RA-2582_16143_CA_LSA_20100216_Terraine LSA Report

Limited Site Assessment Report – Phase I

Former Agrotec Incorporated

7840 NC Highway 35
Pendleton, North Carolina
Northampton County
Incident No. 16143
Latitude: 36° 28’ 57” N
Longitude: 77° 11’ 55” W

Prepared For:

North Carolina Department of
Environment and Natural Resources
1637 Mail Service Center Raleigh, North Carolina 27699-1637

Prepared By:

Terraine, Inc.
LongView Center
118 South Person Street Raleigh, North Carolina 27601

NCDENR Contract No. 16-1713-5C
Terraine Project No. 13-NCSL09-002

February 16, 2010

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Contents

Signature Page _______________________________________________________________________ ii
I. General Site Information ________________________________________________________ 1
II. Risk Classification _____________________________________________________________ 3
III. Receptor Information ___________________________________________________________ 7
IV. Geology and Hydrogeology ______________________________________________________ 9
V. Monitoring Well Installation and Sampling __________________________________________ 10
VI. Sampling Results _____________________________________________________________ 12
VII. Conclusions and Recommendations ______________________________________________ 13
VIII. References __________________________________________________________________ 14
Tables
Table 1 Contiguous Property Owners __________________________________________ App A Table 2 Water Supply Wells within 1,500 Feet of Source Area _______________________ App A
Table 3 Well Construction Details and Groundwater Elevation Data __________________ App A Table 4 Summary of Soil Analytical Results _____________________________________ App A
Table 5 Summary of Groundwater Analytical Results ______________________________ App A Figures
Figure 1 Topographic Map ___________________________________________________ App B
Figure 2 Aerial Site Photograph _______________________________________________ App B Figure 3 Site Map __________________________________________________________ App B
Figure 4 Water Supply Wells within 1,500 Feet of Source Area _______________________ App B Figure 5 Soil Boring Location and Analytical Data Map _____________________________ App B
Figure 6 Monitoring Well Location and Analytical Data Map _________________________ App B
Appendices
Appendix A Tables Appendix B Figures
Appendix C Site Photographs Appendix D Boring Log Key
Soil Boring Log Well Construction Record
Appendix E Soil Analytical Results Chain of Custody Records
Cooler Receipt Forms Laboratory Certificates of Analysis
Quality Control Certificates Groundwater Analytical Results
Chain of Custody Records Cooler Receipt Forms
Laboratory Certificates of Analysis Quality Control Certificates

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Signature Page
We, the undersigned, do hereby affirm that the information contained in this report is accurate and correct
to the best of our knowledge and belief.

Laura R. Robertson Date 2/16/2010
Staff Geologist Terraine, Inc.

Jad R. Bean Date 2/16/2010
Project Manager Terraine, Inc.

James L. Young, L.G. Date
2/16/2010
North Carolina Licensed Geologist # 1707
Senior Geologist Terraine, Inc.

Limited Site Assessment Report – Phase I – 2/16/2010 Incident No. 16143 Former Agrotec Incorporated Page 1 Pendleton, Northampton County, North Carolina
I. General Site Information
A. Facility Information
Facility Name: Former Agrotec Incorporated (Agrotec)
UST Incident #: 16143 Facility Address and County:
7840 NC Highway 35 Pendleton, NC 27845
Northampton County B. Current Property Owners
Severn Peanut Company 413 Main Street Severn, NC 27877 C. Contacts
1. Name, address, telephone number, and job title of primary contact person:
R.P. Watson, Property Manager of Severn Peanut Company 413 Main Street
Severn, NC 27877 [phone]
[phone]
2. Name, address, telephone number of primary consultant: Terraine, Inc. (Terraine)
LongView Center 118 South Person Street
Raleigh, NC 27601 [phone]
3. Name, address, telephone number, and State certification number of laboratory:
Pace Analytical Services, Inc. (Pace); State Certification # 37712 9800 Kincey Avenue, Suite 100
Huntersville, NC 28078 [phone]
D. Release and UST Information
The former Agrotec site is located at 7840 NC Highway 35 in Pendleton, Northampton County, North Carolina (Figures 1, 2, and 3, Appendix B). Historical information regarding this site was provided to
Terraine by the North Carolina Department of Environment and Natural Resources (NCDENR).
Information about this site was not available in the Registered Underground Storage Tank (UST) Database maintained by NCDENR.
The site consists of a single story warehouse building that is currently vacant and an open lot used for
truck parking by the Severn Peanut Company, which is located north of the site in Severn, NC. According to the Environmental Site Assessment (ESA) by Banks Environmental Consultants dated May 30, 1995,
soil and groundwater samples were collected in areas associated with painting operations and former USTs.
The interior of the facility was reported to contain a paint digester, cutting oils, used paint cans, old
batteries, a wash pit area with floor drain, painting operation residue, and minor leakage of cutting oil or hydraulic oil from manufacturing machinery.

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The exterior of the facility was reported to have:
• Five petroleum USTs o One fuel oil UST and two gasoline USTs were located southwest of the building
o One fuel oil UST was located east of the building o One diesel UST was located north of the building
• Two aboveground storage tanks (ASTs; one fuel oil, one kerosene) next to the southern wall of the building
• One general purpose dumpster and one metal recycle dumpster
• Paint drying metal boxes, which served as staging areas to dry excess paint
• Paint storage area
• Paint spray waterwash system with a sump well and water capture basin
• Enclosure for housing a former steam cleaner and two 55-gallon barrels of cleaning solution
• Storage area for new and used compressed gas cylinders
• Empty 55-gallon steel drum AST converted into a storage tank
• Burn pile used to burn pallets and other wood-based and paper items
• Septic tank near the southwest corner of the building
All five of the USTs and one of the ASTs have reportedly been removed from the site. Soil samples were collected from nine soil borings placed around the building. The soil samples collected near the gasoline
USTs were noted to smell of petroleum; however, only a soil sample collected from soil boring SB-4 and a groundwater sample collected from GW-2 had detected amounts of gasoline- and diesel-range organics.
These samples were collected on the eastern side of the warehouse building, south of the fuel oil UST. The report is unclear if the samples of groundwater were collected from permanent monitoring wells or
through the use of a Geoprobe.
According to the Pollution Incident/UST Leak Reporting Form dated June 1, 1995, a modified Phase I Environmental Investigation identified groundwater contamination of 58 parts per billion (ppb)
ethylbenzene; 1,400 ppb xylenes; and 31 ppb naphthalene. The amount of gasoline/diesel material leaking from the UST was unknown. Groundwater and soil samples were collected, and no water supply
wells were identified as impacted by the underground leak. This form does not specify which UST was leaking or from where the samples were taken. Six private domestic water supply wells were identified
within 1,500 feet down-gradient of the contaminant source; at least one was within 250 feet of the source area.
According to the June 26, 1995, NCDENR Response to the ESA, rain water seeping through the soil was
maintaining the contaminant concentrations above the regulatory limits, and the site did not appear to be a significant threat to human health or the environment. A Release Report/Complaint Log was attached to
the NCDENR Response. This document identified the release as a UST surface spill of gasoline and solvents.
According to the NCDENR Inspection Report dated June 29, 2006, the site was classified as “High Risk.”
The site was described as vacant and gated. County water “appeared to be available,” but water supply wells were located near the site. According to the ESA, the property was served by the county water
department. The NCDENR Recommendation for State Lead Cleanup Memo dated December 8, 2006, gives a brief site history and describes the lack of a responsible party for the release.
Based on this information, NCDENR requested that a Phase I Limited Site Assessment (LSA) be
conducted at this site. This report summarizes the assessment activities and results of the modified Phase I LSA conducted by Terraine in September, October, and December 2009 and January 2010.

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II. Risk Classification
A. Groundwater / Surface Water / Vapor Impacts
High Risk
1. Has the discharge or release contaminated any water supply wells including any used for non-
drinking purposes?
Yes. A groundwater sample collected by Terraine on October 8, 2009, from water supply well
WSW-3 indicated concentrations of toluene and lead above method detection limits (Table 5, Appendix A). Water supply well WSW-3 is located approximately 480 feet to the southeast of the
source area. A groundwater sample collected from water supply well WSW-2 indicated
concentrations of bromodichloromethane, chloroform, and dibromochloromethane above method detection limits; however, these compounds are generally not associated with a petroleum
release. Water supply well WSW-2 is located approximately 1,300 feet to the south of the source area. A complete discussion of petroleum contaminants identified in water supply well WSW-3 can be found in Section VII. Historical records provided by NCDENR did not contain information
about contamination of water supply wells associated with this release.
2. Is a water supply well used for drinking water located within 1,000 feet of the source area of the
discharge or release?
Yes. Two water supply wells utilized for drinking water were identified within 1,000 feet of the
source area. Water supply well WSW-3 is approximately 480 feet southeast from the source area,
and water supply well WSW-4 is approximately 250 feet southeast from the source area. The uses of water supply wells WSW-1 and WSW-5 are not known; however, as the properties are connected to municipal water, it is assumed that they are not used for drinking.
3. Is a water supply well used for any purpose (e.g., irrigation, washing cars, industrial cooling water, filling swimming pools) located within 250 feet of the source area of the release or
discharge?
Yes. Water supply well WSW-4 is located approximately 250 feet southeast of the source area
and is used for drinking water purposes.
4. Does groundwater within 500 feet of the source area of the discharge or release have the
potential for future use in that there is no other source of water supply other than the
groundwater?
No. Public water supplied by the Northampton County Water Department is available to the area
located within 500 feet of the source area; Terraine personnel identified multiple fire hydrants along Highway 35 during site reconnaissance on October 8, 2009 (Figure 4).
5. Do vapors from the discharge or release pose a threat of explosion because of accumulation of
the vapors in a confined space or pose any other serious threat to public health, public safety, or
the environment?
Unlikely. A water line running parallel to Highway 35 and west of the site was the only subsurface feature identified (Figure 3).
6. Are there any other factors that would cause the discharge or release to pose an imminent danger to public health, public safety, or the environment?
No. No factors were identified that would cause the release to pose an imminent danger to public
health, public safety, or the environment.

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Intermediate Risk
7. Is a surface water body located within 500 feet of the source area of the discharge or release? If
YES, does the maximum groundwater contaminant concentration exceed the surface water
quality standards and criteria found in 15A NCAC 2B .0200 by a factor of 10?
No. Based on site observations and a review of the topographic map (Figure 1), no surface water bodies were identified within 500 feet of the source area. According to the topographic map, the nearest stream is approximately 1,200 feet southwest of the site. This stream flows southwest
and is a tributary of Kirbys Creek.
8. Is the source area of the discharge or release located within a designated wellhead protection
area as defined in 42 USC 300h-7(e)?
No. The source area is not located within a designated wellhead protection area, according to the
following website maintained by NCDENR: http://swap.deh.enr.state.nc.us/swap_app/viewer.htm.
9. Is the discharge or release located in the Coastal Plain Physiographic Province as designated on
a map entitled “Geology of North Carolina” published by the Department in 1985? If YES, is the
source area of the release located in an area in which there is recharge to an unconfined or semi-
confined deep aquifer that is being used or may be used as a source of drinking water?
Yes. The site is located in the Coastal Plain Physiographic Province. The subject site is located in
the Undivided Yorktown Formation and Duplin Formation and does not appear to be located in an area where there is recharge to a confined or semi-confined deep aquifer currently being used as
a drinking water source.
10. Do the levels of groundwater contamination for any contaminant exceed the gross contamination levels (GCLs) established by the Department?
No. Groundwater samples collected from monitoring well MW-1 and water supply wells WSW-1,
WSW-2, WSW-3, and WSW-4 on October 8, 2009, as well as samples from monitoring well MW-2 on January 7, 2010, did not contain contaminant concentrations that exceeded the GCLs (Table 5).
B. Property Containing Source Area of Release Land Use
1. Does the property contain one or more primary or secondary residences (permanent or temporary)?
No. The site is currently the location of the former Agrotec Incorporated facility and is vacant (Figure 3). The nearest primary residence is approximately 250 feet to the southeast of the
source area (Clyde Martin residence, Table 1).
2. Does the property contain a school, daycare center, hospital, playground, park, recreation area,
church, nursing home, or other place of public assembly?
No. The nearest places of public assembly are the Willis Hare Elementary School and Roberts
Chapel. The Willis Hare Elementary School is located approximately 3,500 feet southeast of the site at 479 Willis Hare Road in Pendleton, NC. Roberts Chapel is located approximately 3,500
feet south of the site on Highway 35 in Pendleton, NC.

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3. Does the property contain a commercial (e.g., retail, warehouse, office/building space, etc.) or industrial (e.g., manufacturing, utilities, industrial research and development, chemical/petroleum
bulk storage, etc.) enterprise, an inactive commercial or industrial enterprise, or is the land undeveloped?
Yes. The site is currently the location of the former Agrotec Incorporated facility, an inactive industrial enterprise that includes a large warehouse building.
4. Do children visit the property?
Possibly. There is no access restriction to the parking lot on the west side of the site. However,
the warehouse, southern, and eastern portions of the site are fenced. It is possible that children visit the premises.
5. Is access to the property reliably restricted consistent with its use (e.g., by fences, security personnel, or both)?
Yes. Access to the warehouse and the majority of the property, except the parking lot area, is restricted by a locked fence.
6. Do pavement, buildings, or other structures cap the contaminated soil? If YES, what mechanisms are in place or can be put into place to ensure that the contaminated soil will remain capped in
the foreseeable future?
No. The source area is covered by grass. The source area could be capped by paving the area
with asphalt.
7. What is the zoning status of the property?
Industrial. The zoning status is not indicated on the following website, which is maintained by Northampton County, North Carolina: http://gis.northamptonnc.com/. Based on the site history,
Terraine assumes the property has a zoning status of industrial.
8. Is the use of the property likely to change in the next 20 years?
Unknown. The site is currently used for truck storage and peanut waste storage but may be utilized for another purpose in the future.
C. Property Surrounding Source Area of Discharge or Release
1. What is the distance from the source area of the discharge or release to the nearest primary or
secondary residence (permanent or temporary)?
The nearest primary residence is approximately 250 feet to the west of the source area (Clyde Martin residence, Table 1).
2. What is the distance from the source area of the release to the nearest school, daycare center,
hospital, playground, park, recreation area, church, nursing home, or other place of public assembly?
The nearest places of public assembly are the Willis Hare Elementary School and Roberts Chapel. This Willis Hare Elementary School is located approximately 3,500 feet southeast of the site at 479 Willis Hare Road, Pendleton, NC. Roberts Chapel is located approximately 3,500 feet
south of the site on Highway 35 in Pendleton, NC.

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3. What is the zoning status of the properties in the surrounding area?
Residential. The zoning status is not indicated on the following website, which is maintained by
Northampton County, North Carolina: http://gis.northamptonnc.com/. Based on the presence of residential properties in the surrounding area, Terraine assumes the surrounding area has a
zoning status of residential.
4. Briefly characterize the use and activities of the land in the surrounding area.
The property is surrounded by single-family residences, forested land, and open farm fields. Contiguous property owners are summarized in Table 1.

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III. Receptor Information
A. Water Supply Wells
Terraine performed a receptor survey on the subject site in October 2009. Water supply well survey forms were mailed to the owners of all parcels within a 500-foot radius of the site; no forms were returned.
According to information provided by the Northampton County Public Works Department and site observations, three water supply wells used for drinking water were identified within 1,500 feet of the
source area. Water supply well WSW-1 is approximately 450 feet from the source area, WSW-3 is approximately 480 feet from the source area, and water supply well WSW-4 is approximately 250 feet
from the source area. The use of water supply wells WSW-2 and WSW-5 is unknown; however, the properties where the wells are located are connected to municipal water. Therefore, it is assumed that
these wells are not used for drinking. Information regarding water supply wells is provided in Table 2.
B. Municipal Water Supply
Are public water supplies available within 1,500 feet of the source area of the release?
Yes. Public water supplied by the Northampton County Water Department is available to properties
located within 1,500 feet of the source area, according to site reconnaissance and personal
communication with several contiguous property residents on October 8, 2009. The properties on which water supply wells WSW-1, WSW-2, and WSW-5 are located are connected to municipal water.
C. Surface Water
Identify all surface water bodies (e.g., ditch, pond, stream, lake, river) within 1,500 feet of the source area
of the release.
Based on site observations and a review of the topographic map (Figure 1), no surface water bodies
were identified within 500 feet of the source area. According to the topographic map, the nearest stream is approximately 1,200 feet southwest of the site. This stream flows southwest and is a tributary of Kirbys
Creek.
D. Wellhead Protection Areas
Identify all planned or approved wellhead protection areas (e.g., ditch, pond, stream, lake, river) within 1,500 feet of the source area of the release. This information must be shown on the USGS topographic
map. Wellhead protection areas are defined in 42 USC 300h-7(e).
The area within 1,500 feet of the source area is not located within a designated wellhead protection area,
according to the following website maintained by NCDENR: http://swap.deh.enr.state.nc.us/ swap_app/viewer.htm.
E. Physiographic Province
According to the Geologic Map of North Carolina dated 1985, the site is located in the Undivided Yorktown Formation and Duplin Formation of the Coastal Plain Physiographic Province. The Yorktown
Formation has the following description: fossiliferous clay with varying amounts of fine-grained sand, bluish gray, shell material commonly concentrated in lenses; mainly in the area north of the Neuse River.
The Duplin Formation has the following description: shelly, medium- to coarse-grained sand, sandy marl, and limestone, bluish gray; mainly in the area south of the Neuse River.
F. Subsurface Structures
Water lines were identified running parallel to Highway 35, west of the site (Figure 3).

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G. Property Owners and Occupants
The property is owned by the Severn Peanut Company. The site is currently the location of a vacant
warehouse and fenced lot. Single family residences, forested land, and open farm fields surround the subject site. A summary of contiguous property owners is listed in Table 1.

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IV. Geology and Hydrogeology
Geologic and hydrogeologic observations were made during monitoring well installation activities
conducted by Terraine on September 24 and December 7, 2009. For soil boring SB-1T, brown silty sand was observed from the surface to a depth of 5 feet below surface grade (bsg). Brown sandy clay was
observed from 5 feet bsg to 10 feet bsg. Tan clayey sand was observed from 10 feet bsg to termination depth at 13 feet bsg. Groundwater was encountered at approximately 5 feet bsg. Soil boring SB-2T was
drilled and then converted into monitoring well MW-2. Soil from this boring was not properly collected, so a third soil boring, SB-3T, was drilled in order to collect representative soil samples and to properly
describe the subsurface adjacent to SB-2T. Moist, light brown clayey sand was observed from the surface to 7 feet bsg. Gray clayey sand was observed from 7 feet bsg to termination depth at 13 feet bsg.
Groundwater was encountered at approximately 5 feet bsg. Soil boring logs are included in Appendix D. Based on topography, the anticipated groundwater flow direction is to the southwest (Figure 1).

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V. Monitoring Well Installation and Sampling
A. Soil Sampling

Terraine personnel mobilized to the site on September 24, 2009, to install soil boring SB-1T for the collection of a soil sample. Based on site observations, soil boring SB-1T was placed adjacent to the
southwest corner of the building and within 20 feet of the former fuel oil UST and two gasoline USTs (Figure 5). A soil sample was collected with a track-mounted direct push technology Geoprobe®
6620DPT using a device that allows for continuous soil core sampling in 5-foot sections. The boring was terminated at 15 feet bsg. Upon retrieval of the first soil core, a soil sample from 4-5 feet bsg was
collected into a laboratory prepared container and placed on ice. The remaining soil core was logged for physical characteristics, and a portion was sealed in a resealable plastic bag. The bagged portion was
allowed to volatilize for a minimum of 15 minutes, after which the headspace within the bag was field-screened for the presence of volatile organic vapors with a calibrated Mini RAE Systems™ photo-
ionization detector (PID). A PID reading of 1.0 parts per million (ppm) at 4-5 feet bsg was recorded. The soil sample was submitted for laboratory analysis under proper chain of custody controls to the Pace
laboratory in Huntersville, North Carolina, for analysis by:
• Environmental Protection Agency (EPA) Method 8260B for volatile organic compounds (VOCs),
modified to include diisopropyl ether (IPE) and methyl tert-butyl ether (MTBE)
• EPA Method 8270 for semi-volatile organic compounds (SVOCs)
• Massachusetts Department of Environmental Protection (MADEP) Method for volatile petroleum
hydrocarbons (VPH)
• MADEP Method for extractable petroleum hydrocarbons (EPH) Terraine personnel remobilized to the site on December 7, 2009, to install soil boring SB-2T for the collection of a soil sample. Based on site observations, soil boring SB-2T was placed on the southern end
of the east side of the building and within 20 feet of 1995 soil borings SB-4, SB-7, SB-8, and SB-9, as well as groundwater samples GW-2, GW-3, GW-4, and GW-5. Due to improper sample collection from soil
boring SB-2T, an additional soil boring (SB-3T) was drilled several feet from soil boring SB-2T (Figure 5).
A soil sample was collected from soil boring SB-3T with a track-mounted direct push technology Geoprobe® 6620DPT using a device that allows for continuous soil core sampling in 5-foot sections. The boring was terminated at 13 feet bsg. Upon retrieval of the first soil core from soil boring SB-3T, soil
samples from 4-5 feet bsg and 9-10 feet bsg were collected into laboratory prepared containers and placed on ice. The remaining soil core was logged for physical characteristics, and portions were sealed
in resealable plastic bags. The bagged portions were allowed to volatilize for a minimum of 15 minutes, after which the headspaces within the bags were field-screened for the presence of volatile organic
vapors with a calibrated PID. PID readings of 0.1 ppm at 4-5 feet bsg and 6.5 ppm at 9-10 feet bsg were recorded. The soil samples were submitted for laboratory analysis under proper chain of custody controls
to the Pace laboratory in Huntersville, North Carolina, for analysis by:
• EPA Method 8260B for VOCs, modified to include IPE and MTBE
• EPA Method 8270 for SVOCs
• MADEP Method for VPH
• MADEP Method for EPH
B. Groundwater Sampling
On September 24, 2009, soil boring SB-1T was converted into monitoring well MW-1. Figure 6 and
photos in Appendix C illustrate the location of the monitoring well. The monitoring well was installed to a total depth of 13 feet bsg with the screen set between 13 feet bsg and 3 feet bsg. The well was of
standard Type II construction, which included 10 feet of 2-inch diameter, 0.010-inch slotted polyvinyl chloride (PVC) screen and 3 feet of 2-inch diameter PVC riser. A #2 sand filter was placed around the
annulus of the well from a depth of 13 feet to 3 feet bsg. High-yield bentonite chips were placed above the

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sand pack from a depth of 2 feet bsg to 1 feet bsg. Neat cement grout annular sealant was placed above the bentonite seal to near surface grade. The well was capped with a locking expansion plug; protected
with a flush-mount, bolt-down, 8-inch diameter manhole cover; and finished with a sloping concrete apron around the manhole cover to reduce water infiltration during rainfall events. The well construction record
is included in Appendix D.
Monitoring well MW-1 was developed on September 24, 2009, using a decontaminated submersible pump. On October 8, 2009, Terraine collected a groundwater sample from monitoring well MW-1. Depth
to water was measured at 5.48 feet below top of casing using a decontaminated water level indicator. The monitoring well was purged in excess of three well volumes and sampled using a new disposable bailer.
Groundwater samples were collected from water supply wells WSW-1, WSW-2, WSW-3, and WSW-4 from a sink inside the residence, a spigot on the well house, a spigot on the front of the house, and a
spigot on the well house, respectively. Water supply wells were purged for 15 minutes prior to sampling. The groundwater samples were transferred into laboratory prepared containers, immediately placed on
ice, and submitted under proper chain of custody controls to Pace for analysis by:
• Standard Method 6200B for VOCs
• MADEP VPH
• MADEP EPH
• EPA Method 625
• EPA Method 3030C for lead
On December 7, 2009, soil boring SB-2T was converted into monitoring well MW-2. Figure 6 and photos
in Appendix C illustrate the location of the monitoring well. The monitoring well was installed to a total depth of 13 feet bsg with the screen set between 13 feet bsg and 3 feet bsg. The well was of standard
Type II construction, which included 10 feet of 2-inch diameter, 0.010-inch slotted polyvinyl chloride (PVC) screen and 3 feet of 2-inch diameter PVC riser. A #2 sand filter was placed around the annulus of
the well from a depth of 13 feet to 3 feet bsg. High-yield bentonite chips were placed above the sand pack from a depth of 2 feet bsg to 1 feet bsg. Neat cement grout annular sealant was placed above the
bentonite seal to near surface grade. The well was capped with a locking expansion plug; protected with a flush-mount, bolt-down, 8-inch diameter manhole cover; and finished with a sloping concrete apron
around the manhole cover to reduce water infiltration during rainfall events. The well construction record is included in Appendix D.
Monitoring well MW-2 was developed on December 7, 2009, using a decontaminated submersible pump.
On January 7, 2010, Terraine collected a groundwater sample from monitoring well MW-2. Depth to water was measured at 1.82 feet below top of casing using a decontaminated water level indicator. Depth to
water was also measured on this date in monitoring well MW-1 as 3.84 feet below top of casing. Monitoring well MW-2 was purged in excess of three well volumes and sampled using a new disposable
bailer. The groundwater sample was transferred into laboratory prepared containers, immediately placed on ice, and submitted under proper chain of custody controls to Pace for analysis by:

• Standard Method 6200B for VOCs
• MADEP VPH
• MADEP EPH
• EPA Method 625
• EPA Method 3030C for lead

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VI. Sampling Results
A. Soil Sampling Results

The soil sample collected on September 24, 2009, from soil boring SB-1T at a depth of 4-5 feet bsg did not contain contaminant concentrations above method detection limits.
Contaminant concentrations were not identified above method detection limits in the soil sample collected
on December 7, 2009, from soil boring SB-3T at a depth of 4-5 feet bsg. Concentrations of acetone, C5-C8 aliphatics, C9-C12 aliphatics, and C9-C10 aromatics were identified above the method detection limits
but below the MSCCs in the soil sample collected from soil boring SB-3T at a depth of 9-10 feet bsg. This soil sample was taken from below the water table.
A summary of the laboratory analytical results for the soil samples collected from soil borings SB-1T and
SB-3T is presented in Table 4. Figure 5 depicts the soil analytical results and the soil boring locations. The soil boring logs are included in Appendix D. Laboratory certificates of analysis and the chain of
custody forms are included in Appendix E. B. Groundwater Sampling Results
In the groundwater sample collected from monitoring well MW-1 on October 8, 2009, target contaminant
concentrations were not identified above the 15A NCAC 2L.0202 (2L) Standards; lead was detected above method detection limits but below 2L Standards.
The groundwater samples collected from water supply wells WSW-1 and WSW-4 did not identify target
contaminant concentrations above method detection limits. Groundwater samples from water supply well WSW-3 contained toluene and lead above method detection limits but below 2L Standards. Groundwater
samples from water supply well WSW-2 contained bromodichloromethane, chloroform, and dibromochloromethane above method detection limits but below 2L Standards. According to an e-mail communication with Pace Project Manager Renee Spencer, the three compounds identified in water
supply well WSW-2 can sometimes be present as a result of a disinfection process (i.e., chlorinating a
private well) and are three of the four trihalomethanes. NCDENR was notified of the contamination detected in water supply wells WSW-2 and WSW-3 following receipt of the analytical results on
November 11, 2009.
The groundwater sample collected from monitoring well MW-2 on January 7, 2010, contained contaminant concentrations above method detection limits but below the 2L Standards for 4-Chloro-3-
methylphenol; 2-chlorophenol; 3,3-dichlorobenzidine; 2,4-dimethylphenol; 4-nitrophenol; N-nitrosodimethylamine; and phenol. Lead was identified above 2L Standards.
Laboratory analytical results are summarized in Table 5. The monitoring well location and groundwater analytical results are shown in Figure 6. Laboratory certificates of analysis and the chain of custody forms
are included in Appendix E.

Limited Site Assessment Report – Phase I – 2/16/2010 Incident No. 16143 Former Agrotec Incorporated Page 13 Pendleton, Northampton County, North Carolina
VII. Conclusions and Recommendations
A. Conclusions

Terraine has performed a LSA – Phase I on the subject property. Target petroleum contaminants were not detected above method detection limits in the soil sample collected from SB-1T at 4-5 feet bsg on
September 24, 2009. Target petroleum contaminants were not detected above method detection limits in the soil sample collected from SB-3T at 4-5 feet bsg on December 7, 2009. The soil sample collected at
9-10 feet bsg contained target compounds above method detection limits but below 2L Standards; this sample was collected below the water table.
Lead was detected above the method detection limit but below the 2L Standard in a groundwater sample
collected from monitoring well MW-1 on October 8, 2009. Lead was detected above the 2L Standard in the groundwater sample collected from monitoring well MW-2 on January 7, 2010.
Contaminants were detected in groundwater samples collected from water supply wells WSW-2 and
WSW-3 on October 8, 2009. Groundwater contaminants identified in water supply well WSW-2 are commonly associated with disinfection processes, while the contaminants identified in water supply well
WSW-3 are commonly associated with petroleum releases. Target contaminants were not identified above method detection limits in groundwater samples collected from water supply wells WSW-1 and
WSW-4.
The receptor survey identified five water supply wells located within 1,500 feet of the source area; two of these water supply wells are used as sources of drinking water. According to regulations established in
15A NCAC 2L.115, the subject site appears to warrant a “High Risk” classification due to petroleum contamination detected in water supply well WSW-3 and due to the presence of two water supply wells
used for drinking water within 1,000 feet of the source area; one of these water supply wells is within 250 feet of the source area.
A residential land use classification is appropriate for this site.
B. Recommendations

Terraine recommends the following actions:
• Abandon water supply well WSW-3 and connect the associated residence to municipal water.

• Resample groundwater from monitoring well MW-2 using low flow sampling techniques in order to minimize disturbance to the water column. This will help to determine if the lead concentration
reported during the January 2010 sampling event may have been a result of high turbidity rather than actual groundwater conditions.

Limited Site Assessment Report – Phase I – 2/16/2010 Incident No. 16143 Former Agrotec Incorporated Page 14 Pendleton, Northampton County, North Carolina
VIII. References
Banks Environmental Consultants. Environmental Site Assessment, May 30, 1995.
NCDENR. Division of Water Resources Ground Water Database Access, from:
http://www.ncwater.org/Data_and_Modeling/Ground_Water_Databases/.
NCDENR. Inspection Report, June 29, 2006.
NCDENR. NC SWAPinfo, from: http://swap.deh.enr.state.nc.us/Swap_app/viewer.htm.
NCDENR. Pollution Incident/UST Leak Reporting Form, June 1, 1995.
NCDENR. Recommendation for State Lead Cleanup Memo, December 8, 2006. NCDENR. Response to ESA, June 26, 1995.
North Carolina Geological Survey. Geologic Map of North Carolina. 1985.
Northampton County, North Carolina GIS Website, from: http://gis.northamptonnc.com/.

Limited Site Assessment Report – Phase I – 2/16/2010 Incident No. 16143 Former Agrotec Incorporated Pendleton, Northampton County, North Carolina
Appendix A

Table 1 Contiguous Property Owners Table 2 Water Supply Wells within 1,500 Feet of Source Area
Table 3 Well Construction Details and Groundwater Elevation Data Table 4 Summary of Soil Analytical Results
Table 5 Summary of Groundwater Analytical Results
Table 1Contiguous Property OwnersFormer Agrotec Incorporated7840 NC Highway 35Pendleton, NCNorthampton CountyNCDENR Incident No. 16143PARCEL ID PROPERTY OWNER PARCEL ADDRESS OWNER ADDRESSDIRECTION FROM SITE302173Severn Peanut Company7840 NC Highway 35 Pendleton, NC413 Main Street Severn, NCSite301071John & Sandra Woodard8029 NC Highway 35 Pendleton, NC8173 NC Highway 35 Pendleton, NCNorth & Northwest302600 Albert & Marion Ridley7941 NC Highway 35 Pendleton, NC561 Menola Road Woodland, NC 27897Northwest304454 Ronald Woodard unlisted208 Lewiston Court Cary, NC 27513West302458 Sarah Allen (Heirs) unlisted Detroit, MI 48207 South1300582 Clyde Martin7748 NC Highway 35 Pendleton, NC7748 NC Highway 35 Pendleton, NCSoutheast301370 M.B. Johnson Farms unlistedC/O Linwood Taylor Murfreesboro, NC East301659John & Sandra Woodardunlisted8173 NC Highway 35 Pendleton, NCEast & NortheastProperty addresses obtained as listed from the Northampton County GIS Website (http://gis.northamptonnc.com/mapguide/northamptongis/)
Table 2
Water Supply Wells within 1,500 Feet of Source Area
Former Agrotec Incorporated
7840 NC Highway 35
Pendleton, NC
Northampton County
NCDENR Incident No. 16143
WELL ID PARCEL ID PROPERTY OWNER PROPERTY ADDRESS WATER USE
MUNICIPAL
WATER DISTANCE
301217 Thomas & Elvornia Long
7795 NC Hwy 35 N,
Pendleton, NC Unknown YES
301854 Ernest & Bernice Warren
7748 NC Hwy 35 N,
Pendleton, NC Drinking NO
WSW-2 300434
Jarvis & Gerthare
Vaughan
7687 NC Hwy 35,
Pendleton, NC Unknown YES
1,300 Feet
SOUTH
WSW-3 301526 Roger & Mary Everette
7744 NC Hwy 35
Pendleton, NC Drinking NO
480 Feet
SOUTHEAST
WSW-4 1300582 Mrs. Clyde Martin
7748 NC Hwy 35
Pendleton, NC Drinking NO
250 Feet
SOUTHEAST
WSW-5 302600 Albert & Marion Ridley
7941 NC Hwy 35
Pendleton, NC Unknown YES
900 feet
NORTHWEST
Parcel information obtained from the Northampton County GIS website: gis.northamptonnc.com.
Water Use information obtained from the Northampton County Public Works Department.
WSW-1 450 Feet
SOUTHWEST
Table 3Well Construction Details and Groundwater Elevation DataFormer Agrotec Incorporated7840 NC Highway 35Pendleton, NCNorthampton CountyNCDENR Incident No. 16143WELL IDINSTALLATION DATETOC ELEVATION SCREEN INTERVAL WELL DIAMETER (IN.)TOTAL DEPTHDEPTH TO WATERGROUNDWATER ELEVATION 3.84 (1/7/2010) 96.165.48 (10/8/2009) 94.52MW-2 12/7/2009 NM 3-13 2 13 1.82 (1/7/2010) NMTOC - Top of casingNM - Not measuredUnits measured in feet unless otherwise noted. Groundwater elevations relative to an arbitrary benchmark of 100.00 feet at MW-1 TOC. MW-1 9/24/2009 100.00 3-13 2 13
Table 4
Summary of Soil Analytical Results
Former Agrotec Incorporated
7840 Highway 35 North
Pendleton, NC
Northampton County
NCDENR Incident No. 16143
EPA 8260B:
Benzene 0.0056 18
Toluene 7.3 3,200
Ethylbenzene 4.6 1,560
Xylenes (total)5 3,129
Total BTEX NE NE
Methyl tert-Butyl Ether 0.92 213
n-Butylbenzene 4.30 626
sec-Butylbenzene 3.30 626
Isopropylbenzene 1.70 1,564
p-Isopropyltoluene NE NE
Naphthalene 0.58 313
n-Propylbenzene 1.70 626
1,2,4-Trimethylbenzene 7.5 782
1,3,5-Trimethylbenzene 7.3 782
Acetone 2.8 1,564
MADEP VPH/EPH:
72 939
C9-12 Aliphatics ND ND 66.5
C9-18 Aliphatics ND ND ND
Considered
Immobile 93,860
C9-10 Aromatics ND ND 14.1
C11-22 Aromatics ND ND ND
Data expressed in parts per million (mg/kg)
NE - No Standard Established
ND - None Detected (below method detection limits)
A complete list of target compounds is included with the laboratory report in Appendix E
MSCC - Maximum Soil Contaminant Concentration
EPA - Environmental Protection Agency
MADEP - Massachusetts Department of Environmental Protection
VPH - Volatile Petroleum Hydrocarbons
EPH - Extractable Petroleum Hydrocarbons
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
MSCC (Soil-to-
Groundwater)
Residential
Cleanup
Levels
C9-C18 Aliphatic
Hydrocarbons
C9-C22 Aromatic
Hydrocarbons
C5-C8 Aliphatic Hydrocarbons
C19-C36 Aliphatic Hydrocarbons
ND
SB-1 4-5'
ND
ND
ND
ND
14:00
ND
ND
ND
ND
ND
ND
Sample ID:
Depth (feet):
Sample Date:
Sample Time:
ND
4-5
9/24/09
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
SB-3T 4-5'
4-5
12/7/09
11:15
ND
ND
ND
ND
ND
ND
ND
ND
469
3,300 9,386
34
ND
ND
ND
ND
ND
SB-3T 9-10'
9-10
12/7/09
11:30
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
20.8
ND
ND ND 0.013 J
ND
ND
ND
Table 5Summary of Groundwater Analytical ResultsFormer Agrotec Incorporated7840 NC Highway 35Pendleton, NCNorthampton CountyNCDENR Incident No. 16143C5-C8 C19-C36Well ID Sample DateAliphaticsC9-C12 AliphaticsC9-C18 AliphaticsAliphaticsC9-C10 AromaticsC11-C22 AromaticsND ND ND NDND ND ND NDND ND ND NDND ND ND NDND ND ND NDND ND ND ND1 600 600 500 20 70 0.02 6 NE 70 0.4 NE NE NE 100 NE NE 30 42042,00015Gross Contamination Level (GCL)5,000 260,000 84,500 85,500 20,000 70,000 50 6,000 NE 70,000 400 NE NE NE 100,000 NE NE 30,000 NE NE 15,000All results expressed in µg/L (ppb) Values shown in bold, italicized, highlighted font indicate concentrations that exceed the 2L StandardsND - None Detected (below method detection limits) MADEP - Massachusetts Department of Environmental ProtectionNE - No Standard Established VPH - Volatile Petroleum HydrocarbonsMTBE - Methyl tert-butyl ether EPH - Extractable Petroleum HydrocarbonsIPE - Diisopropyl ether J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limitEDB - 1,2-DibromoethaneWSW-1WSW-2WSW-3WSW-4MADEP VPH & EPHLeadC9-C18 Aliphatics C9-C22 AromaticsND ND10/8/2009 ND ND ND ND NDND ND ND ND NDND ND ND ND ND NDNDNDND10/8/2009 ND ND ND NDNDNDND ND ND 1.5 0.91.810/8/200910/8/2009 ND 0.53 NDND NDNDND NDNDND10/8/2009 ND ND ND ND ND15A NCAC 2L.0202 (2L) StandardMW-1MW-2NDNDND ND ND ND NDND ND NDND ND ND ND ND1/7/2010 ND ND ND ND NDChloroformND ND4-NitrophenolN-NitrosodimethylamineND ND6.2NDNDNDNDND NDND ND ND ND NDND ND NDND NDNDND ND NDNDND NDNDND ND NDBenzeneMTBEXylenesNDNaphthaleneBromodichloromethaneNDEDBIPEEthylbenzeneNDDibromochloromethaneND18.7 94-Chloro-3-methylphenolTolueneNDND ND NDND ND8.7 JNE NEND ND ND2-Chlorophenol3,3-Dichlorobenzidine2,4-DimethylphenolNDND7.39.1ND NDND ND2164,200 210NDNDND NDPhenolND ND ND50.1 J 15.7 8.7ND ND ND

Limited Site Assessment Report – Phase I – 2/16/2010 Incident No. 16143 Former Agrotec Incorporated Pendleton, Northampton County, North Carolina
Appendix B

Figure 1 Topographic Map Figure 2 Aerial Site Photograph
Figure 3 Site Map Figure 4 Water Supply Wells within 1,500 Feet of Source Area
Figure 5 Soil Boring Location and Analytical Data Map Figure 6 Monitoring Well Location and Analytical Data Map

Limited Site Assessment Report – Phase I – 2/16/2010 Incident No. 16143 Former Agrotec Incorporated Pendleton, Northampton County, North Carolina
Appendix C

Site Photographs
Site Photographs
Former Agrotec Incorporated
7840 NC Highway 35
Pendleton, NC
Northampton County
NCDENR Incident # 16143
View to north along western side of building, which faces NC Highway
35.
1 of 6
View to south toward monitoring well MW-1.2 of 6
Site Photographs
Former Agrotec Incorporated
7840 NC Highway 35
Pendleton, NC
Northampton County
NCDENR Incident # 16143
Monitoring well MW-1, view to the southeast.3 of 6
Monitoring well MW-2, view to the north.4 of 6
Site Photographs
Former Agrotec Incorporated
7840 NC Highway 35
Pendleton, NC
Northampton County
NCDENR Incident # 16143
Bucket of Round-Up in swampy area 20 feet west of monitoring well
MW-2.
5 of 6
Runoff grate approximatley 20 feet southwest of monitoring well MW-2.6 of 6

Limited Site Assessment Report – Phase I – 2/16/2010 Incident No. 16143 Former Agrotec Incorporated Pendleton, Northampton County, North Carolina
Appendix D

Boring Log Key Soil Boring Logs
Well Construction Records

SILT
MUDSTONE
SAND
GRAVEL
LIMESTONE
DOLOMITE
CHERT
METAMORPHIC BEDROCK
IGNEOUS
COAL
CONCRETE
ASPHALT
ORGANIC SOIL
FILL
CLAY
OOLITES,PISOLITESCONCTRETIONS,ETC.
BEDDING PLANES
CALCITE,LIMESTONE
FOSSILS CHERT
SAND
CLAY,SHALE
DOLOMITE H
SILT
FRACTURES
VISIBLE POROSITY
HYDROCARBON ODOR,STAINING,FREE PRODUCT
MODIFYING COMPONENTS,CEMENTS,ETC.
SOIL AND ROCK LITHOLOGY SYMBOLS
SOLID PIPE WITHNOPACKING
GROUT SEALAROUNDSOLID PIPE
BENTONITE SEALAROUNDSOLIDPIPE
SOLID PIPEPACKEDINSAND
SLOTTED PIPEPACKEDINSAND
END CAP ON SLOTTEDPIPEPACKEDINSAND
SS
ST P
CS OVD
SPLIT SPOON SAMPLE75-100%RECOVERY
SHELBY TUBE SAMPLE50-75 %RECOVERY
CONTINUOUS SAMPLE25-50%RECOVERYANALYZEDWITHOVD
COMPLETION DIAGRAM SYMBOLS SAMPLE SYMBOLS
WATER LEVELFIRSTENCOUNTERED
WATER LEVELUPONCOMPLETION
SS -SPLIT SPOONST-SHELBY TUBECS-CONTINUOUS SAMPLEOVD-ORGANIC VAPOR DETECTORk-PERMEABILITY
X -75-100%RECOVERY>-50-75%RECOVERY<-25-50%RECOVERYI-0-25%RECOVERY
SYMBOLS AND ABBREVIATIONS USED IN BORING LOGS
31SB-1T
MW-1
2"PVCCasing
PortlandCementGrout
2"PVCScreen(10-slot)
End Plug
#2 FilterSand
BentoniteSeal
5.4810/8/09
5.09/24/09 82608270VPHEPH
CS BROWN SILTY SAND,MOIST
ORGANIC SOIL
Soil boring SB-1T was converted to monitoring well MW-1 on September 24,2009.
1.0 ppm
CS
CS
BROWN SANDY CLAY,WET
TAN CLAYEY SAND,WET
9/24/09 2:00
9/24/09 4:00
Vince Federle,Geologic Exploration,Inc.
START DATE &TIME:
COMP.DATE&TIME:
LOGGEDBY:
DRILLER:
DRILLING METHOD:
ELEV (MSL):T.D.(MSL):
COMMENTS:
Incident#:BORING#
WELL#
PG
OF
FACILITY NAME:
COMPLETION
DIAGRAM
BOREHOLE DIAMETER:WATERLEVELPENETRATIONRATEMSL DEPTH /
TIME
GRAPHIC
LITHOLOGY OVD
SAMPLES&CORES
TYPEREC.ANALDESCRIPTION(Color,Texture,Structure,etc.)
Standard Boring Log
0 1 2 3 4 5 6 7 8
0
30
40
20
10
0
30
40
10
20
16143
LOCATION MAP
BORINGTERMINATEDAT15 FEET BSG
Former Agrotec Incorporated,7840 Highway 35,Pendleton,NC,Northampton Co.
Laura Robertson,Terraine
Geoprobe®6620DPT
32
12/7/2009 10:00
12/7/2009 12:00
SB-2TMW-2
2"PVCCasing
PortlandCementGrout
2"PVCScreen(10-slot)
End Plug
#2 Filter
Sand
BentoniteSeal
1.821/7/10
4.012/7/09
TAN SAND,MOIST
ORGANIC SOIL
Soil boring SB-2T was converted to monitoring well MW-2 on December 7,2009.
TAN SANDY CLAY,WET
Danny Summers,Geologic Exploration,Inc.
START DATE &TIME:
COMP.DATE&TIME:
LOGGEDBY:
DRILLER:
DRILLING METHOD:
ELEV (MSL):T.D.(MSL):
COMMENTS:
Incident#:BORING#
WELL#
PG
OF
FACILITY NAME:
COMPLETION
DIAGRAM
BOREHOLE DIAMETER:WATERLEVELPENETRATIONRATEMSL DEPTH /
TIME
GRAPHIC
LITHOLOGY OVD
SAMPLES&CORES
TYPEREC.ANALDESCRIPTION(Color,Texture,Structure,etc.)
Standard Boring Log
0 1 2 3 4 5 6 7 8
0
30
40
20
10
0
30
40
10
20
16143
LOCATION MAP
BORINGTERMINATED AT13 FEET BSG
Former Agrotec Incorporated,7840 Highway 35,Pendleton,NC,Northampton Co.
Laura Robertson,Terraine
Geoprobe®6620DPT
33
12/7/2009 10:00
12/7/2009 12:00
SB-3T
82608270
VPHEPH
CS TAN SAND,MOIST
ORGANIC SOIL
Soil boring SB-3T was drilled directly adjacent soil boring SB-2T,
in order to collect soil samples according to protocol,representative of SB-2T.
0.1 ppm
CS
CS
TAN SANDY CLAY,WET6.5 ppm 82608270
VPHEPH
Danny Summers,Geologic Exploration,Inc.SB-3T
START DATE &TIME:
COMP.DATE&TIME:
LOGGEDBY:
DRILLER:
DRILLING METHOD:
ELEV (MSL):T.D.(MSL):
COMMENTS:
Incident#:BORING#
WELL#
PG
OF
FACILITY NAME:
COMPLETION
DIAGRAM
BOREHOLE DIAMETER:WATERLEVELPENETRATIONRATEMSL DEPTH /
TIME
GRAPHIC
LITHOLOGY OVD
SAMPLES&CORES
TYPEREC.ANALDESCRIPTION(Color,Texture,Structure,etc.)
Standard Boring Log
0 1 2 3 4 5 6 7 8
0
30
40
20
10
0
30
40
10
20
16143
LOCATION MAP
BORINGTERMINATED AT13 FEET BSG
Former Agrotec Incorporated,7840 Highway 35,Pendleton,NC,Northampton Co.
Laura Robertson,Terraine
Geoprobe®6620DPT
-l[oNR,E^srD.Elrrr,4z*u"r.onrr*o"tto*,*".o*o
Nodh Carolina Departrnent of Environment and Natural Resources- Division of Water Quality
WELL CONTRACTOR Cf,RTIFICATION # 2579
.I. WELL CONTRACTOR:
DANNY SUMMERS
Wdl Contractor (lndividual) Name
GEOLOGIC EXPLORATION, INC,
Wdl Contractd Company Name
STREETADDRESS 176 COMMERCE BLVD
STATESVILLE NC 28625
City or Tom State Zip Code
{ 704 )- 872-7986
Areacode Phonenumber
2. WELL INFORMATION:
SITE WELL ID #fif
STATE WELL PERMIT#1lf applicable)-
1€Wffi+mr*PERMIT#(if ryPlicable)' :
WELL USE (Check Applicable Box) Monitaing E Municipal/Public n
lridustriavCornmercid tr Agricultural tr Recovery tr Iniection tr
llnigationtr Other n $st use)
I olrr oruu-e}-:2to7los-
]TIMECOMPLETED- AMtr PMtr
3.]WELL LOCATION:
ctTy: PeNoleroN cou1rY xgxIIlYT9N
7840 NC HIGHWAY35 NORTH 27862
u)
]TOPOGRAPITIC I LAND SETTING:
Eslope trValley trFlat trRidge D other
(check appropriate box)
,I-ATITUDE May be in degees,
minutes, seconds or
in a decimal formatLONGITUDE
Latitude/longitude source: nGPS nTopographic map
(bcatbn of weil must be shown on a USGS topo map aN
atfached fo this form frnot usrhg GPS)
4. FAGILITY- is ttre name ol the business whefe the well is located.
FACILITY lD #{if applicabl
NAME OF FACtLtTy reR()TEc,|NC
STREET ADDRESS 7840 NC HIGHWAY 35 NORTH
PENDLETON NC 27862
City or Tottvn State
NCDEHNRCONTACT PERSON
MAILING ADDRESS 601 OBERLIN ROAD
RALEIGH
City or Tom-r State Zip Code
(_J:
Area code - Phme number
5. WELL DETAILS:
A; TOTAL DEPTH:13.0 FEET
bt DOESWELLREPLACEEXSTINGWELL? YESE NOE
c; W,ATER LEVEL Belo\,vTop of Casing: 4.0 FT.
(Use "+" if Above Top of Casing)
Zip Code
d.TOP oF cAslNG lS 0.0 FT. Abo\e Land Surface*
.Top of casing terminated aVor belorrv land surface may require
a variance in accordance with 15A NCAC 2C .01 18.
ytELD (gpm): N/A METHoD oF TEST-IiA
DISINFECTION: Type NA Amount$
WATER zoNES (depth):
Frorn- T Frorn- To-
Frorn-To- From-To-
From-To- Fror-T
e.
t.
s,
6.CASING:
F,,"-g!-Dfltt 3- Ft. 2l'ttEflu'
Frorn- To- Ft.-
7. GROUT: Depth Material
Thickness/gsglt ffiia
Ft. Portland bentonite
Ft.-
Ft.-
Diameter Slot Size
Melhod
SLURRY
Ft._19_in, .o1o 6.
Ft. in. - in.
Ft. in. - in.
Material
PVC
Size Material
Formation Description
TAN SAND
TAN/BROWN SANDY CLAY
rrorn-o n-roj'o-
Frorn- To-
Frorn- T
8. SCREEN: Depth
rron_lq-ro 139-
Frcn- To-
Fran- To-
9. SAND'GRAVELPACK:
DePth
Frorn l!-lo-l!.0- Ft. 20-40 FINE SlLlcA SAND
Frorn-To- Ft.-
Frun-To- Ft.-
10. DRILLING LOG
From To
0.0 5.O
5.0 '13.0
11. REMARKS:
BENTONITE SEAL FROM 1.0 TO 2.0 FEET
DANNY SUMMERS
PRINTED NAME OF PERSON CONSTRUCTING THE WELL
I DO HEREBY CERTIFY THAT THIS CONSTRUCT€D IN ACCOROANCE WITH
.RDS, ANB TIIAT A COPY OF THIS
CERTIFIED WELL GONTRACTOR
Submit the original to the Division of Water Quality within 30 days. Attn: Information Mgt.,
1617 lMail service center - Raleigh, Nc 27699-16't 7 Phone No. (9{ 9) 733-701s ext s6g.Form GW-1b
Rev.7/05

Limited Site Assessment Report – Phase I – 2/16/2010 Incident No. 16143 Former Agrotec Incorporated Pendleton, Northampton County, North Carolina
Appendix E

Soil Analytical Results Chain of Custody Records
Cooler Receipt Forms Laboratory Certificates of Analysis
Quality Control Certificates
Groundwater Analytical Results Chain of Custody Records
Cooler Receipt Forms Laboratory Certificates of Analysis
Quality Control Certificates

October 13, 2009
LIMS USE: FR - LINDA BLALOCK
LIMS OBJECT ID: 9253894
9253894
Project:
Pace Project No.:
RE:
Ms. Linda BlalockNCDENR - UST Section1637 Mail Service CenterRaleigh, NC 276991637
16143 Agrotec
Dear Ms. Blalock:
Enclosed are the analytical results for sample(s) received by the laboratory on September 25, 2009.
The results relate only to the samples included in this report. Results reported herein conform to themost current NELAC standards, where applicable, unless otherwise narrated in the body of the
report.
Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and
Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All
Microbiological analyses were performed at the laboratory where the samples were received.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Renee Spencer
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 22
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
CERTIFICATIONS
Pace Project No.:
Project:
9253894
16143 Agrotec
Charlotte Certification IDsWest Virginia Certification #: 357Virginia Certification #: 00213Tennessee Certification #: 04010South Carolina Drinking Water Cert. #: 990060003South Carolina Certification #: 990060001Pennsylvania Certification #: 68-00784Connecticut Certification #: PH-0104
North Carolina Field Services Certification #: 5342North Carolina Drinking Water Certification #: 37706New Jersey Certification #: NC012Louisiana/LELAP Certification #: 04034Kentucky UST Certification #: 84Florida/NELAP Certification #: E87627North Carolina Wastewater Certification #: 12
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 22
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
9253894
16143 Agrotec
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
9253894001 MW-1 5ft.ASTM D2974-87 1 PASI-CCLW
EPA 8260 71 PASI-CDLK
EPA 8270 70 PASI-CCMJ
MADEP EPH 7 PASI-CJAC
MADEP VPH 5 PASI-CDHW
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 22
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9253894
16143 Agrotec
Sample:MW-1 5ft.Lab ID:9253894001 Collected:09/24/09 14:00 Received:09/25/09 13:33 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
MADEP EPH NC Soil Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)ND mg/kg 1 09/30/09 17:5309/29/09 09:3012.0
Aliphatic (C19-C36)ND mg/kg 1 09/30/09 17:5309/29/09 09:3012.0
Aromatic (C11-C22)ND mg/kg 1 09/30/09 17:5309/29/09 09:3012.0
Nonatriacontane (S)70 %1 09/30/09 17:53 7194-86-709/29/09 09:3040-140
o-Terphenyl (S)65 %1 09/30/09 17:53 84-15-109/29/09 09:3040-140
2-Fluorobiphenyl (S)64 %1 09/30/09 17:53 321-60-809/29/09 09:3040-140
2-Bromonaphthalene (S)70 %1 09/30/09 17:53 580-13-209/29/09 09:3040-140
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)ND mg/kg 1 09/30/09 05:2609/29/09 15:129.3
Aliphatic (C09-C12)ND mg/kg 1 09/30/09 05:2609/29/09 15:129.3
Aromatic (C09-C10)ND mg/kg 1 09/30/09 05:2609/29/09 15:129.3
2,5-Dibromotoluene (PID)(S)92 %1 09/30/09 05:2609/29/09 15:1270-130
2,5-Dibromotoluene (FID)(S)124 %1 09/30/09 05:2609/29/09 15:1270-130
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene ND ug/kg 1 10/10/09 18:31 83-32-909/29/09 14:00395
Acenaphthylene ND ug/kg 1 10/10/09 18:31 208-96-809/29/09 14:00395
Aniline ND ug/kg 1 10/10/09 18:31 62-53-309/29/09 14:00395
Anthracene ND ug/kg 1 10/10/09 18:31 120-12-709/29/09 14:00395
Benzo(a)anthracene ND ug/kg 1 10/10/09 18:31 56-55-309/29/09 14:00395
Benzo(a)pyrene ND ug/kg 1 10/10/09 18:31 50-32-809/29/09 14:00395
Benzo(b)fluoranthene ND ug/kg 1 10/10/09 18:31 205-99-209/29/09 14:00395
Benzo(g,h,i)perylene ND ug/kg 1 10/10/09 18:31 191-24-209/29/09 14:00395
Benzo(k)fluoranthene ND ug/kg 1 10/10/09 18:31 207-08-909/29/09 14:00395
Benzoic Acid ND ug/kg 1 10/10/09 18:31 65-85-009/29/09 14:001970
Benzyl alcohol ND ug/kg 1 10/10/09 18:31 100-51-609/29/09 14:00790
4-Bromophenylphenyl ether ND ug/kg 1 10/10/09 18:31 101-55-309/29/09 14:00395
Butylbenzylphthalate ND ug/kg 1 10/10/09 18:31 85-68-709/29/09 14:00395
4-Chloro-3-methylphenol ND ug/kg 1 10/10/09 18:31 59-50-709/29/09 14:00790
4-Chloroaniline ND ug/kg 1 10/10/09 18:31 106-47-809/29/09 14:001970
bis(2-Chloroethoxy)methane ND ug/kg 1 10/10/09 18:31 111-91-109/29/09 14:00395
bis(2-Chloroethyl) ether ND ug/kg 1 10/10/09 18:31 111-44-409/29/09 14:00395
2-Chloronaphthalene ND ug/kg 1 10/10/09 18:31 91-58-709/29/09 14:00395
2-Chlorophenol ND ug/kg 1 10/10/09 18:31 95-57-809/29/09 14:00395
4-Chlorophenylphenyl ether ND ug/kg 1 10/10/09 18:31 7005-72-309/29/09 14:00395
Chrysene ND ug/kg 1 10/10/09 18:31 218-01-909/29/09 14:00395
Dibenz(a,h)anthracene ND ug/kg 1 10/10/09 18:31 53-70-309/29/09 14:00395
Dibenzofuran ND ug/kg 1 10/10/09 18:31 132-64-909/29/09 14:00395
1,2-Dichlorobenzene ND ug/kg 1 10/10/09 18:31 95-50-109/29/09 14:00395
1,3-Dichlorobenzene ND ug/kg 1 10/10/09 18:31 541-73-109/29/09 14:00395
1,4-Dichlorobenzene ND ug/kg 1 10/10/09 18:31 106-46-709/29/09 14:00395
3,3'-Dichlorobenzidine ND ug/kg 1 10/10/09 18:31 91-94-109/29/09 14:001970
2,4-Dichlorophenol ND ug/kg 1 10/10/09 18:31 120-83-209/29/09 14:00395
Diethylphthalate ND ug/kg 1 10/10/09 18:31 84-66-209/29/09 14:00395
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/13/2009 05:21 PM Page 4 of 22
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9253894
16143 Agrotec
Sample:MW-1 5ft.Lab ID:9253894001 Collected:09/24/09 14:00 Received:09/25/09 13:33 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
2,4-Dimethylphenol ND ug/kg 1 10/10/09 18:31 105-67-909/29/09 14:00395
Dimethylphthalate ND ug/kg 1 10/10/09 18:31 131-11-309/29/09 14:00395
Di-n-butylphthalate ND ug/kg 1 10/10/09 18:31 84-74-209/29/09 14:00395
4,6-Dinitro-2-methylphenol ND ug/kg 1 10/10/09 18:31 534-52-109/29/09 14:00790
2,4-Dinitrophenol ND ug/kg 1 10/10/09 18:31 51-28-509/29/09 14:001970
2,4-Dinitrotoluene ND ug/kg 1 10/10/09 18:31 121-14-209/29/09 14:00395
2,6-Dinitrotoluene ND ug/kg 1 10/10/09 18:31 606-20-209/29/09 14:00395
Di-n-octylphthalate ND ug/kg 1 10/10/09 18:31 117-84-009/29/09 14:00395
bis(2-Ethylhexyl)phthalate ND ug/kg 1 10/10/09 18:31 117-81-709/29/09 14:00395
Fluoranthene ND ug/kg 1 10/10/09 18:31 206-44-009/29/09 14:00395
Fluorene ND ug/kg 1 10/10/09 18:31 86-73-709/29/09 14:00395
Hexachloro-1,3-butadiene ND ug/kg 1 10/10/09 18:31 87-68-309/29/09 14:00395
Hexachlorobenzene ND ug/kg 1 10/10/09 18:31 118-74-109/29/09 14:00395
Hexachlorocyclopentadiene ND ug/kg 1 10/10/09 18:31 77-47-409/29/09 14:00395
Hexachloroethane ND ug/kg 1 10/10/09 18:31 67-72-109/29/09 14:00395
Indeno(1,2,3-cd)pyrene ND ug/kg 1 10/10/09 18:31 193-39-509/29/09 14:00395
Isophorone ND ug/kg 1 10/10/09 18:31 78-59-109/29/09 14:00395
1-Methylnaphthalene ND ug/kg 1 10/10/09 18:31 90-12-009/29/09 14:00395
2-Methylnaphthalene ND ug/kg 1 10/10/09 18:31 91-57-609/29/09 14:00395
2-Methylphenol(o-Cresol)ND ug/kg 1 10/10/09 18:31 95-48-709/29/09 14:00395
3&4-Methylphenol(m&p Cresol)ND ug/kg 1 10/10/09 18:3109/29/09 14:00395
Naphthalene ND ug/kg 1 10/10/09 18:31 91-20-309/29/09 14:00395
2-Nitroaniline ND ug/kg 1 10/10/09 18:31 88-74-409/29/09 14:001970
3-Nitroaniline ND ug/kg 1 10/10/09 18:31 99-09-209/29/09 14:001970
4-Nitroaniline ND ug/kg 1 10/10/09 18:31 100-01-609/29/09 14:00790
Nitrobenzene ND ug/kg 1 10/10/09 18:31 98-95-309/29/09 14:00395
2-Nitrophenol ND ug/kg 1 10/10/09 18:31 88-75-509/29/09 14:00395
4-Nitrophenol ND ug/kg 1 10/10/09 18:31 100-02-709/29/09 14:001970
Pentachlorophenol ND ug/kg 1 10/10/09 18:31 87-86-509/29/09 14:001970
Phenanthrene ND ug/kg 1 10/10/09 18:31 85-01-809/29/09 14:00395
Phenol ND ug/kg 1 10/10/09 18:31 108-95-209/29/09 14:00395
Pyrene ND ug/kg 1 10/10/09 18:31 129-00-009/29/09 14:00395
1,2,4-Trichlorobenzene ND ug/kg 1 10/10/09 18:31 120-82-109/29/09 14:00395
2,4,5-Trichlorophenol ND ug/kg 1 10/10/09 18:31 95-95-409/29/09 14:00395
2,4,6-Trichlorophenol ND ug/kg 1 10/10/09 18:31 88-06-209/29/09 14:00395
Nitrobenzene-d5 (S)79 %1 10/10/09 18:31 4165-60-009/29/09 14:0030-150
2-Fluorobiphenyl (S)57 %1 10/10/09 18:31 321-60-809/29/09 14:0046-120
Terphenyl-d14 (S)45 %1 10/10/09 18:31 1718-51-009/29/09 14:0038-108
Phenol-d6 (S)71 %1 10/10/09 18:31 13127-88-309/29/09 14:0035-120
2-Fluorophenol (S)56 %1 10/10/09 18:31 367-12-409/29/09 14:0024-120
2,4,6-Tribromophenol (S)80 %1 10/10/09 18:31 118-79-609/29/09 14:0044-136
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone ND ug/kg 1 09/26/09 20:13 67-64-196.2
Benzene ND ug/kg 1 09/26/09 20:13 71-43-24.8
Bromobenzene ND ug/kg 1 09/26/09 20:13 108-86-14.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/13/2009 05:21 PM Page 5 of 22
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9253894
16143 Agrotec
Sample:MW-1 5ft.Lab ID:9253894001 Collected:09/24/09 14:00 Received:09/25/09 13:33 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Bromochloromethane ND ug/kg 1 09/26/09 20:13 74-97-54.8
Bromodichloromethane ND ug/kg 1 09/26/09 20:13 75-27-44.8
Bromoform ND ug/kg 1 09/26/09 20:13 75-25-24.8
Bromomethane ND ug/kg 1 09/26/09 20:13 74-83-99.6
2-Butanone (MEK)ND ug/kg 1 09/26/09 20:13 78-93-396.2
n-Butylbenzene ND ug/kg 1 09/26/09 20:13 104-51-84.8
sec-Butylbenzene ND ug/kg 1 09/26/09 20:13 135-98-84.8
tert-Butylbenzene ND ug/kg 1 09/26/09 20:13 98-06-64.8
Carbon tetrachloride ND ug/kg 1 09/26/09 20:13 56-23-54.8
Chlorobenzene ND ug/kg 1 09/26/09 20:13 108-90-74.8
Chloroethane ND ug/kg 1 09/26/09 20:13 75-00-39.6
Chloroform ND ug/kg 1 09/26/09 20:13 67-66-34.8
Chloromethane ND ug/kg 1 09/26/09 20:13 74-87-39.6
2-Chlorotoluene ND ug/kg 1 09/26/09 20:13 95-49-84.8
4-Chlorotoluene ND ug/kg 1 09/26/09 20:13 106-43-44.8
1,2-Dibromo-3-chloropropane ND ug/kg 1 09/26/09 20:13 96-12-84.8
Dibromochloromethane ND ug/kg 1 09/26/09 20:13 124-48-14.8
1,2-Dibromoethane (EDB)ND ug/kg 1 09/26/09 20:13 106-93-44.8
Dibromomethane ND ug/kg 1 09/26/09 20:13 74-95-34.8
1,2-Dichlorobenzene ND ug/kg 1 09/26/09 20:13 95-50-14.8
1,3-Dichlorobenzene ND ug/kg 1 09/26/09 20:13 541-73-14.8
1,4-Dichlorobenzene ND ug/kg 1 09/26/09 20:13 106-46-74.8
Dichlorodifluoromethane ND ug/kg 1 09/26/09 20:13 75-71-89.6
1,1-Dichloroethane ND ug/kg 1 09/26/09 20:13 75-34-34.8
1,2-Dichloroethane ND ug/kg 1 09/26/09 20:13 107-06-24.8
1,1-Dichloroethene ND ug/kg 1 09/26/09 20:13 75-35-44.8
cis-1,2-Dichloroethene ND ug/kg 1 09/26/09 20:13 156-59-24.8
trans-1,2-Dichloroethene ND ug/kg 1 09/26/09 20:13 156-60-54.8
1,2-Dichloropropane ND ug/kg 1 09/26/09 20:13 78-87-54.8
1,3-Dichloropropane ND ug/kg 1 09/26/09 20:13 142-28-94.8
2,2-Dichloropropane ND ug/kg 1 09/26/09 20:13 594-20-74.8
1,1-Dichloropropene ND ug/kg 1 09/26/09 20:13 563-58-64.8
cis-1,3-Dichloropropene ND ug/kg 1 09/26/09 20:13 10061-01-54.8
trans-1,3-Dichloropropene ND ug/kg 1 09/26/09 20:13 10061-02-64.8
Diisopropyl ether ND ug/kg 1 09/26/09 20:13 108-20-34.8
Ethylbenzene ND ug/kg 1 09/26/09 20:13 100-41-44.8
Hexachloro-1,3-butadiene ND ug/kg 1 09/26/09 20:13 87-68-34.8
2-Hexanone ND ug/kg 1 09/26/09 20:13 591-78-648.1
Isopropylbenzene (Cumene)ND ug/kg 1 09/26/09 20:13 98-82-84.8
p-Isopropyltoluene ND ug/kg 1 09/26/09 20:13 99-87-64.8
Methylene Chloride ND ug/kg 1 09/26/09 20:13 75-09-219.2
4-Methyl-2-pentanone (MIBK)ND ug/kg 1 09/26/09 20:13 108-10-148.1
Methyl-tert-butyl ether ND ug/kg 1 09/26/09 20:13 1634-04-44.8
Naphthalene ND ug/kg 1 09/26/09 20:13 91-20-34.8
n-Propylbenzene ND ug/kg 1 09/26/09 20:13 103-65-14.8
Styrene ND ug/kg 1 09/26/09 20:13 100-42-54.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/13/2009 05:21 PM Page 6 of 22
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9253894
16143 Agrotec
Sample:MW-1 5ft.Lab ID:9253894001 Collected:09/24/09 14:00 Received:09/25/09 13:33 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
1,1,1,2-Tetrachloroethane ND ug/kg 1 09/26/09 20:13 630-20-64.8
1,1,2,2-Tetrachloroethane ND ug/kg 1 09/26/09 20:13 79-34-54.8
Tetrachloroethene ND ug/kg 1 09/26/09 20:13 127-18-44.8
Toluene ND ug/kg 1 09/26/09 20:13 108-88-34.8
1,2,3-Trichlorobenzene ND ug/kg 1 09/26/09 20:13 87-61-64.8
1,2,4-Trichlorobenzene ND ug/kg 1 09/26/09 20:13 120-82-14.8
1,1,1-Trichloroethane ND ug/kg 1 09/26/09 20:13 71-55-64.8
1,1,2-Trichloroethane ND ug/kg 1 09/26/09 20:13 79-00-54.8
Trichloroethene ND ug/kg 1 09/26/09 20:13 79-01-64.8
Trichlorofluoromethane ND ug/kg 1 09/26/09 20:13 75-69-44.8
1,2,3-Trichloropropane ND ug/kg 1 09/26/09 20:13 96-18-44.8
1,2,4-Trimethylbenzene ND ug/kg 1 09/26/09 20:13 95-63-64.8
1,3,5-Trimethylbenzene ND ug/kg 1 09/26/09 20:13 108-67-84.8
Vinyl acetate ND ug/kg 1 09/26/09 20:13 108-05-448.1
Vinyl chloride ND ug/kg 1 09/26/09 20:13 75-01-49.6
Xylene (Total)ND ug/kg 1 09/26/09 20:13 1330-20-79.6
m&p-Xylene ND ug/kg 1 09/26/09 20:13 1330-20-79.6
o-Xylene ND ug/kg 1 09/26/09 20:13 95-47-64.8
Dibromofluoromethane (S)103 %1 09/26/09 20:13 1868-53-779-116
Toluene-d8 (S)97 %1 09/26/09 20:13 2037-26-588-110
4-Bromofluorobenzene (S)97 %1 09/26/09 20:13 460-00-474-115
1,2-Dichloroethane-d4 (S)105 %1 09/26/09 20:13 17060-07-069-121
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 16.4 %1 09/30/09 12:340.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/13/2009 05:21 PM Page 7 of 22
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9253894
16143 Agrotec
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/8142
MADEP EPH
MADEP EPH
MADEP EPH NC Soil
Associated Lab Samples:9253894001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:342705
Associated Lab Samples:9253894001
Matrix:Solid
Analyzed
Aliphatic (C09-C18)mg/kg ND 10.0 09/30/09 15:41
Aliphatic (C19-C36)mg/kg ND 10.0 09/30/09 15:41
Aromatic (C11-C22)mg/kg ND 10.0 09/30/09 15:41
2-Bromonaphthalene (S)%81 40-140 09/30/09 15:41
2-Fluorobiphenyl (S)%79 40-140 09/30/09 15:41
Nonatriacontane (S)%98 40-140 09/30/09 15:41
o-Terphenyl (S)%69 40-140 09/30/09 15:41
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
342706LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
342707
Aliphatic (C09-C18)mg/kg ND10 67 40-14073ND 50
Aliphatic (C19-C36)mg/kg 11.813.3 88 40-1409512.7 7 50
Aromatic (C11-C22)mg/kg 25.628.3 90 40-14010429.4 14 50
2-Bromonaphthalene (S)%85 40-14086
2-Fluorobiphenyl (S)%83 40-14086
Nonatriacontane (S)%67 40-14076
o-Terphenyl (S)%80 40-14091
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/13/2009 05:21 PM Page 8 of 22
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9253894
16143 Agrotec
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GCV/3521
MADEP VPH
MADEP VPH
VPH NC Soil
Associated Lab Samples:9253894001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:342451
Associated Lab Samples:9253894001
Matrix:Solid
Analyzed
Aliphatic (C05-C08)mg/kg ND 10.0 09/30/09 00:15
Aliphatic (C09-C12)mg/kg ND 10.0 09/30/09 00:15
Aromatic (C09-C10)mg/kg ND 10.0 09/30/09 00:15
2,5-Dibromotoluene (FID)(S)%112 70-130 09/30/09 00:15
2,5-Dibromotoluene (PID)(S)%88 70-130 09/30/09 00:15
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
342452LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
342453
Aliphatic (C05-C08)mg/kg 15.715 104 70-13010215.3 2 25
Aliphatic (C09-C12)mg/kg 13.415 89 30-1309314.0 5 25
Aromatic (C09-C10)mg/kg ND5 83 70-13083ND 25
2,5-Dibromotoluene (FID)(S)%120 70-130116
2,5-Dibromotoluene (PID)(S)%98 70-13097
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/13/2009 05:21 PM Page 9 of 22
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9253894
16143 Agrotec
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/8149
EPA 3546
EPA 8270
8270 Solid MSSV Microwave
Associated Lab Samples:9253894001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:342915
Associated Lab Samples:9253894001
Matrix:Solid
Analyzed
1,2,4-Trichlorobenzene ug/kg ND 330 10/10/09 17:39
1,2-Dichlorobenzene ug/kg ND 330 10/10/09 17:39
1,3-Dichlorobenzene ug/kg ND 330 10/10/09 17:39
1,4-Dichlorobenzene ug/kg ND 330 10/10/09 17:39
1-Methylnaphthalene ug/kg ND 330 10/10/09 17:39
2,4,5-Trichlorophenol ug/kg ND 330 10/10/09 17:39
2,4,6-Trichlorophenol ug/kg ND 330 10/10/09 17:39
2,4-Dichlorophenol ug/kg ND 330 10/10/09 17:39
2,4-Dimethylphenol ug/kg ND 330 10/10/09 17:39
2,4-Dinitrophenol ug/kg ND 1650 10/10/09 17:39
2,4-Dinitrotoluene ug/kg ND 330 10/10/09 17:39
2,6-Dinitrotoluene ug/kg ND 330 10/10/09 17:39
2-Chloronaphthalene ug/kg ND 330 10/10/09 17:39
2-Chlorophenol ug/kg ND 330 10/10/09 17:39
2-Methylnaphthalene ug/kg ND 330 10/10/09 17:39
2-Methylphenol(o-Cresol)ug/kg ND 330 10/10/09 17:39
2-Nitroaniline ug/kg ND 1650 10/10/09 17:39
2-Nitrophenol ug/kg ND 330 10/10/09 17:39
3&4-Methylphenol(m&p Cresol)ug/kg ND 330 10/10/09 17:39
3,3'-Dichlorobenzidine ug/kg ND 1650 10/10/09 17:39
3-Nitroaniline ug/kg ND 1650 10/10/09 17:39
4,6-Dinitro-2-methylphenol ug/kg ND 660 10/10/09 17:39
4-Bromophenylphenyl ether ug/kg ND 330 10/10/09 17:39
4-Chloro-3-methylphenol ug/kg ND 660 10/10/09 17:39
4-Chloroaniline ug/kg ND 1650 10/10/09 17:39
4-Chlorophenylphenyl ether ug/kg ND 330 10/10/09 17:39
4-Nitroaniline ug/kg ND 660 10/10/09 17:39
4-Nitrophenol ug/kg ND 1650 10/10/09 17:39
Acenaphthene ug/kg ND 330 10/10/09 17:39
Acenaphthylene ug/kg ND 330 10/10/09 17:39
Aniline ug/kg ND 330 10/10/09 17:39
Anthracene ug/kg ND 330 10/10/09 17:39
Benzo(a)anthracene ug/kg ND 330 10/10/09 17:39
Benzo(a)pyrene ug/kg ND 330 10/10/09 17:39
Benzo(b)fluoranthene ug/kg ND 330 10/10/09 17:39
Benzo(g,h,i)perylene ug/kg ND 330 10/10/09 17:39
Benzo(k)fluoranthene ug/kg ND 330 10/10/09 17:39
Benzoic Acid ug/kg ND 1650 10/10/09 17:39
Benzyl alcohol ug/kg ND 660 10/10/09 17:39
bis(2-Chloroethoxy)methane ug/kg ND 330 10/10/09 17:39
bis(2-Chloroethyl) ether ug/kg ND 330 10/10/09 17:39
bis(2-Ethylhexyl)phthalate ug/kg ND 330 10/10/09 17:39
Butylbenzylphthalate ug/kg ND 330 10/10/09 17:39
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/13/2009 05:21 PM Page 10 of 22
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9253894
16143 Agrotec
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:342915
Associated Lab Samples:9253894001
Matrix:Solid
Analyzed
Chrysene ug/kg ND 330 10/10/09 17:39
Di-n-butylphthalate ug/kg ND 330 10/10/09 17:39
Di-n-octylphthalate ug/kg ND 330 10/10/09 17:39
Dibenz(a,h)anthracene ug/kg ND 330 10/10/09 17:39
Dibenzofuran ug/kg ND 330 10/10/09 17:39
Diethylphthalate ug/kg ND 330 10/10/09 17:39
Dimethylphthalate ug/kg ND 330 10/10/09 17:39
Fluoranthene ug/kg ND 330 10/10/09 17:39
Fluorene ug/kg ND 330 10/10/09 17:39
Hexachloro-1,3-butadiene ug/kg ND 330 10/10/09 17:39
Hexachlorobenzene ug/kg ND 330 10/10/09 17:39
Hexachlorocyclopentadiene ug/kg ND 330 10/10/09 17:39
Hexachloroethane ug/kg ND 330 10/10/09 17:39
Indeno(1,2,3-cd)pyrene ug/kg ND 330 10/10/09 17:39
Isophorone ug/kg ND 330 10/10/09 17:39
Naphthalene ug/kg ND 330 10/10/09 17:39
Nitrobenzene ug/kg ND 330 10/10/09 17:39
Pentachlorophenol ug/kg ND 1650 10/10/09 17:39
Phenanthrene ug/kg ND 330 10/10/09 17:39
Phenol ug/kg ND 330 10/10/09 17:39
Pyrene ug/kg ND 330 10/10/09 17:39
2,4,6-Tribromophenol (S)%73 44-136 10/10/09 17:39
2-Fluorobiphenyl (S)%78 46-120 10/10/09 17:39
2-Fluorophenol (S)%65 24-120 10/10/09 17:39
Nitrobenzene-d5 (S)%75 30-150 10/10/09 17:39
Phenol-d6 (S)%71 35-120 10/10/09 17:39
Terphenyl-d14 (S)%65 38-108 10/10/09 17:39
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
342916LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/kg 11201670 67 50-150
1,2-Dichlorobenzene ug/kg 10601670 63 50-150
1,3-Dichlorobenzene ug/kg 10501670 63 50-150
1,4-Dichlorobenzene ug/kg 10601670 64 50-150
1-Methylnaphthalene ug/kg 11001670 66 50-150
2,4,5-Trichlorophenol ug/kg 13401670 80 50-150
2,4,6-Trichlorophenol ug/kg 11401670 68 50-150
2,4-Dichlorophenol ug/kg 12401670 74 50-150
2,4-Dimethylphenol ug/kg 11401670 69 50-150
2,4-Dinitrophenol ug/kg 1280J1670 77 20-111
2,4-Dinitrotoluene ug/kg 12701670 76 50-150
2,6-Dinitrotoluene ug/kg 13301670 80 50-150
2-Chloronaphthalene ug/kg 12101670 72 50-150
2-Chlorophenol ug/kg 11201670 67 50-150
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/13/2009 05:21 PM Page 11 of 22
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9253894
16143 Agrotec
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
342916LABORATORY CONTROL SAMPLE:
LCSSpike
2-Methylnaphthalene ug/kg 11601670 70 50-150
2-Methylphenol(o-Cresol)ug/kg 11401670 69 50-150
2-Nitroaniline ug/kg 1300J1670 78 50-150
2-Nitrophenol ug/kg 12401670 74 50-150
3&4-Methylphenol(m&p Cresol)ug/kg 9581670 58 50-150
3,3'-Dichlorobenzidine ug/kg 1370J1670 82 50-150
3-Nitroaniline ug/kg 17001670 102 50-150
4,6-Dinitro-2-methylphenol ug/kg 11501670 69 15-136
4-Bromophenylphenyl ether ug/kg 13901670 84 50-150
4-Chloro-3-methylphenol ug/kg 12601670 75 50-150
4-Chloroaniline ug/kg 18601670 111 50-150
4-Chlorophenylphenyl ether ug/kg 12701670 76 50-150
4-Nitroaniline ug/kg 14301670 86 50-150
4-Nitrophenol ug/kg 2040 L0167012233-105
Acenaphthene ug/kg 12501670 75 50-150
Acenaphthylene ug/kg 12001670 72 50-150
Aniline ug/kg 12201670 73 50-150
Anthracene ug/kg 12201670 73 50-150
Benzo(a)anthracene ug/kg 12101670 73 50-150
Benzo(a)pyrene ug/kg 12401670 74 50-150
Benzo(b)fluoranthene ug/kg 12801670 77 50-150
Benzo(g,h,i)perylene ug/kg 11801670 71 24-117
Benzo(k)fluoranthene ug/kg 12801670 77 50-150
Benzoic Acid ug/kg 474J1670 28 15-104
Benzyl alcohol ug/kg 12301670 74 50-150
bis(2-Chloroethoxy)methane ug/kg 14201670 85 50-150
bis(2-Chloroethyl) ether ug/kg 12801670 77 50-150
bis(2-Ethylhexyl)phthalate ug/kg 12301670 74 50-150
Butylbenzylphthalate ug/kg 12401670 74 50-150
Chrysene ug/kg 14801670 89 50-150
Di-n-butylphthalate ug/kg 11501670 69 50-150
Di-n-octylphthalate ug/kg 12601670 75 50-150
Dibenz(a,h)anthracene ug/kg 11701670 70 17-128
Dibenzofuran ug/kg 12001670 72 50-150
Diethylphthalate ug/kg 12401670 74 50-150
Dimethylphthalate ug/kg 13001670 78 50-150
Fluoranthene ug/kg 12301670 74 50-150
Fluorene ug/kg 12201670 73 50-150
Hexachloro-1,3-butadiene ug/kg 12001670 72 50-150
Hexachlorobenzene ug/kg 11801670 71 50-150
Hexachlorocyclopentadiene ug/kg 14001670 84 15-114
Hexachloroethane ug/kg 10601670 64 50-150
Indeno(1,2,3-cd)pyrene ug/kg 8521670 51 19-128
Isophorone ug/kg 12201670 73 50-150
Naphthalene ug/kg 11701670 70 50-150
Nitrobenzene ug/kg 12201670 73 50-150
Pentachlorophenol ug/kg 1520J1670 91 15-130
Phenanthrene ug/kg 12501670 75 50-150
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/13/2009 05:21 PM Page 12 of 22
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9253894
16143 Agrotec
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
342916LABORATORY CONTROL SAMPLE:
LCSSpike
Phenol ug/kg 11701670 70 42-120
Pyrene ug/kg 12001670 72 50-150
2,4,6-Tribromophenol (S)%68 44-136
2-Fluorobiphenyl (S)%69 46-120
2-Fluorophenol (S)%60 24-120
Nitrobenzene-d5 (S)%68 30-150
Phenol-d6 (S)%64 35-120
Terphenyl-d14 (S)%69 38-108
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
342917MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9253867006
342918
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1-Methylnaphthalene ug/kg M0,R122003950-15048 212200ND8581060
2-Methylnaphthalene ug/kg M0,R122003950-15049 222200ND8671080
Acenaphthene ug/kg M0,R122004250-15054 252200ND9151180
Acenaphthylene ug/kg M0,R122004150-15052 242200ND9011140
Anthracene ug/kg M0,R122004350-15056 262200ND9521230
Benzo(a)anthracene ug/kg M0,R122003950-15055 352200ND8511210
Benzo(a)pyrene ug/kg M0,R122003550-15049 302200ND8411130
Benzo(b)fluoranthene ug/kg M0,R122004050-15059 382200ND9101340
Benzo(g,h,i)perylene ug/kg M0,R122003650-15045 222200ND787984
Benzo(k)fluoranthene ug/kg M0,R122003450-15045 262200ND7741010
Chrysene ug/kg M0,R122004150-15057 342200ND8951260
Dibenz(a,h)anthracene ug/kg M0,R122003950-15048 212200ND8581060
Fluoranthene ug/kg M0,R122003550-15053 37220074.1J 875 1270
Fluorene ug/kg M0,R122003850-15051 292200ND8381120
Indeno(1,2,3-cd)pyrene ug/kg M0,R122003750-15047 232200ND8191030
Naphthalene ug/kg M0,R122003950-15048 202200ND8631050
Phenanthrene ug/kg M0,R122004550-15064 33220059.7J 1070 1480
Pyrene ug/kg M0,R122004350-15066 392200ND10201510
2-Fluorobiphenyl (S)%S04046-12052
Nitrobenzene-d5 (S)%35 30-15046
Terphenyl-d14 (S)%38 38-10858
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/13/2009 05:21 PM Page 13 of 22
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9253894
16143 Agrotec
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/8437
EPA 8260
EPA 8260
8260 MSV 5035A Volatile Organics
Associated Lab Samples:9253894001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:342227
Associated Lab Samples:9253894001
Matrix:Solid
Analyzed
1,1,1,2-Tetrachloroethane ug/kg ND 5.0 09/26/09 12:53
1,1,1-Trichloroethane ug/kg ND 5.0 09/26/09 12:53
1,1,2,2-Tetrachloroethane ug/kg ND 5.0 09/26/09 12:53
1,1,2-Trichloroethane ug/kg ND 5.0 09/26/09 12:53
1,1-Dichloroethane ug/kg ND 5.0 09/26/09 12:53
1,1-Dichloroethene ug/kg ND 5.0 09/26/09 12:53
1,1-Dichloropropene ug/kg ND 5.0 09/26/09 12:53
1,2,3-Trichlorobenzene ug/kg ND 5.0 09/26/09 12:53
1,2,3-Trichloropropane ug/kg ND 5.0 09/26/09 12:53
1,2,4-Trichlorobenzene ug/kg ND 5.0 09/26/09 12:53
1,2,4-Trimethylbenzene ug/kg ND 5.0 09/26/09 12:53
1,2-Dibromo-3-chloropropane ug/kg ND 5.0 09/26/09 12:53
1,2-Dibromoethane (EDB)ug/kg ND 5.0 09/26/09 12:53
1,2-Dichlorobenzene ug/kg ND 5.0 09/26/09 12:53
1,2-Dichloroethane ug/kg ND 5.0 09/26/09 12:53
1,2-Dichloropropane ug/kg ND 5.0 09/26/09 12:53
1,3,5-Trimethylbenzene ug/kg ND 5.0 09/26/09 12:53
1,3-Dichlorobenzene ug/kg ND 5.0 09/26/09 12:53
1,3-Dichloropropane ug/kg ND 5.0 09/26/09 12:53
1,4-Dichlorobenzene ug/kg ND 5.0 09/26/09 12:53
2,2-Dichloropropane ug/kg ND 5.0 09/26/09 12:53
2-Butanone (MEK)ug/kg ND 100 09/26/09 12:53
2-Chlorotoluene ug/kg ND 5.0 09/26/09 12:53
2-Hexanone ug/kg ND 50.0 09/26/09 12:53
4-Chlorotoluene ug/kg ND 5.0 09/26/09 12:53
4-Methyl-2-pentanone (MIBK)ug/kg ND 50.0 09/26/09 12:53
Acetone ug/kg ND 100 09/26/09 12:53
Benzene ug/kg ND 5.0 09/26/09 12:53
Bromobenzene ug/kg ND 5.0 09/26/09 12:53
Bromochloromethane ug/kg ND 5.0 09/26/09 12:53
Bromodichloromethane ug/kg ND 5.0 09/26/09 12:53
Bromoform ug/kg ND 5.0 09/26/09 12:53
Bromomethane ug/kg ND 10.0 09/26/09 12:53
Carbon tetrachloride ug/kg ND 5.0 09/26/09 12:53
Chlorobenzene ug/kg ND 5.0 09/26/09 12:53
Chloroethane ug/kg ND 10.0 09/26/09 12:53
Chloroform ug/kg ND 5.0 09/26/09 12:53
Chloromethane ug/kg ND 10.0 09/26/09 12:53
cis-1,2-Dichloroethene ug/kg ND 5.0 09/26/09 12:53
cis-1,3-Dichloropropene ug/kg ND 5.0 09/26/09 12:53
Dibromochloromethane ug/kg ND 5.0 09/26/09 12:53
Dibromomethane ug/kg ND 5.0 09/26/09 12:53
Dichlorodifluoromethane ug/kg ND 10.0 09/26/09 12:53
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/13/2009 05:21 PM Page 14 of 22
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9253894
16143 Agrotec
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:342227
Associated Lab Samples:9253894001
Matrix:Solid
Analyzed
Diisopropyl ether ug/kg ND 5.0 09/26/09 12:53
Ethylbenzene ug/kg ND 5.0 09/26/09 12:53
Hexachloro-1,3-butadiene ug/kg ND 5.0 09/26/09 12:53
Isopropylbenzene (Cumene)ug/kg ND 5.0 09/26/09 12:53
m&p-Xylene ug/kg ND 10.0 09/26/09 12:53
Methyl-tert-butyl ether ug/kg ND 5.0 09/26/09 12:53
Methylene Chloride ug/kg ND 20.0 09/26/09 12:53
n-Butylbenzene ug/kg ND 5.0 09/26/09 12:53
n-Propylbenzene ug/kg ND 5.0 09/26/09 12:53
Naphthalene ug/kg ND 5.0 09/26/09 12:53
o-Xylene ug/kg ND 5.0 09/26/09 12:53
p-Isopropyltoluene ug/kg ND 5.0 09/26/09 12:53
sec-Butylbenzene ug/kg ND 5.0 09/26/09 12:53
Styrene ug/kg ND 5.0 09/26/09 12:53
tert-Butylbenzene ug/kg ND 5.0 09/26/09 12:53
Tetrachloroethene ug/kg ND 5.0 09/26/09 12:53
Toluene ug/kg ND 5.0 09/26/09 12:53
trans-1,2-Dichloroethene ug/kg ND 5.0 09/26/09 12:53
trans-1,3-Dichloropropene ug/kg ND 5.0 09/26/09 12:53
Trichloroethene ug/kg ND 5.0 09/26/09 12:53
Trichlorofluoromethane ug/kg ND 5.0 09/26/09 12:53
Vinyl acetate ug/kg ND 50.0 09/26/09 12:53
Vinyl chloride ug/kg ND 10.0 09/26/09 12:53
Xylene (Total)ug/kg ND 10.0 09/26/09 12:53
1,2-Dichloroethane-d4 (S)%100 69-121 09/26/09 12:53
4-Bromofluorobenzene (S)%95 74-115 09/26/09 12:53
Dibromofluoromethane (S)%100 79-116 09/26/09 12:53
Toluene-d8 (S)%99 88-110 09/26/09 12:53
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
342228LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/kg 54.050 108 75-137
1,1,1-Trichloroethane ug/kg 46.950 94 70-140
1,1,2,2-Tetrachloroethane ug/kg 51.550 103 74-133
1,1,2-Trichloroethane ug/kg 51.850 104 79-129
1,1-Dichloroethane ug/kg 47.650 95 72-139
1,1-Dichloroethene ug/kg 51.350 103 69-154
1,1-Dichloropropene ug/kg 50.450 101 74-138
1,2,3-Trichlorobenzene ug/kg 52.250 104 71-150
1,2,3-Trichloropropane ug/kg 53.750 107 74-135
1,2,4-Trichlorobenzene ug/kg 53.850 108 68-150
1,2,4-Trimethylbenzene ug/kg 56.550 113 70-130
1,2-Dibromo-3-chloropropane ug/kg 51.650 103 65-146
1,2-Dibromoethane (EDB)ug/kg 53.850 108 77-136
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/13/2009 05:21 PM Page 15 of 22
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9253894
16143 Agrotec
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
342228LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichlorobenzene ug/kg 54.150 108 75-141
1,2-Dichloroethane ug/kg 49.250 98 74-134
1,2-Dichloropropane ug/kg 52.650 105 77-138
1,3,5-Trimethylbenzene ug/kg 54.550 109 65-128
1,3-Dichlorobenzene ug/kg 54.150 108 76-133
1,3-Dichloropropane ug/kg 53.750 107 79-132
1,4-Dichlorobenzene ug/kg 53.450 107 75-137
2,2-Dichloropropane ug/kg 49.950 100 73-137
2-Butanone (MEK)ug/kg 103100 103 61-138
2-Chlorotoluene ug/kg 52.350 105 73-138
2-Hexanone ug/kg 106100 106 58-159
4-Chlorotoluene ug/kg 55.650 111 75-136
4-Methyl-2-pentanone (MIBK)ug/kg 101100 101 74-139
Acetone ug/kg 108100 108 58-150
Benzene ug/kg 49.250 98 71-140
Bromobenzene ug/kg 52.750 105 72-144
Bromochloromethane ug/kg 51.550 103 78-133
Bromodichloromethane ug/kg 48.750 97 78-133
Bromoform ug/kg 51.450 103 74-132
Bromomethane ug/kg 38.450 77 63-184
Carbon tetrachloride ug/kg 59.350 119 73-143
Chlorobenzene ug/kg 52.950 106 77-137
Chloroethane ug/kg 51.850 104 68-146
Chloroform ug/kg 48.850 98 75-137
Chloromethane ug/kg 53.050 106 54-143
cis-1,2-Dichloroethene ug/kg 49.850 100 71-143
cis-1,3-Dichloropropene ug/kg 52.050 104 76-133
Dibromochloromethane ug/kg 51.750 103 77-131
Dibromomethane ug/kg 51.350 103 63-184
Dichlorodifluoromethane ug/kg 45.650 91 36-173
Diisopropyl ether ug/kg 48.750 97 68-144
Ethylbenzene ug/kg 52.950 106 69-141
Hexachloro-1,3-butadiene ug/kg 54.650 109 70-152
Isopropylbenzene (Cumene)ug/kg 54.550 109 77-143
m&p-Xylene ug/kg 109100 109 72-138
Methyl-tert-butyl ether ug/kg 47.650 95 2-138
Methylene Chloride ug/kg 51.350 103 69-136
n-Butylbenzene ug/kg 56.250 112 65-128
n-Propylbenzene ug/kg 55.050 110 72-139
Naphthalene ug/kg 51.250 102 61-138
o-Xylene ug/kg 52.850 106 74-137
p-Isopropyltoluene ug/kg 55.450 111 66-128
sec-Butylbenzene ug/kg 53.750 107 72-140
Styrene ug/kg 54.050 108 76-137
tert-Butylbenzene ug/kg 54.150 108 68-141
Tetrachloroethene ug/kg 53.650 107 72-136
Toluene ug/kg 48.950 98 69-139
trans-1,2-Dichloroethene ug/kg 46.950 94 72-144
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/13/2009 05:21 PM Page 16 of 22
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9253894
16143 Agrotec
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
342228LABORATORY CONTROL SAMPLE:
LCSSpike
trans-1,3-Dichloropropene ug/kg 53.950 108 73-135
Trichloroethene ug/kg 52.650 105 75-136
Trichlorofluoromethane ug/kg 52.450 105 69-144
Vinyl acetate ug/kg 126100 126 50-150
Vinyl chloride ug/kg 54.050 108 61-145
Xylene (Total)ug/kg 162150 108 73-138
1,2-Dichloroethane-d4 (S)%98 69-121
4-Bromofluorobenzene (S)%101 74-115
Dibromofluoromethane (S)%100 79-116
Toluene-d8 (S)%97 88-110
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
342249MATRIX SPIKE SAMPLE:
MSSpike
Result
9253894001
1,1-Dichloroethene ug/kg 43.548.8 89 33-158ND
Benzene ug/kg 38.548.8 79 46-143ND
Chlorobenzene ug/kg 38.048.8 78 29-159ND
Toluene ug/kg 38.248.8 78 38-145ND
Trichloroethene ug/kg 39.748.8 81 70-130ND
1,2-Dichloroethane-d4 (S)%105 69-121
4-Bromofluorobenzene (S)%97 74-115
Dibromofluoromethane (S)%103 79-116
Toluene-d8 (S)%101 88-110
Parameter Units
Dup
Result QualifiersRPDResult
9253906001
342248SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/kg NDND
1,1,1-Trichloroethane ug/kg NDND
1,1,2,2-Tetrachloroethane ug/kg NDND
1,1,2-Trichloroethane ug/kg NDND
1,1-Dichloroethane ug/kg NDND
1,1-Dichloroethene ug/kg NDND
1,1-Dichloropropene ug/kg NDND
1,2,3-Trichlorobenzene ug/kg NDND
1,2,3-Trichloropropane ug/kg NDND
1,2,4-Trichlorobenzene ug/kg NDND
1,2,4-Trimethylbenzene ug/kg NDND
1,2-Dibromo-3-chloropropane ug/kg NDND
1,2-Dibromoethane (EDB)ug/kg NDND
1,2-Dichlorobenzene ug/kg NDND
1,2-Dichloroethane ug/kg NDND
1,2-Dichloropropane ug/kg NDND
1,3,5-Trimethylbenzene ug/kg NDND
1,3-Dichlorobenzene ug/kg NDND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/13/2009 05:21 PM Page 17 of 22
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9253894
16143 Agrotec
Parameter Units
Dup
Result QualifiersRPDResult
9253906001
342248SAMPLE DUPLICATE:
1,3-Dichloropropane ug/kg NDND
1,4-Dichlorobenzene ug/kg NDND
2,2-Dichloropropane ug/kg NDND
2-Butanone (MEK)ug/kg NDND
2-Chlorotoluene ug/kg NDND
2-Hexanone ug/kg NDND
4-Chlorotoluene ug/kg NDND
4-Methyl-2-pentanone (MIBK)ug/kg NDND
Acetone ug/kg 14.6JND
Benzene ug/kg NDND
Bromobenzene ug/kg NDND
Bromochloromethane ug/kg NDND
Bromodichloromethane ug/kg NDND
Bromoform ug/kg NDND
Bromomethane ug/kg NDND
Carbon tetrachloride ug/kg NDND
Chlorobenzene ug/kg NDND
Chloroethane ug/kg NDND
Chloroform ug/kg NDND
Chloromethane ug/kg NDND
cis-1,2-Dichloroethene ug/kg NDND
cis-1,3-Dichloropropene ug/kg NDND
Dibromochloromethane ug/kg NDND
Dibromomethane ug/kg NDND
Dichlorodifluoromethane ug/kg NDND
Diisopropyl ether ug/kg NDND
Ethylbenzene ug/kg NDND
Hexachloro-1,3-butadiene ug/kg NDND
Isopropylbenzene (Cumene)ug/kg NDND
m&p-Xylene ug/kg NDND
Methyl-tert-butyl ether ug/kg NDND
Methylene Chloride ug/kg NDND
n-Butylbenzene ug/kg NDND
n-Propylbenzene ug/kg NDND
Naphthalene ug/kg NDND
o-Xylene ug/kg NDND
p-Isopropyltoluene ug/kg NDND
sec-Butylbenzene ug/kg NDND
Styrene ug/kg NDND
tert-Butylbenzene ug/kg NDND
Tetrachloroethene ug/kg NDND
Toluene ug/kg NDND
trans-1,2-Dichloroethene ug/kg NDND
trans-1,3-Dichloropropene ug/kg NDND
Trichloroethene ug/kg NDND
Trichlorofluoromethane ug/kg NDND
Vinyl acetate ug/kg NDND
Vinyl chloride ug/kg NDND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/13/2009 05:21 PM Page 18 of 22
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9253894
16143 Agrotec
Parameter Units
Dup
Result QualifiersRPDResult
9253906001
342248SAMPLE DUPLICATE:
Xylene (Total)ug/kg NDND
1,2-Dichloroethane-d4 (S)%101 8108
4-Bromofluorobenzene (S)%97 097
Dibromofluoromethane (S)%99 6105
Toluene-d8 (S)%102 399
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/13/2009 05:21 PM Page 19 of 22
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9253894
16143 Agrotec
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
PMST/2748
ASTM D2974-87
ASTM D2974-87
Dry Weight/Percent Moisture
Associated Lab Samples:9253894001
Parameter Units
Dup
Result QualifiersRPDResult
9253867006
343286SAMPLE DUPLICATE:
Percent Moisture %22.9 524.1
Parameter Units
Dup
Result QualifiersRPDResult
9253989001
343287SAMPLE DUPLICATE:
Percent Moisture %20.9 922.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/13/2009 05:21 PM Page 20 of 22
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALIFIERS
Pace Project No.:
Project:
9253894
16143 Agrotec
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution ofthe sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes.
U - Indicates the compound was analyzed for, but not detected.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
RPD value was outside control limits.R1
Surrogate recovery outside laboratory control limits.S0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/13/2009 05:21 PM Page 21 of 22
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
9253894
16143 Agrotec
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
9253894001 MSV/8437MW-1 5ft.EPA 8260
9253894001 GCV/3521 GCV/3524MW-1 5ft.MADEP VPH MADEP VPH
9253894001 OEXT/8142 GCSV/6355MW-1 5ft.MADEP EPH MADEP EPH
9253894001 OEXT/8149 MSSV/3131MW-1 5ft.EPA 3546 EPA 8270
9253894001 PMST/2748MW-1 5ft.ASTM D2974-87
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/13/2009 05:21 PM Page 22 of 22
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
December 30, 2009
LIMS USE: FR - LINDA BLALOCK
LIMS OBJECT ID: 9259046
9259046
Project:
Pace Project No.:
RE:
Ms. Linda BlalockNCDENR - UST Section1637 Mail Service CenterRaleigh, NC 276991637
16143 AGROTEC
Dear Ms. Blalock:
Enclosed are the analytical results for sample(s) received by the laboratory on December 08, 2009.
The results relate only to the samples included in this report. Results reported herein conform to themost current NELAC standards, where applicable, unless otherwise narrated in the body of the
report.
Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and
Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All
Microbiological analyses were performed at the laboratory where the samples were received.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Renee Spencer
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 29
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
CERTIFICATIONS
Pace Project No.:
Project:
9259046
16143 AGROTEC
Ormond Beach Certification IDs8 East Tower Circle Ormond Beach, FL 32174Wyoming Certification: FL NELAC ReciprocityAlabama Certification #: 41320Arizona Certification #: AZ0735Colorado Certification: FL NELAC ReciprocityConnecticut Certification #: PH 0216Florida Certification #: E83079Georgia Certification #: 955Guam Certification: FL NELAC ReciprocityHawaii Certification: FL NELAC ReciprocityKansas Certification #: E-10383Kentucky Certification #: 90050Louisiana Certification #: LA090012Maine Certification #: FL1264
Massachusetts Certification #: M-FL1264Michigan Certification #: 9911Virginia Certification #: 00432Texas Certification: FL NELAC ReciprocityTennessee Certification #: TN02974Puerto Rico Certification #: FL01264Pennsylvania Certification #: 68-547North Carolina Certification #: 12710New York Certification #: 11608New Jersey Certification #: FL765New Hampshire Certification #: 2958Nevada Certification: FL NELAC ReciprocityMontana Certification #: Cert 0074Mississippi Certification: FL NELAC Reciprocity
Charlotte Certification IDsWest Virginia Certification #: 357Connecticut Certification #: PH-0104Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84Louisiana/LELAP Certification #: 04034New Jersey Certification #: NC012North Carolina Drinking Water Certification #: 37706North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12Pennsylvania Certification #: 68-00784South Carolina Certification #: 990060001South Carolina Drinking Water Cert. #: 990060003Tennessee Certification #: 04010Virginia Certification #: 002139800 Kincey Ave. - Ste 100 Huntersville, NC 28078
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 29
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE SUMMARY
Pace Project No.:
Project:
9259046
16143 AGROTEC
Lab ID Sample ID Matrix Date Collected Date Received
9259046001 SB-3T 4-5 FT.Solid 12/07/09 11:15 12/08/09 16:00
9259046002 SB-3T 9-10 FT.Solid 12/07/09 11:30 12/08/09 16:00
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
Page 3 of 29
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
9259046
16143 AGROTEC
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
9259046001 SB-3T 4-5 FT.MADEP EPH 7 PASI-CCAH
MADEP VPH 5 PASI-CDHW
EPA 8270 21 PASI-OEAO
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CTNM
9259046002 SB-3T 9-10 FT.MADEP EPH 7 PASI-CCAH
MADEP VPH 5 PASI-CDHW
EPA 8270 21 PASI-OEAO
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CTNM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 4 of 29
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9259046
16143 AGROTEC
Sample:SB-3T 4-5 FT.Lab ID:9259046001 Collected:12/07/09 11:15 Received:12/08/09 16:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
MADEP EPH NC Soil Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)ND mg/kg 1 12/14/09 19:3912/11/09 08:3011.9 11.9
Aliphatic (C19-C36)ND mg/kg 1 12/14/09 19:3912/11/09 08:3011.9 11.9
Aromatic (C11-C22)ND mg/kg 1 12/14/09 19:3912/11/09 08:3011.9 11.9
Nonatriacontane (S)55 %1 12/14/09 19:39 7194-86-712/11/09 08:3040-140
o-Terphenyl (S)78 %1 12/14/09 19:39 84-15-112/11/09 08:3040-140
2-Fluorobiphenyl (S)85 %1 12/14/09 19:39 321-60-812/11/09 08:3040-140
2-Bromonaphthalene (S)92 %1 12/14/09 19:39 580-13-212/11/09 08:3040-140
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)ND mg/kg 1 12/29/09 03:2212/28/09 15:3316.2 16.2
Aliphatic (C09-C12)ND mg/kg 1 12/29/09 03:2212/28/09 15:3316.2 16.2
Aromatic (C09-C10)ND mg/kg 1 12/29/09 03:2212/28/09 15:3316.2 16.2
2,5-Dibromotoluene (PID)(S)121 %1 12/29/09 03:2212/28/09 15:3370-130
2,5-Dibromotoluene (FID)(S)120 %1 12/29/09 03:2212/28/09 15:3370-130
8270 MSSV Short List Microwave Analytical Method: EPA 8270
Acenaphthene ND ug/kg 1 12/16/09 20:52 83-32-912/14/09 12:5733.0 3.3
Acenaphthylene ND ug/kg 1 12/16/09 20:52 208-96-812/14/09 12:5733.0 3.9
Anthracene ND ug/kg 1 12/16/09 20:52 120-12-712/14/09 12:5733.0 2.0
Benzo(a)anthracene ND ug/kg 1 12/16/09 20:52 56-55-3 IR12/14/09 12:5733.0 3.0
Benzo(a)pyrene ND ug/kg 1 12/16/09 20:52 50-32-812/14/09 12:5733.0 3.6
Benzo(b)fluoranthene ND ug/kg 1 12/16/09 20:52 205-99-212/14/09 12:5733.0 2.3
Benzo(g,h,i)perylene ND ug/kg 1 12/16/09 20:52 191-24-212/14/09 12:5733.0 3.0
Benzo(k)fluoranthene ND ug/kg 1 12/16/09 20:52 207-08-912/14/09 12:5733.0 4.9
Chrysene ND ug/kg 1 12/16/09 20:52 218-01-912/14/09 12:5733.0 3.0
Dibenz(a,h)anthracene ND ug/kg 1 12/16/09 20:52 53-70-312/14/09 12:5733.0 3.5
Fluoranthene ND ug/kg 1 12/16/09 20:52 206-44-012/14/09 12:5733.0 3.7
Fluorene ND ug/kg 1 12/16/09 20:52 86-73-712/14/09 12:5733.0 2.5
Indeno(1,2,3-cd)pyrene ND ug/kg 1 12/16/09 20:52 193-39-512/14/09 12:5733.0 3.5
1-Methylnaphthalene ND ug/kg 1 12/16/09 20:52 90-12-012/14/09 12:5733.0 4.2
2-Methylnaphthalene ND ug/kg 1 12/16/09 20:52 91-57-612/14/09 12:5733.0 4.6
Naphthalene ND ug/kg 1 12/16/09 20:52 91-20-312/14/09 12:5733.0 3.5
Phenanthrene ND ug/kg 1 12/16/09 20:52 85-01-812/14/09 12:5733.0 3.1
Pyrene ND ug/kg 1 12/16/09 20:52 129-00-012/14/09 12:5733.0 4.0
Nitrobenzene-d5 (S)46 %1 12/16/09 20:52 4165-60-012/14/09 12:5710-110
2-Fluorobiphenyl (S)52 %1 12/16/09 20:52 321-60-812/14/09 12:5718-110
Terphenyl-d14 (S)54 %1 12/16/09 20:52 1718-51-012/14/09 12:5710-123
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone ND mg/kg 1 12/10/09 16:33 67-64-10.11 0.011
Benzene ND mg/kg 1 12/10/09 16:33 71-43-20.0055 0.0018
Bromobenzene ND mg/kg 1 12/10/09 16:33 108-86-10.0055 0.0022
Bromochloromethane ND mg/kg 1 12/10/09 16:33 74-97-50.0055 0.0019
Bromodichloromethane ND mg/kg 1 12/10/09 16:33 75-27-40.0055 0.0021
Bromoform ND mg/kg 1 12/10/09 16:33 75-25-20.0055 0.0025
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/30/2009 12:17 PM Page 5 of 29
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9259046
16143 AGROTEC
Sample:SB-3T 4-5 FT.Lab ID:9259046001 Collected:12/07/09 11:15 Received:12/08/09 16:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
8260/5035A Volatile Organics Analytical Method: EPA 8260
Bromomethane ND mg/kg 1 12/10/09 16:33 74-83-90.011 0.0028
2-Butanone (MEK)ND mg/kg 1 12/10/09 16:33 78-93-30.11 0.0032
n-Butylbenzene ND mg/kg 1 12/10/09 16:33 104-51-80.0055 0.0020
sec-Butylbenzene ND mg/kg 1 12/10/09 16:33 135-98-80.0055 0.0018
tert-Butylbenzene ND mg/kg 1 12/10/09 16:33 98-06-60.0055 0.0022
Carbon tetrachloride ND mg/kg 1 12/10/09 16:33 56-23-50.0055 0.0029
Chlorobenzene ND mg/kg 1 12/10/09 16:33 108-90-70.0055 0.0021
Chloroethane ND mg/kg 1 12/10/09 16:33 75-00-30.011 0.0026
Chloroform ND mg/kg 1 12/10/09 16:33 67-66-30.0055 0.0018
Chloromethane ND mg/kg 1 12/10/09 16:33 74-87-30.011 0.0026
2-Chlorotoluene ND mg/kg 1 12/10/09 16:33 95-49-80.0055 0.0019
4-Chlorotoluene ND mg/kg 1 12/10/09 16:33 106-43-40.0055 0.0020
1,2-Dibromo-3-chloropropane ND mg/kg 1 12/10/09 16:33 96-12-80.0055 0.0040
Dibromochloromethane ND mg/kg 1 12/10/09 16:33 124-48-10.0055 0.0020
1,2-Dibromoethane (EDB)ND mg/kg 1 12/10/09 16:33 106-93-40.0055 0.0020
Dibromomethane ND mg/kg 1 12/10/09 16:33 74-95-30.0055 0.0028
1,2-Dichlorobenzene ND mg/kg 1 12/10/09 16:33 95-50-10.0055 0.0021
1,3-Dichlorobenzene ND mg/kg 1 12/10/09 16:33 541-73-10.0055 0.0022
1,4-Dichlorobenzene ND mg/kg 1 12/10/09 16:33 106-46-70.0055 0.0019
Dichlorodifluoromethane ND mg/kg 1 12/10/09 16:33 75-71-80.011 0.0040
1,1-Dichloroethane ND mg/kg 1 12/10/09 16:33 75-34-30.0055 0.0017
1,2-Dichloroethane ND mg/kg 1 12/10/09 16:33 107-06-20.0055 0.0024
1,1-Dichloroethene ND mg/kg 1 12/10/09 16:33 75-35-40.0055 0.0020
cis-1,2-Dichloroethene ND mg/kg 1 12/10/09 16:33 156-59-20.0055 0.0015
trans-1,2-Dichloroethene ND mg/kg 1 12/10/09 16:33 156-60-50.0055 0.0021
1,2-Dichloropropane ND mg/kg 1 12/10/09 16:33 78-87-50.0055 0.0019
1,3-Dichloropropane ND mg/kg 1 12/10/09 16:33 142-28-90.0055 0.0021
2,2-Dichloropropane ND mg/kg 1 12/10/09 16:33 594-20-70.0055 0.0019
1,1-Dichloropropene ND mg/kg 1 12/10/09 16:33 563-58-60.0055 0.0017
cis-1,3-Dichloropropene ND mg/kg 1 12/10/09 16:33 10061-01-50.0055 0.0020
trans-1,3-Dichloropropene ND mg/kg 1 12/10/09 16:33 10061-02-60.0055 0.0017
Diisopropyl ether ND mg/kg 1 12/10/09 16:33 108-20-30.0055 0.0019
Ethylbenzene ND mg/kg 1 12/10/09 16:33 100-41-40.0055 0.0020
Hexachloro-1,3-butadiene ND mg/kg 1 12/10/09 16:33 87-68-30.0055 0.0022
2-Hexanone ND mg/kg 1 12/10/09 16:33 591-78-60.055 0.0043
Isopropylbenzene (Cumene)ND mg/kg 1 12/10/09 16:33 98-82-80.0055 0.0021
p-Isopropyltoluene ND mg/kg 1 12/10/09 16:33 99-87-60.0055 0.0019
Methylene Chloride ND mg/kg 1 12/10/09 16:33 75-09-20.022 0.0033
4-Methyl-2-pentanone (MIBK)ND mg/kg 1 12/10/09 16:33 108-10-10.055 0.0041
Methyl-tert-butyl ether ND mg/kg 1 12/10/09 16:33 1634-04-40.0055 0.0017
Naphthalene ND mg/kg 1 12/10/09 16:33 91-20-30.0055 0.0013
n-Propylbenzene ND mg/kg 1 12/10/09 16:33 103-65-10.0055 0.0019
Styrene ND mg/kg 1 12/10/09 16:33 100-42-50.0055 0.0020
1,1,1,2-Tetrachloroethane ND mg/kg 1 12/10/09 16:33 630-20-60.0055 0.0023
1,1,2,2-Tetrachloroethane ND mg/kg 1 12/10/09 16:33 79-34-50.0055 0.0021
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/30/2009 12:17 PM Page 6 of 29
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9259046
16143 AGROTEC
Sample:SB-3T 4-5 FT.Lab ID:9259046001 Collected:12/07/09 11:15 Received:12/08/09 16:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
8260/5035A Volatile Organics Analytical Method: EPA 8260
Tetrachloroethene ND mg/kg 1 12/10/09 16:33 127-18-40.0055 0.0019
Toluene ND mg/kg 1 12/10/09 16:33 108-88-30.0055 0.0020
1,2,3-Trichlorobenzene ND mg/kg 1 12/10/09 16:33 87-61-60.0055 0.0024
1,2,4-Trichlorobenzene ND mg/kg 1 12/10/09 16:33 120-82-10.0055 0.0018
1,1,1-Trichloroethane ND mg/kg 1 12/10/09 16:33 71-55-60.0055 0.0020
1,1,2-Trichloroethane ND mg/kg 1 12/10/09 16:33 79-00-50.0055 0.0023
Trichloroethene ND mg/kg 1 12/10/09 16:33 79-01-60.0055 0.0023
Trichlorofluoromethane ND mg/kg 1 12/10/09 16:33 75-69-40.0055 0.0024
1,2,3-Trichloropropane ND mg/kg 1 12/10/09 16:33 96-18-40.0055 0.0018
1,2,4-Trimethylbenzene ND mg/kg 1 12/10/09 16:33 95-63-60.0055 0.0022
1,3,5-Trimethylbenzene ND mg/kg 1 12/10/09 16:33 108-67-80.0055 0.0020
Vinyl acetate ND mg/kg 1 12/10/09 16:33 108-05-40.055 0.0097
Vinyl chloride ND mg/kg 1 12/10/09 16:33 75-01-40.011 0.0020
Xylene (Total)ND mg/kg 1 12/10/09 16:33 1330-20-70.011 0.0040
m&p-Xylene ND mg/kg 1 12/10/09 16:33 1330-20-70.011 0.0040
o-Xylene ND mg/kg 1 12/10/09 16:33 95-47-60.0055 0.0021
Dibromofluoromethane (S)103 %1 12/10/09 16:33 1868-53-779-116
Toluene-d8 (S)99 %1 12/10/09 16:33 2037-26-588-110
4-Bromofluorobenzene (S)104 %1 12/10/09 16:33 460-00-474-115
1,2-Dichloroethane-d4 (S)102 %1 12/10/09 16:33 17060-07-069-121
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 15.9 %1 12/10/09 08:480.10 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/30/2009 12:17 PM Page 7 of 29
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9259046
16143 AGROTEC
Sample:SB-3T 9-10 FT.Lab ID:9259046002 Collected:12/07/09 11:30 Received:12/08/09 16:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
MADEP EPH NC Soil Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)ND mg/kg 1 12/14/09 20:1212/11/09 08:3012.2 12.2
Aliphatic (C19-C36)ND mg/kg 1 12/14/09 20:1212/11/09 08:3012.2 12.2
Aromatic (C11-C22)ND mg/kg 1 12/14/09 20:1212/11/09 08:3012.2 12.2
Nonatriacontane (S)53 %1 12/14/09 20:12 7194-86-712/11/09 08:3040-140
o-Terphenyl (S)87 %1 12/14/09 20:12 84-15-112/11/09 08:3040-140
2-Fluorobiphenyl (S)106 %1 12/14/09 20:12 321-60-812/11/09 08:3040-140
2-Bromonaphthalene (S)109 %1 12/14/09 20:12 580-13-212/11/09 08:3040-140
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)20.8 mg/kg 1 12/29/09 02:5712/28/09 15:3311.9 11.9
Aliphatic (C09-C12)66.5 mg/kg 1 12/29/09 02:5712/28/09 15:3311.9 11.9
Aromatic (C09-C10)14.1 mg/kg 1 12/29/09 02:5712/28/09 15:3311.9 11.9
2,5-Dibromotoluene (PID)(S)138 %1 12/29/09 02:57 S512/28/09 15:3370-130
2,5-Dibromotoluene (FID)(S)160 %1 12/29/09 02:57 S512/28/09 15:3370-130
8270 MSSV Short List Microwave Analytical Method: EPA 8270
Acenaphthene ND ug/kg 1 12/16/09 21:18 83-32-912/14/09 12:5733.0 3.3
Acenaphthylene ND ug/kg 1 12/16/09 21:18 208-96-812/14/09 12:5733.0 3.9
Anthracene ND ug/kg 1 12/16/09 21:18 120-12-712/14/09 12:5733.0 2.0
Benzo(a)anthracene ND ug/kg 1 12/16/09 21:18 56-55-3 IR12/14/09 12:5733.0 3.0
Benzo(a)pyrene ND ug/kg 1 12/16/09 21:18 50-32-812/14/09 12:5733.0 3.6
Benzo(b)fluoranthene ND ug/kg 1 12/16/09 21:18 205-99-212/14/09 12:5733.0 2.3
Benzo(g,h,i)perylene ND ug/kg 1 12/16/09 21:18 191-24-212/14/09 12:5733.0 3.0
Benzo(k)fluoranthene ND ug/kg 1 12/16/09 21:18 207-08-912/14/09 12:5733.0 4.9
Chrysene ND ug/kg 1 12/16/09 21:18 218-01-912/14/09 12:5733.0 3.0
Dibenz(a,h)anthracene ND ug/kg 1 12/16/09 21:18 53-70-312/14/09 12:5733.0 3.5
Fluoranthene ND ug/kg 1 12/16/09 21:18 206-44-012/14/09 12:5733.0 3.7
Fluorene ND ug/kg 1 12/16/09 21:18 86-73-712/14/09 12:5733.0 2.5
Indeno(1,2,3-cd)pyrene ND ug/kg 1 12/16/09 21:18 193-39-512/14/09 12:5733.0 3.5
1-Methylnaphthalene ND ug/kg 1 12/16/09 21:18 90-12-012/14/09 12:5733.0 4.2
2-Methylnaphthalene ND ug/kg 1 12/16/09 21:18 91-57-612/14/09 12:5733.0 4.6
Naphthalene ND ug/kg 1 12/16/09 21:18 91-20-312/14/09 12:5733.0 3.5
Phenanthrene ND ug/kg 1 12/16/09 21:18 85-01-812/14/09 12:5733.0 3.1
Pyrene ND ug/kg 1 12/16/09 21:18 129-00-012/14/09 12:5733.0 4.0
Nitrobenzene-d5 (S)52 %1 12/16/09 21:18 4165-60-012/14/09 12:5710-110
2-Fluorobiphenyl (S)64 %1 12/16/09 21:18 321-60-812/14/09 12:5718-110
Terphenyl-d14 (S)77 %1 12/16/09 21:18 1718-51-012/14/09 12:5710-123
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone 0.013J mg/kg 1 12/11/09 17:09 67-64-10.088 0.0088
Benzene ND mg/kg 1 12/11/09 17:09 71-43-20.0044 0.0014
Bromobenzene ND mg/kg 1 12/11/09 17:09 108-86-10.0044 0.0018
Bromochloromethane ND mg/kg 1 12/11/09 17:09 74-97-50.0044 0.0015
Bromodichloromethane ND mg/kg 1 12/11/09 17:09 75-27-40.0044 0.0017
Bromoform ND mg/kg 1 12/11/09 17:09 75-25-20.0044 0.0020
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/30/2009 12:17 PM Page 8 of 29
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9259046
16143 AGROTEC
Sample:SB-3T 9-10 FT.Lab ID:9259046002 Collected:12/07/09 11:30 Received:12/08/09 16:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
8260/5035A Volatile Organics Analytical Method: EPA 8260
Bromomethane ND mg/kg 1 12/11/09 17:09 74-83-90.0088 0.0022
2-Butanone (MEK)ND mg/kg 1 12/11/09 17:09 78-93-30.088 0.0026
n-Butylbenzene ND mg/kg 1 12/11/09 17:09 104-51-80.0044 0.0016
sec-Butylbenzene ND mg/kg 1 12/11/09 17:09 135-98-80.0044 0.0014
tert-Butylbenzene ND mg/kg 1 12/11/09 17:09 98-06-60.0044 0.0018
Carbon tetrachloride ND mg/kg 1 12/11/09 17:09 56-23-50.0044 0.0023
Chlorobenzene ND mg/kg 1 12/11/09 17:09 108-90-70.0044 0.0017
Chloroethane ND mg/kg 1 12/11/09 17:09 75-00-30.0088 0.0021
Chloroform ND mg/kg 1 12/11/09 17:09 67-66-30.0044 0.0014
Chloromethane ND mg/kg 1 12/11/09 17:09 74-87-30.0088 0.0021
2-Chlorotoluene ND mg/kg 1 12/11/09 17:09 95-49-80.0044 0.0015
4-Chlorotoluene ND mg/kg 1 12/11/09 17:09 106-43-40.0044 0.0016
1,2-Dibromo-3-chloropropane ND mg/kg 1 12/11/09 17:09 96-12-80.0044 0.0032
Dibromochloromethane ND mg/kg 1 12/11/09 17:09 124-48-10.0044 0.0016
1,2-Dibromoethane (EDB)ND mg/kg 1 12/11/09 17:09 106-93-40.0044 0.0016
Dibromomethane ND mg/kg 1 12/11/09 17:09 74-95-30.0044 0.0022
1,2-Dichlorobenzene ND mg/kg 1 12/11/09 17:09 95-50-10.0044 0.0017
1,3-Dichlorobenzene ND mg/kg 1 12/11/09 17:09 541-73-10.0044 0.0018
1,4-Dichlorobenzene ND mg/kg 1 12/11/09 17:09 106-46-70.0044 0.0015
Dichlorodifluoromethane ND mg/kg 1 12/11/09 17:09 75-71-80.0088 0.0032
1,1-Dichloroethane ND mg/kg 1 12/11/09 17:09 75-34-30.0044 0.0013
1,2-Dichloroethane ND mg/kg 1 12/11/09 17:09 107-06-20.0044 0.0019
1,1-Dichloroethene ND mg/kg 1 12/11/09 17:09 75-35-40.0044 0.0016
cis-1,2-Dichloroethene ND mg/kg 1 12/11/09 17:09 156-59-20.0044 0.0012
trans-1,2-Dichloroethene ND mg/kg 1 12/11/09 17:09 156-60-50.0044 0.0017
1,2-Dichloropropane ND mg/kg 1 12/11/09 17:09 78-87-50.0044 0.0015
1,3-Dichloropropane ND mg/kg 1 12/11/09 17:09 142-28-90.0044 0.0017
2,2-Dichloropropane ND mg/kg 1 12/11/09 17:09 594-20-70.0044 0.0015
1,1-Dichloropropene ND mg/kg 1 12/11/09 17:09 563-58-60.0044 0.0013
cis-1,3-Dichloropropene ND mg/kg 1 12/11/09 17:09 10061-01-50.0044 0.0016
trans-1,3-Dichloropropene ND mg/kg 1 12/11/09 17:09 10061-02-60.0044 0.0013
Diisopropyl ether ND mg/kg 1 12/11/09 17:09 108-20-30.0044 0.0015
Ethylbenzene ND mg/kg 1 12/11/09 17:09 100-41-40.0044 0.0016
Hexachloro-1,3-butadiene ND mg/kg 1 12/11/09 17:09 87-68-30.0044 0.0018
2-Hexanone ND mg/kg 1 12/11/09 17:09 591-78-60.044 0.0034
Isopropylbenzene (Cumene)ND mg/kg 1 12/11/09 17:09 98-82-80.0044 0.0017
p-Isopropyltoluene ND mg/kg 1 12/11/09 17:09 99-87-60.0044 0.0015
Methylene Chloride ND mg/kg 1 12/11/09 17:09 75-09-20.018 0.0027
4-Methyl-2-pentanone (MIBK)ND mg/kg 1 12/11/09 17:09 108-10-10.044 0.0033
Methyl-tert-butyl ether ND mg/kg 1 12/11/09 17:09 1634-04-40.0044 0.0013
Naphthalene ND mg/kg 1 12/11/09 17:09 91-20-30.0044 0.0011
n-Propylbenzene ND mg/kg 1 12/11/09 17:09 103-65-10.0044 0.0015
Styrene ND mg/kg 1 12/11/09 17:09 100-42-50.0044 0.0016
1,1,1,2-Tetrachloroethane ND mg/kg 1 12/11/09 17:09 630-20-60.0044 0.0019
1,1,2,2-Tetrachloroethane ND mg/kg 1 12/11/09 17:09 79-34-50.0044 0.0017
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/30/2009 12:17 PM Page 9 of 29
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9259046
16143 AGROTEC
Sample:SB-3T 9-10 FT.Lab ID:9259046002 Collected:12/07/09 11:30 Received:12/08/09 16:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
8260/5035A Volatile Organics Analytical Method: EPA 8260
Tetrachloroethene ND mg/kg 1 12/11/09 17:09 127-18-40.0044 0.0015
Toluene ND mg/kg 1 12/11/09 17:09 108-88-30.0044 0.0016
1,2,3-Trichlorobenzene ND mg/kg 1 12/11/09 17:09 87-61-60.0044 0.0019
1,2,4-Trichlorobenzene ND mg/kg 1 12/11/09 17:09 120-82-10.0044 0.0014
1,1,1-Trichloroethane ND mg/kg 1 12/11/09 17:09 71-55-60.0044 0.0016
1,1,2-Trichloroethane ND mg/kg 1 12/11/09 17:09 79-00-50.0044 0.0019
Trichloroethene ND mg/kg 1 12/11/09 17:09 79-01-60.0044 0.0019
Trichlorofluoromethane ND mg/kg 1 12/11/09 17:09 75-69-40.0044 0.0019
1,2,3-Trichloropropane ND mg/kg 1 12/11/09 17:09 96-18-40.0044 0.0014
1,2,4-Trimethylbenzene ND mg/kg 1 12/11/09 17:09 95-63-60.0044 0.0018
1,3,5-Trimethylbenzene ND mg/kg 1 12/11/09 17:09 108-67-80.0044 0.0016
Vinyl acetate ND mg/kg 1 12/11/09 17:09 108-05-40.044 0.0078
Vinyl chloride ND mg/kg 1 12/11/09 17:09 75-01-40.0088 0.0016
Xylene (Total)ND mg/kg 1 12/11/09 17:09 1330-20-70.0088 0.0032
m&p-Xylene ND mg/kg 1 12/11/09 17:09 1330-20-70.0088 0.0032
o-Xylene ND mg/kg 1 12/11/09 17:09 95-47-60.0044 0.0017
Dibromofluoromethane (S)115 %1 12/11/09 17:09 1868-53-779-116
Toluene-d8 (S)101 %1 12/11/09 17:09 2037-26-588-110
4-Bromofluorobenzene (S)108 %1 12/11/09 17:09 460-00-474-115
1,2-Dichloroethane-d4 (S)105 %1 12/11/09 17:09 17060-07-069-121
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 18.2 %1 12/10/09 08:490.10 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/30/2009 12:17 PM Page 10 of 29
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9259046
16143 AGROTEC
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/8764
MADEP EPH
MADEP EPH
MADEP EPH NC Soil
Associated Lab Samples:9259046001, 9259046002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:377710
Associated Lab Samples:9259046001, 9259046002
Matrix:Solid
Analyzed
Aliphatic (C09-C18)mg/kg ND 10.0 12/14/09 17:58
Aliphatic (C19-C36)mg/kg ND 10.0 12/14/09 17:58
Aromatic (C11-C22)mg/kg ND 10.0 12/14/09 17:58
2-Bromonaphthalene (S)%104 40-140 12/14/09 17:58
2-Fluorobiphenyl (S)%102 40-140 12/14/09 17:58
Nonatriacontane (S)%76 40-140 12/14/09 17:58
o-Terphenyl (S)%94 40-140 12/14/09 17:58
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
377711LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
377712
Aliphatic (C09-C18)mg/kg ND10 76 40-14058ND 50
Aliphatic (C19-C36)mg/kg 10.213.3 76 40-14059ND 50
Aromatic (C11-C22)mg/kg 25.228.3 89 40-1409526.9 7 50
2-Bromonaphthalene (S)%106 40-140109
2-Fluorobiphenyl (S)%105 40-140107
Nonatriacontane (S)%76 40-14050
o-Terphenyl (S)%86 40-14090
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/30/2009 12:17 PM Page 11 of 29
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9259046
16143 AGROTEC
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GCV/3712
MADEP VPH
MADEP VPH
VPH NC Soil
Associated Lab Samples:9259046001, 9259046002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:384571
Associated Lab Samples:9259046001, 9259046002
Matrix:Solid
Analyzed
Aliphatic (C05-C08)mg/kg ND 10.0 12/29/09 01:43
Aliphatic (C09-C12)mg/kg ND 10.0 12/29/09 01:43
Aromatic (C09-C10)mg/kg ND 10.0 12/29/09 01:43
2,5-Dibromotoluene (FID)(S)%119 70-130 12/29/09 01:43
2,5-Dibromotoluene (PID)(S)%117 70-130 12/29/09 01:43
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
384572LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
384573
Aliphatic (C05-C08)mg/kg 14.915 99 70-13010215.3 3 25
Aliphatic (C09-C12)mg/kg 16.515 110 30-13011817.6 7 25
Aromatic (C09-C10)mg/kg ND5 101 70-130105ND 25
2,5-Dibromotoluene (FID)(S)%121 70-130118
2,5-Dibromotoluene (PID)(S)%120 70-130121
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/30/2009 12:17 PM Page 12 of 29
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9259046
16143 AGROTEC
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSSV/1501
EPA 8270
EPA 8270
8270 Solid MSSV Microwave Short Spike
Associated Lab Samples:9259046001, 9259046002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:26345
Associated Lab Samples:9259046001, 9259046002
Matrix:Solid
Analyzed
1-Methylnaphthalene ug/kg ND 32.8 12/16/09 19:34
2-Methylnaphthalene ug/kg ND 32.8 12/16/09 19:34
Acenaphthene ug/kg ND 32.8 12/16/09 19:34
Acenaphthylene ug/kg ND 32.8 12/16/09 19:34
Anthracene ug/kg ND 32.8 12/16/09 19:34
Benzo(a)anthracene ug/kg ND 32.8 IR12/16/09 19:34
Benzo(a)pyrene ug/kg ND 32.8 12/16/09 19:34
Benzo(b)fluoranthene ug/kg ND 32.8 12/16/09 19:34
Benzo(g,h,i)perylene ug/kg ND 32.8 12/16/09 19:34
Benzo(k)fluoranthene ug/kg ND 32.8 12/16/09 19:34
Chrysene ug/kg ND 32.8 12/16/09 19:34
Dibenz(a,h)anthracene ug/kg ND 32.8 12/16/09 19:34
Fluoranthene ug/kg ND 32.8 12/16/09 19:34
Fluorene ug/kg ND 32.8 12/16/09 19:34
Indeno(1,2,3-cd)pyrene ug/kg ND 32.8 12/16/09 19:34
Naphthalene ug/kg ND 32.8 12/16/09 19:34
Phenanthrene ug/kg ND 32.8 12/16/09 19:34
Pyrene ug/kg ND 32.8 12/16/09 19:34
2-Fluorobiphenyl (S)%68 18-110 12/16/09 19:34
Nitrobenzene-d5 (S)%59 10-110 12/16/09 19:34
Terphenyl-d14 (S)%81 10-123 12/16/09 19:34
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
26346LABORATORY CONTROL SAMPLE:
LCSSpike
1-Methylnaphthalene ug/kg 13001670 78 52.1-93
2-Methylnaphthalene ug/kg 13201670 79 51.8-92.6
Acenaphthene ug/kg 11401670 69 55.6-94.8
Acenaphthylene ug/kg 12901670 77 57.6-94
Anthracene ug/kg 13601670 82 63.5-98.2
Benzo(a)anthracene ug/kg 1380 IR16708357.3-101.5
Benzo(a)pyrene ug/kg 14401670 86 68.5-98.8
Benzo(b)fluoranthene ug/kg 14701670 88 66.7-98.6
Benzo(g,h,i)perylene ug/kg 13901670 83 70-130
Benzo(k)fluoranthene ug/kg 15101670 90 68.5-99.2
Chrysene ug/kg 13401670 81 52.9-104.1
Dibenz(a,h)anthracene ug/kg 13601670 82 58.1-100
Fluoranthene ug/kg 13901670 83 60-99.7
Fluorene ug/kg 13701670 82 61.2-97.5
Indeno(1,2,3-cd)pyrene ug/kg 13201670 79 49-102.7
Naphthalene ug/kg 11901670 72 53.9-103.7
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
Date: 12/30/2009 12:17 PM Page 13 of 29
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9259046
16143 AGROTEC
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
26346LABORATORY CONTROL SAMPLE:
LCSSpike
Phenanthrene ug/kg 13401670 81 48.2-98.3
Pyrene ug/kg 13601670 81 21.3-106.5
2-Fluorobiphenyl (S)%72 18-110
Nitrobenzene-d5 (S)%66 10-110
Terphenyl-d14 (S)%87 10-123
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
26347MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9259046002
26348
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1-Methylnaphthalene ug/kg 1670 67 52.1-9354 23 401640ND1110888
2-Methylnaphthalene ug/kg 1670 69 51.8-92.53 27 401640ND1160881
Acenaphthene ug/kg 1670 64 55.6-94.53 21 401640ND1070874
Acenaphthylene ug/kg 1670 73 57.6-9458 24 401640ND1220954
Anthracene ug/kg 1670 76 63.5-98.67 15 401640ND12701100
Benzo(a)anthracene ug/kg IR16707857.3-10167 17 401640ND13001090
Benzo(a)pyrene ug/kg 1670 78 68.5-98.69 13 401640ND13001140
Benzo(b)fluoranthene ug/kg 1670 80 66.7-98.65 22 401640ND13301070
Benzo(g,h,i)perylene ug/kg 1670 84 70-13073 16 401640ND14101200
Benzo(k)fluoranthene ug/kg 1670 81 68.5-99.69 17 401640ND13601140
Chrysene ug/kg 1670 75 52.9-10463 18 401640ND12401040
Dibenz(a,h)anthracene ug/kg 1670 80 58.1-10072 12 401640ND13301180
Fluoranthene ug/kg 1670 74 60-99.767 11 401640ND12301100
Fluorene ug/kg 1670 75 61.2-97.56 31 401640ND1260923
Indeno(1,2,3-cd)pyrene ug/kg 1670 79 49-102.770 14 401640ND13201150
Naphthalene ug/kg 1670 66 53.9-10353 24 401640ND1100867
Phenanthrene ug/kg 1670 75 48.2-98.63 19 401640ND12501030
Pyrene ug/kg 1670 75 21.3-10664 18 401640ND12501050
2-Fluorobiphenyl (S)%69 18-11056
Nitrobenzene-d5 (S)%58 10-11048
Terphenyl-d14 (S)%80 10-12369
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/30/2009 12:17 PM Page 14 of 29
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9259046
16143 AGROTEC
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/9286
EPA 8260
EPA 8260
8260 MSV 5035A Volatile Organics
Associated Lab Samples:9259046001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:377393
Associated Lab Samples:9259046001
Matrix:Solid
Analyzed
1,1,1,2-Tetrachloroethane mg/kg ND 0.0050 12/10/09 11:58
1,1,1-Trichloroethane mg/kg ND 0.0050 12/10/09 11:58
1,1,2,2-Tetrachloroethane mg/kg ND 0.0050 12/10/09 11:58
1,1,2-Trichloroethane mg/kg ND 0.0050 12/10/09 11:58
1,1-Dichloroethane mg/kg ND 0.0050 12/10/09 11:58
1,1-Dichloroethene mg/kg ND 0.0050 12/10/09 11:58
1,1-Dichloropropene mg/kg ND 0.0050 12/10/09 11:58
1,2,3-Trichlorobenzene mg/kg ND 0.0050 12/10/09 11:58
1,2,3-Trichloropropane mg/kg ND 0.0050 12/10/09 11:58
1,2,4-Trichlorobenzene mg/kg ND 0.0050 12/10/09 11:58
1,2,4-Trimethylbenzene mg/kg ND 0.0050 12/10/09 11:58
1,2-Dibromo-3-chloropropane mg/kg ND 0.0050 12/10/09 11:58
1,2-Dibromoethane (EDB)mg/kg ND 0.0050 12/10/09 11:58
1,2-Dichlorobenzene mg/kg ND 0.0050 12/10/09 11:58
1,2-Dichloroethane mg/kg ND 0.0050 12/10/09 11:58
1,2-Dichloropropane mg/kg ND 0.0050 12/10/09 11:58
1,3,5-Trimethylbenzene mg/kg ND 0.0050 12/10/09 11:58
1,3-Dichlorobenzene mg/kg ND 0.0050 12/10/09 11:58
1,3-Dichloropropane mg/kg ND 0.0050 12/10/09 11:58
1,4-Dichlorobenzene mg/kg ND 0.0050 12/10/09 11:58
2,2-Dichloropropane mg/kg ND 0.0050 12/10/09 11:58
2-Butanone (MEK)mg/kg ND 0.10 12/10/09 11:58
2-Chlorotoluene mg/kg ND 0.0050 12/10/09 11:58
2-Hexanone mg/kg ND 0.050 12/10/09 11:58
4-Chlorotoluene mg/kg ND 0.0050 12/10/09 11:58
4-Methyl-2-pentanone (MIBK)mg/kg ND 0.050 12/10/09 11:58
Acetone mg/kg ND 0.10 12/10/09 11:58
Benzene mg/kg ND 0.0050 12/10/09 11:58
Bromobenzene mg/kg ND 0.0050 12/10/09 11:58
Bromochloromethane mg/kg ND 0.0050 12/10/09 11:58
Bromodichloromethane mg/kg ND 0.0050 12/10/09 11:58
Bromoform mg/kg ND 0.0050 12/10/09 11:58
Bromomethane mg/kg ND 0.010 12/10/09 11:58
Carbon tetrachloride mg/kg ND 0.0050 12/10/09 11:58
Chlorobenzene mg/kg ND 0.0050 12/10/09 11:58
Chloroethane mg/kg ND 0.010 12/10/09 11:58
Chloroform mg/kg ND 0.0050 12/10/09 11:58
Chloromethane mg/kg ND 0.010 12/10/09 11:58
cis-1,2-Dichloroethene mg/kg ND 0.0050 12/10/09 11:58
cis-1,3-Dichloropropene mg/kg ND 0.0050 12/10/09 11:58
Dibromochloromethane mg/kg ND 0.0050 12/10/09 11:58
Dibromomethane mg/kg ND 0.0050 12/10/09 11:58
Dichlorodifluoromethane mg/kg ND 0.010 12/10/09 11:58
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/30/2009 12:17 PM Page 15 of 29
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9259046
16143 AGROTEC
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:377393
Associated Lab Samples:9259046001
Matrix:Solid
Analyzed
Diisopropyl ether mg/kg ND 0.0050 12/10/09 11:58
Ethylbenzene mg/kg ND 0.0050 12/10/09 11:58
Hexachloro-1,3-butadiene mg/kg ND 0.0050 12/10/09 11:58
Isopropylbenzene (Cumene)mg/kg ND 0.0050 12/10/09 11:58
m&p-Xylene mg/kg ND 0.010 12/10/09 11:58
Methyl-tert-butyl ether mg/kg ND 0.0050 12/10/09 11:58
Methylene Chloride mg/kg ND 0.020 12/10/09 11:58
n-Butylbenzene mg/kg ND 0.0050 12/10/09 11:58
n-Propylbenzene mg/kg ND 0.0050 12/10/09 11:58
Naphthalene mg/kg ND 0.0050 12/10/09 11:58
o-Xylene mg/kg ND 0.0050 12/10/09 11:58
p-Isopropyltoluene mg/kg ND 0.0050 12/10/09 11:58
sec-Butylbenzene mg/kg ND 0.0050 12/10/09 11:58
Styrene mg/kg ND 0.0050 12/10/09 11:58
tert-Butylbenzene mg/kg ND 0.0050 12/10/09 11:58
Tetrachloroethene mg/kg ND 0.0050 12/10/09 11:58
Toluene mg/kg ND 0.0050 12/10/09 11:58
trans-1,2-Dichloroethene mg/kg ND 0.0050 12/10/09 11:58
trans-1,3-Dichloropropene mg/kg ND 0.0050 12/10/09 11:58
Trichloroethene mg/kg ND 0.0050 12/10/09 11:58
Trichlorofluoromethane mg/kg ND 0.0050 12/10/09 11:58
Vinyl acetate mg/kg ND 0.050 12/10/09 11:58
Vinyl chloride mg/kg ND 0.010 12/10/09 11:58
Xylene (Total)mg/kg ND 0.010 12/10/09 11:58
1,2-Dichloroethane-d4 (S)%101 69-121 12/10/09 11:58
4-Bromofluorobenzene (S)%102 74-115 12/10/09 11:58
Dibromofluoromethane (S)%103 79-116 12/10/09 11:58
Toluene-d8 (S)%100 88-110 12/10/09 11:58
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
377394LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane mg/kg 0.060.05 120 75-137
1,1,1-Trichloroethane mg/kg 0.057.05 113 70-140
1,1,2,2-Tetrachloroethane mg/kg 0.058.05 115 74-133
1,1,2-Trichloroethane mg/kg 0.059.05 118 79-129
1,1-Dichloroethane mg/kg 0.056.05 112 72-139
1,1-Dichloroethene mg/kg 0.057.05 114 69-154
1,1-Dichloropropene mg/kg 0.058.05 116 74-138
1,2,3-Trichlorobenzene mg/kg 0.059.05 119 71-150
1,2,3-Trichloropropane mg/kg 0.062.05 123 74-135
1,2,4-Trichlorobenzene mg/kg 0.060.05 120 68-150
1,2,4-Trimethylbenzene mg/kg 0.060.05 120 70-130
1,2-Dibromo-3-chloropropane mg/kg 0.054.05 109 65-146
1,2-Dibromoethane (EDB)mg/kg 0.060.05 120 77-136
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/30/2009 12:17 PM Page 16 of 29
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9259046
16143 AGROTEC
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
377394LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichlorobenzene mg/kg 0.057.05 114 75-141
1,2-Dichloroethane mg/kg 0.058.05 115 74-134
1,2-Dichloropropane mg/kg 0.057.05 115 77-138
1,3,5-Trimethylbenzene mg/kg 0.058.05 117 65-128
1,3-Dichlorobenzene mg/kg 0.056.05 113 76-133
1,3-Dichloropropane mg/kg 0.059.05 118 79-132
1,4-Dichlorobenzene mg/kg 0.056.05 112 75-137
2,2-Dichloropropane mg/kg 0.056.05 112 73-137
2-Butanone (MEK)mg/kg 0.11.1 108 61-138
2-Chlorotoluene mg/kg 0.056.05 111 73-138
2-Hexanone mg/kg 0.12.1 116 58-159
4-Chlorotoluene mg/kg 0.057.05 114 75-136
4-Methyl-2-pentanone (MIBK)mg/kg 0.11.1 112 74-139
Acetone mg/kg 0.11.1 113 58-150
Benzene mg/kg 0.056.05 112 71-140
Bromobenzene mg/kg 0.055.05 111 72-144
Bromochloromethane mg/kg 0.058.05 117 78-133
Bromodichloromethane mg/kg 0.054.05 108 78-133
Bromoform mg/kg 0.061.05 122 74-132
Bromomethane mg/kg 0.067.05 135 63-184
Carbon tetrachloride mg/kg 0.057.05 115 73-143
Chlorobenzene mg/kg 0.060.05 121 77-137
Chloroethane mg/kg 0.059.05 117 68-146
Chloroform mg/kg 0.055.05 110 75-137
Chloromethane mg/kg 0.058.05 117 54-143
cis-1,2-Dichloroethene mg/kg 0.056.05 113 71-143
cis-1,3-Dichloropropene mg/kg 0.059.05 117 76-133
Dibromochloromethane mg/kg 0.058.05 115 77-131
Dibromomethane mg/kg 0.060.05 120 63-184
Dichlorodifluoromethane mg/kg 0.059.05 118 36-173
Diisopropyl ether mg/kg 0.053.05 106 68-144
Ethylbenzene mg/kg 0.059.05 119 69-141
Hexachloro-1,3-butadiene mg/kg 0.057.05 114 70-152
Isopropylbenzene (Cumene)mg/kg 0.062.05 124 77-143
m&p-Xylene mg/kg 0.12.1 120 72-138
Methyl-tert-butyl ether mg/kg 0.055.05 110 2-138
Methylene Chloride mg/kg 0.054.05 108 69-136
n-Butylbenzene mg/kg 0.058.05 116 65-128
n-Propylbenzene mg/kg 0.058.05 116 72-139
Naphthalene mg/kg 0.060.05 120 61-138
o-Xylene mg/kg 0.060.05 121 74-137
p-Isopropyltoluene mg/kg 0.059.05 118 66-128
sec-Butylbenzene mg/kg 0.057.05 114 72-140
Styrene mg/kg 0.063.05 126 76-137
tert-Butylbenzene mg/kg 0.059.05 117 68-141
Tetrachloroethene mg/kg 0.060.05 120 72-136
Toluene mg/kg 0.055.05 111 69-139
trans-1,2-Dichloroethene mg/kg 0.055.05 110 72-144
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/30/2009 12:17 PM Page 17 of 29
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9259046
16143 AGROTEC
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
377394LABORATORY CONTROL SAMPLE:
LCSSpike
trans-1,3-Dichloropropene mg/kg 0.059.05 119 73-135
Trichloroethene mg/kg 0.060.05 121 75-136
Trichlorofluoromethane mg/kg 0.059.05 118 69-144
Vinyl acetate mg/kg 0.13.1 131 50-150
Vinyl chloride mg/kg 0.055.05 109 61-145
Xylene (Total)mg/kg 0.18.15 120 73-138
1,2-Dichloroethane-d4 (S)%96 69-121
4-Bromofluorobenzene (S)%106 74-115
Dibromofluoromethane (S)%100 79-116
Toluene-d8 (S)%98 88-110
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
377778MATRIX SPIKE SAMPLE:
MSSpike
Result
9259051002
1,1-Dichloroethene mg/kg 0.040.041 98 33-158ND
Benzene mg/kg 0.042.041 103 46-143ND
Chlorobenzene mg/kg 0.046.041 113 29-159ND
Toluene mg/kg 0.043.041 105 38-145ND
Trichloroethene mg/kg 0.045.041 109 70-130ND
1,2-Dichloroethane-d4 (S)%93 69-121
4-Bromofluorobenzene (S)%98 74-115
Dibromofluoromethane (S)%99 79-116
Toluene-d8 (S)%98 88-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
9258756003
377777SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane mg/kg ND 30ND
1,1,1-Trichloroethane mg/kg ND 30ND
1,1,2,2-Tetrachloroethane mg/kg ND 30ND
1,1,2-Trichloroethane mg/kg ND 30ND
1,1-Dichloroethane mg/kg ND 30ND
1,1-Dichloroethene mg/kg ND 30ND
1,1-Dichloropropene mg/kg ND 30ND
1,2,3-Trichlorobenzene mg/kg ND 30ND
1,2,3-Trichloropropane mg/kg ND 30ND
1,2,4-Trichlorobenzene mg/kg ND 30ND
1,2,4-Trimethylbenzene mg/kg ND 30ND
1,2-Dibromo-3-chloropropane mg/kg ND 30ND
1,2-Dibromoethane (EDB)mg/kg ND 30ND
1,2-Dichlorobenzene mg/kg ND 30ND
1,2-Dichloroethane mg/kg ND 30ND
1,2-Dichloropropane mg/kg ND 30ND
1,3,5-Trimethylbenzene mg/kg ND 30ND
1,3-Dichlorobenzene mg/kg ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/30/2009 12:17 PM Page 18 of 29
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9259046
16143 AGROTEC
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
9258756003
377777SAMPLE DUPLICATE:
1,3-Dichloropropane mg/kg ND 30ND
1,4-Dichlorobenzene mg/kg ND 30ND
2,2-Dichloropropane mg/kg ND 30ND
2-Butanone (MEK)mg/kg ND 30ND
2-Chlorotoluene mg/kg ND 30ND
2-Hexanone mg/kg ND 30ND
4-Chlorotoluene mg/kg ND 30ND
4-Methyl-2-pentanone (MIBK)mg/kg ND 30ND
Acetone mg/kg 0.015J 30ND
Benzene mg/kg ND 30ND
Bromobenzene mg/kg ND 30ND
Bromochloromethane mg/kg ND 30ND
Bromodichloromethane mg/kg ND 30ND
Bromoform mg/kg ND 30ND
Bromomethane mg/kg ND 30ND
Carbon tetrachloride mg/kg ND 30ND
Chlorobenzene mg/kg ND 30ND
Chloroethane mg/kg ND 30ND
Chloroform mg/kg ND 30ND
Chloromethane mg/kg ND 30ND
cis-1,2-Dichloroethene mg/kg ND 30ND
cis-1,3-Dichloropropene mg/kg ND 30ND
Dibromochloromethane mg/kg ND 30ND
Dibromomethane mg/kg ND 30ND
Dichlorodifluoromethane mg/kg ND 30ND
Diisopropyl ether mg/kg ND 30ND
Ethylbenzene mg/kg ND 30ND
Hexachloro-1,3-butadiene mg/kg ND 30ND
Isopropylbenzene (Cumene)mg/kg ND 30ND
m&p-Xylene mg/kg ND 30ND
Methyl-tert-butyl ether mg/kg ND 30ND
Methylene Chloride mg/kg ND 30ND
n-Butylbenzene mg/kg ND 30ND
n-Propylbenzene mg/kg ND 30ND
Naphthalene mg/kg ND 30ND
o-Xylene mg/kg ND 30ND
p-Isopropyltoluene mg/kg ND 30ND
sec-Butylbenzene mg/kg ND 30ND
Styrene mg/kg ND 30ND
tert-Butylbenzene mg/kg ND 30ND
Tetrachloroethene mg/kg ND 30ND
Toluene mg/kg ND 30ND
trans-1,2-Dichloroethene mg/kg ND 30ND
trans-1,3-Dichloropropene mg/kg ND 30ND
Trichloroethene mg/kg ND 30ND
Trichlorofluoromethane mg/kg ND 30ND
Vinyl acetate mg/kg ND 30ND
Vinyl chloride mg/kg ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/30/2009 12:17 PM Page 19 of 29
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9259046
16143 AGROTEC
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
9258756003
377777SAMPLE DUPLICATE:
Xylene (Total)mg/kg ND 30ND
1,2-Dichloroethane-d4 (S)%104 6103
4-Bromofluorobenzene (S)%102 8103
Dibromofluoromethane (S)%103 6102
Toluene-d8 (S)%100 7100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/30/2009 12:17 PM Page 20 of 29
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9259046
16143 AGROTEC
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/9294
EPA 8260
EPA 8260
8260 MSV 5035A Volatile Organics
Associated Lab Samples:9259046002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:377877
Associated Lab Samples:9259046002
Matrix:Solid
Analyzed
1,1,1,2-Tetrachloroethane mg/kg ND 0.0050 12/11/09 09:50
1,1,1-Trichloroethane mg/kg ND 0.0050 12/11/09 09:50
1,1,2,2-Tetrachloroethane mg/kg ND 0.0050 12/11/09 09:50
1,1,2-Trichloroethane mg/kg ND 0.0050 12/11/09 09:50
1,1-Dichloroethane mg/kg ND 0.0050 12/11/09 09:50
1,1-Dichloroethene mg/kg ND 0.0050 12/11/09 09:50
1,1-Dichloropropene mg/kg ND 0.0050 12/11/09 09:50
1,2,3-Trichlorobenzene mg/kg ND 0.0050 12/11/09 09:50
1,2,3-Trichloropropane mg/kg ND 0.0050 12/11/09 09:50
1,2,4-Trichlorobenzene mg/kg ND 0.0050 12/11/09 09:50
1,2,4-Trimethylbenzene mg/kg ND 0.0050 12/11/09 09:50
1,2-Dibromo-3-chloropropane mg/kg ND 0.0050 12/11/09 09:50
1,2-Dibromoethane (EDB)mg/kg ND 0.0050 12/11/09 09:50
1,2-Dichlorobenzene mg/kg ND 0.0050 12/11/09 09:50
1,2-Dichloroethane mg/kg ND 0.0050 12/11/09 09:50
1,2-Dichloropropane mg/kg ND 0.0050 12/11/09 09:50
1,3,5-Trimethylbenzene mg/kg ND 0.0050 12/11/09 09:50
1,3-Dichlorobenzene mg/kg ND 0.0050 12/11/09 09:50
1,3-Dichloropropane mg/kg ND 0.0050 12/11/09 09:50
1,4-Dichlorobenzene mg/kg ND 0.0050 12/11/09 09:50
2,2-Dichloropropane mg/kg ND 0.0050 12/11/09 09:50
2-Butanone (MEK)mg/kg ND 0.10 12/11/09 09:50
2-Chlorotoluene mg/kg ND 0.0050 12/11/09 09:50
2-Hexanone mg/kg ND 0.050 12/11/09 09:50
4-Chlorotoluene mg/kg ND 0.0050 12/11/09 09:50
4-Methyl-2-pentanone (MIBK)mg/kg ND 0.050 12/11/09 09:50
Acetone mg/kg ND 0.10 12/11/09 09:50
Benzene mg/kg ND 0.0050 12/11/09 09:50
Bromobenzene mg/kg ND 0.0050 12/11/09 09:50
Bromochloromethane mg/kg ND 0.0050 12/11/09 09:50
Bromodichloromethane mg/kg ND 0.0050 12/11/09 09:50
Bromoform mg/kg ND 0.0050 12/11/09 09:50
Bromomethane mg/kg ND 0.010 12/11/09 09:50
Carbon tetrachloride mg/kg ND 0.0050 12/11/09 09:50
Chlorobenzene mg/kg ND 0.0050 12/11/09 09:50
Chloroethane mg/kg ND 0.010 12/11/09 09:50
Chloroform mg/kg ND 0.0050 12/11/09 09:50
Chloromethane mg/kg ND 0.010 12/11/09 09:50
cis-1,2-Dichloroethene mg/kg ND 0.0050 12/11/09 09:50
cis-1,3-Dichloropropene mg/kg ND 0.0050 12/11/09 09:50
Dibromochloromethane mg/kg ND 0.0050 12/11/09 09:50
Dibromomethane mg/kg ND 0.0050 12/11/09 09:50
Dichlorodifluoromethane mg/kg ND 0.010 12/11/09 09:50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/30/2009 12:17 PM Page 21 of 29
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9259046
16143 AGROTEC
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:377877
Associated Lab Samples:9259046002
Matrix:Solid
Analyzed
Diisopropyl ether mg/kg ND 0.0050 12/11/09 09:50
Ethylbenzene mg/kg ND 0.0050 12/11/09 09:50
Hexachloro-1,3-butadiene mg/kg ND 0.0050 12/11/09 09:50
Isopropylbenzene (Cumene)mg/kg ND 0.0050 12/11/09 09:50
m&p-Xylene mg/kg ND 0.010 12/11/09 09:50
Methyl-tert-butyl ether mg/kg ND 0.0050 12/11/09 09:50
Methylene Chloride mg/kg ND 0.020 12/11/09 09:50
n-Butylbenzene mg/kg ND 0.0050 12/11/09 09:50
n-Propylbenzene mg/kg ND 0.0050 12/11/09 09:50
Naphthalene mg/kg ND 0.0050 12/11/09 09:50
o-Xylene mg/kg ND 0.0050 12/11/09 09:50
p-Isopropyltoluene mg/kg ND 0.0050 12/11/09 09:50
sec-Butylbenzene mg/kg ND 0.0050 12/11/09 09:50
Styrene mg/kg ND 0.0050 12/11/09 09:50
tert-Butylbenzene mg/kg ND 0.0050 12/11/09 09:50
Tetrachloroethene mg/kg ND 0.0050 12/11/09 09:50
Toluene mg/kg ND 0.0050 12/11/09 09:50
trans-1,2-Dichloroethene mg/kg ND 0.0050 12/11/09 09:50
trans-1,3-Dichloropropene mg/kg ND 0.0050 12/11/09 09:50
Trichloroethene mg/kg ND 0.0050 12/11/09 09:50
Trichlorofluoromethane mg/kg ND 0.0050 12/11/09 09:50
Vinyl acetate mg/kg ND 0.050 12/11/09 09:50
Vinyl chloride mg/kg ND 0.010 12/11/09 09:50
Xylene (Total)mg/kg ND 0.010 12/11/09 09:50
1,2-Dichloroethane-d4 (S)%101 69-121 12/11/09 09:50
4-Bromofluorobenzene (S)%101 74-115 12/11/09 09:50
Dibromofluoromethane (S)%102 79-116 12/11/09 09:50
Toluene-d8 (S)%100 88-110 12/11/09 09:50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
377878LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane mg/kg 0.057.05 114 75-137
1,1,1-Trichloroethane mg/kg 0.054.05 108 70-140
1,1,2,2-Tetrachloroethane mg/kg 0.054.05 108 74-133
1,1,2-Trichloroethane mg/kg 0.057.05 115 79-129
1,1-Dichloroethane mg/kg 0.053.05 106 72-139
1,1-Dichloroethene mg/kg 0.055.05 109 69-154
1,1-Dichloropropene mg/kg 0.056.05 111 74-138
1,2,3-Trichlorobenzene mg/kg 0.058.05 115 71-150
1,2,3-Trichloropropane mg/kg 0.055.05 111 74-135
1,2,4-Trichlorobenzene mg/kg 0.058.05 116 68-150
1,2,4-Trimethylbenzene mg/kg 0.059.05 117 70-130
1,2-Dibromo-3-chloropropane mg/kg 0.053.05 107 65-146
1,2-Dibromoethane (EDB)mg/kg 0.058.05 116 77-136
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/30/2009 12:17 PM Page 22 of 29
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9259046
16143 AGROTEC
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
377878LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichlorobenzene mg/kg 0.055.05 110 75-141
1,2-Dichloroethane mg/kg 0.054.05 108 74-134
1,2-Dichloropropane mg/kg 0.054.05 108 77-138
1,3,5-Trimethylbenzene mg/kg 0.057.05 113 65-128
1,3-Dichlorobenzene mg/kg 0.055.05 110 76-133
1,3-Dichloropropane mg/kg 0.056.05 112 79-132
1,4-Dichlorobenzene mg/kg 0.054.05 109 75-137
2,2-Dichloropropane mg/kg 0.054.05 107 73-137
2-Butanone (MEK)mg/kg 0.10.1 104 61-138
2-Chlorotoluene mg/kg 0.053.05 107 73-138
2-Hexanone mg/kg 0.11.1 114 58-159
4-Chlorotoluene mg/kg 0.055.05 111 75-136
4-Methyl-2-pentanone (MIBK)mg/kg 0.11.1 107 74-139
Acetone mg/kg 0.10.1 102 58-150
Benzene mg/kg 0.053.05 105 71-140
Bromobenzene mg/kg 0.054.05 108 72-144
Bromochloromethane mg/kg 0.054.05 108 78-133
Bromodichloromethane mg/kg 0.051.05 103 78-133
Bromoform mg/kg 0.058.05 116 74-132
Bromomethane mg/kg 0.062.05 125 63-184
Carbon tetrachloride mg/kg 0.055.05 110 73-143
Chlorobenzene mg/kg 0.057.05 115 77-137
Chloroethane mg/kg 0.056.05 112 68-146
Chloroform mg/kg 0.052.05 105 75-137
Chloromethane mg/kg 0.057.05 113 54-143
cis-1,2-Dichloroethene mg/kg 0.053.05 106 71-143
cis-1,3-Dichloropropene mg/kg 0.057.05 113 76-133
Dibromochloromethane mg/kg 0.054.05 108 77-131
Dibromomethane mg/kg 0.056.05 113 63-184
Dichlorodifluoromethane mg/kg 0.056.05 113 36-173
Diisopropyl ether mg/kg 0.051.05 102 68-144
Ethylbenzene mg/kg 0.056.05 112 69-141
Hexachloro-1,3-butadiene mg/kg 0.055.05 110 70-152
Isopropylbenzene (Cumene)mg/kg 0.059.05 118 77-143
m&p-Xylene mg/kg 0.11.1 114 72-138
Methyl-tert-butyl ether mg/kg 0.051.05 102 2-138
Methylene Chloride mg/kg 0.051.05 102 69-136
n-Butylbenzene mg/kg 0.057.05 115 65-128
n-Propylbenzene mg/kg 0.056.05 112 72-139
Naphthalene mg/kg 0.059.05 118 61-138
o-Xylene mg/kg 0.057.05 114 74-137
p-Isopropyltoluene mg/kg 0.058.05 115 66-128
sec-Butylbenzene mg/kg 0.056.05 111 72-140
Styrene mg/kg 0.060.05 120 76-137
tert-Butylbenzene mg/kg 0.057.05 114 68-141
Tetrachloroethene mg/kg 0.057.05 114 72-136
Toluene mg/kg 0.053.05 106 69-139
trans-1,2-Dichloroethene mg/kg 0.052.05 104 72-144
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/30/2009 12:17 PM Page 23 of 29
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9259046
16143 AGROTEC
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
377878LABORATORY CONTROL SAMPLE:
LCSSpike
trans-1,3-Dichloropropene mg/kg 0.056.05 112 73-135
Trichloroethene mg/kg 0.057.05 115 75-136
Trichlorofluoromethane mg/kg 0.056.05 113 69-144
Vinyl acetate mg/kg 0.13.1 134 50-150
Vinyl chloride mg/kg 0.051.05 103 61-145
Xylene (Total)mg/kg 0.17.15 114 73-138
1,2-Dichloroethane-d4 (S)%97 69-121
4-Bromofluorobenzene (S)%103 74-115
Dibromofluoromethane (S)%100 79-116
Toluene-d8 (S)%99 88-110
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
378086MATRIX SPIKE SAMPLE:
MSSpike
Result
9259236001
1,1-Dichloroethene mg/kg 0.040.046 88 33-158ND
Benzene mg/kg 0.044.046 97 46-143ND
Chlorobenzene mg/kg 0.047.046 104 29-159ND
Toluene mg/kg 0.045.046 98 38-145ND
Trichloroethene mg/kg 0.047.046 104 70-130ND
1,2-Dichloroethane-d4 (S)%102 69-121
4-Bromofluorobenzene (S)%102 74-115
Dibromofluoromethane (S)%98 79-116
Toluene-d8 (S)%99 88-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
9259238001
378087SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane mg/kg ND 30ND
1,1,1-Trichloroethane mg/kg ND 30ND
1,1,2,2-Tetrachloroethane mg/kg ND 30ND
1,1,2-Trichloroethane mg/kg ND 30ND
1,1-Dichloroethane mg/kg ND 30ND
1,1-Dichloroethene mg/kg ND 30ND
1,1-Dichloropropene mg/kg ND 30ND
1,2,3-Trichlorobenzene mg/kg ND 30ND
1,2,3-Trichloropropane mg/kg ND 30ND
1,2,4-Trichlorobenzene mg/kg ND 30ND
1,2,4-Trimethylbenzene mg/kg ND 30ND
1,2-Dibromo-3-chloropropane mg/kg ND 30ND
1,2-Dibromoethane (EDB)mg/kg ND 30ND
1,2-Dichlorobenzene mg/kg ND 30ND
1,2-Dichloroethane mg/kg ND 30ND
1,2-Dichloropropane mg/kg ND 30ND
1,3,5-Trimethylbenzene mg/kg ND 30ND
1,3-Dichlorobenzene mg/kg ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/30/2009 12:17 PM Page 24 of 29
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9259046
16143 AGROTEC
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
9259238001
378087SAMPLE DUPLICATE:
1,3-Dichloropropane mg/kg ND 30ND
1,4-Dichlorobenzene mg/kg ND 30ND
2,2-Dichloropropane mg/kg ND 30ND
2-Butanone (MEK)mg/kg ND 30ND
2-Chlorotoluene mg/kg ND 30ND
2-Hexanone mg/kg ND 30ND
4-Chlorotoluene mg/kg ND 30ND
4-Methyl-2-pentanone (MIBK)mg/kg ND 30ND
Acetone mg/kg ND 30ND
Benzene mg/kg ND 30ND
Bromobenzene mg/kg ND 30ND
Bromochloromethane mg/kg ND 30ND
Bromodichloromethane mg/kg ND 30ND
Bromoform mg/kg ND 30ND
Bromomethane mg/kg ND 30ND
Carbon tetrachloride mg/kg ND 30ND
Chlorobenzene mg/kg ND 30ND
Chloroethane mg/kg ND 30ND
Chloroform mg/kg ND 30ND
Chloromethane mg/kg ND 30ND
cis-1,2-Dichloroethene mg/kg ND 30ND
cis-1,3-Dichloropropene mg/kg ND 30ND
Dibromochloromethane mg/kg ND 30ND
Dibromomethane mg/kg ND 30ND
Dichlorodifluoromethane mg/kg ND 30ND
Diisopropyl ether mg/kg ND 30ND
Ethylbenzene mg/kg ND 30ND
Hexachloro-1,3-butadiene mg/kg ND 30ND
Isopropylbenzene (Cumene)mg/kg ND 30ND
m&p-Xylene mg/kg ND 30ND
Methyl-tert-butyl ether mg/kg ND 30ND
Methylene Chloride mg/kg ND 30ND
n-Butylbenzene mg/kg ND 30ND
n-Propylbenzene mg/kg ND 30ND
Naphthalene mg/kg ND 30ND
o-Xylene mg/kg ND 30ND
p-Isopropyltoluene mg/kg ND 30ND
sec-Butylbenzene mg/kg ND 30ND
Styrene mg/kg ND 30ND
tert-Butylbenzene mg/kg ND 30ND
Tetrachloroethene mg/kg ND 30ND
Toluene mg/kg ND 30ND
trans-1,2-Dichloroethene mg/kg ND 30ND
trans-1,3-Dichloropropene mg/kg ND 30ND
Trichloroethene mg/kg ND 30ND
Trichlorofluoromethane mg/kg ND 30ND
Vinyl acetate mg/kg ND 30ND
Vinyl chloride mg/kg ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/30/2009 12:17 PM Page 25 of 29
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9259046
16143 AGROTEC
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
9259238001
378087SAMPLE DUPLICATE:
Xylene (Total)mg/kg ND 30ND
1,2-Dichloroethane-d4 (S)%100 6104
4-Bromofluorobenzene (S)%103 10103
Dibromofluoromethane (S)%105 10104
Toluene-d8 (S)%99 9100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/30/2009 12:17 PM Page 26 of 29
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9259046
16143 AGROTEC
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
PMST/2923
ASTM D2974-87
ASTM D2974-87
Dry Weight/Percent Moisture
Associated Lab Samples:9259046001, 9259046002
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
9258968001
376874SAMPLE DUPLICATE:
Percent Moisture %11.0 1 2511.1
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
9259092003
376875SAMPLE DUPLICATE:
Percent Moisture %21.0 4 2521.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/30/2009 12:17 PM Page 27 of 29
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALIFIERS
Pace Project No.:
Project:
9259046
16143 AGROTEC
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution ofthe sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes.
U - Indicates the compound was analyzed for, but not detected.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
The internal standard recovery associated with this result exceeds the upper control limit. The reported result should beconsidered an estimated value.IR
Surrogate recovery outside control limits due to matrix interferences (not confirmed by re-analysis).S5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/30/2009 12:17 PM Page 28 of 29
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
9259046
16143 AGROTEC
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
9259046001 OEXT/8764 GCSV/6846SB-3T 4-5 FT.MADEP EPH MADEP EPH
9259046002 OEXT/8764 GCSV/6846SB-3T 9-10 FT.MADEP EPH MADEP EPH
9259046001 GCV/3712 GCV/3716SB-3T 4-5 FT.MADEP VPH MADEP VPH
9259046002 GCV/3712 GCV/3716SB-3T 9-10 FT.MADEP VPH MADEP VPH
9259046001 MSSV/1501 MSSV/1170SB-3T 4-5 FT.EPA 8270 EPA 8270
9259046002 MSSV/1501 MSSV/1170SB-3T 9-10 FT.EPA 8270 EPA 8270
9259046001 MSV/9286SB-3T 4-5 FT.EPA 8260
9259046002 MSV/9294SB-3T 9-10 FT.EPA 8260
9259046001 PMST/2923SB-3T 4-5 FT.ASTM D2974-87
9259046002 PMST/2923SB-3T 9-10 FT.ASTM D2974-87
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 12/30/2009 12:17 PM Page 29 of 29
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
October 26, 2009
LIMS USE: FR - LINDA BLALOCK
LIMS OBJECT ID: 9254959
9254959
Project:
Pace Project No.:
RE:
Ms. Linda BlalockNCDENR - UST Section1637 Mail Service CenterRaleigh, NC 276991637
16143 AGROTEC
Dear Ms. Blalock:
Enclosed are the analytical results for sample(s) received by the laboratory on October 09, 2009.
The results relate only to the samples included in this report. Results reported herein conform to themost current NELAC standards, where applicable, unless otherwise narrated in the body of the
report.
Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and
Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All
Microbiological analyses were performed at the laboratory where the samples were received.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Renee Spencer
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
Page 1 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
CERTIFICATIONS
Pace Project No.:
Project:
9254959
16143 AGROTEC
Charlotte Certification IDsWest Virginia Certification #: 357Virginia Certification #: 00213Connecticut Certification #: PH-0104Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84Louisiana/LELAP Certification #: 04034New Jersey Certification #: NC012
North Carolina Drinking Water Certification #: 37706North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12Pennsylvania Certification #: 68-00784South Carolina Certification #: 990060001South Carolina Drinking Water Cert. #: 990060003Tennessee Certification #: 04010
Asheville Certification IDsWest Virginia Certification #: 356Florida/NELAP Certification #: E87648Louisiana/LELAP Certification #: 03095Massachusetts Certification #: M-NC030New Jersey Certification #: NC011North Carolina Bioassay Certification #: 9Connecticut Certification #: PH-0106
North Carolina Wastewater Certification #: 40Pennsylvania Certification #: 68-03578South Carolina Bioassay Certification #: 99030002South Carolina Certification #: 99030001Tennessee Certification #: 2980Virginia Certification #: 00072North Carolina Drinking Water Certification #: 37712
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE SUMMARY
Pace Project No.:
Project:
9254959
16143 AGROTEC
Lab ID Sample ID Matrix Date Collected Date Received
9254959001 MW-1 Water 10/08/09 11:45 10/09/09 16:00
9254959002 WSW-1 Water 10/08/09 12:00 10/09/09 16:00
9254959003 WSW-2 Water 10/08/09 12:30 10/09/09 16:00
9254959004 WSW-3 Water 10/08/09 13:20 10/09/09 16:00
9254959005 WSW-4 Water 10/08/09 13:00 10/09/09 16:00
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
Page 3 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
9254959
16143 AGROTEC
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
9254959001 MW-1 EPA 200.7 1 PASI-AJMW
EPA 625 58 PASI-CPPM
MADEP EPH 7 PASI-CJAC
MADEP VPH 5 PASI-CDHW
SM 6200B 64 PASI-CMCK
9254959002 WSW-1 EPA 200.7 1 PASI-AJMW
EPA 625 58 PASI-CPPM
MADEP EPH 7 PASI-CJAC
MADEP VPH 5 PASI-CDHW
SM 6200B 64 PASI-CMCK
9254959003 WSW-2 EPA 200.7 1 PASI-AJMW
EPA 625 58 PASI-CPPM
MADEP EPH 7 PASI-CJAC
MADEP VPH 5 PASI-CDHW
SM 6200B 64 PASI-CMCK
9254959004 WSW-3 EPA 200.7 1 PASI-AJMW
EPA 625 58 PASI-CPPM
MADEP EPH 7 PASI-CJAC
MADEP VPH 5 PASI-CDHW
SM 6200B 64 PASI-CMCK
9254959005 WSW-4 EPA 200.7 1 PASI-AJMW
EPA 625 58 PASI-CPPM
MADEP EPH 7 PASI-CJAC
MADEP VPH 5 PASI-CDHW
SM 6200B 64 PASI-CMCK
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 4 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9254959
16143 AGROTEC
Sample:MW-1 Lab ID:9254959001 Collected:10/08/09 11:45 Received:10/09/09 16:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
MADEP EPH NC Water Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)ND ug/L 1 10/14/09 21:1010/13/09 08:00143143
Aliphatic (C19-C36)ND ug/L 1 10/14/09 21:1010/13/09 08:00143143
Aromatic (C11-C22)ND ug/L 1 10/15/09 21:1010/13/09 08:00143143
Nonatriacontane (S)91 %1 10/14/09 21:10 7194-86-710/13/09 08:0040-140
o-Terphenyl (S)72 %1 10/15/09 21:10 84-15-110/13/09 08:0040-140
2-Fluorobiphenyl (S)80 %1 10/15/09 21:10 321-60-810/13/09 08:0040-140
2-Bromonaphthalene (S)84 %1 10/15/09 21:10 580-13-210/13/09 08:0040-140
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)ND ug/L 1 10/20/09 17:37100100
Aliphatic (C09-C12)ND ug/L 1 10/20/09 17:37100100
Aromatic (C09-C10)ND ug/L 1 10/20/09 17:37100100
2,5-Dibromotoluene (PID)(S)79 %1 10/20/09 17:3770-130
2,5-Dibromotoluene (FID)(S)93 %1 10/20/09 17:3770-130
200.7 MET ICP, 3030C Analytical Method: EPA 200.7 Preparation Method: SM 3030C
Lead 9.1 ug/L 1 10/13/09 04:02 7439-92-110/11/09 09:405.0 4.0
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
Acenaphthene ND ug/L 1 10/21/09 04:57 83-32-910/13/09 11:155.9 3.3
Acenaphthylene ND ug/L 1 10/21/09 04:57 208-96-810/13/09 11:155.9 3.3
Anthracene ND ug/L 1 10/21/09 04:57 120-12-710/13/09 11:155.9 3.4
Benzo(a)anthracene ND ug/L 1 10/21/09 04:57 56-55-310/13/09 11:155.9 3.3
Benzo(a)pyrene ND ug/L 1 10/21/09 04:57 50-32-810/13/09 11:155.9 3.6
Benzo(b)fluoranthene ND ug/L 1 10/21/09 04:57 205-99-210/13/09 11:155.9 4.2
Benzo(g,h,i)perylene ND ug/L 1 10/21/09 04:57 191-24-210/13/09 11:155.9 3.6
Benzo(k)fluoranthene ND ug/L 1 10/21/09 04:57 207-08-910/13/09 11:155.9 3.5
4-Bromophenylphenyl ether ND ug/L 1 10/21/09 04:57 101-55-310/13/09 11:155.9 2.8
Butylbenzylphthalate ND ug/L 1 10/21/09 04:57 85-68-710/13/09 11:155.9 3.4
4-Chloro-3-methylphenol ND ug/L 1 10/21/09 04:57 59-50-710/13/09 11:155.9 3.3
bis(2-Chloroethoxy)methane ND ug/L 1 10/21/09 04:57 111-91-110/13/09 11:1511.8 6.8
bis(2-Chloroethyl) ether ND ug/L 1 10/21/09 04:57 111-44-410/13/09 11:155.9 5.6
bis(2-Chloroisopropyl) ether ND ug/L 1 10/21/09 04:57 108-60-110/13/09 11:155.9 4.7
2-Chloronaphthalene ND ug/L 1 10/21/09 04:57 91-58-710/13/09 11:155.9 4.2
2-Chlorophenol ND ug/L 1 10/21/09 04:57 95-57-810/13/09 11:155.9 5.2
4-Chlorophenylphenyl ether ND ug/L 1 10/21/09 04:57 7005-72-310/13/09 11:155.9 3.2
Chrysene ND ug/L 1 10/21/09 04:57 218-01-910/13/09 11:155.9 3.2
Dibenz(a,h)anthracene ND ug/L 1 10/21/09 04:57 53-70-310/13/09 11:155.9 3.4
3,3'-Dichlorobenzidine ND ug/L 1 10/21/09 04:57 91-94-110/13/09 11:155.9 4.0
2,4-Dichlorophenol ND ug/L 1 10/21/09 04:57 120-83-210/13/09 11:155.9 4.8
Diethylphthalate ND ug/L 1 10/21/09 04:57 84-66-210/13/09 11:155.9 3.2
2,4-Dimethylphenol ND ug/L 1 10/21/09 04:57 105-67-910/13/09 11:1511.8 6.6
Dimethylphthalate ND ug/L 1 10/21/09 04:57 131-11-310/13/09 11:155.9 2.8
Di-n-butylphthalate ND ug/L 1 10/21/09 04:57 84-74-210/13/09 11:155.9 3.4
4,6-Dinitro-2-methylphenol ND ug/L 1 10/21/09 04:57 534-52-110/13/09 11:1523.5 9.2
2,4-Dinitrophenol ND ug/L 1 10/21/09 04:57 51-28-510/13/09 11:1558.8 11.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 5 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9254959
16143 AGROTEC
Sample:MW-1 Lab ID:9254959001 Collected:10/08/09 11:45 Received:10/09/09 16:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
2,4-Dinitrotoluene ND ug/L 1 10/21/09 04:57 121-14-210/13/09 11:155.9 3.1
2,6-Dinitrotoluene ND ug/L 1 10/21/09 04:57 606-20-210/13/09 11:155.9 3.3
Di-n-octylphthalate ND ug/L 1 10/21/09 04:57 117-84-010/13/09 11:155.9 3.4
bis(2-Ethylhexyl)phthalate ND ug/L 1 10/21/09 04:57 117-81-710/13/09 11:155.9 2.5
Fluoranthene ND ug/L 1 10/21/09 04:57 206-44-010/13/09 11:155.9 3.4
Fluorene ND ug/L 1 10/21/09 04:57 86-73-710/13/09 11:155.9 3.1
Hexachloro-1,3-butadiene ND ug/L 1 10/21/09 04:57 87-68-310/13/09 11:155.9 3.9
Hexachlorobenzene ND ug/L 1 10/21/09 04:57 118-74-110/13/09 11:155.9 3.1
Hexachlorocyclopentadiene ND ug/L 1 10/21/09 04:57 77-47-410/13/09 11:1511.8 4.4
Hexachloroethane ND ug/L 1 10/21/09 04:57 67-72-110/13/09 11:155.9 3.9
Indeno(1,2,3-cd)pyrene ND ug/L 1 10/21/09 04:57 193-39-510/13/09 11:155.9 3.5
Isophorone ND ug/L 1 10/21/09 04:57 78-59-110/13/09 11:1511.8 7.6
Naphthalene ND ug/L 1 10/21/09 04:57 91-20-310/13/09 11:155.9 4.5
Nitrobenzene ND ug/L 1 10/21/09 04:57 98-95-310/13/09 11:155.9 5.2
2-Nitrophenol ND ug/L 1 10/21/09 04:57 88-75-510/13/09 11:155.9 5.4
4-Nitrophenol ND ug/L 1 10/21/09 04:57 100-02-710/13/09 11:1558.8 2.4
N-Nitrosodimethylamine ND ug/L 1 10/21/09 04:57 62-75-910/13/09 11:155.9 3.6
N-Nitroso-di-n-propylamine ND ug/L 1 10/21/09 04:57 621-64-710/13/09 11:155.9 4.4
N-Nitrosodiphenylamine ND ug/L 1 10/21/09 04:57 86-30-610/13/09 11:1511.8 7.8
Pentachlorophenol ND ug/L 1 10/21/09 04:57 87-86-510/13/09 11:1529.4 1.9
Phenanthrene ND ug/L 1 10/21/09 04:57 85-01-810/13/09 11:155.9 3.2
Phenol ND ug/L 1 10/21/09 04:57 108-95-210/13/09 11:155.9 2.1
Pyrene ND ug/L 1 10/21/09 04:57 129-00-010/13/09 11:155.9 3.4
1,2,4-Trichlorobenzene ND ug/L 1 10/21/09 04:57 120-82-110/13/09 11:155.9 4.0
2,4,6-Trichlorophenol ND ug/L 1 10/21/09 04:57 88-06-210/13/09 11:1511.8 7.2
Nitrobenzene-d5 (S)75 %1 10/21/09 04:57 4165-60-010/13/09 11:1510-120
2-Fluorobiphenyl (S)65 %1 10/21/09 04:57 321-60-810/13/09 11:1515-120
Terphenyl-d14 (S)98 %1 10/21/09 04:57 1718-51-010/13/09 11:1511-131
Phenol-d6 (S)37 %1 10/21/09 04:57 13127-88-310/13/09 11:1510-120
2-Fluorophenol (S)47 %1 10/21/09 04:57 367-12-410/13/09 11:1510-120
2,4,6-Tribromophenol (S)83 %1 10/21/09 04:57 118-79-610/13/09 11:1510-137
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 10/17/09 01:59 71-43-20.50 0.50
Bromobenzene ND ug/L 1 10/17/09 01:59 108-86-10.50 0.50
Bromochloromethane ND ug/L 1 10/17/09 01:59 74-97-50.50 0.50
Bromodichloromethane ND ug/L 1 10/17/09 01:59 75-27-40.50 0.50
Bromoform ND ug/L 1 10/17/09 01:59 75-25-20.50 0.50
Bromomethane ND ug/L 1 10/17/09 01:59 74-83-91.0 1.0
n-Butylbenzene ND ug/L 1 10/17/09 01:59 104-51-80.50 0.50
sec-Butylbenzene ND ug/L 1 10/17/09 01:59 135-98-80.50 0.50
tert-Butylbenzene ND ug/L 1 10/17/09 01:59 98-06-60.50 0.50
Carbon tetrachloride ND ug/L 1 10/17/09 01:59 56-23-50.50 0.50
Chlorobenzene ND ug/L 1 10/17/09 01:59 108-90-70.50 0.50
Chloroethane ND ug/L 1 10/17/09 01:59 75-00-31.0 1.0
Chloroform ND ug/L 1 10/17/09 01:59 67-66-30.50 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 6 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9254959
16143 AGROTEC
Sample:MW-1 Lab ID:9254959001 Collected:10/08/09 11:45 Received:10/09/09 16:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
Chloromethane ND ug/L 1 10/17/09 01:59 74-87-31.0 1.0
2-Chlorotoluene ND ug/L 1 10/17/09 01:59 95-49-80.50 0.50
4-Chlorotoluene ND ug/L 1 10/17/09 01:59 106-43-40.50 0.50
1,2-Dibromo-3-chloropropane ND ug/L 1 10/17/09 01:59 96-12-81.0 1.0
Dibromochloromethane ND ug/L 1 10/17/09 01:59 124-48-10.50 0.50
1,2-Dibromoethane (EDB)ND ug/L 1 10/17/09 01:59 106-93-40.50 0.50
Dibromomethane ND ug/L 1 10/17/09 01:59 74-95-30.50 0.50
1,2-Dichlorobenzene ND ug/L 1 10/17/09 01:59 95-50-10.50 0.50
1,3-Dichlorobenzene ND ug/L 1 10/17/09 01:59 541-73-10.50 0.50
1,4-Dichlorobenzene ND ug/L 1 10/17/09 01:59 106-46-70.50 0.50
Dichlorodifluoromethane ND ug/L 1 10/17/09 01:59 75-71-80.50 0.50
1,1-Dichloroethane ND ug/L 1 10/17/09 01:59 75-34-30.50 0.50
1,2-Dichloroethane ND ug/L 1 10/17/09 01:59 107-06-20.50 0.50
1,1-Dichloroethene ND ug/L 1 10/17/09 01:59 75-35-40.50 0.50
cis-1,2-Dichloroethene ND ug/L 1 10/17/09 01:59 156-59-20.50 0.50
trans-1,2-Dichloroethene ND ug/L 1 10/17/09 01:59 156-60-50.50 0.50
1,2-Dichloropropane ND ug/L 1 10/17/09 01:59 78-87-50.50 0.50
1,3-Dichloropropane ND ug/L 1 10/17/09 01:59 142-28-90.50 0.50
2,2-Dichloropropane ND ug/L 1 10/17/09 01:59 594-20-70.50 0.50
1,1-Dichloropropene ND ug/L 1 10/17/09 01:59 563-58-60.50 0.50
cis-1,3-Dichloropropene ND ug/L 1 10/17/09 01:59 10061-01-50.50 0.50
trans-1,3-Dichloropropene ND ug/L 1 10/17/09 01:59 10061-02-60.50 0.50
Diisopropyl ether ND ug/L 1 10/17/09 01:59 108-20-30.50 0.50
Ethylbenzene ND ug/L 1 10/17/09 01:59 100-41-40.50 0.50
Hexachloro-1,3-butadiene ND ug/L 1 10/17/09 01:59 87-68-32.0 2.0
Isopropylbenzene (Cumene)ND ug/L 1 10/17/09 01:59 98-82-80.50 0.50
Methylene Chloride ND ug/L 1 10/17/09 01:59 75-09-22.0 2.0
Methyl-tert-butyl ether ND ug/L 1 10/17/09 01:59 1634-04-40.50 0.50
Naphthalene ND ug/L 1 10/17/09 01:59 91-20-32.0 2.0
n-Propylbenzene ND ug/L 1 10/17/09 01:59 103-65-10.50 0.50
Styrene ND ug/L 1 10/17/09 01:59 100-42-50.50 0.50
1,1,1,2-Tetrachloroethane ND ug/L 1 10/17/09 01:59 630-20-60.50 0.50
1,1,2,2-Tetrachloroethane ND ug/L 1 10/17/09 01:59 79-34-50.50 0.50
Tetrachloroethene ND ug/L 1 10/17/09 01:59 127-18-40.50 0.50
Toluene ND ug/L 1 10/17/09 01:59 108-88-30.50 0.50
1,2,3-Trichlorobenzene ND ug/L 1 10/17/09 01:59 87-61-62.0 2.0
1,2,4-Trichlorobenzene ND ug/L 1 10/17/09 01:59 120-82-12.0 2.0
1,1,1-Trichloroethane ND ug/L 1 10/17/09 01:59 71-55-60.50 0.50
1,1,2-Trichloroethane ND ug/L 1 10/17/09 01:59 79-00-50.50 0.50
Trichloroethene ND ug/L 1 10/17/09 01:59 79-01-60.50 0.50
Trichlorofluoromethane ND ug/L 1 10/17/09 01:59 75-69-41.0 1.0
1,2,3-Trichloropropane ND ug/L 1 10/17/09 01:59 96-18-40.50 0.50
1,2,4-Trimethylbenzene ND ug/L 1 10/17/09 01:59 95-63-60.50 0.50
1,3,5-Trimethylbenzene ND ug/L 1 10/17/09 01:59 108-67-80.50 0.50
Vinyl chloride ND ug/L 1 10/17/09 01:59 75-01-41.0 1.0
m&p-Xylene ND ug/L 1 10/17/09 01:59 1330-20-71.0 1.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 7 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9254959
16143 AGROTEC
Sample:MW-1 Lab ID:9254959001 Collected:10/08/09 11:45 Received:10/09/09 16:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
o-Xylene ND ug/L 1 10/17/09 01:59 95-47-60.50 0.50
1,2-Dichloroethane-d4 (S)102 %1 10/17/09 01:59 17060-07-070-130
Dibromofluoromethane (S)110 %1 10/17/09 01:59 1868-53-770-130
4-Bromofluorobenzene (S)99 %1 10/17/09 01:59 460-00-470-130
Toluene-d8 (S)99 %1 10/17/09 01:59 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 8 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9254959
16143 AGROTEC
Sample:WSW-1 Lab ID:9254959002 Collected:10/08/09 12:00 Received:10/09/09 16:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
MADEP EPH NC Water Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)ND ug/L 1 10/14/09 21:4410/13/09 08:00100100
Aliphatic (C19-C36)ND ug/L 1 10/14/09 21:4410/13/09 08:00100100
Aromatic (C11-C22)ND ug/L 1 10/15/09 21:4310/13/09 08:00100100
Nonatriacontane (S)76 %1 10/14/09 21:44 7194-86-710/13/09 08:0040-140
o-Terphenyl (S)59 %1 10/15/09 21:43 84-15-110/13/09 08:0040-140
2-Fluorobiphenyl (S)76 %1 10/15/09 21:43 321-60-810/13/09 08:0040-140
2-Bromonaphthalene (S)84 %1 10/15/09 21:43 580-13-210/13/09 08:0040-140
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)ND ug/L 1 10/20/09 18:01100100
Aliphatic (C09-C12)ND ug/L 1 10/20/09 18:01100100
Aromatic (C09-C10)ND ug/L 1 10/20/09 18:01100100
2,5-Dibromotoluene (PID)(S)77 %1 10/20/09 18:0170-130
2,5-Dibromotoluene (FID)(S)89 %1 10/20/09 18:0170-130
200.7 MET ICP, 3030C Analytical Method: EPA 200.7 Preparation Method: SM 3030C
Lead ND ug/L 1 10/13/09 04:16 7439-92-110/11/09 09:405.0 4.0
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
Acenaphthene ND ug/L 1 10/21/09 05:22 83-32-910/13/09 11:155.7 3.2
Acenaphthylene ND ug/L 1 10/21/09 05:22 208-96-810/13/09 11:155.7 3.2
Anthracene ND ug/L 1 10/21/09 05:22 120-12-710/13/09 11:155.7 3.3
Benzo(a)anthracene ND ug/L 1 10/21/09 05:22 56-55-310/13/09 11:155.7 3.2
Benzo(a)pyrene ND ug/L 1 10/21/09 05:22 50-32-810/13/09 11:155.7 3.6
Benzo(b)fluoranthene ND ug/L 1 10/21/09 05:22 205-99-210/13/09 11:155.7 4.1
Benzo(g,h,i)perylene ND ug/L 1 10/21/09 05:22 191-24-210/13/09 11:155.7 3.6
Benzo(k)fluoranthene ND ug/L 1 10/21/09 05:22 207-08-910/13/09 11:155.7 3.4
4-Bromophenylphenyl ether ND ug/L 1 10/21/09 05:22 101-55-310/13/09 11:155.7 2.8
Butylbenzylphthalate ND ug/L 1 10/21/09 05:22 85-68-710/13/09 11:155.7 3.3
4-Chloro-3-methylphenol ND ug/L 1 10/21/09 05:22 59-50-710/13/09 11:155.7 3.2
bis(2-Chloroethoxy)methane ND ug/L 1 10/21/09 05:22 111-91-110/13/09 11:1511.5 6.7
bis(2-Chloroethyl) ether ND ug/L 1 10/21/09 05:22 111-44-410/13/09 11:155.7 5.5
bis(2-Chloroisopropyl) ether ND ug/L 1 10/21/09 05:22 108-60-110/13/09 11:155.7 4.6
2-Chloronaphthalene ND ug/L 1 10/21/09 05:22 91-58-710/13/09 11:155.7 4.1
2-Chlorophenol ND ug/L 1 10/21/09 05:22 95-57-810/13/09 11:155.7 5.1
4-Chlorophenylphenyl ether ND ug/L 1 10/21/09 05:22 7005-72-310/13/09 11:155.7 3.1
Chrysene ND ug/L 1 10/21/09 05:22 218-01-910/13/09 11:155.7 3.1
Dibenz(a,h)anthracene ND ug/L 1 10/21/09 05:22 53-70-310/13/09 11:155.7 3.3
3,3'-Dichlorobenzidine ND ug/L 1 10/21/09 05:22 91-94-110/13/09 11:155.7 3.9
2,4-Dichlorophenol ND ug/L 1 10/21/09 05:22 120-83-210/13/09 11:155.7 4.7
Diethylphthalate ND ug/L 1 10/21/09 05:22 84-66-210/13/09 11:155.7 3.1
2,4-Dimethylphenol ND ug/L 1 10/21/09 05:22 105-67-910/13/09 11:1511.5 6.4
Dimethylphthalate ND ug/L 1 10/21/09 05:22 131-11-310/13/09 11:155.7 2.8
Di-n-butylphthalate ND ug/L 1 10/21/09 05:22 84-74-210/13/09 11:155.7 3.3
4,6-Dinitro-2-methylphenol ND ug/L 1 10/21/09 05:22 534-52-110/13/09 11:1523.0 9.0
2,4-Dinitrophenol ND ug/L 1 10/21/09 05:22 51-28-510/13/09 11:1557.5 11.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 9 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9254959
16143 AGROTEC
Sample:WSW-1 Lab ID:9254959002 Collected:10/08/09 12:00 Received:10/09/09 16:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
2,4-Dinitrotoluene ND ug/L 1 10/21/09 05:22 121-14-210/13/09 11:155.7 3.0
2,6-Dinitrotoluene ND ug/L 1 10/21/09 05:22 606-20-210/13/09 11:155.7 3.2
Di-n-octylphthalate ND ug/L 1 10/21/09 05:22 117-84-010/13/09 11:155.7 3.3
bis(2-Ethylhexyl)phthalate ND ug/L 1 10/21/09 05:22 117-81-710/13/09 11:155.7 2.4
Fluoranthene ND ug/L 1 10/21/09 05:22 206-44-010/13/09 11:155.7 3.3
Fluorene ND ug/L 1 10/21/09 05:22 86-73-710/13/09 11:155.7 3.0
Hexachloro-1,3-butadiene ND ug/L 1 10/21/09 05:22 87-68-310/13/09 11:155.7 3.8
Hexachlorobenzene ND ug/L 1 10/21/09 05:22 118-74-110/13/09 11:155.7 3.0
Hexachlorocyclopentadiene ND ug/L 1 10/21/09 05:22 77-47-410/13/09 11:1511.5 4.3
Hexachloroethane ND ug/L 1 10/21/09 05:22 67-72-110/13/09 11:155.7 3.8
Indeno(1,2,3-cd)pyrene ND ug/L 1 10/21/09 05:22 193-39-510/13/09 11:155.7 3.4
Isophorone ND ug/L 1 10/21/09 05:22 78-59-110/13/09 11:1511.5 7.5
Naphthalene ND ug/L 1 10/21/09 05:22 91-20-310/13/09 11:155.7 4.4
Nitrobenzene ND ug/L 1 10/21/09 05:22 98-95-310/13/09 11:155.7 5.1
2-Nitrophenol ND ug/L 1 10/21/09 05:22 88-75-510/13/09 11:155.7 5.3
4-Nitrophenol ND ug/L 1 10/21/09 05:22 100-02-710/13/09 11:1557.5 2.3
N-Nitrosodimethylamine ND ug/L 1 10/21/09 05:22 62-75-910/13/09 11:155.7 3.6
N-Nitroso-di-n-propylamine ND ug/L 1 10/21/09 05:22 621-64-710/13/09 11:155.7 4.3
N-Nitrosodiphenylamine ND ug/L 1 10/21/09 05:22 86-30-610/13/09 11:1511.5 7.6
Pentachlorophenol ND ug/L 1 10/21/09 05:22 87-86-510/13/09 11:1528.7 1.8
Phenanthrene ND ug/L 1 10/21/09 05:22 85-01-810/13/09 11:155.7 3.1
Phenol ND ug/L 1 10/21/09 05:22 108-95-210/13/09 11:155.7 2.1
Pyrene ND ug/L 1 10/21/09 05:22 129-00-010/13/09 11:155.7 3.3
1,2,4-Trichlorobenzene ND ug/L 1 10/21/09 05:22 120-82-110/13/09 11:155.7 3.9
2,4,6-Trichlorophenol ND ug/L 1 10/21/09 05:22 88-06-210/13/09 11:1511.5 7.0
Nitrobenzene-d5 (S)47 %1 10/21/09 05:22 4165-60-010/13/09 11:1510-120
2-Fluorobiphenyl (S)42 %1 10/21/09 05:22 321-60-810/13/09 11:1515-120
Terphenyl-d14 (S)69 %1 10/21/09 05:22 1718-51-010/13/09 11:1511-131
Phenol-d6 (S)20 %1 10/21/09 05:22 13127-88-310/13/09 11:1510-120
2-Fluorophenol (S)29 %1 10/21/09 05:22 367-12-410/13/09 11:1510-120
2,4,6-Tribromophenol (S)54 %1 10/21/09 05:22 118-79-610/13/09 11:1510-137
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 10/17/09 02:22 71-43-20.50 0.50
Bromobenzene ND ug/L 1 10/17/09 02:22 108-86-10.50 0.50
Bromochloromethane ND ug/L 1 10/17/09 02:22 74-97-50.50 0.50
Bromodichloromethane ND ug/L 1 10/17/09 02:22 75-27-40.50 0.50
Bromoform ND ug/L 1 10/17/09 02:22 75-25-20.50 0.50
Bromomethane ND ug/L 1 10/17/09 02:22 74-83-91.0 1.0
n-Butylbenzene ND ug/L 1 10/17/09 02:22 104-51-80.50 0.50
sec-Butylbenzene ND ug/L 1 10/17/09 02:22 135-98-80.50 0.50
tert-Butylbenzene ND ug/L 1 10/17/09 02:22 98-06-60.50 0.50
Carbon tetrachloride ND ug/L 1 10/17/09 02:22 56-23-50.50 0.50
Chlorobenzene ND ug/L 1 10/17/09 02:22 108-90-70.50 0.50
Chloroethane ND ug/L 1 10/17/09 02:22 75-00-31.0 1.0
Chloroform ND ug/L 1 10/17/09 02:22 67-66-30.50 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 10 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9254959
16143 AGROTEC
Sample:WSW-1 Lab ID:9254959002 Collected:10/08/09 12:00 Received:10/09/09 16:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
Chloromethane ND ug/L 1 10/17/09 02:22 74-87-31.0 1.0
2-Chlorotoluene ND ug/L 1 10/17/09 02:22 95-49-80.50 0.50
4-Chlorotoluene ND ug/L 1 10/17/09 02:22 106-43-40.50 0.50
1,2-Dibromo-3-chloropropane ND ug/L 1 10/17/09 02:22 96-12-81.0 1.0
Dibromochloromethane ND ug/L 1 10/17/09 02:22 124-48-10.50 0.50
1,2-Dibromoethane (EDB)ND ug/L 1 10/17/09 02:22 106-93-40.50 0.50
Dibromomethane ND ug/L 1 10/17/09 02:22 74-95-30.50 0.50
1,2-Dichlorobenzene ND ug/L 1 10/17/09 02:22 95-50-10.50 0.50
1,3-Dichlorobenzene ND ug/L 1 10/17/09 02:22 541-73-10.50 0.50
1,4-Dichlorobenzene ND ug/L 1 10/17/09 02:22 106-46-70.50 0.50
Dichlorodifluoromethane ND ug/L 1 10/17/09 02:22 75-71-80.50 0.50
1,1-Dichloroethane ND ug/L 1 10/17/09 02:22 75-34-30.50 0.50
1,2-Dichloroethane ND ug/L 1 10/17/09 02:22 107-06-20.50 0.50
1,1-Dichloroethene ND ug/L 1 10/17/09 02:22 75-35-40.50 0.50
cis-1,2-Dichloroethene ND ug/L 1 10/17/09 02:22 156-59-20.50 0.50
trans-1,2-Dichloroethene ND ug/L 1 10/17/09 02:22 156-60-50.50 0.50
1,2-Dichloropropane ND ug/L 1 10/17/09 02:22 78-87-50.50 0.50
1,3-Dichloropropane ND ug/L 1 10/17/09 02:22 142-28-90.50 0.50
2,2-Dichloropropane ND ug/L 1 10/17/09 02:22 594-20-70.50 0.50
1,1-Dichloropropene ND ug/L 1 10/17/09 02:22 563-58-60.50 0.50
cis-1,3-Dichloropropene ND ug/L 1 10/17/09 02:22 10061-01-50.50 0.50
trans-1,3-Dichloropropene ND ug/L 1 10/17/09 02:22 10061-02-60.50 0.50
Diisopropyl ether ND ug/L 1 10/17/09 02:22 108-20-30.50 0.50
Ethylbenzene ND ug/L 1 10/17/09 02:22 100-41-40.50 0.50
Hexachloro-1,3-butadiene ND ug/L 1 10/17/09 02:22 87-68-32.0 2.0
Isopropylbenzene (Cumene)ND ug/L 1 10/17/09 02:22 98-82-80.50 0.50
Methylene Chloride ND ug/L 1 10/17/09 02:22 75-09-22.0 2.0
Methyl-tert-butyl ether ND ug/L 1 10/17/09 02:22 1634-04-40.50 0.50
Naphthalene ND ug/L 1 10/17/09 02:22 91-20-32.0 2.0
n-Propylbenzene ND ug/L 1 10/17/09 02:22 103-65-10.50 0.50
Styrene ND ug/L 1 10/17/09 02:22 100-42-50.50 0.50
1,1,1,2-Tetrachloroethane ND ug/L 1 10/17/09 02:22 630-20-60.50 0.50
1,1,2,2-Tetrachloroethane ND ug/L 1 10/17/09 02:22 79-34-50.50 0.50
Tetrachloroethene ND ug/L 1 10/17/09 02:22 127-18-40.50 0.50
Toluene ND ug/L 1 10/17/09 02:22 108-88-30.50 0.50
1,2,3-Trichlorobenzene ND ug/L 1 10/17/09 02:22 87-61-62.0 2.0
1,2,4-Trichlorobenzene ND ug/L 1 10/17/09 02:22 120-82-12.0 2.0
1,1,1-Trichloroethane ND ug/L 1 10/17/09 02:22 71-55-60.50 0.50
1,1,2-Trichloroethane ND ug/L 1 10/17/09 02:22 79-00-50.50 0.50
Trichloroethene ND ug/L 1 10/17/09 02:22 79-01-60.50 0.50
Trichlorofluoromethane ND ug/L 1 10/17/09 02:22 75-69-41.0 1.0
1,2,3-Trichloropropane ND ug/L 1 10/17/09 02:22 96-18-40.50 0.50
1,2,4-Trimethylbenzene ND ug/L 1 10/17/09 02:22 95-63-60.50 0.50
1,3,5-Trimethylbenzene ND ug/L 1 10/17/09 02:22 108-67-80.50 0.50
Vinyl chloride ND ug/L 1 10/17/09 02:22 75-01-41.0 1.0
m&p-Xylene ND ug/L 1 10/17/09 02:22 1330-20-71.0 1.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 11 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9254959
16143 AGROTEC
Sample:WSW-1 Lab ID:9254959002 Collected:10/08/09 12:00 Received:10/09/09 16:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
o-Xylene ND ug/L 1 10/17/09 02:22 95-47-60.50 0.50
1,2-Dichloroethane-d4 (S)103 %1 10/17/09 02:22 17060-07-070-130
Dibromofluoromethane (S)109 %1 10/17/09 02:22 1868-53-770-130
4-Bromofluorobenzene (S)100 %1 10/17/09 02:22 460-00-470-130
Toluene-d8 (S)101 %1 10/17/09 02:22 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 12 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9254959
16143 AGROTEC
Sample:WSW-2 Lab ID:9254959003 Collected:10/08/09 12:30 Received:10/09/09 16:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
MADEP EPH NC Water Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)ND ug/L 1 10/14/09 22:1710/13/09 08:00100100
Aliphatic (C19-C36)ND ug/L 1 10/14/09 22:1710/13/09 08:00100100
Aromatic (C11-C22)ND ug/L 1 10/15/09 22:1710/13/09 08:00100100
Nonatriacontane (S)82 %1 10/14/09 22:17 7194-86-710/13/09 08:0040-140
o-Terphenyl (S)85 %1 10/15/09 22:17 84-15-110/13/09 08:0040-140
2-Fluorobiphenyl (S)93 %1 10/15/09 22:17 321-60-810/13/09 08:0040-140
2-Bromonaphthalene (S)91 %1 10/15/09 22:17 580-13-210/13/09 08:0040-140
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)ND ug/L 1 10/20/09 18:25100100
Aliphatic (C09-C12)ND ug/L 1 10/20/09 18:25100100
Aromatic (C09-C10)ND ug/L 1 10/20/09 18:25100100
2,5-Dibromotoluene (PID)(S)65 %1 10/20/09 18:25 S070-130
2,5-Dibromotoluene (FID)(S)78 %1 10/20/09 18:2570-130
200.7 MET ICP, 3030C Analytical Method: EPA 200.7 Preparation Method: SM 3030C
Lead ND ug/L 1 10/13/09 04:34 7439-92-110/11/09 09:405.0 4.0
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
Acenaphthene ND ug/L 1 10/21/09 05:48 83-32-910/13/09 11:155.0 2.8
Acenaphthylene ND ug/L 1 10/21/09 05:48 208-96-810/13/09 11:155.0 2.8
Anthracene ND ug/L 1 10/21/09 05:48 120-12-710/13/09 11:155.0 2.9
Benzo(a)anthracene ND ug/L 1 10/21/09 05:48 56-55-310/13/09 11:155.0 2.8
Benzo(a)pyrene ND ug/L 1 10/21/09 05:48 50-32-810/13/09 11:155.0 3.1
Benzo(b)fluoranthene ND ug/L 1 10/21/09 05:48 205-99-210/13/09 11:155.0 3.6
Benzo(g,h,i)perylene ND ug/L 1 10/21/09 05:48 191-24-210/13/09 11:155.0 3.1
Benzo(k)fluoranthene ND ug/L 1 10/21/09 05:48 207-08-910/13/09 11:155.0 3.0
4-Bromophenylphenyl ether ND ug/L 1 10/21/09 05:48 101-55-310/13/09 11:155.0 2.4
Butylbenzylphthalate ND ug/L 1 10/21/09 05:48 85-68-710/13/09 11:155.0 2.9
4-Chloro-3-methylphenol ND ug/L 1 10/21/09 05:48 59-50-710/13/09 11:155.0 2.8
bis(2-Chloroethoxy)methane ND ug/L 1 10/21/09 05:48 111-91-110/13/09 11:1510.0 5.8
bis(2-Chloroethyl) ether ND ug/L 1 10/21/09 05:48 111-44-410/13/09 11:155.0 4.8
bis(2-Chloroisopropyl) ether ND ug/L 1 10/21/09 05:48 108-60-110/13/09 11:155.0 4.0
2-Chloronaphthalene ND ug/L 1 10/21/09 05:48 91-58-710/13/09 11:155.0 3.6
2-Chlorophenol ND ug/L 1 10/21/09 05:48 95-57-810/13/09 11:155.0 4.4
4-Chlorophenylphenyl ether ND ug/L 1 10/21/09 05:48 7005-72-310/13/09 11:155.0 2.7
Chrysene ND ug/L 1 10/21/09 05:48 218-01-910/13/09 11:155.0 2.7
Dibenz(a,h)anthracene ND ug/L 1 10/21/09 05:48 53-70-310/13/09 11:155.0 2.9
3,3'-Dichlorobenzidine ND ug/L 1 10/21/09 05:48 91-94-110/13/09 11:155.0 3.4
2,4-Dichlorophenol ND ug/L 1 10/21/09 05:48 120-83-210/13/09 11:155.0 4.1
Diethylphthalate ND ug/L 1 10/21/09 05:48 84-66-210/13/09 11:155.0 2.7
2,4-Dimethylphenol ND ug/L 1 10/21/09 05:48 105-67-910/13/09 11:1510.0 5.6
Dimethylphthalate ND ug/L 1 10/21/09 05:48 131-11-310/13/09 11:155.0 2.4
Di-n-butylphthalate ND ug/L 1 10/21/09 05:48 84-74-210/13/09 11:155.0 2.9
4,6-Dinitro-2-methylphenol ND ug/L 1 10/21/09 05:48 534-52-110/13/09 11:1520.0 7.8
2,4-Dinitrophenol ND ug/L 1 10/21/09 05:48 51-28-510/13/09 11:1550.0 10.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 13 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9254959
16143 AGROTEC
Sample:WSW-2 Lab ID:9254959003 Collected:10/08/09 12:30 Received:10/09/09 16:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
2,4-Dinitrotoluene ND ug/L 1 10/21/09 05:48 121-14-210/13/09 11:155.0 2.6
2,6-Dinitrotoluene ND ug/L 1 10/21/09 05:48 606-20-210/13/09 11:155.0 2.8
Di-n-octylphthalate ND ug/L 1 10/21/09 05:48 117-84-010/13/09 11:155.0 2.9
bis(2-Ethylhexyl)phthalate ND ug/L 1 10/21/09 05:48 117-81-710/13/09 11:155.0 2.1
Fluoranthene ND ug/L 1 10/21/09 05:48 206-44-010/13/09 11:155.0 2.9
Fluorene ND ug/L 1 10/21/09 05:48 86-73-710/13/09 11:155.0 2.6
Hexachloro-1,3-butadiene ND ug/L 1 10/21/09 05:48 87-68-310/13/09 11:155.0 3.3
Hexachlorobenzene ND ug/L 1 10/21/09 05:48 118-74-110/13/09 11:155.0 2.6
Hexachlorocyclopentadiene ND ug/L 1 10/21/09 05:48 77-47-410/13/09 11:1510.0 3.7
Hexachloroethane ND ug/L 1 10/21/09 05:48 67-72-110/13/09 11:155.0 3.3
Indeno(1,2,3-cd)pyrene ND ug/L 1 10/21/09 05:48 193-39-510/13/09 11:155.0 3.0
Isophorone ND ug/L 1 10/21/09 05:48 78-59-110/13/09 11:1510.0 6.5
Naphthalene ND ug/L 1 10/21/09 05:48 91-20-310/13/09 11:155.0 3.8
Nitrobenzene ND ug/L 1 10/21/09 05:48 98-95-310/13/09 11:155.0 4.4
2-Nitrophenol ND ug/L 1 10/21/09 05:48 88-75-510/13/09 11:155.0 4.6
4-Nitrophenol ND ug/L 1 10/21/09 05:48 100-02-710/13/09 11:1550.0 2.0
N-Nitrosodimethylamine ND ug/L 1 10/21/09 05:48 62-75-910/13/09 11:155.0 3.1
N-Nitroso-di-n-propylamine ND ug/L 1 10/21/09 05:48 621-64-710/13/09 11:155.0 3.7
N-Nitrosodiphenylamine ND ug/L 1 10/21/09 05:48 86-30-610/13/09 11:1510.0 6.6
Pentachlorophenol ND ug/L 1 10/21/09 05:48 87-86-510/13/09 11:1525.0 1.6
Phenanthrene ND ug/L 1 10/21/09 05:48 85-01-810/13/09 11:155.0 2.7
Phenol ND ug/L 1 10/21/09 05:48 108-95-210/13/09 11:155.0 1.8
Pyrene ND ug/L 1 10/21/09 05:48 129-00-010/13/09 11:155.0 2.9
1,2,4-Trichlorobenzene ND ug/L 1 10/21/09 05:48 120-82-110/13/09 11:155.0 3.4
2,4,6-Trichlorophenol ND ug/L 1 10/21/09 05:48 88-06-210/13/09 11:1510.0 6.1
Nitrobenzene-d5 (S)44 %1 10/21/09 05:48 4165-60-010/13/09 11:1510-120
2-Fluorobiphenyl (S)51 %1 10/21/09 05:48 321-60-810/13/09 11:1515-120
Terphenyl-d14 (S)129 %1 10/21/09 05:48 1718-51-010/13/09 11:1511-131
Phenol-d6 (S)2 %1 10/21/09 05:48 13127-88-3 S010/13/09 11:1510-120
2-Fluorophenol (S)23 %1 10/21/09 05:48 367-12-410/13/09 11:1510-120
2,4,6-Tribromophenol (S)91 %1 10/21/09 05:48 118-79-610/13/09 11:1510-137
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 10/15/09 20:45 71-43-20.50 0.50
Bromobenzene ND ug/L 1 10/15/09 20:45 108-86-10.50 0.50
Bromochloromethane ND ug/L 1 10/15/09 20:45 74-97-50.50 0.50
Bromodichloromethane 1.5 ug/L 1 10/15/09 20:45 75-27-40.50 0.50
Bromoform ND ug/L 1 10/15/09 20:45 75-25-20.50 0.50
Bromomethane ND ug/L 1 10/15/09 20:45 74-83-91.0 1.0
n-Butylbenzene ND ug/L 1 10/15/09 20:45 104-51-80.50 0.50
sec-Butylbenzene ND ug/L 1 10/15/09 20:45 135-98-80.50 0.50
tert-Butylbenzene ND ug/L 1 10/15/09 20:45 98-06-60.50 0.50
Carbon tetrachloride ND ug/L 1 10/15/09 20:45 56-23-50.50 0.50
Chlorobenzene ND ug/L 1 10/15/09 20:45 108-90-70.50 0.50
Chloroethane ND ug/L 1 10/15/09 20:45 75-00-31.0 1.0
Chloroform 0.90 ug/L 1 10/15/09 20:45 67-66-30.50 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 14 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9254959
16143 AGROTEC
Sample:WSW-2 Lab ID:9254959003 Collected:10/08/09 12:30 Received:10/09/09 16:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
Chloromethane ND ug/L 1 10/15/09 20:45 74-87-31.0 1.0
2-Chlorotoluene ND ug/L 1 10/15/09 20:45 95-49-80.50 0.50
4-Chlorotoluene ND ug/L 1 10/15/09 20:45 106-43-40.50 0.50
1,2-Dibromo-3-chloropropane ND ug/L 1 10/15/09 20:45 96-12-81.0 1.0
Dibromochloromethane 1.8 ug/L 1 10/15/09 20:45 124-48-10.50 0.50
1,2-Dibromoethane (EDB)ND ug/L 1 10/15/09 20:45 106-93-40.50 0.50
Dibromomethane ND ug/L 1 10/15/09 20:45 74-95-30.50 0.50
1,2-Dichlorobenzene ND ug/L 1 10/15/09 20:45 95-50-10.50 0.50
1,3-Dichlorobenzene ND ug/L 1 10/15/09 20:45 541-73-10.50 0.50
1,4-Dichlorobenzene ND ug/L 1 10/15/09 20:45 106-46-70.50 0.50
Dichlorodifluoromethane ND ug/L 1 10/15/09 20:45 75-71-80.50 0.50
1,1-Dichloroethane ND ug/L 1 10/15/09 20:45 75-34-30.50 0.50
1,2-Dichloroethane ND ug/L 1 10/15/09 20:45 107-06-20.50 0.50
1,1-Dichloroethene ND ug/L 1 10/15/09 20:45 75-35-40.50 0.50
cis-1,2-Dichloroethene ND ug/L 1 10/15/09 20:45 156-59-20.50 0.50
trans-1,2-Dichloroethene ND ug/L 1 10/15/09 20:45 156-60-50.50 0.50
1,2-Dichloropropane ND ug/L 1 10/15/09 20:45 78-87-50.50 0.50
1,3-Dichloropropane ND ug/L 1 10/15/09 20:45 142-28-90.50 0.50
2,2-Dichloropropane ND ug/L 1 10/15/09 20:45 594-20-70.50 0.50
1,1-Dichloropropene ND ug/L 1 10/15/09 20:45 563-58-60.50 0.50
cis-1,3-Dichloropropene ND ug/L 1 10/15/09 20:45 10061-01-50.50 0.50
trans-1,3-Dichloropropene ND ug/L 1 10/15/09 20:45 10061-02-60.50 0.50
Diisopropyl ether ND ug/L 1 10/15/09 20:45 108-20-30.50 0.50
Ethylbenzene ND ug/L 1 10/15/09 20:45 100-41-40.50 0.50
Hexachloro-1,3-butadiene ND ug/L 1 10/15/09 20:45 87-68-32.0 2.0
Isopropylbenzene (Cumene)ND ug/L 1 10/15/09 20:45 98-82-80.50 0.50
Methylene Chloride ND ug/L 1 10/15/09 20:45 75-09-22.0 2.0
Methyl-tert-butyl ether ND ug/L 1 10/15/09 20:45 1634-04-40.50 0.50
Naphthalene ND ug/L 1 10/15/09 20:45 91-20-32.0 2.0
n-Propylbenzene ND ug/L 1 10/15/09 20:45 103-65-10.50 0.50
Styrene ND ug/L 1 10/15/09 20:45 100-42-50.50 0.50
1,1,1,2-Tetrachloroethane ND ug/L 1 10/15/09 20:45 630-20-60.50 0.50
1,1,2,2-Tetrachloroethane ND ug/L 1 10/15/09 20:45 79-34-50.50 0.50
Tetrachloroethene ND ug/L 1 10/15/09 20:45 127-18-40.50 0.50
Toluene ND ug/L 1 10/15/09 20:45 108-88-30.50 0.50
1,2,3-Trichlorobenzene ND ug/L 1 10/15/09 20:45 87-61-62.0 2.0
1,2,4-Trichlorobenzene ND ug/L 1 10/15/09 20:45 120-82-12.0 2.0
1,1,1-Trichloroethane ND ug/L 1 10/15/09 20:45 71-55-60.50 0.50
1,1,2-Trichloroethane ND ug/L 1 10/15/09 20:45 79-00-50.50 0.50
Trichloroethene ND ug/L 1 10/15/09 20:45 79-01-60.50 0.50
Trichlorofluoromethane ND ug/L 1 10/15/09 20:45 75-69-41.0 1.0
1,2,3-Trichloropropane ND ug/L 1 10/15/09 20:45 96-18-40.50 0.50
1,2,4-Trimethylbenzene ND ug/L 1 10/15/09 20:45 95-63-60.50 0.50
1,3,5-Trimethylbenzene ND ug/L 1 10/15/09 20:45 108-67-80.50 0.50
Vinyl chloride ND ug/L 1 10/15/09 20:45 75-01-41.0 1.0
m&p-Xylene ND ug/L 1 10/15/09 20:45 1330-20-71.0 1.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 15 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9254959
16143 AGROTEC
Sample:WSW-2 Lab ID:9254959003 Collected:10/08/09 12:30 Received:10/09/09 16:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
o-Xylene ND ug/L 1 10/15/09 20:45 95-47-60.50 0.50
1,2-Dichloroethane-d4 (S)91 %1 10/15/09 20:45 17060-07-070-130
Dibromofluoromethane (S)98 %1 10/15/09 20:45 1868-53-770-130
4-Bromofluorobenzene (S)109 %1 10/15/09 20:45 460-00-470-130
Toluene-d8 (S)92 %1 10/15/09 20:45 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 16 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9254959
16143 AGROTEC
Sample:WSW-3 Lab ID:9254959004 Collected:10/08/09 13:20 Received:10/09/09 16:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
MADEP EPH NC Water Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)ND ug/L 1 10/14/09 22:5010/13/09 08:00143143
Aliphatic (C19-C36)ND ug/L 1 10/14/09 22:5010/13/09 08:00143143
Aromatic (C11-C22)ND ug/L 1 10/15/09 22:5010/13/09 08:00143143
Nonatriacontane (S)79 %1 10/14/09 22:50 7194-86-710/13/09 08:0040-140
o-Terphenyl (S)92 %1 10/15/09 22:50 84-15-110/13/09 08:0040-140
2-Fluorobiphenyl (S)102 %1 10/15/09 22:50 321-60-810/13/09 08:0040-140
2-Bromonaphthalene (S)103 %1 10/15/09 22:50 580-13-210/13/09 08:0040-140
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)ND ug/L 1 10/20/09 18:49100100
Aliphatic (C09-C12)ND ug/L 1 10/20/09 18:49100100
Aromatic (C09-C10)ND ug/L 1 10/20/09 18:49100100
2,5-Dibromotoluene (PID)(S)75 %1 10/20/09 18:4970-130
2,5-Dibromotoluene (FID)(S)87 %1 10/20/09 18:4970-130
200.7 MET ICP, 3030C Analytical Method: EPA 200.7 Preparation Method: SM 3030C
Lead 6.2 ug/L 1 10/13/09 04:42 7439-92-110/11/09 09:405.0 4.0
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
Acenaphthene ND ug/L 1 10/21/09 06:13 83-32-910/13/09 11:156.1 3.4
Acenaphthylene ND ug/L 1 10/21/09 06:13 208-96-810/13/09 11:156.1 3.4
Anthracene ND ug/L 1 10/21/09 06:13 120-12-710/13/09 11:156.1 3.5
Benzo(a)anthracene ND ug/L 1 10/21/09 06:13 56-55-310/13/09 11:156.1 3.4
Benzo(a)pyrene ND ug/L 1 10/21/09 06:13 50-32-810/13/09 11:156.1 3.8
Benzo(b)fluoranthene ND ug/L 1 10/21/09 06:13 205-99-210/13/09 11:156.1 4.4
Benzo(g,h,i)perylene ND ug/L 1 10/21/09 06:13 191-24-210/13/09 11:156.1 3.8
Benzo(k)fluoranthene ND ug/L 1 10/21/09 06:13 207-08-910/13/09 11:156.1 3.7
4-Bromophenylphenyl ether ND ug/L 1 10/21/09 06:13 101-55-310/13/09 11:156.1 2.9
Butylbenzylphthalate ND ug/L 1 10/21/09 06:13 85-68-710/13/09 11:156.1 3.5
4-Chloro-3-methylphenol ND ug/L 1 10/21/09 06:13 59-50-710/13/09 11:156.1 3.4
bis(2-Chloroethoxy)methane ND ug/L 1 10/21/09 06:13 111-91-110/13/09 11:1512.2 7.1
bis(2-Chloroethyl) ether ND ug/L 1 10/21/09 06:13 111-44-410/13/09 11:156.1 5.9
bis(2-Chloroisopropyl) ether ND ug/L 1 10/21/09 06:13 108-60-110/13/09 11:156.1 4.9
2-Chloronaphthalene ND ug/L 1 10/21/09 06:13 91-58-710/13/09 11:156.1 4.4
2-Chlorophenol ND ug/L 1 10/21/09 06:13 95-57-810/13/09 11:156.1 5.4
4-Chlorophenylphenyl ether ND ug/L 1 10/21/09 06:13 7005-72-310/13/09 11:156.1 3.3
Chrysene ND ug/L 1 10/21/09 06:13 218-01-910/13/09 11:156.1 3.3
Dibenz(a,h)anthracene ND ug/L 1 10/21/09 06:13 53-70-310/13/09 11:156.1 3.5
3,3'-Dichlorobenzidine ND ug/L 1 10/21/09 06:13 91-94-110/13/09 11:156.1 4.1
2,4-Dichlorophenol ND ug/L 1 10/21/09 06:13 120-83-210/13/09 11:156.1 5.0
Diethylphthalate ND ug/L 1 10/21/09 06:13 84-66-210/13/09 11:156.1 3.3
2,4-Dimethylphenol ND ug/L 1 10/21/09 06:13 105-67-910/13/09 11:1512.2 6.8
Dimethylphthalate ND ug/L 1 10/21/09 06:13 131-11-310/13/09 11:156.1 2.9
Di-n-butylphthalate ND ug/L 1 10/21/09 06:13 84-74-210/13/09 11:156.1 3.5
4,6-Dinitro-2-methylphenol ND ug/L 1 10/21/09 06:13 534-52-110/13/09 11:1524.4 9.5
2,4-Dinitrophenol ND ug/L 1 10/21/09 06:13 51-28-510/13/09 11:1561.0 12.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 17 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9254959
16143 AGROTEC
Sample:WSW-3 Lab ID:9254959004 Collected:10/08/09 13:20 Received:10/09/09 16:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
2,4-Dinitrotoluene ND ug/L 1 10/21/09 06:13 121-14-210/13/09 11:156.1 3.2
2,6-Dinitrotoluene ND ug/L 1 10/21/09 06:13 606-20-210/13/09 11:156.1 3.4
Di-n-octylphthalate ND ug/L 1 10/21/09 06:13 117-84-010/13/09 11:156.1 3.5
bis(2-Ethylhexyl)phthalate ND ug/L 1 10/21/09 06:13 117-81-710/13/09 11:156.1 2.6
Fluoranthene ND ug/L 1 10/21/09 06:13 206-44-010/13/09 11:156.1 3.5
Fluorene ND ug/L 1 10/21/09 06:13 86-73-710/13/09 11:156.1 3.2
Hexachloro-1,3-butadiene ND ug/L 1 10/21/09 06:13 87-68-310/13/09 11:156.1 4.0
Hexachlorobenzene ND ug/L 1 10/21/09 06:13 118-74-110/13/09 11:156.1 3.2
Hexachlorocyclopentadiene ND ug/L 1 10/21/09 06:13 77-47-410/13/09 11:1512.2 4.5
Hexachloroethane ND ug/L 1 10/21/09 06:13 67-72-110/13/09 11:156.1 4.0
Indeno(1,2,3-cd)pyrene ND ug/L 1 10/21/09 06:13 193-39-510/13/09 11:156.1 3.7
Isophorone ND ug/L 1 10/21/09 06:13 78-59-110/13/09 11:1512.2 7.9
Naphthalene ND ug/L 1 10/21/09 06:13 91-20-310/13/09 11:156.1 4.6
Nitrobenzene ND ug/L 1 10/21/09 06:13 98-95-310/13/09 11:156.1 5.4
2-Nitrophenol ND ug/L 1 10/21/09 06:13 88-75-510/13/09 11:156.1 5.6
4-Nitrophenol ND ug/L 1 10/21/09 06:13 100-02-710/13/09 11:1561.0 2.4
N-Nitrosodimethylamine ND ug/L 1 10/21/09 06:13 62-75-910/13/09 11:156.1 3.8
N-Nitroso-di-n-propylamine ND ug/L 1 10/21/09 06:13 621-64-710/13/09 11:156.1 4.5
N-Nitrosodiphenylamine ND ug/L 1 10/21/09 06:13 86-30-610/13/09 11:1512.2 8.0
Pentachlorophenol ND ug/L 1 10/21/09 06:13 87-86-510/13/09 11:1530.5 2.0
Phenanthrene ND ug/L 1 10/21/09 06:13 85-01-810/13/09 11:156.1 3.3
Phenol ND ug/L 1 10/21/09 06:13 108-95-210/13/09 11:156.1 2.2
Pyrene ND ug/L 1 10/21/09 06:13 129-00-010/13/09 11:156.1 3.5
1,2,4-Trichlorobenzene ND ug/L 1 10/21/09 06:13 120-82-110/13/09 11:156.1 4.1
2,4,6-Trichlorophenol ND ug/L 1 10/21/09 06:13 88-06-210/13/09 11:1512.2 7.4
Nitrobenzene-d5 (S)32 %1 10/21/09 06:13 4165-60-010/13/09 11:1510-120
2-Fluorobiphenyl (S)31 %1 10/21/09 06:13 321-60-810/13/09 11:1515-120
Terphenyl-d14 (S)65 %1 10/21/09 06:13 1718-51-010/13/09 11:1511-131
Phenol-d6 (S)17 %1 10/21/09 06:13 13127-88-310/13/09 11:1510-120
2-Fluorophenol (S)21 %1 10/21/09 06:13 367-12-410/13/09 11:1510-120
2,4,6-Tribromophenol (S)50 %1 10/21/09 06:13 118-79-610/13/09 11:1510-137
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 10/15/09 21:09 71-43-20.50 0.50
Bromobenzene ND ug/L 1 10/15/09 21:09 108-86-10.50 0.50
Bromochloromethane ND ug/L 1 10/15/09 21:09 74-97-50.50 0.50
Bromodichloromethane ND ug/L 1 10/15/09 21:09 75-27-40.50 0.50
Bromoform ND ug/L 1 10/15/09 21:09 75-25-20.50 0.50
Bromomethane ND ug/L 1 10/15/09 21:09 74-83-91.0 1.0
n-Butylbenzene ND ug/L 1 10/15/09 21:09 104-51-80.50 0.50
sec-Butylbenzene ND ug/L 1 10/15/09 21:09 135-98-80.50 0.50
tert-Butylbenzene ND ug/L 1 10/15/09 21:09 98-06-60.50 0.50
Carbon tetrachloride ND ug/L 1 10/15/09 21:09 56-23-50.50 0.50
Chlorobenzene ND ug/L 1 10/15/09 21:09 108-90-70.50 0.50
Chloroethane ND ug/L 1 10/15/09 21:09 75-00-31.0 1.0
Chloroform ND ug/L 1 10/15/09 21:09 67-66-30.50 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 18 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9254959
16143 AGROTEC
Sample:WSW-3 Lab ID:9254959004 Collected:10/08/09 13:20 Received:10/09/09 16:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
Chloromethane ND ug/L 1 10/15/09 21:09 74-87-31.0 1.0
2-Chlorotoluene ND ug/L 1 10/15/09 21:09 95-49-80.50 0.50
4-Chlorotoluene ND ug/L 1 10/15/09 21:09 106-43-40.50 0.50
1,2-Dibromo-3-chloropropane ND ug/L 1 10/15/09 21:09 96-12-81.0 1.0
Dibromochloromethane ND ug/L 1 10/15/09 21:09 124-48-10.50 0.50
1,2-Dibromoethane (EDB)ND ug/L 1 10/15/09 21:09 106-93-40.50 0.50
Dibromomethane ND ug/L 1 10/15/09 21:09 74-95-30.50 0.50
1,2-Dichlorobenzene ND ug/L 1 10/15/09 21:09 95-50-10.50 0.50
1,3-Dichlorobenzene ND ug/L 1 10/15/09 21:09 541-73-10.50 0.50
1,4-Dichlorobenzene ND ug/L 1 10/15/09 21:09 106-46-70.50 0.50
Dichlorodifluoromethane ND ug/L 1 10/15/09 21:09 75-71-80.50 0.50
1,1-Dichloroethane ND ug/L 1 10/15/09 21:09 75-34-30.50 0.50
1,2-Dichloroethane ND ug/L 1 10/15/09 21:09 107-06-20.50 0.50
1,1-Dichloroethene ND ug/L 1 10/15/09 21:09 75-35-40.50 0.50
cis-1,2-Dichloroethene ND ug/L 1 10/15/09 21:09 156-59-20.50 0.50
trans-1,2-Dichloroethene ND ug/L 1 10/15/09 21:09 156-60-50.50 0.50
1,2-Dichloropropane ND ug/L 1 10/15/09 21:09 78-87-50.50 0.50
1,3-Dichloropropane ND ug/L 1 10/15/09 21:09 142-28-90.50 0.50
2,2-Dichloropropane ND ug/L 1 10/15/09 21:09 594-20-70.50 0.50
1,1-Dichloropropene ND ug/L 1 10/15/09 21:09 563-58-60.50 0.50
cis-1,3-Dichloropropene ND ug/L 1 10/15/09 21:09 10061-01-50.50 0.50
trans-1,3-Dichloropropene ND ug/L 1 10/15/09 21:09 10061-02-60.50 0.50
Diisopropyl ether ND ug/L 1 10/15/09 21:09 108-20-30.50 0.50
Ethylbenzene ND ug/L 1 10/15/09 21:09 100-41-40.50 0.50
Hexachloro-1,3-butadiene ND ug/L 1 10/15/09 21:09 87-68-32.0 2.0
Isopropylbenzene (Cumene)ND ug/L 1 10/15/09 21:09 98-82-80.50 0.50
Methylene Chloride ND ug/L 1 10/15/09 21:09 75-09-22.0 2.0
Methyl-tert-butyl ether ND ug/L 1 10/15/09 21:09 1634-04-40.50 0.50
Naphthalene ND ug/L 1 10/15/09 21:09 91-20-32.0 2.0
n-Propylbenzene ND ug/L 1 10/15/09 21:09 103-65-10.50 0.50
Styrene ND ug/L 1 10/15/09 21:09 100-42-50.50 0.50
1,1,1,2-Tetrachloroethane ND ug/L 1 10/15/09 21:09 630-20-60.50 0.50
1,1,2,2-Tetrachloroethane ND ug/L 1 10/15/09 21:09 79-34-50.50 0.50
Tetrachloroethene ND ug/L 1 10/15/09 21:09 127-18-40.50 0.50
Toluene 0.53 ug/L 1 10/15/09 21:09 108-88-30.50 0.50
1,2,3-Trichlorobenzene ND ug/L 1 10/15/09 21:09 87-61-62.0 2.0
1,2,4-Trichlorobenzene ND ug/L 1 10/15/09 21:09 120-82-12.0 2.0
1,1,1-Trichloroethane ND ug/L 1 10/15/09 21:09 71-55-60.50 0.50
1,1,2-Trichloroethane ND ug/L 1 10/15/09 21:09 79-00-50.50 0.50
Trichloroethene ND ug/L 1 10/15/09 21:09 79-01-60.50 0.50
Trichlorofluoromethane ND ug/L 1 10/15/09 21:09 75-69-41.0 1.0
1,2,3-Trichloropropane ND ug/L 1 10/15/09 21:09 96-18-40.50 0.50
1,2,4-Trimethylbenzene ND ug/L 1 10/15/09 21:09 95-63-60.50 0.50
1,3,5-Trimethylbenzene ND ug/L 1 10/15/09 21:09 108-67-80.50 0.50
Vinyl chloride ND ug/L 1 10/15/09 21:09 75-01-41.0 1.0
m&p-Xylene ND ug/L 1 10/15/09 21:09 1330-20-71.0 1.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 19 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9254959
16143 AGROTEC
Sample:WSW-3 Lab ID:9254959004 Collected:10/08/09 13:20 Received:10/09/09 16:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
o-Xylene ND ug/L 1 10/15/09 21:09 95-47-60.50 0.50
1,2-Dichloroethane-d4 (S)94 %1 10/15/09 21:09 17060-07-070-130
Dibromofluoromethane (S)100 %1 10/15/09 21:09 1868-53-770-130
4-Bromofluorobenzene (S)106 %1 10/15/09 21:09 460-00-470-130
Toluene-d8 (S)97 %1 10/15/09 21:09 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 20 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9254959
16143 AGROTEC
Sample:WSW-4 Lab ID:9254959005 Collected:10/08/09 13:00 Received:10/09/09 16:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
MADEP EPH NC Water Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)ND ug/L 1 10/14/09 23:2410/13/09 08:00100100
Aliphatic (C19-C36)ND ug/L 1 10/14/09 23:2410/13/09 08:00100100
Aromatic (C11-C22)ND ug/L 1 10/15/09 23:2410/13/09 08:00100100
Nonatriacontane (S)74 %1 10/14/09 23:24 7194-86-710/13/09 08:0040-140
o-Terphenyl (S)71 %1 10/15/09 23:24 84-15-110/13/09 08:0040-140
2-Fluorobiphenyl (S)85 %1 10/15/09 23:24 321-60-810/13/09 08:0040-140
2-Bromonaphthalene (S)83 %1 10/15/09 23:24 580-13-210/13/09 08:0040-140
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)ND ug/L 1 10/20/09 19:13100100
Aliphatic (C09-C12)ND ug/L 1 10/20/09 19:13100100
Aromatic (C09-C10)ND ug/L 1 10/20/09 19:13100100
2,5-Dibromotoluene (PID)(S)82 %1 10/20/09 19:1370-130
2,5-Dibromotoluene (FID)(S)93 %1 10/20/09 19:1370-130
200.7 MET ICP, 3030C Analytical Method: EPA 200.7 Preparation Method: SM 3030C
Lead ND ug/L 1 10/13/09 04:38 7439-92-110/11/09 09:405.0 4.0
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
Acenaphthene ND ug/L 1 10/21/09 06:39 83-32-910/13/09 11:155.3 2.9
Acenaphthylene ND ug/L 1 10/21/09 06:39 208-96-810/13/09 11:155.3 2.9
Anthracene ND ug/L 1 10/21/09 06:39 120-12-710/13/09 11:155.3 3.1
Benzo(a)anthracene ND ug/L 1 10/21/09 06:39 56-55-310/13/09 11:155.3 2.9
Benzo(a)pyrene ND ug/L 1 10/21/09 06:39 50-32-810/13/09 11:155.3 3.3
Benzo(b)fluoranthene ND ug/L 1 10/21/09 06:39 205-99-210/13/09 11:155.3 3.8
Benzo(g,h,i)perylene ND ug/L 1 10/21/09 06:39 191-24-210/13/09 11:155.3 3.3
Benzo(k)fluoranthene ND ug/L 1 10/21/09 06:39 207-08-910/13/09 11:155.3 3.2
4-Bromophenylphenyl ether ND ug/L 1 10/21/09 06:39 101-55-310/13/09 11:155.3 2.5
Butylbenzylphthalate ND ug/L 1 10/21/09 06:39 85-68-710/13/09 11:155.3 3.1
4-Chloro-3-methylphenol ND ug/L 1 10/21/09 06:39 59-50-710/13/09 11:155.3 2.9
bis(2-Chloroethoxy)methane ND ug/L 1 10/21/09 06:39 111-91-110/13/09 11:1510.5 6.1
bis(2-Chloroethyl) ether ND ug/L 1 10/21/09 06:39 111-44-410/13/09 11:155.3 5.1
bis(2-Chloroisopropyl) ether ND ug/L 1 10/21/09 06:39 108-60-110/13/09 11:155.3 4.2
2-Chloronaphthalene ND ug/L 1 10/21/09 06:39 91-58-710/13/09 11:155.3 3.8
2-Chlorophenol ND ug/L 1 10/21/09 06:39 95-57-810/13/09 11:155.3 4.6
4-Chlorophenylphenyl ether ND ug/L 1 10/21/09 06:39 7005-72-310/13/09 11:155.3 2.8
Chrysene ND ug/L 1 10/21/09 06:39 218-01-910/13/09 11:155.3 2.8
Dibenz(a,h)anthracene ND ug/L 1 10/21/09 06:39 53-70-310/13/09 11:155.3 3.1
3,3'-Dichlorobenzidine ND ug/L 1 10/21/09 06:39 91-94-110/13/09 11:155.3 3.6
2,4-Dichlorophenol ND ug/L 1 10/21/09 06:39 120-83-210/13/09 11:155.3 4.3
Diethylphthalate ND ug/L 1 10/21/09 06:39 84-66-210/13/09 11:155.3 2.8
2,4-Dimethylphenol ND ug/L 1 10/21/09 06:39 105-67-910/13/09 11:1510.5 5.9
Dimethylphthalate ND ug/L 1 10/21/09 06:39 131-11-310/13/09 11:155.3 2.5
Di-n-butylphthalate ND ug/L 1 10/21/09 06:39 84-74-210/13/09 11:155.3 3.1
4,6-Dinitro-2-methylphenol ND ug/L 1 10/21/09 06:39 534-52-110/13/09 11:1521.1 8.2
2,4-Dinitrophenol ND ug/L 1 10/21/09 06:39 51-28-510/13/09 11:1552.6 10.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 21 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9254959
16143 AGROTEC
Sample:WSW-4 Lab ID:9254959005 Collected:10/08/09 13:00 Received:10/09/09 16:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
2,4-Dinitrotoluene ND ug/L 1 10/21/09 06:39 121-14-210/13/09 11:155.3 2.7
2,6-Dinitrotoluene ND ug/L 1 10/21/09 06:39 606-20-210/13/09 11:155.3 2.9
Di-n-octylphthalate ND ug/L 1 10/21/09 06:39 117-84-010/13/09 11:155.3 3.1
bis(2-Ethylhexyl)phthalate ND ug/L 1 10/21/09 06:39 117-81-710/13/09 11:155.3 2.2
Fluoranthene ND ug/L 1 10/21/09 06:39 206-44-010/13/09 11:155.3 3.1
Fluorene ND ug/L 1 10/21/09 06:39 86-73-710/13/09 11:155.3 2.7
Hexachloro-1,3-butadiene ND ug/L 1 10/21/09 06:39 87-68-310/13/09 11:155.3 3.5
Hexachlorobenzene ND ug/L 1 10/21/09 06:39 118-74-110/13/09 11:155.3 2.7
Hexachlorocyclopentadiene ND ug/L 1 10/21/09 06:39 77-47-410/13/09 11:1510.5 3.9
Hexachloroethane ND ug/L 1 10/21/09 06:39 67-72-110/13/09 11:155.3 3.5
Indeno(1,2,3-cd)pyrene ND ug/L 1 10/21/09 06:39 193-39-510/13/09 11:155.3 3.2
Isophorone ND ug/L 1 10/21/09 06:39 78-59-110/13/09 11:1510.5 6.8
Naphthalene ND ug/L 1 10/21/09 06:39 91-20-310/13/09 11:155.3 4.0
Nitrobenzene ND ug/L 1 10/21/09 06:39 98-95-310/13/09 11:155.3 4.6
2-Nitrophenol ND ug/L 1 10/21/09 06:39 88-75-510/13/09 11:155.3 4.8
4-Nitrophenol ND ug/L 1 10/21/09 06:39 100-02-710/13/09 11:1552.6 2.1
N-Nitrosodimethylamine ND ug/L 1 10/21/09 06:39 62-75-910/13/09 11:155.3 3.3
N-Nitroso-di-n-propylamine ND ug/L 1 10/21/09 06:39 621-64-710/13/09 11:155.3 3.9
N-Nitrosodiphenylamine ND ug/L 1 10/21/09 06:39 86-30-610/13/09 11:1510.5 6.9
Pentachlorophenol ND ug/L 1 10/21/09 06:39 87-86-510/13/09 11:1526.3 1.7
Phenanthrene ND ug/L 1 10/21/09 06:39 85-01-810/13/09 11:155.3 2.8
Phenol ND ug/L 1 10/21/09 06:39 108-95-210/13/09 11:155.3 1.9
Pyrene ND ug/L 1 10/21/09 06:39 129-00-010/13/09 11:155.3 3.1
1,2,4-Trichlorobenzene ND ug/L 1 10/21/09 06:39 120-82-110/13/09 11:155.3 3.6
2,4,6-Trichlorophenol ND ug/L 1 10/21/09 06:39 88-06-210/13/09 11:1510.5 6.4
Nitrobenzene-d5 (S)80 %1 10/21/09 06:39 4165-60-010/13/09 11:1510-120
2-Fluorobiphenyl (S)67 %1 10/21/09 06:39 321-60-810/13/09 11:1515-120
Terphenyl-d14 (S)110 %1 10/21/09 06:39 1718-51-010/13/09 11:1511-131
Phenol-d6 (S)34 %1 10/21/09 06:39 13127-88-310/13/09 11:1510-120
2-Fluorophenol (S)45 %1 10/21/09 06:39 367-12-410/13/09 11:1510-120
2,4,6-Tribromophenol (S)89 %1 10/21/09 06:39 118-79-610/13/09 11:1510-137
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 10/15/09 21:32 71-43-20.50 0.50
Bromobenzene ND ug/L 1 10/15/09 21:32 108-86-10.50 0.50
Bromochloromethane ND ug/L 1 10/15/09 21:32 74-97-50.50 0.50
Bromodichloromethane ND ug/L 1 10/15/09 21:32 75-27-40.50 0.50
Bromoform ND ug/L 1 10/15/09 21:32 75-25-20.50 0.50
Bromomethane ND ug/L 1 10/15/09 21:32 74-83-91.0 1.0
n-Butylbenzene ND ug/L 1 10/15/09 21:32 104-51-80.50 0.50
sec-Butylbenzene ND ug/L 1 10/15/09 21:32 135-98-80.50 0.50
tert-Butylbenzene ND ug/L 1 10/15/09 21:32 98-06-60.50 0.50
Carbon tetrachloride ND ug/L 1 10/15/09 21:32 56-23-50.50 0.50
Chlorobenzene ND ug/L 1 10/15/09 21:32 108-90-70.50 0.50
Chloroethane ND ug/L 1 10/15/09 21:32 75-00-31.0 1.0
Chloroform ND ug/L 1 10/15/09 21:32 67-66-30.50 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 22 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9254959
16143 AGROTEC
Sample:WSW-4 Lab ID:9254959005 Collected:10/08/09 13:00 Received:10/09/09 16:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
Chloromethane ND ug/L 1 10/15/09 21:32 74-87-31.0 1.0
2-Chlorotoluene ND ug/L 1 10/15/09 21:32 95-49-80.50 0.50
4-Chlorotoluene ND ug/L 1 10/15/09 21:32 106-43-40.50 0.50
1,2-Dibromo-3-chloropropane ND ug/L 1 10/15/09 21:32 96-12-81.0 1.0
Dibromochloromethane ND ug/L 1 10/15/09 21:32 124-48-10.50 0.50
1,2-Dibromoethane (EDB)ND ug/L 1 10/15/09 21:32 106-93-40.50 0.50
Dibromomethane ND ug/L 1 10/15/09 21:32 74-95-30.50 0.50
1,2-Dichlorobenzene ND ug/L 1 10/15/09 21:32 95-50-10.50 0.50
1,3-Dichlorobenzene ND ug/L 1 10/15/09 21:32 541-73-10.50 0.50
1,4-Dichlorobenzene ND ug/L 1 10/15/09 21:32 106-46-70.50 0.50
Dichlorodifluoromethane ND ug/L 1 10/15/09 21:32 75-71-80.50 0.50
1,1-Dichloroethane ND ug/L 1 10/15/09 21:32 75-34-30.50 0.50
1,2-Dichloroethane ND ug/L 1 10/15/09 21:32 107-06-20.50 0.50
1,1-Dichloroethene ND ug/L 1 10/15/09 21:32 75-35-40.50 0.50
cis-1,2-Dichloroethene ND ug/L 1 10/15/09 21:32 156-59-20.50 0.50
trans-1,2-Dichloroethene ND ug/L 1 10/15/09 21:32 156-60-50.50 0.50
1,2-Dichloropropane ND ug/L 1 10/15/09 21:32 78-87-50.50 0.50
1,3-Dichloropropane ND ug/L 1 10/15/09 21:32 142-28-90.50 0.50
2,2-Dichloropropane ND ug/L 1 10/15/09 21:32 594-20-70.50 0.50
1,1-Dichloropropene ND ug/L 1 10/15/09 21:32 563-58-60.50 0.50
cis-1,3-Dichloropropene ND ug/L 1 10/15/09 21:32 10061-01-50.50 0.50
trans-1,3-Dichloropropene ND ug/L 1 10/15/09 21:32 10061-02-60.50 0.50
Diisopropyl ether ND ug/L 1 10/15/09 21:32 108-20-30.50 0.50
Ethylbenzene ND ug/L 1 10/15/09 21:32 100-41-40.50 0.50
Hexachloro-1,3-butadiene ND ug/L 1 10/15/09 21:32 87-68-32.0 2.0
Isopropylbenzene (Cumene)ND ug/L 1 10/15/09 21:32 98-82-80.50 0.50
Methylene Chloride ND ug/L 1 10/15/09 21:32 75-09-22.0 2.0
Methyl-tert-butyl ether ND ug/L 1 10/15/09 21:32 1634-04-40.50 0.50
Naphthalene ND ug/L 1 10/15/09 21:32 91-20-32.0 2.0
n-Propylbenzene ND ug/L 1 10/15/09 21:32 103-65-10.50 0.50
Styrene ND ug/L 1 10/15/09 21:32 100-42-50.50 0.50
1,1,1,2-Tetrachloroethane ND ug/L 1 10/15/09 21:32 630-20-60.50 0.50
1,1,2,2-Tetrachloroethane ND ug/L 1 10/15/09 21:32 79-34-50.50 0.50
Tetrachloroethene ND ug/L 1 10/15/09 21:32 127-18-40.50 0.50
Toluene ND ug/L 1 10/15/09 21:32 108-88-30.50 0.50
1,2,3-Trichlorobenzene ND ug/L 1 10/15/09 21:32 87-61-62.0 2.0
1,2,4-Trichlorobenzene ND ug/L 1 10/15/09 21:32 120-82-12.0 2.0
1,1,1-Trichloroethane ND ug/L 1 10/15/09 21:32 71-55-60.50 0.50
1,1,2-Trichloroethane ND ug/L 1 10/15/09 21:32 79-00-50.50 0.50
Trichloroethene ND ug/L 1 10/15/09 21:32 79-01-60.50 0.50
Trichlorofluoromethane ND ug/L 1 10/15/09 21:32 75-69-41.0 1.0
1,2,3-Trichloropropane ND ug/L 1 10/15/09 21:32 96-18-40.50 0.50
1,2,4-Trimethylbenzene ND ug/L 1 10/15/09 21:32 95-63-60.50 0.50
1,3,5-Trimethylbenzene ND ug/L 1 10/15/09 21:32 108-67-80.50 0.50
Vinyl chloride ND ug/L 1 10/15/09 21:32 75-01-41.0 1.0
m&p-Xylene ND ug/L 1 10/15/09 21:32 1330-20-71.0 1.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 23 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9254959
16143 AGROTEC
Sample:WSW-4 Lab ID:9254959005 Collected:10/08/09 13:00 Received:10/09/09 16:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
o-Xylene ND ug/L 1 10/15/09 21:32 95-47-60.50 0.50
1,2-Dichloroethane-d4 (S)92 %1 10/15/09 21:32 17060-07-070-130
Dibromofluoromethane (S)99 %1 10/15/09 21:32 1868-53-770-130
4-Bromofluorobenzene (S)105 %1 10/15/09 21:32 460-00-470-130
Toluene-d8 (S)98 %1 10/15/09 21:32 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 24 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9254959
16143 AGROTEC
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/5195
SM 3030C
EPA 200.7
200.7 MET 3030C
Associated Lab Samples:9254959001, 9254959002, 9254959003, 9254959004, 9254959005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:349239
Associated Lab Samples:9254959001, 9254959002, 9254959003, 9254959004, 9254959005
Matrix:Water
Analyzed
Lead ug/L ND 5.0 10/13/09 03:55
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
349240LABORATORY CONTROL SAMPLE:
LCSSpike
Lead ug/L 551500 110 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
349241MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9254959001
349242
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Lead ug/L 500 109 70-130106 2 205009.1 553 541
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
9254959002
349243SAMPLE DUPLICATE:
Lead ug/L ND 20ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 25 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9254959
16143 AGROTEC
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/8292
EPA 625
EPA 625
625 MSS
Associated Lab Samples:9254959001, 9254959002, 9254959003, 9254959004, 9254959005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:349949
Associated Lab Samples:9254959001, 9254959002, 9254959003, 9254959004, 9254959005
Matrix:Water
Analyzed
1,2,4-Trichlorobenzene ug/L ND 5.0 10/21/09 04:05
2,4,6-Trichlorophenol ug/L ND 10.0 10/21/09 04:05
2,4-Dichlorophenol ug/L ND 5.0 10/21/09 04:05
2,4-Dimethylphenol ug/L ND 10.0 10/21/09 04:05
2,4-Dinitrophenol ug/L ND 50.0 10/21/09 04:05
2,4-Dinitrotoluene ug/L ND 5.0 10/21/09 04:05
2,6-Dinitrotoluene ug/L ND 5.0 10/21/09 04:05
2-Chloronaphthalene ug/L ND 5.0 10/21/09 04:05
2-Chlorophenol ug/L ND 5.0 10/21/09 04:05
2-Nitrophenol ug/L ND 5.0 10/21/09 04:05
3,3'-Dichlorobenzidine ug/L ND 5.0 10/21/09 04:05
4,6-Dinitro-2-methylphenol ug/L ND 20.0 10/21/09 04:05
4-Bromophenylphenyl ether ug/L ND 5.0 10/21/09 04:05
4-Chloro-3-methylphenol ug/L ND 5.0 10/21/09 04:05
4-Chlorophenylphenyl ether ug/L ND 5.0 10/21/09 04:05
4-Nitrophenol ug/L ND 50.0 10/21/09 04:05
Acenaphthene ug/L ND 5.0 10/21/09 04:05
Acenaphthylene ug/L ND 5.0 10/21/09 04:05
Anthracene ug/L ND 5.0 10/21/09 04:05
Benzo(a)anthracene ug/L ND 5.0 10/21/09 04:05
Benzo(a)pyrene ug/L ND 5.0 10/21/09 04:05
Benzo(b)fluoranthene ug/L ND 5.0 10/21/09 04:05
Benzo(g,h,i)perylene ug/L ND 5.0 10/21/09 04:05
Benzo(k)fluoranthene ug/L ND 5.0 10/21/09 04:05
bis(2-Chloroethoxy)methane ug/L ND 10.0 10/21/09 04:05
bis(2-Chloroethyl) ether ug/L ND 5.0 10/21/09 04:05
bis(2-Chloroisopropyl) ether ug/L ND 5.0 10/21/09 04:05
bis(2-Ethylhexyl)phthalate ug/L ND 5.0 10/21/09 04:05
Butylbenzylphthalate ug/L ND 5.0 10/21/09 04:05
Chrysene ug/L ND 5.0 10/21/09 04:05
Di-n-butylphthalate ug/L ND 5.0 10/21/09 04:05
Di-n-octylphthalate ug/L ND 5.0 10/21/09 04:05
Dibenz(a,h)anthracene ug/L ND 5.0 10/21/09 04:05
Diethylphthalate ug/L ND 5.0 10/21/09 04:05
Dimethylphthalate ug/L ND 5.0 10/21/09 04:05
Fluoranthene ug/L ND 5.0 10/21/09 04:05
Fluorene ug/L ND 5.0 10/21/09 04:05
Hexachloro-1,3-butadiene ug/L ND 5.0 10/21/09 04:05
Hexachlorobenzene ug/L ND 5.0 10/21/09 04:05
Hexachlorocyclopentadiene ug/L ND 10.0 10/21/09 04:05
Hexachloroethane ug/L ND 5.0 10/21/09 04:05
Indeno(1,2,3-cd)pyrene ug/L ND 5.0 10/21/09 04:05
Isophorone ug/L ND 10.0 10/21/09 04:05
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 26 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9254959
16143 AGROTEC
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:349949
Associated Lab Samples:9254959001, 9254959002, 9254959003, 9254959004, 9254959005
Matrix:Water
Analyzed
N-Nitroso-di-n-propylamine ug/L ND 5.0 10/21/09 04:05
N-Nitrosodimethylamine ug/L ND 5.0 10/21/09 04:05
N-Nitrosodiphenylamine ug/L ND 10.0 10/21/09 04:05
Naphthalene ug/L ND 5.0 10/21/09 04:05
Nitrobenzene ug/L ND 5.0 10/21/09 04:05
Pentachlorophenol ug/L ND 25.0 10/21/09 04:05
Phenanthrene ug/L ND 5.0 10/21/09 04:05
Phenol ug/L ND 5.0 10/21/09 04:05
Pyrene ug/L ND 5.0 10/21/09 04:05
2,4,6-Tribromophenol (S)%93 10-137 10/21/09 04:05
2-Fluorobiphenyl (S)%71 15-120 10/21/09 04:05
2-Fluorophenol (S)%45 10-120 10/21/09 04:05
Nitrobenzene-d5 (S)%80 10-120 10/21/09 04:05
Phenol-d6 (S)%36 10-120 10/21/09 04:05
Terphenyl-d14 (S)%105 11-131 10/21/09 04:05
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
349950LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/L 19.1 L0503844-142
2,4,6-Trichlorophenol ug/L 38.250 76 37-144
2,4-Dichlorophenol ug/L 36.050 72 1-191
2,4-Dimethylphenol ug/L 36.750 73 32-119
2,4-Dinitrophenol ug/L 23.8J50 48 1-181
2,4-Dinitrotoluene ug/L 39.850 80 39-139
2,6-Dinitrotoluene ug/L 37.250 74 50-158
2-Chloronaphthalene ug/L 32.350 65 60-118
2-Chlorophenol ug/L 29.850 60 23-134
2-Nitrophenol ug/L 34.250 68 29-182
3,3'-Dichlorobenzidine ug/L 18.650 37 1-262
4,6-Dinitro-2-methylphenol ug/L 35.350 71 1-181
4-Bromophenylphenyl ether ug/L 39.150 78 53-127
4-Chloro-3-methylphenol ug/L 39.850 80 22-147
4-Chlorophenylphenyl ether ug/L 36.050 72 25-158
4-Nitrophenol ug/L 94.0 L0501881-132
Acenaphthene ug/L 34.450 69 47-145
Acenaphthylene ug/L 34.850 70 33-145
Anthracene ug/L 38.550 77 1-166
Benzo(a)anthracene ug/L 42.650 85 33-143
Benzo(a)pyrene ug/L 44.450 89 17-163
Benzo(b)fluoranthene ug/L 58.250 116 24-159
Benzo(g,h,i)perylene ug/L 20.650 41 1-219
Benzo(k)fluoranthene ug/L 52.950 106 11-162
bis(2-Chloroethoxy)methane ug/L 40.050 80 33-184
bis(2-Chloroethyl) ether ug/L 33.950 68 12-158
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 27 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9254959
16143 AGROTEC
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
349950LABORATORY CONTROL SAMPLE:
LCSSpike
bis(2-Ethylhexyl)phthalate ug/L 52.450 105 8-158
Butylbenzylphthalate ug/L 55.850 112 1-152
Chrysene ug/L 35.550 71 17-168
Di-n-butylphthalate ug/L 39.750 79 1-118
Di-n-octylphthalate ug/L 45.250 90 4-146
Dibenz(a,h)anthracene ug/L 22.950 46 1-227
Diethylphthalate ug/L 40.250 80 1-114
Dimethylphthalate ug/L 38.750 77 1-112
Fluoranthene ug/L 42.750 85 26-137
Fluorene ug/L 35.750 71 59-121
Hexachloro-1,3-butadiene ug/L 14.850 30 24-116
Hexachlorobenzene ug/L 33.250 66 1-152
Hexachlorocyclopentadiene ug/L 13.850 28 25-150
Hexachloroethane ug/L 13.6 L0502740-113
Indeno(1,2,3-cd)pyrene ug/L 22.950 46 1-171
Isophorone ug/L 35.750 71 21-196
N-Nitroso-di-n-propylamine ug/L 39.550 79 1-230
N-Nitrosodimethylamine ug/L 23.550 47 25-150
N-Nitrosodiphenylamine ug/L 61.250 122 25-150
Naphthalene ug/L 28.650 57 21-133
Nitrobenzene ug/L 30.650 61 35-180
Pentachlorophenol ug/L 60.350 121 14-176
Phenanthrene ug/L 37.050 74 54-120
Phenol ug/L 16.550 33 5-112
Pyrene ug/L 55.150 110 52-115
2,4,6-Tribromophenol (S)%79 10-137
2-Fluorobiphenyl (S)%64 15-120
2-Fluorophenol (S)%39 10-120
Nitrobenzene-d5 (S)%66 10-120
Phenol-d6 (S)%29 10-120
Terphenyl-d14 (S)%108 11-131
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
349951MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9254948005
349952
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,2,4-Trichlorobenzene ug/L 116 49 44-14257 16 30116ND56.4 66.5
2,4,6-Trichlorophenol ug/L 116 58 37-14466 13 30116ND67.7 76.7
2,4-Dichlorophenol ug/L 116 57 1-19161 7 30116ND66.1 70.9
2,4-Dimethylphenol ug/L M0116832-1195 30116NDNDND
2,4-Dinitrophenol ug/L R11161181-181166 34 30116ND137193
2,4-Dinitrotoluene ug/L 116 73 39-13989 21 30116ND84.4 104
2,6-Dinitrotoluene ug/L 116 65 50-15881 22 30116ND76.2 94.5
2-Chloronaphthalene ug/L 116 63 60-11880 24 30116ND73.1 93.5
2-Chlorophenol ug/L 116 53 23-13456 6 30116ND61.4 65.0
2-Nitrophenol ug/L 116 66 29-18283 23 30116ND76.3 96.5
3,3'-Dichlorobenzidine ug/L M011601-2620 30116NDNDND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 28 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9254959
16143 AGROTEC
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
349951MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9254948005
349952
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
4,6-Dinitro-2-methylphenol ug/L R1116641-18189 33 30116ND74.8 104
4-Bromophenylphenyl ether ug/L 116 64 53-12787 30 30116ND74.4 101
4-Chloro-3-methylphenol ug/L R11165022-14736 33 30116ND58.4 42.0
4-Chlorophenylphenyl ether ug/L 116 66 25-15882 21 30116ND77.1 95.5
4-Nitrophenol ug/L 116 64 1-13288 30116ND74.2J 103J
Acenaphthene ug/L 116 64 47-14580 22 30116ND75.0 93.4
Acenaphthylene ug/L 116 64 33-14580 22 30116ND74.8 93.5
Anthracene ug/L 116 63 1-16682 26 30116ND72.9 94.8
Benzo(a)anthracene ug/L 116 70 33-14395 29 30116ND81.9 110
Benzo(a)pyrene ug/L 116 73 17-16391 22 30116ND84.8 105
Benzo(b)fluoranthene ug/L 116 95 24-159123 26 30116ND110144
Benzo(g,h,i)perylene ug/L R1116351-21950 35 30116ND41.2 58.6
Benzo(k)fluoranthene ug/L R11168811-162120 31 30116ND102139
bis(2-Chloroethoxy)methane ug/L 116 74 33-18493 23 30116ND86.4 109
bis(2-Chloroethyl) ether ug/L 116 68 12-15882 19 30116ND78.8 95.7
bis(2-Ethylhexyl)phthalate ug/L 116 88 8-158114 25 30116ND103132
Butylbenzylphthalate ug/L 116 91 1-152123 29 30116ND106142
Chrysene ug/L 116 60 17-16878 26 30116ND70.1 91.2
Di-n-butylphthalate ug/L 116 65 1-11888 30 30116ND75.2 102
Di-n-octylphthalate ug/L R1116764-146105 33 30116ND87.9 122
Dibenz(a,h)anthracene ug/L R1116381-22757 38 30116ND44.7 65.9
Diethylphthalate ug/L 116 68 1-11486 23 30116ND79.4 99.7
Dimethylphthalate ug/L 116 62 1-11279 25 30116ND71.5 92.1
Fluoranthene ug/L 116 70 26-13793 28 30116ND81.4 108
Fluorene ug/L 116 65 59-12181 21 30116ND76.0 93.7
Hexachloro-1,3-butadiene ug/L 116 49 24-11654 10 30116ND56.9 62.6
Hexachlorobenzene ug/L R1116541-15273 31 30116ND62.7 85.4
Hexachlorocyclopentadiene ug/L 116 54 25-15067 23 30116ND62.2 78.3
Hexachloroethane ug/L 116 44 40-11350 11 30116ND51.4 57.6
Indeno(1,2,3-cd)pyrene ug/L R1116381-17156 38 30116ND44.5 65.0
Isophorone ug/L 116 65 21-19683 25 30116ND75.0 96.1
N-Nitroso-di-n-propylamine ug/L 116 76 1-23093 20 30116ND88.0 108
N-Nitrosodimethylamine ug/L 116 60 25-15080 29 30116ND69.4 92.8
N-Nitrosodiphenylamine ug/L 116 90 25-150101 11 30116ND105117
Naphthalene ug/L 116 61 21-13373 19 30116ND70.5 85.1
Nitrobenzene ug/L 116 60 35-18077 26 30116ND69.3 90.0
Pentachlorophenol ug/L R11168614-176136 46 30116ND99.6 159
Phenanthrene ug/L 116 61 54-12081 29 30116ND70.5 94.3
Phenol ug/L 116 26 5-11210 30116ND29.9 11.4J
Pyrene ug/L M01169152-115120 27 30116ND106139
2,4,6-Tribromophenol (S)%69 10-13767
2-Fluorobiphenyl (S)%67 15-12073
2-Fluorophenol (S)%33 10-12015
Nitrobenzene-d5 (S)%68 10-12080
Phenol-d6 (S)%29 10-12011
Terphenyl-d14 (S)%103 11-131117
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 29 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9254959
16143 AGROTEC
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/8283
MADEP EPH
MADEP EPH
MADEP EPH NC Water
Associated Lab Samples:9254959001, 9254959002, 9254959003, 9254959004, 9254959005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:349785
Associated Lab Samples:9254959001, 9254959002, 9254959003, 9254959004, 9254959005
Matrix:Water
Analyzed
Aliphatic (C09-C18)ug/L ND 100 10/14/09 16:43
Aliphatic (C19-C36)ug/L ND 100 10/14/09 16:43
Aromatic (C11-C22)ug/L ND 100 10/15/09 16:42
2-Bromonaphthalene (S)%72 40-140 10/15/09 16:42
2-Fluorobiphenyl (S)%71 40-140 10/15/09 16:42
Nonatriacontane (S)%76 40-140 10/14/09 16:43
o-Terphenyl (S)%56 40-140 10/15/09 16:42
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
349786LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
349787
Aliphatic (C09-C18)ug/L 120300 40 40-14041123 2 50
Aliphatic (C19-C36)ug/L 321400 80 40-14081322 0 50
Aromatic (C11-C22)ug/L 741850 87 40-14094803 8 50
2-Bromonaphthalene (S)%102 40-140106
2-Fluorobiphenyl (S)%97 40-140103
Nonatriacontane (S)%79 40-14077
o-Terphenyl (S)%83 40-14093
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 30 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9254959
16143 AGROTEC
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GCV/3570
MADEP VPH
MADEP VPH
VPH NC Water
Associated Lab Samples:9254959001, 9254959002, 9254959003, 9254959004, 9254959005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:353072
Associated Lab Samples:9254959001, 9254959002, 9254959003, 9254959004, 9254959005
Matrix:Water
Analyzed
Aliphatic (C05-C08)ug/L ND 100 10/20/09 16:25
Aliphatic (C09-C12)ug/L ND 100 10/20/09 16:25
Aromatic (C09-C10)ug/L ND 100 10/20/09 16:25
2,5-Dibromotoluene (FID)(S)%105 70-130 10/20/09 16:25
2,5-Dibromotoluene (PID)(S)%88 70-130 10/20/09 16:25
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
353073LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
353074
Aliphatic (C05-C08)ug/L 292300 97 70-13098294 1 25
Aliphatic (C09-C12)ug/L 264300 88 30-13091273 3 25
Aromatic (C09-C10)ug/L ND100 82 70-13085ND 25
2,5-Dibromotoluene (FID)(S)%106 70-130109
2,5-Dibromotoluene (PID)(S)%84 70-13090
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 31 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9254959
16143 AGROTEC
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/8653
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:9254959001, 9254959002, 9254959003, 9254959004, 9254959005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:351198
Associated Lab Samples:9254959001, 9254959002, 9254959003, 9254959004, 9254959005
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 10/15/09 12:22
1,1,1-Trichloroethane ug/L ND 0.50 10/15/09 12:22
1,1,2,2-Tetrachloroethane ug/L ND 0.50 10/15/09 12:22
1,1,2-Trichloroethane ug/L ND 0.50 10/15/09 12:22
1,1-Dichloroethane ug/L ND 0.50 10/15/09 12:22
1,1-Dichloroethene ug/L ND 0.50 10/15/09 12:22
1,1-Dichloropropene ug/L ND 0.50 10/15/09 12:22
1,2,3-Trichlorobenzene ug/L ND 2.0 10/15/09 12:22
1,2,3-Trichloropropane ug/L ND 0.50 10/15/09 12:22
1,2,4-Trichlorobenzene ug/L ND 2.0 10/15/09 12:22
1,2,4-Trimethylbenzene ug/L ND 0.50 10/15/09 12:22
1,2-Dibromo-3-chloropropane ug/L ND 1.0 10/15/09 12:22
1,2-Dibromoethane (EDB)ug/L ND 0.50 10/15/09 12:22
1,2-Dichlorobenzene ug/L ND 0.50 10/15/09 12:22
1,2-Dichloroethane ug/L ND 0.50 10/15/09 12:22
1,2-Dichloropropane ug/L ND 0.50 10/15/09 12:22
1,3,5-Trimethylbenzene ug/L ND 0.50 10/15/09 12:22
1,3-Dichlorobenzene ug/L ND 0.50 10/15/09 12:22
1,3-Dichloropropane ug/L ND 0.50 10/15/09 12:22
1,4-Dichlorobenzene ug/L ND 0.50 10/15/09 12:22
2,2-Dichloropropane ug/L ND 0.50 10/15/09 12:22
2-Chlorotoluene ug/L ND 0.50 10/15/09 12:22
4-Chlorotoluene ug/L ND 0.50 10/15/09 12:22
Benzene ug/L ND 0.50 10/15/09 12:22
Bromobenzene ug/L ND 0.50 10/15/09 12:22
Bromochloromethane ug/L ND 0.50 10/15/09 12:22
Bromodichloromethane ug/L ND 0.50 10/15/09 12:22
Bromoform ug/L ND 0.50 10/15/09 12:22
Bromomethane ug/L ND 1.0 10/15/09 12:22
Carbon tetrachloride ug/L ND 0.50 10/15/09 12:22
Chlorobenzene ug/L ND 0.50 10/15/09 12:22
Chloroethane ug/L ND 1.0 10/15/09 12:22
Chloroform ug/L ND 0.50 10/15/09 12:22
Chloromethane ug/L ND 1.0 10/15/09 12:22
cis-1,2-Dichloroethene ug/L ND 0.50 10/15/09 12:22
cis-1,3-Dichloropropene ug/L ND 0.50 10/15/09 12:22
Dibromochloromethane ug/L ND 0.50 10/15/09 12:22
Dibromomethane ug/L ND 0.50 10/15/09 12:22
Dichlorodifluoromethane ug/L ND 0.50 10/15/09 12:22
Diisopropyl ether ug/L ND 0.50 10/15/09 12:22
Ethylbenzene ug/L ND 0.50 10/15/09 12:22
Hexachloro-1,3-butadiene ug/L ND 2.0 10/15/09 12:22
Isopropylbenzene (Cumene)ug/L ND 0.50 10/15/09 12:22
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 32 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9254959
16143 AGROTEC
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:351198
Associated Lab Samples:9254959001, 9254959002, 9254959003, 9254959004, 9254959005
Matrix:Water
Analyzed
m&p-Xylene ug/L ND 1.0 10/15/09 12:22
Methyl-tert-butyl ether ug/L ND 0.50 10/15/09 12:22
Methylene Chloride ug/L 2.2 2.0 C910/15/09 12:22
n-Butylbenzene ug/L ND 0.50 10/15/09 12:22
n-Propylbenzene ug/L ND 0.50 10/15/09 12:22
Naphthalene ug/L ND 2.0 10/15/09 12:22
o-Xylene ug/L ND 0.50 10/15/09 12:22
sec-Butylbenzene ug/L ND 0.50 10/15/09 12:22
Styrene ug/L ND 0.50 10/15/09 12:22
tert-Butylbenzene ug/L ND 0.50 10/15/09 12:22
Tetrachloroethene ug/L ND 0.50 10/15/09 12:22
Toluene ug/L ND 0.50 10/15/09 12:22
trans-1,2-Dichloroethene ug/L ND 0.50 10/15/09 12:22
trans-1,3-Dichloropropene ug/L ND 0.50 10/15/09 12:22
Trichloroethene ug/L ND 0.50 10/15/09 12:22
Trichlorofluoromethane ug/L ND 1.0 10/15/09 12:22
Vinyl chloride ug/L ND 1.0 10/15/09 12:22
1,2-Dichloroethane-d4 (S)%102 70-130 10/15/09 12:22
4-Bromofluorobenzene (S)%102 70-130 10/15/09 12:22
Dibromofluoromethane (S)%105 70-130 10/15/09 12:22
Toluene-d8 (S)%101 70-130 10/15/09 12:22
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
351199LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 58.150 116 60-140
1,1,1-Trichloroethane ug/L 56.350 113 60-140
1,1,2,2-Tetrachloroethane ug/L 50.050 100 60-140
1,1,2-Trichloroethane ug/L 57.450 115 60-140
1,1-Dichloroethane ug/L 57.550 115 60-140
1,1-Dichloroethene ug/L 58.750 117 60-140
1,1-Dichloropropene ug/L 58.050 116 60-140
1,2,3-Trichlorobenzene ug/L 51.250 102 60-140
1,2,3-Trichloropropane ug/L 51.450 103 60-140
1,2,4-Trichlorobenzene ug/L 52.750 105 60-140
1,2,4-Trimethylbenzene ug/L 54.950 110 60-140
1,2-Dibromo-3-chloropropane ug/L 46.250 92 60-140
1,2-Dibromoethane (EDB)ug/L 55.550 111 60-140
1,2-Dichlorobenzene ug/L 51.350 103 60-140
1,2-Dichloroethane ug/L 53.050 106 60-140
1,2-Dichloropropane ug/L 61.450 123 60-140
1,3,5-Trimethylbenzene ug/L 53.950 108 60-140
1,3-Dichlorobenzene ug/L 51.050 102 60-140
1,3-Dichloropropane ug/L 53.450 107 60-140
1,4-Dichlorobenzene ug/L 49.250 98 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 33 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9254959
16143 AGROTEC
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
351199LABORATORY CONTROL SAMPLE:
LCSSpike
2,2-Dichloropropane ug/L 45.550 91 60-140
2-Chlorotoluene ug/L 49.050 98 60-140
4-Chlorotoluene ug/L 51.050 102 60-140
Benzene ug/L 58.050 116 60-140
Bromobenzene ug/L 50.350 101 60-140
Bromochloromethane ug/L 48.150 96 60-140
Bromodichloromethane ug/L 54.650 109 60-140
Bromoform ug/L 46.150 92 60-140
Bromomethane ug/L 64.750 129 60-140
Carbon tetrachloride ug/L 62.450 125 60-140
Chlorobenzene ug/L 54.650 109 60-140
Chloroethane ug/L 61.450 123 60-140
Chloroform ug/L 53.750 107 60-140
Chloromethane ug/L 48.550 97 60-140
cis-1,2-Dichloroethene ug/L 59.650 119 60-140
cis-1,3-Dichloropropene ug/L 62.350 125 60-140
Dibromochloromethane ug/L 53.450 107 60-140
Dibromomethane ug/L 63.250 126 60-140
Dichlorodifluoromethane ug/L 48.850 98 60-140
Diisopropyl ether ug/L 58.850 118 60-140
Ethylbenzene ug/L 55.250 110 60-140
Hexachloro-1,3-butadiene ug/L 56.450 113 60-140
Isopropylbenzene (Cumene)ug/L 58.750 117 60-140
m&p-Xylene ug/L 112100 112 60-140
Methyl-tert-butyl ether ug/L 54.350 109 60-140
Methylene Chloride ug/L 56.650 113 60-140
n-Butylbenzene ug/L 53.950 108 60-140
n-Propylbenzene ug/L 52.450 105 60-140
Naphthalene ug/L 57.850 116 60-140
o-Xylene ug/L 56.850 114 60-140
sec-Butylbenzene ug/L 53.550 107 60-140
Styrene ug/L 60.250 120 60-140
tert-Butylbenzene ug/L 53.950 108 60-140
Tetrachloroethene ug/L 56.450 113 60-140
Toluene ug/L 56.550 113 60-140
trans-1,2-Dichloroethene ug/L 57.150 114 60-140
trans-1,3-Dichloropropene ug/L 60.450 121 60-140
Trichloroethene ug/L 64.150 128 60-140
Trichlorofluoromethane ug/L 57.050 114 60-140
Vinyl chloride ug/L 51.550 103 60-140
1,2-Dichloroethane-d4 (S)%89 70-130
4-Bromofluorobenzene (S)%114 70-130
Dibromofluoromethane (S)%97 70-130
Toluene-d8 (S)%100 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 34 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9254959
16143 AGROTEC
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
351200MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9254959005
351201
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 123 60-140126 3 3020ND24.5 25.2
1,1,1-Trichloroethane ug/L 20 122 60-140124 2 3020ND24.4 24.9
1,1,2,2-Tetrachloroethane ug/L 20 108 60-140112 4 3020ND21.6 22.4
1,1,2-Trichloroethane ug/L 20 121 60-140128 5 3020ND24.2 25.5
1,1-Dichloroethane ug/L 20 121 60-140128 5 3020ND24.3 25.5
1,1-Dichloroethene ug/L 20 95 60-140125 28 3020ND19.0 25.1
1,1-Dichloropropene ug/L 20 123 60-140127 3 3020ND24.7 25.4
1,2,3-Trichlorobenzene ug/L 20 107 60-140121 13 3020ND21.3 24.3
1,2,3-Trichloropropane ug/L 20 111 60-140117 6 3020ND22.1 23.5
1,2,4-Trichlorobenzene ug/L 20 105 60-140121 15 3020ND21.0 24.3
1,2,4-Trimethylbenzene ug/L 20 116 60-140115 1 3020ND23.4 23.1
1,2-Dibromo-3-chloropropane ug/L 20 90 60-140103 14 3020ND18.0 20.6
1,2-Dibromoethane (EDB)ug/L 20 120 60-140128 7 3020ND24.0 25.7
1,2-Dichlorobenzene ug/L 20 109 60-140116 6 3020ND21.8 23.1
1,2-Dichloroethane ug/L 20 110 60-140118 7 3020ND22.0 23.7
1,2-Dichloropropane ug/L 20 124 60-140133 6 3020ND24.9 26.5
1,3,5-Trimethylbenzene ug/L 20 115 60-140113 2 3020ND23.1 22.7
1,3-Dichlorobenzene ug/L 20 109 60-140114 4 3020ND21.8 22.8
1,3-Dichloropropane ug/L 20 117 60-140123 5 3020ND23.4 24.6
1,4-Dichlorobenzene ug/L 20 107 60-140111 4 3020ND21.4 22.3
2,2-Dichloropropane ug/L 20 81 60-14085 5 3020ND16.2 17.0
2-Chlorotoluene ug/L 20 104 60-140108 4 3020ND20.7 21.5
4-Chlorotoluene ug/L 20 107 60-140111 4 3020ND21.4 22.1
Benzene ug/L 20 124 60-140127 3 3020ND24.7 25.3
Bromobenzene ug/L 20 107 60-140112 5 3020ND21.3 22.5
Bromochloromethane ug/L 20 109 60-140126 14 3020ND21.8 25.1
Bromodichloromethane ug/L 20 114 60-140119 5 3020ND22.8 23.9
Bromoform ug/L 20 107 60-140111 4 3020ND21.5 22.3
Bromomethane ug/L 20 82 60-14079 3 3020ND16.3 15.9
Carbon tetrachloride ug/L 20 129 60-140137 6 3020ND25.8 27.4
Chlorobenzene ug/L 20 119 60-140121 1 3020ND23.9 24.1
Chloroethane ug/L 20 128 60-140127 1 3020ND25.7 25.4
Chloroform ug/L 20 115 60-140116 2 3020ND22.9 23.3
Chloromethane ug/L 20 107 60-140104 2 3020ND21.4 20.9
cis-1,2-Dichloroethene ug/L 20 125 60-140131 5 3020ND24.9 26.1
cis-1,3-Dichloropropene ug/L 20 123 60-140128 4 3020ND24.6 25.6
Dibromochloromethane ug/L 20 117 60-140122 5 3020ND23.3 24.4
Dibromomethane ug/L M02013360-140145 9 3020ND26.5 28.9
Dichlorodifluoromethane ug/L 20 104 60-140109 4 3020ND20.8 21.8
Diisopropyl ether ug/L 20 119 60-140128 7 3020ND23.9 25.5
Ethylbenzene ug/L 20 120 60-140119 0 3020ND24.0 24.0
Hexachloro-1,3-butadiene ug/L 20 118 60-140129 9 3020ND23.5 25.7
Isopropylbenzene (Cumene)ug/L 20 128 60-140126 1 3020ND25.5 25.2
m&p-Xylene ug/L 40 120 60-140117 2 3040ND48.3 47.3
Methyl-tert-butyl ether ug/L 20 111 60-140122 10 3020ND22.2 24.4
Methylene Chloride ug/L 20 112 60-140121 8 3020ND22.3 24.2
n-Butylbenzene ug/L 20 113 60-140120 6 3020ND22.6 24.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 35 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9254959
16143 AGROTEC
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
351200MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9254959005
351201
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
n-Propylbenzene ug/L 20 112 60-140115 3 3020ND22.3 23.0
Naphthalene ug/L 20 105 60-140130 22 3020ND20.9 26.0
o-Xylene ug/L 20 121 60-140120 0 3020ND24.2 24.2
sec-Butylbenzene ug/L 20 116 60-140123 6 3020ND23.2 24.6
Styrene ug/L 20 117 60-140115 2 3020ND23.5 23.0
tert-Butylbenzene ug/L 20 117 60-140123 5 3020ND23.4 24.6
Tetrachloroethene ug/L 20 123 60-140127 3 3020ND24.6 25.3
Toluene ug/L 20 120 60-140121 1 3020ND24.4 24.7
trans-1,2-Dichloroethene ug/L 20 120 60-140125 4 3020ND24.0 24.9
trans-1,3-Dichloropropene ug/L 20 122 60-140127 4 3020ND24.4 25.3
Trichloroethene ug/L M02013660-140145 6 3020ND27.3 28.9
Trichlorofluoromethane ug/L 20 87 60-14098 11 3020ND17.4 19.5
Vinyl chloride ug/L 20 115 60-140119 3 3020ND23.0 23.7
1,2-Dichloroethane-d4 (S)%85 70-13087
4-Bromofluorobenzene (S)%115 70-130110
Dibromofluoromethane (S)%94 70-13098
Toluene-d8 (S)%98 70-13097
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 36 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALIFIERS
Pace Project No.:
Project:
9254959
16143 AGROTEC
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution ofthe sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes.
U - Indicates the compound was analyzed for, but not detected.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Common Laboratory Contaminant.C9
Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
RPD value was outside control limits.R1
Surrogate recovery outside laboratory control limits.S0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 37 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
9254959
16143 AGROTEC
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
9254959001 MPRP/5195 ICP/4815MW-1 SM 3030C EPA 200.7
9254959002 MPRP/5195 ICP/4815WSW-1 SM 3030C EPA 200.7
9254959003 MPRP/5195 ICP/4815WSW-2 SM 3030C EPA 200.7
9254959004 MPRP/5195 ICP/4815WSW-3 SM 3030C EPA 200.7
9254959005 MPRP/5195 ICP/4815WSW-4 SM 3030C EPA 200.7
9254959001 OEXT/8283 GCSV/6465MW-1 MADEP EPH MADEP EPH
9254959002 OEXT/8283 GCSV/6465WSW-1 MADEP EPH MADEP EPH
9254959003 OEXT/8283 GCSV/6465WSW-2 MADEP EPH MADEP EPH
9254959004 OEXT/8283 GCSV/6465WSW-3 MADEP EPH MADEP EPH
9254959005 OEXT/8283 GCSV/6465WSW-4 MADEP EPH MADEP EPH
9254959001 OEXT/8292 MSSV/3149MW-1 EPA 625 EPA 625
9254959002 OEXT/8292 MSSV/3149WSW-1 EPA 625 EPA 625
9254959003 OEXT/8292 MSSV/3149WSW-2 EPA 625 EPA 625
9254959004 OEXT/8292 MSSV/3149WSW-3 EPA 625 EPA 625
9254959005 OEXT/8292 MSSV/3149WSW-4 EPA 625 EPA 625
9254959001 MSV/8653MW-1 SM 6200B
9254959002 MSV/8653WSW-1 SM 6200B
9254959003 MSV/8653WSW-2 SM 6200B
9254959004 MSV/8653WSW-3 SM 6200B
9254959005 MSV/8653WSW-4 SM 6200B
9254959001 GCV/3570MW-1 MADEP VPH
9254959002 GCV/3570WSW-1 MADEP VPH
9254959003 GCV/3570WSW-2 MADEP VPH
9254959004 GCV/3570WSW-3 MADEP VPH
9254959005 GCV/3570WSW-4 MADEP VPH
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 10/26/2009 11:59 AM Page 38 of 38
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
January 25, 2010
LIMS USE: FR - LINDA BLALOCK
LIMS OBJECT ID: 9260951
9260951
Project:
Pace Project No.:
RE:
Ms. Linda BlalockNCDENR - UST Section1637 Mail Service CenterRaleigh, NC 276991637
16143 Agrotec
Dear Ms. Blalock:
Enclosed are the analytical results for sample(s) received by the laboratory on January 08, 2010.
The results relate only to the samples included in this report. Results reported herein conform to themost current NELAC standards, where applicable, unless otherwise narrated in the body of the
report.
Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and
Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All
Microbiological analyses were performed at the laboratory where the samples were received.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Renee Spencer
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 21
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
CERTIFICATIONS
Pace Project No.:
Project:
9260951
16143 Agrotec
Charlotte Certification IDsConnecticut Certification #: PH-0104Florida/NELAP Certification #: E876279800 Kincey Ave. - Ste 100 Huntersville, NC 28078West Virginia Certification #: 357Virginia Certification #: 00213Tennessee Certification #: 04010South Carolina Drinking Water Cert. #: 990060003South Carolina Certification #: 990060001
Pennsylvania Certification #: 68-00784North Carolina Wastewater Certification #: 12North Carolina Field Services Certification #: 5342North Carolina Drinking Water Certification #: 37706New Jersey Certification #: NC012Louisiana/LELAP Certification #: 04034Kentucky UST Certification #: 84
Asheville Certification IDsConnecticut Certification #: PH-01062225 Riverside Dr. Asheville, NC 28804Virginia Certification #: 00072Tennessee Certification #: 2980South Carolina Certification #: 99030001South Carolina Bioassay Certification #: 99030002Pennsylvania Certification #: 68-03578North Carolina Wastewater Certification #: 40
North Carolina Drinking Water Certification #: 37712North Carolina Bioassay Certification #: 9New Jersey Certification #: NC011Massachusetts Certification #: M-NC030Louisiana/LELAP Certification #: 03095Florida/NELAP Certification #: E87648West Virginia Certification #: 356
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 21
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE SUMMARY
Pace Project No.:
Project:
9260951
16143 Agrotec
Lab ID Sample ID Matrix Date Collected Date Received
9260951001 MW-2 Water 01/07/10 11:20 01/08/10 16:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 21
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
9260951
16143 Agrotec
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
9260951001 MW-2 MADEP EPH 7 PASI-CCAH
MADEP VPH 5 PASI-CDHW
EPA 200.7 1 PASI-AEWS
EPA 625 58 PASI-CSH
SM 6200B 64 PASI-CAW
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 4 of 21
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9260951
16143 Agrotec
Sample:MW-2 Lab ID:9260951001 Collected:01/07/10 11:20 Received:01/08/10 16:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
MADEP EPH NC Water Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)ND ug/L 1 01/15/10 18:0501/14/10 08:30119119
Aliphatic (C19-C36)ND ug/L 1 01/15/10 18:0501/14/10 08:30119119
Aromatic (C11-C22)ND ug/L 1 01/15/10 18:0501/14/10 08:30119119
Nonatriacontane (S)100 %1 01/15/10 18:05 7194-86-701/14/10 08:3040-140
o-Terphenyl (S)73 %1 01/15/10 18:05 84-15-101/14/10 08:3040-140
2-Fluorobiphenyl (S)74 %1 01/15/10 18:05 321-60-801/14/10 08:3040-140
2-Bromonaphthalene (S)59 %1 01/15/10 18:05 580-13-201/14/10 08:3040-140
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)ND ug/L 1 01/11/10 16:44100100
Aliphatic (C09-C12)ND ug/L 1 01/11/10 16:44100100
Aromatic (C09-C10)ND ug/L 1 01/11/10 16:44100100
2,5-Dibromotoluene (PID)(S)99 %1 01/11/10 16:4470-130
2,5-Dibromotoluene (FID)(S)103 %1 01/11/10 16:4470-130
200.7 MET ICP, 3030C Analytical Method: EPA 200.7 Preparation Method: SM 3030C
Lead 216 ug/L 1 01/13/10 22:14 7439-92-101/10/10 09:005.0 4.0
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
Acenaphthene ND ug/L 1 01/20/10 11:05 83-32-901/12/10 08:006.8 3.8
Acenaphthylene ND ug/L 1 01/20/10 11:05 208-96-801/12/10 08:006.8 3.8
Anthracene ND ug/L 1 01/20/10 11:05 120-12-701/12/10 08:006.8 3.9
Benzo(a)anthracene ND ug/L 1 01/20/10 11:05 56-55-301/12/10 08:006.8 3.8
Benzo(a)pyrene ND ug/L 1 01/20/10 11:05 50-32-801/12/10 08:006.8 4.2
Benzo(b)fluoranthene ND ug/L 1 01/20/10 11:05 205-99-201/12/10 08:006.8 4.9
Benzo(g,h,i)perylene ND ug/L 1 01/20/10 11:05 191-24-201/12/10 08:006.8 4.2
Benzo(k)fluoranthene ND ug/L 1 01/20/10 11:05 207-08-901/12/10 08:006.8 4.1
4-Bromophenylphenyl ether ND ug/L 1 01/20/10 11:05 101-55-301/12/10 08:006.8 3.2
Butylbenzylphthalate ND ug/L 1 01/20/10 11:05 85-68-701/12/10 08:006.8 3.9
4-Chloro-3-methylphenol 18.7 ug/L 1 01/20/10 11:05 59-50-701/12/10 08:006.8 3.8
bis(2-Chloroethoxy)methane ND ug/L 1 01/20/10 11:05 111-91-101/12/10 08:0013.5 7.8
bis(2-Chloroethyl) ether ND ug/L 1 01/20/10 11:05 111-44-401/12/10 08:006.8 6.5
bis(2-Chloroisopropyl) ether ND ug/L 1 01/20/10 11:05 108-60-101/12/10 08:006.8 5.4
2-Chloronaphthalene ND ug/L 1 01/20/10 11:05 91-58-701/12/10 08:006.8 4.9
2-Chlorophenol 9.0 ug/L 1 01/20/10 11:05 95-57-801/12/10 08:006.8 5.9
4-Chlorophenylphenyl ether ND ug/L 1 01/20/10 11:05 7005-72-301/12/10 08:006.8 3.6
Chrysene ND ug/L 1 01/20/10 11:05 218-01-901/12/10 08:006.8 3.6
Dibenz(a,h)anthracene ND ug/L 1 01/20/10 11:05 53-70-301/12/10 08:006.8 3.9
3,3'-Dichlorobenzidine 7.3 ug/L 1 01/20/10 11:05 91-94-101/12/10 08:006.8 4.6
2,4-Dichlorophenol ND ug/L 1 01/20/10 11:05 120-83-201/12/10 08:006.8 5.5
Diethylphthalate ND ug/L 1 01/20/10 11:05 84-66-201/12/10 08:006.8 3.6
2,4-Dimethylphenol 8.7J ug/L 1 01/20/10 11:05 105-67-901/12/10 08:0013.5 7.6
Dimethylphthalate ND ug/L 1 01/20/10 11:05 131-11-301/12/10 08:006.8 3.2
Di-n-butylphthalate ND ug/L 1 01/20/10 11:05 84-74-201/12/10 08:006.8 3.9
4,6-Dinitro-2-methylphenol ND ug/L 1 01/20/10 11:05 534-52-101/12/10 08:0027.0 10.5
2,4-Dinitrophenol ND ug/L 1 01/20/10 11:05 51-28-501/12/10 08:0067.6 13.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/25/2010 10:46 AM Page 5 of 21
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9260951
16143 Agrotec
Sample:MW-2 Lab ID:9260951001 Collected:01/07/10 11:20 Received:01/08/10 16:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
2,4-Dinitrotoluene ND ug/L 1 01/20/10 11:05 121-14-201/12/10 08:006.8 3.5
2,6-Dinitrotoluene ND ug/L 1 01/20/10 11:05 606-20-201/12/10 08:006.8 3.8
Di-n-octylphthalate ND ug/L 1 01/20/10 11:05 117-84-001/12/10 08:006.8 3.9
bis(2-Ethylhexyl)phthalate ND ug/L 1 01/20/10 11:05 117-81-701/12/10 08:006.8 2.8
Fluoranthene ND ug/L 1 01/20/10 11:05 206-44-001/12/10 08:006.8 3.9
Fluorene ND ug/L 1 01/20/10 11:05 86-73-701/12/10 08:006.8 3.5
Hexachloro-1,3-butadiene ND ug/L 1 01/20/10 11:05 87-68-301/12/10 08:006.8 4.5
Hexachlorobenzene ND ug/L 1 01/20/10 11:05 118-74-101/12/10 08:006.8 3.5
Hexachlorocyclopentadiene ND ug/L 1 01/20/10 11:05 77-47-401/12/10 08:0013.5 5.0
Hexachloroethane ND ug/L 1 01/20/10 11:05 67-72-101/12/10 08:006.8 4.5
Indeno(1,2,3-cd)pyrene ND ug/L 1 01/20/10 11:05 193-39-501/12/10 08:006.8 4.1
Isophorone ND ug/L 1 01/20/10 11:05 78-59-101/12/10 08:0013.5 8.8
Naphthalene ND ug/L 1 01/20/10 11:05 91-20-301/12/10 08:006.8 5.1
Nitrobenzene ND ug/L 1 01/20/10 11:05 98-95-301/12/10 08:006.8 5.9
2-Nitrophenol ND ug/L 1 01/20/10 11:05 88-75-501/12/10 08:006.8 6.2
4-Nitrophenol 50.1J ug/L 1 01/20/10 11:05 100-02-701/12/10 08:0067.6 2.7
N-Nitrosodimethylamine 15.7 ug/L 1 01/20/10 11:05 62-75-901/12/10 08:006.8 4.2
N-Nitroso-di-n-propylamine ND ug/L 1 01/20/10 11:05 621-64-701/12/10 08:006.8 5.0
N-Nitrosodiphenylamine ND ug/L 1 01/20/10 11:05 86-30-601/12/10 08:0013.5 8.9
Pentachlorophenol ND ug/L 1 01/20/10 11:05 87-86-501/12/10 08:0033.8 2.2
Phenanthrene ND ug/L 1 01/20/10 11:05 85-01-801/12/10 08:006.8 3.6
Phenol 8.7 ug/L 1 01/20/10 11:05 108-95-201/12/10 08:006.8 2.4
Pyrene ND ug/L 1 01/20/10 11:05 129-00-001/12/10 08:006.8 3.9
1,2,4-Trichlorobenzene ND ug/L 1 01/20/10 11:05 120-82-101/12/10 08:006.8 4.6
2,4,6-Trichlorophenol ND ug/L 1 01/20/10 11:05 88-06-201/12/10 08:0013.5 8.2
Nitrobenzene-d5 (S)45 %1 01/20/10 11:05 4165-60-001/12/10 08:0010-120
2-Fluorobiphenyl (S)51 %1 01/20/10 11:05 321-60-801/12/10 08:0015-120
Terphenyl-d14 (S)61 %1 01/20/10 11:05 1718-51-001/12/10 08:0011-131
Phenol-d6 (S)22 %1 01/20/10 11:05 13127-88-301/12/10 08:0010-120
2-Fluorophenol (S)31 %1 01/20/10 11:05 367-12-401/12/10 08:0010-120
2,4,6-Tribromophenol (S)62 %1 01/20/10 11:05 118-79-601/12/10 08:0010-137
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 01/12/10 01:47 71-43-20.50 0.50
Bromobenzene ND ug/L 1 01/12/10 01:47 108-86-10.50 0.50
Bromochloromethane ND ug/L 1 01/12/10 01:47 74-97-50.50 0.50
Bromodichloromethane ND ug/L 1 01/12/10 01:47 75-27-40.50 0.50
Bromoform ND ug/L 1 01/12/10 01:47 75-25-20.50 0.50
Bromomethane ND ug/L 1 01/12/10 01:47 74-83-95.0 1.0
n-Butylbenzene ND ug/L 1 01/12/10 01:47 104-51-80.50 0.50
sec-Butylbenzene ND ug/L 1 01/12/10 01:47 135-98-80.50 0.50
tert-Butylbenzene ND ug/L 1 01/12/10 01:47 98-06-60.50 0.50
Carbon tetrachloride ND ug/L 1 01/12/10 01:47 56-23-50.50 0.50
Chlorobenzene ND ug/L 1 01/12/10 01:47 108-90-70.50 0.50
Chloroethane ND ug/L 1 01/12/10 01:47 75-00-31.0 1.0
Chloroform ND ug/L 1 01/12/10 01:47 67-66-30.50 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/25/2010 10:46 AM Page 6 of 21
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9260951
16143 Agrotec
Sample:MW-2 Lab ID:9260951001 Collected:01/07/10 11:20 Received:01/08/10 16:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
Chloromethane ND ug/L 1 01/12/10 01:47 74-87-31.0 1.0
2-Chlorotoluene ND ug/L 1 01/12/10 01:47 95-49-80.50 0.50
4-Chlorotoluene ND ug/L 1 01/12/10 01:47 106-43-40.50 0.50
1,2-Dibromo-3-chloropropane ND ug/L 1 01/12/10 01:47 96-12-81.0 1.0
Dibromochloromethane ND ug/L 1 01/12/10 01:47 124-48-10.50 0.50
1,2-Dibromoethane (EDB)ND ug/L 1 01/12/10 01:47 106-93-40.50 0.50
Dibromomethane ND ug/L 1 01/12/10 01:47 74-95-30.50 0.50
1,2-Dichlorobenzene ND ug/L 1 01/12/10 01:47 95-50-10.50 0.50
1,3-Dichlorobenzene ND ug/L 1 01/12/10 01:47 541-73-10.50 0.50
1,4-Dichlorobenzene ND ug/L 1 01/12/10 01:47 106-46-70.50 0.50
Dichlorodifluoromethane ND ug/L 1 01/12/10 01:47 75-71-80.50 0.50
1,1-Dichloroethane ND ug/L 1 01/12/10 01:47 75-34-30.50 0.50
1,2-Dichloroethane ND ug/L 1 01/12/10 01:47 107-06-20.50 0.50
1,1-Dichloroethene ND ug/L 1 01/12/10 01:47 75-35-40.50 0.50
cis-1,2-Dichloroethene ND ug/L 1 01/12/10 01:47 156-59-20.50 0.50
trans-1,2-Dichloroethene ND ug/L 1 01/12/10 01:47 156-60-50.50 0.50
1,2-Dichloropropane ND ug/L 1 01/12/10 01:47 78-87-50.50 0.50
1,3-Dichloropropane ND ug/L 1 01/12/10 01:47 142-28-90.50 0.50
2,2-Dichloropropane ND ug/L 1 01/12/10 01:47 594-20-70.50 0.50
1,1-Dichloropropene ND ug/L 1 01/12/10 01:47 563-58-60.50 0.50
cis-1,3-Dichloropropene ND ug/L 1 01/12/10 01:47 10061-01-50.50 0.50
trans-1,3-Dichloropropene ND ug/L 1 01/12/10 01:47 10061-02-60.50 0.50
Diisopropyl ether ND ug/L 1 01/12/10 01:47 108-20-30.50 0.50
Ethylbenzene ND ug/L 1 01/12/10 01:47 100-41-40.50 0.50
Hexachloro-1,3-butadiene ND ug/L 1 01/12/10 01:47 87-68-32.0 2.0
Isopropylbenzene (Cumene)ND ug/L 1 01/12/10 01:47 98-82-80.50 0.50
Methylene Chloride ND ug/L 1 01/12/10 01:47 75-09-22.0 2.0
Methyl-tert-butyl ether ND ug/L 1 01/12/10 01:47 1634-04-40.50 0.50
Naphthalene ND ug/L 1 01/12/10 01:47 91-20-32.0 2.0
n-Propylbenzene ND ug/L 1 01/12/10 01:47 103-65-10.50 0.50
Styrene ND ug/L 1 01/12/10 01:47 100-42-50.50 0.50
1,1,1,2-Tetrachloroethane ND ug/L 1 01/12/10 01:47 630-20-60.50 0.50
1,1,2,2-Tetrachloroethane ND ug/L 1 01/12/10 01:47 79-34-50.50 0.50
Tetrachloroethene ND ug/L 1 01/12/10 01:47 127-18-40.50 0.50
Toluene ND ug/L 1 01/12/10 01:47 108-88-30.50 0.50
1,2,3-Trichlorobenzene ND ug/L 1 01/12/10 01:47 87-61-62.0 2.0
1,2,4-Trichlorobenzene ND ug/L 1 01/12/10 01:47 120-82-12.0 2.0
1,1,1-Trichloroethane ND ug/L 1 01/12/10 01:47 71-55-60.50 0.50
1,1,2-Trichloroethane ND ug/L 1 01/12/10 01:47 79-00-50.50 0.50
Trichloroethene ND ug/L 1 01/12/10 01:47 79-01-60.50 0.50
Trichlorofluoromethane ND ug/L 1 01/12/10 01:47 75-69-41.0 1.0
1,2,3-Trichloropropane ND ug/L 1 01/12/10 01:47 96-18-40.50 0.50
1,2,4-Trimethylbenzene ND ug/L 1 01/12/10 01:47 95-63-60.50 0.50
1,3,5-Trimethylbenzene ND ug/L 1 01/12/10 01:47 108-67-80.50 0.50
Vinyl chloride ND ug/L 1 01/12/10 01:47 75-01-41.0 1.0
m&p-Xylene ND ug/L 1 01/12/10 01:47 1330-20-71.0 1.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/25/2010 10:46 AM Page 7 of 21
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9260951
16143 Agrotec
Sample:MW-2 Lab ID:9260951001 Collected:01/07/10 11:20 Received:01/08/10 16:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
o-Xylene ND ug/L 1 01/12/10 01:47 95-47-60.50 0.50
1,2-Dichloroethane-d4 (S)97 %1 01/12/10 01:47 17060-07-070-130
Dibromofluoromethane (S)98 %1 01/12/10 01:47 1868-53-770-130
4-Bromofluorobenzene (S)98 %1 01/12/10 01:47 460-00-470-130
Toluene-d8 (S)100 %1 01/12/10 01:47 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/25/2010 10:46 AM Page 8 of 21
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9260951
16143 Agrotec
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/9042
MADEP EPH
MADEP EPH
MADEP EPH NC Water
Associated Lab Samples:9260951001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:390279
Associated Lab Samples:9260951001
Matrix:Water
Analyzed
Aliphatic (C09-C18)ug/L ND 100 01/15/10 16:25
Aliphatic (C19-C36)ug/L ND 100 01/15/10 16:25
Aromatic (C11-C22)ug/L ND 100 01/15/10 16:25
2-Bromonaphthalene (S)%74 40-140 01/15/10 16:25
2-Fluorobiphenyl (S)%86 40-140 01/15/10 16:25
Nonatriacontane (S)%102 40-140 01/15/10 16:25
o-Terphenyl (S)%81 40-140 01/15/10 16:25
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
390280LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
390281
Aliphatic (C09-C18)ug/L 173 1g3005840-14060179 3 50
Aliphatic (C19-C36)ug/L 313400 78 40-14085340 8 50
Aromatic (C11-C22)ug/L 604850 71 40-14073620 3 50
2-Bromonaphthalene (S)%66 40-14067
2-Fluorobiphenyl (S)%76 40-14080
Nonatriacontane (S)%98 40-14092
o-Terphenyl (S)%71 40-14069
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/25/2010 10:46 AM Page 9 of 21
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9260951
16143 Agrotec
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GCV/3764
MADEP VPH
MADEP VPH
VPH NC Water
Associated Lab Samples:9260951001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:388970
Associated Lab Samples:9260951001
Matrix:Water
Analyzed
Aliphatic (C05-C08)ug/L ND 100 01/11/10 15:54
Aliphatic (C09-C12)ug/L ND 100 01/11/10 15:54
Aromatic (C09-C10)ug/L ND 100 01/11/10 15:54
2,5-Dibromotoluene (FID)(S)%102 70-130 01/11/10 15:54
2,5-Dibromotoluene (PID)(S)%97 70-130 01/11/10 15:54
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
388971LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
388972
Aliphatic (C05-C08)ug/L 294300 98 70-130101304 3 25
Aliphatic (C09-C12)ug/L 299300 100 30-130114341 13 25
Aromatic (C09-C10)ug/L ND100 96 70-130101101 25
2,5-Dibromotoluene (FID)(S)%109 70-130115
2,5-Dibromotoluene (PID)(S)%108 70-130111
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/25/2010 10:46 AM Page 10 of 21
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9260951
16143 Agrotec
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/5653
SM 3030C
EPA 200.7
200.7 MET 3030C
Associated Lab Samples:9260951001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:388814
Associated Lab Samples:9260951001
Matrix:Water
Analyzed
Lead ug/L ND 5.0 01/13/10 21:55
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
388815LABORATORY CONTROL SAMPLE:
LCSSpike
Lead ug/L 471500 94 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
388816MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9260951001
388817
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Lead ug/L 500 70 70-13075 5 20500216564592
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
9260955001
388818SAMPLE DUPLICATE:
Lead ug/L 338 10 20307
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/25/2010 10:46 AM Page 11 of 21
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9260951
16143 Agrotec
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/9022
EPA 625
EPA 625
625 MSS
Associated Lab Samples:9260951001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:389100
Associated Lab Samples:9260951001
Matrix:Water
Analyzed
1,2,4-Trichlorobenzene ug/L ND 5.0 01/19/10 21:23
2,4,6-Trichlorophenol ug/L ND 10.0 01/19/10 21:23
2,4-Dichlorophenol ug/L ND 5.0 01/19/10 21:23
2,4-Dimethylphenol ug/L ND 10.0 01/19/10 21:23
2,4-Dinitrophenol ug/L ND 50.0 01/19/10 21:23
2,4-Dinitrotoluene ug/L ND 5.0 01/19/10 21:23
2,6-Dinitrotoluene ug/L ND 5.0 01/19/10 21:23
2-Chloronaphthalene ug/L ND 5.0 01/19/10 21:23
2-Chlorophenol ug/L ND 5.0 01/19/10 21:23
2-Nitrophenol ug/L ND 5.0 01/19/10 21:23
3,3'-Dichlorobenzidine ug/L ND 5.0 01/19/10 21:23
4,6-Dinitro-2-methylphenol ug/L ND 20.0 01/19/10 21:23
4-Bromophenylphenyl ether ug/L ND 5.0 01/19/10 21:23
4-Chloro-3-methylphenol ug/L ND 5.0 01/19/10 21:23
4-Chlorophenylphenyl ether ug/L ND 5.0 01/19/10 21:23
4-Nitrophenol ug/L ND 50.0 01/19/10 21:23
Acenaphthene ug/L ND 5.0 01/19/10 21:23
Acenaphthylene ug/L ND 5.0 01/19/10 21:23
Anthracene ug/L ND 5.0 01/19/10 21:23
Benzo(a)anthracene ug/L ND 5.0 01/19/10 21:23
Benzo(a)pyrene ug/L ND 5.0 01/19/10 21:23
Benzo(b)fluoranthene ug/L ND 5.0 01/19/10 21:23
Benzo(g,h,i)perylene ug/L ND 5.0 01/19/10 21:23
Benzo(k)fluoranthene ug/L ND 5.0 01/19/10 21:23
bis(2-Chloroethoxy)methane ug/L ND 10.0 01/19/10 21:23
bis(2-Chloroethyl) ether ug/L ND 5.0 01/19/10 21:23
bis(2-Chloroisopropyl) ether ug/L ND 5.0 01/19/10 21:23
bis(2-Ethylhexyl)phthalate ug/L ND 5.0 01/19/10 21:23
Butylbenzylphthalate ug/L ND 5.0 01/19/10 21:23
Chrysene ug/L ND 5.0 01/19/10 21:23
Di-n-butylphthalate ug/L ND 5.0 01/19/10 21:23
Di-n-octylphthalate ug/L ND 5.0 01/19/10 21:23
Dibenz(a,h)anthracene ug/L ND 5.0 01/19/10 21:23
Diethylphthalate ug/L ND 5.0 01/19/10 21:23
Dimethylphthalate ug/L ND 5.0 01/19/10 21:23
Fluoranthene ug/L ND 5.0 01/19/10 21:23
Fluorene ug/L ND 5.0 01/19/10 21:23
Hexachloro-1,3-butadiene ug/L ND 5.0 01/19/10 21:23
Hexachlorobenzene ug/L ND 5.0 01/19/10 21:23
Hexachlorocyclopentadiene ug/L ND 10.0 01/19/10 21:23
Hexachloroethane ug/L ND 5.0 01/19/10 21:23
Indeno(1,2,3-cd)pyrene ug/L ND 5.0 01/19/10 21:23
Isophorone ug/L ND 10.0 01/19/10 21:23
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/25/2010 10:46 AM Page 12 of 21
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9260951
16143 Agrotec
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:389100
Associated Lab Samples:9260951001
Matrix:Water
Analyzed
N-Nitroso-di-n-propylamine ug/L ND 5.0 01/19/10 21:23
N-Nitrosodimethylamine ug/L ND 5.0 01/19/10 21:23
N-Nitrosodiphenylamine ug/L ND 10.0 01/19/10 21:23
Naphthalene ug/L ND 5.0 01/19/10 21:23
Nitrobenzene ug/L ND 5.0 01/19/10 21:23
Pentachlorophenol ug/L ND 25.0 01/19/10 21:23
Phenanthrene ug/L ND 5.0 01/19/10 21:23
Phenol ug/L ND 5.0 01/19/10 21:23
Pyrene ug/L ND 5.0 01/19/10 21:23
2,4,6-Tribromophenol (S)%38 10-137 01/19/10 21:23
2-Fluorobiphenyl (S)%32 15-120 01/19/10 21:23
2-Fluorophenol (S)%19 10-120 01/19/10 21:23
Nitrobenzene-d5 (S)%32 10-120 01/19/10 21:23
Phenol-d6 (S)%13 10-120 01/19/10 21:23
Terphenyl-d14 (S)%38 11-131 01/19/10 21:23
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
389101LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
389102
1,2,4-Trichlorobenzene ug/L 17.0 L2,R1503444-1422110.6 46 30
2,4,6-Trichlorophenol ug/L 33.550 67 37-1445326.3 24 30
2,4-Dichlorophenol ug/L 30.6 R150611-1914120.4 40 30
2,4-Dimethylphenol ug/L 21.9 L2,R1504432-1192211.0 67 30
2,4-Dinitrophenol ug/L 161250 64 1-18156141 13 30
2,4-Dinitrotoluene ug/L 37.550 75 39-1396231.1 19 30
2,6-Dinitrotoluene ug/L 37.450 75 50-1586230.9 19 30
2-Chloronaphthalene ug/L 26.2 L2,R1505260-1184019.9 27 30
2-Chlorophenol ug/L 18.5 R1503723-1342311.4 48 30
2-Nitrophenol ug/L 29.3 R1505929-1823718.6 45 30
3,3'-Dichlorobenzidine ug/L 35.350 71 1-2625929.3 19 30
4,6-Dinitro-2-methylphenol ug/L 73.8100 74 1-1816161.2 19 30
4-Bromophenylphenyl ether ug/L 35.250 70 53-1275829.0 19 30
4-Chloro-3-methylphenol ug/L 49.1100 49 22-1473838.3 25 30
4-Chlorophenylphenyl ether ug/L 32.950 66 25-1585427.1 19 30
4-Nitrophenol ug/L 28.5J250 11 1-132922.9J 30
Acenaphthene ug/L 30.750 61 47-1455024.8 21 30
Acenaphthylene ug/L 31.250 62 33-1455025.0 22 30
Anthracene ug/L 35.750 71 1-1665929.7 19 30
Benzo(a)anthracene ug/L 34.850 70 33-1435829.2 17 30
Benzo(a)pyrene ug/L 35.250 70 17-1635929.4 18 30
Benzo(b)fluoranthene ug/L 36.650 73 24-1595829.1 23 30
Benzo(g,h,i)perylene ug/L 29.050 58 1-2194723.3 22 30
Benzo(k)fluoranthene ug/L 39.250 78 11-1626532.5 19 30
bis(2-Chloroethoxy)methane ug/L 28.4 R1505733-1843818.9 40 30
bis(2-Chloroethyl) ether ug/L 25.4 R1505112-1583216.0 45 30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/25/2010 10:46 AM Page 13 of 21
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9260951
16143 Agrotec
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
389101LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
389102
bis(2-Chloroisopropyl) ether ug/L 23.9 L2,R1504836-1663115.6 42 30
bis(2-Ethylhexyl)phthalate ug/L 33.150 66 8-1585627.9 17 30
Butylbenzylphthalate ug/L 35.050 70 1-1525828.9 19 30
Chrysene ug/L 36.150 72 17-1686030.2 18 30
Di-n-butylphthalate ug/L 34.950 70 1-1185829.0 18 30
Di-n-octylphthalate ug/L 36.950 74 4-1466030.2 20 30
Dibenz(a,h)anthracene ug/L 33.050 66 1-2275427.0 20 30
Diethylphthalate ug/L 35.750 71 1-1145929.5 19 30
Dimethylphthalate ug/L 35.350 71 1-1125929.4 18 30
Fluoranthene ug/L 37.050 74 26-1376130.7 19 30
Fluorene ug/L 33.6 L2506759-1215627.8 19 30
Hexachloro-1,3-butadiene ug/L 9.5 L2,R1501924-116126.2 42 30
Hexachlorobenzene ug/L 34.850 70 1-1525829.1 18 30
Hexachlorocyclopentadiene ug/L 11.7 L2,R1502325-150157.7J 30
Hexachloroethane ug/L 7.4 L2,R1501540-113105.0 39 30
Indeno(1,2,3-cd)pyrene ug/L 31.250 62 1-1715125.7 20 30
Isophorone ug/L 32.250 64 21-1964823.8 30 30
N-Nitroso-di-n-propylamine ug/L 30.5 R150611-2304321.3 36 30
N-Nitrosodimethylamine ug/L 3.9J L2,R150825-1505ND 30
N-Nitrosodiphenylamine ug/L 36.550 73 25-1506030.0 20 30
Naphthalene ug/L 23.8 R1504821-1333015.0 45 30
Nitrobenzene ug/L 27.5 R1505535-1803517.5 45 30
Pentachlorophenol ug/L 174250 70 14-17658145 18 30
Phenanthrene ug/L 35.050 70 54-1205829.0 19 30
Phenol ug/L 4.1J50 8 5-11252.5J 30
Pyrene ug/L 35.350 71 52-1155829.2 19 30
2,4,6-Tribromophenol (S)%71 10-13759
2-Fluorobiphenyl (S)%62 15-12046
2-Fluorophenol (S)%32 10-12018
Nitrobenzene-d5 (S)%55 10-12035
Phenol-d6 (S)%25 10-12013
Terphenyl-d14 (S)%72 11-13156
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/25/2010 10:46 AM Page 14 of 21
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9260951
16143 Agrotec
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/9611
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:9260951001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:388889
Associated Lab Samples:9260951001
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 01/11/10 23:56
1,1,1-Trichloroethane ug/L ND 0.50 01/11/10 23:56
1,1,2,2-Tetrachloroethane ug/L ND 0.50 01/11/10 23:56
1,1,2-Trichloroethane ug/L ND 0.50 01/11/10 23:56
1,1-Dichloroethane ug/L ND 0.50 01/11/10 23:56
1,1-Dichloroethene ug/L ND 0.50 01/11/10 23:56
1,1-Dichloropropene ug/L ND 0.50 01/11/10 23:56
1,2,3-Trichlorobenzene ug/L ND 2.0 01/11/10 23:56
1,2,3-Trichloropropane ug/L ND 0.50 01/11/10 23:56
1,2,4-Trichlorobenzene ug/L ND 2.0 01/11/10 23:56
1,2,4-Trimethylbenzene ug/L ND 0.50 01/11/10 23:56
1,2-Dibromo-3-chloropropane ug/L ND 1.0 01/11/10 23:56
1,2-Dibromoethane (EDB)ug/L ND 0.50 01/11/10 23:56
1,2-Dichlorobenzene ug/L ND 0.50 01/11/10 23:56
1,2-Dichloroethane ug/L ND 0.50 01/11/10 23:56
1,2-Dichloropropane ug/L ND 0.50 01/11/10 23:56
1,3,5-Trimethylbenzene ug/L ND 0.50 01/11/10 23:56
1,3-Dichlorobenzene ug/L ND 0.50 01/11/10 23:56
1,3-Dichloropropane ug/L ND 0.50 01/11/10 23:56
1,4-Dichlorobenzene ug/L ND 0.50 01/11/10 23:56
2,2-Dichloropropane ug/L ND 0.50 01/11/10 23:56
2-Chlorotoluene ug/L ND 0.50 01/11/10 23:56
4-Chlorotoluene ug/L ND 0.50 01/11/10 23:56
Benzene ug/L ND 0.50 01/11/10 23:56
Bromobenzene ug/L ND 0.50 01/11/10 23:56
Bromochloromethane ug/L ND 0.50 01/11/10 23:56
Bromodichloromethane ug/L ND 0.50 01/11/10 23:56
Bromoform ug/L ND 0.50 01/11/10 23:56
Bromomethane ug/L ND 5.0 01/11/10 23:56
Carbon tetrachloride ug/L ND 0.50 01/11/10 23:56
Chlorobenzene ug/L ND 0.50 01/11/10 23:56
Chloroethane ug/L ND 1.0 01/11/10 23:56
Chloroform ug/L ND 0.50 01/11/10 23:56
Chloromethane ug/L ND 1.0 01/11/10 23:56
cis-1,2-Dichloroethene ug/L ND 0.50 01/11/10 23:56
cis-1,3-Dichloropropene ug/L ND 0.50 01/11/10 23:56
Dibromochloromethane ug/L ND 0.50 01/11/10 23:56
Dibromomethane ug/L ND 0.50 01/11/10 23:56
Dichlorodifluoromethane ug/L ND 0.50 01/11/10 23:56
Diisopropyl ether ug/L ND 0.50 01/11/10 23:56
Ethylbenzene ug/L ND 0.50 01/11/10 23:56
Hexachloro-1,3-butadiene ug/L ND 2.0 01/11/10 23:56
Isopropylbenzene (Cumene)ug/L ND 0.50 01/11/10 23:56
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/25/2010 10:46 AM Page 15 of 21
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9260951
16143 Agrotec
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:388889
Associated Lab Samples:9260951001
Matrix:Water
Analyzed
m&p-Xylene ug/L ND 1.0 01/11/10 23:56
Methyl-tert-butyl ether ug/L ND 0.50 01/11/10 23:56
Methylene Chloride ug/L ND 2.0 01/11/10 23:56
n-Butylbenzene ug/L ND 0.50 01/11/10 23:56
n-Propylbenzene ug/L ND 0.50 01/11/10 23:56
Naphthalene ug/L ND 2.0 01/11/10 23:56
o-Xylene ug/L ND 0.50 01/11/10 23:56
sec-Butylbenzene ug/L ND 0.50 01/11/10 23:56
Styrene ug/L ND 0.50 01/11/10 23:56
tert-Butylbenzene ug/L ND 0.50 01/11/10 23:56
Tetrachloroethene ug/L ND 0.50 01/11/10 23:56
Toluene ug/L ND 0.50 01/11/10 23:56
trans-1,2-Dichloroethene ug/L ND 0.50 01/11/10 23:56
trans-1,3-Dichloropropene ug/L ND 0.50 01/11/10 23:56
Trichloroethene ug/L ND 0.50 01/11/10 23:56
Trichlorofluoromethane ug/L ND 1.0 01/11/10 23:56
Vinyl chloride ug/L ND 1.0 01/11/10 23:56
1,2-Dichloroethane-d4 (S)%99 70-130 01/11/10 23:56
4-Bromofluorobenzene (S)%101 70-130 01/11/10 23:56
Dibromofluoromethane (S)%97 70-130 01/11/10 23:56
Toluene-d8 (S)%99 70-130 01/11/10 23:56
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
388890LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.850 102 60-140
1,1,1-Trichloroethane ug/L 49.550 99 60-140
1,1,2,2-Tetrachloroethane ug/L 49.650 99 60-140
1,1,2-Trichloroethane ug/L 49.950 100 60-140
1,1-Dichloroethane ug/L 48.350 97 60-140
1,1-Dichloroethene ug/L 48.550 97 60-140
1,1-Dichloropropene ug/L 46.950 94 60-140
1,2,3-Trichlorobenzene ug/L 49.250 98 60-140
1,2,3-Trichloropropane ug/L 47.750 95 60-140
1,2,4-Trichlorobenzene ug/L 49.050 98 60-140
1,2,4-Trimethylbenzene ug/L 49.550 99 60-140
1,2-Dibromo-3-chloropropane ug/L 47.550 95 60-140
1,2-Dibromoethane (EDB)ug/L 49.850 100 60-140
1,2-Dichlorobenzene ug/L 48.850 98 60-140
1,2-Dichloroethane ug/L 49.050 98 60-140
1,2-Dichloropropane ug/L 49.450 99 60-140
1,3,5-Trimethylbenzene ug/L 50.650 101 60-140
1,3-Dichlorobenzene ug/L 48.750 97 60-140
1,3-Dichloropropane ug/L 49.850 100 60-140
1,4-Dichlorobenzene ug/L 48.350 97 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/25/2010 10:46 AM Page 16 of 21
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9260951
16143 Agrotec
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
388890LABORATORY CONTROL SAMPLE:
LCSSpike
2,2-Dichloropropane ug/L 43.550 87 60-140
2-Chlorotoluene ug/L 49.250 98 60-140
4-Chlorotoluene ug/L 49.650 99 60-140
Benzene ug/L 50.150 100 60-140
Bromobenzene ug/L 48.750 97 60-140
Bromochloromethane ug/L 42.550 85 60-140
Bromodichloromethane ug/L 51.450 103 60-140
Bromoform ug/L 51.650 103 60-140
Bromomethane ug/L 33.950 68 60-140
Carbon tetrachloride ug/L 52.950 106 60-140
Chlorobenzene ug/L 48.350 97 60-140
Chloroethane ug/L 45.650 91 60-140
Chloroform ug/L 48.950 98 60-140
Chloromethane ug/L 48.450 97 60-140
cis-1,2-Dichloroethene ug/L 49.550 99 60-140
cis-1,3-Dichloropropene ug/L 51.350 103 60-140
Dibromochloromethane ug/L 51.550 103 60-140
Dibromomethane ug/L 48.550 97 60-140
Dichlorodifluoromethane ug/L 29.0 L0505860-140
Diisopropyl ether ug/L 50.650 101 60-140
Ethylbenzene ug/L 49.450 99 60-140
Hexachloro-1,3-butadiene ug/L 50.350 101 60-140
Isopropylbenzene (Cumene)ug/L 49.750 99 60-140
m&p-Xylene ug/L 99.2100 99 60-140
Methyl-tert-butyl ether ug/L 50.550 101 60-140
Methylene Chloride ug/L 50.650 101 60-140
n-Butylbenzene ug/L 50.650 101 60-140
n-Propylbenzene ug/L 50.750 101 60-140
Naphthalene ug/L 47.150 94 60-140
o-Xylene ug/L 49.350 99 60-140
sec-Butylbenzene ug/L 49.950 100 60-140
Styrene ug/L 50.450 101 60-140
tert-Butylbenzene ug/L 49.650 99 60-140
Tetrachloroethene ug/L 48.350 97 60-140
Toluene ug/L 48.650 97 60-140
trans-1,2-Dichloroethene ug/L 48.650 97 60-140
trans-1,3-Dichloropropene ug/L 52.850 106 60-140
Trichloroethene ug/L 48.450 97 60-140
Trichlorofluoromethane ug/L 41.350 83 60-140
Vinyl chloride ug/L 40.950 82 60-140
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%99 70-130
Dibromofluoromethane (S)%103 70-130
Toluene-d8 (S)%99 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/25/2010 10:46 AM Page 17 of 21
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9260951
16143 Agrotec
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
389080MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9260940011
389081
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 110 60-140120 8 3020ND22.0 23.9
1,1,1-Trichloroethane ug/L 20 120 60-140128 6 3020ND24.0 25.6
1,1,2,2-Tetrachloroethane ug/L 20 105 60-140119 12 3020ND21.1 23.7
1,1,2-Trichloroethane ug/L 20 111 60-140123 11 3020ND22.2 24.7
1,1-Dichloroethane ug/L 20 112 60-140122 9 3020ND22.4 24.4
1,1-Dichloroethene ug/L 20 121 60-140126 4 3020ND24.3 25.2
1,1-Dichloropropene ug/L 20 108 60-140112 3 3020ND21.7 22.3
1,2,3-Trichlorobenzene ug/L 20 102 60-140130 24 3020ND20.6 26.2
1,2,3-Trichloropropane ug/L 20 106 60-140120 13 3020ND21.2 24.0
1,2,4-Trichlorobenzene ug/L 20 107 60-140125 16 3020ND21.5 25.2
1,2,4-Trimethylbenzene ug/L 20 119 60-140118 1 302026.7 50.5 50.3
1,2-Dibromo-3-chloropropane ug/L 20 103 60-140127 21 3020ND20.5 25.4
1,2-Dibromoethane (EDB)ug/L 20 107 60-140120 11 3020ND21.5 23.9
1,2-Dichlorobenzene ug/L 20 110 60-140121 10 3020ND22.0 24.2
1,2-Dichloroethane ug/L 20 109 60-140118 8 3020ND21.8 23.6
1,2-Dichloropropane ug/L 20 111 60-140118 6 3020ND22.3 23.7
1,3,5-Trimethylbenzene ug/L 20 116 60-140121 3 30209.8 33.0 34.0
1,3-Dichlorobenzene ug/L 20 110 60-140117 6 3020ND21.9 23.3
1,3-Dichloropropane ug/L 20 111 60-140120 8 3020ND22.2 24.0
1,4-Dichlorobenzene ug/L 20 109 60-140116 6 3020ND21.8 23.3
2,2-Dichloropropane ug/L 20 105 60-140112 7 3020ND21.0 22.4
2-Chlorotoluene ug/L 20 116 60-140124 7 3020ND23.3 24.9
4-Chlorotoluene ug/L 20 117 60-140124 6 3020ND23.4 24.8
Benzene ug/L 20 114 60-140116 1 30207.3 30.1 30.5
Bromobenzene ug/L 20 115 60-140122 6 3020ND22.9 24.3
Bromochloromethane ug/L 20 95 60-140105 10 3020ND18.9 20.9
Bromodichloromethane ug/L 20 109 60-140116 7 3020ND21.7 23.2
Bromoform ug/L 20 111 60-140127 13 3020ND22.3 25.4
Bromomethane ug/L 20 84 60-14094 12 3020ND16.7 18.9
Carbon tetrachloride ug/L 20 131 60-140138 5 3020ND26.2 27.6
Chlorobenzene ug/L 20 115 60-140120 4 3020ND23.0 24.1
Chloroethane ug/L M02014260-140145 2 3020ND28.4 29.0
Chloroform ug/L 20 110 60-140115 4 3020ND22.1 22.9
Chloromethane ug/L M02015560-140157 1 3020ND31.0 31.4
cis-1,2-Dichloroethene ug/L 20 117 60-140126 8 3020ND23.3 25.2
cis-1,3-Dichloropropene ug/L 20 111 60-140118 6 3020ND22.2 23.6
Dibromochloromethane ug/L 20 107 60-140118 10 3020ND21.5 23.6
Dibromomethane ug/L 20 112 60-140125 10 3020ND22.5 25.0
Dichlorodifluoromethane ug/L M02026760-140281 5 3020ND53.5 56.1
Diisopropyl ether ug/L 20 109 60-140119 8 30200.83 22.7 24.7
Ethylbenzene ug/L 20 111 60-140111 0 302018.2 40.3 40.4
Hexachloro-1,3-butadiene ug/L 20 108 60-140113 5 3020ND21.7 22.9
Isopropylbenzene (Cumene)ug/L 20 116 60-140124 6 30202.7 25.9 27.4
m&p-Xylene ug/L 40 114 60-140114 0 304030.5 76.0 76.1
Methyl-tert-butyl ether ug/L 20 112 60-140118 3 302016.0 38.3 39.7
Methylene Chloride ug/L 20 109 60-140117 7 3020ND21.8 23.5
n-Butylbenzene ug/L 20 107 60-140120 11 30201.7 23.0 25.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/25/2010 10:46 AM Page 18 of 21
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9260951
16143 Agrotec
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
389080MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9260940011
389081
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
n-Propylbenzene ug/L 20 118 60-140125 5 30203.9 27.6 29.0
Naphthalene ug/L 20 104 60-140134 20 30206.2 27.1 33.0
o-Xylene ug/L 20 113 60-140119 5 30204.4 27.0 28.2
sec-Butylbenzene ug/L M02023660-140235 1 3020ND47.2 46.9
Styrene ug/L 20 114 60-140124 8 3020ND22.8 24.7
tert-Butylbenzene ug/L 20 115 60-140127 10 3020ND23.0 25.3
Tetrachloroethene ug/L 20 115 60-140120 4 3020ND23.0 24.1
Toluene ug/L 20 112 60-140115 2 30204.8 27.2 27.8
trans-1,2-Dichloroethene ug/L 20 115 60-140121 5 3020ND23.1 24.2
trans-1,3-Dichloropropene ug/L 20 116 60-140126 8 3020ND23.3 25.1
Trichloroethene ug/L 20 113 60-140119 5 3020ND22.6 23.9
Trichlorofluoromethane ug/L 20 122 60-140128 4 3020ND24.5 25.5
Vinyl chloride ug/L M02014860-140152 3 3020ND29.6 30.4
1,2-Dichloroethane-d4 (S)%98 70-13099
4-Bromofluorobenzene (S)%100 70-13099
Dibromofluoromethane (S)%101 70-130102
Toluene-d8 (S)%100 70-130100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/25/2010 10:46 AM Page 19 of 21
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALIFIERS
Pace Project No.:
Project:
9260951
16143 Agrotec
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution ofthe sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes.
U - Indicates the compound was analyzed for, but not detected.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Aromatic breakthrough present in LCSD exceeds method requirement. Batch refractionated.1g
Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0
Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated
samples may be biased low.L2
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/25/2010 10:46 AM Page 20 of 21
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
9260951
16143 Agrotec
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
9260951001 OEXT/9042 GCSV/7021MW-2 MADEP EPH MADEP EPH
9260951001 GCV/3764MW-2 MADEP VPH
9260951001 MPRP/5653 ICP/5231MW-2 SM 3030C EPA 200.7
9260951001 OEXT/9022 MSSV/3277MW-2 EPA 625 EPA 625
9260951001 MSV/9611MW-2 SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 01/25/2010 10:46 AM Page 21 of 21
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]