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HomeMy WebLinkAbout23079_Northern Telecom_Stockpile Assessment Rpt_20201027Mid Atlantic Engineering & Environmental Solutions October 27, 2020 Ms. Holly Samaha, PE NC Division of Waste Management Brownfields Program 1646 Mail Service Center Raleigh, NC 27699-1646 Subject: STOCKPILE ASSESSMENT REPORT NORTHERN TELECOM 4001 AND 4151 EAST NC HIGHWAY 54 DURHAM, DURHAM COUNTY, NORTH CAROLINA BROWNFIELDS PROJECT NO.: 23079-19-032 MID -ATLANTIC JOB NO. OOOR3358.01 TASK 70010 MID -ATLANTIC PE LICENSE: F-0967 Dear Ms. Samaha: 409 Rogers View Court Raleigh. NC 27610 office 919,250,9918 facsimile 919,250.9950 MAAONLINE.COM Mid -Atlantic Associates, Inc. (Mid -Atlantic) performed a Stockpile Assessment at the Northern Telecom redevelopment site (subject site) located in Durham, North Carolina (Drawing 1). The subject site is comprised of three parcels totaling 94.89 acres located within the Research Triangle Park (RTP) area of Durham, North Carolina (Drawing 2). The site has been used for industrial purposes since at least 1979. The subject site is developed with unoccupied commercial office/warehouse buildings, parking lots, storage structures, two fire suppression water tanks and associated pump buildings, guard shack, tennis and volleyball courts, and cemetery. The redevelopment consists of primarily fill areas, with some cut areas located around the existing structures where utilities will be installed. The soil in these areas is being excavated and reused on -site if geotechnically usable. Excavated material that in not geotechnically usable is planned to be wasted on -site in a grassy area located on the western portion of the property (Drawing 2). After the stockpiled material is spread in the grassy area, the area will be seeded and maintained as a grass landscaped area. The stockpile currently contains approximately 600 cubic yards of cut material. This report details the October 2020 stockpile and grass area sampling activities conducted on the subject site. The objective of this assessment was to determine if the stockpiled cut material was suitable for reuse in the grassy area where the soil is planned to be spread. The assessment was conducted in accordance with the Environmental Management Plan dated September 17, 2020. — EXPERIENCED CUSTOMER FOCUSED INNOVATIVE — Stockpile Assessment Report Northern Telecom Durham, North Carolina October 27, 2020 Page 2 The opinions included herein are based on our experience and the information obtained during the study. This report is based on limited observations made on the dates noted using the procedures described herein. If additional information becomes available, we request the opportunity to review the information, reassess the potential environmental concerns and modify our conclusions and recommendations, if appropriate. SUMMARY OF FIELD ACTIVITIES On October 6, 2020, a composite soil sample was collected from stockpiled cut material located on - site and four grab samples were collected from the grassy area where the cut soils are planned to be spread. The estimated volume of the stockpiled soil is approximately 600 cubic yards. The composite sample (SP-1) was collected from the stockpile and consisted of five aliquots from varying depths (Drawing 3). The sample was analyzed for semi -volatile organic compounds (SVOCs) and RCRA Metals (plus hexavalent chromium). One grab sample was also collected along with each of the composite samples and analyzed for volatile organic compounds (VOCs). Mid -Atlantic also collected four grab soil samples from just below the surface at approximately 0.5 feet below land surface (bls) from the grass area where the stockpiled soil is planned to be spread (Drawing 4). The four grab samples (PP-GA-1 through PP-GA-4) were analyzed for VOCs, SVOCs, RCRA Metals (plus hexavalent chromium). Soil cuttings from each stockpile soil boring were screened using a photoionization detector (PID) to evaluate if VOCs were detected in soil during sample collection activities. A portion of each soil sample was removed from the sampling device and placed in a pre -labeled, plastic "Ziploc" bag. After several minutes, the gas contained in the "headspace" or void area within the bag was screened with a PID. The PID was also used for air monitoring in accordance with provisions in the site health and safety plan (HASP). The soil samples collected for laboratory analysis were removed from the sampling device and placed directly into laboratory supplied sample jars. Samples were collected from a depth of 1 to 2 feet into the stockpile and from 0.5 to 1 foot bls in the grass area. Samples could not be collected further into the stockpile due to auger refusal on rocks and debris. VOCs were not detected in any of the soils screened with the PID above 1 part per million (ppm). Soil samples were submitted for laboratory analysis of VOCs by EPA Method 8260, SVOCs by EPA Method 8270, eight RCRA metals by EPA Methods 7471A and 6010B, and hexavalent chromium by EPA Method 7199. One duplicate soil sample (DUP-SP) was collected from composite soil sample SP-1. Soil samples were shipped to Pace Analytical Laboratory (Pace) of Huntersville, North Carolina for laboratory analysis as shown on the chain of custody record provided in Appendix A. SUMMARY OF LABORATORY ANALYTICAL RESULTS Soil samples were compared to the Residential Preliminary Soil Remediation Goals (PSRGs), the Protection of Groundwater PSRGs, and the Industrial PSRGs. As summarized in Table 1, total chromium was detected in each of the stockpile and grass area samples, and the duplicate sample at concentrations exceeding the Residential, Industrial/Commercial, and Protection of Groundwater ft Mid Atlantic Stockpile Assessment Report Northern Telecom Durham, North Carolina October 27, 2020 Page 3 PSRGs for total chromium. The soil samples with the highest total chromium concentrations in each area [SP-01 at 8.4 milligrams per kilogram (mg/kg) and PP-GA-1 at 33.9 mg/kg] were speciated for hexavalent chromium and the concentrations were below the laboratory reporting limits. The speciation results indicate the chromium concentrations identified in the soil samples consist primarily of trivalent chromium. Neither the speciated hexavalent chromium concentrations nor the remaining trivalent chromium concentrations identified in the samples exceed the PSRGs. Arsenic was detected in samples PP-GA-1, PP-GA-3, and PP-GA-4 at concentrations exceeding the Residential and Industrial/Commercial PSRGs, but below the Protection of Groundwater PSRG. Arsenic was detected in samples PP-GA-2, SP-01 and the duplicate sample DUP-SP at concentrations exceeding the Residential PSRG but below the Protection of Groundwater and Industrial/Commercial PSRGs. Arsenic is a metal that is found naturally occurring in North Carolina soils. According to the North Carolina Department of Agriculture and Consumer Services (NCDA), an average concentration of 4.5 mg/Kg of arsenic was detected in laboratory testing of 3,286 soil samples collected across North Carolina between 2005 and 2007 (NCDA, 2008). Furthermore, the EPA notes that arsenic concentrations typically range from four to nine mg/Kg in most soils (EPA, 2003). According to the laboratory analysis, the arsenic concentrations detected in the assessment samples collected from the subject site fall within levels believed to be found naturally in North Carolina soils. Barium, cadmium, lead, and mercury were detected in some or all of the stockpile and grass area samples, and the duplicate sample at concentrations above laboratory method detection limits but below the PSRGs, and at similar concentrations to those detected in previous soil samples collected at the subject site. As summarized in Table 1, VOCs and SVOCs were not detected in any of the samples above to the laboratory detection limits. Mid -Atlantic completed risk calculations for the stockpiled soil using the maximum concentrations identified in the primary and duplicate samples. The risk calculations were completed to evaluate the residential and non-residential worker scenarios. The Brownfields Program allows a maximum cancer risk sum for all carcinogens of 1.0E-04 and a maximum cumulative hazard index (HI) of 1.0 for all non - carcinogens for direct contact with soil. The HI is the sum of the hazard quotient (HQs) calculated for each compound detected above the reporting limit. Cancer risk sums and cumulative non -cancer hazard indexes were determined using the maximum concentrations identified in the soil samples (Appendix B). The residential cancer risk sum was 7.1 E- 06, below the target cancer risk sum of 1.0E-04. The residential cumulative non -cancer hazard index was 1.6E-01, below the target cancer risk sum of 1.0. The non-residential worker cancer risk sum was 1.6E-06, below the target cancer risk sum of 1.0E-04. The non-residential worker cumulative non - cancer hazard index was 1.2E-02, below the target index of 1.0. The objective of this assessment was to determine if the on -site stockpiled cut material is suitable to be spread in the grass area located in the western portion of the subject site. Based on review of the data collected during this assessment Mid -Atlantic concludes: • With the exception of arsenic and total chromium detected in all of the soil samples, metals concentrations in the stockpiled cut material and the grass area do not exceed the PSRGs. 0 Mid Atlantic Stockpile Assessment Report Northern Telecom Durham, North Carolina October 27, 2020 Page 4 The arsenic concentrations detected in the soil samples and the duplicate fall within levels believed to be found naturally in North Carolina soils. • Soil samples SP-01 and PP-GA-1 were speciated for hexavalent chromium and the results are below the laboratory reporting limits; • VOCs and SVOCs were not identified in the samples at concentrations above the laboratory detection limits; and • The calculated cancer risk sums and cumulative non -cancer hazard index calculated using the maximum concentrations identified in the soil samples did not exceed the target cancer risk sum of 1.0E-04 or the target cumulative non -cancer hazard index of 1.0 when calculated for both the residential and non-residential worker scenarios . Based on the totality of the data collected during this investigation, it appears that the stockpiled cut material is suitable for spreading in the noted grass area. As such, Mid -Atlantic recommends that the stockpiled soil located on -site be approved for spreading in the grass area located on the western portion of the subject site. We appreciate the opportunity to submit this report. Should you have any questions please do not hesitate to reach me at 919-250-9918. Sincerely, MID -ATLANTIC ASSOCIATES, INC. Katie A. Lippard Senior Project Manager Darin M. McClure, PE Principal Engineer NCPE License No: 18967 Attachments: Table 1 — Summary of Chemical Constituents Detected in Soil Drawing 1 — Topographic Site Map Drawing 2 — Site Map Drawing 3 — Stockpile Sample Locations Drawing 4 — Grass Area Sample Locations Appendix A — Laboratory Analytical Report and Chain of Custody Appendix B — Risk Calculation Worksheets cc: Tyler Strutzenberg, Trinity Capital Advisors Jeff Sheehan, Trinity Capital Advisors T Mid Atlantic TABLE 0 Mid Atlantic TABLE 1 SUMMARY OF CHEMICAL CONSTITUENTS DETECTED IN SOIL STOCKPILE AND GRASS AREA NORTHERN TELECOM - PARK POINT DURHAM, NORTH CAROLINA BROWNFIELDS PROJECT NUMBER 23079-19-032 MID -ATLANTIC JOB NO.: R3358.01 STOCKPILE GRASS AREA CHEMICAL APPLICABLE STANDARD SAMPLE ID CONSTITUENT SP-01 DUP-SP PP-GA-1 PP-GA-2 PP-GA-3 PP-GA-4 DEPTH 1 to 2 (COMPOSITE SAMPLE) 1 to 2 (COMPOSITE SAMPLE) 0.5 0.5 0.5 0.5 (ft BLS) DATE 10/6/20 10/6/20 10/6/20 10/6/20 10/6/20 10/6/20 PROTECTION OF RCRA METALS (METHODS 6010D/7471B/7196A) GROUNDWATER PSRG PSRG RESIDENTIAL ALkg) INDUSTRIAL PSRG (mg/kg) (mg/kg) Arsenic 2.5 1.9 4.8 2.8 3.8 4.1 5.8 0.68 3 Barium 73.3 61.6 166 123 280 122 580 3100 47000 Cadmium 0.096 0.067 J 0.13 0.077 J 0.14 0.092 J 3.0 14 200 Chromium (Total) 8.4 6.8 33.9 11.5 23.8 18.1 3.8 0.31 6.5 Lead 11.9 10.1 14.9 15.5 14.0 11.9 250 400 800 Selenium 0.49 J 0.61 J 0.83 J 0.55 J 0.69 J 0.76 J 2.1 78 1200 Mercury 0.0044 J 0.0044 0.0043 J 0.0041 J 0.0088 0.0072 1.0 2.3 9.7 HEXAVALENT CHROMIUM (METHOD 7199) Hexavalent Chromium <0.291 -- I <0.311 -- -- -- 3.8 0.31 6.5 Notes: All concentrations reported in mg/Kg mg/Kg = Milligrams per kilogram PSRG = Preliminary Soil Remediation Goals (July 2020) J = Estimated concentrations above laboratory method detection limits -- = Not analyzed Stockpile sample SP-01 and duplicate samples DUP-SP were composite samples collected from 5 aliquot sample locations from depths ranging from 1 to 2 feet into the stockpile and analyzed for semi -volatile organic compounds and RCRA metals. One grab sample representative of the composite sample location was collected from the aliquot sample exhibiting the highest volatile organic concentrations during field screening and analyzed for volatile organic compounds. DRAWINGS 0 Mid Atlantic a REFERENCES: 1. SOUTH EAST DURHAM, NC DIGITAL RASTER GRAPHICS, USGS. SCANNED FROM 1:24,000-SCALE DURHAM, NC TOPOGRAPHIC MAPS, PUBLISHED 2013, USGS. 2. INSET MAP DIGITAL DATA FROM 2002 NATIONAL TRANSPORTATION ATLAS, BUREAU OF TRANSPORTATION STATISTICS, WASHINGTON, D.C. 3. PROPERTY BOUNDARY DATA FROM WAKE COUNTY GIS. TOPOGRAPHIC SITE MAP NORTHERN TELECOM 4001 AND 4151 NC HWY 54 DURHAM, NORTH CAROLINA SCALE: 1:24,000 Feet 2,000 4,000 DRAWN I DATE: BY: GCH NOVEMBER 2019 . r. ,r x � � o F M WIWI 27 K _ fin' AMDW \ V raSS Hrea=�?R Aree�E .. M 2�7 _ Area C ding C/E i N / r '' r Ar^ea1F ; - k_ Y t Area D r , i � y cog /F . Buildin D Stockpile Legend - . � 1 inch : 300 feet - - y J SUBJECT SITE 7 0 wF 500 1,000 1,500 2,000 PARCEL BOUNDARIES Feet� DRAWN BY: KRC DATE: OCTOBER 2020 ''• SITE MAP DRAFT CHECK M i d Atl anti c PARK POINT JOB NO.: R3358.01 4001 AND 4151 EAST HIGHWAY 54 ENGINEER CHECK GIS NO.: 3G-R3358.01-2 Site Engineering & Environmental Solutions BY: — DURHAM, NORTH CAROLINA APPROVED BY: DRAWING NO.: 2 REFERENCE: PARCEL BOUNDARIES FROM NC ONEMAP. PROPOSED DEVELOPMENT PLAN FROM TRINITY CAPITAL ADVISORS. MID-ATLANTI FIELD NOTES �.. 1 SP 3. SP-1 r SP-5 S P-4Ilk %-MIL r OIW4- � T� A. T} 0 100 200 3vv Z+vv Feet STOCKPILE SAMPLE LOCATIONS Mid Atlantic NORTHERN TELECOM 4001 AND 4151 EAST HIGHWAY 54 Engineering & Environmental Solutions DURHAM, NORTH CAROLINA REFERENCE: MID -ATLANTIC FIELD NOTES. NC ONEMAP Legend • Sample Location Approximate Extent of Stockpile L - - - DRAWN BY: KRC DATE: SEPTEMBER 2020 DRAFT CHECK BY: JOB NO.: R3358.01 ENGINEER CHECK GIS NO.: 3G-R3358.01-4 SS Sam BY: — — P APPROVED BY: I DRAWING NO.: 3 I a 14 LABORATORY ANALYTICAL REPORTs AND CHAIN OF CUSTODY RECORDs IL Mid Atlantic leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 October 27, 2020 Katie Lippard Mid -Atlantic Associates 409 Rogers View Ct. Raleigh, NC 27610 RE: Project: Park Pointe Stockpile Pace Project No.: 92499338 Dear Katie Lippard: Enclosed are the analytical results for sample(s) received by the laboratory on October 06, 2020. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace National - Mt. Juliet • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Tyriek Hooks tyriek.hooks@pacelabs.com (704)875-9092 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 37 lacieAnalyfica(' www,pacelabs.com Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Park Pointe Stockpile Pace Project No.: 92499338 Pace Analytical Services National 12065 Lebanon Road, Mt. Juliet, TN 37122 Alabama Certification #: 40660 Alaska Certification 17-026 Arizona Certification #: AZ0612 Arkansas Certification #: 88-0469 California Certification #: 2932 Canada Certification #: 1461.01 Colorado Certification #: TN00003 Connecticut Certification #: PH-0197 DOD Certification: #1461.01 EPA# TN00003 Florida Certification #: E87487 Georgia DW Certification #: 923 Georgia Certification: NELAP Idaho Certification #: TN00003 Illinois Certification #: 200008 Indiana Certification #: C-TN-01 Iowa Certification #: 364 Kansas Certification #: E-10277 Kentucky UST Certification #: 16 Kentucky Certification #: 90010 Louisiana Certification #: A130792 Louisiana DW Certification #: LA180010 Maine Certification #: TN0002 Maryland Certification #: 324 Massachusetts Certification #: M-TNO03 Michigan Certification #: 9958 Minnesota Certification #: 047-999-395 Mississippi Certification #: TN00003 Missouri Certification #: 340 Montana Certification M CERT0086 Nebraska Certification #: NE-OS-15-05 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS Nevada Certification #: TN-03-2002-34 New Hampshire Certification #: 2975 New Jersey Certification #: TNO02 New Mexico DW Certification New York Certification #: 11742 North Carolina Aquatic Toxicity Certification #: 41 North Carolina Drinking Water Certification #: 21704 North Carolina Environmental Certificate #: 375 North Dakota Certification #: R-140 Ohio VAP Certification #: CL0069 Oklahoma Certification #: 9915 Oregon Certification #: TN200002 Pennsylvania Certification #: 68-02979 Rhode Island Certification #: LA000356 South Carolina Certification #: 84004 South Dakota Certification Tennessee DW/Chem/Micro Certification #: 2006 Texas Certification #: T 104704245-17-14 Texas Mold Certification #: LAB0152 USDA Soil Permit #: P330-15-00234 Utah Certification #: TN00003 Vermont Dept. of Health: ID# VT-2006 Virginia Certification #: VT2006 Virginia Certification #: 460132 Washington Certification #: C847 West Virginia Certification #: 233 Wisconsin Certification #: 998093910 Wyoming UST Certification #: via A21-A 2926.01 A21-A-ISO 17025 Certification #: 1461.01 A21-A-ISO 17025 Certification #: 1461.02 AIHA-LAP/LLC EMLAP Certification #:100789 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 37 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Park Pointe Stockpile Pace Project No.: 92499338 Lab ID Sample ID Matrix Date Collected Date Received 92499338001 92499338002 SP-01 DUP-SP Solid Solid 10/06/2013:15 10/06/2013:20 10/06/2016:45 10/06/2016:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 37 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Park Pointe Stockpile Pace Project No.: 92499338 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92499338001 SP-01 EPA 601 OD IDS, RDT 7 PASI-A EPA 7471 B SOO 1 PASI-A EPA 8270E BPJ 75 PASI-C EPA 8260D CL 70 PASI-C ASTM D2974-87 KDF 1 PASI-C SM 2540G KBC 1 PAN EPA 7199 GB 1 PAN 92499338002 DLIP-SP EPA 601 OD IDS, RDT 7 PASI-A EPA 7471 B SOO 1 PASI-A EPA 8270E BPJ 75 PASI-C EPA 8260D CL 70 PASI-C ASTM D2974-87 KDF 1 PASI-C PAN = Pace National - Mt. Juliet PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 37 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Park Pointe Stockpile Pace Project No.: 92499338 Sample: SP-01 Lab ID: 92499338001 Collected: 10/06/20 13:15 Received: 10/06/20 16:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3050B Pace Analytical Services -Asheville Arsenic 2.5 mg/kg 0.90 0.45 1 10/08/20 15:31 10/11/20 20:35 7440-38-2 BC Barium 73.3 mg/kg 0.45 0.23 1 10/08/20 15:31 10/11/20 02:10 7440-39-3 Cadmium 0.096 mg/kg 0.090 0.045 1 10/08/20 15:31 10/11/20 20:35 7440-43-9 Chromium 8.4 mg/kg 0.45 0.23 1 10/08/20 15:31 10/11/20 02:10 7440-47-3 Lead 11.9 mg/kg 0.45 0.23 1 10/08/20 15:31 10/11/20 20:35 7439-92-1 Selenium 0.49J mg/kg 0.90 0.45 1 10/08/20 15:31 10/11/20 02:10 7782-49-2 Silver ND mg/kg 0.45 0.23 1 10/08/20 15:31 10/11/20 02:10 7440-22-4 7471 Mercury Analytical Method: EPA 7471 B Preparation Method: EPA 7471 B Pace Analytical Services -Asheville Mercury 0.0044J mg/kg 0.0050 0.0039 1 10/08/2019:54 10/09/2011:23 7439-97-6 8270E MSSV Microwave Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte Acenaphthene ND ug/kg 404 104 1 10/10/20 14:17 10/12/20 13:00 83-32-9 Acenaphthylene ND ug/kg 404 95.7 1 10/10/20 14:17 10/12/20 13:00 208-96-8 Aniline ND ug/kg 404 90.8 1 10/10/20 14:17 10/12/20 13:00 62-53-3 Anthracene ND ug/kg 404 105 1 10/10/20 14:17 10/12/20 13:00 120-12-7 Benzo(a)anthracene ND ug/kg 404 129 1 10/10/20 14:17 10/12/20 13:00 56-55-3 Benzo(a)pyrene ND ug/kg 404 175 1 10/10/20 14:17 10/12/20 13:00 50-32-8 Benzo(b)fluoranthene ND ug/kg 404 163 1 10/10/20 14:17 10/12/20 13:00 205-99-2 Benzo(g,h,i)perylene ND ug/kg 404 158 1 10/10/20 14:17 10/12/20 13:00 191-24-2 Benzo(k)fluoranthene ND ug/kg 404 170 1 10/10/20 14:17 10/12/20 13:00 207-08-9 Benzoic Acid ND ug/kg 2020 436 1 10/10/20 14:17 10/12/20 13:00 65-85-0 Benzyl alcohol ND ug/kg 808 214 1 10/10/20 14:17 10/12/20 13:00 100-51-6 4-Bromophenylphenyl ether ND ug/kg 404 106 1 10/10/20 14:17 10/12/20 13:00 101-55-3 Butylbenzylphthalate ND ug/kg 404 108 1 10/10/20 14:17 10/12/20 13:00 85-68-7 4-ChIoro-3-methyl phenol ND ug/kg 808 246 1 10/10/20 14:17 10/12/20 13:00 59-50-7 4-Chloroaniline ND ug/kg 808 247 1 10/10/20 14:17 10/12/20 13:00 106-47-8 bis(2-Chloroethoxy)methane ND ug/kg 404 108 1 10/10/20 14:17 10/12/20 13:00 111-91-1 bis(2-Chloroethyl) ether ND ug/kg 404 85.9 1 10/10/20 14:17 10/12/20 13:00 111-44-4 2-Chloronaphthalene ND ug/kg 404 90.0 1 10/10/20 14:17 10/12/20 13:00 91-58-7 2-Chlorophenol ND ug/kg 404 94.1 1 10/10/20 14:17 10/12/20 13:00 95-57-8 4-Chlorophenylphenyl ether ND ug/kg 404 105 1 10/10/20 14:17 10/12/20 13:00 7005-72-3 Chrysene ND ug/kg 404 117 1 10/10/20 14:17 10/12/20 13:00 218-01-9 Dibenz(a,h)anthracene ND ug/kg 404 162 1 10/10/20 14:17 10/12/20 13:00 53-70-3 Dibenzofuran ND ug/kg 404 101 1 10/10/20 14:17 10/12/20 13:00 132-64-9 1,2-Dichlorobenzene ND ug/kg 404 87.5 1 10/10/20 14:17 10/12/20 13:00 95-50-1 1,3-Dichlorobenzene ND ug/kg 404 91.0 1 10/10/20 14:17 10/12/20 13:00 541-73-1 1,4-Dichlorobenzene ND ug/kg 404 88.9 1 10/10/20 14:17 10/12/20 13:00 106-46-7 3,3'-Dichlorobenzidine ND ug/kg 808 282 1 10/10/20 14:17 10/12/20 13:00 91-94-1 2,4-Dichlorophenol ND ug/kg 404 134 1 10/10/20 14:17 10/12/20 13:00 120-83-2 Diethylphthalate ND ug/kg 404 87.7 1 10/10/20 14:17 10/12/20 13:00 84-66-2 2,4-Dimethylphenol ND ug/kg 404 101 1 10/10/20 14:17 10/12/20 13:00 105-67-9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:29 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 37 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Park Pointe Stockpile Pace Project No.: 92499338 Sample: SP-01 Lab ID: 92499338001 Collected: 10/06/20 13:15 Received: 10/06/20 16:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8270E MSSV Microwave Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte Dimethylphthalate ND ug/kg 404 91.4 1 10/10/20 14:17 10/12/20 13:00 131-11-3 Di-n-butylphthalate ND ug/kg 404 99.7 1 10/10/20 14:17 10/12/20 13:00 84-74-2 4,6-Dinitro-2-methyl phenol ND ug/kg 808 652 1 10/10/20 14:17 10/12/20 13:00 534-52-1 2,4-Dinitrophenol ND ug/kg 2020 1290 1 10/10/20 14:17 10/12/20 13:00 51-28-5 2,4-Dinitrotoluene ND ug/kg 404 107 1 10/10/20 14:17 10/12/20 13:00 121-14-2 2,6-Dinitrotoluene ND ug/kg 404 106 1 10/10/20 14:17 10/12/20 13:00 606-20-2 Di-n-octylphthalate ND ug/kg 404 230 1 10/10/20 14:17 10/12/20 13:00 117-84-0 bis(2- Ethyl hexyl)phthalate ND ug/kg 404 132 1 10/10/20 14:17 10/12/20 13:00 117-81-7 Fluoranthene ND ug/kg 404 122 1 10/10/20 14:17 10/12/20 13:00 206-44-0 Fluorene ND ug/kg 404 108 1 10/10/20 14:17 10/12/20 13:00 86-73-7 Hexachloro-1,3-butadiene ND ug/kg 404 98.2 1 10/10/20 14:17 10/12/20 13:00 87-68-3 Hexachlorobenzene ND ug/kg 404 103 1 10/10/20 14:17 10/12/20 13:00 118-74-1 Hexachlorocyclopentadiene ND ug/kg 404 162 1 10/10/20 14:17 10/12/20 13:00 77-47-4 Hexachloroethane ND ug/kg 404 92.1 1 10/10/20 14:17 10/12/20 13:00 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/kg 404 185 1 10/10/20 14:17 10/12/20 13:00 193-39-5 Isophorone ND ug/kg 404 87.8 1 10/10/20 14:17 10/12/20 13:00 78-59-1 1-Methylnaphthalene ND ug/kg 404 108 1 10/10/20 14:17 10/12/20 13:00 90-12-0 2-Methylnaphthalene ND ug/kg 404 103 1 10/10/20 14:17 10/12/20 13:00 91-57-6 2-Methylphenol(o-Cresol) ND ug/kg 404 89.5 1 10/10/20 14:17 10/12/20 13:00 95-48-7 3&4-Methyl phenol (m&p Cresol) ND ug/kg 404 102 1 10/10/20 14:17 10/12/20 13:00 15831-10-4 Naphthalene ND ug/kg 404 96.8 1 10/10/20 14:17 10/12/20 13:00 91-20-3 2-Nitroaniline ND ug/kg 2020 203 1 10/10/20 14:17 10/12/20 13:00 88-74-4 3-Nitroaniline ND ug/kg 2020 214 1 10/10/20 14:17 10/12/20 13:00 99-09-2 4-Nitroaniline ND ug/kg 808 200 1 10/10/20 14:17 10/12/20 13:00 100-01-6 Nitrobenzene ND ug/kg 404 96.5 1 10/10/20 14:17 10/12/20 13:00 98-95-3 2-Nitrophenol ND ug/kg 404 125 1 10/10/20 14:17 10/12/20 13:00 88-75-5 4-Nitrophenol ND ug/kg 2020 644 1 10/10/20 14:17 10/12/20 13:00 100-02-7 N-Nitrosodimethylamine ND ug/kg 404 114 1 10/10/20 14:17 10/12/20 13:00 62-75-9 N-Nitroso-di-n-propylamine ND ug/kg 404 113 1 10/10/20 14:17 10/12/20 13:00 621-64-7 N-Nitrosodiphenylamine ND ug/kg 404 103 1 10/10/20 14:17 10/12/20 13:00 86-30-6 2,2'-Oxybis(1-chloropropane) ND ug/kg 404 112 1 10/10/20 14:17 10/12/20 13:00 108-60-1 Pentachlorophenol ND ug/kg 808 185 1 10/10/20 14:17 10/12/20 13:00 87-86-5 Phenanthrene ND ug/kg 404 102 1 10/10/20 14:17 10/12/20 13:00 85-01-8 Phenol ND ug/kg 404 96.5 1 10/10/20 14:17 10/12/20 13:00 108-95-2 Pyrene ND ug/kg 404 ill 1 10/10/20 14:17 10/12/20 13:00 129-00-0 Pyridine ND ug/kg 404 102 1 10/10/20 14:17 10/12/20 13:00 110-86-1 1,2,4-Trichlorobenzene ND ug/kg 404 92.6 1 10/10/20 14:17 10/12/20 13:00 120-82-1 2,4,5-Trichlorophenol ND ug/kg 404 105 1 10/10/20 14:17 10/12/20 13:00 95-95-4 2,4,6-Trichlorophenol ND ug/kg 404 102 1 10/10/20 14:17 10/12/20 13:00 88-06-2 Surrogates Nitrobenzene-d5 (S) 78 % 21-130 1 10/10/20 14:17 10/12/20 13:00 4165-60-0 2-Fluorobiphenyl (S) 61 % 19-130 1 10/10/20 14:17 10/12/20 13:00 321-60-8 Terphenyl-dl4 (S) 88 % 15-130 1 10/10/20 14:17 10/12/20 13:00 1718-51-0 Phenol-d6 (S) 82 % 18-130 1 10/10/20 14:17 10/12/20 13:00 13127-88-3 REPORT OF LABORATORY ANALYSIS v2 This report shall not be reproduced, except in full, Date: 10/27/2020 12:29 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 37 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Park Pointe Stockpile Pace Project No.: 92499338 Sample: SP-01 Lab ID: 92499338001 Collected: 10/06/20 13:15 Received: 10/06/20 16:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8270E MSSV Microwave Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte Surrogates 2-Fluorophenol (S) 77 % 18-130 1 10/10/20 14:17 10/12/20 13:00 367-12-4 2,4,6-Tribromophenol (S) 83 % 18-130 1 10/10/20 14:17 10/12/20 13:00 118-79-6 8260D/5035A/5030B Volatiles Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte Acetone ND ug/kg 249 92.8 1 10/08/20 16:38 10/09/20 14:04 67-64-1 Benzene ND ug/kg 12.4 8.8 1 10/08/20 16:38 10/09/20 14:04 71-43-2 Bromobenzene ND ug/kg 12.4 8.4 1 10/08/20 16:38 10/09/20 14:04 108-86-1 Bromochloromethane ND ug/kg 12.4 9.5 1 10/08/20 16:38 10/09/20 14:04 74-97-5 Bromodichloromethane ND ug/kg 12.4 8.2 1 10/08/20 16:38 10/09/20 14:04 75-27-4 Bromoform ND ug/kg 12.4 6.7 1 10/08/20 16:38 10/09/20 14:04 75-25-2 Bromomethane ND ug/kg 24.9 19.6 1 10/08/20 16:38 10/09/20 14:04 74-83-9 2-Butanone (MEK) ND ug/kg 249 105 1 10/08/20 16:38 10/09/20 14:04 78-93-3 n-Butylbenzene ND ug/kg 12.4 6.7 1 10/08/20 16:38 10/09/20 14:04 104-51-8 sec-Butylbenzene ND ug/kg 12.4 7.9 1 10/08/20 16:38 10/09/20 14:04 135-98-8 tert-Butyl benzene ND ug/kg 12.4 6.7 1 10/08/20 16:38 10/09/20 14:04 98-06-6 Carbon tetrachloride ND ug/kg 12.4 5.5 1 10/08/20 16:38 10/09/20 14:04 56-23-5 Chlorobenzene ND ug/kg 12.4 8.1 1 10/08/20 16:38 10/09/20 14:04 108-90-7 Chloroethane ND ug/kg 24.9 13.2 1 10/08/20 16:38 10/09/20 14:04 75-00-3 Chloroform ND ug/kg 12.4 6.1 1 10/08/20 16:38 10/09/20 14:04 67-66-3 Chloromethane ND ug/kg 24.9 17.5 1 10/08/20 16:38 10/09/20 14:04 74-87-3 2-Chlorotoluene ND ug/kg 12.4 8.9 1 10/08/20 16:38 10/09/20 14:04 95-49-8 4-Chlorotoluene ND ug/kg 12.4 7.9 1 10/08/20 16:38 10/09/20 14:04 106-43-4 1,2-Dibromo-3-chloropropane ND ug/kg 12.4 11.5 1 10/08/20 16:38 10/09/20 14:04 96-12-8 Dibromochloromethane ND ug/kg 12.4 6.7 1 10/08/20 16:38 10/09/20 14:04 124-48-1 1,2-Dibromoethane (EDB) ND ug/kg 12.4 8.8 1 10/08/20 16:38 10/09/20 14:04 106-93-4 Dibromomethane ND ug/kg 12.4 6.2 1 10/08/20 16:38 10/09/20 14:04 74-95-3 1,2-Dichlorobenzene ND ug/kg 12.4 7.4 1 10/08/20 16:38 10/09/20 14:04 95-50-1 1,3-Dichlorobenzene ND ug/kg 12.4 10.3 1 10/08/20 16:38 10/09/20 14:04 541-73-1 1,4-Dichlorobenzene ND ug/kg 12.4 9.3 1 10/08/20 16:38 10/09/20 14:04 106-46-7 Dichlorodifluoromethane ND ug/kg 24.9 4.3 1 10/08/20 16:38 10/09/20 14:04 75-71-8 1,1-Dichloroethane ND ug/kg 12.4 5.5 1 10/08/20 16:38 10/09/20 14:04 75-34-3 1,2-Dichloroethane ND ug/kg 12.4 5.1 1 10/08/20 16:38 10/09/20 14:04 107-06-2 1,1-Dichloroethene ND ug/kg 12.4 3.9 1 10/08/20 16:38 10/09/20 14:04 75-35-4 cis-1,2-Dichloroethene ND ug/kg 12.4 7.1 1 10/08/20 16:38 10/09/20 14:04 156-59-2 trans-1,2-Dichloroethene ND ug/kg 12.4 5.4 1 10/08/20 16:38 10/09/20 14:04 156-60-5 1,2-Dichloropropane ND ug/kg 12.4 7.7 1 10/08/20 16:38 10/09/20 14:04 78-87-5 1,3-Dichloropropane ND ug/kg 12.4 8.6 1 10/08/20 16:38 10/09/20 14:04 142-28-9 2,2-Dichloropropane ND ug/kg 12.4 6.8 1 10/08/20 16:38 10/09/20 14:04 594-20-7 1,1-Dichloropropene ND ug/kg 12.4 5.9 1 10/08/20 16:38 10/09/20 14:04 563-58-6 cis-1,3-Dichloropropene ND ug/kg 12.4 8.1 1 10/08/20 16:38 10/09/20 14:04 10061-01-5 trans- 1,3-Dichloropropene ND ug/kg 12.4 10.5 1 10/08/20 16:38 10/09/20 14:04 10061-02-6 Diisopropyl ether ND ug/kg 12.4 5.0 1 10/08/20 16:38 10/09/20 14:04 108-20-3 REPORT OF LABORATORY ANALYSIS v2 IK This report shall not be reproduced, except in full, Date: 10/27/2020 12:29 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 37 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Park Pointe Stockpile Pace Project No.: 92499338 Sample: SP-01 Lab ID: 92499338001 Collected: 10/06/20 13:15 Received: 10/06/20 16:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D/5035A/5030B Volatiles Ethylbenzene Hexachloro-1,3-butadiene 2-Hexanone Isopropylbenzene (Cumene) p-Isopropyltoluene Methylene Chloride 4-Methyl-2-pentanone (MIBK) Methyl-tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates Toluene-d8 (S) 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Percent Moisture Percent Moisture Total Solids 2540 G-2011 Total Solids Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte ND ug/kg 12.4 11.6 1 10/08/2016:38 10/09/2014:04 100-41-4 ND ug/kg 12.4 11.8 1 10/08/2016:38 10/09/2014:04 87-68-3 ND ug/kg 124 24.7 1 10/08/2016:38 10/09/2014:04 591-78-6 ND ug/kg 12.4 7.9 1 10/08/2016:38 10/09/2014:04 98-82-8 ND ug/kg 12.4 6.9 1 10/08/2016:38 10/09/2014:04 99-87-6 ND ug/kg 49.8 18.5 1 10/08/2016:38 10/09/2014:04 75-09-2 ND ug/kg 124 105 1 10/08/2016:38 10/09/2014:04 108-10-1 ND ug/kg 12.4 8.0 1 10/08/2016:38 10/09/2014:04 1634-04-4 ND ug/kg 12.4 7.0 1 10/08/2016:38 10/09/2014:04 91-20-3 ND ug/kg 12.4 8.6 1 10/08/2016:38 10/09/2014:04 103-65-1 ND ug/kg 12.4 5.9 1 10/08/2016:38 10/09/2014:04 100-42-5 ND ug/kg 12.4 8.2 1 10/08/2016:38 10/09/2014:04 630-20-6 ND ug/kg 12.4 11.0 1 10/08/2016:38 10/09/2014:04 79-34-5 ND ug/kg 12.4 6.2 1 10/08/2016:38 10/09/2014:04 127-18-4 ND ug/kg 12.4 7.1 1 10/08/2016:38 10/09/2014:04 108-88-3 ND ug/kg 12.4 7.6 1 10/08/2016:38 10/09/2014:04 87-61-6 ND ug/kg 12.4 6.9 1 10/08/2016:38 10/09/2014:04 120-82-1 ND ug/kg 12.4 5.0 1 10/08/2016:38 10/09/2014:04 71-55-6 ND ug/kg 12.4 9.3 1 10/08/2016:38 10/09/2014:04 79-00-5 ND ug/kg 12.4 7.8 1 10/08/2016:38 10/09/2014:04 79-01-6 ND ug/kg 12.4 3.1 1 10/08/2016:38 10/09/2014:04 75-69-4 ND ug/kg 12.4 10.1 1 10/08/2016:38 10/09/2014:04 96-18-4 ND ug/kg 12.4 9.0 1 10/08/2016:38 10/09/2014:04 95-63-6 ND ug/kg 12.4 7.4 1 10/08/2016:38 10/09/2014:04 108-67-8 ND ug/kg 124 10.7 1 10/08/2016:38 10/09/2014:04 108-05-4 ND ug/kg 24.9 4.8 1 10/08/2016:38 10/09/2014:04 75-01-4 ND ug/kg 24.9 7.1 1 10/08/2016:38 10/09/2014:04 1330-20-7 ND ug/kg 24.9 19.1 1 10/08/2016:38 10/09/2014:04 179601-23-1 ND ug/kg 12.4 7.1 1 10/08/2016:38 10/09/2014:04 95-47-6 100 % 70-130 1 10/08/2016:38 10/09/2014:04 2037-26-5 101 % 70-130 1 10/08/2016:38 10/09/2014:04 460-00-4 109 % 70-132 1 10/08/2016:38 10/09/2014:04 17060-07-0 Analytical Method: ASTM D2974-87 Pace Analytical Services - Charlotte 18.6 % 0.10 0.10 1 Analytical Method: SM 2540G Preparation Method: SM 2540 G Pace National - Mt. Juliet 87.6 % 10/08/20 16:44 1 10/20/20 13:39 10/20/20 13:48 REPORT OF LABORATORY ANALYSIS L�Z:1 This report shall not be reproduced, except in full, Date: 10/27/2020 12:29 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 37 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Park Pointe Stockpile Pace Project No.: 92499338 Sample: SP-01 Lab ID: 92499338001 Collected: 10/06/20 13:15 Received: 10/06/20 16:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Wet Chemistry 7199 Analytical Method: EPA 7199 Preparation Method: 3060A Pace National - Mt. Juliet Chromium, Hexavalent ND mg/kg 1.14 0.291 1 10/19/20 19:19 10/20/20 16:06 18540-29-9 Date: 10/27/2020 12:29 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 37 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Park Pointe Stockpile Pace Project No.: 92499338 Sample: DUP-SP Lab ID: 92499338002 Collected: 10/06/20 13:20 Received: 10/06/20 16:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3050B Pace Analytical Services -Asheville Arsenic 1.9 mg/kg 0.82 0.41 1 10/08/20 15:31 10/11/20 20:38 7440-38-2 BC Barium 61.6 mg/kg 0.41 0.20 1 10/08/20 15:31 10/11/20 02:20 7440-39-3 Cadmium 0.067J mg/kg 0.082 0.041 1 10/08/20 15:31 10/11/20 20:38 7440-43-9 Chromium 6.8 mg/kg 0.41 0.20 1 10/08/20 15:31 10/11/20 02:20 7440-47-3 Lead 10.1 mg/kg 0.41 0.20 1 10/08/20 15:31 10/11/20 20:38 7439-92-1 Selenium 0.61J mg/kg 0.82 0.41 1 10/08/20 15:31 10/11/20 02:20 7782-49-2 Silver ND mg/kg 0.41 0.20 1 10/08/20 15:31 10/11/20 02:20 7440-22-4 7471 Mercury Analytical Method: EPA 7471 B Preparation Method: EPA 7471 B Pace Analytical Services -Asheville Mercury 0.0044 mg/kg 0.0043 0.0033 1 10/08/2019:54 10/09/2011:26 7439-97-6 8270E MSSV Microwave Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte Acenaphthene ND ug/kg 362 93.1 1 10/10/20 14:17 10/12/20 13:26 83-32-9 Acenaphthylene ND ug/kg 362 85.6 1 10/10/20 14:17 10/12/20 13:26 208-96-8 Aniline ND ug/kg 362 81.2 1 10/10/20 14:17 10/12/20 13:26 62-53-3 Anthracene ND ug/kg 362 93.8 1 10/10/20 14:17 10/12/20 13:26 120-12-7 Benzo(a)anthracene ND ug/kg 362 115 1 10/10/20 14:17 10/12/20 13:26 56-55-3 Benzo(a)pyrene ND ug/kg 362 157 1 10/10/20 14:17 10/12/20 13:26 50-32-8 Benzo(b)fluoranthene ND ug/kg 362 146 1 10/10/20 14:17 10/12/20 13:26 205-99-2 Benzo(g,h,i)perylene ND ug/kg 362 141 1 10/10/20 14:17 10/12/20 13:26 191-24-2 Benzo(k)fluoranthene ND ug/kg 362 152 1 10/10/20 14:17 10/12/20 13:26 207-08-9 Benzoic Acid ND ug/kg 1810 390 1 10/10/20 14:17 10/12/20 13:26 65-85-0 Benzyl alcohol ND ug/kg 724 192 1 10/10/20 14:17 10/12/20 13:26 100-51-6 4-Bromophenylphenyl ether ND ug/kg 362 94.9 1 10/10/20 14:17 10/12/20 13:26 101-55-3 Butylbenzylphthalate ND ug/kg 362 96.4 1 10/10/20 14:17 10/12/20 13:26 85-68-7 4-ChIoro-3-methyl phenol ND ug/kg 724 220 1 10/10/20 14:17 10/12/20 13:26 59-50-7 4-Chloroaniline ND ug/kg 724 221 1 10/10/20 14:17 10/12/20 13:26 106-47-8 bis(2-Chloroethoxy)methane ND ug/kg 362 96.6 1 10/10/20 14:17 10/12/20 13:26 111-91-1 bis(2-Chloroethyl) ether ND ug/kg 362 76.9 1 10/10/20 14:17 10/12/20 13:26 111-44-4 2-Chloronaphthalene ND ug/kg 362 80.6 1 10/10/20 14:17 10/12/20 13:26 91-58-7 2-Chlorophenol ND ug/kg 362 84.2 1 10/10/20 14:17 10/12/20 13:26 95-57-8 4-Chlorophenylphenyl ether ND ug/kg 362 94.0 1 10/10/20 14:17 10/12/20 13:26 7005-72-3 Chrysene ND ug/kg 362 105 1 10/10/20 14:17 10/12/20 13:26 218-01-9 Dibenz(a,h)anthracene ND ug/kg 362 145 1 10/10/20 14:17 10/12/20 13:26 53-70-3 Dibenzofuran ND ug/kg 362 90.4 1 10/10/20 14:17 10/12/20 13:26 132-64-9 1,2-Dichlorobenzene ND ug/kg 362 78.3 1 10/10/20 14:17 10/12/20 13:26 95-50-1 1,3-Dichlorobenzene ND ug/kg 362 81.5 1 10/10/20 14:17 10/12/20 13:26 541-73-1 1,4-Dichlorobenzene ND ug/kg 362 79.6 1 10/10/20 14:17 10/12/20 13:26 106-46-7 3,3'-Dichlorobenzidine ND ug/kg 724 252 1 10/10/20 14:17 10/12/20 13:26 91-94-1 2,4-Dichlorophenol ND ug/kg 362 120 1 10/10/20 14:17 10/12/20 13:26 120-83-2 Diethylphthalate ND ug/kg 362 78.5 1 10/10/20 14:17 10/12/20 13:26 84-66-2 2,4-Dimethylphenol ND ug/kg 362 90.1 1 10/10/20 14:17 10/12/20 13:26 105-67-9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:29 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 37 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Park Pointe Stockpile Pace Project No.: 92499338 Sample: DUP-SP Lab ID: 92499338002 Collected: 10/06/20 13:20 Received: 10/06/20 16:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8270E MSSV Microwave Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte Dimethylphthalate ND ug/kg 362 81.8 1 10/10/20 14:17 10/12/20 13:26 131-11-3 Di-n-butylphthalate ND ug/kg 362 89.2 1 10/10/20 14:17 10/12/20 13:26 84-74-2 4,6-Dinitro-2-methyl phenol ND ug/kg 724 583 1 10/10/20 14:17 10/12/20 13:26 534-52-1 2,4-Dinitrophenol ND ug/kg 1810 1160 1 10/10/20 14:17 10/12/20 13:26 51-28-5 2,4-Dinitrotoluene ND ug/kg 362 95.8 1 10/10/20 14:17 10/12/20 13:26 121-14-2 2,6-Dinitrotoluene ND ug/kg 362 94.6 1 10/10/20 14:17 10/12/20 13:26 606-20-2 Di-n-octylphthalate ND ug/kg 362 206 1 10/10/20 14:17 10/12/20 13:26 117-84-0 bis(2- Ethyl hexyl)phthalate ND ug/kg 362 118 1 10/10/20 14:17 10/12/20 13:26 117-81-7 Fluoranthene ND ug/kg 362 109 1 10/10/20 14:17 10/12/20 13:26 206-44-0 Fluorene ND ug/kg 362 96.8 1 10/10/20 14:17 10/12/20 13:26 86-73-7 Hexachloro-1,3-butadiene ND ug/kg 362 87.9 1 10/10/20 14:17 10/12/20 13:26 87-68-3 Hexachlorobenzene ND ug/kg 362 91.9 1 10/10/20 14:17 10/12/20 13:26 118-74-1 Hexachlorocyclopentadiene ND ug/kg 362 145 1 10/10/20 14:17 10/12/20 13:26 77-47-4 Hexachloroethane ND ug/kg 362 82.4 1 10/10/20 14:17 10/12/20 13:26 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/kg 362 166 1 10/10/20 14:17 10/12/20 13:26 193-39-5 Isophorone ND ug/kg 362 78.6 1 10/10/20 14:17 10/12/20 13:26 78-59-1 1-Methylnaphthalene ND ug/kg 362 96.4 1 10/10/20 14:17 10/12/20 13:26 90-12-0 2-Methylnaphthalene ND ug/kg 362 92.1 1 10/10/20 14:17 10/12/20 13:26 91-57-6 2-Methylphenol(o-Cresol) ND ug/kg 362 80.1 1 10/10/20 14:17 10/12/20 13:26 95-48-7 3&4-Methyl phenol (m&p Cresol) ND ug/kg 362 91.0 1 10/10/20 14:17 10/12/20 13:26 15831-10-4 Naphthalene ND ug/kg 362 86.6 1 10/10/20 14:17 10/12/20 13:26 91-20-3 2-Nitroaniline ND ug/kg 1810 182 1 10/10/20 14:17 10/12/20 13:26 88-74-4 3-Nitroaniline ND ug/kg 1810 192 1 10/10/20 14:17 10/12/20 13:26 99-09-2 4-Nitroaniline ND ug/kg 724 179 1 10/10/20 14:17 10/12/20 13:26 100-01-6 Nitrobenzene ND ug/kg 362 86.4 1 10/10/20 14:17 10/12/20 13:26 98-95-3 2-Nitrophenol ND ug/kg 362 112 1 10/10/20 14:17 10/12/20 13:26 88-75-5 4-Nitrophenol ND ug/kg 1810 577 1 10/10/20 14:17 10/12/20 13:26 100-02-7 N-Nitrosodimethylamine ND ug/kg 362 102 1 10/10/20 14:17 10/12/20 13:26 62-75-9 N-Nitroso-di-n-propylamine ND ug/kg 362 101 1 10/10/20 14:17 10/12/20 13:26 621-64-7 N-Nitrosodiphenylamine ND ug/kg 362 92.3 1 10/10/20 14:17 10/12/20 13:26 86-30-6 2,2'-Oxybis(1-chloropropane) ND ug/kg 362 101 1 10/10/20 14:17 10/12/20 13:26 108-60-1 Pentachlorophenol ND ug/kg 724 166 1 10/10/20 14:17 10/12/20 13:26 87-86-5 Phenanthrene ND ug/kg 362 91.1 1 10/10/20 14:17 10/12/20 13:26 85-01-8 Phenol ND ug/kg 362 86.4 1 10/10/20 14:17 10/12/20 13:26 108-95-2 Pyrene ND ug/kg 362 99.5 1 10/10/20 14:17 10/12/20 13:26 129-00-0 Pyridine ND ug/kg 362 91.5 1 10/10/20 14:17 10/12/20 13:26 110-86-1 1,2,4-Trichlorobenzene ND ug/kg 362 82.9 1 10/10/20 14:17 10/12/20 13:26 120-82-1 2,4,5-Trichlorophenol ND ug/kg 362 94.0 1 10/10/20 14:17 10/12/20 13:26 95-95-4 2,4,6-Trichlorophenol ND ug/kg 362 90.9 1 10/10/20 14:17 10/12/20 13:26 88-06-2 Surrogates Nitrobenzene-d5 (S) 78 % 21-130 1 10/10/20 14:17 10/12/20 13:26 4165-60-0 2-Fluorobiphenyl (S) 61 % 19-130 1 10/10/20 14:17 10/12/20 13:26 321-60-8 Terphenyl-d14 (S) 86 % 15-130 1 10/10/20 14:17 10/12/20 13:26 1718-51-0 Phenol-d6 (S) 76 % 18-130 1 10/10/20 14:17 10/12/20 13:26 13127-88-3 REPORT OF LABORATORY ANALYSIS v2 This report shall not be reproduced, except in full, Date: 10/27/2020 12:29 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 37 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Park Pointe Stockpile Pace Project No.: 92499338 Sample: DUP-SP Lab ID: 92499338002 Collected: 10/06/20 13:20 Received: 10/06/20 16:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8270E MSSV Microwave Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte Surrogates 2-Fluorophenol (S) 74 % 18-130 1 10/10/20 14:17 10/12/20 13:26 367-12-4 2,4,6-Tribromophenol (S) 76 % 18-130 1 10/10/20 14:17 10/12/20 13:26 118-79-6 8260D/5035A/5030B Volatiles Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte Acetone ND ug/kg 240 89.7 1 10/08/20 16:38 10/09/20 14:22 67-64-1 Benzene ND ug/kg 12.0 8.5 1 10/08/20 16:38 10/09/20 14:22 71-43-2 Bromobenzene ND ug/kg 12.0 8.1 1 10/08/20 16:38 10/09/20 14:22 108-86-1 Bromochloromethane ND ug/kg 12.0 9.1 1 10/08/20 16:38 10/09/20 14:22 74-97-5 Bromodichloromethane ND ug/kg 12.0 7.9 1 10/08/20 16:38 10/09/20 14:22 75-27-4 Bromoform ND ug/kg 12.0 6.5 1 10/08/20 16:38 10/09/20 14:22 75-25-2 Bromomethane ND ug/kg 24.0 18.9 1 10/08/20 16:38 10/09/20 14:22 74-83-9 2-Butanone (MEK) ND ug/kg 240 102 1 10/08/20 16:38 10/09/20 14:22 78-93-3 n-Butylbenzene ND ug/kg 12.0 6.5 1 10/08/20 16:38 10/09/20 14:22 104-51-8 sec-Butylbenzene ND ug/kg 12.0 7.6 1 10/08/20 16:38 10/09/20 14:22 135-98-8 tert-Butyl benzene ND ug/kg 12.0 6.4 1 10/08/20 16:38 10/09/20 14:22 98-06-6 Carbon tetrachloride ND ug/kg 12.0 5.3 1 10/08/20 16:38 10/09/20 14:22 56-23-5 Chlorobenzene ND ug/kg 12.0 7.8 1 10/08/20 16:38 10/09/20 14:22 108-90-7 Chloroethane ND ug/kg 24.0 12.7 1 10/08/20 16:38 10/09/20 14:22 75-00-3 Chloroform ND ug/kg 12.0 5.9 1 10/08/20 16:38 10/09/20 14:22 67-66-3 Chloromethane ND ug/kg 24.0 16.9 1 10/08/20 16:38 10/09/20 14:22 74-87-3 2-Chlorotoluene ND ug/kg 12.0 8.6 1 10/08/20 16:38 10/09/20 14:22 95-49-8 4-Chlorotoluene ND ug/kg 12.0 7.7 1 10/08/20 16:38 10/09/20 14:22 106-43-4 1,2-Dibromo-3-chloropropane ND ug/kg 12.0 11.2 1 10/08/20 16:38 10/09/20 14:22 96-12-8 Dibromochloromethane ND ug/kg 12.0 6.5 1 10/08/20 16:38 10/09/20 14:22 124-48-1 1,2-Dibromoethane (EDB) ND ug/kg 12.0 8.5 1 10/08/20 16:38 10/09/20 14:22 106-93-4 Dibromomethane ND ug/kg 12.0 6.0 1 10/08/20 16:38 10/09/20 14:22 74-95-3 1,2-Dichlorobenzene ND ug/kg 12.0 7.1 1 10/08/20 16:38 10/09/20 14:22 95-50-1 1,3-Dichlorobenzene ND ug/kg 12.0 10 1 10/08/20 16:38 10/09/20 14:22 541-73-1 1,4-Dichlorobenzene ND ug/kg 12.0 9.0 1 10/08/20 16:38 10/09/20 14:22 106-46-7 Dichlorodifluoromethane ND ug/kg 24.0 4.1 1 10/08/20 16:38 10/09/20 14:22 75-71-8 1,1-Dichloroethane ND ug/kg 12.0 5.3 1 10/08/20 16:38 10/09/20 14:22 75-34-3 1,2-Dichloroethane ND ug/kg 12.0 4.9 1 10/08/20 16:38 10/09/20 14:22 107-06-2 1,1-Dichloroethene ND ug/kg 12.0 3.8 1 10/08/20 16:38 10/09/20 14:22 75-35-4 cis-1,2-Dichloroethene ND ug/kg 12.0 6.9 1 10/08/20 16:38 10/09/20 14:22 156-59-2 trans-1,2-Dichloroethene ND ug/kg 12.0 5.2 1 10/08/20 16:38 10/09/20 14:22 156-60-5 1,2-Dichloropropane ND ug/kg 12.0 7.5 1 10/08/20 16:38 10/09/20 14:22 78-87-5 1,3-Dichloropropane ND ug/kg 12.0 8.3 1 10/08/20 16:38 10/09/20 14:22 142-28-9 2,2-Dichloropropane ND ug/kg 12.0 6.6 1 10/08/20 16:38 10/09/20 14:22 594-20-7 1,1-Dichloropropene ND ug/kg 12.0 5.7 1 10/08/20 16:38 10/09/20 14:22 563-58-6 cis-1,3-Dichloropropene ND ug/kg 12.0 7.8 1 10/08/20 16:38 10/09/20 14:22 10061-01-5 trans- 1,3-Dichloropropene ND ug/kg 12.0 10.2 1 10/08/20 16:38 10/09/20 14:22 10061-02-6 Diisopropyl ether ND ug/kg 12.0 4.9 1 10/08/20 16:38 10/09/20 14:22 108-20-3 REPORT OF LABORATORY ANALYSIS v2 IK This report shall not be reproduced, except in full, Date: 10/27/2020 12:29 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 37 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Park Pointe Stockpile Pace Project No.: 92499338 Sample: DUP-SP Lab ID: 92499338002 Collected: 10/06/20 13:20 Received: 10/06/20 16:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D/5035A/5030B Volatiles Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte Ethylbenzene ND ug/kg 12.0 11.3 1 10/08/20 16:38 10/09/20 14:22 100-41-4 Hexachloro-1,3-butadiene ND ug/kg 12.0 11.4 1 10/08/20 16:38 10/09/20 14:22 87-68-3 2-Hexanone ND ug/kg 120 23.9 1 10/08/20 16:38 10/09/20 14:22 591-78-6 Isopropylbenzene (Cumene) ND ug/kg 12.0 7.6 1 10/08/20 16:38 10/09/20 14:22 98-82-8 p-Isopropyltoluene ND ug/kg 12.0 6.6 1 10/08/20 16:38 10/09/20 14:22 99-87-6 Methylene Chloride ND ug/kg 48.1 17.8 1 10/08/20 16:38 10/09/20 14:22 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/kg 120 102 1 10/08/20 16:38 10/09/20 14:22 108-10-1 Methyl-tert-butyl ether ND ug/kg 12.0 7.7 1 10/08/20 16:38 10/09/20 14:22 1634-04-4 Naphthalene ND ug/kg 12.0 6.8 1 10/08/20 16:38 10/09/20 14:22 91-20-3 n-Propylbenzene ND ug/kg 12.0 8.3 1 10/08/20 16:38 10/09/20 14:22 103-65-1 Styrene ND ug/kg 12.0 5.7 1 10/08/20 16:38 10/09/20 14:22 100-42-5 1,1,1,2-Tetrachloroethane ND ug/kg 12.0 7.9 1 10/08/20 16:38 10/09/20 14:22 630-20-6 1,1,2,2-Tetrachloroethane ND ug/kg 12.0 10.6 1 10/08/20 16:38 10/09/20 14:22 79-34-5 Tetrachloroethene ND ug/kg 12.0 6.0 1 10/08/20 16:38 10/09/20 14:22 127-18-4 Toluene ND ug/kg 12.0 6.9 1 10/08/20 16:38 10/09/20 14:22 108-88-3 1,2,3-Trichlorobenzene ND ug/kg 12.0 7.4 1 10/08/20 16:38 10/09/20 14:22 87-61-6 1,2,4-Trichlorobenzene ND ug/kg 12.0 6.7 1 10/08/20 16:38 10/09/20 14:22 120-82-1 1,1,1-Trichloroethane ND ug/kg 12.0 4.9 1 10/08/20 16:38 10/09/20 14:22 71-55-6 1,1,2-Trichloroethane ND ug/kg 12.0 8.9 1 10/08/20 16:38 10/09/20 14:22 79-00-5 Trichloroethene ND ug/kg 12.0 7.5 1 10/08/20 16:38 10/09/20 14:22 79-01-6 Trichlorofluoromethane ND ug/kg 12.0 3.0 1 10/08/20 16:38 10/09/20 14:22 75-69-4 1,2,3-Trichloropropane ND ug/kg 12.0 9.8 1 10/08/20 16:38 10/09/20 14:22 96-18-4 1,2,4-Trimethylbenzene ND ug/kg 12.0 8.7 1 10/08/20 16:38 10/09/20 14:22 95-63-6 1,3,5-Trimethylbenzene ND ug/kg 12.0 7.2 1 10/08/20 16:38 10/09/20 14:22 108-67-8 Vinyl acetate ND ug/kg 120 10.4 1 10/08/20 16:38 10/09/20 14:22 108-05-4 Vinyl chloride ND ug/kg 24.0 4.6 1 10/08/20 16:38 10/09/20 14:22 75-01-4 Xylene (Total) ND ug/kg 24.0 6.9 1 10/08/20 16:38 10/09/20 14:22 1330-20-7 m&p-Xylene ND ug/kg 24.0 18.5 1 10/08/20 16:38 10/09/20 14:22 179601-23-1 o-Xylene ND ug/kg 12.0 6.9 1 10/08/20 16:38 10/09/20 14:22 95-47-6 Surrogates Toluene-d8 (S) 100 % 70-130 1 10/08/20 16:38 10/09/20 14:22 2037-26-5 4-Bromofluorobenzene (S) 101 % 70-130 1 10/08/20 16:38 10/09/20 14:22 460-00-4 1,2-Dichloroethane-d4 (S) 106 % 70-132 1 10/08/20 16:38 10/09/20 14:22 17060-07-0 Percent Moisture Analytical Method: ASTM D2974-87 Pace Analytical Services - Charlotte Percent Moisture 8.8 % 0.10 0.10 1 10/08/20 16:44 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:29 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 37 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Park Pointe Stockpile Pace Project No.: 92499338 QC Batch: 571881 Analysis Method: EPA 7471 B QC Batch Method: EPA 7471 B Analysis Description: 7471 Mercury Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92499338001, 92499338002 METHOD BLANK: 3029078 Matrix: Solid Associated Lab Samples: 92499338001, 92499338002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury mg/kg ND 0.0060 0.0046 10/09/2010:43 LABORATORY CONTROL SAMPLE: 3029079 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg 0.083 0.086 103 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3029080 3029081 MS MSD 92498943001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg ND 0.088 0.091 0.093 0.092 103 98 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:29 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 37 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Park Pointe Stockpile Pace Project No.: 92499338 QC Batch: 571871 Analysis Method: EPA 6010D QC Batch Method: EPA 3050E Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92499338001, 92499338002 METHOD BLANK: 3029037 Matrix: Solid Associated Lab Samples: 92499338001, 92499338002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic mg/kg 0.54J 1.0 0.50 10/11/2019:10 BC Barium mg/kg ND 0.50 0.25 10/11/20 01:02 Cadmium mg/kg ND 0.10 0.050 10/11/20 01:02 Chromium mg/kg ND 0.50 0.25 10/11/20 01:02 Lead mg/kg ND 0.50 0.25 10/11/20 01:02 Selenium mg/kg ND 1.0 0.50 10/11/20 01:02 Silver mg/kg ND 0.50 0.25 10/11/20 01:02 LABORATORY CONTROL SAMPLE: 3029038 Parameter Units Arsenic mg/kg Barium mg/kg Cadmium mg/kg Chromium mg/kg Lead mg/kg Selenium mg/kg Silver mg/kg Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 50 49.2 98 80-120 50 51.3 103 80-120 50 45.5 91 80-120 50 49.1 98 80-120 50 45.7 91 80-120 50 39.9 80 80-120 25 22.9 92 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3029039 3029040 MS MSD 92498829001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic mg/kg 3.7 77.9 76.6 66.5 66.3 81 82 75-125 0 20 Barium mg/kg 174 77.9 76.6 243 235 88 80 75-125 3 20 Cadmium mg/kg 0.23 77.9 76.6 61.2 60.2 78 78 75-125 2 20 Chromium mg/kg 45.4 77.9 76.6 114 110 89 84 75-125 4 20 Lead mg/kg 7.3 77.9 76.6 66.9 65.4 77 76 75-125 2 20 Selenium mg/kg 1.9 77.9 76.6 53.8 53.7 67 68 75-125 0 20 M1 Silver mg/kg ND 38.9 38.3 30.8 30.5 79 80 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:29 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 37 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Park Pointe Stockpile Pace Project No.: 92499338 QC Batch: 571919 Analysis Method: EPA 8260D QC Batch Method: EPA 5035A/5030B Analysis Description: 8260D 5035A 5030E Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92499338001, 92499338002 METHOD BLANK: 3029247 Associated Lab Samples: 92499338001, 92499338002 Parameter Units Matrix: Blank Result Solid Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/kg ND 5.0 3.3 10/09/20 12:26 1,1,1-Trichloroethane ug/kg ND 5.0 2.0 10/09/20 12:26 1,1,2,2-Tetrachloroethane ug/kg ND 5.0 4.4 10/09/20 12:26 1,1,2-Trichloroethane ug/kg ND 5.0 3.7 10/09/20 12:26 1,1-Dichloroethane ug/kg ND 5.0 2.2 10/09/20 12:26 1,1-Dichloroethene ug/kg ND 5.0 1.6 10/09/20 12:26 1,1-Dichloropropene ug/kg ND 5.0 2.4 10/09/20 12:26 1,2,3-Trichlorobenzene ug/kg ND 5.0 3.1 10/09/20 12:26 1,2,3-Trichloropropane ug/kg ND 5.0 4.1 10/09/20 12:26 1,2,4-Trichlorobenzene ug/kg ND 5.0 2.8 10/09/20 12:26 1,2,4-Trimethylbenzene ug/kg ND 5.0 3.6 10/09/20 12:26 1,2-Dibromo-3-chloropropane ug/kg ND 5.0 4.6 10/09/20 12:26 1,2-Dibromoethane (EDB) ug/kg ND 5.0 3.5 10/09/20 12:26 1,2-Dichlorobenzene ug/kg ND 5.0 3.0 10/09/20 12:26 1,2-Dichloroethane ug/kg ND 5.0 2.0 10/09/20 12:26 1,2-Dichloropropane ug/kg ND 5.0 3.1 10/09/20 12:26 1,3,5-Trimethylbenzene ug/kg ND 5.0 3.0 10/09/20 12:26 1,3-Dichlorobenzene ug/kg ND 5.0 4.1 10/09/20 12:26 1,3-Dichloropropane ug/kg ND 5.0 3.5 10/09/20 12:26 1,4-Dichlorobenzene ug/kg ND 5.0 3.8 10/09/20 12:26 2,2-Dichloropropane ug/kg ND 5.0 2.8 10/09/20 12:26 2-Butanone (MEK) ug/kg ND 100 42.4 10/09/20 12:26 2-Chlorotoluene ug/kg ND 5.0 3.6 10/09/20 12:26 2-Hexanone ug/kg ND 50.0 9.9 10/09/20 12:26 4-Chlorotoluene ug/kg ND 5.0 3.2 10/09/20 12:26 4-Methyl-2-pentanone (MIBK) ug/kg ND 50.0 42.3 10/09/20 12:26 Acetone ug/kg ND 100 37.3 10/09/20 12:26 Benzene ug/kg ND 5.0 3.5 10/09/20 12:26 Bromobenzene ug/kg ND 5.0 3.4 10/09/20 12:26 Bromochloromethane ug/kg ND 5.0 3.8 10/09/20 12:26 Bromodichloromethane ug/kg ND 5.0 3.3 10/09/20 12:26 Bromoform ug/kg ND 5.0 2.7 10/09/20 12:26 Bromomethane ug/kg ND 10.0 7.9 10/09/20 12:26 Carbon tetrachloride ug/kg ND 5.0 2.2 10/09/20 12:26 Chlorobenzene ug/kg ND 5.0 3.2 10/09/20 12:26 Chloroethane ug/kg ND 10.0 5.3 10/09/20 12:26 IK Chloroform ug/kg ND 5.0 2.5 10/09/20 12:26 Chloromethane ug/kg ND 10.0 7.0 10/09/20 12:26 cis-1,2-Dichloroethene ug/kg ND 5.0 2.9 10/09/20 12:26 cis-1,3-Dichloropropene ug/kg ND 5.0 3.2 10/09/20 12:26 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:29 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 37 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Park Pointe Stockpile Pace Project No.: 92499338 METHOD BLANK: 3029247 Associated Lab Samples: 92499338001, 92499338002 Parameter Units Matrix: Blank Result Solid Reporting Limit MDL Analyzed Dibromochloromethane ug/kg ND 5.0 2.7 10/09/20 12:26 Dibromomethane ug/kg ND 5.0 2.5 10/09/20 12:26 Dichlorodifluoromethane ug/kg ND 10.0 1.7 10/09/20 12:26 Diisopropyl ether ug/kg ND 5.0 2.0 10/09/20 12:26 Ethylbenzene ug/kg ND 5.0 4.7 10/09/20 12:26 Hexachloro-1,3-butadiene ug/kg ND 5.0 4.7 10/09/20 12:26 Isopropylbenzene (Cumene) ug/kg ND 5.0 3.2 10/09/20 12:26 m&p-Xylene ug/kg ND 10.0 7.7 10/09/20 12:26 Methyl-tert-butyl ether ug/kg ND 5.0 3.2 10/09/20 12:26 Methylene Chloride ug/kg ND 20.0 7.4 10/09/20 12:26 n-Butylbenzene ug/kg ND 5.0 2.7 10/09/20 12:26 n-Propylbenzene ug/kg ND 5.0 3.4 10/09/20 12:26 Naphthalene ug/kg ND 5.0 2.8 10/09/20 12:26 o-Xylene ug/kg ND 5.0 2.8 10/09/20 12:26 p-Isopropyltoluene ug/kg ND 5.0 2.8 10/09/20 12:26 sec-Butylbenzene ug/kg ND 5.0 3.2 10/09/20 12:26 Styrene ug/kg ND 5.0 2.4 10/09/20 12:26 tert-Butyl benzene ug/kg ND 5.0 2.7 10/09/20 12:26 Tetrachloroethene ug/kg ND 5.0 2.5 10/09/20 12:26 Toluene ug/kg ND 5.0 2.9 10/09/20 12:26 trans-1,2-Dichloroethene ug/kg ND 5.0 2.2 10/09/20 12:26 trans- 1,3-Dichloropropene ug/kg ND 5.0 4.2 10/09/20 12:26 Trichloroethene ug/kg ND 5.0 3.1 10/09/20 12:26 Trichlorofluoromethane ug/kg ND 5.0 1.2 10/09/20 12:26 Vinyl acetate ug/kg ND 50.0 4.3 10/09/20 12:26 Vinyl chloride ug/kg ND 10.0 1.9 10/09/20 12:26 Xylene (Total) ug/kg ND 10.0 2.8 10/09/20 12:26 1,2-Dichloroethane-d4 (S) % 109 70-132 10/09/20 12:26 4-Bromofluorobenzene (S) % 97 70-130 10/09/20 12:26 Toluene-d8 (S) % 98 70-130 10/09/20 12:26 v2 Qualifiers LABORATORY CONTROL SAMPLE: 3029248 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/kg 1250 1320 106 70-130 1,1,1-Trichloroethane ug/kg 1250 1360 109 70-130 1,1,2,2-Tetrachloroethane ug/kg 1250 1310 105 55-130 1,1,2-Trichloroethane ug/kg 1250 1290 103 70-130 1,1-Dichloroethane ug/kg 1250 1370 110 68-130 1,1-Dichloroethene ug/kg 1250 1500 120 70-130 1,1-Dichloropropene ug/kg 1250 1190 95 70-130 1,2,3-Trichlorobenzene ug/kg 1250 1220 97 70-130 1,2,3-Trichloropropane ug/kg 1250 1310 105 70-130 1,2,4-Trichlorobenzene ug/kg 1250 1270 101 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:29 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 37 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Park Pointe Stockpile Pace Project No.: 92499338 LABORATORY CONTROL SAMPLE: Parameter 3029248 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,2,4-Trimethylbenzene ug/kg 1250 1220 98 69-130 1,2-Dibromo-3-chloropropane ug/kg 1250 1320 106 57-141 1,2-Dibromoethane (EDB) ug/kg 1250 1360 109 70-130 1,2-Dichlorobenzene ug/kg 1250 1250 100 70-130 1,2-Dichloroethane ug/kg 1250 1170 93 70-130 1,2-Dichloropropane ug/kg 1250 1280 102 70-130 1,3,5-Trimethylbenzene ug/kg 1250 1280 102 70-130 1,3-Dichlorobenzene ug/kg 1250 1240 99 70-130 1,3-Dichloropropane ug/kg 1250 1340 107 70-130 1,4-Dichlorobenzene ug/kg 1250 1200 96 70-130 2,2-Dichloropropane ug/kg 1250 1410 113 70-130 2-Butanone (MEK) ug/kg 2500 2580 103 60-130 2-Chlorotoluene ug/kg 1250 1310 105 70-130 2-Hexanone ug/kg 2500 2670 107 70-132 4-Chlorotoluene ug/kg 1250 1240 100 70-130 4-Methyl-2-pentanone (MIBK) ug/kg 2500 2580 103 69-130 Acetone ug/kg 2500 2510 100 49-148 Benzene ug/kg 1250 1310 105 70-130 Bromobenzene ug/kg 1250 1270 102 70-130 Bromochloromethane ug/kg 1250 1340 107 70-130 Bromodichloromethane ug/kg 1250 1230 98 70-130 Bromoform ug/kg 1250 1310 105 68-136 Bromomethane ug/kg 1250 1300 104 60-140 Carbon tetrachloride ug/kg 1250 1210 97 70-130 Chlorobenzene ug/kg 1250 1260 101 70-130 Chloroethane ug/kg 1250 1440 115 51-147IK Chloroform ug/kg 1250 1310 105 70-130 Chloromethane ug/kg 1250 1220 98 48-130 cis-1,2-Dichloroethene ug/kg 1250 1380 110 70-130 cis-1,3-Dichloropropene ug/kg 1250 1370 109 70-130 Dibromochloromethane ug/kg 1250 1360 109 70-130 Dibromomethane ug/kg 1250 1300 104 70-130 Dichlorodifluoromethane ug/kg 1250 1600 128 49-130 Diisopropyl ether ug/kg 1250 1290 103 66-130 Ethylbenzene ug/kg 1250 1200 96 70-130 Hexachloro-1,3-butadiene ug/kg 1250 1310 105 70-130 Isopropylbenzene (Cumene) ug/kg 1250 1280 102 70-130 m&p-Xylene ug/kg 2500 2560 102 70-130 Methyl-tert-butyl ether ug/kg 1250 1300 104 70-130 Methylene Chloride ug/kg 1250 1260 101 50-137 n-Butylbenzene ug/kg 1250 1290 103 70-130 n-Propylbenzene ug/kg 1250 1290 103 70-130 Naphthalene ug/kg 1250 1220 98 70-131 o-Xylene ug/kg 1250 1240 99 70-130 p-Isopropyltoluene ug/kg 1250 1290 103 70-130 sec-Butylbenzene ug/kg 1250 1290 103 70-130 Styrene ug/kg 1250 1330 107 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:29 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 37 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Park Pointe Stockpile Pace Project No.: 92499338 LABORATORY CONTROL SAMPLE: Parameter 3029248 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers tert-Butyl benzene ug/kg 1250 936 75 69-130 v3 Tetrachloroethene ug/kg 1250 1230 99 56-130 Toluene ug/kg 1250 1240 99 70-130 trans-1,2-Dichloroethene ug/kg 1250 1410 113 70-130 trans- 1,3-Dichloropropene ug/kg 1250 1300 104 70-130 Trichloroethene ug/kg 1250 1220 98 70-141 Trichlorofluoromethane ug/kg 1250 1390 111 67-130 Vinyl acetate ug/kg 2500 2930 117 10-136 Vinyl chloride ug/kg 1250 1330 107 67-130 Xylene (Total) ug/kg 3750 3800 101 70-130 1,2-Dichloroethane-d4 (S) % 94 70-132 4-Bromofluorobenzene (S) % 101 70-130 Toluene-d8 (S) % 98 70-130 MATRIX SPIKE SAMPLE: Parameter 3029250 Units 92499316002 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/kg ND 935 1120 119 52-133 1,1,1-Trichloroethane ug/kg ND 935 1250 133 49-137 1,1,2,2-Tetrachloroethane ug/kg ND 935 1120 119 39-150 1,1,2-Trichloroethane ug/kg ND 935 1230 132 48-140 1,1-Dichloroethane ug/kg ND 935 1310 140 46-135 M1 1,1-Dichloroethene ug/kg ND 935 517 55 38-149 1,1-Dichloropropene ug/kg ND 935 1150 123 41-140 1,2,3-Trichlorobenzene ug/kg ND 935 503 54 10-158 1,2,3-Trichloropropane ug/kg ND 935 1120 120 33-157 1,2,4-Trichlorobenzene ug/kg ND 935 860 92 10-155 1,2,4-Trimethylbenzene ug/kg ND 935 1190 127 24-154 1,2-Dibromo-3-chloropropane ug/kg ND 935 535 57 33-158 1,2-Dibromoethane (EDB) ug/kg ND 935 1140 122 40-136 1,2-Dichlorobenzene ug/kg ND 935 1130 120 27-146 1,2-Dichloroethane ug/kg ND 935 1170 125 49-140 1,2-Dichloropropane ug/kg ND 935 1200 128 44-143 1,3,5-Trimethylbenzene ug/kg ND 935 1180 126 40-144 1,3-Dichlorobenzene ug/kg ND 935 1120 120 33-140 1,3-Dichloropropane ug/kg ND 935 1240 133 47-147 1,4-Dichlorobenzene ug/kg ND 935 1120 119 35-139 2,2-Dichloropropane ug/kg ND 935 996 107 41-140 2-Butanone (MEK) ug/kg ND 1870 1070 54 10-181 2-Chlorotoluene ug/kg ND 935 1200 128 38-147 2-Hexanone ug/kg ND 1870 732 39 18-169 4-Chlorotoluene ug/kg ND 935 1160 124 36-145 4-Methyl-2-pentanone (MIBK) ug/kg ND 1870 1560 83 16-175 Acetone ug/kg ND 1870 1240 66 10-200 Benzene ug/kg ND 935 1240 133 46-136 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:29 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 37 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Park Pointe Stockpile Pace Project No.: 92499338 MATRIX SPIKE SAMPLE: 3029250 92499316002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Bromobenzene ug/kg ND 935 1240 133 38-149 Bromochloromethane ug/kg ND 935 1240 133 44-142 Bromodichloromethane ug/kg ND 935 1080 116 41-140 Bromoform ug/kg ND 935 963 103 34-145 Bromomethane ug/kg ND 935 1120 120 14-162 Carbon tetrachloride ug/kg ND 935 1060 114 44-141 Chlorobenzene ug/kg ND 935 1120 120 39-141 Chloroethane ug/kg ND 935 342 37 10-182 IK Chloroform ug/kg ND 935 1230 131 45-140 Chloromethane ug/kg ND 935 1220 130 19-149 v3 cis-1,2-Dichloroethene ug/kg ND 935 1300 139 38-150 cis-1,3-Dichloropropene ug/kg ND 935 1250 134 30-144 Dibromochloromethane ug/kg ND 935 1070 114 36-145 Dibromomethane ug/kg ND 935 1120 120 41-145 Dichlorodifluoromethane ug/kg ND 935 1580 169 16-146 M1,v3 Diisopropyl ether ug/kg ND 935 1250 134 41-143 Ethylbenzene ug/kg ND 935 1100 117 35-144 Hexachloro-1,3-butadiene ug/kg ND 935 1170 126 10-160 Isopropylbenzene (Cumene) ug/kg ND 935 1150 123 30-152 m&p-Xylene ug/kg ND 1870 2330 125 33-145 Methyl-tert-butyl ether ug/kg ND 935 1210 130 49-140 Methylene Chloride ug/kg ND 935 965 103 10-174 n-Butylbenzene ug/kg ND 935 1250 134 10-160 n-Propylbenzene ug/kg ND 935 1220 130 24-159 Naphthalene ug/kg ND 935 2700 288 10-171 C8,M1 o-Xylene ug/kg ND 935 1140 122 31-150 p-Isopropyltoluene ug/kg ND 935 1200 128 21-154 sec-Butylbenzene ug/kg ND 935 1230 131 19-159 Styrene ug/kg ND 935 1160 124 15-152 tert-Butyl benzene ug/kg ND 935 871 93 31-141 Tetrachloroethene ug/kg ND 935 1060 113 19-141 Toluene ug/kg ND 935 1180 126 31-146 trans-1,2-Dichloroethene ug/kg ND 935 1380 148 28-157 trans- 1,3-Dichloropropene ug/kg ND 935 1190 127 25-146 Trichloroethene ug/kg ND 935 1140 122 34-149 Trichlorofluoromethane ug/kg ND 935 15.8 2 10-167 M1 Vinyl acetate ug/kg ND 1870 2610 140 10-200 Vinyl chloride ug/kg ND 935 1430 152 36-155 Xylene (Total) ug/kg ND 2810 3470 124 29-148 1,2-Dichloroethane-d4 (S) % 127 70-132 4-Bromofluorobenzene (S) % 104 70-130 Toluene-d8 (S) % 100 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:29 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 37 Pace Analytical Services, LLC lac, Analyilcal ® 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: Park Pointe Stockpile Pace Project No.: 92499338 SAMPLE DUPLICATE: 3029249 Parameter Units 92499316001 Result Dup Result RPD Max RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/kg ND ND 30 1,1,1-Trichloroethane ug/kg ND ND 30 1,1,2,2-Tetrachloroethane ug/kg ND ND 30 1,1,2-Trichloroethane ug/kg ND ND 30 1,1-Dichloroethane ug/kg ND ND 30 1,1-Dichloroethene ug/kg ND ND 30 1,1-Dichloropropene ug/kg ND ND 30 1,2,3-Trichlorobenzene ug/kg ND ND 30 1,2,3-Trichloropropane ug/kg ND ND 30 1,2,4-Trichlorobenzene ug/kg ND ND 30 1,2,4-Trimethylbenzene ug/kg ND ND 30 1,2-Dibromo-3-chloropropane ug/kg ND ND 30 1,2-Dibromoethane (EDB) ug/kg ND ND 30 1,2-Dichlorobenzene ug/kg ND ND 30 1,2-Dichloroethane ug/kg ND ND 30 1,2-Dichloropropane ug/kg ND ND 30 1,3,5-Trimethylbenzene ug/kg ND ND 30 1,3-Dichlorobenzene ug/kg ND ND 30 1,3-Dichloropropane ug/kg ND ND 30 1,4-Dichlorobenzene ug/kg ND ND 30 2,2-Dichloropropane ug/kg ND ND 30 2-Butanone (MEK) ug/kg ND ND 30 2-Chlorotoluene ug/kg ND ND 30 2-Hexanone ug/kg ND ND 30 4-Chlorotoluene ug/kg ND ND 30 4-Methyl-2-pentanone (MIBK) ug/kg ND ND 30 Acetone ug/kg ND ND 30 Benzene ug/kg ND ND 30 Bromobenzene ug/kg ND ND 30 Bromochloromethane ug/kg ND ND 30 Bromodichloromethane ug/kg ND ND 30 Bromoform ug/kg ND ND 30 Bromomethane ug/kg ND ND 30 v2 Carbon tetrachloride ug/kg ND ND 30 Chlorobenzene ug/kg ND ND 30 Chloroethane ug/kg ND ND 301K Chloroform ug/kg ND ND 30 Chloromethane ug/kg ND ND 30 cis-1,2-Dichloroethene ug/kg ND ND 30 cis-1,3-Dichloropropene ug/kg ND ND 30 Dibromochloromethane ug/kg ND ND 30 Dibromomethane ug/kg ND ND 30 Dichlorodifluoromethane ug/kg ND ND 30 v2 Diisopropyl ether ug/kg ND ND 30 Ethylbenzene ug/kg ND ND 30 Hexachloro-1,3-butadiene ug/kg ND ND 30 Isopropylbenzene (Cumene) ug/kg ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:29 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 37 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Park Pointe Stockpile Pace Project No.: 92499338 SAMPLE DUPLICATE: 3029249 Parameter Units 92499316001 Result Dup Result m&p-Xylene ug/kg ND ND Methyl-tert-butyl ether ug/kg ND ND Methylene Chloride ug/kg ND ND n-Butylbenzene ug/kg ND ND n-Propylbenzene ug/kg ND ND Naphthalene ug/kg ND ND o-Xylene ug/kg ND ND p-Isopropyltoluene ug/kg ND ND sec-Butylbenzene ug/kg ND ND Styrene ug/kg ND ND tert-Butyl benzene ug/kg ND ND Tetrachloroethene ug/kg ND ND Toluene ug/kg ND ND trans-1,2-Dichloroethene ug/kg ND ND trans- 1,3-Dichloropropene ug/kg ND ND Trichloroethene ug/kg ND ND Trichlorofluoromethane ug/kg ND ND Vinyl acetate ug/kg ND ND Vinyl chloride ug/kg ND ND Xylene (Total) ug/kg ND ND 1,2-Dichloroethane-d4 (S) % 108 113 4-Bromofluorobenzene (S) % 101 101 Toluene-d8(S) % 101 101 Max RPD RPD Qualifiers 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:29 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 37 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Park Pointe Stockpile Pace Project No.: 92499338 QC Batch: 572372 Analysis Method: EPA 8270E QC Batch Method: EPA 3546 Analysis Description: 8270E Solid MSSV Microwave Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92499338001, 92499338002 METHOD BLANK: 3031498 Associated Lab Samples: 92499338001, 92499338002 Parameter Units Matrix: Blank Result Solid Reporting Limit MDL Analyzed 1,2,4-Trichlorobenzene ug/kg ND 334 76.6 10/12/20 09:51 1,2-Dichlorobenzene ug/kg ND 334 72.4 10/12/20 09:51 1,3-Dichlorobenzene ug/kg ND 334 75.3 10/12/20 09:51 1,4-Dichlorobenzene ug/kg ND 334 73.6 10/12/20 09:51 1-Methylnaphthalene ug/kg ND 334 89.1 10/12/20 09:51 2,2'-Oxybis(1-chloropropane) ug/kg ND 334 92.9 10/12/20 09:51 2,4,5-Trichlorophenol ug/kg ND 334 86.9 10/12/20 09:51 2,4,6-Trichlorophenol ug/kg ND 334 84.0 10/12/20 09:51 2,4-Dichlorophenol ug/kg ND 334 110 10/12/20 09:51 2,4-Dimethylphenol ug/kg ND 334 83.3 10/12/20 09:51 2,4-Dinitrophenol ug/kg ND 1670 1070 10/12/20 09:51 2,4-Dinitrotoluene ug/kg ND 334 88.6 10/12/20 09:51 2,6-Dinitrotoluene ug/kg ND 334 87.5 10/12/20 09:51 2-Chloronaphthalene ug/kg ND 334 74.5 10/12/20 09:51 2-Chlorophenol ug/kg ND 334 77.8 10/12/20 09:51 2-Methylnaphthalene ug/kg ND 334 85.1 10/12/20 09:51 2-Methylphenol(o-Cresol) ug/kg ND 334 74.1 10/12/20 09:51 2-Nitroaniline ug/kg ND 1670 168 10/12/20 09:51 2-Nitrophenol ug/kg ND 334 103 10/12/20 09:51 3&4-Methyl phenol (m&p Cresol) ug/kg ND 334 84.1 10/12/20 09:51 3,3'-Dichlorobenzidine ug/kg ND 669 233 10/12/20 09:51 3-Nitroaniline ug/kg ND 1670 177 10/12/20 09:51 4,6-Dinitro-2-methyl phenol ug/kg ND 669 539 10/12/20 09:51 4-Bromophenylphenyl ether ug/kg ND 334 87.8 10/12/20 09:51 4-ChIoro-3-methyl phenol ug/kg ND 669 204 10/12/20 09:51 4-Chloroaniline ug/kg ND 669 205 10/12/20 09:51 4-Chlorophenylphenyl ether ug/kg ND 334 86.9 10/12/20 09:51 4-Nitroaniline ug/kg ND 669 165 10/12/20 09:51 4-Nitrophenol ug/kg ND 1670 533 10/12/20 09:51 Acenaphthene ug/kg ND 334 86.0 10/12/20 09:51 Acenaphthylene ug/kg ND 334 79.2 10/12/20 09:51 Aniline ug/kg ND 334 75.1 10/12/20 09:51 Anthracene ug/kg ND 334 86.8 10/12/20 09:51 Benzo(a)anthracene ug/kg ND 334 106 10/12/20 09:51 Benzo(a)pyrene ug/kg ND 334 145 10/12/20 09:51 Benzo(b)fluoranthene ug/kg ND 334 135 10/12/20 09:51 Benzo(g,h,i)perylene ug/kg ND 334 131 10/12/20 09:51 Benzo(k)fluoranthene ug/kg ND 334 141 10/12/20 09:51 Benzoic Acid ug/kg ND 1670 361 10/12/20 09:51 Benzyl alcohol ug/kg ND 669 177 10/12/20 09:51 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:29 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 37 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Park Pointe Stockpile Pace Project No.: 92499338 METHOD BLANK: 3031498 Associated Lab Samples: 92499338001, 92499338002 Parameter Units Matrix: Blank Result Solid Reporting Limit MDL Analyzed bis(2-Chloroethoxy)methane ug/kg ND 334 89.3 10/12/20 09:51 bis(2-Chloroethyl) ether ug/kg ND 334 71.0 10/12/20 09:51 bis(2-Ethylhexyl)phthalate ug/kg ND 334 109 10/12/20 09:51 Butylbenzylphthalate ug/kg ND 334 89.1 10/12/20 09:51 Chrysene ug/kg ND 334 97.1 10/12/20 09:51 Di-n-butylphthalate ug/kg ND 334 82.5 10/12/20 09:51 Di-n-octylphthalate ug/kg ND 334 191 10/12/20 09:51 Dibenz(a,h)anthracene ug/kg ND 334 134 10/12/20 09:51 Dibenzofuran ug/kg ND 334 83.6 10/12/20 09:51 Diethylphthalate ug/kg ND 334 72.6 10/12/20 09:51 Dimethylphthalate ug/kg ND 334 75.6 10/12/20 09:51 Fluoranthene ug/kg ND 334 101 10/12/20 09:51 Fluorene ug/kg ND 334 89.5 10/12/20 09:51 Hexachloro-1,3-butadiene ug/kg ND 334 81.3 10/12/20 09:51 Hexachlorobenzene ug/kg ND 334 84.9 10/12/20 09:51 Hexachlorocyclopentadiene ug/kg ND 334 134 10/12/20 09:51 Hexachloroethane ug/kg ND 334 76.2 10/12/20 09:51 Indeno(1,2,3-cd)pyrene ug/kg ND 334 153 10/12/20 09:51 Isophorone ug/kg ND 334 72.7 10/12/20 09:51 N-Nitroso-di-n-propylamine ug/kg ND 334 93.6 10/12/20 09:51 N-Nitrosodimethylamine ug/kg ND 334 94.1 10/12/20 09:51 N-Nitrosodiphenylamine ug/kg ND 334 85.3 10/12/20 09:51 Naphthalene ug/kg ND 334 80.1 10/12/20 09:51 Nitrobenzene ug/kg ND 334 79.9 10/12/20 09:51 Pentachlorophenol ug/kg ND 669 153 10/12/20 09:51 Phenanthrene ug/kg ND 334 84.2 10/12/20 09:51 Phenol ug/kg ND 334 79.9 10/12/20 09:51 Pyrene ug/kg ND 334 92.0 10/12/20 09:51 Pyridine ug/kg ND 334 84.6 10/12/20 09:51 2,4,6-Tribromophenol (S) % 80 18-130 10/12/20 09:51 2-Fluorobiphenyl (S) % 80 19-130 10/12/20 09:51 2-Fluorophenol (S) % 81 18-130 10/12/20 09:51 Nitrobenzene-d5 (S) % 84 21-130 10/12/20 09:51 Phenol-d6 (S) % 85 18-130 10/12/20 09:51 Terphenyl-d14 (S) % 110 15-130 10/12/20 09:51 v2 Qualifiers LABORATORY CONTROL SAMPLE: 3031499 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,2,4-Trichlorobenzene ug/kg 1690 1420 84 47-130 1,2-Dichlorobenzene ug/kg 1690 1450 85 49-130 1,3-Dichlorobenzene ug/kg 1690 1440 85 48-130 1,4-Dichlorobenzene ug/kg 1690 1470 87 49-130 1-Methylnaphthalene ug/kg 1690 1440 85 54-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:29 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 37 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Park Pointe Stockpile Pace Project No.: 92499338 LABORATORY CONTROL SAMPLE: Parameter 3031499 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 2,2'-Oxybis(1-chloropropane) ug/kg 1690 1480 87 38-130 2,4,5-Trichlorophenol ug/kg 1690 1700 100 49-130 2,4,6-Trichlorophenol ug/kg 1690 1550 92 50-130 2,4-Dichlorophenol ug/kg 1690 1540 91 51-130 2,4-Dimethylphenol ug/kg 1690 1570 93 53-130 2,4-Dinitrophenol ug/kg 8470 7100 84 39-130 2,4-Dinitrotoluene ug/kg 1690 1700 101 53-130 2,6-Dinitrotoluene ug/kg 1690 1700 100 55-130 2-Chloronaphthalene ug/kg 1690 1590 94 48-130 2-Chlorophenol ug/kg 1690 1530 90 54-130 2-Methylnaphthalene ug/kg 1690 1480 88 57-130 2-Methylphenol(o-Cresol) ug/kg 1690 1620 96 50-130 2-Nitroaniline ug/kg 3390 3590 106 49-130 2-Nitrophenol ug/kg 1690 1490 88 50-130 3&4-Methyl phenol (m&p Cresol) ug/kg 1690 1580 93 50-130 3,3'-Dichlorobenzidine ug/kg 3390 3000 89 47-130 3-Nitroaniline ug/kg 3390 3170 94 45-130 4,6-Dinitro-2-methyl phenol ug/kg 3390 3020 89 50-142 4-Bromophenylphenyl ether ug/kg 1690 1560 92 55-130 4-ChIoro-3-methyl phenol ug/kg 3390 3240 96 52-130 4-Chloroaniline ug/kg 3390 2930 86 49-130 4-Chlorophenylphenyl ether ug/kg 1690 1650 98 53-130 4-Nitroaniline ug/kg 3390 3540 104 51-130 4-Nitrophenol ug/kg 8470 9760 115 40-130 Acenaphthene ug/kg 1690 1580 93 56-130 Acenaphthylene ug/kg 1690 1590 94 58-130 Aniline ug/kg 1690 1400 82 44-130 Anthracene ug/kg 1690 1490 88 60-130 Benzo(a)anthracene ug/kg 1690 1700 100 59-130 Benzo(a)pyrene ug/kg 1690 1710 101 57-130 Benzo(b)fluoranthene ug/kg 1690 1700 100 54-130 Benzo(g,h,i)perylene ug/kg 1690 1570 92 59-130 Benzo(k)fluoranthene ug/kg 1690 1760 104 54-130 Benzoic Acid ug/kg 8470 5760 68 19-130 Benzyl alcohol ug/kg 3390 2980 88 50-130 bis(2-Chloroethoxy)methane ug/kg 1690 1440 85 55-130 bis(2-Chloroethyl) ether ug/kg 1690 1570 92 53-130 bis(2-Ethylhexyl)phthalate ug/kg 1690 1600 94 58-130 Butylbenzylphthalate ug/kg 1690 1590 94 46-138 Chrysene ug/kg 1690 1710 101 57-130 Di-n-butylphthalate ug/kg 1690 1650 97 57-130 Di-n-octylphthalate ug/kg 1690 1580 93 57-130 Dibenz(a,h)anthracene ug/kg 1690 1560 92 60-130 Dibenzofuran ug/kg 1690 1660 98 54-130 Diethylphthalate ug/kg 1690 1670 98 55-130 Dimethylphthalate ug/kg 1690 1660 98 57-130 Fluoranthene ug/kg 1690 1800 106 57-130 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:29 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 37 Pace Analytical Services, LLC lac, Analyilcal ® 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: Park Pointe Stockpile Pace Project No.: 92499338 LABORATORY CONTROL SAMPLE: Parameter 3031499 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Fluorene ug/kg 1690 1660 98 56-130 Hexachloro-1,3-butadiene ug/kg 1690 1430 84 41-130 Hexachlorobenzene ug/kg 1690 1560 92 53-130 Hexachlorocyclopentadiene ug/kg 1690 854 50 23-130 v3 Hexachloroethane ug/kg 1690 1410 83 48-130 Indeno(1,2,3-cd)pyrene ug/kg 1690 1580 93 61-130 Isophorone ug/kg 1690 1520 90 49-130 N-Nitroso-di-n-propylamine ug/kg 1690 1530 90 52-130 N-Nitrosodimethylamine ug/kg 1690 1510 89 45-130 N-Nitrosodiphenylamine ug/kg 1690 1590 94 56-130 Naphthalene ug/kg 1690 1460 86 56-130 Nitrobenzene ug/kg 1690 1540 91 50-130 Pentachlorophenol ug/kg 3390 3330 98 33-130 Phenanthrene ug/kg 1690 1680 99 60-130 Phenol ug/kg 1690 1600 94 54-130 Pyrene ug/kg 1690 1610 95 61-130 Pyridine ug/kg 1690 1250 74 35-130 2,4,6-Tribromophenol (S) % 93 18-130 2-Fluorobiphenyl (S) % 81 19-130 2-Fluorophenol(S) % 81 18-130 Nitrobenzene-d5(S) % 81 21-130 Phenol-d6 (S) % 86 18-130 Terphenyl-d14 (S) % 87 15-130 MATRIX SPIKE SAMPLE: Parameter 3031500 Units 92499114004 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,2,4-Trichlorobenzene ug/kg ND 2050 1170 57 22-130 1,2-Dichlorobenzene ug/kg ND 2050 1170 57 23-130 1,3-Dichlorobenzene ug/kg ND 2050 1170 57 26-130 1,4-Dichlorobenzene ug/kg ND 2050 1200 58 27-130 1-Methylnaphthalene ug/kg ND 2050 1190 58 30-130 2,2'-Oxybis(1-chloropropane) ug/kg ND 2050 1260 61 30-130 2,4,5-Trichlorophenol ug/kg ND 2050 1390 68 26-130 2,4,6-Trichlorophenol ug/kg ND 2050 1240 60 23-130 2,4-Dichlorophenol ug/kg ND 2050 1300 64 29-130 2,4-Dimethylphenol ug/kg ND 2050 1300 63 13-130 2,4-Dinitrophenol ug/kg ND 10300 5450 53 10-131 2,4-Dinitrotoluene ug/kg ND 2050 1380 67 28-130 2,6-Dinitrotoluene ug/kg ND 2050 1370 67 36-130 2-Chloronaphthalene ug/kg ND 2050 1260 62 27-130 2-Chlorophenol ug/kg ND 2050 1320 64 29-130 2-Methylnaphthalene ug/kg ND 2050 1210 59 29-130 2-Methylphenol(o-Cresol) ug/kg ND 2050 1390 68 20-130 2-Nitroaniline ug/kg ND 4100 3040 74 29-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:29 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 37 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Park Pointe Stockpile Pace Project No.: 92499338 MATRIX SPIKE SAMPLE: 3031500 92499114004 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 2-Nitrophenol ug/kg ND 2050 1270 62 26-130 3&4-Methyl phenol (m&p Cresol) ug/kg ND 2050 1380 67 10-176 3,3'-Dichlorobenzidine ug/kg ND 4100 2260 55 15-130 3-Nitroaniline ug/kg ND 4100 2750 67 28-130 4,6-Dinitro-2-methyl phenol ug/kg ND 4100 2300 56 15-132 4-Bromophenylphenyl ether ug/kg ND 2050 1210 59 35-130 4-Chloro-3-methylphenol ug/kg ND 4100 2740 67 30-130 4-Chloroaniline ug/kg ND 4100 2490 61 28-130 4-Chlorophenylphenyl ether ug/kg ND 2050 1260 61 32-130 4-Nitroaniline ug/kg ND 4100 3040 74 30-130 4-Nitrophenol ug/kg ND 10300 8060 79 17-130 Acenaphthene ug/kg ND 2050 1270 62 29-130 Acenaphthylene ug/kg ND 2050 1290 63 31-130 Aniline ug/kg ND 2050 1110 54 10-130 Anthracene ug/kg ND 2050 1160 57 33-130 Benzo(a)anthracene ug/kg ND 2050 1290 63 32-130 Benzo(a)pyrene ug/kg ND 2050 1310 64 32-130 Benzo(b)fluoranthene ug/kg ND 2050 1310 64 33-130 Benzo(g,h,i)perylene ug/kg ND 2050 1160 57 28-130 Benzo(k)fluoranthene ug/kg ND 2050 1390 68 31-130 Benzoic Acid ug/kg ND 10300 5370 52 10-130 Benzyl alcohol ug/kg ND 4100 2560 62 31-130 bis(2-Chloroethoxy)methane ug/kg ND 2050 1250 61 30-130 bis(2-Chloroethyl) ether ug/kg ND 2050 1330 65 68-130 M1 bis(2-Ethylhexyl)phthalate ug/kg ND 2050 1220 59 40-130 Butylbenzylphthalate ug/kg ND 2050 1260 61 40-130 Chrysene ug/kg ND 2050 1370 67 30-130 Di-n-butylphthalate ug/kg ND 2050 1240 60 41-130 Di-n-octylphthalate ug/kg ND 2050 1260 61 42-130 Dibenz(a,h)anthracene ug/kg ND 2050 1160 57 27-130 Dibenzofuran ug/kg ND 2050 1330 65 32-130 Diethylphthalate ug/kg ND 2050 1340 66 40-130 Dimethylphthalate ug/kg ND 2050 1380 67 37-130 Fluoranthene ug/kg ND 2050 1380 67 26-130 Fluorene ug/kg ND 2050 1290 63 31-130 Hexachloro-1,3-butadiene ug/kg ND 2050 1140 55 20-130 Hexachlorobenzene ug/kg ND 2050 1220 59 29-130 Hexachlorocyclopentadiene ug/kg ND 2050 432 21 10-130 v3 Hexachloroethane ug/kg ND 2050 1130 55 21-130 Indeno(1,2,3-cd)pyrene ug/kg ND 2050 1190 58 28-130 Isophorone ug/kg ND 2050 1300 63 32-130 N-Nitroso-di-n-propylamine ug/kg ND 2050 1290 63 31-130 N-Nitrosodimethylamine ug/kg ND 2050 1280 62 20-130 N-Nitrosodiphenylamine ug/kg ND 2050 1230 60 32-130 Naphthalene ug/kg ND 2050 1200 59 30-130 Nitrobenzene ug/kg ND 2050 1330 65 25-130 Pentachlorophenol ug/kg ND 4100 2570 62 10-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:29 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 37 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Park Pointe Stockpile Pace Project No.: 92499338 MATRIX SPIKE SAMPLE: Parameter 3031500 Units 92499114004 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers Phenanthrene ug/kg ND 2050 1310 64 34-130 Phenol ug/kg ND 2050 1330 65 14-130 Pyrene ug/kg ND 2050 1280 62 31-130 Pyridine ug/kg ND 2050 339J 17 10-130 2,4,6-Tribromophenol (S) % 80 18-130 2-Fluorobiphenyl (S) % 67 19-130 2-Fluorophenol (S) % 70 18-130 Nitrobenzene-d5 (S) % 71 21-130 Phenol-d6 (S) % 73 18-130 Terphenyl-d14 (S) % 71 15-130 SAMPLE DUPLICATE: 3031501 Parameter Units 92499114005 Result Dup Result RPD Max RPD Qualifiers 1,2,4-Trichlorobenzene ug/kg ND ND 30 1,2-Dichlorobenzene ug/kg ND ND 30 1,3-Dichlorobenzene ug/kg ND ND 30 1,4-Dichlorobenzene ug/kg ND ND 30 1-Methylnaphthalene ug/kg ND ND 30 2,2'-Oxybis(1-chloropropane) ug/kg ND ND 30 2,4,5-Trichlorophenol ug/kg ND ND 30 2,4,6-Trichlorophenol ug/kg ND ND 30 2,4-Dichlorophenol ug/kg ND ND 30 2,4-Dimethylphenol ug/kg ND ND 30 2,4-Dinitrophenol ug/kg ND ND 30 2,4-Dinitrotoluene ug/kg ND ND 30 2,6-Dinitrotoluene ug/kg ND ND 30 2-Chloronaphthalene ug/kg ND ND 30 2-Chlorophenol ug/kg ND ND 30 2-Methylnaphthalene ug/kg ND ND 30 2-Methylphenol(o-Cresol) ug/kg ND ND 30 2-Nitroaniline ug/kg ND ND 30 2-Nitrophenol ug/kg ND ND 30 3&4-Methyl phenol (m&p Cresol) ug/kg ND ND 30 3,3'-Dichlorobenzidine ug/kg ND ND 30 3-Nitroaniline ug/kg ND ND 30 4,6-Dinitro-2-methyl phenol ug/kg ND ND 30 4-Bromophenylphenyl ether ug/kg ND ND 30 4-ChIoro-3-methyl phenol ug/kg ND ND 30 4-Chloroaniline ug/kg ND ND 30 4-Chlorophenylphenyl ether ug/kg ND ND 30 4-Nitroaniline ug/kg ND ND 30 4-Nitrophenol ug/kg ND ND 30 Acenaphthene ug/kg ND ND 30 Acenaphthylene ug/kg ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:29 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 37 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Park Pointe Stockpile Pace Project No.: 92499338 SAMPLE DUPLICATE: 3031501 Parameter Aniline Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Benzoic Acid Benzyl alcohol bis(2-Chloroethoxy)methane bis(2-Chloroethyl) ether bis(2-Ethylhexyl)phthalate Butylbenzylphthalate Chrysene Di-n-butylphthalate Di-n-octylphthalate Dibenz(a,h)anthracene Dibenzofuran Diethylphthalate Dimethylphthalate Fluoranthene Fluorene Hexachloro-1,3-butadiene Hexachlorobenzene Hexachlorocyclopentadiene Hexachloroethane Indeno(1,2,3-cd)pyrene Isophorone N-Nitroso-di-n-propylamine N-Nitrosodimethylamine N-Nitrosodiphenylamine Naphthalene Nitrobenzene Pentachlorophenol Phenanthrene Phenol Pyrene Pyridine 2,4,6-Tribromophenol (S) 2-Fluorobiphenyl (S) 2-Fluorophenol(S) Nitrobenzene-d5 (S) Phenol-d6 (S) Terphenyl-d14 (S) QUALITY CONTROL DATA Units 92499114005 Dup Result Result ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND % 65 % 59 72 74 73 % 51 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 68 60 65 69 68 55 Max RPD RPD 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 v2 30 30 30 30 30 30 30 30 30 30 30 30 30 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:29 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 37 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Park Pointe Stockpile Pace Project No.: 92499338 QC Batch: 571925 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92499338001, 92499338002 SAMPLE DUPLICATE: 3029273 92499338001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 18.6 11.2 50 25 D6 SAMPLE DUPLICATE: 3029274 92499230018 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 24.2 23.5 3 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:29 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 37 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Park Pointe Stockpile Pace Project No.: 92499338 QC Batch: 1561959 Analysis Method: SM 2540G QC Batch Method: SM 2540 G Analysis Description: Total Solids 2540 G-2011 Laboratory: Pace National - Mt. Juliet Associated Lab Samples: 92499338001 METHOD BLANK: R3583803-1 Associated Lab Samples: 92499338001 Parameter Units Total Solids % LABORATORY CONTROL SAMPLE: R3583803-2 Parameter Units Total Solids % Matrix: Solid Blank Reporting Result Limit MDL ND Spike LCS LCS Conc. Result % Rec 50.0 50.0 100 Analyzed Qualifiers 10/20/20 13:48 % Rec Limits Qualifiers 85.0-115 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:29 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 37 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Park Pointe Stockpile Pace Project No.: 92499338 QC Batch: 1559988 Analysis Method: EPA 7199 QC Batch Method: 3060A Analysis Description: Wet Chemistry 7199 Laboratory: Pace National - Mt. Juliet Associated Lab Samples: 92499338001 METHOD BLANK: R3583525-1 Matrix: Solid Associated Lab Samples: 92499338001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chromium, Hexavalent mg/kg ND 1.00 0.255 10/20/20 14:27 LABORATORY CONTROL SAMPLE: R3583525-2 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chromium, Hexavalent mg/kg 10.0 9.28 92.8 80.0-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: R3583525-4 R3583525-5 MS MSD L1273091-03 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chromium, Hexavalent mg/kg ND 22.7 22.7 14.9 15.0 65.7 66.0 75.0-125 0.530 20 ML MATRIX SPIKE SAMPLE: R3583525-6 L1273091-03 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Chromium, Hexavalent mg/kg ND 738 612 83.0 75.0-125 SAMPLE DUPLICATE: R3583525-8 L1274408-06 Dup Max Parameter Units Result Result RPD RPD Qualifiers Chromium, Hexavalent mg/kg ND ND 0.00 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:29 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 37 Pace Analytical Services, LLC lac, Analyilcal ® 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 www.pacelabs.com (704)875-9092 QUALIFIERS Project: Park Pointe Stockpile Pace Project No.: 92499338 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. ANALYTE QUALIFIERS BC The same analyte was detected in an associated blank at a concentration above 1/2 the reporting limit but below the laboratory reporting limit. C8 Result may be biased high due to carryover from previously analyzed sample. D6 The precision between the sample and sample duplicate exceeded laboratory control limits. IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. ML Matrix spike recovery and/or matrix spike duplicate recovery was below laboratory control limits. Result may be biased low. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:29 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 37 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Park Pointe Stockpile 92499338 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92499338001 SP-01 EPA 3050B 571871 EPA 6010D 572005 92499338002 DUP-SP EPA3050B 571871 EPA6010D 572005 92499338001 SP-01 EPA 7471 B 571881 EPA 7471 B 571992 92499338002 DUP-SP EPA 7471 B 571881 EPA 7471 B 571992 92499338001 SP-01 EPA 3546 572372 EPA 8270E 572465 92499338002 DUP-SP EPA 3546 572372 EPA 8270E 572465 92499338001 SP-01 EPA 5035A/5030B 571919 EPA 8260D 572075 92499338002 DUP-SP EPA 5035A/5030B 571919 EPA 8260D 572075 92499338001 SP-01 ASTM D2974-87 571925 92499338002 DUP-SP ASTM D2974-87 571925 92499338001 SP-01 SM 2540 G 1561959 SM 2540G 1561959 92499338001 SP-01 3060A 1559988 EPA 7199 1559988 Date: 10/27/2020 12:29 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 34 of 37 Document dame: I Document Revised: Fioruarl r. i�uia 5ampie Condition Upon Recaipt(SLUR) Pa e i of 2 aceAnatAcal' Document No.: issuing Authority: F.CAR-05-033-Rev.06 ?eicP Carolinas Quality Office Laboratory receiving samples; Asheville ❑ Etien[] Greenwood ❑ Hurttersviller; Raleigh❑ Mechanicsville❑ t Same.. , . Client Yarn W4# : 92499338 Upon Receiiot �t) 1AN Courier. ❑Fed Fx :]UPS ❑Ocher. []Client ❑ � Commercial aCe ❑ 92499338 l 1 1 II l 11 Dale/Inivals Person aamintngContents: r Paging Material: []Bubble Wrap Bubble Bags ❑None ❑ Other 31oioglcal Tlssu razen? 1 � ❑Yes ❑No N/A Thermometer: 92TO61 Type of Ice: wet ❑ague ❑None pIR Gun 10' !/1 1�, y Caaler Temp VP: ✓ r Carrettian Factor: Add/Subtract (°C) 0.0 Temp should De3balie freezing to o'C Cooler Tamp Corrected [°t ]: - ` Jam- ❑sampimorn of temp crite{la. Samples on ice, cooling process has begun USDA Regulated Soil �P 'N/A, water sample] r! d samples prig nate'n a quarantine zone within the United States: CA, NY, or SC (check maps}? Inc ;dingHaes aalI an z -am a `ico)? source {in C]NOtana!Sy, ❑Yes ❑No InciudingNawall and Puerto Rico)? ❑Ys ❑No Cornmenis/Dlscrenancv: Chain of Custody Present? Vfis []No ❑N/A 1 1. Samples Arrived within Hoid Time? Yes []No ❑NIA 2. Short Hold Time Analysis {02 hr.)? 6Y.es ❑]Na ❑N/A D• Rush Turn Around Time Requested? ❑Yes C&. []NIA 4. Sufficient Volume? y s ❑No ❑N/A 5. Correct Conminers Used? Yes ❑Na ❑N(A 6- -Pace Containers Used?,/yes ❑No ❑N/A Containers Intact? eyes []NO ©N/A 7. Dissolved analysis: Samples Field filtered? ❑yes o ❑NIA S. sample Labels Match CDC? es []No ❑N/A 9. -Incfudes 17ateirime/ID/Analysis Matrix: VV ! Headspace in VOA Vials >5-6mm)? (Dyes []NO Trip Blank Present? ❑Yes ❑No NIA 1}• Trio Blank Custody 5eals Present? Dyes [)NO .rN/A COMMENTS/5AMPL'c DISCREPANCY Lot iO of spilt containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Reylew: Project Manager SiRF Review: Date/Time: Date: Date: Fleid data Required? ❑Yes ::]NO Page 35 of 37 p Sample Condition Upon Recelpt(SCLJR) Page I of 2 "C Anaar Document No.: Issuing Authority: f-GAR-0-033-Rev.06 ?ace Carolinas Quality Office "Check maffk top haiif of box if pad ands/or dechlorination Is Project, WO# : 92499338 verified and within the acceptance range for preservation PM: TIH Due Date: 10/13/20 Samples. Exceptions; VC7A, Cokiform, i OC, Oil and Grease, ORC)/9015 (water) COC, iLLHS CLIENT: 92—MID ATLAN **90ttorn half of box is to list number Df battle z? V y Y a Y a � �t y v yG T O�y dZ z `a IS c U - rr1 ' rNDaO Z 2 a C l.r N y a �_ V% a ui y _1 2 79c7Ea QQ E v �+ Q `m J E Q7. v C E E 16 C E i 6 5 c E O >_ _ 5 0 p O CN �q ^J O _ �, :R N _ = N = N O 'T o fl N I Q eq InN N ``7le N N ,-, Q I1I1 O n m I"F-a. 6 a t7 LS In C7 ,Na L7 C1 l7 t7 l7 t7 7 O a a LM 4 g a 3 Em 3 a a a a a a o a 7 0 a i m m „ a 2 111 3 I� 5NN 1 6 i i NN 7 � i I L NNI 8 � 9 toN N N N I N pH Adjustment Log for Preserved Samples Sample M Tytpe of ➢reservative pH upon recelpt Date preservation adiusted Time preserntlon Amount of Preservative Lot A 81 1 added Note! Wheneeerthere �s a discrepaner affecting North Carolina compliance samples, a capV of this form mill be -:ant to the North Carolina DEH14R Certification Office (Le. Out of hold, Incorrect preservative, out of temp, incorrect containers. Page 36 of 37 U� Mix) l�eluj saidweg O o E a!oo0 po G_ °z paleas c c $ A alsn IN(A) a 'y - ¢ LN ao! C j 2 uO pan!aaOH -17 (N1),) eui)oW0 jenp!saa d O 0 ul dMi so a 1. z F N a U. � a m � i+ c 66LL may0 xaH slelea V210'8 a cy rn n E S H OOAS OL69 a E411 PN,A 09Z9 11 ;sel ee13rSlr3uy a laylO glaueylayy C� "J £OZSZeN aa)) HOeN Vt\ IOH e @ o N c � V £ONH 9 E # a 60SZH w z m m° u 'o n paAmaldun .� t J 52f3 NIV1N0D30# n c G U Q a M M N0I13311071V MR1 9ldWVS W F C7 a 4 05 y C) J 1 Z Val zLU Lu W F i C.)O 7 Z z F o W z z s a r y (Ul m m a Ul w c a a 5 -24 IdW00=0 BVbJ=J) 3dA13ldWVs a a 2 sepoa P!!an eac) 300o Xi lI1VW 7 E ua) a 0 E m a d o v Z Q o T m v uoallo3¢o� u a N 19 a a U a' S a a u ¢S� m a rN- z ❑ x 7 0 c u. a ` o V LV (} u H; $ J `umE 0 Q. p N F 0 4> c 'E 'T € U E2 A V G c a� a eLL v m (/j E 0 l o p W N a i Z Y y c c N c c E a m o # W31.1L N r) .! u� m e- co w o r r r N r ix Page 37 o 37 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 October 27, 2020 Katie Lippard Mid -Atlantic Associates 409 Rogers View Ct. Raleigh, NC 27610 RE: Project: PARK POINT GRASS AREA Pace Project No.: 92499316 Dear Katie Lippard: Enclosed are the analytical results for sample(s) received by the laboratory on October 06, 2020. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace National - Mt. Juliet • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Tyriek Hooks tyriek.hooks@pacelabs.com (704)875-9092 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 45 lacieAnalyfica(' www,pacelabs.com Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: PARK POINT GRASS AREA Pace Project No.: 92499316 Pace Analytical Services National 12065 Lebanon Road, Mt. Juliet, TN 37122 Alabama Certification #: 40660 Alaska Certification 17-026 Arizona Certification #: AZ0612 Arkansas Certification #: 88-0469 California Certification #: 2932 Canada Certification #: 1461.01 Colorado Certification #: TN00003 Connecticut Certification #: PH-0197 DOD Certification: #1461.01 EPA# TN00003 Florida Certification #: E87487 Georgia DW Certification #: 923 Georgia Certification: NELAP Idaho Certification #: TN00003 Illinois Certification #: 200008 Indiana Certification #: C-TN-01 Iowa Certification #: 364 Kansas Certification #: E-10277 Kentucky UST Certification #: 16 Kentucky Certification #: 90010 Louisiana Certification #: A130792 Louisiana DW Certification #: LA180010 Maine Certification #: TN0002 Maryland Certification #: 324 Massachusetts Certification #: M-TNO03 Michigan Certification #: 9958 Minnesota Certification #: 047-999-395 Mississippi Certification #: TN00003 Missouri Certification #: 340 Montana Certification M CERT0086 Nebraska Certification #: NE-OS-15-05 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS Nevada Certification #: TN-03-2002-34 New Hampshire Certification #: 2975 New Jersey Certification #: TNO02 New Mexico DW Certification New York Certification #: 11742 North Carolina Aquatic Toxicity Certification #: 41 North Carolina Drinking Water Certification #: 21704 North Carolina Environmental Certificate #: 375 North Dakota Certification #: R-140 Ohio VAP Certification #: CL0069 Oklahoma Certification #: 9915 Oregon Certification #: TN200002 Pennsylvania Certification #: 68-02979 Rhode Island Certification #: LA000356 South Carolina Certification #: 84004 South Dakota Certification Tennessee DW/Chem/Micro Certification #: 2006 Texas Certification #: T 104704245-17-14 Texas Mold Certification #: LAB0152 USDA Soil Permit #: P330-15-00234 Utah Certification #: TN00003 Vermont Dept. of Health: ID# VT-2006 Virginia Certification #: VT2006 Virginia Certification #: 460132 Washington Certification #: C847 West Virginia Certification #: 233 Wisconsin Certification #: 998093910 Wyoming UST Certification #: via A21-A 2926.01 A21-A-ISO 17025 Certification #: 1461.01 A21-A-ISO 17025 Certification #: 1461.02 AIHA-LAP/LLC EMLAP Certification #:100789 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: PARK POINT GRASS AREA Pace Project No.: 92499316 Lab ID Sample ID Matrix Date Collected Date Received 92499316001 PP-GA-1 Solid 10/06/2010:15 10/06/2016:43 92499316002 PP-GA-2 Solid 10/06/2010:20 10/06/2016:43 92499316003 PP-GA-3 Solid 10/06/2010:25 10/06/2016:43 92499316004 PP-GA-4 Solid 10/06/2010:30 10/06/2016:43 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: PARK POINT GRASS AREA Pace Project No.: 92499316 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92499316001 PP-GA-1 EPA 6010D IDS, RDT 7 PASI-A EPA 7471 B SOO 1 PASI-A EPA 8270E BPJ 75 PASI-C EPA 8260D CL 70 PASI-C ASTM D2974-87 KDF 1 PASI-C SM 2540G KBC 1 PAN EPA 7199 GB 1 PAN 92499316002 PP-GA-2 EPA 6010D IDS, RDT 7 PASI-A EPA 7471 B SOO 1 PASI-A EPA 8270E BPJ 75 PASI-C EPA 8260D CL 70 PASI-C ASTM D2974-87 KDF 1 PASI-C 92499316003 PP-GA-3 EPA 6010D IDS, RDT 7 PASI-A EPA 7471 B SOO 1 PASI-A EPA 8270E BPJ 75 PASI-C EPA 8260D CL 70 PASI-C ASTM D2974-87 KDF 1 PASI-C 92499316004 PP-GA-4 EPA 6010D IDS, RDT 7 PASI-A EPA 7471 B SOO 1 PASI-A EPA 8270E BPJ 75 PASI-C EPA 8260D CL 70 PASI-C ASTM D2974-87 KDF 1 PASI-C PAN = Pace National - Mt. Juliet PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: PARK POINT GRASS AREA Pace Project No.: 92499316 Sample: PP-GA-1 Lab ID: 92499316001 Collected: 10/06/20 10:15 Received: 10/06/20 16:43 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3050B Pace Analytical Services -Asheville Arsenic 4.8 mg/kg 1.0 0.50 1 10/08/20 15:31 10/11/2019:58 7440-38-2 BC Barium 166 mg/kg 0.50 0.25 1 10/08/20 15:31 10/11/20 01:57 7440-39-3 Cadmium 0.13 mg/kg 0.10 0.050 1 10/08/20 15:31 10/11/2019:58 7440-43-9 Chromium 33.9 mg/kg 0.50 0.25 1 10/08/20 15:31 10/11/20 01:57 7440-47-3 Lead 14.9 mg/kg 0.50 0.25 1 10/08/20 15:31 10/11/2019:58 7439-92-1 Selenium 0.83J mg/kg 1.0 0.50 1 10/08/20 15:31 10/11/20 01:57 7782-49-2 Silver ND mg/kg 0.50 0.25 1 10/08/20 15:31 10/11/20 01:57 7440-22-4 7471 Mercury Analytical Method: EPA 7471 B Preparation Method: EPA 7471 B Pace Analytical Services -Asheville Mercury 0.0043J mg/kg 0.0056 0.0043 1 10/08/2019:54 10/09/2011:54 7439-97-6 8270E MSSV Microwave Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte Acenaphthene ND ug/kg 406 105 1 10/10/20 14:17 10/12/20 11:12 83-32-9 Acenaphthylene ND ug/kg 406 96.2 1 10/10/20 14:17 10/12/20 11:12 208-96-8 Aniline ND ug/kg 406 91.3 1 10/10/20 14:17 10/12/20 11:12 62-53-3 Anthracene ND ug/kg 406 105 1 10/10/20 14:17 10/12/20 11:12 120-12-7 Benzo(a)anthracene ND ug/kg 406 129 1 10/10/20 14:17 10/12/20 11:12 56-55-3 Benzo(a)pyrene ND ug/kg 406 176 1 10/10/20 14:17 10/12/20 11:12 50-32-8 Benzo(b)fluoranthene ND ug/kg 406 164 1 10/10/20 14:17 10/12/20 11:12 205-99-2 Benzo(g,h,i)perylene ND ug/kg 406 159 1 10/10/20 14:17 10/12/20 11:12 191-24-2 Benzo(k)fluoranthene ND ug/kg 406 171 1 10/10/20 14:17 10/12/20 11:12 207-08-9 Benzoic Acid ND ug/kg 2030 438 1 10/10/20 14:17 10/12/20 11:12 65-85-0 Benzyl alcohol ND ug/kg 813 216 1 10/10/20 14:17 10/12/20 11:12 100-51-6 4-Bromophenylphenyl ether ND ug/kg 406 107 1 10/10/20 14:17 10/12/20 11:12 101-55-3 Butylbenzylphthalate ND ug/kg 406 108 1 10/10/20 14:17 10/12/20 11:12 85-68-7 4-ChIoro-3-methyl phenol ND ug/kg 813 248 1 10/10/20 14:17 10/12/20 11:12 59-50-7 4-Chloroaniline ND ug/kg 813 249 1 10/10/20 14:17 10/12/20 11:12 106-47-8 bis(2-Chloroethoxy)methane ND ug/kg 406 109 1 10/10/20 14:17 10/12/20 11:12 111-91-1 bis(2-Chloroethyl) ether ND ug/kg 406 86.3 1 10/10/20 14:17 10/12/20 11:12 111-44-4 2-Chloronaphthalene ND ug/kg 406 90.5 1 10/10/20 14:17 10/12/20 11:12 91-58-7 2-Chlorophenol ND ug/kg 406 94.6 1 10/10/20 14:17 10/12/20 11:12 95-57-8 4-Chlorophenylphenyl ether ND ug/kg 406 106 1 10/10/20 14:17 10/12/20 11:12 7005-72-3 Chrysene ND ug/kg 406 118 1 10/10/20 14:17 10/12/20 11:12 218-01-9 Dibenz(a,h)anthracene ND ug/kg 406 163 1 10/10/20 14:17 10/12/20 11:12 53-70-3 Dibenzofuran ND ug/kg 406 102 1 10/10/20 14:17 10/12/20 11:12 132-64-9 1,2-Dichlorobenzene ND ug/kg 406 87.9 1 10/10/20 14:17 10/12/20 11:12 95-50-1 1,3-Dichlorobenzene ND ug/kg 406 91.5 1 10/10/20 14:17 10/12/20 11:12 541-73-1 1,4-Dichlorobenzene ND ug/kg 406 89.4 1 10/10/20 14:17 10/12/20 11:12 106-46-7 3,3'-Dichlorobenzidine ND ug/kg 813 283 1 10/10/20 14:17 10/12/20 11:12 91-94-1 2,4-Dichlorophenol ND ug/kg 406 134 1 10/10/20 14:17 10/12/20 11:12 120-83-2 Diethylphthalate ND ug/kg 406 88.2 1 10/10/20 14:17 10/12/20 11:12 84-66-2 2,4-Dimethylphenol ND ug/kg 406 101 1 10/10/20 14:17 10/12/20 11:12 105-67-9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: PARK POINT GRASS AREA Pace Project No.: 92499316 Sample: PP-GA-1 Lab ID: 92499316001 Collected: 10/06/20 10:15 Received: 10/06/20 16:43 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8270E MSSV Microwave Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte Dimethylphthalate ND ug/kg 406 91.9 1 10/10/20 14:17 10/12/20 11:12 131-11-3 Di-n-butylphthalate ND ug/kg 406 100 1 10/10/20 14:17 10/12/20 11:12 84-74-2 4,6-Dinitro-2-methyl phenol ND ug/kg 813 655 1 10/10/20 14:17 10/12/20 11:12 534-52-1 2,4-Dinitrophenol ND ug/kg 2030 1300 1 10/10/20 14:17 10/12/20 11:12 51-28-5 2,4-Dinitrotoluene ND ug/kg 406 108 1 10/10/20 14:17 10/12/20 11:12 121-14-2 2,6-Dinitrotoluene ND ug/kg 406 106 1 10/10/20 14:17 10/12/20 11:12 606-20-2 Di-n-octylphthalate ND ug/kg 406 232 1 10/10/20 14:17 10/12/20 11:12 117-84-0 bis(2- Ethyl hexyl)phthalate ND ug/kg 406 133 1 10/10/20 14:17 10/12/20 11:12 117-81-7 Fluoranthene ND ug/kg 406 123 1 10/10/20 14:17 10/12/20 11:12 206-44-0 Fluorene ND ug/kg 406 109 1 10/10/20 14:17 10/12/20 11:12 86-73-7 Hexachloro-1,3-butadiene ND ug/kg 406 98.8 1 10/10/20 14:17 10/12/20 11:12 87-68-3 Hexachlorobenzene ND ug/kg 406 103 1 10/10/20 14:17 10/12/20 11:12 118-74-1 Hexachlorocyclopentadiene ND ug/kg 406 163 1 10/10/20 14:17 10/12/20 11:12 77-47-4 v2 Hexachloroethane ND ug/kg 406 92.6 1 10/10/20 14:17 10/12/20 11:12 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/kg 406 186 1 10/10/20 14:17 10/12/20 11:12 193-39-5 Isophorone ND ug/kg 406 88.3 1 10/10/20 14:17 10/12/20 11:12 78-59-1 1-Methylnaphthalene ND ug/kg 406 108 1 10/10/20 14:17 10/12/20 11:12 90-12-0 2-Methylnaphthalene ND ug/kg 406 103 1 10/10/20 14:17 10/12/20 11:12 91-57-6 2-Methylphenol(o-Cresol) ND ug/kg 406 90.0 1 10/10/20 14:17 10/12/20 11:12 95-48-7 3&4-Methyl phenol (m&p Cresol) ND ug/kg 406 102 1 10/10/20 14:17 10/12/20 11:12 15831-10-4 Naphthalene ND ug/kg 406 97.3 1 10/10/20 14:17 10/12/20 11:12 91-20-3 2-Nitroaniline ND ug/kg 2030 204 1 10/10/20 14:17 10/12/20 11:12 88-74-4 3-Nitroaniline ND ug/kg 2030 216 1 10/10/20 14:17 10/12/20 11:12 99-09-2 4-Nitroaniline ND ug/kg 813 201 1 10/10/20 14:17 10/12/20 11:12 100-01-6 Nitrobenzene ND ug/kg 406 97.1 1 10/10/20 14:17 10/12/20 11:12 98-95-3 2-Nitrophenol ND ug/kg 406 126 1 10/10/20 14:17 10/12/20 11:12 88-75-5 4-Nitrophenol ND ug/kg 2030 648 1 10/10/20 14:17 10/12/20 11:12 100-02-7 N-Nitrosodimethylamine ND ug/kg 406 114 1 10/10/20 14:17 10/12/20 11:12 62-75-9 N-Nitroso-di-n-propylamine ND ug/kg 406 114 1 10/10/20 14:17 10/12/20 11:12 621-64-7 N-Nitrosodiphenylamine ND ug/kg 406 104 1 10/10/20 14:17 10/12/20 11:12 86-30-6 2,2'-Oxybis(1-chloropropane) ND ug/kg 406 113 1 10/10/20 14:17 10/12/20 11:12 108-60-1 Pentachlorophenol ND ug/kg 813 186 1 10/10/20 14:17 10/12/20 11:12 87-86-5 Phenanthrene ND ug/kg 406 102 1 10/10/20 14:17 10/12/20 11:12 85-01-8 Phenol ND ug/kg 406 97.1 1 10/10/20 14:17 10/12/20 11:12 108-95-2 Pyrene ND ug/kg 406 112 1 10/10/20 14:17 10/12/20 11:12 129-00-0 Pyridine ND ug/kg 406 103 1 10/10/20 14:17 10/12/20 11:12 110-86-1 1,2,4-Trichlorobenzene ND ug/kg 406 93.1 1 10/10/20 14:17 10/12/20 11:12 120-82-1 2,4,5-Trichlorophenol ND ug/kg 406 106 1 10/10/20 14:17 10/12/20 11:12 95-95-4 2,4,6-Trichlorophenol ND ug/kg 406 102 1 10/10/20 14:17 10/12/20 11:12 88-06-2 Surrogates Nitrobenzene-d5 (S) 73 % 21-130 1 10/10/20 14:17 10/12/20 11:12 4165-60-0 2-Fluorobiphenyl (S) 46 % 19-130 1 10/10/20 14:17 10/12/20 11:12 321-60-8 Terphenyl-d14 (S) 78 % 15-130 1 10/10/20 14:17 10/12/20 11:12 1718-51-0 Phenol-d6 (S) 67 % 18-130 1 10/10/20 14:17 10/12/20 11:12 13127-88-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: PARK POINT GRASS AREA Pace Project No.: 92499316 Sample: PP-GA-1 Lab ID: 92499316001 Collected: 10/06/20 10:15 Received: 10/06/20 16:43 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8270E MSSV Microwave Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte Surrogates 2-Fluorophenol (S) 66 % 18-130 1 10/10/20 14:17 10/12/20 11:12 367-12-4 2,4,6-Tribromophenol (S) 61 % 18-130 1 10/10/20 14:17 10/12/20 11:12 118-79-6 8260D/5035A/5030B Volatiles Analytical Method: EPA 8260D Preparation Method: EPA 5035A/503013 Pace Analytical Services - Charlotte Acetone ND ug/kg 181 67.5 1 10/08/20 16:38 10/09/20 12:54 67-64-1 Benzene ND ug/kg 9.1 6.4 1 10/08/20 16:38 10/09/20 12:54 71-43-2 Bromobenzene ND ug/kg 9.1 6.1 1 10/08/20 16:38 10/09/20 12:54 108-86-1 Bromochloromethane ND ug/kg 9.1 6.9 1 10/08/20 16:38 10/09/20 12:54 74-97-5 Bromodichloromethane ND ug/kg 9.1 5.9 1 10/08/20 16:38 10/09/20 12:54 75-27-4 Bromoform ND ug/kg 9.1 4.9 1 10/08/20 16:38 10/09/20 12:54 75-25-2 Bromomethane ND ug/kg 18.1 14.2 1 10/08/20 16:38 10/09/20 12:54 74-83-9 2-Butanone (MEK) ND ug/kg 181 76.8 1 10/08/20 16:38 10/09/20 12:54 78-93-3 n-Butylbenzene ND ug/kg 9.1 4.9 1 10/08/20 16:38 10/09/20 12:54 104-51-8 sec-Butylbenzene ND ug/kg 9.1 5.7 1 10/08/20 16:38 10/09/20 12:54 135-98-8 tert-Butyl benzene ND ug/kg 9.1 4.9 1 10/08/20 16:38 10/09/20 12:54 98-06-6 Carbon tetrachloride ND ug/kg 9.1 4.0 1 10/08/20 16:38 10/09/20 12:54 56-23-5 Chlorobenzene ND ug/kg 9.1 5.9 1 10/08/20 16:38 10/09/20 12:54 108-90-7 Chloroethane ND ug/kg 18.1 9.6 1 10/08/20 16:38 10/09/20 12:54 75-00-3 Chloroform ND ug/kg 9.1 4.5 1 10/08/20 16:38 10/09/20 12:54 67-66-3 Chloromethane ND ug/kg 18.1 12.7 1 10/08/20 16:38 10/09/20 12:54 74-87-3 2-Chlorotoluene ND ug/kg 9.1 6.4 1 10/08/20 16:38 10/09/20 12:54 95-49-8 4-Chlorotoluene ND ug/kg 9.1 5.8 1 10/08/20 16:38 10/09/20 12:54 106-43-4 1,2-Dibromo-3-chloropropane ND ug/kg 9.1 8.4 1 10/08/20 16:38 10/09/20 12:54 96-12-8 Dibromochloromethane ND ug/kg 9.1 4.9 1 10/08/20 16:38 10/09/20 12:54 124-48-1 1,2-Dibromoethane (EDB) ND ug/kg 9.1 6.4 1 10/08/20 16:38 10/09/20 12:54 106-93-4 Dibromomethane ND ug/kg 9.1 4.5 1 10/08/20 16:38 10/09/20 12:54 74-95-3 1,2-Dichlorobenzene ND ug/kg 9.1 5.4 1 10/08/20 16:38 10/09/20 12:54 95-50-1 1,3-Dichlorobenzene ND ug/kg 9.1 7.5 1 10/08/20 16:38 10/09/20 12:54 541-73-1 1,4-Dichlorobenzene ND ug/kg 9.1 6.8 1 10/08/20 16:38 10/09/20 12:54 106-46-7 Dichlorodifluoromethane ND ug/kg 18.1 3.1 1 10/08/20 16:38 10/09/20 12:54 75-71-8 1,1-Dichloroethane ND ug/kg 9.1 4.0 1 10/08/20 16:38 10/09/20 12:54 75-34-3 1,2-Dichloroethane ND ug/kg 9.1 3.7 1 10/08/20 16:38 10/09/20 12:54 107-06-2 1,1-Dichloroethene ND ug/kg 9.1 2.8 1 10/08/20 16:38 10/09/20 12:54 75-35-4 cis-1,2-Dichloroethene ND ug/kg 9.1 5.2 1 10/08/20 16:38 10/09/20 12:54 156-59-2 trans-1,2-Dichloroethene ND ug/kg 9.1 3.9 1 10/08/20 16:38 10/09/20 12:54 156-60-5 1,2-Dichloropropane ND ug/kg 9.1 5.6 1 10/08/20 16:38 10/09/20 12:54 78-87-5 1,3-Dichloropropane ND ug/kg 9.1 6.3 1 10/08/20 16:38 10/09/20 12:54 142-28-9 2,2-Dichloropropane ND ug/kg 9.1 5.0 1 10/08/20 16:38 10/09/20 12:54 594-20-7 1,1-Dichloropropene ND ug/kg 9.1 4.3 1 10/08/20 16:38 10/09/20 12:54 563-58-6 cis-1,3-Dichloropropene ND ug/kg 9.1 5.9 1 10/08/20 16:38 10/09/20 12:54 10061-01-5 trans- 1,3-Dichloropropene ND ug/kg 9.1 7.7 1 10/08/20 16:38 10/09/20 12:54 10061-02-6 Diisopropyl ether ND ug/kg 9.1 3.7 1 10/08/20 16:38 10/09/20 12:54 108-20-3 REPORT OF LABORATORY ANALYSIS v2 IK This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: PARK POINT GRASS AREA Pace Project No.: 92499316 Sample: PP-GA-1 Lab ID: 92499316001 Collected: 10/06/20 10:15 Received: 10/06/20 16:43 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters 8260D/5035A/5030B Volatiles Ethylbenzene Hexachloro-1,3-butadiene 2-Hexanone Isopropylbenzene (Cumene) p-Isopropyltoluene Methylene Chloride 4-Methyl-2-pentanone (MIBK) Methyl-tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates Toluene-d8 (S) 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Percent Moisture Percent Moisture Total Solids 2540 G-2011 Total Solids Results Units PQL MDL DF Prepared Analyzed CAS No. Qual Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte ND ug/kg 9.1 8.5 1 10/08/2016:38 10/09/2012:54 100-41-4 ND ug/kg 9.1 8.6 1 10/08/2016:38 10/09/2012:54 87-68-3 ND ug/kg 90.5 18.0 1 10/08/2016:38 10/09/2012:54 591-78-6 ND ug/kg 9.1 5.7 1 10/08/2016:38 10/09/2012:54 98-82-8 ND ug/kg 9.1 5.0 1 10/08/2016:38 10/09/2012:54 99-87-6 ND ug/kg 36.2 13.4 1 10/08/2016:38 10/09/2012:54 75-09-2 ND ug/kg 90.5 76.6 1 10/08/2016:38 10/09/2012:54 108-10-1 ND ug/kg 9.1 5.8 1 10/08/2016:38 10/09/2012:54 1634-04-4 ND ug/kg 9.1 5.1 1 10/08/2016:38 10/09/2012:54 91-20-3 ND ug/kg 9.1 6.2 1 10/08/2016:38 10/09/2012:54 103-65-1 ND ug/kg 9.1 4.3 1 10/08/2016:38 10/09/2012:54 100-42-5 ND ug/kg 9.1 6.0 1 10/08/2016:38 10/09/2012:54 630-20-6 ND ug/kg 9.1 8.0 1 10/08/2016:38 10/09/2012:54 79-34-5 ND ug/kg 9.1 4.5 1 10/08/2016:38 10/09/2012:54 127-18-4 ND ug/kg 9.1 5.2 1 10/08/2016:38 10/09/2012:54 108-88-3 ND ug/kg 9.1 5.5 1 10/08/2016:38 10/09/2012:54 87-61-6 ND ug/kg 9.1 5.1 1 10/08/2016:38 10/09/2012:54 120-82-1 ND ug/kg 9.1 3.7 1 10/08/2016:38 10/09/2012:54 71-55-6 ND ug/kg 9.1 6.7 1 10/08/2016:38 10/09/2012:54 79-00-5 ND ug/kg 9.1 5.6 1 10/08/2016:38 10/09/2012:54 79-01-6 ND ug/kg 9.1 2.2 1 10/08/2016:38 10/09/2012:54 75-69-4 ND ug/kg 9.1 7.4 1 10/08/2016:38 10/09/2012:54 96-18-4 ND ug/kg 9.1 6.5 1 10/08/2016:38 10/09/2012:54 95-63-6 ND ug/kg 9.1 5.4 1 10/08/2016:38 10/09/2012:54 108-67-8 ND ug/kg 90.5 7.8 1 10/08/2016:38 10/09/2012:54 108-05-4 ND ug/kg 18.1 3.5 1 10/08/2016:38 10/09/2012:54 75-01-4 ND ug/kg 18.1 5.2 1 10/08/2016:38 10/09/2012:54 1330-20-7 ND ug/kg 18.1 13.9 1 10/08/2016:38 10/09/2012:54 179601-23-1 ND ug/kg 9.1 5.2 1 10/08/2016:38 10/09/2012:54 95-47-6 101 % 70-130 1 10/08/2016:38 10/09/2012:54 2037-26-5 101 % 70-130 1 10/08/2016:38 10/09/2012:54 460-00-4 108 % 70-132 1 10/08/2016:38 10/09/2012:54 17060-07-0 Analytical Method: ASTM D2974-87 Pace Analytical Services - Charlotte 17.4 % 0.10 0.10 1 Analytical Method: SM 2540G Preparation Method: SM 2540 G Pace National - Mt. Juliet 82.0 % 10/08/20 13:24 1 10/20/20 13:39 10/20/20 13:48 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: PARK POINT GRASS AREA Pace Project No.: 92499316 Sample: PP-GA-1 Lab ID: 92499316001 Collected: 10/06/20 10:15 Received: 10/06/20 16:43 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual Wet Chemistry 7199 Analytical Method: EPA 7199 Preparation Method: 3060A Pace National - Mt. Juliet Chromium, Hexavalent ND mg/kg 1.22 0.311 1 10/19/20 19:19 10/20/20 16:11 18540-29-9 Date: 10/27/2020 12:33 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: PARK POINT GRASS AREA Pace Project No.: 92499316 Sample: PP-GA-2 Lab ID: 92499316002 Collected: 10/06/20 10:20 Received: 10/06/20 16:43 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3050B Pace Analytical Services -Asheville Arsenic 2.8 mg/kg 0.92 0.46 1 10/08/20 15:31 10/11/20 20:01 7440-38-2 BC Barium 123 mg/kg 0.46 0.23 1 10/08/20 15:31 10/11/20 02:00 7440-39-3 Cadmium 0.077J mg/kg 0.092 0.046 1 10/08/20 15:31 10/11/20 20:01 7440-43-9 Chromium 11.5 mg/kg 0.46 0.23 1 10/08/20 15:31 10/11/20 02:00 7440-47-3 Lead 15.5 mg/kg 0.46 0.23 1 10/08/20 15:31 10/11/20 20:01 7439-92-1 Selenium 0.55J mg/kg 0.92 0.46 1 10/08/20 15:31 10/11/20 02:00 7782-49-2 Silver ND mg/kg 0.46 0.23 1 10/08/20 15:31 10/11/20 02:00 7440-22-4 7471 Mercury Analytical Method: EPA 7471 B Preparation Method: EPA 7471 B Pace Analytical Services -Asheville Mercury 0.0041J mg/kg 0.0045 0.0035 1 10/08/2019:54 10/09/2012:01 7439-97-6 8270E MSSV Microwave Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte Acenaphthene ND ug/kg 385 99.1 1 10/10/20 14:17 10/12/20 11:39 83-32-9 Acenaphthylene ND ug/kg 385 91.2 1 10/10/20 14:17 10/12/20 11:39 208-96-8 Aniline ND ug/kg 385 86.5 1 10/10/20 14:17 10/12/20 11:39 62-53-3 Anthracene ND ug/kg 385 100 1 10/10/20 14:17 10/12/20 11:39 120-12-7 Benzo(a)anthracene ND ug/kg 385 123 1 10/10/20 14:17 10/12/20 11:39 56-55-3 Benzo(a)pyrene ND ug/kg 385 167 1 10/10/20 14:17 10/12/20 11:39 50-32-8 Benzo(b)fluoranthene ND ug/kg 385 155 1 10/10/20 14:17 10/12/20 11:39 205-99-2 Benzo(g,h,i)perylene ND ug/kg 385 151 1 10/10/20 14:17 10/12/20 11:39 191-24-2 Benzo(k)fluoranthene ND ug/kg 385 162 1 10/10/20 14:17 10/12/20 11:39 207-08-9 Benzoic Acid ND ug/kg 1930 416 1 10/10/20 14:17 10/12/20 11:39 65-85-0 Benzyl alcohol ND ug/kg 771 204 1 10/10/20 14:17 10/12/20 11:39 100-51-6 4-Bromophenylphenyl ether ND ug/kg 385 101 1 10/10/20 14:17 10/12/20 11:39 101-55-3 Butylbenzylphthalate ND ug/kg 385 103 1 10/10/20 14:17 10/12/20 11:39 85-68-7 4-ChIoro-3-methyl phenol ND ug/kg 771 235 1 10/10/20 14:17 10/12/20 11:39 59-50-7 4-Chloroaniline ND ug/kg 771 236 1 10/10/20 14:17 10/12/20 11:39 106-47-8 bis(2-Chloroethoxy)methane ND ug/kg 385 103 1 10/10/20 14:17 10/12/20 11:39 111-91-1 bis(2-Chloroethyl) ether ND ug/kg 385 81.9 1 10/10/20 14:17 10/12/20 11:39 111-44-4 2-Chloronaphthalene ND ug/kg 385 85.8 1 10/10/20 14:17 10/12/20 11:39 91-58-7 2-Chlorophenol ND ug/kg 385 89.7 1 10/10/20 14:17 10/12/20 11:39 95-57-8 4-Chlorophenylphenyl ether ND ug/kg 385 100 1 10/10/20 14:17 10/12/20 11:39 7005-72-3 Chrysene ND ug/kg 385 112 1 10/10/20 14:17 10/12/20 11:39 218-01-9 Dibenz(a,h)anthracene ND ug/kg 385 154 1 10/10/20 14:17 10/12/20 11:39 53-70-3 Dibenzofuran ND ug/kg 385 96.3 1 10/10/20 14:17 10/12/20 11:39 132-64-9 1,2-Dichlorobenzene ND ug/kg 385 83.4 1 10/10/20 14:17 10/12/20 11:39 95-50-1 1,3-Dichlorobenzene ND ug/kg 385 86.8 1 10/10/20 14:17 10/12/20 11:39 541-73-1 1,4-Dichlorobenzene ND ug/kg 385 84.8 1 10/10/20 14:17 10/12/20 11:39 106-46-7 3,3'-Dichlorobenzidine ND ug/kg 771 269 1 10/10/20 14:17 10/12/20 11:39 91-94-1 2,4-Dichlorophenol ND ug/kg 385 127 1 10/10/20 14:17 10/12/20 11:39 120-83-2 Diethylphthalate ND ug/kg 385 83.6 1 10/10/20 14:17 10/12/20 11:39 84-66-2 2,4-Dimethylphenol ND ug/kg 385 96.0 1 10/10/20 14:17 10/12/20 11:39 105-67-9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: PARK POINT GRASS AREA Pace Project No.: 92499316 Sample: PP-GA-2 Lab ID: 92499316002 Collected: 10/06/20 10:20 Received: 10/06/20 16:43 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8270E MSSV Microwave Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte Dimethylphthalate ND ug/kg 385 87.1 1 10/10/20 14:17 10/12/20 11:39 131-11-3 Di-n-butylphthalate ND ug/kg 385 95.1 1 10/10/20 14:17 10/12/20 11:39 84-74-2 4,6-Dinitro-2-methyl phenol ND ug/kg 771 621 1 10/10/20 14:17 10/12/20 11:39 534-52-1 2,4-Dinitrophenol ND ug/kg 1930 1230 1 10/10/20 14:17 10/12/20 11:39 51-28-5 2,4-Dinitrotoluene ND ug/kg 385 102 1 10/10/20 14:17 10/12/20 11:39 121-14-2 2,6-Dinitrotoluene ND ug/kg 385 101 1 10/10/20 14:17 10/12/20 11:39 606-20-2 Di-n-octylphthalate ND ug/kg 385 220 1 10/10/20 14:17 10/12/20 11:39 117-84-0 bis(2- Ethyl hexyl)phthalate ND ug/kg 385 126 1 10/10/20 14:17 10/12/20 11:39 117-81-7 Fluoranthene ND ug/kg 385 116 1 10/10/20 14:17 10/12/20 11:39 206-44-0 Fluorene ND ug/kg 385 103 1 10/10/20 14:17 10/12/20 11:39 86-73-7 Hexachloro-1,3-butadiene ND ug/kg 385 93.7 1 10/10/20 14:17 10/12/20 11:39 87-68-3 Hexachlorobenzene ND ug/kg 385 97.9 1 10/10/20 14:17 10/12/20 11:39 118-74-1 Hexachlorocyclopentadiene ND ug/kg 385 154 1 10/10/20 14:17 10/12/20 11:39 77-47-4 v2 Hexachloroethane ND ug/kg 385 87.8 1 10/10/20 14:17 10/12/20 11:39 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/kg 385 176 1 10/10/20 14:17 10/12/20 11:39 193-39-5 Isophorone ND ug/kg 385 83.7 1 10/10/20 14:17 10/12/20 11:39 78-59-1 1-Methylnaphthalene ND ug/kg 385 103 1 10/10/20 14:17 10/12/20 11:39 90-12-0 2-Methylnaphthalene ND ug/kg 385 98.1 1 10/10/20 14:17 10/12/20 11:39 91-57-6 2-Methylphenol(o-Cresol) ND ug/kg 385 85.4 1 10/10/20 14:17 10/12/20 11:39 95-48-7 3&4-Methyl phenol (m&p Cresol) ND ug/kg 385 96.9 1 10/10/20 14:17 10/12/20 11:39 15831-10-4 Naphthalene ND ug/kg 385 92.3 1 10/10/20 14:17 10/12/20 11:39 91-20-3 2-Nitroaniline ND ug/kg 1930 194 1 10/10/20 14:17 10/12/20 11:39 88-74-4 3-Nitroaniline ND ug/kg 1930 204 1 10/10/20 14:17 10/12/20 11:39 99-09-2 4-Nitroaniline ND ug/kg 771 190 1 10/10/20 14:17 10/12/20 11:39 100-01-6 Nitrobenzene ND ug/kg 385 92.0 1 10/10/20 14:17 10/12/20 11:39 98-95-3 2-Nitrophenol ND ug/kg 385 119 1 10/10/20 14:17 10/12/20 11:39 88-75-5 4-Nitrophenol ND ug/kg 1930 614 1 10/10/20 14:17 10/12/20 11:39 100-02-7 N-Nitrosodimethylamine ND ug/kg 385 108 1 10/10/20 14:17 10/12/20 11:39 62-75-9 N-Nitroso-di-n-propylamine ND ug/kg 385 108 1 10/10/20 14:17 10/12/20 11:39 621-64-7 N-Nitrosodiphenylamine ND ug/kg 385 98.3 1 10/10/20 14:17 10/12/20 11:39 86-30-6 2,2'-Oxybis(1-chloropropane) ND ug/kg 385 107 1 10/10/20 14:17 10/12/20 11:39 108-60-1 Pentachlorophenol ND ug/kg 771 176 1 10/10/20 14:17 10/12/20 11:39 87-86-5 Phenanthrene ND ug/kg 385 97.0 1 10/10/20 14:17 10/12/20 11:39 85-01-8 Phenol ND ug/kg 385 92.0 1 10/10/20 14:17 10/12/20 11:39 108-95-2 Pyrene ND ug/kg 385 106 1 10/10/20 14:17 10/12/20 11:39 129-00-0 Pyridine ND ug/kg 385 97.5 1 10/10/20 14:17 10/12/20 11:39 110-86-1 1,2,4-Trichlorobenzene ND ug/kg 385 88.3 1 10/10/20 14:17 10/12/20 11:39 120-82-1 2,4,5-Trichlorophenol ND ug/kg 385 100 1 10/10/20 14:17 10/12/20 11:39 95-95-4 2,4,6-Trichlorophenol ND ug/kg 385 96.8 1 10/10/20 14:17 10/12/20 11:39 88-06-2 Surrogates Nitrobenzene-d5 (S) 77 % 21-130 1 10/10/20 14:17 10/12/20 11:39 4165-60-0 2-Fluorobiphenyl (S) 49 % 19-130 1 10/10/20 14:17 10/12/20 11:39 321-60-8 Terphenyl-d14 (S) 90 % 15-130 1 10/10/20 14:17 10/12/20 11:39 1718-51-0 Phenol-d6 (S) 74 % 18-130 1 10/10/20 14:17 10/12/20 11:39 13127-88-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: PARK POINT GRASS AREA Pace Project No.: 92499316 Sample: PP-GA-2 Lab ID: 92499316002 Collected: 10/06/20 10:20 Received: 10/06/20 16:43 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8270E MSSV Microwave Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte Surrogates 2-Fluorophenol (S) 70 % 18-130 1 10/10/20 14:17 10/12/20 11:39 367-12-4 2,4,6-Tribromophenol (S) 62 % 18-130 1 10/10/20 14:17 10/12/20 11:39 118-79-6 8260D/5035A/5030B Volatiles Analytical Method: EPA 8260D Preparation Method: EPA 5035A/503013 Pace Analytical Services - Charlotte Acetone ND ug/kg 187 69.8 1 10/08/20 16:38 10/09/20 13:11 67-64-1 Benzene ND ug/kg 9.4 6.6 1 10/08/20 16:38 10/09/20 13:11 71-43-2 Bromobenzene ND ug/kg 9.4 6.3 1 10/08/20 16:38 10/09/20 13:11 108-86-1 Bromochloromethane ND ug/kg 9.4 7.1 1 10/08/20 16:38 10/09/20 13:11 74-97-5 Bromodichloromethane ND ug/kg 9.4 6.1 1 10/08/20 16:38 10/09/20 13:11 75-27-4 Bromoform ND ug/kg 9.4 5.1 1 10/08/20 16:38 10/09/20 13:11 75-25-2 Bromomethane ND ug/kg 18.7 14.7 1 10/08/20 16:38 10/09/20 13:11 74-83-9 2-Butanone (MEK) ND ug/kg 187 79.3 1 10/08/20 16:38 10/09/20 13:11 78-93-3 n-Butylbenzene ND ug/kg 9.4 5.1 1 10/08/20 16:38 10/09/20 13:11 104-51-8 sec-Butylbenzene ND ug/kg 9.4 5.9 1 10/08/20 16:38 10/09/20 13:11 135-98-8 tert-Butyl benzene ND ug/kg 9.4 5.0 1 10/08/20 16:38 10/09/20 13:11 98-06-6 Carbon tetrachloride ND ug/kg 9.4 4.2 1 10/08/20 16:38 10/09/20 13:11 56-23-5 Chlorobenzene ND ug/kg 9.4 6.1 1 10/08/20 16:38 10/09/20 13:11 108-90-7 Chloroethane ND ug/kg 18.7 9.9 1 10/08/20 16:38 10/09/20 13:11 75-00-3 Chloroform ND ug/kg 9.4 4.6 1 10/08/20 16:38 10/09/20 13:11 67-66-3 Chloromethane ND ug/kg 18.7 13.1 1 10/08/20 16:38 10/09/20 13:11 74-87-3 2-Chlorotoluene ND ug/kg 9.4 6.7 1 10/08/20 16:38 10/09/20 13:11 95-49-8 4-Chlorotoluene ND ug/kg 9.4 6.0 1 10/08/20 16:38 10/09/20 13:11 106-43-4 1,2-Dibromo-3-chloropropane ND ug/kg 9.4 8.7 1 10/08/20 16:38 10/09/20 13:11 96-12-8 Dibromochloromethane ND ug/kg 9.4 5.0 1 10/08/20 16:38 10/09/20 13:11 124-48-1 1,2-Dibromoethane (EDB) ND ug/kg 9.4 6.6 1 10/08/20 16:38 10/09/20 13:11 106-93-4 Dibromomethane ND ug/kg 9.4 4.7 1 10/08/20 16:38 10/09/20 13:11 74-95-3 1,2-Dichlorobenzene ND ug/kg 9.4 5.5 1 10/08/20 16:38 10/09/20 13:11 95-50-1 1,3-Dichlorobenzene ND ug/kg 9.4 7.7 1 10/08/20 16:38 10/09/20 13:11 541-73-1 1,4-Dichlorobenzene ND ug/kg 9.4 7.0 1 10/08/20 16:38 10/09/20 13:11 106-46-7 Dichlorodifluoromethane ND ug/kg 18.7 3.2 1 10/08/20 16:38 10/09/20 13:11 75-71-8 1,1-Dichloroethane ND ug/kg 9.4 4.1 1 10/08/20 16:38 10/09/20 13:11 75-34-3 1,2-Dichloroethane ND ug/kg 9.4 3.8 1 10/08/20 16:38 10/09/20 13:11 107-06-2 1,1-Dichloroethene ND ug/kg 9.4 2.9 1 10/08/20 16:38 10/09/20 13:11 75-35-4 cis-1,2-Dichloroethene ND ug/kg 9.4 5.4 1 10/08/20 16:38 10/09/20 13:11 156-59-2 trans-1,2-Dichloroethene ND ug/kg 9.4 4.1 1 10/08/20 16:38 10/09/20 13:11 156-60-5 1,2-Dichloropropane ND ug/kg 9.4 5.8 1 10/08/20 16:38 10/09/20 13:11 78-87-5 1,3-Dichloropropane ND ug/kg 9.4 6.5 1 10/08/20 16:38 10/09/20 13:11 142-28-9 2,2-Dichloropropane ND ug/kg 9.4 5.1 1 10/08/20 16:38 10/09/20 13:11 594-20-7 1,1-Dichloropropene ND ug/kg 9.4 4.5 1 10/08/20 16:38 10/09/20 13:11 563-58-6 cis-1,3-Dichloropropene ND ug/kg 9.4 6.1 1 10/08/20 16:38 10/09/20 13:11 10061-01-5 trans- 1,3-Dichloropropene ND ug/kg 9.4 7.9 1 10/08/20 16:38 10/09/20 13:11 10061-02-6 Diisopropyl ether ND ug/kg 9.4 3.8 1 10/08/20 16:38 10/09/20 13:11 108-20-3 REPORT OF LABORATORY ANALYSIS v2 IK M1 M1 This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: PARK POINT GRASS AREA Pace Project No.: 92499316 Sample: PP-GA-2 Lab ID: 92499316002 Collected: 10/06/20 10:20 Received: 10/06/20 16:43 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters 8260D/5035A/5030B Volatiles Ethylbenzene Hexachloro-1,3-butadiene 2-Hexanone Isopropylbenzene (Cumene) p-Isopropyltoluene Methylene Chloride 4-Methyl-2-pentanone (MIBK) Methyl-tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates Toluene-d8 (S) 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Percent Moisture Percent Moisture Results Units PQL MDL DF Prepared Analyzed CAS No. Qual Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte ND ug/kg 9.4 8.8 1 10/08/2016:38 10/09/2013:11 100-41-4 ND ug/kg 9.4 8.9 1 10/08/2016:38 10/09/2013:11 87-68-3 ND ug/kg 93.5 18.6 1 10/08/2016:38 10/09/2013:11 591-78-6 ND ug/kg 9.4 5.9 1 10/08/2016:38 10/09/2013:11 98-82-8 ND ug/kg 9.4 5.2 1 10/08/2016:38 10/09/2013:11 99-87-6 ND ug/kg 37.4 13.9 1 10/08/2016:38 10/09/2013:11 75-09-2 ND ug/kg 93.5 79.1 1 10/08/2016:38 10/09/2013:11 108-10-1 ND ug/kg 9.4 6.0 1 10/08/2016:38 10/09/2013:11 1634-04-4 ND ug/kg 9.4 5.3 1 10/08/2016:38 10/09/2013:11 91-20-3 ND ug/kg 9.4 6.5 1 10/08/2016:38 10/09/2013:11 103-65-1 ND ug/kg 9.4 4.4 1 10/08/2016:38 10/09/2013:11 100-42-5 ND ug/kg 9.4 6.2 1 10/08/2016:38 10/09/2013:11 630-20-6 ND ug/kg 9.4 8.3 1 10/08/2016:38 10/09/2013:11 79-34-5 ND ug/kg 9.4 4.6 1 10/08/2016:38 10/09/2013:11 127-18-4 ND ug/kg 9.4 5.4 1 10/08/2016:38 10/09/2013:11 108-88-3 ND ug/kg 9.4 5.7 1 10/08/2016:38 10/09/2013:11 87-61-6 ND ug/kg 9.4 5.2 1 10/08/2016:38 10/09/2013:11 120-82-1 ND ug/kg 9.4 3.8 1 10/08/2016:38 10/09/2013:11 71-55-6 ND ug/kg 9.4 7.0 1 10/08/2016:38 10/09/2013:11 79-00-5 ND ug/kg 9.4 5.8 1 10/08/2016:38 10/09/2013:11 79-01-6 ND ug/kg 9.4 2.3 1 10/08/2016:38 10/09/2013:11 75-69-4 ND ug/kg 9.4 7.6 1 10/08/2016:38 10/09/2013:11 96-18-4 ND ug/kg 9.4 6.7 1 10/08/2016:38 10/09/2013:11 95-63-6 ND ug/kg 9.4 5.6 1 10/08/2016:38 10/09/2013:11 108-67-8 ND ug/kg 93.5 8.1 1 10/08/2016:38 10/09/2013:11 108-05-4 ND ug/kg 18.7 3.6 1 10/08/2016:38 10/09/2013:11 75-01-4 ND ug/kg 18.7 5.3 1 10/08/2016:38 10/09/2013:11 1330-20-7 ND ug/kg 18.7 14.4 1 10/08/2016:38 10/09/2013:11 179601-23-1 ND ug/kg 9.4 5.3 1 10/08/2016:38 10/09/2013:11 95-47-6 99 % 70-130 1 10/08/2016:38 10/09/2013:11 2037-26-5 100 % 70-130 1 10/08/2016:38 10/09/2013:11 460-00-4 106 % 70-132 1 10/08/2016:38 10/09/2013:11 17060-07-0 Analytical Method: ASTM D2974-87 Pace Analytical Services - Charlotte 13.8 % 0.10 0.10 1 REPORT OF LABORATORY ANALYSIS 10/08/20 13:24 This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: PARK POINT GRASS AREA Pace Project No.: 92499316 Sample: PP-GA-3 Lab ID: 92499316003 Collected: 10/06/20 10:25 Received: 10/06/20 16:43 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3050B Pace Analytical Services -Asheville Arsenic 3.8 mg/kg 1.0 0.51 1 10/08/20 15:31 10/11/20 20:29 7440-38-2 BC Barium 280 mg/kg 0.51 0.25 1 10/08/20 15:31 10/11/20 02:04 7440-39-3 Cadmium 0.14 mg/kg 0.10 0.051 1 10/08/20 15:31 10/11/20 20:29 7440-43-9 Chromium 23.8 mg/kg 0.51 0.25 1 10/08/20 15:31 10/11/20 02:04 7440-47-3 Lead 14.0 mg/kg 0.51 0.25 1 10/08/20 15:31 10/11/20 20:29 7439-92-1 Selenium 0.69J mg/kg 1.0 0.51 1 10/08/20 15:31 10/11/20 02:04 7782-49-2 Silver ND mg/kg 0.51 0.25 1 10/08/20 15:31 10/11/20 02:04 7440-22-4 7471 Mercury Analytical Method: EPA 7471 B Preparation Method: EPA 7471 B Pace Analytical Services -Asheville Mercury 0.0088 mg/kg 0.0053 0.0041 1 10/08/2019:54 10/09/2012:08 7439-97-6 8270E MSSV Microwave Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte Acenaphthene ND ug/kg 416 107 1 10/10/20 14:17 10/12/20 12:06 83-32-9 Acenaphthylene ND ug/kg 416 98.5 1 10/10/20 14:17 10/12/20 12:06 208-96-8 Aniline ND ug/kg 416 93.4 1 10/10/20 14:17 10/12/20 12:06 62-53-3 Anthracene ND ug/kg 416 108 1 10/10/20 14:17 10/12/20 12:06 120-12-7 Benzo(a)anthracene ND ug/kg 416 132 1 10/10/20 14:17 10/12/20 12:06 56-55-3 Benzo(a)pyrene ND ug/kg 416 180 1 10/10/20 14:17 10/12/20 12:06 50-32-8 Benzo(b)fluoranthene ND ug/kg 416 168 1 10/10/20 14:17 10/12/20 12:06 205-99-2 Benzo(g,h,i)perylene ND ug/kg 416 163 1 10/10/20 14:17 10/12/20 12:06 191-24-2 Benzo(k)fluoranthene ND ug/kg 416 175 1 10/10/20 14:17 10/12/20 12:06 207-08-9 Benzoic Acid ND ug/kg 2080 449 1 10/10/20 14:17 10/12/20 12:06 65-85-0 Benzyl alcohol ND ug/kg 832 221 1 10/10/20 14:17 10/12/20 12:06 100-51-6 4-Bromophenylphenyl ether ND ug/kg 416 109 1 10/10/20 14:17 10/12/20 12:06 101-55-3 Butylbenzylphthalate ND ug/kg 416 ill 1 10/10/20 14:17 10/12/20 12:06 85-68-7 4-ChIoro-3-methyl phenol ND ug/kg 832 253 1 10/10/20 14:17 10/12/20 12:06 59-50-7 4-Chloroaniline ND ug/kg 832 255 1 10/10/20 14:17 10/12/20 12:06 106-47-8 bis(2-Chloroethoxy)methane ND ug/kg 416 ill 1 10/10/20 14:17 10/12/20 12:06 111-91-1 bis(2-Chloroethyl) ether ND ug/kg 416 88.4 1 10/10/20 14:17 10/12/20 12:06 111-44-4 2-Chloronaphthalene ND ug/kg 416 92.7 1 10/10/20 14:17 10/12/20 12:06 91-58-7 2-Chlorophenol ND ug/kg 416 96.8 1 10/10/20 14:17 10/12/20 12:06 95-57-8 4-Chlorophenylphenyl ether ND ug/kg 416 108 1 10/10/20 14:17 10/12/20 12:06 7005-72-3 Chrysene ND ug/kg 416 121 1 10/10/20 14:17 10/12/20 12:06 218-01-9 Dibenz(a,h)anthracene ND ug/kg 416 166 1 10/10/20 14:17 10/12/20 12:06 53-70-3 Dibenzofuran ND ug/kg 416 104 1 10/10/20 14:17 10/12/20 12:06 132-64-9 1,2-Dichlorobenzene ND ug/kg 416 90.0 1 10/10/20 14:17 10/12/20 12:06 95-50-1 1,3-Dichlorobenzene ND ug/kg 416 93.7 1 10/10/20 14:17 10/12/20 12:06 541-73-1 1,4-Dichlorobenzene ND ug/kg 416 91.5 1 10/10/20 14:17 10/12/20 12:06 106-46-7 3,3'-Dichlorobenzidine ND ug/kg 832 290 1 10/10/20 14:17 10/12/20 12:06 91-94-1 2,4-Dichlorophenol ND ug/kg 416 137 1 10/10/20 14:17 10/12/20 12:06 120-83-2 Diethylphthalate ND ug/kg 416 90.3 1 10/10/20 14:17 10/12/20 12:06 84-66-2 2,4-Dimethylphenol ND ug/kg 416 104 1 10/10/20 14:17 10/12/20 12:06 105-67-9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: PARK POINT GRASS AREA Pace Project No.: 92499316 Sample: PP-GA-3 Lab ID: 92499316003 Collected: 10/06/20 10:25 Received: 10/06/20 16:43 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8270E MSSV Microwave Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte Dimethylphthalate ND ug/kg 416 94.0 1 10/10/20 14:17 10/12/20 12:06 131-11-3 Di-n-butylphthalate ND ug/kg 416 103 1 10/10/20 14:17 10/12/20 12:06 84-74-2 4,6-Dinitro-2-methyl phenol ND ug/kg 832 671 1 10/10/20 14:17 10/12/20 12:06 534-52-1 2,4-Dinitrophenol ND ug/kg 2080 1330 1 10/10/20 14:17 10/12/20 12:06 51-28-5 2,4-Dinitrotoluene ND ug/kg 416 110 1 10/10/20 14:17 10/12/20 12:06 121-14-2 2,6-Dinitrotoluene ND ug/kg 416 109 1 10/10/20 14:17 10/12/20 12:06 606-20-2 Di-n-octylphthalate ND ug/kg 416 237 1 10/10/20 14:17 10/12/20 12:06 117-84-0 bis(2- Ethyl hexyl)phthalate ND ug/kg 416 136 1 10/10/20 14:17 10/12/20 12:06 117-81-7 Fluoranthene ND ug/kg 416 126 1 10/10/20 14:17 10/12/20 12:06 206-44-0 Fluorene ND ug/kg 416 ill 1 10/10/20 14:17 10/12/20 12:06 86-73-7 Hexachloro-1,3-butadiene ND ug/kg 416 101 1 10/10/20 14:17 10/12/20 12:06 87-68-3 Hexachlorobenzene ND ug/kg 416 106 1 10/10/20 14:17 10/12/20 12:06 118-74-1 Hexachlorocyclopentadiene ND ug/kg 416 166 1 10/10/20 14:17 10/12/20 12:06 77-47-4 v2 Hexachloroethane ND ug/kg 416 94.8 1 10/10/20 14:17 10/12/20 12:06 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/kg 416 190 1 10/10/20 14:17 10/12/20 12:06 193-39-5 Isophorone ND ug/kg 416 90.4 1 10/10/20 14:17 10/12/20 12:06 78-59-1 1-Methylnaphthalene ND ug/kg 416 ill 1 10/10/20 14:17 10/12/20 12:06 90-12-0 2-Methylnaphthalene ND ug/kg 416 106 1 10/10/20 14:17 10/12/20 12:06 91-57-6 2-Methylphenol(o-Cresol) ND ug/kg 416 92.1 1 10/10/20 14:17 10/12/20 12:06 95-48-7 3&4-Methyl phenol (m&p Cresol) ND ug/kg 416 105 1 10/10/20 14:17 10/12/20 12:06 15831-10-4 Naphthalene ND ug/kg 416 99.6 1 10/10/20 14:17 10/12/20 12:06 91-20-3 2-Nitroaniline ND ug/kg 2080 209 1 10/10/20 14:17 10/12/20 12:06 88-74-4 3-Nitroaniline ND ug/kg 2080 221 1 10/10/20 14:17 10/12/20 12:06 99-09-2 4-Nitroaniline ND ug/kg 832 205 1 10/10/20 14:17 10/12/20 12:06 100-01-6 Nitrobenzene ND ug/kg 416 99.3 1 10/10/20 14:17 10/12/20 12:06 98-95-3 2-Nitrophenol ND ug/kg 416 129 1 10/10/20 14:17 10/12/20 12:06 88-75-5 4-Nitrophenol ND ug/kg 2080 663 1 10/10/20 14:17 10/12/20 12:06 100-02-7 N-Nitrosodimethylamine ND ug/kg 416 117 1 10/10/20 14:17 10/12/20 12:06 62-75-9 N-Nitroso-di-n-propylamine ND ug/kg 416 116 1 10/10/20 14:17 10/12/20 12:06 621-64-7 N-Nitrosodiphenylamine ND ug/kg 416 106 1 10/10/20 14:17 10/12/20 12:06 86-30-6 2,2'-Oxybis(1-chloropropane) ND ug/kg 416 116 1 10/10/20 14:17 10/12/20 12:06 108-60-1 Pentachlorophenol ND ug/kg 832 190 1 10/10/20 14:17 10/12/20 12:06 87-86-5 Phenanthrene ND ug/kg 416 105 1 10/10/20 14:17 10/12/20 12:06 85-01-8 Phenol ND ug/kg 416 99.3 1 10/10/20 14:17 10/12/20 12:06 108-95-2 Pyrene ND ug/kg 416 114 1 10/10/20 14:17 10/12/20 12:06 129-00-0 Pyridine ND ug/kg 416 105 1 10/10/20 14:17 10/12/20 12:06 110-86-1 1,2,4-Trichlorobenzene ND ug/kg 416 95.3 1 10/10/20 14:17 10/12/20 12:06 120-82-1 2,4,5-Trichlorophenol ND ug/kg 416 108 1 10/10/20 14:17 10/12/20 12:06 95-95-4 2,4,6-Trichlorophenol ND ug/kg 416 105 1 10/10/20 14:17 10/12/20 12:06 88-06-2 Surrogates Nitrobenzene-d5 (S) 68 % 21-130 1 10/10/20 14:17 10/12/20 12:06 4165-60-0 2-Fluorobiphenyl (S) 44 % 19-130 1 10/10/20 14:17 10/12/20 12:06 321-60-8 Terphenyl-dl4 (S) 76 % 15-130 1 10/10/20 14:17 10/12/20 12:06 1718-51-0 Phenol-d6 (S) 65 % 18-130 1 10/10/20 14:17 10/12/20 12:06 13127-88-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: PARK POINT GRASS AREA Pace Project No.: 92499316 Sample: PP-GA-3 Lab ID: 92499316003 Collected: 10/06/20 10:25 Received: 10/06/20 16:43 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8270E MSSV Microwave Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte Surrogates 2-Fluorophenol (S) 64 % 18-130 1 10/10/20 14:17 10/12/20 12:06 367-12-4 2,4,6-Tribromophenol (S) 61 % 18-130 1 10/10/20 14:17 10/12/20 12:06 118-79-6 8260D/5035A/5030B Volatiles Analytical Method: EPA 8260D Preparation Method: EPA 5035A/503013 Pace Analytical Services - Charlotte Acetone ND ug/kg 187 69.8 1 10/08/20 16:38 10/09/20 13:29 67-64-1 Benzene ND ug/kg 9.4 6.6 1 10/08/20 16:38 10/09/20 13:29 71-43-2 Bromobenzene ND ug/kg 9.4 6.3 1 10/08/20 16:38 10/09/20 13:29 108-86-1 Bromochloromethane ND ug/kg 9.4 7.1 1 10/08/20 16:38 10/09/20 13:29 74-97-5 Bromodichloromethane ND ug/kg 9.4 6.1 1 10/08/20 16:38 10/09/20 13:29 75-27-4 Bromoform ND ug/kg 9.4 5.0 1 10/08/20 16:38 10/09/20 13:29 75-25-2 Bromomethane ND ug/kg 18.7 14.7 1 10/08/20 16:38 10/09/20 13:29 74-83-9 2-Butanone (MEK) ND ug/kg 187 79.3 1 10/08/20 16:38 10/09/20 13:29 78-93-3 n-Butylbenzene ND ug/kg 9.4 5.1 1 10/08/20 16:38 10/09/20 13:29 104-51-8 sec-Butylbenzene ND ug/kg 9.4 5.9 1 10/08/20 16:38 10/09/20 13:29 135-98-8 tert-Butyl benzene ND ug/kg 9.4 5.0 1 10/08/20 16:38 10/09/20 13:29 98-06-6 Carbon tetrachloride ND ug/kg 9.4 4.2 1 10/08/20 16:38 10/09/20 13:29 56-23-5 Chlorobenzene ND ug/kg 9.4 6.1 1 10/08/20 16:38 10/09/20 13:29 108-90-7 Chloroethane ND ug/kg 18.7 9.9 1 10/08/20 16:38 10/09/20 13:29 75-00-3 Chloroform ND ug/kg 9.4 4.6 1 10/08/20 16:38 10/09/20 13:29 67-66-3 Chloromethane ND ug/kg 18.7 13.1 1 10/08/20 16:38 10/09/20 13:29 74-87-3 2-Chlorotoluene ND ug/kg 9.4 6.7 1 10/08/20 16:38 10/09/20 13:29 95-49-8 4-Chlorotoluene ND ug/kg 9.4 6.0 1 10/08/20 16:38 10/09/20 13:29 106-43-4 1,2-Dibromo-3-chloropropane ND ug/kg 9.4 8.7 1 10/08/20 16:38 10/09/20 13:29 96-12-8 Dibromochloromethane ND ug/kg 9.4 5.0 1 10/08/20 16:38 10/09/20 13:29 124-48-1 1,2-Dibromoethane (EDB) ND ug/kg 9.4 6.6 1 10/08/20 16:38 10/09/20 13:29 106-93-4 Dibromomethane ND ug/kg 9.4 4.7 1 10/08/20 16:38 10/09/20 13:29 74-95-3 1,2-Dichlorobenzene ND ug/kg 9.4 5.5 1 10/08/20 16:38 10/09/20 13:29 95-50-1 1,3-Dichlorobenzene ND ug/kg 9.4 7.7 1 10/08/20 16:38 10/09/20 13:29 541-73-1 1,4-Dichlorobenzene ND ug/kg 9.4 7.0 1 10/08/20 16:38 10/09/20 13:29 106-46-7 Dichlorodifluoromethane ND ug/kg 18.7 3.2 1 10/08/20 16:38 10/09/20 13:29 75-71-8 1,1-Dichloroethane ND ug/kg 9.4 4.1 1 10/08/20 16:38 10/09/20 13:29 75-34-3 1,2-Dichloroethane ND ug/kg 9.4 3.8 1 10/08/20 16:38 10/09/20 13:29 107-06-2 1,1-Dichloroethene ND ug/kg 9.4 2.9 1 10/08/20 16:38 10/09/20 13:29 75-35-4 cis-1,2-Dichloroethene ND ug/kg 9.4 5.3 1 10/08/20 16:38 10/09/20 13:29 156-59-2 trans-1,2-Dichloroethene ND ug/kg 9.4 4.1 1 10/08/20 16:38 10/09/20 13:29 156-60-5 1,2-Dichloropropane ND ug/kg 9.4 5.8 1 10/08/20 16:38 10/09/20 13:29 78-87-5 1,3-Dichloropropane ND ug/kg 9.4 6.5 1 10/08/20 16:38 10/09/20 13:29 142-28-9 2,2-Dichloropropane ND ug/kg 9.4 5.1 1 10/08/20 16:38 10/09/20 13:29 594-20-7 1,1-Dichloropropene ND ug/kg 9.4 4.5 1 10/08/20 16:38 10/09/20 13:29 563-58-6 cis-1,3-Dichloropropene ND ug/kg 9.4 6.1 1 10/08/20 16:38 10/09/20 13:29 10061-01-5 trans- 1,3-Dichloropropene ND ug/kg 9.4 7.9 1 10/08/20 16:38 10/09/20 13:29 10061-02-6 Diisopropyl ether ND ug/kg 9.4 3.8 1 10/08/20 16:38 10/09/20 13:29 108-20-3 REPORT OF LABORATORY ANALYSIS v2 IK This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: PARK POINT GRASS AREA Pace Project No.: 92499316 Sample: PP-GA-3 Lab ID: 92499316003 Collected: 10/06/20 10:25 Received: 10/06/20 16:43 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters 8260D/5035A/5030B Volatiles Ethylbenzene Hexachloro-1,3-butadiene 2-Hexanone Isopropylbenzene (Cumene) p-Isopropyltoluene Methylene Chloride 4-Methyl-2-pentanone (MIBK) Methyl-tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates Toluene-d8 (S) 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Percent Moisture Percent Moisture Results Units PQL MDL DF Prepared Analyzed CAS No. Qual Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte ND ug/kg 9.4 8.8 1 10/08/2016:38 10/09/2013:29 100-41-4 ND ug/kg 9.4 8.9 1 10/08/2016:38 10/09/2013:29 87-68-3 ND ug/kg 93.5 18.6 1 10/08/2016:38 10/09/2013:29 591-78-6 ND ug/kg 9.4 5.9 1 10/08/2016:38 10/09/2013:29 98-82-8 ND ug/kg 9.4 5.2 1 10/08/2016:38 10/09/2013:29 99-87-6 ND ug/kg 37.4 13.9 1 10/08/2016:38 10/09/2013:29 75-09-2 ND ug/kg 93.5 79.1 1 10/08/2016:38 10/09/2013:29 108-10-1 ND ug/kg 9.4 6.0 1 10/08/2016:38 10/09/2013:29 1634-04-4 ND ug/kg 9.4 5.3 1 10/08/2016:38 10/09/2013:29 91-20-3 ND ug/kg 9.4 6.5 1 10/08/2016:38 10/09/2013:29 103-65-1 ND ug/kg 9.4 4.4 1 10/08/2016:38 10/09/2013:29 100-42-5 ND ug/kg 9.4 6.2 1 10/08/2016:38 10/09/2013:29 630-20-6 ND ug/kg 9.4 8.2 1 10/08/2016:38 10/09/2013:29 79-34-5 ND ug/kg 9.4 4.6 1 10/08/2016:38 10/09/2013:29 127-18-4 ND ug/kg 9.4 5.3 1 10/08/2016:38 10/09/2013:29 108-88-3 ND ug/kg 9.4 5.7 1 10/08/2016:38 10/09/2013:29 87-61-6 ND ug/kg 9.4 5.2 1 10/08/2016:38 10/09/2013:29 120-82-1 ND ug/kg 9.4 3.8 1 10/08/2016:38 10/09/2013:29 71-55-6 ND ug/kg 9.4 7.0 1 10/08/2016:38 10/09/2013:29 79-00-5 ND ug/kg 9.4 5.8 1 10/08/2016:38 10/09/2013:29 79-01-6 ND ug/kg 9.4 2.3 1 10/08/2016:38 10/09/2013:29 75-69-4 ND ug/kg 9.4 7.6 1 10/08/2016:38 10/09/2013:29 96-18-4 ND ug/kg 9.4 6.7 1 10/08/2016:38 10/09/2013:29 95-63-6 ND ug/kg 9.4 5.6 1 10/08/2016:38 10/09/2013:29 108-67-8 ND ug/kg 93.5 8.1 1 10/08/2016:38 10/09/2013:29 108-05-4 ND ug/kg 18.7 3.6 1 10/08/2016:38 10/09/2013:29 75-01-4 ND ug/kg 18.7 5.3 1 10/08/2016:38 10/09/2013:29 1330-20-7 ND ug/kg 18.7 14.4 1 10/08/2016:38 10/09/2013:29 179601-23-1 ND ug/kg 9.4 5.3 1 10/08/2016:38 10/09/2013:29 95-47-6 102 % 70-130 1 10/08/2016:38 10/09/2013:29 2037-26-5 100 % 70-130 1 10/08/2016:38 10/09/2013:29 460-00-4 105 % 70-132 1 10/08/2016:38 10/09/2013:29 17060-07-0 Analytical Method: ASTM D2974-87 Pace Analytical Services - Charlotte 19.6 % 0.10 0.10 1 REPORT OF LABORATORY ANALYSIS 10/08/20 13:24 This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: PARK POINT GRASS AREA Pace Project No.: 92499316 Sample: PP-GA-4 Lab ID: 92499316004 Collected: 10/06/20 10:30 Received: 10/06/20 16:43 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3050B Pace Analytical Services -Asheville Arsenic 4.1 mg/kg 0.99 0.50 1 10/08/20 15:31 10/11/20 20:32 7440-38-2 BC Barium 122 mg/kg 0.50 0.25 1 10/08/20 15:31 10/11/20 02:07 7440-39-3 Cadmium 0.092J mg/kg 0.099 0.050 1 10/08/20 15:31 10/11/20 20:32 7440-43-9 Chromium 18.1 mg/kg 0.50 0.25 1 10/08/20 15:31 10/11/20 02:07 7440-47-3 Lead 11.9 mg/kg 0.50 0.25 1 10/08/20 15:31 10/11/20 20:32 7439-92-1 Selenium 0.76J mg/kg 0.99 0.50 1 10/08/20 15:31 10/11/20 02:07 7782-49-2 Silver ND mg/kg 0.50 0.25 1 10/08/20 15:31 10/11/20 02:07 7440-22-4 7471 Mercury Analytical Method: EPA 7471 B Preparation Method: EPA 7471 B Pace Analytical Services -Asheville Mercury 0.0072 mg/kg 0.0053 0.0041 1 10/08/2019:54 10/09/2012:11 7439-97-6 8270E MSSV Microwave Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte Acenaphthene ND ug/kg 427 110 1 10/10/20 14:17 10/12/20 12:33 83-32-9 Acenaphthylene ND ug/kg 427 101 1 10/10/20 14:17 10/12/20 12:33 208-96-8 Aniline ND ug/kg 427 95.8 1 10/10/20 14:17 10/12/20 12:33 62-53-3 Anthracene ND ug/kg 427 ill 1 10/10/20 14:17 10/12/20 12:33 120-12-7 Benzo(a)anthracene ND ug/kg 427 136 1 10/10/20 14:17 10/12/20 12:33 56-55-3 Benzo(a)pyrene ND ug/kg 427 185 1 10/10/20 14:17 10/12/20 12:33 50-32-8 Benzo(b)fluoranthene ND ug/kg 427 172 1 10/10/20 14:17 10/12/20 12:33 205-99-2 Benzo(g,h,i)perylene ND ug/kg 427 167 1 10/10/20 14:17 10/12/20 12:33 191-24-2 Benzo(k)fluoranthene ND ug/kg 427 180 1 10/10/20 14:17 10/12/20 12:33 207-08-9 Benzoic Acid ND ug/kg 2130 460 1 10/10/20 14:17 10/12/20 12:33 65-85-0 Benzyl alcohol ND ug/kg 853 226 1 10/10/20 14:17 10/12/20 12:33 100-51-6 4-Bromophenylphenyl ether ND ug/kg 427 112 1 10/10/20 14:17 10/12/20 12:33 101-55-3 Butylbenzylphthalate ND ug/kg 427 114 1 10/10/20 14:17 10/12/20 12:33 85-68-7 4-ChIoro-3-methyl phenol ND ug/kg 853 260 1 10/10/20 14:17 10/12/20 12:33 59-50-7 4-Chloroaniline ND ug/kg 853 261 1 10/10/20 14:17 10/12/20 12:33 106-47-8 bis(2-Chloroethoxy)methane ND ug/kg 427 114 1 10/10/20 14:17 10/12/20 12:33 111-91-1 bis(2-Chloroethyl) ether ND ug/kg 427 90.6 1 10/10/20 14:17 10/12/20 12:33 111-44-4 2-Chloronaphthalene ND ug/kg 427 95.0 1 10/10/20 14:17 10/12/20 12:33 91-58-7 2-Chlorophenol ND ug/kg 427 99.3 1 10/10/20 14:17 10/12/20 12:33 95-57-8 4-Chlorophenylphenyl ether ND ug/kg 427 ill 1 10/10/20 14:17 10/12/20 12:33 7005-72-3 Chrysene ND ug/kg 427 124 1 10/10/20 14:17 10/12/20 12:33 218-01-9 Dibenz(a,h)anthracene ND ug/kg 427 171 1 10/10/20 14:17 10/12/20 12:33 53-70-3 Dibenzofuran ND ug/kg 427 107 1 10/10/20 14:17 10/12/20 12:33 132-64-9 1,2-Dichlorobenzene ND ug/kg 427 92.3 1 10/10/20 14:17 10/12/20 12:33 95-50-1 1,3-Dichlorobenzene ND ug/kg 427 96.0 1 10/10/20 14:17 10/12/20 12:33 541-73-1 1,4-Dichlorobenzene ND ug/kg 427 93.8 1 10/10/20 14:17 10/12/20 12:33 106-46-7 3,3'-Dichlorobenzidine ND ug/kg 853 297 1 10/10/20 14:17 10/12/20 12:33 91-94-1 2,4-Dichlorophenol ND ug/kg 427 141 1 10/10/20 14:17 10/12/20 12:33 120-83-2 Diethylphthalate ND ug/kg 427 92.5 1 10/10/20 14:17 10/12/20 12:33 84-66-2 2,4-Dimethylphenol ND ug/kg 427 106 1 10/10/20 14:17 10/12/20 12:33 105-67-9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: PARK POINT GRASS AREA Pace Project No.: 92499316 Sample: PP-GA-4 Lab ID: 92499316004 Collected: 10/06/20 10:30 Received: 10/06/20 16:43 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8270E MSSV Microwave Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte Dimethylphthalate ND ug/kg 427 96.4 1 10/10/20 14:17 10/12/20 12:33 131-11-3 Di-n-butylphthalate ND ug/kg 427 105 1 10/10/20 14:17 10/12/20 12:33 84-74-2 4,6-Dinitro-2-methyl phenol ND ug/kg 853 688 1 10/10/20 14:17 10/12/20 12:33 534-52-1 2,4-Dinitrophenol ND ug/kg 2130 1360 1 10/10/20 14:17 10/12/20 12:33 51-28-5 2,4-Dinitrotoluene ND ug/kg 427 113 1 10/10/20 14:17 10/12/20 12:33 121-14-2 2,6-Dinitrotoluene ND ug/kg 427 112 1 10/10/20 14:17 10/12/20 12:33 606-20-2 Di-n-octylphthalate ND ug/kg 427 243 1 10/10/20 14:17 10/12/20 12:33 117-84-0 bis(2- Ethyl hexyl)phthalate ND ug/kg 427 140 1 10/10/20 14:17 10/12/20 12:33 117-81-7 Fluoranthene ND ug/kg 427 129 1 10/10/20 14:17 10/12/20 12:33 206-44-0 Fluorene ND ug/kg 427 114 1 10/10/20 14:17 10/12/20 12:33 86-73-7 Hexachloro-1,3-butadiene ND ug/kg 427 104 1 10/10/20 14:17 10/12/20 12:33 87-68-3 Hexachlorobenzene ND ug/kg 427 108 1 10/10/20 14:17 10/12/20 12:33 118-74-1 Hexachlorocyclopentadiene ND ug/kg 427 171 1 10/10/20 14:17 10/12/20 12:33 77-47-4 v2 Hexachloroethane ND ug/kg 427 97.2 1 10/10/20 14:17 10/12/20 12:33 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/kg 427 195 1 10/10/20 14:17 10/12/20 12:33 193-39-5 Isophorone ND ug/kg 427 92.7 1 10/10/20 14:17 10/12/20 12:33 78-59-1 1-Methylnaphthalene ND ug/kg 427 114 1 10/10/20 14:17 10/12/20 12:33 90-12-0 2-Methylnaphthalene ND ug/kg 427 109 1 10/10/20 14:17 10/12/20 12:33 91-57-6 2-Methylphenol(o-Cresol) ND ug/kg 427 94.5 1 10/10/20 14:17 10/12/20 12:33 95-48-7 3&4-Methyl phenol (m&p Cresol) ND ug/kg 427 107 1 10/10/20 14:17 10/12/20 12:33 15831-10-4 Naphthalene ND ug/kg 427 102 1 10/10/20 14:17 10/12/20 12:33 91-20-3 2-Nitroaniline ND ug/kg 2130 215 1 10/10/20 14:17 10/12/20 12:33 88-74-4 3-Nitroaniline ND ug/kg 2130 226 1 10/10/20 14:17 10/12/20 12:33 99-09-2 4-Nitroaniline ND ug/kg 853 211 1 10/10/20 14:17 10/12/20 12:33 100-01-6 Nitrobenzene ND ug/kg 427 102 1 10/10/20 14:17 10/12/20 12:33 98-95-3 2-Nitrophenol ND ug/kg 427 132 1 10/10/20 14:17 10/12/20 12:33 88-75-5 4-Nitrophenol ND ug/kg 2130 680 1 10/10/20 14:17 10/12/20 12:33 100-02-7 N-Nitrosodimethylamine ND ug/kg 427 120 1 10/10/20 14:17 10/12/20 12:33 62-75-9 N-Nitroso-di-n-propylamine ND ug/kg 427 119 1 10/10/20 14:17 10/12/20 12:33 621-64-7 N-Nitrosodiphenylamine ND ug/kg 427 109 1 10/10/20 14:17 10/12/20 12:33 86-30-6 2,2'-Oxybis(1-chloropropane) ND ug/kg 427 119 1 10/10/20 14:17 10/12/20 12:33 108-60-1 Pentachlorophenol ND ug/kg 853 195 1 10/10/20 14:17 10/12/20 12:33 87-86-5 Phenanthrene ND ug/kg 427 107 1 10/10/20 14:17 10/12/20 12:33 85-01-8 Phenol ND ug/kg 427 102 1 10/10/20 14:17 10/12/20 12:33 108-95-2 Pyrene ND ug/kg 427 117 1 10/10/20 14:17 10/12/20 12:33 129-00-0 Pyridine ND ug/kg 427 108 1 10/10/20 14:17 10/12/20 12:33 110-86-1 1,2,4-Trichlorobenzene ND ug/kg 427 97.7 1 10/10/20 14:17 10/12/20 12:33 120-82-1 2,4,5-Trichlorophenol ND ug/kg 427 ill 1 10/10/20 14:17 10/12/20 12:33 95-95-4 2,4,6-Trichlorophenol ND ug/kg 427 107 1 10/10/20 14:17 10/12/20 12:33 88-06-2 Surrogates Nitrobenzene-d5 (S) 78 % 21-130 1 10/10/20 14:17 10/12/20 12:33 4165-60-0 2-Fluorobiphenyl (S) 51 % 19-130 1 10/10/20 14:17 10/12/20 12:33 321-60-8 Terphenyl-dl4 (S) 84 % 15-130 1 10/10/20 14:17 10/12/20 12:33 1718-51-0 Phenol-d6 (S) 76 % 18-130 1 10/10/20 14:17 10/12/20 12:33 13127-88-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: PARK POINT GRASS AREA Pace Project No.: 92499316 Sample: PP-GA-4 Lab ID: 92499316004 Collected: 10/06/20 10:30 Received: 10/06/20 16:43 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8270E MSSV Microwave Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte Surrogates 2-Fluorophenol (S) 73 % 18-130 1 10/10/20 14:17 10/12/20 12:33 367-12-4 2,4,6-Tribromophenol (S) 69 % 18-130 1 10/10/20 14:17 10/12/20 12:33 118-79-6 8260D/5035A/5030B Volatiles Analytical Method: EPA 8260D Preparation Method: EPA 5035A/503013 Pace Analytical Services - Charlotte Acetone ND ug/kg 225 83.8 1 10/08/20 16:38 10/09/20 13:47 67-64-1 Benzene ND ug/kg 11.2 7.9 1 10/08/20 16:38 10/09/20 13:47 71-43-2 Bromobenzene ND ug/kg 11.2 7.6 1 10/08/20 16:38 10/09/20 13:47 108-86-1 Bromochloromethane ND ug/kg 11.2 8.5 1 10/08/20 16:38 10/09/20 13:47 74-97-5 Bromodichloromethane ND ug/kg 11.2 7.4 1 10/08/20 16:38 10/09/20 13:47 75-27-4 Bromoform ND ug/kg 11.2 6.1 1 10/08/20 16:38 10/09/20 13:47 75-25-2 Bromomethane ND ug/kg 22.5 17.7 1 10/08/20 16:38 10/09/20 13:47 74-83-9 2-Butanone (MEK) ND ug/kg 225 95.3 1 10/08/20 16:38 10/09/20 13:47 78-93-3 n-Butylbenzene ND ug/kg 11.2 6.1 1 10/08/20 16:38 10/09/20 13:47 104-51-8 sec-Butylbenzene ND ug/kg 11.2 7.1 1 10/08/20 16:38 10/09/20 13:47 135-98-8 tert-Butyl benzene ND ug/kg 11.2 6.0 1 10/08/20 16:38 10/09/20 13:47 98-06-6 Carbon tetrachloride ND ug/kg 11.2 5.0 1 10/08/20 16:38 10/09/20 13:47 56-23-5 Chlorobenzene ND ug/kg 11.2 7.3 1 10/08/20 16:38 10/09/20 13:47 108-90-7 Chloroethane ND ug/kg 22.5 11.9 1 10/08/20 16:38 10/09/20 13:47 75-00-3 Chloroform ND ug/kg 11.2 5.6 1 10/08/20 16:38 10/09/20 13:47 67-66-3 Chloromethane ND ug/kg 22.5 15.8 1 10/08/20 16:38 10/09/20 13:47 74-87-3 2-Chlorotoluene ND ug/kg 11.2 8.0 1 10/08/20 16:38 10/09/20 13:47 95-49-8 4-Chlorotoluene ND ug/kg 11.2 7.2 1 10/08/20 16:38 10/09/20 13:47 106-43-4 1,2-Dibromo-3-chloropropane ND ug/kg 11.2 10.4 1 10/08/20 16:38 10/09/20 13:47 96-12-8 Dibromochloromethane ND ug/kg 11.2 6.0 1 10/08/20 16:38 10/09/20 13:47 124-48-1 1,2-Dibromoethane (EDB) ND ug/kg 11.2 7.9 1 10/08/20 16:38 10/09/20 13:47 106-93-4 Dibromomethane ND ug/kg 11.2 5.6 1 10/08/20 16:38 10/09/20 13:47 74-95-3 1,2-Dichlorobenzene ND ug/kg 11.2 6.7 1 10/08/20 16:38 10/09/20 13:47 95-50-1 1,3-Dichlorobenzene ND ug/kg 11.2 9.3 1 10/08/20 16:38 10/09/20 13:47 541-73-1 1,4-Dichlorobenzene ND ug/kg 11.2 8.4 1 10/08/20 16:38 10/09/20 13:47 106-46-7 Dichlorodifluoromethane ND ug/kg 22.5 3.9 1 10/08/20 16:38 10/09/20 13:47 75-71-8 1,1-Dichloroethane ND ug/kg 11.2 4.9 1 10/08/20 16:38 10/09/20 13:47 75-34-3 1,2-Dichloroethane ND ug/kg 11.2 4.6 1 10/08/20 16:38 10/09/20 13:47 107-06-2 1,1-Dichloroethene ND ug/kg 11.2 3.5 1 10/08/20 16:38 10/09/20 13:47 75-35-4 cis-1,2-Dichloroethene ND ug/kg 11.2 6.4 1 10/08/20 16:38 10/09/20 13:47 156-59-2 trans-1,2-Dichloroethene ND ug/kg 11.2 4.9 1 10/08/20 16:38 10/09/20 13:47 156-60-5 1,2-Dichloropropane ND ug/kg 11.2 7.0 1 10/08/20 16:38 10/09/20 13:47 78-87-5 1,3-Dichloropropane ND ug/kg 11.2 7.8 1 10/08/20 16:38 10/09/20 13:47 142-28-9 2,2-Dichloropropane ND ug/kg 11.2 6.2 1 10/08/20 16:38 10/09/20 13:47 594-20-7 1,1-Dichloropropene ND ug/kg 11.2 5.4 1 10/08/20 16:38 10/09/20 13:47 563-58-6 cis-1,3-Dichloropropene ND ug/kg 11.2 7.3 1 10/08/20 16:38 10/09/20 13:47 10061-01-5 trans- 1,3-Dichloropropene ND ug/kg 11.2 9.5 1 10/08/20 16:38 10/09/20 13:47 10061-02-6 Diisopropyl ether ND ug/kg 11.2 4.5 1 10/08/20 16:38 10/09/20 13:47 108-20-3 REPORT OF LABORATORY ANALYSIS v2 IK This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: PARK POINT GRASS AREA Pace Project No.: 92499316 Sample: PP-GA-4 Lab ID: 92499316004 Collected: 10/06/20 10:30 Received: 10/06/20 16:43 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters 8260D/5035A/5030B Volatiles Ethylbenzene Hexachloro-1,3-butadiene 2-Hexanone Isopropylbenzene (Cumene) p-Isopropyltoluene Methylene Chloride 4-Methyl-2-pentanone (MIBK) Methyl-tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates Toluene-d8 (S) 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Percent Moisture Percent Moisture Results Units PQL MDL DF Prepared Analyzed CAS No. Qual Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte ND ug/kg 11.2 10.5 1 10/08/2016:38 10/09/2013:47 100-41-4 ND ug/kg 11.2 10.7 1 10/08/2016:38 10/09/2013:47 87-68-3 ND ug/kg 112 22.3 1 10/08/2016:38 10/09/2013:47 591-78-6 ND ug/kg 11.2 7.1 1 10/08/2016:38 10/09/2013:47 98-82-8 ND ug/kg 11.2 6.2 1 10/08/2016:38 10/09/2013:47 99-87-6 ND ug/kg 45.0 16.7 1 10/08/2016:38 10/09/2013:47 75-09-2 ND ug/kg 112 95.1 1 10/08/2016:38 10/09/2013:47 108-10-1 ND ug/kg 11.2 7.2 1 10/08/2016:38 10/09/2013:47 1634-04-4 ND ug/kg 11.2 6.3 1 10/08/2016:38 10/09/2013:47 91-20-3 ND ug/kg 11.2 7.8 1 10/08/2016:38 10/09/2013:47 103-65-1 ND ug/kg 11.2 5.3 1 10/08/2016:38 10/09/2013:47 100-42-5 ND ug/kg 11.2 7.4 1 10/08/2016:38 10/09/2013:47 630-20-6 ND ug/kg 11.2 9.9 1 10/08/2016:38 10/09/2013:47 79-34-5 ND ug/kg 11.2 5.6 1 10/08/2016:38 10/09/2013:47 127-18-4 ND ug/kg 11.2 6.4 1 10/08/2016:38 10/09/2013:47 108-88-3 ND ug/kg 11.2 6.9 1 10/08/2016:38 10/09/2013:47 87-61-6 ND ug/kg 11.2 6.3 1 10/08/2016:38 10/09/2013:47 120-82-1 ND ug/kg 11.2 4.5 1 10/08/2016:38 10/09/2013:47 71-55-6 ND ug/kg 11.2 8.4 1 10/08/2016:38 10/09/2013:47 79-00-5 ND ug/kg 11.2 7.0 1 10/08/2016:38 10/09/2013:47 79-01-6 ND ug/kg 11.2 2.8 1 10/08/2016:38 10/09/2013:47 75-69-4 ND ug/kg 11.2 9.1 1 10/08/2016:38 10/09/2013:47 96-18-4 ND ug/kg 11.2 8.1 1 10/08/2016:38 10/09/2013:47 95-63-6 ND ug/kg 11.2 6.7 1 10/08/2016:38 10/09/2013:47 108-67-8 ND ug/kg 112 9.7 1 10/08/2016:38 10/09/2013:47 108-05-4 ND ug/kg 22.5 4.3 1 10/08/2016:38 10/09/2013:47 75-01-4 ND ug/kg 22.5 6.4 1 10/08/2016:38 10/09/2013:47 1330-20-7 ND ug/kg 22.5 17.3 1 10/08/2016:38 10/09/2013:47 179601-23-1 ND ug/kg 11.2 6.4 1 10/08/2016:38 10/09/2013:47 95-47-6 100 % 70-130 1 10/08/2016:38 10/09/2013:47 2037-26-5 100 % 70-130 1 10/08/2016:38 10/09/2013:47 460-00-4 107 % 70-132 1 10/08/2016:38 10/09/2013:47 17060-07-0 Analytical Method: ASTM D2974-87 Pace Analytical Services - Charlotte 22.6 % 0.10 0.10 1 REPORT OF LABORATORY ANALYSIS 10/08/20 13:25 This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: PARK POINT GRASS AREA Pace Project No.: 92499316 QC Batch: 571883 Analysis Method: EPA 7471 B QC Batch Method: EPA 7471 B Analysis Description: 7471 Mercury Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92499316001, 92499316002, 92499316003, 92499316004 METHOD BLANK: 3029083 Matrix: Solid Associated Lab Samples: 92499316001, 92499316002, 92499316003, 92499316004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury mg/kg ND 0.0060 0.0046 10/09/2010:48 LABORATORY CONTROL SAMPLE: 3029084 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg 0.083 0.085 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3029085 3029086 MS MSD 92499316001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.0043J 0.074 0.075 0.079 0.083 101 104 75-125 6 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: PARK POINT GRASS AREA Pace Project No.: 92499316 QC Batch: 571871 Analysis Method: EPA 6010D QC Batch Method: EPA 3050E Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92499316001, 92499316002, 92499316003, 92499316004 METHOD BLANK: 3029037 Matrix: Solid Associated Lab Samples: 92499316001, 92499316002, 92499316003, 92499316004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic mg/kg 0.54J 1.0 0.50 10/11/2019:10 BC Barium mg/kg ND 0.50 0.25 10/11/20 01:02 Cadmium mg/kg ND 0.10 0.050 10/11/20 01:02 Chromium mg/kg ND 0.50 0.25 10/11/20 01:02 Lead mg/kg ND 0.50 0.25 10/11/20 01:02 Selenium mg/kg ND 1.0 0.50 10/11/20 01:02 Silver mg/kg ND 0.50 0.25 10/11/20 01:02 LABORATORY CONTROL SAMPLE: 3029038 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic mg/kg 50 49.2 98 80-120 Barium mg/kg 50 51.3 103 80-120 Cadmium mg/kg 50 45.5 91 80-120 Chromium mg/kg 50 49.1 98 80-120 Lead mg/kg 50 45.7 91 80-120 Selenium mg/kg 50 39.9 80 80-120 Silver mg/kg 25 22.9 92 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3029039 3029040 MS MSD 92498829001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic mg/kg 3.7 77.9 76.6 66.5 66.3 81 82 75-125 0 20 Barium mg/kg 174 77.9 76.6 243 235 88 80 75-125 3 20 Cadmium mg/kg 0.23 77.9 76.6 61.2 60.2 78 78 75-125 2 20 Chromium mg/kg 45.4 77.9 76.6 114 110 89 84 75-125 4 20 Lead mg/kg 7.3 77.9 76.6 66.9 65.4 77 76 75-125 2 20 Selenium mg/kg 1.9 77.9 76.6 53.8 53.7 67 68 75-125 0 20 M1 Silver mg/kg ND 38.9 38.3 30.8 30.5 79 80 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: PARK POINT GRASS AREA Pace Project No.: 92499316 QC Batch: 571919 Analysis Method: EPA 8260D QC Batch Method: EPA 5035A/5030B Analysis Description: 8260D 5035A 5030E Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92499316001, 92499316002, 92499316003, 92499316004 METHOD BLANK: 3029247 Matrix: Solid Associated Lab Samples: 92499316001, 92499316002, 92499316003, 92499316004 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/kg ND 5.0 3.3 10/09/20 12:26 1,1,1-Trichloroethane ug/kg ND 5.0 2.0 10/09/20 12:26 1,1,2,2-Tetrachloroethane ug/kg ND 5.0 4.4 10/09/20 12:26 1,1,2-Trichloroethane ug/kg ND 5.0 3.7 10/09/20 12:26 1,1-Dichloroethane ug/kg ND 5.0 2.2 10/09/20 12:26 1,1-Dichloroethene ug/kg ND 5.0 1.6 10/09/20 12:26 1,1-Dichloropropene ug/kg ND 5.0 2.4 10/09/20 12:26 1,2,3-Trichlorobenzene ug/kg ND 5.0 3.1 10/09/20 12:26 1,2,3-Trichloropropane ug/kg ND 5.0 4.1 10/09/20 12:26 1,2,4-Trichlorobenzene ug/kg ND 5.0 2.8 10/09/20 12:26 1,2,4-Trimethylbenzene ug/kg ND 5.0 3.6 10/09/20 12:26 1,2-Dibromo-3-chloropropane ug/kg ND 5.0 4.6 10/09/20 12:26 1,2-Dibromoethane (EDB) ug/kg ND 5.0 3.5 10/09/20 12:26 1,2-Dichlorobenzene ug/kg ND 5.0 3.0 10/09/20 12:26 1,2-Dichloroethane ug/kg ND 5.0 2.0 10/09/20 12:26 1,2-Dichloropropane ug/kg ND 5.0 3.1 10/09/20 12:26 1,3,5-Trimethylbenzene ug/kg ND 5.0 3.0 10/09/20 12:26 1,3-Dichlorobenzene ug/kg ND 5.0 4.1 10/09/20 12:26 1,3-Dichloropropane ug/kg ND 5.0 3.5 10/09/20 12:26 1,4-Dichlorobenzene ug/kg ND 5.0 3.8 10/09/20 12:26 2,2-Dichloropropane ug/kg ND 5.0 2.8 10/09/20 12:26 2-Butanone (MEK) ug/kg ND 100 42.4 10/09/20 12:26 2-Chlorotoluene ug/kg ND 5.0 3.6 10/09/20 12:26 2-Hexanone ug/kg ND 50.0 9.9 10/09/20 12:26 4-Chlorotoluene ug/kg ND 5.0 3.2 10/09/20 12:26 4-Methyl-2-pentanone (MIBK) ug/kg ND 50.0 42.3 10/09/20 12:26 Acetone ug/kg ND 100 37.3 10/09/20 12:26 Benzene ug/kg ND 5.0 3.5 10/09/20 12:26 Bromobenzene ug/kg ND 5.0 3.4 10/09/20 12:26 Bromochloromethane ug/kg ND 5.0 3.8 10/09/20 12:26 Bromodichloromethane ug/kg ND 5.0 3.3 10/09/20 12:26 Bromoform ug/kg ND 5.0 2.7 10/09/20 12:26 Bromomethane ug/kg ND 10.0 7.9 10/09/20 12:26 Carbon tetrachloride ug/kg ND 5.0 2.2 10/09/20 12:26 Chlorobenzene ug/kg ND 5.0 3.2 10/09/20 12:26 Chloroethane ug/kg ND 10.0 5.3 10/09/20 12:26 IK Chloroform ug/kg ND 5.0 2.5 10/09/20 12:26 Chloromethane ug/kg ND 10.0 7.0 10/09/20 12:26 cis-1,2-Dichloroethene ug/kg ND 5.0 2.9 10/09/20 12:26 cis-1,3-Dichloropropene ug/kg ND 5.0 3.2 10/09/20 12:26 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: PARK POINT GRASS AREA Pace Project No.: 92499316 METHOD BLANK: 3029247 Matrix: Solid Associated Lab Samples: 92499316001, 92499316002, 92499316003, 92499316004 Blank Reporting Parameter Units Result Limit MDL Analyzed Dibromochloromethane ug/kg ND 5.0 2.7 10/09/20 12:26 Dibromomethane ug/kg ND 5.0 2.5 10/09/20 12:26 Dichlorodifluoromethane ug/kg ND 10.0 1.7 10/09/20 12:26 Diisopropyl ether ug/kg ND 5.0 2.0 10/09/20 12:26 Ethylbenzene ug/kg ND 5.0 4.7 10/09/20 12:26 Hexachloro-1,3-butadiene ug/kg ND 5.0 4.7 10/09/20 12:26 Isopropylbenzene (Cumene) ug/kg ND 5.0 3.2 10/09/20 12:26 m&p-Xylene ug/kg ND 10.0 7.7 10/09/20 12:26 Methyl-tert-butyl ether ug/kg ND 5.0 3.2 10/09/20 12:26 Methylene Chloride ug/kg ND 20.0 7.4 10/09/20 12:26 n-Butylbenzene ug/kg ND 5.0 2.7 10/09/20 12:26 n-Propylbenzene ug/kg ND 5.0 3.4 10/09/20 12:26 Naphthalene ug/kg ND 5.0 2.8 10/09/20 12:26 o-Xylene ug/kg ND 5.0 2.8 10/09/20 12:26 p-Isopropyltoluene ug/kg ND 5.0 2.8 10/09/20 12:26 sec-Butylbenzene ug/kg ND 5.0 3.2 10/09/20 12:26 Styrene ug/kg ND 5.0 2.4 10/09/20 12:26 tert-Butyl benzene ug/kg ND 5.0 2.7 10/09/20 12:26 Tetrachloroethene ug/kg ND 5.0 2.5 10/09/20 12:26 Toluene ug/kg ND 5.0 2.9 10/09/20 12:26 trans-1,2-Dichloroethene ug/kg ND 5.0 2.2 10/09/20 12:26 trans- 1,3-Dichloropropene ug/kg ND 5.0 4.2 10/09/20 12:26 Trichloroethene ug/kg ND 5.0 3.1 10/09/20 12:26 Trichlorofluoromethane ug/kg ND 5.0 1.2 10/09/20 12:26 Vinyl acetate ug/kg ND 50.0 4.3 10/09/20 12:26 Vinyl chloride ug/kg ND 10.0 1.9 10/09/20 12:26 Xylene (Total) ug/kg ND 10.0 2.8 10/09/20 12:26 1,2-Dichloroethane-d4 (S) % 109 70-132 10/09/20 12:26 4-Bromofluorobenzene (S) % 97 70-130 10/09/20 12:26 Toluene-d8 (S) % 98 70-130 10/09/20 12:26 v2 Qualifiers LABORATORY CONTROL SAMPLE: 3029248 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/kg 1250 1320 106 70-130 1,1,1-Trichloroethane ug/kg 1250 1360 109 70-130 1,1,2,2-Tetrachloroethane ug/kg 1250 1310 105 55-130 1,1,2-Trichloroethane ug/kg 1250 1290 103 70-130 1,1-Dichloroethane ug/kg 1250 1370 110 68-130 1,1-Dichloroethene ug/kg 1250 1500 120 70-130 1,1-Dichloropropene ug/kg 1250 1190 95 70-130 1,2,3-Trichlorobenzene ug/kg 1250 1220 97 70-130 1,2,3-Trichloropropane ug/kg 1250 1310 105 70-130 1,2,4-Trichlorobenzene ug/kg 1250 1270 101 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: PARK POINT GRASS AREA Pace Project No.: 92499316 LABORATORY CONTROL SAMPLE: Parameter 3029248 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,2,4-Trimethylbenzene ug/kg 1250 1220 98 69-130 1,2-Dibromo-3-chloropropane ug/kg 1250 1320 106 57-141 1,2-Dibromoethane (EDB) ug/kg 1250 1360 109 70-130 1,2-Dichlorobenzene ug/kg 1250 1250 100 70-130 1,2-Dichloroethane ug/kg 1250 1170 93 70-130 1,2-Dichloropropane ug/kg 1250 1280 102 70-130 1,3,5-Trimethylbenzene ug/kg 1250 1280 102 70-130 1,3-Dichlorobenzene ug/kg 1250 1240 99 70-130 1,3-Dichloropropane ug/kg 1250 1340 107 70-130 1,4-Dichlorobenzene ug/kg 1250 1200 96 70-130 2,2-Dichloropropane ug/kg 1250 1410 113 70-130 2-Butanone (MEK) ug/kg 2500 2580 103 60-130 2-Chlorotoluene ug/kg 1250 1310 105 70-130 2-Hexanone ug/kg 2500 2670 107 70-132 4-Chlorotoluene ug/kg 1250 1240 100 70-130 4-Methyl-2-pentanone (MIBK) ug/kg 2500 2580 103 69-130 Acetone ug/kg 2500 2510 100 49-148 Benzene ug/kg 1250 1310 105 70-130 Bromobenzene ug/kg 1250 1270 102 70-130 Bromochloromethane ug/kg 1250 1340 107 70-130 Bromodichloromethane ug/kg 1250 1230 98 70-130 Bromoform ug/kg 1250 1310 105 68-136 Bromomethane ug/kg 1250 1300 104 60-140 Carbon tetrachloride ug/kg 1250 1210 97 70-130 Chlorobenzene ug/kg 1250 1260 101 70-130 Chloroethane ug/kg 1250 1440 115 51-147IK Chloroform ug/kg 1250 1310 105 70-130 Chloromethane ug/kg 1250 1220 98 48-130 cis-1,2-Dichloroethene ug/kg 1250 1380 110 70-130 cis-1,3-Dichloropropene ug/kg 1250 1370 109 70-130 Dibromochloromethane ug/kg 1250 1360 109 70-130 Dibromomethane ug/kg 1250 1300 104 70-130 Dichlorodifluoromethane ug/kg 1250 1600 128 49-130 Diisopropyl ether ug/kg 1250 1290 103 66-130 Ethylbenzene ug/kg 1250 1200 96 70-130 Hexachloro-1,3-butadiene ug/kg 1250 1310 105 70-130 Isopropylbenzene (Cumene) ug/kg 1250 1280 102 70-130 m&p-Xylene ug/kg 2500 2560 102 70-130 Methyl-tert-butyl ether ug/kg 1250 1300 104 70-130 Methylene Chloride ug/kg 1250 1260 101 50-137 n-Butylbenzene ug/kg 1250 1290 103 70-130 n-Propylbenzene ug/kg 1250 1290 103 70-130 Naphthalene ug/kg 1250 1220 98 70-131 o-Xylene ug/kg 1250 1240 99 70-130 p-Isopropyltoluene ug/kg 1250 1290 103 70-130 sec-Butylbenzene ug/kg 1250 1290 103 70-130 Styrene ug/kg 1250 1330 107 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: PARK POINT GRASS AREA Pace Project No.: 92499316 LABORATORY CONTROL SAMPLE: Parameter 3029248 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers tert-Butyl benzene ug/kg 1250 936 75 69-130 v3 Tetrachloroethene ug/kg 1250 1230 99 56-130 Toluene ug/kg 1250 1240 99 70-130 trans-1,2-Dichloroethene ug/kg 1250 1410 113 70-130 trans- 1,3-Dichloropropene ug/kg 1250 1300 104 70-130 Trichloroethene ug/kg 1250 1220 98 70-141 Trichlorofluoromethane ug/kg 1250 1390 111 67-130 Vinyl acetate ug/kg 2500 2930 117 10-136 Vinyl chloride ug/kg 1250 1330 107 67-130 Xylene (Total) ug/kg 3750 3800 101 70-130 1,2-Dichloroethane-d4 (S) % 94 70-132 4-Bromofluorobenzene (S) % 101 70-130 Toluene-d8 (S) % 98 70-130 MATRIX SPIKE SAMPLE: Parameter 3029250 Units 92499316002 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/kg ND 935 1120 119 52-133 1,1,1-Trichloroethane ug/kg ND 935 1250 133 49-137 1,1,2,2-Tetrachloroethane ug/kg ND 935 1120 119 39-150 1,1,2-Trichloroethane ug/kg ND 935 1230 132 48-140 1,1-Dichloroethane ug/kg ND 935 1310 140 46-135 M1 1,1-Dichloroethene ug/kg ND 935 517 55 38-149 1,1-Dichloropropene ug/kg ND 935 1150 123 41-140 1,2,3-Trichlorobenzene ug/kg ND 935 503 54 10-158 1,2,3-Trichloropropane ug/kg ND 935 1120 120 33-157 1,2,4-Trichlorobenzene ug/kg ND 935 860 92 10-155 1,2,4-Trimethylbenzene ug/kg ND 935 1190 127 24-154 1,2-Dibromo-3-chloropropane ug/kg ND 935 535 57 33-158 1,2-Dibromoethane (EDB) ug/kg ND 935 1140 122 40-136 1,2-Dichlorobenzene ug/kg ND 935 1130 120 27-146 1,2-Dichloroethane ug/kg ND 935 1170 125 49-140 1,2-Dichloropropane ug/kg ND 935 1200 128 44-143 1,3,5-Trimethylbenzene ug/kg ND 935 1180 126 40-144 1,3-Dichlorobenzene ug/kg ND 935 1120 120 33-140 1,3-Dichloropropane ug/kg ND 935 1240 133 47-147 1,4-Dichlorobenzene ug/kg ND 935 1120 119 35-139 2,2-Dichloropropane ug/kg ND 935 996 107 41-140 2-Butanone (MEK) ug/kg ND 1870 1070 54 10-181 2-Chlorotoluene ug/kg ND 935 1200 128 38-147 2-Hexanone ug/kg ND 1870 732 39 18-169 4-Chlorotoluene ug/kg ND 935 1160 124 36-145 4-Methyl-2-pentanone (MIBK) ug/kg ND 1870 1560 83 16-175 Acetone ug/kg ND 1870 1240 66 10-200 Benzene ug/kg ND 935 1240 133 46-136 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: PARK POINT GRASS AREA Pace Project No.: 92499316 MATRIX SPIKE SAMPLE: 3029250 92499316002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Bromobenzene ug/kg ND 935 1240 133 38-149 Bromochloromethane ug/kg ND 935 1240 133 44-142 Bromodichloromethane ug/kg ND 935 1080 116 41-140 Bromoform ug/kg ND 935 963 103 34-145 Bromomethane ug/kg ND 935 1120 120 14-162 Carbon tetrachloride ug/kg ND 935 1060 114 44-141 Chlorobenzene ug/kg ND 935 1120 120 39-141 Chloroethane ug/kg ND 935 342 37 10-182 IK Chloroform ug/kg ND 935 1230 131 45-140 Chloromethane ug/kg ND 935 1220 130 19-149 v3 cis-1,2-Dichloroethene ug/kg ND 935 1300 139 38-150 cis-1,3-Dichloropropene ug/kg ND 935 1250 134 30-144 Dibromochloromethane ug/kg ND 935 1070 114 36-145 Dibromomethane ug/kg ND 935 1120 120 41-145 Dichlorodifluoromethane ug/kg ND 935 1580 169 16-146 M1,v3 Diisopropyl ether ug/kg ND 935 1250 134 41-143 Ethylbenzene ug/kg ND 935 1100 117 35-144 Hexachloro-1,3-butadiene ug/kg ND 935 1170 126 10-160 Isopropylbenzene (Cumene) ug/kg ND 935 1150 123 30-152 m&p-Xylene ug/kg ND 1870 2330 125 33-145 Methyl-tert-butyl ether ug/kg ND 935 1210 130 49-140 Methylene Chloride ug/kg ND 935 965 103 10-174 n-Butylbenzene ug/kg ND 935 1250 134 10-160 n-Propylbenzene ug/kg ND 935 1220 130 24-159 Naphthalene ug/kg ND 935 2700 288 10-171 C8,M1 o-Xylene ug/kg ND 935 1140 122 31-150 p-Isopropyltoluene ug/kg ND 935 1200 128 21-154 sec-Butylbenzene ug/kg ND 935 1230 131 19-159 Styrene ug/kg ND 935 1160 124 15-152 tert-Butyl benzene ug/kg ND 935 871 93 31-141 Tetrachloroethene ug/kg ND 935 1060 113 19-141 Toluene ug/kg ND 935 1180 126 31-146 trans-1,2-Dichloroethene ug/kg ND 935 1380 148 28-157 trans- 1,3-Dichloropropene ug/kg ND 935 1190 127 25-146 Trichloroethene ug/kg ND 935 1140 122 34-149 Trichlorofluoromethane ug/kg ND 935 15.8 2 10-167 M1 Vinyl acetate ug/kg ND 1870 2610 140 10-200 Vinyl chloride ug/kg ND 935 1430 152 36-155 Xylene (Total) ug/kg ND 2810 3470 124 29-148 1,2-Dichloroethane-d4 (S) % 127 70-132 4-Bromofluorobenzene (S) % 104 70-130 Toluene-d8 (S) % 100 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 45 Pace Analytical Services, LLC lac, Analyilcal ® 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: PARK POINT GRASS AREA Pace Project No.: 92499316 SAMPLE DUPLICATE: 3029249 Parameter Units 92499316001 Result Dup Result RPD Max RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/kg ND ND 30 1,1,1-Trichloroethane ug/kg ND ND 30 1,1,2,2-Tetrachloroethane ug/kg ND ND 30 1,1,2-Trichloroethane ug/kg ND ND 30 1,1-Dichloroethane ug/kg ND ND 30 1,1-Dichloroethene ug/kg ND ND 30 1,1-Dichloropropene ug/kg ND ND 30 1,2,3-Trichlorobenzene ug/kg ND ND 30 1,2,3-Trichloropropane ug/kg ND ND 30 1,2,4-Trichlorobenzene ug/kg ND ND 30 1,2,4-Trimethylbenzene ug/kg ND ND 30 1,2-Dibromo-3-chloropropane ug/kg ND ND 30 1,2-Dibromoethane (EDB) ug/kg ND ND 30 1,2-Dichlorobenzene ug/kg ND ND 30 1,2-Dichloroethane ug/kg ND ND 30 1,2-Dichloropropane ug/kg ND ND 30 1,3,5-Trimethylbenzene ug/kg ND ND 30 1,3-Dichlorobenzene ug/kg ND ND 30 1,3-Dichloropropane ug/kg ND ND 30 1,4-Dichlorobenzene ug/kg ND ND 30 2,2-Dichloropropane ug/kg ND ND 30 2-Butanone (MEK) ug/kg ND ND 30 2-Chlorotoluene ug/kg ND ND 30 2-Hexanone ug/kg ND ND 30 4-Chlorotoluene ug/kg ND ND 30 4-Methyl-2-pentanone (MIBK) ug/kg ND ND 30 Acetone ug/kg ND ND 30 Benzene ug/kg ND ND 30 Bromobenzene ug/kg ND ND 30 Bromochloromethane ug/kg ND ND 30 Bromodichloromethane ug/kg ND ND 30 Bromoform ug/kg ND ND 30 Bromomethane ug/kg ND ND 30 v2 Carbon tetrachloride ug/kg ND ND 30 Chlorobenzene ug/kg ND ND 30 Chloroethane ug/kg ND ND 301K Chloroform ug/kg ND ND 30 Chloromethane ug/kg ND ND 30 cis-1,2-Dichloroethene ug/kg ND ND 30 cis-1,3-Dichloropropene ug/kg ND ND 30 Dibromochloromethane ug/kg ND ND 30 Dibromomethane ug/kg ND ND 30 Dichlorodifluoromethane ug/kg ND ND 30 v2 Diisopropyl ether ug/kg ND ND 30 Ethylbenzene ug/kg ND ND 30 Hexachloro-1,3-butadiene ug/kg ND ND 30 Isopropylbenzene (Cumene) ug/kg ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: PARK POINT GRASS AREA Pace Project No.: 92499316 SAMPLE DUPLICATE: 3029249 Parameter Units 92499316001 Result Dup Result m&p-Xylene ug/kg ND ND Methyl-tert-butyl ether ug/kg ND ND Methylene Chloride ug/kg ND ND n-Butylbenzene ug/kg ND ND n-Propylbenzene ug/kg ND ND Naphthalene ug/kg ND ND o-Xylene ug/kg ND ND p-Isopropyltoluene ug/kg ND ND sec-Butylbenzene ug/kg ND ND Styrene ug/kg ND ND tert-Butyl benzene ug/kg ND ND Tetrachloroethene ug/kg ND ND Toluene ug/kg ND ND trans-1,2-Dichloroethene ug/kg ND ND trans- 1,3-Dichloropropene ug/kg ND ND Trichloroethene ug/kg ND ND Trichlorofluoromethane ug/kg ND ND Vinyl acetate ug/kg ND ND Vinyl chloride ug/kg ND ND Xylene (Total) ug/kg ND ND 1,2-Dichloroethane-d4 (S) % 108 113 4-Bromofluorobenzene (S) % 101 101 Toluene-d8(S) % 101 101 Max RPD RPD Qualifiers 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: PARK POINT GRASS AREA Pace Project No.: 92499316 QC Batch: 572372 Analysis Method: EPA 8270E QC Batch Method: EPA 3546 Analysis Description: 8270E Solid MSSV Microwave Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92499316001, 92499316002, 92499316003, 92499316004 METHOD BLANK: 3031498 Matrix: Solid Associated Lab Samples: 92499316001, 92499316002, 92499316003, 92499316004 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,2,4-Trichlorobenzene ug/kg ND 334 76.6 10/12/20 09:51 1,2-Dichlorobenzene ug/kg ND 334 72.4 10/12/20 09:51 1,3-Dichlorobenzene ug/kg ND 334 75.3 10/12/20 09:51 1,4-Dichlorobenzene ug/kg ND 334 73.6 10/12/20 09:51 1-Methylnaphthalene ug/kg ND 334 89.1 10/12/20 09:51 2,2'-Oxybis(1-chloropropane) ug/kg ND 334 92.9 10/12/20 09:51 2,4,5-Trichlorophenol ug/kg ND 334 86.9 10/12/20 09:51 2,4,6-Trichlorophenol ug/kg ND 334 84.0 10/12/20 09:51 2,4-Dichlorophenol ug/kg ND 334 110 10/12/20 09:51 2,4-Dimethylphenol ug/kg ND 334 83.3 10/12/20 09:51 2,4-Dinitrophenol ug/kg ND 1670 1070 10/12/20 09:51 2,4-Dinitrotoluene ug/kg ND 334 88.6 10/12/20 09:51 2,6-Dinitrotoluene ug/kg ND 334 87.5 10/12/20 09:51 2-Chloronaphthalene ug/kg ND 334 74.5 10/12/20 09:51 2-Chlorophenol ug/kg ND 334 77.8 10/12/20 09:51 2-Methylnaphthalene ug/kg ND 334 85.1 10/12/20 09:51 2-Methylphenol(o-Cresol) ug/kg ND 334 74.1 10/12/20 09:51 2-Nitroaniline ug/kg ND 1670 168 10/12/20 09:51 2-Nitrophenol ug/kg ND 334 103 10/12/20 09:51 3&4-Methyl phenol (m&p Cresol) ug/kg ND 334 84.1 10/12/20 09:51 3,3'-Dichlorobenzidine ug/kg ND 669 233 10/12/20 09:51 3-Nitroaniline ug/kg ND 1670 177 10/12/20 09:51 4,6-Dinitro-2-methyl phenol ug/kg ND 669 539 10/12/20 09:51 4-Bromophenylphenyl ether ug/kg ND 334 87.8 10/12/20 09:51 4-ChIoro-3-methyl phenol ug/kg ND 669 204 10/12/20 09:51 4-Chloroaniline ug/kg ND 669 205 10/12/20 09:51 4-Chlorophenylphenyl ether ug/kg ND 334 86.9 10/12/20 09:51 4-Nitroaniline ug/kg ND 669 165 10/12/20 09:51 4-Nitrophenol ug/kg ND 1670 533 10/12/20 09:51 Acenaphthene ug/kg ND 334 86.0 10/12/20 09:51 Acenaphthylene ug/kg ND 334 79.2 10/12/20 09:51 Aniline ug/kg ND 334 75.1 10/12/20 09:51 Anthracene ug/kg ND 334 86.8 10/12/20 09:51 Benzo(a)anthracene ug/kg ND 334 106 10/12/20 09:51 Benzo(a)pyrene ug/kg ND 334 145 10/12/20 09:51 Benzo(b)fluoranthene ug/kg ND 334 135 10/12/20 09:51 Benzo(g,h,i)perylene ug/kg ND 334 131 10/12/20 09:51 Benzo(k)fluoranthene ug/kg ND 334 141 10/12/20 09:51 Benzoic Acid ug/kg ND 1670 361 10/12/20 09:51 Benzyl alcohol ug/kg ND 669 177 10/12/20 09:51 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: PARK POINT GRASS AREA Pace Project No.: 92499316 METHOD BLANK: 3031498 Matrix: Solid Associated Lab Samples: 92499316001, 92499316002, 92499316003, 92499316004 Blank Reporting Parameter Units Result Limit MDL Analyzed bis(2-Chloroethoxy)methane ug/kg ND 334 89.3 10/12/20 09:51 bis(2-Chloroethyl) ether ug/kg ND 334 71.0 10/12/20 09:51 bis(2-Ethylhexyl)phthalate ug/kg ND 334 109 10/12/20 09:51 Butylbenzylphthalate ug/kg ND 334 89.1 10/12/20 09:51 Chrysene ug/kg ND 334 97.1 10/12/20 09:51 Di-n-butylphthalate ug/kg ND 334 82.5 10/12/20 09:51 Di-n-octylphthalate ug/kg ND 334 191 10/12/20 09:51 Dibenz(a,h)anthracene ug/kg ND 334 134 10/12/20 09:51 Dibenzofuran ug/kg ND 334 83.6 10/12/20 09:51 Diethylphthalate ug/kg ND 334 72.6 10/12/20 09:51 Dimethylphthalate ug/kg ND 334 75.6 10/12/20 09:51 Fluoranthene ug/kg ND 334 101 10/12/20 09:51 Fluorene ug/kg ND 334 89.5 10/12/20 09:51 Hexachloro-1,3-butadiene ug/kg ND 334 81.3 10/12/20 09:51 Hexachlorobenzene ug/kg ND 334 84.9 10/12/20 09:51 Hexachlorocyclopentadiene ug/kg ND 334 134 10/12/20 09:51 Hexachloroethane ug/kg ND 334 76.2 10/12/20 09:51 Indeno(1,2,3-cd)pyrene ug/kg ND 334 153 10/12/20 09:51 Isophorone ug/kg ND 334 72.7 10/12/20 09:51 N-Nitroso-di-n-propylamine ug/kg ND 334 93.6 10/12/20 09:51 N-Nitrosodimethylamine ug/kg ND 334 94.1 10/12/20 09:51 N-Nitrosodiphenylamine ug/kg ND 334 85.3 10/12/20 09:51 Naphthalene ug/kg ND 334 80.1 10/12/20 09:51 Nitrobenzene ug/kg ND 334 79.9 10/12/20 09:51 Pentachlorophenol ug/kg ND 669 153 10/12/20 09:51 Phenanthrene ug/kg ND 334 84.2 10/12/20 09:51 Phenol ug/kg ND 334 79.9 10/12/20 09:51 Pyrene ug/kg ND 334 92.0 10/12/20 09:51 Pyridine ug/kg ND 334 84.6 10/12/20 09:51 2,4,6-Tribromophenol (S) % 80 18-130 10/12/20 09:51 2-Fluorobiphenyl (S) % 80 19-130 10/12/20 09:51 2-Fluorophenol (S) % 81 18-130 10/12/20 09:51 Nitrobenzene-d5 (S) % 84 21-130 10/12/20 09:51 Phenol-d6 (S) % 85 18-130 10/12/20 09:51 Terphenyl-d14 (S) % 110 15-130 10/12/20 09:51 v2 Qualifiers LABORATORY CONTROL SAMPLE: 3031499 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,2,4-Trichlorobenzene ug/kg 1690 1420 84 47-130 1,2-Dichlorobenzene ug/kg 1690 1450 85 49-130 1,3-Dichlorobenzene ug/kg 1690 1440 85 48-130 1,4-Dichlorobenzene ug/kg 1690 1470 87 49-130 1-Methylnaphthalene ug/kg 1690 1440 85 54-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: PARK POINT GRASS AREA Pace Project No.: 92499316 LABORATORY CONTROL SAMPLE: Parameter 3031499 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 2,2'-Oxybis(1-chloropropane) ug/kg 1690 1480 87 38-130 2,4,5-Trichlorophenol ug/kg 1690 1700 100 49-130 2,4,6-Trichlorophenol ug/kg 1690 1550 92 50-130 2,4-Dichlorophenol ug/kg 1690 1540 91 51-130 2,4-Dimethylphenol ug/kg 1690 1570 93 53-130 2,4-Dinitrophenol ug/kg 8470 7100 84 39-130 2,4-Dinitrotoluene ug/kg 1690 1700 101 53-130 2,6-Dinitrotoluene ug/kg 1690 1700 100 55-130 2-Chloronaphthalene ug/kg 1690 1590 94 48-130 2-Chlorophenol ug/kg 1690 1530 90 54-130 2-Methylnaphthalene ug/kg 1690 1480 88 57-130 2-Methylphenol(o-Cresol) ug/kg 1690 1620 96 50-130 2-Nitroaniline ug/kg 3390 3590 106 49-130 2-Nitrophenol ug/kg 1690 1490 88 50-130 3&4-Methyl phenol (m&p Cresol) ug/kg 1690 1580 93 50-130 3,3'-Dichlorobenzidine ug/kg 3390 3000 89 47-130 3-Nitroaniline ug/kg 3390 3170 94 45-130 4,6-Dinitro-2-methyl phenol ug/kg 3390 3020 89 50-142 4-Bromophenylphenyl ether ug/kg 1690 1560 92 55-130 4-ChIoro-3-methyl phenol ug/kg 3390 3240 96 52-130 4-Chloroaniline ug/kg 3390 2930 86 49-130 4-Chlorophenylphenyl ether ug/kg 1690 1650 98 53-130 4-Nitroaniline ug/kg 3390 3540 104 51-130 4-Nitrophenol ug/kg 8470 9760 115 40-130 Acenaphthene ug/kg 1690 1580 93 56-130 Acenaphthylene ug/kg 1690 1590 94 58-130 Aniline ug/kg 1690 1400 82 44-130 Anthracene ug/kg 1690 1490 88 60-130 Benzo(a)anthracene ug/kg 1690 1700 100 59-130 Benzo(a)pyrene ug/kg 1690 1710 101 57-130 Benzo(b)fluoranthene ug/kg 1690 1700 100 54-130 Benzo(g,h,i)perylene ug/kg 1690 1570 92 59-130 Benzo(k)fluoranthene ug/kg 1690 1760 104 54-130 Benzoic Acid ug/kg 8470 5760 68 19-130 Benzyl alcohol ug/kg 3390 2980 88 50-130 bis(2-Chloroethoxy)methane ug/kg 1690 1440 85 55-130 bis(2-Chloroethyl) ether ug/kg 1690 1570 92 53-130 bis(2-Ethylhexyl)phthalate ug/kg 1690 1600 94 58-130 Butylbenzylphthalate ug/kg 1690 1590 94 46-138 Chrysene ug/kg 1690 1710 101 57-130 Di-n-butylphthalate ug/kg 1690 1650 97 57-130 Di-n-octylphthalate ug/kg 1690 1580 93 57-130 Dibenz(a,h)anthracene ug/kg 1690 1560 92 60-130 Dibenzofuran ug/kg 1690 1660 98 54-130 Diethylphthalate ug/kg 1690 1670 98 55-130 Dimethylphthalate ug/kg 1690 1660 98 57-130 Fluoranthene ug/kg 1690 1800 106 57-130 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 45 Pace Analytical Services, LLC lac, Analyilcal ® 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: PARK POINT GRASS AREA Pace Project No.: 92499316 LABORATORY CONTROL SAMPLE: Parameter 3031499 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Fluorene ug/kg 1690 1660 98 56-130 Hexachloro-1,3-butadiene ug/kg 1690 1430 84 41-130 Hexachlorobenzene ug/kg 1690 1560 92 53-130 Hexachlorocyclopentadiene ug/kg 1690 854 50 23-130 v3 Hexachloroethane ug/kg 1690 1410 83 48-130 Indeno(1,2,3-cd)pyrene ug/kg 1690 1580 93 61-130 Isophorone ug/kg 1690 1520 90 49-130 N-Nitroso-di-n-propylamine ug/kg 1690 1530 90 52-130 N-Nitrosodimethylamine ug/kg 1690 1510 89 45-130 N-Nitrosodiphenylamine ug/kg 1690 1590 94 56-130 Naphthalene ug/kg 1690 1460 86 56-130 Nitrobenzene ug/kg 1690 1540 91 50-130 Pentachlorophenol ug/kg 3390 3330 98 33-130 Phenanthrene ug/kg 1690 1680 99 60-130 Phenol ug/kg 1690 1600 94 54-130 Pyrene ug/kg 1690 1610 95 61-130 Pyridine ug/kg 1690 1250 74 35-130 2,4,6-Tribromophenol (S) % 93 18-130 2-Fluorobiphenyl (S) % 81 19-130 2-Fluorophenol(S) % 81 18-130 Nitrobenzene-d5(S) % 81 21-130 Phenol-d6 (S) % 86 18-130 Terphenyl-d14 (S) % 87 15-130 MATRIX SPIKE SAMPLE: Parameter 3031500 Units 92499114004 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,2,4-Trichlorobenzene ug/kg ND 2050 1170 57 22-130 1,2-Dichlorobenzene ug/kg ND 2050 1170 57 23-130 1,3-Dichlorobenzene ug/kg ND 2050 1170 57 26-130 1,4-Dichlorobenzene ug/kg ND 2050 1200 58 27-130 1-Methylnaphthalene ug/kg ND 2050 1190 58 30-130 2,2'-Oxybis(1-chloropropane) ug/kg ND 2050 1260 61 30-130 2,4,5-Trichlorophenol ug/kg ND 2050 1390 68 26-130 2,4,6-Trichlorophenol ug/kg ND 2050 1240 60 23-130 2,4-Dichlorophenol ug/kg ND 2050 1300 64 29-130 2,4-Dimethylphenol ug/kg ND 2050 1300 63 13-130 2,4-Dinitrophenol ug/kg ND 10300 5450 53 10-131 2,4-Dinitrotoluene ug/kg ND 2050 1380 67 28-130 2,6-Dinitrotoluene ug/kg ND 2050 1370 67 36-130 2-Chloronaphthalene ug/kg ND 2050 1260 62 27-130 2-Chlorophenol ug/kg ND 2050 1320 64 29-130 2-Methylnaphthalene ug/kg ND 2050 1210 59 29-130 2-Methylphenol(o-Cresol) ug/kg ND 2050 1390 68 20-130 2-Nitroaniline ug/kg ND 4100 3040 74 29-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: PARK POINT GRASS AREA Pace Project No.: 92499316 MATRIX SPIKE SAMPLE: 3031500 92499114004 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 2-Nitrophenol ug/kg ND 2050 1270 62 26-130 3&4-Methyl phenol (m&p Cresol) ug/kg ND 2050 1380 67 10-176 3,3'-Dichlorobenzidine ug/kg ND 4100 2260 55 15-130 3-Nitroaniline ug/kg ND 4100 2750 67 28-130 4,6-Dinitro-2-methyl phenol ug/kg ND 4100 2300 56 15-132 4-Bromophenylphenyl ether ug/kg ND 2050 1210 59 35-130 4-Chloro-3-methylphenol ug/kg ND 4100 2740 67 30-130 4-Chloroaniline ug/kg ND 4100 2490 61 28-130 4-Chlorophenylphenyl ether ug/kg ND 2050 1260 61 32-130 4-Nitroaniline ug/kg ND 4100 3040 74 30-130 4-Nitrophenol ug/kg ND 10300 8060 79 17-130 Acenaphthene ug/kg ND 2050 1270 62 29-130 Acenaphthylene ug/kg ND 2050 1290 63 31-130 Aniline ug/kg ND 2050 1110 54 10-130 Anthracene ug/kg ND 2050 1160 57 33-130 Benzo(a)anthracene ug/kg ND 2050 1290 63 32-130 Benzo(a)pyrene ug/kg ND 2050 1310 64 32-130 Benzo(b)fluoranthene ug/kg ND 2050 1310 64 33-130 Benzo(g,h,i)perylene ug/kg ND 2050 1160 57 28-130 Benzo(k)fluoranthene ug/kg ND 2050 1390 68 31-130 Benzoic Acid ug/kg ND 10300 5370 52 10-130 Benzyl alcohol ug/kg ND 4100 2560 62 31-130 bis(2-Chloroethoxy)methane ug/kg ND 2050 1250 61 30-130 bis(2-Chloroethyl) ether ug/kg ND 2050 1330 65 68-130 M1 bis(2-Ethylhexyl)phthalate ug/kg ND 2050 1220 59 40-130 Butylbenzylphthalate ug/kg ND 2050 1260 61 40-130 Chrysene ug/kg ND 2050 1370 67 30-130 Di-n-butylphthalate ug/kg ND 2050 1240 60 41-130 Di-n-octylphthalate ug/kg ND 2050 1260 61 42-130 Dibenz(a,h)anthracene ug/kg ND 2050 1160 57 27-130 Dibenzofuran ug/kg ND 2050 1330 65 32-130 Diethylphthalate ug/kg ND 2050 1340 66 40-130 Dimethylphthalate ug/kg ND 2050 1380 67 37-130 Fluoranthene ug/kg ND 2050 1380 67 26-130 Fluorene ug/kg ND 2050 1290 63 31-130 Hexachloro-1,3-butadiene ug/kg ND 2050 1140 55 20-130 Hexachlorobenzene ug/kg ND 2050 1220 59 29-130 Hexachlorocyclopentadiene ug/kg ND 2050 432 21 10-130 v3 Hexachloroethane ug/kg ND 2050 1130 55 21-130 Indeno(1,2,3-cd)pyrene ug/kg ND 2050 1190 58 28-130 Isophorone ug/kg ND 2050 1300 63 32-130 N-Nitroso-di-n-propylamine ug/kg ND 2050 1290 63 31-130 N-Nitrosodimethylamine ug/kg ND 2050 1280 62 20-130 N-Nitrosodiphenylamine ug/kg ND 2050 1230 60 32-130 Naphthalene ug/kg ND 2050 1200 59 30-130 Nitrobenzene ug/kg ND 2050 1330 65 25-130 Pentachlorophenol ug/kg ND 4100 2570 62 10-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: PARK POINT GRASS AREA Pace Project No.: 92499316 MATRIX SPIKE SAMPLE: Parameter 3031500 Units 92499114004 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers Phenanthrene ug/kg ND 2050 1310 64 34-130 Phenol ug/kg ND 2050 1330 65 14-130 Pyrene ug/kg ND 2050 1280 62 31-130 Pyridine ug/kg ND 2050 339J 17 10-130 2,4,6-Tribromophenol (S) % 80 18-130 2-Fluorobiphenyl (S) % 67 19-130 2-Fluorophenol (S) % 70 18-130 Nitrobenzene-d5 (S) % 71 21-130 Phenol-d6 (S) % 73 18-130 Terphenyl-d14 (S) % 71 15-130 SAMPLE DUPLICATE: 3031501 Parameter Units 92499114005 Result Dup Result RPD Max RPD Qualifiers 1,2,4-Trichlorobenzene ug/kg ND ND 30 1,2-Dichlorobenzene ug/kg ND ND 30 1,3-Dichlorobenzene ug/kg ND ND 30 1,4-Dichlorobenzene ug/kg ND ND 30 1-Methylnaphthalene ug/kg ND ND 30 2,2'-Oxybis(1-chloropropane) ug/kg ND ND 30 2,4,5-Trichlorophenol ug/kg ND ND 30 2,4,6-Trichlorophenol ug/kg ND ND 30 2,4-Dichlorophenol ug/kg ND ND 30 2,4-Dimethylphenol ug/kg ND ND 30 2,4-Dinitrophenol ug/kg ND ND 30 2,4-Dinitrotoluene ug/kg ND ND 30 2,6-Dinitrotoluene ug/kg ND ND 30 2-Chloronaphthalene ug/kg ND ND 30 2-Chlorophenol ug/kg ND ND 30 2-Methylnaphthalene ug/kg ND ND 30 2-Methylphenol(o-Cresol) ug/kg ND ND 30 2-Nitroaniline ug/kg ND ND 30 2-Nitrophenol ug/kg ND ND 30 3&4-Methyl phenol (m&p Cresol) ug/kg ND ND 30 3,3'-Dichlorobenzidine ug/kg ND ND 30 3-Nitroaniline ug/kg ND ND 30 4,6-Dinitro-2-methyl phenol ug/kg ND ND 30 4-Bromophenylphenyl ether ug/kg ND ND 30 4-ChIoro-3-methyl phenol ug/kg ND ND 30 4-Chloroaniline ug/kg ND ND 30 4-Chlorophenylphenyl ether ug/kg ND ND 30 4-Nitroaniline ug/kg ND ND 30 4-Nitrophenol ug/kg ND ND 30 Acenaphthene ug/kg ND ND 30 Acenaphthylene ug/kg ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 36 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: PARK POINT GRASS AREA Pace Project No.: 92499316 SAMPLE DUPLICATE: 3031501 Parameter Aniline Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Benzoic Acid Benzyl alcohol bis(2-Chloroethoxy)methane bis(2-Chloroethyl) ether bis(2-Ethylhexyl)phthalate Butylbenzylphthalate Chrysene Di-n-butylphthalate Di-n-octylphthalate Dibenz(a,h)anthracene Dibenzofuran Diethylphthalate Dimethylphthalate Fluoranthene Fluorene Hexachloro-1,3-butadiene Hexachlorobenzene Hexachlorocyclopentadiene Hexachloroethane Indeno(1,2,3-cd)pyrene Isophorone N-Nitroso-di-n-propylamine N-Nitrosodimethylamine N-Nitrosodiphenylamine Naphthalene Nitrobenzene Pentachlorophenol Phenanthrene Phenol Pyrene Pyridine 2,4,6-Tribromophenol (S) 2-Fluorobiphenyl (S) 2-Fluorophenol(S) Nitrobenzene-d5 (S) Phenol-d6 (S) Terphenyl-d14 (S) QUALITY CONTROL DATA Units 92499114005 Dup Result Result ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND ug/kg ND % 65 % 59 72 74 73 % 51 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 68 60 65 69 68 55 Max RPD RPD 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 v2 30 30 30 30 30 30 30 30 30 30 30 30 30 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: PARK POINT GRASS AREA Pace Project No.: 92499316 QC Batch: 571656 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92499316001, 92499316002, 92499316003, 92499316004 SAMPLE DUPLICATE: 3027940 92499021001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 4.1 4.9 17 25 SAMPLE DUPLICATE: 3027941 92499248001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 83.5 83.1 1 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: PARK POINT GRASS AREA Pace Project No.: 92499316 QC Batch: 1561959 Analysis Method: SM 2540G QC Batch Method: SM 2540 G Analysis Description: Total Solids 2540 G-2011 Laboratory: Pace National - Mt. Juliet Associated Lab Samples: 92499316001 METHOD BLANK: R3583803-1 Matrix: Solid Associated Lab Samples: 92499316001 Blank Reporting Parameter Units Result Limit Total Solids % ND LABORATORY CONTROL SAMPLE: R3583803-2 Spike LCS Parameter Units Conc. Result Total Solids % 50.0 50.0 SAMPLE DUPLICATE: R3583803-3 Dup Parameter Units Result Result Total Solids % 95.4 MDL Analyzed Qualifiers 10/20/20 13:48 LCS % Rec % Rec Limits Qualifiers 100 85.0-115 Max RPD RPD Qualifiers 0.0667 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 39 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: PARK POINT GRASS AREA Pace Project No.: 92499316 QC Batch: 1559988 Analysis Method: EPA 7199 QC Batch Method: 3060A Analysis Description: Wet Chemistry 7199 Laboratory: Pace National - Mt. Juliet Associated Lab Samples: 92499316001 METHOD BLANK: R3583525-1 Matrix: Solid Associated Lab Samples: 92499316001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chromium, Hexavalent mg/kg ND 1.00 0.255 10/20/20 14:27 LABORATORY CONTROL SAMPLE: R3583525-2 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chromium, Hexavalent mg/kg 10.0 9.28 92.8 80.0-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: R3583525-4 R3583525-5 MS MSD L1273091-03 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chromium, Hexavalent mg/kg ND 22.7 22.7 14.9 15.0 65.7 66.0 75.0-125 0.530 20 ML MATRIX SPIKE SAMPLE: R3583525-6 L1273091-03 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Chromium, Hexavalent mg/kg ND 738 612 83.0 75.0-125 SAMPLE DUPLICATE: R3583525-8 L1274408-06 Dup Max Parameter Units Result Result RPD RPD Qualifiers Chromium, Hexavalent mg/kg ND ND 0.00 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 40 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: PARK POINT GRASS AREA Pace Project No.: 92499316 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. ANALYTE QUALIFIERS BC The same analyte was detected in an associated blank at a concentration above 1/2 the reporting limit but below the laboratory reporting limit. C8 Result may be biased high due to carryover from previously analyzed sample. IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. ML Matrix spike recovery and/or matrix spike duplicate recovery was below laboratory control limits. Result may be biased low. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. Page 41 of 45 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: PARK POINT GRASS AREA Pace Project No.: 92499316 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92499316001 PP-GA-1 EPA 3050B 571871 EPA 6010D 572005 92499316002 PP-GA-2 EPA 3050B 571871 EPA 6010D 572005 92499316003 PP-GA-3 EPA 3050B 571871 EPA 6010D 572005 92499316004 PP-GA-4 EPA 3050B 571871 EPA 6010D 572005 92499316001 PP-GA-1 EPA 7471 B 571883 EPA 7471 B 571993 92499316002 PP-GA-2 EPA 7471 B 571883 EPA 7471 B 571993 92499316003 PP-GA-3 EPA 7471 B 571883 EPA 7471 B 571993 92499316004 PP-GA-4 EPA 7471 B 571883 EPA 7471 B 571993 92499316001 PP-GA-1 EPA 3546 572372 EPA 8270E 572465 92499316002 PP-GA-2 EPA 3546 572372 EPA 8270E 572465 92499316003 PP-GA-3 EPA 3546 572372 EPA 8270E 572465 92499316004 PP-GA-4 EPA 3546 572372 EPA 8270E 572465 92499316001 PP-GA-1 EPA 5035A/5030B 571919 EPA 8260D 572075 92499316002 PP-GA-2 EPA 5035A/5030B 571919 EPA 8260D 572075 92499316003 PP-GA-3 EPA 5035A/5030B 571919 EPA 8260D 572075 92499316004 PP-GA-4 EPA 5035A/5030B 571919 EPA 8260D 572075 92499316001 PP-GA-1 ASTM D2974-87 571656 92499316002 PP-GA-2 ASTM D2974-87 571656 92499316003 PP-GA-3 ASTM D2974-87 571656 92499316004 PP-GA4 ASTM D2974-87 571656 92499316001 PP-GA-1 SM 2540 G 1561959 SM 254OG 1561959 92499316001 PP-GA-1 3060A 1559988 EPA 7199 1559988 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/27/2020 12:33 PM without the written consent of Pace Analytical Services, LLC. 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O E �SauJio�aOr u v °a m a o °1 °1 m a In K tY U a a` a c m Fsz„off o e8 � �a-33a�na;d5r v � c> E W a m 5 g J c 2 Yqm (� o i E z c v o ooj O p 0 v a 2 z # wall C u Q m E y L a m m a N Page 45c na�a away f 45 APPENDIX 6 RISK CALCULATION WORKSHEETS 0 Mid Atlantic North Carolina Department of Environmental Quality Risk Calculator Version Date: July 2020 Basis: May 2020 EPA RSL Table Site Name: Northern Telecom Site Address: 4001 and 4151 East NC Hwy 54, Durham, NC DEQ Section: Brownfields Site ID: Brownfields Project No. 23079-19-032; MAA Project No. R3358.01 Exposure Unit ID: Max Concentrations of Site Stockpile and Grass Area Sampling Submittal Date: 10/16/2020 Prepared By: Katie Lippard Reviewed B North Carolina DEQ Risk Calculator Point Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: Brownfields Project No. 23079-19-032; MAA Project No. R3358.01 Exposure Unit ID: Max Concentrations of Site Stockpile and Grass Area S, Description of Exposure Point Concentration Selection: Exposure Point Minimum Maximum Location of Concentration Screening Potential Potential COPC Rationale for Detection Range of Background Toxicity ValueARAR/TBC Concentration Notes: CAS Number Chemical Concentration Concentration Units Maximum Used for ARAR/TBC Flag Selection or (mg/kg) (Qualifier) (Qualifier) Concentration Frequency Detection Limits Screening Value (Screening Value Source (YQN) Deletion Level) (n/c) 4.8 7440-38-2 Arsenic, Inorganic mg/kg 280 1 7440-39-3 Barium — kg 0.14 7440-43-9 Cadmium (Diet) mg/kg 33.9 16065-83-1 Chromium III , Insoluble Salts — kg 0 18540-29-9 Chromium(VI) mg/kg 15.5 7439-92-1 Lead and Compounds — kg 0.0088 7439-97-6 —Mercury (elemental) mg/kg 0.83 7782-49-2 Selenium mg/kg North Carolina DEQ Risk Calculator Risk for Individual Pathways rim Version Date: July 2020 Basis: May 2020 EPA RSL Table 7 Site ID: Brownfields Project No. 23079-19-032; MAA Project No. R3358.01 Exposure Unit ID: Max Concentrations of Site Stockpile and Grass Area Sampling DIRECT CONTACT SOIL AND WATER CALCULATORS Receptor Pathway CarcinogenicHazard Risk Index Risk exceeded`. Resident Soil 7.1E-06 1.6E-01 NO NC Groundwater Use* NC NC Non -Residential Worker Soil 1.6E-06 1.2E-02 NO Groundwater Use* NC NC NC Construction Worker Soil NC NC NC Recreator/Trespasser Soil NC NC NC Surface Water* NC NC NC VAPOR INTRUSION CALCULATORS ff Receptor Pathway CarcinogenicRisk Hazard Index Risk exceeded? Resident Groundwater to Indoor Air 0.0E+00 0.0E+00 NO Soil Gas to Indoor Air 0.0E+00 0.0E+00 NO Indoor Air 0.0E+00 0.0E+00 NO Non -Residential Worker Groundwater to Indoor Air 0.0E+00 0.0E+00 NO Soil Gas to Indoor Air 0.0E+00 0.0E+00 NO Indoor Air 0.0E+00 0.0E+00 NO CONTAMINANT MIGRATION CALCULATORS Pathway Source Target Receptor Concentrations Exceeded? Groundwater Source Soil Exceedence of 21, at Receptor? NM Source Groundwater Exceedence of 21, at Receptor? NM Surface Water Source Soil Exceedence of 2B at Receptor? NM Source Groundwater Exceedence of 2B at Receptor? NM Notes: 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk -based closure. 3. NM = Not Modeled 4. NC = Pathway not complete North Carolina DEQ Risk Calculator NorU Carolina DEO Rlak Calculabr