20037_Highland Mill#3_VMS Installation and Pre-Occupancy Sampling Report Unit 11_20190424

SUMMIT Engineering, Laboratory & Testing, P.C. 3575 Centre Circle Fort Mill, South Carolina 29715 www.SUMMIT-companies.com Phone: [phone] Fax: [phone]
April 24, 2019
Ms. Joselyn Harriger, P.G. North Carolina Department of Environmental Quality Brownfields Program 610 E. Center Avenue Mooresville, NC 28115
Subject: Vapor Mitigation System Installation and Pre-Occupancy Report
Unit 11 Highland Mill Townhomes Highland Mill #3 2767 N. Brevard Street Charlotte, Mecklenburg County, North Carolina SUMMIT Project No. 1820.59
Brownfields Project Number 20037-16-060
Dear Ms. Harriger:
SUMMIT ENGINEERING, LABORATORY & TESTING, P.C . (SUMMIT) is pleased to submit this
report summarizing vapor mitigation system installation, testing, inspections and pre-occupancy
testing and sampling activities conducted at the residential townhome Unit 11 of the Highland Mill Townhomes development at the Highland Mill #3 Brownfields site, located in the northwestern quadrant of the intersection of North Davidson and North Brevard Streets, Charlotte, Mecklenburg County, North Carolina.
If you have any questions regarding our assessment of the subject property or our conclusions, please
do not hesitate to call us at [phone].
Sincerely, SUMMIT
Michael D. Zavislak, NRCC-EAC, CHMM, CIH, PE SUMMIT’s North Carolina Engineering Firm License C-4391

VAPOR MITIGATION INSTALLATION INSPECTIONS, PRE-OCCUPANCY TESTING & SAMPLING REPORT
UNIT 11 HIGHLAND MILL TOWNHOMES HIGHLAND MILL #3 CHARLOTTE MECKLENBURG COUNTY NORTH CAROLINA
BROWNFIELDS PROJECT NO. 20037-16-060 SUMMIT PROJECT NO. 1820.59
Prepared For: North Carolina Department of Environmental Quality Brownfields Program 610 E. Center Avenue
Mooresville, NC 28115
Prepared By: SUMMIT ENGINEERING, LABORATORY & TESTING, P.C.
3575 Centre Circle Fort Mill, South Carolina 29715 704-504-1717
April 24, 2019
VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59
Charlotte, North Carolina April 24, 2019

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TABLE OF CONTENTS
1.0 INTRODUCTION .................................................................................................................... 1
1.1. PURPOSE .......................................................................................................................................... 1
1.2. PROJECT OVERVIEW..................................................................................................................... 1
1.3. TOWNHOME UNIT OVERVIEW ................................................................................................... 2
2.0 VAPOR MITIGATION SYSTEM INSTALLATION AND TESTING .................................. 3
2.1. VMS OVERVIEW ............................................................................................................................. 3
2.2. INSPECTIONS .................................................................................................................................. 3
2.3. STONE BASE .................................................................................................................................... 4
2.4. SUB-SLAB VAPOR EXTRACTION LINES ................................................................................... 4
2.5. PRESSURE MONITORING POINTS ............................................................................................. 5
2.6. VAPOR BARRIER INSTALLATION .............................................................................................. 5
2.7. SYSTEM TESTING .......................................................................................................................... 6
2.8. SYSTEM IDENTIFICATION ........................................................................................................... 7
2.9. SYSTEM ALARMS .......................................................................................................................... 8
3.0 PRE-OCCUPANCY SAMPLING ............................................................................................ 9
3.1. OVERVIEW ....................................................................................................................................... 9
3.2. EXTERIOR SOIL GAS SAMPLING ............................................................................................... 9
3.3. SOIL GAS SAMPLING RESULTS ................................................................................................ 11
3.4. INDOOR & AMBIENT AIR SAMPLING ..................................................................................... 12
3.5. POTENTIAL CONTAMINANT SOURCES ................................................................................. 13
3.6. AMBIENT AIR SAMPLING RESULTS ........................................................................................ 14
3.7. RISK ASSESSMENT ...................................................................................................................... 14
4.0 FINDINGS AND CONCLUSIONS ....................................................................................... 16
5.0 RECOMMENDATIONS ........................................................................................................ 18

APPENDICES
Appendix I: FIGURES
Appendix II: PHOTOGRAPH LOGS Appendix III: VMS FIELD INSPECTION LOGS Appendix IV: SAMPLE DATA TABLES
Appendix V: LABORATORY REPORTS Appendix VI: RISK CALCULATOR Appendix VII: SAMPLE COLLECTION LOGS/FIELD REPORTS
Appendix VIII: POTENTIAL CONTAMINANT SOURCES / SDS Appendix IX: VMS ALARM Appendix X: DRAGO SEALANT
VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59
Charlotte, North Carolina April 24, 2019

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1.0 INTRODUCTION

1.1. PURPOSE

On behalf of CCH-Highland Mill, LLC, SUMMIT prepared this report summarizing vapor
mitigation system installation inspections and pre-occupancy testing and sampling activities
conducted for residential townhome Unit 11 of the Highland Mill Townhomes development at the
Highland Mill #3 Brownfields site, located in the northwestern quadrant of the intersection of North
Davidson and North Brevard Streets, Charlotte, Mecklenburg County, North Carolina. SUMMIT
performed inspections, testing and pre-occupancy sampling activities outlined in the approved
October 13, 2017 Vapor Mitigation Plan. Pre-occupancy sampling was conducted for the following
residential townhome unit:

Townhome Physical Address Townhome
Unit #
Proposed Occupancy
Date *
2817 N. Brevard Street 11 May
*- approximate date pending DEQ approval of this report.

Additional VMP inspection and testing certifications as well as additional pre-occupancy sampling
will be conducted for the remaining units in accordance with the approved VMP.

1.2. PROJECT OVERVIEW

The development of the subject site includes the construction of fifteen (15) townhome units. The
units are multi-story, wood framed townhomes constructed on slab on grade foundations. Previous
environmental assessments documented soil impacts from SVOC continents, soil gas and
groundwater impacts by VOC constituents. Based on known groundwater impacts originating
from an upgradient off-site source, SUMMIT proposed an active sub-slab depressurization vapor
mitigation system be utilized in development of the site. SUMMIT initially submitted a Vapor
Mitigation Plan (VMP) dated June 12, 2017 and received DEQ approval on June 26, 2017. Based
VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59
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on foundation design conflicts with the June VMP, a revision to the VMP was required. A revised
VMP was submitted on October 13, 2017 and received DEQ approval on October 13, 2017.

1.3. TOWNHOME UNIT OVERVIEW

The development of the subject site includes the construction of fifteen (15) townhome units. The
units are multi-story, wood framed townhomes constructed on slab on grade foundations. The
townhome units are constructed on a split-level foundation with the upper slab portion being
utilized as a garage space and the lower slab area as a 400 SF living space. The lower slab portions
of the units are located on the southern elevation of all units, facing N. Brevard Street with the
upper garage slab located along the northern elevation of the building.

VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59
Charlotte, North Carolina April 24, 2019

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2.0 VAPOR MITIGATION SYSTEM INSTALLATION AND TESTING

2.1. VMS OVERVIEW

The PD proposed to develop the townhome buildings utilizing a vapor barrier system and sub-slab
depressurization system. One (1) system per unit for a total of fifteen (15) individual systems are
utilized for this development. All sub-slab components of the system were installed by concrete and
waterproofing subcontractors (Doggett). The VMP specified vapor mitigation system consisted of:

• 6 inches of washed stone sub-slab
• Vapor extraction lines installed in stone base layer sub-slab and connected to a vertical riser
• Six (6) pressure monitoring points installed in upper 1 inch of stone base layer
• 10-mil vapor barrier membrane film base layer (Stego Wrap Class A)
• Active fan system (Fantech HP220)
• Installation of two (2) exterior soil gas monitoring points to depths of 6 feet below ground
surface (2 ft below lower slab elevations) in accordance with DEQ guidance documents.

The SUMMIT provided QA/QC to include field inspections to measure thickness of stone base,
placement of extraction lines, placement and construction of pressure monitoring points, placement
of vapor barrier and activation of fan units. Photographs of unit inspections are included in Appendix
II of this Inspection Report.

2.2. INSPECTIONS

Initial construction activities to include grading of the site started in December 2017. Each of the 15
townhome units being built was constructed utilizing a poured wall footing foundation separating
each townhome unit. Based on the foundation design, each unit required a sub-slab vapor mitigation
system (VMS). VMS installation inspections were conducted between February 28, 2018 and July
3, 2018. Inspections were performed on multiple units as they became available for review.

VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59
Charlotte, North Carolina April 24, 2019

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Inspections were completed to include the following:
• Confirm thickness of stone base prior to installation of vapor mitigation extraction piping.
• Confirm installation of extraction piping.
• Confirm thickness of stone base following installation of vapor mitigation extraction
piping.
• Confirm proper installation of permanent pressure monitoring and sub-slab soil gas
sampling points prior to vapor barrier installation.
• Confirm installation of vapor barrier, supervised by a Professional Engineer.
• Confirm installation of riser and fan.
• Confirm installation of VMS signage.

2.3. STONE BASE

Stone base thickness was measured in the field by Patrick Lowery, P.G. and Michael Zavislak, P.E.
The stone material was inspected and appeared in conformance to the VMP specifications of
aggregate equal to or larger than the following: 100% passing a 2-inch grate; 90 to 100% passing a 1-
1/2-inch grate; 20-55% passing a 1-inch grate; 0-15% passing a ¾ inch grate; and 0-5% passing a 3/8-
inch grate. Stone appeared washed and generally clear of fines. Stone thickness was measured at 6
inches across all prepared surfaces of Unit 11.

2.4. SUB-SLAB VAPOR EXTRACTION LINES

Horizontal sub-slab vapor extraction lines were planned for installation in each unit. For this
development, the townhome units were split level, with a lower floor situated along N. Brevard Street
(front of townhome) and an upper level utilized as a garage on the northern side of the development.
Each level is comprised of two (2) 2-inch PVC perforated extraction lines connected to 3-inch
collector lines from the 4-inch vertical riser. All joints shall be sealed with solvent free glue or taped
to ensure proper seal.

VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59
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Extraction line inspections were completed by Patrick Lowery, P.G. and Michael Zavislak, P.E. Initial
inspections began on March 8, 2018 and continued through 2018 as units were ready for inspection.
The extraction lines were installed within the stone base material at approximately 3 inches above
grade and 3 inches below slab in all units. The extraction lines were installed in the proper locations
as outlined in the VMP specification for Unit 11. Photographs of the systems are included in
Appendix II of this report.

2.5. PRESSURE MONITORING POINTS

The vapor mitigation system included the installation of six (6) sub-slab pressure monitoring points.
Pressure monitoring points were installed so that a pressure reading can be made from an observation
point located along the exterior of the structure. At each location ¼ inch Tygon tubing was extended
within 1-inch conduit piping from the exterior observation point to the predetermined pressure
monitoring point in each extraction system. Pressure monitoring points are located in Unit 5, Unit 8,
Unit 10, Unit 13 and Unit 15. Pressure monitoring point locations are outline in Figure 1 in Appendix
I of this report. SUMMIT verified the pressure monitoring point locations in Unit 10 (garage) and
Unit 8 (lower living space), the installation of the conduit, tubing and installation in the upper 1 inch
of stone base beneath the planned slab. Inspections started on March 8, 2018 and continued through
2018 as units were made available for inspection.

2.6. VAPOR BARRIER INSTALLATION

The vapor mitigation plan specified the use of a minimum 10 mil Stego™ Wrap Class A Vapor Barrier
membrane. The VMP details the methods for installation, taping seams, overlap distances and
penetration seals. Vapor Barrier inspections were completed by Patrick Lowery, P.G. and Michael
Zavislak, P.E. Initial inspections began on March 8, 2018 can continued through 2018 as units were
made available for inspection. The use of 10-mil Stego™ Wrap Class A Vapor Barrier was confirmed.
Photographs of completed vapor barriers for Unit 11 from the April 4, 2018 inspection are included
in Appendix II of this report. Minor repairs and patches were required during subsequent inspections.
Prior to slab pour, all vapor barriers passed inspections completed by SUMMIT.
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2.7. SYSTEM TESTING

On February 26, 2019 SUMMIT conducted pilot testing of the sub-slab VMS of townhome 8, 9, 10,
11 and 12 verify the active fan and VMS were providing sufficient vacuum influence. The pilot
testing completed varied from the approved VMP procedure of pilot testing prior to installation of the
concrete slab foundations. Due to unknown complications to the construction schedules, the lower
slab portions of the VMS could not be installed and tested at the same time as the upper slabs which
were scheduled to be installed in advance of all lower slabs. Therefore, all pilot testing was conducted
after the concrete slabs were installed for both the upper and lower slab elevations of each unit.
Pressure readings were recorded from the two (2) installed permanent pressure monitoring points
installed at predetermined locations beneath the upper and lower slab on grade foundations. The
pressure points were installed utilizing conduit and tubing allowing for measurement to be obtained
from the exterior of the Townhome units. At the time of pilot testing the inline fan units were
installed, therefore the FanTech HP220 fan was utilized for the pilot testing. Prior to turning the fans
on, vacuum measurements were collected at each pressure measuring point to establish baseline
conditions. After baseline conditions were recorded, fans were turned on. A Dwyer series 475 Mark
III Digital Manometer or a TSI 9565 VelociCalc Multifunction Ventilation Meter (capable of
measuring to 0.001 inches of water column (in-WC) or 0.25 Pascals [Pa]) was connected to each
pressure measuring port via Teflon tubing to record differential pressures. Vacuum measurements
were collected from each monitoring point over an approximately 30-minute period.

Following Occupancy Sampling conducted December 30, 2018 with respect to Units 15, 14 and 13,
SUMMIT re-inspected all Units for indications of pressure leaks associated with the system risers,
slab penetrations or slab joints. Indications of a potential leak point was observed in Units 15, 14 and
13 associated with a bath drain. Therefore, SUMMIT made the recommendation to the contractor to
seal all penetrations using Drago Sealant. On January 11, 2019 the slab penetrations were cleaned of
debris and sealed using Drago Sealant 2-Part Epoxy. Photographs are included in the Photograph
Log located in Appendix II of this report.

VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59
Charlotte, North Carolina April 24, 2019

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VMS Performance logs summarizing differential pressure measurements at each pressure monitoring
point during the February 26, 2018 testing are provided in Appendix III of this report. Locations of
the pressure monitoring points are detailed on Figure 1 in Appendix I of this report.

Minimum and maximum vacuum measurements recorded at each pressure monitoring point and riser
tests are summarized below:

Date Unit Low Reading High Reading Temp. Riser CFM Wind Relative Humidity
2/26/19 10 -0.55 -0.60 51 F 76 8mph NW 55% 2/26/19 08 -0.37 -0.38 55 F 86 8mph NW

Riser air flow velocity and differential pressure was measured using a VelociCalc Multifunction
meter. Air flow was measured between 76 and 86 CFM on the tested systems. Differential pressure
in the riser was measured at 1.8 and 1.9 in W.C. Differential pressures measured at the permanent
monitoring points are above the -0.02 in-WC outlined in the VMP and above the 4 pascals (-0.016 in
WC) outlined in DMW Vapor Intrusion guidance.

During previous inspection of the units, SUMMIT learned that the foundation system for each unit
includes a foundation drain installed at the base of the split wall beneath the upper garage portion of
each unit. The foundation drains are connected to the stormdrain system leading off-site. SUMMIT
concludes that the drain system is likely reducing the systems pressures as the vacuum is lost through
the open piping beneath the slab however adequate pressures have been maintained and no action is
recommended.

2.8. SYSTEM IDENTIFICATION

SUMMIT confirmed that visible and accessible areas of the system riser were labeled with yellow
and black stenciling with “Soil Vapor Mitigation System”.

VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59
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2.9. SYSTEM ALARMS

System alarms consisting of a Dwyer Series 1800 Low Differential Pressure Switch, visible indicator
light (Dayton 22NY60 or equivalent) and system label are installed in all units of the townhome
development. The pressure switch is installed below the fan unit on the riser pipe with the indicator
light installed in the Laundry Room/Master Closets above the light switch plate. A label reading
“VAPOR MITIGATION SYSTEM ALARM - IF LIGHT IS ILLUMINATED, CONTACT HOA” is
installed beneath each alarm light. The system alarms were tested on March 28, 2019 by removing
power to the fan system. The installed lights illuminated as needed when the riser pressures dropped
below 1.0 inches WC. Specifications for the alarm system is included in Appendix IX of this report.
VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59
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3.0 PRE-OCCUPANCY SAMPLING

3.1. OVERVIEW

Occupancy sampling was conducted in accordance with the approved VMP and utilizing Division of
Waste Management Vapor Intrusion Guidance (VIG) and Inactive Hazardous Site Branch (IHSB)
guidance. Occupancy sampling was restricted to Unit 11. Unit 11 was sampled during the February
28, 2019 sampling event which included Units 8-12. Unit 11 was sampled with duplicate sample
during the February 28, 2019 sampling event. Results between sample U11-1 and U11-1-Dup of that
sampling event indicated a quality control concern with the duplicate analysis differing in results from
that of the sample U11-1. Additionally, it was noted that the duplicate sample was received by the
laboratory with less pressure in the sample canister than recorded in the field at termination of the
sampling event indicating a potential leak in the sampling device. SUMMIT recommended retesting
of Unit 11 to insure proper analysis and QA/QC. On March 28, 2019 Unit 11 was retested in
accordance with eth approved VMP. Two (2) exterior soil gas sampling points were sampled
concurrently with the collection of indoor ambient air samples for this occupancy sampling event.
Exterior soil gas samples were collected and analyzed for the presence of compounds previously
detected in soil gas assessments by TO-15 while the indoor air and ambient air samples were collected
and analyzed for the presence of Tetrachloroethylene (PCE) and daughter products (trichloroethylene,
1,1-dichloroethylene, cis-1,2-dichloroethylene, trans-1,2-dichloroethylene and vinyl chloride) by TO-
15. One (1) duplicate sample was collected for each media for each sampling event. Locations of
the collected samples can be viewed on Figure 1 in Appendix I of this report.

The occupancy sampling for Unit 11 was conducted on March 28th, 2019. Pace Analytical and
ConTest Analytical Laboratory provided laboratory analysis of the collected samples.

3.2. EXTERIOR SOIL GAS SAMPLING

As outlined in the VMP, two (2) soil gas sampling points were required to monitor soil gas
concentrations at locations adjacent to the townhome development. On December 5, 2018 SUMMIT
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personnel mobilized to the subject site and installed the two (2) soil gas sample points. The locations
of the soil gas sampling points are detailed in Figure 1 in Appendix I of this report. The soil gas
sample locations were installed by Patrick Lowery, P.G. in accordance with Division of Waste
Management Vapor Intrusion Guidance (VIG) and Inactive Hazardous Site Branch (IHSB) guidance.
At the time of installation, temporary surface protection was provided. Permanent surface protection
will be installed once final grade of landscaping is achieved.

Prior to sample collection, a leak test was performed on each soil gas sampling point by placing a
shroud around the point, saturating the air within the shroud with helium gas, then purging soil gas
from the sampling point with a GilAir-5 vacuum pump into a Tedlar® bag. A Dielectric MGD 2002
helium gas detector was used to measure helium concentrations in the shroud and bag. The leak test
was considered successful if the helium concentration measured in the soil gas purged from the
sampling point was less than 10% of the concentration measured in the shroud. Following a passing
leak test, soil gas samples were collected in laboratory prepared 1 Litter Summa Canisters and 100-
ml per minute regulators. Collected soil gas samples were analyzed by EPA Method TO-15 for the
presence of all compounds previously detected in the soil gas sampling and vinyl chloride by ConTest
Analytical Laboratory and Pace Analytical. Canister vacuum readings never reached 0 and were
received by the laboratory at similar vacuum psi readings as reported at the end of the sampling event
with the exception of HMSG-1 Duplicate which was received with a pressure of zero (0). Soil gas
sampling was conducted concurrently during indoor and ambient air occupancy sampling. A copy of
sampling forms for each sampling event are included in Appendix VII of this report. A summary of
sampling event data is provided below:

Date Sample IDs Pass Leak Test Maint. Pressure Weather Conditions 12/7/18 HMSG-1*, HMSG-2 Yes Yes 45 F Overcast
12/30/18 HMSG-1*, HMSG-2 Yes Yes 40 F Rain
1/13/19 HMSG-1*, HMSG-2 Yes Yes 39 F clear
1/30/19 HMSG-1*, HMSG-2 Yes Yes 40.5 F clear
2/28/19 HMSG-1*, HMSG-2 Yes Yes 66 F clear
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3/28/19 HMSG-1*, HMSG-2 Yes No 66 F Clear
*- Duplicate sample collected

Canister pressure for sample HMSG-1 Dup was received by the lab at zero (0) pressure. The lab
noted the turn nob was open at receipt which may have occurred during packaging. HMSG-1 and
HMSG-2 were received by the lab with proper pressure for analysis. HMSG-1 Dup was not analyzed
for this assessment.

Decreased sampling volumes were observed in HMSG-1 during the 12/31, 1/13 and 2/27 sampling
events. HMSG-1 is located within a large landscaped bed while HMSG-2 is located between paved
driveways and other impervious surfaces. SUMMIT attributed the decreased volume to increased
saturation levels of the surrounding soils. During the March 28, 2019 sampling HMSG-1 was noted
to have water in the sample tubing. It is unknown if the water was a result of perched water or rain
infiltration through surface protection. The water was purged from the sampling point and HMSG-1
was allowed 4 hours equilibrium time prior to sampling. A leak test was passed prior to sampling. If
water and decreased volumes are noted in the next round of sampling, the sampling point will be
replaced with a new soil gas point in accordance with DWM VI Guidance.

3.3. SOIL GAS SAMPLING RESULTS

A summary of laboratory detections and comparisons to DWM Residential Vapor Intrusion Screening
Levels can be found on Table 1.0 in Appendix IV of this report. The following summarizes the soil
gas sample detections:
• Multiple VOC compounds were detected in the soil gas samples collected during the 3/28/19
sampling event. VOCs have historically been detected in previous sampling events (12/7,
12/30, 1/13, 1/30, 2/28, 3/28).
• Trichloroethylene (TCE) was not detected in the soil gas samples collected during the 3/28/19
sampling event. Historically, TCE was not detected above the detection limits with the
exception of a 1.8 ug/m3 “J Value” result in HMSG-1 on 2/28/19.
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• Tetrachloroethylene (PCE) was detected in sampling locations HMSG-1 and HMSG-2 in the
3/28/19 sampling event at concentrations of 3.5 ug/m3 and 78 ug/m3 respectively, below the
NC DWM Residential SGSL of 280 ug/m3. Historically, PCE has been detected in sampling
location HMSG-1 and HMSG-2 in previous sampling events (12/7, 12/30, 1/13, 1/30, 2/28)
with a maximum concentration of 406 ug/m3 collected on 12/30/18 from HMSG-2.

3.4. INDOOR & AMBIENT AIR SAMPLING

Occupancy sampling was conducted in accordance with the VMP and general industry standards.
Sampling was conducted with the VMS activated and maintaining pressures greater than 0.02 in-WC.
The initial sample event was conducted with the HVAC system off. All units were inspected for
potential contaminate sources on 3/27/19, prior to sampling event.

Ambient air samples were collected in laboratory prepared 6 Liter Summa Canisters and calibrated
24-hour regulators. Regulator pressure readings were recorded throughout the sampling event to
ensure the canister vacuum did not reach 0 in HG vacuum during the sampling period. Temperature
and relative humidity measurements were recorded for the sampling period utilizing a Krestral 2500
hand held weather meter. Collected occupancy ambient air samples were analyzed by EPA Method
TO-15 for the presence PCE and PCE daughter products (trichloroethylene, 1,1-dichloroethylene, cis-
1,2-dichloroethylene, trans-1,2-dichloroethylene and vinyl chloride) by Pace Analytical. Canister
vacuum readings never reached 0 in HG and were received by the laboratory at similar vacuum
readings as reported at the end of the sampling event.

A copy of sampling forms detailing each sampling event are included in Appendix VII of this report.
Tables 3.0 in Appendix IV of this report detail the sampling event conditions. A summary of sampling
event data is provided below:

Date Sample IDs Initial Pressure (in Hg)
Final
Pressure (in Hg)
Weather Conditions
3/28/19 U11-2* 30 4 40-60 F Clear
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3/28/19 AA-3 28 5 40-60 F Clear
*- Duplicate sample collected

3.5. POTENTIAL CONTAMINANT SOURCES

During each sampling event, SUMMIT conducted a reconnaissance of the sample areas for potential
on-site and off-site contaminant sources that may interfere with the sample collection conducted at
that time. Copies of the DWM sampling form is included in Appendix VII of this report.

On-site:
• Building Products – The townhome units were constructed and finished with glued-down
finished wood floors, new and painted surfaces (Unit 11). SDS sheets for construction and
building materials did not identify potential contaminants of concern.
Off-Site:
• The subject site is located approximately 180 feet southwest of DSCA Site Cunningham
Cleaners (Site ID 600019). The DSCA site along with the former use of the building
containing the DSCA site are believed to be the source of the identified groundwater impacts
at the subject site. Currently the DSCA site utilizes an active sub-slab depressurization system
to reduce indoor air concentrations of chlorinated solvent compounds. The depressurization
system vents to the exterior air, from the building elevation closest to the subject property.
Figure 2 in Appendix I depicts the DSCA site location in relation to the subject site. A review
of the DSCA site information documents concentrations of TCE/PCE in ambient outside and
indoor air on the Highland Mill property. A 2013 Air Results Map documenting indoor and
outdoor TCE/PCE concentrations is included in Appendix VIII of this report. Wind direction
during the sample events was recorded to be variable with winds trending from and away
from the DSCA site. The active venting of chlorinated solvent compounds on the nearby
adjacent property is considered an outside air contaminant source.

VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59
Charlotte, North Carolina April 24, 2019

D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Unit 11 3-28-19\1820.59 VMS Installation Pre-Occupancy Sampling Report Units 11 3-28-19.docx
3.6. AMBIENT AIR SAMPLING RESULTS

A summary of laboratory detections and comparisons to DWM Residential Indoor Air Screening
Levels (IASLs) can be found on Table 2.0 in Appendix IV of this report.

The following summarizes the laboratory results for Unit 11 on the March 28, 2019 sampling event:

• No detections were reported in indoor air or exterior ambient air samples with respect to Unit
11 collected on 3/28/19.

3.7. RISK ASSESSMENT

SUMMIT utilized the February 2018 DEQ Risk Calculator for soil gas to indoor air exposure
pathway and indoor air exposure pathway risk calculations. The default conservative risk factors and
calculations were utilized for each Exposure Unit. Two soil gas risk assessments were calculated
using the highest detections at the sampling location from all sampling events and also inputting the
last three (3) sampling event. For indoor air risk assessment, the highest concentration detected from
each constituent from the indoor sampling locations was input into each exposure point calculation.
The risk factors are included in the data tables in Appendix IV of this report. A copy of the risk
assessment can be found in Appendix VI of this report. A summary of risk assessment data is provided
below:

Units 11 March 28, 2019 Sampling Event
Date Exposure Pathway Description Carcinogenic Risk
Non-Carcinogenic Hazard Index
Risk Exceeded?
2/27/19 Indoor Air No Detections 0.00E+00 0.00E+00 NO
12/7/18 through 3/28/19 Soil Gas
Highest detections
from all sampling events from sampling point outside of Unit 15
7.00E-07 9.30E-02 NO
VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59
Charlotte, North Carolina April 24, 2019

D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Unit 11 3-28-19\1820.59 VMS Installation Pre-Occupancy Sampling Report Units 11 3-28-19.docx
12/7/18
through
3/28/19
Soil Gas
Highest detections from all sampling
events from
sampling point outside of Unit 8/9
1.70E-06 3.40E-01 NO
3/28/19 Soil Gas
Highest detections from last three (3) sampling events from sampling point outside of
Unit 15
3.40E-07 6.00E-02 NO
3/28/19 Soil Gas
Highest detections
from last three (3) sampling events from sampling point outside of Unit 8/9
9.40E-07 2.20E-02 NO

Based on the input variables and the most conservative risk factors utilized, risk thresholds were not
exceeded.

VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59
Charlotte, North Carolina April 24, 2019

D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Unit 11 3-28-19\1820.59 VMS Installation Pre-Occupancy Sampling Report Units 11 3-28-19.docx
4.0 FINDINGS AND CONCLUSIONS

This report details the results of VMS installation inspections at residential townhome Unit 11, system
testing and ambient air pre-occupancy sampling of this unit. Additional sampling and system testing
will be conducted for the remaining units as outlined in the EMP and VMP for this development.

From February 2018 through July 2018, SUMMIT personnel inspected the VMS installations of all
15 townhomes currently being built by CCH-Highland Mill. Unit 11 was inspected to be in
compliance with the VMP specifications at the time of installation. Subsequent system testing
utilizing the installed inline fans at those units confirmed depressurization is occurring at pressure
differentials greater than the VMP goal of 0.02 in-WC. Subsequent inspections observed potential
leak points at slab penetrations in select units. Potential leak points in all units were re-sealed with
Drago Epoxy and the systems were re-tested. While no signs of a leak were noted for Unit 11, it was
sealed with Drago as a precaution. SUMMIT certifies that the VMS installed in Unit 11 of Highland
Mill Townhomes are installed and operating properly. As-Built drawings will be provided when they
are available.

Soil gas sampling conducted in concurrence with the 3/28/19 pre-occupancy sampling at the site
documented the presence of multiple VOC compounds to include Tetrachloroethylene.
Trichloroethylene was not detected in this assessment. No concentrations exceeded the DMW
Residential SGSLs in the 3/28/19 sampling event. In previous sample events, samples collected from
HMSG-2, adjacent to Unit 8/9 detected Tetrachloroethylene above the DMW Residential SGSLs in
December 30, 2018 and January 13, 2019 sampling events. Risk Assessment calculations indicate
that the hazard index and carcinogenic risk are below risk thresholds for both sampling points.

Indoor and outdoor ambient air samples were collected for pre-occupancy sampling of Unit 11 on
March 28, 2019. The March 28, 2019 results reported no detections of PCE or PCE breakdown
products above laboratory detection limits in the indoor or exterior ambient air samples.

VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59
Charlotte, North Carolina April 24, 2019

D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Unit 11 3-28-19\1820.59 VMS Installation Pre-Occupancy Sampling Report Units 11 3-28-19.docx
Risk Assessment calculations for the indoor air sampling events indicate that the hazard index and
carcinogenic risk are below risk thresholds for Unit 11.

Based on the system testing indicating active depressurization is occurring within acceptable ranges
for Unit 11, the results of the contaminate source investigations, the results of the Risk Assessment
calculations, and the results of the March 28, 2019 sampling event, SUMMIT concludes that the
VMS is operating as intended and thus the townhome units are ready for occupancy.

VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59
Charlotte, North Carolina April 24, 2019

D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Unit 11 3-28-19\1820.59 VMS Installation Pre-Occupancy Sampling Report Units 11 3-28-19.docx
5.0 RECOMMENDATIONS

Based on the VMS inspection and testing, contaminant investigation and remedial actions, Risk
Assessment, and the results of the occupancy sampling events for Unit 11 of the Highland Mill
Townhomes development SUMMIT offers the following recommendations:
• SUMMIT recommends conducting Bi-Weekly (i.e., once every two weeks) pressure
monitoring of all installed pressure monitoring points for a period of 6 months to ensure
adequate depressurization is occurring for the VMS.
• SUMMIT recommends Brownfields approve occupancy of Unit 11 conditioned on the
recommendations outlined above.

VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59
Charlotte, North Carolina April 24, 2019

D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Unit 11 3-28-19\1820.59 VMS Installation Pre-Occupancy Sampling Report Units 11 3-28-19.docx

APPENDIX I
FIGURES
Source: Drawn by SUMMIT. Base Map provided by Metrolina.
Prepared By\Date:PL/01/19Checked By\Date:MZ/01/19
Figure 11 inch = 40 feet
Charlotte, NC
Vapor Mitigation System Sampling Plan
Brownfields Project No. 20037-16-060 CCH-Highland Mill, LLC
Townhomes at Highland Mill 2550 West Tyvola Road, Suite 100
N. Brevard Street Charlotte, NC 28217
Approximate Scale
KEY
Ambient Air Sample Location
Pressure Monitoring Point
Exterior Soil Gas Sampling Point
Townhome Unit Number
Denotes Lower Slab
1 8 1591011121314345672
8
HMSG-1
Cunningham
Cleaners DSCA Site ID 60-0019
HMSG-2
N
AA-3
U11-2
Source: Drawn by SUMMIT. Base Map surveyed by SUMMIT Land Services.
Prepared By\Date:PL/01/19Checked By\Date:MZ/01/19
Scale
Figure 2NTS
Charlotte, NC
Site Overview Map
Brownfields Project No. 20037-16-060 CCH-Highland Mill, LLC
Townhomes at Highland Mill 2550 West Tyvola Road, Suite 100
N. Brevard Street Charlotte, NC 28217
N
Cunningham
Cleaners DSCA
Site ID 60-0019
Subject Site
VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina April 24, 2019

D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Unit 11 3-28-19\Appendix II - Photo Log.rtf

APPENDIX II
PHOTOGRAH LOGS

Highland Park Townhomes SUMMIT Project No.1820.59 Charlotte, Mecklenburg County, North Carolina April 24, 2019

D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Unit 11 3-28-19\VMP Install Photographs Unit 11.doc
1
SITE PHOTOGRAPHS

View of the subject site on 11-14-17
View of the subject site on 1-12-18
Highland Park Townhomes SUMMIT Project No.1820.59 Charlotte, Mecklenburg County, North Carolina April 24, 2019

D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Unit 11 3-28-19\VMP Install Photographs Unit 11.doc
2

View of subject site on 1-24-18
View of foundation walls for Unit 15, 14 and 13 on 2-28-18.
Highland Park Townhomes SUMMIT Project No.1820.59 Charlotte, Mecklenburg County, North Carolina April 24, 2019

D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Unit 11 3-28-19\VMP Install Photographs Unit 11.doc
3

View of typical water proofing of split-level walls
View of sub-slab aggregate, meeting VMP specifications.
Highland Park Townhomes SUMMIT Project No.1820.59 Charlotte, Mecklenburg County, North Carolina April 24, 2019

D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Unit 11 3-28-19\VMP Install Photographs Unit 11.doc
4

View showing 4” space sub-slab for aggregate layer per VMP on 2-28-18.
View of vapor extraction system installed on 3-8-18.
Highland Park Townhomes SUMMIT Project No.1820.59 Charlotte, Mecklenburg County, North Carolina April 24, 2019

D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Unit 11 3-28-19\VMP Install Photographs Unit 11.doc
5
View of pressure monitoring point conduit installed in Unit 10 on 3-8-18.

View of sub-slab plumbing install on Unit 10.

Highland Park Townhomes SUMMIT Project No.1820.59 Charlotte, Mecklenburg County, North Carolina April 24, 2019

D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Unit 11 3-28-19\VMP Install Photographs Unit 11.doc
6
View of concrete pour on Unit 10-11.
View of vapor barrier installed under porch footer.
Highland Park Townhomes SUMMIT Project No.1820.59 Charlotte, Mecklenburg County, North Carolina April 24, 2019

D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Unit 11 3-28-19\VMP Install Photographs Unit 11.doc
7
View of Unit 8 upper slab.
View of Unit 7 upper slab.

Highland Park Townhomes SUMMIT Project No.1820.59 Charlotte, Mecklenburg County, North Carolina April 24, 2019

D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Unit 11 3-28-19\VMP Install Photographs Unit 11.doc
8
View of 1L soil vapor cannisters with duplicate T sampling setup.
View of negative differential pressures at Unit 10 during sampling of Unit 11.

Highland Park Townhomes SUMMIT Project No.1820.59 Charlotte, Mecklenburg County, North Carolina April 24, 2019

D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Unit 11 3-28-19\VMP Install Photographs Unit 11.doc
9
View of negative differential pressures at unit 15 during sampling event of Unit 11.
View of negative differential pressures at unit 13 during sampling event of Unit 11.

Highland Park Townhomes SUMMIT Project No.1820.59 Charlotte, Mecklenburg County, North Carolina April 24, 2019

D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Unit 11 3-28-19\VMP Install Photographs Unit 11.doc
10
View of negative differential pressures at unit 8 during sampling event of Unit 11.
View of system testing Units 10 through 8, 2-26-19

Highland Park Townhomes SUMMIT Project No.1820.59 Charlotte, Mecklenburg County, North Carolina April 24, 2019

D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Unit 11 3-28-19\VMP Install Photographs Unit 11.doc
11
View of system testing Units 10 through 8, 2-26-19

VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina April 24, 2019
D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Unit 11 3-28-19\Appendix III - VMS Field Inspection Logs.rtf

APPENDIX III
VMS FIELD INSPECTION LOGS

Vapor M.itigation System inspectior, Log
Highland Mill Townhomes
Browrrfi ef d Proiect # : 20037 -16-060
Date 2-zx- t s/Inspector: PW r-_
Yes Repairs/Mod ificat ions
Stone-base th icknes aceptable htA P,-,rpJ J"' s{o*
Extraction piping installed properly
Stone-base over extraction piping proper thickness
Pressure monitoring pooint constructed and iustalled properly
Vapor barrier membrane installed properly
Riser/fan installed correctly
commertls: 9. k- q ^J.l , {. -, n Jn--L:"'us
7ul.L J-- ,/l't, uq&Lu*-r'
(>*st*+oh 6- /{. P"Js
Date Z- X-/<Inspector: f0V C_
Yes Repairs/Mod ifications
Stone-base thicknes aceptable Lt-
Extraction piping installed properly NA
Stone-base over extraction piping proper thiokness
Pressure monitoring pooiut constructed and installed properly
Vapor barrier membrane installed properly
Riser/fan installed correctly
commetrts: $Lu^z bn>-- r"*, l-t/.r/( o^K- tY- uff-" s loL 5
Date 3- 2q- (r f nspector: ?W (_,
Yes Repairs/Modifications
Stone-base thicknes aceptable L/
Extraction piping installed properly t/-
Stone-base over extraction piping proper thiokness htA
Pressnre monitoring pooint constructed and installed properly L/
Vapor barrier rnembrane installed properly NK
Riser/fan instal led correctly N,+
Comments:
Vapor Mitigation System inspection Log
Highland Mill Townhomes
Brownfief d Project #:2003j-16-060
MZ
Repairs/Modifications
Stone-base thicknes aceotable
Extraction piping installed
Stone-base over extraction oioi roper th ickuess
Pressure monitoring pooint constructed and installed
Vapor barrier membrane installed
Riser/fan installed correctly S'|-'. l. qtr' Pwt'tComments: r,t p-
V q?atI
4*l r.o.t
o.. 7 u ^,1-2
t&r.v:os, (L*-t
3*n-'{."> otr* J-u
U&\S coxely-Jwn
'v' ;^ t+*l/
or..'-|r ) r cts
Date LI-23- ty lrrspector: f (rrr L-
Yes Repairs/Modifications
Stone-base thicknes aceptable
Extraction piping installed properly
Stone-base over extraction piping proper thickness
Pressure monitoring pooint constructed ancl installed properly
Cotnments: / / t
'2['tb>zla(a '<- )Ao P- u
d^ - Fs g- /g's t*'ltt.,f**.,t >{
/..--- vAS l-!.1-116.-4
Date 5-q- rd Inspector: CE
Yes Repairs/Modifications
Stone-base thicknes aceDtab le L-/-
Extraclion piping installed properly L./
Stone-base over extraction piping proper thickness u-/
Pressure monitoring pooiut constructed and installed properly l//''
Vapor barrier membrane installed properly ,-/
Riser/fan installed correctly (-"t/l I l=u--sComments: (/n,15 rn1,---f*.( - 6 / K-,?.'r,.4 //z-lL F,f-l -Sr-r S**7t23
Vapor Mitigation System inspection Log
Highland Mill Townhornes
Brownfief d Project #:20037-16-060
Date s- t/-- tK Inspector: F\^t L
Yes Repairs/Modifications
Stone-base thicknes aceptable \,-
Extraction piping instal led property t-
Stone-base over extraction piping proper thickness r--
Pressure monitoring pooint constructed and installed properly (/
Vapor barrier membrane installed properly t/-
Ri ser/fan instal led correctly /rno F-eq)comments: S\J2 6r..-rJ !'-lt 6 - l{ /
l-f 9{-,* V-+c ooool ?;?"--+ o-f("ouuJ-
U"h s V/V.5 4s-f---fr
Date (-26_/e.. llnspector: pU,tt- +AZ
Yes Repairs/Mod ifical ions
Stone-base th icknes aceptable V
Extraction piping installed properly
Stone-base over extraction piping proper thickness
Pressure monitoring pooint constructed and iustalled properly
Vapor barrier rnelnbrane installed properly
Riser/fan installed correctly N- Fn-.Cotntnetrts: tl t tVY.- v)qv-:-,J\- o.-1 0^-Fs t-{ ; "t7 --l-.tL u/f" /euol
Date >-3- tr Inspector: ?WL-
Yes Repairs/Modifications
Stone-base th icknes aceptable
Extraction piping installed properly
Stone-base over extraction piping proper thickness
Pressure monitoring pooint constructed and installed properly
Vapor barrier mernbrane installed properly
Riser/fan instal led correctly
6r,! U,^;ts t- -t
(c1s-z-.l (*-.
Ln-n l.r*( t^t/t- -+*J f
VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina April 24, 2019

D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Unit 11 3-28-19\Appendix IV - Data Tables.rtf

APPENDIX IV
SAMPLE DATA TABLES

Page 1 of 1
CAS Analyte*12/7/2018 12/30/2018 1/13/2019 1/31/2019 2/28/2019 3/28/2019 12/7/2018 12/30/2018 1/13/2019 1/31/2019 2/28/2019 3/28/2019 12/7/2018 12/30/2018 1/13/2019 1/31/2019 2/28/2019 3/28/2019
67-64-1 Acetone 131 33.6 <12.3 29.8 42.2 46 147 37.3 <12.3 12.1 173 -197 10.5 25.3 39.8 <5.1 9.0 J 2.20E+05
71-43-2 Benzene 2.9 5.8 <1.6 1.0 J 1.5 0.38 3.2 0.92 J <1.6 1.1 J 1.4 J -4.8 <0.37 <0.32 0.90 J <.65 <0.13 1.20E+02
75-15-0 Carbon disulfide 8.7 <1.1 <2.2 <1.0 7.4 <0.21 9.3 <1.1 <2.2 <1.0 12.5 -17 1.3J <0.46 <0.84 1.7 J <0.21 4.90E+03
74-87-3 Chloromethane <0.13 1.2 J <1.6 1.0 J 3.5 9.4 <0.13 1.4 J <1.6 <0.72 1.7 J -<0.13 <0.37 <0.33 <0.60 11 <0.14 6.30E+02
110-82-7 Cyclohexane 7.2 <1.7 <3.6 <1.6 <1.5 <0.24 7.6 3.9 J <3.6 <1.6 <1.5 -7.2 <0.85 <0.74 <1.4 <1.5 <0.24 4.20E+0475-71-8 Dichlorodifluoromethane 2.5 J 2.0 J <3.0 2.9 J 2.4 J 1.6 2.4 J 2.2 J <3.0 2.0 J 2.2 J -<0.33 1.8 J 2.2 2.5 J <1.2 <0.21 7.00E+02
156-59-2 cis-1,2-Dichloroethylene <0.19 <1.1 <2.2 <1.0 6.3 <0.16 <0.19 <1.1 <2.2 <1.0 4.7 -<0.19 <0.53 <0.46 <0.84 <0.92 <0.16 NA
100-78-6 Ethylbenzene 4.8 <1.5 <3.1 <1.4 1.9 J <0.25 5.2 <1.5 <3.1 <1.4 1.4 J -<0.26 <0.73 <0.64 <1.2 <1.3 <0.25 3.70E+02
622-96-8 4-Ethyltoluene <0.59 <2.7 <5.8 <2.6 <2.4 0.52 <0.59 <2.7 <5.8 <2.6 <2.4 -<0.59 <1.4 <1.2 <2.2 <2.4 <0.30 NA142-82-5 n-Heptane 6.1 <1.8 <3.9 <1.7 <1.6 <0.24 7 <1.8 <3.9 <1.7 <1.6 -18 <0.91 <0.8 <1.5 <1.6 <0.24 2.80E+03
110-54-3 n-Hexane 13 76.8 8.4 35.5 28 <0.62 12 363 <3.2 2.2 J 19.3 -23 12.4 2.2 35 24.6 <0.62 4.90E+04
591-78-6 2-Hexanone <0.61 <3.6 <7.6 <3.4 <3.1 <0.24 <0.61 <3.6 <7.6 <3.4 <3.1 -<0.61 <1.8 <1.6 <2.9 <3.1 <0.24 2.10E+02
75-09-2 Methylene chloride <0.20 65.8 49.7 117 71.1 1.1 J <0.20 126 <9.6 12.5 J 84.9 -<0.20 19.9 12 213 46.7 0.81 J 4.20E+0378-93-3 2-Butanone (MEK)<0.50 6.4 J <3.8 <1.7 <1.6 3.0 J <0.50 3.4 J <3.8 2.1 J <1.6 -<0.50 2.2 J <0.77 1.5 J 8.3 J 1.8 J 3.50E+04
108-10-1 4-Methyl-2-pentanone (MIBK)<0.57 <2.5 <5.3 <2.4 <2.2 0.67 <0.57 <2.5 <5.3 <2.4 2.4 J -<0.57 <1.2 <1.1 <2.0 <2.2 <0.20 2.10E+04
91-20-3 Naphthalene <1.9 <6.4 <13.5 <6.1 <5.6 <0.40 <1.9 <6.4 <13.5 <6.1 <5.6 -<1.9 <3.2 <2.8 <5.1 <5.6 <0.40 2.10E+01
115-07-1 Propylene 148 9.3 <1.5 8 5.9 <0.17 156 9.8 <1.5 7.4 <0.60 -57.4 8.8 <0.30 <0.55 <0.60 <0.17 2.10E+04
100-42-5 Styrene <0.32 <1.7 <3.5 <1.6 <1.5 <0.26 <0.32 <1.7 <3.5 <1.6 <1.5 -<0.32 <0.83 <0.72 <1.3 <1.5 <0.26 7.00E+0395-63-6 1,2,4-Trimethylbenzene <0.64 2.6 J <4.6 <2.1 3.2 J <0.31 <0.64 <2.2 11.1 <2.1 2.1 J -<0.64 <1.1 <0.95 <1.7 <1.9 <0.31 4.20E+02
108-67-8 1,3,5-Trimethylbenzene <0.64 <1.9 <4.1 <1.8 1.9 J 0.65 <0.64 <1.9 <4.1 <1.8 <1.7 -<0.64 <0.96 <0.84 <1.5 <1.7 <0.31 4.20E+02
127-18-4 Tetrachloroethylene 4.8 9.9 29.8 <1.4 25.1 3.5 1.4 13.1 29.8 <1.4 20.6 -2.4 406 344 25.8 252 78 2.80E+02108-88-3 Toluene 17 18.9 <3.6 3.7 9.5 0.93 16 2.5 J 9.2 <1.6 7 -10 0.95 J <0.74 4.2 3.2 J 0.46 3.50E+0479-01-6 Trichloroethylene <0.41 <1.2 <2.6 <1.2 1.8 J <0.22 <0.41 <1.2 <2.6 <1.2 1.4 J -<0.41 <0.62 <0.54 <0.99 1.7 J <0.22 1.40E+01
75-69-4 Trichlorofluoromethane 2.5 J <1.8 <3.7 <1.7 <1.5 1.1 J 2.6 J <1.8 <3.7 <1.7 1.6 J -<0.62 4.8 4.3 3.1 J 5.3 1.8 J NA
75-01-4 Vinyl chloride <0.23 <0.61 <1.3 <0.58 <0.53 <0.16 <0.23 <0.61 <1.3 <0.58 <0.53 -<0.23 <0.30 <0.26 <0.49 <0.53 <0.16 5.60E+01m,p-Xylene 21 5.2 J <7.1 <3.2 6.8 J 0.73 J 22 <3.4 <7.1 <3.2 5 J -4.3 <1.7 <1.5 <2.7 <2.9 <0.50 7.00E+02
95-47-6 o-Xylene 4.3 1.8 J <7.5 <1.6 2.6 J 0.41 J 5.2 <1.7 9.4 <1.6 2 J -<0.30 <0.83 <0.72 <1.3 <1.5 <0.27 7.00E+02
Risk Assessment - Soil Gas to Indoor Air - All sampling events
2/2018 DWM Residential Soil Gas Screening Levels (SGSLs) used for comparison
2/2018 DEQ Risk Calculator Untilized to calulate Carinogenic Risk (CR) and Hazard Index (HI).
CR/HI calculated with the highest detection from all events and last three (3) sampling events conducted at that location.
J = Estimated Concentration
NT = Not Tested
3/28/19 HMSG-1 DUP lost pressure in shipping and was not analyzed in accordance with DEQ VI Guidance.
Table 1.0: TO-15 Soil Gas Sample Detection Summary Table
All Values in ug/m3 Sample Date
HMSG-1
Soil Gas Point @ 6'Sample Date
HMSG-2
Soil Gas Point @ 6'Sample Date
Carcinoenic Risk (Resident)
Hazard Index (Resident)
Soil Gas Point @ 6'
HMSG-1 DUP NC DWM
Residential
SGSL
7.00E-07
9.30E-02
1.70E-06
3.40E-01
Carcinoenic Risk (Resident)Hazard Index (Resident)
Risk Assessment - Soil Gas to Indoor Air - Last 3 sampling events
3.40E-076.00E-02 9.40E-072.20E-02
Highland Mill #3
Charlotte, NC
April 24, 2019
SUMMIT Project No: 1820.59
Page 2 of 4
127-18-4 79-01-6 75-35-4 156-59-2 156-60-5 75-01-4
Sample ID Sample Note Date Collected CR HI
U11-2 <0.48 <0.39 <0.42 <0.33 <0.43 <0.19
U11-2 Dup <0.48 <0.39 <0.42 <0.33 <0.43 <0.19
AA-3
Exterior Location
# 3 3/28/2019 <0.50 <.41 <0.43 <0.35 <0.45 <0.20
8.30E+00 4.20E-01 4.20E+01 NA NA 1.70E-01
<# = Below Method Detection Limit
BOLD = Concentration Above Reference Values
2/2018 DWM Residential IASLs used for comparison
2/2018 DEQ Risk Calculator Untilized to calulate Carinogenic Risk (CR) and Hazard Index (HI).
PCE and daughter products analyzed for this assessment
J = Estimated Concentration
NT = Not Tested
Unit 11 - Lower
Level 3/28/2019
NC DMW Indoor Air Screening Level (IASL)
Table 2.0: TO-15 Ambient Air Sample Detection Summary Table
All Values in ug/m3
TetrachloroethyleneTrichloroethylene 1,1-dichloroethylene cis-1,2-dichloroethylene trans-1,2-dichloroethylen Vinyl chlorideHighland Mill #3
Charlotte, NC
April 24, 2019
SUMMIT Project No: 1820.59
Page 3 of 4
127-18-4 79-01-6 75-35-4 156-59-2 156-60-5 75-01-4
Sample ID Sample Note Date Collected CR HI
U15-1 0.57 0.19 J <0.067 <0.029 <0.048 <0.056U15-1 DUP 0.6 0.2 J <0.067 <0.029 <0.048 <0.056 4.70E-07 1.10E-01
U15-2 12/30/2018 0.56 J <0.40 <0.42 <0.34 <0.44 <0.20
U15-3 1/13/2019*<0.47 <0.38 <0.41 <0.33 <0.42 <0.19U15-4 1/30/2019 <0.47 <0.38 <0.41 <0.33 <0.42 <0.19
U14-1 3.5 <0.40 <0.42 <0.34 <0.44 <0.20
U14-1 DUP 3.3 <0.40 <0.42 <0.34 <0.44 <0.20
U14-2 1/13/2019*<0.49 <0.40 <0.42 <0.34 <0.44 <0.20U14-3 1/30/2019 <0.47 <0.38 <0.41 <0.33 <0.42 <0.19
U13-1 12/30/2018 38.5 <0.41 <0.43 <0.35 <0.45 <0.20 3.60E-06 9.20E-01
U13-2 <0.45 <0.37 <0.39 <0.32 <0.41 <0.18
U13-2 DUP <0.45 <0.37 <0.39 <0.32 <0.41 <0.18U13-3 <0.47 <0.38 <0.41 <0.33 <0.42 <0.19U13-3 DUP <0.47 <0.38 <0.41 <0.33 <0.42 <0.19
U12-1 Unit 12 - Lower
Level 2/27/2019 <0.49 <0.40 <0.42 <0.34 <0.44 <0.2
U11-2 <0.48 <0.39 <0.42 <0.33 <0.43 <0.19
U11-2 Dup <0.48 <0.39 <0.42 <0.33 <0.43 <0.19
U10-1 Unit 10 - Lower
Level 2/27/2019 <0.47 <0.38 <0.41 <0.33 <0.42 <0.19
U09-1 Unit 09 - Lower
Level 2/27/2019 <0.47 <0.38 <0.41 <0.33 <0.42 <0.19
U08-1 Unit 08 - Lower
Level 2/27/2019 <0.48 <0.39 <0.42 <0.33 <0.43 <0.19
EXTA1-1 12/7/2018 0.81 0.28 <0.067 <0.029 <0.048 <0.056
AA-1 12/30/2018 <0.49 <0.40 <0.42 <0.34 <0.44 <0.20
AA-1 1/13/2019 <0.45 <0.37 <0.39 <0.32 <0.41 <0.18
AA-1 1/30/2019 <0.44 <0.36 <0.39 <0.31 <0.40 <0.18
AA-1 2/27/2019 <0.47 <0.38 <0.41 <0.33 <0.42 <0.19
AA-2 12/30/2018 <0.49 <0.40 <0.42 <0.34 <0.44 <0.20
AA-2 1/13/2019 <0.47 <0.38 <0.41 <0.33 <0.42 <0.19AA-2 2/27/2019 <0.51 <0.41 <0.44 <0.35 <0.46 <0.20
AA-3
Exterior Location
# 3 1/30/2019 <0.61 <0.50 <0.53 <0.42 <0.55 <0.24
AA-3
Exterior Location
# 3 3/28/2019 <0.50 <.41 <0.43 <0.35 <0.45 <0.20
8.30E+00 4.20E-01 4.20E+01 NA NA 1.70E-01
<# = Below Method Detection LimitBOLD = Concentration Above Reference Values
2/2018 DWM Residential IASLs used for comparison2/2018 DEQ Risk Calculator Untilized to calulate Carinogenic Risk (CR) and Hazard Index (HI).
PCE and daughter products analyzed for this assessment
J = Estimated Concentration
NT = Not Tested
* - 1/13/19 indoor air samples collected 6hrs following shut off of air exchange units.
Table 3.0: TO-15 Historical Ambient Air Sample Detection Summary Table
Unit 13 - Lower
Level.
Exterior Location
# 1
Exterior Location
# 2 Trichloroethylene 1,1-dichloroethylene cis-1,2-dichloroethylene trans-1,2-dichloroethylen Vinyl chlorideNC DMW Indoor Air Screening Level (IASL)
All Values in ug/m3
12/7/2018
12/30/2018 TetrachloroethyleneUnit 15 - Lower
Level.
Unit 14 - Lower
Level.
1/13/2019*
1/30/2019
Unit 11 - Lower
Level 3/28/2019
Highland Mill #3
Charlotte, NC
April 24, 2019
SUMMIT Project No: 1820.59
Time
PM08
(in WC)
PM10
(in WC)
PM13
(in WC)
PM15
(in WC)
Temp.
(F)
Relative
Humidity (%)
Wind Speed
(mph)
Barometric
Pressure
(in Hg)
Condition U11-
2/DUP AA-3
1100 ----63 28 4 E 30.01 Clear 30+281200---0.08 -0.202 64 28 5 SW 30.01 Clear 30 28
1300 ---0.08 -0.192 65 28 3 SW 30.01 Clear 29 281400-0.393 -0.093 -0.08 -0.182 66 29 6 SW 30.01 Clear 28 27
1500 -3.81 -0.112 -0.08 -0.22 67 31 8 SW 30.01 Clear 28 261600-0.421 -0.137 -0.08 -0.233 65 39 7 SW 30.01 Clear 27 251700-0.457 -0.164 -0.078 -0.23 62 42 2 SW 30.01 Clear 26 24
1800 -0.497 -0.174 -0.08 -0.23 59 42 3 SW 30.01 Clear 25 241900-0.475 -0.135 -0.08 -0.23 54 49 3 SW 30.01 Clear 24 23
2000 -0.483 -0.197 -0.08 -0.253 53 52 3 SW 30.01 Clear 23 222100-0.5 -0.22 -0.08 -0.25 51 55 1 SW 30.01 Clear 21 20
2200 -0.53 ---49 55 1 V 30.01 Clear --2300 ----47 57 0 30.01 Clear --
2400 --------Clear --100 --------Clear --
200 --------Clear --300 --------Clear --
400 --------Clear --500 --------Clear --
600 -0.389 -0.198 -0.08 -0.2 56 52 7 SW 30.00 Clear 10 11700-0.392 -0.187 --63 39 5 SW 30.00 Clear 9 10
800 ----67 29 0 30.00 Clear 8 9900----71 26 5 SW 30.00 Clear 7 8
1000 --0.187 -0.08 -0.201 72 23 4 SW 30.00 Clear 6 61100-0.39 -0.189 -0.08 -0.2 73 25 3 V 30.00 Clear 5 51200-0.38 -0.187 -0.08 -0.2 73 21 0 30.00 Clear 4 5
Table 4.0: Sample Collection Summary Table
March 28, 2019
Pressure Monitoring Readings Weather Conditions Canister Pressure Readings
VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina April 24, 2019

D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Unit 11 3-28-19\Appendix V - Laboratory Reports.rtf

APPENDIX V
LABORATORY REPORTS

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Page 16 of 16
#=CL#
April 16, 2019
LIMS USE: FR - ASHTON BROWN
LIMS OBJECT ID: 92423328
92423328
Project:
Pace Project No.:
RE:
Ashton Brown
3575 Centre Circle
Fort Mill, SC 29718
HIGHLAND MILL
Dear Ashton Brown:
Enclosed are the analytical results for sample(s) received by the laboratory on March 29, 2019. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Taylor Ezell
[e-mail]
Project Manager
[phone]
Enclosures
cc:Michael Zavislak, Summit Engineering
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 10
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92423328
HIGHLAND MILL
Minnesota Certification IDs
1700 Elm Street SE, Minneapolis, MN 55414-2485
A2LA Certification #: 2926.01
Alabama Certification #: 40770
Alaska Contaminated Sites Certification #: 17-009
Alaska DW Certification #: MN00064
Arizona Certification #: AZ0014
Arkansas DW Certification #: MN00064
Arkansas WW Certification #: 88-0680
California Certification #: 2929
CNMI Saipan Certification #: MP0003
Colorado Certification #: MN00064
Connecticut Certification #: PH-0256
EPA Region 8+Wyoming DW Certification #: via MN 027-
053-137
Florida Certification #: E87605
Georgia Certification #: 959
Guam EPA Certification #: MN00064
Hawaii Certification #: MN00064
Idaho Certification #: MN00064
Illinois Certification #: 200011
Indiana Certification #: C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
Kentucky DW Certification #: 90062
Kentucky WW Certification #: 90062
Louisiana DEQ Certification #: 03086
Louisiana DW Certification #: MN00064
Maine Certification #: MN00064
Maryland Certification #: 322
Massachusetts Certification #: M-MN064
Michigan Certification #: 9909
Minnesota Certification #: 027-053-137
Minnesota Dept of Ag Certifcation #: via MN 027-053-137
Minnesota Petrofund Certification #: 1240
Mississippi Certification #: MN00064
Missouri Certification #: 10100
Montana Certification #: CERT0092
Nebraska Certification #: NE-OS-18-06
Nevada Certification #: MN00064
New Hampshire Certification #: 2081
New Jersey Certification #: MN002
New York Certification #: 11647
North Carolina DW Certification #: 27700
North Carolina WW Certification #: 530
North Dakota Certification #: R-036
Ohio DW Certification #: 41244
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Primary Certification #: MN300001
Oregon Secondary Certification #: MN200001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification #: MN00064
South Carolina Certification #:74003001
Tennessee Certification #: TN02818
Texas Certification #: T104704192
Utah Certification #: MN00064
Vermont Certification #: VT-027053137
Virginia Certification #: 460163
Washington Certification #: C486
West Virginia DEP Certification #: 382
West Virginia DW Certification #: 9952 C
Wisconsin Certification #: 999407970
Wyoming UST Certification #: via A2LA 2926.01
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
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[phone]
Page 2 of 10
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92423328
HIGHLAND MILL
Lab ID Sample ID Matrix Date Collected Date Received
92423328001 U11-2 #3424 Air 03/29/19 12:30 03/29/19 12:50
92423328002 U11-2 DUP #2752 Air 03/29/19 12:30 03/29/19 12:50
92423328003 AA-3 #3462 Air 03/29/19 12:35 03/29/19 12:50
92423328004 3424 Cert Air 03/29/19 00:00 03/29/19 13:57
92423328005 2752 Cert Air 03/29/19 00:00 03/29/19 13:57
92423328006 3462 Cert Air 03/29/19 00:00 03/29/19 13:57
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
Page 3 of 10
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92423328
HIGHLAND MILL
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92423328001 U11-2 #3424 TO-15 6 PASI-MMG2
92423328002 U11-2 DUP #2752 TO-15 6 PASI-MMG2
92423328003 AA-3 #3462 TO-15 6 PASI-MMG2
92423328004 3424 Cert TO-15 6 PASI-MNCK
92423328005 2752 Cert TO-15 6 PASI-MNCK
92423328006 3462 Cert TO-15 6 PASI-MMJL
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
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[phone]
Page 4 of 10
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92423328
HIGHLAND MILL
Sample:U11-2 #3424 Lab ID:92423328001 Collected:03/29/19 12:30 Received:03/29/19 12:50 Matrix:Air
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: TO-15TO15 MSV AIR
1,1-Dichloroethene ND ug/m3 04/11/19 16:28 75-35-41.2 0.42 1.52
cis-1,2-Dichloroethene ND ug/m3 04/11/19 16:28 156-59-21.2 0.33 1.52
trans-1,2-Dichloroethene ND ug/m3 04/11/19 16:28 156-60-51.2 0.43 1.52
Tetrachloroethene ND ug/m3 04/11/19 16:28 127-18-41.0 0.48 1.52
Trichloroethene ND ug/m3 04/11/19 16:28 79-01-60.83 0.39 1.52
Vinyl chloride ND ug/m3 04/11/19 16:28 75-01-40.40 0.19 1.52
Sample:U11-2 DUP #2752 Lab ID:92423328002 Collected:03/29/19 12:30 Received:03/29/19 12:50 Matrix:Air
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: TO-15TO15 MSV AIR
1,1-Dichloroethene ND ug/m3 04/11/19 15:58 75-35-41.2 0.42 1.52
cis-1,2-Dichloroethene ND ug/m3 04/11/19 15:58 156-59-21.2 0.33 1.52
trans-1,2-Dichloroethene ND ug/m3 04/11/19 15:58 156-60-51.2 0.43 1.52
Tetrachloroethene ND ug/m3 04/11/19 15:58 127-18-41.0 0.48 1.52
Trichloroethene ND ug/m3 04/11/19 15:58 79-01-60.83 0.39 1.52
Vinyl chloride ND ug/m3 04/11/19 15:58 75-01-40.40 0.19 1.52
Sample:AA-3 #3462 Lab ID:92423328003 Collected:03/29/19 12:35 Received:03/29/19 12:50 Matrix:Air
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: TO-15TO15 MSV AIR
1,1-Dichloroethene ND ug/m3 04/11/19 14:57 75-35-41.3 0.43 1.58
cis-1,2-Dichloroethene ND ug/m3 04/11/19 14:57 156-59-21.3 0.35 1.58
trans-1,2-Dichloroethene ND ug/m3 04/11/19 14:57 156-60-51.3 0.45 1.58
Tetrachloroethene ND ug/m3 04/11/19 14:57 127-18-41.1 0.50 1.58
Trichloroethene ND ug/m3 04/11/19 14:57 79-01-60.86 0.41 1.58
Vinyl chloride ND ug/m3 04/11/19 14:57 75-01-40.41 0.20 1.58
Sample:3424 Cert Lab ID:92423328004 Collected:03/29/19 00:00 Received:03/29/19 13:57 Matrix:Air
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: TO-15Individual Can Certification
1,1-Dichloroethene ND ug/m3 03/08/19 22:21 75-35-40.81 0.27 1
cis-1,2-Dichloroethene ND ug/m3 03/08/19 22:21 156-59-20.81 0.22 1
trans-1,2-Dichloroethene ND ug/m3 03/08/19 22:21 156-60-50.81 0.28 1
Tetrachloroethene ND ug/m3 03/08/19 22:21 127-18-40.69 0.31 1
Trichloroethene ND ug/m3 03/08/19 22:21 79-01-60.55 0.26 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/16/2019 06:08 PM
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[phone]
Page 5 of 10
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92423328
HIGHLAND MILL
Sample:3424 Cert Lab ID:92423328004 Collected:03/29/19 00:00 Received:03/29/19 13:57 Matrix:Air
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: TO-15Individual Can Certification
Vinyl chloride ND ug/m3 03/08/19 22:21 75-01-40.26 0.13 1
Sample:2752 Cert Lab ID:92423328005 Collected:03/29/19 00:00 Received:03/29/19 13:57 Matrix:Air
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: TO-15Individual Can Certification
1,1-Dichloroethene ND ug/m3 03/08/19 20:02 75-35-40.81 0.27 1
cis-1,2-Dichloroethene ND ug/m3 03/08/19 20:02 156-59-20.81 0.22 1
trans-1,2-Dichloroethene ND ug/m3 03/08/19 20:02 156-60-50.81 0.28 1
Tetrachloroethene ND ug/m3 03/08/19 20:02 127-18-40.69 0.31 1
Trichloroethene ND ug/m3 03/08/19 20:02 79-01-60.55 0.26 1
Vinyl chloride ND ug/m3 03/08/19 20:02 75-01-40.26 0.13 1
Sample:3462 Cert Lab ID:92423328006 Collected:03/29/19 00:00 Received:03/29/19 13:57 Matrix:Air
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: TO-15Individual Can Certification
1,1-Dichloroethene ND ug/m3 03/11/19 12:53 75-35-40.40 0.14 0.5
cis-1,2-Dichloroethene ND ug/m3 03/11/19 12:53 156-59-20.40 0.11 0.5
trans-1,2-Dichloroethene ND ug/m3 03/11/19 12:53 156-60-50.40 0.14 0.5
Tetrachloroethene ND ug/m3 03/11/19 12:53 127-18-40.34 0.16 0.5
Trichloroethene ND ug/m3 03/11/19 12:53 79-01-60.27 0.13 0.5
Vinyl chloride ND ug/m3 03/11/19 12:53 75-01-40.26 0.063 0.5
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/16/2019 06:08 PM
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Page 6 of 10
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92423328
HIGHLAND MILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
598904
TO-15
TO-15
TO15 MSV AIR Low Level
Associated Lab Samples:92423328001, 92423328002, 92423328003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3237956
Associated Lab Samples:92423328001, 92423328002, 92423328003
Matrix:Air
AnalyzedMDL
1,1-Dichloroethene ug/m3 ND 0.81 04/11/19 06:580.27
cis-1,2-Dichloroethene ug/m3 ND 0.81 04/11/19 06:580.22
Tetrachloroethene ug/m3 ND 0.69 04/11/19 06:580.31
trans-1,2-Dichloroethene ug/m3 ND 0.81 04/11/19 06:580.28
Trichloroethene ug/m3 ND 0.55 04/11/19 06:580.26
Vinyl chloride ug/m3 ND 0.26 04/11/19 06:580.13
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3237957LABORATORY CONTROL SAMPLE:
LCSSpike
1,1-Dichloroethene ug/m3 41.940.3 104 70-130
cis-1,2-Dichloroethene ug/m3 44.340.3 110 70-130
Tetrachloroethene ug/m3 66.968.9 97 70-130
trans-1,2-Dichloroethene ug/m3 36.640.3 91 70-130
Trichloroethene ug/m3 57.354.6 105 70-130
Vinyl chloride ug/m3 25.926 100 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92423328003
3239101SAMPLE DUPLICATE:
1,1-Dichloroethene ug/m3 ND 25ND
cis-1,2-Dichloroethene ug/m3 ND 25ND
Tetrachloroethene ug/m3 ND 25ND
trans-1,2-Dichloroethene ug/m3 ND 25ND
Trichloroethene ug/m3 ND 25ND
Vinyl chloride ug/m3 ND 25ND
REPORT OF LABORATORY ANALYSIS
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Page 7 of 10
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92423328
HIGHLAND MILL
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - MinneapolisPASI-M
REPORT OF LABORATORY ANALYSIS
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Page 8 of 10
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92423328
HIGHLAND MILL
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92423328001 598904U11-2 #3424 TO-15
92423328002 598904U11-2 DUP #2752 TO-15
92423328003 598904AA-3 #3462 TO-15
92423328004 5976913424 Cert TO-15
92423328005 5976912752 Cert TO-15
92423328006 5976913462 Cert TO-15
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/16/2019 06:08 PM
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[phone]
Page 9 of 10
Page 10 of 10
4/1/19
VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina April 24, 2019

D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Unit 11 3-28-19\Appendix VI - Risk.rtf

APPENDIX VI
RISK CALCULATOR

Version Date:
Basis:
Site Name:
Site Address:
DEQ Section:
Site ID:
Exposure Unit ID:Submittal Date:
Reviewed By:
HMSG-1 Highest Concentration (all sampling events)
North Carolina Department of Environmental Quality
Risk Calculator
Highland Mill #3
N. Brevard and N. Davidson
Brownfields
20037-16-060
February 2018
November 2017 EPA RSL Table
3/12/2019
Prepared By:Patrick Lowery
SUMMIT ELT
MZ
North Carolina DEQ Risk Calculator
Complete Exposure Pathways
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: 20037-16-060
Exposure Unit ID: HMSG-1 Highest Concentration (all sampling events)
Note: Risk output will only be calculated for complete exposure pathways.
Receptor Pathway
Check box if
pathway
complete
Soil Combined Pathways
Groundwater Combined Pathways
Soil Combined Pathways
Groundwater Combined Pathways
Construction Worker Soil Combined Pathways
Soil Combined Pathways
Surface Water Combined Pathways
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Source Soil
Source Groundwater
Source Soil
Source Groundwater
Resident
Non-Residential Worker
CONTAMINANT MIGRATION PATHWAYS
Protection of Groundwater Use
Protection of Surface Water
Input Form 1A
VAPOR INTRUSION PATHWAYS
PRIMARY PATHWAYS
Resident
Non-Residential Worker
User Defined
North Carolina DEQ Risk Calculator
Exposure Point Concentrations
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: 20037-16-060
Exposure Unit ID: HMSG-1 Highest Concentration (all sampling events)
Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.
Exposure Point Concentration
(ug/m3)
Justification for Exposure Point Concentration CAS Number Chemical Minimum Concentration (Qualifier)
Maximum Concentration (Qualifier)Units Location of Maximum Concentration
Detection Frequency
Range of Detection Limits
Concentration Used for Screening
Background Value
Screening Toxicity Value (Screening Level) (n/c)
Potential ARAR/TBC Value
Potential ARAR/TBC Source
COPC Flag (Y/N)
Rationale for Selection or Deletion
173 Table 1.0 67-64-1 Acetone ug/m3 2/28/2019
5.8 Table 1.0 71-43-2 Benzene ug/m3 12/30/2018
12.5 Table 1.0 75-15-0 Carbon Disulfide ug/m3 2/28/2019
3.5 Table 1.0 74-87-3 Chloromethane ug/m3 2/28/2019
7.6 Table 1.0 110-82-7 Cyclohexane ug/m3 12/7/2018
2.9 Table 1.0 75-71-8 Dichlorodifluoromethane ug/m3 1/31/2019
6.3 Table 1.0 156-59-2 Dichloroethylene, 1,2-cis-ug/m3 2/28/2019
7 Table 1.0 142-82-5 Heptane, N-ug/m3 12/7/2018
363 Table 1.0 110-54-3 Hexane, N-ug/m3 12/30/2018
0 Table 1.0 591-78-6 Hexanone, 2-ug/m3
6.4 Table 1.0 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 12/30/2018
2.4 Table 1.0 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 2/28/2019
84.9 Table 1.0 75-09-2 Methylene Chloride ug/m3 2/28/2019
0 Table 1.0 91-20-3 ~Naphthalene ug/m3
156 Table 1.0 115-07-1 Propylene ug/m3 12/7/2018
0 Table 1.0 100-42-5 Styrene ug/m3
29.8 Table 1.0 127-18-4 Tetrachloroethylene ug/m3 12/30/2018
18.9 Table 1.0 108-88-3 Toluene ug/m3 12/30/2018
1.8 Table 1.0 79-01-6 Trichloroethylene ug/m3 2/28/2019
2.6 Table 1.0 75-69-4 Trichlorofluoromethane ug/m3 12/7/2018
3.2 Table 1.0 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 2/28/2019
1.9 Table 1.0 108-67-8 Trimethylbenzene, 1,3,5-ug/m3 2/28/2019
0 Table 1.0 75-01-4 Vinyl Chloride ug/m3
22 Table 1.0 106-42-3 Xylene, P-ug/m3 12/7/2018
22 Table 1.0 108-38-3 Xylene, m-ug/m3 12/7/2018
5.2 Table 1.0 95-47-6 Xylene, o-ug/m3 12/7/2018
Input Form 2E
Soil Gas Exposure Point Concentration Table
North Carolina DEQ Risk Calculator
Summary of Risk Assessment Output Output Form 1A
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: 20037-16-060
Exposure Unit ID: HMSG-1 Highest Concentration (all sampling events)
Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded?
Soil Combined Pathways NC NC NC
Groundwater Combined Pathways*NC NC NC
Soil Combined Pathways NC NC NC
Groundwater Combined Pathways*NC NC NC
Construction Worker Soil Combined Pathways NC NC NC
Soil Combined Pathways NC NC NC
Surface Water Combined Pathways*NC NC NC
Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded?
Groundwater to Indoor Air NC NC NC
Soil Gas to Indoor Air 7.0E-07 9.3E-02 NO
Indoor Air NC NC NC
Groundwater to Indoor Air NC NC NC
Soil Gas to Indoor Air NC NC NC
Indoor Air NC NC NC
Pathway Source
Source Soil NC
Source Groundwater NC
Source Soil NC
Source Groundwater NC
2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed
the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-
based closure.
Protection of Surface Water Exceedence of 2B at POE?
Exceedence of 2B at POE?
VAPOR INTRUSION CALCULATORS
Resident
Non-Residential Worker
CONTAMINANT MIGRATION CALCULATORS
Target POE Concentrations Exceeded?
Protection of Groundwater Use Exceedence of 2L at POE?
Exceedence of 2L at POE?
1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for
lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations.
Notes:
PRIMARY CALCULATORS
Resident
Non-Residential Worker
User Defined
North Carolina DEQ Risk Calculator
DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: 20037-16-060
Exposure Unit ID: HMSG-1 Highest Concentration (all sampling events)
CAS #Chemical Name:
Soil Gas Concentration
(ug/m3)
Calculated
Indoor Air
Concentration
(ug/m3)
Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06
Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2
Calculated
Carcinogenic
Risk
Calculated
Non-
Carcinogenic
Hazard
Quotient67-64-1 Acetone 173 5.19 -6.5E+03 1.6E-0471-43-2 Benzene 5.8 0.174 3.6E-01 6.3E+00 4.8E-07 5.6E-03
75-15-0 Carbon Disulfide 12.5 0.375 -1.5E+02 5.1E-0474-87-3 Chloromethane 3.5 0.105 -1.9E+01 1.1E-03110-82-7 Cyclohexane 7.6 0.228 -1.3E+03 3.6E-0575-71-8 Dichlorodifluoromethane 2.9 0.087 -2.1E+01 8.3E-04
156-59-2 Dichloroethylene, 1,2-cis-6.3 0.189 --142-82-5 Heptane, N-7 0.21 -8.3E+01 5.0E-04110-54-3 Hexane, N-363 10.89 -1.5E+02 1.5E-02591-78-6 Hexanone, 2-0 0 -6.3E+00 0.0E+00
78-93-3 Methyl Ethyl Ketone (2-Butanone)6.4 0.192 -1.0E+03 3.7E-05108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)2.4 0.072 -6.3E+02 2.3E-05
75-09-2 Methylene Chloride 84.9 2.547 1.0E+02 1.3E+02 2.5E-08 4.1E-0391-20-3 ~Naphthalene 0 0 8.3E-02 6.3E-01 0.0E+00 0.0E+00115-07-1 Propylene 156 4.68 -6.3E+02 1.5E-03100-42-5 Styrene 0 0 -2.1E+02 0.0E+00
127-18-4 Tetrachloroethylene 29.8 0.894 1.1E+01 8.3E+00 8.3E-08 2.1E-02
108-88-3 Toluene 18.9 0.567 -1.0E+03 1.1E-04
79-01-6 Trichloroethylene 1.8 0.054 4.8E-01 4.2E-01 1.1E-07 2.6E-02
75-69-4 Trichlorofluoromethane 2.6 0.078 --95-63-6 Trimethylbenzene, 1,2,4-3.2 0.096 -1.3E+01 1.5E-03108-67-8 Trimethylbenzene, 1,3,5-1.9 0.057 -1.3E+01 9.1E-04
75-01-4 Vinyl Chloride 0 0 1.7E-01 2.1E+01 0.0E+00 0.0E+00
106-42-3 Xylene, P-22 0.66 -2.1E+01 6.3E-03108-38-3 Xylene, m-22 0.66 -2.1E+01 6.3E-0395-47-6 Xylene, o-5.2 0.156 -2.1E+01 1.5E-03
Cumulative:7.0E-07 9.3E-02
All concentrations are in ug/m3
Output Form 3B
Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion
risk, no risk values are calculated for these chemicals.
North Carolina DEQ Risk Calculator
Version Date:
Basis:
Site Name:
Site Address:
DEQ Section:
Site ID:
Exposure Unit ID:Submittal Date:
Reviewed By:
HMSG-1 - Last 3 Sample Events Highest Detections
North Carolina Department of Environmental Quality
Risk Calculator
Highland Mill #3
N. Brevard and N. Davidson
Brownfields
20037-16-060
February 2018
November 2017 EPA RSL Table
4/24/2019
Prepared By:Patrick Lowery
SUMMIT ELT
MZ
North Carolina DEQ Risk Calculator
Complete Exposure Pathways
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: 20037-16-060
Exposure Unit ID: HMSG-1 - Last 3 Sample Events Highest Detections
Note: Risk output will only be calculated for complete exposure pathways.
Receptor Pathway
Check box if
pathway
complete
Soil Combined Pathways
Groundwater Combined Pathways
Soil Combined Pathways
Groundwater Combined Pathways
Construction Worker Soil Combined Pathways
Soil Combined Pathways
Surface Water Combined Pathways
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Source Soil
Source Groundwater
Source Soil
Source Groundwater
Resident
Non-Residential Worker
CONTAMINANT MIGRATION PATHWAYS
Protection of Groundwater Use
Protection of Surface Water
Input Form 1A
VAPOR INTRUSION PATHWAYS
PRIMARY PATHWAYS
Resident
Non-Residential Worker
User Defined
North Carolina DEQ Risk Calculator
Exposure Point Concentrations
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: 20037-16-060
Exposure Unit ID: HMSG-1 - Last 3 Sample Events Highest Detections
Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.
Exposure Point Concentration
(ug/m3)
Justification for Exposure Point Concentration CAS Number Chemical Minimum Concentration (Qualifier)
Maximum Concentration (Qualifier)Units Location of Maximum Concentration
Detection Frequency
Range of Detection Limits
Concentration Used for Screening
Background Value
Screening Toxicity Value (Screening Level) (n/c)
Potential ARAR/TBC Value
Potential ARAR/TBC Source
COPC Flag (Y/N)
Rationale for Selection or Deletion
173 Table 1.0 67-64-1 Acetone ug/m3 2/28/2019
1.5 Table 1.0 71-43-2 Benzene ug/m3 2/28/2019
12.5 Table 1.0 75-15-0 Carbon Disulfide ug/m3 2/28/2019
3.5 Table 1.0 74-87-3 Chloromethane ug/m3 2/28/2019
2.9 Table 1.0 75-71-8 Dichlorodifluoromethane ug/m3 1/31/2019
6.3 Table 1.0 156-59-2 Dichloroethylene, 1,2-cis-ug/m3 2/28/2019
35.5 Table 1.0 110-54-3 Hexane, N-ug/m3 1/31/2019
3 Table 1.0 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 3/28/2019
2.4 Table 1.0 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 2/28/2019
117 Table 1.0 75-09-2 Methylene Chloride ug/m3 1/31/2019
7.4 Table 1.0 115-07-1 Propylene ug/m3 1/31/2019
25.1 Table 1.0 127-18-4 Tetrachloroethylene ug/m3 2/8/2019
9.5 Table 1.0 108-88-3 Toluene ug/m3 2/28/2019
1.8 Table 1.0 79-01-6 Trichloroethylene ug/m3 2/28/2019
1.1 Table 1.0 75-69-4 Trichlorofluoromethane ug/m3 3/28/2019
3.2 Table 1.0 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 2/28/2019
1.9 Table 1.0 108-67-8 Trimethylbenzene, 1,3,5-ug/m3 2/28/2019
6.8 Table 1.0 95-47-6 Xylene, o-ug/m3 2/28/2019
Input Form 2E
Soil Gas Exposure Point Concentration Table
North Carolina DEQ Risk Calculator
Summary of Risk Assessment Output Output Form 1A
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: 20037-16-060
Exposure Unit ID: HMSG-1 - Last 3 Sample Events Highest Detections
Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded?
Soil Combined Pathways NC NC NC
Groundwater Combined Pathways*NC NC NC
Soil Combined Pathways NC NC NC
Groundwater Combined Pathways*NC NC NC
Construction Worker Soil Combined Pathways NC NC NC
Soil Combined Pathways NC NC NC
Surface Water Combined Pathways*NC NC NC
Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded?
Groundwater to Indoor Air NC NC NC
Soil Gas to Indoor Air 3.4E-07 6.0E-02 NO
Indoor Air NC NC NC
Groundwater to Indoor Air NC NC NC
Soil Gas to Indoor Air NC NC NC
Indoor Air NC NC NC
Pathway Source
Source Soil NC
Source Groundwater NC
Source Soil NC
Source Groundwater NC
2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed
the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-
based closure.
Protection of Surface Water Exceedence of 2B at POE?
Exceedence of 2B at POE?
VAPOR INTRUSION CALCULATORS
Resident
Non-Residential Worker
CONTAMINANT MIGRATION CALCULATORS
Target POE Concentrations Exceeded?
Protection of Groundwater Use Exceedence of 2L at POE?
Exceedence of 2L at POE?
1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for
lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations.
Notes:
PRIMARY CALCULATORS
Resident
Non-Residential Worker
User Defined
North Carolina DEQ Risk Calculator
DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: 20037-16-060
Exposure Unit ID: HMSG-1 - Last 3 Sample Events Highest Detections
CAS #Chemical Name:
Soil Gas Concentration
(ug/m3)
Calculated
Indoor Air
Concentration
(ug/m3)
Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06
Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2
Calculated
Carcinogenic
Risk
Calculated
Non-
Carcinogenic
Hazard
Quotient67-64-1 Acetone 173 5.19 -6.5E+03 1.6E-0471-43-2 Benzene 1.5 0.045 3.6E-01 6.3E+00 1.3E-07 1.4E-03
75-15-0 Carbon Disulfide 12.5 0.375 -1.5E+02 5.1E-0474-87-3 Chloromethane 3.5 0.105 -1.9E+01 1.1E-03110-82-7 Cyclohexane -1.3E+0375-71-8 Dichlorodifluoromethane 2.9 0.087 -2.1E+01 8.3E-04
156-59-2 Dichloroethylene, 1,2-cis-6.3 0.189 --142-82-5 Heptane, N--8.3E+01110-54-3 Hexane, N-35.5 1.065 -1.5E+02 1.5E-03591-78-6 Hexanone, 2--6.3E+00
78-93-3 Methyl Ethyl Ketone (2-Butanone)3 0.09 -1.0E+03 1.7E-05108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)2.4 0.072 -6.3E+02 2.3E-05
75-09-2 Methylene Chloride 117 3.51 1.0E+02 1.3E+02 3.5E-08 5.6E-0391-20-3 ~Naphthalene 8.3E-02 6.3E-01115-07-1 Propylene 7.4 0.222 -6.3E+02 7.1E-05100-42-5 Styrene -2.1E+02
127-18-4 Tetrachloroethylene 25.1 0.753 1.1E+01 8.3E+00 7.0E-08 1.8E-02
108-88-3 Toluene 9.5 0.285 -1.0E+03 5.5E-05
79-01-6 Trichloroethylene 1.8 0.054 4.8E-01 4.2E-01 1.1E-07 2.6E-02
75-69-4 Trichlorofluoromethane 1.1 0.033 --95-63-6 Trimethylbenzene, 1,2,4-3.2 0.096 -1.3E+01 1.5E-03108-67-8 Trimethylbenzene, 1,3,5-1.9 0.057 -1.3E+01 9.1E-04
75-01-4 Vinyl Chloride 1.7E-01 2.1E+01
106-42-3 Xylene, P--2.1E+01108-38-3 Xylene, m--2.1E+0195-47-6 Xylene, o-6.8 0.204 -2.1E+01 2.0E-03
Cumulative:3.4E-07 6.0E-02
All concentrations are in ug/m3
Output Form 3B
Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion
risk, no risk values are calculated for these chemicals.
North Carolina DEQ Risk Calculator
Version Date:
Basis:
Site Name:
Site Address:
DEQ Section:
Site ID:
Exposure Unit ID:Submittal Date:
Reviewed By:
3/12/2019
Prepared By:Patrick Lowery
SUMMIT ELT
MZ
HMSG-2 Highest Concentrations (all sampling events)
North Carolina Department of Environmental Quality
Risk Calculator
Highland Mill #3
N. Brevard and N. Davidson
Brownfields
20037-16-060
February 2018
November 2017 EPA RSL Table
North Carolina DEQ Risk Calculator
Complete Exposure Pathways
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: 20037-16-060
Exposure Unit ID: HMSG-2 Highest Concentrations (all sampling events)
Note: Risk output will only be calculated for complete exposure pathways.
Receptor Pathway
Check box if
pathway
complete
Soil Combined Pathways
Groundwater Combined Pathways
Soil Combined Pathways
Groundwater Combined Pathways
Construction Worker Soil Combined Pathways
Soil Combined Pathways
Surface Water Combined Pathways
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Source Soil
Source Groundwater
Source Soil
Source Groundwater
Input Form 1A
VAPOR INTRUSION PATHWAYS
PRIMARY PATHWAYS
Resident
Non-Residential Worker
User Defined
Resident
Non-Residential Worker
CONTAMINANT MIGRATION PATHWAYS
Protection of Groundwater Use
Protection of Surface Water
North Carolina DEQ Risk Calculator
Exposure Point Concentrations
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: 20037-16-060
Exposure Unit ID: HMSG-2 Highest Concentrations (all sampling events)
Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.
Exposure Point Concentration
(ug/m3)
Justification for Exposure Point Concentration CAS Number Chemical Minimum Concentration (Qualifier)
Maximum Concentration (Qualifier)Units Location of Maximum Concentration
Detection Frequency
Range of Detection Limits
Concentration Used for Screening
Background Value
Screening Toxicity Value (Screening Level) (n/c)
Potential ARAR/TBC Value
Potential ARAR/TBC Source
COPC Flag (Y/N)
Rationale for Selection or Deletion
197 Table 1.0 67-64-1 Acetone ug/m3 12/7/2018
4.8 Table 1.0 71-43-2 Benzene ug/m3 12/7/2018
17 Table 1.0 75-15-0 Carbon Disulfide ug/m3 12/7/2018
11 Table 1.0 74-87-3 Chloromethane ug/m3 2/28/2019
7.2 Table 1.0 110-82-7 Cyclohexane ug/m3 12/7/2018
2.5 Table 1.0 75-71-8 Dichlorodifluoromethane ug/m3 1/31/2019
0 Table 1.0 156-59-2 Dichloroethylene, 1,2-cis-ug/m3
18 Table 1.0 142-82-5 Heptane, N-ug/m3 12/7/2018
24.6 Table 1.0 110-54-3 Hexane, N-ug/m3 2/28/2019
0 Table 1.0 591-78-6 Hexanone, 2-ug/m3
8.3 Table 1.0 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 2/28/2019
0 Table 1.0 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 2/28/2019
213 Table 1.0 75-09-2 Methylene Chloride ug/m3 1/31/2019
0 Table 1.0 91-20-3 ~Naphthalene ug/m3
57.4 Table 1.0 115-07-1 Propylene ug/m3 12/7/2018
0 Table 1.0 100-42-5 Styrene ug/m3
406 Table 1.0 127-18-4 Tetrachloroethylene ug/m3 12/30/2018
10 Table 1.0 108-88-3 Toluene ug/m3 12/7/2018
1.7 Table 1.0 79-01-6 Trichloroethylene ug/m3 2/28/2019
5.3 Table 1.0 75-69-4 Trichlorofluoromethane ug/m3 2/28/2019
0 Table 1.0 95-63-6 Trimethylbenzene, 1,2,4-ug/m3
0 Table 1.0 108-67-8 Trimethylbenzene, 1,3,5-ug/m3
0 Table 1.0 75-01-4 Vinyl Chloride ug/m3
4.3 Table 1.0 106-42-3 Xylene, P-ug/m3 12/7/2018
4.3 Table 1.0 108-38-3 Xylene, m-ug/m3 12/7/2018
0 Table 1.0 95-47-6 Xylene, o-ug/m3
Input Form 2E
Soil Gas Exposure Point Concentration Table
North Carolina DEQ Risk Calculator
Summary of Risk Assessment Output Output Form 1A
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: 20037-16-060
Exposure Unit ID: HMSG-2 Highest Concentrations (all sampling events)
Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded?
Soil Combined Pathways NC NC NC
Groundwater Combined Pathways*NC NC NC
Soil Combined Pathways NC NC NC
Groundwater Combined Pathways*NC NC NC
Construction Worker Soil Combined Pathways NC NC NC
Soil Combined Pathways NC NC NC
Surface Water Combined Pathways*NC NC NC
Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded?
Groundwater to Indoor Air NC NC NC
Soil Gas to Indoor Air 1.7E-06 3.4E-01 NO
Indoor Air NC NC NC
Groundwater to Indoor Air NC NC NC
Soil Gas to Indoor Air NC NC NC
Indoor Air NC NC NC
Pathway Source
Source Soil NC
Source Groundwater NC
Source Soil NC
Source Groundwater NC
PRIMARY CALCULATORS
Resident
Non-Residential Worker
User Defined
2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed
the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-
based closure.
Protection of Surface Water Exceedence of 2B at POE?
Exceedence of 2B at POE?
VAPOR INTRUSION CALCULATORS
Resident
Non-Residential Worker
CONTAMINANT MIGRATION CALCULATORS
Target POE Concentrations Exceeded?
Protection of Groundwater Use Exceedence of 2L at POE?
Exceedence of 2L at POE?
1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for
lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations.
Notes:
North Carolina DEQ Risk Calculator
DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: 20037-16-060
Exposure Unit ID: HMSG-2 Highest Concentrations (all sampling events)
CAS #Chemical Name:
Soil Gas Concentration
(ug/m3)
Calculated
Indoor Air
Concentration
(ug/m3)
Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06
Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2
Calculated
Carcinogenic
Risk
Calculated
Non-
Carcinogenic
Hazard
Quotient67-64-1 Acetone 197 5.91 -6.5E+03 1.8E-0471-43-2 Benzene 4.8 0.144 3.6E-01 6.3E+00 4.0E-07 4.6E-03
75-15-0 Carbon Disulfide 17 0.51 -1.5E+02 7.0E-0474-87-3 Chloromethane 11 0.33 -1.9E+01 3.5E-03110-82-7 Cyclohexane 7.2 0.216 -1.3E+03 3.5E-0575-71-8 Dichlorodifluoromethane 2.5 0.075 -2.1E+01 7.2E-04
156-59-2 Dichloroethylene, 1,2-cis-0 0 --142-82-5 Heptane, N-18 0.54 -8.3E+01 1.3E-03110-54-3 Hexane, N-24.6 0.738 -1.5E+02 1.0E-03591-78-6 Hexanone, 2-0 0 -6.3E+00 0.0E+00
78-93-3 Methyl Ethyl Ketone (2-Butanone)8.3 0.249 -1.0E+03 4.8E-05108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)0 0 -6.3E+02 0.0E+00
75-09-2 Methylene Chloride 213 6.39 1.0E+02 1.3E+02 6.3E-08 1.0E-0291-20-3 ~Naphthalene 0 0 8.3E-02 6.3E-01 0.0E+00 0.0E+00115-07-1 Propylene 57.4 1.722 -6.3E+02 5.5E-04100-42-5 Styrene 0 0 -2.1E+02 0.0E+00
127-18-4 Tetrachloroethylene 406 12.18 1.1E+01 8.3E+00 1.1E-06 2.9E-01
108-88-3 Toluene 10 0.3 -1.0E+03 5.8E-05
79-01-6 Trichloroethylene 1.7 0.051 4.8E-01 4.2E-01 1.1E-07 2.4E-02
75-69-4 Trichlorofluoromethane 5.3 0.159 --95-63-6 Trimethylbenzene, 1,2,4-0 0 -1.3E+01 0.0E+00108-67-8 Trimethylbenzene, 1,3,5-0 0 -1.3E+01 0.0E+00
75-01-4 Vinyl Chloride 0 0 1.7E-01 2.1E+01 0.0E+00 0.0E+00
106-42-3 Xylene, P-4.3 0.129 -2.1E+01 1.2E-03108-38-3 Xylene, m-4.3 0.129 -2.1E+01 1.2E-0395-47-6 Xylene, o-0 0 -2.1E+01 0.0E+00
Cumulative:1.7E-06 3.4E-01
All concentrations are in ug/m3
Output Form 3B
Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion
risk, no risk values are calculated for these chemicals.
North Carolina DEQ Risk Calculator
Version Date:
Basis:
Site Name:
Site Address:
DEQ Section:
Site ID:
Exposure Unit ID:Submittal Date:
Reviewed By:
HMSG-2 - Last 3 Sample Events Highest Detections
North Carolina Department of Environmental Quality
Risk Calculator
Highland Mill #3
N. Brevard and N. Davidson
Brownfields
20037-16-060
February 2018
November 2017 EPA RSL Table
4/24/2019
Prepared By:Patrick Lowery
SUMMIT ELT
MZ
North Carolina DEQ Risk Calculator
Complete Exposure Pathways
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: 20037-16-060
Exposure Unit ID: HMSG-2 - Last 3 Sample Events Highest Detections
Note: Risk output will only be calculated for complete exposure pathways.
Receptor Pathway
Check box if
pathway
complete
Soil Combined Pathways
Groundwater Combined Pathways
Soil Combined Pathways
Groundwater Combined Pathways
Construction Worker Soil Combined Pathways
Soil Combined Pathways
Surface Water Combined Pathways
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Source Soil
Source Groundwater
Source Soil
Source Groundwater
Resident
Non-Residential Worker
CONTAMINANT MIGRATION PATHWAYS
Protection of Groundwater Use
Protection of Surface Water
Input Form 1A
VAPOR INTRUSION PATHWAYS
PRIMARY PATHWAYS
Resident
Non-Residential Worker
User Defined
North Carolina DEQ Risk Calculator
Exposure Point Concentrations
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: 20037-16-060
Exposure Unit ID: HMSG-2 - Last 3 Sample Events Highest Detections
Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.
Exposure Point Concentration
(ug/m3)
Justification for Exposure Point Concentration CAS Number Chemical Minimum Concentration (Qualifier)
Maximum Concentration (Qualifier)Units Location of Maximum Concentration
Detection Frequency
Range of Detection Limits
Concentration Used for Screening
Background Value
Screening Toxicity Value (Screening Level) (n/c)
Potential ARAR/TBC Value
Potential ARAR/TBC Source
COPC Flag (Y/N)
Rationale for Selection or Deletion
39.8 Table 1.0 67-64-1 Acetone ug/m3 1/31/2019
0.9 Table 1.0 71-43-2 Benzene ug/m3 1/31/2019
1.7 Table 1.0 75-15-0 Carbon Disulfide ug/m3 2/28/2019
11 Table 1.0 74-87-3 Chloromethane ug/m3 2/28/2019
2.5 Table 1.0 75-71-8 Dichlorodifluoromethane ug/m3 1/31/2019
24.6 Table 1.0 110-54-3 Hexane, N-ug/m3 2/28/2019
8.3 Table 1.0 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 2/28/2019
213 Table 1.0 75-09-2 Methylene Chloride ug/m3 1/31/2019
252 Table 1.0 127-18-4 Tetrachloroethylene ug/m3 2/28/2019
4.2 Table 1.0 108-88-3 Toluene ug/m3 1/31/2019
1.7 Table 1.0 79-01-6 Trichloroethylene ug/m3 2/28/2019
5.3 Table 1.0 75-69-4 Trichlorofluoromethane ug/m3 2/28/2019
Input Form 2E
Soil Gas Exposure Point Concentration Table
North Carolina DEQ Risk Calculator
Summary of Risk Assessment Output Output Form 1A
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: 20037-16-060
Exposure Unit ID: HMSG-2 - Last 3 Sample Events Highest Detections
Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded?
Soil Combined Pathways NC NC NC
Groundwater Combined Pathways*NC NC NC
Soil Combined Pathways NC NC NC
Groundwater Combined Pathways*NC NC NC
Construction Worker Soil Combined Pathways NC NC NC
Soil Combined Pathways NC NC NC
Surface Water Combined Pathways*NC NC NC
Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded?
Groundwater to Indoor Air NC NC NC
Soil Gas to Indoor Air 9.4E-07 2.2E-01 NO
Indoor Air NC NC NC
Groundwater to Indoor Air NC NC NC
Soil Gas to Indoor Air NC NC NC
Indoor Air NC NC NC
Pathway Source
Source Soil NC
Source Groundwater NC
Source Soil NC
Source Groundwater NC
2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed
the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-
based closure.
Protection of Surface Water Exceedence of 2B at POE?
Exceedence of 2B at POE?
VAPOR INTRUSION CALCULATORS
Resident
Non-Residential Worker
CONTAMINANT MIGRATION CALCULATORS
Target POE Concentrations Exceeded?
Protection of Groundwater Use Exceedence of 2L at POE?
Exceedence of 2L at POE?
1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for
lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations.
Notes:
PRIMARY CALCULATORS
Resident
Non-Residential Worker
User Defined
North Carolina DEQ Risk Calculator
DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air
Version Date: February 2018
Basis: November 2017 EPA RSL Table
Site ID: 20037-16-060
Exposure Unit ID: HMSG-2 - Last 3 Sample Events Highest Detections
CAS #Chemical Name:
Soil Gas Concentration
(ug/m3)
Calculated
Indoor Air
Concentration
(ug/m3)
Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06
Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2
Calculated
Carcinogenic
Risk
Calculated
Non-
Carcinogenic
Hazard
Quotient67-64-1 Acetone 39.8 1.194 -6.5E+03 3.7E-0571-43-2 Benzene 0.9 0.027 3.6E-01 6.3E+00 7.5E-08 8.6E-04
75-15-0 Carbon Disulfide 1.7 0.051 -1.5E+02 7.0E-0574-87-3 Chloromethane 11 0.33 -1.9E+01 3.5E-03110-82-7 Cyclohexane -1.3E+0375-71-8 Dichlorodifluoromethane 2.5 0.075 -2.1E+01 7.2E-04
156-59-2 Dichloroethylene, 1,2-cis---142-82-5 Heptane, N--8.3E+01110-54-3 Hexane, N-24.6 0.738 -1.5E+02 1.0E-03591-78-6 Hexanone, 2--6.3E+00
78-93-3 Methyl Ethyl Ketone (2-Butanone)8.3 0.249 -1.0E+03 4.8E-05108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)-6.3E+02
75-09-2 Methylene Chloride 213 6.39 1.0E+02 1.3E+02 6.3E-08 1.0E-0291-20-3 ~Naphthalene 8.3E-02 6.3E-01115-07-1 Propylene -6.3E+02100-42-5 Styrene -2.1E+02
127-18-4 Tetrachloroethylene 252 7.56 1.1E+01 8.3E+00 7.0E-07 1.8E-01
108-88-3 Toluene 4.2 0.126 -1.0E+03 2.4E-05
79-01-6 Trichloroethylene 1.7 0.051 4.8E-01 4.2E-01 1.1E-07 2.4E-02
75-69-4 Trichlorofluoromethane 5.3 0.159 --95-63-6 Trimethylbenzene, 1,2,4--1.3E+01108-67-8 Trimethylbenzene, 1,3,5--1.3E+01
75-01-4 Vinyl Chloride 1.7E-01 2.1E+01
106-42-3 Xylene, P--2.1E+01108-38-3 Xylene, m--2.1E+0195-47-6 Xylene, o--2.1E+01
Cumulative:9.4E-07 2.2E-01
All concentrations are in ug/m3
Output Form 3B
Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion
risk, no risk values are calculated for these chemicals.
North Carolina DEQ Risk Calculator
VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina April 24, 2019

D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Unit 11 3-28-19\Appendix VII - Sample Collection Field Logs.rtf

APPENDIX VII
SAMPLE COLLECTION LOGS/FIELD REPORTS

VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina April 24, 2019

D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Unit 11 3-28-19\Appendix VIII - Potential Contaminant Sources.rtf

APPENDIX VIII
POTENTIAL CONTAMINANT SOURCES / SDS

Safety Data Sheet

Revision Number: 003.1 Issue date: 05/22/2018

IDH number: 1652275 Product name: Loctite PL400 Subfloor Adhesive
Page 1 of 8

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: Loctite PL400 Subfloor Adhesive IDH number: 1652275 Product type: Assembly adhesive, solvent
Restriction of Use: None identified Region: United States
Company address: Contact information:
Henkel Corporation
One Henkel Way Rocky Hill, Connecticut 06067
Telephone: [phone]
MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: www.henkelna.com

2. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
DANGER: HIGHLY FLAMMABLE LIQUID AND VAPOR.
CAUSES SERIOUS EYE IRRITATION.

HAZARD CLASS HAZARD CATEGORY
FLAMMABLE LIQUID 2
EYE IRRITATION 2A

PICTOGRAM(S)

Precautionary Statements

Prevention: Keep away from heat, sparks, open flames, hot surfaces - no smoking. Keep container tightly closed. No release into water. Use explosion-proof equipment. Use non-sparking tools. Take
action to prevent static discharges. Wash affected area thoroughly after handling. Wear
protective gloves, eye protection, and face protection.
Response: If on skin (or hair): Take off immediately all contaminated clothing. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical attention. In case of fire: Use foam, dry
chemical or carbon dioxide to extinguish.
Storage: Store in a well-ventilated place. Keep cool.
Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local
governmental regulations.

Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the
United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous Component(s) CAS Number Percentage*
Limestone 1317-65-3 20 - 30

IDH number: 1652275 Product name: Loctite PL400 Subfloor Adhesive
Page 2 of 8

Kaolin 1332-58-7 10 - 20
Acetone 67-64-1 10 - 20
Resin acids and Rosin acids, esters with
pentaerythritol 8050-26-8 1 - 5
Methyl acetate 79-20-9 1 - 5
Titanium dioxide 13463-67-7 0.1 - 1
Quartz (SiO2), <1% respirable 14808-60-7 0.1 - 1

* Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections.

4. FIRST AID MEASURES

Inhalation: If inhaled, immediately remove the affected person to fresh air. If breathing is difficult, give oxygen. If symptoms develop and persist, get medical attention.

Skin contact: Immediately wash skin thoroughly with soap and water. If symptoms develop
and persist, get medical attention.
Eye contact: In case of contact with the eyes, rinse immediately with plenty of water for 15
minutes, and seek immediate medical attention.

Ingestion: Do not induce vomiting, seek medical advice immediately.
Symptoms: See Section 11.

5. FIRE FIGHTING MEASURES

Extinguishing media: Foam, dry chemical or carbon dioxide. In case of fire, keep containers cool
with water spray.

Special firefighting procedures: Wear a self-contained breathing apparatus with a full face piece operated in
pressure-demand or other positive pressure mode. Wear full protective
clothing.

Unusual fire or explosion hazards: Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air. Vapors are heavier than air and may travel
along floor to an ignition source.

Hazardous combustion products: Upon decomposition, this product emits carbon monoxide, carbon dioxide
and/or low molecular weight hydrocarbons.
6. ACCIDENTAL RELEASE MEASURES

Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.

Environmental precautions: Eliminate all sources of ignition or flammables that may come into contact with
a spill of this material. Ventilate area. Prevent further leakage or spillage if
safe to do so. Wear appropriate protective equipment and clothing during
clean-up. Do not allow product to enter sewer or waterways.
Clean-up methods: Use noncombustible absorbent material such as sand. Use non-sparking tools
for clean-up. Absorb spill with inert material. Shovel material into appropriate
container for disposal. Dispose of according to Federal, State and local
governmental regulations.

IDH number: 1652275 Product name: Loctite PL400 Subfloor Adhesive
Page 3 of 8

7. HANDLING AND STORAGE

Handling: Do not pressurize, cut, heat or weld containers. Empty product containers
may contain product residue. Do not reuse empty containers. Use only in
well-ventilated areas. Keep out of the reach of children. Keep away from heat,
spark and flame. Containers should be grounded and bonded to the receiving
container.

Storage: For safe storage, store between -20 °C (-4°F) and 50 °C (122°F)
Keep away from heat, spark and flame. Keep containers closed when not in
use.

For information on product shelf life, please review labels on container or check the Technical Data Sheet.

IDH number: 1652275 Product name: Loctite PL400 Subfloor Adhesive
Page 4 of 8

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.

Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER
Limestone 10 mg/m3 TWA Total
dust.
5 mg/m3 PEL
Respirable fraction.
15 mg/m3 PEL Total
dust.
None None
Kaolin 2 mg/m3 TWA
Respirable fraction.
5 mg/m3 PEL
Respirable fraction.
15 mg/m3 PEL Total
dust. 15 MPPCF TWA
Respirable fraction.
50 MPPCF TWA
Total dust.
5 mg/m3 TWA Respirable fraction.
15 mg/m3 TWA Total
dust.
None None
Acetone 250 ppm TWA
500 ppm STEL
1,000 ppm (2,400
mg/m3) PEL None None
Resin acids and Rosin acids, esters with
pentaerythritol None None None None
Methyl acetate 200 ppm TWA
250 ppm STEL
200 ppm (610
mg/m3) PEL None None
Titanium dioxide 10 mg/m3 TWA
15 mg/m3 PEL Total
dust.
15 MPPCF TWA
Respirable fraction.
15 mg/m3 TWA Total
dust. 50 MPPCF TWA
Total dust.
5 mg/m3 TWA
Respirable fraction.
None None
Quartz (SiO2), <1% respirable 0.025 mg/m3 TWA
Respirable fraction.
2.4 MPPCF TWA
Respirable.
0.1 mg/m3 TWA
Respirable.
0.05 mg/m3 TWA
(Respirable dust.)
(Respirable dust.)
0.025 mg/m3
OSHA_ACT
(Respirable dust.)
0.05 mg/m3 PEL
Respirable dust.
None None

Engineering controls: Local exhaust ventilation is recommended when general ventilation is not
sufficient to control airborne contamination below occupational exposure
limits.
Respiratory protection: Use a NIOSH approved air-purifying respirator if the potential to exceed
established exposure limits exists. When workplace hazards warrant the use
of a respirator, appropriate respirators must be used, and a program that
follows 29 CFR 1910.134 must be followed.
Eye/face protection: Safety goggles or safety glasses with side shields.

Skin protection: Chemical resistant, impermeable gloves.

IDH number: 1652275 Product name: Loctite PL400 Subfloor Adhesive
Page 5 of 8

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Liquid
Color: Beige
Odor: Acetone-like Odor threshold: Not available. pH: 7
Vapor pressure: Not available.
Boiling point/range: 56 - 57 °C (132.8 - 134.6 °F)
Melting point/ range: < 0 °C (< 32°F)
Specific gravity: 1.44 Vapor density: 2.0
Flash point: -17 °C (1.4 °F)
Flammable/Explosive limits - lower: Not available.
Flammable/Explosive limits - upper: Not available.
Autoignition temperature: Not available. Flammability: Not applicable
Evaporation rate: 14.4
Solubility in water: Slightly soluble
Partition coefficient (n-octanol/water): Not available. VOC content: 0.22 %; 5.67 g/l (by weight, calculated using CARB method; g/L less water,
less exempts calculated using SCAQMD method)
Viscosity: 375,000 mPa.s
Decomposition temperature: Not available.

10. STABILITY AND REACTIVITY
Stability: Stable under normal conditions of storage and use.

Hazardous reactions: Will not occur.

Hazardous decomposition
products:
Carbon dioxide, carbon monoxide and irritating and/or toxic gases and particulate may be
generated by thermal decomposition or combustion.

Incompatible materials: Strong oxidizing agents.

Reactivity: Not available.
Conditions to avoid: Heat, flames, sparks and other sources of ignition.

11. TOXICOLOGICAL INFORMATION

Relevant routes of exposure: Inhalation, Skin contact

IDH number: 1652275 Product name: Loctite PL400 Subfloor Adhesive
Page 6 of 8

Potential Health Effects/Symptoms

Inhalation: Irritates the nose, throat and respiratory system. Exposure to high doses may cause central nervous system depression. Such doses may also cause adverse effects in the liver, kidneys,
and lungs. Abrasion of cured material such as by sanding or grinding could release respirable
particles of silica quartz, a cancer hazard by inhalation. Normal use of this product causes no
such release. Reports have associated repeated and prolonged overexposure to solvents with
permanent brain and nervous system damage. Intentional misuse by deliberately concentrating
and inhaling the contents may be harmful or fatal. Skin contact: Prolonged and/or repeated skin contact with this product may cause irritation/dermatitis.
Eye contact: Contact with eyes can cause eye irritation. Symptoms may include stinging, tearing, redness,
swelling, and blurred vision.
Ingestion: Ingestion can cause gastrointestinal irritation, nausea, vomiting and diarrhea.

Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects
Limestone None Nuisance dust
Kaolin Oral LD50 (Rat) = > 5,000 mg/kg
Dermal LD50 (Rat) = > 5,000 mg/kg Nuisance dust
Acetone
Oral LD50 (Mouse) = 5.2 g/kg Oral LD50 (Mouse) = 3,000 mg/kg
Oral LD50 (Rabbit) = 5,340 mg/kg
Oral LD50 (Rat) = 5,800 mg/kg
Oral LD50 (Rat) = 9,800 mg/kg
Dermal LD50 (Rabbit) = 20,000 mg/kg
Inhalation LC50 (Rat, 4 h) = 76 mg/l
Central nervous system, Irritant
Resin acids and Rosin acids, esters with
pentaerythritol None Irritant
Methyl acetate Oral LD50 (Rabbit) = 3.7 g/kg Blood, Central nervous system, Eyes, Irritant
Titanium dioxide None Irritant, Respiratory, Some evidence of
carcinogenicity
Quartz (SiO2), <1% respirable None Immune system, Lung, Some evidence of
carcinogenicity

Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen
(Specifically Regulated)
Limestone No No No
Kaolin No No No
Acetone No No No
Resin acids and Rosin acids, esters with
pentaerythritol No No No
Methyl acetate No No No
Titanium dioxide No Group 2B No
Quartz (SiO2), <1% respirable Known To Be Human
Carcinogen. Group 1 Yes

12. ECOLOGICAL INFORMATION

Ecological information: Not available.

IDH number: 1652275 Product name: Loctite PL400 Subfloor Adhesive
Page 7 of 8

13. DISPOSAL CONSIDERATIONS

Information provided is for unused product only.

Recommended method of disposal: Dispose of according to Federal, State and local governmental regulations. Hazardous waste number: It is the responsibility of the user to determine if an item is hazardous as
defined in the Resource Conservation and Recovery Act (RCRA) at the time of
disposal. Product uses, transformations, mixtures, processes, etc., may
render the resulting material hazardous, under the criteria of ignitability,
corrosivity, reactivity and toxicity characteristics of the Toxicity Characteristics
Leaching Procedure (TCLP) 40 CFR 261.20-24. If discarded, this product is
considered a RCRA ignitable waste, D001.

14. TRANSPORT INFORMATION

The transport information provided in this section only applies to the material/formulation itself, and is not specific to any
package/configuration.

U.S. Department of Transportation Ground (49 CFR)
Proper shipping name: Adhesives
Hazard class or division: 3
Identification number: UN 1133
Packing group: II

International Air Transportation (ICAO/IATA)
Proper shipping name: Adhesives Hazard class or division: 3 Identification number: UN 1133
Packing group: II

Water Transportation (IMO/IMDG)
Proper shipping name: ADHESIVES Hazard class or division: 3
Identification number: UN 1133
Packing group: II

15. REGULATORY INFORMATION
United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.
TSCA 12 (b) Export Notification: None above reporting de minimis

CERCLA/SARA Section 302 EHS: None above reporting de minimis.
CERCLA/SARA Section 311/312: Fire, Immediate Health, Delayed Health
CERCLA/SARA Section 313: None above reporting de minimis.
California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This
product contains a chemical known to the State of California to cause birth defects or other
reproductive harm.

Canada Regulatory Information

CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic
Substances List.

16. OTHER INFORMATION
This safety data sheet contains changes from the previous version in sections: This Safety Data Sheet contains changes
from the previous version in Section(s): 2, 3, 16

IDH number: 1652275 Product name: Loctite PL400 Subfloor Adhesive
Page 8 of 8

Prepared by: Product Safety and Regulatory Affairs

Issue date: 05/22/2018 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.

09/04/2014Revision:
10/06/2014Printed:
Page: 1
Jasco Xylol XyleneSAFETY DATA SHEET
06/16/2011Supersedes Revision:
Jasco Xylol XyleneProduct Name:
W. M. BarrCompany Name:
2105 Channel Avenue
Memphis, TN 38113
3E 24 Hour Emergency ContactEmergency Contact:[phone]
W.M. Barr Customer ServiceInformation:[phone]
[phone]
Phone Number:
Paint, stain, and varnish thinning.Intended Use:
www.wmbarr.comWeb site address:
GJXY24, QJXY24, CJXY24, GJXY170Synonyms:
1. PRODUCT AND COMPANY IDENTIFICATION
2. HAZARDS IDENTIFICATION
P233: Keep container tightly closed.
P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/lighting equipment.
P243: Take precautionary measures against static discharge.
P242: Use only non-sparking tools.
P271: Use only outdoors or in a well-ventilated area.
P261: Avoid breathing gas/mist/vapours/spray.
P264: Wash hands thoroughly after handling.
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P281: Use personal protective equipment as required.
GHS Precaution Phrases:
P370+378: In case of fire, use dry chemical to extinguish.
P303+361+353: IF ON SKIN (or hair): Remove/take off immediately all contaminated
clothing. Rinse skin with water/shower.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
P312: Call a POISON CENTER/doctor if you feel unwell.
P302+352: IF ON SKIN: Wash with plenty of soap and water.
P322: Specific measures see label.
P363: Wash contaminated clothing before reuse.
P321: Specific treatment see label.
P332+313: If skin irritation occurs, get medical advice/attention.
GHS Response Phrases:
H225: Highly flammable liquid and vapor.
H332: Harmful if inhaled.
H312: Harmful in contact with skin.
H315: Causes skin irritation.
H351: Suspected of causing cancer.
GHS Hazard Phrases:
Flammable Liquids, Category 2
Acute Toxicity: Inhalation, Category 4
Acute Toxicity: Skin, Category 4
Skin Corrosion/Irritation, Category 2
Carcinogenicity, Category 2
DangerGHS Signal Word:
Licensed to W.M. Barr and Company GHS format
09/04/2014Revision:
10/06/2014Printed:
Page: 2
Jasco Xylol XyleneSAFETY DATA SHEET
06/16/2011Supersedes Revision:
P362: Take off contaminated clothing.
P308+313: IF exposed or concerned: Get medical attention/advice.
P403+235: Store in cool/well-ventilated place.
P501: Dispose of contents/container according to local, state and federal regulations.
P405: Store locked up.
GHS Storage and Disposal
Phrases:
Hazard Rating System:Instability
Special Hazard
Health
FlammabilityHEALTH
FLAMMABILITY
PPE
PHYSICAL
2
0
3
*
X
2 3 0
NFPA:HMIS:
This material is classified as hazardous under OSHA regulations.OSHA Regulatory Status:
Diseases of the skin, liver, and kidneys.Medical Conditions Generally
Aggravated By Exposure:
Inhalation Acute Exposure Effects:
Vapor harmful. May cause dizziness, headache, irritation of respiratory tract, weakness,
drowsiness, depression of central nervous system, and watering of eyes. Severe
overexposure may cause unconsciousness, anesthesia, irregular heartbeat, and death.
Intentional misuse of this product by deliberately concentrating and inhaling can be
harmful or fatal.
Skin Contact Acute Exposure Effects:
This product is a skin irritant. It may be absorbed through the skin. It may cause
irritation, dermatitis, drying of skin, and numbness in fingers and arms. May increase
severity of symptoms listed under inhalation.
Eye Contact Acute Exposure Effects:
This material is an eye irritant. It may cause irritation, redness, stinging, tearing,
excessive swelling of the conjunctiva; and or excessive blinking.
Ingestion Acute Exposure Effects:
Harmful or fatal if swallowed. May cause nausea, vomiting, gastrointestinal irritation, or
diarrhea.
Chronic Exposure Effects:
Reports have associated repeated and prolonged overexposure to solvents with
neurological and other physiological damage. Prolonged or repeated contact may cause
dermatitis. May cause skin irritation, permanent central nervous system changes, kidney
damage, and liver damage.
Potential Health Effects
(Acute and Chronic):
CAS # Hazardous Components (Chemical Name)
3. COMPOSITION/INFORMATION ON INGREDIENTS
Concentration
1330-20-7 Xylene (mixed isomers) {Benzene, dimethyl-} 60.0 -100.0 %
100-41-4 Ethylbenzene {Ethylbenzol; Phenylethane} 10.0 -30.0 %
Ethylbenzene is a component of Xylene.Additional Chemical
Information
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4. FIRST AID MEASURES
Inhalation:
If user experiences breathing difficulty, move to air free of vapors. Administer oxygen or
artificial respiration until medical assistance can be rendered.
Skin Contact:
Irritation may result. Immediately wash with soap and water.
Eye Contact:
Immediately flush with water, remove any contact lenses, continue flushing with water for
at least 15 minutes, then get medical attention.
Ingestion:
Do not induce vomiting. Call you local poison control center, hospital emergency room,
or physician immediately for instructions.
Emergency and First Aid
Procedures:
Call your local poison control center for further information.Note to Physician:
See Potential Health Effects.Signs and Symptoms Of
Exposure:
5. FIRE FIGHTING MEASURES
Flash Pt:81.00 F Method Used: Closed Cup
Self-contained respiratory protection should be provided for fire fighters fighting fires in
buildings or confined areas. Storage containers exposed to fire should be kept cool with
water spay to prevent pressure build-up. Stay away from heads of containers that have
been exposed to intense heat or flame.
Fire Fighting Instructions:
Flammable Liquid! This material releases vapors at or below ambient temperatures.
When
mixed with air in certain proportions and exposed to an ignition source, its vapor can
cause a
flash fire. Use only with adequate ventilation. Vapors are heavier than air and may travel
long distances along the ground to an ignition source and flash back. A vapor and air
mixture can create an explosion hazard in confined spaces such as sewers. If container
is
not properly cooled, it can rupture in the heat of a fire.
Flammable Properties and
Hazards:
Autoignition Pt:432.00 C
Explosive Limits:LEL: AP 1% UEL: AP 7%
NFPA Class IC flammable liquid
Use carbon dioxide, dry powder, or foam.Suitable Extinguishing Media:
6. ACCIDENTAL RELEASE MEASURES
Vapors may cause flash fire or ignite explosively.
Clean up: Keep unnecessary people away; isolate hazard area and deny entry. Stay
upwind, out of low areas, and ventilate closed spaces before entering. Shut off ignition
sources; keep flares, smoking or flames out of hazard area. Use non-sparking tools.
Use proper bonding and grounding methods for all equipment and processes. Keep out
of waterways and bodies of water. Be cautious of vapors collecting in small enclosed
spaces, sewers, low lying areas, confined spaces, etc.
Small spills: Take up with sand, earth or other noncombustible absorbent material and
place in a plastic container where applicable.
Steps To Be Taken In Case
Material Is Released Or
Spilled:
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Large spills: Dike far ahead of spill for later disposal.
Waste Disposal: Dispose in accordance with applicable local, state and federal
regulations.
7. HANDLING AND STORAGE
Read carefully all cautions and directions on product label before use. Since empty
container retains residue, follow all label warnings even after container is empty.
Dispose of empty container according to all regulations. Do not reuse this container.
Do not use this product near any source of heat or open flame, furnace areas, pilot
lights, stoves, etc.
Do not use in small enclosed spaces, such as basements and bathrooms. Vapors can
accumulate and explode if ignited.
Do not spread this product over large surface areas because fire and health safety risks
will increase dramatically.
Precautions To Be Taken in
Handling:
Keep container tightly closed when not in use. Store in a cool, dry place. Do not store
near flames or at elevated temperatures.
Precautions To Be Taken in
Storing:
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
OSHA TWA ACGIH TWACAS # Partial Chemical Name Other Limits
PEL: 100 ppm TLV: 100 ppm
STEL: 150 ppm
1330-20-7 Xylene (mixed isomers) {Benzene,
dimethyl-}
No data.
PEL: 100 ppm TLV: 100 ppm
STEL: 125 ppm
100-41-4 Ethylbenzene {Ethylbenzol;
Phenylethane}
No data.
For OSHA controlled work place and other regular users --Use only with adequate
ventilation under engineered air control systems designed to prevent exceeding
appropriate TLV. For occasional use, where engineered air control is not feasible, use
properly maintained and properly fitted NIOSH approved respirator for organic solvent
vapors. A dust mask does not provided protection against vapors.
Respiratory Equipment
(Specify Type):
Safety glasses, chemical goggles or face shields are recommended to safeguard against
potential eye contact, irritation, or injury. Contact lenses should not be worn while
working with chemicals.
Eye Protection:
Wear gloves with as much resistance to the chemical ingredients as possible. Glove
materials such as nitrile rubber may provide protection. Glove selection should be based
on chemicals being used and conditions of use. Consult your glove supplier for
additional information. Gloves contaminated with product should be discarded and not
reused.
Protective Gloves:
Various application methods can dictate the use of additional protective safety
equipment, such as impermeable aprons, etc., to minimize exposure.
Other Protective Clothing:
Use process enclosures, local exhaust ventilation, or other engineering controls to
control airborne levels below recommended exposure limits.
Use only with adequate ventilation to prevent buildup of vapors. Do not use in areas
where vapors can accumulate and concentrate, such as basements, bathrooms or small
Engineering Controls
(Ventilation etc.):
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enclosed areas. Whenever possible, use outdoors in an open air area. If using indoors
open all windows and doors and maintain a cross ventilation of moving fresh air across
the work area. If strong odor is noticed or you experience slight dizziness, headache,
nausea or eye-watering -- STOP -- ventilation is inadequate. Leave area immediately
and move to fresh air.
Wash hands thoroughly after use and before eating, drinking, or smoking.
Do not eat, drink, or smoke in the work area.
Discard any clothing or other protective equipment that cannot be decontaminated.
Facilities storing or handling this material should be equipped with an emergency
eyewash and safety shower.
Work/Hygienic/Maintenance
Practices:
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical States:[ ] Gas [ X ] Liquid [ ] Solid
Melting Point:-48.00 C - -25.00 C
Boiling Point:280.00 F - 288.00 F
Autoignition Pt:432.00 C
Flash Pt:81.00 F Method Used: Closed Cup
Explosive Limits:LEL: AP 1% UEL: AP 7%
Specific Gravity (Water = 1): 0.87
Density: 7.18 LB/GL at 77.0 F
Sweet, pungent aromatic
hydrocarbon
Appearance and Odor:
Vapor Pressure (vs. Air or
mm Hg):
7 MM HG at 20.0 C
Vapor Density (vs. Air = 1):No data.
Evaporation Rate:No data.
Solubility in Water:No data.
Percent Volatile:99.999 % by weight.
VOC / Volume:872.0000 G/L
10. STABILITY AND REACTIVITY
No data available.Conditions To Avoid -
Instability:
Unstable [ ] Stable [ X ]Stability:
Incompatible with strong oxidizing agents.Incompatibility - Materials To
Avoid:
Decomposition may produce carbon monoxide and carbon dioxide.Hazardous Decomposition Or
Byproducts:
Will occur [ ] Will not occur [ X ]Possibility of Hazardous
Reactions:
No data available.Conditions To Avoid -
Hazardous Reactions:
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11. TOXICOLOGICAL INFORMATION
Overexposure to xylene may cause upper respiratory tract irritation, headache, cyanosis,
blood serum changes, CNS damage and narcosis. Effects may be increased by the use
of
alcoholic beverages. Evidence of liver and kidney impairment were reported in workers
recovering from a gross over-exposure.
Toxicological Information:
Xylene, all isomers:
Effects from Prolonged or Repeated Exposure:
Impaired neurological function was reported in workers exposed to solvents including
xylene.
Studies in laboratory animals have shown evidence of impaired hearing following high
levels
of exposure. Studies in laboratory animals suggest some changes in reproductive organs
following high levels of exposure but no significant effects on reproduction were
observed.
Studies in laboratory animals indicate skeletal and visceral malformations,
developmental
delays, and increased fetal resorptions following extremely high levels of maternal
exposure.
Chronic Toxicological
Effects:
CAS# 1330-20-7:
Acute toxicity, LC50, Inhalation, Rat, 5000. PPM, 4 H.
Result:
Behavioral: Muscle contraction or spasticity.
Lungs, Thorax, or Respiration:Other changes.
- Raw Material Data Handbook, Vol.1: Organic Solvents, 1974., National Assoc. of
Printing Ink Research Institute, Francis McDonald Sinclair Memorial Labor, Lehigh Univ.,
Bethlehem, PA 18015, Vol/p/yr: 1,123, 1974
Acute toxicity, LD50, Subcutaneous, Rat, 1700. MG/KG.
Result:
Kidney, Ureter, Bladder:Proteinuria.
Kidney, Ureter, Bladder:Other changes in urine composition.
- Raw Material Data Handbook, Vol.1: Organic Solvents, 1974., National Assoc. of
Printing Ink Research Institute, Francis McDonald Sinclair Memorial Labor, Lehigh Univ.,
Bethlehem, PA 18015, Vol/p/yr: 1,123, 1974
Standard Draize Test, Skin, Species: Rabbit, 100.0 %, Moderate.
Result:
Specific Developmental Abnormalities: Craniofacial (including nose and tongue).
- AMA Archives of Industrial Health., For publisher information, see AEHLAU, Chicago,
IL, Vol/p/yr: 14,387, 1956
CAS# 100-41-4:
Tumorigenic Effects:, TCLo, Inhalation, Rat, 750.0 ppm.
Result:
Tumorigenic: Carcinogenic by RTECS criteria.
Kidney, Ureter, Bladder: Tumors.
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CAS # Hazardous Components (Chemical Name) NTP
Adverse effects on the liver, kidney, bone marrow (changes in blood cell parameters)
were
observed in laboratory animals following high levels of exposure. The relevance of these
observations to humans is not clear at this time.
Ethyl Benzene:
Effects from Prolonged or Repeated Exposure:
Findings from a 2-year inhalation study in rodents conducted by NTP were as follows:
Effects
were observed only at the highest exposure level (750 ppm). At this level the incidence
of
renal tumors was elevated in male rats (tubular carcinomas) and female rats (tubular
adenomas). Also, the incidence of tumors was elevated in male mice (alveolar and
bronchiolar carcinomas) and female mice (hepatocellular carcinomas). IARC has
classified
ethyl benzene as “possibly carcinogenic to humans” (Group 2B). Studies in laboratory
animals indicate some evidence of post-implantation deaths following high levels of
maternal
exposure. The relevance of these findings to humans is not clear at this time. Studies in
laboratory animals indicate limited evidence of renal malformations, resorptions, and
developmental delays following high levels of maternal exposure. The relevance of these
findings to humans is not clear at this time. Studies in laboratory animals indicate some
evidence of adverse effects on the liver, kidney, thyroid, and pituitary gland.
IARC 2B - Possibly Carcinogenic to Humans
ACGIH A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans
ACGIH A4 - Not Classifiable as a Human Carcinogen.
Carcinogenicity/Other
Information:
IARC ACGIH OSHA
1330-20-7 Xylene (mixed isomers) {Benzene, dimethyl-} n.a. 3 A4 n.a.
100-41-4 Ethylbenzene {Ethylbenzol; Phenylethane} n.a. 2B A3 n.a.
No data available.
12. ECOLOGICAL INFORMATION
Dispose in accordance with local, state, and federal regulations.Waste Disposal Method:
13. DISPOSAL CONSIDERATIONS
14. TRANSPORT INFORMATION
XylenesDOT Proper Shipping Name:
3 FLAMMABLE LIQUIDDOT Hazard Class:
UN1307UN/NA Number:IIIPacking Group:
LAND TRANSPORT (US DOT):
For D.O.T. information, contact W.M. Barr Technical Services at 1-800-398-3892.
The shipper/supplier may apply one of the following exceptions: Combustible Liquid,
Consumer Commodity, Limited Quantity, Viscous Liquid, Does Not Sustain Combustion,
or others, as allowed under 49CFR Hazmat Regulations. Please consult 49CFR
Subchapter C to ensure that subsequent shipments comply with these exceptions.
Additional Transport
Information:
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15. REGULATORY INFORMATION
[X] Yes [ ] No Acute (immediate) Health Hazard
[X] Yes [ ] No Chronic (delayed) Health Hazard
[X] Yes [ ] No Fire Hazard
[ ] Yes [X] No Sudden Release of Pressure Hazard
[ ] Yes [X] No Reactive Hazard
This material meets the EPA
'Hazard Categories' defined
for SARA Title III Sections
311/312 as indicated:
CAS # Hazardous Components (Chemical Name) Other US EPA or State Lists
1330-20-7 Xylene (mixed isomers) {Benzene, dimethyl-} CAA HAP,ODC: HAP; CWA NPDES: Yes; TSCA: Yes -
Inventory; CA PROP.65: No
100-41-4 Ethylbenzene {Ethylbenzol; Phenylethane} CAA HAP,ODC: HAP; CWA NPDES: Yes; TSCA: Yes -
Inventory, 4 Test; CA PROP.65: Yes
All components of this material are listed on the TSCA Inventory or are exempt.Regulatory Information
Statement:
16. OTHER INFORMATION
No data available.Additional Information About
This Product:
The information contained herein is presented in good faith and believed to be accurate
as of the effective date shown above. This information is furnished without warranty of
any kind. Employers should use this information only as a supplement to other
information gathered by them and must make independent determination of suitability
and completeness of information from all sources to assure proper use of these
materials and the safety and health of employees. Any use of this data and information
must be determined by the user to be in accordance with applicable federal, state and
local laws and regulations.
Company Policy or
Disclaimer:
09/04/2014Revision Date:
W.M. Barr EHS Department [phone]Preparer Name:
Licensed to W.M. Barr and Company GHS format

Technical Data

MASTERLINE® Commercial Grade POLYURETHANE

PRODUCTION DESCRIPTION:

MASTERLINE® Polyurethane is a durable finish suitable for large volume applications such as meeting halls,
multiple-unit dwellings, and other commercial uses. It is available in Gloss, Semi-Gloss and Satin.

PRODUCT PROPORTIES:

DRY TIME AND CURE - Allow to dry fully for 8 hours before recoating
Wait overnight before allowing light traffic
Wait 48 hours before replacing furniture and rugs

COVERAGE - Approx. 500-600 sq. ft. per gallon

CLEAN-UP - Clean applicators with mineral spirits or paint thinner

STORAGE - Store at room temperature. Keep container tightly
closed

PHYSICAL PROPERITES:
RESIN TYPE Oil Modified Urethane
DENSITY (LBS/GAL) 7.30
SOLVENT Mineral Spirits
VISCOSITY 200 cps
% SOLIDS 44.0
VOC less than 550 grams/liter
FLASH POINT 105°F - Seta Flash

HEALTH/SAFETY HMIS RATING: Health 2
Flammability 2
Reactivity 0

CAUTION: COMBUSTIBLE: Keep away from heat and open flames.
VAPOR HARMFUL – use only with adequate ventilation
Avoid contact with skin and eyes. Wash hands after using.

KEEP OUT OF REACH OF CHILDREN
DO NOT TAKE INTERNALLY.

PRODUCT USE
DIRECTIONS:
New Wood Floors:
1. Prepare floor according to NOFMA or NWFA specifications.
2. Apply Masterline® Polyurethane using a lambswool applicator or a natural bristle brush at a coverage rat of
500-600 square feet per gallon. Application of thicker coats extends dry time.
3. Allow to dry fully for 8-10 hours, then screen the floor and tack with a cloth dampened with mineral spirits to
remove dust.
4. Apply at least two more coats in the same manner as steps 2 and 3. Additional coats may be applied if
desired. Be sure to allow each coat to dry fully and screen lightly between each coat.

10 Mountainview Rd., Upper Saddle River, NJ 07458-1933 ● Tel: [phone] ● Fax: [phone]

MASTERLINE® Commercial Grade POLYURETHANE

Screen and Recoat:
1. Clean floors with an abrasive pad dampened with mineral spirits to remove all grease, soap residue, oil, dirt,
etc. Once dry, screen using a No. 100 grit screen. Do not apply over floors previously finished with shellac,
lacquer, wax, or stains containing stearates, wax, or finishes in very poor condition in need of complete
removal.
2. See step 2 under New Wood Floors.

Old Wood Floors:
1. Sand floor to bare wood according to NOFMA or NWFA approved methods. Make sure to remove all
existing stain and finish.
2. Tack floor with cloth dampened with mineral spirits to remove all dust.
3. Follow steps 2 through 4 under New Wood Floors.

PRECAUTION: Polyurethane will have a slight ambering/darkening effect when applied over light-colored
surfaces. Do not apply over floors previously coated with wax, shellac, lacquer, or stains containing wax or
stearates.

SHEEN: SIZE SKU # CASE/PACK

550 VOC

Gloss Qt. 33460 4
Gal 33410 4
Five 33450 1
Semi-Gloss Qt. 33462 4
Gal 33412 4
Five 33452 1
Satin Qt. 33461 4
Gal 33411 4
Five 33451 1

5/16/10

Safety Data Sheet

Revision Number: 001.3 Issue date: 11/14/2014

IDH number: 1630096 Product name: OSI F-38 Drywall and Panel Adhesive
Page 1 of 7

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: OSI F-38 Drywall and Panel Adhesive IDH number: 1630096
Product type: Assembly adhesive, solvent
Restriction of Use: None identified Region: United States
Company address: Contact information:
Henkel Corporation
One Henkel Way
Rocky Hill, Connecticut 06067
Telephone: [phone]
MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-
4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY
Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887

2. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
DANGER: ABRASION COULD RELEASE RESPIRABLE PARTICLES OF SILICA
QUARTZ, A CANCER HAZARD BY INHALATION. NORMAL USE OF THIS
PRODUCT CAUSES NO SUCH RELEASE.

HIGHLY FLAMMABLE LIQUID AND VAPOR.
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.

HAZARD CLASS HAZARD CATEGORY
FLAMMABLE LIQUID 2
SKIN IRRITATION 2
EYE IRRITATION 2A
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3

PICTOGRAM(S)

Precautionary Statements

Prevention:
Keep away from heat, sparks, open flames, hot surfaces - no smoking. Keep container tightly
closed. No release into water. Use explosion-proof equipment. Use only non-sparking tools.
Take precautionary measures against static discharge. Avoid breathing vapors, mist, or spray.
Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective
gloves, eye protection, and face protection.
Response:
If on skin (or hair): Take off immediately all contaminated clothing. IF INHALED: Remove
person to fresh air and keep comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to remove. Continue rinsing. Call a poison control center or physician if you
feel unwell. If skin irritation occurs: Get medical attention. If eye irritation persists: Get medical
attention. Take off contaminated clothing. In case of fire: Use foam, dry chemical or carbon
dioxide to extinguish.
Storage:
Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place.

IDH number: 1630096 Product name: OSI F-38 Drywall and Panel Adhesive
Page 2 of 7

Keep cool. Store locked up.
Disposal:
Dispose of contents and/or container according to Federal, State/Provincial and local
governmental regulations.

Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the
United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).

See Section 11 for additional toxicological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous Component(s) CAS Number Percentage*
Limestone 1317-65-3 30 - 60
Acetone 67-64-1 10 - 30
Kaolin 1332-58-7 10 - 30
Methyl acetate 79-20-9 1 - 5
Titanium dioxide 13463-67-7 0.1 - 1
Quartz (SiO2) 14808-60-7 0.1 - 1

* Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections.

4. FIRST AID MEASURES

Inhalation: If inhaled, immediately remove the affected person to fresh air. If breathing is
difficult, give oxygen. If not breathing, give artificial respiration. If symptoms
develop and persist, get medical attention.

Skin contact: Rinse with running water and soap. Apply replenishing cream. Change all
contaminated clothing.

Eye contact: In case of contact with the eyes, rinse immediately with plenty of water for 15
minutes, and seek immediate medical attention.

Ingestion: Do not induce vomiting, seek medical advice immediately.

Symptoms: See Section 11.

5. FIRE FIGHTING MEASURES

Extinguishing media: Foam, dry chemical or carbon dioxide. In case of fire, keep containers cool
with water spray.

Special firefighting procedures: Wear a self-contained breathing apparatus with a full face piece operated in
pressure-demand or other positive pressure mode. Wear full protective
clothing.

Unusual fire or explosion hazards: Closed containers may explode when exposed to extreme heat. Vapors may
form explosive mixtures with air. Vapors are heavier than air and may travel
along floor to an ignition source.

IDH number: 1630096 Product name: OSI F-38 Drywall and Panel Adhesive
Page 3 of 7

Hazardous combustion products: Upon decomposition, this product emits carbon monoxide, carbon dioxide
and/or low molecular weight hydrocarbons.

6. ACCIDENTAL RELEASE MEASURES

Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.

Environmental precautions: Eliminate all sources of ignition or flammables that may come into contact with
a spill of this material. Ventilate area. Do not allow product to enter sewer or
waterways.

Clean-up methods: Use noncombustible absorbent material such as sand. Use non-sparking tools
for clean-up. Absorb spill with inert material. Shovel material into appropriate
container for disposal. Wear suitable protective clothing, gloves and eye/face
protection.

7. HANDLING AND STORAGE

Handling: Do not pressurize, cut, heat or weld containers. Empty product containers
may contain product residue. Do not reuse empty containers. Use only in
well-ventilated areas. Keep out of the reach of children.

Storage: For safe storage, store between -20 °C (-4°F) and 50 °C (122°F)
Keep away from heat, spark and flame. Keep containers closed when not in
use.

For information on product shelf life, please review labels on container or check the Technical Data Sheet.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.

Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER
Limestone 10 mg/m3 TWA Total
dust.
5 mg/m3 PEL
Respirable fraction.
15 mg/m3 PEL Total
dust.
None None
Acetone 750 ppm STEL
500 ppm TWA
1,000 ppm (2,400
mg/m3) PEL None None
Kaolin 2 mg/m3 TWA
Respirable fraction.
15 mg/m3 PEL Total
dust.
5 mg/m3 PEL
Respirable fraction.
None None
Methyl acetate 200 ppm TWA
250 ppm STEL
200 ppm (610
mg/m3) PEL None None
Titanium dioxide 10 mg/m3 TWA 15 mg/m3 PEL Total
dust. None None
Quartz (SiO2) 0.025 mg/m3 TWA
Respirable fraction.
2.4 MPPCF TWA
Respirable.
0.1 mg/m3 TWA
Respirable.
0.3 mg/m3 TWA Total
dust.
None None

Engineering controls: Local exhaust ventilation is recommended when general ventilation is not
sufficient to control airborne contamination below occupational exposure
limits.

Respiratory protection: If ventilation is not sufficient to effectively prevent buildup of aerosols, mists or
vapors, appropriate NIOSH/MSHA respiratory protection must be provided.

IDH number: 1630096 Product name: OSI F-38 Drywall and Panel Adhesive
Page 4 of 7

Eye/face protection: Safety goggles or safety glasses with side shields.

Skin protection: Chemical resistant, impermeable gloves.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Paste
Color: Tan
Odor: Strong, Solvent
Odor threshold: Not available.
pH: 7
Vapor pressure: Not available.
Boiling point/range: 56 - 57 °C (132.8 - 134.6 °F)
Melting point/ range: < 0 °C (< 32°F)
Specific gravity: 1.39
Vapor density: 2.0
Flash point: -17 °C (1.4 °F)
Flammable/Explosive limits - lower: Not available.
Flammable/Explosive limits - upper: Not available.
Autoignition temperature: Not available.
Evaporation rate: 14.4
Solubility in water: Slightly soluble
Partition coefficient (n-octanol/water): Not available.
VOC content: 0.25 %; 7.5 g/l (by weight, calculated using CARB method; g/L less water, less
exempts calculated using SCAQMD method)
Viscosity: 270,000 mPa.s
Decomposition temperature: Not available.

10. STABILITY AND REACTIVITY

Stability: Stable under normal conditions of storage and use.

Hazardous reactions: Will not occur.

Hazardous decomposition
products:
Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low
molecular weight hydrocarbons.

Incompatible materials: Strong oxidizing agents.

Reactivity: Not available.

Conditions to avoid: Heat, flames, sparks and other sources of ignition.

11. TOXICOLOGICAL INFORMATION

Relevant routes of exposure: Inhalation, Skin contact

IDH number: 1630096 Product name: OSI F-38 Drywall and Panel Adhesive
Page 5 of 7

Potential Health Effects/Symptoms

Inhalation: Irritates the nose, throat and respiratory system. Exposure to high doses may cause central
nervous system depression. Such doses may also cause adverse effects in the liver, kidneys,
and lungs. Abrasion of cured material such as by sanding or grinding could release respirable
particles of silica quartz, a cancer hazard by inhalation. Normal use of this product causes no
such release. Reports have associated repeated and prolonged overexposure to solvents with
permanent brain and nervous system damage. Intentional misuse by deliberately concentrating
and inhaling the contents may be harmful or fatal.
Skin contact: Prolonged and/or repeated skin contact with this product may cause irritation/dermatitis.
Eye contact: Contact with eyes can cause eye irritation. Symptoms may include stinging, tearing, redness,
swelling, and blurred vision.
Ingestion: Ingestion can cause gastrointestinal irritation, nausea, vomiting and diarrhea.

Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects
Limestone None Nuisance dust
Acetone
Oral LD50 (RABBIT) = 5,340 mg/kg
Oral LD50 (RAT) = 5,800 mg/kg
Oral LD50 (RAT) = 9,800 mg/kg
Dermal LD50 (RABBIT) = 20,000 mg/kg
Inhalation LC50 (RAT, 8 h) = 50.1 mg/l
Inhalation LC50 (RAT, 4 h) = 76 mg/l
Blood, Central nervous system, Irritant,
Reproductive
Kaolin Oral LD50 (RAT) = > 5,000 mg/kg
Dermal LD50 (RAT) = > 5,000 mg/kg Nuisance dust
Methyl acetate Oral LD50 (RABBIT) = 3.7 g/kg Blood, Central nervous system, Eyes, Irritant
Titanium dioxide None Irritant, Respiratory, Some evidence of
carcinogenicity
Quartz (SiO2) None Immune system, Lung, Some evidence of
carcinogenicity

Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen
(Specifically Regulated)
Limestone No No No
Acetone No No No
Kaolin No No No
Methyl acetate No No No
Titanium dioxide No Group 2B No
Quartz (SiO2) Known To Be Human
Carcinogen. Group 1 No

12. ECOLOGICAL INFORMATION

Ecological information: Not available.

IDH number: 1630096 Product name: OSI F-38 Drywall and Panel Adhesive
Page 6 of 7

13. DISPOSAL CONSIDERATIONS

Information provided is for unused product only.

Recommended method of disposal: Dispose of according to Federal, State and local governmental regulations.

Hazardous waste number: Material, if discarded, is not expected to be a characteristic hazardous waste
under RCRA.

14. TRANSPORT INFORMATION

The transport information provided in this section only applies to the material/formulation itself, and is not specific to any
package/configuration.

U.S. Department of Transportation Ground (49 CFR)
Proper shipping name: Adhesives
Hazard class or division: 3
Identification number: UN 1133
Packing group: II
DOT Hazardous Substance(s): Acetone

International Air Transportation (ICAO/IATA)
Proper shipping name: Adhesives
Hazard class or division: 3
Identification number: UN 1133
Packing group: II

Water Transportation (IMO/IMDG)
Proper shipping name: ADHESIVES
Hazard class or division: 3
Identification number: UN 1133
Packing group: II

15. REGULATORY INFORMATION

United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.
TSCA 12 (b) Export Notification: None above reporting de minimis

CERCLA/SARA Section 302 EHS: None above reporting de minimis
CERCLA/SARA Section 311/312: Fire, Immediate Health, Delayed Health
CERCLA/SARA Section 313: None above reporting de minimis

California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This
product contains a chemical known to the State of California to cause birth defects or other
reproductive harm.

Canada Regulatory Information

CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic
Substances List.

16. OTHER INFORMATION

This safety data sheet contains changes from the previous version in sections: This Safety Data Sheet contains changes
from the previous version in Section(s):
7

Prepared by: Mary Ellen Roddy, Sr. Regulatory Affairs Specialist

Issue date: 11/14/2014

IDH number: 1630096 Product name: OSI F-38 Drywall and Panel Adhesive
Page 7 of 7

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.

PP610 PORTER PAINTS ACRI-SHIELD EXTERIOR GLOSS ACRYLIC-BLACK
Not available.
Liquid.
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Section 1. Identification
:
:
:
Product code :00409676
Date of issue/Date of revision 25 June 2018
Version 5
Relevant identified uses of the substance or mixture and uses advised against
Uses advised against Not applicable.
Product use :Consumer applications, Professional applications, Used by spraying.
Use of the substance/
mixture
:Coating.
:
Manufacturer PPG Industries, Inc.
One PPG Place
Pittsburgh, PA 15272
[phone] (U.S.)
[phone] (Canada)
01-800-00-21-400 or + 52 55 5559 1588 (Mexico)
Emergency telephone
number
:
:
Technical Phone Number :1-800-441-9695 (8:00 am to 5:00 pm EST)
Section 2. Hazards identification
CARCINOGENICITY - Category 2Classification of the
substance or mixture
:
Signal word :Warning
Hazard statements :Suspected of causing cancer.
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 29.1% (Oral),
31.8% (Dermal), 34.4% (Inhalation)
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
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Section 2. Hazards identification
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing.
Response :IF exposed or concerned: Get medical attention.
Storage :Store locked up.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations.
General :Read label before use. Keep out of reach of children. If medical advice is needed,
have product container or label at hand.
Supplemental label
elements
:Contains isothiazolinones. May cause allergic reaction. Emits toxic fumes when heated.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
carbon black, respirable powder ≥1.0 - ≤5.0 1333-86-4
propane-1,2-diol ≥1.0 - ≤5.0 57-55-6
1,2-benzisothiazol-3(2H)-one <0.10 2634-33-5
diammonium peroxodisulphate <0.10 7727-54-0
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Substance/mixture :
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Product name PP610 PORTER PAINTS ACRI-SHIELD EXTERIOR GLOSS ACRYLIC-BLACK:
SUB codes represent substances without registered CAS Numbers.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of
this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have
Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.
Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids
apart for at least 10 minutes and seek immediate medical advice.
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water
or use recognized skin cleanser. Do NOT use solvents or thinners.
If swallowed, seek medical advice immediately and show this container or label. Keep
person warm and at rest. Do NOT induce vomiting.
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Section 4. First aid measures
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :
:Ingestion
Skin contact :
:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
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Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Section 7. Handling and storage
Advice on general
occupational hygiene
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not ingest.
Avoid breathing vapor or mist. If during normal use the material presents a respiratory
hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Empty containers retain product residue and can be
hazardous. Do not reuse container.
:
Precautions for safe handling
Special precautions :If this material is part of a multiple component system, read the Safety Data Sheet(s) for
the other component or components before blending as the resulting mixture may have
the hazards of all of its parts.
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Section 7. Handling and storage
Conditions for safe storage,
including any
incompatibilities
Do not store below the following temperature: 5°C (41°F). Store in accordance with
local regulations. Store in original container protected from direct sunlight in a dry, cool
and well-ventilated area, away from incompatible materials (see Section 10) and food
and drink. Keep container tightly closed and sealed until ready for use. Containers that
have been opened must be carefully resealed and kept upright to prevent leakage. Do
not store in unlabeled containers. Use appropriate containment to avoid environmental
contamination.
:
carbon black, respirable powder ACGIH TLV (United States, 3/2017).
TWA: 3 mg/m³ 8 hours. Form: Inhalable
fraction
OSHA PEL (United States, 6/2016).
TWA: 3.5 mg/m³ 8 hours.
propane-1,2-diol IPEL (PPG).
TWA: 10 mg/m³
1,2-benzisothiazol-3(2H)-one None.
diammonium peroxodisulphate ACGIH TLV (United States, 3/2017).
TWA: 0.1 mg/m³, (as persulfate) 8 hours.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
Control parameters
Individual protection measures
Occupational exposure limits
Recommended monitoring
procedures
:If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
Key to abbreviations
A Acceptable Maximum Peak=
ACGIH =American Conference of Governmental Industrial Hygienists.
C =Ceiling Limit
Potential skin absorptionS
SR =Respiratory sensitization
=Skin sensitizationSS
TD =Total dust
Consult local authorities for acceptable exposure limits.
=Threshold Limit ValueTLV
TWA =Time Weighted Average
Fume=F
IPEL =Internal Permissible Exposure Limit
=Occupational Safety and Health Administration.OSHA
R =Respirable
OSHA 29 CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z
STEL =
=
Short term Exposure limit values
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Section 8. Exposure controls/personal protection
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Skin protection
Other skin protection :
Safety glasses with side shields.
Gloves For prolonged or repeated handling, use the following type of gloves:
Recommended: Viton®, PVC, natural rubber (latex), nitrile rubber
:
Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator. If workers
are exposed to concentrations above the exposure limit, they must use appropriate,
certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying
with an approved standard if a risk assessment indicates this is necessary.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Liquid.
Not available.
Not available.
Characteristic.Odor
pH
Not available.Color
Evaporation rate Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: 113.33°C (236°F) [Product does not sustain combustion.]
Not available.
Not available.Odor threshold
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :>37.78°C (>100°F)
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Decomposition temperature :Not available.
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Section 9. Physical and chemical properties
Relative density
Vapor density
Solubility
1.04
Not available.
Soluble in the following materials: cold water.
Not available.
Viscosity Kinematic (40°C (104°F)): <0.14 cm2/s (<14 cSt)
Partition coefficient: n-
octanol/water
:
:
:
:
:
% Solid. (w/w):33.308
Density ( lbs / gal ):8.68
Volatility :70% (v/v), 66.692% (w/w)
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid
The product is stable.Chemical stability :
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
When exposed to high temperatures may produce hazardous decomposition products.
Keep away from the following materials to prevent strong exothermic reactions:
oxidizing agents, strong alkalis, strong acids.
Decomposition products may include the following materials: carbon monoxide, carbon
dioxide, smoke, oxides of nitrogen.
Refer to protective measures listed in sections 7 and 8.
Section 11. Toxicological information
Acute toxicity
carbon black, respirable
powder
LD50 Dermal Rabbit >3 g/kg -
LD50 Oral Rat >15400 mg/kg -
propane-1,2-diol LD50 Dermal Rabbit 20800 mg/kg -
LD50 Oral Rat 20 g/kg -
1,2-benzisothiazol-3(2H)-one LC50 Inhalation Dusts and mists Rat 0.4 mg/l 4 hours
LD50 Oral Rat 1020 mg/kg -
diammonium
peroxodisulphate
LD50 Oral Rat 0.6 g/kg -
Product/ingredient name Result Species Dose Exposure
Conclusion/Summary :
Irritation/Corrosion
Conclusion/Summary
Information on toxicological effects
There are no data available on the mixture itself.
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Section 11. Toxicological information
Carcinogenicity
Conclusion/Summary :
Mutagenicity
Conclusion/Summary :
Teratogenicity
Conclusion/Summary :
Reproductive toxicity
Conclusion/Summary :
Skin :
Eyes :
Respiratory :
Sensitization
1,2-benzisothiazol-3(2H)-one skin Guinea pig Sensitizing
Product/ingredient name Route of
exposure
Species Result
Conclusion/Summary
Skin :
Respiratory :
Specific target organ toxicity (single exposure)
Classification
carbon black, respirable
powder
-2B -
Product/ingredient name NTPIARCOSHA
Carcinogen Classification code:
IARC: 1, 2A, 2B, 3, 4
NTP: Known to be a human carcinogen; Reasonably anticipated to be a human carcinogen
OSHA: +
Not listed/not regulated: -
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
Name
Information on the likely routes of exposure
Specific target organ toxicity (repeated exposure)
diammonium peroxodisulphate Category 3
Category
Not available.
Aspiration hazard
Not available.
Potential acute health effects
No known significant effects or critical hazards.:Eye contact
Target organs :Contains material which may cause damage to the following organs: lungs, upper
respiratory tract, eyes.
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Section 11. Toxicological information
Conclusion/Summary :
General :
Carcinogenicity :
Mutagenicity :
Teratogenicity :
Developmental effects :
Fertility effects :
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral 83845.4 mg/kg
Route ATE value
Acute toxicity estimates
Potential immediate
effects
:
Short term exposure
Potential delayed effects :
Potential immediate
effects
:
Long term exposure
Potential delayed effects :
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
There are no data available on the mixture itself. If splashed in the eyes, the liquid may
cause irritation and reversible damage. Ingestion may cause nausea, diarrhea and
vomiting. This takes into account, where known, delayed and immediate effects and
also chronic effects of components from short-term and long-term exposure by oral,
inhalation and dermal routes of exposure and eye contact.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
Section 12. Ecological information
Toxicity
1,2-benzisothiazol-3(2H)-one Acute EC50 0.11 mg/l Algae 72 hours
Chronic NOEC 0.09 mg/l Fish 28 days
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
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Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Product/ingredient name
propane-1,2-diol -0.92 -low
1,2-benzisothiazol-3(2H)-one 0.7 -low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
1,2-benzisothiazol-3(2H)-one --Readily
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
:Disposal methods
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees. Section 6. Accidental release measures
14. Transport information
-
-
-
-
-
-
-
Not regulated.
-
-
Not regulated.Not regulated.
DOT IMDG IATA
UN number
UN proper shipping
name
Transport hazard class
(es)
Packing group
Environmental hazards No.No.No.
Marine pollutant
substances
Not applicable.Not applicable.Not applicable.
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14. Transport information
Special precautions for user Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
:
Additional information
None identified.
None identified.
DOT
IMDG
:
:
IATA :None identified.
Section 15. Regulatory information
SARA 302/304
SARA 304 RQ :Not applicable.
Composition/information on ingredients
All components are listed or exempted.United States inventory (TSCA 8b):
United States
Additional environmental information is contained on the Environmental Data Sheet for this product, which
can be obtained from your PPG representative.
California Prop. 65
No products were found.
SARA 311/312
Classification :CARCINOGENICITY - Category 2
carbon black, respirable powder ≥1.0 - ≤5.0 COMBUSTIBLE DUSTS
CARCINOGENICITY - Category 2
1,2-benzisothiazol-3(2H)-one <0.10 COMBUSTIBLE DUSTS
ACUTE TOXICITY (oral) - Category 4
ACUTE TOXICITY (inhalation) - Category 2
SKIN IRRITATION - Category 2
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1A
diammonium peroxodisulphate <0.10 OXIDIZING SOLIDS - Category 3
ACUTE TOXICITY (oral) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
RESPIRATORY SENSITIZATION - Category 1A
SKIN SENSITIZATION - Category 1B
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
Name %Classification
Composition/information on ingredients
WARNING: Cancer - www.P65Warnings.ca.gov.
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PP610 PORTER PAINTS ACRI-SHIELD EXTERIOR GLOSS ACRYLIC-BLACKProduct name
5Product code Date of issue Version0040967625 June 2018
Section 16. Other information
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Hazardous Material Information System (U.S.A.)
1
01
National Fire Protection Association (U.S.A.)
Health InstabilityFlammability
Health Flammability Physical hazards
Disclaimer
The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures
described in this data sheet or for any misuse of the products.
Date of previous issue 3/30/2018:
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or
risks. Although HMIS® ratings and the associated label are not required on MSDSs or products leaving a facility under 29 CFR 1910.1200, the
preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark
and service mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
Indicates information that has changed from previously issued version.
Organization that prepared
the MSDS
:EHS
:::
:::1 *
1
0
( * ) - Chronic effects
United States Page: 12/12
PP649 PORTER PAINTS ACRI-SHIELD EXTERIOR SEMI-GLOSS 100% ACRYLIC-
LIGHT BASE
Not available.
Liquid.
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Section 1. Identification
:
:
:
Product code :00404790
Date of issue/Date of revision 24 June 2018
Version 5.04
Relevant identified uses of the substance or mixture and uses advised against
Uses advised against Not applicable.
Product use :Consumer applications, Professional applications, Used by spraying.
Use of the substance/
mixture
:Coating.
:
Manufacturer PPG Industries, Inc.
One PPG Place
Pittsburgh, PA 15272
[phone] (U.S.)
[phone] (Canada)
01-800-00-21-400 or + 52 55 5559 1588 (Mexico)
Emergency telephone
number
:
:
Technical Phone Number :1-800-441-9695 (8:00 am to 5:00 pm EST)
Section 2. Hazards identification
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 2
Classification of the
substance or mixture
:
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 23.2% (Oral),
24.4% (Dermal), 24.4% (Inhalation)
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
This product contains TiO2 which has been classified as a GHS Carcinogen Category 2
based on its IARC 2B classification. For many PPG products, TiO2 is utilized as a raw
material in a liquid coating formulation. In this case, the TiO2 particles are bound in a
matrix with no meaningful potential for human exposure to unbound particles of TiO2
when the product is applied with a brush or roller. Sanding the coating surface or mist
from spray applications may be harmful depending on the duration and level of
exposure and require the use of appropriate personal protective equipment and/or
engineering controls (see Section 8).
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Product name
5.04Product code Date of issue Version0040479024 June 2018
Section 2. Hazards identification
Signal word :Warning
Hazard statements :May cause an allergic skin reaction.
Suspected of causing cancer.
Hazard pictograms :
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing. Avoid breathing vapor. Contaminated work clothing must not
be allowed out of the workplace.
Response :IF exposed or concerned: Get medical attention. IF ON SKIN: Wash with plenty of
soap and water. Wash contaminated clothing before reuse. If skin irritation or rash
occurs: Get medical attention.
Storage :Store locked up.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations.
General :Read label before use. Keep out of reach of children. If medical advice is needed,
have product container or label at hand.
Supplemental label
elements
:Contains isothiazolinones. May cause allergic reaction. Emits toxic fumes when heated.
Hazards not otherwise
classified
:None known.
Photosensitive agents : In case of accidental eye contact, avoid concurrent exposure to
the sun or other sources of UV light which may increase the sensitivity of the eyes. In
case of accidental skin contact, avoid concurrent exposure to the sun or other sources
of UV light which may increase the sensitivity of skin.
Section 3. Composition/information on ingredients
titanium dioxide ≥10 - ≤20 13463-67-7
propane-1,2-diol ≥1.0 - ≤5.0 57-55-6
octhilinone (ISO)<1.0 26530-20-1
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Substance/mixture :Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Product name PP649 PORTER PAINTS ACRI-SHIELD EXTERIOR SEMI-GLOSS 100% ACRYLIC-
LIGHT BASE
:
SUB codes represent substances without registered CAS Numbers.
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5.04Product code Date of issue Version0040479024 June 2018
Section 3. Composition/information on ingredients
Occupational exposure limits, if available, are listed in Section 8.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Description of necessary first aid measures
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :
:Ingestion
Skin contact :
:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :No specific data.
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
In case of accidental eye contact, avoid concurrent exposure to the sun or other
sources of UV light which may increase the sensitivity of the eyes.
In case of accidental skin contact, avoid concurrent exposure to the sun or other
sources of UV light which may increase the sensitivity of skin.
If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of
this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have
Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.
Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids
apart for at least 10 minutes and seek immediate medical advice.
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water
or use recognized skin cleanser. Do NOT use solvents or thinners.
If swallowed, seek medical advice immediately and show this container or label. Keep
person warm and at rest. Do NOT induce vomiting.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
May cause an allergic skin reaction.
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5.04Product code Date of issue Version0040479024 June 2018
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon oxides
metal oxide/oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
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5.04Product code Date of issue Version0040479024 June 2018
Section 6. Accidental release measures
Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
Large spill :
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Do not store below the following temperature: 5°C (41°F). Store in accordance with
local regulations. Store in original container protected from direct sunlight in a dry, cool
and well-ventilated area, away from incompatible materials (see Section 10) and food
and drink. Keep container tightly closed and sealed until ready for use. Containers that
have been opened must be carefully resealed and kept upright to prevent leakage. Do
not store in unlabeled containers. Use appropriate containment to avoid environmental
contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Avoid exposure - obtain special instructions before use. Do not
handle until all safety precautions have been read and understood. Do not get in eyes
or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. If during normal
use the material presents a respiratory hazard, use only with adequate ventilation or
wear appropriate respirator. Keep in the original container or an approved alternative
made from a compatible material, kept tightly closed when not in use. Empty containers
retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Special precautions :If this material is part of a multiple component system, read the Safety Data Sheet(s) for
the other component or components before blending as the resulting mixture may have
the hazards of all of its parts.
Section 8. Exposure controls/personal protection
Control parameters
Occupational exposure limits
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Section 8. Exposure controls/personal protection
titanium dioxide OSHA PEL (United States, 6/2016).
TWA: 15 mg/m³ 8 hours. Form: Total dust
ACGIH TLV (United States, 3/2017).
TWA: 10 mg/m³ 8 hours.
propane-1,2-diol IPEL (PPG).
TWA: 10 mg/m³
octhilinone (ISO)None.
Ingredient name Exposure limits
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Eye/face protection
:
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Recommended monitoring
procedures
:If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
Safety glasses with side shields.
Key to abbreviations
A Acceptable Maximum Peak=
ACGIH =American Conference of Governmental Industrial Hygienists.
C =Ceiling Limit
Potential skin absorptionS
SR =Respiratory sensitization
=Skin sensitizationSS
TD =Total dust
Consult local authorities for acceptable exposure limits.
=Threshold Limit ValueTLV
TWA =Time Weighted Average
Fume=F
IPEL =Internal Permissible Exposure Limit
=Occupational Safety and Health Administration.OSHA
R =Respirable
OSHA 29 CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z
STEL =
=
Short term Exposure limit values
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5.04Product code Date of issue Version0040479024 June 2018
Section 8. Exposure controls/personal protection
Respiratory protection :
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Other skin protection :
Gloves butyl rubber polyethylene:
Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator. If workers
are exposed to concentrations above the exposure limit, they must use appropriate,
certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying
with an approved standard if a risk assessment indicates this is necessary.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.15
Not available.
Not available.
Soluble in the following materials: cold water.
Characteristic.Odor
pH
Not available.Color
Evaporation rate Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: 113.33°C (236°F) [Product does not sustain combustion.]
Not available.
Not available.
Viscosity Kinematic (40°C (104°F)): <0.14 cm2/s (<14 cSt)
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :>37.78°C (>100°F)
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Decomposition temperature :Not available.
% Solid. (w/w):39.16
Density ( lbs / gal ):9.6
Volatility :70% (v/v), 60.84% (w/w)
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5.04Product code Date of issue Version0040479024 June 2018
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid
The product is stable.Chemical stability :
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
When exposed to high temperatures may produce hazardous decomposition products.
Keep away from the following materials to prevent strong exothermic reactions:
oxidizing agents, strong alkalis, strong acids.
Decomposition products may include the following materials: carbon monoxide, carbon
dioxide, smoke, oxides of nitrogen.
Refer to protective measures listed in sections 7 and 8.
Section 11. Toxicological information
Acute toxicity
titanium dioxide LC50 Inhalation Dusts and mists Rat >6.82 mg/l 4 hours
LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat >5000 mg/kg -
propane-1,2-diol LD50 Dermal Rabbit 20800 mg/kg -
LD50 Oral Rat 20 g/kg -
octhilinone (ISO)LD50 Dermal Rabbit 0.69 g/kg -
LD50 Oral Rat 0.55 g/kg -
Product/ingredient name Result Species Dose Exposure
Conclusion/Summary :
Mutagenicity
Irritation/Corrosion
Conclusion/Summary
Skin :
Eyes :
Respiratory :
Sensitization
octhilinone (ISO)skin Mouse Sensitizing
Product/ingredient name Route of
exposure
Species Result
Conclusion/Summary
Skin :
Respiratory :
Information on toxicological effects
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
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Section 11. Toxicological information
Carcinogenicity
Conclusion/Summary :
Conclusion/Summary :
Teratogenicity
Conclusion/Summary :
Reproductive toxicity
Conclusion/Summary :
Specific target organ toxicity (single exposure)
Classification
titanium dioxide -2B -
Product/ingredient name NTPIARCOSHA
Carcinogen Classification code:
IARC: 1, 2A, 2B, 3, 4
NTP: Known to be a human carcinogen; Reasonably anticipated to be a human carcinogen
OSHA: +
Not listed/not regulated: -
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
Information on the likely routes of exposure
Delayed and immediate effects and also chronic effects from short and long term exposure
Specific target organ toxicity (repeated exposure)
Not available.
Not available.
Aspiration hazard
Not available.
Potential acute health effects
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :May cause an allergic skin reaction.
No known significant effects or critical hazards.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :No specific data.
Target organs :Contains material which may cause damage to the following organs: upper respiratory
tract.
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Section 11. Toxicological information
Conclusion/Summary :
General :
Carcinogenicity :
Mutagenicity :
Teratogenicity :
Developmental effects :
Fertility effects :
Potential chronic health effects
Numerical measures of toxicity
Oral 200053.8 mg/kg
Route ATE value
Acute toxicity estimates
Potential immediate
effects
:
Short term exposure
Potential delayed effects :
Potential immediate
effects
:
Long term exposure
Potential delayed effects :
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
There are no data available on the mixture itself. This product contains TiO2 which has
been classified as a GHS Carcinogen Category 2 based on its IARC 2B classification.
For many PPG products, TiO2 is utilized as a raw material in a liquid coating formulation.
In this case, the TiO2 particles are bound in a matrix with no meaningful potential for
human exposure to unbound particles of TiO2 when the product is applied with a brush
or roller. Sanding the coating surface or mist from spray applications may be harmful
depending on the duration and level of exposure and require the use of appropriate
personal protective equipment and/or engineering controls (see Section 8). Acrylate
components of the mixture have irritating properties. Prolonged or repeated contact
with skin or mucous membrane may result in irritation symptoms, such as redness,
blistering, dermatitis etc. May cause allergic skin reactions with repeated exposure.
The inhalation of airborne droplets or aerosols may cause irritation of the respiratory
tract. Ingestion may cause nausea, weakness and central nervous system effects. If
splashed in the eyes, the liquid may cause irritation and reversible damage. This takes
into account, where known, delayed and immediate effects and also chronic effects of
components from short-term and long-term exposure by oral, inhalation and dermal
routes of exposure and eye contact.
Once sensitized, a severe allergic reaction may occur when subsequently exposed to
very low levels.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
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Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Product/ingredient name
propane-1,2-diol -0.92 -low
octhilinone (ISO)2.45 -low
Toxicity
titanium dioxide Acute LC50 >100 mg/l Fresh water Daphnia - Daphnia magna 48 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
:Disposal methods
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees. Section 6. Accidental release measures
14. Transport information
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14. Transport information
-
-
-
-
-
-
-
Not regulated.
-
-
Not regulated.Not regulated.
DOT IMDG IATA
UN number
UN proper shipping
name
Transport hazard class
(es)
Packing group
Environmental hazards No.No.No.
Marine pollutant
substances
Not applicable.Not applicable.Not applicable.
Special precautions for user Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
:
Additional information
None identified.
None identified.
DOT
IMDG
:
:
IATA :None identified.
Section 15. Regulatory information
SARA 302/304
SARA 304 RQ :Not applicable.
Composition/information on ingredients
All components are listed or exempted.United States inventory (TSCA 8b):
United States
No products were found.
SARA 311/312
Classification :SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 2
titanium dioxide ≥10 - ≤20 CARCINOGENICITY - Category 2
octhilinone (ISO)<1.0 ACUTE TOXICITY (oral) - Category 4
ACUTE TOXICITY (dermal) - Category 3
ACUTE TOXICITY (inhalation) - Category 2
SKIN CORROSION - Category 1
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1A
Name %Classification
Composition/information on ingredients
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Section 15. Regulatory information
Additional environmental information is contained on the Environmental Data Sheet for this product, which
can be obtained from your PPG representative.
Section 16. Other information
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Hazardous Material Information System (U.S.A.)
1
01
National Fire Protection Association (U.S.A.)
Health InstabilityFlammability
Health Flammability Physical hazards
Disclaimer
The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures
described in this data sheet or for any misuse of the products.
Date of previous issue 6/5/2018:
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or
risks. Although HMIS® ratings and the associated label are not required on MSDSs or products leaving a facility under 29 CFR 1910.1200, the
preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark
and service mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
Indicates information that has changed from previously issued version.
Organization that prepared
the MSDS
:EHS
:::
:::2 *
2
0
( * ) - Chronic effects
United States Page: 13/13
1414X PPG TOP GUN 200XI SILICONIZED ACRYLIC SEALANT - WHITE
Not available.
Solid.
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Section 1. Identification
:
:
:
Product code :00378507
Date of issue/Date of revision 23 June 2018
Version 10
Relevant identified uses of the substance or mixture and uses advised against
Uses advised against Not applicable.
Product use :Consumer applications, Professional applications.
Use of the substance/
mixture
:Sealants; Adhesive.
:
Manufacturer PPG Industries, Inc.
One PPG Place
Pittsburgh, PA 15272
[phone] (U.S.)
[phone] (Canada)
01-800-00-21-400 or + 52 55 5559 1588 (Mexico)
Emergency telephone
number
:
:
Technical Phone Number :1-800-441-9695 (8:00 am to 5:00 pm EST)
Section 2. Hazards identification
CARCINOGENICITY - Category 1A
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (kidneys) -
Category 2
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :May cause cancer.
May cause damage to organs through prolonged or repeated exposure. (kidneys)
Hazard pictograms :
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 76.2% (Oral),
80.3% (Dermal), 25.8% (Inhalation)
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
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Section 2. Hazards identification
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing. Do not breathe dust.
Response :Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention.
Storage :Store locked up.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations.
General :Read label before use. Keep out of reach of children. If medical advice is needed,
have product container or label at hand.
Supplemental label
elements
:Contains isothiazolinones. May cause allergic reaction. Sanding and grinding dusts
may be harmful if inhaled. This product contains crystalline silica which can cause lung
cancer or silicosis. The risk of cancer depends on the duration and level of exposure to
dust from sanding surfaces or mist from spray applications. This product either contains
formaldehyde or is capable of releasing formaldehyde above 0.5 ppm under certain
conditions. Formaldehyde is a known cancer hazard, a skin sensitizer and a respiratory
sensitizer. Avoid contact with skin and clothing. Wash thoroughly after handling. Emits
toxic fumes when heated.
Hazards not otherwise
classified
:Prolonged or repeated contact may dry skin and cause irritation.
Section 3. Composition/information on ingredients
Limestone ≥50 - ≤75 1317-65-3
ethanediol ≥1.0 - ≤3.7 107-21-1
titanium dioxide ≤1.0 13463-67-7
crystalline silica, respirable powder (<10 microns)<1.0 14808-60-7
Formaldehyde, solution <0.10 50-00-0
1,2-benzisothiazol-3(2H)-one <0.10 2634-33-5
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Substance/mixture :
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Product name 1414X PPG TOP GUN 200XI SILICONIZED ACRYLIC SEALANT - WHITE:
SUB codes represent substances without registered CAS Numbers.
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Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Description of necessary first aid measures
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :
:Ingestion
Skin contact :
:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:
irritation
dryness
cracking
:
:
:
Eye contact :No specific data.
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of
this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have
Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.
Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids
apart for at least 10 minutes and seek immediate medical advice.
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water
or use recognized skin cleanser. Do NOT use solvents or thinners.
If swallowed, seek medical advice immediately and show this container or label. Keep
person warm and at rest. Do NOT induce vomiting.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
Defatting to the skin. May cause skin dryness and irritation.
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Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon oxides
metal oxide/oxides
Formaldehyde.
No specific fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Move containers from spill area. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Avoid dust generation. Do not
dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed,
labeled waste container. Dispose of via a licensed waste disposal contractor. Note:
see Section 1 for emergency contact information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Provide adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Put on appropriate
personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Move containers from spill area. Avoid dust generation. Do not dry sweep. Vacuum
dust with equipment fitted with a HEPA filter and place in a closed, labeled waste
container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
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Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Do not store below the following temperature: 5°C (41°F). Store in accordance with
local regulations. Store in original container protected from direct sunlight in a dry, cool
and well-ventilated area, away from incompatible materials (see Section 10) and food
and drink. Keep container tightly closed and sealed until ready for use. Containers that
have been opened must be carefully resealed and kept upright to prevent leakage. Do
not store in unlabeled containers. Use appropriate containment to avoid environmental
contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not ingest. If
during normal use the material presents a respiratory hazard, use only with adequate
ventilation or wear appropriate respirator. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use. Empty
containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Special precautions :If this material is part of a multiple component system, read the Safety Data Sheet(s) for
the other component or components before blending as the resulting mixture may have
the hazards of all of its parts.
Limestone OSHA PEL (United States, 6/2016).
TWA: 5 mg/m³ 8 hours. Form: Respirable
fraction
TWA: 15 mg/m³ 8 hours. Form: Total dust
ethanediol ACGIH TLV (United States, 3/2017).
STEL: 10 mg/m³ 15 minutes. Form: Inhalable
fraction. Aerosol only.
STEL: 50 ppm 15 minutes. Form: Vapor
fraction
TWA: 25 ppm 8 hours. Form: Vapor fraction
titanium dioxide OSHA PEL (United States, 6/2016).
TWA: 15 mg/m³ 8 hours. Form: Total dust
ACGIH TLV (United States, 3/2017).
TWA: 10 mg/m³ 8 hours.
crystalline silica, respirable powder (<10 microns)ACGIH TLV (United States, 3/2017).
TWA: 0.025 mg/m³ 8 hours. Form:
Respirable
OSHA PEL Z3 (United States, 6/2016).
TWA: 10 mg/m³ / (%SiO2+2) 8 hours. Form:
Respirable
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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Section 8. Exposure controls/personal protection
TWA: 250 mppcf / (%SiO2+5) 8 hours. Form:
Respirable
OSHA PEL (United States, 6/2016).
TWA: 50 µg/m³ 8 hours. Form: Respirable
dust
Formaldehyde, solution OSHA PEL (United States, 6/2016).
STEL: 2 ppm 15 minutes.
TWA: 0.75 ppm 8 hours.
OSHA PEL Z2 (United States, 2/2013).
STEL: 2 ppm 15 minutes.
TWA: 0.75 ppm 8 hours.
ACGIH TLV (United States, 3/2017). Skin
sensitizer. Inhalation sensitizer.
STEL: 0.3 ppm 15 minutes.
TWA: 0.1 ppm 8 hours.
1,2-benzisothiazol-3(2H)-one None.
Eye/face protection :
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Recommended monitoring
procedures
:If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
Safety glasses with side shields.
Key to abbreviations
A Acceptable Maximum Peak=
ACGIH =American Conference of Governmental Industrial Hygienists.
C =Ceiling Limit
Potential skin absorptionS
SR =Respiratory sensitization
=Skin sensitizationSS
TD =Total dust
Consult local authorities for acceptable exposure limits.
=Threshold Limit ValueTLV
TWA =Time Weighted Average
Fume=F
IPEL =Internal Permissible Exposure Limit
=Occupational Safety and Health Administration.OSHA
R =Respirable
OSHA 29 CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z
STEL =
=
Short term Exposure limit values
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Section 8. Exposure controls/personal protection
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Respiratory protection :
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator. If workers
are exposed to concentrations above the exposure limit, they must use appropriate,
certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying
with an approved standard if a risk assessment indicates this is necessary.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Solid.
Not available.
1.64
Not available.
Not available.
Insoluble in the following materials: cold water.
Characteristic.Odor
pH
Not available.Color
Evaporation rate Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: 93.89°C (201°F) [Product does not sustain combustion.]
Not available.
Not available.
Viscosity Kinematic (40°C (104°F)): Not applicable.
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :Not available.
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Decomposition temperature :Not available.
% Solid. (w/w):82.816
Density ( lbs / gal ):13.69
Volatility :28% (v/v), 17.184% (w/w)
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Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid
The product is stable.Chemical stability :
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
When exposed to high temperatures may produce hazardous decomposition products.
Keep away from the following materials to prevent strong exothermic reactions:
oxidizing agents, strong alkalis, strong acids.
Decomposition products may include the following materials: carbon monoxide, carbon
dioxide, smoke, oxides of nitrogen.
Refer to protective measures listed in sections 7 and 8.
Section 11. Toxicological information
Acute toxicity
ethanediol LD50 Dermal Rabbit 9.53 g/kg -
LD50 Oral Rat 4700 mg/kg -
titanium dioxide LC50 Inhalation Dusts and mists Rat >6.82 mg/l 4 hours
LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat >5000 mg/kg -
Formaldehyde, solution LC50 Inhalation Gas.Rat 250 ppm 4 hours
LD50 Dermal Rabbit 270 mg/kg -
LD50 Oral Rat 100 mg/kg -
1,2-benzisothiazol-3(2H)-one LC50 Inhalation Dusts and mists Rat 0.4 mg/l 4 hours
LD50 Oral Rat 1020 mg/kg -
Product/ingredient name Result Species Dose Exposure
Conclusion/Summary :
Irritation/Corrosion
Conclusion/Summary
Skin :
Eyes :
Respiratory :
Sensitization
1,2-benzisothiazol-3(2H)-one skin Guinea pig Sensitizing
Product/ingredient name Route of
exposure
Species Result
Conclusion/Summary
Skin :
Information on toxicological effects
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
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Section 11. Toxicological information
Carcinogenicity
Conclusion/Summary :
Mutagenicity
Conclusion/Summary :
Teratogenicity
Conclusion/Summary :
Reproductive toxicity
Conclusion/Summary :
Respiratory :
Specific target organ toxicity (single exposure)
Classification
titanium dioxide -2B -
crystalline silica, respirable
powder (<10 microns)
-1 Known to be a human carcinogen.
Formaldehyde, solution +1 Known to be a human carcinogen.
Product/ingredient name NTPIARCOSHA
Carcinogen Classification code:
IARC: 1, 2A, 2B, 3, 4
NTP: Known to be a human carcinogen; Reasonably anticipated to be a human carcinogen
OSHA: +
Not listed/not regulated: -
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
Name
Information on the likely routes of exposure
Specific target organ toxicity (repeated exposure)
Formaldehyde, solution Category 3
Category
Name Category
ethanediol Category 2
crystalline silica, respirable powder (<10 microns)Category 1
Aspiration hazard
Not available.
Potential acute health effects
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :Defatting to the skin. May cause skin dryness and irritation.
No known significant effects or critical hazards.:Eye contact
Over-exposure signs/symptoms
Inhalation No specific data.:
Eye contact :No specific data.
Target organs :Contains material which may cause damage to the following organs: blood, kidneys,
lungs, upper respiratory tract, skin, eyes, central nervous system (CNS).
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Section 11. Toxicological information
Conclusion/Summary :
General :
Carcinogenicity :
Mutagenicity :
Teratogenicity :
Developmental effects :
Fertility effects :
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral 6265.7 mg/kg
Route ATE value
Acute toxicity estimates
Potential immediate
effects
:
Short term exposure
Potential delayed effects :
Potential immediate
effects
:
Long term exposure
Potential delayed effects :
Skin contact
Ingestion No specific data.
Adverse symptoms may include the following:
irritation
dryness
cracking
:
:
May cause cancer. Risk of cancer depends on duration and level of exposure.
There are no data available on the mixture itself. This product either contains
formaldehyde or is capable of releasing formaldehyde above 0.5 ppm under certain
conditions. Formaldehyde is a known cancer hazard, a skin sensitizer and a respiratory
sensitizer. This product contains crystalline silica which can cause lung cancer or
silicosis. The risk of cancer depends on the duration and level of exposure to dust from
sanding surfaces or mist from spray applications. Ingestion may cause nausea,
diarrhea and vomiting. This takes into account, where known, delayed and immediate
effects and also chronic effects of components from short-term and long-term exposure
by oral, inhalation and dermal routes of exposure and eye contact.
May cause damage to organs through prolonged or repeated exposure. Prolonged or
repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
Section 12. Ecological information
Toxicity
titanium dioxide Acute LC50 >100 mg/l Fresh water Daphnia - Daphnia magna 48 hours
Formaldehyde, solution Acute EC50 3.48 mg/l Fresh water Algae - Desmodesmus
subspicatus
72 hours
1,2-benzisothiazol-3(2H)-one Acute EC50 0.11 mg/l Algae 72 hours
Chronic NOEC 0.09 mg/l Fish 28 days
Product/ingredient name SpeciesResult Exposure
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Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Product/ingredient name
ethanediol -1.36 -low
1,2-benzisothiazol-3(2H)-one 0.7 -low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
1,2-benzisothiazol-3(2H)-one --Readily
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
:Disposal methods
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees. Section 6. Accidental release measures
14. Transport information
ENVIRONMENTALLY
HAZARDOUS SUBSTANCE,
SOLID, N.O.S.
9
III
-
-
-
-
Not regulated.
-
-
UN3077 Not regulated.
DOT IMDG IATA
UN number
UN proper shipping
name
Transport hazard class
(es)
Packing group
Environmental hazards No.No.No.
(carbendazim (ISO))
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14. Transport information
Marine pollutant
substances
Not applicable.Not applicable.
RQ substances
29411.8
(carbendazim (ISO))
Not applicable.
Not applicable.
Not applicable.
Not applicable.
Not applicable.
Special precautions for user Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
:
Additional information
The classification of the product is due solely to the presence of one or more US DOT-listed
‘Hazardous substances’ that are subject to reportable quantity requirements and only applies to
shipments of packages greater than, or equal to, the product reportable quantity. Package sizes
less than the product reportable quantity are not regulated as hazardous materials.
None identified.
DOT
IMDG
:
:
IATA :None identified.
Product RQ (lbs)
Section 15. Regulatory information
SARA 302/304
SARA 304 RQ :Not applicable.
Composition/information on ingredients
All components are listed or exempted.United States inventory (TSCA 8b):
United States
No products were found.
SARA 311/312
Classification :CARCINOGENICITY - Category 1A
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (kidneys) - Category
2
HNOC - Defatting irritant
ethanediol ≥1.0 - ≤3.7 ACUTE TOXICITY (oral) - Category 4
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) - Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) (kidneys) (oral) - Category 2
HNOC - Defatting irritant
titanium dioxide ≤1.0 CARCINOGENICITY - Category 2
crystalline silica, respirable
powder (<10 microns)
<1.0 CARCINOGENICITY - Category 1A
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) - Category 1
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) (inhalation) - Category 1
Formaldehyde, solution <0.10 FLAMMABLE LIQUIDS - Category 4
Name %Classification
Composition/information on ingredients
United States Page: 12/14
1414X PPG TOP GUN 200XI SILICONIZED ACRYLIC SEALANT - WHITEProduct name
10Product code Date of issue Version0037850723 June 2018
Section 15. Regulatory information
SARA 313
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
Additional environmental information is contained on the Environmental Data Sheet for this product, which
can be obtained from your PPG representative.
California Prop. 65
Supplier notification
Chemical name
:ethanediol 107-21-1 0.5 - 1.5
CAS number Concentration
ACUTE TOXICITY (oral) - Category 3
ACUTE TOXICITY (dermal) - Category 3
ACUTE TOXICITY (inhalation) - Category 3
SKIN CORROSION - Category 1B
SERIOUS EYE DAMAGE - Category 1
RESPIRATORY SENSITIZATION - Category 1A
SKIN SENSITIZATION - Category 1A
GERM CELL MUTAGENICITY - Category 2
CARCINOGENICITY - Category 1A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
1,2-benzisothiazol-3(2H)-one <0.10 COMBUSTIBLE DUSTS
ACUTE TOXICITY (oral) - Category 4
ACUTE TOXICITY (inhalation) - Category 2
SKIN IRRITATION - Category 2
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1A
WARNING: Cancer - www.P65Warnings.ca.gov.
Section 16. Other information
Hazardous Material Information System (U.S.A.)
1
01
National Fire Protection Association (U.S.A.)
Health InstabilityFlammability
Health Flammability Physical hazards
Date of previous issue 5/4/2018:
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or
risks. Although HMIS® ratings and the associated label are not required on MSDSs or products leaving a facility under 29 CFR 1910.1200, the
preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark
and service mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
Organization that prepared
the MSDS
:EHS
:::
:::2 *
2
0
( * ) - Chronic effects
United States Page: 13/14
1414X PPG TOP GUN 200XI SILICONIZED ACRYLIC SEALANT - WHITEProduct name
10Product code Date of issue Version0037850723 June 2018
Section 16. Other information
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Disclaimer
The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures
described in this data sheet or for any misuse of the products.
Indicates information that has changed from previously issued version.
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6-904XI SPEEDHIDE 100% ACRYLIC LATEX EXTERIOR SEMI-GLOSS-ULTRA DEEP
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Not available.
Liquid.
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Section 1. Identification
:
:
:
Product code :00408297
Date of issue/Date of revision 25 June 2018
Version 6.01
Relevant identified uses of the substance or mixture and uses advised against
Uses advised against Not applicable.
Product use :Consumer applications, Professional applications, Used by spraying.
Use of the substance/
mixture
:Coating.
:
Manufacturer PPG Industries, Inc.
One PPG Place
Pittsburgh, PA 15272
[phone] (U.S.)
[phone] (Canada)
01-800-00-21-400 or + 52 55 5559 1588 (Mexico)
Emergency telephone
number
:
:
Technical Phone Number :1-800-441-9695 (8:00 am to 5:00 pm EST)
Section 2. Hazards identification
SKIN SENSITIZATION - Category 1Classification of the
substance or mixture
:
Signal word :Warning
Hazard statements :May cause an allergic skin reaction.
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 27.4% (Oral),
27.4% (Dermal), 27.4% (Inhalation)
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
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6.01Product code Date of issue Version0040829725 June 2018
Section 2. Hazards identification
Prevention :Wear protective gloves. Avoid breathing vapor. Contaminated work clothing must not
be allowed out of the workplace.
Response :IF ON SKIN: Wash with plenty of soap and water. Wash contaminated clothing before
reuse. If skin irritation or rash occurs: Get medical attention.
Storage :Not applicable.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations.
General :Read label before use. Keep out of reach of children. If medical advice is needed,
have product container or label at hand.
Supplemental label
elements
:Contains isothiazolinones. May cause allergic reaction. Emits toxic fumes when heated.
Hazards not otherwise
classified
:None known.
Photosensitive agents : In case of accidental eye contact, avoid concurrent exposure to
the sun or other sources of UV light which may increase the sensitivity of the eyes. In
case of accidental skin contact, avoid concurrent exposure to the sun or other sources
of UV light which may increase the sensitivity of skin.
Section 3. Composition/information on ingredients
octhilinone (ISO)<1.0 26530-20-1
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Substance/mixture :
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Product name 6-904XI SPEEDHIDE 100% ACRYLIC LATEX EXTERIOR SEMI-GLOSS-ULTRA DEEP
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:
SUB codes represent substances without registered CAS Numbers.
Section 4. First aid measures
Eye contact
Inhalation :
:
Description of necessary first aid measures
In case of accidental eye contact, avoid concurrent exposure to the sun or other
sources of UV light which may increase the sensitivity of the eyes.
If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of
this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have
Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.
Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids
apart for at least 10 minutes and seek immediate medical advice.
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel.
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Section 4. First aid measures
Skin contact
Ingestion :
:
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :
:Ingestion
Skin contact :
:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :No specific data.
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
In case of accidental skin contact, avoid concurrent exposure to the sun or other
sources of UV light which may increase the sensitivity of skin.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water
or use recognized skin cleanser. Do NOT use solvents or thinners.
If swallowed, seek medical advice immediately and show this container or label. Keep
person warm and at rest. Do NOT induce vomiting.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
May cause an allergic skin reaction.
Section 5. Fire-fighting measures
Specific hazards arising
from the chemical
In a fire or if heated, a pressure increase will occur and the container may burst. This
material is harmful to aquatic life with long lasting effects. Fire water contaminated with
this material must be contained and prevented from being discharged to any waterway,
sewer or drain.
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
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6.01Product code Date of issue Version0040829725 June 2018
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Decomposition products may include the following materials:
carbon oxides
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
:
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
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Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Do not store below the following temperature: 5°C (41°F). Store in accordance with
local regulations. Store in original container protected from direct sunlight in a dry, cool
and well-ventilated area, away from incompatible materials (see Section 10) and food
and drink. Keep container tightly closed and sealed until ready for use. Containers that
have been opened must be carefully resealed and kept upright to prevent leakage. Do
not store in unlabeled containers. Use appropriate containment to avoid environmental
contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Do not get in eyes or on skin or clothing. Do not ingest. Avoid
breathing vapor or mist. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Empty containers retain
product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Special precautions :If this material is part of a multiple component system, read the Safety Data Sheet(s) for
the other component or components before blending as the resulting mixture may have
the hazards of all of its parts.
octhilinone (ISO)None.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
Recommended monitoring
procedures
:If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
Key to abbreviations
A Acceptable Maximum Peak=
ACGIH =American Conference of Governmental Industrial Hygienists.
C =Ceiling Limit
Potential skin absorptionS
SR =Respiratory sensitization
=Skin sensitizationSS
TD =Total dust
Consult local authorities for acceptable exposure limits.
=Threshold Limit ValueTLV
TWA =Time Weighted Average
Fume=F
IPEL =Internal Permissible Exposure Limit
=Occupational Safety and Health Administration.OSHA
R =Respirable
OSHA 29 CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z
STEL =
=
Short term Exposure limit values
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6.01Product code Date of issue Version0040829725 June 2018
Section 8. Exposure controls/personal protection
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Good general ventilation should be sufficient to control worker exposure to airborne
contaminants.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :
Safety glasses with side shields.
Gloves butyl rubber polyethylene:
Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator. If workers
are exposed to concentrations above the exposure limit, they must use appropriate,
certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying
with an approved standard if a risk assessment indicates this is necessary.
Section 9. Physical and chemical properties
Physical state
Melting point
Liquid.
Not available.
Alcohol-like.Odor
pH
VariousColor
Auto-ignition temperature
Flash point
Not available.
Closed cup: Not applicable. [Product does not sustain combustion.]
9
Not available.Odor threshold
:
:
:
:
:
:
:
:
Appearance
Boiling point :100°C (212°F)
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6.01Product code Date of issue Version0040829725 June 2018
Section 9. Physical and chemical properties
Vapor pressure
Relative density
Vapor density
Solubility
1.03
Not available.
3.3 kPa (25 mm Hg) [room temperature]
Soluble in the following materials: cold water.
Evaporation rate 0.05 (butyl acetate = 1)
Not available.
Viscosity Kinematic (40°C (104°F)): >0.21 cm2/s (>21 cSt)
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Decomposition temperature :Not available.
% Solid. (w/w):30.278
Density ( lbs / gal ):8.6
Volatility :72% (v/v), 69.722% (w/w)
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid
The product is stable.Chemical stability :
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
When exposed to high temperatures may produce hazardous decomposition products.
Keep away from the following materials to prevent strong exothermic reactions:
oxidizing agents, strong alkalis, strong acids.
Decomposition products may include the following materials: carbon monoxide, carbon
dioxide, smoke, oxides of nitrogen.
Refer to protective measures listed in sections 7 and 8.
Section 11. Toxicological information
Acute toxicity
octhilinone (ISO)LD50 Dermal Rabbit 0.69 g/kg -
LD50 Oral Rat 0.55 g/kg -
Product/ingredient name Result Species Dose Exposure
Conclusion/Summary :
Information on toxicological effects
There are no data available on the mixture itself.
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Section 11. Toxicological information
Carcinogenicity
Conclusion/Summary :
Mutagenicity
Conclusion/Summary :
Teratogenicity
Conclusion/Summary :
Reproductive toxicity
Conclusion/Summary :
Irritation/Corrosion
Conclusion/Summary
Skin :
Eyes :
Respiratory :
Sensitization
octhilinone (ISO)skin Mouse Sensitizing
Product/ingredient name Route of
exposure
Species Result
Conclusion/Summary
Skin :
Respiratory :
Specific target organ toxicity (single exposure)
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
Information on the likely routes of exposure
Delayed and immediate effects and also chronic effects from short and long term exposure
Specific target organ toxicity (repeated exposure)
Not available.
Not available.
Aspiration hazard
Not available.
Potential acute health effects
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :May cause an allergic skin reaction.
No known significant effects or critical hazards.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :No specific data.
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Section 11. Toxicological information
Conclusion/Summary :
General :
Carcinogenicity :
Mutagenicity :
Teratogenicity :
Developmental effects :
Fertility effects :
Potential chronic health effects
Potential immediate
effects
:
Short term exposure
Potential delayed effects :
Potential immediate
effects
:
Long term exposure
Potential delayed effects :
No known significant effects or critical hazards.
There are no data available on the mixture itself. Acrylate components of the mixture
have irritating properties. Prolonged or repeated contact with skin or mucous
membrane may result in irritation symptoms, such as redness, blistering, dermatitis etc.
May cause allergic skin reactions with repeated exposure. The inhalation of airborne
droplets or aerosols may cause irritation of the respiratory tract. Ingestion may cause
nausea, weakness and central nervous system effects. If splashed in the eyes, the
liquid may cause irritation and reversible damage. This takes into account, where
known, delayed and immediate effects and also chronic effects of components from
short-term and long-term exposure by oral, inhalation and dermal routes of exposure
and eye contact.
Once sensitized, a severe allergic reaction may occur when subsequently exposed to
very low levels.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Product/ingredient name
octhilinone (ISO)2.45 -low
Toxicity
Not available.
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
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Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
:Disposal methods
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees. Section 6. Accidental release measures
14. Transport information
-
-
-
-
-
-
-
Not regulated.
-
-
Not regulated.Not regulated.
DOT IMDG IATA
UN number
UN proper shipping
name
Transport hazard class
(es)
Packing group
Environmental hazards No.No.No.
Marine pollutant
substances
Not applicable.Not applicable.Not applicable.
Special precautions for user Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
:
Additional information
None identified.
None identified.
DOT
IMDG
:
:
IATA :None identified.
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Section 15. Regulatory information
SARA 302/304
SARA 304 RQ :Not applicable.
Composition/information on ingredients
All components are listed or exempted.United States inventory (TSCA 8b):
United States
United States - TSCA 5(e) - Substances consent order:
United States - TSCA 5(a)2 - Final significant new use rules:
United States - TSCA 5(a)2 - Proposed significant new use rules:
Additional environmental information is contained on the Environmental Data Sheet for this product, which
can be obtained from your PPG representative.
No products were found.
partially fluorinated alcohol, reaction products Listed
2-(nonylphenoxy)ethanol Listed
partially fluorinated alcohol, reaction products Listed
SARA 311/312
Classification :SKIN SENSITIZATION - Category 1
octhilinone (ISO)<1.0 ACUTE TOXICITY (oral) - Category 4
ACUTE TOXICITY (dermal) - Category 3
ACUTE TOXICITY (inhalation) - Category 2
SKIN CORROSION - Category 1
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1A
Name %Classification
Composition/information on ingredients
Section 16. Other information
Hazardous Material Information System (U.S.A.)
0
00
National Fire Protection Association (U.S.A.)
Health InstabilityFlammability
Health Flammability Physical hazards
Date of previous issue 6/8/2018:
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or
risks. Although HMIS® ratings and the associated label are not required on MSDSs or products leaving a facility under 29 CFR 1910.1200, the
preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark
and service mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
Organization that prepared
the MSDS
:EHS
:::
:::2
2
0
( * ) - Chronic effects
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Section 16. Other information
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Disclaimer
The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures
described in this data sheet or for any misuse of the products.
Indicates information that has changed from previously issued version.
United States Page: 12/12
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Safety Data Sheet SDS No. GB-5002 Ready Mix Joint Compounds

Product Name
Ready Mix Joint Compounds
Product Identifiers
Easy Finish Topping
Easy Finish All Purpose
ProForm All Purpose Heavy Viscosity
ProForm All Purpose Export EX 70
ProForm Multi-Use
ProForm Taping
ProForm Taping Lite
ProForm Lite Blue
ProForm Texture Grade
ProForm Tinted Lite
ProForm Pre-Blend 50 lb. bag
ProForm All Purpose
ProForm All Purpose Machine Grade
ProForm Lite
ProForm Lite with Dust-Tech
ProForm Ultra Lite All Purpose
ProForm Topping
ProForm XP with Dust-Tech
ProForm XP Lite with Dust-Tech
Advantage
Advantage Lite
Advantage Topping
ProForm Concrete-Cover Compound
ProForm Factory Built Housing Texture Grade Compound
Other means of identification
Joint Compound, Taping Compound, Gypsum Board Finishing Compound
Recommended Use
All-purpose drying-type compounds used for finishing gypsum board products. Use per manufacturer’s recommendations
Restrictions on Use
Use in well-ventilated area and avoid breathing dust.
Avoid skin contact.
Manufacturer/Supplier Details
National Gypsum Company
2001 Rexford Road
Charlotte, NC 28211
Emergency Telephone Number
Director Quality Services
[phone] - 24 Hour Emergency Response
Website: www.nationalgypsum.com

United States (US)
According to OSHA 29CFR 1910.1200 (HCS)
GHS Classification of the substance or mixture
Carcinogenicity - Category 1A - (H-350)
Specific target organ toxicity, repeated exposure – Category 1 (H-372)
Acute toxicity, inhalation - Category 4 (H-332)
Skin corrosion/irritation Category 2 (H315)
GHS Label Elements
Pictogram
Signal Word Danger
Hazard Statements
H-350 May cause cancer.
H-332, 372 Harmful if inhaled. Causes damage to organs (lungs) through prolonged or repeated
exposure.
H-315 Causes skin corrosion/irritation

Section 1: Product and Company Identification

Section 2: Hazards Identification

SDS No. GB-5002
Safety Data Sheet Ready Mix Joint Compounds

Page 2 of 7
H-315 Causes skin corrosion/irritation

Precautionary Statements
Prevention
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Do not breathe dust.
Use personal protective equipment as required. (See Section 8)
Use engineering controls and wet methods to minimize dust.
Response
If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
If on skin, wash with plenty of soap and water.
If in eyes, rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Get medical attention if exposed or concerned.
Storage
Store material in a cool, dry, ventilated area, away from excessive heat or sunlight.
Disposal
Dispose of material in accordance with federal, state, and local regulations

Common name/ Identifiers
Chemical Name Synonym CAS Number % (weight)

Calcium Carbonate or
Calcium/Magnesium
Carbonate

Limestone or
Dolomite

1317-65-3
16389-88-1

<50
And may contain one or more of the following:
Mixture-silicates and
aluminates Mica 12001-26-2 <10

Hydrated magnesium
silicate Talc (non-asbestiform) 14807-96-6 <5

Mixture-various metal
oxides Perlite 93763-70-3 <10

magnesium aluminum
phyllosilicate Attapulgite Clay 12174-11-7 <5

Magnesium silicate Sepiolite Clay 63800-37-3 <5

Magnesium aluminum
phyllosilicate Smectite Clay 1302-78-9 <5
Polyvinyl Acetate Latex 9003-20-7 <5
Ethylene Vinyl Acetate
Latex 24937-78-8 <5
Vinyl Acetate/Acrylic
Copolymer 108-05-4 <5

All concentrations are in percent by weight unless ingredient is a gas.

Section 3: Composition/Information on Ingredients

Section 2: Hazards Identification (Continued)

SDS No. GB-5002
Safety Data Sheet Ready Mix Joint Compounds

Page 3 of 7
Raw materials in this product contain respirable crystalline silica as an impurity. The OSHA PEL respirable crystalline silica has
been lowered to 0.05 mg/m3, effective June 23, 2016 with compliance dates of September 23, 2017 for construction and June
23, 2018 for general industry. Testing of this product and its constituents suggests that under normal conditions the expected
use of this product will not result in exposure to respirable crystalline silica that exceeds the OSHA PEL. Because every jobsite is
different, NGC cannot provide customers with any documentation that would exempt a customer from OSHA investigating the
customer’s jobsite for respirable silica. Actual exposures to respirable crystalline silica on a given jobsite must be determined by
workplace hygiene testing.

Inhalation Remove exposed individual to fresh air immediately. If breathing difficulty persists, seek medical attention.
Eye contact Do not rub or scratch eyes. Immediately flush eyes with water for 15 minutes.
Remove contact lenses (if applicable). Seek medical attention if irritation persists.
Skin contact Flush and wash skin with soap and water. Utilize lotions to alleviate dryness if present. Seek medical
attention if irritation persists.
Ingestion This product is not expected to be hazardous and no harmful effects are expected upon ingestion of small
amounts. Larger amounts may cause abdominal discomfort or possible obstruction of the digestive tract.
Seek medical attention if problems persist.
Medical Conditions aggravated by exposure
Pre-existing upper respiratory and lung diseases such as, but not limited to, bronchitis, emphysema and asthma. Pre-existing skin
diseases such as, but not limited to, rashes and dermatitis.

Extinguishing Media
Dry chemical, foam, water, or extinguishing media appropriate for surrounding fire.
Unusual Fire and Explosion Hazards
Mixture poses no fire-related hazard.
Special hazards arising from the mixture
None known
Special Protective Equipment and Precautions for Firefighters
A SCBA is recommended to limit exposures to combustion products when fighting any fire.

Personal precautions, protective equipment and emergency procedures
No special precautions required.
General recommendations:
Wear appropriate Personal Protective Equipment. (See Section 8)
Maintain proper ventilation.
Environmental precautions
This product does not present an ecological hazard to the environment.
Dispose of in accordance with applicable federal, state, and local regulations.
Methods and materials for containment and cleaning up
Shovel or scoop spilled material back into container for use, if possible, or disposal.
Maintain proper ventilation to minimize dust.
Avoid washing material down drains. This material will eventually set and can cause clogs.

Precautions for safe handling
Avoid breathing vapors when opening container.
Avoid breathing dust.
Minimize generation of dust.
Provide appropriate exhaust ventilation at places where dust is formed.
Section 4: First-Aid Measures

Section 5: Fire-Fighting Measures

Section 6: Accidental Release Measures

Section 7: Handling and Storage

SDS No. GB-5002
Safety Data Sheet Ready Mix Joint Compounds

Page 4 of 7
Avoid contact with eyes, skin and clothing.
Wear recommended personal protective equipment when handling. (See Section 8)
Conditions for safe storage, including any incompatibilities
Store material in a cool, dry, ventilated area, away from excessive heat or sunlight.
Keep from freezing to preserve usefulness.
Keep containers closed when not in use.
Avoid contact with strong acids.

Control Parameters
Exposure Limits
Component OSHA PEL
(mg/m3)
ACGIH TLV
(mg/m3)

Calcium Carbonate or Dolomite (limestone)
15 (T)
5 (R) 10 (T)
Mica 20 mppcf 3
Talc (non-asbestiform) 20 mppcf 2

Perlite
15 (T)
5 (R) 10 (T)
Attapulgite Clay 15 (T)
5 (R)
10 (T)
Sepiolite Clay 15 (T)
5 (R)
10 (T)
Smectite Clay 15 (T)
5 (R)
10 (T)
Crystalline Silica1 [(10) / (%SiO2+2)] (R);
[(30) / (%SiO2+2)] (T) 0.025(R)
Polyvinyl Acetate Latex NE NE
Ethylene Vinyl Acetate Latex NE NE

1 – Present as an impurity in raw materials NE- None Established
T- Total Dust Mppcf – million particles per cubic foot
R- Respirable Dust
Exposure Controls
Appropriate Engineering Controls
Work/Hygiene Practices: Utilize methods to minimize dust production. Use sanders equipped with vacuum capabilities
whenever possible. Utilize a light water spray when feasible.
Ventilation: Provide local and general exhaust ventilation sufficient to maintain a dust level below the PEL/TLV.
Personal Protective Equipment
Respiratory Protection
A NIOSH approved particulate respirator is recommended in poorly ventilated areas or if the PEL/TLV is exceeded. OSHA's 29
CFR 1910.134 (Respiratory Protection Standard) must be followed whenever work conditions require respirator use.
Eye Protection
Safety glasses or goggles.
Skin
Gloves, protective clothing and/or barrier creams may be utilized if conditions warrant.

Section 8: Exposure Controls/Personal Protection

SDS No. GB-5002
Safety Data Sheet Ready Mix Joint Compounds

Page 5 of 7

(a) Appearance: A white to gray paste
(b) Odor: Mild latex initially, Low to none after opening
(c) Odor threshold: Not available
(d) pH : 7-9
(e) Melting point/freezing point: Not Available
(f) Initial boiling point and boiling range: Not Available
(g) Flash point: Not available
(h) Evaporation rate: Not available
(i) Flammability (solid, gas): Not flammable
(j) Upper/lower flammability or explosive limits: Not available
(k) Vapor pressure: Not available
(l) Vapor density: Not available
(m) Relative density: ~1.0-1.8
(n) Solubility(ies): slightly soluble in water
(o) Partition coefficient: n-octanol/water: Not available
(p) Auto-ignition temperature: Not available
(q) Decomposition temperature: 825oC
(r) Viscosity: Not available
(s) Volatile organic compound (VOC) content: <2 g/l

(a) Reactivity: No data available
(b) Chemical stability: Stable in dry environments
(c) Possibility of hazardous reactions: None known
(d) Conditions to avoid (e.g., static discharge, shock, or vibration): None known
(e) Incompatible materials: Strong acids
(f) Hazardous decomposition products: None known. Above 825o C limestone (CaCO3)
decomposes to calcium oxide (CaO) and carbon dioxide.(CO2)

Information on Toxicological effects
Information on likely routes of exposure
Ingestion Possible abdominal obstruction.
Inhalation Dust may irritate respiratory system. Chronic exposure may result in lung disease. (See below)
Skin contact May cause irritation, rash, itching, or dermatitis.
Eye contact Dust may cause mechanical irritation.

Symptoms related to the physical, chemical and toxicological characteristics
Acute exposure to airborne dust concentrations in excess of the PEL/TLV may result in coughing, dyspnea, wheezing, and a
burning irritation of the nose, throat, and upper respiratory tract, along with possible impaired pulmonary function. Chronic
exposures may result in lung disease. (Silicosis and/or lung cancer)
Toxicological data
No toxicological data is available for this product. Toxicological information for components of this product listed below.
Acute toxicity Not available
Skin corrosion/irritation Not available
Serious eye damage/eye irritation Not available
Skin sensitization Not available
Respiratory sensitization Not available
Sensitization Not available
Mutagenicity Not available
Section 9: Physical and Chemical Properties

Section 10: Stability and Reactivity

Section 11: Toxicological Information

SDS No. GB-5002
Safety Data Sheet Ready Mix Joint Compounds

Page 6 of 7
Carcinogenicity Not available
This product contains crystalline silica (quartz) as a naturally occurring impurity in some of the raw materials. The International
Agency for Research on Cancer (IARC) classifies crystalline silica inhaled in the form of quartz or cristobalite from occupational sources
as carcinogenic to humans, Group 1. The National Toxicology Program (NTP) classifies respirable crystalline silica as a substance which
may be reasonably anticipated to be a carcinogen. OSHA does not regulate crystalline silica as a human carcinogen.
Some products may contain attapulgite clay. IARC classifies attapulgite (long fiber) carcinogenic to humans, Group 2B. Attapulgite is
not classified as a carcinogen by NTP or OSHA.
Exposures to respirable crystalline silica are not expected during the recommended use of this product. However, actual levels must
be determined by workplace Industrial Hygiene testing.
Reproductive effects Not available
Specific target organ toxicity –
single exposure Not available
Aspiration toxicity Not available

(a) Ecotoxicity (aquatic and terrestrial, where available): This product does not present an ecological
hazard to the environment.
(b) Persistence and degradability: Unknown
(c) Bioaccumulative potential: Limestone is a naturally occurring mineral. Biodegradation and/or
bioaccumulation potential is not applicable.
(d) Mobility in soil: Unknown
(e) Other adverse effects (such as hazardous to the ozone layer): None known

This material is not considered a hazardous waste. Dispose of according to Local, State, Federal, and Provincial Environmental
Regulations.

This product is not a DOT hazardous material
Shipping Name: Same as product name
ICAO/IATA/IMO: Not applicable

All ingredients are included on the TSCA inventory.
Federal Regulations
SARA Title III: Not listed under Sections 302, 304, and 313
CERCLA: Not listed
RCRA: Not listed
OSHA: Dust and potential respirable crystalline silica generated during product use may be hazardous.
State Regulations
California Prop 65: Respirable crystalline silica is known to the state of California to cause cancer. Industrial hygiene monitoring
during recommended use of this product failed to identify any respirable crystalline silica.
Canada WHMIS
All components of this product are included in the Canadian Domestic Substances List (DSL).
Crystalline silica: WHMIS Classification D2A

SDS Prepared by: National Gypsum Company
Section 12: Ecological Information

Section 13: Disposal Considerations

Section 14: Transport Information

Section 15: Regulatory Information

Section 16: Other Information

SDS No. GB-5002
Safety Data Sheet Ready Mix Joint Compounds

Page 7 of 7
2001 Rexford Road
Charlotte, NC 28211
Phone Number: [phone]

Date of Preparation: March 3, 2015
Revision indicators and Date
Effective Date Change: 6/15/2017 Supersedes: 5/9/2017
Format Changes: Updated chart in Section 3:Composition/Information on Ingredients

Key to Abbreviations
ACGIH American Conference of Governmental Industrial Hygienists
CAS Chemical Abstract Services Number
CFR Code of Federal Regulations
DOT Department of Transportation EPA Environmental Protection Agency
HEPA High Efficiency Particulate Air
HCS Hazard Communications Standard
HMIS Hazardous Material Identification System
IARC International Agency for Research on Cancer
IATA International Air Transport Association
ICAO International Civil Aviation Organization
IMO International Maritime Organization
NIOSH National Institute for Occupational Safety and Health
NFPA National Fire Protection Association
NTP National Toxicology Program
OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
PPE Personal Protective Equipment
TLV Threshold Limit Value
TSCA Toxic Substance Control Act
TWA Time Weighted Average
WHMIS Workplace Hazardous Materials Information System

The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee
or warranty of any kind expressed or implied is made with respect to the information contained herein. This safety data sheet
was prepared to comply with the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Disclaimer of Liability:
As the conditions or methods of use are beyond our control, we do not assume any responsibility and expressly
disclaim any liability for any use of the material. Information contained herein is believed to be true and accurate,
but all statements or suggestions are made without any warranty, express or implied, regarding accuracy of the
information, the hazards connected with the use of the material, or the results to be obtained for the use thereof.

Section 16: Other Information (Continued)

SAFETY DATA SHEET
Based upon Regulation (EC) No 1907/2006, as amended by Regulation (EU) No 2015/830
SOUDAFOAM WINDOW & DOOR GUN GRADE
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name : SOUDAFOAM WINDOW & DOOR GUN GRADE
Registration number REACH : Not applicable (mixture)
Product type REACH : Mixture
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1 Relevant identified uses
polyurethane
1.2.2 Uses advised against
No uses advised against known
1.3. Details of the supplier of the safety data sheet
Supplier of the safety data sheet
SOUDAL N.V. Everdongenlaan 18-20 B-2300 Turnhout ☎ [phone] [phone] [e-mail]
Manufacturer of the product
SOUDAL N.V. Everdongenlaan 18-20 B-2300 Turnhout ☎ [phone] [phone] [e-mail]
1.4. Emergency telephone number
24h/24h (Telephone advice: English, French, German, Dutch):
[phone] (BIG)
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classified as dangerous according to the criteria of Regulation (EC) No 1272/2008
Class Category Hazard statements
Aerosol category 1 H222: Extremely flammable aerosol.
Aerosol category 1 H229: Pressurised container: May burst if heated.
Carc. category 2 H351: Suspected of causing cancer.
Lact. - H362: May cause harm to breast-fed children.
Acute Tox. category 4 H332: Harmful if inhaled.
STOT RE category 2 H373: May cause damage to organs through prolonged or repeated exposure if inhaled.
Eye Irrit. category 2 H319: Causes serious eye irritation.
STOT SE category 3 H335: May cause respiratory irritation.
Skin Irrit. category 2 H315: Causes skin irritation.
Resp. Sens. category 1 H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Skin Sens. category 1 H317: May cause an allergic skin reaction.
Aquatic Chronic category 4 H413: May cause long lasting harmful effects to aquatic life.
2.2. Label elements

Contains: polymethylene polyphenyl isocyanate; alkanes, C14-17, chloro.

Created by: Brandweerinformatiecentrum voor gevaarlijke stoffen vzw (BIG)
Technische Schoolstraat 43 A, B-2440 Geel
http://www.big.be
' BIG vzw
Publication date: 2002-03-23 134-15960-503-en Date of revision: 2016-08-08
Reason for revision: 15.1
Revision number: 0501 Product number: 51803 1 / 17

SOUDAFOAM WINDOW & DOOR GUN GRADE
Signal word Danger
H-statements
H222 Extremely flammable aerosol.
H229 Pressurised container: May burst if heated.
H351 Suspected of causing cancer.
H362 May cause harm to breast-fed children.
H332 Harmful if inhaled.
H373 May cause damage to organs through prolonged or repeated exposure if inhaled.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H315 Causes skin irritation.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317 May cause an allergic skin reaction.
H413 May cause long lasting harmful effects to aquatic life.
P-statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Do not pierce or burn, even after use.
P308 + P313 IF exposed or concerned: Get medical advice/attention.
P405 Store locked up.
P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50 C/ 122F.
P501 Dispose of contents/container in accordance with local/regional/national/international regulation.
Supplemental information
- Persons already sensitised to diisocyanates may develop allergic reactions when using this product.
- Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product.
- This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e.
type A1 according to standard EN 14387) is used.
2.3. Other hazards
Gas/vapour spreads at floor level: ignition hazard
SECTION 3: Composition/information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name
REACH Registration No
CAS No
EC No Conc. (C) Classification according to CLP Note Remark
propane
01-2119486944-21 74-98-6
200-827-9
1%<C<10% Flam. Gas 1; H220
Press. Gas - Liquefied gas; H280
(1)(2)(10) Propellant
dimethyl ether
01-2119472128-37
115-10-6
204-065-8
1%<C<15% Flam. Gas 1; H220
Press. Gas - Liquefied gas; H280
(1)(2)(10) Propellant
polymethylene polyphenyl isocyanate

9016-87-9

10%<C<40% Carc. 2; H351
Acute Tox. 4; H332
STOT RE 2; H373
Eye Irrit. 2; H319
STOT SE 3; H335
Skin Irrit. 2; H315
Resp. Sens. 1; H334
Skin Sens. 1; H317
(1)(2)(8)(10) Polymer
isobutane
01-2119485395-27
75-28-5
200-857-2
1%<C<10% Flam. Gas 1; H220
Press. Gas - Liquefied gas; H280
(1)(2)(10) Propellant
alkanes, C14-17, chloro
01-2119519269-33 85535-85-9
287-477-0
1%<C<20% Lact. ; H362
Aquatic Acute 1; H400
Aquatic Chronic 1; H410
(1)(2)(8)(10) UVCB

Reason for revision: 15.1 Publication date: 2002-03-23
Date of revision: 2016-08-08
Revision number: 0501 Product number: 51803 2 / 17
SOUDAFOAM WINDOW & DOOR GUN GRADE
reaction mass of tris(2-chloropropyl) phosphate and
tris(2-chloro-1-methylethyl) phosphate and
phosphoric acid, bis(2-chloro-1-methylethyl) 2-
chloropropyl ester and phosphoric acid, 2-chloro-1-
methylethyl bis(2-chloropropyl) ester
01-2119486772-26

1%C<5% Acute Tox. 4; H302 (1)(10) Reaction product
(1,3-butadiene, conc<0.1%)

(1) For H-statements in full: see heading 16
(2) Substance with a Community workplace exposure limit
(8) Specific concentration limits, see heading 16
(10) Subject to restrictions of Annex XVII of Regulation (EC) No. 1907/2006
SECTION 4: First aid measures
4.1. Description of first aid measures
General:
GENERAL. Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory arrest: artificial respiration or oxygen. Cardiac arrest:
perform resuscitation. Victim conscious with laboured breathing: half-seated. Victim in shock: on his back with legs slightly raised. Vomiting: prevent
asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no warming up). Keep watching the victim. Give psychological aid. Keep the victim
calm, avoid physical strain. Depending on the victim’s condition: doctor/hospital.
After inhalation:
Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service.
After skin contact:
Wash immediately with lots of water. Take victim to a doctor if irritation persists.
After eye contact:
Rinse immediately with plenty of water. Do not apply neutralizing agents. Take victim to an ophthalmologist if irritation persists.
After ingestion:
Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Do not induce vomiting. Consult a doctor/medical service if you feel unwell.
4.2. Most important symptoms and effects, both acute and delayed
4.2.1 Acute symptoms
After inhalation:
Dry/sore throat. Coughing. Irritation of the respiratory tract. Irritation of the nasal mucous membranes. Runny nose. FOLLOWING SYMPTOMS MAY APPEAR
LATER: Possible inflammation of the respiratory tract. Risk of lung oedema. Respiratory difficulties.
After skin contact:
Tingling/irritation of the skin.
After eye contact:
Irritation of the eye tissue. Lacrimation.
After ingestion:
Not applicable.
4.2.2 Delayed symptoms
No effects known.
4.3. Indication of any immediate medical attention and special treatment needed
If applicable and available it will be listed below.
SECTION 5: Firefighting measures
5.1. Extinguishing media
5.1.1 Suitable extinguishing media:
Quantities of water. Polyvalent foam. BC powder. Carbon dioxide.
5.1.2 Unsuitable extinguishing media:
No unsuitable extinguishing media known.
5.2. Special hazards arising from the substance or mixture
On burning: release of toxic and corrosive gases/vapours (nitrous vapours, hydrogen chloride, carbon monoxide - carbon dioxide). Pressurised container: May
burst if heated. May polymerize on exposure to temperature rise. On heating: release of toxic/combustible gases/vapours (hydrogen cyanide).
5.3. Advice for firefighters
5.3.1 Instructions:
If exposed to fire cool the closed containers by spraying with water. Physical explosion risk: extinguish/cool from behind cover. Do not move the load if
exposed to heat. After cooling: persistant risk of physical explosion. Dilute toxic gases with water spray. Take account of toxic/corrosive precipitation water.
5.3.2 Special protective equipment for fire-fighters:
Gloves. Protective goggles. Head/neck protection. Protective clothing. Heat/fire exposure: compressed air/oxygen apparatus.

Reason for revision: 15.1 Publication date: 2002-03-23
Date of revision: 2016-08-08
Revision number: 0501 Product number: 51803 3 / 17
SOUDAFOAM WINDOW & DOOR GUN GRADE
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Stop engines and no smoking. No naked flames or sparks. Spark- and explosionproof appliances and lighting equipment.
6.1.1 Protective equipment for non-emergency personnel
See heading 8.2
6.1.2 Protective equipment for emergency responders
Gloves. Protective goggles. Head/neck protection. Protective clothing.
Suitable protective clothing
See heading 8.2
6.2. Environmental precautions
Dam up the solid spill. Use appropriate containment to avoid environmental contamination.
6.3. Methods and material for containment and cleaning up
Allow product to solidify and remove it by mechanical means. Carefully collect the spill/leftovers. Clean (treat) contaminated surfaces with acetone. Take collected
spill to manufacturer/competent authority. Wash clothing and equipment after handling.
6.4. Reference to other sections
See heading 13.
SECTION 7: Handling and storage
The information in this section is a general description. If applicable and available, exposure scenarios are attached in annex. Always use the relevant exposure
scenarios that correspond to your identified use.
7.1. Precautions for safe handling
Use spark-/explosionproof appliances and lighting system. Keep away from naked flames/heat. Keep away from ignition sources/sparks. Observe very strict
hygiene - avoid contact. Remove contaminated clothing immediately.
7.2. Conditions for safe storage, including any incompatibilities
7.2.1 Safe storage requirements:
Storage temperature: < 50 C. Store in a cool area. Keep out of direct sunlight. Store in a dry area. Ventilation at floor level. Fireproof storeroom. Unauthorized
persons are not admitted. Meet the legal requirements. Max. storage time: 1 year(s).
7.2.2 Keep away from:
Heat sources, ignition sources, (strong) acids, (strong) bases.
7.2.3 Suitable packaging material:
Aerosol.
7.2.4 Non suitable packaging material:
No data available
7.3. Specific end use(s)
If applicable and available, exposure scenarios are attached in annex. See information supplied by the manufacturer.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
8.1.1 Occupational exposure
a) Occupational exposure limit values
If limit values are applicable and available these will be listed below.
EU
Dimethylether Time-weighted average exposure limit 8 h (Indicative occupational
exposure limit value)
1000 ppm
Time-weighted average exposure limit 8 h (Indicative occupational
exposure limit value)
1920 mg/m‡
Belgium
Hydrocarbures aliphatiques sous forme gazeuse : (Alcanes C1-
C4)
Time-weighted average exposure limit 8 h 1000 ppm
Oxyde de dimØthyle Time-weighted average exposure limit 8 h 1000 ppm
Time-weighted average exposure limit 8 h 1920 mg/m‡
The Netherlands
Dimethylether Time-weighted average exposure limit 8 h (Public occupational exposure
limit value)
496 ppm
Time-weighted average exposure limit 8 h (Public occupational exposure
limit value)
950 mg/m‡
Reason for revision: 15.1 Publication date: 2002-03-23
Date of revision: 2016-08-08
Revision number: 0501 Product number: 51803 4 / 17
SOUDAFOAM WINDOW & DOOR GUN GRADE
Dimethylether Short time value (Public occupational exposure limit value) 783 ppm
Short time value (Public occupational exposure limit value) 1500 mg/m‡
France
Oxyde de dimØthyle Time-weighted average exposure limit 8 h (VRI: Valeur rØglementaire
indicative)
1000 ppm
Time-weighted average exposure limit 8 h (VRI: Valeur rØglementaire
indicative)
1920 mg/m‡
Germany
Chloralkane, C14-17 (Chlorierte Paraffine C14-17 ) Time-weighted average exposure limit 8 h (TRGS 900) 0.3 ppm
Time-weighted average exposure limit 8 h (TRGS 900) 6 mg/m‡
Dimethylether Time-weighted average exposure limit 8 h (TRGS 900) 1000 ppm
Time-weighted average exposure limit 8 h (TRGS 900) 1900 mg/m‡
Isobutan Time-weighted average exposure limit 8 h (TRGS 900) 1000 ppm
Time-weighted average exposure limit 8 h (TRGS 900) 2400 mg/m‡
pMDI (als MDI berechnet) Time-weighted average exposure limit 8 h (TRGS 900) 0.05 mg/m‡
Propan Time-weighted average exposure limit 8 h (TRGS 900) 1000 ppm
Time-weighted average exposure limit 8 h (TRGS 900) 1800 mg/m‡
UK
Dimethyl ether Time-weighted average exposure limit 8 h (Workplace exposure limit
(EH40/2005))
400 ppm
Time-weighted average exposure limit 8 h (Workplace exposure limit
(EH40/2005))
766 mg/m‡
Short time value (Workplace exposure limit (EH40/2005)) 500 ppm
Short time value (Workplace exposure limit (EH40/2005)) 958 mg/m‡
Isocyanates, all (as -NCO) Except methyl isocyanate Time-weighted average exposure limit 8 h (Workplace exposure limit
(EH40/2005))
0.02 mg/m‡
Short time value (Workplace exposure limit (EH40/2005)) 0.07 mg/m‡
USA (TLV-ACGIH)
Butane, all isomers Short time value (TLV - Adopted Value) 1000 ppm
b) National biological limit values
If limit values are applicable and available these will be listed below.
8.1.2 Sampling methods
If applicable and available it will be listed below.
Isocyanates NIOSH 5521
Isocyanates NIOSH 5522
8.1.3 Applicable limit values when using the substance or mixture as intended
If limit values are applicable and available these will be listed below.
8.1.4 DNEL/PNEC values
DNEL/DMEL - Workers
alkanes, C14-17, chloro
Effect level (DNEL/DMEL) Type Value Remark
DNEL Long-term systemic effects inhalation 6.7 mg/m‡
Long-term systemic effects dermal 47.9 mg/kg bw/day
reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl
Effect level (DNEL/DMEL) Type Value Remark
DNEL Long-term systemic effects inhalation 5.82 mg/m‡
Acute systemic effects inhalation 22.4 mg/m‡
Long-term systemic effects dermal 2.08 mg/kg bw/day
Acute systemic effects dermal 8 mg/kg bw/day
DNEL/DMEL - General population
alkanes, C14-17, chloro
Effect level (DNEL/DMEL) Type Value Remark
DNEL Long-term systemic effects inhalation 2 mg/m‡
Long-term systemic effects dermal 28.75 mg/kg bw/day
Long-term systemic effects oral 0.58 mg/kg bw/day

Reason for revision: 15.1 Publication date: 2002-03-23
Date of revision: 2016-08-08
Revision number: 0501 Product number: 51803 5 / 17
SOUDAFOAM WINDOW & DOOR GUN GRADE
reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl
dh hi id2hl 1 hl hlbi(2 hl l) Effect level (DNEL/DMEL) Type Value Remark
DNEL Long-term systemic effects inhalation 1.46 mg/m‡
Acute systemic effects inhalation 11.2 mg/m‡
Long-term systemic effects dermal 1.04 mg/kg bw/day
Acute systemic effects dermal 4 mg/kg bw/day
Long-term systemic effects oral 0.52 mg/kg bw/day
PNEC
alkanes, C14-17, chloro
Compartments Value Remark
Fresh water 1 g/l
Marine water 0.2 g/l
STP 80 mg/l
Fresh water sediment 13 mg/kg sediment dw
Marine water sediment 2.6 mg/kg sediment dw
Soil 11.9 mg/kg soil dw
Oral 10 mg/kg food
reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl
Compartments Value Remark
Fresh water 0.64 mg/l
Marine water 0.064 mg/l
Aqua (intermittent releases) 0.51 mg/l
STP 7.84 mg/l
Fresh water sediment 13.4 mg/kg sediment dw
Marine water sediment 1.34 mg/kg sediment dw
Soil 1.7 mg/kg soil dw
Oral 11.6 mg/kg food
8.1.5 Control banding
If applicable and available it will be listed below.
8.2. Exposure controls
The information in this section is a general description. If applicable and available, exposure scenarios are attached in annex. Always use the relevant exposure
scenarios that correspond to your identified use.
8.2.1 Appropriate engineering controls
Use spark-/explosionproof appliances and lighting system. Keep away from naked flames/heat. Keep away from ignition sources/sparks. Measure the
concentration in the air regularly.
8.2.2 Individual protection measures, such as personal protective equipment
Observe very strict hygiene - avoid contact. Do not eat, drink or smoke during work.
a) Respiratory protection:
Wear gas mask with filter type A if conc. in air > exposure limit.
b) Hand protection:
Gloves.
Materials Breakthrough time Thickness
LDPE (Low Density Poly Ethylene) 10 minutes 0.025 mm
c) Eye protection:
Protective goggles.
d) Skin protection:
Head/neck protection. Protective clothing.
8.2.3 Environmental exposure controls:
See headings 6.2, 6.3 and 13
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical form Aerosol
Odour Characteristic odour
Odour threshold No data available
Colour Variable in colour, depending on the composition
Particle size Not applicable
Explosion limits No data available
Flammability Extremely flammable aerosol.
Log Kow Not applicable (mixture)
Reason for revision: 15.1 Publication date: 2002-03-23
Date of revision: 2016-08-08
Revision number: 0501 Product number: 51803 6 / 17
SOUDAFOAM WINDOW & DOOR GUN GRADE
Dynamic viscosity No data available
Kinematic viscosity No data available
Melting point No data available
Boiling point No data available
Flash point Not applicable
Evaporation rate No data available
Relative vapour density > 1
Vapour pressure No data available
Solubility organic solvents ; soluble
water ; insoluble
Relative density 0.95 ; 20 C
Decomposition temperature No data available
Auto-ignition temperature No data available
Explosive properties No chemical group associated with explosive properties
Oxidising properties No chemical group associated with oxidising properties
pH No data available
9.2. Other information
Absolute density 950 kg/m‡ ; 20 C
SECTION 10: Stability and reactivity
10.1. Reactivity
May be ignited by sparks. Gas/vapour spreads at floor level: ignition hazard. No data available.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
May polymerize with many compounds e.g.: (strong) bases and amines. Reacts violently with (some) acids/bases.
10.4. Conditions to avoid
Use spark-/explosionproof appliances and lighting system. Keep away from naked flames/heat. Keep away from ignition sources/sparks.
10.5. Incompatible materials
(strong) acids, (strong) bases.
10.6. Hazardous decomposition products
On heating: release of toxic/combustible gases/vapours (hydrogen cyanide). On burning: release of toxic and corrosive gases/vapours (nitrous vapours,
hydrogen chloride, carbon monoxide - carbon dioxide).
SECTION 11: Toxicological information
11.1. Information on toxicological effects
11.1.1 Test results
Acute toxicity
SOUDAFOAM WINDOW & DOOR GUN GRADE
No (test)data on the mixture available
polymethylene polyphenyl isocyanate
Route of exposure Parameter Method Value Exposure time Species Value
determination
Remark
Oral LD50 > 10000 mg/kg Rat Literature study
Dermal LD50 > 5000 mg/kg Rabbit Literature study
Inhalation (vapours) LD50 10 mg/l - 20 mg/l 4 h Rat Literature study
Inhalation category 4 Literature study
alkanes, C14-17, chloro
Route of exposure Parameter Method Value Exposure time Species Value
determination
Remark
Oral LD50 > 4000 mg/kg bw Rat (male/female) Experimental value
Dermal LD50 > 13500 mg/kg bw 24 h Rabbit Read-across
Inhalation (vapours) LC50 > 48170 mg/m‡ 1 h Rat Read-across

Reason for revision: 15.1 Publication date: 2002-03-23
Date of revision: 2016-08-08
Revision number: 0501 Product number: 51803 7 / 17
SOUDAFOAM WINDOW & DOOR GUN GRADE
reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl ester
and phosphoric acid, 2-chloro-1-methylethyl bis(2-chloropropyl) ester
Route of exposure Parameter Method Value Exposure time Species Value
determination
Remark
Oral LD50 EU Method B.1 tris 632 mg/kg bw Rat (female) Experimental value
Dermal LD50 OECD 402 > 2000 mg/kg bw 24 h Rat (male/female) Experimental value
Inhalation (aerosol) LC50 OECD 403 > 7 mg/l 4 h Rat (male/female) Experimental value
Judgement is based on the relevant ingredients
Conclusion
Harmful if inhaled.
Not classified as acute toxic in contact with skin
Not classified as acute toxic if swallowed
Corrosion/irritation

SOUDAFOAM WINDOW & DOOR GUN GRADE
No (test)data on the mixture available
polymethylene polyphenyl isocyanate
Route of exposure Result Method Exposure time Time point Species Value
determination
Remark
Eye Irritating;
category 2
Literature study
Skin Irritating;
category 2
Literature study
Inhalation Irritating;
STOT SE cat.3
Literature study
alkanes, C14-17, chloro
Route of exposure Result Method Exposure time Time point Species Value
determination
Remark
Eye Slightly irritating Rabbit Expert judgement
Skin Slightly irritating OECD 404 4 h 24; 72 hours Rabbit Expert judgement
reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl ester
and phosphoric acid, 2-chloro-1-methylethyl bis(2-chloropropyl) ester
Route of exposure Result Method Exposure time Time point Species Value
determination
Remark
Eye Not irritating OECD 405 24 h 7 days Rabbit Experimental value
Skin Not irritating OECD 404 4 h 7 days Rabbit Experimental value
Classification is based on the relevant ingredients
Conclusion
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

Respiratory or skin sensitisation
SOUDAFOAM WINDOW & DOOR GUN GRADE
No (test)data on the mixture available
polymethylene polyphenyl isocyanate
Route of exposure Result Method Exposure time Observation time
point
Species Value determination Remark
Skin Sensitizing;
category 1
Literature study
Inhalation Sensitizing;
category 1
Literature study
alkanes, C14-17, chloro
Route of exposure Result Method Exposure time Observation time
point
Species Value determination Remark
Skin Not sensitizing Guinea pig
maximisation test
48 hours Guinea pig Experimental value
reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl ester
and phosphoric acid, 2-chloro-1-methylethyl bis(2-chloropropyl) ester
Route of exposure Result Method Exposure time Observation time
point
Species Value determination Remark
Skin Not sensitizing OECD 429 Mouse (female) Experimental value
Classification is based on the relevant ingredients
Conclusion
Reason for revision: 15.1 Publication date: 2002-03-23
Date of revision: 2016-08-08
Revision number: 0501 Product number: 51803 8 / 17
SOUDAFOAM WINDOW & DOOR GUN GRADE
May cause an allergic skin reaction.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Specific target organ toxicity
SOUDAFOAM WINDOW & DOOR GUN GRADE
No (test)data on the mixture available
polymethylene polyphenyl isocyanate
Route of exposure Parameter Method Value Organ Effect Exposure time Species Value
determination
Inhalation STOT RE cat.2 Literature study
alkanes, C14-17, chloro
Route of exposure Parameter Method Value Organ Effect Exposure time Species Value
determination
Oral (diet) NOAEL Equivalent to
OECD 408
300 ppm Liver; kidney No adverse
systemic effects
13 week(s) Rat
(male/female)
Experimental
value
Oral (diet) NOAEL Equivalent to
OECD 408
100 mg/kg
bw/day
Kidney No adverse
systemic effects
13 week(s) Rat
(male/female)
Experimental
value
Dermal Data waiving
Inhalation Data waiving
reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl ester
and phosphoric acid, 2-chloro-1-methylethyl bis(2-chloropropyl) ester
Route of exposure Parameter Method Value Organ Effect Exposure time Species Value
determination
Oral (diet) NOAEL Subchronic
toxicity test
171 mg/kg
bw/day
No effect 13 weeks (daily) Rat (female) Experimental
value
Oral (diet) LOAEL Subchronic
toxicity test
52 mg/kg
bw/day
Liver Weight gain 13 weeks (daily) Rat (male) Experimental
value
Inhalation
(vapours)
Dose level 0.586 mg/l air No effect Mouse (male) Experimental
value
Classification is based on the relevant ingredients
Conclusion
May cause damage to organs through prolonged or repeated exposure if inhaled.
Not classified as sub-chronically toxic in contact with skin
Not classified as sub-chronically toxic if swallowed
Mutagenicity (in vitro)

SOUDAFOAM WINDOW & DOOR GUN GRADE
No (test)data on the mixture available
alkanes, C14-17, chloro
Result Method Test substrate Effect Value determination
Negative with metabolic
activation, negative without
metabolic activation
OECD 471 Bacteria (S.typhimurium) No effect Experimental value
reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl ester
and phosphoric acid, 2-chloro-1-methylethyl bis(2-chloropropyl) ester
Result Method Test substrate Effect Value determination
Negative with metabolic
activation, negative without
metabolic activation
OECD 482 Rat liver cells Experimental value
Negative without metabolic
activation, positive with
metabolic activation
OECD 476 Mouse (lymphoma L5178Y
cells)
Experimental value
Mutagenicity (in vivo)
SOUDAFOAM WINDOW & DOOR GUN GRADE
No (test)data on the mixture available
alkanes, C14-17, chloro
Result Method Exposure time Test substrate Organ Value determination
Negative Equivalent to OECD
475
5 day(s) Rat (male) Bone marrow Experimental value
Negative Equivalent to OECD
474
Mouse (male/female) Bone marrow Experimental value

Reason for revision: 15.1 Publication date: 2002-03-23
Date of revision: 2016-08-08
Revision number: 0501 Product number: 51803 9 / 17
SOUDAFOAM WINDOW & DOOR GUN GRADE
reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl ester
and phosphoric acid, 2-chloro-1-methylethyl bis(2-chloropropyl) ester
Result Method Exposure time Test substrate Organ Value determination
Negative OECD 474 Mouse (male/female) Bone marrow Experimental value
Classification is based on the relevant ingredients
Conclusion
Not classified for mutagenic or genotoxic toxicity
Carcinogenicity

SOUDAFOAM WINDOW & DOOR GUN GRADE
No (test)data on the mixture available
polymethylene polyphenyl isocyanate
Route of
exposure
Parameter Method Value Exposure time Species Effect Organ Value
determination
Unknown category 2 Literature study
alkanes, C14-17, chloro
Route of
exposure
Parameter Method Value Exposure time Species Effect Organ Value
determination
Oral LOAEL Equivalent to
OECD 451
312 mg/kg
bw/day
104 weeks (5
days/week)
Rat
(male/female)
Carcinogenicity Read-across
Oral LOAEL Equivalent to
OECD 451
125 mg/kg
bw/day
103 weeks (5
days/week)
Mouse
(male/female)
Carcinogenicity Read-across
reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl ester
and phosphoric acid, 2-chloro-1-methylethyl bis(2-chloropropyl) ester
Route of
exposure
Parameter Method Value Exposure time Species Effect Organ Value
determination
Inhalation Data waiving
Dermal Data waiving
Oral Data waiving
Classification is based on the relevant ingredients
Conclusion
Suspected of causing cancer.

Reproductive toxicity
SOUDAFOAM WINDOW & DOOR GUN GRADE
No (test)data on the mixture available
alkanes, C14-17, chloro
Parameter Method Value Exposure time Species Effect Organ Value
determination
Developmental toxicity NOAEL Equivalent to
OECD 414
100 mg/kg
bw/day
22 day(s) Rabbit No effect Experimental
value
Maternal toxicity NOAEL Equivalent to
OECD 414
100 mg/kg
bw/day
22 day(s) Rabbit No effect Experimental
value
Effects on fertility NOAEL (P) OECD 421 100 mg/kg
bw/day
9 week(s) Rat (male) No effect Male
reproductive
organ
Experimental
value
NOAEL (P) OECD 421 100 mg/kg
bw/day
11 week(s) - 12
week(s)
Rat (female) No effect Female
reproductive
organ
Experimental
value
Effects on lactation May cause
harm to breast-
fed children.
Experimental
value
reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl ester
and phosphoric acid, 2-chloro-1-methylethyl bis(2-chloropropyl) ester
Parameter Method Value Exposure time Species Effect Organ Value
determination
Developmental toxicity LOAEL OECD 416 99 mg/kg
bw/day
Rat (female) Embryotoxicity Experimental
value
Effects on fertility LOAEL OECD 416 99 mg/kg
bw/day
Rat
(male/female)
Weight changes Female
reproductive
organ
Experimental
value
Classification is based on the relevant ingredients
Conclusion
May cause harm to breast-fed children.
Not classified for reprotoxic or developmental toxicity
Reason for revision: 15.1 Publication date: 2002-03-23
Date of revision: 2016-08-08
Revision number: 0501 Product number: 51803 10 / 17
SOUDAFOAM WINDOW & DOOR GUN GRADE

Toxicity other effects
SOUDAFOAM WINDOW & DOOR GUN GRADE
No (test)data on the mixture available
alkanes, C14-17, chloro
Parameter Method Value Organ Effect Exposure time Species Value
determination
Other Skin Skin dryness or
cracking
Rat Experimental value
Chronic effects from short and long-term exposure

SOUDAFOAM WINDOW & DOOR GUN GRADE
ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Feeling of weakness. Itching. Skin rash/inflammation. May stain the skin. Dry skin. Coughing. Possible
inflammation of the respiratory tract. Respiratory difficulties.
SECTION 12: Ecological information
12.1. Toxicity

SOUDAFOAM WINDOW & DOOR GUN GRADE
No (test)data on the mixture available
polymethylene polyphenyl isocyanate
Parameter Method Value Duration Species Test design Fresh/salt
water
Value determination
Acute toxicity other aquatic
organisms
LC50 > 1000 mg/l 96 h Literature study
Toxicity aquatic micro-
organisms
EC50 OECD 209 > 100 mg/l Activated sludge Literature study
alkanes, C14-17, chloro
Parameter Method Value Duration Species Test design Fresh/salt
water
Value determination
Acute toxicity fishes LC50 OECD 203 > 10000 mg/l 96 h Alburnus
alburnus
Static system Salt water Experimental value
Acute toxicity invertebrates EC50 OECD 203 0.0077 mg/l 48 h Daphnia magna Static system Fresh water Experimental value
Toxicity algae and other aquatic
plants
EC50 OECD 201 > 3.2 mg/l 72 h Pseudokirchneriel
la subcapitata
Static system Fresh water Experimental value;
Growth rate
Long-term toxicity fish NOEC OECD 204 > 125 g/l 14 day(s) Alburnus
alburnus
Semi-static
system
Salt water Experimental value
Long-term toxicity invertebrates NOEC OECD 202 0.01 mg/l 21 day(s) Daphnia magna Static system Fresh water Experimental value
reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl
ester and phosphoric acid, 2-chloro-1-methylethyl bis(2-chloropropyl) ester
Parameter Method Value Duration Species Test design Fresh/salt
water
Value determination
Acute toxicity fishes LC50 Other 56.2 mg/l 96 h Brachydanio rerioStatic system Fresh water Experimental value;
GLP
Acute toxicity invertebrates LC50 131 mg/l 48 h Daphnia magna Static system Fresh water Locomotor effect
Toxicity algae and other aquatic
plants
ErC50 OECD 201 82 mg/l 72 h Pseudokirchneriel
la subcapitata
Static system Fresh water Experimental value;
GLP
Long-term toxicity invertebrates NOEC OECD 202 32 mg/l 21 day(s) Daphnia magna Semi-static
system
Fresh water Experimental value;
GLP
Toxicity aquatic micro-
organisms
EC50 ISO 8192 784 mg/l 3 h Activated sludge Static system Fresh water Experimental value;
GLP
Classification of the mixture is based on test data on the mixture as a whole
Conclusion
May cause long lasting harmful effects to aquatic life.
12.2. Persistence and degradability
polymethylene polyphenyl isocyanate
Biodegradation water
Method Value Duration Value determination
OECD 302C: Inherent Biodegradability:
Modified MITI Test (II)
< 60 % Experimental value

Reason for revision: 15.1 Publication date: 2002-03-23
Date of revision: 2016-08-08
Revision number: 0501 Product number: 51803 11 / 17
SOUDAFOAM WINDOW & DOOR GUN GRADE
alkanes, C14-17, chloro
Biodegradation water
Method Value Duration Value determination
OECD 301D: Closed Bottle Test 63 % 60 day(s) Experimental value
Biodegradation soil
Method Value Duration Value determination
51 % - 57 % 36 h Experimental value
reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl
ester and phosphoric acid, 2-chloro-1-methylethyl bis(2-chloropropyl) ester
Biodegradation water
Method Value Duration Value determination
OECD 301E: Modified OECD Screening Test 14 %; GLP 28 day(s) Experimental value
Conclusion
Contains non readily biodegradable component(s)
12.3. Bioaccumulative potential
SOUDAFOAM WINDOW & DOOR GUN GRADE
Log Kow
Method Remark Value Temperature Value determination
Not applicable (mixture)
polymethylene polyphenyl isocyanate
BCF fishes
Parameter Method Value Duration Species Value determination
BCF 1 Pisces Literature study
Log Kow
Method Remark Value Temperature Value determination
No data available
alkanes, C14-17, chloro
BCF fishes
Parameter Method Value Duration Species Value determination
BCF OECD 305 6660 35 day(s) Oncorhynchus mykiss Experimental value
Log Kow
Method Remark Value Temperature Value determination
5.47 - 8.01 Experimental value
> 5
reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl
ester and phosphoric acid, 2-chloro-1-methylethyl bis(2-chloropropyl) ester
BCF fishes
Parameter Method Value Duration Species Value determination
BCF OECD 305 0.8 - 14 6 week(s) Cyprinus carpio Experimental value
Log Kow
Method Remark Value Temperature Value determination
EU Method A.8 2.68 30 C Experimental value
Conclusion
Contains bioaccumulative component(s)
12.4. Mobility in soil
alkanes, C14-17, chloro
(log) Koc
Parameter Method Value Value determination
log Koc 5 Experimental value

Reason for revision: 15.1 Publication date: 2002-03-23
Date of revision: 2016-08-08
Revision number: 0501 Product number: 51803 12 / 17
SOUDAFOAM WINDOW & DOOR GUN GRADE
reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl
ester and phosphoric acid, 2-chloro-1-methylethyl bis(2-chloropropyl) ester
(log) Koc
Parameter Method Value Value determination
log Koc EU Method C.19 2.76 Experimental value
Volatility (Henry's Law constant H)
Value Method Temperature Remark Value determination
0.00042 Pa.m‡/mol 25 C Read-across
Percent distribution
Method Fraction air Fraction biota Fraction
sediment
Fraction soil Fraction water Value determination
Mackay level I 0.01 % 0 % 3.55 % 3.52 % 92.89 % Read-across
Conclusion
Contains component(s) that adsorb(s) into the soil
Contains component(s) with potential for mobility in the soil
12.5. Results of PBT and vPvB assessment
Does not contain component(s) that meet(s) the criteria of PBT and/or vPvB as listed in Annex XIII of Regulation (EC) No 1907/2006.
12.6. Other adverse effects
SOUDAFOAM WINDOW & DOOR GUN GRADE
Fluorinated greenhouse gases (Regulation (EU) No 517/2014)
None of the known components is included in the list of fluorinated greenhouse gases (Regulation (EU) No 517/2014)
Ozone-depleting potential (ODP)
Not classified as dangerous for the ozone layer (Regulation (EC) No 1005/2009)
SECTION 13: Disposal considerations
The information in this section is a general description. If applicable and available, exposure scenarios are attached in annex. Always use the relevant exposure
scenarios that correspond to your identified use.
13.1. Waste treatment methods
13.1.1 Provisions relating to waste
Hazardous waste according to Directive 2008/98/EC, as amended by Regulation (EU) No 1357/2014.
Waste material code (Directive 2008/98/EC, Decision 2000/0532/EC).
08 05 01* (wastes not otherwise specified in 08: waste isocyanates).
16 05 04* (gases in pressure containers and discarded chemicals: gases in pressure containers (including halons) containing hazardous substances).
Depending on branch of industry and production process, also other waste codes may be applicable.
13.1.2 Disposal methods
Recycle/reuse. Remove waste in accordance with local and/or national regulations. Hazardous waste shall not be mixed together with other waste. Different
types of hazardous waste shall not be mixed together if this may entail a risk of pollution or create problems for the further management of the waste.
Hazardous waste shall be managed responsibly. All entities that store, transport or handle hazardous waste shall take the necessary measures to prevent
risks of pollution or damage to people or animals. Specific treatment. Do not discharge into drains or the environment.
13.1.3 Packaging/Container
Waste material code packaging (Directive 2008/98/EC).
15 01 10* (packaging containing residues of or contaminated by dangerous substances).
SECTION 14: Transport information
Road (ADR)
14.1. UN number
UN number 1950
14.2. UN proper shipping name
Proper shipping name Aerosols
14.3. Transport hazard class(es)
Hazard identification number
Class 2
Classification code 5F
14.4. Packing group
Packing group
Labels 2.1
14.5. Environmental hazards
Environmentally hazardous substance mark no
14.6. Special precautions for user
Special provisions 190
Reason for revision: 15.1 Publication date: 2002-03-23
Date of revision: 2016-08-08
Revision number: 0501 Product number: 51803 13 / 17
SOUDAFOAM WINDOW & DOOR GUN GRADE
Special provisions 327
Special provisions 344
Special provisions 625
Limited quantities Combination packagings: not more than 1 liter per inner packaging for
liquids. A package shall not weigh more than 30 kg. (gross mass)
Rail (RID)
14.1. UN number
UN number 1950
14.2. UN proper shipping name
Proper shipping name Aerosols
14.3. Transport hazard class(es)
Hazard identification number 23
Class 2
Classification code 5F
14.4. Packing group
Packing group
Labels 2.1
14.5. Environmental hazards
Environmentally hazardous substance mark no
14.6. Special precautions for user
Special provisions 190
Special provisions 327
Special provisions 344
Special provisions 625
Limited quantities Combination packagings: not more than 1 liter per inner packaging for
liquids. A package shall not weigh more than 30 kg. (gross mass)
Inland waterways (ADN)
14.1. UN number
UN number 1950
14.2. UN proper shipping name
Proper shipping name Aerosols
14.3. Transport hazard class(es)
Class 2
Classification code 5F
14.4. Packing group
Packing group
Labels 2.1
14.5. Environmental hazards
Environmentally hazardous substance mark no
14.6. Special precautions for user
Special provisions 190
Special provisions 327
Special provisions 344
Special provisions 625
Limited quantities Combination packagings: not more than 1 liter per inner packaging for
liquids. A package shall not weigh more than 30 kg. (gross mass)
Sea (IMDG/IMSBC)
14.1. UN number
UN number 1950
14.2. UN proper shipping name
Proper shipping name Aerosols
14.3. Transport hazard class(es)
Class 2.1
14.4. Packing group
Packing group
Labels 2.1
14.5. Environmental hazards
Marine pollutant -
Environmentally hazardous substance mark no
14.6. Special precautions for user
Reason for revision: 15.1 Publication date: 2002-03-23
Date of revision: 2016-08-08
Revision number: 0501 Product number: 51803 14 / 17
SOUDAFOAM WINDOW & DOOR GUN GRADE
Special provisions 63
Special provisions 190
Special provisions 277
Special provisions 327
Special provisions 344
Special provisions 959
Limited quantities Combination packagings: not more than 1 liter per inner packaging for
liquids. A package shall not weigh more than 30 kg. (gross mass)
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Annex II of MARPOL 73/78 Not applicable
Air (ICAO-TI/IATA-DGR)
14.1. UN number
UN number 1950
14.2. UN proper shipping name
Proper shipping name Aerosols, flammable
14.3. Transport hazard class(es)
Class 2.1
14.4. Packing group
Packing group
Labels 2.1
14.5. Environmental hazards
Environmentally hazardous substance mark no
14.6. Special precautions for user
Special provisions A145
Special provisions A167
Special provisions A802
limited quantities: maximum net quantity per packaging 30 kg G
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
European legislation:
VOC content Directive 2010/75/EU
VOC content Remark
< 24 %
< 228 g/l
REACH Annex XVII - Restriction
Contains component(s) subject to restrictions of Annex XVII of Regulation (EC) No 1907/2006: restrictions on the manufacture, placing on the market and
use of certain dangerous substances, mixtures and articles.
Designation of the substance, of the group of
substances or of the mixture
Conditions of restriction
• polymethylene polyphenyl isocyanate
• alkanes, C14-17, chloro
• reaction mass of tris(2-chloropropyl)
phosphate and tris(2-chloro-1-methylethyl)
phosphate and phosphoric acid, bis(2-chloro-
1-methylethyl) 2-chloropropyl ester and
phosphoric acid, 2-chloro-1-methylethyl
bis(2-chloropropyl) ester

Liquid substances or mixtures which are
regarded as dangerous in accordance with
Directive 1999/45/EC or are fulfilling the criteria
for any of the following hazard classes or
categories set out in Annex I to Regulation (EC)
No 1272/2008:
(a) hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8
types A and B, 2.9, 2.10, 2.12, 2.13 categories 1
and 2, 2.14 categories 1 and 2, 2.15 types A to
F;
(b) hazard classes 3.1 to 3.6, 3.7 adverse effects
on sexual function and fertility or on
development, 3.8 effects other than narcotic
effects, 3.9 and 3.10;
(c) hazard class 4.1;
(d) hazard class 5.1.
1. Shall not be used in:
ornamental articles intended to produce light or colour effects by means of different
phases, for example in ornamental lamps and ashtrays,
tricks and jokes,
games for one or more participants, or any arti cle intended to be used as such, even with
ornamental aspects,2. Articles not complying with paragraph 1 shall not be placed on the
market.3. Shall not be placed on the market if they contain a colouring agent, unless required
for fiscal reasons, or perfume, or both, if they:
can be used as fuel in decorative oil lamps for supply to the general public, and,
present an aspiration hazard and are labelled with R65 or H304,4. Decorative oil lamps for
supply to the general public shall not be placed on the market unless they conform to the
European Standard on Decorative oil lamps (EN 14059) adopted by the European Committee
for Standardisation (CEN).5. Without prejudice to the implementation of other Community
provisions relating to the classification, packaging and labelling of dangerous substances and
mixtures, suppliers shall ensure, before the placing on the market, that the following
requirements are met:
a) lamp oils, labelled with R65 or H304, intended for supply to the general public are visibly,
legibly and indelibly marked as follows: Keep lamps filled with this liquid out of the reach of
children; and, by 1 December 2010, Just a sip of lamp oil or even sucking the wick of
lamps may lead to life- threatening lung damage;
b) grill lighter fluids, labelled with R65 or H304, intended for supply to the general public are
legibly and indelibly marked by 1 December 2010 as follows: Just a sip of grill lighter may
lead to life threatening lung damage;
c) lamp oils and grill lighters, labelled with R65 or H304, intended for supply to the general
public are packaged in black opaque containers not exceeding 1 litre by 1 December 2010.6.
No later than 1 June 2014, the Commission shall request the European Chemicals Agency to
prepare a dossier, in accordance with Article 69 of the present Regulation with a view to ban,
Reason for revision: 15.1 Publication date: 2002-03-23
Date of revision: 2016-08-08
Revision number: 0501 Product number: 51803 15 / 17
SOUDAFOAM WINDOW & DOOR GUN GRADE
if appropriate, grill lighter fluids and fuel for decorative lamps, labelled R65 or H304, intended
for supply to the general public.7. Natural or legal persons placing on the market for the first
time lamp oils and grill lighter fluids, labelled with R65 or H304, shall by 1 December 2011,
and annually thereafter, provide data on alternatives to lamp oils and grill lighter fluids
labelled R65 or H304 to the competent authority in the Member State concerned. Member
States shall make those data available to the Commission.
National legislation Belgium
SOUDAFOAM WINDOW & DOOR GUN GRADE
No data available
National legislation The Netherlands
SOUDAFOAM WINDOW & DOOR GUN GRADE
Waste identification (the
Netherlands)
LWCA (the Netherlands): KGA category 06
Waterbezwaarlijkheid A (2)
National legislation France
SOUDAFOAM WINDOW & DOOR GUN GRADE
No data available
National legislation Germany
SOUDAFOAM WINDOW & DOOR GUN GRADE
WGK 2; Classification water polluting based on the components in compliance with Verwaltungsvorschrift wassergefhrdender
Stoffe (VwVwS) of 27 July 2005 (Anhang 4)
polymethylene polyphenyl isocyanate
TRGS905 - Krebserzeugend 2
TRGS905 - Erbgutverndernd -
TRGS905 -
Fruchtbarkeitsgefhrdend
-
TRGS905 - Fruchtschdigend -
TA-Luft 5.2.5; I
TRGS900 - Risiko der
Fruchtschdigung
pMDI (als MDI berechnet); Y; Risiko der Fruchtschdigung braucht bei Einhaltung des Arbeitsplatzgrenzwertes und des
biologischen Grenzwertes nicht befrchtet zu werden
Sensibilisierende Stoffe pMDI (als MDI berechnet); Sa; Atemwegssensibilisierende Stoffe
Hautresorptive Stoffe pMDI (als MDI berechnet); H; Hautresorptiv
alkanes, C14-17, chloro
TA-Luft 5.2.5; I
TRGS900 - Risiko der
Fruchtschdigung
Chloralkane, C14-17 (Chlorierte Paraffine C14-17 ); Y; Risiko der Fruchtschdigung braucht bei Einhaltung des
Arbeitsplatzgrenzwertes und des biologischen Grenzwertes nicht befrchtet zu werden
Hautresorptive Stoffe Chloralkane, C14-17 (Chlorierte Paraffine C14-17 ); H; Hautresorptiv
reaction mass of tris(2-chloropropyl) phosphate and tris(2-chloro-1-methylethyl) phosphate and phosphoric acid, bis(2-chloro-1-methylethyl) 2-chloropropyl
ester and phosphoric acid, 2-chloro-1-methylethyl bis(2-chloropropyl) ester
TA-Luft 5.2.5
National legislation United Kingdom
SOUDAFOAM WINDOW & DOOR GUN GRADE
No data available
polymethylene polyphenyl isocyanate
Skin Sensitisation Isocyanates, all (as -NCO) Except methyl isocyanate; Sen
Respiratory sensitisation Isocyanates, all (as -NCO) Except methyl isocyanate; Sen
Other relevant data
SOUDAFOAM WINDOW & DOOR GUN GRADE
No data available
polymethylene polyphenyl isocyanate
IARC - classification 3; Polymethylene polyphenyl isocyanate
alkanes, C14-17, chloro
IARC - classification 2B; Chlorinated paraffins
15.2. Chemical safety assessment
No chemical safety assessment has been conducted for the mixture.
SECTION 16: Other information
Full text of any H-statements referred to under headings 2 and 3:
H220 Extremely flammable gas.
H222 Extremely flammable aerosol.

Reason for revision: 15.1 Publication date: 2002-03-23
Date of revision: 2016-08-08
Revision number: 0501 Product number: 51803 16 / 17
SOUDAFOAM WINDOW & DOOR GUN GRADE
H229 Pressurised container: May burst if heated.
H280 Contains gas under pressure; may explode if heated.
H302 Harmful if swallowed.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.
H362 May cause harm to breast-fed children.
H373 May cause damage to organs through prolonged or repeated exposure if inhaled.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H413 May cause long lasting harmful effects to aquatic life.

(*) INTERNAL CLASSIFICATION BY BIG
PBT-substances persistent, bioaccumulative and toxic substances
CLP (EU-GHS) Classification, labelling and packaging (Globally Harmonised System in Europe)
Specific concentration limits CLP
polymethylene polyphenyl isocyanate C ≥ 5 % Eye Irrit 2;H319 analogous to Annex VI
C ≥ 5 % Skin Irrit 2;H315 analogous to Annex VI
C ≥ 0.1 % Resp Sens 1;H334 analogous to Annex VI
C ≥ 5 % STOT SE 3;H335 analogous to Annex VI
alkanes, C14-17, chloro 1,0 % ≤ C ≤ 20 % EUH066 FEICA Position Paper
on the classification
and labelling of One
Component Foam
(OCF) containing Mid
Chained Chlorinated
Paraffin (MCCP) March
7th 2014)
1,0 % ≤ C ≤ 20 % Lact. ; H362 FEICA Position Paper
on the classification
and labelling of One
Component Foam
(OCF) containing Mid
Chained Chlorinated
Paraffin (MCCP) March
7th 2014)
0,25 % ≤ C ≤ 20 % Aquatic Chron. 4;H413 FEICA Position Paper
on the classification
and labelling of One
Component Foam
(OCF) containing Mid
Chained Chlorinated
Paraffin (MCCP) March
7th 2014)

The information in this safety data sheet is based on data and samples provided to BIG. The sheet was written to the best of our ability and according to the
state of knowledge at that time. The safety data sheet only constitutes a guideline for the safe handling, use, consumption, storage, transport and disposal of
the substances/preparations/mixtures mentioned under point 1. New safety data sheets are written from time to time. Only the most recent versions may be
used. Old versions must be destroyed. Unless indicated otherwise word for word on the safety data sheet, the information does not apply to
substances/preparations/mixtures in purer form, mixed with other substances or in processes. The safety data sheet offers no quality specification for the
substances/preparations/mixtures in question. Compliance with the instructions in this safety data sheet does not release the user from the obligation to take
all measures dictated by common sense, regulations and recommendations or which are necessary and/or useful based on the real applicable circumstances.
BIG does not guarantee the accuracy or exhaustiveness of the information provided and cannot be held liable for any changes by third parties. This safety data
sheet is only to be used within the European Union, Switzerland, Iceland, Norway and Liechtenstein. Any use outside of this area is at your own risk. Use of this
safety data sheet is subject to the licence and liability limiting conditions as stated in your BIG licence agreement or when this is failing the general conditions
of BIG. All intellectual property rights to this sheet are the property of BIG and its distribution and reproduction are limited. Consult the mentioned
agreement/conditions for details.

Reason for revision: 15.1 Publication date: 2002-03-23
Date of revision: 2016-08-08
Revision number: 0501 Product number: 51803 17 / 17

VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina April 24, 2019

D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Unit 11 3-28-19\Appendix IX- VMS Alarm.rtf

APPENDIX IX
VMS ALARM

VMS Installation, Testing & Sampling Report SUMMIT Project No. 1820.59 Charlotte, North Carolina April 24, 2019

D:\Project Forms\Projects\1820 Saussy Burbank\1820.59 Highland Mill EMP\OS Unit 11 3-28-19\Appendix X- DRAGO.rtf

APPENDIX X
DREGO SEAL EPOXY

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DRAGO® SEALANT
A STEGO TECHNOLOGY, LLC INNOVATION | VAPOR RETARDERS 07 26 00, 03 30 00 | VERSION: 06/23/2017
1. PRODUCT NAME
DRAGO SEALANT
2. MANUFACTURER
c/o Stego® Industries, LLC*
216 Avenida Fabricante, Suite 101
San Clemente, CA 92672
Sales, Technical Assistance
Ph: [phone]
Fx: [phone]
www.stegoindustries.com
3. PRODUCT DESCRIPTION
USES: Drago Sealant is designed to be used as a vapor intrusion membrane in conjunction with Drago® Wrap Vapor
Intrusion Barrier. Drago Sealant can be used as an alternate to detail patches for penetrations in Drago Wrap.
COMPOSITION: Drago Sealant is a two-component, high performance modified cycloaliphatic epoxy sealant.
SIZE: Drago Sealant comes in a 1.8-gallon kit size: Part A (Resin) and Part B (Hardener).
4. TECHNICAL DATA
TABLE 4.1: PHYSICAL PROPERTIES OF DRAGO SEALANT
PROPERTY TEST RESULTS
Elongation ASTM D412 550-600%
Tensile Strength ASTM D412 2,000 +/- 100 psi
Compressive Strength ASTM C695 8,800 psi
Hardness, Shore D ASTM D2240 52
Flexural Strength ASTM D790 4,700 psi
Bond to Concrete ASTM D4541 350 psi
Water Vapor Permeance ASTM E96 0.027 perms @ 20-mils
Taber Abrasion ASTM D4060 75-80 Mgs
Chemical Resistance ASTM D471/D543 No significant change (TCE, PCE, Toluene, Xylene) to mass or volume.
Continued... Note – legal notice on page 2.
5. INSTALLATION
PREPARATION:
• A test application simulating the project environment should always be done prior to final usage of Drago Sealant.
• All surfaces should be dry and free of loose materials, oils, and other contaminants. The surfaces should be cleaned
in the same fashion as the test surface in order to ensure proper application.
• Drago Sealant can be applied to virtually any shape or contour by brush, paint roller, trowel or squeegee at various
spread rates. Optimum ambient temperature is between 40-90°F during application. Note: Cure times are affected
by ambient and surface temperatures. Temperatures of 40°F and lower can slow cure times. Temperatures of 85°F
and higher will speed up cured times and reduce working time.
DRAGO® SEALANT
A STEGO TECHNOLOGY, LLC INNOVATION | VAPOR RETARDERS 07 26 00, 03 30 00 | VERSION: 06/23/2017
DATA SHEETS ARE SUBJECT TO CHANGE. FOR MOST CURRENT VERSION, VISIT WWW.STEGOINDUSTRIES.COM
[phone] | www.stegoindustries.com
* Stego Industries, LLC is the exclusive Representative for all products, including Drago® Wrap and accessory products, owned by Stego Technology, LLC, a wholly independent company from Stego Industries, LLC. Drago, the Drago logo, and DragoTack are deemed to be registered and/or protectable trademarks of Stego Technology, LLC. Stego and the stegosaurus logo, are deemed to be registered and/or protectable trademarks of Stego Industries, LLC. © 2017 Stego Industries, LLC. All Rights Reserved. Installation and Warranty Information: www.stegoindustries.com/legal.
PREPARATION: Continued...
• Drago Sealant comes in a 1.8-gallon kit size. It consists of Part A (Resin) and Part B (Hardener). Mix the following
with a drill and mixing paddle (Note: If using a drill mixer, use a low speed [not to exceed 300 rpm] to prevent air
entrapment):
- Pour Part B into Part A (2-gallon bucket) and mix well for 2 minutes.
- Drago Sealant is designed to be immediately poured. Leaving mixed product in the container will greatly
reduce pot life. Once poured out on the membrane, 15 minutes of working time can generally be expected.
PENETRATIONS:
• To repair penetrations in Drago Wrap, cut a hole in Drago Wrap such that the membrane fits over and around the
base of the pipes as closely as possible, ensuring that it is flush with the base of the penetrations.
• Install Drago® Sealant Form continuously around the entire perimeter of the group of penetrations and at least
1 inch beyond the terminating edge of Drago Wrap.
• Pour Drago Sealant inside of Drago Sealant Form to create a seal around the penetrations.
• If the void space between Drago Wrap and the penetrations is not minimized and/or the base course allows for too
much drainage of the sealant, a second coat of Drago Sealant may need to be poured after the first application
has cured.
Review Drago Wrap’s complete installation instructions prior to installation.
6. AVAILABILITY & COST
Drago Sealant is available nationally through our network of building supply distributors. For current cost information,
contact your local Drago distributor or Stego Industries’ Sales Representative.
7. WARRANTY
Stego Industries, LLC believes to the best of its knowledge, that specifications and recommendations herein are
accurate and reliable. However, since site conditions are not within its control, Stego Industries does not guarantee
results from the use of the information provided and disclaims all liability from any loss or damage. Stego Technology,
LLC does offer a limited warranty on Drago Wrap. Please see www.stegoindustries.com/legal.
8. MAINTENANCE
Store Drago Sealant in a dry and temperate area.
9. TECHNICAL SERVICES
Technical advice, custom CAD drawings, and additional information can be obtained by contacting Stego Industries or
by visiting the website.
Contact Number: [phone]
Website: www.stegoindustries.com
10. FILING SYSTEMS
• www.stegoindustries.com
• Buildsite
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