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HomeMy WebLinkAbout22007 S. Tryon Commercial Vertical Soil Gas Profile Assessment Report_S. Tryon Commercial_20190515 Via Email May 15, 2019 North Carolina Department of Environmental Quality Division of Waste Management – Brownfields Program 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Attention: Mr. Bill Schmithorst, PG Re: Vertical Soil Gas Profile Assessment Report S. Tryon Commercial Charlotte, North Carolina Brownfields Project No. 22007-18-060 H&H Job No. RMR-006 Dear Bill: 1.0 Introduction On behalf of RRPV South Tryon Charlotte, LP (the Prospective Developer or PD), Hart & Hickman, PC (H&H) has prepared this report to document vertical soil gas profile assessment activities recently completed at the South Tryon Commercial Brownfields property (Brownfields Project No. 22007-18-060) located northeast of the South Tryon Street and West Tremont Avenue intersection in a mixed residential and commercial area of South End Charlotte, Mecklenburg County, North Carolina (Site). A Site location map is provided as Figure 1, and the Site and surrounding area are shown in Figure 2. Proposed redevelopment at the Site includes construction of two commercial buildings (Building AB and Building C) with associated parking areas and open spaces. The future intended uses of the new buildings include retail and office spaces. The proposed redevelopment layout Site is depicted in Figure 3. Mr. Bill Schmithorst, PG May 15, 2019 Page 2 S:\AAA-Master Projects\Ram Realty - RMR\RMR-006 Tryon & Tremont Brownfields Assistance\Vertical Soil Gas Profile Report\Final to DEQ\Vertical Soil Gas Profile Assessment Report_S. Tryon Commercial (BPN 22007-18-060)_20190515.doc The Site received eligibility into the North Carolina Department of Environmental Quality (DEQ) Brownfields Program via a Letter of Eligibility dated February 18, 2018. The PD subsequently elected to participate in the Brownfields Program Redevelopment Now option. As part of this process, a kick-off/data gap meeting with the PD, counsel for the PD, DEQ Brownfields personnel, and H&H was held on March 22, 2018 to conduct a Site walk and to discuss historical uses of the Site, available environmental information, proposed redevelopment plans, data gaps, and the proposed schedule for completing the Brownfields Agreement. Based on discussions with DEQ Brownfields during the kick-off/data gap meeting, H&H prepared a Brownfields Assessment Work Plan (Work Plan) and revisions to the Work Plan based on DEQ Brownfields comments. The Work Plan received DEQ Brownfields approval in an email dated May 8, 2018. A brief summary of previous Site assessment activities is provided in the following section. 1.1 Previous Environmental Assessments H&H completed soil and soil gas assessment activities at the Site in May 2018 in accordance with the DEQ Brownfields approved Work Plan. Results of the assessment activities are documented in the Brownfields Assessment Report dated July 9, 2018. The Brownfields assessment soil and soil gas sample locations are shown in Figure 3, and a brief summary of the assessment results is provided below.  Low levels of volatile organic compounds (VOCs), semi-VOCs (SVOCs), and metals were detected in soil below DEQ Inactive Hazardous Sites Branch (IHSB) Industrial/Commercial Preliminary Soil Remediation Goals (PSRGs) and within the ranges for naturally occurring metals in the area of the Site. Results of cumulative risk calculations indicated that grading and movement of soil during redevelopment activities at the Site will not present a significant risk to construction workers or future non- residential workers. Mr. Bill Schmithorst, PG May 15, 2019 Page 3 S:\AAA-Master Projects\Ram Realty - RMR\RMR-006 Tryon & Tremont Brownfields Assistance\Vertical Soil Gas Profile Report\Final to DEQ\Vertical Soil Gas Profile Assessment Report_S. Tryon Commercial (BPN 22007-18-060)_20190515.doc  Soil gas sample monitoring points were installed to a depth of 10 feet (ft) below ground surface (bgs) within the footprints of the proposed commercial buildings. Laboratory analytical results indicated that low levels of several VOCs were detected in each soil gas sample at concentrations below the DEQ Division of Waste Management (DWM) Non- Residential Sub-slab and Exterior Soil Gas Screening Levels (SGSLs). Results of cumulative risk calculations using the highest compound concentrations detected in soil gas samples collected at the Site indicated that there is no significant vapor intrusion risk into the proposed buildings. A tabular summary of the May 2018 soil gas sample analytical data is provided in Table 1. H&H completed groundwater assessment activities at the Site in July and August 2007. July 2007 groundwater assessment activities included installation of three (3) temporary groundwater monitoring wells (DPT-2, DPT-8, DPT-9) and collection of groundwater samples for laboratory analysis. In August 2007, permanent groundwater monitoring well MW-3 was installed and sampled to further evaluate groundwater conditions in the area of temporary groundwater monitoring well DPT-9. Locations of the temporary and permanent groundwater monitoring wells (denoted by DPT and MW nomenclature, respectively) are depicted on Figure 3. The 2007 groundwater assessment activities are documented in the Summary of Previous Groundwater Assessment Activities report dated November 19, 2018. A brief summary of the groundwater assessment results is provided below.  Results of the groundwater assessment activities indicated that low levels of tetrachloroethene or PCE (up to 1.6 micrograms per liter [µg/L]), trichloroethene or TCE (up to 14 µg/L), aldrin (up to 0.63 µg/L), dieldrin (up to 0.75 µg/L) and selenium (up to 33 µg/L) were detected in Site groundwater at concentrations exceeding DEQ groundwater screening criteria. Cumulative risk calculation results using the highest compound concentrations detected in Site groundwater samples indicates that there is no significant vapor intrusion risk for the proposed buildings. This is consistent with results of the 2018 soil gas sampling activities. Mr. Bill Schmithorst, PG May 15, 2019 Page 4 S:\AAA-Master Projects\Ram Realty - RMR\RMR-006 Tryon & Tremont Brownfields Assistance\Vertical Soil Gas Profile Report\Final to DEQ\Vertical Soil Gas Profile Assessment Report_S. Tryon Commercial (BPN 22007-18-060)_20190515.doc Although cumulative risk calculations did not indicate that there is a significant risk for vapor intrusion into the proposed commercial buildings, DEQ Brownfields expressed concerns associated with changes to subsurface vapor concentrations and vapor migration patterns that may result from placement of paved surfaces and construction of new slab-on-grade buildings at the Site. Based on discussions with DEQ Brownfields personnel, H&H prepared a Vertical Soil Gas Profile Assessment Work Plan (VI Work Plan) dated April 3, 2019 to complete additional soil gas assessment activities to further evaluate the potential for vapor intrusion into the proposed commercial buildings. DEQ provided approval of the VI Work Plan in an email dated April 8, 2019. A summary of the vertical soil gas profile assessment activities is provided in the following sections. 2.0 Vertical Soil Gas Profile Assessment Activities On April 18 and April 19, 2019, H&H completed vertical soil gas profile assessment activities at the Site to further evaluate the potential for vapor intrusion and confirm that there are no vadose zone soil impacts at the Site that would contribute to potential vapor intrusion upon completion of redevelopment activities. Vertical soil gas profile assessment activities consisted of advancing five (5) soil borings for installation of nested shallow and deeper soil gas monitoring points within the approximate footprints of the proposed commercial buildings. Soil gas borings VMP-8 and VMP-9 were advanced within the footprint of Building C and soil gas borings VMP-10 through VMP-12 were advanced within the footprint of Building AB. Nested soil gas boring locations are shown in Figure 4. The assessment activities were conducted in general accordance with the DEQ Brownfields approved VI Work Plan, the DEQ IHSB Guidelines for Assessment and Cleanup (Guidelines) dated October 2015, the DEQ DWM Vapor Intrusion Guidance (VI Guidance) dated March 2018, and the most recent versions of the U.S. Environmental Protection Agency (EPA) Region IV Science and Ecosystem Support Division (SESD) Field Branches Quality System and Mr. Bill Schmithorst, PG May 15, 2019 Page 5 S:\AAA-Master Projects\Ram Realty - RMR\RMR-006 Tryon & Tremont Brownfields Assistance\Vertical Soil Gas Profile Report\Final to DEQ\Vertical Soil Gas Profile Assessment Report_S. Tryon Commercial (BPN 22007-18-060)_20190515.doc Technical Procedures guidance. Prior to conducting field activities, H&H contacted NC One-Call (811), the public utility locator, to mark subsurface utilities at the Site. H&H also contracted with Probe Utility Locating (Probe), a private utility locator to screen the proposed boring locations for subsurface utilities. Additionally, each soil gas boring location was hand cleared to a depth of approximately 5 ft bgs to further screen the boring locations for the presence of subsurface utilities. 2.1 Soil Gas Sampling Methodologies H&H contracted with Mid South Environmental, Inc. (Mid South) to advance soil gas borings utilizing a track-mounted direct-push technology (DPT) drill rig. As described in Section 2.0, the initial 5 ft of each soil boring were advanced with a decontaminated stainless-steel hand auger. Beyond the initial 5 ft, the borings were advanced using DPT drilling methods. Continuous soil samples were collected from the center of the hand auger bucket and using acetate lined DPT macrocore sleeves at each soil boring. Soil samples were described for lithologic purposes, observed for obvious evidence of staining and odors, and field screened for the presence of volatile organic vapors using a calibrated photoionization detector (PID). Field screening results did not identify obvious evidence of potential soil impacts in soil samples collected from the soil gas borings. Boring logs with lithologic descriptions and field screening results are provided in Appendix A. During soil gas boring advancement, H&H observed the water table at a depth of approximately 20 ft bgs in the area of Building C and approximately 19 ft in the area of Building AB. Therefore, the deeper Building C soil gas monitoring points (VMP-8 and VMP-9) were installed to a depth of approximately 16 ft bgs and the deeper Building AB soil gas monitoring points (VMP-10 through VMP-12) were installed to a depth of approximately 15 ft bgs. Shallow soil gas monitoring points were installed to a depth of approximately 5.5 ft bgs at each soil gas boring location. Mr. Bill Schmithorst, PG May 15, 2019 Page 6 S:\AAA-Master Projects\Ram Realty - RMR\RMR-006 Tryon & Tremont Brownfields Assistance\Vertical Soil Gas Profile Report\Final to DEQ\Vertical Soil Gas Profile Assessment Report_S. Tryon Commercial (BPN 22007-18-060)_20190515.doc A dedicated six-inch stainless-steel vapor implant screen fitted with ¼-inch diameter Teflon® tubing was installed at the base of each soil gas boring for construction of the deeper soil gas monitoring points. Filter sand was placed from the base of the soil gas boring to approximately 6-inches above the deeper screened interval. A hydrated bentonite seal was placed from the top of the filter sand to approximately 5.5 ft bgs. A second six-inch stainless-steel vapor implant screen fitted with ¼-inch diameter Teflon® tubing was placed at the top of the bentonite seal within each soil gas boring for construction of the shallow soil gas monitoring points. Filter sand was placed from the top of the bentonite to approximately 6-inches above the shallow screened interval. A hydrated bentonite seal was placed from the top of the shallow sample filter sand to the ground surface. Prior to sampling, a leak check was conducted for each nested soil gas monitoring point by constructing a shroud around the sampling system and flooding air within the shroud with helium gas. Helium concentrations inside the shroud were measured using a helium gas detector throughout the leak check. Using a syringe and three-way valve, the Teflon® tubing and surrounding sand pack were purged of approximately three volumes. Once the soil gas monitoring points were properly purged, vapor was collected from the sample tubing outside the shroud into a Tedlar® bag and analyzed using the helium gas detector to ensure that helium concentrations were less than 10% of the helium concentrations measured within the shroud. Each of the nested soil gas monitoring points passed the leak check criteria. Following a successful field leak check, soil gas samples were collected from each nested soil gas monitoring point into six-liter Summa canisters for laboratory analysis by connecting the Teflon® sample tubing to an airflow regulator using a brass nut and ferrule assembly to create an air tight seal. The airflow regulator was calibrated by the laboratory to allow the Summa canisters to fill at a rate of approximately 100 mL/min. Once the sample train was assembled, the intake valve on the canister was fully opened to begin collection of the soil gas sample. Vacuum readings from the Summa canister were recorded prior to and following the sampling period to ensure adequate sample volume was collected. Per laboratory requirements, vacuum was maintained within each canister at the conclusion of the sampling event. Mr. Bill Schmithorst, PG May 15, 2019 Page 7 S:\AAA-Master Projects\Ram Realty - RMR\RMR-006 Tryon & Tremont Brownfields Assistance\Vertical Soil Gas Profile Report\Final to DEQ\Vertical Soil Gas Profile Assessment Report_S. Tryon Commercial (BPN 22007-18-060)_20190515.doc Upon collection of each sample, each Summa canister valve was closed, and the regulator was disconnected from the canister. The canisters were placed in laboratory supplied shipping containers, properly labeled and shipped under standard chain-of-custody protocols to Pace Analytical Services (Pace) for analysis of PCE, TCE, cis-1,2-dichloroethene (DCE), trans-1,2- DCE, and vinyl chloride by EPA Method TO-15. Upon completion of sampling activities, each soil gas boring was properly abandoned and the surfaces were repaired similar to surrounding ground surface. The soil gas boring locations were estimated using the hand-held global positioning system (GPS) unit. 2.2 Soil Gas Analytical Results A tabular summary of the vertical soil gas profile analytical results is provided in Table 2. The soil gas analytical results were compared to DEQ DWM Vapor Intrusion Residential and Non- Residential Sub-Slab and Exterior Soil Gas Screening Levels (SGSLs) dated February 2018. A copy of the laboratory analytical report is provided in Appendix B. A summary of deeper and shallow soil gas sample laboratory analytical results for each proposed building is provided below. Building C - Vertical Soil Gas Profile Sampling Results As shown in Table 2 and in Figure 4, shallow and deeper soil gas samples were collected from the VMP-8 and VMP-9 soil gas sample locations within the Building C footprint. Low levels of PCE were detected at concentrations below the Residential and Non-Residential SGSLs of 280 µg/m3 and 3,500 µg/m3, respectively in both deeper (range 1.1 µg/m3 to 7.0 µg/m3) and shallow (range 1.3 µg/m3 to 1.6 µg/m3) VMP-8 and VMP-9 soil gas samples. Laboratory analytical results indicate that low levels of TCE were also detected in both the deeper and shallow VMP-8 and VMP-9 soil gas samples. TCE concentrations detected in the deeper VMP-8 (85.0 µg/m3) and VMP-9 (15.4 µg/m3) soil gas samples were above the Residential SGSL of 14 µg/m3, but below the Non-Residential SGSL of 180 µg/m3. Low levels Mr. Bill Schmithorst, PG May 15, 2019 Page 8 S:\AAA-Master Projects\Ram Realty - RMR\RMR-006 Tryon & Tremont Brownfields Assistance\Vertical Soil Gas Profile Report\Final to DEQ\Vertical Soil Gas Profile Assessment Report_S. Tryon Commercial (BPN 22007-18-060)_20190515.doc of TCE were also detected in the shallow VMP-8 (15.2 µg/m3) and VMP-9 (6.2 µg/m3) soil gas samples. The TCE concentrations in the shallow VMP-8 soil gas sample slightly exceeds the Residential SGSL. The TCE concentration detected in the shallow VMP-9 (6.2 µg/m3) soil gas sample is below both the Residential and Non-Residential SGSLs. TCE was not detected at concentrations exceeding the Non-Residential SGSL in deeper or shallow VMP-8 and VMP-9 soil gas samples and TCE concentrations detected in shallow soil gas were less than the concentrations found in the nested deeper soil gas samples. No other compounds were detected at concentrations above the laboratory method detection limits in the Building C deeper or shallow soil gas samples, and no compounds were detected at concentrations exceeding the Non-Residential SGSLs in deeper or shallow Building C soil gas samples. Building AB – Vertical Soil Gas Profile Sampling Results Shallow and deeper soil gas samples were collected from the VMP-10 through VMP-12 sample locations within the Building AB footprint (Table 2 and Figure 4). Low levels of PCE (up to 130 µg/m3) were detected at concentrations below the Residential SGSL of 280 µg/m3 in each of the three deeper Building AB soil gas samples. A low level of PCE was detected at a concentration above the laboratory method detection limit in the shallow VMP-10 (1.9 µg/m3) soil gas sample, but well below the Residential SGSL. PCE was not detected above the laboratory method detection limits in the shallow VMP-11 and VMP-12 soil gas samples. PCE was not detected above the Non-Residential SGSL in the shallow or deeper Building AB soil gas samples. Laboratory analytical results indicate that low levels of TCE (up to 140 µg/m3) were also detected at concentrations above the Residential SGSL of 14 µg/m3 in each of the deeper Building AB soil gas samples. Concentrations of TCE (up to 1.4 µg/m3) were detected in the shallow Building AB soil gas samples at levels below the Residential SGSL. TCE was not detected above the Non-Residential SGSL of 180 µg/m3 in the deeper or shallow Building AB soil gas samples. In addition, TCE concentrations in shallow Building AB soil gas samples were Mr. Bill Schmithorst, PG May 15, 2019 Page 9 S:\AAA-Master Projects\Ram Realty - RMR\RMR-006 Tryon & Tremont Brownfields Assistance\Vertical Soil Gas Profile Report\Final to DEQ\Vertical Soil Gas Profile Assessment Report_S. Tryon Commercial (BPN 22007-18-060)_20190515.doc detected at lower levels than found in deeper Building AB soil gas samples. 2.3 Cumulative Risk Calculations The DEQ DWM SGSLs are conservative and based on a lifetime incremental cancer risk (LICR) for potential carcinogenic risks of 1 x 10-5 and a non-carcinogenic hazard quotient (HQ) of 0.2 for potential non-carcinogenic risks. The DEQ acceptable level for potential carcinogenic risks is 1 x 10-4 and the acceptable level for non-carcinogenic risks is a HI less than 1. To further evaluate potential cumulative risks for structural vapor intrusion into the proposed Site buildings, H&H utilized the DEQ risk calculator (February 2018) assuming a non- residential land use scenario based on the planned use at the Site. H&H calculated the hypothetical worst-case cumulative risks using the highest concentrations of any compound detected in the soil gas samples. Additionally, H&H calculated the worst-case scenario using the highest concentrations of any detected compound in the shallow samples and the worst-case scenario for the deep samples to compare the risk levels for the vertical soil profile within the footprints of the proposed buildings. Copies of the completed risk calculator results are provided in Appendix C and a summary of the risk calculation results is below: Sample ID Depth Non-Residential Scenario LICR HI Worst Case Shallow 5.1 x 10-8 1.7 x 10-2 Worst Case Deeper 5.0 x 10-7 1.7 x 10-1 Worst Case Either Depth 5.0 x 10-7 1.7 x 10-1 As noted in the table above, results of risk calculations indicate that the calculated cumulative risks do not exceed acceptable levels for a non-residential worker for shallow or deeper soil gas Mr. Bill Schmithorst, PG May 15, 2019 Page 10 S:\AAA-Master Projects\Ram Realty - RMR\RMR-006 Tryon & Tremont Brownfields Assistance\Vertical Soil Gas Profile Report\Final to DEQ\Vertical Soil Gas Profile Assessment Report_S. Tryon Commercial (BPN 22007-18-060)_20190515.doc under a hypothetical worst-case scenario for the proposed buildings. Additionally, the shallow worst-case scenario is an order of magnitude below the cumulative risk calculated for deeper soil gas samples. Results of vertical soil gas profile assessment activities confirm that there is not a significant vapor intrusion risk into the proposed commercial buildings. Additionally, attenuation of concentrations in shallow soil gas indicates that there is no soil source within the footprints of the proposed buildings that would contribute to potential vapor intrusion or changes to vapor migration patterns upon completion of proposed redevelopment. 3.0 Summary and Conclusion H&H has completed vertical soil gas profile assessment activities on the South Tryon Commercial Brownfields property located northeast of the South Tryon Street and West Tremont Avenue intersection in Charlotte, North Carolina. The assessment activities were conducted in accordance with the DEQ Brownfields approved VI Work Plan dated April 3, 2019. Assessment activities included installation of five (5) nested shallow and deeper soil gas monitoring points within the footprints of proposed commercial buildings. Soil gas samples representative of conditions in the shallow and deeper soil profile were collected from each location and submitted for laboratory analysis the further evaluate the potential for vapor intrusion and changes to vapor migration patterns that may result from placement of paved surfaces and construction of new slab-on-grade buildings at the Site. Results of the assessment indicate that PCE and/or TCE were detected at concentrations above the laboratory method detection limits in both deeper and shallow soil gas samples. No compounds were detected at concentrations above the DEQ DWM Vapor Intrusion Non- Residential SGSLs in shallow or deeper soil gas samples. In addition, compound concentrations in shallow soil gas were lower than compound concentrations in deeper soil gas. Results of hypothetical worst-case risk calculations indicate that the cumulative LICR and HI values for Mr. Bill Schmithorst, PG May 15, 2019 Page 12 S:\AAA-Master Projects\Ram Realty - RMR\RMR-006 Tryon & Tremont Brownfields Assistance\Vertical Soil Gas Profile Report\Final to DEQ\Vertical Soil Gas Profile Assessment Report_S. Tryon Commercial (BPN 22007-18-060)_20190515.doc Attachments: Table 1 Summary of Previous Soil Gas Analytical Data Table 2 Summary of Vertical Soil Gas Profile Analytical Data Figure 1 Site Location Map Figure 2 Site Map Figure 3 Previous Assessment Sample Location Map Figure 4 Vertical Soil Gas Profile Sample Location Map Appendix A Soil Gas Boring Logs and Monitoring Point Construction Details Appendix B Laboratory Analytical Report Appendix C DEQ Risk Calculators (February 2018) Table 1Summary of Previous Soil Gas Analytical DataSouth Tryon CommercialCharlotte, North CarolinaBrownfields Project No. 22007-18-060H&H Job No. RMR-006DRAFTSample LocationSample IDVMP-1 VMP-2 VMP-4 VMP-5 VMP-6 VMP-7Sample Depth (ft bgs)9.5-10 9.5-10 9.5-10 9.5-10 9.5-10 9.5-10Sampling Date 05/18/18 05/18/18 05/18/18 05/18/18 05/18/18 05/18/18UnitsVOCs (TO-15)Acetone13 J 14 J 11 J 9.9 J 25<6.635 9.2 J 220,000 2,700,000Benzene8.7 21 30 31 36 61 77 5.4 120 1,6002-Butanone (Methyl Ethyl Ketone)1.3 J 1.6 J 1.6 J 1.4 J<0.441.5 J 1.8 J 1.3 J 35,000 440,000Carbon Disulfide5.9 J 12 17 16 32 71 82 3.0 J 4,900 61,000Carbon Tetrachloride<0.372.4 4.1 4.3<0.37 <0.37 <0.371.3 160 2,000Chloroform72 6928 2754 46 290 36041 530cis-1,2-Dichloroethene<0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32NE NECyclohexane<0.49 <0.49 <0.49 <0.49 <0.496.9 8.5<0.4942,000 530,0001,3-Dichlorobenzene25 24 17 15 25 28 31 26 NE NEDichlorodifluoromethane (Freon 12)3.2 L-05 2.8 3.4 L-05 2.9<0.433.0 3.8 L-05 2.8 700 8,8001,1-Dichloroethylene<0.31 <0.31<0.31 <0.31 <0.311.6<0.31 <0.311,400 7,700Ethanol<6.77.1 J<6.7 <6.7 <6.7 <6.7 <6.7 <6.7NE NEEthylbenzene78 90 110 120 91 160 170 22 370 4,9004-Ethyltoluene<0.6040 38 40 20 36 50 8.4 NE NEHeptane13 35 31 34 58 90 110 7.8 2,800 35,000Hexane3.2 J 16 J 10 J 11 J 39 68 88 5.7 J 4,900 61,000Isopropanol0.99 J 3.9 J 1.2 J<0.60 <0.60 <0.60 <0.60 <0.601,400 18,000Propene (Propylene)2.3 J<0.34 <0.34 <0.34 <0.3412 J 48<0.3421,000 260,000Tetrachloroethene6.2 3.7 12 13 84 3.7 1.9<0.75280 3,500Toluene280 380 580 590 580 970 1,100 110 35,000 440,000trans-1,2-Dichloroethene<0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32NE NETrichloroethene66 42 52 536.4708.0 6.1 14 180Trichlorofluoromethane (Freon 11)3.2 J 2.2 J 6.2 5.2 2.2 J 2.9 J 4.2 J 2.2 J NE NE1,2,4-Trimethylbenzene120 120 100 100 45 90 120 25 420 5,3001,3,5-Trimethylbenzene28 26 20 20 11 19 26 6.5 420 5,300Vinyl Acetate1.4 J 3.2 J<0.34 <0.34 <0.349.8 J 12 J 1.8 J 1,400 18,000Vinyl Chloride<0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.3256 2,800m&p-Xylene300 320 410 420 320 550 640 84 700 8,800o-Xylene96 110 140 140 94 160 190 25 700 8,800Notes:1) North Carolina Department of Environmental Quality (DEQ) Division of Waste Management (DWM) Residential Sub-slab and Exterior Soil Gas Screening Levels (SGSLs) (February 2018).2) North Carolina DEQ DWM Non-Residential SGSLs (February 2018).Bold indicates concentration exceeds DEQ Residential SGSLs (February 2018).Only compounds detected in at least one sample are shown.Compound concentrations reported in micrograms per cubic meter (µg/m3) and to the laboratory method detection limits.Analytical method is indicated in parentheses.J = Detected concentration is above the laboratory method detection limit, but below the laboratory reporting limit.L-05 = Laboratory fortified blank/laboratory control sample recovery is outside of control limits and is biased on the high side.ft bgs = feet below ground surface; NE = Not Establishedµg/m3µg/m3µg/m3Building ABBuilding CResidentialSGSL(1)Non-Residential SGSL(2)VMP-3 / DUPLICATE9.5-1005/18/18S:\AAA‐Master Projects\Ram Realty ‐ RMR\RMR‐006 Tryon & Tremont Brownfields Assistance\Vertical Soil Gas Profile Report\Tables\Table 1 South Tryon Commercial SV Table5/3/2019Table 1 (Page 1 of 1)Hart & Hickman, PC Table 2Summary of Vertical Soil Gas Profile Analytical DataSouth Tryon CommercialCharlotte, North CarolinaBrownfields Project No. 22007-18-060H&H Job No. RMR-006DRAFTSample LocationSample IDSample Depth (ft bgs)5-5.5 15.5-16 5-5.5 15.5-16 5-5.5 14.5-15 5-5.5 14.5-15 5-5.5 14.5-15Sampling Date UnitsVOCs (TO-15)cis-1,2-Dichloroethene<0.34 <0.34 <0.37 <0.33 <0.35 <0.35 <0.35 <0.36 <0.36 <0.34NE NETetrachloroethene1.6 7.0 1.3 1.1 1.9 130<0.5111.9<0.512.7 280 3,500trans-1,2-Dichloroethene<0.44 <0.44 <0.48 <0.42 <0.46 <0.45 <0.46 <0.47 <0.47 <0.44NE NETrichloroethene15.2 85.06.215.4<0.4132.80.68 J1401.411414 180Vinyl Chloride<0.20 <0.20 <0.21 <0.19 <0.20 <0.20 <0.20 <0.21 <0.21 <0.2056 2,800Notes:1) North Carolina Department of Environmental Quality (DEQ) Division of Waste Management (DWM) Residential Sub-slab and Exterior Soil Gas Screening Levels (SGSLs) (February 2018).2) North Carolina DEQ DWM Non-Residential SGSLs (February 2018).Bold indicates concentration exceeds DEQ Residential SGSLs (February 2018).Compound concentrations reported in micrograms per cubic meter (µg/m3) and to the laboratory method detection limits.Analytical method is indicated in parentheses.J = Detected concentration is above the laboratory method detection limit, but below the laboratory reporting limit.ft bgs = feet below ground surface; NE = Not Established04/18/19µg/m3µg/m3µg/m304/18/19 04/18/19 04/18/19 04/18/19Building C Building ABResidential SGSL(1)Non-Residential SGSL(2)VMP-8 VMP-9 VMP-10 VMP-11 VMP-12S:\AAA‐Master Projects\Ram Realty ‐ RMR\RMR‐006 Tryon & Tremont Brownfields Assistance\Vertical Soil Gas Profile Report\Tables\Table 1 South Tryon Commercial SV Table5/3/2019Table 1 (Page 1 of 1)Hart & Hickman, PC TITLE PROJECT SITE LOCATION MAP SOUTH TRYON COMMERICAL CHARLOTTE, NORTH CAROLINA DATE: JOB NO: REVISION NO: FIGURE: 5-3-19 0 1RMR-006 SITE 0 2000 4000 APPROXIMATE SCALE IN FEET N U.S.G.S. QUADRANGLE MAP QUADRANGLE 7.5 MINUTE SERIES (TOPOGRAPHIC) CHARLOTTE EAST, NORTH CAROLINA, 1991 REVISION NO. 0 JOB NO. RMR-006 DATE: 5-3-19 FIGURE NO. 2 SOUTH TRYON COMMERCIAL CHARLOTTE, NORTH CAROLINA SITE MAP LEGEND BROWNFIELDS PROPERTY BOUNDARY FORMER BUILDING FOOTPRINT APPROXIMATE LOCATION OF FORMER GASOLINE UNDERGROUND STORAGE TANK 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology MOTOR FRE I G H T S T A T I O N (1950-1950) S. TR Y O N S T R E E T FORMER B&B CONTRACTING COMPANY W. TREMON T A V E N U E DO GG E T T S TR E E T NOTES: 1.AERIAL IMAGERY OBTAINED FROM MECKLENBURG COUNTY GIS (2017). 2.HISTORICAL BUILDING FOOTPRINTS & HISTORICAL USES OBTAINED FROM AVAILABLE RESOURCES INCLUDING SANBORN FIRE INSURANCE MAPS, AERIAL PHOTOGRAPHY, & CITY DIRECTORY. 3.UST = UNDERGROUND STORAGE TANK FORMER RESTAURANT (1949-1959) FORMER FARM MACHINERY SALES & SERVICE (1959-1963) ELECTRICAL SUPPLY WAREHOUSE BUILDING C (1960-1990) FORMER B&B CONTRACTING COMPANY FORMER TERMINIX, INC. (1969-2014) EMCI LTD (2101 S. TRYON STREET) GAS FIRED PRODUCTS (305 DOGGETT STREET) MULTI-TENANT COMMERCIAL (1926-2030 S. TRYON STREET) MULTI-TENANT COMMERCIAL (1927 S. TRYON STREET) FORMER AUTO REPAIR SHOP (1950-1963) APPROXIMATE LOCATION FORMER UST DISPENSER WEST TREMONT (BPN 14006-10-060) TREMONT REDEVELOPMENT (BPN 18004-14-060) 2100 S. TRYON STREET (BPN 22054-18-060) HUGH SUPPLY PROPERTY (BPN 10049-06-060)S:\AAA-Master Projects\Ram Realty - RMR\RMR-006 Tryon & Tremont Brownfields Assistance\Figures\Figures060418.dwg, FIG 2, 5/3/2019 3:32:41 PM, amckenzie SB-2 SB-1 SB-3 VMP-3 VMP-2 VMP-1 SB-4 VMP-4 VMP-5 VMP-6 VMP-7 SB-5 SB-6 REVISION NO. 0 JOB NO. RMR-006 DATE: 5-2-19 FIGURE NO. 3 SOUTH TRYON COMMERCIAL CHARLOTTE, NORTH CAROLINA PREVIOUS ASSESSMENT SAMPLE LOCATION MAP LEGEND BROWNFIELDS PROPERTY BOUNDARY FORMER BUILDING FOOTPRINT PROPOSED BUILDING FOOTPRINT PROPOSED PARKING/ PLAZA AREA APPROXIMATE LOCATION OF FORMER GASOLINE UNDERGROUND STORAGE TANK SOIL BORING LOCATION SOIL GAS SAMPLE LOCATION MONITORING WELL LOCATION TEMPORARY MONITORING WELL LOCATION TEMPORARY MONITORING WELL/ SOIL BORING LOCATION 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology MOTOR FRE I G H T S T A T I O N (1950-1950) S. TR Y O N S T R E E T FORMER B&B CONTRACTING COMPANY W. TREMON T A V E N U E DO G G E T T S T R E E T NOTES: 1.AERIAL IMAGERY OBTAINED FROM MECHLENBURG COUNTY GIS (2017). 2.SOIL SAMPLES COLLECTED ON 5/17/18 AND 5/18/18. 3.SOIL GAS SAMPLES COLLECTED ON 5/18/18. 4.TCE = TRICHLOROETHYLENE BZP = BENZO(A)PYRENE CF = CHLOROFORM PCE = TETRACHLOROETHYLENE μg/L = MICROGRAMS PER LITER μg/m³ = MICROGRAMS PER CUBIC METER mg/kg = MILLIGRAMS PER KILOGRAM NA = NOT ANALYZED 5.J FLAG INDICATES AN ESTIMATED CONCENTRATION BETWEEN THE LABORATORY REPORTING LIMIT AND THE METHOD DETECTION LIMIT. 6.NO COMPOUNDS DETECTED ABOVE SCREENING LEVELS IN SOIL SAMPLES SB-1, SB-2, SB-3, SB-4 AND SB-5. 7.HISTORICAL GROUNDWATER DATA ARE IDENTIFIED IN PURPLE. FORMER RESTAURANT (1949-1959) FORMER B&B CONTRACTING COMPANY FORMER TERMINIX, INC. (1969-2014) FORMER AUTO REPAIR SHOP (1950-1963) APPROXIMATE LOCATION FORMER UST DISPENSER SOIL GAS VMP-2 TCE 42 μg/m³ CF 69 μg/m³ FORMER FARM MACHINERY SALES & SERVICE (1959-1963) ELECTRICAL SUPPLY WAREHOUSE BUILDING C (1960-1990) SAMPLE ID CONCENTRATIONSCONSTITUENTS SOIL GAS VMP-2 TCE 42 μg/m³ CF 69 μg/m³ SOIL GAS VMP-1 TCE 66 μg/m³ CF 72 μg/m³ SOIL GAS VMP-3 / DUPLICATE TCE 52/53 μg/m³ CF 28/27 μg/m³ SOIL GAS VMP-4 TCE 6.4 μg/m³ CF 54 μg/m³ SOIL GAS VMP-5 TCE 70 μg/m³ CF 46 μg/m³ SOIL GAS VMP-6 TCE 8.0 μg/m³ CF 290 μg/m³ SOIL GAS VMP-7 TCE 6.1 μg/m³ CF 360 μg/m³ SOIL SB-6 BZP 0.17J mg/kg GROUNDWATER DPT-8 (7/23/07) PCE <1.0 μg/L TCE 2.5 μg/L DIELDRIN 0.75 μg/LGROUNDWATER DPT-9 (7/24/07) PCE <1.0 μg/L TCE 14 μg/L DIELDRIN 0.15 μg/LGROUNDWATER MW-3 (8/9/07) PCE 1.6 μg/L TCE 11 μg/L DIELDRIN <0.050 μg/L GROUNDWATER DPT-2 (7/20/07) PCE <1.0 μg/L TCE 5.7 μg/L DIELDRIN NA BUILDING AB BUILDING C S:\AAA-Master Projects\Ram Realty - RMR\RMR-006 Tryon & Tremont Brownfields Assistance\Figures\Figures060418.dwg, FIG 2 ALT, 5/3/2019 3:36:52 PM, amckenzie VMP-8 VMP-9 VMP-10 VMP-11 VMP-12 REVISION NO. 0 JOB NO. RMR-006 DATE: 5-3-19 FIGURE NO. 4 SOUTH TRYON COMMERCIAL CHARLOTTE, NORTH CAROLINA VERTICAL SOIL GAS PROFILE SAMPLE LOCATION MAP LEGEND BROWNFIELDS PROPERTY BOUNDARY PROPOSED BUILDING FOOTPRINT PROPOSED PARKING/ PLAZA AREA NESTED SHALLOW AND DEEPER SOIL GAS MONITORING POINT SAMPLE LOCATION 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology S. TR Y O N S T R E E T W. TREMON T A V E N U E DO GG E T T S TR E E T BUILDING AB BUILDING C NOTES: 1.AERIAL IMAGERY OBTAINED FROM MECKLENBURG COUNTY GIS (2017). 2.NESTED SOIL GAS MONITORING POINTS INSTALLED AND SAMPLED ON 4/18/19. 3.PCE = TETRACHLOROETHENE TCE = TRICHLOROETHENE FT BGS = FEET BELOW GROUND SURFACE μg/m³ = MICROGRAMS PER CUBIC METER DEQ = DEPARTMENT OF ENVIRONMENTAL QUALITY DWM = DIVISION OF WASTE MANAGEMENT SGSL = SUB-SLAB AND EXTERIOR SOIL GAS SCREENING LEVELS 4.J FLAG INDICATES AN ESTIMATED CONCENTRATION BETWEEN THE LABORATORY REPORTING LIMIT AND THE METHOD DETECTION LIMIT. 5.BOLD INDICATES CONCENTRATION EXCEED NORTH CAROLINA DEQ DWM RESIDENTIAL SGSL. VMP-8 DEPTH 5-5.5 15.5-16 PCE 1.6 7.0 TCE 15.2 85.0 VMP-9 DEPTH 5-5.5 15.5-16 PCE 1.3 1.1 TCE 6.2 15.4 VMP-10 DEPTH 5-5.5 14.5-15 PCE 1.9 130 TCE <0.41 32.8 VMP-11 DEPTH 5-5.5 14.5-15 PCE <0.51 11.9 TCE 0.68 J 140 VMP-12 DEPTH 5-5.5 14.5-15 PCE <0.51 2.7 TCE 1.4 114 VMP-10 DEPTH 5-5.5 14.5-15 PCE 1.9 130 TCE <0.41 32.8 SAMPLE ID CONCENTRATIONS (μg/m³)CONSTITUENTS SAMPLE DEPTH (FT BGS)S:\AAA-Master Projects\Ram Realty - RMR\RMR-006 Tryon & Tremont Brownfields Assistance\Figures\Figures060418.dwg, FIG 3, 5/3/2019 4:13:39 PM, amckenzie Appendix A Soil Gas Boring Logs and Construction Details NOTES: Hole precleared to 5.0' on 4/18/19 8:45 by Mid South using hand auger. Shallow screen point installed to 5.5 ft bgs. Deeperscreen point installed to 16 ft bgs. generated using GroundLogs.online Client: Project: Address: Ram Realty RMR-006 S. Tryon Commercial , Mecklenburg,Charlotte, NC WELL LOG Well No. Page: VMP-8 1 of 1 Drilling Start Date: Drilling End Date: Drilling Company: Drilling Method: Drilling Equipment: Driller: Logged By: 4/18/19 4/18/19 9:25 Mid South Direct Push Geoprobe 54 DT Don Warren Shane Sisco Boring Depth (ft): Boring Diameter (in): Sampling Method(s): DTW During Drilling (ft): DTW After Drilling (ft): Top of Casing Elev. (ft): Location (X,Y): 16.0 2.50 Well Depth (ft): Well Diameter (in): Screen Slot (in): Riser Material: Screen Material: Seal Material(s): Filter Pack: Bent. Pellets Sand Pack DEPTH (ft)LITHOLOGYWATER LEVELWELLCOMPLETIONCOLLECT Sample TypeTimeBlow CountsRecovery (ft)SOIL/ROCK VISUAL DESCRIPTION MEASURE PID (ppm)Lab SampleDEPTH (ft)0 5 10 15 20 (0') SILT with clay (ML), stiff, moist, reddish orange (1.5') SILT with sand (ML); medium stiff, dry, white (5') As Above: gray and tan (7') As Above: Rock fragments (7'-8') (12') Sandy SILT (ML); soft, moist, gray and tan and white (16') Boring terminated 0.0 0.4 0.3 VMP-8Shallow VMP-8Deep 0 5 10 15 20 NOTES: Hole precleared to 5.0' on 4/18/19 08:10 by Mid South using hand auger. Shallow screen point installed to 5.5 ft bgs. Deeperscreen point installed to 16 ft bgs. generated using GroundLogs.online Client: Project: Address: Ram Realty RMR-006 S. Tryon Commercial , Mecklenburg,Charlotte, NC WELL LOG Well No. Page: VMP-9 1 of 1 Drilling Start Date: Drilling End Date: Drilling Company: Drilling Method: Drilling Equipment: Driller: Logged By: 4/18/19 8:45 Mid South Direct Push Geoprobe 54 DT Don Warren Shane Sisco Boring Depth (ft): Boring Diameter (in): Sampling Method(s): DTW During Drilling (ft): DTW After Drilling (ft): Top of Casing Elev. (ft): Location (X,Y): 20.0 2.50 Well Depth (ft): Well Diameter (in): Screen Slot (in): Riser Material: Screen Material: Seal Material(s): Filter Pack: Bent. Pellets Sand Pack DEPTH (ft)LITHOLOGYWATER LEVELWELLCOMPLETIONCOLLECT Sample TypeTimeBlow CountsRecovery (ft)SOIL/ROCK VISUAL DESCRIPTION MEASURE PID (ppm)Lab SampleDEPTH (ft)0 5 10 15 20 (0') SILT with some clay (ML); stiff, moist, reddish orange (3') As Above: medium Stiff, dry (6') As Above: stiff, moist, tan, red and mottled orange (13') As Above: some black, relict structure 0.0 0.7 0.3 VMP-9Shallow VMP-9Deep 0 5 10 15 20 (20') As Above: wet (20') Boring terminated NOTES: Hole precleared to 5.0' on 4/18/19 9:25 by Mid South using hand auger. Shallow screen point installed to 5.5 ft bgs. Deeperscreen point installed to 15 ft bgs. generated using GroundLogs.online Client: Project: Address: Ram Realty RMR-006 S. Tryon Commercial , Mecklenburg,Charlotte, NC WELL LOG Well No. Page: VMP-10 1 of 1 Drilling Start Date: Drilling End Date: Drilling Company: Drilling Method: Drilling Equipment: Driller: Logged By: 4/18/19 10:00 Mid South Direct Push Geoprobe 54 DT Don Warren Shane Sisco Boring Depth (ft): Boring Diameter (in): Sampling Method(s): DTW During Drilling (ft): DTW After Drilling (ft): Top of Casing Elev. (ft): Location (X,Y): 16.0 2.50 Well Depth (ft): Well Diameter (in): Screen Slot (in): Riser Material: Screen Material: Seal Material(s): Filter Pack: Bent. Pellets Sand Pack DEPTH (ft)LITHOLOGYWATER LEVELWELLCOMPLETIONCOLLECT Sample TypeTimeBlow CountsRecovery (ft)SOIL/ROCK VISUAL DESCRIPTION MEASURE PID (ppm)Lab SampleDEPTH (ft)0 5 10 15 20 (0') Lean CLAY with some silt (CL); medium plasticity, very stiff, dry, brown to red (2') As Above: Moist (6') SILT with some clay (ML); medium stiff, moist, reddish (10') As Above: Mottled orange and tan and red (16') Boring terminated 6.7 5.9 0.9 VMP-10Shallow VMP-10Deep 0 5 10 15 20 NOTES: Hole precleared to 5.0' on 4/18/19 10:00 by Mid South using hand auger. Shallow screen point installed to 5.5 ft bgs. Deeperscreen point installed to 15 ft bgs. generated using GroundLogs.online Client: Project: Address: Ram Realty RMR-006 S. Tryon Commercial , Mecklenburg,Charlotte, NC WELL LOG Well No. Page: VMP-11 1 of 1 Drilling Start Date: Drilling End Date: Drilling Company: Drilling Method: Drilling Equipment: Driller: Logged By: 4/18/19 10:30 Mid South Direct Push Geoprobe 54 DT Don Warren Alexis McKenzie Boring Depth (ft): Boring Diameter (in): Sampling Method(s): DTW During Drilling (ft): DTW After Drilling (ft): Top of Casing Elev. (ft): Location (X,Y): 15.0 2.50 Well Depth (ft): Well Diameter (in): Screen Slot (in): Riser Material: Screen Material: Seal Material(s): Filter Pack: Bent. Pellets Sand Pack DEPTH (ft)LITHOLOGYWATER LEVELWELLCOMPLETIONCOLLECT Sample TypeTimeBlow CountsRecovery (ft)SOIL/ROCK VISUAL DESCRIPTION MEASURE PID (ppm)Lab SampleDEPTH (ft)0 5 10 15 20 (0') Lean CLAY with some silt (CL); medium plasticity, very stiff, dry, reddish-brown (2') As Above: stiff and moist (7') As Above: soft and yellow (15') Boring terminated 18.0 31.0 15.4 VMP-11Shallow VMP-11Deep 0 5 10 15 20 NOTES: Hole precleared to 5.0' on 4/18/19 10:30 by Mid South using hand auger. Shallow screen point installed to 5.5 ft bgs. Deeperscreen point installed to 15 ft bgs. generated using GroundLogs.online Client: Project: Address: Ram Realty RMR-006 S. Tryon Commercial , Mecklenburg,Charlotte, NC WELL LOG Well No. Page: VMP-12 1 of 1 Drilling Start Date: Drilling End Date: Drilling Company: Drilling Method: Drilling Equipment: Driller: Logged By: 4/18/19 11:15 Mid South Direct Push Geoprobe 54 DT Don Warren Alexis McKenzie Boring Depth (ft): Boring Diameter (in): Sampling Method(s): DTW During Drilling (ft): DTW After Drilling (ft): Top of Casing Elev. (ft): Location (X,Y): 15.0 2.50 Well Depth (ft): Well Diameter (in): Screen Slot (in): Riser Material: Screen Material: Seal Material(s): Filter Pack: Bent. Pellets Sand Pack DEPTH (ft)LITHOLOGYWATER LEVELWELLCOMPLETIONCOLLECT Sample TypeTimeBlow CountsRecovery (ft)SOIL/ROCK VISUAL DESCRIPTION MEASURE PID (ppm)Lab SampleDEPTH (ft)0 5 10 15 20 (0') Asphalt: former parking lot material (1') Lean CLAY with some silt (CL); medium plasticity, very stiff, dry, reddish-brown (3') As Above: stiff (5') Lean CLAY with some silt (CL); medium plasticity, stiff, moist, reddish-brown (7') As Above: stiff, orange (15') Boring terminated 27.3 30.2 22.4 VMP-12Deep VMP-12Shallow 0 5 10 15 20 Appendix B Laboratory Analytical Report #=CL# April 26, 2019 LIMS USE: FR - RALPH MCGEE LIMS OBJECT ID: 92426138 92426138 Project: Pace Project No.: RE: Ralph McGee Hart & Hickman 2923 S. Tryon St Suite 100 Charlotte, NC 28203 RMR-006 Dear Ralph McGee: Enclosed are the analytical results for sample(s) received by the laboratory on April 19, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Godwin kevin.godwin@pacelabs.com Project Manager 1(704)875-9092 Enclosures cc:Alexis McKenzie, Hart & Hickman REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 18 #=CP# CERTIFICATIONS Pace Project No.: Project: 92426138 RMR-006 Minnesota Certification IDs 1700 Elm Street SE, Minneapolis, MN 55414-2485 A2LA Certification #: 2926.01 Alabama Certification #: 40770 Alaska Contaminated Sites Certification #: 17-009 Alaska DW Certification #: MN00064 Arizona Certification #: AZ0014 Arkansas DW Certification #: MN00064 Arkansas WW Certification #: 88-0680 California Certification #: 2929 CNMI Saipan Certification #: MP0003 Colorado Certification #: MN00064 Connecticut Certification #: PH-0256 EPA Region 8+Wyoming DW Certification #: via MN 027- 053-137 Florida Certification #: E87605 Georgia Certification #: 959 Guam EPA Certification #: MN00064 Hawaii Certification #: MN00064 Idaho Certification #: MN00064 Illinois Certification #: 200011 Indiana Certification #: C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky DW Certification #: 90062 Kentucky WW Certification #: 90062 Louisiana DEQ Certification #: 03086 Louisiana DW Certification #: MN00064 Maine Certification #: MN00064 Maryland Certification #: 322 Massachusetts Certification #: M-MN064 Michigan Certification #: 9909 Minnesota Certification #: 027-053-137 Minnesota Dept of Ag Certifcation #: via MN 027-053-137 Minnesota Petrofund Certification #: 1240 Mississippi Certification #: MN00064 Missouri Certification #: 10100 Montana Certification #: CERT0092 Nebraska Certification #: NE-OS-18-06 Nevada Certification #: MN00064 New Hampshire Certification #: 2081 New Jersey Certification #: MN002 New York Certification #: 11647 North Carolina DW Certification #: 27700 North Carolina WW Certification #: 530 North Dakota Certification #: R-036 Ohio DW Certification #: 41244 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Primary Certification #: MN300001 Oregon Secondary Certification #: MN200001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification #: MN00064 South Carolina Certification #:74003001 Tennessee Certification #: TN02818 Texas Certification #: T104704192 Utah Certification #: MN00064 Vermont Certification #: VT-027053137 Virginia Certification #: 460163 Washington Certification #: C486 West Virginia DEP Certification #: 382 West Virginia DW Certification #: 9952 C Wisconsin Certification #: 999407970 Wyoming UST Certification #: via A2LA 2926.01 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 18 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92426138 RMR-006 Lab ID Sample ID Matrix Date Collected Date Received 92426138001 VMP-8(5.5') #2055 Air 04/18/19 15:33 04/19/19 06:20 92426138002 VMP-8(16') #0873 Air 04/18/19 15:34 04/19/19 06:20 92426138003 VMP-9(5.5') #3391 Air 04/18/19 15:31 04/19/19 06:20 92426138004 VMP-9(16') #1555 Air 04/18/19 15:32 04/19/19 06:20 92426138005 VMP-10(5.5') #3650 Air 04/18/19 15:26 04/19/19 06:20 92426138006 VMP-10(15') #3450 Air 04/18/19 15:27 04/19/19 06:20 92426138007 VMP-11(5.5') #2807 Air 04/18/19 15:30 04/19/19 06:20 92426138008 VMP-11(15') #0186 Air 04/18/19 15:20 04/19/19 06:20 92426138009 VMP-12(5.5') #0618 Air 04/18/19 15:16 04/19/19 06:20 92426138010 VMP-12(15') #1488 Air 04/18/19 15:22 04/19/19 06:20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 18 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92426138 RMR-006 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92426138001 VMP-8(5.5') #2055 TO-15 5 PASI-MNCK 92426138002 VMP-8(16') #0873 TO-15 5 PASI-MNCK 92426138003 VMP-9(5.5') #3391 TO-15 5 PASI-MNCK 92426138004 VMP-9(16') #1555 TO-15 5 PASI-MNCK 92426138005 VMP-10(5.5') #3650 TO-15 5 PASI-MNCK 92426138006 VMP-10(15') #3450 TO-15 5 PASI-MNCK 92426138007 VMP-11(5.5') #2807 TO-15 5 PASI-MNCK 92426138008 VMP-11(15') #0186 TO-15 5 PASI-MNCK 92426138009 VMP-12(5.5') #0618 TO-15 5 PASI-MNCK 92426138010 VMP-12(15') #1488 TO-15 5 PASI-MNCK REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 18 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92426138 RMR-006 Sample:VMP-8(5.5') #2055 Lab ID:92426138001 Collected:04/18/19 15:33 Received:04/19/19 06:20 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15TO15 MSV AIR cis-1,2-Dichloroethene ND ug/m3 04/25/19 22:52 156-59-21.2 0.34 1.55 trans-1,2-Dichloroethene ND ug/m3 04/25/19 22:52 156-60-51.2 0.44 1.55 Tetrachloroethene 1.6 ug/m3 04/25/19 22:52 127-18-41.1 0.49 1.55 Trichloroethene 15.2 ug/m3 04/25/19 22:52 79-01-60.85 0.40 1.55 Vinyl chloride ND ug/m3 04/25/19 22:52 75-01-40.40 0.20 1.55 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 04/26/2019 04:32 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 18 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92426138 RMR-006 Sample:VMP-8(16') #0873 Lab ID:92426138002 Collected:04/18/19 15:34 Received:04/19/19 06:20 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15TO15 MSV AIR cis-1,2-Dichloroethene ND ug/m3 04/25/19 22:24 156-59-21.2 0.34 1.55 trans-1,2-Dichloroethene ND ug/m3 04/25/19 22:24 156-60-51.2 0.44 1.55 Tetrachloroethene 7.0 ug/m3 04/25/19 22:24 127-18-41.1 0.49 1.55 Trichloroethene 85.0 ug/m3 04/25/19 22:24 79-01-60.85 0.40 1.55 Vinyl chloride ND ug/m3 04/25/19 22:24 75-01-40.40 0.20 1.55 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 04/26/2019 04:32 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 18 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92426138 RMR-006 Sample:VMP-9(5.5') #3391 Lab ID:92426138003 Collected:04/18/19 15:31 Received:04/19/19 06:20 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15TO15 MSV AIR cis-1,2-Dichloroethene ND ug/m3 04/25/19 23:21 156-59-21.4 0.37 1.68 trans-1,2-Dichloroethene ND ug/m3 04/25/19 23:21 156-60-51.4 0.48 1.68 Tetrachloroethene 1.3 ug/m3 04/25/19 23:21 127-18-41.2 0.53 1.68 Trichloroethene 6.2 ug/m3 04/25/19 23:21 79-01-60.92 0.43 1.68 Vinyl chloride ND ug/m3 04/25/19 23:21 75-01-40.44 0.21 1.68 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 04/26/2019 04:32 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 18 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92426138 RMR-006 Sample:VMP-9(16') #1555 Lab ID:92426138004 Collected:04/18/19 15:32 Received:04/19/19 06:20 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15TO15 MSV AIR cis-1,2-Dichloroethene ND ug/m3 04/25/19 23:50 156-59-21.2 0.33 1.49 trans-1,2-Dichloroethene ND ug/m3 04/25/19 23:50 156-60-51.2 0.42 1.49 Tetrachloroethene 1.1 ug/m3 04/25/19 23:50 127-18-41.0 0.47 1.49 Trichloroethene 15.4 ug/m3 04/25/19 23:50 79-01-60.81 0.38 1.49 Vinyl chloride ND ug/m3 04/25/19 23:50 75-01-40.39 0.19 1.49 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 04/26/2019 04:32 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 18 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92426138 RMR-006 Sample:VMP-10(5.5') #3650 Lab ID:92426138005 Collected:04/18/19 15:26 Received:04/19/19 06:20 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15TO15 MSV AIR cis-1,2-Dichloroethene ND ug/m3 04/26/19 00:47 156-59-21.3 0.35 1.61 trans-1,2-Dichloroethene ND ug/m3 04/26/19 00:47 156-60-51.3 0.46 1.61 Tetrachloroethene 1.9 ug/m3 04/26/19 00:47 127-18-41.1 0.51 1.61 Trichloroethene ND ug/m3 04/26/19 00:47 79-01-60.88 0.41 1.61 Vinyl chloride ND ug/m3 04/26/19 00:47 75-01-40.42 0.20 1.61 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 04/26/2019 04:32 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 18 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92426138 RMR-006 Sample:VMP-10(15') #3450 Lab ID:92426138006 Collected:04/18/19 15:27 Received:04/19/19 06:20 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15TO15 MSV AIR cis-1,2-Dichloroethene ND ug/m3 04/26/19 01:16 156-59-21.3 0.35 1.58 trans-1,2-Dichloroethene ND ug/m3 04/26/19 01:16 156-60-51.3 0.45 1.58 Tetrachloroethene 130 ug/m3 04/26/19 01:16 127-18-41.1 0.50 1.58 Trichloroethene 32.8 ug/m3 04/26/19 01:16 79-01-60.86 0.41 1.58 Vinyl chloride ND ug/m3 04/26/19 01:16 75-01-40.41 0.20 1.58 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 04/26/2019 04:32 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 18 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92426138 RMR-006 Sample:VMP-11(5.5') #2807 Lab ID:92426138007 Collected:04/18/19 15:30 Received:04/19/19 06:20 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15TO15 MSV AIR cis-1,2-Dichloroethene ND ug/m3 04/26/19 01:45 156-59-21.3 0.35 1.61 trans-1,2-Dichloroethene ND ug/m3 04/26/19 01:45 156-60-51.3 0.46 1.61 Tetrachloroethene ND ug/m3 04/26/19 01:45 127-18-41.1 0.51 1.61 Trichloroethene 0.68J ug/m3 04/26/19 01:45 79-01-60.88 0.41 1.61 Vinyl chloride ND ug/m3 04/26/19 01:45 75-01-40.42 0.20 1.61 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 04/26/2019 04:32 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 18 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92426138 RMR-006 Sample:VMP-11(15') #0186 Lab ID:92426138008 Collected:04/18/19 15:20 Received:04/19/19 06:20 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15TO15 MSV AIR cis-1,2-Dichloroethene ND ug/m3 04/26/19 02:14 156-59-21.3 0.36 1.64 trans-1,2-Dichloroethene ND ug/m3 04/26/19 02:14 156-60-51.3 0.47 1.64 Tetrachloroethene 11.9 ug/m3 04/26/19 02:14 127-18-41.1 0.51 1.64 Trichloroethene 140 ug/m3 04/26/19 02:14 79-01-60.90 0.42 1.64 Vinyl chloride ND ug/m3 04/26/19 02:14 75-01-40.43 0.21 1.64 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 04/26/2019 04:32 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 18 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92426138 RMR-006 Sample:VMP-12(5.5') #0618 Lab ID:92426138009 Collected:04/18/19 15:16 Received:04/19/19 06:20 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15TO15 MSV AIR cis-1,2-Dichloroethene ND ug/m3 04/26/19 02:42 156-59-21.3 0.36 1.64 trans-1,2-Dichloroethene ND ug/m3 04/26/19 02:42 156-60-51.3 0.47 1.64 Tetrachloroethene ND ug/m3 04/26/19 02:42 127-18-41.1 0.51 1.64 Trichloroethene 1.4 ug/m3 04/26/19 02:42 79-01-60.90 0.42 1.64 Vinyl chloride ND ug/m3 04/26/19 02:42 75-01-40.43 0.21 1.64 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 04/26/2019 04:32 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 18 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92426138 RMR-006 Sample:VMP-12(15') #1488 Lab ID:92426138010 Collected:04/18/19 15:22 Received:04/19/19 06:20 Matrix:Air Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: TO-15TO15 MSV AIR cis-1,2-Dichloroethene ND ug/m3 04/26/19 03:11 156-59-21.2 0.34 1.55 trans-1,2-Dichloroethene ND ug/m3 04/26/19 03:11 156-60-51.2 0.44 1.55 Tetrachloroethene 2.7 ug/m3 04/26/19 03:11 127-18-41.1 0.49 1.55 Trichloroethene 114 ug/m3 04/26/19 03:11 79-01-60.85 0.40 1.55 Vinyl chloride ND ug/m3 04/26/19 03:11 75-01-40.40 0.20 1.55 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 04/26/2019 04:32 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 18 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92426138 RMR-006 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 601882 TO-15 TO-15 TO15 MSV AIR Low Level Associated Lab Samples:92426138001, 92426138002, 92426138003, 92426138004, 92426138005, 92426138006, 92426138007, 92426138008, 92426138009, 92426138010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3253341 Associated Lab Samples:92426138001, 92426138002, 92426138003, 92426138004, 92426138005, 92426138006, 92426138007, 92426138008, 92426138009, 92426138010 Matrix:Air AnalyzedMDL cis-1,2-Dichloroethene ug/m3 ND 0.81 04/25/19 18:330.22 Tetrachloroethene ug/m3 ND 0.69 04/25/19 18:330.31 trans-1,2-Dichloroethene ug/m3 ND 0.81 04/25/19 18:330.28 Trichloroethene ug/m3 ND 0.55 04/25/19 18:330.26 Vinyl chloride ug/m3 ND 0.26 04/25/19 18:330.13 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3253342LABORATORY CONTROL SAMPLE: LCSSpike cis-1,2-Dichloroethene ug/m3 42.340.3 105 70-130 Tetrachloroethene ug/m3 72.868.9 106 70-130 trans-1,2-Dichloroethene ug/m3 49.840.3 123 70-130 Trichloroethene ug/m3 53.854.6 99 70-130 Vinyl chloride ug/m3 25.126 97 70-130 Parameter Units Dup Result Max RPD QualifiersRPDResult 92426138004 3253980SAMPLE DUPLICATE: cis-1,2-Dichloroethene ug/m3 ND 25ND Tetrachloroethene ug/m3 1.0J 251.1 trans-1,2-Dichloroethene ug/m3 ND 25ND Trichloroethene ug/m3 15.4 0 2515.4 Vinyl chloride ug/m3 ND 25ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 04/26/2019 04:32 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 18 #=QL# QUALIFIERS Pace Project No.: Project: 92426138 RMR-006 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - MinneapolisPASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 04/26/2019 04:32 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 18 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92426138 RMR-006 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92426138001 601882VMP-8(5.5') #2055 TO-15 92426138002 601882VMP-8(16') #0873 TO-15 92426138003 601882VMP-9(5.5') #3391 TO-15 92426138004 601882VMP-9(16') #1555 TO-15 92426138005 601882VMP-10(5.5') #3650 TO-15 92426138006 601882VMP-10(15') #3450 TO-15 92426138007 601882VMP-11(5.5') #2807 TO-15 92426138008 601882VMP-11(15') #0186 TO-15 92426138009 601882VMP-12(5.5') #0618 TO-15 92426138010 601882VMP-12(15') #1488 TO-15 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 04/26/2019 04:32 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 18 Page 18 of 18 Appendix C DEQ Risk Calculators (February 2018) North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 5/1/2019 Prepared By:Alexis McKenzie Ralph McGee Worst Case - Deep Soil Gas North Carolina Department of Environmental Quality Risk Calculator RMR-006 South Tryon Commerical Department of Waste Management Brownfields Program 22007-18-060 February 2018 November 2017 EPA RSL Table North Carolina DEQ Risk Calculator Table of Contents Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 22007-18-060 Exposure Unit ID: Worst Case - Deep Soil Gas Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Surface Soil Exposure Point Concentration Table Input Form 2B Subsurface Soil Exposure Point Concentration Table Input Form 2C Groundwater Exposure Point Concentration Table Input Form 2D Surface Water Exposure Point Concentration Table Input Form 2E Soil Gas Exposure Point Concentration Table Input Form 2F Indoor Air Exposure Point Concentration Table Output Form 1A Summary of Risk Assessment Output Output Form 2A Resident Soil Combined Pathways Output Form 2B Resident Groundwater Combined Pathways Output Form 2C Non-Residential Worker Soil Combined Pathways Output Form 2D Non-Residential Worker Groundwater Combined Pathways Output Form 2E Construction Worker Soil Combined Pathways Output Form 2F User Defined Soil Combined Pathways Output Form 2G User Defined Surface Water Combined Pathways Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil Source to Groundwater POE - Forward Mode Output Form 4B Groundwater Source to Groundwater POE - Forward Mode Output Form 4C Soil Source to Surface Water POE - Forward Mode Output Form 4D Groundwater Source to Surface Water POE - Forward Mode Output Form 4E Soil Source to Groundwater POE - Backward Mode Output Form 4F Groundwater Source to Groundwater POE - Backward Mode Output Form 4G Soil Source to Surface Water POE - Backward Mode Output Form 4H Groundwater Source to Surface Water POE - Backward Mode Output Section 4 - Contaminant Migration to Point of Exposure (POE) Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Primary Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 22007-18-060 Exposure Unit ID: Worst Case - Deep Soil Gas Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Combined Pathways Groundwater Combined Pathways Soil Combined Pathways Groundwater Combined Pathways Construction Worker Soil Combined Pathways Soil Combined Pathways Surface Water Combined Pathways Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS PRIMARY PATHWAYS Resident Non-Residential Worker User Defined Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Protection of Groundwater Use Protection of Surface Water North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 22007-18-060 Exposure Unit ID: Worst Case - Deep Soil Gas Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Justification for Exposure Point Concentration CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 130 127-18-4 Tetrachloroethylene ug/m3 140 79-01-6 Trichloroethylene ug/m3 Input Form 2E Soil Gas Exposure Point Concentration Table North Carolina DEQ Risk Calculator Summary of Risk Assessment Output Output Form 1A Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 22007-18-060 Exposure Unit ID: Worst Case - Deep Soil Gas Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil Combined Pathways NC NC NC Groundwater Combined Pathways*NC NC NC Soil Combined Pathways NC NC NC Groundwater Combined Pathways*NC NC NC Construction Worker Soil Combined Pathways NC NC NC Soil Combined Pathways NC NC NC Surface Water Combined Pathways*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 5.0E-07 1.7E-01 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC PRIMARY CALCULATORS Resident Non-Residential Worker User Defined 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Protection of Surface Water Exceedence of 2B at POE? Exceedence of 2B at POE? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target POE Concentrations Exceeded? Protection of Groundwater Use Exceedence of 2L at POE? Exceedence of 2L at POE? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 22007-18-060 Exposure Unit ID: Worst Case - Deep Soil Gas CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 127-18-4 Tetrachloroethylene 130 1.3 4.7E+01 3.5E+01 2.8E-08 7.4E-03 79-01-6 Trichloroethylene 140 1.4 3.0E+00 1.8E+00 4.7E-07 1.6E-01 Cumulative:5.0E-07 1.7E-01 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Worst Case - Shallow Soil Gas North Carolina Department of Environmental Quality Risk Calculator RMR-006 South Tryon Commerical Department of Waste Management Brownfields Program 22007-18-060 February 2018 November 2017 EPA RSL Table 5/1/2019 Prepared By:Alexis McKenzie Ralph McGee North Carolina DEQ Risk Calculator Table of Contents Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 22007-18-060 Exposure Unit ID: Worst Case - Shallow Soil Gas Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Surface Soil Exposure Point Concentration Table Input Form 2B Subsurface Soil Exposure Point Concentration Table Input Form 2C Groundwater Exposure Point Concentration Table Input Form 2D Surface Water Exposure Point Concentration Table Input Form 2E Soil Gas Exposure Point Concentration Table Input Form 2F Indoor Air Exposure Point Concentration Table Output Form 1A Summary of Risk Assessment Output Output Form 2A Resident Soil Combined Pathways Output Form 2B Resident Groundwater Combined Pathways Output Form 2C Non-Residential Worker Soil Combined Pathways Output Form 2D Non-Residential Worker Groundwater Combined Pathways Output Form 2E Construction Worker Soil Combined Pathways Output Form 2F User Defined Soil Combined Pathways Output Form 2G User Defined Surface Water Combined Pathways Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil Source to Groundwater POE - Forward Mode Output Form 4B Groundwater Source to Groundwater POE - Forward Mode Output Form 4C Soil Source to Surface Water POE - Forward Mode Output Form 4D Groundwater Source to Surface Water POE - Forward Mode Output Form 4E Soil Source to Groundwater POE - Backward Mode Output Form 4F Groundwater Source to Groundwater POE - Backward Mode Output Form 4G Soil Source to Surface Water POE - Backward Mode Output Form 4H Groundwater Source to Surface Water POE - Backward Mode Output Section 4 - Contaminant Migration to Point of Exposure (POE) Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Primary Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 22007-18-060 Exposure Unit ID: Worst Case - Shallow Soil Gas Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Combined Pathways Groundwater Combined Pathways Soil Combined Pathways Groundwater Combined Pathways Construction Worker Soil Combined Pathways Soil Combined Pathways Surface Water Combined Pathways Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Protection of Groundwater Use Protection of Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS PRIMARY PATHWAYS Resident Non-Residential Worker User Defined North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 22007-18-060 Exposure Unit ID: Worst Case - Shallow Soil Gas Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Justification for Exposure Point Concentration CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 1.9 127-18-4 Tetrachloroethylene ug/m3 15.2 79-01-6 Trichloroethylene ug/m3 Input Form 2E Soil Gas Exposure Point Concentration Table North Carolina DEQ Risk Calculator Summary of Risk Assessment Output Output Form 1A Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 22007-18-060 Exposure Unit ID: Worst Case - Shallow Soil Gas Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil Combined Pathways NC NC NC Groundwater Combined Pathways*NC NC NC Soil Combined Pathways NC NC NC Groundwater Combined Pathways*NC NC NC Construction Worker Soil Combined Pathways NC NC NC Soil Combined Pathways NC NC NC Surface Water Combined Pathways*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 5.1E-08 1.7E-02 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Protection of Surface Water Exceedence of 2B at POE? Exceedence of 2B at POE? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target POE Concentrations Exceeded? Protection of Groundwater Use Exceedence of 2L at POE? Exceedence of 2L at POE? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: PRIMARY CALCULATORS Resident Non-Residential Worker User Defined North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 22007-18-060 Exposure Unit ID: Worst Case - Shallow Soil Gas CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 127-18-4 Tetrachloroethylene 1.9 0.019 4.7E+01 3.5E+01 4.0E-10 1.1E-04 79-01-6 Trichloroethylene 15.2 0.152 3.0E+00 1.8E+00 5.1E-08 1.7E-02 Cumulative:5.1E-08 1.7E-02 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 5/1/2019 Prepared By:Alexis McKenzie Ralph McGee Worst Case - Shallow/Deep Soil Gas North Carolina Department of Environmental Quality Risk Calculator RMR-006 South Tryon Commerical Department of Waste Management Brownfields Program 22007-18-060 February 2018 November 2017 EPA RSL Table North Carolina DEQ Risk Calculator Table of Contents Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 22007-18-060 Exposure Unit ID: Worst Case - Shallow/Deep Soil Gas Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Surface Soil Exposure Point Concentration Table Input Form 2B Subsurface Soil Exposure Point Concentration Table Input Form 2C Groundwater Exposure Point Concentration Table Input Form 2D Surface Water Exposure Point Concentration Table Input Form 2E Soil Gas Exposure Point Concentration Table Input Form 2F Indoor Air Exposure Point Concentration Table Output Form 1A Summary of Risk Assessment Output Output Form 2A Resident Soil Combined Pathways Output Form 2B Resident Groundwater Combined Pathways Output Form 2C Non-Residential Worker Soil Combined Pathways Output Form 2D Non-Residential Worker Groundwater Combined Pathways Output Form 2E Construction Worker Soil Combined Pathways Output Form 2F User Defined Soil Combined Pathways Output Form 2G User Defined Surface Water Combined Pathways Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil Source to Groundwater POE - Forward Mode Output Form 4B Groundwater Source to Groundwater POE - Forward Mode Output Form 4C Soil Source to Surface Water POE - Forward Mode Output Form 4D Groundwater Source to Surface Water POE - Forward Mode Output Form 4E Soil Source to Groundwater POE - Backward Mode Output Form 4F Groundwater Source to Groundwater POE - Backward Mode Output Form 4G Soil Source to Surface Water POE - Backward Mode Output Form 4H Groundwater Source to Surface Water POE - Backward Mode Output Section 4 - Contaminant Migration to Point of Exposure (POE) Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Primary Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 22007-18-060 Exposure Unit ID: Worst Case - Shallow/Deep Soil Gas Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Combined Pathways Groundwater Combined Pathways Soil Combined Pathways Groundwater Combined Pathways Construction Worker Soil Combined Pathways Soil Combined Pathways Surface Water Combined Pathways Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS PRIMARY PATHWAYS Resident Non-Residential Worker User Defined Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Protection of Groundwater Use Protection of Surface Water North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 22007-18-060 Exposure Unit ID: Worst Case - Shallow/Deep Soil Gas Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Justification for Exposure Point Concentration CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 130 127-18-4 Tetrachloroethylene ug/m3 140 79-01-6 Trichloroethylene ug/m3 Input Form 2E Soil Gas Exposure Point Concentration Table North Carolina DEQ Risk Calculator Summary of Risk Assessment Output Output Form 1A Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 22007-18-060 Exposure Unit ID: Worst Case - Shallow/Deep Soil Gas Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil Combined Pathways NC NC NC Groundwater Combined Pathways*NC NC NC Soil Combined Pathways NC NC NC Groundwater Combined Pathways*NC NC NC Construction Worker Soil Combined Pathways NC NC NC Soil Combined Pathways NC NC NC Surface Water Combined Pathways*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 5.0E-07 1.7E-01 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC PRIMARY CALCULATORS Resident Non-Residential Worker User Defined 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Protection of Surface Water Exceedence of 2B at POE? Exceedence of 2B at POE? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target POE Concentrations Exceeded? Protection of Groundwater Use Exceedence of 2L at POE? Exceedence of 2L at POE? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: February 2018 Basis: November 2017 EPA RSL Table Site ID: 22007-18-060 Exposure Unit ID: Worst Case - Shallow/Deep Soil Gas CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 127-18-4 Tetrachloroethylene 130 1.3 4.7E+01 3.5E+01 2.8E-08 7.4E-03 79-01-6 Trichloroethylene 140 1.4 3.0E+00 1.8E+00 4.7E-07 1.6E-01 Cumulative:5.0E-07 1.7E-01 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.