RA-2582_16143_CA_MRP_20100623_Terraine MW-GW Rpt

Monitoring Well Installation &
Groundwater Monitoring Report

Former Agrotec Incorporated

7840 NC Highway 35
Pendleton, North Carolina
Northampton County
Incident No. 16143

Prepared For:
North Carolina Department of
Environment and Natural Resources
1637 Mail Service Center
Raleigh, North Carolina 27699-1637

Prepared By:

Terraine, Inc.
LongView Center
118 South Person Street Raleigh, North Carolina 27601

NCDENR Contract No. 16-1713-5C Terraine Project No. 13-NCSL09-002

June 23, 2010

Monitoring Well Installation & Groundwater Monitoring Report – 6/23/2010 Incident No. 16143 Former Agrotec Incorporated Page i Pendleton, Northampton County, North Carolina
Table of Contents
Signature Page ______________________________________________________________________ ii
I. Introduction ______________________________________________________________________ 1
II. Monitoring Well Installation and Soil Sampling Results ____________________________________ 3
III. Groundwater Sampling and Results ___________________________________________________ 4
IV. Conclusions and Recommendations __________________________________________________ 5
V. References ______________________________________________________________________ 6
Tables

Table 1 Water Supply Wells within 1,500 Feet of Source Area _______________________ App A Table 2 Well Construction Details and Groundwater Elevation Data __________________ App A
Table 3 Summary of Soil Analytical Results _____________________________________ App A Table 4 Summary of Current and Historical Groundwater Analytical Results ____________ App A
Figures
Figure 1 Topographic Map ___________________________________________________ App B Figure 2 Water Supply Wells within 1,500 Feet of Source Area _______________________ App B Figure 3 Site Map __________________________________________________________ App B Figure 4 Soil Boring Location & Analytical Data Map (3/30/2010) _____________________ App B Figure 5 Groundwater Sampling Location and Analytical Data Map (3/30/2010 & 4/6/2010) App B
Appendices

Appendix A Tables
Appendix B Figures
Appendix C Site Photographs
Appendix D Boring Log Key Soil Boring Log (SB-3T)
Soil Boring Log (SB-4T) Soil Boring Log (SB-5T)
Soil Boring Log (SB-6T) Soil Boring Log (SB-7T)
Well Construction Record (MW-3)
Appendix E Low Flow Sampling Measurements
Appendix F Chain of Custody Records Cooler Receipt Forms
Laboratory Certificates of Analysis Quality Control Certificates

Monitoring Well Installation & Groundwater Monitoring Report – 6/23/2010 Incident No. 16143 Former Agrotec Incorporated Page ii Pendleton, Northampton County, North Carolina
Signature Page
We, the undersigned, do hereby affirm that the information contained in this report is accurate and correct
to the best of our knowledge and belief.

6/23/2010
Laura R. Robertson Date Staff Geologist
Terraine, Inc.

6/23/2010 Jad R. Bean Date
Project Manager Terraine, Inc.

6/23/2010
James L. Young, L.G. Date North Carolina Licensed Geologist # 1707
Senior Geologist
Terraine, Inc.

Monitoring Well Installation & Groundwater Monitoring Report – 6/23/2010 Incident No. 16143 Former Agrotec Incorporated Page 1 Pendleton, Northampton County, North Carolina
I. Introduction
This report documents activities performed by Terraine, Inc. (Terraine) in accordance with the North
Carolina State Lead Contract Task Authorization number 13-NCSL09-002-2 authorized on March 11, 2010, by the North Carolina Department of the Environment and Natural Resources (NCDENR).
Historical information regarding this site was provided to Terraine by NCDENR. The former Agrotec, Inc. site is located at 7840 NC Highway 35 in Pendleton, Northampton County, North Carolina (Figures 1, 2,
and 3, Appendix B; Photos, Appendix C). Additional information about this site was not available in the Registered Underground Storage Tank (UST) Database maintained by NCDENR
(http://www.ncwater.org/Data_and_Modeling/Ground_Water_Databases/).
The site consists of a fenced grassy lot with a single story warehouse building used for storage by the owner, the Severn Peanut Company, which is located north of the site in Severn, NC. According to the
Environmental Site Assessment (ESA) by Banks Environmental Consultants dated May 30, 1995, soil and groundwater samples were collected in areas associated with painting operations and former USTs used by the former owners.
In 1995, the interior of the facility was reported to contain a paint digester, cutting oils, used paint cans,
old batteries, a wash pit area with floor drain, and there was also painting operation residue, and minor leakage of cutting oil or hydraulic oil present from manufacturing machinery. The exterior of the facility
was reported to have:
Five petroleum USTs
o One fuel oil UST and two gasoline USTs were located southwest of the building
o One fuel oil UST was located east of the building
o One diesel UST was located north of the building
Two aboveground storage tanks (ASTs) were located south of the southern wall of the building; one fuel oil, one kerosene
One general purpose dumpster and one metal recycling dumpster
Metal boxes used as staging areas to dry paint
Paint storage area
Paint spray water wash system with a sump well and water capture basin
Enclosure for housing a former steam cleaner and two 55-gallon barrels of cleaning solution
Storage area for new and used compressed gas cylinders
Empty 55-gallon steel drum converted into a storage tank
Burn pile used to burn pallets and other wood-based and paper items
Septic tank near the southwest corner of the building
All five USTs and one AST have reportedly been removed from the site. Soil samples were collected from nine soil borings surrounding the building. The soil samples collected near the gasoline USTs were noted
to smell of petroleum; however, only a soil sample collected from soil boring SB-4 and a groundwater sample collected from GW-2 had detected amounts of gasoline- and diesel-range organics; these
samples were collected from soil borings on the eastern side of the warehouse building, south of the fuel oil UST.
According to the Pollution Incident/UST Leak Reporting Form dated June 1, 1995, a modified Phase I Environmental Investigation identified groundwater contamination of 58 parts per billion (ppb)
ethylbenzene; 1,400 ppb xylenes; and 31 ppb naphthalene. The amount of gasoline/diesel material leaking from the UST was unknown. This form does not specify which UST was leaking or from where the
samples were taken. Six private domestic water supply wells were identified within 1,500 feet down-gradient of the contaminant source; at least one was within 250 feet of the source area.

Monitoring Well Installation & Groundwater Monitoring Report – 6/23/2010 Incident No. 16143 Former Agrotec Incorporated Page 2 Pendleton, Northampton County, North Carolina
According to the June 26, 1995, NCDENR Response to the ESA, rain water infiltration was maintaining the contaminant concentrations above the regulatory limits, but the site did not appear to be a significant
threat to human health or the environment. A Release Report/Complaint Log was attached to the
NCDENR Response. This document identified the release as a UST surface spill of gasoline and
solvents.
According to the NCDENR Inspection Report dated June 29, 2006, the site was classified as “High Risk.”
The site was described as vacant and gated. Water supply wells were determined to be located near the site. According to the ESA, the property was served by the county water department.
Terraine performed a modified Phase I Limited Site Assessment (LSA) at this site in September and October 2009. This report identified five water supply wells located within 1,500 feet of the source area, at
least three of which were used for drinking water: WSW-1, WSW-3, and WSW-4 (Table 1, Figure 2). Analysis of groundwater samples identified several contaminants in water supply wells WSW-2 and
WSW-3 in October 2009. As part of the Phase I LSA, two monitoring wells were installed, MW-1 in September 2009 and MW-2 in December 2009. After a January 2010 sampling event, a concentration of
lead was identified above the 2L Standard in the groundwater sample from monitoring well MW-2. Historical groundwater analytical results are summarized in Table 4. Groundwater flow was inferred to be
toward the southwest, based on topography (Figure 1).
Based on the results of the Phase I LSA, NCDENR requested additional soil and groundwater sampling,
along with the installation of another on-site monitoring well, MW-3. The soil borings were advanced in former tank locations, and the monitoring well was placed at the southern border of the property in order
to determine if the nearby water supply well contamination in WSW-2 may be caused by an on-site source area. The following report documents monitoring well installation activities conducted by Terraine
on March 30, 2010, and groundwater sampling activities conducted on April 6, 2010.

Monitoring Well Installation & Groundwater Monitoring Report – 6/23/2010 Incident No. 16143 Former Agrotec Incorporated Page 3 Pendleton, Northampton County, North Carolina
II. Monitoring Well Installation & Soil Sampling Results
On March 30, 2010, Terraine personnel supervised the installation of five soil borings for the collection of
soil and groundwater samples by Geologic Exploration, Inc. of Statesville, North Carolina.
Soil boring SB-3T was placed at the southern property boundary, as suggested by the NCDENR incident
manager. Soil boring SB-3T was drilled to 11 feet bsg, and included light brown fine-grained clayey sand to light tan fine-grained sand. Soil borings SB-4T, SB-5T, SB-6T, and SB-7T were each placed in the
vicinity of former underground and above ground storage tanks, as identified in historical records (Figure 4). The soil borings were installed using a hand auger. Lithological observations generally indicated that
the subsurface to a depth of 5 feet below surface grade (bsg) is generally comprised of light brown and red, coarse-grained, well-sorted sand.
Upon retrieval of the soil cores, soil samples were sealed in resealable plastic bags. The bagged portions
were allowed to volatilize for a minimum of 15 minutes, after which the headspaces within the bags were field-screened for the presence of volatile organic vapors with a calibrated Mini RAE Systems™ photo-
ionization detector (PID). Soil samples were collected from each soil boring from the horizon just above the water table. Samples were collected into laboratory prepared containers, placed immediately on ice,
and submitted under proper chain of custody controls to the Pace Analytical Services, Inc. laboratory in Huntersville, North Carolina, for chemical analyses. The soil boring logs, lithological descriptions and PID
readings are included in Appendix D. The laboratory report, associated chain of custody record, and cooler receipt form are included in Appendix F.
Target contaminants were not detected above Maximum Soil Contaminant Concentrations (MSCCs) in
the soil samples collected from soil borings SB-3T, SB-4T, SB-5T, SB-6T, and SB-7T. Concentrations of total aliphatic hydrocarbons (C09-C18) and total aromatic hydrocarbons (C09-C22) were detected in the
soil sample from soil boring SB-4T at a depth of 2 feet bsg. Table 3 provides a summary of current soil analytical results. Soil boring locations and analytical results are provided in Figure 4.
Soil boring SB-3T was converted into monitoring well MW-3 on December 7, 2009, using a GeoProbe
6620 DPT turning 6-inch inner diameter hollow stem augers. The well was set at a total depth of 11 feet bsg with a screened interval from 1 foot bsg to 11 feet bsg. The well was completed with standard Type II
construction and was developed using a submersible pump to remove sediment to the fullest extent possible. The well construction record is included in Appendix D.

Monitoring Well Installation & Groundwater Monitoring Report – 6/23/2010 Incident No. 16143 Former Agrotec Incorporated Page 4 Pendleton, Northampton County, North Carolina
III. Groundwater Sampling and Results

Groundwater samples were collected from soil borings SB-4T, SB-5T, SB-6T, and SB-7T on March 30, 2010 using new check valve and tubing assemblies. Groundwater samples were collected into laboratory
prepared containers, placed immediately on ice, and submitted under proper chain of custody controls to Pace Analytical Services, Inc. laboratory in Huntersville, North Carolina, for chemical analyses. The
laboratory report, associated chain of custody record, and cooler receipt form are included in Appendix F. The groundwater samples collected from soil borings SB-4T and SB-5T contained target contaminant
concentrations above 2L Standards; a sheen was noted on the surface of the groundwater sample from SB-5T and a strong petroleum odor was observed. Lead was detected above 2L Standards in the
groundwater samples collected from soil borings SB-4T, SB-5T, SB-6T, and SB-7T. Samples obtained were noted to be turbid; samples that are turbid usually contain higher proportions of metals.
On April 6, 2010, Terraine personnel mobilized to the site to collect groundwater samples from monitoring
wells MW-2 and MW-3. Monitoring well locations are shown in Figure 3. Prior to sampling, depth to water measurements were obtained from monitoring wells MW-2 and MW-3 using a decontaminated oil-water
interface probe (Table 2). Terraine attempted to survey the wells’ top of casing elevations on April 6, 2010, but were unable to collect this data due to equipment malfunction in the field, unrelated to battery
power. As a result, groundwater flow direction based on groundwater elevations could not be determined. Monitoring wells MW-2 and MW-3 were purged using low flow methodology until field parameters
(temperature, dissolved oxygen, pH, conductivity, turbidity, depth to water, and oxidation-reduction potential) stabilized. Low flow sampling measurements are included in Appendix E. Groundwater
samples obtained on April 6, 2010, were collected into laboratory prepared containers, placed immediately on ice, and submitted under proper chain of custody controls to the Pace Analytical Services,
Inc. laboratory in Huntersville, North Carolina, for chemical analyses. The laboratory report, associated chain of custody record, and cooler receipt form are included in Appendix F.
Target contaminants were not detected above method detection limits in the groundwater samples
collected from monitoring wells MW-2 and MW-3. Table 4 provides a summary of current and historical groundwater analytical results. Monitoring well locations and groundwater analytical results are provided
in Figure 5.

Monitoring Well Installation & Groundwater Monitoring Report – 6/23/2010 Incident No. 16143 Former Agrotec Incorporated Page 5 Pendleton, Northampton County, North Carolina
IV. Conclusions and Recommendations
A. Conclusions

Terraine performed a monitoring well installation and groundwater sampling event at the Former Agrotec, Incorporated site and, upon review of the assessment activities and results, concludes the following:
No residual soil contamination at concentrations greater than MSCCs was detected in soil
samples from borings on March 30, 2010.
1,2-Dichloroethane was detected in groundwater samples collected from soil boring SB-4T;
naphthalene, 2-methylnaphthalene, C09-C18 total aliphatic hydrocarbons, and C09-C22 total aromatic hydrocarbons were detected in groundwater samples collected from soil boring SB-5T
above 2L Standards but below GCLs.
Lead was identified at levels that exceed the 2L standard in the groundwater samples from all of the soil borings. Samples obtained from soil borings were noted to be turbid; samples that are
turbid usually contain higher proportions of metals.
No target contaminants were detected above method detection limits in groundwater samples from monitoring wells MW-2 or MW-3.
There is no clear correlation between the contaminants detected in groundwater in April 2010 on site and the contaminants detected in groundwater from water supply wells surrounding the site in
October 2009.
B. Recommendations
Based on the laboratory analytical results from the past sampling events, Terraine recommends the
following:
Sample on-site monitoring wells and all water supply wells within 1,500 feet of the site. The next sampling event is suggested for October 2010.

Determine if resident on property on which water supply well WSW-1 is located is using municipal water or well water.

Survey monitoring well top of casing elevations.

Monitoring Well Installation & Groundwater Monitoring Report – 6/23/2010 Incident No. 16143 Former Agrotec Incorporated Page 6 Pendleton, Northampton County, North Carolina
V. References
Banks Environmental Consultants. Environmental Site Assessment, May 30, 1995.
NCDENR. Division of Water Resources Ground Water Database Access, from:
http://www.ncwater.org/Data_and_Modeling/Ground_Water_Databases/.
NCDENR. Inspection Report, June 29, 2006.
NCDENR. Pollution Incident/UST Leak Reporting Form, June 1, 1995.
NCDENR. Recommendation for State Lead Cleanup Memo, December 8, 2006.
NCDENR. Response to ESA, June 26, 1995.
Terraine, Inc. Limited Site Assessment Report – Phase 1. February 16, 2010.

Monitoring Well Installation & Groundwater Monitoring Report – 6/23/2010 Incident No. 16143 Former Agrotec Incorporated Pendleton, Northampton County, North Carolina
Appendix A
Table 1 Water Supply Wells within 1,500 Feet of Source Area Table 2 Well Construction Details and Groundwater Elevation Data
Table 3 Summary of Soil Analytical Results Table 4 Summary of Current and Historical Groundwater Analytical Results
Table 1
Water Supply Wells within 1,500 Feet of Source Area
Former Agrotec Incorporated
7840 NC Highway 35
Pendleton, NC
Northampton County
NCDENR Incident No. 16143
WELL ID PARCEL ID PROPERTY OWNER PROPERTY ADDRESS WATER USE
MUNICIPAL
WATER DISTANCE
301217 Thomas & Elvornia Long
7795 NC Hwy 35 N,
Pendleton, NC Unknown YES
301854 Ernest & Bernice Warren
7748 NC Hwy 35 N,
Pendleton, NC Drinking NO*
WSW-2 300434
Jarvis & Gerthare
Vaughan
7687 NC Hwy 35,
Pendleton, NC Unknown YES
1,300 Feet
SOUTH
WSW-3 301526 Roger & Mary Everette
7744 NC Hwy 35
Pendleton, NC Drinking NO
480 Feet
SOUTHEAST
WSW-4 1300582 Mrs. Clyde Martin
7748 NC Hwy 35
Pendleton, NC Drinking NO
250 Feet
SOUTHEAST
WSW-5 302600 Albert & Marion Ridley
7941 NC Hwy 35
Pendleton, NC Unknown YES
900 feet
NORTHWEST
*According to the Northampton County Public Works Department, this residence is serviced by county water. Resident denies this.
Parcel information obtained from the Northampton County GIS website: http://gis.northamptonnc.com.
Water Use information obtained from the Northampton County Public Works Department.
WSW-1 450 Feet
SOUTHWEST
Table 2Well Construction Details and Groundwater Elevation DataFormer Agrotec Incorporated7840 NC Highway 35Pendleton, NCNorthampton CountyNCDENR Incident No. 16143WELL IDINSTALLATION DATETOC ELEVATION SCREEN INTERVAL WELL DIAMETER (IN.)TOTAL DEPTHWELL GAUGE DATEDEPTH TO WATERGROUNDWATER ELEVATION 10/8/2009 5.48 94.521/7/2010 3.84 96.161/7/2010 1.82 NM4/6/2010 1.86 NMMW-3 3/30/2010 NM 1-11 2 11 4/6/2010 2.32 NMTOC - Top of casingNM - Not measuredUnits measured in feet unless otherwise noted. Groundwater elevations relative to an arbitrary benchmark of 100.00 feet at MW-1 TOC. MW-1 9/24/2009 100.00 3-13 2 13MW-2 12/7/2009 NM 3-13 2 13
Table 3
Summary of Soil Analytical Results
Former Agrotec Incorporated
7840 Highway 35 North
Pendleton, NC
Northampton County
NCDENR Incident No. 16143
EPA 8260B:
Benzene 0.0056 18
Toluene 4.3 1,200
Ethylbenzene 4.9 1,560
Xylenes (total)4.6 3,129
Methyl tert-Butyl Ether 0.091 350
0.16 313
0.35 0.88
1.2 0.88
39 88
290 620
NE NE
Acetone 24 14,000
MADEP VPH/EPH:
68 939
C09-C12 Aliphatics ND 52.1 ND ND ND
C09-C18 Aliphatics ND ND ND ND ND
Considered
Immobile 31,000
C09-C10 Aromatics ND 13.6 ND ND ND
C11-C22 Aromatics ND ND ND ND ND
Data expressed in parts per million (mg/kg)
NE - No Standard Established
ND - None Detected (below method detection limits)
A complete list of target compounds is included with the laboratory report in Appendix F
MSCC - Maximum Soil Contaminant Concentration
EPA - Environmental Protection Agency
MADEP - Massachusetts Department of Environmental Protection
VPH - Volatile Petroleum Hydrocarbons
EPH - Extractable Petroleum Hydrocarbons
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
ND
ND
52.1
ND
13.6
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
13:00
ND
Benzo(a)anthracene ND
Benzo(b)fluoranthene ND
Chrysene ND
3,3'-Dichlorobenzidine ND
Fluoranthene ND
ND
ND
Naphthalene ND
C09-C18 Aliphatic
Hydrocarbons
C09-C22 Aromatic
Hydrocarbons
C05-C08 Aliphatic Hydrocarbons
C19-C36 Aliphatic Hydrocarbons
SB-4T 2FT
2
3/30/10
10:45
ND
Sample ID:
Depth (feet):
Sample Date:
Sample Time:
2
3/30/10
ND
SB-3T 2FT SB-5T 1.5FT
1.5
3/30/10
11:15
ND
469
540 1,500
31
MSCC (Soil-to-
Groundwater)
Residential
Cleanup
Levels
ND 0.090 J ND
ND 0.083 J ND
ND 0.091 J ND
ND 0.15 J 0.14 J
ND
ND
ND
ND
ND
0.012 J ND ND
ND ND
ND
ND
ND
ND
ND
ND
NDND
ND
ND
ND ND
0.067 J
ND
ND
ND
ND
SB-7T 2FT
2
3/30/10
12:30
ND
ND
ND
ND
ND
ND
SB-6T 2FT
2
3/30/10
11:45
ND
ND ND
Table 4Summary of Current and Historical Groundwater Analytical ResultsFormer Agrotec Incorporated7840 NC Highway 35Pendleton, NCNorthampton CountyNCDENR Incident No. 16143Well ID Sample DateAliphatic (C05-C08)Aliphatic (C09-C12) Aliphatic (C09-C18)Total Aliphatics (C09-C18)Aliphatic (C19-C36)Aromatic (C09-C10)Aromatic (C11-C22)Total Aromatics (C09-C22)MW-1 10/8/2009 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 9.11/7/2010 ND ND ND ND ND ND ND ND ND ND ND ND 18.7 9 7.3 8.7 J ND ND ND ND ND 50.1 J 15.7 ND 8.7 ND ND ND ND ND ND ND ND2164/6/2010 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDMW-3 4/6/2010 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDSB-4T 3/30/2010 ND ND ND ND ND ND ND ND ND ND ND0.58ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND217SB-5T 3/30/2010 ND ND ND ND ND ND ND12.7ND ND ND ND ND ND ND ND 1.8 5.4 J42.60.59 3.0 ND ND 8.6 ND ND 236 9,2309,4662,330 129 6,5106,639 1,040SB-6T 3/30/2010 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND646SB-7T 3/30/2010 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND780WSW-1 10/8/2009 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDWSW-2 10/8/2009 ND ND ND ND ND ND ND ND 1.5 0.91.8ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDWSW-3 10/8/2009 ND 0.53 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 6.2WSW-4 10/8/2009 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND1 600 600 500 20 70 0.02 6 NE 70 0.4 0.4 NE NE NE 100 400 300 30 70 70 NE NE 200 30 420NE NE 4,200 42,000 NE NE 21015Gross Contamination Level (GCL)5,000 260,000 84,500 85,500 20,000 70,000 50 6,000 NE 70,000 400 400 NE NE NE 100,000 28,500 990 12,500 30,000 8,500 NE NE 410 30,000 NE NE NE NENENE NE NE 15,000Values shown in bold, italicized, yellow highlighted font indicate concentrations that exceed the 2L StandardsIn cases where an analyte was detected by more than one method, the higher result is displayed.A complete list of target compounds is included with the laboratory report in Appendix FMADEP - Massachusetts Department of Environmental ProtectionVPH - Volatile Petroleum HydrocarbonsEPH - Extractable Petroleum HydrocarbonsJ - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limitLead1,2-DichloroethaneFluorene2-Methylnaphthalenen-Propylbenzene1,2,4-TrimethylbenzeneN-NitrosodimethylaminePhenolsec-ButylbenzenePhenanthreneEDB - 1,2-DibromoethaneBenzeneTolueneEthylbenzeneXylenesND - None Detected (below method detection limit)NE - No Standard EstablishedMTBE - Methyl tert-butyl etherIPE - Diisopropyl etherMTBEMW-2MADEP VPH & EPH15A NCAC 2L.0202 (2L) StandardAll results expressed in µg/L (ppb)IPEEDBNaphthaleneBromodichloromethaneChloroformDibromochloromethane4-Chloro-3-methylphenol2-Chlorophenol3,3-Dichlorobenzidine2,4-Dimethylphenol4-Nitrophenol

Monitoring Well Installation & Groundwater Monitoring Report – 6/23/2010 Incident No. 16143 Former Agrotec Incorporated Pendleton, Northampton County, North Carolina
Appendix B

Figure 1 Topographic Map Figure 2 Water Supply Wells within 1,500 Feet of Source Area
Figure 3 Site Map Figure 4 Soil Boring Location & Analytical Data Map (3/30/2010)
Figure 5 Groundwater Sampling Location and Analytical Data Map (3/30/2010 & 4/6/2010)

Monitoring Well Installation & Groundwater Monitoring Report – 6/23/2010 Incident No. 16143 Former Agrotec Incorporated Pendleton, Northampton County, North Carolina
Appendix C
Site Photographs
Site Photographs
Former Agrotec Incorporated
7840 NC Highway 35
Pendleton, NC
Northampton County
NCDENR Incident # 16143
View to the north from the southern property boundary.1 of 4
View to the east of monitoring well MW-3. Railroad is in background.2 of 4
Site Photographs
Former Agrotec Incorporated
7840 NC Highway 35
Pendleton, NC
Northampton County
NCDENR Incident # 16143
View of east face of building; monitoring well MW-2 is next to building.3 of 4
Bucket of Round-Up herbicide in swampy area 20 feet west of
monitoring well MW-2.
4 of 4

Monitoring Well Installation & Groundwater Monitoring Report – 6/23/2010 Incident No. 16143 Former Agrotec Incorporated Pendleton, Northampton County, North Carolina
Appendix D
Boring Log Key Soil Boring Log (SB-3T)
Soil Boring Log (SB-4T) Soil Boring Log (SB-5T)
Soil Boring Log (SB-6T) Soil Boring Log (SB-7T) Well Construction Record (MW-3)
SILT
MUDSTONE
SAND
GRAVEL
LIMESTONE
DOLOMITE
CHERT
METAMORPHIC BEDROCK
IGNEOUS
COAL
CONCRETE
ASPHALT
ORGANIC SOIL
FILL
CLAY
OOLITES,PISOLITESCONCTRETIONS,ETC.
BEDDING PLANES
CALCITE,LIMESTONE
FOSSILS CHERT
SAND
CLAY,SHALE
DOLOMITE H
SILT
FRACTURES
VISIBLE POROSITY
HYDROCARBON ODOR,STAINING,FREE PRODUCT
MODIFYING COMPONENTS,CEMENTS,ETC.
SOIL AND ROCK LITHOLOGY SYMBOLS
SOLID PIPE WITHNOPACKING
GROUT SEALAROUNDSOLID PIPE
BENTONITE SEALAROUNDSOLIDPIPE
SOLID PIPEPACKEDINSAND
SLOTTED PIPEPACKEDINSAND
END CAP ON SLOTTEDPIPEPACKEDINSAND
SS
ST P
CS OVD
SPLIT SPOON SAMPLE75-100%RECOVERY
SHELBY TUBE SAMPLE50-75 %RECOVERY
CONTINUOUS SAMPLE25-50%RECOVERYANALYZEDWITHOVD
COMPLETION DIAGRAM SYMBOLS SAMPLE SYMBOLS
WATER LEVELFIRSTENCOUNTERED
WATER LEVELUPONCOMPLETION
SS -SPLIT SPOONST-SHELBY TUBECS-CONTINUOUS SAMPLEOVD-ORGANIC VAPOR DETECTORk-PERMEABILITY
X -75-100%RECOVERY>-50-75%RECOVERY<-25-50%RECOVERYI-0-25%RECOVERY
SYMBOLS AND ABBREVIATIONS USED IN BORING LOGS
3/30/10 @ 13:00
3/30/10 @ 14:30
SB-3T
MW-3
TOPSOIL
LIGHTBROWNFINE-GRAINED CLAYEY SAND,MOIST0.6 ppm
2-in
2"PVCScreen(10-slot)
#2FilterSand End Plug
LockingCap
2"PVCCasing
PortlandCementGrout
BentoniteSeal 3 ft3/30/10
2.32ft4/6/10
Soil boring SB-3T was converted to monitoring well MW-3 on March 30,2010.
8260BVPHEPH
BORING TERMINATED AT 11 FEET BSG
11 Feet
LIGHTTANFINE-GRAINED SAND,WET
START DATE &TIME:
COMP.DATE&TIME:
LOGGEDBY:
DRILLER:
DRILLING METHOD:
ELEV (MSL):T.D.(MSL):
COMMENTS:
Incident#:BORING#
WELL#
FACILITY NAME:
LOCATION MAP:
COMPLETION
DIAGRAM
BOREHOLE DIAMETER:WATERLEVELPENETRATIONRATEMSL DEPTH /
TIME
GRAPHIC
LITHOLOGY OVD
SAMPLES&CORES
TYPEREC.ANALDESCRIPTION(Color,Texture,Structure,etc.)
Standard Boring Log
0 1 2 3 4 5 6 7 8
20
10
0
30
40
50 50
20
10
0
30
40
Former Agrotec Incorporated,7840 NC Highway 35,Pendleton,Northampton County,NC 16143
Laura Robertson Terraine
James Hess,Geologic Exploration,Inc.
Geoprobe 6620 DPT
PG 5
OF 5
3/30/10 @ 10:35
3/30/10 @ 11:05
SB-4T
LIGHTBROWN,COARSE-GRAINEDWELL-SORTEDSAND,MOIST
3feet
3/30/10
Groundwater sample SB-4T was collected from soil boring SB-4T.Soil boring SB-4T
was not converted to a monitoring well.
0.9 ppm
8260B
VPHEPH
TOPSOIL
BORING TERMINATEDAT 5 FEET BSG
5 Feet
START DATE &TIME:
COMP.DATE&TIME:
LOGGEDBY:
DRILLER:
DRILLING METHOD:
ELEV (MSL):T.D.(MSL):
COMMENTS:
Incident#:BORING#
WELL#
FACILITY NAME:
LOCATION MAP:
COMPLETION
DIAGRAM
BOREHOLE DIAMETER:WATERLEVELPENETRATIONRATEMSL DEPTH /
TIME
GRAPHIC
LITHOLOGY OVD
SAMPLES&CORES
TYPEREC.ANALDESCRIPTION(Color,Texture,Structure,etc.)
Standard Boring Log
0 1 2 3 4 5 6 7 8
20
10
0
30
40
50 50
20
10
0
30
40
Former Agrotec Incorporated,7840 NC Highway 35,Pendleton,Northampton County,NC 16143
Laura Robertson Terraine
James Hess,Geologic Exploration,Inc.
Geoprobe 6620 DPT
PG 5
OF 5
2.5 feet3/30/10
3/30/10 @ 11:15
3/30/10 @ 11:35
SB-5T
TOPSOIL
0.9ppm
8260BVPH
EPH LIGHT BROWN,COARSE-GRAINED WELL-SORTEDSAND,MOIST,PETROLEUMODOR
BORINGTERMINATEDAT5FEETBSG
Groundwater sample SB-5T was collected from soil boring SB-5T.Soil boring SB-5T
was not converted to a monitoring well.A strong petroleum odor was noted.
5 Feet
START DATE &TIME:
COMP.DATE&TIME:
LOGGEDBY:
DRILLER:
DRILLING METHOD:
ELEV (MSL):T.D.(MSL):
COMMENTS:
Incident#:BORING#
WELL#
FACILITY NAME:
LOCATION MAP:
COMPLETION
DIAGRAM
BOREHOLE DIAMETER:WATERLEVELPENETRATIONRATEMSL DEPTH /
TIME
GRAPHIC
LITHOLOGY OVD
SAMPLES&CORES
TYPEREC.ANALDESCRIPTION(Color,Texture,Structure,etc.)
Standard Boring Log
0 1 2 3 4 5 6 7 8
20
10
0
30
40
50 50
20
10
0
30
40
Former Agrotec Incorporated,7840 NC Highway 35,Pendleton,Northampton County,NC 16143
Laura Robertson Terraine
James Hess,Geologic Exploration,Inc.
Geoprobe 6620 DPT
PG 5
OF 5
3 feet3/30/10
3/30/10 @ 11:45
3/30/10 @ 12:20
SB-6T
TOPSOIL
3.1 ppm
8260BVPH
EPH
LIGHT BROWN, COARSE-GRAINED WELL-SORTED
SAND,MOIST
BORING TERMINATED AT 5 FEET BSG
Groundwater sample SB-6T was collected from soil boring SB-6T. Soil boring SB-6T
was not converted to a monitoring well.
5 Feet
START DATE & TIME:
COMP. DATE & TIME:
LOGGED BY:
DRILLER:
DRILLING METHOD:
ELEV (MSL):T.D. (MSL):
COMMENTS:
Incident #:BORING#
WELL#
FACILITY NAME:
LOCATION MAP:
COMPLETION
DIAGRAM
BOREHOLE DIAMETER:WATERLEVELPENETRATIONRATEMSL DEPTH /
TIME
GRAPHIC
LITHOLOGY OVD
SAMPLES&CORES
TYPEREC.ANALDESCRIPTION(Color, Texture, Structure, etc.)
Standard Boring Log
0 1 2 3 4 5 6 7 8
20
10
0
30
40
50 50
20
10
0
30
40
Former Agrotec Incorporated, 7840 NC Highway 35, Pendleton, Northampton County, NC
16143
Laura Robertson Terraine
James Hess, Geologic Exploration, Inc.
Geoprobe 6620 DPT
PG 5
OF 5
3 feet3/30/10
3/30/10 @ 12:30
3/30/10 @ 12:50
SB-7T
TOPSOIL
3.5 ppm
8260BVPH
EPH
LIGHT BROWN TO RED, COARSE-GRAINED WELL-SORTED CLAYEYSAND,MOIST
BORING TERMINATED AT 5 FEET BSG
Groundwater sample SB-7T was collected from soil boring SB-7T. Soil boring SB-7Twas not converted to a monitoring well.
555555 Feet
START DATE & TIME:
COMP. DATE & TIME:
LOGGED BY:
DRILLER:
DRILLING METHOD:
ELEV (MSL):T.D. (MSL):
COMMENTS:
Incident #:BORING#
WELL#
FACILITY NAME:
LOCATION MAP:
COMPLETION
DIAGRAM
BOREHOLE DIAMETER:WATERLEVELPENETRATIONRATEMSL DEPTH /
TIME
GRAPHIC
LITHOLOGY OVD
SAMPLES&CORES
TYPEREC.ANALDESCRIPTION(Color, Texture, Structure, etc.)
Standard Boring Log
0 1 2 3 4 5 6 7 8
20
10
0
30
40
50 50
20
10
0
30
40
Former Agrotec Incorporated, 7840 NC Highway 35, Pendleton, Northampton County, NC
16143
Laura Robertson Terraine
James Hess, Geologic Exploration, Inc.
Geoprobe 6620 DPT
PG 5
OF 5
NON RESIDENTIAL WELL CONSTRUCTION RECORD
North Carolina Department of Environment and Natural Resources-Division of Water Quality
WELL CONTRACTOR CERTIFICATION # _35_5_o ________ _
1. WELL CONTRACTOR:
JAMES HESS
Well Contractor (Individual) Name
GEOLOGIC EXPLORATION, INC.
Well Contractor Company Name
STREET ADDRESS 176 COMMERCE BLVD
STATESVILLE NC
City or Town State
~)_ 872-7686
Area code-Phone number
2. WELL INFORMATION:
28625
Zip Code
SITE WELL 10 #(if applicable),_M_W_-_3 __________ _
STATE WELL PERMIT#(if applicable), __________ _
DWQ or OTHER PERMIT #(if applicable), ________ _
WELL USE (Check Applicable Box) Monitoring KI Municipal/Public 0
Industrial/CommercialD Agricultural 0 Recovery 0 Injection 0
IrrigationD Other 0 (list use) ___________ _
DATE DRILLED_O_3_/3_0_/1_0 ____ _
TIME COMPLETED, _______ AM 0 PM 0
3. WELL LOCATION:
CITY: PENDLETON COUNTY NORTHAMPTON
7840 HIGHWAY 35 27862
(Street Name, Numbers, Community, Subdivision, Lot No" Parcel, Zip Code)
TOPOGRAPHIC I LAND SETTING:
DSlope DValley DFlat DRidge DOther, ______ _
(check appropriate box)
LATITUDE
LONGITUDE
May be in degrees,
minutes, seconds or
in a decimal format
Latitude/longitude source: 0 GPS 0 Topographic map
(location of weI! must be shown on a USGS tapa map and
attached to this form if not using GPS)
4. FACILlTY-is the name of the business where the well is located.
FACILITY ID #(if applicable) __________ _
NAME OF FACILlTY_A_G_R_A_T_E_C_H ________ _
STREET ADDRESS _7_84_0_H_I_G_H_W_A_Y_3_5 ______ _
PENDLETON NC 27862
City or Town State Zip Code
CONTACT PERSON NCDEHNR ---------------
MAILING ADDRESS 601 OBERLIN ROAD
RALEIGH NC 27605
City or Town State Zip Code
'---~)---:---------Area code -Phone number
5. WELL DETAILS:
a. TOTAL DEPTH: 11.0 FEET
b. DOES WELL REPLACE EXISTING WELL? YES 0 NO KI
c. WATER LEVEL Below Top of Casing: 0.6 FT.
(Use "+" if Above Top of Casing)
d. TOP OF CASING IS 0.0 FT. Above Land Surface*
*Top of casing terminated atlor below land surface may require
a variance in accordance with 15A NCAC 2C .0118.
e. YIELD (gpm): _N_/A ___ METHOD OF TEST_N_I_A ___ _
f. DISINFECTION: Type._N_I_A ____ Amount _N_/A ___ _
g. WATER ZONES (depth):
From ___ To___ From ___ To __ _
From ___ To___ From ___ To __ _
From ___ To___ From ___ To __ _
6. CASING: Thicknessl
9.
Depth Diameter From~ To_1_.0 __ Ft. 2 INCH
From ___ To ___ Ft.. __ _
From ___ To ___ Ft.. __ _
7. GROUT: Depth Material
~~W~b Material PVC
0.0 From ___ 0.3 To ___ Ft. Portland benlonite
Method
SLURRY
From ___ To ___ Ft.
From ___ To ___ Ft.
8. SCREEN: Depth Diameter Slot Size Material
From_1_.O __ To~ Ft.~in . . 010 in. PVC
From ___ To ___ Ft. ---in. in.
From ---To ___ Ft. ---in. in.
SAND/GRAVEL PACK:
Depth Size Material
From 0.6 To~ Ft. 20-40 FINE SILICA SAND
From To ___ Ft.
From To ___ Ft.
10. DRILLING LOG
From To
0.0 11.0
11. REMARKS:
Formation Description
TAN CLAYEY SAND
BENTONITE SEAL FROM 0.3 TO 0.6 FT
• THAT THIS WELL WAS CONSTRUCTED Il)Ii~CCOROANCE WITH
. CONSTRUi1fCJ~TA~DS, AND THAT. ,toPY OF THIS V D HE WE WNER.
• (fo 04115/10
DATE
PRINTED NAME OF PERSON CONSTRUCTING THE WELL
Submit the original to the Division of Water Quality within 30 days. Attn: Information Mgt.,
1617 Mail Service Center -Raleigh, NC 27699-1617 Phone No. [phone] ext 568. Form GW-1b
Rev. 7/05

Monitoring Well Installation & Groundwater Monitoring Report – 6/23/2010 Incident No. 16143 Former Agrotec Incorporated Pendleton, Northampton County, North Carolina
Appendix E
Low Flow Sampling Measurements
!II~~7
,·1 , Pace Analytical"
www.pacelabs.com
CHAIN-OF-CUSTODY I Analytical Request Document
The Chain-of-Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
Section A Section B Section C Page: \ of
Required Client Information: Required Project Information: I nvoice Information:
Attention: 1353982 company--r-«i~ I\(\~ • IReportT0flU(:ia..~~
Addresn~S.,e~ ~-. ICOPYTOJ~IU.\i\I p(j(J..t.itLtd ICompanyName: IREGULATORYAGENCY
GROUND WATER DRINKING WATER
Purchase Order No.: '\ U \ "'2... RCRA OTHER _ .. V Reference:
1~.lfLli.lJlt;~lFax: --... -.~ ····fOTeCtName: ~[; [nlliVP,,,c,A-<4
Requested Due DatelT AT:
Section D
Required Client Information
SAMPLE ID
(A-Z, 0-9/ ,-)
Sample IDs MUST BE UNIQUE
Project Number: J ~, 1\1 t~ LOl-O'{)Z --z...
Matrix Codes
MATRIX I CODE
Drinking Water OW
Water WT
Waste Water WW
Product P
Soil/Solid SL
Oil OL
Wipe WP
Air AR
Tissue TS
Other aT
~ ~ COLLECTED .s 0
W 0 ~ (j
:E: m ~ ~
COMPOSITE
START
COMPOSITE
END/GRAB
m rr -~ r------.-------r------r-----~
w Cl w o 0..
U ~ X w
a:: ~
Pace projeGt'j[ /1.11 ,D r" f) .1\/ ... r
Manager: LN V'-\ ~.;t{.II \.A.-'V
Pace Profile # 2.tIr C / (/ ?-.
Site Location
STATE: tie;
\,.. Requested Analysis Filtered (YIN)
2 0 >= 0 W ...J ...J 81~
I-W « 2 0.. -::;: ~ w Z I-0 ~ U
"0
0.. Uo ::;:
-z
Preservatives 1 >=
..
~ ~
~ ::;; w !::
f-::;: « « :;; en DATE TIME DATE
0
TIME .C1j ~ 11~1~lul~lilil~ ::JIIIZZ:2;O
,j
v,/
'-"--.~--.---' .. -~
"I ....,
10
11
12
ADDITIONAL COMMENTS RELINQUISHED BY I AFFILIATION DATE TIME ACCEPTED BY I AFFILIATION DATE TIME
12J~71i,1'J\'~c..-1311 1/10 t· 'tol::;;:?,,~.d)-'3-i3J-1t> I !'Io
z
IAlRMl4l2 ro :::J "0 '00 ~ I Pace Project No.1 Lab to,
~ ~
,Uf6 oca
(ll!
C')(}1
\i'I~
SAMPLE CONDITIONS
I" ~~;'C<tL-d.L lJ-3J-10 U:: J I:; r \LJ""-. -(----'I C ~ I ~)/I'4 If '. ui (,!> L . ~ Irr<--
7 I \
ORiGINAL SAMPLER NAME AND SIGNATURE
PRINT Name of SAMPLER: t '" •• ~6~~
SIGNATURE of SAMPLER: J<~ ""K~-:C:::: I ~~~~D~~~ ~ ~!30 120 JO.
"Important Note: By signing this form you are accepting Pace's NET 30 day payment terms and agreeing to late charges of 1.5% per month for any invoices not paid within 30 days.
p
.~ c. E ~
-v
" 0_ "z ~>= .~ i
0::
~ ,..0 ,,0_
002 ~~~ Om Q) en
1
F-ALL-Q-020rev.07, 15-May-2007
t) 2 " "ii lie
E '" en
?'ZArIa/yucar
, www.pacalabs.com
CHAIN-Of-CUSTODY I Analytical Request Document
The Chain-of-Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
Section A Section B Section C Page: { of /
Required Client Information: Required Project Information: Invoice Infonnation:
Attention: 1353985 Company: 7 ( IReport To: r I • rAJ I • i !r"'~JV\.(' ~ ,~
Address: l (}" 5 ICOPY To' \_ I -,,-IC N' l b r;>ur"" fel':)~ $'" . ~ ~E'rM-I V ompany ame. IREGULATORY AGENCY
cl ~Oo¥\. e> re~ "e .. .., r NPDES r GROUND WATER ,-DRINKING WATER
Purchase Order No.: Pace Quote ~UST r' RCRA r OTHER Reference: " jp--,
Pho~l9_ "f..'f.l-S/'3'+ Fax: rlJ tee I-.. {I {(,t I.f Site Location AlG Requested Due DateITAT: I ~-: f{C&1-f> J ,0Ql..
Section D Matrix Codes
Required Client Information M8TRIX / CQDE
Drinking Water OW
Water WT
WasteWater WW
Product P
SoiVSolid SL
Oil OL
Wipe WP
Air AR
SAMPLE 10
(A-Z,O-9/,-)
Sample IDs MUST BE UNIQUE Tissue TS I Other OT ...,
::!l w
:1 MLv-""2...
tT). IN-~
3
~
!
6
7
8
i a:-::;: .9 0 I u " U
"C <Xl ~ ~ " Cl ! " Cl -w 0 w
0 0-
U ~
X w a: ...J 0-~ ::;: « ::!: C/l
COLLECTED
COMPOSITE
START
COMPOSITE
END/GRAB
~ ~ W ...J
r------r------r-----.------il 8 ~
DATE I TIME DATE I TIME
f.f161{f) II;"!I~
L.e16ll0 II "'00
0-::;: ~
W ...J 0-::;:
(Jl
PreseNatives
1Q w z ~ al z C:
8 ~Iol '" ~ aCl) OI_ l:: NZU '110 :::JJ:J:J: m
t/
J:1q:1~1 ~ ~~~£ zz:::EO
I
-~ )::
I ....
STATE:
RequijSted Analysis Filtered (YIN)
I)<IXLXLXI)(
XlX1)qXIX
z ~
CD I:: .~
:EO U
ii'i :::J :!2 ~
1~~1
Pace Project No.1 Lab '-D.
(y)(
f')d)J-...
9 , I I I I I I I I I I I Ii J I I I I I I I I I I I I I
10
11
12 lJ"
ADDITIONAL COMMENTS RELINQUISHED BY / AFFILIATION DATE TIME ACCJlrijSY I AFjI1ArlON D~TE TIME SAMPLE CONDITIONS
FT.:_IA c~L /.flollZ0 r 9:t ( I J7lI\U:AA7.lI/lLc-.. ~r7nk~ I Q IJ v7,/J~IJPor~·otm~c~t1l4~\~s IUtl1 'l In\( PI~ 7 lIft.e-,--c:: \() \? .......
SAMPLER NAME ANb SIGNATURE ORIGINAL
PRINT Name of SAMPLER: rros~t> h c,.. k:b II / ~,,(II"
I L ~I ( VI DATE Signed SIGNATURE of SAMPLER: ~ C-~. (MMlDDNY): 04-If) -:} / (0
Important Note: By signing this form you are accepting Pace's NET 30 day payment terms and agreeing to late charges of 1.5% per month for any lVOices not paid within 30 daysl/
P
.5 c. E {!!.
" o~ ~~ >-.~ ~
a:
~ ~8~ oUZ cn-ci: c3~~
" C/l
F-ALL-Q-020rev.07. 15-Mav-2007
u ~ i~
E
&'l
Client Name:'T--rr~<~ ------~----------------Project # ______ __
Courier: 0 Fed Ex 0 UPS 0 USPS o Client 0 Commercial~ce Other _____ _
Custody Seal on Cooler/Box Present: o yes fl--~~' Seals intact 0 yes rEJ-~Z···
Thermometer Used T060
pubble Bags 0 None DOther ____ _
Type Oflce~;;> Blce Noee P:"'~PI" '" 'ce cooliogpmtt" h" beg",
Packing Material: 0 Bubble Wrap
1 10 -
Cooler Temperature Biological Ti sue is Frozen: Yes No N/A Date and InliaJs ':.~per o~ercni/g
contents: I'VYTrn-I I ~
Temp should be above freezing to 6°C Comments: I
Chain of Custody Present: ~No DN/A 1.
Chain of Custody Filled Out ~ONo DN/A 2.
Chain of Custody Relinquished ~ONO DN/A 3.
Sampler Name & Signature on COC: ~"DNO DN/A 4. ..
Samples Arrived within Hold Time: ~·DNo DN/A ':' ..
5. -.
Short Hold Time Analysis «72hr): . ~·'DNo DN/A 6. ;:
Rush Turn Around Time Requested: DYes )drrO' DN/A 7.
Sufficient Volume: DYes~LJN/A I\~ ') 't..""'1IJ c---, N~)t-.~ \1\."" { 8. t..f\
. Correct Containers Used: .,...-ErYes DNo DN/A 9 . t,,~ VPI{ \s'lr .p>r, ~(s,.. 3 'T
-Pace Containers Used: ...-B1e~ DNo DN/A
Containers Intact ---erYe~ DNo DNfA 10.
Filtered volume received for Dissolved tests DYes DNo~ ,.
11.
Sample Labels match COC: DYe~o DN/A 12. S& G, r )01 \)-ct.::l ~6+ "-'-t.-<--
-Includes date!time/ID!Analysis Matrix: hJ..ll-Or\. ~.
All containers needing preservation have been checked. ? DNo DNfA 13. ~& 1-1 J~ ,..·~f nc...",,-es )-~; \ \'
All containers needing preservation are found to be in ~ .. -. DNo DN/A cJJ-r ¥'"'-0 f\. ~ 4(tul 3 U1 ..:>
compliance with EPA recommendation. .' Yes --(G,W~ DYes DNo ~1' -N:>·f exceptions: VOA, coliform, TOe, O&G. WI·DRO (water) Initial when comp e ed :
~ONO C ~---'-..... Samples checked for dechlorination: DN/A 14.
Headspace in VOA Vials ( >6mm): ~~s DNo DNfA 15. I \,1\"", ( .-~7~ -~-;;-f )
,E1NiA • (i')-s-y Trip Blank Present: DYes DNo 16. l ~c. ( -
Trip Blank Custody Seals Present DYes DNo ~'
Pace Trip Blank Lot # (if purchased): N/A
/
Client Notification! Resolution: y / N / N!A
Person Contacted: Daterrime:
Field 7'Q"'''d1
Comments! Resolution: IV
"' Wt:.tLv-hc-frk-
Project Manager Review: Date: -----------------
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR
Certification Office (i.e out of hold, incorrect preservative, out of temp, incorrect containers)
~ ~' }
/ ~ .' / __ /f'ace Analytical
f ~
Client Name: Tasnioe
Courier: 0 Fed Ex 0 UPS 0 USPS 0 Client 0 Commercial ~ Other, __ _
Custody Seal on Cooler!Box Present: 0 yes ~o Seals intact 0 yes ~
Packing Material: 0 Bubble Wrap ~ble Bags 0 None DOther ___ _
Thermometer Used T060 Type of Ice: G;!) Blue None ffsamples on ice, cooling process has begun
Cooler Temperature' L\.\ Biological Tissue is Frozen: Yes No N/A Date and Initials of Qerson examining
contents:3("t\fl\ L\. .. '"1-\0
Temp should be above freezing to 6°C Comments:
Chain of Custody Present ~DNo DN/A 1,
Chain of Custody Filled Out:. ~ DNo DN/A 2. " " -
Chain of Custody Relinquished: gCs DNa DN/A 3.
Sampler Name & Signature on COC: ~ DNa oN/A 4. .
Samples Arrived within Hold Tirne: ~ DNo DN/A 5.
":"J.
'.
Short Hold Time Analysis «72hr): ~ DNa oN/A
,
6, ;~
Rush Turn Around Time Requested: DYes ~ oN/A 7.
Sufficient Volume: ,~ DNo oN/A 8, ,-
Correct Containers Used: ~ DNQ DN/A 9. , .. ,"
·Pace Containers Used: ~ DNo, oNtA
Containers Intact: ~' DNa oNtA 10.
Filtered volume received for Dissolved tests DYes DNo ~ 11.
.,
~ DNo oN/A -Sample Labels match COC: 12.
-Includes date/time/lD/Analysis Matrix:
All containers needing preservation have been checked. , ~DNo DN/A 13.
All containers needing preservation are found to be in ~'NO DN/A
,.
compliance with EPA recommendation, -;.
!-
exceptions: VOA, coliform. TOC, O&G, WI·ORO (water) DYes oNo Initial when completed
Samples checked for dechlorination: '~oNO oN/A 14.
Headspace in VOA Vials ( >6mm): DYes ~DN/A 15.
Trip Blank Present: DYes oNo f1N7A 16.
Trip Blank Custody Seals Present DYes oNo ~
Pace Trip Blank Lot # (if purchased): N!A
Client Notification! Resolution: Field Data Required? YIN t N/A
Person Contacted: ______________ Datemme: ________ _
Commentsl Resolution: ----------------------------------------------
Project Manager Review: oate:/fi<:( f1v
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR
Certification Office (i.e out of hold, incorrect preservative, out of temp, incorrect containers)

Monitoring Well Installation & Groundwater Monitoring Report – 6/23/2010 Incident No. 16143 Former Agrotec Incorporated Pendleton, Northampton County, North Carolina
Appendix F
Chain of Custody Records Cooler Receipt Forms
Laboratory Certificates of Analysis Quality Control Certificates

April 09, 2010
LIMS USE: FR - LINDA BLALOCK
LIMS OBJECT ID: 9266446
9266446
Project:
Pace Project No.:
RE:
Ms. Linda BlalockNCDENR - UST Section1637 Mail Service CenterRaleigh, NC 276991637
16143 AGROTEC INCORPORATED
Dear Ms. Blalock:
Enclosed are the analytical results for sample(s) received by the laboratory on March 31, 2010. The
results relate only to the samples included in this report. Results reported herein conform to themost current NELAC standards, where applicable, unless otherwise narrated in the body of the
report.
Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and
Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All
Microbiological analyses were performed at the laboratory where the samples were received.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Renee Spencer
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
CERTIFICATIONS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Charlotte Certification IDs9800 Kincey Ave. - Ste 100 Huntersville, NC 28078West Virginia Certification #: 357Connecticut Certification #: PH-0104Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84Louisiana/LELAP Certification #: 04034New Jersey Certification #: NC012North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12Pennsylvania Certification #: 68-00784South Carolina Certification #: 990060001South Carolina Drinking Water Cert. #: 990060003Tennessee Certification #: 04010Virginia Certification #: 00213
Asheville Certification IDs2225 Riverside Dr. Asheville, NC 28804Connecticut Certification #: PH-0106Louisiana/LELAP Certification #: 03095Massachusetts Certification #: M-NC030New Jersey Certification #: NC011North Carolina Bioassay Certification #: 9North Carolina Drinking Water Certification #: 37712North Carolina Wastewater Certification #: 40
Pennsylvania Certification #: 68-03578South Carolina Bioassay Certification #: 99030002South Carolina Certification #: 99030001Tennessee Certification #: 2980Virginia Certification #: 00072West Virginia Certification #: 356Florida/NELAP Certification #: E87648
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE SUMMARY
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Lab ID Sample ID Matrix Date Collected Date Received
9266446001 SB-4T 2FT Solid 03/30/10 10:45 03/31/10 15:15
9266446002 SB-5T 1.5FT Solid 03/30/10 11:15 03/31/10 15:15
9266446003 SB-6T 2FT Solid 03/30/10 11:45 03/31/10 15:15
9266446004 SB-7T 2FT Solid 03/30/10 12:30 03/31/10 15:15
9266446005 SB-3T 2FT Solid 03/30/10 13:00 03/31/10 15:15
9266446006 SB-4T Water 03/30/10 10:45 03/31/10 15:15
9266446007 SB-5T Water 03/30/10 11:15 03/31/10 15:15
9266446008 SB-6T Water 03/30/10 11:45 03/31/10 15:15
9266446009 SB-7T Water 03/30/10 12:30 03/31/10 15:15
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
9266446001 SB-4T 2FT MADEP EPH 7 PASI-CRES
MADEP VPH 5 PASI-CDHW
EPA 8270 73 PASI-CBPJ
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CTNM
9266446002 SB-5T 1.5FT MADEP EPH 7 PASI-CRES
MADEP VPH 5 PASI-CDHW
EPA 8270 73 PASI-CBPJ
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CTNM
9266446003 SB-6T 2FT MADEP EPH 7 PASI-CRES
MADEP VPH 5 PASI-CDHW
EPA 8270 73 PASI-CBPJ
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CTNM
9266446004 SB-7T 2FT MADEP EPH 7 PASI-CRES
MADEP VPH 5 PASI-CDHW
EPA 8270 73 PASI-CBPJ
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CTNM
9266446005 SB-3T 2FT MADEP EPH 7 PASI-CRES
MADEP VPH 5 PASI-CDHW
EPA 8270 73 PASI-CBPJ
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CTNM
9266446006 SB-4T MADEP EPH 7 PASI-CRES
MADEP VPH 5 PASI-CDHW
EPA 200.7 1 PASI-AJMW
EPA 625 59 PASI-CPPM
SM 6200B 64 PASI-CAW
9266446007 SB-5T MADEP EPH 7 PASI-CRES
MADEP VPH 5 PASI-CDHW
EPA 200.7 1 PASI-AJMW
EPA 625 59 PASI-CPPM
SM 6200B 64 PASI-CAW
9266446008 SB-6T MADEP EPH 7 PASI-CRES
MADEP VPH 5 PASI-CDHW
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 4 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
EPA 200.7 1 PASI-AJMW
EPA 625 59 PASI-CPPM
SM 6200B 64 PASI-CAW
9266446009 SB-7T MADEP EPH 7 PASI-CRES
MADEP VPH 5 PASI-CDHW
EPA 200.7 1 PASI-AJMW
EPA 625 59 PASI-CPPM
SM 6200B 64 PASI-CAW
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 5 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-4T 2FT Lab ID:9266446001 Collected:03/30/10 10:45 Received:03/31/10 15:15 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
MADEP EPH NC Soil Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)ND mg/kg 1 04/06/10 00:0304/02/10 11:3012.0 12.0
Aliphatic (C19-C36)ND mg/kg 1 04/06/10 00:0304/02/10 11:3012.0 12.0
Aromatic (C11-C22)ND mg/kg 1 04/06/10 00:0304/02/10 11:3012.0 12.0
Nonatriacontane (S)78 %1 04/06/10 00:03 7194-86-704/02/10 11:3040-140
o-Terphenyl (S)48 %1 04/06/10 00:03 84-15-104/02/10 11:3040-140
2-Fluorobiphenyl (S)64 %1 04/06/10 00:03 321-60-804/02/10 11:3040-140
2-Bromonaphthalene (S)63 %1 04/06/10 00:03 580-13-204/02/10 11:3040-140
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)ND mg/kg 1 04/06/10 17:2704/06/10 15:4012.5 12.5
Aliphatic (C09-C12)52.1 mg/kg 1 04/06/10 17:2704/06/10 15:4012.5 12.5
Aromatic (C09-C10)13.6 mg/kg 1 04/06/10 17:2704/06/10 15:4012.5 12.5
2,5-Dibromotoluene (PID)(S)127 %1 04/06/10 17:2704/06/10 15:4070-130
2,5-Dibromotoluene (FID)(S)190 %1 04/06/10 17:27 S504/06/10 15:4070-130
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene ND mg/kg 1 04/07/10 19:41 83-32-904/01/10 13:000.40 0.091
Acenaphthylene ND mg/kg 1 04/07/10 19:41 208-96-804/01/10 13:000.40 0.094
Anthracene ND mg/kg 1 04/07/10 19:41 120-12-704/01/10 13:000.40 0.089
Benzo(a)anthracene ND mg/kg 1 04/07/10 19:41 56-55-304/01/10 13:000.40 0.073
Benzo(a)pyrene ND mg/kg 1 04/07/10 19:41 50-32-804/01/10 13:000.40 0.076
Benzo(b)fluoranthene ND mg/kg 1 04/07/10 19:41 205-99-204/01/10 13:000.40 0.068
Benzo(g,h,i)perylene ND mg/kg 1 04/07/10 19:41 191-24-204/01/10 13:000.40 0.10
Benzo(k)fluoranthene ND mg/kg 1 04/07/10 19:41 207-08-904/01/10 13:000.40 0.078
Benzoic Acid ND mg/kg 1 04/07/10 19:41 65-85-004/01/10 13:002.0 0.072
Benzyl alcohol ND mg/kg 1 04/07/10 19:41 100-51-604/01/10 13:000.79 0.079
4-Bromophenylphenyl ether ND mg/kg 1 04/07/10 19:41 101-55-304/01/10 13:000.40 0.072
Butylbenzylphthalate ND mg/kg 1 04/07/10 19:41 85-68-704/01/10 13:000.40 0.084
4-Chloro-3-methylphenol ND mg/kg 1 04/07/10 19:41 59-50-704/01/10 13:000.79 0.082
4-Chloroaniline ND mg/kg 1 04/07/10 19:41 106-47-804/01/10 13:002.0 0.11
bis(2-Chloroethoxy)methane ND mg/kg 1 04/07/10 19:41 111-91-104/01/10 13:000.40 0.092
bis(2-Chloroethyl) ether ND mg/kg 1 04/07/10 19:41 111-44-404/01/10 13:000.40 0.10
bis(2-Chloroisopropyl) ether ND mg/kg 1 04/07/10 19:41 108-60-104/01/10 13:000.40 0.11
2-Chloronaphthalene ND mg/kg 1 04/07/10 19:41 91-58-704/01/10 13:000.40 0.078
2-Chlorophenol ND mg/kg 1 04/07/10 19:41 95-57-804/01/10 13:000.40 0.11
4-Chlorophenylphenyl ether ND mg/kg 1 04/07/10 19:41 7005-72-304/01/10 13:000.40 0.082
Chrysene ND mg/kg 1 04/07/10 19:41 218-01-904/01/10 13:000.40 0.053
Dibenz(a,h)anthracene ND mg/kg 1 04/07/10 19:41 53-70-304/01/10 13:000.40 0.084
Dibenzofuran ND mg/kg 1 04/07/10 19:41 132-64-904/01/10 13:000.40 0.065
1,2-Dichlorobenzene ND mg/kg 1 04/07/10 19:41 95-50-104/01/10 13:000.40 0.11
1,3-Dichlorobenzene ND mg/kg 1 04/07/10 19:41 541-73-104/01/10 13:000.40 0.090
1,4-Dichlorobenzene ND mg/kg 1 04/07/10 19:41 106-46-704/01/10 13:000.40 0.11
3,3'-Dichlorobenzidine ND mg/kg 1 04/07/10 19:41 91-94-104/01/10 13:002.0 0.086
2,4-Dichlorophenol ND mg/kg 1 04/07/10 19:41 120-83-204/01/10 13:000.40 0.086
Diethylphthalate ND mg/kg 1 04/07/10 19:41 84-66-204/01/10 13:000.40 0.061
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 6 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-4T 2FT Lab ID:9266446001 Collected:03/30/10 10:45 Received:03/31/10 15:15 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
2,4-Dimethylphenol ND mg/kg 1 04/07/10 19:41 105-67-904/01/10 13:000.40 0.16
Dimethylphthalate ND mg/kg 1 04/07/10 19:41 131-11-304/01/10 13:000.40 0.080
Di-n-butylphthalate ND mg/kg 1 04/07/10 19:41 84-74-204/01/10 13:000.40 0.065
4,6-Dinitro-2-methylphenol ND mg/kg 1 04/07/10 19:41 534-52-104/01/10 13:000.79 0.079
2,4-Dinitrophenol ND mg/kg 1 04/07/10 19:41 51-28-504/01/10 13:002.0 0.065
2,4-Dinitrotoluene ND mg/kg 1 04/07/10 19:41 121-14-204/01/10 13:000.40 0.074
2,6-Dinitrotoluene ND mg/kg 1 04/07/10 19:41 606-20-204/01/10 13:000.40 0.083
Di-n-octylphthalate ND mg/kg 1 04/07/10 19:41 117-84-004/01/10 13:000.40 0.083
bis(2-Ethylhexyl)phthalate ND mg/kg 1 04/07/10 19:41 117-81-704/01/10 13:000.40 0.11
Fluoranthene ND mg/kg 1 04/07/10 19:41 206-44-004/01/10 13:000.40 0.058
Fluorene ND mg/kg 1 04/07/10 19:41 86-73-704/01/10 13:000.40 0.082
Hexachloro-1,3-butadiene ND mg/kg 1 04/07/10 19:41 87-68-304/01/10 13:000.40 0.068
Hexachlorobenzene ND mg/kg 1 04/07/10 19:41 118-74-104/01/10 13:000.40 0.050
Hexachlorocyclopentadiene ND mg/kg 1 04/07/10 19:41 77-47-404/01/10 13:000.40 0.073
Hexachloroethane ND mg/kg 1 04/07/10 19:41 67-72-104/01/10 13:000.40 0.10
Indeno(1,2,3-cd)pyrene ND mg/kg 1 04/07/10 19:41 193-39-504/01/10 13:000.40 0.082
Isophorone ND mg/kg 1 04/07/10 19:41 78-59-104/01/10 13:000.40 0.089
1-Methylnaphthalene ND mg/kg 1 04/07/10 19:41 90-12-004/01/10 13:000.40 0.10
2-Methylnaphthalene ND mg/kg 1 04/07/10 19:41 91-57-604/01/10 13:000.40 0.085
2-Methylphenol(o-Cresol)ND mg/kg 1 04/07/10 19:41 95-48-704/01/10 13:000.40 0.12
3&4-Methylphenol(m&p Cresol)ND mg/kg 1 04/07/10 19:4104/01/10 13:000.40 0.16
Naphthalene ND mg/kg 1 04/07/10 19:41 91-20-304/01/10 13:000.40 0.097
2-Nitroaniline ND mg/kg 1 04/07/10 19:41 88-74-404/01/10 13:002.0 0.12
3-Nitroaniline ND mg/kg 1 04/07/10 19:41 99-09-204/01/10 13:002.0 0.11
4-Nitroaniline ND mg/kg 1 04/07/10 19:41 100-01-604/01/10 13:000.79 0.11
Nitrobenzene ND mg/kg 1 04/07/10 19:41 98-95-304/01/10 13:000.40 0.11
2-Nitrophenol ND mg/kg 1 04/07/10 19:41 88-75-504/01/10 13:000.40 0.096
4-Nitrophenol ND mg/kg 1 04/07/10 19:41 100-02-704/01/10 13:002.0 0.071
N-Nitrosodimethylamine ND mg/kg 1 04/07/10 19:41 62-75-904/01/10 13:000.40 0.13
N-Nitroso-di-n-propylamine ND mg/kg 1 04/07/10 19:41 621-64-704/01/10 13:000.40 0.076
N-Nitrosodiphenylamine ND mg/kg 1 04/07/10 19:41 86-30-604/01/10 13:000.40 0.12
Pentachlorophenol ND mg/kg 1 04/07/10 19:41 87-86-504/01/10 13:002.0 0.072
Phenanthrene ND mg/kg 1 04/07/10 19:41 85-01-804/01/10 13:000.40 0.066
Phenol ND mg/kg 1 04/07/10 19:41 108-95-204/01/10 13:000.40 0.12
Pyrene ND mg/kg 1 04/07/10 19:41 129-00-004/01/10 13:000.40 0.067
1,2,4-Trichlorobenzene ND mg/kg 1 04/07/10 19:41 120-82-104/01/10 13:000.40 0.077
2,4,5-Trichlorophenol ND mg/kg 1 04/07/10 19:41 95-95-404/01/10 13:000.40 0.12
2,4,6-Trichlorophenol ND mg/kg 1 04/07/10 19:41 88-06-204/01/10 13:000.40 0.088
Nitrobenzene-d5 (S)68 %1 04/07/10 19:41 4165-60-004/01/10 13:0030-120
2-Fluorobiphenyl (S)61 %1 04/07/10 19:41 321-60-804/01/10 13:0030-120
Terphenyl-d14 (S)67 %1 04/07/10 19:41 1718-51-004/01/10 13:0035-108
Phenol-d6 (S)61 %1 04/07/10 19:41 13127-88-304/01/10 13:0035-120
2-Fluorophenol (S)61 %1 04/07/10 19:41 367-12-404/01/10 13:0024-120
2,4,6-Tribromophenol (S)56 %1 04/07/10 19:41 118-79-604/01/10 13:0040-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 7 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-4T 2FT Lab ID:9266446001 Collected:03/30/10 10:45 Received:03/31/10 15:15 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone ND mg/kg 1 04/01/10 14:16 67-64-10.080 0.0080
Benzene ND mg/kg 1 04/01/10 14:16 71-43-20.0040 0.0013
Bromobenzene ND mg/kg 1 04/01/10 14:16 108-86-10.0040 0.0016
Bromochloromethane ND mg/kg 1 04/01/10 14:16 74-97-50.0040 0.0014
Bromodichloromethane ND mg/kg 1 04/01/10 14:16 75-27-40.0040 0.0015
Bromoform ND mg/kg 1 04/01/10 14:16 75-25-20.0040 0.0018
Bromomethane ND mg/kg 1 04/01/10 14:16 74-83-90.0080 0.0020
2-Butanone (MEK)ND mg/kg 1 04/01/10 14:16 78-93-30.080 0.0023
n-Butylbenzene ND mg/kg 1 04/01/10 14:16 104-51-80.0040 0.0014
sec-Butylbenzene ND mg/kg 1 04/01/10 14:16 135-98-80.0040 0.0013
tert-Butylbenzene ND mg/kg 1 04/01/10 14:16 98-06-60.0040 0.0016
Carbon tetrachloride ND mg/kg 1 04/01/10 14:16 56-23-50.0040 0.0021
Chlorobenzene ND mg/kg 1 04/01/10 14:16 108-90-70.0040 0.0015
Chloroethane ND mg/kg 1 04/01/10 14:16 75-00-30.0080 0.0019
Chloroform ND mg/kg 1 04/01/10 14:16 67-66-30.0040 0.0013
Chloromethane ND mg/kg 1 04/01/10 14:16 74-87-30.0080 0.0019
2-Chlorotoluene ND mg/kg 1 04/01/10 14:16 95-49-80.0040 0.0014
4-Chlorotoluene ND mg/kg 1 04/01/10 14:16 106-43-40.0040 0.0014
1,2-Dibromo-3-chloropropane ND mg/kg 1 04/01/10 14:16 96-12-80.0040 0.0029
Dibromochloromethane ND mg/kg 1 04/01/10 14:16 124-48-10.0040 0.0014
1,2-Dibromoethane (EDB)ND mg/kg 1 04/01/10 14:16 106-93-40.0040 0.0014
Dibromomethane ND mg/kg 1 04/01/10 14:16 74-95-30.0040 0.0020
1,2-Dichlorobenzene ND mg/kg 1 04/01/10 14:16 95-50-10.0040 0.0015
1,3-Dichlorobenzene ND mg/kg 1 04/01/10 14:16 541-73-10.0040 0.0016
1,4-Dichlorobenzene ND mg/kg 1 04/01/10 14:16 106-46-70.0040 0.0014
Dichlorodifluoromethane ND mg/kg 1 04/01/10 14:16 75-71-80.0080 0.0029
1,1-Dichloroethane ND mg/kg 1 04/01/10 14:16 75-34-30.0040 0.0012
1,2-Dichloroethane ND mg/kg 1 04/01/10 14:16 107-06-20.0040 0.0018
1,1-Dichloroethene ND mg/kg 1 04/01/10 14:16 75-35-40.0040 0.0014
cis-1,2-Dichloroethene ND mg/kg 1 04/01/10 14:16 156-59-20.0040 0.0011
trans-1,2-Dichloroethene ND mg/kg 1 04/01/10 14:16 156-60-50.0040 0.0015
1,2-Dichloropropane ND mg/kg 1 04/01/10 14:16 78-87-50.0040 0.0014
1,3-Dichloropropane ND mg/kg 1 04/01/10 14:16 142-28-90.0040 0.0015
2,2-Dichloropropane ND mg/kg 1 04/01/10 14:16 594-20-70.0040 0.0014
1,1-Dichloropropene ND mg/kg 1 04/01/10 14:16 563-58-60.0040 0.0012
cis-1,3-Dichloropropene ND mg/kg 1 04/01/10 14:16 10061-01-50.0040 0.0014
trans-1,3-Dichloropropene ND mg/kg 1 04/01/10 14:16 10061-02-60.0040 0.0012
Diisopropyl ether ND mg/kg 1 04/01/10 14:16 108-20-30.0040 0.0014
Ethylbenzene ND mg/kg 1 04/01/10 14:16 100-41-40.0040 0.0014
Hexachloro-1,3-butadiene ND mg/kg 1 04/01/10 14:16 87-68-30.0040 0.0016
2-Hexanone ND mg/kg 1 04/01/10 14:16 591-78-60.040 0.0031
Isopropylbenzene (Cumene)ND mg/kg 1 04/01/10 14:16 98-82-80.0040 0.0015
p-Isopropyltoluene ND mg/kg 1 04/01/10 14:16 99-87-60.0040 0.0014
Methylene Chloride ND mg/kg 1 04/01/10 14:16 75-09-20.016 0.0024
4-Methyl-2-pentanone (MIBK)ND mg/kg 1 04/01/10 14:16 108-10-10.040 0.0030
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 8 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-4T 2FT Lab ID:9266446001 Collected:03/30/10 10:45 Received:03/31/10 15:15 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
8260/5035A Volatile Organics Analytical Method: EPA 8260
Methyl-tert-butyl ether ND mg/kg 1 04/01/10 14:16 1634-04-40.0040 0.0012
Naphthalene ND mg/kg 1 04/01/10 14:16 91-20-30.0040 0.00096
n-Propylbenzene ND mg/kg 1 04/01/10 14:16 103-65-10.0040 0.0014
Styrene ND mg/kg 1 04/01/10 14:16 100-42-50.0040 0.0014
1,1,1,2-Tetrachloroethane ND mg/kg 1 04/01/10 14:16 630-20-60.0040 0.0017
1,1,2,2-Tetrachloroethane ND mg/kg 1 04/01/10 14:16 79-34-50.0040 0.0015
Tetrachloroethene ND mg/kg 1 04/01/10 14:16 127-18-40.0040 0.0014
Toluene ND mg/kg 1 04/01/10 14:16 108-88-30.0040 0.0014
1,2,3-Trichlorobenzene ND mg/kg 1 04/01/10 14:16 87-61-60.0040 0.0018
1,2,4-Trichlorobenzene ND mg/kg 1 04/01/10 14:16 120-82-10.0040 0.0013
1,1,1-Trichloroethane ND mg/kg 1 04/01/10 14:16 71-55-60.0040 0.0014
1,1,2-Trichloroethane ND mg/kg 1 04/01/10 14:16 79-00-50.0040 0.0017
Trichloroethene ND mg/kg 1 04/01/10 14:16 79-01-60.0040 0.0017
Trichlorofluoromethane ND mg/kg 1 04/01/10 14:16 75-69-40.0040 0.0018
1,2,3-Trichloropropane ND mg/kg 1 04/01/10 14:16 96-18-40.0040 0.0013
1,2,4-Trimethylbenzene ND mg/kg 1 04/01/10 14:16 95-63-60.0040 0.0016
1,3,5-Trimethylbenzene ND mg/kg 1 04/01/10 14:16 108-67-80.0040 0.0014
Vinyl acetate ND mg/kg 1 04/01/10 14:16 108-05-40.040 0.0070
Vinyl chloride ND mg/kg 1 04/01/10 14:16 75-01-40.0080 0.0014
Xylene (Total)ND mg/kg 1 04/01/10 14:16 1330-20-70.0080 0.0029
m&p-Xylene ND mg/kg 1 04/01/10 14:16 1330-20-70.0080 0.0029
o-Xylene ND mg/kg 1 04/01/10 14:16 95-47-60.0040 0.0015
Dibromofluoromethane (S)107 %1 04/01/10 14:16 1868-53-779-116
Toluene-d8 (S)101 %1 04/01/10 14:16 2037-26-588-110
4-Bromofluorobenzene (S)93 %1 04/01/10 14:16 460-00-474-115
1,2-Dichloroethane-d4 (S)110 %1 04/01/10 14:16 17060-07-069-121
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 16.6 %1 04/02/10 14:260.10 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 9 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-5T 1.5FT Lab ID:9266446002 Collected:03/30/10 11:15 Received:03/31/10 15:15 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
MADEP EPH NC Soil Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)ND mg/kg 1 04/06/10 00:3904/02/10 11:3011.0 11.0
Aliphatic (C19-C36)ND mg/kg 1 04/06/10 00:3904/02/10 11:3011.0 11.0
Aromatic (C11-C22)ND mg/kg 1 04/06/10 00:3904/02/10 11:3011.0 11.0
Nonatriacontane (S)80 %1 04/06/10 00:39 7194-86-704/02/10 11:3040-140
o-Terphenyl (S)59 %1 04/06/10 00:39 84-15-104/02/10 11:3040-140
2-Fluorobiphenyl (S)81 %1 04/06/10 00:39 321-60-804/02/10 11:3040-140
2-Bromonaphthalene (S)80 %1 04/06/10 00:39 580-13-204/02/10 11:3040-140
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)ND mg/kg 1 04/06/10 17:5204/06/10 15:4010.6 10.6
Aliphatic (C09-C12)ND mg/kg 1 04/06/10 17:5204/06/10 15:4010.6 10.6
Aromatic (C09-C10)ND mg/kg 1 04/06/10 17:5204/06/10 15:4010.6 10.6
2,5-Dibromotoluene (PID)(S)104 %1 04/06/10 17:5204/06/10 15:4070-130
2,5-Dibromotoluene (FID)(S)126 %1 04/06/10 17:5204/06/10 15:4070-130
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene ND mg/kg 1 04/07/10 20:08 83-32-904/01/10 13:000.36 0.083
Acenaphthylene ND mg/kg 1 04/07/10 20:08 208-96-804/01/10 13:000.36 0.086
Anthracene ND mg/kg 1 04/07/10 20:08 120-12-704/01/10 13:000.36 0.081
Benzo(a)anthracene ND mg/kg 1 04/07/10 20:08 56-55-304/01/10 13:000.36 0.067
Benzo(a)pyrene ND mg/kg 1 04/07/10 20:08 50-32-804/01/10 13:000.36 0.069
Benzo(b)fluoranthene ND mg/kg 1 04/07/10 20:08 205-99-204/01/10 13:000.36 0.062
Benzo(g,h,i)perylene ND mg/kg 1 04/07/10 20:08 191-24-204/01/10 13:000.36 0.092
Benzo(k)fluoranthene ND mg/kg 1 04/07/10 20:08 207-08-904/01/10 13:000.36 0.071
Benzoic Acid ND mg/kg 1 04/07/10 20:08 65-85-004/01/10 13:001.8 0.066
Benzyl alcohol ND mg/kg 1 04/07/10 20:08 100-51-604/01/10 13:000.72 0.072
4-Bromophenylphenyl ether ND mg/kg 1 04/07/10 20:08 101-55-304/01/10 13:000.36 0.066
Butylbenzylphthalate ND mg/kg 1 04/07/10 20:08 85-68-704/01/10 13:000.36 0.077
4-Chloro-3-methylphenol ND mg/kg 1 04/07/10 20:08 59-50-704/01/10 13:000.72 0.075
4-Chloroaniline ND mg/kg 1 04/07/10 20:08 106-47-804/01/10 13:001.8 0.10
bis(2-Chloroethoxy)methane ND mg/kg 1 04/07/10 20:08 111-91-104/01/10 13:000.36 0.084
bis(2-Chloroethyl) ether ND mg/kg 1 04/07/10 20:08 111-44-404/01/10 13:000.36 0.092
bis(2-Chloroisopropyl) ether ND mg/kg 1 04/07/10 20:08 108-60-104/01/10 13:000.36 0.096
2-Chloronaphthalene ND mg/kg 1 04/07/10 20:08 91-58-704/01/10 13:000.36 0.071
2-Chlorophenol ND mg/kg 1 04/07/10 20:08 95-57-804/01/10 13:000.36 0.099
4-Chlorophenylphenyl ether ND mg/kg 1 04/07/10 20:08 7005-72-304/01/10 13:000.36 0.075
Chrysene ND mg/kg 1 04/07/10 20:08 218-01-904/01/10 13:000.36 0.048
Dibenz(a,h)anthracene ND mg/kg 1 04/07/10 20:08 53-70-304/01/10 13:000.36 0.077
Dibenzofuran ND mg/kg 1 04/07/10 20:08 132-64-904/01/10 13:000.36 0.059
1,2-Dichlorobenzene ND mg/kg 1 04/07/10 20:08 95-50-104/01/10 13:000.36 0.096
1,3-Dichlorobenzene ND mg/kg 1 04/07/10 20:08 541-73-104/01/10 13:000.36 0.082
1,4-Dichlorobenzene ND mg/kg 1 04/07/10 20:08 106-46-704/01/10 13:000.36 0.10
3,3'-Dichlorobenzidine ND mg/kg 1 04/07/10 20:08 91-94-104/01/10 13:001.8 0.079
2,4-Dichlorophenol ND mg/kg 1 04/07/10 20:08 120-83-204/01/10 13:000.36 0.079
Diethylphthalate ND mg/kg 1 04/07/10 20:08 84-66-204/01/10 13:000.36 0.056
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 10 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-5T 1.5FT Lab ID:9266446002 Collected:03/30/10 11:15 Received:03/31/10 15:15 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
2,4-Dimethylphenol ND mg/kg 1 04/07/10 20:08 105-67-904/01/10 13:000.36 0.14
Dimethylphthalate ND mg/kg 1 04/07/10 20:08 131-11-304/01/10 13:000.36 0.073
Di-n-butylphthalate ND mg/kg 1 04/07/10 20:08 84-74-204/01/10 13:000.36 0.059
4,6-Dinitro-2-methylphenol ND mg/kg 1 04/07/10 20:08 534-52-104/01/10 13:000.72 0.072
2,4-Dinitrophenol ND mg/kg 1 04/07/10 20:08 51-28-504/01/10 13:001.8 0.059
2,4-Dinitrotoluene ND mg/kg 1 04/07/10 20:08 121-14-204/01/10 13:000.36 0.068
2,6-Dinitrotoluene ND mg/kg 1 04/07/10 20:08 606-20-204/01/10 13:000.36 0.076
Di-n-octylphthalate ND mg/kg 1 04/07/10 20:08 117-84-004/01/10 13:000.36 0.076
bis(2-Ethylhexyl)phthalate ND mg/kg 1 04/07/10 20:08 117-81-704/01/10 13:000.36 0.099
Fluoranthene ND mg/kg 1 04/07/10 20:08 206-44-004/01/10 13:000.36 0.053
Fluorene ND mg/kg 1 04/07/10 20:08 86-73-704/01/10 13:000.36 0.075
Hexachloro-1,3-butadiene ND mg/kg 1 04/07/10 20:08 87-68-304/01/10 13:000.36 0.062
Hexachlorobenzene ND mg/kg 1 04/07/10 20:08 118-74-104/01/10 13:000.36 0.046
Hexachlorocyclopentadiene ND mg/kg 1 04/07/10 20:08 77-47-404/01/10 13:000.36 0.067
Hexachloroethane ND mg/kg 1 04/07/10 20:08 67-72-104/01/10 13:000.36 0.095
Indeno(1,2,3-cd)pyrene ND mg/kg 1 04/07/10 20:08 193-39-504/01/10 13:000.36 0.075
Isophorone ND mg/kg 1 04/07/10 20:08 78-59-104/01/10 13:000.36 0.081
1-Methylnaphthalene ND mg/kg 1 04/07/10 20:08 90-12-004/01/10 13:000.36 0.094
2-Methylnaphthalene ND mg/kg 1 04/07/10 20:08 91-57-604/01/10 13:000.36 0.078
2-Methylphenol(o-Cresol)ND mg/kg 1 04/07/10 20:08 95-48-704/01/10 13:000.36 0.11
3&4-Methylphenol(m&p Cresol)ND mg/kg 1 04/07/10 20:0804/01/10 13:000.36 0.14
Naphthalene ND mg/kg 1 04/07/10 20:08 91-20-304/01/10 13:000.36 0.089
2-Nitroaniline ND mg/kg 1 04/07/10 20:08 88-74-404/01/10 13:001.8 0.11
3-Nitroaniline ND mg/kg 1 04/07/10 20:08 99-09-204/01/10 13:001.8 0.099
4-Nitroaniline ND mg/kg 1 04/07/10 20:08 100-01-604/01/10 13:000.72 0.10
Nitrobenzene ND mg/kg 1 04/07/10 20:08 98-95-304/01/10 13:000.36 0.099
2-Nitrophenol ND mg/kg 1 04/07/10 20:08 88-75-504/01/10 13:000.36 0.088
4-Nitrophenol ND mg/kg 1 04/07/10 20:08 100-02-704/01/10 13:001.8 0.065
N-Nitrosodimethylamine ND mg/kg 1 04/07/10 20:08 62-75-904/01/10 13:000.36 0.12
N-Nitroso-di-n-propylamine ND mg/kg 1 04/07/10 20:08 621-64-704/01/10 13:000.36 0.069
N-Nitrosodiphenylamine ND mg/kg 1 04/07/10 20:08 86-30-604/01/10 13:000.36 0.11
Pentachlorophenol ND mg/kg 1 04/07/10 20:08 87-86-504/01/10 13:001.8 0.066
Phenanthrene ND mg/kg 1 04/07/10 20:08 85-01-804/01/10 13:000.36 0.060
Phenol ND mg/kg 1 04/07/10 20:08 108-95-204/01/10 13:000.36 0.11
Pyrene ND mg/kg 1 04/07/10 20:08 129-00-004/01/10 13:000.36 0.061
1,2,4-Trichlorobenzene ND mg/kg 1 04/07/10 20:08 120-82-104/01/10 13:000.36 0.070
2,4,5-Trichlorophenol ND mg/kg 1 04/07/10 20:08 95-95-404/01/10 13:000.36 0.11
2,4,6-Trichlorophenol ND mg/kg 1 04/07/10 20:08 88-06-204/01/10 13:000.36 0.080
Nitrobenzene-d5 (S)38 %1 04/07/10 20:08 4165-60-004/01/10 13:0030-120
2-Fluorobiphenyl (S)35 %1 04/07/10 20:08 321-60-804/01/10 13:0030-120
Terphenyl-d14 (S)44 %1 04/07/10 20:08 1718-51-004/01/10 13:0035-108
Phenol-d6 (S)35 %1 04/07/10 20:08 13127-88-304/01/10 13:0035-120
2-Fluorophenol (S)34 %1 04/07/10 20:08 367-12-404/01/10 13:0024-120
2,4,6-Tribromophenol (S)38 %1 04/07/10 20:08 118-79-6 S004/01/10 13:0040-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 11 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-5T 1.5FT Lab ID:9266446002 Collected:03/30/10 11:15 Received:03/31/10 15:15 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone ND mg/kg 1 04/01/10 14:34 67-64-10.089 0.0089
Benzene ND mg/kg 1 04/01/10 14:34 71-43-20.0045 0.0014
Bromobenzene ND mg/kg 1 04/01/10 14:34 108-86-10.0045 0.0018
Bromochloromethane ND mg/kg 1 04/01/10 14:34 74-97-50.0045 0.0015
Bromodichloromethane ND mg/kg 1 04/01/10 14:34 75-27-40.0045 0.0017
Bromoform ND mg/kg 1 04/01/10 14:34 75-25-20.0045 0.0020
Bromomethane ND mg/kg 1 04/01/10 14:34 74-83-90.0089 0.0022
2-Butanone (MEK)ND mg/kg 1 04/01/10 14:34 78-93-30.089 0.0026
n-Butylbenzene ND mg/kg 1 04/01/10 14:34 104-51-80.0045 0.0016
sec-Butylbenzene ND mg/kg 1 04/01/10 14:34 135-98-80.0045 0.0014
tert-Butylbenzene ND mg/kg 1 04/01/10 14:34 98-06-60.0045 0.0018
Carbon tetrachloride ND mg/kg 1 04/01/10 14:34 56-23-50.0045 0.0023
Chlorobenzene ND mg/kg 1 04/01/10 14:34 108-90-70.0045 0.0017
Chloroethane ND mg/kg 1 04/01/10 14:34 75-00-30.0089 0.0021
Chloroform ND mg/kg 1 04/01/10 14:34 67-66-30.0045 0.0014
Chloromethane ND mg/kg 1 04/01/10 14:34 74-87-30.0089 0.0021
2-Chlorotoluene ND mg/kg 1 04/01/10 14:34 95-49-80.0045 0.0015
4-Chlorotoluene ND mg/kg 1 04/01/10 14:34 106-43-40.0045 0.0016
1,2-Dibromo-3-chloropropane ND mg/kg 1 04/01/10 14:34 96-12-80.0045 0.0032
Dibromochloromethane ND mg/kg 1 04/01/10 14:34 124-48-10.0045 0.0016
1,2-Dibromoethane (EDB)ND mg/kg 1 04/01/10 14:34 106-93-40.0045 0.0016
Dibromomethane ND mg/kg 1 04/01/10 14:34 74-95-30.0045 0.0022
1,2-Dichlorobenzene ND mg/kg 1 04/01/10 14:34 95-50-10.0045 0.0017
1,3-Dichlorobenzene ND mg/kg 1 04/01/10 14:34 541-73-10.0045 0.0018
1,4-Dichlorobenzene ND mg/kg 1 04/01/10 14:34 106-46-70.0045 0.0015
Dichlorodifluoromethane ND mg/kg 1 04/01/10 14:34 75-71-80.0089 0.0032
1,1-Dichloroethane ND mg/kg 1 04/01/10 14:34 75-34-30.0045 0.0013
1,2-Dichloroethane ND mg/kg 1 04/01/10 14:34 107-06-20.0045 0.0020
1,1-Dichloroethene ND mg/kg 1 04/01/10 14:34 75-35-40.0045 0.0016
cis-1,2-Dichloroethene ND mg/kg 1 04/01/10 14:34 156-59-20.0045 0.0012
trans-1,2-Dichloroethene ND mg/kg 1 04/01/10 14:34 156-60-50.0045 0.0017
1,2-Dichloropropane ND mg/kg 1 04/01/10 14:34 78-87-50.0045 0.0015
1,3-Dichloropropane ND mg/kg 1 04/01/10 14:34 142-28-90.0045 0.0017
2,2-Dichloropropane ND mg/kg 1 04/01/10 14:34 594-20-70.0045 0.0015
1,1-Dichloropropene ND mg/kg 1 04/01/10 14:34 563-58-60.0045 0.0013
cis-1,3-Dichloropropene ND mg/kg 1 04/01/10 14:34 10061-01-50.0045 0.0016
trans-1,3-Dichloropropene ND mg/kg 1 04/01/10 14:34 10061-02-60.0045 0.0013
Diisopropyl ether ND mg/kg 1 04/01/10 14:34 108-20-30.0045 0.0015
Ethylbenzene ND mg/kg 1 04/01/10 14:34 100-41-40.0045 0.0016
Hexachloro-1,3-butadiene ND mg/kg 1 04/01/10 14:34 87-68-30.0045 0.0018
2-Hexanone ND mg/kg 1 04/01/10 14:34 591-78-60.045 0.0035
Isopropylbenzene (Cumene)ND mg/kg 1 04/01/10 14:34 98-82-80.0045 0.0017
p-Isopropyltoluene ND mg/kg 1 04/01/10 14:34 99-87-60.0045 0.0015
Methylene Chloride ND mg/kg 1 04/01/10 14:34 75-09-20.018 0.0027
4-Methyl-2-pentanone (MIBK)ND mg/kg 1 04/01/10 14:34 108-10-10.045 0.0033
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 12 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-5T 1.5FT Lab ID:9266446002 Collected:03/30/10 11:15 Received:03/31/10 15:15 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
8260/5035A Volatile Organics Analytical Method: EPA 8260
Methyl-tert-butyl ether ND mg/kg 1 04/01/10 14:34 1634-04-40.0045 0.0013
Naphthalene ND mg/kg 1 04/01/10 14:34 91-20-30.0045 0.0011
n-Propylbenzene ND mg/kg 1 04/01/10 14:34 103-65-10.0045 0.0015
Styrene ND mg/kg 1 04/01/10 14:34 100-42-50.0045 0.0016
1,1,1,2-Tetrachloroethane ND mg/kg 1 04/01/10 14:34 630-20-60.0045 0.0019
1,1,2,2-Tetrachloroethane ND mg/kg 1 04/01/10 14:34 79-34-50.0045 0.0017
Tetrachloroethene ND mg/kg 1 04/01/10 14:34 127-18-40.0045 0.0015
Toluene ND mg/kg 1 04/01/10 14:34 108-88-30.0045 0.0016
1,2,3-Trichlorobenzene ND mg/kg 1 04/01/10 14:34 87-61-60.0045 0.0020
1,2,4-Trichlorobenzene ND mg/kg 1 04/01/10 14:34 120-82-10.0045 0.0014
1,1,1-Trichloroethane ND mg/kg 1 04/01/10 14:34 71-55-60.0045 0.0016
1,1,2-Trichloroethane ND mg/kg 1 04/01/10 14:34 79-00-50.0045 0.0019
Trichloroethene ND mg/kg 1 04/01/10 14:34 79-01-60.0045 0.0019
Trichlorofluoromethane ND mg/kg 1 04/01/10 14:34 75-69-40.0045 0.0020
1,2,3-Trichloropropane ND mg/kg 1 04/01/10 14:34 96-18-40.0045 0.0014
1,2,4-Trimethylbenzene ND mg/kg 1 04/01/10 14:34 95-63-60.0045 0.0018
1,3,5-Trimethylbenzene ND mg/kg 1 04/01/10 14:34 108-67-80.0045 0.0016
Vinyl acetate ND mg/kg 1 04/01/10 14:34 108-05-40.045 0.0078
Vinyl chloride ND mg/kg 1 04/01/10 14:34 75-01-40.0089 0.0016
Xylene (Total)ND mg/kg 1 04/01/10 14:34 1330-20-70.0089 0.0032
m&p-Xylene ND mg/kg 1 04/01/10 14:34 1330-20-70.0089 0.0032
o-Xylene ND mg/kg 1 04/01/10 14:34 95-47-60.0045 0.0017
Dibromofluoromethane (S)104 %1 04/01/10 14:34 1868-53-779-116
Toluene-d8 (S)101 %1 04/01/10 14:34 2037-26-588-110
4-Bromofluorobenzene (S)86 %1 04/01/10 14:34 460-00-474-115
1,2-Dichloroethane-d4 (S)106 %1 04/01/10 14:34 17060-07-069-121
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 8.8 %1 04/02/10 14:260.10 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 13 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-6T 2FT Lab ID:9266446003 Collected:03/30/10 11:45 Received:03/31/10 15:15 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
MADEP EPH NC Soil Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)ND mg/kg 1 04/06/10 01:1504/02/10 11:3011.1 11.1
Aliphatic (C19-C36)ND mg/kg 1 04/06/10 01:1504/02/10 11:3011.1 11.1
Aromatic (C11-C22)ND mg/kg 1 04/06/10 01:1504/02/10 11:3011.1 11.1
Nonatriacontane (S)68 %1 04/06/10 01:15 7194-86-704/02/10 11:3040-140
o-Terphenyl (S)85 %1 04/06/10 01:15 84-15-104/02/10 11:3040-140
2-Fluorobiphenyl (S)114 %1 04/06/10 01:15 321-60-804/02/10 11:3040-140
2-Bromonaphthalene (S)114 %1 04/06/10 01:15 580-13-204/02/10 11:3040-140
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)ND mg/kg 1 04/06/10 18:1704/06/10 15:409.3 9.3
Aliphatic (C09-C12)ND mg/kg 1 04/06/10 18:1704/06/10 15:409.3 9.3
Aromatic (C09-C10)ND mg/kg 1 04/06/10 18:1704/06/10 15:409.3 9.3
2,5-Dibromotoluene (PID)(S)113 %1 04/06/10 18:1704/06/10 15:4070-130
2,5-Dibromotoluene (FID)(S)121 %1 04/06/10 18:1704/06/10 15:4070-130
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene ND mg/kg 1 04/07/10 21:30 83-32-904/01/10 13:000.37 0.085
Acenaphthylene ND mg/kg 1 04/07/10 21:30 208-96-804/01/10 13:000.37 0.087
Anthracene ND mg/kg 1 04/07/10 21:30 120-12-704/01/10 13:000.37 0.082
Benzo(a)anthracene 0.090J mg/kg 1 04/07/10 21:30 56-55-304/01/10 13:000.37 0.068
Benzo(a)pyrene ND mg/kg 1 04/07/10 21:30 50-32-804/01/10 13:000.37 0.070
Benzo(b)fluoranthene 0.083J mg/kg 1 04/07/10 21:30 205-99-204/01/10 13:000.37 0.063
Benzo(g,h,i)perylene ND mg/kg 1 04/07/10 21:30 191-24-204/01/10 13:000.37 0.093
Benzo(k)fluoranthene ND mg/kg 1 04/07/10 21:30 207-08-904/01/10 13:000.37 0.072
Benzoic Acid ND mg/kg 1 04/07/10 21:30 65-85-004/01/10 13:001.8 0.067
Benzyl alcohol ND mg/kg 1 04/07/10 21:30 100-51-604/01/10 13:000.73 0.073
4-Bromophenylphenyl ether ND mg/kg 1 04/07/10 21:30 101-55-304/01/10 13:000.37 0.067
Butylbenzylphthalate ND mg/kg 1 04/07/10 21:30 85-68-704/01/10 13:000.37 0.078
4-Chloro-3-methylphenol ND mg/kg 1 04/07/10 21:30 59-50-704/01/10 13:000.73 0.076
4-Chloroaniline ND mg/kg 1 04/07/10 21:30 106-47-804/01/10 13:001.8 0.10
bis(2-Chloroethoxy)methane ND mg/kg 1 04/07/10 21:30 111-91-104/01/10 13:000.37 0.086
bis(2-Chloroethyl) ether ND mg/kg 1 04/07/10 21:30 111-44-404/01/10 13:000.37 0.093
bis(2-Chloroisopropyl) ether ND mg/kg 1 04/07/10 21:30 108-60-104/01/10 13:000.37 0.098
2-Chloronaphthalene ND mg/kg 1 04/07/10 21:30 91-58-704/01/10 13:000.37 0.072
2-Chlorophenol ND mg/kg 1 04/07/10 21:30 95-57-804/01/10 13:000.37 0.10
4-Chlorophenylphenyl ether ND mg/kg 1 04/07/10 21:30 7005-72-304/01/10 13:000.37 0.076
Chrysene 0.091J mg/kg 1 04/07/10 21:30 218-01-904/01/10 13:000.37 0.049
Dibenz(a,h)anthracene ND mg/kg 1 04/07/10 21:30 53-70-304/01/10 13:000.37 0.078
Dibenzofuran ND mg/kg 1 04/07/10 21:30 132-64-904/01/10 13:000.37 0.060
1,2-Dichlorobenzene ND mg/kg 1 04/07/10 21:30 95-50-104/01/10 13:000.37 0.098
1,3-Dichlorobenzene ND mg/kg 1 04/07/10 21:30 541-73-104/01/10 13:000.37 0.083
1,4-Dichlorobenzene ND mg/kg 1 04/07/10 21:30 106-46-704/01/10 13:000.37 0.10
3,3'-Dichlorobenzidine 0.15J mg/kg 1 04/07/10 21:30 91-94-104/01/10 13:001.8 0.080
2,4-Dichlorophenol ND mg/kg 1 04/07/10 21:30 120-83-204/01/10 13:000.37 0.080
Diethylphthalate ND mg/kg 1 04/07/10 21:30 84-66-204/01/10 13:000.37 0.057
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 14 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-6T 2FT Lab ID:9266446003 Collected:03/30/10 11:45 Received:03/31/10 15:15 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
2,4-Dimethylphenol ND mg/kg 1 04/07/10 21:30 105-67-904/01/10 13:000.37 0.14
Dimethylphthalate ND mg/kg 1 04/07/10 21:30 131-11-304/01/10 13:000.37 0.075
Di-n-butylphthalate ND mg/kg 1 04/07/10 21:30 84-74-204/01/10 13:000.37 0.060
4,6-Dinitro-2-methylphenol ND mg/kg 1 04/07/10 21:30 534-52-104/01/10 13:000.73 0.073
2,4-Dinitrophenol ND mg/kg 1 04/07/10 21:30 51-28-504/01/10 13:001.8 0.060
2,4-Dinitrotoluene ND mg/kg 1 04/07/10 21:30 121-14-204/01/10 13:000.37 0.069
2,6-Dinitrotoluene ND mg/kg 1 04/07/10 21:30 606-20-204/01/10 13:000.37 0.077
Di-n-octylphthalate ND mg/kg 1 04/07/10 21:30 117-84-004/01/10 13:000.37 0.077
bis(2-Ethylhexyl)phthalate ND mg/kg 1 04/07/10 21:30 117-81-704/01/10 13:000.37 0.10
Fluoranthene 0.067J mg/kg 1 04/07/10 21:30 206-44-004/01/10 13:000.37 0.053
Fluorene ND mg/kg 1 04/07/10 21:30 86-73-704/01/10 13:000.37 0.076
Hexachloro-1,3-butadiene ND mg/kg 1 04/07/10 21:30 87-68-304/01/10 13:000.37 0.063
Hexachlorobenzene ND mg/kg 1 04/07/10 21:30 118-74-104/01/10 13:000.37 0.047
Hexachlorocyclopentadiene ND mg/kg 1 04/07/10 21:30 77-47-404/01/10 13:000.37 0.068
Hexachloroethane ND mg/kg 1 04/07/10 21:30 67-72-104/01/10 13:000.37 0.097
Indeno(1,2,3-cd)pyrene ND mg/kg 1 04/07/10 21:30 193-39-504/01/10 13:000.37 0.076
Isophorone ND mg/kg 1 04/07/10 21:30 78-59-104/01/10 13:000.37 0.082
1-Methylnaphthalene ND mg/kg 1 04/07/10 21:30 90-12-004/01/10 13:000.37 0.096
2-Methylnaphthalene ND mg/kg 1 04/07/10 21:30 91-57-604/01/10 13:000.37 0.079
2-Methylphenol(o-Cresol)ND mg/kg 1 04/07/10 21:30 95-48-704/01/10 13:000.37 0.11
3&4-Methylphenol(m&p Cresol)ND mg/kg 1 04/07/10 21:3004/01/10 13:000.37 0.14
Naphthalene ND mg/kg 1 04/07/10 21:30 91-20-304/01/10 13:000.37 0.090
2-Nitroaniline ND mg/kg 1 04/07/10 21:30 88-74-404/01/10 13:001.8 0.11
3-Nitroaniline ND mg/kg 1 04/07/10 21:30 99-09-204/01/10 13:001.8 0.10
4-Nitroaniline ND mg/kg 1 04/07/10 21:30 100-01-604/01/10 13:000.73 0.10
Nitrobenzene ND mg/kg 1 04/07/10 21:30 98-95-304/01/10 13:000.37 0.10
2-Nitrophenol ND mg/kg 1 04/07/10 21:30 88-75-504/01/10 13:000.37 0.089
4-Nitrophenol ND mg/kg 1 04/07/10 21:30 100-02-704/01/10 13:001.8 0.066
N-Nitrosodimethylamine ND mg/kg 1 04/07/10 21:30 62-75-904/01/10 13:000.37 0.12
N-Nitroso-di-n-propylamine ND mg/kg 1 04/07/10 21:30 621-64-704/01/10 13:000.37 0.070
N-Nitrosodiphenylamine ND mg/kg 1 04/07/10 21:30 86-30-604/01/10 13:000.37 0.11
Pentachlorophenol ND mg/kg 1 04/07/10 21:30 87-86-504/01/10 13:001.8 0.067
Phenanthrene ND mg/kg 1 04/07/10 21:30 85-01-804/01/10 13:000.37 0.061
Phenol ND mg/kg 1 04/07/10 21:30 108-95-204/01/10 13:000.37 0.11
Pyrene ND mg/kg 1 04/07/10 21:30 129-00-004/01/10 13:000.37 0.062
1,2,4-Trichlorobenzene ND mg/kg 1 04/07/10 21:30 120-82-104/01/10 13:000.37 0.071
2,4,5-Trichlorophenol ND mg/kg 1 04/07/10 21:30 95-95-404/01/10 13:000.37 0.11
2,4,6-Trichlorophenol ND mg/kg 1 04/07/10 21:30 88-06-204/01/10 13:000.37 0.081
Nitrobenzene-d5 (S)48 %1 04/07/10 21:30 4165-60-004/01/10 13:0030-120
2-Fluorobiphenyl (S)49 %1 04/07/10 21:30 321-60-804/01/10 13:0030-120
Terphenyl-d14 (S)53 %1 04/07/10 21:30 1718-51-004/01/10 13:0035-108
Phenol-d6 (S)39 %1 04/07/10 21:30 13127-88-304/01/10 13:0035-120
2-Fluorophenol (S)38 %1 04/07/10 21:30 367-12-404/01/10 13:0024-120
2,4,6-Tribromophenol (S)50 %1 04/07/10 21:30 118-79-604/01/10 13:0040-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 15 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-6T 2FT Lab ID:9266446003 Collected:03/30/10 11:45 Received:03/31/10 15:15 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone ND mg/kg 1 04/01/10 14:52 67-64-10.10 0.010
Benzene ND mg/kg 1 04/01/10 14:52 71-43-20.0052 0.0017
Bromobenzene ND mg/kg 1 04/01/10 14:52 108-86-10.0052 0.0021
Bromochloromethane ND mg/kg 1 04/01/10 14:52 74-97-50.0052 0.0018
Bromodichloromethane ND mg/kg 1 04/01/10 14:52 75-27-40.0052 0.0020
Bromoform ND mg/kg 1 04/01/10 14:52 75-25-20.0052 0.0024
Bromomethane ND mg/kg 1 04/01/10 14:52 74-83-90.010 0.0026
2-Butanone (MEK)ND mg/kg 1 04/01/10 14:52 78-93-30.10 0.0030
n-Butylbenzene ND mg/kg 1 04/01/10 14:52 104-51-80.0052 0.0019
sec-Butylbenzene ND mg/kg 1 04/01/10 14:52 135-98-80.0052 0.0017
tert-Butylbenzene ND mg/kg 1 04/01/10 14:52 98-06-60.0052 0.0021
Carbon tetrachloride ND mg/kg 1 04/01/10 14:52 56-23-50.0052 0.0027
Chlorobenzene ND mg/kg 1 04/01/10 14:52 108-90-70.0052 0.0020
Chloroethane ND mg/kg 1 04/01/10 14:52 75-00-30.010 0.0025
Chloroform ND mg/kg 1 04/01/10 14:52 67-66-30.0052 0.0017
Chloromethane ND mg/kg 1 04/01/10 14:52 74-87-30.010 0.0025
2-Chlorotoluene ND mg/kg 1 04/01/10 14:52 95-49-80.0052 0.0018
4-Chlorotoluene ND mg/kg 1 04/01/10 14:52 106-43-40.0052 0.0019
1,2-Dibromo-3-chloropropane ND mg/kg 1 04/01/10 14:52 96-12-80.0052 0.0038
Dibromochloromethane ND mg/kg 1 04/01/10 14:52 124-48-10.0052 0.0019
1,2-Dibromoethane (EDB)ND mg/kg 1 04/01/10 14:52 106-93-40.0052 0.0019
Dibromomethane ND mg/kg 1 04/01/10 14:52 74-95-30.0052 0.0026
1,2-Dichlorobenzene ND mg/kg 1 04/01/10 14:52 95-50-10.0052 0.0020
1,3-Dichlorobenzene ND mg/kg 1 04/01/10 14:52 541-73-10.0052 0.0021
1,4-Dichlorobenzene ND mg/kg 1 04/01/10 14:52 106-46-70.0052 0.0018
Dichlorodifluoromethane ND mg/kg 1 04/01/10 14:52 75-71-80.010 0.0038
1,1-Dichloroethane ND mg/kg 1 04/01/10 14:52 75-34-30.0052 0.0016
1,2-Dichloroethane ND mg/kg 1 04/01/10 14:52 107-06-20.0052 0.0023
1,1-Dichloroethene ND mg/kg 1 04/01/10 14:52 75-35-40.0052 0.0019
cis-1,2-Dichloroethene ND mg/kg 1 04/01/10 14:52 156-59-20.0052 0.0015
trans-1,2-Dichloroethene ND mg/kg 1 04/01/10 14:52 156-60-50.0052 0.0020
1,2-Dichloropropane ND mg/kg 1 04/01/10 14:52 78-87-50.0052 0.0018
1,3-Dichloropropane ND mg/kg 1 04/01/10 14:52 142-28-90.0052 0.0020
2,2-Dichloropropane ND mg/kg 1 04/01/10 14:52 594-20-70.0052 0.0018
1,1-Dichloropropene ND mg/kg 1 04/01/10 14:52 563-58-60.0052 0.0016
cis-1,3-Dichloropropene ND mg/kg 1 04/01/10 14:52 10061-01-50.0052 0.0019
trans-1,3-Dichloropropene ND mg/kg 1 04/01/10 14:52 10061-02-60.0052 0.0016
Diisopropyl ether ND mg/kg 1 04/01/10 14:52 108-20-30.0052 0.0018
Ethylbenzene ND mg/kg 1 04/01/10 14:52 100-41-40.0052 0.0019
Hexachloro-1,3-butadiene ND mg/kg 1 04/01/10 14:52 87-68-30.0052 0.0021
2-Hexanone ND mg/kg 1 04/01/10 14:52 591-78-60.052 0.0041
Isopropylbenzene (Cumene)ND mg/kg 1 04/01/10 14:52 98-82-80.0052 0.0020
p-Isopropyltoluene ND mg/kg 1 04/01/10 14:52 99-87-60.0052 0.0018
Methylene Chloride ND mg/kg 1 04/01/10 14:52 75-09-20.021 0.0031
4-Methyl-2-pentanone (MIBK)ND mg/kg 1 04/01/10 14:52 108-10-10.052 0.0039
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 16 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-6T 2FT Lab ID:9266446003 Collected:03/30/10 11:45 Received:03/31/10 15:15 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
8260/5035A Volatile Organics Analytical Method: EPA 8260
Methyl-tert-butyl ether ND mg/kg 1 04/01/10 14:52 1634-04-40.0052 0.0016
Naphthalene ND mg/kg 1 04/01/10 14:52 91-20-30.0052 0.0013
n-Propylbenzene ND mg/kg 1 04/01/10 14:52 103-65-10.0052 0.0018
Styrene ND mg/kg 1 04/01/10 14:52 100-42-50.0052 0.0019
1,1,1,2-Tetrachloroethane ND mg/kg 1 04/01/10 14:52 630-20-60.0052 0.0022
1,1,2,2-Tetrachloroethane ND mg/kg 1 04/01/10 14:52 79-34-50.0052 0.0020
Tetrachloroethene ND mg/kg 1 04/01/10 14:52 127-18-40.0052 0.0018
Toluene ND mg/kg 1 04/01/10 14:52 108-88-30.0052 0.0019
1,2,3-Trichlorobenzene ND mg/kg 1 04/01/10 14:52 87-61-60.0052 0.0023
1,2,4-Trichlorobenzene ND mg/kg 1 04/01/10 14:52 120-82-10.0052 0.0017
1,1,1-Trichloroethane ND mg/kg 1 04/01/10 14:52 71-55-60.0052 0.0019
1,1,2-Trichloroethane ND mg/kg 1 04/01/10 14:52 79-00-50.0052 0.0022
Trichloroethene ND mg/kg 1 04/01/10 14:52 79-01-60.0052 0.0022
Trichlorofluoromethane ND mg/kg 1 04/01/10 14:52 75-69-40.0052 0.0023
1,2,3-Trichloropropane ND mg/kg 1 04/01/10 14:52 96-18-40.0052 0.0017
1,2,4-Trimethylbenzene ND mg/kg 1 04/01/10 14:52 95-63-60.0052 0.0021
1,3,5-Trimethylbenzene ND mg/kg 1 04/01/10 14:52 108-67-80.0052 0.0019
Vinyl acetate ND mg/kg 1 04/01/10 14:52 108-05-40.052 0.0092
Vinyl chloride ND mg/kg 1 04/01/10 14:52 75-01-40.010 0.0019
Xylene (Total)ND mg/kg 1 04/01/10 14:52 1330-20-70.010 0.0038
m&p-Xylene ND mg/kg 1 04/01/10 14:52 1330-20-70.010 0.0038
o-Xylene ND mg/kg 1 04/01/10 14:52 95-47-60.0052 0.0020
Dibromofluoromethane (S)108 %1 04/01/10 14:52 1868-53-779-116
Toluene-d8 (S)101 %1 04/01/10 14:52 2037-26-588-110
4-Bromofluorobenzene (S)86 %1 04/01/10 14:52 460-00-474-115
1,2-Dichloroethane-d4 (S)109 %1 04/01/10 14:52 17060-07-069-121
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 10.1 %1 04/02/10 14:260.10 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 17 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-7T 2FT Lab ID:9266446004 Collected:03/30/10 12:30 Received:03/31/10 15:15 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
MADEP EPH NC Soil Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)ND mg/kg 1 04/06/10 01:5104/02/10 11:3011.6 11.6
Aliphatic (C19-C36)ND mg/kg 1 04/06/10 01:5104/02/10 11:3011.6 11.6
Aromatic (C11-C22)ND mg/kg 1 04/06/10 01:5104/02/10 11:3011.6 11.6
Nonatriacontane (S)79 %1 04/06/10 01:51 7194-86-704/02/10 11:3040-140
o-Terphenyl (S)96 %1 04/06/10 01:51 84-15-104/02/10 11:3040-140
2-Fluorobiphenyl (S)123 %1 04/06/10 01:51 321-60-804/02/10 11:3040-140
2-Bromonaphthalene (S)127 %1 04/06/10 01:51 580-13-204/02/10 11:3040-140
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)ND mg/kg 1 04/06/10 18:4104/06/10 15:409.5 9.5
Aliphatic (C09-C12)ND mg/kg 1 04/06/10 18:4104/06/10 15:409.5 9.5
Aromatic (C09-C10)ND mg/kg 1 04/06/10 18:4104/06/10 15:409.5 9.5
2,5-Dibromotoluene (PID)(S)99 %1 04/06/10 18:4104/06/10 15:4070-130
2,5-Dibromotoluene (FID)(S)103 %1 04/06/10 18:4104/06/10 15:4070-130
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene ND mg/kg 1 04/07/10 21:58 83-32-904/01/10 13:000.38 0.088
Acenaphthylene ND mg/kg 1 04/07/10 21:58 208-96-804/01/10 13:000.38 0.090
Anthracene ND mg/kg 1 04/07/10 21:58 120-12-704/01/10 13:000.38 0.086
Benzo(a)anthracene ND mg/kg 1 04/07/10 21:58 56-55-304/01/10 13:000.38 0.071
Benzo(a)pyrene ND mg/kg 1 04/07/10 21:58 50-32-804/01/10 13:000.38 0.073
Benzo(b)fluoranthene ND mg/kg 1 04/07/10 21:58 205-99-204/01/10 13:000.38 0.066
Benzo(g,h,i)perylene ND mg/kg 1 04/07/10 21:58 191-24-204/01/10 13:000.38 0.097
Benzo(k)fluoranthene ND mg/kg 1 04/07/10 21:58 207-08-904/01/10 13:000.38 0.075
Benzoic Acid ND mg/kg 1 04/07/10 21:58 65-85-004/01/10 13:001.9 0.070
Benzyl alcohol ND mg/kg 1 04/07/10 21:58 100-51-604/01/10 13:000.77 0.077
4-Bromophenylphenyl ether ND mg/kg 1 04/07/10 21:58 101-55-304/01/10 13:000.38 0.070
Butylbenzylphthalate ND mg/kg 1 04/07/10 21:58 85-68-704/01/10 13:000.38 0.081
4-Chloro-3-methylphenol ND mg/kg 1 04/07/10 21:58 59-50-704/01/10 13:000.77 0.079
4-Chloroaniline ND mg/kg 1 04/07/10 21:58 106-47-804/01/10 13:001.9 0.11
bis(2-Chloroethoxy)methane ND mg/kg 1 04/07/10 21:58 111-91-104/01/10 13:000.38 0.089
bis(2-Chloroethyl) ether ND mg/kg 1 04/07/10 21:58 111-44-404/01/10 13:000.38 0.097
bis(2-Chloroisopropyl) ether ND mg/kg 1 04/07/10 21:58 108-60-104/01/10 13:000.38 0.10
2-Chloronaphthalene ND mg/kg 1 04/07/10 21:58 91-58-704/01/10 13:000.38 0.075
2-Chlorophenol ND mg/kg 1 04/07/10 21:58 95-57-804/01/10 13:000.38 0.10
4-Chlorophenylphenyl ether ND mg/kg 1 04/07/10 21:58 7005-72-304/01/10 13:000.38 0.079
Chrysene ND mg/kg 1 04/07/10 21:58 218-01-904/01/10 13:000.38 0.051
Dibenz(a,h)anthracene ND mg/kg 1 04/07/10 21:58 53-70-304/01/10 13:000.38 0.081
Dibenzofuran ND mg/kg 1 04/07/10 21:58 132-64-904/01/10 13:000.38 0.063
1,2-Dichlorobenzene ND mg/kg 1 04/07/10 21:58 95-50-104/01/10 13:000.38 0.10
1,3-Dichlorobenzene ND mg/kg 1 04/07/10 21:58 541-73-104/01/10 13:000.38 0.087
1,4-Dichlorobenzene ND mg/kg 1 04/07/10 21:58 106-46-704/01/10 13:000.38 0.11
3,3'-Dichlorobenzidine 0.14J mg/kg 1 04/07/10 21:58 91-94-104/01/10 13:001.9 0.083
2,4-Dichlorophenol ND mg/kg 1 04/07/10 21:58 120-83-204/01/10 13:000.38 0.083
Diethylphthalate ND mg/kg 1 04/07/10 21:58 84-66-204/01/10 13:000.38 0.059
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 18 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-7T 2FT Lab ID:9266446004 Collected:03/30/10 12:30 Received:03/31/10 15:15 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
2,4-Dimethylphenol ND mg/kg 1 04/07/10 21:58 105-67-904/01/10 13:000.38 0.15
Dimethylphthalate ND mg/kg 1 04/07/10 21:58 131-11-304/01/10 13:000.38 0.078
Di-n-butylphthalate ND mg/kg 1 04/07/10 21:58 84-74-204/01/10 13:000.38 0.063
4,6-Dinitro-2-methylphenol ND mg/kg 1 04/07/10 21:58 534-52-104/01/10 13:000.77 0.077
2,4-Dinitrophenol ND mg/kg 1 04/07/10 21:58 51-28-504/01/10 13:001.9 0.063
2,4-Dinitrotoluene ND mg/kg 1 04/07/10 21:58 121-14-204/01/10 13:000.38 0.072
2,6-Dinitrotoluene ND mg/kg 1 04/07/10 21:58 606-20-204/01/10 13:000.38 0.080
Di-n-octylphthalate ND mg/kg 1 04/07/10 21:58 117-84-004/01/10 13:000.38 0.080
bis(2-Ethylhexyl)phthalate ND mg/kg 1 04/07/10 21:58 117-81-704/01/10 13:000.38 0.10
Fluoranthene ND mg/kg 1 04/07/10 21:58 206-44-004/01/10 13:000.38 0.056
Fluorene ND mg/kg 1 04/07/10 21:58 86-73-704/01/10 13:000.38 0.079
Hexachloro-1,3-butadiene ND mg/kg 1 04/07/10 21:58 87-68-304/01/10 13:000.38 0.066
Hexachlorobenzene ND mg/kg 1 04/07/10 21:58 118-74-104/01/10 13:000.38 0.049
Hexachlorocyclopentadiene ND mg/kg 1 04/07/10 21:58 77-47-404/01/10 13:000.38 0.071
Hexachloroethane ND mg/kg 1 04/07/10 21:58 67-72-104/01/10 13:000.38 0.10
Indeno(1,2,3-cd)pyrene ND mg/kg 1 04/07/10 21:58 193-39-504/01/10 13:000.38 0.079
Isophorone ND mg/kg 1 04/07/10 21:58 78-59-104/01/10 13:000.38 0.086
1-Methylnaphthalene ND mg/kg 1 04/07/10 21:58 90-12-004/01/10 13:000.38 0.10
2-Methylnaphthalene ND mg/kg 1 04/07/10 21:58 91-57-604/01/10 13:000.38 0.082
2-Methylphenol(o-Cresol)ND mg/kg 1 04/07/10 21:58 95-48-704/01/10 13:000.38 0.12
3&4-Methylphenol(m&p Cresol)ND mg/kg 1 04/07/10 21:5804/01/10 13:000.38 0.15
Naphthalene ND mg/kg 1 04/07/10 21:58 91-20-304/01/10 13:000.38 0.094
2-Nitroaniline ND mg/kg 1 04/07/10 21:58 88-74-404/01/10 13:001.9 0.12
3-Nitroaniline ND mg/kg 1 04/07/10 21:58 99-09-204/01/10 13:001.9 0.10
4-Nitroaniline ND mg/kg 1 04/07/10 21:58 100-01-604/01/10 13:000.77 0.11
Nitrobenzene ND mg/kg 1 04/07/10 21:58 98-95-304/01/10 13:000.38 0.10
2-Nitrophenol ND mg/kg 1 04/07/10 21:58 88-75-504/01/10 13:000.38 0.093
4-Nitrophenol ND mg/kg 1 04/07/10 21:58 100-02-704/01/10 13:001.9 0.068
N-Nitrosodimethylamine ND mg/kg 1 04/07/10 21:58 62-75-904/01/10 13:000.38 0.12
N-Nitroso-di-n-propylamine ND mg/kg 1 04/07/10 21:58 621-64-704/01/10 13:000.38 0.073
N-Nitrosodiphenylamine ND mg/kg 1 04/07/10 21:58 86-30-604/01/10 13:000.38 0.11
Pentachlorophenol ND mg/kg 1 04/07/10 21:58 87-86-504/01/10 13:001.9 0.070
Phenanthrene ND mg/kg 1 04/07/10 21:58 85-01-804/01/10 13:000.38 0.064
Phenol ND mg/kg 1 04/07/10 21:58 108-95-204/01/10 13:000.38 0.11
Pyrene ND mg/kg 1 04/07/10 21:58 129-00-004/01/10 13:000.38 0.065
1,2,4-Trichlorobenzene ND mg/kg 1 04/07/10 21:58 120-82-104/01/10 13:000.38 0.074
2,4,5-Trichlorophenol ND mg/kg 1 04/07/10 21:58 95-95-404/01/10 13:000.38 0.12
2,4,6-Trichlorophenol ND mg/kg 1 04/07/10 21:58 88-06-204/01/10 13:000.38 0.085
Nitrobenzene-d5 (S)50 %1 04/07/10 21:58 4165-60-004/01/10 13:0030-120
2-Fluorobiphenyl (S)41 %1 04/07/10 21:58 321-60-804/01/10 13:0030-120
Terphenyl-d14 (S)44 %1 04/07/10 21:58 1718-51-004/01/10 13:0035-108
Phenol-d6 (S)41 %1 04/07/10 21:58 13127-88-304/01/10 13:0035-120
2-Fluorophenol (S)44 %1 04/07/10 21:58 367-12-404/01/10 13:0024-120
2,4,6-Tribromophenol (S)38 %1 04/07/10 21:58 118-79-6 S004/01/10 13:0040-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 19 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-7T 2FT Lab ID:9266446004 Collected:03/30/10 12:30 Received:03/31/10 15:15 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone ND mg/kg 1 04/01/10 15:10 67-64-10.10 0.010
Benzene ND mg/kg 1 04/01/10 15:10 71-43-20.0052 0.0017
Bromobenzene ND mg/kg 1 04/01/10 15:10 108-86-10.0052 0.0021
Bromochloromethane ND mg/kg 1 04/01/10 15:10 74-97-50.0052 0.0018
Bromodichloromethane ND mg/kg 1 04/01/10 15:10 75-27-40.0052 0.0020
Bromoform ND mg/kg 1 04/01/10 15:10 75-25-20.0052 0.0024
Bromomethane ND mg/kg 1 04/01/10 15:10 74-83-90.010 0.0026
2-Butanone (MEK)ND mg/kg 1 04/01/10 15:10 78-93-30.10 0.0030
n-Butylbenzene ND mg/kg 1 04/01/10 15:10 104-51-80.0052 0.0019
sec-Butylbenzene ND mg/kg 1 04/01/10 15:10 135-98-80.0052 0.0017
tert-Butylbenzene ND mg/kg 1 04/01/10 15:10 98-06-60.0052 0.0021
Carbon tetrachloride ND mg/kg 1 04/01/10 15:10 56-23-50.0052 0.0027
Chlorobenzene ND mg/kg 1 04/01/10 15:10 108-90-70.0052 0.0020
Chloroethane ND mg/kg 1 04/01/10 15:10 75-00-30.010 0.0025
Chloroform ND mg/kg 1 04/01/10 15:10 67-66-30.0052 0.0017
Chloromethane ND mg/kg 1 04/01/10 15:10 74-87-30.010 0.0025
2-Chlorotoluene ND mg/kg 1 04/01/10 15:10 95-49-80.0052 0.0018
4-Chlorotoluene ND mg/kg 1 04/01/10 15:10 106-43-40.0052 0.0019
1,2-Dibromo-3-chloropropane ND mg/kg 1 04/01/10 15:10 96-12-80.0052 0.0038
Dibromochloromethane ND mg/kg 1 04/01/10 15:10 124-48-10.0052 0.0019
1,2-Dibromoethane (EDB)ND mg/kg 1 04/01/10 15:10 106-93-40.0052 0.0019
Dibromomethane ND mg/kg 1 04/01/10 15:10 74-95-30.0052 0.0026
1,2-Dichlorobenzene ND mg/kg 1 04/01/10 15:10 95-50-10.0052 0.0020
1,3-Dichlorobenzene ND mg/kg 1 04/01/10 15:10 541-73-10.0052 0.0021
1,4-Dichlorobenzene ND mg/kg 1 04/01/10 15:10 106-46-70.0052 0.0018
Dichlorodifluoromethane ND mg/kg 1 04/01/10 15:10 75-71-80.010 0.0038
1,1-Dichloroethane ND mg/kg 1 04/01/10 15:10 75-34-30.0052 0.0016
1,2-Dichloroethane ND mg/kg 1 04/01/10 15:10 107-06-20.0052 0.0023
1,1-Dichloroethene ND mg/kg 1 04/01/10 15:10 75-35-40.0052 0.0019
cis-1,2-Dichloroethene ND mg/kg 1 04/01/10 15:10 156-59-20.0052 0.0015
trans-1,2-Dichloroethene ND mg/kg 1 04/01/10 15:10 156-60-50.0052 0.0020
1,2-Dichloropropane ND mg/kg 1 04/01/10 15:10 78-87-50.0052 0.0018
1,3-Dichloropropane ND mg/kg 1 04/01/10 15:10 142-28-90.0052 0.0020
2,2-Dichloropropane ND mg/kg 1 04/01/10 15:10 594-20-70.0052 0.0018
1,1-Dichloropropene ND mg/kg 1 04/01/10 15:10 563-58-60.0052 0.0016
cis-1,3-Dichloropropene ND mg/kg 1 04/01/10 15:10 10061-01-50.0052 0.0019
trans-1,3-Dichloropropene ND mg/kg 1 04/01/10 15:10 10061-02-60.0052 0.0016
Diisopropyl ether ND mg/kg 1 04/01/10 15:10 108-20-30.0052 0.0018
Ethylbenzene ND mg/kg 1 04/01/10 15:10 100-41-40.0052 0.0019
Hexachloro-1,3-butadiene ND mg/kg 1 04/01/10 15:10 87-68-30.0052 0.0021
2-Hexanone ND mg/kg 1 04/01/10 15:10 591-78-60.052 0.0041
Isopropylbenzene (Cumene)ND mg/kg 1 04/01/10 15:10 98-82-80.0052 0.0020
p-Isopropyltoluene ND mg/kg 1 04/01/10 15:10 99-87-60.0052 0.0018
Methylene Chloride ND mg/kg 1 04/01/10 15:10 75-09-20.021 0.0031
4-Methyl-2-pentanone (MIBK)ND mg/kg 1 04/01/10 15:10 108-10-10.052 0.0039
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 20 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-7T 2FT Lab ID:9266446004 Collected:03/30/10 12:30 Received:03/31/10 15:15 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
8260/5035A Volatile Organics Analytical Method: EPA 8260
Methyl-tert-butyl ether ND mg/kg 1 04/01/10 15:10 1634-04-40.0052 0.0016
Naphthalene ND mg/kg 1 04/01/10 15:10 91-20-30.0052 0.0013
n-Propylbenzene ND mg/kg 1 04/01/10 15:10 103-65-10.0052 0.0018
Styrene ND mg/kg 1 04/01/10 15:10 100-42-50.0052 0.0019
1,1,1,2-Tetrachloroethane ND mg/kg 1 04/01/10 15:10 630-20-60.0052 0.0022
1,1,2,2-Tetrachloroethane ND mg/kg 1 04/01/10 15:10 79-34-50.0052 0.0020
Tetrachloroethene ND mg/kg 1 04/01/10 15:10 127-18-40.0052 0.0018
Toluene ND mg/kg 1 04/01/10 15:10 108-88-30.0052 0.0019
1,2,3-Trichlorobenzene ND mg/kg 1 04/01/10 15:10 87-61-60.0052 0.0023
1,2,4-Trichlorobenzene ND mg/kg 1 04/01/10 15:10 120-82-10.0052 0.0017
1,1,1-Trichloroethane ND mg/kg 1 04/01/10 15:10 71-55-60.0052 0.0019
1,1,2-Trichloroethane ND mg/kg 1 04/01/10 15:10 79-00-50.0052 0.0022
Trichloroethene ND mg/kg 1 04/01/10 15:10 79-01-60.0052 0.0022
Trichlorofluoromethane ND mg/kg 1 04/01/10 15:10 75-69-40.0052 0.0023
1,2,3-Trichloropropane ND mg/kg 1 04/01/10 15:10 96-18-40.0052 0.0017
1,2,4-Trimethylbenzene ND mg/kg 1 04/01/10 15:10 95-63-60.0052 0.0021
1,3,5-Trimethylbenzene ND mg/kg 1 04/01/10 15:10 108-67-80.0052 0.0019
Vinyl acetate ND mg/kg 1 04/01/10 15:10 108-05-40.052 0.0092
Vinyl chloride ND mg/kg 1 04/01/10 15:10 75-01-40.010 0.0019
Xylene (Total)ND mg/kg 1 04/01/10 15:10 1330-20-70.010 0.0038
m&p-Xylene ND mg/kg 1 04/01/10 15:10 1330-20-70.010 0.0038
o-Xylene ND mg/kg 1 04/01/10 15:10 95-47-60.0052 0.0020
Dibromofluoromethane (S)108 %1 04/01/10 15:10 1868-53-779-116
Toluene-d8 (S)104 %1 04/01/10 15:10 2037-26-588-110
4-Bromofluorobenzene (S)91 %1 04/01/10 15:10 460-00-474-115
1,2-Dichloroethane-d4 (S)111 %1 04/01/10 15:10 17060-07-069-121
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 13.7 %1 04/02/10 14:270.10 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 21 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-3T 2FT Lab ID:9266446005 Collected:03/30/10 13:00 Received:03/31/10 15:15 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
MADEP EPH NC Soil Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)ND mg/kg 1 04/06/10 02:2604/02/10 11:3011.5 11.5
Aliphatic (C19-C36)ND mg/kg 1 04/06/10 02:2604/02/10 11:3011.5 11.5
Aromatic (C11-C22)ND mg/kg 1 04/06/10 02:2604/02/10 11:3011.5 11.5
Nonatriacontane (S)73 %1 04/06/10 02:26 7194-86-704/02/10 11:3040-140
o-Terphenyl (S)48 %1 04/06/10 02:26 84-15-104/02/10 11:3040-140
2-Fluorobiphenyl (S)64 %1 04/06/10 02:26 321-60-804/02/10 11:3040-140
2-Bromonaphthalene (S)67 %1 04/06/10 02:26 580-13-204/02/10 11:3040-140
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)ND mg/kg 1 04/06/10 19:0604/06/10 15:4011.2 11.2
Aliphatic (C09-C12)ND mg/kg 1 04/06/10 19:0604/06/10 15:4011.2 11.2
Aromatic (C09-C10)ND mg/kg 1 04/06/10 19:0604/06/10 15:4011.2 11.2
2,5-Dibromotoluene (PID)(S)106 %1 04/06/10 19:0604/06/10 15:4070-130
2,5-Dibromotoluene (FID)(S)112 %1 04/06/10 19:0604/06/10 15:4070-130
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene ND mg/kg 1 04/07/10 22:25 83-32-904/01/10 13:000.38 0.088
Acenaphthylene ND mg/kg 1 04/07/10 22:25 208-96-804/01/10 13:000.38 0.090
Anthracene ND mg/kg 1 04/07/10 22:25 120-12-704/01/10 13:000.38 0.085
Benzo(a)anthracene ND mg/kg 1 04/07/10 22:25 56-55-304/01/10 13:000.38 0.070
Benzo(a)pyrene ND mg/kg 1 04/07/10 22:25 50-32-804/01/10 13:000.38 0.073
Benzo(b)fluoranthene ND mg/kg 1 04/07/10 22:25 205-99-204/01/10 13:000.38 0.066
Benzo(g,h,i)perylene ND mg/kg 1 04/07/10 22:25 191-24-204/01/10 13:000.38 0.097
Benzo(k)fluoranthene ND mg/kg 1 04/07/10 22:25 207-08-904/01/10 13:000.38 0.075
Benzoic Acid ND mg/kg 1 04/07/10 22:25 65-85-004/01/10 13:001.9 0.069
Benzyl alcohol ND mg/kg 1 04/07/10 22:25 100-51-604/01/10 13:000.76 0.076
4-Bromophenylphenyl ether ND mg/kg 1 04/07/10 22:25 101-55-304/01/10 13:000.38 0.069
Butylbenzylphthalate ND mg/kg 1 04/07/10 22:25 85-68-704/01/10 13:000.38 0.081
4-Chloro-3-methylphenol ND mg/kg 1 04/07/10 22:25 59-50-704/01/10 13:000.76 0.078
4-Chloroaniline ND mg/kg 1 04/07/10 22:25 106-47-804/01/10 13:001.9 0.11
bis(2-Chloroethoxy)methane ND mg/kg 1 04/07/10 22:25 111-91-104/01/10 13:000.38 0.089
bis(2-Chloroethyl) ether ND mg/kg 1 04/07/10 22:25 111-44-404/01/10 13:000.38 0.097
bis(2-Chloroisopropyl) ether ND mg/kg 1 04/07/10 22:25 108-60-104/01/10 13:000.38 0.10
2-Chloronaphthalene ND mg/kg 1 04/07/10 22:25 91-58-704/01/10 13:000.38 0.075
2-Chlorophenol ND mg/kg 1 04/07/10 22:25 95-57-804/01/10 13:000.38 0.10
4-Chlorophenylphenyl ether ND mg/kg 1 04/07/10 22:25 7005-72-304/01/10 13:000.38 0.078
Chrysene ND mg/kg 1 04/07/10 22:25 218-01-904/01/10 13:000.38 0.051
Dibenz(a,h)anthracene ND mg/kg 1 04/07/10 22:25 53-70-304/01/10 13:000.38 0.081
Dibenzofuran ND mg/kg 1 04/07/10 22:25 132-64-904/01/10 13:000.38 0.062
1,2-Dichlorobenzene ND mg/kg 1 04/07/10 22:25 95-50-104/01/10 13:000.38 0.10
1,3-Dichlorobenzene ND mg/kg 1 04/07/10 22:25 541-73-104/01/10 13:000.38 0.086
1,4-Dichlorobenzene ND mg/kg 1 04/07/10 22:25 106-46-704/01/10 13:000.38 0.11
3,3'-Dichlorobenzidine ND mg/kg 1 04/07/10 22:25 91-94-104/01/10 13:001.9 0.083
2,4-Dichlorophenol ND mg/kg 1 04/07/10 22:25 120-83-204/01/10 13:000.38 0.083
Diethylphthalate ND mg/kg 1 04/07/10 22:25 84-66-204/01/10 13:000.38 0.059
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 22 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-3T 2FT Lab ID:9266446005 Collected:03/30/10 13:00 Received:03/31/10 15:15 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
2,4-Dimethylphenol ND mg/kg 1 04/07/10 22:25 105-67-904/01/10 13:000.38 0.15
Dimethylphthalate ND mg/kg 1 04/07/10 22:25 131-11-304/01/10 13:000.38 0.077
Di-n-butylphthalate ND mg/kg 1 04/07/10 22:25 84-74-204/01/10 13:000.38 0.062
4,6-Dinitro-2-methylphenol ND mg/kg 1 04/07/10 22:25 534-52-104/01/10 13:000.76 0.076
2,4-Dinitrophenol ND mg/kg 1 04/07/10 22:25 51-28-504/01/10 13:001.9 0.062
2,4-Dinitrotoluene ND mg/kg 1 04/07/10 22:25 121-14-204/01/10 13:000.38 0.071
2,6-Dinitrotoluene ND mg/kg 1 04/07/10 22:25 606-20-204/01/10 13:000.38 0.079
Di-n-octylphthalate ND mg/kg 1 04/07/10 22:25 117-84-004/01/10 13:000.38 0.079
bis(2-Ethylhexyl)phthalate ND mg/kg 1 04/07/10 22:25 117-81-704/01/10 13:000.38 0.10
Fluoranthene ND mg/kg 1 04/07/10 22:25 206-44-004/01/10 13:000.38 0.055
Fluorene ND mg/kg 1 04/07/10 22:25 86-73-704/01/10 13:000.38 0.078
Hexachloro-1,3-butadiene ND mg/kg 1 04/07/10 22:25 87-68-304/01/10 13:000.38 0.066
Hexachlorobenzene ND mg/kg 1 04/07/10 22:25 118-74-104/01/10 13:000.38 0.048
Hexachlorocyclopentadiene ND mg/kg 1 04/07/10 22:25 77-47-404/01/10 13:000.38 0.070
Hexachloroethane ND mg/kg 1 04/07/10 22:25 67-72-104/01/10 13:000.38 0.10
Indeno(1,2,3-cd)pyrene ND mg/kg 1 04/07/10 22:25 193-39-504/01/10 13:000.38 0.078
Isophorone ND mg/kg 1 04/07/10 22:25 78-59-104/01/10 13:000.38 0.085
1-Methylnaphthalene ND mg/kg 1 04/07/10 22:25 90-12-004/01/10 13:000.38 0.099
2-Methylnaphthalene ND mg/kg 1 04/07/10 22:25 91-57-604/01/10 13:000.38 0.082
2-Methylphenol(o-Cresol)ND mg/kg 1 04/07/10 22:25 95-48-704/01/10 13:000.38 0.12
3&4-Methylphenol(m&p Cresol)ND mg/kg 1 04/07/10 22:2504/01/10 13:000.38 0.15
Naphthalene ND mg/kg 1 04/07/10 22:25 91-20-304/01/10 13:000.38 0.093
2-Nitroaniline ND mg/kg 1 04/07/10 22:25 88-74-404/01/10 13:001.9 0.12
3-Nitroaniline ND mg/kg 1 04/07/10 22:25 99-09-204/01/10 13:001.9 0.10
4-Nitroaniline ND mg/kg 1 04/07/10 22:25 100-01-604/01/10 13:000.76 0.11
Nitrobenzene ND mg/kg 1 04/07/10 22:25 98-95-304/01/10 13:000.38 0.10
2-Nitrophenol ND mg/kg 1 04/07/10 22:25 88-75-504/01/10 13:000.38 0.092
4-Nitrophenol ND mg/kg 1 04/07/10 22:25 100-02-704/01/10 13:001.9 0.068
N-Nitrosodimethylamine ND mg/kg 1 04/07/10 22:25 62-75-904/01/10 13:000.38 0.12
N-Nitroso-di-n-propylamine ND mg/kg 1 04/07/10 22:25 621-64-704/01/10 13:000.38 0.073
N-Nitrosodiphenylamine ND mg/kg 1 04/07/10 22:25 86-30-604/01/10 13:000.38 0.11
Pentachlorophenol ND mg/kg 1 04/07/10 22:25 87-86-504/01/10 13:001.9 0.069
Phenanthrene ND mg/kg 1 04/07/10 22:25 85-01-804/01/10 13:000.38 0.063
Phenol ND mg/kg 1 04/07/10 22:25 108-95-204/01/10 13:000.38 0.11
Pyrene ND mg/kg 1 04/07/10 22:25 129-00-004/01/10 13:000.38 0.064
1,2,4-Trichlorobenzene ND mg/kg 1 04/07/10 22:25 120-82-104/01/10 13:000.38 0.074
2,4,5-Trichlorophenol ND mg/kg 1 04/07/10 22:25 95-95-404/01/10 13:000.38 0.12
2,4,6-Trichlorophenol ND mg/kg 1 04/07/10 22:25 88-06-204/01/10 13:000.38 0.084
Nitrobenzene-d5 (S)49 %1 04/07/10 22:25 4165-60-004/01/10 13:0030-120
2-Fluorobiphenyl (S)45 %1 04/07/10 22:25 321-60-804/01/10 13:0030-120
Terphenyl-d14 (S)49 %1 04/07/10 22:25 1718-51-004/01/10 13:0035-108
Phenol-d6 (S)45 %1 04/07/10 22:25 13127-88-304/01/10 13:0035-120
2-Fluorophenol (S)47 %1 04/07/10 22:25 367-12-404/01/10 13:0024-120
2,4,6-Tribromophenol (S)46 %1 04/07/10 22:25 118-79-604/01/10 13:0040-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 23 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-3T 2FT Lab ID:9266446005 Collected:03/30/10 13:00 Received:03/31/10 15:15 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone 0.012J mg/kg 1 04/01/10 15:28 67-64-10.085 0.0085
Benzene ND mg/kg 1 04/01/10 15:28 71-43-20.0043 0.0014
Bromobenzene ND mg/kg 1 04/01/10 15:28 108-86-10.0043 0.0017
Bromochloromethane ND mg/kg 1 04/01/10 15:28 74-97-50.0043 0.0014
Bromodichloromethane ND mg/kg 1 04/01/10 15:28 75-27-40.0043 0.0016
Bromoform ND mg/kg 1 04/01/10 15:28 75-25-20.0043 0.0020
Bromomethane ND mg/kg 1 04/01/10 15:28 74-83-90.0085 0.0021
2-Butanone (MEK)ND mg/kg 1 04/01/10 15:28 78-93-30.085 0.0025
n-Butylbenzene ND mg/kg 1 04/01/10 15:28 104-51-80.0043 0.0015
sec-Butylbenzene ND mg/kg 1 04/01/10 15:28 135-98-80.0043 0.0014
tert-Butylbenzene ND mg/kg 1 04/01/10 15:28 98-06-60.0043 0.0017
Carbon tetrachloride ND mg/kg 1 04/01/10 15:28 56-23-50.0043 0.0022
Chlorobenzene ND mg/kg 1 04/01/10 15:28 108-90-70.0043 0.0016
Chloroethane ND mg/kg 1 04/01/10 15:28 75-00-30.0085 0.0020
Chloroform ND mg/kg 1 04/01/10 15:28 67-66-30.0043 0.0014
Chloromethane ND mg/kg 1 04/01/10 15:28 74-87-30.0085 0.0020
2-Chlorotoluene ND mg/kg 1 04/01/10 15:28 95-49-80.0043 0.0014
4-Chlorotoluene ND mg/kg 1 04/01/10 15:28 106-43-40.0043 0.0015
1,2-Dibromo-3-chloropropane ND mg/kg 1 04/01/10 15:28 96-12-80.0043 0.0031
Dibromochloromethane ND mg/kg 1 04/01/10 15:28 124-48-10.0043 0.0015
1,2-Dibromoethane (EDB)ND mg/kg 1 04/01/10 15:28 106-93-40.0043 0.0015
Dibromomethane ND mg/kg 1 04/01/10 15:28 74-95-30.0043 0.0021
1,2-Dichlorobenzene ND mg/kg 1 04/01/10 15:28 95-50-10.0043 0.0016
1,3-Dichlorobenzene ND mg/kg 1 04/01/10 15:28 541-73-10.0043 0.0017
1,4-Dichlorobenzene ND mg/kg 1 04/01/10 15:28 106-46-70.0043 0.0014
Dichlorodifluoromethane ND mg/kg 1 04/01/10 15:28 75-71-80.0085 0.0031
1,1-Dichloroethane ND mg/kg 1 04/01/10 15:28 75-34-30.0043 0.0013
1,2-Dichloroethane ND mg/kg 1 04/01/10 15:28 107-06-20.0043 0.0019
1,1-Dichloroethene ND mg/kg 1 04/01/10 15:28 75-35-40.0043 0.0015
cis-1,2-Dichloroethene ND mg/kg 1 04/01/10 15:28 156-59-20.0043 0.0012
trans-1,2-Dichloroethene ND mg/kg 1 04/01/10 15:28 156-60-50.0043 0.0016
1,2-Dichloropropane ND mg/kg 1 04/01/10 15:28 78-87-50.0043 0.0014
1,3-Dichloropropane ND mg/kg 1 04/01/10 15:28 142-28-90.0043 0.0016
2,2-Dichloropropane ND mg/kg 1 04/01/10 15:28 594-20-70.0043 0.0014
1,1-Dichloropropene ND mg/kg 1 04/01/10 15:28 563-58-60.0043 0.0013
cis-1,3-Dichloropropene ND mg/kg 1 04/01/10 15:28 10061-01-50.0043 0.0015
trans-1,3-Dichloropropene ND mg/kg 1 04/01/10 15:28 10061-02-60.0043 0.0013
Diisopropyl ether ND mg/kg 1 04/01/10 15:28 108-20-30.0043 0.0014
Ethylbenzene ND mg/kg 1 04/01/10 15:28 100-41-40.0043 0.0015
Hexachloro-1,3-butadiene ND mg/kg 1 04/01/10 15:28 87-68-30.0043 0.0017
2-Hexanone ND mg/kg 1 04/01/10 15:28 591-78-60.043 0.0033
Isopropylbenzene (Cumene)ND mg/kg 1 04/01/10 15:28 98-82-80.0043 0.0016
p-Isopropyltoluene ND mg/kg 1 04/01/10 15:28 99-87-60.0043 0.0014
Methylene Chloride ND mg/kg 1 04/01/10 15:28 75-09-20.017 0.0026
4-Methyl-2-pentanone (MIBK)ND mg/kg 1 04/01/10 15:28 108-10-10.043 0.0032
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 24 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-3T 2FT Lab ID:9266446005 Collected:03/30/10 13:00 Received:03/31/10 15:15 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
8260/5035A Volatile Organics Analytical Method: EPA 8260
Methyl-tert-butyl ether ND mg/kg 1 04/01/10 15:28 1634-04-40.0043 0.0013
Naphthalene ND mg/kg 1 04/01/10 15:28 91-20-30.0043 0.0010
n-Propylbenzene ND mg/kg 1 04/01/10 15:28 103-65-10.0043 0.0014
Styrene ND mg/kg 1 04/01/10 15:28 100-42-50.0043 0.0015
1,1,1,2-Tetrachloroethane ND mg/kg 1 04/01/10 15:28 630-20-60.0043 0.0018
1,1,2,2-Tetrachloroethane ND mg/kg 1 04/01/10 15:28 79-34-50.0043 0.0016
Tetrachloroethene ND mg/kg 1 04/01/10 15:28 127-18-40.0043 0.0014
Toluene ND mg/kg 1 04/01/10 15:28 108-88-30.0043 0.0015
1,2,3-Trichlorobenzene ND mg/kg 1 04/01/10 15:28 87-61-60.0043 0.0019
1,2,4-Trichlorobenzene ND mg/kg 1 04/01/10 15:28 120-82-10.0043 0.0014
1,1,1-Trichloroethane ND mg/kg 1 04/01/10 15:28 71-55-60.0043 0.0015
1,1,2-Trichloroethane ND mg/kg 1 04/01/10 15:28 79-00-50.0043 0.0018
Trichloroethene ND mg/kg 1 04/01/10 15:28 79-01-60.0043 0.0018
Trichlorofluoromethane ND mg/kg 1 04/01/10 15:28 75-69-40.0043 0.0019
1,2,3-Trichloropropane ND mg/kg 1 04/01/10 15:28 96-18-40.0043 0.0014
1,2,4-Trimethylbenzene ND mg/kg 1 04/01/10 15:28 95-63-60.0043 0.0017
1,3,5-Trimethylbenzene ND mg/kg 1 04/01/10 15:28 108-67-80.0043 0.0015
Vinyl acetate ND mg/kg 1 04/01/10 15:28 108-05-40.043 0.0075
Vinyl chloride ND mg/kg 1 04/01/10 15:28 75-01-40.0085 0.0015
Xylene (Total)ND mg/kg 1 04/01/10 15:28 1330-20-70.0085 0.0031
m&p-Xylene ND mg/kg 1 04/01/10 15:28 1330-20-70.0085 0.0031
o-Xylene ND mg/kg 1 04/01/10 15:28 95-47-60.0043 0.0016
Dibromofluoromethane (S)109 %1 04/01/10 15:28 1868-53-779-116
Toluene-d8 (S)103 %1 04/01/10 15:28 2037-26-588-110
4-Bromofluorobenzene (S)89 %1 04/01/10 15:28 460-00-474-115
1,2-Dichloroethane-d4 (S)111 %1 04/01/10 15:28 17060-07-069-121
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 13.1 %1 04/06/10 16:270.10 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 25 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-4T Lab ID:9266446006 Collected:03/30/10 10:45 Received:03/31/10 15:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
MADEP EPH NC Water Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)ND ug/L 1 04/07/10 17:4904/02/10 14:00133133
Aliphatic (C19-C36)ND ug/L 1 04/07/10 17:4904/02/10 14:00133133
Aromatic (C11-C22)ND ug/L 1 04/07/10 02:1904/02/10 14:00133133
Nonatriacontane (S)89 %1 04/07/10 17:49 7194-86-704/02/10 14:0040-140
o-Terphenyl (S)69 %1 04/07/10 02:19 84-15-104/02/10 14:0040-140
2-Fluorobiphenyl (S)97 %1 04/07/10 02:19 321-60-804/02/10 14:0040-140
2-Bromonaphthalene (S)96 %1 04/07/10 02:19 580-13-204/02/10 14:0040-140
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)ND ug/L 1 04/01/10 19:41100100
Aliphatic (C09-C12)ND ug/L 1 04/01/10 19:41100100
Aromatic (C09-C10)ND ug/L 1 04/01/10 19:41100100
2,5-Dibromotoluene (PID)(S)112 %1 04/01/10 19:4170-130
2,5-Dibromotoluene (FID)(S)114 %1 04/01/10 19:4170-130
200.7 MET ICP, 3030C Analytical Method: EPA 200.7 Preparation Method: SM 3030C
Lead 217 ug/L 1 04/07/10 00:38 7439-92-104/01/10 08:005.0 4.0
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
Acenaphthene ND ug/L 1 04/09/10 01:39 83-32-904/01/10 11:005.8 3.3
Acenaphthylene ND ug/L 1 04/09/10 01:39 208-96-804/01/10 11:005.8 3.3
Anthracene ND ug/L 1 04/09/10 01:39 120-12-704/01/10 11:005.8 3.4
Benzo(a)anthracene ND ug/L 1 04/09/10 01:39 56-55-304/01/10 11:005.8 3.3
Benzo(a)pyrene ND ug/L 1 04/09/10 01:39 50-32-804/01/10 11:005.8 3.6
Benzo(b)fluoranthene ND ug/L 1 04/09/10 01:39 205-99-204/01/10 11:005.8 4.2
Benzo(g,h,i)perylene ND ug/L 1 04/09/10 01:39 191-24-204/01/10 11:005.8 3.6
Benzo(k)fluoranthene ND ug/L 1 04/09/10 01:39 207-08-904/01/10 11:005.8 3.5
4-Bromophenylphenyl ether ND ug/L 1 04/09/10 01:39 101-55-304/01/10 11:005.8 2.8
Butylbenzylphthalate ND ug/L 1 04/09/10 01:39 85-68-704/01/10 11:005.8 3.4
4-Chloro-3-methylphenol ND ug/L 1 04/09/10 01:39 59-50-704/01/10 11:005.8 3.3
bis(2-Chloroethoxy)methane ND ug/L 1 04/09/10 01:39 111-91-104/01/10 11:0011.6 6.7
bis(2-Chloroethyl) ether ND ug/L 1 04/09/10 01:39 111-44-404/01/10 11:005.8 5.6
bis(2-Chloroisopropyl) ether ND ug/L 1 04/09/10 01:39 108-60-104/01/10 11:005.8 4.7
2-Chloronaphthalene ND ug/L 1 04/09/10 01:39 91-58-704/01/10 11:005.8 4.2
2-Chlorophenol ND ug/L 1 04/09/10 01:39 95-57-804/01/10 11:005.8 5.1
4-Chlorophenylphenyl ether ND ug/L 1 04/09/10 01:39 7005-72-304/01/10 11:005.8 3.1
Chrysene ND ug/L 1 04/09/10 01:39 218-01-904/01/10 11:005.8 3.1
Dibenz(a,h)anthracene ND ug/L 1 04/09/10 01:39 53-70-304/01/10 11:005.8 3.4
3,3'-Dichlorobenzidine ND ug/L 1 04/09/10 01:39 91-94-104/01/10 11:005.8 4.0
2,4-Dichlorophenol ND ug/L 1 04/09/10 01:39 120-83-204/01/10 11:005.8 4.8
Diethylphthalate ND ug/L 1 04/09/10 01:39 84-66-204/01/10 11:005.8 3.1
2,4-Dimethylphenol ND ug/L 1 04/09/10 01:39 105-67-904/01/10 11:0011.6 6.5
Dimethylphthalate ND ug/L 1 04/09/10 01:39 131-11-304/01/10 11:005.8 2.8
Di-n-butylphthalate ND ug/L 1 04/09/10 01:39 84-74-204/01/10 11:005.8 3.4
4,6-Dinitro-2-methylphenol ND ug/L 1 04/09/10 01:39 534-52-104/01/10 11:0023.3 9.1
2,4-Dinitrophenol ND ug/L 1 04/09/10 01:39 51-28-504/01/10 11:0058.1 11.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 26 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-4T Lab ID:9266446006 Collected:03/30/10 10:45 Received:03/31/10 15:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
2,4-Dinitrotoluene ND ug/L 1 04/09/10 01:39 121-14-204/01/10 11:005.8 3.0
2,6-Dinitrotoluene ND ug/L 1 04/09/10 01:39 606-20-204/01/10 11:005.8 3.3
Di-n-octylphthalate ND ug/L 1 04/09/10 01:39 117-84-004/01/10 11:005.8 3.4
bis(2-Ethylhexyl)phthalate ND ug/L 1 04/09/10 01:39 117-81-704/01/10 11:005.8 2.4
Fluoranthene ND ug/L 1 04/09/10 01:39 206-44-004/01/10 11:005.8 3.4
Fluorene ND ug/L 1 04/09/10 01:39 86-73-704/01/10 11:005.8 3.0
Hexachloro-1,3-butadiene ND ug/L 1 04/09/10 01:39 87-68-304/01/10 11:005.8 3.8
Hexachlorobenzene ND ug/L 1 04/09/10 01:39 118-74-104/01/10 11:005.8 3.0
Hexachlorocyclopentadiene ND ug/L 1 04/09/10 01:39 77-47-404/01/10 11:0011.6 4.3
Hexachloroethane ND ug/L 1 04/09/10 01:39 67-72-104/01/10 11:005.8 3.8
Indeno(1,2,3-cd)pyrene ND ug/L 1 04/09/10 01:39 193-39-504/01/10 11:005.8 3.5
Isophorone ND ug/L 1 04/09/10 01:39 78-59-104/01/10 11:0011.6 7.6
2-Methylnaphthalene ND ug/L 1 04/09/10 01:39 91-57-604/01/10 11:005.8 4.0
Naphthalene ND ug/L 1 04/09/10 01:39 91-20-304/01/10 11:005.8 4.4
Nitrobenzene ND ug/L 1 04/09/10 01:39 98-95-304/01/10 11:005.8 5.1
2-Nitrophenol ND ug/L 1 04/09/10 01:39 88-75-504/01/10 11:005.8 5.3
4-Nitrophenol ND ug/L 1 04/09/10 01:39 100-02-704/01/10 11:0058.1 2.3
N-Nitrosodimethylamine ND ug/L 1 04/09/10 01:39 62-75-904/01/10 11:005.8 3.6
N-Nitroso-di-n-propylamine ND ug/L 1 04/09/10 01:39 621-64-704/01/10 11:005.8 4.3
N-Nitrosodiphenylamine ND ug/L 1 04/09/10 01:39 86-30-604/01/10 11:0011.6 7.7
Pentachlorophenol ND ug/L 1 04/09/10 01:39 87-86-504/01/10 11:0029.1 1.9
Phenanthrene ND ug/L 1 04/09/10 01:39 85-01-804/01/10 11:005.8 3.1
Phenol ND ug/L 1 04/09/10 01:39 108-95-204/01/10 11:005.8 2.1
Pyrene ND ug/L 1 04/09/10 01:39 129-00-004/01/10 11:005.8 3.4
1,2,4-Trichlorobenzene ND ug/L 1 04/09/10 01:39 120-82-104/01/10 11:005.8 4.0
2,4,6-Trichlorophenol ND ug/L 1 04/09/10 01:39 88-06-204/01/10 11:0011.6 7.1
Nitrobenzene-d5 (S)76 %1 04/09/10 01:39 4165-60-004/01/10 11:0010-120
2-Fluorobiphenyl (S)75 %1 04/09/10 01:39 321-60-804/01/10 11:0015-120
Terphenyl-d14 (S)104 %1 04/09/10 01:39 1718-51-004/01/10 11:0011-131
Phenol-d6 (S)27 %1 04/09/10 01:39 13127-88-304/01/10 11:0010-120
2-Fluorophenol (S)43 %1 04/09/10 01:39 367-12-404/01/10 11:0010-120
2,4,6-Tribromophenol (S)89 %1 04/09/10 01:39 118-79-604/01/10 11:0010-137
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 04/02/10 03:10 71-43-20.50 0.50
Bromobenzene ND ug/L 1 04/02/10 03:10 108-86-10.50 0.50
Bromochloromethane ND ug/L 1 04/02/10 03:10 74-97-50.50 0.50
Bromodichloromethane ND ug/L 1 04/02/10 03:10 75-27-40.50 0.50
Bromoform ND ug/L 1 04/02/10 03:10 75-25-20.50 0.50
Bromomethane ND ug/L 1 04/02/10 03:10 74-83-95.0 1.0
n-Butylbenzene ND ug/L 1 04/02/10 03:10 104-51-80.50 0.50
sec-Butylbenzene ND ug/L 1 04/02/10 03:10 135-98-80.50 0.50
tert-Butylbenzene ND ug/L 1 04/02/10 03:10 98-06-60.50 0.50
Carbon tetrachloride ND ug/L 1 04/02/10 03:10 56-23-50.50 0.50
Chlorobenzene ND ug/L 1 04/02/10 03:10 108-90-70.50 0.50
Chloroethane ND ug/L 1 04/02/10 03:10 75-00-31.0 1.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 27 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-4T Lab ID:9266446006 Collected:03/30/10 10:45 Received:03/31/10 15:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
Chloroform ND ug/L 1 04/02/10 03:10 67-66-30.50 0.50
Chloromethane ND ug/L 1 04/02/10 03:10 74-87-31.0 1.0
2-Chlorotoluene ND ug/L 1 04/02/10 03:10 95-49-80.50 0.50
4-Chlorotoluene ND ug/L 1 04/02/10 03:10 106-43-40.50 0.50
1,2-Dibromo-3-chloropropane ND ug/L 1 04/02/10 03:10 96-12-81.0 1.0
Dibromochloromethane ND ug/L 1 04/02/10 03:10 124-48-10.50 0.50
1,2-Dibromoethane (EDB)ND ug/L 1 04/02/10 03:10 106-93-40.50 0.50
Dibromomethane ND ug/L 1 04/02/10 03:10 74-95-30.50 0.50
1,2-Dichlorobenzene ND ug/L 1 04/02/10 03:10 95-50-10.50 0.50
1,3-Dichlorobenzene ND ug/L 1 04/02/10 03:10 541-73-10.50 0.50
1,4-Dichlorobenzene ND ug/L 1 04/02/10 03:10 106-46-70.50 0.50
Dichlorodifluoromethane ND ug/L 1 04/02/10 03:10 75-71-80.50 0.50
1,1-Dichloroethane ND ug/L 1 04/02/10 03:10 75-34-30.50 0.50
1,2-Dichloroethane 0.58 ug/L 1 04/02/10 03:10 107-06-20.50 0.50
1,1-Dichloroethene ND ug/L 1 04/02/10 03:10 75-35-40.50 0.50
cis-1,2-Dichloroethene ND ug/L 1 04/02/10 03:10 156-59-20.50 0.50
trans-1,2-Dichloroethene ND ug/L 1 04/02/10 03:10 156-60-50.50 0.50
1,2-Dichloropropane ND ug/L 1 04/02/10 03:10 78-87-50.50 0.50
1,3-Dichloropropane ND ug/L 1 04/02/10 03:10 142-28-90.50 0.50
2,2-Dichloropropane ND ug/L 1 04/02/10 03:10 594-20-70.50 0.50
1,1-Dichloropropene ND ug/L 1 04/02/10 03:10 563-58-60.50 0.50
cis-1,3-Dichloropropene ND ug/L 1 04/02/10 03:10 10061-01-50.50 0.50
trans-1,3-Dichloropropene ND ug/L 1 04/02/10 03:10 10061-02-60.50 0.50
Diisopropyl ether ND ug/L 1 04/02/10 03:10 108-20-30.50 0.50
Ethylbenzene ND ug/L 1 04/02/10 03:10 100-41-40.50 0.50
Hexachloro-1,3-butadiene ND ug/L 1 04/02/10 03:10 87-68-32.0 2.0
Isopropylbenzene (Cumene)ND ug/L 1 04/02/10 03:10 98-82-80.50 0.50
Methylene Chloride ND ug/L 1 04/02/10 03:10 75-09-22.0 2.0
Methyl-tert-butyl ether ND ug/L 1 04/02/10 03:10 1634-04-40.50 0.50
Naphthalene ND ug/L 1 04/02/10 03:10 91-20-32.0 2.0
n-Propylbenzene ND ug/L 1 04/02/10 03:10 103-65-10.50 0.50
Styrene ND ug/L 1 04/02/10 03:10 100-42-50.50 0.50
1,1,1,2-Tetrachloroethane ND ug/L 1 04/02/10 03:10 630-20-60.50 0.50
1,1,2,2-Tetrachloroethane ND ug/L 1 04/02/10 03:10 79-34-50.50 0.50
Tetrachloroethene ND ug/L 1 04/02/10 03:10 127-18-40.50 0.50
Toluene ND ug/L 1 04/02/10 03:10 108-88-30.50 0.50
1,2,3-Trichlorobenzene ND ug/L 1 04/02/10 03:10 87-61-62.0 2.0
1,2,4-Trichlorobenzene ND ug/L 1 04/02/10 03:10 120-82-12.0 2.0
1,1,1-Trichloroethane ND ug/L 1 04/02/10 03:10 71-55-60.50 0.50
1,1,2-Trichloroethane ND ug/L 1 04/02/10 03:10 79-00-50.50 0.50
Trichloroethene ND ug/L 1 04/02/10 03:10 79-01-60.50 0.50
Trichlorofluoromethane ND ug/L 1 04/02/10 03:10 75-69-41.0 1.0
1,2,3-Trichloropropane ND ug/L 1 04/02/10 03:10 96-18-40.50 0.50
1,2,4-Trimethylbenzene ND ug/L 1 04/02/10 03:10 95-63-60.50 0.50
1,3,5-Trimethylbenzene ND ug/L 1 04/02/10 03:10 108-67-80.50 0.50
Vinyl chloride ND ug/L 1 04/02/10 03:10 75-01-41.0 1.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 28 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-4T Lab ID:9266446006 Collected:03/30/10 10:45 Received:03/31/10 15:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
m&p-Xylene ND ug/L 1 04/02/10 03:10 1330-20-71.0 1.0
o-Xylene ND ug/L 1 04/02/10 03:10 95-47-60.50 0.50
1,2-Dichloroethane-d4 (S)104 %1 04/02/10 03:10 17060-07-070-130
Dibromofluoromethane (S)103 %1 04/02/10 03:10 1868-53-770-130
4-Bromofluorobenzene (S)94 %1 04/02/10 03:10 460-00-470-130
Toluene-d8 (S)99 %1 04/02/10 03:10 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 29 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-5T Lab ID:9266446007 Collected:03/30/10 11:15 Received:03/31/10 15:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
MADEP EPH NC Water Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)9230 ug/L 10 04/08/10 09:4004/02/10 14:0014301430
Aliphatic (C19-C36)2330 ug/L 10 04/08/10 09:4004/02/10 14:0014301430
Aromatic (C11-C22)6510 ug/L 2 04/08/10 09:4004/02/10 14:00286286
Nonatriacontane (S)0 %10 04/08/10 09:40 7194-86-7 S404/02/10 14:0040-140
o-Terphenyl (S)189 %2 04/08/10 09:40 84-15-1 S504/02/10 14:0040-140
2-Fluorobiphenyl (S)205 %2 04/08/10 09:40 321-60-8 S504/02/10 14:0040-140
2-Bromonaphthalene (S)235 %2 04/08/10 09:40 580-13-2 S504/02/10 14:0040-140
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)ND ug/L 1 04/01/10 20:06100100
Aliphatic (C09-C12)236 ug/L 1 04/01/10 20:06100100
Aromatic (C09-C10)129 ug/L 1 04/01/10 20:06100100
2,5-Dibromotoluene (PID)(S)115 %1 04/01/10 20:0670-130
2,5-Dibromotoluene (FID)(S)147 %1 04/01/10 20:06 S570-130
200.7 MET ICP, 3030C Analytical Method: EPA 200.7 Preparation Method: SM 3030C
Lead 1040 ug/L 5 04/07/10 12:05 7439-92-1 D304/01/10 08:0025.0 20.0
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
Acenaphthene ND ug/L 1 04/09/10 02:03 83-32-904/01/10 11:006.2 3.5
Acenaphthylene ND ug/L 1 04/09/10 02:03 208-96-804/01/10 11:006.2 3.5
Anthracene ND ug/L 1 04/09/10 02:03 120-12-704/01/10 11:006.2 3.6
Benzo(a)anthracene ND ug/L 1 04/09/10 02:03 56-55-304/01/10 11:006.2 3.5
Benzo(a)pyrene ND ug/L 1 04/09/10 02:03 50-32-804/01/10 11:006.2 3.8
Benzo(b)fluoranthene ND ug/L 1 04/09/10 02:03 205-99-204/01/10 11:006.2 4.4
Benzo(g,h,i)perylene ND ug/L 1 04/09/10 02:03 191-24-204/01/10 11:006.2 3.8
Benzo(k)fluoranthene ND ug/L 1 04/09/10 02:03 207-08-904/01/10 11:006.2 3.7
4-Bromophenylphenyl ether ND ug/L 1 04/09/10 02:03 101-55-304/01/10 11:006.2 3.0
Butylbenzylphthalate ND ug/L 1 04/09/10 02:03 85-68-704/01/10 11:006.2 3.6
4-Chloro-3-methylphenol ND ug/L 1 04/09/10 02:03 59-50-704/01/10 11:006.2 3.5
bis(2-Chloroethoxy)methane ND ug/L 1 04/09/10 02:03 111-91-104/01/10 11:0012.3 7.2
bis(2-Chloroethyl) ether ND ug/L 1 04/09/10 02:03 111-44-404/01/10 11:006.2 5.9
bis(2-Chloroisopropyl) ether ND ug/L 1 04/09/10 02:03 108-60-104/01/10 11:006.2 4.9
2-Chloronaphthalene ND ug/L 1 04/09/10 02:03 91-58-704/01/10 11:006.2 4.4
2-Chlorophenol ND ug/L 1 04/09/10 02:03 95-57-804/01/10 11:006.2 5.4
4-Chlorophenylphenyl ether ND ug/L 1 04/09/10 02:03 7005-72-304/01/10 11:006.2 3.3
Chrysene ND ug/L 1 04/09/10 02:03 218-01-904/01/10 11:006.2 3.3
Dibenz(a,h)anthracene ND ug/L 1 04/09/10 02:03 53-70-304/01/10 11:006.2 3.6
3,3'-Dichlorobenzidine ND ug/L 1 04/09/10 02:03 91-94-104/01/10 11:006.2 4.2
2,4-Dichlorophenol ND ug/L 1 04/09/10 02:03 120-83-204/01/10 11:006.2 5.1
Diethylphthalate ND ug/L 1 04/09/10 02:03 84-66-204/01/10 11:006.2 3.3
2,4-Dimethylphenol ND ug/L 1 04/09/10 02:03 105-67-904/01/10 11:0012.3 6.9
Dimethylphthalate ND ug/L 1 04/09/10 02:03 131-11-304/01/10 11:006.2 3.0
Di-n-butylphthalate ND ug/L 1 04/09/10 02:03 84-74-204/01/10 11:006.2 3.6
4,6-Dinitro-2-methylphenol ND ug/L 1 04/09/10 02:03 534-52-104/01/10 11:0024.7 9.6
2,4-Dinitrophenol ND ug/L 1 04/09/10 02:03 51-28-504/01/10 11:0061.7 12.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 30 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-5T Lab ID:9266446007 Collected:03/30/10 11:15 Received:03/31/10 15:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
2,4-Dinitrotoluene ND ug/L 1 04/09/10 02:03 121-14-204/01/10 11:006.2 3.2
2,6-Dinitrotoluene ND ug/L 1 04/09/10 02:03 606-20-204/01/10 11:006.2 3.5
Di-n-octylphthalate ND ug/L 1 04/09/10 02:03 117-84-004/01/10 11:006.2 3.6
bis(2-Ethylhexyl)phthalate ND ug/L 1 04/09/10 02:03 117-81-704/01/10 11:006.2 2.6
Fluoranthene ND ug/L 1 04/09/10 02:03 206-44-004/01/10 11:006.2 3.6
Fluorene 5.4J ug/L 1 04/09/10 02:03 86-73-704/01/10 11:006.2 3.2
Hexachloro-1,3-butadiene ND ug/L 1 04/09/10 02:03 87-68-304/01/10 11:006.2 4.1
Hexachlorobenzene ND ug/L 1 04/09/10 02:03 118-74-104/01/10 11:006.2 3.2
Hexachlorocyclopentadiene ND ug/L 1 04/09/10 02:03 77-47-404/01/10 11:0012.3 4.6
Hexachloroethane ND ug/L 1 04/09/10 02:03 67-72-104/01/10 11:006.2 4.1
Indeno(1,2,3-cd)pyrene ND ug/L 1 04/09/10 02:03 193-39-504/01/10 11:006.2 3.7
Isophorone ND ug/L 1 04/09/10 02:03 78-59-104/01/10 11:0012.3 8.0
2-Methylnaphthalene 42.6 ug/L 1 04/09/10 02:03 91-57-604/01/10 11:006.2 4.2
Naphthalene 5.5J ug/L 1 04/09/10 02:03 91-20-304/01/10 11:006.2 4.7
Nitrobenzene ND ug/L 1 04/09/10 02:03 98-95-304/01/10 11:006.2 5.4
2-Nitrophenol ND ug/L 1 04/09/10 02:03 88-75-504/01/10 11:006.2 5.7
4-Nitrophenol ND ug/L 1 04/09/10 02:03 100-02-704/01/10 11:0061.7 2.5
N-Nitrosodimethylamine ND ug/L 1 04/09/10 02:03 62-75-904/01/10 11:006.2 3.8
N-Nitroso-di-n-propylamine ND ug/L 1 04/09/10 02:03 621-64-704/01/10 11:006.2 4.6
N-Nitrosodiphenylamine ND ug/L 1 04/09/10 02:03 86-30-604/01/10 11:0012.3 8.1
Pentachlorophenol ND ug/L 1 04/09/10 02:03 87-86-504/01/10 11:0030.9 2.0
Phenanthrene 8.6 ug/L 1 04/09/10 02:03 85-01-804/01/10 11:006.2 3.3
Phenol ND ug/L 1 04/09/10 02:03 108-95-204/01/10 11:006.2 2.2
Pyrene ND ug/L 1 04/09/10 02:03 129-00-004/01/10 11:006.2 3.6
1,2,4-Trichlorobenzene ND ug/L 1 04/09/10 02:03 120-82-104/01/10 11:006.2 4.2
2,4,6-Trichlorophenol ND ug/L 1 04/09/10 02:03 88-06-204/01/10 11:0012.3 7.5
Nitrobenzene-d5 (S)36 %1 04/09/10 02:03 4165-60-004/01/10 11:0010-120
2-Fluorobiphenyl (S)40 %1 04/09/10 02:03 321-60-804/01/10 11:0015-120
Terphenyl-d14 (S)62 %1 04/09/10 02:03 1718-51-004/01/10 11:0011-131
Phenol-d6 (S)14 %1 04/09/10 02:03 13127-88-304/01/10 11:0010-120
2-Fluorophenol (S)19 %1 04/09/10 02:03 367-12-404/01/10 11:0010-120
2,4,6-Tribromophenol (S)52 %1 04/09/10 02:03 118-79-604/01/10 11:0010-137
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 04/02/10 16:22 71-43-20.50 0.50
Bromobenzene ND ug/L 1 04/02/10 16:22 108-86-10.50 0.50
Bromochloromethane ND ug/L 1 04/02/10 16:22 74-97-50.50 0.50
Bromodichloromethane ND ug/L 1 04/02/10 16:22 75-27-40.50 0.50
Bromoform ND ug/L 1 04/02/10 16:22 75-25-20.50 0.50
Bromomethane ND ug/L 1 04/02/10 16:22 74-83-95.0 1.0
n-Butylbenzene ND ug/L 1 04/02/10 16:22 104-51-80.50 0.50
sec-Butylbenzene 3.0 ug/L 1 04/02/10 16:22 135-98-80.50 0.50
tert-Butylbenzene ND ug/L 1 04/02/10 16:22 98-06-60.50 0.50
Carbon tetrachloride ND ug/L 1 04/02/10 16:22 56-23-50.50 0.50
Chlorobenzene ND ug/L 1 04/02/10 16:22 108-90-70.50 0.50
Chloroethane ND ug/L 1 04/02/10 16:22 75-00-31.0 1.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 31 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-5T Lab ID:9266446007 Collected:03/30/10 11:15 Received:03/31/10 15:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
Chloroform ND ug/L 1 04/02/10 16:22 67-66-30.50 0.50
Chloromethane ND ug/L 1 04/02/10 16:22 74-87-31.0 1.0
2-Chlorotoluene ND ug/L 1 04/02/10 16:22 95-49-80.50 0.50
4-Chlorotoluene ND ug/L 1 04/02/10 16:22 106-43-40.50 0.50
1,2-Dibromo-3-chloropropane ND ug/L 1 04/02/10 16:22 96-12-81.0 1.0
Dibromochloromethane ND ug/L 1 04/02/10 16:22 124-48-10.50 0.50
1,2-Dibromoethane (EDB)ND ug/L 1 04/02/10 16:22 106-93-40.50 0.50
Dibromomethane ND ug/L 1 04/02/10 16:22 74-95-30.50 0.50
1,2-Dichlorobenzene ND ug/L 1 04/02/10 16:22 95-50-10.50 0.50
1,3-Dichlorobenzene ND ug/L 1 04/02/10 16:22 541-73-10.50 0.50
1,4-Dichlorobenzene ND ug/L 1 04/02/10 16:22 106-46-70.50 0.50
Dichlorodifluoromethane ND ug/L 1 04/02/10 16:22 75-71-80.50 0.50
1,1-Dichloroethane ND ug/L 1 04/02/10 16:22 75-34-30.50 0.50
1,2-Dichloroethane ND ug/L 1 04/02/10 16:22 107-06-20.50 0.50
1,1-Dichloroethene ND ug/L 1 04/02/10 16:22 75-35-40.50 0.50
cis-1,2-Dichloroethene ND ug/L 1 04/02/10 16:22 156-59-20.50 0.50
trans-1,2-Dichloroethene ND ug/L 1 04/02/10 16:22 156-60-50.50 0.50
1,2-Dichloropropane ND ug/L 1 04/02/10 16:22 78-87-50.50 0.50
1,3-Dichloropropane ND ug/L 1 04/02/10 16:22 142-28-90.50 0.50
2,2-Dichloropropane ND ug/L 1 04/02/10 16:22 594-20-70.50 0.50
1,1-Dichloropropene ND ug/L 1 04/02/10 16:22 563-58-60.50 0.50
cis-1,3-Dichloropropene ND ug/L 1 04/02/10 16:22 10061-01-50.50 0.50
trans-1,3-Dichloropropene ND ug/L 1 04/02/10 16:22 10061-02-60.50 0.50
Diisopropyl ether ND ug/L 1 04/02/10 16:22 108-20-30.50 0.50
Ethylbenzene ND ug/L 1 04/02/10 16:22 100-41-40.50 0.50
Hexachloro-1,3-butadiene ND ug/L 1 04/02/10 16:22 87-68-32.0 2.0
Isopropylbenzene (Cumene)ND ug/L 1 04/02/10 16:22 98-82-80.50 0.50
Methylene Chloride ND ug/L 1 04/02/10 16:22 75-09-22.0 2.0
Methyl-tert-butyl ether ND ug/L 1 04/02/10 16:22 1634-04-40.50 0.50
Naphthalene 12.7 ug/L 1 04/02/10 16:22 91-20-32.0 2.0
n-Propylbenzene 0.59 ug/L 1 04/02/10 16:22 103-65-10.50 0.50
Styrene ND ug/L 1 04/02/10 16:22 100-42-50.50 0.50
1,1,1,2-Tetrachloroethane ND ug/L 1 04/02/10 16:22 630-20-60.50 0.50
1,1,2,2-Tetrachloroethane ND ug/L 1 04/02/10 16:22 79-34-50.50 0.50
Tetrachloroethene ND ug/L 1 04/02/10 16:22 127-18-40.50 0.50
Toluene ND ug/L 1 04/02/10 16:22 108-88-30.50 0.50
1,2,3-Trichlorobenzene ND ug/L 1 04/02/10 16:22 87-61-62.0 2.0
1,2,4-Trichlorobenzene ND ug/L 1 04/02/10 16:22 120-82-12.0 2.0
1,1,1-Trichloroethane ND ug/L 1 04/02/10 16:22 71-55-60.50 0.50
1,1,2-Trichloroethane ND ug/L 1 04/02/10 16:22 79-00-50.50 0.50
Trichloroethene ND ug/L 1 04/02/10 16:22 79-01-60.50 0.50
Trichlorofluoromethane ND ug/L 1 04/02/10 16:22 75-69-41.0 1.0
1,2,3-Trichloropropane ND ug/L 1 04/02/10 16:22 96-18-40.50 0.50
1,2,4-Trimethylbenzene 1.8 ug/L 1 04/02/10 16:22 95-63-60.50 0.50
1,3,5-Trimethylbenzene ND ug/L 1 04/02/10 16:22 108-67-80.50 0.50
Vinyl chloride ND ug/L 1 04/02/10 16:22 75-01-41.0 1.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 32 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-5T Lab ID:9266446007 Collected:03/30/10 11:15 Received:03/31/10 15:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
m&p-Xylene ND ug/L 1 04/02/10 16:22 1330-20-71.0 1.0
o-Xylene ND ug/L 1 04/02/10 16:22 95-47-60.50 0.50
1,2-Dichloroethane-d4 (S)105 %1 04/02/10 16:22 17060-07-070-130
Dibromofluoromethane (S)102 %1 04/02/10 16:22 1868-53-770-130
4-Bromofluorobenzene (S)96 %1 04/02/10 16:22 460-00-470-130
Toluene-d8 (S)99 %1 04/02/10 16:22 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 33 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-6T Lab ID:9266446008 Collected:03/30/10 11:45 Received:03/31/10 15:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
MADEP EPH NC Water Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)ND ug/L 1 04/07/10 19:0104/02/10 14:00133133
Aliphatic (C19-C36)ND ug/L 1 04/07/10 19:0104/02/10 14:00133133
Aromatic (C11-C22)ND ug/L 1 04/07/10 03:3104/02/10 14:00133133
Nonatriacontane (S)85 %1 04/07/10 19:01 7194-86-704/02/10 14:0040-140
o-Terphenyl (S)67 %1 04/07/10 03:31 84-15-104/02/10 14:0040-140
2-Fluorobiphenyl (S)93 %1 04/07/10 03:31 321-60-804/02/10 14:0040-140
2-Bromonaphthalene (S)96 %1 04/07/10 03:31 580-13-204/02/10 14:0040-140
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)ND ug/L 1 04/01/10 20:31100100
Aliphatic (C09-C12)ND ug/L 1 04/01/10 20:31100100
Aromatic (C09-C10)ND ug/L 1 04/01/10 20:31100100
2,5-Dibromotoluene (PID)(S)114 %1 04/01/10 20:3170-130
2,5-Dibromotoluene (FID)(S)134 %1 04/01/10 20:31 S370-130
200.7 MET ICP, 3030C Analytical Method: EPA 200.7 Preparation Method: SM 3030C
Lead 646 ug/L 1 04/07/10 00:52 7439-92-104/01/10 08:005.0 4.0
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
Acenaphthene ND ug/L 1 04/09/10 02:28 83-32-904/01/10 11:005.7 3.2
Acenaphthylene ND ug/L 1 04/09/10 02:28 208-96-804/01/10 11:005.7 3.2
Anthracene ND ug/L 1 04/09/10 02:28 120-12-704/01/10 11:005.7 3.3
Benzo(a)anthracene ND ug/L 1 04/09/10 02:28 56-55-304/01/10 11:005.7 3.2
Benzo(a)pyrene ND ug/L 1 04/09/10 02:28 50-32-804/01/10 11:005.7 3.6
Benzo(b)fluoranthene ND ug/L 1 04/09/10 02:28 205-99-204/01/10 11:005.7 4.1
Benzo(g,h,i)perylene ND ug/L 1 04/09/10 02:28 191-24-204/01/10 11:005.7 3.6
Benzo(k)fluoranthene ND ug/L 1 04/09/10 02:28 207-08-904/01/10 11:005.7 3.4
4-Bromophenylphenyl ether ND ug/L 1 04/09/10 02:28 101-55-304/01/10 11:005.7 2.8
Butylbenzylphthalate ND ug/L 1 04/09/10 02:28 85-68-704/01/10 11:005.7 3.3
4-Chloro-3-methylphenol ND ug/L 1 04/09/10 02:28 59-50-704/01/10 11:005.7 3.2
bis(2-Chloroethoxy)methane ND ug/L 1 04/09/10 02:28 111-91-104/01/10 11:0011.5 6.7
bis(2-Chloroethyl) ether ND ug/L 1 04/09/10 02:28 111-44-404/01/10 11:005.7 5.5
bis(2-Chloroisopropyl) ether ND ug/L 1 04/09/10 02:28 108-60-104/01/10 11:005.7 4.6
2-Chloronaphthalene ND ug/L 1 04/09/10 02:28 91-58-704/01/10 11:005.7 4.1
2-Chlorophenol ND ug/L 1 04/09/10 02:28 95-57-804/01/10 11:005.7 5.1
4-Chlorophenylphenyl ether ND ug/L 1 04/09/10 02:28 7005-72-304/01/10 11:005.7 3.1
Chrysene ND ug/L 1 04/09/10 02:28 218-01-904/01/10 11:005.7 3.1
Dibenz(a,h)anthracene ND ug/L 1 04/09/10 02:28 53-70-304/01/10 11:005.7 3.3
3,3'-Dichlorobenzidine ND ug/L 1 04/09/10 02:28 91-94-104/01/10 11:005.7 3.9
2,4-Dichlorophenol ND ug/L 1 04/09/10 02:28 120-83-204/01/10 11:005.7 4.7
Diethylphthalate ND ug/L 1 04/09/10 02:28 84-66-204/01/10 11:005.7 3.1
2,4-Dimethylphenol ND ug/L 1 04/09/10 02:28 105-67-904/01/10 11:0011.5 6.4
Dimethylphthalate ND ug/L 1 04/09/10 02:28 131-11-304/01/10 11:005.7 2.8
Di-n-butylphthalate ND ug/L 1 04/09/10 02:28 84-74-204/01/10 11:005.7 3.3
4,6-Dinitro-2-methylphenol ND ug/L 1 04/09/10 02:28 534-52-104/01/10 11:0023.0 9.0
2,4-Dinitrophenol ND ug/L 1 04/09/10 02:28 51-28-504/01/10 11:0057.5 11.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 34 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-6T Lab ID:9266446008 Collected:03/30/10 11:45 Received:03/31/10 15:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
2,4-Dinitrotoluene ND ug/L 1 04/09/10 02:28 121-14-204/01/10 11:005.7 3.0
2,6-Dinitrotoluene ND ug/L 1 04/09/10 02:28 606-20-204/01/10 11:005.7 3.2
Di-n-octylphthalate ND ug/L 1 04/09/10 02:28 117-84-004/01/10 11:005.7 3.3
bis(2-Ethylhexyl)phthalate ND ug/L 1 04/09/10 02:28 117-81-704/01/10 11:005.7 2.4
Fluoranthene ND ug/L 1 04/09/10 02:28 206-44-004/01/10 11:005.7 3.3
Fluorene ND ug/L 1 04/09/10 02:28 86-73-704/01/10 11:005.7 3.0
Hexachloro-1,3-butadiene ND ug/L 1 04/09/10 02:28 87-68-304/01/10 11:005.7 3.8
Hexachlorobenzene ND ug/L 1 04/09/10 02:28 118-74-104/01/10 11:005.7 3.0
Hexachlorocyclopentadiene ND ug/L 1 04/09/10 02:28 77-47-404/01/10 11:0011.5 4.3
Hexachloroethane ND ug/L 1 04/09/10 02:28 67-72-104/01/10 11:005.7 3.8
Indeno(1,2,3-cd)pyrene ND ug/L 1 04/09/10 02:28 193-39-504/01/10 11:005.7 3.4
Isophorone ND ug/L 1 04/09/10 02:28 78-59-104/01/10 11:0011.5 7.5
2-Methylnaphthalene ND ug/L 1 04/09/10 02:28 91-57-604/01/10 11:005.7 3.9
Naphthalene ND ug/L 1 04/09/10 02:28 91-20-304/01/10 11:005.7 4.4
Nitrobenzene ND ug/L 1 04/09/10 02:28 98-95-304/01/10 11:005.7 5.1
2-Nitrophenol ND ug/L 1 04/09/10 02:28 88-75-504/01/10 11:005.7 5.3
4-Nitrophenol ND ug/L 1 04/09/10 02:28 100-02-704/01/10 11:0057.5 2.3
N-Nitrosodimethylamine ND ug/L 1 04/09/10 02:28 62-75-904/01/10 11:005.7 3.6
N-Nitroso-di-n-propylamine ND ug/L 1 04/09/10 02:28 621-64-704/01/10 11:005.7 4.3
N-Nitrosodiphenylamine ND ug/L 1 04/09/10 02:28 86-30-604/01/10 11:0011.5 7.6
Pentachlorophenol ND ug/L 1 04/09/10 02:28 87-86-504/01/10 11:0028.7 1.8
Phenanthrene ND ug/L 1 04/09/10 02:28 85-01-804/01/10 11:005.7 3.1
Phenol ND ug/L 1 04/09/10 02:28 108-95-204/01/10 11:005.7 2.1
Pyrene ND ug/L 1 04/09/10 02:28 129-00-004/01/10 11:005.7 3.3
1,2,4-Trichlorobenzene ND ug/L 1 04/09/10 02:28 120-82-104/01/10 11:005.7 3.9
2,4,6-Trichlorophenol ND ug/L 1 04/09/10 02:28 88-06-204/01/10 11:0011.5 7.0
Nitrobenzene-d5 (S)76 %1 04/09/10 02:28 4165-60-004/01/10 11:0010-120
2-Fluorobiphenyl (S)70 %1 04/09/10 02:28 321-60-804/01/10 11:0015-120
Terphenyl-d14 (S)103 %1 04/09/10 02:28 1718-51-004/01/10 11:0011-131
Phenol-d6 (S)28 %1 04/09/10 02:28 13127-88-304/01/10 11:0010-120
2-Fluorophenol (S)45 %1 04/09/10 02:28 367-12-404/01/10 11:0010-120
2,4,6-Tribromophenol (S)95 %1 04/09/10 02:28 118-79-604/01/10 11:0010-137
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 04/02/10 03:32 71-43-20.50 0.50
Bromobenzene ND ug/L 1 04/02/10 03:32 108-86-10.50 0.50
Bromochloromethane ND ug/L 1 04/02/10 03:32 74-97-50.50 0.50
Bromodichloromethane ND ug/L 1 04/02/10 03:32 75-27-40.50 0.50
Bromoform ND ug/L 1 04/02/10 03:32 75-25-20.50 0.50
Bromomethane ND ug/L 1 04/02/10 03:32 74-83-95.0 1.0
n-Butylbenzene ND ug/L 1 04/02/10 03:32 104-51-80.50 0.50
sec-Butylbenzene ND ug/L 1 04/02/10 03:32 135-98-80.50 0.50
tert-Butylbenzene ND ug/L 1 04/02/10 03:32 98-06-60.50 0.50
Carbon tetrachloride ND ug/L 1 04/02/10 03:32 56-23-50.50 0.50
Chlorobenzene ND ug/L 1 04/02/10 03:32 108-90-70.50 0.50
Chloroethane ND ug/L 1 04/02/10 03:32 75-00-31.0 1.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 35 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-6T Lab ID:9266446008 Collected:03/30/10 11:45 Received:03/31/10 15:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
Chloroform ND ug/L 1 04/02/10 03:32 67-66-30.50 0.50
Chloromethane ND ug/L 1 04/02/10 03:32 74-87-31.0 1.0
2-Chlorotoluene ND ug/L 1 04/02/10 03:32 95-49-80.50 0.50
4-Chlorotoluene ND ug/L 1 04/02/10 03:32 106-43-40.50 0.50
1,2-Dibromo-3-chloropropane ND ug/L 1 04/02/10 03:32 96-12-81.0 1.0
Dibromochloromethane ND ug/L 1 04/02/10 03:32 124-48-10.50 0.50
1,2-Dibromoethane (EDB)ND ug/L 1 04/02/10 03:32 106-93-40.50 0.50
Dibromomethane ND ug/L 1 04/02/10 03:32 74-95-30.50 0.50
1,2-Dichlorobenzene ND ug/L 1 04/02/10 03:32 95-50-10.50 0.50
1,3-Dichlorobenzene ND ug/L 1 04/02/10 03:32 541-73-10.50 0.50
1,4-Dichlorobenzene ND ug/L 1 04/02/10 03:32 106-46-70.50 0.50
Dichlorodifluoromethane ND ug/L 1 04/02/10 03:32 75-71-80.50 0.50
1,1-Dichloroethane ND ug/L 1 04/02/10 03:32 75-34-30.50 0.50
1,2-Dichloroethane ND ug/L 1 04/02/10 03:32 107-06-20.50 0.50
1,1-Dichloroethene ND ug/L 1 04/02/10 03:32 75-35-40.50 0.50
cis-1,2-Dichloroethene ND ug/L 1 04/02/10 03:32 156-59-20.50 0.50
trans-1,2-Dichloroethene ND ug/L 1 04/02/10 03:32 156-60-50.50 0.50
1,2-Dichloropropane ND ug/L 1 04/02/10 03:32 78-87-50.50 0.50
1,3-Dichloropropane ND ug/L 1 04/02/10 03:32 142-28-90.50 0.50
2,2-Dichloropropane ND ug/L 1 04/02/10 03:32 594-20-70.50 0.50
1,1-Dichloropropene ND ug/L 1 04/02/10 03:32 563-58-60.50 0.50
cis-1,3-Dichloropropene ND ug/L 1 04/02/10 03:32 10061-01-50.50 0.50
trans-1,3-Dichloropropene ND ug/L 1 04/02/10 03:32 10061-02-60.50 0.50
Diisopropyl ether ND ug/L 1 04/02/10 03:32 108-20-30.50 0.50
Ethylbenzene ND ug/L 1 04/02/10 03:32 100-41-40.50 0.50
Hexachloro-1,3-butadiene ND ug/L 1 04/02/10 03:32 87-68-32.0 2.0
Isopropylbenzene (Cumene)ND ug/L 1 04/02/10 03:32 98-82-80.50 0.50
Methylene Chloride ND ug/L 1 04/02/10 03:32 75-09-22.0 2.0
Methyl-tert-butyl ether ND ug/L 1 04/02/10 03:32 1634-04-40.50 0.50
Naphthalene ND ug/L 1 04/02/10 03:32 91-20-32.0 2.0
n-Propylbenzene ND ug/L 1 04/02/10 03:32 103-65-10.50 0.50
Styrene ND ug/L 1 04/02/10 03:32 100-42-50.50 0.50
1,1,1,2-Tetrachloroethane ND ug/L 1 04/02/10 03:32 630-20-60.50 0.50
1,1,2,2-Tetrachloroethane ND ug/L 1 04/02/10 03:32 79-34-50.50 0.50
Tetrachloroethene ND ug/L 1 04/02/10 03:32 127-18-40.50 0.50
Toluene ND ug/L 1 04/02/10 03:32 108-88-30.50 0.50
1,2,3-Trichlorobenzene ND ug/L 1 04/02/10 03:32 87-61-62.0 2.0
1,2,4-Trichlorobenzene ND ug/L 1 04/02/10 03:32 120-82-12.0 2.0
1,1,1-Trichloroethane ND ug/L 1 04/02/10 03:32 71-55-60.50 0.50
1,1,2-Trichloroethane ND ug/L 1 04/02/10 03:32 79-00-50.50 0.50
Trichloroethene ND ug/L 1 04/02/10 03:32 79-01-60.50 0.50
Trichlorofluoromethane ND ug/L 1 04/02/10 03:32 75-69-41.0 1.0
1,2,3-Trichloropropane ND ug/L 1 04/02/10 03:32 96-18-40.50 0.50
1,2,4-Trimethylbenzene ND ug/L 1 04/02/10 03:32 95-63-60.50 0.50
1,3,5-Trimethylbenzene ND ug/L 1 04/02/10 03:32 108-67-80.50 0.50
Vinyl chloride ND ug/L 1 04/02/10 03:32 75-01-41.0 1.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 36 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-6T Lab ID:9266446008 Collected:03/30/10 11:45 Received:03/31/10 15:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
m&p-Xylene ND ug/L 1 04/02/10 03:32 1330-20-71.0 1.0
o-Xylene ND ug/L 1 04/02/10 03:32 95-47-60.50 0.50
1,2-Dichloroethane-d4 (S)105 %1 04/02/10 03:32 17060-07-070-130
Dibromofluoromethane (S)104 %1 04/02/10 03:32 1868-53-770-130
4-Bromofluorobenzene (S)94 %1 04/02/10 03:32 460-00-470-130
Toluene-d8 (S)100 %1 04/02/10 03:32 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 37 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-7T Lab ID:9266446009 Collected:03/30/10 12:30 Received:03/31/10 15:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
MADEP EPH NC Water Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)ND ug/L 1 04/07/10 19:3704/02/10 14:00137137
Aliphatic (C19-C36)ND ug/L 1 04/07/10 19:3704/02/10 14:00137137
Aromatic (C11-C22)ND ug/L 1 04/07/10 04:0704/02/10 14:00137137
Nonatriacontane (S)83 %1 04/07/10 19:37 7194-86-704/02/10 14:0040-140
o-Terphenyl (S)68 %1 04/07/10 04:07 84-15-104/02/10 14:0040-140
2-Fluorobiphenyl (S)98 %1 04/07/10 04:07 321-60-804/02/10 14:0040-140
2-Bromonaphthalene (S)101 %1 04/07/10 04:07 580-13-204/02/10 14:0040-140
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)ND ug/L 1 04/01/10 20:55100100
Aliphatic (C09-C12)ND ug/L 1 04/01/10 20:55100100
Aromatic (C09-C10)ND ug/L 1 04/01/10 20:55100100
2,5-Dibromotoluene (PID)(S)116 %1 04/01/10 20:5570-130
2,5-Dibromotoluene (FID)(S)123 %1 04/01/10 20:5570-130
200.7 MET ICP, 3030C Analytical Method: EPA 200.7 Preparation Method: SM 3030C
Lead 780 ug/L 5 04/07/10 12:09 7439-92-1 D304/01/10 08:0025.0 20.0
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
Acenaphthene ND ug/L 1 04/09/10 02:52 83-32-904/01/10 11:006.7 3.7
Acenaphthylene ND ug/L 1 04/09/10 02:52 208-96-804/01/10 11:006.7 3.7
Anthracene ND ug/L 1 04/09/10 02:52 120-12-704/01/10 11:006.7 3.9
Benzo(a)anthracene ND ug/L 1 04/09/10 02:52 56-55-304/01/10 11:006.7 3.7
Benzo(a)pyrene ND ug/L 1 04/09/10 02:52 50-32-804/01/10 11:006.7 4.1
Benzo(b)fluoranthene ND ug/L 1 04/09/10 02:52 205-99-204/01/10 11:006.7 4.8
Benzo(g,h,i)perylene ND ug/L 1 04/09/10 02:52 191-24-204/01/10 11:006.7 4.1
Benzo(k)fluoranthene ND ug/L 1 04/09/10 02:52 207-08-904/01/10 11:006.7 4.0
4-Bromophenylphenyl ether ND ug/L 1 04/09/10 02:52 101-55-304/01/10 11:006.7 3.2
Butylbenzylphthalate ND ug/L 1 04/09/10 02:52 85-68-704/01/10 11:006.7 3.9
4-Chloro-3-methylphenol ND ug/L 1 04/09/10 02:52 59-50-704/01/10 11:006.7 3.7
bis(2-Chloroethoxy)methane ND ug/L 1 04/09/10 02:52 111-91-104/01/10 11:0013.3 7.7
bis(2-Chloroethyl) ether ND ug/L 1 04/09/10 02:52 111-44-404/01/10 11:006.7 6.4
bis(2-Chloroisopropyl) ether ND ug/L 1 04/09/10 02:52 108-60-104/01/10 11:006.7 5.3
2-Chloronaphthalene ND ug/L 1 04/09/10 02:52 91-58-704/01/10 11:006.7 4.8
2-Chlorophenol ND ug/L 1 04/09/10 02:52 95-57-804/01/10 11:006.7 5.9
4-Chlorophenylphenyl ether ND ug/L 1 04/09/10 02:52 7005-72-304/01/10 11:006.7 3.6
Chrysene ND ug/L 1 04/09/10 02:52 218-01-904/01/10 11:006.7 3.6
Dibenz(a,h)anthracene ND ug/L 1 04/09/10 02:52 53-70-304/01/10 11:006.7 3.9
3,3'-Dichlorobenzidine ND ug/L 1 04/09/10 02:52 91-94-104/01/10 11:006.7 4.5
2,4-Dichlorophenol ND ug/L 1 04/09/10 02:52 120-83-204/01/10 11:006.7 5.5
Diethylphthalate ND ug/L 1 04/09/10 02:52 84-66-204/01/10 11:006.7 3.6
2,4-Dimethylphenol ND ug/L 1 04/09/10 02:52 105-67-904/01/10 11:0013.3 7.5
Dimethylphthalate ND ug/L 1 04/09/10 02:52 131-11-304/01/10 11:006.7 3.2
Di-n-butylphthalate ND ug/L 1 04/09/10 02:52 84-74-204/01/10 11:006.7 3.9
4,6-Dinitro-2-methylphenol ND ug/L 1 04/09/10 02:52 534-52-104/01/10 11:0026.7 10.4
2,4-Dinitrophenol ND ug/L 1 04/09/10 02:52 51-28-504/01/10 11:0066.7 13.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 38 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-7T Lab ID:9266446009 Collected:03/30/10 12:30 Received:03/31/10 15:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
2,4-Dinitrotoluene ND ug/L 1 04/09/10 02:52 121-14-204/01/10 11:006.7 3.5
2,6-Dinitrotoluene ND ug/L 1 04/09/10 02:52 606-20-204/01/10 11:006.7 3.7
Di-n-octylphthalate ND ug/L 1 04/09/10 02:52 117-84-004/01/10 11:006.7 3.9
bis(2-Ethylhexyl)phthalate ND ug/L 1 04/09/10 02:52 117-81-704/01/10 11:006.7 2.8
Fluoranthene ND ug/L 1 04/09/10 02:52 206-44-004/01/10 11:006.7 3.9
Fluorene ND ug/L 1 04/09/10 02:52 86-73-704/01/10 11:006.7 3.5
Hexachloro-1,3-butadiene ND ug/L 1 04/09/10 02:52 87-68-304/01/10 11:006.7 4.4
Hexachlorobenzene ND ug/L 1 04/09/10 02:52 118-74-104/01/10 11:006.7 3.5
Hexachlorocyclopentadiene ND ug/L 1 04/09/10 02:52 77-47-404/01/10 11:0013.3 4.9
Hexachloroethane ND ug/L 1 04/09/10 02:52 67-72-104/01/10 11:006.7 4.4
Indeno(1,2,3-cd)pyrene ND ug/L 1 04/09/10 02:52 193-39-504/01/10 11:006.7 4.0
Isophorone ND ug/L 1 04/09/10 02:52 78-59-104/01/10 11:0013.3 8.7
2-Methylnaphthalene ND ug/L 1 04/09/10 02:52 91-57-604/01/10 11:006.7 4.5
Naphthalene ND ug/L 1 04/09/10 02:52 91-20-304/01/10 11:006.7 5.1
Nitrobenzene ND ug/L 1 04/09/10 02:52 98-95-304/01/10 11:006.7 5.9
2-Nitrophenol ND ug/L 1 04/09/10 02:52 88-75-504/01/10 11:006.7 6.1
4-Nitrophenol ND ug/L 1 04/09/10 02:52 100-02-704/01/10 11:0066.7 2.7
N-Nitrosodimethylamine ND ug/L 1 04/09/10 02:52 62-75-904/01/10 11:006.7 4.1
N-Nitroso-di-n-propylamine ND ug/L 1 04/09/10 02:52 621-64-704/01/10 11:006.7 4.9
N-Nitrosodiphenylamine ND ug/L 1 04/09/10 02:52 86-30-604/01/10 11:0013.3 8.8
Pentachlorophenol ND ug/L 1 04/09/10 02:52 87-86-504/01/10 11:0033.3 2.1
Phenanthrene ND ug/L 1 04/09/10 02:52 85-01-804/01/10 11:006.7 3.6
Phenol ND ug/L 1 04/09/10 02:52 108-95-204/01/10 11:006.7 2.4
Pyrene ND ug/L 1 04/09/10 02:52 129-00-004/01/10 11:006.7 3.9
1,2,4-Trichlorobenzene ND ug/L 1 04/09/10 02:52 120-82-104/01/10 11:006.7 4.5
2,4,6-Trichlorophenol ND ug/L 1 04/09/10 02:52 88-06-204/01/10 11:0013.3 8.1
Nitrobenzene-d5 (S)68 %1 04/09/10 02:52 4165-60-004/01/10 11:0010-120
2-Fluorobiphenyl (S)61 %1 04/09/10 02:52 321-60-804/01/10 11:0015-120
Terphenyl-d14 (S)101 %1 04/09/10 02:52 1718-51-004/01/10 11:0011-131
Phenol-d6 (S)26 %1 04/09/10 02:52 13127-88-304/01/10 11:0010-120
2-Fluorophenol (S)40 %1 04/09/10 02:52 367-12-404/01/10 11:0010-120
2,4,6-Tribromophenol (S)94 %1 04/09/10 02:52 118-79-604/01/10 11:0010-137
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 04/02/10 03:54 71-43-20.50 0.50
Bromobenzene ND ug/L 1 04/02/10 03:54 108-86-10.50 0.50
Bromochloromethane ND ug/L 1 04/02/10 03:54 74-97-50.50 0.50
Bromodichloromethane ND ug/L 1 04/02/10 03:54 75-27-40.50 0.50
Bromoform ND ug/L 1 04/02/10 03:54 75-25-20.50 0.50
Bromomethane ND ug/L 1 04/02/10 03:54 74-83-95.0 1.0
n-Butylbenzene ND ug/L 1 04/02/10 03:54 104-51-80.50 0.50
sec-Butylbenzene ND ug/L 1 04/02/10 03:54 135-98-80.50 0.50
tert-Butylbenzene ND ug/L 1 04/02/10 03:54 98-06-60.50 0.50
Carbon tetrachloride ND ug/L 1 04/02/10 03:54 56-23-50.50 0.50
Chlorobenzene ND ug/L 1 04/02/10 03:54 108-90-70.50 0.50
Chloroethane ND ug/L 1 04/02/10 03:54 75-00-31.0 1.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 39 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-7T Lab ID:9266446009 Collected:03/30/10 12:30 Received:03/31/10 15:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
Chloroform ND ug/L 1 04/02/10 03:54 67-66-30.50 0.50
Chloromethane ND ug/L 1 04/02/10 03:54 74-87-31.0 1.0
2-Chlorotoluene ND ug/L 1 04/02/10 03:54 95-49-80.50 0.50
4-Chlorotoluene ND ug/L 1 04/02/10 03:54 106-43-40.50 0.50
1,2-Dibromo-3-chloropropane ND ug/L 1 04/02/10 03:54 96-12-81.0 1.0
Dibromochloromethane ND ug/L 1 04/02/10 03:54 124-48-10.50 0.50
1,2-Dibromoethane (EDB)ND ug/L 1 04/02/10 03:54 106-93-40.50 0.50
Dibromomethane ND ug/L 1 04/02/10 03:54 74-95-30.50 0.50
1,2-Dichlorobenzene ND ug/L 1 04/02/10 03:54 95-50-10.50 0.50
1,3-Dichlorobenzene ND ug/L 1 04/02/10 03:54 541-73-10.50 0.50
1,4-Dichlorobenzene ND ug/L 1 04/02/10 03:54 106-46-70.50 0.50
Dichlorodifluoromethane ND ug/L 1 04/02/10 03:54 75-71-80.50 0.50
1,1-Dichloroethane ND ug/L 1 04/02/10 03:54 75-34-30.50 0.50
1,2-Dichloroethane ND ug/L 1 04/02/10 03:54 107-06-20.50 0.50
1,1-Dichloroethene ND ug/L 1 04/02/10 03:54 75-35-40.50 0.50
cis-1,2-Dichloroethene ND ug/L 1 04/02/10 03:54 156-59-20.50 0.50
trans-1,2-Dichloroethene ND ug/L 1 04/02/10 03:54 156-60-50.50 0.50
1,2-Dichloropropane ND ug/L 1 04/02/10 03:54 78-87-50.50 0.50
1,3-Dichloropropane ND ug/L 1 04/02/10 03:54 142-28-90.50 0.50
2,2-Dichloropropane ND ug/L 1 04/02/10 03:54 594-20-70.50 0.50
1,1-Dichloropropene ND ug/L 1 04/02/10 03:54 563-58-60.50 0.50
cis-1,3-Dichloropropene ND ug/L 1 04/02/10 03:54 10061-01-50.50 0.50
trans-1,3-Dichloropropene ND ug/L 1 04/02/10 03:54 10061-02-60.50 0.50
Diisopropyl ether ND ug/L 1 04/02/10 03:54 108-20-30.50 0.50
Ethylbenzene ND ug/L 1 04/02/10 03:54 100-41-40.50 0.50
Hexachloro-1,3-butadiene ND ug/L 1 04/02/10 03:54 87-68-32.0 2.0
Isopropylbenzene (Cumene)ND ug/L 1 04/02/10 03:54 98-82-80.50 0.50
Methylene Chloride ND ug/L 1 04/02/10 03:54 75-09-22.0 2.0
Methyl-tert-butyl ether ND ug/L 1 04/02/10 03:54 1634-04-40.50 0.50
Naphthalene ND ug/L 1 04/02/10 03:54 91-20-32.0 2.0
n-Propylbenzene ND ug/L 1 04/02/10 03:54 103-65-10.50 0.50
Styrene ND ug/L 1 04/02/10 03:54 100-42-50.50 0.50
1,1,1,2-Tetrachloroethane ND ug/L 1 04/02/10 03:54 630-20-60.50 0.50
1,1,2,2-Tetrachloroethane ND ug/L 1 04/02/10 03:54 79-34-50.50 0.50
Tetrachloroethene ND ug/L 1 04/02/10 03:54 127-18-40.50 0.50
Toluene ND ug/L 1 04/02/10 03:54 108-88-30.50 0.50
1,2,3-Trichlorobenzene ND ug/L 1 04/02/10 03:54 87-61-62.0 2.0
1,2,4-Trichlorobenzene ND ug/L 1 04/02/10 03:54 120-82-12.0 2.0
1,1,1-Trichloroethane ND ug/L 1 04/02/10 03:54 71-55-60.50 0.50
1,1,2-Trichloroethane ND ug/L 1 04/02/10 03:54 79-00-50.50 0.50
Trichloroethene ND ug/L 1 04/02/10 03:54 79-01-60.50 0.50
Trichlorofluoromethane ND ug/L 1 04/02/10 03:54 75-69-41.0 1.0
1,2,3-Trichloropropane ND ug/L 1 04/02/10 03:54 96-18-40.50 0.50
1,2,4-Trimethylbenzene ND ug/L 1 04/02/10 03:54 95-63-60.50 0.50
1,3,5-Trimethylbenzene ND ug/L 1 04/02/10 03:54 108-67-80.50 0.50
Vinyl chloride ND ug/L 1 04/02/10 03:54 75-01-41.0 1.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 40 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Sample:SB-7T Lab ID:9266446009 Collected:03/30/10 12:30 Received:03/31/10 15:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
m&p-Xylene ND ug/L 1 04/02/10 03:54 1330-20-71.0 1.0
o-Xylene ND ug/L 1 04/02/10 03:54 95-47-60.50 0.50
1,2-Dichloroethane-d4 (S)104 %1 04/02/10 03:54 17060-07-070-130
Dibromofluoromethane (S)102 %1 04/02/10 03:54 1868-53-770-130
4-Bromofluorobenzene (S)94 %1 04/02/10 03:54 460-00-470-130
Toluene-d8 (S)99 %1 04/02/10 03:54 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 41 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/9655
MADEP EPH
MADEP EPH
MADEP EPH NC Soil
Associated Lab Samples:9266446001, 9266446002, 9266446003, 9266446004, 9266446005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:423894
Associated Lab Samples:9266446001, 9266446002, 9266446003, 9266446004, 9266446005
Matrix:Solid
Analyzed
Aliphatic (C09-C18)mg/kg ND 10.0 04/05/10 20:27
Aliphatic (C19-C36)mg/kg ND 10.0 04/05/10 20:27
Aromatic (C11-C22)mg/kg ND 10.0 04/05/10 20:27
2-Bromonaphthalene (S)%75 40-140 04/05/10 20:27
2-Fluorobiphenyl (S)%79 40-140 04/05/10 20:27
Nonatriacontane (S)%81 40-140 04/05/10 20:27
o-Terphenyl (S)%56 40-140 04/05/10 20:27
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
423895LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
423896
Aliphatic (C09-C18)mg/kg ND10 82 40-14080ND 50
Aliphatic (C19-C36)mg/kg 11.713.3 88 40-1408010.7 9 50
Aromatic (C11-C22)mg/kg 27.628.3 97 40-1408423.8 15 50
2-Bromonaphthalene (S)%120 40-14082
2-Fluorobiphenyl (S)%115 40-14078
Nonatriacontane (S)%80 40-14078
o-Terphenyl (S)%93 40-14081
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 42 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/9653
MADEP EPH
MADEP EPH
MADEP EPH NC Water
Associated Lab Samples:9266446006, 9266446007, 9266446008, 9266446009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:423807
Associated Lab Samples:9266446006, 9266446007, 9266446008, 9266446009
Matrix:Water
Analyzed
Aliphatic (C09-C18)ug/L ND 100 04/07/10 15:25
Aliphatic (C19-C36)ug/L ND 100 04/07/10 15:25
Aromatic (C11-C22)ug/L ND 100 04/06/10 23:55
2-Bromonaphthalene (S)%92 40-140 04/06/10 23:55
2-Fluorobiphenyl (S)%89 40-140 04/06/10 23:55
Nonatriacontane (S)%98 40-140 04/07/10 15:25
o-Terphenyl (S)%69 40-140 04/06/10 23:55
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
423808LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
423809
Aliphatic (C09-C18)ug/L 180300 60 40-14067201 11 50
Aliphatic (C19-C36)ug/L 315400 79 40-14093373 17 50
Aromatic (C11-C22)ug/L 770850 91 40-14077658 16 50
2-Bromonaphthalene (S)%107 40-14093
2-Fluorobiphenyl (S)%106 40-14093
Nonatriacontane (S)%86 40-14091
o-Terphenyl (S)%83 40-14068
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 43 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GCV/3962
MADEP VPH
MADEP VPH
VPH NC Soil
Associated Lab Samples:9266446001, 9266446002, 9266446003, 9266446004, 9266446005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:425070
Associated Lab Samples:9266446001, 9266446002, 9266446003, 9266446004, 9266446005
Matrix:Solid
Analyzed
Aliphatic (C05-C08)mg/kg ND 10.0 04/06/10 16:38
Aliphatic (C09-C12)mg/kg ND 10.0 04/06/10 16:38
Aromatic (C09-C10)mg/kg ND 10.0 04/06/10 16:38
2,5-Dibromotoluene (FID)(S)%129 70-130 04/06/10 16:38
2,5-Dibromotoluene (PID)(S)%126 70-130 04/06/10 16:38
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
425071LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
425072
Aliphatic (C05-C08)mg/kg 15.515 103 70-13010215.2 2 25
Aliphatic (C09-C12)mg/kg 17.015 114 30-13011216.8 2 25
Aromatic (C09-C10)mg/kg ND5 101 70-13098ND 25
2,5-Dibromotoluene (FID)(S)%114 70-13098
2,5-Dibromotoluene (PID)(S)%103 70-13089
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 44 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GCV/3953
MADEP VPH
MADEP VPH
VPH NC Water
Associated Lab Samples:9266446006, 9266446007, 9266446008, 9266446009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:423065
Associated Lab Samples:9266446006, 9266446007, 9266446008, 9266446009
Matrix:Water
Analyzed
Aliphatic (C05-C08)ug/L ND 100 04/01/10 17:13
Aliphatic (C09-C12)ug/L ND 100 04/01/10 17:13
Aromatic (C09-C10)ug/L ND 100 04/01/10 17:13
2,5-Dibromotoluene (FID)(S)%120 70-130 04/01/10 17:13
2,5-Dibromotoluene (PID)(S)%114 70-130 04/01/10 17:13
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
423066LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
423067
Aliphatic (C05-C08)ug/L 302300 101 70-130101304 1 25
Aliphatic (C09-C12)ug/L 329300 110 30-130112335 2 25
Aromatic (C09-C10)ug/L ND100 100 70-130100100 25
2,5-Dibromotoluene (FID)(S)%107 70-130106
2,5-Dibromotoluene (PID)(S)%100 70-13098
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 45 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/6076
SM 3030C
EPA 200.7
200.7 MET 3030C
Associated Lab Samples:9266446006, 9266446007, 9266446008, 9266446009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:422932
Associated Lab Samples:9266446006, 9266446007, 9266446008, 9266446009
Matrix:Water
Analyzed
Lead ug/L ND 5.0 04/07/10 00:12
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
422933LABORATORY CONTROL SAMPLE:
LCSSpike
Lead ug/L 556500 111 85-115
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
422934MATRIX SPIKE SAMPLE:
MSSpike
Result
9266445004
Lead ug/L 532
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
9266446006
422935SAMPLE DUPLICATE:
Lead ug/L 183 17 20217
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 46 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/9643
EPA 625
EPA 625
625 MSS
Associated Lab Samples:9266446006, 9266446007, 9266446008, 9266446009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:423071
Associated Lab Samples:9266446006, 9266446007, 9266446008, 9266446009
Matrix:Water
Analyzed
1,2,4-Trichlorobenzene ug/L ND 5.0 04/08/10 16:34
2,4,6-Trichlorophenol ug/L ND 10.0 04/08/10 16:34
2,4-Dichlorophenol ug/L ND 5.0 04/08/10 16:34
2,4-Dimethylphenol ug/L ND 10.0 04/08/10 16:34
2,4-Dinitrophenol ug/L ND 50.0 04/08/10 16:34
2,4-Dinitrotoluene ug/L ND 5.0 04/08/10 16:34
2,6-Dinitrotoluene ug/L ND 5.0 04/08/10 16:34
2-Chloronaphthalene ug/L ND 5.0 04/08/10 16:34
2-Chlorophenol ug/L ND 5.0 04/08/10 16:34
2-Methylnaphthalene ug/L ND 5.0 04/08/10 16:34
2-Nitrophenol ug/L ND 5.0 04/08/10 16:34
3,3'-Dichlorobenzidine ug/L ND 5.0 04/08/10 16:34
4,6-Dinitro-2-methylphenol ug/L ND 20.0 04/08/10 16:34
4-Bromophenylphenyl ether ug/L ND 5.0 04/08/10 16:34
4-Chloro-3-methylphenol ug/L ND 5.0 04/08/10 16:34
4-Chlorophenylphenyl ether ug/L ND 5.0 04/08/10 16:34
4-Nitrophenol ug/L ND 50.0 04/08/10 16:34
Acenaphthene ug/L ND 5.0 04/08/10 16:34
Acenaphthylene ug/L ND 5.0 04/08/10 16:34
Anthracene ug/L ND 5.0 04/08/10 16:34
Benzo(a)anthracene ug/L ND 5.0 04/08/10 16:34
Benzo(a)pyrene ug/L ND 5.0 04/08/10 16:34
Benzo(b)fluoranthene ug/L ND 5.0 04/08/10 16:34
Benzo(g,h,i)perylene ug/L ND 5.0 04/08/10 16:34
Benzo(k)fluoranthene ug/L ND 5.0 04/08/10 16:34
bis(2-Chloroethoxy)methane ug/L ND 10.0 04/08/10 16:34
bis(2-Chloroethyl) ether ug/L ND 5.0 04/08/10 16:34
bis(2-Chloroisopropyl) ether ug/L ND 5.0 04/08/10 16:34
bis(2-Ethylhexyl)phthalate ug/L ND 5.0 04/08/10 16:34
Butylbenzylphthalate ug/L ND 5.0 04/08/10 16:34
Chrysene ug/L ND 5.0 04/08/10 16:34
Di-n-butylphthalate ug/L ND 5.0 04/08/10 16:34
Di-n-octylphthalate ug/L ND 5.0 04/08/10 16:34
Dibenz(a,h)anthracene ug/L ND 5.0 04/08/10 16:34
Diethylphthalate ug/L ND 5.0 04/08/10 16:34
Dimethylphthalate ug/L ND 5.0 04/08/10 16:34
Fluoranthene ug/L ND 5.0 04/08/10 16:34
Fluorene ug/L ND 5.0 04/08/10 16:34
Hexachloro-1,3-butadiene ug/L ND 5.0 04/08/10 16:34
Hexachlorobenzene ug/L ND 5.0 04/08/10 16:34
Hexachlorocyclopentadiene ug/L ND 10.0 04/08/10 16:34
Hexachloroethane ug/L ND 5.0 04/08/10 16:34
Indeno(1,2,3-cd)pyrene ug/L ND 5.0 04/08/10 16:34
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 47 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:423071
Associated Lab Samples:9266446006, 9266446007, 9266446008, 9266446009
Matrix:Water
Analyzed
Isophorone ug/L ND 10.0 04/08/10 16:34
N-Nitroso-di-n-propylamine ug/L ND 5.0 04/08/10 16:34
N-Nitrosodimethylamine ug/L ND 5.0 04/08/10 16:34
N-Nitrosodiphenylamine ug/L ND 10.0 04/08/10 16:34
Naphthalene ug/L ND 5.0 04/08/10 16:34
Nitrobenzene ug/L ND 5.0 04/08/10 16:34
Pentachlorophenol ug/L ND 25.0 04/08/10 16:34
Phenanthrene ug/L ND 5.0 04/08/10 16:34
Phenol ug/L ND 5.0 04/08/10 16:34
Pyrene ug/L ND 5.0 04/08/10 16:34
2,4,6-Tribromophenol (S)%54 10-137 04/08/10 16:34
2-Fluorobiphenyl (S)%41 15-120 04/08/10 16:34
2-Fluorophenol (S)%26 10-120 04/08/10 16:34
Nitrobenzene-d5 (S)%45 10-120 04/08/10 16:34
Phenol-d6 (S)%16 10-120 04/08/10 16:34
Terphenyl-d14 (S)%61 11-131 04/08/10 16:34
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
423072LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
423073
1,2,4-Trichlorobenzene ug/L 25.050 50 44-1426833.9 30 30
2,4,6-Trichlorophenol ug/L 29.1 R1505837-1448944.5 42 30
2,4-Dichlorophenol ug/L 30.9 R150621-1918844.0 35 30
2,4-Dimethylphenol ug/L 24.0 R1504832-1197035.0 37 30
2,4-Dinitrophenol ug/L 31.3J R1250131-18156141 30
2,4-Dinitrotoluene ug/L 26.9 R1505439-1398341.4 42 30
2,6-Dinitrotoluene ug/L 28.5 R1505750-1588843.8 42 30
2-Chloronaphthalene ug/L 27.3 L2,R1505560-1188040.0 38 30
2-Chlorophenol ug/L 28.050 56 23-1347035.1 23 30
2-Methylnaphthalene ug/L 26.6 R1505325-1507537.6 34 30
2-Nitrophenol ug/L 29.0 R1505829-1828140.6 34 30
3,3'-Dichlorobenzidine ug/L 186 R1250741-262113282 41 30
4,6-Dinitro-2-methylphenol ug/L 54.3 R1100541-181101101 60 30
4-Bromophenylphenyl ether ug/L 28.9 R1505853-1279145.5 45 30
4-Chloro-3-methylphenol ug/L 60.8 R11006122-1478988.8 38 30
4-Chlorophenylphenyl ether ug/L 28.5 R1505725-1588743.5 42 30
4-Nitrophenol ug/L 47.4J R1250191-1323793.3 30
Acenaphthene ug/L 26.6 R1505347-1458140.6 42 30
Acenaphthylene ug/L 26.5 R1505333-1458140.5 42 30
Anthracene ug/L 29.9 R150601-1669145.6 42 30
Benzo(a)anthracene ug/L 33.5 R1506733-14310452.0 43 30
Benzo(a)pyrene ug/L 29.3 R1505917-1638944.7 41 30
Benzo(b)fluoranthene ug/L 28.9 R1505824-1598743.4 40 30
Benzo(g,h,i)perylene ug/L 34.0 R150681-21910451.9 42 30
Benzo(k)fluoranthene ug/L 32.2 R1506411-1629648.1 40 30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 48 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
423072LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
423073
bis(2-Chloroethoxy)methane ug/L 27.3 R1505533-1847738.6 34 30
bis(2-Chloroethyl) ether ug/L 29.850 60 12-1587537.4 23 30
bis(2-Chloroisopropyl) ether ug/L 29.750 59 36-1667537.4 23 30
bis(2-Ethylhexyl)phthalate ug/L 25.2 R150508-1588442.1 50 30
Butylbenzylphthalate ug/L 26.7 R150531-1529044.8 51 30
Chrysene ug/L 32.5 R1506517-16810753.6 49 30
Di-n-butylphthalate ug/L 27.3 R150551-1188341.6 42 30
Di-n-octylphthalate ug/L 25.5 R150514-1468441.9 49 30
Dibenz(a,h)anthracene ug/L 34.5 R150691-22710552.4 41 30
Diethylphthalate ug/L 27.4 R150551-1148441.8 41 30
Dimethylphthalate ug/L 26.0 R150521-1128140.7 44 30
Fluoranthene ug/L 31.6 R1506326-1379547.3 40 30
Fluorene ug/L 29.9 R1506059-1219045.1 41 30
Hexachloro-1,3-butadiene ug/L 23.5 R1504724-1166432.1 31 30
Hexachlorobenzene ug/L 32.9 R150661-15210251.1 43 30
Hexachlorocyclopentadiene ug/L 26.150 52 25-1506331.7 19 30
Hexachloroethane ug/L 22.750 45 40-1135728.6 23 30
Indeno(1,2,3-cd)pyrene ug/L 33.9 R150681-17110452.2 43 30
Isophorone ug/L 29.3 R1505921-1968442.2 36 30
N-Nitroso-di-n-propylamine ug/L 31.950 64 1-2308240.9 25 30
N-Nitrosodimethylamine ug/L 25.650 51 25-1506431.8 21 30
N-Nitrosodiphenylamine ug/L 29.7 R1505925-1509346.3 44 30
Naphthalene ug/L 26.750 53 21-1337236.1 30 30
Nitrobenzene ug/L 28.8 R1505835-1808040.0 33 30
Pentachlorophenol ug/L 142 R12505714-17681202 35 30
Phenanthrene ug/L 29.8 R1506054-1209045.2 41 30
Phenol ug/L 13.050 26 5-1123215.9 20 30
Pyrene ug/L 31.0 R1506252-11510351.7 50 30
2,4,6-Tribromophenol (S)%65 10-13795
2-Fluorobiphenyl (S)%50 15-12074
2-Fluorophenol (S)%34 10-12042
Nitrobenzene-d5 (S)%57 10-12076
Phenol-d6 (S)%22 10-12026
Terphenyl-d14 (S)%59 11-13197
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
423074MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9266362001
423075
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,2,4-Trichlorobenzene ug/L 109 79 44-14275 6 30109ND85.9 81.2
2,4,6-Trichlorophenol ug/L R11096337-14489 34 30109ND68.4 96.8
2,4-Dichlorophenol ug/L 109 99 1-19195 3 30109ND107104
2,4-Dimethylphenol ug/L 109 56 32-11960 6 30109ND61.4 65.0
2,4-Dinitrophenol ug/L 543 15 1-18131 30543ND79.2J 170
2,4-Dinitrotoluene ug/L 109 89 39-13985 4 30109ND96.6 92.5
2,6-Dinitrotoluene ug/L 109 93 50-15888 5 30109ND10195.8
2-Chloronaphthalene ug/L 109 94 60-11891 4 30109ND10398.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 49 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
423074MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9266362001
423075
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
2-Chlorophenol ug/L 109 81 23-13477 4 30109ND87.6 83.8
2-Methylnaphthalene ug/L 109 85 25-15081 5 30109ND92.9 88.4
2-Nitrophenol ug/L 109 97 29-18295 2 30109ND105103
3,3'-Dichlorobenzidine ug/L R1543181-26212 41 30543ND10066.3
4,6-Dinitro-2-methylphenol ug/L R1217421-18182 64 30217ND91.2 178
4-Bromophenylphenyl ether ug/L 109 98 53-12791 7 30109ND10799.4
4-Chloro-3-methylphenol ug/L 217 99 22-14793 6 30217ND216203
4-Chlorophenylphenyl ether ug/L 109 99 25-15894 6 30109ND108102
4-Nitrophenol ug/L R1543331-13256 53 30543ND177305
Acenaphthene ug/L 109 90 47-14586 4 30109ND97.8 93.7
Acenaphthylene ug/L 109 89 33-14585 5 30109ND96.7 92.3
Anthracene ug/L 109 98 1-16692 6 30109ND107100
Benzo(a)anthracene ug/L 109 95 33-14388 8 30109ND10395.4
Benzo(a)pyrene ug/L 109 92 17-16386 6 30109ND99.8 93.8
Benzo(b)fluoranthene ug/L 109 96 24-15991 5 30109ND10599.2
Benzo(g,h,i)perylene ug/L 109 89 1-21981 10 30109ND96.9 87.8
Benzo(k)fluoranthene ug/L 109 108 11-162103 5 30109ND118112
bis(2-Chloroethoxy)methane ug/L 109 87 33-18483 6 30109ND95.0 89.9
bis(2-Chloroethyl) ether ug/L 109 82 12-15879 3 30109ND88.9 86.0
bis(2-Chloroisopropyl) ether ug/L 109 83 36-16678 7 30109ND90.7 84.5
bis(2-Ethylhexyl)phthalate ug/L 109 95 8-15886 10 30109ND10393.0
Butylbenzylphthalate ug/L 109 96 1-15286 11 30109ND10493.4
Chrysene ug/L 109 123 17-168115 7 30109ND134125
Di-n-butylphthalate ug/L 109 91 1-11884 7 30109ND98.4 91.5
Di-n-octylphthalate ug/L 109 91 4-14684 8 30109ND98.8 91.1
Dibenz(a,h)anthracene ug/L 109 100 1-22788 13 30109ND10995.9
Diethylphthalate ug/L 109 91 1-11486 6 30109ND99.2 93.3
Dimethylphthalate ug/L 109 87 1-11284 3 30109ND94.1 91.0
Fluoranthene ug/L 109 105 26-13799 6 30109ND114107
Fluorene ug/L 109 101 59-12195 6 30109ND110103
Hexachloro-1,3-butadiene ug/L 109 81 24-11677 5 30109ND87.7 83.6
Hexachlorobenzene ug/L 109 112 1-152104 7 30109ND122113
Hexachlorocyclopentadiene ug/L 109 78 25-15080 2 30109ND84.5 86.5
Hexachloroethane ug/L 109 69 40-11364 8 30109ND75.2 69.2
Indeno(1,2,3-cd)pyrene ug/L 109 93 1-17185 8 30109ND10192.8
Isophorone ug/L 109 93 21-19688 5 30109ND10195.5
N-Nitroso-di-n-propylamine ug/L 109 94 1-23085 9 30109ND10292.7
N-Nitrosodimethylamine ug/L 109 94 25-15091 3 30109ND10298.6
N-Nitrosodiphenylamine ug/L 109 102 25-15097 5 30109ND111105
Naphthalene ug/L 109 82 21-13378 4 30109ND88.6 84.8
Nitrobenzene ug/L 109 155 35-180163 5 30109ND169177
Pentachlorophenol ug/L M0,R15431314-17631 80 30543ND72.3 169
Phenanthrene ug/L 109 100 54-12094 6 30109ND109102
Phenol ug/L 109 57 5-11255 4 30109ND61.8 59.4
Pyrene ug/L 109 113 52-115101 11 30109ND123110
2,4,6-Tribromophenol (S)%60 10-13788
2-Fluorobiphenyl (S)%84 15-12080
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 50 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
423074MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9266362001
423075
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
2-Fluorophenol (S)%60 10-12058
Nitrobenzene-d5 (S)%87 10-12085
Phenol-d6 (S)%48 10-12046
Terphenyl-d14 (S)%107 11-13196
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 51 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/9645
EPA 3546
EPA 8270
8270 Solid MSSV Microwave
Associated Lab Samples:9266446001, 9266446002, 9266446003, 9266446004, 9266446005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:423106
Associated Lab Samples:9266446001, 9266446002, 9266446003, 9266446004, 9266446005
Matrix:Solid
Analyzed
1,2,4-Trichlorobenzene mg/kg ND 0.33 04/06/10 18:36
1,2-Dichlorobenzene mg/kg ND 0.33 04/06/10 18:36
1,3-Dichlorobenzene mg/kg ND 0.33 04/06/10 18:36
1,4-Dichlorobenzene mg/kg ND 0.33 04/06/10 18:36
1-Methylnaphthalene mg/kg ND 0.33 04/06/10 18:36
2,4,5-Trichlorophenol mg/kg ND 0.33 04/06/10 18:36
2,4,6-Trichlorophenol mg/kg ND 0.33 04/06/10 18:36
2,4-Dichlorophenol mg/kg ND 0.33 04/06/10 18:36
2,4-Dimethylphenol mg/kg ND 0.33 04/06/10 18:36
2,4-Dinitrophenol mg/kg ND 1.6 04/06/10 18:36
2,4-Dinitrotoluene mg/kg ND 0.33 04/06/10 18:36
2,6-Dinitrotoluene mg/kg ND 0.33 04/06/10 18:36
2-Chloronaphthalene mg/kg ND 0.33 04/06/10 18:36
2-Chlorophenol mg/kg ND 0.33 04/06/10 18:36
2-Methylnaphthalene mg/kg ND 0.33 04/06/10 18:36
2-Methylphenol(o-Cresol)mg/kg ND 0.33 04/06/10 18:36
2-Nitroaniline mg/kg ND 1.6 04/06/10 18:36
2-Nitrophenol mg/kg ND 0.33 04/06/10 18:36
3&4-Methylphenol(m&p Cresol)mg/kg ND 0.33 04/06/10 18:36
3,3'-Dichlorobenzidine mg/kg ND 1.6 04/06/10 18:36
3-Nitroaniline mg/kg ND 1.6 04/06/10 18:36
4,6-Dinitro-2-methylphenol mg/kg ND 0.66 04/06/10 18:36
4-Bromophenylphenyl ether mg/kg ND 0.33 04/06/10 18:36
4-Chloro-3-methylphenol mg/kg ND 0.66 04/06/10 18:36
4-Chloroaniline mg/kg ND 1.6 04/06/10 18:36
4-Chlorophenylphenyl ether mg/kg ND 0.33 04/06/10 18:36
4-Nitroaniline mg/kg ND 0.66 04/06/10 18:36
4-Nitrophenol mg/kg ND 1.6 04/06/10 18:36
Acenaphthene mg/kg ND 0.33 04/06/10 18:36
Acenaphthylene mg/kg ND 0.33 04/06/10 18:36
Anthracene mg/kg ND 0.33 04/06/10 18:36
Benzo(a)anthracene mg/kg ND 0.33 04/06/10 18:36
Benzo(a)pyrene mg/kg ND 0.33 04/06/10 18:36
Benzo(b)fluoranthene mg/kg ND 0.33 04/06/10 18:36
Benzo(g,h,i)perylene mg/kg ND 0.33 04/06/10 18:36
Benzo(k)fluoranthene mg/kg ND 0.33 04/06/10 18:36
Benzoic Acid mg/kg ND 1.6 04/06/10 18:36
Benzyl alcohol mg/kg ND 0.66 04/06/10 18:36
bis(2-Chloroethoxy)methane mg/kg ND 0.33 04/06/10 18:36
bis(2-Chloroethyl) ether mg/kg ND 0.33 04/06/10 18:36
bis(2-Chloroisopropyl) ether mg/kg ND 0.33 04/06/10 18:36
bis(2-Ethylhexyl)phthalate mg/kg ND 0.33 04/06/10 18:36
Butylbenzylphthalate mg/kg ND 0.33 04/06/10 18:36
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 52 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:423106
Associated Lab Samples:9266446001, 9266446002, 9266446003, 9266446004, 9266446005
Matrix:Solid
Analyzed
Chrysene mg/kg ND 0.33 04/06/10 18:36
Di-n-butylphthalate mg/kg ND 0.33 04/06/10 18:36
Di-n-octylphthalate mg/kg ND 0.33 04/06/10 18:36
Dibenz(a,h)anthracene mg/kg ND 0.33 04/06/10 18:36
Dibenzofuran mg/kg ND 0.33 04/06/10 18:36
Diethylphthalate mg/kg ND 0.33 04/06/10 18:36
Dimethylphthalate mg/kg ND 0.33 04/06/10 18:36
Fluoranthene mg/kg ND 0.33 04/06/10 18:36
Fluorene mg/kg ND 0.33 04/06/10 18:36
Hexachloro-1,3-butadiene mg/kg ND 0.33 04/06/10 18:36
Hexachlorobenzene mg/kg ND 0.33 04/06/10 18:36
Hexachlorocyclopentadiene mg/kg ND 0.33 04/06/10 18:36
Hexachloroethane mg/kg ND 0.33 04/06/10 18:36
Indeno(1,2,3-cd)pyrene mg/kg ND 0.33 04/06/10 18:36
Isophorone mg/kg ND 0.33 04/06/10 18:36
N-Nitroso-di-n-propylamine mg/kg ND 0.33 04/06/10 18:36
N-Nitrosodimethylamine mg/kg ND 0.33 04/06/10 18:36
N-Nitrosodiphenylamine mg/kg ND 0.33 04/06/10 18:36
Naphthalene mg/kg ND 0.33 04/06/10 18:36
Nitrobenzene mg/kg ND 0.33 04/06/10 18:36
Pentachlorophenol mg/kg ND 1.6 04/06/10 18:36
Phenanthrene mg/kg ND 0.33 04/06/10 18:36
Phenol mg/kg ND 0.33 04/06/10 18:36
Pyrene mg/kg ND 0.33 04/06/10 18:36
2,4,6-Tribromophenol (S)%63 40-130 04/06/10 18:36
2-Fluorobiphenyl (S)%69 30-120 04/06/10 18:36
2-Fluorophenol (S)%66 24-120 04/06/10 18:36
Nitrobenzene-d5 (S)%72 30-120 04/06/10 18:36
Phenol-d6 (S)%63 35-120 04/06/10 18:36
Terphenyl-d14 (S)%81 35-108 04/06/10 18:36
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
423107LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
423108
1,2,4-Trichlorobenzene mg/kg 1.3 L2,R11.7 76 50-150360.59 73 30
1,2-Dichlorobenzene mg/kg 1.2 L2,R11.7 73 50-150340.57 72 30
1,3-Dichlorobenzene mg/kg 1.2 L2,R11.7 75 50-150350.58 73 30
1,4-Dichlorobenzene mg/kg 1.2 L2,R11.7 72 50-150340.56 73 30
1-Methylnaphthalene mg/kg 1.3 L2,R11.7 77 50-150340.57 77 30
2,4,5-Trichlorophenol mg/kg 1.4 L2,R11.7 87 50-150370.62 80 30
2,4,6-Trichlorophenol mg/kg 1.5 L2,R11.7 90 50-150360.59 86 30
2,4-Dichlorophenol mg/kg 1.4 L2,R11.7 84 50-150330.55 87 30
2,4-Dimethylphenol mg/kg 1.2 L2,R11.7 73 50-150310.52 80 30
2,4-Dinitrophenol mg/kg 6.4 L2,R18.3 76 20-111433.6 56 30
2,4-Dinitrotoluene mg/kg 1.5 L2,R11.7 91 50-150400.67 78 30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 53 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
423107LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
423108
2,6-Dinitrotoluene mg/kg 1.7 L2,R11.7 101 50-150460.77 75 30
2-Chloronaphthalene mg/kg 1.5 L2,R11.7 90 50-150370.61 84 30
2-Chlorophenol mg/kg 1.2 L2,R11.7 71 50-150310.51 79 30
2-Methylnaphthalene mg/kg 1.3 L2,R11.7 78 50-150340.56 79 30
2-Methylphenol(o-Cresol)mg/kg 1.2 L2,R11.7 73 50-150290.48 86 30
2-Nitroaniline mg/kg 9.6 L2,R18.3 115 50-150534.4 74 30
2-Nitrophenol mg/kg 1.2 L2,R11.7 71 50-150310.52 77 30
3&4-Methylphenol(m&p Cresol)mg/kg 1.3 L2,R11.7 79 50-150320.53 85 30
3,3'-Dichlorobenzidine mg/kg 8.1 L2,R18.3 98 50-150463.8 72 30
3-Nitroaniline mg/kg 8.1 L2,R18.3 97 50-150443.7 75 30
4,6-Dinitro-2-methylphenol mg/kg 2.9 L2,R13.3 87 15-136361.2 83 30
4-Bromophenylphenyl ether mg/kg 1.4 L2,R11.7 85 50-150390.66 73 30
4-Chloro-3-methylphenol mg/kg 3.0 L2,R13.3 90 50-150411.4 76 30
4-Chloroaniline mg/kg 7.3 L2,R18.3 87 50-150352.9 85 30
4-Chlorophenylphenyl ether mg/kg 1.5 L2,R11.7 87 50-150380.63 79 30
4-Nitroaniline mg/kg 8.3 L2,R18.3 99 50-150463.8 73 30
4-Nitrophenol mg/kg 10.3 L1,L2,R18.3 124 33-105615.1 68 30
Acenaphthene mg/kg 1.4 L2,R11.7 83 50-150350.58 82 30
Acenaphthylene mg/kg 1.4 L2,R11.7 81 50-150350.58 81 30
Anthracene mg/kg 1.5 L2,R11.7 88 50-150410.69 73 30
Benzo(a)anthracene mg/kg 1.5 L2,R11.7 90 50-150480.80 61 30
Benzo(a)pyrene mg/kg 1.3 L2,R11.7 78 50-150220.37 111 30
Benzo(b)fluoranthene mg/kg 1.4 L2,R11.7 82 50-150410.68 67 30
Benzo(g,h,i)perylene mg/kg 1.3 L2,R11.7 79 24-117390.66 67 30
Benzo(k)fluoranthene mg/kg 1.4 L2,R11.7 81 50-150400.67 67 30
Benzoic Acid mg/kg 3.6 L2,R18.3 43 15-104252.1 53 30
Benzyl alcohol mg/kg 2.7 L2,R13.3 81 50-150311.0 90 30
bis(2-Chloroethoxy)methane mg/kg 1.2 L2,R11.7 70 50-150290.49 82 30
bis(2-Chloroethyl) ether mg/kg 1.1 L2,R11.7 68 50-150290.48 80 30
bis(2-Chloroisopropyl) ether mg/kg 1.2 L2,R11.7 69 50-150310.51 78 30
bis(2-Ethylhexyl)phthalate mg/kg 1.5 L2,R11.7 89 50-150440.73 68 30
Butylbenzylphthalate mg/kg 1.5 L2,R11.7 91 50-150440.73 70 30
Chrysene mg/kg 1.5 L2,R11.7 89 50-150470.78 61 30
Di-n-butylphthalate mg/kg 1.5 L2,R11.7 90 50-150430.71 72 30
Di-n-octylphthalate mg/kg 1.4 L2,R11.7 82 50-150430.71 64 30
Dibenz(a,h)anthracene mg/kg 1.5 L2,R11.7 89 17-128420.71 71 30
Dibenzofuran mg/kg 1.4 L2,R11.7 87 50-150370.62 80 30
Diethylphthalate mg/kg 1.6 L2,R11.7 95 50-150440.74 73 30
Dimethylphthalate mg/kg 1.5 L2,R11.7 93 50-150440.73 72 30
Fluoranthene mg/kg 1.5 L2,R11.7 92 50-150440.74 70 30
Fluorene mg/kg 1.5 L2,R11.7 90 50-150400.67 77 30
Hexachloro-1,3-butadiene mg/kg 1.3 L2,R11.7 77 50-150370.62 70 30
Hexachlorobenzene mg/kg 1.7 L2,R11.7 102 50-150480.80 73 30
Hexachlorocyclopentadiene mg/kg 1.2 L2,R11.7 71 15-114270.45 91 30
Hexachloroethane mg/kg 1.3 L2,R11.7 77 50-150360.59 73 30
Indeno(1,2,3-cd)pyrene mg/kg 1.4 L2,R11.7 84 19-128410.68 70 30
Isophorone mg/kg 1.5 L2,R11.7 88 50-150390.65 77 30
N-Nitroso-di-n-propylamine mg/kg 1.6 L2,R11.7 93 50-150350.58 91 30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 54 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
423107LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
423108
N-Nitrosodimethylamine mg/kg 1.8 R11.7 106 50-150500.84 71 30
N-Nitrosodiphenylamine mg/kg 1.6 L2,R11.7 98 50-150460.77 72 30
Naphthalene mg/kg 1.2 L2,R11.7 71 50-150320.53 76 30
Nitrobenzene mg/kg 1.3 L2,R11.7 79 50-150340.56 80 30
Pentachlorophenol mg/kg 8.3 L2,R18.3 100 15-130393.3 87 30
Phenanthrene mg/kg 1.5 L2,R11.7 92 50-150430.72 73 30
Phenol mg/kg 1.3 L2,R11.7 78 42-120310.51 87 30
Pyrene mg/kg 1.6 L2,R11.7 98 50-150470.78 71 30
2,4,6-Tribromophenol (S)%92 40-13042
2-Fluorobiphenyl (S)%79 30-12032
2-Fluorophenol (S)%66 24-12029
Nitrobenzene-d5 (S)%75 30-12032
Phenol-d6 (S)%S07135-12029
Terphenyl-d14 (S)%92 35-10844
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
423109MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9266446002
423110
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,2,4-Trichlorobenzene mg/kg M0,R11.9 35 50-15052 39 301.9ND 0.64 0.94
1,2-Dichlorobenzene mg/kg M0,R11.9 31 50-15047 41 301.9ND 0.57 0.87
1,3-Dichlorobenzene mg/kg M0,R11.9 32 50-15050 42 301.9ND 0.59 0.90
1,4-Dichlorobenzene mg/kg M0,R11.9 31 50-15049 43 301.9ND 0.57 0.89
1-Methylnaphthalene mg/kg M0,R11.9 38 50-15061 46 301.9ND 0.70 1.1
2,4,5-Trichlorophenol mg/kg M0,R11.9 49 50-15073 38 301.9ND 0.90 1.3
2,4,6-Trichlorophenol mg/kg M0,R11.9 47 50-15074 43 301.9ND 0.87 1.3
2,4-Dichlorophenol mg/kg M0,R11.9 40 50-15068 51 301.9ND 0.74 1.2
2,4-Dimethylphenol mg/kg M0,R11.9 39 50-15065 51 301.9ND 0.70 1.2
2,4-Dinitrophenol mg/kg R19.1 51 50-15075 37 309.1ND 4.7 6.8
2,4-Dinitrotoluene mg/kg R11.9 52 50-15077 39 301.9ND 0.95 1.4
2,6-Dinitrotoluene mg/kg R11.9 58 50-15084 37 301.9ND 1.1 1.5
2-Chloronaphthalene mg/kg M0,R11.9 45 50-15072 46 301.9ND 0.82 1.3
2-Chlorophenol mg/kg M0,R11.9 30 50-15047 45 301.9ND 0.55 0.86
2-Methylnaphthalene mg/kg M0,R11.9 36 50-15061 51 301.9ND 0.66 1.1
2-Methylphenol(o-Cresol)mg/kg M0,R11.9 33 50-15056 53 301.9ND 0.60 1.0
2-Nitroaniline mg/kg R19.1 71 50-150103 37 309.1ND 6.5 9.4
2-Nitrophenol mg/kg M0,R11.9 33 50-15052 45 301.9ND 0.60 0.95
3&4-Methylphenol(m&pCresol)mg/kg M0,R11.9 38 50-15063 50 301.9ND 0.69 1.1
3,3'-Dichlorobenzidine mg/kg R19.1 53 50-15078 38 309.1ND 4.8 7.1
3-Nitroaniline mg/kg R19.1 58 50-15081 34 309.1ND 5.3 7.4
4,6-Dinitro-2-methylphenol mg/kg M0,R13.6 48 50-15077 46 303.6ND 1.8 2.8
4-Bromophenylphenyl ether mg/kg R11.9 50 50-15070 33 301.9ND 0.91 1.3
4-Chloro-3-methylphenol mg/kg R13.6 51 50-15079 43 303.6ND 1.9 2.9
4-Chloroaniline mg/kg M0,R19.1 42 50-15070 50 309.1ND 3.9 6.4
4-Chlorophenylphenyl ether mg/kg M0,R11.9 47 50-15073 42 301.9ND 0.87 1.3
4-Nitroaniline mg/kg R19.1 59 50-15083 35 309.1ND 5.3 7.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 55 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
423109MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9266446002
423110
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
4-Nitrophenol mg/kg R19.1 73 50-150108 39 309.1ND 6.6 9.9
Acenaphthene mg/kg M0,R11.9 44 50-15068 44 301.9ND 0.80 1.2
Acenaphthylene mg/kg M0,R11.9 44 50-15070 46 301.9ND 0.80 1.3
Anthracene mg/kg R11.9 51 50-15073 36 301.9ND 0.94 1.3
Benzo(a)anthracene mg/kg R11.9 52 50-15073 34 301.9ND 0.95 1.3
Benzo(a)pyrene mg/kg M0,R11.9 23 50-15065 95 301.9ND 0.42 1.2
Benzo(b)fluoranthene mg/kg M0,R11.9 45 50-15065 35 301.9ND 0.87 1.2
Benzo(g,h,i)perylene mg/kg M01.9 48 50-15064 29 301.9ND 0.87 1.2
Benzo(k)fluoranthene mg/kg M0,R11.9 49 50-15066 31 301.9ND 0.89 1.2
Benzoic Acid mg/kg M0,R19.1 38 50-15059 43 309.1ND 3.5 5.4
Benzyl alcohol mg/kg M0,R13.6 36 50-15062 54 303.6ND 1.3 2.3
bis(2-Chloroethoxy)methane mg/kg M0,R11.9 33 50-15055 49 301.9ND 0.61 1.0
bis(2-Chloroethyl) ether mg/kg M0,R11.9 31 50-15046 40 301.9ND 0.56 0.84
bis(2-Chloroisopropyl) ether mg/kg M0,R11.9 33 50-15051 44 301.9ND 0.60 0.94
bis(2-Ethylhexyl)phthalate mg/kg R11.9 52 50-15072 32 301.9ND 0.95 1.3
Butylbenzylphthalate mg/kg 1.9 55 50-15075 30 301.9ND 1.0 1.4
Chrysene mg/kg R11.9 51 50-15073 37 301.9ND 0.92 1.3
Di-n-butylphthalate mg/kg R11.9 51 50-15072 34 301.9ND 0.93 1.3
Di-n-octylphthalate mg/kg M0,R11.9 48 50-15067 34 301.9ND 0.87 1.2
Dibenz(a,h)anthracene mg/kg R11.9 52 50-15072 33 301.9ND 0.95 1.3
Dibenzofuran mg/kg M0,R11.9 48 50-15073 41 301.9ND 0.88 1.3
Diethylphthalate mg/kg R11.9 56 50-15079 35 301.9ND 1.0 1.5
Dimethylphthalate mg/kg R11.9 55 50-15077 34 301.9ND 1.0 1.4
Fluoranthene mg/kg R11.9 50 50-15072 37 301.9ND 0.92 1.3
Fluorene mg/kg R11.9 51 50-15077 40 301.9ND 0.94 1.4
Hexachloro-1,3-butadiene mg/kg M0,R11.9 33 50-15050 41 301.9ND 0.59 0.91
Hexachlorobenzene mg/kg R11.9 57 50-15081 36 301.9ND 1.0 1.5
Hexachlorocyclopentadiene mg/kg M0,R11.9 29 50-15056 64 301.9ND 0.53 1.0
Hexachloroethane mg/kg M0,R11.9 34 50-15052 43 301.9ND 0.62 0.96
Indeno(1,2,3-cd)pyrene mg/kg R11.9 50 50-15070 34 301.9ND 0.91 1.3
Isophorone mg/kg M0,R11.9 47 50-15079 50 301.9ND 0.87 1.4
N-Nitroso-di-n-propylamine mg/kg M0,R11.9 45 50-15079 55 301.9ND 0.82 1.4
N-Nitrosodimethylamine mg/kg R11.9 53 50-15077 37 301.9ND 0.97 1.4
N-Nitrosodiphenylamine mg/kg R11.9 58 50-15083 35 301.9ND 1.1 1.5
Naphthalene mg/kg M0,R11.9 33 50-15048 36 301.9ND 0.61 0.87
Nitrobenzene mg/kg M0,R11.9 37 50-15056 41 301.9ND 0.67 1.0
Pentachlorophenol mg/kg R19.1 50 50-15079 46 309.1ND 4.5 7.2
Phenanthrene mg/kg R11.9 53 50-15076 35 301.9ND 0.98 1.4
Phenol mg/kg M0,R11.9 33 50-15053 45 301.9ND 0.61 0.97
Pyrene mg/kg 1.9 61 50-15080 28 301.9ND 1.1 1.5
2,4,6-Tribromophenol (S)%51 40-13076
2-Fluorobiphenyl (S)%39 30-12065
2-Fluorophenol (S)%28 24-12046
Nitrobenzene-d5 (S)%35 30-12054
Phenol-d6 (S)%S03135-12051
Terphenyl-d14 (S)%54 35-10872
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 56 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/10491
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:9266446006, 9266446007, 9266446008, 9266446009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:423586
Associated Lab Samples:9266446006, 9266446007, 9266446008, 9266446009
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 04/02/10 00:58
1,1,1-Trichloroethane ug/L ND 0.50 04/02/10 00:58
1,1,2,2-Tetrachloroethane ug/L ND 0.50 04/02/10 00:58
1,1,2-Trichloroethane ug/L ND 0.50 04/02/10 00:58
1,1-Dichloroethane ug/L ND 0.50 04/02/10 00:58
1,1-Dichloroethene ug/L ND 0.50 04/02/10 00:58
1,1-Dichloropropene ug/L ND 0.50 04/02/10 00:58
1,2,3-Trichlorobenzene ug/L ND 2.0 04/02/10 00:58
1,2,3-Trichloropropane ug/L ND 0.50 04/02/10 00:58
1,2,4-Trichlorobenzene ug/L ND 2.0 04/02/10 00:58
1,2,4-Trimethylbenzene ug/L ND 0.50 04/02/10 00:58
1,2-Dibromo-3-chloropropane ug/L ND 1.0 04/02/10 00:58
1,2-Dibromoethane (EDB)ug/L ND 0.50 04/02/10 00:58
1,2-Dichlorobenzene ug/L ND 0.50 04/02/10 00:58
1,2-Dichloroethane ug/L ND 0.50 04/02/10 00:58
1,2-Dichloropropane ug/L ND 0.50 04/02/10 00:58
1,3,5-Trimethylbenzene ug/L ND 0.50 04/02/10 00:58
1,3-Dichlorobenzene ug/L ND 0.50 04/02/10 00:58
1,3-Dichloropropane ug/L ND 0.50 04/02/10 00:58
1,4-Dichlorobenzene ug/L ND 0.50 04/02/10 00:58
2,2-Dichloropropane ug/L ND 0.50 04/02/10 00:58
2-Chlorotoluene ug/L ND 0.50 04/02/10 00:58
4-Chlorotoluene ug/L ND 0.50 04/02/10 00:58
Benzene ug/L ND 0.50 04/02/10 00:58
Bromobenzene ug/L ND 0.50 04/02/10 00:58
Bromochloromethane ug/L ND 0.50 04/02/10 00:58
Bromodichloromethane ug/L ND 0.50 04/02/10 00:58
Bromoform ug/L ND 0.50 04/02/10 00:58
Bromomethane ug/L ND 5.0 04/02/10 00:58
Carbon tetrachloride ug/L ND 0.50 04/02/10 00:58
Chlorobenzene ug/L ND 0.50 04/02/10 00:58
Chloroethane ug/L ND 1.0 04/02/10 00:58
Chloroform ug/L ND 0.50 04/02/10 00:58
Chloromethane ug/L ND 1.0 04/02/10 00:58
cis-1,2-Dichloroethene ug/L ND 0.50 04/02/10 00:58
cis-1,3-Dichloropropene ug/L ND 0.50 04/02/10 00:58
Dibromochloromethane ug/L ND 0.50 04/02/10 00:58
Dibromomethane ug/L ND 0.50 04/02/10 00:58
Dichlorodifluoromethane ug/L ND 0.50 04/02/10 00:58
Diisopropyl ether ug/L ND 0.50 04/02/10 00:58
Ethylbenzene ug/L ND 0.50 04/02/10 00:58
Hexachloro-1,3-butadiene ug/L ND 2.0 04/02/10 00:58
Isopropylbenzene (Cumene)ug/L ND 0.50 04/02/10 00:58
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 57 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:423586
Associated Lab Samples:9266446006, 9266446007, 9266446008, 9266446009
Matrix:Water
Analyzed
m&p-Xylene ug/L ND 1.0 04/02/10 00:58
Methyl-tert-butyl ether ug/L ND 0.50 04/02/10 00:58
Methylene Chloride ug/L ND 2.0 04/02/10 00:58
n-Butylbenzene ug/L ND 0.50 04/02/10 00:58
n-Propylbenzene ug/L ND 0.50 04/02/10 00:58
Naphthalene ug/L ND 2.0 04/02/10 00:58
o-Xylene ug/L ND 0.50 04/02/10 00:58
sec-Butylbenzene ug/L ND 0.50 04/02/10 00:58
Styrene ug/L ND 0.50 04/02/10 00:58
tert-Butylbenzene ug/L ND 0.50 04/02/10 00:58
Tetrachloroethene ug/L ND 0.50 04/02/10 00:58
Toluene ug/L ND 0.50 04/02/10 00:58
trans-1,2-Dichloroethene ug/L ND 0.50 04/02/10 00:58
trans-1,3-Dichloropropene ug/L ND 0.50 04/02/10 00:58
Trichloroethene ug/L ND 0.50 04/02/10 00:58
Trichlorofluoromethane ug/L ND 1.0 04/02/10 00:58
Vinyl chloride ug/L ND 1.0 04/02/10 00:58
1,2-Dichloroethane-d4 (S)%104 70-130 04/02/10 00:58
4-Bromofluorobenzene (S)%96 70-130 04/02/10 00:58
Dibromofluoromethane (S)%103 70-130 04/02/10 00:58
Toluene-d8 (S)%100 70-130 04/02/10 00:58
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
423587LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 52.150 104 60-140
1,1,1-Trichloroethane ug/L 50.850 102 60-140
1,1,2,2-Tetrachloroethane ug/L 53.150 106 60-140
1,1,2-Trichloroethane ug/L 49.250 98 60-140
1,1-Dichloroethane ug/L 49.650 99 60-140
1,1-Dichloroethene ug/L 48.450 97 60-140
1,1-Dichloropropene ug/L 48.250 96 60-140
1,2,3-Trichlorobenzene ug/L 49.850 100 60-140
1,2,3-Trichloropropane ug/L 54.150 108 60-140
1,2,4-Trichlorobenzene ug/L 48.750 97 60-140
1,2,4-Trimethylbenzene ug/L 50.250 100 60-140
1,2-Dibromo-3-chloropropane ug/L 52.050 104 60-140
1,2-Dibromoethane (EDB)ug/L 51.250 102 60-140
1,2-Dichlorobenzene ug/L 50.350 101 60-140
1,2-Dichloroethane ug/L 48.450 97 60-140
1,2-Dichloropropane ug/L 45.950 92 60-140
1,3,5-Trimethylbenzene ug/L 51.950 104 60-140
1,3-Dichlorobenzene ug/L 49.350 99 60-140
1,3-Dichloropropane ug/L 49.050 98 60-140
1,4-Dichlorobenzene ug/L 48.450 97 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 58 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
423587LABORATORY CONTROL SAMPLE:
LCSSpike
2,2-Dichloropropane ug/L 43.350 87 60-140
2-Chlorotoluene ug/L 50.650 101 60-140
4-Chlorotoluene ug/L 51.550 103 60-140
Benzene ug/L 46.950 94 60-140
Bromobenzene ug/L 49.250 98 60-140
Bromochloromethane ug/L 46.850 94 60-140
Bromodichloromethane ug/L 49.350 99 60-140
Bromoform ug/L 50.950 102 60-140
Bromomethane ug/L 44.550 89 60-140
Carbon tetrachloride ug/L 48.750 97 60-140
Chlorobenzene ug/L 49.050 98 60-140
Chloroethane ug/L 31.050 62 60-140
Chloroform ug/L 47.650 95 60-140
Chloromethane ug/L 43.850 88 60-140
cis-1,2-Dichloroethene ug/L 46.950 94 60-140
cis-1,3-Dichloropropene ug/L 36.250 72 60-140
Dibromochloromethane ug/L 49.950 100 60-140
Dibromomethane ug/L 48.050 96 60-140
Dichlorodifluoromethane ug/L 49.450 99 60-140
Diisopropyl ether ug/L 44.350 89 60-140
Ethylbenzene ug/L 48.450 97 60-140
Hexachloro-1,3-butadiene ug/L 49.350 99 60-140
Isopropylbenzene (Cumene)ug/L 50.750 101 60-140
m&p-Xylene ug/L 95.3100 95 60-140
Methyl-tert-butyl ether ug/L 51.050 102 60-140
Methylene Chloride ug/L 44.050 88 60-140
n-Butylbenzene ug/L 50.050 100 60-140
n-Propylbenzene ug/L 50.150 100 60-140
Naphthalene ug/L 51.550 103 60-140
o-Xylene ug/L 48.850 98 60-140
sec-Butylbenzene ug/L 51.650 103 60-140
Styrene ug/L 52.850 106 60-140
tert-Butylbenzene ug/L 50.950 102 60-140
Tetrachloroethene ug/L 48.350 97 60-140
Toluene ug/L 47.550 95 60-140
trans-1,2-Dichloroethene ug/L 46.050 92 60-140
trans-1,3-Dichloropropene ug/L 37.450 75 60-140
Trichloroethene ug/L 47.250 94 60-140
Trichlorofluoromethane ug/L 47.450 95 60-140
Vinyl chloride ug/L 45.850 92 60-140
1,2-Dichloroethane-d4 (S)%103 70-130
4-Bromofluorobenzene (S)%100 70-130
Dibromofluoromethane (S)%104 70-130
Toluene-d8 (S)%100 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 59 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
423588MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9266446006
423589
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 99 60-140111 12 3020ND19.7 22.2
1,1,1-Trichloroethane ug/L 20 107 60-140116 8 3020ND21.4 23.1
1,1,2,2-Tetrachloroethane ug/L 20 101 60-140114 12 3020ND20.3 22.8
1,1,2-Trichloroethane ug/L 20 101 60-140113 11 3020ND20.3 22.6
1,1-Dichloroethane ug/L 20 103 60-140115 11 3020ND20.7 23.0
1,1-Dichloroethene ug/L 20 102 60-140103 1 3020ND20.4 20.7
1,1-Dichloropropene ug/L 20 94 60-140103 9 3020ND18.9 20.7
1,2,3-Trichlorobenzene ug/L 20 96 60-140122 24 3020ND19.2 24.3
1,2,3-Trichloropropane ug/L 20 111 60-140122 9 3020ND22.3 24.5
1,2,4-Trichlorobenzene ug/L 20 91 60-140114 22 3020ND18.3 22.8
1,2,4-Trimethylbenzene ug/L 20 102 60-140116 13 3020ND20.4 23.2
1,2-Dibromo-3-chloropropane ug/L 20 102 60-140114 11 3020ND20.5 22.8
1,2-Dibromoethane (EDB)ug/L 20 101 60-140113 12 3020ND20.2 22.7
1,2-Dichlorobenzene ug/L 20 99 60-140115 15 3020ND19.8 22.9
1,2-Dichloroethane ug/L 20 96 60-140106 9 30200.58 19.8 21.7
1,2-Dichloropropane ug/L 20 97 60-140106 9 3020ND19.4 21.1
1,3,5-Trimethylbenzene ug/L 20 105 60-140117 11 3020ND21.1 23.5
1,3-Dichlorobenzene ug/L 20 98 60-140113 14 3020ND19.6 22.6
1,3-Dichloropropane ug/L 20 98 60-140109 11 3020ND19.5 21.8
1,4-Dichlorobenzene ug/L 20 95 60-140110 15 3020ND19.0 22.0
2,2-Dichloropropane ug/L 20 63 60-14073 15 3020ND12.6 14.6
2-Chlorotoluene ug/L 20 102 60-140116 14 3020ND20.3 23.3
4-Chlorotoluene ug/L 20 105 60-140117 11 3020ND21.0 23.4
Benzene ug/L 20 96 60-140107 10 3020ND19.5 21.6
Bromobenzene ug/L 20 101 60-140110 8 3020ND20.2 21.9
Bromochloromethane ug/L 20 105 60-140116 10 3020ND21.0 23.2
Bromodichloromethane ug/L 20 92 60-140104 12 3020ND18.4 20.7
Bromoform ug/L 20 89 60-140103 15 3020ND17.8 20.6
Bromomethane ug/L 20 101 60-140104 3 3020ND20.1 20.8
Carbon tetrachloride ug/L 20 111 60-140116 5 3020ND22.1 23.2
Chlorobenzene ug/L 20 102 60-140112 9 3020ND20.4 22.4
Chloroethane ug/L 20 110 60-140109 0 3020ND22.0 21.9
Chloroform ug/L 20 99 60-140109 10 3020ND19.7 21.7
Chloromethane ug/L 20 80 60-14085 6 3020ND16.0 16.9
cis-1,2-Dichloroethene ug/L 20 97 60-140107 10 3020ND19.4 21.4
cis-1,3-Dichloropropene ug/L 20 68 60-14078 15 3020ND13.5 15.6
Dibromochloromethane ug/L 20 91 60-140102 12 3020ND18.1 20.3
Dibromomethane ug/L 20 100 60-140112 11 3020ND20.1 22.4
Dichlorodifluoromethane ug/L 20 115 60-140122 6 3020ND22.9 24.4
Diisopropyl ether ug/L 20 90 60-140102 12 3020ND18.1 20.3
Ethylbenzene ug/L 20 101 60-140108 6 3020ND20.2 21.5
Hexachloro-1,3-butadiene ug/L 20 99 60-140114 13 3020ND19.9 22.8
Isopropylbenzene (Cumene)ug/L 20 105 60-140120 14 3020ND21.0 24.1
m&p-Xylene ug/L 40 101 60-140111 9 3040ND40.5 44.5
Methyl-tert-butyl ether ug/L 20 117 60-140121 4 3020ND23.4 24.2
Methylene Chloride ug/L 20 87 60-14096 10 3020ND17.5 19.2
n-Butylbenzene ug/L 20 98 60-140117 17 3020ND19.6 23.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 60 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
423588MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9266446006
423589
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
n-Propylbenzene ug/L 20 107 60-140119 11 3020ND21.3 23.9
Naphthalene ug/L 20 111 60-140125 12 3020ND22.7 25.6
o-Xylene ug/L 20 101 60-140113 11 3020ND20.2 22.7
sec-Butylbenzene ug/L 20 107 60-140126 16 3020ND21.3 25.1
Styrene ug/L 20 99 60-140111 11 3020ND19.9 22.3
tert-Butylbenzene ug/L 20 108 60-140125 15 3020ND21.6 25.0
Tetrachloroethene ug/L 20 98 60-140106 7 3020ND19.7 21.2
Toluene ug/L 20 99 60-140109 10 3020ND19.9 21.8
trans-1,2-Dichloroethene ug/L 20 93 60-140102 10 3020ND18.7 20.6
trans-1,3-Dichloropropene ug/L 20 70 60-14078 11 3020ND13.9 15.5
Trichloroethene ug/L 20 98 60-140109 11 3020ND19.6 21.8
Trichlorofluoromethane ug/L 20 115 60-14086 29 3020ND23.0 17.2
Vinyl chloride ug/L 20 103 60-140109 6 3020ND20.6 21.8
1,2-Dichloroethane-d4 (S)%103 70-130103
4-Bromofluorobenzene (S)%98 70-13098
Dibromofluoromethane (S)%105 70-130104
Toluene-d8 (S)%99 70-13099
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 61 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/10489
EPA 8260
EPA 8260
8260 MSV 5035A Volatile Organics
Associated Lab Samples:9266446001, 9266446002, 9266446003, 9266446004, 9266446005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:423213
Associated Lab Samples:9266446001, 9266446002, 9266446003, 9266446004, 9266446005
Matrix:Solid
Analyzed
1,1,1,2-Tetrachloroethane mg/kg ND 0.0050 04/01/10 12:27
1,1,1-Trichloroethane mg/kg ND 0.0050 04/01/10 12:27
1,1,2,2-Tetrachloroethane mg/kg ND 0.0050 04/01/10 12:27
1,1,2-Trichloroethane mg/kg ND 0.0050 04/01/10 12:27
1,1-Dichloroethane mg/kg ND 0.0050 04/01/10 12:27
1,1-Dichloroethene mg/kg ND 0.0050 04/01/10 12:27
1,1-Dichloropropene mg/kg ND 0.0050 04/01/10 12:27
1,2,3-Trichlorobenzene mg/kg ND 0.0050 04/01/10 12:27
1,2,3-Trichloropropane mg/kg ND 0.0050 04/01/10 12:27
1,2,4-Trichlorobenzene mg/kg ND 0.0050 04/01/10 12:27
1,2,4-Trimethylbenzene mg/kg ND 0.0050 04/01/10 12:27
1,2-Dibromo-3-chloropropane mg/kg ND 0.0050 04/01/10 12:27
1,2-Dibromoethane (EDB)mg/kg ND 0.0050 04/01/10 12:27
1,2-Dichlorobenzene mg/kg ND 0.0050 04/01/10 12:27
1,2-Dichloroethane mg/kg ND 0.0050 04/01/10 12:27
1,2-Dichloropropane mg/kg ND 0.0050 04/01/10 12:27
1,3,5-Trimethylbenzene mg/kg ND 0.0050 04/01/10 12:27
1,3-Dichlorobenzene mg/kg ND 0.0050 04/01/10 12:27
1,3-Dichloropropane mg/kg ND 0.0050 04/01/10 12:27
1,4-Dichlorobenzene mg/kg ND 0.0050 04/01/10 12:27
2,2-Dichloropropane mg/kg ND 0.0050 04/01/10 12:27
2-Butanone (MEK)mg/kg ND 0.10 04/01/10 12:27
2-Chlorotoluene mg/kg ND 0.0050 04/01/10 12:27
2-Hexanone mg/kg ND 0.050 04/01/10 12:27
4-Chlorotoluene mg/kg ND 0.0050 04/01/10 12:27
4-Methyl-2-pentanone (MIBK)mg/kg ND 0.050 04/01/10 12:27
Acetone mg/kg ND 0.10 04/01/10 12:27
Benzene mg/kg ND 0.0050 04/01/10 12:27
Bromobenzene mg/kg ND 0.0050 04/01/10 12:27
Bromochloromethane mg/kg ND 0.0050 04/01/10 12:27
Bromodichloromethane mg/kg ND 0.0050 04/01/10 12:27
Bromoform mg/kg ND 0.0050 04/01/10 12:27
Bromomethane mg/kg ND 0.010 04/01/10 12:27
Carbon tetrachloride mg/kg ND 0.0050 04/01/10 12:27
Chlorobenzene mg/kg ND 0.0050 04/01/10 12:27
Chloroethane mg/kg ND 0.010 04/01/10 12:27
Chloroform mg/kg ND 0.0050 04/01/10 12:27
Chloromethane mg/kg ND 0.010 04/01/10 12:27
cis-1,2-Dichloroethene mg/kg ND 0.0050 04/01/10 12:27
cis-1,3-Dichloropropene mg/kg ND 0.0050 04/01/10 12:27
Dibromochloromethane mg/kg ND 0.0050 04/01/10 12:27
Dibromomethane mg/kg ND 0.0050 04/01/10 12:27
Dichlorodifluoromethane mg/kg ND 0.010 04/01/10 12:27
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 62 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:423213
Associated Lab Samples:9266446001, 9266446002, 9266446003, 9266446004, 9266446005
Matrix:Solid
Analyzed
Diisopropyl ether mg/kg ND 0.0050 04/01/10 12:27
Ethylbenzene mg/kg ND 0.0050 04/01/10 12:27
Hexachloro-1,3-butadiene mg/kg ND 0.0050 04/01/10 12:27
Isopropylbenzene (Cumene)mg/kg ND 0.0050 04/01/10 12:27
m&p-Xylene mg/kg ND 0.010 04/01/10 12:27
Methyl-tert-butyl ether mg/kg ND 0.0050 04/01/10 12:27
Methylene Chloride mg/kg ND 0.020 04/01/10 12:27
n-Butylbenzene mg/kg ND 0.0050 04/01/10 12:27
n-Propylbenzene mg/kg ND 0.0050 04/01/10 12:27
Naphthalene mg/kg ND 0.0050 04/01/10 12:27
o-Xylene mg/kg ND 0.0050 04/01/10 12:27
p-Isopropyltoluene mg/kg ND 0.0050 04/01/10 12:27
sec-Butylbenzene mg/kg ND 0.0050 04/01/10 12:27
Styrene mg/kg ND 0.0050 04/01/10 12:27
tert-Butylbenzene mg/kg ND 0.0050 04/01/10 12:27
Tetrachloroethene mg/kg ND 0.0050 04/01/10 12:27
Toluene mg/kg ND 0.0050 04/01/10 12:27
trans-1,2-Dichloroethene mg/kg ND 0.0050 04/01/10 12:27
trans-1,3-Dichloropropene mg/kg ND 0.0050 04/01/10 12:27
Trichloroethene mg/kg ND 0.0050 04/01/10 12:27
Trichlorofluoromethane mg/kg ND 0.0050 04/01/10 12:27
Vinyl acetate mg/kg ND 0.050 04/01/10 12:27
Vinyl chloride mg/kg ND 0.010 04/01/10 12:27
Xylene (Total)mg/kg ND 0.010 04/01/10 12:27
1,2-Dichloroethane-d4 (S)%104 69-121 04/01/10 12:27
4-Bromofluorobenzene (S)%95 74-115 04/01/10 12:27
Dibromofluoromethane (S)%104 79-116 04/01/10 12:27
Toluene-d8 (S)%100 88-110 04/01/10 12:27
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
423214LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane mg/kg 0.056.05 112 75-137
1,1,1-Trichloroethane mg/kg 0.057.05 113 70-140
1,1,2,2-Tetrachloroethane mg/kg 0.053.05 106 74-133
1,1,2-Trichloroethane mg/kg 0.055.05 111 79-129
1,1-Dichloroethane mg/kg 0.057.05 113 72-139
1,1-Dichloroethene mg/kg 0.056.05 113 69-154
1,1-Dichloropropene mg/kg 0.053.05 107 74-138
1,2,3-Trichlorobenzene mg/kg 0.057.05 114 71-150
1,2,3-Trichloropropane mg/kg 0.055.05 110 74-135
1,2,4-Trichlorobenzene mg/kg 0.055.05 110 68-150
1,2,4-Trimethylbenzene mg/kg 0.055.05 110 70-130
1,2-Dibromo-3-chloropropane mg/kg 0.055.05 109 65-146
1,2-Dibromoethane (EDB)mg/kg 0.054.05 109 77-136
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 63 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
423214LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichlorobenzene mg/kg 0.055.05 110 75-141
1,2-Dichloroethane mg/kg 0.054.05 109 74-134
1,2-Dichloropropane mg/kg 0.058.05 116 77-138
1,3,5-Trimethylbenzene mg/kg 0.055.05 110 65-128
1,3-Dichlorobenzene mg/kg 0.054.05 107 76-133
1,3-Dichloropropane mg/kg 0.055.05 110 79-132
1,4-Dichlorobenzene mg/kg 0.055.05 109 75-137
2,2-Dichloropropane mg/kg 0.057.05 114 73-137
2-Butanone (MEK)mg/kg 0.11.1 107 61-138
2-Chlorotoluene mg/kg 0.053.05 106 73-138
2-Hexanone mg/kg 0.12.1 115 58-159
4-Chlorotoluene mg/kg 0.057.05 113 75-136
4-Methyl-2-pentanone (MIBK)mg/kg 0.11.1 112 74-139
Acetone mg/kg 0.11.1 111 58-150
Benzene mg/kg 0.055.05 110 71-140
Bromobenzene mg/kg 0.056.05 113 72-144
Bromochloromethane mg/kg 0.058.05 116 78-133
Bromodichloromethane mg/kg 0.055.05 109 78-133
Bromoform mg/kg 0.057.05 114 74-132
Bromomethane mg/kg 0.059.05 118 63-184
Carbon tetrachloride mg/kg 0.060.05 119 73-143
Chlorobenzene mg/kg 0.056.05 112 77-137
Chloroethane mg/kg 0.059.05 118 68-146
Chloroform mg/kg 0.056.05 112 75-137
Chloromethane mg/kg 0.055.05 111 54-143
cis-1,2-Dichloroethene mg/kg 0.056.05 112 71-143
cis-1,3-Dichloropropene mg/kg 0.056.05 113 76-133
Dibromochloromethane mg/kg 0.056.05 112 77-131
Dibromomethane mg/kg 0.057.05 115 63-184
Dichlorodifluoromethane mg/kg 0.053.05 107 36-173
Diisopropyl ether mg/kg 0.055.05 110 68-144
Ethylbenzene mg/kg 0.055.05 111 69-141
Hexachloro-1,3-butadiene mg/kg 0.056.05 111 70-152
Isopropylbenzene (Cumene)mg/kg 0.057.05 113 77-143
m&p-Xylene mg/kg 0.11.1 114 72-138
Methyl-tert-butyl ether mg/kg 0.057.05 113 2-138
Methylene Chloride mg/kg 0.054.05 107 69-136
n-Butylbenzene mg/kg 0.054.05 108 65-128
n-Propylbenzene mg/kg 0.056.05 111 72-139
Naphthalene mg/kg 0.059.05 118 61-138
o-Xylene mg/kg 0.057.05 115 74-137
p-Isopropyltoluene mg/kg 0.054.05 108 66-128
sec-Butylbenzene mg/kg 0.055.05 110 72-140
Styrene mg/kg 0.057.05 115 76-137
tert-Butylbenzene mg/kg 0.056.05 113 68-141
Tetrachloroethene mg/kg 0.055.05 109 72-136
Toluene mg/kg 0.054.05 107 69-139
trans-1,2-Dichloroethene mg/kg 0.055.05 110 72-144
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 64 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
423214LABORATORY CONTROL SAMPLE:
LCSSpike
trans-1,3-Dichloropropene mg/kg 0.057.05 114 73-135
Trichloroethene mg/kg 0.056.05 113 75-136
Trichlorofluoromethane mg/kg 0.054.05 107 69-144
Vinyl acetate mg/kg 0.096.1 96 50-150
Vinyl chloride mg/kg 0.053.05 107 61-145
Xylene (Total)mg/kg 0.17.15 114 73-138
1,2-Dichloroethane-d4 (S)%99 69-121
4-Bromofluorobenzene (S)%98 74-115
Dibromofluoromethane (S)%102 79-116
Toluene-d8 (S)%100 88-110
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
423750MATRIX SPIKE SAMPLE:
MSSpike
Result
9266431005
1,1-Dichloroethene mg/kg 0.057.045 127 33-158ND
Benzene mg/kg 0.047.045 106 46-143ND
Chlorobenzene mg/kg 0.039.045 89 29-159ND
Toluene mg/kg 0.045.045 98 38-145ND
Trichloroethene mg/kg 0.043.045 97 70-130ND
1,2-Dichloroethane-d4 (S)%S013069-121
4-Bromofluorobenzene (S)%81 74-115
Dibromofluoromethane (S)%114 79-116
Toluene-d8 (S)%102 88-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
9266446002
424731SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane mg/kg ND 30ND
1,1,1-Trichloroethane mg/kg ND 30ND
1,1,2,2-Tetrachloroethane mg/kg ND 30ND
1,1,2-Trichloroethane mg/kg ND 30ND
1,1-Dichloroethane mg/kg ND 30ND
1,1-Dichloroethene mg/kg ND 30ND
1,1-Dichloropropene mg/kg ND 30ND
1,2,3-Trichlorobenzene mg/kg ND 30ND
1,2,3-Trichloropropane mg/kg ND 30ND
1,2,4-Trichlorobenzene mg/kg ND 30ND
1,2,4-Trimethylbenzene mg/kg ND 30ND
1,2-Dibromo-3-chloropropane mg/kg ND 30ND
1,2-Dibromoethane (EDB)mg/kg ND 30ND
1,2-Dichlorobenzene mg/kg ND 30ND
1,2-Dichloroethane mg/kg ND 30ND
1,2-Dichloropropane mg/kg ND 30ND
1,3,5-Trimethylbenzene mg/kg ND 30ND
1,3-Dichlorobenzene mg/kg ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 65 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
9266446002
424731SAMPLE DUPLICATE:
1,3-Dichloropropane mg/kg ND 30ND
1,4-Dichlorobenzene mg/kg ND 30ND
2,2-Dichloropropane mg/kg ND 30ND
2-Butanone (MEK)mg/kg ND 30ND
2-Chlorotoluene mg/kg ND 30ND
2-Hexanone mg/kg ND 30ND
4-Chlorotoluene mg/kg ND 30ND
4-Methyl-2-pentanone (MIBK)mg/kg ND 30ND
Acetone mg/kg ND 30ND
Benzene mg/kg ND 30ND
Bromobenzene mg/kg ND 30ND
Bromochloromethane mg/kg ND 30ND
Bromodichloromethane mg/kg ND 30ND
Bromoform mg/kg ND 30ND
Bromomethane mg/kg ND 30ND
Carbon tetrachloride mg/kg ND 30ND
Chlorobenzene mg/kg ND 30ND
Chloroethane mg/kg ND 30ND
Chloroform mg/kg ND 30ND
Chloromethane mg/kg ND 30ND
cis-1,2-Dichloroethene mg/kg ND 30ND
cis-1,3-Dichloropropene mg/kg ND 30ND
Dibromochloromethane mg/kg ND 30ND
Dibromomethane mg/kg ND 30ND
Dichlorodifluoromethane mg/kg ND 30ND
Diisopropyl ether mg/kg ND 30ND
Ethylbenzene mg/kg ND 30ND
Hexachloro-1,3-butadiene mg/kg ND 30ND
Isopropylbenzene (Cumene)mg/kg ND 30ND
m&p-Xylene mg/kg ND 30ND
Methyl-tert-butyl ether mg/kg ND 30ND
Methylene Chloride mg/kg ND 30ND
n-Butylbenzene mg/kg ND 30ND
n-Propylbenzene mg/kg ND 30ND
Naphthalene mg/kg ND 30ND
o-Xylene mg/kg ND 30ND
p-Isopropyltoluene mg/kg ND 30ND
sec-Butylbenzene mg/kg ND 30ND
Styrene mg/kg ND 30ND
tert-Butylbenzene mg/kg ND 30ND
Tetrachloroethene mg/kg ND 30ND
Toluene mg/kg ND 30ND
trans-1,2-Dichloroethene mg/kg ND 30ND
trans-1,3-Dichloropropene mg/kg ND 30ND
Trichloroethene mg/kg ND 30ND
Trichlorofluoromethane mg/kg ND 30ND
Vinyl acetate mg/kg ND 30ND
Vinyl chloride mg/kg ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 66 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
9266446002
424731SAMPLE DUPLICATE:
Xylene (Total)mg/kg ND 30ND
1,2-Dichloroethane-d4 (S)%106 9106
4-Bromofluorobenzene (S)%96 2086
Dibromofluoromethane (S)%102 7104
Toluene-d8 (S)%102 10101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 67 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
PMST/3101
ASTM D2974-87
ASTM D2974-87
Dry Weight/Percent Moisture
Associated Lab Samples:9266446001, 9266446002, 9266446003, 9266446004
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
9266491001
423689SAMPLE DUPLICATE:
Percent Moisture %2.3 3 252.3
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
9266446004
423690SAMPLE DUPLICATE:
Percent Moisture %14.8 8 2513.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 68 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
PMST/3113
ASTM D2974-87
ASTM D2974-87
Dry Weight/Percent Moisture
Associated Lab Samples:9266446005
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
9266608001
424755SAMPLE DUPLICATE:
Percent Moisture %14.6 8 2515.8
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
9266437002
424756SAMPLE DUPLICATE:
Percent Moisture %22.3 1 2522.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 69 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALIFIERS
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution ofthe sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes.
U - Indicates the compound was analyzed for, but not detected.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3
Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associatedsamples may be biased high.L1
Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associatedsamples may be biased low.L2
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
RPD value was outside control limits.R1
Surrogate recovery outside laboratory control limits.S0
Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated samples.Results unaffected by high bias.S3
Surrogate recovery not evaluated against control limits due to sample dilution.S4
Surrogate recovery outside control limits due to matrix interferences (not confirmed by re-analysis).S5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 70 of 72
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
9266446001 OEXT/9655 GCSV/7410SB-4T 2FT MADEP EPH MADEP EPH
9266446002 OEXT/9655 GCSV/7410SB-5T 1.5FT MADEP EPH MADEP EPH
9266446003 OEXT/9655 GCSV/7410SB-6T 2FT MADEP EPH MADEP EPH
9266446004 OEXT/9655 GCSV/7410SB-7T 2FT MADEP EPH MADEP EPH
9266446005 OEXT/9655 GCSV/7410SB-3T 2FT MADEP EPH MADEP EPH
9266446006 OEXT/9653 GCSV/7413SB-4T MADEP EPH MADEP EPH
9266446007 OEXT/9653 GCSV/7413SB-5T MADEP EPH MADEP EPH
9266446008 OEXT/9653 GCSV/7413SB-6T MADEP EPH MADEP EPH
9266446009 OEXT/9653 GCSV/7413SB-7T MADEP EPH MADEP EPH
9266446001 GCV/3962 GCV/3963SB-4T 2FT MADEP VPH MADEP VPH
9266446002 GCV/3962 GCV/3963SB-5T 1.5FT MADEP VPH MADEP VPH
9266446003 GCV/3962 GCV/3963SB-6T 2FT MADEP VPH MADEP VPH
9266446004 GCV/3962 GCV/3963SB-7T 2FT MADEP VPH MADEP VPH
9266446005 GCV/3962 GCV/3963SB-3T 2FT MADEP VPH MADEP VPH
9266446006 GCV/3953SB-4T MADEP VPH
9266446007 GCV/3953SB-5T MADEP VPH
9266446008 GCV/3953SB-6T MADEP VPH
9266446009 GCV/3953SB-7T MADEP VPH
9266446006 MPRP/6076 ICP/5617SB-4T SM 3030C EPA 200.7
9266446007 MPRP/6076 ICP/5617SB-5T SM 3030C EPA 200.7
9266446008 MPRP/6076 ICP/5617SB-6T SM 3030C EPA 200.7
9266446009 MPRP/6076 ICP/5617SB-7T SM 3030C EPA 200.7
9266446006 OEXT/9643 MSSV/3483SB-4T EPA 625 EPA 625
9266446007 OEXT/9643 MSSV/3483SB-5T EPA 625 EPA 625
9266446008 OEXT/9643 MSSV/3483SB-6T EPA 625 EPA 625
9266446009 OEXT/9643 MSSV/3483SB-7T EPA 625 EPA 625
9266446001 OEXT/9645 MSSV/3477SB-4T 2FT EPA 3546 EPA 8270
9266446002 OEXT/9645 MSSV/3477SB-5T 1.5FT EPA 3546 EPA 8270
9266446003 OEXT/9645 MSSV/3477SB-6T 2FT EPA 3546 EPA 8270
9266446004 OEXT/9645 MSSV/3477SB-7T 2FT EPA 3546 EPA 8270
9266446005 OEXT/9645 MSSV/3477SB-3T 2FT EPA 3546 EPA 8270
9266446006 MSV/10491SB-4T SM 6200B
9266446007 MSV/10491SB-5T SM 6200B
9266446008 MSV/10491SB-6T SM 6200B
9266446009 MSV/10491SB-7T SM 6200B
9266446001 MSV/10489SB-4T 2FT EPA 8260
9266446002 MSV/10489SB-5T 1.5FT EPA 8260
9266446003 MSV/10489SB-6T 2FT EPA 8260
9266446004 MSV/10489SB-7T 2FT EPA 8260
9266446005 MSV/10489SB-3T 2FT EPA 8260
9266446001 PMST/3101SB-4T 2FT ASTM D2974-87
9266446002 PMST/3101SB-5T 1.5FT ASTM D2974-87
9266446003 PMST/3101SB-6T 2FT ASTM D2974-87
9266446004 PMST/3101SB-7T 2FT ASTM D2974-87
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 71 of 72
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Pace Analytical Services, Inc.
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[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
9266446
16143 AGROTEC INCORPORATED
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
9266446005 PMST/3113SB-3T 2FT ASTM D2974-87
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
Date: 04/09/2010 05:05 PM Page 72 of 72
Pace Analytical Services, Inc.
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Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
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[phone]
April 20, 2010
LIMS USE: FR - LINDA BLALOCK
LIMS OBJECT ID: 9266897
9266897
Project:
Pace Project No.:
RE:
Ms. Linda BlalockNCDENR - UST Section1637 Mail Service CenterRaleigh, NC 276991637
16143 Agrotech
Dear Ms. Blalock:
Enclosed are the analytical results for sample(s) received by the laboratory on April 07, 2010. The
results relate only to the samples included in this report. Results reported herein conform to themost current NELAC standards, where applicable, unless otherwise narrated in the body of the
report.
Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and
Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All
Microbiological analyses were performed at the laboratory where the samples were received.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Renee Spencer
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
Page 1 of 25
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9800 Kincey Ave. Suite 100
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Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
CERTIFICATIONS
Pace Project No.:
Project:
9266897
16143 Agrotech
Charlotte Certification IDs9800 Kincey Ave. - Ste 100 Huntersville, NC 28078West Virginia Certification #: 357Connecticut Certification #: PH-0104Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84Louisiana/LELAP Certification #: 04034New Jersey Certification #: NC012North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12Pennsylvania Certification #: 68-00784South Carolina Certification #: 990060001South Carolina Drinking Water Cert. #: 990060003Tennessee Certification #: 04010Virginia Certification #: 00213
Asheville Certification IDs2225 Riverside Dr. Asheville, NC 28804Connecticut Certification #: PH-0106Louisiana/LELAP Certification #: 03095Massachusetts Certification #: M-NC030New Jersey Certification #: NC011North Carolina Bioassay Certification #: 9North Carolina Drinking Water Certification #: 37712North Carolina Wastewater Certification #: 40
Pennsylvania Certification #: 68-03578South Carolina Bioassay Certification #: 99030002South Carolina Certification #: 99030001Tennessee Certification #: 2980Virginia Certification #: 00072West Virginia Certification #: 356Florida/NELAP Certification #: E87648
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Pace Analytical Services, Inc.
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SAMPLE SUMMARY
Pace Project No.:
Project:
9266897
16143 Agrotech
Lab ID Sample ID Matrix Date Collected Date Received
9266897001 MW-2 Water 04/06/10 12:15 04/07/10 18:05
9266897002 MW-3 Water 04/06/10 11:00 04/07/10 18:05
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
Page 3 of 25
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Pace Analytical Services, Inc.
2225 Riverside Dr.
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SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
9266897
16143 Agrotech
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
9266897001 MW-2 MADEP EPH 7 PASI-CRES
MADEP VPH 5 PASI-CDHW
EPA 200.7 1 PASI-AJMW
EPA 625 59 PASI-CPPM
SM 6200B 64 PASI-CAW
9266897002 MW-3 MADEP EPH 7 PASI-CRES
MADEP VPH 5 PASI-CDHW
EPA 200.7 1 PASI-AJMW
EPA 625 59 PASI-CPPM
SM 6200B 64 PASI-CAW
REPORT OF LABORATORY ANALYSIS
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Page 4 of 25
Pace Analytical Services, Inc.
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Huntersville, NC 28078
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Pace Analytical Services, Inc.
2225 Riverside Dr.
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[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266897
16143 Agrotech
Sample:MW-2 Lab ID:9266897001 Collected:04/06/10 12:15 Received:04/07/10 18:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
MADEP EPH NC Water Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)ND ug/L 1 04/14/10 16:4904/14/10 07:30100100
Aliphatic (C19-C36)ND ug/L 1 04/14/10 16:4904/14/10 07:30100100
Aromatic (C11-C22)ND ug/L 1 04/14/10 16:4904/14/10 07:30100100
Nonatriacontane (S)87 %1 04/14/10 16:49 7194-86-704/14/10 07:3040-140
o-Terphenyl (S)79 %1 04/14/10 16:49 84-15-104/14/10 07:3040-140
2-Fluorobiphenyl (S)99 %1 04/14/10 16:49 321-60-804/14/10 07:3040-140
2-Bromonaphthalene (S)98 %1 04/14/10 16:49 580-13-204/14/10 07:3040-140
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)ND ug/L 1 04/08/10 18:44100100
Aliphatic (C09-C12)ND ug/L 1 04/08/10 18:44100100
Aromatic (C09-C10)ND ug/L 1 04/08/10 18:44100100
2,5-Dibromotoluene (PID)(S)114 %1 04/08/10 18:4470-130
2,5-Dibromotoluene (FID)(S)118 %1 04/08/10 18:4470-130
200.7 MET ICP, 3030C Analytical Method: EPA 200.7 Preparation Method: SM 3030C
Lead ND ug/L 1 04/10/10 01:19 7439-92-104/08/10 14:005.0 4.0
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
Acenaphthene ND ug/L 1 04/16/10 04:43 83-32-904/09/10 08:305.0 2.8
Acenaphthylene ND ug/L 1 04/16/10 04:43 208-96-804/09/10 08:305.0 2.8
Anthracene ND ug/L 1 04/16/10 04:43 120-12-704/09/10 08:305.0 2.9
Benzo(a)anthracene ND ug/L 1 04/16/10 04:43 56-55-304/09/10 08:305.0 2.8
Benzo(a)pyrene ND ug/L 1 04/16/10 04:43 50-32-804/09/10 08:305.0 3.1
Benzo(b)fluoranthene ND ug/L 1 04/16/10 04:43 205-99-204/09/10 08:305.0 3.6
Benzo(g,h,i)perylene ND ug/L 1 04/16/10 04:43 191-24-204/09/10 08:305.0 3.1
Benzo(k)fluoranthene ND ug/L 1 04/16/10 04:43 207-08-904/09/10 08:305.0 3.0
4-Bromophenylphenyl ether ND ug/L 1 04/16/10 04:43 101-55-304/09/10 08:305.0 2.4
Butylbenzylphthalate ND ug/L 1 04/16/10 04:43 85-68-704/09/10 08:305.0 2.9
4-Chloro-3-methylphenol ND ug/L 1 04/16/10 04:43 59-50-704/09/10 08:305.0 2.8
bis(2-Chloroethoxy)methane ND ug/L 1 04/16/10 04:43 111-91-104/09/10 08:3010.0 5.8
bis(2-Chloroethyl) ether ND ug/L 1 04/16/10 04:43 111-44-404/09/10 08:305.0 4.8
bis(2-Chloroisopropyl) ether ND ug/L 1 04/16/10 04:43 108-60-104/09/10 08:305.0 4.0
2-Chloronaphthalene ND ug/L 1 04/16/10 04:43 91-58-704/09/10 08:305.0 3.6
2-Chlorophenol ND ug/L 1 04/16/10 04:43 95-57-804/09/10 08:305.0 4.4
4-Chlorophenylphenyl ether ND ug/L 1 04/16/10 04:43 7005-72-304/09/10 08:305.0 2.7
Chrysene ND ug/L 1 04/16/10 04:43 218-01-904/09/10 08:305.0 2.7
Dibenz(a,h)anthracene ND ug/L 1 04/16/10 04:43 53-70-304/09/10 08:305.0 2.9
3,3'-Dichlorobenzidine ND ug/L 1 04/16/10 04:43 91-94-104/09/10 08:305.0 3.4
2,4-Dichlorophenol ND ug/L 1 04/16/10 04:43 120-83-204/09/10 08:305.0 4.1
Diethylphthalate ND ug/L 1 04/16/10 04:43 84-66-204/09/10 08:305.0 2.7
2,4-Dimethylphenol ND ug/L 1 04/16/10 04:43 105-67-904/09/10 08:3010.0 5.6
Dimethylphthalate ND ug/L 1 04/16/10 04:43 131-11-304/09/10 08:305.0 2.4
Di-n-butylphthalate ND ug/L 1 04/16/10 04:43 84-74-204/09/10 08:305.0 2.9
4,6-Dinitro-2-methylphenol ND ug/L 1 04/16/10 04:43 534-52-104/09/10 08:3020.0 7.8
2,4-Dinitrophenol ND ug/L 1 04/16/10 04:43 51-28-504/09/10 08:3050.0 10.0
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
Date: 04/20/2010 01:39 PM Page 5 of 25
Pace Analytical Services, Inc.
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Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266897
16143 Agrotech
Sample:MW-2 Lab ID:9266897001 Collected:04/06/10 12:15 Received:04/07/10 18:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
2,4-Dinitrotoluene ND ug/L 1 04/16/10 04:43 121-14-204/09/10 08:305.0 2.6
2,6-Dinitrotoluene ND ug/L 1 04/16/10 04:43 606-20-204/09/10 08:305.0 2.8
Di-n-octylphthalate ND ug/L 1 04/16/10 04:43 117-84-004/09/10 08:305.0 2.9
bis(2-Ethylhexyl)phthalate ND ug/L 1 04/16/10 04:43 117-81-704/09/10 08:305.0 2.1
Fluoranthene ND ug/L 1 04/16/10 04:43 206-44-004/09/10 08:305.0 2.9
Fluorene ND ug/L 1 04/16/10 04:43 86-73-704/09/10 08:305.0 2.6
Hexachloro-1,3-butadiene ND ug/L 1 04/16/10 04:43 87-68-304/09/10 08:305.0 3.3
Hexachlorobenzene ND ug/L 1 04/16/10 04:43 118-74-104/09/10 08:305.0 2.6
Hexachlorocyclopentadiene ND ug/L 1 04/16/10 04:43 77-47-404/09/10 08:3010.0 3.7
Hexachloroethane ND ug/L 1 04/16/10 04:43 67-72-104/09/10 08:305.0 3.3
Indeno(1,2,3-cd)pyrene ND ug/L 1 04/16/10 04:43 193-39-504/09/10 08:305.0 3.0
Isophorone ND ug/L 1 04/16/10 04:43 78-59-104/09/10 08:3010.0 6.5
2-Methylnaphthalene ND ug/L 1 04/16/10 04:43 91-57-604/09/10 08:305.0 3.4
Naphthalene ND ug/L 1 04/16/10 04:43 91-20-304/09/10 08:305.0 3.8
Nitrobenzene ND ug/L 1 04/16/10 04:43 98-95-304/09/10 08:305.0 4.4
2-Nitrophenol ND ug/L 1 04/16/10 04:43 88-75-504/09/10 08:305.0 4.6
4-Nitrophenol ND ug/L 1 04/16/10 04:43 100-02-704/09/10 08:3050.0 2.0
N-Nitrosodimethylamine ND ug/L 1 04/16/10 04:43 62-75-904/09/10 08:305.0 3.1
N-Nitroso-di-n-propylamine ND ug/L 1 04/16/10 04:43 621-64-704/09/10 08:305.0 3.7
N-Nitrosodiphenylamine ND ug/L 1 04/16/10 04:43 86-30-604/09/10 08:3010.0 6.6
Pentachlorophenol ND ug/L 1 04/16/10 04:43 87-86-504/09/10 08:3025.0 1.6
Phenanthrene ND ug/L 1 04/16/10 04:43 85-01-804/09/10 08:305.0 2.7
Phenol ND ug/L 1 04/16/10 04:43 108-95-204/09/10 08:305.0 1.8
Pyrene ND ug/L 1 04/16/10 04:43 129-00-004/09/10 08:305.0 2.9
1,2,4-Trichlorobenzene ND ug/L 1 04/16/10 04:43 120-82-104/09/10 08:305.0 3.4
2,4,6-Trichlorophenol ND ug/L 1 04/16/10 04:43 88-06-204/09/10 08:3010.0 6.1
Nitrobenzene-d5 (S)51 %1 04/16/10 04:43 4165-60-004/09/10 08:3010-120
2-Fluorobiphenyl (S)48 %1 04/16/10 04:43 321-60-804/09/10 08:3015-120
Terphenyl-d14 (S)64 %1 04/16/10 04:43 1718-51-004/09/10 08:3011-131
Phenol-d6 (S)26 %1 04/16/10 04:43 13127-88-304/09/10 08:3010-120
2-Fluorophenol (S)33 %1 04/16/10 04:43 367-12-404/09/10 08:3010-120
2,4,6-Tribromophenol (S)100 %1 04/16/10 04:43 118-79-604/09/10 08:3010-137
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 04/11/10 00:49 71-43-20.50 0.50
Bromobenzene ND ug/L 1 04/11/10 00:49 108-86-10.50 0.50
Bromochloromethane ND ug/L 1 04/11/10 00:49 74-97-50.50 0.50
Bromodichloromethane ND ug/L 1 04/11/10 00:49 75-27-40.50 0.50
Bromoform ND ug/L 1 04/11/10 00:49 75-25-20.50 0.50
Bromomethane ND ug/L 1 04/11/10 00:49 74-83-95.0 1.0
n-Butylbenzene ND ug/L 1 04/11/10 00:49 104-51-80.50 0.50
sec-Butylbenzene ND ug/L 1 04/11/10 00:49 135-98-80.50 0.50
tert-Butylbenzene ND ug/L 1 04/11/10 00:49 98-06-60.50 0.50
Carbon tetrachloride ND ug/L 1 04/11/10 00:49 56-23-50.50 0.50
Chlorobenzene ND ug/L 1 04/11/10 00:49 108-90-70.50 0.50
Chloroethane ND ug/L 1 04/11/10 00:49 75-00-31.0 1.0
REPORT OF LABORATORY ANALYSIS
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Date: 04/20/2010 01:39 PM Page 6 of 25
Pace Analytical Services, Inc.
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[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266897
16143 Agrotech
Sample:MW-2 Lab ID:9266897001 Collected:04/06/10 12:15 Received:04/07/10 18:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
Chloroform ND ug/L 1 04/11/10 00:49 67-66-30.50 0.50
Chloromethane ND ug/L 1 04/11/10 00:49 74-87-31.0 1.0
2-Chlorotoluene ND ug/L 1 04/11/10 00:49 95-49-80.50 0.50
4-Chlorotoluene ND ug/L 1 04/11/10 00:49 106-43-40.50 0.50
1,2-Dibromo-3-chloropropane ND ug/L 1 04/11/10 00:49 96-12-81.0 1.0
Dibromochloromethane ND ug/L 1 04/11/10 00:49 124-48-10.50 0.50
1,2-Dibromoethane (EDB)ND ug/L 1 04/11/10 00:49 106-93-40.50 0.50
Dibromomethane ND ug/L 1 04/11/10 00:49 74-95-30.50 0.50
1,2-Dichlorobenzene ND ug/L 1 04/11/10 00:49 95-50-10.50 0.50
1,3-Dichlorobenzene ND ug/L 1 04/11/10 00:49 541-73-10.50 0.50
1,4-Dichlorobenzene ND ug/L 1 04/11/10 00:49 106-46-70.50 0.50
Dichlorodifluoromethane ND ug/L 1 04/11/10 00:49 75-71-80.50 0.50
1,1-Dichloroethane ND ug/L 1 04/11/10 00:49 75-34-30.50 0.50
1,2-Dichloroethane ND ug/L 1 04/11/10 00:49 107-06-20.50 0.50
1,1-Dichloroethene ND ug/L 1 04/11/10 00:49 75-35-40.50 0.50
cis-1,2-Dichloroethene ND ug/L 1 04/11/10 00:49 156-59-20.50 0.50
trans-1,2-Dichloroethene ND ug/L 1 04/11/10 00:49 156-60-50.50 0.50
1,2-Dichloropropane ND ug/L 1 04/11/10 00:49 78-87-50.50 0.50
1,3-Dichloropropane ND ug/L 1 04/11/10 00:49 142-28-90.50 0.50
2,2-Dichloropropane ND ug/L 1 04/11/10 00:49 594-20-70.50 0.50
1,1-Dichloropropene ND ug/L 1 04/11/10 00:49 563-58-60.50 0.50
cis-1,3-Dichloropropene ND ug/L 1 04/11/10 00:49 10061-01-50.50 0.50
trans-1,3-Dichloropropene ND ug/L 1 04/11/10 00:49 10061-02-60.50 0.50
Diisopropyl ether ND ug/L 1 04/11/10 00:49 108-20-30.50 0.50
Ethylbenzene ND ug/L 1 04/11/10 00:49 100-41-40.50 0.50
Hexachloro-1,3-butadiene ND ug/L 1 04/11/10 00:49 87-68-32.0 2.0
Isopropylbenzene (Cumene)ND ug/L 1 04/11/10 00:49 98-82-80.50 0.50
Methylene Chloride ND ug/L 1 04/11/10 00:49 75-09-22.0 2.0
Methyl-tert-butyl ether ND ug/L 1 04/11/10 00:49 1634-04-40.50 0.50
Naphthalene ND ug/L 1 04/11/10 00:49 91-20-32.0 2.0
n-Propylbenzene ND ug/L 1 04/11/10 00:49 103-65-10.50 0.50
Styrene ND ug/L 1 04/11/10 00:49 100-42-50.50 0.50
1,1,1,2-Tetrachloroethane ND ug/L 1 04/11/10 00:49 630-20-60.50 0.50
1,1,2,2-Tetrachloroethane ND ug/L 1 04/11/10 00:49 79-34-50.50 0.50
Tetrachloroethene ND ug/L 1 04/11/10 00:49 127-18-40.50 0.50
Toluene ND ug/L 1 04/11/10 00:49 108-88-30.50 0.50
1,2,3-Trichlorobenzene ND ug/L 1 04/11/10 00:49 87-61-62.0 2.0
1,2,4-Trichlorobenzene ND ug/L 1 04/11/10 00:49 120-82-12.0 2.0
1,1,1-Trichloroethane ND ug/L 1 04/11/10 00:49 71-55-60.50 0.50
1,1,2-Trichloroethane ND ug/L 1 04/11/10 00:49 79-00-50.50 0.50
Trichloroethene ND ug/L 1 04/11/10 00:49 79-01-60.50 0.50
Trichlorofluoromethane ND ug/L 1 04/11/10 00:49 75-69-41.0 1.0
1,2,3-Trichloropropane ND ug/L 1 04/11/10 00:49 96-18-40.50 0.50
1,2,4-Trimethylbenzene ND ug/L 1 04/11/10 00:49 95-63-60.50 0.50
1,3,5-Trimethylbenzene ND ug/L 1 04/11/10 00:49 108-67-80.50 0.50
Vinyl chloride ND ug/L 1 04/11/10 00:49 75-01-41.0 1.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/20/2010 01:39 PM Page 7 of 25
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266897
16143 Agrotech
Sample:MW-2 Lab ID:9266897001 Collected:04/06/10 12:15 Received:04/07/10 18:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
m&p-Xylene ND ug/L 1 04/11/10 00:49 1330-20-71.0 1.0
o-Xylene ND ug/L 1 04/11/10 00:49 95-47-60.50 0.50
1,2-Dichloroethane-d4 (S)91 %1 04/11/10 00:49 17060-07-070-130
Dibromofluoromethane (S)91 %1 04/11/10 00:49 1868-53-770-130
4-Bromofluorobenzene (S)112 %1 04/11/10 00:49 460-00-470-130
Toluene-d8 (S)96 %1 04/11/10 00:49 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/20/2010 01:39 PM Page 8 of 25
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266897
16143 Agrotech
Sample:MW-3 Lab ID:9266897002 Collected:04/06/10 11:00 Received:04/07/10 18:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
MADEP EPH NC Water Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)ND ug/L 1 04/14/10 17:2504/14/10 07:30122122
Aliphatic (C19-C36)ND ug/L 1 04/14/10 17:2504/14/10 07:30122122
Aromatic (C11-C22)ND ug/L 1 04/14/10 17:2504/14/10 07:30122122
Nonatriacontane (S)84 %1 04/14/10 17:25 7194-86-704/14/10 07:3040-140
o-Terphenyl (S)83 %1 04/14/10 17:25 84-15-104/14/10 07:3040-140
2-Fluorobiphenyl (S)101 %1 04/14/10 17:25 321-60-804/14/10 07:3040-140
2-Bromonaphthalene (S)99 %1 04/14/10 17:25 580-13-204/14/10 07:3040-140
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)ND ug/L 1 04/08/10 19:09100100
Aliphatic (C09-C12)ND ug/L 1 04/08/10 19:09100100
Aromatic (C09-C10)ND ug/L 1 04/08/10 19:09100100
2,5-Dibromotoluene (PID)(S)110 %1 04/08/10 19:0970-130
2,5-Dibromotoluene (FID)(S)115 %1 04/08/10 19:0970-130
200.7 MET ICP, 3030C Analytical Method: EPA 200.7 Preparation Method: SM 3030C
Lead ND ug/L 1 04/10/10 01:02 7439-92-104/08/10 14:005.0 4.0
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
Acenaphthene ND ug/L 1 04/16/10 05:11 83-32-904/09/10 08:305.0 2.8
Acenaphthylene ND ug/L 1 04/16/10 05:11 208-96-804/09/10 08:305.0 2.8
Anthracene ND ug/L 1 04/16/10 05:11 120-12-704/09/10 08:305.0 2.9
Benzo(a)anthracene ND ug/L 1 04/16/10 05:11 56-55-304/09/10 08:305.0 2.8
Benzo(a)pyrene ND ug/L 1 04/16/10 05:11 50-32-804/09/10 08:305.0 3.1
Benzo(b)fluoranthene ND ug/L 1 04/16/10 05:11 205-99-204/09/10 08:305.0 3.6
Benzo(g,h,i)perylene ND ug/L 1 04/16/10 05:11 191-24-204/09/10 08:305.0 3.1
Benzo(k)fluoranthene ND ug/L 1 04/16/10 05:11 207-08-904/09/10 08:305.0 3.0
4-Bromophenylphenyl ether ND ug/L 1 04/16/10 05:11 101-55-304/09/10 08:305.0 2.4
Butylbenzylphthalate ND ug/L 1 04/16/10 05:11 85-68-704/09/10 08:305.0 2.9
4-Chloro-3-methylphenol ND ug/L 1 04/16/10 05:11 59-50-704/09/10 08:305.0 2.8
bis(2-Chloroethoxy)methane ND ug/L 1 04/16/10 05:11 111-91-104/09/10 08:3010.0 5.8
bis(2-Chloroethyl) ether ND ug/L 1 04/16/10 05:11 111-44-404/09/10 08:305.0 4.8
bis(2-Chloroisopropyl) ether ND ug/L 1 04/16/10 05:11 108-60-104/09/10 08:305.0 4.0
2-Chloronaphthalene ND ug/L 1 04/16/10 05:11 91-58-704/09/10 08:305.0 3.6
2-Chlorophenol ND ug/L 1 04/16/10 05:11 95-57-804/09/10 08:305.0 4.4
4-Chlorophenylphenyl ether ND ug/L 1 04/16/10 05:11 7005-72-304/09/10 08:305.0 2.7
Chrysene ND ug/L 1 04/16/10 05:11 218-01-904/09/10 08:305.0 2.7
Dibenz(a,h)anthracene ND ug/L 1 04/16/10 05:11 53-70-304/09/10 08:305.0 2.9
3,3'-Dichlorobenzidine ND ug/L 1 04/16/10 05:11 91-94-104/09/10 08:305.0 3.4
2,4-Dichlorophenol ND ug/L 1 04/16/10 05:11 120-83-204/09/10 08:305.0 4.1
Diethylphthalate ND ug/L 1 04/16/10 05:11 84-66-204/09/10 08:305.0 2.7
2,4-Dimethylphenol ND ug/L 1 04/16/10 05:11 105-67-904/09/10 08:3010.0 5.6
Dimethylphthalate ND ug/L 1 04/16/10 05:11 131-11-304/09/10 08:305.0 2.4
Di-n-butylphthalate ND ug/L 1 04/16/10 05:11 84-74-204/09/10 08:305.0 2.9
4,6-Dinitro-2-methylphenol ND ug/L 1 04/16/10 05:11 534-52-104/09/10 08:3020.0 7.8
2,4-Dinitrophenol ND ug/L 1 04/16/10 05:11 51-28-504/09/10 08:3050.0 10.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/20/2010 01:39 PM Page 9 of 25
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266897
16143 Agrotech
Sample:MW-3 Lab ID:9266897002 Collected:04/06/10 11:00 Received:04/07/10 18:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
2,4-Dinitrotoluene ND ug/L 1 04/16/10 05:11 121-14-204/09/10 08:305.0 2.6
2,6-Dinitrotoluene ND ug/L 1 04/16/10 05:11 606-20-204/09/10 08:305.0 2.8
Di-n-octylphthalate ND ug/L 1 04/16/10 05:11 117-84-004/09/10 08:305.0 2.9
bis(2-Ethylhexyl)phthalate ND ug/L 1 04/16/10 05:11 117-81-704/09/10 08:305.0 2.1
Fluoranthene ND ug/L 1 04/16/10 05:11 206-44-004/09/10 08:305.0 2.9
Fluorene ND ug/L 1 04/16/10 05:11 86-73-704/09/10 08:305.0 2.6
Hexachloro-1,3-butadiene ND ug/L 1 04/16/10 05:11 87-68-304/09/10 08:305.0 3.3
Hexachlorobenzene ND ug/L 1 04/16/10 05:11 118-74-104/09/10 08:305.0 2.6
Hexachlorocyclopentadiene ND ug/L 1 04/16/10 05:11 77-47-404/09/10 08:3010.0 3.7
Hexachloroethane ND ug/L 1 04/16/10 05:11 67-72-104/09/10 08:305.0 3.3
Indeno(1,2,3-cd)pyrene ND ug/L 1 04/16/10 05:11 193-39-504/09/10 08:305.0 3.0
Isophorone ND ug/L 1 04/16/10 05:11 78-59-104/09/10 08:3010.0 6.5
2-Methylnaphthalene ND ug/L 1 04/16/10 05:11 91-57-604/09/10 08:305.0 3.4
Naphthalene ND ug/L 1 04/16/10 05:11 91-20-304/09/10 08:305.0 3.8
Nitrobenzene ND ug/L 1 04/16/10 05:11 98-95-304/09/10 08:305.0 4.4
2-Nitrophenol ND ug/L 1 04/16/10 05:11 88-75-504/09/10 08:305.0 4.6
4-Nitrophenol ND ug/L 1 04/16/10 05:11 100-02-704/09/10 08:3050.0 2.0
N-Nitrosodimethylamine ND ug/L 1 04/16/10 05:11 62-75-904/09/10 08:305.0 3.1
N-Nitroso-di-n-propylamine ND ug/L 1 04/16/10 05:11 621-64-704/09/10 08:305.0 3.7
N-Nitrosodiphenylamine ND ug/L 1 04/16/10 05:11 86-30-604/09/10 08:3010.0 6.6
Pentachlorophenol ND ug/L 1 04/16/10 05:11 87-86-504/09/10 08:3025.0 1.6
Phenanthrene ND ug/L 1 04/16/10 05:11 85-01-804/09/10 08:305.0 2.7
Phenol ND ug/L 1 04/16/10 05:11 108-95-204/09/10 08:305.0 1.8
Pyrene ND ug/L 1 04/16/10 05:11 129-00-004/09/10 08:305.0 2.9
1,2,4-Trichlorobenzene ND ug/L 1 04/16/10 05:11 120-82-104/09/10 08:305.0 3.4
2,4,6-Trichlorophenol ND ug/L 1 04/16/10 05:11 88-06-204/09/10 08:3010.0 6.1
Nitrobenzene-d5 (S)37 %1 04/16/10 05:11 4165-60-004/09/10 08:3010-120
2-Fluorobiphenyl (S)35 %1 04/16/10 05:11 321-60-804/09/10 08:3015-120
Terphenyl-d14 (S)49 %1 04/16/10 05:11 1718-51-004/09/10 08:3011-131
Phenol-d6 (S)16 %1 04/16/10 05:11 13127-88-304/09/10 08:3010-120
2-Fluorophenol (S)23 %1 04/16/10 05:11 367-12-404/09/10 08:3010-120
2,4,6-Tribromophenol (S)73 %1 04/16/10 05:11 118-79-604/09/10 08:3010-137
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 04/11/10 01:11 71-43-20.50 0.50
Bromobenzene ND ug/L 1 04/11/10 01:11 108-86-10.50 0.50
Bromochloromethane ND ug/L 1 04/11/10 01:11 74-97-50.50 0.50
Bromodichloromethane ND ug/L 1 04/11/10 01:11 75-27-40.50 0.50
Bromoform ND ug/L 1 04/11/10 01:11 75-25-20.50 0.50
Bromomethane ND ug/L 1 04/11/10 01:11 74-83-95.0 1.0
n-Butylbenzene ND ug/L 1 04/11/10 01:11 104-51-80.50 0.50
sec-Butylbenzene ND ug/L 1 04/11/10 01:11 135-98-80.50 0.50
tert-Butylbenzene ND ug/L 1 04/11/10 01:11 98-06-60.50 0.50
Carbon tetrachloride ND ug/L 1 04/11/10 01:11 56-23-50.50 0.50
Chlorobenzene ND ug/L 1 04/11/10 01:11 108-90-70.50 0.50
Chloroethane ND ug/L 1 04/11/10 01:11 75-00-31.0 1.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/20/2010 01:39 PM Page 10 of 25
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266897
16143 Agrotech
Sample:MW-3 Lab ID:9266897002 Collected:04/06/10 11:00 Received:04/07/10 18:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
Chloroform ND ug/L 1 04/11/10 01:11 67-66-30.50 0.50
Chloromethane ND ug/L 1 04/11/10 01:11 74-87-31.0 1.0
2-Chlorotoluene ND ug/L 1 04/11/10 01:11 95-49-80.50 0.50
4-Chlorotoluene ND ug/L 1 04/11/10 01:11 106-43-40.50 0.50
1,2-Dibromo-3-chloropropane ND ug/L 1 04/11/10 01:11 96-12-81.0 1.0
Dibromochloromethane ND ug/L 1 04/11/10 01:11 124-48-10.50 0.50
1,2-Dibromoethane (EDB)ND ug/L 1 04/11/10 01:11 106-93-40.50 0.50
Dibromomethane ND ug/L 1 04/11/10 01:11 74-95-30.50 0.50
1,2-Dichlorobenzene ND ug/L 1 04/11/10 01:11 95-50-10.50 0.50
1,3-Dichlorobenzene ND ug/L 1 04/11/10 01:11 541-73-10.50 0.50
1,4-Dichlorobenzene ND ug/L 1 04/11/10 01:11 106-46-70.50 0.50
Dichlorodifluoromethane ND ug/L 1 04/11/10 01:11 75-71-80.50 0.50
1,1-Dichloroethane ND ug/L 1 04/11/10 01:11 75-34-30.50 0.50
1,2-Dichloroethane ND ug/L 1 04/11/10 01:11 107-06-20.50 0.50
1,1-Dichloroethene ND ug/L 1 04/11/10 01:11 75-35-40.50 0.50
cis-1,2-Dichloroethene ND ug/L 1 04/11/10 01:11 156-59-20.50 0.50
trans-1,2-Dichloroethene ND ug/L 1 04/11/10 01:11 156-60-50.50 0.50
1,2-Dichloropropane ND ug/L 1 04/11/10 01:11 78-87-50.50 0.50
1,3-Dichloropropane ND ug/L 1 04/11/10 01:11 142-28-90.50 0.50
2,2-Dichloropropane ND ug/L 1 04/11/10 01:11 594-20-70.50 0.50
1,1-Dichloropropene ND ug/L 1 04/11/10 01:11 563-58-60.50 0.50
cis-1,3-Dichloropropene ND ug/L 1 04/11/10 01:11 10061-01-50.50 0.50
trans-1,3-Dichloropropene ND ug/L 1 04/11/10 01:11 10061-02-60.50 0.50
Diisopropyl ether ND ug/L 1 04/11/10 01:11 108-20-30.50 0.50
Ethylbenzene ND ug/L 1 04/11/10 01:11 100-41-40.50 0.50
Hexachloro-1,3-butadiene ND ug/L 1 04/11/10 01:11 87-68-32.0 2.0
Isopropylbenzene (Cumene)ND ug/L 1 04/11/10 01:11 98-82-80.50 0.50
Methylene Chloride ND ug/L 1 04/11/10 01:11 75-09-22.0 2.0
Methyl-tert-butyl ether ND ug/L 1 04/11/10 01:11 1634-04-40.50 0.50
Naphthalene ND ug/L 1 04/11/10 01:11 91-20-32.0 2.0
n-Propylbenzene ND ug/L 1 04/11/10 01:11 103-65-10.50 0.50
Styrene ND ug/L 1 04/11/10 01:11 100-42-50.50 0.50
1,1,1,2-Tetrachloroethane ND ug/L 1 04/11/10 01:11 630-20-60.50 0.50
1,1,2,2-Tetrachloroethane ND ug/L 1 04/11/10 01:11 79-34-50.50 0.50
Tetrachloroethene ND ug/L 1 04/11/10 01:11 127-18-40.50 0.50
Toluene ND ug/L 1 04/11/10 01:11 108-88-30.50 0.50
1,2,3-Trichlorobenzene ND ug/L 1 04/11/10 01:11 87-61-62.0 2.0
1,2,4-Trichlorobenzene ND ug/L 1 04/11/10 01:11 120-82-12.0 2.0
1,1,1-Trichloroethane ND ug/L 1 04/11/10 01:11 71-55-60.50 0.50
1,1,2-Trichloroethane ND ug/L 1 04/11/10 01:11 79-00-50.50 0.50
Trichloroethene ND ug/L 1 04/11/10 01:11 79-01-60.50 0.50
Trichlorofluoromethane ND ug/L 1 04/11/10 01:11 75-69-41.0 1.0
1,2,3-Trichloropropane ND ug/L 1 04/11/10 01:11 96-18-40.50 0.50
1,2,4-Trimethylbenzene ND ug/L 1 04/11/10 01:11 95-63-60.50 0.50
1,3,5-Trimethylbenzene ND ug/L 1 04/11/10 01:11 108-67-80.50 0.50
Vinyl chloride ND ug/L 1 04/11/10 01:11 75-01-41.0 1.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/20/2010 01:39 PM Page 11 of 25
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9266897
16143 Agrotech
Sample:MW-3 Lab ID:9266897002 Collected:04/06/10 11:00 Received:04/07/10 18:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
m&p-Xylene ND ug/L 1 04/11/10 01:11 1330-20-71.0 1.0
o-Xylene ND ug/L 1 04/11/10 01:11 95-47-60.50 0.50
1,2-Dichloroethane-d4 (S)92 %1 04/11/10 01:11 17060-07-070-130
Dibromofluoromethane (S)91 %1 04/11/10 01:11 1868-53-770-130
4-Bromofluorobenzene (S)114 %1 04/11/10 01:11 460-00-470-130
Toluene-d8 (S)96 %1 04/11/10 01:11 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/20/2010 01:39 PM Page 12 of 25
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266897
16143 Agrotech
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/9723
MADEP EPH
MADEP EPH
MADEP EPH NC Water
Associated Lab Samples:9266897001, 9266897002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:428191
Associated Lab Samples:9266897001, 9266897002
Matrix:Water
Analyzed
Aliphatic (C09-C18)ug/L ND 100 04/14/10 15:02
Aliphatic (C19-C36)ug/L ND 100 04/14/10 15:02
Aromatic (C11-C22)ug/L ND 100 04/14/10 15:02
2-Bromonaphthalene (S)%109 40-140 04/14/10 15:02
2-Fluorobiphenyl (S)%107 40-140 04/14/10 15:02
Nonatriacontane (S)%79 40-140 04/14/10 15:02
o-Terphenyl (S)%87 40-140 04/14/10 15:02
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
428192LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
428193
Aliphatic (C09-C18)ug/L 148300 49 40-14062187 23 50
Aliphatic (C19-C36)ug/L 289400 72 40-14079316 9 50
Aromatic (C11-C22)ug/L 820850 96 40-14097822 0 50
2-Bromonaphthalene (S)%113 40-140106
2-Fluorobiphenyl (S)%115 40-140109
Nonatriacontane (S)%80 40-14085
o-Terphenyl (S)%96 40-14091
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/20/2010 01:39 PM Page 13 of 25
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266897
16143 Agrotech
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GCV/3966
MADEP VPH
MADEP VPH
VPH NC Water
Associated Lab Samples:9266897001, 9266897002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:426084
Associated Lab Samples:9266897001, 9266897002
Matrix:Water
Analyzed
Aliphatic (C05-C08)ug/L ND 100 04/08/10 16:16
Aliphatic (C09-C12)ug/L ND 100 04/08/10 16:16
Aromatic (C09-C10)ug/L ND 100 04/08/10 16:16
2,5-Dibromotoluene (FID)(S)%110 70-130 04/08/10 16:16
2,5-Dibromotoluene (PID)(S)%104 70-130 04/08/10 16:16
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
426085LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
426086
Aliphatic (C05-C08)ug/L 314300 105 70-130106319 2 25
Aliphatic (C09-C12)ug/L 340300 113 30-130116349 3 25
Aromatic (C09-C10)ug/L 100100 100 70-130101101 0 25
2,5-Dibromotoluene (FID)(S)%113 70-130103
2,5-Dibromotoluene (PID)(S)%101 70-13092
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/20/2010 01:39 PM Page 14 of 25
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266897
16143 Agrotech
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/6114
SM 3030C
EPA 200.7
200.7 MET 3030C
Associated Lab Samples:9266897001, 9266897002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:426119
Associated Lab Samples:9266897001, 9266897002
Matrix:Water
Analyzed
Lead ug/L ND 5.0 04/10/10 00:56
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
426120LABORATORY CONTROL SAMPLE:
LCSSpike
Lead ug/L 539500 108 85-115
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
426121MATRIX SPIKE SAMPLE:
MSSpike
Result
9266897002
Lead ug/L 532500 106 70-130ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
9266897001
426122SAMPLE DUPLICATE:
Lead ug/L ND 20ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/20/2010 01:39 PM Page 15 of 25
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266897
16143 Agrotech
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/9699
EPA 625
EPA 625
625 MSS
Associated Lab Samples:9266897001, 9266897002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:426500
Associated Lab Samples:9266897001, 9266897002
Matrix:Water
Analyzed
1,2,4-Trichlorobenzene ug/L ND 5.0 04/16/10 18:00
2,4,6-Trichlorophenol ug/L ND 10.0 04/16/10 18:00
2,4-Dichlorophenol ug/L ND 5.0 04/16/10 18:00
2,4-Dimethylphenol ug/L ND 10.0 04/16/10 18:00
2,4-Dinitrophenol ug/L ND 50.0 04/16/10 18:00
2,4-Dinitrotoluene ug/L ND 5.0 04/16/10 18:00
2,6-Dinitrotoluene ug/L ND 5.0 04/16/10 18:00
2-Chloronaphthalene ug/L ND 5.0 04/16/10 18:00
2-Chlorophenol ug/L ND 5.0 04/16/10 18:00
2-Methylnaphthalene ug/L ND 5.0 04/16/10 18:00
2-Nitrophenol ug/L ND 5.0 04/16/10 18:00
3,3'-Dichlorobenzidine ug/L 9.1 5.0 P804/16/10 18:00
4,6-Dinitro-2-methylphenol ug/L ND 20.0 04/16/10 18:00
4-Bromophenylphenyl ether ug/L ND 5.0 04/16/10 18:00
4-Chloro-3-methylphenol ug/L ND 5.0 04/16/10 18:00
4-Chlorophenylphenyl ether ug/L ND 5.0 04/16/10 18:00
4-Nitrophenol ug/L 2.3J 50.0 04/16/10 18:00
Acenaphthene ug/L ND 5.0 04/16/10 18:00
Acenaphthylene ug/L ND 5.0 04/16/10 18:00
Anthracene ug/L ND 5.0 04/16/10 18:00
Benzo(a)anthracene ug/L 3.0J 5.0 04/16/10 18:00
Benzo(a)pyrene ug/L ND 5.0 04/16/10 18:00
Benzo(b)fluoranthene ug/L ND 5.0 04/16/10 18:00
Benzo(g,h,i)perylene ug/L ND 5.0 04/16/10 18:00
Benzo(k)fluoranthene ug/L ND 5.0 04/16/10 18:00
bis(2-Chloroethoxy)methane ug/L ND 10.0 04/16/10 18:00
bis(2-Chloroethyl) ether ug/L ND 5.0 04/16/10 18:00
bis(2-Chloroisopropyl) ether ug/L ND 5.0 04/16/10 18:00
bis(2-Ethylhexyl)phthalate ug/L 3.0J 5.0 04/16/10 18:00
Butylbenzylphthalate ug/L ND 5.0 04/16/10 18:00
Chrysene ug/L ND 5.0 04/16/10 18:00
Di-n-butylphthalate ug/L ND 5.0 04/16/10 18:00
Di-n-octylphthalate ug/L 2.9J 5.0 04/16/10 18:00
Dibenz(a,h)anthracene ug/L ND 5.0 04/16/10 18:00
Diethylphthalate ug/L ND 5.0 04/16/10 18:00
Dimethylphthalate ug/L ND 5.0 04/16/10 18:00
Fluoranthene ug/L ND 5.0 04/16/10 18:00
Fluorene ug/L ND 5.0 04/16/10 18:00
Hexachloro-1,3-butadiene ug/L ND 5.0 04/16/10 18:00
Hexachlorobenzene ug/L ND 5.0 04/16/10 18:00
Hexachlorocyclopentadiene ug/L ND 10.0 04/16/10 18:00
Hexachloroethane ug/L ND 5.0 04/16/10 18:00
Indeno(1,2,3-cd)pyrene ug/L ND 5.0 04/16/10 18:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/20/2010 01:39 PM Page 16 of 25
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266897
16143 Agrotech
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:426500
Associated Lab Samples:9266897001, 9266897002
Matrix:Water
Analyzed
Isophorone ug/L ND 10.0 04/16/10 18:00
N-Nitroso-di-n-propylamine ug/L ND 5.0 04/16/10 18:00
N-Nitrosodimethylamine ug/L ND 5.0 04/16/10 18:00
N-Nitrosodiphenylamine ug/L ND 10.0 04/16/10 18:00
Naphthalene ug/L ND 5.0 04/16/10 18:00
Nitrobenzene ug/L ND 5.0 04/16/10 18:00
Pentachlorophenol ug/L 2.2J 25.0 04/16/10 18:00
Phenanthrene ug/L ND 5.0 04/16/10 18:00
Phenol ug/L ND 5.0 04/16/10 18:00
Pyrene ug/L ND 5.0 04/16/10 18:00
2,4,6-Tribromophenol (S)%78 10-137 04/16/10 18:00
2-Fluorobiphenyl (S)%59 15-120 04/16/10 18:00
2-Fluorophenol (S)%37 10-120 04/16/10 18:00
Nitrobenzene-d5 (S)%64 10-120 04/16/10 18:00
Phenol-d6 (S)%25 10-120 04/16/10 18:00
Terphenyl-d14 (S)%73 11-131 04/16/10 18:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
426501LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
426502
1,2,4-Trichlorobenzene ug/L 36.050 72 44-1427738.3 6 30
2,4,6-Trichlorophenol ug/L 43.750 87 37-1449547.4 8 30
2,4-Dichlorophenol ug/L 46.350 93 1-1919446.8 1 30
2,4-Dimethylphenol ug/L 39.350 79 32-1198140.4 3 30
2,4-Dinitrophenol ug/L 26.3J250 11 1-1811025.5J 30
2,4-Dinitrotoluene ug/L 47.050 94 39-1398944.7 5 30
2,6-Dinitrotoluene ug/L 47.150 94 50-1589447.1 0 30
2-Chloronaphthalene ug/L 42.750 85 60-1189648.1 12 30
2-Chlorophenol ug/L 37.350 75 23-1348240.8 9 30
2-Methylnaphthalene ug/L 38.050 76 25-1507939.3 3 30
2-Nitrophenol ug/L 44.350 89 29-1829748.6 9 30
3,3'-Dichlorobenzidine ug/L 206250 82 1-26279197 4 30
4,6-Dinitro-2-methylphenol ug/L 66.6100 67 1-1816160.8 9 30
4-Bromophenylphenyl ether ug/L 40.950 82 53-1279145.5 11 30
4-Chloro-3-methylphenol ug/L 89.2100 89 22-1478383.4 7 30
4-Chlorophenylphenyl ether ug/L 42.550 85 25-1588642.8 1 30
4-Nitrophenol ug/L 72.8250 29 1-1321948.5J 30
Acenaphthene ug/L 42.050 84 47-1458944.5 6 30
Acenaphthylene ug/L 40.950 82 33-1458642.9 5 30
Anthracene ug/L 44.250 88 1-1669346.6 5 30
Benzo(a)anthracene ug/L 43.550 87 33-1439346.4 7 30
Benzo(a)pyrene ug/L 39.750 79 17-1638542.3 7 30
Benzo(b)fluoranthene ug/L 40.450 81 24-1598743.6 8 30
Benzo(g,h,i)perylene ug/L 41.550 83 1-2198844.1 6 30
Benzo(k)fluoranthene ug/L 37.850 76 11-1628442.1 11 30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/20/2010 01:39 PM Page 17 of 25
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266897
16143 Agrotech
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
426501LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
426502
bis(2-Chloroethoxy)methane ug/L 39.150 78 33-1848341.6 6 30
bis(2-Chloroethyl) ether ug/L 38.450 77 12-1588241.1 7 30
bis(2-Chloroisopropyl) ether ug/L 34.950 70 36-1667637.8 8 30
bis(2-Ethylhexyl)phthalate ug/L 45.450 91 8-1589848.9 7 30
Butylbenzylphthalate ug/L 44.250 88 1-1529648.1 8 30
Chrysene ug/L 43.650 87 17-1689547.5 9 30
Di-n-butylphthalate ug/L 46.250 92 1-1189246.0 0 30
Di-n-octylphthalate ug/L 43.650 87 4-1468743.7 0 30
Dibenz(a,h)anthracene ug/L 42.350 85 1-2279044.9 6 30
Diethylphthalate ug/L 44.450 89 1-1148542.5 4 30
Dimethylphthalate ug/L 42.250 84 1-1128442.1 0 30
Fluoranthene ug/L 47.950 96 26-1379547.5 1 30
Fluorene ug/L 44.150 88 59-1218844.0 0 30
Hexachloro-1,3-butadiene ug/L 31.950 64 24-1166633.2 4 30
Hexachlorobenzene ug/L 46.550 93 1-15210250.9 9 30
Hexachlorocyclopentadiene ug/L 34.050 68 25-1508944.6 27 30
Hexachloroethane ug/L 28.650 57 40-1136030.0 5 30
Indeno(1,2,3-cd)pyrene ug/L 41.750 83 1-1718843.9 5 30
Isophorone ug/L 43.550 87 21-1969246.1 6 30
N-Nitroso-di-n-propylamine ug/L 41.950 84 1-2309145.3 8 30
N-Nitrosodimethylamine ug/L 27.150 54 25-1505829.0 7 30
N-Nitrosodiphenylamine ug/L 45.750 91 25-15010050.1 9 30
Naphthalene ug/L 37.350 75 21-1337839.2 5 30
Nitrobenzene ug/L 42.250 84 35-1809045.1 7 30
Pentachlorophenol ug/L 193250 77 14-17685212 9 30
Phenanthrene ug/L 42.650 85 54-1209045.1 6 30
Phenol ug/L 18.950 38 5-1124020.1 6 30
Pyrene ug/L 41.850 84 52-1159748.3 14 30
2,4,6-Tribromophenol (S)%96 10-13793
2-Fluorobiphenyl (S)%79 15-12089
2-Fluorophenol (S)%46 10-12050
Nitrobenzene-d5 (S)%78 10-12084
Phenol-d6 (S)%31 10-12033
Terphenyl-d14 (S)%84 11-13194
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/20/2010 01:39 PM Page 18 of 25
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266897
16143 Agrotech
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/10574
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:9266897001, 9266897002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:427304
Associated Lab Samples:9266897001, 9266897002
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 04/10/10 17:23
1,1,1-Trichloroethane ug/L ND 0.50 04/10/10 17:23
1,1,2,2-Tetrachloroethane ug/L ND 0.50 04/10/10 17:23
1,1,2-Trichloroethane ug/L ND 0.50 04/10/10 17:23
1,1-Dichloroethane ug/L ND 0.50 04/10/10 17:23
1,1-Dichloroethene ug/L ND 0.50 04/10/10 17:23
1,1-Dichloropropene ug/L ND 0.50 04/10/10 17:23
1,2,3-Trichlorobenzene ug/L ND 2.0 04/10/10 17:23
1,2,3-Trichloropropane ug/L ND 0.50 04/10/10 17:23
1,2,4-Trichlorobenzene ug/L ND 2.0 04/10/10 17:23
1,2,4-Trimethylbenzene ug/L ND 0.50 04/10/10 17:23
1,2-Dibromo-3-chloropropane ug/L ND 1.0 04/10/10 17:23
1,2-Dibromoethane (EDB)ug/L ND 0.50 04/10/10 17:23
1,2-Dichlorobenzene ug/L ND 0.50 04/10/10 17:23
1,2-Dichloroethane ug/L ND 0.50 04/10/10 17:23
1,2-Dichloropropane ug/L ND 0.50 04/10/10 17:23
1,3,5-Trimethylbenzene ug/L ND 0.50 04/10/10 17:23
1,3-Dichlorobenzene ug/L ND 0.50 04/10/10 17:23
1,3-Dichloropropane ug/L ND 0.50 04/10/10 17:23
1,4-Dichlorobenzene ug/L ND 0.50 04/10/10 17:23
2,2-Dichloropropane ug/L ND 0.50 04/10/10 17:23
2-Chlorotoluene ug/L ND 0.50 04/10/10 17:23
4-Chlorotoluene ug/L ND 0.50 04/10/10 17:23
Benzene ug/L ND 0.50 04/10/10 17:23
Bromobenzene ug/L ND 0.50 04/10/10 17:23
Bromochloromethane ug/L ND 0.50 04/10/10 17:23
Bromodichloromethane ug/L ND 0.50 04/10/10 17:23
Bromoform ug/L ND 0.50 04/10/10 17:23
Bromomethane ug/L ND 5.0 04/10/10 17:23
Carbon tetrachloride ug/L ND 0.50 04/10/10 17:23
Chlorobenzene ug/L ND 0.50 04/10/10 17:23
Chloroethane ug/L ND 1.0 04/10/10 17:23
Chloroform ug/L ND 0.50 04/10/10 17:23
Chloromethane ug/L ND 1.0 04/10/10 17:23
cis-1,2-Dichloroethene ug/L ND 0.50 04/10/10 17:23
cis-1,3-Dichloropropene ug/L ND 0.50 04/10/10 17:23
Dibromochloromethane ug/L ND 0.50 04/10/10 17:23
Dibromomethane ug/L ND 0.50 04/10/10 17:23
Dichlorodifluoromethane ug/L ND 0.50 04/10/10 17:23
Diisopropyl ether ug/L ND 0.50 04/10/10 17:23
Ethylbenzene ug/L ND 0.50 04/10/10 17:23
Hexachloro-1,3-butadiene ug/L ND 2.0 04/10/10 17:23
Isopropylbenzene (Cumene)ug/L ND 0.50 04/10/10 17:23
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/20/2010 01:39 PM Page 19 of 25
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266897
16143 Agrotech
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:427304
Associated Lab Samples:9266897001, 9266897002
Matrix:Water
Analyzed
m&p-Xylene ug/L ND 1.0 04/10/10 17:23
Methyl-tert-butyl ether ug/L ND 0.50 04/10/10 17:23
Methylene Chloride ug/L ND 2.0 04/10/10 17:23
n-Butylbenzene ug/L ND 0.50 04/10/10 17:23
n-Propylbenzene ug/L ND 0.50 04/10/10 17:23
Naphthalene ug/L ND 2.0 04/10/10 17:23
o-Xylene ug/L ND 0.50 04/10/10 17:23
sec-Butylbenzene ug/L ND 0.50 04/10/10 17:23
Styrene ug/L ND 0.50 04/10/10 17:23
tert-Butylbenzene ug/L ND 0.50 04/10/10 17:23
Tetrachloroethene ug/L ND 0.50 04/10/10 17:23
Toluene ug/L ND 0.50 04/10/10 17:23
trans-1,2-Dichloroethene ug/L ND 0.50 04/10/10 17:23
trans-1,3-Dichloropropene ug/L ND 0.50 04/10/10 17:23
Trichloroethene ug/L ND 0.50 04/10/10 17:23
Trichlorofluoromethane ug/L ND 1.0 04/10/10 17:23
Vinyl chloride ug/L ND 1.0 04/10/10 17:23
1,2-Dichloroethane-d4 (S)%93 70-130 04/10/10 17:23
4-Bromofluorobenzene (S)%112 70-130 04/10/10 17:23
Dibromofluoromethane (S)%92 70-130 04/10/10 17:23
Toluene-d8 (S)%97 70-130 04/10/10 17:23
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
427305LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 54.450 109 60-140
1,1,1-Trichloroethane ug/L 46.550 93 60-140
1,1,2,2-Tetrachloroethane ug/L 43.350 87 60-140
1,1,2-Trichloroethane ug/L 45.750 91 60-140
1,1-Dichloroethane ug/L 42.050 84 60-140
1,1-Dichloroethene ug/L 42.150 84 60-140
1,1-Dichloropropene ug/L 41.250 82 60-140
1,2,3-Trichlorobenzene ug/L 46.950 94 60-140
1,2,3-Trichloropropane ug/L 49.050 98 60-140
1,2,4-Trichlorobenzene ug/L 48.750 97 60-140
1,2,4-Trimethylbenzene ug/L 46.050 92 60-140
1,2-Dibromo-3-chloropropane ug/L 43.250 86 60-140
1,2-Dibromoethane (EDB)ug/L 49.650 99 60-140
1,2-Dichlorobenzene ug/L 48.550 97 60-140
1,2-Dichloroethane ug/L 43.450 87 60-140
1,2-Dichloropropane ug/L 42.850 86 60-140
1,3,5-Trimethylbenzene ug/L 48.050 96 60-140
1,3-Dichlorobenzene ug/L 48.650 97 60-140
1,3-Dichloropropane ug/L 46.550 93 60-140
1,4-Dichlorobenzene ug/L 47.450 95 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/20/2010 01:39 PM Page 20 of 25
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266897
16143 Agrotech
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
427305LABORATORY CONTROL SAMPLE:
LCSSpike
2,2-Dichloropropane ug/L 34.050 68 60-140
2-Chlorotoluene ug/L 45.750 91 60-140
4-Chlorotoluene ug/L 45.950 92 60-140
Benzene ug/L 43.550 87 60-140
Bromobenzene ug/L 42.850 86 60-140
Bromochloromethane ug/L 43.250 86 60-140
Bromodichloromethane ug/L 48.650 97 60-140
Bromoform ug/L 55.150 110 60-140
Bromomethane ug/L 43.350 87 60-140
Carbon tetrachloride ug/L 53.350 107 60-140
Chlorobenzene ug/L 49.550 99 60-140
Chloroethane ug/L 54.050 108 60-140
Chloroform ug/L 42.350 85 60-140
Chloromethane ug/L 37.350 75 60-140
cis-1,2-Dichloroethene ug/L 41.350 83 60-140
cis-1,3-Dichloropropene ug/L 41.050 82 60-140
Dibromochloromethane ug/L 54.450 109 60-140
Dibromomethane ug/L 51.950 104 60-140
Dichlorodifluoromethane ug/L 43.950 88 60-140
Diisopropyl ether ug/L 38.450 77 60-140
Ethylbenzene ug/L 49.550 99 60-140
Hexachloro-1,3-butadiene ug/L 49.050 98 60-140
Isopropylbenzene (Cumene)ug/L 52.250 104 60-140
m&p-Xylene ug/L 101100 101 60-140
Methyl-tert-butyl ether ug/L 48.850 98 60-140
Methylene Chloride ug/L 40.050 80 60-140
n-Butylbenzene ug/L 43.250 86 60-140
n-Propylbenzene ug/L 45.650 91 60-140
Naphthalene ug/L 43.750 87 60-140
o-Xylene ug/L 49.650 99 60-140
sec-Butylbenzene ug/L 46.650 93 60-140
Styrene ug/L 51.150 102 60-140
tert-Butylbenzene ug/L 48.750 97 60-140
Tetrachloroethene ug/L 53.550 107 60-140
Toluene ug/L 45.650 91 60-140
trans-1,2-Dichloroethene ug/L 40.250 80 60-140
trans-1,3-Dichloropropene ug/L 41.050 82 60-140
Trichloroethene ug/L 50.850 102 60-140
Trichlorofluoromethane ug/L 46.050 92 60-140
Vinyl chloride ug/L 40.050 80 60-140
1,2-Dichloroethane-d4 (S)%92 70-130
4-Bromofluorobenzene (S)%114 70-130
Dibromofluoromethane (S)%93 70-130
Toluene-d8 (S)%99 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/20/2010 01:39 PM Page 21 of 25
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266897
16143 Agrotech
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
427306MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9266623007
427307
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L R1209460-140130 31 3020ND18.9 25.9
1,1,1-Trichloroethane ug/L 20 89 60-140119 29 3020ND17.8 23.9
1,1,2,2-Tetrachloroethane ug/L 20 80 60-140102 25 3020ND16.0 20.5
1,1,2-Trichloroethane ug/L 20 86 60-140112 26 3020ND17.3 22.4
1,1-Dichloroethane ug/L 20 80 60-140108 29 3020ND16.0 21.5
1,1-Dichloroethene ug/L 20 81 60-140104 25 3020ND16.2 20.9
1,1-Dichloropropene ug/L 20 77 60-14099 25 3020ND15.4 19.8
1,2,3-Trichlorobenzene ug/L R1208560-140126 39 3020ND17.1 25.3
1,2,3-Trichloropropane ug/L 20 94 60-140117 22 3020ND18.9 23.5
1,2,4-Trichlorobenzene ug/L R1208860-140130 39 3020ND17.5 26.0
1,2,4-Trimethylbenzene ug/L 20 81 60-140106 27 3020ND16.3 21.3
1,2-Dibromo-3-chloropropane ug/L 20 77 60-14098 25 3020ND15.4 19.7
1,2-Dibromoethane (EDB)ug/L 20 91 60-140120 27 3020ND18.2 24.0
1,2-Dichlorobenzene ug/L R1208760-140120 33 3020ND17.3 24.1
1,2-Dichloroethane ug/L 20 80 60-140105 27 3020ND16.0 20.9
1,2-Dichloropropane ug/L 20 79 60-140107 30 3020ND15.8 21.3
1,3,5-Trimethylbenzene ug/L 20 84 60-140107 24 3020ND16.8 21.4
1,3-Dichlorobenzene ug/L R1208760-140121 33 3020ND17.3 24.1
1,3-Dichloropropane ug/L 20 86 60-140114 27 3020ND17.2 22.7
1,4-Dichlorobenzene ug/L R1208660-140119 32 3020ND17.3 23.8
2,2-Dichloropropane ug/L 20 73 60-14095 26 3020ND14.6 19.1
2-Chlorotoluene ug/L R1208360-140114 32 3020ND16.5 22.7
4-Chlorotoluene ug/L R1208560-140118 33 3020ND17.0 23.6
Benzene ug/L 20 83 60-140110 28 3020ND16.6 22.0
Bromobenzene ug/L 20 80 60-140108 30 3020ND16.1 21.6
Bromochloromethane ug/L 20 92 60-140119 25 3020ND18.5 23.8
Bromodichloromethane ug/L 20 83 60-140111 29 3020ND16.5 22.2
Bromoform ug/L 20 92 60-140122 28 3020ND18.4 24.5
Bromomethane ug/L 20 87 60-140115 28 3020ND17.4 23.1
Carbon tetrachloride ug/L 20 105 60-140139 28 3020ND20.9 27.7
Chlorobenzene ug/L 20 94 60-140126 29 3020ND18.8 25.2
Chloroethane ug/L 20 96 60-140129 29 3020ND19.2 25.8
Chloroform ug/L 20 77 60-140104 30 3020ND15.5 20.8
Chloromethane ug/L M0,R1205560-14077 34 3020ND11.0 15.5
cis-1,2-Dichloroethene ug/L 20 77 60-140103 28 3020ND15.5 20.6
cis-1,3-Dichloropropene ug/L 20 70 60-14092 28 3020ND13.9 18.5
Dibromochloromethane ug/L 20 91 60-140121 29 3020ND18.1 24.3
Dibromomethane ug/L 20 100 60-140131 27 3020ND19.9 26.3
Dichlorodifluoromethane ug/L 20 84 60-140107 25 3020ND16.7 21.4
Diisopropyl ether ug/L 20 71 60-14096 29 3020ND14.3 19.2
Ethylbenzene ug/L 20 93 60-140123 28 3020ND18.5 24.6
Hexachloro-1,3-butadiene ug/L 20 88 60-140118 29 3020ND17.5 23.5
Isopropylbenzene (Cumene)ug/L R12010060-140137 31 3020ND20.1 27.4
m&p-Xylene ug/L 40 98 60-140125 24 3040ND39.2 50.0
Methyl-tert-butyl ether ug/L 20 90 60-140116 25 3020ND18.1 23.3
Methylene Chloride ug/L R1206660-14091 32 3020ND13.3 18.3
n-Butylbenzene ug/L R1208060-140111 33 3020ND15.9 22.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/20/2010 01:39 PM Page 22 of 25
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9266897
16143 Agrotech
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
427306MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9266623007
427307
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
n-Propylbenzene ug/L R1208760-140121 32 3020ND17.4 24.2
Naphthalene ug/L 20 88 60-140115 26 3020ND18.2 23.6
o-Xylene ug/L 20 94 60-140124 27 3020ND18.8 24.7
sec-Butylbenzene ug/L R1208760-140124 35 3020ND17.4 24.9
Styrene ug/L 20 87 60-140106 20 3020ND17.4 21.1
tert-Butylbenzene ug/L R1209260-140132 36 3020ND18.4 26.4
Tetrachloroethene ug/L 20 102 60-140138 29 3020ND20.6 27.7
Toluene ug/L 20 87 60-140113 27 3020ND17.3 22.6
trans-1,2-Dichloroethene ug/L 20 78 60-140101 26 3020ND15.5 20.2
trans-1,3-Dichloropropene ug/L 20 71 60-14093 27 3020ND14.2 18.7
Trichloroethene ug/L 20 96 60-140127 27 3020ND19.3 25.4
Trichlorofluoromethane ug/L 20 90 60-140116 25 3020ND18.0 23.2
Vinyl chloride ug/L 20 79 60-14098 21 3020ND15.7 19.5
1,2-Dichloroethane-d4 (S)%90 70-13088
4-Bromofluorobenzene (S)%113 70-130113
Dibromofluoromethane (S)%92 70-13092
Toluene-d8 (S)%97 70-13097
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/20/2010 01:39 PM Page 23 of 25
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALIFIERS
Pace Project No.:
Project:
9266897
16143 Agrotech
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution ofthe sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes.
U - Indicates the compound was analyzed for, but not detected.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater thanthe blank or were below the reporting limit.P8
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/20/2010 01:39 PM Page 24 of 25
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
9266897
16143 Agrotech
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
9266897001 OEXT/9723 GCSV/7462MW-2 MADEP EPH MADEP EPH
9266897002 OEXT/9723 GCSV/7462MW-3 MADEP EPH MADEP EPH
9266897001 GCV/3966MW-2 MADEP VPH
9266897002 GCV/3966MW-3 MADEP VPH
9266897001 MPRP/6114 ICP/5649MW-2 SM 3030C EPA 200.7
9266897002 MPRP/6114 ICP/5649MW-3 SM 3030C EPA 200.7
9266897001 OEXT/9699 MSSV/3495MW-2 EPA 625 EPA 625
9266897002 OEXT/9699 MSSV/3495MW-3 EPA 625 EPA 625
9266897001 MSV/10574MW-2 SM 6200B
9266897002 MSV/10574MW-3 SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 04/20/2010 01:39 PM Page 25 of 25
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]