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HomeMy WebLinkAbout20037_Highland Mill#3 VMS Installation and Pre-Occupancy Sampling Report Units 1-7_Revsion No 1_20190715 SUMMIT Engineering, Laboratory & Testing, P.C. 3575 Centre Circle Fort Mill, South Carolina 29715 www.SUMMIT-companies.com Phone: (704) 504-1717 Fax: (704) 504-1125 July 15, 2019 Ms. Joselyn Harriger, P.G. North Carolina Department of Environmental Quality Brownfields Program 610 E. Center Avenue Mooresville, NC 28115 Subject: Vapor Mitigation System Installation and Pre-Occupancy Report Units 1, 2, 3, 4, 5, 6 and 7 Highland Mill Townhomes Highland Mill #3 2767 N. Brevard Street Charlotte, Mecklenburg County, North Carolina SUMMIT Project No. 1820.59 Brownfields Project Number 20037-16-060 Dear Ms. Harriger: SUMMIT ENGINEERING, LABORATORY & TESTING, P.C . (SUMMIT) is pleased to submit this report summarizing vapor mitigation system installation, testing, inspections and pre-occupancy testing and sampling activities conducted at the residential townhome Units 1, 2, 3, 4, 5, 6 and 7 of the Highland Mill Townhomes development at the Highland Mill #3 Brownfields site, located in the northwestern quadrant of the intersection of North Davidson and North Brevard Streets, Charlotte, Mecklenburg County, North Carolina. If you have any questions regarding our assessment of the subject property or our conclusions, please do not hesitate to call us at (704) 504-1717. Sincerely, SUMMIT Michael D. Zavislak, NRCC-EAC, CHMM, CIH, PE SUMMIT’s North Carolina Engineering Firm License C-4391 VAPOR MITIGATION INSTALLATION INSPECTIONS, PRE-OCCUPANCY TESTING & SAMPLING REPORT UNITS 1, 2, 3, 4, 5, 6 & 7 HIGHLAND MILL TOWNHOMES HIGHLAND MILL #3 CHARLOTTE MECKLENBURG COUNTY NORTH CAROLINA BROWNFIELDS PROJECT NO. 20037-16-060 SUMMIT PROJECT NO. 1820.59 Prepared For: North Carolina Department of Environmental Quality Brownfields Program 610 E. Center Avenue Mooresville, NC 28115 Prepared By: SUMMIT ENGINEERING, LABORATORY & TESTING, P.C. 3575 Centre Circle Fort Mill, South Carolina 29715 704-504-1717 May 28, 2019 Revision #1: July 15, 2019 VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\1820.59 VMS Installation Pre-Occupancy Sampling Report Units 1-7 5.3.19.docx i TABLE OF CONTENTS 1.0 INTRODUCTION .................................................................................................................... 1 1.1. PURPOSE .......................................................................................................................................... 1 1.2. PROJECT OVERVIEW..................................................................................................................... 1 1.3. TOWNHOME UNIT OVERVIEW ................................................................................................... 2 2.0 VAPOR MITIGATION SYSTEM INSTALLATION AND TESTING .................................. 3 2.1. VMS OVERVIEW ............................................................................................................................. 3 2.2. INSPECTIONS .................................................................................................................................. 3 2.3. STONE BASE .................................................................................................................................... 4 2.4. SUB-SLAB VAPOR EXTRACTION LINES ................................................................................... 4 2.5. PRESSURE MONITORING POINTS ............................................................................................. 5 2.6. VAPOR BARRIER INSTALLATION .............................................................................................. 5 2.7. SYSTEM TESTING .......................................................................................................................... 6 2.8. SYSTEM IDENTIFICATION ........................................................................................................... 7 2.9. SYSTEM ALARMS .......................................................................................................................... 8 3.0 PRE-OCCUPANCY SAMPLING ............................................................................................ 9 3.1. OVERVIEW ....................................................................................................................................... 9 3.2. EXTERIOR SOIL GAS SAMPLING ............................................................................................... 9 3.3. SOIL GAS SAMPLING RESULTS ................................................................................................ 11 3.4. INDOOR & AMBIENT AIR SAMPLING ..................................................................................... 12 3.5. POTENTIAL CONTAMINANT SOURCES ................................................................................. 13 3.6. AMBIENT AIR SAMPLING RESULTS ........................................................................................ 14 3.7. RISK ASSESSMENT ...................................................................................................................... 14 4.0 FINDINGS AND CONCLUSIONS ....................................................................................... 16 5.0 RECOMMENDATIONS ........................................................................................................ 18 APPENDICES Appendix I: FIGURES Appendix II: PHOTOGRAPH LOGS Appendix III: VMS FIELD INSPECTION LOGS Appendix IV: SAMPLE DATA TABLES Appendix V: LABORATORY REPORTS Appendix VI: RISK CALCULATOR Appendix VII: SAMPLE COLLECTION LOGS/FIELD REPORTS Appendix VIII: POTENTIAL CONTAMINANT SOURCES / SDS Appendix IX: VMS ALARM Appendix X: DRAGO SEALANT VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\1820.59 VMS Installation Pre-Occupancy Sampling Report Units 1-7 5.3.19.docx 1.0 INTRODUCTION 1.1. PURPOSE On behalf of CCH-Highland Mill, LLC, SUMMIT prepared this report summarizing vapor mitigation system installation inspections and pre-occupancy testing and sampling activities conducted for residential townhome Units 1, 2, 3, 4, 5, 6 and 7 of the Highland Mill Townhomes development at the Highland Mill #3 Brownfields site, located in the northwestern quadrant of the intersection of North Davidson and North Brevard Streets, Charlotte, Mecklenburg County, North Carolina. SUMMIT performed inspections, testing and pre-occupancy sampling activities outlined in the approved October 13, 2017 Vapor Mitigation Plan. Pre-occupancy sampling was conducted for the following seven (7) residential townhome units: Townhome Physical Address Townhome Unit # Proposed Occupancy Date * 2715 N. Brevard Street 1 July 1, 2019 2719 N. Brevard Street 2 2723 N. Brevard Street 3 2727 N. Brevard Street 4 2731 N. Brevard Street 5 2735 N. Brevard Street 6 2801 N. Brevard Street 7 *- approximate date pending DEQ approval of this report. 1.2. PROJECT OVERVIEW The development of the subject site includes the construction of fifteen (15) townhome units. The units are multi-story, wood framed townhomes constructed on slab on grade foundations. Previous environmental assessments documented soil impacts from SVOC continents, soil gas and groundwater impacts by VOC constituents. Based on known groundwater impacts originating VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\1820.59 VMS Installation Pre-Occupancy Sampling Report Units 1-7 5.3.19.docx from an upgradient off-site source, SUMMIT proposed an active sub-slab depressurization vapor mitigation system be utilized in development of the site. SUMMIT initially submitted a Vapor Mitigation Plan (VMP) dated June 12, 2017 and received DEQ approval on June 26, 2017. Based on foundation design conflicts with the June VMP, a revision to the VMP was required. A revised VMP was submitted on October 13, 2017 and received DEQ approval on October 13, 2017. 1.3. TOWNHOME UNIT OVERVIEW The development of the subject site includes the construction of fifteen (15) townhome units. The units are multi-story, wood framed townhomes constructed on slab on grade foundations. The townhome units are constructed on a split-level foundation with the upper slab portion being utilized as a garage space and the lower slab area as a 400 SF living space. The lower slab portions of the units are located on the southern elevation of all units, facing N. Brevard Street with the upper garage slab located along the northern elevation of the building. VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\1820.59 VMS Installation Pre-Occupancy Sampling Report Units 1-7 5.3.19.docx 2.0 VAPOR MITIGATION SYSTEM INSTALLATION AND TESTING 2.1. VMS OVERVIEW The PD proposed to develop the townhome buildings utilizing a vapor barrier system and sub-slab depressurization system. One (1) system per unit for a total of fifteen (15) individual systems are utilized for this development. All sub-slab components of the system were installed by concrete and waterproofing subcontractors (Doggett). The VMP specified vapor mitigation system consisted of: • 6 inches of washed stone sub-slab • Vapor extraction lines installed in stone base layer sub-slab and connected to a vertical riser • Six (6) pressure monitoring points installed in upper 1 inch of stone base layer • 10-mil vapor barrier membrane film base layer (Stego Wrap Class A) • Active fan system (Fantech HP220) • Installation of two (2) exterior soil gas monitoring points to depths of 6 feet below ground surface (2 ft below lower slab elevations) in accordance with DEQ guidance documents. The SUMMIT provided QA/QC to include field inspections to measure thickness of stone base, placement of extraction lines, placement and construction of pressure monitoring points, placement of vapor barrier and activation of fan units. Photographs of unit inspections are included in Appendix II of this Inspection Report. 2.2. INSPECTIONS Initial construction activities to include grading of the site started in December 2017. Each of the 15 townhome units being built was constructed utilizing a poured wall footing foundation separating each townhome unit. Based on the foundation design, each unit required a sub-slab vapor mitigation system (VMS). VMS installation inspections were conducted between February 28, 2018 and July 3, 2018. Inspections were performed on multiple units as they became available for review. VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\1820.59 VMS Installation Pre-Occupancy Sampling Report Units 1-7 5.3.19.docx Inspections were completed to include the following: • Confirm thickness of stone base prior to installation of vapor mitigation extraction piping. • Confirm installation of extraction piping. • Confirm thickness of stone base following installation of vapor mitigation extraction piping. • Confirm proper installation of permanent pressure monitoring and sub-slab soil gas sampling points prior to vapor barrier installation. • Confirm installation of vapor barrier, supervised by a Professional Engineer. • Confirm installation of riser and fan. • Confirm installation of VMS signage. 2.3. STONE BASE Stone base thickness was measured in the field by Patrick Lowery, P.G. and Michael Zavislak, P.E. The stone material was inspected and appeared in conformance to the VMP specifications of aggregate equal to or larger than the following: 100% passing a 2-inch grate; 90 to 100% passing a 1- 1/2-inch grate; 20-55% passing a 1-inch grate; 0-15% passing a ¾ inch grate; and 0-5% passing a 3/8- inch grate. Stone appeared washed and generally clear of fines. Stone thickness was measured at 6 inches across all prepared surfaces of Units 1, 2, 3, 4, 5, 6 and 7. 2.4. SUB-SLAB VAPOR EXTRACTION LINES Horizontal sub-slab vapor extraction lines were planned for installation in each unit. For this development, the townhome units were split level, with a lower floor situated along N. Brevard Street (front of townhome) and an upper level utilized as a garage on the northern side of the development. Each level is comprised of two (2) 2-inch PVC perforated extraction lines connected to 3-inch collector lines from the 4-inch vertical riser. All joints shall be sealed with solvent free glue or taped to ensure proper seal. VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\1820.59 VMS Installation Pre-Occupancy Sampling Report Units 1-7 5.3.19.docx Extraction line inspections were completed by Patrick Lowery, P.G. and Michael Zavislak, P.E. Initial inspections began on March 8, 2018 and continued through 2018 as units were ready for inspection. The extraction lines were installed within the stone base material at approximately 3 inches above grade and 3 inches below slab in all units. The extraction lines were installed in the proper locations as outlined in the VMP specification for Units 1, 2, 3, 4, 5, 6 and 7. Photographs of the systems are included in Appendix II of this report. 2.5. PRESSURE MONITORING POINTS The vapor mitigation system included the installation of six (6) sub-slab pressure monitoring points. Pressure monitoring points were installed so that a pressure reading can be made from an observation point located along the exterior of the structure. At each location ¼ inch Tygon tubing was extended within 1-inch conduit piping from the exterior observation point to the predetermined pressure monitoring point in each extraction system. Pressure monitoring points are located in Unit 2, Unit 5, Unit 8, Unit 10, Unit 13 and Unit 15. Pressure monitoring point locations are outline in Figure 1 in Appendix I of this report. SUMMIT verified the pressure monitoring point locations in Unit 5 (garage) and Unit 2 (lower living space), the installation of the conduit, tubing and installation in the upper 1 inch of stone base beneath the planned slab. Inspections started on March 8, 2018 and continued through 2018 as units were made available for inspection. 2.6. VAPOR BARRIER INSTALLATION The vapor mitigation plan specified the use of a minimum 10 mil Stego™ Wrap Class A Vapor Barrier membrane. The VMP details the methods for installation, taping seams, overlap distances and penetration seals. Vapor Barrier inspections were completed by Patrick Lowery, P.G. and Michael Zavislak, P.E. Initial inspections began on March 8, 2018 can continued through 2018 as units were made available for inspection. The use of 10-mil Stego™ Wrap Class A Vapor Barrier was confirmed. Photographs of completed vapor barriers for Units 1, 2, 3, 4, 5, 6 and 7 from the April through July 2018 inspections are included in Appendix II of this report. Minor repairs and patches were required VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\1820.59 VMS Installation Pre-Occupancy Sampling Report Units 1-7 5.3.19.docx during subsequent inspections. Prior to slab pour, all vapor barriers passed inspections completed by SUMMIT. 2.7. SYSTEM TESTING On May 2, 2019 SUMMIT conducted pilot testing of the sub-slab VMS of all townhome Units 1, 2, 3, 4, 5, 6 and 7 to verify the active fan and VMS were providing sufficient vacuum influence. The pilot testing completed varied from the approved VMP procedure of pilot testing prior to installation of the concrete slab foundations. Due to unknown complications to the construction schedules, the lower slab portions of the VMS could not be installed and tested at the same time as the upper slabs which were scheduled to be installed in advance of all lower slabs. Therefore, all pilot testing was conducted after the concrete slabs were installed for both the upper and lower slab elevations of each unit. Pressure readings were recorded from the two (2) installed permanent pressure monitoring points installed at predetermined locations beneath the upper and lower slab on grade foundations. The pressure points were installed utilizing conduit and tubing allowing for measurement to be obtained from the exterior of the Townhome units. At the time of pilot testing the inline fan units were installed, therefore the FanTech HP220 fan was utilized for the pilot testing. Prior to turning the fans on, vacuum measurements were collected at each pressure measuring point to establish baseline conditions. After baseline conditions were recorded, fans were turned on. A Dwyer series 475 Mark III Digital Manometer or a TSI 9565 VelociCalc Multifunction Ventilation Meter (capable of measuring to 0.001 inches of water column (in-WC) or 0.25 Pascals [Pa]) was connected to each pressure measuring port via Teflon tubing to record differential pressures. Vacuum measurements were collected from each monitoring point over an approximately 30-minute period. Following Occupancy Sampling conducted December 30, 2018 with respect to Units 15, 14 and 13, SUMMIT re-inspected all Units for indications of pressure leaks associated with the system risers, slab penetrations or slab joints. Indications of a potential leak point was observed in Units 15, 14 and 13 associated with a bath drain. Therefore, SUMMIT made the recommendation to the contractor to seal all penetrations using Drago Sealant. On January 11, 2019 all slab penetrations related to the VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\1820.59 VMS Installation Pre-Occupancy Sampling Report Units 1-7 5.3.19.docx bath plumbing were cleaned of debris and sealed using Drago Sealant 2-Part Epoxy. Photographs are included in the Photograph Log located in Appendix II of this report. VMS Performance logs summarizing differential pressure measurements at each pressure monitoring point during the May 2, 2019 testing are provided in Appendix III of this report. Locations of the pressure monitoring points are detailed on Figure 1 in Appendix I of this report. Minimum and maximum vacuum measurements recorded at each pressure monitoring point and riser tests are summarized below: Date Unit Low Reading High Reading Temp. Riser CFM Wind Relative Humidity 5/3/19 2 -0.15 -0.15 71 F 72 4 mph S 68-65% 5/3/19 5 -0.09 -0.09 55 F 56 4 mph S Riser air flow velocity and differential pressure was measured using a VelociCalc Multifunction meter. Air flow was measured between 76 and 86 CFM on the tested systems. Differential pressure in the riser was measured at 1.8 and 1.4 in W.C. Differential pressures measured at the permanent monitoring points are above the -0.02 in-WC outlined in the VMP and above the 4 pascals (-0.016 in WC) outlined in DMW Vapor Intrusion guidance. During inspection of these units, SUMMIT learned that the foundation system for each unit includes a foundation drain installed at the base of the split wall beneath the upper garage portion of each unit. The foundation drains are connected to the stormdrain system leading off-site. SUMMIT concludes that the drain system is likely reducing the systems pressures as the vacuum is lost through the open piping beneath the slab however adequate pressures have been maintained and no action is recommended. 2.8. SYSTEM IDENTIFICATION SUMMIT confirmed that visible and accessible areas of the system riser were labeled with yellow and black stenciling with “Soil Vapor Mitigation System”. VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\1820.59 VMS Installation Pre-Occupancy Sampling Report Units 1-7 5.3.19.docx 2.9. SYSTEM ALARMS System alarms consisting of a Dwyer Series 1800 Low Differential Pressure Switch, visible indicator light (Dayton 22NY60 or equivalent) and system label were installed and tested on July 15, 2019 for Units 1 through 7 of the townhome development. Alarm systems are installed and operational in Units 8 through 15. The pressure switch was installed below the fan unit on the riser pipe with the indicator light installed in the Laundry Room/Master Closets above the light switch plate. A label reading “VAPOR MITIGATION SYSTEM ALARM - IF LIGHT IS ILLUMINATED, CONTACT HOA” was installed beneath each alarm light. The system alarms were tested by removing power to the fan system. The installed lights illuminated as needed when the riser pressures dropped below 1.0 inches WC. Specifications for the alarm system is included in Appendix IX of this report. VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\1820.59 VMS Installation Pre-Occupancy Sampling Report Units 1-7 5.3.19.docx 3.0 PRE-OCCUPANCY SAMPLING 3.1. OVERVIEW Occupancy sampling was conducted in accordance with the approved VMP and utilizing Division of Waste Management Vapor Intrusion Guidance (VIG) and Inactive Hazardous Site Branch (IHSB) guidance. Two (2) exterior soil gas sampling points were sampled concurrently with the collection of indoor ambient air samples for this occupancy sampling event. Occupancy sampling was restricted to Units 1, 2, 3, 4, 5, 6 and 7 as the remaining units have previously been tested. Exterior soil gas samples were collected and analyzed for the presence of compounds previously detected in soil gas assessments by TO-15 while the indoor air and ambient air samples were collected and analyzed for the presence of Tetrachloroethylene (PCE) and daughter products (trichloroethylene, 1,1- dichloroethylene, cis-1,2-dichloroethylene, trans-1,2-dichloroethylene and vinyl chloride) by TO-15. One (1) duplicate sample was collected for each media for each sampling event. Locations of the collected samples can be viewed on Figure 1 in Appendix I of this report. The occupancy sampling for Units 1, 2, 3, 4, 5, 6 and 7 was conducted on May 3rd and 4th, 2019. Pace Analytical provided laboratory analysis of the collected samples. 3.2. EXTERIOR SOIL GAS SAMPLING As outlined in the VMP, two (2) soil gas sampling points were required to monitor soil gas concentrations at locations adjacent to the townhome development. On December 5, 2018 SUMMIT personnel mobilized to the subject site and installed the two (2) soil gas sample points. The locations of the soil gas sampling points are detailed in Figure 1 in Appendix I of this report. The soil gas sample locations were installed by Patrick Lowery, P.G. in accordance with Division of Waste Management Vapor Intrusion Guidance (VIG) and Inactive Hazardous Site Branch (IHSB) guidance. At the time of installation, temporary surface protection was provided. Permanent surface protection will be installed once final grade of landscaping is achieved. VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\1820.59 VMS Installation Pre-Occupancy Sampling Report Units 1-7 5.3.19.docx Prior to sample collection, a leak test was performed on each soil gas sampling point by placing a shroud around the point, saturating the air within the shroud with helium gas, then purging soil gas from the sampling point with a GilAir-5 vacuum pump into a Tedlar® bag. A Dielectric MGD 2002 helium gas detector was used to measure helium concentrations in the shroud and bag. The leak test was considered successful if the helium concentration measured in the soil gas purged from the sampling point was less than 10% of the concentration measured in the shroud. Following a passing leak test, soil gas samples were collected in laboratory prepared 1 Litter Summa Canisters and 200- ml per minute regulators. Collected soil gas samples were analyzed by EPA Method TO-15 for the presence of all compounds previously detected in the soil gas sampling and vinyl chloride by Pace Analytical. Canister vacuum readings never reached 0 and were received by the laboratory at similar vacuum psi readings as reported at the end of the sampling event with the exception of HMSG-1. HMSG-1 was reported to be received with a pressure of -1.0 while the duplicate sample HMSG-1 DUP and HMSG-2 were received with a pressure of -11.0. As HMSG-1 and HMSG-1 DUP were collected with a “T” duplicate sampler, SUMMIT believes that the -1.0 received pressure was recorded in error by the lab and should have read -11.0. Pace Analytical could not confirm if the -1.0 was a typo but acknowledged that it was possible. As no confirmation could be determined as to the received pressure, SUMMIT has included the analytical results from HMSG-1 and HMSG-1 DUP for review and consideration. Soil gas sampling was conducted concurrently during indoor and ambient air occupancy sampling. A copy of sampling forms for each sampling event are included in Appendix VII of this report. A summary of sampling event data is provided below: Date Sample IDs Pass Leak Test Maint. Pressure Weather Conditions 12/7/18 HMSG-1*, HMSG-2 Yes Yes 45 F Overcast 12/30/18 HMSG-1*, HMSG-2 Yes Yes 40 F Rain 1/13/19 HMSG-1*, HMSG-2 Yes Yes 39 F clear 1/30/19 HMSG-1*, HMSG-2 Yes Yes 40.5 F clear 2/28/19 HMSG-1*, HMSG-2 Yes Yes 66 F clear 3/28/19 HMSG-1*, HMSG-2 Yes No 66 F Clear 5/2/19 HMSG-1*, HMSG-2 Yes Unk 75 F Clear *- Duplicate sample collected VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\1820.59 VMS Installation Pre-Occupancy Sampling Report Units 1-7 5.3.19.docx Decreased sampling volumes were observed in HMSG-1 during the 12/31, 1/13 and 2/27 sampling events. HMSG-1 is located within a large landscaped bed while HMSG-2 is located between paved driveways and other impervious surfaces. SUMMIT attributed the decreased volume to increased saturation levels of the surrounding soils. December 2018 experienced approximately 7 inches of rain; January 2019 experienced 5 inches of rain while February 2019 experienced 5.5 inches prior to the February 28 sampling. Average precipitation and dry days were noted in April and March of 2019. The May 3, 2019 sampling event did not encounter decreased sample volumes. SUMMIT attributes the increased sample volume to dryer conditions. If the sampling volumes decrease in the future, the sampling point will be replaced with a new soil gas point in accordance with DWM VI Guidance. 3.3. SOIL GAS SAMPLING RESULTS A summary of laboratory detections and comparisons to DWM Residential Vapor Intrusion Screening Levels can be found on Table 1.0 in Appendix IV of this report. The following summarizes the soil gas sample detections: • Multiple VOC compounds were detected in the soil gas samples collected during the 5/3/19 sampling event. VOCs have historically been detected in previous sampling events (12/7, 12/30, 1/13, 1/30, 2/28, 3/28). • Trichloroethylene (TCE) was detected in the soil gas sample HMSG-1 collected during this sampling event at 2.0 ug/m3. Historically, TCE was not detected above the detection limits with the exception of a 1.8 ug/m3 “J Value” result in HMSG-1 on 2/28/19. • Tetrachloroethylene (PCE) was detected in sampling locations HMSG-1 and HMSG-2 in the 5/3/19 sampling event at concentrations of 1.5 ug/m3 and 124 ug/m3 respectively, below the NC DWM Residential SGSL of 280 ug/m3. Historically, PCE has been detected in sampling locations HMSG-1 and HMSG-2 in previous sampling events (12/7, 12/30, 1/13, 1/30, 2/28, 3/28) with a maximum concentration of 406 ug/m3 collected on 12/30/18 from HMSG-2. • Methylene chloride, 2-butanone (MEK) and Toluene were noted to be reported in HMSG-1 5/3/19 sample with the highest reported detections when compared to all previous sampling events. All detections were below NC DWM Residential SGSLs. VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\1820.59 VMS Installation Pre-Occupancy Sampling Report Units 1-7 5.3.19.docx 3.4. INDOOR & AMBIENT AIR SAMPLING Occupancy sampling was conducted in accordance with the VMP and general industry standards. Sampling was conducted with the VMS activated and maintaining pressures greater than 0.02 in-WC. The initial sample event was conducted with the HVAC system off in Units 1, 2, 3, 4 and 5 while HVAC system was operational in Units 6 and 7. All units were inspected for potential contaminate sources on 5/2/19, prior to sampling event. Ambient air samples were collected in laboratory prepared 6 Liter Summa Canisters and calibrated 24-hour regulators. Regulator pressure readings were recorded throughout the sampling event to ensure the canister vacuum did not reach 0 in HG vacuum during the sampling period. Temperature and relative humidity measurements were recorded for the sampling period utilizing a Krestral 2500 hand held weather meter. Collected occupancy ambient air samples were analyzed by EPA Method TO-15 for the presence PCE and PCE daughter products (trichloroethylene, 1,1-dichloroethylene, cis- 1,2-dichloroethylene, trans-1,2-dichloroethylene and vinyl chloride) by SGS North America, Inc and Pace Analytical. Canister vacuum readings never reached 0 in HG and were received by the laboratory at similar vacuum readings as reported at the end of the sampling event. A copy of sampling forms detailing each sampling event are included in Appendix VII of this report. Tables 3.0 in Appendix IV of this report detail the sampling event conditions. A summary of sampling event data is provided below: Date Sample IDs Initial Pressure (in Hg) Final Pressure (in Hg) Weather Conditions 5/3/19 U1-1 28 5 60-80 F Clear 5/3/19 U2-1 29 5 60-80 F Clear 5/3/19 U3-1 29 5 60-80 F Clear 5/3/19 U4-1* 29 5 60-80 F Clear 5/3/19 U5-1 30+ 6 60-80 F Clear 5/3/19 U6-1 30+ 5 60-80 F Clear VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\1820.59 VMS Installation Pre-Occupancy Sampling Report Units 1-7 5.3.19.docx 5/3/19 U7-1 29 5 60-80 F Clear 5/3/19 AA-1 24 5 60-80 F Clear 5/3/19 AA-2 10 - 60-80 F Clear *- Duplicate sample collected Sample canister AA-2 was received from the lab with an initial pressure of -10. Therefore, AA-2 was not collected and the specific canister was noted on the Chain of Custody as a voided sample. 3.5. POTENTIAL CONTAMINANT SOURCES During each sampling event, SUMMIT conducted a reconnaissance of the sample areas for potential on-site and off-site contaminant sources that may interfere with the sample collection conducted at that time. Copies of the DWM sampling form is included in Appendix VII of this report. On-site: • Building Products – The townhome units were constructed and finished with glued-down finished wood floors, new and painted surfaces (Units 1-7). SDS sheets for construction and building materials did not identify potential contaminants of concern. Off-Site: • The subject site is located approximately 180 feet southwest of DSCA Site Cunningham Cleaners (Site ID 600019). The DSCA site along with the former use of the building containing the DSCA site are believed to be the source of the identified groundwater impacts at the subject site. Currently the DSCA site utilizes an active sub-slab depressurization system to reduce indoor air concentrations of chlorinated solvent compounds. The depressurization system vents to the exterior air, from the building elevation closest to the subject property. Figure 2 in Appendix I depicts the DSCA site location in relation to the subject site. A review of the DSCA site information documents concentrations of TCE/PCE in ambient outside and indoor air on the Highland Mill property. A 2013 Air Results Map documenting indoor and outdoor TCE/PCE concentrations is included in Appendix VIII of this report. Wind direction VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\1820.59 VMS Installation Pre-Occupancy Sampling Report Units 1-7 5.3.19.docx during the sample events was recorded to be variable with winds trending from and away from the DSCA site. The active venting of chlorinated solvent compounds on the nearby adjacent property is considered an outside air contaminant source. 3.6. AMBIENT AIR SAMPLING RESULTS A summary of laboratory detections and comparisons to DWM Residential Indoor Air Screening Levels (IASLs) can be found on Table 2.0 in Appendix IV of this report. The following summarizes the laboratory results for Units 1, 2, 3, 4, 5, 6 and 7 on the May 3, 2019 sampling event: • No detections were reported in indoor air samples with respect to Units 1, 2, 3, 4, 5, 6 and 7 collected on 5/3/19. • Tetrachloroethylene was detected in exterior ambient air sample AA-1 at an estimated concentration (J Value) of 0.79 ug/m3 collected on 5/3/19. No other detections reported in AA-1. 3.7. RISK ASSESSMENT SUMMIT utilized the February 2018 DEQ Risk Calculator for soil gas to indoor air exposure pathway and indoor air exposure pathway risk calculations. The default conservative risk factors and calculations were utilized for each Exposure Unit. Two soil gas risk assessments were calculated using the highest detections at the sampling location from all sampling events and also inputting the last four (4) sampling event. For indoor air risk assessment, the highest concentration detected from each constituent from the indoor sampling locations was input into each exposure point calculation. The risk factors are included in the data tables in Appendix IV of this report. A copy of the risk assessment can be found in Appendix VI of this report. A summary of risk assessment data is provided below: VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\1820.59 VMS Installation Pre-Occupancy Sampling Report Units 1-7 5.3.19.docx Units 11 March 28, 2019 Sampling Event Date Exposure Pathway Description Carcinogenic Risk Non-Carcinogenic Hazard Index Risk Exceeded? 5/3/19 Indoor Air No Detections 0.00E+00 0.00E+00 NO 12/7/18 through 5/3/19 Soil Gas Highest detections from all sampling events from HMSG-1 5.20E-06 2.70E-01 NO 12/7/18 through 5/3/19 Soil Gas Highest detections from all sampling events from HMSG-2 6.60E-06 4.80E-01 NO 1/13/19 through 5/3/19 Soil Gas Highest detections from last four (4) sampling events from HMSG-1 4.90E-06 2.40E-01 NO 1/13/19 through 5/3/19 Soil Gas Highest detections from last four (4) sampling events from HMSG-2 6.20E-06 3.60E-01 NO Based on the input variables and the most conservative risk factors utilized, risk thresholds were not exceeded. VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\1820.59 VMS Installation Pre-Occupancy Sampling Report Units 1-7 5.3.19.docx 4.0 FINDINGS AND CONCLUSIONS This report details the results of VMS installation inspections at residential townhome Units 1, 2, 3, 4, 5, 6 and 7, system testing of these units, and ambient air pre-occupancy sampling of these units. From February 2018 through July 2018, SUMMIT personnel inspected the VMS installations of all 15 townhomes currently being built by CCH-Highland Mill. Units 1, 2, 3, 4, 5, 6 and 7 were inspected to be in compliance with the VMP specifications at the time of installation. Subsequent system testing utilizing the installed inline fans at those units confirmed depressurization is occurring at pressure differentials greater than the VMP goal of 0.02 in-WC. Subsequent inspections observed potential leak points at slab penetrations in the units. The potential leak points were re-sealed with Drago Epoxy and the systems were re-tested. Subsequent testing and monitoring indicated an increase in sub-slab pressures in the lower level living spaces. SUMMIT certifies that the VMS installed in Units 1, 2, 3, 4, 5, 6 and 7 of Highland Mill Townhomes are installed and operating properly. As- Built drawings will be provided when they are available. Soil gas sampling conducted in concurrence with the 5/3/19 pre-occupancy sampling at the site documented the presence of multiple VOC compounds to include Tetrachloroethylene and estimated J Value concentrations of Trichloroethylene. No concentrations exceeded the DMW Residential SGSLs in the 5/3/19 sampling event. In previous sample events, samples collected from HMSG-2, adjacent to Unit 8/9 detected Tetrachloroethylene above the DMW Residential SGSLs in December 30, 2018 and January 13, 2019 sampling events. Risk Assessment calculations indicate that the hazard index and carcinogenic risk are below risk thresholds for both sampling points. Indoor and outdoor ambient air samples were collected for pre-occupancy sampling of Units 1, 2, 3, 4, 5, 6 and 7 on May 3, 2019. The May 3, 2019 results reported no detections of PCE, PCE breakdown products or Vinyl Chloride above laboratory method detection limits in the collected indoor air samples. Exterior ambient air sample AA-1 reported an estimated J Value concentration of tetrachloroethylene at 0.79 ug/m3. This detection is attributed to off-site contamination sources such as the nearby DSCA site that is currently operating a sub-slab vapor mitigation system for chlorinated VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\1820.59 VMS Installation Pre-Occupancy Sampling Report Units 1-7 5.3.19.docx solvents. Additionally, SUMMIT determined that the exterior sampling location was down-wind for the majority of the sampling interval for this sampling event. Based on the system testing indicating active depressurization is occurring within acceptable ranges for Units 1, 2, 3, 4, 5, 6 and 7, the results of the contaminate source investigations, the results of the Risk Assessment calculations, and the results of the May 3, 2019 sampling event, SUMMIT concludes that the VMS is operating as intended and thus the townhome units are ready for occupancy. VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\1820.59 VMS Installation Pre-Occupancy Sampling Report Units 1-7 5.3.19.docx 5.0 RECOMMENDATIONS Based on the VMS inspection and testing, contaminant investigation and remedial actions, Risk Assessment, and the results of the occupancy sampling events for Units 1, 2, 3, 4, 5, 6 and 7 of the Highland Mill Townhomes development SUMMIT offers the following recommendations: • SUMMIT recommends conducting Bi-Weekly (i.e., once every two weeks) pressure monitoring of all installed pressure monitoring points for a period of 6 months to ensure adequate depressurization is occurring for the VMS. • SUMMIT recommends Brownfields approve occupancy of Units 1, 2, 3, 4, 5, 6 and 7 conditioned on the recommendations outlined above. VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\1820.59 VMS Installation Pre-Occupancy Sampling Report Units 1-7 5.3.19.docx APPENDIX I FIGURES Source: Drawn by SUMMIT. Base Map provided by Metrolina. Prepared By\Date:PL/05/19Checked By\Date:MZ/05/19 Figure 11 inch = 40 feet Charlotte, NC Vapor Mitigation System Sampling Plan Brownfields Project No. 20037-16-060 CCH-Highland Mill, LLC Units 08, 09, 10 & 12 Townhomes at Highland Mill 2550 West Tyvola Road, Suite 100 N. Brevard Street Charlotte, NC 28217 Approximate Scale KEY Ambient Air Sample Location Pressure Monitoring Point Exterior Soil Gas Sampling Point Townhome Unit Number 1 8 1591011121314345672 8 HMSG-1 Cunningham Cleaners DSCA Site ID 60-0019 HMSG-2 N U2-1 U3-1 U4-1 AA-1 U1-1 U5-1 U6-1 U7-1 Source: Drawn by SUMMIT. Base Map surveyed by SUMMIT Land Services. Prepared By\Date:PL/01/19Checked By\Date:MZ/01/19 Scale Figure 2NTS Charlotte, NC Site Overview Map Brownfields Project No. 20037-16-060 CCH-Highland Mill, LLC Townhomes at Highland Mill 2550 West Tyvola Road, Suite 100 N. Brevard Street Charlotte, NC 28217 N Cunningham Cleaners DSCA Site ID 60-0019 Subject Site VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\Appendix II - Photo Log.rtf APPENDIX II PHOTOGRAH LOGS Highland Park Townhomes SUMMIT Project No.1820.59 Charlotte, Mecklenburg County, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\VMP Install Photographs Unit 1-7.doc 1 SITE PHOTOGRAPHS View of the subject site on 11-14-17 View of the subject site on 1-12-18 Highland Park Townhomes SUMMIT Project No.1820.59 Charlotte, Mecklenburg County, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\VMP Install Photographs Unit 1-7.doc 2 View of subject site on 1-24-18 View of foundation walls for Unit 15, 14 and 13 on 2-28-18. Highland Park Townhomes SUMMIT Project No.1820.59 Charlotte, Mecklenburg County, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\VMP Install Photographs Unit 1-7.doc 3 View of typical water proofing of split-level walls View of sub-slab aggregate, meeting VMP specifications. Highland Park Townhomes SUMMIT Project No.1820.59 Charlotte, Mecklenburg County, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\VMP Install Photographs Unit 1-7.doc 4 View showing 4” space sub-slab for aggregate layer per VMP on 2-28-18. View of vapor extraction system installed on 3-8-18. Highland Park Townhomes SUMMIT Project No.1820.59 Charlotte, Mecklenburg County, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\VMP Install Photographs Unit 1-7.doc 5 View of pressure monitoring point conduit installed in Unit 10 on 3-8-18. View of sub-slab vapor barrier install on Unit 7. Highland Park Townhomes SUMMIT Project No.1820.59 Charlotte, Mecklenburg County, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\VMP Install Photographs Unit 1-7.doc 6 View of concrete pour on Unit 6. View of Unit 6 following slab pour. Highland Park Townhomes SUMMIT Project No.1820.59 Charlotte, Mecklenburg County, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\VMP Install Photographs Unit 1-7.doc 7 View of Unit 4 lower level stone installed. View of Unit 4 upper slab. Highland Park Townhomes SUMMIT Project No.1820.59 Charlotte, Mecklenburg County, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\VMP Install Photographs Unit 1-7.doc 8 View of Unit 3 lower level. View of Units 1-3 on 7-25-18. Highland Park Townhomes SUMMIT Project No.1820.59 Charlotte, Mecklenburg County, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\VMP Install Photographs Unit 1-7.doc 9 View of vent riser Unit 7. View of vent riser Unit 1 on 1-7-19. Highland Park Townhomes SUMMIT Project No.1820.59 Charlotte, Mecklenburg County, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\VMP Install Photographs Unit 1-7.doc 10 View of penetrations following pour and rough-in. View of inspection of Unit 1 on 5/2/19 prior to sampling 5/3/19. Highland Park Townhomes SUMMIT Project No.1820.59 Charlotte, Mecklenburg County, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\VMP Install Photographs Unit 1-7.doc 11 View of inspection of Unit 3 on 5/2/19 prior to sampling 5/3/19. View of inspection of Unit 4 on 5/2/19 prior to sampling 5/3/19. Highland Park Townhomes SUMMIT Project No.1820.59 Charlotte, Mecklenburg County, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\VMP Install Photographs Unit 1-7.doc 12 View of N. Brevard exterior side from Unit 1 on 5/2/19. View of rear garage exterior side from Unit 6 on 5/2/19. Highland Park Townhomes SUMMIT Project No.1820.59 Charlotte, Mecklenburg County, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\VMP Install Photographs Unit 1-7.doc 13 View of air flow riser pilot test in Unit 5. View of pressure measurement on riser of Unit 5. Highland Park Townhomes SUMMIT Project No.1820.59 Charlotte, Mecklenburg County, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\VMP Install Photographs Unit 1-7.doc 14 View of air flow riser pilot test in Unit 2. View of pressure measurement on riser of Unit 2. Highland Park Townhomes SUMMIT Project No.1820.59 Charlotte, Mecklenburg County, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\VMP Install Photographs Unit 1-7.doc 15 View of pressure monitoring point Unit 5 during pilot test. View of pressure monitoring point Unit 2 at startup of pressure test. Highland Park Townhomes SUMMIT Project No.1820.59 Charlotte, Mecklenburg County, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\VMP Install Photographs Unit 1-7.doc 16 View of pressure monitor point Unit 13. View of pressure monitoring point Unit 15. Highland Park Townhomes SUMMIT Project No.1820.59 Charlotte, Mecklenburg County, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\VMP Install Photographs Unit 1-7.doc 17 View of pressure monitoring point Unit10. View of sample container prep. Highland Park Townhomes SUMMIT Project No.1820.59 Charlotte, Mecklenburg County, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\VMP Install Photographs Unit 1-7.doc 18 View of VMS alarms installed and illuminated during testing on July 15, 2019. View of VMS alarms installed and illuminated during testing on July 15, 2019. Highland Park Townhomes SUMMIT Project No.1820.59 Charlotte, Mecklenburg County, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\VMP Install Photographs Unit 1-7.doc 19 View of VMS alarms installed and illuminated during testing on July 15, 2019. View of VMS alarms installed and illuminated during testing on July 15, 2019. VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\Appendix III - VMS Field Inspection Logs.rtf APPENDIX III VMS FIELD INSPECTION LOGS Vapor M.itigation System inspectior, Log Highland Mill Townhomes Browrrfi ef d Proiect # : 20037 -16-060 Date 2-zx- t s/Inspector: PW r-_ Yes Repairs/Mod ificat ions Stone-base th icknes aceptable htA P,-,rpJ J"' s{o* Extraction piping installed properly Stone-base over extraction piping proper thickness Pressure monitoring pooint constructed and iustalled properly Vapor barrier membrane installed properly Riser/fan installed correctly commertls: 9. k- q ^J.l , {. -, n Jn--L:"'us 7ul.L J-- ,/l't, uq&Lu*-r' (>*st*+oh 6- /{. P"Js Date Z- X-/<Inspector: f0V C_ Yes Repairs/Mod ifications Stone-base thicknes aceptable Lt- Extraction piping installed properly NA Stone-base over extraction piping proper thiokness Pressure monitoring pooiut constructed and installed properly Vapor barrier membrane installed properly Riser/fan installed correctly commetrts: $Lu^z bn>-- r"*, l-t/.r/( o^K- tY- uff-" s loL 5 Date 3- 2q- (r f nspector: ?W (_, Yes Repairs/Modifications Stone-base thicknes aceptable L/ Extraction piping installed properly t/- Stone-base over extraction piping proper thiokness htA Pressnre monitoring pooint constructed and installed properly L/ Vapor barrier rnembrane installed properly NK Riser/fan instal led correctly N,+ Comments: Vapor Mitigation System inspection Log Highland Mill Townhomes Brownfief d Project #:2003j-16-060 MZ Repairs/Modifications Stone-base thicknes aceotable Extraction piping installed Stone-base over extraction oioi roper th ickuess Pressure monitoring pooint constructed and installed Vapor barrier membrane installed Riser/fan installed correctly S'|-'. l. qtr' Pwt'tComments: r,t p- V q?atI 4*l r.o.t o.. 7 u ^,1-2 t&r.v:os, (L*-t 3*n-'{."> otr* J-u U&\S coxely-Jwn 'v' ;^ t+*l/ or..'-|r ) r cts Date LI-23- ty lrrspector: f (rrr L- Yes Repairs/Modifications Stone-base thicknes aceptable Extraction piping installed properly Stone-base over extraction piping proper thickness Pressure monitoring pooint constructed ancl installed properly Cotnments: / / t '2['tb>zla(a '<- )Ao P- u d^ - Fs g- /g's t*'ltt.,f**.,t >{ /..--- vAS l-!.1-116.-4 Date 5-q- rd Inspector: CE Yes Repairs/Modifications Stone-base thicknes aceDtab le L-/- Extraclion piping installed properly L./ Stone-base over extraction piping proper thickness u-/ Pressure monitoring pooiut constructed and installed properly l//'' Vapor barrier membrane installed properly ,-/ Riser/fan installed correctly (-"t/l I l=u--sComments: (/n,15 rn1,---f*.( - 6 / K-,?.'r,.4 //z-lL F,f-l -Sr-r S**7t23 Vapor Mitigation System inspection Log Highland Mill Townhornes Brownfief d Project #:20037-16-060 Date s- t/-- tK Inspector: F\^t L Yes Repairs/Modifications Stone-base thicknes aceptable \,- Extraction piping instal led property t- Stone-base over extraction piping proper thickness r-- Pressure monitoring pooint constructed and installed properly (/ Vapor barrier membrane installed properly t/- Ri ser/fan instal led correctly /rno F-eq)comments: S\J2 6r..-rJ !'-lt 6 - l{ / l-f 9{-,* V-+c ooool ?;?"--+ o-f("ouuJ- U"h s V/V.5 4s-f---fr Date (-26_/e.. llnspector: pU,tt- +AZ Yes Repairs/Mod ifical ions Stone-base th icknes aceptable V Extraction piping installed properly Stone-base over extraction piping proper thickness Pressure monitoring pooint constructed and iustalled properly Vapor barrier rnelnbrane installed properly Riser/fan installed correctly N- Fn-.Cotntnetrts: tl t tVY.- v)qv-:-,J\- o.-1 0^-Fs t-{ ; "t7 --l-.tL u/f" /euol Date >-3- tr Inspector: ?WL- Yes Repairs/Modifications Stone-base th icknes aceptable Extraction piping installed properly Stone-base over extraction piping proper thickness Pressure monitoring pooint constructed and installed properly Vapor barrier mernbrane installed properly Riser/fan instal led correctly 6r,! U,^;ts t- -t (c1s-z-.l (*-. Ln-n l.r*( t^t/t- -+*J f VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\Appendix IV - Data Tables.rtf APPENDIX IV SAMPLE DATA TABLES Page 1 of 4 CAS Analyte*12/7/2018 12/30/2018 1/13/2019 1/31/2019 2/28/2019 3/28/2019 5/3/2019 12/7/2018 12/30/2018 1/13/2019 1/31/2019 2/28/2019 3/28/2019 5/3/2019 12/7/2018 12/30/2018 1/13/2019 1/31/2019 2/28/2019 3/28/2019 5/3/2019 67-64-1 Acetone 131 33.6 <12.3 29.8 42.2 46 784 147 37.3 <12.3 12.1 173 -102 197 10.5 25.3 39.8 <5.1 9.0 J 35.4 2.20E+05 71-43-2 Benzene 2.9 5.8 <1.6 1.0 J 1.5 0.38 3.8 3.2 0.92 J <1.6 1.1 J 1.4 J -1.9 4.8 <0.37 <0.32 0.90 J <.65 <0.13 9.4 1.20E+02 75-15-0 Carbon disulfide 8.7 <1.1 <2.2 <1.0 7.4 <0.21 7 9.3 <1.1 <2.2 <1.0 12.5 -69.9 17 1.3J <0.46 <0.84 1.7 J <0.21 2.8 4.90E+03 74-87-3 Chloromethane <0.13 1.2 J <1.6 1.0 J 3.5 9.4 3.9 <0.13 1.4 J <1.6 <0.72 1.7 J -0.88 J <0.13 <0.37 <0.33 <0.60 11 <0.14 <0.41 6.30E+02110-82-7 Cyclohexane 7.2 <1.7 <3.6 <1.6 <1.5 <0.24 11.2 7.6 3.9 J <3.6 <1.6 <1.5 -<0.94 7.2 <0.85 <0.74 <1.4 <1.5 <0.24 <0.94 4.20E+04 75-71-8 Dichlorodifluoromethane 2.5 J 2.0 J <3.0 2.9 J 2.4 J 1.6 2 2.4 J 2.2 J <3.0 2.0 J 2.2 J -1.9 J <0.33 1.8 J 2.2 2.5 J <1.2 <0.21 1.6 J 7.00E+02156-59-2 cis-1,2-Dichloroethylene <0.19 <1.1 <2.2 <1.0 6.3 <0.16 1.7 <0.19 <1.1 <2.2 <1.0 4.7 -<0.58 <0.19 <0.53 <0.46 <0.84 <0.92 <0.16 1.4 J NA 100-41-4 Ethylbenzene 4.8 <1.5 <3.1 <1.4 1.9 J <0.25 12.9 5.2 <1.5 <3.1 <1.4 1.4 J -5.4 <0.26 <0.73 <0.64 <1.2 <1.3 <0.25 14.6 3.70E+02 622-96-8 4-Ethyltoluene <0.59 <2.7 <5.8 <2.6 <2.4 0.52 6.7 <0.59 <2.7 <5.8 <2.6 <2.4 -3.3 J <0.59 <1.4 <1.2 <2.2 <2.4 <0.30 7.3 NA142-82-5 n-Heptane 6.1 <1.8 <3.9 <1.7 <1.6 <0.24 7.6 7 <1.8 <3.9 <1.7 <1.6 -1.5 J 18 <0.91 <0.8 <1.5 <1.6 <0.24 56 2.80E+03 110-54-3 n-Hexane 13 76.8 8.4 35.5 28 <0.62 15.7 12 363 <3.2 2.2 J 19.3 -3.7 23 12.4 2.2 35 24.6 <0.62 3.2 4.90E+04591-78-6 2-Hexanone <0.61 <3.6 <7.6 <3.4 <3.1 <0.24 <1.3 <0.61 <3.6 <7.6 <3.4 <3.1 -<2.0 <0.61 <1.8 <1.6 <2.9 <3.1 <0.24 <2.0 2.10E+02 75-09-2 Methylene chloride <0.20 65.8 49.7 117 71.1 1.1 J 303 <0.20 126 <9.6 12.5 J 84.9 -22.4 <0.20 19.9 12 213 46.7 0.81 J 19.5 4.20E+0378-93-3 2-Butanone (MEK)<0.50 6.4 J <3.8 <1.7 <1.6 3.0 J 35.3 <0.50 3.4 J <3.8 2.1 J <1.6 -54.3 <0.50 2.2 J <0.77 1.5 J 8.3 J 1.8 J 5.9 J 3.50E+04 108-10-1 4-Methyl-2-pentanone (MIBK)<0.57 <2.5 <5.3 <2.4 <2.2 0.67 4.2 J <0.57 <2.5 <5.3 <2.4 2.4 J -2.2 J <0.57 <1.2 <1.1 <2.0 <2.2 <0.20 <1.4 2.10E+0491-20-3 Naphthalene <1.9 <6.4 <13.5 <6.1 <5.6 <0.40 2.9 J <1.9 <6.4 <13.5 <6.1 <5.6 -12.1 <1.9 <3.2 <2.8 <5.1 <5.6 <0.40 12.4 2.10E+01 115-07-1 Propylene 148 9.3 <1.5 8 5.9 <0.17 <0.25 156 9.8 <1.5 7.4 <0.60 -5.2 57.4 8.8 <0.30 <0.55 <0.60 <0.17 0.62 J 2.10E+04100-42-5 Styrene <0.32 <1.7 <3.5 <1.6 <1.5 <0.26 2 <0.32 <1.7 <3.5 <1.6 <1.5 -<0.92 <0.32 <0.83 <0.72 <1.3 <1.5 <0.26 <0.92 7.00E+0395-63-6 1,2,4-Trimethylbenzene <0.64 2.6 J <4.6 <2.1 3.2 J <0.31 24.8 <0.64 <2.2 11.1 <2.1 2.1 J -13.1 <0.64 <1.1 <0.95 <1.7 <1.9 <0.31 5.8 4.20E+02 108-67-8 1,3,5-Trimethylbenzene <0.64 <1.9 <4.1 <1.8 1.9 J 0.65 7.4 <0.64 <1.9 <4.1 <1.8 <1.7 -4.4 <0.64 <0.96 <0.84 <1.5 <1.7 <0.31 <1.1 4.20E+02 127-18-4 Tetrachloroethylene 4.8 9.9 29.8 <1.4 25.1 3.5 1.5 1.4 13.1 29.8 <1.4 20.6 -<0.84 2.4 406 344 25.8 252 78 124 2.80E+02 108-88-3 Toluene 17 18.9 <3.6 3.7 9.5 0.93 244 16 2.5 J 9.2 <1.6 7 -22.4 10 0.95 J <0.74 4.2 3.2 J 0.46 55.7 3.50E+0479-01-6 Trichloroethylene <0.41 <1.2 <2.6 <1.2 1.8 J <0.22 2 <0.41 <1.2 <2.6 <1.2 1.4 J -<0.68 <0.41 <0.62 <0.54 <0.99 1.7 J <0.22 <0.68 1.40E+01 75-69-4 Trichlorofluoromethane 2.5 J <1.8 <3.7 <1.7 <1.5 1.1 J 1.9 J 2.6 J <1.8 <3.7 <1.7 1.6 J -<0.97 <0.62 4.8 4.3 3.1 J 5.3 1.8 J 2.2 J NA 75-01-4 Vinyl chloride <0.23 <0.61 <1.3 <0.58 <0.53 <0.16 <0.22 <0.23 <0.61 <1.3 <0.58 <0.53 -<0.34 <0.23 <0.30 <0.26 <0.49 <0.53 <0.16 <0.34 5.60E+01 m,p-Xylene 21 5.2 J <7.1 <3.2 6.8 J 0.73 J 64 22 <3.4 <7.1 <3.2 5 J -17.4 4.3 <1.7 <1.5 <2.7 <2.9 <0.50 12.5 7.00E+0295-47-6 o-Xylene 4.3 1.8 J <7.5 <1.6 2.6 J 0.41 J 26.2 5.2 <1.7 9.4 <1.6 2 J -7.3 <0.30 <0.83 <0.72 <1.3 <1.5 <0.27 3.4 7.00E+02 Risk Assessment - Soil Gas to Indoor Air - All sampling events 2/2018 DWM Residential Soil Gas Screening Levels (SGSLs) used for comparison2/2018 DEQ Risk Calculator Untilized to calulate Carinogenic Risk (CR) and Hazard Index (HI). CR/HI calculated with the highest detection from all events and last three (3) sampling events conducted at that location. J = Estimated Concentration NT = Not Tested 3/28/19 HMSG-1 DUP lost pressure in shipping and was not analyzed in accordance with DEQ VI Guidance. Carcinoenic Risk (Resident) Hazard Index (Resident) Risk Assessment - Soil Gas to Indoor Air - Last 4 sampling events 4.90E-06 2.40E-01 6.20E-06 3.60E-01 Carcinoenic Risk (Resident) Hazard Index (Resident) Soil Gas Point @ 6'HMSG-1 DUP NC DWM Residential SGSL 5.20E-06 2.70E-01 6.60E-06 4.80E-01 Table 1.0: TO-15 Soil Gas Sample Detection Summary Table All Values in ug/m3 Sample Date HMSG-1Soil Gas Point @ 6'Sample Date HMSG-2Soil Gas Point @ 6'Sample Date Highland Mill #3 Charlotte, NC May 28, 2019 SUMMIT Project No: 1820.59 Page 2 of 4 127-18-4 79-01-6 75-35-4 156-59-2 156-60-5 75-01-4 Sample ID Sample Note Date Collected CR HI U1-1 Unit 1 - Lower Level 5/4/2019 <0.48 <0.39 <0.42 <0.33 <0.43 <0.19 U2-1 Unit 2 - Lower Level 5/4/2019 <0.51 <0.41 <0.44 <0.35 <0.46 <0.20 U3-1 Unit 3 - Lower Level 5/4/2019 <0.50 <0.41 <0.43 <0.35 <0.45 <0.20 U4-1 5/4/2019 <0.50 <0.41 <0.43 <0.35 <0.45 <0.20 U4-1 DUP 5/4/2019 <0.50 <0.41 <0.43 <0.35 <0.45 <0.20 U5-1 Unit 5 - Lower Level 5/4/2019 <0.51 <0.41 <0.44 <0.35 <0.46 <0.20 U6-1 Unit 6 - Lower Level 5/4/2019 <0.51 <0.42 <0.45 <0.36 <0.47 <0.21 U7-1 Unit 7 - Lower Level 5/4/2019 <0.50 <0.41 <0.43 <0.35 <0.45 <0.20 AA-1 Exterior Location # 1 5/4/2019 0.79 J <0.40 <0.42 <0.34 <0.44 <0.20 8.30E+00 4.20E-01 4.20E+01 NA NA 1.70E-01 <# = Below Method Detection Limit BOLD = Concentration Above Reference Values 2/2018 DWM Residential IASLs used for comparison 2/2018 DEQ Risk Calculator Untilized to calulate Carinogenic Risk (CR) and Hazard Index (HI). PCE and daughter products analyzed for this assessment J = Estimated Concentration NT = Not Tested NC DMW Indoor Air Screening Level (IASL) Table 2.0: TO-15 Ambient Air Sample Detection Summary Table All Values in ug/m3 TetrachloroethyleneTrichloroethylene 1,1-Dichloroethylene cis-1,2-Dichloroethylene trans-1,2-Dichloroethylen Vinyl ChlorideUnit 4 - Lower Level Highland Mill #3 Charlotte, NC May 28, 2019 SUMMIT Project No: 1820.59 Page 3 of 4 127-18-4 79-01-6 75-35-4 156-59-2 156-60-5 75-01-4 Sample ID Sample Note Date Collected CR HI U15-1 0.57 0.19 J <0.067 <0.029 <0.048 <0.056 U15-1 DUP 0.6 0.2 J <0.067 <0.029 <0.048 <0.056 4.70E-07 1.10E-01 U15-2 12/30/2018 0.56 J <0.40 <0.42 <0.34 <0.44 <0.20 U15-3 1/13/2019*<0.47 <0.38 <0.41 <0.33 <0.42 <0.19U15-4 1/30/2019 <0.47 <0.38 <0.41 <0.33 <0.42 <0.19 U14-1 3.5 <0.40 <0.42 <0.34 <0.44 <0.20U14-1 DUP 3.3 <0.40 <0.42 <0.34 <0.44 <0.20U14-2 1/13/2019*<0.49 <0.40 <0.42 <0.34 <0.44 <0.20U14-3 1/30/2019 <0.47 <0.38 <0.41 <0.33 <0.42 <0.19 U13-1 12/30/2018 38.5 <0.41 <0.43 <0.35 <0.45 <0.20 3.60E-06 9.20E-01 U13-2 <0.45 <0.37 <0.39 <0.32 <0.41 <0.18 U13-2 DUP <0.45 <0.37 <0.39 <0.32 <0.41 <0.18 U13-3 <0.47 <0.38 <0.41 <0.33 <0.42 <0.19U13-3 DUP <0.47 <0.38 <0.41 <0.33 <0.42 <0.19 U12-1 Unit 12 - Lower Level 2/27/2019 <0.49 <0.40 <0.42 <0.34 <0.44 <0.2 U11-2 <0.48 <0.39 <0.42 <0.33 <0.43 <0.19U11-2 Dup <0.48 <0.39 <0.42 <0.33 <0.43 <0.19 U10-1 Unit 10 - Lower Level 2/27/2019 <0.47 <0.38 <0.41 <0.33 <0.42 <0.19 U09-1 Unit 09 - Lower Level 2/27/2019 <0.47 <0.38 <0.41 <0.33 <0.42 <0.19 U08-1 Unit 08 - Lower Level 2/27/2019 <0.48 <0.39 <0.42 <0.33 <0.43 <0.19 U7-1 Unit 7 - Lower Level 5/4/2019 <0.50 <0.41 <0.43 <0.35 <0.45 <0.20 U6-1 Unit 6 - Lower Level 5/4/2019 <0.51 <0.42 <0.45 <0.36 <0.47 <0.21 U5-1 Unit 5 - Lower Level 5/4/2019 <0.51 <0.41 <0.44 <0.35 <0.46 <0.20 U4-1 <0.50 <0.41 <0.43 <0.35 <0.45 <0.20U4-1 DUP <0.50 <0.41 <0.43 <0.35 <0.45 <0.20 U3-1 Unit 3 - Lower Level 5/4/2019 <0.50 <0.41 <0.43 <0.35 <0.45 <0.20 U2-1 Unit 2 - Lower Level 5/4/2019 <0.51 <0.41 <0.44 <0.35 <0.46 <0.20 U1-1 Unit 1 - Lower Level 5/4/2019 <0.48 <0.39 <0.42 <0.33 <0.43 <0.19 EXTA1-1 12/7/2018 0.81 0.28 <0.067 <0.029 <0.048 <0.056AA-1 12/30/2018 <0.49 <0.40 <0.42 <0.34 <0.44 <0.20AA-1 1/13/2019 <0.45 <0.37 <0.39 <0.32 <0.41 <0.18AA-1 1/30/2019 <0.44 <0.36 <0.39 <0.31 <0.40 <0.18AA-1 2/27/2019 <0.47 <0.38 <0.41 <0.33 <0.42 <0.19AA-1 5/4/2019 0.79 J <0.40 <0.42 <0.34 <0.44 <0.20 AA-2 12/30/2018 <0.49 <0.40 <0.42 <0.34 <0.44 <0.20 AA-2 1/13/2019 <0.47 <0.38 <0.41 <0.33 <0.42 <0.19AA-2 2/27/2019 <0.51 <0.41 <0.44 <0.35 <0.46 <0.20 AA-3 Exterior Location # 3 1/30/2019 <0.61 <0.50 <0.53 <0.42 <0.55 <0.24 AA-3 Exterior Location # 3 3/28/2019 <0.50 <.41 <0.43 <0.35 <0.45 <0.208.30E+00 4.20E-01 4.20E+01 NA NA 1.70E-01 <# = Below Method Detection LimitBOLD = Concentration Above Reference Values 2/2018 DWM Residential IASLs used for comparison2/2018 DEQ Risk Calculator Untilized to calulate Carinogenic Risk (CR) and Hazard Index (HI). PCE and daughter products analyzed for this assessment J = Estimated Concentration NT = Not Tested* - 1/13/19 indoor air samples collected 6hrs following shut off of air exchange units. Table 3.0: TO-15 Historical Ambient Air Sample Detection Summary Table Unit 13 - Lower Level. Exterior Location # 1 Exterior Location # 2 Trichloroethylene 1,1-dichloroethylene cis-1,2-dichloroethylene trans-1,2-dichloroethylen Vinyl chloride5/4/2019Unit 4 - Lower Level NC DMW Indoor Air Screening Level (IASL) All Values in ug/m3 12/7/2018 12/30/2018 TetrachloroethyleneUnit 15 - Lower Level. Unit 14 - Lower Level. 1/13/2019* 1/30/2019 Unit 11 - Lower Level 3/28/2019 Highland Mill #3 Charlotte, NC May 28,2019 SUMMIT Project No: 1820.59 Time PM02 (in WC) PM05 (in WC) PM08 (in WC) PM10 (in WC) PM13 (in WC) PM15 (in WC) Temp. (F) Relative Humidity (%) Wind Speed (mph) Barometric Pressure (in Hg) Condition U1-1 U2-1 U3-1 U4-1/DUP U5-1 U6-1 U7-1 AA-1 1100 -0.23 -0.11 -0.1 -0.22 -0.1 -0.17 75 70 5 SW 30.1 Clear 28 29 29 29 30+30+29 24 1200 -0.19 -0.11 -0.1 -0.21 -0.09 -0.18 77 62 2 SW 30.09 Clear 28 28 28 28 30 30 28 241300-0.15 -0.11 -0.1 -0.22 -0.08 -0.17 79 60 1 SE 30.09 Clear 27 27 27 27 29 29 27 241400-0.15 -0.11 -0.1 -0.19 -0.08 -0.18 81 59 0 30.04 Clear 26 26 26 26 28 29 26 231500-0.15 -0.09 -0.09 -0.19 -0.08 -0.17 81 54 5 S 30.01 Clear 25 25 25 25 28 28 25 231600-0.19 -0.09 -0.08 -0.2 -0.08 -0.16 82 54 5 S 30.01 Clear 24 24 24 24 26 26 24 23 1700 -0.2 -0.11 -0.09 -0.19 -0.078 -0.17 82 54 5 S 29.95 Clear 23 23 23 23 25 25 23 22 1800 -0.18 -0.11 -0.09 -0.21 -0.08 -0.16 81 55 8 S 29.95 Clear 22 22 22 22 23 23 22 221900-0.19 -0.1 -0.1 -0.22 -0.08 -0.17 80 63 9 S 29.95 Clear 21 21 21 21 23 23 21 212000-0.15 -0.1 -0.1 -0.23 -0.09 -0.19 78 70 12 S 29.99 Clear 20 20 20 20 22 22 20 202100-0.2 -0.12 -0.1 -0.22 -0.09 -0.2 75 75 5 S 29.99 Clear 19 19 19 19 21 20 19 192200------------------- 2300 ------------------- 2400 -------------------100 -------------------200 -------------------300 -------------------400 ------------------- 500 -0.26 -0.15 -0.11 -0.25 -0.1 -0.2 68 90 6 SW 29.92 Fog 11 11 11 11 12 12 11 11 600 -0.23 -0.15 -0.15 -0.24 -0.1 -0.2 69 90 5 SW 29.92 Fog 10 10 10 10 11 11 10 10700-0.23 -0.14 -0.11 -0.024 -0.09 -0.2 -------------800 -------------------900 ------71 82 5 W 29.96 Clear 7 7 7 7 7 7 7 71000-0.2 -0.12 -0.11 -0.21 -0.1 -0.2 71 82 3 S 29.96 Clear 6 6 6 6 6 6 6 61100-0.2 -0.12 -0.11 -0.22 -0.1 -0.2 73 75 3 SW 29.95 Clear 5 5 5 5 6 5 5 5 Table 4.0: Sample Collection Summary Table May 3, 2019 Pressure Monitoring Readings Weather Conditions Canister Pressure Readings VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\Appendix V - Laboratory Reports.rtf APPENDIX V LABORATORY REPORTS #=CL# May 20, 2019 LIMS USE: FR - PATRICK LOWERY LIMS OBJECT ID: 92427929 92427929 Project: Pace Project No.: RE: Patrick Lowery Summit Engineering 101 Rice Bent Way Unit 9 Columbia, SC 29229 HIGHLAND MILL-Revised Report Dear Patrick Lowery: Enclosed are the analytical results for sample(s) received by the laboratory on May 06, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Report revised to add MDLs and Fflags. If you have any questions concerning this report, please feel free to contact me. Sincerely, Taylor Ezell taylor.ezell@pacelabs.com Project Manager (704)875-9092 Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 15 #=CP# CERTIFICATIONS Pace Project No.: Project: 92427929 HIGHLAND MILL-Revised Report Minnesota Certification IDs 1700 Elm Street SE, Minneapolis, MN 55414-2485 A2LA Certification #: 2926.01 Alabama Certification #: 40770 Alaska Contaminated Sites Certification #: 17-009 Alaska DW Certification #: MN00064 Arizona Certification #: AZ0014 Arkansas DW Certification #: MN00064 Arkansas WW Certification #: 88-0680 California Certification #: 2929 CNMI Saipan Certification #: MP0003 Colorado Certification #: MN00064 Connecticut Certification #: PH-0256 EPA Region 8+Wyoming DW Certification #: via MN 027- 053-137 Florida Certification #: E87605 Georgia Certification #: 959 Guam EPA Certification #: MN00064 Hawaii Certification #: MN00064 Idaho Certification #: MN00064 Illinois Certification #: 200011 Indiana Certification #: C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky DW Certification #: 90062 Kentucky WW Certification #: 90062 Louisiana DEQ Certification #: 03086 Louisiana DW Certification #: MN00064 Maine Certification #: MN00064 Maryland Certification #: 322 Massachusetts Certification #: M-MN064 Michigan Certification #: 9909 Minnesota Certification #: 027-053-137 Minnesota Dept of Ag Certifcation #: via MN 027-053-137 Minnesota Petrofund Certification #: 1240 Mississippi Certification #: MN00064 Missouri Certification #: 10100 Montana Certification #: CERT0092 Nebraska Certification #: NE-OS-18-06 Nevada Certification #: MN00064 New Hampshire Certification #: 2081 New Jersey Certification #: MN002 New York Certification #: 11647 North Carolina DW Certification #: 27700 North Carolina WW Certification #: 530 North Dakota Certification #: R-036 Ohio DW Certification #: 41244 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Primary Certification #: MN300001 Oregon Secondary Certification #: MN200001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification #: MN00064 South Carolina Certification #:74003001 Tennessee Certification #: TN02818 Texas Certification #: T104704192 Utah Certification #: MN00064 Vermont Certification #: VT-027053137 Virginia Certification #: 460163 Washington Certification #: C486 West Virginia DEP Certification #: 382 West Virginia DW Certification #: 9952 C Wisconsin Certification #: 999407970 Wyoming UST Certification #: via A2LA 2926.01 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 15 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92427929 HIGHLAND MILL-Revised Report Lab ID Sample ID Matrix Date Collected Date Received 92427929001 U1-1 #0795 Air 05/04/19 11:00 05/06/19 11:25 92427929002 U2-1 #3606 Air 05/04/19 11:00 05/06/19 11:25 92427929003 U3-1 #1740 Air 05/04/19 11:00 05/06/19 11:25 92427929004 U4-1 #0839 Air 05/04/19 11:00 05/06/19 11:25 92427929005 U4-1 DUP #1203 Air 05/04/19 11:00 05/06/19 11:25 92427929006 U5-1 #0581 Air 05/04/19 11:00 05/06/19 11:25 92427929007 U6-1 #0352 Air 05/04/19 11:00 05/06/19 11:25 92427929008 U7-1 #1622 Air 05/04/19 11:00 05/06/19 11:25 92427929009 AA-1 #3317 Air 05/04/19 11:00 05/06/19 11:25 92427929010 UNUSED AIR CAN #2020 Air 05/04/19 11:00 05/06/19 11:25 92427929011 0795 Cert Air 05/06/19 00:00 05/06/19 10:41 92427929012 3606 Cert Air 05/06/19 00:00 05/06/19 10:41 92427929013 1740 Cert Air 05/06/19 00:00 05/06/19 10:41 92427929014 0839 Cert Air 05/06/19 00:00 05/06/19 10:41 92427929015 1203 Cert Air 05/06/19 00:00 05/06/19 10:41 92427929016 0581 Cert Air 05/06/19 00:00 05/06/19 10:41 92427929017 0352 Cert Air 05/06/19 00:00 05/06/19 10:41 92427929018 1622 Cert Air 05/06/19 00:00 05/06/19 10:41 92427929019 3317 Cert Air 05/06/19 00:00 05/06/19 10:41 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 15 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92427929 HIGHLAND MILL-Revised Report Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92427929001 U1-1 #0795 TO-15 6 PASI-MMJL 92427929002 U2-1 #3606 TO-15 6 PASI-MMJL 92427929003 U3-1 #1740 TO-15 6 PASI-MMJL 92427929004 U4-1 #0839 TO-15 6 PASI-MMJL 92427929005 U4-1 DUP #1203 TO-15 6 PASI-MMJL 92427929006 U5-1 #0581 TO-15 6 PASI-MMJL 92427929007 U6-1 #0352 TO-15 6 PASI-MMJL 92427929008 U7-1 #1622 TO-15 6 PASI-MMJL 92427929009 AA-1 #3317 TO-15 6 PASI-MMJL 92427929011 0795 Cert TO-15 6 PASI-MCH1 92427929012 3606 Cert TO-15 6 PASI-MCH1 92427929013 1740 Cert TO-15 6 PASI-MCH1 92427929014 0839 Cert TO-15 6 PASI-MCH1 92427929015 1203 Cert TO-15 6 PASI-MCH1 92427929016 0581 Cert TO-15 6 PASI-MCH1 92427929017 0352 Cert TO-15 6 PASI-MCH1 92427929018 1622 Cert TO-15 6 PASI-MCH1 92427929019 3317 Cert TO-15 6 PASI-MCH1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 15 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92427929 HIGHLAND MILL-Revised Report Sample:U1-1 #0795 Lab ID:92427929001 Collected:05/04/19 11:00 Received:05/06/19 11:25 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15TO15 MSV AIR 1,1-Dichloroethene ND ug/m3 05/10/19 21:23 75-35-41.2 0.42 1.52 cis-1,2-Dichloroethene ND ug/m3 05/10/19 21:23 156-59-21.2 0.33 1.52 trans-1,2-Dichloroethene ND ug/m3 05/10/19 21:23 156-60-51.2 0.43 1.52 Tetrachloroethene ND ug/m3 05/10/19 21:23 127-18-41.0 0.48 1.52 Trichloroethene ND ug/m3 05/10/19 21:23 79-01-61.7 0.39 1.52 Vinyl chloride ND ug/m3 05/10/19 21:23 75-01-40.40 0.19 1.52 Sample:U2-1 #3606 Lab ID:92427929002 Collected:05/04/19 11:00 Received:05/06/19 11:25 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15TO15 MSV AIR 1,1-Dichloroethene ND ug/m3 05/10/19 21:49 75-35-41.3 0.44 1.61 cis-1,2-Dichloroethene ND ug/m3 05/10/19 21:49 156-59-21.3 0.35 1.61 trans-1,2-Dichloroethene ND ug/m3 05/10/19 21:49 156-60-51.3 0.46 1.61 Tetrachloroethene ND ug/m3 05/10/19 21:49 127-18-41.1 0.51 1.61 Trichloroethene ND ug/m3 05/10/19 21:49 79-01-61.8 0.41 1.61 Vinyl chloride ND ug/m3 05/10/19 21:49 75-01-40.42 0.20 1.61 Sample:U3-1 #1740 Lab ID:92427929003 Collected:05/04/19 11:00 Received:05/06/19 11:25 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15TO15 MSV AIR 1,1-Dichloroethene ND ug/m3 05/10/19 22:16 75-35-41.3 0.43 1.58 cis-1,2-Dichloroethene ND ug/m3 05/10/19 22:16 156-59-21.3 0.35 1.58 trans-1,2-Dichloroethene ND ug/m3 05/10/19 22:16 156-60-51.3 0.45 1.58 Tetrachloroethene ND ug/m3 05/10/19 22:16 127-18-41.1 0.50 1.58 Trichloroethene ND ug/m3 05/10/19 22:16 79-01-61.7 0.41 1.58 Vinyl chloride ND ug/m3 05/10/19 22:16 75-01-40.41 0.20 1.58 Sample:U4-1 #0839 Lab ID:92427929004 Collected:05/04/19 11:00 Received:05/06/19 11:25 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15TO15 MSV AIR 1,1-Dichloroethene ND ug/m3 05/10/19 22:42 75-35-41.3 0.43 1.58 cis-1,2-Dichloroethene ND ug/m3 05/10/19 22:42 156-59-21.3 0.35 1.58 trans-1,2-Dichloroethene ND ug/m3 05/10/19 22:42 156-60-51.3 0.45 1.58 Tetrachloroethene ND ug/m3 05/10/19 22:42 127-18-41.1 0.50 1.58 Trichloroethene ND ug/m3 05/10/19 22:42 79-01-61.7 0.41 1.58 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/20/2019 01:03 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 15 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92427929 HIGHLAND MILL-Revised Report Sample:U4-1 #0839 Lab ID:92427929004 Collected:05/04/19 11:00 Received:05/06/19 11:25 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15TO15 MSV AIR Vinyl chloride ND ug/m3 05/10/19 22:42 75-01-40.41 0.20 1.58 Sample:U4-1 DUP #1203 Lab ID:92427929005 Collected:05/04/19 11:00 Received:05/06/19 11:25 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15TO15 MSV AIR 1,1-Dichloroethene ND ug/m3 05/10/19 23:09 75-35-41.3 0.43 1.58 cis-1,2-Dichloroethene ND ug/m3 05/10/19 23:09 156-59-21.3 0.35 1.58 trans-1,2-Dichloroethene ND ug/m3 05/10/19 23:09 156-60-51.3 0.45 1.58 Tetrachloroethene ND ug/m3 05/10/19 23:09 127-18-41.1 0.50 1.58 Trichloroethene ND ug/m3 05/10/19 23:09 79-01-61.7 0.41 1.58 Vinyl chloride ND ug/m3 05/10/19 23:09 75-01-40.41 0.20 1.58 Sample:U5-1 #0581 Lab ID:92427929006 Collected:05/04/19 11:00 Received:05/06/19 11:25 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15TO15 MSV AIR 1,1-Dichloroethene ND ug/m3 05/10/19 23:35 75-35-41.3 0.44 1.61 cis-1,2-Dichloroethene ND ug/m3 05/10/19 23:35 156-59-21.3 0.35 1.61 trans-1,2-Dichloroethene ND ug/m3 05/10/19 23:35 156-60-51.3 0.46 1.61 Tetrachloroethene ND ug/m3 05/10/19 23:35 127-18-41.1 0.51 1.61 Trichloroethene ND ug/m3 05/10/19 23:35 79-01-61.8 0.41 1.61 Vinyl chloride ND ug/m3 05/10/19 23:35 75-01-40.42 0.20 1.61 Sample:U6-1 #0352 Lab ID:92427929007 Collected:05/04/19 11:00 Received:05/06/19 11:25 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15TO15 MSV AIR 1,1-Dichloroethene ND ug/m3 05/11/19 00:01 75-35-41.3 0.45 1.64 cis-1,2-Dichloroethene ND ug/m3 05/11/19 00:01 156-59-21.3 0.36 1.64 trans-1,2-Dichloroethene ND ug/m3 05/11/19 00:01 156-60-51.3 0.47 1.64 Tetrachloroethene ND ug/m3 05/11/19 00:01 127-18-41.1 0.51 1.64 Trichloroethene ND ug/m3 05/11/19 00:01 79-01-61.8 0.42 1.64 Vinyl chloride ND ug/m3 05/11/19 00:01 75-01-40.43 0.21 1.64 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/20/2019 01:03 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 15 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92427929 HIGHLAND MILL-Revised Report Sample:U7-1 #1622 Lab ID:92427929008 Collected:05/04/19 11:00 Received:05/06/19 11:25 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15TO15 MSV AIR 1,1-Dichloroethene ND ug/m3 05/11/19 00:28 75-35-41.3 0.43 1.58 cis-1,2-Dichloroethene ND ug/m3 05/11/19 00:28 156-59-21.3 0.35 1.58 trans-1,2-Dichloroethene ND ug/m3 05/11/19 00:28 156-60-51.3 0.45 1.58 Tetrachloroethene ND ug/m3 05/11/19 00:28 127-18-41.1 0.50 1.58 Trichloroethene ND ug/m3 05/11/19 00:28 79-01-61.7 0.41 1.58 Vinyl chloride ND ug/m3 05/11/19 00:28 75-01-40.41 0.20 1.58 Sample:AA-1 #3317 Lab ID:92427929009 Collected:05/04/19 11:00 Received:05/06/19 11:25 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15TO15 MSV AIR 1,1-Dichloroethene ND ug/m3 05/11/19 00:55 75-35-41.2 0.42 1.55 cis-1,2-Dichloroethene ND ug/m3 05/11/19 00:55 156-59-21.2 0.34 1.55 trans-1,2-Dichloroethene ND ug/m3 05/11/19 00:55 156-60-51.2 0.44 1.55 Tetrachloroethene 0.79J ug/m3 05/11/19 00:55 127-18-41.1 0.49 1.55 Trichloroethene ND ug/m3 05/11/19 00:55 79-01-61.7 0.40 1.55 Vinyl chloride ND ug/m3 05/11/19 00:55 75-01-40.40 0.20 1.55 Sample:0795 Cert Lab ID:92427929011 Collected:05/06/19 00:00 Received:05/06/19 10:41 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15Individual Can Certification 1,1-Dichloroethene ND ug/m3 04/06/19 21:51 75-35-40.40 0.14 0.5 cis-1,2-Dichloroethene ND ug/m3 04/06/19 21:51 156-59-20.40 0.11 0.5 trans-1,2-Dichloroethene ND ug/m3 04/06/19 21:51 156-60-50.40 0.14 0.5 Tetrachloroethene ND ug/m3 04/06/19 21:51 127-18-40.34 0.16 0.5 Trichloroethene ND ug/m3 04/06/19 21:51 79-01-60.27 0.13 0.5 Vinyl chloride ND ug/m3 04/06/19 21:51 75-01-40.13 0.063 0.5 Sample:3606 Cert Lab ID:92427929012 Collected:05/06/19 00:00 Received:05/06/19 10:41 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15Individual Can Certification 1,1-Dichloroethene ND ug/m3 04/01/19 02:59 75-35-40.40 0.14 0.5 cis-1,2-Dichloroethene ND ug/m3 04/01/19 02:59 156-59-20.40 0.11 0.5 trans-1,2-Dichloroethene ND ug/m3 04/01/19 02:59 156-60-50.40 0.14 0.5 Tetrachloroethene ND ug/m3 04/01/19 02:59 127-18-40.34 0.16 0.5 Trichloroethene ND ug/m3 04/01/19 02:59 79-01-60.27 0.13 0.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/20/2019 01:03 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 15 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92427929 HIGHLAND MILL-Revised Report Sample:3606 Cert Lab ID:92427929012 Collected:05/06/19 00:00 Received:05/06/19 10:41 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15Individual Can Certification Vinyl chloride ND ug/m3 04/01/19 02:59 75-01-40.13 0.063 0.5 Sample:1740 Cert Lab ID:92427929013 Collected:05/06/19 00:00 Received:05/06/19 10:41 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15Individual Can Certification 1,1-Dichloroethene ND ug/m3 03/31/19 17:30 75-35-40.40 0.14 0.5 cis-1,2-Dichloroethene ND ug/m3 03/31/19 17:30 156-59-20.40 0.11 0.5 trans-1,2-Dichloroethene ND ug/m3 03/31/19 17:30 156-60-50.40 0.14 0.5 Tetrachloroethene ND ug/m3 03/31/19 17:30 127-18-40.34 0.16 0.5 Trichloroethene ND ug/m3 03/31/19 17:30 79-01-60.27 0.13 0.5 Vinyl chloride ND ug/m3 03/31/19 17:30 75-01-40.13 0.063 0.5 Sample:0839 Cert Lab ID:92427929014 Collected:05/06/19 00:00 Received:05/06/19 10:41 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15Individual Can Certification 1,1-Dichloroethene ND ug/m3 04/07/19 04:48 75-35-40.40 0.14 0.5 cis-1,2-Dichloroethene ND ug/m3 04/07/19 04:48 156-59-20.40 0.11 0.5 trans-1,2-Dichloroethene ND ug/m3 04/07/19 04:48 156-60-50.40 0.14 0.5 Tetrachloroethene ND ug/m3 04/07/19 04:48 127-18-40.34 0.16 0.5 Trichloroethene ND ug/m3 04/07/19 04:48 79-01-60.27 0.13 0.5 Vinyl chloride ND ug/m3 04/07/19 04:48 75-01-40.13 0.063 0.5 Sample:1203 Cert Lab ID:92427929015 Collected:05/06/19 00:00 Received:05/06/19 10:41 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15Individual Can Certification 1,1-Dichloroethene ND ug/m3 04/07/19 02:19 75-35-40.40 0.14 0.5 cis-1,2-Dichloroethene ND ug/m3 04/07/19 02:19 156-59-20.40 0.11 0.5 trans-1,2-Dichloroethene ND ug/m3 04/07/19 02:19 156-60-50.40 0.14 0.5 Tetrachloroethene ND ug/m3 04/07/19 02:19 127-18-40.34 0.16 0.5 Trichloroethene ND ug/m3 04/07/19 02:19 79-01-60.27 0.13 0.5 Vinyl chloride ND ug/m3 04/07/19 02:19 75-01-40.13 0.063 0.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/20/2019 01:03 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 15 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92427929 HIGHLAND MILL-Revised Report Sample:0581 Cert Lab ID:92427929016 Collected:05/06/19 00:00 Received:05/06/19 10:41 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15Individual Can Certification 1,1-Dichloroethene ND ug/m3 04/05/19 09:13 75-35-40.40 0.14 0.5 cis-1,2-Dichloroethene ND ug/m3 04/05/19 09:13 156-59-20.40 0.11 0.5 trans-1,2-Dichloroethene ND ug/m3 04/05/19 09:13 156-60-50.40 0.14 0.5 Tetrachloroethene ND ug/m3 04/05/19 09:13 127-18-40.34 0.16 0.5 Trichloroethene ND ug/m3 04/05/19 09:13 79-01-60.27 0.13 0.5 Vinyl chloride ND ug/m3 04/05/19 09:13 75-01-40.13 0.063 0.5 Sample:0352 Cert Lab ID:92427929017 Collected:05/06/19 00:00 Received:05/06/19 10:41 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15Individual Can Certification 1,1-Dichloroethene ND ug/m3 04/06/19 09:47 75-35-40.40 0.14 0.5 cis-1,2-Dichloroethene ND ug/m3 04/06/19 09:47 156-59-20.40 0.11 0.5 trans-1,2-Dichloroethene ND ug/m3 04/06/19 09:47 156-60-50.40 0.14 0.5 Tetrachloroethene ND ug/m3 04/06/19 09:47 127-18-40.34 0.16 0.5 Trichloroethene ND ug/m3 04/06/19 09:47 79-01-60.27 0.13 0.5 Vinyl chloride ND ug/m3 04/06/19 09:47 75-01-40.13 0.063 0.5 Sample:1622 Cert Lab ID:92427929018 Collected:05/06/19 00:00 Received:05/06/19 10:41 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15Individual Can Certification 1,1-Dichloroethene ND ug/m3 03/31/19 21:54 75-35-40.40 0.14 0.5 cis-1,2-Dichloroethene ND ug/m3 03/31/19 21:54 156-59-20.40 0.11 0.5 trans-1,2-Dichloroethene ND ug/m3 03/31/19 21:54 156-60-50.40 0.14 0.5 Tetrachloroethene ND ug/m3 03/31/19 21:54 127-18-40.34 0.16 0.5 Trichloroethene ND ug/m3 03/31/19 21:54 79-01-60.27 0.13 0.5 Vinyl chloride ND ug/m3 03/31/19 21:54 75-01-40.13 0.063 0.5 Sample:3317 Cert Lab ID:92427929019 Collected:05/06/19 00:00 Received:05/06/19 10:41 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15Individual Can Certification 1,1-Dichloroethene ND ug/m3 04/04/19 08:42 75-35-40.40 0.14 0.5 cis-1,2-Dichloroethene ND ug/m3 04/04/19 08:42 156-59-20.40 0.11 0.5 trans-1,2-Dichloroethene ND ug/m3 04/04/19 08:42 156-60-50.40 0.14 0.5 Tetrachloroethene ND ug/m3 04/04/19 08:42 127-18-40.34 0.16 0.5 Trichloroethene ND ug/m3 04/04/19 08:42 79-01-60.27 0.13 0.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/20/2019 01:03 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 15 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92427929 HIGHLAND MILL-Revised Report Sample:3317 Cert Lab ID:92427929019 Collected:05/06/19 00:00 Received:05/06/19 10:41 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15Individual Can Certification Vinyl chloride ND ug/m3 04/04/19 08:42 75-01-40.13 0.063 0.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/20/2019 01:03 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 15 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92427929 HIGHLAND MILL-Revised Report Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 605174 TO-15 TO-15 TO15 MSV AIR Low Level Associated Lab Samples:92427929001, 92427929002, 92427929003, 92427929004, 92427929005, 92427929006, 92427929007, 92427929008, 92427929009 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3271512 Associated Lab Samples:92427929001, 92427929002, 92427929003, 92427929004, 92427929005, 92427929006, 92427929007, 92427929008, 92427929009 Matrix:Air AnalyzedMDL 1,1-Dichloroethene ug/m3 ND 0.40 05/10/19 11:270.14 cis-1,2-Dichloroethene ug/m3 ND 0.40 05/10/19 11:270.11 Tetrachloroethene ug/m3 ND 0.34 05/10/19 11:270.16 trans-1,2-Dichloroethene ug/m3 ND 0.40 05/10/19 11:270.14 Trichloroethene ug/m3 ND 0.55 MN05/10/19 11:270.13 Vinyl chloride ug/m3 ND 0.13 05/10/19 11:270.063 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3271513LABORATORY CONTROL SAMPLE: LCSSpike 1,1-Dichloroethene ug/m3 38.440.3 95 70-130 cis-1,2-Dichloroethene ug/m3 39.440.3 98 70-130 Tetrachloroethene ug/m3 71.168.9 103 70-130 trans-1,2-Dichloroethene ug/m3 39.640.3 98 70-130 Trichloroethene ug/m3 54.154.6 99 70-130 Vinyl chloride ug/m3 24.926 96 70-130 Parameter Units Dup Result Max RPD QualifiersRPDResult 60301731001 3272256SAMPLE DUPLICATE: 1,1-Dichloroethene ug/m3 ND 25ND cis-1,2-Dichloroethene ug/m3 ND 25ND Tetrachloroethene ug/m3 52.4 0 2552.4 trans-1,2-Dichloroethene ug/m3 ND 25ND Trichloroethene ug/m3 ND 25ND Vinyl chloride ug/m3 ND 25ND Parameter Units Dup Result Max RPD QualifiersRPDResult 60301731002 3272257SAMPLE DUPLICATE: 1,1-Dichloroethene ug/m3 ND 25ND cis-1,2-Dichloroethene ug/m3 ND 25ND Tetrachloroethene ug/m3 43.5 6 2540.9 trans-1,2-Dichloroethene ug/m3 ND 25ND Trichloroethene ug/m3 ND 25ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/20/2019 01:03 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 15 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92427929 HIGHLAND MILL-Revised Report Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result Max RPD QualifiersRPDResult 60301731002 3272257SAMPLE DUPLICATE: Vinyl chloride ug/m3 ND 25ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/20/2019 01:03 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 15 #=QL# QUALIFIERS Pace Project No.: Project: 92427929 HIGHLAND MILL-Revised Report DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - MinneapolisPASI-M ANALYTE QUALIFIERS The reporting limit has been raised in accordance with Minnesota Statutes 4740.2100 Subpart 8. C, D. Reporting Limit Evaluation Rule.MN REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/20/2019 01:03 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 15 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92427929 HIGHLAND MILL-Revised Report Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92427929001 605174U1-1 #0795 TO-15 92427929002 605174U2-1 #3606 TO-15 92427929003 605174U3-1 #1740 TO-15 92427929004 605174U4-1 #0839 TO-15 92427929005 605174U4-1 DUP #1203 TO-15 92427929006 605174U5-1 #0581 TO-15 92427929007 605174U6-1 #0352 TO-15 92427929008 605174U7-1 #1622 TO-15 92427929009 605174AA-1 #3317 TO-15 92427929011 6050970795 Cert TO-15 92427929012 6050973606 Cert TO-15 92427929013 6050971740 Cert TO-15 92427929014 6050970839 Cert TO-15 92427929015 6050971203 Cert TO-15 92427929016 6050970581 Cert TO-15 92427929017 6050970352 Cert TO-15 92427929018 6050971622 Cert TO-15 92427929019 6050973317 Cert TO-15 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/20/2019 01:03 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 15 Page 15 of 15 5/8/19 #=CL# May 20, 2019 LIMS USE: FR - PATRICK LOWERY LIMS OBJECT ID: 92427931 92427931 Project: Pace Project No.: RE: Patrick Lowery Summit Engineering 101 Rice Bent Way Unit 9 Columbia, SC 29229 HIGHLAND MILL-Revised Report Dear Patrick Lowery: Enclosed are the analytical results for sample(s) received by the laboratory on May 06, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Report revised to add MDLs and Jflags. If you have any questions concerning this report, please feel free to contact me. Sincerely, Taylor Ezell taylor.ezell@pacelabs.com Project Manager (704)875-9092 Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 15 #=CP# CERTIFICATIONS Pace Project No.: Project: 92427931 HIGHLAND MILL-Revised Report Minnesota Certification IDs 1700 Elm Street SE, Minneapolis, MN 55414-2485 A2LA Certification #: 2926.01 Alabama Certification #: 40770 Alaska Contaminated Sites Certification #: 17-009 Alaska DW Certification #: MN00064 Arizona Certification #: AZ0014 Arkansas DW Certification #: MN00064 Arkansas WW Certification #: 88-0680 California Certification #: 2929 CNMI Saipan Certification #: MP0003 Colorado Certification #: MN00064 Connecticut Certification #: PH-0256 EPA Region 8+Wyoming DW Certification #: via MN 027- 053-137 Florida Certification #: E87605 Georgia Certification #: 959 Guam EPA Certification #: MN00064 Hawaii Certification #: MN00064 Idaho Certification #: MN00064 Illinois Certification #: 200011 Indiana Certification #: C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky DW Certification #: 90062 Kentucky WW Certification #: 90062 Louisiana DEQ Certification #: 03086 Louisiana DW Certification #: MN00064 Maine Certification #: MN00064 Maryland Certification #: 322 Massachusetts Certification #: M-MN064 Michigan Certification #: 9909 Minnesota Certification #: 027-053-137 Minnesota Dept of Ag Certifcation #: via MN 027-053-137 Minnesota Petrofund Certification #: 1240 Mississippi Certification #: MN00064 Missouri Certification #: 10100 Montana Certification #: CERT0092 Nebraska Certification #: NE-OS-18-06 Nevada Certification #: MN00064 New Hampshire Certification #: 2081 New Jersey Certification #: MN002 New York Certification #: 11647 North Carolina DW Certification #: 27700 North Carolina WW Certification #: 530 North Dakota Certification #: R-036 Ohio DW Certification #: 41244 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Primary Certification #: MN300001 Oregon Secondary Certification #: MN200001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification #: MN00064 South Carolina Certification #:74003001 Tennessee Certification #: TN02818 Texas Certification #: T104704192 Utah Certification #: MN00064 Vermont Certification #: VT-027053137 Virginia Certification #: 460163 Washington Certification #: C486 West Virginia DEP Certification #: 382 West Virginia DW Certification #: 9952 C Wisconsin Certification #: 999407970 Wyoming UST Certification #: via A2LA 2926.01 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 15 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92427931 HIGHLAND MILL-Revised Report Lab ID Sample ID Matrix Date Collected Date Received 92427931001 HMSG-1 #1454 Air 05/03/19 13:05 05/06/19 11:25 92427931002 HMSG-1 DUP #1439 Air 05/03/19 13:05 05/06/19 11:25 92427931003 HMSG-2 #3815 Air 05/03/19 12:35 05/06/19 11:25 92427931004 1454 Cert Air 05/06/19 00:00 05/06/19 10:41 92427931005 1439 Cert Air 05/06/19 00:00 05/06/19 10:41 92427931006 3815 Cert Air 05/06/19 00:00 05/06/19 10:41 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 15 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92427931 HIGHLAND MILL-Revised Report Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92427931001 HMSG-1 #1454 TO-15 27 PASI-MMJL 92427931002 HMSG-1 DUP #1439 TO-15 27 PASI-MMJL 92427931003 HMSG-2 #3815 TO-15 27 PASI-MMJL 92427931004 1454 Cert TO-15 27 PASI-MCH1 92427931005 1439 Cert TO-15 27 PASI-MCH1 92427931006 3815 Cert TO-15 27 PASI-MCH1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 15 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92427931 HIGHLAND MILL-Revised Report Sample:HMSG-1 #1454 Lab ID:92427931001 Collected:05/03/19 13:05 Received:05/06/19 11:25 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15TO15 MSV AIR Acetone 784 ug/m3 05/12/19 07:50 67-64-18.4 4.2 3.48 Benzene 3.8 ug/m3 05/11/19 17:41 71-43-20.57 0.27 1.74 2-Butanone (MEK)35.3 ug/m3 05/11/19 17:41 78-93-35.2 0.64 1.74 Carbon disulfide 7.0 ug/m3 05/11/19 17:41 75-15-01.1 0.38 1.74 Chloromethane 3.9 ug/m3 05/11/19 17:41 74-87-30.73 0.27 1.74 Cyclohexane 11.2 ug/m3 05/11/19 17:41 110-82-73.0 0.61 1.74 Dichlorodifluoromethane 2.0 ug/m3 05/11/19 17:41 75-71-81.8 0.51 1.74 cis-1,2-Dichloroethene 1.7 ug/m3 05/11/19 17:41 156-59-21.4 0.38 1.74 Ethylbenzene 12.9 ug/m3 05/11/19 17:41 100-41-41.5 0.53 1.74 4-Ethyltoluene 6.7 ug/m3 05/11/19 17:41 622-96-84.4 0.99 1.74 n-Heptane 7.6 ug/m3 05/11/19 17:41 142-82-51.4 0.66 1.74 n-Hexane 15.7 ug/m3 05/11/19 17:41 110-54-31.2 0.54 1.74 2-Hexanone ND ug/m3 05/11/19 17:41 591-78-67.2 1.3 1.74 Methylene Chloride 303 ug/m3 05/11/19 17:41 75-09-26.1 1.6 1.74 4-Methyl-2-pentanone (MIBK)4.2J ug/m3 05/11/19 17:41 108-10-17.2 0.90 1.74 Naphthalene 2.9J ug/m3 05/11/19 17:41 91-20-34.6 2.3 1.74 Propylene ND ug/m3 05/11/19 17:41 115-07-10.61 0.25 1.74 Styrene 2.0 ug/m3 05/11/19 17:41 100-42-51.5 0.60 1.74 Tetrachloroethene 1.5 ug/m3 05/11/19 17:41 127-18-41.2 0.55 1.74 Toluene 244 ug/m3 05/12/19 07:50 108-88-32.7 1.2 3.48 Trichloroethene 2.0 ug/m3 05/11/19 17:41 79-01-61.9 0.45 1.74 Trichlorofluoromethane 1.9J ug/m3 05/11/19 17:41 75-69-42.0 0.64 1.74 1,2,4-Trimethylbenzene 24.8 ug/m3 05/11/19 17:41 95-63-61.7 0.79 1.74 1,3,5-Trimethylbenzene 7.4 ug/m3 05/11/19 17:41 108-67-81.7 0.69 1.74 Vinyl chloride ND ug/m3 05/11/19 17:41 75-01-40.45 0.22 1.74 m&p-Xylene 64.0 ug/m3 05/11/19 17:41 179601-23-13.1 1.2 1.74 o-Xylene 26.2 ug/m3 05/11/19 17:41 95-47-61.5 0.60 1.74 Sample:HMSG-1 DUP #1439 Lab ID:92427931002 Collected:05/03/19 13:05 Received:05/06/19 11:25 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15TO15 MSV AIR Acetone 102 ug/m3 05/11/19 18:08 67-64-16.4 3.2 2.66 Benzene 1.9 ug/m3 05/11/19 18:08 71-43-20.86 0.41 2.66 2-Butanone (MEK)54.3 ug/m3 05/11/19 18:08 78-93-38.0 0.98 2.66 Carbon disulfide 69.9 ug/m3 05/11/19 18:08 75-15-01.7 0.58 2.66 Chloromethane 0.88J ug/m3 05/11/19 18:08 74-87-31.1 0.41 2.66 Cyclohexane ND ug/m3 05/11/19 18:08 110-82-74.7 0.94 2.66 Dichlorodifluoromethane 1.9J ug/m3 05/11/19 18:08 75-71-82.7 0.78 2.66 cis-1,2-Dichloroethene ND ug/m3 05/11/19 18:08 156-59-22.1 0.58 2.66 Ethylbenzene 5.4 ug/m3 05/11/19 18:08 100-41-42.3 0.81 2.66 4-Ethyltoluene 3.3J ug/m3 05/11/19 18:08 622-96-86.6 1.5 2.66 n-Heptane 1.5J ug/m3 05/11/19 18:08 142-82-52.2 1.0 2.66 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/20/2019 01:03 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 15 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92427931 HIGHLAND MILL-Revised Report Sample:HMSG-1 DUP #1439 Lab ID:92427931002 Collected:05/03/19 13:05 Received:05/06/19 11:25 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15TO15 MSV AIR n-Hexane 3.7 ug/m3 05/11/19 18:08 110-54-31.9 0.83 2.66 2-Hexanone ND ug/m3 05/11/19 18:08 591-78-611.1 2.0 2.66 Methylene Chloride 22.4 ug/m3 05/11/19 18:08 75-09-29.4 2.5 2.66 4-Methyl-2-pentanone (MIBK)2.2J ug/m3 05/11/19 18:08 108-10-111.1 1.4 2.66 Naphthalene 12.1 ug/m3 05/11/19 18:08 91-20-37.1 3.5 2.66 Propylene 5.2 ug/m3 05/11/19 18:08 115-07-10.93 0.38 2.66 Styrene ND ug/m3 05/11/19 18:08 100-42-52.3 0.92 2.66 Tetrachloroethene ND ug/m3 05/11/19 18:08 127-18-41.8 0.84 2.66 Toluene 22.4 ug/m3 05/11/19 18:08 108-88-32.0 0.93 2.66 Trichloroethene ND ug/m3 05/11/19 18:08 79-01-62.9 0.68 2.66 Trichlorofluoromethane ND ug/m3 05/11/19 18:08 75-69-43.0 0.97 2.66 1,2,4-Trimethylbenzene 13.1 ug/m3 05/11/19 18:08 95-63-62.7 1.2 2.66 1,3,5-Trimethylbenzene 4.4 ug/m3 05/11/19 18:08 108-67-82.7 1.1 2.66 Vinyl chloride ND ug/m3 05/11/19 18:08 75-01-40.69 0.34 2.66 m&p-Xylene 17.4 ug/m3 05/11/19 18:08 179601-23-14.7 1.9 2.66 o-Xylene 7.3 ug/m3 05/11/19 18:08 95-47-62.3 0.92 2.66 Sample:HMSG-2 #3815 Lab ID:92427931003 Collected:05/03/19 12:35 Received:05/06/19 11:25 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15TO15 MSV AIR Acetone 35.4 ug/m3 05/11/19 18:34 67-64-16.4 3.2 2.66 Benzene 9.4 ug/m3 05/11/19 18:34 71-43-20.86 0.41 2.66 2-Butanone (MEK)5.9J ug/m3 05/11/19 18:34 78-93-38.0 0.98 2.66 Carbon disulfide 2.8 ug/m3 05/11/19 18:34 75-15-01.7 0.58 2.66 Chloromethane ND ug/m3 05/11/19 18:34 74-87-31.1 0.41 2.66 Cyclohexane ND ug/m3 05/11/19 18:34 110-82-74.7 0.94 2.66 Dichlorodifluoromethane 1.6J ug/m3 05/11/19 18:34 75-71-82.7 0.78 2.66 cis-1,2-Dichloroethene 1.4J ug/m3 05/11/19 18:34 156-59-22.1 0.58 2.66 Ethylbenzene 14.6 ug/m3 05/11/19 18:34 100-41-42.3 0.81 2.66 4-Ethyltoluene 7.3 ug/m3 05/11/19 18:34 622-96-86.6 1.5 2.66 n-Heptane 56.0 ug/m3 05/11/19 18:34 142-82-52.2 1.0 2.66 n-Hexane 3.2 ug/m3 05/11/19 18:34 110-54-31.9 0.83 2.66 2-Hexanone ND ug/m3 05/11/19 18:34 591-78-611.1 2.0 2.66 Methylene Chloride 19.5 ug/m3 05/11/19 18:34 75-09-29.4 2.5 2.66 4-Methyl-2-pentanone (MIBK)ND ug/m3 05/11/19 18:34 108-10-111.1 1.4 2.66 Naphthalene 12.4 ug/m3 05/11/19 18:34 91-20-37.1 3.5 2.66 Propylene 0.62J ug/m3 05/11/19 18:34 115-07-10.93 0.38 2.66 Styrene ND ug/m3 05/11/19 18:34 100-42-52.3 0.92 2.66 Tetrachloroethene 124 ug/m3 05/11/19 18:34 127-18-41.8 0.84 2.66 Toluene 55.7 ug/m3 05/11/19 18:34 108-88-32.0 0.93 2.66 Trichloroethene ND ug/m3 05/11/19 18:34 79-01-62.9 0.68 2.66 Trichlorofluoromethane 2.2J ug/m3 05/11/19 18:34 75-69-43.0 0.97 2.66 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/20/2019 01:03 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 15 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92427931 HIGHLAND MILL-Revised Report Sample:HMSG-2 #3815 Lab ID:92427931003 Collected:05/03/19 12:35 Received:05/06/19 11:25 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15TO15 MSV AIR 1,2,4-Trimethylbenzene 5.8 ug/m3 05/11/19 18:34 95-63-62.7 1.2 2.66 1,3,5-Trimethylbenzene ND ug/m3 05/11/19 18:34 108-67-82.7 1.1 2.66 Vinyl chloride ND ug/m3 05/11/19 18:34 75-01-40.69 0.34 2.66 m&p-Xylene 12.5 ug/m3 05/11/19 18:34 179601-23-14.7 1.9 2.66 o-Xylene 3.4 ug/m3 05/11/19 18:34 95-47-62.3 0.92 2.66 Sample:1454 Cert Lab ID:92427931004 Collected:05/06/19 00:00 Received:05/06/19 10:41 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15Individual Can Certification Acetone ND ug/m3 03/25/19 16:25 67-64-12.4 1.2 1 Benzene ND ug/m3 03/25/19 16:25 71-43-20.32 0.15 1 2-Butanone (MEK)ND ug/m3 03/25/19 16:25 78-93-33.0 0.37 1 Carbon disulfide ND ug/m3 03/25/19 16:25 75-15-00.63 0.22 1 Chloromethane ND ug/m3 03/25/19 16:25 74-87-30.42 0.16 1 Cyclohexane ND ug/m3 03/25/19 16:25 110-82-71.8 0.35 1 Dichlorodifluoromethane ND ug/m3 03/25/19 16:25 75-71-81.0 0.29 1 cis-1,2-Dichloroethene ND ug/m3 03/25/19 16:25 156-59-20.81 0.22 1 Ethylbenzene ND ug/m3 03/25/19 16:25 100-41-40.88 0.30 1 4-Ethyltoluene ND ug/m3 03/25/19 16:25 622-96-82.5 0.57 1 n-Heptane ND ug/m3 03/25/19 16:25 142-82-50.83 0.38 1 n-Hexane ND ug/m3 03/25/19 16:25 110-54-30.72 0.31 1 2-Hexanone ND ug/m3 03/25/19 16:25 591-78-64.2 0.74 1 Methylene Chloride ND ug/m3 03/25/19 16:25 75-09-23.5 0.94 1 4-Methyl-2-pentanone (MIBK)ND ug/m3 03/25/19 16:25 108-10-14.2 0.52 1 Naphthalene 1.7J ug/m3 03/25/19 16:25 91-20-32.7 1.3 1 Propylene ND ug/m3 03/25/19 16:25 115-07-10.35 0.14 1 Styrene ND ug/m3 03/25/19 16:25 100-42-52.2 0.34 1 Tetrachloroethene ND ug/m3 03/25/19 16:25 127-18-40.69 0.31 1 Toluene ND ug/m3 03/25/19 16:25 108-88-30.77 0.35 1 Trichloroethene ND ug/m3 03/25/19 16:25 79-01-60.55 0.26 1 Trichlorofluoromethane ND ug/m3 03/25/19 16:25 75-69-41.1 0.37 1 1,2,4-Trimethylbenzene ND ug/m3 03/25/19 16:25 95-63-61.0 0.45 1 1,3,5-Trimethylbenzene ND ug/m3 03/25/19 16:25 108-67-81.0 0.40 1 Vinyl chloride ND ug/m3 03/25/19 16:25 75-01-40.26 0.13 1 m&p-Xylene ND ug/m3 03/25/19 16:25 179601-23-11.8 0.70 1 o-Xylene ND ug/m3 03/25/19 16:25 95-47-60.88 0.34 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/20/2019 01:03 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 15 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92427931 HIGHLAND MILL-Revised Report Sample:1439 Cert Lab ID:92427931005 Collected:05/06/19 00:00 Received:05/06/19 10:41 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15Individual Can Certification Acetone ND ug/m3 03/25/19 17:49 67-64-12.4 1.2 1 Benzene ND ug/m3 03/25/19 17:49 71-43-20.32 0.15 1 2-Butanone (MEK)ND ug/m3 03/25/19 17:49 78-93-33.0 0.37 1 Carbon disulfide ND ug/m3 03/25/19 17:49 75-15-00.63 0.22 1 Chloromethane ND ug/m3 03/25/19 17:49 74-87-30.42 0.16 1 Cyclohexane ND ug/m3 03/25/19 17:49 110-82-71.8 0.35 1 Dichlorodifluoromethane ND ug/m3 03/25/19 17:49 75-71-81.0 0.29 1 cis-1,2-Dichloroethene ND ug/m3 03/25/19 17:49 156-59-20.81 0.22 1 Ethylbenzene ND ug/m3 03/25/19 17:49 100-41-40.88 0.30 1 4-Ethyltoluene ND ug/m3 03/25/19 17:49 622-96-82.5 0.57 1 n-Heptane ND ug/m3 03/25/19 17:49 142-82-50.83 0.38 1 n-Hexane ND ug/m3 03/25/19 17:49 110-54-30.72 0.31 1 2-Hexanone ND ug/m3 03/25/19 17:49 591-78-64.2 0.74 1 Methylene Chloride ND ug/m3 03/25/19 17:49 75-09-23.5 0.94 1 4-Methyl-2-pentanone (MIBK)ND ug/m3 03/25/19 17:49 108-10-14.2 0.52 1 Naphthalene ND ug/m3 03/25/19 17:49 91-20-32.7 1.3 1 Propylene ND ug/m3 03/25/19 17:49 115-07-10.35 0.14 1 Styrene ND ug/m3 03/25/19 17:49 100-42-52.2 0.34 1 Tetrachloroethene ND ug/m3 03/25/19 17:49 127-18-40.69 0.31 1 Toluene ND ug/m3 03/25/19 17:49 108-88-30.77 0.35 1 Trichloroethene ND ug/m3 03/25/19 17:49 79-01-60.55 0.26 1 Trichlorofluoromethane ND ug/m3 03/25/19 17:49 75-69-41.1 0.37 1 1,2,4-Trimethylbenzene ND ug/m3 03/25/19 17:49 95-63-61.0 0.45 1 1,3,5-Trimethylbenzene ND ug/m3 03/25/19 17:49 108-67-81.0 0.40 1 Vinyl chloride ND ug/m3 03/25/19 17:49 75-01-40.26 0.13 1 m&p-Xylene ND ug/m3 03/25/19 17:49 179601-23-11.8 0.70 1 o-Xylene ND ug/m3 03/25/19 17:49 95-47-60.88 0.34 1 Sample:3815 Cert Lab ID:92427931006 Collected:05/06/19 00:00 Received:05/06/19 10:41 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15Individual Can Certification Acetone ND ug/m3 03/25/19 14:03 67-64-12.4 1.2 1 Benzene ND ug/m3 03/25/19 14:03 71-43-20.32 0.15 1 2-Butanone (MEK)ND ug/m3 03/25/19 14:03 78-93-33.0 0.37 1 Carbon disulfide ND ug/m3 03/25/19 14:03 75-15-00.63 0.22 1 Chloromethane ND ug/m3 03/25/19 14:03 74-87-30.42 0.16 1 Cyclohexane ND ug/m3 03/25/19 14:03 110-82-71.8 0.35 1 Dichlorodifluoromethane ND ug/m3 03/25/19 14:03 75-71-81.0 0.29 1 cis-1,2-Dichloroethene ND ug/m3 03/25/19 14:03 156-59-20.81 0.22 1 Ethylbenzene ND ug/m3 03/25/19 14:03 100-41-40.88 0.30 1 4-Ethyltoluene 0.70J ug/m3 03/25/19 14:03 622-96-82.5 0.57 1 n-Heptane ND ug/m3 03/25/19 14:03 142-82-50.83 0.38 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/20/2019 01:03 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 15 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92427931 HIGHLAND MILL-Revised Report Sample:3815 Cert Lab ID:92427931006 Collected:05/06/19 00:00 Received:05/06/19 10:41 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15Individual Can Certification n-Hexane ND ug/m3 03/25/19 14:03 110-54-30.72 0.31 1 2-Hexanone ND ug/m3 03/25/19 14:03 591-78-64.2 0.74 1 Methylene Chloride ND ug/m3 03/25/19 14:03 75-09-23.5 0.94 1 4-Methyl-2-pentanone (MIBK)ND ug/m3 03/25/19 14:03 108-10-14.2 0.52 1 Naphthalene 1.9J ug/m3 03/25/19 14:03 91-20-32.7 1.3 1 Propylene ND ug/m3 03/25/19 14:03 115-07-10.35 0.14 1 Styrene ND ug/m3 03/25/19 14:03 100-42-50.87 0.34 1 Tetrachloroethene ND ug/m3 03/25/19 14:03 127-18-40.69 0.31 1 Toluene ND ug/m3 03/25/19 14:03 108-88-30.77 0.35 1 Trichloroethene ND ug/m3 03/25/19 14:03 79-01-60.55 0.26 1 Trichlorofluoromethane ND ug/m3 03/25/19 14:03 75-69-41.1 0.37 1 1,2,4-Trimethylbenzene ND ug/m3 03/25/19 14:03 95-63-61.0 0.45 1 1,3,5-Trimethylbenzene ND ug/m3 03/25/19 14:03 108-67-81.0 0.40 1 Vinyl chloride ND ug/m3 03/25/19 14:03 75-01-40.26 0.13 1 m&p-Xylene ND ug/m3 03/25/19 14:03 179601-23-11.8 0.70 1 o-Xylene ND ug/m3 03/25/19 14:03 95-47-60.88 0.34 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/20/2019 01:03 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 15 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92427931 HIGHLAND MILL-Revised Report Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 605267 TO-15 TO-15 TO15 MSV AIR Low Level Associated Lab Samples:92427931001, 92427931002, 92427931003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3272373 Associated Lab Samples:92427931001, 92427931002, 92427931003 Matrix:Air AnalyzedMDL 1,2,4-Trimethylbenzene ug/m3 ND 1.0 05/11/19 09:320.45 1,3,5-Trimethylbenzene ug/m3 ND 1.0 05/11/19 09:320.40 2-Butanone (MEK)ug/m3 ND 3.0 05/11/19 09:320.37 2-Hexanone ug/m3 ND 4.2 05/11/19 09:320.74 4-Ethyltoluene ug/m3 ND 2.5 05/11/19 09:320.57 4-Methyl-2-pentanone (MIBK)ug/m3 ND 4.2 05/11/19 09:320.52 Acetone ug/m3 ND 2.4 05/11/19 09:321.2 Benzene ug/m3 ND 0.32 05/11/19 09:320.15 Carbon disulfide ug/m3 ND 0.63 05/11/19 09:320.22 Chloromethane ug/m3 ND 0.42 05/11/19 09:320.16 cis-1,2-Dichloroethene ug/m3 ND 0.81 05/11/19 09:320.22 Cyclohexane ug/m3 ND 1.8 05/11/19 09:320.35 Dichlorodifluoromethane ug/m3 ND 1.0 05/11/19 09:320.29 Ethylbenzene ug/m3 ND 0.88 05/11/19 09:320.30 m&p-Xylene ug/m3 ND 1.8 05/11/19 09:320.70 Methylene Chloride ug/m3 ND 3.5 05/11/19 09:320.94 n-Heptane ug/m3 ND 0.83 05/11/19 09:320.38 n-Hexane ug/m3 ND 0.72 05/11/19 09:320.31 Naphthalene ug/m3 ND 2.7 05/11/19 09:321.3 o-Xylene ug/m3 ND 0.88 05/11/19 09:320.34 Propylene ug/m3 ND 0.35 05/11/19 09:320.14 Styrene ug/m3 ND 0.87 05/11/19 09:320.34 Tetrachloroethene ug/m3 ND 0.69 05/11/19 09:320.31 Toluene ug/m3 ND 0.77 05/11/19 09:320.35 Trichloroethene ug/m3 ND 1.1 05/11/19 09:320.26 Trichlorofluoromethane ug/m3 ND 1.1 05/11/19 09:320.37 Vinyl chloride ug/m3 ND 0.26 05/11/19 09:320.13 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3272374LABORATORY CONTROL SAMPLE: LCSSpike 1,2,4-Trimethylbenzene ug/m3 53.550 107 70-134 1,3,5-Trimethylbenzene ug/m3 52.150 104 70-132 2-Butanone (MEK)ug/m3 32.030 107 70-130 2-Hexanone ug/m3 41.841.6 100 70-135 4-Ethyltoluene ug/m3 55.650 111 70-138 4-Methyl-2-pentanone (MIBK)ug/m3 40.141.6 96 70-131 Acetone ug/m3 102121 85 67-130 Benzene ug/m3 31.832.5 98 70-130 Carbon disulfide ug/m3 30.031.6 95 56-137 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/20/2019 01:03 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 15 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92427931 HIGHLAND MILL-Revised Report Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3272374LABORATORY CONTROL SAMPLE: LCSSpike Chloromethane ug/m3 19.921 95 66-130 cis-1,2-Dichloroethene ug/m3 40.040.3 99 70-130 Cyclohexane ug/m3 35.335 101 68-132 Dichlorodifluoromethane ug/m3 48.050.3 96 70-130 Ethylbenzene ug/m3 44.944.1 102 67-131 m&p-Xylene ug/m3 89.188.3 101 70-132 Methylene Chloride ug/m3 158177 89 65-130 n-Heptane ug/m3 38.041.7 91 65-130 n-Hexane ug/m3 33.735.8 94 66-130 Naphthalene ug/m3 59.853.3 112 56-130 o-Xylene ug/m3 44.744.1 101 70-130 Propylene ug/m3 16.617.5 95 67-130 Styrene ug/m3 47.743.3 110 69-136 Tetrachloroethene ug/m3 70.468.9 102 70-130 Toluene ug/m3 38.638.3 101 70-130 Trichloroethene ug/m3 54.654.6 100 70-130 Trichlorofluoromethane ug/m3 53.457.1 93 65-130 Vinyl chloride ug/m3 25.726 99 70-130 Parameter Units Dup Result Max RPD QualifiersRPDResult 30292263001 3272637SAMPLE DUPLICATE: 1,2,4-Trimethylbenzene ug/m3 11.3 7 2510.5 1,3,5-Trimethylbenzene ug/m3 3.1 2 253.1 2-Butanone (MEK)ug/m3 1.3J 25ND 2-Hexanone ug/m3 ND 25ND 4-Ethyltoluene ug/m3 3.2J 25ND 4-Methyl-2-pentanone (MIBK)ug/m3 ND 25ND Acetone ug/m3 6.8 6 256.4 Benzene ug/m3 0.28J 25ND Carbon disulfide ug/m3 ND 25ND Chloromethane ug/m3 ND 25ND cis-1,2-Dichloroethene ug/m3 ND 25ND Cyclohexane ug/m3 ND 25ND Dichlorodifluoromethane ug/m3 1.7 2 251.7 Ethylbenzene ug/m3 2.1 3 252.2 m&p-Xylene ug/m3 10.4 4 2510.1 Methylene Chloride ug/m3 2.3J 25ND n-Heptane ug/m3 ND 25ND n-Hexane ug/m3 1.1 6 251.2 Naphthalene ug/m3 2.1J 25ND o-Xylene ug/m3 4.2 3 254.1 Propylene ug/m3 ND 25ND Styrene ug/m3 ND 25ND Tetrachloroethene ug/m3 ND 25ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/20/2019 01:03 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 15 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92427931 HIGHLAND MILL-Revised Report Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result Max RPD QualifiersRPDResult 30292263001 3272637SAMPLE DUPLICATE: Toluene ug/m3 2.8 2 252.8 Trichloroethene ug/m3 0.83J 25ND Trichlorofluoromethane ug/m3 1.4J 25ND Vinyl chloride ug/m3 ND 25ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/20/2019 01:03 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 15 #=QL# QUALIFIERS Pace Project No.: Project: 92427931 HIGHLAND MILL-Revised Report DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - MinneapolisPASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/20/2019 01:03 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 15 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92427931 HIGHLAND MILL-Revised Report Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92427931001 605267HMSG-1 #1454 TO-15 92427931002 605267HMSG-1 DUP #1439 TO-15 92427931003 605267HMSG-2 #3815 TO-15 92427931004 6050971454 Cert TO-15 92427931005 6050971439 Cert TO-15 92427931006 6050973815 Cert TO-15 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/20/2019 01:03 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 15 Page 15 of 15 5/8/19 VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\Appendix VI - Risk.rtf APPENDIX VI RISK CALCULATOR Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID:Submittal Date: Reviewed By: 5/28/2019 Prepared By:Patrick Lowery SUMMIT ELT MZ HMSG-1 Highest Concentration (all sampling events) North Carolina Department of Environmental Quality Risk Calculator Highland Mill #3 N. Brevard and N. Davidson Brownfields 20037-16-060 February 2018 November 2017 EPA RSL Table North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 20037-16-060 Exposure Unit ID: HMSG-1 Highest Concentration (all sampling events) Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Combined Pathways Groundwater Combined Pathways Soil Combined Pathways Groundwater Combined Pathways Construction Worker Soil Combined Pathways Soil Combined Pathways Surface Water Combined Pathways Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS PRIMARY PATHWAYS Resident Non-Residential Worker User Defined Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Protection of Groundwater Use Protection of Surface Water North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 20037-16-060 Exposure Unit ID: HMSG-1 Highest Concentration (all sampling events) Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Justification for Exposure Point Concentration CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier)Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 784 Table 1.0 67-64-1 Acetone ug/m3 5/3/2019 5.8 Table 1.0 71-43-2 Benzene ug/m3 12/30/2018 12.5 Table 1.0 75-15-0 Carbon Disulfide ug/m3 2/28/2019 9.4 Table 1.0 74-87-3 Chloromethane ug/m3 3/28/2019 11.2 Table 1.0 110-82-7 Cyclohexane ug/m3 5/3/2019 2.9 Table 1.0 75-71-8 Dichlorodifluoromethane ug/m3 1/31/2019 6.3 Table 1.0 156-59-2 Dichloroethylene, 1,2-cis-ug/m3 2/28/2019 12.9 Table 1.0 100-41-4 Ethylbenzene ug/m3 5/3/2019 7.6 Table 1.0 142-82-5 Heptane, N-ug/m3 5/3/2019 363 Table 1.0 110-54-3 Hexane, N-ug/m3 12/30/2018 0 Table 1.0 591-78-6 Hexanone, 2-ug/m3 54.3 Table 1.0 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 5/3/2019 4.2 Table 1.0 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 5/3/2019 303 Table 1.0 75-09-2 Methylene Chloride ug/m3 5/3/2019 12.1 Table 1.0 91-20-3 ~Naphthalene ug/m3 5/3/2019 156 Table 1.0 115-07-1 Propylene ug/m3 12/7/2018 2 Table 1.0 100-42-5 Styrene ug/m3 5/3/2019 29.8 Table 1.0 127-18-4 Tetrachloroethylene ug/m3 12/30/2018 244 Table 1.0 108-88-3 Toluene ug/m3 5/3/2019 2 Table 1.0 79-01-6 Trichloroethylene ug/m3 5/3/2019 2.6 Table 1.0 75-69-4 Trichlorofluoromethane ug/m3 12/7/2018 24.8 Table 1.0 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 5/3/2019 7.4 Table 1.0 108-67-8 Trimethylbenzene, 1,3,5-ug/m3 5/3/2019 0 Table 1.0 75-01-4 Vinyl Chloride ug/m3 64 Table 1.0 106-42-3 Xylene, P-ug/m3 5/3/2019 64 Table 1.0 108-38-3 Xylene, m-ug/m3 5/3/2019 26.2 Table 1.0 95-47-6 Xylene, o-ug/m3 5/3/2019 Input Form 2E Soil Gas Exposure Point Concentration Table North Carolina DEQ Risk Calculator Summary of Risk Assessment Output Output Form 1A Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 20037-16-060 Exposure Unit ID: HMSG-1 Highest Concentration (all sampling events) Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil Combined Pathways NC NC NC Groundwater Combined Pathways*NC NC NC Soil Combined Pathways NC NC NC Groundwater Combined Pathways*NC NC NC Construction Worker Soil Combined Pathways NC NC NC Soil Combined Pathways NC NC NC Surface Water Combined Pathways*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 5.2E-06 2.7E-01 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC PRIMARY CALCULATORS Resident Non-Residential Worker User Defined 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk- based closure. Protection of Surface Water Exceedence of 2B at POE? Exceedence of 2B at POE? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target POE Concentrations Exceeded? Protection of Groundwater Use Exceedence of 2L at POE? Exceedence of 2L at POE? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 20037-16-060 Exposure Unit ID: HMSG-1 Highest Concentration (all sampling events) CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient67-64-1 Acetone 784 23.52 -6.5E+03 7.3E-0471-43-2 Benzene 5.8 0.174 3.6E-01 6.3E+00 4.8E-07 5.6E-03 75-15-0 Carbon Disulfide 12.5 0.375 -1.5E+02 5.1E-0474-87-3 Chloromethane 9.4 0.282 -1.9E+01 3.0E-03110-82-7 Cyclohexane 11.2 0.336 -1.3E+03 5.4E-0575-71-8 Dichlorodifluoromethane 2.9 0.087 -2.1E+01 8.3E-04 156-59-2 Dichloroethylene, 1,2-cis-6.3 0.189 --142-82-5 Heptane, N-7.6 0.228 -8.3E+01 5.5E-04110-54-3 Hexane, N-363 10.89 -1.5E+02 1.5E-02591-78-6 Hexanone, 2-0 0 -6.3E+00 0.0E+00 78-93-3 Methyl Ethyl Ketone (2-Butanone)54.3 1.629 -1.0E+03 3.1E-04108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)4.2 0.126 -6.3E+02 4.0E-05 75-09-2 Methylene Chloride 303 9.09 1.0E+02 1.3E+02 9.0E-08 1.5E-0291-20-3 ~Naphthalene 12.1 0.363 8.3E-02 6.3E-01 4.4E-06 1.2E-01115-07-1 Propylene 156 4.68 -6.3E+02 1.5E-03100-42-5 Styrene 2 0.06 -2.1E+02 5.8E-05 127-18-4 Tetrachloroethylene 29.8 0.894 1.1E+01 8.3E+00 8.3E-08 2.1E-02 108-88-3 Toluene 244 7.32 -1.0E+03 1.4E-03 79-01-6 Trichloroethylene 2 0.06 4.8E-01 4.2E-01 1.3E-07 2.9E-02 75-69-4 Trichlorofluoromethane 2.6 0.078 --95-63-6 Trimethylbenzene, 1,2,4-24.8 0.744 -1.3E+01 1.2E-02108-67-8 Trimethylbenzene, 1,3,5-7.4 0.222 -1.3E+01 3.5E-03 75-01-4 Vinyl Chloride 0 0 1.7E-01 2.1E+01 0.0E+00 0.0E+00 106-42-3 Xylene, P-64 1.92 -2.1E+01 1.8E-02108-38-3 Xylene, m-64 1.92 -2.1E+01 1.8E-0295-47-6 Xylene, o-26.2 0.786 -2.1E+01 7.5E-03 Cumulative:5.2E-06 2.7E-01 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID:Submittal Date: Reviewed By: 5/28/2019 Prepared By:Patrick Lowery SUMMIT ELT MZ HMSG-1 Last 4 Sampling Events North Carolina Department of Environmental Quality Risk Calculator Highland Mill #3 N. Brevard and N. Davidson Brownfields 20037-16-060 February 2018 November 2017 EPA RSL Table North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 20037-16-060 Exposure Unit ID: HMSG-1 Last 4 Sampling Events Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Combined Pathways Groundwater Combined Pathways Soil Combined Pathways Groundwater Combined Pathways Construction Worker Soil Combined Pathways Soil Combined Pathways Surface Water Combined Pathways Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS PRIMARY PATHWAYS Resident Non-Residential Worker User Defined Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Protection of Groundwater Use Protection of Surface Water North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 20037-16-060 Exposure Unit ID: HMSG-1 Last 4 Sampling Events Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Justification for Exposure Point Concentration CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier)Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 784 Table 1.0 67-64-1 Acetone ug/m3 5/3/2019 3.8 Table 1.0 71-43-2 Benzene ug/m3 5/3/2019 12.5 Table 1.0 75-15-0 Carbon Disulfide ug/m3 2/28/2019 3.9 Table 1.0 74-87-3 Chloromethane ug/m3 5/3/2019 2.9 Table 1.0 75-71-8 Dichlorodifluoromethane ug/m3 1/31/2019 6.3 Table 1.0 156-59-2 Dichloroethylene, 1,2-cis-ug/m3 2/28/2019 12.9 Table 1.0 100-41-4 Ethylbenzene ug/m3 5/3/2019 7.6 Table 1.0 142-82-5 Heptane, N-ug/m3 5/3/2019 35.5 Table 1.0 110-54-3 Hexane, N-ug/m3 1/31/2019 54.3 Table 1.0 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 5/3/2019 4.2 Table 1.0 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 5/3/2019 117 Table 1.0 75-09-2 Methylene Chloride ug/m3 1/31/2019 12.1 Table 1.0 91-20-3 ~Naphthalene ug/m3 5/3/2019 8 Table 1.0 115-07-1 Propylene ug/m3 1/31/2019 2 Table 1.0 100-42-5 Styrene ug/m3 5/3/2019 25.1 Table 1.0 127-18-4 Tetrachloroethylene ug/m3 2/8/2019 244 Table 1.0 108-88-3 Toluene ug/m3 5/3/2019 2 Table 1.0 79-01-6 Trichloroethylene ug/m3 5/3/2019 1.6 Table 1.0 75-69-4 Trichlorofluoromethane ug/m3 2/28/2019 24.8 Table 1.0 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 5/3/2019 7.4 Table 1.0 108-67-8 Trimethylbenzene, 1,3,5-ug/m3 5/3/2019 64 Table 1.0 106-42-3 Xylene, P-ug/m3 5/3/2019 64 Table 1.0 108-38-3 Xylene, m-ug/m3 5/3/2019 26.2 Table 1.0 95-47-6 Xylene, o-ug/m3 5/3/2019 Input Form 2E Soil Gas Exposure Point Concentration Table North Carolina DEQ Risk Calculator Summary of Risk Assessment Output Output Form 1A Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 20037-16-060 Exposure Unit ID: HMSG-1 Last 4 Sampling Events Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil Combined Pathways NC NC NC Groundwater Combined Pathways*NC NC NC Soil Combined Pathways NC NC NC Groundwater Combined Pathways*NC NC NC Construction Worker Soil Combined Pathways NC NC NC Soil Combined Pathways NC NC NC Surface Water Combined Pathways*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 4.9E-06 2.4E-01 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC PRIMARY CALCULATORS Resident Non-Residential Worker User Defined 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk- based closure. Protection of Surface Water Exceedence of 2B at POE? Exceedence of 2B at POE? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target POE Concentrations Exceeded? Protection of Groundwater Use Exceedence of 2L at POE? Exceedence of 2L at POE? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 20037-16-060 Exposure Unit ID: HMSG-1 Last 4 Sampling Events CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient67-64-1 Acetone 784 23.52 -6.5E+03 7.3E-0471-43-2 Benzene 3.8 0.114 3.6E-01 6.3E+00 3.2E-07 3.6E-03 75-15-0 Carbon Disulfide 12.5 0.375 -1.5E+02 5.1E-0474-87-3 Chloromethane 3.9 0.117 -1.9E+01 1.2E-03110-82-7 Cyclohexane -1.3E+0375-71-8 Dichlorodifluoromethane 2.9 0.087 -2.1E+01 8.3E-04 156-59-2 Dichloroethylene, 1,2-cis-6.3 0.189 --142-82-5 Heptane, N-7.6 0.228 -8.3E+01 5.5E-04110-54-3 Hexane, N-35.5 1.065 -1.5E+02 1.5E-03591-78-6 Hexanone, 2--6.3E+00 78-93-3 Methyl Ethyl Ketone (2-Butanone)54.3 1.629 -1.0E+03 3.1E-04108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)4.2 0.126 -6.3E+02 4.0E-05 75-09-2 Methylene Chloride 117 3.51 1.0E+02 1.3E+02 3.5E-08 5.6E-0391-20-3 ~Naphthalene 12.1 0.363 8.3E-02 6.3E-01 4.4E-06 1.2E-01115-07-1 Propylene 8 0.24 -6.3E+02 7.7E-05100-42-5 Styrene 2 0.06 -2.1E+02 5.8E-05 127-18-4 Tetrachloroethylene 25.1 0.753 1.1E+01 8.3E+00 7.0E-08 1.8E-02 108-88-3 Toluene 244 7.32 -1.0E+03 1.4E-03 79-01-6 Trichloroethylene 2 0.06 4.8E-01 4.2E-01 1.3E-07 2.9E-02 75-69-4 Trichlorofluoromethane 1.6 0.048 --95-63-6 Trimethylbenzene, 1,2,4-24.8 0.744 -1.3E+01 1.2E-02108-67-8 Trimethylbenzene, 1,3,5-7.4 0.222 -1.3E+01 3.5E-03 75-01-4 Vinyl Chloride 1.7E-01 2.1E+01 106-42-3 Xylene, P-64 1.92 -2.1E+01 1.8E-02108-38-3 Xylene, m-64 1.92 -2.1E+01 1.8E-0295-47-6 Xylene, o-26.2 0.786 -2.1E+01 7.5E-03 Cumulative:4.9E-06 2.4E-01 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID:Submittal Date: Reviewed By: HMSG-2 Highest Concentrations (all sampling events) North Carolina Department of Environmental Quality Risk Calculator Highland Mill #3 N. Brevard and N. Davidson Brownfields 20037-16-060 February 2018 November 2017 EPA RSL Table 5/28/2019 Prepared By:Patrick Lowery SUMMIT ELT MZ North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 20037-16-060 Exposure Unit ID: HMSG-2 Highest Concentrations (all sampling events) Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Combined Pathways Groundwater Combined Pathways Soil Combined Pathways Groundwater Combined Pathways Construction Worker Soil Combined Pathways Soil Combined Pathways Surface Water Combined Pathways Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Protection of Groundwater Use Protection of Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS PRIMARY PATHWAYS Resident Non-Residential Worker User Defined North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 20037-16-060 Exposure Unit ID: HMSG-2 Highest Concentrations (all sampling events) Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Justification for Exposure Point Concentration CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier)Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 197 Table 1.0 67-64-1 Acetone ug/m3 12/7/2018 9.4 Table 1.0 71-43-2 Benzene ug/m3 5/3/2019 17 Table 1.0 75-15-0 Carbon Disulfide ug/m3 12/7/2018 11 Table 1.0 74-87-3 Chloromethane ug/m3 2/28/2019 7.2 Table 1.0 110-82-7 Cyclohexane ug/m3 12/7/2018 2.5 Table 1.0 75-71-8 Dichlorodifluoromethane ug/m3 1/31/2019 1.4 Table 1.0 156-59-2 Dichloroethylene, 1,2-cis-ug/m3 5/3/2019 14.6 Table 1.0 100-41-4 Ethylbenzene ug/m3 5/3/2019 56 Table 1.0 142-82-5 Heptane, N-ug/m3 5/3/2019 35 Table 1.0 110-54-3 Hexane, N-ug/m3 1/31/2019 0 Table 1.0 591-78-6 Hexanone, 2-ug/m3 8.3 Table 1.0 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 2/28/2019 0 Table 1.0 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 2/28/2019 213 Table 1.0 75-09-2 Methylene Chloride ug/m3 1/31/2019 12.4 Table 1.0 91-20-3 ~Naphthalene ug/m3 5/3/2019 57.4 Table 1.0 115-07-1 Propylene ug/m3 12/7/2018 0 Table 1.0 100-42-5 Styrene ug/m3 406 Table 1.0 127-18-4 Tetrachloroethylene ug/m3 12/30/2018 55.7 Table 1.0 108-88-3 Toluene ug/m3 5/3/2019 1.7 Table 1.0 79-01-6 Trichloroethylene ug/m3 2/28/2019 5.3 Table 1.0 75-69-4 Trichlorofluoromethane ug/m3 2/28/2019 5.8 Table 1.0 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 5/3/2019 0 Table 1.0 108-67-8 Trimethylbenzene, 1,3,5-ug/m3 0 Table 1.0 75-01-4 Vinyl Chloride ug/m3 12.5 Table 1.0 106-42-3 Xylene, P-ug/m3 5/3/2019 12.5 Table 1.0 108-38-3 Xylene, m-ug/m3 5/3/2019 3.4 Table 1.0 95-47-6 Xylene, o-ug/m3 5/3/2019 Input Form 2E Soil Gas Exposure Point Concentration Table North Carolina DEQ Risk Calculator Summary of Risk Assessment Output Output Form 1A Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 20037-16-060 Exposure Unit ID: HMSG-2 Highest Concentrations (all sampling events) Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil Combined Pathways NC NC NC Groundwater Combined Pathways*NC NC NC Soil Combined Pathways NC NC NC Groundwater Combined Pathways*NC NC NC Construction Worker Soil Combined Pathways NC NC NC Soil Combined Pathways NC NC NC Surface Water Combined Pathways*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 6.6E-06 4.8E-01 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk- based closure. Protection of Surface Water Exceedence of 2B at POE? Exceedence of 2B at POE? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target POE Concentrations Exceeded? Protection of Groundwater Use Exceedence of 2L at POE? Exceedence of 2L at POE? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: PRIMARY CALCULATORS Resident Non-Residential Worker User Defined North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 20037-16-060 Exposure Unit ID: HMSG-2 Highest Concentrations (all sampling events) CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient67-64-1 Acetone 197 5.91 -6.5E+03 1.8E-0471-43-2 Benzene 9.4 0.282 3.6E-01 6.3E+00 7.8E-07 9.0E-03 75-15-0 Carbon Disulfide 17 0.51 -1.5E+02 7.0E-0474-87-3 Chloromethane 11 0.33 -1.9E+01 3.5E-03110-82-7 Cyclohexane 7.2 0.216 -1.3E+03 3.5E-0575-71-8 Dichlorodifluoromethane 2.5 0.075 -2.1E+01 7.2E-04 156-59-2 Dichloroethylene, 1,2-cis-1.4 0.042 --142-82-5 Heptane, N-56 1.68 -8.3E+01 4.0E-03110-54-3 Hexane, N-35 1.05 -1.5E+02 1.4E-03591-78-6 Hexanone, 2-0 0 -6.3E+00 0.0E+00 78-93-3 Methyl Ethyl Ketone (2-Butanone)8.3 0.249 -1.0E+03 4.8E-05108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)0 0 -6.3E+02 0.0E+00 75-09-2 Methylene Chloride 213 6.39 1.0E+02 1.3E+02 6.3E-08 1.0E-0291-20-3 ~Naphthalene 12.4 0.372 8.3E-02 6.3E-01 4.5E-06 1.2E-01115-07-1 Propylene 57.4 1.722 -6.3E+02 5.5E-04100-42-5 Styrene 0 0 -2.1E+02 0.0E+00 127-18-4 Tetrachloroethylene 406 12.18 1.1E+01 8.3E+00 1.1E-06 2.9E-01 108-88-3 Toluene 55.7 1.671 -1.0E+03 3.2E-04 79-01-6 Trichloroethylene 1.7 0.051 4.8E-01 4.2E-01 1.1E-07 2.4E-02 75-69-4 Trichlorofluoromethane 5.3 0.159 --95-63-6 Trimethylbenzene, 1,2,4-5.8 0.174 -1.3E+01 2.8E-03108-67-8 Trimethylbenzene, 1,3,5-0 0 -1.3E+01 0.0E+00 75-01-4 Vinyl Chloride 0 0 1.7E-01 2.1E+01 0.0E+00 0.0E+00 106-42-3 Xylene, P-12.5 0.375 -2.1E+01 3.6E-03108-38-3 Xylene, m-12.5 0.375 -2.1E+01 3.6E-0395-47-6 Xylene, o-3.4 0.102 -2.1E+01 9.8E-04 Cumulative:6.6E-06 4.8E-01 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID:Submittal Date: Reviewed By: 5/3/2019 Prepared By:Patrick Lowery SUMMIT ELT MZ HMSG-2 Last 4 Sampling Events North Carolina Department of Environmental Quality Risk Calculator Highland Mill #3 N. Brevard and N. Davidson Brownfields 20037-16-060 February 2018 November 2017 EPA RSL Table North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 20037-16-060 Exposure Unit ID: HMSG-2 Last 4 Sampling Events Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Combined Pathways Groundwater Combined Pathways Soil Combined Pathways Groundwater Combined Pathways Construction Worker Soil Combined Pathways Soil Combined Pathways Surface Water Combined Pathways Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS PRIMARY PATHWAYS Resident Non-Residential Worker User Defined Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Protection of Groundwater Use Protection of Surface Water North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 20037-16-060 Exposure Unit ID: HMSG-2 Last 4 Sampling Events Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Justification for Exposure Point Concentration CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier)Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 39.8 Table 1.0 67-64-1 Acetone ug/m3 1/31/2019 9.4 Table 1.0 71-43-2 Benzene ug/m3 5/3/2019 2.8 Table 1.0 75-15-0 Carbon Disulfide ug/m3 5/3/2019 11 Table 1.0 74-87-3 Chloromethane ug/m3 2/28/2019 2.5 Table 1.0 75-71-8 Dichlorodifluoromethane ug/m3 1/31/2019 1.4 Table 1.0 156-59-2 Dichloroethylene, 1,2-cis-ug/m3 5/3/2019 14.6 Table 1.0 100-41-4 Ethylbenzene ug/m3 5/3/2019 56 Table 1.0 142-82-5 Heptane, N-ug/m3 5/3/2019 35 Table 1.0 110-54-3 Hexane, N-ug/m3 1/31/2019 8.3 Table 1.0 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 2/28/2019 213 Table 1.0 75-09-2 Methylene Chloride ug/m3 1/31/2019 12.4 Table 1.0 91-20-3 ~Naphthalene ug/m3 5/3/2019 0.62 Table 1.0 115-07-1 Propylene ug/m3 5/3/2019 252 Table 1.0 127-18-4 Tetrachloroethylene ug/m3 2/28/2019 55.7 Table 1.0 108-88-3 Toluene ug/m3 5/3/2019 1.7 Table 1.0 79-01-6 Trichloroethylene ug/m3 2/28/2019 5.3 Table 1.0 75-69-4 Trichlorofluoromethane ug/m3 2/28/2019 5.8 Table 1.0 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 5/3/2019 12.5 Table 1.0 106-42-3 Xylene, P-ug/m3 5/3/2019 12.5 Table 1.0 108-38-3 Xylene, m-ug/m3 5/3/2019 3.4 Table 1.0 95-47-6 Xylene, o-ug/m3 5/3/2019 Input Form 2E Soil Gas Exposure Point Concentration Table North Carolina DEQ Risk Calculator Summary of Risk Assessment Output Output Form 1A Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 20037-16-060 Exposure Unit ID: HMSG-2 Last 4 Sampling Events Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil Combined Pathways NC NC NC Groundwater Combined Pathways*NC NC NC Soil Combined Pathways NC NC NC Groundwater Combined Pathways*NC NC NC Construction Worker Soil Combined Pathways NC NC NC Soil Combined Pathways NC NC NC Surface Water Combined Pathways*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 6.2E-06 3.6E-01 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC PRIMARY CALCULATORS Resident Non-Residential Worker User Defined 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk- based closure. Protection of Surface Water Exceedence of 2B at POE? Exceedence of 2B at POE? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target POE Concentrations Exceeded? Protection of Groundwater Use Exceedence of 2L at POE? Exceedence of 2L at POE? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 20037-16-060 Exposure Unit ID: HMSG-2 Last 4 Sampling Events CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient67-64-1 Acetone 39.8 1.194 -6.5E+03 3.7E-0571-43-2 Benzene 9.4 0.282 3.6E-01 6.3E+00 7.8E-07 9.0E-03 75-15-0 Carbon Disulfide 2.8 0.084 -1.5E+02 1.2E-0474-87-3 Chloromethane 11 0.33 -1.9E+01 3.5E-03110-82-7 Cyclohexane -1.3E+0375-71-8 Dichlorodifluoromethane 2.5 0.075 -2.1E+01 7.2E-04 156-59-2 Dichloroethylene, 1,2-cis-1.4 0.042 --142-82-5 Heptane, N-56 1.68 -8.3E+01 4.0E-03110-54-3 Hexane, N-35 1.05 -1.5E+02 1.4E-03591-78-6 Hexanone, 2--6.3E+00 78-93-3 Methyl Ethyl Ketone (2-Butanone)8.3 0.249 -1.0E+03 4.8E-05108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)-6.3E+02 75-09-2 Methylene Chloride 213 6.39 1.0E+02 1.3E+02 6.3E-08 1.0E-0291-20-3 ~Naphthalene 12.4 0.372 8.3E-02 6.3E-01 4.5E-06 1.2E-01115-07-1 Propylene 0.62 0.0186 -6.3E+02 5.9E-06100-42-5 Styrene -2.1E+02 127-18-4 Tetrachloroethylene 252 7.56 1.1E+01 8.3E+00 7.0E-07 1.8E-01 108-88-3 Toluene 55.7 1.671 -1.0E+03 3.2E-04 79-01-6 Trichloroethylene 1.7 0.051 4.8E-01 4.2E-01 1.1E-07 2.4E-02 75-69-4 Trichlorofluoromethane 5.3 0.159 --95-63-6 Trimethylbenzene, 1,2,4-5.8 0.174 -1.3E+01 2.8E-03108-67-8 Trimethylbenzene, 1,3,5--1.3E+01 75-01-4 Vinyl Chloride 1.7E-01 2.1E+01 106-42-3 Xylene, P-12.5 0.375 -2.1E+01 3.6E-03108-38-3 Xylene, m-12.5 0.375 -2.1E+01 3.6E-0395-47-6 Xylene, o-3.4 0.102 -2.1E+01 9.8E-04 Cumulative:6.2E-06 3.6E-01 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\Appendix VII - Sample Collection Field Logs.rtf APPENDIX VII SAMPLE COLLECTION LOGS/FIELD REPORTS VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\Appendix VIII - Potential Contaminant Sources.rtf APPENDIX VIII POTENTIAL CONTAMINANT SOURCES / SDS 09/04/2014Revision: 10/06/2014Printed: Page: 1 Jasco Xylol XyleneSAFETY DATA SHEET 06/16/2011Supersedes Revision: Jasco Xylol XyleneProduct Name: W. M. BarrCompany Name: 2105 Channel Avenue Memphis, TN 38113 3E 24 Hour Emergency ContactEmergency Contact:(800)451-8346 W.M. Barr Customer ServiceInformation:(800)398-3892 (901)775-0100 Phone Number: Paint, stain, and varnish thinning.Intended Use: www.wmbarr.comWeb site address: GJXY24, QJXY24, CJXY24, GJXY170Synonyms: 1. PRODUCT AND COMPANY IDENTIFICATION 2. HAZARDS IDENTIFICATION P233: Keep container tightly closed. P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P280: Wear protective gloves/protective clothing/eye protection/face protection. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting equipment. P243: Take precautionary measures against static discharge. P242: Use only non-sparking tools. P271: Use only outdoors or in a well-ventilated area. P261: Avoid breathing gas/mist/vapours/spray. P264: Wash hands thoroughly after handling. P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P281: Use personal protective equipment as required. GHS Precaution Phrases: P370+378: In case of fire, use dry chemical to extinguish. P303+361+353: IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P312: Call a POISON CENTER/doctor if you feel unwell. P302+352: IF ON SKIN: Wash with plenty of soap and water. P322: Specific measures see label. P363: Wash contaminated clothing before reuse. P321: Specific treatment see label. P332+313: If skin irritation occurs, get medical advice/attention. GHS Response Phrases: H225: Highly flammable liquid and vapor. H332: Harmful if inhaled. H312: Harmful in contact with skin. H315: Causes skin irritation. H351: Suspected of causing cancer. GHS Hazard Phrases: Flammable Liquids, Category 2 Acute Toxicity: Inhalation, Category 4 Acute Toxicity: Skin, Category 4 Skin Corrosion/Irritation, Category 2 Carcinogenicity, Category 2 DangerGHS Signal Word: Licensed to W.M. Barr and Company GHS format 09/04/2014Revision: 10/06/2014Printed: Page: 2 Jasco Xylol XyleneSAFETY DATA SHEET 06/16/2011Supersedes Revision: P362: Take off contaminated clothing. P308+313: IF exposed or concerned: Get medical attention/advice. P403+235: Store in cool/well-ventilated place. P501: Dispose of contents/container according to local, state and federal regulations. P405: Store locked up. GHS Storage and Disposal Phrases: Hazard Rating System:Instability Special Hazard Health FlammabilityHEALTH FLAMMABILITY PPE PHYSICAL 2 0 3 * X 2 3 0 NFPA:HMIS: This material is classified as hazardous under OSHA regulations.OSHA Regulatory Status: Diseases of the skin, liver, and kidneys.Medical Conditions Generally Aggravated By Exposure: Inhalation Acute Exposure Effects: Vapor harmful. May cause dizziness, headache, irritation of respiratory tract, weakness, drowsiness, depression of central nervous system, and watering of eyes. Severe overexposure may cause unconsciousness, anesthesia, irregular heartbeat, and death. Intentional misuse of this product by deliberately concentrating and inhaling can be harmful or fatal. Skin Contact Acute Exposure Effects: This product is a skin irritant. It may be absorbed through the skin. It may cause irritation, dermatitis, drying of skin, and numbness in fingers and arms. May increase severity of symptoms listed under inhalation. Eye Contact Acute Exposure Effects: This material is an eye irritant. It may cause irritation, redness, stinging, tearing, excessive swelling of the conjunctiva; and or excessive blinking. Ingestion Acute Exposure Effects: Harmful or fatal if swallowed. May cause nausea, vomiting, gastrointestinal irritation, or diarrhea. Chronic Exposure Effects: Reports have associated repeated and prolonged overexposure to solvents with neurological and other physiological damage. Prolonged or repeated contact may cause dermatitis. May cause skin irritation, permanent central nervous system changes, kidney damage, and liver damage. Potential Health Effects (Acute and Chronic): CAS # Hazardous Components (Chemical Name) 3. COMPOSITION/INFORMATION ON INGREDIENTS Concentration 1330-20-7 Xylene (mixed isomers) {Benzene, dimethyl-} 60.0 -100.0 % 100-41-4 Ethylbenzene {Ethylbenzol; Phenylethane} 10.0 -30.0 % Ethylbenzene is a component of Xylene.Additional Chemical Information Licensed to W.M. Barr and Company GHS format 09/04/2014Revision: 10/06/2014Printed: Page: 3 Jasco Xylol XyleneSAFETY DATA SHEET 06/16/2011Supersedes Revision: 4. FIRST AID MEASURES Inhalation: If user experiences breathing difficulty, move to air free of vapors. Administer oxygen or artificial respiration until medical assistance can be rendered. Skin Contact: Irritation may result. Immediately wash with soap and water. Eye Contact: Immediately flush with water, remove any contact lenses, continue flushing with water for at least 15 minutes, then get medical attention. Ingestion: Do not induce vomiting. Call you local poison control center, hospital emergency room, or physician immediately for instructions. Emergency and First Aid Procedures: Call your local poison control center for further information.Note to Physician: See Potential Health Effects.Signs and Symptoms Of Exposure: 5. FIRE FIGHTING MEASURES Flash Pt:81.00 F Method Used: Closed Cup Self-contained respiratory protection should be provided for fire fighters fighting fires in buildings or confined areas. Storage containers exposed to fire should be kept cool with water spay to prevent pressure build-up. Stay away from heads of containers that have been exposed to intense heat or flame. Fire Fighting Instructions: Flammable Liquid! This material releases vapors at or below ambient temperatures. When mixed with air in certain proportions and exposed to an ignition source, its vapor can cause a flash fire. Use only with adequate ventilation. Vapors are heavier than air and may travel long distances along the ground to an ignition source and flash back. A vapor and air mixture can create an explosion hazard in confined spaces such as sewers. If container is not properly cooled, it can rupture in the heat of a fire. Flammable Properties and Hazards: Autoignition Pt:432.00 C Explosive Limits:LEL: AP 1% UEL: AP 7% NFPA Class IC flammable liquid Use carbon dioxide, dry powder, or foam.Suitable Extinguishing Media: 6. ACCIDENTAL RELEASE MEASURES Vapors may cause flash fire or ignite explosively. Clean up: Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, out of low areas, and ventilate closed spaces before entering. Shut off ignition sources; keep flares, smoking or flames out of hazard area. Use non-sparking tools. Use proper bonding and grounding methods for all equipment and processes. Keep out of waterways and bodies of water. Be cautious of vapors collecting in small enclosed spaces, sewers, low lying areas, confined spaces, etc. Small spills: Take up with sand, earth or other noncombustible absorbent material and place in a plastic container where applicable. Steps To Be Taken In Case Material Is Released Or Spilled: Licensed to W.M. Barr and Company GHS format 09/04/2014Revision: 10/06/2014Printed: Page: 4 Jasco Xylol XyleneSAFETY DATA SHEET 06/16/2011Supersedes Revision: Large spills: Dike far ahead of spill for later disposal. Waste Disposal: Dispose in accordance with applicable local, state and federal regulations. 7. HANDLING AND STORAGE Read carefully all cautions and directions on product label before use. Since empty container retains residue, follow all label warnings even after container is empty. Dispose of empty container according to all regulations. Do not reuse this container. Do not use this product near any source of heat or open flame, furnace areas, pilot lights, stoves, etc. Do not use in small enclosed spaces, such as basements and bathrooms. Vapors can accumulate and explode if ignited. Do not spread this product over large surface areas because fire and health safety risks will increase dramatically. Precautions To Be Taken in Handling: Keep container tightly closed when not in use. Store in a cool, dry place. Do not store near flames or at elevated temperatures. Precautions To Be Taken in Storing: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION OSHA TWA ACGIH TWACAS # Partial Chemical Name Other Limits PEL: 100 ppm TLV: 100 ppm STEL: 150 ppm 1330-20-7 Xylene (mixed isomers) {Benzene, dimethyl-} No data. PEL: 100 ppm TLV: 100 ppm STEL: 125 ppm 100-41-4 Ethylbenzene {Ethylbenzol; Phenylethane} No data. For OSHA controlled work place and other regular users --Use only with adequate ventilation under engineered air control systems designed to prevent exceeding appropriate TLV. For occasional use, where engineered air control is not feasible, use properly maintained and properly fitted NIOSH approved respirator for organic solvent vapors. A dust mask does not provided protection against vapors. Respiratory Equipment (Specify Type): Safety glasses, chemical goggles or face shields are recommended to safeguard against potential eye contact, irritation, or injury. Contact lenses should not be worn while working with chemicals. Eye Protection: Wear gloves with as much resistance to the chemical ingredients as possible. Glove materials such as nitrile rubber may provide protection. Glove selection should be based on chemicals being used and conditions of use. Consult your glove supplier for additional information. Gloves contaminated with product should be discarded and not reused. Protective Gloves: Various application methods can dictate the use of additional protective safety equipment, such as impermeable aprons, etc., to minimize exposure. Other Protective Clothing: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Use only with adequate ventilation to prevent buildup of vapors. Do not use in areas where vapors can accumulate and concentrate, such as basements, bathrooms or small Engineering Controls (Ventilation etc.): Licensed to W.M. Barr and Company GHS format 09/04/2014Revision: 10/06/2014Printed: Page: 5 Jasco Xylol XyleneSAFETY DATA SHEET 06/16/2011Supersedes Revision: enclosed areas. Whenever possible, use outdoors in an open air area. If using indoors open all windows and doors and maintain a cross ventilation of moving fresh air across the work area. If strong odor is noticed or you experience slight dizziness, headache, nausea or eye-watering -- STOP -- ventilation is inadequate. Leave area immediately and move to fresh air. Wash hands thoroughly after use and before eating, drinking, or smoking. Do not eat, drink, or smoke in the work area. Discard any clothing or other protective equipment that cannot be decontaminated. Facilities storing or handling this material should be equipped with an emergency eyewash and safety shower. Work/Hygienic/Maintenance Practices: 9. PHYSICAL AND CHEMICAL PROPERTIES Physical States:[ ] Gas [ X ] Liquid [ ] Solid Melting Point:-48.00 C - -25.00 C Boiling Point:280.00 F - 288.00 F Autoignition Pt:432.00 C Flash Pt:81.00 F Method Used: Closed Cup Explosive Limits:LEL: AP 1% UEL: AP 7% Specific Gravity (Water = 1): 0.87 Density: 7.18 LB/GL at 77.0 F Sweet, pungent aromatic hydrocarbon Appearance and Odor: Vapor Pressure (vs. Air or mm Hg): 7 MM HG at 20.0 C Vapor Density (vs. Air = 1):No data. Evaporation Rate:No data. Solubility in Water:No data. Percent Volatile:99.999 % by weight. VOC / Volume:872.0000 G/L 10. STABILITY AND REACTIVITY No data available.Conditions To Avoid - Instability: Unstable [ ] Stable [ X ]Stability: Incompatible with strong oxidizing agents.Incompatibility - Materials To Avoid: Decomposition may produce carbon monoxide and carbon dioxide.Hazardous Decomposition Or Byproducts: Will occur [ ] Will not occur [ X ]Possibility of Hazardous Reactions: No data available.Conditions To Avoid - Hazardous Reactions: Licensed to W.M. Barr and Company GHS format 09/04/2014Revision: 10/06/2014Printed: Page: 6 Jasco Xylol XyleneSAFETY DATA SHEET 06/16/2011Supersedes Revision: 11. TOXICOLOGICAL INFORMATION Overexposure to xylene may cause upper respiratory tract irritation, headache, cyanosis, blood serum changes, CNS damage and narcosis. Effects may be increased by the use of alcoholic beverages. Evidence of liver and kidney impairment were reported in workers recovering from a gross over-exposure. Toxicological Information: Xylene, all isomers: Effects from Prolonged or Repeated Exposure: Impaired neurological function was reported in workers exposed to solvents including xylene. Studies in laboratory animals have shown evidence of impaired hearing following high levels of exposure. Studies in laboratory animals suggest some changes in reproductive organs following high levels of exposure but no significant effects on reproduction were observed. Studies in laboratory animals indicate skeletal and visceral malformations, developmental delays, and increased fetal resorptions following extremely high levels of maternal exposure. Chronic Toxicological Effects: CAS# 1330-20-7: Acute toxicity, LC50, Inhalation, Rat, 5000. PPM, 4 H. Result: Behavioral: Muscle contraction or spasticity. Lungs, Thorax, or Respiration:Other changes. - Raw Material Data Handbook, Vol.1: Organic Solvents, 1974., National Assoc. of Printing Ink Research Institute, Francis McDonald Sinclair Memorial Labor, Lehigh Univ., Bethlehem, PA 18015, Vol/p/yr: 1,123, 1974 Acute toxicity, LD50, Subcutaneous, Rat, 1700. MG/KG. Result: Kidney, Ureter, Bladder:Proteinuria. Kidney, Ureter, Bladder:Other changes in urine composition. - Raw Material Data Handbook, Vol.1: Organic Solvents, 1974., National Assoc. of Printing Ink Research Institute, Francis McDonald Sinclair Memorial Labor, Lehigh Univ., Bethlehem, PA 18015, Vol/p/yr: 1,123, 1974 Standard Draize Test, Skin, Species: Rabbit, 100.0 %, Moderate. Result: Specific Developmental Abnormalities: Craniofacial (including nose and tongue). - AMA Archives of Industrial Health., For publisher information, see AEHLAU, Chicago, IL, Vol/p/yr: 14,387, 1956 CAS# 100-41-4: Tumorigenic Effects:, TCLo, Inhalation, Rat, 750.0 ppm. Result: Tumorigenic: Carcinogenic by RTECS criteria. Kidney, Ureter, Bladder: Tumors. Licensed to W.M. Barr and Company GHS format 09/04/2014Revision: 10/06/2014Printed: Page: 7 Jasco Xylol XyleneSAFETY DATA SHEET 06/16/2011Supersedes Revision: CAS # Hazardous Components (Chemical Name) NTP Adverse effects on the liver, kidney, bone marrow (changes in blood cell parameters) were observed in laboratory animals following high levels of exposure. The relevance of these observations to humans is not clear at this time. Ethyl Benzene: Effects from Prolonged or Repeated Exposure: Findings from a 2-year inhalation study in rodents conducted by NTP were as follows: Effects were observed only at the highest exposure level (750 ppm). At this level the incidence of renal tumors was elevated in male rats (tubular carcinomas) and female rats (tubular adenomas). Also, the incidence of tumors was elevated in male mice (alveolar and bronchiolar carcinomas) and female mice (hepatocellular carcinomas). IARC has classified ethyl benzene as “possibly carcinogenic to humans” (Group 2B). Studies in laboratory animals indicate some evidence of post-implantation deaths following high levels of maternal exposure. The relevance of these findings to humans is not clear at this time. Studies in laboratory animals indicate limited evidence of renal malformations, resorptions, and developmental delays following high levels of maternal exposure. The relevance of these findings to humans is not clear at this time. Studies in laboratory animals indicate some evidence of adverse effects on the liver, kidney, thyroid, and pituitary gland. IARC 2B - Possibly Carcinogenic to Humans ACGIH A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans ACGIH A4 - Not Classifiable as a Human Carcinogen. Carcinogenicity/Other Information: IARC ACGIH OSHA 1330-20-7 Xylene (mixed isomers) {Benzene, dimethyl-} n.a. 3 A4 n.a. 100-41-4 Ethylbenzene {Ethylbenzol; Phenylethane} n.a. 2B A3 n.a. No data available. 12. ECOLOGICAL INFORMATION Dispose in accordance with local, state, and federal regulations.Waste Disposal Method: 13. DISPOSAL CONSIDERATIONS 14. TRANSPORT INFORMATION XylenesDOT Proper Shipping Name: 3 FLAMMABLE LIQUIDDOT Hazard Class: UN1307UN/NA Number:IIIPacking Group: LAND TRANSPORT (US DOT): For D.O.T. information, contact W.M. Barr Technical Services at 1-800-398-3892. The shipper/supplier may apply one of the following exceptions: Combustible Liquid, Consumer Commodity, Limited Quantity, Viscous Liquid, Does Not Sustain Combustion, or others, as allowed under 49CFR Hazmat Regulations. Please consult 49CFR Subchapter C to ensure that subsequent shipments comply with these exceptions. Additional Transport Information: Licensed to W.M. Barr and Company GHS format 09/04/2014Revision: 10/06/2014Printed: Page: 8 Jasco Xylol XyleneSAFETY DATA SHEET 06/16/2011Supersedes Revision: 15. REGULATORY INFORMATION [X] Yes [ ] No Acute (immediate) Health Hazard [X] Yes [ ] No Chronic (delayed) Health Hazard [X] Yes [ ] No Fire Hazard [ ] Yes [X] No Sudden Release of Pressure Hazard [ ] Yes [X] No Reactive Hazard This material meets the EPA 'Hazard Categories' defined for SARA Title III Sections 311/312 as indicated: CAS # Hazardous Components (Chemical Name) Other US EPA or State Lists 1330-20-7 Xylene (mixed isomers) {Benzene, dimethyl-} CAA HAP,ODC: HAP; CWA NPDES: Yes; TSCA: Yes - Inventory; CA PROP.65: No 100-41-4 Ethylbenzene {Ethylbenzol; Phenylethane} CAA HAP,ODC: HAP; CWA NPDES: Yes; TSCA: Yes - Inventory, 4 Test; CA PROP.65: Yes All components of this material are listed on the TSCA Inventory or are exempt.Regulatory Information Statement: 16. OTHER INFORMATION No data available.Additional Information About This Product: The information contained herein is presented in good faith and believed to be accurate as of the effective date shown above. This information is furnished without warranty of any kind. Employers should use this information only as a supplement to other information gathered by them and must make independent determination of suitability and completeness of information from all sources to assure proper use of these materials and the safety and health of employees. Any use of this data and information must be determined by the user to be in accordance with applicable federal, state and local laws and regulations. Company Policy or Disclaimer: 09/04/2014Revision Date: W.M. Barr EHS Department (901)775-0100Preparer Name: Licensed to W.M. Barr and Company GHS format Technical Data MASTERLINE® Commercial Grade POLYURETHANE PRODUCTION DESCRIPTION: MASTERLINE® Polyurethane is a durable finish suitable for large volume applications such as meeting halls, multiple-unit dwellings, and other commercial uses. It is available in Gloss, Semi-Gloss and Satin. PRODUCT PROPORTIES: DRY TIME AND CURE - Allow to dry fully for 8 hours before recoating Wait overnight before allowing light traffic Wait 48 hours before replacing furniture and rugs COVERAGE - Approx. 500-600 sq. ft. per gallon CLEAN-UP - Clean applicators with mineral spirits or paint thinner STORAGE - Store at room temperature. Keep container tightly closed PHYSICAL PROPERITES: RESIN TYPE Oil Modified Urethane DENSITY (LBS/GAL) 7.30 SOLVENT Mineral Spirits VISCOSITY 200 cps % SOLIDS 44.0 VOC less than 550 grams/liter FLASH POINT 105°F - Seta Flash HEALTH/SAFETY HMIS RATING: Health 2 Flammability 2 Reactivity 0 CAUTION: COMBUSTIBLE: Keep away from heat and open flames. VAPOR HARMFUL – use only with adequate ventilation Avoid contact with skin and eyes. Wash hands after using. KEEP OUT OF REACH OF CHILDREN DO NOT TAKE INTERNALLY. PRODUCT USE DIRECTIONS: New Wood Floors: 1. Prepare floor according to NOFMA or NWFA specifications. 2. Apply Masterline® Polyurethane using a lambswool applicator or a natural bristle brush at a coverage rat of 500-600 square feet per gallon. Application of thicker coats extends dry time. 3. Allow to dry fully for 8-10 hours, then screen the floor and tack with a cloth dampened with mineral spirits to remove dust. 4. Apply at least two more coats in the same manner as steps 2 and 3. Additional coats may be applied if desired. Be sure to allow each coat to dry fully and screen lightly between each coat. 10 Mountainview Rd., Upper Saddle River, NJ 07458-1933 ● Tel: 1-800-364-1359 ● Fax: 1-800-601-9055 MASTERLINE® Commercial Grade POLYURETHANE Screen and Recoat: 1. Clean floors with an abrasive pad dampened with mineral spirits to remove all grease, soap residue, oil, dirt, etc. Once dry, screen using a No. 100 grit screen. Do not apply over floors previously finished with shellac, lacquer, wax, or stains containing stearates, wax, or finishes in very poor condition in need of complete removal. 2. See step 2 under New Wood Floors. Old Wood Floors: 1. Sand floor to bare wood according to NOFMA or NWFA approved methods. Make sure to remove all existing stain and finish. 2. Tack floor with cloth dampened with mineral spirits to remove all dust. 3. Follow steps 2 through 4 under New Wood Floors. PRECAUTION: Polyurethane will have a slight ambering/darkening effect when applied over light-colored surfaces. Do not apply over floors previously coated with wax, shellac, lacquer, or stains containing wax or stearates. SHEEN: SIZE SKU # CASE/PACK 550 VOC Gloss Qt. 33460 4 Gal 33410 4 Five 33450 1 Semi-Gloss Qt. 33462 4 Gal 33412 4 Five 33452 1 Satin Qt. 33461 4 Gal 33411 4 Five 33451 1 5/16/10 Safety Data Sheet Revision Number: 001.3 Issue date: 11/14/2014 IDH number: 1630096 Product name: OSI F-38 Drywall and Panel Adhesive Page 1 of 7 1. PRODUCT AND COMPANY IDENTIFICATION Product name: OSI F-38 Drywall and Panel Adhesive IDH number: 1630096 Product type: Assembly adhesive, solvent Restriction of Use: None identified Region: United States Company address: Contact information: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067 Telephone: +1 (800) 624-7767 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671- 4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW DANGER: ABRASION COULD RELEASE RESPIRABLE PARTICLES OF SILICA QUARTZ, A CANCER HAZARD BY INHALATION. NORMAL USE OF THIS PRODUCT CAUSES NO SUCH RELEASE. HIGHLY FLAMMABLE LIQUID AND VAPOR. CAUSES SKIN IRRITATION. CAUSES SERIOUS EYE IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS. HAZARD CLASS HAZARD CATEGORY FLAMMABLE LIQUID 2 SKIN IRRITATION 2 EYE IRRITATION 2A SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3 PICTOGRAM(S) Precautionary Statements Prevention: Keep away from heat, sparks, open flames, hot surfaces - no smoking. Keep container tightly closed. No release into water. Use explosion-proof equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing vapors, mist, or spray. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves, eye protection, and face protection. Response: If on skin (or hair): Take off immediately all contaminated clothing. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. Call a poison control center or physician if you feel unwell. If skin irritation occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off contaminated clothing. In case of fire: Use foam, dry chemical or carbon dioxide to extinguish. Storage: Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. IDH number: 1630096 Product name: OSI F-38 Drywall and Panel Adhesive Page 2 of 7 Keep cool. Store locked up. Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) CAS Number Percentage* Limestone 1317-65-3 30 - 60 Acetone 67-64-1 10 - 30 Kaolin 1332-58-7 10 - 30 Methyl acetate 79-20-9 1 - 5 Titanium dioxide 13463-67-7 0.1 - 1 Quartz (SiO2) 14808-60-7 0.1 - 1 * Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: If inhaled, immediately remove the affected person to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. If symptoms develop and persist, get medical attention. Skin contact: Rinse with running water and soap. Apply replenishing cream. Change all contaminated clothing. Eye contact: In case of contact with the eyes, rinse immediately with plenty of water for 15 minutes, and seek immediate medical attention. Ingestion: Do not induce vomiting, seek medical advice immediately. Symptoms: See Section 11. 5. FIRE FIGHTING MEASURES Extinguishing media: Foam, dry chemical or carbon dioxide. In case of fire, keep containers cool with water spray. Special firefighting procedures: Wear a self-contained breathing apparatus with a full face piece operated in pressure-demand or other positive pressure mode. Wear full protective clothing. Unusual fire or explosion hazards: Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air. Vapors are heavier than air and may travel along floor to an ignition source. IDH number: 1630096 Product name: OSI F-38 Drywall and Panel Adhesive Page 3 of 7 Hazardous combustion products: Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Eliminate all sources of ignition or flammables that may come into contact with a spill of this material. Ventilate area. Do not allow product to enter sewer or waterways. Clean-up methods: Use noncombustible absorbent material such as sand. Use non-sparking tools for clean-up. Absorb spill with inert material. Shovel material into appropriate container for disposal. Wear suitable protective clothing, gloves and eye/face protection. 7. HANDLING AND STORAGE Handling: Do not pressurize, cut, heat or weld containers. Empty product containers may contain product residue. Do not reuse empty containers. Use only in well-ventilated areas. Keep out of the reach of children. Storage: For safe storage, store between -20 °C (-4°F) and 50 °C (122°F) Keep away from heat, spark and flame. Keep containers closed when not in use. For information on product shelf life, please review labels on container or check the Technical Data Sheet. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Limestone 10 mg/m3 TWA Total dust. 5 mg/m3 PEL Respirable fraction. 15 mg/m3 PEL Total dust. None None Acetone 750 ppm STEL 500 ppm TWA 1,000 ppm (2,400 mg/m3) PEL None None Kaolin 2 mg/m3 TWA Respirable fraction. 15 mg/m3 PEL Total dust. 5 mg/m3 PEL Respirable fraction. None None Methyl acetate 200 ppm TWA 250 ppm STEL 200 ppm (610 mg/m3) PEL None None Titanium dioxide 10 mg/m3 TWA 15 mg/m3 PEL Total dust. None None Quartz (SiO2) 0.025 mg/m3 TWA Respirable fraction. 2.4 MPPCF TWA Respirable. 0.1 mg/m3 TWA Respirable. 0.3 mg/m3 TWA Total dust. None None Engineering controls: Local exhaust ventilation is recommended when general ventilation is not sufficient to control airborne contamination below occupational exposure limits. Respiratory protection: If ventilation is not sufficient to effectively prevent buildup of aerosols, mists or vapors, appropriate NIOSH/MSHA respiratory protection must be provided. IDH number: 1630096 Product name: OSI F-38 Drywall and Panel Adhesive Page 4 of 7 Eye/face protection: Safety goggles or safety glasses with side shields. Skin protection: Chemical resistant, impermeable gloves. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Paste Color: Tan Odor: Strong, Solvent Odor threshold: Not available. pH: 7 Vapor pressure: Not available. Boiling point/range: 56 - 57 °C (132.8 - 134.6 °F) Melting point/ range: < 0 °C (< 32°F) Specific gravity: 1.39 Vapor density: 2.0 Flash point: -17 °C (1.4 °F) Flammable/Explosive limits - lower: Not available. Flammable/Explosive limits - upper: Not available. Autoignition temperature: Not available. Evaporation rate: 14.4 Solubility in water: Slightly soluble Partition coefficient (n-octanol/water): Not available. VOC content: 0.25 %; 7.5 g/l (by weight, calculated using CARB method; g/L less water, less exempts calculated using SCAQMD method) Viscosity: 270,000 mPa.s Decomposition temperature: Not available. 10. STABILITY AND REACTIVITY Stability: Stable under normal conditions of storage and use. Hazardous reactions: Will not occur. Hazardous decomposition products: Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Incompatible materials: Strong oxidizing agents. Reactivity: Not available. Conditions to avoid: Heat, flames, sparks and other sources of ignition. 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Inhalation, Skin contact IDH number: 1630096 Product name: OSI F-38 Drywall and Panel Adhesive Page 5 of 7 Potential Health Effects/Symptoms Inhalation: Irritates the nose, throat and respiratory system. Exposure to high doses may cause central nervous system depression. Such doses may also cause adverse effects in the liver, kidneys, and lungs. Abrasion of cured material such as by sanding or grinding could release respirable particles of silica quartz, a cancer hazard by inhalation. Normal use of this product causes no such release. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Skin contact: Prolonged and/or repeated skin contact with this product may cause irritation/dermatitis. Eye contact: Contact with eyes can cause eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Ingestion: Ingestion can cause gastrointestinal irritation, nausea, vomiting and diarrhea. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Limestone None Nuisance dust Acetone Oral LD50 (RABBIT) = 5,340 mg/kg Oral LD50 (RAT) = 5,800 mg/kg Oral LD50 (RAT) = 9,800 mg/kg Dermal LD50 (RABBIT) = 20,000 mg/kg Inhalation LC50 (RAT, 8 h) = 50.1 mg/l Inhalation LC50 (RAT, 4 h) = 76 mg/l Blood, Central nervous system, Irritant, Reproductive Kaolin Oral LD50 (RAT) = > 5,000 mg/kg Dermal LD50 (RAT) = > 5,000 mg/kg Nuisance dust Methyl acetate Oral LD50 (RABBIT) = 3.7 g/kg Blood, Central nervous system, Eyes, Irritant Titanium dioxide None Irritant, Respiratory, Some evidence of carcinogenicity Quartz (SiO2) None Immune system, Lung, Some evidence of carcinogenicity Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Limestone No No No Acetone No No No Kaolin No No No Methyl acetate No No No Titanium dioxide No Group 2B No Quartz (SiO2) Known To Be Human Carcinogen. Group 1 No 12. ECOLOGICAL INFORMATION Ecological information: Not available. IDH number: 1630096 Product name: OSI F-38 Drywall and Panel Adhesive Page 6 of 7 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Dispose of according to Federal, State and local governmental regulations. Hazardous waste number: Material, if discarded, is not expected to be a characteristic hazardous waste under RCRA. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Adhesives Hazard class or division: 3 Identification number: UN 1133 Packing group: II DOT Hazardous Substance(s): Acetone International Air Transportation (ICAO/IATA) Proper shipping name: Adhesives Hazard class or division: 3 Identification number: UN 1133 Packing group: II Water Transportation (IMO/IMDG) Proper shipping name: ADHESIVES Hazard class or division: 3 Identification number: UN 1133 Packing group: II 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. TSCA 12 (b) Export Notification: None above reporting de minimis CERCLA/SARA Section 302 EHS: None above reporting de minimis CERCLA/SARA Section 311/312: Fire, Immediate Health, Delayed Health CERCLA/SARA Section 313: None above reporting de minimis California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: This Safety Data Sheet contains changes from the previous version in Section(s): 7 Prepared by: Mary Ellen Roddy, Sr. Regulatory Affairs Specialist Issue date: 11/14/2014 IDH number: 1630096 Product name: OSI F-38 Drywall and Panel Adhesive Page 7 of 7 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. PP610 PORTER PAINTS ACRI-SHIELD EXTERIOR GLOSS ACRYLIC-BLACK Not available. Liquid. SAFETY DATA SHEET Product name Other means of identification Product type Section 1. Identification : : : Product code :00409676 Date of issue/Date of revision 25 June 2018 Version 5 Relevant identified uses of the substance or mixture and uses advised against Uses advised against Not applicable. Product use :Consumer applications, Professional applications, Used by spraying. Use of the substance/ mixture :Coating. : Manufacturer PPG Industries, Inc. One PPG Place Pittsburgh, PA 15272 (412) 434-4515 (U.S.) (514) 645-1320 (Canada) 01-800-00-21-400 or + 52 55 5559 1588 (Mexico) Emergency telephone number : : Technical Phone Number :1-800-441-9695 (8:00 am to 5:00 pm EST) Section 2. Hazards identification CARCINOGENICITY - Category 2Classification of the substance or mixture : Signal word :Warning Hazard statements :Suspected of causing cancer. Hazard pictograms : Precautionary statements GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 29.1% (Oral), 31.8% (Dermal), 34.4% (Inhalation) OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). United States Page: 1/12 PP610 PORTER PAINTS ACRI-SHIELD EXTERIOR GLOSS ACRYLIC-BLACKProduct name 5Product code Date of issue Version0040967625 June 2018 Section 2. Hazards identification Prevention :Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection. Wear protective clothing. Response :IF exposed or concerned: Get medical attention. Storage :Store locked up. Disposal :Dispose of contents and container in accordance with all local, regional, national and international regulations. General :Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Supplemental label elements :Contains isothiazolinones. May cause allergic reaction. Emits toxic fumes when heated. Hazards not otherwise classified :None known. Section 3. Composition/information on ingredients carbon black, respirable powder ≥1.0 - ≤5.0 1333-86-4 propane-1,2-diol ≥1.0 - ≤5.0 57-55-6 1,2-benzisothiazol-3(2H)-one <0.10 2634-33-5 diammonium peroxodisulphate <0.10 7727-54-0 Ingredient name CAS number% There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Substance/mixture : Occupational exposure limits, if available, are listed in Section 8. Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. Product name PP610 PORTER PAINTS ACRI-SHIELD EXTERIOR GLOSS ACRYLIC-BLACK: SUB codes represent substances without registered CAS Numbers. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person. Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids apart for at least 10 minutes and seek immediate medical advice. Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting. United States Page: 2/12 PP610 PORTER PAINTS ACRI-SHIELD EXTERIOR GLOSS ACRYLIC-BLACKProduct name 5Product code Date of issue Version0040967625 June 2018 Section 4. First aid measures Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments :No specific treatment. Most important symptoms/effects, acute and delayed Inhalation : :Ingestion Skin contact : :Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact :No specific data. Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon oxides In a fire or if heated, a pressure increase will occur and the container may burst. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : United States Page: 3/12 PP610 PORTER PAINTS ACRI-SHIELD EXTERIOR GLOSS ACRYLIC-BLACKProduct name 5Product code Date of issue Version0040967625 June 2018 Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Advice on general occupational hygiene Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. : Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Special precautions :If this material is part of a multiple component system, read the Safety Data Sheet(s) for the other component or components before blending as the resulting mixture may have the hazards of all of its parts. United States Page: 4/12 PP610 PORTER PAINTS ACRI-SHIELD EXTERIOR GLOSS ACRYLIC-BLACKProduct name 5Product code Date of issue Version0040967625 June 2018 Section 7. Handling and storage Conditions for safe storage, including any incompatibilities Do not store below the following temperature: 5°C (41°F). Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : carbon black, respirable powder ACGIH TLV (United States, 3/2017). TWA: 3 mg/m³ 8 hours. Form: Inhalable fraction OSHA PEL (United States, 6/2016). TWA: 3.5 mg/m³ 8 hours. propane-1,2-diol IPEL (PPG). TWA: 10 mg/m³ 1,2-benzisothiazol-3(2H)-one None. diammonium peroxodisulphate ACGIH TLV (United States, 3/2017). TWA: 0.1 mg/m³, (as persulfate) 8 hours. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Environmental exposure controls :Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls :If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Control parameters Individual protection measures Occupational exposure limits Recommended monitoring procedures :If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required. Key to abbreviations A Acceptable Maximum Peak= ACGIH =American Conference of Governmental Industrial Hygienists. C =Ceiling Limit Potential skin absorptionS SR =Respiratory sensitization =Skin sensitizationSS TD =Total dust Consult local authorities for acceptable exposure limits. =Threshold Limit ValueTLV TWA =Time Weighted Average Fume=F IPEL =Internal Permissible Exposure Limit =Occupational Safety and Health Administration.OSHA R =Respirable OSHA 29 CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z STEL = = Short term Exposure limit values United States Page: 5/12 PP610 PORTER PAINTS ACRI-SHIELD EXTERIOR GLOSS ACRYLIC-BLACKProduct name 5Product code Date of issue Version0040967625 June 2018 Section 8. Exposure controls/personal protection Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Skin protection Other skin protection : Safety glasses with side shields. Gloves For prolonged or repeated handling, use the following type of gloves: Recommended: Viton®, PVC, natural rubber (latex), nitrile rubber : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Liquid. Not available. Not available. Characteristic.Odor pH Not available.Color Evaporation rate Not available. Auto-ignition temperature Flash point Not available. Closed cup: 113.33°C (236°F) [Product does not sustain combustion.] Not available. Not available.Odor threshold : : : : : : : : : : Appearance Boiling point :>37.78°C (>100°F) Flammability (solid, gas):Not available. Lower and upper explosive (flammable) limits :Not available. Decomposition temperature :Not available. United States Page: 6/12 PP610 PORTER PAINTS ACRI-SHIELD EXTERIOR GLOSS ACRYLIC-BLACKProduct name 5Product code Date of issue Version0040967625 June 2018 Section 9. Physical and chemical properties Relative density Vapor density Solubility 1.04 Not available. Soluble in the following materials: cold water. Not available. Viscosity Kinematic (40°C (104°F)): <0.14 cm2/s (<14 cSt) Partition coefficient: n- octanol/water : : : : : % Solid. (w/w):33.308 Density ( lbs / gal ):8.68 Volatility :70% (v/v), 66.692% (w/w) Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid The product is stable.Chemical stability : : : Incompatible materials : Possibility of hazardous reactions :Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity :No specific test data related to reactivity available for this product or its ingredients. When exposed to high temperatures may produce hazardous decomposition products. Keep away from the following materials to prevent strong exothermic reactions: oxidizing agents, strong alkalis, strong acids. Decomposition products may include the following materials: carbon monoxide, carbon dioxide, smoke, oxides of nitrogen. Refer to protective measures listed in sections 7 and 8. Section 11. Toxicological information Acute toxicity carbon black, respirable powder LD50 Dermal Rabbit >3 g/kg - LD50 Oral Rat >15400 mg/kg - propane-1,2-diol LD50 Dermal Rabbit 20800 mg/kg - LD50 Oral Rat 20 g/kg - 1,2-benzisothiazol-3(2H)-one LC50 Inhalation Dusts and mists Rat 0.4 mg/l 4 hours LD50 Oral Rat 1020 mg/kg - diammonium peroxodisulphate LD50 Oral Rat 0.6 g/kg - Product/ingredient name Result Species Dose Exposure Conclusion/Summary : Irritation/Corrosion Conclusion/Summary Information on toxicological effects There are no data available on the mixture itself. United States Page: 7/12 PP610 PORTER PAINTS ACRI-SHIELD EXTERIOR GLOSS ACRYLIC-BLACKProduct name 5Product code Date of issue Version0040967625 June 2018 Section 11. Toxicological information Carcinogenicity Conclusion/Summary : Mutagenicity Conclusion/Summary : Teratogenicity Conclusion/Summary : Reproductive toxicity Conclusion/Summary : Skin : Eyes : Respiratory : Sensitization 1,2-benzisothiazol-3(2H)-one skin Guinea pig Sensitizing Product/ingredient name Route of exposure Species Result Conclusion/Summary Skin : Respiratory : Specific target organ toxicity (single exposure) Classification carbon black, respirable powder -2B - Product/ingredient name NTPIARCOSHA Carcinogen Classification code: IARC: 1, 2A, 2B, 3, 4 NTP: Known to be a human carcinogen; Reasonably anticipated to be a human carcinogen OSHA: + Not listed/not regulated: - There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. Name Information on the likely routes of exposure Specific target organ toxicity (repeated exposure) diammonium peroxodisulphate Category 3 Category Not available. Aspiration hazard Not available. Potential acute health effects No known significant effects or critical hazards.:Eye contact Target organs :Contains material which may cause damage to the following organs: lungs, upper respiratory tract, eyes. United States Page: 8/12 PP610 PORTER PAINTS ACRI-SHIELD EXTERIOR GLOSS ACRYLIC-BLACKProduct name 5Product code Date of issue Version0040967625 June 2018 Section 11. Toxicological information Conclusion/Summary : General : Carcinogenicity : Mutagenicity : Teratogenicity : Developmental effects : Fertility effects : Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Oral 83845.4 mg/kg Route ATE value Acute toxicity estimates Potential immediate effects : Short term exposure Potential delayed effects : Potential immediate effects : Long term exposure Potential delayed effects : Inhalation :No known significant effects or critical hazards. No known significant effects or critical hazards.:Ingestion Skin contact :No known significant effects or critical hazards. Over-exposure signs/symptoms Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact :No specific data. Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. There are no data available on the mixture itself. If splashed in the eyes, the liquid may cause irritation and reversible damage. Ingestion may cause nausea, diarrhea and vomiting. This takes into account, where known, delayed and immediate effects and also chronic effects of components from short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. Section 12. Ecological information Toxicity 1,2-benzisothiazol-3(2H)-one Acute EC50 0.11 mg/l Algae 72 hours Chronic NOEC 0.09 mg/l Fish 28 days Product/ingredient name SpeciesResult Exposure Persistence and degradability United States Page: 9/12 PP610 PORTER PAINTS ACRI-SHIELD EXTERIOR GLOSS ACRYLIC-BLACKProduct name 5Product code Date of issue Version0040967625 June 2018 Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Product/ingredient name propane-1,2-diol -0.92 -low 1,2-benzisothiazol-3(2H)-one 0.7 -low Product/ingredient name Aquatic half-life Photolysis Biodegradability 1,2-benzisothiazol-3(2H)-one --Readily Soil/water partition coefficient (KOC) :Not available. Mobility in soil Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Disposal should be in accordance with applicable regional, national and local laws and regulations. Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 6. Accidental release measures 14. Transport information - - - - - - - Not regulated. - - Not regulated.Not regulated. DOT IMDG IATA UN number UN proper shipping name Transport hazard class (es) Packing group Environmental hazards No.No.No. Marine pollutant substances Not applicable.Not applicable.Not applicable. United States Page: 10/12 PP610 PORTER PAINTS ACRI-SHIELD EXTERIOR GLOSS ACRYLIC-BLACKProduct name 5Product code Date of issue Version0040967625 June 2018 14. Transport information Special precautions for user Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Additional information None identified. None identified. DOT IMDG : : IATA :None identified. Section 15. Regulatory information SARA 302/304 SARA 304 RQ :Not applicable. Composition/information on ingredients All components are listed or exempted.United States inventory (TSCA 8b): United States Additional environmental information is contained on the Environmental Data Sheet for this product, which can be obtained from your PPG representative. California Prop. 65 No products were found. SARA 311/312 Classification :CARCINOGENICITY - Category 2 carbon black, respirable powder ≥1.0 - ≤5.0 COMBUSTIBLE DUSTS CARCINOGENICITY - Category 2 1,2-benzisothiazol-3(2H)-one <0.10 COMBUSTIBLE DUSTS ACUTE TOXICITY (oral) - Category 4 ACUTE TOXICITY (inhalation) - Category 2 SKIN IRRITATION - Category 2 SERIOUS EYE DAMAGE - Category 1 SKIN SENSITIZATION - Category 1A diammonium peroxodisulphate <0.10 OXIDIZING SOLIDS - Category 3 ACUTE TOXICITY (oral) - Category 4 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A RESPIRATORY SENSITIZATION - Category 1A SKIN SENSITIZATION - Category 1B SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Name %Classification Composition/information on ingredients WARNING: Cancer - www.P65Warnings.ca.gov. United States Page: 11/12 PP610 PORTER PAINTS ACRI-SHIELD EXTERIOR GLOSS ACRYLIC-BLACKProduct name 5Product code Date of issue Version0040967625 June 2018 Section 16. Other information Key to abbreviations :ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations Hazardous Material Information System (U.S.A.) 1 01 National Fire Protection Association (U.S.A.) Health InstabilityFlammability Health Flammability Physical hazards Disclaimer The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products. Date of previous issue 3/30/2018: Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on MSDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual. Indicates information that has changed from previously issued version. Organization that prepared the MSDS :EHS ::: :::1 * 1 0 ( * ) - Chronic effects United States Page: 12/12 PP649 PORTER PAINTS ACRI-SHIELD EXTERIOR SEMI-GLOSS 100% ACRYLIC- LIGHT BASE Not available. Liquid. SAFETY DATA SHEET Product name Other means of identification Product type Section 1. Identification : : : Product code :00404790 Date of issue/Date of revision 24 June 2018 Version 5.04 Relevant identified uses of the substance or mixture and uses advised against Uses advised against Not applicable. Product use :Consumer applications, Professional applications, Used by spraying. Use of the substance/ mixture :Coating. : Manufacturer PPG Industries, Inc. One PPG Place Pittsburgh, PA 15272 (412) 434-4515 (U.S.) (514) 645-1320 (Canada) 01-800-00-21-400 or + 52 55 5559 1588 (Mexico) Emergency telephone number : : Technical Phone Number :1-800-441-9695 (8:00 am to 5:00 pm EST) Section 2. Hazards identification SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2 Classification of the substance or mixture : GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 23.2% (Oral), 24.4% (Dermal), 24.4% (Inhalation) OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). This product contains TiO2 which has been classified as a GHS Carcinogen Category 2 based on its IARC 2B classification. For many PPG products, TiO2 is utilized as a raw material in a liquid coating formulation. In this case, the TiO2 particles are bound in a matrix with no meaningful potential for human exposure to unbound particles of TiO2 when the product is applied with a brush or roller. Sanding the coating surface or mist from spray applications may be harmful depending on the duration and level of exposure and require the use of appropriate personal protective equipment and/or engineering controls (see Section 8). United States Page: 1/13 PP649 PORTER PAINTS ACRI-SHIELD EXTERIOR SEMI-GLOSS 100% ACRYLIC- LIGHT BASE Product name 5.04Product code Date of issue Version0040479024 June 2018 Section 2. Hazards identification Signal word :Warning Hazard statements :May cause an allergic skin reaction. Suspected of causing cancer. Hazard pictograms : Precautionary statements Prevention :Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection. Wear protective clothing. Avoid breathing vapor. Contaminated work clothing must not be allowed out of the workplace. Response :IF exposed or concerned: Get medical attention. IF ON SKIN: Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical attention. Storage :Store locked up. Disposal :Dispose of contents and container in accordance with all local, regional, national and international regulations. General :Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Supplemental label elements :Contains isothiazolinones. May cause allergic reaction. Emits toxic fumes when heated. Hazards not otherwise classified :None known. Photosensitive agents : In case of accidental eye contact, avoid concurrent exposure to the sun or other sources of UV light which may increase the sensitivity of the eyes. In case of accidental skin contact, avoid concurrent exposure to the sun or other sources of UV light which may increase the sensitivity of skin. Section 3. Composition/information on ingredients titanium dioxide ≥10 - ≤20 13463-67-7 propane-1,2-diol ≥1.0 - ≤5.0 57-55-6 octhilinone (ISO)<1.0 26530-20-1 Ingredient name CAS number% There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Substance/mixture :Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. Product name PP649 PORTER PAINTS ACRI-SHIELD EXTERIOR SEMI-GLOSS 100% ACRYLIC- LIGHT BASE : SUB codes represent substances without registered CAS Numbers. United States Page: 2/13 PP649 PORTER PAINTS ACRI-SHIELD EXTERIOR SEMI-GLOSS 100% ACRYLIC- LIGHT BASE Product name 5.04Product code Date of issue Version0040479024 June 2018 Section 3. Composition/information on ingredients Occupational exposure limits, if available, are listed in Section 8. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Description of necessary first aid measures Specific treatments :No specific treatment. Most important symptoms/effects, acute and delayed Inhalation : :Ingestion Skin contact : :Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation No specific data. No specific data. Adverse symptoms may include the following: irritation redness : : : Eye contact :No specific data. Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary In case of accidental eye contact, avoid concurrent exposure to the sun or other sources of UV light which may increase the sensitivity of the eyes. In case of accidental skin contact, avoid concurrent exposure to the sun or other sources of UV light which may increase the sensitivity of skin. If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person. Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids apart for at least 10 minutes and seek immediate medical advice. Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. May cause an allergic skin reaction. United States Page: 3/13 PP649 PORTER PAINTS ACRI-SHIELD EXTERIOR SEMI-GLOSS 100% ACRYLIC- LIGHT BASE Product name 5.04Product code Date of issue Version0040479024 June 2018 Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon oxides metal oxide/oxides In a fire or if heated, a pressure increase will occur and the container may burst. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures : :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". United States Page: 4/13 PP649 PORTER PAINTS ACRI-SHIELD EXTERIOR SEMI-GLOSS 100% ACRYLIC- LIGHT BASE Product name 5.04Product code Date of issue Version0040479024 June 2018 Section 6. Accidental release measures Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Large spill : Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Do not store below the following temperature: 5°C (41°F). Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Special precautions :If this material is part of a multiple component system, read the Safety Data Sheet(s) for the other component or components before blending as the resulting mixture may have the hazards of all of its parts. Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits United States Page: 5/13 PP649 PORTER PAINTS ACRI-SHIELD EXTERIOR SEMI-GLOSS 100% ACRYLIC- LIGHT BASE Product name 5.04Product code Date of issue Version0040479024 June 2018 Section 8. Exposure controls/personal protection titanium dioxide OSHA PEL (United States, 6/2016). TWA: 15 mg/m³ 8 hours. Form: Total dust ACGIH TLV (United States, 3/2017). TWA: 10 mg/m³ 8 hours. propane-1,2-diol IPEL (PPG). TWA: 10 mg/m³ octhilinone (ISO)None. Ingredient name Exposure limits Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Eye/face protection : : Environmental exposure controls :Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls :If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Recommended monitoring procedures :If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required. Safety glasses with side shields. Key to abbreviations A Acceptable Maximum Peak= ACGIH =American Conference of Governmental Industrial Hygienists. C =Ceiling Limit Potential skin absorptionS SR =Respiratory sensitization =Skin sensitizationSS TD =Total dust Consult local authorities for acceptable exposure limits. =Threshold Limit ValueTLV TWA =Time Weighted Average Fume=F IPEL =Internal Permissible Exposure Limit =Occupational Safety and Health Administration.OSHA R =Respirable OSHA 29 CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z STEL = = Short term Exposure limit values United States Page: 6/13 PP649 PORTER PAINTS ACRI-SHIELD EXTERIOR SEMI-GLOSS 100% ACRYLIC- LIGHT BASE Product name 5.04Product code Date of issue Version0040479024 June 2018 Section 8. Exposure controls/personal protection Respiratory protection : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Other skin protection : Gloves butyl rubber polyethylene: Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. Not available. 1.15 Not available. Not available. Soluble in the following materials: cold water. Characteristic.Odor pH Not available.Color Evaporation rate Not available. Auto-ignition temperature Flash point Not available. Closed cup: 113.33°C (236°F) [Product does not sustain combustion.] Not available. Not available. Viscosity Kinematic (40°C (104°F)): <0.14 cm2/s (<14 cSt) Not available.Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point :>37.78°C (>100°F) Flammability (solid, gas):Not available. Lower and upper explosive (flammable) limits :Not available. Decomposition temperature :Not available. % Solid. (w/w):39.16 Density ( lbs / gal ):9.6 Volatility :70% (v/v), 60.84% (w/w) United States Page: 7/13 PP649 PORTER PAINTS ACRI-SHIELD EXTERIOR SEMI-GLOSS 100% ACRYLIC- LIGHT BASE Product name 5.04Product code Date of issue Version0040479024 June 2018 Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid The product is stable.Chemical stability : : : Incompatible materials : Possibility of hazardous reactions :Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity :No specific test data related to reactivity available for this product or its ingredients. When exposed to high temperatures may produce hazardous decomposition products. Keep away from the following materials to prevent strong exothermic reactions: oxidizing agents, strong alkalis, strong acids. Decomposition products may include the following materials: carbon monoxide, carbon dioxide, smoke, oxides of nitrogen. Refer to protective measures listed in sections 7 and 8. Section 11. Toxicological information Acute toxicity titanium dioxide LC50 Inhalation Dusts and mists Rat >6.82 mg/l 4 hours LD50 Dermal Rabbit >5000 mg/kg - LD50 Oral Rat >5000 mg/kg - propane-1,2-diol LD50 Dermal Rabbit 20800 mg/kg - LD50 Oral Rat 20 g/kg - octhilinone (ISO)LD50 Dermal Rabbit 0.69 g/kg - LD50 Oral Rat 0.55 g/kg - Product/ingredient name Result Species Dose Exposure Conclusion/Summary : Mutagenicity Irritation/Corrosion Conclusion/Summary Skin : Eyes : Respiratory : Sensitization octhilinone (ISO)skin Mouse Sensitizing Product/ingredient name Route of exposure Species Result Conclusion/Summary Skin : Respiratory : Information on toxicological effects There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. United States Page: 8/13 PP649 PORTER PAINTS ACRI-SHIELD EXTERIOR SEMI-GLOSS 100% ACRYLIC- LIGHT BASE Product name 5.04Product code Date of issue Version0040479024 June 2018 Section 11. Toxicological information Carcinogenicity Conclusion/Summary : Conclusion/Summary : Teratogenicity Conclusion/Summary : Reproductive toxicity Conclusion/Summary : Specific target organ toxicity (single exposure) Classification titanium dioxide -2B - Product/ingredient name NTPIARCOSHA Carcinogen Classification code: IARC: 1, 2A, 2B, 3, 4 NTP: Known to be a human carcinogen; Reasonably anticipated to be a human carcinogen OSHA: + Not listed/not regulated: - There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. Information on the likely routes of exposure Delayed and immediate effects and also chronic effects from short and long term exposure Specific target organ toxicity (repeated exposure) Not available. Not available. Aspiration hazard Not available. Potential acute health effects Inhalation :No known significant effects or critical hazards. No known significant effects or critical hazards.:Ingestion Skin contact :May cause an allergic skin reaction. No known significant effects or critical hazards.:Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation No specific data. No specific data. Adverse symptoms may include the following: irritation redness : : : Eye contact :No specific data. Target organs :Contains material which may cause damage to the following organs: upper respiratory tract. United States Page: 9/13 PP649 PORTER PAINTS ACRI-SHIELD EXTERIOR SEMI-GLOSS 100% ACRYLIC- LIGHT BASE Product name 5.04Product code Date of issue Version0040479024 June 2018 Section 11. Toxicological information Conclusion/Summary : General : Carcinogenicity : Mutagenicity : Teratogenicity : Developmental effects : Fertility effects : Potential chronic health effects Numerical measures of toxicity Oral 200053.8 mg/kg Route ATE value Acute toxicity estimates Potential immediate effects : Short term exposure Potential delayed effects : Potential immediate effects : Long term exposure Potential delayed effects : Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. There are no data available on the mixture itself. This product contains TiO2 which has been classified as a GHS Carcinogen Category 2 based on its IARC 2B classification. For many PPG products, TiO2 is utilized as a raw material in a liquid coating formulation. In this case, the TiO2 particles are bound in a matrix with no meaningful potential for human exposure to unbound particles of TiO2 when the product is applied with a brush or roller. Sanding the coating surface or mist from spray applications may be harmful depending on the duration and level of exposure and require the use of appropriate personal protective equipment and/or engineering controls (see Section 8). Acrylate components of the mixture have irritating properties. Prolonged or repeated contact with skin or mucous membrane may result in irritation symptoms, such as redness, blistering, dermatitis etc. May cause allergic skin reactions with repeated exposure. The inhalation of airborne droplets or aerosols may cause irritation of the respiratory tract. Ingestion may cause nausea, weakness and central nervous system effects. If splashed in the eyes, the liquid may cause irritation and reversible damage. This takes into account, where known, delayed and immediate effects and also chronic effects of components from short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. United States Page: 10/13 PP649 PORTER PAINTS ACRI-SHIELD EXTERIOR SEMI-GLOSS 100% ACRYLIC- LIGHT BASE Product name 5.04Product code Date of issue Version0040479024 June 2018 Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Product/ingredient name propane-1,2-diol -0.92 -low octhilinone (ISO)2.45 -low Toxicity titanium dioxide Acute LC50 >100 mg/l Fresh water Daphnia - Daphnia magna 48 hours Product/ingredient name SpeciesResult Exposure Persistence and degradability Soil/water partition coefficient (KOC) :Not available. Mobility in soil Not available. Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Disposal should be in accordance with applicable regional, national and local laws and regulations. Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 6. Accidental release measures 14. Transport information United States Page: 11/13 PP649 PORTER PAINTS ACRI-SHIELD EXTERIOR SEMI-GLOSS 100% ACRYLIC- LIGHT BASE Product name 5.04Product code Date of issue Version0040479024 June 2018 14. Transport information - - - - - - - Not regulated. - - Not regulated.Not regulated. DOT IMDG IATA UN number UN proper shipping name Transport hazard class (es) Packing group Environmental hazards No.No.No. Marine pollutant substances Not applicable.Not applicable.Not applicable. Special precautions for user Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Additional information None identified. None identified. DOT IMDG : : IATA :None identified. Section 15. Regulatory information SARA 302/304 SARA 304 RQ :Not applicable. Composition/information on ingredients All components are listed or exempted.United States inventory (TSCA 8b): United States No products were found. SARA 311/312 Classification :SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2 titanium dioxide ≥10 - ≤20 CARCINOGENICITY - Category 2 octhilinone (ISO)<1.0 ACUTE TOXICITY (oral) - Category 4 ACUTE TOXICITY (dermal) - Category 3 ACUTE TOXICITY (inhalation) - Category 2 SKIN CORROSION - Category 1 SERIOUS EYE DAMAGE - Category 1 SKIN SENSITIZATION - Category 1A Name %Classification Composition/information on ingredients United States Page: 12/13 PP649 PORTER PAINTS ACRI-SHIELD EXTERIOR SEMI-GLOSS 100% ACRYLIC- LIGHT BASE Product name 5.04Product code Date of issue Version0040479024 June 2018 Section 15. Regulatory information Additional environmental information is contained on the Environmental Data Sheet for this product, which can be obtained from your PPG representative. Section 16. Other information Key to abbreviations :ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations Hazardous Material Information System (U.S.A.) 1 01 National Fire Protection Association (U.S.A.) Health InstabilityFlammability Health Flammability Physical hazards Disclaimer The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products. Date of previous issue 6/5/2018: Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on MSDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual. Indicates information that has changed from previously issued version. Organization that prepared the MSDS :EHS ::: :::2 * 2 0 ( * ) - Chronic effects United States Page: 13/13 1414X PPG TOP GUN 200XI SILICONIZED ACRYLIC SEALANT - WHITE Not available. Solid. SAFETY DATA SHEET Product name Other means of identification Product type Section 1. Identification : : : Product code :00378507 Date of issue/Date of revision 23 June 2018 Version 10 Relevant identified uses of the substance or mixture and uses advised against Uses advised against Not applicable. Product use :Consumer applications, Professional applications. Use of the substance/ mixture :Sealants; Adhesive. : Manufacturer PPG Industries, Inc. One PPG Place Pittsburgh, PA 15272 (412) 434-4515 (U.S.) (514) 645-1320 (Canada) 01-800-00-21-400 or + 52 55 5559 1588 (Mexico) Emergency telephone number : : Technical Phone Number :1-800-441-9695 (8:00 am to 5:00 pm EST) Section 2. Hazards identification CARCINOGENICITY - Category 1A SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (kidneys) - Category 2 Classification of the substance or mixture : Signal word :Danger Hazard statements :May cause cancer. May cause damage to organs through prolonged or repeated exposure. (kidneys) Hazard pictograms : GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 76.2% (Oral), 80.3% (Dermal), 25.8% (Inhalation) OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). United States Page: 1/14 1414X PPG TOP GUN 200XI SILICONIZED ACRYLIC SEALANT - WHITEProduct name 10Product code Date of issue Version0037850723 June 2018 Section 2. Hazards identification Precautionary statements Prevention :Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection. Wear protective clothing. Do not breathe dust. Response :Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. Storage :Store locked up. Disposal :Dispose of contents and container in accordance with all local, regional, national and international regulations. General :Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Supplemental label elements :Contains isothiazolinones. May cause allergic reaction. Sanding and grinding dusts may be harmful if inhaled. This product contains crystalline silica which can cause lung cancer or silicosis. The risk of cancer depends on the duration and level of exposure to dust from sanding surfaces or mist from spray applications. This product either contains formaldehyde or is capable of releasing formaldehyde above 0.5 ppm under certain conditions. Formaldehyde is a known cancer hazard, a skin sensitizer and a respiratory sensitizer. Avoid contact with skin and clothing. Wash thoroughly after handling. Emits toxic fumes when heated. Hazards not otherwise classified :Prolonged or repeated contact may dry skin and cause irritation. Section 3. Composition/information on ingredients Limestone ≥50 - ≤75 1317-65-3 ethanediol ≥1.0 - ≤3.7 107-21-1 titanium dioxide ≤1.0 13463-67-7 crystalline silica, respirable powder (<10 microns)<1.0 14808-60-7 Formaldehyde, solution <0.10 50-00-0 1,2-benzisothiazol-3(2H)-one <0.10 2634-33-5 Ingredient name CAS number% There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Substance/mixture : Occupational exposure limits, if available, are listed in Section 8. Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. Product name 1414X PPG TOP GUN 200XI SILICONIZED ACRYLIC SEALANT - WHITE: SUB codes represent substances without registered CAS Numbers. United States Page: 2/14 1414X PPG TOP GUN 200XI SILICONIZED ACRYLIC SEALANT - WHITEProduct name 10Product code Date of issue Version0037850723 June 2018 Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Description of necessary first aid measures Specific treatments :No specific treatment. Most important symptoms/effects, acute and delayed Inhalation : :Ingestion Skin contact : :Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation No specific data. No specific data. Adverse symptoms may include the following: irritation dryness cracking : : : Eye contact :No specific data. Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person. Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids apart for at least 10 minutes and seek immediate medical advice. Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Defatting to the skin. May cause skin dryness and irritation. United States Page: 3/14 1414X PPG TOP GUN 200XI SILICONIZED ACRYLIC SEALANT - WHITEProduct name 10Product code Date of issue Version0037850723 June 2018 Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon oxides metal oxide/oxides Formaldehyde. No specific fire or explosion hazard. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Avoid dust generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled waste container. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Move containers from spill area. Avoid dust generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled waste container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". United States Page: 4/14 1414X PPG TOP GUN 200XI SILICONIZED ACRYLIC SEALANT - WHITEProduct name 10Product code Date of issue Version0037850723 June 2018 Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Do not store below the following temperature: 5°C (41°F). Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not ingest. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Special precautions :If this material is part of a multiple component system, read the Safety Data Sheet(s) for the other component or components before blending as the resulting mixture may have the hazards of all of its parts. Limestone OSHA PEL (United States, 6/2016). TWA: 5 mg/m³ 8 hours. Form: Respirable fraction TWA: 15 mg/m³ 8 hours. Form: Total dust ethanediol ACGIH TLV (United States, 3/2017). STEL: 10 mg/m³ 15 minutes. Form: Inhalable fraction. Aerosol only. STEL: 50 ppm 15 minutes. Form: Vapor fraction TWA: 25 ppm 8 hours. Form: Vapor fraction titanium dioxide OSHA PEL (United States, 6/2016). TWA: 15 mg/m³ 8 hours. Form: Total dust ACGIH TLV (United States, 3/2017). TWA: 10 mg/m³ 8 hours. crystalline silica, respirable powder (<10 microns)ACGIH TLV (United States, 3/2017). TWA: 0.025 mg/m³ 8 hours. Form: Respirable OSHA PEL Z3 (United States, 6/2016). TWA: 10 mg/m³ / (%SiO2+2) 8 hours. Form: Respirable Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits United States Page: 5/14 1414X PPG TOP GUN 200XI SILICONIZED ACRYLIC SEALANT - WHITEProduct name 10Product code Date of issue Version0037850723 June 2018 Section 8. Exposure controls/personal protection TWA: 250 mppcf / (%SiO2+5) 8 hours. Form: Respirable OSHA PEL (United States, 6/2016). TWA: 50 µg/m³ 8 hours. Form: Respirable dust Formaldehyde, solution OSHA PEL (United States, 6/2016). STEL: 2 ppm 15 minutes. TWA: 0.75 ppm 8 hours. OSHA PEL Z2 (United States, 2/2013). STEL: 2 ppm 15 minutes. TWA: 0.75 ppm 8 hours. ACGIH TLV (United States, 3/2017). Skin sensitizer. Inhalation sensitizer. STEL: 0.3 ppm 15 minutes. TWA: 0.1 ppm 8 hours. 1,2-benzisothiazol-3(2H)-one None. Eye/face protection : Environmental exposure controls :Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls :If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Recommended monitoring procedures :If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required. Safety glasses with side shields. Key to abbreviations A Acceptable Maximum Peak= ACGIH =American Conference of Governmental Industrial Hygienists. C =Ceiling Limit Potential skin absorptionS SR =Respiratory sensitization =Skin sensitizationSS TD =Total dust Consult local authorities for acceptable exposure limits. =Threshold Limit ValueTLV TWA =Time Weighted Average Fume=F IPEL =Internal Permissible Exposure Limit =Occupational Safety and Health Administration.OSHA R =Respirable OSHA 29 CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z STEL = = Short term Exposure limit values United States Page: 6/14 1414X PPG TOP GUN 200XI SILICONIZED ACRYLIC SEALANT - WHITEProduct name 10Product code Date of issue Version0037850723 June 2018 Section 8. Exposure controls/personal protection Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Respiratory protection : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Solid. Not available. 1.64 Not available. Not available. Insoluble in the following materials: cold water. Characteristic.Odor pH Not available.Color Evaporation rate Not available. Auto-ignition temperature Flash point Not available. Closed cup: 93.89°C (201°F) [Product does not sustain combustion.] Not available. Not available. Viscosity Kinematic (40°C (104°F)): Not applicable. Not available.Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point :Not available. Flammability (solid, gas):Not available. Lower and upper explosive (flammable) limits :Not available. Decomposition temperature :Not available. % Solid. (w/w):82.816 Density ( lbs / gal ):13.69 Volatility :28% (v/v), 17.184% (w/w) United States Page: 7/14 1414X PPG TOP GUN 200XI SILICONIZED ACRYLIC SEALANT - WHITEProduct name 10Product code Date of issue Version0037850723 June 2018 Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid The product is stable.Chemical stability : : : Incompatible materials : Possibility of hazardous reactions :Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity :No specific test data related to reactivity available for this product or its ingredients. When exposed to high temperatures may produce hazardous decomposition products. Keep away from the following materials to prevent strong exothermic reactions: oxidizing agents, strong alkalis, strong acids. Decomposition products may include the following materials: carbon monoxide, carbon dioxide, smoke, oxides of nitrogen. Refer to protective measures listed in sections 7 and 8. Section 11. Toxicological information Acute toxicity ethanediol LD50 Dermal Rabbit 9.53 g/kg - LD50 Oral Rat 4700 mg/kg - titanium dioxide LC50 Inhalation Dusts and mists Rat >6.82 mg/l 4 hours LD50 Dermal Rabbit >5000 mg/kg - LD50 Oral Rat >5000 mg/kg - Formaldehyde, solution LC50 Inhalation Gas.Rat 250 ppm 4 hours LD50 Dermal Rabbit 270 mg/kg - LD50 Oral Rat 100 mg/kg - 1,2-benzisothiazol-3(2H)-one LC50 Inhalation Dusts and mists Rat 0.4 mg/l 4 hours LD50 Oral Rat 1020 mg/kg - Product/ingredient name Result Species Dose Exposure Conclusion/Summary : Irritation/Corrosion Conclusion/Summary Skin : Eyes : Respiratory : Sensitization 1,2-benzisothiazol-3(2H)-one skin Guinea pig Sensitizing Product/ingredient name Route of exposure Species Result Conclusion/Summary Skin : Information on toxicological effects There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. United States Page: 8/14 1414X PPG TOP GUN 200XI SILICONIZED ACRYLIC SEALANT - WHITEProduct name 10Product code Date of issue Version0037850723 June 2018 Section 11. Toxicological information Carcinogenicity Conclusion/Summary : Mutagenicity Conclusion/Summary : Teratogenicity Conclusion/Summary : Reproductive toxicity Conclusion/Summary : Respiratory : Specific target organ toxicity (single exposure) Classification titanium dioxide -2B - crystalline silica, respirable powder (<10 microns) -1 Known to be a human carcinogen. Formaldehyde, solution +1 Known to be a human carcinogen. Product/ingredient name NTPIARCOSHA Carcinogen Classification code: IARC: 1, 2A, 2B, 3, 4 NTP: Known to be a human carcinogen; Reasonably anticipated to be a human carcinogen OSHA: + Not listed/not regulated: - There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. Name Information on the likely routes of exposure Specific target organ toxicity (repeated exposure) Formaldehyde, solution Category 3 Category Name Category ethanediol Category 2 crystalline silica, respirable powder (<10 microns)Category 1 Aspiration hazard Not available. Potential acute health effects Inhalation :No known significant effects or critical hazards. No known significant effects or critical hazards.:Ingestion Skin contact :Defatting to the skin. May cause skin dryness and irritation. No known significant effects or critical hazards.:Eye contact Over-exposure signs/symptoms Inhalation No specific data.: Eye contact :No specific data. Target organs :Contains material which may cause damage to the following organs: blood, kidneys, lungs, upper respiratory tract, skin, eyes, central nervous system (CNS). United States Page: 9/14 1414X PPG TOP GUN 200XI SILICONIZED ACRYLIC SEALANT - WHITEProduct name 10Product code Date of issue Version0037850723 June 2018 Section 11. Toxicological information Conclusion/Summary : General : Carcinogenicity : Mutagenicity : Teratogenicity : Developmental effects : Fertility effects : Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Oral 6265.7 mg/kg Route ATE value Acute toxicity estimates Potential immediate effects : Short term exposure Potential delayed effects : Potential immediate effects : Long term exposure Potential delayed effects : Skin contact Ingestion No specific data. Adverse symptoms may include the following: irritation dryness cracking : : May cause cancer. Risk of cancer depends on duration and level of exposure. There are no data available on the mixture itself. This product either contains formaldehyde or is capable of releasing formaldehyde above 0.5 ppm under certain conditions. Formaldehyde is a known cancer hazard, a skin sensitizer and a respiratory sensitizer. This product contains crystalline silica which can cause lung cancer or silicosis. The risk of cancer depends on the duration and level of exposure to dust from sanding surfaces or mist from spray applications. Ingestion may cause nausea, diarrhea and vomiting. This takes into account, where known, delayed and immediate effects and also chronic effects of components from short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact. May cause damage to organs through prolonged or repeated exposure. Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. Section 12. Ecological information Toxicity titanium dioxide Acute LC50 >100 mg/l Fresh water Daphnia - Daphnia magna 48 hours Formaldehyde, solution Acute EC50 3.48 mg/l Fresh water Algae - Desmodesmus subspicatus 72 hours 1,2-benzisothiazol-3(2H)-one Acute EC50 0.11 mg/l Algae 72 hours Chronic NOEC 0.09 mg/l Fish 28 days Product/ingredient name SpeciesResult Exposure United States Page: 10/14 1414X PPG TOP GUN 200XI SILICONIZED ACRYLIC SEALANT - WHITEProduct name 10Product code Date of issue Version0037850723 June 2018 Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Product/ingredient name ethanediol -1.36 -low 1,2-benzisothiazol-3(2H)-one 0.7 -low Product/ingredient name Aquatic half-life Photolysis Biodegradability 1,2-benzisothiazol-3(2H)-one --Readily Persistence and degradability Soil/water partition coefficient (KOC) :Not available. Mobility in soil Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Disposal should be in accordance with applicable regional, national and local laws and regulations. Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 6. Accidental release measures 14. Transport information ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. 9 III - - - - Not regulated. - - UN3077 Not regulated. DOT IMDG IATA UN number UN proper shipping name Transport hazard class (es) Packing group Environmental hazards No.No.No. (carbendazim (ISO)) United States Page: 11/14 1414X PPG TOP GUN 200XI SILICONIZED ACRYLIC SEALANT - WHITEProduct name 10Product code Date of issue Version0037850723 June 2018 14. Transport information Marine pollutant substances Not applicable.Not applicable. RQ substances 29411.8 (carbendazim (ISO)) Not applicable. Not applicable. Not applicable. Not applicable. Not applicable. Special precautions for user Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Additional information The classification of the product is due solely to the presence of one or more US DOT-listed ‘Hazardous substances’ that are subject to reportable quantity requirements and only applies to shipments of packages greater than, or equal to, the product reportable quantity. Package sizes less than the product reportable quantity are not regulated as hazardous materials. None identified. DOT IMDG : : IATA :None identified. Product RQ (lbs) Section 15. Regulatory information SARA 302/304 SARA 304 RQ :Not applicable. Composition/information on ingredients All components are listed or exempted.United States inventory (TSCA 8b): United States No products were found. SARA 311/312 Classification :CARCINOGENICITY - Category 1A SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (kidneys) - Category 2 HNOC - Defatting irritant ethanediol ≥1.0 - ≤3.7 ACUTE TOXICITY (oral) - Category 4 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (kidneys) (oral) - Category 2 HNOC - Defatting irritant titanium dioxide ≤1.0 CARCINOGENICITY - Category 2 crystalline silica, respirable powder (<10 microns) <1.0 CARCINOGENICITY - Category 1A SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (inhalation) - Category 1 Formaldehyde, solution <0.10 FLAMMABLE LIQUIDS - Category 4 Name %Classification Composition/information on ingredients United States Page: 12/14 1414X PPG TOP GUN 200XI SILICONIZED ACRYLIC SEALANT - WHITEProduct name 10Product code Date of issue Version0037850723 June 2018 Section 15. Regulatory information SARA 313 SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed. Additional environmental information is contained on the Environmental Data Sheet for this product, which can be obtained from your PPG representative. California Prop. 65 Supplier notification Chemical name :ethanediol 107-21-1 0.5 - 1.5 CAS number Concentration ACUTE TOXICITY (oral) - Category 3 ACUTE TOXICITY (dermal) - Category 3 ACUTE TOXICITY (inhalation) - Category 3 SKIN CORROSION - Category 1B SERIOUS EYE DAMAGE - Category 1 RESPIRATORY SENSITIZATION - Category 1A SKIN SENSITIZATION - Category 1A GERM CELL MUTAGENICITY - Category 2 CARCINOGENICITY - Category 1A SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 1,2-benzisothiazol-3(2H)-one <0.10 COMBUSTIBLE DUSTS ACUTE TOXICITY (oral) - Category 4 ACUTE TOXICITY (inhalation) - Category 2 SKIN IRRITATION - Category 2 SERIOUS EYE DAMAGE - Category 1 SKIN SENSITIZATION - Category 1A WARNING: Cancer - www.P65Warnings.ca.gov. Section 16. Other information Hazardous Material Information System (U.S.A.) 1 01 National Fire Protection Association (U.S.A.) Health InstabilityFlammability Health Flammability Physical hazards Date of previous issue 5/4/2018: Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on MSDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual. Organization that prepared the MSDS :EHS ::: :::2 * 2 0 ( * ) - Chronic effects United States Page: 13/14 1414X PPG TOP GUN 200XI SILICONIZED ACRYLIC SEALANT - WHITEProduct name 10Product code Date of issue Version0037850723 June 2018 Section 16. Other information Key to abbreviations :ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations Disclaimer The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products. Indicates information that has changed from previously issued version. United States Page: 14/14 6-904XI SPEEDHIDE 100% ACRYLIC LATEX EXTERIOR SEMI-GLOSS-ULTRA DEEP BASE Not available. Liquid. SAFETY DATA SHEET Product name Other means of identification Product type Section 1. Identification : : : Product code :00408297 Date of issue/Date of revision 25 June 2018 Version 6.01 Relevant identified uses of the substance or mixture and uses advised against Uses advised against Not applicable. Product use :Consumer applications, Professional applications, Used by spraying. Use of the substance/ mixture :Coating. : Manufacturer PPG Industries, Inc. One PPG Place Pittsburgh, PA 15272 (412) 434-4515 (U.S.) (514) 645-1320 (Canada) 01-800-00-21-400 or + 52 55 5559 1588 (Mexico) Emergency telephone number : : Technical Phone Number :1-800-441-9695 (8:00 am to 5:00 pm EST) Section 2. Hazards identification SKIN SENSITIZATION - Category 1Classification of the substance or mixture : Signal word :Warning Hazard statements :May cause an allergic skin reaction. Hazard pictograms : Precautionary statements GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 27.4% (Oral), 27.4% (Dermal), 27.4% (Inhalation) OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). United States Page: 1/12 6-904XI SPEEDHIDE 100% ACRYLIC LATEX EXTERIOR SEMI-GLOSS-ULTRA DEEP BASE Product name 6.01Product code Date of issue Version0040829725 June 2018 Section 2. Hazards identification Prevention :Wear protective gloves. Avoid breathing vapor. Contaminated work clothing must not be allowed out of the workplace. Response :IF ON SKIN: Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical attention. Storage :Not applicable. Disposal :Dispose of contents and container in accordance with all local, regional, national and international regulations. General :Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Supplemental label elements :Contains isothiazolinones. May cause allergic reaction. Emits toxic fumes when heated. Hazards not otherwise classified :None known. Photosensitive agents : In case of accidental eye contact, avoid concurrent exposure to the sun or other sources of UV light which may increase the sensitivity of the eyes. In case of accidental skin contact, avoid concurrent exposure to the sun or other sources of UV light which may increase the sensitivity of skin. Section 3. Composition/information on ingredients octhilinone (ISO)<1.0 26530-20-1 Ingredient name CAS number% There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Substance/mixture : Occupational exposure limits, if available, are listed in Section 8. Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. Product name 6-904XI SPEEDHIDE 100% ACRYLIC LATEX EXTERIOR SEMI-GLOSS-ULTRA DEEP BASE : SUB codes represent substances without registered CAS Numbers. Section 4. First aid measures Eye contact Inhalation : : Description of necessary first aid measures In case of accidental eye contact, avoid concurrent exposure to the sun or other sources of UV light which may increase the sensitivity of the eyes. If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person. Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids apart for at least 10 minutes and seek immediate medical advice. Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. United States Page: 2/12 6-904XI SPEEDHIDE 100% ACRYLIC LATEX EXTERIOR SEMI-GLOSS-ULTRA DEEP BASE Product name 6.01Product code Date of issue Version0040829725 June 2018 Section 4. First aid measures Skin contact Ingestion : : Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments :No specific treatment. Most important symptoms/effects, acute and delayed Inhalation : :Ingestion Skin contact : :Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation No specific data. No specific data. Adverse symptoms may include the following: irritation redness : : : Eye contact :No specific data. Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary In case of accidental skin contact, avoid concurrent exposure to the sun or other sources of UV light which may increase the sensitivity of skin. Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. May cause an allergic skin reaction. Section 5. Fire-fighting measures Specific hazards arising from the chemical In a fire or if heated, a pressure increase will occur and the container may burst. This material is harmful to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : None known. Suitable extinguishing media : Unsuitable extinguishing media : United States Page: 3/12 6-904XI SPEEDHIDE 100% ACRYLIC LATEX EXTERIOR SEMI-GLOSS-ULTRA DEEP BASE Product name 6.01Product code Date of issue Version0040829725 June 2018 Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Hazardous thermal decomposition products Decomposition products may include the following materials: carbon oxides Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters : : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". United States Page: 4/12 6-904XI SPEEDHIDE 100% ACRYLIC LATEX EXTERIOR SEMI-GLOSS-ULTRA DEEP BASE Product name 6.01Product code Date of issue Version0040829725 June 2018 Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Do not store below the following temperature: 5°C (41°F). Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Special precautions :If this material is part of a multiple component system, read the Safety Data Sheet(s) for the other component or components before blending as the resulting mixture may have the hazards of all of its parts. octhilinone (ISO)None. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits Recommended monitoring procedures :If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required. Key to abbreviations A Acceptable Maximum Peak= ACGIH =American Conference of Governmental Industrial Hygienists. C =Ceiling Limit Potential skin absorptionS SR =Respiratory sensitization =Skin sensitizationSS TD =Total dust Consult local authorities for acceptable exposure limits. =Threshold Limit ValueTLV TWA =Time Weighted Average Fume=F IPEL =Internal Permissible Exposure Limit =Occupational Safety and Health Administration.OSHA R =Respirable OSHA 29 CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z STEL = = Short term Exposure limit values United States Page: 5/12 6-904XI SPEEDHIDE 100% ACRYLIC LATEX EXTERIOR SEMI-GLOSS-ULTRA DEEP BASE Product name 6.01Product code Date of issue Version0040829725 June 2018 Section 8. Exposure controls/personal protection Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Environmental exposure controls :Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls :Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection : Safety glasses with side shields. Gloves butyl rubber polyethylene: Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Section 9. Physical and chemical properties Physical state Melting point Liquid. Not available. Alcohol-like.Odor pH VariousColor Auto-ignition temperature Flash point Not available. Closed cup: Not applicable. [Product does not sustain combustion.] 9 Not available.Odor threshold : : : : : : : : Appearance Boiling point :100°C (212°F) United States Page: 6/12 6-904XI SPEEDHIDE 100% ACRYLIC LATEX EXTERIOR SEMI-GLOSS-ULTRA DEEP BASE Product name 6.01Product code Date of issue Version0040829725 June 2018 Section 9. Physical and chemical properties Vapor pressure Relative density Vapor density Solubility 1.03 Not available. 3.3 kPa (25 mm Hg) [room temperature] Soluble in the following materials: cold water. Evaporation rate 0.05 (butyl acetate = 1) Not available. Viscosity Kinematic (40°C (104°F)): >0.21 cm2/s (>21 cSt) Partition coefficient: n- octanol/water : : : : : : : Flammability (solid, gas):Not available. Lower and upper explosive (flammable) limits :Not available. Decomposition temperature :Not available. % Solid. (w/w):30.278 Density ( lbs / gal ):8.6 Volatility :72% (v/v), 69.722% (w/w) Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid The product is stable.Chemical stability : : : Incompatible materials : Possibility of hazardous reactions :Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity :No specific test data related to reactivity available for this product or its ingredients. When exposed to high temperatures may produce hazardous decomposition products. Keep away from the following materials to prevent strong exothermic reactions: oxidizing agents, strong alkalis, strong acids. Decomposition products may include the following materials: carbon monoxide, carbon dioxide, smoke, oxides of nitrogen. Refer to protective measures listed in sections 7 and 8. Section 11. Toxicological information Acute toxicity octhilinone (ISO)LD50 Dermal Rabbit 0.69 g/kg - LD50 Oral Rat 0.55 g/kg - Product/ingredient name Result Species Dose Exposure Conclusion/Summary : Information on toxicological effects There are no data available on the mixture itself. United States Page: 7/12 6-904XI SPEEDHIDE 100% ACRYLIC LATEX EXTERIOR SEMI-GLOSS-ULTRA DEEP BASE Product name 6.01Product code Date of issue Version0040829725 June 2018 Section 11. Toxicological information Carcinogenicity Conclusion/Summary : Mutagenicity Conclusion/Summary : Teratogenicity Conclusion/Summary : Reproductive toxicity Conclusion/Summary : Irritation/Corrosion Conclusion/Summary Skin : Eyes : Respiratory : Sensitization octhilinone (ISO)skin Mouse Sensitizing Product/ingredient name Route of exposure Species Result Conclusion/Summary Skin : Respiratory : Specific target organ toxicity (single exposure) There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. Information on the likely routes of exposure Delayed and immediate effects and also chronic effects from short and long term exposure Specific target organ toxicity (repeated exposure) Not available. Not available. Aspiration hazard Not available. Potential acute health effects Inhalation :No known significant effects or critical hazards. No known significant effects or critical hazards.:Ingestion Skin contact :May cause an allergic skin reaction. No known significant effects or critical hazards.:Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation No specific data. No specific data. Adverse symptoms may include the following: irritation redness : : : Eye contact :No specific data. United States Page: 8/12 6-904XI SPEEDHIDE 100% ACRYLIC LATEX EXTERIOR SEMI-GLOSS-ULTRA DEEP BASE Product name 6.01Product code Date of issue Version0040829725 June 2018 Section 11. Toxicological information Conclusion/Summary : General : Carcinogenicity : Mutagenicity : Teratogenicity : Developmental effects : Fertility effects : Potential chronic health effects Potential immediate effects : Short term exposure Potential delayed effects : Potential immediate effects : Long term exposure Potential delayed effects : No known significant effects or critical hazards. There are no data available on the mixture itself. Acrylate components of the mixture have irritating properties. Prolonged or repeated contact with skin or mucous membrane may result in irritation symptoms, such as redness, blistering, dermatitis etc. May cause allergic skin reactions with repeated exposure. The inhalation of airborne droplets or aerosols may cause irritation of the respiratory tract. Ingestion may cause nausea, weakness and central nervous system effects. If splashed in the eyes, the liquid may cause irritation and reversible damage. This takes into account, where known, delayed and immediate effects and also chronic effects of components from short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. There are no data available on the mixture itself. Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Product/ingredient name octhilinone (ISO)2.45 -low Toxicity Not available. Persistence and degradability Soil/water partition coefficient (KOC) :Not available. Mobility in soil Not available. United States Page: 9/12 6-904XI SPEEDHIDE 100% ACRYLIC LATEX EXTERIOR SEMI-GLOSS-ULTRA DEEP BASE Product name 6.01Product code Date of issue Version0040829725 June 2018 Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Disposal should be in accordance with applicable regional, national and local laws and regulations. Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 6. Accidental release measures 14. Transport information - - - - - - - Not regulated. - - Not regulated.Not regulated. DOT IMDG IATA UN number UN proper shipping name Transport hazard class (es) Packing group Environmental hazards No.No.No. Marine pollutant substances Not applicable.Not applicable.Not applicable. Special precautions for user Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Additional information None identified. None identified. DOT IMDG : : IATA :None identified. United States Page: 10/12 6-904XI SPEEDHIDE 100% ACRYLIC LATEX EXTERIOR SEMI-GLOSS-ULTRA DEEP BASE Product name 6.01Product code Date of issue Version0040829725 June 2018 Section 15. Regulatory information SARA 302/304 SARA 304 RQ :Not applicable. Composition/information on ingredients All components are listed or exempted.United States inventory (TSCA 8b): United States United States - TSCA 5(e) - Substances consent order: United States - TSCA 5(a)2 - Final significant new use rules: United States - TSCA 5(a)2 - Proposed significant new use rules: Additional environmental information is contained on the Environmental Data Sheet for this product, which can be obtained from your PPG representative. No products were found. partially fluorinated alcohol, reaction products Listed 2-(nonylphenoxy)ethanol Listed partially fluorinated alcohol, reaction products Listed SARA 311/312 Classification :SKIN SENSITIZATION - Category 1 octhilinone (ISO)<1.0 ACUTE TOXICITY (oral) - Category 4 ACUTE TOXICITY (dermal) - Category 3 ACUTE TOXICITY (inhalation) - Category 2 SKIN CORROSION - Category 1 SERIOUS EYE DAMAGE - Category 1 SKIN SENSITIZATION - Category 1A Name %Classification Composition/information on ingredients Section 16. Other information Hazardous Material Information System (U.S.A.) 0 00 National Fire Protection Association (U.S.A.) Health InstabilityFlammability Health Flammability Physical hazards Date of previous issue 6/8/2018: Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on MSDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual. Organization that prepared the MSDS :EHS ::: :::2 2 0 ( * ) - Chronic effects United States Page: 11/12 6-904XI SPEEDHIDE 100% ACRYLIC LATEX EXTERIOR SEMI-GLOSS-ULTRA DEEP BASE Product name 6.01Product code Date of issue Version0040829725 June 2018 Section 16. Other information Key to abbreviations :ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations Disclaimer The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products. Indicates information that has changed from previously issued version. United States Page: 12/12 SAFETY DATA SHEET Based upon Regulation (EC) No 1907/2006, as amended by Regulation (EU) No 2015/830 SOUDAFOAM WINDOW & DOOR GUN GRADE SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : SOUDAFOAM WINDOW & DOOR GUN GRADE Registration number REACH : Not applicable (mixture) Product type REACH : Mixture 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.2.1 Relevant identified uses polyurethane 1.2.2 Uses advised against No uses advised against known 1.3. Details of the supplier of the safety data sheet Supplier of the safety data sheet SOUDAL N.V. Everdongenlaan 18-20 B-2300 Turnhout ☎ +32 14 42 42 31 +32 14 42 65 14 msds@soudal.com Manufacturer of the product SOUDAL N.V. Everdongenlaan 18-20 B-2300 Turnhout ☎ +32 14 42 42 31 +32 14 42 65 14 msds@soudal.com 1.4. Emergency telephone number 24h/24h (Telephone advice: English, French, German, Dutch): +32 14 58 45 45 (BIG) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classified as dangerous according to the criteria of Regulation (EC) No 1272/2008 Class Category Hazard statements Aerosol category 1 H222: Extremely flammable aerosol. Aerosol category 1 H229: Pressurised container: May burst if heated. Carc. category 2 H351: Suspected of causing cancer. Lact. - H362: May cause harm to breast-fed children. Acute Tox. category 4 H332: Harmful if inhaled. STOT RE category 2 H373: May cause damage to organs through prolonged or repeated exposure if inhaled. Eye Irrit. category 2 H319: Causes serious eye irritation. STOT SE category 3 H335: May cause respiratory irritation. Skin Irrit. category 2 H315: Causes skin irritation. Resp. Sens. category 1 H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. Skin Sens. category 1 H317: May cause an allergic skin reaction. Aquatic Chronic category 4 H413: May cause long lasting harmful effects to aquatic life. 2.2. Label elements Contains: polymethylene polyphenyl isocyanate; alkanes, C14-17, chloro. Created by: Brandweerinformatiecentrum voor gevaarlijke stoffen vzw (BIG) Technische Schoolstraat 43 A, B-2440 Geel http://www.big.be ' BIG vzw Publication date: 2002-03-23 134-15960-503-en Date of revision: 2016-08-08 Reason for revision: 15.1 Revision number: 0501 Product number: 51803 1 / 17 SOUDAFOAM WINDOW & DOOR GUN GRADE Signal word Danger H-statements H222 Extremely flammable aerosol. H229 Pressurised container: May burst if heated. H351 Suspected of causing cancer. H362 May cause harm to breast-fed children. H332 Harmful if inhaled. H373 May cause damage to organs through prolonged or repeated exposure if inhaled. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H315 Causes skin irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H413 May cause long lasting harmful effects to aquatic life. P-statements P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P211 Do not spray on an open flame or other ignition source. P251 Do not pierce or burn, even after use. P308 + P313 IF exposed or concerned: Get medical advice/attention. P405 Store locked up. P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50 C/ 122F. P501 Dispose of contents/container in accordance with local/regional/national/international regulation. Supplemental information - Persons already sensitised to diisocyanates may develop allergic reactions when using this product. - Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product. - This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used. 2.3. Other hazards Gas/vapour spreads at floor level: ignition hazard SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name REACH Registration No CAS No EC No Conc. (C) Classification according to CLP Note Remark propane 01-2119486944-21 74-98-6 200-827-9 1%<C<10% Flam. Gas 1; H220 Press. Gas - Liquefied gas; H280 (1)(2)(10) Propellant dimethyl ether 01-2119472128-37 115-10-6 204-065-8 1%<C<15% Flam. Gas 1; H220 Press. Gas - Liquefied gas; H280 (1)(2)(10) Propellant polymethylene polyphenyl isocyanate 9016-87-9 10%<C<40% Carc. 2; H351 Acute Tox. 4; H332 STOT RE 2; H373 Eye Irrit. 2; H319 STOT SE 3; H335 Skin Irrit. 2; H315 Resp. Sens. 1; H334 Skin Sens. 1; H317 (1)(2)(8)(10) Polymer isobutane 01-2119485395-27 75-28-5 200-857-2 1%<C<10% Flam. Gas 1; H220 Press. Gas - Liquefied gas; H280 (1)(2)(10) Propellant alkanes, C14-17, chloro 01-2119519269-33 85535-85-9 287-477-0 1%<C<20% Lact. ; H362 Aquatic Acute 1; H400 Aquatic Chronic 1; H410 (1)(2)(8)(10) UVCB Reason for revision: 15.1 Publication date: 2002-03-23 Date of revision: 2016-08-08 Revision number: 0501 Product number: 51803 2 / 17 SOUDAFOAM WINDOW & DOOR GUN GRADE reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2- chloropropyl ester and phosphoric acid, 2-chloro-1- methylethyl bis(2-chloropropyl) ester 01-2119486772-26 1%C<5% Acute Tox. 4; H302 (1)(10) Reaction product (1,3-butadiene, conc<0.1%) (1) For H-statements in full: see heading 16 (2) Substance with a Community workplace exposure limit (8) Specific concentration limits, see heading 16 (10) Subject to restrictions of Annex XVII of Regulation (EC) No. 1907/2006 SECTION 4: First aid measures 4.1. Description of first aid measures General: GENERAL. Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious with laboured breathing: half-seated. Victim in shock: on his back with legs slightly raised. Vomiting: prevent asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no warming up). Keep watching the victim. Give psychological aid. Keep the victim calm, avoid physical strain. Depending on the victim’s condition: doctor/hospital. After inhalation: Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service. After skin contact: Wash immediately with lots of water. Take victim to a doctor if irritation persists. After eye contact: Rinse immediately with plenty of water. Do not apply neutralizing agents. Take victim to an ophthalmologist if irritation persists. After ingestion: Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Do not induce vomiting. Consult a doctor/medical service if you feel unwell. 4.2. Most important symptoms and effects, both acute and delayed 4.2.1 Acute symptoms After inhalation: Dry/sore throat. Coughing. Irritation of the respiratory tract. Irritation of the nasal mucous membranes. Runny nose. FOLLOWING SYMPTOMS MAY APPEAR LATER: Possible inflammation of the respiratory tract. Risk of lung oedema. Respiratory difficulties. After skin contact: Tingling/irritation of the skin. After eye contact: Irritation of the eye tissue. Lacrimation. After ingestion: Not applicable. 4.2.2 Delayed symptoms No effects known. 4.3. Indication of any immediate medical attention and special treatment needed If applicable and available it will be listed below. SECTION 5: Firefighting measures 5.1. Extinguishing media 5.1.1 Suitable extinguishing media: Quantities of water. Polyvalent foam. BC powder. Carbon dioxide. 5.1.2 Unsuitable extinguishing media: No unsuitable extinguishing media known. 5.2. Special hazards arising from the substance or mixture On burning: release of toxic and corrosive gases/vapours (nitrous vapours, hydrogen chloride, carbon monoxide - carbon dioxide). Pressurised container: May burst if heated. May polymerize on exposure to temperature rise. On heating: release of toxic/combustible gases/vapours (hydrogen cyanide). 5.3. Advice for firefighters 5.3.1 Instructions: If exposed to fire cool the closed containers by spraying with water. Physical explosion risk: extinguish/cool from behind cover. Do not move the load if exposed to heat. After cooling: persistant risk of physical explosion. Dilute toxic gases with water spray. Take account of toxic/corrosive precipitation water. 5.3.2 Special protective equipment for fire-fighters: Gloves. Protective goggles. Head/neck protection. Protective clothing. Heat/fire exposure: compressed air/oxygen apparatus. Reason for revision: 15.1 Publication date: 2002-03-23 Date of revision: 2016-08-08 Revision number: 0501 Product number: 51803 3 / 17 SOUDAFOAM WINDOW & DOOR GUN GRADE SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Stop engines and no smoking. No naked flames or sparks. Spark- and explosionproof appliances and lighting equipment. 6.1.1 Protective equipment for non-emergency personnel See heading 8.2 6.1.2 Protective equipment for emergency responders Gloves. Protective goggles. Head/neck protection. Protective clothing. Suitable protective clothing See heading 8.2 6.2. Environmental precautions Dam up the solid spill. Use appropriate containment to avoid environmental contamination. 6.3. Methods and material for containment and cleaning up Allow product to solidify and remove it by mechanical means. Carefully collect the spill/leftovers. Clean (treat) contaminated surfaces with acetone. Take collected spill to manufacturer/competent authority. Wash clothing and equipment after handling. 6.4. Reference to other sections See heading 13. SECTION 7: Handling and storage The information in this section is a general description. If applicable and available, exposure scenarios are attached in annex. Always use the relevant exposure scenarios that correspond to your identified use. 7.1. Precautions for safe handling Use spark-/explosionproof appliances and lighting system. Keep away from naked flames/heat. Keep away from ignition sources/sparks. Observe very strict hygiene - avoid contact. Remove contaminated clothing immediately. 7.2. Conditions for safe storage, including any incompatibilities 7.2.1 Safe storage requirements: Storage temperature: < 50 C. Store in a cool area. Keep out of direct sunlight. Store in a dry area. Ventilation at floor level. Fireproof storeroom. Unauthorized persons are not admitted. Meet the legal requirements. Max. storage time: 1 year(s). 7.2.2 Keep away from: Heat sources, ignition sources, (strong) acids, (strong) bases. 7.2.3 Suitable packaging material: Aerosol. 7.2.4 Non suitable packaging material: No data available 7.3. Specific end use(s) If applicable and available, exposure scenarios are attached in annex. See information supplied by the manufacturer. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.1.1 Occupational exposure a) Occupational exposure limit values If limit values are applicable and available these will be listed below. EU Dimethylether Time-weighted average exposure limit 8 h (Indicative occupational exposure limit value) 1000 ppm Time-weighted average exposure limit 8 h (Indicative occupational exposure limit value) 1920 mg/m‡ Belgium Hydrocarbures aliphatiques sous forme gazeuse : (Alcanes C1- C4) Time-weighted average exposure limit 8 h 1000 ppm Oxyde de dimØthyle Time-weighted average exposure limit 8 h 1000 ppm Time-weighted average exposure limit 8 h 1920 mg/m‡ The Netherlands Dimethylether Time-weighted average exposure limit 8 h (Public occupational exposure limit value) 496 ppm Time-weighted average exposure limit 8 h (Public occupational exposure limit value) 950 mg/m‡ Reason for revision: 15.1 Publication date: 2002-03-23 Date of revision: 2016-08-08 Revision number: 0501 Product number: 51803 4 / 17 SOUDAFOAM WINDOW & DOOR GUN GRADE Dimethylether Short time value (Public occupational exposure limit value) 783 ppm Short time value (Public occupational exposure limit value) 1500 mg/m‡ France Oxyde de dimØthyle Time-weighted average exposure limit 8 h (VRI: Valeur rØglementaire indicative) 1000 ppm Time-weighted average exposure limit 8 h (VRI: Valeur rØglementaire indicative) 1920 mg/m‡ Germany Chloralkane, C14-17 (Chlorierte Paraffine C14-17 ) Time-weighted average exposure limit 8 h (TRGS 900) 0.3 ppm Time-weighted average exposure limit 8 h (TRGS 900) 6 mg/m‡ Dimethylether Time-weighted average exposure limit 8 h (TRGS 900) 1000 ppm Time-weighted average exposure limit 8 h (TRGS 900) 1900 mg/m‡ Isobutan Time-weighted average exposure limit 8 h (TRGS 900) 1000 ppm Time-weighted average exposure limit 8 h (TRGS 900) 2400 mg/m‡ pMDI (als MDI berechnet) Time-weighted average exposure limit 8 h (TRGS 900) 0.05 mg/m‡ Propan Time-weighted average exposure limit 8 h (TRGS 900) 1000 ppm Time-weighted average exposure limit 8 h (TRGS 900) 1800 mg/m‡ UK Dimethyl ether Time-weighted average exposure limit 8 h (Workplace exposure limit (EH40/2005)) 400 ppm Time-weighted average exposure limit 8 h (Workplace exposure limit (EH40/2005)) 766 mg/m‡ Short time value (Workplace exposure limit (EH40/2005)) 500 ppm Short time value (Workplace exposure limit (EH40/2005)) 958 mg/m‡ Isocyanates, all (as -NCO) Except methyl isocyanate Time-weighted average exposure limit 8 h (Workplace exposure limit (EH40/2005)) 0.02 mg/m‡ Short time value (Workplace exposure limit (EH40/2005)) 0.07 mg/m‡ USA (TLV-ACGIH) Butane, all isomers Short time value (TLV - Adopted Value) 1000 ppm b) National biological limit values If limit values are applicable and available these will be listed below. 8.1.2 Sampling methods If applicable and available it will be listed below. Isocyanates NIOSH 5521 Isocyanates NIOSH 5522 8.1.3 Applicable limit values when using the substance or mixture as intended If limit values are applicable and available these will be listed below. 8.1.4 DNEL/PNEC values DNEL/DMEL - Workers alkanes, C14-17, chloro Effect level (DNEL/DMEL) Type Value Remark DNEL Long-term systemic effects inhalation 6.7 mg/m‡ Long-term systemic effects dermal 47.9 mg/kg bw/day reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl Effect level (DNEL/DMEL) Type Value Remark DNEL Long-term systemic effects inhalation 5.82 mg/m‡ Acute systemic effects inhalation 22.4 mg/m‡ Long-term systemic effects dermal 2.08 mg/kg bw/day Acute systemic effects dermal 8 mg/kg bw/day DNEL/DMEL - General population alkanes, C14-17, chloro Effect level (DNEL/DMEL) Type Value Remark DNEL Long-term systemic effects inhalation 2 mg/m‡ Long-term systemic effects dermal 28.75 mg/kg bw/day Long-term systemic effects oral 0.58 mg/kg bw/day Reason for revision: 15.1 Publication date: 2002-03-23 Date of revision: 2016-08-08 Revision number: 0501 Product number: 51803 5 / 17 SOUDAFOAM WINDOW & DOOR GUN GRADE reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl dh hi id2hl 1 hl hlbi(2 hl l) Effect level (DNEL/DMEL) Type Value Remark DNEL Long-term systemic effects inhalation 1.46 mg/m‡ Acute systemic effects inhalation 11.2 mg/m‡ Long-term systemic effects dermal 1.04 mg/kg bw/day Acute systemic effects dermal 4 mg/kg bw/day Long-term systemic effects oral 0.52 mg/kg bw/day PNEC alkanes, C14-17, chloro Compartments Value Remark Fresh water 1 g/l Marine water 0.2 g/l STP 80 mg/l Fresh water sediment 13 mg/kg sediment dw Marine water sediment 2.6 mg/kg sediment dw Soil 11.9 mg/kg soil dw Oral 10 mg/kg food reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl Compartments Value Remark Fresh water 0.64 mg/l Marine water 0.064 mg/l Aqua (intermittent releases) 0.51 mg/l STP 7.84 mg/l Fresh water sediment 13.4 mg/kg sediment dw Marine water sediment 1.34 mg/kg sediment dw Soil 1.7 mg/kg soil dw Oral 11.6 mg/kg food 8.1.5 Control banding If applicable and available it will be listed below. 8.2. Exposure controls The information in this section is a general description. If applicable and available, exposure scenarios are attached in annex. Always use the relevant exposure scenarios that correspond to your identified use. 8.2.1 Appropriate engineering controls Use spark-/explosionproof appliances and lighting system. Keep away from naked flames/heat. Keep away from ignition sources/sparks. Measure the concentration in the air regularly. 8.2.2 Individual protection measures, such as personal protective equipment Observe very strict hygiene - avoid contact. Do not eat, drink or smoke during work. a) Respiratory protection: Wear gas mask with filter type A if conc. in air > exposure limit. b) Hand protection: Gloves. Materials Breakthrough time Thickness LDPE (Low Density Poly Ethylene) 10 minutes 0.025 mm c) Eye protection: Protective goggles. d) Skin protection: Head/neck protection. Protective clothing. 8.2.3 Environmental exposure controls: See headings 6.2, 6.3 and 13 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical form Aerosol Odour Characteristic odour Odour threshold No data available Colour Variable in colour, depending on the composition Particle size Not applicable Explosion limits No data available Flammability Extremely flammable aerosol. Log Kow Not applicable (mixture) Reason for revision: 15.1 Publication date: 2002-03-23 Date of revision: 2016-08-08 Revision number: 0501 Product number: 51803 6 / 17 SOUDAFOAM WINDOW & DOOR GUN GRADE Dynamic viscosity No data available Kinematic viscosity No data available Melting point No data available Boiling point No data available Flash point Not applicable Evaporation rate No data available Relative vapour density > 1 Vapour pressure No data available Solubility organic solvents ; soluble water ; insoluble Relative density 0.95 ; 20 C Decomposition temperature No data available Auto-ignition temperature No data available Explosive properties No chemical group associated with explosive properties Oxidising properties No chemical group associated with oxidising properties pH No data available 9.2. Other information Absolute density 950 kg/m‡ ; 20 C SECTION 10: Stability and reactivity 10.1. Reactivity May be ignited by sparks. Gas/vapour spreads at floor level: ignition hazard. No data available. 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions May polymerize with many compounds e.g.: (strong) bases and amines. Reacts violently with (some) acids/bases. 10.4. Conditions to avoid Use spark-/explosionproof appliances and lighting system. Keep away from naked flames/heat. Keep away from ignition sources/sparks. 10.5. Incompatible materials (strong) acids, (strong) bases. 10.6. Hazardous decomposition products On heating: release of toxic/combustible gases/vapours (hydrogen cyanide). On burning: release of toxic and corrosive gases/vapours (nitrous vapours, hydrogen chloride, carbon monoxide - carbon dioxide). SECTION 11: Toxicological information 11.1. Information on toxicological effects 11.1.1 Test results Acute toxicity SOUDAFOAM WINDOW & DOOR GUN GRADE No (test)data on the mixture available polymethylene polyphenyl isocyanate Route of exposure Parameter Method Value Exposure time Species Value determination Remark Oral LD50 > 10000 mg/kg Rat Literature study Dermal LD50 > 5000 mg/kg Rabbit Literature study Inhalation (vapours) LD50 10 mg/l - 20 mg/l 4 h Rat Literature study Inhalation category 4 Literature study alkanes, C14-17, chloro Route of exposure Parameter Method Value Exposure time Species Value determination Remark Oral LD50 > 4000 mg/kg bw Rat (male/female) Experimental value Dermal LD50 > 13500 mg/kg bw 24 h Rabbit Read-across Inhalation (vapours) LC50 > 48170 mg/m‡ 1 h Rat Read-across Reason for revision: 15.1 Publication date: 2002-03-23 Date of revision: 2016-08-08 Revision number: 0501 Product number: 51803 7 / 17 SOUDAFOAM WINDOW & DOOR GUN GRADE reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl ester and phosphoric acid, 2-chloro-1-methylethyl bis(2-chloropropyl) ester Route of exposure Parameter Method Value Exposure time Species Value determination Remark Oral LD50 EU Method B.1 tris 632 mg/kg bw Rat (female) Experimental value Dermal LD50 OECD 402 > 2000 mg/kg bw 24 h Rat (male/female) Experimental value Inhalation (aerosol) LC50 OECD 403 > 7 mg/l 4 h Rat (male/female) Experimental value Judgement is based on the relevant ingredients Conclusion Harmful if inhaled. Not classified as acute toxic in contact with skin Not classified as acute toxic if swallowed Corrosion/irritation SOUDAFOAM WINDOW & DOOR GUN GRADE No (test)data on the mixture available polymethylene polyphenyl isocyanate Route of exposure Result Method Exposure time Time point Species Value determination Remark Eye Irritating; category 2 Literature study Skin Irritating; category 2 Literature study Inhalation Irritating; STOT SE cat.3 Literature study alkanes, C14-17, chloro Route of exposure Result Method Exposure time Time point Species Value determination Remark Eye Slightly irritating Rabbit Expert judgement Skin Slightly irritating OECD 404 4 h 24; 72 hours Rabbit Expert judgement reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl ester and phosphoric acid, 2-chloro-1-methylethyl bis(2-chloropropyl) ester Route of exposure Result Method Exposure time Time point Species Value determination Remark Eye Not irritating OECD 405 24 h 7 days Rabbit Experimental value Skin Not irritating OECD 404 4 h 7 days Rabbit Experimental value Classification is based on the relevant ingredients Conclusion Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Respiratory or skin sensitisation SOUDAFOAM WINDOW & DOOR GUN GRADE No (test)data on the mixture available polymethylene polyphenyl isocyanate Route of exposure Result Method Exposure time Observation time point Species Value determination Remark Skin Sensitizing; category 1 Literature study Inhalation Sensitizing; category 1 Literature study alkanes, C14-17, chloro Route of exposure Result Method Exposure time Observation time point Species Value determination Remark Skin Not sensitizing Guinea pig maximisation test 48 hours Guinea pig Experimental value reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl ester and phosphoric acid, 2-chloro-1-methylethyl bis(2-chloropropyl) ester Route of exposure Result Method Exposure time Observation time point Species Value determination Remark Skin Not sensitizing OECD 429 Mouse (female) Experimental value Classification is based on the relevant ingredients Conclusion Reason for revision: 15.1 Publication date: 2002-03-23 Date of revision: 2016-08-08 Revision number: 0501 Product number: 51803 8 / 17 SOUDAFOAM WINDOW & DOOR GUN GRADE May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Specific target organ toxicity SOUDAFOAM WINDOW & DOOR GUN GRADE No (test)data on the mixture available polymethylene polyphenyl isocyanate Route of exposure Parameter Method Value Organ Effect Exposure time Species Value determination Inhalation STOT RE cat.2 Literature study alkanes, C14-17, chloro Route of exposure Parameter Method Value Organ Effect Exposure time Species Value determination Oral (diet) NOAEL Equivalent to OECD 408 300 ppm Liver; kidney No adverse systemic effects 13 week(s) Rat (male/female) Experimental value Oral (diet) NOAEL Equivalent to OECD 408 100 mg/kg bw/day Kidney No adverse systemic effects 13 week(s) Rat (male/female) Experimental value Dermal Data waiving Inhalation Data waiving reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl ester and phosphoric acid, 2-chloro-1-methylethyl bis(2-chloropropyl) ester Route of exposure Parameter Method Value Organ Effect Exposure time Species Value determination Oral (diet) NOAEL Subchronic toxicity test 171 mg/kg bw/day No effect 13 weeks (daily) Rat (female) Experimental value Oral (diet) LOAEL Subchronic toxicity test 52 mg/kg bw/day Liver Weight gain 13 weeks (daily) Rat (male) Experimental value Inhalation (vapours) Dose level 0.586 mg/l air No effect Mouse (male) Experimental value Classification is based on the relevant ingredients Conclusion May cause damage to organs through prolonged or repeated exposure if inhaled. Not classified as sub-chronically toxic in contact with skin Not classified as sub-chronically toxic if swallowed Mutagenicity (in vitro) SOUDAFOAM WINDOW & DOOR GUN GRADE No (test)data on the mixture available alkanes, C14-17, chloro Result Method Test substrate Effect Value determination Negative with metabolic activation, negative without metabolic activation OECD 471 Bacteria (S.typhimurium) No effect Experimental value reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl ester and phosphoric acid, 2-chloro-1-methylethyl bis(2-chloropropyl) ester Result Method Test substrate Effect Value determination Negative with metabolic activation, negative without metabolic activation OECD 482 Rat liver cells Experimental value Negative without metabolic activation, positive with metabolic activation OECD 476 Mouse (lymphoma L5178Y cells) Experimental value Mutagenicity (in vivo) SOUDAFOAM WINDOW & DOOR GUN GRADE No (test)data on the mixture available alkanes, C14-17, chloro Result Method Exposure time Test substrate Organ Value determination Negative Equivalent to OECD 475 5 day(s) Rat (male) Bone marrow Experimental value Negative Equivalent to OECD 474 Mouse (male/female) Bone marrow Experimental value Reason for revision: 15.1 Publication date: 2002-03-23 Date of revision: 2016-08-08 Revision number: 0501 Product number: 51803 9 / 17 SOUDAFOAM WINDOW & DOOR GUN GRADE reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl ester and phosphoric acid, 2-chloro-1-methylethyl bis(2-chloropropyl) ester Result Method Exposure time Test substrate Organ Value determination Negative OECD 474 Mouse (male/female) Bone marrow Experimental value Classification is based on the relevant ingredients Conclusion Not classified for mutagenic or genotoxic toxicity Carcinogenicity SOUDAFOAM WINDOW & DOOR GUN GRADE No (test)data on the mixture available polymethylene polyphenyl isocyanate Route of exposure Parameter Method Value Exposure time Species Effect Organ Value determination Unknown category 2 Literature study alkanes, C14-17, chloro Route of exposure Parameter Method Value Exposure time Species Effect Organ Value determination Oral LOAEL Equivalent to OECD 451 312 mg/kg bw/day 104 weeks (5 days/week) Rat (male/female) Carcinogenicity Read-across Oral LOAEL Equivalent to OECD 451 125 mg/kg bw/day 103 weeks (5 days/week) Mouse (male/female) Carcinogenicity Read-across reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl ester and phosphoric acid, 2-chloro-1-methylethyl bis(2-chloropropyl) ester Route of exposure Parameter Method Value Exposure time Species Effect Organ Value determination Inhalation Data waiving Dermal Data waiving Oral Data waiving Classification is based on the relevant ingredients Conclusion Suspected of causing cancer. Reproductive toxicity SOUDAFOAM WINDOW & DOOR GUN GRADE No (test)data on the mixture available alkanes, C14-17, chloro Parameter Method Value Exposure time Species Effect Organ Value determination Developmental toxicity NOAEL Equivalent to OECD 414 100 mg/kg bw/day 22 day(s) Rabbit No effect Experimental value Maternal toxicity NOAEL Equivalent to OECD 414 100 mg/kg bw/day 22 day(s) Rabbit No effect Experimental value Effects on fertility NOAEL (P) OECD 421 100 mg/kg bw/day 9 week(s) Rat (male) No effect Male reproductive organ Experimental value NOAEL (P) OECD 421 100 mg/kg bw/day 11 week(s) - 12 week(s) Rat (female) No effect Female reproductive organ Experimental value Effects on lactation May cause harm to breast- fed children. Experimental value reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl ester and phosphoric acid, 2-chloro-1-methylethyl bis(2-chloropropyl) ester Parameter Method Value Exposure time Species Effect Organ Value determination Developmental toxicity LOAEL OECD 416 99 mg/kg bw/day Rat (female) Embryotoxicity Experimental value Effects on fertility LOAEL OECD 416 99 mg/kg bw/day Rat (male/female) Weight changes Female reproductive organ Experimental value Classification is based on the relevant ingredients Conclusion May cause harm to breast-fed children. Not classified for reprotoxic or developmental toxicity Reason for revision: 15.1 Publication date: 2002-03-23 Date of revision: 2016-08-08 Revision number: 0501 Product number: 51803 10 / 17 SOUDAFOAM WINDOW & DOOR GUN GRADE Toxicity other effects SOUDAFOAM WINDOW & DOOR GUN GRADE No (test)data on the mixture available alkanes, C14-17, chloro Parameter Method Value Organ Effect Exposure time Species Value determination Other Skin Skin dryness or cracking Rat Experimental value Chronic effects from short and long-term exposure SOUDAFOAM WINDOW & DOOR GUN GRADE ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Feeling of weakness. Itching. Skin rash/inflammation. May stain the skin. Dry skin. Coughing. Possible inflammation of the respiratory tract. Respiratory difficulties. SECTION 12: Ecological information 12.1. Toxicity SOUDAFOAM WINDOW & DOOR GUN GRADE No (test)data on the mixture available polymethylene polyphenyl isocyanate Parameter Method Value Duration Species Test design Fresh/salt water Value determination Acute toxicity other aquatic organisms LC50 > 1000 mg/l 96 h Literature study Toxicity aquatic micro- organisms EC50 OECD 209 > 100 mg/l Activated sludge Literature study alkanes, C14-17, chloro Parameter Method Value Duration Species Test design Fresh/salt water Value determination Acute toxicity fishes LC50 OECD 203 > 10000 mg/l 96 h Alburnus alburnus Static system Salt water Experimental value Acute toxicity invertebrates EC50 OECD 203 0.0077 mg/l 48 h Daphnia magna Static system Fresh water Experimental value Toxicity algae and other aquatic plants EC50 OECD 201 > 3.2 mg/l 72 h Pseudokirchneriel la subcapitata Static system Fresh water Experimental value; Growth rate Long-term toxicity fish NOEC OECD 204 > 125 g/l 14 day(s) Alburnus alburnus Semi-static system Salt water Experimental value Long-term toxicity invertebrates NOEC OECD 202 0.01 mg/l 21 day(s) Daphnia magna Static system Fresh water Experimental value reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl ester and phosphoric acid, 2-chloro-1-methylethyl bis(2-chloropropyl) ester Parameter Method Value Duration Species Test design Fresh/salt water Value determination Acute toxicity fishes LC50 Other 56.2 mg/l 96 h Brachydanio rerioStatic system Fresh water Experimental value; GLP Acute toxicity invertebrates LC50 131 mg/l 48 h Daphnia magna Static system Fresh water Locomotor effect Toxicity algae and other aquatic plants ErC50 OECD 201 82 mg/l 72 h Pseudokirchneriel la subcapitata Static system Fresh water Experimental value; GLP Long-term toxicity invertebrates NOEC OECD 202 32 mg/l 21 day(s) Daphnia magna Semi-static system Fresh water Experimental value; GLP Toxicity aquatic micro- organisms EC50 ISO 8192 784 mg/l 3 h Activated sludge Static system Fresh water Experimental value; GLP Classification of the mixture is based on test data on the mixture as a whole Conclusion May cause long lasting harmful effects to aquatic life. 12.2. Persistence and degradability polymethylene polyphenyl isocyanate Biodegradation water Method Value Duration Value determination OECD 302C: Inherent Biodegradability: Modified MITI Test (II) < 60 % Experimental value Reason for revision: 15.1 Publication date: 2002-03-23 Date of revision: 2016-08-08 Revision number: 0501 Product number: 51803 11 / 17 SOUDAFOAM WINDOW & DOOR GUN GRADE alkanes, C14-17, chloro Biodegradation water Method Value Duration Value determination OECD 301D: Closed Bottle Test 63 % 60 day(s) Experimental value Biodegradation soil Method Value Duration Value determination 51 % - 57 % 36 h Experimental value reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl ester and phosphoric acid, 2-chloro-1-methylethyl bis(2-chloropropyl) ester Biodegradation water Method Value Duration Value determination OECD 301E: Modified OECD Screening Test 14 %; GLP 28 day(s) Experimental value Conclusion Contains non readily biodegradable component(s) 12.3. Bioaccumulative potential SOUDAFOAM WINDOW & DOOR GUN GRADE Log Kow Method Remark Value Temperature Value determination Not applicable (mixture) polymethylene polyphenyl isocyanate BCF fishes Parameter Method Value Duration Species Value determination BCF 1 Pisces Literature study Log Kow Method Remark Value Temperature Value determination No data available alkanes, C14-17, chloro BCF fishes Parameter Method Value Duration Species Value determination BCF OECD 305 6660 35 day(s) Oncorhynchus mykiss Experimental value Log Kow Method Remark Value Temperature Value determination 5.47 - 8.01 Experimental value > 5 reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl ester and phosphoric acid, 2-chloro-1-methylethyl bis(2-chloropropyl) ester BCF fishes Parameter Method Value Duration Species Value determination BCF OECD 305 0.8 - 14 6 week(s) Cyprinus carpio Experimental value Log Kow Method Remark Value Temperature Value determination EU Method A.8 2.68 30 C Experimental value Conclusion Contains bioaccumulative component(s) 12.4. Mobility in soil alkanes, C14-17, chloro (log) Koc Parameter Method Value Value determination log Koc 5 Experimental value Reason for revision: 15.1 Publication date: 2002-03-23 Date of revision: 2016-08-08 Revision number: 0501 Product number: 51803 12 / 17 SOUDAFOAM WINDOW & DOOR GUN GRADE reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl ester and phosphoric acid, 2-chloro-1-methylethyl bis(2-chloropropyl) ester (log) Koc Parameter Method Value Value determination log Koc EU Method C.19 2.76 Experimental value Volatility (Henry's Law constant H) Value Method Temperature Remark Value determination 0.00042 Pa.m‡/mol 25 C Read-across Percent distribution Method Fraction air Fraction biota Fraction sediment Fraction soil Fraction water Value determination Mackay level I 0.01 % 0 % 3.55 % 3.52 % 92.89 % Read-across Conclusion Contains component(s) that adsorb(s) into the soil Contains component(s) with potential for mobility in the soil 12.5. Results of PBT and vPvB assessment Does not contain component(s) that meet(s) the criteria of PBT and/or vPvB as listed in Annex XIII of Regulation (EC) No 1907/2006. 12.6. Other adverse effects SOUDAFOAM WINDOW & DOOR GUN GRADE Fluorinated greenhouse gases (Regulation (EU) No 517/2014) None of the known components is included in the list of fluorinated greenhouse gases (Regulation (EU) No 517/2014) Ozone-depleting potential (ODP) Not classified as dangerous for the ozone layer (Regulation (EC) No 1005/2009) SECTION 13: Disposal considerations The information in this section is a general description. If applicable and available, exposure scenarios are attached in annex. Always use the relevant exposure scenarios that correspond to your identified use. 13.1. Waste treatment methods 13.1.1 Provisions relating to waste Hazardous waste according to Directive 2008/98/EC, as amended by Regulation (EU) No 1357/2014. Waste material code (Directive 2008/98/EC, Decision 2000/0532/EC). 08 05 01* (wastes not otherwise specified in 08: waste isocyanates). 16 05 04* (gases in pressure containers and discarded chemicals: gases in pressure containers (including halons) containing hazardous substances). Depending on branch of industry and production process, also other waste codes may be applicable. 13.1.2 Disposal methods Recycle/reuse. Remove waste in accordance with local and/or national regulations. Hazardous waste shall not be mixed together with other waste. Different types of hazardous waste shall not be mixed together if this may entail a risk of pollution or create problems for the further management of the waste. Hazardous waste shall be managed responsibly. All entities that store, transport or handle hazardous waste shall take the necessary measures to prevent risks of pollution or damage to people or animals. Specific treatment. Do not discharge into drains or the environment. 13.1.3 Packaging/Container Waste material code packaging (Directive 2008/98/EC). 15 01 10* (packaging containing residues of or contaminated by dangerous substances). SECTION 14: Transport information Road (ADR) 14.1. UN number UN number 1950 14.2. UN proper shipping name Proper shipping name Aerosols 14.3. Transport hazard class(es) Hazard identification number Class 2 Classification code 5F 14.4. Packing group Packing group Labels 2.1 14.5. Environmental hazards Environmentally hazardous substance mark no 14.6. Special precautions for user Special provisions 190 Reason for revision: 15.1 Publication date: 2002-03-23 Date of revision: 2016-08-08 Revision number: 0501 Product number: 51803 13 / 17 SOUDAFOAM WINDOW & DOOR GUN GRADE Special provisions 327 Special provisions 344 Special provisions 625 Limited quantities Combination packagings: not more than 1 liter per inner packaging for liquids. A package shall not weigh more than 30 kg. (gross mass) Rail (RID) 14.1. UN number UN number 1950 14.2. UN proper shipping name Proper shipping name Aerosols 14.3. Transport hazard class(es) Hazard identification number 23 Class 2 Classification code 5F 14.4. Packing group Packing group Labels 2.1 14.5. Environmental hazards Environmentally hazardous substance mark no 14.6. Special precautions for user Special provisions 190 Special provisions 327 Special provisions 344 Special provisions 625 Limited quantities Combination packagings: not more than 1 liter per inner packaging for liquids. A package shall not weigh more than 30 kg. (gross mass) Inland waterways (ADN) 14.1. UN number UN number 1950 14.2. UN proper shipping name Proper shipping name Aerosols 14.3. Transport hazard class(es) Class 2 Classification code 5F 14.4. Packing group Packing group Labels 2.1 14.5. Environmental hazards Environmentally hazardous substance mark no 14.6. Special precautions for user Special provisions 190 Special provisions 327 Special provisions 344 Special provisions 625 Limited quantities Combination packagings: not more than 1 liter per inner packaging for liquids. A package shall not weigh more than 30 kg. (gross mass) Sea (IMDG/IMSBC) 14.1. UN number UN number 1950 14.2. UN proper shipping name Proper shipping name Aerosols 14.3. Transport hazard class(es) Class 2.1 14.4. Packing group Packing group Labels 2.1 14.5. Environmental hazards Marine pollutant - Environmentally hazardous substance mark no 14.6. Special precautions for user Reason for revision: 15.1 Publication date: 2002-03-23 Date of revision: 2016-08-08 Revision number: 0501 Product number: 51803 14 / 17 SOUDAFOAM WINDOW & DOOR GUN GRADE Special provisions 63 Special provisions 190 Special provisions 277 Special provisions 327 Special provisions 344 Special provisions 959 Limited quantities Combination packagings: not more than 1 liter per inner packaging for liquids. A package shall not weigh more than 30 kg. (gross mass) 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code Annex II of MARPOL 73/78 Not applicable Air (ICAO-TI/IATA-DGR) 14.1. UN number UN number 1950 14.2. UN proper shipping name Proper shipping name Aerosols, flammable 14.3. Transport hazard class(es) Class 2.1 14.4. Packing group Packing group Labels 2.1 14.5. Environmental hazards Environmentally hazardous substance mark no 14.6. Special precautions for user Special provisions A145 Special provisions A167 Special provisions A802 limited quantities: maximum net quantity per packaging 30 kg G SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture European legislation: VOC content Directive 2010/75/EU VOC content Remark < 24 % < 228 g/l REACH Annex XVII - Restriction Contains component(s) subject to restrictions of Annex XVII of Regulation (EC) No 1907/2006: restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles. Designation of the substance, of the group of substances or of the mixture Conditions of restriction • polymethylene polyphenyl isocyanate • alkanes, C14-17, chloro • reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro- 1-methylethyl) 2-chloropropyl ester and phosphoric acid, 2-chloro-1-methylethyl bis(2-chloropropyl) ester Liquid substances or mixtures which are regarded as dangerous in accordance with Directive 1999/45/EC or are fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: (a) hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8 types A and B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2, 2.14 categories 1 and 2, 2.15 types A to F; (b) hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10; (c) hazard class 4.1; (d) hazard class 5.1. 1. Shall not be used in: ornamental articles intended to produce light or colour effects by means of different phases, for example in ornamental lamps and ashtrays, tricks and jokes, games for one or more participants, or any arti cle intended to be used as such, even with ornamental aspects,2. Articles not complying with paragraph 1 shall not be placed on the market.3. Shall not be placed on the market if they contain a colouring agent, unless required for fiscal reasons, or perfume, or both, if they: can be used as fuel in decorative oil lamps for supply to the general public, and, present an aspiration hazard and are labelled with R65 or H304,4. Decorative oil lamps for supply to the general public shall not be placed on the market unless they conform to the European Standard on Decorative oil lamps (EN 14059) adopted by the European Committee for Standardisation (CEN).5. Without prejudice to the implementation of other Community provisions relating to the classification, packaging and labelling of dangerous substances and mixtures, suppliers shall ensure, before the placing on the market, that the following requirements are met: a) lamp oils, labelled with R65 or H304, intended for supply to the general public are visibly, legibly and indelibly marked as follows: Keep lamps filled with this liquid out of the reach of children; and, by 1 December 2010, Just a sip of lamp oil or even sucking the wick of lamps may lead to life- threatening lung damage; b) grill lighter fluids, labelled with R65 or H304, intended for supply to the general public are legibly and indelibly marked by 1 December 2010 as follows: Just a sip of grill lighter may lead to life threatening lung damage; c) lamp oils and grill lighters, labelled with R65 or H304, intended for supply to the general public are packaged in black opaque containers not exceeding 1 litre by 1 December 2010.6. No later than 1 June 2014, the Commission shall request the European Chemicals Agency to prepare a dossier, in accordance with Article 69 of the present Regulation with a view to ban, Reason for revision: 15.1 Publication date: 2002-03-23 Date of revision: 2016-08-08 Revision number: 0501 Product number: 51803 15 / 17 SOUDAFOAM WINDOW & DOOR GUN GRADE if appropriate, grill lighter fluids and fuel for decorative lamps, labelled R65 or H304, intended for supply to the general public.7. Natural or legal persons placing on the market for the first time lamp oils and grill lighter fluids, labelled with R65 or H304, shall by 1 December 2011, and annually thereafter, provide data on alternatives to lamp oils and grill lighter fluids labelled R65 or H304 to the competent authority in the Member State concerned. Member States shall make those data available to the Commission. National legislation Belgium SOUDAFOAM WINDOW & DOOR GUN GRADE No data available National legislation The Netherlands SOUDAFOAM WINDOW & DOOR GUN GRADE Waste identification (the Netherlands) LWCA (the Netherlands): KGA category 06 Waterbezwaarlijkheid A (2) National legislation France SOUDAFOAM WINDOW & DOOR GUN GRADE No data available National legislation Germany SOUDAFOAM WINDOW & DOOR GUN GRADE WGK 2; Classification water polluting based on the components in compliance with Verwaltungsvorschrift wassergefhrdender Stoffe (VwVwS) of 27 July 2005 (Anhang 4) polymethylene polyphenyl isocyanate TRGS905 - Krebserzeugend 2 TRGS905 - Erbgutverndernd - TRGS905 - Fruchtbarkeitsgefhrdend - TRGS905 - Fruchtschdigend - TA-Luft 5.2.5; I TRGS900 - Risiko der Fruchtschdigung pMDI (als MDI berechnet); Y; Risiko der Fruchtschdigung braucht bei Einhaltung des Arbeitsplatzgrenzwertes und des biologischen Grenzwertes nicht befrchtet zu werden Sensibilisierende Stoffe pMDI (als MDI berechnet); Sa; Atemwegssensibilisierende Stoffe Hautresorptive Stoffe pMDI (als MDI berechnet); H; Hautresorptiv alkanes, C14-17, chloro TA-Luft 5.2.5; I TRGS900 - Risiko der Fruchtschdigung Chloralkane, C14-17 (Chlorierte Paraffine C14-17 ); Y; Risiko der Fruchtschdigung braucht bei Einhaltung des Arbeitsplatzgrenzwertes und des biologischen Grenzwertes nicht befrchtet zu werden Hautresorptive Stoffe Chloralkane, C14-17 (Chlorierte Paraffine C14-17 ); H; Hautresorptiv reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl ester and phosphoric acid, 2-chloro-1-methylethyl bis(2-chloropropyl) ester TA-Luft 5.2.5 National legislation United Kingdom SOUDAFOAM WINDOW & DOOR GUN GRADE No data available polymethylene polyphenyl isocyanate Skin Sensitisation Isocyanates, all (as -NCO) Except methyl isocyanate; Sen Respiratory sensitisation Isocyanates, all (as -NCO) Except methyl isocyanate; Sen Other relevant data SOUDAFOAM WINDOW & DOOR GUN GRADE No data available polymethylene polyphenyl isocyanate IARC - classification 3; Polymethylene polyphenyl isocyanate alkanes, C14-17, chloro IARC - classification 2B; Chlorinated paraffins 15.2. Chemical safety assessment No chemical safety assessment has been conducted for the mixture. SECTION 16: Other information Full text of any H-statements referred to under headings 2 and 3: H220 Extremely flammable gas. H222 Extremely flammable aerosol. Reason for revision: 15.1 Publication date: 2002-03-23 Date of revision: 2016-08-08 Revision number: 0501 Product number: 51803 16 / 17 SOUDAFOAM WINDOW & DOOR GUN GRADE H229 Pressurised container: May burst if heated. H280 Contains gas under pressure; may explode if heated. H302 Harmful if swallowed. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H362 May cause harm to breast-fed children. H373 May cause damage to organs through prolonged or repeated exposure if inhaled. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H413 May cause long lasting harmful effects to aquatic life. (*) INTERNAL CLASSIFICATION BY BIG PBT-substances persistent, bioaccumulative and toxic substances CLP (EU-GHS) Classification, labelling and packaging (Globally Harmonised System in Europe) Specific concentration limits CLP polymethylene polyphenyl isocyanate C ≥ 5 % Eye Irrit 2;H319 analogous to Annex VI C ≥ 5 % Skin Irrit 2;H315 analogous to Annex VI C ≥ 0.1 % Resp Sens 1;H334 analogous to Annex VI C ≥ 5 % STOT SE 3;H335 analogous to Annex VI alkanes, C14-17, chloro 1,0 % ≤ C ≤ 20 % EUH066 FEICA Position Paper on the classification and labelling of One Component Foam (OCF) containing Mid Chained Chlorinated Paraffin (MCCP) March 7th 2014) 1,0 % ≤ C ≤ 20 % Lact. ; H362 FEICA Position Paper on the classification and labelling of One Component Foam (OCF) containing Mid Chained Chlorinated Paraffin (MCCP) March 7th 2014) 0,25 % ≤ C ≤ 20 % Aquatic Chron. 4;H413 FEICA Position Paper on the classification and labelling of One Component Foam (OCF) containing Mid Chained Chlorinated Paraffin (MCCP) March 7th 2014) The information in this safety data sheet is based on data and samples provided to BIG. The sheet was written to the best of our ability and according to the state of knowledge at that time. The safety data sheet only constitutes a guideline for the safe handling, use, consumption, storage, transport and disposal of the substances/preparations/mixtures mentioned under point 1. New safety data sheets are written from time to time. Only the most recent versions may be used. Old versions must be destroyed. Unless indicated otherwise word for word on the safety data sheet, the information does not apply to substances/preparations/mixtures in purer form, mixed with other substances or in processes. The safety data sheet offers no quality specification for the substances/preparations/mixtures in question. Compliance with the instructions in this safety data sheet does not release the user from the obligation to take all measures dictated by common sense, regulations and recommendations or which are necessary and/or useful based on the real applicable circumstances. BIG does not guarantee the accuracy or exhaustiveness of the information provided and cannot be held liable for any changes by third parties. This safety data sheet is only to be used within the European Union, Switzerland, Iceland, Norway and Liechtenstein. Any use outside of this area is at your own risk. Use of this safety data sheet is subject to the licence and liability limiting conditions as stated in your BIG licence agreement or when this is failing the general conditions of BIG. All intellectual property rights to this sheet are the property of BIG and its distribution and reproduction are limited. Consult the mentioned agreement/conditions for details. Reason for revision: 15.1 Publication date: 2002-03-23 Date of revision: 2016-08-08 Revision number: 0501 Product number: 51803 17 / 17 VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\Appendix IX- VMS Alarm.rtf APPENDIX IX VMS ALARM VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina July 15, 2019 D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Units 1-7\Appendix X- DRAGO.rtf APPENDIX X DREGO SEAL EPOXY P1 OF 2 DRAGO® SEALANT A STEGO TECHNOLOGY, LLC INNOVATION | VAPOR RETARDERS 07 26 00, 03 30 00 | VERSION: 06/23/2017 1. PRODUCT NAME DRAGO SEALANT 2. MANUFACTURER c/o Stego® Industries, LLC* 216 Avenida Fabricante, Suite 101 San Clemente, CA 92672 Sales, Technical Assistance Ph: (877) 464-7834 Fx: (949) 257-4113 www.stegoindustries.com 3. PRODUCT DESCRIPTION USES: Drago Sealant is designed to be used as a vapor intrusion membrane in conjunction with Drago® Wrap Vapor Intrusion Barrier. Drago Sealant can be used as an alternate to detail patches for penetrations in Drago Wrap. COMPOSITION: Drago Sealant is a two-component, high performance modified cycloaliphatic epoxy sealant. SIZE: Drago Sealant comes in a 1.8-gallon kit size: Part A (Resin) and Part B (Hardener). 4. TECHNICAL DATA TABLE 4.1: PHYSICAL PROPERTIES OF DRAGO SEALANT PROPERTY TEST RESULTS Elongation ASTM D412 550-600% Tensile Strength ASTM D412 2,000 +/- 100 psi Compressive Strength ASTM C695 8,800 psi Hardness, Shore D ASTM D2240 52 Flexural Strength ASTM D790 4,700 psi Bond to Concrete ASTM D4541 350 psi Water Vapor Permeance ASTM E96 0.027 perms @ 20-mils Taber Abrasion ASTM D4060 75-80 Mgs Chemical Resistance ASTM D471/D543 No significant change (TCE, PCE, Toluene, Xylene) to mass or volume. Continued... Note – legal notice on page 2. 5. INSTALLATION PREPARATION: • A test application simulating the project environment should always be done prior to final usage of Drago Sealant. • All surfaces should be dry and free of loose materials, oils, and other contaminants. The surfaces should be cleaned in the same fashion as the test surface in order to ensure proper application. • Drago Sealant can be applied to virtually any shape or contour by brush, paint roller, trowel or squeegee at various spread rates. Optimum ambient temperature is between 40-90°F during application. Note: Cure times are affected by ambient and surface temperatures. Temperatures of 40°F and lower can slow cure times. Temperatures of 85°F and higher will speed up cured times and reduce working time. DRAGO® SEALANT A STEGO TECHNOLOGY, LLC INNOVATION | VAPOR RETARDERS 07 26 00, 03 30 00 | VERSION: 06/23/2017 DATA SHEETS ARE SUBJECT TO CHANGE. FOR MOST CURRENT VERSION, VISIT WWW.STEGOINDUSTRIES.COM (877) 464-7834 | www.stegoindustries.com * Stego Industries, LLC is the exclusive Representative for all products, including Drago® Wrap and accessory products, owned by Stego Technology, LLC, a wholly independent company from Stego Industries, LLC. Drago, the Drago logo, and DragoTack are deemed to be registered and/or protectable trademarks of Stego Technology, LLC. Stego and the stegosaurus logo, are deemed to be registered and/or protectable trademarks of Stego Industries, LLC. © 2017 Stego Industries, LLC. All Rights Reserved. Installation and Warranty Information: www.stegoindustries.com/legal. PREPARATION: Continued... • Drago Sealant comes in a 1.8-gallon kit size. It consists of Part A (Resin) and Part B (Hardener). Mix the following with a drill and mixing paddle (Note: If using a drill mixer, use a low speed [not to exceed 300 rpm] to prevent air entrapment): - Pour Part B into Part A (2-gallon bucket) and mix well for 2 minutes. - Drago Sealant is designed to be immediately poured. Leaving mixed product in the container will greatly reduce pot life. Once poured out on the membrane, 15 minutes of working time can generally be expected. PENETRATIONS: • To repair penetrations in Drago Wrap, cut a hole in Drago Wrap such that the membrane fits over and around the base of the pipes as closely as possible, ensuring that it is flush with the base of the penetrations. • Install Drago® Sealant Form continuously around the entire perimeter of the group of penetrations and at least 1 inch beyond the terminating edge of Drago Wrap. • Pour Drago Sealant inside of Drago Sealant Form to create a seal around the penetrations. • If the void space between Drago Wrap and the penetrations is not minimized and/or the base course allows for too much drainage of the sealant, a second coat of Drago Sealant may need to be poured after the first application has cured. Review Drago Wrap’s complete installation instructions prior to installation. 6. AVAILABILITY & COST Drago Sealant is available nationally through our network of building supply distributors. For current cost information, contact your local Drago distributor or Stego Industries’ Sales Representative. 7. WARRANTY Stego Industries, LLC believes to the best of its knowledge, that specifications and recommendations herein are accurate and reliable. However, since site conditions are not within its control, Stego Industries does not guarantee results from the use of the information provided and disclaims all liability from any loss or damage. Stego Technology, LLC does offer a limited warranty on Drago Wrap. Please see www.stegoindustries.com/legal. 8. MAINTENANCE Store Drago Sealant in a dry and temperate area. 9. TECHNICAL SERVICES Technical advice, custom CAD drawings, and additional information can be obtained by contacting Stego Industries or by visiting the website. Contact Number: (877) 464-7834 Website: www.stegoindustries.com 10. FILING SYSTEMS • www.stegoindustries.com • Buildsite P2 OF 2