MO-5128_17478_CA_MRP_20200212

Monitoring Report
Gunter’s Grocery
2328 Sandy Springs Road
Harmony, Iredell County, North Carolina 28634
NCDEQ Incident #17478
ATC Project #SLP1747802

February 12, 2020

TABLE OF CONTENTS

1.0 SITE IDENTIFICATION .......................................................................................1
2.0 EXECUTIVE SUMMARY .....................................................................................2
3.0 SITE DESCRIPTION .............................................................................................3
3.1 Site Characterization ................................................................................3
3.2 Site Background .......................................................................................3
3.3 Site and Regional Geology ......................................................................4
3.4 Site and Regional Hydrogeology .............................................................4
4.0 GROUNDWATER CHARACTERIZATION.......................................................5
4.1 Water Supply Wells .................................................................................5
4.2 Groundwater Levels .................................................................................5
4.3 Groundwater Quality ...............................................................................6
5.0 CONCLUSIONS AND RECOMMENDATIONS .................................................7

TABLES AND CHART
Table 1 Water Supply Well Information
Table 2 Current Water Supply Well Analytical Results
Table 3 Historical Water Supply Well Analytical Results
Table 4 Monitoring Well Construction Details
Table 5 Groundwater Elevation Data
Table 6 Field Parameters
Table 7 Current Groundwater Analytical Results
Table 8 Historical Groundwater Analytical Results
Chart 1 MW-1 Groundwater Elevations and VOC Concentrations

FIGURES
Figure 1 Site Location Map
Figure 2 Site Vicinity Map with Water Supply Well Locations
Figure 3 Site Map
Figure 4 Groundwater Elevation Contour Map
Figure 5 Benzene Isoconcentration Contour Map
Figure 6 MTBE Isoconcentration Contour Map
Figure 7 Contaminants of Concern

APPENDICES
Appendix A Field Notes
Appendix B Laboratory Analytical Report
Monitoring Report February 12, 2020
Gunter’s Grocery, Incident #17478, Harmony, NC ATC Project# SLP1747802
2
2.0 EXECUTIVE SUMMARY
ATC Associates of North Carolina, P.C. (ATC) has completed a Monitoring Report documenting
the sampling of six on-site monitoring wells and two water supply wells for Gunter’s Grocery,
located at 2328 Sandy Springs Road in Harmony, North Carolina. The groundwater sampling event
was performed based on a October 11, 2019, Task Authorization (TA-02) by the Trust Fund Branch
of the Underground Storage Tank (UST) Section, Division of Waste Management, North Carolina
Department of Environmental Quality (NCDEQ). The work is being performed as part of the State
Lead Contract #N17004 between NCDEQ and ATC.

Former petroleum USTs at the site released petroleum product to the subsurface prior to their
removal in 1998. The site is currently occupied by a convenience store and grill with retail fuel
operations associated with the store using a separate, newer UST system. The site has a small auto
repair shop.

In accordance with TA-02, ATC collected groundwater samples from six groundwater monitoring
wells (MW-1, MW-2, MW-4, MW-5, MW-6, and MW-7) and two water supply wells (WSW-1 and
WSW-2A) located within a 1,000-foot radius of the site. Based on the recent and historical
assessment activities, the following site conditions are noted:

 Municipal water is not available to the area, and there are 2 active (WSW-1 and WSW-2A)
and one inactive (WSW-2) water supply wells located within 1,000 feet of the source area;
 Light non-aqueous phase liquid (LNAPL) has not been observed in any of the monitoring
wells. There are no current exceedances of the Gross Contamination Levels (GCLs),
although monitoring well MW-1 contained a concentration of methyl tertiary butyl ether
(MTBE) at 19,200 micrograms per liter (µg/L) compared to GCL of 20,000 µg/L;
 Volatile organic compounds (VOCs) were detected at concentrations exceeding the 15A
NCAC 02L Groundwater Quality Standards (2L Standards) in monitoring wells MW-1,
MW-2, MW-6, and MW-7;
 Concentrations of VOCs in MW-1 decreased by 22 percent (MTBE) to 75 percent (toluene)
since the January 2018 sampling event, while concentrations in MW-2, MW-6, and MW-7
increased by approximately 160 to 200 percent. Concentrations in MW-4 remained below
detection limits;
 Three oxygenates, tert-amyl alcohol (TAA), tert-amylmethyl ether (TAME), and tert-butyl
alcohol (TBA), were detected in monitoring wells MW-1 and MW-2. Due to the lack of
historical analyses of these compounds, and the presence of these oxygenates in MW-2
associated with the former USTs, the possible source of the oxygenates is the prior UST
system and prior release;
 No constituents were detected in water supply wells WSW-1 or WSW-2A; and
 The depth to groundwater ranges from approximately 31 to 39 ft-bgs, with groundwater
flow towards the south-southwest of the site.

The historical groundwater level and sampling data for monitoring well MW-1 indicate that
concentrations increase as groundwater levels rise, suggesting residual petroleum in the soil at and
above the average groundwater elevation. Based on these results and pending available funds from
the Trust Fund Program, ATC recommends conducting an Aggressive Fluid Vapor Recovery
Monitoring Report February 12, 2020
Gunter’s Grocery, Incident #17478, Harmony, NC ATC Project# SLP1747802
3
(AFVR) event using wells MW-1 and possibly MW-6 and MW-7. Following the AFVR event,
ATC recommends sampling of wells MW-1, MW-2, MW-4, MW-6 and MW-7 to evaluate the
effectiveness of the remediation efforts. ATC also recommends conducting an updated receptor
survey.

3.0 SITE DESCRIPTION
3.1 Site Characterization
ATC, under contract to the NCDEQ, provided environmental consulting services at the Gunter’s
Grocery property, located at 2328 Sandy Springs Road, in Harmony, Iredell County, North
Carolina. Figure 1 depicts the site location on a topographic map. The site currently operates as Red
Sea Grocery III, a retail convenience store and grill with retail fuel operations associated with the
store. One above ground storage tank for used oil exists for an on-site auto repair shop, which has
no secondary containment. Two active potable water supply wells (WSW-1 and WSW-2A) have
been previously identified within 1,000 feet of the site. Municipal water is not currently available to
the site vicinity. Figure 2 indicates the location of water supply wells in the site vicinity, and Table
1 provides the water supply well information.

3.2 Site Background
The two former 4,000- gallon gasoline USTs were removed by Triad Environmental Consultants,
Inc. in June 1996. Tank closure samples indicated total petroleum hydrocarbon (TPH) exceeding
action levels beneath the former USTs, dispensers, and product lines. A new UST system was
installed at the site in 1997.

On November 11, 1998, Mid-Atlantic Associates, P.A. (Mid-Atlantic) advanced soils borings in
the locations of the formers USTs, dispensers, and product lines. Impact was observed to be the
highest on the south side of the former dispensers and product lines. In August 2001 Mid-
Atlantic oversaw the installation of five Type II monitoring wells (MW-1, MW-2, MW-3, MW-
4, and MW-5) and conducted subsequent groundwater sampling. The wells were installed to
depths between 43 and 45 feet below ground surface (ft-bgs). The groundwater samples
indicated impact above 2L standards in wells MW-1 and MW-2. Prior to the installation of the
Type II monitoring wells, a casing was installed to a depth of 86 ft-bgs for a Type III bedrock
well. Following the casing installation the boring was advanced to roughly 175 feet-bgs and
abandoned since no fractures or water bearing units were encountered.

S&ME, Inc. conducted a mobile multi-phase extraction (MMPE) event on the site in March
2004. The MMPE event took place between March 22 and March 26, 2004, with approximately
96 hours of recovery over the 5-day period. Monitoring wells MW-1 and MW-2 were used for
recovery. A total of 6,384 gallons of impacted groundwater were removed and an estimated 214
pounds of VOCs were recovered in the form of vapor.

On December 13, 2006, Terraine, Inc. oversaw the installation of monitoring wells MW-6 and
MW-7. The wells were installed to 45 ft-bgs. The subsequent groundwater sampling event
results showed concentrations of several constituents exceeding their respective 2L Standards in
the sample taken from well MW-1, with benzene exceeding the 2L Standard in the samples
Monitoring Report February 12, 2020
Gunter’s Grocery, Incident #17478, Harmony, NC ATC Project# SLP1747802
4
collected from wells MW-2, MW-6, and MW-7.

On January 22, 2018, ATC performed groundwater monitoring activities at the site including the
sampling of five on-site monitoring wells (MW-1, MW-2, MW-4, MW-6, and MW-7), as well as
two active potable water supply wells (WSW-1 and WSW-2A) located within a 1,000-foot radius
of the site. The results from the groundwater sampling event indicated concentrations of BTEX
and several other petroleum-related constituents exceeding their respective 2L Standards and
MTBE exceeding the Gross Contamination Level (GCL) in monitoring well MW-1. MTBE was
detected above the 2L Standard in monitoring wells MW-2 and MW-6. No VOCs were detected in
the samples from water supply wells WSW-1 and WSW-2A. This data is consistent with previous
analytical results for water supply wells WSW-1 and WSW-2A. Water supply wells WSW-1 and
WSW-2A are north of the site and appear to be upgradient of subsurface impact based on historical
groundwater flow towards the south-southwest of the site.

Two water supply wells (WSW-1 and WSW-2A) have been reported to be active and located within
1,000 feet of the source. Water supply well WSW-2 located approximately 250 feet northeast of the
source and has been reportedly abandoned, although ATC does not have record of the
abandonment. Historically, a water supply well was noted at the property located at 2298 Sandy
Springs Road (residence located approximately 540 feet southeast of the site), but has not been
reported to be present or to have been sampled over the past few years. Also, the residence at 2321
Sandy Springs Road (residence located approximately 240 feet southeast of the site) appears to have
been vacant for several years, but reportedly used a spring as a water supply.

3.3 Site and Regional Geology

According to the Geologic Map of North Carolina, produced by the State of North Carolina in
1985, the Site lies in the Inner Piedmont Belt of the Piedmont Physiographic Province of North
Carolina. The rock type at the site has been identified as mica schist, which is crystalline
metamorphic rock. The shallow subsurface in most areas of the Piedmont contains residual soil
overburden, including structure-free residuum, saprolite, and partially weathered rock (PWR)
that derive from in-place weathering of the crystalline bedrock. Occasional areas containing
recent deposits of alluvium in the uppermost subsurface are found near streams and rivers.
Saprolite and PWR typically contain some relict structures from the original rock material. Depth
to rock ranges from ground surface at occasional outcrops to depths of greater than 100 feet in
areas of easily weathered rock. Boring logs note the presence of sandy to silty clay at depths up
to 45 ft-bgs, during the installation of the shallow monitoring wells. Bedrock consisting of
micaceous schist was encountered during the advancement of the previously mentioned,
abandoned, deep monitoring well at roughly 86 ft-bgs.

3.4 Site and Regional Hydrogeology
The shallow aquifer occurrence varies in depth from ground surface at springs, creeks, and rivers
to as deep as 50 feet or more beneath upland surfaces in some parts of the Piedmont. Water in the
alluvium or unconsolidated residual material, including saprolite and PWR, usually behaves as
an unconfined aquifer, or water table, and will yield water with head elevation equivalent to the
first elevation where water was encountered. Permeability varies with lithology and is typically
relatively low in residual soils, with higher permeability in saprolite or PWR due to relict rock
Monitoring Report February 12, 2020
Gunter’s Grocery, Incident #17478, Harmony, NC ATC Project# SLP1747802
5
texture and variable susceptibility to weathering exhibited by different minerals in the rock.
Groundwater flow in residual soils or alluvium is usually in rough concurrence with local
topographic conditions and is toward local drainage features. Based on the data from the
monitoring well network, shallow groundwater flows generally to the south-southwest. Depth to
water at the site ranges from approximately 31 to 34 ft-bgs, based on the current groundwater
data, with flow to the southwest, similar to the topographic slope of the local area.

The bedrock fractures or other planar features of the Piedmont Physiographic Province generally
constitute the bedrock aquifer, with the surrounding rock material being effectively
impermeable. Along with fractures, contacts between rock bodies probably constitute zones of
significant groundwater occurrence in the bedrock. The surrounding material and overlying
residuum tend to make the bedrock aquifer a semi-confined aquifer. That is, the overlying water
and soil weight normally results in pressure that causes water in a borehole, which intersects a
fracture or other feature, to rise above the elevation of the fracture or feature. Modern water
supply wells in the Piedmont, likely including those in the site vicinity, are typically installed
with a surface casing through the unconsolidated material, and an open borehole into the bedrock
where water-bearing fractures are encountered.

4.0 GROUNDWATER CHARACTERIZATION
4.1 Water Supply Wells
Two active potable water supply wells (WSW-1 and WSW-2A) have been identified within
1,000 feet of the site. Both wells, WSW-1 and WSW-2A, are currently being used for residential
use as municipal water is not available to the nearby area. The former WSW-2 was replaced by
WSW-2A late in the fourth quarter of 2013 on the property owned by the Gunters across Sandy
Springs Road. Figure 2 depicts the locations of the water supply wells on an aerial overlay with
radial distances from the site. Table 1 summarizes water supply well information. As part of TA-
02, ATC sampled water supply wells WSW-1 and WSW-2A on October 18, 2019, by purging
the nearest accessible spigot or faucet to the wellhead for a minimum of five minutes. The
samples were collected in laboratory-supplied containers; entered into chain of custody control;
placed on ice; and shipped to North Carolina accredited Pace Analytical Services, LLC, in
Huntersville, North Carolina. The groundwater samples were analyzed by EPA Method 6200B
for VOCs including petroleum constituents, ethanol, and oxygenates. No constituents were
detected in the two water supply well samples. Note that wells WSW-1 and WSW-2A are located
upgradient of the source area. Table 2 summarizes current water supply well analytical results,
and Table 3 summarizes historical water supply well analytical results. Field notes from the
October 18, 2019, groundwater monitoring event are presented in Appendix A. The analytical
report is included in Appendix B.

4.2 Groundwater Levels
On October 18, 2019, ATC conducted a groundwater monitoring event. Water levels were
gauged in monitoring wells MW-1, MW-2, MW-4, MW-5, MW-6, and MW-7. Well MW-3 was
reportedly destroyed. LNAPL was not detected in the monitoring well network. Table 4 presents
monitoring well construction details. Figure 3 depicts the monitoring well locations on a site
map. Groundwater elevation data are summarized in Table 5. A groundwater contour map
Monitoring Report February 12, 2020
Gunter’s Grocery, Incident #17478, Harmony, NC ATC Project# SLP1747802
6
depicting groundwater flow is presented in Figure 4, which illustrates flow towards the south-
southwest which is consistent with previous interpretations.

4.3 Groundwater Quality
On October 18, 2019, groundwater samples were collected from monitoring wells MW-1, MW-2,
MW-4, MW-5, MW-6, and MW-7. During sampling activities, a three-volume well purge was
implemented prior to groundwater sample collection to ensure representative groundwater samples.
The groundwater samples from the monitoring well network were analyzed by EPA Method 6200B,
including ethanol and oxygenates in the same manner as the water-supply wells. The analytical
report is included in Appendix B.

Water quality field parameter readings for each well are presented in Table 6. Current groundwater
analytical results are summarized in Table 7. Historical groundwater analytical results are shown in
Table 8. The groundwater analytical results were compared to the 2L Standards and GCLs. Chart 1
illustrates the groundwater elevations and concentrations of benzene and MTBE in monitoring well
MW-1 with time. The historical groundwater level and sampling data for monitoring well MW-1
indicate that concentrations increase as groundwater levels rise, suggesting residual petroleum in the
soil at and above the average groundwater elevation. Groundwater analytical results indicated the
following:

 VOCs were detected at concentrations exceeding the 2L Standards in monitoring wells
MW-1, MW-2, MW-6, and MW-7, with the greatest concentrations in MW-1;
 Oxygenates were detected at concentrations exceeding the 2L Standards in monitoring wells
MW-1 and MW-2. Note that the recent sampling event is the first event that included the
analysis of oxygenates;
 Concentrations in MW-1 decreased by approximately 54 percent since the January 2018
sampling event, while concentrations in MW-2, MW-6 and MW-7 increased by
approximately 160 to 200 percent. Concentrations in MW-4 remained below detection
limits;

Isoconcentration maps for dissolved benzene and MTBE are depicted in Figure 5 and Figure 6,
respectively. Figure 7 depicts concentrations of additional detected compounds.

As part of ATC’s quality assurance and quality control (QA and QC) measures, a data review of the
laboratory reports was conducted. During the review, it was found that the samples were received
from the laboratory in acceptable condition and properly preserved. The samples were analyzed
within correct holding times and reported within the lab report, and the chain of custody was
properly completed by all parties. The laboratory QC report shows that an internal blank was
analyzed for each method that was used for the original samples. The laboratory fortified blank
(LFB) and laboratory control sample (LCS) data results were also provided for each analytical
method. ATC also collected a field blank during the groundwater monitoring event, and no
constituents were detected in the field blank. Refer to the laboratory reports in Appendix B for
details regarding QA results for the laboratory samples and any noted exceptions. Overall, ATC
concludes that the laboratory results are usable and any exceptions do not significantly impact the
conclusions presented in this report.
Monitoring Report February 12, 2020
Gunter’s Grocery, Incident #17478, Harmony, NC ATC Project# SLP1747802
7
5.0 CONCLUSIONS AND RECOMMENDATIONS
On behalf of the Trust Fund Branch of the UST Section, ATC submits this Monitoring Report
documenting the October 18, 2019, sampling event for Gunter’s Grocery, located at 2328 Sandy
Springs Road in Harmony, Iredell County, North Carolina. In accordance with TA-02, ATC
collected groundwater samples from six monitoring wells (MW-1, MW-2, MW-4, MW-5, MW-6,
and MW-7) and from two water supply wells (WSW-1 and WSW-2A), located within a 1,000-foot
radius of the site. Based on the recent and historical assessment activities, the following site
conditions are noted:

 Municipal water is not available to the area, and there are 2 active (WSW-1 and WSW-2A)
and one inactive (WSW-2) water supply wells located within 1,000 feet of the source area;
 LNAPL has not been observed in any of the monitoring wells. There are no current
exceedances of the GCLs, although monitoring well MW-1 contained a concentration of
MTBE at 19,200 micrograms per liter (µg/L) compared to GCL of 20,000 µg/L;
 VOCs were detected at concentrations exceeding the 2L Standards in monitoring wells
MW-1, MW-2, MW-6, and MW-7;
 Concentrations of VOCs in MW-1 decreased 22 percent (MTBE) to 75 percent (toluene)
since the January 2018 sampling event, while concentrations in MW-2, MW-6, and MW-7
increased by approximately 160 to 200 percent. Concentrations in MW-4 remained below
detection limits;
 Three oxygenates, tert-amyl alcohol (TAA), tert-amylmethyl ether (TAME), and tert-butyl
alcohol (TBA), were detected in monitoring wells MW-1 and MW-2. Due to the lack of
historical analyses of these compounds, and the presence of these oxygenates in MW-2
associated with the former USTs, the possible source of the oxygenates is the prior UST
system and prior release;
 No constituents were detected in water supply well samples WSW-1 or WSW-2A; and
 The depth to groundwater ranges from approximately 31 to 39 ft bgs, with groundwater
flow towards the south-southwest of the site.

The historical groundwater level and sampling data for monitoring well MW-1 indicate that
concentrations increase as groundwater levels rise, suggesting residual petroleum in the soil at and
above the average groundwater elevation. Based on these results and pending available funds from
the Trust Fund Program, ATC recommends conducting an Aggressive Fluid Vapor Recovery
(AFVR) event using wells MW-1 and possibly MW-6 and MW-7. Following the AFVR event,
ATC recommends sampling of wells MW-1, MW-2, MW-4, MW-6 and MW-7 to evaluate the
effectiveness of the remediation efforts. ATC also recommends conducting an updated receptor
survey.

TABLES AND CHART
Well Parcel ID Well Owners /
Well Users Property Address Owner Address Distance From
Source Area (ft)
Well Use
(P/I/N/A)
Municipal Water
Connection Available
(Y/N)
WSW-1 4892361992 John Odell &
Betty Lou Bullard
2362 Sandy Springs Road
Mocksville, NC 28028
2362 Sandy Springs Road
Mocksville, NC 28028 600 P N
WSW-2 4892266902 Tina Gunter, et. al.2328 Sandy Springs Road
Harmony, NC 28634
2328 Sandy Springs Road
Harmony, NC 28634 250 A N
WSW-2A 4892275323 Tina Gunter, et. al.2341 Sandy Springs Road
Harmony, NC 28634
2328 Sandy Springs Road
Harmony, NC 28634 600 P N
Notes:
P / I / N / A = Potable water supply / Irrigation / Not in use / Abandoned
WATER SUPPLY WELL INFORMATION
TABLE 1
NCDEQ Incident #17478
Harmony, North Carolina 28634
2328 Sandy Springs Road
Gunter's Grocery
BenzeneTolueneEthylbenzeneTotal XylenesIsopropyl EtherMethyl TertiaryButyl EtherNaphthaleneWSW-1 10/18/2019 <0.50 <0.50 <0.50 <1.5 <0.50 <0.50 <2.0
WSW-2A 10/18/2019 <0.50 <0.50 <0.50 <1.5 <0.50 <0.50 <2.0
1 600 600 500 70 20 6
Notes:
< = Not detected at or above the laboratory detection limit
Concentrations are reported in micrograms per liter (µg/L)
J = Estimated value below method reporting limit
Values in bold indicate concentrations exceeding the 15A NCAC 02L .0202 Groundwater Quality Standards (2L Standards)
NCDEQ Incident #17478
2L Standard
Well ID Sample
Date
Concentrations in µg/L
TABLE 2
CURRENT WATER SUPPLY WELL ANALYTICAL RESULTS
Gunter's Grocery
2328 Sandy Springs Road
Harmony, North Carolina 28634
BenzeneTolueneEthylbenzeneTotal XylenesIsopropyl EtherMethyl TertiaryButyl Ethern-Butylbenzenesec-ButylbenzeneIsopropylbenzene(Cumene)p-Isopropyltoluene(p-Cymene)Naphthalenen-Propylbenzene1,3,5-Trimethylbenzene1,2,4-Trimethylbenzene1,4-DichlorobenzeneBromoformMethylene ChlorideChloroform08/14/01 ND ND ND 0.59 ND 0.97 ND ND ND ND ND ND ND ND NA ND ND ND
08/10/06 ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA ND ND ND
01/08/08 ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA ND ND ND
01/08/09 <0.20 <0.27 <0.20 <0.40 <0.24 <0.38 <0.20 <0.24 <0.24 NS <0.39 <0.30 <0.25 <0.20 NA <0.71 1.6 <0.20
05/21/09 <0.50 <0.50 <0.50 <1.5 <0.50 0.93 <0.50 <0.50 <0.50 NS <2.0 <0.50 <0.50 <0.50 NA <0.50 <2.0 <0.50
10/20/09 0.12J <0.50 <0.50 <1.0 <0.50 0.92 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 NA <0.50 <0.50 0.44 J
03/04/10 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 NA <0.50 <0.50 <0.50
08/26/10 <0.50 <0.50 <0.50 <0.50 <0.50 0.93 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 NA <0.50 <0.50 0.53
12/16/11 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 NA <0.50 <0.50 <0.50
07/19/12 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NA NS NS NS
02/14/13 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NA NS NS NS
08/12/14 <0.079 <0.090 <0.092 <0.29 <0.18 <0.090 <0.054 <0.084 <0.11 <0.12 <0.12 <0.094 <0.10 <0.18 <0.046 <0.21 <3.2 <0.14
01/22/18 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <1.0 <0.13
10/18/19 <0.50 <0.50 <0.50 <1.5 <0.50 <0.50 <0.50 <0.50 <0.50 NA <2.0 <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50
07/19/12 <0.50 <0.50 <0.50 <0.50 <0.50 0.471 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 NA <0.50 <0.50 0.22 J
02/14/13 <0.50 <0.50 <0.50 <1.5 <0.50 0.62 <0.50 <0.50 <0.50 NS <2.0 <0.50 <0.50 <0.50 NA <0.50 <2.0 <0.50
08/12/14 <0.079 <0.090 <0.092 <0.29 <0.18 0.21 J <0.054 <0.084 <0.11 <0.12 <0.12 <0.094 <0.10 <0.18 <0.046 <0.21 <3.2 <0.14
01/22/18 <0.13 <0.13 <0.13 <0.25 <0.13 0.24 J <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <1.0 <0.13
10/18/19 <0.50 <0.50 <0.50 <1.5 <0.50 <0.50 <0.50 <0.50 <0.50 NA <2.0 <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50
1 600 600 500 70 20 70 70 70 25 6 70 400 400 6 4 5 70
Notes:
ND = Not detected at or above the laboratory detection limit
Concentrations are reported in micrograms per liter (µg/L)
J = Estimated value below method reporting limit
NS = Not Sampled
NA = Constituent not analyzed
Values in bold indicate concentrations exceeding the 15A NCAC 02L .0202 Groundwater Quality Standards (2L Standards)
Concentrations in µg/L
WSW-2
2L Standard
Sample
DateWell ID
WSW-1
WSW-2A
HISTORICAL WATER SUPPLY WELL ANALYTICAL RESULTS
TABLE 3
NCDEQ Incident #17478
Harmony, North Carolina 28634
2328 Sandy Springs Road
Gunter's Grocery
MW-1 8/10/2001 35 - 45 2 45 100.00
MW-2 8/10/2001 33 - 43 2 43 99.63
MW-3 8/10/2001 33 - 43 2 43 99.23
MW-4 8/10/2001 32 - 42 2 42 97.84
MW-5 8/10/2001 32 - 42 2 42 98.47
MW-6 12/13/2006 30 - 45 2 45 97.98
MW-7 12/13/2006 30 - 45 2 45 96.46
Notes:
Elevations measured to an arbitrary elevation of 100.00 feet, at the MW-1 top of casing
Top of Casing
Elevation
(feet)
Well ID Date
Installed
Screen Interval
(feet)
Well Diameter
(inches)
Total Depth
(feet)
TABLE 4
MONITORING WELL CONSTRUCTION DETAILS
Gunter's Grocery
2328 Sandy Springs Road
Harmony, North Carolina 28634
NCDEQ Incident #17478

08/14/01 38.66 61.34
08/10/06 35.64 64.36
01/04/07 36.31 63.69
01/08/08 37.04 62.96
10/20/09 37.34 62.66
08/26/10 35.32 64.68
03/18/11 36.16 63.84
12/16/11 37.09 62.91
07/09/12 37.55 62.45
02/14/13 38.12 61.88
08/12/14 33.93 66.07
01/22/18 34.66 65.34
10/18/19 33.93 66.07
08/14/01 37.94 61.69
08/10/06 35.23 64.40
01/04/07 35.99 63.64
01/08/08 36.92 62.71
10/20/09 36.87 62.76
08/26/10 35.01 64.62
03/18/11 35.73 63.90
12/16/11 37.53 62.10
07/09/12 37.05 62.58
02/14/13 37.48 62.15
08/12/14 33.63 66.00
01/22/18 34.27 65.36
10/18/19 33.63 66.00
08/14/01 37.51 61.72
08/10/06 34.77 64.46
01/04/07 35.38 63.85
01/08/08 NM NM
08/12/14 NM NM
01/22/18 NM NM
10/18/19 NM NM
08/14/01 37.80 60.04
08/10/06 35.11 62.73
01/04/07 36.10 61.74
01/08/08 36.65 61.19
08/12/14 33.48 64.36
01/22/18 34.06 63.78
10/18/19 33.48 64.36
Total
Well
Depth
MW-1 100.00
MW-2 99.6343
MW-3
MW-4 97.8442
99.2343
TABLE 5
Groundwater
Elevation
Well
ID
TOC
Elevation
Depth to
Groundwater
45
GROUNDWATER ELEVATION DATA
Gauging
Date
NCDEQ Incident #17478
Harmony, North Carolina 28634
2328 Sandy Springs Road
Gunter's Grocery

Total
Well
Depth
MW-1 100.00
TABLE 5
Groundwater
Elevation
Well
ID
TOC
Elevation
Depth to
Groundwater
45
GROUNDWATER ELEVATION DATA
Gauging
Date
NCDEQ Incident #17478
Harmony, North Carolina 28634
2328 Sandy Springs Road
Gunter's Grocery
08/14/01 36.92 61.55
08/10/06 34.23 64.24
01/04/07 35.17 63.30
01/08/08 36.14 62.33
08/12/14 32.01 66.46
01/22/18 NM NM
10/18/19 32.01 66.46
01/04/07 35.33 62.65
01/08/08 34.98 63.00
10/20/09 35.05 62.93
08/26/10 33.85 64.13
03/18/11 33.60 64.38
12/16/11 34.66 63.32
07/09/12 35.25 62.73
02/14/13 43.71 54.27
08/12/14 31.79 66.19
01/22/18 32.42 65.56
10/18/19 31.79 66.19
01/04/07 35.08 61.38
01/08/08 35.98 60.48
10/20/09 36.22 60.24
08/26/10 34.78 61.68
03/18/11 35.05 61.41
12/16/11 35.79 60.67
07/09/12 36.39 60.07
02/14/13 36.67 59.79
08/12/14 33.00 63.46
01/22/18 33.60 62.86
10/18/19 33.00 63.46
Notes:
TOC = Top of Casing
NM = Not Measured
Elevations measured to an arbitrary elevation of 100.00 feet, at the MW-1 TOC
MW-5 98.47
All measurements expressed in feet
42
97.9845MW-6
96.4645MW-7
Well Date Temperature
(◦C)
Conductivity
(µS/cm)
pH
(su)ORP (mV)DO
(mg/L)
MW-1 10/18/19 18.48 0.133 5.99 -5.60 3.53
MW-2 10/18/19 17.92 0.027 5.09 153.1 4.30
MW-3 10/18/19
MW-4 10/18/19
MW-5 10/18/19 18.78 0.050 4.80 166.80 7.72
MW-6 10/18/19 17.91 0.027 4.33 171.6 4.39
MW-7 10/18/19 17.90 0.227 5.82 125.5 6.53
Notes:
°C : Degrees Celsius
µS/cm : microSiemens per centimeter
su : Standard Units
ORP : Oxydation-Reduction Potential; mV : milliVolts
DO : Dissolved Oxygen; mg/L : milligrams per liter
NOT COLLECTED - SAMPLE ONLY
NOT SAMPLED - COULD NOT LOCATE
TABLE 6
FIELD PARAMETERS
Gunter's Grocery
2328 Sandy Springs Road
Harmony, North Carolina 28634
NCDEQ Incident #17478
BenzeneTolueneEthylbenzeneTotal XylenesIsopropyl Ether (IPE)Methyl Tertiary Butyl EtherNaphthaleneEthanolChloroform1,2,4-Trimethylbenzene1,3,5-Trimethylbenzenetert-Amyl Alcoholtert-Amylmethyl ethertert-Butyl AlcoholMW-1 10/18/19 1,150 2,330 222 2,900 387 19,200 112 J <2,000 <62.5 485 258 16,200 1,140 J 2,220 J
MW-2 10/18/19 <5.0 <5.0 8.4 35.8 44.7 1,410 39.8 <2,000 <5.0 14.4 <5.0 691 J 80.5 J 983
MW-3 10/18/19
MW-4 10/18/19 <0.50 <0.50 <0.50 <1.5 <0.50 <0.50 <2.0 <200 <0.50 <0.50 <0.50 <100 <10 <20
MW-5 10/18/19 <0.50 <0.50 <0.50 <1.5 <0.50 <0.50 <2.0 <200 <0.50 <0.50 <0.50 <100 <10 <20
MW-6 10/18/19 <6.2 17.2 6.0 J 29.3 77.4 1,740 24.5 J <2,500 <6.2 9.1 <6.2 <1,250 <125 <250
MW-7 10/18/19 <0.50 <0.50 <0.50 <1.5 1.0 40.8 <2.0 <200 <0.50 <0.50 <0.50 <100 <10 <20
1 600 600 500 70 20 6 4,000 70 400 400 40 128 10
5,000 260,000 84,500 85,500 70,000 20,000 6,000 4,000,000 70,000 28,500 25,000 40,000 128,000 10,000
Notes:
NA = Not Analyzed
< = Not detected at or above the laboratory detection limit
Concentrations are reported in micrograms per liter (µg/L)
Values in bold indicate concentrations exceeding the 15A NCAC 02L .0202 Groundwater Quality Standards (2L Standards)
Values in bold and italicized indicate concentrations exceeding the NCDEQ Gross Contamination Levels for Groundwater (GCLs)
J = Estimated value below method reporting limit
Harmony, North Carolina 28634
NCDEQ Incident #17478
TABLE 7
CURRENT GROUNDWATER ANALYTICAL RESULTS
Gunter's Grocery
2328 Sandy Springs Road
2L Standard
GCL Standard
Well ID Sample
Date
Concentrations in µg/L
NOT SAMPLED - COULD NOT LOCATE
BenzeneTolueneEthylbenzeneTotal XylenesIsopropyl EtherMethyl TertiaryButyl EtherNaphthaleneEthanolBromoformn-Butylbenzenesec-ButylbenzeneChloroform1,4-DichlorobenzeneIsopropylbenzene(Cumene)p-Isopropyltoluene(p-Cymene)Methylene Chloriden-Propylbenzene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzene08/14/01 410 650 37 196 8.4 20 ND NA NA 7.1 ND NA NA 1.2 ND NA 1.5 23 7.9
09/24/03 11,000 16,000 1500 9,200 NA 200 ND NA NA ND NA ND NA NA NA 880 150 1,200 440
10/08/06 7,820 9,970 1330 7,320 303 3,480 330 NA ND ND 15.9 ND NA 81.1 ND ND 203 1,520 469
01/04/07 3,080 5,280 548 3,480 106 1,030 76.7 NA ND 29.7 6.77 ND NA 31.2 2.65 ND 85.6 732 236
08/01/08 1,630 1,100 159 1,370 65.9 480 22.5 NA ND 13.5 3.32 1.31 NA 12.5 1.21 ND 32.7 347 102
05/21/09 810 15 52 280 30 180 <3.9 NA <7.1 <3.9 <2.4 <2.0 NA <2.4 NS <5.3 9.3 140 110
10/20/09 1,820 584 183 1,182 84.6 291 8.9 NA <0.50 <0.50 <0.50 <0.50 NA 19.4 NS <2.0 46.8 313 140
03/04/10 1,700 440 130 990 96 770 6.5 NA <5.0 <5.0 <5.0 <5.0 NA <5.0 6.6 <5.0 19 280 120
08/26/10 2,200 520 92 2,300 300 6,000 <25 NA <25 <25 <25 <25 NA <25 <25 <25 <25 300 230
03/18/11 1,000 120 38 920 150 3,100 8.8 J NA <10 <10 <10 3.6 J NA 3.2 J 1.4 J 18 4.2 J 190 120
12/16/11 470 13 16 440 95 2,600 <10 <2,000 <0.20 <10 <10 <10 NA <10 <10 <3.5 <10 120 72
07/19/12 180 <10 5.4 J 30 26 760 <10 <2,000 <10 <10 <10 <10 NA <10 <10 <10 <10 34 15
02/14/13 226 <1.2 2.9 66.9 20.6 489 <5.0 NA <1.2 <1.2 <1.2 <1.2 NA 3.6 NA <7.5 <1.2 25 6.6
08/12/14 3,400 4,300 140 4,500 340 10,000 <12 <5,000 <21 10 J <8.4 <14 <4.6 <11 <12 <320 <9.4 650 250
01/22/18 3,770 9,260 671 7,090 535 24,700 225 J *<50,000 <63 <63 <63 <63 <63 <63 <63 <500 <63 1,280 549
10/18/19 1,150 2,330 222 2,900 387 19,200 112 J <2,000 <62.5 <62.5 <62.5 <62.5 <62.5 <62.5 NA <250 <62.5 485 258
08/14/01 2.8 1.3 ND 4.6 8.4 0.74 ND NA NA ND ND NA ND ND ND NA ND ND ND
09/24/03 4.6 460 ND ND ND ND NA NA ND ND ND ND ND NA NA NA ND ND ND
10/08/06 1,000 1,000 59 76.9 937 ND 2.17 NA ND 323 4.55 ND 226 ND 4.36 2.96 12.4 90.2 4.55
01/04/07 3,080 228 25.9 495 39.4 173 9.66 NA ND 3.54 0.800 ND ND 2.06 1.24 ND 1.24 125 58.8
08/01/08 1,630 3.99 3.31 85.9 38.5 151 ND NA ND 0.810 ND ND ND 0.710 ND ND ND 29.4 16.0
05/21/09 <0.20 <0.27 <0.20 <0.40 10 58 <0.39 NA <0.71 <0.20 <0.24 <0.20 <0.20 <0.24 NS 0.69 <0.30 <0.20 <0.25
10/20/09 19.1 0.60 <0.50 6.5 19.9 75.4 <2.0 NA <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 NS <2.0 <0.50 2.9 0.87
03/04/10 0.86 <0.50 <0.50 <1.0 9.3 61 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50
08/26/10 <0.50 <0.50 <0.50 <0.50 19 130 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50
03/18/11 <0.50 <0.50 <0.50 <0.50 3.1 21 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50
12/16/11 <0.50 <0.50 <0.50 <0.50 1.7 15 <0.50 <100 <0.50 <0.50 <0.50 <0.50 0.37 J <0.50 <0.50 <0.50 <0.50 <0.50 <0.50
07/19/12 <0.50 <0.50 <0.50 <0.50 0.18 J 3.6 0.29 J <100 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50
02/14/13 <0.50 <0.50 <0.50 <1.5 <0.50 5.3 <2.0 NA <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50
08/12/14 <0.079 <0.090 <0.092 <0.29 2.6 40 <0.12 <50 <0.21 <0.054 <0.084 <0.14 <0.046 <0.11 <0.12 <3.2 <0.094 <0.18 <0.10
01/22/18 <2.5 <2.5 <2.5 <5.0 21.2 578 3.7 J <2,000 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <20 <2.5 <2.5 <2.5
10/18/19 <5.0 <5.0 8.4 35.8 44.7 1410 39.8 <2,000 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NA <20.0 <5.0 14.4 <5.0
1 600 600 500 70 20 6 4,000 4 70 70 70 6 70 25 5 70 400 400
5,000 260,000 84,500 85,500 70,000 20,000 6,000 4,000,000 4,000 6,900 8,500 70,000 6,000 25,000 11,700 5,000 30,000 28,500 25,000
2328 Sandy Springs Road
Concentrations in µg/L
HISTORICAL GROUNDWATER ANALYTICAL RESULTS
TABLE 8
2L Standard
Gunter's Grocery
NCDEQ Incident #17478
Harmony, North Carolina 28634
GCL Standard
Sample
DateWell ID
MW-1
MW-2
Page 10 of 16
BenzeneTolueneEthylbenzeneTotal XylenesIsopropyl EtherMethyl TertiaryButyl EtherNaphthaleneEthanolBromoformn-Butylbenzenesec-ButylbenzeneChloroform1,4-DichlorobenzeneIsopropylbenzene(Cumene)p-Isopropyltoluene(p-Cymene)Methylene Chloriden-Propylbenzene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzene2328 Sandy Springs Road
Concentrations in µg/L
HISTORICAL GROUNDWATER ANALYTICAL RESULTS
TABLE 8
Gunter's Grocery
NCDEQ Incident #17478
Harmony, North Carolina 28634
Sample
DateWell ID
08/14/01 ND ND ND 0.78 ND ND ND ND NA ND ND NA NA ND ND ND ND ND ND
09/24/03 ND ND ND ND ND ND ND ND NA ND ND ND NA ND ND ND ND ND ND
10/08/06 0.92 0.84 ND 2.06 ND ND 0.7 ND ND ND ND ND NA ND ND ND ND 0.82 ND
01/04/07 ND ND ND 1.29 ND ND ND ND ND ND ND ND NA ND ND ND ND 1.21 ND
08/01/08 NS NS NS NS NS NS NS NS NS NS NS NS NA NS NS NS NS NS NS
08/12/14 NS NS NS NS NS NS NS NS NS NS NS NS NA NS NS NS NS NS NS
01/22/18 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
10/18/19 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
08/14/01 ND ND ND 0.6 ND ND ND ND NA ND ND NA NA ND ND ND ND ND ND
09/24/03 ND ND ND ND ND ND ND ND NA ND ND ND NA ND ND ND ND ND ND
10/08/06 ND ND ND ND ND ND ND ND ND ND ND ND NA ND ND ND ND ND ND
01/04/07 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
08/01/08 NS NS NS NS NS NS NS NA NS NS NS NS NA NS NS NS NS NS NS
08/12/14 <0.079 <0.090 <0.092 <0.29 <0.18 <0.090 <0.12 <50 <0.21 <0.054 <0.084 <0.14 <0.046 <0.11 <0.12 <3.2 <0.094 <0.18 <0.10
01/22/18 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <100 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <1.0 <0.13 <0.13 <0.13
10/18/19 <0.50 <0.50 <0.50 <1.5 <0.50 <0.50 <2.0 <200 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 NA <2.0 <0.50 <0.50 <0.50
08/14/01 ND ND ND 0.63 ND ND ND ND NA ND ND NA NA ND ND ND ND ND ND
09/24/03 ND ND ND ND ND ND ND ND NA ND ND ND NA ND ND ND ND ND ND
10/08/06 ND ND ND ND ND ND ND ND ND ND ND ND NA ND ND ND ND ND ND
01/04/07 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
08/01/08 NS NS NS NS NS NS NS NS NS NS NS NS NA NS NS NS NS NS NS
08/12/14 <0.079 <0.090 <0.092 <0.29 <0.18 <0.090 <0.12 <50 <0.21 <0.054 <0.084 0.77 <0.046 <0.11 <0.12 <3.2 <0.094 <0.18 <0.10
01/22/18 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
10/18/19 <0.50 <0.50 <0.50 <1.5 <0.50 <0.50 <2.0 <200 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 NA <2.0 <0.50 <0.50 <0.50
1 600 600 500 70 20 6 4,000 4 70 70 70 6 70 25 5 70 400 400
5,000 260,000 84,500 85,500 70,000 20,000 6,000 4,000,000 4,000 6,900 8,500 70,000 6,000 25,000 11,700 5,000 30,000 28,500 25,000
MW-5
2L Standard
GCL Standard
MW-3
MW-4
Page 11 of 16
BenzeneTolueneEthylbenzeneTotal XylenesIsopropyl EtherMethyl TertiaryButyl EtherNaphthaleneEthanolBromoformn-Butylbenzenesec-ButylbenzeneChloroform1,4-DichlorobenzeneIsopropylbenzene(Cumene)p-Isopropyltoluene(p-Cymene)Methylene Chloriden-Propylbenzene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzene2328 Sandy Springs Road
Concentrations in µg/L
HISTORICAL GROUNDWATER ANALYTICAL RESULTS
TABLE 8
Gunter's Grocery
NCDEQ Incident #17478
Harmony, North Carolina 28634
Sample
DateWell ID
01/04/07 10.1 ND ND 5.66 7.38 30.2 ND ND ND ND ND ND NA ND ND ND ND 0.820 ND
08/01/08 2.13 ND ND 1.04 2.49 20.2 ND ND ND ND ND ND NA ND ND ND ND ND ND
05/21/09 160 <0.27 4.1 22 7.5 37 <0.39 ND <0.71 <0.20 <0.24 <0.20 NA 0.81 NS 0.62 0.63 11 <0.25
10/20/09 268 <0.50 9.8 33.1 36.7 152 <2.0 ND <0.50 <0.50 <0.50 <0.50 NA 0.82 NS 2.4 0.56 16.3 <0.50
03/04/10 240 <0.50 6.4 40 23 94 1.9 ND <0.50 0.40 J 0.31 J <0.50 NA 1.3 <0.50 <0.50 1.3 24 1.5
08/26/10 83 <0.50 4.7 18.4 28 160 0.62 ND <0.50 <0.50 <0.50 <0.50 NA 0.51 <0.50 <0.50 0.52 11 0.49 J
03/18/11 180 <0.50 4.5 38 41 220 2.6 ND <0.50 <0.50 <0.50 <0.50 NA 0.88 <0.50 <0.50 0.44 J 26 2.8
12/16/11 220 <0.50 3.0 56 43 220 1.2 ND <0.50 0.55 0.29 J <0.50 NA 1.4 0.60 <0.50 0.51 48 11
07/19/12 110 <0.50 2.0 35 21 110 3.4 <100 <0.50 <0.50 0.20 J <0.50 NA 0.89 <0.50 <0.50 0.26 J 29 3.4
02/14/13 156 <0.50 2.3 42.4 20.1 118 4.3 NA <0.50 <0.50 <0.50 <0.50 NA 1.9 NA <2.0 <0.50 25.5 7.8
08/12/14 3.0 <0.45 <0.46 <1.45 20 190 <0.60 <250 <1.0 <0.27 <0.42 <0.72 <0.23 <0.56 <0.62 <16 <0.47 <0.90 <0.50
01/22/18 <0.63 <0.63 <0.63 <1.3 60.7 660 <0.63 <500 <0.63 <0.63 <0.63 <0.63 <0.63 <0.63 <0.63 <5.0 <0.63 <0.63 <0.63
10/18/19 <6.2 17.2 6.0 J 29.3 77.4 1740 24.5 J <2,500 <6.2 <6.2 <6.2 <6.2 <6.2 <6.2 NA <25.0 <6.2 9.1 <6.2
01/04/07 95.9 1.00 8.48 40.8 5.28 13.6 ND ND ND ND ND ND ND ND ND ND 0.730 8.04 1.32
08/01/08 442 0.660 30.0 63.6 20.5 68.2 ND ND ND ND ND ND ND 1.61 ND ND 1.44 19.2 1.30
05/21/09 <0.20 <0.27 <0.20 <0.40 0.53 1.2 <0.39 NA <0.71 <0.20 <0.24 <0.20 <0.20 <0.24 NA 0.62 <0.30 <0.20 <0.25
10/20/09 <0.50 <0.50 <0.50 <1.5 <0.50 3.7 <2.0 NA <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 NA <2.0 <0.50 <0.50 <0.50
03/04/10 <0.50 <0.50 <0.50 <1.0 1.9 2.6 <0.50 NA <0.50 0.221 <0.50 <0.50 <0.50 <0.50 0.14 J <0.50 <0.50 <0.50 <0.50
08/26/10 <0.50 <0.50 <0.50 <0.50 6.3 9.5 <0.50 NA <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50
03/18/11 0.12 J <0.50 <0.50 <0.50 0.90 2.8 <0.50 NA <0.50 <0.50 <0.50 0.18 J <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50
12/16/11 <0.50 <0.50 <0.50 <0.50 0.12 J 0.65 <0.50 NA <0.50 <0.50 <0.50 0.23 J 0.40 J <0.50 <0.50 <0.50 <0.50 <0.50 <0.50
07/19/12 <0.50 <0.50 <0.50 <0.50 <0.50 0.32 J <0.50 <100 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50
02/14/13 <0.50 <0.50 <0.50 <1.5 <0.50 0.55 <2.0 NA <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 NA <2.0 <0.50 <0.50 <0.50
08/12/14 <0.079 <0.090 <0.092 <0.29 0.31 J 1.6 <0.12 <50 <0.21 <0.054 <0.084 <0.14 <0.046 <0.11 <0.12 <3.2 <0.094 <0.18 <0.10
01/22/18 <0.13 <0.13 <0.13 <0.25 0.15 J 13.7 <0.13 <100 <0.13 <0.13 <0.13 0.17 J <0.13 <0.13 <0.13 <1.0 <0.13 <0.13 <0.13
10/18/19 <0.50 <0.50 <0.50 <1.5 1.0 40.8 <2.0 <200 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 NA <2.0 <0.50 <0.50 <0.50
1 600 600 500 70 20 6 4,000 4 70 70 70 6 70 25 5 70 400 400
5,000 260,000 84,500 85,500 70,000 20,000 6,000 4,000,000 4,000 6,900 8,500 70,000 6,000 25,000 11,700 5,000 30,000 28,500 25,000
Notes:
NA = Not Analyzed
ND or "<" = Not detected at or above the laboratory detection limitConcentrations are reported in micrograms per liter (µg/L)
J = Estimated value below method reporting limit
Values in bold indicate concentrations exceeding the 15A NCAC 02L .0202 Groundwater Quality Standards (2L Standards)
Values in bold and italicized indicate concentrations exceeding the NCDEQ Gross Contamination Levels for Groundwater (GCLs)
*<50,000 = Due to dilution introduced to the sample at the time of analysis for ethanol in well MW-1, the laboratory method detection limit is above the 2L Standard, which could be masking a concentration of ethanol above the 2L Standard of 4,000 ug/L.
MW-7
MW-6
2L Standard
GCL Standard
Page 12 of 16
8/1/2001
12/1/2019
7/28/2019
1
10
100
1000
10000
100000
61
62
63
64
65
66
67
08/01/01 08/01/03 07/31/05 07/31/07 07/30/09 07/30/11 07/29/13 07/29/15 07/28/17 07/28/19 VOC Concentration (µg/L)Groundwater Elevation (ft)Date
CHART 1: MW-1 Groundwater Elevations vs VOC Concentrations
Gunter's Grocery, Incident #17478, Harmony, North Carolina
GW Elev Benzene MTBE

FIGURES
SITE
CAD FILE PREP. BYTYPE CODE REV. BY SCALE PROJECT NO.
TITLE
DATE
REFERENCE: USGS 7.5-MINUTE MAP, LONE HICKORY,
NORTH CAROLINA. DATED 2016.
LB CB 12/31/19 2
WSW-2
2328 SANDY SPRINGS ROAD
WSW-1
2362 SANDY SPRINGS ROAD
WSW-2A
2341 SANDY SPRINGS ROAD
SITE
500'1,000'
CAD FILE PREP. BYTYPE CODE REV. BY SCALE PROJECT NO.
TITLE
DATE
WATER SUPPLY WELL LOCATION
EXPLANATION
LB CB 12/31/19 2
MW-6
GUNTER'S
GROCERY
STORE
SHEDGRASS
WOODED
AREA
DISPENSER ISLAND
UST BASIN
MW-5
MW-1
MW-7
MW-3MW-4
MW-2 FORMER UST BASIN
CAD FILE PREP. BYTYPE CODE REV. BY SCALE PROJECT NO.
TITLE
DATE
MONITORING WELL LOCATION
EXPLANATION
APPROXIMATE SITE BOUNDARY
LB CB 12/31/19 2
MW-6
GUNTER'S
GROCERY
STORE
SHEDGRASS
WOODED
AREA
DISPENSER ISLAND
UST BASIN
MW-5
MW-1
MW-7
MW-3MW-4
MW-2
FORMER UST BASINS
CAD FILE PREP. BYTYPE CODE REV. BY SCALE PROJECT NO.
TITLE
DATE
ASSOCIATES OF NORTH CAROLINA, P.C.
C:\Users\robert.deppensmith\Desktop\CAD REFERENCES\ATC Logo_Full Color_CMYK.jpg
MONITORING WELL LOCATION
EXPLANATION
APPROXIMATE SITE BOUNDARY
NM NOT MEASURED
GROUNDWATER CONTOUR LINE
GROUNDWATER FLOW DIRECTION
66.07
66.00
NM
64.36
66.46
66.19
63.46
66.0
65.0
64.0
77.77 GROUNDWATER ELEVATION (AT WELL)
NOTE:
1.GROUNDWATER ELEVATIONSMEASURED ON 10/18/192.DASHED LINES INDICATE AREASOF LESS CERTAINTY
MW-6
GUNTER'S
GROCERY
STORE
SHEDGRASS
WOODED
AREA
DISPENSER ISLAND
UST BASIN
MW-5
MW-1
MW-7
MW-3MW-4
MW-2
FORMER UST BASINS
CAD FILE PREP. BYTYPE CODE REV. BY SCALE PROJECT NO.
TITLE
DATE
ASSOCIATES OF NORTH CAROLINA, P.C.
C:\Users\robert.deppensmith\Desktop\CAD REFERENCES\ATC Logo_Full Color_CMYK.jpg
MONITORING WELL LOCATION
EXPLANATION
APPROXIMATE SITE BOUNDARY
NS NOT SAMPLED
BENZENE CONTOUR LINE
<5.0
NS
<0.50
<6.2
1,000 ug/L
<0.50 BENZENE CONCENTRATION (AT WELL)
<0.50
<0.50
1 ug/L
NOTE:
1.GROUNDWATER SAMPLESCOLLECTED ON 10/18/192.DASHED LINES INDICATE AREASOF LESS CERTAINTY
1,150
MW-6
GUNTER'S
GROCERY
STORE
SHEDGRASS
WOODED
AREA
DISPENSER ISLAND
UST BASIN
MW-5
MW-1
MW-7
MW-3MW-4
MW-2
FORMER UST BASINS
CAD FILE PREP. BYTYPE CODE REV. BY SCALE PROJECT NO.
TITLE
DATE
ASSOCIATES OF NORTH CAROLINA, P.C.
C:\Users\robert.deppensmith\Desktop\CAD REFERENCES\ATC Logo_Full Color_CMYK.jpg
MONITORING WELL LOCATION
EXPLANATION
APPROXIMATE SITE BOUNDARY
NS NOT SAMPLED
MTBE CONTOUR LINE
NS
<0.50
1,740 20,000 ug/L
<0.50 MTBE CONCENTRATION (AT WELL)
<0.50
NOTE:
1.GROUNDWATER SAMPLESCOLLECTED ON 10/18/192.DASHED LINES INDICATE AREASOF LESS CERTAINTY
19,200
40.8
1,410
2,000 ug/L
200 ug/L
20 ug/L
MW-6
GUNTER'S
GROCERY
STORE
SHEDGRASS
WOODED
AREA
DISPENSER ISLAND
UST BASIN
MW-5
MW-1
MW-7
MW-3MW-4
MW-2
FORMER UST BASINS
CAD FILE PREP. BYTYPE CODE REV. BY SCALE PROJECT NO.
TITLE
DATE
ASSOCIATES OF NORTH CAROLINA, P.C.
C:\Users\robert.deppensmith\Desktop\CAD REFERENCES\ATC Logo_Full Color_CMYK.jpg
MONITORING WELL LOCATION
EXPLANATION
APPROXIMATE SITE BOUNDARY
NS NOT SAMPLED
<0.50 MTBE CONCENTRATION (AT WELL)
NOTE:
1.GROUNDWATER SAMPLESCOLLECTED ON 10/18/19
NS

APPENDIX A

FIELD NOTES

APPENDIX B

LABORATORY ANALYTICAL REPORT
#=CL#
January 06, 2020
LIMS USE: FR - STEVEN FRAMBACH
LIMS OBJECT ID: 92450350
92450350
Project:
Pace Project No.:
RE:
Steven Frambach
ATC Group Services
7606 Whitehall Exec Center Dr
Suite 800
Charlotte, NC 28273
GUNTHER'S GROCERY-Revised Report
Dear Steven Frambach:
Enclosed are the analytical results for sample(s) received by the laboratory on October 18, 2019.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Taylor Ezell
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 49
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 49
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Lab ID Sample ID Matrix Date Collected Date Received
92450350001 MW-1 Water 10/18/19 14:10 10/18/19 16:30
92450350002 MW-2 Water 10/18/19 12:45 10/18/19 16:30
92450350003 MW-4 Water 10/18/19 11:45 10/18/19 16:30
92450350004 MW-5 Water 10/18/19 13:20 10/18/19 16:30
92450350005 MW-6 Water 10/18/19 13:45 10/18/19 16:30
92450350006 MW-7 Water 10/18/19 12:25 10/18/19 16:30
92450350007 WSW-1 Water 10/18/19 14:50 10/18/19 16:30
92450350008 WSW-2A Water 10/18/19 15:15 10/18/19 16:30
92450350009 FB Water 10/18/19 13:30 10/18/19 16:30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 49
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92450350001 MW-1 SM 6200B 69 PASI-CSAS
92450350002 MW-2 SM 6200B 69 PASI-CSAS
92450350003 MW-4 SM 6200B 69 PASI-CSAS
92450350004 MW-5 SM 6200B 69 PASI-CSAS
92450350005 MW-6 SM 6200B 69 PASI-CSAS
92450350006 MW-7 SM 6200B 69 PASI-CSAS
92450350007 WSW-1 SM 6200B 69 PASI-CSAS
92450350008 WSW-2A SM 6200B 69 PASI-CSAS
92450350009 FB SM 6200B 69 PASI-CSAS
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Sample:MW-1 Lab ID:92450350001 Collected:10/18/19 14:10 Received:10/18/19 16:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
tert-Amyl Alcohol 16200 ug/L 10/25/19 03:18 75-85-4125005060125
tert-Amylmethyl ether 1140J ug/L 10/25/19 03:18 994-05-81250370125
Benzene 1150 ug/L 10/25/19 03:18 71-43-262.5 30.0 125
Bromobenzene ND ug/L 10/25/19 03:18 108-86-162.5 26.9 125
Bromochloromethane ND ug/L 10/25/19 03:18 74-97-562.5 32.2 125
Bromodichloromethane ND ug/L 10/25/19 03:18 75-27-462.5 23.1 125
Bromoform ND ug/L 10/25/19 03:18 75-25-262.5 50.6 125
Bromomethane ND ug/L 10/25/19 03:18 74-83-9625215125
tert-Butyl Alcohol 2220J ug/L 10/25/19 03:18 75-65-025002200125
n-Butylbenzene ND ug/L 10/25/19 03:18 104-51-862.5 44.1 125
sec-Butylbenzene ND ug/L 10/25/19 03:18 135-98-862.5 30.8 125
tert-Butylbenzene ND ug/L 10/25/19 03:18 98-06-662.5 31.2 125
tert-Butyl Formate ND ug/L 10/25/19 03:18 762-75-425002220125
Carbon tetrachloride ND ug/L 10/25/19 03:18 56-23-562.5 29.0 125
Chlorobenzene ND ug/L 10/25/19 03:18 108-90-762.5 28.1 125
Chloroethane ND ug/L 10/25/19 03:18 75-00-312573.1 125
Chloroform ND ug/L 10/25/19 03:18 67-66-362.5 44.1 125
Chloromethane ND ug/L 10/25/19 03:18 74-87-312551.9 125
2-Chlorotoluene ND ug/L 10/25/19 03:18 95-49-862.5 25.9 125
4-Chlorotoluene ND ug/L 10/25/19 03:18 106-43-462.5 25.8 125
1,2-Dibromo-3-chloropropane ND ug/L 10/25/19 03:18 96-12-812548.1 125
Dibromochloromethane ND ug/L 10/25/19 03:18 124-48-162.5 50.2 125
1,2-Dibromoethane (EDB)ND ug/L 10/25/19 03:18 106-93-462.5 28.9 125
Dibromomethane ND ug/L 10/25/19 03:18 74-95-362.5 38.8 125
1,2-Dichlorobenzene ND ug/L 10/25/19 03:18 95-50-162.5 30.0 125
1,3-Dichlorobenzene ND ug/L 10/25/19 03:18 541-73-162.5 31.2 125
1,4-Dichlorobenzene ND ug/L 10/25/19 03:18 106-46-762.5 31.1 125
Dichlorodifluoromethane ND ug/L 10/25/19 03:18 75-71-862.5 35.5 125
1,1-Dichloroethane ND ug/L 10/25/19 03:18 75-34-362.5 30.5 125
1,2-Dichloroethane ND ug/L 10/25/19 03:18 107-06-262.5 32.9 125
1,1-Dichloroethene ND ug/L 10/25/19 03:18 75-35-462.5 27.2 125
cis-1,2-Dichloroethene ND ug/L 10/25/19 03:18 156-59-262.5 25.9 125
trans-1,2-Dichloroethene ND ug/L 10/25/19 03:18 156-60-562.5 32.1 125
1,2-Dichloropropane ND ug/L 10/25/19 03:18 78-87-562.5 22.9 125
1,3-Dichloropropane ND ug/L 10/25/19 03:18 142-28-962.5 42.6 125
2,2-Dichloropropane ND ug/L 10/25/19 03:18 594-20-762.5 35.1 125
1,1-Dichloropropene ND ug/L 10/25/19 03:18 563-58-662.5 43.5 125
cis-1,3-Dichloropropene ND ug/L 10/25/19 03:18 10061-01-562.5 44.6 125
trans-1,3-Dichloropropene ND ug/L 10/25/19 03:18 10061-02-662.5 49.2 125
Diisopropyl ether 387 ug/L 10/25/19 03:18 108-20-362.5 41.8 125
Ethanol ND ug/L 10/25/19 03:18 64-17-52500012400125
Ethylbenzene 222 ug/L 10/25/19 03:18 100-41-462.5 30.0 125
Ethyl-tert-butyl ether ND ug/L 10/25/19 03:18 637-92-31250476125
Hexachloro-1,3-butadiene ND ug/L 10/25/19 03:18 87-68-3250150125
Isopropylbenzene (Cumene)ND ug/L 10/25/19 03:18 98-82-862.5 29.8 125
Methylene Chloride ND ug/L 10/25/19 03:18 75-09-2250188125
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Sample:MW-1 Lab ID:92450350001 Collected:10/18/19 14:10 Received:10/18/19 16:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Methyl-tert-butyl ether 19200 ug/L 10/25/19 03:18 1634-04-462.5 55.5 125
Naphthalene 112J ug/L 10/25/19 03:18 91-20-325082.4 125
n-Propylbenzene ND ug/L 10/25/19 03:18 103-65-162.5 30.1 125
Styrene ND ug/L 10/25/19 03:18 100-42-562.5 32.0 125
1,1,1,2-Tetrachloroethane ND ug/L 10/25/19 03:18 630-20-662.5 52.8 125
1,1,2,2-Tetrachloroethane ND ug/L 10/25/19 03:18 79-34-562.5 24.1 125
Tetrachloroethene ND ug/L 10/25/19 03:18 127-18-462.5 29.0 125
Toluene 2330 ug/L 10/25/19 03:18 108-88-362.5 28.5 125
1,2,3-Trichlorobenzene ND ug/L 10/25/19 03:18 87-61-625097.6 125
1,2,4-Trichlorobenzene ND ug/L 10/25/19 03:18 120-82-125054.5 125
1,1,1-Trichloroethane ND ug/L 10/25/19 03:18 71-55-662.5 34.8 125
1,1,2-Trichloroethane ND ug/L 10/25/19 03:18 79-00-562.5 29.0 125
Trichloroethene ND ug/L 10/25/19 03:18 79-01-662.5 29.0 125
Trichlorofluoromethane ND ug/L 10/25/19 03:18 75-69-412542.0 125
1,2,3-Trichloropropane ND ug/L 10/25/19 03:18 96-18-462.5 33.9 125
1,2,4-Trimethylbenzene 485 ug/L 10/25/19 03:18 95-63-662.5 24.1 125
1,3,5-Trimethylbenzene 258 ug/L 10/25/19 03:18 108-67-862.5 28.4 125
Vinyl chloride ND ug/L 10/25/19 03:18 75-01-412550.9 125
m&p-Xylene 1750 ug/L 10/25/19 03:18 179601-23-112555.1 125
o-Xylene 1150 ug/L 10/25/19 03:18 95-47-662.5 29.6 125
Surrogates
1,2-Dichloroethane-d4 (S)96 %10/25/19 03:18 17060-07-070-130 125
4-Bromofluorobenzene (S)98 %10/25/19 03:18 460-00-470-130 125
Toluene-d8 (S)106 %10/25/19 03:18 2037-26-570-130 125
Sample:MW-2 Lab ID:92450350002 Collected:10/18/19 12:45 Received:10/18/19 16:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
tert-Amyl Alcohol 691J ug/L 10/24/19 00:56 75-85-4100040510
tert-Amylmethyl ether 80.5J ug/L 10/24/19 00:56 994-05-810029.6 10
Benzene ND ug/L 10/24/19 00:56 71-43-25.0 2.4 10
Bromobenzene ND ug/L 10/24/19 00:56 108-86-15.0 2.2 10
Bromochloromethane ND ug/L 10/24/19 00:56 74-97-55.0 2.6 10
Bromodichloromethane ND ug/L 10/24/19 00:56 75-27-45.0 1.8 10
Bromoform ND ug/L 10/24/19 00:56 75-25-25.0 4.0 10
Bromomethane ND ug/L 10/24/19 00:56 74-83-950.0 17.2 10
tert-Butyl Alcohol 983 ug/L 10/24/19 00:56 75-65-020017610
n-Butylbenzene ND ug/L 10/24/19 00:56 104-51-85.0 3.5 10
sec-Butylbenzene ND ug/L 10/24/19 00:56 135-98-85.0 2.5 10
tert-Butylbenzene ND ug/L 10/24/19 00:56 98-06-65.0 2.5 10
tert-Butyl Formate ND ug/L 10/24/19 00:56 762-75-420017810
Carbon tetrachloride ND ug/L 10/24/19 00:56 56-23-55.0 2.3 10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Sample:MW-2 Lab ID:92450350002 Collected:10/18/19 12:45 Received:10/18/19 16:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Chlorobenzene ND ug/L 10/24/19 00:56 108-90-75.0 2.2 10
Chloroethane ND ug/L 10/24/19 00:56 75-00-310.0 5.8 10
Chloroform ND ug/L 10/24/19 00:56 67-66-35.0 3.5 10
Chloromethane ND ug/L 10/24/19 00:56 74-87-310.0 4.2 10
2-Chlorotoluene ND ug/L 10/24/19 00:56 95-49-85.0 2.1 10
4-Chlorotoluene ND ug/L 10/24/19 00:56 106-43-45.0 2.1 10
1,2-Dibromo-3-chloropropane ND ug/L 10/24/19 00:56 96-12-810.0 3.8 10
Dibromochloromethane ND ug/L 10/24/19 00:56 124-48-15.0 4.0 10
1,2-Dibromoethane (EDB)ND ug/L 10/24/19 00:56 106-93-45.0 2.3 10
Dibromomethane ND ug/L 10/24/19 00:56 74-95-35.0 3.1 10
1,2-Dichlorobenzene ND ug/L 10/24/19 00:56 95-50-15.0 2.4 10
1,3-Dichlorobenzene ND ug/L 10/24/19 00:56 541-73-15.0 2.5 10
1,4-Dichlorobenzene ND ug/L 10/24/19 00:56 106-46-75.0 2.5 10
Dichlorodifluoromethane ND ug/L 10/24/19 00:56 75-71-85.0 2.8 10
1,1-Dichloroethane ND ug/L 10/24/19 00:56 75-34-35.0 2.4 10
1,2-Dichloroethane ND ug/L 10/24/19 00:56 107-06-25.0 2.6 10
1,1-Dichloroethene ND ug/L 10/24/19 00:56 75-35-45.0 2.2 10
cis-1,2-Dichloroethene ND ug/L 10/24/19 00:56 156-59-25.0 2.1 10
trans-1,2-Dichloroethene ND ug/L 10/24/19 00:56 156-60-55.0 2.6 10
1,2-Dichloropropane ND ug/L 10/24/19 00:56 78-87-55.0 1.8 10
1,3-Dichloropropane ND ug/L 10/24/19 00:56 142-28-95.0 3.4 10
2,2-Dichloropropane ND ug/L 10/24/19 00:56 594-20-75.0 2.8 10
1,1-Dichloropropene ND ug/L 10/24/19 00:56 563-58-65.0 3.5 10
cis-1,3-Dichloropropene ND ug/L 10/24/19 00:56 10061-01-55.0 3.6 10
trans-1,3-Dichloropropene ND ug/L 10/24/19 00:56 10061-02-65.0 3.9 10
Diisopropyl ether 44.7 ug/L 10/24/19 00:56 108-20-35.0 3.3 10
Ethanol ND ug/L 10/24/19 00:56 64-17-5200098910
Ethylbenzene 8.4 ug/L 10/24/19 00:56 100-41-45.0 2.4 10
Ethyl-tert-butyl ether ND ug/L 10/24/19 00:56 637-92-310038.1 10
Hexachloro-1,3-butadiene ND ug/L 10/24/19 00:56 87-68-320.0 12.0 10
Isopropylbenzene (Cumene)ND ug/L 10/24/19 00:56 98-82-85.0 2.4 10
Methylene Chloride ND ug/L 10/24/19 00:56 75-09-220.0 15.0 10
Methyl-tert-butyl ether 1410 ug/L 10/24/19 00:56 1634-04-45.0 4.4 10
Naphthalene 39.8 ug/L 10/24/19 00:56 91-20-320.0 6.6 10
n-Propylbenzene ND ug/L 10/24/19 00:56 103-65-15.0 2.4 10
Styrene ND ug/L 10/24/19 00:56 100-42-55.0 2.6 10
1,1,1,2-Tetrachloroethane ND ug/L 10/24/19 00:56 630-20-65.0 4.2 10
1,1,2,2-Tetrachloroethane ND ug/L 10/24/19 00:56 79-34-55.0 1.9 10
Tetrachloroethene ND ug/L 10/24/19 00:56 127-18-45.0 2.3 10
Toluene ND ug/L 10/24/19 00:56 108-88-35.0 2.3 10
1,2,3-Trichlorobenzene ND ug/L 10/24/19 00:56 87-61-620.0 7.8 10
1,2,4-Trichlorobenzene ND ug/L 10/24/19 00:56 120-82-120.0 4.4 10
1,1,1-Trichloroethane ND ug/L 10/24/19 00:56 71-55-65.0 2.8 10
1,1,2-Trichloroethane ND ug/L 10/24/19 00:56 79-00-55.0 2.3 10
Trichloroethene ND ug/L 10/24/19 00:56 79-01-65.0 2.3 10
Trichlorofluoromethane ND ug/L 10/24/19 00:56 75-69-410.0 3.4 10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Sample:MW-2 Lab ID:92450350002 Collected:10/18/19 12:45 Received:10/18/19 16:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
1,2,3-Trichloropropane ND ug/L 10/24/19 00:56 96-18-45.0 2.7 10
1,2,4-Trimethylbenzene 14.4 ug/L 10/24/19 00:56 95-63-65.0 1.9 10
1,3,5-Trimethylbenzene ND ug/L 10/24/19 00:56 108-67-85.0 2.3 10
Vinyl chloride ND ug/L 10/24/19 00:56 75-01-410.0 4.1 10
m&p-Xylene 25.1 ug/L 10/24/19 00:56 179601-23-110.0 4.4 10
o-Xylene 10.7 ug/L 10/24/19 00:56 95-47-65.0 2.4 10
Surrogates
1,2-Dichloroethane-d4 (S)93 %10/24/19 00:56 17060-07-070-130 10
4-Bromofluorobenzene (S)97 %10/24/19 00:56 460-00-470-130 10
Toluene-d8 (S)103 %10/24/19 00:56 2037-26-570-130 10
Sample:MW-4 Lab ID:92450350003 Collected:10/18/19 11:45 Received:10/18/19 16:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
tert-Amyl Alcohol ND ug/L 10/25/19 12:01 75-85-410040.5 1
tert-Amylmethyl ether ND ug/L 10/25/19 12:01 994-05-810.0 3.0 1
Benzene ND ug/L 10/25/19 12:01 71-43-20.50 0.24 1
Bromobenzene ND ug/L 10/25/19 12:01 108-86-10.50 0.22 1
Bromochloromethane ND ug/L 10/25/19 12:01 74-97-50.50 0.26 1
Bromodichloromethane ND ug/L 10/25/19 12:01 75-27-40.50 0.18 1
Bromoform ND ug/L 10/25/19 12:01 75-25-20.50 0.40 1
Bromomethane ND ug/L 10/25/19 12:01 74-83-95.0 1.7 1
tert-Butyl Alcohol ND ug/L 10/25/19 12:01 75-65-020.0 17.6 1
n-Butylbenzene ND ug/L 10/25/19 12:01 104-51-80.50 0.35 1
sec-Butylbenzene ND ug/L 10/25/19 12:01 135-98-80.50 0.25 1
tert-Butylbenzene ND ug/L 10/25/19 12:01 98-06-60.50 0.25 1
tert-Butyl Formate ND ug/L 10/25/19 12:01 762-75-420.0 17.8 1
Carbon tetrachloride ND ug/L 10/25/19 12:01 56-23-50.50 0.23 1
Chlorobenzene ND ug/L 10/25/19 12:01 108-90-70.50 0.22 1
Chloroethane ND ug/L 10/25/19 12:01 75-00-31.0 0.58 1
Chloroform ND ug/L 10/25/19 12:01 67-66-30.50 0.35 1
Chloromethane ND ug/L 10/25/19 12:01 74-87-31.0 0.42 1
2-Chlorotoluene ND ug/L 10/25/19 12:01 95-49-80.50 0.21 1
4-Chlorotoluene ND ug/L 10/25/19 12:01 106-43-40.50 0.21 1
1,2-Dibromo-3-chloropropane ND ug/L 10/25/19 12:01 96-12-81.0 0.38 1
Dibromochloromethane ND ug/L 10/25/19 12:01 124-48-10.50 0.40 1
1,2-Dibromoethane (EDB)ND ug/L 10/25/19 12:01 106-93-40.50 0.23 1
Dibromomethane ND ug/L 10/25/19 12:01 74-95-30.50 0.31 1
1,2-Dichlorobenzene ND ug/L 10/25/19 12:01 95-50-10.50 0.24 1
1,3-Dichlorobenzene ND ug/L 10/25/19 12:01 541-73-10.50 0.25 1
1,4-Dichlorobenzene ND ug/L 10/25/19 12:01 106-46-70.50 0.25 1
Dichlorodifluoromethane ND ug/L 10/25/19 12:01 75-71-80.50 0.28 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Sample:MW-4 Lab ID:92450350003 Collected:10/18/19 11:45 Received:10/18/19 16:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
1,1-Dichloroethane ND ug/L 10/25/19 12:01 75-34-30.50 0.24 1
1,2-Dichloroethane ND ug/L 10/25/19 12:01 107-06-20.50 0.26 1
1,1-Dichloroethene ND ug/L 10/25/19 12:01 75-35-40.50 0.22 1
cis-1,2-Dichloroethene ND ug/L 10/25/19 12:01 156-59-20.50 0.21 1
trans-1,2-Dichloroethene ND ug/L 10/25/19 12:01 156-60-50.50 0.26 1
1,2-Dichloropropane ND ug/L 10/25/19 12:01 78-87-50.50 0.18 1
1,3-Dichloropropane ND ug/L 10/25/19 12:01 142-28-90.50 0.34 1
2,2-Dichloropropane ND ug/L 10/25/19 12:01 594-20-70.50 0.28 1
1,1-Dichloropropene ND ug/L 10/25/19 12:01 563-58-60.50 0.35 1
cis-1,3-Dichloropropene ND ug/L 10/25/19 12:01 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/25/19 12:01 10061-02-60.50 0.39 1
Diisopropyl ether ND ug/L 10/25/19 12:01 108-20-30.50 0.33 1
Ethanol ND ug/L 10/25/19 12:01 64-17-520098.9 1
Ethylbenzene ND ug/L 10/25/19 12:01 100-41-40.50 0.24 1
Ethyl-tert-butyl ether ND ug/L 10/25/19 12:01 637-92-310.0 3.8 1
Hexachloro-1,3-butadiene ND ug/L 10/25/19 12:01 87-68-32.0 1.2 1
Isopropylbenzene (Cumene)ND ug/L 10/25/19 12:01 98-82-80.50 0.24 1
Methylene Chloride ND ug/L 10/25/19 12:01 75-09-22.0 1.5 1
Methyl-tert-butyl ether ND ug/L 10/25/19 12:01 1634-04-40.50 0.44 1
Naphthalene ND ug/L 10/25/19 12:01 91-20-32.0 0.66 1
n-Propylbenzene ND ug/L 10/25/19 12:01 103-65-10.50 0.24 1
Styrene ND ug/L 10/25/19 12:01 100-42-50.50 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/25/19 12:01 630-20-60.50 0.42 1
1,1,2,2-Tetrachloroethane ND ug/L 10/25/19 12:01 79-34-50.50 0.19 1
Tetrachloroethene ND ug/L 10/25/19 12:01 127-18-40.50 0.23 1
Toluene ND ug/L 10/25/19 12:01 108-88-30.50 0.23 1
1,2,3-Trichlorobenzene ND ug/L 10/25/19 12:01 87-61-62.0 0.78 1
1,2,4-Trichlorobenzene ND ug/L 10/25/19 12:01 120-82-12.0 0.44 1
1,1,1-Trichloroethane ND ug/L 10/25/19 12:01 71-55-60.50 0.28 1
1,1,2-Trichloroethane ND ug/L 10/25/19 12:01 79-00-50.50 0.23 1
Trichloroethene ND ug/L 10/25/19 12:01 79-01-60.50 0.23 1
Trichlorofluoromethane ND ug/L 10/25/19 12:01 75-69-41.0 0.34 1
1,2,3-Trichloropropane ND ug/L 10/25/19 12:01 96-18-40.50 0.27 1
1,2,4-Trimethylbenzene ND ug/L 10/25/19 12:01 95-63-60.50 0.19 1
1,3,5-Trimethylbenzene ND ug/L 10/25/19 12:01 108-67-80.50 0.23 1
Vinyl chloride ND ug/L 10/25/19 12:01 75-01-41.0 0.41 1
m&p-Xylene ND ug/L 10/25/19 12:01 179601-23-11.0 0.44 1
o-Xylene ND ug/L 10/25/19 12:01 95-47-60.50 0.24 1
Surrogates
1,2-Dichloroethane-d4 (S)94 %10/25/19 12:01 17060-07-070-130 1
4-Bromofluorobenzene (S)99 %10/25/19 12:01 460-00-470-130 1
Toluene-d8 (S)104 %10/25/19 12:01 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Sample:MW-5 Lab ID:92450350004 Collected:10/18/19 13:20 Received:10/18/19 16:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
tert-Amyl Alcohol ND ug/L 10/25/19 12:19 75-85-410040.5 1
tert-Amylmethyl ether ND ug/L 10/25/19 12:19 994-05-810.0 3.0 1
Benzene ND ug/L 10/25/19 12:19 71-43-20.50 0.24 1
Bromobenzene ND ug/L 10/25/19 12:19 108-86-10.50 0.22 1
Bromochloromethane ND ug/L 10/25/19 12:19 74-97-50.50 0.26 1
Bromodichloromethane ND ug/L 10/25/19 12:19 75-27-40.50 0.18 1
Bromoform ND ug/L 10/25/19 12:19 75-25-20.50 0.40 1
Bromomethane ND ug/L 10/25/19 12:19 74-83-95.0 1.7 1
tert-Butyl Alcohol ND ug/L 10/25/19 12:19 75-65-020.0 17.6 1
n-Butylbenzene ND ug/L 10/25/19 12:19 104-51-80.50 0.35 1
sec-Butylbenzene ND ug/L 10/25/19 12:19 135-98-80.50 0.25 1
tert-Butylbenzene ND ug/L 10/25/19 12:19 98-06-60.50 0.25 1
tert-Butyl Formate ND ug/L 10/25/19 12:19 762-75-420.0 17.8 1
Carbon tetrachloride ND ug/L 10/25/19 12:19 56-23-50.50 0.23 1
Chlorobenzene ND ug/L 10/25/19 12:19 108-90-70.50 0.22 1
Chloroethane ND ug/L 10/25/19 12:19 75-00-31.0 0.58 1
Chloroform ND ug/L 10/25/19 12:19 67-66-30.50 0.35 1
Chloromethane ND ug/L 10/25/19 12:19 74-87-31.0 0.42 1
2-Chlorotoluene ND ug/L 10/25/19 12:19 95-49-80.50 0.21 1
4-Chlorotoluene ND ug/L 10/25/19 12:19 106-43-40.50 0.21 1
1,2-Dibromo-3-chloropropane ND ug/L 10/25/19 12:19 96-12-81.0 0.38 1
Dibromochloromethane ND ug/L 10/25/19 12:19 124-48-10.50 0.40 1
1,2-Dibromoethane (EDB)ND ug/L 10/25/19 12:19 106-93-40.50 0.23 1
Dibromomethane ND ug/L 10/25/19 12:19 74-95-30.50 0.31 1
1,2-Dichlorobenzene ND ug/L 10/25/19 12:19 95-50-10.50 0.24 1
1,3-Dichlorobenzene ND ug/L 10/25/19 12:19 541-73-10.50 0.25 1
1,4-Dichlorobenzene ND ug/L 10/25/19 12:19 106-46-70.50 0.25 1
Dichlorodifluoromethane ND ug/L 10/25/19 12:19 75-71-80.50 0.28 1
1,1-Dichloroethane ND ug/L 10/25/19 12:19 75-34-30.50 0.24 1
1,2-Dichloroethane ND ug/L 10/25/19 12:19 107-06-20.50 0.26 1
1,1-Dichloroethene ND ug/L 10/25/19 12:19 75-35-40.50 0.22 1
cis-1,2-Dichloroethene ND ug/L 10/25/19 12:19 156-59-20.50 0.21 1
trans-1,2-Dichloroethene ND ug/L 10/25/19 12:19 156-60-50.50 0.26 1
1,2-Dichloropropane ND ug/L 10/25/19 12:19 78-87-50.50 0.18 1
1,3-Dichloropropane ND ug/L 10/25/19 12:19 142-28-90.50 0.34 1
2,2-Dichloropropane ND ug/L 10/25/19 12:19 594-20-70.50 0.28 1
1,1-Dichloropropene ND ug/L 10/25/19 12:19 563-58-60.50 0.35 1
cis-1,3-Dichloropropene ND ug/L 10/25/19 12:19 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/25/19 12:19 10061-02-60.50 0.39 1
Diisopropyl ether ND ug/L 10/25/19 12:19 108-20-30.50 0.33 1
Ethanol ND ug/L 10/25/19 12:19 64-17-520098.9 1
Ethylbenzene ND ug/L 10/25/19 12:19 100-41-40.50 0.24 1
Ethyl-tert-butyl ether ND ug/L 10/25/19 12:19 637-92-310.0 3.8 1
Hexachloro-1,3-butadiene ND ug/L 10/25/19 12:19 87-68-32.0 1.2 1
Isopropylbenzene (Cumene)ND ug/L 10/25/19 12:19 98-82-80.50 0.24 1
Methylene Chloride ND ug/L 10/25/19 12:19 75-09-22.0 1.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Sample:MW-5 Lab ID:92450350004 Collected:10/18/19 13:20 Received:10/18/19 16:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Methyl-tert-butyl ether ND ug/L 10/25/19 12:19 1634-04-40.50 0.44 1
Naphthalene ND ug/L 10/25/19 12:19 91-20-32.0 0.66 1
n-Propylbenzene ND ug/L 10/25/19 12:19 103-65-10.50 0.24 1
Styrene ND ug/L 10/25/19 12:19 100-42-50.50 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/25/19 12:19 630-20-60.50 0.42 1
1,1,2,2-Tetrachloroethane ND ug/L 10/25/19 12:19 79-34-50.50 0.19 1
Tetrachloroethene ND ug/L 10/25/19 12:19 127-18-40.50 0.23 1
Toluene ND ug/L 10/25/19 12:19 108-88-30.50 0.23 1
1,2,3-Trichlorobenzene ND ug/L 10/25/19 12:19 87-61-62.0 0.78 1
1,2,4-Trichlorobenzene ND ug/L 10/25/19 12:19 120-82-12.0 0.44 1
1,1,1-Trichloroethane ND ug/L 10/25/19 12:19 71-55-60.50 0.28 1
1,1,2-Trichloroethane ND ug/L 10/25/19 12:19 79-00-50.50 0.23 1
Trichloroethene ND ug/L 10/25/19 12:19 79-01-60.50 0.23 1
Trichlorofluoromethane ND ug/L 10/25/19 12:19 75-69-41.0 0.34 1
1,2,3-Trichloropropane ND ug/L 10/25/19 12:19 96-18-40.50 0.27 1
1,2,4-Trimethylbenzene ND ug/L 10/25/19 12:19 95-63-60.50 0.19 1
1,3,5-Trimethylbenzene ND ug/L 10/25/19 12:19 108-67-80.50 0.23 1
Vinyl chloride ND ug/L 10/25/19 12:19 75-01-41.0 0.41 1
m&p-Xylene ND ug/L 10/25/19 12:19 179601-23-11.0 0.44 1
o-Xylene ND ug/L 10/25/19 12:19 95-47-60.50 0.24 1
Surrogates
1,2-Dichloroethane-d4 (S)95 %10/25/19 12:19 17060-07-070-130 1
4-Bromofluorobenzene (S)98 %10/25/19 12:19 460-00-470-130 1
Toluene-d8 (S)104 %10/25/19 12:19 2037-26-570-130 1
Sample:MW-6 Lab ID:92450350005 Collected:10/18/19 13:45 Received:10/18/19 16:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
tert-Amyl Alcohol ND ug/L 10/25/19 13:12 75-85-4125050612.5
tert-Amylmethyl ether ND ug/L 10/25/19 13:12 994-05-812537.0 12.5
Benzene ND ug/L 10/25/19 13:12 71-43-26.2 3.0 12.5
Bromobenzene ND ug/L 10/25/19 13:12 108-86-16.2 2.7 12.5
Bromochloromethane ND ug/L 10/25/19 13:12 74-97-56.2 3.2 12.5
Bromodichloromethane ND ug/L 10/25/19 13:12 75-27-46.2 2.3 12.5
Bromoform ND ug/L 10/25/19 13:12 75-25-26.2 5.1 12.5
Bromomethane ND ug/L 10/25/19 13:12 74-83-962.5 21.5 12.5
tert-Butyl Alcohol ND ug/L 10/25/19 13:12 75-65-025022012.5
n-Butylbenzene ND ug/L 10/25/19 13:12 104-51-86.2 4.4 12.5
sec-Butylbenzene ND ug/L 10/25/19 13:12 135-98-86.2 3.1 12.5
tert-Butylbenzene ND ug/L 10/25/19 13:12 98-06-66.2 3.1 12.5
tert-Butyl Formate ND ug/L 10/25/19 13:12 762-75-425022212.5
Carbon tetrachloride ND ug/L 10/25/19 13:12 56-23-56.2 2.9 12.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Sample:MW-6 Lab ID:92450350005 Collected:10/18/19 13:45 Received:10/18/19 16:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Chlorobenzene ND ug/L 10/25/19 13:12 108-90-76.2 2.8 12.5
Chloroethane ND ug/L 10/25/19 13:12 75-00-312.5 7.3 12.5
Chloroform ND ug/L 10/25/19 13:12 67-66-36.2 4.4 12.5
Chloromethane ND ug/L 10/25/19 13:12 74-87-312.5 5.2 12.5
2-Chlorotoluene ND ug/L 10/25/19 13:12 95-49-86.2 2.6 12.5
4-Chlorotoluene ND ug/L 10/25/19 13:12 106-43-46.2 2.6 12.5
1,2-Dibromo-3-chloropropane ND ug/L 10/25/19 13:12 96-12-812.5 4.8 12.5
Dibromochloromethane ND ug/L 10/25/19 13:12 124-48-16.2 5.0 12.5
1,2-Dibromoethane (EDB)ND ug/L 10/25/19 13:12 106-93-46.2 2.9 12.5
Dibromomethane ND ug/L 10/25/19 13:12 74-95-36.2 3.9 12.5
1,2-Dichlorobenzene ND ug/L 10/25/19 13:12 95-50-16.2 3.0 12.5
1,3-Dichlorobenzene ND ug/L 10/25/19 13:12 541-73-16.2 3.1 12.5
1,4-Dichlorobenzene ND ug/L 10/25/19 13:12 106-46-76.2 3.1 12.5
Dichlorodifluoromethane ND ug/L 10/25/19 13:12 75-71-86.2 3.6 12.5
1,1-Dichloroethane ND ug/L 10/25/19 13:12 75-34-36.2 3.0 12.5
1,2-Dichloroethane ND ug/L 10/25/19 13:12 107-06-26.2 3.3 12.5
1,1-Dichloroethene ND ug/L 10/25/19 13:12 75-35-46.2 2.7 12.5
cis-1,2-Dichloroethene ND ug/L 10/25/19 13:12 156-59-26.2 2.6 12.5
trans-1,2-Dichloroethene ND ug/L 10/25/19 13:12 156-60-56.2 3.2 12.5
1,2-Dichloropropane ND ug/L 10/25/19 13:12 78-87-56.2 2.3 12.5
1,3-Dichloropropane ND ug/L 10/25/19 13:12 142-28-96.2 4.3 12.5
2,2-Dichloropropane ND ug/L 10/25/19 13:12 594-20-76.2 3.5 12.5
1,1-Dichloropropene ND ug/L 10/25/19 13:12 563-58-66.2 4.4 12.5
cis-1,3-Dichloropropene ND ug/L 10/25/19 13:12 10061-01-56.2 4.5 12.5
trans-1,3-Dichloropropene ND ug/L 10/25/19 13:12 10061-02-66.2 4.9 12.5
Diisopropyl ether 77.4 ug/L 10/25/19 13:12 108-20-36.2 4.2 12.5
Ethanol ND ug/L 10/25/19 13:12 64-17-52500124012.5
Ethylbenzene 6.0J ug/L 10/25/19 13:12 100-41-46.2 3.0 12.5
Ethyl-tert-butyl ether ND ug/L 10/25/19 13:12 637-92-312547.6 12.5
Hexachloro-1,3-butadiene ND ug/L 10/25/19 13:12 87-68-325.0 15.0 12.5
Isopropylbenzene (Cumene)ND ug/L 10/25/19 13:12 98-82-86.2 3.0 12.5
Methylene Chloride ND ug/L 10/25/19 13:12 75-09-225.0 18.8 12.5
Methyl-tert-butyl ether 1740 ug/L 10/25/19 13:12 1634-04-46.2 5.6 12.5
Naphthalene 24.5J ug/L 10/25/19 13:12 91-20-325.0 8.2 12.5
n-Propylbenzene ND ug/L 10/25/19 13:12 103-65-16.2 3.0 12.5
Styrene ND ug/L 10/25/19 13:12 100-42-56.2 3.2 12.5
1,1,1,2-Tetrachloroethane ND ug/L 10/25/19 13:12 630-20-66.2 5.3 12.5
1,1,2,2-Tetrachloroethane ND ug/L 10/25/19 13:12 79-34-56.2 2.4 12.5
Tetrachloroethene ND ug/L 10/25/19 13:12 127-18-46.2 2.9 12.5
Toluene 17.2 ug/L 10/25/19 13:12 108-88-36.2 2.8 12.5
1,2,3-Trichlorobenzene ND ug/L 10/25/19 13:12 87-61-625.0 9.8 12.5
1,2,4-Trichlorobenzene ND ug/L 10/25/19 13:12 120-82-125.0 5.4 12.5
1,1,1-Trichloroethane ND ug/L 10/25/19 13:12 71-55-66.2 3.5 12.5
1,1,2-Trichloroethane ND ug/L 10/25/19 13:12 79-00-56.2 2.9 12.5
Trichloroethene ND ug/L 10/25/19 13:12 79-01-66.2 2.9 12.5
Trichlorofluoromethane ND ug/L 10/25/19 13:12 75-69-412.5 4.2 12.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Sample:MW-6 Lab ID:92450350005 Collected:10/18/19 13:45 Received:10/18/19 16:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
1,2,3-Trichloropropane ND ug/L 10/25/19 13:12 96-18-46.2 3.4 12.5
1,2,4-Trimethylbenzene 9.1 ug/L 10/25/19 13:12 95-63-66.2 2.4 12.5
1,3,5-Trimethylbenzene ND ug/L 10/25/19 13:12 108-67-86.2 2.8 12.5
Vinyl chloride ND ug/L 10/25/19 13:12 75-01-412.5 5.1 12.5
m&p-Xylene 19.9 ug/L 10/25/19 13:12 179601-23-112.5 5.5 12.5
o-Xylene 9.4 ug/L 10/25/19 13:12 95-47-66.2 3.0 12.5
Surrogates
1,2-Dichloroethane-d4 (S)96 %10/25/19 13:12 17060-07-070-130 12.5
4-Bromofluorobenzene (S)96 %10/25/19 13:12 460-00-470-130 12.5
Toluene-d8 (S)105 %10/25/19 13:12 2037-26-570-130 12.5
Sample:MW-7 Lab ID:92450350006 Collected:10/18/19 12:25 Received:10/18/19 16:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
tert-Amyl Alcohol ND ug/L 10/24/19 14:05 75-85-410040.5 1
tert-Amylmethyl ether ND ug/L 10/24/19 14:05 994-05-810.0 3.0 1
Benzene ND ug/L 10/24/19 14:05 71-43-20.50 0.24 1
Bromobenzene ND ug/L 10/24/19 14:05 108-86-10.50 0.22 1
Bromochloromethane ND ug/L 10/24/19 14:05 74-97-50.50 0.26 1
Bromodichloromethane ND ug/L 10/24/19 14:05 75-27-40.50 0.18 1
Bromoform ND ug/L 10/24/19 14:05 75-25-20.50 0.40 1
Bromomethane ND ug/L 10/24/19 14:05 74-83-95.0 1.7 1
tert-Butyl Alcohol ND ug/L 10/24/19 14:05 75-65-020.0 17.6 1
n-Butylbenzene ND ug/L 10/24/19 14:05 104-51-80.50 0.35 1
sec-Butylbenzene ND ug/L 10/24/19 14:05 135-98-80.50 0.25 1
tert-Butylbenzene ND ug/L 10/24/19 14:05 98-06-60.50 0.25 1
tert-Butyl Formate ND ug/L 10/24/19 14:05 762-75-420.0 17.8 1
Carbon tetrachloride ND ug/L 10/24/19 14:05 56-23-50.50 0.23 1
Chlorobenzene ND ug/L 10/24/19 14:05 108-90-70.50 0.22 1
Chloroethane ND ug/L 10/24/19 14:05 75-00-31.0 0.58 1
Chloroform ND ug/L 10/24/19 14:05 67-66-30.50 0.35 1
Chloromethane ND ug/L 10/24/19 14:05 74-87-31.0 0.42 1
2-Chlorotoluene ND ug/L 10/24/19 14:05 95-49-80.50 0.21 1
4-Chlorotoluene ND ug/L 10/24/19 14:05 106-43-40.50 0.21 1
1,2-Dibromo-3-chloropropane ND ug/L 10/24/19 14:05 96-12-81.0 0.38 1
Dibromochloromethane ND ug/L 10/24/19 14:05 124-48-10.50 0.40 1
1,2-Dibromoethane (EDB)ND ug/L 10/24/19 14:05 106-93-40.50 0.23 1
Dibromomethane ND ug/L 10/24/19 14:05 74-95-30.50 0.31 1
1,2-Dichlorobenzene ND ug/L 10/24/19 14:05 95-50-10.50 0.24 1
1,3-Dichlorobenzene ND ug/L 10/24/19 14:05 541-73-10.50 0.25 1
1,4-Dichlorobenzene ND ug/L 10/24/19 14:05 106-46-70.50 0.25 1
Dichlorodifluoromethane ND ug/L 10/24/19 14:05 75-71-80.50 0.28 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Sample:MW-7 Lab ID:92450350006 Collected:10/18/19 12:25 Received:10/18/19 16:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
1,1-Dichloroethane ND ug/L 10/24/19 14:05 75-34-30.50 0.24 1
1,2-Dichloroethane ND ug/L 10/24/19 14:05 107-06-20.50 0.26 1
1,1-Dichloroethene ND ug/L 10/24/19 14:05 75-35-40.50 0.22 1
cis-1,2-Dichloroethene ND ug/L 10/24/19 14:05 156-59-20.50 0.21 1
trans-1,2-Dichloroethene ND ug/L 10/24/19 14:05 156-60-50.50 0.26 1
1,2-Dichloropropane ND ug/L 10/24/19 14:05 78-87-50.50 0.18 1
1,3-Dichloropropane ND ug/L 10/24/19 14:05 142-28-90.50 0.34 1
2,2-Dichloropropane ND ug/L 10/24/19 14:05 594-20-70.50 0.28 1
1,1-Dichloropropene ND ug/L 10/24/19 14:05 563-58-60.50 0.35 1
cis-1,3-Dichloropropene ND ug/L 10/24/19 14:05 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/24/19 14:05 10061-02-60.50 0.39 1
Diisopropyl ether 1.0 ug/L 10/24/19 14:05 108-20-30.50 0.33 1
Ethanol ND ug/L 10/24/19 14:05 64-17-520098.9 1
Ethylbenzene ND ug/L 10/24/19 14:05 100-41-40.50 0.24 1
Ethyl-tert-butyl ether ND ug/L 10/24/19 14:05 637-92-310.0 3.8 1
Hexachloro-1,3-butadiene ND ug/L 10/24/19 14:05 87-68-32.0 1.2 1
Isopropylbenzene (Cumene)ND ug/L 10/24/19 14:05 98-82-80.50 0.24 1
Methylene Chloride ND ug/L 10/24/19 14:05 75-09-22.0 1.5 1
Methyl-tert-butyl ether 40.8 ug/L 10/24/19 14:05 1634-04-40.50 0.44 1
Naphthalene ND ug/L 10/24/19 14:05 91-20-32.0 0.66 1
n-Propylbenzene ND ug/L 10/24/19 14:05 103-65-10.50 0.24 1
Styrene ND ug/L 10/24/19 14:05 100-42-50.50 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/24/19 14:05 630-20-60.50 0.42 1
1,1,2,2-Tetrachloroethane ND ug/L 10/24/19 14:05 79-34-50.50 0.19 1
Tetrachloroethene ND ug/L 10/24/19 14:05 127-18-40.50 0.23 1
Toluene ND ug/L 10/24/19 14:05 108-88-30.50 0.23 1
1,2,3-Trichlorobenzene ND ug/L 10/24/19 14:05 87-61-62.0 0.78 1
1,2,4-Trichlorobenzene ND ug/L 10/24/19 14:05 120-82-12.0 0.44 1
1,1,1-Trichloroethane ND ug/L 10/24/19 14:05 71-55-60.50 0.28 1
1,1,2-Trichloroethane ND ug/L 10/24/19 14:05 79-00-50.50 0.23 1
Trichloroethene ND ug/L 10/24/19 14:05 79-01-60.50 0.23 1
Trichlorofluoromethane ND ug/L 10/24/19 14:05 75-69-41.0 0.34 1
1,2,3-Trichloropropane ND ug/L 10/24/19 14:05 96-18-40.50 0.27 1
1,2,4-Trimethylbenzene ND ug/L 10/24/19 14:05 95-63-60.50 0.19 1
1,3,5-Trimethylbenzene ND ug/L 10/24/19 14:05 108-67-80.50 0.23 1
Vinyl chloride ND ug/L 10/24/19 14:05 75-01-41.0 0.41 1
m&p-Xylene ND ug/L 10/24/19 14:05 179601-23-11.0 0.44 1
o-Xylene ND ug/L 10/24/19 14:05 95-47-60.50 0.24 1
Surrogates
1,2-Dichloroethane-d4 (S)99 %10/24/19 14:05 17060-07-070-130 1
4-Bromofluorobenzene (S)105 %10/24/19 14:05 460-00-470-130 1
Toluene-d8 (S)102 %10/24/19 14:05 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Sample:WSW-1 Lab ID:92450350007 Collected:10/18/19 14:50 Received:10/18/19 16:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
tert-Amyl Alcohol ND ug/L 10/24/19 14:22 75-85-410040.5 1
tert-Amylmethyl ether ND ug/L 10/24/19 14:22 994-05-810.0 3.0 1
Benzene ND ug/L 10/24/19 14:22 71-43-20.50 0.24 1
Bromobenzene ND ug/L 10/24/19 14:22 108-86-10.50 0.22 1
Bromochloromethane ND ug/L 10/24/19 14:22 74-97-50.50 0.26 1
Bromodichloromethane ND ug/L 10/24/19 14:22 75-27-40.50 0.18 1
Bromoform ND ug/L 10/24/19 14:22 75-25-20.50 0.40 1
Bromomethane ND ug/L 10/24/19 14:22 74-83-95.0 1.7 1
tert-Butyl Alcohol ND ug/L 10/24/19 14:22 75-65-020.0 17.6 1
n-Butylbenzene ND ug/L 10/24/19 14:22 104-51-80.50 0.35 1
sec-Butylbenzene ND ug/L 10/24/19 14:22 135-98-80.50 0.25 1
tert-Butylbenzene ND ug/L 10/24/19 14:22 98-06-60.50 0.25 1
tert-Butyl Formate ND ug/L 10/24/19 14:22 762-75-420.0 17.8 1
Carbon tetrachloride ND ug/L 10/24/19 14:22 56-23-50.50 0.23 1
Chlorobenzene ND ug/L 10/24/19 14:22 108-90-70.50 0.22 1
Chloroethane ND ug/L 10/24/19 14:22 75-00-31.0 0.58 1
Chloroform ND ug/L 10/24/19 14:22 67-66-30.50 0.35 1
Chloromethane ND ug/L 10/24/19 14:22 74-87-31.0 0.42 1
2-Chlorotoluene ND ug/L 10/24/19 14:22 95-49-80.50 0.21 1
4-Chlorotoluene ND ug/L 10/24/19 14:22 106-43-40.50 0.21 1
1,2-Dibromo-3-chloropropane ND ug/L 10/24/19 14:22 96-12-81.0 0.38 1
Dibromochloromethane ND ug/L 10/24/19 14:22 124-48-10.50 0.40 1
1,2-Dibromoethane (EDB)ND ug/L 10/24/19 14:22 106-93-40.50 0.23 1
Dibromomethane ND ug/L 10/24/19 14:22 74-95-30.50 0.31 1
1,2-Dichlorobenzene ND ug/L 10/24/19 14:22 95-50-10.50 0.24 1
1,3-Dichlorobenzene ND ug/L 10/24/19 14:22 541-73-10.50 0.25 1
1,4-Dichlorobenzene ND ug/L 10/24/19 14:22 106-46-70.50 0.25 1
Dichlorodifluoromethane ND ug/L 10/24/19 14:22 75-71-80.50 0.28 1
1,1-Dichloroethane ND ug/L 10/24/19 14:22 75-34-30.50 0.24 1
1,2-Dichloroethane ND ug/L 10/24/19 14:22 107-06-20.50 0.26 1
1,1-Dichloroethene ND ug/L 10/24/19 14:22 75-35-40.50 0.22 1
cis-1,2-Dichloroethene ND ug/L 10/24/19 14:22 156-59-20.50 0.21 1
trans-1,2-Dichloroethene ND ug/L 10/24/19 14:22 156-60-50.50 0.26 1
1,2-Dichloropropane ND ug/L 10/24/19 14:22 78-87-50.50 0.18 1
1,3-Dichloropropane ND ug/L 10/24/19 14:22 142-28-90.50 0.34 1
2,2-Dichloropropane ND ug/L 10/24/19 14:22 594-20-70.50 0.28 1
1,1-Dichloropropene ND ug/L 10/24/19 14:22 563-58-60.50 0.35 1
cis-1,3-Dichloropropene ND ug/L 10/24/19 14:22 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/24/19 14:22 10061-02-60.50 0.39 1
Diisopropyl ether ND ug/L 10/24/19 14:22 108-20-30.50 0.33 1
Ethanol ND ug/L 10/24/19 14:22 64-17-520098.9 1
Ethylbenzene ND ug/L 10/24/19 14:22 100-41-40.50 0.24 1
Ethyl-tert-butyl ether ND ug/L 10/24/19 14:22 637-92-310.0 3.8 1
Hexachloro-1,3-butadiene ND ug/L 10/24/19 14:22 87-68-32.0 1.2 1
Isopropylbenzene (Cumene)ND ug/L 10/24/19 14:22 98-82-80.50 0.24 1
Methylene Chloride ND ug/L 10/24/19 14:22 75-09-22.0 1.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Sample:WSW-1 Lab ID:92450350007 Collected:10/18/19 14:50 Received:10/18/19 16:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Methyl-tert-butyl ether ND ug/L 10/24/19 14:22 1634-04-40.50 0.44 1
Naphthalene ND ug/L 10/24/19 14:22 91-20-32.0 0.66 1
n-Propylbenzene ND ug/L 10/24/19 14:22 103-65-10.50 0.24 1
Styrene ND ug/L 10/24/19 14:22 100-42-50.50 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/24/19 14:22 630-20-60.50 0.42 1
1,1,2,2-Tetrachloroethane ND ug/L 10/24/19 14:22 79-34-50.50 0.19 1
Tetrachloroethene ND ug/L 10/24/19 14:22 127-18-40.50 0.23 1
Toluene ND ug/L 10/24/19 14:22 108-88-30.50 0.23 1
1,2,3-Trichlorobenzene ND ug/L 10/24/19 14:22 87-61-62.0 0.78 1
1,2,4-Trichlorobenzene ND ug/L 10/24/19 14:22 120-82-12.0 0.44 1
1,1,1-Trichloroethane ND ug/L 10/24/19 14:22 71-55-60.50 0.28 1
1,1,2-Trichloroethane ND ug/L 10/24/19 14:22 79-00-50.50 0.23 1
Trichloroethene ND ug/L 10/24/19 14:22 79-01-60.50 0.23 1
Trichlorofluoromethane ND ug/L 10/24/19 14:22 75-69-41.0 0.34 1
1,2,3-Trichloropropane ND ug/L 10/24/19 14:22 96-18-40.50 0.27 1
1,2,4-Trimethylbenzene ND ug/L 10/24/19 14:22 95-63-60.50 0.19 1
1,3,5-Trimethylbenzene ND ug/L 10/24/19 14:22 108-67-80.50 0.23 1
Vinyl chloride ND ug/L 10/24/19 14:22 75-01-41.0 0.41 1
m&p-Xylene ND ug/L 10/24/19 14:22 179601-23-11.0 0.44 1
o-Xylene ND ug/L 10/24/19 14:22 95-47-60.50 0.24 1
Surrogates
1,2-Dichloroethane-d4 (S)99 %10/24/19 14:22 17060-07-070-130 1
4-Bromofluorobenzene (S)105 %10/24/19 14:22 460-00-470-130 1
Toluene-d8 (S)102 %10/24/19 14:22 2037-26-570-130 1
Sample:WSW-2A Lab ID:92450350008 Collected:10/18/19 15:15 Received:10/18/19 16:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
tert-Amyl Alcohol ND ug/L 10/24/19 14:40 75-85-410040.5 1
tert-Amylmethyl ether ND ug/L 10/24/19 14:40 994-05-810.0 3.0 1
Benzene ND ug/L 10/24/19 14:40 71-43-20.50 0.24 1
Bromobenzene ND ug/L 10/24/19 14:40 108-86-10.50 0.22 1
Bromochloromethane ND ug/L 10/24/19 14:40 74-97-50.50 0.26 1
Bromodichloromethane ND ug/L 10/24/19 14:40 75-27-40.50 0.18 1
Bromoform ND ug/L 10/24/19 14:40 75-25-20.50 0.40 1
Bromomethane ND ug/L 10/24/19 14:40 74-83-95.0 1.7 1
tert-Butyl Alcohol ND ug/L 10/24/19 14:40 75-65-020.0 17.6 1
n-Butylbenzene ND ug/L 10/24/19 14:40 104-51-80.50 0.35 1
sec-Butylbenzene ND ug/L 10/24/19 14:40 135-98-80.50 0.25 1
tert-Butylbenzene ND ug/L 10/24/19 14:40 98-06-60.50 0.25 1
tert-Butyl Formate ND ug/L 10/24/19 14:40 762-75-420.0 17.8 1
Carbon tetrachloride ND ug/L 10/24/19 14:40 56-23-50.50 0.23 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Sample:WSW-2A Lab ID:92450350008 Collected:10/18/19 15:15 Received:10/18/19 16:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Chlorobenzene ND ug/L 10/24/19 14:40 108-90-70.50 0.22 1
Chloroethane ND ug/L 10/24/19 14:40 75-00-31.0 0.58 1
Chloroform ND ug/L 10/24/19 14:40 67-66-30.50 0.35 1
Chloromethane ND ug/L 10/24/19 14:40 74-87-31.0 0.42 1
2-Chlorotoluene ND ug/L 10/24/19 14:40 95-49-80.50 0.21 1
4-Chlorotoluene ND ug/L 10/24/19 14:40 106-43-40.50 0.21 1
1,2-Dibromo-3-chloropropane ND ug/L 10/24/19 14:40 96-12-81.0 0.38 1
Dibromochloromethane ND ug/L 10/24/19 14:40 124-48-10.50 0.40 1
1,2-Dibromoethane (EDB)ND ug/L 10/24/19 14:40 106-93-40.50 0.23 1
Dibromomethane ND ug/L 10/24/19 14:40 74-95-30.50 0.31 1
1,2-Dichlorobenzene ND ug/L 10/24/19 14:40 95-50-10.50 0.24 1
1,3-Dichlorobenzene ND ug/L 10/24/19 14:40 541-73-10.50 0.25 1
1,4-Dichlorobenzene ND ug/L 10/24/19 14:40 106-46-70.50 0.25 1
Dichlorodifluoromethane ND ug/L 10/24/19 14:40 75-71-80.50 0.28 1
1,1-Dichloroethane ND ug/L 10/24/19 14:40 75-34-30.50 0.24 1
1,2-Dichloroethane ND ug/L 10/24/19 14:40 107-06-20.50 0.26 1
1,1-Dichloroethene ND ug/L 10/24/19 14:40 75-35-40.50 0.22 1
cis-1,2-Dichloroethene ND ug/L 10/24/19 14:40 156-59-20.50 0.21 1
trans-1,2-Dichloroethene ND ug/L 10/24/19 14:40 156-60-50.50 0.26 1
1,2-Dichloropropane ND ug/L 10/24/19 14:40 78-87-50.50 0.18 1
1,3-Dichloropropane ND ug/L 10/24/19 14:40 142-28-90.50 0.34 1
2,2-Dichloropropane ND ug/L 10/24/19 14:40 594-20-70.50 0.28 1
1,1-Dichloropropene ND ug/L 10/24/19 14:40 563-58-60.50 0.35 1
cis-1,3-Dichloropropene ND ug/L 10/24/19 14:40 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/24/19 14:40 10061-02-60.50 0.39 1
Diisopropyl ether ND ug/L 10/24/19 14:40 108-20-30.50 0.33 1
Ethanol ND ug/L 10/24/19 14:40 64-17-520098.9 1
Ethylbenzene ND ug/L 10/24/19 14:40 100-41-40.50 0.24 1
Ethyl-tert-butyl ether ND ug/L 10/24/19 14:40 637-92-310.0 3.8 1
Hexachloro-1,3-butadiene ND ug/L 10/24/19 14:40 87-68-32.0 1.2 1
Isopropylbenzene (Cumene)ND ug/L 10/24/19 14:40 98-82-80.50 0.24 1
Methylene Chloride ND ug/L 10/24/19 14:40 75-09-22.0 1.5 1
Methyl-tert-butyl ether ND ug/L 10/24/19 14:40 1634-04-40.50 0.44 1
Naphthalene ND ug/L 10/24/19 14:40 91-20-32.0 0.66 1
n-Propylbenzene ND ug/L 10/24/19 14:40 103-65-10.50 0.24 1
Styrene ND ug/L 10/24/19 14:40 100-42-50.50 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/24/19 14:40 630-20-60.50 0.42 1
1,1,2,2-Tetrachloroethane ND ug/L 10/24/19 14:40 79-34-50.50 0.19 1
Tetrachloroethene ND ug/L 10/24/19 14:40 127-18-40.50 0.23 1
Toluene ND ug/L 10/24/19 14:40 108-88-30.50 0.23 1
1,2,3-Trichlorobenzene ND ug/L 10/24/19 14:40 87-61-62.0 0.78 1
1,2,4-Trichlorobenzene ND ug/L 10/24/19 14:40 120-82-12.0 0.44 1
1,1,1-Trichloroethane ND ug/L 10/24/19 14:40 71-55-60.50 0.28 1
1,1,2-Trichloroethane ND ug/L 10/24/19 14:40 79-00-50.50 0.23 1
Trichloroethene ND ug/L 10/24/19 14:40 79-01-60.50 0.23 1
Trichlorofluoromethane ND ug/L 10/24/19 14:40 75-69-41.0 0.34 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Sample:WSW-2A Lab ID:92450350008 Collected:10/18/19 15:15 Received:10/18/19 16:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
1,2,3-Trichloropropane ND ug/L 10/24/19 14:40 96-18-40.50 0.27 1
1,2,4-Trimethylbenzene ND ug/L 10/24/19 14:40 95-63-60.50 0.19 1
1,3,5-Trimethylbenzene ND ug/L 10/24/19 14:40 108-67-80.50 0.23 1
Vinyl chloride ND ug/L 10/24/19 14:40 75-01-41.0 0.41 1
m&p-Xylene ND ug/L 10/24/19 14:40 179601-23-11.0 0.44 1
o-Xylene ND ug/L 10/24/19 14:40 95-47-60.50 0.24 1
Surrogates
1,2-Dichloroethane-d4 (S)93 %10/24/19 14:40 17060-07-070-130 1
4-Bromofluorobenzene (S)100 %10/24/19 14:40 460-00-470-130 1
Toluene-d8 (S)104 %10/24/19 14:40 2037-26-570-130 1
Sample:FB Lab ID:92450350009 Collected:10/18/19 13:30 Received:10/18/19 16:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
tert-Amyl Alcohol ND ug/L 10/24/19 13:18 75-85-410040.5 1
tert-Amylmethyl ether ND ug/L 10/24/19 13:18 994-05-810.0 3.0 1
Benzene ND ug/L 10/24/19 13:18 71-43-20.50 0.24 1
Bromobenzene ND ug/L 10/24/19 13:18 108-86-10.50 0.22 1
Bromochloromethane ND ug/L 10/24/19 13:18 74-97-50.50 0.26 1
Bromodichloromethane ND ug/L 10/24/19 13:18 75-27-40.50 0.18 1
Bromoform ND ug/L 10/24/19 13:18 75-25-20.50 0.40 1
Bromomethane ND ug/L 10/24/19 13:18 74-83-95.0 1.7 1
tert-Butyl Alcohol ND ug/L 10/24/19 13:18 75-65-020.0 17.6 1
n-Butylbenzene ND ug/L 10/24/19 13:18 104-51-80.50 0.35 1
sec-Butylbenzene ND ug/L 10/24/19 13:18 135-98-80.50 0.25 1
tert-Butylbenzene ND ug/L 10/24/19 13:18 98-06-60.50 0.25 1
tert-Butyl Formate ND ug/L 10/24/19 13:18 762-75-420.0 17.8 1
Carbon tetrachloride ND ug/L 10/24/19 13:18 56-23-50.50 0.23 1
Chlorobenzene ND ug/L 10/24/19 13:18 108-90-70.50 0.22 1
Chloroethane ND ug/L 10/24/19 13:18 75-00-31.0 0.58 1
Chloroform ND ug/L 10/24/19 13:18 67-66-30.50 0.35 1
Chloromethane ND ug/L 10/24/19 13:18 74-87-31.0 0.42 1
2-Chlorotoluene ND ug/L 10/24/19 13:18 95-49-80.50 0.21 1
4-Chlorotoluene ND ug/L 10/24/19 13:18 106-43-40.50 0.21 1
1,2-Dibromo-3-chloropropane ND ug/L 10/24/19 13:18 96-12-81.0 0.38 1
Dibromochloromethane ND ug/L 10/24/19 13:18 124-48-10.50 0.40 1
1,2-Dibromoethane (EDB)ND ug/L 10/24/19 13:18 106-93-40.50 0.23 1
Dibromomethane ND ug/L 10/24/19 13:18 74-95-30.50 0.31 1
1,2-Dichlorobenzene ND ug/L 10/24/19 13:18 95-50-10.50 0.24 1
1,3-Dichlorobenzene ND ug/L 10/24/19 13:18 541-73-10.50 0.25 1
1,4-Dichlorobenzene ND ug/L 10/24/19 13:18 106-46-70.50 0.25 1
Dichlorodifluoromethane ND ug/L 10/24/19 13:18 75-71-80.50 0.28 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 49
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Sample:FB Lab ID:92450350009 Collected:10/18/19 13:30 Received:10/18/19 16:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
1,1-Dichloroethane ND ug/L 10/24/19 13:18 75-34-30.50 0.24 1
1,2-Dichloroethane ND ug/L 10/24/19 13:18 107-06-20.50 0.26 1
1,1-Dichloroethene ND ug/L 10/24/19 13:18 75-35-40.50 0.22 1
cis-1,2-Dichloroethene ND ug/L 10/24/19 13:18 156-59-20.50 0.21 1
trans-1,2-Dichloroethene ND ug/L 10/24/19 13:18 156-60-50.50 0.26 1
1,2-Dichloropropane ND ug/L 10/24/19 13:18 78-87-50.50 0.18 1
1,3-Dichloropropane ND ug/L 10/24/19 13:18 142-28-90.50 0.34 1
2,2-Dichloropropane ND ug/L 10/24/19 13:18 594-20-70.50 0.28 1
1,1-Dichloropropene ND ug/L 10/24/19 13:18 563-58-60.50 0.35 1
cis-1,3-Dichloropropene ND ug/L 10/24/19 13:18 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 10/24/19 13:18 10061-02-60.50 0.39 1
Diisopropyl ether ND ug/L 10/24/19 13:18 108-20-30.50 0.33 1
Ethanol ND ug/L 10/24/19 13:18 64-17-520098.9 1
Ethylbenzene ND ug/L 10/24/19 13:18 100-41-40.50 0.24 1
Ethyl-tert-butyl ether ND ug/L 10/24/19 13:18 637-92-310.0 3.8 1
Hexachloro-1,3-butadiene ND ug/L 10/24/19 13:18 87-68-32.0 1.2 1
Isopropylbenzene (Cumene)ND ug/L 10/24/19 13:18 98-82-80.50 0.24 1
Methylene Chloride ND ug/L 10/24/19 13:18 75-09-22.0 1.5 1
Methyl-tert-butyl ether ND ug/L 10/24/19 13:18 1634-04-40.50 0.44 1
Naphthalene ND ug/L 10/24/19 13:18 91-20-32.0 0.66 1
n-Propylbenzene ND ug/L 10/24/19 13:18 103-65-10.50 0.24 1
Styrene ND ug/L 10/24/19 13:18 100-42-50.50 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 10/24/19 13:18 630-20-60.50 0.42 1
1,1,2,2-Tetrachloroethane ND ug/L 10/24/19 13:18 79-34-50.50 0.19 1
Tetrachloroethene ND ug/L 10/24/19 13:18 127-18-40.50 0.23 1
Toluene ND ug/L 10/24/19 13:18 108-88-30.50 0.23 1
1,2,3-Trichlorobenzene ND ug/L 10/24/19 13:18 87-61-62.0 0.78 1
1,2,4-Trichlorobenzene ND ug/L 10/24/19 13:18 120-82-12.0 0.44 1
1,1,1-Trichloroethane ND ug/L 10/24/19 13:18 71-55-60.50 0.28 1
1,1,2-Trichloroethane ND ug/L 10/24/19 13:18 79-00-50.50 0.23 1
Trichloroethene ND ug/L 10/24/19 13:18 79-01-60.50 0.23 1
Trichlorofluoromethane ND ug/L 10/24/19 13:18 75-69-41.0 0.34 1
1,2,3-Trichloropropane ND ug/L 10/24/19 13:18 96-18-40.50 0.27 1
1,2,4-Trimethylbenzene ND ug/L 10/24/19 13:18 95-63-60.50 0.19 1
1,3,5-Trimethylbenzene ND ug/L 10/24/19 13:18 108-67-80.50 0.23 1
Vinyl chloride ND ug/L 10/24/19 13:18 75-01-41.0 0.41 1
m&p-Xylene ND ug/L 10/24/19 13:18 179601-23-11.0 0.44 1
o-Xylene ND ug/L 10/24/19 13:18 95-47-60.50 0.24 1
Surrogates
1,2-Dichloroethane-d4 (S)91 %10/24/19 13:18 17060-07-070-130 1
4-Bromofluorobenzene (S)97 %10/24/19 13:18 460-00-470-130 1
Toluene-d8 (S)103 %10/24/19 13:18 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
505333
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92450350002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2714914
Associated Lab Samples:92450350002
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 0.50 10/23/19 21:220.42
1,1,1-Trichloroethane ug/L ND 0.50 10/23/19 21:220.28
1,1,2,2-Tetrachloroethane ug/L ND 0.50 10/23/19 21:220.19
1,1,2-Trichloroethane ug/L ND 0.50 10/23/19 21:220.23
1,1-Dichloroethane ug/L ND 0.50 10/23/19 21:220.24
1,1-Dichloroethene ug/L ND 0.50 10/23/19 21:220.22
1,1-Dichloropropene ug/L ND 0.50 10/23/19 21:220.35
1,2,3-Trichlorobenzene ug/L ND 2.0 10/23/19 21:220.78
1,2,3-Trichloropropane ug/L ND 0.50 10/23/19 21:220.27
1,2,4-Trichlorobenzene ug/L ND 2.0 10/23/19 21:220.44
1,2,4-Trimethylbenzene ug/L ND 0.50 10/23/19 21:220.19
1,2-Dibromo-3-chloropropane ug/L ND 1.0 10/23/19 21:220.38
1,2-Dibromoethane (EDB)ug/L ND 0.50 10/23/19 21:220.23
1,2-Dichlorobenzene ug/L ND 0.50 10/23/19 21:220.24
1,2-Dichloroethane ug/L ND 0.50 10/23/19 21:220.26
1,2-Dichloropropane ug/L ND 0.50 10/23/19 21:220.18
1,3,5-Trimethylbenzene ug/L ND 0.50 10/23/19 21:220.23
1,3-Dichlorobenzene ug/L ND 0.50 10/23/19 21:220.25
1,3-Dichloropropane ug/L ND 0.50 10/23/19 21:220.34
1,4-Dichlorobenzene ug/L ND 0.50 10/23/19 21:220.25
2,2-Dichloropropane ug/L ND 0.50 10/23/19 21:220.28
2-Chlorotoluene ug/L ND 0.50 10/23/19 21:220.21
4-Chlorotoluene ug/L ND 0.50 10/23/19 21:220.21
Benzene ug/L ND 0.50 10/23/19 21:220.24
Bromobenzene ug/L ND 0.50 10/23/19 21:220.22
Bromochloromethane ug/L ND 0.50 10/23/19 21:220.26
Bromodichloromethane ug/L ND 0.50 10/23/19 21:220.18
Bromoform ug/L ND 0.50 10/23/19 21:220.40
Bromomethane ug/L ND 5.0 10/23/19 21:221.7
Carbon tetrachloride ug/L ND 0.50 10/23/19 21:220.23
Chlorobenzene ug/L ND 0.50 10/23/19 21:220.22
Chloroethane ug/L ND 1.0 10/23/19 21:220.58
Chloroform ug/L ND 0.50 10/23/19 21:220.35
Chloromethane ug/L ND 1.0 10/23/19 21:220.42
cis-1,2-Dichloroethene ug/L ND 0.50 10/23/19 21:220.21
cis-1,3-Dichloropropene ug/L ND 0.50 10/23/19 21:220.36
Dibromochloromethane ug/L ND 0.50 10/23/19 21:220.40
Dibromomethane ug/L ND 0.50 10/23/19 21:220.31
Dichlorodifluoromethane ug/L ND 0.50 10/23/19 21:220.28
Diisopropyl ether ug/L ND 0.50 10/23/19 21:220.33
Ethanol ug/L ND 200 10/23/19 21:2298.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2714914
Associated Lab Samples:92450350002
Matrix:Water
AnalyzedMDL
Ethyl-tert-butyl ether ug/L ND 10.0 10/23/19 21:223.8
Ethylbenzene ug/L ND 0.50 10/23/19 21:220.24
Hexachloro-1,3-butadiene ug/L ND 2.0 10/23/19 21:221.2
Isopropylbenzene (Cumene)ug/L ND 0.50 10/23/19 21:220.24
m&p-Xylene ug/L ND 1.0 10/23/19 21:220.44
Methyl-tert-butyl ether ug/L ND 0.50 10/23/19 21:220.44
Methylene Chloride ug/L ND 2.0 10/23/19 21:221.5
n-Butylbenzene ug/L ND 0.50 10/23/19 21:220.35
n-Propylbenzene ug/L ND 0.50 10/23/19 21:220.24
Naphthalene ug/L ND 2.0 10/23/19 21:220.66
o-Xylene ug/L ND 0.50 10/23/19 21:220.24
sec-Butylbenzene ug/L ND 0.50 10/23/19 21:220.25
Styrene ug/L ND 0.50 10/23/19 21:220.26
tert-Amyl Alcohol ug/L ND 100 10/23/19 21:2240.5
tert-Amylmethyl ether ug/L ND 10.0 10/23/19 21:223.0
tert-Butyl Alcohol ug/L ND 20.0 10/23/19 21:2217.6
tert-Butyl Formate ug/L ND 20.0 10/23/19 21:2217.8
tert-Butylbenzene ug/L ND 0.50 10/23/19 21:220.25
Tetrachloroethene ug/L ND 0.50 10/23/19 21:220.23
Toluene ug/L ND 0.50 10/23/19 21:220.23
trans-1,2-Dichloroethene ug/L ND 0.50 10/23/19 21:220.26
trans-1,3-Dichloropropene ug/L ND 0.50 10/23/19 21:220.39
Trichloroethene ug/L ND 0.50 10/23/19 21:220.23
Trichlorofluoromethane ug/L ND 1.0 10/23/19 21:220.34
Vinyl chloride ug/L ND 1.0 10/23/19 21:220.41
1,2-Dichloroethane-d4 (S)%94 70-130 10/23/19 21:22
4-Bromofluorobenzene (S)%97 70-130 10/23/19 21:22
Toluene-d8 (S)%103 70-130 10/23/19 21:22
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2714915LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 48.150 96 60-140
1,1,1-Trichloroethane ug/L 46.750 93 60-140
1,1,2,2-Tetrachloroethane ug/L 51.350 103 60-140
1,1,2-Trichloroethane ug/L 51.150 102 60-140
1,1-Dichloroethane ug/L 49.250 98 60-140
1,1-Dichloroethene ug/L 48.450 97 60-140
1,1-Dichloropropene ug/L 48.050 96 60-140
1,2,3-Trichlorobenzene ug/L 51.250 102 60-140
1,2,3-Trichloropropane ug/L 50.350 101 60-140
1,2,4-Trichlorobenzene ug/L 47.750 95 60-140
1,2,4-Trimethylbenzene ug/L 47.650 95 60-140
1,2-Dibromo-3-chloropropane ug/L 53.550 107 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2714915LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dibromoethane (EDB)ug/L 51.750 103 60-140
1,2-Dichlorobenzene ug/L 48.750 97 60-140
1,2-Dichloroethane ug/L 43.550 87 60-140
1,2-Dichloropropane ug/L 51.350 103 60-140
1,3,5-Trimethylbenzene ug/L 48.150 96 60-140
1,3-Dichlorobenzene ug/L 47.550 95 60-140
1,3-Dichloropropane ug/L 53.050 106 60-140
1,4-Dichlorobenzene ug/L 46.250 92 60-140
2,2-Dichloropropane ug/L 48.450 97 60-140
2-Chlorotoluene ug/L 48.050 96 60-140
4-Chlorotoluene ug/L 48.150 96 60-140
Benzene ug/L 51.050 102 60-140
Bromobenzene ug/L 48.450 97 60-140
Bromochloromethane ug/L 48.250 96 60-140
Bromodichloromethane ug/L 50.950 102 60-140
Bromoform ug/L 51.050 102 60-140
Bromomethane ug/L 42.750 85 60-140
Carbon tetrachloride ug/L 45.650 91 60-140
Chlorobenzene ug/L 47.350 95 60-140
Chloroethane ug/L 39.350 79 60-140
Chloroform ug/L 47.550 95 60-140
Chloromethane ug/L 46.050 92 60-140
cis-1,2-Dichloroethene ug/L 49.650 99 60-140
cis-1,3-Dichloropropene ug/L 55.150 110 60-140
Dibromochloromethane ug/L 50.250 100 60-140
Dibromomethane ug/L 51.050 102 60-140
Dichlorodifluoromethane ug/L 45.350 91 60-140
Diisopropyl ether ug/L 53.250 106 60-140
Ethanol ug/L 2970 L1200014860-140
Ethyl-tert-butyl ether ug/L 98.7100 99 60-140
Ethylbenzene ug/L 48.750 97 60-140
Hexachloro-1,3-butadiene ug/L 46.750 93 60-140
Isopropylbenzene (Cumene)ug/L 49.150 98 60-140
m&p-Xylene ug/L 95.9100 96 60-140
Methyl-tert-butyl ether ug/L 51.350 103 60-140
Methylene Chloride ug/L 43.850 88 60-140
n-Butylbenzene ug/L 48.650 97 60-140
n-Propylbenzene ug/L 49.250 98 60-140
Naphthalene ug/L 52.650 105 60-140
o-Xylene ug/L 49.950 100 60-140
sec-Butylbenzene ug/L 50.650 101 60-140
Styrene ug/L 48.850 98 60-140
tert-Amyl Alcohol ug/L 12401000 124 60-140
tert-Amylmethyl ether ug/L 101100 101 60-140
tert-Butyl Alcohol ug/L 608500 122 60-140
tert-Butyl Formate ug/L 435400 109 60-140
tert-Butylbenzene ug/L 42.050 84 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2714915LABORATORY CONTROL SAMPLE:
LCSSpike
Tetrachloroethene ug/L 47.450 95 60-140
Toluene ug/L 48.550 97 60-140
trans-1,2-Dichloroethene ug/L 48.850 98 60-140
trans-1,3-Dichloropropene ug/L 52.150 104 60-140
Trichloroethene ug/L 48.450 97 60-140
Trichlorofluoromethane ug/L 43.250 86 60-140
Vinyl chloride ug/L 49.550 99 60-140
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2714916MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92449953013
2714917
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 2500 103 60-140104 1 302500ND25702590
1,1,1-Trichloroethane ug/L 2500 104 60-140107 2 302500ND26102670
1,1,2,2-Tetrachloroethane ug/L 2500 103 60-140107 4 302500ND25702690
1,1,2-Trichloroethane ug/L 2500 104 60-140110 5 302500ND26102740
1,1-Dichloroethane ug/L 2500 113 60-140115 2 302500ND28202880
1,1-Dichloroethene ug/L 2500 113 60-140116 3 302500ND28102900
1,1-Dichloropropene ug/L 2500 108 60-140111 2 302500ND27102770
1,2,3-Trichlorobenzene ug/L 2500 89 60-140100 11 302500ND22402500
1,2,3-Trichloropropane ug/L 2500 106 60-140109 3 302500ND26402720
1,2,4-Trichlorobenzene ug/L 2500 91 60-14098 7 302500ND22902450
1,2,4-Trimethylbenzene ug/L 2500 87 60-14084 1 302500548076607590
1,2-Dibromo-3-chloropropane ug/L 2500 92 60-140101 9 302500ND23102530
1,2-Dibromoethane (EDB)ug/L 2500 106 60-140108 2 302500ND26502690
1,2-Dichlorobenzene ug/L 2500 101 60-140106 5 302500ND25202640
1,2-Dichloroethane ug/L 2500 96 60-14099 3 302500ND24002480
1,2-Dichloropropane ug/L 2500 112 60-140115 3 302500ND28002870
1,3,5-Trimethylbenzene ug/L 2500 101 60-140104 2 302500150040204090
1,3-Dichlorobenzene ug/L 2500 100 60-140105 5 302500ND24902630
1,3-Dichloropropane ug/L 2500 108 60-140113 4 302500ND27102820
1,4-Dichlorobenzene ug/L 2500 95 60-140101 6 302500ND23902530
2,2-Dichloropropane ug/L 2500 93 60-14097 4 302500ND23302420
2-Chlorotoluene ug/L 2500 111 60-140109 2 302500ND27702720
4-Chlorotoluene ug/L 2500 102 60-140107 5 302500ND25602680
Benzene ug/L 2500 114 60-140117 2 30250042332703350
Bromobenzene ug/L 2500 103 60-140107 4 302500ND25802670
Bromochloromethane ug/L 2500 107 60-140109 2 302500ND26702720
Bromodichloromethane ug/L 2500 110 60-140111 1 302500ND27502780
Bromoform ug/L 2500 96 60-14099 4 302500ND23902480
Bromomethane ug/L 2500 70 60-14080 14 302500ND17402010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2714916MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92449953013
2714917
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Carbon tetrachloride ug/L 2500 104 60-140104 0 302500ND26102600
Chlorobenzene ug/L 2500 103 60-140106 3 302500ND25702640
Chloroethane ug/L 2500 113 60-140114 1 302500ND28302840
Chloroform ug/L 2500 110 60-140107 2 302500ND27402670
Chloromethane ug/L 2500 96 60-140103 7 302500ND23902570
cis-1,2-Dichloroethene ug/L 2500 111 60-140115 4 302500ND27602870
cis-1,3-Dichloropropene ug/L 2500 113 60-140116 3 302500ND28202890
Dibromochloromethane ug/L 2500 102 60-140103 2 302500ND25402580
Dibromomethane ug/L 2500 108 60-140111 3 302500ND27002770
Dichlorodifluoromethane ug/L 2500 97 60-140100 3 302500ND24202500
Diisopropyl ether ug/L 2500 116 60-140121 4 302500ND28903030
Ethanol ug/L 100000 98 60-140115 16 30100000ND97900115000
Ethyl-tert-butyl ether ug/L 5000 105 60-140109 4 305000ND52605460
Ethylbenzene ug/L 2500 99 60-14098 0 302500371062006170
Hexachloro-1,3-butadiene ug/L 2500 88 60-14096 9 302500ND22002410
Isopropylbenzene
(Cumene)ug/L 2500 107 60-140109 2 30250021628802930
m&p-Xylene ug/L 5000 95 60-14090 1 305000126001730017100
Methyl-tert-butyl ether ug/L 2500 110 60-140113 3 302500ND27702860
Methylene Chloride ug/L 2500 101 60-140103 2 302500ND25302580
n-Butylbenzene ug/L 2500 113 60-140117 4 302500ND28102930
n-Propylbenzene ug/L 2500 136 60-140138 2 302500ND33903440
Naphthalene ug/L 2500 84 60-14098 8 302500164037504080
o-Xylene ug/L 2500 103 60-14099 1 302500574083108210
sec-Butylbenzene ug/L 2500 111 60-140115 4 302500ND27702890
Styrene ug/L 2500 106 60-140107 1 30250065.3 2700 2740
tert-Amyl Alcohol ug/L 50000 103 60-140110 7 3050000ND5140055100
tert-Amylmethyl ether ug/L 5000 106 60-140109 2 305000ND53005430
tert-Butyl Alcohol ug/L 25000 97 60-140108 11 3025000ND2430027000
tert-Butyl Formate ug/L 20000 99 60-140106 7 3020000ND1980021200
tert-Butylbenzene ug/L 2500 91 60-14095 5 302500ND22702380
Tetrachloroethene ug/L 2500 106 60-140109 3 302500ND26502720
Toluene ug/L 2500 73 60-14075 0 302500188002070020700
trans-1,2-Dichloroethene ug/L 2500 112 60-140116 4 302500ND28002910
trans-1,3-Dichloropropene ug/L 2500 102 60-140107 5 302500ND25402670
Trichloroethene ug/L 2500 109 60-140113 4 302500ND27302830
Trichlorofluoromethane ug/L 2500 102 60-140107 5 302500ND25502670
Vinyl chloride ug/L 2500 115 60-140116 0 302500ND28802890
1,2-Dichloroethane-d4 (S)%95 70-13094
4-Bromofluorobenzene (S)%99 70-13098
Toluene-d8 (S)%101 70-130102
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
505527
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92450350009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2715729
Associated Lab Samples:92450350009
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 0.50 10/24/19 12:240.42
1,1,1-Trichloroethane ug/L ND 0.50 10/24/19 12:240.28
1,1,2,2-Tetrachloroethane ug/L ND 0.50 10/24/19 12:240.19
1,1,2-Trichloroethane ug/L ND 0.50 10/24/19 12:240.23
1,1-Dichloroethane ug/L ND 0.50 10/24/19 12:240.24
1,1-Dichloroethene ug/L ND 0.50 10/24/19 12:240.22
1,1-Dichloropropene ug/L ND 0.50 10/24/19 12:240.35
1,2,3-Trichlorobenzene ug/L ND 2.0 10/24/19 12:240.78
1,2,3-Trichloropropane ug/L ND 0.50 10/24/19 12:240.27
1,2,4-Trichlorobenzene ug/L ND 2.0 10/24/19 12:240.44
1,2,4-Trimethylbenzene ug/L ND 0.50 10/24/19 12:240.19
1,2-Dibromo-3-chloropropane ug/L ND 1.0 10/24/19 12:240.38
1,2-Dibromoethane (EDB)ug/L ND 0.50 10/24/19 12:240.23
1,2-Dichlorobenzene ug/L ND 0.50 10/24/19 12:240.24
1,2-Dichloroethane ug/L ND 0.50 10/24/19 12:240.26
1,2-Dichloropropane ug/L ND 0.50 10/24/19 12:240.18
1,3,5-Trimethylbenzene ug/L ND 0.50 10/24/19 12:240.23
1,3-Dichlorobenzene ug/L ND 0.50 10/24/19 12:240.25
1,3-Dichloropropane ug/L ND 0.50 10/24/19 12:240.34
1,4-Dichlorobenzene ug/L ND 0.50 10/24/19 12:240.25
2,2-Dichloropropane ug/L ND 0.50 10/24/19 12:240.28
2-Chlorotoluene ug/L ND 0.50 10/24/19 12:240.21
4-Chlorotoluene ug/L ND 0.50 10/24/19 12:240.21
Benzene ug/L ND 0.50 10/24/19 12:240.24
Bromobenzene ug/L ND 0.50 10/24/19 12:240.22
Bromochloromethane ug/L ND 0.50 10/24/19 12:240.26
Bromodichloromethane ug/L ND 0.50 10/24/19 12:240.18
Bromoform ug/L ND 0.50 10/24/19 12:240.40
Bromomethane ug/L ND 5.0 10/24/19 12:241.7
Carbon tetrachloride ug/L ND 0.50 10/24/19 12:240.23
Chlorobenzene ug/L ND 0.50 10/24/19 12:240.22
Chloroethane ug/L ND 1.0 10/24/19 12:240.58
Chloroform ug/L ND 0.50 10/24/19 12:240.35
Chloromethane ug/L ND 1.0 10/24/19 12:240.42
cis-1,2-Dichloroethene ug/L ND 0.50 10/24/19 12:240.21
cis-1,3-Dichloropropene ug/L ND 0.50 10/24/19 12:240.36
Dibromochloromethane ug/L ND 0.50 10/24/19 12:240.40
Dibromomethane ug/L ND 0.50 10/24/19 12:240.31
Dichlorodifluoromethane ug/L ND 0.50 10/24/19 12:240.28
Diisopropyl ether ug/L ND 0.50 10/24/19 12:240.33
Ethanol ug/L ND 200 10/24/19 12:2498.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2715729
Associated Lab Samples:92450350009
Matrix:Water
AnalyzedMDL
Ethyl-tert-butyl ether ug/L ND 10.0 10/24/19 12:243.8
Ethylbenzene ug/L ND 0.50 10/24/19 12:240.24
Hexachloro-1,3-butadiene ug/L ND 2.0 10/24/19 12:241.2
Isopropylbenzene (Cumene)ug/L ND 0.50 10/24/19 12:240.24
m&p-Xylene ug/L ND 1.0 10/24/19 12:240.44
Methyl-tert-butyl ether ug/L ND 0.50 10/24/19 12:240.44
Methylene Chloride ug/L ND 2.0 10/24/19 12:241.5
n-Butylbenzene ug/L ND 0.50 10/24/19 12:240.35
n-Propylbenzene ug/L ND 0.50 10/24/19 12:240.24
Naphthalene ug/L ND 2.0 10/24/19 12:240.66
o-Xylene ug/L ND 0.50 10/24/19 12:240.24
sec-Butylbenzene ug/L ND 0.50 10/24/19 12:240.25
Styrene ug/L ND 0.50 10/24/19 12:240.26
tert-Amyl Alcohol ug/L ND 100 10/24/19 12:2440.5
tert-Amylmethyl ether ug/L ND 10.0 10/24/19 12:243.0
tert-Butyl Alcohol ug/L ND 20.0 10/24/19 12:2417.6
tert-Butyl Formate ug/L ND 20.0 10/24/19 12:2417.8
tert-Butylbenzene ug/L ND 0.50 10/24/19 12:240.25
Tetrachloroethene ug/L ND 0.50 10/24/19 12:240.23
Toluene ug/L ND 0.50 10/24/19 12:240.23
trans-1,2-Dichloroethene ug/L ND 0.50 10/24/19 12:240.26
trans-1,3-Dichloropropene ug/L ND 0.50 10/24/19 12:240.39
Trichloroethene ug/L ND 0.50 10/24/19 12:240.23
Trichlorofluoromethane ug/L ND 1.0 10/24/19 12:240.34
Vinyl chloride ug/L ND 1.0 10/24/19 12:240.41
1,2-Dichloroethane-d4 (S)%98 70-130 10/24/19 12:24
4-Bromofluorobenzene (S)%98 70-130 10/24/19 12:24
Toluene-d8 (S)%104 70-130 10/24/19 12:24
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2715730LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 47.850 96 60-140
1,1,1-Trichloroethane ug/L 48.250 96 60-140
1,1,2,2-Tetrachloroethane ug/L 50.250 100 60-140
1,1,2-Trichloroethane ug/L 51.650 103 60-140
1,1-Dichloroethane ug/L 50.750 101 60-140
1,1-Dichloroethene ug/L 50.350 101 60-140
1,1-Dichloropropene ug/L 49.950 100 60-140
1,2,3-Trichlorobenzene ug/L 49.850 100 60-140
1,2,3-Trichloropropane ug/L 49.550 99 60-140
1,2,4-Trichlorobenzene ug/L 48.050 96 60-140
1,2,4-Trimethylbenzene ug/L 47.950 96 60-140
1,2-Dibromo-3-chloropropane ug/L 49.450 99 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2715730LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dibromoethane (EDB)ug/L 50.650 101 60-140
1,2-Dichlorobenzene ug/L 48.250 96 60-140
1,2-Dichloroethane ug/L 44.550 89 60-140
1,2-Dichloropropane ug/L 53.050 106 60-140
1,3,5-Trimethylbenzene ug/L 48.150 96 60-140
1,3-Dichlorobenzene ug/L 47.150 94 60-140
1,3-Dichloropropane ug/L 52.650 105 60-140
1,4-Dichlorobenzene ug/L 46.350 93 60-140
2,2-Dichloropropane ug/L 53.350 107 60-140
2-Chlorotoluene ug/L 47.850 96 60-140
4-Chlorotoluene ug/L 48.650 97 60-140
Benzene ug/L 52.550 105 60-140
Bromobenzene ug/L 48.250 96 60-140
Bromochloromethane ug/L 50.250 100 60-140
Bromodichloromethane ug/L 51.550 103 60-140
Bromoform ug/L 48.250 96 60-140
Bromomethane ug/L 47.050 94 60-140
Carbon tetrachloride ug/L 46.050 92 60-140
Chlorobenzene ug/L 47.350 95 60-140
Chloroethane ug/L 43.850 88 60-140
Chloroform ug/L 48.650 97 60-140
Chloromethane ug/L 44.450 89 60-140
cis-1,2-Dichloroethene ug/L 51.650 103 60-140
cis-1,3-Dichloropropene ug/L 56.750 113 60-140
Dibromochloromethane ug/L 49.750 99 60-140
Dibromomethane ug/L 50.650 101 60-140
Dichlorodifluoromethane ug/L 47.150 94 60-140
Diisopropyl ether ug/L 56.650 113 60-140
Ethanol ug/L 26102000 130 60-140
Ethyl-tert-butyl ether ug/L 105100 105 60-140
Ethylbenzene ug/L 48.350 97 60-140
Hexachloro-1,3-butadiene ug/L 46.750 93 60-140
Isopropylbenzene (Cumene)ug/L 48.750 97 60-140
m&p-Xylene ug/L 96.5100 97 60-140
Methyl-tert-butyl ether ug/L 53.950 108 60-140
Methylene Chloride ug/L 45.750 91 60-140
n-Butylbenzene ug/L 48.850 98 60-140
n-Propylbenzene ug/L 48.450 97 60-140
Naphthalene ug/L 49.350 99 60-140
o-Xylene ug/L 49.950 100 60-140
sec-Butylbenzene ug/L 49.750 99 60-140
Styrene ug/L 49.050 98 60-140
tert-Amyl Alcohol ug/L 11501000 115 60-140
tert-Amylmethyl ether ug/L 105100 105 60-140
tert-Butyl Alcohol ug/L 566500 113 60-140
tert-Butyl Formate ug/L 468400 117 60-140
tert-Butylbenzene ug/L 41.950 84 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2715730LABORATORY CONTROL SAMPLE:
LCSSpike
Tetrachloroethene ug/L 47.950 96 60-140
Toluene ug/L 49.150 98 60-140
trans-1,2-Dichloroethene ug/L 51.350 103 60-140
trans-1,3-Dichloropropene ug/L 53.050 106 60-140
Trichloroethene ug/L 48.950 98 60-140
Trichlorofluoromethane ug/L 45.350 91 60-140
Vinyl chloride ug/L 51.750 103 60-140
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%103 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2715731MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92450297006
2715732
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 500 104 60-140103 1 30500ND519513
1,1,1-Trichloroethane ug/L 500 107 60-140106 1 30500ND536532
1,1,2,2-Tetrachloroethane ug/L 500 108 60-140109 1 30500ND542545
1,1,2-Trichloroethane ug/L 500 111 60-140108 2 30500ND556542
1,1-Dichloroethane ug/L 500 115 60-140111 3 30500ND575557
1,1-Dichloroethene ug/L 500 116 60-140112 4 30500ND580560
1,1-Dichloropropene ug/L 500 113 60-140109 4 30500ND563543
1,2,3-Trichlorobenzene ug/L 500 99 60-14096 4 30500ND496478
1,2,3-Trichloropropane ug/L 500 108 60-140109 1 30500ND541544
1,2,4-Trichlorobenzene ug/L 500 98 60-14095 3 30500ND488475
1,2,4-Trimethylbenzene ug/L 500 100 60-14096 2 3050065411501130
1,2-Dibromo-3-chloropropane ug/L 500 104 60-14097 7 30500ND519486
1,2-Dibromoethane (EDB)ug/L 500 109 60-140108 0 30500181723722
1,2-Dichlorobenzene ug/L 500 104 60-140100 4 30500ND522502
1,2-Dichloroethane ug/L 500 92 60-14090 1 3050088213401330
1,2-Dichloropropane ug/L 500 115 60-140118 3 30500ND583599
1,3,5-Trimethylbenzene ug/L 500 106 60-14099 4 30500321853817
1,3-Dichlorobenzene ug/L 500 103 60-14098 5 30500ND516491
1,3-Dichloropropane ug/L 500 111 60-140111 0 30500ND554554
1,4-Dichlorobenzene ug/L 500 100 60-14097 4 30500ND501484
2,2-Dichloropropane ug/L 500 106 60-140101 4 30500ND529507
2-Chlorotoluene ug/L 500 106 60-140102 4 30500ND531510
4-Chlorotoluene ug/L 500 107 60-140101 5 30500ND534507
Benzene ug/L 500 84 60-14088 1 30500305034703490
Bromobenzene ug/L 500 107 60-140102 4 30500ND534510
Bromochloromethane ug/L 500 112 60-140107 4 30500ND558536
Bromodichloromethane ug/L 500 112 60-140109 3 30500ND560544
Bromoform ug/L 500 100 60-14098 3 30500ND502490
Bromomethane ug/L M15005960-14078 28 30500ND294391
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2715731MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92450297006
2715732
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Carbon tetrachloride ug/L 500 104 60-140102 1 30500ND518511
Chlorobenzene ug/L 500 104 60-140103 1 30500ND522514
Chloroethane ug/L 500 109 60-140108 1 30500ND544539
Chloroform ug/L 500 112 60-140109 3 30500ND561544
Chloromethane ug/L 500 94 60-14092 2 30500ND471462
cis-1,2-Dichloroethene ug/L 500 114 60-140112 2 30500ND572561
cis-1,3-Dichloropropene ug/L 500 118 60-140116 2 30500ND591580
Dibromochloromethane ug/L 500 106 60-140105 1 30500ND530527
Dibromomethane ug/L 500 108 60-140107 1 30500ND538533
Dichlorodifluoromethane ug/L 500 93 60-14091 2 30500ND463453
Diisopropyl ether ug/L 500 125 60-140114 2 30500182024502390
Ethanol ug/L 19 302990024700
Ethyl-tert-butyl ether ug/L 3 3011301100
Ethylbenzene ug/L 500 106 60-140103 2 30500337866852
Hexachloro-1,3-butadiene ug/L 500 96 60-14095 1 30500ND480475
Isopropylbenzene
(Cumene)ug/L 500 108 60-140107 1 3050014.3 553 550
m&p-Xylene ug/L 1000 104 60-140100 1 301000234033703340
Methyl-tert-butyl ether ug/L 500 117 60-140116 1 30500184770762
Methylene Chloride ug/L 500 104 60-140101 3 30500ND519505
n-Butylbenzene ug/L 500 107 60-140106 1 30500ND537531
n-Propylbenzene ug/L 500 113 60-140109 3 30500ND563546
Naphthalene ug/L 500 99 60-14083 8 305005621060978
o-Xylene ug/L 500 111 60-140101 2 30500165022002150
sec-Butylbenzene ug/L 500 111 60-140109 2 30500ND557545
Styrene ug/L 500 107 60-140106 1 30500ND534528
tert-Amyl Alcohol ug/L 6 306070056900
tert-Amylmethyl ether ug/L 1 3011001090
tert-Butyl Alcohol ug/L 9 3084207700
tert-Butyl Formate ug/L 2 3035403470
tert-Butylbenzene ug/L 500 93 60-14090 3 30500ND466451
Tetrachloroethene ug/L 500 106 60-140103 3 30500ND530515
Toluene ug/L M15007060-14052 2 30500407044204330
trans-1,2-Dichloroethene ug/L 500 116 60-140112 4 30500ND582562
trans-1,3-Dichloropropene ug/L 500 109 60-140105 4 30500ND547525
Trichloroethene ug/L 500 112 60-140108 4 30500ND558539
Trichlorofluoromethane ug/L 500 105 60-140102 3 30500ND525510
Vinyl chloride ug/L 500 115 60-140113 2 30500ND574564
1,2-Dichloroethane-d4 (S)%95 70-13095
4-Bromofluorobenzene (S)%100 70-130102
Toluene-d8 (S)%98 70-13099
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
505532
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92450350006, 92450350007, 92450350008
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2715752
Associated Lab Samples:92450350006, 92450350007, 92450350008
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 0.50 10/24/19 11:080.42
1,1,1-Trichloroethane ug/L ND 0.50 10/24/19 11:080.28
1,1,2,2-Tetrachloroethane ug/L ND 0.50 10/24/19 11:080.19
1,1,2-Trichloroethane ug/L ND 0.50 10/24/19 11:080.23
1,1-Dichloroethane ug/L ND 0.50 10/24/19 11:080.24
1,1-Dichloroethene ug/L ND 0.50 10/24/19 11:080.22
1,1-Dichloropropene ug/L ND 0.50 10/24/19 11:080.35
1,2,3-Trichlorobenzene ug/L ND 2.0 10/24/19 11:080.78
1,2,3-Trichloropropane ug/L ND 0.50 10/24/19 11:080.27
1,2,4-Trichlorobenzene ug/L ND 2.0 10/24/19 11:080.44
1,2,4-Trimethylbenzene ug/L ND 0.50 10/24/19 11:080.19
1,2-Dibromo-3-chloropropane ug/L ND 1.0 10/24/19 11:080.38
1,2-Dibromoethane (EDB)ug/L ND 0.50 10/24/19 11:080.23
1,2-Dichlorobenzene ug/L ND 0.50 10/24/19 11:080.24
1,2-Dichloroethane ug/L ND 0.50 10/24/19 11:080.26
1,2-Dichloropropane ug/L ND 0.50 10/24/19 11:080.18
1,3,5-Trimethylbenzene ug/L ND 0.50 10/24/19 11:080.23
1,3-Dichlorobenzene ug/L ND 0.50 10/24/19 11:080.25
1,3-Dichloropropane ug/L ND 0.50 10/24/19 11:080.34
1,4-Dichlorobenzene ug/L ND 0.50 10/24/19 11:080.25
2,2-Dichloropropane ug/L ND 0.50 10/24/19 11:080.28
2-Chlorotoluene ug/L ND 0.50 10/24/19 11:080.21
4-Chlorotoluene ug/L ND 0.50 10/24/19 11:080.21
Benzene ug/L ND 0.50 10/24/19 11:080.24
Bromobenzene ug/L ND 0.50 10/24/19 11:080.22
Bromochloromethane ug/L ND 0.50 10/24/19 11:080.26
Bromodichloromethane ug/L ND 0.50 10/24/19 11:080.18
Bromoform ug/L ND 0.50 10/24/19 11:080.40
Bromomethane ug/L ND 5.0 10/24/19 11:081.7
Carbon tetrachloride ug/L ND 0.50 10/24/19 11:080.23
Chlorobenzene ug/L ND 0.50 10/24/19 11:080.22
Chloroethane ug/L ND 1.0 10/24/19 11:080.58
Chloroform ug/L ND 0.50 10/24/19 11:080.35
Chloromethane ug/L ND 1.0 10/24/19 11:080.42
cis-1,2-Dichloroethene ug/L ND 0.50 10/24/19 11:080.21
cis-1,3-Dichloropropene ug/L ND 0.50 10/24/19 11:080.36
Dibromochloromethane ug/L ND 0.50 10/24/19 11:080.40
Dibromomethane ug/L ND 0.50 10/24/19 11:080.31
Dichlorodifluoromethane ug/L ND 0.50 10/24/19 11:080.28
Diisopropyl ether ug/L ND 0.50 10/24/19 11:080.33
Ethanol ug/L ND 200 10/24/19 11:0898.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2715752
Associated Lab Samples:92450350006, 92450350007, 92450350008
Matrix:Water
AnalyzedMDL
Ethyl-tert-butyl ether ug/L ND 10.0 10/24/19 11:083.8
Ethylbenzene ug/L ND 0.50 10/24/19 11:080.24
Hexachloro-1,3-butadiene ug/L ND 2.0 10/24/19 11:081.2
Isopropylbenzene (Cumene)ug/L ND 0.50 10/24/19 11:080.24
m&p-Xylene ug/L ND 1.0 10/24/19 11:080.44
Methyl-tert-butyl ether ug/L ND 0.50 10/24/19 11:080.44
Methylene Chloride ug/L ND 2.0 10/24/19 11:081.5
n-Butylbenzene ug/L ND 0.50 10/24/19 11:080.35
n-Propylbenzene ug/L ND 0.50 10/24/19 11:080.24
Naphthalene ug/L ND 2.0 10/24/19 11:080.66
o-Xylene ug/L ND 0.50 10/24/19 11:080.24
sec-Butylbenzene ug/L ND 0.50 10/24/19 11:080.25
Styrene ug/L ND 0.50 10/24/19 11:080.26
tert-Amyl Alcohol ug/L ND 100 10/24/19 11:0840.5
tert-Amylmethyl ether ug/L ND 10.0 10/24/19 11:083.0
tert-Butyl Alcohol ug/L ND 20.0 10/24/19 11:0817.6
tert-Butyl Formate ug/L ND 20.0 10/24/19 11:0817.8
tert-Butylbenzene ug/L ND 0.50 10/24/19 11:080.25
Tetrachloroethene ug/L ND 0.50 10/24/19 11:080.23
Toluene ug/L ND 0.50 10/24/19 11:080.23
trans-1,2-Dichloroethene ug/L ND 0.50 10/24/19 11:080.26
trans-1,3-Dichloropropene ug/L ND 0.50 10/24/19 11:080.39
Trichloroethene ug/L ND 0.50 10/24/19 11:080.23
Trichlorofluoromethane ug/L ND 1.0 10/24/19 11:080.34
Vinyl chloride ug/L ND 1.0 10/24/19 11:080.41
1,2-Dichloroethane-d4 (S)%94 70-130 10/24/19 11:08
4-Bromofluorobenzene (S)%99 70-130 10/24/19 11:08
Toluene-d8 (S)%103 70-130 10/24/19 11:08
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2715753LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 51.850 104 60-140
1,1,1-Trichloroethane ug/L 46.650 93 60-140
1,1,2,2-Tetrachloroethane ug/L 51.150 102 60-140
1,1,2-Trichloroethane ug/L 50.250 100 60-140
1,1-Dichloroethane ug/L 46.850 94 60-140
1,1-Dichloroethene ug/L 47.450 95 60-140
1,1-Dichloropropene ug/L 49.250 98 60-140
1,2,3-Trichlorobenzene ug/L 52.050 104 60-140
1,2,3-Trichloropropane ug/L 52.850 106 60-140
1,2,4-Trichlorobenzene ug/L 50.550 101 60-140
1,2,4-Trimethylbenzene ug/L 49.050 98 60-140
1,2-Dibromo-3-chloropropane ug/L 50.350 101 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2715753LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dibromoethane (EDB)ug/L 51.350 103 60-140
1,2-Dichlorobenzene ug/L 48.250 96 60-140
1,2-Dichloroethane ug/L 42.350 85 60-140
1,2-Dichloropropane ug/L 49.850 100 60-140
1,3,5-Trimethylbenzene ug/L 48.650 97 60-140
1,3-Dichlorobenzene ug/L 48.650 97 60-140
1,3-Dichloropropane ug/L 53.350 107 60-140
1,4-Dichlorobenzene ug/L 46.550 93 60-140
2,2-Dichloropropane ug/L 47.450 95 60-140
2-Chlorotoluene ug/L 48.950 98 60-140
4-Chlorotoluene ug/L 47.250 94 60-140
Benzene ug/L 48.650 97 60-140
Bromobenzene ug/L 50.050 100 60-140
Bromochloromethane ug/L 44.550 89 60-140
Bromodichloromethane ug/L 49.850 100 60-140
Bromoform ug/L 53.950 108 60-140
Bromomethane ug/L 44.750 89 60-140
Carbon tetrachloride ug/L 47.350 95 60-140
Chlorobenzene ug/L 46.650 93 60-140
Chloroethane ug/L 39.150 78 60-140
Chloroform ug/L 45.150 90 60-140
Chloromethane ug/L 44.450 89 60-140
cis-1,2-Dichloroethene ug/L 46.250 92 60-140
cis-1,3-Dichloropropene ug/L 54.150 108 60-140
Dibromochloromethane ug/L 53.050 106 60-140
Dibromomethane ug/L 47.850 96 60-140
Dichlorodifluoromethane ug/L 44.250 88 60-140
Diisopropyl ether ug/L 51.250 102 60-140
Ethanol ug/L 19202000 96 60-140
Ethyl-tert-butyl ether ug/L 98.5100 98 60-140
Ethylbenzene ug/L 48.150 96 60-140
Hexachloro-1,3-butadiene ug/L 49.650 99 60-140
Isopropylbenzene (Cumene)ug/L 48.050 96 60-140
m&p-Xylene ug/L 95.5100 95 60-140
Methyl-tert-butyl ether ug/L 54.250 108 60-140
Methylene Chloride ug/L 42.650 85 60-140
n-Butylbenzene ug/L 49.650 99 60-140
n-Propylbenzene ug/L 49.350 99 60-140
Naphthalene ug/L 52.550 105 60-140
o-Xylene ug/L 48.450 97 60-140
sec-Butylbenzene ug/L 50.650 101 60-140
Styrene ug/L 49.750 99 60-140
tert-Amyl Alcohol ug/L 10901000 109 60-140
tert-Amylmethyl ether ug/L 100100 100 60-140
tert-Butyl Alcohol ug/L 445500 89 60-140
tert-Butyl Formate ug/L 453400 113 60-140
tert-Butylbenzene ug/L 42.650 85 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2715753LABORATORY CONTROL SAMPLE:
LCSSpike
Tetrachloroethene ug/L 48.450 97 60-140
Toluene ug/L 45.350 91 60-140
trans-1,2-Dichloroethene ug/L 47.550 95 60-140
trans-1,3-Dichloropropene ug/L 51.050 102 60-140
Trichloroethene ug/L 49.850 100 60-140
Trichlorofluoromethane ug/L 47.550 95 60-140
Vinyl chloride ug/L 47.450 95 60-140
1,2-Dichloroethane-d4 (S)%94 70-130
4-Bromofluorobenzene (S)%98 70-130
Toluene-d8 (S)%98 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2715754MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92450348002
2715755
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 500 105 60-140103 2 30500ND524514
1,1,1-Trichloroethane ug/L 500 103 60-14098 4 30500ND514492
1,1,2,2-Tetrachloroethane ug/L 500 100 60-140102 2 30500ND501512
1,1,2-Trichloroethane ug/L 500 103 60-140101 2 30500ND514505
1,1-Dichloroethane ug/L 500 100 60-14096 4 30500ND499482
1,1-Dichloroethene ug/L 500 101 60-14099 2 30500ND506494
1,1-Dichloropropene ug/L 500 104 60-140103 1 30500ND520513
1,2,3-Trichlorobenzene ug/L 500 105 60-140104 1 30500ND523520
1,2,3-Trichloropropane ug/L 500 105 60-140108 3 30500ND526540
1,2,4-Trichlorobenzene ug/L 500 103 60-140102 0 30500ND513512
1,2,4-Trimethylbenzene ug/L 500 99 60-14090 2 30500131018001760
1,2-Dibromo-3-chloropropane ug/L 500 102 60-140102 0 30500ND512511
1,2-Dibromoethane (EDB)ug/L 500 103 60-140103 0 30500ND515514
1,2-Dichlorobenzene ug/L 500 100 60-140100 0 30500ND499498
1,2-Dichloroethane ug/L 500 87 60-14087 1 30500ND436433
1,2-Dichloropropane ug/L 500 103 60-140101 2 30500ND517505
1,3,5-Trimethylbenzene ug/L M150017160-140168 2 30500ND857842
1,3-Dichlorobenzene ug/L 500 96 60-14096 1 30500ND482478
1,3-Dichloropropane ug/L 500 106 60-140107 2 30500ND528536
1,4-Dichlorobenzene ug/L 500 101 60-14098 3 30500ND505490
2,2-Dichloropropane ug/L 500 95 60-14091 4 30500ND473456
2-Chlorotoluene ug/L 500 124 60-140109 13 30500ND618543
4-Chlorotoluene ug/L 500 101 60-14099 1 30500ND503496
Benzene ug/L 500 106 60-14083 3 30500343039603850
Bromobenzene ug/L 500 103 60-140103 0 30500ND514515
Bromochloromethane ug/L 500 93 60-14093 1 30500ND467465
Bromodichloromethane ug/L 500 104 60-140100 4 30500ND519501
Bromoform ug/L 500 101 60-140103 2 30500ND503516
Bromomethane ug/L 500 98 60-14099 1 30500ND491496
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2715754MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92450348002
2715755
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Carbon tetrachloride ug/L 500 104 60-140102 2 30500ND522509
Chlorobenzene ug/L 500 100 60-140100 0 30500ND499498
Chloroethane ug/L 500 102 60-14095 7 30500ND511476
Chloroform ug/L 500 97 60-14094 3 30500ND485470
Chloromethane ug/L 500 89 60-14084 6 30500ND443418
cis-1,2-Dichloroethene ug/L 500 98 60-14096 2 30500ND492480
cis-1,3-Dichloropropene ug/L 500 108 60-140105 3 30500ND540525
Dibromochloromethane ug/L 500 102 60-140105 3 30500ND511526
Dibromomethane ug/L 500 100 60-14097 3 30500ND500487
Dichlorodifluoromethane ug/L 500 83 60-14078 7 30500ND414388
Diisopropyl ether ug/L 500 102 60-140104 1 30500362870881
Ethanol ug/L 5 301820019100
Ethyl-tert-butyl ether ug/L 2 30955974
Ethylbenzene ug/L 500 99 60-140100 1 3050056310601060
Hexachloro-1,3-butadiene ug/L 500 103 60-14098 5 30500ND516492
Isopropylbenzene
(Cumene)ug/L 500 104 60-140101 3 3050024.2 544 529
m&p-Xylene ug/L 1000 82 60-14082 0 301000259034103410
Methyl-tert-butyl ether ug/L 500 120 60-140129 2 30500118017801830
Methylene Chloride ug/L 500 91 60-14089 2 30500ND454445
n-Butylbenzene ug/L 500 110 60-140106 4 30500ND549528
n-Propylbenzene ug/L 500 116 60-140114 1 30500ND578572
Naphthalene ug/L 500 105 60-140107 1 30500103015501560
o-Xylene ug/L 500 95 60-14087 2 30500118016501620
sec-Butylbenzene ug/L 500 107 60-140104 3 30500ND534518
Styrene ug/L 500 109 60-140110 1 30500ND546549
tert-Amyl Alcohol ug/L 9 302220024100
tert-Amylmethyl ether ug/L 0 3011901190
tert-Butyl Alcohol ug/L 14 3048805600
tert-Butyl Formate ug/L 2 3034303510
tert-Butylbenzene ug/L 500 89 60-14090 1 30500ND447451
Tetrachloroethene ug/L 500 100 60-140102 2 30500ND502511
Toluene ug/L M15006760-14047 3 30500349038203730
trans-1,2-Dichloroethene ug/L 500 99 60-14098 1 30500ND495490
trans-1,3-Dichloropropene ug/L 500 101 60-140100 2 30500ND506499
Trichloroethene ug/L 500 107 60-140105 2 30500ND537527
Trichlorofluoromethane ug/L 500 104 60-14098 6 30500ND518488
Vinyl chloride ug/L 500 94 60-14089 6 30500ND472443
1,2-Dichloroethane-d4 (S)%99 70-130100
4-Bromofluorobenzene (S)%98 70-13099
Toluene-d8 (S)%99 70-13097
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
505583
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92450350001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2716090
Associated Lab Samples:92450350001
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 0.50 10/24/19 21:200.42
1,1,1-Trichloroethane ug/L ND 0.50 10/24/19 21:200.28
1,1,2,2-Tetrachloroethane ug/L ND 0.50 10/24/19 21:200.19
1,1,2-Trichloroethane ug/L ND 0.50 10/24/19 21:200.23
1,1-Dichloroethane ug/L ND 0.50 10/24/19 21:200.24
1,1-Dichloroethene ug/L ND 0.50 10/24/19 21:200.22
1,1-Dichloropropene ug/L ND 0.50 10/24/19 21:200.35
1,2,3-Trichlorobenzene ug/L ND 2.0 10/24/19 21:200.78
1,2,3-Trichloropropane ug/L ND 0.50 10/24/19 21:200.27
1,2,4-Trichlorobenzene ug/L ND 2.0 10/24/19 21:200.44
1,2,4-Trimethylbenzene ug/L ND 0.50 10/24/19 21:200.19
1,2-Dibromo-3-chloropropane ug/L ND 1.0 10/24/19 21:200.38
1,2-Dibromoethane (EDB)ug/L ND 0.50 10/24/19 21:200.23
1,2-Dichlorobenzene ug/L ND 0.50 10/24/19 21:200.24
1,2-Dichloroethane ug/L ND 0.50 10/24/19 21:200.26
1,2-Dichloropropane ug/L ND 0.50 10/24/19 21:200.18
1,3,5-Trimethylbenzene ug/L ND 0.50 10/24/19 21:200.23
1,3-Dichlorobenzene ug/L ND 0.50 10/24/19 21:200.25
1,3-Dichloropropane ug/L ND 0.50 10/24/19 21:200.34
1,4-Dichlorobenzene ug/L ND 0.50 10/24/19 21:200.25
2,2-Dichloropropane ug/L ND 0.50 10/24/19 21:200.28
2-Chlorotoluene ug/L ND 0.50 10/24/19 21:200.21
4-Chlorotoluene ug/L ND 0.50 10/24/19 21:200.21
Benzene ug/L ND 0.50 10/24/19 21:200.24
Bromobenzene ug/L ND 0.50 10/24/19 21:200.22
Bromochloromethane ug/L ND 0.50 10/24/19 21:200.26
Bromodichloromethane ug/L ND 0.50 10/24/19 21:200.18
Bromoform ug/L ND 0.50 10/24/19 21:200.40
Bromomethane ug/L ND 5.0 10/24/19 21:201.7
Carbon tetrachloride ug/L ND 0.50 10/24/19 21:200.23
Chlorobenzene ug/L ND 0.50 10/24/19 21:200.22
Chloroethane ug/L ND 1.0 10/24/19 21:200.58
Chloroform ug/L ND 0.50 10/24/19 21:200.35
Chloromethane ug/L ND 1.0 10/24/19 21:200.42
cis-1,2-Dichloroethene ug/L ND 0.50 10/24/19 21:200.21
cis-1,3-Dichloropropene ug/L ND 0.50 10/24/19 21:200.36
Dibromochloromethane ug/L ND 0.50 10/24/19 21:200.40
Dibromomethane ug/L ND 0.50 10/24/19 21:200.31
Dichlorodifluoromethane ug/L ND 0.50 10/24/19 21:200.28
Diisopropyl ether ug/L ND 0.50 10/24/19 21:200.33
Ethanol ug/L ND 200 10/24/19 21:2098.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2716090
Associated Lab Samples:92450350001
Matrix:Water
AnalyzedMDL
Ethyl-tert-butyl ether ug/L ND 10.0 10/24/19 21:203.8
Ethylbenzene ug/L ND 0.50 10/24/19 21:200.24
Hexachloro-1,3-butadiene ug/L ND 2.0 10/24/19 21:201.2
Isopropylbenzene (Cumene)ug/L ND 0.50 10/24/19 21:200.24
m&p-Xylene ug/L ND 1.0 10/24/19 21:200.44
Methyl-tert-butyl ether ug/L ND 0.50 10/24/19 21:200.44
Methylene Chloride ug/L ND 2.0 10/24/19 21:201.5
n-Butylbenzene ug/L ND 0.50 10/24/19 21:200.35
n-Propylbenzene ug/L ND 0.50 10/24/19 21:200.24
Naphthalene ug/L ND 2.0 10/24/19 21:200.66
o-Xylene ug/L ND 0.50 10/24/19 21:200.24
sec-Butylbenzene ug/L ND 0.50 10/24/19 21:200.25
Styrene ug/L ND 0.50 10/24/19 21:200.26
tert-Amyl Alcohol ug/L ND 100 10/24/19 21:2040.5
tert-Amylmethyl ether ug/L ND 10.0 10/24/19 21:203.0
tert-Butyl Alcohol ug/L ND 20.0 10/24/19 21:2017.6
tert-Butyl Formate ug/L ND 20.0 10/24/19 21:2017.8
tert-Butylbenzene ug/L ND 0.50 10/24/19 21:200.25
Tetrachloroethene ug/L ND 0.50 10/24/19 21:200.23
Toluene ug/L ND 0.50 10/24/19 21:200.23
trans-1,2-Dichloroethene ug/L ND 0.50 10/24/19 21:200.26
trans-1,3-Dichloropropene ug/L ND 0.50 10/24/19 21:200.39
Trichloroethene ug/L ND 0.50 10/24/19 21:200.23
Trichlorofluoromethane ug/L ND 1.0 10/24/19 21:200.34
Vinyl chloride ug/L ND 1.0 10/24/19 21:200.41
1,2-Dichloroethane-d4 (S)%93 70-130 10/24/19 21:20
4-Bromofluorobenzene (S)%97 70-130 10/24/19 21:20
Toluene-d8 (S)%103 70-130 10/24/19 21:20
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2716091LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.250 100 60-140
1,1,1-Trichloroethane ug/L 50.350 101 60-140
1,1,2,2-Tetrachloroethane ug/L 52.050 104 60-140
1,1,2-Trichloroethane ug/L 52.650 105 60-140
1,1-Dichloroethane ug/L 53.950 108 60-140
1,1-Dichloroethene ug/L 52.650 105 60-140
1,1-Dichloropropene ug/L 52.450 105 60-140
1,2,3-Trichlorobenzene ug/L 46.950 94 60-140
1,2,3-Trichloropropane ug/L 52.450 105 60-140
1,2,4-Trichlorobenzene ug/L 46.650 93 60-140
1,2,4-Trimethylbenzene ug/L 49.550 99 60-140
1,2-Dibromo-3-chloropropane ug/L 50.150 100 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2716091LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dibromoethane (EDB)ug/L 52.550 105 60-140
1,2-Dichlorobenzene ug/L 49.750 99 60-140
1,2-Dichloroethane ug/L 47.150 94 60-140
1,2-Dichloropropane ug/L 55.950 112 60-140
1,3,5-Trimethylbenzene ug/L 49.750 99 60-140
1,3-Dichlorobenzene ug/L 49.050 98 60-140
1,3-Dichloropropane ug/L 54.950 110 60-140
1,4-Dichlorobenzene ug/L 47.450 95 60-140
2,2-Dichloropropane ug/L 54.350 109 60-140
2-Chlorotoluene ug/L 49.250 98 60-140
4-Chlorotoluene ug/L 49.850 100 60-140
Benzene ug/L 55.450 111 60-140
Bromobenzene ug/L 49.850 100 60-140
Bromochloromethane ug/L 52.750 105 60-140
Bromodichloromethane ug/L 53.450 107 60-140
Bromoform ug/L 49.950 100 60-140
Bromomethane ug/L 53.950 108 60-140
Carbon tetrachloride ug/L 48.750 97 60-140
Chlorobenzene ug/L 49.550 99 60-140
Chloroethane ug/L 46.450 93 60-140
Chloroform ug/L 51.450 103 60-140
Chloromethane ug/L 44.250 88 60-140
cis-1,2-Dichloroethene ug/L 54.450 109 60-140
cis-1,3-Dichloropropene ug/L 58.150 116 60-140
Dibromochloromethane ug/L 50.750 101 60-140
Dibromomethane ug/L 53.650 107 60-140
Dichlorodifluoromethane ug/L 41.250 82 60-140
Diisopropyl ether ug/L 58.250 116 60-140
Ethanol ug/L 25102000 126 60-140
Ethyl-tert-butyl ether ug/L 108100 108 60-140
Ethylbenzene ug/L 50.750 101 60-140
Hexachloro-1,3-butadiene ug/L 46.450 93 60-140
Isopropylbenzene (Cumene)ug/L 51.350 103 60-140
m&p-Xylene ug/L 101100 101 60-140
Methyl-tert-butyl ether ug/L 55.550 111 60-140
Methylene Chloride ug/L 47.150 94 60-140
n-Butylbenzene ug/L 50.850 102 60-140
n-Propylbenzene ug/L 51.050 102 60-140
Naphthalene ug/L 48.350 97 60-140
o-Xylene ug/L 52.650 105 60-140
sec-Butylbenzene ug/L 52.350 105 60-140
Styrene ug/L 51.050 102 60-140
tert-Amyl Alcohol ug/L 11601000 116 60-140
tert-Amylmethyl ether ug/L 109100 109 60-140
tert-Butyl Alcohol ug/L 583500 117 60-140
tert-Butyl Formate ug/L 478400 119 60-140
tert-Butylbenzene ug/L 43.550 87 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2716091LABORATORY CONTROL SAMPLE:
LCSSpike
Tetrachloroethene ug/L 49.750 99 60-140
Toluene ug/L 51.550 103 60-140
trans-1,2-Dichloroethene ug/L 54.350 109 60-140
trans-1,3-Dichloropropene ug/L 54.050 108 60-140
Trichloroethene ug/L 51.850 104 60-140
Trichlorofluoromethane ug/L 46.850 94 60-140
Vinyl chloride ug/L 52.450 105 60-140
1,2-Dichloroethane-d4 (S)%93 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%102 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2716092MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92450348003
2716093
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 2000 103 60-140104 1 302000ND20602090
1,1,1-Trichloroethane ug/L 2000 107 60-140107 0 302000ND21402150
1,1,2,2-Tetrachloroethane ug/L 2000 103 60-140104 0 302000ND20602070
1,1,2-Trichloroethane ug/L 2000 109 60-140112 2 302000ND21902240
1,1-Dichloroethane ug/L 2000 111 60-140111 1 302000ND22102220
1,1-Dichloroethene ug/L 2000 110 60-140111 1 302000ND22002220
1,1-Dichloropropene ug/L 2000 108 60-140109 2 302000ND21502190
1,2,3-Trichlorobenzene ug/L 2000 86 60-14099 15 302000ND17101980
1,2,3-Trichloropropane ug/L 2000 103 60-140104 1 302000ND20502080
1,2,4-Trichlorobenzene ug/L 2000 87 60-14096 9 302000ND17501920
1,2,4-Trimethylbenzene ug/L 2000 98 60-140101 2 30200091628802940
1,2-Dibromo-3-chloropropane ug/L 2000 96 60-14099 4 302000ND19101980
1,2-Dibromoethane (EDB)ug/L 2000 101 60-140107 6 302000ND20102130
1,2-Dichlorobenzene ug/L 2000 98 60-140102 3 302000ND19702030
1,2-Dichloroethane ug/L 2000 97 60-14099 2 302000ND19401980
1,2-Dichloropropane ug/L 2000 109 60-140113 3 302000ND21902260
1,3,5-Trimethylbenzene ug/L 2000 113 60-140114 1 302000ND22602290
1,3-Dichlorobenzene ug/L 2000 98 60-14098 1 302000ND19501970
1,3-Dichloropropane ug/L 2000 110 60-140108 1 302000ND21902170
1,4-Dichlorobenzene ug/L 2000 94 60-14097 3 302000ND18801940
2,2-Dichloropropane ug/L 2000 87 60-14090 3 302000ND17401790
2-Chlorotoluene ug/L 2000 101 60-140102 1 302000ND20102030
4-Chlorotoluene ug/L 2000 99 60-140103 4 302000ND19802050
Benzene ug/L 2000 113 60-140115 1 30200062828902930
Bromobenzene ug/L 2000 100 60-140103 3 302000ND20002060
Bromochloromethane ug/L 2000 107 60-140111 3 302000ND21402210
Bromodichloromethane ug/L 2000 108 60-140109 1 302000ND21602190
Bromoform ug/L 2000 100 60-140103 3 302000ND20102070
Bromomethane ug/L M120005160-14065 25 302000ND10101300
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2716092MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92450348003
2716093
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Carbon tetrachloride ug/L 2000 102 60-140105 3 302000ND20402110
Chlorobenzene ug/L 2000 102 60-140102 0 302000ND20402040
Chloroethane ug/L 2000 111 60-140105 6 302000ND22202100
Chloroform ug/L 2000 108 60-140109 1 302000ND21702180
Chloromethane ug/L 2000 86 60-14086 0 302000ND17201710
cis-1,2-Dichloroethene ug/L 2000 111 60-140113 2 302000ND22102260
cis-1,3-Dichloropropene ug/L 2000 111 60-140115 4 302000ND22202310
Dibromochloromethane ug/L 2000 104 60-140104 0 302000ND20802070
Dibromomethane ug/L 2000 108 60-140112 4 302000ND21502230
Dichlorodifluoromethane ug/L 2000 93 60-14095 2 302000ND18601910
Diisopropyl ether ug/L 2000 116 60-140117 1 302000ND23202330
Ethanol ug/L 4 30106000101000
Ethyl-tert-butyl ether ug/L 4 3041004280
Ethylbenzene ug/L 2000 104 60-140105 0 30200090229903000
Hexachloro-1,3-butadiene ug/L 2000 86 60-14094 9 302000ND17201890
Isopropylbenzene
(Cumene)ug/L 2000 107 60-140109 1 302000ND21502170
m&p-Xylene ug/L 4000 103 60-140104 1 304000324073607410
Methyl-tert-butyl ether ug/L 2000 107 60-140108 2 302000ND21302170
Methylene Chloride ug/L 2000 102 60-140104 2 302000ND20402090
n-Butylbenzene ug/L 2000 97 60-140102 4 302000ND19502030
n-Propylbenzene ug/L 2000 106 60-140109 3 302000ND21302190
Naphthalene ug/L 2000 87 60-140107 16 30200051422602660
o-Xylene ug/L 2000 107 60-140108 0 302000199041304150
sec-Butylbenzene ug/L 2000 106 60-140108 2 302000ND21202160
Styrene ug/L 2000 104 60-140105 1 30200036.1J 2120 2140
tert-Amyl Alcohol ug/L 9 304120045100
tert-Amylmethyl ether ug/L 2 3041004190
tert-Butyl Alcohol ug/L 8 302270024700
tert-Butyl Formate ug/L 3 301550016000
tert-Butylbenzene ug/L 2000 88 60-14091 3 302000ND17701810
Tetrachloroethene ug/L 2000 102 60-140103 1 302000ND20402070
Toluene ug/L 2000 86 60-14094 1 302000131001490015000
trans-1,2-Dichloroethene ug/L 2000 111 60-140111 0 302000ND22202220
trans-1,3-Dichloropropene ug/L 2000 101 60-140107 6 302000ND20302140
Trichloroethene ug/L 2000 107 60-140111 4 302000ND21302230
Trichlorofluoromethane ug/L 2000 103 60-140102 1 302000ND20602040
Vinyl chloride ug/L 2000 110 60-140111 1 302000ND22102230
1,2-Dichloroethane-d4 (S)%95 70-13096
4-Bromofluorobenzene (S)%102 70-13099
Toluene-d8 (S)%100 70-130102
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 39 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
505770
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92450350003, 92450350004, 92450350005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2716933
Associated Lab Samples:92450350003, 92450350004, 92450350005
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 0.50 10/25/19 10:490.42
1,1,1-Trichloroethane ug/L ND 0.50 10/25/19 10:490.28
1,1,2,2-Tetrachloroethane ug/L ND 0.50 10/25/19 10:490.19
1,1,2-Trichloroethane ug/L ND 0.50 10/25/19 10:490.23
1,1-Dichloroethane ug/L ND 0.50 10/25/19 10:490.24
1,1-Dichloroethene ug/L ND 0.50 10/25/19 10:490.22
1,1-Dichloropropene ug/L ND 0.50 10/25/19 10:490.35
1,2,3-Trichlorobenzene ug/L ND 2.0 10/25/19 10:490.78
1,2,3-Trichloropropane ug/L ND 0.50 10/25/19 10:490.27
1,2,4-Trichlorobenzene ug/L ND 2.0 10/25/19 10:490.44
1,2,4-Trimethylbenzene ug/L ND 0.50 10/25/19 10:490.19
1,2-Dibromo-3-chloropropane ug/L ND 1.0 10/25/19 10:490.38
1,2-Dibromoethane (EDB)ug/L ND 0.50 10/25/19 10:490.23
1,2-Dichlorobenzene ug/L ND 0.50 10/25/19 10:490.24
1,2-Dichloroethane ug/L ND 0.50 10/25/19 10:490.26
1,2-Dichloropropane ug/L ND 0.50 10/25/19 10:490.18
1,3,5-Trimethylbenzene ug/L ND 0.50 10/25/19 10:490.23
1,3-Dichlorobenzene ug/L ND 0.50 10/25/19 10:490.25
1,3-Dichloropropane ug/L ND 0.50 10/25/19 10:490.34
1,4-Dichlorobenzene ug/L ND 0.50 10/25/19 10:490.25
2,2-Dichloropropane ug/L ND 0.50 10/25/19 10:490.28
2-Chlorotoluene ug/L ND 0.50 10/25/19 10:490.21
4-Chlorotoluene ug/L ND 0.50 10/25/19 10:490.21
Benzene ug/L ND 0.50 10/25/19 10:490.24
Bromobenzene ug/L ND 0.50 10/25/19 10:490.22
Bromochloromethane ug/L ND 0.50 10/25/19 10:490.26
Bromodichloromethane ug/L ND 0.50 10/25/19 10:490.18
Bromoform ug/L ND 0.50 10/25/19 10:490.40
Bromomethane ug/L ND 5.0 10/25/19 10:491.7
Carbon tetrachloride ug/L ND 0.50 10/25/19 10:490.23
Chlorobenzene ug/L ND 0.50 10/25/19 10:490.22
Chloroethane ug/L ND 1.0 10/25/19 10:490.58
Chloroform ug/L ND 0.50 10/25/19 10:490.35
Chloromethane ug/L ND 1.0 10/25/19 10:490.42
cis-1,2-Dichloroethene ug/L ND 0.50 10/25/19 10:490.21
cis-1,3-Dichloropropene ug/L ND 0.50 10/25/19 10:490.36
Dibromochloromethane ug/L ND 0.50 10/25/19 10:490.40
Dibromomethane ug/L ND 0.50 10/25/19 10:490.31
Dichlorodifluoromethane ug/L ND 0.50 10/25/19 10:490.28
Diisopropyl ether ug/L ND 0.50 10/25/19 10:490.33
Ethanol ug/L ND 200 10/25/19 10:4998.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 40 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2716933
Associated Lab Samples:92450350003, 92450350004, 92450350005
Matrix:Water
AnalyzedMDL
Ethyl-tert-butyl ether ug/L ND 10.0 10/25/19 10:493.8
Ethylbenzene ug/L ND 0.50 10/25/19 10:490.24
Hexachloro-1,3-butadiene ug/L ND 2.0 10/25/19 10:491.2
Isopropylbenzene (Cumene)ug/L ND 0.50 10/25/19 10:490.24
m&p-Xylene ug/L ND 1.0 10/25/19 10:490.44
Methyl-tert-butyl ether ug/L ND 0.50 10/25/19 10:490.44
Methylene Chloride ug/L ND 2.0 10/25/19 10:491.5
n-Butylbenzene ug/L ND 0.50 10/25/19 10:490.35
n-Propylbenzene ug/L ND 0.50 10/25/19 10:490.24
Naphthalene ug/L ND 2.0 10/25/19 10:490.66
o-Xylene ug/L ND 0.50 10/25/19 10:490.24
sec-Butylbenzene ug/L ND 0.50 10/25/19 10:490.25
Styrene ug/L ND 0.50 10/25/19 10:490.26
tert-Amyl Alcohol ug/L ND 100 10/25/19 10:4940.5
tert-Amylmethyl ether ug/L ND 10.0 10/25/19 10:493.0
tert-Butyl Alcohol ug/L ND 20.0 10/25/19 10:4917.6
tert-Butyl Formate ug/L ND 20.0 10/25/19 10:4917.8
tert-Butylbenzene ug/L ND 0.50 10/25/19 10:490.25
Tetrachloroethene ug/L ND 0.50 10/25/19 10:490.23
Toluene ug/L ND 0.50 10/25/19 10:490.23
trans-1,2-Dichloroethene ug/L ND 0.50 10/25/19 10:490.26
trans-1,3-Dichloropropene ug/L ND 0.50 10/25/19 10:490.39
Trichloroethene ug/L ND 0.50 10/25/19 10:490.23
Trichlorofluoromethane ug/L ND 1.0 10/25/19 10:490.34
Vinyl chloride ug/L ND 1.0 10/25/19 10:490.41
1,2-Dichloroethane-d4 (S)%97 70-130 10/25/19 10:49
4-Bromofluorobenzene (S)%98 70-130 10/25/19 10:49
Toluene-d8 (S)%105 70-130 10/25/19 10:49
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2716934LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 48.450 97 60-140
1,1,1-Trichloroethane ug/L 53.050 106 60-140
1,1,2,2-Tetrachloroethane ug/L 50.350 101 60-140
1,1,2-Trichloroethane ug/L 53.750 107 60-140
1,1-Dichloroethane ug/L 54.850 110 60-140
1,1-Dichloroethene ug/L 55.350 111 60-140
1,1-Dichloropropene ug/L 54.650 109 60-140
1,2,3-Trichlorobenzene ug/L 48.050 96 60-140
1,2,3-Trichloropropane ug/L 50.150 100 60-140
1,2,4-Trichlorobenzene ug/L 46.950 94 60-140
1,2,4-Trimethylbenzene ug/L 48.950 98 60-140
1,2-Dibromo-3-chloropropane ug/L 50.150 100 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 41 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2716934LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dibromoethane (EDB)ug/L 52.250 104 60-140
1,2-Dichlorobenzene ug/L 48.850 98 60-140
1,2-Dichloroethane ug/L 47.250 94 60-140
1,2-Dichloropropane ug/L 54.950 110 60-140
1,3,5-Trimethylbenzene ug/L 48.950 98 60-140
1,3-Dichlorobenzene ug/L 47.750 95 60-140
1,3-Dichloropropane ug/L 52.250 104 60-140
1,4-Dichlorobenzene ug/L 47.250 94 60-140
2,2-Dichloropropane ug/L 57.750 115 60-140
2-Chlorotoluene ug/L 48.750 97 60-140
4-Chlorotoluene ug/L 49.350 99 60-140
Benzene ug/L 56.150 112 60-140
Bromobenzene ug/L 49.350 99 60-140
Bromochloromethane ug/L 54.150 108 60-140
Bromodichloromethane ug/L 54.750 109 60-140
Bromoform ug/L 47.950 96 60-140
Bromomethane ug/L 52.450 105 60-140
Carbon tetrachloride ug/L 50.050 100 60-140
Chlorobenzene ug/L 48.250 96 60-140
Chloroethane ug/L 50.350 101 60-140
Chloroform ug/L 52.850 106 60-140
Chloromethane ug/L 46.050 92 60-140
cis-1,2-Dichloroethene ug/L 55.950 112 60-140
cis-1,3-Dichloropropene ug/L 58.750 117 60-140
Dibromochloromethane ug/L 49.850 100 60-140
Dibromomethane ug/L 54.850 110 60-140
Dichlorodifluoromethane ug/L 54.450 109 60-140
Diisopropyl ether ug/L 60.050 120 60-140
Ethanol ug/L 24402000 122 60-140
Ethyl-tert-butyl ether ug/L 110100 110 60-140
Ethylbenzene ug/L 49.750 99 60-140
Hexachloro-1,3-butadiene ug/L 46.150 92 60-140
Isopropylbenzene (Cumene)ug/L 50.050 100 60-140
m&p-Xylene ug/L 98.4100 98 60-140
Methyl-tert-butyl ether ug/L 56.650 113 60-140
Methylene Chloride ug/L 48.850 98 60-140
n-Butylbenzene ug/L 50.150 100 60-140
n-Propylbenzene ug/L 49.850 100 60-140
Naphthalene ug/L 49.050 98 60-140
o-Xylene ug/L 51.050 102 60-140
sec-Butylbenzene ug/L 51.050 102 60-140
Styrene ug/L 49.750 99 60-140
tert-Amyl Alcohol ug/L 11401000 114 60-140
tert-Amylmethyl ether ug/L 109100 109 60-140
tert-Butyl Alcohol ug/L 595500 119 60-140
tert-Butyl Formate ug/L 485400 121 60-140
tert-Butylbenzene ug/L 42.650 85 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 42 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2716934LABORATORY CONTROL SAMPLE:
LCSSpike
Tetrachloroethene ug/L 49.650 99 60-140
Toluene ug/L 51.850 104 60-140
trans-1,2-Dichloroethene ug/L 55.950 112 60-140
trans-1,3-Dichloropropene ug/L 54.450 109 60-140
Trichloroethene ug/L 53.350 107 60-140
Trichlorofluoromethane ug/L 50.950 102 60-140
Vinyl chloride ug/L 57.450 115 60-140
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%103 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2716935MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92450348001
2716936
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 250 107 60-140105 2 30250ND267261
1,1,1-Trichloroethane ug/L 250 110 60-140108 1 30250ND274271
1,1,2,2-Tetrachloroethane ug/L 250 107 60-140108 1 30250ND268270
1,1,2-Trichloroethane ug/L 250 117 60-140112 5 30250ND293279
1,1-Dichloroethane ug/L 250 118 60-140115 2 30250ND294287
1,1-Dichloroethene ug/L 250 114 60-140111 3 30250ND285277
1,1-Dichloropropene ug/L 250 116 60-140114 2 30250ND290284
1,2,3-Trichlorobenzene ug/L 250 93 60-14098 6 30250ND232246
1,2,3-Trichloropropane ug/L 250 106 60-140108 1 30250ND265269
1,2,4-Trichlorobenzene ug/L 250 96 60-14095 1 30250ND240239
1,2,4-Trimethylbenzene ug/L 250 103 60-14097 3 30250216474458
1,2-Dibromo-3-chloropropane ug/L 250 100 60-140102 3 30250ND249256
1,2-Dibromoethane (EDB)ug/L 250 107 60-140107 1 30250ND266269
1,2-Dichlorobenzene ug/L 250 103 60-140102 1 30250ND257254
1,2-Dichloroethane ug/L 250 102 60-14099 3 30250ND255246
1,2-Dichloropropane ug/L 250 120 60-140115 5 30250ND300286
1,3,5-Trimethylbenzene ug/L 250 129 60-140124 3 30250ND322311
1,3-Dichlorobenzene ug/L 250 102 60-140100 2 30250ND255250
1,3-Dichloropropane ug/L 250 111 60-140111 0 30250ND278277
1,4-Dichlorobenzene ug/L 250 100 60-14098 3 30250ND251244
2,2-Dichloropropane ug/L 250 119 60-140117 2 30250ND297292
2-Chlorotoluene ug/L 250 112 60-140102 9 30250ND279254
4-Chlorotoluene ug/L 250 107 60-140102 4 30250ND266256
Benzene ug/L 250 121 60-140114 4 30250153456438
Bromobenzene ug/L 250 104 60-140101 2 30250ND259253
Bromochloromethane ug/L 250 114 60-140111 3 30250ND285276
Bromodichloromethane ug/L 250 119 60-140111 7 30250ND297277
Bromoform ug/L 250 106 60-140102 4 30250ND265255
Bromomethane ug/L 250 84 60-14085 2 30250ND210214
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 43 of 49
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2716935MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92450348001
2716936
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Carbon tetrachloride ug/L 250 106 60-140103 4 30250ND266256
Chlorobenzene ug/L 250 105 60-140103 2 30250ND263259
Chloroethane ug/L 250 108 60-140106 2 30250ND270264
Chloroform ug/L 250 117 60-140111 5 30250ND294279
Chloromethane ug/L 250 89 60-14088 2 30250ND223219
cis-1,2-Dichloroethene ug/L 250 118 60-140114 4 30250ND296285
cis-1,3-Dichloropropene ug/L 250 128 60-140119 6 30250ND319299
Dibromochloromethane ug/L 250 106 60-140104 2 30250ND265261
Dibromomethane ug/L 250 111 60-140110 1 30250ND277274
Dichlorodifluoromethane ug/L 250 88 60-14087 1 30250ND220217
Diisopropyl ether ug/L 250 122 60-140118 4 30250ND307296
Ethanol ug/L 3 301510015600
Ethyl-tert-butyl ether ug/L 1 30552548
Ethylbenzene ug/L 250 109 60-140105 2 30250173445435
Hexachloro-1,3-butadiene ug/L 250 96 60-14093 3 30250ND239233
Isopropylbenzene
(Cumene)ug/L 250 113 60-140110 2 30250ND281275
m&p-Xylene ug/L 500 109 60-140105 2 3050065212001180
Methyl-tert-butyl ether ug/L 250 113 60-140110 3 30250ND283274
Methylene Chloride ug/L 250 106 60-140101 5 30250ND266252
n-Butylbenzene ug/L 250 109 60-140107 2 30250ND272268
n-Propylbenzene ug/L 250 111 60-140109 2 30250ND278272
Naphthalene ug/L 250 97 60-140107 3 30250459702726
o-Xylene ug/L 250 114 60-140109 2 30250410696682
sec-Butylbenzene ug/L 250 110 60-140108 2 30250ND276270
Styrene ug/L 250 112 60-140109 2 30250ND279272
tert-Amyl Alcohol ug/L 0 3062506250
tert-Amylmethyl ether ug/L 3 30546532
tert-Butyl Alcohol ug/L 4 3031703290
tert-Butyl Formate ug/L 2 3021502100
tert-Butylbenzene ug/L 250 92 60-14090 2 30250ND231225
Tetrachloroethene ug/L 250 108 60-140103 5 30250ND269257
Toluene ug/L 250 115 60-14099 3 30250117014601420
trans-1,2-Dichloroethene ug/L 250 116 60-140114 2 30250ND290284
trans-1,3-Dichloropropene ug/L 250 117 60-140114 3 30250ND293284
Trichloroethene ug/L 250 114 60-140109 5 30250ND284272
Trichlorofluoromethane ug/L 250 107 60-140101 5 30250ND267254
Vinyl chloride ug/L 250 113 60-140108 5 30250ND283269
1,2-Dichloroethane-d4 (S)%96 70-13096
4-Bromofluorobenzene (S)%101 70-130101
Toluene-d8 (S)%103 70-130101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 44 of 49
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.L1
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 45 of 49
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92450350
GUNTHER'S GROCERY-Revised Report
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92450350001 505583MW-1 SM 6200B
92450350002 505333MW-2 SM 6200B
92450350003 505770MW-4 SM 6200B
92450350004 505770MW-5 SM 6200B
92450350005 505770MW-6 SM 6200B
92450350006 505532MW-7 SM 6200B
92450350007 505532WSW-1 SM 6200B
92450350008 505532WSW-2A SM 6200B
92450350009 505527FBSM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/06/2020 09:06 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 46 of 49
Page 47 of 49
Page 48 of 49
Page 49 of 49