HomeMy WebLinkAbout22047_University Place Mall_LSI_20210806for
August 6, 2021
Chick-fil-A, Inc.
5200 Buffington Road
Atlanta, GA 30349
Attn: Mr. Nate Thompson
E: nate.thompson@cfacorp.com
Re: Limited Site Investigation
Proposed Chick-fil-A #04954
201 South Estes Drive
Chapel Hill, Orange County, North Carolina
Terracon Project No. 70217369
Dear Mr. Thompson:
Irerracon
At your request, Terracon Consultants, Inc. (Terracon) has completed a Limited Site Investigation
(LSI) at the above -referenced property. This investigation was performed in accordance with
Terracon Proposal No. P70217369, dated May 19, 2021, and authorized June 15, 2021.
If you have any questions or comments pertaining to the material presented herein, please contact
r:he undersigned at 919-873-2211.
13incerely,
'1 Terracon
:_:than C. Dinwiddie
13taff Geologist
ris Sroc
Senior Principal
J/nL/.abriziani, R S M
Environmental Department Manager
Adam A. Lee, P.G.
Senior Geologist
"'•N CAA
�• y��,.....w.
Z:
?: SEAL 9 s
"_. 2716
I''I�,ANnREyJ.••••
Terracon Consultants, Inc. 2401 Brentwood Road Suite 107 Raleigh, NC 27604
P [919] 873 2211 F [919] 873 9555 terracon.com
RED
Limited Site Investigation
Proposed Chick-fil-A #04954
201 South Estes Drive
Chapel Hill, Orange County, North Carolina
August 6, 2021
Terracon Project No. 70217369
Prepared for:
Chick-fil-A, Inc.
Atlanta, Georgia
Prepared by:
Terracon Consultants, Inc.
Raleigh, North Carolina
TABLE OF CONTENTS
1.0 INTRODUCTION.......................................................................................................1
1.1
Standard of Care...................................................................................................1
1.2
Additional Scope Limitations..................................................................................2
1.3
Reliance................................................................................................................2
2.0 FIELD ACTIVITIES...................................................................................................2
2.1 Private Utility Location........................................................................................... 2
2.2 Soil Assessment....................................................................................................3
2.3 Groundwater Assessment...................................................................................... 3
2.4 Soil Vapor Assessment..........................................................................................4
3.0 RESULTS.................................................................................................................5
3.1
Soil Analytical Results........................................................................................... 5
3.2
Groundwater Analytical Results.............................................................................6
3.3
Soil Vapor Analytical Results................................................................................. 6
4.0
FINDINGS AND CONCLUSIONS.............................................................................6
5.0
RECOMMENDATIONS.............................................................................................7
6.0 REFERENCES..........................................................................................................7
EXHIBITS
Exhibit 1 Topographic Vicinity Map
Exhibit 2 Sample Location Map
TABLES
Table 1 Temporary Well Construction Summary
Table 2 Summary of Soil Analytical Results
Table 3 Summary of Groundwater Analytical Results
Table 4 Summary of Soil Vapor Analytical Results
APPENDICES
Appendix A Lithology Logs
Appendix B Photo Log
Appendix C Laboratory Analytical Report and Chain -of -Custody Records
Responsive ■ Resourceful ■ Reliable
LIMITED SITE INVESTIGATION
PROPOSED CHICK-FIL-A #04954
201 SOUTH ESTES DRIVE
CHAPEL HILL, ORANGE COUNTY, NORTH CAROLINA
TERRACON PROJECT NO. 70217369
1.0 INTRODUCTION
Terracon Consultants, Inc. (Terracon) has completed a Limited Site Investigation (LSI) of the
proposed Chick-fil-A #04954 restaurant located at 201 South Estes Drive in Chapel Hill, Orange
County, North Carolina (site). According to client provided information and the Orange County
GIS website, the site consists of an approximate 1.3-acre portion of a 38.39-acre parcel (Orange
County Parcel ID: 9799220604) (Terracon, 2021). A topographic map is included as Exhibit 1.
The location of the site is shown on Exhibit 2.
Terracon previously completed a Phase I Environmental Site Assessment (ESA) of the site
(Terracon Project No.: 70217309, dated May 17, 2021). Terracon identified the following
recognized environmental condition (REC) associated with the site:
Based on 2020 groundwater sampling results (AECOM Technical Services of NC, Inc.
[AECOM], 2020), tetrachloroethene (PCE) was detected in groundwater in monitoring
wells near the northern site boundary associated with the American Dry Cleaners Dry -
Cleaning Solvent Cleanup Act Program (DSCA) incident. PCE was detected in monitoring
wells MW-1 (located approximately 20 feet north) and 2W-6 (located approximately 100
feet northwest) at concentrations of 0.738 micrograms per liter (pg/L) and 160 pg/L,
respectively (Exhibit 2).
Additionally, the parent tract has been granted eligibility into the North Carolina Brownfield
Program due to the on -site DSCA incident and petroleum contamination from an on -site
automotive repair garage (Chapel Hill Tire, Incident #46402). At the time of this report, a finalized
Brownfields Agreement including land -use restrictions was not in place; however, a Notice of
Residual Petroleum (NORP) was recorded for the property on January 23, 2020 due to the
petroleum contamination at the Chapel Hill Tire facility. The NORP implemented an
industrial/commercial use only land -use restriction of soil. Further land -use restrictions may be
implemented when the Brownfields Agreement is finalized.
The purpose of the investigation was to evaluate subsurface conditions in soil, groundwater, and
soil vapor with respect to the potential presence of chlorinated solvent constituents. The scope of
work is not intended to provide complete delineation or develop corrective action costs.
1.1 Standard of Care
Terracon's services were performed in a manner consistent with generally accepted practices of
the profession undertaken in similar studies in the same geographical area during the same time.
Responsive ■ Resourceful ■ Reliable 1
Limited Site Investigation Report
Proposed Chick-fil-A #04954 Chapel Hill, North Carolina Irerracon
August 6, 2021 Terracon Project No. 70217369
Terracon makes no warranties, either express or implied, regarding the findings, conclusions, or
recommendations. Please note that Terracon does not warrant the work of laboratories,
regulatory agencies, or other third parties supplying information used in the preparation of the
report. These LSI services were performed in accordance with the scope of work agreed with you,
our client, as reflected in our proposal and were not restricted by ASTM E1903-11.
1.2 Additional Scope Limitations
Findings, conclusions, and recommendations resulting from these services are based upon
information derived from the on -site activities and other services performed under this scope of
work; such information is subject to change over time. Certain indicators of the presence of
hazardous substances, petroleum products, or other constituents may have been latent,
inaccessible, unobservable, non -detectable, or not present during these services. We cannot
represent that the site contains no hazardous substances, toxic materials, petroleum products, or
other latent conditions beyond those identified during this LSI. Subsurface conditions may vary
from those encountered at specific borings or wells or during other surveys, tests, assessments,
investigations, or exploratory services. The data, interpretations, findings, and our
recommendations are based solely upon data obtained at the time and within the scope of these
services.
1.3 Reliance
The LSI report has been prepared for the exclusive use and reliance of Chick-fil-A, Inc. (client).
Reliance by any other party is prohibited without the written authorization of the client and
Terracon. Reliance on the LSI by the client and all authorized parties will be subject to the terms,
conditions, and limitations stated in the Supplemental to Agreement for Services, sections of this
proposal incorporated therein, the Reliance Agreement (if applicable), and the LSI report. The
defined contractual limitation of liability is the aggregate limit of Terracon's liability to the client
and all relying parties.
2.0 FIELD ACTIVITIES
Field activities were conducted on July 9, 2021. Activities included boring layout, private utility
location, advancement of soil borings and temporary monitoring wells, and sampling of soil,
groundwater, and soil vapor. Prior to LSI drilling operations, public utility locators were notified via
811 call.
2.1 Private Utility Location
Terracon personnel performed a utility locate survey in the vicinity of the borings. Subsurface
utility lines were marked and cleared prior to drilling activities.
Responsive ■ Resourceful ■ Reliable 2
Limited Site Investigation Report
Proposed Chick-fil-A #04954 Chapel Hill, North Carolina Irerracon
August 6, 2021 Terracon Project No. 70217369
2.2 Soil Assessment
Three soil borings (TW-01 through TW-03) were advanced via direct -push technology (DPT) and
auger rotary methods using a track -mounted GeoProbeTm drill rig in the northern portion of the
site (Exhibit 2). Soils were logged to document soil type, relative moisture content, and other
lithologic characteristics. Soil samples collected via DPT methods were screened for organic
vapors using a photoionization detector (PID). Solid stem augers were used to advance the
borings after DPT refusal occurred at depths between 7 and 12.5 feet bls. Borings were
terminated at approximately 30 feet below land surface (bls) after saturated soil conditions were
encountered. Soil boring logs are included in Appendix A.
Soil samples were selected for laboratory analysis based on PID results and/or were selected
from the depth interval with the highest potential for impact above the water table (i.e. shallow
soils). One soil sample was collected from each boring at depths between 2 and 7 feet bls or at
least five feet above the measured water table.
Each soil sample was placed into laboratory supplied containers, packed in ice, and shipped to
Pace Analytical° Laboratory (Pace) in Mt. Juliet, Tennessee and analyzed for chlorinated volatile
organic compounds (VOCs) via United States Environmental Protection Agency (USEPA) Method
8260D.
Non -dedicated sampling equipment was decontaminated using a Liquinox®/water wash followed
by a distilled water rinse prior to use and between borings. Temporary investigation locations
were backfilled with bentonite and abandoned in accordance with applicable state requirements.
2.3 Groundwater Assessment
Temporary wells (TW-01 to TW-03) were installed within the advanced soil boring locations.
Temporary well construction details are summarized on Table 1 and were constructed as follows:
Installation of a 15-foot section of 2-inch diameter, 0.010-inch machine slotted PVC
well screen;
Installation of a 2-inch diameter, threaded, flush -joint PVC riser pipe to the ground
surface; and
Addition of pre -sieved 20/40 grade silica sand for annular sand pack around the
well screen from the bottom of the boring to approximately 2-feet above the top of
the well screen.
Prior to purging the temporary wells, the depth to groundwater was measured relative to the top
of the temporary well casing and converted to depth bls. Water depths range from 8.33 to 28.03
feet bls (Table 1). The temporary monitoring wells were developed, then purged using peristaltic
pumps and disposable tubing. Low flow purging and sampling techniques (i.e., <200 milliliters
per minute) were used for each well to collect representative samples, reduce turbidity, and
Responsive ■ Resourceful ■ Reliable 3
Limited Site Investigation Report
Proposed Chick-fil-A #04954 Chapel Hill, North Carolina Irerracon
August 6, 2021 Terracon Project No. 70217369
minimize purge water volumes. The groundwater samples were collected after stabilization of
field parameters (e.g., pH and specific conductance). Each sample was placed into laboratory
supplied containers, packed in ice, and shipped to Pace Laboratories for analysis of chlorinated
VOCs via USEPA Method 8260D.
Drilling equipment and non -dedicated sampling equipment was decontaminated prior to use and
between borings using a Liquinox®/water wash followed by a distilled water rinse. Temporary
investigation locations were backfilled with bentonite and abandoned in accordance with
applicable state requirements.
2.4 Soil Vapor Assessment
Two temporary sub -slab soil vapor sampling points (SV-01 and SV-02) were installed within the
existing on -site building and within the proposed building location. The sub -slab soil vapor
sampling points were installed by using a handheld rotary hammer to drill a hole through the
concrete floor slab of the building and inserting a sub -slab soil vapor sampling port (VaporPinTM)
into the hole. Each soil vapor point was allowed to equilibrate for a minimum of 2 hours after
installation and leak tested prior to sampling to ensure that the points were properly sealed, thus
preventing indoor air from entering the point during sampling. Sampling locations are displayed
in Exhibit 2. Sampling methodology for the shallow soil vapor sampling is described in the
following paragraphs.
Shut -In Test
Prior to connection of the sampling equipment to the soil vapor sample point, a shut-in (dead-
head) test was conducted to check for leaks in the aboveground purge/sampling manifold. A
sampling train consisting of a batch certified 1-liter Summa canisterfor sample collection (sample
canister) connected to a critical orifice flow restrictor (flow controller). The sampling train influent
was capped, the sampling canister remained closed, and a negative pressure reading of at least
15 inches of mercury was induced on the sampling train pressure gauge. The pressure gauge
was then observed for losses in vacuum. If there was an observable loss of vacuum, the fittings
were adjusted until the vacuum in the sample train did not noticeably dissipate.
Helium Tracer Test
Following the shut-in test, the purge/sampling train was connected to the soil gas sampling point
and a helium tracer gas leak test was conducted. The tracer gas serves as a quality
assurance/quality control (QA/QC) method to verify the integrity of the sampling train seal to the
sample point. An MGD-2002 helium detector was used to verify the presence and concentration
of tracer gas.
The protocol for using a tracer gas is to enclose the sampling train and sample point outlet with a
shroud, enrich the shroud atmosphere with at least 10 percent helium. The purging device
(syringe and/or hand pump) was situated outside of the shroud connected with the sampling train
by Teflon° lined tubing running through the shroud. A minimum of three volumes was evacuated
Responsive ■ Resourceful ■ Reliable 4
Limited Site Investigation Report
Proposed Chick-fil-A #04954 Chapel Hill, North Carolina Irerracon
August 6, 2021 Terracon Project No. 70217369
from the sample point. Purged soil gas was screened for helium to assess for leaks in the
sampling point seal and with a PID to assess for VOCs. The shroud helium concentration and the
helium concentration in the purged soil vapor was documented after each volume purged.
The sampling train and vapor monitoring point connection was considered to be sufficiently sealed
when helium concentrations were less than ten percent of the helium concentration in the shroud.
Each point had a concentration of less than ten percent of the helium concentration in the shroud.
Soil Vapor Sample Collection
Following the helium leak test, the valve to the purge device was closed and the sample canister
valve was opened to initiate collection of soil vapor for laboratory analysis. The sample was
collected at a flow rate of approximately 200 milliliters per minute. The sample canister valve was
closed when the gauge measured approximately five to nine inches of mercury (Hg) vacuum. The
canisters were packaged and delivered along with chain of custody documentation to Pace for
analysis of chlorinated VOCs via USEPA Method TO-15.
3.0 RESULTS
Soils at the site were observed to consist primarily of sand and silt/siltstone. Groundwater at the
site was inferred to flow to the east based on topography. Groundwater elevations and a true
groundwater flow direction at the site were not determined. Groundwater flow at the former
American Drycleaners facility, located approximately 200 feet northwest of the site, was estimated
to flow to the southeast (AECOM, 2020). Site lithology was documented in boring logs provided
in Appendix A. Site photographs documenting field activities and site conditions are provided in
Appendix B. The laboratory analytical reports are provided in Appendix C.
3.1 Soil Analytical Results
Soil sample analytical results were compared with the North Carolina Department of
Environmental Quality (NCDEQ) Residential and Industrial/Commercial Preliminary Soil
Remediation Goals (PSRGs).
Results of soil sample analytical results are as follows:
Cis-1,2-dichloroethene (cis-1,2-DCE) was detected below its Residential and
Industrial/Commercial PSRG in TW-03.
Additional chlorinated VOCs were not detected in the soil samples.
The soil analytical results are summarized in Table 2.
Responsive ■ Resourceful ■ Reliable 5
Limited Site Investigation Report
Proposed Chick-fil-A #04954 Chapel Hill, North Carolina Irerracon
August 6, 2021 Terracon Project No. 70217369
3.2 Groundwater Analytical Results
Groundwater sample analytical results were compared with North Carolina Administrative Code
2L Groundwater Quality Standards (2L standards). Results of groundwater sample analytical
results are as follows:
cis-1,2-DCE, tetrachloroethene (PCE), trichloroethene (TCE), and vinyl chloride were
detected above the 2L standards in TW-03.
cis-1,2-DCE and trans- 1,2-dichloroethene (trans-1,2-DCE) were detected below the 2L
standards TW-02 and TW-03, respectively.
Additional chlorinated solvent VOCs were not detected in the groundwater samples.
The groundwater analytical results are summarized on Table 3.
3.3 Soil Vapor Analytical Results
Soil vapor sample analytical results were compared with NCDEQ Residential and Non -Residential
Sub -Slab Soil Gas Screening Levels (SGSLs) and are summarized as follows:
None of the chlorinated VOCs analyzed were reported to be above the Non -Residential
SGSL.
Chloroform and tetrachloroethene were detected above the Residential SGSL, but not
above the Non -Residential SGSL in SV-02.
Additional chlorinated solvent VOCs were detected below the Residential and Non -
Residential SGSLs in SV-01 and SV-02.
Soil vapor analytical results are summarized on Table 4.
4.0 FINDINGS AND CONCLUSIONS
The findings and conclusions of this investigation are as follows:
The site is part of a larger parcel (parent tract) that has been impacted by a release of dry-
cleaning solvents and petroleum. A NORP has been recorded for the petroleum release
incident (Incident #46402) and implemented an industrial/commercial use only land -use
restriction for on -site soil. The parent tract has also been granted eligibility into the NC
Brownfield Program. When a finalized Brownfields Agreement is in place, it will likely include
further land -use restrictions on the property.
Chlorinated VOCs were not detected above the Residential or Industrial/Commercial
PSRGs in the soil samples. Based on the depth to groundwater, impacted soils are not
anticipated within the shallow onsite soils likely to be disturbed as part of construction.
Responsive ■ Resourceful ■ Reliable
Limited Site Investigation Report
Proposed Chick-fil-A #04954 Chapel Hill, North Carolina Irerracon
August 6, 2021 Terracon Project No. 70217369
Based on the NORP, industrial/commercial use only land -use restrictions were implemented
for on -site soil; however, a soil management plan is not in place for the property.
Cis-1,2-DCE, PCE, TCE, and vinyl chloride were detected in groundwater samples above
the 2L standards in TW-03. Additional chlorinated VOCs were not detected above the 2L
standards in the groundwater samples.
Chloroform and PCE were detected in sub -slab soil gas samples above the Residential
SGSL, but not above the Non -Residential SGSL in SV-02. The chloroform likely is
associated with potable water use and is not considered to be a constituent of concern.
Additional chlorinated VOCs were not detected above the Residential or Non -Residential
SGSL in the soil vapor samples.
5.0 RECOMMENDATIONS
Based on the results of this investigation, Terracon recommends the following:
Based on the observed site groundwater and soil vapor concentrations, Terracon
recommends that the property owner report the detections to the NCDEQ Brownfields
Program. Since the site is located on a NCDEQ Brownfields Program property, an
approved Environmental Management Plan may be required by NCDEQ prior to
construction activities, which could include installation of a vapor mitigation system or
further soil vapor evaluation based on NCDEQ Brownfields Program comment.
Terracon does not recommend further assessment of groundwater or soil vapor based
on the proposed commercial use of the site without input from the NCDEQ Brownfields
Program.
6.0 REFERENCES
AECOM Technical Services of North Carolina, Inc., 2020. Soil Gas and Groundwater Monitoring
Report, American Drycleaners, DSCA Site ID #DC68-002. September 24.
North Carolina Department of Environmental Quality (NCDEQ), 2021 a. Non -Residential Vapor
Intrusion Screening Levels. January 2021.
NCDEQ, 2021 b. Residential Vapor Intrusion Screening Levels. January 2021.
NCDEQ, 2021 c. Preliminary Soil Remediation Goals. June 2021.
Terracon, 2021. Phase I Environmental Site Assessment: Proposed Chick-fil-A #04954 -
University Place. Terracon Project No. 70217309. May 17.
Responsive ■ Resourceful ■ Reliable
EXHIBITS
0 Gill
1�•'1 1
■
NFormerAmerican
Dry Cleaners Location
201 South Estes Drive
(Drycleaners, RCRA-SQG,
DSCA)
2W-6
' _
°I
The 01MT 'Binkley. -
Memorial a tist,Church
s 1712 Willow Drive
A.
MW-1
W-03
wo
( _S SV-02
fit
~�....�CJ
?t
0
� t
University Plaza Mall Building
201 South Estes Drive ,
(Brownfields)
Legend
�� El
-$� DSCA Impacted Monitoring Well
A Sub -slab Soil Vapor Point
Temporary Monitoring Well/Soil Boring Note: ,
Adjacent impacted permanent monitoring .�
Proposed Building Footprint wells MW-1 and 2W-6 from the American
Dry cleaners DSCA site investigations are 4
rl = ISite Boundary shown for reference. These monitoring 0 50 �00
wells were not sampled during this Limited
0 Orange County Parcel Boundary Site Investigation.
PM: Project No.
JLF 70217369
Drawn By: Scale: Irerracon
ECD 1 inch = 100 fee
Checked By: File Path:
JLF Site Diagram
Approved By: Date: 2401 Brentwood Road, Suite 107 Raleigh, NC 27604
CSS 8/3/2021 phone: (919) 873-2211 Fax: (919) 873-9555
Path: N:\GIS\2021\70217369_CFA_Chapel Hill LSI\Exhibit2-SiteDiagram.mxd
Site Diagram
Limited Site Investigation
Proposed Chick-fil-A Store #04954
201 South Estes Drive
Chapel Hill, Orange County, North Carolina
200
m Feet
EXHIBIT
NO.
2
TABLES
Table 1
Temporary Well Construction Summary
Proposed Chick-fil-A #04954
201 South Estes Drive, Chapel Hill, North Carolina
Terracon Project No. 70217369
Sample ID
Well
Construction
Total Depth
(feet bls)
Screen
(feet bls)
Sand
(feet bls)
Bentonite
(feet bls)
Water Depth
(feet bls)
TW-01
2" PVC
30
15-30
13-30
0-13
8.3
TW-02
2" PVC
30
15-30
13-30
0-13
26.1
TW-03
2" PVC
30
15-30
13-30
0-13
28.0
Notes:
Temporary monitoring wells abandoned on 7/9/21.
feet bls - feet below land surface.
PVC - polyvinyl chloride.
Table 2
Summary of Soil Analytical Results
Proposed Chick-fil-A #04954
201 South Estes Drive, Chapel Hill, North Carolina
Terracon Project No. 70217369
Sample ID:
TW-01
TW-02
TW-03
Industrial/Commercial
Sample Date:
7/9/21
7/9/21
7/9/21
PoG PSRG
Residential PSRG
PSRG
Collection Depth (ft bls):
2-3
6-7
6-7
Volatile Organic Compounds (chlorinated
ethenes only)
via EPA Method 8260D
cis-1,2-Dichloroethene
I < 0.000734
1 < 0.000734
1 0.0165
0.41
31
370
Notes:
Analytes detected in one or more samples are shown
Concentrations are reported in milligrams per kilograms (mg/kg)
Bold denotes concentration greater than the method detection limit.
ft bls: feet below land surface
< : not detected above laboratory method reporting limit
PSRG: Inactive Hazardous Sites Branch Preliminary Health -Based Soil Remediation Goal (January 2021)
PoG: Protection of Groundwater
Residential: Residential Unrestricted -Use
Industrial/Commercial: Industrial/Commercial Restricted -Use
Table 3
Summary of Groundwater Analytical Results
Proposed Chick-fil-A #04954
201 South Estes Drive, Chapel Hill, North Carolina
Terracon Project No. 70217369
Sample ID:
Screen Interval (ft bls)
Sample Collection Date:
TW-01
15-30
7/9/21
TW-02
15-30
7/9/21
TW-03
15-30
7/9/21
TB-01
--
2L Standard
Volatile Organic Compounds (chlorinated
ethenes
only) via EPA
Method 8260D
cis-1,2-Dichloroethene
< 0.126
0.227 J
103 < 0.126
70
Tetrachloroethene
< 0.300
< 0.300
67.9 < 0.300
0.7
trans-1,2-Dichloroethene
< 0.149
< 0.149
0.906 J < 0.149
100
Trichloroethene
< 0.190
< 0.190
27.1 < 0.190
3.0
Vinyl chloride
I < 0.234
1 < 0.234
1.19 < 0.234
0.03
Notes:
Concentrations are reported in micrograms per liter (µg/Q.
Compounds detected compounds in one or more samples are shown in the table.
Bold denotes concentration greater than the method detection limit.
Shaded concentrations exceed the applicable screening level.
<: Compound was not detected above laboratory reporting limits.
2L Standard: 15A North Carolina Adminstrative Code 2L Groundwater Quality Standards, April 2013.
ft bls - feet below land surface.
J - Compound was detected at an estimated concentration below the laboratory reporting limit and above the method detection limit.
Table 4
Summary of Soil Vapor Analytical Results
Proposed Chick-fil-A #04954
201 South Estes Drive, Chapel Hill, North Carolina
Terracon Project No. 70217369
Sample ID:
Sample Date:
SV-01
7/9/21
SV-02
7/9/21
Residential
Sub -Slab SGSL
Non -Residential Sub
Slab SGSL
Volatile Organic Compounds (chlorinated
ethenes only)
via EPA Method
8260D
Chloroethane
< 0.528
8,600
70,000
880,000
Chloroform
< 0.973
17.5
4.1
53
1,1-Dichloroethane
< 0.802
0.802
58
770
Tetrachloroethene
11.9
550
280
3,500
Trichloroethene
< 1.07
1.23
14
180
Trichlorofluoromethane
1.44
8.71
NE
NE
Notes:
Concentrations are in micrograms per cubic meter (µg/m3).
Compounds detected in one or more samples are shown in the table.
Bold denotes concentration greater than the method detection limit.
Shaded concentrations exceed the applicable screening level.
Residential Sub -Slab SGSL: North Carolina Department of Environmental Quality (NCDEQ) Residential Sub-Slab/Exterior Soil Gas
Screen Level, January 2021.
Non -Residential Sub -Slab SGSL: NCDEQ Non -Residential Sub-Slab/Exterior Soil Gas Screen Level, January 2021.
NE: Not established
APPENDIX A
Lithology Logs
0
J
H
w
2
Z
0
z
w
WELL LOG NO. TW-01
Page 1 of 1
PROJECT: Proposed Chick-fil-A#04954
CLIENT: Chick-fil-A
Atlanta, Georgia
SITE: 201 South Estes Drive
Chapel Hill, North Carolina
C7
LOCATION See Exhibit 2
INSTALLATION DETAILS
Z
Iwa
z
OJ
x
>�
LU
o
w w
m
a
Q
w�
w
LU
>
a E
> a
LU
IL
IL
Well Completion:
o
w
0
O
~ p
O
Temporary Well
o
<
LU
<
DEPTH MATERIAL DESCRIPTION
1.0 ASPHALT AND AGGREGATE BASE COURSE
SAND (SW1, some silt, light brown, odor not observed, moist to wet
<0.1
<0.1
Grab
<0.1
48
<0.1
<0.1
5
<0.1
6.0
SANDY SILT (ML), reddish brown, odor not observed, dry
<0.1
<0.1
42
<0.1
<0.1
10
<0.1
<0.1
30
12.5
TW-01 (Soil
<0.1
x x
X x
SILTSTONE, reddish brown, odor not observed, moist, DPT refusal at 12.5 feet
>
x x
bls, switch to solid stem auger
and
X X
Groundwater)
x x
X X
X X
X X
X X
X X
X X
15
vocs 8260
X X
X X
X X
X X
X X
X X
X X
X X
X X
x x
x x
x x
20
x x
X X
X X
X X
X X
X X
X X
x x
x x
x x
x x
x x
x x
25
x x
x x
x x
x x
x X
30.0
30
Boring Terminated at 30 Feet
The stratification lines represent the approximate transition between differing soil types and/or rock types;
in -situ these transitions may be gradual or may occur at different depths than shown.
Advancement Method:
Notes:
DPT/SSA
ft bls: feet below land surface
DPT: Direct -push technology
SSA: Solid stem auger
VOCs: Volatile organic compounds
Abandonment Method:
Boring backfilled with bentonite chips upon completion.
WATER LEVEL OBSERVATIONS
Irerraconafter
Well Started: 07-09-2021
Well Completed: 07-09-2021
Groundwater measured at 8.33 feet bls
well installation
Drill Rig: Geoprobe 7822
Driller: Quantex
2401 Brentwood Rd Ste 107
Raleigh, NC
Project No.: 70217369
Appendix A
cD
0
J
H
w
2
Z
0
z
w
WELL LOG NO. TW-02
Page 1 of 1
PROJECT: Proposed Chick-fil-A#04954
CLIENT: Chick-fil-A
Atlanta, Georgia
SITE: 201 South Estes Drive
Chapel Hill, North Carolina
C7
LOCATION See Exhibit 2
INSTALLATION DETAILS
Z
Iwa
z
OJ
x
>�
o
w w
m
a
w�
>
> a
LU
IL
IL
Well Completion:
o
w
0
O
~ p
O
Temporary Well
o
<
LU
<
DEPTH MATERIAL DESCRIPTION
1.0 ASPHALT AND AGGREGATE BASE COURSE
SAND (SW1, some silt, light brown, odor not observed, moist to wet
0.3
0.2
48
0.1
0.1
0.1
5
0.1
°
6 0
SANDY SILT (ML), reddish brown, odor not observed, dry
Grab
0.1
48
0.1
9.0
0.1
x x
SILTSTONE (ML), reddish brown, odor not observed, moist, DPT refusal at 9 feet
X X
x x
x x
x x
x x
x x
bls, switch to solid stem auger
lo—
x x
x x
x x
x x
x x
x x
X X
1 5
TW-02 (Soil
X X
and
x x
x x >
Groundwater)
x x
x x
x x
x x
x x
VOCs 8260
x x
x x
x x
x x
x x
x x
x x
x x
x x
x x
20
x x
X X
X X
X X
X X
X X
X X
25
x x
x x
x x
x x
x x
x x
x x
x x
x x
x x
X X
30.0
30
Boring Terminated at 30 Feet
The stratification lines represent the approximate transition between differing soil types and/or rock types;
in -situ these transitions may be gradual or may occur at different depths than shown.
Advancement Method:
Notes:
DPT/SSA
ft bls: feet below land surface
DPT: Direct -push technology
SSA: Solid stem auger
VOCs: Volatile organic compounds
Abandonment Method:
Boring backfilled with bentonite chips upon completion.
WATER LEVEL OBSERVATIONS
Irerracon
Well Started: 07-09-2021
Well Completed: 07-09-2021
Groundwater measured at 26.10 feet bls after
well installation
Drill Rig: Geoprobe 7822
Driller: Quantex
2401 Brentwood Rd Ste 107
Raleigh, NC
Project No.: 70217369
Appendix A
cD
0
it
w
2
Z
0
z
w
WELL LOG NO. TW-03
Page 1 of 1
PROJECT: Proposed Chick-fil-A#04954
CLIENT: Chick-fil-A
Atlanta, Georgia
SITE: 201 South Estes Drive
Chapel Hill, North Carolina
C7
LOCATION See Exhibit 2
INSTALLATION DETAILS
Z
Iwa
z
OJ
x
>�
LU
o
w w
m
a
Q
w�
w
LU
>
a E
> a
LU
IL
IL
Well Completion:
o
w
0
O
~ p
O
Temporary Well
o
<
LU
<
DEPTH MATERIAL DESCRIPTION
1.0 ASPHALT AND AGGREGATE BASE COURSE
SAND (SW1, some silt, light brown, odor not observed, dry
0.2
<0.1
48
0.2
<0.1
5.0
5
<0.1
SANDY SILT (ML), reddish brown, odor not observed, dry
<0.1
24
Grab
<0,1
7.0
x x
SILTSTONE, reddish brown, odor not observed, moist, DPT refusal at 7 feet bls,
x x>
x x
x x
switch to solid stem auger
x x
x x
x x >
x x
lo—
x x
x x
x x
TW-03 (Soil
x x
and
x x >
Groundwater)
x x
x x
VOCs 8260
x x
x x
x x
x x
x x
x x
x x
15
x x
x x
x x
x x
x x
x x
<0.1
x x
x x >
x x
x x
x x
x x
x x
x x
20
x x
x x
x x
x x
x x
x x
x x
x x
x x
25
x x
x x
x x
x x
x x
x x
x x
x x
x x 130.0
30
Boring Terminated at 30 Feet
The stratification lines represent the approximate transition between differing soil types and/or rock types;
in -situ these transitions may be gradual or may occur at different depths than shown.
Advancement Method:
Notes:
DPT/SSA
ft bls: feet below land surface
DPT: Direct -push technology
SSA: Solid stem auger
VOCs: Volatile organic compounds
Abandonment Method:
Boring backfilled with bentonite chips upon completion.
WATER LEVEL OBSERVATIONS
Irerraconafter
Well Started: 07-09-2021
Well Completed: 07-09-2021
Groundwater measured at 28.03 feet bls
well installation
Drill Rig: Geoprobe 7822
Driller: Quantex
2401 Brentwood Rd Ste 107
Raleigh, NC
Project No.: 70217369
Appendix A
APPENDIX B
Photo Log
Limited Site Investigation
Proposed Chick-fil-A #04954 Chapel Hill, North Carolina
Photos Taken: July 9, 2021 Terracon Project No. 70217369
Photo #1 View of the former K&W building in
the northern portion of the site; facing southeast.
lrerracon
Photo #2 View of the parking lot adjacent to
former K&W located in the western portion of the
site; facing southwest.
Photo #3 View of the location of TW-01 in the Photo #4 View of the location of TW-02 in the
northeast portion of the site; facing southeast. northern portion of the site; facing southeast.
Limited Site Investigation
Proposed Chick-fil-A #04954 Chapel Hill, North Carolina
Photos Taken: July 9, 2021 Terracon Project No. 70217369
Irerracon
Photo #5 View of TW-03 located in the Photo #6 View of SV-01 located in the northeast
northwestern portion of the site; facing west. portion of the current on -site building.
Photo #7 View of SV-02 located in the
northeast portion of the current on -site building.
APPENDIX C
Laboratory Analytical Report and Chain -of -Custody Record
aceAnalXical o ANALYTICAL REPORT
July 29, 2021
Revised Report
Terracon - Raleigh, NC
Sample Delivery Group: L1376539
Samples Received: 07/10/2021
Project Number: 70217369
Description:
Report To: Ethan Dinwiddie
2401 Brentwood Rd
Ste 107
Raleigh, NC 27604
Entire Report Reviewed By: 4�41
Heather J Wagner
Project Manager
Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be
reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace
Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067 and
ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided,
and as the samples are received.
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Terracon - Raleigh, NC 70217369 L1376539 07/29/2116:01 1 of 24
TABLE OF CONTENTS
Cp: Cover Page
Tc: Table of Contents
Ss: Sample Summary
3
Cn: Case Narrative
4
Sr: Sample Results
5
TW-01(2-3) L1376539-01
5
Fn
TW-02(6-7) L1376539-02
6
TW-03(6-7) L1376539-03
7
Fr
TW-01 L1376539-04
8
TW-02 L1376539-05
9
Qc
TW-03 L1376539-06
10
F,
TB-01 L1376539-07
11
Qc: Quality Control Summary
12
rAl
Volatile Organic Compounds (GC/MS) by Method 8260D
12
GI: Glossary of Terms
21
FSC
Al: Accreditations & Locations
22
Sc: Sample Chain of Custody
23
ACCOUNT: PROJECT: SDG:
DATE/TIME:
PAGE:
Terracon - Raleigh, NC 70217369 L1376539
07/29/2116:01
2 of 24
SAMPLE SUMMARY
Collected by Collected date/time Received date/time
TW-01(2-3) L1376539-01 Solid
Ethan Dinwiddie
07/09/2109:45
07/10/2109:15
C p
Method
Batch
Dilution Preparation
Analysis
Analyst Location
date/time
date/time
FTC
Volatile Organic Compounds (GC/MS) by Method 8260D
WG1704141
1 07/09/2109:45
07/13/2105:13
ADM Mt. Juliet, TN
Collected by
Collected date/time
Received date/time
TW-02(6-7) L1376539-02 Solid
Ethan Dinwiddie
07/09/2111:30
07/10/2109:15
rCn]
Method
Batch
Dilution Preparation
Analysis
Analyst Location
date/time
date/time
Organic Compounds (GC/MS) by Method 8260D
WG1704141
1 07/09/2111:30
07/13/2105:33
ADM Mt. Juliet, TN
FSrVolatile
Collected by
Collected date/time
Received date/time
E
TW-03(6-7) L1376539-03 Solid
Ethan Dinwiddie
07/09/2112:15
07/10/2109:15
Method
Batch
Dilution Preparation
Analysis
Analyst Location
F
date/time
date/time
Volatile Organic Compounds (GC/MS) by Method 8260D
WG1704141
1 07/09/2112:15
07/13/21 05:52
ADM Mt. Juliet, TN
FAI
Collected by
Collected date/time
Received date/time
TW-01 L1376539-04 GW
Ethan Dinwiddie
07/09/2110:25
0711012109:15
FSC
Method
Batch
Dilution
Preparation
Analysis
Analyst
Location
date/time
date/time
Volatile Organic Compounds (GC/MS) by Method 8260D
WG1704627
1
07/16/2102:22
07/16/2102:22
JAH
Mt. Juliet, TN
Collected by
Collected date/time
Received date/time
TW-02 L1376539-05 GW
Ethan Dinwiddie
07/09/2111:20
07/10/2109:15
Method
Batch
Dilution
Preparation
Analysis
Analyst
Location
date/time
date/time
Volatile Organic Compounds (GC/MS) by Method 8260D
WG1706422
1
07/16/2119:35
07/16/2119:35
JHH
Mt. Juliet, TN
Collected by
Collected date/time
Received date/time
TW-03 L1376539-06 GW
Ethan Dinwiddie
07/09/2112:45
07/10/2109:15
Method
Batch
Dilution
Preparation
Analysis
Analyst
Location
date/time
date/time
Volatile Organic Compounds (GC/MS) by Method 8260D
WG1706422
1
07/16/2119:55
07/16/2119:55
JHH
Mt. Juliet, TN
Collected by
Collected date/time
Received date/time
TB-01 L1376539-07 GW
Ethan Dinwiddie
07/09/2100:00
07/10/2109:15
Method
Batch
Dilution
Preparation
Analysis
Analyst
Location
date/time
date/time
Volatile Organic Compounds (GC/MS) by Method 8260D
WG1704627
1
07/16/2101:42
07/16/2101:42
JAH
Mt. Juliet, TN
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
PAGE:
Terracon - Raleigh, NC
70217369
L1376539
07/29/2116:01
3 of 24
CASE NARRATIVE
FP
All sample aliquots were received at the correct temperature, in the proper containers, with the
appropriate preservatives, and within method specified holding times, unless qualified or notated within
the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples
FC
have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control
are within established criteria except where addressed in this case narrative, a non-conformance form
or properly qualified within the sample results. By my digital signature below, I affirm to the best of my
FSS
knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the
quality of the data have been identified by the laboratory, and no information or data have been
knowingly withheld that would affect the quality of the data.
Fr
RC
F,
Heather J Wagner
FAI
Project Manager
FSC
Report Revision History
Level II Report -Version 1: 07/19/21 15:17
Project Narrative
Revised Report: Revised to report only chloronated VOC compounds per client request. This report replaces the report issued
7/19/2021.
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Terracon - Raleigh, NC 70217369 L1376539 07/29/21 16:01 4 of 24
TW-01(2-3) SAMPLE RESULTS - 01
Collected date/time: 07/09/21 09:45 L1376539
Volatile Organic Compounds (GC/MS) by Method 8260D
Result
Qualifier MDL
RDL
Dilution Analysis
Batch
u
Analyte
mg/kg
mg/kg
mg/kg
date/time
Bromodichloromethane
U
0.000725
0.00250
1 07/13/202105:13
WG1704141
FTc
Carbon tetrachloride
U
0.000898
0.00500
1 07/13/202105:13
WG1704141
Chlorobenzene
U
0.000210
0.00250
1 07/13/202105:13
WG1704141
F
Chlorodibromomethane
U
0.000612
0.00250
1 07/13/202105:13
WG1704141
Chloroethane
U
0.00170
0.00500
1 07/13/202105:13
WG1704141
Chloroform
U
0.00103
0.00250
1 07/13/202105:13
WG1704141
rCn
Chloromethane
U
0.00435
0.0125
1 07/13/202105:13
WG1704141
2-Chlorotoluene
U
0.000865
0.00250
1 07/13/202105:13
WG1704141
4-Chlorotoluene
U
0.000450
0.00500
1 07/13/202105:13
WG1704141
1,2-Dibromo-3-Chloropropane
U
0.00390
0.0250
1 07/13/202105:13
WG1704141
1,2-Dichlorobenzene
U
0.000425
0.00500
1 07/13/202105:13
WG1704141
Rc
1,3-Dichlorobenzene
U
0.000600
0.00500
1 07/13/202105:13
WG1704141
1,4-Dichlorobenzene
U
0.000700
0.00500
1 07/13/202105:13
WG1704141
Fq
Dichlorodifluoromethane
U
0.00161
0.00250
1 07/13/202105:13
WG1704141
1,1-Dichloroethane
U
0.000491
0.00250
1 07/13/202105:13
WG1704141
1,2-Dichloroethane
U
0.000649
0.00250
1 07/13/202105:13
WG1704141
FAI
1,1-Dichloroethene
U
0.000606
0.00250
1 07/13/202105:13
WG1704141
cis-1,2-Dichloroethene
U
0.000734
0.00250
1 07/13/202105:13
WG1704141
F
trans-1,2-Dichloroethene
U
0.00104
0.00500
1 07/13/202105:13
WG1704141
1,2-Dichloropropane
U
0.00142
0.00500
1 07/13/202105:13
WG1704141
1,1-Dichloropropene
U
0.000809
0.00250
1 07/13/202105:13
WG1704141
1,3-Dichloropropane
U
0.000501
0.00500
1 07/13/202105:13
WG1704141
cis-1,3-Dichloropropene
U
0.000757
0.00250
1 07/13/202105:13
WG1704141
trans-1,3-Dichloropropene
U
0.00114
0.00500
1 07/13/202105:13
WG1704141
2,2-Dichloropropane
U
0.00138
0.00250
1 07/13/202105:13
WG1704141
Hexachloro-1,3-butadiene
U
0.00600
0.0250
1 07/13/202105:13
WG1704141
Methylene Chloride
U
0.00664
0.0250
1 07/13/202105:13
WG1704141
1,1,1,2-Tetrachloroethane
U
0.000948
0.00250
1 07/13/202105:13
WG1704141
1,1,2,2-Tetrachloroethane
U
0.000695
0.00250
1 07/13/202105:13
WG1704141
1,1,2-Trichlorotrifluoroethane
U
0.000754
0.00250
1 07/13/202105:13
WG1704141
Tetrachloroethene
U
0.000896
0.00250
1 07/13/202105:13
WG1704141
1,2,3-Trichlorobenzene
U
0.00733
0.0125
1 07/13/202105:13
WG1704141
1,2,4-Trichlorobenzene
U
0.00440
0.0125
1 07/13/202105:13
WG1704141
1,1,1-Trichloroethane
U
0.000923
0.00250
1 07/13/202105:13
WG1704141
1,1,2-Trichloroethane
U
0.000597
0.00250
1 07/13/202105:13
WG1704141
Trichloroethene
U
0.000584
0.00100
1 07/13/202105:13
WG1704141
Trichlorofluoromethane
U
0.000827
0.00250
1 07/13/202105:13
WG1704141
1,2,3-Trichloropropane
U
0.00162
0.0125
1 07/13/202105:13
WG1704141
Vinyl chloride
U
0.00116
0.00250
1 07/13/202105:13
WG1704141
(S) Toluene-d8
110
75.0-131
07/13/202105.13
WG1704141
(S 4-Bromofluorobenzene
102
67.0-138
071131202105.13
WG1704141
(S)1,2-Dichloroethane-d4
77.5
70.0-130
07/13/202105.13
WG1704141
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
PAGE:
Terracon -
Raleigh, NC
70217369
L1376539
07/29/2116:01
5 of 24
TW-02(6-7) SAMPLE RESULTS - 02
Collected date/time: 07/09/21 11:30 L1376539
Volatile Organic Compounds (GC/MS) by Method 8260D
Result
Qualifier MDL
RDL
Dilution Analysis
Batch
u
Analyte
mg/kg
mg/kg
mg/kg
date/time
Bromodichloromethane
U
0.000725
0.00250
1 07/13/202105:33
WG1704141
FTc
Carbon tetrachloride
U
0.000898
0.00500
1 07/13/202105:33
WG1704141
Chlorobenzene
U
0.000210
0.00250
1 07/13/202105:33
WG1704141
F
Chlorodibromomethane
U
0.000612
0.00250
1 07/13/202105:33
WG1704141
Chloroethane
U
0.00170
0.00500
1 07/13/202105:33
WG1704141
Chloroform
U
0.00103
0.00250
1 07/13/202105:33
WG1704141
rCn
Chloromethane
U
0.00435
0.0125
1 07/13/202105:33
WG1704141
2-Chlorotoluene
U
0.000865
0.00250
1 07/13/202105:33
WG1704141
4-Chlorotoluene
U
0.000450
0.00500
1 07/13/202105:33
WG1704141
1,2-Dibromo-3-Chloropropane
U
0.00390
0.0250
1 07/13/202105:33
WG1704141
1,2-Dichlorobenzene
U
0.000425
0.00500
1 07/13/202105:33
WG1704141
Rc
1,3-Dichlorobenzene
U
0.000600
0.00500
1 07/13/202105:33
WG1704141
1,4-Dichlorobenzene
U
0.000700
0.00500
1 07/13/202105:33
WG1704141
Fq
Dichlorodifluoromethane
U
0.00161
0.00250
1 07/13/202105:33
WG1704141
1,1-Dichloroethane
U
0.000491
0.00250
1 07/13/202105:33
WG1704141
1,2-Dichloroethane
U
0.000649
0.00250
1 07/13/202105:33
WG1704141
FAI
1,1-Dichloroethene
U
0.000606
0.00250
1 07/13/202105:33
WG1704141
cis-1,2-Dichloroethene
U
0.000734
0.00250
1 07/13/202105:33
WG1704141
F
trans-1,2-Dichloroethene
U
0.00104
0.00500
1 07/13/202105:33
WG1704141
1,2-Dichloropropane
U
0.00142
0.00500
1 07/13/202105:33
WG1704141
1,1-Dichloropropene
U
0.000809
0.00250
1 07/13/202105:33
WG1704141
1,3-Dichloropropane
U
0.000501
0.00500
1 07/13/202105:33
WG1704141
cis-1,3-Dichloropropene
U
0.000757
0.00250
1 07/13/202105:33
WG1704141
trans-1,3-Dichloropropene
U
0.00114
0.00500
1 07/13/202105:33
WG1704141
2,2-Dichloropropane
U
0.00138
0.00250
1 07/13/202105:33
WG1704141
Hexachloro-1,3-butadiene
U
0.00600
0.0250
1 07/13/202105:33
WG1704141
Methylene Chloride
U
0.00664
0.0250
1 07/13/202105:33
WG1704141
1,1,1,2-Tetrachloroethane
U
0.000948
0.00250
1 07/13/202105:33
WG1704141
1,1,2,2-Tetrachloroethane
U
0.000695
0.00250
1 07/13/202105:33
WG1704141
1,1,2-Trichlorotrifluoroethane
U
0.000754
0.00250
1 07/13/202105:33
WG1704141
Tetrachloroethene
U
0.000896
0.00250
1 07/13/202105:33
WG1704141
1,2,3-Trichlorobenzene
U
0.00733
0.0125
1 07/13/202105:33
WG1704141
1,2,4-Trichlorobenzene
U
0.00440
0.0125
1 07/13/202105:33
WG1704141
1,1,1-Trichloroethane
U
0.000923
0.00250
1 07/13/202105:33
WG1704141
1,1,2-Trichloroethane
U
0.000597
0.00250
1 07/13/202105:33
WG1704141
Trichloroethene
U
0.000584
0.00100
1 07/13/202105:33
WG1704141
Trichlorofluoromethane
U
0.000827
0.00250
1 07/13/202105:33
WG1704141
1,2,3-Trichloropropane
U
0.00162
0.0125
1 07/13/202105:33
WG1704141
Vinyl chloride
U
0.00116
0.00250
1 07/13/202105:33
WG1704141
(S) Toluene-d8
106
75.0-131
07/13/202105.33
WG1704141
(S) 4-Bromofluorobenzene
99.7
67.0-138
07/13/202105.33
WG1704141
(S)1,2-Dichloroethane-d4
77.4
70.0-130
07/13/202105.33
WG1704141
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
PAGE:
Terracon -
Raleigh, NC
70217369
L1376539
07/29/2116:01
6 of 24
TW-03(6-7) SAMPLE RESULTS - 03
Collected date/time: 07/09/21 12:15 L1376539
Volatile Organic Compounds (GC/MS) by Method 8260D
Result
Qualifier MDL
RDL
Dilution Analysis
Batch
u
Analyte
mg/kg
mg/kg
mg/kg
date/time
Bromodichloromethane
U
0.000725
0.00250
1 07/13/202105:52
WG1704141
FTc
Carbon tetrachloride
U
0.000898
0.00500
1 07/13/202105:52
WG1704141
Chlorobenzene
U
0.000210
0.00250
1 07/13/202105:52
WG1704141
F
Chlorodibromomethane
U
0.000612
0.00250
1 07/13/202105:52
WG1704141
Chloroethane
U
0.00170
0.00500
1 07/13/202105:52
WG1704141
Chloroform
U
0.00103
0.00250
1 07/13/202105:52
WG1704141
rCn
Chloromethane
U
0.00435
0.0125
1 07/13/202105:52
WG1704141
2-Chlorotoluene
U
0.000865
0.00250
1 07/13/202105:52
WG1704141
4-Chlorotoluene
U
0.000450
0.00500
1 07/13/202105:52
WG1704141
1,2-Dibromo-3-Chloropropane
U
0.00390
0.0250
1 07/13/202105:52
WG1704141
1,2-Dichlorobenzene
U
0.000425
0.00500
1 07/13/202105:52
WG1704141
Rc
1,3-Dichlorobenzene
U
0.000600
0.00500
1 07/13/202105:52
WG1704141
1,4-Dichlorobenzene
U
0.000700
0.00500
1 07/13/202105:52
WG1704141
Fq
Dichlorodifluoromethane
U
0.00161
0.00250
1 07/13/202105:52
WG1704141
1,1-Dichloroethane
U
0.000491
0.00250
1 07/13/202105:52
WG1704141
1,2-Dichloroethane
U
0.000649
0.00250
1 07/13/202105:52
WG1704141
FAI
1,1-Dichloroethene
U
0.000606
0.00250
1 07/13/202105:52
WG1704141
cis-1,2-Dichloroethene
0.0165
0.000734
0.00250
1 07/13/202105:52
WG1704141
F
trans-1,2-Dichloroethene
U
0.00104
0.00500
1 07/13/202105:52
WG1704141
1,2-Dichloropropane
U
0.00142
0.00500
1 07/13/202105:52
WG1704141
1,1-Dichloropropene
U
0.000809
0.00250
1 07/13/202105:52
WG1704141
1,3-Dichloropropane
U
0.000501
0.00500
1 07/13/202105:52
WG1704141
cis-1,3-Dichloropropene
U
0.000757
0.00250
1 07/13/202105:52
WG1704141
trans-1,3-Dichloropropene
U
0.00114
0.00500
1 07/13/202105:52
WG1704141
2,2-Dichloropropane
U
0.00138
0.00250
1 07/13/202105:52
WG1704141
Hexachloro-1,3-butadiene
U
0.00600
0.0250
1 07/13/202105:52
WG1704141
Methylene Chloride
U
0.00664
0.0250
1 07/13/202105:52
WG1704141
1,1,1,2-Tetrachloroethane
U
0.000948
0.00250
1 07/13/202105:52
WG1704141
1,1,2,2-Tetrachloroethane
U
0.000695
0.00250
1 07/13/202105:52
WG1704141
1,1,2-Trichlorotrifluoroethane
U
0.000754
0.00250
1 07/13/202105:52
WG1704141
Tetrachloroethene
U
0.000896
0.00250
1 07/13/202105:52
WG1704141
1,2,3-Trichlorobenzene
U
0.00733
0.0125
1 07/13/202105:52
WG1704141
1,2,4-Trichlorobenzene
U
0.00440
0.0125
1 07/13/202105:52
WG1704141
1,1,1-Trichloroethane
U
0.000923
0.00250
1 07/13/202105:52
WG1704141
1,1,2-Trichloroethane
U
0.000597
0.00250
1 07/13/202105:52
WG1704141
Trichloroethene
U
0.000584
0.00100
1 07/13/202105:52
WG1704141
Trichlorofluoromethane
U
0.000827
0.00250
1 07/13/202105:52
WG1704141
1,2,3-Trichloropropane
U
0.00162
0.0125
1 07/13/202105:52
WG1704141
Vinyl chloride
U
0.00116
0.00250
1 07/13/202105:52
WG1704141
(S) Toluene-d8
110
75.0-131
07/13/202105:52
WG1704141
(S 4-Bromofluorobenzene
102
67.0-138
07/13/202105:52
WG1704141
(S)1,2-Dichloroethane-d4
78.0
70.0-130
07/13/202105:52
WG1704141
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
PAGE:
Terracon -
Raleigh, NC
70217369
L1376539
07/29/2116:01
7 of 24
TW-01 SAMPLE RESULTS - 04
Collected date/time: 07/09/21 10:25 L1376539
Volatile Organic Compounds (GC/MS) by Method 8260D
Result
Qualifier
MDL
RDL
Dilution Analysis
Batch
u
Analyte
ug/I
ug/I
ug/I
date / time
Bromodichloromethane
U
0.136
1.00
1 07/16/202102:22
WG1704627
FTc
Carbon tetrachloride
U
0.128
1.00
1 07/16/202102:22
WG1704627
Chlorobenzene
U
0.116
1.00
1 07/16/202102:22
WG1704627
F
Chlorodibromomethane
U
0.140
1.00
1 07/16/202102:22
WG1704627
Chloroethane
U
0.192
5.00
1 07/16/202102:22
WG1704627
Chloroform
U
0.111
5.00
1 07/16/202102:22
WG1704627
rCn
Chloromethane
U
0.960
2.50
1 07/16/202102:22
WG1704627
2-Chlorotoluene
U
0.106
1.00
1 07/16/202102:22
WG1704627
4-Chlorotoluene
U
0.114
1.00
1 07/16/202102:22
WG1704627
1,2-Dibromo-3-Chloropropane
U
0.276
5.00
1 07/16/202102:22
WG1704627
1,2-Dichlorobenzene
U
0.107
1.00
1 07/16/202102:22
WG1704627
6
QC
1,3-Dichlorobenzene
U
J4
0.110
1.00
1 07/16/202102:22
WG1704627
1,4-Dichlorobenzene
U
0.120
1.00
1 07/16/202102:22
WG1704627
�GI
Dichlorodifluoromethane
U
C3
0.374
5.00
1 07/16/202102:22
WG1704627
1,1-Dichloroethane
U
0.100
1.00
1 07/16/202102:22
WG1704627
1,2-Dichloroethane
U
0.0819
1.00
1 07/16/202102:22
WG1704627
FAI
1,1-Dichloroethene
U
0.188
1.00
1 07/16/202102:22
WG1704627
cis-1,2-Dichloroethene
U
0.126
1.00
1 07/16/202102:22
WG1704627
F
trans-1,2-Dichloroethene
U
0.149
1.00
1 07/16/202102:22
WG1704627
1,2-Dichloropropane
U
0.149
1.00
1 07/16/202102:22
WG1704627
1,1-Dichloropropene
U
0.142
1.00
1 07/16/202102:22
WG1704627
1,3-Dichloropropane
U
0.110
1.00
1 07/16/202102:22
WG1704627
cis-1,3-Dichloropropene
U
0.111
1.00
1 07/16/202102:22
WG1704627
trans-1,3-Dichloropropene
U
J4
0.118
1.00
1 07/16/202102:22
WG1704627
2,2-Dichloropropane
U
0.161
1.00
1 07/16/202102:22
WG1704627
Hexachloro-1,3-butadiene
U
0.337
1.00
1 07/16/202102:22
WG1704627
Methylene Chloride
U
0.430
5.00
1 07/16/202102:22
WG1704627
1,1,1,2-Tetrachloroethane
U
0.147
1.00
1 07/16/202102:22
WG1704627
1,1,2,2-Tetrachloroethane
U
0.133
1.00
1 07/16/202102:22
WG1704627
1,1,2-Trichlorotrifluoroethane
U
0.180
1.00
1 07/16/202102:22
WG1704627
Tetrachloroethene
U
0.300
1.00
1 07/16/202102:22
WG1704627
1,2,3-Trichlorobenzene
U
0.230
1.00
1 07/16/202102:22
WG1704627
1,2,4-Trichlorobenzene
U
0.481
1.00
1 07/16/202102:22
WG1704627
1,1,1-Trichloroethane
U
0.149
1.00
1 07/16/202102:22
WG1704627
1,1,2-Trichloroethane
U
0.158
1.00
1 07/16/202102:22
WG1704627
Trichloroethene
U
0.190
1.00
1 07/16/202102:22
WG1704627
Trichlorofluoromethane
U
0.160
5.00
1 07/16/202102:22
WG1704627
1,2,3-Trichloropropane
U
0.237
2.50
1 07/16/202102:22
WG1704627
Vinyl chloride
U
0.234
1.00
1 07/16/202102:22
WG1704627
(S) Toluene-d8
100
80.0-120
07/16/202102:22
WG1704627
(S4-Bromofluorobenzene
91.8
77.0-126
07/16/202102:22
WG1704627
(S)1,2-Dichloroethane-d4
100
70.0-130
07/16/202102:22
WG1704627
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
PAGE:
Terracon -
Raleigh, NC
70217369
L1376539
07/29/2116:01
8 of 24
TW-02 SAMPLE RESULTS - 05
Collected date/time: 07/09/21 11:20 L1376539
Volatile Organic Compounds (GC/MS) by Method 8260D
Result
Qualifier
MDL
RDL
Dilution Analysis
Batch
u
Analyte
ug/I
ug/I
ug/I
date / time
Bromodichloromethane
U
0.136
1.00
1 07/16/202119:35
WG1706422
FTc
Carbon tetrachloride
U
0.128
1.00
1 07/16/202119:35
WG1706422
Chlorobenzene
U
0.116
1.00
1 07/16/202119:35
WG1706422
F
Chlorodibromomethane
U
0.140
1.00
1 07/16/202119:35
WG1706422
Chloroethane
U
0.192
5.00
1 07/16/202119:35
WG1706422
Chloroform
U
0.111
5.00
1 07/16/202119:35
WG1706422
rCn
Chloromethane
U
0.960
2.50
1 07/16/202119:35
WG1706422
2-Chlorotoluene
U
0.106
1.00
1 07/16/202119:35
WG1706422
4-Chlorotoluene
U
0.114
1.00
1 07/16/202119:35
WG1706422
1,2-Dibromo-3-Chloropropane
U
0.276
5.00
1 07/16/202119:35
WG1706422
1,2-Dichlorobenzene
U
0.107
1.00
1 07/16/202119:35
WG1706422
6
QC
1,3-Dichlorobenzene
U
0.110
1.00
1 07/16/202119:35
WG1706422
1,4-Dichlorobenzene
U
0.120
1.00
1 07/16/202119:35
WG1706422
7G1
Dichlorodifluoromethane
U
0.374
5.00
1 07/16/202119:35
WG1706422
1,1-Dichloroethane
U
0.100
1.00
1 07/16/202119:35
WG1706422
1,2-Dichloroethane
U
0.0819
1.00
1 07/16/202119:35
WG1706422
FAI
1,1-Dichloroethene
U
0.188
1.00
1 07/16/202119:35
WG1706422
cis-1,2-Dichloroethene
0.227
J
0.126
1.00
1 07/16/202119:35
WG1706422
F
trans-1,2-Dichloroethene
U
0.149
1.00
1 07/16/202119:35
WG1706422
1,2-Dichloropropane
U
0.149
1.00
1 07/16/202119:35
WG1706422
1,1-Dichloropropene
U
0.142
1.00
1 07/16/202119:35
WG1706422
1,3-Dichloropropane
U
0.110
1.00
1 07/16/202119:35
WG1706422
cis-1,3-Dichloropropene
U
0.111
1.00
1 07/16/202119:35
WG1706422
trans-1,3-Dichloropropene
U
0.118
1.00
1 07/16/202119:35
WG1706422
2,2-Dichloropropane
U
0.161
1.00
1 07/16/202119:35
WG1706422
Hexachloro-1,3-butadiene
U
C3
0.337
1.00
1 07/16/202119:35
WG1706422
Methylene Chloride
U
0.430
5.00
1 07/16/202119:35
WG1706422
1,1,1,2-Tetrachloroethane
U
0.147
1.00
1 07/16/202119:35
WG1706422
1,1,2,2-Tetrachloroethane
U
0.133
1.00
1 07/16/202119:35
WG1706422
1,1,2-Trichlorotrifluoroethane
U
0.180
1.00
1 07/16/202119:35
WG1706422
Tetrachloroethene
U
0.300
1.00
1 07/16/202119:35
WG1706422
1,2,3-Trichlorobenzene
U
C3
0.230
1.00
1 07/16/202119:35
WG1706422
1,2,4-Trichlorobenzene
U
C3
0.481
1.00
1 07/16/202119:35
WG1706422
1,1,1-Trichloroethane
U
0.149
1.00
1 07/16/202119:35
WG1706422
1,1,2-Trichloroethane
U
0.158
1.00
1 07/16/202119:35
WG1706422
Trichloroethene
U
0.190
1.00
1 07/16/202119:35
WG1706422
Trichlorofluoromethane
U
0.160
5.00
1 07/16/202119:35
WG1706422
1,2,3-Trichloropropane
U
0.237
2.50
1 07/16/202119:35
WG1706422
Vinyl chloride
U
0.234
1.00
1 07/16/202119:35
WG1706422
(S) Toluene-d8
104
80.0-120
07/16/202119:35
WG1706422
(S)4-Bromofluorobenzene
89.1
77.0-126
071161202119:35
WG1706422
(S)1,2-Dichloroethane-d4
106
70.0-130
07/16/202119:35
WG1706422
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
PAGE:
Terracon -
Raleigh, NC
70217369
L1376539
07/29/2116:01
9 of 24
TW-03 SAMPLE RESULTS - 06
Collected date/time: 07/09/21 12:45 L1376539
Volatile Organic Compounds (GC/MS) by Method 8260D
Result
Qualifier
MDL
RDL
Dilution Analysis
Batch
u
Analyte
ug/I
ug/I
ug/I
date / time
Bromodichloromethane
U
0.136
1.00
1 07/16/202119:55
WG1706422
FTc
Carbon tetrachloride
U
0.128
1.00
1 07/16/202119:55
WG1706422
Chlorobenzene
U
0.116
1.00
1 07/16/202119:55
WG1706422
F
Chlorodibromomethane
U
0.140
1.00
1 07/16/202119:55
WG1706422
Chloroethane
U
0.192
5.00
1 07/16/202119:55
WG1706422
Chloroform
U
0.111
5.00
1 07/16/202119:55
WG1706422
rCn
Chloromethane
U
0.960
2.50
1 07/16/202119:55
WG1706422
2-Chlorotoluene
U
0.106
1.00
1 07/16/202119:55
WG1706422
4-Chlorotoluene
U
0.114
1.00
1 07/16/202119:55
WG1706422
1,2-Dibromo-3-Chloropropane
U
0.276
5.00
1 07/16/202119:55
WG1706422
1,2-Dichlorobenzene
U
0.107
1.00
1 07/16/202119:55
WG1706422
6
QC
1,3-Dichlorobenzene
U
0.110
1.00
1 07/16/202119:55
WG1706422
1,4-Dichlorobenzene
U
0.120
1.00
1 07/16/202119:55
WG1706422
7G1
Dichlorodifluoromethane
U
0.374
5.00
1 07/16/202119:55
WG1706422
1,1-Dichloroethane
U
0.100
1.00
1 07/16/202119:55
WG1706422
1,2-Dichloroethane
U
0.0819
1.00
1 07/16/202119:55
WG1706422
FAI
1,1-Dichloroethene
U
0.188
1.00
1 07/16/202119:55
WG1706422
cis-1,2-Dichloroethene
103
0.126
1.00
1 07/16/202119:55
WG1706422
F
trans-1,2-Dichloroethene
0.906
J
0.149
1.00
1 07/16/202119:55
WG1706422
1,2-Dichloropropane
U
0.149
1.00
1 07/16/202119:55
WG1706422
1,1-Dichloropropene
U
0.142
1.00
1 07/16/202119:55
WG1706422
1,3-Dichloropropane
U
0.110
1.00
1 07/16/202119:55
WG1706422
cis-1,3-Dichloropropene
U
0.111
1.00
1 07/16/202119:55
WG1706422
trans-1,3-Dichloropropene
U
0.118
1.00
1 07/16/202119:55
WG1706422
2,2-Dichloropropane
U
0.161
1.00
1 07/16/202119:55
WG1706422
Hexachloro-1,3-butadiene
U
C3
0.337
1.00
1 07/16/202119:55
WG1706422
Methylene Chloride
U
0.430
5.00
1 07/16/202119:55
WG1706422
1,1,1,2-Tetrachloroethane
U
0.147
1.00
1 07/16/202119:55
WG1706422
1,1,2,2-Tetrachloroethane
U
0.133
1.00
1 07/16/202119:55
WG1706422
1,1,2-Trichlorotrifluoroethane
U
0.180
1.00
1 07/16/202119:55
WG1706422
Tetrachloroethene
67.9
0.300
1.00
1 07/16/202119:55
WG1706422
1,2,3-Trichlorobenzene
U
C3
0.230
1.00
1 07/16/202119:55
WG1706422
1,2,4-Trichlorobenzene
U
C3
0.481
1.00
1 07/16/202119:55
WG1706422
1,1,1-Trichloroethane
U
0.149
1.00
1 07/16/202119:55
WG1706422
1,1,2-Trichloroethane
U
0.158
1.00
1 07/16/202119:55
WG1706422
Trichloroethene
27.1
0.190
1.00
1 07/16/202119:55
WG1706422
Trichlorofluoromethane
U
0.160
5.00
1 07/16/202119:55
WG1706422
1,2,3-Trichloropropane
U
0.237
2.50
1 07/16/202119:55
WG1706422
Vinyl chloride
1.19
0.234
1.00
1 07/16/202119:55
WG1706422
(S) Toluene-d8
103
80.0-120
071161202119:55
WG1706422
(S4-Bromofluorobenzene
92.4
77.0-126
071161202119:55
WG1706422
(S)1,2-Dichloroethane-d4
108
70.0-130
071161202119:55
WG1706422
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
PAGE:
Terracon -
Raleigh, NC
70217369
L1376539
07/29/21 16:01
10 of 24
TB-01 SAMPLE RESULTS - 07
Collected date/time: 07/09/21 00:00 L1376539
Volatile Organic Compounds (GC/MS) by Method 8260D
Result
Qualifier
MDL
RDL
Dilution Analysis
Batch
u
Analyte
ug/I
ug/I
ug/I
date / time
Bromodichloromethane
U
0.136
1.00
1 07/16/202101:42
WG1704627
FTc
Carbon tetrachloride
U
0.128
1.00
1 07/16/202101:42
WG1704627
Chlorobenzene
U
0.116
1.00
1 07/16/202101:42
WG1704627
F
Chlorodibromomethane
U
0.140
1.00
1 07/16/202101:42
WG1704627
Chloroethane
U
0.192
5.00
1 07/16/202101:42
WG1704627
Chloroform
U
0.111
5.00
1 07/16/202101:42
WG1704627
rCn
Chloromethane
U
0.960
2.50
1 07/16/202101:42
WG1704627
2-Chlorotoluene
U
0.106
1.00
1 07/16/202101:42
WG1704627
4-Chlorotoluene
U
0.114
1.00
1 07/16/202101:42
WG1704627
1,2-Dibromo-3-Chloropropane
U
0.276
5.00
1 07/16/202101:42
WG1704627
1,2-Dichlorobenzene
U
0.107
1.00
1 07/16/202101:42
WG1704627
6
QC
1,3-Dichlorobenzene
U
J4
0.110
1.00
1 07/16/202101:42
WG1704627
1,4-Dichlorobenzene
U
0.120
1.00
1 07/16/202101:42
WG1704627
7G1
Dichlorodifluoromethane
U
C3
0.374
5.00
1 07/16/202101:42
WG1704627
1,1-Dichloroethane
U
0.100
1.00
1 07/16/202101:42
WG1704627
1,2-Dichloroethane
U
0.0819
1.00
1 07/16/202101:42
WG1704627
FAI
1,1-Dichloroethene
U
0.188
1.00
1 07/16/202101:42
WG1704627
cis-1,2-Dichloroethene
U
0.126
1.00
1 07/16/202101:42
WG1704627
F
trans-1,2-Dichloroethene
U
0.149
1.00
1 07/16/202101:42
WG1704627
1,2-Dichloropropane
U
0.149
1.00
1 07/16/202101:42
WG1704627
1,1-Dichloropropene
U
0.142
1.00
1 07/16/202101:42
WG1704627
1,3-Dichloropropane
U
0.110
1.00
1 07/16/202101:42
WG1704627
cis-1,3-Dichloropropene
U
0.111
1.00
1 07/16/202101:42
WG1704627
trans-1,3-Dichloropropene
U
J4
0.118
1.00
1 07/16/202101:42
WG1704627
2,2-Dichloropropane
U
0.161
1.00
1 07/16/202101:42
WG1704627
Hexachloro-1,3-butadiene
U
0.337
1.00
1 07/16/202101:42
WG1704627
Methylene Chloride
U
0.430
5.00
1 07/16/202101:42
WG1704627
1,1,1,2-Tetrachloroethane
U
0.147
1.00
1 07/16/202101:42
WG1704627
1,1,2,2-Tetrachloroethane
U
0.133
1.00
1 07/16/202101:42
WG1704627
1,1,2-Trichlorotrifluoroethane
U
0.180
1.00
1 07/16/202101:42
WG1704627
Tetrachloroethene
U
0.300
1.00
1 07/16/202101:42
WG1704627
1,2,3-Trichlorobenzene
U
0.230
1.00
1 07/16/202101:42
WG1704627
1,2,4-Trichlorobenzene
U
0.481
1.00
1 07/16/202101:42
WG1704627
1,1,1-Trichloroethane
U
0.149
1.00
1 07/16/202101:42
WG1704627
1,1,2-Trichloroethane
U
0.158
1.00
1 07/16/202101:42
WG1704627
Trichloroethene
U
0.190
1.00
1 07/16/202101:42
WG1704627
Trichlorofluoromethane
U
0.160
5.00
1 07/16/202101:42
WG1704627
1,2,3-Trichloropropane
U
0.237
2.50
1 07/16/202101:42
WG1704627
Vinyl chloride
U
0.234
1.00
1 07/16/202101:42
WG1704627
(S) Toluene-d8
104
80.0-120
07/16/202101.42
WG1704627
(S4-Bromofluorobenzene
87.3
77.0-126
07/16/202101.42
WG1704627
(S)1,2-Dichloroethane-d4
105
70.0-130
07/16/202101.42
WG1704627
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Terracon - Raleigh, NC 70217369 L1376539 07/29/2116:01 11 of 24
WG1704141
Volatile Organic Compounds (GC/MS) by Method 8260D
QUALITY CONTROL SUMMARY
1-1376539-01,02,03
Method Blank (MB)
(MB) R3679822-3 07/13/21 00:56
MB Result
Analyte mg/kg
MB Qualifier MB MDL MB RDL
mg/kg mg/kg
Bromodichloromethane
U
0.000725
0.00250
Carbon tetrachloride
U
0.000898
0.00500
Chlorobenzene
U
0.000210
0.00250
Chlorodibromomethane
U
0.000612
0.00250
Chloroethane
U
0.00170
0.00500
Chloroform
U
0.00103
0.00250
Chloromethane
U
0.00435
0.0125
2-Chlorotoluene
U
0.000865
0.00250
4-Chlorotoluene
U
0.000450
0.00500
1,2-Dibromo-3-Chloropropane
U
0.00390
0.0250
1,2-Dichlorobenzene
U
0.000425
0.00500
1,3-Dichlorobenzene
U
0.000600
0.00500
1,4-Dichlorobenzene
U
0.000700
0.00500
Dichlorodifluoromethane
U
0.00161
0.00250
1,1-Dichloroethane
U
0.000491
0.00250
1,2-Dichloroethane
U
0.000649
0.00250
1,1-Dichloroethene
U
0.000606
0.00250
cis-1,2-Dichloroethene
U
0.000734
0.00250
trans-1,2-Dichloroethene
U
0.00104
0.00500
1,2-Dichloropropane
U
0.00142
0.00500
1,1-Dichloropropene
U
0.000809
0.00250
1,3-Dichloropropane
U
0.000501
0.00500
cis-1,3-Dichloropropene
U
0.000757
0.00250
trans-1,3-Dichloropropene
U
0.00114
0.00500
2,2-Dichloropropane
U
0.00138
0.00250
Hexachloro-1,3-butadiene
U
0.00600
0.0250
Methylene Chloride
U
0.00664
0.0250
1,1,1,2-Tetrachloroethane
U
0.000948
0.00250
1,1,2,2-Tetrachloroethane
U
0.000695
0.00250
Tetrachloroethene
U
0.000896
0.00250
1,1,2-Trichlorotrifluoroethane
U
0.000754
0.00250
1,2,3-Trichlorobe nzene
U
0.00733
0.0125
1,2,4-Trichlorobenzene
U
0.00440
0.0125
1,1,1-Trichloroethane
U
0.000923
0.00250
1,1,2-Trichloroethane
U
0.000597
0.00250
Trichloroethene
U
0.000584
0.00100
Trichlorofluoromethane
U
0.000827
0.00250
1,2,3-Trichloropropane
U
0.00162
0.0125
Vinyl chloride
U
0.00116
0.00250
(S) Toluene-d8
109
75.0-131
FP1
FC
FSS
4
Cn
FSr
�GI
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Terracon - Raleigh, INC 70217369 L1376539 07/29/2116:01 12 of 24
WG1704141
Volatile Organic Compounds (GC/MS) by Method 8260D
Method Blank (MB)
(MB) R3679822-3 07/13/21 00:56
MB Result MB Qualifier MB MDL
Analyte mg/kg mg/kg
(S) 4-Bromof/uorobenzene 102
(S)1,2-Dichloroethane-d4 78.3
QUALITY CONTROL SUMMARY
L1376539-01,02,03
MB RDL
mg/kg
67.0-138
70.0-130
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3679822-1 07/12/21 23:39 • (LCSD) R3679822-2 07/12/21 23:58
Spike Amount
LCS Result
LCSD Result
LCS Rec.
LCSD Rec.
Rec. Limits
LCS Qualifier LCSD Qualifier RPD
RPD Limits
Analyte
mg/kg
mg/kg
mg/kg
%
%
%
%
%
Bromodichloromethane
0.125
0.124
0.117
99.2
93.6
73.0-121
5.81
20
Carbon tetrachloride
0.125
0.120
0.117
96.0
93.6
66.0-128
2.53
20
Chlorobenzene
0.125
0.143
0.132
114
106
76.0-128
8.00
20
Chlorodibromomethane
0.125
0.138
0.132
110
106
74.0-127
4.44
20
Chloroethane
0.125
0.126
0.121
101
96.8
61.0-134
4.05
20
Chloroform
0.125
0.125
0.115
100
92.0
72.0-123
8.33
20
Chloromethane
0.125
0.112
0.106
89.6
84.8
51.0-138
5.50
20
2-Chlorotoluene
0.125
0.131
0.132
105
106
75.0-124
0.760
20
4-Chlorotoluene
0.125
0.123
0.119
98.4
95.2
75.0-124
3.31
20
1,2-Dibromo-3-Chloropropane
0.125
0.131
0.128
105
102
59.0-130
2.32
20
1,2-Dichlorobenzene
0.125
0.126
0.121
101
96.8
76.0-124
4.05
20
1,3-Dichlorobenzene
0.125
0.133
0.128
106
102
76.0-125
3.83
20
1,4-Dichlorobenzene
0.125
0.129
0.125
103
100
77.0-121
3.15
20
Dichlorodifluoromethane
0.125
0.111
0.107
88.8
85.6
43.0-156
3.67
20
1,1-Dichloroethane
0.125
0.128
0.118
102
94.4
70.0-127
8.13
20
1,2-Dichloroethane
0.125
0.117
0.112
93.6
89.6
65.0-131
4.37
20
1,1-Dichloroethene
0.125
0.121
0.115
96.8
92.0
65.0-131
5.08
20
cis-1,2-Dichloroethene
0.125
0.140
0.131
112
105
73.0-125
6.64
20
trans-1,2-Dichloroethene
0.125
0.131
0.124
105
99.2
71.0-125
5.49
20
1,2-Dichloropropane
0.125
0.133
0.133
106
106
74.0-125
0.000
20
1,1-Dichloropropene
0.125
0.127
0.120
102
96.0
73.0-125
5.67
20
1,3-Dichloropropane
0.125
0.133
0.127
106
102
80.0-125
4.62
20
cis-1,3-Dichloropropene
0.125
0.124
0.119
99.2
95.2
76.0-127
4.12
20
trans-1,3-Dichloropropene
0.125
0.126
0.119
101
95.2
73.0-127
5.71
20
2,2-Dichloropropane
0.125
0.116
0.115
92.8
92.0
59.0-135
0.866
20
Hexachloro-1,3-butadiene
0.125
0.131
0.128
105
102
57.0-150
2.32
20
Methylene Chloride
0.125
0.139
0.129
ill
103
68.0-123
7.46
20
1,1,1,2-Tetrachloroethane
0.125
0.136
0.127
109
102
74.0-129
6.84
20
1,1,2,2-Tetrachloroethane
0.125
0.127
0.124
102
99.2
68.0-128
2.39
20
Tetrachloroethene
0.125
0.148
0.141
118
113
70.0-136
4.84
20
1,1,2-Trichlorotrifluoroethane
0.125
0.117
0.119
93.6
95.2
61.0-139
1.69
20
ACCOUNT:
PROJECT:
SDG:
DATE/TIME: PAGE:
Terracon
- Raleigh, INC
70217369
L1376539
07/29/2116:01 13 of 24
FP1
FC
FSS
4
Cn
FSr
�GI
FAI
FSC
WG1704141
QUALITY
CONTROL
SUMMARY
Volatile Organic Compounds (GC/MS)
by Method 8260D
L1376539-01,02,03
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3679822-1 07/12/21 23:39 • (LCSD) R3679822-2 07/12/21 23:58
Spike Amount
LCS Result
LCSD Result
LCS Rec. LCSD Rec.
Rec. Limits LCS Qualifier LCSD Qualifier
RPD
RPD Limits
Analyte mg/kg
mg/kg
mg/kg
%
%
%
%
%
1,2,3-Trichlorobenzene 0.125
0.137
0.135
110
108
59.0-139
1.47
20
1,2,4-Trichlorobenzene 0.125
0.145
0.139
116
ill
62.0-137
4.23
20
1,1,1-Trichloroethane 0.125
0.120
0.119
96.0
95.2
69.0-126
0.837
20
1,1,2-Trichloroethane 0.125
0.139
0.134
ill
107
78.0-123
3.66
20
Trichloroethene 0.125
0.138
0.133
110
106
76.0-126
3.69
20
Trichlorofluoromethane 0.125
0.112
0.110
89.6
88.0
61.0-142
1.80
20
1,2,3-Trichloropropane 0.125
0.121
0.115
96.8
92.0
67.0-129
5.08
20
Vinyl chloride 0.125
0.135
0.131
108
105
63.0-134
3.01
20
(S) Toluene-d8
107
105
75.0-131
(S)4-Bromofluorobenzene
104
100
670-138
(S) 1,2-Dich/oroethone-d4
85.2
82.9
70.0-130
ACCOUNT:
PROJECT:
SDG:
DATE/TIME: PAGE:
Terracon - Raleigh, NC
70217369
L1376539
07/29/2116:01 14 of 24
FP1
FC
FSS
4
Cn
FSr
�GI
FAI
FSC
WG1704627 QUALITY CONTROL SUMMARY
Volatile Organic Compounds (GC/MS) by Method 8260D 1-1376539-04,07
Method Blank (MB)
(MB) R3680158-3 07/15/21 20:55
MB Result MB Qualifier
MB MDL
MB RDL
Analyte
ug/I
ug/I
ug/I
Bromodichloromethane
U
0.136
1.00
Carbon tetrachloride
U
0.128
1.00
Chlorobenzene
U
0.116
1.00
Chlorodibromomethane
U
0.140
1.00
Chloroethane
U
0.192
5.00
Chloroform
U
0.111
5.00
Chloromethane
U
0.960
2.50
2-Chlorotoluene
U
0.106
1.00
4-Chlorotoluene
U
0.114
1.00
1,2-Dibromo-3-Chloropropane
U
0.276
5.00
1,2-Dichlorobenzene
U
0.107
1.00
1,3-Dichlorobenzene
U
0.110
1.00
1,4-Dichlorobenzene
U
0.120
1.00
Dichlorodifluoromethane
U
0.374
5.00
1,1-Dichloroethane
U
0.100
1.00
1,2-Dichloroethane
U
0.0819
1.00
1,1-Dichloroethene
U
0.188
1.00
cis-1,2-Dichloroethene
U
0.126
1.00
trans-1,2-Dichloroethene
U
0.149
1.00
1,2-Dichloropropane
U
0.149
1.00
1,1-Dichloropropene
U
0.142
1.00
1,3-Dichloropropane
U
0.110
1.00
cis-1,3-Dichloropropene
U
0.111
1.00
trans-1,3-Dichloropropene
U
0.118
1.00
2,2-Dichloropropane
U
0.161
1.00
Hexachloro-1,3-butadiene
U
0.337
1.00
Methylene Chloride
U
0.430
5.00
1,1,1,2-Tetrachloroethane
U
0.147
1.00
1,1,2,2-Tetrachloroethane
U
0.133
1.00
Tetrachloroethene
U
0.300
1.00
1,1,2-Trichlorotrifluoroethane
U
0.180
1.00
1,2,3-Trichlorobe nzene
0.548 J
0.230
1.00
1,2,4-Trichlorobenzene
U
0.481
1.00
1,1,1-Trichloroethane
U
0.149
1.00
1,1,2-Trichloroethane
U
0.158
1.00
Trichloroethene
U
0.190
1.00
Trichlorofluoromethane
U
0.160
5.00
1,2,3-Trichloropropane
U
0.237
2.50
Vinyl chloride
U
0.234
1.00
(S) Toluene-d8
107
80.0-120
ACCOUNT:
PROJECT: SDG: DATE/TIME: PAGE:
Terracon
- Raleigh, NC
70217369 L1376539 07/29/2116:01 15 of 24
FP1
FC
FSS
4
Cn
FSr
�GI
FAI
FSC
WG1704627
Volatile Organic Compounds (GC/MS) by Method 8260D
QUALITY CONTROL SUMMARY
1-1376539-04,07
Method Blank (MB)
(MB) R3680158-3 07/15/21 20:55
MB Result
Analyte ug/I
(S) 4-Bromof/uorobenzene 97.9
(S)1,2-Dichloroethane-d4 103
MB Qualifier MB MDL MB RDL
ug/1 ug/I
77.0-126
70.0-130
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3680158-1 07/15/21 19:55 • (LCSD) R3680158-2 07/15/21 20:15
Spike Amount
LCS Result
LCSD Result
Analyte
ug/I
ug/I
ug/1
Bromodichloromethane
5.00
4.65
4.57
Carbon tetrachloride
5.00
4.67
4.09
Chlorobenzene
5.00
5.37
5.27
Chlorodibromomethane
5.00
5.17
5.29
Chloroethane
5.00
5.86
5.15
Chloroform
5.00
4.89
4.45
Chloromethane
5.00
6.62
6.21
2-Chlorotoluene
5.00
5.97
6.04
4-Chlorotoluene
5.00
6.05
5.85
1,2-Dibromo-3-Chloropropane
5.00
4.92
5.07
1,2-Dichlorobenzene
5.00
6.06
6.07
1,3-Dichlorobenzene
5.00
6.32
6.52
1,4-Dichlorobenzene
5.00
5.64
5.76
Dichlorodifluoromethane
5.00
3.66
3.55
1,1-Dichloroethane
5.00
5.27
5.06
1,2-Dichloroethane
5.00
5.47
4.93
1,1-Dichloroethene
5.00
5.03
4.39
cis-1,2-Dichloroethene
5.00
5.03
4.57
trans-1,2-Dichloroethene
5.00
4.62
4.29
1,2-Dichloropropane
5.00
4.93
4.74
1,1-Dichloropropene
5.00
5.05
4.90
1,3-Dichloropropane
5.00
5.72
5.47
cis-1,3-Dichloropropene
5.00
5.09
4.72
trans-1,3-Dichloropropene
5.00
6.34
5.84
2,2-Dichloropropane
5.00
4.96
4.75
Hexachloro-1,3-butadiene
5.00
4.99
5.39
Methylene Chloride
5.00
4.81
4.52
1,1,1,2-Tetrachloroethane
5.00
5.40
4.94
1,1,2,2-Tetrachloroethane
5.00
5.40
5.83
Tetrachloroethene
5.00
5.32
5.55
1,1,2-Trichlorotrifluoroethane
5.00
5.18
4.54
ACCOUNT:
Terracon - Raleigh, NC
LCS Rec.
LCSD Rec.
Rec. Limits
LCS Qualifier LCSD Qualifier RPD
RPD Limits
93.0
91.4
75.0-120
1.74
20
93.4
81.8
68.0-126
13.2
20
107
105
80.0-121
1.88
20
103
106
77.0-125
2.29
20
117
103
47.0-150
12.9
20
97.8
89.0
73.0-120
9.42
20
132
124
41.0-142
6.39
20
119
121
76.0-123
1.17
20
121
117
75.0-122
3.36
20
98.4
101
58.0-134
3.00
20
121
121
79.0-121
0.165
20
126
130
79.0-120
J4 J4 3.12
20
113
115
79.0-120
2.11
20
73.2
71.0
51.0-149
3.05
20
105
101
70.0-126
4.07
20
109
98.6
70.0-128
10.4
20
101
87.8
71.0-124
13.6
20
101
91.4
73.0-120
9.58
20
92.4
85.8
73.0-120
7.41
20
98.6
94.8
77.0-125
3.93
20
101
98.0
74.0-126
3.02
20
114
109
80.0-120
4.47
20
102
94.4
80.0-123
7.54
20
127
117
78.0-124
J4 8.21
20
99.2
95.0
58.0-130
4.33
20
99.8
108
54.0-138
7.71
20
96.2
90.4
67.0-120
6.22
20
108
98.8
75.0-125
8.90
20
108
117
65.0-130
7.66
20
106
ill
72.0-132
4.23
20
104
90.8
69.0-132
13.2
20
PROJECT:
SDG:
DATE/TIME: PAGE:
70217369
L1376539
07/29/21 16:01 16 of 24
FP1
FC
FSS
4
Cn
FSr
�GI
FAI
FSC
WG1704627 QUALITY CONTROL SUMMARY
Volatile Organic Compounds (GC/MS) by Method 8260D L1376539-04,07
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3680158-1 07/15/21 19:55 • (LCSD) R3680158-2 07/15/21 20:15
Spike Amount
LCS Result
LCSD Result
LCS Rec.
LCSD Rec.
Rec. Limits
LCS Qualifier LCSD Qualifier RPD
RPD Limits
Analyte
ug/I
ug/I
ug/I
%
%
%
%
%
1,2,3-Trichlorobenzene
5.00
4.78
5.11
95.6
102
50.0-138
6.67
20
1,2,4-Trichlorobenzene
5.00
4.88
5.27
97.6
105
57.0-137
7.68
20
1,1,1-Trichloroethane
5.00
5.27
4.90
105
98.0
73.0-124
7.28
20
1,1,2-Trichloroethane
5.00
5.17
5.23
103
105
80.0-120
1.15
20
Trichloroethene
5.00
4.94
4.29
98.8
85.8
78.0-124
14.1
20
Trichlorofluoromethane
5.00
4.34
3.83
86.8
76.6
59.0-147
12.5
20
1,2,3-Trichloropropane
5.00
6.46
6.39
129
128
73.0-130
1.09
20
Vinyl chloride
5.00
5.47
4.88
109
97.6
67.0-131
11.4
20
(S) Toluene-d8
105
102
80.0-120
(S) 4-Bromofluorobenzene
91.7
96.6
77.0-126
(S)1,2-Dich/oroethane-d4
104
102
70.0-130
FP1
FC
FSS
4
Cn
FSr
�GI
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Terracon - Raleigh, NC 70217369 L1376539 07/29/2116:01 17 of 24
WG1706422
Volatile Organic Compounds (GC/MS) by Method 8260D
QUALITY CONTROL SUMMARY
1-1376539-05,06
Method Blank (MB)
(MB) R3680986-3 07/16/21 18:13
MB Result
Analyte
ug/I
Bromodichloromethane
U
Carbon tetrachloride
U
Chlorobenzene
U
Chlorodibromomethane
U
Chloroethane
U
Chloroform
U
Chloromethane
U
2-Chlorotoluene
U
4-Chlorotoluene
U
1,2-Dibromo-3-Chloropropane
U
1,2-Dichlorobenzene
U
1,3-Dichlorobenzene
U
1,4-Dichlorobenzene
U
Dichlorodifluoromethane
U
1,1-Dichloroethane
U
1,2-Dichloroethane
U
1,1-Dichloroethene
U
cis-1,2-Dichloroethene
U
trans-1,2-Dichloroethene
U
1,2-Dichloropropane
U
1,1-Dichloropropene
U
1,3-Dichloropropane
U
cis-1,3-Dichloropropene
U
trans-1,3-Dichloropropene
U
2,2-Dichloropropane
U
Hexachloro-1,3-butadiene
U
Methylene Chloride
U
1,1,1,2-Tetrachloroethane
U
1,1,2,2-Tetrachloroethane
U
Tetrachloroethene
U
1,1,2-Trichlorotrifluoroethane
U
1,2,3-Trichlorobe nzene
U
1,2,4-Trichlorobenzene
U
1,1,1-Trichloroethane
U
1,1,2-Trichloroethane
U
Trichloroethene
U
Trichlorofluoromethane
U
1,2,3-Trichloropropane
U
Vinyl chloride
U
(S) Toluene-d8
104
MB Qualifier MB MDL MB RDL
ug/I ug/I
0.136 1.00
0.128 1.00
0.116 1.00
0.140 1.00
0.192 5.00
0.111 5.00
0.960 2.50
0.106 1.00
0.114 1.00
0.276 5.00
0.107 1.00
0.110 1.00
0.120 1.00
0.374 5.00
0.100 1.00
0.0819 1.00
0.188 1.00
0.126 1.00
0.149 1.00
0.149 1.00
0.142 1.00
0.110 1.00
0.111 1.00
0.118 1.00
0.161 1.00
0.337 1.00
0.430 5.00
0.147 1.00
0.133 1.00
0.300 1.00
0.180 1.00
0.230 1.00
0.481 1.00
0.149 1.00
0.158 1.00
0.190 1.00
0.160 5.00
0.237 2.50
0.234 1.00
80.0-120
FP1
FC
FSS
4
Cn
FSr
�GI
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Terracon - Raleigh, INC 70217369 L1376539 07/29/2116:01 18 of 24
WG1706422
Volatile Organic Compounds (GC/MS) by Method 8260D
QUALITY CONTROL SUMMARY
1-1376539-05,06
Method Blank (MB)
(MB) R3680986-3 07/16/21 18:13
MB Result
Analyte ug/I
(S) 4-Bromof/uorobenzene 92.5
(S)1,2-Dichloroethane-d4 106
MB Qualifier MB MDL MB RDL
ug/1 ug/I
Laboratory Control Sample (LCS)
(LCS) R3680986-1 07/16/21 16:52
77.0-126
70.0-130
Spike Amount
LCS Result
LCS Rec.
Rec. Limits LCS Qualifier
Analyte
ug/I
Ug/1
%
%
Bromodichloromethane
5.00
5.37
107
75.0-120
Carbon tetrachloride
5.00
5.29
106
68.0-126
Chlorobenzene
5.00
5.48
110
80.0-121
Chlorodibromomethane
5.00
4.80
96.0
77.0-125
Chloroethane
5.00
5.06
101
47.0-150
Chloroform
5.00
5.81
116
73.0-120
Chloromethane
5.00
5.18
104
41.0-142
2-Chlorotoluene
5.00
5.40
108
76.0-123
4-Chlorotoluene
5.00
5.61
112
75.0-122
1,2-Dibromo-3-Chloropropane
5.00
4.38
87.6
58.0-134
1,2-Dichlorobenzene
5.00
5.25
105
79.0-121
1,3-Dichlorobenzene
5.00
5.48
110
79.0-120
1,4-Dichlorobenzene
5.00
5.16
103
79.0-120
Dichlorodifluoromethane
5.00
4.76
95.2
51.0-149
1,1-Dichloroethane
5.00
5.74
115
70.0-126
1,2-Dichloroethane
5.00
5.82
116
70.0-128
1,1-Dichloroethene
5.00
5.06
101
71.0-124
cis-1,2-Dichloroethene
5.00
5.43
109
73.0-120
trans-1,2-Dichloroethene
5.00
5.24
105
73.0-120
1,2-Dichloropropane
5.00
5.27
105
77.0-125
1,1-Dichloropropene
5.00
5.28
106
74.0-126
1,3-Dichloropropane
5.00
5.42
108
80.0-120
cis-1,3-Dichloropropene
5.00
5.48
110
80.0-123
trans-1,3-Dichloropropene
5.00
4.99
99.8
78.0-124
2,2-Dichloropropane
5.00
5.50
110
58.0-130
Hexachloro-1,3-butadiene
5.00
3.24
64.8
54.0-138
Methylene Chloride
5.00
5.32
106
67.0-120
1,1,1,2-Tetrachloroethane
5.00
5.34
107
75.0-125
1,1,2,2-Tetrachloroethane
5.00
5.77
115
65.0-130
Tetrachloroethene
5.00
5.32
106
72.0-132
1,1,2-Trichlorotrifluoroethane
5.00
5.92
118
69.0-132
ACCOUNT:
PROJECT: SDG: DATE/TIME: PAGE:
Terracon
- Raleigh, NC
70217369 L1376539 07/29/2116:01 19 of 24
FP1
FC
FSS
4
Cn
FSr
�GI
FAI
FSC
WG1706422
QUALITY CONTROL SUMMARY
Volatile Organic Compounds (GC/MS) by Method 8260D
1-1376539-05,06
Laboratory Control Sample (LCS)
(LCS) R3680986-1 07/16/21 16:52
Spike Amount LCS Result
LCS Rec.
Rec. Limits LCS Qualifier
Analyte ug/I ug/I
%
%
1,2,3-Trichlorobenzene 5.00 3.16
63.2
50.0-138
1,2,4-Trichlorobenzene 5.00 3.39
67.8
57.0-137
1,1,1-Trichloroethane 5.00 5.48
110
73.0-124
1,1,2-Trichloroethane 5.00 5.25
105
80.0-120
Trichloroethene 5.00 5.48
110
78.0-124
Trichlorofluoromethane 5.00 4.73
94.6
59.0-147
1,2,3-Trichloropropane 5.00 5.80
116
73.0-130
Vinyl chloride 5.00 4.78
95.6
67.0-131
(S) Toluene-d8
102
80.0-120
(S) 4-Bromofluorobenzene
93.3
77.0-126
(S)1,2-Dich/oroethane-d4
107
70.0-130
ACCOUNT:
PROJECT: SDG: DATE/TIME: PAGE:
Terracon - Raleigh, NC
70217369 L1376539 07/29/2116:01 20 of 24
FP1
FC
FSS
4
Cn
FSr
�GI
FAI
FSC
GLOSSARY OF TERMS
Guide to Reading and Understanding Your Laboratory Report
The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not
intended as a comprehensive explanation, and if you have additional questions please contact your project representative.
Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name,
Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On -Site Data, Sampling Collection Dates/Times, and
Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received.
Abbreviations and Definitions
CP
IP
FTC
FSS
MDL
Method Detection Limit.
RDL
Reported Detection Limit.
rCn
Rec.
Recovery.
RPD
Relative Percent Difference.
FSr
SDG
Sample Delivery Group.
Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and
(S)
Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be
rqC
detected in all environmental media.
U
Not detected at the Reporting Limit (or MDL where applicable).
Analyte
The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes
reported.
If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the
Dilution
standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the
FAI
laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the
result reported has already been corrected for this factor.
These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal
Limits
for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or
SC
duplicated within these ranges.
This column provides a letter and/or number designation that corresponds to additional information concerning the result
Qualifier
reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and
potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable.
The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was
no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL"
Result
(Below Detectable Levels). The information in the results column should always be accompanied by either an MDL
(Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect
or report for this analyte.
Uncertainty
(Radiochemistry)
Confidence level of 2 sigma.
A brief discussion about the included sample results, including a discussion of any non -conformances to protocol
Case Narrative (Cn)
observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will
be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.
Quality Control
This section of the report includes the results of the laboratory quality control analyses required by procedure or
Summary (Qc)
analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not
being performed on your samples typically, but on laboratory generated material.
This is the document created in the field when your samples were initially collected. This is used to verify the time and
Sample Chain of
date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This
Custody (Sc)
chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the
samples from the time of collection until delivery to the laboratory for analysis.
This section of your report will provide the results of all testing performed on your samples. These results are provided
Sample Results (Sr)
by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for
each sample will provide the name and method number for the analysis reported.
Sample Summary (Ss)
This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and
times of preparation and/or analysis.
Qualifier
Description
C3
The reported concentration is an estimate. The continuing calibration standard associated with this data responded low.
Method sensitivity check is acceptable.
J
The identification of the analyte is acceptable; the reported value is an estimate.
J4
The associated batch QC was outside the established quality control range for accuracy.
ACCOUNT:
PROJECT: SDG: DATE/TIME: PAGE:
Terracon - Raleigh, NC
70217369 L1376539 07/29/2116:01 21 of 24
ACCREDITATIONS & LOCATIONS
Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122
Alabama
40660
Nebraska
NE-OS-15-05
Alaska
17-026
Nevada
TN000032021-1
Arizona
AZ0612
New Hampshire
2975
Arkansas
88-0469
New Jersey—NELAP
TN002
California
2932
New Mexico
TN00003
Colorado
TN00003
New York
11742
Connecticut
PH-0197
North Carolina
Env375
Florida
E87487
North Carolina'
DW21704
Georgia
NELAP
North Carolinas
41
Georgia'
923
North Dakota
R-140
Idaho
TN00003
Ohio—VAP
CL0069
Illinois
200008
Oklahoma
9915
Indiana
C-TN-01
Oregon
TN200002
Iowa
364
Pennsylvania
68-02979
Kansas
E-10277
Rhodelsland
LA000356
Kentucky16
KY90010
South Carolina
84004002
Kentucky 2
16
South Dakota
n/a
Louisiana
A130792
Tennessee' °
2006
Louisiana
LA018
Texas
T104704245-20-18
Maine
TN00003
Texas'
LAB0152
Maryland
324
Utah
TN000032021-11
Massachusetts
M-TN003
Vermont
VT2006
Michigan
9958
Virginia
110033
Minnesota
047-999-395
Washington
C847
Mississippi
TN00003
West Virginia
233
Missouri
340
Wisconsin
998093910
Montana
CERT0086
Wyoming
A21-A
A21-A — ISO 17025
1461.01
AIHA-LAP,LLC EMLAP
100789
A21-A — ISO 17025 s
1461.02
DOD
1461.01
Canada
1461.01
USDA
P330-15-00234
EPA—Crypto
TN00003
Drinking Water 2 Underground Storage Tanks 'Aquatic Toxicity ° Chemical/Microbiological 'Mold 6 Wastewater n/a Accreditation not applicable
Not all certifications held by the laboratory are applicable to the results reported in the attached report.
Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical.
FP1
FTc
FSS
4
Cn
FSr
rqc
ql
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME:
Terracon - Raleigh, NC 70217369 L1376539 07/29/2116:01
PAGE:
22 of 24
Company Name/Address:
Billing Information:
Analysis/Container/Preservative
i
chain of Custody Page_of
on
\
*ESC
2401 401 Br Brentwood Rd STE 107
Raleigh, NC 27604
I
L. A 9 C I E N C E 5
Report to:
Ethan Dinwiddie
�
L
i
Mcvntl ebaMn Rd 1
Moumm lkt, TN 3711d
R
IAonewre:615.756.Sa5d
: 800767-5859 },
F.. 515 758-5859
Email
ethan.dinwiddie@terracon.com
Project
Description: Proposed CFA #04954
City/State
Collected: c� l #
Lit �i - -
L-094
p
Y
m
C
U
_
Phone: (919) 873-2211
Client Project #
lab Project #
I
Fax
70217369
i
«
a'
Table
_
m
a
W
Collect db (print)'
T7DJk
Site/Facility ID#
P.O.#
Acctnum:TERRRNC
r�W
j
V
0
C
Template:
Collecte re):
Bush? (Lab MUST Be Notified)
Date Results Needed
—__ Same Day ........... ........... ....2op%
,
!
O
Q
'
O
Prelogin:
eat Day ........ _..........._......IW%
oNp
N
TSR. Wagner
Email? NO �YeS
Immediately
Packed on Ice N_ Y�
wo Day .............................. 50%
_Three Day ............................. 25%
FAX? —NO _Yes
No.
of
i
X
U
W
U
Cooler:
Shipped Via:
Sample ID
Comp/Grab
Matrix •
Depth
Date
Time
mrs
0
Rem./conummam
samRk xlhh o�rol
3
T -oz vl
(s
Se-
(,-�%D
02
TW-o3
isw
—
�D 2 S
Lj -DL
(Tr
6w
—
-nr
//zo
3
--
I w-03
f�•bb
—
izY
T3-0 (
•Matrix: SS - Soil GW- Groundwater WW- WasteVilater DW- Drinking Water OT - Other pH Temp
Remarks: Flow Other Mold #
Relinquishedb :Signature)
Date:
Time:
Received by: (Signature)
Samples returned via: ❑UPS
Condition: (lab use only)
(,' '2
3 ( L
1300
❑ FedExx/ ❑ Courier ❑
Relinquished by: (Signature)
Date:
Time:
Received by: (Signature)
Tep0'C Bottles Received:
mp�6
/d"
_
Z. ./:-z.-j
CDC Seal Intact: _Y _N f NA
Relinquished by : (Signature)
Date: Time:
Re ' dfcr lab - y. (Sign r
Date: Time:
pH Checked:
NCF:
L13���-�'1
Pace Analytical National Center for Testing & Innovation
Cooler Receipt F.
Client:
Cooler Received/Opened On:7ffl 10 / 21 Temperature:
Received By:/�
Signature:
Receipt Check List NP
Yes
No
COC Seal Present / Intact?
COC Signed / Accurate?
Bottles arrive intact?
Correct bottles used?
Sufficient volume sent?
If Applicable
VOA Zero headspace?
Preservation Correct / Checked?
aceAnalytical
ANALYTICAL REPORT
July 29, 2021
Revised Report
Terracon - Raleigh, NC
Sample Delivery Group
Samples Received:
Project Number:
Description:
L1376689
07/10/2021
70217369
Proposed CFA #04954
Report To: Ethan Dinwiddie
2401 Brentwood Rd
Ste 107
Raleigh, NC 27604
Entire Report Reviewed By: 4�41
Heather J Wagner
Project Manager
Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be
reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace
Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067 and
ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided,
and as the samples are received.
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Terracon - Raleigh, NC 70217369 L1376689 07/29/2116:02 1 of 12
TABLE OF CONTENTS
Cp: Cover Page
Tc: Table of Contents
Ss: Sample Summary
3
Cn: Case Narrative
4
Sr: Sample Results
5
SV-01 L1376689-01
5
SV-02 L1376689-02
6
Qc: Quality Control Summary
7
Volatile Organic Compounds (MS) by Method TO-15
7
GI: Glossary of Terms
10
Al: Accreditations & Locations
11
Sc: Sample Chain of Custody
12
ACCOUNT: PROJECT: SDG:
DATE/TIME: PAGE:
Terracon - Raleigh, NC 70217369 L1376689
07/29/2116:02 2 of 12
SAMPLE SUMMARY
SV-01 L1376689-01 Air
Collected by
Collected date/time
07/09/2114:44
Received date/time
07/10/2109:15
C p
Method
Batch Dilution Preparation
Analysis
Analyst Location
date/time
date/time
FTC
Volatile Organic Compounds (MS) by Method TO-15
WG1703833 1 07/12/2112:49
07/12/2112:49
FKG Mt. Juliet, TN
Collected by
Collected date/time
Received date/time
SV-02 L1376689-02 Air
07/09/2115:12
07/10/2109:15
F7--]
Method
Volatile Organic Compounds (MS) by Method TO-15
Volatile Organic Compounds (MS) by Method TO-15
Batch Dilution Preparation
Analysis
Analyst Location
u
date/time
date/time
1 07/12/2113:32
07/12/2113:32
FKG Mt. Juliet, TN
FSrWG1703833
WG1705060 100 07/14/2118:07
07/14/2118:07
FKG Mt. Juliet, TN
RC
F,
FAI
FSC
ACCOUNT:
Terracon - Raleigh, NC
PROJECT: SDG: DATE/TIME: PAGE:
70217369 L1376689 07/29/21 16:02 3 of 12
CASE NARRATIVE
FP
All sample aliquots were received at the correct temperature, in the proper containers, with the
appropriate preservatives, and within method specified holding times, unless qualified or notated within
the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples
FC
have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control
are within established criteria except where addressed in this case narrative, a non-conformance form
or properly qualified within the sample results. By my digital signature below, I affirm to the best of my
FSS
knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the
quality of the data have been identified by the laboratory, and no information or data have been
knowingly withheld that would affect the quality of the data.
Fr
RC
F,
Heather J Wagner
FAI
Project Manager
FSC
Report Revision History
Level II Report -Version 1: 07/19/21 15:13
Project Narrative
Revised Report: Revised to report only chloronated VOC compounds per client request. This report replaces the report issued
7/19/2021.
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Terracon - Raleigh, NC 70217369 L1376689 07/29/2116:02 4 of 12
SV-01
Collected date/time: 07/09/21 14:44
SAMPLE RESULTS - 01
L1376689
Volatile Organic Compounds (MS) by Method TO-15
CAS #
Mol. Wt.
RDL1
RDL2
Result
Analyte
ppbv
ug/m3
ppbv
Allyl chloride
107-05-1
76.53
0.200
0.626
ND
Benzyl Chloride
100-44-7
127
0.200
1.04
ND
Bromodichloromethane
75-27-4
164
0.200
1.34
ND
Carbon tetrachloride
56-23-5
154
0.200
1.26
ND
Chlorobenzene
108-90-7
113
0.200
0.924
ND
Chloroethane
75-00-3
64.50
0.200
0.528
ND
Chloroform
67-66-3
119
0.200
0.973
ND
Chloromethane
74-87-3
50.50
0.200
0.413
ND
2-Chlorotoluene
95-49-8
126
0.200
1.03
ND
Dibromochloromethane
124-48-1
208
0.200
1.70
ND
1,2-Dichlorobenzene
95-50-1
147
0.200
1.20
ND
1,3-Dichlorobenzene
541-73-1
147
0.200
1.20
ND
1,4-Dichlorobenzene
106-46-7
147
0.200
1.20
ND
1,2-Dichloroethane
107-06-2
99
0.200
0.810
ND
1,1-Dichloroethane
75-34-3
98
0.200
0.802
ND
1,1-Dichloroethene
75-35-4
96.90
0.200
0.793
ND
cis-1,2-Dichloroethene
156-59-2
96.90
0.200
0.793
ND
trans-1,2-Dichloroethene
156-60-5
96.90
0.200
0.793
ND
1,2-Dichloropropane
78-87-5
113
0.200
0.924
ND
cis-1,3-Dichloropropene
10061-01-5
111
0.200
0.908
ND
trans-1,3-Dichloropropene
10061-02-6
111
0.200
0.908
ND
Trichlorofluoromethane
75-69-4
137.40
0.200
1.12
0.257
Dichlorodifluoromethane
75-71-8
120.92
0.200
0.989
ND
1,1,2-Trichlorotrifluoroethane
76-13-1
187.40
0.200
1.53
ND
1,2-Dichlorotetrafluoroethane
76-14-2
171
0.200
1.40
ND
Hexachloro-1,3-butadiene
87-68-3
261
0.630
6.73
ND
Methylene Chloride
75-09-2
84.90
0.200
0.694
ND
1,1,2,2-Tetrachloroethane
79-34-5
168
0.200
1.37
ND
Tetrachloroethylene
127-18-4
166
0.200
1.36
1.76
1,2,4-Trichlorobenzene
120-82-1
181
0.630
4.66
ND
1,1,1-Trichloroethane
71-55-6
133
0.200
1.09
ND
1,1,2-Trichloroethane
79-00-5
133
0.200
1.09
ND
Trichloroethylene
79-01-6
131
0.200
1.07
ND
Vinyl chloride
75-01-4
62.50
0.200
0.511
ND
(S)1,4-Bromof/uorobenzene
460-00-4
175
60.0-140
92.9
Result Qualifier Dilution Batch
-/i Z
ND
1 WG1703833
ND
1 WG1703833
ND
1 WG1703833
ND
1 WG1703833
ND
1 WG1703833
ND
1 WG1703833
ND
1 WG1703833
ND
1 WG1703833
ND
1 WG1703833
ND
1 WG1703833
ND
1 WG1703833
ND
1 WG1703833
ND
1 WG1703833
ND
1 WG1703833
ND
1 WG1703833
ND
1 WG1703833
ND
1 WG1703833
ND
1 WG1703833
ND
1 WG1703833
ND
1 WG1703833
ND
1 WG1703833
1.44
1 WG1703833
ND
1 WG1703833
ND
1 WG1703833
ND
1 WG1703833
ND
1 WG1703833
ND
1 WG1703833
ND
1 WG1703833
11.9
1 WG1703833
ND
1 WG1703833
ND
1 WG1703833
ND
1 WG1703833
ND
1 WG1703833
ND
1 WG1703833
WG1703833
FP1
FTc
FSS
4
Cn
1qc
I ql
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Terracon - Raleigh, NC 70217369 L1376689 07/29/2116:02 5 of 12
SV-02 SAMPLE
Collected date/time: 07/09/21 15:12
Volatile Organic Compounds (MS) by Method TO-15
RESULTS
L1376689
- 02
CAS #
Mol. Wt.
RDL1
RDL2
Result
Result
Qualifier Dilution Batch
Analyte
ppbv
ug/m3
ppbv
ug/m3
Allyl chloride
107-05-1
76.53
0.200
0.626
ND
ND
1 WG1703833
Benzyl Chloride
100-44-7
127
0.200
1.04
ND
ND
1 WG1703833
Bromodichloromethane
75-27-4
164
0.200
1.34
ND
ND
1 WG1703833
Carbon tetrachloride
56-23-5
154
0.200
1.26
ND
ND
1 WG1703833
Chlorobenzene
108-90-7
113
0.200
0.924
ND
ND
1 WG1703833
Chloroethane
75-00-3
64.50
20.0
52.8
3260
8600
100 WG1705060
Chloroform
67-66-3
119
0.200
0.973
3.59
17.5
1 WG1703833
Chloromethane
74-87-3
50.50
0.200
0.413
ND
ND
1 WG1703833
2-Chlorotoluene
95-49-8
126
0.200
1.03
ND
ND
1 WG1703833
Dibromochloromethane
124-48-1
208
0.200
1.70
ND
ND
1 WG1703833
1,2-Dichlorobenzene
95-50-1
147
0.200
1.20
ND
ND
1 WG1703833
1,3-Dichlorobenzene
541-73-1
147
0.200
1.20
ND
ND
1 WG1703833
1,4-Dichlorobenzene
106-46-7
147
0.200
1.20
ND
ND
1 WG1703833
1,2-Dichloroethane
107-06-2
99
0.200
0.810
ND
ND
1 WG1703833
1,1-Dichloroethane
75-34-3
98
0.200
0.802
0.200
0.802
1 WG1703833
1,1-Dichloroethene
75-35-4
96.90
0.200
0.793
ND
ND
1 WG1703833
cis-1,2-Dichloroethene
156-59-2
96.90
0.200
0.793
ND
ND
1 WG1703833
trans-1,2-Dichloroethene
156-60-5
96.90
0.200
0.793
ND
ND
1 WG1703833
1,2-Dichloropropane
78-87-5
113
0.200
0.924
ND
ND
1 WG1703833
cis-1,3-Dichloropropene
10061-01-5
111
0.200
0.908
ND
ND
1 WG1703833
trans-1,3-Dichloropropene
10061-02-6
111
0.200
0.908
ND
ND
1 WG1703833
Trichlorofluoromethane
75-69-4
137.40
0.200
1.12
1.55
8.71
1 WG1703833
Dichlorodifluoromethane
75-71-8
120.92
0.200
0.989
ND
ND
1 WG1703833
1,1,2-Trichlorotrifluoroethane
76-13-1
187.40
0.200
1.53
ND
ND
1 WG1703833
1,2-Dichlorotetrafluoroethane
76-14-2
171
0.200
1.40
ND
ND
1 WG1703833
Hexachloro-1,3-butadiene
87-68-3
261
0.630
6.73
ND
ND
1 WG1703833
Methylene Chloride
75-09-2
84.90
0.200
0.694
ND
ND
1 WG1703833
1,1,2,2-Tetrachloroethane
79-34-5
168
0.200
1.37
ND
ND
1 WG1703833
Tetrachloroethylene
127-18-4
166
20.0
136
81.0
550
100 WG1705060
1,2,4-Trichlorobenzene
120-82-1
181
0.630
4.66
ND
ND
1 WG1703833
1,1,1-Trichloroethane
71-55-6
133
0.200
1.09
ND
ND
1 WG1703833
1,1,2-Trichloroethane
79-00-5
133
0.200
1.09
ND
ND
1 WG1703833
Trichloroethylene
79-01-6
131
0.200
1.07
0.230
1.23
1 WG1703833
Vinyl chloride
75-01-4
62.50
0.200
0.511
ND
ND
1 WG1703833
(S)1,4-Bromofluorobenzene
460-00-4
175
60.0-140
88.9
WG1703833
(S)1,4-Bromofluorobenzene
460-00-4
175
60.0-140
100
WG1705060
ACCOUNT:
PROJECT:
SDG:
DATE/TIME: PAGE:
Terracon -
Raleigh, NC
70217369
L1376689
07/29/2116:02 6 of 12
FP1
FTc
FSS
4
Cn
1qc
I ql
FAI
FSC
WG1703833
Volatile Organic Compounds (MS) by Method TO-15
QUALITY CONTROL SUMMARY
L1376689-01,02
Method Blank (MB)
(MB) R3678938-2 07/12/21 10:21
MB Result
MB Qualifier MB MDL
MB RDL
Analyte
ppbv
ppbv
ppbv
Allyl Chloride
U
0.114
0.200
Benzyl Chloride
U
0.0598
0.200
Bromodichloromethane
U
0.0702
0.200
Carbon tetrachloride
U
0.0732
0.200
Chlorobenzene
U
0.0832
0.200
Chloroethane
U
0.0996
0.200
Chloroform
U
0.0717
0.200
Chloromethane
U
0.103
0.200
2-Chlorotoluene
U
0.0828
0.200
Dibromochloromethane
U
0.0727
0.200
1,2-Dichlorobenzene
U
0.128
0.200
1,3-Dichlorobenzene
U
0.182
0.200
1,4-Dichlorobenzene
U
0.0557
0.200
1,2-Dichloroethane
U
0.0700
0.200
1,1-Dichloroethane
U
0.0723
0.200
1,1-Dichloroethene
U
0.0762
0.200
cis-1,2-Dichloroethene
U
0.0784
0.200
trans-1,2-Dichloroethene
U
0.0673
0.200
1,2-Dichloropropane
U
0.0760
0.200
cis-1,3-Dichloropropene
U
0.0689
0.200
trans-1,3-Dichloropropene
U
0.0728
0.200
Trichlorofluoromethane
U
0.0819
0.200
Dichlorodifluoromethane
U
0.137
0.200
1,1,2-Trichlorotrifluoroethane
U
0.0793
0.200
1,2-Dichlorotetrafluoroethane
U
0.0890
0.200
Hexachloro-1,3-butadiene
U
0.105
0.630
Methylene Chloride
U
0.0979
0.200
1,1,2,2-Tetrachloroethane
U
0.0743
0.200
Tetrachloroethylene
U
0.0814
0.200
1,2,4-Trichlorobenzene
0.153
J 0.148
0.630
1,1,1-Trichloroethane
U
0.0736
0.200
1,1,2-Trichloroethane
U
0.0775
0.200
Trichloroethylene
U
0.0680
0.200
Vinyl chloride
U
0.0949
0.200
(S)1,4-Bromofluorobenzene
92.3
60.0-140
FP1
FC
FSS
4
Cn
FSr
�GI
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Terracon - Raleigh, NC 70217369 L1376689 07/29/2116:02 7 of 12
WG1703833 QUALITY CONTROL SUMMARY
Volatile Organic Compounds (MS) by Method TO-15 L1376689-01,02
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3678938-1 07/12/21 09:41 • (LCSD) R3678938-3 07/12/21 11:22
Spike Amount
LCS Result
LCSD Result
Analyte
ppbv
ppbv
ppbv
Dichlorodifluoromethane
3.75
3.80
3.79
1,2-Dichlorotetrafluoroethane
3.75
4.02
4.27
Chloromethane
3.75
3.47
3.59
Vinyl chloride
3.75
3.77
3.74
Chloroethane
3.75
3.51
3.57
Trichlorofluoromethane
3.75
3.87
4.03
1,1,2-Trichlorotrifluoroethane
3.75
3.95
4.07
1,1-Dichloroethene
3.75
3.63
3.78
1,1-Dichloroethane
3.75
3.61
3.74
Methylene Chloride
3.75
3.52
3.66
trans-1,2-Dichloroethene
3.75
3.67
3.74
cis-1,2-Dichloroethene
3.75
3.65
3.73
Chloroform
3.75
3.78
3.91
1,1,1-Trichloroethane
3.75
3.79
3.98
Carbon tetrachloride
3.75
3.76
3.88
1,2-Dichloroethane
3.75
3.73
3.75
Trichloroethylene
3.75
3.94
3.93
1,2-Dichloropropane
3.75
3.76
3.83
Bromodichloromethane
3.75
3.82
3.86
cis-1,3-Dichloropropene
3.75
3.75
3.83
trans-1,3-Dichloropropene
3.75
3.73
3.77
1,1,2-Trichloroethane
3.75
4.03
4.02
Tetrachloroethylene
3.75
4.26
4.31
Dibromochloromethane
3.75
3.99
3.98
Chlorobenzene
3.75
4.02
4.02
1,1,2,2-Tetrachloroethane
3.75
3.77
3.82
1,3-Dichlorobenzene
3.75
3.88
3.89
1,4-Dichlorobenzene
3.75
3.83
3.79
Benzyl Chloride
3.75
3.49
3.43
1,2-Dichlorobenzene
3.75
3.85
3.87
1,2,4-Trichlorobenzene
3.75
4.48
4.29
Hexachloro-1,3-butadiene
3.75
4.42
4.49
Allyl Chloride
3.75
3.37
3.27
2-Chlorotoluene
3.75
3.78
3.77
(S)1,4-Bromofluorobenzene
LCS Rec.
LCSD Rec.
Rec. Limits
LCS Qualifier LCSD Qualifier RPD
RPD Limits
101
101
64.0-139
0.264
25
107
114
70.0-130
6.03
25
92.5
95.7
70.0-130
3.40
25
101
99.7
70.0-130
0.799
25
93.6
95.2
70.0-130
1.69
25
103
107
70.0-130
4.05
25
105
109
70.0-130
2.99
25
96.8
101
70.0-130
4.05
25
96.3
99.7
70.0-130
3.54
25
93.9
97.6
70.0-130
3.90
25
97.9
99.7
70.0-130
1.89
25
97.3
99.5
70.0-130
2.17
25
101
104
70.0-130
3.38
25
101
106
70.0-130
4.89
25
100
103
70.0-130
3.14
25
99.5
100
70.0-130
0.535
25
105
105
70.0-130
0.254
25
100
102
70.0-130
1.84
25
102
103
70.0-130
1.04
25
100
102
70.0-130
2.11
25
99.5
101
70.0-130
1.07
25
107
107
70.0-130
0.248
25
114
115
70.0-130
1.17
25
106
106
70.0-130
0.251
25
107
107
70.0-130
0.000
25
101
102
70.0-130
1.32
25
103
104
70.0-130
0.257
25
102
101
70.0-130
1.05
25
93.1
91.5
70.0-152
1.73
25
103
103
70.0-130
0.518
25
119
114
70.0-160
4.33
25
118
120
70.0-151
1.57
25
89.9
87.2
70.0-130
3.01
25
101
101
70.0-130
0.265
25
94.4
93.1
60.0-140
FP1
FC
FSS
4
Cn
FSr
�GI
FAI
FSC
ACCOUNT:
Terracon - Raleigh, NC
PROJECT: SDG: DATE/TIME: PAGE:
70217369 L1376689 07/29/21 16:02 8 of 12
WG1705060
Volatile Organic Compounds (MS) by Method TO-15
Method Blank (MB)
(MB) R3679741-3 07/14/21 10:19
MB Result
Analyte ppbv
Chloroethane U
Tetrachloroethylene U
(S)1,4-Bromofluorobenzene 98.5
QUALITY CONTROL SUMMARY
L1376689-02
MB Qualifier MB MDL
MB RDL
ppbv
ppbv
0.0996
0.200
0.0814
0.200
60.0-140
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3679741-1 07/14/21 09:01 • (LCSD) R3679741-2 07/14/21 09:41
Spike Amount
LCS Result
LCSD Result
LCS Rec.
Analyte
ppbv
ppbv
ppbv
%
Chloroethane
3.75
4.08
4.15
109
Tetrachloroethylene
3.75
4.02
4.07
107
(S)1,4-Bromofluorobenzene
100
LCSD Rec.
111
109
97.4
Rec. Limits LCS Qualifier LCSD Qualifier RPD
70.0-130 1.70
70.0-130 1.24
60.0-140
RPD Limits
25
25
FP1
FC
FSS
4
Cn
FSr
�GI
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Terracon - Raleigh, NC 70217369 L1376689 07/29/2116:02 9 of 12
GLOSSARY OF TERMS
Guide to Reading and Understanding Your Laboratory Report
The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not
intended as a comprehensive explanation, and if you have additional questions please contact your project representative.
Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name,
Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On -Site Data, Sampling Collection Dates/Times, and
Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received.
Abbreviations and Definitions
CP
IP
FTC
FSS
MDL
Method Detection Limit.
ND
Not detected at the Reporting Limit (or MDL where applicable).
rCn
RDL
Reported Detection Limit.
Rec.
Recovery.
FSr
RPD
Relative Percent Difference.
SDG
Sample Delivery Group.
Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and
6
QC
(S)
Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be
detected in all environmental media.
U
Not detected at the Reporting Limit (or MDL where applicable).
Analyte
The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes
reported.
If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the
a
Dilution
standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the
laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the
result reported has already been corrected for this factor.
FSC
These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal
Limits
for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or
duplicated within these ranges.
This column provides a letter and/or number designation that corresponds to additional information concerning the result
Qualifier
reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and
potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable.
The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was
no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL"
Result
(Below Detectable Levels). The information in the results column should always be accompanied by either an MDL
(Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect
or report for this analyte.
Uncertainty
(Radiochemistry)
Confidence level of 2 sigma.
A brief discussion about the included sample results, including a discussion of any non -conformances to protocol
Case Narrative (Cn)
observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will
be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.
Quality Control
This section of the report includes the results of the laboratory quality control analyses required by procedure or
Summary (Qc)
analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not
being performed on your samples typically, but on laboratory generated material.
This is the document created in the field when your samples were initially collected. This is used to verify the time and
Sample Chain of
date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This
Custody (Sc)
chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the
samples from the time of collection until delivery to the laboratory for analysis.
This section of your report will provide the results of all testing performed on your samples. These results are provided
Sample Results (Sr)
by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for
each sample will provide the name and method number for the analysis reported.
Sample Summary (Ss)
This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and
times of preparation and/or analysis.
Qualifier
Description
J
The identification of the analyte is acceptable; the reported value is an estimate.
ACCOUNT:
PROJECT: SDG: DATE/TIME: PAGE:
Terracon - Raleigh, NC
70217369 L1376689 07/29/2116:02 10 of 12
ACCREDITATIONS & LOCATIONS
Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122
Alabama
40660
Nebraska
NE-OS-15-05
Alaska
17-026
Nevada
TN000032021-1
Arizona
AZ0612
New Hampshire
2975
Arkansas
88-0469
New Jersey—NELAP
TN002
California
2932
New Mexico
TN00003
Colorado
TN00003
New York
11742
Connecticut
PH-0197
North Carolina
Env375
Florida
E87487
North Carolina'
DW21704
Georgia
NELAP
North Carolinas
41
Georgia'
923
North Dakota
R-140
Idaho
TN00003
Ohio—VAP
CL0069
Illinois
200008
Oklahoma
9915
Indiana
C-TN-01
Oregon
TN200002
Iowa
364
Pennsylvania
68-02979
Kansas
E-10277
Rhodelsland
LA000356
Kentucky16
KY90010
South Carolina
84004002
Kentucky 2
16
South Dakota
n/a
Louisiana
A130792
Tennessee' °
2006
Louisiana
LA018
Texas
T104704245-20-18
Maine
TN00003
Texas'
LAB0152
Maryland
324
Utah
TN000032021-11
Massachusetts
M-TN003
Vermont
VT2006
Michigan
9958
Virginia
110033
Minnesota
047-999-395
Washington
C847
Mississippi
TN00003
West Virginia
233
Missouri
340
Wisconsin
998093910
Montana
CERT0086
Wyoming
A21-A
A21-A — ISO 17025
1461.01
AIHA-LAP,LLC EMLAP
100789
A21-A — ISO 17025 s
1461.02
DOD
1461.01
Canada
1461.01
USDA
P330-15-00234
EPA—Crypto
TN00003
Drinking Water 2 Underground Storage Tanks 'Aquatic Toxicity ° Chemical/Microbiological 'Mold 6 Wastewater n/a Accreditation not applicable
Not all certifications held by the laboratory are applicable to the results reported in the attached report.
Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical.
FP1
FTc
FSS
4
Cn
FSr
Rc
I ql
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Terracon - Raleigh, NC 70217369 L1376689 07/29/21 16:02 11 of 12
Company Name/Address: Billing Information:
Analy i / ntaln
_
/ Pf SP a
Vv
Chain of Page of
—
Terracon - Raleigh, NC
Accounts Payable Pres
2401 Brentwood Rd Chk
1 Brentwood Rd
�.
Ste 107
aceAnalytical
Ste
Ste 107
Raleigh. NC 27604 Raleigh, NC 27604
Report to.
Email To
Ethan Dlnwiddie ethan.dinwiddie@terracon.com;justin.fabrl2iani
12065 Lebanon Rd M—t auwt, TN 12122
Project Description: City/State Please Circle
Proposed CFA k04954
sabminnsa—pi.—lhnsham.1—mar
. [ansMutes acknowledgment and x Ptanse G1 the
and C. P.. 1—n it mteund t a
huva /hn+o
Collected PT MT CT ET
Aa�eiab: —1hubh1pas-s+andard-
terms Pat
Phone: 919-873-2211 Client Project k Lab Project #
70217369 TERRRNC-CHICK FIL A
SDG d M050
Collected by {print): Site/Facility )D p P p g
Table
_
Acctnum: TERRRNC
Co Pe a ):
Rush? (Lab MUST Be Notified) Quote N
Template7160820
_ Same Day _ Five Day M
Prelogin: P856444
Day _ 5 Day (Rod only) pate Results Needed
Immediately wo Day 10 Day (Rad only)
Packed No
PM: 873 -Heather 1 Wa ner
on IceY , Three Day
Lei
PB: t�z
of
Sample ID Mu'f
p Comp/Grab Matrix ` Depth Date Time ntrs r1
Shipped via: FedEX Ground
r o I U"I
Remarks 5ample a (lab only(
V Air Z L Lj 1 X
Ir7
L Air J 'i 2v,
�' Ll
Matrix:
SS - Soil AIR - Air F - Filter
GW - Groundwater B - Bioassay
WW - wastewater
DW - Drinking Water
OT - Other
Relineen7h7rM tsv—tc—t,.—i
by : (Signature;
by : (5ignature)
C
f`Q,j�„LrG l�ii�t]n � < le .� �-
Y` c
pH
Temp
am 1 A . e Check is
COC Seal Present/intact; P fY1_N
COC Signed/Accurate: / N
Flow
Other
Bottles arrive intact: N
Samples_I�teclExurned via
Correct bottles used:N
Sufficient volume N
UPS _FedEx _Courier
Tracking# ��/� �Q' ���/
((at //
sent:
If Annlirable
Date,
'Time: �Jt
Received by: (Signature)
Trip Blank Received: Yes N
VOA Zero Neadspace: _Y __N
Preservation Correct/Checked: _Y _N
PAD Screen <0.5 mR/hr:
f
HCL/MeoH
�Y _N
Date:
Time:
Received by: (Signature)
Temp: PC
TBR
Battles Received:
If preservation required by Login: Date/Time
Date:
Time:
Received for lab by: (Signature)
Date:
Time:
Id: Conditi
/O�zi
09�
NCF / OK