23080_Almont Shipping II_OAR_20221103

gW_KETTLER
SEAN H. CURTIN
PHONE: [phone]
[e-mail]
November 3, 2022
VIA E-MAIL (Sharon. eckard(a ncdenr.gov)
Ms. Sharon Eckard
N.C. Department of Environmental Quality
Division of Waste Management
Brownfields Program
1646 Mail Service Center
Raleigh, NC 27699-1646
Re: Adjacent Property Soil Assessment Report
Almont Shipping II Brownfields Project
19 & 41 Harnett Street, Wilmington, North Carolina (New Hanover County Parcels No.
R04716-001-026-000, R04716-001-030, & R04712-002-001-000)
Brownfields Project Number: 23080-19-065
Dear Ms. Eckard:
Following up on our previous communications, please find enclosed the Adjacent Property Soil
Assessment Report, Almont Shipping II, prepared by Geosyntec Consultants of NC, P.C. (Geosyntec) for
Clancy & Theys Construction Company ("Clancy"), dated October 25, 2022. Clancy is the General
Contractor for the redevelopment work being conducted at the above -referenced North Carolina Brownfields
Program (NCBP) property. The Prospective Developer, Wilmington Waterfront Property Owner, LLC, is
submitting this report on Clancy's behalf and pursuant to NCBP's August 16, 2022 approval of the Work
Plan for Adjacent Property Soil Sampling, Almont Shipping II prepared by Geosyntec and dated July 13,
2022.
Please let me know of any additional information you need in connection with your review of this
report or confirm that NCBP concurs with the conclusions presented in the attached report. We look forward
to working with you to bring this project to completion.
Very Truly Yours,
Sean H. Curtin
cc: William Edwards, Sean Curtin — Kettler Enterprises Inc.
Kaitlyn Rhonehouse, Abby Wesley, Geosyntec
Michael Goodson, Clancy and Theys
Mary Katherine Stukes — Moore & VanAllen
Dave Waters — PPD, Inc.
Scott Werley — ECS Southeast, LLP
Enclosure Charlotte, NC
Charleston, SC

Prospective Developer:
Wilmington Riverfront Property Owner, LLC
8255 Greensboro Drive, Suite 200
McLean, Virginia 22102
ADJACENT PROPERTY SOIL
ASSESSMENT REPORT
New Hanover County Parcel No. R04716-001-026-000,
R04716-001-0309 & R04712-002-001-000
19 & 41 Harnett Street, Wilmington, North Carolina
Brownfields Project: Almont Shipping II
NCBP No. 23080-19-065
Prepared by
GeosyntecO'
consultants
Geosyntec Consultants of NC, P.C.
Geosyntec Consultants of NC, P.C.
314 Walnut Street, Suite 200
Wilmington, North Carolina 28401
Project Number GN7035B
November 2022

PROFESSIONAL ENGINEER SIGNATURE
I, Kaitlyn Rhonehouse, a Licensed Engineer for Geosyntec Consultants of NC, P.C., do certify
that the information in this report is correct and accurate to the best of my knowledge.
Geosyntec Consultants of NC. P.C. is licensed to practice engineering in North Carolina. The
certification number (Firm's License Number) is C-3500.
Geosyntec Consultants of NC. P.C. is licensed to practice geology in North Carolina. The
certification number (Firm's License Number) is C-295.
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Principal Engineer
North Carolina P.E. License No. 043548
Expiration Date: 31 December 2022
Geosyntec Consultants of NC, P.C.
314 Walnut Street, Suite 200
Wilmington, NC 28401
Telephone: [phone]

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TABLE OF CONTENTS
1. INTRODUCTION................................................................................................................................1
2. SITE ENVIRONMENTAL HISTORY................................................................................................1
3. SCOPE OF WORK............................................................................................................................... 2
4. SAMPLING METHODOLOGY.......................................................................................................... 3
4.1 LABORATORY ANALYSES AND QA/QC.............................................................................. 4
4.2 INVESTIGATION -DERIVED WASTE (IDW) MANAGEMENT.............................................4
5. INVESTIGATION RESULTS.............................................................................................................4
6. RISK ASSESSMENT...........................................................................................................................5
7. CONCLUSIONS...................................................................................................................................8
8. REFERENCES..................................................................................................................................... 8
LIST OF FIGURES
Figure 1 Site Location Map
Figure 2 PPD Property and Soil Sample Analytical Results
LIST OF TABLES
Table 1 Soil Sample Analytical Results
LIST OF APPENDICES
Appendix A Boring Logs
Appendix B Laboratory Analytical Reports
Appendix C Risk Calculator Summary and Output
GN7035B Soil Assessment Report i November 2022

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1. INTRODUCTION
Geosyntec Consultants of NC, P.C. (Geosyntec) prepared this Adjacent Property Soil Assessment
Report (the "Report") for the parcel (New Hanover County Parcel ID: R04712-003-001-000; "PPD
Property") previously owned by PPD, Inc. (PPDl) adjacent to the Site (Figure 1). The Site is
located at 19 and 41 Harnett Street (New Hanover County Parcel IDs: R04716-001-026-000,
R04716-001-030, and R04712-002-001), Wilmington, North Carolina (these three parcels are
collectively referred to herein as the "Site" and the "Almont Shipping II" Brownfields Property
(Figure 1).
The North Carolina Department of Environmental Quality (NCDEQ) approved Wilmington
Waterfront Property Owner, LLC's (the Prospective Developer [PD]) 7 January 2020 Brownfields
Property Application (BPA) in an 18 February 2020 Letter of Eligibility (LOE; NCBP No. 23080-
19-065). An Environmental Management Plan (EMP) was conditionally approved on 28 May 2021
and executed on 4 February 2022. Redevelopment activities were initiated in July 2021. On 10
February 2022, soil was exported from the Site and placed on a portion of the PPD Property (shown
in blue on Figure 2). Neither the PD, PPD, nor Geosyntec were aware of, or authorized, the soil
movement before it occurred. The Site soils have been previously sampled and deemed suitable
for residential use by NCBP. The unauthorized imported soil was subsequently removed from the
PPD Property and returned to the Site. Due to the nature of soil relocation and the soil spreading
conducted, we understand it was not considered feasible to confirm the removal of all of the Site
soils from the PPD Property without undercutting. Therefore, on 6 May 2022, NCBP requested
additional soil sampling on the PPD Property to evaluate potential impacts of the unauthorized soil
transfer to the PPD Property in its current condition. Geosyntec conducted soil sampling at the
PPD Property, in accordance with a Work Plan for Adjacent Property Soil Sampling submitted to
NCBP on 13 July 2022 and approved on 18 August 2022.
2. SITE ENVIRONMENTAL HISTORY
The Site and surrounding area operated as the former Almont Shipping terminal from 1870 until
2005. A BFA was executed between the NCBP and Riverfront Holdings II, LLC on 23 June 2008
for the Almont Shipping Brownfields Property (NCBP No. 10040-06-065; the 19 Harnett Street
parcel and northwestern of portion of the 41 Harnett St. parcel are included in the Almont Shipping
BFA until a new BFA is executed for the Site). The BFA was amended in 2014 to include an
l The property is listed as owned by River Ventures LLC, an entity controlled by PPD; PPD was acquired by Thermo
Fisher Scientific in 2021. The property and owner are herein referred to as the PPD Property and PPD, respectively,
for consistency with prior communication and submittals to NCBP.
2 Note: the blue outline representing the area where Almont Shipping II soil was previously placed has been updated
from the Work Plan for Adjacent Property Soil Sampling; the northwestern portion of the area previously within the
blue outline is outside of an existing retaining wall and is not accessible. The "area of exported soil" has been updated
to reflect conditions and accessible areas observed during sampling.
GN7035B Soil Assessment Report 1 November 2022

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additional land tract owned by CSX. The Site received eligibility for entry into the NCBP on 18
February 2020 to establish a new, stand-alone BFA for only the two Harnett Street parcels.
Multiple environmental assessments have been conducted at the Site prior to and during the
Brownfields Program process. During these assessments, Site soils were sampled, screened against
NCDEQ Residential Preliminary Soil Remediation Goals (PSRG) and evaluated through a risk
assessment using the NCDEQ Risk Calculator. The on -site soil (in addition to imported fill used
during Site redevelopment) was determined to be suitable for residential use by NCBP.
Redevelopment activities, under the approved EMP, began in May 2021 and continue to date. To
aid in the redevelopment process, the PD negotiated a license agreement with PPD for temporary
access to use portions of the PPD Property for equipment laydown and a work trailer (Figure 2).
The license agreement to use the PPD Property was subject to certain restrictions, including
explicit prohibitions against: (i) excavation of any sort on the PPD Property; (ii) disturbance of the
soil on the PPD Property; and (iii) use of any groundwater on the PPD Property. As this space was
being prepared for use, the PD's contractor, without PD's, PPD's, or Geosyntec's knowledge or
consent, moved approximately 300 cubic yards of soil from the Site to the PPD Property on 10
February 2022, intending to use the material to correct the grade required for heavy construction
equipment. Once the PD and PPD were aware that Site soils had been exported to the PPD
Property, the exported soil was removed to the best of the contractor's ability and returned to the
Site on 14 February 2022.
The returned soil was stockpiled at the Site and sampled (one grab sample) and analyzed for
volatile organic compounds (VOCs), semi -volatile organic compounds (SVOCs), and the eight
Resource Conservation and Recovery Act (RCRA) metals including hexavalent chromium. A risk
assessment was performed for the soil sample results using NCDEQ's Risk Calculator (NCDEQ,
2022). Based on the soil sample concentrations, the calculated carcinogenic and hazard indices
were below the thresholds for residential use and consistent with prior on -site sampling of soil and
imported fill to the Site. The remainder of this report summarizes results from soil sampling
completed at the PPD Property, in accordance with a Work Plan for Adjacent Property Soil
Sampling submitted to NCBP on 13 July 2022, as requested by NCBP.
3. SCOPE OF WORK
The scope of work included the collection of ten composite soil samples as shown on Figure 2.
Composite soil samples (comprised of five aliquots, except for the Z6 sample which was
comprised of four aliquots) were collected from six zones (approximately 5,000 square feet each)
on the PPD Property; four (Z1-Z4) that comprise the area where Site soils were placed and two
(Z5-Z6) which are located outside of this area (Figure 2) and were intended to serve as background
soil samples. Two samples, one from 0-0.5 feet below ground surface (ft bgs) and one from 0.5-2
ft bgs, were obtained from each of the zones in the Site soil placement area. The shallower sample
is intended to be representative of the residual Site soils (if present) and the deeper sample is
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intended to be representative of pre-existing PPD Property site conditions in the zone. Composite
soil samples were also collected from the zone outside of the area where Site soils were placed in
order to further establish pre-existing background conditions on the PPD Property.
Results from the three groups (shallow samples in zones Z1-Z4, deeper samples in zones Z1-Z4,
and samples from zones Z5-Z6) were compared to evaluate potential impacts from the soil transfer
from the Site to the PPD Property. Risk assessments for the shallow samples, the deeper and
background samples, and the combined shallow and deeper Z1-Z4 samples were also performed
to evaluate if potentially remaining Site soils have significantly affected the risk at the PPD
Property in its current condition.
4. SAMPLING METHODOLOGY
Sampling procedures generally followed U.S. Environmental Protection Agency (USEPA) Region
IV Science, Ecosystem Support Division (SESD) Operating Procedures, and the July 2022
Workplan for Adjacent Property Soil Sampling (approved by NCBP on 16 August 2022). Prior to
the start of work, Geosyntec prepared a site -specific Health and Safety Task Hazard Analysis in
general accordance with the Occupation Safety and Health Administration (OSHA) rules (29 CFR
1910.120).
On 8 and 9 September 2022, 30 borings (located in Z1-Z6) were advanced to 2 ft bgs using a hand
auger to allow for the collection of 10 composite soil samples within each zone (Figure 2). A
handheld Global Positioning System (GPS) unit and field measurements were used to collect the
approximate coordinates of the borings. Soil from each boring was collected, visually inspected,
screened with a photoionization detector (PID), and classified for lithology. Aliquots were
homogenized (by zone) in a decontaminated stainless -steel bowl. One discrete grab sample was
collected for VOC analysis from the soil boring within each zone with the highest field screening
results or the centrally located aliquot for each zone. The discrete grab samples for VOC analysis
were not collected from composited soil. Boring logs are included in Appendix A.
In zone Z6, Geosyntec personnel experienced refusal with the hand auger, so four aliquots were
collected in zone Z6 as opposed to five due to environmental conditions. Additionally, upon
arriving at the PPD Property, an 8 to 10-inch-thick gravel area was observed in the southern portion
of the property as illustrated on Figure 2. Therefore, in zones Z3 and Z4, one aliquot in each zone
was obtained from beneath the gravel layer (Z3-3 and Z4-3). The gravel layer in the vicinity of the
borings was removed with a shovel and the borings were advanced below the gravel layer. The
soil immediately below the gravel layer was considered representative of the "ground surface" and
the borings were advanced an additional 2 ft bgs using a hand auger. The shallow sample was
obtained from 0-0.5 ft directly below the gravel layer and the deeper sample was collected from
0.5-2 ft below the gravel layer.
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4.1 LABORATORY ANALYSES AND QA/QC
Collected samples were submitted under chain of custody to a North Carolina -certified laboratory
for analysis of VOCs by EPA Method 8260, SVOCs by EPA Method 8270, and the eight RCRA
metals including hexavalent chromium by EPA Methods 6010, 7471, and 7199. Two laboratory
blind duplicate samples were also collected (one per day of sampling). Soil samples (12 total) were
shipped overnight on wet ice under chain of custody and analyzed under a standard 10-day
turnaround time.
4.2 INVESTIGATION -DERIVED WASTE (IDW) MANAGEMENT
Investigation -derived waste (IDW) was containerized in labeled 55-gallon steel drums and stored
in a designated area of the PPD Property pending disposal based on laboratory results. One labeled
drum contains rinse water from decontamination efforts and one labeled drum contains soil
cuttings. Both drums are elevated on a wooden pallet and wrapped in plastic sheeting and orange
construction hazard fencing.
5. INVESTIGATION RESULTS
Soil sample analytical results for constituents detected above the laboratory Method Detection
Limit (MDL) in one or more samples are presented in Table 1. Constituents detected in soil above
their respective NCDEQ Residential or Industrial/Commercial PSRG are shown on Figure 2.
Laboratory analytical reports are included in Appendix B.
Soil Sample Results
Ten soil samples and two duplicate soil samples were collected on 8 and 9 September 2022. The
primary findings associated with the soil analytical results are as follows:
• VOCs: Nine VOCs were detected in at least one of the soil samples. However, no VOCs
were detected at concentrations above the Residential or Commercial/Industrial PSRGs.
• SVOCs: Fifteen SVOCs were detected above their respective MDL ("J" flagged), however
only 1-methylnaphthalene was detected above its laboratory reporting limit (RL) in one
sample (Z4-0.5-2). No SVOCs were detected at concentrations greater than a Residential
or Industrial/Commercial PSRG.
• Metals: At least one metal was detected above its RL in all soil samples. However only
arsenic and hexavalent chromium were detected above PSRG.
o Arsenic was detected above its Residential PSRG (0.68 milligrams per kilogram
[mg/kg]) in seven samples from both depth intervals (Z1-0-0.5, Z2-0-0.5, Z3-0-0.5,
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Z4-0-0.5, Z445-2, Z5-0-2, and Z6-0-2). Arsenic concentrations also exceeded the
Industrial/Commercial PSRG (3 mg/kg) in samples Z2-0-0.5, Z4-0-0.5, and Z5-0-
2.
o Hexavalent chromium was detected above the Residential PSRG (0.31 mg/kg) in
all samples from both depth intervals; reported concentrations range from 0.59 (Z4-
0-0.5) to 1.1 mg/kg (DUP-20220908, obtained from Z3-0.5-2).
6. RISK ASSESSMENT
Based on the detections of constituents in soil above PSRGs, Geosyntec conducted a preliminary
risk assessment (RA) in accordance with the Revised Technical Guidance for Risk -Based
Environmental Remediation of Sites (Risk -Based Guidance) using the July 2022 NCDEQ Risk
Calculator. The analytical results input into the NCDEQ Risk Calculator include the maximum
concentration of each detected compound, including estimated values, and the RLs for compounds
that were not detected in the samples but for which the RL exceeded the lowest respective PSRG.
Cumulative cancer risk below lE-4 and cumulative non -cancer hazards less than 1.0 are assumed
acceptable, as indicated in the Risk -Based Guidance (NCDEQ, 2020).
Risk evaluations, using soil data collected 8 and 9 September 2022, were performed to compare
detected constituents and risk assessment values of shallow soil samples (Z 1-Z4 0-0.5 ft bgs
interval), deeper (Z1-Z4 0.5-2 ft bgs interval) and background (Z5 and Z6 0-2 ft bgs) soil samples,
and the combined results. Three risk assessments ("Tier 1" assessments) were completed: one was
performed with only the results from shallow soil samples in zones Z 1-Z4 that are representative
of soil that has been in contact with transferred Almont Shipping II soil, the second was performed
with only the results from the deeper soil samples in zones Z1-Z4 and background samples from
zones Z5 and Z6 that are representative of the pre-existing soil conditions at the PPD Property,
and the third was performed with all the results which is representative of the current soil
conditions at the PPD Property.
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The Risk Calculator outputs for the three Tier 1 evaluations are presented below:
Assessments
Receptor
Pathway
Carcinogenic
Hazard
Risk
Risk
Index
Exceeded.
Resident
Soil
1.6E-05
3.8E-01
NO
Shallow Sample
Results
Non -Residential
Soil
2.5E-06
2.8E-02
NO
Worker
Resident
Soil
1.0E-04
8.4E-01
YES
Deeper and
Background
Sample Results
Non -Residential
Soil
8.6E-06
1.1E-01
NO
Worker
Resident
Soil
1.1E-04
8.6E-01
YES
Combined
Results
Non -Residential
Soil
8.8E-06
1.2E-01
NO
Worker
The carcinogenic risk (CR) and non -cancer hazard index (HI) for a residential receptor were
calculated to be 0.000016 (1.6E-05) and 0.38 (3.8E-01), respectively, for the shallow soil results.
The CR and HI for a residential receptor were calculated to be 0.0001 (1 E-04) and 0.81 (8.1 E-01),
respectively, for the deeper and background sample results, and 0.00011 (1.1E-04) and 0.86 (8.6E-
01), respectively, for the combined sample results. The CR for both the deeper and background
samples and the combined results exceeds the acceptable cumulative risk. However, this calculated
cumulative risk is driven by elevated RLs of compounds that are not detected in Site media.
The Risk Based Guidance recommends that if a chemical is not detected but the laboratory
reporting limit (RL) (or "Practical Quantitation Limit") exceeds the respective chemical's
Residential PSRG, then the RL is recommended to be input into the Risk Calculator as the
exposure point concentration (EPC). However, in some cases, this data processing approach can
unnecessarily result in elevated RLs of compounds not detected in Site media driving risk
screening results.
GN7035B Soil Assessment Report 6 November 2022

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Due to the elevated RLs driving risk, additional evaluations ("Tier 2" risk evaluations) were
performed. These Tier 2 evaluations incorporated only compounds detected in the soil samples or
compounds that had MDLs above their respective Residential PSRG.
The Risk Calculator outputs for the three Tier 2 evaluations are presented below:
Assessments
Receptor
Pathway
Carcinogenic
Hazard
Risk
Risk
Index
Exceeded?
Resident
Soil
1.0E-05
1.4E-01
NO
Shallow Sample
Results
Non -Residential
Soil
1.7E-06
1.1E-02
NO
Worker
Resident
Soil
3.1E-05
3.1E-01
NO
Deeper and
Background
Sample Results
Non -Residential
Soil
2.8E-06
2.9E-02
NO
Worker
Resident
Soil
3.2E-05
3.4E-01
NO
Combined
Results
Non -Residential
Soil
3.0E-06
3.0E-02
NO
Worker
The CR and HI for a residential receptor were calculated to be 0.000010 (LOE-05) and 0.14 (1.4E-
01), respectively, for the shallow soil results. The CR and HI for a residential receptor were
calculated to be 0.000031 (3.1E-05) and 0.31 (3.1E-01), respectively, for the deeper and
background sample results, and 0.000032 (3.2E-05) and 0.34 (3.4E-01), respectively, for the
combined sample results. All results are far below the CR and HI Risk Thresholds as outlined in
the Risk -Based Guidance (NCDEQ, 2020), indicating that the sampled soil at the PPD Property is
suitable for residential reuse in its current state. Furthermore, the CR and HI for the shallow
samples (which are representative of any potentially remaining Site soils at the PPD Property) are
lower than the deeper and background samples (which are representative of the pre-existing
conditions at the PPD Property).
GN7035B Soil Assessment Report 7 November 2022

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The NCDEQ Risk Calculator summaries and outputs for the Tier 1 and Tier 2 screenings are
included in Appendix C.
7. CONCLUSIONS
Soil sampling activities were performed by Geosyntec on 8 and 9 September 2022; soil samples
were collected at the PPD Property to evaluate potential impacts of the unauthorized soil transfer
to the PPD Property in its current condition.
Multiple VOCs, SVOCs and metals were detected in soil samples from all three groups: shallow
samples from Z1-Z4, deeper samples from Z1-Z4, and background samples from Z5 and Z6.
Arsenic and hexavalent chromium were reported at concentrations above their respective
Residential and/or Industrial/Commercial PSRGs at concentrations consistent with typical
background levels. No other targeted analytes were reported above a Residential or
Industrial/Commercial PSRG.
The results of the Tier 2 risk assessments indicated that the areas and depth intervals sampled at
the PPD Property are suitable for residential reuse in its current condition. Additionally, the CR
and HI calculated for the shallow soil interval was less than that calculated for the deeper and
background samples. This demonstrates that any potentially remaining Almont Shipping II soil
does not significantly impact the risk associated with PPD Property soils and should not impact
any future re -use of the PPD Property.
Geosyntec recommends that no further action is necessary based on the results of the soil sampling
and associated risk assessment. We look forward to your review of the results and findings outlined
in this report and hope that NCBP can provide confirmation that the risk associated with the soils
at the PPD Property has not been impacted by any potentially remaining Almont Shipping II soils.
8. REFERENCES
Geosyntec Consultants of NC, P.C., 2022. Work Plan for Adjacent Property Soil Sampling. New
Hanover County Parcel No. R04712-003-001-000. July 13.
North Carolina Department of Environmental Quality, 2020. Revised Technical Guidance for
Risk -Based Environmental Remediation of Sites. April 2020.
GN7035B Soil Assessment Report 8 November 2022

FIGURES

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1. The topographic basemap was IGeosyntec
obtained database.
2. The PPID Parcel illustrated is New Hanover County Parcel Number 0
.. 0. ... -

NCD.Q NCDEQ NCDEQ
Analyte Units Residential Industrial/ Protection of
PSRG Commercial Groundwater IAr
PSRG PSRG
. t
Arsenic 0.68 3 5_8
Hexavalent Chromium mg/kg 0.31 6.5 3.8
Z5�2 Z6
Z5 Sample Depth
�'•. Sample Depth 0-2 Z5-5 Z613 Constituent
"I1 Constituent �5'3 Arsenic
Arsenic 3.8 ZrJ-4 Hexavalent Chromium
< Hexavalent Chromium 0.92
Z1
_
L
r '
Sample Depth
0-0.5 0.5-2
r
Constituent
Arsenic 1.3 2.1
U
Hexavalent Chrondum 0.78u-
s
j.'
O
Z1-2
Z-2-2
Z-2
Z
!.
Z1-3
Z2
Sample Depth
Z_
Z1-4
Constituent
0-0.5
C.
Z1-5 Z-Z-4
ZZ-5
Arsenic
as
sJ}
Z1
Hexavalent Chromium
0.66
Z3-1
Z4-1
Z�3-1
Za
Z4-2
Sample Depth
73
0-0.5
Z3-3
Z4-3
Constituent
Sample Depth
0-0.5
0.5-2
Arsenic
4.5
Constituent
Z4-4
Hexavalent Chromium
0.59
Arsenic 1.2
Hexavalent Chromium 0.68
2.1 U
0.96
`
1� elf
Legend No 10F N
Notes: Feet
1. Service Layer Credits: Source: Esri, Maxar, GeoEye, Earthstar Geographics, CNES/Airbus DS, USDA, USGS, AeroGRID, IGN, and
Aliquot Locations the GIS User Community
2. The locations of the former contractor laydown area and area of exported soil were provided by ECS Southeast, LLR
3. The exported soil was removed by 14 February 2022.
Gravel Driveway 4. The portion of the PPD Parcel illustrated is New Hanover County Parcel Number R00712-003-001-000.
r 5. mg/kg indicates milligrams per kilogram.
Former Contractor Laydown Area 6. NCDEQ indicates North Carolina Department of Environmental Quality.
7. PSRG indicates North Carolina Department of Environmental Quality Preliminary Soil Remediation Goals, published July 2022.
8. U indicates the analyte was not detected above the method
Area of Exported Soil detection limit.
9. Italics indicate method detection limits that exceed the lowest respective PSRG.
PPD Parcel Boundary 10. Analyte concentrations that exceed the Protection of Groundwater PSRG are underlined.
11. Analyte concentrations that exceed the Protection of Groundwater PSRG are underlined.
Almont Shipping 11 Boundary 12. Analyte detections that exceed Residential PSRG and Industrial/Commercial PSRG are highlighted in yellow and orange,
pp 9 rY respectively.
13. "Approximate Gravel Area" observed during 8 and 9 September 2022 soil sampling.
0-2
1.8
0.76
N
0.5-2
0.71
0.5-2
1.2
0.89
M►
PPD Property and
Soil Sample Analytical Results
Harnett Street
Wilmington, NC
Geosyntec(> Figure
consultants
Geosy- Cons W- of NC, P.C.
GN7035B November 2022 2

TABLES

Table 1
Soil Sample Analytical Results
Almont Shipping II Adjacent Property
Wilmington, North
Geosyntec
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Geosyntec Consultants of NC, P.C.
Analyte
NCDEQ
Residential
PSRG
NCDEQ
Industrial/
Commercial
PSRG
NCDEQ
Protection of
Groundwater
PSRG
Sample ID
Z1-0-0.5
Z1-0.5-2
Z2-0-0.5
Z2-0.5-2
Z3-0-0.5
Z3-0.5-2
DUP-20220908
Z4-0-0.5
Z4-0.5-2
Z5-0-2
Z6-0-2
DUP-20220909
VOC Sample
ID
Z1-1-0-0.5
Z1-1-1-1.5
Z2-2-0-0.5
Z2-3-1.5-2
Z3-3-0-0.5
Z3-3-1.5-2
Z3-3-1.5-2
Z4-1-0-0.5
Z4-2-1.5-2
Z5-5-1.5-2
Z6-5-1-1.5
Z6-5-1-1.5
Sample Date
9/8/2022
9/8/2022
9/8/2022
9/8/2022
9/8/2022
9/8/2022
9/8/2022
9/8/2022
9/8/2022
9/8/2022
9/8/2022
9/8/2022
Sample
Depth
(ft bgs)
0-0.5
0.5-2
0-0.5
0.5-2
0-0.5
0.5-2
0.5-2
0-0.5
0.5-2
0-0.5
0.5-2
0-2
Units
Volatile Organic Compounds b EPA Method 8260
Acetone
14,000
210,000
25
mg/kg
0.08
U
0.075
U
0.13
U
0.071
U
0.069
U
0.076
U
0.079
U
0.093
U
7.5
U
0.075
U
0.077
U
0.172
Benzene
1.2
5.4
0.01
mg/kg
0.00097
U
0.00091
U
0.0055
J
0.00087
U
0.00085
U
0.00093
U
0.00097
U
0.0011
U
0.091
U
0.00091
U
0.00094
U
0.00096
U
2-Butanone (MEK)
5,500
40,000
17
mg/kg
0.0058
U
0.0054
U
0.0127
J
0.0052
U
0.005
U
0.0055
U
0.0058
U
0.0068
U
0.54
U
0.0054
U
0.0056
U
0.0057
U
n-Butylbenzene
780
12,000
4.5
mg/kg
0.0008
U
0.00075
U
0.0013
U
0.00071
U
0.00069
U
0.00076
U
0.00079
U
0.00093
U
0.715
0.00075
U
0.00077
U
0.00079
U
sec-Butylbenzene
1,600
23,000
4.1
mg/kg
0.0008
U
0.00075
U
0.0013
U
0.00071
U
0.00069
U
0.00076
U
0.00079
U
0.00093
U
1.020
0.00075
U
0.00077
U
0.00079
U
Eth lbenzene
6.1
27
13
mg/kg
0.0008
U
1 0.00075
U
0.0016
J
0.00071
U
0.00069
U
0.00076
U
0.00079
U
0.00093
U
0.075
U
0.00075
U
0.00077
U
0.00079
U
Isopropylbenzene
410
2,100
2.3
mg/kg
0.0008
U
0.00075
U
1 0.0013
JUI
0.00071
U
0.00069
U
0.00076
U
0.00079
U
1 0.00093
JUI
0.269
J
0.00075
U
1 0.00077
1U1
0.00079
U
p-Isopropyltoluene
NC
NC
NC
mg/kg
0.0008
U
0.00075
U
0.0013
JUI
0.00071
U
0.00069
U
0.00076
U
0.00079
U
0.00093
JUI
0.075
U
0.00075
U
1 0.0011
1 J
0.0018
J
n-Propylbenzene
780
5,100
2.6
-/kg-g/kg
0.0008
U
0.00075
U
1 0.0013
JUI
0.00071
U
0.00069
U
0.00076
U
0.00079
U
1 0.00093
JUI
0.448
0.00075
U
1 0.00077
JUI
0.00079
U
Semi -Volatile Organic Com ounds h EPA Method 8270
Acenaphthene
720
9,000
16
mg/kg
0.019
U
0.019
U
0.019
U
0.019
U
0.019
U
0.019
U
0.018
U
0.019
U
0.0988
J
0.019
U
0.018
U
0.019
U
Anthracene
3,600
45,000
1300
mg/kg
0.0222
J
0.02
U
0.02
U
0.02
U
0.02
U
0.02
U
0.02
U
0.02
U
0.161
J
0.02
U
0.019
U
0.02
U
Benzo(a)anthracene
1.1
21
0.35
mg/kg
0.0844
J
0.019
J
0.018
U
0.018
U
0.0302
J
0.0201
J
0.017
U
0.0435
J
0.017
U
0.018
U
0.0262
J
0.018
U
Benzo(a)pyrene
0.11
2.1
0.12
mg/kg
0.0743
J
0.021
U
0.021
U
0.021
U
0.0372
J
0.021
U
0.021
U
0.0431
J
0.021
U
0.0212
J
0.0248
J
0.022
U
Benzo(b)fluoranthene
1.1
21
1.2
mg/kg
0.101
J
0.019
U
0.02
U
0.02
U
0.051
J
0.0229
J
0.019
U
0.0651
J1
0.019
U
0.0283
J1
0.0328
J
0.0243
J
Benzo(g,h,i)perylene
NC
NC
NC
mg/kg
0.0465
J
0.018
ul
0.019
U
0.019
U1
0.0254
J
0.018
ul
0.018
U
0.0258
J
0.018
U
0.018
U
0.0170
J
0.019
U
Benzo(k)fluoranthene
11
210
12
mg/kg
0.0504
J
0.023
U
0.024
U
0.023
U
0.023
U
0.023
U
0.023
U
0.023
U
0.023
U
0.023
U
0.022
U
0.024
U
Chrysene
110
2,100
36
mg/kg
0.0693
J
0.018
U
0.018
U
0.018
U
0.0247
J
0.018
U
0.018
U
0.0451
J
0.018
U
0.018
U
0.0184
J
0.019
U
bis(2-Ethy1hexy1)phtha1ate
39
160
14
mg/kg
0.035
U
0.035
U
0.036
U
0.036
U
0.035
U
0.035
U
0.035
U
0.0374
J
0.035
U
0.035
U
0.0444
J
0.0599
J
Fluoranthene
480
6,000
670
mg/kg
0.155
J
0.0182
J
0.018
U
0.018
U
0.0480
J
0.0317
J
0.017
U
0.0705
J
0.0338
J
0.0249
J
0.0309
J
0.018
U
Fluorene
480
6,000
110
mg/kg
0.019
U
0.019
U
0.019
U
0.019
U
0.019
U
0.019
U
0.019
U
0.019
U
0.126
J
0.019
ul
0.018
U
0.02
U
lndeno(l,2,3-cd)pyrene
1.1
1 21
1 3.9
I mg/kg
0.021
U1
0.021
JUI
0.022
JUI
0.022
JUI
0.0721
1 J
1 0.021
JUI
0.021
1 U
0.0594
J
0.021
U
0.021
U
0.0479
JI
0.0332
J
1-Methy1naphthalene
18
73
0.11
mg/kg
0.018
U
0.017
U
0.018
U
0.018
U
0.018
U
0.017
U
0.017
U
0.018
U
0.596
0.018
U
0.017
U
0.018
U
Phenanthrene
NC
NC
NC
mg/kg
0.0665
J
0.017
U1
0.018
U
0.018
U
0.0204
J
0.017
U
0.017
U
0.018
U
0.017
U
0.018
U
0.017
U
0.018
U
P rene
360
4,500
440
I m /k
0.139
JI
0.02
U1
0.021
U
0.021
U
0.0470
J
0.0326
J
0.02
U
0.0627
J
0.0859
J
1 0.0254
J
0.0258
J
0.021
lu
Metals by EPA Methods 6010, 7471, 7199
Arsenic
0.68
3
5.8
mg/kg
1.3
2.1
U
4.5
2.2
U
1.2
2.1
U
2.2
U
4.5
1.2
3.8
1.8
1.8
Barium
3,100
47,000
580
mg/kg
11.3
41
U
44
U
43
U
9.2
U
42
U
43
U
46
U
8.8
U
51
U
16.3
13.9
Cadmium
1.4
20
3
mg/kg
0.17
U
0.83
U
0.87
U
0.86
U
0.18
U
0.83
U
0.86
U
0.91
U
0.18
U
1
U
0.18
U
0.19
U
Chromium
NC
NC
NC
mg/kg
4.3
6.8
13.1
7
4.5
5.8
4.6
18.6
5.1
8.1
4.4
4.0
Hexavalent Chromium
0.31
6.5
3.8
mg/kg
0.78
0.85
0.66
0.71
0.68
0.96
1.1
0.59
0.89
0.92
0.76
0.76
Lead
250
1 800
1 270
1 mg/kg
1 32.6
1
1 28
1 17.5
1
1 180
1
24.5
1
35.9
1
32.5
5.7
1 23
1
1 73.8
27.2
24.9
Mercury
2.3
9.7
1
mg/kg
0.065
0.072
0.039
U
0.075
0.062
0.091
0.090
0.038
U
0.039
U
0.067
0.21
1
1 0.19
Selenium
78
1,200
2.1
mg/kg
0.87
U
4.1
U
4.4
U
4.3
U
0.92
U
4.2
U
4.3
U
4.6
U
0.88
U
5.1
1 U
0.89
JUI
0.96
U
Silver
78
1,200
3.4
mg/kg
0.44
U
2.1
U
2.2
U
2.2
U
0.46
U
2.1
U
2.2
U
2.3
U
0.44
U
2.6
U
0.45
JUI
0.49
U
Notes:
1) PSRG indicates North Carolina Department of Environmental Quality (NCDEQ) Preliminary Soil Remediation Goals, published July 2022
2) U indicates the analyte was not detected above the reporting limit. The reporting limit is shown in ahead of "U" unless otherwise noted.
3) J indicates an estimated concentration above the adjusted MDL and below the adjusted reporting limit
5) NC indicates no criteria
6) Analyte detections are identified in bold
7) Aalyte detections that exceed Residential PSRG and Industrial/Commercial PSRG are highlighted in yellow and orange, respectively
8) AMAe concentrations that exceed the Protection of Groundwater PSRG are underlined
9) Method Detection limits that exceed the lowest respective PSRG are identified in italics. Please note that reporting limits are greater than the corresponding MDLs. Therefore, the italicized text does not indicate that the MDL exceeds the lowest PSRG
10) mg/kg indicates milligrams per kilogram
11) Analytes detected in one or more samples are included in this table
12) EPA indicates U.S. Environmental Protection Agency
13) VOC indicates Volatile Organic Compounds
14) ft bgs indicates feet/foot below ground surface
1 of 1

APPENDIX A

Geosyntec Consultants
Boring Log
GeosMtec
consultants
DRILLING CO.: N/A SITE: C+T/PPD Boring ID: Grid/Zone 1
DRILLER: J. Nolan PROJECT NO.: GN7035B Sheet: I of 1
DRILLING METHOD: Hand Auger DATE STARTED: 8 Sept 2022 Borehole Location Sketch Map / Reference
RIG: DATE FINISHED: 8 Sept 2022
BIT DIAMETER/TYPE: SUPERVISOR: A. Wesley
SAMPLE METHOD: Comnosite/ VOC erab PHOTO TAKEN:
Lithology Log
Depth
ft bls Time
( ) [Secondary/PRIMARY soil type, color, moisture, trace content,
density/consistency, plasticity, grain size]
0-0.5'
0.5'-1.0'
1.0'-1.5'
1.5'-2.0'
0-0.5'
0.5'-1.0'
1.0'-1.5'
1.5'-2.0'
0-0.5'
0.5'-1.0'
1.0'-1.5'
1.5'-2.0'
0-0.5'
0.5'-1.0'
1.0'-1.5'
1.5'-2.0'
0-0.5'
0.5'-1.0'
1.0'-1.5'
1.5'-2.0'
Z1-1
000 organics (soil/grass), medium sand with silt, brown, loose, moist to dry
same as above (all sand with silt), poorly graded
same as above, moist
same as above, moist
Z1-2
organics, dark brown, moist, silt and gravel
silty sand with clay and gravel <2" in diameter, light brown, loose, moist
same as above, light brown, clasts appear to be concrete
same as above
Z1-3
organics, fine to medium sand with silt, brown, loose, moist, poorly graded
poorly graded, fine to medium sand, brown, loose, with silt, moist
fine to medium grain sand with silt and gravel, loose, clasts <1.5", moist
same as above
1030 Z14
organics, well graded, fine to coarse sand, light brown, with silt, loose, dry
fine to medium sand with silt, light brown, loose, dry
medium grained sand, light brown, poorly graded, some < 1 " gravel, loose, i
same as above; gravel up to 2"
1050 Z1-5
organics with silt, sand and gravel, loose, brown, moist
well graded sand with gravel and silt
same as above, larger gravel up to 3"
refusal; hand auger bent
USCS / Rock I Run I Rec I SPT / I Notes / Sample ID / Water
Type
(No.)
(%)
RQD
VOCS
Level
VOC sample @ 1100
sw
15.6
(Z1-1-0-0.5')
SP
7.0
SP
7.8
VOC sample @ 1106
SP
3.7
7.1
SW
0.0
SW
0.0
SW
0.6
SP
0.0
SP
0.0
SW
0.0
SW
0.0
SW
0.0
SW
0.0
SP
0.0
SP
0.0
SW
1.2
SW
1.0
SW
1.8

Geosyntec Consultants
Boring Log
GeosMtec
consultants
DRILLING CO.: N/A
SITE: C+T/PPD
Boring ID: Grid/Zone 2
DRILLER: J. Nolan
PROJECT NO.:
Sheet: I of I
GN7035B
DRILLING METHOD: Hand Auger
DATE STARTED: g Sept 2022
Borehole Location Sketch Map / Reference
RIG:
DATE FINISHED: g Sept 2022
BIT DIAMETER/TYPE:
SUPERVISOR: A. Wesley
SAMPLE METHOD: Composite/ VOC grab PHOTO TAKEN:
Lithology Log
Depth USCS / Rock
Run Rec SPT / Notes / Sample ID / Water
Time
ft (bls) [Secondary/PRIMARY soil type, color, moisture, trace content, Type
(No.) RQD Level
density/consistency, plasticity, grain size]
VOCs
Z2-1 (offset)
0-0.5'
1245
brown silty sand with —50% gravel (well graded)
SW-GW
0.0
0.5'-1.0'
same as above, moist
SW-GW
0.0
1.0'-2.0'
poorly graded, medium sand, dark brown, moist, gravel up to 5"
SP
0.0
Z2-2
VOC sample
0-0.5'
Top 4" of soil and organics, gravel and sand with silt and clay, dark brown,
SW- GW
0.7
Z2-2-0-0.5'
moist, gravel up to 2.5"
0.5'-2.0'
poorly graded medium sand, moist, loose, dark brown grading to beige
SP
0.1
(top to bottom)
Z2-3
0-0.5
light brown, gravel with sand, gravel <2" to medium sand, brown, loose,
th GW
0.0
Solvent/HCO odor —2ftbgs
0.5'-1.0'
light brown, same as above
SW-GW
0.0
1.0'-1.5'
dark brown, medium sand with gravel, moist
SP
0.1
VOC Sample
1.5'-2.0'
reddish brown, poorly graded, medium sand, moist
SP
14.0
Z2-3-0.5-2.'0
Z24
0-0.5'
light brown silty sand with gravel clasts <5", moist
SW
0.0
same as above
SW
0.0
1.0'-1.5'
SP
0.0
dark brown, medium, loose, sand with silt, moist
1.5'-2.0'
same as above with larger gravel clasts and pieces of reddish dry clay
SP
0.0
Z1-5
0-0.5'
silty sand with gravel, poorly graded, gravel <3", dry to moist
SP GP
0.0
0.5'-1.0'
0.0
silty medium sand with gravel, brown, moist, gravel <3"
SP
1.0'-1.5'
same as above
SP
0.0
1.5'-2.0'
same as above, reddish brown, larger gravel (4"), moist to wet at 2'
SP
0.0

Geosyntec Consultants
Boring Log
GeosMtec
consultants
DRILLING CO.: N/A
SITE: C+T/PPD
Boring ID: Grid/Zone 3
DRILLER: J. Nolan
PROJECT NO.: GN7035B
Sheet: I of 1
DRILLING METHOD: Hand Auger
DATE STARTED: 9 Sept 2022
Borehole Location Sketch Map / Reference
RIG:
DATE FINISHED: 9 Sept 2022
BIT DIAMETER/TYPE:
SUPERVISOR: A. Wesley
SAMPLE METHOD: Composite/ VOC grab PHOTO TAKEN:
Lithology Log
Depth USCS / Rock
Run Rec SPT / Notes / Sample ID / Water
Time
$ (bls) [Secondary/PRIMARY soil type, color, moisture, trace content, Type
(No.) RQD Level
density/consistency, plasticity, grain size]
` ocs
Z3-1
0-0, 5'
silt with sand (medium grain) and organics, light brown, dry, loose
ML
0.0
0.5'-2.0'
light brown, fine to medium grain sand with silt and gravel with clasts <2"
SW
0.0
Z3-2
0-0.5'
sand with silt and gavel, moist, and brown
SW
0.0
0.5'-2.0'
sand with gravel, brown, moist, medium grain sand
SW
0.0
1600
Z3-3 - starts —10 inches bgs due to gravel layer
0-0.5'
silty sand with gravel, dark brown, moist, loose, gravel <4"
SW
0.0
VOC sample Z3-3-0-0.5'
same as above
SW
0.0
VOC Samples
1.5'-2.0'
beige sand, medium to coarse grain sand, moist
SP
0.0
Z3-3-0.5-2.0' and
DUP-20220908
Z3-4
0-0.5'
silt with medium -grained sand and organics, light brown, dry, loose
ML
0.0
0.5'-2.0'
light brown, fine to medium grained sand with silt and gravel (<2")
SW
0.0
Z3-5
0-0.5'
silt with sand, gravel, and organics, brown, dry to moist
ML
0.0
0.5'-1.0'
light brown, fine to medium grained sand with silt and gravel up to 2"
SW
0.0
1.0'-2.0'
beige, medium grained sand, moist
SP
0.0

Geosyntec Consultants
Boring Log
GeosMtec
consultants
DRILLING CO.: N/A
SITE: C+T/PPD
Boring ID: Grid/Zone 4
DRILLER: J. Nolan
PROJECT NO.:
Sheet: 1 Of 1
GN7035B
DRILLING METHOD: Hand Auger
DATE STARTED: 9 Sept 2022
Borehole Location Sketch Map / Reference
RIG:
DATE FINISHED: 9 Sept 2022
BIT DIAMETER/TYPE:
SUPERVISOR: A. Wesley
SAMPLE METHOD: Composite/ VOC grab PHOTO TAKEN:
Lithology Log
Depth USCS / Rock
Run Rec SPT / Notes / Sample ID / Water
Time
$ (bls) [Secondary/PRIMARY soil type, color, moisture, trace content, Type
(No.) (%) RQD Level
density/consistency, plasticity, grain size]
` ocs
Z4-1
VOC sample
0-0.5'
0820
sand (well graded) with clay and gravel, gravel <2", light brown to gray,
SW
0.4
moist
(Z4-1-0-0.5')
10.7
OS-1.0'
medium sand with gravel <2", light brown to gray, dry, loose
SW-GW
12.6
1.0'-2.0'
fine to medium sand with silt, moist, dark brown (piece of geotextile
SW
1.6
observed)
Z4-2
0.0
0-0.5'
sand (well graded) with clay and gravel, gravel <2", light brown to gray,
SW
0.5'-1.0'
moist
SW
0.0
HCO �2ft bgS
same as above, sand with clay, silt and gravel, gray, dry
1.0'-1.5'
light brown sand with gravel <4", moist
SP/SW
36.2
VOC sample
1.5'-2.0'
dark brown sand, moist, medium grain sand with silt and some gravel
SP/SW
248.0
(Z4-2-0.5-2.0')
Z4-3- starts at 8.5" bgs due to gravel cover
0-0,5'
sand (well graded) with silt and clay, gravel <2", light brown
SW
0.0
0.5 -1.0 '
reddish dark brown medium grain sand with silt and gravel <2"
SP
0.0
1.0'-1.5'
beige and reddish brown sand, moist
SP
0.0
1.5'-2.0'
dark brown, moist, medium grain sand
Sp
O.5
Z4-4
0-O.5'
sand (well graded) with clay and gravel, gravel <2", light brown to gray,
sw
0.0
moist
OS-1.0'
same as above
SW
0.0
1.0 -1.5
well graded, medium grain sand, brown
SW
0.0
medium grain sand with silt and gravel
1.5'-2.0'
sw
0.0
Z4-5
0-0.5'
soil with organics (d. brown) below sand with gravel and clay light beige to
SW
0.0
gray, dry
0.5'-1.0'
same as above, well graded
SW
0.0
1.0'-1,5'
medium sand with silt, light brown, dry to moist
SP
0.0
1.5'-2.0'
beige, same as above, moist
SP
0.0

Geosyntec Consultants
Boring Log
GeosMtec
consultants
DRILLING CO.: N/A
SITE: C+T/PPD
Boring ID:Grid/Zone 5
DRILLER: J. Nolan
PROJECT NO.: GN7035B
Sheet: 1 of I
DRILLING METHOD: Hand Auger
DATE STARTED: g Sept 2022
Borehole Location Sketch Map / Reference
RIG:
DATE FINISHED: g Sept 2022
BIT DIAMETER/TYPE:
SUPERVISOR: A. Wesley
SAMPLE METHOD: Composite/ VOC grab PHOTO TAKEN:
Lithology Log
Depth USCS / Rock
Run Rec SPT / Notes / Sample ID / Water
Time
$ (bls) [Secondary/PRIMARY soil type, color, moisture, trace content, Type
(No.) RQD Level
density/consistency, plasticity, grain size]
` ocs
Z5-1
0-0.5'
clayey gravel with sand, light brown, gravel clasts up to 4"
GW
0.0
0.5' -2.0'
dark reddish brown, medium grain sand with clay, moist
SW
0.0
0-0.5'
Z5-2
clayey gravel with sand, light brown, gavel clasts <4"
GW
0.0
0.5'-2.0'
dark reddish brown, medium grain sand with clay, moist
SW
0.1
Z5-3
0-0.5'
clayey gravel with sand, light brown, gravel clasts <4"
GW
0.0
0.5'-2.0'
dark reddish brown, medium grain sand with clay, moist
SW
0.0
Z5-4
0-0 5 '
clayey gravel with sand, light brown, gravel clasts <4"
GW
0.0
0 5'_2 0'
dark reddish brown, medium grain sand with clay, moist
SW
0.0
Z5-5
0-0.5'
gravelly silt and sand, beige, dry
SW/ML
0.0
0.5'-1.0'
silt and sand, dry, loose, dark brown
SW/ML
0.0
1.0'-2.0'
medium sand with clay and gravel, moist
SW
0.6
VOC sample
(Z5-5-1.5-2.0')

Geosyntec Consultants
Boring Log
GeosMtec
consultants
DRILLING CO.: N/A
SITE: C+T/PPD
Boring ID:Grid/Zone 6
DRILLER: J. Nolan
PROJECT NO.:
Sheet: 1 of I
GN7035B
DRILLING METHOD: Hand Auger
DATE STARTED: 9 Sept 2022
Borehole Location Sketch Map / Reference
RIG:
DATE FINISHED: 9 Sept 2022
BIT DIAMETER/TYPE:
SUPERVISOR: A. Wesley
SAMPLE METHOD: Composite/ VOC grab PHOTO TAKEN:
Lithology Log
Depth USCS / Rock
Run Rec SPT / Notes / Sample ID / Water
Time
ft (bls) [Secondary/PRIMARY soil type, color, moisture, trace content, Type
(No.) RQD Level
density/consistency, plasticity, grain size]
` ocs
Z6-1
0-0.5'
Refusal - attempted multiple locations
Z6-2
0.5
boring filled with water
0-0.5'
concrete slab
shortly after advancing
2.3
0.5'-1.0'
damp medium sand with silt
SW
2.5
1.0'-2.0'
same as above, moist to wet
SW
1.2
Z6-3
0-0.5'
top —3 inches is light brown soil with grass; grades
SP
0.0
into silty fine grained sand, loose, poorly graded, dry,
light brown
0.5'-2.0'
brown to gray sand with silt, clay, and gravel (<3")
SW
0.0
Z6-4
0-0.5
top —1-3 inches soil with grass; silty fine grained sand,
SP
0.0
loose, poorly graded, dry, light brown
0.5'-1.0'
fine grained, poorly graded sand (same as above)
SP
0.0
1.0-1.5
beige, poorly graded medium sand, moist, loose
SP
0.0
1.5-2.0'
dark brown silty sand, moist, medium dense, well
SW
0.0
graded
Z6-5
0-0.5
top —1-3 inches soil with grass; silty fine grained sand
"),
SP
0.0
with gravel (<1 loose, dry, light brown
0.5'-1.0'
medium grained sand, light brown, moist, poorly graded
SP
0.0
VOC samples
7.3
1.0'-2.0'
brown, medium grained sand, poorly graded with tree roots (or buried bark?
SP
Z6-5-1-1.5' and
moist to wet
0.0
DUP-20220909

APPENDIX B

Orlando, FL
The results set forth herein are provided by SGS North America Inc. a-Hl ydcopy 2. 0
Automated Report
Technical Report for
Geosyntec Consultants
PPD; Harnett St, Wilmington, NC
SGS Job Number: FA98838
Sampling Date: 09/08/22
Report to:
Geosyntec Consultants
314 Wad nut St Suite 200
Wilmington, NC 28401
[e-mail]
TTN: Abby Wesley
Total number of pages in report: 99
Test r esults contained within this data package meet the requirements
Norm Farmer
Technical Director
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
CI i ent Service contact: Kelly Blanchard 407-425-6700
Certifications: FL(E83510), LA(03051), KS(E-10327), NC(573), NJ(FL002), NY(12022), SC(96038001)
DoD ELAP(ANAB 1-2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177),
AL, AK, AR, CT, IA, KY, MA, MI. MS, ND, NH, NV, OK, OR, IL, UT, VT, WA, WI, WV
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc. • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: [phone] • fax: [phone]
SGS is the sole authority for authorizing edits or modifications to this document. Please share your ideas about
Unauthorized modification of this report is strictly prohibited. how we can serve you better at: -.SGS
_
Review standard terms at: http://www.sgs.com/en/terms-and-conditions [e-mail]
1 of 99
FA98838

Sections:
Table of Contents
-I-
Section1: Sample Summary...................................................................................................
3
Section2: Summary of Hits....................................................................................................
5
Section3: Sample Results........................................................................................................
8
3.1: FA98838-1: Z1-1-0-0.5.................................................................................................
9
3.2: FA98838-2: Z1-1-1-1.5.................................................................................................
12
3.3: FA98838-3: Z1-0-0.5....................................................................................................
15
3.4: FA98838-4: Z1-0.5-2....................................................................................................
19
3.5: FA98838-5: Z2-2-0-0.5.................................................................................................
23
3.6: FA98838-6: Z2-3-1.5-2.................................................................................................
26
3.7: FA98838-7: Z2-0-0.5....................................................................................................
29
3.8: FA98838-8: Z2-0.5-2....................................................................................................
33
3.9: FA98838-9: Z3-3-0-0.5.................................................................................................
37
3.10: FA98838-10: Z3-3-1.5-2.............................................................................................
40
3.11: FA98838-11: Z3-0-0.5................................................................................................
43
3.12: FA98838-12: Z3-0.5-2................................................................................................
47
3.13: FA98838-13: DUP-20220908.....................................................................................
51
3.14: FA98838-14: Z5-0-2...................................................................................................
58
3.15: FA98838-15: Z5-5-1.5-2.............................................................................................
62
Section4: Misc. Forms............................................................................................................
65
4.1: Chain of Custody...........................................................................................................
66
Section 5: MS Volatiles - QC Data Summaries.....................................................................
71
5.1: Method Blank Summary................................................................................................
72
5.2: Blank Spike Summary...................................................................................................
75
5.3: Matrix Spike/Matrix Spike Duplicate Summary...........................................................
78
Section 6: MS Semi-volatiles - QC Data Summaries............................................................
81
6.1: Method Blank Summary................................................................................................
82
6.2: Blank Spike Summary...................................................................................................
84
6.3: Matrix Spike/Matrix Spike Duplicate Summary...........................................................
86
Section 7: Metals Analysis - QC Data Summaries................................................................
88
7.1: Prep QC MP41212: Hg..................................................................................................
89
7.2: Prep QC MP41216: As,Ba,Cd,Cr,Pb,Se,Ag..................................................................
94
.SGS

SGS North America Inc.
Sample Summary
Geosyntec Consultants
PPD; Harnett St, Wilmington, NC
Job No: FA98838
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
This report contains results reported as ND = Not detected. The following applies:
Organics ND = Not detected above the MDL
FA98838-1
09/08/22
11:00 JNAW 09/ 10/22
SO
Soil
Z 1-1-0-0.5
FA98838-2
09/08/22
11:00 JNAW 09/10/22
SO
Soil
Z1-1-1-1.5
FA98838-3
09/08/22
11:00 JNAW 09/10/22
SO
Soil
Z1-0-0.5
FA98838-4
09/08/22
11:00 JNAW 09/10/22
SO
Soil
Z1-0.5-2
FA98838-5
09/08/22
14:00 JNAW 09/10/22
SO
Soil
Z2-2-0-0.5
FA98838-6
09/08/22
14:00 JNAW 09/10/22
SO
Soil
Z2-3-1.5-2
FA98838-7
09/08/22
14:00 JNAW 09/10/22
SO
Soil
Z2-0-0.5
FA98838-8
09/08/22
14:00 JNAW 09/10/22
SO
Soil
Z2-0.5-2
FA98838-9
09/08/22
16:00 JNAW 09/10/22
SO
Soil
Z3-3-0-0.5
FA98838-10
09/08/22
16:00 JNAW 09/10/22
SO
Soil
Z3-3-1.5-2
FA98838-11
09/08/22
16:00 JNAW 09/10/22
SO
Soil
Z3-0-0.5
FA98838-12
09/08/22
16:00 JNAW 09/10/22
SO
Soil
Z3-0.5-2
Soil samples reported on a dry weight basis unless otherwise indicated on result page.
SGS3 of 99
FA98838

SGS North America Inc.
Sample Summary
(continued)
Geosyntec Consultants
PPD; Harnett St, Wilmington, NC
Job No: FA98838
ample Collected Matrix Client
lumber Date Time By Received Code Type Sample ID
FA98838-13 09/08/22 16:30 JNAW 09/10/22 SO Soil DUP-20220908
FA98838-14 09/08/22 17:15 JNAW 09/10/22 SO Soil Z5-0-2
FA98838-15 09/08/22 17:15 JNAW 09/10/22 SO Soil Z5-5-1.5-2
Soil samples reported on a dry weight basis unless otherwise indicated on result page.
SGS4 of 99
FA98838

Summary of Hits
Job Number:
FA98838
Account:
Geosyntec Consultants
Project:
PPD; Harnett St, Wilmington, NC
Collected:
09/08/22
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA98838-1 Z1-1-0-0.5
No hits reported in this sample.
FA98838-2 Z1-1-1-1.5
No hits reported in this sample.
FA98838-3 Z1-0-0.5
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(k)fluoranthene
Benzo(g, h, i)perylene
Benzo(k)fluoranthene
Chrysene
Fluoranthene
Phenanthrene
Pyrene
Arsenic
Barium
Chromium
Lead
Mercury
FA98838-4 Z1-0.5-2
Benzo(a)anthracene
Fluoranthene
Chromium a
Lead a
Mercury
FA98838-5 Z2-2-0-0.5
Benzene
2-Butanone (MEK)
Ethylbenzene
FA98838-6 Z2-3-1.5-2
No hits reported in this sample.
22.2 J
180
20
ug/kg
SW846 8270E
84.4 J
180
18
ug/kg
SW846 8270E
74.3 J
180
21
ug/kg
SW846 8270E
101 J
180
19
ug/kg
SW846 8270E
46.5 J
180
18
ug/kg
SW846 8270E
50.4 J
180
23
ug/kg
SW846 8270E
69.3 J
180
18
ug/kg
SW846 8270E
155 J
180
18
ug/kg
SW846 8270E
66.5 J
180
18
ug/kg
SW846 8270E
139 J
180
20
ug/kg
SW846 8270E
1.3
0.44
mg/kg
SW846 6010D
11.3
8.7
mg/kg
SW846 6010D
4.3
0.44
mg/kg
SW846 6010D
32.6
0.87
mg/kg
SW846 6010D
0.065
0.043
mg/kg
SW846 7471B
19.0 J
170
17
ug/kg
SW846 8270E
18.2 J
170
17
ug/kg
SW846 8270E
6.8
2.1
mg/kg
SW846 6010D
28.0
4.1
mg/kg
SW846 6010D
0.072
0.039
mg/kg
SW846 7471B
5.5 J
6.5
1.6
ug/kg
SW846 8260D
12.7 J
33
9.5
ug/kg
SW846 8260D
1.6 J
6.5
1.3
ug/kg
SW846 8260D
Page 1 of 3
SGS5 of 99
FA98838

Summary of Hits
Job Number:
FA98838
Account:
Geosyntec Consultants
Project:
PPD; Harnett St, Wilmington, NC
Collected:
09/08/22
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA98838-7 Z2-0-0.5
Arsenic a
4.5
2.2
mg/kg
SW846 6010D
Chromium a
13.1
2.2
mg/kg
SW846 6010D
Lead a
17.5
4.4
mg/kg
SW846 6010D
FA98838-8 Z2-0.5-2
Chromium a
7.0
2.2
mg/kg
SW846 6010D
Lead a
180
4.3
mg/kg
SW846 6010D
Mercury
0.075
0.039
mg/kg
SW846 7471B
FA98838-9 Z3-3-0-0.5
No hits reported in this sample.
FA98838-10 Z3-3-1.5-2
No hits reported in this sample.
FA98838-11 Z3-0-0.5
Benzo(a)anthracene
30.2 J
180
18
ug/kg
SW846 8270E
Benzo(a)pyrene
37.2 J
180
21
ug/kg
SW846 8270E
Benzo(b)fluoranthene
51.0 J
180
19
ug/kg
SW846 8270E
Benzo(g, h, i)perylene
25.4 J
180
18
ug/kg
SW846 8270E
Chrysene
24.7 J
180
18
ug/kg
SW846 8270E
Fluoranthene
48.0 J
180
18
ug/kg
SW846 8270E
Indeno(1,2,3-cd)pyrene
72.1 J
180
21
ug/kg
SW846 8270E
Phenanthrene
20.4 J
180
18
ug/kg
SW846 8270E
Pyrene
47.0 J
180
20
ug/kg
SW846 8270E
Arsenic
1.2
0.46
mg/kg
SW846 6010D
Chromium
4.5
0.46
mg/kg
SW846 6010D
Lead
24.5
0.92
mg/kg
SW846 6010D
Mercury
0.062
0.042
mg/kg
SW846 7471B
FA98838-12 Z3-0.5-2
Benzo(a)anthracene
20.1 J
170
17
ug/kg
SW846 8270E
Benzo(b)fluoranthene
22.9 J
170
19
ug/kg
SW846 8270E
Fluoranthene
31.7 J
170
17
ug/kg
SW846 8270E
Pyrene
32.6 J
170
20
ug/kg
SW846 8270E
Chromium a
5.8
2.1
mg/kg
SW846 6010D
Lead a
35.9
4.2
mg/kg
SW846 6010D
Mercury
0.091
0.044
mg/kg
SW846 7471B
Page 2 of 3
SGS6 of 99
FA98838

Summary of Hits
Job Number:
FA98838
Account:
Geosyntec Consultants
Project:
PPD; Harnett St, Wilmington, NC
Collected:
09/08/22
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA98838-13 DUP-20220908
Chromium a
4.6
Lead a
32.5
Mercury
0.090
FA98838-14 Z5-0-2
Benzo(a)pyrene
21.2 J
Benzo(b)fluoranthene
28.3 J
Fluoranthene
24.9 J
Pyrene
25.4 J
Arsenic a
3.8
Chromium a
8.1
Lead a
73.8
Mercury
0.067
FA98838-15 Z5-5-1.5-2
No hits reported in this sample.
(a) Sample dilution required due to difficult matrix.
2.2
mg/kg
SW846 6010D
4.3
mg/kg
SW846 6010D
0.037
mg/kg
SW846 7471B
180 21
ug/kg
SW846 8270E
180 19
ug/kg
SW846 8270E
180 18
ug/kg
SW846 8270E
180 20
ug/kg
SW846 8270E
2.6
mg/kg
SW846 6010D
2.6
mg/kg
SW846 6010D
5.1
mg/kg
SW846 6010D
0.042
mg/kg
SW846 7471B
Page 3 of 3
S.GV 7 of 99
FA98838

Orlando, FL
Sample Results
Report of Analysis
Section 3
GS8 of 99
FA98838

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:
Z1-1-0-0.5
Lab Sample ID:
FA98838-1 Date Sampled: 09/08/22
Matrix:
SO - Soil Date Received: 09/10/22
Method:
SW846 8260D Percent Solids: n/a a
Project:
PPD; Harnett St, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 170104657.1) 1 09/14/22 14:34 DB n/a n/a VF3752
Run #2
Initial Weight Final Volume
Run #1 6.27 g 5.0 ml
Run #2
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units
67-64-1
Acetone
ND
160
80
ug/kg
71-43-2
Benzene
ND
4.0
0.97
ug/kg
108-86-1
Bromobenzene
ND
4.0
0.80
ug/kg
74-97-5
Bromochloromethane b
ND
4.0
1.2
ug/kg
75-27-4
Bromodichloromethane
ND
4.0
0.80
ug/kg
75-25-2
Bromoform
ND
4.0
0.80
ug/kg
78-93-3
2-Butanone (MEK)
ND
20
5.8
ug/kg
104-51-8
n-Butylbenzene °
ND
4.0
0.80
ug/kg
135-98-8
sec-Butylbenzene
ND
4.0
0.80
ug/kg
98-06-6
tert-Butylbenzene
ND
4.0
0.80
ug/kg
56-23-5
Carbon Tetrachloride
ND
4.0
0.81
ug/kg
108-90-7
Chlorobenzene
ND
4.0
0.80
ug/kg
75-00-3
Chloroethane
ND
4.0
1.6
ug/kg
67-66-3
Chloroform
ND
4.0
1.1
ug/kg
95-49-8
o-Chlorotoluene
ND
4.0
0.80
ug/kg
106-43-4
p-Chlorotoluene
ND
4.0
0.80
ug/kg
124-48-1
Dibromochloromethane
ND
4.0
0.80
ug/kg
106-93-4
1,2-Dibromoethane
ND
4.0
0.80
ug/kg
75-71-8
Dichlorodifluoromethane
ND
4.0
1.6
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
4.0
0.80
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
4.0
0.80
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
4.0
0.92
ug/kg
75-34-3
1, 1 -Dichloroethane
ND
4.0
1.4
ug/kg
107-06-2
1,2-Dichloroethane
ND
4.0
0.80
ug/kg
75-35-4
1, 1 -Dichloroethylene
ND
4.0
0.80
ug/kg
156-59-2
cis-1,2-Dichloroethylene
ND
4.0
1.1
ug/kg
156-60-5
trans- 1, 2-Dichloroethylene
ND
4.0
0.80
ug/kg
78-87-5
1,2-Dichloropropane
ND
4.0
0.80
ug/kg
142-28-9
1,3-Dichloropropane
ND
4.0
0.80
ug/kg
594-20-7
2,2-Dichloropropane
ND
4.0
0.80
ug/kg
563-58-6
1, 1 -Dichloropropene
ND
4.0
0.81
ug/kg
10061-01-5
cis- 1, 3 -Dichloropropene
ND
4.0
0.80
ug/kg
01
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS9 of 99
FA98838

SGS North America Inc.
Report of Analysis
Page 2 of 3
Client Sample ID:
Z1-1-0-0.5
Lab Sample ID:
FA98838-1 Date Sampled: 09/08/22
Matrix:
SO - Soil Date Received: 09/10/22
Method:
SW846 8260D Percent Solids: n/a a
Project:
PPD; Harnett St, Wilmington, NC
VOA List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
10061-02-6
trans- 1, 3-Dichloropropene
ND
4.0
0.80
ug/kg
108-20-3
Di -Isopropyl Ether
ND
4.0
1.9
ug/kg
64-17-5
Ethyl Alcohol d
ND
320
60
ug/kg
100-41-4
Ethylbenzene
ND
4.0
0.80
ug/kg
591-78-6
2-Hexanone c
ND
20
6.0
ug/kg
98-82-8
Isopropylbenzene
ND
4.0
0.80
ug/kg
99-87-6
p-Isopropyltoluene
ND
4.0
0.80
ug/kg
74-83-9
Methyl Bromide
ND
4.0
1.6
ug/kg
74-87-3
Methyl Chloride
ND
4.0
1.6
ug/kg
75-09-2
Methylene Chloride e
ND
16
8.8
ug/kg
108-10-1
4-Methyl-2-pentanone (MIBK) ND
20
6.0
ug/kg
1634-04-4
Methyl Tert Butyl Ether
ND
4.0
0.80
ug/kg
91-20-3
Naphthalene
ND
4.0
1.6
ug/kg
103-65-1
n-Propylbenzene
ND
4.0
0.80
ug/kg
100-42-5
Styrene
ND
4.0
0.80
ug/kg
630-20-6
1, 1, 1, 2-Tetrachloroethane
ND
4.0
0.82
ug/kg
79-34-5
1,1,2,2-Tetrachloroethane °
ND
4.0
0.80
ug/kg
127-18-4
Tetrachloroethylene
ND
4.0
1.0
ug/kg
108-88-3
Toluene
ND
16
8.0
ug/kg
87-61-6
1, 2,3 -Trichlorobenzene
ND
4.0
1.1
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
4.0
0.80
ug/kg
71-55-6
1, 1, 1 -Trichloroethane
ND
4.0
0.80
ug/kg
79-00-5
1,1,2-Trichloroethane
ND
4.0
0.80
ug/kg
79-01-6
Trichloroethylene
ND
4.0
0.80
ug/kg
75-69-4
Trichlorofluoromethane
ND
4.0
1.6
ug/kg
96-18-4
1, 2,3 -Trichloropropane
ND
4.0
1.0
ug/kg
95-63-6
1,2,4-Trimethylbenzene
ND
4.0
0.80
ug/kg
108-67-8
1,3,5-Trimethylbenzene
ND
4.0
0.80
ug/kg
108-05-4
Vinyl Acetate
ND
20
13
ug/kg
75-01-4
Vinyl Chloride
ND
4.0
0.80
ug/kg
m,p-Xylene
ND
8.0
0.88
ug/kg
95-47-6
o-Xylene
ND
4.0
0.80
ug/kg
1330-20-7
Xylene (total)
ND
12
1.7
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
1868-53-7
Dibromofluoromethane
92%
75-124%
17060-07-0
1,2-Dichloroethane-D4
122%
72-135%
2037-26-5
Toluene-D8
113%
75-126%
460-00-4
4-Bromofluorobenzene
112%
71-133%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS10 of 99
FA98838

SGS North America Inc.
Report of Analysis
Page 3 of 3
Client Sample ID:
Z1-1-0-0.5
Lab Sample ID:
FA98838-1 Date Sampled: 09/08/22
Matrix:
SO - Soil Date Received: 09/10/22
Method:
SW846 8260D Percent Solids: n/a a
Project:
PPD; Harnett St, Wilmington, NC
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(a) All results reported on a wet weight basis.
(b) Associated CCV and BS outside control limits low.
(c) Associated CCV outside control limits high, sample is ND.
(d) Associated CCV outside control limits low.
(e) Associated CCV and BS recovery outside control limits high, sample is ND.
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
aSGV 11 of 99
FA98838

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:
Z1-1-1-1.5
Lab Sample ID:
FA98838-2 Date Sampled: 09/08/22
Matrix:
SO - Soil Date Received: 09/10/22
Method:
SW846 8260D Percent Solids: n/a a
Project:
PPD; Harnett St, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 170104658.1) 1 09/14/22 14:58 DB n/a n/a VF3752
Run #2
Initial Weight Final Volume
Run #1 6.67 g 5.0 ml
Run #2
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
67-64-1
Acetone
ND
150
75
ug/kg
71-43-2
Benzene
ND
3.7
0.91
ug/kg
108-86-1
Bromobenzene
ND
3.7
0.75
ug/kg
74-97-5
Bromochloromethane b
ND
3.7
1.1
ug/kg
75-27-4
Bromodichloromethane
ND
3.7
0.75
ug/kg
75-25-2
Bromoform
ND
3.7
0.75
ug/kg
78-93-3
2-Butanone (MEK)
ND
19
5.4
ug/kg
104-51-8
n-Butylbenzene °
ND
3.7
0.75
ug/kg
135-98-8
sec-Butylbenzene
ND
3.7
0.75
ug/kg
98-06-6
tert-Butylbenzene
ND
3.7
0.75
ug/kg
56-23-5
Carbon Tetrachloride
ND
3.7
0.76
ug/kg
108-90-7
Chlorobenzene
ND
3.7
0.75
ug/kg
75-00-3
Chloroethane
ND
3.7
1.5
ug/kg
67-66-3
Chloroform
ND
3.7
1.0
ug/kg
95-49-8
o-Chlorotoluene
ND
3.7
0.75
ug/kg
106-43-4
p-Chlorotoluene
ND
3.7
0.75
ug/kg
124-48-1
Dibromochloromethane
ND
3.7
0.75
ug/kg
106-93-4
1,2-Dibromoethane
ND
3.7
0.75
ug/kg
75-71-8
Dichlorodifluoromethane
ND
3.7
1.5
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
3.7
0.75
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
3.7
0.75
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
3.7
0.86
ug/kg
75-34-3
1, 1 -Dichloroethane
ND
3.7
1.3
ug/kg
107-06-2
1,2-Dichloroethane
ND
3.7
0.75
ug/kg
75-35-4
1, 1 -Dichloroethylene
ND
3.7
0.75
ug/kg
156-59-2
cis-1,2-Dichloroethylene
ND
3.7
1.0
ug/kg
156-60-5
trans- 1, 2-Dichloroethylene
ND
3.7
0.75
ug/kg
78-87-5
1,2-Dichloropropane
ND
3.7
0.75
ug/kg
142-28-9
1,3-Dichloropropane
ND
3.7
0.75
ug/kg
594-20-7
2,2-Dichloropropane
ND
3.7
0.75
ug/kg
563-58-6
1, 1 -Dichloropropene
ND
3.7
0.76
ug/kg
10061-01-5
cis- 1, 3 -Dichloropropene
ND
3.7
0.75
ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS12 of 99
FA98838

SGS North America Inc.
Report of Analysis
Page 2 of 3
Client Sample ID:
Z1-1-1-1.5
Lab Sample ID:
FA98838-2 Date Sampled: 09/08/22
Matrix:
SO - Soil Date Received: 09/10/22
Method:
SW846 8260D Percent Solids: n/a a
Project:
PPD; Harnett St, Wilmington, NC
VOA List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
10061-02-6
trans- 1, 3-Dichloropropene
ND
3.7
0.75
ug/kg
108-20-3
Di -Isopropyl Ether
ND
3.7
1.7
ug/kg
64-17-5
Ethyl Alcohol d
ND
300
56
ug/kg
100-41-4
Ethylbenzene
ND
3.7
0.75
ug/kg
591-78-6
2-Hexanone c
ND
19
5.6
ug/kg
98-82-8
Isopropylbenzene
ND
3.7
0.75
ug/kg
99-87-6
p-Isopropyltoluene
ND
3.7
0.75
ug/kg
74-83-9
Methyl Bromide
ND
3.7
1.5
ug/kg
74-87-3
Methyl Chloride
ND
3.7
1.5
ug/kg
75-09-2
Methylene Chloride e
ND
15
8.2
ug/kg
108-10-1
4-Methyl-2-pentanone (MIBK) ND
19
5.6
ug/kg
1634-04-4
Methyl Tert Butyl Ether
ND
3.7
0.75
ug/kg
91-20-3
Naphthalene
ND
3.7
1.5
ug/kg
103-65-1
n-Propylbenzene
ND
3.7
0.75
ug/kg
100-42-5
Styrene
ND
3.7
0.75
ug/kg
630-20-6
1, 1, 1, 2-Tetrachloroethane
ND
3.7
0.77
ug/kg
79-34-5
1,1,2,2-Tetrachloroethane °
ND
3.7
0.75
ug/kg
127-18-4
Tetrachloroethylene
ND
3.7
0.96
ug/kg
108-88-3
Toluene
ND
15
7.5
ug/kg
87-61-6
1, 2,3 -Trichlorobenzene
ND
3.7
1.0
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
3.7
0.75
ug/kg
71-55-6
1, 1, 1 -Trichloroethane
ND
3.7
0.75
ug/kg
79-00-5
1,1,2-Trichloroethane
ND
3.7
0.75
ug/kg
79-01-6
Trichloroethylene
ND
3.7
0.75
ug/kg
75-69-4
Trichlorofluoromethane
ND
3.7
1.5
ug/kg
96-18-4
1, 2,3 -Trichloropropane
ND
3.7
0.94
ug/kg
95-63-6
1,2,4-Trimethylbenzene
ND
3.7
0.75
ug/kg
108-67-8
1,3,5-Trimethylbenzene
ND
3.7
0.75
ug/kg
108-05-4
Vinyl Acetate
ND
19
12
ug/kg
75-01-4
Vinyl Chloride
ND
3.7
0.75
ug/kg
m,p-Xylene
ND
7.5
0.82
ug/kg
95-47-6
o-Xylene
ND
3.7
0.75
ug/kg
1330-20-7
Xylene (total)
ND
11
1.6
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
1868-53-7
Dibromofluoromethane
93%
75-124%
17060-07-0
1,2-Dichloroethane-D4
124%
72-135%
2037-26-5
Toluene-D8
109%
75-126%
460-00-4
4-Bromofluorobenzene
107%
71-133%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS13 of 99
FA98838

SGS North America Inc.
Report of Analysis
Page 3 of 3 N
Client Sample ID:
Z1-1-1-1.5
Lab Sample ID:
FA98838-2 Date Sampled: 09/08/22
Matrix:
SO - Soil Date Received: 09/10/22
Method:
SW846 8260D Percent Solids: n/a a
Project:
PPD; Harnett St, Wilmington, NC
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(a) All results reported on a wet weight basis.
(b) Associated CCV and BS outside control limits low.
(c) Associated CCV outside control limits high, sample is ND.
(d) Associated CCV outside control limits low.
(e) Associated CCV and BS recovery outside control limits high, sample is ND.
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
SGS14 of 99
FA98838

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: Z1-0-0.5
Lab Sample ID: FA98838-3 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 94.2
Project: PPD; Harnett St, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 X083993.13 1 09/15/22 15:16 KA 09/14/22 07:30 OP93050 SX3330
Run #2
Initial Weight Final Volume
Run#1 30.2g 1.0ml
Run #2
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
65-85-0
Benzoic Acid
ND
880
180
ug/kg
59-50-7
4-Chloro-3-methyl Phenol
ND
180
20
ug/kg
95-57-8
2-Chlorophenol
ND
180
22
ug/kg
120-83-2
2,4-Dichlorophenol
ND
180
20
ug/kg
105-67-9
2,4-Dimethylphenol
ND
180
47
ug/kg
51-28-5
2,4-Dinitrophenol
ND
880
180
ug/kg
534-52-1
4,6-Dinitro-o-cresol
ND
350
70
ug/kg
95-48-7
2-Methylphenol
ND
180
21
ug/kg
3&4-Methylphenol
ND
180
29
ug/kg
88-75-5
2-Nitrophenol
ND
180
19
ug/kg
100-02-7
4-Nitrophenol
ND
880
180
ug/kg
87-86-5
Pentachlorophenol
ND
880
180
ug/kg
108-95-2
Phenol
ND
180
18
ug/kg
88-06-2
2,4,6-Trichlorophenol
ND
180
20
ug/kg
83-32-9
Acenaphthene
ND
180
19
ug/kg
208-96-8
Acenaphthylene
ND
180
18
ug/kg
120-12-7
Anthracene
22.2
180
20
ug/kg J
56-55-3
Benzo(a)anthracene
84.4
180
18
ug/kg J
50-32-8
Benzo(a)pyrene
74.3
180
21
ug/kg J
205-99-2
Benzo(b)fluoranthene
101
180
19
ug/kg J
191-24-2
Benzo(g, h, i)perylene
46.5
180
18
ug/kg J
207-08-9
Benzo(k)fluoranthene
50.4
180
23
ug/kg J
100-51-6
Benzyl Alcohol
ND
180
18
ug/kg
101-55-3
4-Bromophenyl phenyl ether
ND
180
18
ug/kg
85-68-7
Butyl benzyl phthalate a
ND
180
35
ug/kg
106-47-8
4-Chloroaniline
ND
180
44
ug/kg
111-91-1
bis(2-Chloroethoxy)methane
ND
180
18
ug/kg
111-44-4
bis(2-Chloroethyl)ether
ND
180
20
ug/kg
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
180
22
ug/kg
91-58-7
2-Chloronaphthalene
ND
180
18
ug/kg
7005-72-3
4-Chlorophenyl phenyl ether
ND
180
18
ug/kg
218-01-9
Chrysene
69.3
180
18
ug/kg J
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS15 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: Z1-0-0.5
Lab Sample ID: FA98838-3 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 94.2
Project: PPD; Harnett St, Wilmington, NC
ABN List for NC, May 2012
CAS No.
Compound
Result
RL
MDL Units Q
53-70-3
Dibenzo(a,h)anthracene
ND
180
22
ug/kg
132-64-9
Dibenzofaran
ND
180
18
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
180
18
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
180
19
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
180
23
ug/kg
91-94-1
3,3'-Dichlorobenzidine
ND
180
42
ug/kg
84-66-2
Diethyl Phthalate
ND
350
35
ug/kg
131-11-3
Dimethyl Phthalate
ND
180
35
ug/kg
117-84-0
Di-n-octyl Phthalate a
ND
180
35
ug/kg
84-74-2
Di-n-butyl Phthalate
ND
350
70
ug/kg
122-66-7
1,2-Diphenylhydrazine
ND
180
18
ug/kg
117-81-7
bis(2-Ethylhexyl)phthalate
ND
350
35
ug/kg
206-44-0
Fluoranthene
155
180
18
ug/kg J
86-73-7
Fluorene
ND
180
19
ug/kg
118-74-1
Hexachlorobenzene b
ND
180
18
ug/kg
87-68-3
Hexachlorobutadiene
ND
180
18
ug/kg
77-47-4
Hexachlorocyclopentadiene
ND
180
35
ug/kg
67-72-1
Hexachloroethane
ND
180
21
ug/kg
193-39-5
Indeno(1,2,3-cd)pyrene
ND
180
21
ug/kg
78-59-1
Isophorone
ND
180
18
ug/kg
90-12-0
1-Methylnaphthalene
ND
180
18
ug/kg
91-57-6
2-Methylnaphthalene
ND
180
18
ug/kg
91-20-3
Naphthalene
ND
180
18
ug/kg
98-95-3
Nitrobenzene
ND
180
18
ug/kg
621-64-7
N-Nitrosodi-n-propylamine
ND
180
18
ug/kg
86-30-6
N-Nitrosodiphenylamine
ND
180
19
ug/kg
85-01-8
Phenanthrene
66.5
180
18
ug/kg J
129-00-0
Pyrene
139
180
20
ug/kg J
120-82-1
1,2,4-Trichlorobenzene
ND
180
21
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
367-12-4
2-Fluorophenol
66%
40-102%
4165-62-2
Phenol-d5
69%
41-100%
118-79-6
2,4,6-Tribromophenol
55%
42-108%
4165-60-0
Nitrobenzene-d5
59%
40-105%
321-60-8
2-Fluorobiphenyl
65%
43-107%
1718-51-0
Terphenyl-dl4
82%
45-119%
(a) Associated BS and CCV outside of control limits high, sample was ND.
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS16 of 99
FA98838

SGS North America Inc.
Report of Analysis Page 3 of 3 w
Client Sample ID: Z1-0-0.5
Lab Sample ID: FA98838-3 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 94.2
Project: PPD; Harnett St, Wilmington, NC
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(b) Associated CCV outside of control limits low.
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
SGS17 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: Z1-0-0.5
Lab Sample ID: FA98838-3 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Percent Solids: 94.2
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 1 w
Metals Analysis
Analyte Result RL
Units
DF
Prep
Analyzed
By
Method
Prep Method
Arsenic 1.3 0.44
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Barium 11.3 8.7
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Cadmium < 0.17 0.17
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050E 4
Chromium 4.3 0.44
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Lead 32.6 0.87
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Mercury 0.065 0.043
mg/kg
1
09/15/22
09/15/22
.ic
SW846 7471E 1
SW846 7471B 3
Selenium < 0.87 0.87
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Silver < 0.44 0.44
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
(1) Instrument QC Batch: MA18914
(2) Instrument QC Batch: MA18920
(3) Prep QC Batch: MP41212
(4) Prep QC Batch: MP41216
RL = Reporting Limit
GS18 of 99
FA98838

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: Z1-0.5-2
Lab Sample ID: FA98838-4 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 94.3
Project: PPD; Harnett St, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 X083994.13 1 09/15/22 15:44 KA 09/14/22 07:30 OP93050 SX3330
Run #2
Initial Weight Final Volume
Run #1 30.3 g 1.0 ml
Run #2
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units
65-85-0
Benzoic Acid
ND
870
170
ug/kg
59-50-7
4-Chloro-3-methyl Phenol
ND
170
20
ug/kg
95-57-8
2-Chlorophenol
ND
170
21
ug/kg
120-83-2
2,4-Dichlorophenol
ND
170
20
ug/kg
105-67-9
2,4-Dimethylphenol
ND
170
47
ug/kg
51-28-5
2,4-Dinitrophenol
ND
870
170
ug/kg
534-52-1
4,6-Dinitro-o-cresol
ND
350
70
ug/kg
95-48-7
2-Methylphenol
ND
170
21
ug/kg
3&4-Methylphenol
ND
170
29
ug/kg
88-75-5
2-Nitrophenol
ND
170
19
ug/kg
100-02-7
4-Nitrophenol
ND
870
170
ug/kg
87-86-5
Pentachlorophenol
ND
870
170
ug/kg
108-95-2
Phenol
ND
170
17
ug/kg
88-06-2
2,4,6-Trichlorophenol
ND
170
20
ug/kg
83-32-9
Acenaphthene
ND
170
19
ug/kg
208-96-8
Acenaphthylene
ND
170
17
ug/kg
120-12-7
Anthracene
ND
170
20
ug/kg
56-55-3
Benzo(a)anthracene
19.0
170
17
ug/kg
50-32-8
Benzo(a)pyrene
ND
170
21
ug/kg
205-99-2
Benzo(b)fluoranthene
ND
170
19
ug/kg
191-24-2
Benzo(g, h, i)perylene
ND
170
18
ug/kg
207-08-9
Benzo(k)fluoranthene
ND
170
23
ug/kg
100-51-6
Benzyl Alcohol
ND
170
17
ug/kg
101-55-3
4-Bromophenyl phenyl ether
ND
170
18
ug/kg
85-68-7
Butyl benzyl phthalate a
ND
170
35
ug/kg
106-47-8
4-Chloroaniline
ND
170
44
ug/kg
111-91-1
bis(2-Chloroethoxy)methane
ND
170
17
ug/kg
111-44-4
bis(2-Chloroethyl)ether
ND
170
20
ug/kg
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
170
22
ug/kg
91-58-7
2-Chloronaphthalene
ND
170
17
ug/kg
7005-72-3
4-Chlorophenyl phenyl ether
ND
170
17
ug/kg
218-01-9
Chrysene
ND
170
18
ug/kg
01
J
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS19 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: Z1-0.5-2
Lab Sample ID: FA98838-4 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 94.3
Project: PPD; Harnett St, Wilmington, NC
ABN List for NC, May 2012
CAS No.
Compound
Result
RL
MDL Units Q
53-70-3
Dibenzo(a,h)anthracene
ND
170
22
ug/kg
132-64-9
Dibenzofaran
ND
170
17
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
170
17
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
170
19
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
170
23
ug/kg
91-94-1
3,3'-Dichlorobenzidine
ND
170
42
ug/kg
84-66-2
Diethyl Phthalate
ND
350
35
ug/kg
131-11-3
Dimethyl Phthalate
ND
170
35
ug/kg
117-84-0
Di-n-octyl Phthalate a
ND
170
35
ug/kg
84-74-2
Di-n-butyl Phthalate
ND
350
70
ug/kg
122-66-7
1,2-Diphenylhydrazine
ND
170
17
ug/kg
117-81-7
bis(2-Ethylhexyl)phthalate
ND
350
35
ug/kg
206-44-0
Fluoranthene
18.2
170
17
ug/kg J
86-73-7
Fluorene
ND
170
19
ug/kg
118-74-1
Hexachlorobenzene b
ND
170
18
ug/kg
87-68-3
Hexachlorobutadiene
ND
170
18
ug/kg
77-47-4
Hexachlorocyclopentadiene
ND
170
35
ug/kg
67-72-1
Hexachloroethane
ND
170
21
ug/kg
193-39-5
Indeno(1,2,3-cd)pyrene
ND
170
21
ug/kg
78-59-1
Isophorone
ND
170
17
ug/kg
90-12-0
1-Methylnaphthalene
ND
170
17
ug/kg
91-57-6
2-Methylnaphthalene
ND
170
17
ug/kg
91-20-3
Naphthalene
ND
170
17
ug/kg
98-95-3
Nitrobenzene
ND
170
17
ug/kg
621-64-7
N-Nitrosodi-n-propylamine
ND
170
17
ug/kg
86-30-6
N-Nitrosodiphenylamine
ND
170
19
ug/kg
85-01-8
Phenanthrene
ND
170
17
ug/kg
129-00-0
Pyrene
ND
170
20
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
170
21
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
367-12-4
2-Fluorophenol
74%
40-102%
4165-62-2
Phenol-d5
79%
41-100%
118-79-6
2,4,6-Tribromophenol
60%
42-108%
4165-60-0
Nitrobenzene-d5
65%
40-105%
321-60-8
2-Fluorobiphenyl
71%
43-107%
1718-51-0
Terphenyl-dl4
89%
45-119%
(a) Associated BS and CCV outside of control limits high, sample was ND.
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
GS20 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: Z1-0.5-2
Lab Sample ID: FA98838-4 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 94.3
Project: PPD; Harnett St, Wilmington, NC
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(b) Associated CCV outside of control limits low.
Page 3 of 3
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
aSGV 21 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: Z1-0.5-2
Lab Sample ID: FA98838-4 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Percent Solids: 94.3
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 1 P
Metals Analysis
Analyte Result RL
Units
DF
Prep
Analyzed
By
Method
Prep Method
Arsenic a < 2.1 2.1
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Barium a < 41 41
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Cadmium a < 0.83 0.83
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Chromium a 6.8 2.1
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Lead a 28.0 4.1
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Mercury 0.072 0.039
mg/kg
1
09/15/22
09/15/22
JC
SW846 7471B 1
SW846 7471B 3
Selenium a < 4.1 4.1
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Silver a < 2.1 2.1
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
(1) Instrument QC Batch: MA18914
(2) Instrument QC Batch: MA18920
(3) Prep QC Batch: MP41212
(4) Prep QC Batch: MP41216
(a) Sample dilution required due to difficult matrix.
RL = Reporting Limit
S.GV 22 of 99
FA98838

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: Z2-2-0-0.5
Lab Sample ID: FA98838-5 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8260D Percent Solids: n/a a
Project: PPD; Harnett St, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 170104659.1) 1 09/14/22 15:22 DB n/a n/a VF3752
Run #2
Initial Weight Final Volume
Run # 1 3.84 g 5.0 ml
Run #2
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
67-64-1
Acetone
ND
260
130
ug/kg
71-43-2
Benzene
5.5
6.5
1.6
ug/kg
108-86-1
Bromobenzene
ND
6.5
1.3
ug/kg
74-97-5
Bromochloromethane b
ND
6.5
1.9
ug/kg
75-27-4
Bromodichloromethane
ND
6.5
1.3
ug/kg
75-25-2
Bromoform
ND
6.5
1.3
ug/kg
78-93-3
2-Butanone (MEK)
12.7
33
9.5
ug/kg
104-51-8
n-Butylbenzene °
ND
6.5
1.3
ug/kg
135-98-8
sec-Butylbenzene
ND
6.5
1.3
ug/kg
98-06-6
tert-Butylbenzene
ND
6.5
1.3
ug/kg
56-23-5
Carbon Tetrachloride
ND
6.5
1.3
ug/kg
108-90-7
Chlorobenzene
ND
6.5
1.3
ug/kg
75-00-3
Chloroethane
ND
6.5
2.6
ug/kg
67-66-3
Chloroform
ND
6.5
1.7
ug/kg
95-49-8
o-Chlorotoluene
ND
6.5
1.3
ug/kg
106-43-4
p-Chlorotoluene
ND
6.5
1.3
ug/kg
124-48-1
Dibromochloromethane
ND
6.5
1.3
ug/kg
106-93-4
1,2-Dibromoethane
ND
6.5
1.3
ug/kg
75-71-8
Dichlorodifluoromethane
ND
6.5
2.6
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
6.5
1.3
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
6.5
1.3
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
6.5
1.5
ug/kg
75-34-3
1, 1 -Dichloroethane
ND
6.5
2.3
ug/kg
107-06-2
1,2-Dichloroethane
ND
6.5
1.3
ug/kg
75-35-4
1, 1 -Dichloroethylene
ND
6.5
1.3
ug/kg
156-59-2
cis-1,2-Dichloroethylene
ND
6.5
1.8
ug/kg
156-60-5
trans- 1, 2-Dichloroethylene
ND
6.5
1.3
ug/kg
78-87-5
1,2-Dichloropropane
ND
6.5
1.3
ug/kg
142-28-9
1,3-Dichloropropane
ND
6.5
1.3
ug/kg
594-20-7
2,2-Dichloropropane
ND
6.5
1.3
ug/kg
563-58-6
1, 1 -Dichloropropene
ND
6.5
1.3
ug/kg
10061-01-5
cis- 1, 3 -Dichloropropene
ND
6.5
1.3
ug/kg
J
J
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS23 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: Z2-2-0-0.5
Lab Sample ID: FA98838-5 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8260D Percent Solids: n/a a
Project: PPD; Harnett St, Wilmington, NC
VOA List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
10061-02-6
trans- 1, 3-Dichloropropene
ND
6.5
1.3
ug/kg
108-20-3
Di -Isopropyl Ether
ND
6.5
3.0
ug/kg
64-17-5
Ethyl Alcohol d
ND
520
98
ug/kg
100-41-4
Ethylbenzene
1.6
6.5
1.3
ug/kg J
591-78-6
2-Hexanone c
ND
33
9.8
ug/kg
98-82-8
Isopropylbenzene
ND
6.5
1.3
ug/kg
99-87-6
p-Isopropyltoluene
ND
6.5
1.3
ug/kg
74-83-9
Methyl Bromide
ND
6.5
2.6
ug/kg
74-87-3
Methyl Chloride
ND
6.5
2.6
ug/kg
75-09-2
Methylene Chloride e
ND
26
14
ug/kg
108-10-1
4-Methyl-2-pentanone (MIBK) ND
33
9.8
ug/kg
1634-04-4
Methyl Tert Butyl Ether
ND
6.5
1.3
ug/kg
91-20-3
Naphthalene
ND
6.5
2.6
ug/kg
103-65-1
n-Propylbenzene
ND
6.5
1.3
ug/kg
100-42-5
Styrene
ND
6.5
1.3
ug/kg
630-20-6
1, 1, 1, 2-Tetrachloroethane
ND
6.5
1.3
ug/kg
79-34-5
1,1,2,2-Tetrachloroethane °
ND
6.5
1.3
ug/kg
127-18-4
Tetrachloroethylene
ND
6.5
1.7
ug/kg
108-88-3
Toluene
ND
26
13
ug/kg
87-61-6
1, 2,3 -Trichlorobenzene
ND
6.5
1.8
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
6.5
1.3
ug/kg
71-55-6
1, 1, 1 -Trichloroethane
ND
6.5
1.3
ug/kg
79-00-5
1,1,2-Trichloroethane
ND
6.5
1.3
ug/kg
79-01-6
Trichloroethylene
ND
6.5
1.3
ug/kg
75-69-4
Trichlorofluoromethane
ND
6.5
2.6
ug/kg
96-18-4
1, 2,3 -Trichloropropane
ND
6.5
1.6
ug/kg
95-63-6
1,2,4-Trimethylbenzene
ND
6.5
1.3
ug/kg
108-67-8
1,3,5-Trimethylbenzene
ND
6.5
1.3
ug/kg
108-05-4
Vinyl Acetate
ND
33
21
ug/kg
75-01-4
Vinyl Chloride
ND
6.5
1.3
ug/kg
m,p-Xylene
ND
13
1.4
ug/kg
95-47-6
o-Xylene
ND
6.5
1.3
ug/kg
1330-20-7
Xylene (total)
ND
20
2.7
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
1868-53-7
Dibromofluoromethane
88%
75-124%
17060-07-0
1,2-Dichloroethane-D4
116%
72-135%
2037-26-5
Toluene-D8
113%
75-126%
460-00-4
4-Bromofluorobenzene
109%
71-133%
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS24 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: Z2-2-0-0.5
Lab Sample ID: FA98838-5 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8260D Percent Solids: n/a a
Project: PPD; Harnett St, Wilmington, NC
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(a) All results reported on a wet weight basis.
(b) Associated CCV and BS outside control limits low.
(c) Associated CCV outside control limits high, sample is ND.
(d) Associated CCV outside control limits low.
(e) Associated CCV and BS recovery outside control limits high, sample is ND.
Page 3 of 3 P
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
aSGV 25 of 99
FA98838

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:
Z2-3-1.5-2
Lab Sample ID:
FA98838-6 Date Sampled: 09/08/22
Matrix:
SO - Soil Date Received: 09/10/22
Method:
SW846 8260D Percent Solids: n/a a
Project:
PPD; Harnett St, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 170104660.1) 1 09/14/22 15:47 DB n/a n/a VF3752
Run #2
Initial Weight Final Volume
Run # 1 7.03 g 5.0 ml
Run #2
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
67-64-1
Acetone
ND
140
71
ug/kg
71-43-2
Benzene
ND
3.6
0.87
ug/kg
108-86-1
Bromobenzene
ND
3.6
0.71
ug/kg
74-97-5
Bromochloromethane b
ND
3.6
1.1
ug/kg
75-27-4
Bromodichloromethane
ND
3.6
0.71
ug/kg
75-25-2
Bromoform
ND
3.6
0.71
ug/kg
78-93-3
2-Butanone (MEK)
ND
18
5.2
ug/kg
104-51-8
n-Butylbenzene °
ND
3.6
0.71
ug/kg
135-98-8
sec-Butylbenzene
ND
3.6
0.71
ug/kg
98-06-6
tert-Butylbenzene
ND
3.6
0.71
ug/kg
56-23-5
Carbon Tetrachloride
ND
3.6
0.73
ug/kg
108-90-7
Chlorobenzene
ND
3.6
0.71
ug/kg
75-00-3
Chloroethane
ND
3.6
1.4
ug/kg
67-66-3
Chloroform
ND
3.6
0.95
ug/kg
95-49-8
o-Chlorotoluene
ND
3.6
0.71
ug/kg
106-43-4
p-Chlorotoluene
ND
3.6
0.71
ug/kg
124-48-1
Dibromochloromethane
ND
3.6
0.71
ug/kg
106-93-4
1,2-Dibromoethane
ND
3.6
0.71
ug/kg
75-71-8
Dichlorodifluoromethane
ND
3.6
1.4
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
3.6
0.71
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
3.6
0.71
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
3.6
0.82
ug/kg
75-34-3
1, 1 -Dichloroethane
ND
3.6
1.3
ug/kg
107-06-2
1,2-Dichloroethane
ND
3.6
0.71
ug/kg
75-35-4
1, 1 -Dichloroethylene
ND
3.6
0.71
ug/kg
156-59-2
cis-1,2-Dichloroethylene
ND
3.6
0.98
ug/kg
156-60-5
trans- 1, 2-Dichloroethylene
ND
3.6
0.71
ug/kg
78-87-5
1,2-Dichloropropane
ND
3.6
0.71
ug/kg
142-28-9
1,3-Dichloropropane
ND
3.6
0.71
ug/kg
594-20-7
2,2-Dichloropropane
ND
3.6
0.71
ug/kg
563-58-6
1, 1 -Dichloropropene
ND
3.6
0.73
ug/kg
10061-01-5
cis- 1, 3 -Dichloropropene
ND
3.6
0.71
ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
GS26 of 99
FA98838

SGS North America Inc.
Report of Analysis
Page 2 of 3
Client Sample ID:
Z2-3-1.5-2
Lab Sample ID:
FA98838-6 Date Sampled: 09/08/22
Matrix:
SO - Soil Date Received: 09/10/22
Method:
SW846 8260D Percent Solids: n/a a
Project:
PPD; Harnett St, Wilmington, NC
VOA List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
10061-02-6
trans- 1, 3-Dichloropropene
ND
3.6
0.71
ug/kg
108-20-3
Di -Isopropyl Ether
ND
3.6
1.7
ug/kg
64-17-5
Ethyl Alcohol d
ND
280
53
ug/kg
100-41-4
Ethylbenzene
ND
3.6
0.71
ug/kg
591-78-6
2-Hexanone c
ND
18
5.3
ug/kg
98-82-8
Isopropylbenzene
ND
3.6
0.71
ug/kg
99-87-6
p-Isopropyltoluene
ND
3.6
0.71
ug/kg
74-83-9
Methyl Bromide
ND
3.6
1.4
ug/kg
74-87-3
Methyl Chloride
ND
3.6
1.4
ug/kg
75-09-2
Methylene Chloride e
ND
14
7.8
ug/kg
108-10-1
4-Methyl-2-pentanone (MIBK) ND
18
5.3
ug/kg
1634-04-4
Methyl Tert Butyl Ether
ND
3.6
0.71
ug/kg
91-20-3
Naphthalene
ND
3.6
1.4
ug/kg
103-65-1
n-Propylbenzene
ND
3.6
0.71
ug/kg
100-42-5
Styrene
ND
3.6
0.71
ug/kg
630-20-6
1, 1, 1, 2-Tetrachloroethane
ND
3.6
0.73
ug/kg
79-34-5
1,1,2,2-Tetrachloroethane °
ND
3.6
0.71
ug/kg
127-18-4
Tetrachloroethylene
ND
3.6
0.91
ug/kg
108-88-3
Toluene
ND
14
7.1
ug/kg
87-61-6
1, 2,3 -Trichlorobenzene
ND
3.6
1.0
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
3.6
0.71
ug/kg
71-55-6
1, 1, 1 -Trichloroethane
ND
3.6
0.71
ug/kg
79-00-5
1,1,2-Trichloroethane
ND
3.6
0.71
ug/kg
79-01-6
Trichloroethylene
ND
3.6
0.71
ug/kg
75-69-4
Trichlorofluoromethane
ND
3.6
1.4
ug/kg
96-18-4
1, 2,3 -Trichloropropane
ND
3.6
0.89
ug/kg
95-63-6
1,2,4-Trimethylbenzene
ND
3.6
0.71
ug/kg
108-67-8
1,3,5-Trimethylbenzene
ND
3.6
0.71
ug/kg
108-05-4
Vinyl Acetate
ND
18
12
ug/kg
75-01-4
Vinyl Chloride
ND
3.6
0.71
ug/kg
m,p-Xylene
ND
7.1
0.78
ug/kg
95-47-6
o-Xylene
ND
3.6
0.71
ug/kg
1330-20-7
Xylene (total)
ND
11
1.5
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
1868-53-7
Dibromofluoromethane
88%
75-124%
17060-07-0
1,2-Dichloroethane-D4
122%
72-135%
2037-26-5
Toluene-D8
113%
75-126%
460-00-4
4-Bromofluorobenzene
107%
71-133%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
GS- 27 of 99
FA98838

SGS North America Inc.
Report of Analysis
Page 3 of 3
Client Sample ID:
Z2-3-1.5-2
Lab Sample ID:
FA98838-6 Date Sampled: 09/08/22
Matrix:
SO - Soil Date Received: 09/10/22
Method:
SW846 8260D Percent Solids: n/a a
Project:
PPD; Harnett St, Wilmington, NC
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(a) All results reported on a wet weight basis.
(b) Associated CCV and BS outside control limits low.
(c) Associated CCV outside control limits high, sample is ND.
(d) Associated CCV outside control limits low.
(e) Associated CCV and BS recovery outside control limits high, sample is ND.
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
SGS28 of 99
FA98838

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: Z2-0-0.5
Lab Sample ID: FA98838-7 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 91.9
Project: PPD; Harnett St, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 X083995.13 1 09/15/22 16:11 KA 09/14/22 07:30 OP93050 SX3330
Run #2
Initial Weight Final Volume
Run #1 30.1 g 1.0 ml
Run #2
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units
65-85-0
Benzoic Acid
ND
900
180
ug/kg
59-50-7
4-Chloro-3-methyl Phenol
ND
180
20
ug/kg
95-57-8
2-Chlorophenol
ND
180
22
ug/kg
120-83-2
2,4-Dichlorophenol
ND
180
21
ug/kg
105-67-9
2,4-Dimethylphenol
ND
180
48
ug/kg
51-28-5
2,4-Dinitrophenol
ND
900
180
ug/kg
534-52-1
4,6-Dinitro-o-cresol
ND
360
72
ug/kg
95-48-7
2-Methylphenol
ND
180
22
ug/kg
3&4-Methylphenol
ND
180
30
ug/kg
88-75-5
2-Nitrophenol
ND
180
20
ug/kg
100-02-7
4-Nitrophenol
ND
900
180
ug/kg
87-86-5
Pentachlorophenol
ND
900
180
ug/kg
108-95-2
Phenol
ND
180
18
ug/kg
88-06-2
2,4,6-Trichlorophenol
ND
180
21
ug/kg
83-32-9
Acenaphthene
ND
180
19
ug/kg
208-96-8
Acenaphthylene
ND
180
18
ug/kg
120-12-7
Anthracene
ND
180
20
ug/kg
56-55-3
Benzo(a)anthracene
ND
180
18
ug/kg
50-32-8
Benzo(a)pyrene
ND
180
21
ug/kg
205-99-2
Benzo(b)fluoranthene
ND
180
20
ug/kg
191-24-2
Benzo(g, h, i)perylene
ND
180
19
ug/kg
207-08-9
Benzo(k)fluoranthene
ND
180
24
ug/kg
100-51-6
Benzyl Alcohol
ND
180
18
ug/kg
101-55-3
4-Bromophenyl phenyl ether
ND
180
19
ug/kg
85-68-7
Butyl benzyl phthalate a
ND
180
36
ug/kg
106-47-8
4-Chloroaniline
ND
180
46
ug/kg
111-91-1
bis(2-Chloroethoxy)methane
ND
180
18
ug/kg
111-44-4
bis(2-Chloroethyl)ether
ND
180
21
ug/kg
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
180
23
ug/kg
91-58-7
2-Chloronaphthalene
ND
180
18
ug/kg
7005-72-3
4-Chlorophenyl phenyl ether
ND
180
18
ug/kg
218-01-9
Chrysene
ND
180
18
ug/kg
01
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
GS29 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: Z2-0-0.5
Lab Sample ID: FA98838-7 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 91.9
Project: PPD; Harnett St, Wilmington, NC
ABN List for NC, May 2012
CAS No.
Compound
Result
RL
MDL Units Q
53-70-3
Dibenzo(a,h)anthracene
ND
180
23
ug/kg
132-64-9
Dibenzofaran
ND
180
18
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
180
18
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
180
20
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
180
24
ug/kg
91-94-1
3,3'-Dichlorobenzidine
ND
180
43
ug/kg
84-66-2
Diethyl Phthalate
ND
360
36
ug/kg
131-11-3
Dimethyl Phthalate
ND
180
36
ug/kg
117-84-0
Di-n-octyl Phthalate a
ND
180
36
ug/kg
84-74-2
Di-n-butyl Phthalate
ND
360
72
ug/kg
122-66-7
1,2-Diphenylhydrazine
ND
180
18
ug/kg
117-81-7
bis(2-Ethylhexyl)phthalate
ND
360
36
ug/kg
206-44-0
Fluoranthene
ND
180
18
ug/kg
86-73-7
Fluorene
ND
180
19
ug/kg
118-74-1
Hexachlorobenzene b
ND
180
18
ug/kg
87-68-3
Hexachlorobutadiene
ND
180
18
ug/kg
77-47-4
Hexachlorocyclopentadiene
ND
180
36
ug/kg
67-72-1
Hexachloroethane
ND
180
21
ug/kg
193-39-5
Indeno(1,2,3-cd)pyrene
ND
180
22
ug/kg
78-59-1
Isophorone
ND
180
18
ug/kg
90-12-0
1-Methylnaphthalene
ND
180
18
ug/kg
91-57-6
2-Methylnaphthalene
ND
180
18
ug/kg
91-20-3
Naphthalene
ND
180
18
ug/kg
98-95-3
Nitrobenzene
ND
180
18
ug/kg
621-64-7
N-Nitrosodi-n-propylamine
ND
180
18
ug/kg
86-30-6
N-Nitrosodiphenylamine
ND
180
19
ug/kg
85-01-8
Phenanthrene
ND
180
18
ug/kg
129-00-0
Pyrene
ND
180
21
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
180
21
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
367-12-4
2-Fluorophenol
68%
40-102%
4165-62-2
Phenol-d5
69%
41-100%
118-79-6
2,4,6-Tribromophenol
59%
42-108%
4165-60-0
Nitrobenzene-d5
59%
40-105%
321-60-8
2-Fluorobiphenyl
67%
43-107%
1718-51-0
Terphenyl-dl4
86%
45-119%
(a) Associated BS and CCV outside of control limits high, sample was ND.
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS30 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: Z2-0-0.5
Lab Sample ID: FA98838-7 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 91.9
Project: PPD; Harnett St, Wilmington, NC
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(b) Associated CCV outside of control limits low.
Page 3 of 3 y
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
aSGV 31 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: Z2-0-0.5
Lab Sample ID: FA98838-7 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Percent Solids: 91.9
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 1 y
Metals Analysis
Analyte Result RL
Units
DF
Prep
Analyzed
By
Method
Prep Method
Arsenic a 4.5 2.2
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Barium a < 44 44
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Cadmium a < 0.87 0.87
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Chromium a 13.1 2.2
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Lead a 17.5 4.4
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Mercury < 0.039 0.039
mg/kg
1
09/15/22
09/15/22
JC
SW846 7471B 1
SW846 7471B 3
Selenium a < 4.4 4.4
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Silver a < 2.2 2.2
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
(1) Instrument QC Batch: MA18914
(2) Instrument QC Batch: MA18920
(3) Prep QC Batch: MP41212
(4) Prep QC Batch: MP41216
(a) Sample dilution required due to difficult matrix.
RL = Reporting Limit
SGV 32 of 99
FA98838

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: Z2-0.5-2
Lab Sample ID: FA98838-8 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 93.3
Project: PPD; Harnett St, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 X083996.13 1 09/15/22 16:38 KA 09/14/22 07:30 OP93050 SX3330
Run #2
Initial Weight Final Volume
Run#1 30.0g 1.0ml
Run #2
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units
65-85-0
Benzoic Acid
ND
890
180
ug/kg
59-50-7
4-Chloro-3-methyl Phenol
ND
180
20
ug/kg
95-57-8
2-Chlorophenol
ND
180
22
ug/kg
120-83-2
2,4-Dichlorophenol
ND
180
21
ug/kg
105-67-9
2,4-Dimethylphenol
ND
180
48
ug/kg
51-28-5
2,4-Dinitrophenol
ND
890
180
ug/kg
534-52-1
4,6-Dinitro-o-cresol
ND
360
71
ug/kg
95-48-7
2-Methylphenol
ND
180
22
ug/kg
3&4-Methylphenol
ND
180
29
ug/kg
88-75-5
2-Nitrophenol
ND
180
19
ug/kg
100-02-7
4-Nitrophenol
ND
890
180
ug/kg
87-86-5
Pentachlorophenol
ND
890
180
ug/kg
108-95-2
Phenol
ND
180
18
ug/kg
88-06-2
2,4,6-Trichlorophenol
ND
180
21
ug/kg
83-32-9
Acenaphthene
ND
180
19
ug/kg
208-96-8
Acenaphthylene
ND
180
18
ug/kg
120-12-7
Anthracene
ND
180
20
ug/kg
56-55-3
Benzo(a)anthracene
ND
180
18
ug/kg
50-32-8
Benzo(a)pyrene
ND
180
21
ug/kg
205-99-2
Benzo(b)fluoranthene
ND
180
20
ug/kg
191-24-2
Benzo(g, h, i)perylene
ND
180
19
ug/kg
207-08-9
Benzo(k)fluoranthene
ND
180
23
ug/kg
100-51-6
Benzyl Alcohol
ND
180
18
ug/kg
101-55-3
4-Bromophenyl phenyl ether
ND
180
19
ug/kg
85-68-7
Butyl benzyl phthalate a
ND
180
36
ug/kg
106-47-8
4-Chloroaniline
ND
180
45
ug/kg
111-91-1
bis(2-Chloroethoxy)methane
ND
180
18
ug/kg
111-44-4
bis(2-Chloroethyl)ether
ND
180
21
ug/kg
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
180
22
ug/kg
91-58-7
2-Chloronaphthalene
ND
180
18
ug/kg
7005-72-3
4-Chlorophenyl phenyl ether
ND
180
18
ug/kg
218-01-9
Chrysene
ND
180
18
ug/kg
01
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
w
i"
SGS33 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: Z2-0.5-2
Lab Sample ID: FA98838-8 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 93.3
Project: PPD; Harnett St, Wilmington, NC
ABN List for NC, May 2012
CAS No.
Compound
Result
RL
MDL Units Q
53-70-3
Dibenzo(a,h)anthracene
ND
180
22
ug/kg
132-64-9
Dibenzofaran
ND
180
18
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
180
18
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
180
19
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
180
24
ug/kg
91-94-1
3,3'-Dichlorobenzidine
ND
180
43
ug/kg
84-66-2
Diethyl Phthalate
ND
360
36
ug/kg
131-11-3
Dimethyl Phthalate
ND
180
36
ug/kg
117-84-0
Di-n-octyl Phthalate a
ND
180
36
ug/kg
84-74-2
Di-n-butyl Phthalate
ND
360
71
ug/kg
122-66-7
1,2-Diphenylhydrazine
ND
180
18
ug/kg
117-81-7
bis(2-Ethylhexyl)phthalate
ND
360
36
ug/kg
206-44-0
Fluoranthene
ND
180
18
ug/kg
86-73-7
Fluorene
ND
180
19
ug/kg
118-74-1
Hexachlorobenzene b
ND
180
18
ug/kg
87-68-3
Hexachlorobutadiene
ND
180
18
ug/kg
77-47-4
Hexachlorocyclopentadiene
ND
180
36
ug/kg
67-72-1
Hexachloroethane
ND
180
21
ug/kg
193-39-5
Indeno(1,2,3-cd)pyrene
ND
180
22
ug/kg
78-59-1
Isophorone
ND
180
18
ug/kg
90-12-0
1-Methylnaphthalene
ND
180
18
ug/kg
91-57-6
2-Methylnaphthalene
ND
180
18
ug/kg
91-20-3
Naphthalene
ND
180
18
ug/kg
98-95-3
Nitrobenzene
ND
180
18
ug/kg
621-64-7
N-Nitrosodi-n-propylamine
ND
180
18
ug/kg
86-30-6
N-Nitrosodiphenylamine
ND
180
19
ug/kg
85-01-8
Phenanthrene
ND
180
18
ug/kg
129-00-0
Pyrene
ND
180
21
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
180
21
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
367-12-4
2-Fluorophenol
65%
40-102%
4165-62-2
Phenol-d5
68%
41-100%
118-79-6
2,4,6-Tribromophenol
54%
42-108%
4165-60-0
Nitrobenzene-d5
58%
40-105%
321-60-8
2-Fluorobiphenyl
63%
43-107%
1718-51-0
Terphenyl-dl4
81%
45-119%
(a) Associated BS and CCV outside of control limits high, sample was ND.
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
w
00
SGS34 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: Z2-0.5-2
Lab Sample ID: FA98838-8 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 93.3
Project: PPD; Harnett St, Wilmington, NC
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(b) Associated CCV outside of control limits low.
Page 3 of 3 w
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
aSGV 35 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: Z2-0.5-2
Lab Sample ID: FA98838-8 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Percent Solids: 93.3
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 1 w
Metals Analysis
Analyte Result RL
Units
DF
Prep
Analyzed
By
Method
Prep Method
Arsenic a < 2.2 2.2
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Barium a < 43 43
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Cadmium a < 0.86 0.86
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Chromium a 7.0 2.2
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Lead a 180 4.3
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Mercury 0.075 0.039
mg/kg
1
09/15/22
09/15/22
JC
SW846 7471B 1
SW846 7471B 3
Selenium a < 4.3 4.3
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Silver a < 2.2 2.2
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
(1) Instrument QC Batch: MA18914
(2) Instrument QC Batch: MA18920
(3) Prep QC Batch: MP41212
(4) Prep QC Batch: MP41216
(a) Sample dilution required due to difficult matrix.
RL = Reporting Limit
SGV 36 of 99
FA98838

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:
Z3-3-0-0.5
Lab Sample ID:
FA98838-9 Date Sampled: 09/08/22
Matrix:
SO - Soil Date Received: 09/10/22
Method:
SW846 8260D Percent Solids: n/a a
Project:
PPD; Harnett St, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 170104661.1) 1 09/14/22 16:11 DB n/a n/a VF3752
Run #2
Initial Weight Final Volume
Run #1 7.20 g 5.0 ml
Run #2
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
67-64-1
Acetone
ND
140
69
ug/kg
71-43-2
Benzene
ND
3.5
0.85
ug/kg
108-86-1
Bromobenzene
ND
3.5
0.69
ug/kg
74-97-5
Bromochloromethane b
ND
3.5
1.0
ug/kg
75-27-4
Bromodichloromethane
ND
3.5
0.69
ug/kg
75-25-2
Bromoform
ND
3.5
0.69
ug/kg
78-93-3
2-Butanone (MEK)
ND
17
5.0
ug/kg
104-51-8
n-Butylbenzene °
ND
3.5
0.69
ug/kg
135-98-8
sec-Butylbenzene
ND
3.5
0.69
ug/kg
98-06-6
tert-Butylbenzene
ND
3.5
0.69
ug/kg
56-23-5
Carbon Tetrachloride
ND
3.5
0.71
ug/kg
108-90-7
Chlorobenzene
ND
3.5
0.69
ug/kg
75-00-3
Chloroethane
ND
3.5
1.4
ug/kg
67-66-3
Chloroform
ND
3.5
0.92
ug/kg
95-49-8
o-Chlorotoluene
ND
3.5
0.69
ug/kg
106-43-4
p-Chlorotoluene
ND
3.5
0.69
ug/kg
124-48-1
Dibromochloromethane
ND
3.5
0.69
ug/kg
106-93-4
1,2-Dibromoethane
ND
3.5
0.69
ug/kg
75-71-8
Dichlorodifluoromethane
ND
3.5
1.4
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
3.5
0.69
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
3.5
0.69
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
3.5
0.80
ug/kg
75-34-3
1, 1 -Dichloroethane
ND
3.5
1.2
ug/kg
107-06-2
1,2-Dichloroethane
ND
3.5
0.69
ug/kg
75-35-4
1, 1 -Dichloroethylene
ND
3.5
0.69
ug/kg
156-59-2
cis-1,2-Dichloroethylene
ND
3.5
0.96
ug/kg
156-60-5
trans- 1, 2-Dichloroethylene
ND
3.5
0.69
ug/kg
78-87-5
1,2-Dichloropropane
ND
3.5
0.69
ug/kg
142-28-9
1,3-Dichloropropane
ND
3.5
0.69
ug/kg
594-20-7
2,2-Dichloropropane
ND
3.5
0.69
ug/kg
563-58-6
1, 1 -Dichloropropene
ND
3.5
0.71
ug/kg
10061-01-5
cis- 1, 3 -Dichloropropene
ND
3.5
0.69
ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
GS- 37 of 99
FA98838

SGS North America Inc.
Report of Analysis
Page 2 of 3
Client Sample ID:
Z3-3-0-0.5
Lab Sample ID:
FA98838-9 Date Sampled: 09/08/22
Matrix:
SO - Soil Date Received: 09/10/22
Method:
SW846 8260D Percent Solids: n/a a
Project:
PPD; Harnett St, Wilmington, NC
VOA List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
10061-02-6
trans- 1, 3-Dichloropropene
ND
3.5
0.69
ug/kg
108-20-3
Di -Isopropyl Ether
ND
3.5
1.6
ug/kg
64-17-5
Ethyl Alcohol d
ND
280
52
ug/kg
100-41-4
Ethylbenzene
ND
3.5
0.69
ug/kg
591-78-6
2-Hexanone c
ND
17
5.2
ug/kg
98-82-8
Isopropylbenzene
ND
3.5
0.69
ug/kg
99-87-6
p-Isopropyltoluene
ND
3.5
0.69
ug/kg
74-83-9
Methyl Bromide
ND
3.5
1.4
ug/kg
74-87-3
Methyl Chloride
ND
3.5
1.4
ug/kg
75-09-2
Methylene Chloride e
ND
14
7.6
ug/kg
108-10-1
4-Methyl-2-pentanone (MIBK) ND
17
5.2
ug/kg
1634-04-4
Methyl Tert Butyl Ether
ND
3.5
0.69
ug/kg
91-20-3
Naphthalene
ND
3.5
1.4
ug/kg
103-65-1
n-Propylbenzene
ND
3.5
0.69
ug/kg
100-42-5
Styrene
ND
3.5
0.69
ug/kg
630-20-6
1, 1, 1, 2-Tetrachloroethane
ND
3.5
0.72
ug/kg
79-34-5
1,1,2,2-Tetrachloroethane °
ND
3.5
0.69
ug/kg
127-18-4
Tetrachloroethylene
ND
3.5
0.89
ug/kg
108-88-3
Toluene
ND
14
6.9
ug/kg
87-61-6
1, 2,3 -Trichlorobenzene
ND
3.5
0.97
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
3.5
0.69
ug/kg
71-55-6
1, 1, 1 -Trichloroethane
ND
3.5
0.69
ug/kg
79-00-5
1,1,2-Trichloroethane
ND
3.5
0.69
ug/kg
79-01-6
Trichloroethylene
ND
3.5
0.69
ug/kg
75-69-4
Trichlorofluoromethane
ND
3.5
1.4
ug/kg
96-18-4
1, 2,3 -Trichloropropane
ND
3.5
0.87
ug/kg
95-63-6
1,2,4-Trimethylbenzene
ND
3.5
0.69
ug/kg
108-67-8
1,3,5-Trimethylbenzene
ND
3.5
0.69
ug/kg
108-05-4
Vinyl Acetate
ND
17
11
ug/kg
75-01-4
Vinyl Chloride
ND
3.5
0.69
ug/kg
m,p-Xylene
ND
6.9
0.76
ug/kg
95-47-6
o-Xylene
ND
3.5
0.69
ug/kg
1330-20-7
Xylene (total)
ND
10
1.5
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
1868-53-7
Dibromofluoromethane
90%
75-124%
17060-07-0
1,2-Dichloroethane-D4
123%
72-135%
2037-26-5
Toluene-D8
112%
75-126%
460-00-4
4-Bromofluorobenzene
104%
71-133%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
GS- 38 of 99
FA98838

SGS North America Inc.
Report of Analysis
to
Page 3 of 3 P
Client Sample ID:
Z3-3-0-0.5
Lab Sample ID:
FA98838-9 Date Sampled: 09/08/22
Matrix:
SO - Soil Date Received: 09/10/22
Method:
SW846 8260D Percent Solids: n/a a
Project:
PPD; Harnett St, Wilmington, NC
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(a) All results reported on a wet weight basis.
(b) Associated CCV and BS outside control limits low.
(c) Associated CCV outside control limits high, sample is ND.
(d) Associated CCV outside control limits low.
(e) Associated CCV and BS recovery outside control limits high, sample is ND.
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
SGV 39 of 99
FA98838

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: Z3-3-1.5-2
Lab Sample ID: FA98838-10 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8260D Percent Solids: n/a a
Project: PPD; Harnett St, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 170104662.1) 1 09/14/22 16:35 DB n/a n/a VF3752
Run #2
Initial Weight Final Volume
Run#1 6.59g 5.0ml
Run #2
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
67-64-1
Acetone
ND
150
76
ug/kg
71-43-2
Benzene
ND
3.8
0.93
ug/kg
108-86-1
Bromobenzene
ND
3.8
0.76
ug/kg
74-97-5
Bromochloromethane b
ND
3.8
1.1
ug/kg
75-27-4
Bromodichloromethane
ND
3.8
0.76
ug/kg
75-25-2
Bromoform
ND
3.8
0.76
ug/kg
78-93-3
2-Butanone (MEK)
ND
19
5.5
ug/kg
104-51-8
n-Butylbenzene °
ND
3.8
0.76
ug/kg
135-98-8
sec-Butylbenzene
ND
3.8
0.76
ug/kg
98-06-6
tert-Butylbenzene
ND
3.8
0.76
ug/kg
56-23-5
Carbon Tetrachloride
ND
3.8
0.77
ug/kg
108-90-7
Chlorobenzene
ND
3.8
0.76
ug/kg
75-00-3
Chloroethane
ND
3.8
1.5
ug/kg
67-66-3
Chloroform
ND
3.8
1.0
ug/kg
95-49-8
o-Chlorotoluene
ND
3.8
0.76
ug/kg
106-43-4
p-Chlorotoluene
ND
3.8
0.76
ug/kg
124-48-1
Dibromochloromethane
ND
3.8
0.76
ug/kg
106-93-4
1,2-Dibromoethane
ND
3.8
0.76
ug/kg
75-71-8
Dichlorodifluoromethane
ND
3.8
1.5
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
3.8
0.76
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
3.8
0.76
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
3.8
0.87
ug/kg
75-34-3
1, 1 -Dichloroethane
ND
3.8
1.3
ug/kg
107-06-2
1,2-Dichloroethane
ND
3.8
0.76
ug/kg
75-35-4
1, 1 -Dichloroethylene
ND
3.8
0.76
ug/kg
156-59-2
cis-1,2-Dichloroethylene
ND
3.8
1.0
ug/kg
156-60-5
trans- 1, 2-Dichloroethylene
ND
3.8
0.76
ug/kg
78-87-5
1,2-Dichloropropane
ND
3.8
0.76
ug/kg
142-28-9
1,3-Dichloropropane
ND
3.8
0.76
ug/kg
594-20-7
2,2-Dichloropropane
ND
3.8
0.76
ug/kg
563-58-6
1, 1 -Dichloropropene
ND
3.8
0.77
ug/kg
10061-01-5
cis- 1, 3 -Dichloropropene
ND
3.8
0.76
ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS40 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: Z3-3-1.5-2
Lab Sample ID: FA98838-10 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8260D Percent Solids: n/a a
Project: PPD; Harnett St, Wilmington, NC
VOA List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
10061-02-6
trans- 1, 3-Dichloropropene
ND
3.8
0.76
ug/kg
108-20-3
Di -Isopropyl Ether
ND
3.8
1.8
ug/kg
64-17-5
Ethyl Alcohol d
ND
300
57
ug/kg
100-41-4
Ethylbenzene
ND
3.8
0.76
ug/kg
591-78-6
2-Hexanone c
ND
19
5.7
ug/kg
98-82-8
Isopropylbenzene
ND
3.8
0.76
ug/kg
99-87-6
p-Isopropyltoluene
ND
3.8
0.76
ug/kg
74-83-9
Methyl Bromide
ND
3.8
1.5
ug/kg
74-87-3
Methyl Chloride
ND
3.8
1.5
ug/kg
75-09-2
Methylene Chloride e
ND
15
8.3
ug/kg
108-10-1
4-Methyl-2-pentanone (MIBK) ND
19
5.7
ug/kg
1634-04-4
Methyl Tert Butyl Ether
ND
3.8
0.76
ug/kg
91-20-3
Naphthalene
ND
3.8
1.5
ug/kg
103-65-1
n-Propylbenzene
ND
3.8
0.76
ug/kg
100-42-5
Styrene
ND
3.8
0.76
ug/kg
630-20-6
1, 1, 1, 2-Tetrachloroethane
ND
3.8
0.78
ug/kg
79-34-5
1,1,2,2-Tetrachloroethane °
ND
3.8
0.76
ug/kg
127-18-4
Tetrachloroethylene
ND
3.8
0.97
ug/kg
108-88-3
Toluene
ND
15
7.6
ug/kg
87-61-6
1, 2,3 -Trichlorobenzene
ND
3.8
1.1
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
3.8
0.76
ug/kg
71-55-6
1, 1, 1 -Trichloroethane
ND
3.8
0.76
ug/kg
79-00-5
1,1,2-Trichloroethane
ND
3.8
0.76
ug/kg
79-01-6
Trichloroethylene
ND
3.8
0.76
ug/kg
75-69-4
Trichlorofluoromethane
ND
3.8
1.5
ug/kg
96-18-4
1, 2,3 -Trichloropropane
ND
3.8
0.95
ug/kg
95-63-6
1,2,4-Trimethylbenzene
ND
3.8
0.76
ug/kg
108-67-8
1,3,5-Trimethylbenzene
ND
3.8
0.76
ug/kg
108-05-4
Vinyl Acetate
ND
19
12
ug/kg
75-01-4
Vinyl Chloride
ND
3.8
0.76
ug/kg
m,p-Xylene
ND
7.6
0.83
ug/kg
95-47-6
o-Xylene
ND
3.8
0.76
ug/kg
1330-20-7
Xylene (total)
ND
11
1.6
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
1868-53-7
Dibromofluoromethane
90%
75-124%
17060-07-0
1,2-Dichloroethane-D4
121%
72-135%
2037-26-5
Toluene-D8
112%
75-126%
460-00-4
4-Bromofluorobenzene
107%
71-133%
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
GS41 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: Z3-3-1.5-2
Lab Sample ID: FA98838-10 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8260D Percent Solids: n/a a
Project: PPD; Harnett St, Wilmington, NC
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(a) All results reported on a wet weight basis.
(b) Associated CCV and BS outside control limits low.
(c) Associated CCV outside control limits high, sample is ND.
(d) Associated CCV outside control limits low.
(e) Associated CCV and BS recovery outside control limits high, sample is ND.
Page 3 of 3
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
SGS42 of 99
FA98838

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: Z3-0-0.5
Lab Sample ID: FA98838-11 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 94.5
Project: PPD; Harnett St, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 X083997.13 1 09/15/22 17:06 KA 09/14/22 07:30 OP93050 SX3330
Run #2
Initial Weight Final Volume
Run#1 30.0g 1.0ml
Run #2
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
65-85-0
Benzoic Acid
ND
880
180
ug/kg
59-50-7
4-Chloro-3-methyl Phenol
ND
180
20
ug/kg
95-57-8
2-Chlorophenol
ND
180
22
ug/kg
120-83-2
2,4-Dichlorophenol
ND
180
20
ug/kg
105-67-9
2,4-Dimethylphenol
ND
180
47
ug/kg
51-28-5
2,4-Dinitrophenol
ND
880
180
ug/kg
534-52-1
4,6-Dinitro-o-cresol
ND
350
71
ug/kg
95-48-7
2-Methylphenol
ND
180
21
ug/kg
3&4-Methylphenol
ND
180
29
ug/kg
88-75-5
2-Nitrophenol
ND
180
19
ug/kg
100-02-7
4-Nitrophenol
ND
880
180
ug/kg
87-86-5
Pentachlorophenol
ND
880
180
ug/kg
108-95-2
Phenol
ND
180
18
ug/kg
88-06-2
2,4,6-Trichlorophenol
ND
180
20
ug/kg
83-32-9
Acenaphthene
ND
180
19
ug/kg
208-96-8
Acenaphthylene
ND
180
18
ug/kg
120-12-7
Anthracene
ND
180
20
ug/kg
56-55-3
Benzo(a)anthracene
30.2
180
18
ug/kg J
50-32-8
Benzo(a)pyrene
37.2
180
21
ug/kg J
205-99-2
Benzo(b)fluoranthene
51.0
180
19
ug/kg J
191-24-2
Benzo(g, h, i)perylene
25.4
180
18
ug/kg J
207-08-9
Benzo(k)fluoranthene
ND
180
23
ug/kg
100-51-6
Benzyl Alcohol
ND
180
18
ug/kg
101-55-3
4-Bromophenyl phenyl ether
ND
180
18
ug/kg
85-68-7
Butyl benzyl phthalate a
ND
180
35
ug/kg
106-47-8
4-Chloroaniline
ND
180
44
ug/kg
111-91-1
bis(2-Chloroethoxy)methane
ND
180
18
ug/kg
111-44-4
bis(2-Chloroethyl)ether
ND
180
20
ug/kg
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
180
22
ug/kg
91-58-7
2-Chloronaphthalene
ND
180
18
ug/kg
7005-72-3
4-Chlorophenyl phenyl ether
ND
180
18
ug/kg
218-01-9
Chrysene
24.7
180
18
ug/kg J
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS43 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: Z3-0-0.5
Lab Sample ID: FA98838-11 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 94.5
Project: PPD; Harnett St, Wilmington, NC
ABN List for NC, May 2012
CAS No.
Compound
Result
RL
MDL Units Q
53-70-3
Dibenzo(a,h)anthracene
ND
180
22
ug/kg
132-64-9
Dibenzofaran
ND
180
18
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
180
18
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
180
19
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
180
23
ug/kg
91-94-1
3,3'-Dichlorobenzidine
ND
180
42
ug/kg
84-66-2
Diethyl Phthalate
ND
350
35
ug/kg
131-11-3
Dimethyl Phthalate
ND
180
35
ug/kg
117-84-0
Di-n-octyl Phthalate a
ND
180
35
ug/kg
84-74-2
Di-n-butyl Phthalate
ND
350
71
ug/kg
122-66-7
1,2-Diphenylhydrazine
ND
180
18
ug/kg
117-81-7
bis(2-Ethylhexyl)phthalate
ND
350
35
ug/kg
206-44-0
Fluoranthene
48.0
180
18
ug/kg J
86-73-7
Fluorene
ND
180
19
ug/kg
118-74-1
Hexachlorobenzene b
ND
180
18
ug/kg
87-68-3
Hexachlorobutadiene
ND
180
18
ug/kg
77-47-4
Hexachlorocyclopentadiene
ND
180
35
ug/kg
67-72-1
Hexachloroethane
ND
180
21
ug/kg
193-39-5
Indeno(1,2,3-cd)pyrene
72.1
180
21
ug/kg J
78-59-1
Isophorone
ND
180
18
ug/kg
90-12-0
1-Methylnaphthalene
ND
180
18
ug/kg
91-57-6
2-Methylnaphthalene
ND
180
18
ug/kg
91-20-3
Naphthalene
ND
180
18
ug/kg
98-95-3
Nitrobenzene
ND
180
18
ug/kg
621-64-7
N-Nitrosodi-n-propylamine
ND
180
18
ug/kg
86-30-6
N-Nitrosodiphenylamine
ND
180
19
ug/kg
85-01-8
Phenanthrene
20.4
180
18
ug/kg J
129-00-0
Pyrene
47.0
180
20
ug/kg J
120-82-1
1,2,4-Trichlorobenzene
ND
180
21
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
367-12-4
2-Fluorophenol
66%
40-102%
4165-62-2
Phenol-d5
67%
41-100%
118-79-6
2,4,6-Tribromophenol
57%
42-108%
4165-60-0
Nitrobenzene-d5
57%
40-105%
321-60-8
2-Fluorobiphenyl
65%
43-107%
1718-51-0
Terphenyl-dl4
82%
45-119%
(a) Associated BS and CCV outside of control limits high, sample was ND.
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS44 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: Z3-0-0.5
Lab Sample ID: FA98838-11 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 94.5
Project: PPD; Harnett St, Wilmington, NC
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(b) Associated CCV outside of control limits low.
Page 3 of 3
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
SGS45 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: Z3-0-0.5
Lab Sample ID: FA98838-11 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Percent Solids: 94.5
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 1
Metals Analysis
Analyte Result RL
Units
DF
Prep
Analyzed
By
Method
Prep Method
Arsenic 1.2 0.46
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Barium < 9.2 9.2
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050E 4
Cadmium < 0.18 0.18
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050E 4
Chromium 4.5 0.46
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Lead 24.5 0.92
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Mercury 0.062 0.042
mg/kg
1
09/15/22
09/15/22
JC
SW846 7471B 1
SW846 7471B 3
Selenium < 0.92 0.92
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Silver < 0.46 0.46
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
(1) Instrument QC Batch: MA18914
(2) Instrument QC Batch: MA18920
(3) Prep QC Batch: MP41212
(4) Prep QC Batch: MP41216
RL = Reporting Limit
SGS46 of 99
FA98838

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: Z3-0.5-2
Lab Sample ID: FA98838-12 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 95.6
Project: PPD; Harnett St, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 X083998.13 1 09/15/22 17:33 KA 09/14/22 07:30 OP93050 SX3330
Run #2
Initial Weight Final Volume
Run#1 30.0g 1.0ml
Run #2
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units
65-85-0
Benzoic Acid
ND
870
170
ug/kg
59-50-7
4-Chloro-3-methyl Phenol
ND
170
20
ug/kg
95-57-8
2-Chlorophenol
ND
170
21
ug/kg
120-83-2
2,4-Dichlorophenol
ND
170
20
ug/kg
105-67-9
2,4-Dimethylphenol
ND
170
46
ug/kg
51-28-5
2,4-Dinitrophenol
ND
870
170
ug/kg
534-52-1
4,6-Dinitro-o-cresol
ND
350
70
ug/kg
95-48-7
2-Methylphenol
ND
170
21
ug/kg
3&4-Methylphenol
ND
170
29
ug/kg
88-75-5
2-Nitrophenol
ND
170
19
ug/kg
100-02-7
4-Nitrophenol
ND
870
170
ug/kg
87-86-5
Pentachlorophenol
ND
870
170
ug/kg
108-95-2
Phenol
ND
170
17
ug/kg
88-06-2
2,4,6-Trichlorophenol
ND
170
20
ug/kg
83-32-9
Acenaphthene
ND
170
19
ug/kg
208-96-8
Acenaphthylene
ND
170
17
ug/kg
120-12-7
Anthracene
ND
170
20
ug/kg
56-55-3
Benzo(a)anthracene
20.1
170
17
ug/kg
50-32-8
Benzo(a)pyrene
ND
170
21
ug/kg
205-99-2
Benzo(b)fluoranthene
22.9
170
19
ug/kg
191-24-2
Benzo(g, h, i)perylene
ND
170
18
ug/kg
207-08-9
Benzo(k)fluoranthene
ND
170
23
ug/kg
100-51-6
Benzyl Alcohol
ND
170
17
ug/kg
101-55-3
4-Bromophenyl phenyl ether
ND
170
18
ug/kg
85-68-7
Butyl benzyl phthalate a
ND
170
35
ug/kg
106-47-8
4-Chloroaniline
ND
170
44
ug/kg
111-91-1
bis(2-Chloroethoxy)methane
ND
170
17
ug/kg
111-44-4
bis(2-Chloroethyl)ether
ND
170
20
ug/kg
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
170
22
ug/kg
91-58-7
2-Chloronaphthalene
ND
170
17
ug/kg
7005-72-3
4-Chlorophenyl phenyl ether
ND
170
17
ug/kg
218-01-9
Chrysene
ND
170
18
ug/kg
01
J
J
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS47 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: Z3-0.5-2
Lab Sample ID: FA98838-12 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 95.6
Project: PPD; Harnett St, Wilmington, NC
ABN List for NC, May 2012
CAS No.
Compound
Result
RL
MDL Units Q
53-70-3
Dibenzo(a,h)anthracene
ND
170
22
ug/kg
132-64-9
Dibenzofaran
ND
170
17
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
170
17
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
170
19
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
170
23
ug/kg
91-94-1
3,3'-Dichlorobenzidine
ND
170
41
ug/kg
84-66-2
Diethyl Phthalate
ND
350
35
ug/kg
131-11-3
Dimethyl Phthalate
ND
170
35
ug/kg
117-84-0
Di-n-octyl Phthalate a
ND
170
35
ug/kg
84-74-2
Di-n-butyl Phthalate
ND
350
70
ug/kg
122-66-7
1,2-Diphenylhydrazine
ND
170
17
ug/kg
117-81-7
bis(2-Ethylhexyl)phthalate
ND
350
35
ug/kg
206-44-0
Fluoranthene
31.7
170
17
ug/kg J
86-73-7
Fluorene
ND
170
19
ug/kg
118-74-1
Hexachlorobenzene b
ND
170
18
ug/kg
87-68-3
Hexachlorobutadiene
ND
170
18
ug/kg
77-47-4
Hexachlorocyclopentadiene
ND
170
35
ug/kg
67-72-1
Hexachloroethane
ND
170
21
ug/kg
193-39-5
Indeno(1,2,3-cd)pyrene
ND
170
21
ug/kg
78-59-1
Isophorone
ND
170
17
ug/kg
90-12-0
1-Methylnaphthalene
ND
170
17
ug/kg
91-57-6
2-Methylnaphthalene
ND
170
17
ug/kg
91-20-3
Naphthalene
ND
170
17
ug/kg
98-95-3
Nitrobenzene
ND
170
17
ug/kg
621-64-7
N-Nitrosodi-n-propylamine
ND
170
17
ug/kg
86-30-6
N-Nitrosodiphenylamine
ND
170
19
ug/kg
85-01-8
Phenanthrene
ND
170
17
ug/kg
129-00-0
Pyrene
32.6
170
20
ug/kg J
120-82-1
1,2,4-Trichlorobenzene
ND
170
21
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
367-12-4
2-Fluorophenol
72%
40-102%
4165-62-2
Phenol-d5
74%
41-100%
118-79-6
2,4,6-Tribromophenol
61%
42-108%
4165-60-0
Nitrobenzene-d5
65%
40-105%
321-60-8
2-Fluorobiphenyl
72%
43-107%
1718-51-0
Terphenyl-dl4
93%
45-119%
(a) Associated BS and CCV outside of control limits high, sample was ND.
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
GS48 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: Z3-0.5-2
Lab Sample ID: FA98838-12 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 95.6
Project: PPD; Harnett St, Wilmington, NC
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(b) Associated CCV outside of control limits low.
Page 3 of 3
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
aSGV 49 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: Z3-0.5-2
Lab Sample ID: FA98838-12 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Percent Solids: 95.6
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 1
Metals Analysis
Analyte Result RL
Units
DF
Prep
Analyzed
By
Method
Prep Method
Arsenic a < 2.1 2.1
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Barium a < 42 42
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Cadmium a < 0.83 0.83
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Chromium a 5.8 2.1
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Lead a 35.9 4.2
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Mercury 0.091 0.044
mg/kg
1
09/15/22
09/15/22
JC
SW846 7471B 1
SW846 7471B 3
Selenium a < 4.2 4.2
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Silver a < 2.1 2.1
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
(1) Instrument QC Batch: MA18914
(2) Instrument QC Batch: MA18920
(3) Prep QC Batch: MP41212
(4) Prep QC Batch: MP41216
(a) Sample dilution required due to difficult matrix.
RL = Reporting Limit
aSGV 50 of 99
FA98838

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: DUP-20220908
Lab Sample ID: FA98838-13 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8260D Percent Solids: 95.7
Project: PPD; Harnett St, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 170104663.1) 1 09/14/22 16:59 DB n/a n/a VF3752
Run #2
Initial Weight Final Volume
Run #1 6.60 g 5.0 ml
Run #2
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
67-64-1
Acetone
ND
160
79
ug/kg
71-43-2
Benzene
ND
4.0
0.97
ug/kg
108-86-1
Bromobenzene
ND
4.0
0.79
ug/kg
74-97-5
Bromochloromethane a
ND
4.0
1.2
ug/kg
75-27-4
Bromodichloromethane
ND
4.0
0.79
ug/kg
75-25-2
Bromoform
ND
4.0
0.79
ug/kg
78-93-3
2-Butanone (MEK)
ND
20
5.8
ug/kg
104-51-8
n-Butylbenzene b
ND
4.0
0.79
ug/kg
135-98-8
sec-Butylbenzene
ND
4.0
0.79
ug/kg
98-06-6
tert-Butylbenzene
ND
4.0
0.79
ug/kg
56-23-5
Carbon Tetrachloride
ND
4.0
0.81
ug/kg
108-90-7
Chlorobenzene
ND
4.0
0.79
ug/kg
75-00-3
Chloroethane
ND
4.0
1.6
ug/kg
67-66-3
Chloroform
ND
4.0
1.1
ug/kg
95-49-8
o-Chlorotoluene
ND
4.0
0.79
ug/kg
106-43-4
p-Chlorotoluene
ND
4.0
0.79
ug/kg
124-48-1
Dibromochloromethane
ND
4.0
0.79
ug/kg
106-93-4
1,2-Dibromoethane
ND
4.0
0.79
ug/kg
75-71-8
Dichlorodifluoromethane
ND
4.0
1.6
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
4.0
0.79
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
4.0
0.79
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
4.0
0.91
ug/kg
75-34-3
1, 1 -Dichloroethane
ND
4.0
1.4
ug/kg
107-06-2
1,2-Dichloroethane
ND
4.0
0.79
ug/kg
75-35-4
1, 1 -Dichloroethylene
ND
4.0
0.79
ug/kg
156-59-2
cis-1,2-Dichloroethylene
ND
4.0
1.1
ug/kg
156-60-5
trans- 1, 2-Dichloroethylene
ND
4.0
0.79
ug/kg
78-87-5
1,2-Dichloropropane
ND
4.0
0.79
ug/kg
142-28-9
1,3-Dichloropropane
ND
4.0
0.79
ug/kg
594-20-7
2,2-Dichloropropane
ND
4.0
0.79
ug/kg
563-58-6
1, 1 -Dichloropropene
ND
4.0
0.81
ug/kg
10061-01-5
cis- 1, 3 -Dichloropropene
ND
4.0
0.79
ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS51 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: DUP-20220908
Lab Sample ID: FA98838-13 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8260D Percent Solids: 95.7
Project: PPD; Harnett St, Wilmington, NC
VOA List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
10061-02-6
trans- 1, 3-Dichloropropene
ND
4.0
0.79
ug/kg
108-20-3
Di -Isopropyl Ether
ND
4.0
1.8
ug/kg
64-17-5
Ethyl Alcohol °
ND
320
59
ug/kg
100-41-4
Ethylbenzene
ND
4.0
0.79
ug/kg
591-78-6
2-Hexanone b
ND
20
5.9
ug/kg
98-82-8
Isopropylbenzene
ND
4.0
0.79
ug/kg
99-87-6
p-Isopropyltoluene
ND
4.0
0.79
ug/kg
74-83-9
Methyl Bromide
ND
4.0
1.6
ug/kg
74-87-3
Methyl Chloride
ND
4.0
1.6
ug/kg
75-09-2
Methylene Chloride d
ND
16
8.7
ug/kg
108-10-1
4-Methyl-2-pentanone (MIBK) ND
20
5.9
ug/kg
1634-04-4
Methyl Tert Butyl Ether
ND
4.0
0.79
ug/kg
91-20-3
Naphthalene
ND
4.0
1.6
ug/kg
103-65-1
n-Propylbenzene
ND
4.0
0.79
ug/kg
100-42-5
Styrene
ND
4.0
0.79
ug/kg
630-20-6
1, 1, 1, 2-Tetrachloroethane
ND
4.0
0.82
ug/kg
79-34-5
1,1,2,2-Tetrachloroethane b
ND
4.0
0.79
ug/kg
127-18-4
Tetrachloroethylene
ND
4.0
1.0
ug/kg
108-88-3
Toluene
ND
16
7.9
ug/kg
87-61-6
1, 2,3 -Trichlorobenzene
ND
4.0
1.1
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
4.0
0.79
ug/kg
71-55-6
1, 1, 1 -Trichloroethane
ND
4.0
0.79
ug/kg
79-00-5
1,1,2-Trichloroethane
ND
4.0
0.79
ug/kg
79-01-6
Trichloroethylene
ND
4.0
0.79
ug/kg
75-69-4
Trichlorofluoromethane
ND
4.0
1.6
ug/kg
96-18-4
1, 2,3 -Trichloropropane
ND
4.0
0.99
ug/kg
95-63-6
1,2,4-Trimethylbenzene
ND
4.0
0.79
ug/kg
108-67-8
1,3,5-Trimethylbenzene
ND
4.0
0.79
ug/kg
108-05-4
Vinyl Acetate
ND
20
13
ug/kg
75-01-4
Vinyl Chloride
ND
4.0
0.79
ug/kg
m,p-Xylene
ND
7.9
0.87
ug/kg
95-47-6
o-Xylene
ND
4.0
0.79
ug/kg
1330-20-7
Xylene (total)
ND
12
1.7
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
1868-53-7
Dibromofluoromethane
88%
75-124%
17060-07-0
1,2-Dichloroethane-D4
122%
72-135%
2037-26-5
Toluene-D8
112%
75-126%
460-00-4
4-Bromofluorobenzene
109%
71-133%
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
GS52 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: DUP-20220908
Lab Sample ID: FA98838-13 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8260D Percent Solids: 95.7
Project: PPD; Harnett St, Wilmington, NC
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(a) Associated CCV and BS outside control limits low.
(b) Associated CCV outside control limits high, sample is ND.
(c) Associated CCV outside control limits low.
(d) Associated CCV and BS recovery outside control limits high, sample is ND.
Page 3 of 3
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
SGS53 of 99
FA98838

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: DUP-20220908
Lab Sample ID: FA98838-13 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 95.7
Project: PPD; Harnett St, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 X083999.13 1 09/15/22 18:00 KA 09/14/22 07:30 OP93050 SX3330
Run #2
Initial Weight Final Volume
Run#1 30.0g 1.0ml
Run #2
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units
65-85-0
Benzoic Acid
ND
870
170
ug/kg
59-50-7
4-Chloro-3-methyl Phenol
ND
170
20
ug/kg
95-57-8
2-Chlorophenol
ND
170
21
ug/kg
120-83-2
2,4-Dichlorophenol
ND
170
20
ug/kg
105-67-9
2,4-Dimethylphenol
ND
170
46
ug/kg
51-28-5
2,4-Dinitrophenol
ND
870
170
ug/kg
534-52-1
4,6-Dinitro-o-cresol
ND
350
70
ug/kg
95-48-7
2-Methylphenol
ND
170
21
ug/kg
3&4-Methylphenol
ND
170
29
ug/kg
88-75-5
2-Nitrophenol
ND
170
19
ug/kg
100-02-7
4-Nitrophenol
ND
870
170
ug/kg
87-86-5
Pentachlorophenol
ND
870
170
ug/kg
108-95-2
Phenol
ND
170
17
ug/kg
88-06-2
2,4,6-Trichlorophenol
ND
170
20
ug/kg
83-32-9
Acenaphthene
ND
170
18
ug/kg
208-96-8
Acenaphthylene
ND
170
17
ug/kg
120-12-7
Anthracene
ND
170
20
ug/kg
56-55-3
Benzo(a)anthracene
ND
170
17
ug/kg
50-32-8
Benzo(a)pyrene
ND
170
21
ug/kg
205-99-2
Benzo(b)fluoranthene
ND
170
19
ug/kg
191-24-2
Benzo(g, h, i)perylene
ND
170
18
ug/kg
207-08-9
Benzo(k)fluoranthene
ND
170
23
ug/kg
100-51-6
Benzyl Alcohol
ND
170
17
ug/kg
101-55-3
4-Bromophenyl phenyl ether
ND
170
18
ug/kg
85-68-7
Butyl benzyl phthalate a
ND
170
35
ug/kg
106-47-8
4-Chloroaniline
ND
170
44
ug/kg
111-91-1
bis(2-Chloroethoxy)methane
ND
170
17
ug/kg
111-44-4
bis(2-Chloroethyl)ether
ND
170
20
ug/kg
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
170
22
ug/kg
91-58-7
2-Chloronaphthalene
ND
170
17
ug/kg
7005-72-3
4-Chlorophenyl phenyl ether
ND
170
17
ug/kg
218-01-9
Chrysene
ND
170
18
ug/kg
01
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS54 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: DUP-20220908
Lab Sample ID: FA98838-13 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 95.7
Project: PPD; Harnett St, Wilmington, NC
ABN List for NC, May 2012
CAS No.
Compound
Result
RL
MDL Units Q
53-70-3
Dibenzo(a,h)anthracene
ND
170
22
ug/kg
132-64-9
Dibenzofaran
ND
170
17
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
170
17
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
170
19
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
170
23
ug/kg
91-94-1
3,3'-Dichlorobenzidine
ND
170
41
ug/kg
84-66-2
Diethyl Phthalate
ND
350
35
ug/kg
131-11-3
Dimethyl Phthalate
ND
170
35
ug/kg
117-84-0
Di-n-octyl Phthalate a
ND
170
35
ug/kg
84-74-2
Di-n-butyl Phthalate
ND
350
70
ug/kg
122-66-7
1,2-Diphenylhydrazine
ND
170
17
ug/kg
117-81-7
bis(2-Ethylhexyl)phthalate
ND
350
35
ug/kg
206-44-0
Fluoranthene
ND
170
17
ug/kg
86-73-7
Fluorene
ND
170
19
ug/kg
118-74-1
Hexachlorobenzene b
ND
170
18
ug/kg
87-68-3
Hexachlorobutadiene
ND
170
18
ug/kg
77-47-4
Hexachlorocyclopentadiene
ND
170
35
ug/kg
67-72-1
Hexachloroethane
ND
170
21
ug/kg
193-39-5
Indeno(1,2,3-cd)pyrene
ND
170
21
ug/kg
78-59-1
Isophorone
ND
170
17
ug/kg
90-12-0
1-Methylnaphthalene
ND
170
17
ug/kg
91-57-6
2-Methylnaphthalene
ND
170
17
ug/kg
91-20-3
Naphthalene
ND
170
17
ug/kg
98-95-3
Nitrobenzene
ND
170
17
ug/kg
621-64-7
N-Nitrosodi-n-propylamine
ND
170
17
ug/kg
86-30-6
N-Nitrosodiphenylamine
ND
170
19
ug/kg
85-01-8
Phenanthrene
ND
170
17
ug/kg
129-00-0
Pyrene
ND
170
20
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
170
21
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
367-12-4
2-Fluorophenol
62%
40-102%
4165-62-2
Phenol-d5
63%
41-100%
118-79-6
2,4,6-Tribromophenol
57%
42-108%
4165-60-0
Nitrobenzene-d5
54%
40-105%
321-60-8
2-Fluorobiphenyl
61%
43-107%
1718-51-0
Terphenyl-dl4
80%
45-119%
(a) Associated BS and CCV outside of control limits high, sample was ND.
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS55 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: DUP-20220908
Lab Sample ID: FA98838-13 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 95.7
Project: PPD; Harnett St, Wilmington, NC
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(b) Associated CCV outside of control limits low.
Page 3 of 3
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
SGS56 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: DUP-20220908
Lab Sample ID: FA98838-13 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Percent Solids: 95.7
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 1
Metals Analysis
Analyte Result RL
Units
DF
Prep
Analyzed
By
Method
Prep Method
Arsenic a < 2.2 2.2
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Barium a < 43 43
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Cadmium a < 0.86 0.86
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Chromium a 4.6 2.2
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Lead a 32.5 4.3
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Mercury 0.090 0.037
mg/kg
1
09/15/22
09/15/22
JC
SW846 7471B 1
SW846 7471B 3
Selenium a < 4.3 4.3
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Silver a < 2.2 2.2
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
(1) Instrument QC Batch: MA18914
(2) Instrument QC Batch: MA18920
(3) Prep QC Batch: MP41212
(4) Prep QC Batch: MP41216
(a) Sample dilution required due to difficult matrix.
RL = Reporting Limit
SGS57 of 99
FA98838

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: Z5-0-2
Lab Sample ID: FA98838-14 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 94.5
Project: PPD; Harnett St, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 X084000.13 1 09/15/22 18:28 KA 09/14/22 07:30 OP93050 SX3330
Run #2
Initial Weight Final Volume
Run#1 30.0g 1.0ml
Run #2
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units
65-85-0
Benzoic Acid
ND
880
180
ug/kg
59-50-7
4-Chloro-3-methyl Phenol
ND
180
20
ug/kg
95-57-8
2-Chlorophenol
ND
180
22
ug/kg
120-83-2
2,4-Dichlorophenol
ND
180
20
ug/kg
105-67-9
2,4-Dimethylphenol
ND
180
47
ug/kg
51-28-5
2,4-Dinitrophenol
ND
880
180
ug/kg
534-52-1
4,6-Dinitro-o-cresol
ND
350
71
ug/kg
95-48-7
2-Methylphenol
ND
180
21
ug/kg
3&4-Methylphenol
ND
180
29
ug/kg
88-75-5
2-Nitrophenol
ND
180
19
ug/kg
100-02-7
4-Nitrophenol
ND
880
180
ug/kg
87-86-5
Pentachlorophenol
ND
880
180
ug/kg
108-95-2
Phenol
ND
180
18
ug/kg
88-06-2
2,4,6-Trichlorophenol
ND
180
20
ug/kg
83-32-9
Acenaphthene
ND
180
19
ug/kg
208-96-8
Acenaphthylene
ND
180
18
ug/kg
120-12-7
Anthracene
ND
180
20
ug/kg
56-55-3
Benzo(a)anthracene
ND
180
18
ug/kg
50-32-8
Benzo(a)pyrene
21.2
180
21
ug/kg
205-99-2
Benzo(b)fluoranthene
28.3
180
19
ug/kg
191-24-2
Benzo(g, h, i)perylene
ND
180
18
ug/kg
207-08-9
Benzo(k)fluoranthene
ND
180
23
ug/kg
100-51-6
Benzyl Alcohol
ND
180
18
ug/kg
101-55-3
4-Bromophenyl phenyl ether
ND
180
18
ug/kg
85-68-7
Butyl benzyl phthalate a
ND
180
35
ug/kg
106-47-8
4-Chloroaniline
ND
180
44
ug/kg
111-91-1
bis(2-Chloroethoxy)methane
ND
180
18
ug/kg
111-44-4
bis(2-Chloroethyl)ether
ND
180
20
ug/kg
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
180
22
ug/kg
91-58-7
2-Chloronaphthalene
ND
180
18
ug/kg
7005-72-3
4-Chlorophenyl phenyl ether
ND
180
18
ug/kg
218-01-9
Chrysene
ND
180
18
ug/kg
01
J
J
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
GS58 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: Z5-0-2
Lab Sample ID: FA98838-14 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 94.5
Project: PPD; Harnett St, Wilmington, NC
ABN List for NC, May 2012
CAS No.
Compound
Result
RL
MDL Units Q
53-70-3
Dibenzo(a,h)anthracene
ND
180
22
ug/kg
132-64-9
Dibenzofaran
ND
180
18
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
180
18
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
180
19
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
180
23
ug/kg
91-94-1
3,3'-Dichlorobenzidine
ND
180
42
ug/kg
84-66-2
Diethyl Phthalate
ND
350
35
ug/kg
131-11-3
Dimethyl Phthalate
ND
180
35
ug/kg
117-84-0
Di-n-octyl Phthalate a
ND
180
35
ug/kg
84-74-2
Di-n-butyl Phthalate
ND
350
71
ug/kg
122-66-7
1,2-Diphenylhydrazine
ND
180
18
ug/kg
117-81-7
bis(2-Ethylhexyl)phthalate
ND
350
35
ug/kg
206-44-0
Fluoranthene
24.9
180
18
ug/kg J
86-73-7
Fluorene
ND
180
19
ug/kg
118-74-1
Hexachlorobenzene b
ND
180
18
ug/kg
87-68-3
Hexachlorobutadiene
ND
180
18
ug/kg
77-47-4
Hexachlorocyclopentadiene
ND
180
35
ug/kg
67-72-1
Hexachloroethane
ND
180
21
ug/kg
193-39-5
Indeno(1,2,3-cd)pyrene
ND
180
21
ug/kg
78-59-1
Isophorone
ND
180
18
ug/kg
90-12-0
1-Methylnaphthalene
ND
180
18
ug/kg
91-57-6
2-Methylnaphthalene
ND
180
18
ug/kg
91-20-3
Naphthalene
ND
180
18
ug/kg
98-95-3
Nitrobenzene
ND
180
18
ug/kg
621-64-7
N-Nitrosodi-n-propylamine
ND
180
18
ug/kg
86-30-6
N-Nitrosodiphenylamine
ND
180
19
ug/kg
85-01-8
Phenanthrene
ND
180
18
ug/kg
129-00-0
Pyrene
25.4
180
20
ug/kg J
120-82-1
1,2,4-Trichlorobenzene
ND
180
21
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
367-12-4
2-Fluorophenol
66%
40-102%
4165-62-2
Phenol-d5
68%
41-100%
118-79-6
2,4,6-Tribromophenol
60%
42-108%
4165-60-0
Nitrobenzene-d5
56%
40-105%
321-60-8
2-Fluorobiphenyl
64%
43-107%
1718-51-0
Terphenyl-dl4
82%
45-119%
(a) Associated BS and CCV outside of control limits high, sample was ND.
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS59 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: Z5-0-2
Lab Sample ID: FA98838-14 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 94.5
Project: PPD; Harnett St, Wilmington, NC
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(b) Associated CCV outside of control limits low.
Page 3 of 3
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
aSGV 60 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: Z5-0-2
Lab Sample ID: FA98838-14 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Percent Solids: 94.5
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 1
Metals Analysis
Analyte Result RL
Units
DF
Prep
Analyzed
By
Method
Prep Method
Arsenic a 3.8 2.6
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050E 4
Barium a < 51 51
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Cadmium a < 1.0 1.0
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050E 4
Chromium a 8.1 2.6
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Lead a 73.8 5.1
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Mercury 0.067 0.042
mg/kg
1
09/15/22
09/15/22
JC
SW846 7471B 1
SW846 7471B 3
Selenium a < 5.1 5.1
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Silver a < 2.6 2.6
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
(1) Instrument QC Batch: MA18914
(2) Instrument QC Batch: MA18920
(3) Prep QC Batch: MP41212
(4) Prep QC Batch: MP41216
(a) Sample dilution required due to difficult matrix.
RL = Reporting Limit
aSGV 61 of 99
FA98838

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: Z5-5-1.5-2
Lab Sample ID: FA98838-15 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8260D Percent Solids: n/a a
Project: PPD; Harnett St, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 170104664.1) 1 09/14/22 17:24 DB n/a n/a VF3752
Run #2
Initial Weight Final Volume
Run #1 6.70 g 5.0 ml
Run #2
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
67-64-1
Acetone
ND
150
75
ug/kg
71-43-2
Benzene
ND
3.7
0.91
ug/kg
108-86-1
Bromobenzene
ND
3.7
0.75
ug/kg
74-97-5
Bromochloromethane b
ND
3.7
1.1
ug/kg
75-27-4
Bromodichloromethane
ND
3.7
0.75
ug/kg
75-25-2
Bromoform
ND
3.7
0.75
ug/kg
78-93-3
2-Butanone (MEK)
ND
19
5.4
ug/kg
104-51-8
n-Butylbenzene °
ND
3.7
0.75
ug/kg
135-98-8
sec-Butylbenzene
ND
3.7
0.75
ug/kg
98-06-6
tert-Butylbenzene
ND
3.7
0.75
ug/kg
56-23-5
Carbon Tetrachloride
ND
3.7
0.76
ug/kg
108-90-7
Chlorobenzene
ND
3.7
0.75
ug/kg
75-00-3
Chloroethane
ND
3.7
1.5
ug/kg
67-66-3
Chloroform
ND
3.7
0.99
ug/kg
95-49-8
o-Chlorotoluene
ND
3.7
0.75
ug/kg
106-43-4
p-Chlorotoluene
ND
3.7
0.75
ug/kg
124-48-1
Dibromochloromethane
ND
3.7
0.75
ug/kg
106-93-4
1,2-Dibromoethane
ND
3.7
0.75
ug/kg
75-71-8
Dichlorodifluoromethane
ND
3.7
1.5
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
3.7
0.75
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
3.7
0.75
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
3.7
0.86
ug/kg
75-34-3
1, 1 -Dichloroethane
ND
3.7
1.3
ug/kg
107-06-2
1,2-Dichloroethane
ND
3.7
0.75
ug/kg
75-35-4
1, 1 -Dichloroethylene
ND
3.7
0.75
ug/kg
156-59-2
cis-1,2-Dichloroethylene
ND
3.7
1.0
ug/kg
156-60-5
trans- 1, 2-Dichloroethylene
ND
3.7
0.75
ug/kg
78-87-5
1,2-Dichloropropane
ND
3.7
0.75
ug/kg
142-28-9
1,3-Dichloropropane
ND
3.7
0.75
ug/kg
594-20-7
2,2-Dichloropropane
ND
3.7
0.75
ug/kg
563-58-6
1, 1 -Dichloropropene
ND
3.7
0.76
ug/kg
10061-01-5
cis- 1, 3 -Dichloropropene
ND
3.7
0.75
ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
GS62 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: Z5-5-1.5-2
Lab Sample ID: FA98838-15 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8260D Percent Solids: n/a a
Project: PPD; Harnett St, Wilmington, NC
VOA List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
10061-02-6
trans- 1, 3-Dichloropropene
ND
3.7
0.75
ug/kg
108-20-3
Di -Isopropyl Ether
ND
3.7
1.7
ug/kg
64-17-5
Ethyl Alcohol d
ND
300
56
ug/kg
100-41-4
Ethylbenzene
ND
3.7
0.75
ug/kg
591-78-6
2-Hexanone c
ND
19
5.6
ug/kg
98-82-8
Isopropylbenzene
ND
3.7
0.75
ug/kg
99-87-6
p-Isopropyltoluene
ND
3.7
0.75
ug/kg
74-83-9
Methyl Bromide
ND
3.7
1.5
ug/kg
74-87-3
Methyl Chloride
ND
3.7
1.5
ug/kg
75-09-2
Methylene Chloride e
ND
15
8.2
ug/kg
108-10-1
4-Methyl-2-pentanone (MIBK) ND
19
5.6
ug/kg
1634-04-4
Methyl Tert Butyl Ether
ND
3.7
0.75
ug/kg
91-20-3
Naphthalene
ND
3.7
1.5
ug/kg
103-65-1
n-Propylbenzene
ND
3.7
0.75
ug/kg
100-42-5
Styrene
ND
3.7
0.75
ug/kg
630-20-6
1, 1, 1, 2-Tetrachloroethane
ND
3.7
0.77
ug/kg
79-34-5
1,1,2,2-Tetrachloroethane °
ND
3.7
0.75
ug/kg
127-18-4
Tetrachloroethylene
ND
3.7
0.96
ug/kg
108-88-3
Toluene
ND
15
7.5
ug/kg
87-61-6
1, 2,3 -Trichlorobenzene
ND
3.7
1.0
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
3.7
0.75
ug/kg
71-55-6
1, 1, 1 -Trichloroethane
ND
3.7
0.75
ug/kg
79-00-5
1,1,2-Trichloroethane
ND
3.7
0.75
ug/kg
79-01-6
Trichloroethylene
ND
3.7
0.75
ug/kg
75-69-4
Trichlorofluoromethane
ND
3.7
1.5
ug/kg
96-18-4
1, 2,3 -Trichloropropane
ND
3.7
0.93
ug/kg
95-63-6
1,2,4-Trimethylbenzene
ND
3.7
0.75
ug/kg
108-67-8
1,3,5-Trimethylbenzene
ND
3.7
0.75
ug/kg
108-05-4
Vinyl Acetate
ND
19
12
ug/kg
75-01-4
Vinyl Chloride
ND
3.7
0.75
ug/kg
m,p-Xylene
ND
7.5
0.82
ug/kg
95-47-6
o-Xylene
ND
3.7
0.75
ug/kg
1330-20-7
Xylene (total)
ND
11
1.6
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
1868-53-7
Dibromofluoromethane
88%
75-124%
17060-07-0
1,2-Dichloroethane-D4
122%
72-135%
2037-26-5
Toluene-D8
112%
75-126%
460-00-4
4-Bromofluorobenzene
109%
71-133%
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS63 of 99
FA98838

SGS North America Inc.
Report of Analysis
Client Sample ID: Z5-5-1.5-2
Lab Sample ID: FA98838-15 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8260D Percent Solids: n/a a
Project: PPD; Harnett St, Wilmington, NC
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(a) All results reported on a wet weight basis.
(b) Associated CCV and BS outside control limits low.
(c) Associated CCV outside control limits high, sample is ND.
(d) Associated CCV outside control limits low.
(e) Associated CCV and BS recovery outside control limits high, sample is ND.
Page 3 of 3
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
aSGV 64 of 99
FA98838

Orlando, FL
Misc. Forms
A - I I
Section 4
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
SGS65 of 99
FA98838

SGS North America Inc - Orlando
SG9 Chain Custody
4405 VinelAnd Roxd,S Sucre C-IS 011mido E172R1 I
PACIST 45 SGS- ORLANDOJOB*: PA OF
- - — Tel. 407-425-GTOD EAx 40T-4zs-oTm
wm
SGS - ORLANDO Quote #
SKIFF #
Client Reporting Information I Project Information
Analytic I Information
Matrix Codes
Company Name: ,�„-p.
Cy�� h\
Pmlect Name:
= Q
�`9
0
UW - MnXMg
Water
GW-Ground
Water
WW- Water
SW - Surface
Water
lode
L- -Sole
SLO Sludge
OI - Oil
LID - Other Liquid
AIR - Air
SOL - r Sad
Address: Q"1\ (`.].-
Q \l i
Street
City: ; State: Zip:
a
Pro) Contact: Em Il:
S 1:1,bb .W{11e @ bey
)� #
�.,.
Phone :/fix,..
"r4
Fax#
Sampler(s) Name(s) (Printed)
Sampler 1: Sampler 2:
Client Purchase Order #
SGS
Orlando
Semple #
Field ID / Point of Collection
COLLECTION
CONER
TAIN
INFORMATION
OATS
TIME
B-PLED
BY'.
MATRIx
TorALn
of
BOTTLES
p
_
� w
LAB USE ONLY
i9
\boo
lTN
S'
3
t
10o
d2w
3
L
3
n
(oo
N
.-)-
i
lam\ - i"' z
Iw-
2
X
g
2 -o.ti
I, loon
Z
i
x
l 0
vpbb
AM
3
k kPOo
# w
y
z
><
12
Turnaround Time Business da s
Data
Oelivenbfa
Information
Comme
is 1
Remarks
10 Day (Business) Approved By: / Date:
7 Day
5 Day
3 Day RUSH
2 Day RUSH
1 Day RUSH
Other
Rush T/A Data Available VIA Email or Lablink�-i-
COMMERCIAL "A" (RESULTS ONLY)
COMMERCIAL "B" (RESULTS PLUS OC)
[]REDT1 (EPA LEVEL 3)
L]FULLTI (EPA LEVEL 4)
E]EDD'S
LABEL VERIFICA110NT__
"4
SamoltCustod must be documented bolcw each time samples thane possession, ncludln courier delivery.
Relinquished by Sampler/Affiliation
1
Date Time:
Received eylAnryilllaattei�onn ,q to 22
2 r•V �V 1fnn
Relinquished By/Affiliation
3
Date i.e:T
Received By/Affiliation
4
Relinquished by/Affiliation
5
Date Time:
Re elved By/Affiliation
6
Relinquished By/Affiliation
7
Date Time:
Received By/Affiliation
8
_
Lab Use Onl : Cooler Temperature (s) Celsius (corrected): htt ://—.s s com/en/terms-and-conditions
'SGS COC Rev 031318
FA98838: Chain of Custody
Page 1 of 5
SGS66 of 99
FA98838

SGS North America Inc - Orlando 1;7A 01 S fo O� Is
S� Chain of Custody SGS - ORLANDO JOB #: PAGE 2 OF_
4405 V' I d R d S 'Ic C 15 Orl d FI 32811
—
- TEL.[phone] FAX [phone]
SGS - ORLANDO Quote # SKIFF # -
Client / Reporting Information Pro'ect Information
Analytic I Information
I
Matrix Codes
Company Name:
ProjgFt Name:
PPP
,^
-Vy\'
U
.q
OW- nn mg
Water
GW - Ground
Watett
WW-water
SW -Surface
SO -a
SL-Sludge
OI - Oil
LIQ - Other Liquid
AIR - Air
$ L- th fS011d
Addrebs:
Rfn i M-
Street
City: n11 ^ State: zip: a 4U�
11Y sae
Project tinlact: Email:
0d , dti Q
Project #
Phone#: >�'
Fax#
Sampler(s) Name(s) (Printed)
Sampler 1: Sampler 2:
Client Purchase Order #
SGS
Orlando
Sam le #
Field ID /Point of Collection
COLLECTION
CONTAINER
INFORMATION
LAB USE ONLY
ogre
S eFLEO
ralx
TOTAL
ea� L E5
_
g
w
3
13
a1n-a-aa",o
1/9
1
�w
z 2
►
X
I
Z; _ _
nis
Aw
a
a
ZS -�- -T -P,
I'Mr
4
3
2
Turnaround Time Business days)
Data
Deliverable
Information
Comments
/
Remarks
10 Day (Business) Approved By: I Date:
7 Day
5 Day
3 Day RUSH
2 Day RUSH
1 Day RUSH
Other
Rush T/A Data Available VIA Email or Lablink
FICOMMERCIAL "A" (RESULTS ONLY)
❑COMMERCIAL "B" (RESULTS PLUS QC)
FIREDT1 (EPALEVEL3)
FULLTI (EPA LEVEL 4)
F]EDD'S
CD M
n L
Sample Custody moot be
documented below each time samples
thane pmsession, Including
courier delivery.
Relinquished by Sampler/Affiliation
1
Date Time:
Re eivetl y/Affiliation IO Z�-
2 I (O
Relinquished By/Affiliation
3
Date Time:
Received By/Affiliation
4 r--F
Relinquished by/Affiliation
5
Date Time:
Received By/Affiliation
B
Relinquished By/Affiliation
7
Date Time:
Received By/Affiliation
8
Lab Use Only : Cooler Temperature (a) Celsius (corrected). hit :INmvs .co e e -a d-Ln silo s
ORLD-SMT-0001-03-FORM-COC (4).xls Rev 031318
FA98838: Chain of Custody
Page 2 of 5
SGS67 of 99
FA98838

SGS Sample Receipt Summary
Job Number: FA98838
Client: GEOSYNTEC
Project: PPD
Date / Time Received: 9/10/2022
11:00:00 AM Delivery Method:
FEDEX Airbill Ws: 5707 9049 9574
Therm ID: IR 1;
Therm CF: 0.6;
# of Coolers: 1
Cooler Temps (Raw Measured) °C: Cooler
1: (3.8);
Cooler Temps (Corrected) °C: Cooler
1: (4.4);
Cooler Information
Y or
N
Sample Information
Y or
N
N/A
1. Custody Seals Present
V
❑
1. Sample labels present on bottles
❑J
❑
2. Custody Seals Intact
❑d
❑
2. Samples preserved properly
W
❑
3. Temp criteria achieved
❑,i
❑
3. Sufficient volume/containers recvd for analysis:
❑d
❑
4. Cooler temp verification
IR Gun
4. Condition of sample
Intact
5. Cooler media
Ice (Baal
5. Sample recvd within HT
❑d
❑
6. Dates/Times/IDs on COC match Sample Label
❑�
❑
Trip Blank Information
Y or
N N/A
7. VOCs have headspace
❑
❑
❑d
1. Trip Blank present / cooler
❑
❑ ❑.6
8. Bottles received for unspecified tests
❑
❑d
2. Trip Blank listed on CDC
❑
❑ ❑,/
9. Compositing instructions clear
❑
❑
W
W
S N/A
10. Voa Soil Kits/Jars received past 48hrs?
❑
❑
0
or
11. % Solids Jar received?
❑
❑
0
3. Type Of TB Received
❑
❑ W
12. Residual Chlorine Present?
❑
❑
W
Misc. Information
Number of Encores: 25-Gram
Test Strip Lot #s: pH 0-3
Residual Chlorine Test Strip Lot #:
5-Gram Number of 5035 Field Kits: Number of Lab Filtered Metals:
230315 pH 10-12 219813A Other: (Specify)
Comments FROZEN @ 09/12/22 H 1115.
DID NOT RECEIVE BULK SOIL JARS FOR %SOLIDS ANALYSIS FOR THE FOLLOWING SAMPLES:
SAMPLE -1, ID: "71-1-0-0.5", SAMPLE -2, ID: "71-1-1-1.5", SAMPLE -5, ID: "22-2-0-0.5", SAMPLE -6, ID: "Z2-3-1.5-2", SAMPLE -9, ID: "73-3-0-0.5", SAMPLE -
10, ID: "Z3-3-1.5-2", OR SAMPLE 15, ID: "Z5-5-1.5-2".
FOR SAMPLE -3, ID: "21-0-0.5", TIME OF SAMPLE COLLECTION ON COC IS "1100", BUT TIME OF SAMPLE COLLECTION ON SAMPLE ID LABEL IS "1115".
Rev. Date 05/24/17 Technician: SAMUELM Date: 9/10/2022 11:00:00 A Reviewer: Date:
Rev. D
FA98838: Chain of Custody
Page 3 of 5
GS68 of 99
FA98838

Job Change Order: FA98838
Requested Date: 9/13/2022
Account Name: Geosyntec Consultants
Project Description: Kettler; 31 Harnett St, Wilmington, NC
CSR: KB
Sample M FA98838-all
Dept:
TAT: 7
Sample M FA98838-1
Dept:
TAT: 7
Received Date:
9/10/2022
Due Date:
9/19/2022
Deliverable:
COMMB
TAT (Days):
7
Change:
Per client, log in as new project named "PPD"
Change:
Per client, use %SOL data from FA98838-3
Z1-1-0-0.5
------------------
Sample M FA98838-2 Change:
Dept: Per client, use %SOL data from FA98838-4
TAT: 7
Z1-1-1-1.5
Sample M FA98838-5 Change:
Dept: Per client, use %SOL data from FA98838-7
TAT: 7
Z2-2-0-0.5
-------------------------------------------------------------------------------------------------------------------- 38: Chain of Custody
Above Changes Per: Abby Wesley Date/Time: 9/13/2022 11:19:57 AM Page 4 of 5
To Client: This Change Order is confirmation of the revisions, previously discussed with the Client Service Representative.
Page 1 of 2
.SG`
69 of 99
FA98838

Job Change Order:
Requested Date: 9/13/2022 Received Date
Account Name: Geosyntec Consultants Due Date:
Project Description: Kettler; 31 Harnett St, Wilmington, NC Deliverable:
CSR: KB TAT (Days):
-----------------------------------------------------------------------------------------
Sample #: FA98838-6 Change:
Dept: Per client, use %SOL data from FA98838-8
TAT: 7
Z2-3-1.5-2
Sample #: FA98838-9 Change:
Dept: Per client, use %SOL data from FA98838-11
TAT: 7
rACIIC111111 .".
FA98838
9/10/2022
9/19/2022
COMMB
7
--------------------------------------------------------------------------------------------------------------------
---------------------------------------------------------------------------------------------------------
Sample #: FA98838-10 Change:
Dept: Per client, use %SOL data from FA98838-12
TAT: 7
Z3-3-1.5-2
Sample #: FA98838-15
Dept:
TAT: 7
Z5-5-1.5-2
Above Changes Per: Abby Wesley
Change:
Per client, use %SOL data from FA98838-14
FA98838: Chain of Custody
Date/Time: 9/13/202211:19:57AM Page 5 of 5
To Client: This Change Order is confirmation of the revisions, previously discussed with the Client Service Representative.
Page 2 of 2
P,
.SG`
70 of 99
FA98838

SGS',-
I
Orlando, FL
MS Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Section 5
aSGV 71 of 99
FA98838

Method Blank Summary
Job Number: FA98838
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
VF3752-MB
170104649.1)
1
09/14/22
DB
n/a
n/a
VF3752
The QC reported here applies to the following samples: Method: SW846 8260D
FA98838-1, FA98838-2, FA98838-5, FA98838-6, FA98838-9, FA98838-10, FA98838-13, FA98838-15
CAS No. Compound
Result RL MDL Units Q
67-64-1
Acetone
ND
200
100
ug/kg
71-43-2
Benzene
ND
5.0
1.2
ug/kg
108-86-1
Bromobenzene
ND
5.0
1.0
ug/kg
74-97-5
Bromochloromethane
ND
5.0
1.5
ug/kg
75-27-4
Bromodichloromethane
ND
5.0
1.0
ug/kg
75-25-2
Bromoform
ND
5.0
1.0
ug/kg
78-93-3
2-Butanone (MEK)
ND
25
7.3
ug/kg
104-51-8
n-Butylbenzene
ND
5.0
1.0
ug/kg
135-98-8
sec-Butylbenzene
ND
5.0
1.0
ug/kg
98-06-6
tert-Butylbenzene
ND
5.0
1.0
ug/kg
56-23-5
Carbon Tetrachloride
ND
5.0
1.0
ug/kg
108-90-7
Chlorobenzene
ND
5.0
1.0
ug/kg
75-00-3
Chloroethane
ND
5.0
2.0
ug/kg
67-66-3
Chloroform
ND
5.0
1.3
ug/kg
95-49-8
o-Chlorotoluene
ND
5.0
1.0
ug/kg
106-43-4
p-Chlorotoluene
ND
5.0
1.0
ug/kg
124-48-1
Dibromochloromethane
ND
5.0
1.0
ug/kg
106-93-4
1,2-Dibromoethane
ND
5.0
1.0
ug/kg
75-71-8
Dichlorodifluoromethane
ND
5.0
2.0
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
5.0
1.0
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
5.0
1.0
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
5.0
1.2
ug/kg
75-34-3
1, 1 -Dichloroethane
ND
5.0
1.8
ug/kg
107-06-2
1,2-Dichloroethane
ND
5.0
1.0
ug/kg
75-35-4
1, 1 -Dichloroethylene
ND
5.0
1.0
ug/kg
156-59-2
cis- 1, 2-Dichloroethylene
ND
5.0
1.4
ug/kg
156-60-5
trans- 1, 2-Dichloroethylene
ND
5.0
1.0
ug/kg
78-87-5
1,2-Dichloropropane
ND
5.0
1.0
ug/kg
142-28-9
1,3-Dichloropropane
ND
5.0
1.0
ug/kg
594-20-7
2,2-Dichloropropane
ND
5.0
1.0
ug/kg
563-58-6
1, 1 -Dichloropropene
ND
5.0
1.0
ug/kg
10061-01-5 cis-1,3-Dichloropropene
ND
5.0
1.0
ug/kg
10061-02-6 trans-1,3-Dichloropropene
ND
5.0
1.0
ug/kg
108-20-3
Di -Isopropyl Ether
ND
5.0
2.3
ug/kg
64-17-5
Ethyl Alcohol
ND
400
75
ug/kg
100-41-4
Ethlbenzene
ND
5.0
1.0
ug/kg
SGS72 of 99
FA98838

Method Blank Summary
Job Number: FA98838
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 2 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
VF3752-MB
F0104649.D
1
09/14/22
DB
n/a
n/a
VF3752
The QC reported here applies to the following samples: Method: SW846 8260D
FA98838-1, FA98838-2, FA98838-5, FA98838-6, FA98838-9, FA98838-10, FA98838-13, FA98838-15
CAS No. Compound
Result RL MDL Units Q
591-78-6
2-Hexanone
ND
25
7.5
ug/kg
98-82-8
Isopropylbenzene
ND
5.0
1.0
ug/kg
99-87-6
p-Isopropyltoluene
ND
5.0
1.0
ug/kg
74-83-9
Methyl Bromide
ND
5.0
2.0
ug/kg
74-87-3
Methyl Chloride
ND
5.0
2.0
ug/kg
75-09-2
Methylene Chloride
59.5
20
11
ug/kg
108-10-1
4-Methyl-2-pentanone (MIBK) ND
25
7.5
ug/kg
1634-04-4
Methyl Tert Butyl Ether
ND
5.0
1.0
ug/kg
91-20-3
Naphthalene
ND
5.0
2.0
ug/kg
103-65-1
n-Propylbenzene
ND
5.0
1.0
ug/kg
100-42-5
Styrene
ND
5.0
1.0
ug/kg
630-20-6
1, 1, 1, 2-Tetrachloroethane
ND
5.0
1.0
ug/kg
79-34-5
1,1,2,2-Tetrachloroethane
ND
5.0
1.0
ug/kg
127-18-4
Tetrachloroethylene
ND
5.0
1.3
ug/kg
108-88-3
Toluene
ND
20
10
ug/kg
87-61-6
1,2,3-Trichlorobenzene
ND
5.0
1.4
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
5.0
1.0
ug/kg
71-55-6
1, 1, 1 -Trichloroethane
ND
5.0
1.0
ug/kg
79-00-5
1,1,2-Trichloroethane
ND
5.0
1.0
ug/kg
79-01-6
Trichloroethylene
ND
5.0
1.0
ug/kg
75-69-4
Trichlorofluoromethane
ND
5.0
2.0
ug/kg
96-18-4
1, 2,3 -Trichloropropane
ND
5.0
1.3
ug/kg
95-63-6
1,2,4-Trimethylbenzene
ND
5.0
1.0
ug/kg
108-67-8
1,3,5-Trimethylbenzene
ND
5.0
1.0
ug/kg
108-05-4
Vinyl Acetate
ND
25
16
ug/kg
75-01-4
Vinyl Chloride
ND
5.0
1.0
ug/kg
m,p-Xylene
ND
10
1.1
ug/kg
95-47-6
o-Xylene
ND
5.0
1.0
ug/kg
1330-20-7
Xylene (total)
ND
15
2.1
ug/kg
CAS No.
Surrogate Recoveries
Limits
1868-53-7
Dibromofluoromethane
87%
75-124%
17060-07-0
1,2-Dichloroethane-D4
112%
72-135%
2037-26-5
Toluene-D8
109%
75-126%
SGS73 of 99
FA98838

Method Blank Summary
Job Number: FA98838
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 3 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
VF3752-MB
170104649.1)
1
09/14/22
DB
n/a
n/a
VF3752
The QC reported here applies to the following samples: Method: SW846 8260D
FA98838-1, FA98838-2, FA98838-5, FA98838-6, FA98838-9, FA98838-10, FA98838-13, FA98838-15
CAS No. Surrogate Recoveries Limits
460-00-4 4-Bromofluorobenzene 96% 71-133%
GS74 of 99
FA98838

Blank Spike Summary
Job Number: FA98838
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
VF3752-BS
170104647.1)
1
09/14/22
DB
n/a
n/a
VF3752
The QC reported here applies to the following samples: Method: SW846 8260D
FA98838-1, FA98838-2, FA98838-5, FA98838-6, FA98838-9, FA98838-10, FA98838-13, FA98838-15
Spike BSP BSP
CAS No. Compound ug/kg ug/kg % Limits
67-64-1
Acetone
250
194
78
61-152
71-43-2
Benzene
50
43.8
88
76-126
108-86-1
Bromobenzene
50
48.3
97
76-122
74-97-5
Bromochloromethane
50
37.4
75*
77-120
75-27-4
Bromodichloromethane
50
46.2
92
74-130
75-25-2
Bromoform
50
48.9
98
76-127
78-93-3
2-Butanone (MEK)
250
212
85
75-137
104-51-8
n-Butylbenzene
50
57.4
115
71-128
135-98-8
sec-Butylbenzene
50
58.9
118
79-135
98-06-6
tert-Butylbenzene
50
59.1
118
77-133
56-23-5
Carbon Tetrachloride
50
42.6
85
78-133
108-90-7
Chlorobenzene
50
48.9
98
81-129
75-00-3
Chloroethane
50
42.3
85
68-133
67-66-3
Chloroform
50
45.5
91
72-123
95-49-8
o-Chlorotoluene
50
57.2
114
77-129
106-43-4
p-Chlorotoluene
50
58.0
116
80-134
124-48-1
Dibromochloromethane
50
47.6
95
76-127
106-93-4
1,2-Dibromoethane
50
50.5
101
77-126
75-71-8
Dichlorodifluoromethane
50
50.8
102
68-168
95-50-1
1,2-Dichlorobenzene
50
53.9
108
80-129
541-73-1
1,3-Dichlorobenzene
50
54.2
108
81-129
106-46-7
1,4-Dichlorobenzene
50
54.5
109
76-130
75-34-3
1,1-Dichloroethane
50
46.0
92
73-125
107-06-2
1,2-Dichloroethane
50
46.3
93
74-128
75-35-4
1, 1 -Dichloroethylene
50
45.3
91
81-136
156-59-2
cis- 1, 2-Dichloroethylene
50
43.4
87
74-126
156-60-5
trans- 1, 2-Dichloroethylene
50
43.5
87
70-127
78-87-5
1,2-Dichloropropane
50
41.0
82
74-125
142-28-9
1,3-Dichloropropane
50
51.1
102
76-122
594-20-7
2,2-Dichloropropane
50
44.6
89
77-133
563-58-6
1, 1 -Dichloropropene
50
44.8
90
75-130
10061-01-5 cis-1,3-Dichloropropene
50
44.2
88
80-123
10061-02-6 trans-1,3-Dichloropropene
50
59.5
119
75-131
108-20-3
Di -Isopropyl Ether
50
45.3
91
75-122
64-17-5
Ethyl Alcohol
1000
569
57
53-154
100-41-4
Ethlbenzene
50
52.6
105
77-123
* = Outside of Control Limits.
SGS75 of 99
FA98838

Blank Spike Summary
Job Number: FA98838
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 2 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
VF3752-BS
F0104647.D
1
09/14/22
DB
n/a
n/a
VF3752
The QC reported here applies to the following samples: Method: SW846 8260D
FA98838-1, FA98838-2, FA98838-5, FA98838-6, FA98838-9, FA98838-10, FA98838-13, FA98838-15
Spike
BSP
BSP
CAS No.
Compound
ug/kg
ug/kg
%
Limits
591-78-6
2-Hexanone
250
264
106
72-133
98-82-8
Isopropylbenzene
50
50.7
101
80-136
99-87-6
p-Isopropyltoluene
50
55.6
111
77-131
74-83-9
Methyl Bromide
50
41.1
82
65-139
74-87-3
Methyl Chloride
50
48.4
97
71-144
75-09-2
Methylene Chloride
50
105
210*
74-137
108-10-1
4-Methyl-2-pentanone (MIBK) 250
274
110
76-132
1634-04-4
Methyl Tert Butyl Ether
50
44.2
88
77-120
91-20-3
Naphthalene
50
55.7
111
79-129
103-65-1
n-Propylbenzene
50
59.5
119
80-135
100-42-5
Styrene
50
49.1
98
78-125
630-20-6
1, 1, 1, 2-Tetrachloroethane
50
48.0
96
78-126
79-34-5
1,1,2,2-Tetrachloroethane
50
60.2
120
71-126
127-18-4
Tetrachloroethylene
50
40.0
80
79-130
108-88-3
Toluene
50
51.6
103
76-124
87-61-6
1,2,3-Trichlorobenzene
50
55.6
ill
77-128
120-82-1
1,2,4-Trichlorobenzene
50
55.5
ill
78-130
71-55-6
1, 1, 1 -Trichloroethane
50
44.1
88
70-129
79-00-5
1,1,2-Trichloroethane
50
54.0
108
74-124
79-01-6
Trichloroethylene
50
42.2
84
75-128
75-69-4
Trichlorofluoromethane
50
47.6
95
73-145
96-18-4
1, 2,3 -Trichloropropane
50
56.0
112
74-127
95-63-6
1,2,4-Trimethylbenzene
50
57.0
114
74-123
108-67-8
1,3,5-Trimethylbenzene
50
54.7
109
73-122
108-05-4
Vinyl Acetate
250
234
94
48-164
75-01-4
Vinyl Chloride
50
47.3
95
76-141
m,p-Xylene
100
104
104
80-128
95-47-6
o-Xylene
50
52.7
105
80-132
1330-20-7
Xylene (total)
150
156
104
80-129
CAS No.
Surrogate Recoveries
BSP
Limits
1868-53-7
Dibromofluoromethane
92%
75-124%
17060-07-0
1,2-Dichloroethane-D4
111%
72-135%
2037-26-5
Toluene-D8
111%
75-126%
* = Outside of Control Limits.
GS76 of 99
FA98838

Blank Spike Summary
Job Number: FA98838
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 3 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
VF3752-BS
170104647.1)
1
09/14/22
DB
n/a
n/a
VF3752
The QC reported here applies to the following samples: Method: SW846 8260D
FA98838-1, FA98838-2, FA98838-5, FA98838-6, FA98838-9, FA98838-10, FA98838-13, FA98838-15
CAS No. Surrogate Recoveries
460-00-4 4-Bromofluorobenzene
* = Outside of Control Limits.
BSP Limits
102% 71-133%
SGS77 of 99
FA98838

Matrix Spike/Matrix Spike Duplicate Summary
Job Number: FA98838
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
FA98779-lMS
170104670.1)
1
09/14/22
DB
n/a
n/a
VF3752
FA98779-1MSD
170104671.1)
1
09/14/22
DB
n/a
n/a
VF3752
FA98779-1
170104651.1)
1
09/14/22
DB
n/a
n/a
VF3752
The QC reported here applies to the following samples:
Method: SW846 8260D
FA98838-1, FA98838-2, FA98838-5, FA98838-6, FA98838-9, FA98838-10, FA98838-13, FA98838-15
FA98779-1
Spike
MS
MS
Spike
MSD
MSD
Limits
CAS No.
Compound
ug/kg Q
ug/kg
ug/kg
%
ug/kg
ug/kg
%
RPD
Rec/RPD
67-64-1
Acetone
190 U
290
133
46*
295
152
52*
13
61-152/27
71-43-2
Benzene
4.7 U
58
34.0
59*
59
36.2
61*
6
76-126/26
108-86-1
Bromobenzene
4.7 U
58
26.4
46*
59
25.3
43*
4
76-122/32
74-97-5
Bromochloromethane
4.7 U
58
28.4
49*
59
31.0
53*
9
77-120/24
75-27-4
Bromodichloromethane
4.7 U
58
31.4
54*
59
34.2
58*
9
74-130/25
75-25-2
Bromoform
4.7 U
58
23.1
40*
59
26.8
45*
15
76-127/26
78-93-3
2-Butanone(MEK)
24 U
290
139
48*
295
156
53*
12
75-137/25
104-51-8
n-Butylbenzene
4.7 U
58
16.6
29*
59
18.8
32*
12
71-128/35
135-98-8
sec-Butylbenzene
4.7 U
58
22.1
38*
59
25.4
43*
14
79-135/34
98-06-6
tert-Butylbenzene
4.7 U
58
25.8
44*
59
28.4
48*
10
77-133/34
56-23-5
Carbon Tetrachloride
4.7 U
58
31.1
54*
59
33.0
56*
6
78-133/29
108-90-7
Chlorobenzene
4.7 U
58
27.5
47*
59
30.3
51*
10
81-129/29
75-00-3
Chloroethane
4.7 U
58
38.7
67*
59
39.0
66*
1
68-133/29
67-66-3
Chloroform
4.7 U
58
35.2
61*
59
38.3
65*
8
72-123/26
95-49-8
o-Chlorotoluene
4.7 U
58
26.7
46*
59
28.8
49*
8
77-129/33
106-43-4
p-Chlorotoluene
4.7 U
58
25.2
43*
59
27.9
47*
10
80-134/33
124-48-1
Dibromochloromethane
4.7 U
58
27.2
47*
59
31.9
54*
16
76-127/27
106-93-4
1,2-Dibromoethane
4.7 U
58
30.8
53*
59
35.4
60*
14
77-126/26
75-71-8
Dichlorodifluoromethane
4.7 U
58
45.0
78
59
47.2
80
5
68-168/29
95-50-1
1,2-Dichlorobenzene
4.7 U
58
17.5
30*
59
19.6
33*
11
80-129/32
541-73-1
1, 3 -Dichlorobenzene
4.7 U
58
19.2
33*
59
21.3
36*
10
81-129/33
106-46-7
1,4-Dichlorobenzene
4.7 U
58
19.5
34*
59
20.6
35*
5
76-130/32
75-34-3
1, 1 -Dichloroethane
4.7 U
58
37.7
65*
59
40.0
68*
6
73-125/27
107-06-2
1,2-Dichloroethane
4.7 U
58
35.1
61*
59
38.3
65*
9
74-128/23
75-35-4
1, 1 -Dichloroethylene
4.7 U
58
38.5
66*
59
39.7
67*
3
81-136/28
156-59-2
cis- 1, 2-Dichloroethylene
4.7 U
58
32.7
56*
59
35.4
60*
8
74-126/26
156-60-5
trans- 1, 2-Dichloroethylene
4.7 U
58
34.9
60*
59
36.3
62*
4
70-127/27
78-87-5
1,2-Dichloropropane
4.7 U
58
29.6
51*
59
33.3
56*
12
74-125/25
142-28-9
1,3-Dichloropropane
4.7 U
58
35.8
62*
59
38.4
65*
7
76-122/26
594-20-7
2,2-Dichloropropane
4.7 U
58
35.1
61*
59
37.6
64*
7
77-133/28
563-58-6
1, 1 -Dichloropropene
4.7 U
58
33.6
58*
59
35.4
60*
5
75-130/28
10061-01-5 cis- 1, 3-Dichloropropene
4.7 U
58
26.6
46*
59
29.3
50*
10
80-123/26
10061-02-6 trans- 1, 3-Dichloropropene
4.7 U
58
34.4
59*
59
39.5
67*
14
75-131/28
108-20-3
Di -Isopropyl Ether
4.7 U
58
37.9
65*
59
40.6
69*
7
75-122/25
64-17-5
Ethyl Alcohol
380 U
1160
570
49*
1180
542
46*
5
53-154/42
100-41-4
Ethylbenzene
4.7 U
58
30.3
52*
59
33.8
57*
11
77-123/31
* = Outside of Control Limits.
.SG`
78 of 99
FA98838

CAS No.
591-78-6
98-82-8
99-87-6
74-83-9
74-87-3
75-09-2
108-10-1
1634-04-4
91-20-3
103-65-1
100-42-5
630-20-6
79-34-5
127-18-4
108-88-3
87-61-6
120-82-1
71-55-6
79-00-5
79-01-6
75-69-4
96-18-4
95-63-6
108-67-8
108-05-4
75-01-4
95-47-6
1330-20-7
CAS No.
Matrix Spike/Matrix Spike Duplicate Summary
Job Number: FA98838
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 2 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
FA98779-lMS
F0104670.D
1
09/14/22
DB
n/a
n/a
VF3752
FA98779-1MSD
F0104671.D
1
09/14/22
DB
n/a
n/a
VF3752
FA98779-1
170104651.1)
1
09/14/22
DB
n/a
n/a
VF3752
The QC reported here applies to the following samples:
Method: SW846 8260D
FA98838-1, FA98838-2, FA98838-5, FA98838-6, FA98838-9, FA98838-10, FA98838-13, FA98838-15
FA98779-1
Spike
MS
MS
Spike
MSD
MSD
Limits
Compound
ug/kg Q
ug/kg
ug/kg
%
ug/kg
ug/kg
%
RPD
Rec/RPD
2-Hexanone
24 U
290
165
57*
295
180
61*
9
72-133/26
Isopropylbenzene
4.7 U
58
24.6
42*
59
28.1
48*
13
80-136/32
p-Isopropyltoluene
4.7 U
58
18.9
33*
59
21.2
36*
11
77-131/34
Methyl Bromide
4.7 U
58
33.1
57*
59
33.2
56*
0
65-139/31
Methyl Chloride
4.7 U
58
42.7
74
59
44.5
75
4
71-144/27
Methylene Chloride
19 U
58
52.4
90
59
42.6
72*
21
74-137/28
4-Methyl-2-pentanone (MIBK) 24 U
290
198
68*
295
227
77
14
76-132/26
Methyl Tert Butyl Ether
4.7 U
58
36.0
62*
59
39.7
67*
10
77-120/24
Naphthalene
4.7 U
58
12.2
21*
59
13.9
24*
13
79-129/33
n-Propylbenzene
4.7 U
58
27.9
48*
59
29.8
50*
7
80-135/33
Styrene
4.7 U
58
23.2
40*
59
27.2
46*
16
78-125/30
1, 1, 1,2-Tetrachloroethane
4.7 U
58
28.3
49*
59
32.8
56*
15
78-126/27
1,1,2,2-Tetrachloroethane
4.7 U
58
32.5
56*
59
37.2
63*
13
71-126/30
Tetrachloroethylene
4.7 U
58
21.5
37*
59
24.8
42*
14
79-130/31
Toluene
19 U
58
35.5
61*
59
38.7
66*
9
76-124/30
1,2,3-Trichlorobenzene
4.7 U
58
9.2
16*
59
9.7
16*
5
77-128/35
1,2,4-Trichlorobenzene
4.7 U
58
9.5
16*
59
11.3
19*
17
78-130/34
1, 1, 1 -Trichloroethane
4.7 U
58
35.9
62*
59
37.1
63*
3
70-129/27
1, 1, 2-Trichloroethane
4.7 U
58
35.9
62*
59
41.1
70*
14
74-124/28
Trichloroethylene
4.7 U
58
29.9
52*
59
32.6
55*
9
75-128/27
Trichlorofluoromethane
4.7 U
58
39.6
68*
59
41.3
70*
4
73-145/31
1,2,3-Trichloropropane
4.7 U
58
34.2
59*
59
36.5
62*
7
74-127/27
1,2,4-Trimethylbenzene
4.7 U
58
23.9
41*
59
26.2
44*
9
74-123/34
1,3,5-Trimethylbenzene
4.7 U
58
24.5
42*
59
26.9
46*
9
73-122/33
Vinyl Acetate
24 U
290
ND
0*
295
ND
0*
nc
48-164/37
Vinyl Chloride
4.7 U
58
42.1
73*
59
42.7
72*
1
76-141/27
m,p-Xylene
9.5 U
116
58.8
51*
118
65.1
55*
10
80-128/30
o-Xylene
4.7 U
58
29.5
51*
59
32.1
54*
8
80-132/30
Xylene (total)
14 U
174
88.3
51*
177
97.2
55*
10
80-129/30
Surrogate Recoveries MS
1868-53-7 Dibromofluoromethane 90%
17060-07-0 1,2-Dichloroethane-D4 116%
2037-26-5 Toluene-138 110%
* = Outside of Control Limits.
MSD FA98779-1 Limits
89% 93% 75-124%
118% 121% 72-135%
113% 116% 75-126%
SGS79 of 99
FA98838

Matrix Spike/Matrix Spike Duplicate Summary Page 3 of 3
Job Number: FA98838
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
FA98779-lMS
170104670.1)
1
09/14/22
DB
n/a
n/a
VF3752
FA98779-1MSD
170104671.1)
1
09/14/22
DB
n/a
n/a
VF3752
FA98779-1
170104651.1)
1
09/14/22
DB
n/a
n/a
VF3752
The QC reported here applies to the following samples: Method: SW846 8260D
FA98838-1, FA98838-2, FA98838-5, FA98838-6, FA98838-9, FA98838-10, FA98838-13, FA98838-15
CAS No. Surrogate Recoveries
460-00-4 4-Bromofluorobenzene
* = Outside of Control Limits.
MS MSD FA98779-1 Limits
102% 100% 107% 71-133%
aSGV 80 of 99
FA98838

Orlando, FL
MS Semi-volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Section 6
0
SGS81 of 99
FA98838

Method Blank Summary
Job Number: FA98838
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 2
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
OP93050-MB
X083985.13
1
09/15/22
KA
09/14/22
OP93050
SX3330
The QC reported here applies to the following samples: Method: SW846 8270E
FA98838-3, FA98838-4, FA98838-7, FA98838-8, FA98838-11, FA98838-12, FA98838-13, FA98838-14
CAS No. Compound
Result RL MDL Units Q
65-85-0
Benzoic Acid
ND
830
170
ug/kg
59-50-7
4-Chloro-3-methyl Phenol
ND
170
19
ug/kg
95-57-8
2-Chlorophenol
ND
170
20
ug/kg
120-83-2
2,4-Dichlorophenol
ND
170
19
ug/kg
105-67-9
2,4-Dimethylphenol
ND
170
44
ug/kg
51-28-5
2,4-Dinitrophenol
ND
830
170
ug/kg
534-52-1
4,6-Dinitro-o-cresol
ND
330
67
ug/kg
95-48-7
2-Methylphenol
ND
170
20
ug/kg
3&4-Methylphenol
ND
170
27
ug/kg
88-75-5
2-Nitrophenol
ND
170
18
ug/kg
100-02-7
4-Nitrophenol
ND
830
170
ug/kg
87-86-5
Pentachlorophenol
ND
830
170
ug/kg
108-95-2
Phenol
ND
170
17
ug/kg
88-06-2
2,4,6-Trichlorophenol
ND
170
19
ug/kg
83-32-9
Acenaphthene
ND
170
18
ug/kg
208-96-8
Acenaphthylene
ND
170
17
ug/kg
120-12-7
Anthracene
ND
170
19
ug/kg
56-55-3
Benzo(a)anthracene
ND
170
17
ug/kg
50-32-8
Benzo(a)pyrene
ND
170
20
ug/kg
205-99-2
Benzo(b)fluoranthene
ND
170
18
ug/kg
191-24-2
Benzo(g, h, i)perylene
ND
170
17
ug/kg
207-08-9
Benzo(k)fluoranthene
ND
170
22
ug/kg
100-51-6
Benzyl Alcohol
ND
170
17
ug/kg
101-55-3
4-Bromophenyl phenyl ether
ND
170
17
ug/kg
85-68-7
Butyl benzyl phthalate
ND
170
33
ug/kg
106-47-8
4-Chloroaniline
ND
170
42
ug/kg
111-91-1
bis(2-Chloroethoxy)methane
ND
170
17
ug/kg
111-44-4
bis(2-Chloroethyl)ether
ND
170
19
ug/kg
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
170
21
ug/kg
91-58-7
2-Chloronaphthalene
ND
170
17
ug/kg
7005-72-3
4-Chlorophenyl phenyl ether
ND
170
17
ug/kg
218-01-9
Chrysene
ND
170
17
ug/kg
53-70-3
Dibenzo(a,h)anthracene
ND
170
21
ug/kg
132-64-9
Dibenzofuran
ND
170
17
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
170
17
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
170
18
ug/kg
SGS82 of 99
FA98838

Method Blank Summary
Job Number: FA98838
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 2 of 2
ample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
)P93050-MB
X083985.13
1
09/15/22
KA
09/14/22
OP93050
SX3330
The QC reported here applies to the following samples: Method: SW846 8270E
FA98838-3, FA98838-4, FA98838-7, FA98838-8, FA98838-11, FA98838-12, FA98838-13, FA98838-14
CAS No. Compound
106-46-7
1,4-Dichlorobenzene
91-94-1
3, 3'-Dichlorobenzidine
84-66-2
Diethyl Phthalate
131-11-3
Dimethyl Phthalate
117-84-0
Di-n-octyl Phthalate
84-74-2
Di-n-butyl Phthalate
122-66-7
1, 2-Diphenylhydrazine
117-81-7
bis(2-Ethylhexyl)phthalate
206-44-0
Fluoranthene
86-73-7
Fluorene
118-74-1
Hexachlorobenzene
87-68-3
Hexachlorobutadiene
77-47-4
Hexachlorocyclopentadiene
67-72-1
Hexachloroethane
193-39-5
Indeno(1,2,3-cd)pyrene
78-59-1
Isophorone
90-12-0
1-Methylnaphthalene
91-57-6
2-Methylnaphthalene
91-20-3
Naphthalene
98-95-3
Nitrobenzene
621-64-7
N-Nitrosodi-n-propylamine
86-30-6
N-Nitrosodiphenylamine
85-01-8
Phenanthrene
129-00-0
Pyrene
120-82-1
1,2,4-Trichlorobenzene
CAS No. Surrogate Recoveries
367-12-4 2-Fluorophenol
4165-62-2 Phenol-d5
118-79-6 2,4,6-Tribromophenol
4165-60-0 Nitrobenzene-d5
321-60-8 2-Fluorobiphenyl
1718-51-0 Terphenyl-d14
Result
RL
MDL
Units Q
ND
170
22
ug/kg
ND
170
40
ug/kg
ND
330
33
ug/kg
ND
170
33
ug/kg
ND
170
33
ug/kg
ND
330
67
ug/kg
ND
170
17
ug/kg
ND
330
33
ug/kg
ND
170
17
ug/kg
ND
170
18
ug/kg
ND
170
17
ug/kg
ND
170
17
ug/kg
ND
170
33
ug/kg
ND
170
20
ug/kg
ND
170
20
ug/kg
ND
170
17
ug/kg
ND
170
17
ug/kg
ND
170
17
ug/kg
ND
170
17
ug/kg
ND
170
17
ug/kg
ND
170
17
ug/kg
ND
170
18
ug/kg
ND
170
17
ug/kg
ND
170
19
ug/kg
ND
170
20
ug/kg
Limits
83%
40-102%
87%
41-100%
51%
42-108%
73%
40-105%
77%
43-107%
101%
45-119%
.SG`
83 of 99
FA98838

Blank Spike Summary
Job Number: FA98838
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 2
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
OP93050-BS
X083984.13
1
09/15/22
KA
09/14/22
OP93050
SX3330
The QC reported here applies to the following samples: Method: SW846 8270E
FA98838-3, FA98838-4, FA98838-7, FA98838-8, FA98838-11, FA98838-12, FA98838-13, FA98838-14
CAS No. Compound
Spike BSP BSP
ug/kg ug/kg % Limits
65-85-0
Benzoic Acid
3330
3230
97
36-118
59-50-7
4-Chloro-3-methyl Phenol
1670
1520
91
52-108
95-57-8
2-Chlorophenol
1670
1340
80
48-104
120-83-2
2,4-Dichlorophenol
1670
1400
84
51-105
105-67-9
2,4-Dimethylphenol
1670
1320
79
43-96
51-28-5
2,4-Dinitrophenol
3330
2940
88
40-119
534-52-1
4,6-Dinitro-o-cresol
3330
3190
96
64-121
95-48-7
2-Methylphenol
1670
1340
80
46-107
3&4-Methylphenol
3330
2870
86
44-111
88-75-5
2-Nitrophenol
1670
1340
80
49-104
100-02-7
4-Nitrophenol
3330
3210
96
56-116
87-86-5
Pentachlorophenol
3330
2680
80
61-114
108-95-2
Phenol
1670
1330
80
45-110
88-06-2
2,4,6-Trichlorophenol
1670
1490
89
56-109
83-32-9
Acenaphthene
1670
1380
83
56-109
208-96-8
Acenaphthylene
1670
1410
85
56-106
120-12-7
Anthracene
1670
1350
81
61-110
56-55-3
Benzo(a)anthracene
1670
1800
108
66-111
50-32-8
Benzo(a)pyrene
1670
1580
95
59-104
205-99-2
Benzo(b)fluoranthene
1670
1570
94
67-113
191-24-2
Benzo(g, h, i)perylene
1670
1610
97
67-113
207-08-9
Benzo(k)fluoranthene
1670
1580
95
67-114
100-51-6
Benzyl Alcohol
1670
1350
81
53-108
101-55-3
4-Bromophenyl phenyl ether
1670
1350
81
62-110
85-68-7
Butyl benzyl phthalate
1670
1910
115*
65-113
106-47-8
4-Chloroaniline
1670
1260
76
30-115
111-91-1
bis(2-Chloroethoxy)methane
1670
1370
82
48-105
111-44-4
bis(2-Chloroethyl)ether
1670
1240
74
46-103
108-60-1
2,2'-Oxybis(1-chloropropane)
1670
1250
75
40-110
91-58-7
2-Chloronaphthalene
1670
1360
82
53-106
7005-72-3
4-Chlorophenyl phenyl ether
1670
1390
83
58-106
218-01-9
Chrysene
1670
1780
107
65-112
53-70-3
Dibenzo(a,h)anthracene
1670
1620
97
68-115
132-64-9
Dibenzofuran
1670
1390
83
57-108
95-50-1
1,2-Dichlorobenzene
1670
1220
73
44-102
541-73-1
1,3-Dichlorobenzene
1670
1180
71
42-100
* = Outside of Control Limits.
SGS84 of 99
FA98838

Blank Spike Summary
Job Number: FA98838
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 2 of 2
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
OP93050-BS
X083984.13
1
09/15/22
KA
09/14/22
OP93050
SX3330
The QC reported here applies to the following samples: Method: SW846 8270E
FA98838-3, FA98838-4, FA98838-7, FA98838-8, FA98838-11, FA98838-12, FA98838-13, FA98838-14
Spike BSP BSP
CAS No. Compound ug/kg ug/kg % Limits
106-46-7
1,4-Dichlorobenzene
1670
1160
70
40-106
91-94-1
3,3'-Dichlorobenzidine
1670
1560
94
36-114
84-66-2
Diethyl Phthalate
1670
1560
94
61-109
131-11-3
Dimethyl Phthalate
1670
1480
89
59-108
117-84-0
Di-n-octyl Phthalate
1670
2010
121*
64-119
84-74-2
Di-n-butyl Phthalate
1670
1630
98
63-108
122-66-7
1,2-Diphenylhydrazine
1670
1460
88
58-112
117-81-7
bis(2-Ethylhexyl)phthalate
1670
1840
110
64-115
206-44-0
Fluoranthene
1670
1530
92
60-108
86-73-7
Fluorene
1670
1440
86
58-109
118-74-1
Hexachlorobenzene
1670
1170
70
59-111
87-68-3
Hexachlorobutadiene
1670
1210
73
41-108
77-47-4
Hexachlorocyclopentadiene
1670
1280
77
49-110
67-72-1
Hexachloroethane
1670
1250
75
40-105
193-39-5
Indeno(1,2,3-cd)pyrene
1670
1810
109
66-116
78-59-1
Isophorone
1670
1320
79
42-89
90-12-0
1-Methylnaphthalene
1670
1390
83
49-106
91-57-6
2-Methylnaphthalene
1670
1390
83
47-106
91-20-3
Naphthalene
1670
1310
79
44-104
98-95-3
Nitrobenzene
1670
1320
79
43-108
621-64-7
N-Nitrosodi-n-propylamine
1670
1290
77
48-108
86-30-6
N-Nitrosodiphenylamine
1670
1410
85
62-110
85-01-8
Phenanthrene
1670
1440
86
63-111
129-00-0
Pyrene
1670
1770
106
65-115
120-82-1
1,2,4-Trichlorobenzene
1670
1270
76
45-100
CAS No.
Surrogate Recoveries
BSP
Limits
367-12-4
2-Fluorophenol
75%
40-102%
4165-62-2
Phenol-d5
77%
41-100%
118-79-6
2,4,6-Tribromophenol
62%
42-108%
4165-60-0
Nitrobenzene-d5
71%
40-105%
321-60-8
2-Fluorobiphenyl
73%
43-107%
1718-51-0
Terphenyl-d14
93%
45-119%
* = Outside of Control Limits.
GS85 of 99
FA98838

Matrix Spike/Matrix Spike Duplicate Summary
Job Number: FA98838
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 2
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
OP93050-MS
X084005.13
1
09/15/22
KA
09/14/22
OP93050
SX3330
OP93050-MSD
X084006.13
1
09/15/22
KA
09/14/22
OP93050
SX3330
FA98870-2
X083986.13
1
09/15/22
KA
09/14/22
OP93050
SX3330
The QC reported here applies to the following samples:
Method: SW846 8270E
FA98838-3, FA98838-4, FA98838-7, FA98838-8, FA98838-11, FA98838-12, FA98838-13, FA98838-14
FA98870-2
Spike
MS
MS
Spike
MSD
MSD
Limits
CAS No.
Compound
ug/kg Q
ug/kg
ug/kg
%
ug/kg
ug/kg
%
RPD
Rec/RPD
65-85-0
Benzoic Acid
980 U
3940
3830
97
3940
4030
102
5
36-118/41
59-50-7
4-Chloro-3-methyl Phenol
200 U
1970
1620
82
1970
1690
86
4
52-108/21
95-57-8
2-Chlorophenol
200 U
1970
1450
74
1970
1510
77
4
48-104/26
120-83-2
2,4-Dichlorophenol
200 U
1970
1570
80
1970
1650
84
5
51-105/27
105-67-9
2,4-Dimethylphenol
200 U
1970
1380
70
1970
1480
75
7
43-96/23
51-28-5
2,4-Dinitrophenol
980 U
3940
2490
63
3940
2680
68
7
40-119/32
534-52-1
4,6-Dinitro-o-cresol
390 U
3940
2940
75
3940
3160
80
7
64-121/29
95-48-7
2-Methylphenol
200 U
1970
1350
69
1970
1420
72
5
46-107/24
3&4-Methylphenol
200 U
3940
2880
73
3940
3080
78
7
44-111/24
88-75-5
2-Nitrophenol
200 U
1970
1470
75
1970
1570
80
7
49-104/27
100-02-7
4-Nitrophenol
980 U
3940
3460
88
3940
3710
94
7
56-116/23
87-86-5
Pentachlorophenol
980 U
3940
3380
86
3940
3520
89
4
61-114/23
108-95-2
Phenol
200 U
1970
1330
68
1970
1410
72
6
45-110/24
88-06-2
2,4,6-Trichlorophenol
200 U
1970
1690
86
1970
1820
92
7
56-109/25
83-32-9
Acenaphthene
200 U
1970
1430
73
1970
1540
78
7
56-109/23
208-96-8
Acenaphthylene
200 U
1970
1490
76
1970
1580
80
6
56-106/23
120-12-7
Anthracene
200 U
1970
1430
73
1970
1510
77
5
61-110/21
56-55-3
Benzo(a)anthracene
200 U
1970
1870
95
1970
1990
101
6
66-111/23
50-32-8
Benzo(a)pyrene
200 U
1970
1750
89
1970
1860
95
6
59-104/23
205-99-2
Benzo(b)fluoranthene
200 U
1970
1760
89
1970
1880
96
7
67-113/24
191-24-2
Benzo(g, h, i)perylene
200 U
1970
1780
90
1970
1890
96
6
67-113/21
207-08-9
Benzo(k)fluoranthene
200 U
1970
1540
78
1970
1650
84
7
67-114/22
100-51-6
Benzyl Alcohol
200 U
1970
1370
70
1970
1450
74
6
53-108/24
101-55-3
4-Bromophenyl phenyl ether
200 U
1970
1530
78
1970
1600
81
4
62-110/21
85-68-7
Butyl benzyl phthalate
200 U
1970
2060
105
1970
2150
109
4
65-113/20
106-47-8
4-Chloroaniline
200 U
1970
1290
66
1970
1370
70
6
30-115/30
111-91-1
bis(2-Chloroethoxy)methane
200 U
1970
1360
69
1970
1430
73
5
48-105/24
111-44-4
bis(2-Chloroethyl)ether
200 U
1970
1270
65
1970
1340
68
5
46-103/27
108-60-1
2,2'-Oxybis(1-chloropropane)
200 U
1970
1030
52
1970
1090
55
6
40-110/25
91-58-7
2-Chloronaphthalene
200 U
1970
1420
72
1970
1530
78
7
53-106/23
7005-72-3
4-Chlorophenyl phenyl ether
200 U
1970
1570
80
1970
1670
85
6
58-106/21
218-01-9
Chrysene
200 U
1970
1790
91
1970
1880
96
5
65-112/25
53-70-3
Dibenzo(a,h)anthracene
200 U
1970
1950
99
1970
2050
104
5
68-115/23
132-64-9
Dibenzofuran
200 U
1970
1490
76
1970
1590
81
6
57-108/22
95-50-1
1,2-Dichlorobenzene
200 U
1970
1370
70
1970
1430
73
4
44-102/28
541-73-1
1, 3 -Dichlorobenzene
200 U
1970
1370
70
1970
1430
73
4
42-100/30
* = Outside of Control Limits.
.SG`
86 of 99
FA98838

Matrix Spike/Matrix Spike Duplicate Summary
Job Number: FA98838
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 2 of 2
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
OP93050-MS
X084005.13
1
09/15/22
KA
09/14/22
OP93050
SX3330
OP93050-MSD
X084006.13
1
09/15/22
KA
09/14/22
OP93050
SX3330
FA98870-2
X083986.13
1
09/15/22
KA
09/14/22
OP93050
SX3330
The QC reported here applies to the following samples:
Method: SW846 8270E
FA98838-3, FA98838-4, FA98838-7, FA98838-8, FA98838-11, FA98838-12, FA98838-13, FA98838-14
FA98870-2
Spike
MS
MS
Spike
MSD
MSD
Limits
CAS No.
Compound
ug/kg Q
ug/kg
ug/kg
%
ug/kg
ug/kg
%
RPD
Rec/RPD
106-46-7
1,4-Dichlorobenzene
200 U
1970
1330
68
1970
1390
71
4
40-106/29
91-94-1
3,3'-Dichlorobenzidine
200 U
1970
1900
97
1970
1990
101
5
36-114/28
84-66-2
Diethyl Phthalate
390 U
1970
1650
84
1970
1800
91
9
61-109/20
131-11-3
Dimethyl Phthalate
200 U
1970
1580
80
1970
1670
85
6
59-108/20
117-84-0
Di-n-octyl Phthalate
200 U
1970
2440
124*
1970
2570
131*
5
64-119/21
84-74-2
Di-n-butyl Phthalate
390 U
1970
1750
89
1970
1840
94
5
63-108/19
122-66-7
1,2-Diphenylhydrazine
200 U
1970
1280
65
1970
1360
69
6
58-112/22
117-81-7
bis(2-Ethylhexyl)phthalate
390 U
1970
2120
108
1970
2200
112
4
64-115/23
206-44-0
Fluoranthene
200 U
1970
1620
82
1970
1690
86
4
60-108/25
86-73-7
Fluorene
200 U
1970
1560
79
1970
1650
84
6
58-109/21
118-74-1
Hexachlorobenzene
200 U
1970
1350
69
1970
1430
73
6
59-111/21
87-68-3
Hexachlorobutadiene
200 U
1970
1460
74
1970
1540
78
5
41-108/27
77-47-4
Hexachlorocyclopentadiene
200 U
1970
1090
55
1970
1170
59
7
49-110/31
67-72-1
Hexachloroethane
200 U
1970
1310
67
1970
1380
70
5
40-105/32
193-39-5
Indeno(1,2,3-cd)pyrene
200 U
1970
2430
123*
1970
2530
129*
4
66-116/22
78-59-1
Isophorone
200 U
1970
1260
64
1970
1340
68
6
42-89/22
90-12-0
1-Methylnaphthalene
200 U
1970
1540
78
1970
1600
81
4
49-106/26
91-57-6
2-Methylnaphthalene
200 U
1970
1550
79
1970
1620
82
4
47-106/27
91-20-3
Naphthalene
200 U
1970
1420
72
1970
1470
75
3
44-104/27
98-95-3
Nitrobenzene
200 U
1970
1260
64
1970
1300
66
3
43-108/25
621-64-7
N-Nitrosodi-n-propylamine
200 U
1970
1170
59
1970
1230
63
5
48-108/27
86-30-6
N-Nitrosodiphenylamine
200 U
1970
1480
75
1970
1590
81
7
62-110/21
85-01-8
Phenanthrene
200 U
1970
1470
75
1970
1580
80
7
63-111/22
129-00-0
Pyrene
200 U
1970
1750
89
1970
1870
95
7
65-115/25
120-82-1
1,2,4-Trichlorobenzene
200 U
1970
1490
76
1970
1570
80
5
45-100/26
CAS No.
Surrogate Recoveries
MS
MSD
FA98870-2
Limits
367-12-4
2-Fluorophenol
67%
71%
82%
40-102%
4165-62-2
Phenol-d5
68%
73%
87%
41-100%
118-79-6
2,4,6-Tribromophenol
68%
74%
55%
42-108%
4165-60-0
Nitrobenzene-d5
57%
62%
74%
40-105%
321-60-8
2-Fluorobiphenyl
67%
73%
76%
43-107%
1718-51-0
Terphenyl-d14
86%
92%
101%
45-119%
* = Outside of Control Limits.
GS87 of 99
FA98838

Orlando, FL ,I
Metals Analysis
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Matrix Spike and Duplicate Summaries
• Blank Spike and Lab Control Sample Summaries
• Serial Dilution Summaries
Section 7
SGS88 of 99
FA98838

BLANK RESULTS SUMMARY
Part 2 - Method Blanks
Login Number: FA98838
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41212 Methods: SW846 7471B
Matrix Type: SOLID Units: mg/kg
Prep Date:
MB
letal RL IDL MDL raw final
Mercury 0.042 .0025 .0042-0.00033 <0.042
Associated samples MP41212: FA98838-3, FA98838-4, FA98838-7, FA98838-8, FA98838-11, FA98838-12, FA98838-
13, FA98838-14
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
V
i
Page 1
.SG`
89 of 99
FA98838

MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA98838
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41212 Methods: SW846 7471B
Matrix Type: SOLID Units: mg/kg
Prep Date:
FA98781-1A QC FA98781-1A Spikelot QC
letal Original DUP RPD Limits Original MS HGFLWSI % Rec Limits
Mercury 0.028 0.028 0.0 0-20 0.028 0.25 0.225 98.7 80-120
Associated samples MP41212: FA98838-3, FA98838-4, FA98838-7, FA98838-8, FA98838-11, FA98838-12, FA98838-
13, FA98838-14
V
Results < IDL are shown as zero for calculation purposes j
(*) Outside of QC limits
N
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
Page 1
.SG`
90 of 99
FA98838

MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA98838
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41212 Methods: SW846 7471B
Matrix Type: SOLID Units: mg/kg
Prep Date:
FA98781-1A Spikelot MSD QC
letal Original MSD HGFLWSI % Rec RPD Limit
Mercury 0.028 0.27 0.242 99.9 7.7 20
Associated samples MP41212: FA98838-3, FA98838-4, FA98838-7, FA98838-8, FA98838-11, FA98838-12, FA98838-
13, FA98838-14
V
Results < IDL are shown as zero for calculation purposes y
(*) Outside of QC limits
N
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
Page 2
.SG`
91 of 99
FA98838

SPIKE BLANK AND LAB CONTROL SAMPLE SUMMARY
Login Number: FA98838
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41212 Methods: SW846 7471B
Matrix Type: SOLID Units: mg/kg
Prep Date:
BSP Spikelot QC
letal Result HGFLWSI o Rec Limits
Mercury 0.25 0.25 100.0 80-120
Associated samples MP41212: FA98838-3, FA98838-4, FA98838-7, FA98838-8, FA98838-11, FA98838-12, FA98838-
13, FA98838-14
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
V
i
W
Page 1
GS- 92 of 99
FA98838

SERIAL DILUTION RESULTS SUMMARY
Login Number: FA98838
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41212 Methods: SW846 7471B
Matrix Type: SOLID Units: ug/l
Prep Date:
FA98781-1A QC
letal Original SDL 1:5 oDIF Limits
Mercury 0.330 0.00 100.0(a) 0-10
Associated samples MP41212: FA98838-3, FA98838-4, FA98838-7, FA98838-8, FA98838-11, FA98838-12, FA98838-
13, FA98838-14
V
Results < IDL are shown as zero for calculation purposes j
(*) Outside of QC limits
(anr) Analyte not requested
(a) Percent difference acceptable due to low initial sample concentration (< 50 times IDL).
Page 1
.SG`
93 of 99
FA98838

BLANK RESULTS SUMMARY
Part 2 - Method Blanks
Login Number: FA98838
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41216 Methods: SW846 6010D
Matrix Type: SOLID Units: mg/kg
Prep Date:
MB
letal RL IDL MDL raw final
Aluminum 10 .7 1.8
Antimony 1.0 .05 .065
Arsenic 0.50 .065 .1 -0.020 <0.50
Barium 10 .025 .05 0.050 <10
Beryllium 0.25 .005 .025
Cadmium 0.20 .005 .025-0.0050 <0.20
Calcium 250 2.5 2.5
Chromium 0.50 .025 .05 0.015 <0.50
Cobalt 2.5 .01 .025
Copper 1.3 .05 .05
Iron 15 .75 .85
Lead 1.0 .05 .05 0.010 <1.0
Magnesium 250 1.8 1.8
Manganese 0.75 .013 .025
Molybdenum 2.5 .015 .025
Nickel 2.0 .02 .025
Potassium 500 5 10
Selenium 1.0 .1 .12 0.010 <1.0
Silver 0.50 .025 .041 -0.035 <0.50
Sodium 500 13 25
Strontium 0.50 .013 .025
Thallium 0.50 .05 .055
Tin 2.5 .025 .045
Titanium 0.50 .025 .025
Vanadium 2.5 .025 .025
Zinc 1.0 .15 .15
Associated samples MP41216: FA98838-3, FA98838-4, FA98838-7, FA98838-8, FA98838-11, FA98838-12, FA98838-
13, FA98838-14
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
V
N
Page 1
.SG`
94 of 99
FA98838

MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA98838
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41216 Methods: SW846 6010D
Matrix Type: SOLID Units: mg/kg
Prep Date:
FA98823-1 QC FA98823-1 Spikelot QC
letal Original DUP RPD Limits Original MS MPFLICP2 % Rec Limits
Aluminum
Antimony am
Arsenic 4.5 4.8 (a) 6.5 0-20 4.5 86.6 (a) 97.1 84.5 80-120
Barium 119 114 (a) 4.3 0-20 119 209 (a) 97.1 92.6 80-120
Beryllium am
Cadmium 0.0 0.0 (a) NC 0-20 0.0 1.6 (a) 2.43 65.9N(c) 80-120
Calcium
Chromium 32.1 32.7 (a) 1.9 0-20 32.1 42.3 (a) 9.71 105.0 80-120
Cobalt am
Copper am
Iron
Lead 5.1 5.0 (a) 2.0 0-20 5.1 28.0 (a) 24.3 94.3 80-120
Magnesium
Manganese
Molybdenum am
Nickel am
Potassium
Selenium 0.76 0.60 (a) 23.5 (b) 0-20 0.76 84.2 (a) 97.1 85.9 80-120
Silver 0.0 0.0 (a) NC 0-20 0.0 2.0 (a) 2.43 82.4 80-120
Sodium
Strontium
Thallium am
Tin
Titanium
Vanadium am
Zinc am
Associated samples MP41216: FA98838-3, FA98838-4, FA98838-7, FA98838-8, FA98838-11, FA98838-12, FA98838-
13, FA98838-14
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
(a) Sample dilution required due to difficult matrix.
(b) RPD acceptable due to low duplicate and sample concentrations.
(c) Spike recovery indicates possible matrix interference and/or sample non -homogeneity.
V
N
N
Page 1
.SG`
95 of 99
FA98838

MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA98838
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41216 Methods: SW846 6010D
Matrix Type: SOLID Units: mg/kg
Prep Date:
FA98823-1 Spikelot MSD QC
letal Original MSD MPFLICP2 % Rec RPD Limit
Aluminum
Antimony am
Arsenic 4.5 87.2 (a) 105 79.1N(b) 0.7 20
Barium 119 206 (a) 105 83.2 1.4 20
Beryllium am
Cadmium 0.0 1.6 (a) 2.61 61.2N(b) 0.0 20
Calcium
Chromium 32.1 43.7 (a) 10.5 111.0 3.3 20
Cobalt am
Copper am
Iron
Lead 5.1 28.2 (a) 26.1 88.4 0.7 20
Magnesium
Manganese
Molybdenum am
Nickel am
Potassium
Selenium 0.76 85.3 (a) 105 80.9 1.3 20
Silver 0.0 2.0 (a) 2.61 76.5N(b) 0.0 20
Sodium
Strontium
Thallium am
Tin
Titanium
Vanadium am
Zinc am
Associated samples MP41216: FA98838-3, FA98838-4, FA98838-7, FA98838-8, FA98838-11, FA98838-12, FA98838-
13, FA98838-14
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
(a) Sample dilution required due to difficult matrix.
(b) Spike recovery indicates possible matrix interference and/or sample non -homogeneity.
V
N
N
Page 2
.SG`
96 of 99
FA98838

SPIKE BLANK AND LAB CONTROL SAMPLE SUMMARY
Login Number: FA98838
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41216 Methods: SW846 6010D
Matrix Type: SOLID Units: mg/kg
Prep Date:
BSP Spikelot QC
letal Result MPFLICP2 % Rec Limits
Aluminum
Antimony am
Arsenic 91.2 100 91.2 80-120
Barium 95.5 100 95.5 80-120
Beryllium am
Cadmium 2.4 2.5 96.0 80-120
Calcium
Chromium 10.3 10 103.0 80-120
Cobalt am
Copper am
Iron
Lead 22.8 25 91.2 80-120
Magnesium
Manganese
Molybdenum am
Nickel am
Potassium
Selenium 92.2 100 92.2 80-120
Silver 2.1 2.5 84.0 80-120
Sodium
Strontium
Thallium am
Tin
Titanium
Vanadium am
Zinc am
Associated samples MP41216: FA98838-3, FA98838-4, FA98838-7, FA98838-8, FA98838-11, FA98838-12, FA98838-
13, FA98838-14
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
V
N
W
Page 1
GS- 97 of 99
FA98838

SERIAL DILUTION RESULTS SUMMARY
Login Number: FA98838
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41216 Methods: SW846 6010D
Matrix Type: SOLID Units: ug/l
Prep Date:
FA98823-1 QC
letal Original SDL 5:25 %DIF Limits
Aluminum
Antimony am
Arsenic 86.3 102 18.4 (a) 0-10
Barium 2310 2430 5.5 0-10
Beryllium am
Cadmium 0.00 0.00 NC 0-10
Calcium
Chromium 619 658 6.2 0-10
Cobalt am
Copper am
Iron
Lead 99.0 76.4 22.8 (a) 0-10
Magnesium
Manganese
Molybdenum am
Nickel am
Potassium
Selenium 14.7 0.00 100.0(a) 0-10
Silver 0.00 0.00 NC 0-10
Sodium
Strontium
Thallium am
Tin
Titanium
Vanadium am
Zinc am
Associated samples MP41216: FA98838-3, FA98838-4, FA98838-7, FA98838-8, FA98838-11, FA98838-12, FA98838-
13, FA98838-14
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
(a) Percent difference acceptable due to low initial sample concentration (< 50 times IDL).
V
N
Page 1
.SG`
98 of 99
FA98838

POST DIGESTATE SPIKE SUMMARY
Login Number: FA98838
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41216 Methods: SW846 6010D
Matrix Type: SOLID Units: ug/l
Prep Date:
Sample Final FA98823-1 PS Spike Spike Spike QC
Metal ml ml Raw Corr.** ug/l ml ug/ml ug/l % Rec Limits
Aluminum
Antimony
Arsenic
9.8
10
86.3 84.574
177
0.2
5
100
92.4
80-120
Barium
9.8
10
2305 2258.9
2554
0.2
12.5
250
118.0
80-120
Beryllium
Cadmium
9.8
10
34.7
0.2
2.5
50
69.4*(a)
80-120
Calcium
Chromium
9.8
10
619.4 607.012
680.4
0.2
2.5
50
146.8*(a
80-120
Cobalt
Copper
Iron
Lead
9.8
10
99 97.02
142.6
0.2
2.5
50
91.2
80-120
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
9.8
10
14.7 14.406
97.9
0.2
5
100
83.5
80-120
Silver
9.8
10
43.7
0.2
2.5
50
87.4
80-120
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated
samples
MP41216:
FA98838-3, FA98838-4,
FA98838-7,
FA98838-8,
FA98838-11,
FA98838-12,
FA98838-
13, FA98838-14
Results < IDL
are shown
as zero
for calculation purposes
(*) Outside
of QC limits
(**) Corr.
sample
result =
Raw * (sample volume
/ final
volume)
(anr) Analyte
not requested
(a) Spike recovery
indicates
matrix interference
and/or
outside
control limits
due
to high level
in
sample
relative
to spike
amount.
V
N
N
Page 1
SGS99 of 99
FA98838

Orlando, FL
The results set forth herein are provided by SGS North America Inc. a-Hl ydcopy 2. 0
Automated Report
Technical Report for
Geosyntec Consultants
PPD; Harnett St, Wilmington, NC
SGS Job Number: FA98839
Sampling Date: 09/09/22
Report to:
Geosyntec Consultants
314 Walnut St Suite 200
Wilmington, NC 28401
[e-mail]
ATTN: Abby Wesley
Total number of pages in report: 122
P2
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Norm Farmer
Technical Director
Client Service contact: Kelly Blanchard 407-425-6700
Certifications: FL(E83510), LA(03051), KS(E-10327), NC(573), NJ(FL002), NY(12022), SC(96038001)
DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177),
AL, AK, AR, CT, IA, KY, MA, MI. MS, ND, NH, NV, OK, OR, IL, UT, VT, WA, WI, WV
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc. • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: [phone] • fax: [phone]
SGS is the sole authority for authorizing edits or modifications to this document. Please share your ideas about
Unauthorized modification of this report is strictly prohibited. how we can serve you better at: SGS
Review standard terms at: http://www.sgs.com/en/terms-and-conditions [e-mail]
1 of 122
FA98839

Sections:
Table of Contents
-I-
Section1: Sample Summary...................................................................................................
3
Section2: Summary of Hits....................................................................................................
4
Section3: Sample Results........................................................................................................
6
3.1: FA98839-1: Z4-1-0-0.5.................................................................................................
7
3.2: FA98839-2: Z4-2-1.5-2.................................................................................................
10
3.3: FA98839-3: Z4-0-0.5....................................................................................................
13
3.4: FA98839-4: Z4-0.5-2....................................................................................................
17
3.5: FA98839-5: Z6-5-1-1.5.................................................................................................
21
3.6: FA98839-6: Z6-0-2.......................................................................................................
24
3.7: FA98839-7: DUP-20220909.........................................................................................
28
3.8: FA98839-8: DRUM......................................................................................................
35
Section4: Misc. Forms............................................................................................................
42
4.1: Chain of Custody...........................................................................................................
43
Section 5: MS Volatiles - QC Data Summaries.....................................................................
47
5.1: Method Blank Summary................................................................................................
48
5.2: Blank Spike Summary...................................................................................................
58
5.3: Matrix Spike Summary..................................................................................................
68
5.4: Matrix Spike/Matrix Spike Duplicate Summary...........................................................
71
Section 6: MS Semi-volatiles - QC Data Summaries............................................................
78
6.1: Method Blank Summary................................................................................................
79
6.2: Blank Spike Summary...................................................................................................
85
6.3: Matrix Spike/Matrix Spike Duplicate Summary...........................................................
91
Section7: Metals Analysis - QC Data Summaries................................................................
95
7.1: Prep QC MP41212: Hg..................................................................................................
96
7.2: Prep QC MP41213: Hg..................................................................................................
101
7.3: Prep QC MP41214: As,Ba,Cd,Cr,Pb,Se,Ag..................................................................
106
7.4: Prep QC MP41216: As,Ba,Cd,Cr,Pb,Se,Ag..................................................................
112
7.5: Prep QC MP41233: Hg..................................................................................................
118
SGS2 of 122
FA98839

SGS North America Inc.
Sample Summary
Geosyntec Consultants
PPD; Harnett St, Wilmington, NC
Job No: FA98839
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
This report contains results reported as ND = Not detected. The following applies:
Organics ND = Not detected above the MDL
FA98839-1
09/09/22
11:00 AW
09/10/22
SO
Soil
Z4-1-0-0.5
FA98839-2
09/09/22
11:30 AW
09/10/22
SO
Soil
Z4-2-1.5-2
FA98839-3
09/09/22
11:30 AW
09/10/22
SO
Soil
Z4-0-0.5
FA98839-4
09/09/22
11:30 AW
09/10/22
SO
Soil
Z4-0.5-2
FA98839-5
09/09/22
13:00 AW
09/10/22
SO
Soil
Z6-5-1-1.5
FA98839-6
09/09/22
13:00 AW
09/10/22
SO
Soil
Z6-0-2
FA98839-7
09/09/22
13:00 AW
09/10/22
SO
Soil
DUP-20220909
FA98839-8
09/09/22
14:30 AW
09/10/22
AQ
Water
DRUM
Soil samples reported on a dry weight basis unless otherwise indicated on result page.
SGS3 of 122
FA98839

Summary of Hits
Job Number:
FA98839
Account:
Geosyntec Consultants
Project:
PPD; Harnett St, Wilmington, NC
Collected:
09/09/22
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA98839-1 Z4-1-0-0.5
No hits reported in this sample.
FA98839-2 Z4-2-1.5-2
n-Butylbenzene a
715
370
75
ug/kg
SW846 8260D
sec-Butylbenzene a
1020
370
75
ug/kg
SW846 8260D
Isopropylbenzene a
269 J
370
75
ug/kg
SW846 8260D
n-Propylbenzene a
448
370
75
ug/kg
SW846 8260D
FA98839-3 Z4-0-0.5
Benzo(a)anthracene
43.5 J
180
18
ug/kg
SW846 8270E
Benzo(a)pyrene
43.1 J
180
21
ug/kg
SW846 8270E
Benzo(b)fluoranthene
65.1 J
180
19
ug/kg
SW846 8270E
Benzo(g, h, i)perylene
25.8 J
180
18
ug/kg
SW846 8270E
Chrysene
45.1 J
180
18
ug/kg
SW846 8270E
bis(2-Ethylhexyl)phthalate
37.4 J
350
35
ug/kg
SW846 8270E
Fluoranthene
70.5 J
180
18
ug/kg
SW846 8270E
Indeno(1,2,3-cd)pyrene
59.4 J
180
22
ug/kg
SW846 8270E
Pyrene
62.7 J
180
20
ug/kg
SW846 8270E
Arsenic b
4.5
2.3
mg/kg
SW846 6010D
Chromium b
18.6
2.3
mg/kg
SW846 6010D
Lead b
5.7
4.6
mg/kg
SW846 6010D
FA98839-4 Z4-0.5-2
Acenaphthene
98.8 J
170
19
ug/kg
SW846 8270E
Anthracene
161 J
170
20
ug/kg
SW846 8270E
Fluoranthene
33.8 J
170
17
ug/kg
SW846 8270E
Fluorene
126 J
170
19
ug/kg
SW846 8270E
1-Methylnaphthalene
596
170
17
ug/kg
SW846 8270E
Pyrene
85.9 J
170
20
ug/kg
SW846 8270E
Arsenic
1.2
0.44
mg/kg
SW846 6010D
Chromium
5.1
0.44
mg/kg
SW846 6010D
Lead
23.0
0.88
mg/kg
SW846 6010D
FA98839-5 Z6-5-1-1.5
p-Isopropyltoluene 1.1 J 3.8 0.77 ug/kg SW846 8260D
FA98839-6 Z6-0-2
Benzo(a)anthracene 26.2 J 170 17 ug/kg SW846 8270E
Page 1 of 2
a1��GS 4 of 122
FA98839

Summary of Hits
Job Number:
FA98839
Account:
Geosyntec Consultants
Project:
PPD; Harnett St, Wilmington, NC
Collected:
09/09/22
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
Benzo(a)pyrene
24.8 J
170
20
ug/kg
SW846 8270E
Benzo(b)fluoranthene
32.8 J
170
18
ug/kg
SW846 8270E
Benzo(g, h, i)perylene
17.0 J
170
17
ug/kg
SW846 8270E
Chrysene
18.4 J
170
17
ug/kg
SW846 8270E
bis(2-Ethylhexyl)phthalate
44.4 J
330
33
ug/kg
SW846 8270E
Fluoranthene
30.9 J
170
17
ug/kg
SW846 8270E
Indeno(1,2,3-cd)pyrene
47.9 J
170
20
ug/kg
SW846 8270E
Pyrene
25.8 J
170
19
ug/kg
SW846 8270E
Arsenic
1.8
0.45
mg/kg
SW846 6010D
Barium
16.3
8.9
mg/kg
SW846 6010D
Chromium
4.4
0.45
mg/kg
SW846 6010D
Lead
27.2
0.89
mg/kg
SW846 6010D
Mercury
0.21
0.037
mg/kg
SW846 7471B
FA98839-7 DUP-20220909
Acetone
172
160
79
ug/kg
SW846 8260D
p-Isopropyltoluene
1.8 J
4.0
0.79
ug/kg
SW846 8260D
Benzo(b)fluoranthene
24.3 J
180
20
ug/kg
SW846 8270E
bis(2-Ethylhexyl)phthalate
59.9 J
370
37
ug/kg
SW846 8270E
Indeno(1,2,3-cd)pyrene
33.2 J
180
22
ug/kg
SW846 8270E
Arsenic
1.8
0.48
mg/kg
SW846 6010D
Barium
13.9
9.6
mg/kg
SW846 6010D
Chromium
4.0
0.48
mg/kg
SW846 6010D
Lead
24.9
0.96
mg/kg
SW846 6010D
Mercury
0.19
0.046
mg/kg
SW846 7471B
FA98839-8 DRUM
Acetone c
761
250
100 ug/l
SW846 8260D
2-Butanone (MEK) c
50.3
50
20 ug/l
SW846 8260D
Chromium
29.4
10
ug/1
SW846 6010D
Lead
101
5.0
ug/1
SW846 6010D
(a) Dilution required due to matrix interference (surrogate standard failure).
(b) Sample dilution required due to difficult matrix.
(c) Sample was treated with an anti -foaming agent. Dilution required due to matrix interference (surrogate
standard failure, sample foamed). Sample vial(s) contained significant headspace.
Page 2 of 2
GS5 of 122
FA98839

ffm
Dayton, NJ
The results set forth herein are provided by SGS North America Inc. a-Hl ydcopy 2. 0
Automated Report
Technical Report for
Geosyntec Consultants
PPD, Harnett Street, Wilmington, NC
SGS Job Number: JD51561
Sampling Date: 09/08/22
Report to:
Geosyntec Consultants
314 Walnut Street, Suite 200
Wilmington, NC 28401
Abby. Wesley@Geosyntec. com; Jack.Nolan@Geo
ATTN: Abigail Wesley
Total number of pages in report: 22
. com
Test results contained within this data package meet the requirements David Chastain
of the National Environmental Laboratory Accreditation Program General Manager
and/or state specific certification programs as applicable.
Client Service contact: Tammy McCloskey 732-329-0200
Certifications: NJ(12129), NY(10983), CA, CT, FL, IL, IN, KS, KY, LA, MA, MD, ME, MN, NC,
OH VAP (CL0056), AK(UST-103), AZ (AZ0786), PA(68-00408), RI, SC, TX, UT, VA, WV
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc. • 2235 Route 130 • Dayton, NJ 08810 • tel: [phone] • fax: [phone]
SGS is the sole authority for authorizing edits or modifications to this document. Please share your ideas about
Unauthorized modification of this report is strictly prohibited. how we can serve you better at: _ -SGS.
Review standard terms at: http://www.sgs.com/en/terms-and-conditions [e-mail]
1 of 22
JD51561

Table of Contents
1
Section1: Sample Summary...................................................................................................
Section 2: Case Narrative/Conformance Summary..............................................................
Section3: Summary of Hits....................................................................................................
Section4: Sample Results........................................................................................................
4.1: JD51561-1: Z1-0-0.5....................................................................................................
4.2: JD51561-2: Z1-0.5-2....................................................................................................
4.3: JD51561-3: Z2-0-0.5....................................................................................................
4.4: JD51561-4: Z2-0.5-2....................................................................................................
4.5: JD51561-5: Z3-0-0.5....................................................................................................
4.6: JD51561-6: Z3-0.5-2....................................................................................................
4.7: JD51561-7: DUP-20220908.........................................................................................
4.8: JD51561-8: 25-02.........................................................................................................
Section5: Misc. Forms............................................................................................................
5.1: Chain of Custody...........................................................................................................
Section 6: General Chemistry - QC Data Summaries..........................................................
6.1: Method Blank and Spike Results Summary..................................................................
6.2: Duplicate Results Summary..........................................................................................
6.3: Matrix Spike Results Summary.....................................................................................
Sections:
3
5
6
8
9
10
11
12
13
14
15
16
19
20
21
22
0
0
n
GS2 of 22
JD51561

SGS North America Inc.
Sample Summary
Geosyntec Consultants
Job No: JD51561
PPD, Harnett Street, Wilmington, NC
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
JD51561-1
09/08/22
11:00 JN
09/10/22
SO
Soil
Z1-0-0.5
JD51561-2
09/08/22
11:00 AW
09/10/22
SO
Soil
Z1-0.5-2
JD51561-3
09/08/22
14:00 AW
09/10/22
SO
Soil
Z2-0-0.5
JD51561-4
09/08/22
14:00 AW
09/10/22
SO
Soil
Z2-0.5-2
JD51561-5
09/08/22
16:00 AW
09/10/22
SO
Soil
Z3-0-0.5
JD51561-6
09/08/22
16:00 AW
09/10/22
SO
Soil
Z3-0.5-2
JD51561-7
09/08/22
16:30 AW
09/10/22
SO
Soil
DUP-20220908
JD51561-8
09/08/22
17:18
09/10/22
SO
Soil
25-02
Soil samples reported on a dry weight basis unless otherwise indicated on result page.
GS3 of 22
JD51561

CASE NARRATIVE / CONFORMANCE SUMMARY
Client: Geosyntec Consultants Job No JD51561
Site: PPD, Harnett Street, Wilmington, NC Report Date 9/19/2022 4:55:46 PM
On 09/10/2022, 8 Sample(s), 0 Trip Blank(s) and 0 Field Blank(s) were received at SGS North America Inc. at a maximum
corrected temperature of 5 C. Samples were intact and chemically preserved, unless noted below. A SGS North America Inc. Job
Number of JD51561 was assigned to the project. Laboratory sample ID, client sample ID and dates of sample collection are
detailed in the report's Results Summary Section.
Specified quality control criteria were achieved for this job except as noted below. For more information, please refer to the
analytical results and QC summary pages.
Compounds qualified as out of range in the continuing calibration summary report are acceptable as per method requirements when
there is a high bias but the sample result is non -detect.
General Chemistry By Method SM2540 G 18TH ED MOD
Matrix: SO Batch ID: GN33273
■ Sample(s) JD51606-1DUP were used as the QC samples for Solids, Percent.
General Chemistry By Method SW846 3060A/7199
I Matrix: SO Batch ID: GP42259 I
■ All samples were prepared within the recommended method holding time.
■ All method blanks for this batch meet method specific criteria.
■ Sample(s) JD51561-3DUP, JD51561-3PS, JD51561-3MS were used as the QC samples for Chromium, Hexavalent.
■ GP42259-S2 for Chromium, Hexavalent Good recovery on soluble XCR matrix spike. Good recovery (102.0%) on the post -
spike. Good recovery on insoluble XCR matrix spike. See additional comments on soluble matrix spike recovery.
SGS North America Inc. certifies that data reported for samples received, listed on the associated custody chain or analytical task
order, were produced to specifications meeting the Quality System precision, accuracy and completeness objectives except as noted.
Estimated non-standard method measurement uncertainty data is available on request, based on quality control bias and implicit for
standard methods. Acceptable uncertainty requires tested parameter quality control data to meet method criteria.
SGS North America Inc. is not responsible for data quality assumptions if partial reports are used and recommends that this report
be used in its entirety. Data release is authorized by SGS North America Inc indicated via signature on the report cover
Monday, September 19, 2022 Page 1 of 1
.SGS.
4 of 22
JD51561

Summary of Hits Page 1 of 1
Job Number: JD51561
Account: Geosyntec Consultants
Project: PPD, Harnett Street, Wilmington, NC
Collected: 09/08/22
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
JD51561-1 Z1-0-0.5
Chromium, Hexavalent
0.78
0.51
mg/kg
SW846 3060A/7199
JD51561-2 Z1-0.5-2
Chromium, Hexavalent
0.85
0.46
mg/kg
SW846 3060A/7199
JD51561-3 Z2-0-0.5
Chromium, Hexavalent
0.66
0.42
mg/kg
SW846 3060A/7199
JD51561-4 Z2-0.5-2
Chromium, Hexavalent
0.71
0.44
mg/kg
SW846 3060A/7199
JD51561-5 Z3-0-0.5
Chromium, Hexavalent
0.68
0.51
mg/kg
SW846 3060A/7199
JD51561-6 Z3-0.5-2
Chromium, Hexavalent
0.96
0.50
mg/kg
SW846 3060A/7199
JD51561-7 DUP-20220908
Chromium, Hexavalent
1.1
0.47
mg/kg
SW846 3060A/7199
JD51561-8 25-02
Chromium, Hexavalent
0.92
0.53
mg/kg
SW846 3060A/7199
GS5 of 22
JD51561

ffm
Dayton, NJ
The results set forth herein are provided by SGS North America Inc. a-Hl ydcopy 2. 0
Automated Report
Technical Report for
Geosyntec Consultants
PPD, Harnett Street, Wilmington, NC
SGS Job Number: JD51751
Sampling Date: 09/09/22
Report to:
Geosyntec Consultants
314 Walnut Street, Suite 200
Wilmington, NC 28401
Abby. Wesley@Geosyntec. com; Jack.Nolan@Geo
ATTN: Abigail Wesley
Total number of pages in report: 16
. com
Test results contained within this data package meet the requirements David Chastain
of the National Environmental Laboratory Accreditation Program General Manager
and/or state specific certification programs as applicable.
Client Service contact: Tammy McCloskey 732-329-0200
Certifications: NJ(12129), NY(10983), CA, CT, FL, IL, IN, KS, KY, LA, MA, MD, ME, MN, NC,
OH VAP (CL0056), AK(UST-103), AZ (AZ0786), PA(68-00408), RI, SC, TX, UT, VA, WV
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc. • 2235 Route 130 • Dayton, NJ 08810 • tel: [phone] • fax: [phone]
SGS is the sole authority for authorizing edits or modifications to this document. Please share your ideas about
Unauthorized modification of this report is strictly prohibited. how we can serve you better at: _ -SGS.
Review standard terms at: http://www.sgs.com/en/terms-and-conditions [e-mail]
1 of 16
JD51751

Table of Contents
Sections:
-I-
Section1: Sample Summary...................................................................................................
Section2: Summary of Hits....................................................................................................
Section3: Sample Results........................................................................................................
3.1: JD51751-1: Z4-0-0.5....................................................................................................
3.2: JD51751-2: Z4-0.5-2....................................................................................................
3.3: JD51751-3: Z6-0-2.......................................................................................................
3.4: JD51751-4: DUP-20220909.........................................................................................
Section4: Misc. Forms............................................................................................................
4.1: Chain of Custody...........................................................................................................
Section 5: General Chemistry - QC Data Summaries..........................................................
5.1: Method Blank and Spike Results Summary..................................................................
5.2: Duplicate Results Summary..........................................................................................
5.3: Matrix Spike Results Summary.....................................................................................
3
4
5
6
7
8
9
10
11
13
14
15
16
SGS2 of 16
JD51751

SGS North America Inc.
Sample Summary
Geosyntec Consultants
Job No: JD51751
PPD, Harnett Street, Wilmington, NC
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
JD51751-1 09/09/22 11:00 AW 09/10/22 SO Soil Z4-0-0.5
JD51751-2
09/09/22
15:30 AW
09/10/22
SO
Soil
Z4-0.5-2
JD51751-3
09/09/22
13:00 AW
09/10/22
SO
Soil
Z6-0-2
JD51751-4
09/09/22
13:00 AW
09/10/22
SO
Soil
DUP-20220909
Soil samples reported on a dry weight basis unless otherwise indicated on result page.
SGS3 of 16
JD51751

Summary of Hits
Job Number:
JD51751
Account:
Geosyntec Consultants
Project:
PPD, Harnett Street, Wilmington, NC
Collected:
09/09/22
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
Page 1 of 1
JD51751-1 Z4-0-0.5
Chromium, Hexavalent
0.59
0.44
mg/kg
SW846 3060A/7199
JD51751-2 Z4-0.5-2
Chromium, Hexavalent
0.89
0.41
mg/kg
SW846 3060A/7199
JD51751-3 Z6-0-2
Chromium, Hexavalent
0.76
0.43
mg/kg
SW846 3060A/7199
JD51751-4 DUP-20220909
Chromium, Hexavalent
0.76
0.44
mg/kg
SW846 3060A/7199
SGS4 of 16
JD51751

FM
Dayton, NJ
Sample Results
Report of Analysis
Section 3
SGS5 of 16
JD51751

SGS North America Inc.
Report of Analysis
Client Sample ID: Z4-0-0.5
Lab Sample ID: JD51751-1 Date Sampled: 09/09/22
Matrix: SO - Soil Date Received: 09/10/22
Percent Solids: 90.7
Project: PPD, Harnett Street, Wilmington, NC
General Chemistry
Analyte
Chromium, Hexavalent
Solids, Percent
RL = Reporting Limit
Page 1 of 1 j
Result
RL Units
DF
Analyzed
By
Method
0.59
0.44 mg/kg
1
09/16/2213:58
Ri
SW8463060A/7199
90.7
%
1
09/ 14/22 16:33
BG
SM2540 G 18TH ED MOD
SGS6 of 16
JD51751

SGS North America Inc.
Report of Analysis
Client Sample ID: Z4-0.5-2
Lab Sample ID: JD51751-2 Date Sampled: 09/09/22
Matrix: SO - Soil Date Received: 09/10/22
Percent Solids: 94.9
Project: PPD, Harnett Street, Wilmington, NC
General Chemistry
Analyte
Chromium, Hexavalent
Solids, Percent
RL = Reporting Limit
Page 1 of 1 N
Result
RL Units
DF
Analyzed
By
Method
0.89
0.41 mg/kg
1
09/16/2214:14
Ri
SW8463060A/7199
94.9
%
1
09/ 14/22 16:33
BG
SM2540 G 18TH ED MOD
aSGS7 of 16
JD51751

SGS North America Inc.
Report of Analysis
Client Sample ID: Z6-0-2
Lab Sample ID: JD51751-3 Date Sampled: 09/09/22
Matrix: SO - Soil Date Received: 09/10/22
Percent Solids: 90.6
Project: PPD, Harnett Street, Wilmington, NC
General Chemistry
Analyte
Chromium, Hexavalent
Solids, Percent
RL = Reporting Limit
Page 1 of 1 w
Result
RL Units
DF
Analyzed
By
Method
0.76
0.43 mg/kg
1
09/16/2214:30
Ri
SW8463060A/7199
90.6
%
1
09/ 14/22 16:33
BG
SM2540 G 18TH ED MOD
GS- 8 of 16
JD51751

SGS North America Inc.
Report of Analysis
Client Sample ID: DUP-20220909
Lab Sample ID: JD51751-4 Date Sampled: 09/09/22
Matrix: SO - Soil Date Received: 09/10/22
Percent Solids: 90.8
Project: PPD, Harnett Street, Wilmington, NC
General Chemistry
Analyte
Chromium, Hexavalent
Solids, Percent
RL = Reporting Limit
Page 1 of 1 P
Result
RL Units
DF
Analyzed
By
Method
0.76
0.44 mg/kg
1
09/16/2214:46
Ri
SW8463060A/7199
90.8
%
1
09/ 14/22 16:33
BG
SM2540 G 18TH ED MOD
SGS9 of 16
JD51751

ffm
Dayton, NJ
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
Section 4
SGS10 of 16
JD51751

SG SNorthAmerica Inc - OrlanftS 5'�a]-&'A.nwrka tic -
SGS . ORLANDO JOB Ili: PAGE
Chain of Custody _Y OF tN
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[jdS
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Quote
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�! '-'� Pro eel Information
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Anal
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Matr[xCodes
Cod
-ENV MR)i
Client I Reporting Information ,
Pra(e.thl...:
ID
water
PY3
GW - Ground
Water.
WW
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Water
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Street
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Cloy State: ZIP: Atti
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Sampler(*) Name($) (Printed)
Client Purchase Order#
Sampler Sam [or 2:
corrriwm17
LAB USE ONLY
SGS
Orland.
Sanjple #
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Field ID / Point of C.ctl­
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JD51751: Chain of Custody
Page 1 of 2
.SGS. 11 of 16
JD51751

Job Number: JD51751 Client:
Date / Time Received: 9/10/2022 10:00:00 AM
SGS Sample Receipt Summary
Delivery Method:
Cooler Temps (Raw Measured) °C: Cooler 1: (3.0);
Cooler Temps (Corrected) °C: Cooler 1: (3.6);
Cooler Security Y
1. Custody Seals Present: ❑d
or N
❑ 3. CDC Present:
2. Custody Seals Intact: W
❑ 4. Smpl Dates/Time OK
Cooler Temperature
Y or N
1. Temp criteria achieved:
❑d ❑
2. Cooler temp verification:
IR Gun
3. Cooler media:
Ice (Bag)
4. No. Coolers:
1
Quality Control Preservation
Y or N N/A
1. Trip Blank present / cooler:
❑ ❑d ❑
2. Trip Blank listed on COC:
❑ ❑�/ ❑
3. Samples preserved properly:
❑W ❑
4. VOCs headspace free:
❑ ❑ W
Project:
Airbill #'s:
A
Y or N
Sample Integrity - Documentation
Y
or N
• ❑
1. Sample labels present on bottles:
❑d
❑
• ❑
2. Container labeling complete:
W
❑
3. Sample container label / CDC agree:
W
❑
Sample Intearity - Condition
Y
or N
1. Sample recvd within HT:
❑
2. All containers accounted for:
❑
3. Condition of sample:
Intact
Sample Integrity - Instructions
Y
or N N/A
1. Analysis requested is clear:
❑d
❑
2. Bottles received for unspecified tests
❑
❑d
3. Sufficient volume recvd for analysis:
❑�
❑
4. Compositing instructions clear:
❑
❑ ❑�/
5. Filtering instructions clear:
❑
❑ ❑d
Test Strip Lot #s: pH 1-12: 231619 pH 12+: 203117A Other: (Specify)
Comments
SM039-03
Rev. Date 12/7/17
JD51751: Chain of Custody
Page 2 of 2
12 of 16
JD51751

ffm
Dayton, NJ
General Chemistry
QC Data Summaries
Includes the following where applicable:
• Method Blank and Blank Spike Summaries
• Duplicate Summaries
• Matrix Spike Summaries
Section 5
SGS13 of 16
JD51751

METHOD BLANK AND SPIKE RESULTS SUMMARY
GENERAL CHEMISTRY
Login Number: JD51751
Account: GSYNNCR - Geosyntec Consultants
Project: PPD, Harnett Street, Wilmington, NC
ME
Spike BSP BSP QC
Analyte Batch ID RL Result Units Amount Result %Recov Limits
Chromium, Hexavalent GP42303/GN33403 0.40 0.0 mg/kg 40 38.4 96.0 80-120% L"
Chromium, Hexavalent GP42303/GN33403 mg/kg 748 729 97.5 80-120% :-L
Chromium, Hexavalent GP42303/GN33403 mg/kg 154 94.3 61.2 46-95%
Associated Samples:
Batch GP42303: JD51751-1, JD51751-2, JD51751-3, JD51751-4
(*) Outside of QC limits
Page 1
�GS 14 of 16
a1��V\ JD51751

DUPLICATE RESULTS SUMMARY
GENERAL CHEMISTRY
Login Number: JD51751
Account: GSYNNCR - Geosyntec Consultants
Project: PPD, Harnett Street, Wilmington, NC
QC Original DUP QC
Analyte Batch ID Sample Units Result Result RPD Limits
Chromium, Hexavalent GP42303/GN33403 JD51767-8 mg/kg 1.9 4.8 86.6*(a) 0-20% (J1
Solids, Percent GN33322 JD51751-4 % 90.8 90.6 0.2 0-5o jV
Associated Samples:
Batch GN33322: JD51751-1, JD51751-2, JD51751-3, JD51751-9
Batch GP42303: JD51751-1, JD51751-2, JD51751-3, JD51751-4
(*) Outside of QC limits
(a) High RPD due to low results.
Page 1
SGS15 of 16
JD51751

MATRIX SPIKE RESULTS SUMMARY
GENERAL CHEMISTRY
Login Number: JD51751
Account: GSYNNCR - Geosyntec Consultants
Project: PPD, Harnett Street, Wilmington, NC
QC Original Spike MS QC
nalyte Batch ID Sample Units Result Amount Result %Rec Limits
Chromium, Hexavalent GP42303/GN33403 JD51767-8 mg/kg 1.9 56.9 0.40-2.6N(a) 75-1250 (T1
Chromium, Hexavalent GP42303/GN33403 JD51767-8 mg/kg 1.9 1800 878 48.8N(b) 75-1250 (�
Associated Samples:
Batch GP42303: JD51751-1, JD51751-2, JD51751-3, JD51751-9
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(a) Soluble XCR matrix spike recovery indicates possible matrix interference. Good post spike recovery (101 %) on this
sample.
(b) Insoluble XCR matrix spike recovery indicates possible matrix interference. See additional comments on soluble matrix
spike recovery.
Page 1
SGS16 of 16
JD51751

FM
Dayton, NJ
Sample Results
Report of Analysis
jP
7
Section 4
GS6 of 22
JD51561

SGS North America Inc.
Report of Analysis
Client Sample ID: Z1-0-0.5
Lab Sample ID: JD51561-1 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Percent Solids: 76.4
Project: PPD, Harnett Street, Wilmington, NC
General Chemistry
Analyte
Chromium, Hexavalent
Solids, Percent
RL = Reporting Limit
Page 1 of 1
Result
RL Units
DF
Analyzed
By
Method
0.78
0.51 mg/kg
1
09/15/2212:51
Ri
SW8463060A/7199
76.4
%
1
09/ 13/22 16:40
BG
SM2540 G 18TH ED MOD
A
L
0
GS- 7 of 22
JD51561

SGS North America Inc.
Report of Analysis
Client Sample ID: Z1-0.5-2
Lab Sample ID: JD51561-2 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Percent Solids: 85.0
Project: PPD, Harnett Street, Wilmington, NC
General Chemistry
Analyte
Chromium, Hexavalent
Solids, Percent
RL = Reporting Limit
Page 1 of 1
Result
RL Units
DF
Analyzed
By
Method
0.85
0.46 mg/kg
1
09/15/2213:07
Ri
SW8463060A/7199
85
%
1
09/ 13/22 16:40
BG
SM2540 G 18TH ED MOD
GS8 of 22
JD51561

SGS North America Inc.
Report of Analysis
Client Sample ID: Z2-0-0.5
Lab Sample ID: JD51561-3 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Percent Solids: 92.8
Project: PPD, Harnett Street, Wilmington, NC
General Chemistry
Analyte
Chromium, Hexavalent
Solids, Percent
RL = Reporting Limit
Page 1 of 1
Result
RL Units
DF
Analyzed
By
Method
0.66
0.42 mg/kg
1
09/15/2211:16
Ri
SW8463060A/7199
92.8
%
1
09/ 13/22 16:40
BG
SM2540 G 18TH ED MOD
GS9 of 22
JD51561

SGS North America Inc.
Report of Analysis
Client Sample ID: Z2-0.5-2
Lab Sample ID: JD51561-4 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Percent Solids: 90.5
Project: PPD, Harnett Street, Wilmington, NC
General Chemistry
Analyte
Chromium, Hexavalent
Solids, Percent
RL = Reporting Limit
Page 1 of 1
Result
RL Units
DF
Analyzed
By
Method
0.71
0.44 mg/kg
1
09/15/2213:39
Ri
SW8463060A/7199
90.5
%
1
09/ 13/22 16:40
BG
SM2540 G 18TH ED MOD
A
46
0
SGS10 of 22
JD51561

SGS North America Inc.
Report of Analysis
Client Sample ID: Z3-0-0.5
Lab Sample ID: JD51561-5 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Percent Solids: 75.8
Project: PPD, Harnett Street, Wilmington, NC
General Chemistry
Analyte
Chromium, Hexavalent
Solids, Percent
RL = Reporting Limit
Page 1 of 1
Result
RL Units
DF
Analyzed
By
Method
0.68
0.51 mg/kg
1
09/15/2214:02
Ri
SW8463060A/7199
75.8
%
1
09/ 13/22 16:40
BG
SM2540 G 18TH ED MOD
A
in
SGS11 of 22
JD51561

SGS North America Inc.
Report of Analysis
Client Sample ID: Z3-0.5-2
Lab Sample ID: JD51561-6 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Percent Solids: 77.1
Project: PPD, Harnett Street, Wilmington, NC
General Chemistry
Analyte
Chromium, Hexavalent
Solids, Percent
RL = Reporting Limit
Page 1 of 1
Result
RL Units
DF
Analyzed
By
Method
0.96
0.50 mg/kg
1
09/15/2214:18
Ri
SW8463060A/7199
77.1
%
1
09/ 13/22 16:40
BG
SM2540 G 18TH ED MOD
GS12 of 22
JD51561

SGS North America Inc.
Report of Analysis
Client Sample ID: DUP-20220908
Lab Sample ID: JD51561-7 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Percent Solids: 84.0
Project: PPD, Harnett Street, Wilmington, NC
General Chemistry
Analyte
Chromium, Hexavalent
Solids, Percent
RL = Reporting Limit
Page 1 of 1
Result
RL Units
DF
Analyzed
By
Method
1.1
0.47 mg/kg
1
09/15/2214:34
Ri
SW8463060A/7199
84
%
1
09/ 13/22 16:40
BG
SM2540 G 18TH ED MOD
A
4
0
SGS13 of 22
JD51561

SGS North America Inc.
Report of Analysis
Client Sample ID: 25-02
Lab Sample ID: JD51561-8 Date Sampled: 09/08/22
Matrix: SO - Soil Date Received: 09/10/22
Percent Solids: 73.3
Project: PPD, Harnett Street, Wilmington, NC
General Chemistry
Analyte
Chromium, Hexavalent
Solids, Percent
RL = Reporting Limit
Page 1 of 1
Result
RL Units
DF
Analyzed
By
Method
0.92
0.53 mg/kg
1
09/15/2214:50
Ri
SW8463060A/7199
73.3
%
1
09/ 13/22 16:40
BG
SM2540 G 18TH ED MOD
A
w
a1��GS 14 of 22
JD51561

ffm
Dayton, NJ
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
Section 5
SGS15 of 22
JD51561

snk �,b
S1'7 10"11 373 F
SGS North America Inc - Orlando j�o S i S6 ( +
Chain of Custody SGS-ORLANDOJOB 0: PAGE 1 OF
dM5 VnalnnA RSA Chile f.l S llrlundn r i�Rl I
.____ .5.—....
TFI. 4e7-425-670D FAx 407435m07
w5
3GS - ORLANDO Quote #
SKIFF #
jClient/Re ortin Information - Prowetlydo.ation
- Analyticallnformation
,z;`
Matrix Codes
....my Nam: 6, /tO a 1A
4
ProjectNam n
6
r
. nn mg
Water
GIN -Ground
Water
WW - Water
SW - Surface
Water
SO . soilPhone
SL- Sludge
OI - Oil
LI0 - Other Liquid
AIR -Air
Addr s� 1, YII OL (' • ['1 � 2 0o
VW` V J]
Street w ��
�r�'�4`
City: State: ( Zip: 2� a�
r ' , l a
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9
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ProJec t• Emyl:
GL l� ' 1h%'PS1i
Project# Ofh
�,'`lS l'3 G� • t"
,( _ �— sgcj-q
�"� "1 1
Fax
Sampler(s) Name(s) (Printed)
Sampler 1: Sampler 2:
Client Purchase Order #
Dde d0
Sample #
Field ID / Point of Collection
COLLECTION
CONTNNER
INroRraATIONSGS
DATE
TIME
SAMPLED
MATRIX
TOTAL
OF
BO—ES
_
00 $
w
a ; "�
LAB US�E OfYNLY
`Q6
YL�
3
2- -'•s
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0
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111.119
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Turnaround Time Business days)"'
;;
-4k :
Data
Deliverable
Information
,r x.x,•,g
=
Commenta
/Remarks
10 Day (Business) Approved By: I Date:
7 Day
5 Day
3 Day RUSH
2 Day RUSH
1 Day RUSH I
Other
Rush T/A Data Available VIA Email or Lablink
❑COMMERCIAL "A" (RESULTS ONLY)
COMMERCIAL "B" (RESULTS PLUS OC)
[]REDT1 (EPA LEVEL 3)
[]FULLTI (EPA LEVEL a)
�EDD'S-<'AY#V91�'#a'M#'arE—
'
•-- -
Sample Custody must be
documented below each time samples
thane possession, Including
courier
very
Relinquished by Sampler/Affiliation
1
Date Time:
Rarely y/ ffili n
2 reel
Relinquish ItBylAfFlllalion
3
D e T e:
sicBy/A in
a
RElinquished by/Affiliation
5
Date Time:
Received By/Affiliation
6
Relinquished By/Affiliation
7
Date ime:
1
Recalved By/Affillation
9
Lab Use Onl : Cooler Temperature (a) Celsius (corrected): I hh 7/www,SS mm/en/terms------ntlhions
SGS CDC Rev 031318 a ,
JD51561: Chain of Custody
Page 1 of 3
!A
L
SGS16 of 22
JD51561

SGS Sample Receipt Summary
Job Number: JD51561 Client: GEOSYNTEC
Date / Time Received: 9/10/2022 10:30:00 AM Delivery Method:
Cooler Temps (Raw Measured) °C: Cooler 1: (4.4);
Cooler Temps (Corrected) °C: Cooler 1: (5.0);
Cooler Security Y or N
Y or N
1. Custody Seals Present: ❑d
❑
3. COC Present: ❑d ❑
2. Custody Seals Intact: W
❑
4. Smpl Dates/Time OK ❑d ❑
Cooler Temperature
Y or N
1. Temp criteria achieved:
❑
2. Cooler temp verification:
IR Gun
3. Cooler media:
Ice
(Bag)
4. No. Coolers:
1
Quality Control Preservation
Y
or N
N/A
1. Trip Blank present / cooler:
❑
W
❑
2. Trip Blank listed on COC:
❑
W
❑
3. Samples preserved properly:
❑d
❑
4. VOCs headspace free:
❑
❑
❑
FEDEX
Project: PPD
Airbill #'s:
Sample Inteority - Documentation
Y
or N
1. Sample labels present on bottles:
k
El
2. Container labeling complete:
❑d
❑
3. Sample container label / COC agree:
❑�
❑
Sample Integrity - Condition
Y
or N
1. Sample recvd within HT:
2
❑
2. All containers accounted for:
W
❑
3. Condition of sample:
Intact
Sample Integrity - Instructions
Y
or N N/A
1. Analysis requested is clear:
❑
2. Bottles received for unspecified tests
❑
W
3. Sufficient volume recvd for analysis:
❑
4. Compositing instructions clear:
❑
❑ k
5. Filtering instructions clear:
❑
❑ 2
Test Strip Lot #s: pH 1-12: 231619 pH 12+: 203117A Other: (Specify)
Comments
1. -6 Received extra sample not on the COC 25-02, add to the end on the COC.
JD51561: Chain of Custody
Page 2 of 3
17 of 22
JD51561

SM089-02 Rev. Date 12/1/16
Responded to by: Tammy Esposito McCloskey
1) all JD51561-8 to coc and analyze for XCR7199 per Abigail Wesley
Response Date: 9/12/2022
JD51561: Chain of Custody
Page 3 of 3
GS18 of 22
JD51561

ffm
Dayton, NJ
General Chemistry
QC Data Summaries
Includes the following where applicable:
• Method Blank and Blank Spike Summaries
• Duplicate Summaries
• Matrix Spike Summaries
Section 6
0
SGS19 of 22
JD51561

METHOD BLANK AND SPIKE RESULTS SUMMARY
GENERAL CHEMISTRY
Login Number: JD51561
Account: GSYNNCR - Geosyntec Consultants
Project: PPD, Harnett Street, Wilmington, NC
ME
Spike BSP BSP QC
Analyte Batch ID RL Result Units Amount Result %Recov Limits
Chromium, Hexavalent
GP42259/GN33360 0.40
0.0 mg/kg
40
39.3 98.3 80-120%
Chromium, Hexavalent
GP42259/GN33360
mg/kg
1120
1050 93.8 80-120%
Chromium, Hexavalent
GP42259/GN33360
mg/kg
154
134 87.1 46-95%
Associated Samples:
O)
Batch GP42259: JD51561-1,
JD51561-2, JD51561-3, JD51561-4,
JD51561-5, JD51561-6,
JD51561-7,
JD51561-8
(*) Outside of QC limits
Page 1
1
GS20 of 22
JD51561

DUPLICATE RESULTS SUMMARY
GENERAL CHEMISTRY
Login Number: JD51561
Account: GSYNNCR - Geosyntec Consultants
Project: PPD, Harnett Street, Wilmington, NC
QC Original DUP QC
nalyte Batch ID Sample Units Result Result RPD Limits
Chromium, Hexavalent GP42259/GN33360 JD51561-3 mg/kg 0.66 0.67 1.5 0-20%
Solids, Percent GN33273 JD51606-1 % 85.7 84.7 1.2 0-50
Associated Samples:
Batch GN33273: JD51561-1, JD51561-2, JD51561-3, JD51561-4, JD51561-5, JD51561-6, JD51561-7, JD51561-8
Batch GP42259: JD51561-1, JD51561-2, JD51561-3, JD51561-4, JD51561-5, JD51561-6, JD51561-7, JD51561-8 jV
(*) Outside of QC limits
Page 1
1
GS21 of 22
JD51561

MATRIX SPIKE RESULTS SUMMARY
GENERAL CHEMISTRY
Login Number: JD51561
Account: GSYNNCR - Geosyntec Consultants
Project: PPD, Harnett Street, Wilmington, NC
QC Original Spike MS QC
nalyte Batch ID Sample Units Result Amount Result %Rec Limits
Chromium, Hexavalent GP42259/GN33360 JD51561-3 mg/kg 0.66 991 843 85.0(a) 75-125%
Chromium, Hexavalent GP42259/GN33360 JD51561-3 mg/kg 0.66 41.8 33.4 78.4(b) 75-125%
Associated Samples:
Batch GP42259: JD51561-1, JD51561-2, JD51561-3, JD51561-4, JD51561-5, JD51561-6, JD51561-7, JD51561-8
(*) Outside of QC limits
W
(N) Matrix Spike Rec. outside of QC limits
(a) Good recovery on soluble XCR matrix spike. Good recovery (102.0%) on the post -spike.
(b) Good recovery on insoluble XCR matrix spike. See additional comments on soluble matrix spike recovery. •
Page 1
GS22 of 22
JD51561

Orlando, FL
Sample Results
Report of Analysis
Section 3
GS6 of 122
FA98839

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:
Z4-1-0-0.5
Lab Sample ID:
FA98839-1 Date Sampled: 09/09/22
Matrix:
SO - Soil Date Received: 09/10/22
Method:
SW846 8260D Percent Solids: n/a a
Project:
PPD; Harnett St, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3C183796.D 1 09/21/22 19:27 DB n/a n/a V3C873
Run #2
Initial Weight Final Volume
Run#1 5.36g 5.0ml
Run #2
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
67-64-1
Acetone
ND
190
93
ug/kg
71-43-2
Benzene
ND
4.7
1.1
ug/kg
108-86-1
Bromobenzene
ND
4.7
0.93
ug/kg
74-97-5
Bromochloromethane
ND
4.7
1.4
ug/kg
75-27-4
Bromodichloromethane
ND
4.7
0.93
ug/kg
75-25-2
Bromoform
ND
4.7
0.93
ug/kg
78-93-3
2-Butanone (MEK)
ND
23
6.8
ug/kg
104-51-8
n-Butylbenzene
ND
4.7
0.93
ug/kg
135-98-8
sec-Butylbenzene
ND
4.7
0.93
ug/kg
98-06-6
tert-Butylbenzene
ND
4.7
0.93
ug/kg
56-23-5
Carbon Tetrachloride
ND
4.7
0.95
ug/kg
108-90-7
Chlorobenzene
ND
4.7
0.93
ug/kg
75-00-3
Chloroethane b
ND
4.7
1.9
ug/kg
67-66-3
Chloroform
ND
4.7
1.2
ug/kg
95-49-8
o-Chlorotoluene
ND
4.7
0.93
ug/kg
106-43-4
p-Chlorotoluene
ND
4.7
0.93
ug/kg
124-48-1
Dibromochloromethane
ND
4.7
0.93
ug/kg
106-93-4
1,2-Dibromoethane
ND
4.7
0.93
ug/kg
75-71-8
Dichlorodifluoromethane
ND
4.7
1.9
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
4.7
0.93
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
4.7
0.93
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
4.7
1.1
ug/kg
75-34-3
1, 1 -Dichloroethane
ND
4.7
1.7
ug/kg
107-06-2
1,2-Dichloroethane
ND
4.7
0.93
ug/kg
75-35-4
1, 1 -Dichloroethylene
ND
4.7
0.93
ug/kg
156-59-2
cis-1,2-Dichloroethylene
ND
4.7
1.3
ug/kg
156-60-5
trans- 1, 2-Dichloroethylene
ND
4.7
0.93
ug/kg
78-87-5
1,2-Dichloropropane
ND
4.7
0.93
ug/kg
142-28-9
1,3-Dichloropropane
ND
4.7
0.93
ug/kg
594-20-7
2,2-Dichloropropane
ND
4.7
0.93
ug/kg
563-58-6
1, 1 -Dichloropropene
ND
4.7
0.95
ug/kg
10061-01-5
cis- 1, 3 -Dichloropropene
ND
4.7
0.93
ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
a1��GS 7 of 122
FA98839

SGS North America Inc.
Report of Analysis
Page 2 of 3
Client Sample ID:
Z4-1-0-0.5
Lab Sample ID:
FA98839-1 Date Sampled: 09/09/22
Matrix:
SO - Soil Date Received: 09/10/22
Method:
SW846 8260D Percent Solids: n/a a
Project:
PPD; Harnett St, Wilmington, NC
VOA List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
10061-02-6
trans- 1, 3-Dichloropropene
ND
4.7
0.93
ug/kg
108-20-3
Di -Isopropyl Ether
ND
4.7
2.2
ug/kg
64-17-5
Ethyl Alcohol °
ND
370
70
ug/kg
100-41-4
Ethylbenzene
ND
4.7
0.93
ug/kg
591-78-6
2-Hexanone
ND
23
7.0
ug/kg
98-82-8
Isopropylbenzene
ND
4.7
0.93
ug/kg
99-87-6
p-Isopropyltoluene
ND
4.7
0.93
ug/kg
74-83-9
Methyl Bromide
ND
4.7
1.9
ug/kg
74-87-3
Methyl Chloride
ND
4.7
1.9
ug/kg
75-09-2
Methylene Chloride b
ND
19
10
ug/kg
108-10-1
4-Methyl-2-pentanone (MIBK) ND
23
7.0
ug/kg
1634-04-4
Methyl Tert Butyl Ether
ND
4.7
0.93
ug/kg
91-20-3
Naphthalene
ND
4.7
1.9
ug/kg
103-65-1
n-Propylbenzene
ND
4.7
0.93
ug/kg
100-42-5
Styrene
ND
4.7
0.93
ug/kg
630-20-6
1, 1, 1, 2-Tetrachloroethane
ND
4.7
0.96
ug/kg
79-34-5
1,1,2,2-Tetrachloroethane
ND
4.7
0.93
ug/kg
127-18-4
Tetrachloroethylene
ND
4.7
1.2
ug/kg
108-88-3
Toluene
ND
19
9.3
ug/kg
87-61-6
1, 2,3 -Trichlorobenzene
ND
4.7
1.3
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
4.7
0.93
ug/kg
71-55-6
1, 1, 1 -Trichloroethane
ND
4.7
0.93
ug/kg
79-00-5
1,1,2-Trichloroethane
ND
4.7
0.93
ug/kg
79-01-6
Trichloroethylene
ND
4.7
0.93
ug/kg
75-69-4
Trichlorofluoromethane
ND
4.7
1.9
ug/kg
96-18-4
1, 2,3 -Trichloropropane
ND
4.7
1.2
ug/kg
95-63-6
1,2,4-Trimethylbenzene
ND
4.7
0.93
ug/kg
108-67-8
1,3,5-Trimethylbenzene
ND
4.7
0.93
ug/kg
108-05-4
Vinyl Acetate
ND
23
15
ug/kg
75-01-4
Vinyl Chloride
ND
4.7
0.93
ug/kg
m,p-Xylene
ND
9.3
1.0
ug/kg
95-47-6
o-Xylene
ND
4.7
0.93
ug/kg
1330-20-7
Xylene (total)
ND
14
2.0
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
1868-53-7
Dibromofluoromethane
98%
75-124%
17060-07-0
1,2-Dichloroethane-D4
111%
72-135%
2037-26-5
Toluene-D8
98%
75-126%
460-00-4
4-Bromofluorobenzene
103%
71-133%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
GS8 of 122
FA98839

SGS North America Inc.
Report of Analysis
Page 3 of 3
Client Sample ID:
Z4-1-0-0.5
Lab Sample ID:
FA98839-1 Date Sampled: 09/09/22
Matrix:
SO - Soil Date Received: 09/10/22
Method:
SW846 8260D Percent Solids: n/a a
Project:
PPD; Harnett St, Wilmington, NC
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(a) All results reported on a wet weight basis.
(b) Associated Initial Calibration outside control limits (%RSD > 15%); sample is ND.
(c) Associated ICV outside control limits low, however sample ND.
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
GS9 of 122
FA98839

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:
Z4-2-1.5-2
Lab Sample ID:
FA98839-2 Date Sampled: 09/09/22
Matrix:
SO - Soil Date Received: 09/10/22
Method:
SW846 8260D Percent Solids: n/a a
Project:
PPD; Harnett St, Wilmington, NC
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
Run #1 b F0104808.D
1
09/23/22 19:11
DB
n/a
n/a
VF3759
Run #2 ° 3C183797.D
1
09/21/22 19:52
DB
n/a
n/a
V3C873
Initial Weight Final Volume Methanol Aliquot
Run #1 6.71 g 5.0 ml 50.0 ul
Run #2 6.88 g 5.0 ml
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
67-64-1
Acetone
ND
15000
7500
ug/kg
71-43-2
Benzene
ND
370
91
ug/kg
108-86-1
Bromobenzene
ND
370
75
ug/kg
74-97-5
Bromochloromethane
ND
370
110
ug/kg
75-27-4
Bromodichloromethane
ND
370
75
ug/kg
75-25-2
Bromoform
ND
370
75
ug/kg
78-93-3
2-Butanone (MEK)
ND
1900
540
ug/kg
104-51-8
n-Butylbenzene
715
370
75
ug/kg
135-98-8
sec-Butylbenzene
1020
370
75
ug/kg
98-06-6
tert-Butylbenzene
ND
370
75
ug/kg
56-23-5
Carbon Tetrachloride
ND
370
76
ug/kg
108-90-7
Chlorobenzene
ND
370
75
ug/kg
75-00-3
Chloroethane
ND
370
150
ug/kg
67-66-3
Chloroform
ND
370
99
ug/kg
95-49-8
o-Chlorotoluene
ND
370
75
ug/kg
106-43-4
p-Chlorotoluene
ND
370
75
ug/kg
124-48-1
Dibromochloromethane
ND
370
75
ug/kg
106-93-4
1,2-Dibromoethane
ND
370
75
ug/kg
75-71-8
Dichlorodifluoromethane d
ND
370
150
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
370
75
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
370
75
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
370
86
ug/kg
75-34-3
1, 1 -Dichloroethane
ND
370
130
ug/kg
107-06-2
1,2-Dichloroethane
ND
370
75
ug/kg
75-35-4
1, 1 -Dichloroethylene
ND
370
75
ug/kg
156-59-2
cis-1,2-Dichloroethylene
ND
370
100
ug/kg
156-60-5
trans- 1, 2-Dichloroethylene
ND
370
75
ug/kg
78-87-5
1,2-Dichloropropane
ND
370
75
ug/kg
142-28-9
1,3-Dichloropropane
ND
370
75
ug/kg
594-20-7
2,2-Dichloropropane
ND
370
75
ug/kg
563-58-6
1, 1 -Dichloropropene
ND
370
76
ug/kg
10061-01-5
cis- 1, 3 -Dichloropropene
ND
370
75
ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
�GS 10 of 122
a1��V\ FA98839

SGS North America Inc.
Report of Analysis
Page 2 of 3
Client Sample ID:
Z4-2-1.5-2
Lab Sample ID:
FA98839-2 Date Sampled: 09/09/22
Matrix:
SO - Soil Date Received: 09/10/22
Method:
SW846 8260D Percent Solids: n/a a
Project:
PPD; Harnett St, Wilmington, NC
VOA List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
10061-02-6
trans- 1, 3-Dichloropropene
ND
370
75
ug/kg
108-20-3
Di -Isopropyl Ether
ND
370
170
ug/kg
64-17-5
Ethyl Alcohol e
ND
30000
5600
ug/kg
100-41-4
Ethylbenzene
ND
370
75
ug/kg
591-78-6
2-Hexanone
ND
1900
560
ug/kg
98-82-8
Isopropylbenzene
269
370
75
ug/kg J
99-87-6
p-Isopropyltoluene
ND
370
75
ug/kg
74-83-9
Methyl Bromide
ND
370
150
ug/kg
74-87-3
Methyl Chloride
ND
370
150
ug/kg
75-09-2
Methylene Chloride
ND
1500
820
ug/kg
108-10-1
4-Methyl-2-pentanone (MIBK) ND
1900
560
ug/kg
1634-04-4
Methyl Tert Butyl Ether
ND
370
75
ug/kg
91-20-3
Naphthalene
ND
370
150
ug/kg
103-65-1
n-Propylbenzene
448
370
75
ug/kg
100-42-5
Styrene
ND
370
75
ug/kg
630-20-6
1, 1, 1, 2-Tetrachloroethane
ND
370
77
ug/kg
79-34-5
1,1,2,2-Tetrachloroethane
ND
370
75
ug/kg
127-18-4
Tetrachloroethylene
ND
370
95
ug/kg
108-88-3
Toluene
ND
1500
750
ug/kg
87-61-6
1, 2,3 -Trichlorobenzene
ND
370
100
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
370
75
ug/kg
71-55-6
1, 1, 1 -Trichloroethane
ND
370
75
ug/kg
79-00-5
1,1,2-Trichloroethane
ND
370
75
ug/kg
79-01-6
Trichloroethylene
ND
370
75
ug/kg
75-69-4
Trichlorofluoromethane
ND
370
150
ug/kg
96-18-4
1, 2,3 -Trichloropropane
ND
370
93
ug/kg
95-63-6
1,2,4-Trimethylbenzene
ND
370
75
ug/kg
108-67-8
1,3,5-Trimethylbenzene
ND
370
75
ug/kg
108-05-4
Vinyl Acetate
ND
1900
1200
ug/kg
75-01-4
Vinyl Chloride
ND
370
75
ug/kg
m,p-Xylene
ND
750
82
ug/kg
95-47-6
o-Xylene
ND
370
75
ug/kg
1330-20-7
Xylene (total)
ND
1100
160
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
1868-53-7
Dibromofluoromethane
96%
108%
75-124%
17060-07-0
1,2-Dichloroethane-D4
99%
117%
72-135%
2037-26-5
Toluene-D8
100%
121%
75-126%
460-00-4
4-Bromofluorobenzene
88%
49% f
71-133%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS11 of 122
FA98839

SGS North America Inc.
Report of Analysis
Page 3 of 3 N
Client Sample ID:
Z4-2-1.5-2
Lab Sample ID:
FA98839-2 Date Sampled: 09/09/22
Matrix:
SO - Soil Date Received: 09/10/22
Method:
SW846 8260D Percent Solids: n/a a
Project:
PPD; Harnett St, Wilmington, NC
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(a) All results reported on a wet weight basis.
(b) Dilution required due to matrix interference (surrogate standard failure).
(c) Confirmation run.
(d) Associated CCV outside control limits high, sample is ND.
(e) Associated CCV outside control limits low.
(f) Outside control limits.
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
�GS 12 of 122
a1��V\ FA98839

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: Z4-0-0.5
Lab Sample ID: FA98839-3 Date Sampled: 09/09/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 93.6
Project: PPD; Harnett St, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 X084001.13 1 09/15/22 18:55 KA 09/14/22 07:30 OP93050 SX3330
Run #2
Initial Weight Final Volume
Run #1 30.1 g 1.0 ml
Run #2
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
65-85-0
Benzoic Acid
ND
890
180
ug/kg
59-50-7
4-Chloro-3-methyl Phenol
ND
180
20
ug/kg
95-57-8
2-Chlorophenol
ND
180
22
ug/kg
120-83-2
2,4-Dichlorophenol
ND
180
20
ug/kg
105-67-9
2,4-Dimethylphenol
ND
180
47
ug/kg
51-28-5
2,4-Dinitrophenol
ND
890
180
ug/kg
534-52-1
4,6-Dinitro-o-cresol
ND
350
71
ug/kg
95-48-7
2-Methylphenol
ND
180
21
ug/kg
3&4-Methylphenol
ND
180
29
ug/kg
88-75-5
2-Nitrophenol
ND
180
19
ug/kg
100-02-7
4-Nitrophenol
ND
890
180
ug/kg
87-86-5
Pentachlorophenol
ND
890
180
ug/kg
108-95-2
Phenol
ND
180
18
ug/kg
88-06-2
2,4,6-Trichlorophenol
ND
180
20
ug/kg
83-32-9
Acenaphthene
ND
180
19
ug/kg
208-96-8
Acenaphthylene
ND
180
18
ug/kg
120-12-7
Anthracene
ND
180
20
ug/kg
56-55-3
Benzo(a)anthracene
43.5
180
18
ug/kg J
50-32-8
Benzo(a)pyrene
43.1
180
21
ug/kg J
205-99-2
Benzo(b)fluoranthene
65.1
180
19
ug/kg J
191-24-2
Benzo(g, h, i)perylene
25.8
180
18
ug/kg J
207-08-9
Benzo(k)fluoranthene
ND
180
23
ug/kg
100-51-6
Benzyl Alcohol
ND
180
18
ug/kg
101-55-3
4-Bromophenyl phenyl ether
ND
180
18
ug/kg
85-68-7
Butyl benzyl phthalate a
ND
180
35
ug/kg
106-47-8
4-Chloroaniline
ND
180
45
ug/kg
111-91-1
bis(2-Chloroethoxy)methane
ND
180
18
ug/kg
111-44-4
bis(2-Chloroethyl)ether
ND
180
21
ug/kg
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
180
22
ug/kg
91-58-7
2-Chloronaphthalene
ND
180
18
ug/kg
7005-72-3
4-Chlorophenyl phenyl ether
ND
180
18
ug/kg
218-01-9
Chrysene
45.1
180
18
ug/kg J
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS13 of 122
FA98839

SGS North America Inc.
Report of Analysis
Client Sample ID: Z4-0-0.5
Lab Sample ID: FA98839-3 Date Sampled: 09/09/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 93.6
Project: PPD; Harnett St, Wilmington, NC
ABN List for NC, May 2012
CAS No.
Compound
Result
RL
MDL Units Q
53-70-3
Dibenzo(a,h)anthracene
ND
180
22
ug/kg
132-64-9
Dibenzofaran
ND
180
18
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
180
18
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
180
19
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
180
24
ug/kg
91-94-1
3,3'-Dichlorobenzidine
ND
180
42
ug/kg
84-66-2
Diethyl Phthalate
ND
350
35
ug/kg
131-11-3
Dimethyl Phthalate
ND
180
35
ug/kg
117-84-0
Di-n-octyl Phthalate a
ND
180
35
ug/kg
84-74-2
Di-n-butyl Phthalate
ND
350
71
ug/kg
122-66-7
1,2-Diphenylhydrazine
ND
180
18
ug/kg
117-81-7
bis(2-Ethylhexyl)phthalate
37.4
350
35
ug/kg J
206-44-0
Fluoranthene
70.5
180
18
ug/kg J
86-73-7
Fluorene
ND
180
19
ug/kg
118-74-1
Hexachlorobenzene b
ND
180
18
ug/kg
87-68-3
Hexachlorobutadiene
ND
180
18
ug/kg
77-47-4
Hexachlorocyclopentadiene
ND
180
35
ug/kg
67-72-1
Hexachloroethane
ND
180
21
ug/kg
193-39-5
Indeno(1,2,3-cd)pyrene
59.4
180
22
ug/kg J
78-59-1
Isophorone
ND
180
18
ug/kg
90-12-0
1-Methylnaphthalene
ND
180
18
ug/kg
91-57-6
2-Methylnaphthalene
ND
180
18
ug/kg
91-20-3
Naphthalene
ND
180
18
ug/kg
98-95-3
Nitrobenzene
ND
180
18
ug/kg
621-64-7
N-Nitrosodi-n-propylamine
ND
180
18
ug/kg
86-30-6
N-Nitrosodiphenylamine
ND
180
19
ug/kg
85-01-8
Phenanthrene
ND
180
18
ug/kg
129-00-0
Pyrene
62.7
180
20
ug/kg J
120-82-1
1,2,4-Trichlorobenzene
ND
180
21
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
367-12-4
2-Fluorophenol
67%
40-102%
4165-62-2
Phenol-d5
68%
41-100%
118-79-6
2,4,6-Tribromophenol
62%
42-108%
4165-60-0
Nitrobenzene-d5
57%
40-105%
321-60-8
2-Fluorobiphenyl
66%
43-107%
1718-51-0
Terphenyl-dl4
76%
45-119%
(a) Associated BS and CCV outside of control limits high, sample was ND.
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS14 of 122
FA98839

SGS North America Inc.
Report of Analysis Page 3 of 3 w
Client Sample ID: Z4-0-0.5
Lab Sample ID: FA98839-3 Date Sampled: 09/09/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 93.6
Project: PPD; Harnett St, Wilmington, NC
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(b) Associated CCV outside of control limits low.
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
SGS15 of 122
FA98839

SGS North America Inc.
Report of Analysis Page 1 of 1 w
Client Sample ID: Z4-0-0.5
Lab Sample ID: FA98839-3 Date Sampled: 09/09/22
Matrix: SO - Soil Date Received: 09/10/22
Percent Solids: 93.6
Project: PPD; Harnett St, Wilmington, NC
Metals Analysis
Analyte Result RL
Units
DF
Prep
Analyzed
By
Method
Prep Method
Arsenic a 4.5 2.3
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Barium a < 46 46
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Cadmium a < 0.91 0.91
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Chromium a 18.6 2.3
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Lead a 5.7 4.6
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Mercury < 0.038 0.038
mg/kg
1
09/15/22
09/15/22
JC
SW846 7471B 1
SW846 7471B 3
Selenium a < 4.6 4.6
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Silver a < 2.3 2.3
mg/kg
5
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
(1) Instrument QC Batch: MA18914
(2) Instrument QC Batch: MA18920
(3) Prep QC Batch: MP41212
(4) Prep QC Batch: MP41216
(a) Sample dilution required due to difficult matrix.
RL = Reporting Limit
a1��GS 16 of 122
FA98839

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: Z4-0.5-2
Lab Sample ID: FA98839-4 Date Sampled: 09/09/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 95.4
Project: PPD; Harnett St, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 X084002.13 1 09/15/22 19:22 KA 09/14/22 07:30 OP93050 SX3330
Run #2
Initial Weight Final Volume
Run#1 30.0g 1.0ml
Run #2
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units
65-85-0
Benzoic Acid
ND
870
170
ug/kg
59-50-7
4-Chloro-3-methyl Phenol
ND
170
20
ug/kg
95-57-8
2-Chlorophenol
ND
170
21
ug/kg
120-83-2
2,4-Dichlorophenol
ND
170
20
ug/kg
105-67-9
2,4-Dimethylphenol
ND
170
46
ug/kg
51-28-5
2,4-Dinitrophenol
ND
870
170
ug/kg
534-52-1
4,6-Dinitro-o-cresol
ND
350
70
ug/kg
95-48-7
2-Methylphenol
ND
170
21
ug/kg
3&4-Methylphenol
ND
170
29
ug/kg
88-75-5
2-Nitrophenol
ND
170
19
ug/kg
100-02-7
4-Nitrophenol
ND
870
170
ug/kg
87-86-5
Pentachlorophenol
ND
870
170
ug/kg
108-95-2
Phenol
ND
170
17
ug/kg
88-06-2
2,4,6-Trichlorophenol
ND
170
20
ug/kg
83-32-9
Acenaphthene
98.8
170
19
ug/kg
208-96-8
Acenaphthylene
ND
170
17
ug/kg
120-12-7
Anthracene
161
170
20
ug/kg
56-55-3
Benzo(a)anthracene
ND
170
17
ug/kg
50-32-8
Benzo(a)pyrene
ND
170
21
ug/kg
205-99-2
Benzo(b)fluoranthene
ND
170
19
ug/kg
191-24-2
Benzo(g, h, i)perylene
ND
170
18
ug/kg
207-08-9
Benzo(k)fluoranthene
ND
170
23
ug/kg
100-51-6
Benzyl Alcohol
ND
170
17
ug/kg
101-55-3
4-Bromophenyl phenyl ether
ND
170
18
ug/kg
85-68-7
Butyl benzyl phthalate a
ND
170
35
ug/kg
106-47-8
4-Chloroaniline
ND
170
44
ug/kg
111-91-1
bis(2-Chloroethoxy)methane
ND
170
17
ug/kg
111-44-4
bis(2-Chloroethyl)ether
ND
170
20
ug/kg
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
170
22
ug/kg
91-58-7
2-Chloronaphthalene
ND
170
17
ug/kg
7005-72-3
4-Chlorophenyl phenyl ether
ND
170
17
ug/kg
218-01-9
Chrysene
ND
170
18
ug/kg
01
J
J
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS17 of 122
FA98839

SGS North America Inc.
Report of Analysis
Client Sample ID: Z4-0.5-2
Lab Sample ID: FA98839-4 Date Sampled: 09/09/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 95.4
Project: PPD; Harnett St, Wilmington, NC
ABN List for NC, May 2012
CAS No.
Compound
Result
RL
MDL Units Q
53-70-3
Dibenzo(a,h)anthracene
ND
170
22
ug/kg
132-64-9
Dibenzofaran
ND
170
17
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
170
17
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
170
19
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
170
23
ug/kg
91-94-1
3,3'-Dichlorobenzidine
ND
170
42
ug/kg
84-66-2
Diethyl Phthalate
ND
350
35
ug/kg
131-11-3
Dimethyl Phthalate
ND
170
35
ug/kg
117-84-0
Di-n-octyl Phthalate a
ND
170
35
ug/kg
84-74-2
Di-n-butyl Phthalate
ND
350
70
ug/kg
122-66-7
1,2-Diphenylhydrazine
ND
170
17
ug/kg
117-81-7
bis(2-Ethylhexyl)phthalate
ND
350
35
ug/kg
206-44-0
Fluoranthene
33.8
170
17
ug/kg J
86-73-7
Fluorene
126
170
19
ug/kg J
118-74-1
Hexachlorobenzene b
ND
170
18
ug/kg
87-68-3
Hexachlorobutadiene
ND
170
18
ug/kg
77-47-4
Hexachlorocyclopentadiene
ND
170
35
ug/kg
67-72-1
Hexachloroethane
ND
170
21
ug/kg
193-39-5
Indeno(1,2,3-cd)pyrene
ND
170
21
ug/kg
78-59-1
Isophorone
ND
170
17
ug/kg
90-12-0
1-Methylnaphthalene
596
170
17
ug/kg
91-57-6
2-Methylnaphthalene
ND
170
17
ug/kg
91-20-3
Naphthalene
ND
170
17
ug/kg
98-95-3
Nitrobenzene
ND
170
17
ug/kg
621-64-7
N-Nitrosodi-n-propylamine
ND
170
17
ug/kg
86-30-6
N-Nitrosodiphenylamine
ND
170
19
ug/kg
85-01-8
Phenanthrene
ND
170
17
ug/kg
129-00-0
Pyrene
85.9
170
20
ug/kg J
120-82-1
1,2,4-Trichlorobenzene
ND
170
21
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
367-12-4
2-Fluorophenol
59%
40-102%
4165-62-2
Phenol-d5
61%
41-100%
118-79-6
2,4,6-Tribromophenol
61%
42-108%
4165-60-0
Nitrobenzene-d5
49%
40-105%
321-60-8
2-Fluorobiphenyl
59%
43-107%
1718-51-0
Terphenyl-dl4
88%
45-119%
(a) Associated BS and CCV outside of control limits high, sample was ND.
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS18 of 122
FA98839

SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID: Z4-0.5-2
Lab Sample ID: FA98839-4 Date Sampled: 09/09/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 95.4
Project: PPD; Harnett St, Wilmington, NC
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(b) Associated CCV outside of control limits low.
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
�GS 19 of 122
a1��V\ FA98839

SGS North America Inc.
Report of Analysis Page 1 of 1 P
Client Sample ID: Z4-0.5-2
Lab Sample ID: FA98839-4 Date Sampled: 09/09/22
Matrix: SO - Soil Date Received: 09/10/22
Percent Solids: 95.4
Project: PPD; Harnett St, Wilmington, NC
Metals Analysis
Analyte Result RL
Units
DF
Prep
Analyzed
By
Method
Prep Method
Arsenic 1.2 0.44
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Barium < 8.8 8.8
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Cadmium < 0.18 0.18
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050E 4
Chromium 5.1 0.44
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Lead 23.0 0.88
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Mercury < 0.039 0.039
mg/kg
1
09/15/22
09/15/22
JC
SW846 7471B 1
SW846 7471B 3
Selenium < 0.88 0.88
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Silver < 0.44 0.44
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
(1) Instrument QC Batch: MA18914
(2) Instrument QC Batch: MA18920
(3) Prep QC Batch: MP41212
(4) Prep QC Batch: MP41216
RL = Reporting Limit
a1��GS 20 of 122
FA98839

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: Z6-5-1-1.5
Lab Sample ID: FA98839-5 Date Sampled: 09/09/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8260D Percent Solids: n/a a
Project: PPD; Harnett St, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3C183798.D 1 09/21/22 20:18 DB n/a n/a V3C873
Run #2
Initial Weight Final Volume
Run # 1 6.51 g 5.0 ml
Run #2
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
67-64-1
Acetone
ND
150
77
ug/kg
71-43-2
Benzene
ND
3.8
0.94
ug/kg
108-86-1
Bromobenzene
ND
3.8
0.77
ug/kg
74-97-5
Bromochloromethane
ND
3.8
1.1
ug/kg
75-27-4
Bromodichloromethane
ND
3.8
0.77
ug/kg
75-25-2
Bromoform
ND
3.8
0.77
ug/kg
78-93-3
2-Butanone (MEK)
ND
19
5.6
ug/kg
104-51-8
n-Butylbenzene
ND
3.8
0.77
ug/kg
135-98-8
sec-Butylbenzene
ND
3.8
0.77
ug/kg
98-06-6
tert-Butylbenzene
ND
3.8
0.77
ug/kg
56-23-5
Carbon Tetrachloride
ND
3.8
0.78
ug/kg
108-90-7
Chlorobenzene
ND
3.8
0.77
ug/kg
75-00-3
Chloroethane b
ND
3.8
1.5
ug/kg
67-66-3
Chloroform
ND
3.8
1.0
ug/kg
95-49-8
o-Chlorotoluene
ND
3.8
0.77
ug/kg
106-43-4
p-Chlorotoluene
ND
3.8
0.77
ug/kg
124-48-1
Dibromochloromethane
ND
3.8
0.77
ug/kg
106-93-4
1,2-Dibromoethane
ND
3.8
0.77
ug/kg
75-71-8
Dichlorodifluoromethane
ND
3.8
1.5
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
3.8
0.77
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
3.8
0.77
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
3.8
0.88
ug/kg
75-34-3
1, 1 -Dichloroethane
ND
3.8
1.4
ug/kg
107-06-2
1,2-Dichloroethane
ND
3.8
0.77
ug/kg
75-35-4
1, 1 -Dichloroethylene
ND
3.8
0.77
ug/kg
156-59-2
cis-1,2-Dichloroethylene
ND
3.8
1.1
ug/kg
156-60-5
trans- 1, 2-Dichloroethylene
ND
3.8
0.77
ug/kg
78-87-5
1,2-Dichloropropane
ND
3.8
0.77
ug/kg
142-28-9
1,3-Dichloropropane
ND
3.8
0.77
ug/kg
594-20-7
2,2-Dichloropropane
ND
3.8
0.77
ug/kg
563-58-6
1, 1 -Dichloropropene
ND
3.8
0.78
ug/kg
10061-01-5
cis- 1, 3 -Dichloropropene
ND
3.8
0.77
ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
a1��GS 21 of 122
FA98839

SGS North America Inc.
Report of Analysis
Client Sample ID: Z6-5-1-1.5
Lab Sample ID: FA98839-5 Date Sampled: 09/09/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8260D Percent Solids: n/a a
Project: PPD; Harnett St, Wilmington, NC
VOA List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
10061-02-6
trans- 1, 3-Dichloropropene
ND
3.8
0.77
ug/kg
108-20-3
Di -Isopropyl Ether
ND
3.8
1.8
ug/kg
64-17-5
Ethyl Alcohol °
ND
310
58
ug/kg
100-41-4
Ethylbenzene
ND
3.8
0.77
ug/kg
591-78-6
2-Hexanone
ND
19
5.8
ug/kg
98-82-8
Isopropylbenzene
ND
3.8
0.77
ug/kg
99-87-6
p-Isopropyltoluene
1.1
3.8
0.77
ug/kg J
74-83-9
Methyl Bromide
ND
3.8
1.5
ug/kg
74-87-3
Methyl Chloride
ND
3.8
1.5
ug/kg
75-09-2
Methylene Chloride b
ND
15
8.4
ug/kg
108-10-1
4-Methyl-2-pentanone (MIBK) ND
19
5.8
ug/kg
1634-04-4
Methyl Tert Butyl Ether
ND
3.8
0.77
ug/kg
91-20-3
Naphthalene
ND
3.8
1.5
ug/kg
103-65-1
n-Propylbenzene
ND
3.8
0.77
ug/kg
100-42-5
Styrene
ND
3.8
0.77
ug/kg
630-20-6
1, 1, 1, 2-Tetrachloroethane
ND
3.8
0.79
ug/kg
79-34-5
1,1,2,2-Tetrachloroethane
ND
3.8
0.77
ug/kg
127-18-4
Tetrachloroethylene
ND
3.8
0.98
ug/kg
108-88-3
Toluene
ND
15
7.7
ug/kg
87-61-6
1, 2,3 -Trichlorobenzene
ND
3.8
1.1
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
3.8
0.77
ug/kg
71-55-6
1, 1, 1 -Trichloroethane
ND
3.8
0.77
ug/kg
79-00-5
1,1,2-Trichloroethane
ND
3.8
0.77
ug/kg
79-01-6
Trichloroethylene
ND
3.8
0.77
ug/kg
75-69-4
Trichlorofluoromethane
ND
3.8
1.5
ug/kg
96-18-4
1, 2,3 -Trichloropropane
ND
3.8
0.96
ug/kg
95-63-6
1,2,4-Trimethylbenzene
ND
3.8
0.77
ug/kg
108-67-8
1,3,5-Trimethylbenzene
ND
3.8
0.77
ug/kg
108-05-4
Vinyl Acetate
ND
19
13
ug/kg
75-01-4
Vinyl Chloride
ND
3.8
0.77
ug/kg
m,p-Xylene
ND
7.7
0.84
ug/kg
95-47-6
o-Xylene
ND
3.8
0.77
ug/kg
1330-20-7
Xylene (total)
ND
12
1.6
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
1868-53-7
Dibromofluoromethane
98%
75-124%
17060-07-0
1,2-Dichloroethane-D4
106%
72-135%
2037-26-5
Toluene-D8
100%
75-126%
460-00-4
4-Bromofluorobenzene
108%
71-133%
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS22 of 122
FA98839

SGS North America Inc.
Report of Analysis
Client Sample ID: Z6-5-1-1.5
Lab Sample ID: FA98839-5 Date Sampled: 09/09/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8260D Percent Solids: n/a a
Project: PPD; Harnett St, Wilmington, NC
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(a) All results reported on a wet weight basis.
(b) Associated Initial Calibration outside control limits (%RSD > 15%); sample is ND.
(c) Associated ICV outside control limits low, however sample ND.
Page 3 of 3 P
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
SGS23 of 122
FA98839

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: Z6-0-2
Lab Sample ID: FA98839-6 Date Sampled: 09/09/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 91.2
Project: PPD; Harnett St, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 X084003.13 1 09/15/22 19:49 KA 09/14/22 07:30 OP93050 SX3330
Run #2
Initial Weight Final Volume
Run#1 30.2g 1.0ml
Run #2
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
65-85-0
Benzoic Acid
ND
830
170
ug/kg
59-50-7
4-Chloro-3-methyl Phenol
ND
170
19
ug/kg
95-57-8
2-Chlorophenol
ND
170
20
ug/kg
120-83-2
2,4-Dichlorophenol
ND
170
19
ug/kg
105-67-9
2,4-Dimethylphenol
ND
170
44
ug/kg
51-28-5
2,4-Dinitrophenol
ND
830
170
ug/kg
534-52-1
4,6-Dinitro-o-cresol
ND
330
66
ug/kg
95-48-7
2-Methylphenol
ND
170
20
ug/kg
3&4-Methylphenol
ND
170
27
ug/kg
88-75-5
2-Nitrophenol
ND
170
18
ug/kg
100-02-7
4-Nitrophenol
ND
830
170
ug/kg
87-86-5
Pentachlorophenol
ND
830
170
ug/kg
108-95-2
Phenol
ND
170
17
ug/kg
88-06-2
2,4,6-Trichlorophenol
ND
170
19
ug/kg
83-32-9
Acenaphthene
ND
170
18
ug/kg
208-96-8
Acenaphthylene
ND
170
17
ug/kg
120-12-7
Anthracene
ND
170
19
ug/kg
56-55-3
Benzo(a)anthracene
26.2
170
17
ug/kg J
50-32-8
Benzo(a)pyrene
24.8
170
20
ug/kg J
205-99-2
Benzo(b)fluoranthene
32.8
170
18
ug/kg J
191-24-2
Benzo(g, h, i)perylene
17.0
170
17
ug/kg J
207-08-9
Benzo(k)fluoranthene
ND
170
22
ug/kg
100-51-6
Benzyl Alcohol
ND
170
17
ug/kg
101-55-3
4-Bromophenyl phenyl ether
ND
170
17
ug/kg
85-68-7
Butyl benzyl phthalate a
ND
170
33
ug/kg
106-47-8
4-Chloroaniline
ND
170
42
ug/kg
111-91-1
bis(2-Chloroethoxy)methane
ND
170
17
ug/kg
111-44-4
bis(2-Chloroethyl)ether
ND
170
19
ug/kg
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
170
21
ug/kg
91-58-7
2-Chloronaphthalene
ND
170
17
ug/kg
7005-72-3
4-Chlorophenyl phenyl ether
ND
170
17
ug/kg
218-01-9
Chrysene
18.4
170
17
ug/kg J
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS24 of 122
FA98839

SGS North America Inc.
Report of Analysis
Client Sample ID: Z6-0-2
Lab Sample ID: FA98839-6 Date Sampled: 09/09/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 91.2
Project: PPD; Harnett St, Wilmington, NC
ABN List for NC, May 2012
CAS No.
Compound
Result
RL
MDL Units Q
53-70-3
Dibenzo(a,h)anthracene
ND
170
21
ug/kg
132-64-9
Dibenzofaran
ND
170
17
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
170
17
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
170
18
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
170
22
ug/kg
91-94-1
3,3'-Dichlorobenzidine
ND
170
39
ug/kg
84-66-2
Diethyl Phthalate
ND
330
33
ug/kg
131-11-3
Dimethyl Phthalate
ND
170
33
ug/kg
117-84-0
Di-n-octyl Phthalate a
ND
170
33
ug/kg
84-74-2
Di-n-butyl Phthalate
ND
330
66
ug/kg
122-66-7
1,2-Diphenylhydrazine
ND
170
17
ug/kg
117-81-7
bis(2-Ethylhexyl)phthalate
44.4
330
33
ug/kg J
206-44-0
Fluoranthene
30.9
170
17
ug/kg J
86-73-7
Fluorene
ND
170
18
ug/kg
118-74-1
Hexachlorobenzene b
ND
170
17
ug/kg
87-68-3
Hexachlorobutadiene
ND
170
17
ug/kg
77-47-4
Hexachlorocyclopentadiene
ND
170
33
ug/kg
67-72-1
Hexachloroethane
ND
170
20
ug/kg
193-39-5
Indeno(1,2,3-cd)pyrene
47.9
170
20
ug/kg J
78-59-1
Isophorone
ND
170
17
ug/kg
90-12-0
1-Methylnaphthalene
ND
170
17
ug/kg
91-57-6
2-Methylnaphthalene
ND
170
17
ug/kg
91-20-3
Naphthalene
ND
170
17
ug/kg
98-95-3
Nitrobenzene
ND
170
17
ug/kg
621-64-7
N-Nitrosodi-n-propylamine
ND
170
17
ug/kg
86-30-6
N-Nitrosodiphenylamine
ND
170
18
ug/kg
85-01-8
Phenanthrene
ND
170
17
ug/kg
129-00-0
Pyrene
25.8
170
19
ug/kg J
120-82-1
1,2,4-Trichlorobenzene
ND
170
20
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
367-12-4
2-Fluorophenol
61%
40-102%
4165-62-2
Phenol-d5
63%
41-100%
118-79-6
2,4,6-Tribromophenol
57%
42-108%
4165-60-0
Nitrobenzene-d5
51%
40-105%
321-60-8
2-Fluorobiphenyl
60%
43-107%
1718-51-0
Terphenyl-dl4
69%
45-119%
(a) Associated BS and CCV outside of control limits high, sample was ND.
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS25 of 122
FA98839

SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID: Z6-0-2
Lab Sample ID: FA98839-6 Date Sampled: 09/09/22
Matrix: SO - Soil Date Received: 09/10/22
Method: SW846 8270E SW846 3550C Percent Solids: 91.2
Project: PPD; Harnett St, Wilmington, NC
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(b) Associated CCV outside of control limits low.
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
a1��GS 26 of 122
FA98839

SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID: Z6-0-2
Lab Sample ID: FA98839-6 Date Sampled: 09/09/22
Matrix: SO - Soil Date Received: 09/10/22
Percent Solids: 91.2
Project: PPD; Harnett St, Wilmington, NC
Metals Analysis
Analyte Result RL
Units
DF
Prep
Analyzed
By
Method
Prep Method
Arsenic 1.8 0.45
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050E 4
Barium 16.3 8.9
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Cadmium < 0.18 0.18
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050E 4
Chromium 4.4 0.45
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Lead 27.2 0.89
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Mercury 0.21 0.037
mg/kg
1
09/15/22
09/15/22
JC
SW846 7471B 1
SW846 7471B 3
Selenium < 0.89 0.89
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Silver < 0.45 0.45
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
(1) Instrument QC Batch: MA18914
(2) Instrument QC Batch: MA18920
(3) Prep QC Batch: MP41212
(4) Prep QC Batch: MP41216
RL = Reporting Limit
a1��GS 27 of 122
FA98839

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:
DUP-20220909
Lab Sample ID:
FA98839-7 Date Sampled: 09/09/22
Matrix:
SO - Soil Date Received: 09/10/22
Method:
SW846 8260D Percent Solids: 91.1
Project:
PPD; Harnett St, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3C183799.D 1 09/21/22 20:42 DB n/a n/a V3C873
Run #2
Initial Weight Final Volume
Run # 1 6.94 g 5.0 ml
Run #2
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
67-64-1
Acetone
172
160
79
ug/kg
71-43-2
Benzene
ND
4.0
0.96
ug/kg
108-86-1
Bromobenzene
ND
4.0
0.79
ug/kg
74-97-5
Bromochloromethane
ND
4.0
1.2
ug/kg
75-27-4
Bromodichloromethane
ND
4.0
0.79
ug/kg
75-25-2
Bromoform
ND
4.0
0.79
ug/kg
78-93-3
2-Butanone (MEK)
ND
20
5.7
ug/kg
104-51-8
n-Butylbenzene
ND
4.0
0.79
ug/kg
135-98-8
sec-Butylbenzene
ND
4.0
0.79
ug/kg
98-06-6
tert-Butylbenzene
ND
4.0
0.79
ug/kg
56-23-5
Carbon Tetrachloride
ND
4.0
0.81
ug/kg
108-90-7
Chlorobenzene
ND
4.0
0.79
ug/kg
75-00-3
Chloroethane a
ND
4.0
1.6
ug/kg
67-66-3
Chloroform
ND
4.0
1.1
ug/kg
95-49-8
o-Chlorotoluene
ND
4.0
0.79
ug/kg
106-43-4
p-Chlorotoluene
ND
4.0
0.79
ug/kg
124-48-1
Dibromochloromethane
ND
4.0
0.79
ug/kg
106-93-4
1,2-Dibromoethane
ND
4.0
0.79
ug/kg
75-71-8
Dichlorodifluoromethane
ND
4.0
1.6
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
4.0
0.79
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
4.0
0.79
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
4.0
0.91
ug/kg
75-34-3
1, 1 -Dichloroethane
ND
4.0
1.4
ug/kg
107-06-2
1,2-Dichloroethane
ND
4.0
0.79
ug/kg
75-35-4
1, 1 -Dichloroethylene
ND
4.0
0.79
ug/kg
156-59-2
cis-1,2-Dichloroethylene
ND
4.0
1.1
ug/kg
156-60-5
trans- 1, 2-Dichloroethylene
ND
4.0
0.79
ug/kg
78-87-5
1,2-Dichloropropane
ND
4.0
0.79
ug/kg
142-28-9
1,3-Dichloropropane
ND
4.0
0.79
ug/kg
594-20-7
2,2-Dichloropropane
ND
4.0
0.79
ug/kg
563-58-6
1, 1 -Dichloropropene
ND
4.0
0.81
ug/kg
10061-01-5
cis- 1, 3 -Dichloropropene
ND
4.0
0.79
ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
a1��GS 28 of 122
FA98839

SGS North America Inc.
Report of Analysis
Page 2 of 3
Client Sample ID:
DUP-20220909
Lab Sample ID:
FA98839-7 Date Sampled: 09/09/22
Matrix:
SO - Soil Date Received: 09/10/22
Method:
SW846 8260D Percent Solids: 91.1
Project:
PPD; Harnett St, Wilmington, NC
VOA List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
10061-02-6
trans- 1, 3-Dichloropropene
ND
4.0
0.79
ug/kg
108-20-3
Di -Isopropyl Ether
ND
4.0
1.8
ug/kg
64-17-5
Ethyl Alcohol b
ND
320
59
ug/kg
100-41-4
Ethylbenzene
ND
4.0
0.79
ug/kg
591-78-6
2-Hexanone
ND
20
5.9
ug/kg
98-82-8
Isopropylbenzene
ND
4.0
0.79
ug/kg
99-87-6
p-Isopropyltoluene
1.8
4.0
0.79
ug/kg J
74-83-9
Methyl Bromide
ND
4.0
1.6
ug/kg
74-87-3
Methyl Chloride
ND
4.0
1.6
ug/kg
75-09-2
Methylene Chloride a
ND
16
8.7
ug/kg
108-10-1
4-Methyl-2-pentanone (MIBK) ND
20
5.9
ug/kg
1634-04-4
Methyl Tert Butyl Ether
ND
4.0
0.79
ug/kg
91-20-3
Naphthalene
ND
4.0
1.6
ug/kg
103-65-1
n-Propylbenzene
ND
4.0
0.79
ug/kg
100-42-5
Styrene
ND
4.0
0.79
ug/kg
630-20-6
1, 1, 1, 2-Tetrachloroethane
ND
4.0
0.81
ug/kg
79-34-5
1,1,2,2-Tetrachloroethane
ND
4.0
0.79
ug/kg
127-18-4
Tetrachloroethylene
ND
4.0
1.0
ug/kg
108-88-3
Toluene
ND
16
7.9
ug/kg
87-61-6
1, 2,3 -Trichlorobenzene
ND
4.0
1.1
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
4.0
0.79
ug/kg
71-55-6
1, 1, 1 -Trichloroethane
ND
4.0
0.79
ug/kg
79-00-5
1,1,2-Trichloroethane
ND
4.0
0.79
ug/kg
79-01-6
Trichloroethylene
ND
4.0
0.79
ug/kg
75-69-4
Trichlorofluoromethane
ND
4.0
1.6
ug/kg
96-18-4
1, 2,3 -Trichloropropane
ND
4.0
0.99
ug/kg
95-63-6
1,2,4-Trimethylbenzene
ND
4.0
0.79
ug/kg
108-67-8
1,3,5-Trimethylbenzene
ND
4.0
0.79
ug/kg
108-05-4
Vinyl Acetate
ND
20
13
ug/kg
75-01-4
Vinyl Chloride
ND
4.0
0.79
ug/kg
m,p-Xylene
ND
7.9
0.87
ug/kg
95-47-6
o-Xylene
ND
4.0
0.79
ug/kg
1330-20-7
Xylene (total)
ND
12
1.7
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
1868-53-7
Dibromofluoromethane
100%
75-124%
17060-07-0
1,2-Dichloroethane-D4
110%
72-135%
2037-26-5
Toluene-D8
98%
75-126%
460-00-4
4-Bromofluorobenzene
106%
71-133%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS29 of 122
FA98839

SGS North America Inc.
Report of Analysis
Page 3 of 3 P
Client Sample ID:
DUP-20220909
Lab Sample ID:
FA98839-7 Date Sampled: 09/09/22
Matrix:
SO - Soil Date Received: 09/10/22
Method:
SW846 8260D Percent Solids: 91.1
Project:
PPD; Harnett St, Wilmington, NC
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(a) Associated Initial Calibration outside control limits (%RSD > 15%); sample is ND.
(b) Associated ICV outside control limits low, however sample ND.
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
SGS30 of 122
FA98839

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:
DUP-20220909
Lab Sample ID:
FA98839-7 Date Sampled: 09/09/22
Matrix:
SO - Soil Date Received: 09/10/22
Method:
SW846 8270E SW846 3550C Percent Solids: 91.1
Project:
PPD; Harnett St, Wilmington, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 X084004.13 1 09/15/22 20:16 KA 09/14/22 07:30 OP93050 SX3330
Run #2
Initial Weight Final Volume
Run#1 30.0g 1.0ml
Run #2
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units
65-85-0
Benzoic Acid
ND
910
180
ug/kg
59-50-7
4-Chloro-3-methyl Phenol
ND
180
21
ug/kg
95-57-8
2-Chlorophenol
ND
180
22
ug/kg
120-83-2
2,4-Dichlorophenol
ND
180
21
ug/kg
105-67-9
2,4-Dimethylphenol
ND
180
49
ug/kg
51-28-5
2,4-Dinitrophenol
ND
910
180
ug/kg
534-52-1
4,6-Dinitro-o-cresol
ND
370
73
ug/kg
95-48-7
2-Methylphenol
ND
180
22
ug/kg
3&4-Methylphenol
ND
180
30
ug/kg
88-75-5
2-Nitrophenol
ND
180
20
ug/kg
100-02-7
4-Nitrophenol
ND
910
180
ug/kg
87-86-5
Pentachlorophenol
ND
910
180
ug/kg
108-95-2
Phenol
ND
180
18
ug/kg
88-06-2
2,4,6-Trichlorophenol
ND
180
21
ug/kg
83-32-9
Acenaphthene
ND
180
19
ug/kg
208-96-8
Acenaphthylene
ND
180
18
ug/kg
120-12-7
Anthracene
ND
180
20
ug/kg
56-55-3
Benzo(a)anthracene
ND
180
18
ug/kg
50-32-8
Benzo(a)pyrene
ND
180
22
ug/kg
205-99-2
Benzo(b)fluoranthene
24.3
180
20
ug/kg
191-24-2
Benzo(g, h, i)perylene
ND
180
19
ug/kg
207-08-9
Benzo(k)fluoranthene
ND
180
24
ug/kg
100-51-6
Benzyl Alcohol
ND
180
18
ug/kg
101-55-3
4-Bromophenyl phenyl ether
ND
180
19
ug/kg
85-68-7
Butyl benzyl phthalate a
ND
180
37
ug/kg
106-47-8
4-Chloroaniline
ND
180
46
ug/kg
111-91-1
bis(2-Chloroethoxy)methane
ND
180
18
ug/kg
111-44-4
bis(2-Chloroethyl)ether
ND
180
21
ug/kg
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
180
23
ug/kg
91-58-7
2-Chloronaphthalene
ND
180
18
ug/kg
7005-72-3
4-Chlorophenyl phenyl ether
ND
180
18
ug/kg
218-01-9
Chrysene
ND
180
19
ug/kg
01
J
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS31 of 122
FA98839

SGS North America Inc.
Report of Analysis
Page 2 of 3
Client Sample ID:
DUP-20220909
Lab Sample ID:
FA98839-7 Date Sampled: 09/09/22
Matrix:
SO - Soil Date Received: 09/10/22
Method:
SW846 8270E SW846 3550C Percent Solids: 91.1
Project:
PPD; Harnett St, Wilmington, NC
ABN List for NC, May 2012
CAS No.
Compound
Result
RL
MDL Units Q
53-70-3
Dibenzo(a,h)anthracene
ND
180
23
ug/kg
132-64-9
Dibenzofaran
ND
180
18
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
180
18
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
180
20
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
180
24
ug/kg
91-94-1
3,3'-Dichlorobenzidine
ND
180
44
ug/kg
84-66-2
Diethyl Phthalate
ND
370
37
ug/kg
131-11-3
Dimethyl Phthalate
ND
180
37
ug/kg
117-84-0
Di-n-octyl Phthalate a
ND
180
37
ug/kg
84-74-2
Di-n-butyl Phthalate
ND
370
73
ug/kg
122-66-7
1,2-Diphenylhydrazine
ND
180
18
ug/kg
117-81-7
bis(2-Ethylhexyl)phthalate
59.9
370
37
ug/kg J
206-44-0
Fluoranthene
ND
180
18
ug/kg
86-73-7
Fluorene
ND
180
20
ug/kg
118-74-1
Hexachlorobenzene b
ND
180
19
ug/kg
87-68-3
Hexachlorobutadiene
ND
180
19
ug/kg
77-47-4
Hexachlorocyclopentadiene
ND
180
37
ug/kg
67-72-1
Hexachloroethane
ND
180
22
ug/kg
193-39-5
Indeno(1,2,3-cd)pyrene
33.2
180
22
ug/kg J
78-59-1
Isophorone
ND
180
18
ug/kg
90-12-0
1-Methylnaphthalene
ND
180
18
ug/kg
91-57-6
2-Methylnaphthalene
ND
180
18
ug/kg
91-20-3
Naphthalene
ND
180
18
ug/kg
98-95-3
Nitrobenzene
ND
180
18
ug/kg
621-64-7
N-Nitrosodi-n-propylamine
ND
180
18
ug/kg
86-30-6
N-Nitrosodiphenylamine
ND
180
20
ug/kg
85-01-8
Phenanthrene
ND
180
18
ug/kg
129-00-0
Pyrene
ND
180
21
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
180
22
ug/kg
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
367-12-4
2-Fluorophenol
70%
40-102%
4165-62-2
Phenol-d5
71%
41-100%
118-79-6
2,4,6-Tribromophenol
64%
42-108%
4165-60-0
Nitrobenzene-d5
60%
40-105%
321-60-8
2-Fluorobiphenyl
70%
43-107%
1718-51-0
Terphenyl-dl4
88%
45-119%
(a) Associated BS and CCV outside of control limits high, sample was ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS32 of 122
FA98839

SGS North America Inc.
Report of Analysis Page 3 of 3 P
Client Sample ID:
DUP-20220909
Lab Sample ID:
FA98839-7 Date Sampled: 09/09/22
Matrix:
SO - Soil Date Received: 09/10/22
Method:
SW846 8270E SW846 3550C Percent Solids: 91.1
Project:
PPD; Harnett St, Wilmington, NC
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(b) Associated CCV outside of control limits low.
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
SGS33 of 122
FA98839

SGS North America Inc.
Report of Analysis Page 1 of 1 P
Client Sample ID:
DUP-20220909
Lab Sample ID:
FA98839-7 Date Sampled: 09/09/22
Matrix:
SO - Soil Date Received: 09/10/22
Percent Solids: 91.1
Project:
PPD; Harnett St, Wilmington, NC
Metals Analysis
Analyte Result RL
Units
DF
Prep
Analyzed
By
Method
Prep Method
Arsenic 1.8 0.48
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Barium 13.9 9.6
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Cadmium < 0.19 0.19
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Chromium 4.0 0.48
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Lead 24.9 0.96
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Mercury 0.19 0.046
mg/kg
1
09/15/22
09/15/22
JC
SW846 7471B 1
SW846 7471B 3
Selenium < 0.96 0.96
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
Silver < 0.48 0.48
mg/kg
1
09/15/22
09/16/22
LM
SW846 6010D 2
SW846 3050B 4
(1) Instrument QC Batch: MA18914
(2) Instrument QC Batch: MA18920
(3) Prep QC Batch: MP41213
(4) Prep QC Batch: MP41216
RL = Reporting Limit
SGS34 of 122
FA98839

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: DRUM
Lab Sample ID: FA98839-8 Date Sampled: 09/09/22
Matrix: AQ - Water Date Received: 09/10/22
Method: SW846 8260D Percent Solids: n/a
Project: PPD; Harnett St, Wilmington, NC
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
Run #1 a 5E34178.D
1
09/16/22 19:45
CF
n/a
n/a
V5E1556
Run #2 b 2P93160.D
10
09/20/22 20:15
CF
n/a
n/a
V2P3580
Purge Volume
Run #1 5.0 ml
Run #2 5.0 ml
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
67-64-1
Acetone
761 c
250
100
ug/1
71-43-2
Benzene
ND c
10
3.1
ug/1
108-86-1
Bromobenzene
ND c
10
3.7
ug/1
74-97-5
Bromochloromethane
ND c
10
4.5
ug/1
75-27-4
Bromodichloromethane
ND c
10
2.4
ug/1
75-25-2
Bromoform
ND c
10
4.1
ug/1
78-93-3
2-Butanone (MEK)
50.3 °
50
20
ug/1
104-51-8
n-Butylbenzene
ND °
10
2.3
ug/1
135-98-8
sec-Butylbenzene
ND °
10
2.4
ug/1
98-06-6
tert-Butylbenzene
ND °
10
3.1
ug/1
56-23-5
Carbon Tetrachloride
ND °
10
3.6
ug/1
108-90-7
Chlorobenzene
ND °
10
2.0
ug/1
75-00-3
Chloroethane
ND °
20
6.7
ug/1
67-66-3
Chloroform
ND °
10
3.0
ug/1
95-49-8
o-Chlorotoluene
ND °
10
2.2
ug/1
106-43-4
p-Chlorotoluene
ND °
10
3.1
ug/1
124-48-1
Dibromochloromethane
ND c
10
2.8
ug/1
106-93-4
1,2-Dibromoethane
ND c
20
2.8
ug/1
75-71-8
Dichlorodifluoromethane d
ND c
20
5.0
ug/1
95-50-1
1,2-Dichlorobenzene
ND c
10
3.2
ug/1
541-73-1
1,3-Dichlorobenzene
ND c
10
2.2
ug/1
106-46-7
1,4-Dichlorobenzene
ND c
10
2.6
ug/1
75-34-3
1, 1 -Dichloroethane
ND c
10
3.4
ug/1
107-06-2
1,2-Dichloroethane
ND c
10
3.1
ug/1
75-35-4
1, 1 -Dichloroethylene
ND °
10
3.2
ug/1
156-59-2
cis-1,2-Dichloroethylene
ND °
10
2.8
ug/1
156-60-5
trans- 1, 2-Dichloroethylene
ND °
10
2.2
ug/1
78-87-5
1,2-Dichloropropane
ND °
10
4.3
ug/1
142-28-9
1,3-Dichloropropane
ND °
10
3.1
ug/1
594-20-7
2,2-Dichloropropane
ND °
10
2.4
ug/1
563-58-6
1, 1 -Dichloropropene
ND °
10
3.4
ug/1
10061-01-5
cis- 1, 3-Dichloropropene
ND °
10
2.9
ug/1
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
w
00
SGS35 of 122
FA98839

SGS North America Inc.
Report of Analysis
Client Sample ID: DRUM
Lab Sample ID: FA98839-8 Date Sampled: 09/09/22
Matrix: AQ - Water Date Received: 09/10/22
Method: SW846 8260D Percent Solids: n/a
Project: PPD; Harnett St, Wilmington, NC
VOA List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
10061-02-6
trans- 1, 3-Dichloropropene
ND °
10
2.1
ug/1
108-20-3
Di -Isopropyl Ether
ND °
10
2.4
ug/1
64-17-5
Ethyl Alcohol
ND °
2000
820
ug/1
100-41-4
Ethylbenzene
ND °
10
3.6
ug/1
591-78-6
2-Hexanone
ND °
100
20
ug/1
98-82-8
Isopropylbenzene
ND °
10
2.2
ug/1
99-87-6
p-Isopropyltoluene
ND °
10
2.1
ug/1
74-83-9
Methyl Bromide
ND c
50
20
ug/1
74-87-3
Methyl Chloride
ND c
20
5.0
ug/1
75-09-2
Methylene Chloride
ND c
50
20
ug/1
108-10-1
4-Methyl-2-pentanone (MIBK)
ND °
50
10
ug/1
1634-04-4
Methyl Tert Butyl Ether
ND c
10
2.3
ug/1
91-20-3
Naphthalene
ND c
50
10
ug/1
103-65-1
n-Propylbenzene
ND c
10
2.9
ug/1
100-42-5
Styrene
ND c
10
2.2
ug/1
630-20-6
1, 1, 1, 2-Tetrachloroethane
ND °
10
2.8
ug/1
79-34-5
1,1,2,2-Tetrachloroethane
ND °
10
3.0
ug/1
127-18-4
Tetrachloroethylene
ND °
10
2.2
ug/1
108-88-3
Toluene
ND °
10
3.0
ug/1
87-61-6
1, 2,3 -Trichlorobenzene
ND °
20
6.1
ug/1
120-82-1
1,2,4-Trichlorobenzene
ND °
20
5.0
ug/1
71-55-6
1, 1, 1 -Trichloroethane
ND °
10
2.5
ug/1
79-00-5
1,1,2-Trichloroethane
ND °
10
4.7
ug/1
79-01-6
Trichloroethylene
ND °
10
3.5
ug/1
75-69-4
Trichlorofluoromethane d
ND c
20
5.0
ug/1
96-18-4
1,2,3-Trichloropropane
ND c
20
6.3
ug/1
95-63-6
1,2,4-Trimethylbenzene
ND c
10
3.2
ug/1
108-67-8
1,3,5-Trimethylbenzene
ND c
10
2.7
ug/1
108-05-4
Vinyl Acetate
ND °
100
20
ug/1
75-01-4
Vinyl Chloride
ND c
10
4.1
ug/1
m,p-Xylene
ND c
20
4.7
ug/1
95-47-6
o-Xylene
ND c
10
2.6
ug/1
1330-20-7
Xylene (total)
ND °
30
7.2
ug/1
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
1868-53-7
Dibromofluoromethane
0% e
94%
83-118%
17060-07-0
1,2-Dichloroethane-D4
0% e
94%
79-125%
2037-26-5
Toluene-D8
93%
98%
85-112%
460-00-4
4-Bromofluorobenzene
95%
117%
83-118%
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
w
00
SGS36 of 122
FA98839

SGS North America Inc.
Report of Analysis
Client Sample ID: DRUM
Lab Sample ID: FA98839-8 Date Sampled: 09/09/22
Matrix: AQ - Water Date Received: 09/10/22
Method: SW846 8260D Percent Solids: n/a
Project: PPD; Harnett St, Wilmington, NC
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(a) Sample was treated with an anti -foaming agent.
(b) Sample was treated with an anti -foaming agent. Dilution required due to matrix interference (surrogate
standard failure, sample foamed). Sample vial(s) contained significant headspace.
(c) Result is from Run# 2
(d) Associated CCV outside control limits high, sample is ND.
(e) Outside control limits due to matrix interference.
Page 3 of 3 w
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
SGS37 of 122
FA98839

SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID: DRUM
Lab Sample ID: FA98839-8 Date Sampled: 09/09/22
Matrix: AQ - Water Date Received: 09/10/22
Method: SW846 8270E SW846 3510C Percent Solids: n/a
Project: PPD; Harnett St, Wilmington, NC
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
Run #1 a 6F15669.D
1
09/14/22 22:38
KA
09/14/22 08:10
OP93061
S6F587
Run #2 b 6F15681.D
5
09/15/22 12:19
KA
09/14/22 08:10
OP93061
S6F588
Initial Volume Final Volume
Run #1 960 ml 1.0 ml
Run #2 960 ml 1.0 ml
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
65-85-0
Benzoic Acid
ND
52
10
ug/1
59-50-7
4-Chloro-3-methyl Phenol
ND
5.2
0.62
ug/1
95-57-8
2-Chlorophenol
ND
5.2
0.66
ug/1
120-83-2
2,4-Dichlorophenol
ND
5.2
0.87
ug/1
105-67-9
2,4-Dimethylphenol
ND
5.2
0.77
ug/1
51-28-5
2,4-Dinitrophenol
ND
26
5.2
ug/1
534-52-1
4,6-Dinitro-o-cresol
ND
10
2.1
ug/1
95-48-7
2-Methylphenol
ND
5.2
0.58
ug/1
3&4-Methylphenol
ND
5.2
1.0
ug/1
88-75-5
2-Nitrophenol
ND
5.2
0.89
ug/1
100-02-7
4-Nitrophenol
ND
26
5.2
ug/1
87-86-5
Pentachlorophenol
ND
26
5.2
ug/1
108-95-2
Phenol
ND
5.2
0.52
ug/1
88-06-2
2,4,6-Trichlorophenol°
ND
5.2
0.78
ug/1
83-32-9
Acenaphthene
ND
5.2
0.65
ug/1
208-96-8
Acenaphthylene
ND
5.2
0.66
ug/1
120-12-7
Anthracene
ND
5.2
0.83
ug/1
56-55-3
Benzo(a)anthracene
ND
5.2
0.79
ug/1
50-32-8
Benzo(a)pyrene
ND
5.2
0.82
ug/1
205-99-2
Benzo(b)fluoranthene
ND
5.2
0.81
ug/1
191-24-2
Benzo(g, h, i)perylene
ND
5.2
0.86
ug/1
207-08-9
Benzo(k)fluoranthene
ND
5.2
0.89
ug/1
100-51-6
Benzyl Alcohol
ND
5.2
0.64
ug/1
101-55-3
4-Bromophenyl Phenyl Ether
ND
5.2
0.88
ug/1
85-68-7
Butyl Benzyl Phthalate
ND
5.2
1.0
ug/1
106-47-8
4-Chloroaniline
ND
5.2
0.66
ug/1
111-91-1
bis(2-Chloroethoxy)methane
ND
5.2
0.84
ug/1
111-44-4
bis(2-Chloroethyl)ether
ND
5.2
0.76
ug/1
108-60-1
2,2'-Oxybis(1-chloropropane)
AND
5.2
0.79
ug/1
91-58-7
2-Chloronaphthalene
ND
5.2
0.53
ug/1
7005-72-3
4-Chlorophenyl Phenyl Ether
ND
5.2
0.56
ug/1
218-01-9
Chrysene
ND
5.2
0.89
ug/1
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
w
i"
GS38 of 122
FA98839

SGS North America Inc.
Report of Analysis
Client Sample ID: DRUM
Lab Sample ID: FA98839-8 Date Sampled: 09/09/22
Matrix: AQ - Water Date Received: 09/10/22
Method: SW846 8270E SW846 3510C Percent Solids: n/a
Project: PPD; Harnett St, Wilmington, NC
ABN List for NC, May 2012
CAS No.
Compound
Result
RL
MDL
Units Q
53-70-3
Dibenzo(a,h)anthracene
ND
5.2
0.84
ug/1
132-64-9
Dibenzofaran
ND
5.2
0.63
ug/1
95-50-1
1,2-Dichlorobenzene
ND
5.2
0.52
ug/1
541-73-1
1,3-Dichlorobenzene
ND
5.2
0.52
ug/1
106-46-7
1,4-Dichlorobenzene
ND
5.2
0.52
ug/1
91-94-1
3,3'-Dichlorobenzidine
ND
5.2
0.67
ug/1
84-66-2
Diethyl Phthalate
ND
5.2
1.0
ug/1
131-11-3
Dimethyl Phthalate
ND
5.2
1.0
ug/1
84-74-2
Di-n-butyl Phthalate
ND
5.2
1.0
ug/1
117-84-0
Di-n-octyl Phthalate
ND
5.2
1.0
ug/1
122-66-7
1,2-Diphenylhydrazine
ND
5.2
0.79
ug/1
117-81-7
bis(2-Ethylhexyl)phthalate
ND
5.2
1.0
ug/1
206-44-0
Fluoranthene
ND
5.2
0.58
ug/1
86-73-7
Fluorene
ND
5.2
0.73
ug/1
118-74-1
Hexachlorobenzene
ND
5.2
0.72
ug/1
87-68-3
Hexachlorobutadiene
ND
5.2
0.52
ug/1
77-47-4
Hexachlorocyclopentadiene °
ND
5.2
1.9
ug/1
67-72-1
Hexachloroethane
ND
5.2
1.7
ug/1
193-39-5
Indeno(1,2,3-cd)pyrene
ND
5.2
0.74
ug/1
78-59-1
Isophorone °
ND
5.2
0.81
ug/1
90-12-0
1-Methylnaphthalene
ND
5.2
0.55
ug/1
91-57-6
2-Methylnaphthalene
ND
5.2
0.63
ug/1
91-20-3
Naphthalene
ND
5.2
0.52
ug/1
98-95-3
Nitrobenzene
ND
5.2
0.97
ug/1
621-64-7
N-Nitrosodi-n-propylamine
ND
5.2
0.70
ug/1
86-30-6
N-Nitrosodiphenylamine
ND
5.2
0.84
ug/1
85-01-8
Phenanthrene
ND
5.2
0.90
ug/1
129-00-0
Pyrene
ND
5.2
0.71
ug/1
120-82-1
1,2,4-Trichlorobenzene c
ND
5.2
1.1
ug/1
CAS No.
Surrogate Recoveries
Run# 1
Run# 2
Limits
367-12-4
2-Fluorophenol
40%
28%
14-67%
4165-62-2
Phenol-d5
30%
24%
10-50%
118-79-6
2,4,6-Tribromophenol
46%
0%
33-118%
4165-60-0
Nitrobenzene-d5
56%
47%
42-108%
321-60-8
2-Fluorobiphenyl
45%
41%
40-106%
1718-51-0
Terphenyl-dl4
14% d
12%
39-121%
(a) Confirmed by reanalysis. Insufficient sample for re -extraction.
Page 2 of 3
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
SGS39 of 122
FA98839

SGS North America Inc.
Report of Analysis
Client Sample ID: DRUM
Lab Sample ID: FA98839-8 Date Sampled: 09/09/22
Matrix: AQ - Water Date Received: 09/10/22
Method: SW846 8270E SW846 3510C Percent Solids: n/a
Project: PPD; Harnett St, Wilmington, NC
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(b) Confirmation run for surrogates.
(c) Associated BS outside control limits high, sample was ND.
(d) Outside control limits.
Page 3 of 3 w
ND
= Not detected MDL = Method Detection Limit
J =
Indicates an estimated value
RL
= Reporting Limit
B =
Indicates analyte found in associated method blank
E =
Indicates value exceeds calibration range
N
= Indicates presumptive evidence of a compound
�GS 40 of 122
a1��V\ FA98839

SGS North America Inc.
Report of Analysis
Client Sample ID: DRUM
Lab Sample ID: FA98839-8 Date Sampled: 09/09/22
Matrix: AQ - Water Date Received: 09/10/22
Percent Solids: n/a
Project: PPD; Harnett St, Wilmington, NC
Total Metals Analysis
Analyte Result RL
Arsenic < 10 10
Barium < 200 200
Cadmium < 5.0 5.0
Chromium 29.4 10
Lead 101 5.0
Mercury < 0.50 0.50
Selenium < 10 10
Silver < 10 10
(1) Instrument QC Batch: MA18920
(2) Instrument QC Batch: MA18928
(3) Prep QC Batch: MP41214
(4) Prep QC Batch: MP41233
RL = Reporting Limit
Page 1 of 1 w
Units DF Prep Analyzed By Method Prep Method
ug/I
1
09/15/22
09/16/22
LM
SW846 6010D 1
SW846 3010A 3
ug/I
1
09/15/22
09/16/22
LM
SW846 6010D 1
SW846 3010A 3
ug/I
1
09/15/22
09/16/22
LM
SW846 6010D 1
SW846 3010A 3
ug/I
1
09/15/22
09/16/22
LM
SW846 6010D 1
SW846 3010A 3
ug/I
1
09/15/22
09/16/22
LM
SW846 6010D 1
SW846 3010A 3
ug/I
1
09/21/22
09/21/22
JC
SW846 7470A 2
SW846 7470A 4
ug/I
1
09/15/22
09/16/22
LM
SW846 6010D 1
SW846 3010A 3
ug/I
1
09/15/22
09/16/22
LM
SW846 6010D 1
SW846 3010A 3
�GS 41 of 122
a1��V\ FA98839

Orlando, FL
Misc. Forms
A — I I
Section 4
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
SGS42 of 122
FA98839

SGS North America Inc - Orlando PAT3 % T 1
_qra Chain of Custody SGS -ORLANDOJOB #: PAGE�OF 41
TEL [phone] PAX: 407-425-0707
Nrwwa ,aim
SGS - ORLANDO Quote # SKIFF #
Client / Reporting Information Pro ect Information
Analytical
Information
Matrix Codes
C pa�yONsme
L �nsw1 A
V�
Project Name: �
x
0 7
-^
J
!
.f.�
�,
(A
Ow - Will mg
water
GW-Grcund
Www_ater
Water
SWSurface
Water
SO -Soil
SL-Sludge
OI - Oil
LIO -Other Liquid
AIRAir
s - Iher Solid
Addr s:.
Street nu`
a
C state: Zip: rZ
1 , 4 a
l 1v
Pr Contact: Ema I• r
Protect#
Phone#:^L
1T
Fax#
Sampler(s) Name(s) (Printed)
Sam ter 1: Sam ter 2:
Client Purchase Order #
SGS
Odando
Sample #
Field ID / Point of Collection
COLLECTION
CONTMNER
INFORMATION
LAB USE ONLV
AloE
nMa
FL
sa ev eoI.
TOTnLa
LEs
rc
_
8
0 3
-
m
0.S
o
6'2
o
x
s
- �- 1- .5
bob
x
Cp- o-- 2
1 o
x
* - 2,y2ZtAuqw
n
x
x
V-%&M
wu
5
Turnaround Time Business days)
Data
Deliverable
Information
Gomments
I
Remark
10 Day (Business) Approved By: / Date:
7 Day
5 Day
3 Day RUSH
2 Day RUSH
1 Day RUSH
Other
Rush T/A Data Available VIA Email or Lablink
COMMERCIAL "A" (RESULTS ONLY)
FCOMMERCIAL"B"(RESULTS PLUS OC)
❑ REDT1 (EPA LEVEL 3)
E]FULLTI (EPA LEVEL 4)
FIEDD'S
C
C ,
n
�n
v V 7
L_
Sample Custody must be
documented below each time samples
thane possession. including
Courtin, delivery.
tin i nad y a p1or1A!lillation
Date Time:
0
Rec¢Iv
2
I tI
Relinquished BylAfflliation
3
Dale Time:
R slued ylAHilla{0 y(101 Z
4
'Relinquished by/Affi iation
5
Date i e.
Received By/Affiliation
e
Relinquished By/Affiliation
7
Date Time_
Received BilA filiation
a
Lab Use Only : Coelar Temneranna fsf Celeius learraciadl! `Y-� / c L h00T7wvnv sss com7eNlenns and-conUdi9lLLs
ORLD-SMT-0001-03-FORM-COC (4}xis Rev 031318
FA98839: Chain of Custody
Page 1 of 4
.SGS
43 of 122
a1��V\ FA98839

SGS Sample Receipt Summary
Job Number: FA98839
Client: GEOSYNTEC CONSULTANTS Project: PPD
Date / Time Received: 9/10/2022 11:00:00 AM Delivery Method:
FEDEX Airbill Ws: 5707 9049 3635
Therm ID: IR 1;
Therm CF: 0.6;
# of Coolers: 1
Cooler Temps (Raw Measured) °C: Cooler
1: (4.2);
Cooler Temps (Corrected) °C: Cooler
1: (4.8);
Cooler Information
Y or
N
Sample Information
Y or
N
N/A
1. Custody Seals Present
V
❑
1. Sample labels present on bottles
❑J
❑
2. Custody Seals Intact
❑d
❑
2. Samples preserved properly
W
❑
3. Temp criteria achieved
❑,i
❑
3. Sufficient volume/containers recvd for analysis:
❑d
❑
4. Cooler temp verification
IR Gun
4. Condition of sample
Intact
5. Cooler media
Ice (Baal
5. Sample recvd within HT
0
❑
6. Dates/Times/IDs on COC match Sample Label
❑�
❑
Trip Blank Information
Y or
N N/A
7. VOCs have headspace
0
❑
❑
1. Trip Blank present / cooler
❑
❑ ❑.6
8. Bottles received for unspecified tests
❑
❑d
2. Trip Blank listed on CDC
❑
❑ ❑,/
9. Compositing instructions clear
❑
❑
W
W
S N/A
10. Voa Soil Kits/Jars received past 48hrs?
❑
❑
0
or
11. % Solids Jar received?
❑
❑
0
3. Type Of TB Received
❑
❑ W
12. Residual Chlorine Present?
❑
❑
W
Misc. Information
Number of Encores: 25-Gram
Test Strip Lot #s: pH 0-3
Residual Chlorine Test Strip Lot #:
5-Gram Number of 5035 Field Kits: Number of Lab Filtered Metals:
230315 pH 10-12 219813A Other: (Specify)
Comments FROZEN @ 09/12/22 H 1115.
DID NOT RECEIVE BULK SOIL JAR FOR % SOLIDS ANALYSIS FOR THE FOLLOWING SAMPLES:
SAMPLE -1, ID: "74-1-0-0.5", SAMPLE -2, ID: "Z4-2-1.5-2", OR SAMPLE -5, ID: "76-5-1-1.5".
FOR SAMPLE -7, ID: "DUP-20220909", RECEIVED TWO NAHSO4 PRESERVED VIALS AND ONE DI H2O PRESERVED VIAL FOR "VOCS" ANALYSIS
INSTEAD OF TWO NAHSO4 VIALS AND ONE MEOH PRESERVED VIAL. DI H2O PRESERVED VIAL WAS FROZEN 09/10/22 AT 1500.
Lr)D 4AMDI G _A Irl- "r)PI Inn" Al I TI-IDGG I -ICI VIAI B DGCGIVGr) %A/ITI-I I-ILArISADCG
Rev. Date 05/24/17 Technician: SAMUELM Date: 9/10/2022 11:00:00 A Reviewer: Date:
Rev. D
FA98839: Chain of Custody
Page 2 of 4
SGS44 of 122
FA98839

Job Change Order: FA98839
Requested Date: 9/13/2022
Account Name: Geosyntec Consultants
Project Description: Kettler; 31 Harnett St, Wilmington, NC
CSR: KB
Sample M FA98839-all
Dept:
TAT: 7
Sample M FA98839-1
Dept:
TAT: 7
Received Date:
9/10/2022
Due Date:
9/19/2022
Deliverable:
COMMB
TAT (Days):
7
Change:
Per client, log in as a new project named "PPD"
Change:
Per client, use %SOL data from FA98839-3
Z4-1-0-0.5
------------------
Sample M FA98839-2 Change:
Dept: Per client, use %SOL data from FA98839-4
TAT: 7
Z4-2-1.5-2
Sample M FA98839-5 Change:
Dept: Per client, use %SOL data from FA98839-6
TAT: 7
Z6-5-1-1.5
-------------------------------------------------------------------------------------------------------------------- 39: Chain of Custody
Above Changes Per: Abby Wesley Date/Time: 9/13/2022 11:33:35 AM Page 3 of 4
To Client: This Change Order is confirmation of the revisions, previously discussed with the Client Service Representative.
Page 1 of 2
�GS 45 of 122
a1��V\ FA98839

Job Change Order:
FA98839
Requested Date:
9/13/2022 Received Date:
9/10/2022
Account Name:
Geosyntec Consultants Due Date:
9/19/2022
Project Description:
Kettler; 31 Harnett St, Wilmington, NC Deliverable:
COMMB
CSR:
KB TAT (Days):
7
--------------------------------------------------------------------------------------------------------------------
Sample #: FA98839- Change:
Dept:
TAT:
Above Changes Per: Abby Wesley Date/Time: 9/13/2022 11:33:35 AM
To Client: This Change Order is confirmation of the revisions, previously discussed with the Client Service Representative.
Page 2 of 2
FA98839: Chain of Custody
Page 4 of 4
SGS46 of 122
FA98839

Orlando, FL
MS Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Section 5
SGS47 of 122
FA98839

Method Blank Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 1
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
V5E1556-MB a
5E34163.1)
1
09/16/22
CF
n/a
n/a
V5E1556
The QC reported here applies to the following samples: Method: SW846 8260D
FA98839-8
CAS No. Compound Result RL MDL Units Q
CAS No.
Surrogate Recoveries
Limits
1868-53-7
Dibromofluoromethane 99%
83-118%
17060-07-0
1,2-Dichloroethane-D4 102%
79-125%
2037-26-5
Toluene-D8 103%
85-112%
460-00-4
4-Bromofluorobenzene 106%
83-118%
CAS No.
Tentatively Identified Compounds
R.T.
Est. Conc. Units Q
124-38-9
Carbon dioxide
2.57
45 ug/1 JN
Total TIC, Volatile
0 ug/1
(a) Sample was treated with an anti -foaming agent.
GS48 of 122
FA98839

Method Blank Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 3
ample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batct
72P3580-MB a
2P93141.D
1
09/20/22
CF
n/a
n/a
V2P3580
The QC reported here applies to the following samples: Method: SW846 8260D
FA98839-8
CAS No. Compound Result RL MDL Units Q
67-64-1
Acetone
ND
25
10
ug/l
71-43-2
Benzene
ND
1.0
0.31
ug/l
108-86-1
Bromobenzene
ND
1.0
0.37
ug/l
74-97-5
Bromochloromethane
ND
1.0
0.45
ug/l
75-27-4
Bromodichloromethane
ND
1.0
0.24
ug/l
75-25-2
Bromoform
ND
1.0
0.41
ug/l
78-93-3
2-Butanone (MEK)
ND
5.0
2.0
ug/l
104-51-8
n-Butylbenzene
ND
1.0
0.23
ug/1
135-98-8
sec-Butylbenzene
ND
1.0
0.24
ug/1
98-06-6
tert-Butylbenzene
ND
1.0
0.31
ug/1
56-23-5
Carbon Tetrachloride
ND
1.0
0.36
ug/1
108-90-7
Chlorobenzene
ND
1.0
0.20
ug/1
75-00-3
Chloroethane
ND
2.0
0.67
ug/1
67-66-3
Chloroform
ND
1.0
0.30
ug/1
95-49-8
o-Chlorotoluene
ND
1.0
0.22
ug/1
106-43-4
p-Chlorotoluene
ND
1.0
0.31
ug/l
124-48-1
Dibromochloromethane
ND
1.0
0.28
ug/l
106-93-4
1,2-Dibromoethane
ND
2.0
0.28
ug/l
75-71-8
Dichlorodifluoromethane
ND
2.0
0.50
ug/l
95-50-1
1,2-Dichlorobenzene
ND
1.0
0.32
ug/l
541-73-1
1,3-Dichlorobenzene
ND
1.0
0.22
ug/l
106-46-7
1,4-Dichlorobenzene
ND
1.0
0.26
ug/l
75-34-3
1, 1 -Dichloroethane
ND
1.0
0.34
ug/1
107-06-2
1,2-Dichloroethane
ND
1.0
0.31
ug/1
75-35-4
1, 1 -Dichloroethylene
ND
1.0
0.32
ug/1
156-59-2
cis- 1, 2-Dichloroethylene
ND
1.0
0.28
ug/1
156-60-5
trans- 1, 2-Dichloroethylene
ND
1.0
0.22
ug/1
78-87-5
1,2-Dichloropropane
ND
1.0
0.43
ug/1
142-28-9
1,3-Dichloropropane
ND
1.0
0.31
ug/1
594-20-7
2,2-Dichloropropane
ND
1.0
0.24
ug/1
563-58-6
1, 1 -Dichloropropene
ND
1.0
0.34
ug/1
10061-01-5 cis-1,3-Dichloropropene
ND
1.0
0.29
ug/1
10061-02-6 trans-1,3-Dichloropropene
ND
1.0
0.21
ug/l
108-20-3
Di -Isopropyl Ether
ND
1.0
0.24
ug/l
64-17-5
Ethyl Alcohol
ND
200
82
ug/l
100-41-4
Ethlbenzene
ND
1.0
0.36
ug/l
�GS 49 of 122
a1��V\ FA98839

Method Blank Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 2 of 3
ample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batct
72P3580-MB a
2P93141.D
1
09/20/22
CF
n/a
n/a
V2P3580
The QC reported here applies to the following samples: Method: SW846 8260D
FA98839-8
CAS No. Compound Result RL MDL Units Q
591-78-6
2-Hexanone
ND
10
2.0
ug/l
98-82-8
Isopropylbenzene
ND
1.0
0.22
ug/l
99-87-6
p-Isopropyltoluene
ND
1.0
0.21
ug/l
74-83-9
Methyl Bromide
ND
5.0
2.0
ug/l
74-87-3
Methyl Chloride
ND
2.0
0.50
ug/l
75-09-2
Methylene Chloride
ND
5.0
2.0
ug/l
108-10-1
4-Methyl-2-pentanone (MIBK) ND
5.0
1.0
ug/l
1634-04-4
Methyl Tert Butyl Ether
ND
1.0
0.23
ug/1
91-20-3
Naphthalene
ND
5.0
1.0
ug/1
103-65-1
n-Propylbenzene
ND
1.0
0.29
ug/1
100-42-5
Styrene
ND
1.0
0.22
ug/1
630-20-6
1, 1, 1, 2-Tetrachloroethane
ND
1.0
0.28
ug/1
79-34-5
1,1,2,2-Tetrachloroethane
ND
1.0
0.30
ug/1
127-18-4
Tetrachloroethylene
ND
1.0
0.22
ug/1
108-88-3
Toluene
ND
1.0
0.30
ug/1
87-61-6
1,2,3-Trichlorobenzene
ND
2.0
0.61
ug/l
120-82-1
1,2,4-Trichlorobenzene
ND
2.0
0.50
ug/l
71-55-6
1, 1, 1 -Trichloroethane
ND
1.0
0.25
ug/l
79-00-5
1,1,2-Trichloroethane
ND
1.0
0.47
ug/l
79-01-6
Trichloroethylene
ND
1.0
0.35
ug/l
75-69-4
Trichlorofluoromethane
ND
2.0
0.50
ug/l
96-18-4
1, 2,3 -Trichloropropane
ND
2.0
0.63
ug/l
95-63-6
1,2,4-Trimethylbenzene
ND
1.0
0.32
ug/1
108-67-8
1,3,5-Trimethylbenzene
ND
1.0
0.27
ug/1
108-05-4
Vinyl Acetate
ND
10
2.0
ug/1
75-01-4
Vinyl Chloride
ND
1.0
0.41
ug/1
m,p-Xylene
ND
2.0
0.47
ug/1
95-47-6
o-Xylene
ND
1.0
0.26
ug/1
1330-20-7
Xylene (total)
ND
3.0
0.72
ug/1
CAS No.
Surrogate Recoveries
Limits
1868-53-7
Dibromofluoromethane
93%
83-118%
17060-07-0
1,2-Dichloroethane-D4
95%
79-125%
2037-26-5
Toluene-D8
98%
85-112%
SGS50 of 122
FA98839

Method Blank Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 3 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
V2P3580-MB a
2P93141.D
1
09/20/22
CF
n/a
n/a
V21`3580
The QC reported here applies to the following samples:
FA98839-8
CAS No. Surrogate Recoveries
460-00-4 4-Bromofluorobenzene 99%
CAS No. Tentatively Identified Compounds
124-38-9 Carbon dioxide
124-38-9 Carbon dioxide
Total TIC, Volatile
(a) Sample was treated with an anti -foaming agent.
Method: SW846 8260D
Limits
83-118%
R.T. Est. Conc.
Units Q
1.02 14
ug/1 JN
1.04 17
ug/1 JN
0
ug/1
SGS51 of 122
FA98839

Method Blank Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
V3C873-MB
3C183783.1)
1
09/21/22
DB
n/a
n/a
V3C873
The QC reported here applies to the following samples: Method: SW846 8260D
FA98839-1, FA98839-5, FA98839-7
CAS No. Compound
Result RL MDL Units Q
67-64-1
Acetone
ND
200
100
ug/kg
71-43-2
Benzene
ND
5.0
1.2
ug/kg
108-86-1
Bromobenzene
ND
5.0
1.0
ug/kg
74-97-5
Bromochloromethane
ND
5.0
1.5
ug/kg
75-27-4
Bromodichloromethane
ND
5.0
1.0
ug/kg
75-25-2
Bromoform
ND
5.0
1.0
ug/kg
78-93-3
2-Butanone (MEK)
ND
25
7.3
ug/kg
104-51-8
n-Butylbenzene
ND
5.0
1.0
ug/kg
135-98-8
sec-Butylbenzene
ND
5.0
1.0
ug/kg
98-06-6
tert-Butylbenzene
ND
5.0
1.0
ug/kg
56-23-5
Carbon Tetrachloride
ND
5.0
1.0
ug/kg
108-90-7
Chlorobenzene
ND
5.0
1.0
ug/kg
75-00-3
Chloroethane
ND
5.0
2.0
ug/kg
67-66-3
Chloroform
ND
5.0
1.3
ug/kg
95-49-8
o-Chlorotoluene
ND
5.0
1.0
ug/kg
106-43-4
p-Chlorotoluene
ND
5.0
1.0
ug/kg
124-48-1
Dibromochloromethane
ND
5.0
1.0
ug/kg
106-93-4
1,2-Dibromoethane
ND
5.0
1.0
ug/kg
75-71-8
Dichlorodifluoromethane
ND
5.0
2.0
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
5.0
1.0
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
5.0
1.0
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
5.0
1.2
ug/kg
75-34-3
1, 1 -Dichloroethane
ND
5.0
1.8
ug/kg
107-06-2
1,2-Dichloroethane
ND
5.0
1.0
ug/kg
75-35-4
1, 1 -Dichloroethylene
ND
5.0
1.0
ug/kg
156-59-2
cis- 1, 2-Dichloroethylene
ND
5.0
1.4
ug/kg
156-60-5
trans- 1, 2-Dichloroethylene
ND
5.0
1.0
ug/kg
78-87-5
1,2-Dichloropropane
ND
5.0
1.0
ug/kg
142-28-9
1,3-Dichloropropane
ND
5.0
1.0
ug/kg
594-20-7
2,2-Dichloropropane
ND
5.0
1.0
ug/kg
563-58-6
1, 1 -Dichloropropene
ND
5.0
1.0
ug/kg
10061-01-5 cis-1,3-Dichloropropene
ND
5.0
1.0
ug/kg
10061-02-6 trans-1,3-Dichloropropene
ND
5.0
1.0
ug/kg
108-20-3
Di -Isopropyl Ether
ND
5.0
2.3
ug/kg
64-17-5
Ethyl Alcohol
ND
400
75
ug/kg
100-41-4
Ethlbenzene
ND
5.0
1.0
ug/kg
is
0
SGS52 of 122
FA98839

Method Blank Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 2 of 3
ample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batct
73C873-MB
3C183783.1)
1
09/21/22
DB
n/a
n/a
V3C873
The QC reported here applies to the following samples: Method: SW846 8260D
FA98839-1, FA98839-5, FA98839-7
CAS No. Compound Result RL MDL Units Q
591-78-6
2-Hexanone
ND
25
7.5
ug/kg
98-82-8
Isopropylbenzene
ND
5.0
1.0
ug/kg
99-87-6
p-Isopropyltoluene
ND
5.0
1.0
ug/kg
74-83-9
Methyl Bromide
ND
5.0
2.0
ug/kg
74-87-3
Methyl Chloride
ND
5.0
2.0
ug/kg
75-09-2
Methylene Chloride
ND
20
11
ug/kg
108-10-1
4-Methyl-2-pentanone (MIBK) ND
25
7.5
ug/kg
1634-04-4
Methyl Tert Butyl Ether
ND
5.0
1.0
ug/kg
91-20-3
Naphthalene
ND
5.0
2.0
ug/kg
103-65-1
n-Propylbenzene
ND
5.0
1.0
ug/kg
100-42-5
Styrene
ND
5.0
1.0
ug/kg
630-20-6
1, 1, 1, 2-Tetrachloroethane
ND
5.0
1.0
ug/kg
79-34-5
1,1,2,2-Tetrachloroethane
ND
5.0
1.0
ug/kg
127-18-4
Tetrachloroethylene
ND
5.0
1.3
ug/kg
108-88-3
Toluene
ND
20
10
ug/kg
87-61-6
1,2,3-Trichlorobenzene
ND
5.0
1.4
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
5.0
1.0
ug/kg
71-55-6
1, 1, 1 -Trichloroethane
ND
5.0
1.0
ug/kg
79-00-5
1,1,2-Trichloroethane
ND
5.0
1.0
ug/kg
79-01-6
Trichloroethylene
ND
5.0
1.0
ug/kg
75-69-4
Trichlorofluoromethane
ND
5.0
2.0
ug/kg
96-18-4
1, 2,3 -Trichloropropane
ND
5.0
1.3
ug/kg
95-63-6
1,2,4-Trimethylbenzene
ND
5.0
1.0
ug/kg
108-67-8
1,3,5-Trimethylbenzene
ND
5.0
1.0
ug/kg
108-05-4
Vinyl Acetate
ND
25
16
ug/kg
75-01-4
Vinyl Chloride
ND
5.0
1.0
ug/kg
m,p-Xylene
ND
10
1.1
ug/kg
95-47-6
o-Xylene
ND
5.0
1.0
ug/kg
1330-20-7
Xylene (total)
ND
15
2.1
ug/kg
CAS No.
Surrogate Recoveries
Limits
1868-53-7
Dibromofluoromethane
96%
75-124%
17060-07-0
1,2-Dichloroethane-D4
98%
72-135%
2037-26-5
Toluene-D8
100%
75-126%
is
0
SGS53 of 122
FA98839

Method Blank Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 3 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
V3C873-MB
3C183783.1)
1
09/21/22
DB
n/a
n/a
V3C873
The QC reported here applies to the following samples: Method: SW846 8260D
FA98839-1, FA98839-5, FA98839-7
CAS No. Surrogate Recoveries Limits
460-00-4 4-Bromofluorobenzene 102% 71-133%
SGS54 of 122
FA98839

Method Blank Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
VF3759-MB
170104790.1)
1
09/23/22
DB
n/a
n/a
VF3759
The QC reported here applies to the following samples: Method: SW846 8260D
FA98839-2
CAS No. Compound
Result RL MDL Units Q
67-64-1
Acetone
ND
200
100
ug/kg
71-43-2
Benzene
ND
5.0
1.2
ug/kg
108-86-1
Bromobenzene
ND
5.0
1.0
ug/kg
74-97-5
Bromochloromethane
ND
5.0
1.5
ug/kg
75-27-4
Bromodichloromethane
ND
5.0
1.0
ug/kg
75-25-2
Bromoform
ND
5.0
1.0
ug/kg
78-93-3
2-Butanone (MEK)
ND
25
7.3
ug/kg
104-51-8
n-Butylbenzene
ND
5.0
1.0
ug/kg
135-98-8
sec-Butylbenzene
ND
5.0
1.0
ug/kg
98-06-6
tert-Butylbenzene
ND
5.0
1.0
ug/kg
56-23-5
Carbon Tetrachloride
ND
5.0
1.0
ug/kg
108-90-7
Chlorobenzene
ND
5.0
1.0
ug/kg
75-00-3
Chloroethane
ND
5.0
2.0
ug/kg
67-66-3
Chloroform
ND
5.0
1.3
ug/kg
95-49-8
o-Chlorotoluene
ND
5.0
1.0
ug/kg
106-43-4
p-Chlorotoluene
ND
5.0
1.0
ug/kg
124-48-1
Dibromochloromethane
ND
5.0
1.0
ug/kg
106-93-4
1,2-Dibromoethane
ND
5.0
1.0
ug/kg
75-71-8
Dichlorodifluoromethane
ND
5.0
2.0
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
5.0
1.0
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
5.0
1.0
ug/kg
106-46-7
1,4-Dichlorobenzene
ND
5.0
1.2
ug/kg
75-34-3
1, 1 -Dichloroethane
ND
5.0
1.8
ug/kg
107-06-2
1,2-Dichloroethane
ND
5.0
1.0
ug/kg
75-35-4
1, 1 -Dichloroethylene
ND
5.0
1.0
ug/kg
156-59-2
cis- 1, 2-Dichloroethylene
ND
5.0
1.4
ug/kg
156-60-5
trans- 1, 2-Dichloroethylene
ND
5.0
1.0
ug/kg
78-87-5
1,2-Dichloropropane
ND
5.0
1.0
ug/kg
142-28-9
1,3-Dichloropropane
ND
5.0
1.0
ug/kg
594-20-7
2,2-Dichloropropane
ND
5.0
1.0
ug/kg
563-58-6
1, 1 -Dichloropropene
ND
5.0
1.0
ug/kg
10061-01-5 cis-1,3-Dichloropropene
ND
5.0
1.0
ug/kg
10061-02-6 trans-1,3-Dichloropropene
ND
5.0
1.0
ug/kg
108-20-3
Di -Isopropyl Ether
ND
5.0
2.3
ug/kg
64-17-5
Ethyl Alcohol
ND
400
75
ug/kg
100-41-4
Ethlbenzene
ND
5.0
1.0
ug/kg
SGS55 of 122
FA98839

Method Blank Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 2 of 3
ample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batct
TF3759-MB
F0104790.D
1
09/23/22
DB
n/a
n/a
VF3759
The QC reported here applies to the following samples: Method: SW846 8260D
FA98839-2
CAS No. Compound Result RL MDL Units Q
591-78-6
2-Hexanone
ND
25
7.5
ug/kg
98-82-8
Isopropylbenzene
ND
5.0
1.0
ug/kg
99-87-6
p-Isopropyltoluene
ND
5.0
1.0
ug/kg
74-83-9
Methyl Bromide
ND
5.0
2.0
ug/kg
74-87-3
Methyl Chloride
ND
5.0
2.0
ug/kg
75-09-2
Methylene Chloride
ND
20
11
ug/kg
108-10-1
4-Methyl-2-pentanone (MIBK) ND
25
7.5
ug/kg
1634-04-4
Methyl Tert Butyl Ether
ND
5.0
1.0
ug/kg
91-20-3
Naphthalene
ND
5.0
2.0
ug/kg
103-65-1
n-Propylbenzene
ND
5.0
1.0
ug/kg
100-42-5
Styrene
ND
5.0
1.0
ug/kg
630-20-6
1, 1, 1, 2-Tetrachloroethane
ND
5.0
1.0
ug/kg
79-34-5
1,1,2,2-Tetrachloroethane
ND
5.0
1.0
ug/kg
127-18-4
Tetrachloroethylene
ND
5.0
1.3
ug/kg
108-88-3
Toluene
ND
20
10
ug/kg
87-61-6
1,2,3-Trichlorobenzene
ND
5.0
1.4
ug/kg
120-82-1
1,2,4-Trichlorobenzene
ND
5.0
1.0
ug/kg
71-55-6
1, 1, 1 -Trichloroethane
ND
5.0
1.0
ug/kg
79-00-5
1,1,2-Trichloroethane
ND
5.0
1.0
ug/kg
79-01-6
Trichloroethylene
ND
5.0
1.0
ug/kg
75-69-4
Trichlorofluoromethane
ND
5.0
2.0
ug/kg
96-18-4
1, 2,3 -Trichloropropane
ND
5.0
1.3
ug/kg
95-63-6
1,2,4-Trimethylbenzene
ND
5.0
1.0
ug/kg
108-67-8
1,3,5-Trimethylbenzene
ND
5.0
1.0
ug/kg
108-05-4
Vinyl Acetate
ND
25
16
ug/kg
75-01-4
Vinyl Chloride
ND
5.0
1.0
ug/kg
m,p-Xylene
ND
10
1.1
ug/kg
95-47-6
o-Xylene
ND
5.0
1.0
ug/kg
1330-20-7
Xylene (total)
ND
15
2.1
ug/kg
CAS No.
Surrogate Recoveries
Limits
1868-53-7
Dibromofluoromethane
96%
75-124%
17060-07-0
1,2-Dichloroethane-D4
101%
72-135%
2037-26-5
Toluene-D8
100%
75-126%
SGS56 of 122
FA98839

Method Blank Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 3 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
VF3759-MB
170104790.1)
1
09/23/22
DB
n/a
n/a
VF3759
The QC reported here applies to the following samples: Method: SW846 8260D
FA98839-2
CAS No. Surrogate Recoveries Limits
460-00-4 4-Bromofluorobenzene 98% 71-133%
SGS57 of 122
FA98839

Blank Spike Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 1
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
V5E1556-13S
5E34160.1)
1
09/16/22
CF
n/a
n/a
V5E1556
The QC reported here applies to the following samples: Method: SW846 8260D
FA98839-8
CAS No. Compound
CAS No. Surrogate Recoveries
1868-53-7 Dibromofluoromethane
17060-07-0 1,2-Dichloroethane-D4
2037-26-5 Toluene-D8
460-00-4 4-Bromofluorobenzene
* = Outside of Control Limits.
Spike BSP BSP
ug/1 ug/l % Limits
BSP Limits
102% 83-118%
98% 79-125%
100% 85-112%
100% 83-118%
GS58 of 122
FA98839

Blank Spike Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
V2P3580-BS
2P93138.1)
1
09/20/22
CF
n/a
n/a
V2P3580
The QC reported here applies to the following samples: Method: SW846 8260D
FA98839-8
CAS No. Compound
Spike BSP BSP
ug/1 ug/l % Limits
67-64-1
Acetone
125
104
83
50-147
71-43-2
Benzene
25
27.2
109
81-122
108-86-1
Bromobenzene
25
24.3
97
80-121
74-97-5
Bromochloromethane
25
25.7
103
76-123
75-27-4
Bromodichloromethane
25
26.7
107
79-123
75-25-2
Bromoform
25
24.5
98
66-123
78-93-3
2-Butanone (MEK)
125
125
100
56-143
104-51-8
n-Butylbenzene
25
25.4
102
79-126
135-98-8
sec-Butylbenzene
25
28.0
112
83-133
98-06-6
tert-Butylbenzene
25
25.5
102
80-133
56-23-5
Carbon Tetrachloride
25
27.6
110
76-136
108-90-7
Chlorobenzene
25
26.4
106
82-124
75-00-3
Chloroethane
25
24.1
96
62-144
67-66-3
Chloroform
25
27.4
110
80-124
95-49-8
o-Chlorotoluene
25
24.9
100
81-127
106-43-4
p-Chlorotoluene
25
25.1
100
83-130
124-48-1
Dibromochloromethane
25
24.2
97
78-122
106-93-4
1,2-Dibromoethane
25
25.5
102
75-120
75-71-8
Dichlorodifluoromethane
25
26.9
108
42-167
95-50-1
1,2-Dichlorobenzene
25
25.3
101
82-124
541-73-1
1,3-Dichlorobenzene
25
25.7
103
84-125
106-46-7
1,4-Dichlorobenzene
25
25.1
100
78-120
75-34-3
1,1-Dichloroethane
25
28.4
114
81-122
107-06-2
1,2-Dichloroethane
25
25.6
102
75-125
75-35-4
1, 1 -Dichloroethylene
25
28.4
114
78-137
156-59-2
cis- 1, 2-Dichloroethylene
25
27.3
109
78-120
156-60-5
trans- 1, 2-Dichloroethylene
25
27.2
109
76-127
78-87-5
1,2-Dichloropropane
25
26.1
104
76-124
142-28-9
1,3-Dichloropropane
25
23.2
93
80-118
594-20-7
2,2-Dichloropropane
25
26.3
105
74-139
563-58-6
1, 1 -Dichloropropene
25
27.7
111
79-131
10061-01-5 cis-1,3-Dichloropropene
25
26.3
105
75-118
10061-02-6 trans-1,3-Dichloropropene
25
26.5
106
80-120
108-20-3
Di -Isopropyl Ether
25
26.6
106
68-123
64-17-5
Ethyl Alcohol
500
508
102
46-145
100-41-4
Ethlbenzene
25
26.4
106
81-121
* = Outside of Control Limits.
SGS59 of 122
FA98839

Blank Spike Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 2 of 3
ample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batct
72P3580-BS
2P93138.D
1
09/20/22
CF
n/a
n/a
V2P3580
The QC reported here applies to the following samples:
FA98839-8
Spike
BSP
BSP
CAS No.
Compound
ug/1
ug/l
%
Limits
591-78-6
2-Hexanone
125
133
106
61-129
98-82-8
Isopropylbenzene
25
27.2
109
83-132
99-87-6
p-Isopropyltoluene
25
27.9
112
79-130
74-83-9
Methyl Bromide
25
24.4
98
59-143
74-87-3
Methyl Chloride
25
26.0
104
50-159
75-09-2
Methylene Chloride
25
24.0
96
69-135
108-10-1
4-Methyl-2-pentanone (MIBK) 125
136
109
66-122
1634-04-4
Methyl Tert Butyl Ether
25
26.9
108
72-117
91-20-3
Naphthalene
25
25.2
101
63-132
103-65-1
n-Propylbenzene
25
25.7
103
82-133
100-42-5
Styrene
25
26.2
105
78-119
630-20-6
1, 1, 1, 2-Tetrachloroethane
25
25.9
104
77-122
79-34-5
1,1,2,2-Tetrachloroethane
25
24.4
98
72-120
127-18-4
Tetrachloroethylene
25
27.8
111
76-135
108-88-3
Toluene
25
25.4
102
80-120
87-61-6
1,2,3-Trichlorobenzene
25
26.2
105
68-131
120-82-1
1,2,4-Trichlorobenzene
25
25.9
104
73-129
71-55-6
1, 1, 1 -Trichloroethane
25
27.8
111
75-130
79-00-5
1,1,2-Trichloroethane
25
25.2
101
76-119
79-01-6
Trichloroethylene
25
26.5
106
81-126
75-69-4
Trichlorofluoromethane
25
28.0
112
71-156
96-18-4
1, 2,3 -Trichloropropane
25
22.8
91
77-120
95-63-6
1,2,4-Trimethylbenzene
25
25.4
102
79-120
108-67-8
1,3,5-Trimethylbenzene
25
25.0
100
79-120
108-05-4
Vinyl Acetate
125
106
85
43-154
75-01-4
Vinyl Chloride
25
26.8
107
69-159
m,p-Xylene
50
51.3
103
79-126
95-47-6
o-Xylene
25
26.2
105
80-127
1330-20-7
Xylene (total)
75
77.5
103
80-126
CAS No.
Surrogate Recoveries
BSP
Limits
1868-53-7
Dibromofluoromethane
101%
83-118%
17060-07-0
1,2-Dichloroethane-D4
98%
79-125%
2037-26-5
Toluene-D8
96%
85-112%
* = Outside of Control Limits.
Method: SW846 8260D
SGS60 of 122
FA98839

Blank Spike Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 3 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
V2P3580-13S
2P93138.1)
1
09/20/22
CF
n/a
n/a
V2P3580
The QC reported here applies to the following samples: Method: SW846 8260D
FA98839-8
CAS No. Surrogate Recoveries
460-00-4 4-Bromofluorobenzene
* = Outside of Control Limits.
BSP Limits
99% 83-118%
SGS61 of 122
FA98839

Blank Spike Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
V3C873-BS
3C183781.1)
1
09/21/22
DB
n/a
n/a
V3C873
The QC reported here applies to the following samples: Method: SW846 8260D
FA98839-1, FA98839-5, FA98839-7
CAS No. Compound
Spike BSP BSP
ug/kg ug/kg % Limits
67-64-1
Acetone
250
208
83
61-152
71-43-2
Benzene
50
45.2
90
76-126
108-86-1
Bromobenzene
50
43.4
87
76-122
74-97-5
Bromochloromethane
50
47.8
96
77-120
75-27-4
Bromodichloromethane
50
47.9
96
74-130
75-25-2
Bromoform
50
45.9
92
76-127
78-93-3
2-Butanone (MEK)
250
235
94
75-137
104-51-8
n-Butylbenzene
50
44.1
88
71-128
135-98-8
sec-Butylbenzene
50
47.7
95
79-135
98-06-6
tert-Butylbenzene
50
45.2
90
77-133
56-23-5
Carbon Tetrachloride
50
45.8
92
78-133
108-90-7
Chlorobenzene
50
45.9
92
81-129
75-00-3
Chloroethane
50
26.1
52*
68-133
67-66-3
Chloroform
50
45.4
91
72-123
95-49-8
o-Chlorotoluene
50
44.6
89
77-129
106-43-4
p-Chlorotoluene
50
45.2
90
80-134
124-48-1
Dibromochloromethane
50
46.7
93
76-127
106-93-4
1,2-Dibromoethane
50
47.2
94
77-126
75-71-8
Dichlorodifluoromethane
50
49.0
98
68-168
95-50-1
1,2-Dichlorobenzene
50
45.9
92
80-129
541-73-1
1,3-Dichlorobenzene
50
46.6
93
81-129
106-46-7
1,4-Dichlorobenzene
50
45.0
90
76-130
75-34-3
1,1-Dichloroethane
50
47.0
94
73-125
107-06-2
1,2-Dichloroethane
50
45.1
90
74-128
75-35-4
1, 1 -Dichloroethylene
50
44.7
89
81-136
156-59-2
cis- 1, 2-Dichloroethylene
50
47.3
95
74-126
156-60-5
trans- 1, 2-Dichloroethylene
50
45.0
90
70-127
78-87-5
1,2-Dichloropropane
50
44.7
89
74-125
142-28-9
1,3-Dichloropropane
50
43.3
87
76-122
594-20-7
2,2-Dichloropropane
50
43.5
87
77-133
563-58-6
1, 1 -Dichloropropene
50
45.0
90
75-130
10061-01-5 cis-1,3-Dichloropropene
50
47.5
95
80-123
10061-02-6 trans-1,3-Dichloropropene
50
50.0
100
75-131
108-20-3
Di -Isopropyl Ether
50
45.3
91
75-122
64-17-5
Ethyl Alcohol
1000
814
81
53-154
100-41-4
Ethlbenzene
50
45.1
90
77-123
* = Outside of Control Limits.
SGS62 of 122
FA98839

Blank Spike Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 2 of 3
ample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batct
73C873-BS
3C183781.1)
1
09/21/22
DB
n/a
n/a
V3C873
The QC reported here applies to the following samples:
FA98839-1, FA98839-5, FA98839-7
Spike
BSP
BSP
CAS No.
Compound
ug/kg
ug/kg
%
Limits
591-78-6
2-Hexanone
250
248
99
72-133
98-82-8
Isopropylbenzene
50
47.2
94
80-136
99-87-6
p-Isopropyltoluene
50
48.2
96
77-131
74-83-9
Methyl Bromide
50
47.0
94
65-139
74-87-3
Methyl Chloride
50
46.3
93
71-144
75-09-2
Methylene Chloride
50
ND
0*
74-137
108-10-1
4-Methyl-2-pentanone (MIBK) 250
248
99
76-132
1634-04-4
Methyl Tert Butyl Ether
50
46.1
92
77-120
91-20-3
Naphthalene
50
50.9
102
79-129
103-65-1
n-Propylbenzene
50
45.1
90
80-135
100-42-5
Styrene
50
46.6
93
78-125
630-20-6
1, 1, 1, 2-Tetrachloroethane
50
47.4
95
78-126
79-34-5
1,1,2,2-Tetrachloroethane
50
46.1
92
71-126
127-18-4
Tetrachloroethylene
50
46.1
92
79-130
108-88-3
Toluene
50
44.2
88
76-124
87-61-6
1,2,3-Trichlorobenzene
50
46.9
94
77-128
120-82-1
1,2,4-Trichlorobenzene
50
47.4
95
78-130
71-55-6
1, 1, 1 -Trichloroethane
50
45.3
91
70-129
79-00-5
1,1,2-Trichloroethane
50
46.2
92
74-124
79-01-6
Trichloroethylene
50
46.5
93
75-128
75-69-4
Trichlorofluoromethane
50
48.3
97
73-145
96-18-4
1, 2,3 -Trichloropropane
50
44.0
88
74-127
95-63-6
1,2,4-Trimethylbenzene
50
46.0
92
74-123
108-67-8
1,3,5-Trimethylbenzene
50
45.3
91
73-122
108-05-4
Vinyl Acetate
250
232
93
48-164
75-01-4
Vinyl Chloride
50
46.2
92
76-141
m,p-Xylene
100
92.9
93
80-128
95-47-6
o-Xylene
50
47.4
95
80-132
1330-20-7
Xylene (total)
150
140
93
80-129
CAS No.
Surrogate Recoveries
BSP
Limits
1868-53-7
Dibromofluoromethane
100%
75-124%
17060-07-0
1,2-Dichloroethane-D4
98%
72-135%
2037-26-5
Toluene-D8
98%
75-126%
* = Outside of Control Limits.
Method: SW846 8260D
SGS63 of 122
FA98839

Blank Spike Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 3 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
V3C873-13S
3C183781.1)
1
09/21/22
DB
n/a
n/a
V3C873
The QC reported here applies to the following samples: Method: SW846 8260D
FA98839-1, FA98839-5, FA98839-7
CAS No. Surrogate Recoveries BSP Limits
460-00-4 4-Bromofluorobenzene 99% 71-133%
* = Outside of Control Limits.
SGS64 of 122
FA98839

Blank Spike Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
VF3759-BS
F0104788.D
1
09/23/22
DB
n/a
n/a
VF3759
The QC reported here applies to the following samples: Method: SW846 8260D
FA98839-2
CAS No. Compound
Spike BSP BSP
ug/kg ug/kg % Limits
67-64-1
Acetone
250
283
113
61-152
71-43-2
Benzene
50
51.4
103
76-126
108-86-1
Bromobenzene
50
44.6
89
76-122
74-97-5
Bromochloromethane
50
47.9
96
77-120
75-27-4
Bromodichloromethane
50
51.2
102
74-130
75-25-2
Bromoform
50
48.1
96
76-127
78-93-3
2-Butanone (MEK)
250
277
111
75-137
104-51-8
n-Butylbenzene
50
46.7
93
71-128
135-98-8
sec-Butylbenzene
50
52.5
105
79-135
98-06-6
tert-Butylbenzene
50
50.5
101
77-133
56-23-5
Carbon Tetrachloride
50
50.0
100
78-133
108-90-7
Chlorobenzene
50
48.7
97
81-129
75-00-3
Chloroethane
50
48.2
96
68-133
67-66-3
Chloroform
50
51.2
102
72-123
95-49-8
o-Chlorotoluene
50
49.8
100
77-129
106-43-4
p-Chlorotoluene
50
49.9
100
80-134
124-48-1
Dibromochloromethane
50
45.6
91
76-127
106-93-4
1,2-Dibromoethane
50
47.5
95
77-126
75-71-8
Dichlorodifluoromethane
50
57.9
116
68-168
95-50-1
1,2-Dichlorobenzene
50
48.2
96
80-129
541-73-1
1,3-Dichlorobenzene
50
48.8
98
81-129
106-46-7
1,4-Dichlorobenzene
50
47.0
94
76-130
75-34-3
1,1-Dichloroethane
50
54.1
108
73-125
107-06-2
1,2-Dichloroethane
50
50.6
101
74-128
75-35-4
1, 1 -Dichloroethylene
50
52.4
105
81-136
156-59-2
cis- 1, 2-Dichloroethylene
50
50.3
101
74-126
156-60-5
trans- 1, 2-Dichloroethylene
50
51.2
102
70-127
78-87-5
1,2-Dichloropropane
50
47.4
95
74-125
142-28-9
1,3-Dichloropropane
50
45.6
91
76-122
594-20-7
2,2-Dichloropropane
50
48.0
96
77-133
563-58-6
1, 1 -Dichloropropene
50
52.7
105
75-130
10061-01-5 cis-1,3-Dichloropropene
50
50.2
100
80-123
10061-02-6 trans-1,3-Dichloropropene
50
53.8
108
75-131
108-20-3
Di -Isopropyl Ether
50
50.8
102
75-122
64-17-5
Ethyl Alcohol
1000
754
75
53-154
100-41-4
Ethlbenzene
50
49.1
98
77-123
* = Outside of Control Limits.
SGS65 of 122
FA98839

Blank Spike Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 2 of 3
ample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batct
TF3759-BS
F0104788.D
1
09/23/22
DB
n/a
n/a
VF3759
The QC reported here applies to the following samples:
FA98839-2
Spike
BSP
BSP
CAS No.
Compound
ug/kg
ug/kg
%
Limits
591-78-6
2-Hexanone
250
248
99
72-133
98-82-8
Isopropylbenzene
50
49.2
98
80-136
99-87-6
p-Isopropyltoluene
50
50.6
101
77-131
74-83-9
Methyl Bromide
50
47.9
96
65-139
74-87-3
Methyl Chloride
50
57.9
116
71-144
75-09-2
Methylene Chloride
50
45.9
92
74-137
108-10-1
4-Methyl-2-pentanone (MIBK) 250
272
109
76-132
1634-04-4
Methyl Tert Butyl Ether
50
57.2
114
77-120
91-20-3
Naphthalene
50
49.1
98
79-129
103-65-1
n-Propylbenzene
50
50.5
101
80-135
100-42-5
Styrene
50
48.7
97
78-125
630-20-6
1, 1, 1, 2-Tetrachloroethane
50
47.0
94
78-126
79-34-5
1,1,2,2-Tetrachloroethane
50
49.6
99
71-126
127-18-4
Tetrachloroethylene
50
47.0
94
79-130
108-88-3
Toluene
50
50.1
100
76-124
87-61-6
1,2,3-Trichlorobenzene
50
49.0
98
77-128
120-82-1
1,2,4-Trichlorobenzene
50
48.6
97
78-130
71-55-6
1, 1, 1 -Trichloroethane
50
51.6
103
70-129
79-00-5
1,1,2-Trichloroethane
50
49.1
98
74-124
79-01-6
Trichloroethylene
50
50.3
101
75-128
75-69-4
Trichlorofluoromethane
50
54.4
109
73-145
96-18-4
1, 2,3 -Trichloropropane
50
44.4
89
74-127
95-63-6
1,2,4-Trimethylbenzene
50
50.1
100
74-123
108-67-8
1,3,5-Trimethylbenzene
50
49.3
99
73-122
108-05-4
Vinyl Acetate
250
266
106
48-164
75-01-4
Vinyl Chloride
50
54.2
108
76-141
m,p-Xylene
100
99.4
99
80-128
95-47-6
o-Xylene
50
50.4
101
80-132
1330-20-7
Xylene (total)
150
150
100
80-129
CAS No.
Surrogate Recoveries
BSP
Limits
1868-53-7
Dibromofluoromethane
102%
75-124%
17060-07-0
1,2-Dichloroethane-D4
104%
72-135%
2037-26-5
Toluene-D8
101%
75-126%
* = Outside of Control Limits.
Method: SW846 8260D
SGS66 of 122
FA98839

Blank Spike Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 3 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
VF3759-BS
170104788.1)
1
09/23/22
DB
n/a
n/a
VF3759
The QC reported here applies to the following samples: Method: SW846 8260D
FA98839-2
CAS No. Surrogate Recoveries
460-00-4 4-Bromofluorobenzene
* = Outside of Control Limits.
BSP Limits
101% 71-133%
SGS67 of 122
FA98839

Matrix Spike Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 3
Sample
File ID DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
FA98908-3MS
170104811.1) 1
09/23/22
DB
n/a
n/a
VF3759
FA98908-3
170104792.13 1
09/23/22
DB
n/a
n/a
VF3759
The QC reported here applies to the following samples:
FA98839-2
CAS No. Compound
FA98908-3 Spike MS MS
ug/kg Q ug/kg ug/kg %
Method: SW846 8260D
Limits
67-64-1
Acetone
130 U
225
189
84
61-152
71-43-2
Benzene
3.3 U
45
38.7
86
76-126
108-86-1
Bromobenzene
3.3 U
45
63.6
141*
76-122
74-97-5
Bromochloromethane
3.3 U
45
36.9
82
77-120
75-27-4
Bromodichloromethane
3.3 U
45
37.2
83
74-130
75-25-2
Bromoform
3.3 U
45
29.8
66*
76-127
78-93-3
2-Butanone (MEK)
16 U
225
176
78
75-137
104-51-8
n-Butylbenzene
3.3 U
45
26.2
58*
71-128
135-98-8
sec-Butylbenzene
3.3 U
45
31.8
71*
79-135
98-06-6
tert-Butylbenzene
3.3 U
45
34.0
75*
77-133
56-23-5
Carbon Tetrachloride
3.3 U
45
37.8
84
78-133
108-90-7
Chlorobenzene
3.3 U
45
36.3
81
81-129
75-00-3
Chloroethane
6.3
45
36.1
66*
68-133
67-66-3
Chloroform
3.3 U
45
37.9
84
72-123
95-49-8
o-Chlorotoluene
3.3 U
45
34.2
76*
77-129
106-43-4
p-Chlorotoluene
3.3 U
45
33.7
75*
80-134
124-48-1
Dibromochloromethane
3.3 U
45
32.9
73*
76-127
106-93-4
1,2-Dibromoethane
3.3 U
45
35.7
79
77-126
75-71-8
Dichlorodifluoromethane
3.3 U
45
42.8
95
68-168
95-50-1
1,2-Dichlorobenzene
3.3 U
45
30.9
69*
80-129
541-73-1
1,3-Dichlorobenzene
3.3 U
45
32.2
71*
81-129
106-46-7
1,4-Dichlorobenzene
3.3 U
45
31.6
70*
76-130
75-34-3
1,1-Dichloroethane
10.2
45
43.1
73
73-125
107-06-2
1,2-Dichloroethane
3.3 U
45
36.0
80
74-128
75-35-4
1, 1 -Dichloroethylene
3.3 U
45
40.2
89
81-136
156-59-2
cis- 1, 2-Dichloroethylene
3.3 U
45
39.7
88
74-126
156-60-5
trans- 1, 2-Dichloroethylene
3.4
45
40.0
81
70-127
78-87-5
1,2-Dichloropropane
3.3 U
45
35.9
80
74-125
142-28-9
1,3-Dichloropropane
3.3 U
45
32.9
73*
76-122
594-20-7
2,2-Dichloropropane
3.3 U
45
34.6
77
77-133
563-58-6
1, 1 -Dichloropropene
3.3 U
45
38.8
86
75-130
10061-01-5 cis- 1, 3-Dichloropropene
3.3 U
45
31.9
71*
80-123
10061-02-6 trans- 1, 3-Dichloropropene
3.3 U
45
34.9
77
75-131
108-20-3
Di -Isopropyl Ether
3.3 U
45
37.6
83
75-122
64-17-5
Ethyl Alcohol
260 U
901
542
60
53-154
100-41-4
Ethlbenzene
2.9 1
45
35.2
72*
77-123
* = Outside of Control Limits.
GS68 of 122
FA98839

Matrix Spike Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 2 of 3
Sample
File ID DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
FA98908-3MS
170104811.1) 1
09/23/22
DB
n/a
n/a
VF3759
FA98908-3
170104792.13 1
09/23/22
DB
n/a
n/a
VF3759
The QC reported here applies to the following samples: Method: SW846 8260D
FA98839-2
FA98908-3 Spike MS MS
CAS No. Compound ug/kg Q ug/kg ug/kg % Limits
591-78-6
2-Hexanone
16 U
225
164
73
72-133
98-82-8
Isopropylbenzene
3.3 U
45
31.9
71*
80-136
99-87-6
p-Isopropyltoluene
1.9 1
45
36.5
77
77-131
74-83-9
Methyl Bromide
3.3 U
45
34.3
76
65-139
74-87-3
Methyl Chloride
3.3 U
45
42.8
95
71-144
75-09-2
Methylene Chloride
13 U
45
38.4
85
74-137
108-10-1
4-Methyl-2-pentanone (MIBK) 16 U
225
183
81
76-132
1634-04-4
Methyl Tert Butyl Ether
3.3 U
45
40.4
90
77-120
91-20-3
Naphthalene
3.3 U
45
26.3
58*
79-129
103-65-1
n-Propylbenzene
3.3 U
45
28.9
64*
80-135
100-42-5
Styrene
3.3 U
45
31.4
70*
78-125
630-20-6
1, 1, 1, 2-Tetrachloroethane
3.3 U
45
34.9
77*
78-126
79-34-5
1,1,2,2-Tetrachloroethane
3.3 U
45
30.4
67*
71-126
127-18-4
Tetrachloroethylene
3.3 U
45
53.0
118
79-130
108-88-3
Toluene
25.8
45
41.1
34*
76-124
87-61-6
1,2,3-Trichlorobenzene
3.3 U
45
22.8
51*
77-128
120-82-1
1,2,4-Trichlorobenzene
3.3 U
45
24.4
54*
78-130
71-55-6
1, 1, 1 -Trichloroethane
3.3 U
45
39.3
87
70-129
79-00-5
1,1,2-Trichloroethane
3.3 U
45
35.7
79
74-124
79-01-6
Trichloroethylene
3.3 U
45
42.0
93
75-128
75-69-4
Trichlorofluoromethane
3.3 U
45
42.2
94
73-145
96-18-4
1,2,3-Trichloropropane
3.3 U
45
31.6
70*
74-127
95-63-6
1,2,4-Trimethylbenzene
3.3 U
45
31.5
70*
74-123
108-67-8
1,3,5-Trimethylbenzene
3.3 U
45
35.2
78
73-122
108-05-4
Vinyl Acetate
16 U
225
ND
0*
48-164
75-01-4
Vinyl Chloride
3.3 U
45
41.5
92
76-141
m,p-Xylene
10.9
90.1
76.4
73*
80-128
95-47-6
o-Xylene
4.5
45
41.0
81
80-132
1330-20-7
Xylene (total)
15.5
135
117
75*
80-129
CAS No.
Surrogate Recoveries
MS
FA98908-3 Limits
1868-53-7
Dibromofluoromethane
100%
96%
75-124%
17060-07-0
1,2-Dichloroethane-D4
95%
105%
72-135%
2037-26-5
Toluene-D8
101%
101%
75-126%
* = Outside of Control Limits.
SGS69 of 122
FA98839

Matrix Spike Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 3 of 3
Sample
File ID DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
FA98908-3MS
170104811.1) 1
09/23/22
DB
n/a
n/a
VF3759
FA98908-3
170104792.13 1
09/23/22
DB
n/a
n/a
VF3759
The QC reported here applies to the following samples: Method: SW846 8260D
FA98839-2
CAS No. Surrogate Recoveries
460-00-4 4-Bromofluorobenzene
* = Outside of Control Limits.
MS FA98908-3 Limits
102% 101% 71-133%
a1��GS 70 of 122
FA98839

Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
FA98918-5MS
5E34184.D
25
09/16/22
CF
n/a
n/a
V5E1556
FA98918-5MSD
5E34185.D
25
09/16/22
CF
n/a
n/a
V5E1556
FA98918-5 a
5E34182.1)
25
09/16/22
CF
n/a
n/a
V5E1556
The QC reported here applies to the following samples:
FA98839-8
CAS No. Compound
FA98918-5 Spike MS
ug/l Q ug/l ug/l
CAS No.
Surrogate Recoveries
MS
MSD
1868-53-7
Dibromofluoromethane
96%
96%
17060-07-0
1,2-Dichloroethane-D4
110%
106%
2037-26-5
Toluene-D8
104%
106%
460-00-4
4-Bromofluorobenzene
100%
102%
(a) Sample was not preserved to a pH < 2.
* = Outside of Control Limits.
Method: SW846 8260D
MS Spike MSD MSD Limits
% ug/l ug/l % RPD Rec/RPD
FA98918-5 Limits
100% 83-118%
108% 79-125%
106% 85-112%
108% 83-118%
A
a1��GS 71 of 122
FA98839

Matrix Spike/Matrix Spike Duplicate Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
FA98918-5MS
2P93161.1)
25
09/20/22
CF
n/a
n/a
V2P3580
FA98918-5MSD
2P93162.D
25
09/20/22
CF
n/a
n/a
V2P3580
FA98918-5 a
2P93158.1)
25
09/20/22
CF
n/a
n/a
V2P3580
The QC reported here applies to the following samples:
FA98839-8
CAS No. Compound
FA98918-5 Spike MS
ug/1 Q ug/l ug/l
Method: SW846 8260D
MS Spike MSD MSD Limits
% ug/l ug/l % RPD Rec/RPD
67-64-1
Acetone
630 U
3130
2460
79
3130
2430
78
1
50-147/21
71-43-2
Benzene
18.3 J
625
686
107
625
686
107
0
81-122/14
108-86-1
Bromobenzene
25 U
625
597
96
625
602
96
1
80-121/14
74-97-5
Bromochloromethane
25 U
625
662
106
625
650
104
2
76-123/14
75-27-4
Bromodichloromethane
25 U
625
643
103
625
666
107
4
79-123/19
75-25-2
Bromoform
25 U
625
556
89
625
604
97
8
66-123/21
78-93-3
2-Butanone(MEK)
130 U
3130
2970
95
3130
2930
94
1
56-143/18
104-51-8
n-Butylbenzene
25 U
625
589
94
625
601
96
2
79-126/16
135-98-8
sec-Butylbenzene
25 U
625
659
105
625
674
108
2
83-133/16
98-06-6
tert-Butylbenzene
25 U
625
603
96
625
620
99
3
80-133/16
56-23-5
Carbon Tetrachloride
25 U
625
675
108
625
683
109
1
76-136/23
108-90-7
Chlorobenzene
25 U
625
638
102
625
654
105
2
82-124/14
75-00-3
Chloroethane
50 U
625
595
95
625
683
109
14
62-144/20
67-66-3
Chloroform
25 U
625
679
109
625
687
110
1
80-124/15
95-49-8
o-Chlorotoluene
25 U
625
594
95
625
611
98
3
81-127/15
106-43-4
p-Chlorotoluene
25 U
625
594
95
625
610
98
3
83-130/15
124-48-1
Dibromochloromethane
25 U
625
575
92
625
598
96
4
78-122/19
106-93-4
1,2-Dibromoethane
50 U
625
612
98
625
643
103
5
75-120/13
75-71-8
Dichlorodifluoromethane
50 U
625
660
106
625
733
117
10
42-167/19
95-50-1
1,2-Dichlorobenzene
25 U
625
622
100
625
625
100
0
82-124/14
541-73-1
1, 3 -Dichlorobenzene
25 U
625
635
102
625
633
101
0
84-125/14
106-46-7
1,4-Dichlorobenzene
25 U
625
606
97
625
615
98
1
78-120/15
75-34-3
1, 1 -Dichloroethane
210
625
776
91
625
795
94
2
81-122/15
107-06-2
1,2-Dichloroethane
25 U
625
641
103
625
655
105
2
75-125/14
75-35-4
1, 1 -Dichloroethylene
25 U
625
706
113
625
708
113
0
78-137/18
156-59-2
cis- 1, 2-Dichloroethylene
3830 E
625
1950
-301*
b 625
2000
-293*
b 3
78-120/15
156-60-5
trans- 1, 2-Dichloroethylene
278
625
778
80
625
802
84
3
76-127/17
78-87-5
1,2-Dichloropropane
25 U
625
632
101
625
650
104
3
76-124/14
142-28-9
1,3-Dichloropropane
25 U
625
570
91
625
591
95
4
80-118/13
594-20-7
2,2-Dichloropropane
25 U
625
570
91
625
593
95
4
74-139/17
563-58-6
1, 1 -Dichloropropene
25 U
625
689
110
625
700
112
2
79-131/16
10061-01-5 cis- 1, 3-Dichloropropene
25 U
625
613
98
625
642
103
5
75-118/23
10061-02-6 trans- 1, 3-Dichloropropene
25 U
625
624
100
625
645
103
3
80-120/22
108-20-3
Di -Isopropyl Ether
25 U
625
664
106
625
661
106
0
68-123/16
64-17-5
Ethyl Alcohol
5000 U
12500
11700
94
12500
12800
102
9
46-145/30
100-41-4
Ethylbenzene
25 U
625
633
101
625
653
104
3
81-121/14
* = Outside of Control Limits.
A
N
SGS72 of 122
FA98839

Matrix Spike/Matrix Spike Duplicate Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 2 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
FA98918-5MS
2P93161.D
25
09/20/22
CF
n/a
n/a
V2P3580
FA98918-5MSD
2P93162.D
25
09/20/22
CF
n/a
n/a
V2P3580
FA98918-5 a
2P93158.D
25
09/20/22
CF
n/a
n/a
V2P3580
The QC reported here applies to the following samples:
FA98839-8
CAS No. Compound
591-78-6
98-82-8
99-87-6
74-83-9
74-87-3
75-09-2
108-10-1
1634-04-4
91-20-3
103-65-1
100-42-5
630-20-6
79-34-5
127-18-4
108-88-3
87-61-6
120-82-1
71-55-6
79-00-5
79-01-6
75-69-4
96-18-4
95-63-6
108-67-8
108-05-4
75-01-4
95-47-6
1330-20-7
CAS No.
FA98918-5 Spike MS
ug/1 Q ug/l ug/l
Method: SW846 8260D
MS Spike MSD MSD Limits
% ug/l ug/1 % RPD Rec/RPD
2-Hexanone
250 U
3130
3280
105
3130
3250
104
1
61-129/18
Isopropylbenzene
25 U
625
655
105
625
671
107
2
83-132/15
p-Isopropyltoluene
25 U
625
663
106
625
674
108
2
79-130/16
Methyl Bromide
130 U
625
509
81
625
618
99
19
59-143/19
Methyl Chloride
50 U
625
651
104
625
718
115
10
50-159/19
Methylene Chloride
130 U
625
614
98
625
620
99
1
69-135/16
4-Methyl-2-pentanone (MIBK) 130 U
3130
3300
106
3130
3230
103
2
66-122/16
Methyl Tert Butyl Ether
25 U
625
665
106
625
678
108
2
72-117/14
Naphthalene
130 U
625
594
95
625
618
99
4
63-132/25
n-Propylbenzene
25 U
625
622
100
625
626
100
1
82-133/15
Styrene
25 U
625
628
100
625
655
105
4
78-119/23
1, 1, 1,2-Tetrachloroethane
25 U
625
622
100
625
644
103
3
77-122/19
1,1,2,2-Tetrachloroethane
25 U
625
581
93
625
602
96
4
72-120/14
Tetrachloroethylene
25 U
625
704
113
625
737
118
5
76-135/16
Toluene
25 U
625
618
99
625
639
102
3
80-120/14
1,2,3-Trichlorobenzene
50 U
625
606
97
625
631
101
4
68-131/25
1,2,4-Trichlorobenzene
50 U
625
606
97
625
618
99
2
73-129/20
1, 1, 1 -Trichloroethane
25 U
625
691
111
625
703
112
2
75-130/16
1, 1, 2-Trichloroethane
16.3
J 625
634
99
625
647
101
2
76-119/14
Trichloroethylene
2200
625
1410
-126*
b 625
1440
-122*
b 2
81-126/15
Trichlorofluoromethane
50 U
625
730
117
625
815
130
11
71-156/21
1,2,3-Trichloropropane
50 U
625
556
89
625
570
91
2
77-120/16
1,2,4-Trimethylbenzene
25 U
625
614
98
625
620
99
1
79-120/18
1,3,5-Trimethylbenzene
25 U
625
601
96
625
612
98
2
79-120/19
Vinyl Acetate
250 U
3130
2590
83
3130
2800
90
8
43-154/14
Vinyl Chloride
309
625
768
73
625
836
84
8
69-159/18
m,p-Xylene
50 U
1250
1250
100
1250
1270
102
2
79-126/15
o-Xylene
25 U
625
646
103
625
663
106
3
80-127/14
Xylene (total)
75 U
1880
1900
101
1880
1940
103
2
80-126/15
Surrogate Recoveries MS
1868-53-7 Dibromofluoromethane 101%
17060-07-0 1,2-Dichloroethane-D4 98%
2037-26-5 Toluene-D8 94%
* = Outside of Control Limits.
MSD FA98918-5 Limits
101% 98% 83-118%
99% 101% 79-125%
95% 97% 85-112%
A
N
SGS73 of 122
FA98839

Matrix Spike/Matrix Spike Duplicate Summary Page 3 of 3
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
FA98918-5MS
2P93161.1)
25
09/20/22
CF
n/a
n/a
V2P3580
FA98918-5MSD
2P93162.D
25
09/20/22
CF
n/a
n/a
V2P3580
FA98918-5 a
2P93158.1)
25
09/20/22
CF
n/a
n/a
V2P3580
The QC reported here applies to the following samples:
FA98839-8
CAS No. Surrogate Recoveries MS MSD FA98918-5 Limits
460-00-4 4-Bromofluorobenzene 98% 98% 98% 83-118%
(a) Sample was not preserved to a pH < 2. Sample used for QC purposes only.
(b) Outside control limits due to high level in sample relative to spike amount.
* = Outside of Control Limits.
Method: SW846 8260D
A
N
a1��GS 74 of 122
FA98839

Matrix Spike/Matrix Spike Duplicate Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
FA98908-6MS
3C183804.1)
1
09/21/22
DB
n/a
n/a
V3C873
FA98908-6MSD
3C183805.1)
1
09/21/22
DB
n/a
n/a
V3C873
FA98908-6
3C183789.13
1
09/21/22
DB
n/a
n/a
V3C873
The QC reported here applies to the following samples:
FA98839-1, FA98839-5, FA98839-7
CAS No. Compound
FA98908-6 Spike MS MS
ug/kg Q ug/kg ug/kg %
Method: SW846 8260D
Spike MSD MSD Limits
ug/kg ug/kg % RPD Rec/RPD
67-64-1
Acetone
133 I
176
143
6*
176
141
5*
1
61-152/27
71-43-2
Benzene
5.1 U
35.1
28.6
81
35.1
28.7
82
0
76-126/26
108-86-1
Bromobenzene
5.1 U
35.1
24.2
69*
35.1
23.7
67*
2
76-122/32
74-97-5
Bromochloromethane
5.1 U
35.1
29.5
84
35.1
29.5
84
0
77-120/24
75-27-4
Bromodichloromethane
5.1 U
35.1
27.9
79
35.1
28.2
80
1
74-130/25
75-25-2
Bromoform
5.1 U
35.1
23.3
66*
35.1
23.8
68*
2
76-127/26
78-93-3
2-Butanone(MEK)
26 U
176
117
67*
176
103
59*
13
75-137/25
104-51-8
n-Butylbenzene
5.1 U
35.1
19.1
54*
35.1
19.8
56*
4
71-128/35
135-98-8
sec-Butylbenzene
5.1 U
35.1
24.2
69*
35.1
24.4
69*
1
79-135/34
98-06-6
tert-Butylbenzene
5.1 U
35.1
24.9
71*
35.1
25.4
72*
2
77-133/34
56-23-5
Carbon Tetrachloride
5.1 U
35.1
27.9
79
35.1
28.5
81
2
78-133/29
108-90-7
Chlorobenzene
5.1 U
35.1
25.9
74*
35.1
26.5
75*
2
81-129/29
75-00-3
Chloroethane
5.1 U
35.1
18.9
54*
35.1
18.5
53*
2
68-133/29
67-66-3
Chloroform
5.1 U
35.1
28.1
80
35.1
28.3
81
1
72-123/26
95-49-8
o-Chlorotoluene
5.1 U
35.1
24.8
71*
35.1
25.6
73*
3
77-129/33
106-43-4
p-Chlorotoluene
5.1 U
35.1
24.7
70*
35.1
25.8
73*
4
80-134/33
124-48-1
Dibromochloromethane
5.1 U
35.1
25.6
73*
35.1
26.2
75*
2
76-127/27
106-93-4
1,2-Dibromoethane
5.1 U
35.1
27.2
77
35.1
28.0
80
3
77-126/26
75-71-8
Dichlorodifluoromethane
5.1 U
35.1
31.5
90
35.1
30.0
85
5
68-168/29
95-50-1
1,2-Dichlorobenzene
5.1 U
35.1
22.2
63*
35.1
23.1
66*
4
80-129/32
541-73-1
1, 3 -Dichlorobenzene
5.1 U
35.1
23.1
66*
35.1
24.2
69*
5
81-129/33
106-46-7
1,4-Dichlorobenzene
5.1 U
35.1
22.3
64*
35.1
23.2
66*
4
76-130/32
75-34-3
1, 1 -Dichloroethane
5.1 U
35.1
31.3
89
35.1
31.4
89
0
73-125/27
107-06-2
1,2-Dichloroethane
5.1 U
35.1
26.5
75
35.1
26.5
75
0
74-128/23
75-35-4
1, 1 -Dichloroethylene
5.1 U
35.1
28.7
82
35.1
28.7
82
0
81-136/28
156-59-2
cis- 1, 2-Dichloroethylene
5.1 U
35.1
30.2
86
35.1
30.3
86
0
74-126/26
156-60-5
trans- 1, 2-Dichloroethylene
5.1 U
35.1
29.0
83
35.1
29.1
83
0
70-127/27
78-87-5
1,2-Dichloropropane
5.1 U
35.1
27.7
79
35.1
27.8
79
0
74-125/25
142-28-9
1,3-Dichloropropane
5.1 U
35.1
26.2
75*
35.1
26.0
74*
1
76-122/26
594-20-7
2,2-Dichloropropane
5.1 U
35.1
27.0
77
35.1
26.3
75*
3
77-133/28
563-58-6
1, 1 -Dichloropropene
5.1 U
35.1
28.6
81
35.1
28.8
82
1
75-130/28
10061-01-5 cis- 1, 3-Dichloropropene
5.1 U
35.1
26.2
75*
35.1
26.8
76*
2
80-123/26
10061-02-6 trans- 1, 3-Dichloropropene
5.1 U
35.1
27.3
78
35.1
27.7
79
1
75-131/28
108-20-3
Di -Isopropyl Ether
5.1 U
35.1
28.1
80
35.1
28.1
80
0
75-122/25
64-17-5
Ethyl Alcohol
410 U
702
277
39*
703
177
25*
44*
53-154/42
100-41-4
Ethylbenzene
5.1 U
35.1
24.0
68*
35.1
24.4
69*
2
77-123/31
* = Outside of Control Limits.
SGS75 of 122
FA98839

Matrix Spike/Matrix Spike Duplicate Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 2 of 3
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
FA98908-6MS
3C183804.1)
1
09/21/22
DB
n/a
n/a
V3C873
FA98908-6MSD
3C183805.1)
1
09/21/22
DB
n/a
n/a
V3C873
FA98908-6
3C183789.13
1
09/21/22
DB
n/a
n/a
V3C873
The QC reported here applies to the following samples:
FA98839-1, FA98839-5, FA98839-7
CAS No. Compound
591-78-6
98-82-8
99-87-6
74-83-9
74-87-3
75-09-2
108-10-1
1634-04-4
91-20-3
103-65-1
100-42-5
630-20-6
79-34-5
127-18-4
108-88-3
87-61-6
120-82-1
71-55-6
79-00-5
79-01-6
75-69-4
96-18-4
95-63-6
108-67-8
108-05-4
75-01-4
95-47-6
1330-20-7
CAS No.
FA98908-6 Spike MS MS
ug/kg Q ug/kg ug/kg %
Method: SW846 8260D
Spike MSD MSD Limits
ug/kg ug/kg % RPD Rec/RPD
2-Hexanone
26 U
176
124
71*
176
120
68*
3
72-133/26
Isopropylbenzene
5.1 U
35.1
24.9
71*
35.1
24.5
70*
2
80-136/32
p-Isopropyltoluene
5.1 U
35.1
27.2
77
35.1
27.1
77
0
77-131/34
Methyl Bromide
5.1 U
35.1
18.8
54*
35.1
23.0
65
20
65-139/31
Methyl Chloride
5.1 U
35.1
28.2
80
35.1
28.2
80
0
71-144/27
Methylene Chloride
21 U
35.1
ND
0*
35.1
ND
0*
nc
74-137/28
4-Methyl-2-pentanone (MIBK) 26 U
176
133
76
176
134
76
1
76-132/26
Methyl Tert Butyl Ether
5.1 U
35.1
27.8
79
35.1
27.6
79
1
77-120/24
Naphthalene
5.1 U
35.1
22.3
64*
35.1
21.5
61*
4
79-129/33
n-Propylbenzene
5.1 U
35.1
20.2
58*
35.1
20.1
57*
0
80-135/33
Styrene
5.1 U
35.1
23.9
68*
35.1
24.3
69*
2
78-125/30
1, 1, 1,2-Tetrachloroethane
5.1 U
35.1
28.1
80
35.1
28.5
81
1
78-126/27
1,1,2,2-Tetrachloroethane
5.1 U
35.1
24.0
68*
35.1
24.7
70*
3
71-126/30
Tetrachloroethylene
5.1 U
35.1
38.0
108
35.1
38.3
109
1
79-130/31
Toluene
21 U
35.1
27.9
79
35.1
28.3
81
1
76-124/30
1,2,3-Trichlorobenzene
5.1 U
35.1
15.0
43*
35.1
15.6
44*
4
77-128/35
1,2,4-Trichlorobenzene
5.1 U
35.1
16.4
47*
35.1
17.6
50*
7
78-130/34
1, 1, 1 -Trichloroethane
5.1 U
35.1
28.6
81
35.1
29.1
83
2
70-129/27
1, 1, 2-Trichloroethane
5.1 U
35.1
27.6
79
35.1
27.5
78
0
74-124/28
Trichloroethylene
5.1 U
35.1
32.5
93
35.1
31.9
91
2
75-128/27
Trichlorofluoromethane
5.1 U
35.1
30.4
87
35.1
30.6
87
1
73-145/31
1,2,3-Trichloropropane
5.1 U
35.1
25.4
72*
35.1
25.7
73*
1
74-127/27
1,2,4-Trimethylbenzene
5.1 U
35.1
23.6
67*
35.1
24.6
70*
4
74-123/34
1,3,5-Trimethylbenzene
5.1 U
35.1
25.9
74
35.1
26.2
75
1
73-122/33
Vinyl Acetate
26 U
176
ND
0*
176
ND
0*
nc
48-164/37
Vinyl Chloride
5.1 U
35.1
29.8
85
35.1
29.6
84
1
76-141/27
m,p-Xylene
10 U
70.2
54.4
77*
70.3
55.9
80
3
80-128/30
o-Xylene
5.1 U
35.1
30.3
86
35.1
31.0
88
2
80-132/30
Xylene (total)
15 U
105
84.6
80
105
86.9
82
3
80-129/30
Surrogate Recoveries MS
1868-53-7 Dibromofluoromethane 98%
17060-07-0 1,2-Dichloroethane-D4 91%
2037-26-5 Toluene-D8 98%
* = Outside of Control Limits.
MSD FA98908-6 Limits
97% 98% 75-124%
89% 121% 72-135%
100% 98% 75-126%
SGS76 of 122
FA98839

Matrix Spike/Matrix Spike Duplicate Summary Page 3 of 3
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
FA98908-6MS
3C183804.1)
1
09/21/22
DB
n/a
n/a
V3C873
FA98908-6MSD
3C183805.1)
1
09/21/22
DB
n/a
n/a
V3C873
FA98908-6
3C183789.13
1
09/21/22
DB
n/a
n/a
V3C873
The QC reported here applies to the following samples: Method: SW846 8260D
FA98839-1, FA98839-5, FA98839-7
CAS No. Surrogate Recoveries
460-00-4 4-Bromofluorobenzene
* = Outside of Control Limits.
MS MSD FA98908-6 Limits
106% 106% 100% 71-133%
a1��GS 77 of 122
FA98839

Orlando, FL
MS Semi-volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Section 6
0
a1��GS 78 of 122
FA98839

Method Blank Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 2
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
DP93050-MB
X083985.13
1
09/15/22
KA
09/14/22
OP93050
SX3330
The QC reported here applies to the following samples: Method: SW846 8270E
FA98839-3, FA98839-4, FA98839-6, FA98839-7
CAS No. Compound
Result RL MDL Units Q
65-85-0
Benzoic Acid
ND
830
170
ug/kg
59-50-7
4-Chloro-3-methyl Phenol
ND
170
19
ug/kg
95-57-8
2-Chlorophenol
ND
170
20
ug/kg
120-83-2
2,4-Dichlorophenol
ND
170
19
ug/kg
105-67-9
2,4-Dimethylphenol
ND
170
44
ug/kg
51-28-5
2,4-Dinitrophenol
ND
830
170
ug/kg
534-52-1
4,6-Dinitro-o-cresol
ND
330
67
ug/kg
95-48-7
2-Methylphenol
ND
170
20
ug/kg
3&4-Methylphenol
ND
170
27
ug/kg
88-75-5
2-Nitrophenol
ND
170
18
ug/kg
100-02-7
4-Nitrophenol
ND
830
170
ug/kg
87-86-5
Pentachlorophenol
ND
830
170
ug/kg
108-95-2
Phenol
ND
170
17
ug/kg
88-06-2
2,4,6-Trichlorophenol
ND
170
19
ug/kg
83-32-9
Acenaphthene
ND
170
18
ug/kg
208-96-8
Acenaphthylene
ND
170
17
ug/kg
120-12-7
Anthracene
ND
170
19
ug/kg
56-55-3
Benzo(a)anthracene
ND
170
17
ug/kg
50-32-8
Benzo(a)pyrene
ND
170
20
ug/kg
205-99-2
Benzo(b)fluoranthene
ND
170
18
ug/kg
191-24-2
Benzo(g, h, i)perylene
ND
170
17
ug/kg
207-08-9
Benzo(k)fluoranthene
ND
170
22
ug/kg
100-51-6
Benzyl Alcohol
ND
170
17
ug/kg
101-55-3
4-Bromophenyl phenyl ether
ND
170
17
ug/kg
85-68-7
Butyl benzyl phthalate
ND
170
33
ug/kg
106-47-8
4-Chloroaniline
ND
170
42
ug/kg
111-91-1
bis(2-Chloroethoxy)methane
ND
170
17
ug/kg
111-44-4
bis(2-Chloroethyl)ether
ND
170
19
ug/kg
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
170
21
ug/kg
91-58-7
2-Chloronaphthalene
ND
170
17
ug/kg
7005-72-3
4-Chlorophenyl phenyl ether
ND
170
17
ug/kg
218-01-9
Chrysene
ND
170
17
ug/kg
53-70-3
Dibenzo(a,h)anthracene
ND
170
21
ug/kg
132-64-9
Dibenzofuran
ND
170
17
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
170
17
ug/kg
541-73-1
1,3-Dichlorobenzene
ND
170
18
ug/kg
SGS79 of 122
FA98839

Method Blank Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 2 of 2
ample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
)P93050-MB
X083985.13
1
09/15/22
KA
09/14/22
OP93050
SX3330
The QC reported here applies to the following samples: Method: SW846 8270E
FA98839-3, FA98839-4, FA98839-6, FA98839-7
CAS No. Compound
106-46-7
1,4-Dichlorobenzene
91-94-1
3, 3'-Dichlorobenzidine
84-66-2
Diethyl Phthalate
131-11-3
Dimethyl Phthalate
117-84-0
Di-n-octyl Phthalate
84-74-2
Di-n-butyl Phthalate
122-66-7
1, 2-Diphenylhydrazine
117-81-7
bis(2-Ethylhexyl)phthalate
206-44-0
Fluoranthene
86-73-7
Fluorene
118-74-1
Hexachlorobenzene
87-68-3
Hexachlorobutadiene
77-47-4
Hexachlorocyclopentadiene
67-72-1
Hexachloroethane
193-39-5
Indeno(1,2,3-cd)pyrene
78-59-1
Isophorone
90-12-0
1-Methylnaphthalene
91-57-6
2-Methylnaphthalene
91-20-3
Naphthalene
98-95-3
Nitrobenzene
621-64-7
N-Nitrosodi-n-propylamine
86-30-6
N-Nitrosodiphenylamine
85-01-8
Phenanthrene
129-00-0
Pyrene
120-82-1
1,2,4-Trichlorobenzene
CAS No. Surrogate Recoveries
367-12-4 2-Fluorophenol
4165-62-2 Phenol-d5
118-79-6 2,4,6-Tribromophenol
4165-60-0 Nitrobenzene-d5
321-60-8 2-Fluorobiphenyl
1718-51-0 Terphenyl-d14
Result
RL
MDL
Units Q
ND
170
22
ug/kg
ND
170
40
ug/kg
ND
330
33
ug/kg
ND
170
33
ug/kg
ND
170
33
ug/kg
ND
330
67
ug/kg
ND
170
17
ug/kg
ND
330
33
ug/kg
ND
170
17
ug/kg
ND
170
18
ug/kg
ND
170
17
ug/kg
ND
170
17
ug/kg
ND
170
33
ug/kg
ND
170
20
ug/kg
ND
170
20
ug/kg
ND
170
17
ug/kg
ND
170
17
ug/kg
ND
170
17
ug/kg
ND
170
17
ug/kg
ND
170
17
ug/kg
ND
170
17
ug/kg
ND
170
18
ug/kg
ND
170
17
ug/kg
ND
170
19
ug/kg
ND
170
20
ug/kg
Limits
83%
40-102%
87%
41-100%
51%
42-108%
73%
40-105%
77%
43-107%
101%
45-119%
GS80 of 122
FA98839

Method Blank Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 2
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
DP93061-MB
61715654.13
1
09/14/22
KA
09/14/22
OP93061
S6F587
The QC reported here applies to the following samples: Method: SW846 8270E
FA98839-8
CAS No. Compound
Result RL MDL Units Q
65-85-0
Benzoic Acid
ND
50
10
ug/l
59-50-7
4-Chloro-3-methyl Phenol
ND
5.0
0.59
ug/l
95-57-8
2-Chlorophenol
ND
5.0
0.63
ug/l
120-83-2
2,4-Dichlorophenol
ND
5.0
0.84
ug/l
105-67-9
2,4-Dimethylphenol
ND
5.0
0.74
ug/l
51-28-5
2,4-Dinitrophenol
ND
25
5.0
ug/l
534-52-1
4,6-Dinitro-o-cresol
ND
10
2.0
ug/l
95-48-7
2-Methylphenol
ND
5.0
0.56
ug/l
3&4-Methylphenol
ND
5.0
0.98
ug/l
88-75-5
2-Nitrophenol
ND
5.0
0.85
ug/l
100-02-7
4-Nitrophenol
ND
25
5.0
ug/l
87-86-5
Pentachlorophenol
ND
25
5.0
ug/l
108-95-2
Phenol
ND
5.0
0.50
ug/l
88-06-2
2,4,6-Trichlorophenol
ND
5.0
0.75
ug/l
83-32-9
Acenaphthene
ND
5.0
0.63
ug/1
208-96-8
Acenaphthylene
ND
5.0
0.64
ug/l
120-12-7
Anthracene
ND
5.0
0.80
ug/l
56-55-3
Benzo(a)anthracene
ND
5.0
0.76
ug/l
50-32-8
Benzo(a)pyrene
ND
5.0
0.78
ug/l
205-99-2
Benzo(b)fluoranthene
ND
5.0
0.78
ug/l
191-24-2
Benzo(g, h, i)perylene
ND
5.0
0.82
ug/l
207-08-9
Benzo(k)fluoranthene
ND
5.0
0.86
ug/l
100-51-6
Benzyl Alcohol
ND
5.0
0.61
ug/1
101-55-3
4-Bromophenyl Phenyl Ether
ND
5.0
0.85
ug/l
85-68-7
Butyl Benzyl Phthalate
ND
5.0
1.0
ug/l
106-47-8
4-Chloroaniline
ND
5.0
0.63
ug/l
111-91-1
bis(2-Chloroethoxy)methane
ND
5.0
0.81
ug/l
111-44-4
bis(2-Chloroethyl)ether
ND
5.0
0.73
ug/l
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
5.0
0.76
ug/l
91-58-7
2-Chloronaphthalene
ND
5.0
0.50
ug/l
7005-72-3
4-Chlorophenyl Phenyl Ether
ND
5.0
0.54
ug/1
218-01-9
Chrysene
ND
5.0
0.85
ug/1
53-70-3
Dibenzo(a,h)anthracene
ND
5.0
0.80
ug/l
132-64-9
Dibenzofuran
ND
5.0
0.60
ug/l
95-50-1
1,2-Dichlorobenzene
ND
5.0
0.50
ug/l
541-73-1
1,3-Dichlorobenzene
ND
5.0
0.50
ug/l
GS81 of 122
FA98839

Method Blank Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 2 of 2
ample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
)P93061-MB
61715654.13
1
09/14/22
KA
09/14/22
OP93061
S6F587
The QC reported here applies to the following samples: Method: SW846 8270E
FA98839-8
CAS No. Compound
106-46-7
1,4-Dichlorobenzene
91-94-1
3,3'-Dichlorobenzidine
84-66-2
Diethyl Phthalate
131-11-3
Dimethyl Phthalate
84-74-2
Di-n-butyl Phthalate
117-84-0
Di-n-octyl Phthalate
122-66-7
1, 2-Diphenylhydrazine
117-81-7
bis(2-Ethylhexyl)phthalate
206-44-0
Fluoranthene
86-73-7
Fluorene
118-74-1
Hexachlorobenzene
87-68-3
Hexachlorobutadiene
77-47-4
Hexachlorocyclopentadiene
67-72-1
Hexachloroethane
193-39-5
Indeno(1,2,3-cd)pyrene
78-59-1
Isophorone
90-12-0
1-Methylnaphthalene
91-57-6
2-Methylnaphthalene
91-20-3
Naphthalene
98-95-3
Nitrobenzene
621-64-7
N-Nitrosodi-n-propylamine
86-30-6
N-Nitrosodiphenylamine
85-01-8
Phenanthrene
129-00-0
Pyrene
120-82-1
1,2,4-Trichlorobenzene
CAS No. Surrogate Recoveries
367-12-4 2-Fluorophenol
4165-62-2 Phenol-d5
118-79-6 2,4,6-Tribromophenol
4165-60-0 Nitrobenzene-d5
321-60-8 2-Fluorobiphenyl
1718-51-0 Terphenyl-d14
Result
RL
MDL
Units Q
ND
5.0
0.50
ug/l
ND
5.0
0.64
ug/l
ND
5.0
1.0
ug/l
ND
5.0
1.0
ug/l
ND
5.0
1.0
ug/l
ND
5.0
1.0
ug/l
ND
5.0
0.76
ug/l
ND
5.0
1.0
ug/l
ND
5.0
0.55
ug/l
ND
5.0
0.70
ug/l
ND
5.0
0.69
ug/l
ND
5.0
0.50
ug/l
ND
5.0
1.8
ug/l
ND
5.0
1.6
ug/l
ND
5.0
0.71
ug/1
ND
5.0
0.78
ug/l
ND
5.0
0.53
ug/l
ND
5.0
0.60
ug/l
ND
5.0
0.50
ug/l
ND
5.0
0.93
ug/l
ND
5.0
0.67
ug/l
ND
5.0
0.81
ug/l
ND
5.0
0.86
ug/1
ND
5.0
0.68
ug/l
ND
5.0
1.1
ug/l
Limits
46%
14-67%
33%
10-50%
89%
33-118%
79%
42-108%
78%
40-106%
87%
39-121%
GS82 of 122
FA98839

Method Blank Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 2
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
DP93061-MB
X083976.13
1
09/15/22
KA
09/14/22
OP93061
SX3329
The QC reported here applies to the following samples: Method: SW846 8270E
FA98839-8
CAS No. Compound
Result RL MDL Units Q
65-85-0
Benzoic Acid
ND
50
10
ug/l
59-50-7
4-Chloro-3-methyl Phenol
ND
5.0
0.59
ug/l
95-57-8
2-Chlorophenol
ND
5.0
0.63
ug/l
120-83-2
2,4-Dichlorophenol
ND
5.0
0.84
ug/l
105-67-9
2,4-Dimethylphenol
ND
5.0
0.74
ug/l
51-28-5
2,4-Dinitrophenol
ND
25
5.0
ug/l
534-52-1
4,6-Dinitro-o-cresol
ND
10
2.0
ug/l
95-48-7
2-Methylphenol
ND
5.0
0.56
ug/l
3&4-Methylphenol
ND
5.0
0.98
ug/l
88-75-5
2-Nitrophenol
ND
5.0
0.85
ug/l
100-02-7
4-Nitrophenol
ND
25
5.0
ug/l
87-86-5
Pentachlorophenol
ND
25
5.0
ug/l
108-95-2
Phenol
ND
5.0
0.50
ug/l
88-06-2
2,4,6-Trichlorophenol
ND
5.0
0.75
ug/l
83-32-9
Acenaphthene
ND
5.0
0.63
ug/1
208-96-8
Acenaphthylene
ND
5.0
0.64
ug/l
120-12-7
Anthracene
ND
5.0
0.80
ug/l
56-55-3
Benzo(a)anthracene
ND
5.0
0.76
ug/l
50-32-8
Benzo(a)pyrene
ND
5.0
0.78
ug/l
205-99-2
Benzo(b)fluoranthene
ND
5.0
0.78
ug/l
191-24-2
Benzo(g, h, i)perylene
ND
5.0
0.82
ug/l
207-08-9
Benzo(k)fluoranthene
ND
5.0
0.86
ug/l
100-51-6
Benzyl Alcohol
ND
5.0
0.61
ug/1
101-55-3
4-Bromophenyl Phenyl Ether
ND
5.0
0.85
ug/l
85-68-7
Butyl Benzyl Phthalate
ND
5.0
1.0
ug/l
106-47-8
4-Chloroaniline
ND
5.0
0.63
ug/l
111-91-1
bis(2-Chloroethoxy)methane
ND
5.0
0.81
ug/l
111-44-4
bis(2-Chloroethyl)ether
ND
5.0
0.73
ug/l
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
5.0
0.76
ug/l
91-58-7
2-Chloronaphthalene
ND
5.0
0.50
ug/l
7005-72-3
4-Chlorophenyl Phenyl Ether
ND
5.0
0.54
ug/1
218-01-9
Chrysene
ND
5.0
0.85
ug/1
53-70-3
Dibenzo(a,h)anthracene
ND
5.0
0.80
ug/l
132-64-9
Dibenzofuran
ND
5.0
0.60
ug/l
95-50-1
1,2-Dichlorobenzene
ND
5.0
0.50
ug/l
541-73-1
1,3-Dichlorobenzene
ND
5.0
0.50
ug/l
SGS83 of 122
FA98839

Method Blank Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 2 of 2
ample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
)P93061-MB
X083976.13
1
09/15/22
KA
09/14/22
OP93061
SX3329
The QC reported here applies to the following samples: Method: SW846 8270E
FA98839-8
CAS No. Compound
106-46-7
1,4-Dichlorobenzene
91-94-1
3,3'-Dichlorobenzidine
84-66-2
Diethyl Phthalate
131-11-3
Dimethyl Phthalate
84-74-2
Di-n-butyl Phthalate
117-84-0
Di-n-octyl Phthalate
122-66-7
1, 2-Diphenylhydrazine
117-81-7
bis(2-Ethylhexyl)phthalate
206-44-0
Fluoranthene
86-73-7
Fluorene
118-74-1
Hexachlorobenzene
87-68-3
Hexachlorobutadiene
77-47-4
Hexachlorocyclopentadiene
67-72-1
Hexachloroethane
193-39-5
Indeno(1,2,3-cd)pyrene
78-59-1
Isophorone
90-12-0
1-Methylnaphthalene
91-57-6
2-Methylnaphthalene
91-20-3
Naphthalene
98-95-3
Nitrobenzene
621-64-7
N-Nitrosodi-n-propylamine
86-30-6
N-Nitrosodiphenylamine
85-01-8
Phenanthrene
129-00-0
Pyrene
120-82-1
1,2,4-Trichlorobenzene
CAS No. Surrogate Recoveries
367-12-4 2-Fluorophenol
4165-62-2 Phenol-d5
118-79-6 2,4,6-Tribromophenol
4165-60-0 Nitrobenzene-d5
321-60-8 2-Fluorobiphenyl
1718-51-0 Terphenyl-d14
Result
RL
MDL
Units Q
ND
5.0
0.50
ug/l
ND
5.0
0.64
ug/l
ND
5.0
1.0
ug/l
ND
5.0
1.0
ug/l
ND
5.0
1.0
ug/l
ND
5.0
1.0
ug/l
ND
5.0
0.76
ug/l
ND
5.0
1.0
ug/l
ND
5.0
0.55
ug/l
ND
5.0
0.70
ug/l
ND
5.0
0.69
ug/l
ND
5.0
0.50
ug/l
ND
5.0
1.8
ug/l
ND
5.0
1.6
ug/l
ND
5.0
0.71
ug/1
ND
5.0
0.78
ug/l
ND
5.0
0.53
ug/l
ND
5.0
0.60
ug/l
ND
5.0
0.50
ug/l
ND
5.0
0.93
ug/l
ND
5.0
0.67
ug/l
ND
5.0
0.81
ug/l
ND
5.0
0.86
ug/1
ND
5.0
0.68
ug/l
ND
5.0
1.1
ug/l
Limits
47%
14-67%
33%
10-50%
61%
33-118%
66%
42-108%
74%
40-106%
102%
39-121%
GS84 of 122
FA98839

Blank Spike Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 2
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
OP93050-BS
X083984.13
1
09/15/22
KA
09/14/22
OP93050
SX3330
The QC reported here applies to the following samples: Method: SW846 8270E
FA98839-3, FA98839-4, FA98839-6, FA98839-7
CAS No. Compound
Spike BSP BSP
ug/kg ug/kg % Limits
65-85-0
Benzoic Acid
3330
3230
97
36-118
59-50-7
4-Chloro-3-methyl Phenol
1670
1520
91
52-108
95-57-8
2-Chlorophenol
1670
1340
80
48-104
120-83-2
2,4-Dichlorophenol
1670
1400
84
51-105
105-67-9
2,4-Dimethylphenol
1670
1320
79
43-96
51-28-5
2,4-Dinitrophenol
3330
2940
88
40-119
534-52-1
4,6-Dinitro-o-cresol
3330
3190
96
64-121
95-48-7
2-Methylphenol
1670
1340
80
46-107
3&4-Methylphenol
3330
2870
86
44-111
88-75-5
2-Nitrophenol
1670
1340
80
49-104
100-02-7
4-Nitrophenol
3330
3210
96
56-116
87-86-5
Pentachlorophenol
3330
2680
80
61-114
108-95-2
Phenol
1670
1330
80
45-110
88-06-2
2,4,6-Trichlorophenol
1670
1490
89
56-109
83-32-9
Acenaphthene
1670
1380
83
56-109
208-96-8
Acenaphthylene
1670
1410
85
56-106
120-12-7
Anthracene
1670
1350
81
61-110
56-55-3
Benzo(a)anthracene
1670
1800
108
66-111
50-32-8
Benzo(a)pyrene
1670
1580
95
59-104
205-99-2
Benzo(b)fluoranthene
1670
1570
94
67-113
191-24-2
Benzo(g, h, i)perylene
1670
1610
97
67-113
207-08-9
Benzo(k)fluoranthene
1670
1580
95
67-114
100-51-6
Benzyl Alcohol
1670
1350
81
53-108
101-55-3
4-Bromophenyl phenyl ether
1670
1350
81
62-110
85-68-7
Butyl benzyl phthalate
1670
1910
115*
65-113
106-47-8
4-Chloroaniline
1670
1260
76
30-115
111-91-1
bis(2-Chloroethoxy)methane
1670
1370
82
48-105
111-44-4
bis(2-Chloroethyl)ether
1670
1240
74
46-103
108-60-1
2,2'-Oxybis(1-chloropropane)
1670
1250
75
40-110
91-58-7
2-Chloronaphthalene
1670
1360
82
53-106
7005-72-3
4-Chlorophenyl phenyl ether
1670
1390
83
58-106
218-01-9
Chrysene
1670
1780
107
65-112
53-70-3
Dibenzo(a,h)anthracene
1670
1620
97
68-115
132-64-9
Dibenzofuran
1670
1390
83
57-108
95-50-1
1,2-Dichlorobenzene
1670
1220
73
44-102
541-73-1
1,3-Dichlorobenzene
1670
1180
71
42-100
* = Outside of Control Limits.
GS85 of 122
FA98839

Blank Spike Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 2 of 2
ample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
)P93050-13S
X083984.13
1
09/15/22
KA
09/14/22
OP93050
SX3330
The QC reported here applies to the following samples: Method: SW846 8270E
FA98839-3, FA98839-4, FA98839-6, FA98839-7
Spike
BSP
BSP
CAS No.
Compound
ug/kg
ug/kg
%
Limits
106-46-7
1,4-Dichlorobenzene
1670
1160
70
40-106
91-94-1
3,3'-Dichlorobenzidine
1670
1560
94
36-114
84-66-2
Diethyl Phthalate
1670
1560
94
61-109
131-11-3
Dimethyl Phthalate
1670
1480
89
59-108
117-84-0
Di-n-octyl Phthalate
1670
2010
121*
64-119
84-74-2
Di-n-butyl Phthalate
1670
1630
98
63-108
122-66-7
1,2-Diphenylhydrazine
1670
1460
88
58-112
117-81-7
bis(2-Ethylhexyl)phthalate
1670
1840
110
64-115
206-44-0
Fluoranthene
1670
1530
92
60-108
86-73-7
Fluorene
1670
1440
86
58-109
118-74-1
Hexachlorobenzene
1670
1170
70
59-111
87-68-3
Hexachlorobutadiene
1670
1210
73
41-108
77-47-4
Hexachlorocyclopentadiene
1670
1280
77
49-110
67-72-1
Hexachloroethane
1670
1250
75
40-105
193-39-5
Indeno(1,2,3-cd)pyrene
1670
1810
109
66-116
78-59-1
Isophorone
1670
1320
79
42-89
90-12-0
1-Methylnaphthalene
1670
1390
83
49-106
91-57-6
2-Methylnaphthalene
1670
1390
83
47-106
91-20-3
Naphthalene
1670
1310
79
44-104
98-95-3
Nitrobenzene
1670
1320
79
43-108
621-64-7
N-Nitrosodi-n-propylamine
1670
1290
77
48-108
86-30-6
N-Nitrosodiphenylamine
1670
1410
85
62-110
85-01-8
Phenanthrene
1670
1440
86
63-111
129-00-0
Pyrene
1670
1770
106
65-115
120-82-1
1,2,4-Trichlorobenzene
1670
1270
76
45-100
CAS No.
Surrogate Recoveries
BSP
Limits
367-12-4
2-Fluorophenol
75%
40-102%
4165-62-2
Phenol-d5
77%
41-100%
118-79-6
2,4,6-Tribromophenol
62%
42-108%
4165-60-0
Nitrobenzene-d5
71%
40-105%
321-60-8
2-Fluorobiphenyl
73%
43-107%
1718-51-0
Terphenyl-d14
93%
45-119%
* = Outside of Control Limits.
GS86 of 122
FA98839

Blank Spike Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 2
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
OP93061-BS
61715653.13
1
09/14/22
KA
09/14/22
OP93061
S6F587
The QC reported here applies to the following samples: Method: SW846 8270E
FA98839-8
CAS No. Compound
Spike BSP BSP
ug/1 ug/l % Limits
65-85-0
Benzoic Acid
100
42.3
42
10-69
59-50-7
4-Chloro-3-methyl Phenol
50
46.6
93
54-103
95-57-8
2-Chlorophenol
50
42.1
84
52-98
120-83-2
2,4-Dichlorophenol
50
48.3
97
53-103
105-67-9
2,4-Dimethylphenol
50
44.1
88
43-90
51-28-5
2,4-Dinitrophenol
100
102
102
44-112
534-52-1
4,6-Dinitro-o-cresol
100
ill
ill
66-121
95-48-7
2-Methylphenol
50
37.3
75
43-90
3&4-Methylphenol
100
72.7
73
36-88
88-75-5
2-Nitrophenol
50
49.0
98
53-102
100-02-7
4-Nitrophenol
100
46.2
46
18-62
87-86-5
Pentachlorophenol
100
102
102
61-115
108-95-2
Phenol
50
23.9
48
19-56
88-06-2
2,4,6-Trichlorophenol
50
56.9
114*
59-107
83-32-9
Acenaphthene
50
47.1
94
61-107
208-96-8
Acenaphthylene
50
48.9
98
60-104
120-12-7
Anthracene
50
47.3
95
65-108
56-55-3
Benzo(a)anthracene
50
54.2
108
66-111
50-32-8
Benzo(a)pyrene
50
53.3
107
62-107
205-99-2
Benzo(b)fluoranthene
50
54.5
109
65-114
191-24-2
Benzo(g, h, i)perylene
50
52.1
104
66-116
207-08-9
Benzo(k)fluoranthene
50
51.1
102
65-114
100-51-6
Benzyl Alcohol
50
42.6
85
46-94
101-55-3
4-BromophenylPhenyl Ether
50
50.8
102
65-109
85-68-7
Butyl Benzyl Phthalate
50
54.1
108
65-112
106-47-8
4-Chloroaniline
50
41.6
83
49-105
111-91-1
bis(2-Chloroethoxy)methane
50
49.7
99
51-102
111-44-4
bis(2-Chloroethyl)ether
50
48.7
97
53-100
108-60-1
2,2'-Oxybis(1-chloropropane)
50
54.7
109*
45-106
91-58-7
2-Chloronaphthalene
50
49.5
99
57-103
7005-72-3
4-Chlorophenyl Phenyl Ether
50
52.5
105
62-105
218-01-9
Chrysene
50
53.1
106
66-111
53-70-3
Dibenzo(a,h)anthracene
50
53.3
107
66-119
132-64-9
Dibenzofuran
50
47.0
94
61-106
95-50-1
1,2-Dichlorobenzene
50
44.5
89
48-97
541-73-1
1,3-Dichlorobenzene
50
44.1
88
45-95
* = Outside of Control Limits.
GS87 of 122
FA98839

Blank Spike Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 2 of 2
ample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
)P93061-13S
61715653.13
1
09/14/22
KA
09/14/22
OP93061
S6F587
The QC reported here applies to the following samples:
FA98839-8
Spike
BSP
BSP
CAS No.
Compound
ug/1
ug/l
%
Limits
106-46-7
1,4-Dichlorobenzene
50
44.1
88
45-98
91-94-1
3,3'-Dichlorobenzidine
50
55.4
ill
46-117
84-66-2
Diethyl Phthalate
50
52.8
106
64-108
131-11-3
Dimethyl Phthalate
50
50.2
100
63-106
84-74-2
Di-n-butyl Phthalate
50
50.5
101
65-107
117-84-0
Di-n-octyl Phthalate
50
52.9
106
62-118
122-66-7
1,2-Diphenylhydrazine
50
49.2
98
61-110
117-81-7
bis(2-Ethylhexyl)phthalate
50
53.2
106
61-117
206-44-0
Fluoranthene
50
50.1
100
63-106
86-73-7
Fluorene
50
51.1
102
62-108
118-74-1
Hexachlorobenzene
50
48.4
97
63-108
87-68-3
Hexachlorobutadiene
50
50.0
100
42-102
77-47-4
Hexachlorocyclopentadiene
50
52.3
105*
39-102
67-72-1
Hexachloroethane
50
46.8
94
42-100
193-39-5
Indeno(1,2,3-cd)pyrene
50
56.6
113
64-119
78-59-1
Isophorone
50
48.0
96*
43-87
90-12-0
1-Methylnaphthalene
50
47.3
95
53-102
91-57-6
2-Methylnaphthalene
50
49.3
99
51-102
91-20-3
Naphthalene
50
43.5
87
47-100
98-95-3
Nitrobenzene
50
48.5
97
50-104
621-64-7
N-Nitrosodi-n-propylamine
50
48.7
97
52-104
86-30-6
N-Nitrosodiphenylamine
50
43.2
86
64-108
85-01-8
Phenanthrene
50
48.5
97
66-110
129-00-0
Pyrene
50
53.0
106
64-113
120-82-1
1,2,4-Trichlorobenzene
50
49.6
99*
45-97
CAS No.
Surrogate Recoveries
BSP
Limits
367-12-4
2-Fluorophenol
55%
14-67%
4165-62-2
Phenol-d5
39%
10-50%
118-79-6
2,4,6-Tribromophenol
93%
33-118%
4165-60-0
Nitrobenzene-d5
86%
42-108%
321-60-8
2-Fluorobiphenyl
86%
40-106%
1718-51-0
Terphenyl-d14
93%
39-121%
* = Outside of Control Limits.
Method: SW846 8270E
GS88 of 122
FA98839

Blank Spike Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 2
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
OP93061-BS
X083975.13
1
09/15/22
KA
09/14/22
OP93061
SX3329
The QC reported here applies to the following samples: Method: SW846 8270E
FA98839-8
CAS No. Compound
Spike BSP BSP
ug/1 ug/l % Limits
65-85-0
Benzoic Acid
100
49.1
49
10-69
59-50-7
4-Chloro-3-methyl Phenol
50
42.2
84
54-103
95-57-8
2-Chlorophenol
50
38.4
77
52-98
120-83-2
2,4-Dichlorophenol
50
41.1
82
53-103
105-67-9
2,4-Dimethylphenol
50
40.4
81
43-90
51-28-5
2,4-Dinitrophenol
100
85.3
85
44-112
534-52-1
4,6-Dinitro-o-cresol
100
96.2
96
66-121
95-48-7
2-Methylphenol
50
34.3
69
43-90
3&4-Methylphenol
100
67.2
67
36-88
88-75-5
2-Nitrophenol
50
43.4
87
53-102
100-02-7
4-Nitrophenol
100
53.1
53
18-62
87-86-5
Pentachlorophenol
100
86.5
87
61-115
108-95-2
Phenol
50
18.4
37
19-56
88-06-2
2,4,6-Trichlorophenol
50
46.4
93
59-107
83-32-9
Acenaphthene
50
44.4
89
61-107
208-96-8
Acenaphthylene
50
44.3
89
60-104
120-12-7
Anthracene
50
43.5
87
65-108
56-55-3
Benzo(a)anthracene
50
57.0
114*
66-111
50-32-8
Benzo(a)pyrene
50
52.0
104
62-107
205-99-2
Benzo(b)fluoranthene
50
51.2
102
65-114
191-24-2
Benzo(g, h, i)perylene
50
50.3
101
66-116
207-08-9
Benzo(k)fluoranthene
50
47.6
95
65-114
100-51-6
Benzyl Alcohol
50
36.1
72
46-94
101-55-3
4-BromophenylPhenyl Ether
50
43.2
86
65-109
85-68-7
Butyl Benzyl Phthalate
50
61.2
122*
65-112
106-47-8
4-Chloroaniline
50
38.1
76
49-105
111-91-1
bis(2-Chloroethoxy)methane
50
45.1
90
51-102
111-44-4
bis(2-Chloroethyl)ether
50
42.2
84
53-100
108-60-1
2,2'-Oxybis(1-chloropropane)
50
41.8
84
45-106
91-58-7
2-Chloronaphthalene
50
43.6
87
57-103
7005-72-3
4-Chlorophenyl Phenyl Ether
50
44.0
88
62-105
218-01-9
Chrysene
50
54.3
109
66-111
53-70-3
Dibenzo(a,h)anthracene
50
53.6
107
66-119
132-64-9
Dibenzofuran
50
43.1
86
61-106
95-50-1
1,2-Dichlorobenzene
50
40.3
81
48-97
541-73-1
1,3-Dichlorobenzene
50
40.4
81
45-95
* = Outside of Control Limits.
GS89 of 122
FA98839

Blank Spike Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 2 of 2
ample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
)P93061-13S
X083975.13
1
09/15/22
KA
09/14/22
OP93061
SX3329
The QC reported here applies to the following samples:
FA98839-8
Spike
BSP
BSP
CAS No.
Compound
ug/1
ug/l
%
Limits
106-46-7
1,4-Dichlorobenzene
50
39.9
80
45-98
91-94-1
3,3'-Dichlorobenzidine
50
54.8
110
46-117
84-66-2
Diethyl Phthalate
50
49.2
98
64-108
131-11-3
Dimethyl Phthalate
50
46.6
93
63-106
84-74-2
Di-n-butyl Phthalate
50
52.9
106
65-107
117-84-0
Di-n-octyl Phthalate
50
70.6
141*
62-118
122-66-7
1,2-Diphenylhydrazine
50
43.1
86
61-110
117-81-7
bis(2-Ethylhexyl)phthalate
50
60.9
122*
61-117
206-44-0
Fluoranthene
50
47.9
96
63-106
86-73-7
Fluorene
50
45.4
91
62-108
118-74-1
Hexachlorobenzene
50
37.0
74
63-108
87-68-3
Hexachlorobutadiene
50
40.2
80
42-102
77-47-4
Hexachlorocyclopentadiene
50
38.7
77
39-102
67-72-1
Hexachloroethane
50
41.2
82
42-100
193-39-5
Indeno(1,2,3-cd)pyrene
50
64.1
128*
64-119
78-59-1
Isophorone
50
43.7
87
43-87
90-12-0
1-Methylnaphthalene
50
44.3
89
53-102
91-57-6
2-Methylnaphthalene
50
44.0
88
51-102
91-20-3
Naphthalene
50
43.0
86
47-100
98-95-3
Nitrobenzene
50
43.7
87
50-104
621-64-7
N-Nitrosodi-n-propylamine
50
42.1
84
52-104
86-30-6
N-Nitrosodiphenylamine
50
45.2
90
64-108
85-01-8
Phenanthrene
50
44.7
89
66-110
129-00-0
Pyrene
50
55.2
110
64-113
120-82-1
1,2,4-Trichlorobenzene
50
41.5
83
45-97
CAS No.
Surrogate Recoveries
BSP
Limits
367-12-4
2-Fluorophenol
49%
14-67%
4165-62-2
Phenol-d5
35%
10-50%
118-79-6
2,4,6-Tribromophenol
68%
33-118%
4165-60-0
Nitrobenzene-d5
77%
42-108%
321-60-8
2-Fluorobiphenyl
79%
40-106%
1718-51-0
Terphenyl-d14
98%
39-121%
* = Outside of Control Limits.
Method: SW846 8270E
SGS90 of 122
FA98839

Matrix Spike/Matrix Spike Duplicate Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 2
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
OP93050-MS
X084005.13
1
09/15/22
KA
09/14/22
OP93050
SX3330
OP93050-MSD
X084006.13
1
09/15/22
KA
09/14/22
OP93050
SX3330
FA98870-2
X083986.13
1
09/15/22
KA
09/14/22
OP93050
SX3330
The QC reported here applies to the following samples:
FA98839-3, FA98839-4, FA98839-6, FA98839-7
CAS No. Compound
FA98870-2 Spike MS MS
ug/kg Q ug/kg ug/kg %
Method: SW846 8270E
Spike MSD MSD Limits
ug/kg ug/kg % RPD Rec/RPD
65-85-0
Benzoic Acid
980 U
3940
3830
97
3940
4030
102
5
36-118/41
59-50-7
4-Chloro-3-methyl Phenol
200 U
1970
1620
82
1970
1690
86
4
52-108/21
95-57-8
2-Chlorophenol
200 U
1970
1450
74
1970
1510
77
4
48-104/26
120-83-2
2,4-Dichlorophenol
200 U
1970
1570
80
1970
1650
84
5
51-105/27
105-67-9
2,4-Dimethylphenol
200 U
1970
1380
70
1970
1480
75
7
43-96/23
51-28-5
2,4-Dinitrophenol
980 U
3940
2490
63
3940
2680
68
7
40-119/32
534-52-1
4,6-Dinitro-o-cresol
390 U
3940
2940
75
3940
3160
80
7
64-121/29
95-48-7
2-Methylphenol
200 U
1970
1350
69
1970
1420
72
5
46-107/24
3&4-Methylphenol
200 U
3940
2880
73
3940
3080
78
7
44-111/24
88-75-5
2-Nitrophenol
200 U
1970
1470
75
1970
1570
80
7
49-104/27
100-02-7
4-Nitrophenol
980 U
3940
3460
88
3940
3710
94
7
56-116/23
87-86-5
Pentachlorophenol
980 U
3940
3380
86
3940
3520
89
4
61-114/23
108-95-2
Phenol
200 U
1970
1330
68
1970
1410
72
6
45-110/24
88-06-2
2,4,6-Trichlorophenol
200 U
1970
1690
86
1970
1820
92
7
56-109/25
83-32-9
Acenaphthene
200 U
1970
1430
73
1970
1540
78
7
56-109/23
208-96-8
Acenaphthylene
200 U
1970
1490
76
1970
1580
80
6
56-106/23
120-12-7
Anthracene
200 U
1970
1430
73
1970
1510
77
5
61-110/21
56-55-3
Benzo(a)anthracene
200 U
1970
1870
95
1970
1990
101
6
66-111/23
50-32-8
Benzo(a)pyrene
200 U
1970
1750
89
1970
1860
95
6
59-104/23
205-99-2
Benzo(b)fluoranthene
200 U
1970
1760
89
1970
1880
96
7
67-113/24
191-24-2
Benzo(g, h, i)perylene
200 U
1970
1780
90
1970
1890
96
6
67-113/21
207-08-9
Benzo(k)fluoranthene
200 U
1970
1540
78
1970
1650
84
7
67-114/22
100-51-6
Benzyl Alcohol
200 U
1970
1370
70
1970
1450
74
6
53-108/24
101-55-3
4-Bromophenyl phenyl ether
200 U
1970
1530
78
1970
1600
81
4
62-110/21
85-68-7
Butyl benzyl phthalate
200 U
1970
2060
105
1970
2150
109
4
65-113/20
106-47-8
4-Chloroaniline
200 U
1970
1290
66
1970
1370
70
6
30-115/30
111-91-1
bis(2-Chloroethoxy)methane
200 U
1970
1360
69
1970
1430
73
5
48-105/24
111-44-4
bis(2-Chloroethyl)ether
200 U
1970
1270
65
1970
1340
68
5
46-103/27
108-60-1
2,2'-Oxybis(1-chloropropane)
200 U
1970
1030
52
1970
1090
55
6
40-110/25
91-58-7
2-Chloronaphthalene
200 U
1970
1420
72
1970
1530
78
7
53-106/23
7005-72-3
4-Chlorophenyl phenyl ether
200 U
1970
1570
80
1970
1670
85
6
58-106/21
218-01-9
Chrysene
200 U
1970
1790
91
1970
1880
96
5
65-112/25
53-70-3
Dibenzo(a,h)anthracene
200 U
1970
1950
99
1970
2050
104
5
68-115/23
132-64-9
Dibenzofuran
200 U
1970
1490
76
1970
1590
81
6
57-108/22
95-50-1
1,2-Dichlorobenzene
200 U
1970
1370
70
1970
1430
73
4
44-102/28
541-73-1
1, 3 -Dichlorobenzene
200 U
1970
1370
70
1970
1430
73
4
42-100/30
* = Outside of Control Limits.
SGS91 of 122
FA98839

Matrix Spike/Matrix Spike Duplicate Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 2 of 2
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
OP93050-MS
X084005.13
1
09/15/22
KA
09/14/22
OP93050
SX3330
OP93050-MSD
X084006.13
1
09/15/22
KA
09/14/22
OP93050
SX3330
FA98870-2
X083986.13
1
09/15/22
KA
09/14/22
OP93050
SX3330
The QC reported here applies to the following samples:
FA98839-3, FA98839-4, FA98839-6, FA98839-7
CAS No. Compound
FA98870-2 Spike MS MS
ug/kg Q ug/kg ug/kg %
Method: SW846 8270E
Spike MSD MSD Limits
ug/kg ug/kg % RPD Rec/RPD
106-46-7
1,4-Dichlorobenzene
200 U
1970
1330
68
1970
1390
71
4
40-106/29
91-94-1
3,3'-Dichlorobenzidine
200 U
1970
1900
97
1970
1990
101
5
36-114/28
84-66-2
Diethyl Phthalate
390 U
1970
1650
84
1970
1800
91
9
61-109/20
131-11-3
Dimethyl Phthalate
200 U
1970
1580
80
1970
1670
85
6
59-108/20
117-84-0
Di-n-octyl Phthalate
200 U
1970
2440
124*
1970
2570
131*
5
64-119/21
84-74-2
Di-n-butyl Phthalate
390 U
1970
1750
89
1970
1840
94
5
63-108/19
122-66-7
1,2-Diphenylhydrazine
200 U
1970
1280
65
1970
1360
69
6
58-112/22
117-81-7
bis(2-Ethylhexyl)phthalate
390 U
1970
2120
108
1970
2200
112
4
64-115/23
206-44-0
Fluoranthene
200 U
1970
1620
82
1970
1690
86
4
60-108/25
86-73-7
Fluorene
200 U
1970
1560
79
1970
1650
84
6
58-109/21
118-74-1
Hexachlorobenzene
200 U
1970
1350
69
1970
1430
73
6
59-111/21
87-68-3
Hexachlorobutadiene
200 U
1970
1460
74
1970
1540
78
5
41-108/27
77-47-4
Hexachlorocyclopentadiene
200 U
1970
1090
55
1970
1170
59
7
49-110/31
67-72-1
Hexachloroethane
200 U
1970
1310
67
1970
1380
70
5
40-105/32
193-39-5
Indeno(1,2,3-cd)pyrene
200 U
1970
2430
123*
1970
2530
129*
4
66-116/22
78-59-1
Isophorone
200 U
1970
1260
64
1970
1340
68
6
42-89/22
90-12-0
1-Methylnaphthalene
200 U
1970
1540
78
1970
1600
81
4
49-106/26
91-57-6
2-Methylnaphthalene
200 U
1970
1550
79
1970
1620
82
4
47-106/27
91-20-3
Naphthalene
200 U
1970
1420
72
1970
1470
75
3
44-104/27
98-95-3
Nitrobenzene
200 U
1970
1260
64
1970
1300
66
3
43-108/25
621-64-7
N-Nitrosodi-n-propylamine
200 U
1970
1170
59
1970
1230
63
5
48-108/27
86-30-6
N-Nitrosodiphenylamine
200 U
1970
1480
75
1970
1590
81
7
62-110/21
85-01-8
Phenanthrene
200 U
1970
1470
75
1970
1580
80
7
63-111/22
129-00-0
Pyrene
200 U
1970
1750
89
1970
1870
95
7
65-115/25
120-82-1
1,2,4-Trichlorobenzene
200 U
1970
1490
76
1970
1570
80
5
45-100/26
CAS No.
Surrogate Recoveries
MS
MSD
FA98870-2
Limits
367-12-4
2-Fluorophenol
67%
71%
82%
40-102%
4165-62-2
Phenol-d5
68%
73%
87%
41-100%
118-79-6
2,4,6-Tribromophenol
68%
74%
55%
42-108%
4165-60-0
Nitrobenzene-d5
57%
62%
74%
40-105%
321-60-8
2-Fluorobiphenyl
67%
73%
76%
43-107%
1718-51-0
Terphenyl-d14
86%
92%
101%
45-119%
* = Outside of Control Limits.
SGS92 of 122
FA98839

Matrix Spike/Matrix Spike Duplicate Summary
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Page 1 of 2
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
OP93061-MS
61715670.13
1
09/14/22
KA
09/14/22
OP93061
S6F587
OP93061-MSD
61715671.13
1
09/14/22
KA
09/14/22
OP93061
S617587
FA98757-2
6F15661.D
1
09/14/22
KA
09/14/22
OP93061
S6F587
The QC reported here applies to the following samples:
FA98839-8
CAS No. Compound
FA98757-2 Spike MS
ug/1 Q ug/l ug/l
Method: SW846 8270E
MS Spike MSD MSD Limits
% ug/l ug/1 % RPD Rec/RPD
65-85-0
Benzoic Acid
ND
192
67.1
35
192
54.0
28
22
10-69/39
59-50-7
4-Chloro-3-methyl Phenol
ND
96.2
77.0
80
96.2
75.0
78
3
54-103/23
95-57-8
2-Chlorophenol
ND
96.2
71.9
75
96.2
68.2
71
5
52-98/25
120-83-2
2,4-Dichlorophenol
ND
96.2
79.8
83
96.2
79.0
82
1
53-103/26
105-67-9
2,4-Dimethylphenol
ND
96.2
71.3
74
96.2
69.5
72
3
43-90/27
51-28-5
2,4-Dinitrophenol
ND
192
150
78
192
142
74
5
44-112/25
534-52-1
4,6-Dinitro-o-cresol
ND
192
165
86
192
163
85
1
66-121/23
95-48-7
2-Methylphenol
ND
96.2
63.5
66
96.2
58.7
61
8
43-90/28
3&4-Methylphenol
ND
192
123
64
192
114
59
8
36-88/28
88-75-5
2-Nitrophenol
ND
96.2
81.9
85
96.2
81.6
85
0
53-102/29
100-02-7
4-Nitrophenol
ND
192
86.1
45
192
80.2
42
7
18-62/33
87-86-5
Pentachlorophenol
ND
192
175
91
192
170
88
3
61-115/26
108-95-2
Phenol
ND
96.2
40.7
42
96.2
36.4
38
11
19-56/35
88-06-2
2,4,6-Trichlorophenol
ND
96.2
91.2
95
96.2
92.2
96
1
59-107/23
83-32-9
Acenaphthene
ND
96.2
80.1
83
96.2
80.7
84
1
61-107/22
208-96-8
Acenaphthylene
ND
96.2
83.8
87
96.2
82.6
86
1
60-104/22
120-12-7
Anthracene
ND
96.2
79.3
82
96.2
79.1
82
0
65-108/20
56-55-3
Benzo(a)anthracene
ND
96.2
90.9
95
96.2
89.7
93
1
66-111/22
50-32-8
Benzo(a)pyrene
ND
96.2
91.1
95
96.2
89.7
93
2
62-107/23
205-99-2
Benzo(b)fluoranthene
ND
96.2
89.2
93
96.2
88.4
92
1
65-114/23
191-24-2
Benzo(g, h, i)perylene
ND
96.2
86.6
90
96.2
85.6
89
1
66-116/23
207-08-9
Benzo(k)fluoranthene
ND
96.2
91.9
96
96.2
90.9
95
1
65-114/24
100-51-6
Benzyl Alcohol
ND
96.2
61.5
64
96.2
45.5
47
30*
46-94/27
101-55-3
4-BromophenylPhenyl Ether
ND
96.2
84.7
88
96.2
84.4
88
0
65-109/23
85-68-7
Butyl Benzyl Phthalate
ND
96.2
93.1
97
96.2
92.2
96
1
65-112/24
106-47-8
4-Chloroaniline
ND
96.2
57.5
60
96.2
48.5
50
17
49-105/27
111-91-1
bis(2-Chloroethoxy)methane
ND
96.2
85.8
89
96.2
83.8
87
2
51-102/28
111-44-4
bis(2-Chloroethyl)ether
ND
96.2
92.9
97
96.2
95.7
100
3
53-100/27
108-60-1
2,2'-Oxybis(1-chloropropane)
ND
96.2
99.0
103
96.2
93.5
97
6
45-106/26
91-58-7
2-Chloronaphthalene
ND
96.2
84.1
87
96.2
84.3
88
0
57-103/23
7005-72-3
4-ChlorophenylPhenyl Ether
ND
96.2
88.2
92
96.2
88.3
92
0
62-105/20
218-01-9
Chrysene
ND
96.2
92.1
96
96.2
92.0
96
0
66-111/22
53-70-3
Dibenzo(a,h)anthracene
ND
96.2
89.6
93
96.2
88.5
92
1
66-119/24
132-64-9
Dibenzofuran
ND
96.2
80.3
84
96.2
79.9
83
0
61-106/21
95-50-1
1,2-Dichlorobenzene
ND
96.2
79.8
83
96.2
76.3
79
4
48-97/24
541-73-1
1, 3 -Dichlorobenzene
ND
96.2
78.4
82
96.2
75.5
79
4
45-95/25
* = Outside of Control Limits.
SGS93 of 122
FA98839

Matrix Spike/Matrix Spike Duplicate Summary Page 2 of
Job Number: FA98839
Account: GSYNNCW Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
Sample
File ID
DF
Analyzed
By
Prep Date
Prep Batch
Analytical Batch
DP93061-MS
61715670.13
1
09/14/22
KA
09/14/22
OP93061
S6F587
DP93061-MSD
61715671.13
1
09/14/22
KA
09/14/22
OP93061
S617587
FA98757-2
6F15661.D
1
09/14/22
KA
09/14/22
OP93061
S6F587
The QC reported here applies to the following samples:
FA98839-8
CAS No. Compound
FA98757-2 Spike MS
ug/l Q ug/l ug/l
Method: SW846 8270E
MS Spike MSD MSD Limits
% ug/l ug/1 % RPD Rec/RPD
106-46-7
1,4-Dichlorobenzene
ND
96.2
78.9
82
96.2
75.4
78
5
45-98/25
91-94-1
3,3'-Dichlorobenzidine
ND
96.2
69.9
73
96.2
69.8
73
0
46-117/29
84-66-2
Diethyl Phthalate
ND
96.2
90.3
94
96.2
88.9
92
2
64-108/21
131-11-3
Dimethyl Phthalate
ND
96.2
84.4
88
96.2
83.9
87
1
63-106/22
84-74-2
Di-n-butyl Phthalate
ND
96.2
86.8
90
96.2
85.6
89
1
65-107/21
117-84-0
Di-n-octyl Phthalate
ND
96.2
96.7
101
96.2
94.7
98
2
62-118/24
122-66-7
1,2-Diphenylhydrazine
ND
96.2
82.3
86
96.2
82.2
85
0
61-110/24
117-81-7
bis(2-Ethylhexyl)phthalate
ND
96.2
93.2
97
96.2
92.0
96
1
61-117/23
206-44-0
Fluoranthene
ND
96.2
87.4
91
96.2
87.7
91
0
63-106/21
86-73-7
Fluorene
ND
96.2
87.8
91
96.2
86.9
90
1
62-108/20
118-74-1
Hexachlorobenzene
ND
96.2
79.5
83
96.2
80.4
84
1
63-108/22
87-68-3
Hexachlorobutadiene
ND
96.2
85.8
89
96.2
85.6
89
0
42-102/28
77-47-4
Hexachlorocyclopentadiene
ND
96.2
90.6
94
96.2
91.3
95
1
39-102/29
67-72-1
Hexachloroethane
ND
96.2
82.7
86
96.2
80.3
84
3
42-100/29
193-39-5
Indeno(1,2,3-cd)pyrene
ND
96.2
95.0
99
96.2
93.7
97
1
64-119/24
78-59-1
Isophorone
ND
96.2
83.6
87
96.2
81.4
85
3
43-87/25
90-12-0
1-Methylnaphthalene
ND
96.2
81.2
84
96.2
80.5
84
1
53-102/27
91-57-6
2-Methylnaphthalene
ND
96.2
86.0
89
96.2
83.7
87
3
51-102/26
91-20-3
Naphthalene
ND
96.2
75.5
79
96.2
73.9
77
2
47-100/29
98-95-3
Nitrobenzene
ND
96.2
88.0
92
96.2
88.3
92
0
50-104/28
621-64-7
N-Nitrosodi-n-propylamine
ND
96.2
87.0
90
96.2
81.8
85
6
52-104/25
86-30-6
N-Nitrosodiphenylamine
ND
96.2
73.1
76
96.2
72.3
75
1
64-108/23
85-01-8
Phenanthrene
ND
96.2
82.9
86
96.2
82.2
85
1
66-110/21
129-00-0
Pyrene
ND
96.2
89.6
93
96.2
89.1
93
1
64-113/23
120-82-1
1,2,4-Trichlorobenzene
ND
96.2
86.4
90
96.2
84.9
88
2
45-97/28
CAS No.
Surrogate Recoveries
MS
MSD
FA98757-2
Limits
367-12-4
2-Fluorophenol
48%
44%
27%
14-67%
4165-62-2
Phenol-d5
37%
33%
18%
10-50%
118-79-6
2,4,6-Tribromophenol
79%
78%
82%
33-118%
4165-60-0
Nitrobenzene-d5
78%
77%
72%
42-108%
321-60-8
2-Fluorobiphenyl
76%
76%
71%
40-106%
1718-51-0
Terphenyl-d14
78%
77%
80%
39-121%
* = Outside of Control Limits.
SGS94 of 122
FA98839

Orlando, FL ,I
Metals Analysis
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Matrix Spike and Duplicate Summaries
• Blank Spike and Lab Control Sample Summaries
• Serial Dilution Summaries
Section 7
SGS95 of 122
FA98839

BLANK RESULTS SUMMARY
Part 2 - Method Blanks
Login Number: FA98839
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41212 Methods: SW846 7471B
Matrix Type: SOLID Units: mg/kg
Prep Date:
MB
letal RL IDL MDL raw final
Mercury 0.042 .0025 .0042-0.00033 <0.042
Associated samples MP41212: FA98839-3, FA98839-4, FA98839-6
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
V
i
Page 1
GS96 of 122
FA98839

MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA98839
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41212 Methods: SW846 7471B
Matrix Type: SOLID Units: mg/kg
Prep Date:
FA98781-1A QC FA98781-1A Spikelot QC
Metal Original DUP RPD Limits Original MS HGFLWSI % Rec Limits
Mercury 0.028 0.028 0.0 0-20 0.028 0.25 0.225 98.7 80-120
Associated samples MP41212: FA98839-3, FA98839-4, FA98839-6
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
V
i
N
N
Page 1
SGS97 of 122
FA98839

MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA98839
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41212 Methods: SW846 7471B
Matrix Type: SOLID Units: mg/kg
Prep Date:
FA98781-1A Spikelot MSD QC
letal Original MSD HGFLWSI % Rec RPD Limit
Mercury 0.028 0.27 0.242 99.9 7.7 20
Associated samples MP41212: FA98839-3, FA98839-4, FA98839-6
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
V
i
N
Page 2
GS98 of 122
FA98839

SPIKE BLANK AND LAB CONTROL SAMPLE SUMMARY
Login Number: FA98839
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41212 Methods: SW846 7471B
Matrix Type: SOLID Units: mg/kg
Prep Date:
BSP Spikelot QC
letal Result HGFLWSI o Rec Limits
Mercury 0.25 0.25 100.0 80-120
Associated samples MP41212: FA98839-3, FA98839-4, FA98839-6
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
V
i
W
Page 1
SGS99 of 122
FA98839

SERIAL DILUTION RESULTS SUMMARY
Login Number: FA98839
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41212 Methods: SW846 7471B
Matrix Type: SOLID Units: ug/l
Prep Date:
FA98781-1A QC
letal Original SDL 1:5 oDIF Limits
Mercury 0.330 0.00 100.0(a) 0-10
Associated samples MP41212: FA98839-3, FA98839-4, FA98839-6
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
(a) Percent difference acceptable due to low initial sample concentration (< 50 times IDL).
V
i
Page 1
�GS 100 of 122
a1��V\ FA98839

BLANK RESULTS SUMMARY
Part 2 - Method Blanks
Login Number: FA98839
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41213 Methods: SW846 7471B
Matrix Type: SOLID Units: mg/kg
Prep Date:
MB
letal RL IDL MDL raw final
Mercury 0.042 .0025 .0042-0.0013 <0.042
Associated samples MP41213: FA98839-7
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
V
N
Page 1
SGS101 of 122
FA98839

MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA98839
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41213 Methods: SW846 7471B
Matrix Type: SOLID Units: mg/kg
Prep Date:
FA98856-1 QC FA98856-1 Spikelot QC
Metal Original DUP RPD Limits Original MS HGFLWSI % Rec Limits
Mercury 0.0064 0.0058 9.8 0-20 0.0064 0.30 0.288 101.8 80-120
Associated samples MP41213: FA98839-7
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
V
N
N
Page 1
�GS 102 of 122
a1��V\ FA98839

MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA98839
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41213 Methods: SW846 7471B
Matrix Type: SOLID Units: mg/kg
Prep Date:
FA98856-1 Spikelot MSD QC
letal Original MSD HGFLWSI % Rec RPD Limit
Mercury 0.0064 0.28 0.263 104.1 6.9 20
Associated samples MP41213: FA98839-7
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
V
N
N
Page 2
SGS103 of 122
FA98839

SPIKE BLANK AND LAB CONTROL SAMPLE SUMMARY
Login Number: FA98839
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41213 Methods: SW846 7471B
Matrix Type: SOLID Units: mg/kg
Prep Date:
BSP Spikelot QC
letal Result HGFLWSI o Rec Limits
Mercury 0.25 0.25 100.0 80-120
Associated samples MP41213: FA98839-7
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
V
N
W
Page 1
�GS 104 of 122
a1��V\ FA98839

SERIAL DILUTION RESULTS SUMMARY
Login Number: FA98839
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41213 Methods: SW846 7471B
Matrix Type: SOLID Units: ug/l
Prep Date:
FA98856-1 QC
letal Original SDL 1:5 oDIF Limits
Mercury 0.0734 0.00 100.0(a) 0-10
Associated samples MP41213: FA98839-7
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
(a) Percent difference acceptable due to low initial sample concentration (< 50 times IDL).
V
N
Page 1
�GS 105 of 122
a1��V\ FA98839

BLANK RESULTS SUMMARY
Part 2 - Method Blanks
Login Number: FA98839
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41214 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date:
MB
letal RL IDL MDL raw final
Aluminum
200
14
14
Antimony
6.0
1
1
Arsenic
10
1.3
1.3
-1.3
<10
Barium
200
.5
1
-0.10
<200
Beryllium
4.0
.1
.2
Cadmium
5.0
.1
.2
-0.10
<5.0
Calcium
1000
50
50
Chromium
10
.5
1
-0.10
<10
Cobalt
50
.2
.2
Copper
25
1
1
Iron
300
15
17
Lead
5.0
1
1.1
-0.40
<5.0
Magnesium
5000
35
35
Manganese
15
.25
1
Molybdenum
50
.3
.3
Nickel
40
.4
.4
Potassium
10000
100
200
Selenium
10
2
2.9
-0.40
<10
Silver
10
.5
.7
-1.0
<10
Sodium
10000
250
500
Strontium
10
.25
.5
Thallium
10
1
1.4
Tin
50
.5
1
Titanium
10
.5
1
Vanadium
50
.5
.6
Zinc
20
3
4.4
Associated samples
MP41214:
FA98839-8
Results < IDL
are shown
as
zero for calculation
purposes
(*) Outside of
QC limits
(anr) Analyte
not requested
V
W
Page 1
�GS 106 of 122
a1��V\ FA98839

MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA98839
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41214 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date:
FA98803-1 QC FA98803-1 Spikelot QC
Metal Original DUP RPD Limits Original MS MPFLICP2 % Rec Limits
Aluminum
am
Antimony
Arsenic
0.0 0.0
NC 0-20
0.0
Barium
179 174
2.8 0-20
179
Beryllium
am
Cadmium
4.4 4.3
2.3 0-20
4.4
Calcium
am
2010 2000 100.5 80-120 v
2260 2000 104.1 80-120 WIV
54.3 50 99.8 80-120
Chromium 16.4 15.6 5.0 0-20 16.4 223 200 103.3 80-120
Cobalt
Copper am
Iron am
Lead 141 137 2.9 0-20 141
Magnesium am
Manganese am
Molybdenum
Nickel am
Potassium
Selenium 0.0 0.0 NC 0-20 0.0
Silver 0.0 0.0 NC 0-20 0.0
Sodium am
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc am
Associated samples MP41214: FA98839-8
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
628 500 97.4 80-120
2000 2000 100.0 80-120
44.8 50 89.6 80-120
Page 1
�GS 107 of 122
a1��V\ FA98839

MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA98839
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41214 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date:
FA98803-1 Spikelot MSD QC
letal Original MSD MPFLICP2 % Rec RPD Limit
Aluminum am
Antimony
Arsenic 0.0 2000 2000 100.0 0.5
Barium 179 2250 2000 103.6 0.4
Beryllium am
Cadmium 4.4 54.0 50 99.2 0.6
Calcium am
Chromium 16.4 220 200 101.8 1.4
Cobalt
Copper am
Iron am
Lead 141 624 500 96.6 0.6
Magnesium am
Manganese am
Molybdenum
Nickel am
Potassium
Selenium 0.0 1990 2000 99.5 0.5
Silver 0.0 45.1 50 90.2 0.7
Sodium am
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc am
Associated samples MP41214: FA98839-8
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
20 v
W
20 IV
20
20
20
20
20
Page 2
�GS 108 of 122
a1��V\ FA98839

SPIKE BLANK AND LAB CONTROL SAMPLE SUMMARY
Login Number: FA98839
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41214 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date:
BSP Spikelot QC
letal Result MPFLICP2 % Rec Limits
Aluminum
am
Antimony
Arsenic
2010
2000
100.5
80-120
Barium
2110
2000
105.5
80-120
Beryllium
am
Cadmium
51.1
50
102.2
80-120
Calcium
am
Chromium
208
200
104.0
80-120
Cobalt
Copper
am
Iron
am
Lead
490
500
98.0
80-120
Magnesium
am
Manganese
am
Molybdenum
Nickel
am
Potassium
Selenium
2010
2000
100.5
80-120
Silver
45.0
50
90.0
80-120
Sodium
am
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
am
Associated samples
MP41214:
FA98839-8
Results < IDL
are shown
as zero
for calculation
purposes
(*) Outside of
QC limits
(anr) Analyte
not requested
V
W
W
Page 1
�GS 109 of 122
a1��V\ FA98839

SERIAL DILUTION RESULTS SUMMARY
Login Number: FA98839
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41214 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date:
FA98803-1 QC
letal Original SDL 1:5 %DIF Limits
Aluminum
am
Antimony
Arsenic
0.00
0.00
NC
0-10
Barium
179
177
1.1
0-10
Beryllium
am
Cadmium
4.40
4.00
9.1
0-10
Calcium
am
Chromium
16.4
15.6
4.9
0-10
Cobalt
Copper
am
Iron
am
Lead
141
136
3.5
0-10
Magnesium
am
Manganese
am
Molybdenum
Nickel
am
Potassium
Selenium
0.00
0.00
NC
0-10
Silver
0.00
0.00
NC
0-10
Sodium
am
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
am
Associated samples
MP41214:
FA98839-8
Results < IDL
are shown
as zero
for calculation purposes
(*) Outside of
QC limits
(anr) Analyte
not requested
v
W
Page 1
�GS 110 of 122
a1��V\ FA98839

POST DIGESTATE SPIKE SUMMARY
Login Number: FA98839
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41214 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date:
Sample Final FA98803-1 PS Spike Spike Spike QC
Metal ml ml Raw Corr.** ug/l ml ug/ml ug/l o Rec Limits
Aluminum
Antimony
Arsenic
9.8
10
106.8
0.2
Barium
9.8
10
179
175.42
439.1
0.2
Beryllium
Cadmium
9.8
10
4.4
4.312
58.1
0.2
Calcium
Chromium
9.8
10
16.4
16.072
70
0.2
Cobalt
Copper
Iron
Lead
9.8
10
140.9
138.082
188
0.2
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
9.8
10
102.4
0.2
Silver
9.8
10
50.1
0.2
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated
samples
MP41214:
FA98839-8
Results < IDL
are
shown as
zero for calculation purposes
(*) Outside
of QC
limits
(**) Corr.
sample
result =
Raw * (sample
volume /
final
volume)
(anr) Analyte
not
requested
5 100 106.8 80-120 v
12.5 250 105.5 80-120 54�
2.5 50 107.6 80-120
2.5 50 107.9 80-120
2.5 50 99.8 80-120
5 100 102.4 80-120
2.5 50 100.2 80-120
Page 1
SGS111 of 122
FA98839

BLANK RESULTS SUMMARY
Part 2 - Method Blanks
Login Number: FA98839
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41216 Methods: SW846 6010D
Matrix Type: SOLID Units: mg/kg
Prep Date:
MB
letal RL IDL MDL raw final
Aluminum 10 .7 1.8
Antimony 1.0 .05 .065
Arsenic 0.50 .065 .1 -0.020 <0.50
Barium 10 .025 .05 0.050 <10
Beryllium 0.25 .005 .025
Cadmium 0.20 .005 .025-0.0050 <0.20
Calcium 250 2.5 2.5
Chromium 0.50 .025 .05 0.015 <0.50
Cobalt 2.5 .01 .025
Copper 1.3 .05 .05
Iron 15 .75 .85
Lead 1.0 .05 .05 0.010 <1.0
Magnesium 250 1.8 1.8
Manganese 0.75 .013 .025
Molybdenum 2.5 .015 .025
Nickel 2.0 .02 .025
Potassium 500 5 10
Selenium 1.0 .1 .12 0.010 <1.0
Silver 0.50 .025 .041 -0.035 <0.50
Sodium 500 13 25
Strontium 0.50 .013 .025
Thallium 0.50 .05 .055
Tin 2.5 .025 .045
Titanium 0.50 .025 .025
Vanadium 2.5 .025 .025
Zinc 1.0 .15 .15
Associated samples MP41216: FA98839-3, FA98839-4, FA98839-6, FA98839-7
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
V
Page 1
�GS 112 of 122
a1��V\ FA98839

MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA98839
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41216 Methods: SW846 6010D
Matrix Type: SOLID Units: mg/kg
Prep Date:
FA98823-1 QC FA98823-1 Spikelot QC
Metal Original DUP RPD Limits Original MS MPFLICP2 % Rec Limits
Aluminum
Antimony
am
Arsenic
4.5
4.8
(a)
6.5
0-20
4.5
86.6
(a)
97.1
84.5
80-120
v
Barium
119
119
(a)
4.3
0-20
119
209
(a)
97.1
92.6
80-120
IV
Beryllium
am
Cadmium
0.0
0.0
(a)
NC
0-20
0.0
1.6
(a)
2.43
65.9N(c)
80-120
Calcium
Chromium
32.1
32.7
(a)
1.9
0-20
32.1
42.3
(a)
9.71
105.0
80-120
Cobalt am
Copper am
Iron
Lead 5.1 5.0 (a) 2.0 0-20 5.1 28.0 (a) 24.3 94.3
Magnesium
Manganese
Molybdenum am
Nickel am
Potassium
Selenium 0.76 0.60 (a) 23.5 (b) 0-20 0.76 84.2 (a) 97.1 85.9
Silver 0.0 0.0 (a) NC 0-20 0.0 2.0 (a) 2.43 82.4
Sodium
Strontium
Thallium am
Tin
Titanium
Vanadium am
Zinc am
Associated samples MP41216: FA98839-3, FA98839-4, FA98839-6, FA98839-7
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
(a) Sample dilution required due to difficult matrix.
(b) RPD acceptable due to low duplicate and sample concentrations.
(c) Spike recovery indicates possible matrix interference and/or sample non -homogeneity
80-120
80-120
80-120
Page 1
SGS113 of 122
FA98839

MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA98839
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41216 Methods: SW846 6010D
Matrix Type: SOLID Units: mg/kg
Prep Date:
FA98823-1 Spikelot MSD QC
letal Original MSD MPFLICP2 % Rec RPD Limit
Aluminum
Antimony
am
Arsenic
4.5 87.2
(a)
105
79.1N(b)
0.7
20
Barium
119 206
(a)
105
83.2
1.4
20
Beryllium
am
Cadmium
0.0 1.6
(a)
2.61
61.2N(b)
0.0
20
Calcium
Chromium
32.1 43.7
(a)
10.5
111.0
3.3
20
Cobalt
am
Copper
am
Iron
Lead
5.1 28.2
(a)
26.1
88.4
0.7
20
Magnesium
Manganese
Molybdenum
am
Nickel
am
Potassium
Selenium
0.76 85.3
(a)
105
80.9
1.3
20
Silver
0.0 2.0
(a)
2.61
76.5N(b)
0.0
20
Sodium
Strontium
Thallium
am
Tin
Titanium
Vanadium
am
Zinc
am
Associated
samples MP41216: FA98839-3,
FA98839-4,
FA98839-6, FA98839-7
Results <
IDL are shown as zero
for calculation
purposes
(*) Outside
of QC limits
(N) Matrix
Spike Rec. outside of
QC limits
(anr) Analyte
not requested
(a) Sample
dilution required
due
to difficult
matrix.
(b) Spike
recovery indicates
possible
matrix interference
and/or sample non -homogeneity.
V
N
Page 2
a1��GS 114 of 122
FA98839

SPIKE BLANK AND LAB CONTROL SAMPLE SUMMARY
Login Number: FA98839
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41216 Methods: SW846 6010D
Matrix Type: SOLID Units: mg/kg
Prep Date:
BSP Spikelot QC
letal Result MPFLICP2 % Rec Limits
Aluminum
Antimony
am
Arsenic
91.2 100
91.2
80-120
Barium
95.5 100
95.5
80-120
Beryllium
am
Cadmium
2.4 2.5
96.0
80-120
Calcium
Chromium
10.3 10
103.0
80-120
Cobalt
am
Copper
am
Iron
Lead
22.8 25
91.2
80-120
Magnesium
Manganese
Molybdenum
am
Nickel
am
Potassium
Selenium
92.2 100
92.2
80-120
Silver
2.1 2.5
84.0
80-120
Sodium
Strontium
Thallium
am
Tin
Titanium
Vanadium
am
Zinc
am
Associated samples
MP41216:
FA98839-3,
FA98839-4, FA98839-6, FA98839-7
Results < IDL
are shown as
zero for calculation purposes
(*) Outside of
QC limits
(anr) Analyte
not requested
V
W
Page 1
SGS115 of 122
FA98839

SERIAL DILUTION RESULTS SUMMARY
Login Number: FA98839
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41216 Methods: SW846 6010D
Matrix Type: SOLID Units: ug/l
Prep Date:
FA98823-1 QC
letal Original SDL 5:25 %DIF Limits
Aluminum
Antimony am
Arsenic 86.3 102 18.4 (a) 0-10
Barium 2310 2430 5.5 0-10
Beryllium am
Cadmium 0.00 0.00 NC 0-10
Calcium
Chromium 619 658 6.2 0-10
Cobalt am
Copper am
Iron
Lead 99.0 76.4 22.8 (a) 0-10
Magnesium
Manganese
Molybdenum am
Nickel am
Potassium
Selenium 14.7 0.00 100.0(a) 0-10
Silver 0.00 0.00 NC 0-10
Sodium
Strontium
Thallium am
Tin
Titanium
Vanadium am
Zinc am
Associated samples MP41216: FA98839-3, FA98839-4, FA98839-6, FA98839-7
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
(a) Percent difference acceptable due to low initial sample concentration (< 50 times IDL).
V
Page 1
�GS 116 of 122
a1��V\ FA98839

POST DIGESTATE SPIKE SUMMARY
Login Number: FA98839
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41216 Methods: SW846 6010D
Matrix Type: SOLID Units: ug/l
Prep Date:
Sample Final FA98823-1 PS Spike Spike Spike QC
Metal ml ml Raw Corr.** ug/l ml ug/ml ug/l % Rec Limits
Aluminum
Antimony
Arsenic
9.8 10
86.3 84.574
177
0.2
5
100
92.4
80-120
Barium
9.8 10
2305 2258.9
2554
0.2
12.5
250
118.0
80-120
Beryllium
Cadmium
9.8 10
34.7
0.2
2.5
50
69.4*(a)
80-120
Calcium
Chromium
9.8 10
619.4 607.012
680.4
0.2
2.5
50
146.8*(a
80-120
Cobalt
Copper
Iron
Lead
9.8 10
99 97.02
142.6
0.2
2.5
50
91.2
80-120
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
9.8 10
14.7 14.406
97.9
0.2
5
100
83.5
80-120
Silver
9.8 10
43.7
0.2
2.5
50
87.4
80-120
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated
samples MP41216:
FA98839-3, FA98839-4,
FA98839-6,
FA98839-7
Results < IDL
are shown as zero
for calculation purposes
(*) Outside
of QC limits
(**) Corr.
sample result =
Raw * (sample volume
/ final
volume)
(anr) Analyte
not requested
(a) Spike recovery
indicates
matrix interference
and/or
outside
control limits
due
to high level
in
sample
relative to spike
amount.
V
N
Page 1
�GS 117 of 122
a1��V\ FA98839

BLANK RESULTS SUMMARY
Part 2 - Method Blanks
Login Number: FA98839
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41233 Methods: SW846 7470A
Matrix Type: AQUEOUS Units: ug/l
Prep Date:
MB
letal RL IDL MDL raw final
Mercury 0.50 .03 .03 0.041 <0.50
Associated samples MP41233: FA98839-8
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
V
fJl
Page 1
a1��GS 118 of 122
FA98839

MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA98839
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41233 Methods: SW846 7470A
Matrix Type: AQUEOUS Units: ug/l
Prep Date:
FA98941-1 QC FA98941-1 Spikelot QC
Metal Original DUP RPD Limits Original MS HGFLWSI % Rec Limits
Mercury 0.048 0.044 8.7 0-20 0.048 2.7 3 88.4 80-120
Associated samples MP41233: FA98839-8
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
v
CJ1
N
Page 1
�GS 119 of 122
a1��V\ FA98839

MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA98839
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41233 Methods: SW846 7470A
Matrix Type: AQUEOUS Units: ug/l
Prep Date:
FA98941-1 Spikelot MSD QC
letal Original MSD HGFLWSI % Rec RPD Limit
Mercury 0.048 2.7 3 88.4 0.0 20
Associated samples MP41233: FA98839-8
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
v
CJ1
N
Page 2
�GS 120 of 122
a1��V\ FA98839

SPIKE BLANK AND LAB CONTROL SAMPLE SUMMARY
Login Number: FA98839
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41233 Methods: SW846 7470A
Matrix Type: AQUEOUS Units: ug/l
Prep Date:
BSP Spikelot QC
letal Result HGFLWSI o Rec Limits
Mercury 2.7 3 90.0 80-120
Associated samples MP41233: FA98839-8
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
V
W
Page 1
�GS 121 of 122
a1��V\ FA98839

SERIAL DILUTION RESULTS SUMMARY
Login Number: FA98839
Account: GSYNNCW - Geosyntec Consultants
Project: PPD; Harnett St, Wilmington, NC
QC Batch ID: MP41233 Methods: SW846 7470A
Matrix Type: AQUEOUS Units: ug/l
Prep Date:
FA98941-1 QC
letal Original SDL 1:5 oDIF Limits
Mercury 0.0484 0.00 100.0(a) 0-10
Associated samples MP41233: FA98839-8
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
(a) Percent difference acceptable due to low initial sample concentration (< 50 times IDL).
v
CJ1
Page 1
SGS122 of 122
FA98839

APPENDIX C

Risk for Individual Pathways
Version Date: July 2022
Basis: May 2022 EPA RSL Table
Site ID: Almont Shipping II Adjacent Property
Exposure Unit ID: Shallow Samples - Tier 1
DIRECT CONTACT SOIL AND WATER CALCULATORS
Receptor
Path�� ay
Carcinogenic
Risk
Hazard Index
Risk exceeded?
Resident
Soil
1.6E-05
3.8E-01
NO
Groundwater Use*
NC
NC
NC
Non -Residential Worker
Soil
2.5E-06
2.8E-02
NO
Groundwater Use*
NC
NC
NC
Construction Worker
Soil
5.9E-07
1.7E-01
NO
Recreator/Trespasser
Soil
8.7E-06
2.1E-01
NO
Surface Water*
NC
NC
NC
VAPOR INTRUSION CALCULATORS RF
Receptor
Pathway
Carcinogenic
Risk
Hazard Index
Risk exceeded?
Resident
Groundwater to Indoor Air
0.0E+00
0.0E+00
NO
Soil Gas to Indoor Air
0.0E+00
0.0E+00
NO
Indoor Air
0.0E+00
0.0E+00
NO
Non -Residential Worker
Groundwater to Indoor Air
0.0E+00
0.0E+00
NO
Soil Gas to Indoor Air
0.0E+00
0.0E+00
NO
Indoor Air
0.0E+00
0.0E+00
NO
CONTAMINANT MIGRATION CALCULATORS
Pathway
Source
Target Receptor Concentrations Exceeded?
Groundwater
Source Soil
Exceedence of 2L at Receptor?
NM
Source Groundwater
Exceedence of 2L at Receptor?
NM
Surface Water
Source Soil
Exceedence of 2B at Receptor?
NM
Source Groundwater
Exceedence of 2B at Receptor?
NM
Notes:
1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead
concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations.
2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the
NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk -based
closure.
3. NM = Not Modeled
4. NC = Pathway not calculated
North Carolina DEQ Risk Calculator

Risk for Individual Pathways
Version Date: July 2022
Basis: May 2022 EPA RSL Table
Site ID: Almont Shipping II Adjacent Property
Exposure Unit ID: Deep and Background Samples - Tier 1
DIRECT CONTACT SOIL AND WATER CALCULATORS
Receptor
PatPathwayCarcinogenicRisk
Hazard Index
Risk exceeded?
Resident
Soil
1.0E-04
8.4E-01
YES
Groundwater Use*
NC
NC
NC
Non -Residential Worker
Soil
8.6E-06
1.1E-01
NO
Groundwater Use*
NC
NC
NC
Construction Worker
Soil
1.6E-06
3.2E-01
NO
Recreator/Trespasser
Soil
5.4E-05
3.0E-01
NO
Surface Water*
NC
NC
NC
VAPOR INTRUSION CALCULATORS RF
Receptor
Pathway
Carcinogenic
Risk
Hazard Index
Risk exceeded?
Resident
Groundwater to Indoor Air
0.0E+00
0.0E+00
NO
Soil Gas to Indoor Air
0.0E+00
0.0E+00
NO
Indoor Air
0.0E+00
0.0E+00
NO
Non -Residential Worker
Groundwater to Indoor Air
0.0E+00
0.0E+00
NO
Soil Gas to Indoor Air
0.0E+00
0.0E+00
NO
Indoor Air
0.0E+00
0.0E+00
NO
CONTAMINANT MIGRATION CALCULATORS
Pathway
Source
Target Receptor Concentrations Exceeded?
Groundwater
Source Soil
Exceedence of 2L at Receptor?
NM
Source Groundwater
Exceedence of 2L at Receptor?
NM
Surface Water
Source Soil
Exceedence of 2B at Receptor?
NM
Source Groundwater
Exceedence of 2B at Receptor?
NM
Notes:
1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead
concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations.
2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the
NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk -based
closure.
3. NM = Not Modeled
4. NC = Pathway not calculated
North Carolina DEQ Risk Calculator

Risk for Individual Pathways
Version Date: July 2022
Basis: May 2022 EPA RSL Table
Site ID: Almont Shipping II - Adjacent Property
Exposure Unit ID: Combined Samples - Tier 1
DIRECT CONTACT SOIL AND WATER CALCULATORS
Receptor
PatPathwayCarcinogenicRisk
Hazard Index
Risk exceeded?
Resident
Soil
1.1E-04
8.6E-01
YES
Groundwater Use*
NC
NC
NC
Non -Residential Worker
Soil
8.8E-06
1.2E-01
NO
Groundwater Use*
NC
NC
NC
Construction Worker
Soil
1.7E-06
3.4E-01
NO
Recreator/Trespasser
Soil
5.4E-05
3.1E-01
NO
Surface Water*
NC
NC
NC
VAPOR INTRUSION CALCULATORS RF
Receptor
Pathway
Carcinogenic
Risk
Hazard Index
Risk exceeded?
Resident
Groundwater to Indoor Air
NC
NC
NC
Soil Gas to Indoor Air
NC
NC
NC
Indoor Air
NC
NC
NC
Non -Residential Worker
Groundwater to Indoor Air
NC
NC
NC
Soil Gas to Indoor Air
NC
NC
NC
Indoor Air
NC
NC
NC
CONTAMINANT MIGRATION CALCULATORS
OF
Pathway
Source
Target Receptor Concentrations Exceeded?
Groundwater
Source Soil
Exceedence of 2L at Receptor?
NM
Source Groundwater
Exceedence of 2L at Receptor?
NC
Surface Water
Source Soil
Exceedence of 2B at Receptor?
NM
Source Groundwater
Exceedence of 2B at Receptor?
NC
Notes:
1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead
concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations.
2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the
NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk -based
closure.
3. NM = Not Modeled
4. NC = Pathway not calculated
North Carolina DEQ Risk Calculator

Risk for Individual Pathways
Version Date: July 2022
Basis: May 2022 EPA RSL Table
Site ID: Almont Shipping Adjacent Property
Exposure Unit ID: Shallow Samples - Tier 2
DIRECT CONTACT SOIL AND WATER CALCULATORS
Receptor
Path�� ay
Carcinogenic
Risk
Hazard Index
Risk exceeded?
Resident
Soil
1.0E-05
1.4E-01
NO
Groundwater Use*
NC
NC
NC
Non -Residential Worker
Soil
1.7E-06
1.1E-02
NO
Groundwater Use*
NC
NC
NC
Construction Worker
Soil
NC
NC
NC
Recreator/Trespasser
Soil
NC
NC
NC
Surface Water*
NC
NC
NC
VAPOR INTRUSION CALCULATORS
Receptor
Pathway
Carcinogenic
Risk
Hazard Index
Risk exceeded?
Resident
Groundwater to Indoor Air
0.0E+00
0.0E+00
NO
Soil Gas to Indoor Air
0.0E+00
0.0E+00
NO
Indoor Air
0.0E+00
0.0E+00
NO
Non -Residential Worker
Groundwater to Indoor Air
0.0E+00
0.0E+00
NO
Soil Gas to Indoor Air
0.0E+00
0.0E+00
NO
Indoor Air
0.0E+00
0.0E+00
NO
CONTAMINANT MIGRATION CALCULATORS
Pathway
Source
Target Receptor Concentrations Exceeded?
Groundwater
Source Soil
Exceedence of 2L at Receptor?
NM
Source Groundwater
Exceedence of 2L at Receptor?
NM
Surface Water
Source Soil
Exceedence of 2B at Receptor?
NM
Source Groundwater
Exceedence of 2B at Receptor?
NM
Notes:
1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead
concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations.
2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the
NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk -based
closure.
3. NM = Not Modeled
4. NC = Pathway not calculated
North Carolina DEQ Risk Calculator

Risk for Individual Pathways
Version Date: July 2022
Basis: May 2022 EPA RSL Table
Site ID: Almont Shipping Adjacent Property
Exposure Unit ID: Deep and Background Samples - Tier 2
DIRECT CONTACT SOIL AND WATER CALCULATORS
Receptor
Path�� ay
Carcinogenic
Risk
Hazard Index
Risk exceeded?
Resident
Soil
3.1E-05
3.1E-01
NO
Groundwater Use*
NC
NC
NC
Non -Residential Worker
Soil
2.8E-06
2.9E-02
NO
Groundwater Use*
NC
NC
NC
Construction Worker
Soil
NC
NC
NC
Recreator/Trespasser
Soil
NC
NC
NC
Surface Water*
NC
NC
NC
VAPOR INTRUSION CALCULATORS
Receptor
Pathway
Carcinogenic
Risk
Hazard Index
Risk exceeded?
Resident
Groundwater to Indoor Air
0.0E+00
0.0E+00
NO
Soil Gas to Indoor Air
0.0E+00
0.0E+00
NO
Indoor Air
0.0E+00
0.0E+00
NO
Non -Residential Worker
Groundwater to Indoor Air
0.0E+00
0.0E+00
NO
Soil Gas to Indoor Air
0.0E+00
0.0E+00
NO
Indoor Air
0.0E+00
0.0E+00
NO
CONTAMINANT MIGRATION CALCULATORS
Pathway
Source
Target Receptor Concentrations Exceeded?
Groundwater
Source Soil
Exceedence of 2L at Receptor?
NM
Source Groundwater
Exceedence of 2L at Receptor?
NM
Surface Water
Source Soil
Exceedence of 2B at Receptor?
NM
Source Groundwater
Exceedence of 2B at Receptor?
NM
Notes:
1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead
concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations.
2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the
NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk -based
closure.
3. NM = Not Modeled
4. NC = Pathway not calculated
North Carolina DEQ Risk Calculator

Risk for Individual Pathways
Version Date: July 2022
Basis: May 2022 EPA RSL Table
Site ID: Almont Shipping Adjacent Property
Exposure Unit ID: Combined Samples - Tier 2
DIRECT CONTACT SOIL AND WATER CALCULATORS
Receptor
Path�� ay
Carcinogenic
Risk
Hazard Index
Risk exceeded?
Resident
Soil
3.2E-05
3.4E-01
NO
Groundwater Use*
NC
NC
NC
Non -Residential Worker
Soil
3.0E-06
3.0E-02
NO
Groundwater Use*
NC
NC
NC
Construction Worker
Soil
NC
NC
NC
Recreator/Trespasser
Soil
NC
NC
NC
Surface Water*
NC
NC
NC
VAPOR INTRUSION CALCULATORS
Receptor
Pathway
Carcinogenic
Risk
Hazard Index
Risk exceeded?
Resident
Groundwater to Indoor Air
0.0E+00
0.0E+00
NO
Soil Gas to Indoor Air
0.0E+00
0.0E+00
NO
Indoor Air
0.0E+00
0.0E+00
NO
Non -Residential Worker
Groundwater to Indoor Air
0.0E+00
0.0E+00
NO
Soil Gas to Indoor Air
0.0E+00
0.0E+00
NO
Indoor Air
0.0E+00
0.0E+00
NO
CONTAMINANT MIGRATION CALCULATORS
Pathway
Source
Target Receptor Concentrations Exceeded?
Groundwater
Source Soil
Exceedence of 2L at Receptor?
NM
Source Groundwater
Exceedence of 2L at Receptor?
NM
Surface Water
Source Soil
Exceedence of 2B at Receptor?
NM
Source Groundwater
Exceedence of 2B at Receptor?
NM
Notes:
1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead
concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations.
2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the
NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk -based
closure.
3. NM = Not Modeled
4. NC = Pathway not calculated
North Carolina DEQ Risk Calculator