Loading...
HomeMy WebLinkAbout20050-16-060 Brownfields Vapor Assessment Report_Building 2 - South_031921 Brownfields Vapor Assessment Report Building 2 - South Rite Aid Brownfields Site Charlotte, North Carolina Brownfields Project ID #20050-16-060 March 19, 2021 H&H Job No. ATL-001 i \\hhfs01\MasterFiles\AAA-Master Projects\ATCO LLC - ATC\ATL-Vapor Building 2\Vapor Assessment Report\20050-16-060 Brownfields Vapor Assessment Report_031921.docx Brownfields Vapor Assessment Report Building 2 – South Rite Aid Brownfields Site Charlotte, North Carolina H&H Job ATL-001 Table of Contents 1.0 Introduction ..................................................................................................................................... 1 2.0 Previous Assessment Activities ....................................................................................................... 3 3.0 Vapor Assessment Activities ........................................................................................................... 4 3.1 Sub-slab Vapor Point Installation Activities ......................................................................... 4 3.2 Sub-Slab Vapor and Soil Gas Sampling Activities ............................................................... 5 3.3 Quality Assurance/Quality Control ........................................................................................ 6 4.0 Vapor Assessment Results ............................................................................................................. 8 5.0 Summary and Recommendations ............................................................................................... 10 List of Tables Table 1 Summary of Sub-Slab and Soil Gas Vapor Samples List of Figures Figure 1 Site Location Map Figure 2 Sub-Slab and Soil Gas Sample Location Map List of Appendices Appendix A Field QA/QC Sampling Data and Soil Gas Point Boring Log Appendix B Laboratory Analytical Reports Appendix C Risk Calculator Summary Pages 1 \\hhfs01\MasterFiles\AAA-Master Projects\ATCO LLC - ATC\ATL-Vapor Building 2\Vapor Assessment Report\20050-16-060 Brownfields Vapor Assessment Report_031921.docx Brownfields Vapor Assessment Report Building 2 – South Rite Aid Brownfields Site Charlotte, North Carolina H&H Job ATL-001 1.0 Introduction On behalf of Camp Landowner, LP c/o Camp North End (CNE), Hart & Hickman, PC (H&H) has prepared this Brownfields Vapor Assessment Report for the southern portion of Building 2 located on the Rite Aid Brownfields property located at 1730 Statesville Avenue (also listed at 201 Camp Road and 701 Keswick Avenue) in Charlotte, Mecklenburg County. The Brownfields vapor assessment consisted of conducting sub-slab and soil gas sampling activities in the southern portion of Building 2 (including an area proposed for residential development located south of Building 2), in accordance with the Work Plan – Additional Vapor Assessment – Revision 2 (Work Plan), dated November 17, 2020 approved by the NC Department of Environmental Quality (DEQ) Brownfields Program. A summary of background information, recent sub-slab and soil gas sampling activities, and the results of the Brownfields vapor assessment are summarized in the sections below. The Rite Aid Brownfields Site is approximately 47.87 acres and is comprised of three contiguous parcels of land (Mecklenburg PIN #s 07903102, 07903105, and 07903103). The Site entered into a Brownfields Agreement with the DEQ Brownfields Program (Brownfields Project #20050-16-060) in October 2017. Soil and groundwater contamination consisting primarily of volatile organic compounds (VOCs including chlorinated solvents) and metals due to historical operations and activities. The US Army Corps of Engineers (Corps), on behalf of the US Department of Defense (DOD) is working with DEQ to address impacts release to historical operations conducted at the Site including manufacturing of Model T Ford automobiles, a storage depot for the US Government, and for production of Hercules missiles for the military. The Prospective Developer (PD) is Camp Landowner, LP, and the current mixed-use development is known as Camp North End. Building 2 (previously referred to as Building 1 during initial Brownfields assessment activities, and Corps Building 5) is located in the eastern-central portion of 2 \\hhfs01\MasterFiles\AAA-Master Projects\ATCO LLC - ATC\ATL-Vapor Building 2\Vapor Assessment Report\20050-16-060 Brownfields Vapor Assessment Report_031921.docx the Rite Aid Brownfields Site as depicted on Figure 1. The current Building 2 designation for this building is used throughout this report. Building 2 is currently a vacant warehouse constructed with brick and concrete block walls on a raised concrete foundation. During Site redevelopment activities, Keswick Avenue was recently extended across N. Graham Street in a westerly direction and passes through the central portion of the Building 2 creating two separate structures connected by a roof. The two Building 2 structures are referred to as Building 2-North and Building 2-South. Both Building 2–North and South are proposed to be retrofitted for future commercial use. Building 2-South is proposed to contain commercial retail spaces in the northern portion of the structure. The central portion of the Building 2-South structure will be demolished and re-built with an open-air parking deck. The southern portion of Building 2- South (including areas south of the existing building) will be redeveloped with a five-floor multi- family residential apartment building with amenity spaces. In addition, a small commercial space is proposed to be constructed on the ground floor in the north central portion of the parking deck and is proposed to contain a slab-on-grade. Also, please note that although it appears the parking deck will be physically connected to the residential apartment building and retail spaces, we do not anticipate that there will be a connected HVAC system between these structures. 3 \\hhfs01\MasterFiles\AAA-Master Projects\ATCO LLC - ATC\ATL-Vapor Building 2\Vapor Assessment Report\20050-16-060 Brownfields Vapor Assessment Report_031921.docx 2.0 Previous Assessment Activities Background Information Soil gas and indoor air samples were previously conducted in the northern and southern portions of Building 2 during initial Brownfield vapor assessment activities conducted in 2016. Analytical results from 2016 sampling activities indicated that trichloroethylene (TCE) and other VOCs were detected above the NC DEQ non-residential Sub-Slab Soil Gas Screening Levels (SGSLs) in sub-slab samples collected in the northern portion of Building 2 with TCE concentrations reported as high as 3,000,000 micrograms per cubic meter (µg/m3). TCE and other VOCs was also detected in the southern portion of Building 2; however, at concentrations below the residential SGSL. Prior to and after construction of after a temporary vapor wall barrier (comprised of plastic sheeting and drywall) installed between the northern side and southern side of Building 2, indoor air sampling activities detected TCE in indoor air within the northern portion of Building 2 at concentrations above DEQ residential and non- residential Indoor Air Screening Levels (IASLs). TCE was not detected above the residential IASL in samples collected from the southern portion of Building 2 – South after installation of the temporary vapor wall barrier. H&H recently prepared a Vapor Intrusion Mitigation Plan (VIMP) for a proposed Cupolex® VMS to be installed above the existing concrete floor in Building 2 – North. During recent review of the VIMP prepared for the VMS proposed in the northern portion of Building 2, DEQ requested conducting additional vapor assessment activities in Building 2 – South. A summary of the recent vapor assessment activities conducted to address the additional sub-slab and soil gas sampling activities within Building 2–South and on a proposed residential development south of Building 2– South are summarized below. 4 \\hhfs01\MasterFiles\AAA-Master Projects\ATCO LLC - ATC\ATL-Vapor Building 2\Vapor Assessment Report\20050-16-060 Brownfields Vapor Assessment Report_031921.docx 3.0 Vapor Assessment Activities 3.1 Sub-slab Vapor Point Installation Activities To further evaluate the potential for vapor intrusion associated with the proposed uses for Building 2- South, H&H installed and sampled seven (7) permanent sub-slab vapor sampling points (B2-SSVP- 1 through B2-SSVP-7) in December 2020 and January 2021 at the following locations: • B2-SSVP-1, B2-SSVP-2, and B-2-SSVP-6 were installed in the northern section of Building 2–South where the proposed commercial use spaces are located; • B2-SSVP-3 was installed in the north-central section of Building 2-South where the new commercial space within the parking garage structure is proposed to be located; • B2-SSVP-4 and B2-SSVP-5 were installed in the southern section of Building 2–South within the footprint of the proposed residential building, and • B2-SSVP-7 was installed in the east-central section of Building 2-South within the footprint of the proposed parking deck stairwell. In addition to the sub-slab vapor points, one (1) permanent soil gas vapor point (B2-SGP-1) was installed and sampled in a location south of Building 2-South and within the southwestern footprint of the proposed residential building. Note, H&H also collected indoor air samples within Building 2-South during the recent assessment per the DEQ-approved Work Plan and the indoor samples were placed on hold pending the sub-slab samples results, but which were not analyzed. The sub-slab vapor and the soil gas sample locations are depicted on Figure 2. The sub-slab vapor sample locations (B2-SSVP-1 through B2-SSVP-7) were installed as permanent vapor points and were sampled in general accordance with the DEQ Division of Waste Management (DWM) Vapor Intrusion Guidance. The sub-slab vapor points were installed by utilizing a hammer drill and 1½-inch diameter drill bit to advance a pilot hole into the concrete slab to a depth of approximately 1¾ inches below the surface. A drill guide was then placed in the pilot hole, and a 5/8-inch diameter drill bit was utilized to advance the boring through the concrete slab. Following concrete borehole advancement, loose concrete cuttings were removed from the boring using a bottlebrush and high efficiency particulate air (HEPA) vacuum. A Cox- Colvin Vapor Pin™ (vapor pin) assembly (brass sampling point and silicone sleeve) was seated in 5 \\hhfs01\MasterFiles\AAA-Master Projects\ATCO LLC - ATC\ATL-Vapor Building 2\Vapor Assessment Report\20050-16-060 Brownfields Vapor Assessment Report_031921.docx the borehole using an installation/extraction tool and hammer. The vapor pins were installed as flush-mount sample points and secured with a stainless-steel cover that screws onto the sampling point and is seated within the pilot hole annulus. The soil gas monitoring point (SGP-1) was installed using hand auger methods to advance the boring into the vadose zone to a depth of 5 ft below ground surface. The soil was logged for lithological description and field screened for indication of potential impacts by observation for staining, and the presence of organic vapors using a calibrated photoionization detector (PID). No notable staining or odors were observed in the soil cuttings. A 6-inch stainless-steel screen point fitted with ¼-inch diameter Teflon® tubing was then installed in the borehole to the maximum depth of the boring. Filter sand was placed in the annulus space between the screen point and the borehole and the sand was extended to approximately one ft above the bottom of the borehole. The sampling point was completed by placing hydrated bentonite from the top of the filter sand to the ground surface and installation of a lockable vapor point cap, protective steel cover, and a concrete pad set flush with surrounding ground surface. A boring log for the soil gas point (B2-SGP-1) is located in Appendix A. Upon installation, the sample point was purged of a minimum of three times the volume of the annular space plus the tubing volume using a syringe or air pump. In addition, the soil gas point was sampled approximately one week after installation which allowed the sub-slab vapors to stabilize prior to sampling. 3.2 Sub-Slab Vapor and Soil Gas Sampling Activities Prior to sampling the sub-slab and soil-gas vapor monitoring points, a leak check was conducted at each location by constructing a shroud over the entire sampling train and flooding the air within the shroud with helium gas. Using an air pump, a sample was collected from the gas in the shroud into a Tedlar® bag and analyzed for helium concentrations using a helium gas detector. Vapor from the monitoring points was purged and sampled outside of the shroud into a separate Tedlar® bag and analyzed using the helium gas detector. The leak checks indicated that the helium concentrations through the sample train were less than 10% of the concentration measured within the shroud indicating a successful leak check for each sample. 6 \\hhfs01\MasterFiles\AAA-Master Projects\ATCO LLC - ATC\ATL-Vapor Building 2\Vapor Assessment Report\20050-16-060 Brownfields Vapor Assessment Report_031921.docx Following the successful field leak check, the sub-slab and soil-gas samples were collected into approximate one-liter Summa canisters for laboratory analysis by connecting the Teflon® sample tubing to an airflow regulator using a brass nut and ferrule assembly to create an airtight seal. The airflow regulator was calibrated by the laboratory to allow the Summa canisters to fill slowly at a rate not greater than 200 milliliters per minute. The vacuum pressure in each Summa canister upon completion of the sampling event was between three and six inches of mercury (inHg). In addition to the helium leak tests, shut-in leak tests were performed on each Summa canister and sampling train prior to sampling to ensure no leaks were present through the regulator or canister connections. Upon completion of sample collection, the air flow regulator was removed from the Summa canister and the samples were submitted to Waypoint Analytical, LLC (Waypoint) under standard chain of custody protocols for analysis of full-list VOCs by EPA Method TO-15. Upon receipt of the samples, the laboratory recorded the final received vacuum pressure for each Summa canister. The laboratory and field starting and ending vacuum concentrations are listed on the chain- of-custody and in Table 1. Indoor Air Samples In accordance with the Work Plan, H&H collected two indoor air samples from the northern portion of Building 2 – South that are proposed to contain enclosed retrofitted tenant spaces. The indoor air samples were collected in these locations because the existing building concrete slab and exterior walls are proposed to remain in-place. Additionally, an exterior background sample (BAS-1) was collected. The indoor air and background samples were placed on-hold pending the results of the sub-slab vapor samples. These samples were to be released for analysis of risk calculations indicated that unacceptable carcinogenic or non-carcinogenic risk were present in the soil-gas and/or sub-slab samples. As summarized in Section 4, unacceptable risks were not present in the sub-slab vapor and soil-gas samples and thus the indoor air and background air samples were not released for analysis. 3.3 Quality Assurance/Quality Control For field and laboratory quality assurance/quality control (QA/QC) purposes, H&H collected one duplicate sub-slab sample and one duplicate indoor air sample to satisfy DEQ Brownfields minimum 7 \\hhfs01\MasterFiles\AAA-Master Projects\ATCO LLC - ATC\ATL-Vapor Building 2\Vapor Assessment Report\20050-16-060 Brownfields Vapor Assessment Report_031921.docx sample frequency of 1 duplicate per 20 samples per media and method. As noted above, the indoor air samples were placed on hold pending results of the sub-slab vapor and soil gas samples and the indoor air samples were not released for analysis. The duplicate sub-slab sample was analyzed for the same compounds as the parent sample. In addition, H&H requested a Level II QA/QC data package from the laboratory and the laboratory reported values to the laboratory-specified method detection limits using J-flags. 8 \\hhfs01\MasterFiles\AAA-Master Projects\ATCO LLC - ATC\ATL-Vapor Building 2\Vapor Assessment Report\20050-16-060 Brownfields Vapor Assessment Report_031921.docx 4.0 Vapor Assessment Results The vapor assessment results are summarized on Table 1. As anticipated, multiple low-level VOCs were detected in the sub-slab and soil gas samples. Of the VOCs detected, only chloroform was detected in the B2-SGP-1 soil gas sample at a concentration (70 µg/m³) above the DWM residential and non-residential SGSL of 4.1 and 53 µg/m³. Benzyl chloride (5.1 µg/m³) and bromodichloromethane (12 µg/m³) were also detected in the B2-SGP-1 soil gas sample at concentrations above their respective DWM residential SGSLs of 1.9 and 2.5 µg/m³, but below their respective DWM non-residential SGSLs of 25 and 33 µg/m³. Please note that B2-SGP-1 is located south of Building 2-South in the footprint of the proposed residential building. Naphthalene (6.4 µg/m³) was also detected at a concentration above the DWM residential SGSL of 2.8 µg/m³, but below the DWM non-residential SGSL of 36 µg/m³ in the B2-SSVP-7 sub-slab sample. Please note that B2-SSVP-7 is located in the northern portion of Building 2-South in an area proposed for commercial use. Additionally, TCE (5.2 µg/m³) was detected in only one sub-slab or soil gas sample (SSVP-1 collected in the northern portion of Building 2-South and closest to the Keswick Cut), but at a concentration below residential and non-residential SGSLs. None of the remaining low- level VOCs detected in the sub-slab or soil gas samples exceeded residential or non-residential DWM SGSLs. To further assesses the sub-slab and soil gas results, H&H calculated risk for the detected VOC concentrations. Specifically, H&H utilized the data collected from the B2-SSVP-1, B2-SSVP-2, B2- SSVP-3, B2-SSVP-6, and B2-SSVP-7 to assess commercial risk due to their locations within Building 2-South and the proposed garage structure. In addition, H&H utilized the data collected from B2-SSVP-4, B2-SSVP-5, and B2-SGP-1 to assess residential risk due to their locations within or near the footprint of the proposed residential structure. Please note, both commercial risk and residential risk calculations are presented on Table 1 for each sample for comparative purposes, but only the areas around locations B2-SSVP-4, B2-SSVP-5, and B2-SGP-1 are proposed to contain future residential use buildings. In addition, for comparative purposes, a combined “worse-case” commercial risk calculation was performed by using the highest detected concentration of each constituent from all of the samples within the proposed commercial use areas, and a combined “worse-case” residential risk calculation was performed using the constituent concentrations from all 9 \\hhfs01\MasterFiles\AAA-Master Projects\ATCO LLC - ATC\ATL-Vapor Building 2\Vapor Assessment Report\20050-16-060 Brownfields Vapor Assessment Report_031921.docx the samples within the proposed residential use areas. Risk calculator summary pages are included as Appendix C. The results of the cumulative risk calculations for the recent vapor assessment event indicate that all of the calculated cumulative potential carcinogenic and non-carcinogenic risks for the soil gas samples are within the acceptable risk range of 1 x10-4 to 1 x 10-6 and the calculated hazardous index (HI) are less than 1 for both residential and non-residential use, including the combined worse-case calculations. Therefore, it does not appear that the results of the vapor assessment activities identified a significant risk exposure to future workers within Building 2-South or the parking garage, or to future occupants within the proposed residential building. 10 \\hhfs01\MasterFiles\AAA-Master Projects\ATCO LLC - ATC\ATL-Vapor Building 2\Vapor Assessment Report\20050-16-060 Brownfields Vapor Assessment Report_031921.docx 5.0 Summary and Recommendations H&H has completed sub-slab vapor and soil gas point installation and sampling in Building 2 – South at the Rite Aid Brownfields Property. A brief summary of the sampling results is provided below. • H&H installed and sampled seven (7) permanent sub-slab vapor sampling points (B2-SSVP- 1 through B2-SSVP-7) and one permanent soil-gas point (B2-SGP-1) in December 2020 and January 2021. • Chloroform was detected in the B2-SGP-1 soil gas sample at a concentration (70 µg/m³) above the DWM residential and non-residential SGSL of 4.1 and 53 µg/m³. Benzyl chloride (5.1 µg/m³) and bromodichloromethane (12 µg/m³) were also detected in the B2-SGP-1 soil gas sample at concentrations above their respective DWM residential SGSLs of 1.9 and 2.5 µg/m³, but below their respective DWM non-residential SGSLs of 25 and 33 µg/m³. • Naphthalene (6.4 µg/m³) was also detected at a concentration above the DWM residential SGSL of 2.8 µg/m³, but below the DWM non-residential SGSL of 36 µg/m³ in the B2-SSVP- 7 sub-slab sample. • TCE (5.2 µg/m³) was detected in only one sub-slab or soil gas sample (SSVP-1 collected in the northern portion of Building 2-South and closest to the Keswick Cut), but at a concentration below residential and non-residential SGSLs. • The results of the cumulative risk calculations for the recent vapor assessment event indicate that all of the calculated cumulative potential carcinogenic and non-carcinogenic risks for the soil gas samples are within the acceptable risk range of 1 x10-4 to 1 x 10-6 and the calculated hazardous index (HI) are less than 1 for both residential and non-residential use, including the combined worse-case calculations. Based on the vapor assessment results of Building 2 – South and the proposed residential area to the south of Building 2 – South, there does not appear to be a significant risk exposure to future workers within Building 2-South or the parking garage, or to future occupants within the proposed residential building. Table 1Summary of Soil Gas and Sub-Slab Vapor SamplesBuilding 2 - SouthRite Aid Brownfields Site1730 Statesville AvenueCharlotte, North CarolinaH&H Job No. ATL-001Sampling MediaSoil GasSample LocationSouth of B2 WarehouseSample ObjectiveFuture Residential UseSample ID B2-SSVP-1 B2-SSVP-2 B2-SSVP-DUP B2-SSVP-3 B2-SSVP-4 B2-SSVP-5 B2-SSVP-6 B2-SSVP-7 B2-SGP-1Sample Date 12/22/20 12/20/20 12/20/20 12/18/20 12/18/20 12/18/20 1/14/21 1/14/21 12/18/20Units µg/m³ µg/m³ µg/m³ µg/m³ µg/m³ µg/m³ µg/m³ µg/m³ µg/m³ µg/m³ µg/m³ µg/m³ µg/m³ Acetone 16 13 6.8 18 44 49 45 68 7.4 49 68 220,000 2,700,000Benzene<0.16 <0.16 <0.16 <0.16 <0.16 <0.16 <0.160.64 J<0.16 ND0.64 12 160Benzyl chloride<0.20 <0.20 <0.20 <0.20 <0.20 <0.20 <0.20 <0.205.1 5.1ND1.9 25Bromodichloromethane<0.26 <0.26 <0.26 <0.26 <0.26 <0.26 <0.26 <0.2612 12ND2.5 33Carbon disulfide 2.9 J<1.62.3 J<1.6 <1.6 <1.65.8 J<1.610 10 5.8 4,900 61,000Chloroform<0.26 <0.26 <0.26 <0.26 <0.26 <0.26 <0.26 <0.267070ND4.1 53Cyclohexane 1.9 J 2.2 J 2.2 J 3.0 J 4.0 3.2 J<0.87 <0.874.0 4.0 3.0 42,000 530,000Dibromochloromethane<0.48 <0.48 <0.48 <0.48 <0.48 <0.48 <0.48 <0.482.1 J 2.1NDNS NS1,4-Dichlorobenzene<0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.251.3 J 1.3ND8.5 110Dichlorodifluoromethane 3.2 3.5 3.6 3.3 3.6 3.6 3.5 3.2 4.1 4.1 3.6 700 8,8001,1-Dichloroethylene<0.41 <0.41 <0.41 <0.413.6<0.41 <0.41 <0.41 <0.413.6ND1,400 18,000trans-1,2-Dichloroethylene<0.48 <0.48 <0.48 <0.483.7<0.48 <0.48 <0.48 <0.483.7NDNE NE1,4-Dioxane 1.0 J<0.10 <0.100.86 J<0.10 <0.10 <0.10 <0.10 <0.10 ND1.0 19 250Hexane<0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.252.5<0.25 ND2.5 4,900 61,000Isopropyl alcohol 3.2 J 2.0 J 2.0 J 3.2 J 3.0 J 2.7 J 6.9 11 4.2 J 4.2 11 1,400 18,000Methyl Butyl Ketone (2-Hexanone)<0.26 <0.26 <0.26 <0.26 <0.26 <0.264.6 4.5<0.26 ND4.6 210 2,600Methyl Ethyl Ketone (2-Butanone) 1.2 J 0.97 J 0.91 J 1.5 1.3 J 1.3 J 3.2 2.5 0.97 J 1.3 3.2 35,000 440,000Methyl Isobutyl Ketone<0.26 <0.26 <0.26 <0.26 <0.26 <0.264.8 4.7<0.26 ND4.8 21,000 260,000Methylene Chloride 1.2 J 5.3 10 9.7 11 12 3.9 8.7 10 12 10 3,400 53,000Naphthalene<1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.06.4<1.0 ND6.42.8 36Styrene<0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.154.3 4.3ND7,000 88,000Tetrachloroethylene 2.3 J 3.7 3.7<0.443.1 J 3.1 J<0.44 <0.4428 28 3.7 280 3,500Tetrahydrofuran<0.21 <0.21 <0.21 <0.21 <0.21 <0.210.91 J 0.94 J 1.0 J 1.0 0.94 14,000 180,000Toluene<0.75 <0.75 <0.75 <0.750.83 J<0.751.0 J 2.1 1.8 J 1.8 2.1 35,000 440,0001,1,2-Trichloro-1,2,2-trifluoroethane<0.532.5 J 2.4 J<0.53 <0.53 <0.53 <0.53 <0.53 <0.53 ND2.5 35,000 440,000Trichloroethylene 5.2<0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 <0.27 ND5.2 14 180Trichlorofluoromethane<0.432.6 J 2.9<0.431.9 J 2.0 J 2.0 J<0.436.3 6.3 2.9 NE NE1,2,4-Trimethylbenzene 4.3 4.4 4.4 4.4 4.3 4.3<0.29 <0.295.1 5.1 4.4 420 5,300m,p-Xylenes<0.38 <0.38 <0.381.1 J<0.38 <0.382.0 J 2.4 J 1.8 J 1.8 2.4 700 8,800Cumulative Risks - ResidentCarcinogenic Risk 3.9E-07 4.9E-08 1.2E-08 1.2E-08 1.2E-09 2.4E-06 2.5E-05 2.5E-05 2.8E-06 -- --Non-Carcinogenic Hazard Index8.1E-02 5.2E-03 6.9E-03 6.4E-03 7.5E-03 7.0E-02 1.9E-01 1.9E-01 1.5E-01 -- --Cumulative Risks - Non-Resident WorkerCarcinogenic Risk 2.2E-08 3.6E-09 7.5E-10 7.6E-10 3.2E-11 1.8E-07 1.9E-06 1.9E-06 2.0E-07 -- --Non-Carcinogenic Hazard Index6.4E-03 4.1E-04 5.5E-04 5.0E-04 6.0E-04 5.6E-03 1.5E-02 1.5E-02 1.2E-02 -- --Canister Identification Number5918 5995 5896 5858 5896 5522Starting Vacuum, inHG (Lab / Field) NA / 27 30 / 28 28.5 / 26.5 30 / 28 29 /27 30 / 26.5Ending Vacuum, inHG (Lab / Field)4 / 5 4 / 5 4.5 / 5 5 / 5 5 / 5 4.5 / 5Notes:1) North Carolina Department of Environmental Quality (DEQ) Division of Waste Management (DWM) Residential Sub-slab and Exterior Soil Gas Screening Levels (SGSLs) dated July 2020.2) DEQ DWM Non-Residential Sub-slab and Exterior SGSLs dated July 2020.Areas of future residential use are represented by samples (B2-)SSVP-4, SSVP-5, and SGP-1. For purposes of risk calculation, the highest concentration for each constituent detected was used.Areas of future commercial use are represented by samples (B2-)SSVP-1, SSVP-2, SSVP-3, SSVP-6, and SSVP-7. For purposes of risk calculation, the highest concentration from each constituent detected was used.Duplicate sample (B2-SSVP-DUP) collected with parent sample B2-SSVP-2. For purposes of risk calculation, the highest concentration is used.Concentrations are reported in micrograms per cubic meter (µg/m3). Only constituents detected in at least one sample are shown above; refer to the laboratory reportNote, canister vacuums may be measured with different gauges in the laboratory as compared to the field gauge.Bold indicates concentration exceeds Residential Sub-slab and Exterior SGSL.Bold and Underlined indicates concentration exceeds Non-Residential Sub-slab and Exterior SGSL.J = Compound detected above laboratory method detection limit, but below laboratory reporting limit; and therefore reported value is an estimated value.NE = Not Established; < = Compound detected below the laboratory method detection limit; NA = not available, inHG = inches of mercuryB2-SSVP-4 & 5, B2-SGP-1B2-SSVP-1, 2, 3, 6, & 78.7E-105.3E-04594130 / 27.5 4 / 5DWM Non-Residential Sub-Slab and Exterior Soil Gas Screening Level(2)Building 2-South WarehouseSub-Slab VaporFuture Commercial Use6.7E-031.3E-08DWM Residential Sub-Slab and Exterior Soil Gas Screening Level(1)Future Residential Use Future Commercial UseCombined Worse-CaseFuture Residential UseFuture Commercial UseS:\AAA-Master Projects\ATCO LLC - ATC\ATL-Vapor Building 2\Vapor Assessment Report\Table 2 - SubSlab and Soil GasTable 1Hart & Hickman TITLE PROJECT SITE LOCATION MAP BUILDING 2 - SOUTH 1730 STATESVILLE AVENUE CHARLOTTE, NORTH CAROLINA DATE: JOB NO: REVISION NO: FIGURE NO: 11-13-20 0 1ATL-001 0 2000 4000 APPROXIMATE SCALE IN FEET N U.S.G.S. QUADRANGLE MAP QUADRANGLE 7.5 MINUTE SERIES (TOPOGRAPHIC) CHARLOTTE EAST, NC 1967 REVISED/INSPECTED 1988 AND DERITA, NC 1993 SITE FORMER OFFICES STATESVILLE AVENUECAMP ROADKE S W I C K A V E N U E PROPOSED OPEN-AIR COVERED PORCH MV GRAHAM PROPERTY FORMERLY KNOWN AS BUILDING #3 BUILDING 2 - SOUTH (FORMER BUILDING 1) PROPOSED RETROFITTED COMMERCIAL / RETAIL SPACEPROPOSED NEW PARKING DECK PROPOSED NEW COMMERCIAL SPACE PROPOSED NEW RESIDENTIAL AND AMENITY SPACE KESWICK AVENUE EXTENSION (KESWICK CUT) BUILDING 2 - NORTH (FORMER BUILDING 1) B2-SSVP-1 B2-SSVP-6 B2-SSVP-3 B2-SSVP-4B2-SSVP-5 B2-SGP-1 B2-SSVP-2 B2-SSVP-7 JOB NO. ATL-001 REVISION NO. 2DATE: 3-1-21 FIGURE NO. 2 CAMP NORTH END / RITE AID FACILITYBROWNFIELDS PROJECT NO. 20050-16-0601776 STATESVILLE AVENUECHARLOTTE, NORTH CAROLINA SUB-SLAB & SOIL GAS SAMPLE LOCATION MAPLEGEND SITE PROPERTY BOUNDARY TEMPORARY WALL SEAL LOCATION(INSTALLED FOR THE SEPTEMBER 2016INDOOR AIR SAMPLING EVENT) PROPOSED AREA FOR VAPOR INTUSION MITIGATION SYSTEM(APPROXIMATELY 101,000 SQ FT) PROPOSED KESWICK EXTENSION (KESWICKCUT) OPEN-AIR STREET NOTES: 1. VAPOR INTRUSION MITIGATION SYSTEM (VIMS) IS PROPOSED FORBUILDING 2 - NORTH. 2. REFER TO BUILDING PLANS - A0.11 - LEASING PLAN B - PROPOSEDFOR DETAILS REGARDING THE PROPOSED RESIDENTIAL ANDCOMMERCIAL SPACE LAYOUT AND FOR THE SAMPLE LOCATIONS INRELATION TO THE PROPOSED BUILDING. SUB-SLAB VAPOR SAMPLE SOIL-GAS POINT AND SAMPLE B2-SSVP-4 B2-SGP-1 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 GeologyNORTH GRAHAM STREETS:\AAA-Master Projects\ATCO LLC - ATC\ATL-Vapor Building 2\Revision 2\Figures\Sample Location Map_R1.dwg, FIG 3, 3/1/2021 1:03:40 PM, SVincent Appendix A Field QA/QC Sampling Data and Soil Gas Point Boring Log Sub-Slab / Soil Gas Vapor QA/QC Field FormProject No.: ATL-001 Depth of ScreenDate & TimeAmbient Temp.Purge Method Purge VolHelium Conc.ShroudHelium Conc.PurgeLeak Test PassedYes / No SS, SGperm., temp.concrete, wood, asphalt, grass, soil, gravel etc.thicknessinches(if appl.)ft bgsmm/dd/yy 24-hour clockoFsyringe, peristaltic, etc.Liters %% or ppm(indicate units below)Yes / No(see note)S:B2‐SGP‐1C:5769R:6555YesSG perm asphalt -- 4.5 - 512/18/2014:0045 air pump 2 26.9 0 YesS: B2‐SSVP‐2C:5941R:13115Yes SS perm concrete 6 in --12/18/209:4542 air pump 2 21.7 0 YesS: B2‐SSVP‐3C: 5995R: 13125Yes SS perm concrete 6 in --12/18/2015:5550 air pump 2 31.8 0 YesS: B2‐SSVP‐4C: 5896R: 6559Yes SS perm concrete 6 in --12/18/2015:0850 air pump 2 30.1 25 ppm YesS: B2‐SSVP‐5C: 5858R: 6565Yes SS perm concrete 6 in --12/18/2014:4250 air pump 2 42.1 0 YesS: B2‐SSVP‐1C: 5918R: 13125Yes SS perm concrete 6 in --12/22/207:5047 air pump 2 25.1 0 YesS: B2‐SSVP‐6C: 5896R: 6558Yes SS perm concrete 6 in --01/14/2115:1652 air pump 2 28.2 0 YesS: B2‐SSVP‐7C: 5522R: 6552Yes SS perm concrete 6 in --01/14/2115:4452 air pump 2 30.6 0 YesS= sample; C/R = canister/regulator; SS = sub-slab; SG = soil gas; perm = permanent; temp = temporarySampler(s): Sean HorganWeather: All sampling events - no preciptation,, 40s to 50s F, sunny/partly cloudyNotes: See Figure 2 for sample locations. Leak test conducted on entire sampling train.B2-SSVP-1 through B2-SSVP-7 were installed with vapor pinsHelium Leak TestCanister / RegulatorShut-in Test PassedGround SurfaceID NumbersSample / Canister / RegulatorTypeVapor Monitoring Point ConstructionNote: Leak Test RequirementsPer NC DEQ DWM Vapor Intrusion Guidance, leak test passes if helium concentration in purge air is less than 10% of helium concentration in shroud. S:\AAA‐Master Projects\ATCO LLC ‐ ATC\ATL‐Vapor Building 2\Vapor Assessment Report\Sub‐slab & Soil Gas QA_QC Field FormSub‐Slab / Soil Gas Sampling Vapor QA/QC Field FormHart & Hickman, PC NOTES: Hole precleared using hand auger. generated using GroundLogs.online Client: Project: Address: ATCO, LLC ATL-001 1776 Statesville Avenue, Charlotte,NC WELL LOG Well No. Page: B2-SGP-1 1 of 1 Drilling Start Date: Drilling End Date: Drilling Company: Drilling Method: Drilling Equipment: Driller: Logged By: 12/10/2021 10:30 12/10/2021 11:50 Hart & Hickman Other Hand Auger Sean Horgan Sean Horgan Boring Depth (ft): Boring Diameter (in): Sampling Method(s): DTW During Drilling (ft): DTW After Drilling (ft): Top of Casing Elev. (ft): Location (X,Y): 5.0 2.5 Grab Well Depth (ft): Well Diameter (in): Screen Slot (in): Riser Material: Screen Material: Seal Material(s): Filter Type: 5.0 0.1 Teflon tubing 6" Vapor Screen Bent. Powder Sand Pack DEPTH (ft)LITHOLOGYWATER LEVELWELLCOMPLETIONCOLLECT Sample TypeTimeBlow CountsRecovery (ft)SOIL/ROCK VISUAL DESCRIPTION MEASURE PID (ppm)Lab SampleDEPTH (ft)0 5 10 GR GR GR GR GR 1.00 1.00 1.00 1.00 1.00 (0') Asphalt (0.5') Poorly graded GRAVEL with sand (GP); some coarse sand, dense, dry, dark yellowish-brown (1') Lean CLAY (CL); some silt, medium plasticity, very stiff, moist, reddish (3.5') SILT (ML); some clay, stiff, moist, reddish (4') SILT (ML); few clay, stiff, moist, yellowish-red (5') Boring terminated 3.8 7.7 13.0 14.7 12.7 0 5 10 -- -- -- -- -- NOTES: BORING AND WELL LOG LEGEND LITHOLOGYWATER LEVELWELL/BORINGCOMPLETIONSample TypeDESCRIPTION GR EN SS SH CO DP ID ASPHALT CONCRETE BEDROCK IGNEOUS Rock METAMORPHIC Rock SEDIMENTARY Rock Well-graded GRAVEL (GW) Poorly graded GRAVEL (GP) Silty GRAVEL (GM) Clayey GRAVEL (GC) Well-graded GRAVEL with silt (GW-GM) Poorly graded GRAVEL with silt (GP-GM) Well-graded GRAVEL with clay (GW-GC) Poorly graded GRAVEL with clay (GP-GC) Well-graded SAND (SW) Poorly graded SAND (SP) Silty SAND (SM) Clayey SAND (SC) Well-graded SAND with silt (SW-SM) Poorly graded SAND with silt (SP-SM) Well-graded SAND with clay (SW-SC) Poorly graded SAND with clay (SP-SC) SILT (ML) Lean CLAY (CL) Organic SOIL (OL) Elastic SILT (MH) Fat CLAY (CH) Organic SOIL (OH) Organic SOIL (OL/OH) PEAT (PT) Volume Descriptors: Trace = <5% Few = 5-10% Little = 15-25% Some = 30-45% Mostly = >=50% Water Level During Drilling Water Level at End of Drilling/in Completed Well Cap Riser Screen End Plug Annular Seal (Bentonite-Cement Grout, Bentonite Slurry/Chips/Pellets/Powder, Other) Sanitary Seal (Bentonite Slurry/Chips/Pellets/Powder, Other) Filter Pack (Sand, Gravel, Other) Backfill Grab Encore Split Spoon Shelby Tube Core Barrel Direct Push Lab Sample and ID Appendix B Laboratory Analytical Reports This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. NC Certification No. 402 NC Drinking Water Cert No. 37735 SC Certification No. 99012 Case Narrative 12/31/20 11:14 Hart & Hickman (Charlotte) Matt Ingalls 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: ATL-001 Former Rite Aid Lab Submittal Date: 12/22/2020 Work Order: 0120370 Please call if you have any questions relating to this analytical report. Respectfully, WAYPOINT ANALYTICAL Senior Project Manager Angela D. Overcash Data Qualifiers Key Reference: J Detected but below the Reporting Limit; therefore, result is an estimated concentration (CLP J-Flag). Method Detection LimitMDL Below Reporting LimitBRL Relative Percent DifferenceRPD *Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 1 of 24 Sample Receipt Summary 12/31/2020 Work Order: 0120370 Client Sample ID MatrixLab Sample ID Date/Time Sampled Date/Time Received 0120370-01 12/18/20 15:57B2-SSVP-3 12/22/20 14:20Air 0120370-02 12/20/20 9:45B2-SSVP-2 12/22/20 14:20Air 0120370-03 12/18/20 14:01B2-SGP-1 12/22/20 14:20Air 0120370-04 12/18/20 14:44B2-SSVP-5 12/22/20 14:20Air 0120370-05 12/18/20 15:09B2-SSVP-4 12/22/20 14:20Air 0120370-06 12/20/20 0:00B2-SSVP-DUP 12/22/20 14:20Air 0120370-07 12/22/20 7:54B2-SSVP-1 12/22/20 14:20Air Samples were received in good condition at 6.0 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 2 of 24 Client ID ResultParameterMethod UnitsWaypoint ID Work Order: 0120370 12/31/2020 Summary of Detections 4.4 ug/m‡ Air0120370-01 B2-SSVP-3 1,2,4-Trimethylbenzene TO-15 0.86 J ug/m‡ Air0120370-01 B2-SSVP-3 1,4-Dioxane TO-15 18 ug/m‡ Air0120370-01 B2-SSVP-3 Acetone TO-15 3.0 J ug/m‡ Air0120370-01 B2-SSVP-3 Cyclohexane TO-15 3.3 ug/m‡ Air0120370-01 B2-SSVP-3 Dichlorodifluoromethane TO-15 3.2 J ug/m‡ Air0120370-01 B2-SSVP-3 Isopropyl alcohol TO-15 1.1 J ug/m‡ Air0120370-01 B2-SSVP-3 m,p-Xylenes TO-15 1.5 ug/m‡ Air0120370-01 B2-SSVP-3 Methyl Ethyl Ketone (2-Butanone)TO-15 9.7 ug/m‡ Air0120370-01 B2-SSVP-3 Methylene Chloride TO-15 2.5 J ug/m‡ Air0120370-02 B2-SSVP-2 1,1,2-Trichloro-1,2,2-trifluoroethane TO-15 4.4 ug/m‡ Air0120370-02 B2-SSVP-2 1,2,4-Trimethylbenzene TO-15 13 ug/m‡ Air0120370-02 B2-SSVP-2 Acetone TO-15 2.2 J ug/m‡ Air0120370-02 B2-SSVP-2 Cyclohexane TO-15 3.5 ug/m‡ Air0120370-02 B2-SSVP-2 Dichlorodifluoromethane TO-15 2.0 J ug/m‡ Air0120370-02 B2-SSVP-2 Isopropyl alcohol TO-15 0.97 J ug/m‡ Air0120370-02 B2-SSVP-2 Methyl Ethyl Ketone (2-Butanone)TO-15 5.3 ug/m‡ Air0120370-02 B2-SSVP-2 Methylene Chloride TO-15 3.7 ug/m‡ Air0120370-02 B2-SSVP-2 Tetrachloroethylene TO-15 2.6 J ug/m‡ Air0120370-02 B2-SSVP-2 Trichlorofluoromethane TO-15 5.1 ug/m‡ Air0120370-03 B2-SGP-1 1,2,4-Trimethylbenzene TO-15 1.3 J ug/m‡ Air0120370-03 B2-SGP-1 1,4-Dichlorobenzene TO-15 7.4 ug/m‡ Air0120370-03 B2-SGP-1 Acetone TO-15 5.1 ug/m‡ Air0120370-03 B2-SGP-1 Benzyl chloride TO-15 12 ug/m‡ Air0120370-03 B2-SGP-1 Bromodichloromethane TO-15 10 ug/m‡ Air0120370-03 B2-SGP-1 Carbon disulfide TO-15 70 ug/m‡ Air0120370-03 B2-SGP-1 Chloroform TO-15 4.0 ug/m‡ Air0120370-03 B2-SGP-1 Cyclohexane TO-15 2.1 J ug/m‡ Air0120370-03 B2-SGP-1 Dibromochloromethane TO-15 4.1 ug/m‡ Air0120370-03 B2-SGP-1 Dichlorodifluoromethane TO-15 4.2 J ug/m‡ Air0120370-03 B2-SGP-1 Isopropyl alcohol TO-15 1.8 J ug/m‡ Air0120370-03 B2-SGP-1 m,p-Xylenes TO-15 0.97 J ug/m‡ Air0120370-03 B2-SGP-1 Methyl Ethyl Ketone (2-Butanone)TO-15 10 ug/m‡ Air0120370-03 B2-SGP-1 Methylene Chloride TO-15 4.3 ug/m‡ Air0120370-03 B2-SGP-1 Styrene TO-15 28 ug/m‡ Air0120370-03 B2-SGP-1 Tetrachloroethylene TO-15 1.0 J ug/m‡ Air0120370-03 B2-SGP-1 Tetrahydrofuran TO-15 1.8 J ug/m‡ Air0120370-03 B2-SGP-1 Toluene TO-15 6.3 ug/m‡ Air0120370-03 B2-SGP-1 Trichlorofluoromethane TO-15 4.3 ug/m‡ Air0120370-04 B2-SSVP-5 1,2,4-Trimethylbenzene TO-15 49 ug/m‡ Air0120370-04 B2-SSVP-5 Acetone TO-15 3.2 J ug/m‡ Air0120370-04 B2-SSVP-5 Cyclohexane TO-15 3.6 ug/m‡ Air0120370-04 B2-SSVP-5 Dichlorodifluoromethane TO-15 2.7 J ug/m‡ Air0120370-04 B2-SSVP-5 Isopropyl alcohol TO-15 1.3 J ug/m‡ Air0120370-04 B2-SSVP-5 Methyl Ethyl Ketone (2-Butanone)TO-15 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 3 of 24 Client ID ResultParameterMethod UnitsWaypoint ID Work Order: 0120370 12/31/2020 Summary of Detections 12 ug/m‡ Air0120370-04 B2-SSVP-5 Methylene Chloride TO-15 3.1 J ug/m‡ Air0120370-04 B2-SSVP-5 Tetrachloroethylene TO-15 2.0 J ug/m‡ Air0120370-04 B2-SSVP-5 Trichlorofluoromethane TO-15 3.6 ug/m‡ Air0120370-05 B2-SSVP-4 1,1-Dichloroethylene TO-15 4.3 ug/m‡ Air0120370-05 B2-SSVP-4 1,2,4-Trimethylbenzene TO-15 44 ug/m‡ Air0120370-05 B2-SSVP-4 Acetone TO-15 4.0 ug/m‡ Air0120370-05 B2-SSVP-4 Cyclohexane TO-15 3.6 ug/m‡ Air0120370-05 B2-SSVP-4 Dichlorodifluoromethane TO-15 3.0 J ug/m‡ Air0120370-05 B2-SSVP-4 Isopropyl alcohol TO-15 1.3 J ug/m‡ Air0120370-05 B2-SSVP-4 Methyl Ethyl Ketone (2-Butanone)TO-15 11 ug/m‡ Air0120370-05 B2-SSVP-4 Methylene Chloride TO-15 3.1 J ug/m‡ Air0120370-05 B2-SSVP-4 Tetrachloroethylene TO-15 0.83 J ug/m‡ Air0120370-05 B2-SSVP-4 Toluene TO-15 3.7 ug/m‡ Air0120370-05 B2-SSVP-4 trans-1,2-Dichloroethylene TO-15 1.9 J ug/m‡ Air0120370-05 B2-SSVP-4 Trichlorofluoromethane TO-15 2.4 J ug/m‡ Air0120370-06 B2-SSVP-DUP 1,1,2-Trichloro-1,2,2-trifluoroethane TO-15 4.4 ug/m‡ Air0120370-06 B2-SSVP-DUP 1,2,4-Trimethylbenzene TO-15 6.8 ug/m‡ Air0120370-06 B2-SSVP-DUP Acetone TO-15 2.3 J ug/m‡ Air0120370-06 B2-SSVP-DUP Carbon disulfide TO-15 2.2 J ug/m‡ Air0120370-06 B2-SSVP-DUP Cyclohexane TO-15 3.6 ug/m‡ Air0120370-06 B2-SSVP-DUP Dichlorodifluoromethane TO-15 2.0 J ug/m‡ Air0120370-06 B2-SSVP-DUP Isopropyl alcohol TO-15 0.91 J ug/m‡ Air0120370-06 B2-SSVP-DUP Methyl Ethyl Ketone (2-Butanone)TO-15 10 ug/m‡ Air0120370-06 B2-SSVP-DUP Methylene Chloride TO-15 3.7 ug/m‡ Air0120370-06 B2-SSVP-DUP Tetrachloroethylene TO-15 2.9 ug/m‡ Air0120370-06 B2-SSVP-DUP Trichlorofluoromethane TO-15 4.3 ug/m‡ Air0120370-07 B2-SSVP-1 1,2,4-Trimethylbenzene TO-15 1.0 J ug/m‡ Air0120370-07 B2-SSVP-1 1,4-Dioxane TO-15 16 ug/m‡ Air0120370-07 B2-SSVP-1 Acetone TO-15 2.9 J ug/m‡ Air0120370-07 B2-SSVP-1 Carbon disulfide TO-15 1.9 J ug/m‡ Air0120370-07 B2-SSVP-1 Cyclohexane TO-15 3.2 ug/m‡ Air0120370-07 B2-SSVP-1 Dichlorodifluoromethane TO-15 3.2 J ug/m‡ Air0120370-07 B2-SSVP-1 Isopropyl alcohol TO-15 1.2 J ug/m‡ Air0120370-07 B2-SSVP-1 Methyl Ethyl Ketone (2-Butanone)TO-15 1.2 J ug/m‡ Air0120370-07 B2-SSVP-1 Methylene Chloride TO-15 2.3 J ug/m‡ Air0120370-07 B2-SSVP-1 Tetrachloroethylene TO-15 5.2 ug/m‡ Air0120370-07 B2-SSVP-1 Trichloroethylene TO-15 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 4 of 24 Laboratory Report 12/31/2020 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: ATL-001 Former Rite AidHart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: B2-SSVP-3 Sample ID: 0120370-01 Work Order: 0120370 Time Collected: 12/18/20 15:57 Time Submitted: 12/22/20 14:20 Volatile Organic Compounds by GC/MS TO-15 P0L050712.7 12/28/20 13:29 CBMug/m‡ Air 0.291,1,1-Trichloroethane BDL TO-15 P0L050713.4 12/28/20 13:29 CBMug/m‡ Air 0.281,1,2,2-Tetrachloroethane BDL TO-15 P0L050713.8 12/28/20 13:29 CBMug/m‡ Air 0.531,1,2-Trichloro-1,2,2-trifluoroethane BDL TO-15 P0L050712.7 12/28/20 13:29 CBMug/m‡ Air 0.351,1,2-Trichloroethane BDL TO-15 P0L050712.0 12/28/20 13:29 CBMug/m‡ Air 0.471,1-Dichloroethane BDL TO-15 P0L050712.0 12/28/20 13:29 CBMug/m‡ Air 0.411,1-Dichloroethylene BDL TO-15 P0L050713.7 12/28/20 13:29 CBMug/m‡ Air 0.251,2,4-Trichlorobenzene BDL TO-15 P0L050712.5 12/28/20 13:29 CBMug/m‡ Air 0.291,2,4-Trimethylbenzene 4.4 TO-15 P0L050713.8 12/28/20 13:29 CBMug/m‡ Air 0.611,2-Dibromoethane BDL TO-15 P0L050713.0 12/28/20 13:29 CBMug/m‡ Air 0.481,2-Dichlorobenzene BDL TO-15 P0L050712.0 12/28/20 13:29 CBMug/m‡ Air 0.221,2-Dichloroethane BDL TO-15 P0L050712.3 12/28/20 13:29 CBMug/m‡ Air 0.401,2-Dichloropropane BDL TO-15 P0L050713.5 12/28/20 13:29 CBMug/m‡ Air 0.621,2-Dichloro-1,1,2,2-tetrafluoroethane BDL TO-15 P0L050712.5 12/28/20 13:29 CBMug/m‡ Air 0.261,3,5-Trimethylbenzene BDL TO-15 P0L050711.1 12/28/20 13:29 CBMug/m‡ Air 0.191,3-Butadiene BDL TO-15 P0L050713.0 12/28/20 13:29 CBMug/m‡ Air 0.211,3-Dichlorobenzene BDL TO-15 P0L050713.0 12/28/20 13:29 CBMug/m‡ Air 0.251,4-Dichlorobenzene BDL TO-15 P0L050711.8 12/28/20 13:29 CBMJug/m‡ Air 0.101,4-Dioxane 0.86 TO-15 P0L050712.5 12/28/20 13:29 CBMug/m‡ Air 0.264-Ethyltoluene BDL TO-15 P0L050712.4 12/28/20 13:29 CBMug/m‡ Air 0.59Acetone18 TO-15 P0L050711.6 12/28/20 13:29 CBMug/m‡ Air 0.16BenzeneBDL TO-15 P0L050712.6 12/28/20 13:29 CBMug/m‡ Air 0.20Benzyl chloride BDL TO-15 P0L050713.4 12/28/20 13:29 CBMug/m‡ Air 0.26BromodichloromethaneBDL TO-15 P0L050715.2 12/28/20 13:29 CBMug/m‡ Air 0.45BromoformBDL TO-15 P0L050711.9 12/28/20 13:29 CBMug/m‡ Air 0.32BromomethaneBDL TO-15 P0L050716.2 12/28/20 13:29 CBMug/m‡ Air 1.6Carbon disulfide BDL TO-15 P0L050713.1 12/28/20 13:29 CBMug/m‡ Air 0.24Carbon Tetrachloride BDL TO-15 P0L050712.3 12/28/20 13:29 CBMug/m‡ Air 0.17ChlorobenzeneBDL TO-15 P0L050711.3 12/28/20 13:29 CBMug/m‡ Air 0.38ChloroethaneBDL TO-15 P0L050712.4 12/28/20 13:29 CBMug/m‡ Air 0.26ChloroformBDL TO-15 P0L050711.0 12/28/20 13:29 CBMug/m‡ Air 0.26ChloromethaneBDL TO-15 P0L050712.0 12/28/20 13:29 CBMug/m‡ Air 0.52cis-1,2-Dichloroethylene BDL TO-15 P0L050712.3 12/28/20 13:29 CBMug/m‡ Air 0.16cis-1,3-Dichloropropylene BDL TO-15 P0L050713.4 12/28/20 13:29 CBMJug/m‡ Air 0.87Cyclohexane3.0 TO-15 P0L050714.3 12/28/20 13:29 CBMug/m‡ Air 0.48DibromochloromethaneBDL TO-15 P0L050712.5 12/28/20 13:29 CBMug/m‡ Air 0.41Dichlorodifluoromethane3.3 TO-15 P0L050711.8 12/28/20 13:29 CBMug/m‡ Air 0.25Ethyl Acetate BDL TO-15 P0L050712.2 12/28/20 13:29 CBMug/m‡ Air 0.19EthylbenzeneBDL TO-15 P0L050712.0 12/28/20 13:29 CBMug/m‡ Air 0.19HeptaneBDL TO-15 P0L050715.3 12/28/20 13:29 CBMug/m‡ Air 0.43HexachlorobutadieneBDL TO-15 P0L050711.8 12/28/20 13:29 CBMug/m‡ Air 0.25HexaneBDL TO-15 P0L050714.9 12/28/20 13:29 CBMJug/m‡ Air 0.17Isopropyl alcohol 3.2 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 5 of 24 Laboratory Report 12/31/2020 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: ATL-001 Former Rite AidHart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: B2-SSVP-3 Sample ID: 0120370-01 Work Order: 0120370 Time Collected: 12/18/20 15:57 Time Submitted: 12/22/20 14:20 TO-15 P0L050715.6 12/28/20 13:29 CBMJug/m‡ Air 0.38m,p-Xylenes 1.1 TO-15 P0L050712.0 12/28/20 13:29 CBMug/m‡ Air 0.26Methyl Butyl Ketone (2-Hexanone)BDL TO-15 P0L050711.5 12/28/20 13:29 CBMug/m‡ Air 0.30Methyl Ethyl Ketone (2-Butanone)1.5 TO-15 P0L050712.0 12/28/20 13:29 CBMug/m‡ Air 0.26Methyl Isobutyl Ketone BDL TO-15 P0L050711.7 12/28/20 13:29 CBMug/m‡ Air 0.39Methylene Chloride 9.7 TO-15 P0L050711.8 12/28/20 13:29 CBMug/m‡ Air 0.21Methyl-tert-Butyl Ether BDL TO-15 P0L050712.6 12/28/20 13:29 CBMug/m‡ Air 1.0NaphthaleneBDL TO-15 P0L050712.2 12/28/20 13:29 CBMug/m‡ Air 0.18o-Xylene BDL TO-15 P0L050710.86 12/28/20 13:29 CBMug/m‡ Air 0.14PropyleneBDL TO-15 P0L050712.1 12/28/20 13:29 CBMug/m‡ Air 0.15StyreneBDL TO-15 P0L050713.4 12/28/20 13:29 CBMug/m‡ Air 0.44TetrachloroethyleneBDL TO-15 P0L050711.5 12/28/20 13:29 CBMug/m‡ Air 0.21TetrahydrofuranBDL TO-15 P0L050711.9 12/28/20 13:29 CBMug/m‡ Air 0.75TolueneBDL TO-15 P0L050712.0 12/28/20 13:29 CBMug/m‡ Air 0.48trans-1,2-Dichloroethylene BDL TO-15 P0L050712.3 12/28/20 13:29 CBMug/m‡ Air 0.17trans-1,3-Dichloropropylene BDL TO-15 P0L050712.7 12/28/20 13:29 CBMug/m‡ Air 0.27TrichloroethyleneBDL TO-15 P0L050712.8 12/28/20 13:29 CBMug/m‡ Air 0.43TrichlorofluoromethaneBDL TO-15 P0L050711.8 12/28/20 13:29 CBMug/m‡ Air 0.25Vinyl acetate BDL TO-15 P0L050711.3 12/28/20 13:29 CBMug/m‡ Air 0.29Vinyl chloride BDL Surrogate Recovery Control Limits 70-13088 %4-Bromofluorobenzene This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 6 of 24 Laboratory Report 12/31/2020 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: ATL-001 Former Rite AidHart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: B2-SSVP-2 Sample ID: 0120370-02 Work Order: 0120370 Time Collected: 12/20/20 09:45 Time Submitted: 12/22/20 14:20 Volatile Organic Compounds by GC/MS TO-15 P0L050712.7 12/28/20 14:21 CBMug/m‡ Air 0.291,1,1-Trichloroethane BDL TO-15 P0L050713.4 12/28/20 14:21 CBMug/m‡ Air 0.281,1,2,2-Tetrachloroethane BDL TO-15 P0L050713.8 12/28/20 14:21 CBMJug/m‡ Air 0.531,1,2-Trichloro-1,2,2-trifluoroethane 2.5 TO-15 P0L050712.7 12/28/20 14:21 CBMug/m‡ Air 0.351,1,2-Trichloroethane BDL TO-15 P0L050712.0 12/28/20 14:21 CBMug/m‡ Air 0.471,1-Dichloroethane BDL TO-15 P0L050712.0 12/28/20 14:21 CBMug/m‡ Air 0.411,1-Dichloroethylene BDL TO-15 P0L050713.7 12/28/20 14:21 CBMug/m‡ Air 0.251,2,4-Trichlorobenzene BDL TO-15 P0L050712.5 12/28/20 14:21 CBMug/m‡ Air 0.291,2,4-Trimethylbenzene 4.4 TO-15 P0L050713.8 12/28/20 14:21 CBMug/m‡ Air 0.611,2-Dibromoethane BDL TO-15 P0L050713.0 12/28/20 14:21 CBMug/m‡ Air 0.481,2-Dichlorobenzene BDL TO-15 P0L050712.0 12/28/20 14:21 CBMug/m‡ Air 0.221,2-Dichloroethane BDL TO-15 P0L050712.3 12/28/20 14:21 CBMug/m‡ Air 0.401,2-Dichloropropane BDL TO-15 P0L050713.5 12/28/20 14:21 CBMug/m‡ Air 0.621,2-Dichloro-1,1,2,2-tetrafluoroethane BDL TO-15 P0L050712.5 12/28/20 14:21 CBMug/m‡ Air 0.261,3,5-Trimethylbenzene BDL TO-15 P0L050711.1 12/28/20 14:21 CBMug/m‡ Air 0.191,3-Butadiene BDL TO-15 P0L050713.0 12/28/20 14:21 CBMug/m‡ Air 0.211,3-Dichlorobenzene BDL TO-15 P0L050713.0 12/28/20 14:21 CBMug/m‡ Air 0.251,4-Dichlorobenzene BDL TO-15 P0L050711.8 12/28/20 14:21 CBMug/m‡ Air 0.101,4-Dioxane BDL TO-15 P0L050712.5 12/28/20 14:21 CBMug/m‡ Air 0.264-Ethyltoluene BDL TO-15 P0L050712.4 12/28/20 14:21 CBMug/m‡ Air 0.59Acetone13 TO-15 P0L050711.6 12/28/20 14:21 CBMug/m‡ Air 0.16BenzeneBDL TO-15 P0L050712.6 12/28/20 14:21 CBMug/m‡ Air 0.20Benzyl chloride BDL TO-15 P0L050713.4 12/28/20 14:21 CBMug/m‡ Air 0.26BromodichloromethaneBDL TO-15 P0L050715.2 12/28/20 14:21 CBMug/m‡ Air 0.45BromoformBDL TO-15 P0L050711.9 12/28/20 14:21 CBMug/m‡ Air 0.32BromomethaneBDL TO-15 P0L050716.2 12/28/20 14:21 CBMug/m‡ Air 1.6Carbon disulfide BDL TO-15 P0L050713.1 12/28/20 14:21 CBMug/m‡ Air 0.24Carbon Tetrachloride BDL TO-15 P0L050712.3 12/28/20 14:21 CBMug/m‡ Air 0.17ChlorobenzeneBDL TO-15 P0L050711.3 12/28/20 14:21 CBMug/m‡ Air 0.38ChloroethaneBDL TO-15 P0L050712.4 12/28/20 14:21 CBMug/m‡ Air 0.26ChloroformBDL TO-15 P0L050711.0 12/28/20 14:21 CBMug/m‡ Air 0.26ChloromethaneBDL TO-15 P0L050712.0 12/28/20 14:21 CBMug/m‡ Air 0.52cis-1,2-Dichloroethylene BDL TO-15 P0L050712.3 12/28/20 14:21 CBMug/m‡ Air 0.16cis-1,3-Dichloropropylene BDL TO-15 P0L050713.4 12/28/20 14:21 CBMJug/m‡ Air 0.87Cyclohexane2.2 TO-15 P0L050714.3 12/28/20 14:21 CBMug/m‡ Air 0.48DibromochloromethaneBDL TO-15 P0L050712.5 12/28/20 14:21 CBMug/m‡ Air 0.41Dichlorodifluoromethane3.5 TO-15 P0L050711.8 12/28/20 14:21 CBMug/m‡ Air 0.25Ethyl Acetate BDL TO-15 P0L050712.2 12/28/20 14:21 CBMug/m‡ Air 0.19EthylbenzeneBDL TO-15 P0L050712.0 12/28/20 14:21 CBMug/m‡ Air 0.19HeptaneBDL TO-15 P0L050715.3 12/28/20 14:21 CBMug/m‡ Air 0.43HexachlorobutadieneBDL TO-15 P0L050711.8 12/28/20 14:21 CBMug/m‡ Air 0.25HexaneBDL TO-15 P0L050714.9 12/28/20 14:21 CBMJug/m‡ Air 0.17Isopropyl alcohol 2.0 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 7 of 24 Laboratory Report 12/31/2020 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: ATL-001 Former Rite AidHart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: B2-SSVP-2 Sample ID: 0120370-02 Work Order: 0120370 Time Collected: 12/20/20 09:45 Time Submitted: 12/22/20 14:20 TO-15 P0L050715.6 12/28/20 14:21 CBMug/m‡ Air 0.38m,p-Xylenes BDL TO-15 P0L050712.0 12/28/20 14:21 CBMug/m‡ Air 0.26Methyl Butyl Ketone (2-Hexanone)BDL TO-15 P0L050711.5 12/28/20 14:21 CBMJug/m‡ Air 0.30Methyl Ethyl Ketone (2-Butanone)0.97 TO-15 P0L050712.0 12/28/20 14:21 CBMug/m‡ Air 0.26Methyl Isobutyl Ketone BDL TO-15 P0L050711.7 12/28/20 14:21 CBMug/m‡ Air 0.39Methylene Chloride 5.3 TO-15 P0L050711.8 12/28/20 14:21 CBMug/m‡ Air 0.21Methyl-tert-Butyl Ether BDL TO-15 P0L050712.6 12/28/20 14:21 CBMug/m‡ Air 1.0NaphthaleneBDL TO-15 P0L050712.2 12/28/20 14:21 CBMug/m‡ Air 0.18o-Xylene BDL TO-15 P0L050710.86 12/28/20 14:21 CBMug/m‡ Air 0.14PropyleneBDL TO-15 P0L050712.1 12/28/20 14:21 CBMug/m‡ Air 0.15StyreneBDL TO-15 P0L050713.4 12/28/20 14:21 CBMug/m‡ Air 0.44Tetrachloroethylene3.7 TO-15 P0L050711.5 12/28/20 14:21 CBMug/m‡ Air 0.21TetrahydrofuranBDL TO-15 P0L050711.9 12/28/20 14:21 CBMug/m‡ Air 0.75TolueneBDL TO-15 P0L050712.0 12/28/20 14:21 CBMug/m‡ Air 0.48trans-1,2-Dichloroethylene BDL TO-15 P0L050712.3 12/28/20 14:21 CBMug/m‡ Air 0.17trans-1,3-Dichloropropylene BDL TO-15 P0L050712.7 12/28/20 14:21 CBMug/m‡ Air 0.27TrichloroethyleneBDL TO-15 P0L050712.8 12/28/20 14:21 CBMJug/m‡ Air 0.43Trichlorofluoromethane2.6 TO-15 P0L050711.8 12/28/20 14:21 CBMug/m‡ Air 0.25Vinyl acetate BDL TO-15 P0L050711.3 12/28/20 14:21 CBMug/m‡ Air 0.29Vinyl chloride BDL Surrogate Recovery Control Limits 70-13089 %4-Bromofluorobenzene This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 8 of 24 Laboratory Report 12/31/2020 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: ATL-001 Former Rite AidHart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: B2-SGP-1 Sample ID: 0120370-03 Work Order: 0120370 Time Collected: 12/18/20 14:01 Time Submitted: 12/22/20 14:20 Volatile Organic Compounds by GC/MS TO-15 P0L050712.7 12/28/20 15:13 CBMug/m‡ Air 0.291,1,1-Trichloroethane BDL TO-15 P0L050713.4 12/28/20 15:13 CBMug/m‡ Air 0.281,1,2,2-Tetrachloroethane BDL TO-15 P0L050713.8 12/28/20 15:13 CBMug/m‡ Air 0.531,1,2-Trichloro-1,2,2-trifluoroethane BDL TO-15 P0L050712.7 12/28/20 15:13 CBMug/m‡ Air 0.351,1,2-Trichloroethane BDL TO-15 P0L050712.0 12/28/20 15:13 CBMug/m‡ Air 0.471,1-Dichloroethane BDL TO-15 P0L050712.0 12/28/20 15:13 CBMug/m‡ Air 0.411,1-Dichloroethylene BDL TO-15 P0L050713.7 12/28/20 15:13 CBMug/m‡ Air 0.251,2,4-Trichlorobenzene BDL TO-15 P0L050712.5 12/28/20 15:13 CBMug/m‡ Air 0.291,2,4-Trimethylbenzene 5.1 TO-15 P0L050713.8 12/28/20 15:13 CBMug/m‡ Air 0.611,2-Dibromoethane BDL TO-15 P0L050713.0 12/28/20 15:13 CBMug/m‡ Air 0.481,2-Dichlorobenzene BDL TO-15 P0L050712.0 12/28/20 15:13 CBMug/m‡ Air 0.221,2-Dichloroethane BDL TO-15 P0L050712.3 12/28/20 15:13 CBMug/m‡ Air 0.401,2-Dichloropropane BDL TO-15 P0L050713.5 12/28/20 15:13 CBMug/m‡ Air 0.621,2-Dichloro-1,1,2,2-tetrafluoroethane BDL TO-15 P0L050712.5 12/28/20 15:13 CBMug/m‡ Air 0.261,3,5-Trimethylbenzene BDL TO-15 P0L050711.1 12/28/20 15:13 CBMug/m‡ Air 0.191,3-Butadiene BDL TO-15 P0L050713.0 12/28/20 15:13 CBMug/m‡ Air 0.211,3-Dichlorobenzene BDL TO-15 P0L050713.0 12/28/20 15:13 CBMJug/m‡ Air 0.251,4-Dichlorobenzene 1.3 TO-15 P0L050711.8 12/28/20 15:13 CBMug/m‡ Air 0.101,4-Dioxane BDL TO-15 P0L050712.5 12/28/20 15:13 CBMug/m‡ Air 0.264-Ethyltoluene BDL TO-15 P0L050712.4 12/28/20 15:13 CBMug/m‡ Air 0.59Acetone7.4 TO-15 P0L050711.6 12/28/20 15:13 CBMug/m‡ Air 0.16BenzeneBDL TO-15 P0L050712.6 12/28/20 15:13 CBMug/m‡ Air 0.20Benzyl chloride 5.1 TO-15 P0L050713.4 12/28/20 15:13 CBMug/m‡ Air 0.26Bromodichloromethane12 TO-15 P0L050715.2 12/28/20 15:13 CBMug/m‡ Air 0.45BromoformBDL TO-15 P0L050711.9 12/28/20 15:13 CBMug/m‡ Air 0.32BromomethaneBDL TO-15 P0L050716.2 12/28/20 15:13 CBMug/m‡ Air 1.6Carbon disulfide 10 TO-15 P0L050713.1 12/28/20 15:13 CBMug/m‡ Air 0.24Carbon Tetrachloride BDL TO-15 P0L050712.3 12/28/20 15:13 CBMug/m‡ Air 0.17ChlorobenzeneBDL TO-15 P0L050711.3 12/28/20 15:13 CBMug/m‡ Air 0.38ChloroethaneBDL TO-15 P0L050712.4 12/28/20 15:13 CBMug/m‡ Air 0.26Chloroform70 TO-15 P0L050711.0 12/28/20 15:13 CBMug/m‡ Air 0.26ChloromethaneBDL TO-15 P0L050712.0 12/28/20 15:13 CBMug/m‡ Air 0.52cis-1,2-Dichloroethylene BDL TO-15 P0L050712.3 12/28/20 15:13 CBMug/m‡ Air 0.16cis-1,3-Dichloropropylene BDL TO-15 P0L050713.4 12/28/20 15:13 CBMug/m‡ Air 0.87Cyclohexane4.0 TO-15 P0L050714.3 12/28/20 15:13 CBMJug/m‡ Air 0.48Dibromochloromethane2.1 TO-15 P0L050712.5 12/28/20 15:13 CBMug/m‡ Air 0.41Dichlorodifluoromethane4.1 TO-15 P0L050711.8 12/28/20 15:13 CBMug/m‡ Air 0.25Ethyl Acetate BDL TO-15 P0L050712.2 12/28/20 15:13 CBMug/m‡ Air 0.19EthylbenzeneBDL TO-15 P0L050712.0 12/28/20 15:13 CBMug/m‡ Air 0.19HeptaneBDL TO-15 P0L050715.3 12/28/20 15:13 CBMug/m‡ Air 0.43HexachlorobutadieneBDL TO-15 P0L050711.8 12/28/20 15:13 CBMug/m‡ Air 0.25HexaneBDL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 9 of 24 Laboratory Report 12/31/2020 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: ATL-001 Former Rite AidHart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: B2-SGP-1 Sample ID: 0120370-03 Work Order: 0120370 Time Collected: 12/18/20 14:01 Time Submitted: 12/22/20 14:20 TO-15 P0L050714.9 12/28/20 15:13 CBMJug/m‡ Air 0.17Isopropyl alcohol 4.2 TO-15 P0L050715.6 12/28/20 15:13 CBMJug/m‡ Air 0.38m,p-Xylenes 1.8 TO-15 P0L050712.0 12/28/20 15:13 CBMug/m‡ Air 0.26Methyl Butyl Ketone (2-Hexanone)BDL TO-15 P0L050711.5 12/28/20 15:13 CBMJug/m‡ Air 0.30Methyl Ethyl Ketone (2-Butanone)0.97 TO-15 P0L050712.0 12/28/20 15:13 CBMug/m‡ Air 0.26Methyl Isobutyl Ketone BDL TO-15 P0L050711.7 12/28/20 15:13 CBMug/m‡ Air 0.39Methylene Chloride 10 TO-15 P0L050711.8 12/28/20 15:13 CBMug/m‡ Air 0.21Methyl-tert-Butyl Ether BDL TO-15 P0L050712.6 12/28/20 15:13 CBMug/m‡ Air 1.0NaphthaleneBDL TO-15 P0L050712.2 12/28/20 15:13 CBMug/m‡ Air 0.18o-Xylene BDL TO-15 P0L050710.86 12/28/20 15:13 CBMug/m‡ Air 0.14PropyleneBDL TO-15 P0L050712.1 12/28/20 15:13 CBMug/m‡ Air 0.15Styrene4.3 TO-15 P0L050713.4 12/28/20 15:13 CBMug/m‡ Air 0.44Tetrachloroethylene28 TO-15 P0L050711.5 12/28/20 15:13 CBMJug/m‡ Air 0.21Tetrahydrofuran1.0 TO-15 P0L050711.9 12/28/20 15:13 CBMJug/m‡ Air 0.75Toluene1.8 TO-15 P0L050712.0 12/28/20 15:13 CBMug/m‡ Air 0.48trans-1,2-Dichloroethylene BDL TO-15 P0L050712.3 12/28/20 15:13 CBMug/m‡ Air 0.17trans-1,3-Dichloropropylene BDL TO-15 P0L050712.7 12/28/20 15:13 CBMug/m‡ Air 0.27TrichloroethyleneBDL TO-15 P0L050712.8 12/28/20 15:13 CBMug/m‡ Air 0.43Trichlorofluoromethane6.3 TO-15 P0L050711.8 12/28/20 15:13 CBMug/m‡ Air 0.25Vinyl acetate BDL TO-15 P0L050711.3 12/28/20 15:13 CBMug/m‡ Air 0.29Vinyl chloride BDL Surrogate Recovery Control Limits 70-13090 %4-Bromofluorobenzene This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 10 of 24 Laboratory Report 12/31/2020 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: ATL-001 Former Rite AidHart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: B2-SSVP-5 Sample ID: 0120370-04 Work Order: 0120370 Time Collected: 12/18/20 14:44 Time Submitted: 12/22/20 14:20 Volatile Organic Compounds by GC/MS TO-15 P0L050712.7 12/28/20 16:06 CBMug/m‡ Air 0.291,1,1-Trichloroethane BDL TO-15 P0L050713.4 12/28/20 16:06 CBMug/m‡ Air 0.281,1,2,2-Tetrachloroethane BDL TO-15 P0L050713.8 12/28/20 16:06 CBMug/m‡ Air 0.531,1,2-Trichloro-1,2,2-trifluoroethane BDL TO-15 P0L050712.7 12/28/20 16:06 CBMug/m‡ Air 0.351,1,2-Trichloroethane BDL TO-15 P0L050712.0 12/28/20 16:06 CBMug/m‡ Air 0.471,1-Dichloroethane BDL TO-15 P0L050712.0 12/28/20 16:06 CBMug/m‡ Air 0.411,1-Dichloroethylene BDL TO-15 P0L050713.7 12/28/20 16:06 CBMug/m‡ Air 0.251,2,4-Trichlorobenzene BDL TO-15 P0L050712.5 12/28/20 16:06 CBMug/m‡ Air 0.291,2,4-Trimethylbenzene 4.3 TO-15 P0L050713.8 12/28/20 16:06 CBMug/m‡ Air 0.611,2-Dibromoethane BDL TO-15 P0L050713.0 12/28/20 16:06 CBMug/m‡ Air 0.481,2-Dichlorobenzene BDL TO-15 P0L050712.0 12/28/20 16:06 CBMug/m‡ Air 0.221,2-Dichloroethane BDL TO-15 P0L050712.3 12/28/20 16:06 CBMug/m‡ Air 0.401,2-Dichloropropane BDL TO-15 P0L050713.5 12/28/20 16:06 CBMug/m‡ Air 0.621,2-Dichloro-1,1,2,2-tetrafluoroethane BDL TO-15 P0L050712.5 12/28/20 16:06 CBMug/m‡ Air 0.261,3,5-Trimethylbenzene BDL TO-15 P0L050711.1 12/28/20 16:06 CBMug/m‡ Air 0.191,3-Butadiene BDL TO-15 P0L050713.0 12/28/20 16:06 CBMug/m‡ Air 0.211,3-Dichlorobenzene BDL TO-15 P0L050713.0 12/28/20 16:06 CBMug/m‡ Air 0.251,4-Dichlorobenzene BDL TO-15 P0L050711.8 12/28/20 16:06 CBMug/m‡ Air 0.101,4-Dioxane BDL TO-15 P0L050712.5 12/28/20 16:06 CBMug/m‡ Air 0.264-Ethyltoluene BDL TO-15 P0L050712.4 12/28/20 16:06 CBMug/m‡ Air 0.59Acetone49 TO-15 P0L050711.6 12/28/20 16:06 CBMug/m‡ Air 0.16BenzeneBDL TO-15 P0L050712.6 12/28/20 16:06 CBMug/m‡ Air 0.20Benzyl chloride BDL TO-15 P0L050713.4 12/28/20 16:06 CBMug/m‡ Air 0.26BromodichloromethaneBDL TO-15 P0L050715.2 12/28/20 16:06 CBMug/m‡ Air 0.45BromoformBDL TO-15 P0L050711.9 12/28/20 16:06 CBMug/m‡ Air 0.32BromomethaneBDL TO-15 P0L050716.2 12/28/20 16:06 CBMug/m‡ Air 1.6Carbon disulfide BDL TO-15 P0L050713.1 12/28/20 16:06 CBMug/m‡ Air 0.24Carbon Tetrachloride BDL TO-15 P0L050712.3 12/28/20 16:06 CBMug/m‡ Air 0.17ChlorobenzeneBDL TO-15 P0L050711.3 12/28/20 16:06 CBMug/m‡ Air 0.38ChloroethaneBDL TO-15 P0L050712.4 12/28/20 16:06 CBMug/m‡ Air 0.26ChloroformBDL TO-15 P0L050711.0 12/28/20 16:06 CBMug/m‡ Air 0.26ChloromethaneBDL TO-15 P0L050712.0 12/28/20 16:06 CBMug/m‡ Air 0.52cis-1,2-Dichloroethylene BDL TO-15 P0L050712.3 12/28/20 16:06 CBMug/m‡ Air 0.16cis-1,3-Dichloropropylene BDL TO-15 P0L050713.4 12/28/20 16:06 CBMJug/m‡ Air 0.87Cyclohexane3.2 TO-15 P0L050714.3 12/28/20 16:06 CBMug/m‡ Air 0.48DibromochloromethaneBDL TO-15 P0L050712.5 12/28/20 16:06 CBMug/m‡ Air 0.41Dichlorodifluoromethane3.6 TO-15 P0L050711.8 12/28/20 16:06 CBMug/m‡ Air 0.25Ethyl Acetate BDL TO-15 P0L050712.2 12/28/20 16:06 CBMug/m‡ Air 0.19EthylbenzeneBDL TO-15 P0L050712.0 12/28/20 16:06 CBMug/m‡ Air 0.19HeptaneBDL TO-15 P0L050715.3 12/28/20 16:06 CBMug/m‡ Air 0.43HexachlorobutadieneBDL TO-15 P0L050711.8 12/28/20 16:06 CBMug/m‡ Air 0.25HexaneBDL TO-15 P0L050714.9 12/28/20 16:06 CBMJug/m‡ Air 0.17Isopropyl alcohol 2.7 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 11 of 24 Laboratory Report 12/31/2020 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: ATL-001 Former Rite AidHart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: B2-SSVP-5 Sample ID: 0120370-04 Work Order: 0120370 Time Collected: 12/18/20 14:44 Time Submitted: 12/22/20 14:20 TO-15 P0L050715.6 12/28/20 16:06 CBMug/m‡ Air 0.38m,p-Xylenes BDL TO-15 P0L050712.0 12/28/20 16:06 CBMug/m‡ Air 0.26Methyl Butyl Ketone (2-Hexanone)BDL TO-15 P0L050711.5 12/28/20 16:06 CBMJug/m‡ Air 0.30Methyl Ethyl Ketone (2-Butanone)1.3 TO-15 P0L050712.0 12/28/20 16:06 CBMug/m‡ Air 0.26Methyl Isobutyl Ketone BDL TO-15 P0L050711.7 12/28/20 16:06 CBMug/m‡ Air 0.39Methylene Chloride 12 TO-15 P0L050711.8 12/28/20 16:06 CBMug/m‡ Air 0.21Methyl-tert-Butyl Ether BDL TO-15 P0L050712.6 12/28/20 16:06 CBMug/m‡ Air 1.0NaphthaleneBDL TO-15 P0L050712.2 12/28/20 16:06 CBMug/m‡ Air 0.18o-Xylene BDL TO-15 P0L050710.86 12/28/20 16:06 CBMug/m‡ Air 0.14PropyleneBDL TO-15 P0L050712.1 12/28/20 16:06 CBMug/m‡ Air 0.15StyreneBDL TO-15 P0L050713.4 12/28/20 16:06 CBMJug/m‡ Air 0.44Tetrachloroethylene3.1 TO-15 P0L050711.5 12/28/20 16:06 CBMug/m‡ Air 0.21TetrahydrofuranBDL TO-15 P0L050711.9 12/28/20 16:06 CBMug/m‡ Air 0.75TolueneBDL TO-15 P0L050712.0 12/28/20 16:06 CBMug/m‡ Air 0.48trans-1,2-Dichloroethylene BDL TO-15 P0L050712.3 12/28/20 16:06 CBMug/m‡ Air 0.17trans-1,3-Dichloropropylene BDL TO-15 P0L050712.7 12/28/20 16:06 CBMug/m‡ Air 0.27TrichloroethyleneBDL TO-15 P0L050712.8 12/28/20 16:06 CBMJug/m‡ Air 0.43Trichlorofluoromethane2.0 TO-15 P0L050711.8 12/28/20 16:06 CBMug/m‡ Air 0.25Vinyl acetate BDL TO-15 P0L050711.3 12/28/20 16:06 CBMug/m‡ Air 0.29Vinyl chloride BDL Surrogate Recovery Control Limits 70-13088 %4-Bromofluorobenzene This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 12 of 24 Laboratory Report 12/31/2020 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: ATL-001 Former Rite AidHart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: B2-SSVP-4 Sample ID: 0120370-05 Work Order: 0120370 Time Collected: 12/18/20 15:09 Time Submitted: 12/22/20 14:20 Volatile Organic Compounds by GC/MS TO-15 P0L050712.7 12/28/20 17:01 CBMug/m‡ Air 0.291,1,1-Trichloroethane BDL TO-15 P0L050713.4 12/28/20 17:01 CBMug/m‡ Air 0.281,1,2,2-Tetrachloroethane BDL TO-15 P0L050713.8 12/28/20 17:01 CBMug/m‡ Air 0.531,1,2-Trichloro-1,2,2-trifluoroethane BDL TO-15 P0L050712.7 12/28/20 17:01 CBMug/m‡ Air 0.351,1,2-Trichloroethane BDL TO-15 P0L050712.0 12/28/20 17:01 CBMug/m‡ Air 0.471,1-Dichloroethane BDL TO-15 P0L050712.0 12/28/20 17:01 CBMug/m‡ Air 0.411,1-Dichloroethylene 3.6 TO-15 P0L050713.7 12/28/20 17:01 CBMug/m‡ Air 0.251,2,4-Trichlorobenzene BDL TO-15 P0L050712.5 12/28/20 17:01 CBMug/m‡ Air 0.291,2,4-Trimethylbenzene 4.3 TO-15 P0L050713.8 12/28/20 17:01 CBMug/m‡ Air 0.611,2-Dibromoethane BDL TO-15 P0L050713.0 12/28/20 17:01 CBMug/m‡ Air 0.481,2-Dichlorobenzene BDL TO-15 P0L050712.0 12/28/20 17:01 CBMug/m‡ Air 0.221,2-Dichloroethane BDL TO-15 P0L050712.3 12/28/20 17:01 CBMug/m‡ Air 0.401,2-Dichloropropane BDL TO-15 P0L050713.5 12/28/20 17:01 CBMug/m‡ Air 0.621,2-Dichloro-1,1,2,2-tetrafluoroethane BDL TO-15 P0L050712.5 12/28/20 17:01 CBMug/m‡ Air 0.261,3,5-Trimethylbenzene BDL TO-15 P0L050711.1 12/28/20 17:01 CBMug/m‡ Air 0.191,3-Butadiene BDL TO-15 P0L050713.0 12/28/20 17:01 CBMug/m‡ Air 0.211,3-Dichlorobenzene BDL TO-15 P0L050713.0 12/28/20 17:01 CBMug/m‡ Air 0.251,4-Dichlorobenzene BDL TO-15 P0L050711.8 12/28/20 17:01 CBMug/m‡ Air 0.101,4-Dioxane BDL TO-15 P0L050712.5 12/28/20 17:01 CBMug/m‡ Air 0.264-Ethyltoluene BDL TO-15 P0L050712.4 12/28/20 17:01 CBMug/m‡ Air 0.59Acetone44 TO-15 P0L050711.6 12/28/20 17:01 CBMug/m‡ Air 0.16BenzeneBDL TO-15 P0L050712.6 12/28/20 17:01 CBMug/m‡ Air 0.20Benzyl chloride BDL TO-15 P0L050713.4 12/28/20 17:01 CBMug/m‡ Air 0.26BromodichloromethaneBDL TO-15 P0L050715.2 12/28/20 17:01 CBMug/m‡ Air 0.45BromoformBDL TO-15 P0L050711.9 12/28/20 17:01 CBMug/m‡ Air 0.32BromomethaneBDL TO-15 P0L050716.2 12/28/20 17:01 CBMug/m‡ Air 1.6Carbon disulfide BDL TO-15 P0L050713.1 12/28/20 17:01 CBMug/m‡ Air 0.24Carbon Tetrachloride BDL TO-15 P0L050712.3 12/28/20 17:01 CBMug/m‡ Air 0.17ChlorobenzeneBDL TO-15 P0L050711.3 12/28/20 17:01 CBMug/m‡ Air 0.38ChloroethaneBDL TO-15 P0L050712.4 12/28/20 17:01 CBMug/m‡ Air 0.26ChloroformBDL TO-15 P0L050711.0 12/28/20 17:01 CBMug/m‡ Air 0.26ChloromethaneBDL TO-15 P0L050712.0 12/28/20 17:01 CBMug/m‡ Air 0.52cis-1,2-Dichloroethylene BDL TO-15 P0L050712.3 12/28/20 17:01 CBMug/m‡ Air 0.16cis-1,3-Dichloropropylene BDL TO-15 P0L050713.4 12/28/20 17:01 CBMug/m‡ Air 0.87Cyclohexane4.0 TO-15 P0L050714.3 12/28/20 17:01 CBMug/m‡ Air 0.48DibromochloromethaneBDL TO-15 P0L050712.5 12/28/20 17:01 CBMug/m‡ Air 0.41Dichlorodifluoromethane3.6 TO-15 P0L050711.8 12/28/20 17:01 CBMug/m‡ Air 0.25Ethyl Acetate BDL TO-15 P0L050712.2 12/28/20 17:01 CBMug/m‡ Air 0.19EthylbenzeneBDL TO-15 P0L050712.0 12/28/20 17:01 CBMug/m‡ Air 0.19HeptaneBDL TO-15 P0L050715.3 12/28/20 17:01 CBMug/m‡ Air 0.43HexachlorobutadieneBDL TO-15 P0L050711.8 12/28/20 17:01 CBMug/m‡ Air 0.25HexaneBDL TO-15 P0L050714.9 12/28/20 17:01 CBMJug/m‡ Air 0.17Isopropyl alcohol 3.0 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 13 of 24 Laboratory Report 12/31/2020 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: ATL-001 Former Rite AidHart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: B2-SSVP-4 Sample ID: 0120370-05 Work Order: 0120370 Time Collected: 12/18/20 15:09 Time Submitted: 12/22/20 14:20 TO-15 P0L050715.6 12/28/20 17:01 CBMug/m‡ Air 0.38m,p-Xylenes BDL TO-15 P0L050712.0 12/28/20 17:01 CBMug/m‡ Air 0.26Methyl Butyl Ketone (2-Hexanone)BDL TO-15 P0L050711.5 12/28/20 17:01 CBMJug/m‡ Air 0.30Methyl Ethyl Ketone (2-Butanone)1.3 TO-15 P0L050712.0 12/28/20 17:01 CBMug/m‡ Air 0.26Methyl Isobutyl Ketone BDL TO-15 P0L050711.7 12/28/20 17:01 CBMug/m‡ Air 0.39Methylene Chloride 11 TO-15 P0L050711.8 12/28/20 17:01 CBMug/m‡ Air 0.21Methyl-tert-Butyl Ether BDL TO-15 P0L050712.6 12/28/20 17:01 CBMug/m‡ Air 1.0NaphthaleneBDL TO-15 P0L050712.2 12/28/20 17:01 CBMug/m‡ Air 0.18o-Xylene BDL TO-15 P0L050710.86 12/28/20 17:01 CBMug/m‡ Air 0.14PropyleneBDL TO-15 P0L050712.1 12/28/20 17:01 CBMug/m‡ Air 0.15StyreneBDL TO-15 P0L050713.4 12/28/20 17:01 CBMJug/m‡ Air 0.44Tetrachloroethylene3.1 TO-15 P0L050711.5 12/28/20 17:01 CBMug/m‡ Air 0.21TetrahydrofuranBDL TO-15 P0L050711.9 12/28/20 17:01 CBMJug/m‡ Air 0.75Toluene0.83 TO-15 P0L050712.0 12/28/20 17:01 CBMug/m‡ Air 0.48trans-1,2-Dichloroethylene 3.7 TO-15 P0L050712.3 12/28/20 17:01 CBMug/m‡ Air 0.17trans-1,3-Dichloropropylene BDL TO-15 P0L050712.7 12/28/20 17:01 CBMug/m‡ Air 0.27TrichloroethyleneBDL TO-15 P0L050712.8 12/28/20 17:01 CBMJug/m‡ Air 0.43Trichlorofluoromethane1.9 TO-15 P0L050711.8 12/28/20 17:01 CBMug/m‡ Air 0.25Vinyl acetate BDL TO-15 P0L050711.3 12/28/20 17:01 CBMug/m‡ Air 0.29Vinyl chloride BDL Surrogate Recovery Control Limits 70-13089 %4-Bromofluorobenzene This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 14 of 24 Laboratory Report 12/31/2020 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: ATL-001 Former Rite AidHart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: B2-SSVP-DUP Sample ID: 0120370-06 Work Order: 0120370 Time Collected: 12/20/20 00:00 Time Submitted: 12/22/20 14:20 Volatile Organic Compounds by GC/MS TO-15 P0L050712.7 12/28/20 17:53 CBMug/m‡ Air 0.291,1,1-Trichloroethane BDL TO-15 P0L050713.4 12/28/20 17:53 CBMug/m‡ Air 0.281,1,2,2-Tetrachloroethane BDL TO-15 P0L050713.8 12/28/20 17:53 CBMJug/m‡ Air 0.531,1,2-Trichloro-1,2,2-trifluoroethane 2.4 TO-15 P0L050712.7 12/28/20 17:53 CBMug/m‡ Air 0.351,1,2-Trichloroethane BDL TO-15 P0L050712.0 12/28/20 17:53 CBMug/m‡ Air 0.471,1-Dichloroethane BDL TO-15 P0L050712.0 12/28/20 17:53 CBMug/m‡ Air 0.411,1-Dichloroethylene BDL TO-15 P0L050713.7 12/28/20 17:53 CBMug/m‡ Air 0.251,2,4-Trichlorobenzene BDL TO-15 P0L050712.5 12/28/20 17:53 CBMug/m‡ Air 0.291,2,4-Trimethylbenzene 4.4 TO-15 P0L050713.8 12/28/20 17:53 CBMug/m‡ Air 0.611,2-Dibromoethane BDL TO-15 P0L050713.0 12/28/20 17:53 CBMug/m‡ Air 0.481,2-Dichlorobenzene BDL TO-15 P0L050712.0 12/28/20 17:53 CBMug/m‡ Air 0.221,2-Dichloroethane BDL TO-15 P0L050712.3 12/28/20 17:53 CBMug/m‡ Air 0.401,2-Dichloropropane BDL TO-15 P0L050713.5 12/28/20 17:53 CBMug/m‡ Air 0.621,2-Dichloro-1,1,2,2-tetrafluoroethane BDL TO-15 P0L050712.5 12/28/20 17:53 CBMug/m‡ Air 0.261,3,5-Trimethylbenzene BDL TO-15 P0L050711.1 12/28/20 17:53 CBMug/m‡ Air 0.191,3-Butadiene BDL TO-15 P0L050713.0 12/28/20 17:53 CBMug/m‡ Air 0.211,3-Dichlorobenzene BDL TO-15 P0L050713.0 12/28/20 17:53 CBMug/m‡ Air 0.251,4-Dichlorobenzene BDL TO-15 P0L050711.8 12/28/20 17:53 CBMug/m‡ Air 0.101,4-Dioxane BDL TO-15 P0L050712.5 12/28/20 17:53 CBMug/m‡ Air 0.264-Ethyltoluene BDL TO-15 P0L050712.4 12/28/20 17:53 CBMug/m‡ Air 0.59Acetone6.8 TO-15 P0L050711.6 12/28/20 17:53 CBMug/m‡ Air 0.16BenzeneBDL TO-15 P0L050712.6 12/28/20 17:53 CBMug/m‡ Air 0.20Benzyl chloride BDL TO-15 P0L050713.4 12/28/20 17:53 CBMug/m‡ Air 0.26BromodichloromethaneBDL TO-15 P0L050715.2 12/28/20 17:53 CBMug/m‡ Air 0.45BromoformBDL TO-15 P0L050711.9 12/28/20 17:53 CBMug/m‡ Air 0.32BromomethaneBDL TO-15 P0L050716.2 12/28/20 17:53 CBMJug/m‡ Air 1.6Carbon disulfide 2.3 TO-15 P0L050713.1 12/28/20 17:53 CBMug/m‡ Air 0.24Carbon Tetrachloride BDL TO-15 P0L050712.3 12/28/20 17:53 CBMug/m‡ Air 0.17ChlorobenzeneBDL TO-15 P0L050711.3 12/28/20 17:53 CBMug/m‡ Air 0.38ChloroethaneBDL TO-15 P0L050712.4 12/28/20 17:53 CBMug/m‡ Air 0.26ChloroformBDL TO-15 P0L050711.0 12/28/20 17:53 CBMug/m‡ Air 0.26ChloromethaneBDL TO-15 P0L050712.0 12/28/20 17:53 CBMug/m‡ Air 0.52cis-1,2-Dichloroethylene BDL TO-15 P0L050712.3 12/28/20 17:53 CBMug/m‡ Air 0.16cis-1,3-Dichloropropylene BDL TO-15 P0L050713.4 12/28/20 17:53 CBMJug/m‡ Air 0.87Cyclohexane2.2 TO-15 P0L050714.3 12/28/20 17:53 CBMug/m‡ Air 0.48DibromochloromethaneBDL TO-15 P0L050712.5 12/28/20 17:53 CBMug/m‡ Air 0.41Dichlorodifluoromethane3.6 TO-15 P0L050711.8 12/28/20 17:53 CBMug/m‡ Air 0.25Ethyl Acetate BDL TO-15 P0L050712.2 12/28/20 17:53 CBMug/m‡ Air 0.19EthylbenzeneBDL TO-15 P0L050712.0 12/28/20 17:53 CBMug/m‡ Air 0.19HeptaneBDL TO-15 P0L050715.3 12/28/20 17:53 CBMug/m‡ Air 0.43HexachlorobutadieneBDL TO-15 P0L050711.8 12/28/20 17:53 CBMug/m‡ Air 0.25HexaneBDL TO-15 P0L050714.9 12/28/20 17:53 CBMJug/m‡ Air 0.17Isopropyl alcohol 2.0 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 15 of 24 Laboratory Report 12/31/2020 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: ATL-001 Former Rite AidHart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: B2-SSVP-DUP Sample ID: 0120370-06 Work Order: 0120370 Time Collected: 12/20/20 00:00 Time Submitted: 12/22/20 14:20 TO-15 P0L050715.6 12/28/20 17:53 CBMug/m‡ Air 0.38m,p-Xylenes BDL TO-15 P0L050712.0 12/28/20 17:53 CBMug/m‡ Air 0.26Methyl Butyl Ketone (2-Hexanone)BDL TO-15 P0L050711.5 12/28/20 17:53 CBMJug/m‡ Air 0.30Methyl Ethyl Ketone (2-Butanone)0.91 TO-15 P0L050712.0 12/28/20 17:53 CBMug/m‡ Air 0.26Methyl Isobutyl Ketone BDL TO-15 P0L050711.7 12/28/20 17:53 CBMug/m‡ Air 0.39Methylene Chloride 10 TO-15 P0L050711.8 12/28/20 17:53 CBMug/m‡ Air 0.21Methyl-tert-Butyl Ether BDL TO-15 P0L050712.6 12/28/20 17:53 CBMug/m‡ Air 1.0NaphthaleneBDL TO-15 P0L050712.2 12/28/20 17:53 CBMug/m‡ Air 0.18o-Xylene BDL TO-15 P0L050710.86 12/28/20 17:53 CBMug/m‡ Air 0.14PropyleneBDL TO-15 P0L050712.1 12/28/20 17:53 CBMug/m‡ Air 0.15StyreneBDL TO-15 P0L050713.4 12/28/20 17:53 CBMug/m‡ Air 0.44Tetrachloroethylene3.7 TO-15 P0L050711.5 12/28/20 17:53 CBMug/m‡ Air 0.21TetrahydrofuranBDL TO-15 P0L050711.9 12/28/20 17:53 CBMug/m‡ Air 0.75TolueneBDL TO-15 P0L050712.0 12/28/20 17:53 CBMug/m‡ Air 0.48trans-1,2-Dichloroethylene BDL TO-15 P0L050712.3 12/28/20 17:53 CBMug/m‡ Air 0.17trans-1,3-Dichloropropylene BDL TO-15 P0L050712.7 12/28/20 17:53 CBMug/m‡ Air 0.27TrichloroethyleneBDL TO-15 P0L050712.8 12/28/20 17:53 CBMug/m‡ Air 0.43Trichlorofluoromethane2.9 TO-15 P0L050711.8 12/28/20 17:53 CBMug/m‡ Air 0.25Vinyl acetate BDL TO-15 P0L050711.3 12/28/20 17:53 CBMug/m‡ Air 0.29Vinyl chloride BDL Surrogate Recovery Control Limits 70-13088 %4-Bromofluorobenzene This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 16 of 24 Laboratory Report 12/31/2020 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: ATL-001 Former Rite AidHart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: B2-SSVP-1 Sample ID: 0120370-07 Work Order: 0120370 Time Collected: 12/22/20 07:54 Time Submitted: 12/22/20 14:20 Volatile Organic Compounds by GC/MS TO-15 P0L050712.7 12/28/20 18:45 CBMug/m‡ Air 0.291,1,1-Trichloroethane BDL TO-15 P0L050713.4 12/28/20 18:45 CBMug/m‡ Air 0.281,1,2,2-Tetrachloroethane BDL TO-15 P0L050713.8 12/28/20 18:45 CBMug/m‡ Air 0.531,1,2-Trichloro-1,2,2-trifluoroethane BDL TO-15 P0L050712.7 12/28/20 18:45 CBMug/m‡ Air 0.351,1,2-Trichloroethane BDL TO-15 P0L050712.0 12/28/20 18:45 CBMug/m‡ Air 0.471,1-Dichloroethane BDL TO-15 P0L050712.0 12/28/20 18:45 CBMug/m‡ Air 0.411,1-Dichloroethylene BDL TO-15 P0L050713.7 12/28/20 18:45 CBMug/m‡ Air 0.251,2,4-Trichlorobenzene BDL TO-15 P0L050712.5 12/28/20 18:45 CBMug/m‡ Air 0.291,2,4-Trimethylbenzene 4.3 TO-15 P0L050713.8 12/28/20 18:45 CBMug/m‡ Air 0.611,2-Dibromoethane BDL TO-15 P0L050713.0 12/28/20 18:45 CBMug/m‡ Air 0.481,2-Dichlorobenzene BDL TO-15 P0L050712.0 12/28/20 18:45 CBMug/m‡ Air 0.221,2-Dichloroethane BDL TO-15 P0L050712.3 12/28/20 18:45 CBMug/m‡ Air 0.401,2-Dichloropropane BDL TO-15 P0L050713.5 12/28/20 18:45 CBMug/m‡ Air 0.621,2-Dichloro-1,1,2,2-tetrafluoroethane BDL TO-15 P0L050712.5 12/28/20 18:45 CBMug/m‡ Air 0.261,3,5-Trimethylbenzene BDL TO-15 P0L050711.1 12/28/20 18:45 CBMug/m‡ Air 0.191,3-Butadiene BDL TO-15 P0L050713.0 12/28/20 18:45 CBMug/m‡ Air 0.211,3-Dichlorobenzene BDL TO-15 P0L050713.0 12/28/20 18:45 CBMug/m‡ Air 0.251,4-Dichlorobenzene BDL TO-15 P0L050711.8 12/28/20 18:45 CBMJug/m‡ Air 0.101,4-Dioxane 1.0 TO-15 P0L050712.5 12/28/20 18:45 CBMug/m‡ Air 0.264-Ethyltoluene BDL TO-15 P0L050712.4 12/28/20 18:45 CBMug/m‡ Air 0.59Acetone16 TO-15 P0L050711.6 12/28/20 18:45 CBMug/m‡ Air 0.16BenzeneBDL TO-15 P0L050712.6 12/28/20 18:45 CBMug/m‡ Air 0.20Benzyl chloride BDL TO-15 P0L050713.4 12/28/20 18:45 CBMug/m‡ Air 0.26BromodichloromethaneBDL TO-15 P0L050715.2 12/28/20 18:45 CBMug/m‡ Air 0.45BromoformBDL TO-15 P0L050711.9 12/28/20 18:45 CBMug/m‡ Air 0.32BromomethaneBDL TO-15 P0L050716.2 12/28/20 18:45 CBMJug/m‡ Air 1.6Carbon disulfide 2.9 TO-15 P0L050713.1 12/28/20 18:45 CBMug/m‡ Air 0.24Carbon Tetrachloride BDL TO-15 P0L050712.3 12/28/20 18:45 CBMug/m‡ Air 0.17ChlorobenzeneBDL TO-15 P0L050711.3 12/28/20 18:45 CBMug/m‡ Air 0.38ChloroethaneBDL TO-15 P0L050712.4 12/28/20 18:45 CBMug/m‡ Air 0.26ChloroformBDL TO-15 P0L050711.0 12/28/20 18:45 CBMug/m‡ Air 0.26ChloromethaneBDL TO-15 P0L050712.0 12/28/20 18:45 CBMug/m‡ Air 0.52cis-1,2-Dichloroethylene BDL TO-15 P0L050712.3 12/28/20 18:45 CBMug/m‡ Air 0.16cis-1,3-Dichloropropylene BDL TO-15 P0L050713.4 12/28/20 18:45 CBMJug/m‡ Air 0.87Cyclohexane1.9 TO-15 P0L050714.3 12/28/20 18:45 CBMug/m‡ Air 0.48DibromochloromethaneBDL TO-15 P0L050712.5 12/28/20 18:45 CBMug/m‡ Air 0.41Dichlorodifluoromethane3.2 TO-15 P0L050711.8 12/28/20 18:45 CBMug/m‡ Air 0.25Ethyl Acetate BDL TO-15 P0L050712.2 12/28/20 18:45 CBMug/m‡ Air 0.19EthylbenzeneBDL TO-15 P0L050712.0 12/28/20 18:45 CBMug/m‡ Air 0.19HeptaneBDL TO-15 P0L050715.3 12/28/20 18:45 CBMug/m‡ Air 0.43HexachlorobutadieneBDL TO-15 P0L050711.8 12/28/20 18:45 CBMug/m‡ Air 0.25HexaneBDL TO-15 P0L050714.9 12/28/20 18:45 CBMJug/m‡ Air 0.17Isopropyl alcohol 3.2 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 17 of 24 Laboratory Report 12/31/2020 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: ATL-001 Former Rite AidHart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: B2-SSVP-1 Sample ID: 0120370-07 Work Order: 0120370 Time Collected: 12/22/20 07:54 Time Submitted: 12/22/20 14:20 TO-15 P0L050715.6 12/28/20 18:45 CBMug/m‡ Air 0.38m,p-Xylenes BDL TO-15 P0L050712.0 12/28/20 18:45 CBMug/m‡ Air 0.26Methyl Butyl Ketone (2-Hexanone)BDL TO-15 P0L050711.5 12/28/20 18:45 CBMJug/m‡ Air 0.30Methyl Ethyl Ketone (2-Butanone)1.2 TO-15 P0L050712.0 12/28/20 18:45 CBMug/m‡ Air 0.26Methyl Isobutyl Ketone BDL TO-15 P0L050711.7 12/28/20 18:45 CBMJug/m‡ Air 0.39Methylene Chloride 1.2 TO-15 P0L050711.8 12/28/20 18:45 CBMug/m‡ Air 0.21Methyl-tert-Butyl Ether BDL TO-15 P0L050712.6 12/28/20 18:45 CBMug/m‡ Air 1.0NaphthaleneBDL TO-15 P0L050712.2 12/28/20 18:45 CBMug/m‡ Air 0.18o-Xylene BDL TO-15 P0L050710.86 12/28/20 18:45 CBMug/m‡ Air 0.14PropyleneBDL TO-15 P0L050712.1 12/28/20 18:45 CBMug/m‡ Air 0.15StyreneBDL TO-15 P0L050713.4 12/28/20 18:45 CBMJug/m‡ Air 0.44Tetrachloroethylene2.3 TO-15 P0L050711.5 12/28/20 18:45 CBMug/m‡ Air 0.21TetrahydrofuranBDL TO-15 P0L050711.9 12/28/20 18:45 CBMug/m‡ Air 0.75TolueneBDL TO-15 P0L050712.0 12/28/20 18:45 CBMug/m‡ Air 0.48trans-1,2-Dichloroethylene BDL TO-15 P0L050712.3 12/28/20 18:45 CBMug/m‡ Air 0.17trans-1,3-Dichloropropylene BDL TO-15 P0L050712.7 12/28/20 18:45 CBMug/m‡ Air 0.27Trichloroethylene5.2 TO-15 P0L050712.8 12/28/20 18:45 CBMug/m‡ Air 0.43TrichlorofluoromethaneBDL TO-15 P0L050711.8 12/28/20 18:45 CBMug/m‡ Air 0.25Vinyl acetate BDL TO-15 P0L050711.3 12/28/20 18:45 CBMug/m‡ Air 0.29Vinyl chloride BDL Surrogate Recovery Control Limits 70-13093 %4-Bromofluorobenzene This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 18 of 24 12/31/20 Level II QC Report 2923 South Tryon St. Ste 100 Project: ATL-001 Former Rite AidHart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 0120370 Time Submitted: 12/22/2020 2:20:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control Batch P0L0507 - NO PREP VOA Blank (P0L0507-BLK1)Prepared & Analyzed: 12/28/20 1,1,1-Trichloroethane ug/m‡ AirBRL2.7 1,1,2,2-Tetrachloroethane ug/m‡ AirBRL3.4 1,1,2-Trichloro-1,2,2-trifluoroethane ug/m‡ AirBRL3.8 1,1,2-Trichloroethane ug/m‡ AirBRL2.7 1,1-Dichloroethane ug/m‡ AirBRL2.0 1,1-Dichloroethylene ug/m‡ AirBRL2.0 1,2,4-Trichlorobenzene ug/m‡ AirBRL3.7 1,2,4-Trimethylbenzene ug/m‡ AirBRL2.5 1,2-Dibromoethane ug/m‡ AirBRL3.8 1,2-Dichlorobenzene ug/m‡ AirBRL3.0 1,2-Dichloroethane ug/m‡ AirBRL2.0 1,2-Dichloropropane ug/m‡ AirBRL2.3 1,2-Dichloro-1,1,2,2-tetrafluoroethane ug/m‡ AirBRL3.5 1,3,5-Trimethylbenzene ug/m‡ AirBRL2.5 1,3-Butadiene ug/m‡ AirBRL1.1 1,3-Dichlorobenzene ug/m‡ AirBRL3.0 1,4-Dichlorobenzene ug/m‡ AirBRL3.0 1,4-Dioxane ug/m‡ AirBRL1.8 4-Ethyltoluene ug/m‡ AirBRL2.5 Acetone ug/m‡ AirBRL2.4 Benzene ug/m‡ AirBRL1.6 Benzyl chloride ug/m‡ AirBRL2.6 Bromodichloromethane ug/m‡ AirBRL3.4 Bromoform ug/m‡ AirBRL5.2 Bromomethane ug/m‡ AirBRL1.9 Carbon disulfide ug/m‡ AirBRL6.2 Carbon Tetrachloride ug/m‡ AirBRL3.1 Chlorobenzene ug/m‡ AirBRL2.3 Chloroethane ug/m‡ AirBRL1.3 Chloroform ug/m‡ AirBRL2.4 Chloromethane ug/m‡ AirBRL1.0 cis-1,2-Dichloroethylene ug/m‡ AirBRL2.0 cis-1,3-Dichloropropylene ug/m‡ AirBRL2.3 Cyclohexane ug/m‡ AirBRL3.4 Dibromochloromethane ug/m‡ AirBRL4.3 Dichlorodifluoromethane ug/m‡ AirBRL2.5 Ethyl Acetate ug/m‡ AirBRL1.8 Ethylbenzene ug/m‡ AirBRL2.2 Heptane ug/m‡ AirBRL2.0 Hexachlorobutadiene ug/m‡ AirBRL5.3 Hexane ug/m‡ AirBRL1.8 Isopropyl alcohol ug/m‡ AirBRL4.9 m,p-Xylenes ug/m‡ AirBRL5.6 Methyl Butyl Ketone (2-Hexanone)ug/m‡ AirBRL2.0 Methyl Ethyl Ketone (2-Butanone)ug/m‡ AirBRL1.5 Methyl Isobutyl Ketone ug/m‡ AirBRL2.0 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 19 of 24 12/31/20 Level II QC Report 2923 South Tryon St. Ste 100 Project: ATL-001 Former Rite AidHart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 0120370 Time Submitted: 12/22/2020 2:20:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control Batch P0L0507 - NO PREP VOA Blank (P0L0507-BLK1)Prepared & Analyzed: 12/28/20 Methylene Chloride ug/m‡ AirBRL1.7 Methyl-tert-Butyl Ether ug/m‡ AirBRL1.8 Naphthalene ug/m‡ AirBRL2.6 o-Xylene ug/m‡ AirBRL2.2 Propylene ug/m‡ AirBRL0.86 Styrene ug/m‡ AirBRL2.1 Tetrachloroethylene ug/m‡ AirBRL3.4 Tetrahydrofuran ug/m‡ AirBRL1.5 Toluene ug/m‡ AirBRL1.9 trans-1,2-Dichloroethylene ug/m‡ AirBRL2.0 trans-1,3-Dichloropropylene ug/m‡ AirBRL2.3 Trichloroethylene ug/m‡ AirBRL2.7 Trichlorofluoromethane ug/m‡ AirBRL2.8 Vinyl acetate ug/m‡ AirBRL1.8 Vinyl chloride ug/m‡ AirBRL1.3 ppbv 5.000 70-130Surrogate: 4-Bromofluorobenzene 904.51 LCS (P0L0507-BS1)Prepared & Analyzed: 12/28/20 1,1,1-Trichloroethane ug/m‡ Air25.6 2.7 27.28 70-13094 1,1,2,2-Tetrachloroethane ug/m‡ Air40.0 3.4 34.33 70-130116 1,1,2-Trichloro-1,2,2-trifluoroethane ug/m‡ Air40.6 3.8 38.32 70-130106 1,1,2-Trichloroethane ug/m‡ Air28.9 2.7 27.28 70-130106 1,1-Dichloroethane ug/m‡ Air21.3 2.0 20.24 70-130105 1,1-Dichloroethylene ug/m‡ Air20.5 2.0 19.82 70-130103 1,2,4-Trichlorobenzene ug/m‡ Air41.4 3.7 37.11 70-130112 1,2,4-Trimethylbenzene ug/m‡ Air20.6 2.5 24.58 70-13084 1,2-Dibromoethane ug/m‡ Air40.5 3.8 38.42 70-130105 1,2-Dichlorobenzene ug/m‡ Air29.5 3.0 30.06 70-13098 1,2-Dichloroethane ug/m‡ Air19.8 2.0 20.24 70-13098 1,2-Dichloropropane ug/m‡ Air22.3 2.3 23.11 70-13096 1,2-Dichloro-1,1,2,2-tetrafluoroethane ug/m‡ Air38.0 3.5 34.95 70-130109 1,3,5-Trimethylbenzene ug/m‡ Air27.4 2.5 24.58 70-130112 1,3-Butadiene ug/m‡ Air11.1 1.1 11.06 70-130101 1,3-Dichlorobenzene ug/m‡ Air28.6 3.0 30.06 70-13095 1,4-Dichlorobenzene ug/m‡ Air27.1 3.0 30.06 70-13090 1,4-Dioxane ug/m‡ Air16.8 1.8 18.02 70-13093 4-Ethyltoluene ug/m‡ Air21.6 2.5 24.58 70-13088 Acetone ug/m‡ Air11.9 2.4 11.88 70-130100 Benzene ug/m‡ Air15.7 1.6 15.97 70-13098 Benzyl chloride ug/m‡ Air22.7 2.6 25.89 70-13088 Bromodichloromethane ug/m‡ Air32.7 3.4 33.50 70-13098 Bromoform ug/m‡ Air56.6 5.2 51.69 70-130110 Bromomethane ug/m‡ Air20.7 1.9 19.42 70-130107 Carbon disulfide ug/m‡ Air16.3 6.2 15.57 70-130105 Carbon Tetrachloride ug/m‡ Air30.9 3.1 31.46 70-13098 Chlorobenzene ug/m‡ Air24.5 2.3 23.02 70-130107 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 20 of 24 12/31/20 Level II QC Report 2923 South Tryon St. Ste 100 Project: ATL-001 Former Rite AidHart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 0120370 Time Submitted: 12/22/2020 2:20:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control Batch P0L0507 - NO PREP VOA LCS (P0L0507-BS1)Prepared & Analyzed: 12/28/20 Chloroethane ug/m‡ Air13.9 1.3 13.19 70-130105 Chloroform ug/m‡ Air24.2 2.4 24.41 70-13099 Chloromethane ug/m‡ Air10.9 1.0 10.33 70-130105 cis-1,2-Dichloroethylene ug/m‡ Air20.5 2.0 19.82 70-130104 cis-1,3-Dichloropropylene ug/m‡ Air22.2 2.3 22.69 70-13098 Cyclohexane ug/m‡ Air14.5 3.4 17.21 70-13084 Dibromochloromethane ug/m‡ Air45.7 4.3 42.60 70-130107 Dichlorodifluoromethane ug/m‡ Air25.4 2.5 24.73 70-130103 Ethyl Acetate ug/m‡ Air17.8 1.8 18.02 70-13099 Ethylbenzene ug/m‡ Air23.1 2.2 21.71 70-130106 Heptane ug/m‡ Air20.1 2.0 20.49 70-13098 Hexachlorobutadiene ug/m‡ Air55.8 5.3 53.33 70-130105 Hexane ug/m‡ Air18.2 1.8 17.62 70-130103 Isopropyl alcohol ug/m‡ Air12.5 4.9 12.29 70-130102 m,p-Xylenes ug/m‡ Air62.4 5.6 56.49 70-130110 Methyl Butyl Ketone (2-Hexanone)ug/m‡ Air21.2 2.0 20.48 70-130104 Methyl Ethyl Ketone (2-Butanone)ug/m‡ Air15.0 1.5 14.75 70-130101 Methyl Isobutyl Ketone ug/m‡ Air19.4 2.0 20.48 70-13095 Methylene Chloride ug/m‡ Air17.8 1.7 17.37 70-130102 Methyl-tert-Butyl Ether ug/m‡ Air17.3 1.8 18.03 70-13096 Naphthalene ug/m‡ Air25.5 2.6 26.21 64-13697 o-Xylene ug/m‡ Air22.9 2.2 21.71 70-130105 Propylene ug/m‡ Air8.69 0.86 8.605 70-130101 Styrene ug/m‡ Air18.5 2.1 21.30 70-13087 Tetrachloroethylene ug/m‡ Air34.0 3.4 33.91 70-130100 Tetrahydrofuran ug/m‡ Air14.1 1.5 14.75 70-13096 Toluene ug/m‡ Air18.2 1.9 18.84 70-13097 trans-1,2-Dichloroethylene ug/m‡ Air20.0 2.0 19.82 70-130101 trans-1,3-Dichloropropylene ug/m‡ Air22.2 2.3 22.69 70-13098 Trichloroethylene ug/m‡ Air26.8 2.7 26.87 70-130100 Trichlorofluoromethane ug/m‡ Air29.5 2.8 28.09 70-130105 Vinyl acetate ug/m‡ Air18.1 1.8 17.61 70-130103 Vinyl chloride ug/m‡ Air13.0 1.3 12.78 70-130101 ppbv 5.000 70-130Surrogate: 4-Bromofluorobenzene 1025.08 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 21 of 24 Sample Extraction Data Prep Method: NO PREP VOA Lab Number Batch Date/TimeInitialFinal P0L05070120370-01 12/28/20 9:00250 250mL mL P0L05070120370-02 12/28/20 9:00250 250mL mL P0L05070120370-03 12/28/20 9:00250 250mL mL P0L05070120370-04 12/28/20 9:00250 250mL mL P0L05070120370-05 12/28/20 9:00250 250mL mL P0L05070120370-06 12/28/20 9:00250 250mL mL P0L05070120370-07 12/28/20 9:00250 250mL mL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 22 of 24 Page 23 of 24 Page 24 of 24 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. NC Certification No. 402 NC Drinking Water Cert No. 37735 SC Certification No. 99012 Case Narrative 1/15/21 15:06 Hart & Hickman (Charlotte) Matt Ingalls 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: ATL-001 Former Rite Aid Lab Submittal Date: 01/14/2021 Work Order: 1010231 Please call if you have any questions relating to this analytical report. Respectfully, WAYPOINT ANALYTICAL Senior Project Manager Angela D. Overcash Data Qualifiers Key Reference: J Detected but below the Reporting Limit; therefore, result is an estimated concentration (CLP J-Flag). Method Detection LimitMDL Below Reporting LimitBRL Relative Percent DifferenceRPD *Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 1 of 11 Sample Receipt Summary 01/15/2021 Work Order: 1010231 Client Sample ID MatrixLab Sample ID Date/Time Sampled Date/Time Received 1010231-01 01/14/21 15:16B2-SSVP-6 01/14/21 16:14Air 1010231-02 01/14/21 15:44B2-SSVP-7 01/14/21 16:14Air Samples were received in good condition at 6.0 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 2 of 11 Client ID ResultParameterMethod UnitsWaypoint ID Work Order: 1010231 01/15/2021 Summary of Detections 45 ug/m‡ Air1010231-01 B2-SSVP-6 Acetone TO-15 5.8 J ug/m‡ Air1010231-01 B2-SSVP-6 Carbon disulfide TO-15 3.5 ug/m‡ Air1010231-01 B2-SSVP-6 Dichlorodifluoromethane TO-15 6.9 ug/m‡ Air1010231-01 B2-SSVP-6 Isopropyl alcohol TO-15 2.0 J ug/m‡ Air1010231-01 B2-SSVP-6 m,p-Xylenes TO-15 4.6 ug/m‡ Air1010231-01 B2-SSVP-6 Methyl Butyl Ketone (2-Hexanone)TO-15 3.2 ug/m‡ Air1010231-01 B2-SSVP-6 Methyl Ethyl Ketone (2-Butanone)TO-15 4.8 ug/m‡ Air1010231-01 B2-SSVP-6 Methyl Isobutyl Ketone TO-15 3.9 ug/m‡ Air1010231-01 B2-SSVP-6 Methylene Chloride TO-15 0.91 J ug/m‡ Air1010231-01 B2-SSVP-6 Tetrahydrofuran TO-15 1.0 J ug/m‡ Air1010231-01 B2-SSVP-6 Toluene TO-15 2.0 J ug/m‡ Air1010231-01 B2-SSVP-6 Trichlorofluoromethane TO-15 68 ug/m‡ Air1010231-02 B2-SSVP-7 Acetone TO-15 0.64 J ug/m‡ Air1010231-02 B2-SSVP-7 Benzene TO-15 3.2 ug/m‡ Air1010231-02 B2-SSVP-7 Dichlorodifluoromethane TO-15 2.5 ug/m‡ Air1010231-02 B2-SSVP-7 Hexane TO-15 11 ug/m‡ Air1010231-02 B2-SSVP-7 Isopropyl alcohol TO-15 2.4 J ug/m‡ Air1010231-02 B2-SSVP-7 m,p-Xylenes TO-15 4.5 ug/m‡ Air1010231-02 B2-SSVP-7 Methyl Butyl Ketone (2-Hexanone)TO-15 2.5 ug/m‡ Air1010231-02 B2-SSVP-7 Methyl Ethyl Ketone (2-Butanone)TO-15 4.7 ug/m‡ Air1010231-02 B2-SSVP-7 Methyl Isobutyl Ketone TO-15 8.7 ug/m‡ Air1010231-02 B2-SSVP-7 Methylene Chloride TO-15 6.4 ug/m‡ Air1010231-02 B2-SSVP-7 Naphthalene TO-15 0.94 J ug/m‡ Air1010231-02 B2-SSVP-7 Tetrahydrofuran TO-15 2.1 ug/m‡ Air1010231-02 B2-SSVP-7 Toluene TO-15 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 3 of 11 Laboratory Report 01/15/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: ATL-001 Former Rite AidHart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: B2-SSVP-6 Sample ID: 1010231-01 Work Order: 1010231 Time Collected: 01/14/21 15:16 Time Submitted: 01/14/21 16:14 Volatile Organic Compounds by GC/MS TO-15 P1A065812.7 1/15/21 12:26 CBMug/m‡ Air 0.291,1,1-Trichloroethane BDL TO-15 P1A065813.4 1/15/21 12:26 CBMug/m‡ Air 0.281,1,2,2-Tetrachloroethane BDL TO-15 P1A065813.8 1/15/21 12:26 CBMug/m‡ Air 0.531,1,2-Trichloro-1,2,2-trifluoroethane BDL TO-15 P1A065812.7 1/15/21 12:26 CBMug/m‡ Air 0.351,1,2-Trichloroethane BDL TO-15 P1A065812.0 1/15/21 12:26 CBMug/m‡ Air 0.471,1-Dichloroethane BDL TO-15 P1A065812.0 1/15/21 12:26 CBMug/m‡ Air 0.411,1-Dichloroethylene BDL TO-15 P1A065813.7 1/15/21 12:26 CBMug/m‡ Air 0.251,2,4-Trichlorobenzene BDL TO-15 P1A065812.5 1/15/21 12:26 CBMug/m‡ Air 0.291,2,4-Trimethylbenzene BDL TO-15 P1A065813.8 1/15/21 12:26 CBMug/m‡ Air 0.611,2-Dibromoethane BDL TO-15 P1A065813.0 1/15/21 12:26 CBMug/m‡ Air 0.481,2-Dichlorobenzene BDL TO-15 P1A065812.0 1/15/21 12:26 CBMug/m‡ Air 0.221,2-Dichloroethane BDL TO-15 P1A065812.3 1/15/21 12:26 CBMug/m‡ Air 0.401,2-Dichloropropane BDL TO-15 P1A065813.5 1/15/21 12:26 CBMug/m‡ Air 0.621,2-Dichloro-1,1,2,2-tetrafluoroethane BDL TO-15 P1A065812.5 1/15/21 12:26 CBMug/m‡ Air 0.261,3,5-Trimethylbenzene BDL TO-15 P1A065811.1 1/15/21 12:26 CBMug/m‡ Air 0.191,3-Butadiene BDL TO-15 P1A065813.0 1/15/21 12:26 CBMug/m‡ Air 0.211,3-Dichlorobenzene BDL TO-15 P1A065813.0 1/15/21 12:26 CBMug/m‡ Air 0.251,4-Dichlorobenzene BDL TO-15 P1A065811.8 1/15/21 12:26 CBMug/m‡ Air 0.101,4-Dioxane BDL TO-15 P1A065812.5 1/15/21 12:26 CBMug/m‡ Air 0.264-Ethyltoluene BDL TO-15 P1A065812.4 1/15/21 12:26 CBMug/m‡ Air 0.59Acetone45 TO-15 P1A065811.6 1/15/21 12:26 CBMug/m‡ Air 0.16BenzeneBDL TO-15 P1A065812.6 1/15/21 12:26 CBMug/m‡ Air 0.20Benzyl chloride BDL TO-15 P1A065813.4 1/15/21 12:26 CBMug/m‡ Air 0.26BromodichloromethaneBDL TO-15 P1A065815.2 1/15/21 12:26 CBMug/m‡ Air 0.45BromoformBDL TO-15 P1A065811.9 1/15/21 12:26 CBMug/m‡ Air 0.32BromomethaneBDL TO-15 P1A065816.2 1/15/21 12:26 CBMJug/m‡ Air 1.6Carbon disulfide 5.8 TO-15 P1A065813.1 1/15/21 12:26 CBMug/m‡ Air 0.24Carbon Tetrachloride BDL TO-15 P1A065812.3 1/15/21 12:26 CBMug/m‡ Air 0.17ChlorobenzeneBDL TO-15 P1A065811.3 1/15/21 12:26 CBMug/m‡ Air 0.38ChloroethaneBDL TO-15 P1A065812.4 1/15/21 12:26 CBMug/m‡ Air 0.26ChloroformBDL TO-15 P1A065811.0 1/15/21 12:26 CBMug/m‡ Air 0.26ChloromethaneBDL TO-15 P1A065812.0 1/15/21 12:26 CBMug/m‡ Air 0.52cis-1,2-Dichloroethylene BDL TO-15 P1A065812.3 1/15/21 12:26 CBMug/m‡ Air 0.16cis-1,3-Dichloropropylene BDL TO-15 P1A065813.4 1/15/21 12:26 CBMug/m‡ Air 0.87CyclohexaneBDL TO-15 P1A065814.3 1/15/21 12:26 CBMug/m‡ Air 0.48DibromochloromethaneBDL TO-15 P1A065812.5 1/15/21 12:26 CBMug/m‡ Air 0.41Dichlorodifluoromethane3.5 TO-15 P1A065811.8 1/15/21 12:26 CBMug/m‡ Air 0.25Ethyl Acetate BDL TO-15 P1A065812.2 1/15/21 12:26 CBMug/m‡ Air 0.19EthylbenzeneBDL TO-15 P1A065812.0 1/15/21 12:26 CBMug/m‡ Air 0.19HeptaneBDL TO-15 P1A065815.3 1/15/21 12:26 CBMug/m‡ Air 0.43HexachlorobutadieneBDL TO-15 P1A065811.8 1/15/21 12:26 CBMug/m‡ Air 0.25HexaneBDL TO-15 P1A065814.9 1/15/21 12:26 CBMug/m‡ Air 0.17Isopropyl alcohol 6.9 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 4 of 11 Laboratory Report 01/15/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: ATL-001 Former Rite AidHart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: B2-SSVP-6 Sample ID: 1010231-01 Work Order: 1010231 Time Collected: 01/14/21 15:16 Time Submitted: 01/14/21 16:14 TO-15 P1A065815.6 1/15/21 12:26 CBMJug/m‡ Air 0.38m,p-Xylenes 2.0 TO-15 P1A065812.0 1/15/21 12:26 CBMug/m‡ Air 0.26Methyl Butyl Ketone (2-Hexanone)4.6 TO-15 P1A065811.5 1/15/21 12:26 CBMug/m‡ Air 0.30Methyl Ethyl Ketone (2-Butanone)3.2 TO-15 P1A065812.0 1/15/21 12:26 CBMug/m‡ Air 0.26Methyl Isobutyl Ketone 4.8 TO-15 P1A065811.7 1/15/21 12:26 CBMug/m‡ Air 0.39Methylene Chloride 3.9 TO-15 P1A065811.8 1/15/21 12:26 CBMug/m‡ Air 0.21Methyl-tert-Butyl Ether BDL TO-15 P1A065812.6 1/15/21 12:26 CBMug/m‡ Air 1.0NaphthaleneBDL TO-15 P1A065812.2 1/15/21 12:26 CBMug/m‡ Air 0.18o-Xylene BDL TO-15 P1A065810.86 1/15/21 12:26 CBMug/m‡ Air 0.14PropyleneBDL TO-15 P1A065812.1 1/15/21 12:26 CBMug/m‡ Air 0.15StyreneBDL TO-15 P1A065813.4 1/15/21 12:26 CBMug/m‡ Air 0.44TetrachloroethyleneBDL TO-15 P1A065811.5 1/15/21 12:26 CBMJug/m‡ Air 0.21Tetrahydrofuran0.91 TO-15 P1A065811.9 1/15/21 12:26 CBMJug/m‡ Air 0.75Toluene1.0 TO-15 P1A065812.0 1/15/21 12:26 CBMug/m‡ Air 0.48trans-1,2-Dichloroethylene BDL TO-15 P1A065812.3 1/15/21 12:26 CBMug/m‡ Air 0.17trans-1,3-Dichloropropylene BDL TO-15 P1A065812.7 1/15/21 12:26 CBMug/m‡ Air 0.27TrichloroethyleneBDL TO-15 P1A065812.8 1/15/21 12:26 CBMJug/m‡ Air 0.43Trichlorofluoromethane2.0 TO-15 P1A065811.8 1/15/21 12:26 CBMug/m‡ Air 0.25Vinyl acetate BDL TO-15 P1A065811.3 1/15/21 12:26 CBMug/m‡ Air 0.29Vinyl chloride BDL Surrogate Recovery Control Limits 70-13087 %4-Bromofluorobenzene This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 5 of 11 Laboratory Report 01/15/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: ATL-001 Former Rite AidHart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: B2-SSVP-7 Sample ID: 1010231-02 Work Order: 1010231 Time Collected: 01/14/21 15:44 Time Submitted: 01/14/21 16:14 Volatile Organic Compounds by GC/MS TO-15 P1A065812.7 1/15/21 13:19 CBMug/m‡ Air 0.291,1,1-Trichloroethane BDL TO-15 P1A065813.4 1/15/21 13:19 CBMug/m‡ Air 0.281,1,2,2-Tetrachloroethane BDL TO-15 P1A065813.8 1/15/21 13:19 CBMug/m‡ Air 0.531,1,2-Trichloro-1,2,2-trifluoroethane BDL TO-15 P1A065812.7 1/15/21 13:19 CBMug/m‡ Air 0.351,1,2-Trichloroethane BDL TO-15 P1A065812.0 1/15/21 13:19 CBMug/m‡ Air 0.471,1-Dichloroethane BDL TO-15 P1A065812.0 1/15/21 13:19 CBMug/m‡ Air 0.411,1-Dichloroethylene BDL TO-15 P1A065813.7 1/15/21 13:19 CBMug/m‡ Air 0.251,2,4-Trichlorobenzene BDL TO-15 P1A065812.5 1/15/21 13:19 CBMug/m‡ Air 0.291,2,4-Trimethylbenzene BDL TO-15 P1A065813.8 1/15/21 13:19 CBMug/m‡ Air 0.611,2-Dibromoethane BDL TO-15 P1A065813.0 1/15/21 13:19 CBMug/m‡ Air 0.481,2-Dichlorobenzene BDL TO-15 P1A065812.0 1/15/21 13:19 CBMug/m‡ Air 0.221,2-Dichloroethane BDL TO-15 P1A065812.3 1/15/21 13:19 CBMug/m‡ Air 0.401,2-Dichloropropane BDL TO-15 P1A065813.5 1/15/21 13:19 CBMug/m‡ Air 0.621,2-Dichloro-1,1,2,2-tetrafluoroethane BDL TO-15 P1A065812.5 1/15/21 13:19 CBMug/m‡ Air 0.261,3,5-Trimethylbenzene BDL TO-15 P1A065811.1 1/15/21 13:19 CBMug/m‡ Air 0.191,3-Butadiene BDL TO-15 P1A065813.0 1/15/21 13:19 CBMug/m‡ Air 0.211,3-Dichlorobenzene BDL TO-15 P1A065813.0 1/15/21 13:19 CBMug/m‡ Air 0.251,4-Dichlorobenzene BDL TO-15 P1A065811.8 1/15/21 13:19 CBMug/m‡ Air 0.101,4-Dioxane BDL TO-15 P1A065812.5 1/15/21 13:19 CBMug/m‡ Air 0.264-Ethyltoluene BDL TO-15 P1A065820481/14/21 17:45 CBMug/m‡ Air 12Acetone68 TO-15 P1A065811.6 1/15/21 13:19 CBMJug/m‡ Air 0.16Benzene0.64 TO-15 P1A065812.6 1/15/21 13:19 CBMug/m‡ Air 0.20Benzyl chloride BDL TO-15 P1A065813.4 1/15/21 13:19 CBMug/m‡ Air 0.26BromodichloromethaneBDL TO-15 P1A065815.2 1/15/21 13:19 CBMug/m‡ Air 0.45BromoformBDL TO-15 P1A065811.9 1/15/21 13:19 CBMug/m‡ Air 0.32BromomethaneBDL TO-15 P1A065816.2 1/15/21 13:19 CBMug/m‡ Air 1.6Carbon disulfide BDL TO-15 P1A065813.1 1/15/21 13:19 CBMug/m‡ Air 0.24Carbon Tetrachloride BDL TO-15 P1A065812.3 1/15/21 13:19 CBMug/m‡ Air 0.17ChlorobenzeneBDL TO-15 P1A065811.3 1/15/21 13:19 CBMug/m‡ Air 0.38ChloroethaneBDL TO-15 P1A065812.4 1/15/21 13:19 CBMug/m‡ Air 0.26ChloroformBDL TO-15 P1A065811.0 1/15/21 13:19 CBMug/m‡ Air 0.26ChloromethaneBDL TO-15 P1A065812.0 1/15/21 13:19 CBMug/m‡ Air 0.52cis-1,2-Dichloroethylene BDL TO-15 P1A065812.3 1/15/21 13:19 CBMug/m‡ Air 0.16cis-1,3-Dichloropropylene BDL TO-15 P1A065813.4 1/15/21 13:19 CBMug/m‡ Air 0.87CyclohexaneBDL TO-15 P1A065814.3 1/15/21 13:19 CBMug/m‡ Air 0.48DibromochloromethaneBDL TO-15 P1A065812.5 1/15/21 13:19 CBMug/m‡ Air 0.41Dichlorodifluoromethane3.2 TO-15 P1A065811.8 1/15/21 13:19 CBMug/m‡ Air 0.25Ethyl Acetate BDL TO-15 P1A065812.2 1/15/21 13:19 CBMug/m‡ Air 0.19EthylbenzeneBDL TO-15 P1A065812.0 1/15/21 13:19 CBMug/m‡ Air 0.19HeptaneBDL TO-15 P1A065815.3 1/15/21 13:19 CBMug/m‡ Air 0.43HexachlorobutadieneBDL TO-15 P1A065811.8 1/15/21 13:19 CBMug/m‡ Air 0.25Hexane2.5 TO-15 P1A065814.9 1/15/21 13:19 CBMug/m‡ Air 0.17Isopropyl alcohol 11 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 6 of 11 Laboratory Report 01/15/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: ATL-001 Former Rite AidHart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: B2-SSVP-7 Sample ID: 1010231-02 Work Order: 1010231 Time Collected: 01/14/21 15:44 Time Submitted: 01/14/21 16:14 TO-15 P1A065815.6 1/15/21 13:19 CBMJug/m‡ Air 0.38m,p-Xylenes 2.4 TO-15 P1A065812.0 1/15/21 13:19 CBMug/m‡ Air 0.26Methyl Butyl Ketone (2-Hexanone)4.5 TO-15 P1A065811.5 1/15/21 13:19 CBMug/m‡ Air 0.30Methyl Ethyl Ketone (2-Butanone)2.5 TO-15 P1A065812.0 1/15/21 13:19 CBMug/m‡ Air 0.26Methyl Isobutyl Ketone 4.7 TO-15 P1A065811.7 1/15/21 13:19 CBMug/m‡ Air 0.39Methylene Chloride 8.7 TO-15 P1A065811.8 1/15/21 13:19 CBMug/m‡ Air 0.21Methyl-tert-Butyl Ether BDL TO-15 P1A065812.6 1/15/21 13:19 CBMug/m‡ Air 1.0Naphthalene6.4 TO-15 P1A065812.2 1/15/21 13:19 CBMug/m‡ Air 0.18o-Xylene BDL TO-15 P1A065810.86 1/15/21 13:19 CBMug/m‡ Air 0.14PropyleneBDL TO-15 P1A065812.1 1/15/21 13:19 CBMug/m‡ Air 0.15StyreneBDL TO-15 P1A065813.4 1/15/21 13:19 CBMug/m‡ Air 0.44TetrachloroethyleneBDL TO-15 P1A065811.5 1/15/21 13:19 CBMJug/m‡ Air 0.21Tetrahydrofuran0.94 TO-15 P1A065811.9 1/15/21 13:19 CBMug/m‡ Air 0.75Toluene2.1 TO-15 P1A065812.0 1/15/21 13:19 CBMug/m‡ Air 0.48trans-1,2-Dichloroethylene BDL TO-15 P1A065812.3 1/15/21 13:19 CBMug/m‡ Air 0.17trans-1,3-Dichloropropylene BDL TO-15 P1A065812.7 1/15/21 13:19 CBMug/m‡ Air 0.27TrichloroethyleneBDL TO-15 P1A065812.8 1/15/21 13:19 CBMug/m‡ Air 0.43TrichlorofluoromethaneBDL TO-15 P1A065811.8 1/15/21 13:19 CBMug/m‡ Air 0.25Vinyl acetate BDL TO-15 P1A065811.3 1/15/21 13:19 CBMug/m‡ Air 0.29Vinyl chloride BDL Surrogate Recovery Control Limits 70-13085 %4-Bromofluorobenzene This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 7 of 11 1/15/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: ATL-001 Former Rite AidHart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 1010231 Time Submitted: 1/14/2021 4:14:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control Batch P1A0658 - NO PREP VOA Blank (P1A0658-BLK1)Prepared & Analyzed: 01/15/21 1,1,1-Trichloroethane ug/m‡ AirBRL2.7 1,1,2,2-Tetrachloroethane ug/m‡ AirBRL3.4 1,1,2-Trichloro-1,2,2-trifluoroethane ug/m‡ AirBRL3.8 1,1,2-Trichloroethane ug/m‡ AirBRL2.7 1,1-Dichloroethane ug/m‡ AirBRL2.0 1,1-Dichloroethylene ug/m‡ AirBRL2.0 1,2,4-Trichlorobenzene ug/m‡ AirBRL3.7 1,2,4-Trimethylbenzene ug/m‡ AirBRL2.5 1,2-Dibromoethane ug/m‡ AirBRL3.8 1,2-Dichlorobenzene ug/m‡ AirBRL3.0 1,2-Dichloroethane ug/m‡ AirBRL2.0 1,2-Dichloropropane ug/m‡ AirBRL2.3 1,2-Dichloro-1,1,2,2-tetrafluoroethane ug/m‡ AirBRL3.5 1,3,5-Trimethylbenzene ug/m‡ AirBRL2.5 1,3-Butadiene ug/m‡ AirBRL1.1 1,3-Dichlorobenzene ug/m‡ AirBRL3.0 1,4-Dichlorobenzene ug/m‡ AirBRL3.0 1,4-Dioxane ug/m‡ AirBRL1.8 4-Ethyltoluene ug/m‡ AirBRL2.5 Acetone ug/m‡ AirBRL2.4 Benzene ug/m‡ AirBRL1.6 Benzyl chloride ug/m‡ AirBRL2.6 Bromodichloromethane ug/m‡ AirBRL3.4 Bromoform ug/m‡ AirBRL5.2 Bromomethane ug/m‡ AirBRL1.9 Carbon disulfide ug/m‡ AirBRL6.2 Carbon Tetrachloride ug/m‡ AirBRL3.1 Chlorobenzene ug/m‡ AirBRL2.3 Chloroethane ug/m‡ AirBRL1.3 Chloroform ug/m‡ AirBRL2.4 Chloromethane ug/m‡ AirBRL1.0 cis-1,2-Dichloroethylene ug/m‡ AirBRL2.0 cis-1,3-Dichloropropylene ug/m‡ AirBRL2.3 Cyclohexane ug/m‡ AirBRL3.4 Dibromochloromethane ug/m‡ AirBRL4.3 Dichlorodifluoromethane ug/m‡ AirBRL2.5 Ethyl Acetate ug/m‡ AirBRL1.8 Ethylbenzene ug/m‡ AirBRL2.2 Heptane ug/m‡ AirBRL2.0 Hexachlorobutadiene ug/m‡ AirBRL5.3 Hexane ug/m‡ AirBRL1.8 Isopropyl alcohol ug/m‡ AirBRL4.9 m,p-Xylenes ug/m‡ AirBRL5.6 Methyl Butyl Ketone (2-Hexanone)ug/m‡ AirBRL2.0 Methyl Ethyl Ketone (2-Butanone)ug/m‡ AirBRL1.5 Methyl Isobutyl Ketone ug/m‡ AirBRL2.0 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 8 of 11 1/15/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: ATL-001 Former Rite AidHart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 1010231 Time Submitted: 1/14/2021 4:14:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control Batch P1A0658 - NO PREP VOA Blank (P1A0658-BLK1)Prepared & Analyzed: 01/15/21 Methylene Chloride ug/m‡ AirBRL1.7 Methyl-tert-Butyl Ether ug/m‡ AirBRL1.8 Naphthalene ug/m‡ AirBRL2.6 o-Xylene ug/m‡ AirBRL2.2 Propylene ug/m‡ AirBRL0.86 Styrene ug/m‡ AirBRL2.1 Tetrachloroethylene ug/m‡ AirBRL3.4 Tetrahydrofuran ug/m‡ AirBRL1.5 Toluene ug/m‡ AirBRL1.9 trans-1,2-Dichloroethylene ug/m‡ AirBRL2.0 trans-1,3-Dichloropropylene ug/m‡ AirBRL2.3 Trichloroethylene ug/m‡ AirBRL2.7 Trichlorofluoromethane ug/m‡ AirBRL2.8 Vinyl acetate ug/m‡ AirBRL1.8 Vinyl chloride ug/m‡ AirBRL1.3 ppbv 5.000 70-130Surrogate: 4-Bromofluorobenzene 904.49 LCS (P1A0658-BS1)Prepared & Analyzed: 01/15/21 1,1,1-Trichloroethane ug/m‡ Air28.6 2.7 27.28 70-130105 1,1,2,2-Tetrachloroethane ug/m‡ Air36.7 3.4 34.33 70-130107 1,1,2-Trichloro-1,2,2-trifluoroethane ug/m‡ Air42.2 3.8 38.32 70-130110 1,1,2-Trichloroethane ug/m‡ Air30.4 2.7 27.28 70-130111 1,1-Dichloroethane ug/m‡ Air22.3 2.0 20.24 70-130110 1,1-Dichloroethylene ug/m‡ Air22.5 2.0 19.82 70-130113 1,2,4-Trichlorobenzene ug/m‡ Air42.3 3.7 37.11 70-130114 1,2,4-Trimethylbenzene ug/m‡ Air24.8 2.5 24.58 70-130101 1,2-Dibromoethane ug/m‡ Air43.6 3.8 38.42 70-130113 1,2-Dichlorobenzene ug/m‡ Air34.0 3.0 30.06 70-130113 1,2-Dichloroethane ug/m‡ Air21.7 2.0 20.24 70-130107 1,2-Dichloropropane ug/m‡ Air24.9 2.3 23.11 70-130108 1,2-Dichloro-1,1,2,2-tetrafluoroethane ug/m‡ Air34.8 3.5 34.95 70-130100 1,3,5-Trimethylbenzene ug/m‡ Air26.9 2.5 24.58 70-130110 1,3-Butadiene ug/m‡ Air12.6 1.1 11.06 70-130114 1,3-Dichlorobenzene ug/m‡ Air33.4 3.0 30.06 70-130111 1,4-Dichlorobenzene ug/m‡ Air32.2 3.0 30.06 70-130107 1,4-Dioxane ug/m‡ Air20.0 1.8 18.02 70-130111 4-Ethyltoluene ug/m‡ Air24.9 2.5 24.58 70-130101 Acetone ug/m‡ Air12.6 2.4 11.88 70-130106 Benzene ug/m‡ Air17.3 1.6 15.97 70-130108 Benzyl chloride ug/m‡ Air30.5 2.6 25.89 70-130118 Bromodichloromethane ug/m‡ Air36.4 3.4 33.50 70-130109 Bromoform ug/m‡ Air57.6 5.2 51.69 70-130111 Bromomethane ug/m‡ Air21.4 1.9 19.42 70-130110 Carbon disulfide ug/m‡ Air17.7 6.2 15.57 70-130113 Carbon Tetrachloride ug/m‡ Air34.2 3.1 31.46 70-130109 Chlorobenzene ug/m‡ Air25.9 2.3 23.02 70-130113 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 9 of 11 1/15/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: ATL-001 Former Rite AidHart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 1010231 Time Submitted: 1/14/2021 4:14:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control Batch P1A0658 - NO PREP VOA LCS (P1A0658-BS1)Prepared & Analyzed: 01/15/21 Chloroethane ug/m‡ Air14.5 1.3 13.19 70-130110 Chloroform ug/m‡ Air26.6 2.4 24.41 70-130109 Chloromethane ug/m‡ Air11.1 1.0 10.33 70-130108 cis-1,2-Dichloroethylene ug/m‡ Air21.9 2.0 19.82 70-130110 cis-1,3-Dichloropropylene ug/m‡ Air25.1 2.3 22.69 70-130111 Cyclohexane ug/m‡ Air16.6 3.4 17.21 70-13097 Dibromochloromethane ug/m‡ Air47.5 4.3 42.60 70-130111 Dichlorodifluoromethane ug/m‡ Air27.0 2.5 24.73 70-130109 Ethyl Acetate ug/m‡ Air19.7 1.8 18.02 70-130110 Ethylbenzene ug/m‡ Air24.5 2.2 21.71 70-130113 Heptane ug/m‡ Air23.4 2.0 20.49 70-130114 Hexachlorobutadiene ug/m‡ Air64.8 5.3 53.33 70-130122 Hexane ug/m‡ Air19.6 1.8 17.62 70-130111 Isopropyl alcohol ug/m‡ Air12.8 4.9 12.29 70-130104 m,p-Xylenes ug/m‡ Air67.6 5.6 56.49 70-130120 Methyl Butyl Ketone (2-Hexanone)ug/m‡ Air23.4 2.0 20.48 70-130114 Methyl Ethyl Ketone (2-Butanone)ug/m‡ Air16.1 1.5 14.75 70-130109 Methyl Isobutyl Ketone ug/m‡ Air21.6 2.0 20.48 70-130106 Methylene Chloride ug/m‡ Air18.9 1.7 17.37 70-130109 Methyl-tert-Butyl Ether ug/m‡ Air18.9 1.8 18.03 70-130105 Naphthalene ug/m‡ Air30.8 2.6 26.21 64-136118 o-Xylene ug/m‡ Air25.2 2.2 21.71 70-130116 Propylene ug/m‡ Air9.26 0.86 8.605 70-130108 Styrene ug/m‡ Air21.1 2.1 21.30 70-13099 Tetrachloroethylene ug/m‡ Air37.4 3.4 33.91 70-130110 Tetrahydrofuran ug/m‡ Air15.6 1.5 14.75 70-130106 Toluene ug/m‡ Air20.7 1.9 18.84 70-130110 trans-1,2-Dichloroethylene ug/m‡ Air21.7 2.0 19.82 70-130109 trans-1,3-Dichloropropylene ug/m‡ Air25.1 2.3 22.69 70-130111 Trichloroethylene ug/m‡ Air29.1 2.7 26.87 70-130108 Trichlorofluoromethane ug/m‡ Air31.3 2.8 28.09 70-130111 Vinyl acetate ug/m‡ Air19.4 1.8 17.61 70-130110 Vinyl chloride ug/m‡ Air14.1 1.3 12.78 70-130110 ppbv 5.000 70-130Surrogate: 4-Bromofluorobenzene 1055.26 Sample Extraction Data Prep Method: NO PREP VOA Lab Number Batch Date/TimeInitialFinal P1A06581010231-01 01/15/21 9:00250 250mL mL P1A06581010231-02 01/14/21 17:00250 250mL mL P1A06581010231-02 01/14/21 17:00250 250mL mL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 10 of 11 Page 11 of 11 Appendix C Risk Calculator Summary Pages Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 1/28/2021 Prepared By:Sean Horgan Hart & Hickman SGP-1 North Carolina Department of Environmental Quality Risk Calculator Rite Aid Brownfields Site 1730 Statesville Avenue Brownfields 20050-16-060 July 2020 May 2020 EPA RSL Table North Carolina DEQ Risk Calculator Table of Contents Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SGP-1 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SGP-1 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2020 Basis: May 2020 EPA RSL TableSite ID: 20050-16-060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual)1.0E-06 Target Cancer Risk (cumulative)1.0E-04 Target Hazard Index (individual)2.0E-01 Target Hazard Index (cumulative)1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg)15 Exposure Duration (ED) (yr)6 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day)200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d)0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)20 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)25 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Working Weeks (EW) (wk/yr)50 Exposure Duration (ED) (yr)1 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day)330 1 70 80 330 1 250 8 3527 0.3 50 100 19652 2.5 0.71 1 20 350 24 6032 0.07 0.54 1 70 80 2373 0.2 200 6365 0.78 Input Form 1B Exposure Unit ID: SGP-1 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2020 Basis: May 2020 EPA RSL TableSite ID: 20050-16-060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: SGP-1 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr)365 NA 365 Body Weight (BW) (kg)15 NA 15 Exposure Duration 0-2 (ED) (yr)2 NA 2 Exposure Duration 2-6 (ED) (yr)4 NA 4 Exposure Frequency (EF) (d/yr)195 NA 195 Exposure Time (ET) (hr)2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day)200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr)0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day)100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr)0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SGP-1 Description of Exposure Point Concentration Selection: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 7.4 67-64-1 Acetone ug/m3 5.1 100-44-7 Benzyl Chloride ug/m3 12 75-27-4 Bromodichloromethane ug/m3 10 75-15-0 Carbon Disulfide ug/m3 70 67-66-3 Chloroform ug/m3 4 110-82-7 Cyclohexane ug/m3 2.1 124-48-1 Dibromochloromethane ug/m3 1.3 106-46-7 Dichlorobenzene, 1,4-ug/m3 4.1 75-71-8 Dichlorodifluoromethane ug/m3 1 109-99-9 ~Tetrahydrofuran ug/m3 4.2 67-63-0 Isopropanol ug/m3 0.97 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 10 75-09-2 Methylene Chloride ug/m3 4.3 100-42-5 Styrene ug/m3 28 127-18-4 Tetrachloroethylene ug/m3 1.8 108-88-3 Toluene ug/m3 6.3 75-69-4 Trichlorofluoromethane ug/m3 5.1 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 1.8 108-38-3 Xylene, m-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Concentrations provided are those detected in the SGP-1 sample. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SGP-1 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 2.5E-05 1.9E-01 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.9E-06 1.5E-02 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SGP-1 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 7.4 0.222 -6.5E+03 6.9E-06 100-44-7 Benzyl Chloride 5.1 0.153 5.7E-02 2.1E-01 2.7E-06 1.5E-01 75-27-4 Bromodichloromethane 12 0.36 7.6E-02 -4.7E-06 75-15-0 Carbon Disulfide 10 0.3 -1.5E+02 4.1E-04 67-66-3 Chloroform 70 2.1 1.2E-01 2.0E+01 1.7E-05 2.1E-02 110-82-7 Cyclohexane 4 0.12 -1.3E+03 1.9E-05 124-48-1 Dibromochloromethane 2.1 0.063 -- 106-46-7 Dichlorobenzene, 1,4-1.3 0.039 2.6E-01 1.7E+02 1.5E-07 4.7E-05 75-71-8 Dichlorodifluoromethane 4.1 0.123 -2.1E+01 1.2E-03 109-99-9 ~Tetrahydrofuran 1 0.03 -4.2E+02 1.4E-05 67-63-0 Isopropanol 4.2 0.126 -4.2E+01 6.0E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)0.97 0.0291 -1.0E+03 5.6E-06 75-09-2 Methylene Chloride 10 0.3 1.0E+02 1.3E+02 3.0E-09 4.8E-04 100-42-5 Styrene 4.3 0.129 -2.1E+02 1.2E-04 127-18-4 Tetrachloroethylene 28 0.84 1.1E+01 8.3E+00 7.8E-08 2.0E-02 108-88-3 Toluene 1.8 0.054 -1.0E+03 1.0E-05 75-69-4 Trichlorofluoromethane 6.3 0.189 -- 95-63-6 Trimethylbenzene, 1,2,4-5.1 0.153 -1.3E+01 2.4E-03 108-38-3 Xylene, m-1.8 0.054 -2.1E+01 5.2E-04 Cumulative:2.5E-05 1.9E-01 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SGP-1 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 7.4 0.074 -2.7E+04 5.4E-07100-44-7 Benzyl Chloride 5.1 0.051 2.5E-01 8.8E-01 2.0E-07 1.2E-0275-27-4 Bromodichloromethane 12 0.12 3.3E-01 -3.6E-0775-15-0 Carbon Disulfide 10 0.1 -6.1E+02 3.3E-0567-66-3 Chloroform 70 0.7 5.3E-01 8.6E+01 1.3E-06 1.6E-03110-82-7 Cyclohexane 4 0.04 -5.3E+03 1.5E-06124-48-1 Dibromochloromethane 2.1 0.021 --106-46-7 Dichlorobenzene, 1,4-1.3 0.013 1.1E+00 7.0E+02 1.2E-08 3.7E-0675-71-8 Dichlorodifluoromethane 4.1 0.041 -8.8E+01 9.4E-05109-99-9 ~Tetrahydrofuran 1 0.01 -1.8E+03 1.1E-0667-63-0 Isopropanol 4.2 0.042 -1.8E+02 4.8E-05 78-93-3 Methyl Ethyl Ketone (2-Butanone)0.97 0.0097 -4.4E+03 4.4E-07 75-09-2 Methylene Chloride 10 0.1 1.2E+03 5.3E+02 8.2E-11 3.8E-05100-42-5 Styrene 4.3 0.043 -8.8E+02 9.8E-06127-18-4 Tetrachloroethylene 28 0.28 4.7E+01 3.5E+01 5.9E-09 1.6E-03108-88-3 Toluene 1.8 0.018 -4.4E+03 8.2E-0775-69-4 Trichlorofluoromethane 6.3 0.063 --95-63-6 Trimethylbenzene, 1,2,4-5.1 0.051 -5.3E+01 1.9E-04108-38-3 Xylene, m-1.8 0.018 -8.8E+01 4.1E-05 Cumulative:1.9E-06 1.5E-02 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 1/28/2021 Prepared By:Sean Horgan Hart & Hickman SSVP-1 North Carolina Department of Environmental Quality Risk Calculator Rite Aid Brownfields Site 1730 Statesville Avenue, Charlotte, North Carolina Brownfields 20050-16-060 July 2020 May 2020 EPA RSL Table North Carolina DEQ Risk Calculator Table of Contents Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-1 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-1 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2020 Basis: May 2020 EPA RSL TableSite ID: 20050-16-060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual)1.0E-06 Target Cancer Risk (cumulative)1.0E-04 Target Hazard Index (individual)2.0E-01 Target Hazard Index (cumulative)1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg)15 Exposure Duration (ED) (yr)6 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day)200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d)0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)20 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)25 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Working Weeks (EW) (wk/yr)50 Exposure Duration (ED) (yr)1 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day)330 1 70 80 330 1 250 8 3527 0.3 50 100 19652 2.5 0.71 1 20 350 24 6032 0.07 0.54 1 70 80 2373 0.2 200 6365 0.78 Input Form 1B Exposure Unit ID: SSVP-1 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2020 Basis: May 2020 EPA RSL TableSite ID: 20050-16-060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: SSVP-1 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr)365 NA 365 Body Weight (BW) (kg)15 NA 15 Exposure Duration 0-2 (ED) (yr)2 NA 2 Exposure Duration 2-6 (ED) (yr)4 NA 4 Exposure Frequency (EF) (d/yr)195 NA 195 Exposure Time (ET) (hr)2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day)200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr)0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day)100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr)0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-1 Description of Exposure Point Concentration Selection: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 16 67-64-1 Acetone ug/m3 2.9 75-15-0 Carbon Disulfide ug/m3 1.9 110-82-7 Cyclohexane ug/m3 3.2 75-71-8 Dichlorodifluoromethane ug/m3 1 123-91-1 Dioxane, 1,4-ug/m3 3.2 67-63-0 Isopropanol ug/m3 1.2 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 1.2 75-09-2 Methylene Chloride ug/m3 2.3 127-18-4 Tetrachloroethylene ug/m3 5.2 79-01-6 Trichloroethylene ug/m3 4.3 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Concentrations provided are those detected in the SSVP-1 sample. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-1 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 3.9E-07 8.1E-02 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 2.2E-08 6.4E-03 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-1 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 16 0.48 -6.5E+03 1.5E-05 75-15-0 Carbon Disulfide 2.9 0.087 -1.5E+02 1.2E-04 110-82-7 Cyclohexane 1.9 0.057 -1.3E+03 9.1E-06 75-71-8 Dichlorodifluoromethane 3.2 0.096 -2.1E+01 9.2E-04 123-91-1 Dioxane, 1,4-1 0.03 5.6E-01 6.3E+00 5.3E-08 9.6E-04 67-63-0 Isopropanol 3.2 0.096 -4.2E+01 4.6E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)1.2 0.036 -1.0E+03 6.9E-06 75-09-2 Methylene Chloride 1.2 0.036 1.0E+02 1.3E+02 3.6E-10 5.8E-05 127-18-4 Tetrachloroethylene 2.3 0.069 1.1E+01 8.3E+00 6.4E-09 1.7E-03 79-01-6 Trichloroethylene 5.2 0.156 4.8E-01 4.2E-01 3.3E-07 7.5E-02 95-63-6 Trimethylbenzene, 1,2,4-4.3 0.129 -1.3E+01 2.1E-03 Cumulative:3.9E-07 8.1E-02 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-1 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 16 0.16 -2.7E+04 1.2E-0675-15-0 Carbon Disulfide 2.9 0.029 -6.1E+02 9.5E-06110-82-7 Cyclohexane 1.9 0.019 -5.3E+03 7.2E-0775-71-8 Dichlorodifluoromethane 3.2 0.032 -8.8E+01 7.3E-05123-91-1 Dioxane, 1,4-1 0.01 2.5E+00 2.6E+01 4.1E-09 7.6E-0567-63-0 Isopropanol 3.2 0.032 -1.8E+02 3.7E-05 78-93-3 Methyl Ethyl Ketone (2-Butanone)1.2 0.012 -4.4E+03 5.5E-07 75-09-2 Methylene Chloride 1.2 0.012 1.2E+03 5.3E+02 9.8E-12 4.6E-06127-18-4 Tetrachloroethylene 2.3 0.023 4.7E+01 3.5E+01 4.9E-10 1.3E-0479-01-6 Trichloroethylene 5.2 0.052 3.0E+00 1.8E+00 1.7E-08 5.9E-0395-63-6 Trimethylbenzene, 1,2,4-4.3 0.043 -5.3E+01 1.6E-04 Cumulative:2.2E-08 6.4E-03 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: SSVP-2/SSVP-DUP North Carolina Department of Environmental Quality Risk Calculator Rite Aid Brownfields Site 1730 Statesville Avenue, Charlotte, North Carolina Brownfields 20050-16-060 July 2020 May 2020 EPA RSL Table 1/28/2021 Prepared By:Sean Horgan Hart & Hickman North Carolina DEQ Risk Calculator Table of Contents Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-2/SSVP-DUP Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-2/SSVP-DUP Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2020 Basis: May 2020 EPA RSL TableSite ID: 20050-16-060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual)1.0E-06 Target Cancer Risk (cumulative)1.0E-04 Target Hazard Index (individual)2.0E-01 Target Hazard Index (cumulative)1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg)15 Exposure Duration (ED) (yr)6 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day)200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d)0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)20 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)25 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Working Weeks (EW) (wk/yr)50 Exposure Duration (ED) (yr)1 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day)330 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 Input Form 1B Exposure Unit ID: SSVP-2/SSVP-DUP Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 2373 0.2 200 6365 0.78 0.54 1 70 80 20 350 24 6032 0.07 100 19652 2.5 0.71 1 1 70 80 330 1 250 8 3527 0.3 50 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2020 Basis: May 2020 EPA RSL TableSite ID: 20050-16-060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: SSVP-2/SSVP-DUP Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr)365 NA 365 Body Weight (BW) (kg)15 NA 15 Exposure Duration 0-2 (ED) (yr)2 NA 2 Exposure Duration 2-6 (ED) (yr)4 NA 4 Exposure Frequency (EF) (d/yr)195 NA 195 Exposure Time (ET) (hr)2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day)200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr)0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day)100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr)0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-2/SSVP-DUP Description of Exposure Point Concentration Selection: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 13 67-64-1 Acetone ug/m3 2.3 75-15-0 Carbon Disulfide ug/m3 2.2 110-82-7 Cyclohexane ug/m3 3.6 75-71-8 Dichlorodifluoromethane ug/m3 2 67-63-0 Isopropanol ug/m3 0.97 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 10 75-09-2 Methylene Chloride ug/m3 3.7 127-18-4 Tetrachloroethylene ug/m3 2.5 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-ug/m3 2.9 75-69-4 Trichlorofluoromethane ug/m3 4.4 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Concentrations provided are those detected in the maximum of the SSVP-2 and SSVP-DUP samples, which were each collected from the same location. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-2/SSVP-DUP Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.3E-08 6.7E-03 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 8.7E-10 5.3E-04 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-2/SSVP-DUP CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 13 0.39 -6.5E+03 1.2E-05 75-15-0 Carbon Disulfide 2.3 0.069 -1.5E+02 9.5E-05 110-82-7 Cyclohexane 2.2 0.066 -1.3E+03 1.1E-05 75-71-8 Dichlorodifluoromethane 3.6 0.108 -2.1E+01 1.0E-03 67-63-0 Isopropanol 2 0.06 -4.2E+01 2.9E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)0.97 0.0291 -1.0E+03 5.6E-06 75-09-2 Methylene Chloride 10 0.3 1.0E+02 1.3E+02 3.0E-09 4.8E-04 127-18-4 Tetrachloroethylene 3.7 0.111 1.1E+01 8.3E+00 1.0E-08 2.7E-03 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-2.5 0.075 -1.0E+03 1.4E-05 75-69-4 Trichlorofluoromethane 2.9 0.087 -- 95-63-6 Trimethylbenzene, 1,2,4-4.4 0.132 -1.3E+01 2.1E-03 Cumulative:1.3E-08 6.7E-03 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-2/SSVP-DUP CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 13 0.13 -2.7E+04 9.6E-0775-15-0 Carbon Disulfide 2.3 0.023 -6.1E+02 7.5E-06110-82-7 Cyclohexane 2.2 0.022 -5.3E+03 8.4E-0775-71-8 Dichlorodifluoromethane 3.6 0.036 -8.8E+01 8.2E-0567-63-0 Isopropanol 2 0.02 -1.8E+02 2.3E-05 78-93-3 Methyl Ethyl Ketone (2-Butanone)0.97 0.0097 -4.4E+03 4.4E-07 75-09-2 Methylene Chloride 10 0.1 1.2E+03 5.3E+02 8.2E-11 3.8E-05127-18-4 Tetrachloroethylene 3.7 0.037 4.7E+01 3.5E+01 7.8E-10 2.1E-0476-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-2.5 0.025 -4.4E+03 1.1E-0675-69-4 Trichlorofluoromethane 2.9 0.029 --95-63-6 Trimethylbenzene, 1,2,4-4.4 0.044 -5.3E+01 1.7E-04 Cumulative:8.7E-10 5.3E-04 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 1/28/2021 Prepared By:Sean Horgan Hart & Hickman SSVP-3 North Carolina Department of Environmental Quality Risk Calculator Rite Aid Brownfields Site 1730 Statesville Avenue, Charlotte, North Carolina Brownfields 20050-16-060 July 2020 May 2020 EPA RSL Table North Carolina DEQ Risk Calculator Table of Contents Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-3 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-3 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2020 Basis: May 2020 EPA RSL TableSite ID: 20050-16-060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual)1.0E-06 Target Cancer Risk (cumulative)1.0E-04 Target Hazard Index (individual)2.0E-01 Target Hazard Index (cumulative)1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg)15 Exposure Duration (ED) (yr)6 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day)200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d)0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)20 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)25 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Working Weeks (EW) (wk/yr)50 Exposure Duration (ED) (yr)1 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day)330 1 70 80 330 1 250 8 3527 0.3 50 100 19652 2.5 0.71 1 20 350 24 6032 0.07 0.54 1 70 80 2373 0.2 200 6365 0.78 Input Form 1B Exposure Unit ID: SSVP-3 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2020 Basis: May 2020 EPA RSL TableSite ID: 20050-16-060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: SSVP-3 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr)365 NA 365 Body Weight (BW) (kg)15 NA 15 Exposure Duration 0-2 (ED) (yr)2 NA 2 Exposure Duration 2-6 (ED) (yr)4 NA 4 Exposure Frequency (EF) (d/yr)195 NA 195 Exposure Time (ET) (hr)2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day)200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr)0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day)100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr)0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-3 Description of Exposure Point Concentration Selection: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 18 67-64-1 Acetone ug/m3 3 110-82-7 Cyclohexane ug/m3 3.3 75-71-8 Dichlorodifluoromethane ug/m3 0.86 123-91-1 Dioxane, 1,4-ug/m3 3.2 67-63-0 Isopropanol ug/m3 1.5 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 9.7 75-09-2 Methylene Chloride ug/m3 4.4 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 1.1 108-38-3 Xylene, m-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Concentrations provided are those detected in the SSVP-3 sample North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-3 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 4.9E-08 5.2E-03 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 3.6E-09 4.1E-04 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-3 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 18 0.54 -6.5E+03 1.7E-05 110-82-7 Cyclohexane 3 0.09 -1.3E+03 1.4E-05 75-71-8 Dichlorodifluoromethane 3.3 0.099 -2.1E+01 9.5E-04 123-91-1 Dioxane, 1,4-0.86 0.0258 5.6E-01 6.3E+00 4.6E-08 8.2E-04 67-63-0 Isopropanol 3.2 0.096 -4.2E+01 4.6E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)1.5 0.045 -1.0E+03 8.6E-06 75-09-2 Methylene Chloride 9.7 0.291 1.0E+02 1.3E+02 2.9E-09 4.7E-04 95-63-6 Trimethylbenzene, 1,2,4-4.4 0.132 -1.3E+01 2.1E-03 108-38-3 Xylene, m-1.1 0.033 -2.1E+01 3.2E-04 Cumulative:4.9E-08 5.2E-03 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-3 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 18 0.18 -2.7E+04 1.3E-06110-82-7 Cyclohexane 3 0.03 -5.3E+03 1.1E-0675-71-8 Dichlorodifluoromethane 3.3 0.033 -8.8E+01 7.5E-05123-91-1 Dioxane, 1,4-0.86 0.0086 2.5E+00 2.6E+01 3.5E-09 6.5E-0567-63-0 Isopropanol 3.2 0.032 -1.8E+02 3.7E-05 78-93-3 Methyl Ethyl Ketone (2-Butanone)1.5 0.015 -4.4E+03 6.8E-07 75-09-2 Methylene Chloride 9.7 0.097 1.2E+03 5.3E+02 7.9E-11 3.7E-0595-63-6 Trimethylbenzene, 1,2,4-4.4 0.044 -5.3E+01 1.7E-04108-38-3 Xylene, m-1.1 0.011 -8.8E+01 2.5E-05 Cumulative:3.6E-09 4.1E-04 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: SSVP-4 North Carolina Department of Environmental Quality Risk Calculator Rite Aid Brownfields Site 1730 Statesville Avenue, Charlotte, North Carolina Brownfields 20050-16-060 July 2020 May 2020 EPA RSL Table 1/28/2021 Prepared By:Sean Horgan Hart & Hickman North Carolina DEQ Risk Calculator Table of Contents Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-4 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-4 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2020 Basis: May 2020 EPA RSL TableSite ID: 20050-16-060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual)1.0E-06 Target Cancer Risk (cumulative)1.0E-04 Target Hazard Index (individual)2.0E-01 Target Hazard Index (cumulative)1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg)15 Exposure Duration (ED) (yr)6 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day)200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d)0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)20 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)25 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Working Weeks (EW) (wk/yr)50 Exposure Duration (ED) (yr)1 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day)330 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 Input Form 1B Exposure Unit ID: SSVP-4 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 2373 0.2 200 6365 0.78 0.54 1 70 80 20 350 24 6032 0.07 100 19652 2.5 0.71 1 1 70 80 330 1 250 8 3527 0.3 50 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2020 Basis: May 2020 EPA RSL TableSite ID: 20050-16-060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: SSVP-4 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr)365 NA 365 Body Weight (BW) (kg)15 NA 15 Exposure Duration 0-2 (ED) (yr)2 NA 2 Exposure Duration 2-6 (ED) (yr)4 NA 4 Exposure Frequency (EF) (d/yr)195 NA 195 Exposure Time (ET) (hr)2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day)200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr)0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day)100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr)0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-4 Description of Exposure Point Concentration Selection: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 44 67-64-1 Acetone ug/m3 4 110-82-7 Cyclohexane ug/m3 3.6 75-71-8 Dichlorodifluoromethane ug/m3 3.6 75-35-4 Dichloroethylene, 1,1-ug/m3 3.7 156-60-5 Dichloroethylene, 1,2-trans-ug/m3 3 67-63-0 Isopropanol ug/m3 1.3 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 11 75-09-2 Methylene Chloride ug/m3 3.1 127-18-4 Tetrachloroethylene ug/m3 0.83 108-88-3 Toluene ug/m3 1.9 75-69-4 Trichlorofluoromethane ug/m3 4.3 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Concentrations provided are those detected in the SSVP-4 sample North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-4 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.2E-08 6.9E-03 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 7.5E-10 5.5E-04 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-4 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 44 1.32 -6.5E+03 4.1E-05 110-82-7 Cyclohexane 4 0.12 -1.3E+03 1.9E-05 75-71-8 Dichlorodifluoromethane 3.6 0.108 -2.1E+01 1.0E-03 75-35-4 Dichloroethylene, 1,1-3.6 0.108 -4.2E+01 5.2E-04 156-60-5 Dichloroethylene, 1,2-trans-3.7 0.111 -- 67-63-0 Isopropanol 3 0.09 -4.2E+01 4.3E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)1.3 0.039 -1.0E+03 7.5E-06 75-09-2 Methylene Chloride 11 0.33 1.0E+02 1.3E+02 3.3E-09 5.3E-04 127-18-4 Tetrachloroethylene 3.1 0.093 1.1E+01 8.3E+00 8.6E-09 2.2E-03 108-88-3 Toluene 0.83 0.0249 -1.0E+03 4.8E-06 75-69-4 Trichlorofluoromethane 1.9 0.057 -- 95-63-6 Trimethylbenzene, 1,2,4-4.3 0.129 -1.3E+01 2.1E-03 Cumulative:1.2E-08 6.9E-03 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-4 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 44 0.44 -2.7E+04 3.2E-06110-82-7 Cyclohexane 4 0.04 -5.3E+03 1.5E-0675-71-8 Dichlorodifluoromethane 3.6 0.036 -8.8E+01 8.2E-0575-35-4 Dichloroethylene, 1,1-3.6 0.036 -1.8E+02 4.1E-05156-60-5 Dichloroethylene, 1,2-trans-3.7 0.037 --67-63-0 Isopropanol 3 0.03 -1.8E+02 3.4E-05 78-93-3 Methyl Ethyl Ketone (2-Butanone)1.3 0.013 -4.4E+03 5.9E-07 75-09-2 Methylene Chloride 11 0.11 1.2E+03 5.3E+02 9.0E-11 4.2E-05127-18-4 Tetrachloroethylene 3.1 0.031 4.7E+01 3.5E+01 6.6E-10 1.8E-04108-88-3 Toluene 0.83 0.0083 -4.4E+03 3.8E-0775-69-4 Trichlorofluoromethane 1.9 0.019 --95-63-6 Trimethylbenzene, 1,2,4-4.3 0.043 -5.3E+01 1.6E-04 Cumulative:7.5E-10 5.5E-04 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 1/28/2021 Prepared By:Sean Horgan Hart & Hickman SSVP-5 North Carolina Department of Environmental Quality Risk Calculator Rite Aid Brownfields Site 1730 Statesville Avenue, Charlotte, North Carolina Brownfields 20050-16-060 July 2020 May 2020 EPA RSL Table North Carolina DEQ Risk Calculator Table of Contents Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-5 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-5 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2020 Basis: May 2020 EPA RSL TableSite ID: 20050-16-060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual)1.0E-06 Target Cancer Risk (cumulative)1.0E-04 Target Hazard Index (individual)2.0E-01 Target Hazard Index (cumulative)1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg)15 Exposure Duration (ED) (yr)6 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day)200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d)0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)20 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)25 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Working Weeks (EW) (wk/yr)50 Exposure Duration (ED) (yr)1 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day)330 1 70 80 330 1 250 8 3527 0.3 50 100 19652 2.5 0.71 1 20 350 24 6032 0.07 0.54 1 70 80 2373 0.2 200 6365 0.78 Input Form 1B Exposure Unit ID: SSVP-5 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2020 Basis: May 2020 EPA RSL TableSite ID: 20050-16-060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: SSVP-5 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr)365 NA 365 Body Weight (BW) (kg)15 NA 15 Exposure Duration 0-2 (ED) (yr)2 NA 2 Exposure Duration 2-6 (ED) (yr)4 NA 4 Exposure Frequency (EF) (d/yr)195 NA 195 Exposure Time (ET) (hr)2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day)200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr)0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day)100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr)0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-5 Description of Exposure Point Concentration Selection: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 49 67-64-1 Acetone ug/m3 3.2 110-82-7 Cyclohexane ug/m3 3.6 75-71-8 Dichlorodifluoromethane ug/m3 2.7 67-63-0 Isopropanol ug/m3 1.3 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 12 75-09-2 Methylene Chloride ug/m3 3.1 127-18-4 Tetrachloroethylene ug/m3 2 75-69-4 Trichlorofluoromethane ug/m3 4.3 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Concentrations provided are those detected in the SSVP-5 sample North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-5 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.2E-08 6.4E-03 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 7.6E-10 5.0E-04 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-5 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 49 1.47 -6.5E+03 4.5E-05 110-82-7 Cyclohexane 3.2 0.096 -1.3E+03 1.5E-05 75-71-8 Dichlorodifluoromethane 3.6 0.108 -2.1E+01 1.0E-03 67-63-0 Isopropanol 2.7 0.081 -4.2E+01 3.9E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)1.3 0.039 -1.0E+03 7.5E-06 75-09-2 Methylene Chloride 12 0.36 1.0E+02 1.3E+02 3.6E-09 5.8E-04 127-18-4 Tetrachloroethylene 3.1 0.093 1.1E+01 8.3E+00 8.6E-09 2.2E-03 75-69-4 Trichlorofluoromethane 2 0.06 -- 95-63-6 Trimethylbenzene, 1,2,4-4.3 0.129 -1.3E+01 2.1E-03 Cumulative:1.2E-08 6.4E-03 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-5 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 49 0.49 -2.7E+04 3.6E-06110-82-7 Cyclohexane 3.2 0.032 -5.3E+03 1.2E-0675-71-8 Dichlorodifluoromethane 3.6 0.036 -8.8E+01 8.2E-0567-63-0 Isopropanol 2.7 0.027 -1.8E+02 3.1E-05 78-93-3 Methyl Ethyl Ketone (2-Butanone)1.3 0.013 -4.4E+03 5.9E-07 75-09-2 Methylene Chloride 12 0.12 1.2E+03 5.3E+02 9.8E-11 4.6E-05127-18-4 Tetrachloroethylene 3.1 0.031 4.7E+01 3.5E+01 6.6E-10 1.8E-0475-69-4 Trichlorofluoromethane 2 0.02 --95-63-6 Trimethylbenzene, 1,2,4-4.3 0.043 -5.3E+01 1.6E-04 Cumulative:7.6E-10 5.0E-04 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 1/28/2021 Prepared By:Sean Horgan Hart & Hickman SSVP-6 North Carolina Department of Environmental Quality Risk Calculator Rite Aid Brownfields Site 1730 Statesville Avenue, Charlotte, North Carolina Brownfields 20050-16-060 July 2020 May 2020 EPA RSL Table North Carolina DEQ Risk Calculator Table of Contents Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-6 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-6 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2020 Basis: May 2020 EPA RSL TableSite ID: 20050-16-060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual)1.0E-06 Target Cancer Risk (cumulative)1.0E-04 Target Hazard Index (individual)2.0E-01 Target Hazard Index (cumulative)1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg)15 Exposure Duration (ED) (yr)6 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day)200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d)0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)20 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)25 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Working Weeks (EW) (wk/yr)50 Exposure Duration (ED) (yr)1 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day)330 1 70 80 330 1 250 8 3527 0.3 50 100 19652 2.5 0.71 1 20 350 24 6032 0.07 0.54 1 70 80 2373 0.2 200 6365 0.78 Input Form 1B Exposure Unit ID: SSVP-6 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2020 Basis: May 2020 EPA RSL TableSite ID: 20050-16-060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: SSVP-6 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr)365 NA 365 Body Weight (BW) (kg)15 NA 15 Exposure Duration 0-2 (ED) (yr)2 NA 2 Exposure Duration 2-6 (ED) (yr)4 NA 4 Exposure Frequency (EF) (d/yr)195 NA 195 Exposure Time (ET) (hr)2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day)200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr)0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day)100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr)0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-6 Description of Exposure Point Concentration Selection: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 45 67-64-1 Acetone ug/m3 5.8 75-15-0 Carbon Disulfide ug/m3 3.5 75-71-8 Dichlorodifluoromethane ug/m3 0.91 109-99-9 ~Tetrahydrofuran ug/m3 4.6 591-78-6 Hexanone, 2-ug/m3 6.9 67-63-0 Isopropanol ug/m3 3.2 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 4.8 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 3.9 75-09-2 Methylene Chloride ug/m3 1 108-88-3 Toluene ug/m3 2 75-69-4 Trichlorofluoromethane ug/m3 2 108-38-3 Xylene, m-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Concentrations provided are those detected in the SSVP-6 sample North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-6 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.2E-09 7.5E-03 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 3.2E-11 6.0E-04 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-6 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 45 1.35 -6.5E+03 4.2E-05 75-15-0 Carbon Disulfide 5.8 0.174 -1.5E+02 2.4E-04 75-71-8 Dichlorodifluoromethane 3.5 0.105 -2.1E+01 1.0E-03 109-99-9 ~Tetrahydrofuran 0.91 0.0273 -4.2E+02 1.3E-05 591-78-6 Hexanone, 2-4.6 0.138 -6.3E+00 4.4E-03 67-63-0 Isopropanol 6.9 0.207 -4.2E+01 9.9E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)3.2 0.096 -1.0E+03 1.8E-05 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)4.8 0.144 -6.3E+02 4.6E-05 75-09-2 Methylene Chloride 3.9 0.117 1.0E+02 1.3E+02 1.2E-09 1.9E-04 108-88-3 Toluene 1 0.03 -1.0E+03 5.8E-06 75-69-4 Trichlorofluoromethane 2 0.06 -- 108-38-3 Xylene, m-2 0.06 -2.1E+01 5.8E-04 Cumulative:1.2E-09 7.5E-03 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-6 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 45 0.45 -2.7E+04 3.3E-0675-15-0 Carbon Disulfide 5.8 0.058 -6.1E+02 1.9E-0575-71-8 Dichlorodifluoromethane 3.5 0.035 -8.8E+01 8.0E-05109-99-9 ~Tetrahydrofuran 0.91 0.0091 -1.8E+03 1.0E-06591-78-6 Hexanone, 2-4.6 0.046 -2.6E+01 3.5E-0467-63-0 Isopropanol 6.9 0.069 -1.8E+02 7.9E-05 78-93-3 Methyl Ethyl Ketone (2-Butanone)3.2 0.032 -4.4E+03 1.5E-06 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)4.8 0.048 -2.6E+03 3.7E-0675-09-2 Methylene Chloride 3.9 0.039 1.2E+03 5.3E+02 3.2E-11 1.5E-05108-88-3 Toluene 1 0.01 -4.4E+03 4.6E-0775-69-4 Trichlorofluoromethane 2 0.02 --108-38-3 Xylene, m-2 0.02 -8.8E+01 4.6E-05 Cumulative:3.2E-11 6.0E-04 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: SSVP-7 North Carolina Department of Environmental Quality Risk Calculator Rite Aid Brownfields Site 1730 Statesville Avenue, Charlotte, North Carolina Brownfields 20050-16-060 July 2020 May 2020 EPA RSL Table 1/28/2021 Prepared By:Sean Horgan Hart & Hickman North Carolina DEQ Risk Calculator Table of Contents Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-7 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-7 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2020 Basis: May 2020 EPA RSL TableSite ID: 20050-16-060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual)1.0E-06 Target Cancer Risk (cumulative)1.0E-04 Target Hazard Index (individual)2.0E-01 Target Hazard Index (cumulative)1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg)15 Exposure Duration (ED) (yr)6 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day)200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d)0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)20 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)25 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Working Weeks (EW) (wk/yr)50 Exposure Duration (ED) (yr)1 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day)330 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 Input Form 1B Exposure Unit ID: SSVP-7 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 2373 0.2 200 6365 0.78 0.54 1 70 80 20 350 24 6032 0.07 100 19652 2.5 0.71 1 1 70 80 330 1 250 8 3527 0.3 50 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2020 Basis: May 2020 EPA RSL TableSite ID: 20050-16-060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: SSVP-7 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr)365 NA 365 Body Weight (BW) (kg)15 NA 15 Exposure Duration 0-2 (ED) (yr)2 NA 2 Exposure Duration 2-6 (ED) (yr)4 NA 4 Exposure Frequency (EF) (d/yr)195 NA 195 Exposure Time (ET) (hr)2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day)200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr)0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day)100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr)0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-7 Description of Exposure Point Concentration Selection: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 68 67-64-1 Acetone ug/m3 0.64 71-43-2 Benzene ug/m3 3.2 75-71-8 Dichlorodifluoromethane ug/m3 0.94 109-99-9 ~Tetrahydrofuran ug/m3 2.5 110-54-3 Hexane, N-ug/m3 4.5 591-78-6 Hexanone, 2-ug/m3 11 67-63-0 Isopropanol ug/m3 2.5 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 4.7 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 8.7 75-09-2 Methylene Chloride ug/m3 6.4 91-20-3 ~Naphthalene ug/m3 2.1 108-88-3 Toluene ug/m3 2.4 108-38-3 Xylene, m-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Concentrations provided are those detected in the SSVP-7 sample North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-7 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 2.4E-06 7.0E-02 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.8E-07 5.6E-03 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-7 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 68 2.04 -6.5E+03 6.3E-05 71-43-2 Benzene 0.64 0.0192 3.6E-01 6.3E+00 5.3E-08 6.1E-04 75-71-8 Dichlorodifluoromethane 3.2 0.096 -2.1E+01 9.2E-04 109-99-9 ~Tetrahydrofuran 0.94 0.0282 -4.2E+02 1.4E-05 110-54-3 Hexane, N-2.5 0.075 -1.5E+02 1.0E-04 591-78-6 Hexanone, 2-4.5 0.135 -6.3E+00 4.3E-03 67-63-0 Isopropanol 11 0.33 -4.2E+01 1.6E-03 78-93-3 Methyl Ethyl Ketone (2-Butanone)2.5 0.075 -1.0E+03 1.4E-05 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)4.7 0.141 -6.3E+02 4.5E-05 75-09-2 Methylene Chloride 8.7 0.261 1.0E+02 1.3E+02 2.6E-09 4.2E-04 91-20-3 ~Naphthalene 6.4 0.192 8.3E-02 6.3E-01 2.3E-06 6.1E-02 108-88-3 Toluene 2.1 0.063 -1.0E+03 1.2E-05 108-38-3 Xylene, m-2.4 0.072 -2.1E+01 6.9E-04 Cumulative:2.4E-06 7.0E-02 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: SSVP-7 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 68 0.68 -2.7E+04 5.0E-0671-43-2 Benzene 0.64 0.0064 1.6E+00 2.6E+01 4.1E-09 4.9E-0575-71-8 Dichlorodifluoromethane 3.2 0.032 -8.8E+01 7.3E-05109-99-9 ~Tetrahydrofuran 0.94 0.0094 -1.8E+03 1.1E-06110-54-3 Hexane, N-2.5 0.025 -6.1E+02 8.2E-06591-78-6 Hexanone, 2-4.5 0.045 -2.6E+01 3.4E-0467-63-0 Isopropanol 11 0.11 -1.8E+02 1.3E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)2.5 0.025 -4.4E+03 1.1E-06 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)4.7 0.047 -2.6E+03 3.6E-0675-09-2 Methylene Chloride 8.7 0.087 1.2E+03 5.3E+02 7.1E-11 3.3E-0591-20-3 ~Naphthalene 6.4 0.064 3.6E-01 2.6E+00 1.8E-07 4.9E-03108-88-3 Toluene 2.1 0.021 -4.4E+03 9.6E-07108-38-3 Xylene, m-2.4 0.024 -8.8E+01 5.5E-05 Cumulative:1.8E-07 5.6E-03 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Site-Wide Worst Case for Future Commercial Use North Carolina Department of Environmental Quality Risk Calculator Rite Aid Brownfields Site 1730 Statesville Avenue, Charlotte, North Carolina Brownfields 20050-16-060 July 2020 May 2020 EPA RSL Table 1/28/2021 Prepared By:Sean Horgan Hart & Hickman North Carolina DEQ Risk Calculator Table of Contents Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: Site-Wide Worst Case for Future Commercial Use Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: Site-Wide Worst Case for Future Commercial Use Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2020 Basis: May 2020 EPA RSL TableSite ID: 20050-16-060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual)1.0E-06 Target Cancer Risk (cumulative)1.0E-04 Target Hazard Index (individual)2.0E-01 Target Hazard Index (cumulative)1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg)15 Exposure Duration (ED) (yr)6 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day)200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d)0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)20 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)25 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Working Weeks (EW) (wk/yr)50 Exposure Duration (ED) (yr)1 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day)330 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 Input Form 1B Exposure Unit ID: Site-Wide Worst Case for Future Commercial Use Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 2373 0.2 200 6365 0.78 0.54 1 70 80 20 350 24 6032 0.07 100 19652 2.5 0.71 1 1 70 80 330 1 250 8 3527 0.3 50 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2020 Basis: May 2020 EPA RSL TableSite ID: 20050-16-060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: Site-Wide Worst Case for Future Commercial Use Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr)365 NA 365 Body Weight (BW) (kg)15 NA 15 Exposure Duration 0-2 (ED) (yr)2 NA 2 Exposure Duration 2-6 (ED) (yr)4 NA 4 Exposure Frequency (EF) (d/yr)195 NA 195 Exposure Time (ET) (hr)2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day)200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr)0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day)100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr)0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: Site-Wide Worst Case for Future Commercial Use Description of Exposure Point Concentration Selection: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 68 67-64-1 Acetone ug/m3 0.64 71-43-2 Benzene ug/m3 5.8 75-15-0 Carbon Disulfide ug/m3 3 110-82-7 Cyclohexane ug/m3 3.6 75-71-8 Dichlorodifluoromethane ug/m3 1 123-91-1 Dioxane, 1,4-ug/m3 0.94 109-99-9 ~Tetrahydrofuran ug/m3 2.5 110-54-3 Hexane, N-ug/m3 4.6 591-78-6 Hexanone, 2-ug/m3 11 67-63-0 Isopropanol ug/m3 3.2 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 4.8 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 10 75-09-2 Methylene Chloride ug/m3 6.4 91-20-3 ~Naphthalene ug/m3 3.7 127-18-4 Tetrachloroethylene ug/m3 2.1 108-88-3 Toluene ug/m3 2.5 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-ug/m3 5.2 79-01-6 Trichloroethylene ug/m3 2.9 75-69-4 Trichlorofluoromethane ug/m3 4.4 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 2.4 108-38-3 Xylene, m-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Concentrations provided are the maximum detections between each sub-slab soil vapor sample collected in an area subject to future commercial use. These include: SSVP-1, SSVP-2, SSVP-3, SSVP-6, and SSVP-7. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: Site-Wide Worst Case for Future Commercial Use Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 2.8E-06 1.5E-01 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 2.0E-07 1.2E-02 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: Site-Wide Worst Case for Future Commercial Use CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 68 2.04 -6.5E+03 6.3E-05 71-43-2 Benzene 0.64 0.0192 3.6E-01 6.3E+00 5.3E-08 6.1E-04 75-15-0 Carbon Disulfide 5.8 0.174 -1.5E+02 2.4E-04 110-82-7 Cyclohexane 3 0.09 -1.3E+03 1.4E-05 75-71-8 Dichlorodifluoromethane 3.6 0.108 -2.1E+01 1.0E-03 123-91-1 Dioxane, 1,4-1 0.03 5.6E-01 6.3E+00 5.3E-08 9.6E-04 109-99-9 ~Tetrahydrofuran 0.94 0.0282 -4.2E+02 1.4E-05 110-54-3 Hexane, N-2.5 0.075 -1.5E+02 1.0E-04 591-78-6 Hexanone, 2-4.6 0.138 -6.3E+00 4.4E-03 67-63-0 Isopropanol 11 0.33 -4.2E+01 1.6E-03 78-93-3 Methyl Ethyl Ketone (2-Butanone)3.2 0.096 -1.0E+03 1.8E-05 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)4.8 0.144 -6.3E+02 4.6E-05 75-09-2 Methylene Chloride 10 0.3 1.0E+02 1.3E+02 3.0E-09 4.8E-04 91-20-3 ~Naphthalene 6.4 0.192 8.3E-02 6.3E-01 2.3E-06 6.1E-02 127-18-4 Tetrachloroethylene 3.7 0.111 1.1E+01 8.3E+00 1.0E-08 2.7E-03 108-88-3 Toluene 2.1 0.063 -1.0E+03 1.2E-05 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-2.5 0.075 -1.0E+03 1.4E-05 79-01-6 Trichloroethylene 5.2 0.156 4.8E-01 4.2E-01 3.3E-07 7.5E-02 75-69-4 Trichlorofluoromethane 2.9 0.087 -- 95-63-6 Trimethylbenzene, 1,2,4-4.4 0.132 -1.3E+01 2.1E-03 108-38-3 Xylene, m-2.4 0.072 -2.1E+01 6.9E-04 Cumulative:2.8E-06 1.5E-01 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: Site-Wide Worst Case for Future Commercial Use CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 68 0.68 -2.7E+04 5.0E-0671-43-2 Benzene 0.64 0.0064 1.6E+00 2.6E+01 4.1E-09 4.9E-0575-15-0 Carbon Disulfide 5.8 0.058 -6.1E+02 1.9E-05110-82-7 Cyclohexane 3 0.03 -5.3E+03 1.1E-0675-71-8 Dichlorodifluoromethane 3.6 0.036 -8.8E+01 8.2E-05123-91-1 Dioxane, 1,4-1 0.01 2.5E+00 2.6E+01 4.1E-09 7.6E-05109-99-9 ~Tetrahydrofuran 0.94 0.0094 -1.8E+03 1.1E-06110-54-3 Hexane, N-2.5 0.025 -6.1E+02 8.2E-06591-78-6 Hexanone, 2-4.6 0.046 -2.6E+01 3.5E-0467-63-0 Isopropanol 11 0.11 -1.8E+02 1.3E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)3.2 0.032 -4.4E+03 1.5E-06 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)4.8 0.048 -2.6E+03 3.7E-0675-09-2 Methylene Chloride 10 0.1 1.2E+03 5.3E+02 8.2E-11 3.8E-0591-20-3 ~Naphthalene 6.4 0.064 3.6E-01 2.6E+00 1.8E-07 4.9E-03127-18-4 Tetrachloroethylene 3.7 0.037 4.7E+01 3.5E+01 7.8E-10 2.1E-04108-88-3 Toluene 2.1 0.021 -4.4E+03 9.6E-0776-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-2.5 0.025 -4.4E+03 1.1E-0679-01-6 Trichloroethylene 5.2 0.052 3.0E+00 1.8E+00 1.7E-08 5.9E-0375-69-4 Trichlorofluoromethane 2.9 0.029 --95-63-6 Trimethylbenzene, 1,2,4-4.4 0.044 -5.3E+01 1.7E-04108-38-3 Xylene, m-2.4 0.024 -8.8E+01 5.5E-05 Cumulative:2.0E-07 1.2E-02 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Site-Wide Worst Case for Future Residential Use North Carolina Department of Environmental Quality Risk Calculator Rite Aid Brownfields Site 1730 Statesville Avenue, Charlotte, North Carolina Brownfields 20050-16-060 July 2020 May 2020 EPA RSL Table 1/28/2021 Prepared By:Sean Horgan Hart & Hickman North Carolina DEQ Risk Calculator Table of Contents Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: Site-Wide Worst Case for Future Residential Use Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: Site-Wide Worst Case for Future Residential Use Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2020 Basis: May 2020 EPA RSL TableSite ID: 20050-16-060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual)1.0E-06 Target Cancer Risk (cumulative)1.0E-04 Target Hazard Index (individual)2.0E-01 Target Hazard Index (cumulative)1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg)15 Exposure Duration (ED) (yr)6 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day)200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d)0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)20 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)25 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Working Weeks (EW) (wk/yr)50 Exposure Duration (ED) (yr)1 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day)330 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 Input Form 1B Exposure Unit ID: Site-Wide Worst Case for Future Residential Use Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 2373 0.2 200 6365 0.78 0.54 1 70 80 20 350 24 6032 0.07 100 19652 2.5 0.71 1 1 70 80 330 1 250 8 3527 0.3 50 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: July 2020 Basis: May 2020 EPA RSL TableSite ID: 20050-16-060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: Site-Wide Worst Case for Future Residential Use Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr)365 NA 365 Body Weight (BW) (kg)15 NA 15 Exposure Duration 0-2 (ED) (yr)2 NA 2 Exposure Duration 2-6 (ED) (yr)4 NA 4 Exposure Frequency (EF) (d/yr)195 NA 195 Exposure Time (ET) (hr)2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day)200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr)0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day)100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr)0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: Site-Wide Worst Case for Future Residential Use Description of Exposure Point Concentration Selection: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 49 67-64-1 Acetone ug/m3 5.1 100-44-7 Benzyl Chloride ug/m3 12 75-27-4 Bromodichloromethane ug/m3 10 75-15-0 Carbon Disulfide ug/m3 70 67-66-3 Chloroform ug/m3 4 110-82-7 Cyclohexane ug/m3 2.1 124-48-1 Dibromochloromethane ug/m3 1.3 106-46-7 Dichlorobenzene, 1,4-ug/m3 4.1 75-71-8 Dichlorodifluoromethane ug/m3 3.6 75-35-4 Dichloroethylene, 1,1-ug/m3 3.7 156-60-5 Dichloroethylene, 1,2-trans-ug/m3 1 109-99-9 ~Tetrahydrofuran ug/m3 4.2 67-63-0 Isopropanol ug/m3 1.3 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 12 75-09-2 Methylene Chloride ug/m3 4.3 100-42-5 Styrene ug/m3 28 127-18-4 Tetrachloroethylene ug/m3 1.8 108-88-3 Toluene ug/m3 6.3 75-69-4 Trichlorofluoromethane ug/m3 5.1 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 1.8 108-38-3 Xylene, m-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Concentrations provided are the maximum detections between each sub-slab soil vapor sample collected in an area subject to future residential use. These include: SGP-1, SSVP-4, and SSVP-5. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: Site-Wide Worst Case for Future Residential Use Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 2.5E-05 1.9E-01 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.9E-06 1.5E-02 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: Site-Wide Worst Case for Future Residential Use CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 49 1.47 -6.5E+03 4.5E-05 100-44-7 Benzyl Chloride 5.1 0.153 5.7E-02 2.1E-01 2.7E-06 1.5E-01 75-27-4 Bromodichloromethane 12 0.36 7.6E-02 -4.7E-06 75-15-0 Carbon Disulfide 10 0.3 -1.5E+02 4.1E-04 67-66-3 Chloroform 70 2.1 1.2E-01 2.0E+01 1.7E-05 2.1E-02 110-82-7 Cyclohexane 4 0.12 -1.3E+03 1.9E-05 124-48-1 Dibromochloromethane 2.1 0.063 -- 106-46-7 Dichlorobenzene, 1,4-1.3 0.039 2.6E-01 1.7E+02 1.5E-07 4.7E-05 75-71-8 Dichlorodifluoromethane 4.1 0.123 -2.1E+01 1.2E-03 75-35-4 Dichloroethylene, 1,1-3.6 0.108 -4.2E+01 5.2E-04 156-60-5 Dichloroethylene, 1,2-trans-3.7 0.111 -- 109-99-9 ~Tetrahydrofuran 1 0.03 -4.2E+02 1.4E-05 67-63-0 Isopropanol 4.2 0.126 -4.2E+01 6.0E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)1.3 0.039 -1.0E+03 7.5E-06 75-09-2 Methylene Chloride 12 0.36 1.0E+02 1.3E+02 3.6E-09 5.8E-04 100-42-5 Styrene 4.3 0.129 -2.1E+02 1.2E-04 127-18-4 Tetrachloroethylene 28 0.84 1.1E+01 8.3E+00 7.8E-08 2.0E-02 108-88-3 Toluene 1.8 0.054 -1.0E+03 1.0E-05 75-69-4 Trichlorofluoromethane 6.3 0.189 -- 95-63-6 Trimethylbenzene, 1,2,4-5.1 0.153 -1.3E+01 2.4E-03 108-38-3 Xylene, m-1.8 0.054 -2.1E+01 5.2E-04 Cumulative:2.5E-05 1.9E-01 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: July 2020 Basis: May 2020 EPA RSL Table Site ID: 20050-16-060 Exposure Unit ID: Site-Wide Worst Case for Future Residential Use CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 49 0.49 -2.7E+04 3.6E-06100-44-7 Benzyl Chloride 5.1 0.051 2.5E-01 8.8E-01 2.0E-07 1.2E-0275-27-4 Bromodichloromethane 12 0.12 3.3E-01 -3.6E-0775-15-0 Carbon Disulfide 10 0.1 -6.1E+02 3.3E-0567-66-3 Chloroform 70 0.7 5.3E-01 8.6E+01 1.3E-06 1.6E-03110-82-7 Cyclohexane 4 0.04 -5.3E+03 1.5E-06124-48-1 Dibromochloromethane 2.1 0.021 --106-46-7 Dichlorobenzene, 1,4-1.3 0.013 1.1E+00 7.0E+02 1.2E-08 3.7E-0675-71-8 Dichlorodifluoromethane 4.1 0.041 -8.8E+01 9.4E-0575-35-4 Dichloroethylene, 1,1-3.6 0.036 -1.8E+02 4.1E-05156-60-5 Dichloroethylene, 1,2-trans-3.7 0.037 --109-99-9 ~Tetrahydrofuran 1 0.01 -1.8E+03 1.1E-0667-63-0 Isopropanol 4.2 0.042 -1.8E+02 4.8E-05 78-93-3 Methyl Ethyl Ketone (2-Butanone)1.3 0.013 -4.4E+03 5.9E-07 75-09-2 Methylene Chloride 12 0.12 1.2E+03 5.3E+02 9.8E-11 4.6E-05100-42-5 Styrene 4.3 0.043 -8.8E+02 9.8E-06127-18-4 Tetrachloroethylene 28 0.28 4.7E+01 3.5E+01 5.9E-09 1.6E-03108-88-3 Toluene 1.8 0.018 -4.4E+03 8.2E-0775-69-4 Trichlorofluoromethane 6.3 0.063 --95-63-6 Trimethylbenzene, 1,2,4-5.1 0.051 -5.3E+01 1.9E-04108-38-3 Xylene, m-1.8 0.018 -8.8E+01 4.1E-05 Cumulative:1.9E-06 1.5E-02 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator