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HomeMy WebLinkAbout10054_Lexington Home Brands Plant 1_VI Assessment Report_20200420#C-1269 Engineering #C-245 Geology Brownfields Assessment Report Lexington Home Brands Plant #1 411 South Salisbury Street Lexington, Davidson County, North Carolina Brownfields Project No. 10054-06-029 H&H Job No. CLX-003 April 20, 2020 4/20/2020 i Brownfields Assessment Report Lexington Home Brands Plant #1 411 South Salisbury Street Lexington, Davidson County, North Carolina Brownfields Project No. 10054-06-029 H&H Job No. CLX-003 Table of Contents 1.0 Introduction .............................................................................................................................1 1.1 Previous Assessment Activities .............................................................................................2 2.0 Vapor Intrusion Assessment Activities .................................................................................4 2.1 Sub-Slab Soil Gas Sampling Activities .................................................................................4 2.2 Sub-Slab Soil Gas Sample Analytical Results ......................................................................6 2.3 Evaluation of Vapor Intrusion Assessment Results ..............................................................6 3.0 Summary and Conclusions.....................................................................................................8 List of Tables Table 1 Summary of Sub-Slab Soil Gas Analytical Results List of Figures Figure 1 Site Location Map Figure 2 Site Map and Sample Location Map List of Appendices Appendix A Laboratory Analytical Reports Appendix B DEQ Risk Calculators 1 \\hhfs01\MasterFiles\AAA-Master Projects\City of Lexington - CLX\CLX-003\VI Assessment Report - Bull City + GMB\Final to DEQ\Brownfields Assessment Report_BPN 10054-06-029_4-15-2020.doc Brownfields Assessment Report Lexington Home Brands Plant #1 411 South Salisbury Street Lexington, Davidson County, North Carolina Brownfields Project No. 10054-06-029 H&H Job No. CLX-003 1.0 Introduction On behalf of The City of Lexington (the Prospective Developer or PD), Hart & Hickman, PC (H&H) has prepared this report to document vapor intrusion assessment activities completed at the Lexington Home Brands Plant #1 Brownfields property (Brownfields Project No. 10054-06- 029) located at 411 South Salisbury Street, Lexington, Davidson County, North Carolina (subject Site or Site). The Site consists of nine parcels of land that total approximately 20.5 acres and historically operated as a furniture manufacturer dating back to the early 1900s. A Brownfields Agreement (BFA) for the Site was recorded on April 13, 2016. A Site location map is included as Figure 1. Future redevelopment plans at the Site could potentially include modifications to existing structures located on PIN 6725-02-75-7565 and PIN 6725-02-85-1844 and construction of a passenger rail station on PIN 6725-02-85-3701 and a small area on the northeastern portion of PIN 6725-04-74-2825. The western portion of PIN 6725-04-74-2825 is currently being leased to Lexington Home Brands who have performed warehousing since 2007. With the exception of Lexington Home Brands, redevelopment plans for parcels with existing structures are currently in the early conceptual stages but could possibly include retail uses and/or an agricultural research center with laboratory research. Due to the infancy of the redevelopment planning process for these parcels, potential structural vapor intrusion should be evaluated at a future date, if warranted. Current redevelopment plans at the Site include modifications to the approximately 33,500 square foot (sq ft) existing Bull City Ciderworks brewery/taproom facility (Davidson County Parcel Identification Number [PIN] 6725-02-75-3197) located at 599 S. Salisbury St. In addition, the approximately 10,110 sq ft existing building located at 401 S. Railroad Street (PIN 2 \\hhfs01\MasterFiles\AAA-Master Projects\City of Lexington - CLX\CLX-003\VI Assessment Report - Bull City + GMB\Final to DEQ\Brownfields Assessment Report_BPN 10054-06-029_4-15-2020.doc 6725-02-75-6185) has been recently upfitted to house the new Goose & the Monkey Brewhouse. Specifically, proposed redevelopment plans for Bull City Ciderworks, which is owned by Cider Bros LLC as of December 20, 2019, include upfit of the current taproom to a conditioned retail space, modifications to the existing warehouse to include new roll-up doors and ventilation equipment, and expansion into the adjacent vacant structure to the east for the purpose of constructing an outdoor seating area. Remaining structures on the Bull City Ciderworks parcel will be demolished for future parking. Redevelopment plans for the Goose & the Monkey Brewhouse, which is owned by Goose and the Monkey Brewhouse Holdings LLC as of March 17, 2020, included upfit of the existing structure for a brewery/taproom and construction of an outdoor seating area and parking areas. A Site map showing existing and proposed tenant occupancy information is included as Figure 2. 1.1 Previous Assessment Activities In 2009, H&H conducted assessment activities to investigate areas of potential environmental concern relative to historical operations. These areas included: a former finishing plant, paint/varnish storage and mixing areas, and a boiler room (Study Area 1); a former 550-gallon gasoline underground storage tank (UST) (Study Area 2 – general vicinity of the Goose & The Monkey Brewhouse); and a former block storage building, wood processing area, kilns, and a former gasoline UST (Study Area 3 – east of Bull City Ciderworks). Results of the Study Area 1 assessment indicated impacts of petroleum related compounds above regulatory screening criteria in several soil and groundwater samples. This portion of the Brownfields property was redeveloped as an amphitheater and soil and groundwater impacts were managed under a North Carolina Department of Environmental Quality (DEQ) approved Environmental Management Plan (EMP) dated September 29, 2016. Results of the Study Area 2 assessment indicated impacts of petroleum related compounds above regulatory screening criteria in groundwater sample SB-27 collected near the former gasoline UST (Figure 2). The petroleum release received a notice of No Further Action on January 3, 2005 following recording of a Notice of Residual Petroleum. However, to evaluate the potential 3 \\hhfs01\MasterFiles\AAA-Master Projects\City of Lexington - CLX\CLX-003\VI Assessment Report - Bull City + GMB\Final to DEQ\Brownfields Assessment Report_BPN 10054-06-029_4-15-2020.doc for structural vapor intrusion into the Goose & the Monkey Brewhouse, H&H utilized Study Area 2 groundwater results and the May 2019 DEQ Risk Calculator. Results of the groundwater to indoor air risk evaluation indicated exceedances of acceptable non-residential risk levels (cumulative lifetime incremental cancer risk [LICR] threshold of 1 x 10-4 and cumulative non-carcinogenic hazard index [HI] threshold of 1). Results of the Study Area 3 assessment did not indicate impacts of constituents of concern above regulatory screening criteria. However, portions of the Bull City Ciderworks facility are located within approximately 100 ft of potential groundwater impacts associated with Study Area 2. Consistent with the March 2018 DEQ Division of Waste Management (DWM) Vapor Intrusion Guidance document and the BFA’s Land Use Restriction (LUR) No. 5, H&H has conducted this Brownfields assessment to evaluate the potential for structural vapor intrusion risk into the Bull City Ciderworks and the Goose & the Monkey Brewhouse buildings. H&H conducted the assessment in general accordance with the DEQ approved Brownfields Assessment Work Plan – Revision 1 (Work Plan), dated October 25, 2019. A summary of Brownfields assessment activities conducted is provided in the following sections. 4 \\hhfs01\MasterFiles\AAA-Master Projects\City of Lexington - CLX\CLX-003\VI Assessment Report - Bull City + GMB\Final to DEQ\Brownfields Assessment Report_BPN 10054-06-029_4-15-2020.doc 2.0 Vapor Intrusion Assessment Activities On October 16 and 17, 2019, H&H completed vapor intrusion assessment activities at the Site to evaluate the potential for structural vapor intrusion into the existing Bull City Ciderworks and the Goose & the Monkey Brewhouse buildings. Prior to conducting field activities, H&H contacted North Carolina 811, the public utility locator, to mark subsurface utilities at the Site. H&H also contracted with a private utility locator to mark utilities which were not identified by the public locator. The assessment activities were performed in general accordance with the DEQ approved Work Plan, the DEQ Inactive Hazardous Sites Branch (IHSB) Guidelines for Assessment and Cleanup (Guidelines) dated October 2015 and January 2020, the DEQ DWM Vapor Intrusion Guidance (VI Guidance) dated March 2018, and most recent versions of the U.S. Environmental Protection Agency (EPA) Region IV Science and Ecosystem Support Division (SESD) Field Branches Quality System and Technical Procedures guidance. As part of assessment activities, two sub-slab soil gas samples (SG-1 and SG-2) were collected from the Goose & the Monkey Brewhouse building and five sub-slab soil gas samples (SG-3 through SG-7) were collected from the Bull City Ciderworks building. In addition, seven indoor air samples (IA-1 through IA-7) were collected in areas co-located with the sub-slab soil gas samples and placed on hold pending sub-slab soil gas sample analytical results. Note that based on sub-slab soil gas analytical results (see Section 2.2), indoor air samples were not analyzed per the DEQ approved Work Plan. The sub-slab soil gas locations (denoted by SG nomenclature) are shown in Figure 2. 2.1 Sub-Slab Soil Gas Sampling Activities The sub-slab soil gas sample points were installed by utilizing a hammer drill and a 1½-inch diameter drill bit to advance a pilot hole into the concrete slab to a depth of approximately 1¾ inches below the surface. A drill guide was then placed in the pilot hole, and a 5/8-inch diameter drill bit was utilized to advance the boring through the concrete slab. 5 \\hhfs01\MasterFiles\AAA-Master Projects\City of Lexington - CLX\CLX-003\VI Assessment Report - Bull City + GMB\Final to DEQ\Brownfields Assessment Report_BPN 10054-06-029_4-15-2020.doc Following concrete borehole advancement, loose concrete cuttings were removed from the boring. A Cox-Colvin Vapor Pin™ (vapor pin) assembly (brass sampling point and silicone sleeve) was seated in the borehole using an installation/extraction tool and hammer. The vapor pins were installed as flush-mount sample points capable of being secured with a stainless-steel cover that screws onto the sampling point and is seated within the pilot hole annulus. The vapor pin sampling points were allowed at least two hours for equilibration after installation before sampling was conducted. A sampling train for each point was constructed using a Teflon® tubing, disposable fittings/valves, and a laboratory-supplied 1.4-liter stainless steel Summa sample canister. Prior to sampling, a leak check was conducted at the soil gas monitoring points by constructing a shroud around the entire monitoring point and sampling train, and flooding the air within the shroud with helium gas. Helium concentrations inside the shroud were measured using a helium gas detector. Using a syringe and disposable valves/fittings, the Teflon tubing and sampling train was purged of approximately three sample volumes. Following purging, a sample was collected from the sample tubing outside the shroud into a Tedlar® bag and analyzed using the helium gas detector to ensure that helium concentrations were less than 10% of the helium concentrations in the shroud. Following a successful leak check, the intake valve of the canister was fully opened to begin collection of the sub-slab vapor sample. The airflow regulator for each cannister was pre-set by the laboratory to regulate the vapor intake rate to approximately 200 milliliters per minute. Vacuum readings on the Summa canister were recorded prior to and following the approximately ten-minute sampling period to ensure adequate sample volume was collected. Per laboratory standard operating procedures, a vacuum was maintained within the canisters at the conclusion of the sampling event. H&H attempted to collect a duplicate sub-slab soil gas sample from the SG-5 parent sample. However, the laboratory-supplied flow controller and fittings did not pass the helium leak check conducted prior to sampling and the sample was therefore omitted. Note the SG-5 parent sample successfully passed a leak check after removal of the attempted duplicate sample cannister/flow 6 \\hhfs01\MasterFiles\AAA-Master Projects\City of Lexington - CLX\CLX-003\VI Assessment Report - Bull City + GMB\Final to DEQ\Brownfields Assessment Report_BPN 10054-06-029_4-15-2020.doc controller. After sample collection, the Summa canister’s valves were closed prior to the regulator being disconnected from the canister and the Summa canisters were then placed in laboratory supplied shipping containers, properly labeled, and shipped under standard chain-of-custody protocols to Enthalpy Analytical, LLC (Enthalpy) for analysis of volatile organic compounds (VOCs) by EPA Method TO-15. The TO-15 analysis was conducted using method detection limits below DEQ Residential Soil Gas Screening Levels (SGSLs). Upon completion of sampling activities, each sub-slab vapor boring was secured with a stainless- steel cover that screws onto the sampling point and is seated within the pilot hole annulus. 2.2 Sub-Slab Soil Gas Sample Analytical Results Results of sub-slab soil gas analyses are summarized in Table 1. The laboratory analytical report and chain of custody record are provided in Appendix A. Sub-slab soil gas sample analytical results were compared to the February 2018 DEQ Residential and Non-Residential SGSLs. Laboratory analytical results indicate that VOCs were detected in each sub-slab soil gas sample at concentrations above the laboratory method detection limits. However, no compounds were detected at concentrations that exceed their respective Non-Residential SGSLs. Chloroform was detected in sub-slab soil gas sample SG-1 (Goose & the Monkey Brewhouse) at a concentration of 41.8 micrograms per cubic meter [µg/m3], which is slightly above the Residential SGSL of 41.0 µg/m3. No other compounds were detected at concentrations that exceed Residential SGSLs. 2.3 Evaluation of Vapor Intrusion Assessment Results Consistent with proposed redevelopment at the Site, H&H utilized the December 2019 DEQ Risk Calculator to calculate both non-residential and residential cumulative risks to further evaluate potential structural vapor intrusion risks for each of the on-Site buildings. 7 \\hhfs01\MasterFiles\AAA-Master Projects\City of Lexington - CLX\CLX-003\VI Assessment Report - Bull City + GMB\Final to DEQ\Brownfields Assessment Report_BPN 10054-06-029_4-15-2020.doc Cumulative risk calculations were performed using the highest concentration of each compound detected above the laboratory method detection limit from the soil gas samples collected in each building as a worst-case scenario. Therefore, samples SG-1 and SG-2 were used to calculate the cumulative risk for the Goose & the Monkey Brewhouse facility and samples SG-3 through SG- 7 were used to calculate the cumulative risk for the Bull City Ciderworks facility. The completed risk calculators are provided in Appendix B. For the Bull City Ciderworks facility, the results of non-residential risk calculations indicated a cumulative LICR of 5.1 x 10-8 and a cumulative HI of 0.0044. The results of risk calculations for a resident scenario indicated a cumulative LICR of 7.7 x 10-7 and a cumulative HI of 0.056. For the Goose & the Monkey Brewhouse, the results of non-residential risk calculations indicated a cumulative LICR of 9.1 x 10-7 and a cumulative HI of 0.0070. The results of risk calculations for a resident scenario indicated a cumulative LICR of 1.2 x 10-5 and a cumulative HI of 0.089. The above referenced calculated cumulative risk values for both facilities do not exceed a LICR of 1 x 10-4 or a HI of 1 for the soil gas to indoor air vapor intrusion pathway for residential and non-residential land use scenarios. Based on evaluation of the December 2019 DEQ risk calculator results, there is no evidence of a vapor intrusion concern for the Bull City Ciderworks and the Goose & the Monkey Brewhouse buildings. 8 \\hhfs01\MasterFiles\AAA-Master Projects\City of Lexington - CLX\CLX-003\VI Assessment Report - Bull City + GMB\Final to DEQ\Brownfields Assessment Report_BPN 10054-06-029_4-15-2020.doc 3.0 Summary and Conclusions H&H has completed Brownfields vapor intrusion assessment activities at the Lexington Home Brands Plant #1 Brownfields property located in Lexington, North Carolina. The assessment activities were conducted in general accordance with the DEQ Brownfields approved Work Plan dated October 25, 2019 and the BFA’s LUR No. 5. Brownfields assessment activities included collection of sub-slab soil gas samples from the Bull City Ciderworks and the Goose & the Monkey Brewhouse buildings. With the exception of chloroform in the sub-slab soil gas sample collected from SG-1 in the Goose & the Monkey Brewhouse building, results of soil vapor assessment activities did not identify any additional compounds at concentrations that exceed the Residential and Non- Residential SGSLs. In addition, December 2019 DEQ risk calculator results indicate that calculated cumulative risk values for the soil gas to indoor air vapor intrusion pathway for residential and non-residential worker scenarios are within the acceptable lifetime incremental cancer risk of 1 x 10-4 to 1 x 10-6 and less than a hazard index of 1. In summary, results of soil vapor intrusion assessment activities indicate that structural vapor intrusion into the Bull City Ciderworks and the Goose & the Monkey Brewhouse buildings does not pose a significant risk and does not warrant further assessment in accordance with the DEQ DWM Vapor Intrusion Guidance. Further, vapor mitigation measures do not appear warranted for these buildings. Tables Table 1Summary of Sub-Slab Soil Gas Analytical Results Brownfields Project No. 10054-06-029 Lexington Home Brands Plant #1 411 South Salisbury Street Lexington, North Carolina H&H Job No. CLX.003 File: \\hhfs01\MasterFiles\AAA-Master Projects\City of Lexington - CLX\CLX-003\VI Assessment Report - Bull City + GMB\Tables\Vapor Intrusion Assessment Summary Table_Lexington Home Brands_11-14-2019Date: 3/30/2020 Table 1 (Page 1 of 1) Hart & Hickman, PC Sample ID SG-1 SG-2 SG-3 SG-4 SG-5 SG-6 SG-7 Sample Location Sampling Date 10/17/19 10/17/19 10/17/19 10/17/19 10/17/19 10/17/19 10/17/19 Units VOCs (TO-15) 1,2,4-Trimethylbenzene 1.04 1.04 1.76 1.58 1.79 0.957 1.45 420 5,300 1,3,5-Trimethylbenzene <0.366 <0.433 0.519 0.485 0.562 <0.359 0.417 420 5,300 1,3-Butadiene 0.271 1.25 <0.179 <0.165 <0.165 <0.161 <0.164 14 180 1,4-Dichlorobenzene 0.484 J 0.555 J <0.488 <0.449 <0.450 <0.439 <0.445 85 1,100 cis-1,2-Dichloroethene <0.296 <0.349 <0.322 0.319 J <0.297 <0.289 <0.293 NE NE 1,4-Dioxane <0.269 <0.317 0.328 J <0.269 <0.270 <0.263 <0.267 190 2,500 2-Hexanone (Methyl butyl ketone)1.45 1.36 1.08 1.03 0.750 1.55 1.21 210 2,600 4-Ethyltoluene <0.366 <0.433 0.485 0.463 0.535 <0.359 0.370 J NE NE Acetone 81.7 89.6 40.0 204 62.8 123 402 220,000 2,700,000 Benzene 1.01 3.36 1.13 0.700 0.608 0.669 0.578 120 1,600 Benzyl chloride 0.888 <0.456 <0.420 <0.387 <0.387 <0.378 <0.383 7.0 88 Bromomethane 0.641 <0.342 <0.315 <0.290 <0.290 <0.283 <0.287 35 440 Carbon disulfide 8.83 3.08 5.06 0.456 0.395 0.358 12.2 4,900 61,000 Carbon tetrachloride 0.577 <0.554 <0.510 <0.470 <0.471 <0.459 <0.465 160 2,000 Chloroethane 1.62 <0.232 <0.214 <0.197 <0.197 <0.192 <0.195 70,000 880,000 Chloroethene (Vinyl chloride)<0.191 <0.225 <0.207 0.350 0.462 <0.186 <0.189 56 2,800 Chloroform 41.8 1.38 0.500 <0.365 <0.365 0.578 1.48 41 530 Chloromethane 5.21 <0.182 <0.168 <0.154 <0.154 <0.151 <0.153 630 7,900 Cyclohexane 1.91 6.08 8.60 4.46 5.67 4.93 2.81 42,000 530,000 Ethanol 36.4 55.3 72.9 120 188 161 110 NE NE Ethyl acetate <0.269 <0.317 <0.292 <0.269 0.876 0.280 J 0.356 490 6,100 Ethylbenzene 1.12 0.885 2.07 1.34 1.78 0.797 0.835 370 4,900 Freon 11 (CCl3F)18.2 26.0 5.42 5.07 4.91 4.30 2.79 NE NE Freon 113 (C2Cl3F3)<0.571 <0.674 <0.622 <0.573 0.577 J 0.578 J <0.567 NE NE Freon 12 (CCl2F2)2.34 1.99 2.38 2.55 2.63 2.81 2.49 700 8,800 Heptane 18.1 7.40 1.18 0.609 0.583 <0.299 0.939 2,800 35,000 Hexane 17.5 7.04 11.3 6.70 11.5 2.58 2.82 4,900 61,000 Isopropyl alcohol 30.8 34.7 57.4 66.2 63.1 37.7 33.6 1,400 18,000 Methyl ethyl ketone (2-Butanone)19.5 8.02 13.4 24.9 18.3 22.4 32.1 35,000 440,000 Methyl isobutyl ketone 1.18 1.12 2.73 2.58 1.47 1.90 1.46 21,000 260,000 Methyl tert-butyl ether <0.269 1.14 1.07 <0.269 <0.270 <0.263 <0.267 3,600 47,000 Methylene chloride 1.01 <0.885 <0.816 <0.751 <0.752 <0.733 <0.744 4,200 53,000 Naphthalene 0.403 J 1.04 <0.425 <0.392 <0.392 <0.382 <0.388 21 260 Propylene 10.7 9.96 1.48 1.05 1.02 1.03 1.21 21,000 260,000 Styrene 0.415 <0.375 0.547 0.352 J 0.466 0.315 J <0.315 7,000 88,000 Tetrachloroethene 3.09 <0.597 0.936 19.2 27.8 6.07 4.00 280 3,500 Tetrahydrofuran 1.40 1.21 1.83 2.02 2.81 0.883 1.03 14,000 180,000 Toluene 4.75 3.16 43.4 21.6 46.0 11.5 11.8 35,000 440,000 Trichloroethene <0.401 <0.473 <0.436 <0.402 <0.402 2.40 <0.398 14 180 m-/p-Xylenes 3.20 2.79 7.24 4.74 5.82 2.61 2.73 700 8,800o-Xylene 1.78 1.79 4.11 1.97 2.53 1.10 1.02 700 8,800 Notes: 1) NC Department of Environmental Quality (DEQ) Division of Waste Management (DWM) Sub-slab and Exterior Soil Gas Screening Levels (SGSLs) (February 2018). Compound concentrations are reported in micrograms per cubic meter (μg/m3). Bold values indicate exceedances of Residential SGSLs. Only compounds detected in at least one sample are shown. Laboratory analytical method shown in parentheses. J = compound detected above the laboratory method detection limit, but below the laboratory reporting limit resulting in an estimated concentration. VOCs = volatile organic compounds; µg/m3 = micrograms per cubic meter; NE = not established; < = Less than Laboratory Method Detection Limit. Residential SGSLs(1)Non-Residential SGSLs(1)Goose & The Monkey Brewhouse 401 S. Railroad Street Bull City Ciderworks Brewery & Taproom 599 S. Salisbury Street µg/m3 Figures TITLE PROJECT SITE LOCATION MAP Former Lexington Home Brands – Plant # 1 411 South Salisbury StreetLexington, North Carolina DATE: JOB NO: REVISION NO: FIGURE NO: 09-06-19 0 1CLX-003 0 2000 4000 APPROXIMATE SCALE IN FEETN U.S.G.S. QUADRANGLE MAP QUADRANGLE 7.5 MINUTE SERIES (TOPOGRAPHIC) LEXINGTON WEST, NORTH CAROLINA 1994 SITE S. SALI SBU RY STRE ET S. MAIN ST R EET E. F I F T H A V E N U E E . FOU R T H A V E N U E E. S I X T H A V E N U E E . S E V E N T H A V E N U E ACCESS DRIVEWAYPUBLIC ROAD EASEMENT(S. RAILROAD STREET) LEXINGTON HOME BRANDSWAREHOUSES PROPOSED LOCATION OFAGRICULTURALRESEARCH CENTER(CURRENTLY VACANT) THE GOOSE & THE MONKEY BREWHOUSE VACANT PARKING LOT VACANTBUILDING OUTDOORAMPHITHEATER S. RAI L R O A D S T R E E T ELK S T R E E TE. TH IRD AV E N U E E. TH IRD AVENUEE. F IFTH AVENUE EXTENS IONS. STATE STREET E. SECOND AVENUEPROPOSED FUTURE BULLCITY CIDERWORKSOUTDOOR SEATING AREA BULL CITY CIDERWORKSWAREHOUSE THE GOOSE & THE MONKEY PARKING AREA BULL CITY CIDERWORKSRETAIL AREA THE GOOSE & THE MONKEY OUTDOOR SEATING AREA PROPOSED FUTURE LOCATIONOF BULL CITY CIDERWORKS PARKING AREA (CURRENTLY VACANT AND PROPOSED FORDEMOLITION) REVISION NO. 0 JOB NO. CLX-003 DATE: 4-6-20 FIGURE NO. 2 LEXINGTON HOME BRANDS PLANT #1411 SOUTH SALISBURY STREET LEXINGTON, NORTH CAROLINA SITE MAP AND SAMPLE LOCATION MAP LEGEND BROWNFIELDS PROPERTY BOUNDARY PARCEL BOUNDARY RAILROAD RAILROAD EASEMENT BROWNFIELDS PROPERTY PARCELSUBDIVISION (ACCORDING TO DAVIDSONCOUNTY GIS) AREA OF POTENTIAL SOIL CONTAMINATION PERRECORDED BROWNFIELDS PLAT (8/21/15) GROUNDWATER SAMPLE LOCATION (2009 BROWNFIELDS ASSESSMENT) SUB-SLAB SOIL GAS SAMPLE LOCATION 3921 Sunset Ridge Road, Suite 301 Raleigh, North Carolina 27607 919-847-4241(p) 919-847-4261(f) License # C-1269 / #C-245 Geology NOTES: 1. ALL LOCATIONS ARE APPROXIMATE. 2. BASEMAP PARCEL BOUNDARIES ACQUIRED FROMDAVIDSON COUNTY GIS (2019). 3. BROWNFIELDS PROPERTY BOUNDARIES AND AREAS OF KNOWN CONTAMINATION ACQUIRED FROM RECORDEDBROWNFIELDS PLAT (8/21/15). 4. AERIAL IMAGERY OBTAINED FROM GOOGLE EARTH (2019). SB-27 PIN: 6725-02-75-3197 PIN: 6725-02-75-7565 PIN: 6725-02-75-9908 PIN: 6725-04-74-2825 PIN: 6725-02-75-6185 PIN: 6725-02-85-3701 PIN: 6725-02-85-4923 SG-3SG-4 SG-5 SG-6 SG-7 SG-1 SG-2 PIN: 6725-02-85-1844 PIN: 6725-02-75-5375 S:\AAA-Master Projects\Piedmont Triad COG - PTC\PTC-003 Brownfield Phase II\Figures\PTC-003 Phase II Figure 2 Alt2_4.6.20.dwg, FIG 2 (2), 4/6/2020 5:30:15 PM, SVincent Appendix A Laboratory Analytical Reports Hart & Hickman - Raleigh 3921 Sunset Ridge Road, Suite 301 Raleigh, NC 27607 Lexington Brownfields Client Project # CLX-003 Analytical Report (0919-153) EPA Method TO15 Analysis TO-15 Target Compound List Enthalpy Analytical, LLC Phone: (919) 850 - 4392 / Fax: (919) 850 - 9012 / www.enthalpy.com 800-1 Capitola Drive Durham, NC 27713 I certify that to the best of my knowledge all analytical data presented in this report: • Have been checked for completeness • Are accurate, error-free, and legible • Have been conducted in accordance with approved protocol, and that all deviations and analytical problems are summarized in the appropriate narrative(s) This analytical report was prepared in Portable Document Format (.PDF) and contains 42 pages. Report Issued: 10/31/2019 Results Quantitation Report Enthalpy Analytical, LLC Sample Name : SG-1 Sample Info : 0919-153, can#198, 500mL load Data File : X1904156.D Dilution : 1 Pressurization Factor : 2.130 Acquisition Date : 2019-10-22 12:46:42 Instrument Method : TO15-SCN.M Matrix : AIR Target Compound Concentration (PPBV) RL (PPBV) MDL (PPBV) Concentration (ug/m3) RL (ug/m3) MDL (ug/m3)Flag * Propylene 6.20 0.0817 0.0746 10.7 0.141 0.128 m Freon 12 (CCl2F2)0.474 0.0832 0.0746 2.34 0.411 0.369 Freon 114 (C2Cl2F4)ND 0.0853 0.0746 ND 0.596 0.521 Chloromethane 2.52 0.0831 0.0746 5.21 0.172 0.154 Chloroethene (Vinyl chloride)ND 0.0857 0.0746 ND 0.219 0.191 1,3-Butadiene 0.122 0.0832 0.0746 0.271 0.184 0.165 Bromomethane 0.165 0.0843 0.0746 0.641 0.327 0.289 Chloroethane 0.614 0.0859 0.0746 1.62 0.227 0.197 Freon 11 (CCl3F)3.25 0.0884 0.0746 18.2 0.497 0.419 Ethanol 19.3 0.213 0.0852 36.4 0.401 0.161 Freon 113 (C2Cl3F3)ND 0.0848 0.0746 ND 0.650 0.571 1,1-Dichloroethene ND 0.0853 0.0746 ND 0.338 0.296 Acetone 34.4 0.0856 0.0746 81.7 0.203 0.177 Carbon disulfide 2.83 0.0855 0.0746 8.83 0.266 0.232 Isopropyl alcohol 12.5 0.0855 0.0746 30.8 0.210 0.183 Methylene chloride 0.291 0.216 0.216 1.01 0.750 0.750 trans-1,2-Dichloroethene ND 0.0868 0.0746 ND 0.344 0.296 Methyl tert-butyl ether ND 0.0872 0.0746 ND 0.315 0.269 Hexane 4.96 0.0861 0.0746 17.5 0.304 0.263 1,1-Dichloroethane ND 0.0839 0.0746 ND 0.340 0.302 Vinyl acetate ND 0.0866 0.0746 ND 0.305 0.262 cis-1,2-Dichloroethene ND 0.0858 0.0746 ND 0.340 0.296 Methyl ethyl ketone (2-Butanone)6.61 0.0866 0.0746 19.5 0.255 0.220 Ethyl acetate ND 0.0858 0.0746 ND 0.309 0.269 Chloroform 8.56 0.0861 0.0746 41.8 0.421 0.364 Tetrahydrofuran 0.473 0.0860 0.0746 1.40 0.254 0.220 1,1,1-Trichloroethane ND 0.0848 0.0746 ND 0.463 0.407 Cyclohexane 0.556 0.0866 0.0746 1.91 0.298 0.257 Carbon tetrachloride 0.0917 0.0862 0.0746 0.577 0.542 0.469 Benzene 0.317 0.0850 0.0746 1.01 0.272 0.238 1,2-Dichloroethane ND 0.0871 0.0746 ND 0.352 0.302 Heptane 4.41 0.0856 0.0746 18.1 0.351 0.306 Trichloroethene ND 0.0855 0.0746 ND 0.460 0.401 1,2-Dichloropropane ND 0.0871 0.0746 ND 0.402 0.345 1,4-Dioxane ND 0.0861 0.0746 ND 0.310 0.269 Bromodichloromethane ND 0.0846 0.0746 ND 0.567 0.500 cis-1,3-Dichloropropene ND 0.0838 0.0746 ND 0.380 0.338 Methyl isobutyl ketone 0.289 0.0878 0.0746 1.18 0.360 0.305 Toluene 1.26 0.0866 0.0746 4.75 0.326 0.281 trans-1,3-Dichloropropene ND 0.0866 0.0746 ND 0.393 0.338 1,1,2-Trichloroethane ND 0.0854 0.0746 ND 0.466 0.407 Tetrachloroethene 0.456 0.0860 0.0746 3.09 0.583 0.506 2-Hexanone (Methyl butyl ketone)0.354 0.0866 0.0746 1.45 0.355 0.305 Dibromochloromethane ND 0.0841 0.0746 ND 0.716 0.635 1,2-Dibromoethane ND 0.0863 0.0746 ND 0.663 0.573 Chlorobenzene ND 0.0877 0.0746 ND 0.404 0.343 Ethylbenzene 0.257 0.0838 0.0746 1.12 0.364 0.324 m-/p-Xylenes 0.736 0.0863 0.0746 3.20 0.375 0.324 o-Xylene 0.409 0.0851 0.0746 1.78 0.370 0.324 Styrene 0.0974 0.0830 0.0746 0.415 0.353 0.318 Bromoform ND 0.0855 0.0746 ND 0.884 0.771 1,1,2,2-Tetrachloroethane ND 0.0852 0.0746 ND 0.585 0.512 4-Ethyltoluene ND 0.0858 0.0746 ND 0.422 0.366 1,3,5-Trimethylbenzene ND 0.0855 0.0746 ND 0.420 0.366 1,2,4-Trimethylbenzene 0.213 0.0847 0.0746 1.04 0.416 0.366 m 1,3-Dichlorobenzene ND 0.0860 0.0746 ND 0.517 0.448 Quantitation Report Enthalpy Analytical, LLC Sample Name : SG-1 Sample Info : 0919-153, can#198, 500mL load Data File : X1904156.D Dilution : 1 Pressurization Factor : 2.130 Acquisition Date : 2019-10-22 12:46:42 Instrument Method : TO15-SCN.M Matrix : AIR Target Compound Concentration (PPBV) RL (PPBV) MDL (PPBV) Concentration (ug/m3) RL (ug/m3) MDL (ug/m3)Flag * 1,4-Dichlorobenzene 0.0805 0.0855 0.0746 0.484 0.514 0.448 J Benzyl chloride 0.172 0.0850 0.0746 0.888 0.440 0.386 1,2-Dichlorobenzene ND 0.0868 0.0746 ND 0.522 0.448 1,2,4-Trichlorobenzene ND 0.0865 0.0746 ND 0.642 0.553 Hexachlorobutadiene ND 0.0854 0.0746 ND 0.910 0.795 Naphthalene 0.0769 0.0882 0.0746 0.403 0.462 0.391 J Internal Standards Response Retention Time (min) Concentration (PPBV)Flag * Bromochloromethane (IS)435,914 11.92 5.00 PASS 1,4-Difluorobenzene (IS)1,645,519 13.67 5.04 PASS Chlorobenzene-d5 (IS)1,462,001 17.85 4.80 PASS (ND) = Not Detected * (J) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40% Quantitation Report Enthalpy Analytical, LLC Sample Name : SG-2 Sample Info : 0919-153, can#898, 500mL load Data File : X1904157.D Dilution : 1 Pressurization Factor : 2.514 Acquisition Date : 2019-10-22 13:42:37 Instrument Method : TO15-SCN.M Matrix : AIR Target Compound Concentration (PPBV) RL (PPBV) MDL (PPBV) Concentration (ug/m3) RL (ug/m3) MDL (ug/m3)Flag * Propylene 5.79 0.0964 0.0880 9.96 0.166 0.151 Freon 12 (CCl2F2)0.402 0.0981 0.0880 1.99 0.485 0.435 Freon 114 (C2Cl2F4)ND 0.101 0.0880 ND 0.704 0.615 Chloromethane ND 0.0980 0.0880 ND 0.202 0.182 Chloroethene (Vinyl chloride)ND 0.101 0.0880 ND 0.259 0.225 1,3-Butadiene 0.563 0.0982 0.0880 1.25 0.217 0.195 Bromomethane ND 0.0995 0.0880 ND 0.386 0.342 Chloroethane ND 0.101 0.0880 ND 0.267 0.232 Freon 11 (CCl3F)4.63 0.104 0.0880 26.0 0.586 0.494 Ethanol 29.3 0.251 0.101 55.3 0.474 0.189 Freon 113 (C2Cl3F3)ND 0.100 0.0880 ND 0.767 0.674 1,1-Dichloroethene ND 0.101 0.0880 ND 0.399 0.349 Acetone 37.7 0.101 0.0880 89.6 0.240 0.209 Carbon disulfide 0.989 0.101 0.0880 3.08 0.314 0.274 Isopropyl alcohol 14.1 0.101 0.0880 34.7 0.248 0.216 Methylene chloride ND 0.255 0.255 ND 0.885 0.885 trans-1,2-Dichloroethene ND 0.102 0.0880 ND 0.406 0.349 Methyl tert-butyl ether 0.317 0.103 0.0880 1.14 0.371 0.317 Hexane 2.00 0.102 0.0880 7.04 0.358 0.310 1,1-Dichloroethane ND 0.0991 0.0880 ND 0.401 0.356 Vinyl acetate ND 0.102 0.0880 ND 0.360 0.310 cis-1,2-Dichloroethene ND 0.101 0.0880 ND 0.402 0.349 Methyl ethyl ketone (2-Butanone)2.72 0.102 0.0880 8.02 0.301 0.259 Ethyl acetate ND 0.101 0.0880 ND 0.365 0.317 Chloroform 0.282 0.102 0.0880 1.38 0.496 0.430 Tetrahydrofuran 0.411 0.101 0.0880 1.21 0.299 0.259 1,1,1-Trichloroethane ND 0.100 0.0880 ND 0.546 0.480 Cyclohexane 1.77 0.102 0.0880 6.08 0.352 0.303 m Carbon tetrachloride ND 0.102 0.0880 ND 0.640 0.554 Benzene 1.05 0.100 0.0880 3.36 0.321 0.281 1,2-Dichloroethane ND 0.103 0.0880 ND 0.416 0.356 Heptane 1.81 0.101 0.0880 7.40 0.414 0.361 Trichloroethene ND 0.101 0.0880 ND 0.543 0.473 1,2-Dichloropropane ND 0.103 0.0880 ND 0.475 0.407 1,4-Dioxane ND 0.102 0.0880 ND 0.366 0.317 Bromodichloromethane ND 0.0999 0.0880 ND 0.669 0.590 cis-1,3-Dichloropropene ND 0.0989 0.0880 ND 0.449 0.399 Methyl isobutyl ketone 0.272 0.104 0.0880 1.12 0.425 0.360 Toluene 0.837 0.102 0.0880 3.16 0.385 0.332 trans-1,3-Dichloropropene ND 0.102 0.0880 ND 0.464 0.399 1,1,2-Trichloroethane ND 0.101 0.0880 ND 0.550 0.480 Tetrachloroethene ND 0.101 0.0880 ND 0.688 0.597 2-Hexanone (Methyl butyl ketone)0.331 0.102 0.0880 1.36 0.419 0.360 Dibromochloromethane ND 0.0993 0.0880 ND 0.845 0.750 1,2-Dibromoethane ND 0.102 0.0880 ND 0.783 0.676 Chlorobenzene ND 0.103 0.0880 ND 0.476 0.405 Ethylbenzene 0.204 0.0990 0.0880 0.885 0.430 0.382 m-/p-Xylenes 0.642 0.102 0.0880 2.79 0.442 0.382 o-Xylene 0.412 0.100 0.0880 1.79 0.436 0.382 Styrene ND 0.0979 0.0880 ND 0.417 0.375 Bromoform ND 0.101 0.0880 ND 1.04 0.910 1,1,2,2-Tetrachloroethane ND 0.101 0.0880 ND 0.690 0.604 4-Ethyltoluene ND 0.101 0.0880 ND 0.498 0.433 1,3,5-Trimethylbenzene ND 0.101 0.0880 ND 0.496 0.433 1,2,4-Trimethylbenzene 0.212 0.100 0.0880 1.04 0.491 0.433 m 1,3-Dichlorobenzene ND 0.101 0.0880 ND 0.610 0.529 Quantitation Report Enthalpy Analytical, LLC Sample Name : SG-2 Sample Info : 0919-153, can#898, 500mL load Data File : X1904157.D Dilution : 1 Pressurization Factor : 2.514 Acquisition Date : 2019-10-22 13:42:37 Instrument Method : TO15-SCN.M Matrix : AIR Target Compound Concentration (PPBV) RL (PPBV) MDL (PPBV) Concentration (ug/m3) RL (ug/m3) MDL (ug/m3)Flag * 1,4-Dichlorobenzene 0.0923 0.101 0.0880 0.555 0.606 0.529 J Benzyl chloride ND 0.100 0.0880 ND 0.520 0.456 1,2-Dichlorobenzene ND 0.102 0.0880 ND 0.616 0.529 1,2,4-Trichlorobenzene ND 0.102 0.0880 ND 0.757 0.653 Hexachlorobutadiene ND 0.101 0.0880 ND 1.07 0.938 Naphthalene 0.198 0.104 0.0880 1.04 0.546 0.461 Internal Standards Response Retention Time (min) Concentration (PPBV)Flag * Bromochloromethane (IS)437,964 11.92 5.00 PASS 1,4-Difluorobenzene (IS)1,651,849 13.67 5.04 PASS Chlorobenzene-d5 (IS)1,386,630 17.85 4.80 PASS (ND) = Not Detected * (J) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40% Quantitation Report Enthalpy Analytical, LLC Sample Name : SG-3 Sample Info : 0919-153, can#580, 500mL load Data File : X1904158.D Dilution : 1 Pressurization Factor : 2.318 Acquisition Date : 2019-10-22 14:35:56 Instrument Method : TO15-SCN.M Matrix : AIR Target Compound Concentration (PPBV) RL (PPBV) MDL (PPBV) Concentration (ug/m3) RL (ug/m3) MDL (ug/m3)Flag * Propylene 0.860 0.0889 0.0811 1.48 0.153 0.140 Freon 12 (CCl2F2)0.482 0.0905 0.0811 2.38 0.448 0.401 Freon 114 (C2Cl2F4)ND 0.0928 0.0811 ND 0.649 0.567 Chloromethane ND 0.0904 0.0811 ND 0.187 0.168 Chloroethene (Vinyl chloride)ND 0.0933 0.0811 ND 0.238 0.207 1,3-Butadiene ND 0.0906 0.0811 ND 0.200 0.179 Bromomethane ND 0.0917 0.0811 ND 0.356 0.315 Chloroethane ND 0.0935 0.0811 ND 0.247 0.214 Freon 11 (CCl3F)0.964 0.0962 0.0811 5.42 0.541 0.456 Ethanol 38.7 0.232 0.0927 72.9 0.437 0.175 Freon 113 (C2Cl3F3)ND 0.0923 0.0811 ND 0.707 0.622 1,1-Dichloroethene ND 0.0928 0.0811 ND 0.368 0.322 Acetone 16.8 0.0932 0.0811 40.0 0.221 0.193 Carbon disulfide 1.63 0.0931 0.0811 5.06 0.290 0.253 Isopropyl alcohol 23.3 0.0931 0.0811 57.4 0.229 0.199 Methylene chloride ND 0.235 0.235 ND 0.816 0.816 trans-1,2-Dichloroethene ND 0.0945 0.0811 ND 0.375 0.322 Methyl tert-butyl ether 0.297 0.0949 0.0811 1.07 0.342 0.292 Hexane 3.22 0.0937 0.0811 11.3 0.330 0.286 1,1-Dichloroethane ND 0.0913 0.0811 ND 0.370 0.328 Vinyl acetate ND 0.0943 0.0811 ND 0.332 0.286 cis-1,2-Dichloroethene ND 0.0934 0.0811 ND 0.370 0.322 Methyl ethyl ketone (2-Butanone)4.55 0.0942 0.0811 13.4 0.278 0.239 Ethyl acetate ND 0.0934 0.0811 ND 0.336 0.292 Chloroform 0.102 0.0937 0.0811 0.500 0.458 0.396 Tetrahydrofuran 0.620 0.0936 0.0811 1.83 0.276 0.239 1,1,1-Trichloroethane ND 0.0923 0.0811 ND 0.503 0.443 Cyclohexane 2.50 0.0943 0.0811 8.60 0.325 0.279 Carbon tetrachloride ND 0.0938 0.0811 ND 0.590 0.510 Benzene 0.354 0.0925 0.0811 1.13 0.296 0.259 1,2-Dichloroethane ND 0.0948 0.0811 ND 0.384 0.328 Heptane 0.289 0.0932 0.0811 1.18 0.382 0.332 Trichloroethene ND 0.0931 0.0811 ND 0.500 0.436 1,2-Dichloropropane ND 0.0948 0.0811 ND 0.438 0.375 1,4-Dioxane 0.0910 0.0937 0.0811 0.328 0.338 0.292 J Bromodichloromethane ND 0.0921 0.0811 ND 0.617 0.544 cis-1,3-Dichloropropene ND 0.0911 0.0811 ND 0.414 0.368 Methyl isobutyl ketone 0.665 0.0956 0.0811 2.73 0.392 0.332 Toluene 11.5 0.0942 0.0811 43.4 0.355 0.306 trans-1,3-Dichloropropene ND 0.0942 0.0811 ND 0.428 0.368 1,1,2-Trichloroethane ND 0.0929 0.0811 ND 0.507 0.443 Tetrachloroethene 0.138 0.0936 0.0811 0.936 0.635 0.550 2-Hexanone (Methyl butyl ketone)0.265 0.0942 0.0811 1.08 0.386 0.332 Dibromochloromethane ND 0.0915 0.0811 ND 0.780 0.691 1,2-Dibromoethane ND 0.0939 0.0811 ND 0.722 0.623 Chlorobenzene ND 0.0954 0.0811 ND 0.439 0.373 Ethylbenzene 0.478 0.0912 0.0811 2.07 0.396 0.352 m-/p-Xylenes 1.67 0.0939 0.0811 7.24 0.408 0.352 o-Xylene 0.947 0.0926 0.0811 4.11 0.402 0.352 Styrene 0.128 0.0903 0.0811 0.547 0.385 0.346 Bromoform ND 0.0931 0.0811 ND 0.962 0.839 1,1,2,2-Tetrachloroethane ND 0.0927 0.0811 ND 0.637 0.557 4-Ethyltoluene 0.0987 0.0934 0.0811 0.485 0.459 0.399 1,3,5-Trimethylbenzene 0.106 0.0930 0.0811 0.519 0.457 0.399 1,2,4-Trimethylbenzene 0.358 0.0922 0.0811 1.76 0.453 0.399 m 1,3-Dichlorobenzene ND 0.0936 0.0811 ND 0.562 0.488 Quantitation Report Enthalpy Analytical, LLC Sample Name : SG-3 Sample Info : 0919-153, can#580, 500mL load Data File : X1904158.D Dilution : 1 Pressurization Factor : 2.318 Acquisition Date : 2019-10-22 14:35:56 Instrument Method : TO15-SCN.M Matrix : AIR Target Compound Concentration (PPBV) RL (PPBV) MDL (PPBV) Concentration (ug/m3) RL (ug/m3) MDL (ug/m3)Flag * 1,4-Dichlorobenzene ND 0.0930 0.0811 ND 0.559 0.488 Benzyl chloride ND 0.0925 0.0811 ND 0.479 0.420 1,2-Dichlorobenzene ND 0.0945 0.0811 ND 0.568 0.488 1,2,4-Trichlorobenzene ND 0.0941 0.0811 ND 0.698 0.602 Hexachlorobutadiene ND 0.0929 0.0811 ND 0.991 0.865 Naphthalene ND 0.0960 0.0811 ND 0.503 0.425 Internal Standards Response Retention Time (min) Concentration (PPBV)Flag * Bromochloromethane (IS)434,655 11.92 5.00 PASS 1,4-Difluorobenzene (IS)1,636,027 13.67 5.04 PASS Chlorobenzene-d5 (IS)1,366,880 17.85 4.80 PASS (ND) = Not Detected * (J) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40% Quantitation Report Enthalpy Analytical, LLC Sample Name : SG-4 Sample Info : 0919-153, can#942, 500mL load Data File : X1904159.D Dilution : 1 Pressurization Factor : 2.135 Acquisition Date : 2019-10-22 15:31:47 Instrument Method : TO15-SCN.M Matrix : AIR Target Compound Concentration (PPBV) RL (PPBV) MDL (PPBV) Concentration (ug/m3) RL (ug/m3) MDL (ug/m3)Flag * Propylene 0.610 0.0819 0.0747 1.05 0.141 0.129 Freon 12 (CCl2F2)0.515 0.0834 0.0747 2.55 0.412 0.370 Freon 114 (C2Cl2F4)ND 0.0855 0.0747 ND 0.598 0.522 Chloromethane ND 0.0833 0.0747 ND 0.172 0.154 Chloroethene (Vinyl chloride)0.137 0.0859 0.0747 0.350 0.220 0.191 1,3-Butadiene ND 0.0834 0.0747 ND 0.185 0.165 Bromomethane ND 0.0845 0.0747 ND 0.328 0.290 Chloroethane ND 0.0861 0.0747 ND 0.227 0.197 Freon 11 (CCl3F)0.903 0.0886 0.0747 5.07 0.498 0.420 Ethanol 63.6 0.214 0.0854 120 0.402 0.161 Freon 113 (C2Cl3F3)ND 0.0850 0.0747 ND 0.651 0.573 1,1-Dichloroethene ND 0.0855 0.0747 ND 0.339 0.296 Carbon disulfide 0.146 0.0857 0.0747 0.456 0.267 0.233 Isopropyl alcohol 26.9 0.0857 0.0747 66.2 0.211 0.184 Methylene chloride ND 0.216 0.216 ND 0.751 0.751 trans-1,2-Dichloroethene ND 0.0870 0.0747 ND 0.345 0.296 Methyl tert-butyl ether ND 0.0874 0.0747 ND 0.315 0.269 Hexane 1.90 0.0863 0.0747 6.70 0.304 0.263 1,1-Dichloroethane ND 0.0841 0.0747 ND 0.340 0.302 Vinyl acetate ND 0.0869 0.0747 ND 0.306 0.263 cis-1,2-Dichloroethene 0.0805 0.0860 0.0747 0.319 0.341 0.296 J Methyl ethyl ketone (2-Butanone)8.45 0.0868 0.0747 24.9 0.256 0.220 Ethyl acetate ND 0.0860 0.0747 ND 0.310 0.269 Chloroform ND 0.0863 0.0747 ND 0.422 0.365 Tetrahydrofuran 0.684 0.0862 0.0747 2.02 0.254 0.220 1,1,1-Trichloroethane ND 0.0850 0.0747 ND 0.464 0.408 Cyclohexane 1.29 0.0869 0.0747 4.46 0.299 0.257 Carbon tetrachloride ND 0.0864 0.0747 ND 0.544 0.470 Benzene 0.219 0.0852 0.0747 0.700 0.272 0.239 1,2-Dichloroethane ND 0.0873 0.0747 ND 0.353 0.302 Heptane 0.149 0.0858 0.0747 0.609 0.352 0.306 Trichloroethene ND 0.0857 0.0747 ND 0.461 0.402 1,2-Dichloropropane ND 0.0873 0.0747 ND 0.403 0.345 1,4-Dioxane ND 0.0863 0.0747 ND 0.311 0.269 Bromodichloromethane ND 0.0848 0.0747 ND 0.568 0.501 cis-1,3-Dichloropropene ND 0.0839 0.0747 ND 0.381 0.339 Methyl isobutyl ketone 0.629 0.0880 0.0747 2.58 0.361 0.306 Toluene 5.73 0.0868 0.0747 21.6 0.327 0.282 trans-1,3-Dichloropropene ND 0.0868 0.0747 ND 0.394 0.339 1,1,2-Trichloroethane ND 0.0856 0.0747 ND 0.467 0.408 Tetrachloroethene 2.83 0.0862 0.0747 19.2 0.584 0.507 2-Hexanone (Methyl butyl ketone)0.252 0.0868 0.0747 1.03 0.355 0.306 m Dibromochloromethane ND 0.0843 0.0747 ND 0.718 0.637 1,2-Dibromoethane ND 0.0865 0.0747 ND 0.665 0.574 Chlorobenzene ND 0.0879 0.0747 ND 0.405 0.344 Ethylbenzene 0.308 0.0840 0.0747 1.34 0.365 0.324 m-/p-Xylenes 1.09 0.0865 0.0747 4.74 0.376 0.324 o-Xylene 0.453 0.0853 0.0747 1.97 0.370 0.324 Styrene 0.0827 0.0832 0.0747 0.352 0.354 0.318 J Bromoform ND 0.0857 0.0747 ND 0.886 0.772 1,1,2,2-Tetrachloroethane ND 0.0854 0.0747 ND 0.586 0.513 4-Ethyltoluene 0.0943 0.0860 0.0747 0.463 0.423 0.367 m 1,3,5-Trimethylbenzene 0.0986 0.0857 0.0747 0.485 0.421 0.367 1,2,4-Trimethylbenzene 0.322 0.0849 0.0747 1.58 0.417 0.367 m 1,3-Dichlorobenzene ND 0.0862 0.0747 ND 0.518 0.449 1,4-Dichlorobenzene ND 0.0857 0.0747 ND 0.515 0.449 Quantitation Report Enthalpy Analytical, LLC Sample Name : SG-4 Sample Info : 0919-153, can#942, 500mL load Data File : X1904159.D Dilution : 1 Pressurization Factor : 2.135 Acquisition Date : 2019-10-22 15:31:47 Instrument Method : TO15-SCN.M Matrix : AIR Target Compound Concentration (PPBV) RL (PPBV) MDL (PPBV) Concentration (ug/m3) RL (ug/m3) MDL (ug/m3)Flag * Benzyl chloride ND 0.0852 0.0747 ND 0.441 0.387 1,2-Dichlorobenzene ND 0.0870 0.0747 ND 0.523 0.449 1,2,4-Trichlorobenzene ND 0.0867 0.0747 ND 0.643 0.555 Hexachlorobutadiene ND 0.0856 0.0747 ND 0.913 0.797 Naphthalene ND 0.0884 0.0747 ND 0.463 0.392 Internal Standards Response Retention Time (min) Concentration (PPBV)Flag * Bromochloromethane (IS)438,401 11.92 5.00 PASS 1,4-Difluorobenzene (IS)1,641,385 13.67 5.04 PASS Chlorobenzene-d5 (IS)1,452,390 17.85 4.80 PASS (ND) = Not Detected * (J) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40% Quantitation Report Enthalpy Analytical, LLC Sample Name : SG-4 Sample Info : 0919-153; Can#942; *10=50mL load Data File : X1904163.D Dilution : 10 Pressurization Factor : 2.135 Acquisition Date : 2019-10-22 19:04:39 Instrument Method : TO15-SCN.M Matrix : AIR Target Compound Concentration (PPBV) RL (PPBV) MDL (PPBV) Concentration (ug/m3) RL (ug/m3) MDL (ug/m3)Flag * Acetone 85.7 0.858 0.747 204 2.04 1.78 Internal Standards Response Retention Time (min) Concentration (PPBV)Flag * Bromochloromethane (IS)433,301 11.91 5.00 PASS (ND) = Not Detected * (J) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40% Quantitation Report Enthalpy Analytical, LLC Sample Name : SG-5 Sample Info : 0919-153; Can#190; 500mL load Data File : X1904160.D Dilution : 1 Pressurization Factor : 2.137 Acquisition Date : 2019-10-22 16:24:55 Instrument Method : TO15-SCN.M Matrix : AIR Target Compound Concentration (PPBV) RL (PPBV) MDL (PPBV) Concentration (ug/m3) RL (ug/m3) MDL (ug/m3)Flag * Propylene 0.595 0.0820 0.0748 1.02 0.141 0.129 Freon 12 (CCl2F2)0.531 0.0834 0.0748 2.63 0.413 0.370 Freon 114 (C2Cl2F4)ND 0.0856 0.0748 ND 0.598 0.523 Chloromethane ND 0.0833 0.0748 ND 0.172 0.154 Chloroethene (Vinyl chloride)0.181 0.0860 0.0748 0.462 0.220 0.191 1,3-Butadiene ND 0.0835 0.0748 ND 0.185 0.165 Bromomethane ND 0.0845 0.0748 ND 0.328 0.290 Chloroethane ND 0.0862 0.0748 ND 0.227 0.197 Freon 11 (CCl3F)0.874 0.0887 0.0748 4.91 0.499 0.420 Freon 113 (C2Cl3F3)0.0753 0.0851 0.0748 0.577 0.652 0.573 J 1,1-Dichloroethene ND 0.0856 0.0748 ND 0.339 0.297 Acetone 26.4 0.0859 0.0748 62.8 0.204 0.178 Carbon disulfide 0.127 0.0858 0.0748 0.395 0.267 0.233 Isopropyl alcohol 25.7 0.0858 0.0748 63.1 0.211 0.184 Methylene chloride ND 0.216 0.216 ND 0.752 0.752 trans-1,2-Dichloroethene ND 0.0871 0.0748 ND 0.345 0.297 Methyl tert-butyl ether ND 0.0875 0.0748 ND 0.316 0.270 Hexane 3.26 0.0864 0.0748 11.5 0.305 0.264 1,1-Dichloroethane ND 0.0842 0.0748 ND 0.341 0.303 Vinyl acetate ND 0.0869 0.0748 ND 0.306 0.263 cis-1,2-Dichloroethene ND 0.0861 0.0748 ND 0.341 0.297 Methyl ethyl ketone (2-Butanone)6.21 0.0868 0.0748 18.3 0.256 0.221 Ethyl acetate 0.243 0.0861 0.0748 0.876 0.310 0.270 Chloroform ND 0.0864 0.0748 ND 0.422 0.365 Tetrahydrofuran 0.954 0.0862 0.0748 2.81 0.254 0.221 1,1,1-Trichloroethane ND 0.0851 0.0748 ND 0.464 0.408 Cyclohexane 1.65 0.0869 0.0748 5.67 0.299 0.257 Carbon tetrachloride ND 0.0865 0.0748 ND 0.544 0.471 Benzene 0.190 0.0853 0.0748 0.608 0.273 0.239 1,2-Dichloroethane ND 0.0874 0.0748 ND 0.354 0.303 Heptane 0.142 0.0859 0.0748 0.583 0.352 0.307 Trichloroethene ND 0.0858 0.0748 ND 0.461 0.402 1,2-Dichloropropane ND 0.0874 0.0748 ND 0.404 0.346 1,4-Dioxane ND 0.0864 0.0748 ND 0.311 0.270 Bromodichloromethane ND 0.0849 0.0748 ND 0.569 0.501 cis-1,3-Dichloropropene ND 0.0840 0.0748 ND 0.381 0.339 Methyl isobutyl ketone 0.358 0.0881 0.0748 1.47 0.361 0.306 Toluene 12.2 0.0868 0.0748 46.0 0.327 0.282 trans-1,3-Dichloropropene ND 0.0868 0.0748 ND 0.394 0.339 1,1,2-Trichloroethane ND 0.0857 0.0748 ND 0.467 0.408 Tetrachloroethene 4.10 0.0862 0.0748 27.8 0.585 0.507 2-Hexanone (Methyl butyl ketone)0.183 0.0868 0.0748 0.750 0.356 0.306 Dibromochloromethane ND 0.0844 0.0748 ND 0.719 0.637 1,2-Dibromoethane ND 0.0866 0.0748 ND 0.665 0.575 Chlorobenzene ND 0.0880 0.0748 ND 0.405 0.344 Ethylbenzene 0.409 0.0841 0.0748 1.78 0.365 0.325 m-/p-Xylenes 1.34 0.0866 0.0748 5.82 0.376 0.325 o-Xylene 0.583 0.0854 0.0748 2.53 0.371 0.325 Styrene 0.109 0.0833 0.0748 0.466 0.355 0.319 Bromoform ND 0.0858 0.0748 ND 0.887 0.773 1,1,2,2-Tetrachloroethane ND 0.0855 0.0748 ND 0.587 0.513 4-Ethyltoluene 0.109 0.0861 0.0748 0.535 0.423 0.368 m 1,3,5-Trimethylbenzene 0.114 0.0857 0.0748 0.562 0.421 0.368 1,2,4-Trimethylbenzene 0.364 0.0850 0.0748 1.79 0.418 0.368 m 1,3-Dichlorobenzene ND 0.0862 0.0748 ND 0.519 0.450 1,4-Dichlorobenzene ND 0.0857 0.0748 ND 0.515 0.450 Quantitation Report Enthalpy Analytical, LLC Sample Name : SG-5 Sample Info : 0919-153; Can#190; 500mL load Data File : X1904160.D Dilution : 1 Pressurization Factor : 2.137 Acquisition Date : 2019-10-22 16:24:55 Instrument Method : TO15-SCN.M Matrix : AIR Target Compound Concentration (PPBV) RL (PPBV) MDL (PPBV) Concentration (ug/m3) RL (ug/m3) MDL (ug/m3)Flag * Benzyl chloride ND 0.0853 0.0748 ND 0.442 0.387 1,2-Dichlorobenzene ND 0.0871 0.0748 ND 0.524 0.450 1,2,4-Trichlorobenzene ND 0.0868 0.0748 ND 0.644 0.555 Hexachlorobutadiene ND 0.0857 0.0748 ND 0.913 0.798 Naphthalene ND 0.0885 0.0748 ND 0.464 0.392 Internal Standards Response Retention Time (min) Concentration (PPBV)Flag * Bromochloromethane (IS)431,706 11.92 5.00 PASS 1,4-Difluorobenzene (IS)1,622,002 13.67 5.04 PASS Chlorobenzene-d5 (IS)1,411,510 17.85 4.80 PASS (ND) = Not Detected * (J) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40% Quantitation Report Enthalpy Analytical, LLC Sample Name : SG-5 Sample Info : 0919-153; Can#190; *10=50mL load Data File : X1904164.D Dilution : 10 Pressurization Factor : 2.137 Acquisition Date : 2019-10-22 19:52:43 Instrument Method : TO15-SCN.M Matrix : AIR Target Compound Concentration (PPBV) RL (PPBV) MDL (PPBV) Concentration (ug/m3) RL (ug/m3) MDL (ug/m3)Flag * Ethanol 99.7 2.14 0.855 188 4.03 1.61 Internal Standards Response Retention Time (min) Concentration (PPBV)Flag * Bromochloromethane (IS)412,325 11.91 5.00 PASS (ND) = Not Detected * (J) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40% Quantitation Report Enthalpy Analytical, LLC Sample Name : SG-6 Sample Info : 0919-153; Can#955; 500mL load Data File : X1904161.D Dilution : 1 Pressurization Factor : 2.084 Acquisition Date : 2019-10-22 17:20:46 Instrument Method : TO15-SCN.M Matrix : AIR Target Compound Concentration (PPBV) RL (PPBV) MDL (PPBV) Concentration (ug/m3) RL (ug/m3) MDL (ug/m3)Flag * Propylene 0.599 0.0799 0.0729 1.03 0.138 0.126 Freon 12 (CCl2F2)0.568 0.0814 0.0729 2.81 0.402 0.361 Freon 114 (C2Cl2F4)ND 0.0834 0.0729 ND 0.583 0.510 Chloromethane ND 0.0813 0.0729 ND 0.168 0.151 Chloroethene (Vinyl chloride)ND 0.0839 0.0729 ND 0.214 0.186 1,3-Butadiene ND 0.0814 0.0729 ND 0.180 0.161 Bromomethane ND 0.0824 0.0729 ND 0.320 0.283 Chloroethane ND 0.0840 0.0729 ND 0.222 0.192 Freon 11 (CCl3F)0.765 0.0865 0.0729 4.30 0.486 0.410 Freon 113 (C2Cl3F3)0.0754 0.0829 0.0729 0.578 0.636 0.559 J 1,1-Dichloroethene ND 0.0834 0.0729 ND 0.331 0.289 Acetone 51.7 0.0838 0.0729 123 0.199 0.173 Carbon disulfide 0.115 0.0837 0.0729 0.358 0.261 0.227 Isopropyl alcohol 15.3 0.0837 0.0729 37.7 0.206 0.179 Methylene chloride ND 0.211 0.211 ND 0.733 0.733 trans-1,2-Dichloroethene ND 0.0849 0.0729 ND 0.337 0.289 Methyl tert-butyl ether ND 0.0854 0.0729 ND 0.308 0.263 Hexane 0.731 0.0843 0.0729 2.58 0.297 0.257 1,1-Dichloroethane ND 0.0821 0.0729 ND 0.332 0.295 Vinyl acetate ND 0.0848 0.0729 ND 0.299 0.257 cis-1,2-Dichloroethene ND 0.0839 0.0729 ND 0.333 0.289 Methyl ethyl ketone (2-Butanone)7.59 0.0847 0.0729 22.4 0.250 0.215 Ethyl acetate 0.0778 0.0839 0.0729 0.280 0.302 0.263 m J Chloroform 0.118 0.0843 0.0729 0.578 0.411 0.356 Tetrahydrofuran 0.300 0.0841 0.0729 0.883 0.248 0.215 1,1,1-Trichloroethane ND 0.0829 0.0729 ND 0.453 0.398 Cyclohexane 1.43 0.0848 0.0729 4.93 0.292 0.251 Carbon tetrachloride ND 0.0844 0.0729 ND 0.531 0.459 Benzene 0.210 0.0832 0.0729 0.669 0.266 0.233 1,2-Dichloroethane ND 0.0852 0.0729 ND 0.345 0.295 Heptane ND 0.0838 0.0729 ND 0.343 0.299 Trichloroethene 0.447 0.0837 0.0729 2.40 0.450 0.392 1,2-Dichloropropane ND 0.0852 0.0729 ND 0.394 0.337 1,4-Dioxane ND 0.0843 0.0729 ND 0.304 0.263 Bromodichloromethane ND 0.0828 0.0729 ND 0.555 0.489 cis-1,3-Dichloropropene ND 0.0819 0.0729 ND 0.372 0.331 Methyl isobutyl ketone 0.464 0.0859 0.0729 1.90 0.352 0.299 Toluene 3.06 0.0847 0.0729 11.5 0.319 0.275 trans-1,3-Dichloropropene ND 0.0847 0.0729 ND 0.384 0.331 1,1,2-Trichloroethane ND 0.0835 0.0729 ND 0.456 0.398 Tetrachloroethene 0.895 0.0841 0.0729 6.07 0.570 0.495 2-Hexanone (Methyl butyl ketone)0.378 0.0847 0.0729 1.55 0.347 0.299 m Dibromochloromethane ND 0.0823 0.0729 ND 0.701 0.621 1,2-Dibromoethane ND 0.0844 0.0729 ND 0.649 0.560 Chlorobenzene ND 0.0858 0.0729 ND 0.395 0.336 Ethylbenzene 0.184 0.0820 0.0729 0.797 0.356 0.317 m-/p-Xylenes 0.600 0.0844 0.0729 2.61 0.367 0.317 o-Xylene 0.253 0.0833 0.0729 1.10 0.362 0.317 Styrene 0.0740 0.0812 0.0729 0.315 0.346 0.311 J Bromoform ND 0.0837 0.0729 ND 0.865 0.754 1,1,2,2-Tetrachloroethane ND 0.0834 0.0729 ND 0.572 0.501 4-Ethyltoluene ND 0.0839 0.0729 ND 0.413 0.359 1,3,5-Trimethylbenzene ND 0.0836 0.0729 ND 0.411 0.359 1,2,4-Trimethylbenzene 0.195 0.0829 0.0729 0.957 0.407 0.359 m 1,3-Dichlorobenzene ND 0.0841 0.0729 ND 0.506 0.439 1,4-Dichlorobenzene ND 0.0836 0.0729 ND 0.503 0.439 Quantitation Report Enthalpy Analytical, LLC Sample Name : SG-6 Sample Info : 0919-153; Can#955; 500mL load Data File : X1904161.D Dilution : 1 Pressurization Factor : 2.084 Acquisition Date : 2019-10-22 17:20:46 Instrument Method : TO15-SCN.M Matrix : AIR Target Compound Concentration (PPBV) RL (PPBV) MDL (PPBV) Concentration (ug/m3) RL (ug/m3) MDL (ug/m3)Flag * Benzyl chloride ND 0.0832 0.0729 ND 0.431 0.378 1,2-Dichlorobenzene ND 0.0849 0.0729 ND 0.511 0.439 1,2,4-Trichlorobenzene ND 0.0846 0.0729 ND 0.628 0.541 Hexachlorobutadiene ND 0.0835 0.0729 ND 0.891 0.778 Naphthalene ND 0.0863 0.0729 ND 0.452 0.382 Internal Standards Response Retention Time (min) Concentration (PPBV)Flag * Bromochloromethane (IS)429,202 11.92 5.00 PASS 1,4-Difluorobenzene (IS)1,620,417 13.67 5.04 PASS Chlorobenzene-d5 (IS)1,354,632 17.85 4.80 PASS (ND) = Not Detected * (J) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40% Quantitation Report Enthalpy Analytical, LLC Sample Name : SG-6 Sample Info : 0919-153; Can#955; *10=50mL load Data File : X1904165.D Dilution : 10 Pressurization Factor : 2.084 Acquisition Date : 2019-10-22 20:40:44 Instrument Method : TO15-SCN.M Matrix : AIR Target Compound Concentration (PPBV) RL (PPBV) MDL (PPBV) Concentration (ug/m3) RL (ug/m3) MDL (ug/m3)Flag * Ethanol 85.5 2.08 0.834 161 3.93 1.57 Internal Standards Response Retention Time (min) Concentration (PPBV)Flag * Bromochloromethane (IS)407,042 11.92 5.00 PASS (ND) = Not Detected * (J) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40% Quantitation Report Enthalpy Analytical, LLC Sample Name : SG-7 Sample Info : 0919-153; Can#144; 500mL load Data File : X1904162.D Dilution : 1 Pressurization Factor : 2.114 Acquisition Date : 2019-10-22 18:16:38 Instrument Method : TO15-SCN.M Matrix : AIR Target Compound Concentration (PPBV) RL (PPBV) MDL (PPBV) Concentration (ug/m3) RL (ug/m3) MDL (ug/m3)Flag * Propylene 0.702 0.0811 0.0740 1.21 0.140 0.127 Freon 12 (CCl2F2)0.504 0.0825 0.0740 2.49 0.408 0.366 Freon 114 (C2Cl2F4)ND 0.0846 0.0740 ND 0.592 0.517 Chloromethane ND 0.0824 0.0740 ND 0.170 0.153 Chloroethene (Vinyl chloride)ND 0.0851 0.0740 ND 0.217 0.189 1,3-Butadiene ND 0.0826 0.0740 ND 0.183 0.164 Bromomethane ND 0.0836 0.0740 ND 0.325 0.287 Chloroethane ND 0.0852 0.0740 ND 0.225 0.195 Freon 11 (CCl3F)0.497 0.0878 0.0740 2.79 0.493 0.416 Ethanol 58.2 0.211 0.0846 110 0.398 0.159 Freon 113 (C2Cl3F3)ND 0.0841 0.0740 ND 0.645 0.567 1,1-Dichloroethene ND 0.0846 0.0740 ND 0.336 0.293 Carbon disulfide 3.92 0.0849 0.0740 12.2 0.264 0.230 Isopropyl alcohol 13.7 0.0849 0.0740 33.6 0.209 0.182 Methylene chloride ND 0.214 0.214 ND 0.744 0.744 trans-1,2-Dichloroethene ND 0.0862 0.0740 ND 0.342 0.293 Methyl tert-butyl ether ND 0.0866 0.0740 ND 0.312 0.267 Hexane 0.800 0.0855 0.0740 2.82 0.301 0.261 m 1,1-Dichloroethane ND 0.0833 0.0740 ND 0.337 0.299 Vinyl acetate ND 0.0860 0.0740 ND 0.303 0.261 cis-1,2-Dichloroethene ND 0.0852 0.0740 ND 0.338 0.293 Methyl ethyl ketone (2-Butanone)10.9 0.0859 0.0740 32.1 0.253 0.218 Ethyl acetate 0.0987 0.0852 0.0740 0.356 0.307 0.267 m Chloroform 0.304 0.0855 0.0740 1.48 0.417 0.361 Tetrahydrofuran 0.349 0.0853 0.0740 1.03 0.252 0.218 1,1,1-Trichloroethane ND 0.0841 0.0740 ND 0.459 0.404 Cyclohexane 0.817 0.0860 0.0740 2.81 0.296 0.255 Carbon tetrachloride ND 0.0856 0.0740 ND 0.538 0.465 Benzene 0.181 0.0844 0.0740 0.578 0.270 0.236 1,2-Dichloroethane ND 0.0864 0.0740 ND 0.350 0.299 Heptane 0.229 0.0850 0.0740 0.939 0.348 0.303 Trichloroethene ND 0.0849 0.0740 ND 0.456 0.398 1,2-Dichloropropane ND 0.0864 0.0740 ND 0.399 0.342 1,4-Dioxane ND 0.0855 0.0740 ND 0.308 0.267 Bromodichloromethane ND 0.0840 0.0740 ND 0.563 0.496 cis-1,3-Dichloropropene ND 0.0831 0.0740 ND 0.377 0.336 Methyl isobutyl ketone 0.357 0.0872 0.0740 1.46 0.357 0.303 Toluene 3.13 0.0859 0.0740 11.8 0.324 0.279 trans-1,3-Dichloropropene ND 0.0859 0.0740 ND 0.390 0.336 1,1,2-Trichloroethane ND 0.0847 0.0740 ND 0.462 0.404 Tetrachloroethene 0.590 0.0853 0.0740 4.00 0.579 0.502 2-Hexanone (Methyl butyl ketone)0.296 0.0859 0.0740 1.21 0.352 0.303 Dibromochloromethane ND 0.0835 0.0740 ND 0.711 0.630 1,2-Dibromoethane ND 0.0857 0.0740 ND 0.658 0.569 Chlorobenzene ND 0.0870 0.0740 ND 0.401 0.341 Ethylbenzene 0.192 0.0832 0.0740 0.835 0.361 0.321 m-/p-Xylenes 0.629 0.0857 0.0740 2.73 0.372 0.321 o-Xylene 0.235 0.0845 0.0740 1.02 0.367 0.321 Styrene ND 0.0824 0.0740 ND 0.351 0.315 Bromoform ND 0.0849 0.0740 ND 0.878 0.765 1,1,2,2-Tetrachloroethane ND 0.0846 0.0740 ND 0.581 0.508 4-Ethyltoluene 0.0753 0.0852 0.0740 0.370 0.419 0.364 J 1,3,5-Trimethylbenzene 0.0848 0.0848 0.0740 0.417 0.417 0.364 1,2,4-Trimethylbenzene 0.295 0.0841 0.0740 1.45 0.413 0.364 m 1,3-Dichlorobenzene ND 0.0853 0.0740 ND 0.513 0.445 1,4-Dichlorobenzene ND 0.0848 0.0740 ND 0.510 0.445 Quantitation Report Enthalpy Analytical, LLC Sample Name : SG-7 Sample Info : 0919-153; Can#144; 500mL load Data File : X1904162.D Dilution : 1 Pressurization Factor : 2.114 Acquisition Date : 2019-10-22 18:16:38 Instrument Method : TO15-SCN.M Matrix : AIR Target Compound Concentration (PPBV) RL (PPBV) MDL (PPBV) Concentration (ug/m3) RL (ug/m3) MDL (ug/m3)Flag * Benzyl chloride ND 0.0844 0.0740 ND 0.437 0.383 1,2-Dichlorobenzene ND 0.0862 0.0740 ND 0.518 0.445 1,2,4-Trichlorobenzene ND 0.0858 0.0740 ND 0.637 0.549 Hexachlorobutadiene ND 0.0847 0.0740 ND 0.904 0.789 Naphthalene ND 0.0875 0.0740 ND 0.459 0.388 Internal Standards Response Retention Time (min) Concentration (PPBV)Flag * Bromochloromethane (IS)443,590 11.92 5.00 PASS 1,4-Difluorobenzene (IS)1,652,388 13.67 5.04 PASS Chlorobenzene-d5 (IS)1,381,172 17.85 4.80 PASS (ND) = Not Detected * (J) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40% Quantitation Report Enthalpy Analytical, LLC Sample Name : SG-7 Sample Info : 0919-153; Can#144; *10=50mL load Data File : X1904166.D Dilution : 10 Pressurization Factor : 2.114 Acquisition Date : 2019-10-22 21:28:48 Instrument Method : TO15-SCN.M Matrix : AIR Target Compound Concentration (PPBV) RL (PPBV) MDL (PPBV) Concentration (ug/m3) RL (ug/m3) MDL (ug/m3)Flag * Acetone 169 0.850 0.740 402 2.02 1.76 Internal Standards Response Retention Time (min) Concentration (PPBV)Flag * Bromochloromethane (IS)404,102 11.92 5.00 PASS (ND) = Not Detected * (J) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40% Lab QC Quantitation Report Enthalpy Analytical, LLC Sample Name : Humid Blank #0702 Sample Info : 500mL load; Can #0702 Data File : X1904154.D Dilution : 1 Pressurization Factor : 1.000 Acquisition Date : 2019-10-22 10:43:29 Instrument Method : TO15-SCN.M Matrix : AIR Target Compound Concentration (PPBV) RL (PPBV) MDL (PPBV) Concentration (ug/m3) RL (ug/m3) MDL (ug/m3)Flag * Propylene ND 0.0384 0.0350 ND 0.0660 0.0602 Freon 12 (CCl2F2)ND 0.0390 0.0350 ND 0.193 0.173 Freon 114 (C2Cl2F4)ND 0.0400 0.0350 ND 0.280 0.245 Chloromethane ND 0.0390 0.0350 ND 0.0805 0.0723 Chloroethene (Vinyl chloride)ND 0.0402 0.0350 ND 0.103 0.0895 1,3-Butadiene ND 0.0391 0.0350 ND 0.0865 0.0774 Bromomethane ND 0.0396 0.0350 ND 0.154 0.136 Chloroethane ND 0.0403 0.0350 ND 0.106 0.0924 Freon 11 (CCl3F)ND 0.0415 0.0350 ND 0.233 0.197 Ethanol 0.0656 0.100 0.0400 0.124 0.188 0.0754 J Freon 113 (C2Cl3F3)ND 0.0398 0.0350 ND 0.305 0.268 1,1-Dichloroethene ND 0.0400 0.0350 ND 0.159 0.139 Acetone 0.0450 0.0402 0.0350 0.107 0.0955 0.0831 Carbon disulfide 0.0351 0.0402 0.0350 0.109 0.125 0.109 J Isopropyl alcohol ND 0.0402 0.0350 ND 0.0987 0.0860 Methylene chloride ND 0.101 0.101 ND 0.352 0.352 trans-1,2-Dichloroethene ND 0.0408 0.0350 ND 0.162 0.139 Methyl tert-butyl ether ND 0.0410 0.0350 ND 0.148 0.126 Hexane ND 0.0404 0.0350 ND 0.143 0.123 1,1-Dichloroethane ND 0.0394 0.0350 ND 0.159 0.142 Vinyl acetate ND 0.0407 0.0350 ND 0.143 0.123 cis-1,2-Dichloroethene ND 0.0403 0.0350 ND 0.160 0.139 Methyl ethyl ketone (2-Butanone)ND 0.0406 0.0350 ND 0.120 0.103 Ethyl acetate ND 0.0403 0.0350 ND 0.145 0.126 Chloroform ND 0.0404 0.0350 ND 0.197 0.171 Tetrahydrofuran ND 0.0404 0.0350 ND 0.119 0.103 1,1,1-Trichloroethane ND 0.0398 0.0350 ND 0.217 0.191 Cyclohexane ND 0.0407 0.0350 ND 0.140 0.120 Carbon tetrachloride ND 0.0405 0.0350 ND 0.255 0.220 Benzene ND 0.0399 0.0350 ND 0.128 0.112 1,2-Dichloroethane ND 0.0409 0.0350 ND 0.165 0.142 Heptane ND 0.0402 0.0350 ND 0.165 0.143 Trichloroethene ND 0.0402 0.0350 ND 0.216 0.188 1,2-Dichloropropane ND 0.0409 0.0350 ND 0.189 0.162 1,4-Dioxane ND 0.0404 0.0350 ND 0.146 0.126 Bromodichloromethane ND 0.0397 0.0350 ND 0.266 0.235 cis-1,3-Dichloropropene ND 0.0393 0.0350 ND 0.178 0.159 Methyl isobutyl ketone ND 0.0412 0.0350 ND 0.169 0.143 Toluene ND 0.0406 0.0350 ND 0.153 0.132 trans-1,3-Dichloropropene ND 0.0406 0.0350 ND 0.184 0.159 1,1,2-Trichloroethane ND 0.0401 0.0350 ND 0.219 0.191 Tetrachloroethene ND 0.0404 0.0350 ND 0.274 0.237 2-Hexanone (Methyl butyl ketone)ND 0.0406 0.0350 ND 0.166 0.143 Dibromochloromethane ND 0.0395 0.0350 ND 0.336 0.298 1,2-Dibromoethane ND 0.0405 0.0350 ND 0.311 0.269 Chlorobenzene ND 0.0412 0.0350 ND 0.189 0.161 Ethylbenzene ND 0.0394 0.0350 ND 0.171 0.152 m-/p-Xylenes ND 0.0405 0.0350 ND 0.176 0.152 o-Xylene ND 0.0400 0.0350 ND 0.174 0.152 Styrene ND 0.0390 0.0350 ND 0.166 0.149 Bromoform ND 0.0402 0.0350 ND 0.415 0.362 1,1,2,2-Tetrachloroethane ND 0.0400 0.0350 ND 0.275 0.240 4-Ethyltoluene ND 0.0403 0.0350 ND 0.198 0.172 1,3,5-Trimethylbenzene ND 0.0401 0.0350 ND 0.197 0.172 1,2,4-Trimethylbenzene ND 0.0398 0.0350 ND 0.195 0.172 1,3-Dichlorobenzene ND 0.0404 0.0350 ND 0.243 0.210 Quantitation Report Enthalpy Analytical, LLC Sample Name : Humid Blank #0702 Sample Info : 500mL load; Can #0702 Data File : X1904154.D Dilution : 1 Pressurization Factor : 1.000 Acquisition Date : 2019-10-22 10:43:29 Instrument Method : TO15-SCN.M Matrix : AIR Target Compound Concentration (PPBV) RL (PPBV) MDL (PPBV) Concentration (ug/m3) RL (ug/m3) MDL (ug/m3)Flag * 1,4-Dichlorobenzene ND 0.0401 0.0350 ND 0.241 0.210 Benzyl chloride ND 0.0399 0.0350 ND 0.207 0.181 1,2-Dichlorobenzene ND 0.0408 0.0350 ND 0.245 0.210 1,2,4-Trichlorobenzene ND 0.0406 0.0350 ND 0.301 0.260 Hexachlorobutadiene ND 0.0401 0.0350 ND 0.427 0.373 Naphthalene ND 0.0414 0.0350 ND 0.217 0.183 Internal Standards Response Retention Time (min) Concentration (PPBV)Flag * Bromochloromethane (IS)425,617 11.91 5.00 PASS 1,4-Difluorobenzene (IS)1,610,339 13.67 5.04 PASS Chlorobenzene-d5 (IS)1,353,903 17.85 4.80 PASS (ND) = Not Detected * (J) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40% Quantitation Report Enthalpy Analytical, LLC Sample Name : 5ppbv TO15 LCS Sample Info : 500mL load; Can #000100; GCMSPrepPg800 Data File : X1904151.D Dilution : 1 Pressurization Factor : 1.000 Acquisition Date : 2019-10-22 08:01:27 Instrument Method : TO15-SCN.M Matrix : AIR Target Compound Concentration (PPBV) RL (PPBV) MDL (PPBV) Concentration (ug/m3) RL (ug/m3) MDL (ug/m3)Flag * Propylene 4.24 0.0384 0.0350 7.30 0.0660 0.0602 Freon 12 (CCl2F2)4.70 0.0390 0.0350 23.2 0.193 0.173 Freon 114 (C2Cl2F4)4.81 0.0400 0.0350 33.7 0.280 0.245 Chloromethane 4.80 0.0390 0.0350 9.91 0.0805 0.0723 Chloroethene (Vinyl chloride)5.46 0.0402 0.0350 14.0 0.103 0.0895 1,3-Butadiene 5.08 0.0391 0.0350 11.2 0.0865 0.0774 Bromomethane 5.18 0.0396 0.0350 20.1 0.154 0.136 Chloroethane 5.01 0.0403 0.0350 13.2 0.106 0.0924 Freon 11 (CCl3F)5.05 0.0415 0.0350 28.4 0.233 0.197 Ethanol 4.75 0.100 0.0400 8.94 0.188 0.0754 Freon 113 (C2Cl3F3)5.08 0.0398 0.0350 38.9 0.305 0.268 1,1-Dichloroethene 4.62 0.0400 0.0350 18.3 0.159 0.139 Acetone 4.37 0.0402 0.0350 10.4 0.0955 0.0831 Carbon disulfide 4.63 0.0402 0.0350 14.4 0.125 0.109 Isopropyl alcohol 4.82 0.0402 0.0350 11.9 0.0987 0.0860 Methylene chloride 4.63 0.101 0.101 16.1 0.352 0.352 m trans-1,2-Dichloroethene 4.81 0.0408 0.0350 19.1 0.162 0.139 Methyl tert-butyl ether 4.75 0.0410 0.0350 17.1 0.148 0.126 Hexane 4.79 0.0404 0.0350 16.9 0.143 0.123 1,1-Dichloroethane 4.72 0.0394 0.0350 19.1 0.159 0.142 Vinyl acetate 4.87 0.0407 0.0350 17.2 0.143 0.123 m cis-1,2-Dichloroethene 4.84 0.0403 0.0350 19.2 0.160 0.139 Methyl ethyl ketone (2-Butanone)4.90 0.0406 0.0350 14.4 0.120 0.103 Ethyl acetate 4.81 0.0403 0.0350 17.3 0.145 0.126 Chloroform 4.91 0.0404 0.0350 24.0 0.197 0.171 Tetrahydrofuran 4.81 0.0404 0.0350 14.2 0.119 0.103 m 1,1,1-Trichloroethane 4.84 0.0398 0.0350 26.4 0.217 0.191 Cyclohexane 4.79 0.0407 0.0350 16.5 0.140 0.120 Carbon tetrachloride 5.01 0.0405 0.0350 31.5 0.255 0.220 Benzene 4.81 0.0399 0.0350 15.4 0.128 0.112 1,2-Dichloroethane 4.77 0.0409 0.0350 19.3 0.165 0.142 Heptane 4.78 0.0402 0.0350 19.6 0.165 0.143 Trichloroethene 5.19 0.0402 0.0350 27.9 0.216 0.188 1,2-Dichloropropane 4.89 0.0409 0.0350 22.6 0.189 0.162 1,4-Dioxane 5.18 0.0404 0.0350 18.7 0.146 0.126 m Bromodichloromethane 4.93 0.0397 0.0350 33.1 0.266 0.235 cis-1,3-Dichloropropene 5.29 0.0393 0.0350 24.0 0.178 0.159 Methyl isobutyl ketone 5.65 0.0412 0.0350 23.1 0.169 0.143 Toluene 5.21 0.0406 0.0350 19.6 0.153 0.132 trans-1,3-Dichloropropene 5.37 0.0406 0.0350 24.4 0.184 0.159 1,1,2-Trichloroethane 5.26 0.0401 0.0350 28.7 0.219 0.191 Tetrachloroethene 5.34 0.0404 0.0350 36.2 0.274 0.237 2-Hexanone (Methyl butyl ketone)5.60 0.0406 0.0350 22.9 0.166 0.143 Dibromochloromethane 5.43 0.0395 0.0350 46.2 0.336 0.298 1,2-Dibromoethane 5.51 0.0405 0.0350 42.3 0.311 0.269 Chlorobenzene 5.16 0.0412 0.0350 23.7 0.189 0.161 Ethylbenzene 4.63 0.0394 0.0350 20.1 0.171 0.152 m-/p-Xylenes 4.77 0.0405 0.0350 20.7 0.176 0.152 o-Xylene 4.67 0.0400 0.0350 20.3 0.174 0.152 Styrene 4.81 0.0390 0.0350 20.5 0.166 0.149 Bromoform 5.30 0.0402 0.0350 54.7 0.415 0.362 1,1,2,2-Tetrachloroethane 4.88 0.0400 0.0350 33.5 0.275 0.240 4-Ethyltoluene 5.00 0.0403 0.0350 24.6 0.198 0.172 1,3,5-Trimethylbenzene 4.68 0.0401 0.0350 23.0 0.197 0.172 1,2,4-Trimethylbenzene 4.73 0.0398 0.0350 23.2 0.195 0.172 1,3-Dichlorobenzene 4.96 0.0404 0.0350 29.8 0.243 0.210 Quantitation Report Enthalpy Analytical, LLC Sample Name : 5ppbv TO15 LCS Sample Info : 500mL load; Can #000100; GCMSPrepPg800 Data File : X1904151.D Dilution : 1 Pressurization Factor : 1.000 Acquisition Date : 2019-10-22 08:01:27 Instrument Method : TO15-SCN.M Matrix : AIR Target Compound Concentration (PPBV) RL (PPBV) MDL (PPBV) Concentration (ug/m3) RL (ug/m3) MDL (ug/m3)Flag * 1,4-Dichlorobenzene 4.96 0.0401 0.0350 29.8 0.241 0.210 Benzyl chloride 4.89 0.0399 0.0350 25.3 0.207 0.181 1,2-Dichlorobenzene 5.04 0.0408 0.0350 30.3 0.245 0.210 1,2,4-Trichlorobenzene 5.61 0.0406 0.0350 41.6 0.301 0.260 Hexachlorobutadiene 5.29 0.0401 0.0350 56.5 0.427 0.373 Naphthalene 5.68 0.0414 0.0350 29.8 0.217 0.183 Internal Standards Response Retention Time (min) Concentration (PPBV)Flag * Bromochloromethane (IS)415,772 11.92 5.00 PASS 1,4-Difluorobenzene (IS)1,594,622 13.67 5.04 PASS Chlorobenzene-d5 (IS)1,370,213 17.85 4.80 PASS (ND) = Not Detected * (J) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40% QC Summary Report Enthalpy Analytical, LLC Sample Name : 5ppbv TO15 LCS Sample Info : 500mL load; Can #000100; GCMSPrepPg800 Data File : X1904151.D Dilution : 1 Pressurization Factor : 1.000 Acquisition Date : 2019-10-22 08:01:27 Instrument Method : TO15-SCN.M Matrix : AIR Target Compound Response Concentration (PPBV) Tag Value (PPBV) % Recovery Flag Propylene 344,096 4.24 4.79 88.5 PASS Freon 12 (CCl2F2)755,082 4.70 4.81 97.8 PASS Freon 114 (C2Cl2F4)862,771 4.81 4.98 96.7 PASS Chloromethane 423,639 4.80 4.86 98.7 PASS Chloroethene (Vinyl chloride)430,870 5.46 4.99 109.6 PASS 1,3-Butadiene 379,644 5.08 4.83 105.3 PASS Bromomethane 350,755 5.18 4.90 105.7 PASS Chloroethane 209,568 5.01 5.01 100.0 PASS Freon 11 (CCl3F)892,228 5.05 5.16 97.9 PASS Ethanol 197,035 4.75 4.91 96.8 PASS 1,1-Dichloroethene 624,795 4.62 4.98 92.9 PASS Freon 113 (C2Cl3F3)638,804 5.08 4.96 102.5 PASS Acetone 630,935 4.37 4.94 88.6 PASS Isopropyl alcohol 800,893 4.82 4.95 97.4 PASS Carbon disulfide 1,036,404 4.63 4.97 93.3 PASS Methylene chloride 606,864 4.63 5.01 92.4 PASS Methyl tert-butyl ether 900,144 4.75 5.05 94.0 PASS trans-1,2-Dichloroethene 582,297 4.81 5.05 95.2 PASS Hexane 663,132 4.79 5.04 95.2 PASS Vinyl acetate 1,166,593 4.87 5.02 97.2 PASS 1,1-Dichloroethane 705,974 4.72 4.88 96.8 PASS Methyl ethyl ketone (2-Butanone)174,297 4.90 5.08 96.5 PASS cis-1,2-Dichloroethene 687,243 4.84 4.97 97.4 PASS Ethyl acetate 158,048 4.81 5.01 96.2 PASS Tetrahydrofuran 164,166 4.81 4.99 96.4 PASS Chloroform 733,698 4.91 5.03 97.8 PASS 1,1,1-Trichloroethane 722,697 4.84 4.93 98.2 PASS Cyclohexane 694,548 4.79 5.03 95.4 PASS Carbon tetrachloride 787,264 5.01 5.01 100.0 PASS Benzene 1,067,242 4.81 4.92 97.9 PASS 1,2-Dichloroethane 488,243 4.77 5.05 94.6 PASS Heptane 420,053 4.78 4.97 96.2 PASS Trichloroethene 558,392 5.19 5.00 104.0 PASS 1,2-Dichloropropane 479,211 4.89 4.90 100.0 PASS 1,4-Dioxane 257,430 5.18 4.99 103.9 PASS Bromodichloromethane 771,444 4.93 4.95 99.8 PASS cis-1,3-Dichloropropene 673,980 5.29 4.88 108.5 PASS Methyl isobutyl ketone 1,268,574 5.65 5.11 110.6 PASS Toluene 1,398,118 5.21 5.04 103.5 PASS trans-1,3-Dichloropropene 677,589 5.37 5.06 106.3 PASS 1,1,2-Trichloroethane 509,343 5.26 5.00 105.3 PASS Tetrachloroethene 756,890 5.34 5.00 106.7 PASS QC Summary Report Enthalpy Analytical, LLC Sample Name : 5ppbv TO15 LCS Sample Info : 500mL load; Can #000100; GCMSPrepPg800 Data File : X1904151.D Dilution : 1 Pressurization Factor : 1.000 Acquisition Date : 2019-10-22 08:01:27 Instrument Method : TO15-SCN.M Matrix : AIR Target Compound Response Concentration (PPBV) Tag Value (PPBV) % Recovery Flag 2-Hexanone (Methyl butyl ketone)1,198,541 5.60 5.12 109.3 PASS Dibromochloromethane 1,016,235 5.43 4.94 110.0 PASS 1,2-Dibromoethane 887,322 5.51 5.04 109.3 PASS Chlorobenzene 1,086,866 5.16 5.13 100.5 PASS Ethylbenzene 1,533,446 4.63 4.90 94.6 PASS m-/p-Xylenes 1,329,856 4.77 5.05 94.5 PASS o-Xylene 1,277,065 4.67 4.95 94.4 PASS Styrene 1,036,293 4.81 4.86 99.1 PASS Bromoform 966,311 5.30 5.00 106.0 PASS 1,1,2,2-Tetrachloroethane 1,002,672 4.88 5.00 97.7 PASS 4-Ethyltoluene 1,894,287 5.00 5.03 99.5 PASS 1,3,5-Trimethylbenzene 1,506,240 4.68 5.02 93.3 PASS 1,2,4-Trimethylbenzene 1,548,911 4.73 4.97 95.3 PASS 1,3-Dichlorobenzene 1,149,023 4.96 5.09 97.6 PASS 1,4-Dichlorobenzene 1,138,359 4.96 5.02 98.8 PASS Benzyl chloride 1,357,484 4.89 4.98 98.2 PASS 1,2-Dichlorobenzene 1,138,419 5.04 5.08 99.2 PASS 1,2,4-Trichlorobenzene 849,142 5.61 5.06 110.8 PASS Hexachlorobutadiene 845,305 5.29 5.08 104.2 PASS Naphthalene 2,185,948 5.68 5.21 109.0 PASS Quantitation Report Enthalpy Analytical, LLC Sample Name : 5ppbv TO15 LCS LD Sample Info : 500mL load; Can #000100; GCMSPrepPg800 Data File : X1904152.D Dilution : 1 Pressurization Factor : 1.000 Acquisition Date : 2019-10-22 08:51:08 Instrument Method : TO15-SCN.M Matrix : AIR Target Compound Concentration(PPBV)RL(PPBV)MDL(PPBV)Concentration(ug/m3)RL(ug/m3)MDL(ug/m3) % Diff Flag * Propylene 4.25 0.0384 0.0350 7.31 0.0660 0.0602 0.1 Freon 12 (CCl2F2) 4.67 0.0390 0.0350 23.1 0.193 0.173 0.6 Freon 114 (C2Cl2F4) 4.78 0.0400 0.0350 33.4 0.280 0.245 0.7 Chloromethane 4.74 0.0390 0.0350 9.79 0.0805 0.0723 1.2 Chloroethene (Vinyl chloride) 4.84 0.0402 0.0350 12.4 0.103 0.0895 12.2 1,3-Butadiene 5.03 0.0391 0.0350 11.1 0.0865 0.0774 1.0 Bromomethane 5.10 0.0396 0.0350 19.8 0.154 0.136 1.6 Chloroethane 4.66 0.0403 0.0350 12.3 0.106 0.0924 7.3 Freon 11 (CCl3F) 5.62 0.0415 0.0350 31.6 0.233 0.197 10.7 Ethanol 4.91 0.100 0.0400 9.25 0.188 0.0754 3.4 Freon 113 (C2Cl3F3) 5.03 0.0398 0.0350 38.5 0.305 0.268 1.0 1,1-Dichloroethene 4.56 0.0400 0.0350 18.1 0.159 0.139 1.3 Acetone 4.29 0.0402 0.0350 10.2 0.0955 0.0831 1.9 Carbon disulfide 4.56 0.0402 0.0350 14.2 0.125 0.109 1.6 Isopropyl alcohol 4.76 0.0402 0.0350 11.7 0.0987 0.0860 1.2 Methylene chloride 4.53 0.101 0.101 15.7 0.352 0.352 2.2 trans-1,2-Dichloroethene 4.77 0.0408 0.0350 18.9 0.162 0.139 0.7 Methyl tert-butyl ether 4.73 0.0410 0.0350 17.0 0.148 0.126 0.5 Hexane 4.74 0.0404 0.0350 16.7 0.143 0.123 1.2 1,1-Dichloroethane 4.70 0.0394 0.0350 19.0 0.159 0.142 0.4 Vinyl acetate 4.83 0.0407 0.0350 17.0 0.143 0.123 1.0 m cis-1,2-Dichloroethene 4.83 0.0403 0.0350 19.1 0.160 0.139 0.3 Methyl ethyl ketone (2-Butanone) 4.93 0.0406 0.0350 14.5 0.120 0.103 0.7 Ethyl acetate 4.72 0.0403 0.0350 17.0 0.145 0.126 1.9 m Chloroform 4.88 0.0404 0.0350 23.8 0.197 0.171 0.6 Tetrahydrofuran 4.78 0.0404 0.0350 14.1 0.119 0.103 0.8 1,1,1-Trichloroethane 4.77 0.0398 0.0350 26.0 0.217 0.191 1.5 Cyclohexane 4.73 0.0407 0.0350 16.3 0.140 0.120 1.3 Carbon tetrachloride 5.00 0.0405 0.0350 31.5 0.255 0.220 0.1 Benzene 4.78 0.0399 0.0350 15.3 0.128 0.112 0.6 1,2-Dichloroethane 4.77 0.0409 0.0350 19.3 0.165 0.142 0.0 Heptane 4.75 0.0402 0.0350 19.5 0.165 0.143 0.6 Trichloroethene 5.20 0.0402 0.0350 27.9 0.216 0.188 0.1 1,2-Dichloropropane 4.89 0.0409 0.0350 22.6 0.189 0.162 0.0 1,4-Dioxane 5.17 0.0404 0.0350 18.6 0.146 0.126 0.1 Bromodichloromethane 4.89 0.0397 0.0350 32.8 0.266 0.235 0.8 cis-1,3-Dichloropropene 4.87 0.0393 0.0350 22.1 0.178 0.159 8.4 Methyl isobutyl ketone 5.02 0.0412 0.0350 20.6 0.169 0.143 11.8 Toluene 4.81 0.0406 0.0350 18.1 0.153 0.132 7.9 trans-1,3-Dichloropropene 4.90 0.0406 0.0350 22.2 0.184 0.159 9.1 1,1,2-Trichloroethane 4.84 0.0401 0.0350 26.4 0.219 0.191 8.4 Tetrachloroethene 5.12 0.0404 0.0350 34.7 0.274 0.237 4.1 2-Hexanone (Methyl butyl ketone) 5.04 0.0406 0.0350 20.7 0.166 0.143 10.4 Dibromochloromethane 5.07 0.0395 0.0350 43.2 0.336 0.298 6.7 1,2-Dibromoethane 5.11 0.0405 0.0350 39.3 0.311 0.269 7.5 Chlorobenzene 5.16 0.0412 0.0350 23.7 0.189 0.161 0.1 Ethylbenzene 4.69 0.0394 0.0350 20.3 0.171 0.152 1.1 m-/p-Xylenes 4.80 0.0405 0.0350 20.8 0.176 0.152 0.6 o-Xylene 4.70 0.0400 0.0350 20.4 0.174 0.152 0.6 Styrene 4.79 0.0390 0.0350 20.4 0.166 0.149 0.4 Bromoform 5.30 0.0402 0.0350 54.8 0.415 0.362 0.2 1,1,2,2-Tetrachloroethane 4.92 0.0400 0.0350 33.8 0.275 0.240 0.9 4-Ethyltoluene 5.03 0.0403 0.0350 24.7 0.198 0.172 0.6 1,3,5-Trimethylbenzene 4.68 0.0401 0.0350 23.0 0.197 0.172 0.1 1,2,4-Trimethylbenzene 4.77 0.0398 0.0350 23.4 0.195 0.172 0.8 1,3-Dichlorobenzene 5.00 0.0404 0.0350 30.1 0.243 0.210 0.8 1,4-Dichlorobenzene 4.98 0.0401 0.0350 30.0 0.241 0.210 0.4 Benzyl chloride 4.95 0.0399 0.0350 25.6 0.207 0.181 1.2 1,2-Dichlorobenzene 5.11 0.0408 0.0350 30.7 0.245 0.210 1.4 1,2,4-Trichlorobenzene 5.71 0.0406 0.0350 42.4 0.301 0.260 1.9 Hexachlorobutadiene 5.41 0.0401 0.0350 57.7 0.427 0.373 2.2 Naphthalene 5.79 0.0414 0.0350 30.3 0.217 0.183 1.9 Quantitation Report Enthalpy Analytical, LLC Sample Name : 5ppbv TO15 LCS LD Sample Info : 500mL load; Can #000100; GCMSPrepPg800 Data File : X1904152.D Dilution : 1 Pressurization Factor : 1.000 Acquisition Date : 2019-10-22 08:51:08 Instrument Method : TO15-SCN.M Matrix : AIR Target Compound Concentration(PPBV)RL(PPBV)MDL(PPBV)Concentration(ug/m3)RL(ug/m3)MDL(ug/m3) % Diff Flag * Internal Standards Response Retention Time (min) Concentration (PPBV) Flag * Bromochloromethane (IS) 415,611 11.92 5.00 PASS 1,4-Difluorobenzene (IS) 1,585,899 13.67 5.04 PASS Chlorobenzene-d5 (IS) 1,354,087 17.85 4.80 PASS (ND) = Not Detected * (J) = Below Calibration Range, (E) = Above Calibration Range, (m) = Manual Integration IS Acceptance Criteria: RT +/- 20 sec, Response +/- 40% QC Summary Report Enthalpy Analytical, LLC Sample Name : 5ppbv TO15 LCS LD Sample Info : 500mL load; Can #000100; GCMSPrepPg800 Data File : X1904152.D Dilution : 1 Pressurization Factor : 1.000 Acquisition Date : 2019-10-22 08:51:08 Instrument Method : TO15-SCN.M Matrix : AIR Target Compound Response Concentration (PPBV) Tag Value (PPBV) % Recovery Flag Propylene 344,280 4.25 4.79 88.6 PASS Freon 12 (CCl2F2)749,994 4.67 4.81 97.2 PASS Freon 114 (C2Cl2F4)856,234 4.78 4.98 96.0 PASS Chloromethane 418,411 4.74 4.86 97.5 PASS Chloroethene (Vinyl chloride)381,319 4.84 4.99 97.0 PASS 1,3-Butadiene 375,542 5.03 4.83 104.2 PASS Bromomethane 345,030 5.10 4.90 104.0 PASS Chloroethane 194,638 4.66 5.01 92.9 PASS Freon 11 (CCl3F)992,491 5.62 5.16 109.0 PASS Ethanol 203,767 4.91 4.91 100.1 PASS 1,1-Dichloroethene 616,667 4.56 4.98 91.7 PASS Freon 113 (C2Cl3F3)632,098 5.03 4.96 101.4 PASS Acetone 618,999 4.29 4.94 87.0 PASS Isopropyl alcohol 791,148 4.76 4.95 96.3 PASS Carbon disulfide 1,019,181 4.56 4.97 91.8 PASS Methylene chloride 593,485 4.53 5.01 90.4 PASS Methyl tert-butyl ether 895,281 4.73 5.05 93.6 PASS trans-1,2-Dichloroethene 578,248 4.77 5.05 94.5 PASS Hexane 655,292 4.74 5.04 94.1 PASS Vinyl acetate 1,154,702 4.83 5.02 96.2 PASS 1,1-Dichloroethane 703,129 4.70 4.88 96.4 PASS Methyl ethyl ketone (2-Butanone)175,510 4.93 5.08 97.2 PASS cis-1,2-Dichloroethene 684,758 4.83 4.97 97.1 PASS Ethyl acetate 154,953 4.72 5.01 94.3 PASS Tetrahydrofuran 162,833 4.78 4.99 95.7 PASS Chloroform 728,742 4.88 5.03 97.2 PASS 1,1,1-Trichloroethane 711,932 4.77 4.93 96.8 PASS Cyclohexane 685,052 4.73 5.03 94.1 PASS Carbon tetrachloride 786,410 5.00 5.01 99.9 PASS Benzene 1,054,706 4.78 4.92 97.2 PASS 1,2-Dichloroethane 485,529 4.77 5.05 94.6 PASS Heptane 415,317 4.75 4.97 95.6 PASS Trichloroethene 555,719 5.20 5.00 104.0 PASS 1,2-Dichloropropane 476,721 4.89 4.90 100.0 PASS 1,4-Dioxane 255,701 5.17 4.99 103.8 PASS Bromodichloromethane 760,865 4.89 4.95 99.0 PASS cis-1,3-Dichloropropene 616,296 4.87 4.88 99.7 PASS Methyl isobutyl ketone 1,120,945 5.02 5.11 98.3 PASS Toluene 1,277,007 4.81 5.04 95.6 PASS trans-1,3-Dichloropropene 611,169 4.90 5.06 97.0 PASS 1,1,2-Trichloroethane 462,743 4.84 5.00 96.8 PASS Tetrachloroethene 718,077 5.12 5.00 102.4 PASS QC Summary Report Enthalpy Analytical, LLC Sample Name : 5ppbv TO15 LCS LD Sample Info : 500mL load; Can #000100; GCMSPrepPg800 Data File : X1904152.D Dilution : 1 Pressurization Factor : 1.000 Acquisition Date : 2019-10-22 08:51:08 Instrument Method : TO15-SCN.M Matrix : AIR Target Compound Response Concentration (PPBV) Tag Value (PPBV) % Recovery Flag 2-Hexanone (Methyl butyl ketone)1,067,191 5.04 5.12 98.5 PASS Dibromochloromethane 938,863 5.07 4.94 102.8 PASS 1,2-Dibromoethane 813,741 5.11 5.04 101.4 PASS Chlorobenzene 1,074,845 5.16 5.13 100.6 PASS Ethylbenzene 1,532,803 4.69 4.90 95.7 PASS m-/p-Xylenes 1,321,666 4.80 5.05 95.1 PASS o-Xylene 1,269,281 4.70 4.95 95.0 PASS Styrene 1,020,235 4.79 4.86 98.7 PASS Bromoform 956,436 5.30 5.00 106.2 PASS 1,1,2,2-Tetrachloroethane 999,436 4.92 5.00 98.5 PASS 4-Ethyltoluene 1,882,527 5.03 5.03 100.0 PASS 1,3,5-Trimethylbenzene 1,489,309 4.68 5.02 93.3 PASS 1,2,4-Trimethylbenzene 1,543,192 4.77 4.97 96.0 PASS 1,3-Dichlorobenzene 1,145,117 5.00 5.09 98.4 PASS 1,4-Dichlorobenzene 1,129,635 4.98 5.02 99.3 PASS Benzyl chloride 1,358,197 4.95 4.98 99.4 PASS 1,2-Dichlorobenzene 1,140,706 5.11 5.08 100.6 PASS 1,2,4-Trichlorobenzene 855,128 5.71 5.06 112.9 PASS Hexachlorobutadiene 853,548 5.41 5.08 106.5 PASS Naphthalene 2,201,415 5.79 5.21 111.1 PASS Canister and Controller Data Sheet Enthalpy Analytical, LLC Client Name: Hart & Hickman Client #: CLX-003 Enthalpy Job #: 0919-153 Controller ID Data File Initial Flow (cc/min) Return Flow (cc/min) E-017 X1903701 153.6 153.0 E-021 T1702061 156.0 155.0 E-001 T1702073 153.0 156.0 E044 T1702067 155.0 154.0 E-028 X1903660 150.0 148.0 E-003 X1903660 143.0 142.0 SGS-001 X1903796 131.0 129.0 SGS-009 X1903796 130.0 130.0 Canister ID Sample ID Canister Pressure Pre-Sample (mmHg) Canister Pressure Post-Sample (mmHg) Canister Pressure Final (mmHg) Canister Pressurization Factor 190 X1903636/A1901196 -763 -53 752 2.137 144 X1903640/A1901194 -763 -52 738 2.114 955 X1903639/A1901200 -763 -50 721 2.084 580 X1903626/A1901195 -763 -73 834 2.318 942 X1903645/A1901203 -763 -68 719 2.135 898 X1903643 -763 -165 738 2.514 00198 X1902681 -763 -69 713 2.130 Date Prepared: 9/23/19 Prepared By: BWRDate Received: 10/22/19 Received By: DSM Controller Data Canister Data 0919‐153 CanContrDataSheet V6c (complete) Narrative Summary Enthalpy Analytical Narrative Summary Company Hart & Hickman - Raleigh Client #CLX-003 Analyst TDD Job #0919-153 Parameters EPA Method TO-15 # Samples 7 Canisters Custody David Myers received the samples on 10/18/19 after being relinquished by Hart & Hickman – Raleigh. The samples were received at ambient temperature and in good condition. Prior to, during, and after analysis, the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, LLC. Analysis The samples were analyzed for the client requested TO-15 target compound list using the analytical procedures in EPA Method TO-15, Determination of Volatile Organic Compounds (VOCs) In Air Collected In Specially-Prepared Canisters And Analyzed by Gas Chromatography/Mass Spectrometry (GC/MS). Upon receipt, the canister pressures were measured and recorded. The cans were then pressurized and a dilution ratio was calculated for each (see the Canister and Controller Data Sheet in this report). All samples were analyzed undiluted. Samples SG-4, SG-5, SG-6 and SG-7 were analyzed at a subsequent 10-fold dilution to bring ethanol and/or acetone within the instrument’s calibrated range. Only compounds that exceeded the instrument’s calibration range in the undiluted analysis have been reported in the diluted analysis. The Agilent Technologies Model 6890N, Gas Chromatograph "Xavier" (S/N US10721018) equipped with a 5975C VL Mass Selective Detector (S/N US71215962) and a Restek Rxi-624 Sil MS, 60 m x 0.32 mm x 1.8 µm (S/N 1555499) capillary column was used for these analyses. The samples and standards were introduced directly to the analyzer using an Entech 7200 Preconcentrator Calibration The associated BFB tune met method acceptance criteria. The initial calibration (X082919A-TO15) met the 30% RSD criteria. The initial calibration verification met the 30% recovery criteria. The continuing calibration met the 30% difference criteria. Full calibration data is available upon request. Chromatographic Conditions The acquisition method (TO15-SCN2.M) is not included in this report but is available upon request. Enthalpy Analytical Narrative Summary (continued) QC Notes The BFB tunes associated with this analysis met method acceptance criteria. All internal standard area responses and retention time criteria were met for these analyses. The Laboratory Control Standards (LCS) met 70-130% recovery criteria with allowances. The Laboratory Duplicates (LD) associated with sample data met the 25% difference acceptance criteria. There were no target analytes detected in the associated humid blank at concentrations greater than 3 times the MDL. The samples were analyzed within the 30-day holding time required by the method. Reporting Notes The LCS was analyzed in duplicate and has been reported as a Laboratory Duplicate in the Lab QC section of this report. These analyses met the requirements of the TNI Standard. Any deviations from the requirements of the reference method or TNI Standard have been stated above. The results presented in this report are representative of the samples as provided to the laboratory. General Reporting Notes The following are general reporting notes that are applicable to all Enthalpy Analytical, LLC data reports, unless specifically noted otherwise.  Any analysis which refers to the method as “Type” represents a planned deviation from the reference method. For instance a Hydrogen Sulfide assay from a Tedlar bag would be labeled as “EPA Method 16-Type” because Tedlar bags are not mentioned as one of the collection options in EPA Method 16.  The acronym MDL represents the Minimum Detection Limit. Below this value the laboratory cannot determine the presence of the analyte of interest reliably.  The acronym LOQ represents the Limit of Quantification. Below this value the laboratory cannot quantitate the analyte of interest within the criteria of the method.  The acronym ND following a value indicates a non-detect or analytical result below the MDL.  The letter J in the Qualifier or Flag column in the results indicates that the value is between the MDL and the LOQ. The laboratory can positively identify the analyte of interest as present, but the value should be considered an estimate.  The letter E in the Qualifier or Flag column indicates an analytical result exceeding 100% of the highest calibration point. The associated value should be considered as an estimate.  Sample results are presented ‘as measured’ for single injection methodologies, or an average value if multiple injections are made. If all injections are below the MDL, the sample is considered non-detect and the ND value is presented. If one, but not all, are below the MDL, the MDL value is used for any injections that are below the MDL. For example, if the MDL is 0.500 and LOQ is 1.00, and the instrument measures 0.355, 0.620, and 0.442 - the result reported is the average of 0.500, 0.620, and 0.500 - - - i.e. 0.540 with a J flag.  When a spike recovery (Bag Spike, Collocated Spike Train, or liquid matrix spike) is being calculated, the native (unspiked) sample result is used in the calculations, as long as the value is above the MDL. If a sample is ND, then 0 is used as the native amount (not the MDL value).  The acronym DF represents Dilution Factor. This number represents dilution of the sample during the preparation and/or analysis process. The analytical result taken from a laboratory instrument is multiplied by the DF to determine the final undiluted sample results.  The addition of MS to the Sample ID represents a Matrix Spike. An aliquot of an actual sample is spiked with a known amount of analyte so that a percent recovery value can be determined. The MS analysis indicates what effect the sample matrix may have on the target analyte, i.e. whether or not anything in the sample matrix interferes with the analysis of the analyte(s). General Reporting Notes (continued)  The addition of MSD to the Sample ID represents a Matrix Spike Duplicate. Prepared in the same manner as a MS, the use of duplicate matrix spikes allows further confirmation of laboratory quality by showing the consistency of results gained by performing the same steps multiple times.  The addition of LD to the Sample ID represents a Laboratory Duplicate. The analyst prepares an additional aliquot of sample for testing and the results of the duplicate analysis are compared to the initial result. The result should have a difference value of within 10% of the initial result (if the results of the original analysis are greater than the LOQ).  The addition of AD to the Sample ID represents an Alternate Dilution. The analyst prepares an additional aliquot at a different dilution factor (usually double the initial factor). This analysis helps confirm that no additional compound is present and coeluting or sharing absorbance with the analyte of interest, as they would have a different response/absorbance than the analyte of interest.  The Sample ID LCS represents a Laboratory Control Sample. Clean matrix, similar to the client sample matrix, prepared and analyzed by the laboratory using the same reagents, spiking standards and procedures used for the client samples. The LCS is used to assess the control of the laboratory’s analytical system. Whenever spikes are prepared for our client projects, two spikes are retained as LCSs. The LCSs are labeled with the associated project number and kept in-house at the appropriate temperature conditions. When the project samples are received for analysis, the LCSs are analyzed to confirm that the analyte could be recovered from the media, separate from the samples which were used on the project and which may have been affected by source matrix, sample collection, and/or sample transport.  Significant Figures: Where the reported value is much greater than unity (1.00) in the units expressed, the number is rounded to a whole number of units, rather than to 3 significant figures. For example, a value of 10,456.45 ug catch is rounded to 10,456 ug. There are five significant digits displayed, but no confidence should be placed on more than two significant digits. In the case of small numbers, generally 3 significant figures are presented, but still only 2 should be used with confidence. Many neat materials are only certified to 3 digits, and as the mathematically correct final result is always 1 digit less than all its pre-cursors - 2 significant figures are what are most defensible.  Manual Integration: The data systems used for processing will flag manually integrated peaks with an “M”. There are several reasons a peak may be manually integrated. These reasons will be identified by the following two letter designations on sample chromatograms, if provided in the report. The peak was not integrated by the software “NI”, the peak was integrated incorrectly by the software “II” or the wrong peak was integrated by the software “WP”. These codes will accompany the analyst’s manual integration stamp placed next to the compound name on the chromatogram. Sample Custody This Is The Last Page Of This Report. Appendix B DEQ Risk Calculators North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Bull City Ciderworks Facility North Carolina Department of Environmental Quality Risk Calculator Lexington Home Brands Plant #1 411 South Salisbury Street, Lexington, Davidson County, NC Brownfields Program BPN 10054-06-029 December 2019 November 2019 EPA RSL Table Prepared By:Hart & Hickman, PC 3921 Sunset Ridge Road, Suite 301, Raleigh, North Carolina North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: BPN 10054-06-029 Exposure Unit ID: Bull City Ciderworks Facility Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: BPN 10054-06-029 Exposure Unit ID: Bull City Ciderworks Facility Description of Exposure Point Concentration Selection: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 402 SG-7 67-64-1 Acetone ug/m3 1.13 SG-3 71-43-2 Benzene ug/m3 12.2 SG-7 75-15-0 Carbon Disulfide ug/m3 1.48 SG-7 67-66-3 Chloroform ug/m3 8.6 SG-1 110-82-7 Cyclohexane ug/m3 0.578 SG-6 75-71-8 Dichlorodifluoromethane ug/m3 0.319 SG-4 156-59-2 Dichloroethylene, 1,2-cis-ug/m3 0.328 SG-3 123-91-1 Dioxane, 1,4-ug/m3 0.876 SG-5 141-78-6 Ethyl Acetate ug/m3 2.07 SG-3 100-41-4 Ethylbenzene ug/m3 2.81 SG-5 109-99-9 ~Tetrahydrofuran ug/m3 2.81 SG-6 142-82-5 Heptane, N-ug/m3 1.18 SG-3 110-54-3 Hexane, N-ug/m3 11.5 SG-5 591-78-6 Hexanone, 2-ug/m3 1.55 SG-6 67-63-0 Isopropanol ug/m3 66.2 SG-4 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 32.1 SG-7 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 2.73 SG-3 1634-04-4 Methyl tert-Butyl Ether (MTBE)ug/m3 1.07 SG-3 75-09-2 Methylene Chloride ug/m3 1.48 SG-3 100-42-5 Styrene ug/m3 0.547 SG-3 127-18-4 Tetrachloroethylene ug/m3 46 SG-5 108-88-3 Toluene ug/m3 27.8 SG-5 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-ug/m3 2.4 SG-6 79-01-6 Trichloroethylene ug/m3 5.42 SG-3 75-69-4 Trichlorofluoromethane ug/m3 1.79 SG-5 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 0.562 SG-5 108-67-8 Trimethylbenzene, 1,3,5-ug/m3 0.462 SG-5 75-01-4 Vinyl Chloride ug/m3 11.35 SG-3 1330-20-7 Xylenes ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Maximum detected concentrations in the Bull City Ciderworks facility. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: BPN 10054-06-029 Exposure Unit ID: Bull City Ciderworks Facility Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 7.7E-07 5.6E-02 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 5.1E-08 4.4E-03 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: BPN 10054-06-029 Exposure Unit ID: Bull City Ciderworks Facility CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 402 12.06 -6.5E+03 3.7E-04 71-43-2 Benzene 1.13 0.0339 3.6E-01 6.3E+00 9.4E-08 1.1E-03 75-15-0 Carbon Disulfide 12.2 0.366 -1.5E+02 5.0E-04 67-66-3 Chloroform 1.48 0.0444 1.2E-01 2.0E+01 3.6E-07 4.3E-04 110-82-7 Cyclohexane 8.6 0.258 -1.3E+03 4.1E-05 75-71-8 Dichlorodifluoromethane 0.578 0.01734 -2.1E+01 1.7E-04 156-59-2 Dichloroethylene, 1,2-cis-0.319 0.00957 -- 123-91-1 Dioxane, 1,4-0.328 0.00984 5.6E-01 6.3E+00 1.8E-08 3.1E-04 141-78-6 Ethyl Acetate 0.876 0.02628 -1.5E+01 3.6E-04 100-41-4 Ethylbenzene 2.07 0.0621 1.1E+00 2.1E+02 5.5E-08 6.0E-05 109-99-9 ~Tetrahydrofuran 2.81 0.0843 -4.2E+02 4.0E-05 142-82-5 Heptane, N-2.81 0.0843 -8.3E+01 2.0E-04 110-54-3 Hexane, N-1.18 0.0354 -1.5E+02 4.8E-05 591-78-6 Hexanone, 2-11.5 0.345 -6.3E+00 1.1E-02 67-63-0 Isopropanol 1.55 0.0465 -4.2E+01 2.2E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)66.2 1.986 -1.0E+03 3.8E-04 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)32.1 0.963 -6.3E+02 3.1E-04 1634-04-4 Methyl tert-Butyl Ether (MTBE)2.73 0.0819 1.1E+01 6.3E+02 7.6E-09 2.6E-05 75-09-2 Methylene Chloride 1.07 0.0321 1.0E+02 1.3E+02 3.2E-10 5.1E-05 100-42-5 Styrene 1.48 0.0444 -2.1E+02 4.3E-05 127-18-4 Tetrachloroethylene 0.547 0.01641 1.1E+01 8.3E+00 1.5E-09 3.9E-04 108-88-3 Toluene 46 1.38 -1.0E+03 2.6E-04 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-27.8 0.834 -1.0E+03 1.6E-04 79-01-6 Trichloroethylene 2.4 0.072 4.8E-01 4.2E-01 1.5E-07 3.5E-02 75-69-4 Trichlorofluoromethane 5.42 0.1626 -- 95-63-6 Trimethylbenzene, 1,2,4-1.79 0.0537 -1.3E+01 8.6E-04 108-67-8 Trimethylbenzene, 1,3,5-0.562 0.01686 -1.3E+01 2.7E-04 75-01-4 Vinyl Chloride 0.462 0.01386 1.7E-01 2.1E+01 8.3E-08 1.3E-04 1330-20-7 Xylenes 11.35 0.3405 -2.1E+01 3.3E-03 Cumulative:7.7E-07 5.6E-02 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: BPN 10054-06-029 Exposure Unit ID: Bull City Ciderworks Facility CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 402 4.02 -2.7E+04 3.0E-05 71-43-2 Benzene 1.13 0.0113 1.6E+00 2.6E+01 7.2E-09 8.6E-05 75-15-0 Carbon Disulfide 12.2 0.122 -6.1E+02 4.0E-05 67-66-3 Chloroform 1.48 0.0148 5.3E-01 8.6E+01 2.8E-08 3.4E-05 110-82-7 Cyclohexane 8.6 0.086 -5.3E+03 3.3E-06 75-71-8 Dichlorodifluoromethane 0.578 0.00578 -8.8E+01 1.3E-05 156-59-2 Dichloroethylene, 1,2-cis-0.319 0.00319 --123-91-1 Dioxane, 1,4-0.328 0.00328 2.5E+00 2.6E+01 1.3E-09 2.5E-05141-78-6 Ethyl Acetate 0.876 0.00876 -6.1E+01 2.9E-05100-41-4 Ethylbenzene 2.07 0.0207 4.9E+00 8.8E+02 4.2E-09 4.7E-06 109-99-9 ~Tetrahydrofuran 2.81 0.0281 -1.8E+03 3.2E-06 142-82-5 Heptane, N-2.81 0.0281 -3.5E+02 1.6E-05 110-54-3 Hexane, N-1.18 0.0118 -6.1E+02 3.8E-06591-78-6 Hexanone, 2-11.5 0.115 -2.6E+01 8.8E-0467-63-0 Isopropanol 1.55 0.0155 -1.8E+02 1.8E-0578-93-3 Methyl Ethyl Ketone (2-Butanone)66.2 0.662 -4.4E+03 3.0E-05 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)32.1 0.321 -2.6E+03 2.4E-05 1634-04-4 Methyl tert-Butyl Ether (MTBE)2.73 0.0273 4.7E+01 2.6E+03 5.8E-10 2.1E-06 75-09-2 Methylene Chloride 1.07 0.0107 1.2E+03 5.3E+02 8.7E-12 4.1E-06100-42-5 Styrene 1.48 0.0148 -8.8E+02 3.4E-06127-18-4 Tetrachloroethylene 0.547 0.00547 4.7E+01 3.5E+01 1.2E-10 3.1E-05108-88-3 Toluene 46 0.46 -4.4E+03 2.1E-05 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2-27.8 0.278 -4.4E+03 1.3E-05 79-01-6 Trichloroethylene 2.4 0.024 3.0E+00 1.8E+00 8.0E-09 2.7E-03 75-69-4 Trichlorofluoromethane 5.42 0.0542 -- 95-63-6 Trimethylbenzene, 1,2,4-1.79 0.0179 -5.3E+01 6.8E-05 108-67-8 Trimethylbenzene, 1,3,5-0.562 0.00562 -5.3E+01 2.1E-05 75-01-4 Vinyl Chloride 0.462 0.00462 2.8E+00 8.8E+01 1.7E-09 1.1E-051330-20-7 Xylenes 11.35 0.1135 -8.8E+01 2.6E-04 Cumulative:5.1E-08 4.4E-03 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Goose & the Monkey Brewhouse Facility North Carolina Department of Environmental Quality Risk Calculator Lexington Home Brands Plant #1 411 South Salisbury Street, Lexington, Davidson County, NC Brownfields Program BPN 10054-06-029 December 2019 November 2019 EPA RSL Table Prepared By:Hart & Hickman, PC 3921 Sunset Ridge Road, Suite 301, Raleigh, North Carolina North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: BPN 10054-06-029 Exposure Unit ID: Goose & the Monkey Brewhouse Facility Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: BPN 10054-06-029 Exposure Unit ID: Goose & the Monkey Brewhouse Facility Description of Exposure Point Concentration Selection: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 89.6 SG-2 67-64-1 Acetone ug/m3 3.36 SG-2 71-43-2 Benzene ug/m3 0.888 SG-1 100-44-7 Benzyl Chloride ug/m3 0.641 SG-1 74-83-9 Bromomethane ug/m3 1.25 SG-2 106-99-0 Butadiene, 1,3-ug/m3 8.83 SG-2 75-15-0 Carbon Disulfide ug/m3 0.577 SG-1 56-23-5 Carbon Tetrachloride ug/m3 41.8 SG-1 67-66-3 Chloroform ug/m3 5.21 SG-1 74-87-3 Chloromethane ug/m3 6.08 SG-2 110-82-7 Cyclohexane ug/m3 0.55 SG-2 106-46-7 Dichlorobenzene, 1,4-ug/m3 2.34 SG-1 75-71-8 Dichlorodifluoromethane ug/m3 1.62 SG-1 75-00-3 Ethyl Chloride (Chloroethane)ug/m3 1.12 SG-1 100-41-4 Ethylbenzene ug/m3 1.4 SG-1 109-99-9 ~Tetrahydrofuran ug/m3 18.1 SG-1 142-82-5 Heptane, N-ug/m3 17.5 SG-1 110-54-3 Hexane, N-ug/m3 1.45 SG-1 591-78-6 Hexanone, 2-ug/m3 34.7 SG-2 67-63-0 Isopropanol ug/m3 19.5 SG-1 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 1.18 SG-1 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 1.14 SG-2 1634-04-4 Methyl tert-Butyl Ether (MTBE)ug/m3 1.01 SG-1 75-09-2 Methylene Chloride ug/m3 1.04 SG-2 91-20-3 ~Naphthalene ug/m3 10.7 SG-1 115-07-1 Propylene ug/m3 0.415 SG-1 100-42-5 Styrene ug/m3 3.09 SG-1 127-18-4 Tetrachloroethylene ug/m3 4.75 SG-1 108-88-3 Toluene ug/m3 26 SG-2 75-69-4 Trichlorofluoromethane ug/m3 1.04 SG-1, SG-2 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 4.99 SG-1, SG-2 1330-20-7 Xylenes ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Maximum detected concentrations at the Goose & the Monkey Brewhouse facility. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: BPN 10054-06-029 Exposure Unit ID: Goose & the Monkey Brewhouse Facility Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.2E-05 8.9E-02 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 9.1E-07 7.0E-03 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3.NM = Not Modeled 4.NC = Pathway not complete 2.* = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1.If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: BPN 10054-06-029 Exposure Unit ID: Goose & the Monkey Brewhouse Facility CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 89.6 2.688 -6.5E+03 8.3E-0571-43-2 Benzene 3.36 0.1008 3.6E-01 6.3E+00 2.8E-07 3.2E-03100-44-7 Benzyl Chloride 0.888 0.02664 5.7E-02 2.1E-01 4.6E-07 2.6E-0274-83-9 Bromomethane 0.641 0.01923 -1.0E+00 3.7E-03106-99-0 Butadiene, 1,3-1.25 0.0375 9.4E-02 4.2E-01 4.0E-07 1.8E-0275-15-0 Carbon Disulfide 8.83 0.2649 -1.5E+02 3.6E-0456-23-5 Carbon Tetrachloride 0.577 0.01731 4.7E-01 2.1E+01 3.7E-08 1.7E-0467-66-3 Chloroform 41.8 1.254 1.2E-01 2.0E+01 1.0E-05 1.2E-0274-87-3 Chloromethane 5.21 0.1563 -1.9E+01 1.7E-03110-82-7 Cyclohexane 6.08 0.1824 -1.3E+03 2.9E-05106-46-7 Dichlorobenzene, 1,4-0.55 0.0165 2.6E-01 1.7E+02 6.5E-08 2.0E-0575-71-8 Dichlorodifluoromethane 2.34 0.0702 -2.1E+01 6.7E-0475-00-3 Ethyl Chloride (Chloroethane)1.62 0.0486 -2.1E+03 4.7E-06100-41-4 Ethylbenzene 1.12 0.0336 1.1E+00 2.1E+02 3.0E-08 3.2E-05109-99-9 ~Tetrahydrofuran 1.4 0.042 -4.2E+02 2.0E-05142-82-5 Heptane, N-18.1 0.543 -8.3E+01 1.3E-03110-54-3 Hexane, N-17.5 0.525 -1.5E+02 7.2E-04591-78-6 Hexanone, 2-1.45 0.0435 -6.3E+00 1.4E-0367-63-0 Isopropanol 34.7 1.041 -4.2E+01 5.0E-0378-93-3 Methyl Ethyl Ketone (2-Butanone)19.5 0.585 -1.0E+03 1.1E-04108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)1.18 0.0354 -6.3E+02 1.1E-051634-04-4 Methyl tert-Butyl Ether (MTBE)1.14 0.0342 1.1E+01 6.3E+02 3.2E-09 1.1E-0575-09-2 Methylene Chloride 1.01 0.0303 1.0E+02 1.3E+02 3.0E-10 4.8E-0591-20-3 ~Naphthalene 1.04 0.0312 8.3E-02 6.3E-01 3.8E-07 1.0E-02115-07-1 Propylene 10.7 0.321 -6.3E+02 1.0E-04100-42-5 Styrene 0.415 0.01245 -2.1E+02 1.2E-05127-18-4 Tetrachloroethylene 3.09 0.0927 1.1E+01 8.3E+00 8.6E-09 2.2E-03108-88-3 Toluene 4.75 0.1425 -1.0E+03 2.7E-0575-69-4 Trichlorofluoromethane 26 0.78 --95-63-6 Trimethylbenzene, 1,2,4-1.04 0.0312 -1.3E+01 5.0E-041330-20-7 Xylenes 4.99 0.1497 -2.1E+01 1.4E-03 Cumulative:1.2E-05 8.9E-02 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: BPN 10054-06-029 Exposure Unit ID: Goose & the Monkey Brewhouse Facility CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 89.6 0.896 -2.7E+04 6.6E-0671-43-2 Benzene 3.36 0.0336 1.6E+00 2.6E+01 2.1E-08 2.6E-04100-44-7 Benzyl Chloride 0.888 0.00888 2.5E-01 8.8E-01 3.5E-08 2.0E-03 74-83-9 Bromomethane 0.641 0.00641 -4.4E+00 2.9E-04 106-99-0 Butadiene, 1,3-1.25 0.0125 4.1E-01 1.8E+00 3.1E-08 1.4E-03 75-15-0 Carbon Disulfide 8.83 0.0883 -6.1E+02 2.9E-05 56-23-5 Carbon Tetrachloride 0.577 0.00577 2.0E+00 8.8E+01 2.8E-09 1.3E-05 67-66-3 Chloroform 41.8 0.418 5.3E-01 8.6E+01 7.8E-07 9.7E-04 74-87-3 Chloromethane 5.21 0.0521 -7.9E+01 1.3E-04110-82-7 Cyclohexane 6.08 0.0608 -5.3E+03 2.3E-06106-46-7 Dichlorobenzene, 1,4-0.55 0.0055 1.1E+00 7.0E+02 4.9E-09 1.6E-0675-71-8 Dichlorodifluoromethane 2.34 0.0234 -8.8E+01 5.3E-05 75-00-3 Ethyl Chloride (Chloroethane)1.62 0.0162 -8.8E+03 3.7E-07 100-41-4 Ethylbenzene 1.12 0.0112 4.9E+00 8.8E+02 2.3E-09 2.6E-06 109-99-9 ~Tetrahydrofuran 1.4 0.014 -1.8E+03 1.6E-06 142-82-5 Heptane, N-18.1 0.181 -3.5E+02 1.0E-04 110-54-3 Hexane, N-17.5 0.175 -6.1E+02 5.7E-05591-78-6 Hexanone, 2-1.45 0.0145 -2.6E+01 1.1E-04 67-63-0 Isopropanol 34.7 0.347 -1.8E+02 4.0E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)19.5 0.195 -4.4E+03 8.9E-06 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)1.18 0.0118 -2.6E+03 9.0E-07 1634-04-4 Methyl tert-Butyl Ether (MTBE)1.14 0.0114 4.7E+01 2.6E+03 2.4E-10 8.7E-0775-09-2 Methylene Chloride 1.01 0.0101 1.2E+03 5.3E+02 8.2E-12 3.8E-0691-20-3 ~Naphthalene 1.04 0.0104 3.6E-01 2.6E+00 2.9E-08 7.9E-04 115-07-1 Propylene 10.7 0.107 -2.6E+03 8.1E-06 100-42-5 Styrene 0.415 0.00415 -8.8E+02 9.5E-07 127-18-4 Tetrachloroethylene 3.09 0.0309 4.7E+01 3.5E+01 6.6E-10 1.8E-04 108-88-3 Toluene 4.75 0.0475 -4.4E+03 2.2E-06 75-69-4 Trichlorofluoromethane 26 0.26 -- 95-63-6 Trimethylbenzene, 1,2,4-1.04 0.0104 -5.3E+01 4.0E-051330-20-7 Xylenes 4.99 0.0499 -8.8E+01 1.1E-04 Cumulative:9.1E-07 7.0E-03 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.