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Hazards Identification Classification: Acute toxicity, Oral, Eye Irritation, Category 2B Signal Word: Warning! Hazard Statement: H303+11313 Maybe harmful if swallowed, in contact with +H333 skin or if inhaled. H320 Causes eye irritation. Precautionary P264 Wash hands thoroughly after handling. Statements Prevention: Precautionary P301+330+ IF SWALLOWED: Rinse mouth. Do NOT Statements Response: 331 induce vomiting. P303+352 IF ON SHIN: Wash with plenty of soap and water. P305+351+ IF IN EYES: Rinse cautiously with water for 338 several minutes. Remove contact lenses, if present and easy to do. Continue Rinsing. 3. Composition/Information on Ingredients Ingredients CAS No. Weight Aqua 7732-18-5 70-90 Microbes Proprietary 1-5 Enzymes Proprietary 1-5 Cleaning Aid Proprietary 10-20 Nutrients Proprietary 1-5 4. First Aid Measures Eye Contact: Flush eyes for fifteen minutes with water. If irritation persists, contact a physician. Skin Contact: Wash with soap and water. If irritation persists, contact a physician. Inhalation: Not normally required. Move to fresh air. If symptoms persist, get medical attention. Ingestion: Not normally required. Contact a physician if ingested. 5. Fire Fighting Measures Extinguishing Media: Unused form: Water spray, dry chemical or carbon dioxide. Used form: That which is compatible to liquid (s) absorbed. Special Fire Fighting Procedures: None required. Hazardous Combustion Products: Carbon monoxide and/or carbon dioxide. Unusual Hazards: None expected. Refer to absorbed liquid(s) MSDS(s). Extreme heat may cause pressure to build up inside drum. 6. Accidental Release Measures Spill or Leak Procedures: If material is unused, collect and recover for reuse. Wear protective equipment. Not a listed hazardous waste. 7. Handling and Storage Handling Precautions: Avoid contact with skin and eyes. Do not swallow. Wash hands thoroughly after handling. Storage Precautions: Store in cool, dry area. Prevent product from freezing. Keep out of the reach of children. Shelf life: 3 years as long as the product is kept in a clean, dry environment away from direct sunlight and/or excessive heat. General: Refer to absorbed liquid(s) MSDS(s). Follow label directions carefully. Make sure all containers are labeled properly. The container can be hazardous when empty. Follow label cautions even after the container is empty. Do not re -use empty containers for food, clothing or products for human or animal consumption, or where skin contact can occur. 1 8. Exposure Controls/Personal Protection Engineering Controls: Use adequate ventilation to keep airborne concentrations low PERSONAL PROTECTION Eyes: Safety goggles or glass with side shields Respirator: NIOSH/MSHA approved respirator when ventilation is inadequate. Gloves: Impervious gloves. Other: Maintain eyewash and safety shower in work area. OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200): EXPOSURE LIMIT 8 Ins. TWA (ppm) OSHA PEL ACGIH TLV None Appearance: Amber liquid Odor: Bland pH:7 Melting Point/Freezing Point: 32' F (0' C) Initial Boiling Point and Range: 212° F (100' C) Flash Point: None Method: Not available. Evaporation Rate: Not established. Flammable Limits: Not applicable. Conditions of Flammability: Non-flammable. Explosive Properties: Not established. Vapor Pressure: Not available. Vapor Density: Not established. Relative Density (H2O =1): 1.083 Solubility in Water: Soluble VOC (g/L): 0 10. Stability and Reactivity Data General: This is a stable material Conditions of Reactivity: Reacts with sodium hypochlorite or calcium hypochlorite. Incompatible Materials: Strong oxidants Conditions to Avoid: Excessive heat or flame. Hazardous Decomposition: Not established. Hazardous Polymerization: Will not occur. 11. Toxicological Data LD50: Not established. LC50: Not established. Carcinogenicity: IRAC: None National Toxicology Program: None OSHA: None California Prop 65: No listed ingredient Reproduction Toxicity: Not available Teratogenicity: Not available Mutagenicity: Not available Synergistic Products: Not available 12. Ecological Data No data available 13. Disposal Considerations Waste Disposal Method: Observe all federal, state and local regulations. 14. Transport Information D.O.T. (Department of Transportation): Proper Shipping Name: Non -hazardous liquid Hazard Class: Not regulated Identification Number: Not applicable 15. Regulatory Information CERCLA (Comprehensive Environmental Response Compensation and Liability Act): No Reportable Quantity OSHA Hazard Communication Standard, 28 CFR 1910.1200: No hazardous ingredient. SARA Title III (Superfund Amendments and Reauthorization Act): No listed ingredient. TSCA (Toxic Substances Control Act): All ingredients are listed. 16. OTHER INFORMATION: NFPA Hazard Rating: Health — 1 None 4 Extreme Fire — 0 0 4 4 Reactivity — 0 PPE — B Reason for Issue: GHS changes to Sections 2 & 3. Prepared by: J. Pickett Approved by: C. Matthews Approval Date of Issue: 1/4/2018 Approval Date: 1/4/2018 The information provided in this MSDS is believed to be reliable and accurate. However, the information is provided without any warranty or guarantee, express or implied, regarding its correctness. We do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of the use of this information. The buyer assumes all responsibility of using and handling the product in accordance with the federal, state and local regulations. Beverly, Trudy From: Beverly, Trudy Sent: Thursday, January 9, 2020 3:15 PM To: John Matlock Cc: Pete Hall Subject: RE: [External] Spill follow up Good Afternoon John, We did speak by phone about this release in March and June. I have never been provided contact information for the responsible party, nor a 24-Hour Notification of Discharge form (UST-61) and map. I would greatly appreciate the information so that they may be contacted. Thank you, Trudy Trudy Beverly, L.G. Hydrogeologist, Division of Waste Management North Carolina Department of Environmental Quality UST Section, Mooresville Regional Office 704.235.2182 (Office) Trudy.Beverlykncdenn , og_v Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. From: John Matlock[mailto:JMatlock@shamrockenviro.com] Sent: Wednesday, January 8, 2020 10:01 AM To: Beverly, Trudy <trudy.beverly@ncdenr.gov> Cc: Pete Hall <phall@shamrockenviro.com> Subject: RE: [External] Spill follow up External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to report.spam@nc.gov Good Morning Beverly, In response to the status. At your request I had submitted our remediation plan June 10th with product information and technique. That was the last I heard about it until now. We have not received a "proceed" "Needs altering" " Denial " or further input. So with that being said we have not proceeded. We also have not acquired further financial support from the responsible party. We had contacted him when sending the plan to your office but have had no contact since. Thanks John Matlock Shamrock Environmental Corp. Emergency Response Coordinator 800.881.1098 336.375.8816 Direct Line 336.708.9345 Cell 336.375.1801 Fax R% . 4 -1pp il I I I 4J From: Beverly, Trudy <trudy.beverly@ncdenr.gov> Sent: Friday, January 3, 2020 12:50 PM To: John Matlock <JMatlock@shamrockenviro.com> Subject: RE: [External] Spill follow up Good Afternoon John, Do you have an update on cleanup at this site? Thanks, Trudy Trudy Beverly, L.G. Hydrogeologist, Division of Waste Management Q4 J� North Carolina Department of Environmental Quality ronmenc,i 4ua� UST Section, Mooresville Regional Office 704.235.2182 (Office) Trudy.Beverlykncdenn gov Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. Office Mailing Address: 610 East Center Avenue, Suite 301 Mooresville, NC 28115 Branch's Underground Storage Tanks Website Address: https:Hdeq.nc.gov/about/divisions/waste-management/ust Branch's Above Ground Storage Tanks Website Address: https://deq.nc.gov/about/divisions/waste-management/ust/ast-program INTERACTIVE MAPS WITH DWM SITES AND PERMITTED FACILITIES: https://deq.nc.gov/about/divisions/waste-management/waste-management-rules-data/waste-mana eg ment ig s=mates File Review Procedures: httns://deq.nc. gov/about/divisions/waste-management/ust/file-review-procedures#mooresville-regional-office ONLINE ACCESS TO UST SECTION DOCUMENTS (Laserfiche): hns://deq.nc.gov/about/divisions/waste-management/laserfiche Document Submittal & UST File Names for Laserfiche Policies: https:Hfiles.nc. gov/ncdeq/Waste%20Management/D WM/UST/Corrective%2OAction/Electronic%2ODocument%2OSubmittal%2OMemo%2OUpdate.pdf https:Hfiles.nc.gov/ncdeq/Waste%20Management/DWMfUST/Corrective%2OAction/UST°/a20file%20names%20for°/`2OLaserfiche.docx From: John Matlock [mailto:JMatlock@shamrockenviro.com] Sent: Monday, June 10, 2019 5:17 AM To: Beverly, Trudy <trudy.beverly@ncdenr.gov> Subject: [External] Spill follow up MMI. I External email. Do not click links or open attachments unless you verify. Send all suspicious email as an chment to report.spam@nc.gov Hello Ms. Beverly, As you know we have been trying to remediate a diesel spill at 6777 Mt. Pleasant Rd. in Concord. This has proven to be a difficult excavation site. The unknown location of the sewage leach field being of a major concern. We did dig and haul just short of 8 tons of contaminated soil. The lab results came back with one sample being Non Detectable and another being just over allowable limits. The septic system has constant flow into the yard making for burdensome digging. I am purposing an alternate method of remediation. I am suggesting the use of Enzymes to consume the remaining fuel. The product we use is BioRem 2000 which is listed the EPA's National Contingency Plan Product Schedule and Approved by the Florida Department of Environmental Protection. I would apply the product to the affected area then turn the soil to approximately 6 inch depth and re -apply. We have had amazing results with this method in difficult areas. I have attached the SIDS and a few current spill site pictures where no excavation was used. 100 + gallons of heating oil spill in a soggy yard in Greensboro. Several treatments and Lab samples came back Non Detectable. Please advise if this is acceptable. If you need any further info please do not hesitate to contact me. Thanks John Matlock Shamrock Environmental Corp. Emergency Response Coordinator 800.881.1098 336.375.8816 Direct Line 336.708.9345 Cell 336.375.1801 Fax �RJY1R�5r� •sr�ia •alY