22004_Witherspoon Nursery_BAR_20190221

hart hickman
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Via Email
February 21, 2019
NC Department of Environmental Quality-
Brownfields Program
1646 Mail Service Center
Raleigh, NC 27699-1464
Attention: Mr. Jim Rudder
Re: Brownfields Assessment Report
Witherspoon Nursery
Durham, North Carolina
Brownfields ID 22004-18-032
H&H Job No. CRP-001 and LV L-001
Dear Jim:
On behalf Crowne at 501, Limited Partnership and LRC VII LLC, Hart & Hickman (H&H) is
providing the attached Brownfields Assessment Report for the project located at 3312 Watkins
Road in Durham, North Carolina.
Should you have any questions or comments please do not hesitate to contact me.
Sincerely,
Hart & Hickman, PC
Matt Bramblett, PE
Principal
cc: Ms. Lori Hinnant, K&L Gates (via email)
Ms. Andrea Haines, Crowne (via email)
Mr. Dell Hobbs, Crowne (via email)
Mr. Oaky Dover, Crowne (via email)
Mr. Chris Howlett, LRC (via email)
Attachment
2973 South Tryon Street, Suite 100 3921 Sunset Ridge Rd, Suite 301
Charlotte,NC 28203 Raleigh, NC 27607 www,harthickman.com
704.586.0007 main 1 919.847.4241 main

Brownfields Assessment Report
Witherspoon Nursery
3312 and 3330 Watkins Road
Durham, North Carolina
Brownfields Project ID No. 22004-18-032
OR
SEAL •. �'
25069
WV.
H&H Job No. CRP-001 & LVL-001
February 21, 2019
hart -4 hickman
SMARTER ENVIRONMENTAL SOLUTIONS
#C-1269 Engineering
#C-245 Geology
2923 South Tryon Street, Suite 100 3921 Sunset Ridge Rd, Suite 301
Charlotte, NC 28203 Raleigh, NC 27607 www.harthickman.com
704.586.0007 main 919.847.4241 main

Brownfields Assessment Report
Witherspoon Nursery
Durham, North Carolina
Brownfields Project No. 22004-18-032
H&H Job No. CRP-001 & LVL-001
Table of Contents
1.0 Introduction.............................................................................................................................1
2.0 Previous Assessment Activities..............................................................................................3
2.1 ATC 2015 Assessment Activities..........................................................................................3
2.2 Terracon 2017 Assessment Activities...................................................................................4
2.3 ATC 2018 Assessment Activities..........................................................................................5
3.0 Brownfields Assessment Activities........................................................................................7
4.0 Soil Assessment Activities.......................................................................................................8
4.1 Soil Sampling Methodology..................................................................................................8
4.2 Soil Assessment Results........................................................................................................9
4.3 Cumulative Risk Calculations...............................................................................................9
5.0 Groundwater Assessment Activities....................................................................................11
6.0 Irrigation Pond Assessment Activities................................................................................13
6.1 Surface Water and Sediment Sampling Methodology........................................................13
6.2 Surface Water Sampling Analytical Results.......................................................................14
6.3 Sediment Sampling Analytical Results...............................................................................15
6.4 Cumulative Risk Calculations.............................................................................................16
7.0 Summary and Conclusions...................................................................................................17
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Table 1 Summary of Soil Analytical Data
Table 2 Summary of Surface Water Analytical Data
Table 3 Summary of Sediment Analytical Data
List of Figures
Figure 1 Site Location Map
Figure 2 Site Map
Figure 3 Sample Location Map
List of Anbendices
Appendix A Boring Logs, Well Construction Records, and Well Abandonment Records
Appendix B Laboratory Analytical Reports
Appendix C February 2018 DEQ Risk Calculator Results
Appendix D Surface Water Standards Calculator and Hardness Statistics
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Brownfields Assessment Report
Witherspoon Nursery
Durham, North Carolina
Brownfields Project Nos. 22004-18-032
H&H Job No. CRP-001 & LVL-001
1.0 Introduction
Hart & Hickman, PC (H&H) has prepared this Brownfields Assessment Report for the
Witherspoon Nursery (Brownfields Project No. 22004-18-032) located at 3312 and 3330 Watkins
Road in Durham, Durham County, North Carolina (Site or subject Site). The subject Site totals
approximately 8.0 acres on two parcels of land located in a mixed light industrial and commercial
area of Durham. The Prospective Developer (PD) sold 3.7 acres of the Brownfields Site (i.e., the
western parcel) to Crowne at 501, Limited Partnership (hereinafter referred to as the Witherspoon
Nursery West property), and the PD retained the eastern 4.3 acres of the Brownfields Site
(hereinafter referred to as the Witherspoon Nursery East Property). Future redevelopment of the
Site includes residential apartments, commercial, retail, office, and open spaces. A Site location
map is provided as Figure 1, and a Site map is included as Figure 2.
From the mid- 1970s until the mid-2010s, Witherspoon Rose Culture Inc. conducted plant nursery
operations at the Site. These operations included selling gardening supplies, cultivation of plants,
and storage of agricultural products that contained pesticides and herbicides. The Witherspoon
Nursery East property (3330 Watkins Road; Durham County Parcel Identification No. [PIN]
080021836190) is improved with multiple structures previously used for administration and
storage related to historical plant nursery operations. A residential -type structure was constructed
in the mid- 1950s in the northeastern portion of the Site and used for administrative purposes. Other
Site structures were constructed in various stages from the 1970s through 1980s and are
predominantly situated in the central and southeastern portions of the Witherspoon Nursery East
property. In addition, an approximately 8,000 square foot (sq ft) irrigation pond is near the eastern
property boundary.
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The Witherspoon Nursery West property (3312 Watkins Road; Durham County PIN
080021633681) is improved with an approximately 1,450 sq ft residential -type building located in
the northwest portion of the Site. The building was reportedly constructed in the early 1960s and
then used for administrative purposes. Remaining portions of the Witherspoon Nursery West
property include footprints of former greenhouse structures, gardens, gravel parking, and vegetated
areas.
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2.0 Previous Assessment Activities
From November 2015 through March 2018, several investigations were conducted by ATC
Associates of North Carolina, P.C. (ATC) and Terracon Consultants, Inc. (Terracon) to assess
areas of potential environmental concerns related to plant nursery operations. Areas of potential
environmental concern included septic systems and associated drain fields, an irrigation pond,
three aboveground storage tanks (ASTs) previously utilized for diesel fuel and heating oil, and the
historic usage of pesticides and herbicides on the Site. A brief summary of the historical
investigations is provided below.
2.1 ATC 2015 Assessment Activities
In November 2015, ATC completed soil, groundwater, and sump assessment at the subject Site.
The assessment activities were documented in a December 11, 2015 Limited Phase H
Environmental Site Assessment report. The sampling was conducted to investigate areas identified
during a previous ATC Phase I Environmental Site Assessment (ESA).
As part of the field activities, eight (8) borings were advanced via hollow stem auger in various
locations throughout the subject Site. The borings were advanced to depths ranging from 7.5 to
25 ft below ground surface (bgs) and soils were collected from a hand auger or standard penetration
test (SPT) sampler and later screened with a photoionization detector (PID). The PID screening
results did not indicate the presence of volatile organic compounds (VOCs).
In addition to the soil assessment, water samples were collected from two water supply wells
located in the northeastern and northwestern portions of the Site, two sumps located in the central
and south-central portions of the Site, and two temporary monitoring wells in the south-central and
southeastern portions of the Site. The temporary monitoring wells were installed to a depth of 25
ft bgs and groundwater was only encountered in one of the temporary wells (B-5 located in the
south-central portion of the Site) at an approximate depth of 4.5 ft bgs. According to the report,
the water supply well, sump, and temporary monitoring well samples were analyzed for
organochlorine pesticides and chlorinated herbicides. The laboratory analytical report indicates
that the samples were also analyzed for polychlorinated biphenyls (PCBs). The analytical results
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did not indicate detections of pesticides, herbicides, or PCBs in the water samples above laboratory
reporting limits.
2.2 Terracon 2017 Assessment Activities
In September 2017, Terracon completed soil assessment at the Witherspoon Nursery West
property. The assessment activities were documented in an October 11, 2017 Limited Site
Investigation report and were conducted to investigate areas of potential environmental concern
identified during a previous Terracon Phase I ESA.
As part of the field activities, composite soil sampling was targeted to seven areas based on
historical plant nursery operations. In addition to the composite soil sampling, grab soil sampling
was also conducted to investigate potential impacts related to a heating oil AST in the northwestern
portion of the Site and a former septic drain field in the southwestern portion of the Site. The
composite samples were collected from the ground surface to depths of approximately 6 ft bgs and
submitted for laboratory analysis of organochlorine and organophosphorus pesticides, chlorinated
herbicides, and the metals arsenic, copper, and lead. The grab samples were collected from depths
of approximately 1 to 4 ft bgs and submitted for laboratory analysis of gasoline -range and diesel -
range total petroleum hydrocarbons (TPH-GRO and TPH-DRO).
The laboratory analytical results indicated arsenic was detected at concentrations ranging from
0.79 to 26 milligrams per kilogram (mg/kg) in the composite and grab samples analyzed. These
concentrations exceed the North Carolina Department of Environmental Quality (DEQ)
Residential, Industrial/Commercial, and/or Protection of Groundwater Preliminary Soil
Remediation Goals (PSRGs). Arsenic is a naturally occurring inorganic compound and can be
found in North Carolina soils at concentrations up to 18 mg/kg, which is similar to the
aforementioned levels (see Elements in North American Soils by Dragun and Chekiri, 2005).
Composite samples collected from former gardening areas in the north -central and central portions
of the Site and former septic drain field in the southwestern portion of the Site indicated low levels
of pesticides in soils. Organochlorine pesticides aldrin, gamma-BHC, alpha-BHC, and heptachlor
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epoxide were detected above their respective Protection of Groundwater PSRGs but below
Residential and Industrial/Commercial PSRGs.
Grab sampling conducted in the vicinity of the heating oil AST in the northwestern portion of the
Site indicated impacted soils. DRO was detected at a concentration (270 mg/kg) that exceeded the
DEQ Action Level of 100 mg/kg.
2.3 ATC 2018 Assessment Activities
Based on the results of Terracon's 2017 soil assessment, ATC oversaw removal and excavation
activities of two former diesel ASTs (AST-1 and AST-2) on the Witherspoon Nursery East
property and one former heating oil AST (AST-3) on the Witherspoon Nursery West property.
Removal of the ASTs was conducted in March 2018 and documented in the March 28, 2018 and
May 1, 2018 Soil Excavation Activities — Witherspoon Roses Property reports prepared by ATC.
During removal activities, approximately 5.95 and 6 tons of petroleum impacted soil were
excavated from soils in the vicinity of AST-1 and AST-3, respectively. Confirmatory soil samples
were then collected from each excavation area for analysis of VOCs and semi -volatile organic
compounds (SVOCs). One additional soil sample was also collected from the AST-3 excavation
and analyzed for TPH-GRO and TPH-DRO and Toxicity Characteristic Leaching Procedure
(TCLP) metals (for disposal purposes). The results of the soil sampling did not indicate
exceedances of Residential Maximum Soil Contaminant Concentrations (MSCCs).
The Site received eligibility into the DEQ Brownfields Program (Brownfields Project No. 22004-
18-032) via a Letter of Eligibility dated April 26, 2018. On October 10, 2018, H&H participated
in a conference call with DEQ Brownfields Program personnel to discuss proposed redevelopment
plans for the Site, potential data gaps, and the scope of Brownfields assessment activities needed
to address data gaps for development of an Environmental Management Plan (EMP). As requested
by DEQ during this conference call, on November 16, 2018, H&H submitted a Brownfields
Assessment Work Plan (Work Plan) proposing to conduct soil, groundwater, and irrigation pond
assessment activities to further evaluate Site conditions for potential impacts associated with
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environmental concerns identified during previous investigations. The DEQ Brownfields Program
approved the proposed Work Plan approval in an email dated December 3, 2018.
A summary of Brownfields assessment activities is provided in the following sections.
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3.0 Brownfields Assessment Activities
In January 2019, H&H conducted Brownfields assessment activities at the Site in accordance with
the DEQ Brownfields approved Work Plan. The assessment activities included collection of two
(2) soil samples for laboratory analyses from the Witherspoon Nursery West property and two (2)
co -located surface water and sediment samples for laboratory analyses from the irrigation pond on
the Witherspoon Nursery East property. As further discussed below, groundwater was not
encountered during the assessment activities. Brownfields assessment sample locations are
depicted on Figure 3.
Prior to conducting the field activities, H&H contacted North Carolina 811, the public utility
locator, to mark subsurface utilities located on the Site. H&H also contracted with a private utility
locator to screen proposed sample locations for subgrade utilities not marked by the public locator.
Additionally, soil boring locations were hand cleared to 5 ft bgs to further screen the boring
locations for the presence of subsurface utilities.
The assessment activities were conducted in general accordance with DEQ Inactive Hazardous
Sites Branch (IHSB) Guidelines for Assessment and Cleanup (Guidelines) dated October 2015
and the most recent versions of the U.S. Environmental Protection Agency (EPA) Region IV
Science and Ecosystem Support Division (SESD) Field Branches Quality System and Technical
Procedures guidance. The results of the soil, groundwater, and irrigation pond assessment
activities are provided in Sections 4.0 through 6.0, respectively, and summary and conclusions are
provided in Section 7.0.
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4.0 Soil Assessment Activities
On January 3, 2019, H&H contracted with Innovative Environmental Technologies, Inc. (IET) to
collect soil samples for laboratory analysis in areas of two former septic drain fields on the
Witherspoon Nursery West property. Specifically, the borings were advanced in the former septic
drain field in the southwestern portion of the Site (SB-1) and the former septic drain field south of
the administrative building (SB-2) in the west -central portion of the Site. Soil boring locations
(denoted by SB nomenclature) are shown on Figure 3.
4.1 Soil Sampling Methodology
H&H advanced two (2) soil borings and collected two (2) soil samples for laboratory analysis to
further evaluate the potential for impact in the former septic drain fields. As part of soil assessment
activities, IET utilized a track -mounted direct push technology (DPT) drill rig to advance soil
borings to depths ranging from approximately 5 to 12 ft bgs. Continuous soil samples were
collected from the borings using a decontaminated stainless -steel hand auger or acetate lined
macrocore sleeves. The soil samples were logged for lithologic description and screened using
visual and olfactory methods for obvious evidence of staining, unusual odors, and for the presence
of volatile organic vapors using a calibrated PID. Based upon results of field observations and
field screening, one soil sample was collected for laboratory analysis from each soil boring from
depths below the former septic drain fields (SB-1 at 4-5 ft bgs and SB-2 at 6-8 ft bgs). Boring logs
with lithologic descriptions and field screening results are provided in Appendix A.
Soil samples selected for laboratory analysis were placed directly into dedicated laboratory -
supplied sample containers, labeled with the sample identification, date, and requested analysis,
and placed in a laboratory supplied cooler with ice. The samples were delivered to Pace Analytical,
a North Carolina certified laboratory, under standard chain of custody protocols for analysis of
VOCs by EPA Method 8260 and SVOCs by EPA Method 8270. In addition, soil sample SB-2
was submitted for analysis of Resource Conservation and Recovery Act (RCRA) metals plus
hexavalent chromium by EPA Methods 6020/7471/7199. For quality assurance/quality control
purposes, a duplicate soil sample was collected from the SB-2 soil boring and submitted to Pace
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Analytical for the same analysis as the SB-2 parent soil sample. Estimated values (J-flag reporting)
were requested of the laboratory.
Following sampling activities, the soil sample borings were properly abandoned and the surfaces
were repaired similar to pre -drilling conditions. Additionally, the soil sample locations were
estimated using a hand-held global positioning system (GPS) unit.
4.2 Soil Assessment Results
A tabular summary of soil sample analytical results is presented in Table 1, and the laboratory
analytical report is provided in Appendix B. The laboratory analytical results were compared to
the DEQ IHSB Residential and Industrial/Commercial PSRGs dated February 2018. In addition
to the PSRGs, metals results were compared to published background ranges for North Carolina
soils published in Elements in North American Soils authored by Dragun and Chekiri (2005).
Laboratory analytical results did not indicate the presence of VOCs or SVOCs in either soil sample
at concentrations above laboratory method detection limits.
As expected, naturally occurring levels of several metals were detected at concentrations above
the laboratory method detection limits in each soil sample. Arsenic was detected at a concentration
of 1.0 milligrams per kilogram (mg/kg) in SB-2, which exceeds the Residential PSRG of 0.68
mg/kg. Arsenic was also detected in the duplicate sample collected from SB-2 (DUP-SB) at a
concentration of 3.02 mg/kg, which exceeds the Industrial/Commercial PSRG of 3.0 mg/kg. The
detections of arsenic are consistent with published background ranges for North Carolina soils.
No other metals were detected at concentrations exceeding Residential PSRGs.
4.3 Cumulative Risk Calculations
The DEQ IHSB PSRGs are conservative and based on a lifetime incremental cancer risk (LICR)
for potential carcinogenic risks of 1 x 10-6 and a non -carcinogenic hazard quotient (HQ) of 0.2 for
potential non -carcinogenic risks. When calculating Site -specific risks, the DEQ acceptable
threshold for potential carcinogenic risks is I x 10-4, and the acceptable level for non -carcinogenic
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risks is a hazard index less than 1. Although the arsenic concentrations detected in SB-2 are
consistent with naturally occurring levels, to evaluate the potential exposure risk associated with
the detected soil concentrations, H&H used the DEQ soil risk calculator using the analytical data
for the SB-2 parent and duplicate soil samples. Consistent with planned redevelopment and
proposed use at the Site, H&H completed a risk calculator for the sample with higher
concentrations (SB-2, duplicate) using the residential, non-residential worker, and construction
worker scenarios to evaluate both current risk and potential future need for land use controls.
Results of the risk calculator are summarized below and included in Appendix C.
Non -Residential
Sample
Resident
Construction Worker
Worker
Sample ID
Depth
Carcinogenic
Hazard
Carcinogenic
Hazard
Carcinogenic
Hazard
(ft bgs)
Risk
Index
Risk
Index
Risk
Index
SB-2
Fuplicate)
6-8
4.5 x 10"6
0.10
1.0 x 10-6
0.0074
1.7 x 10"7
0.084
As shown in the table above, calculated cumulative risks do not exceed acceptable levels
(carcinogenic risk <1 x 10"4 and HI <1) for a future resident, non-residential worker, or a
construction worker.
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5.0 Groundwater Assessment Activities
On January 2, 2019, H&H supervised installation of three temporary monitoring wells. Temporary
monitoring well locations (denoted by TMW nomenclature) are shown on Figure 3 and were
advanced in the following locations:
• downgradient of the sumps in the central and south-central portions of the Witherspoon
Nursery East property (TMW-1);
• downgradient of the former septic drain field in the southern portion of the Witherspoon
Nursery West property and near the former boring B-5 where groundwater was previously
reported (TMW-2); and
• near the former heating oil AST south of the administrative building in the northwestern
portion of the Witherspoon Nursery West property (TMW-4).
In accordance with the DEQ Brownfields approved Work Plan, a fourth temporary monitoring
well (TMW-3) was to be installed near the former septic drain field south of the administrative
building in the west -central portion of the Witherspoon Nursery West property. However, as
further described below, this temporary well was not able to be installed to the target depth of 25
ft.
The temporary monitoring well borings were advanced using a combination of hollow -stem auger
(HSA) and air rotary drilling methods. Each temporary monitoring well was advanced to a depth
of 25 ft bgs and was constructed with 2-inch diameter PVC with 15 ft of 0.010 slot well screen. A
sand filter pack was installed from below the base of the monitoring well to approximately 2 ft
above the top of the well screens. The temporary monitoring wells were completed by placing a
hydrated bentonite seal from the top of the sand filter pack to the ground surface. Following
installation, the wells were left overnight to allow to equilibrate to static conditions. Temporary
monitoring well boring logs and construction details are provided in Appendix A.
Up to two borings were advanced in an attempt to install temporary monitoring well TMW-3
(denoted as TMW-3A and TMW-3B on Figure 3) near the former septic drain field south of the
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administrative building in the west -central portion of the Witherspoon Nursery West property.
During drilling, perched water, possibly from the former septic drain field, was encountered from
depths of approximately 2 to 5 ft bgs. The perched water impeded the drill rig's air hammer from
advancing the borings to the target depth of 25 ft bgs. In addition, the perched water contributed
to both boreholes exhibiting cave-ins. Termination depths for borings TMW-3A and TMW-were
approximately 18 and 9 ft bgs, receptively.
On January 3, 2019, H&H returned to the Site to check the three temporary monitoring wells for
the presence of groundwater. Upon inspection, groundwater was not observed in the three installed
temporary monitoring wells; thus, no groundwater samples were collected for laboratory analysis.
The temporary monitoring wells were subsequently properly abandoned and the surfaces were
repaired similar to pre -drilling conditions. Additionally, each temporary monitoring well boring
location was estimated using a GPS unit. Temporary monitoring well abandonment records are
provided in Appendix A.
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6.0 Irrigation Pond Assessment Activities
On January 3, 2019, H&H collected two (2) co -located surface water and sediment samples from
the irrigation pond located on the Witherspoon Nursery East property. The irrigation pond is not
a classified water body according to the DEQ Division of Water Resources North Carolina Surface
Water Classifications Map. The nearest downgradient classified surface water body to the
irrigation pond is New Hope Creek, which has a classification of WS-V; NSW. The surface water
and sediment sample (denoted by SW and SED nomenclature, respectively) locations are shown
in Figure 3.
6.1 Surface Water and Sediment Sampling Methodology
H&H collected two (2) co -located surface water and sediment samples (SW-1/SED-1 and SW-
2/SED-2) from the irrigation pond located on the Witherspoon Nursery East property. Field
measurements of turbidity, dissolved oxygen, temperature, specific conductivity, pH, and
oxidation-reduction potential were collected for each surface water sample. The sediment samples
were collected from the base of the irrigation pond using a decontaminated stainless steel AMS
dredge sampler.
The surface water and sediment samples were placed directly into dedicated laboratory -supplied
sample containers, labeled with the sample identification, date, and requested analysis, and placed
in a laboratory supplied cooler with ice. The samples were delivered to Pace Analytical under
standard chain of custody protocols for analysis of VOCs by EPA Method 8260, SVOCs by EPA
Method 8270, RCRA metals plus hexavalent chromium by EPA Methods 6020/7471/7196,
organochlorine pesticides by EPA Method 8081, organophosphorus pesticides by EPA Method
8141, and herbicides by EPA Method 8151. In addition to total RCRA metals, surface water
samples were also submitted for laboratory analysis of dissolved RCRA metals by EPA Methods
6020/7471 and nitrate by EPA Method 300. Estimated values (J-flag reporting) were requested of
the laboratory.
Upon completion of sampling, the co -located surface water and sediment sample locations were
estimated using a hand-held GPS unit.
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6.2 Surface Water Sampling Analytical Results
A tabular summary of surface water sample analytical results is presented in Table 2, and the
laboratory analytical report is provided in Appendix B. Surface water data were compared to the
DEQ 15A NCAC 02B Surface Water Quality Standards (2B Standards). The 2B Standards for
cadmium, trivalent chromium, lead, and silver are hardness -dependent. Therefore, H&H entered
the 50% median hardness value of New Hope Creek of 43 milligrams per liter (mg/L) as CaCO3
in the DEQ 15A NCAC 02B Water Quality Standards for Surface Waters Calculator (Calculator)
to calculate acute and chronic (where applicable) 2B Standards for cadmium, trivalent chromium,
lead, and silver which are used for comparison in Table 2. The Calculator and DEQ Hardness
Statistics by 8-Digit HUC, North Carolina, 1969-2013 are presented in Appendix D.
Laboratory analytical results did not indicate the presence of VOCs, organochlorine pesticides,
organophosphorus pesticides, herbicides, or nitrate at concentrations above the laboratory method
detection limit in either of the surface water samples collected.
Laboratory analytical results indicate that low levels of phenol were detected in SW-1 (0.508 J
micrograms per liter [µg/L)]) and SW-2 (2.76 J µg/L) surface water samples at concentrations
above the laboratory method detection limit, but below the 2B Standard of 300 µg/L. No other
SVOCs were detected above the laboratory method detection limits.
Laboratory analytical results indicate that low levels of total trivalent chromium and total and
dissolved arsenic and barium were detected at concentrations above laboratory method detection
limits, but below 2B Standards in each surface water sample. No metals were detected at
concentrations exceeding 2B Standards in the surface water samples, except total lead. Low levels
of total lead were detected in SW-1 at estimated values (1.72 J µg/L) and SW-2 (1.21 J µg/L) at
concentrations exceeding the calculated chronic 2B Standard 0.99 µg/L. However, concentrations
of dissolved lead were below the chronic 2B Standard in both surface water samples. Based on
these results and trace levels of total lead detected, H&H attributes the lead detections to be
naturally occurring lead in suspended sediment in the pond water.
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Witherspoon Nursery (BPN 22004-18-032)_20190221.docx
SMARTER ENVIRONMENTAL SOLUTIONS

6.3 Sediment Sampling Analytical Results
A tabular summary of sediment sample analytical results is presented in Table 3 and the laboratory
analytical report is provided in Appendix B. The laboratory analytical results were compared to
the DEQ IHSB Residential and Industrial/Commercial PSRGs dated February 2018. In addition
to the PSRGs, metals results were compared to published background ranges for North Carolina
soils published in Elements in North American Soils authored by Dragun and Chekiri (2005).
Laboratory analytical results indicate that low levels of acetone (up to 0.0557 mg/kg),
ethylbenzene (up to 0.000848 J mg/kg), 2-butanone (up to 0.0186 J mg/kg), and toluene (up to
0. 00 166 J mg/kg) were detected at concentrations above the laboratory method detection limit, but
below their respective Residential and Industrial PSRGs. Acetone was also detected in the
laboratory blank and is attributed to laboratory introduced contamination. The other three VOC
detections were at trace and estimated (J-flagged) concentrations.
Laboratory analytical results did not indicate the presence of SVOCs, organophosphorus pesticides
or herbicides at concentrations above the laboratory method detection limit in either of the
sediment samples collected. A low level of organochlorine pesticide 4,4-DDE was detected in
sediment sample SED-2 at an estimated concentration (0.00498 J mg/kg) above the laboratory
detection limit, but well below the Residential PSRG of 2.0 mg/kg.
As expected, naturally occurring levels of several metals were detected at concentrations above
the laboratory method detection limits in each sediment sample. Arsenic was detected in sediment
samples SED-1 (4.39 mg/kg) and SED-2 (3.6 mg/kg) at concentrations that exceed the Residential
PSRG of 0.68 mg/kg and Industrial/Commercial PSRG of 3.0 mg/kg. The detections of arsenic
are consistent with published background ranges for North Carolina soils. No other metals were
detected at concentrations exceeding Residential PSRGs.
15 ■
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Witherspoon Nursery (BPN 22004-18-032)_20190221.docx
SMARTER ENVIRONMENTAL SOLUTIONS

6.4 Cumulative Risk Calculations
Although the arsenic concentrations detected in SED-1 and SED-2 are consistent with naturally
occurring levels, to evaluate the potential exposure risk associated with the detected sediment
concentrations, H&H used the DEQ soil risk calculator using the analytical data for the SED-1 and
SED-2 sediment samples. Consistent with planned redevelopment and proposed use at the Site,
H&H completed a risk calculator for the sample with higher concentrations (SED-1) using the
residential, non-residential worker, and construction worker scenarios to evaluate both current risk
and potential future need for land use controls. Results of the risk calculator are summarized below
and included in Appendix C.
Non -Residential
Resident
Construction Worker
Sample ID
Worker
Carcinogenic
Hazard
Carcinogenic
Hazard
Carcinogenic
Hazard
Risk
Index
Risk
Index
Risk
Index
SED-1
6.5 x 10-6
0.14
1.5 x 10-6
0.01
2.4 x 10-'
0.11
As shown in the table above, calculated cumulative risks do not exceed acceptable levels
(carcinogenic risk <1 x 10-4 and HI <1) for a future resident, non-residential worker, or a
construction worker.
16 ■
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Witherspoon Nursery (BPN 22004-18-032)_20190221.docx
SMARTER ENVIRONMENTAL SOLUTIONS

7.0 Summary and Conclusions
H&H has completed Brownfields assessment activities at the Witherspoon Nursery Brownfields
property located in Durham, North Carolina. The assessment activities were conducted in
accordance with the DEQ Brownfields approved Work Plan dated November 16, 2018.
Brownfields assessment activities included soil, surface water, and sediment sampling to evaluate
for potential impacts and assist in management of Site media during proposed redevelopment
activities. A brief summary of the assessment activities is provided below.
• Arsenic (up to 3.02 mg/kg) was detected at a concentration above the
Industrial/Commercial PSRG of 3.0 mg/kg in the SB-1/DUP-SB soil sample collected in
the west -central portion of the Site. The arsenic is attributed to naturally occurring arsenic
in the soil. Calculated cumulative risks for soil samples collected at the Site do not exceed
acceptable levels for a construction worker, future resident, or a non-residential worker.
• No compounds were detected above the DEQ 2B Standards in the surface water samples,
except total lead. Total lead (up to 1.72 J µg/L) was detected at estimated concentrations
exceeding the chronic 2B Standard of 0.99 µg/L in irrigation pond surface water samples
SW-1 and SW-2. However, concentrations of dissolved lead were below the chronic 2B
Standard in both surface water samples. Based on these results and trace levels of total
lead detected, H&H attributes the lead detections to be naturally occurring lead in
suspended sediment in the pond water.
• Arsenic (up to 4.39 mg/kg) was detected at concentrations above the
Industrial/Commercial PSRG of 3.0 mg/kg in irrigation pond sediment samples SED-1 and
SED-2. The arsenic is attributed to naturally occurring arsenic in the soil and sediment.
Calculated cumulative risks for sediment samples collected at the Site do not exceed
acceptable levels for a construction worker, future resident, or a non-residential worker.
• Assessment activities using three temporary wells indicate that groundwater is not present
at depths of up to 25 ft bgs.
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Witherspoon Nursery (BPN 22004-18-032)_20190221.docx
SMARTER ENVIRONMENTAL SOLUTIONS

In summary, low level concentrations of naturally occurring arsenic were identified in soil and
sediment at the Site. Based on these results, additional assessment does not appear warranted and
soil disturbed during future redevelopment activities can be managed in accordance with a
Brownfields Environmental Management Plan (EMP).
18 ■
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Witherspoon Nursery (BPN 22004-18-032)_20190221.docx
SMARTER ENVIRONMENTAL SOLUTIONS

Table 1
Summary of Soil Analytical Data
Former Witherspoon Nursery
Durham, North Carolina
H&H Job Nos. CPR.001 and LVL.001
SB-2
Sample ID
SB-1
Regional Background
SB-2
DUP-SB
Industrial/
Metals in Soil (2)
Depth (ft bgs)
4-5
6-8
6-8
Residential
PSRG (1)
Commercial
PSRG(1)
Sample Date
1/3/19
1/3/19
1/3/19
Witherspoon Nursery
West -
Witherspoon Nursery West -
Sample Location
Former Septic Field
Former Administrative Building Septic Field
Range
Mean
Ref.
to the South
Units
mg/kg
VOCs (8260B)
ALL BRL
ALL BRL
--
--
--
--
SVOCs (8270D)
ALL BRL
ALL BRL
ALL BRL
--
--
--
--
--
RCRA Metals (6020B/7471 B/7199)
Arsenic
NA
1.00
3.02
0.68
3.0
1.0-18
4.8
A
Barium
NA
101
127
3,100
47,000
50-1,000
356
A
Cadmium
NA
0.422 J
0.276 J
14
200
1.0-10
4.3
B
Total Chromium
NA
20.4
30.9
*0.31
*6.5
7.0-300
65
A
Trivalent Chromium
NA
20.4
30.9
23,000
350,000
NS
NS
--
Hexavalent Chromium
NA
<0.323
0.31
6.5
NS
NS
--
Lead
NA
8.40
11.9
400
800
BRL-50
16
A
Mercury
NA
0.011 J
0.0113 J
2.3
9.7
0.03-0.52
0.121
A
Selenium
NA
0.385 J
0.559 J
78
1,200
<0.1-0.8
0.42
A
Silver
NA
78
1,200
BRL-5.0
NS
C
Notes:
1) North Carolina Department of Environmental Quality (DEQ) Preliminary Soil Remediation Goals (PSRGs) (February 2018).
2) Range and mean values of background metals for North Carolina soils taken from Elements in North American Soils by Dragun and Chekiri, 2005.
Ref. A. North Carolina soils, B. Southeastern US soils, C. Soils of the conterminous USA
With the exception of metals, only analytes with concentrations above the laboratory reporting limit are shown.
Soil concentrations are reported in milligrams per kilogram (mg/kg).
Laboratory analytical methods are shown in parentheses.
Bold indicates concencentration exceeds DEQ Residential PSRG (February 2018).
Underline indicates concencentration exceeds DEQ Industrial/Commercial PSRG (February 2018).
* = If sample was analyzed for chromium (total) and hexavalent chromium, detections are compared to the trivalent chromium and hexavalent chromium PSRGs.
-- = not applicable; NA = not analyzed; NS= not specified; BRL = below laboratory reporting limit; ft bgs = feet below the ground surface
J = compound was detected above the laboratory method detection limit, but below the laboratory reporting limit resulting in an estimated concentration
Table 1 (Page 2 of 2)
File: S:\AAA-Master Projects\Crowne Partners Inc - CRP\CRP.001 Crowne at 501 I-P Durham BFs\Report\Tables\Brownfields Assessment Tables_ Witherspoon_ 2019011413rownfields Assessment Tables_ Witherspoon_20190114
Date: 1 /22/2019 Hart &Hickman Pa
/
f

Table 2
Summary of Surface Water Analytical Data
Former Witherspoon Nursery
Durham, North Carolina
H&H Job No. CRP.001 and LVL.001
Sample ID
SW-1
SW-2
NC 2B Standards(')
Sample Date
1/3/19
1/3/19
Witherspoon Nursery East -
Chronic
Acute
Sample Location
Irrigation Pond
Units
pg/L
VOCs (8260B)
ALL BRL
--
--
SVOCs (8270D)
Phenol
0.508 J
2.76 J
300 (P)
--
Herbicides (8151)
ALL BRL
--
--
Organophosphorus Pesticides (8141 B)
ALL BRL
--
--
Organochlorine Pesticides (8081 B)
\LL BR'
--
--
Wet Chemistry (300.0)
Nitrate as (N)
NS
NS
RCRA Metals (6020B/7470A/7199)
Total
Dissolved
Total
Dissolved
Arsenic
10 (t)
NS
3.64
1.70 J
3.66
2.12
Barium
29.2
21.3
25.1
18.7
1,000 (t)
NS
Cadmium(h)
<0.160
<0.160
<0.160
<0.160
0.22(2)
1.31(2)
Total Chromium
1.95 B J
1.57 B J
2.38 B
1.14 B J
NS
NS
Trivalent Chromium(")
1.95 B J
NA
2.38 B
37.13(2)
285.43(2)
Hexavalent Chromium
1\14
11
16
Lead(h)
1.72 J
0.615 B J
1.21 J
0.407 B J
0.99(2)
25.48(2)
Mercury
<G-490
<0.0490
<0.0490
J.0490
0.012 (t)
NS
Selenium
<0.380
<0.380
<0.380
<0.380
5 (t)
NS
Silver(h)
<r
<0.310
<0.310
0.06
0.75121
Notes:
1. North Carolina Department of Environmental Quality's (DEQ's) 15A NCAC 02B Surface Water Quality Standards and Criteria for Class WS-V; NSW waters (2B Standards) (September 22, 2017).
2. Standard derived using the DEQ Hardness -Dependent Metal Calculator dated September 22, 2017 using the DEQ published median hardness for New Hope Creek of 43 milligrams per liter as CaCO3.
With the exception of metals, only analytes with concentrations above the laboratory reporting limit are shown.
Surface water concentrations are reported in micrograms per liter (µg/L).
Bold indicates concencentration 2B Standard (September 22, 2017).
-- = not applicable; BRL = below laboratory reporting limit; NA = not analyzed; NS = not specified
B = analyte was detected in the associated laboratory blank as well as in the sample
J = compound was detected above the laboratory method detection limit, but below the laboratory reporting limit resulting in an estimated concentration
(h) = metal is hardness -dependent. See 15A NCAC 02B .0211 for more information.
(t) = based upon measurement of total recoverable metal. See 15A NCAC 02B .0211 for more information.
(P) = public policy document.
Table 2 (Page 1 of 1)
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Date: 2/13/2019 f

Table 3
Summary of Sediment Analytical Data
Former Witherspoon Nursery
Durham, North Carolina
H&H Job Nos. CRP.001 and LVL.001
Sample ID
SED-1
SED-2
Regional Background
Residential
PSRG 11j
Industrial/
Commercial
PSRG(1)
Metals in Soil(2)
Sample Date
1/3/19
1/3/19
Witherspoon Nursery East -
Sample Location
Irrigation Pond
Range
Mean
Ref.
Units
mg/kg
VOCs (8260B)
Acetone
<0.0188
0.0557 B
12,000
140,000
--
--
--
Ethylbenzene
<0.000728
0.000848 J
6.1
27
--
--
--
2-Butanone (MEK)
<0.0171
0.0186 J
5,500
40,000
--
--
--
Toluene
<0.00171
0.00166 J
990
9,700
--
--
--
Herbicides (8151)
ALL BRL
ALL BRL
--
--
--
--
--
Organophosphorus Pesticides (8141 B)
ALL BRL
--
--
--
--
--
Organochlorine Pesticides (8081 B)
4,4-DDE '-DDE
<0.00209
0.00498 J
2.0
9.3
--
--
--
SVOCs (8270D)
ALL BRL
ALL BRL
--
--
--
--
--
RCRA Metals (6020B/7471 B/7199)
Arsenic
4.39
3.6
0.68
3.0
1.0-18
4.8
A
Barium
148
212
3,100
47,000
50-1,000
356
A
Cadmium
<0.109
<0.104
14
200
1.0-10
4.3
B
Chromium (total)
36.6
53.4
*0.31
*6.5
7.0-300
65
A
Trivalent Chromium
36.6
53.4
23,000
350,000
NS
NS
--
Hexavalent Chromium
<0.34i
<0.332
0.31
6.5
NS
NS
--
Lead
17.3
14.4
400
800
BRL-50
16
A
Mercury
0.0103 J
0.147
2.3
9.7
0.03-0.52
0.121
A
Selenium
0.396 J
0.529 J
78
1,200
<0.1-0.8
0.42
A
Silver
<0.211
78
1,200
BRL-5.0
NS
C
Notes:
1) North Carolina Department of Environmental Quality (DEQ) Preliminary Soil Remediation Goals (PSRGs) (February 2018).
2) Range and mean values of background metals for North Carolina soils taken from Elements in North American Soils by Dragun and Chekiri, 2005.
Ref. A. North Carolina soils, B. Southeastern US soils, C. Soils of the conterminous USA
With the exception of metals, only analytes with concentrations above the laboratory reporting limit are shown.
Soil concentrations are reported in milligrams per kilogram (mg/kg).
Laboratory analytical methods are shown in parentheses.
Bold indicates concencentration exceeds DEQ Residential PSRG (February 2018).
Underline indicates concencentration exceeds DEQ Industrial/Commercial PSRG (February 2018).
* = If sample was analyzed for chromium (total) and hexavalent chromium, detections are compared to the trivalent chromium and hexavalent chromium PSRGs.
-- = not applicable; NS= not specified; BRL = below laboratory reporting limit
B = analyte was detected in the associated laboratory blank as well as in the sample
J = compound was detected above the laboratory method detection limit, but below the laboratory reporting limit resulting in an estimated concentration
Table 3 (Page 1 of 1)
File: S:\AAA-Master Projects\Crowne Partners Inc - CRP\CRP.001 Crowne at 501 LP Durham BFs\Report\Tables\BrownfieIds Assessment Tables_ Witherspoon_ 2019012213rownfields Assessment Tables _W itherspoon_20190122 Hart &Hickman PC
Date: 2/13/2019 f

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Appendix A
Boring Logs, Well Construction Records, and Well Abandonment Records
hart hickman
SMAKtER ENVIRONMENTAL SOLUTIONS

14
hart hickman
Client: Crowne Partners Inc
BORING LOG
Project: Witherspoon Nursery
Boring No. SB-1
SMARTER ENVIRONMENTAL SOLUTIONS
Address: 3312 Watkins Road, Durham, NC
Page: 1 of 1
Drilling Start Date: 1/3/19
Boring Depth (ft): 5.0
Drilling End Date: 1/3/19
Boring Diameter (in): 2.00
Drilling Company: Innovative Environmental Technologies
Sampling Method(s): Grab
Drilling Method: Other
DTW During Drilling (ft):
Drilling Equipment: Hand Auger
DTW After Drilling (ft):
Driller: TR White
Ground Surface Elev. (ft):
Logged By: JLN
Location (X,Y):
COLLECT
MEASURE
w
O
J
UJ
Z
O
ap
O
W
J
c7 F
Z W
ro
0-
N
SOIL/ROCK VISUAL DESCRIPTION
N
a
W
d
O2
HT
o
Z
o-
Lu
O
2
J
~¢
mQ
E
E
H
O
3
a)a
'o
pCO
m
W
Q
m
0
d
J
U)
0 0
GR
5.00
(0') Lean CLAY (CL); some silt, medium plasticity, stiff, wet, brown
0.0
-------------------------------------------------------------------------------------------
(1') Lean CLAY (CL); medium plasticity, very stiff, moist, brownish yellow
0.0
0.0
------------------------------------------------------------------------------------------
(T) Lean CLAY (CL); some silt, medium plasticity, stiff, moist, light gray
0.0
-------------------------------------------------------------------------------------------
(4') SILT (ML); little clay, low plasticity, medium stiff, moist, light gray and reddish
0.0
SB-1
(4-5)
brown mottling
5
5
(5) Boring terminated
10 10
NOTES: Hole precleared to 5.0' on 1/3/19 by Innovative Environmental Technologies using hand auger.
generated using Loglttasy.com

14
hart hickman
Client: Crowne Partners Inc
BORING LOG
Project: Witherspoon Nursery
Boring No. SB-2
SMARTER ENVIRONMENTAL SOLUTIONS
Address: 3312 Watkins Road, Durham, NC
Page: 1 of 1
Drilling Start Date: 1/3/19
Boring Depth (ft): 12.0
Drilling End Date: 1/3/19
Boring Diameter (in): 2.00
Drilling Company: Innovative Environmental Technologies
Sampling Method(s): Direct Push, Grab
Drilling Method: Direct Push
DTW During Drilling (ft):
Drilling Equipment: AMS PowerProbe 9520 VTR
DTW After Drilling (ft):
Driller: TR White
Ground Surface Elev. (ft):
Logged By: JLN
Location (X,Y):
COLLECT
MEASURE
w
O
J
UJ
Z
O
a
O
p
W
J
c7 F
Z W
ro
a
N
SOIL/ROCK VISUAL DESCRIPTION
N
a
W
d
O2
HT
o
Z
o_
LU
O
2
J
~¢
mQ
E
E
H
O
3
a)a
'o
pCO
m
W
Q
m
0
d
J
U)
0 0
GR
5.00
(0') Lean CLAY (CL); some silt, medium plasticity, soft, wet, brown and brownish yellow
2.1
-------------------------------------------------------------------------------------------
(1') Lean CLAY (CL); medium plasticity, stiff, saturated, brownish yellow
2.1
1.7
1.8
1.5
5
DP
5.00
1.8
5
-------------------------------------------------------------------------------------------
(6') SILT (ML); little clay, low plasticity, stiff, wet, light gray with reddish brown
2.0
SB-2
(6-8)
inclusions
2.3
(8') SILT (ML); little clay, low plasticity, stiff, moist, reddish brown with light gray
2.2
inclusions
2.4
10
DP
2.00
1.7
10
2.2
(12') Boring terminated
15 15
NOTES: Hole precleared to 5.0' on 1/3/19 by Innovative Environmental Technologies using hand auger.
generated using Loglttasy.com

14
hart hickman
Client: LRC VII, LLC
WELL LOG
Project: Witherspoon Nursery
Well No. TMW-1
SMARTER ENVIRONMENTAL SOLUTIONS
Address: 3312 Watkins Road, Durham, NC
Page: 1 of 1
Drilling Start Date: 1/2/19
Boring Depth (ft): 25.0
Well Depth (ft): 25.0
Drilling End Date: 1/2/19
Boring Diameter (in): 6.00
Well Diameter (in): 2.0
Drilling Company: Innovative Environmental
Technologies
Sampling Method(s): Grab
Screen Slot (in): 0.010
Drilling Method: Air Rotary
DTW During Drilling (ft): Dry
Riser Material: Sch 40 PVC
Drilling Equipment: AMS PowerProbe 9520 VTR
DTW After Drilling (ft): Dry
Screen Material: Sch 40 PVC Slotted
Driller: TR White
Top of Casing Elev. (ft):
Seal Material(s): Bent. Pellets
Logged By: JLN
Location (X,Y):
Filter Pack: Sand Pack
COLLECT
MEASURE
_
w
O
J
W
z
LD
_
ap
0-
J
w d
N
iT
a,
fn
o
SOIL/ROCK VISUAL DESCRIPTION
o-
a
W
=
W
�0
E
0
o
a
m
W
O
J
¢
O
U
o
H
3
pco
O
U
m
IY
d
m
J
GR
5.00
(0) Poorly graded GRAVEL (GP)
0.0
(05) SILT (ML); few coarse gravel, little clay, low plasticity, soft, moist, brown
0.0
= -
(2') Lean CLAY (CL); medium plasticity, stiff, wet, brownish yellow
0.0
-- -
----------------------------------------------------------------------------------------
0.0
=
(3.5') Lean CLAY (CL); some silt, medium plasticity, stiff, moist, yellowish red
0.0
5
== =
5
(5') Lean CLAY (CL); some silt, medium plasticity, very stiff, moist, yellowish red
10
10
15
15
20
20
-----------------------------------------------------------------------------------------
(22') BEDROCK: WEATHERED SANDSTONE; moist, gray
V
V
VV
V
VV
V V
25
25
(25') Boring terminated
30 30
NOTES: Hole precleared to 5.0' on 1/2/19 by Innovative Environmental Technologies using hand auger.
generated using Loglttasy.com

hart hickman
Client: Crowne Partners Inc
WELL LOG
Project: Witherspoon Nursery
Well No. TMW-2
SMARTER ENVIRONMENTAL SOLUTIONS
Address: 3312 Watkins Road, Durham, NC
Page: 1 of 1
Drilling Start Date: 1/2/19
Boring Depth (ft): 25.0
Well Depth (ft): 25.0
Drilling End Date: 1/2/19
Boring Diameter (in): 6.00
Well Diameter (in): 2.0
Drilling Company: Innovative Environmental
Technologies
Sampling Method(s): Grab
Screen Slot (in): 0.010
Drilling Method: Air Rotary
DTW During Drilling (ft): Dry
Riser Material: Sch 40 PVC
Drilling Equipment: AMS PowerProbe 9520 VTR
DTW After Drilling (ft): Dry
Screen Material: Sch 40 PVC Slotted
Driller: TR White
Top of Casing Elev. (ft):
Seal Material(s): Bent. Pellets
Logged By: JLN
Location (X,Y):
Filter Pack: Sand Pack
COLLECT
MEASURE
_
w
J
W
z
LD
_
ap
0-
J
w d
N
iT
a,
fn
o
SOIL/ROCK VISUAL DESCRIPTION
o-
a
W
=
W
�0
E
0
o
a
m
W
O
J
¢
O
U
o
H
3
pco
O
U)
m
d
m
J
0 0
GR
5.00
(0') SILT (ML); some clay, low plasticity, soft, moist, light brown
0.1
-----------------------------------------------------------------------------------------
(1') Lean CLAY (CL); some silt, medium plasticity, stiff, moist, brownish yellow
0.1
0.1
0.1
-------------------
(4') Lean CLAY (CL); some silt, medium plasticity, stiff, wet, light gray
0.1
5
=_ __
5
(5') No Recovery: difficult advancement due to some loss of air pressure and hard
material
10
10
-----------------------------------------------------------------------------------------
(1T) BEDROCK: WEATHERED SANDSTONE; moist, light gray
V
V V
V
15
V VV
15
V
VV
VVV
VVV
VVV
V V
20
VVV
20
V
VVV
V V
V
VVV
VVV
VV
25
25
(25') Boring terminated
30 30
NOTES: Hole precleared to 5.0' on 1/2/19 by Innovative Environmental Technologies using hand auger.
generated using Loglttasy.com

14
hart hickman
Client: Crowne Partners Inc
BORING LOG
Project: Witherspoon Nursery
Boring No. TMW-3A
SMARTER ENVIRONMENTAL SOLUTIONS
Address: 3312 Watkins Road, Durham, NC
Page: 1 of 1
Drilling Start Date: 1/2/18
Boring Depth (ft): 18.0
Drilling End Date: 1/2/18
Boring Diameter (in): 3.00
Drilling Company: Innovative Environmental Technologies
Sampling Method(s): Grab
Drilling Method: DPT / Air Rotary
DTW During Drilling (ft):
Drilling Equipment: AMS PowerProbe 9520 VTR
DTW After Drilling (ft):
Driller: TR White
Ground Surface Elev. (ft):
Logged By: JLN
Location (X,Y):
COLLECT
MEASURE
_
O
J
w
Z
O
O
2
wO
J
J
w
F
ZW
O
CL
m
E
w
U
2.
SOIL/ROCK VISUAL DESCRIPTION
a
O
E
2
w
❑
J
¢
00p
E
3
0
❑_
❑
v
m
m
o-
co
Y
0 0
5.00
(0') Lean CLAY (CL); little silt, medium plasticity, soft, moist, light brown
0.1
zz` .
Q
x.>
-------------------------------------------------------------------------------------------
(1') Lean CLAY (CL); little silt, medium plasticity, soft, wet, light brown
na`
0.1
`4
------------------------------------------------------------------------------------
> a
(T) Lean CLAY (CL); little silt, medium plasticity, soft, saturated, light brown, perched
0.1
water
0.1
5
5.00
0.0
5
DP
------------------------------------------------------------------------------------------
(6') SILT (ML); little clay, low plasticity, medium stiff, moist, light gray
0.0
0.1
10
DP
4.00
10
-------------------------------------------------------------------------------------------
(11') SILT (ML); little clay, low plasticity, stiff, moist, light gray with reddish brown
0.0
inclusions
-------------------------------------------------------------------------------------------
(13') SILT (ML); little clay, low plasticity, stiff, moist, reddish brown and light gray
0.0
mottling
----- -------------------------------------------------------------------------------
(14') No Recovery: DPT refusal - switched to air rotary
15
15
(18') Boring terminated due to interference with perched water zone
20 20
NOTES: Hole precleared to 5.0' on 1/2/18 by Innovative Environmental Technologies using hand auger. Boring advanced via DPT until
refusal at 14 ft. Borehole collapsed to 5 ft.
generated using Logfttasy.com

14
hart hickman
Client: Crowne Partners Inc
BORING LOG
Project: Witherspoon Nursery
Boring No. TMW-313
SMARTER ENVIRONMENTAL SOLUTIONS
Address: 3312 Watkins Road, Durham, NC
Page: 1 of 1
Drilling Start Date: 1/2/19
Boring Depth (ft): 9.0
Drilling End Date: 1/2/19
Boring Diameter (in): 6.00
Drilling Company: Innovative Environmental Technologies
Sampling Method(s): Grab
Drilling Method: Air Rotary
DTW During Drilling (ft):
Drilling Equipment: AMS PowerProbe 9520 VTR
DTW After Drilling (ft):
Driller: TR White
Ground Surface Elev. (ft):
Logged By: JLN
Location (X,Y):
COLLECT
MEASURE
w
O
J
UJ
Z
O
ap
O
W
J
c7 F
Z W
ro
0-
N
SOIL/ROCK VISUAL DESCRIPTION
N
a
W
d
O2
HT
o
Z
o_
LU
0
2
J
~¢
mQ
E
E
H
O
3
a)a
'o
pCO
m
W
Q
m
0
d
J
U)
0 0
GR
5.00
(0') Lean CLAY (CL); little silt, medium plasticity, soft, moist, light brown
0.0
------------------------------------------------------------------------------
(1') Lean CLAY (CL); little silt, medium plasticity, soft, wet, light brown
0.1
-------------- ------------- ------------------------------------------
(2') Lean CLAY (CL); little silt, medium plasticity, soft, saturated, light brown, perched
0.1
water
0.0
0.1
5
5
(5') No Recovery
(9') Boring terminated due to interference with perched water zone
10 10
NOTES: Hole precleared to 5.0' on 1/2/19 by Innovative Environmental Technologies using hand auger.
generated using Loglttasy.com

14
hart hickman
Client: Crowne Partners Inc
WELL LOG
Project: Witherspoon Nursery
Well No. TMW-4
SMARTER ENVIRONMENTAL SOLUTIONS
Address: 3312 Watkins Road, Durham, NC
Page: 1 of 1
Drilling Start Date: 1/2/19
Boring Depth (ft): 25.0
Well Depth (ft): 25.0
Drilling End Date: 1/2/19
Boring Diameter (in): 6.00
Well Diameter (in): 2.0
Drilling Company: Innovative Environmental
Technologies
Sampling Method(s): DP, GR
Screen Slot (in): 0.010
Drilling Method: Air Rotary
DTW During Drilling (ft): Dry
Riser Material: Sch 40 PVC
Drilling Equipment: AMS PowerProbe 9520 VTR
DTW After Drilling (ft): Dry
Screen Material: Sch 40 PVC Slotted
Driller: TR White
Top of Casing Elev. (ft):
Seal Material(s): Bent. Pellets
Logged By: JLN
Location (X,Y):
Filter Pack: Sand Pack
COLLECT
MEASURE
_
�
UJ
z
0
ap
U
W
0,w
a
N 0.N
c'o
e,
SOIL/ROCK VISUAL DESCRIPTION
o-
E CL
W
=
W
�I
y
E
U
>
a
co
ILL
U
0
m
a
co
0 0
GR
5.00
(0') Clayey SAND (SC); little silt, well -graded, medium dense, moist, brownish yellow
8.1
-----------------------------------------------------------------------------------------
(1') Sandy lean CLAY (CL); little silt, medium plasticity, stiff, moist, brownish yellow
0.3
0.0
_
-----------------------------------------------------------------------------------------
(3') Clayey SAND (SC); little silt, well -graded, loose, moist, light brown
0.1
_
----------------------------------------------------------------------------------------
(4') Sandy SILT (ML); few clay, low plasticity, soft, moist, light brown
0.1
5
: =
DP
5.00
0.0
5
== ==
0.0
----------------------------------------------------------------------------------------
(8.5') SILT (ML); some clay, low plasticity, medium stiff, moist, brown and light brown
0.0
10
with reddish yellow inclusions
10
2.00
0.0
V VV
-----------------------------------------------------------------------------------------
(12') BEDROCK: WEATHERED SANDSTONE; moist, brown and light gray layers
VVV
VVV
15
VVV
15
VVV
V VV
VVV
V VV
V V
20
VVV
V
20
V VV
VVV
VVV
V VV
V V
25
25
(25) Boring terminated
30 30
NOTES: Hole precleared to 5.0' on 1/2/19 by Innovative Environmental Technologies using hand auger. Boring advanced via DPT until
refusal at 12 ft.
generated using Loglttasy.com

WELL CONSTRUCTION RECORD (GW-1)
1. Well Contractor Information:
Print Form
For Internal Use
Terry White
Well Contractor Name
3287-B
NC Well Contractor Certification Number
I ET
Company Name
2. Well Construction Permit #:
List all applicable well construction permits (i.e. UIC, County, State, Variance, etc.)
3. Well Use (check well use):
Water Supply Well:
Agricultural []Municipal/Public
Geothermal (Heating/Cooling Supply) [Residential Water Supply (single)
Industrial/Commercial Residential Water Supply (shared)
Irrieation
Non -Water Supply Well:
-L_ - .
Aquifer Recharge
Aquifer Storage and Recovery
Aquifer Test
Experimental Technology
Geothermal (Closed Loop)
Geothermal (Heating/Cooling
[ Groundwater Remediation
[ Salinity Barrier
[ Stormwater Drainage
[Subsidence Control
[Tracer
under #21
4. Date Well(s) Completed. 1 /2/2019 Well ID#TMW-1
5a. Well Location:
Former Witherspoon Nursery
Facility/Owner Name Facility ID# (if applicable)
3312 Watkins Rd. ,Durham 27707
Physical Address, City, and Zip
Durham
County Parcel Identification No. (PIN)
5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees:
(if well field, one lat/long is sufficient)
35 57 05 N 78 59 24 W
6. Is(are) the well(s)1IPermanent or E(Temporary
7. Is this a repair to an existing well: []Yes or XQNo
If this is a repair, fill out known well construction information and explain the nature of the
repair under #21 remarks section or on the back of this form.
8. For Geoprobe/DPT or Closed -Loop Geothermal Wells having the same
construction, only 1 GW-1 is needed. Indicate TOTAL NUMBER of wells
drilled:l
9. Total well depth below land surface: 25 (ft.)
For multiple wells list all depths if different (example- 3@200' and 2@100')
10. Static water level below top of casing: DRY (ft.)
If water level is above casing, use "+"
11. Borehole diameter: 6 (in.)
12. Well construction method: Auger
(i.e. auger, rotary, cable, direct push, etc.)
14. WATER ZONES
FROM
TO
DESCRIPTION
ft.
ft.
DRY Red Silt
ft,
ft.
15. OUTER CASING for multi -cased wells OR LINER if a licable
FROM
TO
DIAMETERT
THICKNESS
MATERIAL
ft,
ft.
I in.
16. INNER CASING OR TUBING eother al closed -loop)
FROM
TO
I DIAMETER I
THICKNESS
MATERIAL
0 ft.
10 ft-
2 in 1
sch40
I pvc
ft.
ft.
in.
17. SCREEN
FROM
TO
DIAMETER
SLOT SIZE
THICKNESS
MATERIAL
10 ft-
25 ft-
2 in-
0.010
sch40
pvc
ft.
ft.
in.
18. GROUT
FROM
TO
MATERIAL
EMPLACEMENT METHOD & AMOUNT
0 ft.
8 ft.
Bentonite
poured
ft.
ft.
ft.
ft.
19. SAND/GRAVEL PACK (if applicable)
FROM
TO
MATERIAL
EMPLACEMENT METHOD
8 ft•
25 ft•
#2 sand
poured
ft,
ft.
20. DRILLING LOG attach additional sheets if necessary)
FROM
TO
DESCRIPTION (color, hardness, soiFrock type, grain size, etc.)
ft.
ft.
See consultant log
ft.
ft.
ft,
ft.
ft.
ft.
ft.
ft.
ft.
ft.
ft.
ft.
21. REMARKS
22. Certification:
jam„ G{�l2 1 /4/2019
Signature of Ce Med Well Contractor Date
By signing this form, I hereby certify that the well(s) was (were) constructed in accordance
with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a
copy of this record has been provided to the well owner.
23. Site diagram or additional well details:
You may use the back of this page to provide additional well site details or well
construction details. You may also attach additional pages if necessary.
SUBMITTAL INSTRUCTIONS
24a. For All Wells: Submit this form within 30 days of completion of well
construction to the following:
Division of Water Resources, Information Processing Unit,
1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Iniection Wells: In addition to sending the form to the address in 24a
above, also submit one copy of this form within 30 days of completion of well
construction to the following:
Division of Water Resources, Underground Injection Control Program,
FOR WATER SUPPLY WELLS ONLY: 1636 Mail Service Center, Raleigh, NC 27699-1636
13a. Yield (gpm) Method of test: 24c. For Water Supply & Iniection Wells: In addition to sending the form to
the address(es) above, also submit one copy of this form within 30 days of
13b. Disinfection type: Amount: completion of well construction to the county health department of the county
where constructed.
Form GW-1 North Carolina Department of Environmental Quality - Division of Water Resources Revised 2-22-2016

WELL CONSTRUCTION RECORD (GW-1)
1. Well Contractor Information:
Print Form
For Internal Use
Terry White
Well Contractor Name
3287-B
NC Well Contractor Certification Number
I ET
Company Name
2. Well Construction Permit #:
List all applicable well construction permits (i.e. UIC, County, State, Variance, etc.)
3. Well Use (check well use):
Water Supply Well:
Agricultural []Municipal/Public
Geothermal (Heating/Cooling Supply) [Residential Water Supply (single)
Industrial/Commercial Residential Water Supply (shared)
Irrieation
Non -Water Supply Well:
-L_ - .
Aquifer Recharge
Aquifer Storage and Recovery
Aquifer Test
Experimental Technology
Geothermal (Closed Loop)
Geothermal (Heating/Cooling
[ Groundwater Remediation
[ Salinity Barrier
[ Stormwater Drainage
[Subsidence Control
[Tracer
under #21
4. Date Well(s) Completed. 1 /2/2019 Well ID#TMW-2
5a. Well Location:
Former Witherspoon Nursery
Facility/Owner Name Facility ID# (if applicable)
3312 Watkins Rd. ,Durham 27707
Physical Address, City, and Zip
Durham
County Parcel Identification No. (PIN)
5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees:
(if well field, one lat/long is sufficient)
35 57 05 N 78 59 24 W
6. Is(are) the well(s)1IPermanent or E(Temporary
7. Is this a repair to an existing well: []Yes or XQNo
If this is a repair, fill out known well construction information and explain the nature of the
repair under #21 remarks section or on the back of this form.
8. For Geoprobe/DPT or Closed -Loop Geothermal Wells having the same
construction, only 1 GW-1 is needed. Indicate TOTAL NUMBER of wells
drilled:l
9. Total well depth below land surface: 25 (ft.)
For multiple wells list all depths if different (example- 3@200' and 2@100')
10. Static water level below top of casing: DRY (ft.)
If water level is above casing, use "+"
11. Borehole diameter: 6 (in.)
12. Well construction method: Auger
(i.e. auger, rotary, cable, direct push, etc.)
14. WATER ZONES
FROM
TO
DESCRIPTION
ft.
ft.
DRY Red Silt
ft,
ft.
15. OUTER CASING for multi -cased wells OR LINER if a licable
FROM
TO
DIAMETERT
THICKNESS
MATERIAL
ft,
ft.
I in.
16. INNER CASING OR TUBING eother al closed -loop)
FROM
TO
I DIAMETER I
THICKNESS
MATERIAL
0 ft.
10 ft-
2 in 1
sch40
I pvc
ft.
ft.
in.
17. SCREEN
FROM
TO
DIAMETER
SLOT SIZE
THICKNESS
MATERIAL
10 ft-
25 ft-
2 in-
0.010
sch40
pvc
ft.
ft.
in.
18. GROUT
FROM
TO
MATERIAL
EMPLACEMENT METHOD & AMOUNT
0 ft.
8 ft.
Bentonite
poured
ft.
ft.
ft.
ft.
19. SAND/GRAVEL PACK (if applicable)
FROM
TO
MATERIAL
EMPLACEMENT METHOD
8 ft•
25 ft•
#2 sand
poured
ft,
ft.
20. DRILLING LOG attach additional sheets if necessary)
FROM
TO
DESCRIPTION (color, hardness, soiFrock type, grain size, etc.)
ft.
ft.
See consultant log
ft.
ft.
ft,
ft.
ft.
ft.
ft.
ft.
ft.
ft.
ft.
ft.
21. REMARKS
22. Certification:
1 /4/2019
Signature euertified Well Contractor Date
By signing this form, I hereby certify that the well(s) was (were) constructed in accordance
with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a
copy of this record has been provided to the well owner.
23. Site diagram or additional well details:
You may use the back of this page to provide additional well site details or well
construction details. You may also attach additional pages if necessary.
SUBMITTAL INSTRUCTIONS
24a. For All Wells: Submit this form within 30 days of completion of well
construction to the following:
Division of Water Resources, Information Processing Unit,
1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Iniection Wells: In addition to sending the form to the address in 24a
above, also submit one copy of this form within 30 days of completion of well
construction to the following:
Division of Water Resources, Underground Injection Control Program,
FOR WATER SUPPLY WELLS ONLY: 1636 Mail Service Center, Raleigh, NC 27699-1636
13a. Yield (gpm) Method of test: 24c. For Water Supply & Iniection Wells: In addition to sending the form to
the address(es) above, also submit one copy of this form within 30 days of
13b. Disinfection type: Amount: completion of well construction to the county health department of the county
where constructed.
Form GW-1 North Carolina Department of Environmental Quality - Division of Water Resources Revised 2-22-2016

WELL CONSTRUCTION RECORD (GW-1)
1. Well Contractor Information:
Print Form
For Internal Use
Terry White
Well Contractor Name
3287-B
NC Well Contractor Certification Number
I ET
Company Name
2. Well Construction Permit #:
List all applicable well construction permits (i.e. UIC, County, State, Variance, etc.)
3. Well Use (check well use):
Water Supply Well:
Agricultural []Municipal/Public
Geothermal (Heating/Cooling Supply) [3Residential Water Supply (single)
Industrial/Commercial Residential Water Supply (shared)
hrieation
Non -Water Supply Well:
-L_ - .
Aquifer Recharge
Aquifer Storage and Recovery
Aquifer Test
Experimental Technology
Geothermal (Closed Loop)
Geothermal (Heating/Cooling
0 Groundwater Remediation
01 Salinity Barrier
01 Stormwater Drainage
Subsidence Control
Tracer
under #21
4. Date Well(s) Completed.1 /2/2019 Well ID# T M W-4
5a. Well Location:
Former Witherspoon Nursery
Facility/Owner Name Facility lD# (if applicable)
3312 Watkins Rd.,Durham 27707
Physical Address, City, and Zip
Durham
County Parcel Identification No. (PIN)
5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees:
(if well field, one lat/long is sufficient)
35 57 08 N 78 59 287 W
6. Is(are) the well(s)OPermanent or xOTemporary
7. Is this a repair to an existing well: QYes or QNo
If this is a repair, fill out known well construction information and explain the nature of the
repair under #21 remarks section or on the back of this form.
8. For Geoprobe/DPT or Closed -Loop Geothermal Wells having the same
construction, only 1 GW-1 is needed. Indicate TOTAL NUMBER of wells
drilled: t
9. Total well depth below land surface: 25 (ft.)
For multiple wells list all depths if different (example- 3@200' and 2@100')
10. Static water level below top of casing: DRY (ft.)
If water level is above casing, use "+"
11. Borehole diameter: 6 (in.)
12. Well construction method: Auger
(i.e. auger, rotary, cable, direct push, etc.)
14. WATER ZONES
FROM
TO
DESCRIPTION
ft.
ft.
DRY Red Silt
ft,
ft.
15. OUTER CASING for multi -cased wells OR LINER if a licable
FROM
TO
DIAMETER
THICKNESS
MATERIAL
ft,
ft,
I in.
16. INNER CASING OR TUBING eother at closed -loop)
FROM
TO
I DIAMETER I
THICKNESS
I MATERIAL
0 ft.
10 ft.
2 in.
Sch40
I pvc
ft.
ft.
I in.
17. SCREEN
FROM
TO
DIAMETER
SLOT SIZE
THICKNESS
MATERIAL
10 ft•
25 ft.
2 in-
0.010
SCh40
pvc
ft.
ft.
in.
18. GROUT
FROM
TO
MATERIAL
EMPLACEMENT METHOD & AMOUNT
0 ft.
g ft.
Bentonite
poured
ft.
ft.
ft.
ft.
19. SAND/GRAVEL PACK (if applicable)
FROM
TO
MATERIAL
EMPLACEMENT METHOD
g ft.
25 ft•
#2 Sand
poured
ft,
ft.
20. DRILLING LOG attach additional sheets if necessary)
FROM
TO
DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft.
ft.
See consultant log
ft.
ft.
ft,
ft.
ft.
ft.
ft.
ft.
ft.
tt.
ft.
ft.
21. REMARKS
22. Certification:
1 /4/2019
Signature z9certified Well Contractor Date
By signing this form, I hereby certify that the well(s) was (were) constructed in accordance
with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a
copy of this record has been provided to the well owner.
23. Site diagram or additional well details:
You may use the back of this page to provide additional well site details or well
construction details. You may also attach additional pages if necessary.
24a. For All Wells: Submit this form within 30 days of completion of well
construction to the following:
Division of Water Resources, Information Processing Unit,
1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Iniection Wells: In addition to sending the form to the address in 24a
above, also submit one copy of this form within 30 days of completion of well
construction to the following:
Division of Water Resources, Underground Injection Control Program,
FOR WATER SUPPLY WELLS ONLY: 1636 Mail Service Center, Raleigh, NC 27699-1636
13a. Yield (gpm) Method of test: 24c. For Water Suimly & Iniection Wells: In addition to sending the form to
the address(es) above, also submit one copy of this form within 30 days of
13b. Disinfection type: Amount: completion of well construction to the county health department of the county
where constructed.
Form GW-1 North Carolina Department of Environmental Quality - Division of Water Resources Revised 2-22-2016

WELL ABANDONMENT RECORD
1. Well Contractor Information:
Terry White
Well Contractor Name (or well owner personally abandoning well on his/her property)
3287-B
NC Well Contractor Certification Number
I ET
Company Name
2. Well Construction Permit #:
List all applicable well construction permits (i.e. UIC County, State, Variance, etc.) ifknown
3. Well use (check well use):
Water Supply Well:
❑Agricultural ❑Municipal/Public
❑Geothermal (Heating/Cooling Supply) ❑Residential Water Supply (single)
❑Industrial/Commercial ❑Residential Water Supply (shared)
❑Irrigation
Non -Water Supply Well:
❑Aquifer Recharge
❑Aquifer Storage and Recovery
❑Aquifer Test
❑Experimental Technology
❑Geothermal (Closed Loop)
El Geothermal (Heating/Cooling
El Groundwater Remediation
❑ Salinity Barrier
❑ Stormwater Drainage
El Subsidence Control
❑Tracer
El Other (explain under 7g)
4. Date well(s) abandoned: 1 /3/201 9
5a. Well location:
Former Witherspoon Nursery
Facility/Owner Name Facility ID# (if applicable)
3312 Watkins Rd.,Durham 27707
Physical Address, City, and Zip
Durham
County Parcel Identification No. (PIN)
5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees:
(if well field, one lat/long is sufficient)
35 57 05 N 78 59 24 W
CONSTRUCTION DETAILS OF WELL(S) BEING ABANDONED
Attach well construction record(s) ifavailable. For multiple injection or non -water supply wells
ONLY with the same constructionlabandonment, you can submit one form.
6a. Well ID#: TMW-1
6b. Total well depth: 25 (ft.)
6c. Borehole diameter: 6 (in.)
6d. Water level below ground surface: DRY (ft.)
6e. Outer casing length (if known):
6L Inner casing/tubing length (if known): 10 (ft.)
6g. Screen length (if known): 15 (ft.)
For Internal Use ONLY:
WELL ABANDONMENT DETAILS
7a. For Geoprobe/DPT or Closed -Loop Geothermal Wells having the same
well construction/depth, only 1 GW-30 is needed. Indicate TOTAL NUMBER of
wells abandoned: t
7b. Approximate volume of water remaining in well(s): 0 (gal.)
FOR WATER SUPPLY WELLS ONLY:
7c. Type of disinfectant used:
7d. Amount of disinfectant used:
7e. Sealing materials used (check all that apply):
❑ Neat Cement Grout S Bentonite Chips or Pellets
❑ Sand Cement Grout
❑ Concrete Grout
❑ Specialty Grout
❑ Bentonite Slurry
❑ Dry Clay
❑ Drill Cuttings
❑ Gravel
❑ Other (explain under 7g)
7f. For each material selected above, provide amount of materials used:
24 pounds
7g. Provide a brief description of the abandonment procedure:
Poured Bentonite from bottom to the top
8. Certification:
66)L& 1 /4/2019
Signature of rtified Well Contractor or Well Owner Date
By signing this form, I hereby certify that the well(s) was (were) abandoned in
accordance with 1 SA NCAC 02C .0100 or 2C .0200 Well Construction Standards
and that a copy of this record has been provided to the well owner.
9. Site diagram or additional well details:
You may use the back of this page to provide additional well site details or well
abandonment details. You may also attach additional pages if necessary.
SUBMITTAL INSTRUCTIONS
10a. For All Wells: Submit this form within 30 days of completion of well
abandonment to the following:
Division of Water Resources, Information Processing Unit,
1617 Mail Service Center, Raleigh, NC 27699-1617
10b. For Infection Wells: In addition to sending the form to the address in 10a
above, also submit one copy of this form within 30 days of completion of well
abandonment to the following:
Division of Water Resources, Underground Injection Control Program,
1636 Mail Service Center, Raleigh, NC 27699-1636
loc. For Water Supply & Iniection Wells: In addition to sending the form to the
address(es) above, also submit one copy of this form within 30 days of completion
of well abandonment to the county health department of the county where
abandoned.
Form GW-30 North Carolina Department of Environmental Quality - Division of Water Resources Revised 2-22-2016

WELL ABANDONMENT RECORD
1. Well Contractor Information:
Terry White
Well Contractor Name (or well owner personally abandoning well on his/her property)
3287-B
NC Well Contractor Certification Number
I ET
Company Name
2. Well Construction Permit #:
List all applicable well construction permits (i.e. UIC County, State, Variance, etc.) ifknown
3. Well use (check well use):
Water Supply Well:
❑Agricultural ❑Municipal/Public
❑Geothermal (Heating/Cooling Supply) ❑Residential Water Supply (single)
❑Industrial/Commercial ❑Residential Water Supply (shared)
❑Irrigation
Non -Water Supply Well:
❑Aquifer Recharge
❑Aquifer Storage and Recovery
❑Aquifer Test
❑Experimental Technology
❑Geothermal (Closed Loop)
El Geothermal (Heating/Cooling
El Groundwater Remediation
❑ Salinity Barrier
❑ Stormwater Drainage
El Subsidence Control
❑Tracer
El Other (explain under 7g)
4. Date well(s) abandoned: 1 /3/201 9
5a. Well location:
Former Witherspoon Nursery
Facility/Owner Name Facility ID# (if applicable)
3312 Watkins Rd.,Durham 27707
Physical Address, City, and Zip
Durham
County Parcel Identification No. (PIN)
5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees:
(if well field, one lat/long is sufficient)
35 57 05 N 78 59 24 W
CONSTRUCTION DETAILS OF WELL(S) BEING ABANDONED
Attach well construction record(s) ifavailable. For multiple injection or non -water supply wells
ONLY with the same constructionlabandonment, you can submit one form.
6a. Well ID#: TMW-2
6b. Total well depth: 25 (ft.)
6c. Borehole diameter: 6 (in.)
6d. Water level below ground surface: DRY (ft.)
6e. Outer casing length (if known):
6L Inner casing/tubing length (if known): 10 (ft.)
6g. Screen length (if known): 15 (ft.)
For Internal Use ONLY:
WELL ABANDONMENT DETAILS
7a. For Geoprobe/DPT or Closed -Loop Geothermal Wells having the same
well construction/depth, only 1 GW-30 is needed. Indicate TOTAL NUMBER of
wells abandoned: t
7b. Approximate volume of water remaining in well(s): 0 (gal.)
FOR WATER SUPPLY WELLS ONLY:
7c. Type of disinfectant used:
7d. Amount of disinfectant used:
7e. Sealing materials used (check all that apply):
❑ Neat Cement Grout S Bentonite Chips or Pellets
❑ Sand Cement Grout
❑ Concrete Grout
❑ Specialty Grout
❑ Bentonite Slurry
❑ Dry Clay
❑ Drill Cuttings
❑ Gravel
❑ Other (explain under 7g)
7f. For each material selected above, provide amount of materials used:
24 pounds
7g. Provide a brief description of the abandonment procedure:
Poured Bentonite from bottom to the top
8. Certification:
U) 1 /4/2019
Signature ertified Well Contractor or Well Owner Date
By signing this form, I hereby certify that the well(s) was (were) abandoned in
accordance with 1 SA NCAC 02C .0100 or 2C .0200 Well Construction Standards
and that a copy of this record has been provided to the well owner.
9. Site diagram or additional well details:
You may use the back of this page to provide additional well site details or well
abandonment details. You may also attach additional pages if necessary.
SUBMITTAL INSTRUCTIONS
10a. For All Wells: Submit this form within 30 days of completion of well
abandonment to the following:
Division of Water Resources, Information Processing Unit,
1617 Mail Service Center, Raleigh, NC 27699-1617
10b. For Infection Wells: In addition to sending the form to the address in 10a
above, also submit one copy of this form within 30 days of completion of well
abandonment to the following:
Division of Water Resources, Underground Injection Control Program,
1636 Mail Service Center, Raleigh, NC 27699-1636
loc. For Water Supply & Iniection Wells: In addition to sending the form to the
address(es) above, also submit one copy of this form within 30 days of completion
of well abandonment to the county health department of the county where
abandoned.
Form GW-30 North Carolina Department of Environmental Quality - Division of Water Resources Revised 2-22-2016

WELL ABANDONMENT RECORD
1. Well Contractor Information:
Terry White
Well Contractor Name (or well owner personally abandoning well on his/her property)
3287-B
NC Well Contractor Certification Number
I ET
Company Name
2. Well Construction Permit #:
List all applicable well construction permits (i.e. UIC County, State, Variance, etc.) ifknown
3. Well use (check well use):
Water Supply Well:
❑Agricultural ❑Municipal/Public
❑Geothermal (Heating/Cooling Supply) ❑Residential Water Supply (single)
❑Industrial/Commercial ❑Residential Water Supply (shared)
❑Irrigation
Non -Water Supply Well:
❑Aquifer Recharge
❑Aquifer Storage and Recovery
❑Aquifer Test
❑Experimental Technology
❑Geothermal (Closed Loop)
El Geothermal (Heating/Cooling
El Groundwater Remediation
❑ Salinity Barrier
❑ Stormwater Drainage
El Subsidence Control
❑Tracer
El Other (explain under 7g)
4. Date well(s) abandoned: 1 /3/201 9
5a. Well location:
Former Witherspoon Nursery
Facility/Owner Name Facility ID# (if applicable)
3312 Watkins Rd.,Durham 27707
Physical Address, City, and Zip
Durham
County Parcel Identification No. (PIN)
5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees:
(if well field, one lat/long is sufficient)
35 57 05 N 78 59 24 W
CONSTRUCTION DETAILS OF WELL(S) BEING ABANDONED
Attach well construction record(s) ifavailable. For multiple injection or non -water supply wells
ONLY with the same constructionlabandonment, you can submit one form.
6a. Well ID#: TMW-4
6b. Total well depth: 25 (ft.)
6c. Borehole diameter: 6 (in.)
6d. Water level below ground surface: DRY (ft.)
6e. Outer casing length (if known):
6L Inner casing/tubing length (if known): 10 (ft.)
6g. Screen length (if known): 15 (ft.)
For Internal Use ONLY:
WELL ABANDONMENT DETAILS
7a. For Geoprobe/DPT or Closed -Loop Geothermal Wells having the same
well construction/depth, only 1 GW-30 is needed. Indicate TOTAL NUMBER of
wells abandoned: t
7b. Approximate volume of water remaining in well(s): 0 (gal.)
FOR WATER SUPPLY WELLS ONLY:
7c. Type of disinfectant used:
7d. Amount of disinfectant used:
7e. Sealing materials used (check all that apply):
❑ Neat Cement Grout S Bentonite Chips or Pellets
❑ Sand Cement Grout
❑ Concrete Grout
❑ Specialty Grout
❑ Bentonite Slurry
❑ Dry Clay
❑ Drill Cuttings
❑ Gravel
❑ Other (explain under 7g)
7f. For each material selected above, provide amount of materials used:
24 pounds
7g. Provide a brief description of the abandonment procedure:
Poured Bentonite from bottom to the top
8. Certification:
1 /4/2019
Signature qTertified Well Contractor or Well Owner Date
By signing this form, I hereby certify that the well(s) was (were) abandoned in
accordance with 1 SA NCAC 02C .0100 or 2C .0200 Well Construction Standards
and that a copy of this record has been provided to the well owner.
9. Site diagram or additional well details:
You may use the back of this page to provide additional well site details or well
abandonment details. You may also attach additional pages if necessary.
SUBMITTAL INSTRUCTIONS
10a. For All Wells: Submit this form within 30 days of completion of well
abandonment to the following:
Division of Water Resources, Information Processing Unit,
1617 Mail Service Center, Raleigh, NC 27699-1617
10b. For Infection Wells: In addition to sending the form to the address in 10a
above, also submit one copy of this form within 30 days of completion of well
abandonment to the following:
Division of Water Resources, Underground Injection Control Program,
1636 Mail Service Center, Raleigh, NC 27699-1636
loc. For Water Supply & Iniection Wells: In addition to sending the form to the
address(es) above, also submit one copy of this form within 30 days of completion
of well abandonment to the county health department of the county where
abandoned.
Form GW-30 North Carolina Department of Environmental Quality - Division of Water Resources Revised 2-22-2016

Appendix B
Laboratory Analytical Reports
hart hickman
SMAKtER ENVIRONMENTAL SOLUTIONS

O
�FaceAnalXical o
National Center for Testing & Innovation
r Ad
ANALYTICAL REPORT
January 22, 2019
Hart and Hickman, PC
Sample Delivery Group: L1058130
Samples Received: 01/04/2019
Project Number: CRP-001
Description: Former Witherspoon Nursey
Report To: Lisa Nickels
3334 Hillsborough Street
Raleigh, NC 27607
Entire Report Reviewed By: 4�41
Heather J Wagner
Project Manager
Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be
reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace National
is performed per guidance provided in laboratory standard operating procedures: 060302, 060303, and 060304.
V
F# 4
U
I &
4b

TABLE OF CONTENTS
ONE LAB. NATIONWIDE.
Cp: Cover Page
Tc: Table of Contents
Ss: Sample Summary
Cn: Case Narrative
Sr: Sample Results
SB-1 (4-5) L1058130-01
SB-2 (6-8) L1058130-02
DUP-SB L1058130-03
Qc: Quality Control Summary
Total Solids by Method 2540 G-2011
Wet Chemistry by Method 7199
Mercury by Method 7471B
Metals (ICPMS) by Method 6020B
Volatile Organic Compounds (GC/MS) by Method 8260B
Semi Volatile Organic Compounds (GC/MS) by Method 8270D
GI: Glossary of Terms
Al: Accreditations & Locations
Sc: Sample Chain of Custody
1
2
3
4
5
5
8
12
16
16
17
19
20
21
27
34
35
36
Fn
FS
[Cn]
Fr
RC
F,
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME:
Hart and Hickman, PC CRP-001 L1058130 01/22/19 07:19
PAGE:
2 of 36

SAMPLE
SUMMARY
ONE LAB. NATIONWIDE.
Collected by
Collected date/time
Received date/time
SB-1 (4-5) L1058130-01 Solid
Lisa Nickels
01/03/1909:45
01/04/1908:45
FP1
Method
Batch
Dilution
Preparation
Analysis
Analyst
date/time
date/time
FTC
Total Solids by Method 2540 G-2011
WG1219482
1
01/08/1916:21
01/08/1916:32
JD
Volatile Organic Compounds (GC/MS) by Method 8260B
WG1219549
1
01/03/19 09:45
01/05/1914:01
GLN
Semi Volatile Organic Compounds (GC/MS) by Method 8270D
WG1219776
1
01/06/1914:44
01/07/19 05:25
CLG
Collected by
Collected date/time
Received date/time
[Cn]
S13-2 (6-8) L1058130-02 Solid
Lisa Nickels
01/03/1914:20
01/04/1908:45
Method
Batch
Dilution
Preparation
Analysis
Analyst
FSr
date/time
date/time
Total Solids by Method 2540 G-2011
WG1219482
1
01/08/1916:21
01/08/1916:32
JD
6
QC
Wet Chemistry by Method 7199
WG1221753
1
01/11/1911:09
01/11/1915:40
MCG
Mercury by Method 7471E
WG1226350
1
01/21/1911:36
01/21/1914:51
ABL
Metals (ICPMS) by Method 6020B
WG1225859
5
01/19/1910:51
01/19/1915:09
JPD
GI
Volatile Organic Compounds (GC/MS) by Method 8260E
WG1219549
1
01/03/1914:20
01/05/1914:20
GLN
Semi Volatile Organic Compounds (GC/MS) by Method 8270D
WG1219776
1
01/06/1914:44
01/06/19 23:58
CLG
FAI
Collected by
Collected date/time
Received date/time
FSC
DUP-SB L1058130-03 Solid
Lisa Nickels
01/03/1900:00
01/04/1908:45
Method
Batch
Dilution
Preparation
Analysis
Analyst
date/time
date/time
Total Solids by Method 2540 G-2011
WG1219482
1
01/08/1916:21
01/08/1916:32
JD
Wet Chemistry by Method 7199
WG1221753
1
01/11/1911:09
01/11/1915:46
MCG
Mercury by Method 7471B
WG1226350
1
01/21/1911:36
01/21/1914:59
ABL
Metals (ICPMS) by Method 6020B
WG1225859
5
01/19/1910:51
01/19/1915:32
JPD
Volatile Organic Compounds (GC/MS) by Method 8260B
WG1219549
1
01/03/19 00:00
01/05/1914:39
GLN
Semi Volatile Organic Compounds (GC/MS) by Method 8270D
WG1219776
1
01/06/1914:44
01/07/19 00:22
CLG
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
PAGE:
Hart and Hickman, PC
CRP-001
L1058130
01/22/19 07:19
3 of 36

CASE NARRATIVE
ONE LAB. NATIONWIDE.
FP1
All sample aliquots were received at the correct temperature, in the proper containers, with the
appropriate preservatives, and within method specified holding times, unless qualified or notated within
the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples
FTChave
been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control
are within established criteria except where addressed in this case narrative, a non-conformance form
or properly qualified within the sample results. By my digital signature below, I affirm to the best of my
FSS
knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the
quality of the data have been identified by the laboratory, and no information or data have been
knowingly withheld that would affect the quality of the data.
FSr
FC-1
4�j
�GI
Heather J Wagner
FAI
Project Manager
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC CRP-001 L1058130 01/22/19 07:19 4 of 36

SB-1 (4-5) SAMPLE RESULTS - 01 ONE LAB. NATIONWIDE.
Collected date/time: 01/03/19 09:45 L1058130
Total Solids by Method 2540 G-2011
Result Qualifier Dilution Analysis
Analyte % date /time
Total Solids 83.0 1 01/08/201916:32
Volatile Organic Compounds (GC/MS) by Method 8260B
Batch
WG1219482
u
FTC
FSS
Result (dry)
Qualifier
MDL (dry)
RDL (dry)
Dilution Analysis
Batch
Analyte
mg/kg
mg/kg
mg/kg
date / time
4Cr1
Acetone
IJ
J3
0.0165
0.0301
1 01/05/201914:01
WG1219549
Acrylonitrile
IJ
0.00229
0.0151
1 01/05/201914:01
WG1219549
Benzene
IJ
0.000482
0.00120
1 01/05/201914:01
WG1219549
Bromobenzene
J
0.00126
0.0151
1 01/05/201914:01
WG1219549
Bromodichloromethane
IJ
J4
0.000949
0.00301
1 01/05/201914:01
WG1219549
6
QC
Bromoform
J
0.00720
0.0301
1 01/05/201914:01
WG1219549
Bromomethane
IJ
0.00446
0.0151
1 01/05/201914:01
WG1219549
n-Butylbenzene
IJ
0.00462
0.0151
1 01/05/201914:01
WG1219549
GI
sec -Butyl benzene
IJ
0.00305
0.0151
1 01/05/201914:01
WG1219549
ter[-Butylbenzene
IJ
0.00187
0.00602
1 01/05/201914:01
WG1219549
FAI
Carbon tetrachloride
IJ
0.00130
0.00602
1 01/05/201914:01
WG1219549
Chlorobenzene
IJ
0.000690
0.00301
1 01/05/201914:01
WG1219549
Chlorodibromomethane
IJ
0.000542
0.00301
1 01/05/201914:01
WG1219549
FSC
Chloroethane
IJ
0.00130
0.00602
1 01/05/201914:01
WG1219549
Chloroform
IJ
0.000500
0.00301
1 01/05/201914:01
WG1219549
Chloromethane
IJ
0.00167
0.0151
1 01/05/201914:01
WG1219549
2-Chlorotoluene
IJ
0.00111
0.00301
1 01/05/201914:01
WG1219549
4-Chlorotoluene
IJ
0.00136
0.00602
1 01/05/201914:01
WG1219549
1,2-Dibromo-3-Chloropropane
IJ
0.00614
0.0301
1 01/05/201914:01
WG1219549
1,2-Dibromoethane
IJ
0.000632
0.00301
1 01/05/201914:01
WG1219549
Dibromomethane
IJ
0.00120
0.00602
1 01/05/201914:01
WG1219549
1,2-Dichlorobenzene
J
0.00175
0.00602
1 01/05/201914:01
WG1219549
1,3-Dichlorobenzene
IJ
0.00205
0.00602
1 01/05/201914:01
WG1219549
1,4-Dichlorobenzene
IJ
0.00237
0.00602
1 01/05/201914:01
WG1219549
Dichlorodifluoromethane
IJ
0.000985
0.00301
1 01/05/201914:01
WG1219549
1,1-Dichloroethane
IJ
0.000692
0.00301
1 01/05/201914:01
WG1219549
1,2-Dichloroethane
IJ
0.000572
0.00301
1 01/05/201914:01
WG1219549
1,1-Dichloroethene
IJ
J3
0.000602
0.00301
1 01/05/201914:01
WG1219549
cis-1,2-Dichloroethene
IJ
0.000831
0.00301
1 01/05/201914:01
WG1219549
trans-1,2-Dichloroethene
IJ
0.00172
0.00602
1 01/05/201914:01
WG1219549
1,2-Dichloropropane
IJ
0.00153
0.00602
1 01/05/201914:01
WG1219549
1,1-Dichloropropene
IJ
J4
0.000843
0.00301
1 01/05/201914:01
WG1219549
1,3-Dichloropropane
IJ
0.00211
0.00602
1 01/05/201914:01
WG1219549
cis-1,3-Dichloropropene
IJ
0.000817
0.00301
1 01/05/201914:01
WG1219549
trans-1,3-Dichloropropene
IJ
0.00184
0.00602
1 01/05/201914:01
WG1219549
2,2-Dichloropropane
J
0.000955
0.00301
1 01/05/201914:01
WG1219549
Di -isopropyl ether
IJ
0.000422
0.00120
1 01/05/201914:01
WG1219549
Ethylbenzene
J
0.000638
0.00301
1 01/05/201914:01
WG1219549
Hexachloro-1,3-butadiene
IJ
0.0153
0.0301
1 01/05/201914:01
WG1219549
Isopropylbenzene
IJ
0.00104
0.00301
1 01/05/201914:01
WG1219549
p-Isopropyltoluene
IJ
0.00281
0.00602
1 01/05/201914:01
WG1219549
2-Butanone (MEK)
IJ
0.0151
0.0301
1 01/05/201914:01
WG1219549
Methylene Chloride
IJ
J3
0.00800
0.0301
1 01/05/201914:01
WG1219549
4-Methyl-2-pentanone (MIBK)
IJ
0.0120
0.0301
1 01/05/201914:01
WG1219549
Methyl tert-butyl ether
IJ
0.000355
0.00120
1 01/05/201914:01
WG1219549
Naphthalene
IJ
0.00376
0.0151
1 01/05/201914:01
WG1219549
n-Propylbenzene
IJ
0.00142
0.00602
1 01/05/201914:01
WG1219549
Styrene
IJ
0.00329
0.0151
1 01/05/201914:01
WG1219549
1,1,1,2-Tetrachloroethane
IJ
J4
0.000602
0.00301
1 01/05/201914:01
WG1219549
1,1,2,2-Tetrachloroethane
IJ
0.000470
0.00301
1 01/05/201914:01
WG1219549
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
PAGE:
Hart and Hickman,
PC
CRP-001
L1058130
01/22/19 07:19
5 of 36

ONE LAB. NATIONWIDE.
SB-1 (4-5) SAMPLE RESULTS - 01
Collected date/time: 01/03/19 09:45 L1058130
Volatile Organic Compounds (GC/MS) by Method 8260B
Result (dry)
Qualifier MDL (dry)
RDL (dry)
Dilution Analysis
Batch
Analyte
mg/kg
mg/kg
mg/kg
date / time
1,1,2-Trichlorotrifluoroethane
U
J3 0.000813
0.00301
1 01/05/201914:01
WG1219549
Tetrachloroethene
U
0.000843
0.00301
1 01/05/201914:01
WG1219549
Toluene
U
0.00151
0.00602
1 01/05/201914:01
WG1219549
1,2,3-Trichlorobenzene
U
0.000753
0.00301
1 01/05/201914:01
WG1219549
1,2,4-Trichlorobenzene
U
0.00580
0.0151
1 01/05/201914:01
WG1219549
1,1,1-Trichloroethane
U
0.000331
0.00301
1 01/05/201914:01
WG1219549
1,1,2-Trichloroethane
U
0.00106
0.00301
1 01/05/201914:01
WG1219549
Trichloroethene
U
J4 0.000482
0.00120
1 01/05/201914:01
WG1219549
Trichlorofluoromethane
U
0.000602
0.00301
1 01/05/201914:01
WG1219549
1,2,3-Trichloropropane
U
0.00614
0.0151
1 01/05/201914:01
WG1219549
1,2,4-Trimethylbenzene
U
0.00140
0.00602
1 01/05/201914:01
WG1219549
1,2,3-Trimethyl benzene
U
0.00138
0.00602
1 01/05/201914:01
WG1219549
1,3,5-Trimethyl benzene
U
0.00130
0.00602
1 01/05/201914:01
WG1219549
Vinyl chloride
U
0.000823
0.00301
1 01/05/201914:01
WG1219549
Xylenes, Total
U
0.00576
0.00783
1 01/05/201914:01
WG1219549
(S) Toluene-d8
107
75.0-131
011051201914:01
WG1219549
(S) Dibromofluoromethane
89.6
65.0-129
011051201914:01
WG1219549
(S) 4-Bromof/uorobenzene
101
67.0-138
011051201914:01
WG1219549
Semi Volatile Organic Compounds (GC/MS) by Method 8270D
Result (dry)
Qualifier MDL (dry)
RDL (dry)
Dilution Analysis
Batch
Analyte
mg/kg
mg/kg
mg/kg
date / time
Acenaphthene
U
0.00773
0.0401
1 01/07/2019 05:25
WG1219776
Acenaphthylene
U
0.00808
0.0401
1 01/07/2019 05:25
WG1219776
Anthracene
U
0.00761
0.0401
1 01/07/2019 05:25
WG1219776
Acetophenone
U
0.0906
0.401
1 01/07/2019 05:25
WG1219776
Atrazine
U
0.113
0.401
1 01/07/2019 05:25
WG1219776
Benzaldehyde
U
0.0641
0.401
1 01/07/2019 05:25
WG1219776
Benzidine
U
J4 J6 0.0767
0.401
1 01/07/2019 05:25
WG1219776
Benzo(a)anth race ne
U
0.00515
0.0401
1 01/07/2019 05:25
WG1219776
Benzo(b)fluoranthene
U
0.00837
0.0401
1 01/07/2019 05:25
WG1219776
Benzo(k)fluoranthene
U
0.00701
0.0401
1 01/07/2019 05:25
WG1219776
Benzo(g,h,i)perylene
U
0.00868
0.0401
1 01/07/2019 05:25
WG1219776
Benzo(a)pyrene
U
0.00660
0.0401
1 01/07/2019 05:25
WG1219776
Benzyl alcohol
U
J3 0.00903
0.401
1 01/07/2019 05:25
WG1219776
Biphenyl
U
0.00708
0.401
1 01/07/2019 05:25
WG1219776
Bis(2-chlorethoxy)methane
U
0.00927
0.401
1 01/07/2019 05:25
WG1219776
Bis(2-chloroethyl)ether
U
0.0108
0.401
1 01/07/2019 05:25
WG1219776
Bis(2-chloroisopropyl)ether
U
0.00915
0.401
1 01/07/2019 05:25
WG1219776
4-Bromophenyl-phenylether
U
0.0137
0.401
1 01/07/2019 05:25
WG1219776
2-Chloronaphthalene
U
0.00770
0.0401
1 01/07/2019 05:25
WG1219776
4-Chlorophenyl-phenylether
U
0.00755
0.401
1 01/07/2019 05:25
WG1219776
Caprolactam
U
0.125
0.401
1 01/07/2019 05:25
WG1219776
Carbazole
U
0.00631
0.401
1 01/07/2019 05:25
WG1219776
4-Chloroaniline
U
0.0424
0.401
1 01/07/2019 05:25
WG1219776
Chrysene
U
0.00668
0.0401
1 01/07/2019 05:25
WG1219776
Dibenz(a,h)anthracene
U
0.00989
0.0401
1 01/07/2019 05:25
WG1219776
Dibenzofuran
U
0.00624
0.401
1 01/07/2019 05:25
WG1219776
1,2-Dichlorobenzene
U
0.0111
0.401
1 01/07/2019 05:25
WG1219776
1,3-Dichlorobenzene
U
0.0120
0.401
1 01/07/2019 05:25
WG1219776
1,4-Dichlorobenzene
U
0.0120
0.401
1 01/07/2019 05:25
WG1219776
3,3-Dichlorobenzidine
U
0.0956
0.401
1 01/07/2019 05:25
WG1219776
2,4-Dinitrotoluene
U
0.00731
0.401
1 01/07/2019 05:25
WG1219776
2,6-Dinitrotoluene
U
0.00888
0.401
1 01/07/2019 05:25
WG1219776
1,2-Diphenylhydrazine
U
0.00636
0.401
1 01/07/2019 05:25
WG1219776
Fluoranthene
U
0.00597
0.0401
1 01/07/2019 05:25
WG1219776
Fp
FTc
FSS
[Cn]
Fc
I ql
FAI
[Sc
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC CRP-001 L1058130 01/22/19 07:19 6 of 36

ONE LAB. NATIONWIDE.
SB-1 (4-5) SAMPLE RESULTS - 01
Collected date/time: 01/03/19 09:45 L1058130
Semi Volatile Organic Compounds (GC/MS) by Method 8270D
Result (dry)
Qualifier MDL (dry)
RDL (dry)
Analyte
mg/kg
mg/kg
mg/kg
Fluorene
U
0.00821
0.0401
Hexachlorobenzene
U
0.0103
0.401
Hexachloro-1,3-butadiene
U
0.0120
0.401
Hexachlorocyclopentadiene
U
0.0707
0.401
Hexachloroethane
U
0.0161
0.401
Indeno(1,2,3-cd)pyrene
u
0.00930
0.0401
Isophorone
U
0.00629
0.401
2-Methylnaphthalene
U
0.0104
0.0401
2-Nitroaniline
U
0.00909
0.401
3-Nitroaniline
U
0.0102
0.401
4-Nitroaniline
U
0.00770
0.401
Naphthalene
U
0.0107
0.0401
Nitrobenzene
U
0.00837
0.401
n-Nitrosodimethyla mine
U
0.0779
0.401
n-Nitrosodiphenyla mine
U
0.108
0.401
n-Nitrosodi-n-propylamine
U
0.0109
0.401
Phenanthrene
U
0.00636
0.0401
Benzylbutyl phthalate
U
0.0124
0.401
Bis(2-ethylhexyl)phthalate
U
0.0145
0.401
Di-n-butyl phthalate
U
0.0131
0.401
Diethyl phthalate
U
0.00832
0.401
Dimethyl phthalate
U
0.00650
0.401
Di-n-octyl phthalate
U
0.0109
0.401
Pyrene
U
0.0148
0.0401
1,2,4-Trichlorobenzene
U
0.0105
0.401
4-ChIoro-3-methyl phenol
U
0.00574
0.401
2-Chlorophenol
U
0.0100
0.401
2,4-Dichlorophenol
U
0.00898
0.401
2,4-Dimethylphenol
U
0.0567
0.401
4,6-Dinitro-2-methylphenol
U
0.149
0.401
2,4-Dinitrophenol
U
0.118
0.401
2-Methylphenol
U
0.0119
0.401
3&4-Methyl Phenol
U
0.00943
0.401
2-Nitrophenol
U
0.0157
0.401
4-Nitrophenol
U
0.0632
0.401
Pentachlorophenol
U
0.0578
0.401
Phenol
U
0.00837
0.401
2,4,5-Trichlorophenol
U
0.0125
0.401
2,4,6-Trichlorophenol
U
0.00938
0.401
(S) 2-F/uorophenol
54.6
12.0-120
(S) Phenol-d5
48.1
10.0-120
(S) Nitrobenzene-d5
49.5
10.0-122
(S) 2-Fluorobiphenyl
51.7
15.0-120
(S)2,4,6-Tribromopheno/
57.7
10.0-127
(S) p-Terphenyl-d14
53.0
10.0-120
Dilution Analysis Batch
date / time
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
01/07/2019 05:25
0110712019 05:25
0110712019 05:25
0110712019 05:25
0110712019 05:25
0110712019 05:25
0110712019 05:25
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
FP
FTc
FSS
[Cn]
Fc
F
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME:
Hart and Hickman, PC CRP-001 L1058130 01/22/19 07:19
PAGE:
7 of 36

SB-2 (6-8)
Collected date/time: 01/03/19 14:20
Total Solids by Method 2540 G-2011
SAMPLE RESULTS - 02
L1058130
Result Qualifier Dilution Analysis Batch
Analyte % date / time
Total Solids 78.9 1 01/08/201916:32 WG1219482
Wet Chemistry by Method 7199
Result (dry)
Analyte mg/kg
Hexavalent Chromium u
Mercury by Method 7471B
Result (dry)
Analyte mg/kg
Mercury 0.0110
Metals (ICPMS) by Method 6020B
Qualifier MDL (dry) RDL (dry) Dilution Analysis
mg/kg mg/kg date / time
0.323 1.27 1 01/11/201915:40
Qualifier MDL (dry) RDL (dry) Dilution Analysis
mg/kg mg/kg date / time
ONE LAB. NATIONWIDE.
FP1
FTC
FSS
Batch
r
WG1221753 Cn
Batch
FQ-C1
J J3 J6 0.00355 0.0253 1 01/21/201914:51 WG1226350
FGI
Result (dry)
Qualifier
MDL (dry)
RDL (dry)
Dilution
Analysis
Analyte
mg/kg
mg/kg
mg/kg
date / time
Arsenic
1.00
0.158
0.634
5
01/19/201915:09
Barium
101
J6
0.203
1.27
5
01/19/201915:09
Cadmium
0.422
1_
0.101
0.634
5
01/19/201915:09
Chromium
20.4
0.342
1.27
5
01/19/201915:09
Lead
8.40
0.152
0.634
5
01/19/201915:09
Selenium
0.385
1_
0.241
0.634
5
01/19/201915:09
Silver
u
0.196
0.634
5
01/19/201915:09
Volatile Organic Compounds (GC/MS) by Method
8260B
Analyte
Acetone
Acrylonitrile
Benzene
Bromobenzene
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec -Butyl benzene
ter[-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dibromoethane
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
Result (dry)
mg/kg
u
J
u
J
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
J
u
u
u
u
u
u
u
u
ACCOUNT:
Hart and Hickman, PC
Batch [Al
WG1225859 FSC
WG1225859
WG1225859
WG1225859
WG1225859
WG1225859
WG1225859
Qualifier
MDL (dry)
RDL (dry)
Dilution Analysis
Batch
mg/kg
mg/kg
date / time
J3
0.0174
0.0317
1 01/05/201914:20
WG1219549
0.00241
0.0158
1 01/05/201914:20
WG1219549
0.000507
0.00127
1 01/05/201914:20
WG1219549
0.00133
0.0158
1 01/05/201914:20
WG1219549
J4
0.000999
0.00317
1 01/05/201914:20
WG1219549
0.00758
0.0317
1 01/05/201914:20
WG1219549
0.00469
0.0158
1 01/05/201914:20
WG1219549
0.00487
0.0158
1 01/05/201914:20
WG1219549
0.00321
0.0158
1 01/05/201914:20
WG1219549
0.00196
0.00634
1 01/05/201914:20
WG1219549
0.00137
0.00634
1 01/05/201914:20
WG1219549
0.000726
0.00317
1 01/05/201914:20
WG1219549
0.000570
0.00317
1 01/05/201914:20
WG1219549
0.00137
0.00634
1 01/05/201914:20
WG1219549
0.000526
0.00317
1 01/05/201914:20
WG1219549
0.00176
0.0158
1 01/05/201914:20
WG1219549
0.00117
0.00317
1 01/05/201914:20
WG1219549
0.00143
0.00634
1 01/05/201914:20
WG1219549
0.00646
0.0317
1 01/05/201914:20
WG1219549
0.000665
0.00317
1 01/05/201914:20
WG1219549
0.00127
0.00634
1 01/05/201914:20
WG1219549
0.00184
0.00634
1 01/05/201914:20
WG1219549
0.00215
0.00634
1 01/05/201914:20
WG1219549
0.00250
0.00634
1 01/05/201914:20
WG1219549
0.00104
0.00317
1 01/05/201914:20
WG1219549
0.000729
0.00317
1 01/05/201914:20
WG1219549
0.000602
0.00317
1 01/05/201914:20
WG1219549
J3
0.000634
0.00317
1 01/05/201914:20
WG1219549
PROJECT:
SDG:
DATE/TIME:
CRP-001
L1058130
01/22/19 07:19
PAGE:
8 of 36

SB-2 (6-8)
SAMPLE
RESULTS - 02
ONE LAB. NATIONWIDE.
Collected date/time: 01/03/19 14:20
L1058130
Volatile Organic Compounds (GC/MS) by Method 8260B
Result (dry)
Qualifier
MDL (dry)
RDL (dry)
Dilution Analysis
Batch
F
Analyte
mg/kg
mg/kg
mg/kg
date / time
cis-1,2-Dichloroethene
U
0.000874
0.00317
1 01/05/201914:20
WG1219549
Z
Tc
trans-1,2-Dichloroethene
U
0.00181
0.00634
1 01/05/201914:20
WG1219549
1,2-Dichloropropane
U
0.00161
0.00634
1 01/05/201914:20
WG1219549
1,1-Dichloropropene
U
J4
0.000887
0.00317
1 01/05/201914:20
WG1219549
F
1,3-Dichloropropane
U
0.00222
0.00634
1 01/05/201914:20
WG1219549
cis-1,3-Dichloropropene
U
0.000859
0.00317
1 01/05/201914:20
WG1219549
[Cn]
trans-1,3-Dichloropropene
U
0.00194
0.00634
1 01/05/201914:20
WG1219549
2,2-Dichloropropane
U
0.00100
0.00317
1 01/05/201914:20
WG1219549
Di -isopropyl ether
U
0.000444
0.00127
1 01/05/201914:20
WG1219549
Ethylbenzene
U
0.000672
0.00317
1 01/05/201914:20
WG1219549
Hexachloro-1,3-butadiene
U
0.0161
0.0317
1 01/05/201914:20
WG1219549
Fc
Isopropylbenzene
U
0.00109
0.00317
1 01/05/201914:20
WG1219549
p-Isopropyltoluene
U
0.00295
0.00634
1 01/05/201914:20
WG1219549
2-Butanone (MEK)
U
0.0158
0.0317
1 01/05/201914:20
WG1219549
ql
Methylene Chloride
U
J3
0.00841
0.0317
1 01/05/201914:20
WG1219549
4-Methyl-2-pentanone (MIBK)
U
0.0127
0.0317
1 01/05/201914:20
WG1219549
FAI
Methyl tert-butyl ether
U
0.000374
0.00127
1 01/05/201914:20
WG1219549
Naphthalene
U
0.00395
0.0158
1 01/05/201914:20
WG1219549
n-Propylbenzene
U
0.00150
0.00634
1 01/05/201914:20
WG1219549
FSC
Styrene
U
0.00346
0.0158
1 01/05/201914:20
WG1219549
1,1,1,2-Tetrachloroethane
U
J4
0.000634
0.00317
1 01/05/201914:20
WG1219549
1,1,2,2-Tetrachloroethane
U
0.000494
0.00317
1 01/05/201914:20
WG1219549
1,1,2-Trichlorotrifluoroethane
U
J3
0.000855
0.00317
1 01/05/201914:20
WG1219549
Tetrachloroethene
U
0.000887
0.00317
1 01/05/201914:20
WG1219549
Toluene
U
0.00158
0.00634
1 01/05/201914:20
WG1219549
1,2,3-Trichlorobenzene
U
0.000792
0.00317
1 01/05/201914:20
WG1219549
1,2,4-Trichlorobenzene
U
0.00611
0.0158
1 01/05/201914:20
WG1219549
1,1,1-Trichloroethane
U
0.000348
0.00317
1 01/05/201914:20
WG1219549
1,1,2-Trichloroethane
U
0.00112
0.00317
1 01/05/201914:20
WG1219549
Trichloroethene
U
J4
0.000507
0.00127
1 01/05/201914:20
WG1219549
Trichlorofluoromethane
U
0.000634
0.00317
1 01/05/201914:20
WG1219549
1,2,3-Trichloropropane
U
0.00646
0.0158
1 01/05/201914:20
WG1219549
1,2,4-Trimethylbenzene
U
0.00147
0.00634
1 01/05/201914:20
WG1219549
1,2,3-Trimethyl benzene
U
0.00146
0.00634
1 01/05/201914:20
WG1219549
1,3,5-Trimethyl benzene
U
0.00137
0.00634
1 01/05/201914:20
WG1219549
Vinyl chloride
U
0.000866
0.00317
1 01/05/201914:20
WG1219549
Xylenes, Total
U
0.00606
0.00824
1 01/05/201914:20
WG1219549
(S) Toluene-d8
108
75.0-131
011051201914:20
WG1219549
(S) Dibromofluoromeftne
94.5
65.0-129
011051201914:20
WG1219549
(S) 4-Bromof/uorobenzene
104
67.0-138
011051201914:20
WG1219549
Semi Volatile Organic Compounds
(GC/MS) by Method 8270D
Result (dry)
Qualifier
MDL (dry)
RDL (dry)
Dilution Analysis
Batch
Analyte
mg/kg
mg/kg
mg/kg
date / time
Acenaphthene
U
0.00814
0.0422
1 01/06/2019 23:58
WG1219776
Acenaphthylene
U
0.00850
0.0422
1 01/06/2019 23:58
WG1219776
Anthracene
U
0.00801
0.0422
1 01/06/2019 23:58
WG1219776
Acetophenone
U
0.0953
0.422
1 01/06/2019 23:58
WG1219776
Atrazine
U
0.119
0.422
1 01/06/2019 23:58
WG1219776
Benzaldehyde
U
0.0674
0.422
1 01/06/2019 23:58
WG1219776
Benzidine
U
J4
0.0807
0.422
1 01/06/2019 23:58
WG1219776
Benzo(a)anth race ne
U
0.00542
0.0422
1 01/06/2019 23:58
WG1219776
Benzo(b)fluoranthene
U
0.00881
0.0422
1 01/06/2019 23:58
WG1219776
Benzo(k)fluoranthene
U
0.00738
0.0422
1 01/06/2019 23:58
WG1219776
Benzo(g,h,i)perylene
U
0.00914
0.0422
1 01/06/2019 23:58
WG1219776
Benzo(a)pyrene
U
0.00694
0.0422
1 01/06/2019 23:58
WG1219776
ACCOUNT:
PROJECT:
SDG:
DATE/TIME: PAGE:
Hart and Hickman,
PC
CRP-001
L1058130
01/22/19 07:19 9 of 36

SB-2 (6-8) SAMPLE RESULTS - 02 ONE LAB. NATIONWIDE.
Collected date/time: 01/03/19 14:20 L1058130
Semi Volatile Organic Compounds (GC/MS) by Method 8270D
Result (dry)
Qualifier MDL (dry)
RDL (dry)
Dilution Analysis
Batch
I Cl7
Analyte
mg/kg
mg/kg
mg/kg
date / time
u
Benzyl alcohol
U
0.00950
0.422
1 01/06/2019 23:58
WG1219776
FTc
Biphenyl
U
0.00745
0.422
1 01/06/2019 23:58
WG1219776
Bis(2-chlorethoxy)methane
U
0.00976
0.422
1 01/06/2019 23:58
WG1219776
Bis(2-chloroethyl)ether
U0.0114
0.422
1 01/06/2019 23:58
WG1219776
FSS
Bis(2-chloroisopropyl)ether
U
0.00963
0.422
1 01/06/2019 23:58
WG1219776
4-Bromophenyl-phenylether
u
0.0144
0.422
1 01/06/2019 23:58
WG1219776
[Cn]
2-Chloronaphthalene
U
0.00810
0.0422
1 01/06/2019 23:58
WG1219776
4-Chlorophenyl-phenylether
U
0.00795
0.422
1 01/06/2019 23:58
WG1219776
Caprolactam
U
0.132
0.422
1 01/06/2019 23:58
WG1219776
Carbazole
U
0.00664
0.422
1 01/06/2019 23:58
WG1219776
4-Chloroaniline
U
0.0446
0.422
1 01/06/2019 23:58
WG1219776
Fc
Chrysene
U
0.00703
0.0422
1 01/06/2019 23:58
WG1219776
Dibenz(a,h)anthracene
U
0.0104
0.0422
1 01/06/2019 23:58
WG1219776
Dibenzofuran
U
0.00656
0.422
1 01/06/2019 23:58
WG1219776
GI
1,2-Dichlorobenzene
U
0.0117
0.422
1 01/06/2019 23:58
WG1219776
1,3-Dichlorobenzene
U
0.0127
0.422
1 01/06/2019 23:58
WG1219776
FAI
1,4-Dichlorobenzene
U
0.0127
0.422
1 01/06/2019 23:58
WG1219776
3,3-Dichlorobenzidine
U
0.101
0.422
1 01/06/2019 23:58
WG1219776
2,4-Dinitrotoluene
U
0.00769
0.422
1 01/06/2019 23:58
WG1219776
F
2,6-Dinitrotoluene
U
0.00934
0.422
1 01/06/2019 23:58
WG1219776
1,2-Diphenylhydrazine
U
0.00669
0.422
1 01/06/2019 23:58
WG1219776
Fluoranthene
U
0.00629
0.0422
1 01/06/2019 23:58
WG1219776
Fluorene
U
0.00864
0.0422
1 01/06/2019 23:58
WG1219776
Hexachlorobenzene
U
0.0108
0.422
1 01/06/2019 23:58
WG1219776
Hexachloro-1,3-butadiene
U
0.0127
0.422
1 01/06/2019 23:58
WG1219776
Hexachlorocyclopentadiene
U
0.0744
0.422
1 01/06/2019 23:58
WG1219776
Hexachloroethane
U
0.0170
0.422
1 01/06/2019 23:58
WG1219776
Indeno(1,2,3-cd)pyrene
U
0.00978
0.0422
1 01/06/2019 23:58
WG1219776
Isophorone
U
0.00661
0.422
1 01/06/2019 23:58
WG1219776
2-Methylnaphthalene
U
0.0109
0.0422
1 01/06/2019 23:58
WG1219776
2-Nitroaniline
U
0.00957
0.422
1 01/06/2019 23:58
WG1219776
3-Nitroaniline
U
0.0108
0.422
1 01/06/2019 23:58
WG1219776
4-Nitroaniline
U
0.00810
0.422
1 01/06/2019 23:58
WG1219776
Naphthalene
U
0.0113
0.0422
1 01/06/2019 23:58
WG1219776
Nitrobenzene
U
0.00881
0.422
1 01/06/2019 23:58
WG1219776
n-Nitrosodimethyla mine
U
0.0820
0.422
1 01/06/2019 23:58
WG1219776
n-Nitrosodiphenyla mine
U
0.114
0.422
1 01/06/2019 23:58
WG1219776
n-Nitrosodi-n-propylamine
u
0.0115
0.422
1 01/06/2019 23:58
WG1219776
Phenanthrene
U
0.00669
0.0422
1 01/06/2019 23:58
WG1219776
Benzylbutyl phthalate
U
0.0131
0.422
1 01/06/2019 23:58
WG1219776
Bis(2-ethylhexyl)phthalate
U
0.0152
0.422
1 01/06/2019 23:58
WG1219776
Di-n-butyl phthalate
U
0.0138
0.422
1 01/06/2019 23:58
WG1219776
Diethyl phthalate
U
0.00876
0.422
1 01/06/2019 23:58
WG1219776
Dimethyl phthalate
U
0.00684
0.422
1 01/06/2019 23:58
WG1219776
Di-n-octyl phthalate
U
0.0115
0.422
1 01/06/2019 23:58
WG1219776
Pyrene
U
0.0156
0.0422
1 01/06/2019 23:58
WG1219776
1,2,4-Trichlorobenzene
U
0.0111
0.422
1 01/06/2019 23:58
WG1219776
4-ChIoro-3-methyl phenol
U
0.00604
0.422
1 01/06/2019 23:58
WG1219776
2-Chlorophenol
U
0.0105
0.422
1 01/06/2019 23:58
WG1219776
2,4-Dichlorophenol
U
0.00945
0.422
1 01/06/2019 23:58
WG1219776
2,4-Dimethylphenol
U
0.0597
0.422
1 01/06/2019 23:58
WG1219776
4,6-Dinitro-2-methylphenol
U
0.157
0.422
1 01/06/2019 23:58
WG1219776
2,4-Dinitrophenol
U
0.124
0.422
1 01/06/2019 23:58
WG1219776
2-Methylphenol
U
0.0125
0.422
1 01/06/2019 23:58
WG1219776
3&4-Methyl Phenol
U
0.00992
0.422
1 01/06/2019 23:58
WG1219776
2-Nitrophenol
U
0.0165
0.422
1 01/06/2019 23:58
WG1219776
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
PAGE:
Hart and Hickman,
PC
CRP-001
L1058130
01/22/19 07:19
10 of 36

ONE LAB. NATIONWIDE.
SB-2 (6-8) SAMPLE RESULTS - 02
Collected date/time: 01/03/19 14:20 L1058130
Semi Volatile Organic Compounds (GC/MS) by Method 8270D
Result (dry)
Qualifier MDL (dry)
RDL (dry)
Dilution Analysis
Analyte
mg/kg
mg/kg
mg/kg
date / time
4-Nitrophenol
U
0.0665
0.422
1 01/06/2019 23:58
Pentachlorophenol
U
0.0608
0.422
1 01/06/2019 23:58
Phenol
U
0.00881
0.422
1 01/06/2019 23:58
2,4,5-Trichlorophenol
U
0.0132
0.422
1 01/06/2019 23:58
2,4,6-Trichlorophenol
U
0.00987
0.422
1 01/06/2019 23:58
(S) 2-F/uorophenol
71.1
12.0-120
0110612019 23:58
(S) Phenol-d5
63.8
10.0-120
0110612019 23:58
(S) Nitrobenzene-d5
65.7
10.0-122
0110612019 23:58
(S) 2-Fluorobiphenyl
64.1
15.0-120
0110612019 23:58
(S)2,4,6-Tribromopheno/
69.8
10.0-127
0110612019 23:58
(S) p-Terphenyl-d14
67.6
10.0-120
0110612019 23:58
Batch
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
FP
FTc
FSS
[Cn]
Fc
F,
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC CRP-001 L1058130 01/22/19 07:19 11 of 36

DUP-SB
Collected date/time: 01/03/19 00:00
Total Solids by Method 2540 G-2011
SAMPLE RESULTS - 03
L1058130
Result Qualifier Dilution Analysis Batch
Analyte % date / time
Total Solids 83.7 1 01/08/201916:32 WG1219482
Wet Chemistry by Method 7199
Result (dry)
Analyte mg/kg
Hexavalent Chromium U
Mercury by Method 7471B
Result (dry)
Analyte mg/kg
Mercury 0.0113
Metals (ICPMS) by Method 6020B
Qualifier MDL (dry) RDL (dry) Dilution Analysis
mg/kg mg/kg date / time
0.305 1.19 1 01/11/201915:46
Qualifier MDL (dry) RDL (dry) Dilution Analysis
mg/kg mg/kg date / time
ONE LAB. NATIONWIDE.
FP1
FTc
FSS
Batch
r
WG1221753 Cn
F-C]
0.00334 0.0239 1 01/21/201914:59 WG1226350
FGI
Result (dry)
Qualifier MDL (dry)
RDL (dry)
Dilution
Analysis
Analyte
mg/kg
mg/kg
mg/kg
date / time
Arsenic
3.02
0.149
0.597
5
01/19/201915:32
Barium
127
0.191
1.19
5
01/19/201915:32
Cadmium
0.276
J 0.0955
0.597
5
01/19/201915:32
Chromium
30.9
0.322
1.19
5
01/19/201915:32
Lead
11.9
0.143
0.597
5
01/19/201915:32
Selenium
0.559
1_ 0.227
0.597
5
01/19/201915:32
Silver
U
0.185
0.597
5
01/19/201915:32
Volatile Organic Compounds (GC/MS) by Method 8260B
Analyte
Acetone
Acrylonitrile
Benzene
Bromobenzene
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec -Butyl benzene
ter[-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dibromoethane
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
Result (dry)
mg/kg
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
ACCOUNT:
Hart and Hickman, PC
Batch
Batch [Al
WG1225859 FSC
WG1225859
WG1225859
WG1225859
WG1225859
WG1225859
WG1225859
Qualifier
MDL (dry)
RDL (dry)
Dilution Analysis
Batch
mg/kg
mg/kg
date / time
J3
0.0164
0.0299
1 01/05/201914:39
WG1219549
0.00227
0.0149
1 01/05/201914:39
WG1219549
0.000478
0.00119
1 01/05/201914:39
WG1219549
0.00125
0.0149
1 01/05/201914:39
WG1219549
J4
0.000941
0.00299
1 01/05/201914:39
WG1219549
0.00714
0.0299
1 01/05/201914:39
WG1219549
0.00442
0.0149
1 01/05/201914:39
WG1219549
0.00459
0.0149
1 01/05/201914:39
WG1219549
0.00302
0.0149
1 01/05/201914:39
WG1219549
0.00185
0.00597
1 01/05/201914:39
WG1219549
0.00129
0.00597
1 01/05/201914:39
WG1219549
0.000684
0.00299
1 01/05/201914:39
WG1219549
0.000537
0.00299
1 01/05/201914:39
WG1219549
0.00129
0.00597
1 01/05/201914:39
WG1219549
0.000496
0.00299
1 01/05/201914:39
WG1219549
0.00166
0.0149
1 01/05/201914:39
WG1219549
0.00110
0.00299
1 01/05/201914:39
WG1219549
0.00135
0.00597
1 01/05/201914:39
WG1219549
0.00609
0.0299
1 01/05/201914:39
WG1219549
0.000627
0.00299
1 01/05/201914:39
WG1219549
0.00119
0.00597
1 01/05/201914:39
WG1219549
0.00173
0.00597
1 01/05/201914:39
WG1219549
0.00203
0.00597
1 01/05/201914:39
WG1219549
0.00235
0.00597
1 01/05/201914:39
WG1219549
0.000977
0.00299
1 01/05/201914:39
WG1219549
0.000687
0.00299
1 01/05/201914:39
WG1219549
0.000567
0.00299
1 01/05/201914:39
WG1219549
J3
0.000597
0.00299
1 01/05/201914:39
WG1219549
PROJECT:
SDG:
DATE/TIME:
CRP-001
L1058130
01/22/19 07:19
PAGE:
12 of 36

DUP-SB
SAMPLE
RESULTS - 03
ONE LAB. NATIONWIDE.
Collected date/time: 01/03/19 00:00
L1058130
Volatile Organic Compounds (GC/MS) by Method 8260B
Result (dry)
Qualifier
MDL (dry)
RDL (dry)
Dilution Analysis
Batch
F
Analyte
mg/kg
mg/kg
mg/kg
date / time
cis-1,2-Dichloroethene
U
0.000824
0.00299
1 01/05/201914:39
WG1219549
Z
Tc
trans-1,2-Dichloroethene
U
0.00171
0.00597
1 01/05/201914:39
WG1219549
1,2-Dichloropropane
U
0.00152
0.00597
1 01/05/201914:39
WG1219549
1,1-Dichloropropene
U
J4
0.000836
0.00299
1 01/05/201914:39
WG1219549
F
1,3-Dichloropropane
U
0.00209
0.00597
1 01/05/201914:39
WG1219549
cis-1,3-Dichloropropene
U
0.000810
0.00299
1 01/05/201914:39
WG1219549
[Cn]
trans-1,3-Dichloropropene
U
0.00183
0.00597
1 01/05/201914:39
WG1219549
2,2-Dichloropropane
U
0.000947
0.00299
1 01/05/201914:39
WG1219549
Di -isopropyl ether
U
0.000418
0.00119
1 01/05/201914:39
WG1219549
Ethylbenzene
U
0.000633
0.00299
1 01/05/201914:39
WG1219549
Hexachloro-1,3-butadiene
U
0.0152
0.0299
1 01/05/201914:39
WG1219549
Fc
Isopropylbenzene
U
0.00103
0.00299
1 01/05/201914:39
WG1219549
p-Isopropyltoluene
U
0.00278
0.00597
1 01/05/201914:39
WG1219549
2-Butanone (MEK)
U
0.0149
0.0299
1 01/05/201914:39
WG1219549
ql
Methylene Chloride
U
J3
0.00793
0.0299
1 01/05/201914:39
WG1219549
4-Methyl-2-pentanone (MIBK)
U
0.0119
0.0299
1 01/05/201914:39
WG1219549
FAI
Methyl tert-butyl ether
U
0.000352
0.00119
1 01/05/201914:39
WG1219549
Naphthalene
U
0.00373
0.0149
1 01/05/201914:39
WG1219549
n-Propylbenzene
U
0.00141
0.00597
1 01/05/201914:39
WG1219549
FSC
Styrene
U
0.00326
0.0149
1 01/05/201914:39
WG1219549
1,1,1,2-Tetrachloroethane
U
J4
0.000597
0.00299
1 01/05/201914:39
WG1219549
1,1,2,2-Tetrachloroethane
U
0.000466
0.00299
1 01/05/201914:39
WG1219549
1,1,2-Trichlorotrifluoroethane
U
J3
0.000806
0.00299
1 01/05/201914:39
WG1219549
Tetrachloroethene
U
0.000836
0.00299
1 01/05/201914:39
WG1219549
Toluene
U
0.00149
0.00597
1 01/05/201914:39
WG1219549
1,2,3-Trichlorobenzene
U
0.000746
0.00299
1 01/05/201914:39
WG1219549
1,2,4-Trichlorobenzene
U
0.00576
0.0149
1 01/05/201914:39
WG1219549
1,1,1-Trichloroethane
U
0.000328
0.00299
1 01/05/201914:39
WG1219549
1,1,2-Trichloroethane
U
0.00105
0.00299
1 01/05/201914:39
WG1219549
Trichloroethene
U
J4
0.000478
0.00119
1 01/05/201914:39
WG1219549
Trichlorofluoromethane
U
0.000597
0.00299
1 01/05/201914:39
WG1219549
1,2,3-Trichloropropane
U
0.00609
0.0149
1 01/05/201914:39
WG1219549
1,2,4-Trimethylbenzene
U
0.00139
0.00597
1 01/05/201914:39
WG1219549
1,2,3-Trimethyl benzene
U
0.00137
0.00597
1 01/05/201914:39
WG1219549
1,3,5-Trimethyl benzene
U
0.00129
0.00597
1 01/05/201914:39
WG1219549
Vinyl chloride
U
0.000816
0.00299
1 01/05/201914:39
WG1219549
Xylenes, Total
U
0.00571
0.00776
1 01/05/201914:39
WG1219549
(S) Toluene-d8
106
75.0-131
01105120191439
WG1219549
(S) Dibromofluoromethane
92.4
65.0-129
011051201914:39
WG1219549
(S) 4-Bromof/uorobenzene
102
67.0-138
011051201914:39
WG1219549
Semi Volatile Organic Compounds
(GC/MS) by Method 8270D
Result (dry)
Qualifier
MDL (dry)
RDL (dry)
Dilution Analysis
Batch
Analyte
mg/kg
mg/kg
mg/kg
date / time
Acenaphthene
U
0.00767
0.0398
1 01/07/2019 00:22
WG1219776
Acenaphthylene
U
0.00801
0.0398
1 01/07/2019 00:22
WG1219776
Anthracene
U
0.00755
0.0398
1 01/07/2019 00:22
WG1219776
Acetophenone
U
0.0898
0.398
1 01/07/2019 00:22
WG1219776
Atrazine
U
0.112
0.398
1 01/07/2019 00:22
WG1219776
Benzaldehyde
U
0.0635
0.398
1 01/07/2019 00:22
WG1219776
Benzidine
U
J4
0.0761
0.398
1 01/07/2019 00:22
WG1219776
Benzo(a)anth race ne
U
0.00511
0.0398
1 01/07/2019 00:22
WG1219776
Benzo(b)fluoranthene
U
0.00830
0.0398
1 01/07/2019 00:22
WG1219776
Benzo(k)fluoranthene
U
0.00695
0.0398
1 01/07/2019 00:22
WG1219776
Benzo(g,h,i)perylene
U
0.00861
0.0398
1 01/07/2019 00:22
WG1219776
Benzo(a)pyrene
U
0.00655
0.0398
1 01/07/2019 00:22
WG1219776
ACCOUNT:
PROJECT:
SDG:
DATE/TIME: PAGE:
Hart and Hickman,
PC
CRP-001
L1058130
01/22/19 07:19 13 of 36

ONE LAB. NATIONWIDE.
DUP-SB SAMPLE RESULTS - 03
Collected date/time: 01/03/19 00:00 L1058130
Semi Volatile Organic Compounds (GC/MS) by Method 8270D
Analyte
Result (dry)
mg/kg
Qualifier MDL (dry)
mg/kg
RDL (dry)
mg/kg
Dilution Analysis
date / time
Batch
Benzyl alcohol
U
0.00896
0.398
1 01/07/2019 00:22
WG1219776
Biphenyl
U
0.00702
0.398
1 01/07/2019 00:22
WG1219776
Bis(2-chlorethoxy)methane
U
0.00920
0.398
1 01/07/2019 00:22
WG1219776
Bis(2-chloroethyl)ether
U
0.0107
0.398
1 01/07/2019 00:22
WG1219776
Bis(2-chloroisopropyl)ether
U
0.00908
0.398
1 01/07/2019 00:22
WG1219776
4-Bromophenyl-phenylether
u
0.0136
0.398
1 01/07/2019 00:22
WG1219776
2-Chloronaphthalene
U
0.00763
0.0398
1 01/07/2019 00:22
WG1219776
4-Chlorophenyl-phenylether
U
0.00749
0.398
1 01/07/2019 00:22
WG1219776
Caprolactam
U
0.124
0.398
1 01/07/2019 00:22
WG1219776
Carbazole
U
0.00626
0.398
1 01/07/2019 00:22
WG1219776
4-Chloroaniline
U
0.0420
0.398
1 01/07/2019 00:22
WG1219776
Chrysene
U
0.00663
0.0398
1 01/07/2019 00:22
WG1219776
Dibenz(a,h)anthracene
U
0.00981
0.0398
1 01/07/2019 00:22
WG1219776
Dibenzofuran
U
0.00619
0.398
1 01/07/2019 00:22
WG1219776
1,2-Dichlorobenzene
U
0.0110
0.398
1 01/07/2019 00:22
WG1219776
1,3-Dichlorobenzene
U
0.0119
0.398
1 01/07/2019 00:22
WG1219776
1,4-Dichlorobenzene
U
0.0119
0.398
1 01/07/2019 00:22
WG1219776
3,3-Dichlorobenzidine
U
0.0948
0.398
1 01/07/2019 00:22
WG1219776
2,4-Dinitrotoluene
U
0.00725
0.398
1 01/07/2019 00:22
WG1219776
2,6-Dinitrotoluene
U
0.00880
0.398
1 01/07/2019 00:22
WG1219776
1,2-Diphenylhydrazine
U
0.00631
0.398
1 01/07/2019 00:22
WG1219776
Fluoranthene
U
0.00592
0.0398
1 01/07/2019 00:22
WG1219776
Fluorene
U
0.00815
0.0398
1 01/07/2019 00:22
WG1219776
Hexachlorobenzene
U
0.0102
0.398
1 01/07/2019 00:22
WG1219776
Hexachloro-1,3-butadiene
U
0.0119
0.398
1 01/07/2019 00:22
WG1219776
Hexachlorocyclopentadiene
U
0.0701
0.398
1 01/07/2019 00:22
WG1219776
Hexachloroethane
U
0.0160
0.398
1 01/07/2019 00:22
WG1219776
Indeno(1,2,3-cd)pyrene
U
0.00922
0.0398
1 01/07/2019 00:22
WG1219776
Isophorone
U
0.00623
0.398
1 01/07/2019 00:22
WG1219776
2-Methylnaphthalene
U
0.0103
0.0398
1 01/07/2019 00:22
WG1219776
2-Nitroaniline
U
0.00902
0.398
1 01/07/2019 00:22
WG1219776
3-Nitroaniline
U
0.0102
0.398
1 01/07/2019 00:22
WG1219776
4-Nitroaniline
U
0.00763
0.398
1 01/07/2019 00:22
WG1219776
Naphthalene
U
0.0106
0.0398
1 01/07/2019 00:22
WG1219776
Nitrobenzene
U
0.00830
0.398
1 01/07/2019 00:22
WG1219776
n-Nitrosodimethyla mine
U
0.0773
0.398
1 01/07/2019 00:22
WG1219776
n-Nitrosodiphenyla mine
U
0.107
0.398
1 01/07/2019 00:22
WG1219776
n-Nitrosodi-n-propylamine
u
0.0108
0.398
1 01/07/2019 00:22
WG1219776
Phenanthrene
U
0.00631
0.0398
1 01/07/2019 00:22
WG1219776
Benzylbutyl phthalate
U
0.0123
0.398
1 01/07/2019 00:22
WG1219776
Bis(2-ethylhexyl)phthalate
U
0.0143
0.398
1 01/07/2019 00:22
WG1219776
Di-n-butyl phthalate
U
0.0130
0.398
1 01/07/2019 00:22
WG1219776
Diethyl phthalate
U
0.00825
0.398
1 01/07/2019 00:22
WG1219776
Dimethyl phthalate
U
0.00645
0.398
1 01/07/2019 00:22
WG1219776
Di-n-octyl phthalate
U
0.0108
0.398
1 01/07/2019 00:22
WG1219776
Pyrene
U
0.0147
0.0398
1 01/07/2019 00:22
WG1219776
1,2,4-Trichlorobenzene
U
0.0105
0.398
1 01/07/2019 00:22
WG1219776
4-ChIoro-3-methyl phenol
U
0.00570
0.398
1 01/07/2019 00:22
WG1219776
2-Chlorophenol
U
0.00993
0.398
1 01/07/2019 00:22
WG1219776
2,4-Dichlorophenol
U
0.00891
0.398
1 01/07/2019 00:22
WG1219776
2,4-Dimethylphenol
U
0.0563
0.398
1 01/07/2019 00:22
WG1219776
4,6-Dinitro-2-methylphenol
U
0.148
0.398
1 01/07/2019 00:22
WG1219776
2,4-Dinitrophenol
U
0.117
0.398
1 01/07/2019 00:22
WG1219776
2-Methylphenol
U
0.0118
0.398
1 01/07/2019 00:22
WG1219776
3&4-Methyl Phenol
U
0.00935
0.398
1 01/07/2019 00:22
WG1219776
2-Nitrophenol
U
0.0155
0.398
1 01/07/2019 00:22
WG1219776
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
Hart and Hickman,
PC
CRP-001
L1058130
01/22/19 07:19
FP
FTc
FSS
[Cn]
Fc
I ql
FAI
FSC
PAGE:
14 of 36

ONE LAB. NATIONWIDE.
DUP-SB SAMPLE RESULTS - 03
Collected date/time: 01/03/19 00:00 L1058130
Semi Volatile Organic Compounds (GC/MS) by Method 8270D
Analyte
Result (dry)
mg/kg
Qualifier MDL (dry)
mg/kg
RDL (dry)
mg/kg
Dilution Analysis
date / time
4-Nitrophenol
U
0.0627
0.398
1 01/07/2019 00:22
Pentachlorophenol
U
0.0573
0.398
1 01/07/2019 00:22
Phenol
U
0.00830
0.398
1 01/07/2019 00:22
2,4,5-Trichlorophenol
U
0.0124
0.398
1 01/07/2019 00:22
2,4,6-Trichlorophenol
U
0.00930
0.398
1 01/07/2019 00:22
(S) 2-F/uorophenol
69.7
12.0-120
0110712019 00.22
(S) Phenol-d5
62.4
10.0-120
0110712019 00.22
(S) Nitrobenzene-d5
63.4
10.0-122
0110712019 00.22
(S) 2-Fluorobiphenyl
63.7
15.0-120
0110712019 00.22
(S)2,4,6-Tribromopheno/
67.9
10.0-127
011071201900.22
(S) p-Terphenyl-d14
64.3
10.0-120
0110712019 00.22
Batch
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
WG1219776
FP
FTc
FSS
[Cn]
Fc
F,
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC CRP-001 L1058130 01/22/19 07:19 15 of 36

WG1219482
QUALITY CONTROL SUMMARY
Total Solids by Method 2540 G-2011
1-1058130-01,02,03
Method Blank (MB)
(MB) R3374407-1 01/08/1916:32
MB Result MB Qualifier MB MDL MB RDL
Analyte % % %
Total Solids 0.00100
L1058130-03 Original Sample (OS) • Duplicate (DUP)
(OS) L1058130-03 01/08/1916:32 • (DUP) R3374407-3 01/08/1916:32
Original Result DUP Result Dilution DUP RPD
DUP Qualifier DUP RPD
Limits
Analyte % % %
%
Total Solids 83.7 82.3 1 1.74
10
Laboratory Control Sample (LCS)
(LCS) R3374407-2 01/08/1916:32
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte % %_ % %
Total Solids 50.0 50.0 100 85.0-115
ONE LAB. NATIONWIDE.
— I
Cp
FTc
FSS
4
— Cn
FSr
— �GI
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC CRP-001 L1058130 01/22/19 07:19 16 of 36

WG1221753
Wet Chemistry by Method 7199
Method Blank (MB)
(MB) R3375251-1 01/11/1915:06
MB Result
Analyte mg/kg
Hexavalent Chromium U
MB Qualifier MB MDL MB RDL
mg/kg mg/kg
0.255 1.00
L1058027-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1058027-01 01/11/1915:19 • (DUP) R3375251-3 01/11/1915:28
Original Result DUP Result Dilution DUP RPD
(dry) (dry)
Analyte mg/kg mg/kg %
Hexavalent Chromium U 0.000 1 0.000
L1058915-05 Original Sample (OS) • Duplicate (DUP)
QUALITY CONTROL SUMMARY
L1058130-02,03
DUP Qualifier DUP RPD
Limits
o�
20
(OS) L1058915-05 01/11/1918:02 • (DUP) R3375251-8 01/11/1918:09
Original Result DUP Result DUP RPD
Dilution DUP RPD DUP Qualifier
(dry) (dry) Limits
Analyte mg/kg mg/kg % %
Hexavalent Chromium 0.311 0.304 1 2.45 J 20
Laboratory Control Sample (LCS)
(LCS) R3375251-2 01/11/19 15:12
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte mg/kg mg/kg % %
Hexavalent Chromium 10.0 9.94 99.4 80.0-120
L1058904-07 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
ONE LAB. NATIONWIDE.
(OS) L1058904-07 01/11/1917:25 • (MS) R3375251-4 01/11/1917:31 • (MSD) R3375251-5 01/11/1917:38
Spike Amount Original Result MS Result (dry) MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
(dry) (dry) (dry)
Analyte mg/kg mg/kg mg/kg mg/kg % % % % %
Hexavalent Chromium 23.9 U 23.7 23.5 98.9 98.3 1 75.0-125 0.527 20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC CRP-001 L1058130 01/22/19 07:19 17 of 36

WG1221753 QUALITY CONTROL SUMMARY
Wet Chemistry by Method 7199 1-1058130-02,03
L1O58904-07 Original Sample (OS) • Matrix Spike (MS)
(OS) L1058904-07 01/11/1917:25 • (MS) R3375251-6 01/11/1917:44
Spike Amount Original Result MS Result (dry) MS Rec.
(dry) (dry)
Analyte mg/kg mg/kg mg/kg %
Hexavalent Chromium 1020 U 365 35.6
Dilution Rec. Limits MS Qualifier
50
75.0-125 J6
ONE LAB. NATIONWIDE.
FP1
FTC
FSS
4
Cn
FSr
�GI
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC CRP-001 L1058130 01/22/19 07:19 18 of 36

WG1226350
Mercury by Method 7471B
Method Blank (MB)
(MB) R3377434-1 01/21/1914:43
MB Result
Analyte mg/kg
Mercury U
MB Qualifier MB MDL MB RDL
mg/kg mg/kg
0.00280 0.0200
QUALITY CONTROL SUMMARY
L1058130-02,03
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3377434-2 01/21/1914:46 • (LCSD) R3377434-3 01/21/19 14:48
Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte mg/kg mg/kg mg/kg % % % % %
Mercury 0.500 0.486 0.470 97.3 94.1 80.0-120 3.31 20
L1058130-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
ONE LAB. NATIONWIDE.
(OS) L1058130-02 01/21/1914:51 • (MS) R3377434-4 01/21/1914:54 • (MSD) R3377434-5 01/21/1914:56
Spike Amount
Original Result
MS Result (dry)
MSD Result MS Rec. MSD Rec.
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD RPD Limits
(dry)
(dry)
(dry)
Analyte mg/kg
mg/kg
mg/kg
mg/kg % %
%
% %
Mercury 0.634
0.0110
0.431
0.581 66.2 90.0
1 75.0-125
J6 J3 29.8 20
ACCOUNT:
PROJECT:
SDG:
DATE/TIME: PAGE:
Hart and Hickman, PC
CRP-001
L1058130
01/22/19 07:19 19 of 36
— I
Cp
FTc
FSS
4
— Cn
FSr
— �GI
FAI
[Sc

WG1225859
Metals (ICPMS) by Method 6020B
Method Blank (MB)
(MB) R3377152-1 01/19/1914:55
MB Result
MB Qualifier MB MDL
MB RDL
Analyte mg/kg
mg/kg
mg/kg
Arsenic U
0.125
0.500
Barium U
0.160
1.00
Cadmium U
0.0800
0.500
Chromium U
0.270
1.00
Lead U
0.120
0.500
Selenium U
0.190
0.500
Silver U
0.155
0.500
QUALITY CONTROL SUMMARY
L1058130-02,03
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3377152-2 01/19/1915:00 • (LCSD) R3377152-3 01/19/1915:05
Spike Amount
LCS Result
LCSD Result
Analyte
mg/kg
mg/kg
mg/kg
Arsenic
100
92.6
93.8
Barium
100
92.7
95.3
Cadmium
100
95.0
95.6
Chromium
100
98.4
98.2
Lead
100
95.8
96.4
Selenium
100
94.9
94.9
Silver
20.0
19.7
20.0
LCS Rec.
LCSD Rec.
Rec. Limits
LCS Qualifier LCSD Qualifier RPD
RPD Limits
92.6
93.8
80.0-120
1.29
20
92.7
95.3
80.0-120
2.71
20
95.0
95.6
80.0-120
0.583
20
98.4
98.2
80.0-120
0.200
20
95.8
96.4
80.0-120
0.664
20
94.9
94.9
80.0-120
0.0323
20
98.7
99.9
80.0-120
1.18
20
L1058130-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1058130-02 01/19/1915:09 • (MS) R3377152-6 01/19/1915:23 • (MSD) R3377152-7 01/19/1915:28
Spike Amount
Original Result
MS Result (dry)
MSD Result
MS Rec.
MSD Rec.
(dry)
(dry)
(dry)
Analyte
mg/kg
mg/kg
mg/kg
mg/kg
%
%
Arsenic
25.3
1.00
111
112
86.6
87.2
Barium
25.3
101
220
195
93.2
74.2
Cadmium
25.3
0.422
117
119
91.9
93.7
Chromium
25.3
20.4
143
138
96.7
93.2
Lead
25.3
8.40
123
123
90.5
90.7
Selenium
25.3
0.385
115
115
90.5
90.7
Silver
5.07
U
24.7
24.8
97.4
97.8
ONE LAB. NATIONWIDE.
Dilution
Rec. Limits
MS Qualifier MSD Qualifier RPD
RPD Limits
5
75.0-125
0.745
20
5
75.0-125
J6 11.6
20
5
75.0-125
1.97
20
5
75.0-125
3.15
20
5
75.0-125
0.210
20
5
75.0-125
0.270
20
5
75.0-125
0.482
20
FP1
FTc
FSS
4
Cn
FSr
�GI
FAI
[Sc
ACCOUNT:
Hart and Hickman, PC
PROJECT:
CRP-001
SDG: DATE/TIME:
L1058130 01/22/19 07:19
PAGE:
20 of 36

WG1219549 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE.
Volatile Organic Compounds (GC/MS) by Method 8260B 1-1058130-01,02,03
Method Blank (MB)
(MB) R3373849-3 01/05/19 12:45
MB Result MB Qualifier
Analyte mg/kg
Acetone
Acrylonitrile
Benzene
Bromobenzene
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec -Butyl benzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dibromoethane
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,1-Dichloropropene
1,3-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
2,2-Dichloropropane
Di -isopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
Isopropylbenzene
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MB MDL
mg/kg
0.0137
0.00190
0.000400
0.00105
0.000788
0.00598
0.00370
0.00384
0.00253
0.00155
0.00108
0.000573
0.000450
0.00108
0.000415
0.00139
0.000920
0.00113
0.00510
0.000525
0.00100
0.00145
0.00170
0.00197
0.000818
0.000575
0.000475
0.000500
0.000690
0.00143
0.00127
0.000700
0.00175
0.000678
0.00153
0.000793
0.000350
0.000530
0.0127
0.000863
MB RDL
mg/kg
0.0250
0.0125
0.00100
0.0125
0.00250
0.0250
0.0125
0.0125
0.0125
0.00500
0.00500
0.00250
0.00250
0.00500
0.00250
0.0125
0.00250
0.00500
0.0250
0.00250
0.00500
0.00500
0.00500
0.00500
0.00250
0.00250
0.00250
0.00250
0.00250
0.00500
0.00500
0.00250
0.00500
0.00250
0.00500
0.00250
0.00100
0.00250
0.0250
0.00250
FP1
FTC
FSS
[Cn]
FSr
�GI
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC CRP-001 L1058130 01/22/19 07:19 21 of 36

WG1219549 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE.
Volatile Organic Compounds (GC/MS) by Method 8260B 1-1058130-01,02,03
Method Blank (MB)
(MB) R3373849-3 01/05/19 12:45
MB Result
Analyte mg/kg
p-Isopropyltoluene
U
2-Butanone (MEK)
U
Methylene Chloride
0.0157
4-Methyl-2-pentanone (MIBK)
U
Methyl tert-butyl ether
U
Naphthalene
U
n-Propylbenzene
U
Styrene
U
1,1,1,2-Tetrachloroethane
U
1,1,2,2-Tetrachloroethane
U
Tetrachloroethene
U
Toluene
U
1,1,2-Trichlorotrifluoroethane
U
1,2,3-Trichlorobe nzene
U
1,2,4-Trichlorobenzene
U
1,1,1-Trichloroethane
U
1,1,2-Trichloroethane
U
Trichloroethene
U
Trichlorofluoromethane
U
1,2,3-Trichloropropane
U
1,2,3-Trimethyl benzene
U
1,2,4-Trimethylbenzene
U
1,3,5-Trimethyl benzene
U
Vinyl chloride
U
Xylenes, Total
U
(S) Toluene-d8
106
(S) DibromoFluoromeftne
90.2
(S) 4-Bromof/uorobenzene
107
MB Qualifier MB MDL
mg/kg
MB RDL
mg/kg
0.00233
0.00500
0.0125
0.0250
J 0.00664
0.0250
0.0100
0.0250
0.000295
0.00100
0.00312
0.0125
0.00118
0.00500
0.00273
0.0125
0.000500
0.00250
0.000390
0.00250
0.000700
0.00250
0.00125
0.00500
0.000675
0.00250
0.000625
0.00250
0.00482
0.0125
0.000275
0.00250
0.000883
0.00250
0.000400
0.00100
0.000500
0.00250
0.00510
0.0125
0.00115
0.00500
0.00116
0.00500
0.00108
0.00500
0.000683
0.00250
0.00478
0.00650
75.0-131
65.0-129
67.0-138
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3373849-1 01/05/1910:52 • (LCSD) R3373849-2 01/05/1911:11
Spike Amount
LCS Result
LCSD Result
LCS Rec.
LCSD Rec.
Rec. Limits
LCS Qualifier LCSD Qualifier RPD
RPD Limits
Analyte mg/kg
mg/kg
mg/kg
%
%
%
%
%
Acetone 0.625
0.299
0.140
47.8
22.5
10.0-160
J3 72.1
31
Acrylonitrile 0.625
0.496
0.491
79.3
78.5
45.0-153
1.10
22
Benzene 0.125
0.0914
0.0884
73.1
70.7
70.0-123
3.39
20
Bromobenzene 0.125
0.110
0.110
88.1
88.0
73.0-121
0.109
20
Bromodichloromethane 0.125
0.0937
0.0904
74.9
72.4
73.0-121
J4 3.50
20
ACCOUNT:
PROJECT:
SDG:
DATE/TIME: PAGE:
Hart and Hickman, PC
CRP-001
L1058130
01/22/19 07:19 22 of 36
FP1
FTc
FSS
4
Cn
FSr
�GI
FAI
FSC

WG1219549
QUALITY
CONTROL
SUMMARY
ONE LAB. NATIONWIDE.
Volatile Organic Compounds
(GC/MS)
by Method 8260B
1-1058130-01,02,03
Laboratory Control
Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
FP1(LCS)
R3373849-1 01/05/1910:52 • (LCSD) R3373849-2 01/05/1911:11
Spike Amount
LCS Result
LCSD Result
LCS Rec. LCSD Rec.
Rec. Limits LCS Qualifier LCSD Qualifier
RPD
RPD Limits
Analyte
mg/kg
mg/kg
mg/kg
%
%
%
%
%
2
TC
Bromoform
0.125
0.111
0.106
89.0
84.5
64.0-132
5.16
20
Bromomethane
0.125
0.150
0.140
120
112
56.0-147
6.82
20
FSS
n-Butylbenzene
0.125
0.117
0.111
93.8
88.5
68.0-135
5.82
20
sec -Butyl benzene
0.125
0.108
0.101
86.0
80.8
74.0-130
6.31
20
tert-Butylbenzene
0.125
0.103
0.0994
82.8
79.5
75.0-127
3.95
20
[Cn]
Carbon tetrachloride
0.125
0.0987
0.0981
78.9
78.5
66.0-128
0.534
20
Chlorobenzene
0.125
0.132
0.126
105
101
76.0-128
4.00
20
FSr
Chlorodibromomethane
0.125
0.118
0.117
94.3
93.5
74.0-127
0.764
20
Chloroethane
0.125
0.164
0.146
131
116
61.0-134
11.7
20
Chloroform
0.125
0.110
0.113
87.6
90.3
72.0-123
3.08
20
Chloromethane
0.125
0.103
0.0999
82.7
79.9
51.0-138
3.48
20
2-Chlorotoluene
0.125
0.109
0.102
87.5
81.7
75.0-124
6.93
20
7G1
4-Chlorotoluene
0.125
0.125
0.120
100
96.3
75.0-124
3.76
20
1,2-Dibromo-3-Chloropropane
0.125
0.116
0.109
92.9
87.6
59.0-130
5.88
20
1,2-Dibromoethane
0.125
0.125
0.124
99.8
99.2
74.0-128
0.675
20
FAI
Dibromomethane
0.125
0.132
0.119
105
94.8
75.0-122
10.5
20
1,2-Dichlorobenzene
0.125
0.0981
0.0981
78.5
78.5
76.0-124
0.0612
20
FSC
1,3-Dichlorobenzene
0.125
0.129
0.127
103
102
76.0-125
1.38
20
1,4-Dichlorobenzene
0.125
0.107
0.104
85.9
83.1
77.0-121
3.30
20
Dichlorodifluoromethane
0.125
0.0915
0.0888
73.2
71.0
43.0-156
2.97
20
1,1-Dichloroethane
0.125
0.106
0.101
85.0
81.1
70.0-127
4.67
20
1,2-Dichloroethane
0.125
0.0949
0.0924
75.9
73.9
65.0-131
2.73
20
1,1-Dichloroethene
0.125
0.105
0.139
83.8
111
65.0-131
J3
28.2
20
cis-1,2-Dichloroethene
0.125
0.0967
0.0976
77.3
78.1
73.0-125
0.950
20
trans-1,2-Dichloroethene
0.125
0.0986
0.0969
78.9
77.6
71.0-125
1.68
20
1,2-Dichloropropane
0.125
0.123
0.115
98.2
92.3
74.0-125
6.21
20
1,1-Dichloropropene
0.125
0.0951
0.0855
76.1
68.4
73.0-125
J4
10.7
20
1,3-Dichloropropane
0.125
0.117
0.117
93.3
93.3
80.0-125
0.0369
20
cis-1,3-Dichloropropene
0.125
0.131
0.133
105
107
76.0-127
1.53
20
trans-1,3-Dichloropropene
0.125
0.110
0.111
88.3
88.5
73.0-127
0.176
20
2,2-Dichloropropane
0.125
0.133
0.133
107
106
59.0-135
0.504
20
Di -isopropyl ether
0.125
0.117
0.118
93.4
94.8
60.0-136
1.40
20
Ethylbenzene
0.125
0.127
0.119
101
95.0
74.0-126
6.34
20
Hexachloro-1,3-butadiene
0.125
0.108
0.105
86.6
84.3
57.0-150
2.71
20
Isopropylbenzene
0.125
0.141
0.133
113
106
72.0-127
6.00
20
p-Isopropyltoluene
0.125
0.129
0.120
103
96.0
72.0-133
7.13
20
2-Butanone (MEK)
0.625
0.524
0.518
83.9
82.9
30.0-160
1.25
24
Methylene Chloride
0.125
0.107
0.150
85.9
120
68.0-123
J3
33.2
20
4-Methyl-2-pentanone (MIBK)
0.625
0.635
0.633
102
101
56.0-143
0.185
20
Methyl tert-butyl ether
0.125
0.121
0.124
96.4
99.0
66.0-132
2.64
20
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
PAGE:
Hart and Hickman, PC
CRP-001
L1058130
01/22/19 07:19
23 of 36

WG1219549
QUALITY
CONTROL
SUMMARY
ONE LAB. NATIONWIDE.
Volatile Organic Compounds (GC/MS)
by Method 8260B
1-1058130-01,02,03
Laboratory Control Sample (LCS) • Laboratory
Control Sample
Duplicate (LCSD)
FP1(LCS)
R3373849-1 01/05/1910:52 • (LCSD) R3373849-2
01/05/1911:11
Spike Amount
LCS Result
LCSD Result
LCS Rec. LCSD Rec.
Rec. Limits
LCS Qualifier LCSD Qualifier
RPD
RPD Limits
Analyte mg/kg
mg/kg
mg/kg
%
%
%
%
%
FTC
Naphthalene 0.125
0.0989
0.101
79.2
81.1
59.0-130
2.42
20
n-Propylbenzene 0.125
0.112
0.105
89.4
84.1
74.0-126
6.12
20
FSS
Styrene 0.125
0.122
0.114
97.7
91.5
72.0-127
6.51
20
1,1,1,2-Tetrachloroethane 0.125
0.0951
0.0923
76.1
73.8
74.0-129
J4
2.98
20
4
1,1,2,2-Tetrachloroethane 0.125
0.0938
0.0895
75.0
71.6
68.0-128
4.72
20
Cn
Tetrachloroethene 0.125
0.130
0.123
104
98.5
70.0-136
5.57
20
Toluene 0.125
0.109
0.103
87.5
82.8
75.0-121
5.54
20
FSr
1,1,2-Trichlorotrifluoroethane 0.125
0.105
0.156
84.1
125
61.0-139
J3
38.8
20
1,2,3-Trichlorobenzene 0.125
0.101
0.104
80.8
83.1
59.0-139
2.77
20
1,2,4-Trichlorobenzene 0.125
0.0963
0.0944
77.0
75.5
62.0-137
1.98
20®
1,1,1-Trichloroethane 0.125
0.120
0.116
95.7
92.5
69.0-126
3.42
20
1,1,2-Trichloroethane 0.125
0.134
0.132
107
106
78.0-123
1.26
20
7G1
Trichloroethene 0.125
0.0927
0.0864
74.2
69.2
76.0-126
J4
J4
6.98
20
Trichlorofluoromethane 0.125
0.113
0.111
90.4
89.0
61.0-142
1.55
20
1,2,3-Trichloropropane 0.125
0.0977
0.0962
78.1
77.0
67.0-129
1.50
20
FAI
1,2,3-Trimethyl benzene 0.125
0.116
0.114
92.9
91.0
74.0-124
2.03
20
1,2,4-Trimethylbenzene 0.125
0.135
0.128
108
102
70.0-126
5.08
20
FSC
1,3,5-Trimethyl benzene 0.125
0.124
0.119
99.5
95.5
73.0-127
4.18
20
Vinyl chloride 0.125
0.100
0.102
80.0
81.4
63.0-134
1.72
20
Xylenes, Total 0.375
0.405
0.398
108
106
72.0-127
1.74
20
(S) Toluene-d8
106
106
75.0-131
(S) DibromoFluoromeftne
93.3
95.3
65.0-129
(S) 4-Bromofluorobenzene
103
99.3
67.0-138
L1058246-01 Original Sample
(OS) • Matrix
Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1058246-01 01/05/19 19:05 • (MS) R3373849-4 01/05/1919:24 •
(MSD) R3373849-5 01/05/19 19:43
Spike Amount
Original Result
MS Result
MSD Result MS Rec.
MSD Rec.
Dilution
Rec. Limits MS Qualifier
MSD Qualifier
RPD
RPD Limits
Analyte mg/kg
mg/kg
mg/kg
mg/kg
%
%
%
%
%
Acetone 0.625
ND
5.67
5.65
ill
ill
8
10.0-160
0.195
40
Acrylonitrile 0.625
ND
6.00
6.25
120
125
8
10.0-160
4.14
40
Benzene 0.125
ND
0.349
0.848
34.9
84.8
8
10.0-149
J3
83.3
37
Bromobenzene 0.125
ND
1.10
1.82
110
182
8
10.0-156
J3 J5
48.9
38
Bromodichloromethane 0.125
ND
0.514
0.807
51.4
80.7
8
10.0-143
J3
44.4
37
Bromoform 0.125
ND
0.801
0.885
80.1
88.5
8
10.0-146
9.94
36
Bromomethane 0.125
ND
0.419
1.08
41.9
108
8
10.0-149
J3
88.2
38
n-Butylbenzene 0.125
8.10
28.1
29.1
2000
2100
8
10.0-160 E V
E V
3.52
40
sec -Butyl benzene 0.125
2.46
4.68
4.84
223
238
8
10.0-159 J5
J5
3.30
39
tert-Butylbenzene 0.125
ND
0.455
9.18
45.5
918
8
10.0-156
J3 J5
181
39
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
PAGE:
Hart and Hickman, PC
CRP-001
L1058130
01/22/19 07:19
24 of 36

WG1219549 QUALITY CONTROL SUMMARY
Volatile Organic Compounds (GC/MS) by Method 8260B 1-1058130-01,02,03
ONE LAB. NATIONWIDE.
L1O58246-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1058246-01 01/05/1919:05 • (MS) R3373849-4 01/05/1919:24 • (MSD) R3373849-5 01/05/19 19:43
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
mg/kg
mg/kg
mg/kg
mg/kg
%
%
Carbon tetrachloride
0.125
ND
0.194
0.936
19.4
93.6
Chlorobenzene
0.125
ND
0.582
1.11
58.2
111
Chlorodibromomethane
0.125
ND
0.764
0.981
76.4
98.1
Chloroethane
0.125
ND
0.362
1.09
36.2
109
Chloroform
0.125
ND
0.493
1.07
49.3
107
Chloromethane
0.125
ND
0.297
1.03
29.7
103
2-Chlorotoluene
0.125
ND
0.405
0.842
40.5
84.2
4-Chlorotoluene
0.125
ND
2.69
2.10
269
210
1,2-Dibromo-3-Chloropropane
0.125
ND
0.991
1.00
99.1
100
1,2-Dibromoethane
0.125
ND
0.902
1.07
90.2
107
Dibromomethane
0.125
ND
0.935
1.04
93.5
104
1,2-Dichlorobenzene
0.125
ND
0.619
0.831
61.9
83.1
1,3-Dichlorobenzene
0.125
ND
0.718
1.13
71.8
113
1,4-Dichlorobenzene
0.125
ND
0.599
0.855
59.9
85.5
Dichlorodifluoromethane
0.125
ND
0.177
1.43
17.7
143
1,1-Dichloroethane
0.125
ND
0.398
1.01
39.8
101
1,2-Dichloroethane
0.125
ND
0.650
0.859
65.0
85.9
1,1-Dichloroethene
0.125
ND
0.229
1.12
22.9
112
cis-1,2-Dichloroethene
0.125
ND
0.451
0.972
45.1
97.2
trans-1,2-Dichloroethene
0.125
ND
0.288
0.980
28.8
98.0
1,2-Dichloropropane
0.125
ND
0.671
1.12
67.1
112
1,1-Dichloropropene
0.125
ND
0.198
0.844
19.8
84.4
1,3-Dichloropropane
0.125
ND
0.809
1.00
80.9
100
cis-1,3-Dichloropropene
0.125
ND
0.753
1.16
75.3
116
trans-1,3-Dichloropropene
0.125
ND
0.711
0.920
71.1
92.0
2,2-Dichloropropane
0.125
ND
0.306
1.17
30.6
117
Di -isopropyl ether
0.125
ND
0.726
1.14
72.6
114
Ethylbenzene
0.125
2.35
4.53
5.26
218
291
Hexachloro-1,3-butadiene
0.125
ND
0.458
0.863
45.8
86.3
Isopropylbenzene
0.125
1.27
2.65
3.25
137
198
p-Isopropyltoluene
0.125
1.96
10.8
4.21
880
225
2-Butanone (MEK)
0.625
ND
5.84
5.72
117
114
Methylene Chloride
0.125
ND
0.681
1.02
68.1
102
4-Methyl-2-pentanone (MIBK)
0.625
ND
6.40
6.33
128
127
Methyl tert-butyl ether
0.125
ND
1.00
1.20
100
120
Naphthalene
0.125
12.5
19.2
18.5
671
597
n-Propylbenzene
0.125
5.43
9.49
9.24
406
382
Styrene
0.125
ND
0.680
1.42
68.0
142
1,1,1,2-Tetrachloroethane
0.125
ND
0.463
0.790
46.3
79.0
1,1,2,2-Tetrachloroethane
0.125
ND
2.20
2.06
220
206
Dilution
Rec. Limits
MS Qualifier
MSD Qualifier
RPD
RPD Limits
8
10.0-145
J3
131
37
8
10.0-152
J3
62.5
39
8
10.0-146
24.9
37
8
10.0-146
J3
100
40
8
10.0-146
J3
74.0
37
8
10.0-159
J3
110
37
8
10.0-159
J3
70.0
38
8
10.0-155
J5
J5
24.6
39
8
10.0-151
0.952
39
8
10.0-148
17.0
34
8
10.0-147
10.9
35
8
10.0-155
29.2
37
8
10.0-153
J3
44.4
38
8
10.0-151
35.2
38
8
10.0-160
J3
156
35
8
10.0-147
J3
86.9
37
8
10.0-148
27.8
35
8
10.0-155
J3
132
37
8
10.0-149
J3
73.2
37
8
10.0-150
J3
109
37
8
10.0-148
J3
50.5
37
8
10.0-153
J3
124
35
8
10.0-154
21.1
35
8
10.0-151
J3
42.5
37
8
10.0-148
25.6
37
8
10.0-138
J3
117
36
8
10.0-147
J3
44.2
36
8
10.0-160
J5
J5
14.9
38
8
10.0-160
J3
61.4
40
8
10.0-155
J5
20.5
38
8
10.0-160
J5
J3 J5
87.6
40
8
10.0-160
2.01
40
8
10.0-141
J3
39.5
37
8
10.0-160
1.09
35
8
11.0-147
17.6
35
8
10.0-160
V
V
3.93
36
8
10.0-158
V
V_
2.61
38
8
10.0-160
J3
70.6
40
8
10.0-149
J3
52.2
39
8
10.0-160
J5
J5
6.43
35
FP1
FTc
FSS
[Cn]
FSr
�GI
FAI
[Sc
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC CRP-001 L1058130 01/22/19 07:19 25 of 36

WG1219549 QUALITY CONTROL SUMMARY
Volatile Organic Compounds (GC/MS) by Method 8260B 1-1058130-01,02,03
L1O58246-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1058246-01 01/05/1919:05 • (MS) R3373849-4 01/05/1919:24 • (MSD) R3373849-5 01/05/19 19:43
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
mg/kg
mg/kg
mg/kg
mg/kg
%
%
Tetrachloroethene
0.125
ND
0.315
1.10
31.5
110
Toluene
0.125
0.285
0.847
1.41
56.1
113
1,1,2-Trichlorotrifluoroethane
0.125
ND
0.164
1.00
16.4
100
1,2,3-Trichlorobe nzene
0.125
ND
0.952
0.819
95.2
81.9
1,2,4-Trichlorobenzene
0.125
ND
0.481
0.759
48.1
75.9
1,1,1-Trichloroethane
0.125
ND
0.281
1.11
28.1
ill
1,1,2-Trichloroethane
0.125
ND
1.32
1.75
132
175
Trichloroethene
0.125
ND
0.287
0.821
28.7
82.1
Trichlorofluoromethane
0.125
ND
0.158
0.978
15.8
97.8
1,2,3-Trichloropropane
0.125
ND
0.939
0.892
93.9
89.2
1,2,3-Trimethyl benzene
0.125
16.2
26.7
24.9
1050
872
1,2,4-Trimethylbenzene
0.125
42.0
47.3
43.8
530
182
1,3,5-Trimethyl benzene
0.125
12.7
21.4
20.2
867
753
Vinyl chloride
0.125
ND
0.183
1.02
18.3
102
Xylenes, Total
0.375
19.5
35.6
37.4
537
597
(S) Toluene-d8
106
106
(S) DibromoFluoromeftne
104
106
(S) 4-Bromof/uorobenzene
161
149
Dilution Rec. Limits
8 10.0-156
8 10.0-156
8 10.0-160
8 10.0-160
8 10.0-160
8 10.0-144
8 10.0-160
8 10.0-156
8 10.0-160
8 10.0-156
8 10.0-160
8 10.0-160
8 10.0-160
8 10.0-160
8 10.0-160
75.0-131
65.0-129
67.0-138
MS Qualifier
EV
EV
EV
MSD Qualifier RPD
J3 ill
J3 50.1
J3 144
15.0
J3 44.8
J3 119
J5 27.7
J3 96.3
J3 144
5.15
E V 7.05
E V 7.65
E V 5.46
J3 139
V 4.93
J1
ONE LAB. NATIONWIDE.
RPD Limits
39
38
36
40
40
35
35
38
40
35
36
36
38
37
38
FP1
FTc
FSS
4
Cn
FSr
�GI
FAI
[Sc
ACCOUNT: PROJECT:
Hart and Hickman, PC CRP-001
SDG:
L1058130
DATE/TIME:
01/22/19 07:19
PAGE:
26 of 36

WG1219776 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 8270D L1058130-01,02,03
ONE LAB. NATIONWIDE.
Method Blank (MB)
(MB) R3373827-3 01/06/19 23:35
MB Result MB Qualifier
Analyte mg/kg
Acenaphthene
Acenaphthylene
Acetophenone
Anthracene
Azobenzene
Atrazine
Benzaldehyde
Benzidine
Benzo(a)anth race ne
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(g,h,i)perylene
Benzo(a)pyrene
Biphenyl
Bis(2-chlorethoxy)methane
B is(2-chloroethyl)eth er
Bis(2-chloroisopropyl)ether
4-Bromophenyl-phenylether
Caprolactam
Carbazole
4-Chloroaniline
2-Chloronaphthalene
4-Chlorophenyl-phenylether
Chrysene
Dibenz(a,h)anthracene
Dibenzofuran
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3,3-Dichlorobenzidine
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachloro-1,3-butadiene
Hexachlorocyclopentadiene
Hexachloroethane
I nd eno(1,2,3-cd) pyrene
Isophorone
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MB MDL
mg/kg
0.00642
0.00671
0.0752
0.00632
0.00528
0.0938
0.0532
0.0637
0.00428
0.00695
0.00582
0.00721
0.00548
0.00588
0.00770
0.00896
0.00760
0.0114
0.104
0.00524
0.0352
0.00639
0.00627
0.00555
0.00821
0.00518
0.00921
0.0100
0.0100
0.0794
0.00607
0.00737
0.00496
0.00682
0.00856
0.0100
0.0587
0.0134
0.00772
0.00522
MB RDL
mg/kg
0.0333
0.0333
0.333
0.0333
0.333
0.333
0.333
0.333
0.0333
0.0333
0.0333
0.0333
0.0333
0.333
0.333
0.333
0.333
0.333
0.333
0.333
0.333
0.0333
0.333
0.0333
0.0333
0.333
0.333
0.333
0.333
0.333
0.333
0.333
0.0333
0.0333
0.333
0.333
0.333
0.333
0.0333
0.333
FP1
FTC
FSS
4
Cn
FSr
�GI
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC CRP-001 L1058130 01/22/19 07:19 27 of 36

WG1219776 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 8270D L1058130-01,02,03
ONE LAB. NATIONWIDE.
Method Blank (MB)
(MB) R3373827-3 01/06/19 23:35
MB Result
Analyte
mg/kg
2-Methylnaphthalene
U
Naphthalene
U
2-Nitroaniline
U
3-Nitroaniline
U
4-Nitroaniline
U
Nitrobenzene
U
n-Nitrosodimethyla mine
U
n-Nitrosodiphenyla mine
U
n-Nitrosodi-n-propylamine
U
Phenanthrene
U
Benzylbutyl phthalate
U
Bis(2-ethylhexyl)phthalate
U
Di-n-butyl phthalate
U
Diethyl phthalate
U
Dimethyl phthalate
U
Di-n-octyl phthalate
U
Pyrene
U
1,2,4-Trichlorobenzene
U
Benzyl Alcohol
U
4-ChIoro-3-methyl phenol
U
2-Chlorophenol
U
2-Methylphenol
U
3&4-Methyl Phenol
U
2,4-Dichlorophenol
U
2,4-Dimethylphenol
U
4,6-Dinitro-2-methylphenol
U
2,4-Dinitrophenol
U
2-Nitrophenol
U
4-Nitrophenol
U
Pentachlorophenol
U
Phenol
U
2,4,5-Trichlorophenol
U
2,4,6-Trichlorophenol
U
(S) Nitrobenzene-d5
60.1
(S) 2-Fluorobiphenyl
60.7
(S) p-Terphenyl-dM
65.2
(S) Phenol-d5
60.5
(S) 2-F/uorophenol
67.0
(S)2,4,6-Tribromopheno/
62.2
MB Qualifier MB MDL
mg/kg
MB RDL
mg/kg
0.00861
0.0333
0.00889
0.0333
0.00755
0.333
0.00850
0.333
0.00639
0.333
0.00695
0.333
0.0647
0.333
0.0900
0.333
0.00906
0.333
0.00528
0.0333
0.0103
0.333
0.0120
0.333
0.0109
0.333
0.00691
0.333
0.00540
0.333
0.00907
0.333
0.0123
0.0333
0.00876
0.333
0.00750
0.333
0.00477
0.333
0.00831
0.333
0.00986
0.333
0.00783
0.333
0.00746
0.333
0.0471
0.333
0.124
0.333
0.0980
0.333
0.0130
0.333
0.0525
0.333
0.0480
0.333
0.00695
0.333
0.0104
0.333
0.00779
0.333
10.0-122
15.0-120
10.0-120
10.0-120
12.0-120
10.0-127
FP1
FTC
FSS
4
Cn
FSr
�GI
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC CRP-001 L1058130 01/22/19 07:19 28 of 36

WG1219776 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 8270D L1058130-01,02,03
ONE LAB. NATIONWIDE.
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3373827-1 01/06/19 22:49 • (LCSD) R3373827-2 01/06/19 23:11
Spike Amount
LCS Result
LCSD Result
Analyte
mg/kg
mg/kg
mg/kg
Acenaphthene
0.666
0.496
0.494
Atrazine
0.666
0.557
0.568
Acenaphthylene
0.666
0.491
0.497
Benzaldehyde
0.666
0.381
0.272
Acetophenone
0.666
0.481
0.478
Anthracene
0.666
0.491
0.490
Azobenzene
0.666
0.468
0.465
Benzidine
0.666
ND
ND
Biphenyl
0.666
0.469
0.471
Benzo(a)anth race ne
0.666
0.479
0.483
Benzo(b)fluoranthene
0.666
0.491
0.509
Benzo(k)fluoranthene
0.666
0.513
0.494
Benzo(g,h,i)perylene
0.666
0.502
0.512
Benzo(a)pyrene
0.666
0.492
0.487
Caprolactam
0.666
0.636
0.636
Carbazole
0.666
0.522
0.537
Bis(2-chlorethoxy)methane
0.666
0.379
0.373
Bis(2-chloroethyl)ether
0.666
0.480
0.471
Bis(2-chloroisopropyl)ether
0.666
0.469
0.465
4-Bromophenyl-phenylether
0.666
0.544
0.541
1,2-Dichlorobenzene
0.666
0.479
0.475
4-Chloroaniline
0.666
0.345
0.337
1,3-Dichlorobenzene
0.666
0.455
0.450
2-Chloronaphthalene
0.666
0.469
0.474
1,4-Dichlorobenzene
0.666
0.462
0.465
4-Chlorophenyl-phenylether
0.666
0.525
0.526
Chrysene
0.666
0.490
0.493
Dibenz(a,h)anthracene
0.666
0.489
0.495
Dibenzofuran
0.666
0.492
0.494
3,3-Dichlorobenzidine
0.666
0.435
0.442
2,4-Dinitrotoluene
0.666
0.592
0.596
2,6-Dinitrotoluene
0.666
0.552
0.552
Fluoranthene
0.666
0.513
0.521
Fluorene
0.666
0.507
0.514
Hexachlorobenzene
0.666
0.540
0.543
Hexachloro-1,3-butadiene
0.666
0.427
0.432
Hexachlorocyclopentadiene
0.666
0.513
0.503
Hexachloroethane
0.666
0.469
0.467
Indeno(1,2,3-cd)pyrene
0.666
0.487
0.497
Isophorone
0.666
0.387
0.386
ACCOUNT:
Hart and Hickman, PC
LCS Rec.
LCSD Rec.
Rec. Limits
LCS Qualifier LCSD Qualifier RPD
RPD Limits
74.5
74.2
38.0-120
0.404
22
83.6
85.3
43.0-120
1.96
21
73.7
74.6
40.0-120
1.21
22
57.2
40.8
10.0-160
33.4
40
72.2
71.8
29.0-120
0.626
27
73.7
73.6
42.0-120
0.204
20
70.3
69.8
43.0-120
0.643
20
0.000
0.000
1.00-120
J4 J4 0.000
40
70.4
70.7
39.0-120
0.426
24
71.9
72.5
44.0-120
0.832
20
73.7
76.4
43.0-120
3.60
22
77.0
74.2
44.0-120
3.77
21
75.4
76.9
43.0-120
1.97
22
73.9
73.1
45.0-120
1.02
20
95.5
95.5
38.0-120
0.000
20
78.4
80.6
48.0-120
2.83
20
56.9
56.0
20.0-120
1.60
23
72.1
70.7
16.0-120
1.89
31
70.4
69.8
23.0-120
0.857
30
81.7
81.2
40.0-120
0.553
21
71.9
71.3
32.0-120
0.839
30
51.8
50.6
18.0-120
2.35
25
68.3
67.6
30.0-120
1.10
31
70.4
71.2
35.0-120
1.06
24
69.4
69.8
31.0-120
0.647
31
78.8
79.0
40.0-120
0.190
22
73.6
74.0
43.0-120
0.610
20
73.4
74.3
44.0-120
1.22
22
73.9
74.2
44.0-120
0.406
21
65.3
66.4
28.0-120
1.60
23
88.9
89.5
45.0-120
0.673
21
82.9
82.9
42.0-120
0.000
21
77.0
78.2
44.0-120
1.55
21
76.1
77.2
41.0-120
1.37
22
81.1
81.5
39.0-120
0.554
21
64.1
64.9
15.0-120
1.16
28
77.0
75.5
15.0-120
1.97
31
70.4
70.1
17.0-120
0.427
31
73.1
74.6
45.0-120
2.03
21
58.1
58.0
23.0-120
0.259
23
PROJECT:
SDG:
DATE/TIME: PAGE:
CRP-001
L1058130
01/22/19 07:19 29 of 36
FP1
FTC
FSS
[Cn]
FSr
�GI
FAI
FSC

WG1219776 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 8270D L1058130-01,02,03
ONE LAB. NATIONWIDE.
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3373827-1 01/06/19 22:49 • (LCSD) R3373827-2 01/06/19 23:11
Spike Amount
LCS Result
LCSD Result
Analyte
mg/kg
mg/kg
mg/kg
2-Methylnaphthalene
0.666
0.396
0.394
Naphthalene
0.666
0.382
0.381
2-Nitroaniline
0.666
0.558
0.571
3-Nitroaniline
0.666
0.504
0.484
4-Nitroaniline
0.666
0.620
0.555
Nitrobenzene
0.666
0.397
0.388
n-Nitrosodimethyla mine
0.666
0.451
0.444
n-Nitrosodiphenyla mine
0.666
0.509
0.504
n-Nitrosodi-n-propylamine
0.666
0.495
0.492
Phenanthrene
0.666
0.487
0.483
Benzylbutyl phthalate
0.666
0.510
0.512
Bis(2-ethylhexyl)phthalate
0.666
0.509
0.511
Di-n-butyl phthalate
0.666
0.535
0.538
Diethyl phthalate
0.666
0.547
0.536
Dimethyl phthalate
0.666
0.522
0.524
Di-n-octyl phthalate
0.666
0.520
0.522
Pyrene
0.666
0.495
0.498
1,2,4-Trichlorobenzene
0.666
0.410
0.404
Benzyl Alcohol
0.666
0.262
0.266
4-ChIoro-3-methyl phenol
0.666
0.435
0.440
2-Chlorophenol
0.666
0.502
0.496
2-Methylphenol
0.666
0.591
0.566
3&4-Methyl Phenol
0.666
0.595
0.587
2,4-Dichlorophenol
0.666
0.441
0.434
2,4-Dimethylphenol
0.666
0.408
0.383
4,6-Dinitro-2-methylphenol
0.666
0.460
0.458
2,4-Dinitrophenol
0.666
0.277
0.245
2-Nitrophenol
0.666
0.441
0.449
4-Nitrophenol
0.666
0.538
0.536
Pentachlorophenol
0.666
0.459
0.485
Phenol
0.666
0.471
0.456
2,4,5-Trichlorophenol
0.666
0.481
0.504
2 4 6-Trichlorophenol
0.666
0.493
0.500
(S) Nitrobenzene-d5
(S) 2-Fluorobiphenyl
(S) p-Terphenyl-d14
(S) Phenol-d5
(S) 2-F/uorophenol
(S) 2,4,6-Tribromophenol
LCS Rec. LCSD Rec.
59.5
57.4
83.8
75.7
93.1
59.6
67.7
76.4
74.3
73.1
76.6
76.4
80.3
82.1
78.4
78.1
74.3
61.6
39.3
65.3
75.4
88.7
89.3
66.2
61.3
69.1
41.6
66.2
80.8
68.9
70.7
72.2
74.0
61.0
74.2
76.3
74.6
83.2
85.3
59.2
57.2
85.7
72.7
83.3
58.3
66.7
75.7
73.9
72.5
76.9
76.7
80.8
80.5
78.7
78.4
74.8
60.7
39.9
66.1
74.5
85.0
88.1
65.2
57.5
68.8
36.8
67.4
80.5
72.8
68.5
75.7
75.1
58.3
72.4
74.8
71.3
78.7
83.0
Rec. Limits
34.0-120
18.0-120
46.0-120
36.0-120
36.0-120
17.0-120
10.0-125
40.0-120
26.0-120
42.0-120
40.0-120
41.0-120
43.0-120
43.0-120
43.0-120
40.0-120
41.0-120
17.0-120
10.0-120
28.0-120
28.0-120
35.0-120
42.0-120
25.0-120
15.0-120
16.0-120
10.0-120
20.0-120
27.0-120
29.0-120
28.0-120
38.0-120
37.0-120
10.0-122
15.0-120
10.0-120
10.0-120
12.0-120
10.0-127
LCS Qualifier LCSD Qualifier RPD
RPD Limits
0.506
22
0.262
24
2.30
22
4.05
22
11.1
23
2.29
26
1.56
33
0.987
21
0.608
27
0.825
20
0.391
21
0.392
21
0.559
20
2.03
21
0.382
22
0.384
21
0.604
21
1.47
26
1.52
33
1.14
20
1.20
28
4.32
24
1.35
25
1.60
21
6.32
26
0.436
33
12.3
40
1.80
25
0.372
24
5.51
25
3.24
27
4.67
24
1.41
24
FP1
FTC
FSS
[Cn]
FSr
�GI
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC CRP-001 L1058130 01/22/19 07:19 30 of 36

WG1219776 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 8270D 1-1058130-01,02,03
ONE LAB. NATIONWIDE.
L1O5813O-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1058130-01 01/07/19 05:25 • (MS) R3373827-4 01/07/19 04:38 • (MSD) R3373827-5 01/07/19 05:01
Spike Amount
Original Result
MS Result (dry)
MSD Result
MS Rec.
MSD Rec.
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD
(dry)
(dry)
(dry)
Analyte
mg/kg
mg/kg
mg/kg
mg/kg
%
%
%
%
Atrazine
0.802
U
0.578
0.531
72.1
68.7
1 20.0-131
8.47
Benzaldehyde
0.802
U
0.396
0.464
49.4
60.0
1 10.0-160
15.7
Acenaphthene
0.802
U
0.461
0.447
57.5
57.8
1 18.0-120
3.18
Acenaphthylene
0.802
U
0.465
0.453
58.0
58.6
1 25.0-120
2.62
Biphenyl
0.802
U
0.440
0.438
54.8
56.7
1 15.0-120
0.274
Acetophenone
0.802
U
0.403
0.429
50.3
55.5
1 10.0-120
6.08
Anthracene
0.802
U
0.485
0.444
60.5
57.5
1 22.0-120
8.81
Azobenzene
0.802
U
0.429
0.401
53.5
51.9
1 18.0-120
6.68
Caprolactam
0.802
U
0.588
0.458
73.3
59.2
1 11.0-141
24.9
Carbazole
0.802
U
0.549
0.505
68.5
65.3
1 31.0-120
8.46
Benzidine
0.802
U
ND
ND
0.000
0.000
1 1.00-120
J6 J6 0.000
Benzo(a)anth race ne
0.802
U
0.519
0.476
64.7
61.5
1 25.0-120
8.72
Benzo(b)fluoranthene
0.802
U
0.495
0.438
61.7
56.7
1 19.0-122
12.1
Benzo(k)fuoranthene
0.802
U
0.488
0.459
60.8
59.3
1 23.0-120
6.11
Benzo(g,h,i)perylene
0.802
U
0.568
0.512
70.9
66.2
1 10.0-120
10.5
Benzo(a)pyrene
0.802
U
0.500
0.450
62.3
58.3
1 24.0-120
10.4
1,2-Dichlorobenzene
0.802
U
0.378
0.415
47.1
53.7
1 10.0-120
9.41
1,3-Dichlorobenzene
0.802
U
0.360
0.399
44.9
51.6
1 10.0-120
10.2
Bis(2-chIorethoxy)methane
0.802
U
0.340
0.343
42.3
44.4
1 10.0-120
1.06
1,4-Dichlorobenzene
0.802
U
0.372
0.412
46.4
53.3
1 10.0-120
10.1
Bis(2-chIoroethyl) ether
0.802
U
0.382
0.413
47.6
53.4
1 10.0-120
7.88
Bis(2-chIoroIsopropyl)ether
0.802
U
0.381
0.400
47.4
51.7
1 10.0-120
4.94
4-Bromophenyl-phenylether
0.802
U
0.538
0.506
67.1
65.4
1 27.0-120
6.23
4-Chloroaniline
0.802
U
0.307
0.241
38.3
31.2
1 10.0-120
24.2
2-Chloronaphthalene
0.802
U
0.440
0.436
54.8
56.4
1 20.0-120
0.825
4-C h I o ro p h e nyl -p h e n yl et h e r
0.802
U
0.491
0.467
61.3
60.4
1 24.0-120
5.03
Chrysene
0.802
U
0.515
0.487
64.3
62.9
1 21.0-120
5.77
Dibenz(a,h)anth racene
0.802
U
0.536
0.483
66.8
62.5
1 10.0-120
10.4
Dibenzofuran
0.802
U
0.466
0.441
58.1
57.0
1 24.0-120
5.58
3,3-D1chIorobenzidine
0.802
U
0.273
0.226
34.1
29.3
1 10.0-120
18.8
2,4-Dinitrotoluene
0.802
U
0.573
0.532
71.5
68.8
1 30.0-120
7.41
2,6-Dinitrotoluene
0.802
U
0.529
0.458
65.9
59.2
1 25.0-120
14.4
Fluoranthene
0.802
U
0.525
0.489
65.5
63.2
1 18.0-126
7.13
Fluorene
0.802
U
0.496
0.468
61.9
60.6
1 25.0-120
5.74
Hexachlorobenzene
0.802
U
0.544
0.507
67.9
65.6
1 27.0-120
7.10
HexachIoro-1,3-butadiene
0.802
U
0.375
0.397
46.7
51.4
1 10.0-120
5.93
H exa c h I o rocyc I o p e nta d I e n e
0.802
U
0.343
0.354
42.8
45.8
1 10.0-120
3.11
Hexachloroethane
0.802
U
0.366
0.395
45.6
51.1
1 10.0-120
7.59
Indeno(1,2,3-cd)pyre ne
0.802
U
0.559
0.497
69.7
64.3
1 10.0-120
11.6
RPD Limits
28
40
32
32
33
37
29
27
31
24
40
29
31
30
33
30
38
40
34
39
40
40
30
36
32
29
29
32
30
34
31
31
32
30
28
38
40
40
32
FP1
FTc
FSS
E
FSr
�GI
$AI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC CRP-001 L1058130 01/22/19 07:19 31 of 36

WG1219776 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 8270D 1-1058130-01,02,03
ONE LAB. NATIONWIDE.
L1O5813O-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1058130-01 01/07/19 05:25 • (MS) R3373827-4 01/07/19 04:38 • (MSD) R3373827-5 01/07/19 05:01
Spike Amount
Original Result
MS Result (dry)
MSD Result MS Rec.
MSD Rec.
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD
RPD Limits
(dry)
(dry)
(dry)
Analyte
mg/kg
mg/kg
mg/kg
mg/kg
%
%
%
%
%
Isophorone
0.802
U
0.355
0.348
44.3
45.0
1 13.0-120
2.05
34
2-Methylnaphthalene
0.802
U
0.370
0.367
46.1
47.5
1 10.0-120
0.654
37
Naphthalene
0.802
U
0.347
0.364
43.2
47.0
1 10.0-120
4.75
35
2-Nitroaniline
0.802
U
0.538
0.511
67.1
66.0
1 24.0-120
5.28
30
3-Nitroaniline
0.802
U
0.478
0.440
59.6
56.9
1 11.0-120
8.40
32
4-Nitroaniline
0.802
U
0.601
0.553
74.9
71.5
1 15.0-120
8.35
31
Nitrobenzene
0.802
U
0.341
0.353
42.5
45.6
1 10.0-120
3.47
36
n-NitrosodImethylamIne
0.802
U
0.320
0.394
39.9
50.9
1 10.0-127
20.6
40
n-Nitrosod1phenylam1ne
0.802
U
0.452
0.413
56.3
53.4
1 17.0-120
8.91
29
n-NitrosodI-n-propylamIne
0.802
U
0.409
0.424
51.1
54.8
1 10.0-120
3.47
37
Phenanthrene
0.802
U
0.483
0.459
60.2
59.3
1 17.0-120
5.12
31
Benzylbutyl phthalate
0.802
U
0.549
0.511
68.5
66.0
1 23.0-120
7.27
30
Bis(2-ethylhexyl)phthalate
0.802
U
0.544
0.507
67.9
65.6
1 17.0-126
7.10
30
Di-n-butyl phthalate
0.802
U
0.552
0.505
68.8
65.3
1 30.0-120
8.89
29
Diethyl phthalate
0.802
U
0.531
0.471
66.2
60.9
1 26.0-120
12.0
28
Dimethyl phthalate
0.802
U
0.503
0.478
62.8
61.8
1 25.0-120
5.15
29
Di-n-octyl phthalate
0.802
U
0.565
0.517
70.4
66.8
1 21.0-123
8.91
29
Pyrene
0.802
U
0.536
0.499
66.8
64.5
1 16.0-121
7.22
32
1,2,4-Trichlorobenzene
0.802
U
0.362
0.379
45.2
49.1
1 12.0-120
4.55
37
Benzyl Alcohol
0.802
U
0.113
0.496
14.0
64.2
1 10.0-136
J3 126
40
4-ChIoro-3-methyl phenol
0.802
U
0.440
0.407
54.8
52.6
1 15.0-120
7.68
30
2-Chlorophenol
0.802
U
0.424
0.437
52.9
56.5
1 15.0-120
3.08
37
2-Methylphenol
0.802
U
0.540
0.612
67.3
79.1
1 11.0-120
12.6
40
3&4-Methyl Phenol
0.802
U
0.546
0.515
68.0
66.7
1 12.0-123
5.68
38
2,4-Dichlorophenol
0.802
U
0.437
0.418
54.5
54.0
1 20.0-120
4.51
31
2,4-Dimethylphenol
0.802
U
0.393
0.297
48.9
38.5
1 10.0-120
27.6
33
4,6-Dinitro-2-methylphenol
0.802
U
0.521
0.483
65.0
62.5
1 10.0-120
7.67
39
2,4-Dinitrophenol
0.802
U
0.414
0.401
51.7
51.9
1 10.0-121
3.25
40
2-Nitrophenol
0.802
U
0.414
0.423
51.7
54.7
1 12.0-120
2.01
39
4-Nitrophenol
0.802
U
0.541
0.482
67.4
62.3
1 10.0-137
11.5
32
Pentachlorophenol
0.802
U
0.531
0.468
66.2
60.6
1 10.0-160
12.5
31
Phenol
0.802
U
0.395
0.385
49.2
49.8
1 12.0-120
2.47
38
2,4,5-Trichlorophenol
0.802
U
0.496
0.428
61.9
55.3
1 20.0-120
14.9
30
2,4,6-Trichlorophenol
0.802
U
0.477
0.487
59.5
62.9
1 19.0-120
2.00
32
(S) Nitrobenzene-d5
41.1
44.9
10.0-122
(S) 2-F/uorobipheny/
54.4
56.1
15.0-120
(S) p-Terphenyl-dM
65.2
62.0
10.0-120
(S) Phenol-d5
50.2
51.1
10.0-120
(S) 2-F/uorophenol
52.4
57.0
12.0-120
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
Hart
and Hickman, PC
CRP-001
L1058130
01/22/19 07:19
PAGE:
32 of 36
FP1
FTc
FSS
E
FSr
�GI
$AI
FSC

WG1219776 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 8270D 1-1058130-01,02,03
L1O5813O-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1058130-01 01/07/19 05:25 • (MS) R3373827-4 01/07/19 04:38 • (MSD) R3373827-5 01/07/19 05:01
Spike Amount Original Result MS Result (dry) MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD
(dry) (dry) (dry)
Analyte mg/kg mg/kg mg/kg mg/kg % % % %
(S) 2,4,6-Tribromopheno/ 70.0
66.8 10.0-127
ONE LAB. NATIONWIDE.
RPD Limits
FP1
FTc
FSS
4
Cn
FSr
�GI
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC CRP-001 L1058130 01/22/19 07:19 33 of 36

GLOSSARY OF TERMS
Guide to Reading and Understanding Your Laboratory Report
ONE LAB. NATIONWIDE.
The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not
intended as a comprehensive explanation, and if you have additional questions please contact your project representative.
and Definitions
CP
IP
FTCAbbreviations
(dry)
Results are reported based on the dry weight of the sample. [this will only be present on a dry report basis for soils].
MDL
Method Detection Limit.
FS
MDL (dry)
Method Detection Limit.
ND
Not detected at the Reporting Limit (or MDL where applicable).
RDL
Reported Detection Limit.
[Cn]
RDL (dry)
Reported Detection Limit.
Rec.
Recovery.
Fr
RPD
Relative Percent Difference.
SDG
Sample Delivery Group.
Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and
PC
(S)
Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be
detected in all environmental media.
U
Not detected at the Reporting Limit (or MDL where applicable).
Analyte
The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes
reported.
$
If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the
AI
Dilution
standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the
laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the
result reported has already been corrected for this factor.
FC
These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal
Limits
for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or
duplicated within these ranges.
Original Sample
The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control
sample. The Original Sample may not be included within the reported SDG.
This column provides a letter and/or number designation that corresponds to additional information concerning the result
Qualifier
reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and
potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable.
The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was
no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL"
Result
(Below Detectable Levels). The information in the results column should always be accompanied by either an MDL
(Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect
or report for this analyte.
Uncertainty
(Radiochemistry)
Confidence level of 2 sigma.
A brief discussion about the included sample results, including a discussion of any non -conformances to protocol
Case Narrative (Cn)
observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will
be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.
Quality Control
This section of the report includes the results of the laboratory quality control analyses required by procedure or
Summary (Qc)
analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not
being performed on your samples typically, but on laboratory generated material.
This is the document created in the field when your samples were initially collected. This is used to verify the time and
Sample Chain of
date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This
Custody (Sc)
chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the
samples from the time of collection until delivery to the laboratory for analysis.
This section of your report will provide the results of all testing performed on your samples. These results are provided
Sample Results (Sr)
by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for
each sample will provide the name and method number for the analysis reported.
Sample Summary (Ss)
This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and
times of preparation and/or analysis.
Qualifier
Description
E
The analyte concentration exceeds the upper limit of the calibration range of the instrument established by the initial
calibration (ICAL).
J
The identification of the analyte is acceptable; the reported value is an estimate.
J1
Surrogate recovery limits have been exceeded; values are outside upper control limits.
J3
The associated batch QC was outside the established quality control range for precision.
J4
The associated batch QC was outside the established quality control range for accuracy.
J5
The sample matrix interfered with the ability to make any accurate determination; spike value is high.
J6
The sample matrix interfered with the ability to make any accurate determination; spike value is low.
v
The sample concentration is too high to evaluate accurate spike recoveries.
ACCOUNT:
PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC
CRP-001 L1058130 01/22/19 07:19 34 of 36

ACCREDITATIONS & LOCATIONS ONE LAB. NATIONWIDE.
Pace National is the only environmental laboratory accredited/certified to support your work nationwide from one location. One phone call, one point of contact, one laboratory. No other lab is as
accessible or prepared to handle your needs throughout the country. Our capacity and capability from our single location laboratory is comparable to the collective totals of the network
laboratories in our industry. The most significant benefit to our one location design is the design of our laboratory campus. The model is conducive to accelerated productivity, decreasing FP1
turn -around time, and preventing cross contamination, thus protecting sample integrity. Our focus on premium quality and prompt service allows us to be YOUR LAB OF CHOICE.
Not all certifications held by the laboratory are applicable to the results reported in the attached report.
Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace National. Z
Tc
State Accreditations
f—�
Alabama
40660
Nebraska _
NE-OS-15-05
SS
Alaska
17-026
Nevada
TN-03-2002-34
Arizona
AZO612
New Hampshire
2975
Arkansas
88-0469
New Jersey_NELAP
TNO02
C n
California
2932
New Mexico
n/a
Colorado
TN00003
New York
11742
s
Connecticut
PH-0197
North Carolina
Env375
Sr
Florida
E87487
North Carolina'
DW21704
Georgia
NELAP
North Carolina'
41
Georgia'
923
North Dakota
R-140
RC
Idaho
TN00003
Ohio—VAP
CL0069
Illinois
200008
Oklahoma
9915
Indiana
C-TN-01
Oregon
TN200002
G
Iowa
364
Pennsylvania
68-02979
Kansas
E-10277
Rhode Island
LA000356
Kentucky76
90010
South Carolina
84004
Kentucky 2
16
South Dakota
n/a
Louisiana
A130792
Tennessee' 4
2006
Louisiana'
LA180010
Texas
T 104704245-17-14
[SC
Maine
TN0002
Texas'
LABO152
Maryland
324
Utah
Massachusetts
M-TNO03
Vermont
Michigan
9958
Virginia
Minnesota
047-999-395
Washington
Mississippi
TN00003
West Virginia
Missouri
340
Wisconsin
Montana
CERT0086
Wyoming
Third Party
Federal Accreditations
A21LA — ISO 17025
1461.01
AIHA-LAP,LLC EMLAP
A21LA — ISO 17025 5
1461.02
DOD
Canada
1461.01
USDA
EPA—Crypto
TN00003
' Drinking Water 'Underground
Storage Tanks 3 Aquatic Toxicity 4 Chemical/Microbiological 5 Mold
6 Wastewater n/a Accreditation not applicable
Our Locations
TN00003
VT2006
460132
C847
233
9980939910
A2LA
100789
1461.01
P330-15-00234
Pace National has sixty-four client support centers that provide sample pickup and/or the delivery of sampling supplies. If you would like assistance from one of our support offices, please contact
our main office. Pace National performs all testing at our central laboratory.
WA
ME
MT NO
OR MN
T ID t WI NY
SD
WY MI
NV
t NE IA OH PA
T f IL Ills WV
vA
UT T
CA�� T
KS MO KY
N
NM O� AR SC
T MS AL`7GA
T TX * LA
T
AK
q FL
wo HI
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC CRP-001 L1058130 01/22/19 07:19 35 of 36

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Pace Analytical - Huntersville, IBC
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98ID13 Kinsey Ave., Ste. 100
9800 K i ncey Avenue, Suite 100
Huntersville, NC 28078
Huntersville, NC 23078
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National Center for Testing & Innovation
r Ad
ANALYT CAL REPORT
January 17, 2019
Hart and Hickman, PC
Sample Delivery Group: L1058027
Samples Received: 01/04/2019
Project Number: LVL-001
Description: Former Witherspoon Nursery
Report To: Lisa Nickels
3334 Hillsborough Street
Raleigh, NC 27607
Entire Report Reviewed By: 4�41
Heather J Wagner
Project Manager
Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be
reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace National
is performed per guidance provided in laboratory standard operating procedures: 060302, 060303, and 060304.
V
F# 4
U
I &
4b

TABLE OF CONTENTS
ONE LAB. NATIONWIDE.
Cp: Cover Page
1
Fn
Tc: Table of Contents
2
Ss: Sample Summary
3
Cn: Case Narrative
5
Sr: Sample Results
6
FS
SED-1 L1058027-01
6
[Cn]
SED-2 L1058027-02
11
SW-1 L1058027-03
16
FSr
TRIP BLANK L1058027-04
21
SW-2 L1058027-05
23
RC
Qc: Quality Control Summary
28
GI
Total Solids by Method 2540 G-2011
28
Wet Chemistry by Method 300.0
29
rAl
Wet Chemistry by Method 7199
30
Mercury by Method 7470A
33
FSC
Mercury by Method 7471B
35
Metals (ICPMS) by Method 6020B
36
Volatile Organic Compounds (GC/MS) by Method 8260B
39
Chlorinated Acid Herbicides (GC) by Method 8151
55
OP Pesticides by Method 8141B
58
Pesticides (GC) by Method 80818
66
Semi Volatile Organic Compounds (GC/MS) by Method 8270D
70
GI: Glossary of Terms
81
Al: Accreditations & Locations
82
Sc: Sample Chain of Custody
83
ACCOUNT: PROJECT: SDG:
DATE/TIME: PAGE:
Hart and Hickman, PC LVL-001 L1058027
01/17/19 15:18 2 of 84

SED-1 L1058027-01 Solid
SAMPLE SUMMARY
Collected by
LN
Method
Batch
Total Solids by Method 2540 G-2011
WG1219475
Wet Chemistry by Method 7199
WG1221753
Mercury by Method 7471B
WG1219882
Metals (ICPMS) by Method 6020B
WG1220117
Volatile Organic Compounds (GC/MS) by Method 8260B
WG1219369
Volatile Organic Compounds (GC/MS) by Method 8260B
WG1219795
Chlorinated Acid Herbicides (GC) by Method 8151
WG1219963
OP Pesticides by Method 8141E
WG1219355
Pesticides (GC) by Method 8081B
WG1219182
Semi Volatile Organic Compounds (GC/MS) by Method 8270D
WG1219730
SED-2 L1058027-02 Solid
Method
Wet Chemistry by Method 7199
Mercury by Method 7471E
Metals (ICPMS) by Method 6020B
Volatile Organic Compounds (GC/MS) by Method 8260E
Chlorinated Acid Herbicides (GC) by Method 8151
OP Pesticides by Method 8141E
Pesticides (GC) by Method 8081E
Semi Volatile Organic Compounds (GC/MS) by Method 8270D
SW-1 L1058027-03 GW
Batch
WG1219475
WG1221753
WG1219882
WG1220117
WG1219795
WG1219963
WG1219897
WG1219182
WG1219730
Dilution Preparation
date/time
1 01/08/1914:08
1 01/11/1911:09
1 01/06/1913:16
5 01/07/1911:16
1.01 01/03/1913:00
1.01 01/03/1913:00
1 01/07/19 05:46
1 01/05/1910:34
1 01/04/1919:06
1 01/05/1918:03
Collected by
LN
Dilution Preparation
date/time
1 01/08/1914:08
1 01/11/1911:09
1 01/06/1913:16
5 01/07/1911:16
1 01/03/1915:30
1 01/07/19 05:46
1 01/07/1916:58
1 01/04/1919:06
2 01/05/1918:03
Collected by
LN
ONE LAB. NATIONWIDE.
Collected date/time
Received date/time
01/03/1913:00
01/04/19 08:45
FP1
Analysis
Analyst
date/time
FTC
01/08/1914:33
JD
01/11/19
MCG
07/19 09:
01/07/19 09:56
JD
01/07/19 22:38
JD
01/05/19 02:02
GLN
[Cn]
01/06/1919:18
GLN
01/07/1918:15
JF
01/09/1918:50
HMH
FSr
01/07/19 20:59
VKS
01/06/1915:30
JF
RC
Collected date/time
Received date/time
GI
01/03/1915:30
01/04/19 08:45
Analysis
Analyst
rzl
date/time
01/08/1914:33
JD
01/11/1915:34
01/07/19 09 59
MCG
JD
FSC
01/07/19 23:18
JD
01/06/1919:40
GLN
01/07/1918:29
JF
01/09/19 20:25
HMH
01/07/19 21:11
VKS
01/06/1918:13
JF
Collected date/time Received date/time
01/03/1912:50 01/04/19 08:45
Method
Batch
Dilution Preparation
Analysis
Analyst
date/time
date/time
Wet Chemistry by Method 300.0
WG1218970
1 01/04/19 21:32
01/04/19 21:32
MCG
Wet Chemistry by Method 7199
WG1221008
1 01/09/1913:14
01/09/1913:14
MCG
Mercury by Method 7470A
WG1219858
1 01/06/1918:34
01/07/1912:10
JD
Mercury by Method 7470A
WG1219860
1 01/06/1918:23
01/07/1910:33
JD
Metals (ICPMS) by Method 6020B
WG1219455
1 01/05/1916:45
01/07/19 20:28
LID
Metals (ICPMS) by Method 6020B
WG1219940
1 01/06/1919:58
01/07/19 20:03
LID
Volatile Organic Compounds (GC/MS) by Method 8260B
WG1219077
1 01/04/1917:03
01/04/1917:03
GLN
Chlorinated Acid Herbicides (GC) by Method 8151
WG1219966
1 01/07/19 05:45
01/08/19 02:29
JF
OP Pesticides by Method 8141B
WG1219785
1 01/06/1918:48
01/09/1919:22
HMH
Pesticides (GC) by Method 8081B
WG1219731
1.02 01/08/19 08:02
01/09/1911:39
VKS
Semi Volatile Organic Compounds (GC/MS) by Method 8270D
WG1219183
1 01/04/1918:28
01/05/1912:42
JF
Collected by
Collected date/time
Received date/time
TRIP BLANK L1058027-04 GW
LN
01/03/1913:00
01/04/19 08:45
Method
Batch
Dilution Preparation
Analysis
Analyst
date/time
date/time
Volatile Organic Compounds (GC/MS) by Method 8260E
WG1219077
1 01/04/1912:33
01/04/1912:33
GLN
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
PAGE:
Hart and Hickman, PC
LVL-001
L1058027
01/17/19 15:18
3 of 84

SAMPLE SUMMARY ONE LAB. NATIONWIDE.
Collected by Collected date/time Received date/time
SW-2 L1058027-05 GW LN 01/03/1915:20 01/04/19 08:45 C
P
Method
Wet Chemistry by Method 300.0
Wet Chemistry by Method 7199
Mercury by Method 7470A
Mercury by Method 7470A
Metals (ICPMS) by Method 6020B
Metals (ICPMS) by Method 6020B
Volatile Organic Compounds (GC/MS) by Method 8260B
Chlorinated Acid Herbicides (GC) by Method 8151
OP Pesticides by Method 8141E
Pesticides (GC) by Method 8081B
Semi Volatile Organic Compounds (GC/MS) by Method 8270D
Batch
WG1218970
WG1221008
WG1219858
WG1219860
WG1219455
WG1219940
WG1219326
WG1219966
WG1219785
WG1219731
WG1219183
Dilution Preparation
date/time
1 01/04/19 21:48
1 01/09/1913:24
1 01/06/1918:34
1 01/06/1918:23
1 01/05/1916:45
1 01/06/1919:58
1 01/04/19 21:17
1 01/07/19 05:45
1 01/06/1918:48
1 01/08/19 08:02
1 01/04/1918:28
Analysis Analyst
date/time
01/04/19 21:48
01/09/1913:24
01/07/1912:13
01/07/1910:35
01/07/19 20:32
01/07/19 20:08
01/04/19 21:17
01/08/19 02:42
01/09/1919:53
01/09/1912:17
01/05/1912:18
MCG
MCG
JD
JD
LD
LD
GLN
JF
HMH
VKS
JF
FTC
M
[Cn]
FSr
RC
F,
FAI
FSC
ACCOUNT: PROJECT: SDG:
Hart and Hickman, PC LVL-001 L1058027
DATE/TIME:
01/17/19 15:18
PAGE:
4 of 84

CASE NARRATIVE
ONE LAB. NATIONWIDE.
FP1
All sample aliquots were received at the correct temperature, in the proper containers, with the
appropriate preservatives, and within method specified holding times, unless qualified or notated within
the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples
FTChave
been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control
are within established criteria except where addressed in this case narrative, a non-conformance form
or properly qualified within the sample results. By my digital signature below, I affirm to the best of my
FSS
knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the
quality of the data have been identified by the laboratory, and no information or data have been
knowingly withheld that would affect the quality of the data.
FSr
FC-1
4�j
�GI
Heather J Wagner
FAI
Project Manager
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC LVL-001 L1058027 01/17/19 15:18 5 of 84

SED-1
Collected date/time: 01/03/19 13:00
Total Solids by Method 2540 G-2011
SAMPLE RESULTS - 01
L1058027
Result Qualifier Dilution Analysis Batch
Analyte % date / time
Total Solids 73.5 1 01/08/201914:33 WG1219475
Wet Chemistry by Method 7199
Result (dry)
Analyte mg/kg
Hexavalent Chromium U
Mercury by Method 7471B
Result (dry)
Analyte mg/kg
Mercury 0.0103
Metals (ICPMS) by Method 6020B
Qualifier MDL (dry) RDL (dry) Dilution Analysis
mg/kg mg/kg date / time
0.347 1.36 1 01/11/201915:19
ONE LAB. NATIONWIDE.
Cp
FTC
FSS
Batch
r
WG1221753 Cn
Batch
C
J
6^0.00381 0.0272 1 01/07/2019 09:56 WG1219882 lam!!
_ 7
Qualifier MDL (dry) RDL (dry) Dilution Analysis
mg/kg mg/kg date/time
Result (dry)
Qualifier MDL (dry)
RDL (dry)
Dilution
Analysis
Analyte
mg/kg
mg/kg
mg/kg
date / time
Arsenic
4.39
0.170
0.680
5
01/07/2019 22:38
Barium
148
0.218
1.36
5
01/07/2019 22:38
Cadmium
U
0.109
0.680
5
01/07/2019 22:38
Chromium
36.6
J5 0.367
1.36
5
01/07/2019 22:38
Lead
17.3
0.163
0.680
5
01/07/2019 22:38
Selenium
0.396
1_ 0.258
0.680
5
01/07/2019 22:38
Silver
U
0.211
0.680
5
01/07/2019 22:38
Volatile Organic Compounds (GC/MS) by Method 8260B
Analyte
Acetone
Acrylonitrile
Benzene
Bromobenzene
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec -Butyl benzene
ter[-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dibromoethane
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
Result (dry)
mg/kg
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
ACCOUNT:
Hart and Hickman, PC
Batch
WG122011
WG122011
WG1220117
WG1220117
WG1220117
WG1220117
WG1220117
7
7
FSC
I$AI
Qualifier MDL (dry) RDL (dry) Dilution Analysis Batch
mg/kg mg/kg date / time
0.0188 0.0343 1.01 01/05/2019 02:02 WG1219369
0.00261 0.0172 1.01 01/05/2019 02:02 WG1219369
0.000549 0.00137 1.01 01/05/2019 02:02 WG1219369
0.00144 0.0172 1.01 01/05/2019 02:02 WG1219369
0.00108 0.00343 1.01 01/05/2019 02:02 WG1219369
0.00821 0.0343 1.01 01/05/2019 02:02 WG1219369
0.00509 0.0172 1.01 01/06/201919:18 WG1219795
0.00528 0.0172 1.01 01/06/201919:18 WG1219795
0.00348 0.0172 1.01 01/05/2019 02:02 WG1219369
0.00212 0.00687 1.01 01/05/2019 02:02 WG1219369
0.00148 0.00687 1.01 01/05/2019 02:02 WG1219369
0.000787 0.00343 1.01 01/05/2019 02:02 WG1219369
0.000617 0.00343 1.01 01/05/2019 02:02 WG1219369
0.00148 0.00687 1.01 01/05/2019 02:02 WG1219369
0.000570 0.00343 1.01 01/05/2019 02:02 WG1219369
0.00190 0.0172 1.01 01/05/2019 02:02 WG1219369
0.00126 0.00343 1.01 01/05/2019 02:02 WG1219369
0.00155 0.00687 1.01 01/05/2019 02:02 WG1219369
0.00700 0.0343 1.01 01/05/2019 02:02 WG1219369
0.000721 0.00343 1.01 01/05/2019 02:02 WG1219369
0.00137 0.00687 1.01 01/05/2019 02:02 WG1219369
0.00199 0.00687 1.01 01/05/2019 02:02 WG1219369
0.00234 0.00687 1.01 01/05/2019 02:02 WG1219369
0.00271 0.00687 1.01 01/05/2019 02:02 WG1219369
0.00112 0.00343 1.01 01/05/2019 02:02 WG1219369
0.000790 0.00343 1.01 01/05/2019 02:02 WG1219369
0.000653 0.00343 1.01 01/05/2019 02:02 WG1219369
0.000687 0.00343 1.01 01/05/2019 02:02 WG1219369
PROJECT: SDG: DATE/TIME: PAGE:
LVL-001 L1058027 01/17/19 15:18 6 of 84
Qualifier MDL (dry) RDL (dry) Dilution Analysis Batch
mg/kg mg/kg date / time
0.0188 0.0343 1.01 01/05/2019 02:02 WG1219369
0.00261 0.0172 1.01 01/05/2019 02:02 WG1219369
0.000549 0.00137 1.01 01/05/2019 02:02 WG1219369
0.00144 0.0172 1.01 01/05/2019 02:02 WG1219369
0.00108 0.00343 1.01 01/05/2019 02:02 WG1219369
0.00821 0.0343 1.01 01/05/2019 02:02 WG1219369
0.00509 0.0172 1.01 01/06/201919:18 WG1219795
0.00528 0.0172 1.01 01/06/201919:18 WG1219795
0.00348 0.0172 1.01 01/05/2019 02:02 WG1219369
0.00212 0.00687 1.01 01/05/2019 02:02 WG1219369
0.00148 0.00687 1.01 01/05/2019 02:02 WG1219369
0.000787 0.00343 1.01 01/05/2019 02:02 WG1219369
0.000617 0.00343 1.01 01/05/2019 02:02 WG1219369
0.00148 0.00687 1.01 01/05/2019 02:02 WG1219369
0.000570 0.00343 1.01 01/05/2019 02:02 WG1219369
0.00190 0.0172 1.01 01/05/2019 02:02 WG1219369
0.00126 0.00343 1.01 01/05/2019 02:02 WG1219369
0.00155 0.00687 1.01 01/05/2019 02:02 WG1219369
0.00700 0.0343 1.01 01/05/2019 02:02 WG1219369
0.000721 0.00343 1.01 01/05/2019 02:02 WG1219369
0.00137 0.00687 1.01 01/05/2019 02:02 WG1219369
0.00199 0.00687 1.01 01/05/2019 02:02 WG1219369
0.00234 0.00687 1.01 01/05/2019 02:02 WG1219369
0.00271 0.00687 1.01 01/05/2019 02:02 WG1219369
0.00112 0.00343 1.01 01/05/2019 02:02 WG1219369
0.000790 0.00343 1.01 01/05/2019 02:02 WG1219369
0.000653 0.00343 1.01 01/05/2019 02:02 WG1219369
0.000687 0.00343 1.01 01/05/2019 02:02 WG1219369
PROJECT: SDG: DATE/TIME: PAGE:
LVL-001 L1058027 01/17/19 15:18 6 of 84

ONE LAB. NATIONWIDE.
SED-1 SAMPLE RESULTS - 01
Collected date/time: 01/03/19 13:00 L1058027
Volatile Organic Compounds (GC/MS) by Method 8260B
Result (dry)
Qualifier MDL (dry)
RDL (dry)
Analyte
mg/kg
mg/kg
mg/kg
cis-1,2-Dichloroethene
U
0.000948
0.00343
trans-1,2-Dichloroethene
U
0.00196
0.00687
1,2-Dichloropropane
U
0.00174
0.00687
1,1-Dichloropropene
U
0.000961
0.00343
1,3-Dichloropropane
U
0.00241
0.00687
cis-1,3-Dichloropropene
U
0.000931
0.00343
trans-1,3-Dichloropropene
U
0.00209
0.00687
2,2-Dichloropropane
U
0.00109
0.00343
Di -isopropyl ether
U
0.000481
0.00137
Ethylbenzene
U
0.000728
0.00343
Hexachloro-1,3-butadiene
U
0.0174
0.0343
Isopropylbenzene
U
0.00119
0.00343
p-Isopropyltoluene
U
0.00320
0.00687
2-Butanone (MEK)
U
0.0171
0.0343
Methylene Chloride
U
0.00912
0.0343
4-Methyl-2-pentanone (MIBK)
U
0.0137
0.0343
Methyl tert-butyl ether
U
0.000405
0.00137
Naphthalene
U
0.00428
0.0172
n-Propylbenzene
U
0.00162
0.00687
Styrene
U
0.00375
0.0172
1,1,1,2-Tetrachloroethane
U
0.000687
0.00343
1,1,2,2-Tetrachloroethane
U
0.000536
0.00343
1,1,2-Trichlorotrifluoroethane
U
0.000927
0.00343
Tetrachloroethene
U
0.000961
0.00343
Toluene
U
0.00171
0.00687
1,2,3-Trichlorobenzene
U
J4 0.000858
0.00343
1,2,4-Trichlorobenzene
U
0.00662
0.0172
1,1,1-Trichloroethane
U
0.000378
0.00343
1,1,2-Trichloroethane
U
0.00121
0.00343
Trichloroethene
U
0.000549
0.00137
Trichlorofluoromethane
U
0.000687
0.00343
1,2,3-Trichloropropane
U
0.00700
0.0172
1,2,4-Trimethylbenzene
U
0.00159
0.00687
1,2,3-Trimethyl benzene
U
0.00158
0.00687
1,3,5-Trimethyl benzene
U
0.00148
0.00687
Vinyl chloride
U
0.000938
0.00343
Xylenes, Total
U
0.00657
0.00893
(S) Toluene-d8
107
75.0-131
(S) Toluene-d8
101
75.0-131
(S) Dibromofluoromethane
100
65.0-129
(S) Dibromofluoromethane
88.5
65.0-129
(S) 4-Bromof/uorobenzene
92.5
67.0-138
(S) 4-Bromof/uorobenzene
94.7
67.0-138
Chlorinated Acid Herbicides (GC) by Method 8151
Result (dry)
Qualifier MDL (dry)
RDL (dry)
Analyte
mg/kg
mg/kg
mg/kg
2,4-D
U
0.00955
0.0952
Dalapon
U
0.0154
0.0952
2,4-DB
U
0.0404
0.0952
Dicamba
U
0.0213
0.0952
Dichloroprop
U
0.0333
0.0952
Dinoseb
U
0.00948
0.0952
MCPA
U
J4 0.602
8.84
MCPP
U
0.499
8.84
2,4,5-T
U
0.0116
0.0952
Dilution
Analysis
date / time
Batch
1.01
01/05/2019 02:02
WG1219369
1.01
01/05/2019 02:02
WG1219369
1.01
01/05/2019 02:02
WG1219369
1.01
01/05/2019 02:02
WG1219369
1.01
01/05/2019 02:02
WG1219369
1.01
01/05/2019 02:02
WG1219369
1.01
01/05/2019 02:02
WG1219369
1.01
01/05/2019 02:02
WG1219369
1.01
01/05/2019 02:02
WG1219369
1.01
01/06/201919:18
WG1219795
1.01
01/05/2019 02:02
WG1219369
1.01
01/05/2019 02:02
WG1219369
1.01
01/05/2019 02:02
WG1219369
1.01
01/05/2019 02:02
WG1219369
1.01
01/05/2019 02:02
WG1219369
1.01
01/05/2019 02:02
WG1219369
1.01
01/05/2019 02:02
WG1219369
1.01
01/06/201919:18
WG1219795
1.01
01/06/201919:18
WG1219795
1.01
01/05/2019 02:02
WG1219369
1.01
01/05/2019 02:02
WG1219369
1.01
01/05/2019 02:02
WG1219369
1.01
01/05/2019 02:02
WG1219369
1.01
01/05/2019 02:02
WG1219369
1.01
01/05/2019 02:02
WG1219369
1.01
01/05/2019 02:02
WG1219369
1.01
01/05/2019 02:02
WG1219369
1.01
01/05/2019 02:02
WG1219369
1.01
01/05/2019 02:02
WG1219369
1.01
01/05/2019 02:02
WG1219369
1.01
01/05/2019 02:02
WG1219369
1.01
01/05/2019 02:02
WG1219369
1.01
01/06/201919:18
WG1219795
1.01
01/06/201919:18
WG1219795
1.01
01/06/201919:18
WG1219795
1.01
01/05/2019 02:02
WG1219369
1.01
01/05/2019 02:02
WG1219369
0110512019 02:02
WG1219369
011061201919:18
WG1219795
0110512019 02:02
WG1219369
011061201919:18
WG1219795
0110512019 02:02
WG1219369
011061201919:18
WG1219795
Dilution Analysis Batch
date / time
1 01/07/201918:15
WG1219963
1 01/07/201918:15
WG1219963
1 01/07/201918:15
WG1219963
1 01/07/201918:15
WG1219963
1 01/07/201918:15
WG1219963
1 01/07/201918:15
WG1219963
1 01/07/201918:15
WG1219963
1 01/07/201918:15
WG1219963
1 01/07/201918:15
WG1219963
Fp
FTc
FSS
Fn
Fc
F
FAI
FSC
ACCOUNT: PROJECT:
Hart and Hickman, PC LVL-001
SDG: DATE/TIME: PAGE:
L1058027 01/17/19 15:18 7 of 84

SED-1 SAMPLE RESULTS - 01
Collected date/time: 01/03/19 13:00 L1058027
Chlorinated Acid Herbicides (GC) by Method 8151
ONE LAB. NATIONWIDE.
Result (dry)
Analyte mg/kg
2,4,5-TP (Silvex) U
(S)2,4-Dichloropheny/Acetic Acid 55.0
CIP Pesticides by Method 8141B
Result (dry)
Analyte
mg/kg
Azinphos-Methyl
U
Bolstar (Sulprofos)
U
Chlorpyrifos
U
Coumaphos
U
Demeton,-0 and -S
U
Diazinon
U
Dichlorvos
U
Dimethoate
U
Disulfoton
U
EPN
U
Ethoprop
U
Ethyl Parathion
U
Fensulfothion
U
Fenthion
U
Marathion
U
Merphos
U
Methyl parathion
U
Mevinphos
U
Naled
U
Phorate
U
Ronnel
U
Stirophos
U
Sulfotep
U
TEPP
U
Tokuthion (Prothothiofos)
U
Trichloronate
U
(S) Trlpheny/ Phosphate
73.0
Pesticides (GC) by Method
8081B
Qualifier MDL (dry)
RDL (dry)
Dilution Analysis Batch
mg/kg
mg/kg
date / time
0.0146
0.0952
1 01/07/201918:15 WG1219963
22.0-132
011071201918.15 WG1219963
Qualifier MDL (dry)
mg/kg
J4
J4
0.00514
0.00753
0.0126
0.00925
0.00461
0.00608
0.0132
0.0269
0.00677
0.00696
0.00632
0.00776
0.0230
0.00827
0.00952
0.00733
0.00910
0.0139
0.00568
0.00640
0.00594
0.00730
0.00525
0.213
0.00821
0.00903
RDL (dry)
mg/kg
0.136
0.136
0.136
0.136
0.0952
0.136
0.136
0.136
0.136
0.136
0.136
0.136
0.136
0.136
0.136
0.136
0.136
0.136
0.136
0.136
0.136
0.136
0.136
1.36
0.136
0.136
36.0-121
Dilution Analysis Batch
date / time
01/09/201918:50
01/09/201918:50
01/09/201918:50
01/09/201918:50
01/09/201918:50
01/09/201918:50
01/09/201918:50
01/09/201918:50
01/09/201918:50
01/09/201918:50
01/09/201918:50
01/09/201918:50
01/09/201918:50
01/09/201918:50
01/09/201918:50
01/09/201918:50
01/09/201918:50
01/09/201918:50
01/09/201918:50
01/09/201918:50
01/09/201918:50
01/09/201918:50
01/09/201918:50
01/09/201918:50
01/09/201918:50
01/09/201918:50
011091201918:50
WG1219355
WG1219355
WG1219355
WG1219355
WG1219355
WG1219355
WG1219355
WG1219355
WG1219355
WG1219355
WG1219355
WG1219355
WG1219355
WG1219355
WG1219355
WG1219355
WG1219355
WG1219355
WG1219355
WG1219355
WG1219355
WG1219355
WG1219355
WG1219355
WG1219355
WG1219355
WG1219355
Result (dry)
Qualifier MDL (dry)
RDL (dry)
Dilution Analysis
Batch
Analyte
mg/kg
mg/kg
mg/kg
date / time
Aldrin
U
0.00184
0.0272
1 01/07/2019 20:59
WG1219182
Alpha BHC
U
0.00185
0.0272
1 01/07/2019 20:59
WG1219182
Beta BHC
U
0.00218
0.0272
1 01/07/2019 20:59
WG1219182
Delta BHC
U
0.00194
0.0272
1 01/07/2019 20:59
WG1219182
Gamma BHC
U
0.00197
0.0272
1 01/07/2019 20:59
WG1219182
Chlordane
U
0.0530
0.272
1 01/07/2019 20:59
WG1219182
4,4-DDD
U
0.00212
0.0272
1 01/07/2019 20:59
WG1219182
4,4-DDE
U
0.00209
0.0272
1 01/07/2019 20:59
WG1219182
4,4-DDT
U
0.00272
0.0272
1 01/07/2019 20:59
WG1219182
Dieldrin
U
0.00207
0.0272
1 01/07/2019 20:59
WG1219182
EndosulfanI
U
0.00203
0.0272
1 01/07/2019 20:59
WG1219182
Endosulfan II
U
0.00218
0.0272
1 01/07/2019 20:59
WG1219182
Endosulfan sulfate
U
0.00205
0.0272
1 01/07/2019 20:59
WG1219182
Endrin
U
0.00213
0.0272
1 01/07/2019 20:59
WG1219182
Endrin aldehyde
U
0.00175
0.0272
1 01/07/2019 20:59
WG1219182
Endrin ketone
U
0.00224
0.0272
1 01/07/2019 20:59
WG1219182
Hexachlorobenzene
U
0.00169
0.0272
1 01/07/2019 20:59
WG1219182
Heptachlor
U
0.00209
0.0272
1 01/07/2019 20:59
WG1219182
CP
FTc
FSS
4
Cn
Fc
F
FAI
FSC
ACCOUNT: PROJECT:
Hart and Hickman, PC LVL-001
SDG: DATE/TIME: PAGE:
L1058027 01/17/19 15:18 8 of 84

SAMPLE RESULTS - 01
L1058027
ONE LAB. NATIONWIDE.
SED-1
Collected date/time: 01/03/19 13:00
Pesticides (GC) by Method 8081B
Result (dry)
Analyte mg/kg
Heptachlor epoxide U
Methoxychlor U
Toxaphene U
(S) Decochlorobipheny/ 95.9
(S)Tetrach/oro-m-xylene 98.8
Semi Volatile Organic Compounds
Qualifier MDL (dry) RDL (dry)
mg/kg mg/kg
0.00219 0.0272
0.00242 0.0272
0.0490 0.544
10.0-135
10.0-139
(GC/MS) by Method 8270D
Dilution Analysis
date / time
1 01/07/2019 20:59
1 01/07/2019 20:59
1 01/07/2019 20:59
0110712019 20:59
011071201920:59
Batch
WG1219182
WG1219182
WG1219182
WG1219182
WG1219182
Result (dry)
Qualifier MDL (dry)
RDL (dry)
Dilution Analysis
Batch
Analyte
mg/kg
mg/kg
mg/kg
date / time
Acenaphthene
U
0.00873
0.0453
1 01/06/2019 15:30
WG1219730
Acenaphthylene
U
0.00912
0.0453
1 01/06/2019 15:30
WG1219730
Anthracene
U
0.00859
0.0453
1 01/06/2019 15:30
WG1219730
Acetophenone
U
0.102
0.453
1 01/06/2019 15:30
WG1219730
Atrazine
U
0.128
0.453
1 01/06/2019 15:30
WG1219730
Benzaldehyde
U
0.0723
0.453
1 01/06/2019 15:30
WG1219730
Benzidine
U
J4 0.0866
0.453
1 01/06/2019 15:30
WG1219730
Benzo(a)anth race ne
U
0.00582
0.0453
1 01/06/2019 15:30
WG1219730
Benzo(b)fluoranthene
U
0.00945
0.0453
1 01/06/2019 15:30
WG1219730
Benzo(k)fluoranthene
U
0.00791
0.0453
1 01/06/2019 15:30
WG1219730
Benzo(g,h,i)perylene
U
0.00980
0.0453
1 01/06/2019 15:30
WG1219730
Benzo(a)pyrene
U
0.00745
0.0453
1 01/06/2019 15:30
WG1219730
Benzyl alcohol
U
0.0102
0.453
1 01/06/2019 15:30
WG1219730
Biphenyl
U
0.00800
0.453
1 01/06/2019 15:30
WG1219730
Bis(2-chlorethoxy)methane
U
0.0105
0.453
1 01/06/2019 15:30
WG1219730
Bis(2-chloroethyl)ether
U
0.0122
0.453
1 01/06/2019 15:30
WG1219730
Bis(2-chloroisopropyl)ether
U
0.0103
0.453
1 01/06/2019 15:30
WG1219730
4-Bromophenyl-phenylether
U
0.0155
0.453
1 01/06/2019 15:30
WG1219730
2-Chloronaphthalene
U
0.00869
0.0453
1 01/06/2019 15:30
WG1219730
4-Chlorophenyl-phenylether
U
0.00853
0.453
1 01/06/2019 15:30
WG1219730
Caprolactam
U
0.141
0.453
1 01/06/2019 15:30
WG1219730
Carbazole
U
0.00713
0.453
1 01/06/2019 15:30
WG1219730
4-Chloroaniline
U
0.0479
0.453
1 01/06/2019 15:30
WG1219730
Chrysene
U
0.00755
0.0453
1 01/06/2019 15:30
WG1219730
Dibenz(a,h)anthracene
U
0.0112
0.0453
1 01/06/2019 15:30
WG1219730
Dibenzofuran
U
0.00704
0.453
1 01/06/2019 15:30
WG1219730
1,2-Dichlorobenzene
U
0.0125
0.453
1 01/06/2019 15:30
WG1219730
1,3-Dichlorobenzene
U
0.0136
0.453
1 01/06/2019 15:30
WG1219730
1,4-Dichlorobenzene
U
0.0136
0.453
1 01/06/2019 15:30
WG1219730
3,3-Dichlorobenzidine
U
0.108
0.453
1 01/06/2019 15:30
WG1219730
2,4-Dinitrotoluene
U
0.00825
0.453
1 01/06/2019 15:30
WG1219730
2,6-Dinitrotoluene
U
0.0100
0.453
1 01/06/2019 15:30
WG1219730
1,2-Diphenylhydrazine
U
0.00718
0.453
1 01/06/2019 15:30
WG1219730
Fluoranthene
U
0.00674
0.0453
1 01/06/2019 15:30
WG1219730
Fluorene
U
0.00927
0.0453
1 01/06/2019 15:30
WG1219730
Hexachlorobenzene
U
0.0116
0.453
1 01/06/2019 15:30
WG1219730
Hexachloro-1,3-butadiene
U
0.0136
0.453
1 01/06/2019 15:30
WG1219730
Hexachlorocyclopentadiene
U
0.0798
0.453
1 01/06/2019 15:30
WG1219730
Hexachloroethane
U
0.0182
0.453
1 01/06/2019 15:30
WG1219730
Indeno(1,2,3-cd)pyrene
U
0.0105
0.0453
1 01/06/2019 15:30
WG1219730
Isophorone
U
0.00710
0.453
1 01/06/2019 15:30
WG1219730
2-Methylnaphthalene
U
0.0117
0.0453
1 01/06/2019 15:30
WG1219730
2-Nitroaniline
U
0.0103
0.453
1 01/06/2019 15:30
WG1219730
3-Nitroaniline
U
0.0116
0.453
1 01/06/2019 15:30
WG1219730
4-Nitroaniline
U
0.00869
0.453
1 01/06/2019 15:30
WG1219730
Naphthalene
U
0.0121
0.0453
1 01/06/2019 15:30
WG1219730
Nitrobenzene
U
0.00945
0.453
1 01/06/2019 15:30
WG1219730
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
Hart and Hickman,
PC
LVL-001
L1058027
01/17/19 15:18
FP
FTC
FSS
a
Cn
FC]
I q,
FAI
FSC
PAGE:
9 of 84

ONE LAB. NATIONWIDE.
SED-1 SAMPLE RESULTS - 01
Collected date/time: 01/03/19 13:00 L1058027
Semi Volatile Organic Compounds (GC/MS) by Method 8270D
Result (dry)
Qualifier MDL (dry)
RDL (dry)
Analyte
mg/kg
mg/kg
mg/kg
n-Nitrosodimethyla mine
U
0.0880
0.453
n-Nitrosodiphenyla mine
U
0.122
0.453
n-Nitrosodi-n-propylamine
U
0.0123
0.453
Phenanthrene
U
0.00718
0.0453
Benzylbutyl phthalate
U
0.0140
0.453
Bis(2-ethylhexyl)phthalate
U
0.0163
0.453
Di-n-butyl phthalate
U
0.0148
0.453
Diethyl phthalate
U
0.00940
0.453
Dimethyl phthalate
U
0.00734
0.453
Di-n-octyl phthalate
U
0.0123
0.453
Pyrene
U
0.0167
0.0453
1,2,4-Trichlorobenzene
U
0.0119
0.453
4-ChIoro-3-methyl phenol
U
0.00649
0.453
2-Chlorophenol
U
0.0113
0.453
2,4-Dichlorophenol
U
0.0101
0.453
2,4-Dimethylphenol
U
0.0640
0.453
4,6-Dinitro-2-methylphenol
U
0.169
0.453
2,4-Dinitrophenol
U
0.133
0.453
2-Methylphenol
U
0.0134
0.453
3&4-Methyl Phenol
U
0.0106
0.453
2-Nitrophenol
U
0.0177
0.453
4-Nitrophenol
U
0.0714
0.453
Pentachlorophenol
U
0.0653
0.453
Phenol
U
0.00945
0.453
2,4,5-Trichlorophenol
U
0.0141
0.453
2,4,6-Trichlorophenol
U
0.0106
0.453
(S) 2-F/uorophenol
58.8
12.0-120
(S) Phenol-d5
53.3
10.0-120
(S) Nitrobenzene-d5
52.9
10.0-122
(S) 2-Fluorobiphenyl
51.7
15.0-120
(S)2,4,6-Tribromopheno/
60.4
10.0-127
(S) p-Terphenyl-d14
53.9
10.0-120
Dilution Analysis Batch
date / time
01/06/201915:30
01/06/201915:30
01/06/201915:30
01/06/201915:30
01/06/201915:30
01/06/201915:30
01/06/201915:30
01/06/201915:30
01/06/201915:30
01/06/201915:30
01/06/201915:30
01/06/201915:30
01/06/201915:30
01/06/201915:30
01/06/201915:30
01/06/201915:30
01/06/201915:30
01/06/201915:30
01/06/201915:30
01/06/201915:30
01/06/201915:30
01/06/201915:30
01/06/201915:30
01/06/201915:30
01/06/201915:30
01/06/201915:30
01/06/201915:30
01106120191530
01/06/201915:30
01106120191530
01/06/201915:30
01106120191530
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
FP1
FTc
FSS
4
Cn
Fc
7G1
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME:
Hart and Hickman, PC LVL-001 L1058027 01/17/19 15:18
PAGE:
10 of 84

SED-2
Collected date/time: 01/03/19 15:30
Total Solids by Method 2540 G-2011
SAMPLE RESULTS - 02
L1058027
Result Qualifier Dilution Analysis Batch
Analyte % date / time
Total Solids 76.9 1 01/08/201914:33 WG1219475
Wet Chemistry by Method 7199
Result (dry)
Analyte mg/kg
Hexavalent Chromium U
Mercury by Method 7471B
Result (dry)
Analyte mg/kg
Mercury 0.147
Metals (ICPMS) by Method 6020B
Qualifier MDL (dry) RDL (dry) Dilution Analysis
mg/kg mg/kg date / time
0.332 1.30 1 01/11/201915:34
Qualifier MDL (dry) RDL (dry) Dilution Analysis
mg/kg mg/kg date/time
ONE LAB. NATIONWIDE.
FP1
FTC
FSS
Batch
r
WG1221753 Cn
FQ-C1
0.00364 0.0260 1 01/07/2019 09:59 WG1219882
7
Result (dry)
Qualifier MDL (dry)
RDL (dry)
Dilution
Analysis
Analyte
mg/kg
mg/kg
mg/kg
date / time
Arsenic
3.60
0.163
0.650
5
01/07/2019 23:18
Barium
212
0.208
1.30
5
01/07/2019 23:18
Cadmium
U
0.104
0.650
5
01/07/2019 23:18
Chromium
53.4
0.351
1.30
5
01/07/2019 23:18
Lead
14.4
0.156
0.650
5
01/07/2019 23:18
Selenium
0.529
1_ 0.247
0.650
5
01/07/2019 23:18
Silver
U
0.202
0.650
5
01/07/2019 23:18
Volatile Organic Compounds (GC/MS) by Method 8260B
Batch
Batch
WG122011
WG122011
WG1220117
WG1220117
WG1220117
WG1220117
WG1220117
7
7
FSC
I$AI
Result (dry) Qualifier MDL (dry) RDL (dry) Dilution Analysis Batch
Analyte mg/kg mg/kg mg/kg date / time
Acetone 0.0557 B 0.0178 0.0325 1 01/06/2019 19:40 WG1219795
Acrylonitrile U 0.00247 0.0163 1 01/06/2019 19:40 WG1219795
Benzene U 0.000520 0.00130 1 01/06/2019 19:40 WG1219795
Bromobenzene U 0.00137 0.0163 1 01/06/2019 19:40 WG1219795
Bromodichloromethane U 0.00102 0.00325 1 01/06/2019 19:40 WG1219795
Bromoform U 0.00778 0.0325 1 01/06/2019 19:40 WG1219795
Bromomethane U 0.00481 0.0163 1 01/06/2019 19:40 WG1219795
n-Butylbenzene U 0.00499 0.0163 1 01/06/2019 19:40 WG1219795
sec -Butyl benzene U 0.00329 0.0163 1 01/06/2019 19:40 WG1219795
ter[-Butylbenzene U 0.00202 0.00650 1 01/06/2019 19:40 WG1219795
Carbon tetrachloride U 0.00140 0.00650 1 01/06/2019 19:40 WG1219795
Chlorobenzene U 0.000745 0.00325 1 01/06/2019 19:40 WG1219795
Chlorodibromomethane U 0.000585 0.00325 1 01/06/2019 19:40 WG1219795
Chloroethane U 0.00140 0.00650 1 01/06/2019 19:40 WG1219795
Chloroform U 0.000540 0.00325 1 01/06/2019 19:40 WG1219795
Chloromethane U 0.00181 0.0163 1 01/06/2019 19:40 WG1219795
2-Chlorotoluene U 0.00120 0.00325 1 01/06/2019 19:40 WG1219795
4-Chlorotoluene U 0.00147 0.00650 1 01/06/2019 19:40 WG1219795
1,2-Dibromo-3-Chloropropane U 0.00663 0.0325 1 01/06/2019 19:40 WG1219795
1,2-Dibromoethane U 0.000683 0.00325 1 01/06/2019 19:40 WG1219795
Dibromomethane U 0.00130 0.00650 1 01/06/2019 19:40 WG1219795
1,2-Dichlorobenzene U 0.00189 0.00650 1 01/06/2019 19:40 WG1219795
1,3-Dichlorobenzene U 0.00221 0.00650 1 01/06/2019 19:40 WG1219795
1,4-Dichlorobenzene U 0.00256 0.00650 1 01/06/2019 19:40 WG1219795
Dichlorodifluoromethane U 0.00106 0.00325 1 01/06/2019 19:40 WG1219795
1,1-Dichloroethane U 0.000748 0.00325 1 01/06/2019 19:40 WG1219795
1,2-Dichloroethane U 0.000618 0.00325 1 01/06/2019 19:40 WG1219795
1,1-Dichloroethene U 0.000650 0.00325 1 01/06/2019 19:40 WG1219795
ACCOUNT: PROJECT: SDG: DATE/TIME:
Hart and Hickman, PC LVL-001 L1058027 01/17/19 15:18
PAGE:
11 of 84
Result (dry) Qualifier MDL (dry) RDL (dry) Dilution Analysis Batch
Analyte mg/kg mg/kg mg/kg date / time
Acetone 0.0557 B 0.0178 0.0325 1 01/06/2019 19:40 WG1219795
Acrylonitrile U 0.00247 0.0163 1 01/06/2019 19:40 WG1219795
Benzene U 0.000520 0.00130 1 01/06/2019 19:40 WG1219795
Bromobenzene U 0.00137 0.0163 1 01/06/2019 19:40 WG1219795
Bromodichloromethane U 0.00102 0.00325 1 01/06/2019 19:40 WG1219795
Bromoform U 0.00778 0.0325 1 01/06/2019 19:40 WG1219795
Bromomethane U 0.00481 0.0163 1 01/06/2019 19:40 WG1219795
n-Butylbenzene U 0.00499 0.0163 1 01/06/2019 19:40 WG1219795
sec -Butyl benzene U 0.00329 0.0163 1 01/06/2019 19:40 WG1219795
ter[-Butylbenzene U 0.00202 0.00650 1 01/06/2019 19:40 WG1219795
Carbon tetrachloride U 0.00140 0.00650 1 01/06/2019 19:40 WG1219795
Chlorobenzene U 0.000745 0.00325 1 01/06/2019 19:40 WG1219795
Chlorodibromomethane U 0.000585 0.00325 1 01/06/2019 19:40 WG1219795
Chloroethane U 0.00140 0.00650 1 01/06/2019 19:40 WG1219795
Chloroform U 0.000540 0.00325 1 01/06/2019 19:40 WG1219795
Chloromethane U 0.00181 0.0163 1 01/06/2019 19:40 WG1219795
2-Chlorotoluene U 0.00120 0.00325 1 01/06/2019 19:40 WG1219795
4-Chlorotoluene U 0.00147 0.00650 1 01/06/2019 19:40 WG1219795
1,2-Dibromo-3-Chloropropane U 0.00663 0.0325 1 01/06/2019 19:40 WG1219795
1,2-Dibromoethane U 0.000683 0.00325 1 01/06/2019 19:40 WG1219795
Dibromomethane U 0.00130 0.00650 1 01/06/2019 19:40 WG1219795
1,2-Dichlorobenzene U 0.00189 0.00650 1 01/06/2019 19:40 WG1219795
1,3-Dichlorobenzene U 0.00221 0.00650 1 01/06/2019 19:40 WG1219795
1,4-Dichlorobenzene U 0.00256 0.00650 1 01/06/2019 19:40 WG1219795
Dichlorodifluoromethane U 0.00106 0.00325 1 01/06/2019 19:40 WG1219795
1,1-Dichloroethane U 0.000748 0.00325 1 01/06/2019 19:40 WG1219795
1,2-Dichloroethane U 0.000618 0.00325 1 01/06/2019 19:40 WG1219795
1,1-Dichloroethene U 0.000650 0.00325 1 01/06/2019 19:40 WG1219795
ACCOUNT: PROJECT: SDG: DATE/TIME:
Hart and Hickman, PC LVL-001 L1058027 01/17/19 15:18
PAGE:
11 of 84
PAGE:
11 of 84

ONE LAB. NATIONWIDE.
SED-2 SAMPLE RESULTS - 02
Collected date/time: 01/03/19 15:30 L1058027
Volatile Organic Compounds (GC/MS) by Method 8260B
Result (dry)
Qualifier
MDL (dry)
RDL (dry)
Dilution Analysis
Batch
Analyte
mg/kg
mg/kg
mg/kg
date / time
cis-1,2-Dichloroethene
U
0.000897
0.00325
1 01/06/201919:40
WG1219795
trans-1,2-Dichloroethene
U
0.00186
0.00650
1 01/06/201919:40
WG1219795
1,2-Dichloropropane
U
0.00165
0.00650
1 01/06/201919:40
WG1219795
1,1-Dichloropropene
U
0.000910
0.00325
1 01/06/201919:40
WG1219795
1,3-Dichloropropane
U
0.00228
0.00650
1 01/06/201919:40
WG1219795
cis-1,3-Dichloropropene
U
0.000882
0.00325
1 01/06/201919:40
WG1219795
trans-1,3-Dichloropropene
U
0.00199
0.00650
1 01/06/201919:40
WG1219795
2,2-Dichloropropane
U
0.00103
0.00325
1 01/06/201919:40
WG1219795
Di -isopropyl ether
U
0.000455
0.00130
1 01/06/201919:40
WG1219795
Ethylbenzene
0.000848
1_
0.000689
0.00325
1 01/06/201919:40
WG1219795
Hexachloro-1,3-butadiene
U
0.0165
0.0325
1 01/06/201919:40
WG1219795
Isopropylbenzene
U
0.00112
0.00325
1 01/06/201919:40
WG1219795
p-Isopropyltoluene
U
0.00303
0.00650
1 01/06/201919:40
WG1219795
2-Butanone (MEK)
0.0186
1_
0.0163
0.0325
1 01/06/201919:40
WG1219795
Methylene Chloride
U
0.00863
0.0325
1 01/06/201919:40
WG1219795
4-Methyl-2-pentanone (MIBK)
U
0.0130
0.0325
1 01/06/201919:40
WG1219795
Methyl tert-butyl ether
U
0.000384
0.00130
1 01/06/201919:40
WG1219795
Naphthalene
U
0.00406
0.0163
1 01/06/201919:40
WG1219795
n-Propylbenzene
U
0.00153
0.00650
1 01/06/201919:40
WG1219795
Styrene
U
0.00355
0.0163
1 01/06/201919:40
WG1219795
1,1,1,2-Tetrachloroethane
U
0.000650
0.00325
1 01/06/201919:40
WG1219795
1,1,2,2-Tetrachloroethane
U
0.000507
0.00325
1 01/06/201919:40
WG1219795
1,1,2-Trichlorotrifluoroethane
U
0.000878
0.00325
1 01/06/201919:40
WG1219795
Tetrachloroethene
U
0.000910
0.00325
1 01/06/201919:40
WG1219795
Toluene
0.00166
1_
0.00163
0.00650
1 01/06/201919:40
WG1219795
1,2,3-Trichlorobenzene
U
0.000813
0.00325
1 01/06/201919:40
WG1219795
1,2,4-Trichlorobenzene
U
0.00627
0.0163
1 01/06/201919:40
WG1219795
1,1,1-Trichloroethane
U
0.000358
0.00325
1 01/06/201919:40
WG1219795
1,1,2-Trichloroethane
U
0.00115
0.00325
1 01/06/201919:40
WG1219795
Trichloroethene
U
0.000520
0.00130
1 01/06/201919:40
WG1219795
Trichlorofluoromethane
U
0.000650
0.00325
1 01/06/201919:40
WG1219795
1,2,3-Trichloropropane
U
0.00663
0.0163
1 01/06/201919:40
WG1219795
1,2,4-Trimethylbenzene
U
0.00151
0.00650
1 01/06/201919:40
WG1219795
1,2,3-Trimethyl benzene
U
0.00150
0.00650
1 01/06/201919:40
WG1219795
1,3,5-Trimethyl benzene
U
0.00140
0.00650
1 01/06/201919:40
WG1219795
Vinyl chloride
U
0.000888
0.00325
1 01/06/201919:40
WG1219795
Xylenes, Total
U
0.00622
0.00845
1 01/06/201919:40
WG1219795
(S) Toluene-d8
101
75.0-131
011061201919:40
WG1219795
(S) Dibromofluoromeftne
89.3
65.0-129
011061201919:40
WG1219795
(S) 4-Bromof/uorobenzene
95.4
67.0-138
011061201919:40
WG1219795
Chlorinated Acid Herbicides (GC) by Method 8151
Analyte
2,4-D
Dalapon
2,4-DB
Dicamba
Dichloroprop
Dinoseb
MCPA
MCPP
2,4,5-T
2,4,5-TP (Silvex)
(S) 2,4-Dichloropheny/Acetic Acid
Result (dry) Qualifier MDL (dry) RDL (dry) Dilution Analysis Batch
mg/kg mg/kg mg/kg date / time
U
0.00913
0.0910 1
01/07/201918:29
WG1219963
U
0.0147
0.0910 1
01/07/201918:29
WG1219963
U
0.0386
0.0910 1
01/07/201918:29
WG1219963
U
0.0204
0.0910 1
01/07/201918:29
WG1219963
U
0.0319
0.0910 1
01/07/201918:29
WG1219963
U
0.00906
0.0910 1
01/07/201918:29
WG1219963
U
J4 0.576
8.45 1
01/07/201918:29
WG1219963
U
0.477
8.45 1
01/07/201918:29
WG1219963
U
0.0111
0.0910 1
01/07/201918:29
WG1219963
U
0.0139
0.0910 1
01/07/201918:29
WG1219963
55.9
22.0-132
011071201918:29
WG1219963
Fp
FTc
FSS
[Cn]
Fc
F ql
FAI
FSC
ACCOUNT:
Hart and Hickman, PC
PROJECT: SDG: DATE/TIME: PAGE:
LVL-001 L1058027 01/17/19 15:18 12 of 84

SAMPLE RESULTS - 02
L1058027
ONE LAB. NATIONWIDE.
SED-2
Collected date/time: 01/03/19 15:30
OP Pesticides by Method 8141B
Result (dry)
Qualifier MDL (dry)
RDL (dry)
Analyte
mg/kg
mg/kg
mg/kg
Azinphos-Methyl
U
0.00492
0.130
Bolstar (Sulprofos)
U
0.00720
0.130
Chlorpyrifos
U
0.0120
0.130
Coumaphos
U
0.00884
0.130
Demeton,-0 and -S
U
0.00441
0.0910
Diazinon
U
0.00581
0.130
Dichlorvos
U
0.0126
0.130
Dimethoate
U
0.0257
0.130
Disulfoton
U
0.00648
0.130
EPN
U
0.00666
0.130
Ethoprop
U
0.00605
0.130
Ethyl Parathion
U
0.00743
0.130
Fensulfothion
U
0.0220
0.130
Fenthion
U
0.00791
0.130
Marathion
U
0.00910
0.130
Merphos
U
J4 0.00701
0.130
Methyl parathion
U
0.00870
0.130
Mevinphos
U
0.0133
0.130
Naled
U
0.00544
0.130
Phorate
U
0.00612
0.130
Ronnel
U
0.00568
0.130
Stirophos
U
0.00698
0.130
Sulfotep
U
0.00502
0.130
TEPP
U
J3 J4 0.204
1.30
Tokuthion (Prothothiofos)
U
0.00785
0.130
Trichloronate
U
0.00863
0.130
(S) Tripheny/ Phosphate
74.1
36.0-121
Pesticides (GC) by Method 8081B
Analyte
Result (dry) Qualifier MDL (dry)
mg/kg mg/kg
Aldrin
U
Alpha BHC
U
Beta BHC
U
Delta BHC
U
Gamma BHC
U
Chlordane
U
4,4-DDD
U
4,4-DDE
0.00498
4,4-DDT
U
Dieldrin
U
Endosulfan I
U
Endosulfan 11
U
Endosulfan sulfate
U
Endrin
U
Endrin aldehyde
U
Endrin ketone
U
Hexachlorobenzene
U
Heptachlor
U
Heptachlor epoxide
U
Methoxychlor
U
Toxaphene
U
(S) Decochlorobipheny/
95.6
(S) Tetrach/oro-m-xylene
99.5
ACCOUNT:
Hart and Hickman,
PC
J
0.00176
0.00177
0.00208
0.00186
0.00189
0.0507
0.00203
0.00200
0.00260
0.00198
0.00194
0.00208
0.00196
0.00204
0.00168
0.00215
0.00161
0.00200
0.00209
0.00231
0.0468
PROJECT:
LVL-001
Dilution Analysis
date / time
Batch
1 01/09/2019 20:25
WG1219897
1 01/09/2019 20:25
WG1219897
1 01/09/2019 20:25
WG1219897
1 01/09/2019 20:25
WG1219897
1 01/09/2019 20:25
WG1219897
1 01/09/2019 20:25
WG1219897
1 01/09/2019 20:25
WG1219897
1 01/09/2019 20:25
WG1219897
1 01/09/2019 20:25
WG1219897
1 01/09/2019 20:25
WG1219897
1 01/09/2019 20:25
WG1219897
1 01/09/2019 20:25
WG1219897
1 01/09/2019 20:25
WG1219897
1 01/09/2019 20:25
WG1219897
1 01/09/2019 20:25
WG1219897
1 01/09/2019 20:25
WG1219897
1 01/09/2019 20:25
WG1219897
1 01/09/2019 20:25
WG1219897
1 01/09/2019 20:25
WG1219897
1 01/09/2019 20:25
WG1219897
1 01/09/2019 20:25
WG1219897
1 01/09/2019 20:25
WG1219897
1 01/09/2019 20:25
WG1219897
1 01/09/2019 20:25
WG1219897
1 01/09/2019 20:25
WG1219897
1 01/09/2019 20:25
WG1219897
011091201920:25
WG1219897
RDL (dry)
Dilution Analysis
Batch
mg/kg
date / time
0.0260
1 01/07/2019 21:11
WG1219182
0.0260
1 01/07/2019 21:11
WG1219182
0.0260
1 01/07/2019 21:11
WG1219182
0.0260
1 01/07/2019 21:11
WG1219182
0.0260
1 01/07/2019 21:11
WG1219182
0.260
1 01/07/2019 21:11
WG1219182
0.0260
1 01/07/2019 21:11
WG1219182
0.0260
1 01/07/2019 21:11
WG1219182
0.0260
1 01/07/2019 21:11
WG1219182
0.0260
1 01/07/2019 21:11
WG1219182
0.0260
1 01/07/2019 21:11
WG1219182
0.0260
1 01/07/2019 21:11
WG1219182
0.0260
1 01/07/2019 21:11
WG1219182
0.0260
1 01/07/2019 21:11
WG1219182
0.0260
1 01/07/2019 21:11
WG1219182
0.0260
1 01/07/2019 21:11
WG1219182
0.0260
1 01/07/2019 21:11
WG1219182
0.0260
1 01/07/2019 21:11
WG1219182
0.0260
1 01/07/2019 21:11
WG1219182
0.0260
1 01/07/2019 21:11
WG1219182
0.520
1 01/07/2019 21:11
WG1219182
10.0-135
011071201921:11
WG1219182
10.0-139
011071201921:11
WG1219182
FP
FTc
FSS
[Cn]
Fc
F
FAI
FSC
SDG: DATE/TIME: PAGE:
L1058027 01/17/19 15:18 13 of 84

ONE LAB. NATIONWIDE.
SED-2 SAMPLE RESULTS - 02
Collected date/time: 01/03/19 15:30 L1058027
Semi Volatile Organic Compounds (GC/MS) by Method 8270D
Analyte
Result (dry)
mg/kg
Qualifier MDL (dry)
mg/kg
RDL (dry)
mg/kg
Dilution Analysis
date / time
Batch
Acenaphthene
U
0.0166
0.0866
2
01/06/2019 18:13
WG1219730
Acenaphthylene
U
0.0174
0.0866
2
01/06/2019 18:13
WG1219730
Anthracene
U
0.0164
0.0866
2
01/06/2019 18:13
WG1219730
Acetophenone
U
0.195
0.866
2
01/06/2019 18:13
WG1219730
Atrazine
U
0.244
0.866
2
01/06/2019 18:13
WG1219730
Benzaldehyde
u
0.138
0.866
2
01/06/2019 18:13
WG1219730
Benzidine
U
J4 0.165
0.866
2
01/06/2019 18:13
WG1219730
Benzo(a)anth race ne
U
0.0111
0.0866
2
01/06/2019 18:13
WG1219730
Benzo(b)fluoranthene
U
0.0181
0.0866
2
01/06/2019 18:13
WG1219730
Benzo(k)fluoranthene
U
0.0151
0.0866
2
01/06/2019 18:13
WG1219730
Benzo(g,h,i)perylene
U
0.0187
0.0866
2
01/06/2019 18:13
WG1219730
Benzo(a)pyrene
U
0.0143
0.0866
2
01/06/2019 18:13
WG1219730
Benzyl alcohol
U
0.0195
0.866
2
01/06/2019 18:13
WG1219730
Biphenyl
U
0.0153
0.866
2
01/06/2019 18:13
WG1219730
Bis(2-chlorethoxy)methane
U
0.0200
0.866
2
01/06/2019 18:13
WG1219730
Bis(2-chloroethyl)ether
U
0.0233
0.866
2
01/06/2019 18:13
WG1219730
Bis(2-chloroisopropyl)ether
U
0.0198
0.866
2
01/06/2019 18:13
WG1219730
4-Bromophenyl-phenylether
U
0.0296
0.866
2
01/06/2019 18:13
WG1219730
2-Chloronaphthalene
U
0.0166
0.0866
2
01/06/2019 18:13
WG1219730
4-Chlorophenyl-phenylether
U
0.0163
0.866
2
01/06/2019 18:13
WG1219730
Caprolactam
U
0.270
0.866
2
01/06/2019 18:13
WG1219730
Carbazole
U
0.0137
0.866
2
01/06/2019 18:13
WG1219730
4-Chloroaniline
U
0.0915
0.866
2
01/06/2019 18:13
WG1219730
Chrysene
U
0.0144
0.0866
2
01/06/2019 18:13
WG1219730
Dibenz(a,h)anthracene
U
0.0213
0.0866
2
01/06/2019 18:13
WG1219730
Dibenzofuran
U
0.0135
0.866
2
01/06/2019 18:13
WG1219730
1,2-Dichlorobenzene
U
0.0239
0.866
2
01/06/2019 18:13
WG1219730
1,3-Dichlorobenzene
U
0.0260
0.866
2
01/06/2019 18:13
WG1219730
1,4-Dichlorobenzene
U
0.0260
0.866
2
01/06/2019 18:13
WG1219730
3,3-Dichlorobenzidine
U
0.207
0.866
2
01/06/2019 18:13
WG1219730
2,4-Dinitrotoluene
U
0.0157
0.866
2
01/06/2019 18:13
WG1219730
2,6-Dinitrotoluene
U
0.0191
0.866
2
01/06/2019 18:13
WG1219730
1,2-Diphenylhydrazine
U
0.0138
0.866
2
01/06/2019 18:13
WG1219730
Fluoranthene
U
0.0129
0.0866
2
01/06/2019 18:13
WG1219730
Fluorene
U
0.0177
0.0866
2
01/06/2019 18:13
WG1219730
Hexachlorobenzene
U
0.0222
0.866
2
01/06/2019 18:13
WG1219730
Hexachloro-1,3-butadiene
U
0.0260
0.866
2
01/06/2019 18:13
WG1219730
Hexachlorocyclopentadiene
u
0.152
0.866
2
01/06/2019 18:13
WG1219730
Hexachloroethane
U
0.0349
0.866
2
01/06/2019 18:13
WG1219730
Indeno(1,2,3-cd)pyrene
U
0.0200
0.0866
2
01/06/2019 18:13
WG1219730
Isophorone
U
0.0135
0.866
2
01/06/2019 18:13
WG1219730
2-Methylnaphthalene
U
0.0224
0.0866
2
01/06/2019 18:13
WG1219730
2-Nitroaniline
U
0.0196
0.866
2
01/06/2019 18:13
WG1219730
3-Nitroaniline
U
0.0221
0.866
2
01/06/2019 18:13
WG1219730
4-Nitroaniline
U
0.0166
0.866
2
01/06/2019 18:13
WG1219730
Naphthalene
U
0.0231
0.0866
2
01/06/2019 18:13
WG1219730
Nitrobenzene
U
0.0181
0.866
2
01/06/2019 18:13
WG1219730
n-Nitrosodimethyla mine
U
0.168
0.866
2
01/06/2019 18:13
WG1219730
n-Nitrosodiphenyla mine
U
0.234
0.866
2
01/06/2019 18:13
WG1219730
n-Nitrosodi-n-propylamine
U
0.0235
0.866
2
01/06/2019 18:13
WG1219730
Phenanthrene
U
0.0138
0.0866
2
01/06/2019 18:13
WG1219730
Benzylbutyl phthalate
U
0.0268
0.866
2
01/06/2019 18:13
WG1219730
Bis(2-ethylhexyl)phthalate
U
0.0312
0.866
2
01/06/2019 18:13
WG1219730
Di-n-butyl phthalate
U
0.0283
0.866
2
01/06/2019 18:13
WG1219730
Diethyl phthalate
U
0.0179
0.866
2
01/06/2019 18:13
WG1219730
Dimethyl phthalate
U
0.0140
0.866
2
01/06/2019 18:13
WG1219730
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
Hart and Hickman,
PC
LVL-001
L1058027
01/17/19 15:18
FP
FTc
FSS
[Cn]
Fc
I ql
FAI
FSC
PAGE:
14 of 84

ONE LAB. NATIONWIDE.
SED-2 SAMPLE RESULTS - 02
Collected date/time: 01/03/19 15:30 L1058027
Semi Volatile Organic Compounds (GC/MS) by Method 8270D
Result (dry)
Qualifier MDL (dry)
RDL (dry)
Dilution
Analysis
Analyte
mg/kg
mg/kg
mg/kg
date / time
Di-n-octyl phthalate
U
0.0235
0.866
2
01/06/201918:13
Pyrene
U
0.0320
0.0866
2
01/06/201918:13
1,2,4-Trichlorobenzene
U
0.0228
0.866
2
01/06/201918:13
4-ChIoro-3-methyl phenol
U
0.0124
0.866
2
01/06/201918:13
2-Chlorophenol
U
0.0216
0.866
2
01/06/201918:13
2,4-Dichlorophenol
u
0.0194
0.866
2
01/06/201918:13
2,4-Dimethylphenol
U
0.122
0.866
2
01/06/201918:13
4,6-Dinitro-2-methylphenol
U
0.322
0.866
2
01/06/201918:13
2,4-Dinitrophenol
U
0.255
0.866
2
01/06/201918:13
2-Methylphenol
U
0.0256
0.866
2
01/06/201918:13
3&4-Methyl Phenol
U
0.0204
0.866
2
01/06/201918:13
2-Nitrophenol
U
0.0338
0.866
2
01/06/201918:13
4-Nitrophenol
U
0.137
0.866
2
01/06/201918:13
Pentachlorophenol
U
0.125
0.866
2
01/06/201918:13
Phenol
U
0.0181
0.866
2
01/06/201918:13
2,4,5-Trichlorophenol
U
0.0270
0.866
2
01/06/201918:13
2,4,6-Trichlorophenol
U
0.0203
0.866
2
01/06/201918:13
(S) 2-F/uorophenol
64.9
12.0-120
011061201918:13
(S) Phenol-d5
59.0
10.0-120
011061201918:13
(S) Nitrobenzene-d5
54.9
10.0-122
011061201918:13
(S) 2-Fluorobiphenyl
57.1
15.0-120
011061201918:13
(S)2,4,6-Tribromopheno/
65.5
10.0-127
011061201918:13
(S) p-Terphenyl-d14
60.0
10.0-120
011061201918:13
Sample Narrative:
L1058027-02 WG1219730: Dilution due to matrix impact during extract concentration procedure
Batch
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
WG1219730
FP
FTc
FSS
[Cn]
Fc
F ql
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC LVL-001 L1058027 01/17/19 15:18 15 of 84

SW-1
Collected date/time: 01/03/19 12:50
Wet Chemistry by Method 300.0
SAMPLE RESULTS - 03
L1058027
Result Qualifier MDL RDL
Analyte ug/I ug/I ug/I
Nitrate as (N) J 22.7 100
Wet Chemistry by Method 7199
Dilution Analysis Batch
date / time
1 01/04/2019 21:32 WG1218970
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/I ug/I ug/I date / time
Hexavalent Chromium J 0.150 0.500 1 01/09/201913:14 WG1221008
Sample Narrative:
L1058027-03 WG1221008: Filtered and preserved 1/4 @ 1200
Mercury by Method 7470A
Result Qualifier
MDL
RDL
Analyte ug/I
ug/I
ug/I
Mercury J
0.0490
0.200
Mercury, Dissolved J
0.0490
0.200
Metals (ICPMS) by Method 6020B
Result
Qualifier
MDL
RDL
Analyte
ug/I
ug/I
ug/I
Arsenic
3.64
0.250
2.00
Arsenic, Dissolved
1.70
J
0.250
2.00
Barium
29.2
0.360
5.00
Barium,Dissolved
21.3
0.360
5.00
Cadmium
J
0.160
1.00
Cadmium,Dissolved
J
0.160
1.00
Chromium
1.95
B J
0.540
2.00
Chromium,Dissolved
1.57
B J
0.540
2.00
Lead
1.72
J
0.240
2.00
Lead,Dissolved
0.615
B J
0.240
2.00
Selenium
J
0.380
2.00
Selenium,Dissolved
J
0.380
2.00
Silver
J
0.310
2.00
Silver,Dissolved
J
0.310
2.00
Volatile Organic
Compounds (GC/MS)
by Method
8260B
Result
Qualifier
MDL
RDL
Analyte
ug/I
ug/I
ug/I
Acetone
J
10.0
50.0
Acrolein
J
J4
8.87
50.0
Acrylonitrile
J
1.87
10.0
Benzene
J
0.331
1.00
Bromobenzene
J
0.352
1.00
Bromodichloromethane
J
0.380
1.00
Bromoform
J
0.469
1.00
Bromomethane
J
0.866
5.00
n-Butylbenzene
J
0.361
1.00
sec -Butyl benzene
J
0.365
1.00
tert-Butylbenzene
J
0.399
1.00
Carbon tetrachloride
J
0.379
1.00
Chlorobenzene
J
0.348
1.00
Chlorodibromomethane
J
0.327
1.00
Chloroethane
J
0.453
5.00
Chloroform
J
0.324
5.00
Chloromethane
J
0.276
2.50
ACCOUNT:
PROJECT:
Hart
and Hickman, PC
LVL-001
Dilution Analysis Batch
date / time
1 01/07/201912:10 WG1219858
1 01/07/201910:33 WG1219860
Dilution Analysis
Batch
date / time
1 01/07/2019 20:28
WG1219455
1 01/07/2019 20:03
WG1219940
1 01/07/2019 20:28
WG1219455
1 01/07/2019 20:03
WG1219940
1 01/07/2019 20:28
WG1219455
1 01/07/2019 20:03
WG1219940
1 01/07/2019 20:28
WG1219455
1 01/07/2019 20:03
WG1219940
1 01/07/2019 20:28
WG1219455
1 01/07/2019 20:03
WG1219940
1 01/07/2019 20:28
WG1219455
1 01/07/2019 20:03
WG1219940
1 01/07/2019 20:28
WG1219455
1 01/07/2019 20:03
WG1219940
Dilution Analysis
date / time
1 01/04/201917:03
1 01/04/201917:03
1 01/04/201917:03
1 01/04/201917:03
1 01/04/201917:03
1 01/04/201917:03
1 01/04/201917:03
1 01/04/201917:03
1 01/04/201917:03
1 01/04/201917:03
1 01/04/201917:03
1 01/04/201917:03
1 01/04/201917:03
1 01/04/201917:03
1 01/04/201917:03
1 01/04/201917:03
1 01/04/201917:03
SDG:
L1058027
Batch
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
ONE LAB. NATIONWIDE.
FP1
FTc
FSS
4
Cn
Rc
�GI
FAI
FSC
DATE/TIME: PAGE:
01/17/19 15:18 16 of 84

ONE LAB. NATIONWIDE.
SW-1 SAMPLE RESULTS - 03
Collected date/time: 01/03/19 12:50 L1058027
Volatile Organic Compounds (GC/MS) by Method 8260B
Result
Qualifier MDL
RDL
Analyte
ug/I
ug/I
ug/I
2-Chlorotoluene
U
0.375
1.00
4-Chlorotoluene
U
0.351
1.00
1,2-Dibromo-3-Chloropropane
U
1.33
5.00
1,2-Dibromoethane
U
0.381
1.00
Dibromomethane
U
0.346
1.00
1,2-Dichlorobenzene
U
0.349
1.00
1,3-Dichlorobenzene
U
0.220
1.00
1,4-Dichlorobenzene
U
0.274
1.00
DichIorodifluoromethane
U
0.551
5.00
1,1-Dichloroethane
U
0.259
1.00
1,2-Dichloroethane
U
0.361
1.00
1,1-Dichloroethene
U
0.398
1.00
cis-1,2-Dichloroethene
U
0.260
1.00
trans-1,2-Dichloroethene
U
0.396
1.00
1,2-Dichloropropane
U
0.306
1.00
1,1-Dichloropropene
U
0.352
1.00
1,3-Dichloropropane
U
0.366
1.00
cis-1,3-Dichlcrop ropene
U
0.418
1.00
trans-1,3-Dichloropropene
U
0.419
1.00
2,2-Dichloropropane
U
0.321
1.00
Di -isopropyl ether
U
0.320
1.00
Ethylbenzene
U
0.384
1.00
Hexachloro-1,3-butadiene
U
0.256
1.00
Isopropylbenzene
U
0.326
1.00
p-Isopropyltoluene
U
0.350
1.00
2-Butanone (M EK)
U
3.93
10.0
Methylene Chloride
U
1.00
5.00
4-Methyl-2-pentanone (MIBK)
U
2.14
10.0
Methyl tert-butyl ether
U
0.367
1.00
Naphthalene
U
1.00
5.00
n-Propylbenzene
U
0.349
1.00
Styrene
U
0.307
1.00
1,1,1,2-Tetrachloroethane
U
0.385
1.00
1,1,2,2-Tetrachloroethane
U
0.130
1.00
Tetrachloroethene
U
0.372
1.00
Toluene
U
0.412
1.00
1,2,3-Trichlorobenzene
U
0.230
1.00
1,2,4-Trichlorobenzene
U
0.355
1.00
1,1,1-Trichloroethane
U
0.319
1.00
1,1,2-Trichloroethane
U
0.383
1.00
Trichloroethene
U
0.398
1.00
Trichlorofluoromethane
U
1.20
5.00
1,2,3-Trichloropropane
U
0.807
2.50
1,2,4-Trimethylbenzene
U
0.373
1.00
1,3,5-Trimethyl benzene
U
0.387
1.00
Vinyl chloride
U
0.259
1.00
Xylenes, Total
U
1.06
3.00
(S) Toluene-d8
105
80.0-120
(S) Dibromofluoromethane
88.7
75.0-120
(S) 4-Bromofluorobenzene
101
77.0-126
Dilution Analysis Batch
date / time
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917:03
01/04/201917.03
01/04/201917.-03
01/04/201917.03
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
FP1
FTc
FSS
4
Cn
Fc
F,
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME:
Hart and Hickman, PC LVL-001 L1058027 01/17/19 15:18
PAGE:
17 of 84

SW-1
SAMPLE
RESULTS - 03
ONE LAB. NATIONWIDE.
Collected date/time: 01/03/19 12:50
L1058027
Chlorinated Acid Herbicides (GC) by Method 8151
Result Qualifier
MDL
RDL
Dilution
Analysis
Batch
FPAnalyte
ug/I
ug/I
ug/I
date / time
2,4-D U
0.744
2.00
1
01/08/2019 02:29
WG1219966
Z
Tc
Dalapon U
1.04
2.00
1
01/08/2019 02:29
WG1219966
2,4-DB U
0.775
4.00
1
01/08/2019 02:29
WG1219966
Dicamba U
0.813
2.00
1
01/08/2019 02:29
WG1219966
FS
Dichloroprop U
0.778
2.00
1
01/08/2019 02:29
WG1219966
Dinoseb U
0.795
2.00
1
01/08/2019 02:29
WG1219966
Fn
MCPA U J3 J4
13.1
200
1
01/08/2019 02:29
WG1219966
MCPP U
7.15
200
1
01/08/2019 02:29
WG1219966
2,4,5-T U
0.843
2.00
1
01/08/2019 02:29
WG1219966
2,4,5-TP (Silvex) U
0.845
2.00
1
01/08/2019 02:29
WG1219966
(S) 2,4-Dichloropheny/Acetic
59.0
14.0-158
01/OS/201902:29
WG1219966
Fc
Acid
CIP Pesticides by Method 8141B
F,
Result Qualifier
MDL
RDL
Dilution
Analysis
Batch
Analyte ug/I
ug/I
ug/I
date/time
sAl
Azinphos-Methyl U
0.348
1.00
1
01/09/2019 19:22
WG1219785
Bolstar (Sulprofos) U
0.205
1.00
1
01/09/2019 19:22
WG1219785
F
Chlorpyrifos U
0.245
1.00
1
01/09/201919:22
WG1219785
Coumaphos U
0.277
1.00
1
01/09/2019 19:22
WG1219785
Demeton,-0 and -S U
0.341
2.00
1
01/09/2019 19:22
WG1219785
Diazinon U
0.377
1.00
1
01/09/2019 19:22
WG1219785
Dichlorvos U
0.212
2.00
1
01/09/2019 19:22
WG1219785
Dimethoate U
0.105
1.00
1
01/09/2019 19:22
WG1219785
Disulfoton U
0.277
1.00
1
01/09/2019 19:22
WG1219785
EPN U
0.261
1.00
1
01/09/2019 19:22
WG1219785
Ethoprop U
0.354
1.00
1
01/09/2019 19:22
WG1219785
Ethyl Parathion U
0.292
1.00
1
01/09/2019 19:22
WG1219785
Fensulfothion U
0.130
1.00
1
01/09/2019 19:22
WG1219785
Fenthion U
0.266
1.00
1
01/09/2019 19:22
WG1219785
Malathion U
0.173
1.00
1
01/09/2019 19:22
WG1219785
Merphos U J4
0.267
2.00
1
01/09/2019 19:22
WG1219785
Methyl parathion U
0.257
1.00
1
01/09/2019 19:22
WG1219785
Mevinphos U
0.118
1.00
1
01/09/2019 19:22
WG1219785
Naled U
0.289
1.00
1
01/09/2019 19:22
WG1219785
Phorate U
0.282
1.00
1
01/09/2019 19:22
WG1219785
Ronnel U
0.252
1.00
1
01/09/2019 19:22
WG1219785
Stirophos U
0.226
1.00
1
01/09/2019 19:22
WG1219785
Sulfotep U
0.202
1.00
1
01/09/2019 19:22
WG1219785
TEPP U
9.74
20.0
1
01/09/2019 19:22
WG1219785
Tokuthion (Prothothiofos) U
0.254
1.00
1
01/09/2019 19:22
WG1219785
Trichloronate U
0.213
1.00
1
01/09/2019 19:22
WG1219785
(S) Trlpheny/ Phosphate 75.8
42.0-129
011091201919:22
WG1219785
Pesticides (GC) by Method 8081B
Result Qualifier
MDL
RDL
Dilution
Analysis
Batch
Analyte ug/I
ug/I
ug/I
date / time
Aldrin U
0.00829
0.0510
1.02
01/09/201911:39
WG1219731
Alpha BHC U
0.0169
0.0510
1.02
01/09/201911:39
WG1219731
Beta BHC U
0.0188
0.0510
1.02
01/09/201911:39
WG1219731
Delta BHC U
0.0201
0.0510
1.02
01/09/201911:39
WG1219731
Gamma BHC U
0.0180
0.0510
1.02
01/09/201911:39
WG1219731
Chlordane U
0.0997
0.510
1.02
01/09/201911:39
WG1219731
4,4-DDD U
0.0173
0.0510
1.02
01/09/201911:39
WG1219731
4,4-DDE U
0.0167
0.0510
1.02
01/09/201911:39
WG1219731
4,4-DDT U
0.0181
0.0510
1.02
01/09/201911:39
WG1219731
ACCOUNT:
PROJECT:
SDG:
DATE/TIME: PAGE:
Hart and Hickman, PC
LVL-001
L1058027
01/17/19 15:18 18 of 84

SAMPLE RESULTS - 03
L1058027
ONE LAB. NATIONWIDE.
SW-1
Collected date/time: 01/03/19 12:50
Pesticides (GC) by Method 8081B
Result
Analyte
ug/I
Dieldrin
U
Endosulfan I
U
Endosulfan II
U
Endosulfan sulfate
U
Endrin
U
Endrin aldehyde
U
Endrin ketone
U
Hexachlorobenzene
U
Heptachlor
U
Heptachlor epoxide
U
Methoxychlor
U
Toxaphene
U
(S) Decachlorobipheny/
79.4
(S) Tetrach/oro-m-xylene
77.6
Qualifier MDL
ug/I
RDL
ug/I
Dilution
Analysis
date / time
Batch
0.00766
0.0510
1.02
01/09/201911:39
WG1219731
0.0183
0.0510
1.02
01/09/201911:39
WG1219731
0.0180
0.0510
1.02
01/09/201911:39
WG1219731
0.0200
0.0510
1.02
01/09/201911:39
WG1219731
0.0193
0.0510
1.02
01/09/201911:39
WG1219731
0.0145
0.0510
1.02
01/09/201911:39
WG1219731
0.0173
0.0510
1.02
01/09/201911:39
WG1219731
0.0137
0.0510
1.02
01/09/201911:39
WG1219731
0.0110
0.0510
1.02
01/09/201911:39
WG1219731
0.0179
0.0510
1.02
01/09/201911:39
WG1219731
0.0197
0.0510
1.02
01/09/201911:39
WG1219731
0.171
0.510
1.02
01/09/201911:39
WG1219731
10.0-128
01109120191139
WG1219731
10.0-127
01109120191139
WG1219731
Semi Volatile Organic Compounds (GC/MS) by Method 8270D
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/I ug/I ug/I date / time
Acenaphthene
U
0.316
1.00 1
01/05/2019 12:42
WG1219183
Acenaphthylene
U
0.309
1.00 1
01/05/2019 12:42
WG1219183
Anthracene
U
0.291
1.00 1
01/05/2019 12:42
WG1219183
Benzidine
U J3
4.32
10.0 1
01/05/2019 12:42
WG1219183
Benzo(a)anth race ne
U
0.0975
1.00 1
01/05/2019 12:42
WG1219183
Benzo(b)fluoranthene
U
0.0896
1.00 1
01/05/2019 12:42
WG1219183
Benzo(k)fluoranthene
U
0.355
1.00 1
01/05/2019 12:42
WG1219183
Benzo(g,h,i)perylene
U
0.161
1.00 1
01/05/2019 12:42
WG1219183
Benzo(a)pyrene
U
0.340
1.00 1
01/05/2019 12:42
WG1219183
Bis(2-chlorethoxy)methane
U
0.329
10.0 1
01/05/2019 12:42
WG1219183
Bis(2-chloroethyl)ether
U
1.62
10.0 1
01/05/2019 12:42
WG1219183
Bis(2-chloroisopropyl)ether
U
0.445
10.0 1
01/05/2019 12:42
WG1219183
4-Bromophenyl-phenylether
U
0.335
10.0 1
01/05/2019 12:42
WG1219183
2-Chloronaphthalene
U
0.330
1.00 1
01/05/2019 12:42
WG1219183
4-Chlorophenyl-phenylether
U
0.303
10.0 1
01/05/2019 12:42
WG1219183
Chrysene
U
0.332
1.00 1
01/05/2019 12:42
WG1219183
Dibenz(a,h)anthracene
U
0.279
1.00 1
01/05/2019 12:42
WG1219183
3,3-Dichlorobenzidine
U
2.02
10.0 1
01/05/2019 12:42
WG1219183
2,4-Dinitrotoluene
U
1.65
10.0 1
01/05/2019 12:42
WG1219183
2,6-Dinitrotoluene
U
0.279
10.0 1
01/05/2019 12:42
WG1219183
Fluoranthene
U
0.310
1.00 1
01/05/2019 12:42
WG1219183
Fluorene
U
0.323
1.00 1
01/05/2019 12:42
WG1219183
Hexachlorobenzene
U
0.341
1.00 1
01/05/2019 12:42
WG1219183
Hexachloro-1,3-butadiene
U
0.329
10.0 1
01/05/2019 12:42
WG1219183
Hexachlorocyclopentadiene
U
2.33
10.0 1
01/05/2019 12:42
WG1219183
Hexachloroethane
U
0.365
10.0 1
01/05/2019 12:42
WG1219183
Indeno(1,2,3-cd)pyrene
U
0.279
1.00 1
01/05/2019 12:42
WG1219183
Isophorone
U
0.272
10.0 1
01/05/2019 12:42
WG1219183
Naphthalene
U
0.372
1.00 1
01/05/2019 12:42
WG1219183
Nitrobenzene
U
0.367
10.0 1
01/05/2019 12:42
WG1219183
n-Nitrosodimethyla mine
U
1.26
10.0 1
01/05/2019 12:42
WG1219183
n-Nitrosodiphenyla mine
U
1.19
10.0 1
01/05/2019 12:42
WG1219183
n-Nitrosodi-n-propylamine
U
0.403
10.0 1
01/05/2019 12:42
WG1219183
Phenanthrene
U
0.366
1.00 1
01/05/2019 12:42
WG1219183
Benzylbutyl phthalate
U
0.275
3.00 1
01/05/2019 12:42
WG1219183
Bis(2-ethylhexyl)phthalate
U
0.709
3.00 1
01/05/2019 12:42
WG1219183
Di-n-butyl phthalate
U
0.266
3.00 1
01/05/2019 12:42
WG1219183
Diethyl phthalate
U
0.282
3.00 1
01/05/2019 12:42
WG1219183
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
Hart and
Hickman, PC
LVL-001
L1058027
01/17/19 15:18
FP1
FTC
FSS
4
Cn
Fc
F,
FAI
FSC
PAGE:
19 of 84

ONE LAB. NATIONWIDE.
SW-1 SAMPLE RESULTS - 03
Collected date/time: 01/03/19 12:50 L1058027
Semi Volatile Organic Compounds (GC/MS) by Method 8270D
Analyte
Dimethyl phthalate
Di-n-octyl phthalate
Pyrene
1,2,4-Trichlorobenzene
4-Ch I oro-3-m ethyl phenol
2-Chlorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
4,6-Di n itro-2-methyl phen of
2,4-Dinitrophenol
2-Nitrophenol
4-Nitrophenol
Pentachlorophenol
Phenol
2,4,6-Trichlorophenol
(S) 2-F/uorophenol
(S) Phenol-d5
(S) Nitrobenzene-d5
(S) 2-F/uorobiphenyl
(S) 2,4,6-Tribromophenol
(S) p-Terphenyl-d14
Result
Qualifier MDL
RDL
Dilution Analysis
ug/I
ug/I
ug/I
date / time
IJ
0.283
3.00
1 01/05/201912:42
IJ
0.278
3.00
1 01/05/201912:42
U
0.330
1.00
1 01/05/201912:42
IJ
0.355
10.0
1 01/05/201912:42
U
0.263
10.0
1 01/05/201912:42
J
0.283
10.0
1 01/05/201912:42
IJ
0.284
10.0
1 01/05/201912:42
J
0.264
10.0
1 01/05/201912:42
IJ
2.62
10.0
1 01/05/201912:42
J
3.25
10.0
1 01/05/201912:42
IJ
0.320
10.0
1 01/05/201912:42
IJ
2.01
10.0
1 01/05/201912:42
IJ
0.313
10.0
1 01/05/201912:42
0.508
1_ 0.334
10.0
1 01/05/201912:42
IJ
0.297
10.0
1 01/05/201912:42
26.5
10.0-120
011051201912.42
15.1
10.0-120
011051201912.42
40.2
10.0-127
011051201912.42
44.1
10.0-130
011051201912.42
37.7
10.0-155
011051201912.42
46.7
10.0-128
011051201912.42
Batch
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
FP
FTc
FS
Fn
FC]
F
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC LVL-001 L1058027 01/17/19 15:18 20 of 84

TRIP BLANK SAMPLE RESULTS - 04 ONE LAB. NATIONWIDE.
Collected date/time: 01/03/19 13:00 L1058027
Volatile Organic Compounds (GC/MS) by Method 8260B
Result
Qualifier MDL
RDL
Dilution Analysis
Batch
Analyte
ug/I
ug/I
ug/I
date / time
Acetone
U
10.0
50.0
1 01/04/2019 12:33
WG1219077
Acrolein
U
J4 8.87
50.0
1 01/04/2019 12:33
WG1219077
Acrylonitrile
U
1.87
10.0
1 01/04/2019 12:33
WG1219077
Benzene
U
0.331
1.00
1 01/04/2019 12:33
WG1219077
Bromobenzene
U
0.352
1.00
1 01/04/2019 12:33
WG1219077
Bromodichloromethane
U
0.380
1.00
1 01/04/2019 12:33
WG1219077
Bromoform
U
0.469
1.00
1 01/04/2019 12:33
WG1219077
Bromomethane
U
0.866
5.00
1 01/04/2019 12:33
WG1219077
n-Butylbenzene
U
0.361
1.00
1 01/04/2019 12:33
WG1219077
sec -Butyl benzene
U
0.365
1.00
1 01/04/2019 12:33
WG1219077
ter[-Butylbenzene
U
0.399
1.00
1 01/04/2019 12:33
WG1219077
Carbon tetrachloride
U
0.379
1.00
1 01/04/2019 12:33
WG1219077
Chlorobenzene
U
0.348
1.00
1 01/04/2019 12:33
WG1219077
Chlorodibromomethane
U
0.327
1.00
1 01/04/2019 12:33
WG1219077
Chloroethane
U
0.453
5.00
1 01/04/2019 12:33
WG1219077
Chloroform
U
0.324
5.00
1 01/04/2019 12:33
WG1219077
Chloromethane
U
0.276
2.50
1 01/04/2019 12:33
WG1219077
2-Chlorotoluene
U
0.375
1.00
1 01/04/2019 12:33
WG1219077
4-Chlorotoluene
U
0.351
1.00
1 01/04/2019 12:33
WG1219077
1,2-Dibromo-3-Chloropropane
U
1.33
5.00
1 01/04/2019 12:33
WG1219077
1,2-Dibromoethane
U
0.381
1.00
1 01/04/2019 12:33
WG1219077
Dibromomethane
U
0.346
1.00
1 01/04/2019 12:33
WG1219077
1,2-Dichlorobenzene
U
0.349
1.00
1 01/04/2019 12:33
WG1219077
1,3-Dichlorobenzene
U
0.220
1.00
1 01/04/2019 12:33
WG1219077
1,4-Dichlorobenzene
U
0.274
1.00
1 01/04/2019 12:33
WG1219077
Dichlorodifluoromethane
U
0.551
5.00
1 01/04/2019 12:33
WG1219077
1,1-Dichloroethane
U
0.259
1.00
1 01/04/2019 12:33
WG1219077
1,2-Dichloroethane
U
0.361
1.00
1 01/04/2019 12:33
WG1219077
1,1-Dichloroethene
U
0.398
1.00
1 01/04/2019 12:33
WG1219077
cis-1,2-Dichloroethene
U
0.260
1.00
1 01/04/2019 12:33
WG1219077
trans-1,2-Dichloroethene
U
0.396
1.00
1 01/04/2019 12:33
WG1219077
1,2-Dichloropropane
U
0.306
1.00
1 01/04/2019 12:33
WG1219077
1,1-Dichloropropene
U
0.352
1.00
1 01/04/2019 12:33
WG1219077
1,3-Dichloropropane
U
0.366
1.00
1 01/04/2019 12:33
WG1219077
cis-1,3-Dichloropropene
U
0.418
1.00
1 01/04/2019 12:33
WG1219077
trans-1,3-Dichloropropene
U
0.419
1.00
1 01/04/2019 12:33
WG1219077
2,2-Dichloropropane
U
0.321
1.00
1 01/04/2019 12:33
WG1219077
Di -isopropyl ether
U
0.320
1.00
1 01/04/2019 12:33
WG1219077
Ethylbenzene
U
0.384
1.00
1 01/04/2019 12:33
WG1219077
Hexachloro-1,3-butadiene
U
0.256
1.00
1 01/04/2019 12:33
WG1219077
Isopropylbenzene
U
0.326
1.00
1 01/04/2019 12:33
WG1219077
p-Isopropyltoluene
U
0.350
1.00
1 01/04/2019 12:33
WG1219077
2-Butanone (MEK)
U
3.93
10.0
1 01/04/2019 12:33
WG1219077
Methylene Chloride
U
1.00
5.00
1 01/04/2019 12:33
WG1219077
4-Methyl-2-pentanone (MIBK)
U
2.14
10.0
1 01/04/2019 12:33
WG1219077
Methyl tert-butyl ether
U
0.367
1.00
1 01/04/2019 12:33
WG1219077
Naphthalene
U
1.00
5.00
1 01/04/2019 12:33
WG1219077
n-Propylbenzene
U
0.349
1.00
1 01/04/2019 12:33
WG1219077
Styrene
U
0.307
1.00
1 01/04/2019 12:33
WG1219077
1,1,1,2-Tetrachloroethane
U
0.385
1.00
1 01/04/2019 12:33
WG1219077
1,1,2,2-Tetrachloroethane
U
0.130
1.00
1 01/04/2019 12:33
WG1219077
Tetrachloroethene
U
0.372
1.00
1 01/04/2019 12:33
WG1219077
Toluene
U
0.412
1.00
1 01/04/2019 12:33
WG1219077
1,2,3-Trichlorobenzene
U
0.230
1.00
1 01/04/2019 12:33
WG1219077
1,2,4-Trichlorobenzene
U
0.355
1.00
1 01/04/2019 12:33
WG1219077
1,1,1-Trichloroethane
U
0.319
1.00
1 01/04/2019 12:33
WG1219077
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
Hart and Hickman,
PC
LVL-001
L1058027
01/17/19 15:18
FP1
FTc
FSS
4
Cn
FC]
F ql
FAI
FSC
PAGE:
21 of 84

ONE LAB. NATIONWIDE.
TRIP BLANK SAMPLE RESULTS - 04
Collected date/time: 01/03/19 13:00 L1058027
Volatile Organic Compounds (GC/MS) by Method 8260B
Analyte
1,1,2-Trich I oroetha n e
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Tri methyl ben zen e
1,3,5-Trim ethyl benzene
Vinyl chloride
Xylenes, Total
(S) Toluene-d8
(S) DibromoFluoromethane
(S) 4-Bromof/uorobenzene
Result
ug/I
Qualifier MDL
ug/I
RDL
ug/I
Dilution Analysis
date / time
U
0.383
1.00
1 01/04/201912:33
U
0.398
1.00
1 01/04/201912:33
U
1.20
5.00
1 01/04/201912:33
U
0.807
2.50
1 01/04/201912:33
U
0.373
1.00
1 01/04/201912:33
U
0.387
1.00
1 01/04/201912:33
U
0.259
1.00
1 01/04/201912:33
U
1.06
3.00
1 01/04/201912:33
105
80.0-120
01/04/201912:33
87.3
75.0-120
01/04/201912:33
106
77.0-126
01/04/201912:33
Batch
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
WG1219077
Fp
FTc
FS
Fn
Fc
F,
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC LVL-001 L1058027 01/17/19 15:18 22 of 84

SW-2
Collected date/time: 01/03/19 15:20
Wet Chemistry by Method 300.0
SAMPLE RESULTS - 05
L1058027
Result Qualifier MDL RDL
Analyte ug/I ug/I ug/I
Nitrate as (N) J 22.7 100
Wet Chemistry by Method 7199
Dilution Analysis Batch
date / time
1 01/04/2019 21:48 WG1218970
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/I ug/I ug/I date / time
Hexavalent Chromium J 0.150 0.500 1 01/09/201913:24 WG1221008
Sample Narrative:
L1058027-05 WG1221008: Filtered and preserved 1/4 @ 1330
Mercury by Method 7470A
Result Qualifier
MDL
RDL
Analyte ug/I
ug/I
ug/I
Mercury J
0.0490
0.200
Mercury, Dissolved J
0.0490
0.200
Metals (ICPMS) by Method 6020B
Result
Qualifier
MDL
RDL
Analyte
ug/I
ug/I
ug/I
Arsenic
3.66
0.250
2.00
Arsenic, Dissolved
2.12
0.250
2.00
Barium
25.1
0.360
5.00
Barium,Dissolved
18.7
0.360
5.00
Cadmium
J
0.160
1.00
Cadmium,Dissolved
J
0.160
1.00
Chromium
2.38
B
0.540
2.00
Chromium,Dissolved
1.14
B J
0.540
2.00
Lead
1.21
J
0.240
2.00
Lead,Dissolved
0.407
B J
0.240
2.00
Selenium
J
0.380
2.00
Selenium,Dissolved
J
0.380
2.00
Silver
J
0.310
2.00
Silver,Dissolved
J
0.310
2.00
Volatile Organic
Compounds (GC/MS)
by Method
8260B
Result
Qualifier
MDL
RDL
Analyte
ug/I
ug/I
ug/I
Acetone
J
10.0
50.0
Acrolein
J
8.87
50.0
Acrylonitrile
J
1.87
10.0
Benzene
J
0.331
1.00
Bromobenzene
J
0.352
1.00
Bromodichloromethane
J
0.380
1.00
Bromoform
J
0.469
1.00
Bromomethane
J
0.866
5.00
n-Butylbenzene
J
0.361
1.00
sec -Butyl benzene
J
0.365
1.00
tert-Butylbenzene
J
0.399
1.00
Carbon tetrachloride
J
0.379
1.00
Chlorobenzene
J
0.348
1.00
Chlorodibromomethane
J
0.327
1.00
Chloroethane
J
0.453
5.00
Chloroform
J
0.324
5.00
Chloromethane
J
0.276
2.50
ACCOUNT:
PROJECT:
Hart
and Hickman, PC
LVL-001
Dilution Analysis Batch
date / time
1 01/07/201912:13 WG1219858
1 01/07/201910:35 WG1219860
Dilution Analysis
Batch
date / time
1 01/07/2019 20:32
WG1219455
1 01/07/2019 20:08
WG1219940
1 01/07/2019 20:32
WG1219455
1 01/07/2019 20:08
WG1219940
1 01/07/2019 20:32
WG1219455
1 01/07/2019 20:08
WG1219940
1 01/07/2019 20:32
WG1219455
1 01/07/2019 20:08
WG1219940
1 01/07/2019 20:32
WG1219455
1 01/07/2019 20:08
WG1219940
1 01/07/2019 20:32
WG1219455
1 01/07/2019 20:08
WG1219940
1 01/07/2019 20:32
WG1219455
1 01/07/2019 20:08
WG1219940
ONE LAB. NATIONWIDE.
FP1
FTc
FSS
4
Cn
Rc
�GI
FAI
FSC
Dilution Analysis
Batch
date / time
1 01/04/2019 21:17
WG1219326
1 01/04/2019 21:17
WG1219326
1 01/04/2019 21:17
WG1219326
1 01/04/2019 21:17
WG1219326
1 01/04/2019 21:17
WG1219326
1 01/04/2019 21:17
WG1219326
1 01/04/2019 21:17
WG1219326
1 01/04/2019 21:17
WG1219326
1 01/04/2019 21:17
WG1219326
1 01/04/2019 21:17
WG1219326
1 01/04/2019 21:17
WG1219326
1 01/04/2019 21:17
WG1219326
1 01/04/2019 21:17
WG1219326
1 01/04/2019 21:17
WG1219326
1 01/04/2019 21:17
WG1219326
1 01/04/2019 21:17
WG1219326
1 01/04/2019 21:17
WG1219326
SDG:
DATE/TIME: PAGE:
L1058027
01/17/19 15:18 23 of 84

ONE LAB. NATIONWIDE.
SW-2 SAMPLE RESULTS - 05
Collected date/time: 01/03/19 15:20 L1058027
Volatile Organic Compounds (GC/MS) by Method 8260B
Result
Qualifier MDL
RDL
Analyte
ug/I
ug/I
ug/I
2-Chlorotoluene
U
0.375
1.00
4-Chlorotoluene
U
0.351
1.00
1,2-Dibromo-3-Chloropropane
U
1.33
5.00
1,2-Dibromoethane
U
0.381
1.00
Dibromomethane
U
0.346
1.00
1,2-Dichlorobenzene
U
0.349
1.00
1,3-Dichlorobenzene
U
0.220
1.00
1,4-Dichlorobenzene
U
0.274
1.00
DichIorodifluoromethane
U
0.551
5.00
1,1-Dichloroethane
U
0.259
1.00
1,2-Dichloroethane
U
0.361
1.00
1,1-Dichloroethene
U
0.398
1.00
cis-1,2-Dichloroethene
U
0.260
1.00
trans-1,2-Dichloroethene
U
0.396
1.00
1,2-Dichloropropane
U
0.306
1.00
1,1-Dichloropropene
U
0.352
1.00
1,3-Dichloropropane
U
0.366
1.00
cis-1,3-Dichlcrop ropene
U
0.418
1.00
trans-1,3-Dichloropropene
U
0.419
1.00
2,2-Dichloropropane
U
0.321
1.00
Di -isopropyl ether
U
0.320
1.00
Ethylbenzene
U
0.384
1.00
Hexachloro-1,3-butadiene
U
0.256
1.00
Isopropylbenzene
U
0.326
1.00
p-Isopropyltoluene
U
0.350
1.00
2-Butanone (M EK)
U
3.93
10.0
Methylene Chloride
U
1.00
5.00
4-Methyl-2-pentanone (MIBK)
U
2.14
10.0
Methyl tert-butyl ether
U
0.367
1.00
Naphthalene
U
1.00
5.00
n-Propylbenzene
U
0.349
1.00
Styrene
U
0.307
1.00
1,1,1,2-Tetrachloroethane
U
0.385
1.00
1,1,2,2-Tetrachloroethane
U
0.130
1.00
Tetrachloroethene
U
0.372
1.00
Toluene
U
0.412
1.00
1,2,3-Trichlorobenzene
U
J3 0.230
1.00
1,2,4-Trichlorobenzene
U
0.355
1.00
1,1,1-Trichloroethane
U
0.319
1.00
1,1,2-Trichloroethane
U
0.383
1.00
Trichloroethene
U
0.398
1.00
Trichlorofluoromethane
U
1.20
5.00
1,2,3-Trichloropropane
U
0.807
2.50
1,2,4-Trimethylbenzene
U
0.373
1.00
1,3,5-Trimethyl benzene
U
0.387
1.00
Vinyl chloride
U
0.259
1.00
Xylenes, Total
U
1.06
3.00
(S) Toluene-d8
105
80.0-120
(S) Dibromofluoromethane
99.9
75.0-120
(S) 4-Bromofluorobenzene
101
77.0-126
Dilution Analysis Batch
date / time
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
01/04/2019 21:17
0110412019 21:17
0110412019 21:17
0110412019 21:17
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
WG1219326
FP1
FTc
FSS
4
Cn
Fc
F,
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME:
Hart and Hickman, PC LVL-001 L1058027 01/17/19 15:18
PAGE:
24 of 84

ONE LAB. NATIONWIDE.
SW-2 SAMPLE RESULTS - 05
Collected date/time: 01/03/19 15:20 L1058027
Chlorinated Acid Herbicides (GC) by Method 8151
Analyte
Result
ug/I
Qualifier MDL
ug/I
RDL
ug/I
Dilution Analysis
date / time
Batch
2,4-D
U
0.744
2.00
1 01/08/2019 02:42
WG1219966
Dalapon
U
1.04
2.00
1 01/08/2019 02:42
WG1219966
2,4-DB
U
0.775
4.00
1 01/08/2019 02:42
WG1219966
Dicamba
U
0.813
2.00
1 01/08/2019 02:42
WG1219966
Dichloroprop
U
0.778
2.00
1 01/08/2019 02:42
WG1219966
Dinoseb
U
0.795
2.00
1 01/08/2019 02:42
WG1219966
MCPA
U
J3 J4 13.1
200
1 01/08/2019 02:42
WG1219966
MCPP
U
7.15
200
1 01/08/2019 02:42
WG1219966
2,4,5-T
U
0.843
2.00
1 01/08/2019 02:42
WG1219966
2,4,5-TP (Silvex)
U
0.845
2.00
1 01/08/2019 02:42
WG1219966
(S)2,4-Dichloropheny/Acetic
60.0
14.0-158
011081201902.42
WG1219966
Acid
OP Pesticides by Method 8141B
Result Qualifier
MDL
RDL
Dilution Analysis
Batch
Analyte
ug/I
ug/I
ug/I
date / time
Azinphos-Methyl
U
0.348
1.00
1 01/09/2019 19:53
WG1219785
Bolstar (Sulprofos)
U
0.205
1.00
1 01/09/2019 19:53
WG1219785
Chlorpyrifos
U
0.245
1.00
1 01/09/2019 19:53
WG1219785
Coumaphos
U
0.277
1.00
1 01/09/2019 19:53
WG1219785
Demeton,-0 and -S
U
0.341
2.00
1 01/09/2019 19:53
WG1219785
Diazinon
U
0.377
1.00
1 01/09/2019 19:53
WG1219785
Dichlorvos
U
0.212
2.00
1 01/09/2019 19:53
WG1219785
Dimethoate
U
0.105
1.00
1 01/09/2019 19:53
WG1219785
Disulfoton
U
0.277
1.00
1 01/09/2019 19:53
WG1219785
EPN
U
0.261
1.00
1 01/09/2019 19:53
WG1219785
Ethoprop
U
0.354
1.00
1 01/09/2019 19:53
WG1219785
Ethyl Parathion
U
0.292
1.00
1 01/09/2019 19:53
WG1219785
Fensulfothion
U
0.130
1.00
1 01/09/2019 19:53
WG1219785
Fenthion
U
0.266
1.00
1 01/09/2019 19:53
WG1219785
Malathion
U
0.173
1.00
1 01/09/2019 19:53
WG1219785
Merphos
U J4
0.267
2.00
1 01/09/2019 19:53
WG1219785
Methyl parathion
U
0.257
1.00
1 01/09/2019 19:53
WG1219785
Mevinphos
U
0.118
1.00
1 01/09/2019 19:53
WG1219785
Naled
U
0.289
1.00
1 01/09/2019 19:53
WG1219785
Phorate
U
0.282
1.00
1 01/09/2019 19:53
WG1219785
Ronnel
U
0.252
1.00
1 01/09/2019 19:53
WG1219785
Stirophos
U
0.226
1.00
1 01/09/2019 19:53
WG1219785
Sulfotep
U
0.202
1.00
1 01/09/2019 19:53
WG1219785
TEPP
U
9.74
20.0
1 01/09/2019 19:53
WG1219785
Tokuthion (Prothothiofos)
U
0.254
1.00
1 01/09/2019 19:53
WG1219785
Trichloronate
U
0.213
1.00
1 01/09/2019 19:53
WG1219785
(S) Tripheny/ Phosphate
69.4
42.0-129
011091201919:53
WG1219785
Pesticides (GC) by Method 8081B
Result Qualifier
MDL
RDL
Dilution Analysis
Batch
Analyte
ug/I
ug/I
ug/I
date / time
Aldrin
U
0.00813
0.0500
1 01/09/201912:17
WG1219731
Alpha BHC
U
0.0166
0.0500
1 01/09/201912:17
WG1219731
Beta BHC
U
0.0184
0.0500
1 01/09/201912:17
WG1219731
Delta BHC
U
0.0197
0.0500
1 01/09/201912:17
WG1219731
Gamma BHC
U
0.0176
0.0500
1 01/09/201912:17
WG1219731
Chlordane
U
0.0977
0.500
1 01/09/201912:17
WG1219731
4,4-DDD
U
0.0170
0.0500
1 01/09/201912:17
WG1219731
4,4-DDE
U
0.0164
0.0500
1 01/09/201912:17
WG1219731
4,4-DDT
U
0.0177
0.0500
1 01/09/201912:17
WG1219731
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC LVL-001 L1058027 01/17/19 15:18 25 of 84

SAMPLE RESULTS - 05
L1058027
ONE LAB. NATIONWIDE.
SW-2
Collected date/time: 01/03/19 15:20
Pesticides (GC) by Method 8081B
Result
Analyte
ug/I
Dieldrin
J
Endosulfan I
U
Endosulfan II
J
Endosulfan sulfate
U
Endrin
J
Endrin aldehyde
IJ
Endrin ketone
U
Hexachlorobenzene
IJ
Heptachlor
U
Heptachlor epoxide
IJ
Methoxychlor
U
Toxaphene
IJ
(S) Decochlorobipheny/
65.5
(S) Tetrach/oro-m-xylene
78.2
Qualifier MDL
RDL
Dilution Analysis
Batch
ug/I
ug/I
date / time
0.00751
0.0500
1 01/09/201912:17
WG1219731
0.0179
0.0500
1 01/09/201912:17
WG1219731
0.0176
0.0500
1 01/09/201912:17
WG1219731
0.0196
0.0500
1 01/09/201912:17
WG1219731
0.0189
0.0500
1 01/09/201912:17
WG1219731
0.0142
0.0500
1 01/09/201912:17
WG1219731
0.0170
0.0500
1 01/09/201912:17
WG1219731
0.0134
0.0500
1 01/09/201912:17
WG1219731
0.0108
0.0500
1 01/09/201912:17
WG1219731
0.0175
0.0500
1 01/09/201912:17
WG1219731
0.0193
0.0500
1 01/09/201912:17
WG1219731
0.168
0.500
1 01/09/201912:17
WG1219731
10.0-128
011091201912:17
WG1219731
10.0-127
011091201912:17
WG1219731
Semi Volatile Organic Compounds (GC/MS) by Method 8270D
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/I ug/I ug/I date / time
Acenaphthene
U
0.316
1.00
1 01/05/2019 12:18
WG1219183
Acenaphthylene
J
0.309
1.00
1 01/05/2019 12:18
WG1219183
Anthracene
IJ
0.291
1.00
1 01/05/2019 12:18
WG1219183
Benzidine
U
J3 4.32
10.0
1 01/05/2019 12:18
WG1219183
Benzo(a)anth race ne
IJ
0.0975
1.00
1 01/05/2019 12:18
WG1219183
Benzo(b)fluoranthene
U
0.0896
1.00
1 01/05/2019 12:18
WG1219183
Benzo(k)fluoranthene
IJ
0.355
1.00
1 01/05/2019 12:18
WG1219183
Benzo(g,h,i)perylene
J
0.161
1.00
1 01/05/2019 12:18
WG1219183
Benzo(a)pyrene
U
0.340
1.00
1 01/05/2019 12:18
WG1219183
Bis(2-chlorethoxy)methane
J
0.329
10.0
1 01/05/2019 12:18
WG1219183
Bis(2-chloroethyl)ether
U
1.62
10.0
1 01/05/2019 12:18
WG1219183
Bis(2-chloroisopropyl)ether
U
0.445
10.0
1 01/05/2019 12:18
WG1219183
4-Bromophenyl-phenylether
IJ
0.335
10.0
1 01/05/2019 12:18
WG1219183
2-Chloronaphthalene
U
0.330
1.00
1 01/05/2019 12:18
WG1219183
4-Chlorophenyl-phenylether
IJ
0.303
10.0
1 01/05/2019 12:18
WG1219183
Chrysene
U
0.332
1.00
1 01/05/2019 12:18
WG1219183
Dibenz(a,h)anthracene
IJ
0.279
1.00
1 01/05/2019 12:18
WG1219183
3,3-Dichlorobenzidine
U
2.02
10.0
1 01/05/2019 12:18
WG1219183
2,4-Dinitrotoluene
IJ
1.65
10.0
1 01/05/2019 12:18
WG1219183
2,6-Dinitrotoluene
U
0.279
10.0
1 01/05/2019 12:18
WG1219183
Fluoranthene
IJ
0.310
1.00
1 01/05/2019 12:18
WG1219183
Fluorene
U
0.323
1.00
1 01/05/2019 12:18
WG1219183
Hexachlorobenzene
U
0.341
1.00
1 01/05/2019 12:18
WG1219183
Hexachloro-1,3-butadiene
U
0.329
10.0
1 01/05/2019 12:18
WG1219183
Hexachlorocyclopentadiene
U
2.33
10.0
1 01/05/2019 12:18
WG1219183
Hexachloroethane
J
0.365
10.0
1 01/05/2019 12:18
WG1219183
Indeno(1,2,3-cd)pyrene
U
0.279
1.00
1 01/05/2019 12:18
WG1219183
Isophorone
J
0.272
10.0
1 01/05/2019 12:18
WG1219183
Naphthalene
U
0.372
1.00
1 01/05/2019 12:18
WG1219183
Nitrobenzene
J
0.367
10.0
1 01/05/2019 12:18
WG1219183
n-Nitrosodimethyla mine
IJ
1.26
10.0
1 01/05/2019 12:18
WG1219183
n-Nitrosodiphenyla mine
U
1.19
10.0
1 01/05/2019 12:18
WG1219183
n-Nitrosodi-n-propylamine
IJ
0.403
10.0
1 01/05/2019 12:18
WG1219183
Phenanthrene
U
0.366
1.00
1 01/05/2019 12:18
WG1219183
Benzylbutyl phthalate
IJ
0.275
3.00
1 01/05/2019 12:18
WG1219183
Bis(2-ethylhexyl)phthalate
U
0.709
3.00
1 01/05/2019 12:18
WG1219183
Di-n-butyl phthalate
IJ
0.266
3.00
1 01/05/2019 12:18
WG1219183
Diethyl phthalate
U
0.282
3.00
1 01/05/2019 12:18
WG1219183
FP1
FTC
FSS
4
Cn
Fc
F,
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC LVL-001 L1058027 01/17/19 15:18 26 of 84

ONE LAB. NATIONWIDE.
SW-2 SAMPLE RESULTS - 05
Collected date/time: 01/03/19 15:20 L1058027
Semi Volatile Organic Compounds (GC/MS) by Method 8270D
Analyte
Dimethyl phthalate
Di-n-octyl phthalate
Pyrene
1,2,4-Trichlorobenzene
4-Ch I oro-3-m ethyl phenol
2-Chlorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
4,6-Di n itro-2-methyl phen of
2,4-Dinitrophenol
2-Nitrophenol
4-Nitrophenol
Pentachlorophenol
Phenol
2,4,6-Trichlorophenol
(S) 2-F/uorophenol
(S) Phenol-d5
(S) Nitrobenzene-d5
(S) 2-F/uorobiphenyl
(S) 2,4,6-Tribromophenol
(S) p-Terphenyl-d14
Result
ug/I
Qualifier MDL
ug/I
RDL
ug/I
Dilution Analysis
date / time
U
0.283
3.00
1 01/05/201912:18
U
0.278
3.00
1 01/05/201912:18
U
0.330
1.00
1 01/05/201912:18
U
0.355
10.0
1 01/05/201912:18
U
0.263
10.0
1 01/05/201912:18
U
0.283
10.0
1 01/05/201912:18
U
0.284
10.0
1 01/05/201912:18
U
0.264
10.0
1 01/05/201912:18
U
2.62
10.0
1 01/05/201912:18
U
3.25
10.0
1 01/05/201912:18
U
0.320
10.0
1 01/05/201912:18
U
2.01
10.0
1 01/05/201912:18
U
0.313
10.0
1 01/05/201912:18
2.76
1_ 0.334
10.0
1 01/05/201912:18
U
0.297
10.0
1 01/05/201912:18
26.3
10.0-120
011051201912:18
15.2
10.0-120
011051201912:18
40.4
10.0-127
011051201912:18
41.6
10.0-130
011051201912:18
38.2
10.0-155
011051201912:18
47.8
10.0-128
011051201912:18
Batch
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
WG1219183
FP
FTc
FS
Fn
FC]
F
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC LVL-001 L1058027 01/17/19 15:18 27 of 84

WG1219475
Total Solids by Method 2540 G-2011
Method Blank (MB)
(MB) R3374438-1 01/08/1914:33
MB Result MB Qualifier MB MDL
Analyte % %
Total Solids 0.000
L1057991-01 Original Sample (OS) • Duplicate (DUP)
MB RDL
(OS) L1057991-01 01/08/1914:33 • (DUP) R3374438-3 01/08/1914:33
Original Result DUP Result Dilution DUP RPD
Analyte % % %
Total Solids 89.8 88.8 1 1.08
Laboratory Control Sample (LCS)
(LCS) R3374438-2 01/08/1914:33
Spike Amount LCS Result LCS Rec.
Analyte % %_ %
Total Solids 50.0 50.0 100
QUALITY CONTROL SUMMARY
1-1058027-01,02
DUP Qualifier DUP RPD
Limits
10
Rec. Limits LCS Qualifier
o/
85.0-115
ONE LAB. NATIONWIDE.
— I
Cp
FTc
FSS
4
— Cn
FSr
— �GI
FAI
[Sc
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC LVL-001 L1058027 01/17/19 15:18 28 of 84

M �
WG1218970
Wet Chemistry by Method 300.0
Method Blank (MB)
(MB) R3373583-1 01/04/19 09:52
MB Result MB Qualifier MB MDL
Analyte ug/I ug/I
Nitrate U 22.7
L1057946-01 Original Sample (OS) • Duplicate (DUP)
MB RDL
ug/I
100
QUALITY CONTROL SUMMARY
L1058027-03,05
(OS) L1057946-01 01/04/1914:23 • (DUP) R3373583-3 01/04/1914.38
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/I ug/I % %
Nitrate 491 492 1 0.204 20
L1057965-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1057965-01 01/04/1919:25 • (DUP) R3373583-6 01/04/19 20:13
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/I ug/I % %
Nitrate U 0.000 1 0.000 20
Laboratory Control Sample (LCS)
(LCS) R3373583-2 01/04/19 10:08
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte ug/I ug/I % %
Nitrate 8000 8110 101 90.0-110
L1057946-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1057946-01 01/04/1914:23 • (MS) R3373583-4 01/04/1914:54 • (MSD) R3373583-5 01/04/1915:10
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD
Analyte ug/I ug/I ug/I ug/I % % % %
Nitrate 5000 491 5840 5850 107 107 1 80.0-120 0.275
L1057965-01 Original Sample (OS) • Matrix Spike (MS)
(OS) L1057965-01 01/04/1919:25 • (MS) R3373583-7 01/04/19 20:29
Spike Amount Original Result MS Result MS Rec. Dilution Rec. Limits MS Qualifier
Analyte ug/I ug/I ug/I % %
Nitrate 5000 U 4890 97.8 1 80.0-120
ONE LAB. NATIONWIDE.
RPD Limits
20
ACCOUNT: PROJECT:
Hart and Hickman, PC LVL-001
SDG: DATE/TIME: PAGE:
L1058027 01/17/19 15:18 29 of 84

WG1221008 QUALITY CONTROL SUMMARY
Wet Chemistry by Method 7199 L1058027-03,05
Method Blank (MB)
(MB) R3374598-1 01/09/1912:05
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/I ug/I ug/I
Hexavalent Chromium U 0.150 0.500
L1058297-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1058297-01 01/09/1913:57 • (DUP) R3374598-5 01/09/1914.35
Original Result DUP Result Dilution DUP RPD
Analyte ug/I ug/I
Hexavalent Chromium 0.666 0.653 1 1.91
Sample Narrative:
OS: Initial pH 9.07
Laboratory Control Sample (LCS)
DUP Qualifier DUP RPD
Limits
20
(LCS) R3374598-2 01/09/1912:13
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte ug/I ug/I % %
Hexavalent Chromium 2.00 2.00 99.9 90.0-110
L1058285-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1058285-01 01/09/1913:32 • (MS) R3374598-3 01/09/1913:40 • (MSD) R3374598-4 01/09/1913:49
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec.
Analyte ug/I ug/I ug/I ug/I % %
Hexavalent Chromium 50.0 U 48.6 49.3 97.3 98.5
Sample Narrative:
OS: Initial pH 8.81
Dilution Rec. Limits MS Qualifier MSD Qualifier RPD
1 90.0-110 1.28
ONE LAB. NATIONWIDE.
RPD Limits
20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
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WG1221753
Wet Chemistry by Method 7199
Method Blank (MB)
(MB) R3375251-1 01/11/1915:06
MB Result
Analyte mg/kg
Hexavalent Chromium U
MB Qualifier MB MDL MB RDL
mg/kg mg/kg
0.255 1.00
L1058027-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1058027-01 01/11/1915:19 • (DUP) R3375251-3 01/11/1915:28
Original Result DUP Result Dilution DUP RPD
(dry) (dry)
Analyte mg/kg mg/kg %
Hexavalent Chromium U 0.000 1 0.000
L1058915-05 Original Sample (OS) • Duplicate (DUP)
QUALITY CONTROL SUMMARY
1-1058027-01,02
DUP Qualifier DUP RPD
Limits
o�
20
(OS) L1058915-05 01/11/1918:02 • (DUP) R3375251-8 01/11/1918:09
Original Result DUP Result DUP RPD
Dilution DUP RPD DUP Qualifier
(dry) (dry) Limits
Analyte mg/kg mg/kg % %
Hexavalent Chromium 0.311 0.304 1 2.45 J 20
Laboratory Control Sample (LCS)
ONE LAB. NATIONWIDE.
(LCS) R3375251-2 01/11/19 15:12
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte mg/kg mg/kg % %
Hexavalent Chromium 10.0 9.94 99.4 80.0-120
L1058904-07 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1058904-07 01/11/1917:25 • (MS) R3375251-4 01/11/1917:31 • (MSD) R3375251-5 01/11/1917:38
Spike Amount
Original Result
MS Result (dry)
MSD Result MS Rec. MSD Rec. Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD RPD Limits
(dry)
(dry)
(dry)
Analyte mg/kg
mg/kg
mg/kg
mg/kg % %
%
% %
Hexavalent Chromium 23.9
U
23.7
23.5 98.9 98.3 1
75.0-125
0.527 20
ACCOUNT:
PROJECT:
SDG:
DATE/TIME: PAGE:
Hart and Hickman, PC
LVL-001
L1058027
01/17/19 15:18 31 of 84

WG1221753 QUALITY CONTROL SUMMARY
Wet Chemistry by Method 7199 L1058027-01,02
L1O58904-07 Original Sample (OS) • Matrix Spike (MS)
(OS) L1058904-07 01/11/1917:25 • (MS) R3375251-6 01/11/1917:44
Spike Amount Original Result MS Result (dry) MS Rec.
(dry) (dry)
Analyte mg/kg mg/kg mg/kg %
Hexavalent Chromium 1020 U 365 35.6
Dilution Rec. Limits MS Qualifier
50
75.0-125 J6
ONE LAB. NATIONWIDE.
FP1
FTC
FSS
4
Cn
FSr
�GI
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC LVL-001 L1058027 01/17/19 15:18 32 of 84

WG1219858
Mercury by Method 7470A
Method Blank (MB)
(MB) R3373889-1 01/07/1911:41
MB Result
Analyte ug/I
Mercury U
MB Qualifier MB MDL MB RDL
ug/I ug/I
0.0490 0.200
QUALITY CONTROL SUMMARY
L1058027-03,05
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3373889-2 01/07/1911:44 • (LCSD) R3373889-3 01/07/19 11:46
Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte ug/I ug/I ug/I % % % % %
Mercury 3.00 2.80 2.89 93.3 96.3 80.0-120 3.17 20
L1057973-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1057973-01 01/07/1911:53 • (MS) R3373889-4 01/07/1911:56 • (MSD) R3373889-5 01/07/1911:58
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD
Analyte ug/I ug/I ug/I ug/I % % % %
Mercury 3.00 ND 2.32 2.79 74.4 90.0 1 75.0-125 J6 18.3
ONE LAB. NATIONWIDE.
RPD Limits
20
— I
Cp
FTc
FSS
4
— Cn
FSr
— �GI
— $AI
[Sc
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
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WG1219860 QUALITY CONTROL SUMMARY
Mercury by Method 7470A 1-1058027-03,05
Method Blank (MB)
(MB) R3373842-1 01/07/1910:01
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/I ug/I ug/I
Mercury, Dissolved U 0.0490 0.200
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3373842-2 01/07/1910:04 • (LCSD) R3373842-3 01/07/1910:06
Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte ug/I ug/I ug/I % % % % %
Mercury, Dissolved 3.00 2.93 2.84 97.6 94.7 80.0-120 3.06 20
L1057793-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1057793-02 01/07/1910:08 • (MS) R3373842-4 01/07/1910:11 • (MSD) R3373842-5 01/07/1910:13
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD
Analyte ug/I ug/I ug/I ug/I % % % %
Mercury, Dissolved 3.00 ND 3.08 2.80 103 93.5 1 75.0-125 9.41
ONE LAB. NATIONWIDE.
RPD Limits
20
— I
Cp
FTc
FSS
4
— Cn
FSr
— �GI
— $AI
[Sc
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
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WG1219882 QUALITY CONTROL SUMMARY
Mercury by Method 7471B 1-1058027-01,02
Method Blank (MB)
(MB) R3373839-1 01/07/19 09:21
MB Result MB Qualifier MB MDL MB RDL
Analyte mg/kg mg/kg mg/kg
Mercury U 0.00280 0.0200
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3373839-2 01/07/19 09:23 • (LCSD) R3373839-3 01/07/19 09:26
Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte mg/kg mg/kg mg/kg % % % % %
Mercury 0.300 0.291 0.281 96.9 93.8 80.0-120 3.24 20
L1057991-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
ONE LAB. NATIONWIDE.
(OS) L1057991-01 01/07/19 09:28 • (MS) R3373839-4 01/07/19 09:31 • (MSD) R3373839-5 01/07/19 09:33
Spike Amount
Original Result
MS Result (dry)
MSD Result MS Rec. MSD Rec.
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD RPD Limits
(dry)
(dry)
(dry)
Analyte mg/kg
mg/kg
mg/kg
mg/kg % %
%
% %
Mercury 0.334
0.00583
0.331
0.319 97.2 93.8
1 75.0-125
3.49 20
ACCOUNT:
PROJECT:
SDG:
DATE/TIME: PAGE:
Hart and Hickman, PC
LVL-001
L1058027
01/17/19 15:18 35 of 84
— I
Cp
FTc
FSS
4
— Cn
FSr
— �GI
FAI
[Sc

WG1219455
Metals (ICPMS) by Method 6020B
Method Blank (MB)
(MB) R3374006-7 01/07/1918:23
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/I ug/I ug/I
Arsenic
U
0.250
2.00
Barium
U
0.360
5.00
Cadmium
U
0.160
1.00
Chromium
0.773 J_
0.540
2.00
Lead
U
0.240
2.00
Selenium
U
0.380
2.00
Silver
U
0.310
2.00
QUALITY CONTROL SUMMARY
L1058027-03,05
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
ONE LAB. NATIONWIDE.
(LCS) R3374006-8 01/07/1918:27 • (LCSD) R3374006-9 01/07/1918:32
Spike Amount
LCS Result
LCSD Result
LCS Rec.
LCSD Rec.
Rec. Limits
LCS Qualifier LCSD Qualifier
RPD
RPD Limits
Analyte
ug/I
ug/I
ug/I
%
%
%
%
%
Arsenic
50.0
48.6
49.8
97.3
99.7
80.0-120
2.44
20
Barium
50.0
44.9
45.6
89.8
91.2
80.0-120
1.55
20
Cadmium
50.0
51.7
51.9
103
104
80.0-120
0.396
20
Chromium
50.0
52.9
53.5
106
107
80.0-120
1.21
20
Lead
50.0
48.6
49.1
97.2
98.3
80.0-120
1.06
20
Selenium
50.0
52.0
51.0
104
102
80.0-120
2.04
20
Silver
50.0
50.6
50.1
101
100
80.0-120
0.883
20
L1057494-08
Original Sample
(OS) • Matrix Spike (MS) • Matrix
Spike Duplicate (MSD)
(OS) L1057494-08 01/07/1918:36 • (MS) R3374006-11 01/07/1918:45 • (MSD) R3374006-12 01/07/1918:49
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Dilution Rec. Limits MS Qualifier
MSD Qualifier
RPD
RPD Limits
Analyte
ug/I
ug/I
ug/I
ug/I
%
%
%
%
%
Arsenic
50.0
3.61
55.2
53.2
103 i
99.3
1 75.0-125
3.70
20
Barium
50.0
17.0
64.5
62.1
95.1
90.2
1 75.0-125
3.89
20
Cadmium
50.0
0.197
54.1
53.5
108
107
1 75.0-125
1.18
20
Chromium
50.0
0.835
54.7
52.1
108
102
1 75.0-125
4.98
20
Lead
50.0
U
50.1
49.2
100
98.3
1 75.0-125
1.86
20
Selenium
50.0
0.507
54.3
54.7
108
108
1 75.0-125
0.802
20
Silver
50.0
U
52.2
51.2
104
102
1 75.0-125
2.01
20
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
PAGE:
Hart and Hickman, PC
LVL-001
L1058027
01/17/19 15:18
36 of 84
FP1
FTc
FSS
4
Cn
FSr
�GI
FAI
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WG1219940
Metals (ICPMS) by Method 6020B
Method Blank (MB)
(MB) R3373979-1 01/07/1918:36
MB Result
Analyte
ug/I
Arsenic, Dissolved
U
Barium,Dissolved
U
Cadmium,Dissolved
U
Chromium,Dissolved
0.920
Lead,Dissolved
0.305
Selenium,Dissolved
U
Silver,Dissolved
U
MB Qualifier MB MDL MB RDL
ug/I ug/I
0.250
2.00
0.360
5.00
0.160
1.00
J 0.540
2.00
J 0.240
2.00
0.380
2.00
0.310
2.00
QUALITY CONTROL SUMMARY
L1058027-03,05
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3373979-2 01/07/1918:41 • (LCSD) R3373979-3 01/07/1918:45
Spike Amount
LCS Result
LCSD Result
LCS Rec.
Analyte
ug/I
ug/I
ug/I
%
Arsenic, Dissolved
50.0
47.7
48.0
95.5
Barium,Dissolved
50.0
44.8
48.2
89.6
Cadmium,Dissolved
50.0
51.7
50.8
103
Chromium,Dissolved
50.0
50.9
50.7
102
Lead,Dissolved
50.0
49.3
48.9
98.6
Selenium,Dissolved
50.0
56.2
53.9
112
Silver,Dissolved
50.0
51.7
51.7
103
LCSD Rec.
Rec. Limits
LCS Qualifier LCSD Qualifier RPD
RPD Limits
96.0
80.0-120
0.579
20
96.4
80.0-120
7.34
20
102
80.0-120
1.81
20
101
80.0-120
0.333
20
97.8
80.0-120
0.793
20
108
80.0-120
4.26
20
103
80.0-120
0.0669
20
L1058344-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1058344-01 01/07/1918:50 • (MS) R3373979-5 01/07/1918:59 • (MSD) R3373979-6 01/07/1919:04
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
ug/I
ug/I
ug/I
ug/I
%
%
Arsenic, Dissolved
50.0
0.797
48.7
49.2
95.8
96.9
Barium,Dissolved
50.0
130
193
196
125
131
Cadmium,Dissolved
50.0
U
44.9
44.0
89.8
88.0
Chromium,Dissolved
50.0
U
49.3
48.9
98.5
97.9
Lead,Dissolved
50.0
4.45
53.3
52.6
97.7
96.4
Selenium,Dissolved
50.0
U
60.3
54.4
121
109
Silver,Dissolved
50.0
U
51.3
50.6
103
101
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD
1 75.0-125
1.08
1 75.0-125
J5 1.42
1 75.0-125
2.04
1 75.0-125
0.648
1 75.0-125
1.24
1 75.0-125
10.4
1 75.0-125
1.45
ONE LAB. NATIONWIDE.
RPD Limits
20
20
20
20
20
20
20
FP1
FTc
FSS
4
Cn
FSr
�GI
FAI
[Sc
ACCOUNT:
Hart and Hickman, PC
PROJECT:
LVL-001
SDG: DATE/TIME:
L1058027 01/17/19 15:18
PAGE:
37 of 84

WG1220117 QUALITY CONTROL SUMMARY
Metals (ICPMS) by Method 6020B 1-1058027-01,02
Method Blank (MB)
(MB) R3374005-1 01/07/19 22:25
MB Result
MB Qualifier MB MDL
MB RDL
Analyte mg/kg
mg/kg
mg/kg
Arsenic U
0.125
0.500
Barium U
0.160
1.00
Cadmium U
0.0800
0.500
Chromium U
0.270
1.00
Lead U
0.120
0.500
Selenium U
0.190
0.500
Silver U
0.155
0.500
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3374005-2 01/07/19 22:29 • (LCSD) R3374005-3 01/07/19 22:34
Spike Amount
LCS Result
LCSD Result
LCS Rec.
LCSD Rec.
Rec. Limits
LCS Qualifier LCSD Qualifier RPD
RPD Limits
Analyte
mg/kg
mg/kg
mg/kg
%
%
%
%
%
Arsenic
100
101
101
101
101
80.0-120
0.650
20
Barium
100
95.9
93.8
95.9
93.8
80.0-120
2.23
20
Cadmium
100
108
108
108
108
80.0-120
0.571
20
Chromium
100
111
110
111
110
80.0-120
0.696
20
Lead
100
104
105
104
105
80.0-120
1.14
20
Selenium
100
106
108
106
108
80.0-120
1.24
20
Silver
20.0
21.2
21.2
106
106
80.0-120
0.216
20
L1058027-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1058027-01 01/07/19 22:38 • (MS) R3374005-6 01/07/19 22:51 • (MSD) R3374005-7 01/07/19 22:55
Spike Amount
Original Result
MS Result (dry)
MSD Result
MS Rec.
MSD Rec.
(dry)
(dry)
(dry)
Analyte
mg/kg
mg/kg
mg/kg
mg/kg
%
%
Arsenic
27.2
4.39
137
140
97.5
100
Barium
27.2
148
304
283
115
99.4
Cadmium
27.2
U
150
149
110
110
Chromium
27.2
36.6
192
208
115
126
Lead
27.2
17.3
158
158
104
104
Selenium
27.2
0.396
146
149
107
109
Silver
5.44
U
29.6
29.6
109
109
ONE LAB. NATIONWIDE.
Dilution
Rec. Limits
MS Qualifier MSD Qualifier RPD
RPD Limits
5
75.0-125
2.49
20
5
75.0-125
7.07
20
5
75.0-125
0.518
20
5
75.0-125
J5 7.97
20
5
75.0-125
0.0151
20
5
75.0-125
2.17
20
5
75.0-125
0.0323
20
FP1
FTc
FSS
4
Cn
FSr
�GI
FAI
[Sc
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC LVL-001 L1058027 01/17/19 15:18 38 of 84

WG1219077 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE.
Volatile Organic Compounds (GC/MS) by Method 8260B 1-1058027-03,04
Method Blank (MB)
(MB) R3373435-3 01/04/1911:15
MB Result
Analyte
ug/I
Acetone
U
Acrylonitrile
U
Acrolein
U
Benzene
U
Bromobenzene
U
Bromodichloromethane
U
Bromoform
U
Bromomethane
U
n-Butylbenzene
U
sec -Butyl benzene
U
tert-Butylbenzene
U
Carbon tetrachloride
U
Chlorobenzene
U
Chlorodibromomethane
U
Chloroethane
U
Chloroform
U
Chloromethane
U
2-Chlorotoluene
U
4-Chlorotoluene
U
1,2-Dibromo-3-Chloropropane
U
1,2-Dibromoethane
U
Dibromomethane
U
1,2-Dichlorobenzene
U
1,3-Dichlorobenzene
U
1,4-Dichlorobenzene
U
Dichlorodifluoromethane
U
1,1-Dichloroethane
U
1,2-Dichloroethane
U
1,1-Dichloroethene
U
cis-1,2-Dichloroethene
U
trans-1,2-Dichloroethene
U
1,2-Dichloropropane
U
1,1-Dichloropropene
U
1,3-Dichloropropane
U
cis-1,3-Dichloropropene
U
trans-1,3-Dichloropropene
U
2,2-Dichloropropane
U
Di -isopropyl ether
U
Ethylbenzene
U
Hexachloro-1,3-butadiene
U
MB Qualifier MB MDL
ug/I
10.0
1.87
8.87
0.331
0.352
0.380
0.469
0.866
0.361
0.365
0.399
0.379
0.348
0.327
0.453
0.324
0.276
0.375
0.351
1.33
0.381
0.346
0.349
0.220
0.274
0.551
0.259
0.361
0.398
0.260
0.396
0.306
0.352
0.366
0.418
0.419
0.321
0.320
0.384
0.256
MB RDL
ug/I
50.0
10.0
50.0
1.00
1.00
1.00
1.00
5.00
1.00
1.00
1.00
1.00
1.00
1.00
5.00
5.00
2.50
1.00
1.00
5.00
1.00
1.00
1.00
1.00
1.00
5.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC LVL-001 L1058027 01/17/19 15:18 39 of 84

WG1219077
Volatile Organic Compounds (GC/MS) by Method 8260B
Method Blank (MB)
QUALITY CONTROL SUMMARY
1-1058027-03,04
ONE LAB. NATIONWIDE.
(MB) R3373435-3 01/04/1911:15
MB Result
MB Qualifier
MB MDL
MB RDL
Analyte ug/I
ug/I
ug/I
Isopropylbenzene U
0.326
1.00
p-Isopropyltoluene U
0.350
1.00
2-Butanone (MEK) U
3.93
10.0
Methylene Chloride U
1.00
5.00
4-Methyl-2-pentanone (MIBK) U
2.14
10.0
Methyl tert-butyl ether U
0.367
1.00
Naphthalene U
1.00
5.00
n-Propylbenzene U
0.349
1.00
Styrene U
0.307
1.00
1,1,1,2-Tetrachloroethane U
0.385
1.00
1,1,2,2-Tetrachloroethane U
0.130
1.00
Tetrachloroethene U
0.372
1.00
Toluene U
0.412
1.00
1,2,3-Trichlorobenzene U
0.230
1.00
1,2,4-Trichlorobenzene U
0.355
1.00
1,1,1-Trichloroethane U
0.319
1.00
1,1,2-Trichloroethane U
0.383
1.00
Trichloroethene U
0.398
1.00
Trichlorofluoromethane U
1.20
5.00
1,2,3-Trichloropropane U
0.807
2.50
1,2,4-Trimethylbenzene U
0.373
1.00
1,3,5-Trimethyl benzene U
0.387
1.00
Vinyl chloride U
0.259
1.00
Xylenes, Total U
1.06
3.00
(S) Toluene-d8 105
80.0-120
(S) Dibromofluoromethane 86.6
75.0-120
(S) 4-Bromof/uorobenzene 108
77.0-126
Laboratory Control Sample (LCS) • Laboratory
Control Sample Duplicate (LCSD)
(LCS) R3373435-1 01/04/19 08:35 • (LCSD) R3373435-4 01/04/1911:35
Spike Amount
LCS Result
LCSD Result
LCS Rec.
LCSD Rec.
Rec. Limits
LCS Qualifier LCSD Qualifier RPD
RPD Limits
Analyte ug/I
ug/I
ug/I
%
%
%
%
%
Acetone 125
121
123
97.0
98.5
19.0-160
1.57
27
Acrylonitrile 125
112
113
89.8
90.1
55.0-149
0.380
20
Benzene 25.0
22.7
22.2
90.7
89.0
70.0-123
1.86
20
Bromobenzene 25.0
28.5
28.4
114
114
73.0-121
0.411
20
Bromodichloromethane 25.0
24.6
23.9
98.3
95.7
75.0-120
2.67
20
Bromoform 25.0
23.8
23.7
95.0
94.9
68.0-132
0.110
20
ACCOUNT:
PROJECT:
SDG:
DATE/TIME: PAGE:
Hart and Hickman, PC
LVL-001
L1058027
01/17/19 15:18 40 of 84
FP1
FTc
FSS
4
Cn
FSr
�GI
FAI
[Sc

WG1219077 QUALITY CONTROL SUMMARY
Volatile Organic Compounds (GC/MS) by Method 8260B 1-1058027-03,04
ONE LAB. NATIONWIDE.
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3373435-1 01/04/19 08:35 • (LCSD) R3373435-4 01/04/1911:35
Spike Amount
LCS Result
LCSD Result
Analyte
ug/I
ug/I
ug/I
Bromomethane
25.0
20.2
19.2
n-Butylbenzene
25.0
24.7
24.6
sec -Butyl benzene
25.0
30.2
31.1
tert-Butylbenzene
25.0
30.0
30.9
Carbon tetrachloride
25.0
21.5
21.4
Chlorobenzene
25.0
27.4
26.4
Chlorodibromomethane
25.0
26.2
25.3
Chloroethane
25.0
22.9
23.1
Chloroform
25.0
22.9
22.8
Chloromethane
25.0
25.2
24.2
2-Chlorotoluene
25.0
29.2
29.0
4-Chlorotoluene
25.0
28.8
29.1
1,2-Dibromo-3-Chloropropane
25.0
17.5
17.3
1,2-Dibromoethane
25.0
25.7
25.2
Dibromomethane
25.0
23.8
24.0
1,2-Dichlorobenzene
25.0
23.4
23.3
1,3-Dichlorobenzene
25.0
27.4
26.8
1,4-Dichlorobenzene
25.0
25.4
25.2
Dichlorodifluoromethane
25.0
23.9
23.6
1,1-Dichloroethane
25.0
22.8
22.4
1,2-Dichloroethane
25.0
22.3
22.0
1,1-Dichloroethene
25.0
22.4
22.2
cis-1,2-Dichloroethene
25.0
22.8
22.4
trans-1,2-Dichloroethene
25.0
22.4
22.2
1,2-Dichloropropane
25.0
26.2
25.6
1,1-Dichloropropene
25.0
22.8
22.7
1,3-Dichloropropane
25.0
26.6
25.9
cis-1,3-Dichloropropene
25.0
27.0
26.0
trans-1,3-Dichloropropene
25.0
26.5
25.6
2,2-Dichloropropane
25.0
22.8
21.7
Di -isopropyl ether
25.0
24.2
23.9
Ethylbenzene
25.0
26.3
25.8
Hexachloro-1,3-butadiene
25.0
25.3
25.4
Isopropylbenzene
25.0
29.2
29.5
p-Isopropyltoluene
25.0
29.9
29.8
2-Butanone (MEK)
125
110
111
Acrolein
125
278
264
Methylene Chloride
25.0
22.9
22.2
4-Methyl-2-pentanone (MIBK)
125
129
127
Methyl tert-butyl ether
25.0
22.8
23.3
ACCOUNT:
Hart and Hickman, PC
LCS Rec.
LCSD Rec.
Rec. Limits
LCS Qualifier LCSD Qualifier RPD
RPD Limits
80.6
76.7
10.0-160
4.96
25
98.9
98.6
73.0-125
0.332
20
121
125
75.0-125
2.94
20
120
123
76.0-124
2.89
20
86.2
85.5
68.0-126
0.775
20
109
106
80.0-121
3.68
20
105
101
77.0-125
3.53
20
91.8
92.2
47.0-150
0.497
20
91.5
91.3
73.0-120
0.191
20
101
96.8
41.0-142
4.05
20
117
116
76.0-123
0.684
20
115
116
75.0-122
1.11
20
69.9
69.3
58.0-134
0.865
20
103
101
80.0-122
1.90
20
95.2
96.2
80.0-120
0.992
20
93.5
93.3
79.0-121
0.173
20
110
107
79.0-120
2.27
20
102
101
79.0-120
0.773
20
95.5
94.4
51.0-149
1.18
20
91.3
89.8
70.0-126
1.68
20
89.3
87.9
70.0-128
1.60
20
89.6
88.9
71.0-124
0.758
20
91.2
89.5
73.0-120
1.88
20
89.8
88.8
73.0-120
1.01
20
105
102
77.0-125
2.14
20
91.2
90.7
74.0-126
0.549
20
106
104
80.0-120
2.61
20
108
104
80.0-123
3.66
20
106
103
78.0-124
3.34
20
91.3
86.8
58.0-130
5.01
20
97.0
95.7
58.0-138
1.33
20
105
103
79.0-123
1.64
20
101
102
54.0-138
0.501
20
117
118
76.0-127
0.910
20
120
119
76.0-125
0.271
20
88.2
88.4
44.0-160
0.271
20
222
211
10.0-160
J4 J4 4.95
26
91.7
88.8
67.0-120
3.21
20
103
101
68.0-142
1.65
20
91.2
93.0
68.0-125
2.02
20
PROJECT:
SDG:
DATE/TIME: PAGE:
LVL-001
L1058027
01/17/19 15:18 41 of 84
FP1
FTC
FSS
[Cn]
FSr
�GI
FAI
FSC

WG1219077 QUALITY CONTROL SUMMARY
Volatile Organic Compounds (GC/MS) by Method 8260B 1-1058027-03,04
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3373435-1 01/04/19 08:35 • (LCSD) R3373435-4 01/04/1911:35
Spike Amount
LCS Result
LCSD Result
LCS Rec.
Analyte
ug/I
ug/I
ug/I
%
Naphthalene
25.0
16.4
17.4
65.4
n-Propylbenzene
25.0
29.3
29.4
117
Styrene
25.0
29.0
29.6
116
1,1,1,2-Tetrachloroethane
25.0
27.4
26.7
110
1,1,2,2-Tetrachloroethane
25.0
26.6
26.9
106
Tetrachloroethene
25.0
27.5
26.9
110
Toluene
25.0
25.5
24.8
102
1,2,3-Trichlorobenzene
25.0
20.7
21.0
82.8
1,2,4-Trichlorobenzene
25.0
22.3
22.7
89.2
1,1,1-Trichloroethane
25.0
22.7
22.4
90.8
1,1,2-Trichloroethane
25.0
26.7
26.3
107
Trichloroethene
25.0
25.0
24.9
100
Trichlorofluoromethane
25.0
18.7
18.2
74.6
1,2,3-Trichloropropane
25.0
27.0
28.2
108
1,2,4-Trimethylbenzene
25.0
29.4
29.7
118
1,3,5-Trimethyl benzene
25.0
29.7
30.5
119
Vinyl chloride
25.0
24.5
24.8
98.2
Xylenes, Total
75.0
81.0
78.6
108
(S) Toluene-d8
103
(S) DibromoFluoromethane
86.2
(S) 4-Bromof/uorobenzene
107
LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD
69.4
117
118
107
108
107
99.0
83.8
91.0
89.5
105
99.6
72.9
113
119
122
99.0
105
101
87.4
112
54.0-135
77.0-124
73.0-130
75.0-125
65.0-130
72.0-132
79.0-120
50.0-138
57.0-137
73.0-124
80.0-120
78.0-124
59.0-147
73.0-130
76.0-121
76.0-122
67.0-131
79.0-123
80.0-120
75.0-120
77.0-126
0.138
1.75
2.78
1.25
2.30
2.95
1.29
1.98
1.47
1.40
0.462
2.35
4.08
0.948
2.63
0.844
3.01
RPD Limits
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
ONE LAB. NATIONWIDE.
FP1
FTC
FSS
4
Cn
FSr
�GI
FAI
FSC
ACCOUNT: PROJECT:
Hart and Hickman, PC LVL-001
SDG: DATE/TIME: PAGE:
L1058027 01/17/19 15:18 42 of 84

WG1219326 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE.
Volatile Organic Compounds (GC/MS) by Method 8260B L1058027-05
Method Blank (MB)
(MB) R3373619-3 01/04/1915:16
MB Result
Analyte
ug/I
Acetone
U
Acrolein
U
Acrylonitrile
U
Benzene
U
Bromobenzene
U
Bromodichloromethane
U
Bromoform
U
Bromomethane
U
n-Butylbenzene
U
sec -Butyl benzene
U
tert-Butylbenzene
U
Carbon tetrachloride
U
Chlorobenzene
U
Chlorodibromomethane
U
Chloroethane
U
Chloroform
U
Chloromethane
U
2-Chlorotoluene
U
4-Chlorotoluene
U
1,2-Dibromo-3-Chloropropane
U
1,2-Dibromoethane
U
Dibromomethane
U
1,2-Dichlorobenzene
U
1,3-Dichlorobenzene
U
1,4-Dichlorobenzene
U
Dichlorodifluoromethane
U
1,1-Dichloroethane
U
1,2-Dichloroethane
U
1,1-Dichloroethene
U
cis-1,2-Dichloroethene
U
trans-1,2-Dichloroethene
U
1,2-Dichloropropane
U
1,1-Dichloropropene
U
1,3-Dichloropropane
U
cis-1,3-Dichloropropene
U
trans-1,3-Dichloropropene
U
2,2-Dichloropropane
U
Di -isopropyl ether
U
Ethylbenzene
U
Hexachloro-1,3-butadiene
U
MB Qualifier MB MDL MB RDL
ug/I ug/I
10.0 50.0
8.87 50.0
1.87 10.0
0.331 1.00
0.352 1.00
0.380 1.00
0.469 1.00
0.866 5.00
0.361 1.00
0.365 1.00
0.399 1.00
0.379 1.00
0.348 1.00
0.327 1.00
0.453 5.00
0.324 5.00
0.276 2.50
0.375 1.00
0.351 1.00
1.33 5.00
0.381 1.00
0.346 1.00
0.349 1.00
0.220 1.00
0.274 1.00
0.551 5.00
0.259 1.00
0.361 1.00
0.398 1.00
0.260 1.00
0.396 1.00
0.306 1.00
0.352 1.00
0.366 1.00
0.418 1.00
0.419 1.00
0.321 1.00
0.320 1.00
0.384 1.00
0.256 1.00
FP1
FTC
FSS
[Cn]
FSr
�GI
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC LVL-001 L1058027 01/17/19 15:18 43 of 84

WG1219326 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE.
Volatile Organic Compounds (GC/MS) by Method 8260B L1058027-05
Method Blank (MB)
(MB) R3373619-3 01/04/1915:16
MB Result
Analyte
ug/I
Isopropylbenzene
U
p-Isopropyltoluene
U
2-Butanone (MEK)
U
Methylene Chloride
U
4-Methyl-2-pentanone (MIBK)
U
Methyl tert-butyl ether
U
Naphthalene
U
n-Propylbenzene
U
Styrene
U
1,1,1,2-Tetrachloroethane
U
1,1,2,2-Tetrachloroethane
U
Tetrachloroethene
U
Toluene
U
1,2,3-Trichlorobenzene
U
1,2,4-Trichlorobenzene
U
1,1,1-Trichloroethane
U
1,1,2-Trichloroethane
U
Trichloroethene
U
Trichlorofluoromethane
U
1,2,3-Trichloropropane
U
1,2,4-Trimethylbenzene
U
1,3,5-Trimethyl benzene
U
Vinyl chloride
U
Xylenes, Total
U
(S) Toluene-d8
107
(S) Dibromofluoromethane
97.3
(S) 4-Bromof/uorobenzene
98.3
MB Qualifier MB MDL MB RDL
ug/I ug/I
0.326
1.00
0.350
1.00
3.93
10.0
1.00
5.00
2.14
10.0
0.367
1.00
1.00
5.00
0.349
1.00
0.307
1.00
0.385
1.00
0.130
1.00
0.372
1.00
0.412
1.00
0.230
1.00
0.355
1.00
0.319
1.00
0.383
1.00
0.398
1.00
1.20
5.00
0.807
2.50
0.373
1.00
0.387
1.00
0.259
1.00
1.06
3.00
80.0-120
75.0-120
77.0-126
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3373619-1 01/04/1914:15 • (LCSD) R3373619-2 01/04/1914:35
Spike Amount
LCS Result
LCSD Result
Analyte
ug/I
ug/I
ug/I
Acetone
125
154
149
Acrolein
125
173
174
Acrylonitrile
125
134
132
Benzene
25.0
24.5
23.9
Bromobenzene
25.0
23.1
22.5
Bromodichloromethane
25.0
21.8
21.6
ACCOUNT:
Hart and Hickman, PC
LCS Rec.
LCSD Rec.
Rec. Limits
LCS Qualifier LCSD Qualifier RPD
RPD Limits
123
119
19.0-160
3.59
27
138
139
10.0-160
0.334
26
108
106
55.0-149
1.89
20
98.2
95.6
70.0-123
2.65
20
92.2
90.1
73.0-121
2.35
20
87.3
86.3
75.0-120
1.15
20
PROJECT:
SDG:
DATE/TIME: PAGE:
LVL-001
L1058027
01/17/19 15:18 44 of 84
FP1
FTc
FSS
4
Cn
FSr
�GI
FAI
FSC

WG1219326 QUALITY CONTROL SUMMARY
Volatile Organic Compounds (GC/MS) by Method 8260B L1058027-05
ONE LAB. NATIONWIDE.
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3373619-1 01/04/1914:15 • (LCSD) R3373619-2 01/04/1914:35
Spike Amount
LCS Result
LCSD Result
LCS Rec.
LCSD Rec.
Rec. Limits
LCS Qualifier LCSD Qualifier RPD
RPD Limits
Analyte
ug/I
ug/I
ug/I
%
%
%
%
%
Bromoform
25.0
24.1
24.3
96.3
97.1
68.0-132
0.771
20
Bromomethane
25.0
29.2
28.5
117
114
10.0-160
2.46
25
n-Butylbenzene
25.0
23.9
24.5
95.7
98.1
73.0-125
2.52
20
sec -Butyl benzene
25.0
24.3
24.1
97.1
96.5
75.0-125
0.573
20
tert-Butylbenzene
25.0
23.9
22.9
95.8
91.7
76.0-124
4.35
20
Carbon tetrachloride
25.0
23.3
22.9
93.1
91.8
68.0-126
1.41
20
Chlorobenzene
25.0
25.8
25.2
103
101
80.0-121
2.34
20
Chlorodibromomethane
25.0
23.4
23.5
93.7
93.9
77.0-125
0.259
20
Chloroethane
25.0
28.1
27.1
113
108
47.0-150
3.65
20
Chloroform
25.0
23.4
22.8
93.8
91.0
73.0-120
3.01
20
Chloromethane
25.0
28.8
27.7
115
111
41.0-142
3.91
20
2-Chlorotoluene
25.0
23.9
23.6
95.4
94.3
76.0-123
1.21
20
4-Chlorotoluene
25.0
24.9
24.3
99.6
97.1
75.0-122
2.55
20
1,2-Dibromo-3-Chloropropane
25.0
20.7
21.3
82.9
85.2
58.0-134
2.73
20
1,2-Dibromoethane
25.0
24.9
25.0
99.8
100
80.0-122
0.284
20
Dibromomethane
25.0
23.7
22.8
94.6
91.3
80.0-120
3.58
20
1,2-Dichlorobenzene
25.0
22.9
22.9
91.5
91.4
79.0-121
0.134
20
1,3-Dichlorobenzene
25.0
23.8
23.7
95.3
94.9
79.0-120
0.426
20
1,4-Dichlorobenzene
25.0
25.6
25.7
102
103
79.0-120
0.603
20
Dichlorodifluoromethane
25.0
31.7
31.6
127
126
51.0-149
0.139
20
1,1-Dichloroethane
25.0
24.6
23.0
98.5
92.2
70.0-126
6.64
20
1,2-Dichloroethane
25.0
24.2
23.4
96.6
93.8
70.0-128
3.01
20
1,1-Dichloroethene
25.0
23.3
22.7
93.1
90.8
71.0-124
2.52
20
cis-1,2-Dichloroethene
25.0
23.0
22.2
92.0
88.8
73.0-120
3.57
20
trans-1,2-Dichloroethene
25.0
24.3
23.2
97.1
92.6
73.0-120
4.70
20
1,2-Dichloropropane
25.0
24.9
25.2
99.7
101
77.0-125
1.24
20
1,1-Dichloropropene
25.0
24.3
22.8
97.1
91.2
74.0-126
6.19
20
1,3-Dichloropropane
25.0
26.4
26.1
106
104
80.0-120
1.16
20
cis-1,3-Dichloropropene
25.0
24.7
24.1
98.7
96.2
80.0-123
2.51
20
trans-1,3-Dichloropropene
25.0
27.0
27.4
108
110
78.0-124
1.67
20
2,2-Dichloropropane
25.0
24.4
23.8
97.4
95.0
58.0-130
2.48
20
Di -isopropyl ether
25.0
25.1
23.9
100
95.4
58.0-138
5.02
20
Ethylbenzene
25.0
25.3
24.2
101
97.0
79.0-123
4.19
20
Hexachloro-1,3-butadiene
25.0
17.5
20.2
70.2
80.9
54.0-138
14.2
20
Isopropylbenzene
25.0
24.3
23.4
97.1
93.8
76.0-127
3.44
20
p-Isopropyltoluene
25.0
23.7
23.8
94.6
95.1
76.0-125
0.499
20
2-Butanone (MEK)
125
130
131
104
105
44.0-160
1.37
20
Methylene Chloride
25.0
25.5
24.3
102
97.0
67.0-120
4.99
20
4-Methyl-2-pentanone (MIBK)
125
128
126
102
101
68.0-142
1.03
20
Methyl tert-butyl ether
25.0
24.6
26.0
98.4
104
68.0-125
5.47
20
ACCOUNT:
PROJECT:
SDG:
DATE/TIME: PAGE:
Hart and Hickman, PC
LVL-001
L1058027
01/17/19 15:18 45 of 84
FP1
FTC
FSS
[Cn]
FSr
�GI
FAI
FSC

WG1219326 QUALITY CONTROL SUMMARY
Volatile Organic Compounds (GC/MS) by Method 8260B L1058027-05
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3373619-1 01/04/1914:15 • (LCSD) R3373619-2 01/04/1914:35
Spike Amount
LCS Result
LCSD Result
LCS Rec.
Analyte
ug/I
ug/I
ug/I
%
Naphthalene
25.0
17.0
20.4
68.0
n-Propylbenzene
25.0
23.7
22.7
94.8
Styrene
25.0
25.0
23.6
100
1,1,1,2-Tetrachloroethane
25.0
22.8
21.9
91.3
1,1,2,2-Tetrachloroethane
25.0
22.8
22.1
91.1
Tetrachloroethene
25.0
24.3
23.7
97.2
Toluene
25.0
25.0
24.6
100
1,2,3-Trichlorobenzene
25.0
16.9
20.9
67.5
1,2,4-Trichlorobenzene
25.0
18.0
21.0
71.9
1,1,1-Trichloroethane
25.0
25.0
23.5
99.8
1,1,2-Trichloroethane
25.0
27.4
27.7
110
Trichloroethene
25.0
25.5
24.0
102
Trichlorofluoromethane
25.0
29.3
28.4
117
1,2,3-Trichloropropane
25.0
24.8
24.5
99.4
1,2,4-Trimethylbenzene
25.0
23.6
23.6
94.5
1,3,5-Trimethyl benzene
25.0
21.3
21.1
85.4
Vinyl chloride
25.0
28.4
27.3
113
Xylenes, Total
75.0
73.9
72.7
98.5
(S) Toluene-d8
102
(S) DibromoFluoromethane
97.4
(S) 4-Bromof/uorobenzene
91.4
LCSD Rec
81.8
90.7
94.5
87.8
88.6
94.7
98.2
83.4
84.0
94.0
ill
96.0
114
98.0
94.2
84.4
109
96.9
102
94.8
92.0
Rec. Limits LCS Qualifier LCSD Qualifier RPD
54.0-135
77.0-124
73.0-130
75.0-125
65.0-130
72.0-132
79.0-120
50.0-138
57.0-137
73.0-124
80.0-120
78.0-124
59.0-147
73.0-130
76.0-121
76.0-122
67.0-131
79.0-123
80.0-120
75.0-120
77.0-126
J3
4.39
5.78
3.92
2.79
2.62
1.82
21.1
15.5
6.02
1.04
6.03
2.93
1.38
0.302
1.08
3.70
1.64
RPD Limits
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
ONE LAB. NATIONWIDE.
FP1
FTC
FSS
4
Cn
FSr
�GI
FAI
FSC
ACCOUNT: PROJECT: SDG:
Hart and Hickman, PC LVL-001 L1058027
DATE/TIME:
01/17/19 15:18
PAGE:
46 of 84

WG1219369 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE.
Volatile Organic Compounds (GC/MS) by Method 8260B L1058027-01
Method Blank (MB)
(MB) R3373678-2 01/04/19 21:05
MB Result MB Qualifier
Analyte mg/kg
Acetone
Acrylonitrile
Benzene
Bromobenzene
Bromodichloromethane
Bromoform
sec -Butyl benzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dibromoethane
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,1-Dichloropropene
1,3-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
2,2-Dichloropropane
Di -isopropyl ether
Hexachloro-1,3-butadiene
Isopropylbenzene
p-Isopropyltoluene
2-Butanone (MEK)
Methylene Chloride
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.0158
J
MB MDL
mg/kg
0.0137
0.00190
0.000400
0.00105
0.000788
0.00598
0.00253
0.00155
0.00108
0.000573
0.000450
0.00108
0.000415
0.00139
0.000920
0.00113
0.00510
0.000525
0.00100
0.00145
0.00170
0.00197
0.000818
0.000575
0.000475
0.000500
0.000690
0.00143
0.00127
0.000700
0.00175
0.000678
0.00153
0.000793
0.000350
0.0127
0.000863
0.00233
0.0125
0.00664
MB RDL
mg/kg
0.0250
0.0125
0.00100
0.0125
0.00250
0.0250
0.0125
0.00500
0.00500
0.00250
0.00250
0.00500
0.00250
0.0125
0.00250
0.00500
0.0250
0.00250
0.00500
0.00500
0.00500
0.00500
0.00250
0.00250
0.00250
0.00250
0.00250
0.00500
0.00500
0.00250
0.00500
0.00250
0.00500
0.00250
0.00100
0.0250
0.00250
0.00500
0.0250
0.0250
FP1
FTC
FSS
[Cn]
FSr
�GI
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC LVL-001 L1058027 01/17/19 15:18 47 of 84

WG1219369
Volatile Organic Compounds (GC/MS) by Method 8260B
Method Blank (MB)
QUALITY CONTROL
L1058027-01
SUMMARY
ONE LAB. NATIONWIDE.
FP1(MB)
R3373678-2 01/04/19 21:05
MB Result
MB Qualifier
MB MDL
MB RDL
Analyte mg/kg
mg/kg
mg/kg
zTC
4-Methyl-2-pentanone (MIBK) U
0.0100
0.0250
Methyl tert-butyl ether U
0.000295
0.00100
FSS
Styrene U
0.00273
0.0125
1,1,1,2-Tetrachloroethane U
0.000500
0.00250
1,1,2,2-Tetrachloroethane U
0.000390
0.00250
rCn
Tetrachloroethene U
0.000700
0.00250
Toluene U
0.00125
0.00500
FSr
1,1,2-Trichlorotrifluoroethane U
0.000675
0.00250
1,2,3-Trichlorobenzene U
0.000625
0.00250
1,2,4-Trichlorobenzene U
0.00482
0.0125
1,1,1-Trichloroethane U
0.000275
0.00250
1,1,2-Trichloroethane U
0.000883
0.00250
7G1
Trichloroethene U
0.000400
0.00100
Trichlorofluoromethane U
0.000500
0.00250
1,2,3-Trichloropropane U
0.00510
0.0125
FAI
Vinyl chloride U
0.000683
0.00250
Xylenes, Total U
0.00478
0.00650
FSC
(S) Toluene-d8 ill
75.0-131
(S) DibromoFluoromeftne 92.2
65.0-129
(S) 4-Bromof/uorobenzene 107
67.0-138
Laboratory Control Sample (LCS)
(LCS) R3373678-1 01/04/1919:27
Spike Amount
LCS Result
LCS Rec.
Rec. Limits LCS Qualifier
Analyte mg/kg
mg/kg
%
%
Acetone 0.625
0.601
96.2
10.0-160
Acrylonitrile 0.625
0.761
122
45.0-153
Benzene 0.125
0.135
108
70.0-123
Bromobenzene 0.125
0.120
96.4
73.0-121
Bromodichloromethane 0.125
0.139
ill
73.0-121
Bromoform 0.125
0.149
119
64.0-132
sec -Butyl benzene 0.125
0.140
112
74.0-130
tert-Butylbenzene 0.125
0.128
102
75.0-127
Carbon tetrachloride 0.125
0.150
120
66.0-128
Chlorobenzene 0.125
0.124
99.0
76.0-128
Chlorodibromomethane 0.125
0.142
114
74.0-127
Chloroethane 0.125
0.159
127
61.0-134
Chloroform 0.125
0.130
104
72.0-123
ACCOUNT:
PROJECT:
SDG:
DATE/TIME: PAGE:
Hart and Hickman, PC
LVL-001
L1058027
01/17/19 15:18 48 of 84

WG1219369 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE.
Volatile Organic Compounds (GC/MS) by Method 8260B L1058027-01
Laboratory Control Sample (LCS)
(LCS) R3373678-1 01/04/1919:27
Spike Amount
LCS Result
LCS Rec.
Rec. Limits LCS Qualifier
Analyte
mg/kg
mg/kg
%
%
Chloromethane
0.125
0.152
122
51.0-138
2-Chlorotoluene
0.125
0.134
107
75.0-124
4-Chlorotoluene
0.125
0.130
104
75.0-124
1,2-Dibromo-3-Chloropropane
0.125
0.113
90.4
59.0-130
1,2-Dibromoethane
0.125
0.133
106
74.0-128
Dibromomethane
0.125
0.140
112
75.0-122
1,2-Dichlorobenzene
0.125
0.123
98.4
76.0-124
1,3-Dichlorobenzene
0.125
0.127
101
76.0-125
1,4-Dichlorobenzene
0.125
0.117
93.9
77.0-121
Dichlorodifluoromethane
0.125
0.192
154
43.0-156
1,1-Dichloroethane
0.125
0.139
111
70.0-127
1,2-Dichloroethane
0.125
0.135
108
65.0-131
1,1-Dichloroethene
0.125
0.144
115
65.0-131
cis-1,2-Dichloroethene
0.125
0.139
111
73.0-125
trans-1,2-Dichloroethene
0.125
0.133
107
71.0-125
1,2-Dichloropropane
0.125
0.134
107
74.0-125
1,1-Dichloropropene
0.125
0.138
110
73.0-125
1,3-Dichloropropane
0.125
0.137
109
80.0-125
cis-1,3-Dichloropropene
0.125
0.150
120
76.0-127
trans-1,3-Dichloropropene
0.125
0.147
117
73.0-127
2,2-Dichloropropane
0.125
0.155
124
59.0-135
Di -isopropyl ether
0.125
0.146
117
60.0-136
Hexachloro-1,3-butadiene
0.125
0.115
92.0
57.0-150
Isopropylbenzene
0.125
0.117
93.3
72.0-127
p-Isopropyltoluene
0.125
0.131
105
72.0-133
2-Butanone (MEK)
0.625
0.836
134
30.0-160
Methylene Chloride
0.125
0.125
99.9
68.0-123
4-Methyl-2-pentanone (MIBK)
0.625
0.752
120
56.0-143
Methyl tert-butyl ether
0.125
0.141
113
66.0-132
Styrene
0.125
0.102
81.4
72.0-127
1,1,1,2-Tetrachloroethane
0.125
0.135
108
74.0-129
1,1,2,2-Tetrachloroethane
0.125
0.139
111
68.0-128
Tetrachloroethene
0.125
0.129
103
70.0-136
Toluene
0.125
0.112
89.8
75.0-121
1,1,2-Trichlorotrifluoroethane
0.125
0.149
119
61.0-139
1,2,3-Trichlorobenzene
0.125
0.0731
58.5
59.0-139 J4
1,2,4-Trichlorobenzene
0.125
0.0869
69.5
62.0-137
1,1,1-Trichloroethane
0.125
0.152
122
69.0-126
1,1,2-Trichloroethane
0.125
0.135
108
78.0-123
Trichloroethene
0.125
0.146
117
76.0-126
ACCOUNT:
PROJECT:
Hart and Hickman, PC
LVL-001
SDG: DATE/TIME: PAGE:
L1058027 01/17/19 15:18 49 of 84
FP1
FTC
FSS
[Cn]
FSr
�GI
FAI
FSC

WG1219369
Volatile Organic Compounds (GC/MS) by Method 8260B
Laboratory Control Sample (LCS)
QUALITY CONTROL SUMMARY
L1058027-01
ONE LAB. NATIONWIDE.
(LCS) R3373678-1 01/04/1919:27
Spike Amount
LCS Result
LCS Rec.
Rec. Limits LCS Qualifier
Analyte mg/kg
mg/kg
%
%
Trichlorofluoromethane 0.125
0.153
123
61.0-142
1,2,3-Trichloropropane 0.125
0.134
107
67.0-129
Vinyl chloride 0.125
0.120
95.8
63.0-134
Xylenes, Total 0.375
0.405
108
72.0-127
(S) Toluene-d8
98.6
75.0-131
(S) DibromoFluoromethane
106
65.0-129
(S) 4-Bromof/uorobenzene
99.6
67.0-138
ACCOUNT:
PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC
LVL-001 L1058027 01/17/19 15:18 50 of 84
FP1
FTC
FSS
4
Cn
FSr
�GI
FAI
FSC

WG1219795 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE.
Volatile Organic Compounds (GC/MS) by Method 8260B 1-1058027-01,02
Method Blank (MB)
(MB) R3373795-2 01/06/1910:51
MB Result
Analyte mg/kg
Acetone
0.0223
Acrylonitrile
U
Benzene
U
Bromobenzene
U
Bromodichloromethane
U
Bromoform
U
Bromomethane
U
n-Butylbenzene
U
sec -Butyl benzene
U
tert-Butylbenzene
U
Carbon tetrachloride
U
Chlorobenzene
U
Chlorodibromomethane
U
Chloroethane
U
Chloroform
U
Chloromethane
U
2-Chlorotoluene
U
4-Chlorotoluene
U
1,2-Dibromo-3-Chloropropane
U
1,2-Dibromoethane
U
Dibromomethane
U
1,2-Dichlorobenzene
U
1,3-Dichlorobenzene
U
1,4-Dichlorobenzene
U
Dichlorodifluoromethane
U
1,1-Dichloroethane
U
1,2-Dichloroethane
U
1,1-Dichloroethene
U
cis-1,2-Dichloroethene
U
trans-1,2-Dichloroethene
U
1,2-Dichloropropane
U
1,1-Dichloropropene
U
1,3-Dichloropropane
U
cis-1,3-Dichloropropene
U
trans-1,3-Dichloropropene
U
2,2-Dichloropropane
U
Di -isopropyl ether
U
Ethylbenzene
U
Hexachloro-1,3-butadiene
U
Isopropylbenzene
U
ACCOUNT:
Hart and Hickman, PC
MB Qualifier MB MDL
MB RDL
mg/kg
mg/kg
J 0.0137
0.0250
0.00190
0.0125
0.000400
0.00100
0.00105
0.0125
0.000788
0.00250
0.00598
0.0250
0.00370
0.0125
0.00384
0.0125
0.00253
0.0125
0.00155
0.00500
0.00108
0.00500
0.000573
0.00250
0.000450
0.00250
0.00108
0.00500
0.000415
0.00250
0.00139
0.0125
0.000920
0.00250
0.00113
0.00500
0.00510
0.0250
0.000525
0.00250
0.00100
0.00500
0.00145
0.00500
0.00170
0.00500
0.00197
0.00500
0.000818
0.00250
0.000575
0.00250
0.000475
0.00250
0.000500
0.00250
0.000690
0.00250
0.00143
0.00500
0.00127
0.00500
0.000700
0.00250
0.00175
0.00500
0.000678
0.00250
0.00153
0.00500
0.000793
0.00250
0.000350
0.00100
0.000530
0.00250
0.0127
0.0250
0.000863
0.00250
PROJECT: SDG: DATE/TIME: PAGE:
LVL-001 L1058027 01/17/19 15:18 51 of 84
FP1
FTC
FSS
[Cn]
FSr
�GI
FAI
FSC

WG1219795 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE.
Volatile Organic Compounds (GC/MS) by Method 8260B 1-1058027-01,02
Method Blank (MB)
(MB) R3373795-2 01/06/1910:51
MB Result
Analyte mg/kg
p-Isopropyltoluene
U
2-Butanone (MEK)
U
Methylene Chloride
0.0162
4-Methyl-2-pentanone (MIBK)
U
Methyl tert-butyl ether
U
Naphthalene
U
n-Propylbenzene
U
Styrene
U
1,1,1,2-Tetrachloroethane
U
1,1,2,2-Tetrachloroethane
U
Tetrachloroethene
U
Toluene
U
1,1,2-Trichlorotrifluoroethane
U
1,2,3-Trichlorobe nzene
U
1,2,4-Trichlorobenzene
U
1,1,1-Trichloroethane
U
1,1,2-Trichloroethane
U
Trichloroethene
U
Trichlorofluoromethane
U
1,2,3-Trichloropropane
U
1,2,3-Trimethyl benzene
U
1,2,4-Trimethylbenzene
U
1,3,5-Trimethyl benzene
U
Vinyl chloride
U
Xylenes, Total
U
(S) Toluene-d8
105
(S) DibromoFluoromeftne
89.5
(S) 4-Bromof/uorobenzene
93.0
MB Qualifier MB MDL
mg/kg
MB RDL
mg/kg
0.00233
0.00500
0.0125
0.0250
J 0.00664
0.0250
0.0100
0.0250
0.000295
0.00100
0.00312
0.0125
0.00118
0.00500
0.00273
0.0125
0.000500
0.00250
0.000390
0.00250
0.000700
0.00250
0.00125
0.00500
0.000675
0.00250
0.000625
0.00250
0.00482
0.0125
0.000275
0.00250
0.000883
0.00250
0.000400
0.00100
0.000500
0.00250
0.00510
0.0125
0.00115
0.00500
0.00116
0.00500
0.00108
0.00500
0.000683
0.00250
0.00478
0.00650
Laboratory Control Sample (LCS)
75.0-131
65.0-129
67.0-138
(LCS) R3373795-1 01/06/19 09:28
Spike Amount
Analyte mg/kg
LCS Result
mg/kg
LCS Rec.
%
Rec. Limits LCS Qualifier
%
Acetone 0.625
0.585
93.6
10.0-160
Acrylonitrile 0.625
0.569
91.0
45.0-153
Benzene 0.125
0.127
102
70.0-123
Bromobenzene 0.125
0.115
92.0
73.0-121
Bromodichloromethane 0.125
0.127
102
73.0-121
ACCOUNT:
PROJECT:
Hart and Hickman, PC
LVL-001
SDG: DATE/TIME: PAGE:
L1058027 01/17/19 15:18 52 of 84
FP1
FTC
FSS
4
Cn
FSr
�GI
FAI
FSC

WG1219795
QUALITY CONTROL
SUMMARY
ONE LAB. NATIONWIDE.
Volatile Organic Compounds (GC/MS)
by Method 8260B
1-1058027-01,02
Laboratory Control Sample (LCS)
FP1(LCS)
R3373795-1 01/06/19 09:28
Spike Amount
LCS Result
LCS Rec.
Rec. Limits LCS Qualifier
Analyte mg/kg
mg/kg
%
%
FTC
Bromoform 0.125
0.113
90.4
64.0-132
Bromomethane 0.125
0.149
119
56.0-147
FSS
n-Butylbenzene 0.125
0.124
99.1
68.0-135
sec -Butyl benzene 0.125
0.118
94.3
74.0-130
tert-Butylbenzene 0.125
0.119
95.5
75.0-127
[Cn]
Carbon tetrachloride 0.125
0.124
98.9
66.0-128
Chlorobenzene 0.125
0.123
98.5
76.0-128
FSr
Chlorodibromomethane 0.125
0.112
89.7
74.0-127
Chloroethane 0.125
0.141
113
61.0-134
Chloroform 0.125
0.126
101
72.0-123
Chloromethane 0.125
0.140
112
51.0-138
2-Chlorotoluene 0.125
0.126
100
75.0-124
7G1
4-Chlorotoluene 0.125
0.118
94.8
75.0-124
1,2-Dibromo-3-Chloropropane 0.125
0.100
80.2
59.0-130
1,2-Dibromoethane 0.125
0.119
95.2
74.0-128
FAI
Dibromomethane 0.125
0.122
97.3
75.0-122
1,2-Dichlorobenzene 0.125
0.124
98.8
76.0-124
FSC
1,3-Dichlorobenzene 0.125
0.127
102
76.0-125
1,4-Dichlorobenzene 0.125
0.122
97.7
77.0-121
Dichlorodifluoromethane 0.125
0.126
101
43.0-156
1,1-Dichloroethane 0.125
0.122
97.7
70.0-127
1,2-Dichloroethane 0.125
0.127
102
65.0-131
1,1-Dichloroethene 0.125
0.135
108
65.0-131
cis-1,2-Dichloroethene 0.125
0.137
110
73.0-125
trans-1,2-Dichloroethene 0.125
0.127
102
71.0-125
1,2-Dichloropropane 0.125
0.136
108
74.0-125
1,1-Dichloropropene 0.125
0.126
101
73.0-125
1,3-Dichloropropane 0.125
0.122
97.7
80.0-125
cis-1,3-Dichloropropene 0.125
0.121
97.2
76.0-127
trans-1,3-Dichloropropene 0.125
0.117
93.5
73.0-127
2,2-Dichloropropane 0.125
0.142
114
59.0-135
Di -isopropyl ether 0.125
0.138
110
60.0-136
Ethylbenzene 0.125
0.123
98.8
74.0-126
Hexachloro-1,3-butadiene 0.125
0.117
93.8
57.0-150
Isopropylbenzene 0.125
0.122
97.6
72.0-127
p-Isopropyltoluene 0.125
0.123
98.7
72.0-133
2-Butanone (MEK) 0.625
0.558
89.3
30.0-160
Methylene Chloride 0.125
0.133
106
68.0-123
4-Methyl-2-pentanone (MIBK) 0.625
0.545
87.2
56.0-143
Methyl tert-butyl ether 0.125
0.123
98.6
66.0-132
ACCOUNT:
PROJECT:
SDG:
DATE/TIME: PAGE:
Hart and Hickman, PC
LVL-001
L1058027
01/17/19 15:18 53 of 84

WG1219795
QUALITY CONTROL
SUMMARY
ONE LAB. NATIONWIDE.
Volatile Organic Compounds (GC/MS)
by Method 8260B
1-1058027-01,02
Laboratory Control Sample (LCS)
FP1(LCS)
R3373795-1 01/06/19 09:28
Spike Amount
LCS Result
LCS Rec.
Rec. Limits LCS Qualifier
Analyte mg/kg
mg/kg
%
%
FTC
Naphthalene 0.125
0.0946
75.7
59.0-130
n-Propylbenzene 0.125
0.127
101
74.0-126
FSS
Styrene 0.125
0.121
96.4
72.0-127
1,1,1,2-Tetrachloroethane 0.125
0.119
95.3
74.0-129
1,1,2,2-Tetrachloroethane 0.125
0.121
97.0
68.0-128
rCn
Tetrachloroethene 0.125
0.136
109
70.0-136
Toluene 0.125
0.124
99.5
75.0-121
FSr
1,1,2-Trichlorotrifluoroethane 0.125
0.121
96.7
61.0-139
1,2,3-Trichlorobenzene 0.125
0.0966
77.3
59.0-139
1,2,4-Trichlorobenzene 0.125
0.118
94.5
62.0-137
1,1,1-Trichloroethane 0.125
0.122
97.6
69.0-126
1,1,2-Trichloroethane 0.125
0.121
97.1
78.0-123
7G1
Trichloroethene 0.125
0.124
99.6
76.0-126
Trichlorofluoromethane 0.125
0.133
107
61.0-142
1,2,3-Trichloropropane 0.125
0.117
93.6
67.0-129
FAI
1,2,3-Trimethyl benzene 0.125
0.117
93.7
74.0-124
1,2,4-Trimethylbenzene 0.125
0.120
95.7
70.0-126
FSC
1,3,5-Trimethyl benzene 0.125
0.121
96.5
73.0-127
Vinyl chloride 0.125
0.139
112
63.0-134
Xylenes, Total 0.375
0.372
99.2
72.0-127
(S) Toluene-d8
98.5
75.0-131
(S) DibromoFluoromeftne
94.4
65.0-129
(S) 4-Bromofluorobenzene
92.3
67.0-138
ACCOUNT:
PROJECT:
SDG:
DATE/TIME: PAGE:
Hart and Hickman, PC
LVL-001
L1058027
01/17/19 15:18 54 of 84

WG1219963
Chlorinated Acid Herbicides (GC) by Method 8151
Method Blank (MB)
QUALITY CONTROL SUMMARY
L1058027-01,02
(MB) R3373997-1 01/07/1917:34
MB Result
Analyte mg/kg
MB Qualifier MB MDL
mg/kg
MB RDL
mg/kg
2,4-D U
0.00702
0.0700
Dalapon U
0.0113
0.0700
2,4-DB U
0.0297
0.0700
Dicamba U
0.0157
0.0700
Dichloroprop U
0.0245
0.0700
Dinoseb U
0.00697
0.0700
MCPA U
0.443
6.50
MCPP U
0.367
6.50
2,4,5-T U
0.00852
0.0700
2,4,5-TP (Silvex) U
0.0107
0.0700
(S)2,4-Dichloropheny/Acetic 58.4
22.0-132
Acid
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3373997-2 01/07/1917:47 • (LCSD) R3373997-3 01/07/1918:01
Spike Amount
LCS Result
LCSD Result
LCS Rec.
Analyte
mg/kg
mg/kg
mg/kg
%
2,4-D
0.167
0.106
0.103
63.5
Dalapon
0.167
0.0801
0.0740
48.0
2,4-DB
0.167
0.112
0.106
67.1
Dicamba
0.167
0.0976
0.0914
58.4
Dichloroprop
0.167
0.115
0.108
68.9
Dinoseb
0.167
0.0433
0.0459
25.9
MCPA
1.67
2.44
2.15
146
MCPP
1.67
0.910
0.803
54.5
2,4,5-T
0.167
0.114
0.110
68.3
2,4,5-TP (Silvex)
0.167
0.108
0.105
64.7
(S) 2,4-Dichloropheny/Acetic
65.3
Acid
LCSD Rec.
Rec. Limits
LCS Qualifier LCSD Qualifier RPD
RPD Limits
61.7
40.0-120
2.87
20
44.3
15.0-120
P P 7.92
27
63.5
25.0-143
5.50
20
54.7
43.0-120
6.56
20
64.7
32.0-129
6.28
20
27.5
10.0-120
5.83
40
129
31.0-121
J4 J4 12.6
33
48.1
28.0-133
12.5
33
65.9
41.0-120
3.57
20
62.9
42.0-120
2.82
20
61.1 22.0-132
L1058208-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1058208-01 01/07/1919:24 • (MS) R3373997-4 01/07/1919:38 • (MSD) R3373997-5 01/07/1919:51
Spike Amount
Original Result
MS Result (dry)
MSD Result
MS Rec.
MSD Rec.
(dry)
(dry)
(dry)
Analyte
mg/kg
mg/kg
mg/kg
mg/kg
%
%
2,4-D
0.205
U
ND
0.116
0.000
56.5
Dalapon
0.205
U
ND
0.0804
0.000
39.2
2,4-DB
0.205
U
ND
0.110
0.000
53.6
Dilution Rec. Limits
MS Qualifier
MSD Qualifier
RPD
1 10.0-160
J6
J3
200
1 10.0-121
J6
J3
200
1 10.0-160
J6
J3
200
ONE LAB. NATIONWIDE.
RPD Limits
24
27
22
FP1
FTc
FSS
4
Cn
FSr
�GI
FAI
[Sc
ACCOUNT: PROJECT:
Hart and Hickman, PC LVL-001
SDG: DATE/TIME:
L1058027 01/17/19 15:18
PAGE:
55 of 84

WG1219963 QUALITY CONTROL SUMMARY
Chlorinated Acid Herbicides (GC) by Method 8151 1-1058027-01,02
L1O58208-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1058208-01 01/07/1919:24 • (MS) R3373997-4 01/07/1919:38 • (MSD) R3373997-5 01/07/1919:51
Spike Amount
Original Result
MS Result (dry)
MSD Result
MS Rec.
MSD Rec.
(dry)
(dry)
(dry)
Analyte
mg/kg
mg/kg
mg/kg
mg/kg
%
%
Dicamba
0.205
U
ND
0.123
0.000
59.7
Dichloroprop
0.205
U
ND
0.117
0.000
57.1
Dinoseb
0.205
U
ND
0.0436
0.000
21.3
MCPA
2.05
U
ND
2.06
0.000
101
MCPP
2.05
U
ND
0.889
0.000
43.3
2,4,5-T
0.205
U
ND
0.118
0.000
57.5
2,4,5-TP (Silvex)
0.205
U
ND
0.108
0.000
52.8
(S) 2,4-Dichlorophenyl Acetic
0.487
58.8
Acid
ACCOUNT: PROJECT:
Hart and Hickman, PC LVL-001
ONE LAB. NATIONWIDE.
Dilution Rec. Limits
MS Qualifier
MSD Qualifier RPD
RPD Limits
1 10.0-154
J6
J3 200
21
1 10.0-158
J6
J3 200
20
1 10.0-120
J6
J3 200
40
1 10.0-160
J6
J3 200
40
1 10.0-160
J6
J3 200
40
1 10.0-157
J6
J3 200
20
1 10.0-156
J6
J3 200
20
22.0-132
J2
SDG:
DATE/TIME:
PAGE:
L1058027
01/17/19 15:18
56 of 84
FP1
FTc
FSS
H
FSr
�GI
FAI
FSC

WG1219966
Chlorinated Acid Herbicides (GC) by Method 8151
Method Blank (MB)
(MB) R3374080-1 01/08/19 01:47
MB Result
MB Qualifier MB MDL
MB RDL
Analyte ug/I
ug/I
ug/I
2,4-D U
0.744
2.00
Dalapon U
1.04
2.00
2,4-DB U
0.775
4.00
Dicamba U
0.813
2.00
Dichloroprop U
0.778
2.00
Dinoseb U
0.795
2.00
MCPA U
13.1
200
MCPP U
7.15
200
2,4,5-T U
0.843
2.00
2,4,5-TP (Silvex) U
0.845
2.00
(S)2,4-Dichloropheny/Acetic 60.6
14.0-158
Acid
QUALITY CONTROL SUMMARY
L1058027-03,05
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3374080-2 01/08/19 02:01 • (LCSD) R3374080-3 01/08/19 02:15
Spike Amount
LCS Result
LCSD Result
LCS Rec.
LCSD Rec.
Rec. Limits
LCS Qualifier
LCSD Qualifier
RPD
RPD Limits
Analyte
ug/I
ug/I
ug/I
%
%
%
%
%
2,4-D
5.00
3.60
3.41
72.0
68.2
50.0-120
5.42
20
Dalapon
5.00
2.55
2.38
51.0
47.6
32.0-120
P
P
6.90
20
2,4-DB
5.00
3.28
3.11
65.6
62.2
53.0-140
5.32
20
Dicamba
5.00
3.07
2.86
61.4
57.2
51.0-120
P
7.08
20
Dichloroprop
5.00
3.69
3.50
73.8
70.0
55.0-127
P
P
5.29
20
Dinoseb
5.00
3.32
3.19
66.4
63.8
36.0-134
3.99
20
MCPA
50.0
109
165
218
330
10.0-160
E J4
E J3 J4
40.9
40
MCPP
50.0
25.9
25.5
51.8
51.0
10.0-160
1.56
23
2,4,5-T
5.00
3.68
3.52
73.6
70.4
54.0-120
4.44
20
2,4,5-TP (Silvex)
5.00
3.70
3.52
74.0
70.4
50.0-125
4.99
20
(S)2,4-Dichloropheny/Acetic
64.2
60.2
14.0-158
Acid
ONE LAB. NATIONWIDE.
FP1
FTc
FSS
4
Cn
FSr
�GI
FAI
[Sc
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC LVL-001 L1058027 01/17/19 15:18 57 of 84

WG1219355 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE.
OP Pesticides by Method 8141B L1058027-01
Method Blank (MB)
(MB) R3374782-1 01/09/1913:01
MB Result
Analyte
mg/kg
Azinphos-Methyl
U
Bolstar (Sulprofos)
U
Chlorpyrifos
U
Coumaphos
U
Demeton,-0 and -S
U
Diazinon
U
Dichlorvos
U
Dimethoate
U
Disulfoton
U
EPN
U
Ethoprop
U
Ethyl Parathion
U
Fensulfothion
U
Fenthion
U
Malathion
U
Merphos
U
Methyl parathion
U
Mevinphos
U
Naled
U
Phorate
U
Ronnel
U
Stirophos
U
Sulfotep
U
TEPP
U
Tokuthion (Prothothiofos)
U
Trichloronate
U
(S) Tripheny/ Phosphate
85.6
MB Qualifier MB MDL
mg/kg
MB RDL
mg/kg
0.00378
0.100
0.00554
0.100
0.00923
0.100
0.00680
0.100
0.00339
0.0700
0.00447
0.100
0.00969
0.100
0.0198
0.100
0.00498
0.100
0.00512
0.100
0.00465
0.100
0.00571
0.100
0.0169
0.100
0.00608
0.100
0.00700
0.100
0.00539
0.100
0.00669
0.100
0.0102
0.100
0.00418
0.100
0.00471
0.100
0.00437
0.100
0.00537
0.100
0.00386
0.100
0.157
1.00
0.00604
0.100
0.00664
0.100
36.0-121
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3374782-2 01/09/1914:36 • (LCSD) R3374782-3 01/09/1915:08
Spike Amount
LCS Result
LCSD Result
Analyte
mg/kg
mg/kg
mg/kg
Azinphos-Methyl
0.333
0.292
0.287
Bolstar (Sulprofos)
0.333
0.307
0.307
Chlorpyrifos
0.333
0.326
0.329
Coumaphos
0.333
0.350
0.345
Demeton,-0 and -S
0.167
0.148
0.151
Diazinon
0.333
0.247
0.221
ACCOUNT:
Hart and Hickman, PC
LCS Rec.
LCSD Rec.
Rec. Limits
LCS Qualifier LCSD Qualifier RPD
RPD Limits
87.7
86.2
58.0-125
1.73
20
92.2
92.2
64.0-120
0.000
20
97.9
98.8
62.0-120
0.916
20
105
104
60.0-120
1.44
20
88.6
90.4
59.0-120
P P 2.01
20
74.2
66.4
49.0-120
11.1
20
PROJECT:
SDG:
DATE/TIME: PAGE:
LVL-001
L1058027
01/17/19 15:18 58 of 84
FP1
FTc
FSS
4
Cn
FSr
�GI
FAI
[Sc

WG1219355 QUALITY CONTROL SUMMARY
OP Pesticides by Method 8141B L1058027-01
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3374782-2 01/09/1914:36 • (LCSD) R3374782-3 01/09/1915:08
Spike Amount
LCS Result
LCSD Result
Analyte
mg/kg
mg/kg
mg/kg
Dichlorvos
0.333
0.291
0.295
Dimethoate
0.333
0.270
0.272
Disulfoton
0.333
0.321
0.329
EPN
0.333
0.328
0.312
Ethoprop
0.333
0.335
0.331
Ethyl Parathion
0.333
0.341
0.334
Fensulfothion
0.333
0.270
0.255
Fenthion
0.333
0.323
0.336
Malathion
0.333
0.312
0.305
Merphos
0.333
0.443
0.455
Methyl parathion
0.333
0.352
0.341
Mevinphos
0.333
0.306
0.293
Naled
0.333
0.189
0.192
Phorate
0.333
0.314
0.316
Ronnel
0.333
0.320
0.325
Stirophos
0.333
0.318
0.314
Sulfotep
0.333
0.350
0.353
TEPP
3.33
ND
ND
Tokuthion (Prothothiofos)
0.333
0.320
0.327
Trichloronate
0.333
0.304
0.308
(S) Tripheny/ Phosphate
LCS Rec.
LCSD Rec.
Rec. Limits
LCS Qualifier LCSD Qualifier RPD
RPD Limits
87.4
88.6
37.0-120
1.37
22
81.1
81.7
46.0-127
0.738
20
96.4
98.8
60.0-121
2.46
20
98.5
93.7
60.0-121
5.00
20
101
99.4
59.0-120
1.20
20
102
100
62.0-120
2.07
20
81.1
76.6
58.0-123
5.71
20
97.0
101
61.0-121
3.95
20
93.7
91.6
59.0-120
2.27
20
133
137
59.0-120
J4 J4 2.67
20
106
102
63.0-120
3.17
20
91.9
88.0
50.0-120
4.34
20
56.8
57.7
10.0-125
1.57
26
94.3
94.9
60.0-120
0.635
20
96.1
97.6
62.0-120
1.55
20
95.5
94.3
62.0-120
1.27
20
105
106
62.0-122
0.853
20
0.000
0.000
1.00-135
J4 J4 0.000
40
96.1
98.2
63.0-120
2.16
20
91.3
92.5
62.0-120
1.31
20
84.4
83.8
36.0-121
L1058081-15 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1058081-15 01/10/1916:31 • (MS) R3375013-2 01/10/1917:02 • (MSD) R3375013-3 01/10/1917:34
Spike Amount
Original Result
MS Result (dry)
MSD Result
MS Rec.
(dry)
(dry)
(dry)
Analyte
mg/kg
mg/kg
mg/kg
mg/kg
%
Azinphos-Methyl
0.369
U
0.312
0.291
84.7
Bolstar (Sulprofos)
0.369
U
0.317
0.309
85.9
Chlorpyrifos
0.369
U
0.337
0.327
91.3
Coumaphos
0.369
U
0.361
0.349
97.9
Demeton,-0 and -S
0.185
U
0.168
0.165
91.0
Diazinon
0.369
U
0.350
0.342
94.9
Dichlorvos
0.369
U
0.518
0.497
141
Dimethoate
0.369
U
0.324
0.314
88.0
Disulfoton
0.369
U
0.342
0.336
92.8
EPN
0.369
U
0.330
0.312
89.5
Ethoprop
0.369
U
0.365
0.352
99.1
Ethyl Parathion
0.369
U
0.350
0.333
94.9
MSD Rec. Dilution Rec. Limits MS Qualifier
79.0
1 10.0-160
83.8
1 10.0-151
88.6
1 12.0-149
94.6
1 10.0-160
89.2
1 10.0-160
92.8
1 11.0-157
135
1 10.0-160
85.3
1 10.0-150
91.0
1 12.0-155
84.7
1 10.0-159
95.5
1 11.0-156
90.4
1 10.0-147
MSD Qualifier RPD
6.97
2.48
3.01
3.43
1.99
2.24
4.14
3.12
1.96
5.52
3.70
4.86
ONE LAB. NATIONWIDE.
RPD Limits
o�
22
20
20
22
23
20
24
27
20
20
20
20
FP1
FTC
FSS
[Cn]
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ACCOUNT: PROJECT:
Hart and Hickman, PC LVL-001
SDG:
L1058027
DATE/TIME:
01/17/19 15:18
PAGE:
59 of 84

WG1219355 QUALITY CONTROL SUMMARY
OP Pesticides by Method 8141B L1058027-01
L1O58O81-15 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1058081-15 01/10/1916:31 • (MS) R3375013-2 01/10/1917:02 • (MSD) R3375013-3 01/10/1917:34
Spike Amount
Original Result
MS Result (dry)
MSD Result
MS Rec.
MSD Rec.
Dilution Rec. Limits
(dry)
(dry)
(dry)
Analyte
mg/kg
mg/kg
mg/kg
mg/kg
%
%
%
Fensulfothion
0.369
U
0.321
0.305
87.1
82.6
1 10.0-157
Fenthion
0.369
U
0.336
0.323
91.0
87.7
1 13.0-155
Malathion
0.369
U
0.322
0.308
87.4
83.5
1 13.0-137
Merphos
0.369
U
0.302
0.297
82.0
80.5
1 10.0-147
Methyl parathion
0.369
U
0.369
0.349
100
94.6
1 10.0-150
Mevinphos
0.369
U
0.383
0.365
104
99.1
1 10.0-158
Naled
0.369
U
0.0918
0.0910
24.9
24.7
1 10.0-137
Phorate
0.369
U
0.347
0.333
94.0
90.4
1 13.0-154
Ronnel
0.369
U
0.333
0.328
90.4
88.9
1 14.0-149
Stirophos
0.369
U
0.338
0.320
91.6
86.8
1 10.0-150
Sulfotep
0.369
U
0.371
0.362
101
98.2
1 10.0-160
TEPP
3.69
U
1.08
1.13
29.2
30.6
1 1.00-142
Tokuthion (Prothothiofos)
0.369
U
0.326
0.313
88.3
85.0
1 12.0-153
Trichloronate
0.369
U
0.323
0.312
87.7
84.7
1 12.0-152
(S) Tripheny/ Phosphate
79.9
77.5
36.0-121
ONE LAB. NATIONWIDE.
MS Qualifier MSD Qualifier RPD RPD Limits
5.31 27
3.70 20
4.57 21
1.85 26
5.56 21
4.73 24
0.848 40
3.91 20
1.68 20
5.39 20
2.42 20
4.82 28
3.81 20
3.48 20
FP1
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SDG:
L1058027
DATE/TIME:
01/17/19 15:18
PAGE:
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WG1219897
OP Pesticides by Method 8141B
Method Blank (MB)
QUALITY CONTROL SUMMARY
L1058027-02
ONE LAB. NATIONWIDE.
(MB) R3374784-1 01/09/1914:05
MB Result
MB Qualifier
MB MDL
MB RDL
Analyte mg/kg
mg/kg
mg/kg
Azinphos-Methyl U
0.00378
0.100
Bolstar (Sulprofos) U
0.00554
0.100
Chlorpyrifos U
0.00923
0.100
Coumaphos U
0.00680
0.100
Demeton,-0 and -S U
0.00339
0.0700
Diazinon U
0.00447
0.100
Dichlorvos U
0.00969
0.100
Dimethoate U
0.0198
0.100
Disulfoton U
0.00498
0.100
EPN U
0.00512
0.100
Ethoprop U
0.00465
0.100
Ethyl Parathion U
0.00571
0.100
Fensulfothion U
0.0169
0.100
Fenthion U
0.00608
0.100
Malathion U
0.00700
0.100
Merphos U
0.00539
0.100
Methyl parathion U
0.00669
0.100
Mevinphos U
0.0102
0.100
Naled U
0.00418
0.100
Phorate U
0.00471
0.100
Ronnel U
0.00437
0.100
Stirophos U
0.00537
0.100
Sulfotep U
0.00386
0.100
TEPP U
0.157
1.00
Tokuthion (Prothothiofos) U
0.00604
0.100
Trichloronate U
0.00664
0.100
(S) Tripheny/ Phosphate 40.2
36.0-121
Laboratory Control Sample (LCS) • Laboratory
Control
Sample Duplicate (LCSD)
(LCS) R3374784-2 01/09/1916:43 • (LCSD) R3374784-3 01/09/1917:15
Spike Amount
LCS Result
LCSD Result
LCS Rec.
LCSD Rec.
Rec. Limits
LCS Qualifier LCSD Qualifier RPD
RPD Limits
Analyte mg/kg
mg/kg
mg/kg
%
%
%
%
%
Azinphos-Methyl 0.333
0.294
0.311
88.3
93.4
58.0-125
5.62
20
Bolstar (Sulprofos) 0.333
0.312
0.329
93.7
98.8
64.0-120
5.30
20
Chlorpyrifos 0.333
0.324
0.343
97.3
103
62.0-120
5.70
20
Coumaphos 0.333
0.344
0.370
103
ill
60.0-120
7.28
20
Demeton,-0 and -S 0.167
0.155
0.166
92.8
99.4
59.0-120
P P 6.85
20
Diazinon 0.333
0.266
0.242
79.9
72.7
49.0-120
9.45
20
ACCOUNT:
PROJECT:
SDG:
DATE/TIME: PAGE:
Hart and Hickman, PC
LVL-001
L1058027
01/17/19 15:18 61 of 84
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WG1219897 QUALITY CONTROL SUMMARY
OP Pesticides by Method 8141B L1058027-02
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3374784-2 01/09/1916:43 • (LCSD) R3374784-3 01/09/1917:15
Spike Amount
LCS Result
LCSD Result
LCS Rec.
LCSD Rec.
Rec. Limits
LCS Qualifier LCSD Qualifier RPD
RPD Limits
Analyte
mg/kg
mg/kg
mg/kg
%
%
%
%
%
Dichlorvos
0.333
0.314
0.317
94.3
95.2
37.0-120
0.951
22
Dimethoate
0.333
0.290
0.307
87.1
92.2
46.0-127
5.70
20
Disulfoton
0.333
0.326
0.345
97.9
104
60.0-121
5.66
20
EPN
0.333
0.304
0.320
91.3
96.1
60.0-121
5.13
20
Ethoprop
0.333
0.336
0.354
101
106
59.0-120
5.22
20
Ethyl Parathion
0.333
0.326
0.345
97.9
104
62.0-120
5.66
20
Fensulfothion
0.333
0.279
0.297
83.8
89.2
58.0-123
6.25
20
Fenthion
0.333
0.333
0.351
100
105
61.0-121
5.26
20
Malathion
0.333
0.305
0.322
91.6
96.7
59.0-120
5.42
20
Merphos
0.333
0.466
0.476
140
143
59.0-120
J4 J4 2.12
20
Methyl parathion
0.333
0.339
0.355
102
107
63.0-120
4.61
20
Mevinphos
0.333
0.316
0.329
94.9
98.8
50.0-120
4.03
20
Naled
0.333
0.229
0.204
68.8
61.3
10.0-125
11.5
26
Phorate
0.333
0.313
0.333
94.0
100
60.0-120
6.19
20
Ronnel
0.333
0.325
0.341
97.6
102
62.0-120
4.80
20
Stirophos
0.333
0.320
0.332
96.1
99.7
62.0-120
3.68
20
Sulfotep
0.333
0.348
0.368
105
ill
62.0-122
5.59
20
TEPP
3.33
0.239
ND
7.18
0.000
1.00-135
J3 J4 200
40
Tokuthion (Prothothiofos)
0.333
0.324
0.344
97.3
103
63.0-120
5.99
20
Trichloronate
0.333
0.313
0.329
94.0
98.8
62.0-120
4.98
20
(S) Tripheny/ Phosphate
88.0
91.6
36.0-121
L10581O3-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1058103-02 01/10/1919:09 • (MS) R3375014-1 01/10/1919:41 • (MSD) R3375014-2 01/10/19 20:12
Spike Amount
Original Result
MS Result (dry)
MSD Result
MS Rec.
(dry)
(dry)
(dry)
Analyte
mg/kg
mg/kg
mg/kg
mg/kg
%
Azinphos-Methyl
0.410
U
0.321
0.344
78.4
Bolstar (Sulprofos)
0.410
U
0.331
0.364
80.8
Chlorpyrifos
0.410
U
0.359
0.380
87.7
Coumaphos
0.410
U
0.383
0.412
93.4
Demeton,-0 and -S
0.205
U
0.186
0.192
90.4
Diazinon
0.410
U
0.370
0.387
90.4
Dichlorvos
0.410
U
0.567
0.611
138
Dimethoate
0.410
U
0.354
0.379
86.5
Disulfoton
0.410
U
0.368
0.387
89.8
EPN
0.410
U
0.349
0.374
85.3
Ethoprop
0.410
U
0.385
0.405
94.0
Ethyl Parathion
0.410
U
0.369
0.391
90.1
MSD Rec
84.1
88.9
92.8
101
93.4
94.6
149
92.5
94.6
91.3
98.8
95.5
Dilution Rec. Limits MS Qualifier
o/-
IV.V-IVV
10.0-151
12.0-149
10.0-160
10.0-160
11.0-157
10.0-160
10.0-150
12.0-155
10.0-159
11.0-156
10.0-147
MSD Qualifier RPD
7.02
9.56
5.66
7.43
3.26
4.55
7.52
6.71
5.21
6.80
4.98
5.83
ONE LAB. NATIONWIDE.
RPD Limits
o�
22
20
20
22
23
20
24
27
20
20
20
20
FP1
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FSS
[Cn]
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ACCOUNT: PROJECT:
Hart and Hickman, PC LVL-001
SDG:
L1058027
DATE/TIME:
01/17/19 15:18
PAGE:
62 of 84

WG1219897 QUALITY CONTROL SUMMARY
OP Pesticides by Method 8141E L1058027-02
L1O581O3-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1058103-02 01/10/1919:09 • (MS) R3375014-1 01/10/1919:41 • (MSD) R3375014-2 01/10/19 20:12
Spike Amount
Original Result
MS Result (dry)
MSD Result
MS Rec.
MSD Rec.
Dilution Rec. Limits
(dry)
(dry)
(dry)
Analyte
mg/kg
mg/kg
mg/kg
mg/kg
%
%
%
Fensulfothion
0.410
U
0.332
0.352
81.1
85.9
1 10.0-157
Fenthion
0.410
U
0.355
0.380
86.8
92.8
1 13.0-155
Malathion
0.410
U
0.342
0.363
83.5
88.6
1 13.0-137
Merphos
0.410
U
0.443
0.456
108
ill
1 10.0-147
Methyl parathion
0.410
U
0.385
0.416
94.0
102
1 10.0-150
Mevinphos
0.410
U
0.408
0.430
99.7
105
1 10.0-158
Naled
0.410
U
0.0546
0.0470
13.3
11.5
1 10.0-137
Phorate
0.410
U
0.359
0.385
87.7
94.0
1 13.0-154
Ronnel
0.410
U
0.365
0.385
89.2
94.0
1 14.0-149
Stirophos
0.410
U
0.348
0.375
85.0
91.6
1 10.0-150
Sulfotep
0.410
U
0.386
0.413
94.3
101
1 10.0-160
TEPP
4.10
U
2.29
2.31
55.9
56.5
1 1.00-142
Tokuthion (Prothothiofos)
0.410
U
0.354
0.381
86.5
93.1
1 12.0-153
Trichloronate
0.410
U
0.347
0.375
84.7
91.6
1 12.0-152
(S) Tripheny/ Phosphate
78.1
84.1
36.0-121
ONE LAB. NATIONWIDE.
MS Qualifier MSD Qualifier RPD RPD Limits
5.76 27
6.69 20
5.93 21
3.01 26
7.68 21
5.28 24
15.0 40
6.94 20
5.25 20
7.48 20
6.77 20
1.07 28
7.36 20
7.84 20
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L1058027
DATE/TIME:
01/17/19 15:18
PAGE:
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WG1219785
OP Pesticides by Method 8141E
Method Blank (MB)
(MB) R3374783-1 01/09/1913:33
MB Result
Analyte
ug/I
Azinphos-Methyl
U
Bolstar (Sulprofos)
U
Chlorpyrifos
U
Coumaphos
U
Demeton,-0 and -S
U
Diazinon
U
Dichlorvos
U
Dimethoate
U
Disulfoton
U
EPN
U
Ethoprop
U
Ethyl Parathion
U
Fensulfothion
U
Fenthion
U
Malathion
U
Merphos
U
Methyl parathion
U
Mevinphos
U
Naled
U
Phorate
U
Ronnel
U
Stirophos
U
Sulfotep
U
TEPP
U
Tokuthion (Prothothiofos)
U
Trichloronate
U
(S) Tripheny/ Phosphate
167
MB Qualifier MB MDL
ug/I
0.348
0.205
0.245
0.277
0.341
0.377
0.212
0.105
0.277
0.261
0.354
0.292
0.130
0.266
0.173
0.267
0.257
0.118
0.289
0.282
0.252
0.226
0.202
9.74
0.254
0.213
A
QUALITY CONTROL SUMMARY
L1058027-03,05
MB RDL
ug/I
1.00
1.00
1.00
1.00
2.00
1.00
2.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
2.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
20.0
1.00
1.00
42.0-129
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3374783-2 01/09/1915:40 • (LCSD) R3374783-3 01/09/1916:11
Spike Amount
LCS Result
LCSD Result
LCS Rec.
LCSD Rec.
Rec. Limits
LCS Qualifier LCSD Qualifier RPD
RPD Limits
Analyte
ug/I
ug/1
ug/I
%
%
%
%
%
Azinphos-Methyl
5.00
4.08
4.31
81.6
86.2
43.0-142
5.48
20
Bolstar (Sulprofos)
5.00
4.34
4.47
86.8
89.4
47.0-128
2.95
20
Chlorpyrifos
5.00
4.62
4.73
92.4
94.6
50.0-126
2.35
20
Coumaphos
5.00
4.35
4.70
87.0
94.0
37.0-137
7.73
20
Demeton,-0 and -S
2.50
2.22
2.28
88.8
91.2
22.0-150
P P 2.67
24
Diazinon
5.00
4.76
5.02
95.2
100
54.0-130
5.32
20
ONE LAB. NATIONWIDE.
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Hart and Hickman, PC LVL-001 L1058027 01/17/19 15:18 64 of 84

WG1219785 QUALITY CONTROL SUMMARY
OP Pesticides by Method 8141B L1058027-03,05
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3374783-2 01/09/1915:40 • (LCSD) R3374783-3 01/09/1916:11
Spike Amount
LCS Result
LCSD Result
LCS Rec.
Analyte
ug/I
ug/I
ug/I
%
Dichlorvos
5.00
4.76
5.05
95.2
Dimethoate
5.00
3.93
4.08
78.6
Disulfoton
5.00
4.65
4.80
93.0
EPN
5.00
4.34
4.52
86.8
Ethoprop
5.00
4.73
5.01
94.6
Ethyl Parathion
5.00
4.64
4.86
92.8
Fensulfothion
5.00
4.19
4.44
83.8
Fenthion
5.00
4.65
4.88
93.0
Marathion
5.00
4.40
4.57
88.0
Merphos
5.00
113
117
2260
Methyl parathion
5.00
4.84
4.98
96.8
Mevinphos
5.00
4.54
4.81
90.8
Naled
5.00
4.26
4.52
85.2
Phorate
5.00
4.29
4.57
85.8
Ronnel
5.00
4.46
4.71
89.2
Stirophos
5.00
4.44
4.83
88.8
Sulfotep
5.00
4.86
5.11
97.2
TEPP
50.0
30.4
34.5
60.8
Tokuthion (Prothothiofos)
5.00
4.50
4.80
90.0
Trichloronate
5.00
4.29
4.47
85.8
(S) Tripheny/ Phosphate
79.4
LCSD Rec.
Rec. Limits
LCS Qualifier LCSD Qualifier RPD
101
43.0-135
5.91
81.6
27.0-120
3.75
96.0
44.0-136
3.17
90.4
31.0-143
4.06
100
52.0-130
5.75
97.2
42.0-134
4.63
88.8
42.0-137
5.79
97.6
53.0-133
4.83
91.4
47.0-121
3.79
2340
14.0-123
J4 P J4 3.48
99.6
43.0-135
2.85
96.2
49.0-123
5.78
90.4
25.0-126
5.92
91.4
44.0-129
6.32
94.2
51.0-125
5.45
96.6
53.0-125
8.41
102
40.0-140
5.02
69.0
18.0-122
12.6
96.0
50.0-128
6.45
89.4
47.0-130
4.11
81.0
42.0-129
RPD Limits
24
27
21
21
20
20
20
20
20
25
20
23
26
20
20
20
22
32
20
21
ONE LAB. NATIONWIDE.
FP1
FTC
FSS
4
Cn
FSr
�GI
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC LVL-001 L1058027 01/17/19 15:18 65 of 84

WG1219182 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE.
Pesticides (GC) by Method 8081B 1-1058027-01,02
Method Blank (MB)
(MB) R3374450-1 01/07/1917:38
MB Result
Analyte mg/kg
Aldrin
U
Alpha BHC
U
Beta BHC
U
Delta BHC
U
Gamma BHC
U
4,4-DDD
U
4,4-DDE
U
4,4-DDT
U
Dieldrin
U
Endosulfan I
U
Endosulfan 11
U
Endosulfan sulfate
U
Endrin
U
Endrin aldehyde
U
Endrin ketone
U
Heptachlor
U
Heptachlor epoxide
U
Hexachlorobenzene
U
Methoxychlor
U
Chlordane
U
Toxaphene
U
(S) Decochlorobipheny/
103
(S) Tetrach/oro-m-xylene
107
MB Qualifier MB MDL
mg/kg
MB RDL
mg/kg
0.00135
0.0200
0.00136
0.0200
0.00160
0.0200
0.00143
0.0200
0.00145
0.0200
0.00156
0.0200
0.00154
0.0200
0.00200
0.0200
0.00152
0.0200
0.00149
0.0200
0.00160
0.0200
0.00151
0.0200
0.00157
0.0200
0.00129
0.0200
0.00165
0.0200
0.00154
0.0200
0.00161
0.0200
0.00124
0.0200
0.00178
0.0200
0.0390
0.200
0.0360
0.400
10.0-135
10.0-139
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3374450-2 01/07/1917:51 • (LCSD) R3374450-3 01/07/1918:03
Spike Amount
LCS Result
LCSD Result
Analyte
mg/kg
mg/kg
mg/kg
Aldrin
0.0666
0.0720
0.0643
Alpha BHC
0.0666
0.0640
0.0568
Beta BHC
0.0666
0.0673
0.0601
Delta BHC
0.0666
0.0623
0.0550
Gamma BHC
0.0666
0.0613
0.0545
4,4-DDD
0.0666
0.0626
0.0561
4,4-DDE
0.0666
0.0637
0.0570
4,4-DDT
0.0666
0.0660
0.0584
Dieldrin
0.0666
0.0723
0.0646
Endosulfan 1
0.0666
0.0711
0.0591
ACCOUNT:
Hart and Hickman, PC
LCS Rec.
LCSD Rec.
Rec. Limits
LCS Qualifier LCSD Qualifier RPD
RPD Limits
108
96.5
34.0-136
11.3
38
96.1
85.3
34.0-139
11.9
38
101
90.2
34.0-133
11.3
37
93.5
82.6
34.0-135
12.4
38
92.0
81.8
34.0-136
11.7
38
94.0
84.2
33.0-141
11.0
39
95.6
85.6
34.0-134
11.1
38
99.1
87.7
30.0-143
12.2
40
109
97.0
35.0-137
11.2
37
107
88.7
34.0-134
18.4
37
PROJECT:
SDG:
DATE/TIME: PAGE:
LVL-001
L1058027
01/17/19 15:18 66 of 84
FP1
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WG1219182 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE.
Pesticides (GC) by Method 8081B L1058027-01,02
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3374450-2 01/07/1917:51 • (LCSD) R3374450-3 01/07/1918:03
Spike Amount
LCS Result
LCSD Result
LCS Rec.
LCSD Rec.
Rec. Limits
LCS Qualifier LCSD Qualifier RPD
RPD Limits
Analyte
mg/kg
mg/kg
mg/kg
%
%
%
%
Endosulfan II
0.0666
0.0688
0.0614
103
92.2
35.0-132
11.4
38
Endosulfan sulfate
0.0666
0.0757
0.0679
114
102
35.0-132
10.9
37
Endrin
0.0666
0.0634
0.0483
95.2
72.5
34.0-137
27.0
37
Endrin aldehyde
0.0666
0.0556
0.0440
83.5
66.1
23.0-121
23.3
39
Endrin ketone
0.0666
0.0727
0.0656
109
98.5
35.0-144
10.3
37
Heptachlor
0.0666
0.0658
0.0588
98.8
88.3
36.0-141
11.2
37
Heptachlor epoxide
0.0666
0.0740
0.0663
ill
99.5
36.0-134
11.0
37
Hexachlorobenzene
0.0666
0.0661
0.0586
99.2
88.0
33.0-129
12.0
37
Methoxychlor
0.0666
0.0748
0.0686
112
103
28.0-150
8.65
38
(S) Decachlorobipheny/
104
93.8
10.0-135
(S) Tetrach/oro-m-xylene
107
94.1
10.0-139
L1057628-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1057628-01 01/07/19 19:31 • (MS) R3374450-4 01/07/1919:44 • (MSD) R3374450-5 01/07/1919:56
Spike Amount
Original Result
MS Result (dry)
MSD Result MS Rec.
MSD Rec.
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD
RPD Limits
(dry)
(dry)
(dry)
Analyte
mg/kg
mg/kg
mg/kg
mg/kg
%
%
%
%
%
Aldrin
0.0703
U
0.0757
0.0703
108
101
1 20.0-135
7.41
37
Alpha BHC
0.0703
U
0.0724
0.0685
103
98.0
1 27.0-140
5.57
35
Beta BHC
0.0703
U
0.0761
0.0719
108
103
1 23.0-141
5.73
37
Delta BHC
0.0703
U
0.0706
0.0669
100
95.8
1 21.0-138
5.40
35
Gamma BHC
0.0703
U
0.0697
0.0657
99.1
94.1
1 27.0-137
5.79
36
4,4-DDD
0.0703
U
0.0661
0.0609
94.0
87.1
1 15.0-152
8.19
39
4,4-DDE
0.0703
U
0.0665
0.0612
94.6
87.6
1 10.0-152
8.31
40
4,4-DDT
0.0703
U
0.0680
0.0621
96.7
88.9
1 10.0-151
8.96
40
Dieldrin
0.0703
U
0.0777
0.0722
ill
103
1 17.0-145
7.36
37
Endosulfan)
0.0703
U
0.0759
0.0716
108
102
1 20.0-137
5.90
36
Endosulfan II
0.0703
U
0.0755
0.0702
107
100
1 15.0-141
7.28
37
Endosulfan sulfate
0.0703
U
0.0844
0.0787
120
113
1 15.0-143
7.02
38
Endrin
0.0703
U
0.0656
0.0632
93.4
90.4
1 19.0-143
3.79
37
Endrin aldehyde
0.0703
U
0.0667
0.0645
94.9
92.3
1 10.0-139
3.40
40
Endrin ketone
0.0703
U
0.0811
0.0757
115
108
1 17.0-149
6.90
38
Heptachlor
0.0703
U
0.0693
0.0647
98.6
92.6
1 22.0-138
6.96
37
Heptachlor epoxide
0.0703
U
0.0799
0.0744
114
107
1 22.0-138
7.14
36
Hexachlorobenzene
0.0703
U
0.0711
0.0665
101
95.1
1 25.0-126
6.78
35
Methoxychlor
0.0703
U
0.0786
0.0719
112
103
1 10.0-159
8.88
40
(S) Decachlorobipheny/
107
101
10.0-135
(S) Tetrach/oro-m-xylene
ill
107
10.0-139
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
PAGE:
Hart
and Hickman, PC
LVL-001
L1058027
01/17/19 15:18
67 of 84
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WG1219731 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE.
Pesticides (GC) by Method 8081B 1-1058027-03,05
Method Blank (MB)
(MB) R3374941-3 01/09/1910:24
MB Result
Analyte
ug/I
Aldrin
U
Alpha BHC
U
Beta BHC
U
Delta BHC
U
Gamma BHC
U
4,4-DDD
U
4,4-DDE
U
4,4-DDT
U
Dieldrin
U
Endosulfan I
U
Endosulfan II
U
Endosulfan sulfate
U
Endrin
U
Endrin aldehyde
U
Endrin ketone
U
Heptachlor
U
Heptachlor epoxide
U
Hexachlorobenzene
U
Methoxychlor
U
Chlordane
U
Toxaphene
U
(S) Decochlorobipheny/
84.0
(S) Tetrach/oro-m-xylene
71.4
MB Qualifier MB MDL
ug/I
MB RDL
ug/I
0.00813
0.0500
0.0166
0.0500
0.0184
0.0500
0.0197
0.0500
0.0176
0.0500
0.0170
0.0500
0.0164
0.0500
0.0177
0.0500
0.00751
0.0500
0.0179
0.0500
0.0176
0.0500
0.0196
0.0500
0.0189
0.0500
0.0142
0.0500
0.0170
0.0500
0.0108
0.0500
0.0175
0.0500
0.0134
0.0500
0.0193
0.0500
0.0977
0.500
0.168
0.500
10.0-128
10.0-127
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3374941-1 01/09/19 09:59 • (LCSD) R3374941-2 01/09/1910:11
Spike Amount LCS Result LCSD Result
Analyte ug/I ug/I ug/I
Aldrin
1.00
1.02
1.03
Alpha BHC
1.00
0.953
0.958
Beta BHC
1.00
1.02
1.04
Delta BHC
1.00
0.940
0.957
Gamma BHC
1.00
0.920
0.924
4,4-DDD
1.00
1.01
1.03
4,4-DDE
1.00
0.938
0.949
4,4-DDT
1.00
1.00
1.02
Dieldrin
1.00
1.11
1.13
Endosulfan 1
1.00
1.10
1.12
ACCOUNT:
Hart and Hickman, PC
LCS Rec.
LCSD Rec.
Rec. Limits
LCS Qualifier LCSD Qualifier RPD
RPD Limits
102
103
22.0-124
0.976
34
95.3
95.8
54.0-130
0.523
23
102
104
53.0-136
1.94
20
94.0
95.7
54.0-133
1.79
20
92.0
92.4
55.0-129
0.434
20
101
103
56.0-140
1.96
22
93.8
94.9
52.0-128
1.17
22
100
102
50.0-141
1.98
23
ill
113
59.0-133
1.79
20
110
112
57.0-131
1.80
20
PROJECT:
SDG:
DATE/TIME: PAGE:
LVL-001
L1058027
01/17/19 15:18 68 of 84
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WG1219731 QUALITY CONTROL SUMMARY
Pesticides (GC) by Method 8081B 1-1058027-03,05
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
ONE LAB. NATIONWIDE.
(LCS) R3374941-1 01/09/19 09:59 • (LCSD) R3374941-2 01/09/1910:11
Spike Amount
LCS Result
LCSD Result
LCS Rec.
LCSD Rec.
Rec. Limits
LCS Qualifier LCSD Qualifier RPD
RPD Limits
Analyte ug/I
ug/I
ug/I
%
%
%
%
Endosulfan II 1.00
1.09
1.11
109
ill
58.0-133
1.82
20
Endosulfan sulfate 1.00
1.21
1.23
121
123
58.0-133
1.64
21
Endrin 1.00
1.03
1.06
103
106
57.0-134
2.87
21
Endrin aldehyde 1.00
0.995
1.04
99.5
104
53.0-129
4.42
20
Endrin ketone 1.00
1.18
1.20
118
120
60.0-145
1.68
20
Heptachlor 1.00
0.955
0.964
95.5
96.4
27.0-132
0.938
31
Heptachlor epoxide 1.00
1.14
1.16
114
116
57.0-130
1.74
20
Hexachlorobenzene 1.00
0.930
0.929
93.0
92.9
30.0-114
0.108
30
Methoxychlor 1.00
1.18
1.23
118
123
54.0-155
4.15
24
(S) Decochlorobipheny/
99.3
101
10.0-128
(S) Tetrach/oro-m-xylene
89.8
86.8
10.0-127
ACCOUNT:
PROJECT:
SDG:
DATE/TIME: PAGE:
Hart and Hickman, PC
LVL-001
L1058027
01/17/19 15:18 69 of 84
FP1
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WG1219183 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 8270D 1-1058027-03,05
ONE LAB. NATIONWIDE.
Method Blank (MB)
(MB) R3373692-3 01/05/1910:18
MB Result
Analyte
ug/I
Acenaphthene
U
Acenaphthylene
U
Anthracene
U
Benzidine
U
Benzo(a)anth race ne
U
Benzo(b)fluoranthene
U
Benzo(k)fluoranthene
U
Benzo(g,h,i)perylene
U
Benzo(a)pyrene
U
Bis(2-chlorethoxy)methane
U
Bis(2-chloroethyl)ether
U
Bis(2-chloroisopropyl)ether
U
4-Bromophenyl-phenylether
U
2-Chloronaphthalene
U
4-Chlorophenyl-phenylether
U
Chrysene
U
Dibenz(a,h)anthracene
U
3,3-Dichlorobenzidine
U
2,4-Dinitrotoluene
U
2,6-Dinitrotoluene
U
Fluoranthene
U
Fluorene
U
Hexachlorobenzene
U
Hexachloro-1,3-butadiene
U
Hexachlorocyclopentadiene
U
Hexachloroethane
U
Indeno(1,2,3-cd)pyrene
U
Isophorone
U
Naphthalene
U
Nitrobenzene
U
n-Nitrosodimethyla mine
U
n-Nitrosodiphenylamine
U
n-Nitrosodi-n-propylamine
U
Phenanthrene
U
Benzylbutyl phthalate
U
Bis(2-ethylhexyl)phthalate
U
Di-n-butyl phthalate
U
Diethyl phthalate
U
Dimethyl phthalate
U
Di-n-octyl phthalate
U
MB Qualifier MB MDL
ug/I
MB RDL
ug/I
0.316
1.00
0.309
1.00
0.291
1.00
4.32
10.0
0.0975
1.00
0.0896
1.00
0.355
1.00
0.161
1.00
0.340
1.00
0.329
10.0
1.62
10.0
0.445
10.0
0.335
10.0
0.330
1.00
0.303
10.0
0.332
1.00
0.279
1.00
2.02
10.0
1.65
10.0
0.279
10.0
0.310
1.00
0.323
1.00
0.341
1.00
0.329
10.0
2.33
10.0
0.365
10.0
0.279
1.00
0.272
10.0
0.372
1.00
0.367
10.0
1.26
10.0
1.19
10.0
0.403
10.0
0.366
1.00
0.275
3.00
0.709
3.00
0.266
3.00
0.282
3.00
0.283
3.00
0.278
3.00
FP1
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FSS
[Cn]
FSr
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FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC LVL-001 L1058027 01/17/19 15:18 70 of 84

WG1219183 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 8270D 1-1058027-03,05
ONE LAB. NATIONWIDE.
Method Blank (MB)
(MB) R3373692-3 01/05/1910:18
MB Result
Analyte
ug/I
Pyrene
U
1,2,4-Trichlorobenzene
U
4-ChIoro-3-methyl phenol
U
2-Chlorophenol
U
2-Nitrophenol
U
4-Nitrophenol
U
Pentachlorophenol
U
Phenol
U
2,4,6-Trichlorophenol
U
2,4-Dichlorophenol
U
2,4-Dimethylphenol
U
4,6-Dinitro-2-methylphenol
U
2,4-Dinitrophenol
U
(S) Nitrobenzene-d5
42.5
(S) 2-Fluorobipheny/
44.2
(S) p-Terphenyl-d14
44.3
(S) Phenol-d5
179
(S) 2-F/uorophenol
30.9
(S)2,4,6-Tribromopheno/ 34.8
MB Qualifier
MB MDL
ug/I
0.330
0.355
0.263
0.283
0.320
2.01
0.313
0.334
0.297
0.284
0.264
2.62
3.25
MB RDL
ug/I
1.00
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0-127
10.0-130
10.0-128
10.0-120
10.0-120
10.0-155
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3373692-1 01/05/19 09:30 • (LCSD) R3373692-2 01/05/19 09:54
Spike Amount LCS Result LCSD Result LCS Rec.
Analyte ug/I ug/I ug/I %
Acenaphthene
50.0
26.7
27.1
53.4
Acenaphthylene
50.0
26.1
25.7
52.2
Anthracene
50.0
26.7
26.2
53.4
Benzidine
50.0
11.1
16.8
22.2
Benzo(a)anth race ne
50.0
25.6
25.2
51.2
Benzo(b)fluoranthene
50.0
27.0
26.5
54.0
Benzo(k)fluoranthene
50.0
26.9
26.1
53.8
Benzo(g,h,i)perylene
50.0
27.3
26.5
54.6
Benzo(a)pyrene
50.0
26.8
26.1
53.6
Bis(2-chlorethoxy)methane
50.0
23.9
23.5
47.8
Bis(2-chloroethyl)ether
50.0
25.7
25.3
51.4
Bis(2-chloroisopropyl)ether
50.0
24.9
25.2
49.8
4-Bromophenyl-phenylether
50.0
26.9
26.5
53.8
2-Chloronaphthalene
50.0
24.7
24.2
49.4
ACCOUNT:
Hart and Hickman, PC
LCSD Rec.
Rec. Limits
LCS Qualifier LCSD Qualifier RPD
RPD Limits
54.2
41.0-120
1.49
22
51.4
43.0-120
1.54
22
52.4
45.0-120
1.89
20
33.6
1.00-120
J3 40.9
36
50.4
47.0-120
1.57
20
53.0
46.0-120
1.87
20
52.2
46.0-120
3.02
21
53.0
48.0-121
2.97
20
52.2
47.0-120
2.65
20
47.0
33.0-120
1.69
24
50.6
23.0-120
1.57
33
50.4
28.0-120
1.20
31
53.0
45.0-120
1.50
20
48.4
37.0-120
2.04
25
PROJECT:
SDG:
DATE/TIME: PAGE:
LVL-001
L1058027
01/17/19 15:18 71 of 84
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WG1219183
QUALITY
CONTROL SUMMARY
ONE LAB. NATIONWIDE.
Semi Volatile Organic
Compounds
(GC/MS) by
Method 8270D
L1058027-03,05
Laboratory Control Sample (LCS) • Laboratory Control
Sample Duplicate (LCSD)
FP1(LCS)
R3373692-1 01/05/19 09:30 • (LCSD)
R3373692-2
01/05/19 09:54
Spike Amount
LCS Result
LCSD Result
LCS Rec. LCSD Rec.
Rec. Limits LCS Qualifier LCSD Qualifier
RPD
RPD Limits
Analyte
ug/I
ug/I
ug/I
%
%
%
%
%
z
TC
4-Chlorophenyl-phenylether
50.0
26.6
27.0
53.2
54.0
44.0-120
1.49
20
Chrysene
50.0
26.9
26.6
53.8
53.2
48.0-120
1.12
20
FSS
Dibenz(a,h)anthracene
50.0
28.0
27.4
56.0
54.8
47.0-120
2.17
20
3,3-Dichlorobenzidine
50.0
28.0
28.1
56.0
56.2
44.0-120
0.357
20
2,4-Dinitrotoluene
50.0
28.2
28.8
56.4
57.6
49.0-124
2.11
20
[Cn]
2,6-Dinitrotoluene
50.0
26.9
26.8
53.8
53.6
46.0-120
0.372
21
Fluoranthene
50.0
28.3
26.9
56.6
53.8
51.0-120
5.07
20
FSr
Fluorene
50.0
26.5
27.2
53.0
54.4
47.0-120
2.61
20
Hexachlorobenzene
50.0
26.7
26.7
53.4
53.4
44.0-120
0.000
20
Hexachloro-1,3-butadiene
50.0
21.3
21.0
42.6
42.0
19.0-120
1.42
32
Hexachlorocyclopentadiene
50.0
20.1
20.9
40.2
41.8
15.0-120
3.90
31
Hexachloroethane
50.0
22.0
21.9
44.0
43.8
15.0-120
0.456
37
GI
Indeno(1,2,3-cd)pyrene
50.0
27.3
26.8
54.6
53.6
49.0-122
1.85
20
Isophorone
50.0
24.9
24.3
49.8
48.6
36.0-120
2.44
23
Naphthalene
50.0
22.8
22.8
45.6
45.6
27.0-120
0.000
27
FAI
Nitrobenzene
50.0
25.1
24.8
50.2
49.6
27.0-120
1.20
29
n-Nitrosodimethyla mine
50.0
17.1
17.9
34.2
35.8
10.0-120
4.57
40
FSC
n-Nitrosodiphenylamine
50.0
27.5
27.0
55.0
54.0
47.0-120
1.83
20
n-Nitrosodi-n-propylamine
50.0
27.2
27.6
54.4
55.2
31.0-120
1.46
28
Phenanthrene
50.0
26.6
26.1
53.2
52.2
46.0-120
1.90
20
Benzylbutyl phthalate
50.0
27.9
27.9
55.8
55.8
43.0-121
0.000
20
Bis(2-ethylhexyl)phthalate
50.0
26.6
26.9
53.2
53.8
43.0-122
1.12
20
Di-n-butyl phthalate
50.0
28.9
28.5
57.8
57.0
49.0-121
1.39
20
Diethyl phthalate
50.0
28.1
28.6
56.2
57.2
48.0-122
1.76
20
Dimethyl phthalate
50.0
28.0
27.6
56.0
55.2
48.0-120
1.44
20
Di-n-octyl phthalate
50.0
28.0
27.7
56.0
55.4
42.0-125
1.08
20
Pyrene
50.0
28.9
27.0
57.8
54.0
47.0-120
6.80
20
1,2,4-Trichlorobenzene
50.0
21.6
21.7
43.2
43.4
24.0-120
0.462
29
4-Chloro-3-methylphenol
50.0
25.7
25.6
51.4
51.2
40.0-120
0.390
21
2-Chlorophenol
50.0
24.4
24.3
48.8
48.6
25.0-120
0.411
35
2,4-Dichlorophenol
50.0
25.3
25.6
50.6
51.2
36.0-120
1.18
26
2,4-Dimethylphenol
50.0
24.2
24.4
48.4
48.8
33.0-120
0.823
26
4,6-Dinitro-2-methylphenol
50.0
36.9
36.1
73.8
72.2
38.0-138
2.19
25
2,4-Dinitrophenol
50.0
33.7
34.6
67.4
69.2
10.0-120
2.64
39
2-Nitrophenol
50.0
26.9
26.8
53.8
53.6
31.0-120
0.372
29
4-Nitrophenol
50.0
11.9
12.1
23.8
24.2
10.0-120
1.67
33
Pentachlorophenol
50.0
33.9
32.8
67.8
65.6
23.0-120
3.30
25
Phenol
50.0
11.4
11.6
22.8
23.2
10.0-120
1.74
36
2,4,6-Trichlorophenol
50.0
27.7
27.8
55.4
55.6
42.0-120
0.360
23
(S) Nitrobenzene-d5
39.3
39.3
10.0-127
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
PAGE:
Hart
and Hickman, PC
LVL-001
L1058027
01/17/19 15:18
72 of 84

WG1219183 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 8270D L1058027-03,05
ONE LAB. NATIONWIDE.
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3373692-1 01/05/19 09:30 • (LCSD) R3373692-2 01/05/19 09:54
Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte ug/I ug/I ug/I % % % % %
(S) 2-Fluorobipheny/ 40.2 40.4 10.0-130
(S) p-Terphenyl-d14 42.9 40.5 10.0-128
(S) Phenol-d5 16.6 16.7 10.0-120
(S) 2-F/uorophenol 28.2 28.7 10.0-120
(S)2,4,6-Tribromopheno/ 41.6 41.5 10.0-155
L1058040-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1058040-01 01/05/1915:53 • (MS) R3373692-4 01/05/1916:16 • (MSD) R3373692-5 01/05/1916:40
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
ug/I
ug/I
ug/I
ug/I
%
%
Acenaphthene
50.0
U
25.0
27.5
50.0
55.0
Acenaphthylene
50.0
U
24.7
27.2
49.4
54.4
Anthracene
50.0
U
27.0
28.1
54.0
56.2
Benzidine
50.0
U
ND
ND
0.000
0.000
Benzo(a)anth race ne
50.0
U
26.9
26.8
53.8
53.6
Benzo(b)fluoranthene
50.0
U
28.6
27.5
57.2
55.0
Benzo(k)fluoranthene
50.0
U
27.9
29.0
55.8
58.0
Benzo(g,h,i)perylene
50.0
U
28.5
28.8
57.0
57.6
Benzo(a)pyrene
50.0
U
28.0
28.3
56.0
56.6
Bis(2-chlorethoxy)methane
50.0
U
21.8
24.2
43.6
48.4
Bis(2-chloroethyl)ether
50.0
U
24.2
26.8
48.4
53.6
Bis(2-chloroisopropyl)ether
50.0
U
23.1
26.4
46.2
52.8
4-Bromophenyl-phenylether
50.0
U
25.6
28.3
51.2
56.6
2-Chloronaphthalene
50.0
U
23.1
25.3
46.2
50.6
4-Chlorophenyl-phenylether
50.0
U
25.8
29.5
51.6
59.0
Chrysene
50.0
U
28.5
28.5
57.0
57.0
Dibenz(a,h)anthracene
50.0
U
27.8
29.5
55.6
59.0
3,3-Dichlorobenzidine
50.0
U
16.9
15.9
33.8
31.8
2,4-Dinitrotoluene
50.0
U
29.3
30.6
58.6
61.2
2,6-Dinitrotoluene
50.0
U
26.3
28.4
52.6
56.8
Fluoranthene
50.0
U
28.6
29.3
57.2
58.6
Fluorene
50.0
U
25.9
29.6
51.8
59.2
Hexachlorobenzene
50.0
U
25.5
27.9
51.0
55.8
Hexachloro-1,3-butadiene
50.0
U
20.0
21.4
40.0
42.8
Hexachlorocyclopentadiene
50.0
U
18.2
20.8
36.4
41.6
Hexachloroethane
50.0
U
21.2
23.4
42.4
46.8
Indeno(1,2,3-cd)pyrene
50.0
U
27.2
28.8
54.4
57.6
Isophorone
50.0
U
22.2
25.6
44.4
51.2
Dilution Rec. Limits MS Qualifier MSD Qualifier
zo.u-ILu
31.0-121
36.0-120
1.00-120
39.0-120
37.0-120
37.0-120
37.0-123
37.0-120
17.0-120
14.0-120
18.0-120
37.0-120
29.0-120
36.0-120
38.0-120
36.0-121
10.0-134
39.0-125
36.0-120
41.0-121
37.0-120
35.0-122
12.0-120
10.0-120
10.0-120
38.0-125
21.0-120
J6 J6
RPD
RPD Limits
9.52
25
9.63
25
3.99
23
0.000
37
0.372
23
3.92
23
3.87
26
1.05
25
1.07
24
10.4
31
10.2
33
13.3
34
10.0
24
9.09
28
13.4
23
0.000
23
5.93
24
6.10
30
4.34
25
7.68
27
2.42
22
13.3
24
8.99
24
6.76
34
13.3
33
9.87
40
5.71
24
14.2
27
FP1
FTC
FSS
[Cn]
s
Sr
�GI
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC LVL-001 L1058027 01/17/19 15:18 73 of 84

WG1219183 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 8270D L1058027-03,05
ONE LAB. NATIONWIDE.
L1O58O40-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1058040-01 01/05/1915:53 • (MS) R3373692-4 01/05/1916:16 • (MSD) R3373692-5 01/05/1916:40
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Dilution Rec. Limits
Analyte
ug/I
ug/I
ug/I
ug/I
%
%
%
Naphthalene
50.0
U
21.0
23.2
42.0
46.4
1 10.0-120
Nitrobenzene
50.0
U
23.5
26.5
47.0
53.0
1 12.0-120
n-Nitrosodimethyla mine
50.0
U
16.3
18.5
32.6
37.0
1 10.0-120
n-Nitrosodiphenyla mine
50.0
U
27.0
29.4
54.0
58.8
1 37.0-120
n-Nitrosodi-n-propylamine
50.0
U
25.3
29.2
50.6
58.4
1 16.0-120
Phenanthrene
50.0
U
27.0
27.7
54.0
55.4
1 33.0-120
Benzylbutyl phthalate
50.0
U
32.7
30.8
65.4
61.6
1 34.0-126
Bis(2-ethylhexyl)phthalate
50.0
U
31.0
31.0
62.0
62.0
1 33.0-126
Di-n-butyl phthalate
50.0
U
31.2
32.1
62.4
64.2
1 35.0-128
Diethyl phthalate
50.0
U
28.6
30.4
57.2
60.8
1 39.0-125
Dimethyl phthalate
50.0
U
27.4
29.2
54.8
58.4
1 37.0-120
Di-n-octyl phthalate
50.0
U
32.6
32.1
65.2
64.2
1 25.0-135
Pyrene
50.0
U
30.6
28.9
61.2
57.8
1 39.0-120
1,2,4-Trichlorobenzene
50.0
U
20.2
21.8
40.4
43.6
1 15.0-120
4-ChIoro-3-methyl phenol
50.0
U
25.1
27.6
50.2
55.2
1 26.0-120
2-Chlorophenol
50.0
U
22.7
25.4
45.4
50.8
1 18.0-120
2,4-Dichlorophenol
50.0
U
23.9
26.7
47.8
53.4
1 19.0-120
2,4-Dimethylphenol
50.0
U
22.3
25.4
44.6
50.8
1 15.0-120
4,6-Dinitro-2-methylphenol
50.0
U
37.5
40.9
75.0
81.8
1 10.0-144
2,4-Dinitrophenol
50.0
U
38.0
42.1
76.0
84.2
1 10.0-120
2-Nitrophenol
50.0
U
24.0
28.0
48.0
56.0
1 20.0-120
4-Nitrophenol
50.0
U
13.6
14.0
27.2
28.0
1 10.0-120
Pentachlorophenol
50.0
U
36.8
38.1
73.6
76.2
1 10.0-128
Phenol
50.0
U
10.5
12.1
21.0
24.2
1 10.0-120
2,4,6-Trichlorophenol
50.0
U
27.7
30.7
55.4
61.4
1 26.0-120
(S) Nitrobenzene-d5
35.0
40.2
10.0-127
(S) 2-Fluorobiphenyl
38.5
42.8
10.0-130
(S) p-Terphenyl-d14
47.0
44.8
10.0-128
(S) Phenol-d5
15.7
18.5
10.0-120
(S) 2-F/uorophenol
26.2
29.3
10.0-120
(S) 2,4,6-Tribromopheno/
43.1
47.9
10.0-155
MS Qualifier MSD Qualifier RPD RPD Limits
9.95 31
12.0 30
12.6 40
8.51 24
14.3 30
2.56 22
5.98 24
0.000 25
2.84 23
6.10 24
6.36 24
1.55 26
5.71 22
7.62 31
9.49 27
11.2 34
11.1 27
13.0 28
8.67 39
10.2 40
15.4 30
2.90 40
3.47 37
14.2 40
10.3 31
FP1
FTc
FSS
[Cn]
FSr
�GI
FAI
[Sc
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC LVL-001 L1058027 01/17/19 15:18 74 of 84

WG1219730 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 8270D L1058027-01,02
ONE LAB. NATIONWIDE.
Method Blank (MB)
(MB) R3373751-3 01/06/1910:50
MB Result
Analyte
mg/kg
Acenaphthene
U
Acenaphthylene
U
Acetophenone
U
Anthracene
U
Azobenzene
U
Atrazine
U
Benzaldehyde
U
Benzidine
U
Benzo(a)anth race ne
U
Benzo(b)fluoranthene
U
Benzo(k)fluoranthene
U
Benzo(g,h,i)perylene
U
Benzo(a)pyrene
U
Biphenyl
U
Bis(2-chlorethoxy)methane
U
Bis(2-chloroethyl)ether
U
Bis(2-chloroisopropyl)ether
U
4-Bromophenyl-phenylether
U
Caprolactam
U
Carbazole
U
4-Chloroaniline
U
2-Chloronaphthalene
U
4-Chlorophenyl-phenylether
U
Chrysene
U
Dibenz(a,h)anthracene
U
Dibenzofuran
U
1,2-Dichlorobenzene
U
1,3-Dichlorobenzene
U
1,4-Dichlorobenzene
U
3,3-Dichlorobenzidine
U
2,4-Dinitrotoluene
U
2,6-Dinitrotoluene
U
Fluoranthene
U
Fluorene
U
Hexachlorobenzene
U
Hexachloro-1,3-butadiene
U
Hexachlorocyclopentadiene
U
Hexachloroethane
U
Indeno(1,2,3-cd)pyrene
U
Isophorone
U
MB Qualifier
MB MDL
mg/kg
0.00642
0.00671
0.0752
0.00632
0.00528
0.0938
0.0532
0.0637
0.00428
0.00695
0.00582
0.00721
0.00548
0.00588
0.00770
0.00896
0.00760
0.0114
0.104
0.00524
0.0352
0.00639
0.00627
0.00555
0.00821
0.00518
0.00921
0.0100
0.0100
0.0794
0.00607
0.00737
0.00496
0.00682
0.00856
0.0100
0.0587
0.0134
0.00772
0.00522
MB RDL
mg/kg
0.0333
0.0333
0.333
0.0333
0.333
0.333
0.333
0.333
0.0333
0.0333
0.0333
0.0333
0.0333
0.333
0.333
0.333
0.333
0.333
0.333
0.333
0.333
0.0333
0.333
0.0333
0.0333
0.333
0.333
0.333
0.333
0.333
0.333
0.333
0.0333
0.0333
0.333
0.333
0.333
0.333
0.0333
0.333
FP1
FTC
FSS
4
Cn
FSr
�GI
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC LVL-001 L1058027 01/17/19 15:18 75 of 84

WG1219730 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 8270D L1058027-01,02
ONE LAB. NATIONWIDE.
Method Blank (MB)
(MB) R3373751-3 01/06/1910:50
MB Result
Analyte
mg/kg
2-Methylnaphthalene
U
Naphthalene
U
2-Nitroaniline
U
3-Nitroaniline
U
4-Nitroaniline
U
Nitrobenzene
U
n-Nitrosodimethyla mine
U
n-Nitrosodiphenyla mine
U
n-Nitrosodi-n-propylamine
U
Phenanthrene
U
Benzylbutyl phthalate
U
Bis(2-ethylhexyl)phthalate
U
Di-n-butyl phthalate
U
Diethyl phthalate
U
Dimethyl phthalate
U
Di-n-octyl phthalate
U
Pyrene
U
1,2,4-Trichlorobenzene
U
Benzyl Alcohol
U
4-ChIoro-3-methyl phenol
U
2-Chlorophenol
U
2-Methylphenol
U
3&4-Methyl Phenol
U
2,4-Dichlorophenol
U
2,4-Dimethylphenol
U
4,6-Dinitro-2-methylphenol
U
2,4-Dinitrophenol
U
2-Nitrophenol
U
4-Nitrophenol
U
Pentachlorophenol
U
Phenol
U
2,4,5-Trichlorophenol
U
2,4,6-Trichlorophenol
U
(S) Nitrobenzene-d5
58.9
(S) 2-Fluorobiphenyl
58.0
(S) p-Terphenyl-dM
61.6
(S) Phenol-d5
56.3
(S) 2-F/uorophenol
63.8
(S)2,4,6-Tribromopheno/
57.8
MB Qualifier MB MDL
mg/kg
MB RDL
mg/kg
0.00861
0.0333
0.00889
0.0333
0.00755
0.333
0.00850
0.333
0.00639
0.333
0.00695
0.333
0.0647
0.333
0.0900
0.333
0.00906
0.333
0.00528
0.0333
0.0103
0.333
0.0120
0.333
0.0109
0.333
0.00691
0.333
0.00540
0.333
0.00907
0.333
0.0123
0.0333
0.00876
0.333
0.00750
0.333
0.00477
0.333
0.00831
0.333
0.00986
0.333
0.00783
0.333
0.00746
0.333
0.0471
0.333
0.124
0.333
0.0980
0.333
0.0130
0.333
0.0525
0.333
0.0480
0.333
0.00695
0.333
0.0104
0.333
0.00779
0.333
10.0-122
15.0-120
10.0-120
10.0-120
12.0-120
10.0-127
FP1
FTC
FSS
4
Cn
FSr
�GI
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC LVL-001 L1058027 01/17/19 15:18 76 of 84

WG1219730
QUALITY
CONTROL
SUMMARY
ONE LAB. NATIONWIDE.
Semi Volatile Organic
Compounds
(GC/MS) by
Method 8270D
L1058027-01,02
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
Cp
(LCS) R3373751-1 01/06/1910:03 • (LCSD) R3373751-2
01/06/1910:27
Spike Amount
LCS Result
LCSD Result
LCS Rec. LCSD Rec.
Rec. Limits LCS Qualifier LCSD Qualifier
RPD
RPD Limits
Analyte
mg/kg
mg/kg
mg/kg
%
%
%
%
%
E
Acetophenone
0.666
0.450
0.407
67.6
61.1
29.0-120
10.0
27
Azobenzene
0.666
0.426
0.382
64.0
57.4
43.0-120
10.9
20
E
Acenaphthene
0.666
0.448
0.407
67.3
61.1
38.0-120
9.59
22
Atrazine
0.666
0.518
0.472
77.8
70.9
43.0-120
9.29
21
Acenaphthylene
0.666
0.448
0.405
67.3
60.8
40.0-120
10.1
22
FC n
Benzaldehyde
0.666
0.262
0.270
39.3
40.5
10.0-160
3.01
40
Anthracene
0.666
0.436
0.402
65.5
60.4
42.0-120
8.11
20
E
Benzidine
0.666
ND
ND
0.000
0.000
1.00-120 J4
J4
0.000
40
Biphenyl
0.666
0.432
0.392
64.9
58.9
39.0-120
9.71
24
Benzo(a)anth race ne
0.666
0.450
0.415
67.6
62.3
44.0-120
8.09
20
ce
Benzo(b)fluoranthene
0.666
0.474
0.418
71.2
62.8
43.0-120
12.6
22
Benzo(k)fluoranthene
0.666
0.465
0.429
69.8
64.4
44.0-120
8.05
21
FG I
Benzo(g,h,i)perylene
0.666
0.491
0.457
73.7
68.6
43.0-120
7.17
22
Benzo(a)pyrene
0.666
0.462
0.412
69.4
61.9
45.0-120
11.4
20
Caprolactam
0.666
0.564
0.533
84.7
80.0
38.0-120
5.65
20
FAI
Carbazole
0.666
0.480
0.443
72.1
66.5
48.0-120
8.02
20
4-Chloroaniline
0.666
0.296
0.288
44.4
43.2
18.0-120
2.74
25
E
Bis(2-chlorethoxy)methane
0.666
0.357
0.330
53.6
49.5
20.0-120
7.86
23
Bis(2-chloroethyl)ether
0.666
0.450
0.402
67.6
60.4
16.0-120
11.3
31
Bis(2-chloroisopropyl)ether
0.666
0.432
0.396
64.9
59.5
23.0-120
8.70
30
4-Bromophenyl-phenylether
0.666
0.469
0.439
70.4
65.9
40.0-120
6.61
21
Dibenzofuran
0.666
0.450
0.402
67.6
60.4
44.0-120
11.3
21
1,2-Dichlorobenzene
0.666
0.439
0.406
65.9
61.0
32.0-120
7.81
30
1,3-Dichlorobenzene
0.666
0.428
0.389
64.3
58.4
30.0-120
9.55
31
2-Chloronaphthalene
0.666
0.434
0.397
65.2
59.6
35.0-120
8.90
24
1,4-Dichlorobenzene
0.666
0.441
0.397
66.2
59.6
31.0-120
10.5
31
4-Chlorophenyl-phenylether
0.666
0.465
0.415
69.8
62.3
40.0-120
11.4
22
Chrysene
0.666
0.465
0.427
69.8
64.1
43.0-120
8.52
20
Dibenz(a,h)anthracene
0.666
0.472
0.429
70.9
64.4
44.0-120
9.54
22
3,3-Dichlorobenzidine
0.666
0.367
0.357
55.1
53.6
28.0-120
2.76
23
2,4-Dinitrotoluene
0.666
0.521
0.471
78.2
70.7
45.0-120
10.1
21
2,6-Dinitrotoluene
0.666
0.479
0.432
71.9
64.9
42.0-120
10.3
21
Fluoranthene
0.666
0.463
0.428
69.5
64.3
44.0-120
7.86
21
Fluorene
0.666
0.459
0.411
68.9
61.7
41.0-120
11.0
22
Hexachlorobenzene
0.666
0.471
0.437
70.7
65.6
39.0-120
7.49
21
2-Methylnaphthalene
0.666
0.366
0.344
55.0
51.7
34.0-120
6.20
22
Hexachloro-1,3-butadiene
0.666
0.402
0.384
60.4
57.7
15.0-120
4.58
28
Hexachlorocyclopentadiene
0.666
0.479
0.438
71.9
65.8
15.0-120
8.94
31
2-Nitroaniline
0.666
0.500
0.457
75.1
68.6
46.0-120
8.99
22
Hexachloroethane
0.666
0.447
0.400
67.1
60.1
17.0-120
11.1
31
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
PAGE:
Hart
and Hickman, PC
LVL-001
L1058027
01/17/19 15:18
77 of 84

WG1219730
QUALITY
CONTROL
SUMMARY
ONE LAB. NATIONWIDE.
Semi Volatile Organic
Compounds
(GC/MS) by
Method 8270D
L1058027-01,02
Laboratory Control Sample (LCS) • Laboratory Control
Sample Duplicate (LCSD)
FP1(LCS)
R3373751-1 01/06/1910:03 • (LCSD)
R3373751-2
01/06/1910:27
Spike Amount
LCS Result
LCSD Result
LCS Rec. LCSD Rec.
Rec. Limits LCS
Qualifier LCSD Qualifier
RPD
RPD Limits
Analyte
mg/kg
mg/kg
mg/kg
%
%
%
%
%
FTC
3-Nitroaniline
0.666
0.414
0.395
62.2
59.3
36.0-120
4.70
22
Indeno(1,2,3-cd)pyrene
0.666
0.473
0.436
71.0
65.5
45.0-120
8.14
21
FSS
4-Nitroaniline
0.666
0.455
0.451
68.3
67.7
36.0-120
0.883
23
Isophorone
0.666
0.358
0.338
53.8
50.8
23.0-120
5.75
23
Naphthalene
0.666
0.359
0.342
53.9
51.4
18.0-120
4.85
24
[Cn]
Nitrobenzene
0.666
0.370
0.354
55.6
53.2
17.0-120
4.42
26
n-Nitrosodimethyla mine
0.666
0.420
0.375
63.1
56.3
10.0-125
11.3
33
FSr
n-Nitrosodiphenyla mine
0.666
0.431
0.401
64.7
60.2
40.0-120
7.21
21
n-Nitrosodi-n-propylamine
0.666
0.453
0.404
68.0
60.7
26.0-120
11.4
27
Phenanthrene
0.666
0.430
0.402
64.6
60.4
42.0-120
6.73
20
Benzylbutyl phthalate
0.666
0.475
0.439
71.3
65.9
40.0-120
7.88
21
Bis(2-ethylhexyl)phthalate
0.666
0.470
0.493
70.6
74.0
41.0-120
4.78
21
7G1
Di-n-butyl phthalate
0.666
0.476
0.444
71.5
66.7
43.0-120
6.96
20
Diethyl phthalate
0.666
0.474
0.430
71.2
64.6
43.0-120
9.73
21
Benzyl Alcohol
0.666
0.290
0.261
43.5
39.2
10.0-120
10.5
33
FAI
Dimethyl phthalate
0.666
0.466
0.420
70.0
63.1
43.0-120
10.4
22
Di-n-octyl phthalate
0.666
0.494
0.459
74.2
68.9
40.0-120
7.35
21
FSC
Pyrene
0.666
0.448
0.407
67.3
61.1
41.0-120
9.59
21
2-Methylphenol
0.666
0.477
0.430
71.6
64.6
35.0-120
10.4
24
1,2,4-Trichlorobenzene
0.666
0.376
0.357
56.5
53.6
17.0-120
5.18
26
3&4-Methyl Phenol
0.666
0.516
0.475
77.5
71.3
42.0-120
8.27
25
4-ChIoro-3-methyl phenol
0.666
0.383
0.345
57.5
51.8
28.0-120
10.4
20
2-Chlorophenol
0.666
0.462
0.414
69.4
62.2
28.0-120
11.0
28
2,4-Dichlorophenol
0.666
0.386
0.363
58.0
54.5
25.0-120
6.14
21
2,4-Dimethylphenol
0.666
0.348
0.335
52.3
50.3
15.0-120
3.81
26
4,6-Dinitro-2-methylphenol
0.666
0.480
0.458
72.1
68.8
16.0-120
4.69
33
2,4,5-Trichlorophenol
0.666
0.399
0.369
59.9
55.4
38.0-120
7.81
24
2,4-Dinitrophenol
0.666
0.340
0.338
51.1
50.8
10.0-120
0.590
40
2-Nitrophenol
0.666
0.418
0.395
62.8
59.3
20.0-120
5.66
25
4-Nitrophenol
0.666
0.458
0.418
68.8
62.8
27.0-120
9.13
24
Pentachlorophenol
0.666
0.411
0.391
61.7
58.7
29.0-120
4.99
25
Phenol
0.666
0.428
0.385
64.3
57.8
28.0-120
10.6
27
2,4,6-Trichlorophenol
0.666
0.434
0.392
65.2
58.9
37.0-120
10.2
24
(S) Nitrobenzene-d5
56.8
51.7
10.0-122
(S) 2-Fluorobiphenyl
67.3
60.1
15.0-120
(S) p-Terphenyl-d14
70.0
61.9
10.0-120
(S) Phenol-d5
68.3
58.7
10.0-120
(S) 2-F/uorophenol
76.0
65.8
12.0-120
(S)2,4,6-Tribromopheno/
71.3
64.9
10.0-127
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
PAGE:
Hart
and Hickman, PC
LVL-001
L1058027
01/17/19 15:18
78 of 84

WG1219730 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 8270D L1058027-01,02
ONE LAB. NATIONWIDE.
L1O58O41-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1058041-02 01/06/1913:10 • (MS) R3373751-4 01/06/1913:33 • (MSD) R3373751-5 01/06/1913:57
Spike Amount
Original Result
MS Result
MSD Result MS Rec.
MSD Rec.
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD
RPD Limits
Analyte
mg/kg
mg/kg
mg/kg
mg/kg
%
%
%
%
%
Acetophenone
0.666
ND
0.226
0.337
33.9
50.6
1 10.0-120
J3
39.4
37
Azobenzene
0.666
ND
0.282
0.333
42.3
50.0
1 18.0-120
16.6
27
Atrazine
0.666
ND
0.476
0.452
71.5
67.9
1 20.0-131
5.17
28
Benzaldehyde
0.666
ND
0.227
0.331
34.1
49.7
1 10.0-160
37.3
40
Acenaphthene
0.666
ND
0.253
0.349
38.0
52.4
1 18.0-120
31.9
32
Acenaphthylene
0.666
ND
0.253
0.344
38.0
51.7
1 25.0-120
30.5
32
Biphenyl
0.666
ND
0.230
0.329
34.5
49.4
1 15.0-120
J3
35.4
33
Anthracene
0.666
ND
0.357
0.376
53.6
56.5
1 22.0-120
5.18
29
Caprolactam
0.666
ND
0.479
0.492
71.9
73.9
1 11.0-141
2.68
31
Carbazole
0.666
ND
0.437
0.422
65.6
63.4
1 31.0-120
3.49
24
4-Chloroaniline
0.666
ND
0.190
0.240
28.5
36.0
1 10.0-120
23.3
36
Benzidine
0.666
ND
ND
ND
0.000
0.000
1 1.00-120
J6 J6
0.000
40
Benzo(a)anth race ne
0.666
ND
0.408
0.389
61.3
58.4
1 25.0-120
4.77
29
Benzo(b)fluoranthene
0.666
ND
0.400
0.375
60.1
56.3
1 19.0-122
6.45
31
Benzo(k)fluoranthene
0.666
ND
0.420
0.401
63.1
60.2
1 23.0-120
4.63
30
Benzo(g,h,i)perylene
0.666
ND
0.390
0.389
58.6
58.4
1 10.0-120
0.257
33
Benzo(a)pyrene
0.666
ND
0.406
0.387
61.0
58.1
1 24.0-120
4.79
30
Dibenzofuran
0.666
ND
0.267
0.344
40.1
51.7
1 24.0-120
25.2
30
1,2-Dichlorobenzene
0.666
ND
0.211
0.336
31.7
50.5
1 10.0-120
J3
45.7
38
1,3-Dichlorobenzene
0.666
ND
0.201
0.316
30.2
47.4
1 10.0-120
J3
44.5
40
Bis(2-chlorethoxy)methane
0.666
ND
0.194
0.274
29.1
41.1
1 10.0-120
J3
34.2
34
1,4-Dichlorobenzene
0.666
ND
0.207
0.325
31.1
48.8
1 10.0-120
J3
44.4
39
Bis(2-chloroethyl)ether
0.666
ND
0.217
0.332
32.6
49.8
1 10.0-120
J3
41.9
40
Bis(2-chloroisopropyl)ether
0.666
ND
0.209
0.319
31.4
47.9
1 10.0-120
J3
41.7
40
4-Bromophenyl-phenylether
0.666
ND
0.342
0.393
51.4
59.0
1 27.0-120
13.9
30
2-Chloronaphthalene
0.666
ND
0.232
0.329
34.8
49.4
1 20.0-120
J3
34.6
32
4-Chlorophenyl-phenylether
0.666
ND
0.290
0.368
43.5
55.3
1 24.0-120
23.7
29
Chrysene
0.666
ND
0.419
0.398
62.9
59.8
1 21.0-120
5.14
29
Dibenz(a,h)anthracene
0.666
ND
0.404
0.398
60.7
59.8
1 10.0-120
1.50
32
2-Methylnaphthalene
0.666
ND
0.200
0.288
30.0
43.2
1 10.0-120
36.1
37
3,3-Dichlorobenzidine
0.666
ND
0.236
0.216
35.4
32.4
1 10.0-120
8.85
34
2,4-Dinitrotoluene
0.666
ND
0.423
0.430
63.5
64.6
1 30.0-120
1.64
31
2-Nitroaniline
0.666
ND
0.341
0.400
51.2
60.1
1 24.0-120
15.9
30
2,6-Dinitrotoluene
0.666
ND
0.333
0.394
50.0
59.2
1 25.0-120
16.8
31
3-Nitroaniline
0.666
ND
0.354
0.365
53.2
54.8
1 11.0-120
3.06
32
4-Nitroaniline
0.666
ND
0.523
0.487
78.5
73.1
1 15.0-120
7.13
31
Fluoranthene
0.666
ND
0.422
0.408
63.4
61.3
1 18.0-126
3.37
32
Fluorene
0.666
ND
0.295
0.363
44.3
54.5
1 25.0-120
20.7
30
Hexachlorobenzene
0.666
ND
0.353
0.397
53.0
59.6
1 27.0-120
11.7
28
Hexachloro-1,3-butadiene
0.666
ND
0.211
0.309
31.7
46.4
1 10.0-120
37.7
38
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
PAGE:
Hart
and Hickman, PC
LVL-001
L1058027
01/17/19 15:18
79 of 84
FP1
FTc
FSS
[Cn]
FSr
�GI
FAI
[Sc

WG1219730
QUALITY
CONTROL
SUMMARY
ONE LAB. NATIONWIDE.
Semi Volatile Organic
Compounds
(GC/MS) by Method 8270D
L1058027-01,02
L1O58O41-02 Original Sample
(OS) • Matrix
Spike (MS)
• Matrix Spike Duplicate
(MSD)
FP1
(OS) L1058041-02 01/06/1913:10 • (MS) R3373751-4 01/06/1913:33 • (MSD)
R3373751-5 01/06/1913:57
Spike Amount
Original Result
MS Result
MSD Result MS Rec.
MSD Rec. Dilution
Rec. Limits MS Qualifier
MSD Qualifier RPD
RPD Limits
Analyte
mg/kg
mg/kg
mg/kg
mg/kg
%
%
%
%
%
TC
Hexachlorocyclopentadiene
0.666
ND
0.169
0.263
25.4
39.5 1
10.0-120
J3
43.5
40
Hexachloroethane
0.666
ND
0.204
0.318
30.6
47.7 1
10.0-120
J2
43.7
40
FSS
Indeno(1,2,3-cd)pyrene
0.666
ND
0.406
0.392
61.0
58.9 1
10.0-120
3.51
32
Isophorone
0.666
ND
0.199
0.283
29.9
42.5 1
13.0-120
J3
34.9
34
4
Naphthalene
0.666
ND
0.198
0.286
29.7
42.9 1
10.0-120
J3
36.4
35
Cn
Nitrobenzene
0.666
ND
0.199
0.288
29.9
43.2 1
10.0-120
J3
36.6
36
n-Nitrosodimethyla mine
0.666
ND
0.177
0.303
26.6
45.5 1
10.0-127
J3
52.5
40
FSr
Benzyl Alcohol
0.666
ND
0.0687
0.0762
10.3
11.4 1
10.0-136
10.4
40
n-Nitrosodiphenyla mine
0.666
ND
0.287
0.317
43.1
47.6 1
17.0-120
9.93
29
n-Nitrosodi-n-propylamine
0.666
ND
0.223
0.335
33.5
50.3 1
10.0-120
J3
40.1
37
Phenanthrene
0.666
ND
0.351
0.369
52.7
55.4 1
17.0-120
5.00
31
2-Methylphenol
0.666
ND
0.253
0.362
38.0
54.4 1
11.0-120
35.4
40
7G1
Benzylbutyl phthalate
0.666
ND
0.434
0.414
65.2
62.2 1
23.0-120
4.72
30
3&4-Methyl Phenol
0.666
ND
0.259
0.370
38.9
55.6 1
12.0-123
35.3
38
Bis(2-ethylhexyl)phthalate
0.666
ND
0.439
0.413
65.9
62.0 1
17.0-126
6.10
30
FAI
Di-n-butyl phthalate
0.666
ND
0.450
0.427
67.6
64.1 1
30.0-120
5.25
29
Diethyl phthalate
0.666
ND
0.384
0.399
57.7
59.9 1
26.0-120
3.83
28
[Sc
Dimethyl phthalate
0.666
ND
0.321
0.372
48.2
55.9 1
25.0-120
14.7
29
Di-n-octyl phthalate
0.666
ND
0.478
0.451
71.8
67.7 1
21.0-123
5.81
29
Pyrene
0.666
ND
0.392
0.382
58.9
57.4 1
16.0-121
2.58
32
1,2,4-Trichlorobenzene
0.666
ND
0.204
0.300
30.6
45.0 1
12.0-120
J3
38.1
37
2,4,5-Trichlorophenol
0.666
ND
0.281
0.333
42.2
50.0 1
20.0-120
16.9
30
4-ChIoro-3-methyl phenol
0.666
ND
0.242
0.289
36.3
43.4 1
15.0-120
17.7
30
2-Chlorophenol
0.666
ND
0.230
0.335
34.5
50.3 1
15.0-120
J3
37.2
37
2,4-Dichlorophenol
0.666
ND
0.229
0.309
34.4
46.4 1
20.0-120
29.7
31
2,4-Dimethylphenol
0.666
ND
0.186
0.255
27.9
38.3 1
10.0-120
31.3
33
4,6-Dinitro-2-methylphenol
0.666
ND
0.252
0.298
37.8
44.7 1
10.0-120
16.7
39
2,4-Dinitrophenol
0.666
ND
0.132
0.224
19.8
33.6 1
10.0-121
J3
51.7
40
2-Nitrophenol
0.666
ND
0.228
0.327
34.2
49.1 1
12.0-120
35.7
39
4-Nitrophenol
0.666
ND
0.436
0.404
65.5
60.7 1
10.0-137
7.62
32
Pentachlorophenol
0.666
ND
0.415
0.392
62.3
58.9 1
10.0-160
5.70
31
Phenol
0.666
ND
0.212
0.307
31.8
46.1 1
12.0-120
36.6
38
2,4,6-Trichlorophenol
0.666
ND
0.253
0.325
38.0
48.8 1
19.0-120
24.9
32
(S) Nitrobenzene-d5
30.3
42.9
10.0-122
(S) 2-Fluorobiphenyl
35.4
49.8
15.0-120
(S) p-Terphenyl-dM
60.7
57.1
10.0-120
(S) Phenol-d5
33.5
47.7
10.0-120
(S) 2-F/uorophenol
36.5
53.5
12.0-120
(S)2,4,6-Tribromopheno/
56.3
58.6
10.0-127
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
PAGE:
Hart
and Hickman, PC
LVL-001
L1058027
01/17/19 15:18
80 of 84

GLOSSARY OF TERMS
Guide to Reading and Understanding Your Laboratory Report
ONE LAB. NATIONWIDE.
The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not
intended as a comprehensive explanation, and if you have additional questions please contact your project representative.
and Definitions
CP
IP
FTCAbbreviations
(dry)
Results are reported based on the dry weight of the sample. [this will only be present on a dry report basis for soils].
MDL
Method Detection Limit.
FS
MDL (dry)
Method Detection Limit.
ND
Not detected at the Reporting Limit (or MDL where applicable).
RDL
Reported Detection Limit.
[Cn]
RDL (dry)
Reported Detection Limit.
Rec.
Recovery.
Fr
RPD
Relative Percent Difference.
SDG
Sample Delivery Group.
Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and
PC
(S)
Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be
detected in all environmental media.
U
Not detected at the Reporting Limit (or MDL where applicable).
Analyte
The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes
reported.
$
If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the
AI
Dilution
standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the
laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the
result reported has already been corrected for this factor.
FC
These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal
Limits
for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or
duplicated within these ranges.
Original Sample
The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control
sample. The Original Sample may not be included within the reported SDG.
This column provides a letter and/or number designation that corresponds to additional information concerning the result
Qualifier
reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and
potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable.
The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was
no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL"
Result
(Below Detectable Levels). The information in the results column should always be accompanied by either an MDL
(Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect
or report for this analyte.
Uncertainty
(Radiochemistry)
Confidence level of 2 sigma.
A brief discussion about the included sample results, including a discussion of any non -conformances to protocol
Case Narrative (Cn)
observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will
be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.
Quality Control
This section of the report includes the results of the laboratory quality control analyses required by procedure or
Summary (Qc)
analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not
being performed on your samples typically, but on laboratory generated material.
This is the document created in the field when your samples were initially collected. This is used to verify the time and
Sample Chain of
date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This
Custody (Sc)
chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the
samples from the time of collection until delivery to the laboratory for analysis.
This section of your report will provide the results of all testing performed on your samples. These results are provided
Sample Results (Sr)
by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for
each sample will provide the name and method number for the analysis reported.
Sample Summary (Ss)
This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and
times of preparation and/or analysis.
Qualifier
Description
B
The same analyte is found in the associated blank.
E
The analyte concentration exceeds the upper limit of the calibration range of the instrument established by the initial
calibration (ICAL).
J
The identification of the analyte is acceptable; the reported value is an estimate.
J1
Surrogate recovery limits have been exceeded; values are outside upper control limits.
J2
Surrogate recovery limits have been exceeded; values are outside lower control limits.
J3
The associated batch QC was outside the established quality control range for precision.
J4
The associated batch QC was outside the established quality control range for accuracy.
J5
The sample matrix interfered with the ability to make any accurate determination; spike value is high.
J6
The sample matrix interfered with the ability to make any accurate determination; spike value is low.
P
RPD between the primary and confirmatory analysis exceeded 40%.
ACCOUNT:
PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC
LVL-001 L1058027 01/17/19 15:18 81 of 84

ACCREDITATIONS & LOCATIONS ONE LAB. NATIONWIDE.
Pace National is the only environmental laboratory accredited/certified to support your work nationwide from one location. One phone call, one point of contact, one laboratory. No other lab is as
accessible or prepared to handle your needs throughout the country. Our capacity and capability from our single location laboratory is comparable to the collective totals of the network
laboratories in our industry. The most significant benefit to our one location design is the design of our laboratory campus. The model is conducive to accelerated productivity, decreasing FP1
turn -around time, and preventing cross contamination, thus protecting sample integrity. Our focus on premium quality and prompt service allows us to be YOUR LAB OF CHOICE.
Not all certifications held by the laboratory are applicable to the results reported in the attached report.
Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace National. Z
Tc
State Accreditations
f—�
Alabama
40660
Nebraska _
NE-OS-15-05
SS
Alaska
17-026
Nevada
TN-03-2002-34
Arizona
AZO612
New Hampshire
2975
Arkansas
88-0469
New Jersey_NELAP
TNO02
C n
California
2932
New Mexico
n/a
Colorado
TN00003
New York
11742
s
Connecticut
PH-0197
North Carolina
Env375
Sr
Florida
E87487
North Carolina'
DW21704
Georgia
NELAP
North Carolina'
41
Georgia'
923
North Dakota
R-140
RC
Idaho
TN00003
Ohio—VAP
CL0069
Illinois
200008
Oklahoma
9915
Indiana
C-TN-01
Oregon
TN200002
G
Iowa
364
Pennsylvania
68-02979
Kansas
E-10277
Rhode Island
LA000356
Kentucky76
90010
South Carolina
84004
Kentucky 2
16
South Dakota
n/a
Louisiana
A130792
Tennessee' 4
2006
Louisiana'
LA180010
Texas
T 104704245-17-14
[SC
Maine
TN0002
Texas'
LABO152
Maryland
324
Utah
Massachusetts
M-TNO03
Vermont
Michigan
9958
Virginia
Minnesota
047-999-395
Washington
Mississippi
TN00003
West Virginia
Missouri
340
Wisconsin
Montana
CERT0086
Wyoming
Third Party
Federal Accreditations
A21LA — ISO 17025
1461.01
AIHA-LAP,LLC EMLAP
A21LA — ISO 17025 5
1461.02
DOD
Canada
1461.01
USDA
EPA—Crypto
TN00003
' Drinking Water 'Underground
Storage Tanks 3 Aquatic Toxicity 4 Chemical/Microbiological 5 Mold
6 Wastewater n/a Accreditation not applicable
Our Locations
TN00003
VT2006
460132
C847
233
9980939910
A2LA
100789
1461.01
P330-15-00234
Pace National has sixty-four client support centers that provide sample pickup and/or the delivery of sampling supplies. If you would like assistance from one of our support offices, please contact
our main office. Pace National performs all testing at our central laboratory.
WA
ME
MT NO
OR MN
T ID t WI NY
SD
WY MI
NV
t NE IA OH PA
T f IL Ills WV
vA
UT T
CA�� T
KS MO KY
N
NM O� AR SC
T MS AL`7GA
T TX * LA
T
AK
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wo HI
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Hart and Hickman, PC LVL-001 L1058027 01/17/19 15:18 82 of 84

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Appendix C
February 2018 DEQ Risk Calculator Results
hart hickman
SMAKtER ENVIRONMENTAL SOLUTIONS

North Carolina Department of Environmental Quality
Risk Calculator
Version Date:
February 2018
Basis:
November 2017 EPA RSL Table
Site Name:
Former Witherspoon Nursery
Site Address:
3312 and 3330 Watkins Road, Durham, North Carolina
DEQ Section:
Brownfields
Site ID:
SB-2 (6-8')
Exposure Unit ID:
Submittal Date:
Prepared By:
Reviewed By:
North Carolina DEQ Risk Calculator

Complete Exposure Pathways
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: SB-2 (6-89)
Exposure Unit ID:
Note: Risk output will only be calculated for complete exposure pathways.
Receptor
Pathway
Check box if
pathway
complete
PRIMARY PATHWAYS
Resident
Soil Combined Pathways
[]
Groundwater Combined Pathways
❑
Non -Residential Worker
Soil Combined Pathways
0
Groundwater Combined Pathways
❑
Construction Worker
Soil Combined Pathways
0
User Defined
Soil Combined Pathways
❑
Surface Water Combined Pathways
❑
VAPOR INTRUSION PATHWAYS
Resident
Groundwater to Indoor Air
❑
Soil Gas to Indoor Air
❑
Indoor Air
❑
Non -Residential Worker
Groundwater to Indoor Air
❑
Soil Gas to Indoor Air
❑
Indoor Air
❑
CONTAMINANT MIGRATION PATHWAYS
Protection of Groundwater Use
Source Soil
❑
Source Groundwater
❑
Protection of Surface Water
Source Soil
❑
Source Groundwater
❑
North Carolina DEQ Risk Calculator

Point Concentrations
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: SB-2 (6-8')
Unit ID:
Surface Soil Exposure Point Concentration Table
Exposure Point
Minimum
Maximum
Location of
Concentration
Screening
Potential
Potential
COPC
Rationale for
Concentration
Justification for Exposure
CAS Number
Chemical
Concentration
Concentration
Units
Maximum
Detection
Range of
Used for
Background
Toxicity Value
ARAR/TBC
ARAR/TBC
Flag
Selection or
(mg/kg)
Point Concentration
(Qualifier)
(Qualifier)
Concentration
Frequency
Detection Limits
Screening
Value
(Screening
Value
Source
(Y/N)
Deletion
Level) (n/c)
1
7440-38-2
Arsenic, Inorganic
mg/kg
101
7440-39-3
Barium
mg/kg
0.422
7440-43-9
Cadmium (Diet)
mg/kg
20.4
16065-83-1
Chromium(III), Insoluble Salts
mg/kg
8.4
7439-92-1
Lead and Compounds
mg/kg
0.011
7439-97-6
Mercury (elemental)
mg/kg
0.385
7782-49-2
Selenium
mg/kg
North Carolina DEQ Risk Calculator

Point Concentrations
ersion Date: February 2018
November 2017 EPA RSL Table
Site ID: SB-2 (6-81)
Unit ID:
Subsurface Soil Exposure Point Concentration Table
Exposure Point
Minimum
Maximum
Location of
Concentration
Screening
Potential
Potential
COPC
Rationale for
Concentration
Justification for Exposure Point
CAS Number
Chemical
Concentration
Concentration
Units
Maximum
Detection
Range of
Used for
Background
Toxicity Value
ARAR/TBC
ARAR/TBC
Flag
Selection or
Concentration
Frequency
Detection Limits
Value
(Screening
(mg/kg)
(Qualifier)
(Qualifier)
Concentration
Screening
Level) (n/c)
Value
Source
(Y/N)
Deletion
1
7440-38-2
Arsenic, Inorganic
mg/kg
101
7440-39-3
Barium
mg/kg
0.422
7440-43-9
Cadmium (Diet)
mg/kg
20.4
16065-83-1
Chromium(III), Insoluble Salts
mg/kg
8.4
7439-92-1
Lead and Compounds
in k
0.011
7439-97-6
—Mercury (elemental)
mg/kg
0.385
7782-49-2
Selenium
mg/kg
North Carolina DEQ Risk Calculator

Summary of Risk Assessment Output
1 I -
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: SB-2 (6-8')
Exposure Unit ID:
PRIMARY CALCULATORS
Receptor
Pathway
CarcinogenicRisk
Hazard Index
Risk exceeded?
Resident
Soil Combined Pathways
1.5E-06
4.3E-02
NO
Groundwater Combined Pathways*
NC
NC
NC
Non -Residential Worker
Soil Combined Pathways
3.3E-07
3.2E-03
NO
Groundwater Combined Pathways*
NC
NC
NC
Construction Worker
Soil Combined Pathways
5.8E-08
4.2E-02
NO
User Defined
Soil Combined Pathways
NC
NC
NC
=NC
Surface Water Combined Pathways*
NC
NC
VAPOR INTRUSION CALCULATORS
Receptor
Pathway
Carcinogenic
Hazard Index
Risk exceeded?
Resident
Groundwater to Indoor Air
NC
NC
NC
Soil Gas to Indoor Air
NC
NC
NC
Indoor Air
NC
NC
NC
Non -Residential Worker
Groundwater to Indoor Air
NC
NC
NC
Soil Gas to Indoor Air
Indoor Air
NC
NC
NC
NC
NC
NC
CONTAMINANT MIGRATION CALCULATORS
Pathway
Source
Target POE Concentrations Exceeded?
Protection of Groundwater Use
Source Soil
Exceedence of 2L at POE?
NC
Source Groundwater
Exceedence of 2L at POE?
NC
Protection of Surface Water
Source Soil
Exceedence of 213 at POE?
NC
Source Groundwater
Exceedence of 213 at POE?
NC
Notes:
1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for
lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations.
2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed
the NC 213 Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a
risk -based closure.
North Carolina DEQ Risk Calculator

North Carolina DEQ Risk Calculator

North Carolina DEQ Risk Calculator

DEQ Risk Calculator - Primary - Construction Worker Soil Combined Pathways
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: SB-2 (6-8')
Exposure Unit ID:
* - Note that inhalation on this calculator refers to outdoor inhalation of volatiles and particulates, not indoor inhalation associated with vapor intrusion.
* * - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate cancer risk or hazard quotient. Lead concentrations are compared to the EPA screening level of 800 mg/kg
for commercial/industrial soil.
CAS #
Chemical Name:
Ingestion
Concentration
(mg/kg)
Dermal
Concentration
(mg/kg)
Inhalation
Concentration
(mg/kg)*
Ingestion
Carcinogenic
Risk
Dermal
Carcinogenic
Risk
Inhalation
Carcinogenic
Risk
Calculated
Carcinogenic
Risk
Ingestion
Hazard
Quotient
Dermal
Hazard
Quotient
Inhalation
Hazard
Quotient
Calculated
Non -
Carcinogenic
Hazard
Quotient
7440-38-2
Arsenic, Inorganic
1
1
1
3.6E-08
5.8E-09
1.3E-08
5.5E-08
5.9E-03
9.4E-04
1.5E-02
2.2E-02
7440-39-3
Barium
101
101
101
1.5E-03
4.5E-03
6.0E-03
7440-43-9
Cadmium (Diet)
0.422
0.422
0.422
2.3E-09
2.3E-09
2.5E-03
3.2E-04
9.5E-03
1.2E-02
16065-83-1
Chromium(III), Insoluble Salts
20.4
20.4
20.4
4.0E-05
9.2E-04
9.6E-04
7439-92-1
Lead and Compounds
8.4
8.4
8.4
<SL**
<SL**
<SL**
7439-97-6
Mercury (elemental)
0.011
0.011
0.011
1.1E-03
1.1E-03
7782-49-2
Selenium
1 0.385
0.385
0.385
2.3E-04
4.3E-06
2.3E-04
Cumulative:
5.8E-08
4.2E-02
North Carolina DEQ Risk Calculator

North Carolina Department of Environmental Quality
Risk Calculator
Version Date:
February 2018
Basis:
November 2017 EPA RSL Table
Site Name:
Former Witherspoon Nursery
Site Address:
3312 and 3330 Watkins Road, Durham, North Carolina
DEQ Section:
Brownfields
Site ID:
DUP-SB (SB-2 [6-8'] Duplicate)
Exposure Unit ID:
Submittal Date:
Prepared By:
Reviewed By:
North Carolina DEQ Risk Calculator

Complete Exposure Pathways
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: DUP-SB (SB-2 [6-8'] Duplicate)
Exposure Unit ID:
Note: Risk output will only be calculated for complete exposure pathways.
Receptor
Pathway
Check box if
pathway
complete
PRIMARY PATHWAYS
Resident
Soil Combined Pathways
[]
Groundwater Combined Pathways
❑
Non -Residential Worker
Soil Combined Pathways
0
Groundwater Combined Pathways
❑
Construction Worker
Soil Combined Pathways
0
User Defined
Soil Combined Pathways
❑
Surface Water Combined Pathways
❑
VAPOR INTRUSION PATHWAYS
Resident
Groundwater to Indoor Air
❑
Soil Gas to Indoor Air
❑
Indoor Air
❑
Non -Residential Worker
Groundwater to Indoor Air
❑
Soil Gas to Indoor Air
❑
Indoor Air
❑
CONTAMINANT MIGRATION PATHWAYSML
Protection of Groundwater Use
Source Soil
❑
Source Groundwater
❑
Protection of Surface Water
Source Soil
❑
Source Groundwater
❑
North Carolina DEQ Risk Calculator

Point Concentrations
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: DUP-SB (SB-2 [6-8'] Duplicate)
Exposure Unit ID:
Surface Soil Exposure Point Concentration Table
Exposure Point
Minimum
Maximum
Location of
Concentration
Screening
Potential
Potential
COPC
Rationale for
Concentration
Justification for Exposure
CAS Number
Chemical
Concentration
Concentration
Units
Maximum
Detection
Range of
Used for
Background
Toxicity Value
ARAR/TBC
ARAR/TBC
Flag
Selection or
(mg/kg)
Point Concentration
(Qualifier)
(Qualifier)
Concentration
Frequency
Detection Limits
Screening
Value
(Screening
Value
Source
(Y/N)
Deletion
Level) (n/c)
3.02
7440-38-2
Arsenic, Inorganic
mg/kg
127
7440-39-3
Barium
mg/kg
0.276
7440-43-9
Cadmium (Diet)
mg/kg
30.9
16065-83-1
Chromium(III), Insoluble Salts
mg/kg
11.9
7439-92-1
Lead and Compounds
mg/kg
0.0113
7439-97-6
Mercury (elemental)
mg/kg
0.559
7782-49-2
Selenium
mg/kg
North Carolina DEQ Risk Calculator

Point Concentrations
ersion Date: February 2018
November 2017 EPA RSL Table
Site ID: DUP-SB (SB-2 [6-8'] Duplicate)
Unit ID:
Subsurface Soil Exposure Point Concentration Table
Exposure Point
Minimum
Maximum
Location of
Concentration
Screening
Potential
Potential
COPC
Rationale for
Concentration
Justification for Exposure Point
CAS Number
Chemical
Concentration
Concentration
Units
Maximum
Detection
Range of
Used for
Background
Toxicity Value
ARAR/TBC
ARAR/TBC
Flag
Selection or
Concentration
Frequency
Detection Limits
Value
(Screening
(mg/kg)
(Qualifier)
(Qualifier)
Concentration
Screening
Level) (n/c)
Value
Source
(Y/N)
Deletion
3.02
7440-38-2
Arsenic, Inorganic
mg/kg
127
7440-39-3
Barium
mg/kg
0.276
7440-43-9
Cadmium (Diet)
mg/kg
30.9
16065-83-1
Chromium(III), Insoluble Salts
mg/kg
11.9
7439-92-1
Lead and Compounds
mg/kg
0.0113
7439-97-6
—Mercury (elemental)
mg/kg
0.559
7782-49-2
Selenium
mg/kg
North Carolina DEQ Risk Calculator

Summary of Risk Assessment Output
1 I -
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: DUP-SB (SB-2 [6-8'] Duplicate)
Exposure Unit ID:
PRIMARY CALCULATORS
Receptor
Pathway
CarcinogenicRisk
Hazard Index
Risk exceeded?
Resident
Soil Combined Pathways
4.5E-06
1.0E-01
NO
Groundwater Combined Pathways*
NC
NC
NC
Non -Residential Worker
Soil Combined Pathways
1.0E-06
7.4E-03
NO
Groundwater Combined Pathways*
NC
NC
NC
Construction Worker
Soil Combined Pathways
1.7E-07
8.4E-02
NO
User Defined
Soil Combined Pathways
NC
NC
NC
Surface Water Combined Pathways*
1 NC
I NC
NC
VAPOR INTRUSION CALCULATORS
Receptor
Pathway
Carcinogenic
Hazard Index
Risk exceeded?
Resident
Groundwater to Indoor Air
NC
NC
NC
Soil Gas to Indoor Air
NC
NC
NC
Indoor Air
NC
NC
NC
Non -Residential Worker
Groundwater to Indoor Air
NC
NC
NC
Soil Gas to Indoor Air
Indoor Air
NC
NC
NC
NC
NC
NC
CONTAMINANT MIGRATION CALCULATORS
Pathway
Source
Target POE Concentrations Exceeded?
Protection of Groundwater Use
Source Soil
Exceedence of 2L at POE?
NC
Source Groundwater
Exceedence of 2L at POE?
NC
Protection of Surface Water
Source Soil
Exceedence of 213 at POE?
NC
Source Groundwater
Exceedence of 2B at POE?
NC
Notes:
1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for
lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations.
2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed
the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a
risk -based closure.
North Carolina DEQ Risk Calculator

North Carolina DEQ Risk Calculator

North Carolina DEQ Risk Calculator

DEQ Risk Calculator - Primary - Construction Worker Soil Combined Pathways
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: DUP-SB (SB-2 [6-8']
Exposure Unit ID:
* - Note that inhalation on this calculator refers to outdoor inhalation of volatiles and particulates, not indoor inhalation associated with vapor intrusion.
* * - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate cancer risk or hazard quotient. Lead concentrations are compared to the EPA screening level of 800 mg/kg
for commercial/industrial soil.
CAS #
Chemical Name:
Ingestion
Concentration
(mg/kg)
Dermal
Concentration
(mg/kg)
Inhalation
Concentration
(mg/kg)*
Ingestion
Carcinogenic
Risk
Dermal
Carcinogenic
Risk
Inhalation
Carcinogenic
Risk
Calculated
Carcinogenic
Risk
Ingestion
Hazard
Quotient
Dermal
Hazard
Quotient
Inhalation
Hazard
Quotient
Calculated
Non -
Carcinogenic
Hazard
Quotient
7440-38-2
Arsenic, Inorganic
3.02
3.02
3.02
1.1E-07
1.8E-08
4.0E-08
1.7E-07
1.8E-02
2.9E-03
4.5E-02
6.6E-02
7440-39-3
Barium
127
127
127
1.9E-03
5.7E-03
7.6E-03
7440-43-9
Cadmium (Diet)
0.276
0.276
0.276
1.5E-09
1.5E-09
1.6E-03
2.1E-04
6.2E-03
8.0E-03
16065-83-1
Chromium(III), Insoluble Salts
30.9
30.9
30.9
6.1E-05
1.4E-03
1.4E-03
7439-92-1
Lead and Compounds
11.9
11.9
11.9
<SL**
<SL**
<SL**
7439-97-6
Mercury (elemental)
0.0113
0.0113
0.0113
1.1E-03
1.1E-03
7782-49-2
Selenium
0.559
0.559
0.559
1
1
1
3.3E-04
6.3E-06
3.4E-04
Cumulative:
1.7E-07
8.4E-02
North Carolina DEQ Risk Calculator

North Carolina Department of Environmental Quality
Risk Calculator
Version Date:
February 2018
Basis:
November 2017 EPA RSL Table
Site Name:
Former Witherspoon Nursery
Site Address:
3312 and 3330 Watkins Road, Durham, North Carolina
DEQ Section:
Brownfields
Site ID:
SED-1
Exposure Unit ID:
Submittal Date:
Prepared By:
Reviewed By:
North Carolina DEQ Risk Calculator

Complete Exposure Pathways
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: SED-1
Exposure Unit ID:
Note: Risk output will only be calculated for complete exposure pathways.
Receptor
Pathway
Check box if
pathway
complete
PRIMARY PATHWAYS
Resident
Soil Combined Pathways
[]
Groundwater Combined Pathways
❑
Non -Residential Worker
Soil Combined Pathways
0
Groundwater Combined Pathways
❑
Construction Worker
Soil Combined Pathways
0
User Defined
Soil Combined Pathways
❑
Surface Water Combined Pathways
❑
VAPOR INTRUSION PATHWAYS
Resident
Groundwater to Indoor Air
❑
Soil Gas to Indoor Air
❑
Indoor Air
❑
Non -Residential Worker
Groundwater to Indoor Air
❑
Soil Gas to Indoor Air
❑
Indoor Air
❑
CONTAMINANT MIGRATION PATHWAYS
Protection of Groundwater Use
Source Soil
❑
Source Groundwater
❑
Protection of Surface Water
Source Soil
❑
Source Groundwater
❑
North Carolina DEQ Risk Calculator

Point Concentrations
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: SED-1
Unit ID:
Surface Soil Exposure Point Concentration Table
Exposure Point
Minimum
Maximum
Location of
Concentration
Screening
Potential
Potential
COPC
Rationale for
Concentration
Justification for Exposure
CAS Number
Chemical
Concentration
Concentration
Units
Maximum
Detection
Range of
Used for
Background
Toxicity Value
ARAR/TBC
ARAR/TBC
Flag
Selection or
(mg/kg)
Point Concentration
(Qualifier)
(Qualifier)
Concentration
Frequency
Detection Limits
Screening
Value
(Screening
Value
Source
(Y/N)
Deletion
Level) (n/c)
4.39
7440-38-2
Arsenic, Inorganic
mg/kg
148
7440-39-3
Barium
mg/kg
36.6
16065-83-1
Chromium(III), Insoluble Salts
mg/kg
17.3
7439-92-1
Lead and Compounds
mg/kg
0.0103
7439-97-6
Mercury (elemental)
mg/kg
0.396
7782-49-2
Selenium
mg/kg
North Carolina DEQ Risk Calculator

Point Concentrations
ersion Date: February 2018
: November 2017 EPA RSL Table
Site ID: SED-1
Unit ID:
Subsurface Soil Exposure Point Concentration Table
Exposure Point
Minimum
Maximum
Location of
Concentration
Screening
Potential
Potential
COPC
Rationale for
Concentration
Justification for Exposure Point
CAS Number
Chemical
Concentration
Concentration
Units
Maximum
Detection
Range of
Used for
Background
Toxicity Value
ARAR/TBC
ARAR/TBC
Flag
Selection or
Concentration
Frequency
Detection Limits
Value
(Screening
(mg/kg)
(Qualifier)
(Qualifier)
Concentration
Screening
Level) (n/c)
Value
Source
(Y/N)
Deletion
4.39
7440-38-2
Arsenic, Inorganic
mg/kg
148
7440-39-3
Barium
mg/kg
36.6
16065-83-1
Chromium(III), Insoluble Salts
mg/kg
17.3
7439-92-1
Lead and Compounds
mg/kg
0.0103
7439-97-6
—Mercury (elemental)
mg/kg
0.396
7782-49-2
Selenium
mg/kg
North Carolina DEQ Risk Calculator

Summary of Risk Assessment Output
1 I -
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: SED-1
Exposure Unit ID:
PRIMARY CALCULATORS
Receptor
Pathway
CarcinogenicRisk
Hazard Index
Risk exceeded?
Resident
Soil Combined Pathways
6.5E-06
1.4E-01
NO
Groundwater Combined Pathways*
NC
NC
NC
Non -Residential Worker
Soil Combined Pathways
1.5E-06
1.0E-02
NO
Groundwater Combined Pathways*
NC
NC
NC
Construction Worker
Soil Combined Pathways
2.4E-07
1.1E-01
NO
User Defined
Soil Combined Pathways
NC
NC
NC
Surface Water Combined Pathways*
NC
NC
NC
VAPOR INTRUSION CALCULATORS
Receptor
Pathway
Carcinogenic
Hazard Index
Risk exceeded?
Resident
Groundwater to Indoor Air
NC
NC
NC
Soil Gas to Indoor Air
NC
NC
NC
Indoor Air
NC
NC
NC
Non -Residential Worker
Groundwater to Indoor Air
NC
NC
NC
Soil Gas to Indoor Air
Indoor Air
NC
NC
NC
NC
NC
NC
CONTAMINANT MIGRATION CALCULATORS
Pathway
Source
Target POE Concentrations Exceeded?
Protection of Groundwater Use
Source Soil
Exceedence of 2L at POE?
NC
Source Groundwater
Exceedence of 2L at POE?
NC
Protection of Surface Water
Source Soil
Exceedence of 213 at POE?
NC
Source Groundwater
Exceedence of 213 at POE?
NC
Notes:
1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for
lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations.
2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed
the NC 213 Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a
risk -based closure.
North Carolina DEQ Risk Calculator

North Carolina DEQ Risk Calculator

North Carolina DEQ Risk Calculator

DEQ Risk Calculator - Primary - Construction Worker Soil Combined Pathways
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: SED-1
Unit ID:
* - Note that inhalation on this calculator refers to outdoor inhalation of volatiles and particulates, not indoor inhalation associated with vapor intrusion.
* * - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate cancer risk or hazard quotient. Lead concentrations are compared to the EPA screening level of 800 mg/kg
for commercial/industrial soil.
CAS #
Chemical Name:
Ingestion
Concentration
(mg/kg)
Dermal
Concentration
(mg/kg)
Inhalation
Concentration
(mg/kg)*
Ingestion
Carcinogenic
Risk
Dermal
Carcinogenic
Risk
Inhalation
Carcinogenic
Risk
Calculated
Carcinogenic
Risk
Ingestion
Hazard
Quotient
Dermal
Hazard
Quotient
Inhalation
Hazard
Quotient
Calculated
Non -
Carcinogenic
Hazard
Quotient
7440-38-2
Arsenic, Inorganic
4.39
4.39
4.39
1.6E-07
2.6E-08
5.8E-08
2.4E-07
2.6E-02
4.1E-03
6.6E-02
9.6E-02
7440-39-3
Barium
148
148
148
2.2E-03
6.6E-03
8.8E-03
7440-43-9
Cadmium (Diet)
16065-83-1
Chromium(III), Insoluble Salts
36.6
36.6
36.6
7.2E-05
1.6E-03
1.7E-03
7439-92-1
Lead and Compounds
17.3
17.3
17.3
<SL**
<SL**
<SL**
7439-97-6
Mercury (elemental)
0.0103
0.0103
0.0103
1.0E-03
1.0E-03
7782-49-2
1 Selenium
0.396
0.396
0.396
2.3E-04
4.4E-06
2.4E-04
Cumulative:
2.4E-07
North Carolina DEQ Risk Calculator

North Carolina Department of Environmental Quality
Risk Calculator
Version Date:
February 2018
Basis:
November 2017 EPA RSL Table
Site Name:
Former Witherspoon Nursery
Site Address:
3312 and 3330 Watkins Road, Durham, North Carolina
DEQ Section:
Brownfields
Site ID:
SED-2
Exposure Unit ID:
Submittal Date:
Prepared By:
Reviewed By:
North Carolina DEQ Risk Calculator

Complete Exposure Pathways
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: SED-2
Exposure Unit ID:
Note: Risk output will only be calculated for complete exposure pathways.
Receptor
Pathway
Check box if
pathway
complete
PRIMARY PATHWAYS
Resident
Soil Combined Pathways
[]
Groundwater Combined Pathways
❑
Non -Residential Worker
Soil Combined Pathways
0
Groundwater Combined Pathways
❑
Construction Worker
Soil Combined Pathways
0
User Defined
Soil Combined Pathways
❑
Surface Water Combined Pathways
❑
VAPOR INTRUSION PATHWAYS
Resident
Groundwater to Indoor Air
❑
Soil Gas to Indoor Air
❑
Indoor Air
❑
Non -Residential Worker
Groundwater to Indoor Air
❑
Soil Gas to Indoor Air
❑
Indoor Air
❑
CONTAMINANT MIGRATION PATHWAYSML
Protection of Groundwater Use
Source Soil
❑
Source Groundwater
❑
Protection of Surface Water
Source Soil
❑
Source Groundwater
❑
North Carolina DEQ Risk Calculator

Point Concentrations
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: SED-2
Unit ID:
Surface Soil Exposure Point Concentration Table
Exposure Point
Concentration
(mg/kg)
Justification for Exposure
Point Concentration
CAS Number
Chemical
Minimum
Concentration
(Qualifier)
Maximum
Concentration
(Qualifier)
Units
Location of
Maximum
Concentration
Detection
Frequency
Range of
Detection Limits
Concentration
Used for
Screening
Background
Value
Screening
Toxicity Value
(Screening
Level) (n/c)
Potential
ARAR/TBC
Value
Potential
ARAR/TBC
Source
COPC
Flag
(Y/N)
Rationale for
Selection or
Deletion
0.0557
67-64-1
Acetone
mg/kg
3.6
7440-38-2
Arsenic, Inorganic
mg/kg
212
7440-39-3
Barium
mg/kg
53.4
16065-83-1
Chromium(III), Insoluble Salts
mg/kg
0.00498
72-55-9
DDE, p,p'-
mg/kg
0.000848
100-41-4
Ethylbenzene
mg/kg
14.4
7439-92-1
Lead and Compounds
mg/kg
0.147
7439-97-6
Mercury (elemental)
mg/kg
0.0186
78-93-3
Methyl Ethyl Ketone (2-Butanone)
mg/kg
0.529
7782-49-2
Selenium
mg/kg
0.00166
108-88-3
Toluene
mg/kg
North Carolina DEQ Risk Calculator

Point Concentrations
ersion Date: February 2018
: November 2017 EPA RSL Table
Site ID: SED-2
Unit ID:
Subsurface Soil Exposure Point Concentration Table
Exposure Point
Concentration
(mg/kg)
Justification for Exposure Point
Concentration
CAS Number
Chemical
Minimum
Concentration
(Qualifier)
Maximum
Concentration
(Qualifier)
Units
Location of
Maximum
Concentration
Detection
Frequency
Range of
Detection Limits
Concentration
Used for
Screening
Background
Value
Screening
Toxicity Value
(Screening
Level) (n/c)
Potential
ARAR/TBC
Value
Potential
ARAR/TBC
Source
COPC
Flag
(Y/N)
Rationale for
Selection or
Deletion
0.0557
67-64-1
Acetone
mg/kg
3.6
7440-38-2
Arsenic, Inorganic
mg/kg
212
7440-39-3
Barium
mg/kg
53.4
16065-83-1
Chromium(III), Insoluble Salts
mg/kg
0.00498
72-55-9
DDE, p,p'-
mg/kg
0.000848
100-41-4
Eth lbenzene
mg/kg
14.4
7439-92-1
Lead and Compounds
mg/kg
0.147
7439-97-6
—Mercury elemental
mg/kg
0.0186
78-93-3
Methyl Ethyl Ketone (2-Butanone)
mg/kg
0.529
7782-49-2
Selenium
mg/kg
0.00166
108-88-3
Toluene
mg/kg
North Carolina DEQ Risk Calculator

Summary of Risk Assessment Output
1 I -
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: SED-2
Exposure Unit ID:
PRIMARY CALCULATORS
Receptor
Pathway
CarcinogenicRisk
Hazard Index
Risk exceeded?
Resident
Soil Combined Pathways
5.3E-06
1.3E-01
NO
Groundwater Combined Pathways*
NC
NC
NC
Non -Residential Worker
Soil Combined Pathways
1.2E-06
1.1E-02
NO
Groundwater Combined Pathways*
NC
NC
NC
Construction Worker
Soil Combined Pathways
2.0E-07
1.1E-01
NO
User Defined
Soil Combined Pathways
NC
NC
NC
Surface Water Combined Pathways*
NC
NC
NC
VAPOR INTRUSION CALCULATORS
Receptor
Pathway
Carcinogenic
Hazard Index
Risk exceeded?
Resident
Groundwater to Indoor Air
NC
NC
NC
Soil Gas to Indoor Air
NC
NC
NC
Indoor Air
NC
NC
NC
Non -Residential Worker
Groundwater to Indoor Air
NC
NC
NC
Soil Gas to Indoor Air
Indoor Air
NC
NC
NC
NC
NC
NC
CONTAMINANT MIGRATION CALCULATORS
Pathway
Source
Target POE Concentrations Exceeded?
Protection of Groundwater Use
Source Soil
Exceedence of 2L at POE?
NC
Source Groundwater
Exceedence of 2L at POE?
NC
Protection of Surface Water
Source Soil
Exceedence of 213 at POE?
NC
Source Groundwater
Exceedence of 213 at POE?
NC
Notes:
1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for
lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations.
2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed
the NC 213 Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a
risk -based closure.
North Carolina DEQ Risk Calculator

North Carolina DEQ Risk Calculator

North Carolina DEQ Risk Calculator

DEQ Risk Calculator - Primary - Construction Worker Soil Combined Pathways
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: SED-2
Unit ID:
* - Note that inhalation on this calculator refers to outdoor inhalation of volatiles and particulates, not indoor inhalation associated with vapor intrusion.
* * - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate cancer risk or hazard quotient. Lead concentrations are compared to the EPA screening level of 800 mg/kg
for commercial/industrial soil.
CAS #
Chemical Name:
Ingestion
Concentration
(mg/kg)
Dermal
Concentration
(mg/kg)
Inhalation
Concentration
(mg/kg)*
Ingestion
Carcinogenic
Risk
Dermal
Carcinogenic
Risk
Inhalation
Carcinogenic
Risk
Calculated
Carcinogenic
Risk
Ingestion
Hazard
Quotient
Dermal
Hazard
Quotient
Inhalation
Hazard
Quotient
Calculated
Non -
Carcinogenic
Hazard
Quotient
7440-38-2
Arsenic, Inorganic
3.6
3.6
3.6
1.3E-07
2.1E-08
4.8E-08
2.0E-07
2.1E-02
3.4E-03
5.4E-02
7.9E-02
7440-39-3
Barium
212
212
212
3.1E-03
9.5E-03
1.3E-02
7440-43-9
Cadmium (Diet)
16065-83-1
Chromium(III), Insoluble Salts
53.4
53.4
53.4
1.0E-04
2.4E-03
2.5E-03
7439-92-1
Lead and Compounds
14.4
14.4
14.4
<SL**
<SL**
<SL**
7439-97-6
Mercury (elemental)
0.147
0.147
0.147
1.5E-02
1.5E-02
7782-49-2
1 Selenium
0.529
0.529
0.529
3.1E-04
5.9E-06
3.2E-04
Cumulative:
2.0E-07
North Carolina DEQ Risk Calculator

Appendix D
Surface Water Standards Calculator and Hardness Statistics
hart hickman
SMAKtER ENVIRONMENTAL SOLUTIONS

Appendix D
Surface Water Quality Standard Calculations
Former Witherspoon Nursery
Durham, North Carolina
H&H Job Nos. CRP.001 and LVL.001
North Carolina 15A NCAC 02B Water Quality Standards for Surface Waters
Freshwater Fresh & Salt Saltwater
Class WS All waters All waters All waters
Class B Class SB Class SA Supplemental Classifications
(I - V) (Class C) (Class C & SC) (Class SC)
Aquatic Life' &
Aquatic Life'
High
Pollutant or
Primary
$
Water
6
Secondary
Fish
3
& Secondary
Primary
s
9
Shellfish
2
Trout
Swamp
Quality
Synonyms & Other
Cancer
Reference Source
Parameter
CAS #
Recreation
Supply
a
Recreation
Consumption
a
Recreation
Recreation
Waters-5,
Waters
Information
io
Endpoint
(See supporting info
(FC & WS)
tab)
All values reported as ug/L unless labeled otherwise.
Acute:
Acute:
Acute:
Click to calculate
ii
Cadmium
7440-43-9
Calc (d,h)
40 (d) Chronic:
Calc
freshwater aquatic life
NA
EPA AWQC 2001 + GEI
Chronic:
CED recalculation
standard
Calc d h
8.8 (d)
(d,h)
Acute:
Click to calculate
Chromium III"
16065-83-1
Calc (d,h)
NA
EPA NRWQC-
freshwater aquatic life
Chronic:
Correction 1999
Calc d h
standard
Acute:
Acute:
Click to calculate
EPA AWQC -Lead
ii
Lead
7439-92-1
Calc (d,h)
210 (d)
freshwater aquatic life
NA
1984; EPA NRWQC-
Chronic:
Chronic:
standard
Calc d h
8.1 d
Correction 1999
Acute:
Acute:
Click to calculate acute
Silver"
7440-22-4
Calc (d,h)
1.9 (d)
NA
EPA AWQC 1980
freshwater aquatic life
Chronic: 0.06
Chronic: 0.1
d
d
standard
The values in these tables do not substitute for any written regulations, nor are they
themselves regulations.
Hardness -Dependent Metal Calculations
Enter in -stream
Metal
Equations for Hardness -Dependent Metals (ug/L)
Calculated standard (ug/L)
hardness (mg/L)
Cadmium, acute
WER*[11.136672-[In hardness] (0.041838)1*e^{0.9151[ln hardness]-3.14851]
43
1.31
Cadmium, chronic
WER*[11.101672-[In hardness] (0.041838)1*e^{0.7998[ln hardness]-4.44511]
43
0.22
Cadmium, acute, trout waters
WER*[11.136672-[In hardness] (0.041838)1*e^{0.9151[In hardness]- 3.62361]
43
0.82
Chromium III, acute
WER*[0.316*e^{0.8190[In hardness]+3.72561]
43
285.43
Chromium III, chronic
WER*[0.860*e^10.8190[In hardness]+0.68481]
43
37.13
Copper, acute
WER*[0.960*e"{0.9422[In hardness]-1.7001]
43
6.07
Copper, chronic
WER*[0.960*e"{0.8545[In hardness]-1.7021]
43
4.35
Lead, acute
WER*[11.46203-[In hardness] (0.145712)1*eAll .273[ln hardness]-1.4601]
43
25.48
Lead, chronic
WER*[11.46203-[In hardness] (0.145712)1*eAll .273[ln hardness]-4.7051]
43
0.99
Nickel, acute
WER*[0.998*e"{0.8460[ln hardness]+2.2551]
43
229.29
Nickel, chronic
WER*[0.997*e^{0.8460[In hardness]+0.05841]
43
25.47
Silver, acute
WER*[0.85*e^11.72[In hardness]-6.591]
43
0.75
Zinc, acute
WER*[0.978*eA10.8473[ln hardness]+0.8841]
43
57.32
Zinc, chronic
WER*[0.986*eA10.8473[ln hardness]+0.8841]
43
57.79
See the Supporting Info tab for information on all footnotes, notes, and abbreviations

Hardness Statistics by 8-Digit HUC
North Carolina, 1969 - 2013
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
Hydrologic
Unit Code
N.
Stations
N.
Samples
10th
Percentile
Median
(50th)
03010102
4
207
40
92
03010103
16
823
17
22
03010104
22
1004
29
34
03010106
7
171
23
32
03010107
13
944
28
31
03010201
03010202
2
87
31
37
03010203
14
711
22
28
03010204
3
176
24
30
03010205
22
281
66
92
03020101
22
1198
23
28
03020102
3
189
22
27
03020103
14
907
28
36
03020104
2
101
12
16
03020105
03020106
1
134
38
60
03020201
65
2730
26
33
03020202
16
725
24
30
03020203
21
680
20
26
03020204
9
166
44
60
03030001
3
248
65
96
03030002
72
3100
32
43
03030003
45
1863
32
42
03030004
29
1370
10
18
03030005
19
1129
21
26
03030006
18
862
18
24
03030007
21
778
31
41
03040101
27
1571
14
20
03040102
7
552
22
34
03040103
56
1936
30
40
03040104
18
645
16
22
03040105
34
1135
37
46
03040201
16
453
14
21
03040202
03040203
63
1445
6
12
03040204
23
391
6
8
03040206
27
550
15
21
03040207
03050101
72
3257
11
15
03050102
20
1385
13
22
03050103
15
1049
52
67
03050105
28
1180
12
17
03060101
3
132
4
5
03060102
05050001
31
825
16
20
06010103
8
352
14
20
06010105
35
2055
6
10
06010106
16
1075
5
10
06010108
12
805
6
13
06010202
15
631
6
8
06010203
12
360
5
6
06010204
8
175
7
10
06020002
1 161
307
81
10
Totals: 1 10251 42850
Minimum
Maximum
19
210
0
120
1
180
12
150
1
860
16
160
2
520
0
150
5
1617
0
140
10
88
1
14000
4
120
18
4200
1
3917
0
800
0
620
0
490
24
34000
1
180
1
4500
1
220
2
16000
1
5900
1
1800
1
1800
1
110
1
17413
3
331
1
557
2
67
2
150
2
140
1
1700
0
1200
1
4500
1
586
2
314
1
20
0
100
0
180
1
478
1
360
0
170
1
35
1
410
2
174
11
208
Cape Fear River Basin, Haw River Subbasin
Note: These data include all quality -assured hardness results in the EPA STORET database for NC from 6/6/1969 - 9/4/2013.