12033_North Tryon Site_February 2020_GW Sampling Report

Terracon Consultants, Inc.2701 Westport Road Charlotte,NC 28208
P 704-509-1777 F 704-509-1888 terracon.com
February 14, 2020
Mr. Matthew Browder
Summit Avenue Northend, LLC
1440 South Tryon Street, Suite 104
Charlotte, North Carolina 28203
P: 704-335-8292
E:[e-mail]
Re: Report of Groundwater Sampling Activities
North Tryon Commercial Brownfields (NCBP #12033-08-060)
2100-2229 North Tryon Street
Charlotte, Mecklenburg County, North Carolina
Terracon Project No. 71177699
Dear Mr. Browder:
Terracon Consultants, Inc. (Terracon) is pleased to submit this report of groundwater sampling
activities conducted at the North Tryon Commercial Brownfields Property located at 2100-2229
North Tryon Street in Charlotte, North Carolina. Terracon conducted the investigation in general
accordance with our Proposal (P71207015), dated January 13, 2020.
The North Tryon Commercial Brownfields Property includes an approximate 0.23-acre partially
paved vacant lot, identified in Mecklenburg County tax records as Parcel No. 07909304 (Figure
1). According to previous assessment activities associated with the Brownfields investigation, a
gasoline station and dry-cleaning facility previously operated on the subject parcel from the 1940s
until the 1970s. Site assessment activities conducted at the property have indicated the presence
of volatile organic compounds (VOCs) in soils, soil gas and groundwater. In accordance with
Paragraph 13.d. of the Brownfields Agreement (BFA), the monitoring well located on the site must
be sampled annually for five consecutive years, at which time a request to terminate sampling
may be submitted to DEQ. Groundwater sampling has been conducted since December 10, 2013.
The Prospective Developer (PD) received an extension from the Brownfields Program until
February 15, 2020 for the submittal for the annual groundwater monitoring results. Terracon
mobilized to the site on January 27, 2020 to conduct groundwater sampling activities. A
groundwater sample was collected from monitoring well MW-1 using a peristaltic pump and low-
flow techniques and clean, new polyethylene tubing. Prior to sample collection, field parameter
readings of pH, oxidation reduction potential (ORP), specific conductivity, dissolved oxygen, and
temperature were recorded on a groundwater sampling log that is included in Appendix A. The
water sample was collected after field parameters stabilized within a ten percent variation for three
consecutive readings at five minute intervals. The sample was placed in clean glassware, labeled,
packed in an ice-filled cooler and transported with chain-of-custody documentation to Pace
Analytical (Pace) in Huntersville, North Carolina for laboratory analysis.
Figures

Site Location Map
North Tryon Site
2229 North Tryon Street
Charlotte, Mecklenburg County, NC
TOPOGRAPHIC MAP IMAGE COURTESY OF THE U.S. GEOLOGICAL SURVEY
QUADRANGLES INCLUDE: DERITA, NC (1/1/1993) and CHARLOTTE EAST, NC (1/1/1988).
2701 Westport Road
Charlotte, NC 28208
71177699
Project Manager:
Drawn by:
Checked by:
Approved by:
HEH
CLC
CLC
1”=2,000’
71177699
January 2018
Project No.
Scale:
File Name:
Date: 1
Figure HEH
APPROXIMATE
SITE BOUNDARY
71177699.2
Groundwater Analytical Results (January 2020)
North Tryon Site
2229 North Tryon Street
Charlotte, Mecklenburg County, NC
2701 Westport Road
Charlotte, NC
711777699
FJD
CLC
CLC
N.T.S.
January 2020
Scale:
2
FigureProject Manager:
Drawn by:
Checked by:
Approved by:
Project No.
File Name:
Date:
FJD
denotes approximate site boundary
approximate location of groundwater
monitoring well
GRAVEL
MW-1
Sample ID: MW-1
Groundwater Sample
8260 –cis-1,2-Dichloroethene: 27.4 µg/L
Tetrachloroethene: 1,380 µg/L
Trichloroethene: 22.3 µg/L
*Values above 2L Standards and non-
residential GWSL are in bold.
Table
Table 1
Groundwater Analytical Results
North Tryon Site
2229 North Tryon Street
Charlotte, Mecklenburg County, North Carolina
Terracon Project No. 71177699
Sample ID:Sample Interval
(ft bgs):
Sample Date: 12/10/2013*12/18/2014*7/11/2016*01/23/2019
Chloroform 70 8.1 36 ND <1 <5 <11.7
cis-1,2-Dichloroethene 70 NS NS 141 82.1 52.0 30.5
trans-1,2-Dichloroethene 100 NS NS <1.0 <1.0 20.0 <5
Tetrachloroethene 0.7 12 48 2,280 1,190 1,500 766
Toluene 600 3,800 16,000 ND <1 <5 2.9J
Trichloroethene 3 1 4.4 87.3 48.2 37 16.7
Notes:
Only detected compounds are shown.
Concentrations are reported in micrograms per liter (μg/L).
* = Labortory data obtained from Hart & Hickman Groundwater Monitoring Reports
2L Standard - North Carolina Administrative Code Subchapter 2L Groundwater Quality Standards (April 1, 2013).
Concentrations highlighted in gray exceed their respective 2L Standard
Concentrations highlighted in orange exceed their respective Non-Residential GWSL.
ND - Not Detected
NS - No Standard
Residential GWSL - NCDEQ Division of Waste Management Residential Vapor Intrusion Screening Concentrations - Health-Based Ground Water Screening Levels,
updated February 2018.
Non-Residential GWSL - NCDEQ Division of Waste Management Non-Residential Vapor Intrusion Screening Concentrations - Health-Based Ground Water Screening
Levels, updated February 2018.
MW-1
25-30
No contaminants detected above the laboratory reporting limit or NCAC 2L GWQS
Analyte 2L Standard
01/05/2018
Residential
GWSL
Non-Residential
GWSL 12/14/2016
<5
34.5
570
20.1
0.77J
1,380
22.3
<1.0
Semi-Volatile Organic Compounds (EPA Method 8270)
Volatile Organic Compounds (EPA Method 8260)
33.3
596
17.8
<5 <1.3
<5
01/27/2020
<2.3
27.4
<1<5
Appendix A
Appendix B
#=CL#
February 07, 2020
LIMS USE: FR - JC WEAVER
LIMS OBJECT ID: 92462652
92462652
Project:
Pace Project No.:
RE:
JC Weaver
Terracon NC
2701 Westport Road
Charlotte, NC 28208
71177699
Dear JC Weaver:
Enclosed are the analytical results for sample(s) received by the laboratory on January 28, 2020.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Taylor Ezell
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 22
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92462652
71177699
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 22
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92462652
71177699
Lab ID Sample ID Matrix Date Collected Date Received
92462652001 MW-1 Water 01/27/20 15:15 01/28/20 07:25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 22
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92462652
71177699
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92462652001 MW-1 EPA 8270E 74 PASI-CPKS
EPA 8260D 62 PASI-CSAS
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 22
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92462652
71177699
Sample:MW-1 Lab ID:92462652001 Collected:01/27/20 15:15 Received:01/28/20 07:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3510C8270E RVE
Acenaphthene ND ug/L 02/03/20 19:25 83-32-902/03/20 12:1610.0 1.4 1
Acenaphthylene ND ug/L 02/03/20 19:25 208-96-802/03/20 12:1610.0 1.5 1
Aniline ND ug/L 02/03/20 19:25 62-53-302/03/20 12:1610.0 1.6 1
Anthracene ND ug/L 02/03/20 19:25 120-12-702/03/20 12:1610.0 1.6 1
Benzo(a)anthracene ND ug/L 02/03/20 19:25 56-55-302/03/20 12:1610.0 1.5 1
Benzo(a)pyrene ND ug/L 02/03/20 19:25 50-32-802/03/20 12:1610.0 1.8 1
Benzo(b)fluoranthene ND ug/L 02/03/20 19:25 205-99-202/03/20 12:1610.0 1.7 1
Benzo(g,h,i)perylene ND ug/L 02/03/20 19:25 191-24-202/03/20 12:1610.0 1.6 1
Benzo(k)fluoranthene ND ug/L 02/03/20 19:25 207-08-902/03/20 12:1610.0 1.5 1
Benzoic Acid ND ug/L 02/03/20 19:25 65-85-002/03/20 12:1650.0 19.5 1
Benzyl alcohol ND ug/L 02/03/20 19:25 100-51-602/03/20 12:1620.0 2.6 1
4-Bromophenylphenyl ether ND ug/L 02/03/20 19:25 101-55-302/03/20 12:1610.0 1.2 1
Butylbenzylphthalate ND ug/L 02/03/20 19:25 85-68-702/03/20 12:1610.0 1.9 1
4-Chloro-3-methylphenol ND ug/L 02/03/20 19:25 59-50-702/03/20 12:1610.0 2.8 1
4-Chloroaniline ND ug/L 02/03/20 19:25 106-47-802/03/20 12:1620.0 2.8 1
bis(2-Chloroethoxy)methane ND ug/L 02/03/20 19:25 111-91-102/03/20 12:1610.0 1.3 1
bis(2-Chloroethyl) ether ND ug/L 02/03/20 19:25 111-44-402/03/20 12:1610.0 1.7 1
2-Chloronaphthalene ND ug/L 02/03/20 19:25 91-58-702/03/20 12:1610.0 1.4 1
2-Chlorophenol ND ug/L 02/03/20 19:25 95-57-802/03/20 12:1610.0 1.4 1
4-Chlorophenylphenyl ether ND ug/L 02/03/20 19:25 7005-72-302/03/20 12:1610.0 1.5 1
Chrysene ND ug/L 02/03/20 19:25 218-01-902/03/20 12:1610.0 1.4 1
Dibenz(a,h)anthracene ND ug/L 02/03/20 19:25 53-70-302/03/20 12:1610.0 1.6 1
Dibenzofuran ND ug/L 02/03/20 19:25 132-64-902/03/20 12:1610.0 1.3 1
1,2-Dichlorobenzene ND ug/L 02/03/20 19:25 95-50-102/03/20 12:1610.0 1.4 1
1,3-Dichlorobenzene ND ug/L 02/03/20 19:25 541-73-102/03/20 12:1610.0 1.4 1
1,4-Dichlorobenzene ND ug/L 02/03/20 19:25 106-46-702/03/20 12:1610.0 1.5 1
3,3'-Dichlorobenzidine ND ug/L 02/03/20 19:25 91-94-102/03/20 12:1620.0 2.7 1
2,4-Dichlorophenol ND ug/L 02/03/20 19:25 120-83-202/03/20 12:1610.0 1.5 1
Diethylphthalate ND ug/L 02/03/20 19:25 84-66-202/03/20 12:1610.0 1.6 1
2,4-Dimethylphenol ND ug/L 02/03/20 19:25 105-67-902/03/20 12:1610.0 1.5 1
Dimethylphthalate ND ug/L 02/03/20 19:25 131-11-302/03/20 12:1610.0 1.4 1
Di-n-butylphthalate ND ug/L 02/03/20 19:25 84-74-202/03/20 12:1610.0 1.6 1
4,6-Dinitro-2-methylphenol ND ug/L 02/03/20 19:25 534-52-102/03/20 12:1620.0 4.5 1
2,4-Dinitrophenol ND ug/L 02/03/20 19:25 51-28-502/03/20 12:1650.0 7.3 1
2,4-Dinitrotoluene ND ug/L 02/03/20 19:25 121-14-202/03/20 12:1610.0 1.7 1
2,6-Dinitrotoluene ND ug/L 02/03/20 19:25 606-20-202/03/20 12:1610.0 1.7 1
Di-n-octylphthalate ND ug/L 02/03/20 19:25 117-84-002/03/20 12:1610.0 2.2 1
bis(2-Ethylhexyl)phthalate ND ug/L 02/03/20 19:25 117-81-702/03/20 12:166.0 2.0 1
Fluoranthene ND ug/L 02/03/20 19:25 206-44-002/03/20 12:1610.0 1.6 1
Fluorene ND ug/L 02/03/20 19:25 86-73-702/03/20 12:1610.0 1.4 1
Hexachloro-1,3-butadiene ND ug/L 02/03/20 19:25 87-68-302/03/20 12:1610.0 1.6 1
Hexachlorobenzene ND ug/L 02/03/20 19:25 118-74-102/03/20 12:1610.0 1.3 1
Hexachlorocyclopentadiene ND ug/L 02/03/20 19:25 77-47-402/03/20 12:1610.0 2.4 1
Hexachloroethane ND ug/L 02/03/20 19:25 67-72-102/03/20 12:1610.0 1.3 1
Indeno(1,2,3-cd)pyrene ND ug/L 02/03/20 19:25 193-39-502/03/20 12:1610.0 1.7 1
Isophorone ND ug/L 02/03/20 19:25 78-59-102/03/20 12:1610.0 1.3 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/07/2020 03:59 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 22
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92462652
71177699
Sample:MW-1 Lab ID:92462652001 Collected:01/27/20 15:15 Received:01/28/20 07:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3510C8270E RVE
1-Methylnaphthalene ND ug/L 02/03/20 19:25 90-12-002/03/20 12:1610.0 1.4 1
2-Methylnaphthalene ND ug/L 02/03/20 19:25 91-57-602/03/20 12:1610.0 1.4 1
2-Methylphenol(o-Cresol)ND ug/L 02/03/20 19:25 95-48-702/03/20 12:1610.0 1.2 1
3&4-Methylphenol(m&p Cresol)ND ug/L 02/03/20 19:25 15831-10-402/03/20 12:1610.0 1.2 1
Naphthalene ND ug/L 02/03/20 19:25 91-20-302/03/20 12:1610.0 1.6 1
2-Nitroaniline ND ug/L 02/03/20 19:25 88-74-402/03/20 12:1620.0 3.0 1
3-Nitroaniline ND ug/L 02/03/20 19:25 99-09-202/03/20 12:1620.0 2.8 1
4-Nitroaniline ND ug/L 02/03/20 19:25 100-01-602/03/20 12:1620.0 3.1 1
Nitrobenzene ND ug/L 02/03/20 19:25 98-95-302/03/20 12:1610.0 1.5 1
2-Nitrophenol ND ug/L 02/03/20 19:25 88-75-502/03/20 12:1610.0 1.7 1
4-Nitrophenol ND ug/L 02/03/20 19:25 100-02-702/03/20 12:1650.0 9.4 1
N-Nitrosodimethylamine ND ug/L 02/03/20 19:25 62-75-902/03/20 12:1610.0 1.8 1
N-Nitroso-di-n-propylamine ND ug/L 02/03/20 19:25 621-64-702/03/20 12:1610.0 1.3 1
N-Nitrosodiphenylamine ND ug/L 02/03/20 19:25 86-30-602/03/20 12:1610.0 1.4 1
2,2'-Oxybis(1-chloropropane)ND ug/L 02/03/20 19:25 108-60-102/03/20 12:1610.0 1.3 1
Pentachlorophenol ND ug/L 02/03/20 19:25 87-86-502/03/20 12:1620.0 2.8 1
Phenanthrene ND ug/L 02/03/20 19:25 85-01-802/03/20 12:1610.0 1.4 1
Phenol ND ug/L 02/03/20 19:25 108-95-202/03/20 12:1610.0 1.5 1
Pyrene ND ug/L 02/03/20 19:25 129-00-002/03/20 12:1610.0 1.5 1
1,2,4-Trichlorobenzene ND ug/L 02/03/20 19:25 120-82-102/03/20 12:1610.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 02/03/20 19:25 95-95-402/03/20 12:1610.0 1.5 1
2,4,6-Trichlorophenol ND ug/L 02/03/20 19:25 88-06-202/03/20 12:1610.0 1.4 1
Surrogates
Nitrobenzene-d5 (S)62 %02/03/20 19:25 4165-60-002/03/20 12:1613-130 1
2-Fluorobiphenyl (S)56 %02/03/20 19:25 321-60-802/03/20 12:1613-130 1
Terphenyl-d14 (S)58 %02/03/20 19:25 1718-51-002/03/20 12:1625-130 1
Phenol-d6 (S)43 %02/03/20 19:25 13127-88-302/03/20 12:1610-130 1
2-Fluorophenol (S)52 %02/03/20 19:25 367-12-402/03/20 12:1610-130 1
2,4,6-Tribromophenol (S)54 %02/03/20 19:25 118-79-602/03/20 12:1610-137 1
Analytical Method: EPA 8260D8260D MSV Low Level
Acetone ND ug/L 01/30/20 02:06 67-64-125.0 6.2 1
Benzene ND ug/L 01/30/20 02:06 71-43-21.0 0.15 1
Bromobenzene ND ug/L 01/30/20 02:06 108-86-11.0 0.22 1
Bromochloromethane ND ug/L 01/30/20 02:06 74-97-51.0 0.34 1
Bromodichloromethane ND ug/L 01/30/20 02:06 75-27-41.0 0.26 1
Bromoform ND ug/L 01/30/20 02:06 75-25-21.0 0.62 1
Bromomethane ND ug/L 01/30/20 02:06 74-83-92.0 0.62 1
2-Butanone (MEK)ND ug/L 01/30/20 02:06 78-93-35.0 3.3 1
Carbon tetrachloride ND ug/L 01/30/20 02:06 56-23-51.0 0.22 1
Chlorobenzene ND ug/L 01/30/20 02:06 108-90-71.0 0.23 1
Chloroethane ND ug/L 01/30/20 02:06 75-00-31.0 0.49 1
Chloroform ND ug/L 01/30/20 02:06 67-66-35.0 2.3 1
Chloromethane ND ug/L 01/30/20 02:06 74-87-31.0 0.39 1
2-Chlorotoluene ND ug/L 01/30/20 02:06 95-49-81.0 0.20 1
4-Chlorotoluene ND ug/L 01/30/20 02:06 106-43-41.0 0.20 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/07/2020 03:59 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 22
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92462652
71177699
Sample:MW-1 Lab ID:92462652001 Collected:01/27/20 15:15 Received:01/28/20 07:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D8260D MSV Low Level
1,2-Dibromo-3-chloropropane ND ug/L 01/30/20 02:06 96-12-85.0 0.26 1
Dibromochloromethane ND ug/L 01/30/20 02:06 124-48-11.0 0.41 1
1,2-Dibromoethane (EDB)ND ug/L 01/30/20 02:06 106-93-41.0 0.26 1
Dibromomethane ND ug/L 01/30/20 02:06 74-95-31.0 0.46 1
1,2-Dichlorobenzene ND ug/L 01/30/20 02:06 95-50-11.0 0.29 1
1,3-Dichlorobenzene ND ug/L 01/30/20 02:06 541-73-11.0 0.22 1
1,4-Dichlorobenzene ND ug/L 01/30/20 02:06 106-46-71.0 0.26 1
Dichlorodifluoromethane ND ug/L 01/30/20 02:06 75-71-81.0 0.23 1
1,1-Dichloroethane ND ug/L 01/30/20 02:06 75-34-31.0 0.27 1
1,2-Dichloroethane ND ug/L 01/30/20 02:06 107-06-21.0 0.34 1
1,1-Dichloroethene ND ug/L 01/30/20 02:06 75-35-41.0 0.24 1
cis-1,2-Dichloroethene 27.4 ug/L 01/30/20 02:06 156-59-21.0 0.29 1
trans-1,2-Dichloroethene ND ug/L 01/30/20 02:06 156-60-51.0 0.25 1
1,2-Dichloropropane ND ug/L 01/30/20 02:06 78-87-51.0 0.19 1
1,3-Dichloropropane ND ug/L 01/30/20 02:06 142-28-91.0 0.16 1
2,2-Dichloropropane ND ug/L 01/30/20 02:06 594-20-71.0 0.27 1
1,1-Dichloropropene ND ug/L 01/30/20 02:06 563-58-61.0 0.21 1
cis-1,3-Dichloropropene ND ug/L 01/30/20 02:06 10061-01-51.0 0.30 1
trans-1,3-Dichloropropene ND ug/L 01/30/20 02:06 10061-02-61.0 0.31 1
Diisopropyl ether ND ug/L 01/30/20 02:06 108-20-31.0 0.22 1
Ethylbenzene ND ug/L 01/30/20 02:06 100-41-41.0 0.26 1
Hexachloro-1,3-butadiene ND ug/L 01/30/20 02:06 87-68-31.0 0.44 1
2-Hexanone ND ug/L 01/30/20 02:06 591-78-65.0 0.57 1
p-Isopropyltoluene ND ug/L 01/30/20 02:06 99-87-61.0 0.21 1
Methylene Chloride ND ug/L 01/30/20 02:06 75-09-25.0 3.7 1
4-Methyl-2-pentanone (MIBK)ND ug/L 01/30/20 02:06 108-10-15.0 4.5 1
Methyl-tert-butyl ether ND ug/L 01/30/20 02:06 1634-04-41.0 0.28 1
Naphthalene ND ug/L 01/30/20 02:06 91-20-31.0 0.35 1
Styrene ND ug/L 01/30/20 02:06 100-42-51.0 0.27 1
1,1,1,2-Tetrachloroethane ND ug/L 01/30/20 02:06 630-20-61.0 0.34 1
1,1,2,2-Tetrachloroethane ND ug/L 01/30/20 02:06 79-34-51.0 0.22 1
Tetrachloroethene 1380 ug/L 01/30/20 02:06 127-18-41.0 0.16 1
Toluene ND ug/L 01/30/20 02:06 108-88-31.0 0.24 1
1,2,3-Trichlorobenzene ND ug/L 01/30/20 02:06 87-61-61.0 0.34 1
1,2,4-Trichlorobenzene ND ug/L 01/30/20 02:06 120-82-11.0 0.22 1
1,1,1-Trichloroethane ND ug/L 01/30/20 02:06 71-55-61.0 0.18 1
1,1,2-Trichloroethane ND ug/L 01/30/20 02:06 79-00-51.0 0.24 1
Trichloroethene 22.3 ug/L 01/30/20 02:06 79-01-61.0 0.22 1
Trichlorofluoromethane ND ug/L 01/30/20 02:06 75-69-41.0 0.31 1
1,2,3-Trichloropropane ND ug/L 01/30/20 02:06 96-18-41.0 0.35 1
Vinyl acetate ND ug/L 01/30/20 02:06 108-05-42.0 1.4 1
Vinyl chloride ND ug/L 01/30/20 02:06 75-01-41.0 0.24 1
m&p-Xylene ND ug/L 01/30/20 02:06 179601-23-12.0 0.41 1
o-Xylene ND ug/L 01/30/20 02:06 95-47-61.0 0.22 1
Surrogates
4-Bromofluorobenzene (S)100 %01/30/20 02:06 460-00-470-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/07/2020 03:59 PM
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Page 7 of 22
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92462652
71177699
Sample:MW-1 Lab ID:92462652001 Collected:01/27/20 15:15 Received:01/28/20 07:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D8260D MSV Low Level
Surrogates
1,2-Dichloroethane-d4 (S)82 %01/30/20 02:06 17060-07-070-130 1
Toluene-d8 (S)90 %01/30/20 02:06 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/07/2020 03:59 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92462652
71177699
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
522130
EPA 8260D
EPA 8260D
8260D MSV Low Level
Associated Lab Samples:92462652001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2792761
Associated Lab Samples:92462652001
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 1.0 01/29/20 22:500.34
1,1,1-Trichloroethane ug/L ND 1.0 01/29/20 22:500.18
1,1,2,2-Tetrachloroethane ug/L ND 1.0 01/29/20 22:500.22
1,1,2-Trichloroethane ug/L ND 1.0 01/29/20 22:500.24
1,1-Dichloroethane ug/L ND 1.0 01/29/20 22:500.27
1,1-Dichloroethene ug/L ND 1.0 01/29/20 22:500.24
1,1-Dichloropropene ug/L ND 1.0 01/29/20 22:500.21
1,2,3-Trichlorobenzene ug/L ND 1.0 01/29/20 22:500.34
1,2,3-Trichloropropane ug/L ND 1.0 01/29/20 22:500.35
1,2,4-Trichlorobenzene ug/L ND 1.0 01/29/20 22:500.22
1,2-Dibromo-3-chloropropane ug/L ND 5.0 01/29/20 22:500.26
1,2-Dibromoethane (EDB)ug/L ND 1.0 01/29/20 22:500.26
1,2-Dichlorobenzene ug/L ND 1.0 01/29/20 22:500.29
1,2-Dichloroethane ug/L ND 1.0 01/29/20 22:500.34
1,2-Dichloropropane ug/L ND 1.0 01/29/20 22:500.19
1,3-Dichlorobenzene ug/L ND 1.0 01/29/20 22:500.22
1,3-Dichloropropane ug/L ND 1.0 01/29/20 22:500.16
1,4-Dichlorobenzene ug/L ND 1.0 01/29/20 22:500.26
2,2-Dichloropropane ug/L ND 1.0 01/29/20 22:500.27
2-Butanone (MEK)ug/L ND 5.0 01/29/20 22:503.3
2-Chlorotoluene ug/L ND 1.0 01/29/20 22:500.20
2-Hexanone ug/L ND 5.0 01/29/20 22:500.57
4-Chlorotoluene ug/L ND 1.0 01/29/20 22:500.20
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 01/29/20 22:504.5
Acetone ug/L ND 25.0 01/29/20 22:506.2
Benzene ug/L ND 1.0 01/29/20 22:500.15
Bromobenzene ug/L ND 1.0 01/29/20 22:500.22
Bromochloromethane ug/L ND 1.0 01/29/20 22:500.34
Bromodichloromethane ug/L ND 1.0 01/29/20 22:500.26
Bromoform ug/L ND 1.0 01/29/20 22:500.62
Bromomethane ug/L ND 2.0 IK01/29/20 22:500.62
Carbon tetrachloride ug/L ND 1.0 01/29/20 22:500.22
Chlorobenzene ug/L ND 1.0 01/29/20 22:500.23
Chloroethane ug/L ND 1.0 01/29/20 22:500.49
Chloroform ug/L ND 5.0 01/29/20 22:502.3
Chloromethane ug/L ND 1.0 01/29/20 22:500.39
cis-1,2-Dichloroethene ug/L ND 1.0 01/29/20 22:500.29
cis-1,3-Dichloropropene ug/L ND 1.0 01/29/20 22:500.30
Dibromochloromethane ug/L ND 1.0 01/29/20 22:500.41
Dibromomethane ug/L ND 1.0 01/29/20 22:500.46
Dichlorodifluoromethane ug/L ND 1.0 01/29/20 22:500.23
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/07/2020 03:59 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92462652
71177699
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2792761
Associated Lab Samples:92462652001
Matrix:Water
AnalyzedMDL
Diisopropyl ether ug/L ND 1.0 01/29/20 22:500.22
Ethylbenzene ug/L ND 1.0 01/29/20 22:500.26
Hexachloro-1,3-butadiene ug/L ND 1.0 01/29/20 22:500.44
m&p-Xylene ug/L ND 2.0 01/29/20 22:500.41
Methyl-tert-butyl ether ug/L ND 1.0 01/29/20 22:500.28
Methylene Chloride ug/L ND 5.0 01/29/20 22:503.7
Naphthalene ug/L ND 1.0 01/29/20 22:500.35
o-Xylene ug/L ND 1.0 01/29/20 22:500.22
p-Isopropyltoluene ug/L ND 1.0 01/29/20 22:500.21
Styrene ug/L ND 1.0 01/29/20 22:500.27
Tetrachloroethene ug/L ND 1.0 01/29/20 22:500.16
Toluene ug/L ND 1.0 01/29/20 22:500.24
trans-1,2-Dichloroethene ug/L ND 1.0 01/29/20 22:500.25
trans-1,3-Dichloropropene ug/L ND 1.0 01/29/20 22:500.31
Trichloroethene ug/L ND 1.0 01/29/20 22:500.22
Trichlorofluoromethane ug/L ND 1.0 01/29/20 22:500.31
Vinyl acetate ug/L ND 2.0 IK01/29/20 22:501.4
Vinyl chloride ug/L ND 1.0 01/29/20 22:500.24
1,2-Dichloroethane-d4 (S)%84 70-130 01/29/20 22:50
4-Bromofluorobenzene (S)%100 70-130 01/29/20 22:50
Toluene-d8 (S)%101 70-130 01/29/20 22:50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2792762LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 54.450 109 70-130
1,1,1-Trichloroethane ug/L 52.350 105 70-130
1,1,2,2-Tetrachloroethane ug/L 50.750 101 70-130
1,1,2-Trichloroethane ug/L 53.750 107 70-130
1,1-Dichloroethane ug/L 50.750 101 70-130
1,1-Dichloroethene ug/L 50.750 101 70-130
1,1-Dichloropropene ug/L 58.550 117 70-130
1,2,3-Trichlorobenzene ug/L 54.650 109 70-130
1,2,3-Trichloropropane ug/L 50.150 100 70-130
1,2,4-Trichlorobenzene ug/L 54.850 110 70-130
1,2-Dibromo-3-chloropropane ug/L 51.250 102 70-130
1,2-Dibromoethane (EDB)ug/L 54.850 110 70-130
1,2-Dichlorobenzene ug/L 54.950 110 70-130
1,2-Dichloroethane ug/L 47.250 94 70-130
1,2-Dichloropropane ug/L 53.650 107 70-130
1,3-Dichlorobenzene ug/L 54.850 110 70-130
1,3-Dichloropropane ug/L 56.350 113 70-131
1,4-Dichlorobenzene ug/L 53.850 108 70-130
2,2-Dichloropropane ug/L 48.850 98 69-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/07/2020 03:59 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92462652
71177699
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2792762LABORATORY CONTROL SAMPLE:
LCSSpike
2-Butanone (MEK)ug/L 93.7100 94 64-135
2-Chlorotoluene ug/L 55.850 112 70-130
2-Hexanone ug/L 91.9100 92 66-135
4-Chlorotoluene ug/L 53.750 107 70-130
4-Methyl-2-pentanone (MIBK)ug/L 96.5100 97 70-130
Acetone ug/L 108100 108 61-157
Benzene ug/L 54.750 109 70-130
Bromobenzene ug/L 57.850 116 70-130
Bromochloromethane ug/L 53.550 107 70-130
Bromodichloromethane ug/L 48.950 98 70-130
Bromoform ug/L 48.150 96 70-130
Bromomethane ug/L 53.9 IK5010838-130
Carbon tetrachloride ug/L 51.150 102 70-130
Chlorobenzene ug/L 52.950 106 70-130
Chloroethane ug/L 35.650 71 37-142
Chloroform ug/L 52.150 104 70-130
Chloromethane ug/L 39.750 79 48-130
cis-1,2-Dichloroethene ug/L 50.250 100 70-130
cis-1,3-Dichloropropene ug/L 54.150 108 70-130
Dibromochloromethane ug/L 52.050 104 70-130
Dibromomethane ug/L 53.450 107 70-130
Dichlorodifluoromethane ug/L 48.850 98 53-134
Diisopropyl ether ug/L 51.950 104 70-135
Ethylbenzene ug/L 51.250 102 70-130
Hexachloro-1,3-butadiene ug/L 52.950 106 68-132
m&p-Xylene ug/L 104100 104 70-130
Methyl-tert-butyl ether ug/L 56.450 113 70-130
Methylene Chloride ug/L 46.750 93 67-132
Naphthalene ug/L 51.650 103 70-130
o-Xylene ug/L 52.850 106 70-131
p-Isopropyltoluene ug/L 53.450 107 70-130
Styrene ug/L 52.150 104 70-130
Tetrachloroethene ug/L 55.450 111 69-130
Toluene ug/L 50.950 102 70-130
trans-1,2-Dichloroethene ug/L 51.550 103 70-130
trans-1,3-Dichloropropene ug/L 51.350 103 70-130
Trichloroethene ug/L 57.650 115 70-130
Trichlorofluoromethane ug/L 44.450 89 63-130
Vinyl acetate ug/L 97.6 IK1009855-143
Vinyl chloride ug/L 46.550 93 70-131
1,2-Dichloroethane-d4 (S)%86 70-130
4-Bromofluorobenzene (S)%96 70-130
Toluene-d8 (S)%96 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/07/2020 03:59 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92462652
71177699
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2793295MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35526205008
2793296
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 103 73-134108 5 30200.34U 20.6 21.7
1,1,1-Trichloroethane ug/L 20 108 82-143110 2 30200.18U 21.6 22.0
1,1,2,2-Tetrachloroethane ug/L 20 104 70-136107 3 30200.22U 20.8 21.5
1,1,2-Trichloroethane ug/L 20 109 70-135112 2 30200.24U 21.8 22.3
1,1-Dichloroethane ug/L 20 105 70-139107 2 30200.27U 21.0 21.4
1,1-Dichloroethene ug/L 20 106 70-154107 2 30200.24U 21.1 21.5
1,1-Dichloropropene ug/L 20 120 70-149121 1 30200.21U 24.0 24.3
1,2,3-Trichlorobenzene ug/L 20 109 70-135111 2 30200.34U 21.8 22.1
1,2,3-Trichloropropane ug/L 20 103 71-137105 2 30200.35U 20.6 21.1
1,2,4-Trichlorobenzene ug/L 20 111 73-140109 2 30200.22U 22.2 21.9
1,2-Dibromo-3-
chloropropane ug/L 20 101 65-13499 2 30200.26U 20.2 19.8
1,2-Dibromoethane (EDB)ug/L 20 107 70-137111 3 30200.26U 21.5 22.1
1,2-Dichlorobenzene ug/L 20 116 70-133115 0 30200.29U 23.1 23.1
1,2-Dichloroethane ug/L 20 96 70-13798 2 30200.34U 19.3 19.6
1,2-Dichloropropane ug/L 20 112 70-140116 3 30200.19U 22.5 23.1
1,3-Dichlorobenzene ug/L 20 119 70-135113 5 30200.22U 23.8 22.7
1,3-Dichloropropane ug/L 20 113 70-143115 2 30200.16U 22.5 23.1
1,4-Dichlorobenzene ug/L 20 113 70-133117 3 30200.26U 22.7 23.4
2,2-Dichloropropane ug/L 20 103 61-148105 2 30200.27U 20.5 20.9
2-Butanone (MEK)ug/L 40 89 60-13989 0 30403.3U 35.5 35.6
2-Chlorotoluene ug/L 20 116 70-144118 1 30200.20U 23.3 23.6
2-Hexanone ug/L 40 97 65-13899 2 30400.57U 38.9 39.6
4-Chlorotoluene ug/L 20 115 70-137117 2 30200.20U 23.0 23.4
4-Methyl-2-pentanone
(MIBK)ug/L 40 99 65-135100 1 30404.5U 39.7 40.0
Acetone ug/L 40 104 60-148105 1 30406.2U 41.5 41.9
Benzene ug/L 20 115 70-151118 2 30200.15U 23.0 23.6
Bromobenzene ug/L 20 117 70-136118 1 30200.22U 23.5 23.7
Bromochloromethane ug/L 20 109 70-141110 1 30200.34U 21.8 22.0
Bromodichloromethane ug/L 20 100 70-138103 3 30200.26U 20.0 20.6
Bromoform ug/L 20 89 63-13091 2 30200.62U 17.8 18.2
Bromomethane ug/L IK208815-15290 3 30200.62U 17.5 18.0
Carbon tetrachloride ug/L 20 112 70-143112 1 30200.22U 22.5 22.4
Chlorobenzene ug/L 20 113 70-138115 2 30200.23U 22.6 23.0
Chloroethane ug/L 20 89 52-16391 3 30200.49U 17.7 18.3
Chloroform ug/L 20 108 70-139111 3 30202.3U 21.9 22.5
Chloromethane ug/L 20 73 41-13974 2 30200.39U 14.5 14.8
cis-1,2-Dichloroethene ug/L 20 103 70-141106 3 30200.29U 20.6 21.2
cis-1,3-Dichloropropene ug/L 20 105 70-137109 4 30200.30U 20.9 21.7
Dibromochloromethane ug/L 20 97 70-13499 2 30200.41U 19.4 19.9
Dibromomethane ug/L 20 112 70-138115 3 30200.46U 22.4 22.9
Dichlorodifluoromethane ug/L 20 79 47-15579 1 30200.23U 15.7 15.8
Diisopropyl ether ug/L 20 97 63-14498 1 30200.22U 19.4 19.5
Ethylbenzene ug/L 20 111 66-153115 3 30200.26U 22.3 22.9
Hexachloro-1,3-butadiene ug/L 20 115 65-149110 5 30200.44U 23.0 22.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/07/2020 03:59 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92462652
71177699
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2793295MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35526205008
2793296
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
m&p-Xylene ug/L 40 115 69-152121 5 30400.41U 46.0 48.5
Methyl-tert-butyl ether ug/L 20 107 54-156108 0 30200.28U 21.5 21.5
Methylene Chloride ug/L 20 97 42-15999 2 30203.7U 19.4 19.9
Naphthalene ug/L 20 105 61-148103 2 30200.35U 21.1 20.6
o-Xylene ug/L 20 113 70-148121 7 30200.22U 22.5 24.1
p-Isopropyltoluene ug/L 20 115 70-146115 0 30200.21U 23.0 22.9
Styrene ug/L 20 109 70-135114 4 30200.27U 21.9 22.9
Tetrachloroethene ug/L 20 117 59-143121 4 30200.16U 23.4 24.3
Toluene ug/L 20 110 59-148112 2 30200.24U 21.9 22.4
trans-1,2-Dichloroethene ug/L 20 107 70-146110 2 30200.25U 21.5 22.0
trans-1,3-Dichloropropene ug/L 20 100 70-135102 2 30200.31U 20.0 20.4
Trichloroethene ug/L 20 118 70-147124 4 30200.22U 23.6 24.7
Trichlorofluoromethane ug/L 20 97 70-14899 2 30200.31U 19.4 19.8
Vinyl acetate ug/L IK409149-15191 1 30401.4U 36.2 36.6
Vinyl chloride ug/L 20 88 70-15692 5 30200.24U 17.7 18.5
1,2-Dichloroethane-d4 (S)%92 70-13093
4-Bromofluorobenzene (S)%100 70-130103
Toluene-d8 (S)%98 70-13099
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/07/2020 03:59 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92462652
71177699
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
522764
EPA 3510C
EPA 8270E
8270E Water MSSV RVE
Associated Lab Samples:92462652001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2795814
Associated Lab Samples:92462652001
Matrix:Water
AnalyzedMDL
1,2,4-Trichlorobenzene ug/L ND 10.0 02/03/20 15:101.5
1,2-Dichlorobenzene ug/L ND 10.0 02/03/20 15:101.3
1,3-Dichlorobenzene ug/L ND 10.0 02/03/20 15:101.5
1,4-Dichlorobenzene ug/L ND 10.0 02/03/20 15:102.1
1-Methylnaphthalene ug/L ND 10.0 02/03/20 15:101.4
2,2'-Oxybis(1-chloropropane)ug/L ND 10.0 02/03/20 15:102.8
2,4,5-Trichlorophenol ug/L ND 10.0 02/03/20 15:101.4
2,4,6-Trichlorophenol ug/L ND 10.0 02/03/20 15:101.5
2,4-Dichlorophenol ug/L ND 10.0 02/03/20 15:101.4
2,4-Dimethylphenol ug/L ND 10.0 02/03/20 15:101.4
2,4-Dinitrophenol ug/L ND 50.0 02/03/20 15:1040.5
2,4-Dinitrotoluene ug/L ND 10.0 02/03/20 15:101.2
2,6-Dinitrotoluene ug/L ND 10.0 02/03/20 15:101.4
2-Chloronaphthalene ug/L ND 10.0 02/03/20 15:101.5
2-Chlorophenol ug/L ND 10.0 02/03/20 15:101.2
2-Methylnaphthalene ug/L ND 10.0 02/03/20 15:101.4
2-Methylphenol(o-Cresol)ug/L ND 10.0 02/03/20 15:101.2
2-Nitroaniline ug/L ND 20.0 02/03/20 15:104.2
2-Nitrophenol ug/L ND 10.0 02/03/20 15:101.4
3&4-Methylphenol(m&p Cresol)ug/L ND 10.0 02/03/20 15:101.2
3,3'-Dichlorobenzidine ug/L ND 20.0 02/03/20 15:103.0
3-Nitroaniline ug/L ND 20.0 02/03/20 15:102.3
4,6-Dinitro-2-methylphenol ug/L ND 20.0 02/03/20 15:1015.2
4-Bromophenylphenyl ether ug/L ND 10.0 02/03/20 15:101.6
4-Chloro-3-methylphenol ug/L ND 10.0 02/03/20 15:102.8
4-Chloroaniline ug/L ND 20.0 02/03/20 15:102.8
4-Chlorophenylphenyl ether ug/L ND 10.0 02/03/20 15:101.6
4-Nitroaniline ug/L ND 20.0 02/03/20 15:102.2
4-Nitrophenol ug/L ND 50.0 02/03/20 15:103.5
Acenaphthene ug/L ND 10.0 02/03/20 15:101.6
Acenaphthylene ug/L ND 10.0 02/03/20 15:101.6
Aniline ug/L ND 10.0 02/03/20 15:101.9
Anthracene ug/L ND 10.0 02/03/20 15:101.7
Benzo(a)anthracene ug/L 2.2J 10.0 02/03/20 15:101.8
Benzo(a)pyrene ug/L ND 10.0 02/03/20 15:102.1
Benzo(b)fluoranthene ug/L ND 10.0 02/03/20 15:101.9
Benzo(g,h,i)perylene ug/L 3.5J 10.0 02/03/20 15:101.4
Benzo(k)fluoranthene ug/L 3.2J 10.0 02/03/20 15:101.9
Benzoic Acid ug/L ND 50.0 02/03/20 15:1043.0
Benzyl alcohol ug/L ND 20.0 02/03/20 15:102.6
bis(2-Chloroethoxy)methane ug/L ND 10.0 02/03/20 15:101.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/07/2020 03:59 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92462652
71177699
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2795814
Associated Lab Samples:92462652001
Matrix:Water
AnalyzedMDL
bis(2-Chloroethyl) ether ug/L ND 10.0 02/03/20 15:101.8
bis(2-Ethylhexyl)phthalate ug/L ND 6.0 02/03/20 15:102.1
Butylbenzylphthalate ug/L ND 10.0 02/03/20 15:101.6
Chrysene ug/L 3.8J 10.0 02/03/20 15:101.7
Di-n-butylphthalate ug/L ND 10.0 02/03/20 15:101.8
Di-n-octylphthalate ug/L ND 10.0 02/03/20 15:101.8
Dibenz(a,h)anthracene ug/L 3.6J 10.0 02/03/20 15:101.6
Dibenzofuran ug/L ND 10.0 02/03/20 15:101.5
Diethylphthalate ug/L ND 10.0 02/03/20 15:102.4
Dimethylphthalate ug/L ND 10.0 02/03/20 15:101.6
Fluoranthene ug/L ND 10.0 02/03/20 15:101.7
Fluorene ug/L ND 10.0 02/03/20 15:101.6
Hexachloro-1,3-butadiene ug/L ND 10.0 02/03/20 15:102.0
Hexachlorobenzene ug/L ND 10.0 02/03/20 15:101.7
Hexachlorocyclopentadiene ug/L ND 10.0 02/03/20 15:101.7
Hexachloroethane ug/L ND 10.0 02/03/20 15:102.0
Indeno(1,2,3-cd)pyrene ug/L 2.4J 10.0 02/03/20 15:101.6
Isophorone ug/L ND 10.0 02/03/20 15:101.6
N-Nitroso-di-n-propylamine ug/L ND 10.0 02/03/20 15:102.2
N-Nitrosodimethylamine ug/L ND 10.0 02/03/20 15:101.2
N-Nitrosodiphenylamine ug/L ND 10.0 02/03/20 15:101.7
Naphthalene ug/L ND 10.0 02/03/20 15:101.4
Nitrobenzene ug/L ND 10.0 02/03/20 15:102.1
Pentachlorophenol ug/L ND 20.0 02/03/20 15:102.2
Phenanthrene ug/L ND 10.0 02/03/20 15:101.7
Phenol ug/L ND 10.0 02/03/20 15:100.92
Pyrene ug/L ND 10.0 02/03/20 15:102.1
2,4,6-Tribromophenol (S)%93 10-137 02/03/20 15:10
2-Fluorobiphenyl (S)%81 13-130 02/03/20 15:10
2-Fluorophenol (S)%77 10-130 02/03/20 15:10
Nitrobenzene-d5 (S)%78 13-130 02/03/20 15:10
Phenol-d6 (S)%62 10-130 02/03/20 15:10
Terphenyl-d14 (S)%97 25-130 02/03/20 15:10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2795815LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/L 38.650 77 30-130
1,2-Dichlorobenzene ug/L 37.150 74 30-130
1,3-Dichlorobenzene ug/L 36.450 73 20-130
1,4-Dichlorobenzene ug/L 36.850 74 30-130
1-Methylnaphthalene ug/L 42.850 86 30-130
2,2'-Oxybis(1-chloropropane)ug/L 34.950 70 20-130
2,4,5-Trichlorophenol ug/L 40.850 82 40-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/07/2020 03:59 PM
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Page 15 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92462652
71177699
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2795815LABORATORY CONTROL SAMPLE:
LCSSpike
2,4,6-Trichlorophenol ug/L 40.850 82 40-130
2,4-Dichlorophenol ug/L 40.550 81 31-130
2,4-Dimethylphenol ug/L 39.750 79 30-130
2,4-Dinitrophenol ug/L 217250 87 30-130
2,4-Dinitrotoluene ug/L 44.750 89 49-130
2,6-Dinitrotoluene ug/L 46.150 92 50-130
2-Chloronaphthalene ug/L 42.550 85 30-130
2-Chlorophenol ug/L 39.850 80 30-130
2-Methylnaphthalene ug/L 41.450 83 30-130
2-Methylphenol(o-Cresol)ug/L 37.150 74 30-130
2-Nitroaniline ug/L 88.3100 88 40-130
2-Nitrophenol ug/L 41.550 83 20-130
3&4-Methylphenol(m&p Cresol)ug/L 36.750 73 20-130
3,3'-Dichlorobenzidine ug/L 71.7100 72 10-150
3-Nitroaniline ug/L 91.3100 91 40-130
4,6-Dinitro-2-methylphenol ug/L 98.5100 98 40-130
4-Bromophenylphenyl ether ug/L 41.650 83 30-130
4-Chloro-3-methylphenol ug/L 80.9100 81 30-130
4-Chloroaniline ug/L 85.0100 85 20-130
4-Chlorophenylphenyl ether ug/L 40.150 80 20-130
4-Nitroaniline ug/L 92.4100 92 40-130
4-Nitrophenol ug/L 176250 70 10-130
Acenaphthene ug/L 42.350 85 30-130
Acenaphthylene ug/L 46.450 93 30-130
Aniline ug/L 34.150 68 20-130
Anthracene ug/L 46.650 93 50-130
Benzo(a)anthracene ug/L 49.850 100 50-130
Benzo(a)pyrene ug/L 50.850 102 50-130
Benzo(b)fluoranthene ug/L 53.550 107 50-130
Benzo(g,h,i)perylene ug/L 52.050 104 50-130
Benzo(k)fluoranthene ug/L 50.350 101 50-130
Benzoic Acid ug/L 157250 63 10-130
Benzyl alcohol ug/L 79.6100 80 20-130
bis(2-Chloroethoxy)methane ug/L 38.350 77 30-130
bis(2-Chloroethyl) ether ug/L 39.050 78 30-130
bis(2-Ethylhexyl)phthalate ug/L 44.650 89 50-130
Butylbenzylphthalate ug/L 48.250 96 50-150
Chrysene ug/L 48.850 98 50-130
Di-n-butylphthalate ug/L 43.750 87 50-130
Di-n-octylphthalate ug/L 49.550 99 50-130
Dibenz(a,h)anthracene ug/L 52.150 104 40-130
Dibenzofuran ug/L 41.950 84 40-130
Diethylphthalate ug/L 41.950 84 40-130
Dimethylphthalate ug/L 41.850 84 40-130
Fluoranthene ug/L 46.950 94 30-130
Fluorene ug/L 43.950 88 20-130
Hexachloro-1,3-butadiene ug/L 36.850 74 10-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/07/2020 03:59 PM
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Huntersville, NC 28078
[phone]
Page 16 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92462652
71177699
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2795815LABORATORY CONTROL SAMPLE:
LCSSpike
Hexachlorobenzene ug/L 43.650 87 30-130
Hexachlorocyclopentadiene ug/L 44.850 90 10-150
Hexachloroethane ug/L 36.650 73 10-130
Indeno(1,2,3-cd)pyrene ug/L 51.250 102 40-130
Isophorone ug/L 40.050 80 30-130
N-Nitroso-di-n-propylamine ug/L 40.850 82 30-130
N-Nitrosodimethylamine ug/L 36.250 72 10-130
N-Nitrosodiphenylamine ug/L 37.150 74 30-130
Naphthalene ug/L 40.550 81 20-130
Nitrobenzene ug/L 40.850 82 20-130
Pentachlorophenol ug/L 93.1100 93 10-140
Phenanthrene ug/L 45.650 91 50-130
Phenol ug/L 29.750 59 10-130
Pyrene ug/L 47.750 95 50-130
2,4,6-Tribromophenol (S)%93 10-137
2-Fluorobiphenyl (S)%78 13-130
2-Fluorophenol (S)%71 10-130
Nitrobenzene-d5 (S)%75 13-130
Phenol-d6 (S)%61 10-130
Terphenyl-d14 (S)%89 25-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2795816MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92458988004
2795817
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,2,4-Trichlorobenzene ug/L 50 82 30-13071 15 3050ND41.2 35.6
1,2-Dichlorobenzene ug/L 50 77 30-13067 13 3050ND38.3 33.6
1,3-Dichlorobenzene ug/L 50 74 20-13065 13 3050ND37.2 32.5
1,4-Dichlorobenzene ug/L 50 75 30-13066 13 3050ND37.7 33.1
1-Methylnaphthalene ug/L 50 99 30-13087 12 3050ND49.5 43.7
2,2'-Oxybis(1-
chloropropane)ug/L 50 84 20-13075 11 3050ND42.1 37.6
2,4,5-Trichlorophenol ug/L 50 97 40-13091 7 3050ND48.7 45.4
2,4,6-Trichlorophenol ug/L 50 100 40-13093 6 3050ND49.8 46.7
2,4-Dichlorophenol ug/L 50 98 31-13088 10 3050ND49.0 44.2
2,4-Dimethylphenol ug/L 50 107 30-13090 17 3050ND53.3 44.9
2,4-Dinitrophenol ug/L R12505230-13097 60 30250ND130241
2,4-Dinitrotoluene ug/L 50 106 49-13096 10 3050ND53.2 48.2
2,6-Dinitrotoluene ug/L 50 109 50-130102 7 3050ND54.6 50.9
2-Chloronaphthalene ug/L 50 100 30-13090 11 3050ND49.8 44.8
2-Chlorophenol ug/L 50 94 30-13086 9 3050ND47.1 43.0
2-Methylnaphthalene ug/L 50 95 30-13084 12 3050ND47.3 41.8
2-Methylphenol(o-Cresol)ug/L 50 88 30-13079 11 3050ND43.8 39.3
2-Nitroaniline ug/L 100 106 40-13097 9 30100ND10696.7
2-Nitrophenol ug/L 50 99 20-13088 11 3050ND49.3 44.0
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/07/2020 03:59 PM
Pace Analytical Services, LLC
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[phone]
Page 17 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92462652
71177699
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2795816MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92458988004
2795817
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
3&4-Methylphenol(m&p
Cresol)ug/L 50 85 20-13077 10 3050ND42.6 38.4
3,3'-Dichlorobenzidine ug/L 100 109 10-15092 17 30100ND10992.2
3-Nitroaniline ug/L 100 110 40-130100 9 30100ND110100
4,6-Dinitro-2-methylphenol ug/L 100 94 40-130105 11 30100ND93.8 105
4-Bromophenylphenyl ether ug/L 50 97 30-13089 9 3050ND48.7 44.4
4-Chloro-3-methylphenol ug/L 100 99 30-13087 13 30100ND99.4 87.5
4-Chloroaniline ug/L 100 104 20-13091 14 30100ND10491.1
4-Chlorophenylphenyl ether ug/L 50 97 20-13088 11 3050ND48.7 43.8
4-Nitroaniline ug/L 100 108 40-13096 11 30100ND10896.5
4-Nitrophenol ug/L 250 69 10-13074 8 30250ND172185
Acenaphthene ug/L 50 102 30-13091 11 3050ND51.2 45.6
Acenaphthylene ug/L 50 112 30-130100 11 3050ND56.1 50.1
Aniline ug/L 50 83 20-13073 13 3050ND41.6 36.6
Anthracene ug/L 50 107 50-13099 8 3050ND53.4 49.3
Benzo(a)anthracene ug/L 50 111 50-130102 9 3050ND55.7 50.8
Benzo(a)pyrene ug/L 50 116 50-130105 10 3050ND57.9 52.3
Benzo(b)fluoranthene ug/L 50 124 50-130111 11 3050ND61.9 55.4
Benzo(g,h,i)perylene ug/L 50 116 50-130102 13 3050ND58.0 51.2
Benzo(k)fluoranthene ug/L 50 113 50-130103 9 3050ND56.7 51.7
Benzoic Acid ug/L M1250910-13069 30250ND22.0J 171
Benzyl alcohol ug/L 100 95 20-13087 9 30100ND94.6 86.8
bis(2-
Chloroethoxy)methane ug/L 50 93 30-13083 11 3050ND46.3 41.6
bis(2-Chloroethyl) ether ug/L 50 95 30-13085 11 3050ND47.4 42.6
bis(2-Ethylhexyl)phthalate ug/L 50 104 50-13093 11 3050ND51.8 46.5
Butylbenzylphthalate ug/L 50 114 50-150100 12 3050ND56.8 50.2
Chrysene ug/L 50 109 50-13098 10 3050ND54.3 49.1
Di-n-butylphthalate ug/L 50 100 50-13092 9 3050ND50.2 46.0
Di-n-octylphthalate ug/L 50 116 50-130104 11 3050ND57.8 51.8
Dibenz(a,h)anthracene ug/L 50 114 40-130102 11 3050ND57.1 50.9
Dibenzofuran ug/L 50 100 40-13090 11 3050ND50.2 45.2
Diethylphthalate ug/L 50 99 40-13090 9 3050ND49.5 45.1
Dimethylphthalate ug/L 50 99 40-13091 9 3050ND49.7 45.4
Fluoranthene ug/L 50 105 30-13096 9 3050ND52.7 48.1
Fluorene ug/L 50 106 20-13095 11 3050ND53.1 47.7
Hexachloro-1,3-butadiene ug/L 50 74 10-13063 15 3050ND36.8 31.7
Hexachlorobenzene ug/L 50 101 30-13093 8 3050ND50.3 46.3
Hexachlorocyclopentadiene ug/L 50 98 10-15087 12 3050ND48.9 43.5
Hexachloroethane ug/L 50 72 10-13063 14 3050ND36.1 31.5
Indeno(1,2,3-cd)pyrene ug/L 50 115 40-130102 12 3050ND57.6 51.1
Isophorone ug/L 50 100 30-13088 12 3050ND49.8 44.2
N-Nitroso-di-n-propylamine ug/L 50 98 30-13090 8 3050ND48.9 45.1
N-Nitrosodimethylamine ug/L 50 89 10-13081 10 3050ND44.7 40.5
N-Nitrosodiphenylamine ug/L 50 102 30-13087 15 3050ND51.0 43.7
Naphthalene ug/L 50 90 20-13079 13 3050ND45.1 39.7
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/07/2020 03:59 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92462652
71177699
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2795816MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92458988004
2795817
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrobenzene ug/L 50 98 20-13086 13 3050ND49.0 43.1
Pentachlorophenol ug/L 100 95 10-14097 3 30100ND94.7 97.3
Phenanthrene ug/L 50 104 50-13095 9 3050ND51.9 47.6
Phenol ug/L 50 72 10-13065 11 3050ND36.1 32.4
Pyrene ug/L 50 108 50-13098 9 3050ND53.9 49.2
2,4,6-Tribromophenol (S)%119 10-137111
2-Fluorobiphenyl (S)%97 13-13086
2-Fluorophenol (S)%88 10-13080
Nitrobenzene-d5 (S)%97 13-13087
Phenol-d6 (S)%79 10-13072
Terphenyl-d14 (S)%115 25-13088
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/07/2020 03:59 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 22
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92462652
71177699
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should
be considered an estimated value.IK
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/07/2020 03:59 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 22
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92462652
71177699
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92462652001 522764 522875MW-1 EPA 3510C EPA 8270E
92462652001 522130MW-1 EPA 8260D
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/07/2020 03:59 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 22
Page 22 of 22