Loading...
HomeMy WebLinkAbout23079_Northern Telecom_IA Assessment Rpt_20200612Mid Atlantic Engineering & Environmental Solutions June 12, 2020 Mr. Tyson Strutzenberg Trinity Capital Advisors 3020 Carrington Mill Boulevard #425 Morrisville, North Carolina 27560 Subject: INDOOR AIR ASSESSMENT REPORT NORTHERN TELECOM (PARK POINT) 4001 AND 4151 EAST NC HIGHWAY 54 DURHAM, DURHAM COUNTY, NORTH CAROLINA BROWNFIELDS PROJECT NO.: 23079-19-032 MID -ATLANTIC JOB NO. 00OR3358.01 MID -ATLANTIC PE LICENSE: F-0967 Dear Mr. Stutzenberg: 409 Rogers View CourE Raleigh, NC 276 10 office 919.250,9918 facsimile 919.250.9950 MAAONLINE.COM We are pleased to present this Indoor Air Assessment Report for the above -referenced site. We appreciate the opportunity to provide Trinity Capital Advisors with environmental services. Please contact me at 919-250-9918 if any questions arise or if we may be of further service. Sincerely, MID -ATLANTIC ASSOCIATES, INC. 4- d ��� Katie Lippard Senior Project Manager Darin McClure, P.E. Principal Engineer EXPERIENCE❑ CUSTOMER FOCUSED INNOVATIVE INDOOR AIR ASSESSMENT REPORT NORTHERN TELECOM (PARK POINT) 4001 AND 4151 EAST NC HIGHWAY 54 DURHAM, DURHAM COUNTY, NORTH CAROLINA Prepared For: Mr. Tyson Strutzenberg c/o Trinity Capital Advisors 3020 Carrington Mill Boulevard #425 Morrisville, North Carolina 27560 Prepared By: Mid -Atlantic Associates, Inc. 409 Rogers View Court Raleigh, North Carolina 27610 Mid -Atlantic Job No. OOOR3358.01 June 12, 2020 0 M i t Atlantic Mid Atlantic Engineering & Environmental Solutions 409 Rogers View Court Raleigh, NC 27610 office 919.250.9918 facsimile 919.250.9950 — MAAONLINE.COM INDOOR AIR ASSESSMENT REPORT NORTHERN TELECOM (PARK POINT) 4001 AND 4151 EAST NC HIGHWAY 54 DURHAM, DURHAM COUNTY, NORTH CAROLINA BROWNFIELDS PROJECT NUMBER 23079-19-032 Mid -Atlantic Associates Job No. 00OR3358.01 Prepared For: Mr. Tyson Strutzenberg Trinity Capital Advisors 3020 Carrington Mill Boulevard #425 Morrisville, North Carolina 27560 June 12, 2020 Prepared By: MID -ATLANTIC ASSOCIATES, INC. Z'L' Q 4x"e Katie A. Lippard Senior Project M Darin McClure: Principal Engine;* NCPE License No: EXPERIENCED CUSTOMER FOCUSED INNOVATIVE TABLE OF CONTENTS 1.0 GENERAL INFORMATION............................................................................................... 1 1.1 Introduction........................................................................................................... 1 1.2 Laboratory............................................................................................................ 1 2.0 SUMMARY OF FIELD ACTIVITIES.................................................................................. 1 3.0 SUMMARY OF LABORATORY ANALYTICAL RESULTS ............................................... 3 3.1 Indoor Air SamDlina Results................................................................................. 3 3.2 Risk Calculations..................................................................................................3 4.0 QUALITY ASSURANCE................................................................................................... 5 5.0 SUMMARY AND CONCLUSIONS.................................................................................... 5 DRAWINGS Drawing 1.1 Topographic Site Map Drawing 2.1 Sample Location Map TABLE Table 3.2 Summary of Chemical Constituents Detected in Indoor Air And Risk Calculations APPENDICES Appendix A Indoor Air Building Survey Appendix B Overall Site Plan Appendix C Photographic Log of Sample Locations Appendix D Laboratory Analytical Report and Chain -of -Custody Record for Indoor/Ambient Air Samples Appendix E Indoor Air and Ambient Air Risk Calculations (All Compounds) Appendix F Indoor Air and Ambient Air Risk Calculations (Minus Acrolein) Appendix G Sub -Slab Soil Gas Vapor Intrusion Risk Calculations (January 2017) 0 Mid Atlantic 1.0 GENERAL INFORMATION 1.1 Introduction The subject site is comprised of three parcels totaling 94.89 acres located within the Research Triangle Park (RTP) area of Durham, North Carolina (Drawing 1.1). As part of the redevelopment, the buildings located on the parcels are currently being renovated into a modern, multi -tenant campus that will accommodate technology, office and life science tenants. Minimal ground disturbance will be required as part of this redevelopment and will be limited to demolition of select site interiors and structures, asbestos -containing material (ACM) abatement, and landscape installation. Previous assessments conducted in January 2017 included the collection of six sub slab soil gas samples across the site. During recent discussions, a potential tenant requested indoor air testing in their proposed space (Building D/F). The potential tenant approved the scope of work consisting of the collection and analysis of four indoor air samples in Building D/F. This report details the May 2020 indoor air sampling activities conducted within the buildings on -site. The opinions included herein are based on our experience and the information obtained during the study. This report is based on limited observations made on the dates noted using the procedures described herein. If additional information becomes available, we request the opportunity to review the information, reassess the potential environmental concerns and modify our conclusions and recommendations, if appropriate. 1.2 Laboratory Enthalpy Analytical, LLC 800 Capitola Drive, Suite 1 Durham, North Carolina 27713 (919) 850-4392 Contact: Mr. David Myers 2.0 SUMMARY OF FIELD ACTIVITIES The scope of work conducted as part of this vapor assessment was conducted in general accordance with the field procedures outlined in the May 21, 2020 Indoor Air Assessment Work Plan prepared by Mid -Atlantic and submitted to the North Carolina Department of Environmental Quality (NCDEQ) Brownfields Program on May 21, 2020. On May 22, 2020, Mid -Atlantic conducted a site reconnaissance to evaluate conditions prior to the proposed indoor air sampling. The structure on -site is divided into three buildings with two areas per building, as shown on Drawing 2.1 and the Overall Site Plan provided in Appendix B. We noted significant demolition activities in Building A/B while demolition in Buildings C/E and D/F appeared mostly complete. We noted two 5-gallon buckets of hydraulic oil, one plastic paint remover container, one spray paint can, one metal cutting lubricant jug and one can of pipe dope within Buildings C/E and D/F. The concrete slab Mid Atlantic Indoor Air Assessment Report June 12, 2020 Northern Telecom (Park Point) Page 2 Durham, North Carolina observed in Buildings C/E and D/F appeared in good shape. Small, petroleum -fueled equipment was observed in Building C/E. We were informed that petroleum -fueled vehicles/equipment were/are used during demolition activities and that vehicles still traverse through Building D/F during demolition. We recommended that the chemicals observed be removed from the building, petroleum -fueled equipment be removed from the building, and demolition activities halted during sampling activities. Since there was no effective way to isolate Building D/F from other buildings, we recommended collecting two additional indoor air samples, one in Building A/E and one in Building C/E for quality control and data evaluation measures. Prior to setting the indoor air sampling cannisters on May 26, 2020, Mid -Atlantic conducted a site reconnaissance to document site conditions. The results of the survey are included in the Indoor Air Building Survey and Sampling Form (Appendix A). We were informed that the renovation and demolition activities were halted on May 21, 2020 and construction materials, chemicals, and petroleum fueled vehicles/equipment used during demolition activities were removed from Building D/F immediately prior to May 26, 2020. Upon arrival we observed all of the loading dock roll doors and exterior entrance doors of the buildings to be open. Prior to beginning the sampling event the doors were closed to simulate actual occupant conditions. An HVAC system is present, but it was not operational at the time of the sampling event. De minimis amounts of household cleaning supplies, a spray paint can, two open containers of pipe sealant, floor sanders, and fork lifts were observed within Building C/E. Piles of demolition debris and roped off areas were observed in Building A/B, specifically in Area B. Although present in the building, no petroleum fueled machinery was observed to be operating at the time of the sampling event. On May 26-27, 2020, Mid -Atlantic mobilized to the site to collect six indoor air samples, one duplicate indoor air sample, and one ambient outdoor air sample at the site. Indoor air samples IA-1 through IA-4 and the duplicate sample (Dup-1) were collected in Building D/F in the same manner and location as indicated in the May 21, 2020 Indoor Air Assessment Work Plan. In addition, sample IA-5 was collected in Building C/E and sample IA-6 was collected in Building A/B in Area B. The ambient outdoor air sample (OA-1) was collected outside, north of Building A/B. A photograph log depicting the conditions of the spaces during sampling can be found in Appendix C. The sample locations are shown on Drawing 2.1. The indoor air samples and duplicate sample were collected at least ten feet from the building entrances at a height of approximately four feet from the floor. The 24-hour air samples were collected using individually certified, 6-liter, stainless steel, Summa canisters at a maximum flow rate of 8-10 milliliters per minute (ml/min). The air samples were collected and delivered to Enthalpy Analytical, LLC (Enthalpy) in Durham, North Carolina. The samples were analyzed for volatile organic compounds (VOCs) using EPA Method TO-15. 0 Mid Atlantic Indoor Air Assessment Report June 12, 2020 Northern Telecom (Park Point) Page 3 Durham, North Carolina 3.0 SUMMARY OF LABORATORY ANALYTICAL RESULTS 3.1 Indoor Air Samplina Results The laboratory analytical report and chain -of -custody record for indoor air samples collected in May 2020 are provided in Appendix D and summarized in Table 3.1. The results of the indoor air sampling activities were initially compared to the February 2018 NCDEQ Residential and Non -Residential Vapor Intrusion Screening Levels (VISLs). Only three compounds (acrolein, carbon tetrachloride and naphthalene) were detected above one of their respective VISLs. As summarized, acrolein was detected in each of the indoor air samples, the duplicate, and the ambient outdoor air sample at concentrations exceeding the Residential and Non -Residential VISLs. The highest concentration of acrolein was detected in the sample collected furthest from the proposed tenant space (IA-6 in Building A/B). Naphthalene was detected in indoor air sample IA-6 (collected in Building A/B) at a concentration exceeding the Residential and Non -Residential VISLs and in sample IA-1 at a concentration exceeding the Non -Residential VISL. Carbon tetrachloride was detected in samples IA-1, IA-2, IA-4 through IA-6, Dup-1, and OA-1 at concentrations exceeding its Residential VISL. Twenty-six other VOCs were detected in each of the primary indoor air samples, the duplicate indoor air sample, and the ambient outdoor air sample at concentrations above laboratory method detection limits but below the Residential and Non -Residential VISLs. Additional discussion regarding risk calculations for the constituents detected in indoor air is provided below in Section 3.2. Acrolein, detected above its Residential and Non -Residential VISL in the indoor air and ambient outdoor air samples, is a non -carcinogen that is ubiquitous in the environment and can be a result of combustion of petroleum, tobacco smoke, pesticide application, and the cooking of food, among other things. As such it is not typically included in a TO-15 analyte list for vapor intrusion investigations. Based on its ubiquitous nature and the results of the pre -sampling inventory of site activities performed by Mid -Atlantic, we do not consider acrolein to be a contaminant associated with vapor intrusion at the site. From an occupational exposure standpoint, the highest concentration of acrolein detected in the indoor air samples (0.802 milligrams per cubic meter (ug/m3)) is well below the Occupational Health and Safety Administration (OSHA) permissible exposure limit (PEL) of 250 ug/m3 for acrolein. 3.2 Risk Calculations The NCDEQ establishes VISLs for individual compounds for both residential and non- residential worker (industrial/commercial) exposure scenarios. The North Carolina Brownfields Program allows a maximum cumulative cancer risk for all carcinogens of 1.0E- Mid Atlantic Indoor Air Assessment Report June 12, 2020 Northern Telecom (Park Point) Page 4 Durham, North Carolina 4 and a maximum cumulative hazard index (HI) of 1 for all non -carcinogens in indoor air. After comparing the indoor air sampling results to the NCDEQ Residential and Non - Residential VISLs, we then calculated the cancer risk and non -cancer risk hazard quotient using the highest concentration for each compound detected at the site that was above the laboratory reporting limit (Appendix E). The cumulative Residential and Non -Residential Worker exposure cancer risk sum and non -cancer hazard index for the indoor air is summarized in the following table: May 2020 Indoor Air Risk Calculations Non -Residential Non -Residential Residential Residential Worker Worker Cumulative Calculated Cumulative Non - Sample ID Calculated Non -Carcinogenic Carcinogenic Carcinogenic Carcinogenic Hazard Index Risk Sum Hazard Index Risk Sum Max Concentrations 2.6E-06 9.3E+00 1.1 E-05 3.9E+01 All Compounds) Max Concentrations 2.6E-06 1.5E-01 1.1 E-05 6.3E-01 Minus Acrolein As indicated, the cumulative non -carcinogenic hazard index for the indoor air exceeded the target cumulative non -cancer hazard index of 1 under residential and non-residential worker exposure scenarios. The Residential and Non -Residential Worker cumulative carcinogenic risk sums did not exceed the target sum of 1.0E-04. Acrolein, which was not included in the analyte list for the January 2017 sub -slab soil gas laboratory report, appears to be the primary compound that is elevating the non -carcinogenic hazard index to levels above the acceptable risk. As previously stated and according to the US National Library of Medicine, and National Institutes of Health, acrolein is ubiquitous in the environment and can be a result of combustion of petroleum, tobacco smoke, pesticide application, and the cooking of food, and is likely not a product of vapor intrusion. When risk calculations were conducted removing acrolein from the input, the cancer risk sum and cumulative non -cancer hazard index for indoor air did not exceed the target risk sum of 1.0E-4 or the target cumulative non -cancer hazard index of 1 for either the residential or non-residential worker exposure scenarios (Appendix F). The Residential and Non -Residential Worker cumulative cancer risk and cumulative non - cancer hazard index were also calculated for the January 2017 sub -slab soil gas data for comparison purposes. The risk was calculated using the highest detected concentration for each compound in the primary samples and duplicate sample (Appendix G). The Residential and Non -Residential Worker exposure cumulative cancer risk sum and cumulative non -cancer hazard index for the sub -slab soil gas are summarized in the following table: Q Mid Atlantic Indoor Air Assessment Report Northern Telecom (Park Point) Durham, North Carolina June 12, 2020 Page 5 January 2017 Soil Gas to Indoor Air Risk Calculations Non -Residential Non -Residential Residential Residential Worker Calculated Worker Calculated Cumulative Non - Exposure Unit Carcinogenic Cumulative Non- Carcinogenic Carcinogenic Risk Sum Carcinogenic Risk Sum Hazard Index Hazard Index Max 8.2E-07 3.9E-02 1.1 E-05 5.0E-01 Concentrations As indicated, the cumulative cancer risk sum and cumulative non -cancer hazard index for soil gas did not exceed the target risk sum of 1.0E-4, nor the target cumulative non -cancer hazard index of 1, for either the residential or non-residential worker exposure scenarios. 4.0 QUALITY ASSURANCE One duplicate indoor air sample was collected during sampling activities. The duplicate sample was analyzed by EPA Method TO-15 (Table 3.1). Mid -Atlantic filled each laboratory provided Summa canister such that the final vacuum in the canister was at least five inches of mercury. Summa canisters were shut off after 24-hours. The chain -of - custody was completed and packed with the samples. The Mid -Atlantic field technician delivered the samples to the Enthalpy laboratory located in Durham, NC. 5.0 SUMMARY AND CONCLUSIONS The objective of this assessment was to test the indoor air environment at the subject property. Mid -Atlantic offers the following summary of observations and conclusions based on the results of this assessment as they pertain to the subject site: • Only three compounds (acrolein, carbon tetrachloride and naphthalene) were detected in the indoor air above one of their respective VISLs. • The concentration of naphthalene was the highest in the sample collected in Building A/B (the building with active demolition activities), indicating that these activities may be contributing to the concentrations of naphthalene (and potentially other constituents) in the building. • Acrolein was detected in each indoor air sample and the ambient outdoor air sample at concentrations exceeding the Residential and Non -Residential VISL. • Acrolein is a non -carcinogenic, ubiquitous compound commonly found in the environment. In addition, major sources/activities associated with the presence of acrolein in air have occurred historically and/or recently at the site (combustion of ICI i t Atlantic Indoor Air Assessment Report Northern Telecom (Park Point) Durham, North Carolina June 12, 2020 Page 6 petroleum, pesticide application, etc.). As such, we do not consider acrolein a contaminant of concern as it pertains to vapor intrusion. Evaluating the vapor intrusion risk using the indoor air data (minus acrolein) results in acceptable risk for both Residential and Non -Residential Worker scenarios. The Residential and Non -Residential Worker cumulative non -cancer hazard indices and cancer risk sums for the indoor air samples and 2017 sub -slab soil gas samples are similar. The highest concentration of acrolein detected in the indoor air samples (0.802 ug/m3) is well below (0.32%) the OSHA PEL of 250 ug/m3 for acrolein. Based on the results of this investigation and data collected in 2017, vapor intrusion does not appear to be causing an unacceptable risk scenario at the site. The acrolein detected in the indoor air samples is present at concentrations well below the OSHA PEL. We would also anticipate that these levels will abate further once demolition/construction activities are complete and the spaces are conditioned consistent with their proposed use. Q Mid Atlantic DRAWINGS 10 Mid Atlantic a REFERENCES: 1. SOUTH EAST DURHAM, NC DIGITAL RASTER GRAPHICS, USGS. SCANNED FROM 1:24,000-SCALE DURHAM, NC TOPOGRAPHIC MAPS, PUBLISHED 2013, USGS. 2. INSET MAP DIGITAL DATA FROM 2002 NATIONAL TRANSPORTATION ATLAS, BUREAU OF TRANSPORTATION STATISTICS, WASHINGTON, D.C. 3. PROPERTY BOUNDARY DATA FROM WAKE COUNTY GIS. TOPOGRAPHIC SITE MAP Mid AtlantiC 4001 AND 4151 NC HWY 54 Enginaering d E"ifo11n1an[3l5olu[lom DURHAM, NORTH CAROLINA SCALE: 1:24,000 Feet 0 2,000 4,000 DRAWN DATE: BY: GCH NOVEMBER 2019 DRAFT JOB NO: CHECK: OOOR3358.01 ENG. GIS NO: CHECK: 2G-R3358.01-1 APPROVAL: DWG NO: 1.1 y.S, a AreaA, BuildingB co �O/V • ..,re_ J�o�� Area B � �'�i M,o ` , �' � - _ ',1 . ' •' ,, p Ao �Q £ r Area E r Q � �tf. Areait. a '-r !!L- /-= - -Z- lTC N^F z Area Fa IA 2 h. BL'lip o, w Area D IAJ Y a Building D/F ty x Legend Z a INDOOR/AMBIENT AIR SAMPLE ;r _•- ;• _ -. _ r : _,= SUBJECT SITE 1. -inch 300 feet - ;� - 0 500 1,000 1,500 2,000 S PARCEL BOUNDARIES Feet DRAWN BY: KRC DATE: JUNE 2020 SAMPLE LOCATION MAP DRAFT CHECK FPARK POINT BY: JOB NO.: R3358.01 Mid Atlantic4001 AND 4151 EAST HIGHWAY 54 ENGINEER CHECK GIS NO.: 3G-R3358.01-2_Samp Engineering & Environmental Solutions BY: DURHAM, NORTH CAROLINA APPROVED BY: DRAWING NO.: 2.1 REFERENCE: PARCEL BOUNDARIES FROM NC ONEMAP. PROPOSED DEVELOPMENT PLAN FROM TRINITY CAPITAL ADVISORS TABLE 10 Mid Atlantic TABLE 3.1 SUMMARY OF CHEMICAL CONSTITUENTS DETECTED IN INDOOR AIR AND RISK CALCULATIONS (24-HOUR SUMMA CANISTERS) NORTHERN TELECOM (PARK POINT) DURHAM, NORTH CAROLINA MID -ATLANTIC JOB NO. OOOR3358.01 Max NCDEQ DWM Non -Residential Indoor SamplelD IA-1 IA-2 IA-3 IA-4 Dup-1 (IA-3) IA-5 IA-6 OA-1 NCDEQ DWM Residential Indoor Air Concentration Air Screening Levels (IA-1 thorugh IA- February 2018 (ug/m3) Screening Levels Sampling Date 5/26/2020 5/26/2020 5/26/2020 5/26/2020 5/26/2020 5/26/2020 5/26/2020 5/26/2020 6 and Dup-1) February 2018 (ug/m3) 1,2,4-Trich lorobenzene 0.396 <0.297 <0.299 <0.299 <0.306 <0.300 <0.303 <0.307 0.396 4.2E-01 1.8E+00 1,2,4-Trimethylbenzene 1.21 0.714 0.860 0.747 0.833 0.759 1.07 <0.204 1.21 1.3E+01 5.3E+01 1,3,5-Trimethyl benzene 0.339 0.220 J 0.290 0.246 0.302 0.248 0.326 <0.204 0.339 1.3E+01 5.3E+01 1,4-Dioxane <0.147 <0.144 <0.145 <0.145 <0.149 <0.146 0.472 <0.149 0.472 5.6E-01 2.5E+00 2-Hexanone (Methyl butyl ketone) 0.436 J 0.343 J 0.496 0.308 J 0.450 J 0.455 J 1.73 <0.170 1.73 6.3E+00 2.6E+01 4-Ethyltoluene 0.259 <0.197 <0.198 <0.198 <0.203 <0.199 0.224 J <0.204 0.259 NS NS Acetone 10.7 10.8 10.6 9.31 11.3 10.6 20.7 4.38 20.7 6.5E+03 2.7E+04 Acetonitrile 0.345 0.336 0.283 0.266 0.415 0.393 0.356 0.309 0.415 1.3E+01 5.3E+01 Acrolein 0.616 0.526 0.683 0.523 0.748 0.633 0.802 0.156 0.802 4.2E-03 1.8E-02 Benzene 0.323 0.285 0.308 0.250 0.309 0.308 0.671 0.161 0.671 3.6E-01 1.6E+00 Carbon disulfide 0.142 0.216 0.129 J 0.156 0.129 J 0.160 0.250 <0.129 0.250 1.5E+01 6.1 E+02 Carbon tetrachloride 0.504 0.530 0.468 0.496 0.497 0.552 0.496 0.502 0.552 4.7E-01 2.0E+00 Chloromethane 1.32 1.44 1.36 1.43 1.36 1.48 1.39 1.37 1.48 1.9E+01 7.9E+01 Ethanol 23.0 14.7 21.7 17.5 22.2 18.9 9.53 1.67 23.0 NS NS Ethyl acetate 0.179 0.202 0.305 0.584 0.972 2.52 <0.147 0.308 2.52 1.5E+01 6.1 E+01 Ethylbenzene 0.573 0.364 0.459 0.396 0.468 0.409 1.05 <0.108 1.05 1.1 E+00 4.9E+00 Trichlorofluoromethane (fFreon 11 (CC13F)) 1.66 1.55 1.57 1.55 1.56 1.56 1.92 1.34 1.92 NS NS 1,1,2-Trich loro-1,2,2-tirfIuoroethane (Freon 113 (C2CI3F 1.55 2.22 1.41 1.96 1.46 1.58 1.03 0.545 2.22 1.0E+03 4.4E+03 Dichlorodifluoromethane (Freon 12 (CC12F2)) 2.53 2.63 2.85 2.65 2.76 2.68 3.48 2.31 3.48 2.1 E+01 8.8E+01 Heptane <0.167 0.250 0.191 0.264 0.264 0.251 0.333 <0.170 0.333 8.3E+01 3.5E+02 Hexane 0.233 0.225 0.234 0.215 0.293 0.244 0.255 <0.146 0.293 1.5E+02 6.1 E+02 Isopropyl alcohol 2.39 1.76 2.25 1.94 2.89 2.22 4.81 0.451 4.81 4.2E+01 1.8E+02 Isopropylbenzene <0.200 <0.197 <0.198 <0.198 <0.203 <0.199 0.225 J <0.204 0.225 NS NS m-/p-Xylenes 1.87 1.15 1.45 1.23 1.52 1.31 3.10 0.198 J 3.10 2.1 E+01 8.8E+01 Methyl ethyl ketone (2-Butanone) 1.49 1.43 1.41 1.32 1.59 1.63 2.74 0.435 2.74 1.0E+03 4.4E+03 Methyl isobutyl ketone 0.391 0.277 0.660 0.268 0.680 0.552 1.10 <0.170 1.10 6.3E+02 2.6E+03 Methylene chloride 0.566 0.556 0.553 0.613 0.720 0.644 0.516 0.582 0.720 1.0E+02 5.3E+02 Naphthalene 0.260 <0.210 <0.211 <0.211 <0.216 <0.212 0.528 <0.217 0.528 8.3E-02 3.6E-01 n-Octane 0.204 J <0.187 <0.188 <0.188 <0.193 <0.189 0.248 <0.193 0.248 NS NS o-Xylene 0.762 0.487 0.622 0.543 0.615 0.528 1.12 <0.180 1.12 2.1 E+01 8.8E+01 Propylene 0.605 0.618 0.595 0.536 0.596 0.595 0.739 0.321 0.739 6.3E+02 2.6E+03 Styrene <0.173 <0.171 <0.172 <0.171 0.247 <0.172 0.479 <0.176 0.479 2.1 E+02 8.8E+02 Tetrahydrofuran 0.656 0.329 0.510 0.420 0.570 0.426 0.819 <0.122 0.819 4.2E+02 1.8E+03 Toluene 0.901 0.707 0.818 0.812 0.960 0.845 0.914 0.314 0.960 1.0E+03 4.4E+03 Residential Acceptable Carcinogenic RESIDENTIAL RISK CALCULATIONS SUMMARY (IA-1 through IA-6 and Dup-1) Sum Risk Range and Maximum Non -Cancer Hazard Index Maximum Concentrations (All Compounds) Calculated Sample Sum Cancer Risk NC NC NC NC NC NC NC 1.1 E-05 3.9E+01 1.0 E-04 Calculated Sample Non -Carcinogenic Hazard Index NC NC NC NC NC NC NC EqNC HI=1 Maximum Concentrations (Minus Acrolein) Calculated Sample Sum Cancer Risk NC NC NC NC NC NC NC NC 1.1 E-05 1.0 E-04 Calculated Sample Non -Carcinogenic Hazard Index NC NC NC NC NC NC NC NC 6.3E-01 HI=1 Non -Residential Acceptable Carcinogenic NON-RESIDENTIAL RISK CALCULATIONS SUMMARY (IA-1 through IA-6 and Dup-1) Sum Risk Range and Maximum Non -Cancer Hazard Index Maxium Concentrations (All Compounds) Calculated Sample Sum Cancer Risk NC NC NC NC NC NC NC NC 2.6E-06 9.3E+00 1.0 E-04 Calculated Sample Non -Carcinogenic Hazard Index NC NC NC NC NC NC NC NC HI=1 Maximum Concentrations (Minus Acrolein) Calculated Sample Sum Cancer Risk NC NC NC NC NC NC NC NC 2.6E-06 1.0 E-04 Calculated Sample Non -Carcinogenic Hazard Index NC NC NC NC NC NC NC NC 1.5E-01 HI=1 Notes: Concentration units; ug/m3 <1.96 = Not detected above the lab method detection limit Italicized = Screening level exceeds laboratory method detection limit NC = Risk calculation not conducted NS = No standard established = Control samples outside of area of concern Bold = Concentration detected above laboratory method detection limit Bold Bold 1.1 E+01 ------------------------ 2.5E+00 ............. ............... No concentration above laboratory method detection limit = Concentration exceeds Residential Indoor Air Screening Level = Concentration exceeds Non -Residential Indoor Air Screening Level = Exceeds Residential risk calculation screening criteria = Exceeds Non -Residential risk calculation screening criteria APPENDIX A INDOOR AIR BUILDING SURVEY Mid Atlantic INDOOR AIR BUILDING SURVEY and SAMPLING FORM Site Name: _Af, Preparer's name: d!5�+,j Preparer's affiliation: `A i 1D#: ? 30?q l � - 02e Date: laa z4d Phone #: 76 ,-1 6 o 9 <:3N Part I - Occupants Building Address: Property Contact: 4�,f o.•; f� Owner / Renter 1 her �rrP. Contact's Phone: home { } work (qA } 13 a�(3G cell } # of Building occupants: Children under age 13 Children age 13-18 Adults Part I1— Building Characteristics Building type: residential // multi -family residential 6ce) strip mall / commercial / industrial Describe building: o-" YuYear constructed: 7j'— ( 4 & Sensitive population: day care 1 nursing ho3ne 1 hospital 1 school 1 other (specify): Number of floors below grade: 0' Mull basement 1 crawl space slab on grade Number of floors at or above grade: f Depth of basement below grade surface: d) ft. Basement size: YA- ft2 Basement floor construction: c ncrete 1 dirt 1 floating 1 stone l other (specify): Foundation walls: oared concrete 1 inder blocks 1 stone 1 other (specify) /t./ 1.4— Basement sump present? Yes /Sump pump? Yes I iW Water in su np? Yes 1 qP V Type of heating systetn (circle all that apply): hot air circulation hot air radiation wood steam radiation heat pump hot water radiation kerosene heater electric baseboard other (specify): 0-- a Type of ventilation system (circle all that apply): central air conditioning mechanical fans bathroom ventilation fans individual air conditioning units kitchen range hood fan outside air intake other {specify}: do-f- p +Ong. { Type of fuel utilized {circle all that apply}: Natural gas 1 ectric fuel oil 1 wood 1 coal 1 solar 1 kerosene Are the basement walls or floor sealed with waterproof paint or epoxy coatings? Yes I60 Part V — Miscellaneous Items Do any occupants of the building smoke? Yes 1 A�_ How often? Last time someone smoked in the building? hours 1 days agn Does the building have an attached garage directly connected to living space? Yes 16D If so, is a car usually parked in the garage? Yes 1 No a 4 Are gas -powered equipment or cans of gasoline/fuels stored in the garage? Yes I No Do the occupants of the building have their clothes dry cleaned? Yes 1 e If yes, how often? weekly 1 monthly 13-4 tunes a year Do any of the occupants use solvents in work? Yes 1 If yes, what types of solvents are used? If yes, are their clothes washed at work? Yes 1 No Have any pesticides/herbicides been applied around the building or in the yard? Yes 1 No If so, when and which chemicals? t),j e2 Has there ever been afire in the building? Yes 1 No If yes, when? Has painting or staining been done in the building in the last 6 months? Yes NO If yes, when Co, �� P �an�dwber�e. Part VI — SamplingSaMpling Information 4� Sample Technician: 4 '�7 Phone number: {_V�( Sample source: oor rawispace Air/ Sub -Slab 1 Near Slab Soil Gas/ Exterior Soil Gas Sampler Type: Tedlar bag 1 Sorben Stainless Steel Canist 1 Other (specify): Analytical Methott6�_? 1 TO-17 1 other: Cert. Laboratory -- Sample locations (floor, room): Field ID # - ':�4 r- I —5_ field ID # Field ID # - T4 —5 7: , ,A Field ID # Were "Instructions for Occupants" followed? Yes n Knot, describe modifications: Is there a whole house fan? Septic system? Irrigation/private well? Yes I(f :) Ye.r 1 Yes {beet not used) Yes 1 Yes ut not used) I No Type of ground cover outside of building: grass concreteCsphalt Existing subsurface depressurization (radon) system in place? Yes 1 Sub -slab vapor/moisture barrier in place'? Yes I� Type of barrier; [[�� Part III - Outside Contaminant Sources other (specify) NO � � active 1 passive Other stationary sources nearby (gas stations, emission stacks, etc.): 5 0-1 -S S -c,& cle-_ III Heavy vehicular traffic nearby (or other mobile sources): �_ , �� f.. I BC& Fi-A" Part IV — Indoor Contaminant Sources ' 9 Si Identify all potential indoor sources found in the building (including attached garages) and crawlspace (if present), the location of the source (floor and room), and whether the item was removed from the building 48 hours prior to indoor air sampling event. Any ventilation implemented after removal of the items should be completed at least 24 hours prior to the commencement of the indoor air sampling event. Potential Sources Location(s) Removed (Yes 1 No 1 NA) Gasoline storage cans Gas -powered equipment Kerosene storage cans Paints / thinners / strippers d4 Cleaning solvents Oven cleaners Carpet 1 upholstery cleaners Other house cleaning products Moth balls Polishes 1 waxes Insecticides Furniture 1 floor polish Nail polish 1 polish remover Hairspray Cologne 1 perfume Air fresheners Fuel tank (inside building) NA Wood stove or fireplace NA New furniture 1 upholstery New carpeting 1 flooring NA Hobbies - glues, paints, etc. Provide Drawing of Sample Location(s) in Building Part VII - Meteorological Conditions Was there significant precipitation within 12 hours prior to (or }during) the sam ling event? Yes No Describe the genera] weather conditions: Part VIII — General Observations Provide any information that inay be pertinent to the sampling event and may assist in The data interpretation process (e.g., observed that drycleaner operated with door or windows propped open for ventilation). -R�•-ti `CJ.j c4^5t� C4; -n - (Adapted from the N]DEP Vapor Intrusion Guidance, October 2005) APPENDIX B OVERALL SITE PLAN WFAk Mid Atlantic N/F NC RAILROAD COMPANY SITE LEGEND / PIN: 0747-01-49-4319 \ \ USE: PUBL SVC/RAILROADS \ \ SIGNAGE / ZONING: SRP \ \ TIER: SUBURBAN/METRO NORTH CN YARD LIGHTS LIGHT POLE CIL POWER POLE TRAFFIC DIRECTIONAL ARROW GRAPHIC SCALE ACC ACCESSIBLE PARKING STALL o so soo zoo — VAN VAN ACCESSIBLE PARKING STALL 1 inch 100 ft. — XX PARKING SPACE COUNT ACCESSIBLE RAMPS 11� /� �, \ \ \ TYPE AQ TYPE © TYPE QC o \ % \ \ \ \ \ \ / / • • • • • • • • i ACCESSIBLE ROUTE F°A \\ \ \ // .ii�ii�ii�ii�ii. PHASE LINE N/F - - PROPERTY LINE III"(A� - 11 F \ \ \ NC RAILROAD COMPANY - - - PIN: 0747--48-2651 USE: PUBL SOVC/RAILROADS - - - - RIGHT-OF-WAY LINE ZONING: SRP LOT LINE 21 / ` o . , \ \ TIER: SUBURBAN f \ 'o,� \ \ \ \ \ — — EASEMENT LINE CENTERLINE 5 \ �\ 23.4?�99A• \ / HEAVY DUTY loll� 2 15. \ \ \ / / \ \ / ASPHALT PAVEMENT N5'04'32"E AREA B 44 \ 103.92' N6'43'48"E / �- �/' 53.49' 100' ZONING\ N/F SETBACK/ \ \ \ NC RAILROAD COMPANY _ \ PIN: 0747-01-48-2243 _+- - BUILDING\`\°� // \ \ \ \ USE: PUBL SVC/RAILROADS 33 ZONING: SRP A/B / \ _ \ \ s39, \ \ \ TIER: SUBURBAN/METRO NORTH CN 100, t. FITNESS N. � AREA"A"'/ \ \ \\\ \\ F \ \ \ N67'04'52"W \� •_: f�j \\ \ / i 288.80' yr v AREA A �� �° �v i ��✓ A AA\ �8 v v > A1� ? N67'04'52'W \ X ,c V A V A / V A AREA"W 228.03' A N1944'10"W HEETC2. 287.30' ! `P� % s S22'55'08"W �� ", 1. �'• QC�` i \ 231.11' /_- ' N67'04.52"W 93.00' � N22.55.08"E ` ` ::� �:. \ \ / o X�x VA� \ \ �R• °QS°, \ \ \� o 00 233.70'.. r' '• • `\ \ / / / / \ ' '� : • (f .+� .'e . '.: . .• •%���// ' \ \ \\ \ \ \ , �\ AREA "C" SHEET BUILDING AREA C `' '': ��// —� \ \\ �\ \ / N/F ETC2. C2.04 �\ \ / / /� \ \ Oa •�' L� / �o° NC RAILROAD -COMPANY / \ � o\ \ / � / / \\ � ® \ � \ s . � : •.. .. .. � � �\\ \ � ` J 'vat �s, PIN: 0747 01 47 3714 SVC USE: PUBL RAILROADS / / ,/' \ � • « ice• '� � \� / / �\ 1 \ ZONING: SRP n I / \\ V 1� �\ _ ~' \ \\ f \ \ \ \ TIER: METRO NORTH CN / '/ !• r AREA E J / M �= �% V A A \ \ \VA' Aik 72 \ BUILDING~ g \\ �\ ` -�-1 30 \ \ NC RAILROAD COMPANY \ \ S25'30'22"W \ \ \\ `� G / ®� �\ V/ / _ \! \ 71 ��/ J PIN: 0747-01-46-2932 348.19' /� / \ \ 0 \ I'll \D/F\ ZONING. SRP / \ / \ \ 4R• �y USE: PUBL SVC/RAILROADS =3 AC. /� �\ �ji�1 // \ \\ \ ��/� \ \\ �T`F TIER: METRO NORTH CN / S22' 8 y✓ s ' AREA D\�\l 71 71 AREA F �✓ /� \ 71 � EX. TENNIS 7 \� �� \�//� \;Cj // \ 40 ®38 "% COURT II \\� —°�98, / 100' ZONING \ �\ \ \ \ \\ `/� 7 /J�/� / / �� \\\ Y C 8\ `\��/ 1 6 \ RN, \ \ ® 34� /I � (r S67'39'08"E SETBACK �� \ \ (/ \/ / �\ �jY \\ \ 0 \�/ �J' / 4.99. °o\ \ \ \ \ \ ✓�\�\ \\ �(//� \ \� `. \ \ O © /�\ \� %� \ I I / R=94.26ol \ f S30'59'13"E EX. VOLLEYBALL \ \ \ '\` / /" / S30'59'13"E \ COURT \ \ ( \ �/ / \/ �' 28.02' \\ w Lo Sv \ sa \ \ / \�\\, • ` / �( I / !1L DUKE ENERGY CAROLINAS LLC NEW LOT 3 \ / / I� / / Z PIN: 0747-01- IC FIELDS 1 AREA=41 .19 AC. �^ \ �/ //� \ _� / USE: RZONIING: SRP FIELDS TIER: SUBURBAN/METRO NORTH CN i N/F BECTON DICKINSON & COMPANY 1026 PIN: 1-19-8542 USE: IND/BIOTE/BIOTECH - BIOPHARM ZONING: SRP TIER: SUBURBAN S5'29'22"W \ 219.11' \ \\ LOOD ZONE "X.. \ \ S21'14122"W \ FEMA PANEL NUMBER 0747 \ \ 239.99' i �\ _ EFFECTIVE 05/02/06 / /-`_ -_- _ - - -_ - - - - - - - - - - / \�I 30' DUKE POWER COMPANY \\ N47 16'04"E 40' UTILITY \ \ \ \ \ /// 111 \ \ / , \` I- UTILITY147 PG. 72.26' EASEMENT \ \ / \ \ \ \J� J1 \ D.B. 1018 PG. 266 _ \ \ \ \\ \ J 1 Nv --------_D.B. 1020 PG. 401 30' DUKE POWER COMPANY 10' GENERAL UTILITY�I D.B. 1074 PG. 477,I` UTILITY EASEMENT EASEMENT , A J l , I — - - - - - - - - _ - - - - \ \ \ EX. POND v�J I I� D.B. 147 PG. 327 D.B. 1021 PG. 4SJ�/v " v�J �I - �1- - - - - - S7l'77 22 E _ \ \ \ \ J S41'18'03"E S42'42'16"E D.B. 1018 PG. 266 11 581.74' 103.49' \ I \ PERMANENT SLOPE EASEMENT D.B. 1020 PG. 401 739.34'- _ - - - - - - - - - �4,- - - _ - _ vD.B.1. _.----- - --- --_ — ---- D.B. 6528 PG. 158 I I � _ _ D074PG477S41'18'03"E S66'44'22"W -�S 1' 8'03"E / 145.78' / I ___-------Igb3"E 237.28' R=19B4.86' _ _ 175.00 / 2712'W 2.20L=480.14' I EXISTING = _ NC HIGHWAY 5 R/W) - __- ----N/F------ �� (VARIABLE WIDTH P _ _ — �1\ � - - - - - _ - - - -T- r RESEARCH TRIANGLE FOUNDATION _ _ _ _ OF NORTH CAROLINA FMRNRTP LLC I PIN: 0747-01-36-4637 PIN: 0747-17-74-2148 I USE: VACANT USE: COM/OFFICE BUILDING I ZONING: OL, CASE:P00-18 - - - - - - ZONING: SRP TIER: METRO NORTH CN TIER: SUBURBAN/METRO NORTH CN PRELIMINARY DRAWING - NOT RELEASED FOR CONSTRUCTION 'J McADAMS The John R. McAdams Company, Inc. 2905 Meridian Parkway Durham, NC 27713 phone 919. 361. 5000 fax 919. 361. 2269 license number: C-0293, C-187 www.mcadamsco.com CLIENT GENSLER 530 HILLSBOROUGH STREET RALEIGH, NORTH CAROLINA 27603 P H 0 N E: 919. 239. 7831 W >- O LL z = N LAM Q(Da OJ I..0 If z Lr) U U > a� LU LU = Q O o a 0 "'1u1uu8gi ��N CARS o SS .'L •Q i �FAL - '•,��;�'••N� I NEB•. REVISIONS NO. DATE 1 03. 23.2020 REVISED PER 15T SITE PLAN SUBMISSION 2 05. 06. 2020 REVISED PER 2ND SITE PLAN SUBMISSION PLAN INFORMATION PROJECT NO FILENAME CHECKED BY DRAWN BY SCALE DATE SHEET G N L-19010 G N L19010-OAS1 RS GH 1"=100' 12. 10. 2019 OVERALL SITE PLAN C2.00 APPENDIX C PHOTOGRAPHIC LOG OF SAMPLE LOCATIONS 10 Mid Atlantic y ea". 5• I a Northern Telecom (Park Point) — 4001 and 4151 East NC Hwy 54 Durham, North Carolina Photo 1 — Indoor Air sample IA-1 collected from Building D/F. Photo 3 — Indoor Air sample IA-3 and duplicate sample Dup-1 collected from Building D/F Photo 5 — Indoor Air sample IA-5 collected from Building C/E. Photo 2 — Indoor Air sample IA-2 collected from Building D/F. Photo 4 — Indoor Air sample IA-4 collected from Building D/F. Photo 6 — De minimis household cleaners and spray paint cans in Building C/E. Mid -Atlantic Associates, Inc. May 2020 Northern Telecom (Park Point) — 4001 and 4151 East NC Hwy 54 Durham, North Carolina II Photo 7 — Indoor Air sample IA-6 collected from Building A/B. Photo 8 — Debris piles present in Area B of Building A/B Mid -Atlantic Associates, Inc. May 2020 APPENDIX D LABORATORY ANALYTICAL REPORT AND CHAIN -OF -CUSTODY RECORD FOR INDOOR/AMBIENT AIR SAMPLES 10 Mid Atlantic `r ENTHALPY ANALYTICAL Mid- Atlantic Associates, Inc. 409 Rogers View Ct Raleigh, NC 27610 Northern Telecom Durham, NC Client Project #R3 3 5 8.01 Analytical Report (0520-176) EPA Method TO-1 S TO-15 Target Compound List Enthalpy Analytical, LLC Phone: (919) 850 - 4392 / Fax: (919) 850 - 9012 / www.enthalpy.com 800-1 Capitola Drive Durham, NC 27713-4385 I certify that to the best of my knowledge all analytical data presented in this report: • Have been checked for completeness • Are accurate, error -free, and legible • Have been conducted in accordance with approved protocol, and that all deviations and analytical problems are summarized in the appropriate narrative(s) This analytical report was prepared in Portable Document Format (.PDF) and contains 37 pages. QA Review Performed by—Quentisha L. Forrester Report Issued: 05/28/2020 EA# 0520-176 Page 2 of 37 �) ENTHALFY A N' A L Y i I C A L Results EA# 0520-176 Page 3 of 37 Quantitation Report Enthalpy Analytical, LLC Sample Name Sample Info Data File Dilution Pressurization Factor Acquisition Date Instrument Method Matrix : IA-1 0520-176; *0.667=750mL load; Can *24090 X2001892.D 0.667 1.744 2020-05-27 14:02:30 T015-SCN.M AIR Concentration RL MDL Concentration RL MDL Target Compound -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- (PPBV) (PPBV) (PPBV) (ug/m3) (ug/m3) (ug/m3) Flag* Propylene 0.352 0.0446 0.0407 0.605 0.0767 0.0701 Freon 12 (CC12F2) 0.512 0.0447 0.0407 2.53 0.221 0.201 Freon 114 (C2Cl2F4) ND 0.0463 0.0407 ND 0.324 0.285 Chloromethane 0.640 0.0452 0.0407 1.32 0.0934 0.0841 Chloroethene (Vinyl chloride) ND 0.0464 0.0407 ND 0.119 0.104 1,3-Butadiene ND 0.0449 0.0407 ND 0.0994 0.0901 Bromomethane ND 0.0456 0.0407 ND 0.177 0.158 Chloroethane ND 0.0466 0.0407 ND 0.123 0.107 Bromoethene (Vinyl bromide) ND 0.0456 0.0407 ND 0.200 0.178 Freon 11 (CC13F) 0.295 0.0480 0.0407 1.66 0.270 0.229 Ethanol 12.2 0.0465 0.0465 23.0 0.0877 0.0877 Acrolein 0.269 0.0451 0.0407 0.616 0.103 0.0934 Freon 113 (C2Cl3F3) 0.202 0.0461 0.0407 1.55 0.353 0.312 1,1-Dichloroethene ND 0.0463 0.0407 ND 0.184 0.161 Acetone 4.49 0.0459 0.0407 10.7 0.109 0.0967 Carbon disulfide 0.0456 0.0462 0.0407 0.142 0.144 0.127 1 Isopropyl alcohol 0.972 0.0461 0.0407 2.39 0.113 0.100 AIIyl chloride (3-chloropropene) ND 0.0464 0.0407 ND 0.145 0.127 Acetonitrile 0.205 0.0459 0.0407 0.345 0.0771 0.0684 Methylene chloride 0.163 0.117 0.117 0.566 0.405 0.405 trans-1,2-Dichloroethene ND 0.0470 0.0407 ND 0.186 0.161 Methyl tert-butyl ether ND 0.0470 0.0407 ND 0.169 0.147 Acrylonitrile ND 0.0467 0.0407 ND 0.101 0.0884 Hexane 0.0660 0.0469 0.0407 0.233 0.165 0.143 1,1-Dichloroethane ND 0.0454 0.0407 ND 0.184 0.165 Vinyl acetate ND 0.0467 0.0407 ND 0.164 0.143 cis-1,2-Dichloroethene ND 0.0463 0.0407 ND 0.183 0.161 Methyl ethyl ketone (2-Butanone) 0.506 0.0472 0.0407 1.49 0.139 0.120 Ethyl acetate 0.0497 0.0466 0.0407 0.179 0.168 0.147 Chloroform ND 0.0468 0.0407 ND 0.228 0.199 Tetrahydrofuran 0.222 0.0464 0.0407 0.656 0.137 0.120 1,1,1-Trichloroethane ND 0.0459 0.0407 ND 0.250 0.222 Cyclohexane ND 0.0468 0.0407 ND 0.161 0.140 Carbon tetrachloride 0.0802 0.0466 0.0407 0.504 0.293 0.256 Benzene 0.101 0.0457 0.0407 0.323 0.146 0.130 2,2,4-trimethylpentane ND 0.0471 0.0407 ND 0.220 0.190 1,2-Dichloroethane ND 0.0469 0.0407 ND 0.190 0.165 Heptane ND 0.0463 0.0407 ND 0.190 0.167 Trichloroethene ND 0.0465 0.0407 ND 0.250 0.219 1,2-Dichloropropene ND 0.0456 0.0407 ND 0.211 0.188 Methyl methacrylate ND 0.0478 0.0407 ND 0.196 0.167 1,4-Dioxane ND 0.0464 0.0407 ND 0.167 0.147 Bromodichloromethane ND 0.0460 0.0407 ND 0.308 0.273 cis-1,3-Dichloropropene ND 0.0454 0.0407 ND 0.206 0.185 Methyl isobutyl ketone 0.0955 0.0475 0.0407 0.391 0.195 0.167 Toluene 0.239 0.0469 0.0407 0.901 0.177 0.153 trans-1,3-Dichloropropene ND 0.0470 0.0407 ND 0.214 0.185 1,1,2-Trichloroethane ND 0.0465 0.0407 ND 0.254 0.222 Tetrachloroethene ND 0.0465 0.0407 ND 0.316 0.276 2-Hexanone (Methyl butyl ketone) 0.106 0.119 0.0407 0.436 0.488 0.167 J Dibromochloromethane ND 0.0459 0.0407 ND 0.391 0.347 1,2-Dibromoethane ND 0.0469 0.0407 ND 0.360 0.313 Chlorobenzene ND 0.0477 0.0407 ND 0.220 0.187 Ethylbenzene 0.132 0.0456 0.0407 0.573 0.198 0.177 1,1,1,2-Tetrachloroethane ND 0.0464 0.0407 ND 0.319 0.280 m-/p-Xylenes 0.431 0.0469 0.0407 1.87 0.204 0.177 EA# 0520-176 Page 4 of 37 Quantitation Report Enthalpy Analytical, LLC Sample Name : IA-1 Sample Info 0520-176; *0.667=750mL load; Can *24090 Data File X2001892.13 Dilution 0.667 Pressurization Factor 1.744 Acquisition Date 2020-05-27 14:02:30 Instrument Method T015-SCN.M Matrix AIR Concentration RL MDL Concentration RL MDL Target Compound -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- (PPBV) (PPBV) (PPBV) (ug/m3) (ug/m3) (ug/m3) Flag o-Xylene 0.176 0.0461 0.0407 0.762 0.200 0.177 Styrene ND 0.0452 0.0407 ND 0.192 0.173 Bromoform ND 0.0465 0.0407 ND 0.480 0.421 1,1,2,2-Tetrachloroethane ND 0.0465 0.0407 ND 0.319 0.279 4-Ethyltoluene 0.0527 0.0468 0.0407 0.259 0.230 0.200 m 2-Chlorotoluene ND 0.0467 0.0407 ND 0.242 0.211 1,3,5-Trimethylbenzene 0.0690 0.0467 0.0407 0.339 0.230 0.200 1,2,4-Trimethylbenzene 0.245 0.0462 0.0407 1.21 0.227 0.200 m 1,3-Dichlorobenzene ND 0.0473 0.0407 ND 0.285 0.245 1,4-Dichlorobenzene ND 0.0468 0.0407 ND 0.281 0.245 Benzyl chloride ND 0.0463 0.0407 ND 0.240 0.211 1,2-Dichlorobenzene ND 0.0472 0.0407 ND 0.284 0.245 1,2,4-Trichlorobenzene 0.0534 0.0471 0.0407 0.396 0.350 0.302 Hexachlorobutadiene ND 0.0472 0.0407 ND 0.504 0.434 Naphthalene 0.0497 0.0485 0.0407 0.260 0.254 0.213 1-Bromopropane ND 0.0454 0.0407 ND 0.228 0.205 1-Octene ND 0.0451 0.0407 ND 0.207 0.187 n-Octane 0.0437 0.0466 0.0407 0.204 0.218 0.190 m 3 Isopropylbenzene ND 0.0469 0.0407 ND 0.231 0.200 n-Propylbenzene ND 0.0471 0.0407 ND 0.231 0.200 Retention Time Concentration Internal Standards Response (min) (PPBV) Flag ------------------------------------------------------------------------------------------------------------------------------------------ Bromochloromethane (IS) 482,881 11.85 5.00 PASS 1,4-Dicuorobenzene (IS) 1,937,064 13.61 5.04 PASS Chlorobenzene-d5 (IS) 1,680,663 17.80 4.80 PASS (ND) = Not Detected * (3) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40% EA# 0520-176 Page 5 of 37 Quantitation Report Enthalpy Analytical, LLC Sample Name Sample Info Data File Dilution Pressurization Factor Acquisition Date Instrument Method Matrix : IA-2 0520-176; *0.667=750mL load; Can *1436 X2001893.D 0.667 1.717 2020-05-27 15:03:04 T015-SCN.M AIR Concentration RL MDL Concentration RL MDL Target Compound -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- (PPBV) (PPBV) (PPB1� (ug/m3) (ug/m3) (ug/m3) Flag* Propylene 0.359 0.0439 0.0401 0.618 0.0755 0.0690 m Freon 12 (CC12F2) 0.533 0.0440 0.0401 2.63 0.218 0.198 Freon 114 (C2Cl2F4) ND 0.0456 0.0401 ND 0.319 0.280 Chloromethane 0.697 0.0445 0.0401 1.44 0.0919 0.0828 Chloroethene (Vinyl chloride) ND 0.0457 0.0401 ND 0.117 0.102 1,3-Butadiene ND 0.0443 0.0401 ND 0.0979 0.0887 Bromomethane ND 0.0449 0.0401 ND 0.174 0.156 Chloroethane ND 0.0459 0.0401 ND 0.121 0.106 Bromoethene (Vinyl bromide) ND 0.0449 0.0401 ND 0.197 0.175 Freon 11(CC13F) 0.276 0.0473 0.0401 1.55 0.266 0.225 Ethanol 7.83 0.0458 0.0458 14.7 0.0863 0.0863 Acrolein 0.229 0.0444 0.0401 0.526 0.102 0.0919 m Freon 113 (C2Cl3F3) 0.289 0.0454 0.0401 2.22 0.348 0.307 1,1-Dichloroethene ND 0.0456 0.0401 ND 0.181 0.159 Acetone 4.57 0.0452 0.0401 10.8 0.107 0.0952 m Carbon disulfide 0.0694 0.0455 0.0401 0.216 0.142 0.125 Isopropyl alcohol 0.717 0.0454 0.0401 1.76 0.111 0.0985 AIIyl chloride (3-chloropropene) ND 0.0457 0.0401 ND 0.143 0.125 Acetonitrile 0.200 0.0452 0.0401 0.336 0.0759 0.0673 Methylene chloride 0.160 0.115 0.115 0.556 0.399 0.399 trans-1,2-Dichloroethene ND 0.0463 0.0401 ND 0.183 0.159 Methyl tert-butyl ether ND 0.0463 0.0401 ND 0.167 0.145 Acrylonitrile ND 0.0459 0.0401 ND 0.0997 0.0870 Hexane 0.0639 0.0461 0.0401 0.225 0.163 0.141 1,1-Dichloroethane ND 0.0447 0.0401 ND 0.181 0.162 Vinyl acetate ND 0.0459 0.0401 ND 0.162 0.141 cis-1,2-Dichloroethene ND 0.0455 0.0401 ND 0.181 0.159 Methyl ethyl ketone (2-Butanone) 0.484 0.0465 0.0401 1.43 0.137 0.118 Ethyl acetate 0.0560 0.0459 0.0401 0.202 0.165 0.144 Chloroform ND 0.0460 0.0401 ND 0.225 0.196 Tetrahydrofuran 0.112 0.0457 0.0401 0.329 0.135 0.118 m 1,1,1-Trichloroethane ND 0.0452 0.0401 ND 0.246 0.219 Cyclohexane ND 0.0460 0.0401 ND 0.158 0.138 Carbon tetrachloride 0.0842 0.0459 0.0401 0.530 0.288 0.252 Benzene 0.0891 0.0450 0.0401 0.285 0.144 0.128 2,2,4-trimethylpentane ND 0.0464 0.0401 ND 0.217 0.187 1,2-Dichloroethane ND 0.0462 0.0401 ND 0.187 0.162 Heptane 0.0610 0.0455 0.0401 0.250 0.187 0.164 Trichloroethene ND 0.0458 0.0401 ND 0.246 0.215 1,2-Dichloropropene ND 0.0448 0.0401 ND 0.207 0.185 Methyl methacrylate ND 0.0470 0.0401 ND 0.193 0.164 1,4-Dioxane ND 0.0457 0.0401 ND 0.165 0.144 Bromodichloromethane ND 0.0453 0.0401 ND 0.304 0.269 cis-1,3-Dichloropropene ND 0.0447 0.0401 ND 0.203 0.182 Methyl isobutyl ketone 0.0677 0.0468 0.0401 0.277 0.192 0.164 Toluene 0.188 0.0461 0.0401 0.707 0.174 0.151 trans-1,3-Dichloropropene ND 0.0463 0.0401 ND 0.210 0.182 1,1,2-Trichloroethane ND 0.0458 0.0401 ND 0.250 0.219 Tetrachloroethene ND 0.0458 0.0401 ND 0.311 0.272 2-Hexanone (Methyl butyl ketone) 0.0837 0.117 0.0401 0.343 0.480 0.164 J Dibromochloromethane ND 0.0452 0.0401 ND 0.385 0.341 1,2-Dibromoethane ND 0.0462 0.0401 ND 0.355 0.308 Chlorobenzene ND 0.0470 0.0401 ND 0.216 0.185 Ethylbenzene 0.0838 0.0448 0.0401 0.364 0.195 0.174 1,1,1,2-Tetrachloroethane ND 0.0457 0.0401 ND 0.314 0.275 m-/p-Xylenes 0.264 0.0462 0.0401 1.15 0.201 0.174 EA# 0520-176 Page 6 of 37 Quantitation Report Enthalpy Analytical, LLC Sample Name : IA-2 Sample Info 0520-176; *0.667=750mL load; Can #1436 Data File X2001893.D Dilution 0.667 Pressurization Factor 1.717 Acquisition Date 2020-05-27 15:03:04 Instrument Method T015-SCN.M Matrix AIR Concentration RL MDL Concentration RL MDL Target Compound -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- (PPBV) (PPBV) (PPBV) (ug/m3) (ug/m3) (ug/m3) Flag o-Xylene 0.112 0.0454 0.0401 0.487 0.197 0.174 Styrene ND 0.0445 0.0401 ND 0.189 0.171 Bromoform ND 0.0458 0.0401 ND 0.473 0.414 1,1,2,2-Tetrachloroethane ND 0.0458 0.0401 ND 0.314 0.275 4-Ethyltoluene ND 0.0460 0.0401 ND 0.226 0.197 2-Chlorotoluene ND 0.0460 0.0401 ND 0.238 0.208 1,3,5-Trimethylbenzene 0.0447 0.0460 0.0401 0.220 0.226 0.197 J 1,2,4-Trimethylbenzene 0.145 0.0455 0.0401 0.714 0.224 0.197 m 1,3-Dichlorobenzene ND 0.0466 0.0401 ND 0.280 0.241 1,4-Dichlorobenzene ND 0.0460 0.0401 ND 0.277 0.241 Benzyl chloride ND 0.0456 0.0401 ND 0.236 0.208 1,2-Dichlorobenzene ND 0.0465 0.0401 ND 0.280 0.241 1,2,4-Trichlorobenzene ND 0.0464 0.0401 ND 0.344 0.297 Hexachlorobutadiene ND 0.0465 0.0401 ND 0.496 0.427 Naphthalene ND 0.0478 0.0401 ND 0.250 0.210 1-Bromopropane ND 0.0447 0.0401 ND 0.225 0.202 1-Octene ND 0.0444 0.0401 ND 0.204 0.184 n-Octane ND 0.0459 0.0401 ND 0.214 0.187 Isopropylbenzene ND 0.0462 0.0401 ND 0.227 0.197 n-Propylbenzene ND 0.0464 0.0401 ND 0.228 0.197 Retention Time Concentration Internal Standards Response (min) (PPBV) Flag ------------------------------------------------------------------------------------------------------------------------------------------ Bromochloromethane (IS) 483,731 11.85 5.00 PASS 1,4-Dicuorobenzene (IS) 1,937,203 13.62 5.04 PASS Chlorobenzene-d5 (IS) 1,686,716 17.80 4.80 PASS (ND) = Not Detected * (3) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40% EA# 0520-176 Page 7 of 37 Quantitation Report Enthalpy Analytical, LLC Sample Name Sample Info Data File Dilution Pressurization Factor Acquisition Date Instrument Method Matrix : IA-3 0520-176; *0.667=750mL load; Can #000020 X2001894.D 0.667 1.728 2020-05-27 16:03:28 T015-SCN.M AIR Concentration RL MDL Concentration RL MDL Target Compound -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- (PPBV) (PPBV) (PPBV) (ug/m3) (ug/m3) (ug/m3) Flag* Propylene 0.346 0.0442 0.0403 0.595 0.0760 0.0694 m Freon 12 (CC12F2) 0.577 0.0443 0.0403 2.85 0.219 0.199 Freon 114 (C2Cl2F4) ND 0.0459 0.0403 ND 0.321 0.282 Chloromethane 0.658 0.0448 0.0403 1.36 0.0925 0.0833 Chloroethene (Vinyl chloride) ND 0.0460 0.0403 ND 0.117 0.103 1,3-Butadiene ND 0.0445 0.0403 ND 0.0985 0.0892 Bromomethane ND 0.0452 0.0403 ND 0.175 0.157 Chloroethane ND 0.0462 0.0403 ND 0.122 0.106 Bromoethene (Vinyl bromide) ND 0.0452 0.0403 ND 0.198 0.176 Freon 11(CC13F) 0.279 0.0476 0.0403 1.57 0.267 0.227 Ethanol 11.5 0.0461 0.0461 21.7 0.0869 0.0869 Acrolein 0.298 0.0447 0.0403 0.683 0.103 0.0925 Freon 113 (C2Cl3F3) 0.184 0.0457 0.0403 1.41 0.350 0.309 1,1-Dichloroethene ND 0.0459 0.0403 ND 0.182 0.160 Acetone 4.48 0.0455 0.0403 10.6 0.108 0.0958 m Carbon disulfide 0.0415 0.0458 0.0403 0.129 0.143 0.126 m I Isopropyl alcohol 0.914 0.0456 0.0403 2.25 0.112 0.0992 AIIyl chloride (3-chloropropene) ND 0.0460 0.0403 ND 0.144 0.126 Acetonitrile 0.169 0.0455 0.0403 0.283 0.0764 0.0677 Methylene chloride 0.159 0.115 0.115 0.553 0.401 0.401 trans-1,2-Dichloroethene ND 0.0466 0.0403 ND 0.185 0.160 Methyl tert-butyl ether ND 0.0466 0.0403 ND 0.168 0.145 Acrylonitrile ND 0.0462 0.0403 ND 0.100 0.0875 Hexane 0.0665 0.0464 0.0403 0.234 0.164 0.142 1,1-Dichloroethane ND 0.0450 0.0403 ND 0.182 0.163 Vinyl acetate ND 0.0462 0.0403 ND 0.163 0.142 cis-1,2-Dichloroethene ND 0.0458 0.0403 ND 0.182 0.160 Methyl ethyl ketone (2-Butanone) 0.480 0.0468 0.0403 1.41 0.138 0.119 Ethyl acetate 0.0848 0.0461 0.0403 0.305 0.166 0.145 Chloroform ND 0.0463 0.0403 ND 0.226 0.197 Tetrahydrofuran 0.173 0.0460 0.0403 0.510 0.136 0.119 1,1,1-Trichloroethane ND 0.0455 0.0403 ND 0.248 0.220 Cyclohexane ND 0.0463 0.0403 ND 0.159 0.139 Carbon tetrachloride 0.0744 0.0461 0.0403 0.468 0.290 0.254 Benzene 0.0965 0.0453 0.0403 0.308 0.145 0.129 2,2,4-trimethylpentane ND 0.0467 0.0403 ND 0.218 0.188 1,2-Dichloroethane ND 0.0465 0.0403 ND 0.188 0.163 Heptane 0.0467 0.0458 0.0403 0.191 0.188 0.165 Trichloroethene ND 0.0461 0.0403 ND 0.247 0.217 1,2-Dichloropropene ND 0.0451 0.0403 ND 0.209 0.186 Methyl methacrylate ND 0.0473 0.0403 ND 0.194 0.165 1,4-Dioxane ND 0.0460 0.0403 ND 0.166 0.145 Bromodichloromethane ND 0.0456 0.0403 ND 0.306 0.270 cis-1,3-Dichloropropene ND 0.0450 0.0403 ND 0.204 0.183 Methyl isobutyl ketone 0.161 0.0471 0.0403 0.660 0.193 0.165 Toluene 0.217 0.0464 0.0403 0.818 0.175 0.152 trans-1,3-Dichloropropene ND 0.0466 0.0403 ND 0.212 0.183 1,1,2-Trichloroethane ND 0.0461 0.0403 ND 0.251 0.220 Tetrachloroethene ND 0.0461 0.0403 ND 0.313 0.274 2-Hexanone (Methyl butyl ketone) 0.121 0.118 0.0403 0.496 0.483 0.165 m Dibromochloromethane ND 0.0455 0.0403 ND 0.388 0.344 1,2-Dibromoethane ND 0.0465 0.0403 ND 0.357 0.310 Chlorobenzene ND 0.0473 0.0403 ND 0.218 0.186 Ethylbenzene 0.106 0.0451 0.0403 0.459 0.196 0.175 1,1,1,2-Tetrachloroethane ND 0.0460 0.0403 ND 0.316 0.277 m-/p-Xylenes 0.334 0.0465 0.0403 1.45 0.202 0.175 EA# 0520-176 Page 8 of 37 Quantitation Report Enthalpy Analytical, LLC Sample Name : IA-3 Sample Info 0520-176; *0.667=750mL load; Can #000020 Data File X2001894.D Dilution 0.667 Pressurization Factor 1.728 Acquisition Date 2020-05-27 16:03:28 Instrument Method T015-SCN.M Matrix AIR Concentration RL MDL Concentration RL MDL Target Compound -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- (PPBV) (PPBV) (PPBV) (ug/m3) (ug/m3) (ug/m3) Flag o-Xylene 0.143 0.0456 0.0403 0.622 0.198 0.175 Styrene ND 0.0448 0.0403 ND 0.191 0.172 Bromoform ND 0.0461 0.0403 ND 0.476 0.417 1,1,2,2-Tetrachloroethane ND 0.0461 0.0403 ND 0.316 0.277 4-Ethyltoluene ND 0.0463 0.0403 ND 0.228 0.198 2-Chlorotoluene ND 0.0463 0.0403 ND 0.240 0.209 1,3,5-Trimethylbenzene 0.0590 0.0463 0.0403 0.290 0.228 0.198 1,2,4-Trimethylbenzene 0.175 0.0458 0.0403 0.860 0.225 0.198 m 1,3-Dichlorobenzene ND 0.0469 0.0403 ND 0.282 0.243 1,4-Dichlorobenzene ND 0.0463 0.0403 ND 0.279 0.243 Benzyl chloride ND 0.0459 0.0403 ND 0.238 0.209 1,2-Dichlorobenzene ND 0.0468 0.0403 ND 0.281 0.243 1,2,4-Trichlorobenzene ND 0.0467 0.0403 ND 0.346 0.299 Hexachlorobutadiene ND 0.0468 0.0403 ND 0.499 0.430 Naphthalene ND 0.0481 0.0403 ND 0.252 0.211 1-Bromopropane ND 0.0450 0.0403 ND 0.226 0.203 1-Octene ND 0.0447 0.0403 ND 0.205 0.185 n-Octane ND 0.0462 0.0403 ND 0.216 0.188 Isopropylbenzene ND 0.0465 0.0403 ND 0.229 0.198 n-Propylbenzene ND 0.0467 0.0403 ND 0.229 0.198 Retention Time Concentration Internal Standards Response (min) (PPBV) Flag ------------------------------------------------------------------------------------------------------------------------------------------ Bromochloromethane (IS) 496,823 11.86 5.00 PASS 1,4-Dicuorobenzene (IS) 1,972,169 13.62 5.04 PASS Chlorobenzene-d5 (IS) 1,715,607 17.80 4.80 PASS (ND) = Not Detected * (3) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40% EA# 0520-176 Page 9 of 37 Quantitation Report Enthalpy Analytical, LLC Sample Name Sample Info Data File Dilution Pressurization Factor Acquisition Date Instrument Method Matrix : IA-4 0520-176; *0.667=750mL load; Can *0724 X2001895.D 0.667 1.724 2020-05-27 17:04:03 TO15-SCN.M AIR Concentration RL MDL Concentration RL MDL Target Compound -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- (PPBV) (PPBV) (PPB1� (ug/m3) (ug/m3) (ug/m3) Flag* Propylene 0.312 0.0441 0.0402 0.536 0.0758 0.0693 Freon 12 (CC12F2) 0.537 0.0442 0.0402 2.65 0.219 0.199 Freon 114 (C2Cl2F4) ND 0.0458 0.0402 ND 0.320 0.281 Chloromethane 0.694 0.0447 0.0402 1.43 0.0923 0.0831 Chloroethene (Vinyl chloride) ND 0.0459 0.0402 ND 0.117 0.103 1,3-Butadiene ND 0.0444 0.0402 ND 0.0983 0.0890 Bromomethane ND 0.0451 0.0402 ND 0.175 0.156 Chloroethane ND 0.0461 0.0402 ND 0.122 0.106 Bromoethene (Vinyl bromide) ND 0.0451 0.0402 ND 0.197 0.176 Freon 11(CC13F) 0.276 0.0475 0.0402 1.55 0.267 0.226 Ethanol 9.29 0.0460 0.0460 17.5 0.0867 0.0867 Acrolein 0.228 0.0446 0.0402 0.523 0.102 0.0923 Freon 113 (C2Cl3F3) 0.256 0.0456 0.0402 1.96 0.349 0.308 1,1-Dichloroethene ND 0.0458 0.0402 ND 0.181 0.160 Acetone 3.92 0.0454 0.0402 9.31 0.108 0.0956 Carbon disulfide 0.0501 0.0457 0.0402 0.156 0.142 0.125 Isopropyl alcohol 0.789 0.0455 0.0402 1.94 0.112 0.0989 AIIyl chloride (3-chloropropene) ND 0.0459 0.0402 ND 0.144 0.126 Acetonitrile 0.158 0.0454 0.0402 0.266 0.0762 0.0676 Methylene chloride 0.177 0.115 0.115 0.613 0.400 0.400 trans-1,2-Dichloroethene ND 0.0465 0.0402 ND 0.184 0.160 Methyl tert-butyl ether ND 0.0465 0.0402 ND 0.167 0.145 Acrylonitrile ND 0.0461 0.0402 ND 0.100 0.0873 Hexane 0.0611 0.0463 0.0402 0.215 0.163 0.142 1,1-Dichloroethane ND 0.0448 0.0402 ND 0.182 0.163 Vinyl acetate ND 0.0461 0.0402 ND 0.162 0.142 cis-1,2-Dichloroethene ND 0.0457 0.0402 ND 0.181 0.160 Methyl ethyl ketone (2-Butanone) 0.447 0.0467 0.0402 1.32 0.138 0.119 Ethyl acetate 0.162 0.0460 0.0402 0.584 0.166 0.145 Chloroform ND 0.0462 0.0402 ND 0.226 0.197 Tetrahydrofuran 0.142 0.0459 0.0402 0.420 0.135 0.119 1,1,1-Trichloroethane ND 0.0454 0.0402 ND 0.247 0.220 Cyclohexane ND 0.0462 0.0402 ND 0.159 0.139 Carbon tetrachloride 0.0788 0.0460 0.0402 0.496 0.290 0.253 Benzene 0.0782 0.0452 0.0402 0.250 0.144 0.129 2,2,4-trimethylpentane ND 0.0466 0.0402 ND 0.218 0.188 1,2-Dichloroethane ND 0.0464 0.0402 ND 0.188 0.163 Heptane 0.0645 0.0457 0.0402 0.264 0.187 0.165 Trichloroethene ND 0.0460 0.0402 ND 0.247 0.216 1,2-Dichloropropene ND 0.0450 0.0402 ND 0.208 0.186 Methyl methacrylate ND 0.0472 0.0402 ND 0.193 0.165 1,4-Dioxane ND 0.0459 0.0402 ND 0.165 0.145 Bromodichloromethane ND 0.0455 0.0402 ND 0.305 0.270 cis-1,3-Dichloropropene ND 0.0449 0.0402 ND 0.204 0.183 Methyl isobutyl ketone 0.0655 0.0470 0.0402 0.268 0.192 0.165 Toluene 0.215 0.0463 0.0402 0.812 0.175 0.152 trans-1,3-Dichloropropene ND 0.0465 0.0402 ND 0.211 0.183 1,1,2-Trichloroethane ND 0.0460 0.0402 ND 0.251 0.220 Tetrachloroethene ND 0.0460 0.0402 ND 0.312 0.273 2-Hexanone (Methyl butyl ketone) 0.0753 0.118 0.0402 0.308 0.482 0.165 J Dibromochloromethane ND 0.0454 0.0402 ND 0.387 0.343 1,2-Dibromoethane ND 0.0464 0.0402 ND 0.356 0.309 Chlorobenzene ND 0.0472 0.0402 ND 0.217 0.185 Ethylbenzene 0.0913 0.0450 0.0402 0.396 0.196 0.175 1,1,1,2-Tetrachloroethane ND 0.0459 0.0402 ND 0.315 0.276 m-/p-Xylenes 0.283 0.0464 0.0402 1.23 0.202 0.175 EA# 0520-176 Page 10 of 37 Quantitation Report Enthalpy Analytical, LLC Sample Name : IA-4 Sample Info 0520-176; *0.667=750mL load; Can #0724 Data File X2001895.D Dilution 0.667 Pressurization Factor 1.724 Acquisition Date 2020-05-27 17:04:03 Instrument Method TO15-SCN.M Matrix AIR Concentration RL MDL Concentration RL MDL Target Compound -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- (PPBV) (PPBV) (PPBV) (ug/m3) (ug/m3) (ug/m3) Flag o-Xylene 0.125 0.0455 0.0402 0.543 0.198 0.175 Styrene ND 0.0447 0.0402 ND 0.190 0.171 Bromoform ND 0.0460 0.0402 ND 0.475 0.416 1,1,2,2-Tetrachloroethane ND 0.0460 0.0402 ND 0.315 0.276 4-Ethyltoluene ND 0.0462 0.0402 ND 0.227 0.198 2-Chlorotoluene ND 0.0462 0.0402 ND 0.239 0.208 1,3,5-Trimethylbenzene 0.0501 0.0462 0.0402 0.246 0.227 0.198 1,2,4-Trimethylbenzene 0.152 0.0457 0.0402 0.747 0.225 0.198 m 1,3-Dichlorobenzene ND 0.0468 0.0402 ND 0.281 0.242 1,4-Dichlorobenzene ND 0.0462 0.0402 ND 0.278 0.242 Benzyl chloride ND 0.0458 0.0402 ND 0.237 0.208 1,2-Dichlorobenzene ND 0.0467 0.0402 ND 0.281 0.242 1,2,4-Trichlorobenzene ND 0.0466 0.0402 ND 0.346 0.299 Hexachlorobutadiene ND 0.0467 0.0402 ND 0.498 0.429 Naphthalene ND 0.0480 0.0402 ND 0.251 0.211 1-Bromopropane ND 0.0448 0.0402 ND 0.226 0.202 1-Octene ND 0.0446 0.0402 ND 0.205 0.185 n-Octane ND 0.0461 0.0402 ND 0.215 0.188 Isopropylbenzene ND 0.0464 0.0402 ND 0.228 0.198 n-Propylbenzene ND 0.0465 0.0402 ND 0.229 0.198 Retention Time Concentration Internal Standards Response (min) (PPBV) Flag ------------------------------------------------------------------------------------------------------------------------------------------ Bromochloromethane (IS) 496,461 11.86 5.00 PASS 1,4-Dicuorobenzene (IS) 1,980,723 13.62 5.04 PASS Chlorobenzene-d5 (IS) 1,714,027 17.80 4.80 PASS (ND) = Not Detected * (3) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40% EA# 0520-176 Page 11 of 37 Quantitation Report Enthalpy Analytical, LLC Sample Name Sample Info Data File Dilution Pressurization Factor Acquisition Date Instrument Method Matrix : IA-5 0520-176; *0.667=750mL load; Can *1478 X2001896.D 0.667 1.732 2020-05-27 18:04:39 TO15-SCN.M AIR Concentration RL MDL Concentration RL MDL Target Compound -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- (PPBV) (PPBV) (PPB1� (ug/m3) (ug/m3) (ug/m3) Flag* Propylene 0.346 0.0443 0.0404 0.595 0.0762 0.0696 Freon 12 (CC12F2) 0.542 0.0444 0.0404 2.68 0.220 0.200 Freon 114 (C2Cl2F4) ND 0.0460 0.0404 ND 0.322 0.283 Chloromethane 0.715 0.0449 0.0404 1.48 0.0927 0.0835 Chloroethene (Vinyl chloride) ND 0.0461 0.0404 ND 0.118 0.103 1,3-Butadiene ND 0.0446 0.0404 ND 0.0988 0.0895 Bromomethane ND 0.0453 0.0404 ND 0.176 0.157 Chloroethane ND 0.0463 0.0404 ND 0.122 0.107 Bromoethene (Vinyl bromide) ND 0.0453 0.0404 ND 0.198 0.177 Freon 11(CC13F) 0.277 0.0477 0.0404 1.56 0.268 0.227 Ethanol 10.0 0.0462 0.0462 18.9 0.0871 0.0871 Acrolein 0.276 0.0448 0.0404 0.633 0.103 0.0927 Freon 113 (C2Cl3F3) 0.206 0.0458 0.0404 1.58 0.351 0.310 1,1-Dichloroethene ND 0.0460 0.0404 ND 0.182 0.160 Acetone 4.46 0.0456 0.0404 10.6 0.108 0.0960 Carbon disulfide 0.0513 0.0459 0.0404 0.160 0.143 0.126 Isopropyl alcohol 0.902 0.0457 0.0404 2.22 0.112 0.0994 AIIyl chloride (3-chloropropene) ND 0.0461 0.0404 ND 0.144 0.127 Acetonitrile 0.234 0.0456 0.0404 0.393 0.0766 0.0679 m Methylene chloride 0.185 0.116 0.116 0.644 0.402 0.402 trans-1,2-Dichloroethene ND 0.0467 0.0404 ND 0.185 0.160 Methyl tert-butyl ether ND 0.0467 0.0404 ND 0.168 0.146 Acrylonitrile ND 0.0463 0.0404 ND 0.101 0.0878 Hexane 0.0691 0.0465 0.0404 0.244 0.164 0.143 1,1-Dichloroethane ND 0.0451 0.0404 ND 0.182 0.164 Vinyl acetate ND 0.0463 0.0404 ND 0.163 0.142 cis-1,2-Dichloroethene ND 0.0459 0.0404 ND 0.182 0.160 Methyl ethyl ketone (2-Butanone) 0.551 0.0469 0.0404 1.63 0.138 0.119 m Ethyl acetate 0.700 0.0463 0.0404 2.52 0.167 0.146 Chloroform ND 0.0464 0.0404 ND 0.227 0.197 Tetrahydrofuran 0.144 0.0461 0.0404 0.426 0.136 0.119 1,1,1-Trichloroethane ND 0.0456 0.0404 ND 0.249 0.221 Cyclohexane ND 0.0464 0.0404 ND 0.160 0.139 Carbon tetrachloride 0.0878 0.0463 0.0404 0.552 0.291 0.254 Benzene 0.0965 0.0454 0.0404 0.308 0.145 0.129 2,2,4-trimethylpentane ND 0.0468 0.0404 ND 0.219 0.189 1,2-Dichloroethane ND 0.0466 0.0404 ND 0.189 0.164 Heptane 0.0613 0.0459 0.0404 0.251 0.188 0.166 Trichloroethene ND 0.0462 0.0404 ND 0.248 0.217 1,2-Dichloropropene ND 0.0452 0.0404 ND 0.209 0.187 Methyl methacrylate ND 0.0475 0.0404 ND 0.194 0.166 1,4-Dioxane ND 0.0461 0.0404 ND 0.166 0.146 Bromodichloromethane ND 0.0457 0.0404 ND 0.306 0.271 cis-1,3-Dichloropropene ND 0.0451 0.0404 ND 0.205 0.184 Methyl isobutyl ketone 0.135 0.0472 0.0404 0.552 0.193 0.166 m Toluene 0.224 0.0465 0.0404 0.845 0.175 0.152 trans-1,3-Dichloropropene ND 0.0467 0.0404 ND 0.212 0.184 1,1,2-Trichloroethane ND 0.0462 0.0404 ND 0.252 0.221 Tetrachloroethene ND 0.0462 0.0404 ND 0.313 0.274 2-Hexanone (Methyl butyl ketone) 0.111 0.118 0.0404 0.455 0.485 0.166 J Dibromochloromethane ND 0.0456 0.0404 ND 0.389 0.344 1,2-Dibromoethane ND 0.0466 0.0404 ND 0.358 0.311 Chlorobenzene ND 0.0474 0.0404 ND 0.218 0.186 Ethylbenzene 0.0942 0.0452 0.0404 0.409 0.196 0.176 1,1,1,2-Tetrachloroethane ND 0.0461 0.0404 ND 0.317 0.278 m-/p-Xylenes 0.303 0.0466 0.0404 1.31 0.202 0.176 EA# 0520-176 Page 12 of 37 Quantitation Report Enthalpy Analytical, LLC Sample Name : IA-5 Sample Info 0520-176; *0.667=750mL load; Can #1478 Data File X2001896.D Dilution 0.667 Pressurization Factor 1.732 Acquisition Date 2020-05-27 18:04:39 Instrument Method TO15-SCN.M Matrix AIR Concentration RL MDL Concentration RL MDL Target Compound -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- (PPBV) (PPBV) (PPBV) (ug/m3) (ug/m3) (ug/m3) Flag o-Xylene 0.122 0.0457 0.0404 0.528 0.199 0.176 Styrene ND 0.0449 0.0404 ND 0.191 0.172 Bromoform ND 0.0462 0.0404 ND 0.477 0.418 1,1,2,2-Tetrachloroethane ND 0.0462 0.0404 ND 0.317 0.278 4-Ethyltoluene ND 0.0464 0.0404 ND 0.228 0.199 2-Chlorotoluene ND 0.0464 0.0404 ND 0.240 0.209 1,3,5-Trimethylbenzene 0.0505 0.0464 0.0404 0.248 0.228 0.199 1,2,4-Trimethylbenzene 0.154 0.0459 0.0404 0.759 0.226 0.199 m 1,3-Dichlorobenzene ND 0.0470 0.0404 ND 0.283 0.243 1,4-Dichlorobenzene ND 0.0464 0.0404 ND 0.279 0.243 Benzyl chloride ND 0.0460 0.0404 ND 0.238 0.209 1,2-Dichlorobenzene ND 0.0469 0.0404 ND 0.282 0.243 1,2,4-Trichlorobenzene ND 0.0468 0.0404 ND 0.347 0.300 Hexachlorobutadiene ND 0.0469 0.0404 ND 0.500 0.431 Naphthalene ND 0.0482 0.0404 ND 0.253 0.212 1-Bromopropane ND 0.0451 0.0404 ND 0.227 0.203 1-Octene ND 0.0448 0.0404 ND 0.206 0.186 n-Octane ND 0.0463 0.0404 ND 0.216 0.189 Isopropylbenzene ND 0.0466 0.0404 ND 0.229 0.199 n-Propylbenzene ND 0.0468 0.0404 ND 0.230 0.199 Retention Time Concentration Internal Standards Response (min) (PPBV) Flag ------------------------------------------------------------------------------------------------------------------------------------------ Bromochloromethane (IS) 501,668 11.85 5.00 PASS 1,4-Dicuorobenzene (IS) 2,016,004 13.61 5.04 PASS Chlorobenzene-d5 (IS) 1,735,218 17.80 4.80 PASS (ND) = Not Detected * (3) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40% EA# 0520-176 Page 13 of 37 Quantitation Report Enthalpy Analytical, LLC Sample Name Sample Info Data File Dilution Pressurization Factor Acquisition Date Instrument Method Matrix : IA-6 0520-176; *0.667=750mL load; Can *0719 X2001898.D 0.667 1.748 2020-05-27 20:05:26 T015-SCN.M AIR Concentration RL MDL Concentration RL MDL Target Compound -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- (PPBV) (PPBV) (PPB1� (ug/m3) (ug/m3) (ug/m3) Flag* Propylene 0.430 0.0447 0.0408 0.739 0.0769 0.0702 m Freon 12 (CC12F2) 0.704 0.0448 0.0408 3.48 0.222 0.202 Freon 114 (C2C12F4) ND 0.0465 0.0408 ND 0.325 0.285 Chloromethane 0.674 0.0453 0.0408 1.39 0.0936 0.0843 Chloroethene (Vinyl chloride) ND 0.0465 0.0408 ND 0.119 0.104 1,3-Butadiene ND 0.0451 0.0408 ND 0.0997 0.0903 Bromomethane ND 0.0457 0.0408 ND 0.177 0.158 Chloroethane ND 0.0467 0.0408 ND 0.123 0.108 Bromoethene (Vinyl bromide) ND 0.0458 0.0408 ND 0.200 0.178 Freon 11 (CC13F) 0.341 0.0481 0.0408 1.92 0.270 0.229 Ethanol 5.06 0.0466 0.0466 9.53 0.0879 0.0879 Acrolein 0.350 0.0452 0.0408 0.802 0.104 0.0936 Freon 113 (C2C13F3) 0.134 0.0462 0.0408 1.03 0.354 0.313 1,1-Dichloroethene ND 0.0464 0.0408 ND 0.184 0.162 Acetone 8.71 0.0461 0.0408 20.7 0.109 0.0969 Carbon disulfide 0.0803 0.0463 0.0408 0.250 0.144 0.127 Isopropyl alcohol 1.96 0.0462 0.0408 4.81 0.113 0.100 AIIyl chloride (3-chloropropene) ND 0.0465 0.0408 ND 0.146 0.128 Acetonitrile 0.212 0.0460 0.0408 0.356 0.0773 0.0685 Methylene chloride 0.148 0.117 0.117 0.516 0.406 0.406 trans-1,2-Dichloroethene ND 0.0471 0.0408 ND 0.187 0.162 Methyl tert-butyl ether ND 0.0471 0.0408 ND 0.170 0.147 Acrylonitrile ND 0.0468 0.0408 ND 0.102 0.0886 Hexane 0.0725 0.0470 0.0408 0.255 0.166 0.144 1,1-Dichloroethane ND 0.0455 0.0408 ND 0.184 0.165 Vinyl acetate ND 0.0468 0.0408 ND 0.165 0.144 cis-1,2-Dichloroethene ND 0.0464 0.0408 ND 0.184 0.162 Methyl ethyl ketone (2-Butanone) 0.931 0.0473 0.0408 2.74 0.140 0.120 Ethyl acetate ND 0.0467 0.0408 ND 0.168 0.147 Chloroform ND 0.0469 0.0408 ND 0.229 0.199 Tetrahydrofuran 0.278 0.0465 0.0408 0.819 0.137 0.120 1,1,1-Trichloroethane ND 0.0460 0.0408 ND 0.251 0.223 Cyclohexane ND 0.0469 0.0408 ND 0.161 0.140 Carbon tetrachloride 0.0788 0.0467 0.0408 0.496 0.294 0.257 Benzene 0.210 0.0458 0.0408 0.671 0.146 0.130 2,2,4-trimethylpentane ND 0.0472 0.0408 ND 0.221 0.191 1,2-Dichloroethane ND 0.0471 0.0408 ND 0.190 0.165 Heptane 0.0813 0.0464 0.0408 0.333 0.190 0.167 Trichloroethene ND 0.0466 0.0408 ND 0.250 0.219 1,2-Dichloropropene ND 0.0457 0.0408 ND 0.211 0.189 Methyl methacrylate ND 0.0479 0.0408 ND 0.196 0.167 1,4-Dioxane 0.131 0.0465 0.0408 0.472 0.168 0.147 Bromodichloromethane ND 0.0461 0.0408 ND 0.309 0.273 cis-1,3-Dichloropropene ND 0.0455 0.0408 ND 0.207 0.185 Methyl isobutyl ketone 0.269 0.0476 0.0408 1.10 0.195 0.167 Toluene 0.243 0.0470 0.0408 0.914 0.177 0.154 trans-1,3-Dichloropropene ND 0.0471 0.0408 ND 0.214 0.185 1,1,2-Trichloroethane ND 0.0466 0.0408 ND 0.254 0.223 Tetrachloroethene ND 0.0466 0.0408 ND 0.316 0.277 2-Hexanone (Methyl butyl ketone) 0.422 0.119 0.0408 1.73 0.489 0.167 m Dibromochloromethane ND 0.0460 0.0408 ND 0.392 0.348 1,2-Dibromoethane ND 0.0470 0.0408 ND 0.361 0.314 Chlorobenzene ND 0.0478 0.0408 ND 0.220 0.188 Ethylbenzene 0.242 0.0457 0.0408 1.05 0.198 0.177 1,1,1,2-Tetrachloroethane ND 0.0465 0.0408 ND 0.320 0.280 m-/p-Xylenes 0.715 0.0471 0.0408 3.10 0.204 0.177 EA# 0520-176 Page 14 of 37 Quantitation Report Enthalpy Analytical, LLC Sample Name : IA-6 Sample Info 0520-176; *0.667=750mL load; Can *0719 Data File X2001898.13 Dilution 0.667 Pressurization Factor 1.748 Acquisition Date 2020-05-27 20:05:26 Instrument Method T015-SCN.M Matrix AIR Concentration RL MDL Concentration RL MDL Target Compound -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- (PPBV) (PPBV) (PPBV) (ug/m3) (ug/m3) (ug/m3) Flag o-Xylene 0.258 0.0462 0.0408 1.12 0.200 0.177 Styrene 0.112 0.0453 0.0408 0.479 0.193 0.174 Bromoform ND 0.0466 0.0408 ND 0.482 0.422 1,1,2,2-Tetrachloroethane ND 0.0466 0.0408 ND 0.320 0.280 4-Ethyltoluene 0.0456 0.0469 0.0408 0.224 0.230 0.201 3 2-Chlorotoluene ND 0.0468 0.0408 ND 0.242 0.211 1,3,5-Trimethylbenzene 0.0664 0.0468 0.0408 0.326 0.230 0.201 1,2,4-Trimethylbenzene 0.218 0.0463 0.0408 1.07 0.228 0.201 1,3-Dichlorobenzene ND 0.0474 0.0408 ND 0.285 0.245 1,4-Dichlorobenzene ND 0.0469 0.0408 ND 0.282 0.245 Benzyl chloride ND 0.0465 0.0408 ND 0.240 0.211 1,2-Dichlorobenzene ND 0.0473 0.0408 ND 0.285 0.245 1,2,4-Trichlorobenzene ND 0.0472 0.0408 ND 0.350 0.303 Hexachlorobutadiene ND 0.0473 0.0408 ND 0.505 0.435 Naphthalene 0.101 0.0486 0.0408 0.528 0.255 0.214 1-Bromopropane ND 0.0455 0.0408 ND 0.229 0.205 1-Octene ND 0.0452 0.0408 ND 0.208 0.187 n-Octane 0.0530 0.0467 0.0408 0.248 0.218 0.191 m Isopropylbenzene 0.0458 0.0471 0.0408 0.225 0.231 0.201 3 n-Propylbenzene ND 0.0472 0.0408 ND 0.232 0.201 Retention Time Concentration Internal Standards Response (min) (PPBV) Flag ------------------------------------------------------------------------------------------------------------------------------------------ Bromochloromethane (IS) 532,046 11.85 5.00 PASS 1,4-Dicuorobenzene (IS) 2,109,884 13.61 5.04 PASS Chlorobenzene-d5 (IS) 1,845,806 17.80 4.80 PASS (ND) = Not Detected * (3) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40% EA# 0520-176 Page 15 of 37 Quantitation Report Enthalpy Analytical, LLC Sample Name Sample Info Data File Dilution Pressurization Factor Acquisition Date Instrument Method Matrix : OA-1 0520-176; *0.667=750mL load; Can *0723 X2001899.D 0.667 1.774 2020-05-27 21:05:58 T015-SCN.M AIR Concentration RL MDL Concentration RL MDL Target Compound -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- (PPBV) (PPBV) (PPBV) (ug/m3) (ug/m3) (ug/m3) Flag* Propylene 0.186 0.0453 0.0414 0.321 0.0780 0.0713 m Freon 12 (CC12F2) 0.468 0.0455 0.0414 2.31 0.225 0.205 Freon 114 (C2C12F4) ND 0.0471 0.0414 ND 0.330 0.290 Chloromethane 0.665 0.0460 0.0414 1.37 0.0950 0.0855 Chloroethene (Vinyl chloride) ND 0.0472 0.0414 ND 0.121 0.106 1,3-Butadiene ND 0.0457 0.0414 ND 0.101 0.0916 Bromomethane ND 0.0464 0.0414 ND 0.180 0.161 Chloroethane ND 0.0474 0.0414 ND 0.125 0.109 Bromoethene (Vinyl bromide) ND 0.0464 0.0414 ND 0.203 0.181 Freon 11(CC13F) 0.238 0.0488 0.0414 1.34 0.274 0.233 Ethanol 0.885 0.0473 0.0473 1.67 0.0892 0.0892 Acrolein 0.0680 0.0459 0.0414 0.156 0.105 0.0950 m Freon 113 (C2Cl3F3) 0.0712 0.0469 0.0414 0.545 0.359 0.317 1,1-Dichloroethene ND 0.0471 0.0414 ND 0.187 0.164 Acetone 1.84 0.0467 0.0414 4.38 0.111 0.0984 m Carbon disulfide ND 0.0470 0.0414 ND 0.146 0.129 Isopropyl alcohol 0.183 0.0469 0.0414 0.451 0.115 0.102 AIIyl chloride (3-chloropropene) ND 0.0472 0.0414 ND 0.148 0.130 Acetonitrile 0.184 0.0467 0.0414 0.309 0.0784 0.0695 Methylene chloride 0.168 0.119 0.119 0.582 0.412 0.412 m trans-1,2-Dichloroethene ND 0.0478 0.0414 ND 0.190 0.164 Methyl tert-butyl ether ND 0.0478 0.0414 ND 0.172 0.149 Acrylonitrile ND 0.0475 0.0414 ND 0.103 0.0899 Hexane ND 0.0477 0.0414 ND 0.168 0.146 1,1-Dichloroethane ND 0.0461 0.0414 ND 0.187 0.168 Vinyl acetate ND 0.0475 0.0414 ND 0.167 0.146 cis-1,2-Dichloroethene ND 0.0470 0.0414 ND 0.187 0.164 Methyl ethyl ketone (2-Butanone) 0.148 0.0480 0.0414 0.435 0.142 0.122 Ethyl acetate 0.0855 0.0474 0.0414 0.308 0.171 0.149 m Chloroform ND 0.0476 0.0414 ND 0.232 0.202 Tetrahydrofuran ND 0.0472 0.0414 ND 0.139 0.122 1,1,1-Trichloroethane ND 0.0467 0.0414 ND 0.255 0.226 Cyclohexane ND 0.0476 0.0414 ND 0.164 0.143 Carbon tetrachloride 0.0798 0.0474 0.0414 0.502 0.298 0.261 Benzene 0.0504 0.0465 0.0414 0.161 0.149 0.132 2,2,4-trimethylpentane ND 0.0479 0.0414 ND 0.224 0.193 1,2-Dichloroethane ND 0.0478 0.0414 ND 0.193 0.168 Heptane ND 0.0470 0.0414 ND 0.193 0.170 Trichloroethene ND 0.0473 0.0414 ND 0.254 0.223 1,2-Dichloropropene ND 0.0463 0.0414 ND 0.214 0.191 Methyl methacrylate ND 0.0486 0.0414 ND 0.199 0.170 1,4-Dioxane ND 0.0472 0.0414 ND 0.170 0.149 Bromodichloromethane ND 0.0468 0.0414 ND 0.314 0.277 cis-1,3-Dichloropropene ND 0.0462 0.0414 ND 0.210 0.188 Methyl isobutyl ketone ND 0.0483 0.0414 ND 0.198 0.170 Toluene 0.0834 0.0477 0.0414 0.314 0.180 0.156 trans-1,3-Dichloropropene ND 0.0479 0.0414 ND 0.217 0.188 1,1,2-Trichloroethane ND 0.0473 0.0414 ND 0.258 0.226 Tetrachloroethene ND 0.0473 0.0414 ND 0.321 0.281 2-Hexanone (Methyl butyl ketone) ND 0.121 0.0414 ND 0.496 0.170 Dibromochloromethane ND 0.0467 0.0414 ND 0.398 0.353 1,2-Dibromoethane ND 0.0477 0.0414 ND 0.367 0.318 Chlorobenzene ND 0.0486 0.0414 ND 0.224 0.191 Ethylbenzene ND 0.0463 0.0414 ND 0.201 0.180 1,1,1,2-Tetrachloroethane ND 0.0472 0.0414 ND 0.324 0.284 m-/p-Xylenes 0.0456 0.0478 0.0414 0.198 0.207 0.180 3 EA# 0520-176 Page 16 of 37 Quantitation Report Enthalpy Analytical, LLC Sample Name Sample Info Data File Dilution Pressurization Factor Acquisition Date Instrument Method Matrix : OA-1 0520-176; *0.667=750mL load; Can #0723 X2001899.D 0.667 1.774 2020-05-27 21:05:58 TO15-SCN.M AIR Concentration RL MDL Concentration RL MDL Target Compound -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- (PPBV) (PPBV) (PPBV) (ug/m3) (ug/m3) (ug/m3) Flag o-Xylene ND 0.0469 0.0414 ND 0.203 0.180 Styrene ND 0.0460 0.0414 ND 0.196 0.176 Bromoform ND 0.0473 0.0414 ND 0.489 0.428 1,1,2,2-Tetrachloroethane ND 0.0473 0.0414 ND 0.325 0.284 4-Ethyltoluene ND 0.0476 0.0414 ND 0.234 0.204 2-Chlorotoluene ND 0.0475 0.0414 ND 0.246 0.214 1,3,5-Trimethylbenzene ND 0.0475 0.0414 ND 0.234 0.204 1,2,4-Trimethylbenzene ND 0.0470 0.0414 ND 0.231 0.204 1,3-Dichlorobenzene ND 0.0481 0.0414 ND 0.289 0.249 1,4-Dichlorobenzene ND 0.0476 0.0414 ND 0.286 0.249 Benzyl chloride ND 0.0471 0.0414 ND 0.244 0.214 1,2-Dichlorobenzene ND 0.0480 0.0414 ND 0.289 0.249 1,2,4-Trichlorobenzene ND 0.0479 0.0414 ND 0.356 0.307 Hexachlorobutadiene ND 0.0480 0.0414 ND 0.512 0.442 Naphthalene ND 0.0493 0.0414 ND 0.259 0.217 1-Bromopropane ND 0.0461 0.0414 ND 0.232 0.208 1-Octene ND 0.0459 0.0414 ND 0.211 0.190 n-Octane ND 0.0474 0.0414 ND 0.222 0.193 Isopropyl benzene ND 0.0478 0.0414 ND 0.235 0.204 n-Propylbenzene ND 0.0479 0.0414 ND 0.235 0.204 Retention Time Concentration Internal Standards ------------------------------------------------------------------------------------------------------------------------------------------ Response (min) (PPBV) Flag Bromochloromethane (IS) 559,321 11.85 5.00 PASS 1,4-Difuorobenzene (IS) 2,199,283 13.62 5.04 PASS Chlorobenzene-d5 (IS) 1,918,812 17.80 4.80 PASS (ND) = Not Detected * (3) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40% EA# 0520-176 Page 17 of 37 Quantitation Report Enthalpy Analytical, LLC Sample Name Sample Info Data File Dilution Pressurization Factor Acquisition Date Instrument Method Matrix : DUP-1 0520-176; *0.667=750mL load; Can *0744 X2001900.D 0.667 1.766 2020-05-27 22:06:38 T015-SCN.M AIR Concentration RL MDL Concentration RL MDL Target Compound -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- (PPBV) (PPBV) (PPB1� (ug/m3) (ug/m3) (ug/m3) Flag* Propylene 0.346 0.0451 0.0412 0.596 0.0777 0.0710 Freon 12 (CC12F2) 0.557 0.0453 0.0412 2.76 0.224 0.204 Freon 114 (C2C12F4) ND 0.0469 0.0412 ND 0.328 0.288 Chloromethane 0.658 0.0458 0.0412 1.36 0.0946 0.0851 Chloroethene (Vinyl chloride) ND 0.0470 0.0412 ND 0.120 0.105 1,3-Butadiene ND 0.0455 0.0412 ND 0.101 0.0912 Bromomethane ND 0.0462 0.0412 ND 0.179 0.160 Chloroethane ND 0.0472 0.0412 ND 0.125 0.109 Bromoethene (Vinyl bromide) ND 0.0462 0.0412 ND 0.202 0.180 Freon 11(CC13F) 0.277 0.0486 0.0412 1.56 0.273 0.232 Ethanol 11.8 0.0471 0.0471 22.2 0.0888 0.0888 Acrolein 0.326 0.0457 0.0412 0.748 0.105 0.0945 Freon 113 (C2Cl3F3) 0.190 0.0467 0.0412 1.46 0.358 0.316 1,1-Dichloroethene ND 0.0469 0.0412 ND 0.186 0.163 Acetone 4.75 0.0465 0.0412 11.3 0.111 0.0979 Carbon disulfide 0.0415 0.0468 0.0412 0.129 0.146 0.128 3 Isopropyl alcohol 1.18 0.0466 0.0412 2.89 0.115 0.101 AIIyl chloride (3-chloropropene) ND 0.0470 0.0412 ND 0.147 0.129 Acetonitrile 0.247 0.0465 0.0412 0.415 0.0781 0.0692 Methylene chloride 0.207 0.118 0.118 0.720 0.410 0.410 trans-1,2-Dichloroethene ND 0.0476 0.0412 ND 0.189 0.163 Methyl tert-butyl ether ND 0.0476 0.0412 ND 0.172 0.149 Acrylonitrile ND 0.0473 0.0412 ND 0.103 0.0895 Hexane 0.0833 0.0474 0.0412 0.293 0.167 0.145 1,1-Dichloroethane ND 0.0459 0.0412 ND 0.186 0.167 Vinyl acetate ND 0.0473 0.0412 ND 0.166 0.145 cis-1,2-Dichloroethene ND 0.0468 0.0412 ND 0.186 0.163 Methyl ethyl ketone (2-Butanone) 0.541 0.0478 0.0412 1.59 0.141 0.122 Ethyl acetate 0.270 0.0472 0.0412 0.972 0.170 0.149 Chloroform ND 0.0474 0.0412 ND 0.231 0.201 Tetrahydrofuran 0.193 0.0470 0.0412 0.570 0.139 0.122 1,1,1-Trichloroethane ND 0.0465 0.0412 ND 0.253 0.225 Cyclohexane ND 0.0474 0.0412 ND 0.163 0.142 Carbon tetrachloride 0.0791 0.0472 0.0412 0.497 0.297 0.259 Benzene 0.0966 0.0463 0.0412 0.309 0.148 0.132 2,2,4-trimethylpentane ND 0.0477 0.0412 ND 0.223 0.193 1,2-Dichloroethane ND 0.0475 0.0412 ND 0.192 0.167 Heptane 0.0645 0.0468 0.0412 0.264 0.192 0.169 Trichloroethene ND 0.0471 0.0412 ND 0.253 0.222 1,2-Dichloropropene ND 0.0461 0.0412 ND 0.213 0.191 Methyl methacrylate ND 0.0484 0.0412 ND 0.198 0.169 1,4-Dioxane ND 0.0470 0.0412 ND 0.169 0.149 Bromodichloromethane ND 0.0466 0.0412 ND 0.312 0.276 cis-1,3-Dichloropropene ND 0.0460 0.0412 ND 0.209 0.187 Methyl isobutyl ketone 0.166 0.0481 0.0412 0.680 0.197 0.169 Toluene 0.255 0.0474 0.0412 0.960 0.179 0.155 trans-1,3-Dichloropropene ND 0.0476 0.0412 ND 0.216 0.187 1,1,2-Trichloroethane ND 0.0471 0.0412 ND 0.257 0.225 Tetrachloroethene ND 0.0471 0.0412 ND 0.320 0.280 2-Hexanone (Methyl butyl ketone) 0.110 0.121 0.0412 0.450 0.494 0.169 3 Dibromochloromethane ND 0.0465 0.0412 ND 0.396 0.351 1,2-Dibromoethane ND 0.0475 0.0412 ND 0.365 0.317 Chlorobenzene ND 0.0483 0.0412 ND 0.223 0.190 Ethylbenzene 0.108 0.0461 0.0412 0.468 0.200 0.179 1,1,1,2-Tetrachloroethane ND 0.0470 0.0412 ND 0.323 0.283 m-/p-Xylenes 0.349 0.0475 0.0412 1.52 0.206 0.179 EA# 0520-176 Page 18 of 37 Quantitation Report Enthalpy Analytical, LLC Sample Name : DUP-1 Sample Info 0520-176; *0.667=750mL load; Can #0744 Data File X2001900.D Dilution 0.667 Pressurization Factor 1.766 Acquisition Date 2020-05-27 22:06:38 Instrument Method TO15-SCN.M Matrix AIR Concentration RL MDL Concentration RL MDL Target Compound -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- (PPBV) (PPBV) (PPBV) (ug/m3) (ug/m3) (ug/m3) Flag o-Xylene 0.142 0.0466 0.0412 0.615 0.203 0.179 Styrene 0.0579 0.0458 0.0412 0.247 0.195 0.176 Bromoform ND 0.0471 0.0412 ND 0.487 0.426 1,1,2,2-Tetrachloroethane ND 0.0471 0.0412 ND 0.323 0.283 4-Ethyltoluene ND 0.0474 0.0412 ND 0.233 0.203 2-Chlorotoluene ND 0.0473 0.0412 ND 0.245 0.213 1,3,5-Trimethylbenzene 0.0613 0.0473 0.0412 0.302 0.233 0.203 1,2,4-Trimethylbenzene 0.169 0.0468 0.0412 0.833 0.230 0.203 m 1,3-Dichlorobenzene ND 0.0479 0.0412 ND 0.288 0.248 1,4-Dichlorobenzene ND 0.0474 0.0412 ND 0.285 0.248 Benzyl chloride ND 0.0469 0.0412 ND 0.243 0.213 1,2-Dichlorobenzene ND 0.0478 0.0412 ND 0.288 0.248 1,2,4-Trichlorobenzene ND 0.0477 0.0412 ND 0.354 0.306 Hexachlorobutadiene ND 0.0478 0.0412 ND 0.510 0.440 Naphthalene ND 0.0491 0.0412 ND 0.257 0.216 1-Bromopropane ND 0.0459 0.0412 ND 0.231 0.207 1-Octene ND 0.0457 0.0412 ND 0.210 0.189 n-Octane ND 0.0472 0.0412 ND 0.221 0.193 Isopropylbenzene ND 0.0475 0.0412 ND 0.234 0.203 n-Propylbenzene ND 0.0477 0.0412 ND 0.234 0.203 Retention Time Concentration Internal Standards Response (min) (PPBV) Flag ------------------------------------------------------------------------------------------------------------------------------------------ Bromochloromethane (IS) 534,984 11.85 5.00 PASS 1,4-Dicuorobenzene (IS) 2,140,035 13.62 5.04 PASS Chlorobenzene-d5 (IS) 1,853,073 17.80 4.80 PASS (ND) = Not Detected * (3) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40% EA# 0520-176 Page 19 of 37 �) ENTHALPY A A A LY i I C A t. Lab QC EA# 0520-176 Page 20 of 37 Quantitation Report Enthalpy Analytical, LLC Sample Name : IA-5 LD Sample Info 0520-176; *0.667=750mL load; Can #1478 Data File X2001897.D Dilution 0.667 Pressurization Factor 1.732 Acquisition Date 2020-05-27 19:05:02 Instrument Method TO15-SCN.M Matrix AIR Concentration RL MDL Concentration RL MDL Target Compound ----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------• (PPBV) (PPBV) (PPBV) (ug/m3) (ug/m3) (ug/m3) % Diff Flag Propylene 0.317 0.0443 0.0404 0.546 0.0762 0.0696 8.6 Freon 12 (CC12F2) 0.518 0.0444 0.0404 2.56 0.220 0.200 4.6 Freon 114 (C2C12F4) ND 0.0460 0.0404 ND 0.322 0.283 Chloromethane 0.690 0.0449 0.0404 1.42 0.0927 0.0835 3.5 Chloroethene (Vinyl chloride) ND 0.0461 0.0404 ND 0.118 0.103 1,3-Butadiene ND 0.0446 0.0404 ND 0.0988 0.0895 Bromomethane ND 0.0453 0.0404 ND 0.176 0.157 Chloroethane ND 0.0463 0.0404 ND 0.122 0.107 Bromcethene (Vinyl bromide) ND 0.0453 0.0404 ND 0.198 0.177 Freon 11 (CC13F) 0.267 0.0477 0.0404 1.50 0.268 0.227 3.8 Ethanol 10.1 0.0462 0.0462 19.1 0.0871 0.0871 0.7 Acrolein 0.269 0.0448 0.0404 0.616 0.103 0.0927 2.7 Freon 113 (C2C13F3) 0.208 0.0458 0.0404 1.60 0.351 0.310 1.1 1,1-Dichloroethene ND 0.0460 0.0404 ND 0.182 0.160 Acetone 4.38 0.0456 0.0404 10.4 0.108 0.0960 1.8 Carbon disulfide 0.0513 0.0459 0.0404 0.160 0.143 0.126 0.1 Isopropyl alcohol 0.883 0.0457 0.0404 2.17 0.112 0.0994 2.1 Allyl chloride (3-chloropropene) ND 0.0461 0.0404 ND 0.144 0.127 Acetonitrile 0.201 0.0456 0.0404 0.338 0.0766 0.0679 15.2 m Methylene chloride 0.181 0.116 0.116 0.630 0.402 0.402 2.2 trans-1,2-Dichloroethene ND 0.0467 0.0404 ND 0.185 0.160 Methyl tert-butyl ether ND 0.0467 0.0404 ND 0.168 0.146 Acrylonitrile ND 0.0463 0.0404 ND 0.101 0.0878 Hexane 0.0649 0.0465 0.0404 0.229 0.164 0.143 6.3 1,1-Dichloroethane ND 0.0451 0.0404 ND 0.182 0.164 Vinyl acetate ND 0.0463 0.0404 ND 0.163 0.142 cis-1,2-Dichloroethene ND 0.0459 0.0404 ND 0.182 0.160 Methyl ethyl ketone (2-Butanone) 0.498 0.0469 0.0404 1.47 0.138 0.119 10.1 Ethyl acetate 0.683 0.0463 0.0404 2.46 0.167 0.146 2.5 Chloroform ND 0.0464 0.0404 ND 0.227 0.197 Tetrahydrofuran 0.140 0.0461 0.0404 0.414 0.136 0.119 2.7 m 1,1,1-Trichloroethane ND 0.0456 0.0404 ND 0.249 0.221 Cyclohexane ND 0.0464 0.0404 ND 0.160 0.139 Carbon tetrachloride 0.0828 0.0463 0.0404 0.521 0.291 0.254 5.8 Benzene 0.0933 0.0454 0.0404 0.298 0.145 0.129 3.3 2,2,4-trimethylpentane ND 0.0468 0.0404 ND 0.219 0.189 1,2-Dichloroethane ND 0.0466 0.0404 ND 0.189 0.164 Heptane 0.0690 0.0459 0.0404 0.283 0.188 0.166 11.7 Trichloroethene ND 0.0462 0.0404 ND 0.248 0.217 1,2-Dichloropropane ND 0.0452 0.0404 ND 0.209 0.187 Methyl methacrylate ND 0.0475 0.0404 ND 0.194 0.166 1,4-Dioxane ND 0.0461 0.0404 ND 0.166 0.146 Bromodichloromethane ND 0.0457 0.0404 ND 0.306 0.271 cis-1,3-Dichloropropene ND 0.0451 0.0404 ND 0.205 0.184 Methyl isobutyl ketone 0.129 0.0472 0.0404 0.530 0.193 0.166 4.1 Toluene 0.223 0.0465 0.0404 0.840 0.175 0.152 0.6 trans-1,3-Dichloropropene ND 0.0467 0.0404 ND 0.212 0.184 1,1,2-Trichloroethane ND 0.0462 0.0404 ND 0.252 0.221 Tetrachloroethene ND 0.0462 0.0404 ND 0.313 0.274 2-Hexanone (Methyl butyl ketone) 0.115 0.118 0.0404 0.470 0.485 0.166 3.4 m 3 Dibromochloromethane ND 0.0456 0.0404 ND 0.389 0.344 1,2-Dibromoethane ND 0.0466 0.0404 ND 0.358 0.311 Chlorobenzene ND 0.0474 0.0404 ND 0.218 0.186 Ethylbenzene 0.0907 0.0452 0.0404 0.394 0.196 0.176 3.7 1,1,1,2-Tetrachloroethane ND 0.0461 0.0404 ND 0.317 0.278 m-/p-Xylenes 0.292 0.0466 0.0404 1.27 0.202 0.176 3.5 o-Xylene 0.118 0.0457 0.0404 0.514 0.199 0.176 2.7 Styrene ND 0.0449 0.0404 ND 0.191 0.172 Bromoform ND 0.0462 0.0404 ND 0.477 0.418 1,1,2,2-Tetrachloroethane ND 0.0462 0.0404 ND 0.317 0.278 4-Ethyltoluene ND 0.0464 0.0404 ND 0.228 0.199 2-Chlorotoluene ND 0.0464 0.0404 ND 0.240 0.209 EA# 0520-176 Page 21 of 37 Quantitation Report Enthalpy Analytical, LLC Sample Name : IA-5 LD Sample Info 0520-176; *0.667=750mL load; Can #1478 Data File X2001897.D Dilution 0.667 Pressurization Factor 1.732 Acquisition Date 2020-05-27 19:05:02 Instrument Method TO15-SCN.M Matrix AIR Concentration RL MDL Concentration RL MDL Target Compound •---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- (PPBV) (PPBV) (PPBV) (ug/m3) (ug/m3) (ug/m3) % Diff Flag 1,3,5-Trimethylbenzene 0.0542 0.0464 0.0404 0.267 0.228 0.199 7.0 1,2,4-Trimethylbenzene 0.150 0.0459 0.0404 0.736 0.226 0.199 3.1 m 1,3-Dichlorobenzene ND 0.0470 0.0404 ND 0.283 0.243 1,4-Dichlorobenzene ND 0.0464 0.0404 ND 0.279 0.243 Benzyl chloride ND 0.0460 0.0404 ND 0.238 0.209 1,2-Dichlorobenzene ND 0.0469 0.0404 ND 0.282 0.243 1,2,4-Trichlorobenzene ND 0.0468 0.0404 ND 0.347 0.300 Hexachlorobutadiene ND 0.0469 0.0404 ND 0.500 0.431 Naphthalene ND 0.0482 0.0404 ND 0.253 0.212 1-Bromopropane ND 0.0451 0.0404 ND 0.227 0.203 1-Octene ND 0.0448 0.0404 ND 0.206 0.186 n-Octane ND 0.0463 0.0404 ND 0.216 0.189 Isopropylbenzene ND 0.0466 0.0404 ND 0.229 0.199 n-Propylbenzene ND 0.0468 0.0404 ND 0.230 0.199 Retention Time Concentration Internal standards ------------------------------------------------------------------------------------------------------------------------------- Response (min) (PPBV) Flag Bromochloromethane (IS) 519,403 11.85 5.00 PASS 1,4-Difluorobenzene (IS) 2,072,566 13.62 5.04 PASS Chlorobenzene-d5 (IS) 1,787,642 17.80 4.80 PASS (ND) = Not Detected * (3) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40% EA# 0520-176 Page 22 of 37 Quantitation Report Enthalpy Analytical, LLC Sample Name Sample Info Data File Dilution Pressurization Factor Acquisition Date Instrument Method Matrix ':[Rii1f.� 3FTi19 500mL load; Can #10893 X2001891.D 1 1.000 2020-05-27 13:02:05 T015-SCN.M AIR Concentration RL MDL Concentration RL MDL Target Compound -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- (PPBV) (PPBV) (PPBV) (ug/m3) (ug/m3) (ug/m3) Flag* Propylene ND 0.0383 0.0350 ND 0.0660 0.0602 Freon 12 (CC12F2) ND 0.0384 0.0350 ND 0.190 0.173 Freon 114 (C2C12F4) ND 0.0398 0.0350 ND 0.279 0.245 Chloromethane ND 0.0389 0.0350 ND 0.0803 0.0723 Chloroethene (Vinyl chloride) ND 0.0399 0.0350 ND 0.102 0.0895 1,3-Butadiene ND 0.0386 0.0350 ND 0.0855 0.0774 Bromomethane ND 0.0392 0.0350 ND 0.152 0.136 Chloroethane ND 0.0401 0.0350 ND 0.106 0.0924 Bromoethene (Vinyl bromide) ND 0.0392 0.0350 ND 0.172 0.153 Freon 11 (CC13F) ND 0.0413 0.0350 ND 0.232 0.197 Ethanol ND 0.0400 0.0400 ND 0.0754 0.0754 Acrolein ND 0.0388 0.0350 ND 0.0890 0.0803 Freon 113 (C2Cl3F3) ND 0.0396 0.0350 ND 0.304 0.268 1,1-Dichloroethene ND 0.0398 0.0350 ND 0.158 0.139 Acetone 0.0488 0.0395 0.0350 0.116 0.0938 0.0831 Carbon disulfide ND 0.0397 0.0350 ND 0.124 0.109 Isopropyl alcohol ND 0.0396 0.0350 ND 0.0973 0.0860 AIIyl chloride (3-chloropropene) ND 0.0399 0.0350 ND 0.125 0.110 Acetonitrile ND 0.0395 0.0350 ND 0.0663 0.0588 Methylene chloride ND 0.100 0.100 ND 0.348 0.348 trans-1,2-Dichloroethene ND 0.0404 0.0350 ND 0.160 0.139 Methyl tert-butyl ether ND 0.0404 0.0350 ND 0.146 0.126 Acrylonitrile ND 0.0401 0.0350 ND 0.0871 0.0760 Hexane ND 0.0403 0.0350 ND 0.142 0.123 1,1-Dichloroethane ND 0.0390 0.0350 ND 0.158 0.142 Vinyl acetate ND 0.0401 0.0350 ND 0.141 0.123 cis-1,2-Dichloroethene ND 0.0398 0.0350 ND 0.158 0.139 Methyl ethyl ketone (2-Butanone) ND 0.0406 0.0350 ND 0.120 0.103 Ethyl acetate ND 0.0400 0.0350 ND 0.144 0.126 Chloroform ND 0.0402 0.0350 ND 0.196 0.171 Tetrahydrofuran ND 0.0399 0.0350 ND 0.118 0.103 1,1,1-Trichloroethane ND 0.0394 0.0350 ND 0.215 0.191 Cyclohexane ND 0.0402 0.0350 ND 0.138 0.120 Carbon tetrachloride ND 0.0400 0.0350 ND 0.252 0.220 Benzene ND 0.0393 0.0350 ND 0.126 0.112 2,2,4-trimethylpentane ND 0.0405 0.0350 ND 0.189 0.164 1,2-Dichloroethane ND 0.0404 0.0350 ND 0.163 0.142 Heptane ND 0.0398 0.0350 ND 0.163 0.143 Trichloroethene ND 0.0400 0.0350 ND 0.215 0.188 1,2-Dichloropropane ND 0.0392 0.0350 ND 0.181 0.162 Methyl methacrylate ND 0.0411 0.0350 ND 0.168 0.143 1,4-Dioxane ND 0.0399 0.0350 ND 0.144 0.126 Bromodichloromethane ND 0.0396 0.0350 ND 0.265 0.235 cis-1,3-Dichloropropene ND 0.0390 0.0350 ND 0.177 0.159 Methyl isobutyl ketone ND 0.0408 0.0350 ND 0.167 0.143 Toluene ND 0.0403 0.0350 ND 0.152 0.132 trans-1,3-Dichloropropene ND 0.0404 0.0350 ND 0.184 0.159 1,1,2-Trichloroethane ND 0.0400 0.0350 ND 0.218 0.191 Tetrachloroethene ND 0.0400 0.0350 ND 0.271 0.237 2-Hexanone (Methyl butyl ketone) ND 0.102 0.0350 ND 0.419 0.143 Dibromochloromethane ND 0.0395 0.0350 ND 0.336 0.298 1,2-Dibromoethane ND 0.0403 0.0350 ND 0.310 0.269 Chlorobenzene ND 0.0410 0.0350 ND 0.189 0.161 Ethylbenzene ND 0.0392 0.0350 ND 0.170 0.152 1,1,1,2-Tetrachloroethane ND 0.0399 0.0350 ND 0.274 0.240 m-/p-Xylenes ND 0.0404 0.0350 ND 0.175 0.152 EA# 0520-176 Page 23 of 37 Quantitation Report Enthalpy Analytical, LLC Sample Name Sample Info Data File Dilution Pressurization Factor Acquisition Date Instrument Method Matrix a:[I1'� IMF , 5 500mL load; Can #10893 X2001891.D 1 1.000 2020-05-27 13:02:05 T015-SCN.M AIR Concentration RL MDL Concentration RL MDL Target Compound -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- (PPBV) (PPBV) (PPBV) (ug/m3) (ug/m3) (ug/m3) Flag* o-Xylene ND 0.0396 0.0350 ND 0.172 0.152 Styrene ND 0.0388 0.0350 ND 0.165 0.149 Bromoform ND 0.0400 0.0350 ND 0.413 0.362 1,1,2,2-Tetrachloroethane ND 0.0400 0.0350 ND 0.274 0.240 4-Ethyltoluene ND 0.0402 0.0350 ND 0.198 0.172 2-Chlorotoluene ND 0.0402 0.0350 ND 0.208 0.181 1,3,5-Trimethylbenzene ND 0.0402 0.0350 ND 0.197 0.172 1,2,4-Trimethylbenzene ND 0.0397 0.0350 ND 0.195 0.172 1,3-Dichlorobenzene ND 0.0407 0.0350 ND 0.245 0.210 1,4-Dichlorobenzene ND 0.0402 0.0350 ND 0.242 0.210 Benzyl chloride ND 0.0398 0.0350 ND 0.206 0.181 1,2-Dichlorobenzene ND 0.0406 0.0350 ND 0.244 0.210 1,2,4-Trichlorobenzene 0.0419 0.0405 0.0350 0.311 0.301 0.260 Hexachlorobutadiene ND 0.0406 0.0350 ND 0.433 0.373 Naphthalene ND 0.0417 0.0350 ND 0.219 0.183 1-Bromopropane ND 0.0390 0.0350 ND 0.196 0.176 1-Octene ND 0.0388 0.0350 ND 0.178 0.161 n-Octane ND 0.0401 0.0350 ND 0.187 0.164 Isopropylbenzene ND 0.0404 0.0350 ND 0.198 0.172 n-Propylbenzene ND 0.0405 0.0350 ND 0.199 0.172 Retention Time Concentration Internal Standards ------------------------------------------------------------------------------------------------------------------------------------------ Response (min) (PPBV) Flag Bromochloromethane (IS) 473,647 11.86 5.00 PASS 1,4-Dicuorobenzene (IS) 1,902,591 13.62 5.04 PASS Chlorobenzene-d5 (IS) 1,645,017 17.80 4.80 PASS (ND) = Not Detected * (3) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40% EA# 0520-176 Page 24 of 37 QC Summary Report Enthalpy Analytical, LLC Sample Name Sample Info Data File Dilution Pressurization Factor Acquisition Date Instrument Method Matrix : 5ppbv T015 LCS 125mL load; Can 2088; GCMSPrepPg0897 X2001887.D 1 1.000 2020-05-27 09:16:49 T015-SCN.M AIR Concentration Tag Value Target Compound Response (PPBV) (PPBV) % Recovery Flag --------------------------------------------------------------------------------------------------------------------------------------- Propylene 573,437 5.20 4.79 108.6 PASS Freon 12 (CC12F2) 1,294,626 5.30 4.81 110.2 PASS Freon 114 (C2Cl2F4) 1,401,511 5.32 4.98 106.9 PASS Chloromethane 695,426 5.24 4.86 107.8 PASS Chloroethene (Vinyl chloride) 487,148 5.34 4.99 107.2 PASS 1,3-Butadiene 503,242 5.87 4.83 121.6 PASS Bromomethane 372,008 5.89 4.90 120.1 PASS Chloroethane 213,955 5.10 5.01 101.9 PASS Bromoethene (Vinyl bromide) 460,781 5.53 4.91 112.7 PASS Freon 11(CC13F) 1,454,861 5.66 5.16 109.6 PASS Ethanol 276,765 4.04 4.91 82.5 PASS Acrolein 224,665 3.98 4.85 82.0 PASS 1,1-Dichloroethene 914,714 4.69 4.98 94.3 PASS Freon 113 (C2Cl3F3) 862,375 5.13 4.96 103.4 PASS Acetone 1,081,219 4.04 4.94 81.8 PASS Isopropyl alcohol 1,219,064 4.37 4.95 88.3 PASS Carbon disulfide 1,329,987 4.77 4.97 96.1 PASS Acetonitrile 625,937 5.14 4.94 104.1 PASS Allyl chloride (3-chloropropene) 199,210 4.66 4.99 93.5 PASS Methylene chloride 927,412 4.20 5.01 83.8 PASS Acrylonitrile 491,837 4.73 5.02 94.4 PASS Methyl tert-butyl ether 1,204,127 4.70 5.05 93.0 PASS trans-1,2-Dichloroethene 782,008 4.50 5.05 89.0 PASS Hexane 847,984 4.13 5.04 82.1 PASS Vinyl acetate 1,886,214 5.17 5.02 103.0 PASS 1,1-Dichloroethane 935,728 4.47 4.88 91.7 PASS Methyl ethyl ketone (2-Butanone) 212,753 4.66 5.08 91.9 PASS cis-1,2-Dichloroethene 926,230 4.68 4.97 94.2 PASS Ethyl acetate 246,476 4.66 5.01 93.1 PASS 1-Bromopropane 1,272,012 5.02 4.88 102.9 PASS Tetrahydrofuran 207,298 4.51 4.99 90.5 PASS Chloroform 1,040,686 5.15 5.03 102.5 PASS 1,1,1-Trichloroethane 1,041,779 4.95 4.93 100.4 PASS Cyclohexane 940,706 4.45 5.03 88.6 PASS Carbon tetrachloride 1,203f4O5 5.07 5.01 101.3 PASS Benzene 1,293,693 4.64 4.92 94.4 PASS 1,2-Dichloroethane 782,283 4.87 5.05 96.6 PASS 2,2,4-trimethylpentane 2,876,537 4.41 5.07 87.1 PASS Heptane 555,415 4.18 4.97 84.0 PASS Trichloroethene 712,049 5.13 5.00 102.7 PASS 1,2-Dichloropropane 616,445 4.43 4.90 90.4 PASS Methyl methacrylate 512,798 4.99 5.14 97.1 PASS EA# 0520-176 Page 25 of 37 QC Summary Report Enthalpy Analytical, LLC Sample Name Sample Info Data File Dilution Pressurization Factor Acquisition Date Instrument Method Matrix : 5ppbv T015 LCS 125mL load; Can 2088; GCMSPrepPg0897 X2001887.D 1 1.000 2020-05-27 09:16:49 T015-SCN.M AIR Concentration Tag Value Target Compound Response (PPBV) (PPBV) % Recovery Flag --------------------------------------------------------------------------------------------------------------------------------------- 1,4-Dioxane 313,460 4.20 4.99 84.2 PASS Bromodichloromethane 1,124,402 5.31 4.95 107.3 PASS cis-1,3-Dichloropropene 799,592 4.76 4.88 97.5 PASS Methyl isobutyl ketone 1,903,840 4.91 5.11 96.1 PASS Toluene 1,726,599 5.01 5.04 99.5 PASS 1-Octene 384,077 4.50 4.85 92.9 PASS n-Octane 504,828 4.66 5.01 93.1 PASS trans-1,3-Dichloropropene 863,600 5.22 5.06 103.3 PASS 1,1,2-Trichloroethane 613,277 5.16 5.00 103.4 PASS Tetra chloroethene 981,159 5.16 5.00 103.1 PASS 2-Hexanone (Methyl butyl ketone) 1,818,305 5.74 5.12 112.1 PASS Dibromochloromethane 1,360,482 5.75 4.94 116.4 PASS 1,2-Dibromoethane 1,117,582 5.38 5.04 106.7 PASS Chlorobenzene 1,538,469 5.45 5.13 106.3 PASS Ethylbenzene 2,285,735 5.04 4.90 103.0 PASS 1,1,1,2-Tetrachloroethane 907,022 5.32 4.99 106.5 PASS m-/p-Xylenes 1,886,072 5.14 5.05 101.9 PASS o-Xylene 1,857,732 4.95 4.95 100.0 PASS Styrene 1,426,924 5.00 4.86 102.9 PASS Bromoform 1,457,467 6.19 5.00 123.8 PASS Isopropyl benzene 2,664,379 5.10 5.05 101.1 PASS 1,1,2,2-Tetrachloroethane 1,474,210 5.26 5.00 105.3 PASS n-Propylbenzene 3,222,566 5.34 5.06 105.6 PASS 4-Ethyltoluene 2,668,039 5.09 5.03 101.3 PASS 2-Chlorotoluene 2,309,693 5.20 5.02 103.7 PASS 1,3,5-Trimethyl benzene 2,301,519 5.08 5.02 101.2 PASS 1,2,4-Trimethyl benzene 2,280,600 4.99 4.97 100.6 PASS 1,3-Dichlorobenzene 1,644,190 5.48 5.09 107.7 PASS 1,4-Dichlorobenzene 1,631,185 5.52 5.02 110.0 PASS Benzyl chloride 1,955,682 5.46 4.98 109.5 PASS 1,2-Dichlorobenzene 1,626,199 5.45 5.08 107.5 PASS 1,2,4-Trichlorobenzene 1,101,747 5.43 5.06 107.2 PASS Hexachlorobutadiene 1,311,105 5.00 5.08 98.5 PASS Naphthalene 2,537,330 5.15 5.21 98.8 PASS EA# 0520-176 Page 26 of 37 Quantitation Report Enthalpy Analytical, LLC Sample Name Sample Info Data File Dilution Pressurization Factor Acquisition Date Instrument Method Matrix 5ppbv T015 LCS 125mL load; Can 2088; GCMSPrepPg0897 X2001887.D 1 1.000 2020-05-27 09:16:49 TO15-SCN.M AIR Concentration RL MDL Concentration RL MDL Target Compound -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- (PPBV) (PPBV) (PPBV) (ug/m3) (ug/m3) (ug/m3) Flag* Propylene 5.20 0.0383 0.0350 8.95 0.0660 0.0602 Freon 12 (CC12F2) 5.30 0.0384 0.0350 26.2 0.190 0.173 Freon 114 (C2C12F4) 5.32 0.0398 0.0350 37.2 0.279 0.245 Chloromethane 5.24 0.0389 0.0350 10.8 0.0803 0.0723 Chloroethene (Vinyl chloride) 5.34 0.0399 0.0350 13.7 0.102 0.0895 1,3-Butadiene 5.87 0.0386 0.0350 13.0 0.0855 0.0774 Bromomethane 5.89 0.0392 0.0350 22.9 0.152 0.136 Chloroethane 5.10 0.0401 0.0350 13.5 0.106 0.0924 Bromoethene (Vinyl bromide) 5.53 0.0392 0.0350 24.2 0.172 0.153 Freon 11 (CC13F) 5.66 0.0413 0.0350 31.8 0.232 0.197 Ethanol 4.04 0.0400 0.0400 7.62 0.0754 0.0754 Acrolein 3.98 0.0388 0.0350 9.12 0.0890 0.0803 Freon 113 (C2Cl3F3) 5.13 0.0396 0.0350 39.3 0.304 0.268 1,1-Dichloroethene 4.69 0.0398 0.0350 18.6 0.158 0.139 Acetone 4.04 0.0395 0.0350 9.59 0.0938 0.0831 m Carbon disulfide 4.77 0.0397 0.0350 14.9 0.124 0.109 Isopropyl alcohol 4.37 0.0396 0.0350 10.7 0.0973 0.0860 AIIyl chloride (3-chloropropene) 4.66 0.0399 0.0350 14.6 0.125 0.110 Acetonitrile 5.14 0.0395 0.0350 8.63 0.0663 0.0588 Methylene chloride 4.20 0.100 0.100 14.6 0.348 0.348 m trans-1,2-Dichloroethene 4.50 0.0404 0.0350 17.8 0.160 0.139 Methyl tert-butyl ether 4.70 0.0404 0.0350 16.9 0.146 0.126 Acrylonitrile 4.73 0.0401 0.0350 10.3 0.0871 0.0760 Hexane 4.13 0.0403 0.0350 14.6 0.142 0.123 1,1-Dichloroethane 4.47 0.0390 0.0350 18.1 0.158 0.142 Vinyl acetate 5.17 0.0401 0.0350 18.2 0.141 0.123 m cis-1,2-Dichloroethene 4.68 0.0398 0.0350 18.6 0.158 0.139 Methyl ethyl ketone (2-Butanone) 4.66 0.0406 0.0350 13.8 0.120 0.103 Ethyl acetate 4.66 0.0400 0.0350 16.8 0.144 0.126 Chloroform 5.15 0.0402 0.0350 25.2 0.196 0.171 Tetrahydrofuran 4.51 0.0399 0.0350 13.3 0.118 0.103 1,1,1-Trichloroethane 4.95 0.0394 0.0350 27.0 0.215 0.191 Cyclohexane 4.45 0.0402 0.0350 15.3 0.138 0.120 Carbon tetrachloride 5.07 0.0400 0.0350 31.9 0.252 0.220 Benzene 4.64 0.0393 0.0350 14.8 0.126 0.112 2,2,4-trimethylpentane 4.41 0.0405 0.0350 20.6 0.189 0.164 1,2-Dichloroethane 4.87 0.0404 0.0350 19.7 0.163 0.142 Heptane 4.18 0.0398 0.0350 17.1 0.163 0.143 Trichloroethene 5.13 0.0400 0.0350 27.6 0.215 0.188 1,2-Dichloropropane 4.43 0.0392 0.0350 20.5 0.181 0.162 Methyl methacrylate 4.99 0.0411 0.0350 20.4 0.168 0.143 1,4-Dioxane 4.20 0.0399 0.0350 15.1 0.144 0.126 Bromodichloromethane 5.31 0.0396 0.0350 35.6 0.265 0.235 cis-1,3-Dichloropropene 4.76 0.0390 0.0350 21.6 0.177 0.159 Methyl isobutyl ketone 4.91 0.0408 0.0350 20.1 0.167 0.143 Toluene 5.01 0.0403 0.0350 18.9 0.152 0.132 trans-1,3-Dichloropropene 5.22 0.0404 0.0350 23.7 0.184 0.159 1,1,2-Trichloroethane 5.16 0.0400 0.0350 28.2 0.218 0.191 m Tetrachloroethene 5.16 0.0400 0.0350 35.0 0.271 0.237 2-Hexanone (Methyl butyl ketone) 5.74 0.102 0.0350 23.5 0.419 0.143 Dibromochloromethane 5.75 0.0395 0.0350 48.9 0.336 0.298 1,2-Dibromoethane 5.38 0.0403 0.0350 41.3 0.310 0.269 Chlorobenzene 5.45 0.0410 0.0350 25.1 0.189 0.161 Ethylbenzene 5.04 0.0392 0.0350 21.9 0.170 0.152 1,1,1,2-Tetrachloroethane 5.32 0.0399 0.0350 36.5 0.274 0.240 m-/p-Xylenes 5.14 0.0404 0.0350 22.3 0.175 0.152 EA# 0520-176 Page 27 of 37 Quantitation Report Enthalpy Analytical, LLC Sample Name Sample Info Data File Dilution Pressurization Factor Acquisition Date Instrument Method Matrix 5ppbv T015 LCS 125mL load; Can 2088; GCMSPrepPg0897 X2001887.D 1 1.000 2020-05-27 09:16:49 TO15-SCN.M AIR Concentration RL MDL Concentration RL MDL Target Compound -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- (PPBV) (PPBV) (PPBV) (ug/m3) (ug/m3) (ug/m3) Flag* o-Xylene 4.95 0.0396 0.0350 21.5 0.172 0.152 Styrene 5.00 0.0388 0.0350 21.3 0.165 0.149 Bromoform 6.19 0.0400 0.0350 63.9 0.413 0.362 1,1,2,2-Tetrachloroethane 5.26 0.0400 0.0350 36.1 0.274 0.240 4-Ethyltoluene 5.09 0.0402 0.0350 25.0 0.198 0.172 2-Chlorotoluene 5.20 0.0402 0.0350 26.9 0.208 0.181 1,3,5-Trimethylbenzene 5.08 0.0402 0.0350 25.0 0.197 0.172 1,2,4-Trimethylbenzene 4.99 0.0397 0.0350 24.5 0.195 0.172 1,3-Dichlorobenzene 5.48 0.0407 0.0350 32.9 0.245 0.210 1,4-Dichlorobenzene 5.52 0.0402 0.0350 33.2 0.242 0.210 Benzyl chloride 5.46 0.0398 0.0350 28.2 0.206 0.181 1,2-Dichlorobenzene 5.45 0.0406 0.0350 32.8 0.244 0.210 1,2,4-Trichlorobenzene 5.43 0.0405 0.0350 40.3 0.301 0.260 Hexachlorobutadiene 5.00 0.0406 0.0350 53.4 0.433 0.373 Naphthalene 5.15 0.0417 0.0350 27.0 0.219 0.183 1-Bromopropane 5.02 0.0390 0.0350 25.2 0.196 0.176 1-Octene 4.50 0.0388 0.0350 20.7 0.178 0.161 n-Octane 4.66 0.0401 0.0350 21.8 0.187 0.164 Isopropylbenzene 5.10 0.0404 0.0350 25.1 0.198 0.172 n-Propylbenzene 5.34 0.0405 0.0350 26.3 0.199 0.172 Retention Time Concentration Internal Standards ------------------------------------------------------------------------------------------------------------------------------------------ Response (min) (PPBV) Flag Bromochloromethane (IS) 512,707 11.85 5.00 PASS 1,4-Difuorobenzene (IS) 2,066,754 13.62 5.04 PASS Chlorobenzene-d5 (IS) 1,862,522 17.80 4.80 PASS (ND) = Not Detected * (1) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40% EA# 0520-176 Page 28 of 37 Canister and Controller Data Sheet Enthalpy Analytical, LLC Client Name: Mid -Atlantic Associates, Inc Client #: R3358.01; Northern Telecom -Durham, NC Enthalpy Job #: 0520-176 Controller Data Controller ID Data File Initial Flow cc min Return Flow cc min 5B-11971 T200430 3.5 3.9 5B-01540 T200303 3.5 3.5 5B-01597 T200305 3.5 3.5 5B-11972 T200430 3.5 3.5 5B-01918 T200430 3.5 3.6 5B-07536 T200430 3.5 3.7 5B-01875 T200430 3.5 3.6 5B-11969 T200430 3.5 3.6 Canister Data Canister ID Blank Check Datafile Canister Pressure Pre -Sample (mmHg) Canister Pressure Post -Sample (mmHg) Canister Pressure Final (mmHg) Canister Pressurization Factor 24090 X2001613 -758 -106 380 1.744 1436 X2000857 -758 -70 424 1.717 000020 Y2000356 -758 -63 444 1.728 0724 X2000910 -758 -57 451 1.724 1478 X1905063 -758 -57 457 1.732 0719 X2000822 -758 -5 559 1.748 0723 X2001655 -758 -70 463 1.774 0744 X2000802 -758 -109 389 1.766 Date Prepared: 5 22 20 Date Received: 5 27 20 Prepared Bv: AAM Received Bv: AMM3 0520-176 CanContrDataSheet V6c (complete) EA# 0520-176 Page 29 of 37 F- p )7OPOU ENTHALPY A A A LY i I C A t. Narrative Summary EA# 0520-176 Page 30 of 37 Enthalpy Analytical Narrative Summary Company Mid -Atlantic Associates, Inc. Analyst TDD Parameters EPA Method TO-15 Client # R3358.01 Job # 0520-176 # Samples 8 Canisters Custody Alyssa Miller received the samples on 5/27/20 after being relinquished by Mid -Atlantic Associates, Inc. The samples were received at ambient temperature and in good condition. Prior to, during, and after analysis, the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, LLC. Analysis The samples were analyzed for the TO-15 target compounds list using the analytical procedures in EPA Method TO-15, Determination of Volatile Organic Compounds (VOCs) In Air Collected In Specially - Prepared Canisters And Analyzed by Gas Chromatography/Mass Spectrometry (GUMS). Upon receipt, the canister pressures were measured and recorded. The canisters were then pressurized with UHP nitrogen and a dilution ratio was calculated for each canister (see Canister Pressurization Sheet in the Lab QC section of this report). The samples were analyzed at a 750mL load resulting in a 0.667-fold dilution to meet the client's requested MDL of 0.05ppbv. Dilution factors are displayed in the sample header information. The Agilent Technologies Model 6890N, Gas Chromatograph "Xavier" (S/N US10721018) was equipped with a 5975C VL Mass Selective Detector (S/N US71215962) and a Restek Rtx-624 Sil MS, 60 in x 0.32 mm x 1.8 µm capillary column (S/N 1555499) for this analysis. All samples and standards were introduced directly to the analyzer using an Entech 7200 Preconcentrator. Calibration The BFB tune analyses associated with the initial and continuing calibrations met all method acceptance criteria. The initial calibration (X050420A-T015) met the 30% RSD criteria. The initial calibration verification met the 70-130% recovery criteria. The continuing calibrations met the 30% difference criteria. Full calibration data is available upon request. Chromatographic The acquisition method (T015-SCN2.* has not been included in this Conditions level 2 report, however is available upon request. r� 071,_ ENTHALPY n N n L Y 1 I C A I. EA# 0520-176 Page 31 of 37 Enthalpy Analytical Narrative Summary (continued) QC Notes All internal standard area (IS) responses and retention time criteria were met for these analyses. The Laboratory Duplicates (LD) analyzed with each batch met the 25% difference criteria. The laboratory humid blank associated with the analysis of these samples did not contain any of the target analytes at a concentration greater than 3 times the MDL value. The Laboratory Control Samples (LCSs) met the 70-130% recovery criteria. All samples were analyzed within the 30-day holding time required by the method. Reporting Notes These analyses met the requirements of the TNI Standard. Any deviations from the requirements of the reference method or TNI Standard have been stated above. 'i �0 L ENTHALPY A N A L Y 1 1 C A I. The results presented in this report are representative of the samples as provided to the laboratory. EA# 0520-176 Page 32 of 37 General Reporting Notes The following are general reporting notes that are applicable to all Enthalpy Analytical, LLC data reports, unless specifically noted otherwise. • Any analysis which refers to the method as "Type" represents a planned deviation from the reference method. For instance a Hydrogen Sulfide assay from a Tedlar bag would be labeled as "EPA Method 16-Type" because Tedlar bags are not mentioned as one of the collection options in EPA Method 16. • The acronym MDL represents the Minimum Detection Limit. Below this value the laboratory cannot determine the presence of the analyte of interest reliably. • The acronym LOQ represents the Limit of Quantification. Below this value the laboratory cannot quantitate the analyte of interest within the criteria of the method. • The acronym ND following a value indicates a non -detect or analytical result below the MDL. • The letter J in the Qualifier or Flag column in the results indicates that the value is between the MDL and the LOQ. The laboratory can positively identify the analyte of interest as present, but the value should be considered an estimate. • The letter E in the Qualifier or Flag column indicates an analytical result exceeding 100% of the highest calibration point. The associated value should be considered as an estimate. • Sample results are presented `as measured' for single injection methodologies, or an average value if multiple injections are made. If all injections are below the MDL, the sample is considered non -detect and the ND value is presented. If one, but not all, are below the MDL, the MDL value is used for any injections that are below the MDL. For example, if the MDL is 0.500 and LOQ is 1.00, and the instrument measures 0.355, 0.620, and 0.442 - the result reported is the average of 0.500, 0.620, and 0.500 - - - i.e. 0.540 with a J flag. • When a spike recovery (Bag Spike, Collocated Spike Train, or liquid matrix spike) is being calculated, the native (unspiked) sample result is used in the calculations, as long as the value is above the MDL. If a sample is ND, then 0 is used as the native amount (not the MDL value). • The acronym DF represents Dilution Factor. This number represents dilution of the sample during the preparation and/or analysis process. The analytical result taken from a laboratory instrument is multiplied by the DF to determine the final undiluted sample results. • The addition of MS to the Sample ID represents a Matrix Spike. An aliquot of an actual sample is spiked with a known amount of analyte so that a percent recovery value can be determined. The MS analysis indicates what effect the sample matrix may have on the target analyte, i.e. whether or not anything in the sample matrix interferes with the analysis of the analyte(s). �) ENTHALPY A V A L Y i I C A L EA# 0520-176 Page 33 of 37 General Reporting Notes (continued) • The addition of MSD to the Sample ID represents a Matrix Spike Duplicate. Prepared in the same manner as a MS, the use of duplicate matrix spikes allows further confirmation of laboratory quality by showing the consistency of results gained by performing the same steps multiple times. • The addition of LD to the Sample ID represents a Laboratory Duplicate. The analyst prepares an additional aliquot of sample for testing and the results of the duplicate analysis are compared to the initial result. The result should have a difference value of within 10% of the initial result (if the results of the original analysis are greater than the LOQ). • The addition of AD to the Sample ID represents an Alternate Dilution. The analyst prepares an additional aliquot at a different dilution factor (usually double the initial factor). This analysis helps confirm that no additional compound is present and coeluting or sharing absorbance with the analyte of interest, as they would have a different response/absorbance than the analyte of interest. • The Sample ID LCS represents a Laboratory Control Sample. Clean matrix, similar to the client sample matrix, prepared and analyzed by the laboratory using the same reagents, spiking standards and procedures used for the client samples. The LCS is used to assess the control of the laboratory's analytical system. Whenever spikes are prepared for our client projects, two spikes are retained as LCSs. The LCSs are labeled with the associated project number and kept in-house at the appropriate temperature conditions. When the project samples are received for analysis, the LCSs are analyzed to confirm that the analyte could be recovered from the media, separate from the samples which were used on the project and which may have been affected by source matrix, sample collection, and/or sample transport. • Significant Figures: Where the reported value is much greater than unity (1.00) in the units expressed, the number is rounded to a whole number of units, rather than to 3 significant figures. For example, a value of 10,456.45 ug catch is rounded to 10,456 ug. There are five significant digits displayed, but no confidence should be placed on more than two significant digits. In the case of small numbers, generally 3 significant figures are presented, but still only 2 should be used with confidence. Many neat materials are only certified to 3 digits, and as the mathematically correct final result is always 1 digit less than all its pre -cursors - 2 significant figures are what are most defensible. • Manual Integration: The data systems used for processing will flag manually integrated peaks with an "M". There are several reasons a peak may be manually integrated. These reasons will be identified by the following two letter designations on sample chromatograms, if provided in the report. The peak was not integrated by the software "NI", the peak was integrated incorrectly by the software "II" or the wrong peak was integrated by the software "WP". These codes will accompany the analyst's manual integration stamp placed next to the compound name on the chromatogram. 'r ■�) ENTHALPY A V A L Y i I C A L EA# 0520-176 Page 34 of 37 �) ENTHALPY A V A L Y i I C A L Sample Custody EA# 0520-176 Page 35 of 37 Air Chain of Custody Record L N T HAL APYLab No: Y��j A N A I T I C A L page; 1 Of ! Turn Around Time (rush by advanced notice only) Standard: � 5 Day: 1 Day: 3 Day: 2 Day: Custom TAT Enthalpy Analytical - Durham CUSTOMER INFORMATION 800 Capitola Drive, Suite 1, Durham, NC 27713 Company: 17 cr �c{w6 Phone 919-850-4392 Report To: t-: e P� d PROJECT INFORMATION Name: Number: 3 S t, Special Instructions: Email: [GLi rqr 3 ,err' a 4�r- P.O. #: 3 U ddress: t is c� �• ��bt Address: ,j Y 5Y 2,_ Phone: Wq S G ct Gt 1 B' Global ID: 1] Fax: ISampled 6y: �s, •-� Analysis Requested Type Equipment Information Sampling Information �_ IA i"dow S"ze flow Sample Sample Vacuum Sample Sample Sample I#7 (a) Ambient Canister ID {1L 3L, Controller Start Start Start End End ISV]SoilVapor{S) Source 6L,15L] ID Date Time IHgl Date Time 'H') ,�-f� { [ -7 Z-1 G c�£s zZ - 3�5Z]/na24 jd0- Q- +�1 7 Z 0f `71 G1 -2 q 5 - 5 �i �? 4(IOf3 -C'cl6 r �j-71�q74 �rze, -z- C�7�� 07Z3 ieag7 KKK -3G 7�� a 6 _ C-"74 07sr 7 9 L 10 Signature Print Name Company/Title Date 1 Time 1 Relinquished By: ". A vitx 7 � 1 Received By: 144�&5a M • ft4 a.' 2 Relinquished By: 2 Received By: b 3 Relinquished By: 3 Received By: _ This Is The Last Page F- P )70POU ENTHALPY A V A L Y i I C A L Of This Report. EA# 0520-176 Page 37 of 37 APPENDIX E INDOOR AIR AND AMBIENT AIR VAPOR INTRUSION RISK CALCULATIONS (ALL COMPOUNDS) 10 Mid Atlantic North Carolina Department of Environmental Quality Risk Calculator Version Date: December 2019 Basis: November 2019 EPA RSL Table Site Name: Northern Telecom (Park Point) Site Address: 4001 and 4151 NC East Hwy 54, Durham, NC DEQ Section: Brownfields Program Site ID: MAA Project Number R3358.01 Exposure Unit ID: Max Concentrations (all compounds) - May 26, 2020 Submittal Date: 6/2/2020 Prepared By: Katie Lippard Reviewed B North Carolina DEQ Risk Calculator Risk for Individual Pathways rim Version Date: December 2019 Basis: November 2019 EPA RSL Table 7 Site ID: MAA Project Number R3358.01 Ex ooure Unit ID: Max Concentrations all compounds) -May 26, 2020 DIRECT CONTACT SOIL AND WATER CALCULATORS Receptor Pathway Carciinn kenic Hazard Index Risk exceeded? Resident Soil 0.0E+00 0.0E+00 NO NC Groundwater Use* NC NC Non -Residential Worker Soil 0.0E+00 0.0E+00 NO Groundwater Use* NC NC NC Construction Worker Soil NC NC NC Recreator/Trespasser Soil NC NC NC Surface Water* NC NC NC VAPOR INTRUSION CALCULATORS no Receptor Pathway CarcinogenicRisk Hazard Index Risk exceeded? Resident Groundwater to Indoor Air 0.0E+00 0.0E+00 NO Soil Gas to Indoor Air 0.0E+00 0.0E+00 NO Indoor Air 1.1E-05 3.9E+01 YES Non -Residential Worker Groundwater to Indoor Air 0.0E+00 0.0E+00 NO Soil Gas to Indoor Air 0.0E+00 0.0E+00 NO Indoor Air 2.6E-06 9.3E+00 YES CONTAMINANT MIGRATION CALCULATORS Pathway Source Target Receptor Concentrations Exceeded? Groundwater Source Soil Exceedence of 21, at Receptor? NM Source Groundwater Exceedence of 21, at Receptor? NM Surface Water Source Soil Exceedence of 2B at Receptor? NM Source Groundwater Exceedence of 2B at Receptor? NM Notes: 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 213 Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk -based closure. 3. NM = Not Modeled 4. NC = Pathway not complete North Carolina DEQ Risk Calculator Risk Calculator - Vapor Intrusion - Resident Indoor Air ersion Date: December 2019 asis: November 2019 EPA RSL Table to ID: MAA Project Number R3358.01 xnosure Unit ID: Max Concentrations (all comnounds) - Mav 26. 2020 ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 µg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. All concentrations are in ug/m3 CAS # Chemical Name: Indoor Air Concentration 3 (ug/m) Target Indoor Au Conc. for Carcinogens @ TCR = 1 E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 20.7 6.5E+03 6.4E-04 75-05-8 Acetouitrile 0.415 1.3E+01 6.6E-03 107-02-8 Acrolein 0.802 4.2E-03 3.8E+01 71-43-2 Benzene 0.671 3.6E-01 6.3E+00 1.9E-06 2.1E-02 75-15-0 Carbon Disulfide 0.25 1.5E+02 3.4E-04 56-23-5 Carbon Tetrachloride 0.552 4.7E-01 2.1E+01 1.2E-06 5.3E-03 75-71-8 Dichlorodifluoromethane 3.48 2.1E+01 3.3E-02 123-91-1 Dioxane, 1,4- 0.472 5.6E-01 6.3E+00 8.4E-07 1.5E-02 141-78-6 Ethyl Acetate 2.52 1.5E+01 3.5E-02 100-41-4 Eth lbenzene 1.05 1.1E+00 2.1E+02 9.3E-07 1.0E-03 109-99-9 -Tetrah drofuran 0.819 4.2E+02 3.9E-04 142-82-5 Heptane, N- 0.333 8.3E+01 8.0E-04 110-54-3 Hexane, N- 0.293 1.5E+02 4.0E-04 591-78-6 Hexanone, 2- 1.73 6.3E+00 5.5E-02 67-63-0 Isopropanol 4.81 4.2E+01 2.3E-02 78-93-3 Methyl Ethyl Ketone (2-Butanone) 2.74 1.0E+03 5.3E-04 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone) 1.1 6.3E+02 3.5E-04 75-09-2 Methylene Chloride 0.72 1.0E+02 1.3E+02 7.1E-09 1.2E-03 91-20-3 -Naphthalene 0.528 8.3E-02 6.3E-01 6.4E-06 1.7E-01 115-07-1 Propylene 0.739 6.3E+02 2.4E-04 100-42-5 Styrene 0.479 2.1E+02 4.6E-04 108-88-3 Toluene 0.96 1.0E+03 1.8E-04 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2- 2.22 1.0E+03 4.3E-04 120-82-1 Trichlorobenzene, 1,2,4- 0.396 4.2E-01 1.9E-01 75-694 Trichlorofluoromethane 1.92 95-63-6 Trimethylbenzene, 1,2,4- 1.21 1.3E+01 1.9E-02 108-67-8 Trimethylbenzene, 1,3,5- 0.339 1.3E+01 5.4E-03 108-38-3 Xylene, m- 3.1 2.1E+01 3.0E-02 9547-6 Xylene, o- 1.12 2.1E+01 1.1E-02 Cumulative: I 1.1E-05 I3.9E+O1 North Carolina DEQ Risk Calculator IDEO Risk Calculator - VaDor Intrusion - Non -Residential Worker Indoor Air r :ion Date: December 2019 s: November 2019 EPA RSL Table Site ID: MAA Project Number R3358.01 J EXDOSure Unit ID: Max Concentrations (all compounds) - Mav 26.2020 ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 µg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. All concentrations are in u2/m3 CAS # Chemical Name: Indoor Air Concentration 3 (ug/m) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non - Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 20.7 2.7E+04 1.5E-04 75-05-8 Acetonitrile 0.415 5.3E+01 1.6E-03 107-02-8 Acrolein 0.802 1.8E-02 9.2E+00 7143-2 Benzene 0.671 1.6E+00 2.6E+01 4.3E-07 5.1E-03 75-15-0 Carbon Disulfide 0.25 6.1E+02 8.2E-05 56-23-5 Carbon Tetrachloride 0.552 2.0E+00 8.8E+01 2.7E-07 1.3E-03 75-71-8 Dichlorodifluoromethane 3.48 8.8E+01 7.9E-03 123-91-1 Dioxane, 1,4- 0.472 2.5E+00 2.6E+01 1.9E-07 3.6E-03 141-78-6 Ethyl Acetate 2.52 6.1E+01 8.2E-03 100414 Eth lbenzene 1.05 4.9E+00 8.8E+02 2.1E-07 2.4E-04 109-99-9 -Tetrah drofuran 0.819 1.8E+03 9.3E-05 142-82-5 He tane, N- 0.333 3.5E+02 1.9E-04 110-54-3 Hexane, N- 0.293 6.1E+02 9.6E-05 591-78-6 Hexanone, 2- 1.73 2.6E+01 1.3E-02 67-63-0 Iso ro anol 4.81 1.8E+02 5.5E-03 78-93-3 Methyl Ethyl Ketone 2-Butanone 2.74 4.4E+03 1.3E-04 108-10-1 Methyl Isobutyl Ketone 4-meth 1-2- entanone 1.1 2.6E+03 8.4E-05 75-09-2 Methylene Chloride 0.72 1.2E+03 5.3E+02 5.9E-10 2.7E-04 91-20-3 -Naphthalene 0.528 3.6E-01 2.6E+00 1.5E-06 4.0E-02 115-07-1 Propylene 0.739 2.6E+03 5.6E-05 10042-5 Styrene 0.479 8.8E+02 1.1E-04 108-88-3 Toluene 0.96 4.4E+03 4.4E-05 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2- 2.22 4.4E+03 1.0E-04 120-82-1 Trichlorobenzene, 1,2,4- 0.396 1.8E+00 4.5E-02 75-69-4 Trichlorofluoromethane 1.92 95-63-6 Trimeth lbenzene, 1,2,4- 1.21 5.3E+01 4.6E-03 108-67-8 1 Trimeth lbenzene, 1,3,5- 1 0.339 1 5.3E+01 1 -03 108-38-3 X lene, m- 3.1 8.8E+01 7.1E-03 95-47-6 X lene, o- 1.12 8.8E+01 2.6E-03 Cumulative: I 2.6E-06 9.3E+00 North Carolina DEQ Risk Calculator APPENDIX F INDOOR AIR AND AMBIENT AIR RISK CALCULATIONS (MINUS ACROLEIN) 10 Mid Atlantic North Carolina Department of Environmental Quality Risk Calculator Version Date: December 2019 Basis: November 2019 EPA RSL Table Site Name: Northern Telecom (Park Point) Site Address: 4001 and 4151 NC East Hwy 54, Durham, NC DEQ Section: Brownfields Program Site ID: MAA Project Number R3358.01 Exposure Unit ID: Max Concentrations (minus acrolein) May 26, 2020 Submittal Date: 6/2/2020 Prepared By: Katie Lippard Reviewed B North Carolina DEQ Risk Calculator Risk for Individual Pathways rim Version Date: December 2019 Basis: November 2019 EPA RSL Table 7 Site ID: MAA Project Number R3358.01 Exposure Unit ID: Max Concentrations minus acrolein May 26, 2020 DIRECT CONTACT SOIL AND WATER CALCULATORS Receptor Pathway Carciinn kenic Hazard Index Risk exceeded? Resident Soil 0.0E+00 0.0E+00 NO NC Groundwater Use* NC NC Non -Residential Worker Soil 0.0E+00 0.0E+00 NO Groundwater Use* NC NC NC Construction Worker Soil NC NC NC Recreator/Trespasser Soil NC NC NC Surface Water* NC NC NC VAPOR INTRUSION CALCULATORS no Receptor Pathway CarcinogenicRisk Hazard Index Risk exceeded? Resident Groundwater to Indoor Air 0.0E+00 0.0E+00 NO Soil Gas to Indoor Air 0.0E+00 0.0E+00 NO Indoor Air 1.1E-05 6.3E-01 NO Non -Residential Worker Groundwater to Indoor Air 0.0E+00 0.0E+00 NO Soil Gas to Indoor Air 0.0E+00 0.0E+00 NO Indoor Air 2.6E-06 1.5E-01 NO CONTAMINANT MIGRATION CALCULATORS Pathway Source Target Receptor Concentrations Exceeded? Groundwater Source Soil Exceedence of 21, at Receptor? NM Source Groundwater Exceedence of 21, at Receptor? NM Surface Water Source Soil Exceedence of 2B at Receptor? NM Source Groundwater Exceedence of 2B at Receptor? NM Notes: 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 213 Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk -based closure. 3. NM = Not Modeled 4. NC = Pathway not complete North Carolina DEQ Risk Calculator Risk Calculator - Vapor Intrusion - Resident Indoor Air ersion Date: December 2019 asis: November 2019 EPA RSL Table Site ID: MAA Project Number R3358.01 Exposure Unit ID: Max Concentrations (minus acrolein) Mav 26. 2020 ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 µg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. All concentrations are in ug/m3 CAS # Chemical Name: Indoor Air Concentration 3 (ug/m) Target Indoor Au Conc. for Carcinogens @ TCR = 1 E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 20.7 6.5E+03 6.4E-04 75-05-8 Acetouitrile 0.415 1.3E+01 6.6E-03 107-02-8 Acrolein 4.2E-03 71-43-2 Benzene 0.671 3.6E-01 6.3E+00 1.9E-06 2.1E-02 75-15-0 Carbon Disulfide 0.25 1.5E+02 3.4E-04 56-23-5 Carbon Tetrachloride 0.552 4.7E-01 2.1E+01 1.2E-06 5.3E-03 75-71-8 Dichlorodifluoromethane 3.48 2.1E+01 3.3E-02 123-91-1 Dioxane, 1,4- 0.472 5.6E-01 6.3E+00 8.4E-07 1.5E-02 141-78-6 Ethyl Acetate 2.52 1.5E+01 3.5E-02 100-41-4 Eth lbenzene 1.05 1.1E+00 2.1E+02 9.3E-07 1.0E-03 109-99-9 -Tetrah drofuran 0.819 4.2E+02 3.9E-04 142-82-5 Heptane, N- 0.333 8.3E+01 8.0E-04 110-54-3 Hexane, N- 0.293 1.5E+02 4.0E-04 591-78-6 Hexanone, 2- 1.73 6.3E+00 5.5E-02 67-63-0 Isopropanol 4.81 4.2E+01 2.3E-02 78-93-3 Methyl Ethyl Ketone (2-Butanone) 2.74 1.0E+03 5.3E-04 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone) 1.1 6.3E+02 3.5E-04 75-09-2 Methylene Chloride 0.72 1.0E+02 1.3E+02 7.1E-09 1.2E-03 91-20-3 -Naphthalene 0.528 8.3E-02 6.3E-01 6.4E-06 1.7E-01 115-07-1 Propylene 0.739 6.3E+02 2.4E-04 100-42-5 Styrene 0.479 2.1E+02 4.6E-04 108-88-3 Toluene 0.96 1.0E+03 1.8E-04 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2- 2.22 1.0E+03 4.3E-04 120-82-1 Trichlorobenzene, 1,2,4- 0.396 4.2E-01 1.9E-01 75-694 Trichlorofluoromethane 1.92 95-63-6 Trimethylbenzene, 1,2,4- 1.21 1.3E+01 1.9E-02 108-67-8 Trimethylbenzene, 1,3,5- 0.339 1.3E+01 5.4E-03 108-38-3 Xylene, m- 3.1 2.1E+01 3.0E-02 9547-6 Xylene, o- 1.12 2.1E+01 1.1E-02 Cumulative: I 1.1E-05 I6.3E-01 North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non -Residential Worker Indoor Air i Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: MAA Project Number R3358.01 Ex osure Unit ID: Max Concentrations minus acrolein May 26, 2020 ** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 µg/m3. Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are likely not associated with vapor intrusion. All concentrations are in u m3 1.5E-0 l CAS # Chemical Name: Indoor Air Concentration 3 (ug/m) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non - Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 20.7 - 2.7E+04 1.5E-04 75-05-8 Acetonitrile 0.415 - 5.3E+01 1.6E-03 107-02-8 Acrolein - 1.8E-02 7143-2 Benzene 0.671 1.6E+00 2.6E+01 4.3E-07 5.1E-03 75-15-0 Carbon Disulfide 0.25 - 6.1E+02 8.2E-05 56-23-5 Carbon Tetrachloride 0.552 2.0E+00 8.8E+01 2.7E-07 1.3E-03 75-71-8 Dichlorodifluoromethane 3.48 - 8.8E+01 7.9E-03 123-91-1 Dioxane, 1,4- 0.472 2.5E+00 2.6E+01 1.9E-07 3.6E-03 141-78-6 Ethyl Acetate 2.52 - 6.1E+01 8.2E-03 100414 Eth lbenzene 1.05 4.9E+00 8.8E+02 2.1E-07 2.4E-04 109-99-9 -Tetrah drofuran 0.819 - 1.8E+03 9.3E-05 142-82-5 He tane, N- 0.333 - 3.5E+02 1.9E-04 110-54-3 Hexane, N- 0.293 - 6.1E+02 9.6E-05 591-78-6 Hexanone, 2- 1.73 - 2.6E+01 1.3E-02 67-63-0 Iso ro anol 4.81 - 1.8E+02 5.5E-03 78-93-3 Methyl Ethyl Ketone 2-Butanone 2.74 - 4.4E+03 1.3E-04 108-10-1 Methyl Isobu 1 Ketone 4-meth 1-2- entanone 1.1 - 2.6E+03 8.4E-05 75-09-2 Methylene Chloride 0.72 1.2E+03 5.3E+02 5.9E-10 2.7E-04 91-20-3 -Naphthalene 0.528 3.6E-01 2.6E+00 1.5E-06 4.0E-02 115-07-1 Propylene 0.739 - 2.6E+03 5.6E-05 10042-5 Styrene 0.479 - 8.8E+02 1.1E-04 108-88-3 Toluene 0.96 - 4.4E+03 4.4E-05 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2- 2.22 - 4.4E+03 1.0E-04 120-82-1 Trichlorobenzene, 1,2,4- 0.396 - 1.8E+00 4.5E-02 75-69-4 Trichlorofluoromethane 1.92 - - 95-63-6 Trimeth lbenzene, 1,2,4- 1.21 - 5.3E+01 4.6E-03 108-67-8 Trimeth lbenzene, 1,3,5- 0.339 - 5.3E+01 1.3E-03 108-38-3 X lene, in- 3.1 - 8.8E+01 7.1E-03 95-47-6 X lene, o- 1.12 - 8.8E+01 2.6E-03 Carolina DEQ Risk Calculator APPENDIX G SUB -SLAB SOIL GAS VAPOR INTRUSION RISK CALCULATIONS (JANUARY 2017) 10 Mid Atlantic North Carolina Department of Environmental Quality Risk Calculator Version Date: December 2019 Basis: November 2019 EPA RSL Table Site Name: Northern Telecom Site Address: 4001 and 4151 East NC Hwy 54 DEQ Section: Brownfields Site ID: Brownfields Proj. # 23079-19-032 Exposure Unit ID: Cumulative Risk For Individual Pathways (Jan. 26, 2017 data) Submittal Date: 5/l/2020 Prepared By: Katie Lippard Reviewed B North Carolina DEQ Risk Calculator Risk for Individual Pathways rim Version Date: December 2019 Basis: November 2019 EPA RSL Table 7 Site ID: Brownfields Proj. # 23079-19-032 Ex ooure Unit ID: Cumulative Risk For Individual Pathways Jan. 26, 2017 data) DIRECT CONTACT SOIL AND WATER CALCULATORS Receptor Pathway Risk Carcinogenic Hazard Index Risk exceeded`., Resident Soil 4.3E-05 1.3E-01 NO NC Groundwater Use* NC NC Non -Residential Worker Soil 2.6E-06 8.8E-03 NO Groundwater Use* NC NC NC Construction Worker Soil NC NC NC Recreator/Trespasser Soil NC NC NC Surface Water* NC NC NC VAPOR INTRUSION CALCULATORS Receptor Pathway CarcinogenicRisk Hazard Index Risk exceeded? Resident Groundwater to Indoor Air 0.0E+00 0.0E+00 NO Soil Gas to Indoor Air 1.1E-05 5.0E-01 NO Indoor Air 0.0E+00 0.0E+00 NO Non -Residential Worker Groundwater to Indoor Air 0.0E+00 0.0E+00 NO Soil Gas to Indoor Air 8.2E-07 3.9E-02 NO Indoor Air 0.0E+00 0.0E+00 NO CONTAMINANT MIGRATION CALCULATORS Pathway Source Target Receptor Concentrations Exceeded? Groundwater Source Soil Exceedence of 21, at Receptor? NM Source Groundwater Exceedence of 21, at Receptor? NM Surface Water Source Soil Exceedence of 2B at Receptor? NM Source Groundwater Exceedence of 2B at Receptor? NM Notes: 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 213 Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk -based closure. 3. NM = Not Modeled 4. NC = Pathway not complete North Carolina DEQ Risk Calculator Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: Browntields Proi. # 23079-19-032 Exposure Unit ID: Cumulative Risk For Individual Pathways (Jan. 26. 2017 Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. All concentrations are in ue/m3 CAS # Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m) Target Indoor Air Conc. for Carcinogens @ TCR = 1 E-06 Target Indoor Air Conc. for Non - Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non - Carcinogenic Hazard Quotient 67-64-1 Acetone 1400 42 6.5E+03 1.3E-03 71-43-2 Benzene 4 0.12 3.6E-01 6.3E+00 3.3E-07 3.8E-03 75-27-4 Bromodichloromethane 3.2 0.096 7.6E-02 1.3E-06 75-15-0 Carbon Disulfide 3.4 0.102 - 1.5E+02 1.4E-04 67-66-3 Chloroform 29 0.87 1.2E-01 2.0E+01 7.1E-06 8.5E-03 110-82-7 C clohexane 1.9 0.057 - 1.3E+03 9.1E-06 75-71-8 Dichlorodifluoromethane 1100 33 2.1E+01 3.2E-01 156-60-5 Dichloroeth lene, 1,2-trans- 2.3 0.069 - 100-41-4 Eth lbenzene 8.5 0.255 1.1E+00 2.1E+02 2.3E-07 2.4E-04 109-99-9 -Tetrah drofuran 19 0.57 4.2E+02 2.7E-04 110-54-3 Hexane, N- 9.5 0.285 1.5E+02 3.9E-04 67-63-0 Iso ro anol 580 17.4 4.2E+01 8.3E-02 78-93-3 Methyl Ethyl Ketone (2-Butanone) 110 3.3 1.0E+03 6.3E-04 108-10-1 Methyl Isobutyl Ketone 4-meth 1-2- entanone 71 2.13 6.3E+02 6.8E-04 75-09-2 Methylene Chloride 19 0.57 1.0E+02 1.3E+02 5.6E-09 9.1E-04 91-20-3 -Naphthalene 4.9 0.147 8.3E-02 6.3E-01 1.8E-06 4.7E-02 100-42-5 Styrene 3.7 0.111 2.1E+02 1.1E-04 108-88-3 Toluene 44 1.32 1.0E+03 2.5E-04 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2- 770 23.1 1.0E+03 4.4E-03 71-55-6 Trichloroethane, 1,1,1- 1.3 0.039 1.0E+03 7.5E-06 75-69-4 Trichlorofluoromethane 1.4 0.042 95-63-6 Trimeth lbenzene, 1,2,4- 24 0.72 1.3E+01 1.2E-02 108-67-8 Trimeth lbenzene, 1,3,5- 4.8 0.144 1.3E+01 2.3E-03 108-05-4 Vinyl Acetate 5.4 0.162 4.2E+01 7.8E-04 10642-3 X lene, P- 33 0.99 2.1E+01 9.5E-03 9547-6 X lene, o- 12 0.36 2.1E+01 3.5E-03 Cumulative: I 1.1E-05 I 5.0E-01 North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Groundwater to Indoor Air Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: Brownlields Proj. # 23079-19-032 E osure Unit ID: Cumulative Risk For Individual Pathways Jan. 26, 2017 data Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Groundwater concentrations are in on/L. Air concentrations are in u m Calculated Target Indoor Target Indoor Calculated Groundwater Indoor Air Air Conn. for Air Conn. for Calculated Non - CAS # Chemical Name: Concentrate °n Concentration Carcinogens @ Non -Carcinogens Carcinogenic Carcinogenic (ug2) (ug/m') TCR=1E-06 @THQ=0.2 Risk Quotient 7440-39-3 Barium 222 1.0E-01 Cumulative 1 0.0E+00 0.0E+00 North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non -Residential Worker Groundwater to Indoor Air 777 Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: Brownfields Proi. # 23079-19-032 Unit ID: Cumulative Risk For Individual Pathways (Jan. 26, 2017 Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. ('rrnundwnte.r cnncentratinne are in no/l.. Air cnncentratinns are in no/m3 Calculated Target Indoor Target Indoor Air Calculated Groundwater Indoor Air Air Conc. for Conc. for Non - Calculated Non - CAS # Chemical Name: Concentration Concentration Carcinogens @ Carcinogens @ Carcinogenic Carcinogenic (ug/L) (ug/m3) TCR = 1 E-06 THQ = 0.2 Risk Hazard Quotient 7440-39-3 Barium 222 4.4E-01 Cumulative: I 0.0E+00 I 0.0E+00 North Carolina DEQ Risk Calculator