-01-6
Trichloroethylene
ND
1.0
0.35
ug/1
75-69-4
Trichlorofluoromethane
ND
2.0
0.50
ug/1
96-18-4
1,2,3-Trichloropropane
ND
2.0
0.63
ug/1
95-63-6
1,2,4-Trimethylbenzene
ND
1.0
0.32
ug/1
108-67-8
1,3,5-Trimethylbenzene
ND
1.0
0.27
ug/1
108-05-4
Vinyl Acetate
ND
10
2.0
ug/1
75-01-4
Vinyl Chloride
ND
1.0
0.41
ug/1
m,p-Xylene
ND
2.0
0.47
ug/1
95-47-6
o-Xylene
ND
1.0
0.26
ug/1
1330-20-7
Xylene (total)
ND
3.0
0.72
ug/1
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
1868-53-7
Dibromofluoromethane
95%
83-118%
17060-07-0
1,2-Dichloroethane-D4
101%
79-125%
2037-26-5
Toluene-D8
102%
85-112%
460-00-4
4-Bromofluorobenzene
104%
83-118%
Page 2 of 2
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
01
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FA75769

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: DUP-01
Lab Sample ID: FA75769-4 Date Sampled: 06/08/20
Matrix: AQ - Ground Water Date Received: 06/10/20
Method: SW846 8270E SW846 3510C Percent Solids: n/a
Project: 31 Harnett, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 61706220.13 1 06/24/20 18:31 MV 06/13/20 10:20 OP80648 S617241
Run #2
Initial Volume Final Volume
Run # 1 100 ml 1.0 ml
Run #2
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
65-85-0
Benzoic Acid
ND
500
100
ug/1
59-50-7
4-Chloro-3-methyl Phenol
ND
50
5.9
ug/1
95-57-8
2-Chlorophenol
ND
50
6.3
ug/1
120-83-2
2,4-Dichlorophenol
ND
50
8.4
ug/1
105-67-9
2,4-Dimethylphenol
ND
50
7.4
ug/1
51-28-5
2,4-Dinitrophenol
ND
250
50
ug/1
534-52-1
4,6-Dinitro-o-cresol
ND
100
20
ug/1
95-48-7
2-Methylphenol
ND
50
5.6
ug/1
3&4-Methylphenol
ND
50
9.8
ug/1
88-75-5
2-Nitrophenol
ND
50
8.5
ug/1
100-02-7
4-Nitrophenol
ND
250
50
ug/1
87-86-5
Pentachlorophenola
ND
250
50
ug/1
108-95-2
Phenol
ND
50
5.0
ug/1
88-06-2
2,4,6-Trichlorophenol
ND
50
7.5
ug/1
83-32-9
Acenaphthene
ND
50
6.3
ug/1
208-96-8
Acenaphthylene
ND
50
6.4
ug/1
120-12-7
Anthracene
ND
50
8.0
ug/1
56-55-3
Benzo(a)anthracene
ND
50
7.6
ug/1
50-32-8
Benzo(a)pyrene
ND
50
7.8
ug/1
205-99-2
Benzo(b)fluoranthene
ND
50
7.8
ug/1
191-24-2
Benzo(g, h, i)perylene
ND
50
8.2
ug/1
207-08-9
Benzo(k)fluoranthene
ND
50
8.6
ug/1
100-51-6
Benzyl Alcohol
ND
50
6.1
ug/1
101-55-3
4-Bromophenyl Phenyl Ether
ND
50
8.5
ug/1
85-68-7
Butyl Benzyl Phthalate b
ND
50
10
ug/1
106-47-8
4-Chloroaniline
ND
50
6.3
ug/1
111-91-1
bis(2-Chloroethoxy)methane
ND
50
8.1
ug/1
111-44-4
bis(2-Chloroethyl)ether
ND
50
7.3
ug/1
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
50
7.6
ug/1
91-58-7
2-Chloronaphthalene
ND
50
5.0
ug/1
7005-72-3
4-Chlorophenyl Phenyl Ether
ND
50
5.4
ug/1
218-01-9
Chrysene
ND
50
8.5
ug/1
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
01
26 of 62
FA75769

SGS North America Inc.
Report of Analysis
Client Sample ID: DUP-0I
Lab Sample ID: FA75769-4 Date Sampled: 06/08/20
Matrix: AQ - Ground Water Date Received: 06/10/20
Method: SW846 8270E SW846 3510C Percent Solids: n/a
Project: 31 Harnett, Wilmington, NC
ABN List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
53-70-3
Dibenzo(a,h)anthracene
ND
50
8.0
ug/1
132-64-9
Dibenzofaran
ND
50
6.0
ug/1
95-50-1
1,2-Dichlorobenzene
ND
50
5.0
ug/1
541-73-1
1,3-Dichlorobenzene
ND
50
5.0
ug/1
106-46-7
1,4-Dichlorobenzene
ND
50
5.0
ug/1
91-94-1
3,3'-Dichlorobenzidine
ND
50
6.4
ug/1
84-66-2
Diethyl Phthalate
ND
50
10
ug/1
131-11-3
Dimethyl Phthalate
ND
50
10
ug/1
84-74-2
Di-n-butyl Phthalate c
ND
50
10
ug/1
117-84-0
Di-n-octyl Phthalate
ND
50
10
ug/1
122-66-7
1,2-Diphenylhydrazine c
ND
50
7.6
ug/1
117-81-7
bis(2-Ethylhexyl)phthalate
ND
50
10
ug/1
206-44-0
Fluoranthene c
ND
50
5.5
ug/1
86-73-7
Fluorene
ND
50
7.0
ug/1
118-74-1
Hexachlorobenzene
ND
50
6.9
ug/1
87-68-3
Hexachlorobutadiene
ND
50
5.0
ug/1
77-47-4
Hexachlorocyclopentadiene
ND
50
18
ug/1
67-72-1
Hexachloroethane
ND
50
16
ug/1
193-39-5
Indeno(1,2,3-cd)pyrene
ND
50
7.1
ug/1
78-59-1
Isophorone
ND
50
7.8
ug/1
90-12-0
1-Methylnaphthalene
ND
50
5.3
ug/1
91-57-6
2-Methylnaphthalene
ND
50
6.0
ug/1
91-20-3
Naphthalene
ND
50
5.0
ug/1
98-95-3
Nitrobenzene
ND
50
9.3
ug/1
621-64-7
N-Nitrosodi-n-propylamine
ND
50
6.7
ug/1
86-30-6
N-Nitrosodiphenylamine °
ND
50
8.1
ug/1
85-01-8
Phenanthrene
ND
50
8.6
ug/1
129-00-0
Pyrene d
ND
50
6.8
ug/1
120-82-1
1,2,4-Trichlorobenzene
ND
50
11
ug/1
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
367-12-4
2-Fluorophenol
25%
14-67%
4165-62-2
Phenol-d5
25%
10-50%
118-79-6
2,4,6-Tribromophenol
72%
33-118%
4165-60-0
Nitrobenzene-d5
55%
42-108%
321-60-8
2-Fluorobiphenyl
68%
40-106%
1718-51-0
Terphenyl-dl4
65%
39-121%
(a) Associated ICV outside control limits high, however sample ND.
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
01
27 of 62
FA75769

SGS North America Inc.
Report of Analysis
Tent Sample ID: DUP-01
,ab Sample ID: FA75769-4 Date Sampled: 06/08/20
Ratrix: AQ - Ground Water Date Received: 06/10/20
lthod: SW846 8270E SW846 3510C Percent Solids: n/a
'roject: 31 Harnett, Wilmington, NC
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
Page 3 of 3
(b) Associated CCV outside of control limits high, sample was ND.
(c) Associated BS recovery outside control limits low.
(d) Associated BS recovery outside control limits low. Associated CCV outside of control limits high, sample was
ND.
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
01
28 of 62
FA75769

SGS North America Inc.
Report of Analysis
Client Sample ID: DUP-0I
Lab Sample ID: FA75769-4 Date Sampled: 06/08/20
Matrix: AQ - Ground Water Date Received: 06/10/20
Percent Solids: n/a
Project: 31 Harnett, Wilmington, NC
Total Metals Analysis
Analyte Result RL
Arsenic 31.9 10
Barium < 200 200
Cadmium < 5.0 5.0
Chromium 12.2 10
Lead 8.4 5.0
Mercury < 0.50 0.50
Selenium < 10 10
Silver < 10 10
(1) Instrument QC Batch: MA16820
(2) Instrument QC Batch: MA16837
(3) Instrument QC Batch: MA16839
(4) Prep QC Batch: MP37370
(5) Prep QC Batch: MP37417
RL = Reporting Limit
Page 1 of 1 P
Units DF Prep Analyzed By Method Prep Method
ug/1
1
06/19/20
06/19/20
LM
SW846 6010D 2
SW846 3010A 5
ug/I
1
06/19/20
06/20/20
LM
SW846 6010D 3
SW846 3010A 5
ug/1
1
06/19/20
06/19/20
LM
SW846 6010D 2
SW846 3010A 5
ug/1
1
06/19/20
06/19/20
LM
SW846 6010D 2
SW846 3010A 5
ug/1
1
06/19/20
06/19/20
LM
SW846 6010D 2
SW846 3010A 5
ug/1
1
06/12/20
06/12/20
JC
SW846 7470A 1
SW846 7470A 4
ug/1
1
06/19/20
06/19/20
LM
SW846 6010D 2
SW846 3010A 5
ug/1
1
06/19/20
06/19/20
LM
SW846 6010D 2
SW846 3010A 5
6 29 of 62
FA75769

SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID: TRIP BLANK
Lab Sample ID: FA75769-5 Date Sampled: 06/08/20
Matrix: AQ - Trip Blank Water Date Received: 06/10/20
Method: SW846 8260D Percent Solids: n/a
Project: 31 Harnett, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 I65755.1) 1 06/20/20 12:37 KB n/a n/a VI2085
Run #2
Purge Volume
Run # 1 5.0 ml
Run #2
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
67-64-1
Acetone
ND
25
10
ug/1
71-43-2
Benzene
ND
1.0
0.31
ug/1
108-86-1
Bromobenzene
ND
1.0
0.37
ug/1
74-97-5
Bromochloromethane
ND
1.0
0.45
ug/1
75-27-4
Bromodichloromethane
ND
1.0
0.24
ug/1
75-25-2
Bromoform
ND
1.0
0.41
ug/1
78-93-3
2-Butanone (MEK)
ND
5.0
2.0
ug/1
104-51-8
n-Butylbenzene
ND
1.0
0.23
ug/1
135-98-8
sec-Butylbenzene
ND
1.0
0.24
ug/1
98-06-6
tert-Butylbenzene
ND
1.0
0.31
ug/1
56-23-5
Carbon Tetrachloride
ND
1.0
0.36
ug/1
108-90-7
Chlorobenzene
ND
1.0
0.20
ug/1
75-00-3
Chloroethane
ND
2.0
0.67
ug/1
67-66-3
Chloroform
ND
1.0
0.30
ug/1
95-49-8
o-Chlorotoluene
ND
1.0
0.22
ug/1
106-43-4
p-Chlorotoluene
ND
1.0
0.31
ug/1
124-48-1
Dibromochloromethane
ND
1.0
0.28
ug/1
106-93-4
1,2-Dibromoethane
ND
2.0
0.28
ug/1
75-71-8
Dichlorodifluoromethane
ND
2.0
0.50
ug/1
95-50-1
1,2-Dichlorobenzene
ND
1.0
0.32
ug/1
541-73-1
1,3-Dichlorobenzene
ND
1.0
0.22
ug/1
106-46-7
1,4-Dichlorobenzene
ND
1.0
0.26
ug/1
75-34-3
1, 1 -Dichloroethane
ND
1.0
0.34
ug/1
107-06-2
1,2-Dichloroethane
ND
1.0
0.31
ug/1
75-35-4
1, 1 -Dichloroethylene
ND
1.0
0.32
ug/1
156-59-2
cis-1,2-Dichloroethylene
ND
1.0
0.28
ug/1
156-60-5
trans- 1, 2-Dichloroethylene
ND
1.0
0.22
ug/1
78-87-5
1,2-Dichloropropane
ND
1.0
0.43
ug/1
142-28-9
1,3-Dichloropropane
ND
1.0
0.31
ug/1
594-20-7
2,2-Dichloropropane
ND
1.0
0.24
ug/1
563-58-6
1, 1 -Dichloropropene
ND
1.0
0.34
ug/1
10061-01-5
cis- 1, 3 -Dichloropropene
ND
1.0
0.29
ug/1
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
01
30 of 62
FA75769

SGS North America Inc.
Report of Analysis
Client Sample ID: TRIP BLANK
Lab Sample ID: FA75769-5 Date Sampled: 06/08/20
Matrix: AQ - Trip Blank Water Date Received: 06/10/20
Method: SW846 8260D Percent Solids: n/a
Project: 31 Harnett, Wilmington, NC
VOA List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
10061-02-6
trans- 1, 3-Dichloropropene
ND
1.0
0.21
ug/1
108-20-3
Di -Isopropyl Ether
ND
1.0
0.24
ug/1
64-17-5
Ethyl Alcohol
ND
200
82
ug/1
100-41-4
Ethylbenzene
ND
1.0
0.36
ug/1
591-78-6
2-Hexanone
ND
10
2.0
ug/1
98-82-8
Isopropylbenzene
ND
1.0
0.22
ug/1
99-87-6
p-Isopropyltoluene
ND
1.0
0.21
ug/1
74-83-9
Methyl Bromide
ND
2.0
0.59
ug/1
74-87-3
Methyl Chloride
ND
2.0
0.50
ug/1
75-09-2
Methylene Chloride
ND
5.0
2.0
ug/1
108-10-1
4-Methyl-2-pentanone (MIBK) ND
5.0
1.0
ug/1
1634-04-4
Methyl Tert Butyl Ether
ND
1.0
0.23
ug/I
91-20-3
Naphthalene
ND
5.0
1.0
ug/I
103-65-1
n-Propylbenzene
ND
1.0
0.29
ug/I
100-42-5
Styrene
ND
1.0
0.22
ug/1
630-20-6
1, 1, 1,2-Tetrachloroethane
ND
1.0
0.28
ug/1
79-34-5
1,1,2,2-Tetrachloroethane
ND
1.0
0.30
ug/1
127-18-4
Tetrachloroethylene
ND
1.0
0.22
ug/1
108-88-3
Toluene
1.6
1.0
0.30
ug/1
87-61-6
1,2,3-Trichlorobenzene
ND
2.0
0.61
ug/1
120-82-1
1,2,4-Trichlorobenzene
ND
2.0
0.50
ug/1
71-55-6
1, 1, 1 -Trichloroethane
ND
1.0
0.25
ug/1
79-00-5
1,1,2-Trichloroethane
ND
1.0
0.47
ug/1
79-01-6
Trichloroethylene
ND
1.0
0.35
ug/1
75-69-4
Trichlorofluoromethane
ND
2.0
0.50
ug/1
96-18-4
1,2,3-Trichloropropane
ND
2.0
0.63
ug/1
95-63-6
1,2,4-Trimethylbenzene
ND
1.0
0.32
ug/1
108-67-8
1,3,5-Trimethylbenzene
ND
1.0
0.27
ug/1
108-05-4
Vinyl Acetate
ND
10
2.0
ug/1
75-01-4
Vinyl Chloride
ND
1.0
0.41
ug/1
m,p-Xylene
ND
2.0
0.47
ug/1
95-47-6
o-Xylene
ND
1.0
0.26
ug/1
1330-20-7
Xylene (total)
ND
3.0
0.72
ug/1
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
1868-53-7
Dibromofluoromethane
94%
83-118%
17060-07-0
1,2-Dichloroethane-D4
99%
79-125%
2037-26-5
Toluene-D8
103%
85-112%
460-00-4
4-Bromofluorobenzene
104%
83-118%
Page 2 of 2
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
01
31 of 62
FA75769

i
SGS
f
Orlando, FL
Section 4
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
� 32 of 62
FA75769

SGS North America Inc - Orlando F -757"
Chain of Custody SGS - ORLANDO JOB #: PAGE-1—OF-L—
.,
-• vv" TaL.aaT-4zs-67oo wFAx 407az107oT"
wwwssucom
SGS • ORLANDO Quote # SKIFF #
> a. ClientlRe Reporting Information K
Company Name: � G
Pro'ectlnformation
Project Name:
1 C � 3 :
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77
C.
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7
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AnalyticalInformation
,�
'=
Matrix Codes
nn ng
Water
GW - Ground
Watar
star
SWW Surface
SO -Soil
OI - OII
S01-oil
LIQ - Other Liquid
AIR - Air
SOL-Other Solid
Address: �+-
ZOl IJ FvOw'H' S� • S� i �-e- J
Street
City:
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Y state
oJectContact: CLH E ail: �`� t�
•P40D %ct #
Phone#; 50 t-31s0 M1tt 3
Fez#
Sampler(s)N r )(Printed)
Sam ter 1: •Yc/[' sampler 2:
Client Purchase Order It
SGS
Orlando
sample #
Field ID I Point of Collection
OLLECr10N
CONTAIN
al—MATON
LAB use ONLY
nAri..3;25K
Tue
sANxso
MATaa
TOTALa
of
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10 Dayay (Business)_O Approved By:I Date:
7 Day
5 Day
3 Day RUSH
2 Day RUSH
1 Day RUSH
Other
Rush TIA Data Available VIA Emall or Labllnk
.„ Data Deliverablelnformation�'
COMMERCIAL "A" (RESULTS ONLY)
NMMERCIAL "B" (RESULTS PLUS QC)
rL�JS REDTT (EPA LEVEL 3)
❑FULLTI (EPA LEVEL 4)
[]EDD'S
'€ CommentslR '•�,re'(.s-
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Raleigh, NC
Service Ceanter
s 'it :":T;
rplerlAffihation
Sam le Custotl ow must be dacumented beleach time sam les thane ess sion, Includingcourier delive . a:" •. :O,1
ReI ed by Sa
1
Date Time:
l5
Received By/Afflllalion
2 1
Relinquishe BylAffiliation
3
Date Time:
Re ' I2
4
fflllatlon
Reli_ uie ed-bylAffilietion
5
Date Time:
Received By/Affiliation
0
Relinquished BylAffiliation
T
Data Time:
ReceivedBy Affiliation
a
Lab USe Only: Cooler Temperature sCelsius corrected): hit nfterms-a - ndi0o
UKLU-sM-uuu—a-rursrvrcw lvl.As navwro io
FA75769: Chain of Custody
Page 1 of 2
6 33 of 62
FA75769

SGS Sample Receipt Summary
Job Number: FA75769 Client: GEOSYNTEC Project: GN7035
Date / Time Received: 6/10/2020 9:30:00 AM
[Therm ID: IR 1; 1
ler Temps (Raw Measured) °C: Cooler 1: (5.0);
Cooler Temps (Corrected) °C: Cooler 1: (4.2);
Cooler Information
Y or N
1. Custody Seals Present
❑.I ❑
2. Custody Seals Intact
❑d ❑
3. Temp criteria achieved
❑d ❑
4. Cooler temp verification
IR Gun
5. Cooler media
Ice(Bag
livery Method: FX Airbill Ws: 4913 8691 3644
;rm CIF: -0.8; # of Coolers: 1
Sample Information
Y
or N N/A
1. Sample labels present on bottles
W
❑
2. Samples preserved properly
❑d
❑
3. Sufficient volume/containers recvd for analysis:
W
❑
4. Condition of sample
Broken / Leakina
5. Sample recvd within HT
0
❑
6. Dates/Times/IDs on COC match Sample Label
0
❑
Trio Blank Information
Y or
N
N/A
7. VOCs have headspace
❑
❑.i
❑
1. Trip Blank present / cooler
❑d
❑
[
8. Bottles received for unspecified tests
❑
❑d
2. Trip Blank listed on COC
❑d
❑
[
9. Compositing instructions clear
❑
❑
k
10. Voa Soil Kits/Jars received past 48hrs?
❑
❑
❑,/
W or S
N/A
11. % Solids Jar received?
❑
❑
0
3. Type Of TB Received
❑d
❑
❑
12. Residual Chlorine Present?
❑
❑
❑,�
Misc. Information
Number of Encores: 25-Gram
5-Gram
Number of 5035 Field Kits: Number of Lab Filtered
Metals:
Test Strip Lot #s: pH 0-3
230315
pH 10-12 219813A Other: (Specify)
Residual Chlorine Test Strip Lot #:
Comments SAMPLE #1 RECEIVED 1 VIAL BROKEN
shoot Rev. Dale 05/24/17 Technician: PETERH Date: 6/10/2020 9:30:00 AM
Reviewer: Date:
FA75769: Chain of Custody
Page 2 of 2
6 34 of 62
FA75769

i
SG$
Orlando, FL
Section 5
MS Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
6 35 of 62
FA75769

Method Blank Summary
Job Number: FA75769
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 1 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
VI2085-MB
I65751.D
1
06/20/20
KB
n/a
n/a
VI2085
The QC reported here applies to the following samples: Method: SW846 8260D
FA75769-1, FA75769-2, FA75769-3, FA75769-4, FA75769-5
CAS No. Compound
Result RL MDL Units Q
67-64-1
Acetone
ND
25
10
ug/l
71-43-2
Benzene
ND
1.0
0.31
ug/l
108-86-1
Bromobenzene
ND
1.0
0.37
ug/l
74-97-5
Bromochloromethane
ND
1.0
0.45
ug/l
75-27-4
Bromodichloromethane
ND
1.0
0.24
ug/l
75-25-2
Bromoform
ND
1.0
0.41
ug/1
78-93-3
2-Butanone (MEK)
ND
5.0
2.0
ug/1
104-51-8
n-Butylbenzene
ND
1.0
0.23
ug/1
135-98-8
sec-Butylbenzene
ND
1.0
0.24
ug/l
98-06-6
tert-Butylbenzene
ND
1.0
0.31
ug/1
56-23-5
Carbon Tetrachloride
ND
1.0
0.36
ug/1
108-90-7
Chlorobenzene
ND
1.0
0.20
ug/1
75-00-3
Chloroethane
ND
2.0
0.67
ug/1
67-66-3
Chloroform
ND
1.0
0.30
ug/l
95-49-8
o-Chlorotoluene
ND
1.0
0.22
ug/l
106-43-4
p-Chlorotoluene
ND
1.0
0.31
ug/l
124-48-1
Dibromochloromethane
ND
1.0
0.28
ug/l
106-93-4
1,2-Dibromoethane
ND
2.0
0.28
ug/l
75-71-8
Dichlorodifluoromethane
ND
2.0
0.50
ug/l
95-50-1
1,2-Dichlorobenzene
ND
1.0
0.32
ug/l
541-73-1
1,3-Dichlorobenzene
ND
1.0
0.22
ug/l
106-46-7
1,4-Dichlorobenzene
ND
1.0
0.26
ug/l
75-34-3
1, 1 -Dichloroethane
ND
1.0
0.34
ug/1
107-06-2
1,2-Dichloroethane
ND
1.0
0.31
ug/1
75-35-4
1, 1 -Dichloroethylene
ND
1.0
0.32
ug/1
156-59-2
cis- 1, 2-Dichloroethylene
ND
1.0
0.28
ug/l
156-60-5
trans- 1, 2-Dichloroethylene
ND
1.0
0.22
ug/l
78-87-5
1,2-Dichloropropane
ND
1.0
0.43
ug/1
142-28-9
1,3-Dichloropropane
ND
1.0
0.31
ug/1
594-20-7
2,2-Dichloropropane
ND
1.0
0.24
ug/l
563-58-6
1, 1 -Dichloropropene
ND
1.0
0.34
ug/l
10061-01-5 cis- 1, 3-Dichloropropene
ND
1.0
0.29
ug/l
10061-02-6 trans- 1, 3-Dichloropropene
ND
1.0
0.21
ug/l
108-20-3
Di -Isopropyl Ether
ND
1.0
0.24
ug/l
64-17-5
Ethyl Alcohol
ND
200
82
ug/l
100-41-4
Ethlbenzene
ND
1.0
0.36
ug/l
6 36 of 62
FA75769

Method Blank Summary
Job Number: FA75769
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 2 of 3
ample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batcl
T12085-MB
I65751.D
1
06/20/20
KB
n/a
n/a
VI2085
The QC reported here applies to the following samples: Method: SW846 8260D
FA75769-1, FA75769-2, FA75769-3, FA75769-4, FA75769-5
CAS No. Compound Result RL MDL Units Q
591-78-6
2-Hexanone
ND
10
2.0
ug/l
98-82-8
Isopropylbenzene
ND
1.0
0.22
ug/l
99-87-6
p-Isopropyltoluene
ND
1.0
0.21
ug/l
74-83-9
Methyl Bromide
ND
2.0
0.59
ug/l
74-87-3
Methyl Chloride
ND
2.0
0.50
ug/l
75-09-2
Methylene Chloride
ND
5.0
2.0
ug/1
108-10-1
4-Methyl-2-pentanone (MIBK) ND
5.0
1.0
ug/1
1634-04-4
Methyl Tert Butyl Ether
ND
1.0
0.23
ug/1
91-20-3
Naphthalene
ND
5.0
1.0
ug/l
103-65-1
n-Propylbenzene
ND
1.0
0.29
ug/1
100-42-5
Styrene
ND
1.0
0.22
ug/1
630-20-6
1, 1, 1, 2-Tetrachloroethane
ND
1.0
0.28
ug/1
79-34-5
1,1,2,2-Tetrachloroethane
ND
1.0
0.30
ug/1
127-18-4
Tetrachloroethylene
ND
1.0
0.22
ug/l
108-88-3
Toluene
ND
1.0
0.30
ug/l
87-61-6
1,2,3-Trichlorobenzene
ND
2.0
0.61
ug/l
120-82-1
1,2,4-Trichlorobenzene
ND
2.0
0.50
ug/l
71-55-6
1, 1, 1 -Trichloroethane
ND
1.0
0.25
ug/l
79-00-5
1,1,2-Trichloroethane
ND
1.0
0.47
ug/l
79-01-6
Trichloroethylene
ND
1.0
0.35
ug/l
75-69-4
Trichlorofluoromethane
ND
2.0
0.50
ug/l
96-18-4
1, 2,3 -Trichloropropane
ND
2.0
0.63
ug/l
95-63-6
1,2,4-Trimethylbenzene
ND
1.0
0.32
ug/1
108-67-8
1,3,5-Trimethylbenzene
ND
1.0
0.27
ug/1
108-05-4
Vinyl Acetate
ND
10
2.0
ug/1
75-01-4
Vinyl Chloride
ND
1.0
0.41
ug/l
m,p-Xylene
ND
2.0
0.47
ug/l
95-47-6
o-Xylene
ND
1.0
0.26
ug/1
1330-20-7
Xylene (total)
ND
3.0
0.72
ug/1
CAS No.
Surrogate Recoveries
Limits
1868-53-7
Dibromofluoromethane
95%
83-118%
17060-07-0
1,2-Dichloroethane-D4
97%
79-125%
2037-26-5
Toluene-D8
102%
85-112%
6 37 of 62
FA75769

Method Blank Summary
Job Number: FA75769
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 3 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
VI2085-MB
I65751.D
1
06/20/20
KB
n/a
n/a
VI2085
The QC reported here applies to the following samples: Method: SW846 8260D
FA75769-1, FA75769-2, FA75769-3, FA75769-4, FA75769-5
CAS No. Surrogate Recoveries Limits
460-00-4 4-Bromofluorobenzene 104% 83-118%
6 38 of 62
FA75769

Blank Spike Summary
Job Number: FA75769
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 1 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
VI2085-BS
I65749.D
1
06/20/20
KB
n/a
n/a
VI2085
The QC reported here applies to the following samples: Method: SW846 8260B
FA75769-1, FA75769-2, FA75769-3, FA75769-4, FA75769-5
CAS No. Compound
Spike BSP BSP
ug/l ug/l % Limits
67-64-1
Acetone
125
107
86
50-147
71-43-2
Benzene
25
23.6
94
81-122
108-86-1
Bromobenzene
25
23.4
94
80-121
74-97-5
Bromochloromethane
25
22.1
88
76-123
75-27-4
Bromodichloromethane
25
23.5
94
79-123
75-25-2
Bromoform
25
20.2
81
66-123
78-93-3
2-Butanone (MEK)
125
103
82
56-143
104-51-8
n-Butylbenzene
25
27.2
109
79-126
135-98-8
sec-Butylbenzene
25
27.4
110
83-133
98-06-6
tert-Butylbenzene
25
25.9
104
80-133
56-23-5
Carbon Tetrachloride
25
27.0
108
76-136
108-90-7
Chlorobenzene
25
23.6
94
82-124
75-00-3
Chloroethane
25
24.5
98
62-144
67-66-3
Chloroform
25
23.4
94
80-124
95-49-8
o-Chlorotoluene
25
24.5
98
81-127
106-43-4
p-Chlorotoluene
25
24.7
99
83-130
124-48-1
Dibromochloromethane
25
22.4
90
78-122
106-93-4
1,2-Dibromoethane
25
21.7
87
75-120
75-71-8
Dichlorodifluoromethane
25
32.9
132
42-167
95-50-1
1,2-Dichlorobenzene
25
23.1
92
82-124
541-73-1
1,3-Dichlorobenzene
25
24.3
97
84-125
106-46-7
1,4-Dichlorobenzene
25
22.8
91
78-120
75-34-3
1, 1 -Dichloroethane
25
23.6
94
81-122
107-06-2
1,2-Dichloroethane
25
22.3
89
75-125
75-35-4
1, 1 -Dichloroethylene
25
25.6
102
78-137
156-59-2
cis- 1, 2-Dichloroethylene
25
23.3
93
78-120
156-60-5
trans- 1, 2-Dichloroethylene
25
24.9
100
76-127
78-87-5
1,2-Dichloropropane
25
24.0
96
76-124
142-28-9
1,3-Dichloropropane
25
21.4
86
80-118
594-20-7
2,2-Dichloropropane
25
25.1
100
74-139
563-58-6
1, 1 -Dichloropropene
25
26.5
106
79-131
10061-01-5 cis- 1, 3-Dichloropropene
25
23.6
94
75-118
10061-02-6 trans- 1, 3-Dichloropropene
25
23.2
93
80-120
108-20-3
Di -Isopropyl Ether
25
23.1
92
68-123
64-17-5
Ethyl Alcohol
500
566
113
46-145
100-41-4
Ethlbenzene
25
24.5
98
81-121
* = Outside of Control Limits.
6 39 of 62
FA75769

Blank Spike Summary
Job Number: FA75769
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 2 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
VI2085-BS
I65749.D
1
06/20/20
KB
n/a
n/a
VI2085
The QC reported here applies to the following samples: Method: SW846 8260B
FA75769-1, FA75769-2, FA75769-3, FA75769-4, FA75769-5
CAS No. Compound
Spike BSP BSP
ug/l ug/l % Limits
591-78-6
2-Hexanone
125
96.4
77
61-129
98-82-8
Isopropylbenzene
25
25.7
103
83-132
99-87-6
p-Isopropyltoluene
25
27.0
108
79-130
74-83-9
Methyl Bromide
25
29.7
119
59-143
74-87-3
Methyl Chloride
25
22.1
88
50-159
75-09-2
Methylene Chloride
25
23.0
92
69-135
108-10-1
4-Methyl-2-pentanone (MIBK) 125
94.3
75
66-122
1634-04-4
Methyl Tert Butyl Ether
25
21.3
85
72-117
91-20-3
Naphthalene
25
20.0
80
63-132
103-65-1
n-Propylbenzene
25
25.7
103
82-133
100-42-5
Styrene
25
25.0
100
78-119
630-20-6
1, 1, 1, 2-Tetrachloroethane
25
24.4
98
77-122
79-34-5
1,1,2,2-Tetrachloroethane
25
21.1
84
72-120
127-18-4
Tetrachloroethylene
25
24.5
98
76-135
108-88-3
Toluene
25
23.7
95
80-120
87-61-6
1,2,3-Trichlorobenzene
25
21.4
86
68-131
120-82-1
1,2,4-Trichlorobenzene
25
23.2
93
73-129
71-55-6
1, 1, 1 -Trichloroethane
25
24.9
100
75-130
79-00-5
1,1,2-Trichloroethane
25
21.9
88
76-119
79-01-6
Trichloroethylene
25
24.5
98
81-126
75-69-4
Trichlorofluoromethane
25
30.0
120
71-156
96-18-4
1, 2,3 -Trichloropropane
25
20.0
80
77-120
95-63-6
1,2,4-Trimethylbenzene
25
24.5
98
79-120
108-67-8
1,3,5-Trimethylbenzene
25
25.6
102
79-120
108-05-4
Vinyl Acetate
125
96.1
77
43-154
75-01-4
Vinyl Chloride
25
24.6
98
69-159
m,p-Xylene
50
49.7
99
79-126
95-47-6
o-Xylene
25
24.5
98
80-127
1330-20-7
Xylene (total)
75
74.2
99
80-126
CAS No.
Surrogate Recoveries
BSP
Limits
1868-53-7
Dibromofluoromethane
99%
83-118%
17060-07-0
1,2-Dichloroethane-D4
98%
79-125%
2037-26-5
Toluene-D8
101%
85-112%
* = Outside of Control Limits.
6 40 of 62
FA75769

Blank Spike Summary
Job Number: FA75769
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 3 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
VI2085-BS
I65749.D
1
06/20/20
KB
n/a
n/a
VI2085
The QC reported here applies to the following samples: Method: SW846 8260B
FA75769-1, FA75769-2, FA75769-3, FA75769-4, FA75769-5
CAS No. Surrogate Recoveries BSP Limits
460-00-4 4-Bromofluorobenzene 100% 83-118%
* = Outside of Control Limits.
6 41 of 62
FA75769

Matrix Spike/Matrix Spike Duplicate Summary
Job Number: FA75769
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 1 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
FA75958-7MS
I65772.D
10
06/20/20
KB
n/a
n/a
VI2085
FA75958-7MSD
I65773.1)
10
06/20/20
KB
n/a
n/a
VI2085
FA75958-7 a
I65771.D
10
06/20/20
KB
n/a
n/a
VI2085
The QC reported here applies to the following samples:
FA75769-1, FA75769-2, FA75769-3, FA75769-4, FA75769-5
CAS No. Compound
FA75958-7 Spike MS
ug/1 Q ug/l ug/l
Method: SW846 8260D
MS Spike MSD MSD Limits
% ug/l ug/l % RPD Rec/RPD
67-64-1
Acetone
ND
1250
1290
103
1250
1230
98
5
50-147/21
71-43-2
Benzene
ND
250
270
108
250
265
106
2
81-122/14
108-86-1
Bromobenzene
ND
250
261
104
250
258
103
1
80-121/14
74-97-5
Bromochloromethane
ND
250
250
100
250
244
98
2
76-123/14
75-27-4
Bromodichloromethane
ND
250
269
108
250
265
106
1
79-123/19
75-25-2
Bromoform
ND
250
233
93
250
234
94
0
66-123/21
78-93-3
2-Butanone(MEK)
ND
1250
1350
108
1250
1310
105
3
56-143/18
104-51-8
n-Butylbenzene
ND
250
288
115
250
284
114
1
79-126/16
135-98-8
sec-Butylbenzene
ND
250
300
120
250
296
118
1
83-133/16
98-06-6
tert-Butylbenzene
ND
250
286
114
250
282
113
1
80-133/16
56-23-5
Carbon Tetrachloride
ND
250
286
114
250
288
115
1
76-136/23
108-90-7
Chlorobenzene
ND
250
262
105
250
259
104
1
82-124/14
75-00-3
Chloroethane
ND
250
305
122
250
288
115
6
62-144/20
67-66-3
Chloroform
6.6
J 250
272
106
250
267
104
2
80-124/15
95-49-8
o-Chlorotoluene
ND
250
273
109
250
269
108
1
81-127/15
106-43-4
p-Chlorotoluene
ND
250
273
109
250
270
108
1
83-130/15
124-48-1
Dibromochloromethane
ND
250
257
103
250
258
103
0
78-122/19
106-93-4
1,2-Dibromoethane
ND
250
256
102
250
255
102
0
75-120/13
75-71-8
Dichlorodifluoromethane
ND
250
393
157
250
378
151
4
42-167/19
95-50-1
1,2-Dichlorobenzene
ND
250
262
105
250
255
102
3
82-124/14
541-73-1
1,3-Dichlorobenzene
ND
250
269
108
250
263
105
2
84-125/14
106-46-7
1,4-Dichlorobenzene
ND
250
253
101
250
248
99
2
78-120/15
75-34-3
1, 1 -Dichloroethane
ND
250
267
107
250
264
106
1
81-122/15
107-06-2
1,2-Dichloroethane
ND
250
258
103
250
256
102
1
75-125/14
75-35-4
1, 1 -Dichloroethylene
ND
250
281
112
250
278
111
1
78-137/18
156-59-2
cis- 1, 2-Dichloroethylene
ND
250
258
103
250
253
101
2
78-120/15
156-60-5
trans- 1, 2-Dichloroethylene
ND
250
273
109
250
273
109
0
76-127/17
78-87-5
1,2-Dichloropropane
ND
250
272
109
250
269
108
1
76-124/14
142-28-9
1,3-Dichloropropane
ND
250
257
103
250
253
101
2
80-118/13
594-20-7
2,2-Dichloropropane
ND
250
230
92
250
229
92
0
74-139/17
563-58-6
1, 1 -Dichloropropene
ND
250
290
116
250
290
116
0
79-131/16
10061-01-5 cis- 1, 3-Dichloropropene
ND
250
256
102
250
254
102
1
75-118/23
10061-02-6 trans- 1, 3-Dichloropropene
ND
250
259
104
250
259
104
0
80-120/22
108-20-3
Di -Isopropyl Ether
ND
250
269
108
250
265
106
1
68-123/16
64-17-5
Ethyl Alcohol
ND
5000
5960
119
5000
5580
112
7
46-145/30
100-41-4
Ethylbenzene
ND
250
274
110
250
269
108
2
81-121/14
* = Outside of Control Limits.
01
42 of 62
FA75769

Matrix Spike/Matrix Spike Duplicate Summary
Job Number: FA75769
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 2 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
FA75958-7MS
I65772.D
10
06/20/20
KB
n/a
n/a
VI2085
FA75958-7MSD
I65773.1)
10
06/20/20
KB
n/a
n/a
VI2085
FA75958-7 a
I65771.D
10
06/20/20
KB
n/a
n/a
VI2085
The QC reported here applies to the following samples:
FA75769-1, FA75769-2, FA75769-3, FA75769-4, FA75769-5
CAS No. Compound
591-78-6
98-82-8
99-87-6
74-83-9
74-87-3
75-09-2
108-10-1
1634-04-4
91-20-3
103-65-1
100-42-5
630-20-6
79-34-5
127-18-4
108-88-3
87-61-6
120-82-1
71-55-6
79-00-5
79-01-6
75-69-4
96-18-4
95-63-6
108-67-8
108-05-4
75-01-4
95-47-6
1330-20-7
CAS No.
FA75958-7 Spike MS
ug/l Q ug/l ug/l
Method: SW846 8260D
MS Spike MSD MSD Limits
% ug/l ug/l % RPD Rec/RPD
2-Hexanone
ND
1250
1350
108
1250
1300
104
4
61-129/18
Isopropylbenzene
ND
250
285
114
250
282
113
1
83-132/15
p-Isopropyltoluene
3.7
J 250
300
119
250
295
117
2
79-130/16
Methyl Bromide
ND
250
193
77
250
232
93
18
59-143/19
Methyl Chloride
ND
250
279
112
250
272
109
3
50-159/19
Methylene Chloride
ND
250
266
106
250
262
105
2
69-135/16
4-Methyl-2-pentanone (MIBK) ND
1250
1310
105
1250
1270
102
3
66-122/16
Methyl Tert Butyl Ether
839
250
1180
136* b
250
1150
124* b
3
72-117/14
Naphthalene
ND
250
266
106
250
260
104
2
63-132/25
n-Propylbenzene
ND
250
282
113
250
279
112
1
82-133/15
Styrene
ND
250
280
112
250
273
109
3
78-119/23
1, 1, 1, 2-Tetrachloroethane
ND
250
274
110
250
271
108
1
77-122/19
1,1,2,2-Tetrachloroethane
ND
250
264
106
250
265
106
0
72-120/14
Tetrachloroethylene
ND
250
265
106
250
261
104
2
76-135/16
Toluene
ND
250
266
106
250
262
105
2
80-120/14
1,2,3-Trichlorobenzene
ND
250
264
106
250
256
102
3
68-131/25
1,2,4-Trichlorobenzene
ND
250
263
105
250
257
103
2
73-129/20
1, 1, 1 -Trichloroethane
ND
250
273
109
250
271
108
1
75-130/16
1,1,2-Trichloroethane
ND
250
263
105
250
259
104
2
76-119/14
Trichloroethylene
ND
250
268
107
250
265
106
1
81-126/15
Trichlorofluoromethane
ND
250
369
148
250
356
142
4
71-156/21
1, 2,3 -Trichloropropane
ND
250
249
100
250
247
99
1
77-120/16
1,2,4-Trimethylbenzene
ND
250
271
108
250
266
106
2
79-120/18
1, 3,5 -Trimethylbenzene
ND
250
280
112
250
278
111
1
79-120/19
Vinyl Acetate
ND
1250
1190
95
1250
1140
91
4
43-154/14
Vinyl Chloride
ND
250
301
120
250
289
116
4
69-159/18
m,p-Xylene
ND
500
557
111
500
546
109
2
79-126/15
o-Xylene
ND
250
276
110
250
271
108
2
80-127/14
Xylene (total)
ND
750
833
111
750
817
109
2
80-126/15
Surrogate Recoveries MS
1868-53-7 Dibromofluoromethane 99%
17060-07-0 1,2-Dichloroethane-D4 98%
2037-26-5 Toluene-D8 100%
* = Outside of Control Limits.
MSD FA75958-7 Limits
99% 95% 83-118%
99% 99% 79-125%
101% 102% 85-112%
6 43 of 62
FA75769

Matrix Spike/Matrix Spike Duplicate Summary Page 3 of 3
Job Number: FA75769
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
FA75958-7MS
I65772.D
10
06/20/20
KB
n/a
n/a
VI2085
FA75958-7MSD
I65773.1)
10
06/20/20
KB
n/a
n/a
VI2085
FA75958-7 a
I65771.D
10
06/20/20
KB
n/a
n/a
VI2085
The QC reported here applies to the following samples:
FA75769-1, FA75769-2, FA75769-3, FA75769-4, FA75769-5
CAS No. Surrogate Recoveries MS MSD FA75958-7 Limits
460-00-4 4-Bromofluorobenzene 99% 99% 102% 83-118%
(a) Confirmation run.
(b) Outside control limits due to high level in sample relative to spike amount.
* = Outside of Control Limits.
Method: SW846 8260D
6 44 of 62
FA75769

ffm
Orlando, FL
MS Semi-volatiles
QC Data Summaries
;ME
i
Section 6
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
0
6 45 of 62
FA75769

Method Blank Summary
Job Number: FA75769
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 1 of 2
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
DP80648-MB
61706215.1)
1
06/24/20
MV
06/13/20
OP80648
S617241
The QC reported here applies to the following samples: Method: SW846 8270E
FA75769-1, FA75769-2, FA75769-3, FA75769-4
CAS No. Compound
Result RL MDL Units Q
65-85-0
Benzoic Acid
ND
50
10
ug/l
59-50-7
4-Chloro-3-methyl Phenol
ND
5.0
0.59
ug/l
95-57-8
2-Chlorophenol
ND
5.0
0.63
ug/l
120-83-2
2,4-Dichlorophenol
ND
5.0
0.84
ug/l
105-67-9
2,4-Dimethylphenol
ND
5.0
0.74
ug/l
51-28-5
2,4-Dinitrophenol
ND
25
5.0
ug/1
534-52-1
4,6-Dinitro-o-cresol
ND
10
2.0
ug/1
95-48-7
2-Methylphenol
ND
5.0
0.56
ug/1
3&4-Methylphenol
ND
5.0
0.98
ug/l
88-75-5
2-Nitrophenol
ND
5.0
0.85
ug/1
100-02-7
4-Nitrophenol
ND
25
5.0
ug/1
87-86-5
Pentachlorophenol
ND
25
5.0
ug/1
108-95-2
Phenol
ND
5.0
0.50
ug/1
88-06-2
2,4,6-Trichlorophenol
ND
5.0
0.75
ug/l
83-32-9
Acenaphthene
ND
5.0
0.63
ug/l
208-96-8
Acenaphthylene
ND
5.0
0.64
ug/l
120-12-7
Anthracene
ND
5.0
0.80
ug/l
56-55-3
Benzo(a)anthracene
ND
5.0
0.76
ug/l
50-32-8
Benzo(a)pyrene
ND
5.0
0.78
ug/l
205-99-2
Benzo(b)fluoranthene
ND
5.0
0.78
ug/l
191-24-2
Benzo(g,h,i)perylene
ND
5.0
0.82
ug/l
207-08-9
Benzo(k)fluoranthene
ND
5.0
0.86
ug/l
100-51-6
Benzyl Alcohol
ND
5.0
0.61
ug/1
101-55-3
4-Bromophenyl Phenyl Ether
ND
5.0
0.85
ug/1
85-68-7
Butyl Benzyl Phthalate
ND
5.0
1.0
ug/1
106-47-8
4-Chloroaniline
ND
5.0
0.63
ug/l
111-91-1
bis(2-Chloroethoxy)methane
ND
5.0
0.81
ug/l
111-44-4
bis(2-Chloroethyl)ether
ND
5.0
0.73
ug/1
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
5.0
0.76
ug/1
91-58-7
2-Chloronaphthalene
ND
5.0
0.50
ug/l
7005-72-3
4-Chlorophenyl Phenyl Ether
ND
5.0
0.54
ug/l
218-01-9
Chrysene
ND
5.0
0.85
ug/l
53-70-3
Dibenzo(a,h)anthracene
ND
5.0
0.80
ug/l
132-64-9
Dibenzofuran
ND
5.0
0.60
ug/l
95-50-1
1,2-Dichlorobenzene
ND
5.0
0.50
ug/l
541-73-1
1,3-Dichlorobenzene
ND
5.0
0.50
ug/l
6 46 of 62
FA75769

Method Blank Summary
Job Number: FA75769
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 2 of 2
ample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batcl
)P80648-MB
61706215.1)
1
06/24/20
MV
06/13/20
OP80648
S617241
The QC reported here applies to the following samples: Method: SW846 8270E
FA75769-1, FA75769-2, FA75769-3, FA75769-4
CAS No. Compound
106-46-7
1,4-Dichlorobenzene
91-94-1
3, 3'-Dichlorobenzidine
84-66-2
Diethyl Phthalate
131-11-3
Dimethyl Phthalate
84-74-2
Di-n-butyl Phthalate
117-84-0
Di-n-octyl Phthalate
122-66-7
1, 2-Diphenylhydrazine
117-81-7
bis(2-Ethylhexyl)phthalate
206-44-0
Fluoranthene
86-73-7
Fluorene
118-74-1
Hexachlorobenzene
87-68-3
Hexachlorobutadiene
77-47-4
Hexachlorocyclopentadiene
67-72-1
Hexachloroethane
193-39-5
Indeno(1,2,3-cd)pyrene
78-59-1
Isophorone
90-12-0
1-M ethylnaphthalene
91-57-6
2-Methylnaphthalene
91-20-3
Naphthalene
98-95-3
Nitrobenzene
621-64-7
N-Nitrosodi-n-propylamine
86-30-6
N-Nitrosodiphenylamine
85-01-8
Phenanthrene
129-00-0
Pyrene
120-82-1
1,2,4-Trichlorobenzene
CAS No. Surrogate Recoveries
367-12-4 2-Fluorophenol
4165-62-2 Phenol-d5
118-79-6 2,4,6-Tribromophenol
4165-60-0 Nitrobenzene-d5
321-60-8 2-Fluorobiphenyl
1718-51-0 Terphenyl-d14
Result
RL
MDL
Units Q
ND
5.0
0.50
ug/l
ND
5.0
0.64
ug/l
ND
5.0
1.0
ug/l
ND
5.0
1.0
ug/l
ND
5.0
1.0
ug/l
ND
5.0
1.0
ug/1
ND
5.0
0.76
ug/1
ND
5.0
1.0
ug/1
ND
5.0
0.55
ug/l
ND
5.0
0.70
ug/1
ND
5.0
0.69
ug/1
ND
5.0
0.50
ug/1
ND
5.0
1.8
ug/1
ND
5.0
1.6
ug/l
ND
5.0
0.71
ug/l
ND
5.0
0.78
ug/l
ND
5.0
0.53
ug/l
ND
5.0
0.60
ug/l
ND
5.0
0.50
ug/l
ND
5.0
0.93
ug/l
ND
5.0
0.67
ug/l
ND
5.0
0.81
ug/l
ND
5.0
0.86
ug/1
ND
5.0
0.68
ug/1
ND
5.0
1.1
ug/1
Limits
33%
14-67%
23%
10-50%
87%
33-118%
66%
42-108%
78%
40-106%
76%
39-121%
6 47 of 62
FA75769

Blank Spike Summary
Job Number: FA75769
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 1 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
OP80648-BS a
61706214.13
1
06/24/20
MV
06/13/20
OP80648
S617241
The QC reported here applies to the following samples:
FA75769-1, FA75769-2, FA75769-3, FA75769-4
Spike
BSP
BSP
CAS No.
Compound
ug/1
ug/l
%
Limits
65-85-0
Benzoic Acid
100
32.9
33
10-69
59-50-7
4-Chloro-3-methyl Phenol
50
39.9
80
54-103
95-57-8
2-Chlorophenol
50
30.8
62
52-98
120-83-2
2,4-Dichlorophenol
50
36.2
72
53-103
105-67-9
2,4-Dimethylphenol
50
40.5
81
43-90
51-28-5
2,4-Dinitrophenol
100
69.5
70
44-112
534-52-1
4,6-Dinitro-o-cresol
100
67.6
68
66-121
95-48-7
2-Methylphenol
50
25.3
51
43-90
3&4-Methylphenol
100
50.2
50
36-88
88-75-5
2-Nitrophenol
50
47.4
95
53-102
100-02-7
4-Nitrophenol
100
32.7
33
18-62
87-86-5
Pentachlorophenol
100
84.9
85
61-115
108-95-2
Phenol
50
14.0
28
19-56
88-06-2
2,4,6-Trichlorophenol
50
35.9
72
59-107
83-32-9
Acenaphthene
50
32.2
64
61-107
208-96-8
Acenaphthylene
50
39.9
80
60-104
120-12-7
Anthracene
50
38.4
77
65-108
56-55-3
Benzo(a)anthracene
50
41.6
83
66-111
50-32-8
Benzo(a)pyrene
50
39.9
80
62-107
205-99-2
Benzo(b)fluoranthene
50
45.2
90
65-114
191-24-2
Benzo(g,h,i)perylene
50
48.2
96
66-116
207-08-9
Benzo(k)fluoranthene
50
42.0
84
65-114
100-51-6
Benzyl Alcohol
50
28.0
56
46-94
101-55-3
4-BromophenylPhenyl Ether
50
37.7
75
65-109
85-68-7
Butyl Benzyl Phthalate
50
35.7
71
65-112
106-47-8
4-Chloroaniline
50
38.2
76
49-105
111-91-1
bis(2-Chloroethoxy)methane
50
38.4
77
51-102
111-44-4
bis(2-Chloroethyl)ether
50
33.7
67
53-100
108-60-1
2,2'-Oxybis(1-chloropropane)
50
35.7
71
45-106
91-58-7
2-Chloronaphthalene
50
35.8
72
57-103
7005-72-3
4-Chlorophenyl Phenyl Ether
50
32.4
65
62-105
218-01-9
Chrysene
50
41.9
84
66-111
53-70-3
Dibenzo(a,h)anthracene
50
50.9
102
66-119
132-64-9
Dibenzofuran
50
41.1
82
61-106
95-50-1
1,2-Dichlorobenzene
50
34.3
69
48-97
541-73-1
1,3-Dichlorobenzene
50
34.2
68
45-95
* = Outside of Control Limits.
Method: SW846 8270E
6 48 of 62
FA75769

Blank Spike Summary
Job Number: FA75769
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 2 of 3
ample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batcl
)P80648-13S a
61706214.13
1
06/24/20
MV
06/13/20
OP80648
S617241
The QC reported here applies to the following samples:
FA75769-1, FA75769-2, FA75769-3, FA75769-4
Spike
BSP
BSP
CAS No.
Compound
ug/l
ug/l
%
Limits
106-46-7
1,4-Dichlorobenzene
50
34.3
69
45-98
91-94-1
3,3'-Dichlorobenzidine
50
43.7
87
46-117
84-66-2
Diethyl Phthalate
50
40.7
81
64-108
131-11-3
Dimethyl Phthalate
50
36.0
72
63-106
84-74-2
Di-n-butyl Phthalate
50
31.0
62*
65-107
117-84-0
Di-n-octyl Phthalate
50
42.2
84
62-118
122-66-7
1,2-Diphenylhydrazine
50
26.6
53*
61-110
117-81-7
bis(2-Ethylhexyl)phthalate
50
40.9
82
61-117
206-44-0
Fluoranthene
50
30.9
62*
63-106
86-73-7
Fluorene
50
31.6
63
62-108
118-74-1
Hexachlorobenzene
50
37.8
76
63-108
87-68-3
Hexachlorobutadiene
50
46.8
94
42-102
77-47-4
Hexachlorocyclopentadiene
50
28.4
57
39-102
67-72-1
Hexachloroethane
50
32.3
65
42-100
193-39-5
Indeno(1,2,3-cd)pyrene
50
51.8
104
64-119
78-59-1
Isophorone
50
38.7
77
43-87
90-12-0
1-Methylnaphthalene
50
46.0
92
53-102
91-57-6
2-Methylnaphthalene
50
42.8
86
51-102
91-20-3
Naphthalene
50
38.2
76
47-100
98-95-3
Nitrobenzene
50
43.3
87
50-104
621-64-7
N-Nitrosodi-n-propylamine
50
36.6
73
52-104
86-30-6
N-Nitrosodiphenylamine
50
28.7
57*
64-108
85-01-8
Phenanthrene
50
39.2
78
66-110
129-00-0
Pyrene
50
30.8
62*
64-113
120-82-1
1,2,4-Trichlorobenzene
50
38.2
76
45-97
CAS No.
Surrogate Recoveries
BSP
Limits
367-12-4
2-Fluorophenol
32%
14-67%
4165-62-2
Phenol-d5
26%
10-50%
118-79-6
2,4,6-Tribromophenol
71%
33-118%
4165-60-0
Nitrobenzene-d5
81%
42-108%
321-60-8
2-Fluorobiphenyl
75%
40-106%
1718-51-0
Terphenyl-d14
60%
39-121%
* = Outside of Control Limits.
Method: SW846 8270E
6 49 of 62
FA75769

Blank Spike Summary
Job Number: FA75769
Account: GSYNNCW Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
Page 3 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
OP80648-BS a
61706214.13
1
06/24/20
MV
06/13/20
OP80648
S617241
The QC reported here applies to the following samples: Method: SW846 8270E
FA75769-1, FA75769-2, FA75769-3, FA75769-4
(a) Insufficient sample for MS/MSD.
* = Outside of Control Limits.
6 50 of 62
FA75769

SG$
Orlando, FL
Metals Analysis
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Matrix Spike and Duplicate Summaries
• Blank Spike and Lab Control Sample Summaries
• Serial Dilution Summaries
i
Section 7
6 51 of 62
FA75769

BLANK RESULTS SUMMARY
Part 2 - Method Blanks
Login Number: FA75769
Account: GSYNNCW - Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
QC Batch ID: MP37370 Methods: SW846 7470A
Matrix Type: AQUEOUS Units: ug/l
Prep Date:
MB
letal RL IDL MDL raw final
Mercury 0.50 .03 .03 0.044 <0.50
Associated samples MP37370: FA75769-1, FA75769-2, FA75769-3, FA75769-4
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
V
N
Page 1
6 52 of 62
FA75769

MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA75769
Account: GSYNNCW - Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
QC Batch ID: MP37370 Methods: SW846 7470A
Matrix Type: AQUEOUS Units: ug/l
Prep Date:
FA75717-3F QC FA75717-3F Spikelot QC
etal Original DUP RPD Limits Original MS HGFLWSI % Rec Limits
Mercury 0.049 0.043 13.0 0-20 0.049 2.3 3 75.ON(a) 80-120
Associated samples MP37370: FA75769-1, FA75769-2, FA75769-3, FA75769-4
Results < IDL are shown as zero for calculation purposes V
(*) Outside of QC limits
i
(N) Matrix Spike Rec. outside of QC limits IV
(anr) Analyte not requested
(a) Spike recovery indicates possible matrix interference.
Page 1
6 53 of 62
FA75769

MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA75769
Account: GSYNNCW - Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
QC Batch ID: MP37370 Methods: SW846 7470A
Matrix Type: AQUEOUS Units: ug/l
Prep Date:
FA75717-3F Spikelot MSD QC
letal Original MSD HGFLWSl % Rec RPD Limit
Mercury 0.049 2.4 3 78.4N(a) 4.3 20
Associated samples MP37370: FA75769-1, FA75769-2, FA75769-3, FA75769-4
Results < IDL are shown as zero for calculation purposes V
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits IV
(anr) Analyte not requested
(a) Spike recovery indicates possible matrix interference.
Page 2
6 54 of 62
FA75769

SPIKE BLANK AND LAB CONTROL SAMPLE SUMMARY
Login Number: FA75769
Account: GSYNNCW - Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
QC Batch ID: MP37370 Methods: SW846 7470A
Matrix Type: AQUEOUS Units: ug/l
Prep Date:
BSP Spikelot QC
letal Result HGFLWSI o Rec Limits
Mercury 3.1 3 103.3 80-120
Associated samples MP37370: FA75769-1, FA75769-2, FA75769-3, FA75769-4
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
V
W
Page 1
6 55 of 62
FA75769

SERIAL DILUTION RESULTS SUMMARY
Login Number: FA75769
Account: GSYNNCW - Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
QC Batch ID: MP37370 Methods: SW846 7470A
Matrix Type: AQUEOUS Units: ug/l
Prep Date:
FA75717-3F QC
letal Original SDL 1:5 oDIF Limits
Mercury 0.0491 0.00 100.0(a) 0-10
Associated samples MP37370: FA75769-1, FA75769-2, FA75769-3, FA75769-4
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
(a) Percent difference acceptable due to low initial sample concentration (< 50 times IDL).
V
i
Page 1
6 56 of 62
FA75769

BLANK RESULTS SUMMARY
Part 2 - Method Blanks
Login Number: FA75769
Account: GSYNNCW - Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
QC Batch ID: MP37417 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date:
MB MB
Metal RL IDL MDL raw final raw final
Aluminum
200
14
14
Antimony
6.0
1
1
Arsenic
10
1.3
1.3
-2.9
<10
-2.6
<10
Barium
200
1
1
-0.10
<200
0.10
<200
Beryllium
4.0
.2
.2
Cadmium
5.0
.2
.2
-0.080
<5.0
-0.070
<5.0
Calcium
1000
50
50
Chromium
10
1
1
0.10
<10
-0.10
<10
Cobalt
50
.2
.2
Copper
25
1
1
Iron
300
17
17
Lead
5.0
1
1.1
-0.30
<5.0
0.0
<5.0
Magnesium
5000
35
35
Manganese
15
.5
1
Molybdenum
50
.3
.3
Nickel
40
.4
.4
Potassium
10000
200
200
Selenium
10
2.4
2.9
0.10
<10
-0.30
<10
Silver
10
.7
.7
-0.80
<10
-0.40
<10
Sodium
10000
500
500
Strontium
10
.5
.5
Thallium
10
1.1
1.4
Tin
50
.9
1
Titanium
10
.5
1
Vanadium
50
.5
.6
Zinc
20
3
4.4
Associated samples
MP37417:
FA75769-1,
FA75769-2,
FA75769-3,
FA75769-4
Results < IDL
are shown
as
zero for calculation
purposes
(*) Outside of
QC limits
(anr) Analyte
not requested
V
N
Page 1
6 57 of 62
FA75769

MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA75769
Account: GSYNNCW - Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
QC Batch ID: MP37417 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date:
FA75765-2F QC FA75765-2F Spikelot QC
Metal Original DUP RPD Limits Original MS MPFLICP2 % Rec Limits
Aluminum
Antimony
Arsenic 0.0 0.0 NC 0-20 0.0 1800 2000 90.0 80-120
Barium 57.1 58.4 2.3 0-20 57.1 2080 2000 101.1 80-120
Beryllium
Cadmium 0.0 0.0 NC 0-20 0.0 47.5 50
Calcium
Chromium 0.0 0.0 NC 0-20 0.0 202 200
Cobalt
Copper
Iron
Lead 0.0 0.0 NC 0-20 0.0 456 500
Magnesium
Manganese
Molybdenum
Nickel
Potassium
95.0 80-120
101.0 80-120
91.2 80-120
Selenium 0.0 0.0 NC 0-20 0.0 1790 2000 89.5 80-120
Silver 0.0 0.0 NC 0-20 0.0 43.2 50 86.4 80-120
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP37417: FA75769-1, FA75769-2, FA75769-3, FA75769-4
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
V
N
N
Page 1
6 58 of 62
FA75769

MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA75769
Account: GSYNNCW - Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
QC Batch ID: MP37417 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date:
FA75765-2F Spikelot MSD QC
letal Original MSD MPFLICP2 % Rec RPD Limit
Aluminum
Antimony
Arsenic
0.0 1790
2000
89.5
0.6
20
Barium
57.1 2170
2000
105.6
4.2
20
Beryllium
Cadmium
0.0 47.1
50
94.2
0.8
20
Calcium
Chromium
0.0 204
200
102.0
1.0
20
Cobalt
Copper
Iron
Lead
0.0 458
500
91.6
0.4
20
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
0.0 1780
2000
89.0
0.6
20
Silver
0.0 43.9
50
87.8
1.6
20
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated
samples MP37417: FA75769-1,
FA75769-2,
FA75769-3,
FA75769-4
Results < IDL
are shown as zero
for calculation
purposes
(*) Outside
of QC limits
(N) Matrix
Spike Rec. outside of
QC limits
(anr) Analyte
not requested
V
N
N
Page 2
6 59 of 62
FA75769

SPIKE BLANK AND LAB CONTROL SAMPLE SUMMARY
Login Number: FA75769
Account: GSYNNCW - Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
QC Batch ID: MP37417 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date:
BSP Spikelot QC
letal Result MPFLICP2 % Rec Limits
Aluminum
Antimony
Arsenic 1850 2000 92.5 80-120
Barium 2010 2000 100.5 80-120
Beryllium
Cadmium 48.5 50 97.0 80-120
Calcium
Chromium 204 200 102.0 80-120
Cobalt
Copper
Iron
Lead 462 500 92.4 80-120
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium 1830 2000 91.5 80-120
Silver 43.6 50 87.2 80-120
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP37417: FA75769-1, FA75769-2, FA75769-3, FA75769-4
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
V
N
W
Page 1
6 60 of 62
FA75769

SERIAL DILUTION RESULTS SUMMARY
Login Number: FA75769
Account: GSYNNCW - Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
QC Batch ID: MP37417 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date:
FA75765-2F QC
letal Original SDL 1:5 %DIF Limits
Aluminum
Antimony
Arsenic
0.00 0.00
NC
0-10
Barium
57.1 56.1
1.8
0-10
Beryllium
Cadmium
0.00 0.00
NC
0-10
Calcium
Chromium
0.00 0.00
NC
0-10
Cobalt
Copper
Iron
Lead
0.00 0.00
NC
0-10
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
0.00 0.00
NC
0-10
Silver
0.00 0.00
NC
0-10
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples
MP37417: FA75769-1,
FA75769-2, FA75769-3, FA75769-4
Results < IDL
are shown as zero
for calculation
purposes
(*) Outside of
QC limits
(anr) Analyte
not requested
V
N
Page 1
6 61 of 62
FA75769

POST DIGESTATE SPIKE SUMMARY
Login Number: FA75769
Account: GSYNNCW - Geosyntec Consultants
Project: 31 Harnett, Wilmington, NC
QC Batch ID: MP37417 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date:
Sample Final FA75765-2F PS Spike Spike Spike QC
Metal ml ml Raw Corr.** ug/l ml ug/ml ug/l o Rec Limits
Aluminum
Antimony
Arsenic 9.8 10 88.8 0.2
Barium 9.8 10 57.1 55.958 298.8 0.2
Beryllium
Cadmium 9.8 10 45.93 0.2
Calcium
Chromium 9.8 10 48.4 0.2
Cobalt
Copper
Iron
Lead 9.8 10 42.3 0.2
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium 9.8 10 84.2 0.2
Silver 9.8 10 46.6 0.2
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP37417: FA75769-1, FA75769-2, FA75769-3, FA75769-
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(**) Corr. sample result = Raw * (sample volume / final volume)
(anr) Analyte not requested
5 100 88.8 80-120
12.5 250 97.1 80-120
2.5 50 91.9 80-120
2.5 50 96.8 80-120
2.5 50 84.6 80-120
5 100 84.2 80-120
2.5 50 93.2 80-120
V
N
N
Page 1
6 62 of 62
FA75769

APPENDIX D
RISK CALCULATOR RESULTS

Appendix D
Risk Screening Results
19 and 41 Harnett Street
Wilmington, North Carolina
Date: December 2019
November 2019 EPA RSL Table
* - Note that inhalation on this calculator refers to outdoor inhalation of volatiles and particulates, not indoor inhalation associated with vapor intrusion.
** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead therefore it is not possible to calculate cancer risk or hazard quotient Lead concentrations are compared to the EPA screening
level of 400 mglkg for residential soil.
CAS #
Chemical Name:
Ingestion
Concentration
(WA9)
Dermal
Concentration
(mg/kg)
Inhalation
Concentration
(mg/kg)*
Ingestion
Carcinogenic
Risk
Dermal
Carcinogenic
Risk
Inhalation
Carcinogenic
Risk*
Calculated
Carcinogenic
Risk
Ingestion
Hazard
Quotient
Dermal
Hazard
Quotient
Inhalation
Hazard
Quotient*
Calculated
Non -
Carcinogenic
Hazard
Quotient
67-64-1
Acetone
0.305
0.305
0.305
4.3E-06
6.5E-07
5.0E-06
7440-38-2
Arsenic, Inorganic
7.8
7.8
7.8
1.0E-05
1.4E-06
2.0E-10
1.2E-05
2.0E-01
2.4E-02
8.4E-06
2.2E-01
7440-39-3
Barium
60.7
60.7
60.7
3.9E-03
2.0E-06
3.9E-03
111444
Bis(2-cM-ethygether
0.26
0.26
0.26
4.1E-07
6.7E-07
1.1E-06
18540-29-9
Chromium(Vp
1.1
1.1
1.1
3.6E-06
1.5E-09
3.6E-06
4.7E-03
1.8E-07
4.7E-03
98-82-8
Cumene
0.0035
0.0035
0.0035
4.5E-07
1.3E-06
1.7E-06
106-934
Dibromoethane, 1,2-
0.049
0.049
0.049
1.4E-07
1.1E-06
1.3E-06
7.0E-05
5.7E-04
6.4E-04
100414
Ethylbenzene
0.0014
0.0014
0.0014
2.2E-11
2.1E-10
2.3E-10
1.8E-07
2.2E-07
4.0E-07
132-64-9
-Dibenzof-
0.133
0.133
0.133
1.7E-03
1.2E-04
1.8E-03
118-74-1
11-cldorobenzene
0.23
0.23
0.23
5.3E-07
5.2E-07
1.0E-06
3.7E-03
3.7E-03
77474
Hexachlorocyulopentadiene
0.45
0.45
0.45
9.6E-04
2.4E-01
2.4E-01
7439-92-1
-Lead and Compounds
160
160
160
<SL**
<SL**
<SL**
7439-97-6
-Mercury(elemental)
0.33
0.33
0.33
1
2.9E-02
2.9E-02
78-93-3
Methyl Ethyl Ketone(2-Butanone)
0.0365
0.0365
0.0365
7.8E-07
5.4E-07
1.3E-06
621-64-7
Nitroso-di-N-propylanune, N-
0.23
0.23
0.23
2.3E-06
6.5E-07
2.8E-12
3.0E-06
87-86-5
Pentachlomphenol
2.3
2.3
2.3
1.3E-06
9.3E-07
7.0E-14
2.3E-06
5.9E-03
3.5E-03
9.4E-03
83-32-9
-Acenaphthene
0.35
0.35
0.35
7.5E-05
2.3E-05
9.8E-05
120-12-7
-And-cent
0.491
0.491
0.491
2.1E-05
6.5E-06
2.7E-05
56-55-3
-Benzralanthracene
0.767
0.767
0.767
5.0E-07
1.7E-07
9.7E-09
6.8E-07
50-32-8
-Benzoralpvrene
0.628
0.628
0.628
4.1E-06
1.4E-06
6.3E-12
5.5E-06
2.7E-02
8.3E-03
5.1E-06
3.5E-02
205-99-2
-Benzorbl0uoranthene
0.972
0.972
0.972
6.3E-07
2.1E-07
9.7E-13
8.5E-07
207-08-9
-Benzork10uoranthene
0.339
0.339
0.339
2.2E-08
7.4E-09
3.4E-14
3.0E-08
218-01-9
-Clmysene
0.781
0.781
0.781
5.1E-09
1.7E-09
7.8E-15
6.8E-09
53-70-3
-Dibenzra,hlanthracene
0.28
0.28
0.28
1.8E-06
6.1E-07
2.8E-12
2.4E-06
206-44-0
-Fluoranthene
2.14
2.14
2.14
6.8E-04
2.1E-04
9.0E-04
86-73-7
-Fluorene
0.25
0.25
0.25
S.OE-05
2.5E-05
1.0E-04
193-39-5
-Indenorl,2,3-cdlpyrene
0.713
0.713
0.713
4.7E-07
1.6E-07
7.1E-13
6.2E-07
91-20-3
-Naphthalene
0.239
0.239
0.239
5.9E-08
5.9E-08
1.5E-04
4.7E-05
1.5E-03
1.7E-03
129-00-0
-Pyrene
3.405
3.405
3.405
1.5E-03
4.5E-04
1.9E-03
108-88-3
Toluene
0.0121
0.0121
0.0121
1.9E-06
5.1E-07
2.4E-06
96-184
Trichloroprepane, 1,2,3-
0.061
0.061
0.061
1.2E-05
1.2E-05
1.9E-04
1.2E-02
1.2E-02
95-63-6
1 Trimethylbenzene, 1,2,4-
0.0029
0.0029
0.0 229
3.7E-06
5.5E-06
9.2E-06
108-67-8
Trimethylbenzene, 1,3,5-
0.0011
0.0011
0.0011
1.4E-06
2.5E-06
3.9E-06
108-38-3
Xylene, m-
0.0041
0.0041
0.0041
2.6E-07
6.7E-06
7.0E-06
9547-6
Xylene, o-
0.0028
0.0028
0.0028
1.8E-07
3.9E-06
4.1E-06
1330-20-7
1 1 1 3.6E-07 I I 8.9E-06 I 9.3E-06 I
Cumulative: 4.6E-OS 5.7E-01
None Carolina DM alak Calculator

Appendix D
Risk Screening Results
19 and 41 Harnett Street
Wilmington, North Carolina
DEQ Risk Calculator - Direct Contact - Noo-Residential Worker Soil s
Version Date: December 2019
Basis: November 2019 EPA RSL Table
Site ID:
Exposure Unit tD:
* -Note that inhalation on this calculator refers to outdoor inhalation ofvolatiles andparticulates, not indoor inhalation associated with vapor intrusion.
** -Note that the EPA has no consensus on reference dose or cancer slope factor values for lead therefore it is not possible to calculate cancer risk or hazard quotient. Lead concentrations are compared to the EPA screening level of 800
mg/kg for commercial/'ndaaMal soil.
Cumulative: 5.9E-06 8.8E-02
CAS#
Chemical Name:
Ingestion
Concentration
(mg/kg)
Dermal
Concentration
(mg/kg)
Inhalation
Concentration
(mg/kg)*
Ingestion
Carcinogenic
Risk
Dermal
Carcinogenic
Risk
Inhalation
Carcinogenic
Risk
Calculated
Carcinogenic
Risk
Ingestion
Hazard
Quotient
Dermal
Hazard
Quotient
Inhalation
Hazard
Quotient
Calculated
Non -
Carcinogenic
Hazard
Quotient
67-64-1
Acetone
0.305
0.305
0.305
2.9E-07
1.5E-07
4.4E-07
7440-38-2
Arsenic, Inorganic
7.8
7.8
7.8
2.1E-06
4.5E-07
4.6E-11
2.6E-06
1.3E-02
2.8E-03
2.0E-06
1.6E-02
7440-39-3
Barium
60.7
60.7
60.7
2.6E-04
4.7E-07
2.6E-04
111-444
Bis(2-chloroethvl)ether
0.26
0.26
0.26
8.7E-08
1.5E-07
2.4E-07
18540-29-9
Chromium(VI)
1.1
1.1
1.1
1.7E-07
1.3E-10
1.7E-07
3.1E-04
4.2E-08
3.1E-04
98-82-8
Cumene
0.0035
0.0035
0.0035
3.0E-08
3.0E-07
3.3E-07
106-934
Dibromoetlsane. 1,2-
0.049
0.049
0.049
3.0E-08
2.6E-07
2.9E-07
4.7E-06
1.4E-04
1.4E-04
100414
Etlrvlbenzene
0.0014
0.0014
0.0014
4.7E-12
4.7E-11
5.2E-1]
1.2E-08
5.3E-08
6.5E-08
132-64-9
-Dibenzofivan
0.133
0.133
0.133
1.1E-04
1.4E-05
1.3E-04
118-74-1
Hexachlorobenzene
0.23
0.23
0.23
1.1E-07
1.2E-07
2.3E-07
2.5E-04
2.5E-04
77-47-4
Hexachlorocvclopentadiene
0.45
0.45
0.45
6.4E-05
5.7E-02
5.7E-02
7439-92-1
-Lead and Compounds
160
160
160
<SL**
eSL**
eSL**
7439-97-6
-Mercury (elemental)
0.33
0.33
0.33
6.8E-03
6.8E-03
78-93-3
Methyl Ethyl Ketone (2-Butanone)
0.0365
0.0365
0.0365
5.2E-08
1.3E-07
1.8E-07
621-64-7
Nitroso-di-N-propvlamine, N.
0.23
0.23
0.23
4.9E-07
2.1E-07
6.3E-13
7.0E-07
87-86-5
Pen[achlorophenol
2.3
2.3
2.3
2.8E-07
3.0E-07
1.6E-14
5.8E-07
3.9E-04
4.2E-04
8.1E-04
83-32-9
-Acenaphthene
0.35
0.35
0.35
5.0E-06
2.7E-06
7.7E-06
120-12-7
-Anthracene
0.491
0.491
0.491
1.4E-06
7.7E-07
2.2E-06
56-55-3
-Benzlalantivacene
0.767
0.767
0.767
2.3E-08
1.3E-08
8.0E-10
3.7E-08
50-32-8
-Benzolalpvrene
0.628
0.628
0.628
1.9E-07
1.1E-07
5.2E-13
3.0E-07
1.8E-03
9.9E-04
1.2E-06
2.8E-03
205-99-2
-BenzolblFluoranthene
0.972
0.972
0.972
3.0E-08
1.6E-08
8.0E-14
4.6E-08
207-08-9
-Benzolklfluoranthene
0.339
0.339
0.339
1.0E-09
5.7E-10
2.8E-15
1.6E-09
218-01-9
-Chrvsene
0.781
0.781
0.781
2.4E-10
1.3E-10
6.4E-16
3.7E-10
53-70-3
-Dibenzla,hlantivacene
0.28
0.28
0.28
8.6E-08
4.7E-08
2.3E-13
1.3E-07
206-44-0
-Fluoranthene
2.14
2.14
2.14
4.6E-05
2.5E-05
7.1E-05
86-73-7
-Fluorene
0.25
0.25
0.25
5.4E-06
2.9E-06
8.3E-06
193-39-5
-Indenol 1,23-cdlpvrene
0.713
0.713
0.713
2.2E-08
1.2E-08
5.9E-14
3.4E-08
91-20-3
-Naphthalene
0.239
0.239
0.239
1.3E-08
1.3E-08
1.0E-05
5.6E-06
3.7E-04
3.8E-04
129-00-0
-Pvrene
3.405
3.405
3.405
9.7E-05
5.3E-05
1.5E-04
108-88-3
Toluene
0.0121
0.0121
0.0121
1.3E-07
1.2E-07
2.5E-07
96-18-4
Trichloropropane, 1,2,3-
0.061
0.061
0.061
5.6E-07
5.6E-07
1.3E-05
2.8E-03
2.8E-03
95-63-6
Trime[hvlbenzene. 1,2,4-
0.0029
0.0029
0.0029
2.5E-07
1.3E-06
1.6E-06
108-67-8
Trimetlrvlbenzene. 1,3.5-
0.0011
0.0011
0.0011
9.4E-08
5.9E-07
6.9E-07
108-38-3
Xvlene. m-
0.0041
0.0041
0.0041
1.8E-OS
1.6E-06
1.6E-06
95-47-6
Xvlene, o-
0.0028
0.0028
0.0028
1.2E-OS
9.3E-07
9.4E-07
1330-20-7
Xvlenes
0.0057
0.0057
0.0057
2.4E-08
2.1E-06
2.2E-06

Appendix D
Risk Screening Results
19 and 41 Harnett Street
Wilmington, North Carolina
DEQ Risk Calculator - Direct Contact - Construction Worker Soil s
Version Date: December 2019
Basis: November 2019 EPA RSL Table
SiteID:
Exposure Unit ID:
' - Note that inhalation on this calculator refers to outdoor inhalation ofvo(afi(es and parficulates, not indoor inhalation associated with vapor intrusion.
" -Note that the EPA has no co -us on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate cancer risk or hazard quotient. Lead concentrations are compared to the EPA screening level of800
mg/kg for commerctau'ndustria(soil.
1330-20-7 Xvlenes 0.0057 0.0057 0.0057 4.2E-08 2.6E-06 2.7Fl06
Cumulative: 1.2E-06 3.9E-01
Ingestion
Dermal
Inhalation
Ingestion
Dermal
Inhalation
Calculated
Ingestion
Dermal
Inhalation
Calculated

Appendix D
Risk Screening Results
19 and 41 Harnett Street
Wilmington, North Carolina
DEQ Risk Calculator - Direct Contact - Recreator/Tres riser Soil s
Version Date: December 2019
Basis: November 2019 EPA RSL Table
Site ID:
Exposure Unit tD:
* -Note that inhalation on this calculator refers to outdoor inhalation ofvolatiles andparticulates, not indoor inhalation associated with vapor intrusion.
** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead therefore it is not possible to calculate cancer risk or hazard quotient. Lead concentrations are compared to the EPA screening level of 400
mgAg for residential soil.
Receptor Two: Recreator
Cumulative: 2.4E-OS 1.7E-01
CAS#
Chemical Name:
Ingestion
Concentration
(mg/kg)
Dermal
Concentration
(mg/kg)
Inhalation
Concentration
(mg/kg)*
Ingestion
Carcinogenic
Risk
Dermal
Carcinogenic
Risk
Inhalation
Carcinogenic
Risk
Calculated
Carcinogenic
Risk
Ingestion
Hazard
Quotient
Dermal
Hazard
Quotient
Inhalation
Hazard
Quotient
Calculated
Non -
Carcinogenic
Hazard
Quotient
67-64-1
Acetone
0.305
0.305
0.305
2.4E-06
3.0E-08
2.4E-06
7440-38-2
Arsenic, Inorganic
7.8
7.8
7.8
5.6E-06
7.9E-07
9.3E-12
6.4E-06
1.1E-01
1.3E-02
3.9E-07
1.2E-01
7440-39-3
Barium
60.7
60.7
60.7
2.2E-03
9.1E-08
2.2E-03
111-444
Bis(2-chloroethvl)ether
0.26
0.26
0.26
2.3E-07
3.1E-08
2.6E-07
18540-29-9
Chromium(VI)
1.1
1.1
1.1
2.0E-06
7.1E-11
2.0E-06
2.6E-03
8.3E-09
2.6E-03
98-82-8
Cumene
0.0035
0.0035
0.0035
2.5E-07
5.9E-08
3.1E-07
106-934
Dibromoethane. 1,2-
0.049
0.049
0.049
7.9E-08
5.3E-08
1.3E-07
3.9E-05
2.6E-05
6.5E-05
100414
Ethvlbenzene
0.0014
0.0014
0.0014
1.2E-11
9.6E-12
2.2E-11
1.0E-07
1.0E-08
1.1E-07
132-64-9
-Dibenzofivan
0.133
0.133
0.133
9.5E-04
6.7E-05
1.0E-03
118-74-1
Hexachlorobenzene
0.23
0.23
0.23
2.9E-07
2.4E-08
3.2E-07
2.0E-03
2.0E-03
77-47-4
Hexachlorocvclopentadiene
0.45
0.45
0.45
5.3E-04
1.1E-02
1.2E-02
7439-92-1
-Lead and Compounds
160
160
160
<SL**
eSL**
eSL**
7439-97-6
-Mercwv(elementap
0.33
0.33
0.33
1.3E-03
1.3E-03
78-93-3
Methyl Ethyl Ketone (2-Butanone)
0.0365
0.0365
0.0365
4.3E-07
2.5E-08
4.6E-07
621-64-7
Nitroso-di-N-propdamine, N.
0.23
0.23
0.23
1.3E-06
3.6E-07
1.3E-13
1.7E-06
87-86-5
Pen[achlorophenol
2.3
2.3
2.3
7.4E-07
5.2E-07
3.3E-15
1.3E-06
3.3E-03
1.9E-03
5.2E-03
83-32-9
-Acenaphthene
0.35
0.35
0.35
4.2E-05
1.3E-05
5.4E-05
120-12-7
-Anthracene
0.491
0.491
0.491
1.2E-05
3.6E-06
1.5E-05
56-55-3
-Benzlalanthracene
0.767
0.767
0.767
2.8E-07
9.3E-08
4.5E-10
3.7E-07
50-32-8
-Benzofalpvrene
0.628
0.628
0.628
23E-06
7.6E-07
2.9E-13
3.0E-06
1.5E-02
4.6E-03
2.4EA7
2.0E-02
205-99-2
-BenzofblFluoranthene
0.972
0.972
0.972
3.5E-07
1.2E-07
4.5E-14
4.7E-07
207-08-9
-Benzofklfluoranthene
0.339
0.339
0.339
1.2E-08
4.1E-09
1.6E-15
1.6E-08
218-01-9
-Chrvsene
0.781
0.781
0.781
2.8E-09
9.5E-10
3.6E-16
3.8E-09
53-70-3
-Dibenzla,hlanthracene
0.28
0.28
0.28
1.0E-06
3.4E-07
1.3E-13
1.4E-06
206-44-0
-Fluoranthene
2.14
2.14
2.14
3.8E-04
1.2E-04
5.0E-04
86-73-7
-Fluorene
0.25
0.25
0.25
4.5E-05
1.4E-05
5.8E-05
193-39-5
-Indenol 1,23-cdlpvrene
0.713
0.713
0.713
2.6E-07
8.7E-08
3.3E-14
3.5E-07
91-20-3
-Naphthalene
0.239
0.239
0.239
2.7E-09
2.7E-09
8.5E-05
2.6E-05
7.2E-05
1.8E-04
129-00-0
-Pyrene
3.405
3.405
3.405
8.1E-04
2.5E-04
1.1E-03
108-88-3
Toluene
0.0121
0.0121
0.0121
1.1E-06
2.4E-08
1.1E-06
96-18-4
Trichloropropane, 1,2,3-
0.061
0.061
0.061
6.7E-06
6.7E-06
1.1E-04
5.4E-04
6.5E-04
95-63-6
Trimetlrvlbenzene. 1,2,4-
0.0029
0.0029
0.0029
2.1E-06
2.6E-07
2.3E-06
108-67-8
Trimetlrvlbenzene. 13.5-
0.0011
0.0011
0.0011
7.8E-07
1.2E-07
9.0E-07
108-38-3
Xylene. en-
0.0041
0.0041
0.0041
1.5E-07
3.1E-07
4.6E-07
95-47-6
Xylene, o-
0.0028
0.0028
0.0028
1.0E-07
1.8E-07
2.8E-07
1330-20-7
Xylenes
0.0057
0.0057
0.0057
2.0E-07
4.2E-07
6.2E-07

Appendix D
Risk Screening Results
19 and 41 Harnett Street
Wilmington, North Carolina
DEQ Risk Calculator - Direct Contact - Recreator/Tres riser Soil s
Version Date: December 2019
Basis: November 2019 EPA RSL Table
Site ID:
Exposure Unit tD:
* -Note that inhalation on this calculator refers to outdoor inhalation ofvolatiles andparticulates, not indoor inhalation associated with vapor intrusion.
** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead therefore it is not possible to calculate cancer risk or hazard quotient. Lead concentrations are compared to the EPA screening level of 400
mgAg for residential soil.
Receptor Two: Trespasser
Cumulative: 4.4E-06 3.5E-02
CAS#
Chemical Name:
Ingestion
Concentration
(mg/kg)
Dermal
Concentration
(mg/kg)
Inhalation
Concentration
(mg/kg)*
Ingestion
Carcinogenic
Risk
Dermal
Carcinogenic
Risk
Inhalation
Carcinogenic
Risk
Calculated
Carcinogenic
Risk
Ingestion
Hazard
Quotient
Dermal
Hazard
Quotient
Inhalation
Hazard
Quotient
Calculated
Non -
Carcinogenic
Hazard
Quotient
67-64-1
Acetone
0.305
0.305
0.305
3.7E-07
1.4E-08
3.9E-07
7440-38-2
Arsenic, Inorganic
7.8
7.8
7.8
ME-06
3.3E-07
1.7E-12
1.4E-06
1.7E-02
5.2E-03
1.8E-07
2.2E-02
7440-39-3
Barium
60.7
60.7
60.7
3.3E-04
4.2E-08
3.3E-04
111-444
Bis(2-chloroethvl)ether
0.26
0.26
0.26
4.5E-08
5.6E-09
5.0E-08
18540-29-9
Chromium(VI)
1.1
1.1
1.1
2.6E-07
1.4E-11
2.6E-07
4.0E-04
3.8E-09
4.0E-04
98-82-8
Cumene
0.0035
0.0035
0.0035
3.8E-08
2.7E-08
6.6E-08
106-934
Dibromoethane. 1,2-
0.049
0.049
0.049
1.5E-08
9.4E-09
2.5E-08
6.0E-06
1.2E-05
1.8E-05
100414
Ethvlbenzene
0.0014
0.0014
0.0014
2.4E-12
1.7E-12
4.1E-12
1.5E-08
4.8E-09
2.0E-08
132-64-9
-Dibenzofivan
0.133
0.133
0.133
1.5E-04
2.6E-05
1.7E-04
118-74-1
Hexachlorobenzene
0.23
0.23
0.23
5.8E-08
4.3E-09
6.2E-08
3.2E-04
3.2E-04
77-47-4
Hexachlorocvclopentadiene
0.45
0.45
0.45
8.2E-05
5.1E-03
5.2E-03
7439-92-1
-Lead and Compounds
160
160
160
<SL**
eSL**
4SL**
7439-97-6
-Mercury (elemental)
0.33
0.33
0.33
6.1E-04
6.1E-04
78-93-3
Methyl Ethyl Ketone (2-Butanone)
0.0365
0.0365
0.0365
6.7E-08
1.2E-08
7.8E-08
621-64-7
Nitroso-di-N-propvlamine, N.
0.23
0.23
0.23
2.5E-07
1.5E-07
2.3E-14
4.0E-07
87-86-5
Pen[achlorophenol
2.3
2.3
2.3
1.4E-07
2.2E-07
5.8E-16
3.6E-07
5.0E-04
7.6E-04
1.3E-03
83-32-9
-Acenaphthene
0.35
0.35
0.35
6.4E-06
5.0E-06
1.1E-05
120-12-7
-Anthracene
0.491
0.491
0.491
1.8E-06
1.4E-06
3.2E-06
56-55-3
-Benzlalanthracene
0.767
0.767
0.767
3.6E-08
2.8E-08
8.6E-11
6.4E-08
50-32-8
-Benzofalpvrene
0.628
0.628
0.628
2.9E-07
2.3E-07
5.6E-14
5.3E-07
2.3E-03
1.8E-03
1.1E-07
4.1E-03
205-99-2
-BenzofblFluoranthene
0.972
0.972
0.972
4.6E-08
3.6E-08
8.7E-15
8.1E-08
207-08-9
-Benzofklfluoranthene
0.339
0.339
0.339
1.6E-09
1.2E-09
3.0E-16
2.8E-09
218-01-9
-Clnvsene
0.781
0.781
0.781
3.7E-10
2.9E-10
7.0E-17
6.5E-10
53-70-3
-Dibenzla,hlanthracene
0.28
0.28
0.28
1.3E-07
1.0E-07
2.5E-14
2.3E-07
206-44-0
-Fluoranthene
2.14
2.14
2.14
5.9E-05
4.6E-05
1.0E-04
86-73-7
-Fluorene
0.25
0.25
0.25
6.8E-06
5.4E-06
1.2E-05
193-39-5
-Indenol 1,23-cdlpvrene
0.713
0.713
0.713
3.3E-08
2.6E-08
6.4E-15
6.0E-08
91-20-3
-Naphthalene
0.239
0.239
0.239
4.8E-10
4.8E-10
1.3E-05
1.0E-05
3.3E-05
5.7E-05
129-00-0
-Pyrene
3.405
3.405
3.405
1.2E-04
9.8E-05
2.2E-04
108-88-3
Toluene
0.0121
0.0121
0.0121
1.7E-07
1.1E-08
1.8E-07
96-18-4
Trichloropropane, 1,2,3-
0.061
0.061
0.061
8.6E-07
8.6E-07
1.7E-05
2.5E-04
2.7E-04
95-63-6
Trimetlrvlbenzene. 1,2,4-
0.0029
0.0029
0.0029
3.2E-07
1.2E-07
4.4E-07
108-67-8
Trimetlrvlbenzene. 13.5-
0.0011
0.0011
0.0011
1.2E-07
5.4E-0S
1.7E-07
108-38-3
Xvlene. m-
0.0041
0.0041
0.0041
2.2E-08
1.4E-07
1.7E-07
95-47-6
Xvlene, o-
0.0028
0.0028
0.0028
1.5E-08
8.4E-OS
9.9E-08
1330-20-7
Xvlenes
0.0057
0.0057
0.0057
3.1E-OS
1.9E-07
2.2E-07