13019_Planters Oil Mill_SSQAPP_20111118

City of Rocky Mount, North Carolina
Cleanup Grant BF — 95414908-0
Awe
Hart &Hickman
2923 South Tryon Street
Suite 100
Charlotte, NC 28203
704-586-0007
3334 Hillsborough Road
Raleigh, NC 27607
919-847-4241
#C-1269 Engineering
#C-245 Geology
Site -Specific QAPP Addendum
Former Planter's Oil Mill Site
1004 Cokey Road
Rocky Mount, North Carolina
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Prepared by:
Hart & Hickman, PC
Project No. CRM-008
Prepared for:
City of Rocky Mount NC
November 18, 2010

City of Rockv Hount NC SitevlrecifieQAPP Addendum
nF-954I496 Formerplanter's Oil Mill Site
Al. Title and Approval Sheet
City of Rocky Mount North Carolina
Site -Specific QAPP Addendum
Former Planter's Oil Mill Site
City of Rocky Mount NC Program Administrator/Program Manager
Peter Varney, Assistant City Manager Date
Revision 0
November 18, 2010
Pagel
This Site -Specific QAPP Addendum was prepared by Hart & Hiclunan, PC on behalf of
the City of Rocky ]Vlount, North Carolina
Hart & Hickman, PC
3334.Hillsborongh Road
Raleigh, NC 27607
919-847-4241
Hart & Hickman, Project Manage
C, ✓li oAF_IV
Leonard ivloretz, PG Project Manager
Hart & Hickman, QA Manager
/Z,,
Matt Bramblett, PE QA Manager
Date
�i•f�-mod
Date
Hart 8 Ifickman, PC

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Page 2
U.S. Environmental Protection Agency Approvals:
Margaret Olson - US EPA, Region 4 — Project Officer
US EPA, Region 4 - Designated Approving Official
Date
Date
This Site -Specific QAPP Addendum has been prepared in accordance with EPA Region 4's
Brownfields Program. This document is valid for the subject project and it is meant to be used in
conjunction with the City of Rocky Mount, North Carolina Generic QAPP — November 15, 2010
previously approved by EPA Region 4 for the City of Rocky Mount, NC Grant BF 95414908.
The work described herein will be performed in accordance with the processes described in the
Generic QAPP.
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City of Rocky Mount North Carolina
Site -Specific QAPP Addendum
Former Planter's Oil Mill Site
A2. Table of Contents
Al.
Title and Approval Sheet.......................................................................................................1
A2.
Table of Contents...................................................................................................................3
A3.
Distribution List.....................................................................................................................5
A4.
Project Organization..............................................................................................................6
A5.
Background/Problem Definition...........................................................................................7
A6.
Project Description/Timeline..............................................................................................14
A7.
Special Training Requirements and Special Certifications
.............................................18
A8.
Documentation and Records...............................................................................................19
B1.
Sampling Process Design.....................................................................................................20
B2.
Sampling & Analytical Method Requirements.................................................................24
B3.
Sampling Handling and Custody Requirements...............................................................26
B4.
Analytical Methods and Requirements..............................................................................27
B5.
Field Quality Control Requirements..................................................................................28
B6.
Laboratory Quality Control Requirements.......................................................................29
B7.
Field Equipment & Corrective Action...............................................................................30
B8.
Lab Equipment & Corrective Action.................................................................................32
B9.
Analytical Sensitivity & Project Criteria...........................................................................33
B10.
Data Management and Documents...................................................................................34
Cl.
Assessment and Response Actions......................................................................................35
C2.
Project Reports.....................................................................................................................36
D1.
Field Data Evaluation..........................................................................................................37
D2.
Laboratory Data Evaluation...............................................................................................38
D3.
Data Usability and Project Evaluation..............................................................................39
El.
References.............................................................................................................................40
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Page 4
Tables
Table 1 Proposed Sample Summary Table
Table 2 Sampling and Analytical Methods Requirements Table
Table 3 Laboratory Analytical Quality Control — Prism Laboratories
Table 4 Analytical Sensitivity and Project Criteria — Prism Laboratories
Figure 1
Figure 2
Figures
Site Location Map
Sampling Location Map
Where specified below, the following Appendices of this Site -Specific QAPP Addendum are
provided in electronic format on a CD that is included in an insert within the bound document.
Appendices
Appendix A Hart & Hickman PC - Site -Specific Health & Safety Plan
(Health & Safety Plan is provided in the enclosed CD)
Hart & Hickman PC - Standard Operating Procedures (SOPs)
(SOPs are provided on the enclosed CD)
Appendix B Prism Laboratories, Inc. - QA Manual (Laboratory manual is
provided on the enclosed CD)
Hart & Hickman, PC

City of Rocky Mount NC Site -Specific QAPP Addendum
BF-95414908 Former Planter's Oil Mill Site
A3. Distribution List
City of Rocky Mount North Carolina
Site -Specific QAPP Addendum
Former Planter's Oil Mill Site
Ms. Margaret Olson
EPA Region 4 Project Officer
RCRA Management Division
Restoration and UST Branch
61 Forsyth Street, SW
Atlanta, GA 30303
404-562-8601
olson.mar ag retkepa.gov
Mr. Peter Varney
Assistant City Manager
City of Rocky Mount
P.O. Box 1180
Rocky Mount, NC 27802
[phone]
peter.vameykrockymountnc. gov
Mr. Leonard Moretz, PG
Project Manager
Hart & Hickman, PC
3334 Hillsborough Street
Raleigh, NC 27607
919-847-4241
lmoretzgharthickman.com
Mr. Matt Bramblett, PE
QA Manager
Hart & Hickman, PC
2923 South Tryon Street
Suite 100
Charlotte, NC 28203
704-586-0007
mbramblett(iDharthickman. com
Revision 0
November 18, 2010
Page 5
All personnel will receive and will follow applicable sections of this Site -Specific QAPP
Addendum and subsequent revisions.
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A4. Project Organization
Project organization for the City's Brownfields Program has been defined in the Generic QAPP.
Modifications and additions to this project organization for this Site -Specific QAPP Addendum
are included in the Project Organization Chart below.
Project Organization Chart
EPA Region 4 Brownfields City of Rocky Mount State
Project Officer Program Administrator / Brownfields Program
Ms. Margaret Olson Project Manager Ms. Sharon Eckerd
[phone] Mr. Peter Varney [phone]
[phone]
EPA Region 4 Quality
Assurance Manager's
Designated Approving
Official I
The QA Manager has
independent authority and
Hart & Hickman
is separate from those who
Leonard Moretz, PG
generate the data
Project Manager
[phone]
Hart & Hickman
Matt Bramblett, PE
QA Manager
-----------
[phone]
Hart & Hickman
Hart & Hickman
Ed Stephens, PG
Senior Project Geologist
QA Manager's
Designated
Hart & Hickman
Tim Klotz
[phone]
Reviewer
Field Team Leader
Prism Laboratories, Inc. Drilling Contractor
Ms. Robbie Jones Quantex, Inc
President [phone]
[phone] ext. 119
Prism Laboratories, Inc.
Mr. Helmuth Janssen
QA Officer
[phone] ext. 104
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A5. Background/Problem Definition
Background
Site Description
The site is comprised of a 7.3-acre parcel located at 1004 Cokey Road in Rocky Mount,
Edgecombe County, North Carolina. The geographic coordinates of the center of the site are 35'
55' 44" North and 77' 47' 26" West. The subject parcel is bounded to the north by Short Street
(formerly Henna Street), to the east by Cokey Road (SR-1164), to the south by the CSX Railroad
right-of-way and Norfolk Street, and to the west by Branch Street. The site is currently an
unoccupied grass -covered field surrounded by a 6-ft high chain link fence.
Current Property Owner
H&H reviewed the tax records for the subject property on the City of Rocky Mount website
(hqp://www.rock ig_s/gisportal.html) and at the Edgecombe County Register of
Deeds website(htip://www.edgecombecountync.gov/). According to available tax records, the
Parcel Identification Number for the property is 375985022100. The property was previously
owned by Hervey E. Evans, Jr. The City of Rocky Mount acquired the site in September 2007.
Former and Current PropeLty Use
The property was formerly used for the manufacture of cottonseed and soybean oil primarily in
the eastern portion of the site. The site was also used for fertilizer manufacturing operations by
Kaiser Agricultural Chemical in the western portion of the property beginning in the 1970s until
1983, although; early site operations included fertilizer production in the eastern portion of the
site. All site operations ceased in 1983 due to a major fire that resulted in the total loss of
several on -site buildings. The fire is believed to have resulted in a release of a significant
volume of hexane (used to extract oil from the cottonseed) to the subsurface in the oil processing
area (southeastern area).
The former on -site structures described in the Phase I ESA report have all been razed. The
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structures were demolished under the direction of the City of Rocky Mount. The site is currently
unoccupied, and it is a grass -covered field surrounded by a 6-ft high chain link security fence.
Several gates and openings are found along the periphery of the fence. Site entry is along the
western side of the property along Branch Street and on the eastern side of the property along
Cokey Road.
Proposed Future Reuse/Redevelopment Plans for the Property
The proposed future reuse of the property is commercial/industrial use.
Adjacent Prope . Uses
The area in the vicinity of the subject site contains commercial, residential, and institutional land
uses. The institutional uses are two churches. The subject site is bordered as follows:
• North — Short Street (formerly Henna Street) with residential and commercial properties
beyond
• Northeast — Former Carolina Telephone building (now owned by Prophetic Power of
Praise Worldwide Ministries) with the intersection of Short Street and Cokey Road
beyond
• East — Cokey Road with residences, commercial business and a church beyond
• South — CSX Railroad right-of-way with outbuildings, metal commercial building
(Wilfab Metal) and Norfolk Street beyond
• West — Branch Street with residential properties beyond.
Known or Likely Chemicals/Contaminants of Concern
A Phase II ESA Report for the subject site was prepared by T N & Associates, Inc. (TN&A) in
May 2009. The Phase II ESA was completed as part of a Targeted Brownfields Assessment
(TBA) conducted on behalf of the U.S. Environmental Protection Agency Region 4 (USEPA) —
Region 4 Brownfields Program to assist the City of Rocky Mount with further assessing the
redevelopment potential and cleanup options for the property. The Phase II ESA focused on
assessing surface soil, subsurface soil, and/or groundwater contamination at selected locations on
the site property. Soil and groundwater samples were collected for VOC, SVOC, TAL metals,
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TPH-DRO, TPH-GRO, organochlorine pesticides (OCP), organophosphate pesticides (OPP),
and PCB analyses. The report conclusions are presented below.
• Evidence of arsenic contamination was found primarily in surface soil samples; but,
extended into the subsurface soil and groundwater samples
• Evidence of lead contamination was found in two groundwater samples at concentrations
exceeding the MCL and NCAC 2L Standard
• Evidence of TPH-DRO contamination was found primarily in surface soil samples; but,
was also detected in subsurface soil and groundwater samples. TPH-GRO contamination
was also identified in a groundwater sample
• Evidence of contamination of two OCPs (dieldrin and toxaphene) was found in surface
soil samples.
• Evidence of VOC contamination was found in groundwater samples
• Evidence of SVOC contamination primarily from PAHs was found in surface soil,
subsurface soil, and groundwater samples.
• No evidence of PCB contamination was found in the surface soils samples in which it
was analyzed.
Known or Suspected Contaminant Sources/Magnitude of Contamination
Known or suspected on -site contaminant sources include:
• A release of hexane to shallow soil and potentially to shallow ground water in the area
under the former hull house, solvent extraction tower, and hexane UST.
• The potential release of petroleum compounds from six on -site petroleum USTs to
shallow soil and ground water at the site.
• The manufacture and potential release of fertilizer compounds, which can contain
elevated metals, to the shallow soil.
• The on -site use of parathion and potentially other organophosphate or organochlorine
pesticides and its potential impact on site soil.
• Certain site structures were found to contain asbestos containing material.
• Several sumps
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• The potential for on -site coal storage and/or coal ash disposal
A site map depicting known and suspected on -site contaminant sources is provided in Figure 2.
Known or suspected off -site contaminant sources with a potential to impact the subject site
include three gasoline USTs closed in place in 1990 at the former gasoline service station located
at 806 Cokey Road (Turnage Property). This property is located approximately 400 feet north
(potentially up gradient) of the site. This site is identified as a State Leaking Underground
Storage Tank (LUST) site with soil contamination stemming from TPH as gasoline up to 3,500
mg/kg. Ground water was not sampled and analyzed as part of the tank closure.
Conceptual Site Model (CSM
Environmental Setting
Relatively mild winters, hot summers, and abundant rainfall characterize the Rocky Mount area.
The average yearly temperature in Rocky Mount is 60 'F. The average annual precipitation is
approximately 47 inches.
Regional Geology and Hydrogeology
The site is located in the Coastal Plain Physiographic Province of North Carolina. Sedimentary
rocks of the Coastal Plain consist of sediment eroded from the Piedmont over the last 100
million years and limestone generated by marine organisms and processes at sea. Sediments
overlying bedrock in the subject site vicinity are typically composed of sands, silts, and clays
that were fluvially deposited. Rocks underlying the site belong to the Yorktown and Dublin
Formations of the Coastal Plain Physiographic Province. In the vicinity of the site, the
Yorktown Formation is typically comprised of fossiliferous sand with silt and clay. The
underlying Dublin Formation is comprised of medium- to coarse -grained sand and limestone.
The hydrogeology of the Coastal Plan is characterized by aquifers consisting of permeable sands,
silts, or limestone, which are confined and separated by units of clay and silts or low
permeability limestone.
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Former Site Operations
The site was developed prior to 1907 and was operated through 1983 as the Planter's Cotton Oil
& Fertilizer Company or Planter's Oil Mill, Inc. The mill produced cottonseed oil and later,
soybean oil and fertilizer. Oil was extracted from cottonseed and soybeans until approximately
1959 or 1960 when the owners switched to a solvent extraction process using hexane.
Cottonseed and soybean oil were manufactured in the eastern portion of the property. Fertilizer
manufacturing operations were conducted by Kaiser Agricultural Chemical primarily in the
western portion of the property beginning in the 1970s until 1983. All site operations ceased in
1983 after a major fire resulted in the total loss of several on -site buildings. The fire is believed
to have resulted in a release of a significant volume of hexane to the subsurface in the
southeastern oil processing area.
Regulatory History
North Carolina Department of Environment and Natural Resources (NCDENR) regulatory files
include correspondence between the site owner (dated March 6, 1991) and North Carolina
Department of Environmental Management (NCDEM). The correspondence indicates that six
underground storage tanks (USTs) were registered at the site in 1991 and were intended to be
removed from the site in June 1991. However, there is no documentation to confirm that the
USTs were removed. The six tanks are listed as one 10,000-gallon fuel oil UST, two 1,000-
gallon (empty) diesel USTs, two 1,000-gallon kerosene USTs ranging from an estimated 200
gallons to 400 gallons residual fluid, and a 10,000-gallon (empty) hexane tank. The tanks were
estimated to have been last used in 1983. No other regulatory information is available in the file
material.
Problem Definition
The objective of this Brownfields data collection effort is to gather additional assessment data to
fill existing data gaps to allow the evaluation and recommendation of an appropriate site cleanup
approach in support of the City's Brownfields Cleanup Grant.
Additional remedial design data will be collected to evaluate whether potential on -site and/or
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identified off -site impacts pose a potential environmental risk for future redevelopment of the
site and to evaluate the need for corrective action. Soil sample analytical data will be compared
with screening criteria established in the DENR Inactive Hazardous Sites Branch (IHSB) Soil
Remediation Goals (SRGs) Table (updated January 2010) and the USEPA Regional Screening
Levels for Chemical Contaminants at Superfund Sites (updated May 2010), whichever is more
stringent. Ground water sample analytical data will be compared with to the Title 15A NCAC
2L ground water quality standards. Naturally occurring metals in site samples will be compared
to background sample concentrations, literature values, and/or allowable concentrations as
determined by the NCDENR Brownfields Program.
If on -site USTs or potential on -site UST releases are suspected, a secondary objective will be to
acquire additional assessment data to determine whether regulatory closure from the NCDENR
UST Section may be required. Soil and ground water data will be compared with the respective
screening levels established by the UST Section to evaluate the need for UST corrective action.
Applicable screening criteria are established in DENR's Guidelines for Site Checks, Tank
Closure and Initial Response and Abatement for UST Releases (rev. 11/26/2008) and Guidelines
for Assessment and Corrective Action for UST Releases (rev. 11/26/2008); Maximum Soil
Contaminant Concentration (MSCC) Table (1/2010); and Gross Contamination Level (GCL)
Table (1/2010).
Qualitatively, the results will be compared to the above applicable screening levels to determine
if remedial activities are warranted to protect future site occupants. Because there are no known
groundwater users in the immediate vicinity of the site, the potential for potable use exposure
pathways are incomplete. Because the future land use may include occupied site buildings,
indoor air vapor intrusion will be anticipated as a potential exposure pathway. Therefore, a
vapor intrusion screening approach will be used in accordance with EPA OSWER Draft
Guidance for Evaluating the Vapor Intrusion to Indoor Air Pathway from Groundwater and
Soils (Subsurface Vapor Intrusion Guidance) (11/2002).
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Risk Assessment of Potential Exposure Pathways
The site conceptual model and potential exposure pathways, as they relate to the subject site, are
summarized as follows:
• Impacted soils may potentially pose a direct exposure or ingestion risk to construction
workers or future site occupants.
• Impacted soils may potentially pose an exposure risk to construction workers or future
site occupants by way of inhalation of dust or inhalation of organic vapors (including
indoor air from vapor intrusion).
• Impacted shallow groundwater may potentially pose a risk to human and ecological
receptors if a route of exposure is identified.
• Impacted shallow groundwater may potentially pose a direct exposure risk to future
construction activities if groundwater is encountered in construction excavations.
• Impacted shallow ground water may potentially pose an exposure risk to future site
occupants by way of inhalation of organic vapors via indoor vapor intrusion.
Based upon the results of the site assessment, can the site be made safe for redevelopment?
Depending on the answer to this question, various subsequent actions/responses may be
appropriate. There are two alternative actions typically identified for an assessment:
1. If results indicate that a release has occurred from the site or an upgradient, off -site
parcel, and the release poses a potential threat to human health or the environment as a
result of redevelopment, conditions at the subject locations may require further
evaluation or engineering controls (ex. development restrictions, engineered barriers)
may need to be implemented.
2. If results indicate that there has not been a release that poses a potential threat to human
health or the environment, then no further evaluation will be necessary and it is unlikely
that the site poses a risk for future site redevelopment.
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A6. Project Description/Timeline
Project Work Tasks to be Performed
The elements of this remedial investigation data gathering were developed in coordination with
the NCDENR Brownfields Program Manager. The attached Figure 2 depicts the proposed
sampling locations, and Table 1 summarizes the selected sample analyses.
Work tasks to be performed at the subject site include the following:
1) The City will provide site utility clearance prior to drilling activities
2) The City will provide a backhoe and operator to complete test pits under the direction of
an H&H representative in an attempt to locate potential USTs at the site
3) Under H&H's oversight, the drilling subcontractor will install seven soil borings using
Direct Push Technology (DPT) to obtain soil cores for visual characterization and field
screening with a photo -ionization vapor detector (PID) leading to the selective collection
of field samples for laboratory analyses. These data will be used to evaluate the potential
on -site impacts from the following concerns:
• Truck scales area in northwest portion of site
• Former drum storage area
• Previous POM-2 sampling location (from TN&A Phase II ESA)
• No. 6 fuel oil UST area
• Hexane tank and solvent extraction area
• Arsenic in site -wide soils
4) H&H will advance seven surface soil borings by manual methods using a stainless steel
hand auger bucket. Soil will be examined for the presence of odor and staining, and
screened for organic vapors with a PID leading to the selective collection of field samples
for laboratory analyses. These data will be generally used to evaluate the potential on -
site impacts from arsenic and pesticides
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5) Under H&H's oversight, the drilling subcontractor will install five permanent ground
water monitoring wells using DPT methods in the areas listed in Task 3. The proposed
monitoring wells are planned to be located downgradient of suspected sources to the
extent that the local ground water gradient is known or inferred. H&H will collect
ground water samples from these wells for laboratory analyses
6) The City will provide a civil survey of soil boring and monitoring well locations and
elevations. H&H will conduct a round of water level measurements in on -site monitoring
wells and will generate a water table contour map depicting the general shallow ground
water flow direction and horizontal hydraulic gradient
7) Evaluate remedial design data and prepare an Analysis of Brownfields Cleanup
Alternatives (ABCA) Addendum or other deliverable as needed to meet NCDENR
requirements for a Brownfields Agreement
A detailed description of the proposed sampling and analysis plan to address the identified areas
of concern at the subject site is presented in Section B1.
Objectives of Project Tasks
Additional soil and ground water data are being collected at the site in an effort to support a
recommended cleanup approach. The results of the assessment activities will likely be used in
negotiating a Brownfields Agreement with DENR.
Media and Sampling Parameters/Off-Site Laboratory Testing
Media -specific samples to be collected and analyses to be performed are outlined in Table 1.
Select soil and ground water sample analytical parameters listed in Table 1 are required by the
DENR UST Section for regulatory closure of USTs.
Field Measurements and Field Analytical Testing
Field measurement will include the following:
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• depth -to -water measurements with an electronic water level probe
• instrument survey of soil boring and monitoring well locations and elevations
Field testing will include the following:
• field -screening of soil cores with an PID
• dissolved oxygen (DO) measurements with a DO meter
• pH, specific conductance, and temperature measurements with a multi -parameter probe
• turbidity measurements with a turbidity meter
A table detailing field equipment calibration QA information for the various types of field
equipment routinely used on Brownfields projects is provided in Section B7.
Critical/Non-Critical Data
The laboratory analytical data is judged to be critical data; whereas, field measurement and other
field methods are judged to be non -critical and will be used in a supporting role.
Project Screening Criteria
Sample analytical data will be compared to specific project screening criteria (i.e. regulatory
analyte or parameter standards/screening levels) as follows:
Non -UST Related Soil Data
DENR Inactive Hazardous Sites Branch (IHSB) Soil Remediation Goals (SRG) —January 2010
and/or USEPA Regional Screening Levels for Chemical Contaminants at Superfund Sites
(updated May 2010), whichever is more stringent.
UST -Related Soil and Ground Water Data
DENR UST Section — Guidelines for Site Checks, Tank Closure and Initial Response and
Abatement for UST Releases (rev. 11/26/2008) and Guidelines for Assessment and Corrective
Action for UST Releases (rev. 11/26/2008); MSCC Table (1/2010) and GCL Table (1/2010).
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Ground Water Data
Title 15A NCAC 2L Standards
Indoor Vapor Screening Evaluation
A vapor intrusion screening approach will be used in accordance with NCDENR Inactive
Hazardous Sites Branch Supplemental Guidelines for the Evaluation of Structural Vapor
Intrusion Potential for Site Assessments and Remedial Actions Under the Inactive Hazardous
Sites Branch (October 6, 2010).
Project Schedule
Once USEPA Region 4 Brownfields Program's approval of this QAPP is received, H&H will
begin scheduling contractors to conduct the data collection activities. Sampling activities are
expected to take up to one week to complete. Laboratory analytical results will be expected 14
working days from sample submittal. Once lab data are received, H&H estimates it will take
four weeks for preparation of an ABCA Addendum or other deliverable as needed to meet
NCDENR requirements for a Brownfields Agreement. Below is a tentative project schedule.
Activity
Anticipated
Anticipated
Deliverable
Anticipated
Initiation Date
Completion Date
Deliverable Date
Prepare Site -
Draft Electronic
Specific QAPP
Oct. 28 2010
Nov. 15 2010
file
Nov. 15' 2010
Addendum
Scheduling of
Nov. 22, 2010
Nov. 26, 2010
None
None
contractors
Field data
collection
Dec. 6, 2010
Dec. 10, 2010
None
None
Laboratory
Laboratory analysis
Dec. 13, 2010
Dec. 30, 2010
analytical data
Dec. 30, 2010
report
ABCA Add.
Dec. 13 2010
Feb. 1 2011
Final ABCA
Feb. 1 2011
preparation
Addendum
'
Update Property
Feb. 2 2011
Feb. 2 2011
Update ACRES
Feb. 2, 2011
Profile Form
Profile Form
* EPA Region 4 requests a 30-day QAPP review period; however, it is anticipated that an
expeditious turnaround is likely.
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A7. Special Training Requirements and Special Certifications
Information required by this section is provided in the Generic QAPP previously approved by
EPA Region 4. No special training requirements or special certifications that are not addressed
in the Generic QAPP are deemed necessary for this specific project.
A copy of H&H's Site -Specific Health & Safety Plan is included on the attached CD in
Appendix A.
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A8. Documentation and Records
Information required by this section is provided in the Generic QAPP previously approved by
EPA Region 4.
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B1. Sampling Process Design
This section provides a detailed description of the proposed sampling and analysis plan to
address the aforementioned areas of concern at the subject site. Based on TN&A's Phase II ESA
report, we expect groundwater will be encountered within 7 to 18 ft of the ground surface, and
the lithology will be silty sand to sandy clay. H&H proposes to advance soil borings for
collection of soil samples and will collect groundwater samples from permanent monitoring
wells through the use of direct push technology (DPT). This approach should be effective in the
anticipated subsurface conditions. The attached Figure 2 depicts the proposed sampling
locations, and Table 1 summarizes the selected sample analyses.
Utility Clearance
The City will provide utility clearance for the proposed drilling activities.
Taos %+c
The City will provide a backhoe and operator to complete test pits under the direction of H&H
field personnel in an attempt to locate potential USTs at the site.
Soil Data Collection
Under H&H's oversight, the drilling subcontractor will advance seven soil borings using direct
push technology (DPT) methods. At each DPT soil boring location, samples will be collected in
continuous 4- or 5-ft sample intervals with a MacroCore° sampler within acetate sleeves.
Following collection of the soil cores, soil will be examined for the presence of odor and
staining, and incremental samples of the soil cores will be screened for organic vapors with a
photo -ionization detector (PID). For all these borings, one shallow sample will be collected
from a depth of 0 to 2 ft for laboratory analysis of arsenic by EPA Method 6010B. Except as
described in the paragraph below, one subsurface sample will be collected from each boring
from an unspecified depth interval based upon field screening results, and the sample will be
analyzed for volatile organic compounds (VOCs) by EPA Method 8260B and polynuclear
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aromatic hydrocarbons (PAHs) by EPA Method 8270C.
For the soil boring targeting the No. 6 fuel oil UST assessment, a sampling strategy will be
employed as described in this paragraph. If it is determined that the tank has not been previously
removed from the ground, two soil samples will be collected and analyzed as described in the
paragraph above, except that a sample may also be collected and analyzed for total petroleum
hydrocarbons as diesel -range organics (TPH-DRO) by EPA Method 8015C, if deemed
appropriate. If it is determined that the tank has been removed from the ground and fuel oil -
impacted soil is identified during the advancement of test pits, H&H proposes to conduct soil
sampling in accordance with a Phase I Limited Site Assessment per the NCDENR UST Section
Guidelines for Assessment and Corrective Action (April 2001). For this scenario, soil samples
will be collected at each five-ft interval down to the local water table for the specified laboratory
analyses for the product stored in the UST. We understand that the UST was used to store No. 6
fuel oil. As specified above, one shallow sample will be collected from a depth of 0 to 2 ft for
analysis of arsenic by EPA Method 6010B. Subsurface soil samples collected at five-ft intervals
will be analyzed for semi-VOCs (SVOCs) by EPA 8270C plus the 10 largest tentatively
identified compounds (TICS) identified and for Massachusetts Department of Environmental
Protection (MADEP) Extractable Petroleum Hydrocarbons (EPH).
In addition, H&H proposes to advance seven surface soil borings by manual methods using a
stainless steel hand auger bucket. Soil will be examined for the presence of odor and staining,
and screened for organic vapors with a PID. A shallow sample will be collected from each
surface soil boring from a depth of 0 to 2 ft for laboratory analysis of arsenic by EPA Method
6010B. H&H will also collect a shallow soil sample within the footprint of the former
maintenance shop and analyze for VOCs, SVOCs, organochlorine pesticides,
organophosphorous pesticides in addition to arsenic.
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Page 22
Groundwater Data Collection
Five DPT soil borings will be subsequently converted into permanent monitoring wells used to
collect groundwater samples. Each proposed permanent monitoring well will be constructed of a
one -inch diameter PVC screen and riser with a sand filter added around the well screen. Based
on our knowledge of local conditions, we have assumed the wells will be completed to 20 ft
below grade. Each well will be completed with a 10-ft section of 0.01-inch slotted well screen
set to bracket the water table.
Following well installation, H&H will purge each monitoring well using a low -flow technique.
Field readings of pH, conductivity, temperature, and turbidity will be collected until the
parameters have stabilized and the well is relatively free of suspended sediment.
Except as noted otherwise, H&H will collect ground water samples from the purged wells for
laboratory analyses of VOCs by EPA Method 8260B and PAHs by EPA Method 8270C. If it is
determined that the No. 6 fuel oil UST has been previously removed from the ground and soil
impacts are identified, the ground water sample collected here will be analyzed for SVOCs by
EPA Method 625 plus the 10 TICs identified and for MADEP EPH.
Comprehensive Round of On -Site Monitoring Well Water Levels
H&H will gauge depth -to -ground water in on -site monitoring wells. Wells will be gauged using
an electronic water level meter. Depth -to -ground water will be measured relative to the top -of -
casing in each well. H&H will generate a water table contour map depicting the general shallow
ground water flow direction and horizontal hydraulic gradient.
Investigation Derived Waste
It is anticipated that soil cuttings and ground water generated during Phase II ESA activities will
be contained in 55-gallon drums on -site. It is anticipated that one drum of soil and one drum of
groundwater will be generated and require disposal at a properly licensed facility based upon
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City of Rocky Mount NC Site -Specific QAPP Addendum Revision 0
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Page 23
result of the sampling program. It is anticipated the soil and groundwater can be disposed of as
non -hazardous waste.
Survey
The City's survey crew will complete a survey of soil sampling locations and monitoring well
locations/elevation data and provide that information to H&H for use in development of future
reports.
Preparation of an ABCA Addendum or Other Deliverable Approved by NCDENR
The field sampling activities and collected data will be documented in an ABCA Addendum or
other deliverable as needed to meet NCDENR requirements for a Brownfields Agreement. This
document will include a description of field activities, a tabular summary of the results of soil
and ground water samples compared to potential regulatory target levels, figures depicting site
structures and sample locations, laboratory analytical report, and conclusions based upon our
pre -design data collection activities. The report will also provide a recommendation for the
cleanup approach and an estimated cost(s). A selected remedy will be developed based upon
commercial/industrial as the anticipated future site use.
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City of Rocky Mount NC Site -Specific QAPP Addendum Revision 0
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Page 24
B2. Sampling & Analytical Method Requirements
Sample Summary Table
A sample summary table is provided in Table 1 that clarifies and reflects the sampling process
design described in Section B I. In addition to the proposed number and type of field samples
and analyses, the number and type of QA samples and analyses are summarized in Table 1. The
required number, size and type of sample container, sample preservation, and maximum sample
holding times are outlined for each analytical parameter in Table 2. Proposed sampling locations
are depicted on Figure 2.
Key Personnel Overseeing Sample Collection Activities
The H&H personnel overseeing sample collection activities include an experienced On -Site
Project Coordinator. The H&H Project Manager may also conduct site visits during the field
activities.
Required Sample Collection Procedures
Subsurface soil sample collection will be performed using DPT methods. In the event that
access is not available to the DPT rig, a clean stainless steel hand auger will be used as an
alternative soil sample collection method. H&H's Standard Operating Procedures for soil
sampling using DPT methods are included in Appendix A (attached on CD). Upon completion
of soil sampling, soil borings will be abandoned by backfilling with bentonite or grout.
Ground water sample collection will be performed in permanent monitoring wells installed using
DPT methods. Wells will be equipped with 1-inch PVC screen assemblies, a sand filter pack,
and a bentonite seal. Ground water is expected to be relatively shallow; however, in the event
refusal is encountered at the proposed monitoring well locations before reaching the water table,
the well site will be relocated within a 20-ft radius of the proposed well location and another
attempt(s) will be made to install a well. Should attempts to install a well be unsuccessful within
the 20-ft radius area using DPT rods, hollow -stem augers will be used to attempt well
installation. H&H's Standard Operating Procedures for well purging and ground water sampling
are presented in Appendix A (attached on CD).
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Page 25
Containerized investigation -derived waste will be held on -site until analytical results determine
how this material will be handled and disposed.
List of Sample Collection Equipment
A list of sample collection equipment (including make and model of certain field equipment) to
be used on this particular Brownfields assessment is provided in Section B7.
On -Site Support Facilities
Potable water will be made available at the site, either from a pressurized source or from
commercially available bottled water. Drinking cups will be supplied so personnel will neither
drink directly from the source of water nor have to share drinking cups. Non -potable water shall
be clearly labeled as such.
Toilet facilities are not available to field staff at the site. However, transportation is readily
available to personnel to nearby public toilet facilities. Therefore, temporary toilet facilities will
not be provided on -site.
Washing facilities will be provided on -site and will be located in the decontamination area or the
support zone. Soap, clean water, wash basins and single -use towels will be available for
personnel use.
Equipment Decontamination Procedures and Requirements
Decontamination procedures and requirements for sample collection equipment to be used on the
subject Brownfields Assessment are described in detail in H&H's Standard Operating
Procedures in Appendix A (attached on CD).
Hart & Hickman, PC

City of Rocky Mount NC Site -Specific QAPP Addendum Revision 0
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Page 26
B3. Sampling Handling and Custody Requirements
Information required by this section is provided in the Generic QAPP previously approved by
EPA Region 4.
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Page 27
B4. Analytical Methods and Requirements
Sample preparation (i.e., extraction, digestion) and analytical methodologies for targeted
sampling parameters are outlined in Tables 1, 3 and 4. It is not anticipated that non-standard or
unpublished analytical methodologies will be required for this assessment project. Prism
Laboratories' Quality Assurance Manual is included as Appendix B (attached on CD).
The analytical procedures utilized in performing the assessment will conform to the protocols
specified in the EPA Standard Methods. The laboratory is not permitted to modify methods or
laboratory protocols without prior approval or unless they fully document the modification in the
data package. If a nonstandard or unapproved method is needed to address an unusual condition,
method validation data will be provided by the laboratory to confirm that the data will be
adequate for the intended use of the data.
Prism Laboratories' QA Manager Helmuth Janssen is responsible for implementing corrective
actions for analyses if deemed necessary.
Laboratory analytical data reports are submitted to H&H electronically, and are expected
approximately 14 business days from the date the samples are received at the laboratory.
Hart & Hickman, PC

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Page 28
B5. Field Quality Control Requirements
Information required by this section is provided in the Generic QAPP previously approved by
EPA Region 4. Field QC samples will be collected and analyzed as specified in Table 1.
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Page 29
B6. Laboratory Quality Control Requirements
Laboratory quality control data for Brownfields projects routinely includes method blanks,
surrogate data and lab control samples, and lab control sample duplicates. A corresponding
laboratory analytical QC table broken down by matrix and analytical parameter is provided as
Table 3 of this Site -Specific QAPP Addendum. Information in Table 3 is provided by Prism
Laboratories, Inc. Further details are provided in Section 11.0 of the Prism Laboratories' QA
Manual provided in Appendix B (attached on CD).
Hart & Hickman, PC

City of Rocky Mount NC Site -Specific QAPP Addendum Revision 0
BF-95414908 Former Planter's Oil Mill Site November 18, 2010
Page 30
B7. Field Equipment & Corrective Action
A list of sample collection equipment (including make and model of certain field equipment) to
be used on this particular Brownfields assessment is provided in the table below.
List of Sample Collection Equipment
Minimum Calibration
Dedicated or Non -
Frequency
Dedicated
Equipment
Calibration Method
Direct Penetration
N/A
N/A
Non -Dedicated
Drill Rig
DPT Rods & Tools
N/A
N/A
Non -Dedicated
DPT Macro -Core
N/A
N/A
Non -Dedicated
Sampler
Macro -Core Acetate
N/A
N/A
Dedicated
Sleeve
Water Level Meter
N/A
N/A
Non -Dedicated
Geo Peristaltic
N/A
N/A
Dedicated sampling tubing
Pump
Horiba D-24
Reference Standards
2 times daily or after every
Method 9040B
10 samples
(pH)
Non -Dedicated
Measurements repeatable
to within 0.2 units.
Hart & Hickman, PC

City of Rocky Mount NC
BF-95414908
Site -Specific QAPP Addendum
Former Planter's Oil Mill Site
Revision 0
November 18, 2010
Page 31
Minimum Calibration
Dedicated or Non -
Frequency
Dedicated
Equipment
Calibration Method
Horiba D-24
Reference Standards
2 times daily or after every
FM 2550B
10 samples
(Specific
Non -Dedicated
Conductance)
Measurements repeatable
to within 20 µmhos.
Horiba D-24
Reference Standards
2 times daily or after every
Method 120.1
10 samples
(Temperature)
Non -Dedicated
Measurements repeatable
to within 0.5 degree.
Turbidity Meter
Reference Standards
2 times daily
Non -Dedicated
Method 180.1
(beginning of day and
middle of day)
PID — MiniRAE
Zero air and
Prior to use each day
Non -Dedicated
(Soil Organic
isobutylene (100
Vapors)
ppm)
DO Meter
Saturation (refer to
2 times daily
manual)
(Dissolved Oxygen)
Method 360.1
(prior to and at end of each
sampling day) or after
every 10 samples
Non -Dedicated
Measurements repeatable
to within 0.2 mg/l.
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Page 32
B8. Lab Equipment & Corrective Action
Information required by this section is provided in Sections 9.0, 10.0, and 13.0 of Prism
Laboratories, Inc. QA Manual provided in Appendix B (attached on CD).
Hart & Hickman, PC

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B9. Analytical Sensitivity & Project Criteria
Information required by this section is provided in Table 4 of this Site -Specific QAPP
Addendum, which provides a summary of analytical detection limits compared to project
criteria.
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BF-95414908 Former Planter's Oil Mill Site November 18, 2010
Page 34
B10. Data Management and Documents
Information required by this section is provided in the Generic QAPP previously approved by
EPA Region 4. The project will not require any modifications or additions to the Generic QAPP
that need to be incorporated in this Site -Specific QAPP Addendum.
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City of Rocky Mount NC Site -Specific QAPP Addendum Revision 0
BF-95414908 Former Planter's Oil Mill Site November 18, 2010
Page 35
C1. Assessment and Response Actions
Information required by this section is provided in the Generic QAPP previously approved by
EPA Region 4.
Hart & Hickman, PC

City of Rocky Mount NC Site -Specific QAPP Addendum Revision 0
BF-95414908 Former Planter's Oil Mill Site November 18, 2010
Page 36
C2. Project Reports
ABCA Addendum or Other Deliverable Annroved by DENR
The field sampling activities and collected data will be documented in an Analysis of
Brownfields Cleanup Alternatives (ABCA) Addendum or other deliverable as needed to meet
NCDENR requirements for a Brownfields Agreement. This document will include a description
of field activities, a tabular summary of the results of soil and ground water samples compared to
potential regulatory target levels, figures depicting site structures and sample locations,
laboratory analytical report, and conclusions based upon our pre -design data collection activities.
The report will also provide a recommendation for the cleanup approach and an estimated
cost(s). A selected remedy will be developed based upon commercial/industrial as the
anticipated future site use.
Hart & Hickman, PC

City of Rocky Mount NC Site -Specific QAPP Addendum Revision 0
BF-95414908 Former Planter's Oil Mill Site November 18, 2010
Page 37
D1. Field Data Evaluation
Information required by this section is provided in the Generic QAPP previously approved by
EPA Region 4.
Hart & Hickman, PC

City of Rocky Mount NC Site -Specific QAPP Addendum Revision 0
BF-95414908 Former Planter's Oil Mill Site November 18, 2010
Page 38
D2. Laboratory Data Evaluation
Information required by this section is provided in Section 12.0 of Prism Laboratories' QA
Manual provided in Appendix B (attached on CD).
Hart & Hickman, PC

City of Rocky Mount NC Site -Specific QAPP Addendum Revision 0
BF-95414908 Former Planter's Oil Mill Site November 18, 2010
Page 39
D3. Data Usability and Project Evaluation
Information required by this section is provided in the Generic QAPP previously approved by
EPA Region 4. The project will not require any modifications or additions to the Generic QAPP
that need to be incorporated in this Site -Specific QAPP Addendum.
Hart & Hickman, PC

City of Rocky Mount NC Site -Specific QAPP Addendum Revision 0
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Page 40
El. References
1. EPA. EPA Regional Screening Levels (RSLs) for Chemical Contaminants at Superfund
Sites (SSLs). Updated May 2010.
2. NCDENR. Inactive Hazardous Sites Branch. Soil Remediation Goals (SRG). January
2010.
3. NCDENR. Inactive Hazardous Sites Branch. Supplemental Guidelines for the
Evaluation of Structural Vapor Intrusion Potential for Site Assessments and Remedial
Actions under the Inactive Hazardous Sites Branch. October 2010.
4. NCDENR. UST Section. Guidelines for Site Checks, Tank Closure and Initial Response
and Abatement for UST Releases. Rev. 11/26/2008.
5. NCDENR. UST Section. Guidelines for Assessment and Corrective Action for UST
Releases (rev. 11/26/2008); MSCC Table (1/2010) and GCL Table (1/2010).
6. North Carolina Administrative Code Title 15A NCDENR Division of Water Quality
Subchapter 2L Classifications and Water Quality Standards Applicable to the
Groundwaters of North Carolina. Updated January 2010.
7. U.S. Environmental Protection Agency. Guidance on Systematic Planning Using the
Data Quality Objectives Process. EPA QA/G-4EPA 240/B-06/001. February 2006.
8. U.S. Environmental Protection Agency. Guidance for Quality Assurance Project Plans.
EPA QA/G-5. EPA 240/R-02/009. December 2002.
9. U.S. Environmental Protection Agency. EPA Requirements for Quality Assurance
Project Plans. EPA QA/R-5. EPA 240-/B-/O14003. Reissued May 2006.
10. U.S. EPA Region 4. Brownfields Quality Assurance Project Plans (QAPPs) Interim
Instructions, Generic QAPP and Site -Specific QAPP Addendum for Brownfield Site
Assessments and/or Cleanup. February 2010.
11. U.S. EPA Region 4. SESD. Field Branches Quality System and Technical Procedures.
February 2008.
Hart & Hickman, PC

FIGURES
Figure 1 - Topographic Map
Figure 2 - Site Layout Map

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QUADRANGLE
7.5 MINUTE SERIES (TOPOGRAPHIC)

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TABLES
Table 1 - Example Sample Summary Table
Table 2 - Sampling and Analytical Methods Requirements Table
Table 3 - Laboratory Analytical Quality Control — Prism Laboratories
Table 4 - Analytical Sensitivity and Project Criteria — Prism Laboratories

Table 1
Sample Summary Table
Brownfield Cleanup Grant - Remedial Design Data Gathering
Former Planter's Oil Mill Site
Rocky Mount, North Carolina
H&H Job No. CRM-008
Proposed Sample ID
Proposed Sample
Depth Intervals (ft
bgs)
Sample Objective
ANALYSES'
VOCs3
EPA-8260B
PAHs
EPA-8270C
Arsenic
SM 6010B
OCPs/OPPs
SM 8081/8141A
SVOCs + 10 TICS
EPA 625/8270
MADEP
EPH
Samples:
NW Truck Scales
S13-1
0-2
Surface Soil Sample
1
S13-1
4-6
Subsurface Soil Sample
1
1
MW-1
GW
Shallow Groundwater Sample
1
1
Former Drum Storage Area/Maintenance Shop
S13-2
0-2
Surface Soil Sample
1
1
S13-2
4-6
Subsurface Soil Sample
1
1
MW-2
GW
Subsurface Soil Sample
1
1
SB-13 0-2 Surface Soil Sample
1
1
1
1
Previous POM-2 Sampling Location
S13-3
0-2
Surface Soil Sample
1
S13-3
4-6
Subsurface Soil Sample
1
1
MW-3
GW
Shallow Groundwater Sample
1
1
No. 6 Fuel Oil UST Area - Limited Site Assessment
S13-4
0-2
Surface Soil Sample
1
S13-4
4-6
Subsurface Soil Sample
1
1
S13-4
9-11
Subsurface Soil Sample
1
1
S13-4
14-16
Subsurface Soil Sample
1
1
MW-4
GW
Shallow Groundwater Sample
1
1
Hexane Tank/Solvent Extraction Area 3
S13-5
0-2
Surface Soil Sample
1
S13-5
4-6
Hexane Tank/Solvent Extraction Area
1
1
MW-5
GW
Shallow Groundwater Sample
1
1
S13-6
0-2
Surface Soil Sample
1
S13-6
4-6
Hexane Tank/Solvent Extraction Area
1
1
SB-14
0-2
Sump
1
SB-14
4-6
Sump
1
1
1
Arsenic in Surface Soils
S13-7
0-2
Surface Soil Sample
1
S13-8
0-2
Surface Soil Sample
1
S13-9
0-2
Surface Soil Sample
1
SB-10
0-2
Surface Soil Sample
1
SB-11
0-2
Surface Soil Sample
1
SB-12
0-2
1 Surface Soil Sample
1
Quality Control Samples
Duplicate
I Data Quality Assurance
1
1
1
MS/MSD
jData Quality Assurance
1
1
1
TOTALS:j
13
113
117
2
4
4
Notes:
1. VOCs - Volatile Organic Compounds; PAHs - Polynuclear Aromatic Hydrocarbons; OPPs - Organophosphorous Pesticides; OCPs - Organochlorine Pesticides; SVOCs - Semi-VOCs; TICs - Tentatively Identified Compounds;
MADEP - Massachusetts Department of Environmental Protection; EPH - Extractable Petroleum Hydrocarbons; SM-Standard Method; MS/MSD - Matrix Spike/Matrix Spike Duplicate
2. Laboratory QA Level II Requested on all data packages.
3. For S13-5, S13-6 and S13-14, hexane will be added to the VOC analyte list.
SAAAA-Master Projects\City of Rocky Mount - CRM\CRM-008 POM Cleanup Grant\SSQAPP\QAPP Tables
December 19, 2007
Hart Hickman, PC

Table 2
Sampling and Analytical Methods Requirements Table
Brownfield Assessment
Former Planter's Oil Mill Site
Rocky Mount, North Carolina
H&H Job No. CRM-008
Sample
Holding Time
Preservation Procedures
Container Type
Analysis
Water
I Soil
Water
Soil
IT Water
Soil
Volatile Organic Compounds
14 days - Advance
14 days- Advance notice
4°C, 5 mL 20%
(3) 40 ml, VOA glass;
(3) 40 mL VOA glass + stir bar,
(including hexane)
notice required to lab
required to lab
4°C; HCL to PH <2
NaHSO4
Teflon lined septum
2oz. glass for dry wt.
7 days until extraction,
14 days until extraction,
Polynuclear Aromatic Hydrocarbons
40 days after extraction
40 days after extraction
0.0080/oNa2S202; 4°C
4°C
(2) l liter glass (amber)
8 oz glass - 200 gm
7 days until extraction,
14 days until extraction,
Polychlorinated Biphenyls
40 days after extraction
40 days after extraction
0.0080/.Na2S202; 4°C
4°C
(2) l liter glass (amber)
8 oz glass - 200 gm
Total Petroleum Hydrocarbons - Gas
(3) 40 ml, VOA glass;
Range Organics
14 days
14 days
HCl to H<2; 4°C
OC
Teflon lined septum
4 oz glass - 100 gin
Total Petroleum Hydrocarbons -
Diesel Range Organics
14 days
14 days
4°C
OC
2 1 liter glass (amber)
8 oz glass - 200 Rm
7 days to extract; 40
7 days to extract; 40 days
Organochlorine Pesticides
days post -extraction
post -extraction
0.0080/.Na2S202; 4°C
OC
(2) l liter glass (amber)
8 oz glass - 200 gm
7 days to extract; 40
7 days to extract; 40 days
Organophosphoms Compounds
days post -extraction
post -extraction
0.0080/.Na2S202; 4°C
4°C
(2) l liter glass (amber)
8 oz glass - 200 gm
Target Metals
180 days; Hg-28 days
180 days; Hg-28 days
pH<2 w/HNO3. 4°C
4°C
1 liter plastic
4 oz glass - 100 gm
Nitrates
48 hours
48 hours
Cool to <6°C
4°C
100 ml plastic
4 oz glass - 50 gin
Temperature, field pH, Conductivity,
Immediately after
Turbidity, ORP, and D.O.
sample collected
Not Applicable
Not Applicable
Not Applicable
Not Applicable
Not Applicable
Note: EPA Method 8260B for soils will be collected using 5035 Field Prep Method
This procedure involves the following tools:
1. laboratory provided easydraw syringe(s)
2. (1) 2 oz jar for dry weight
3. (2) 40 ml VOA vials with stir bars filled with 5 mis of Sodium Bisulfate and tare weight
4. (1) 40 ml VOA vial with 5 mis of Methanol and tare weight
The sample proceedure for the 5035 Field Prep Method includes the following:
1. fill the 2 ozjar with soil for dry weight
2. using the provided laboratory provided syringe fill the (3) VOA vials with approximately 5 grams of soil (as indicated on the easydraw syringe)
3. secure lids
SA\AAA-Master Projects\City of Rocky Mount - CRM\CRM-008 POM Cleanup Grant\SSQAPP\QAPP Tables
December 19, 2007 H. Hka.,.,,x

Table 3
Summary of Primary Compounds of Concern and QA/QC Requirements
Brownfield Assessment
Former Planter's Oil Mill Site
Page 1 of 2
Rocky Mount, North Carolina
H&H Job No. CRM-008
Range of
Analytical
Extraction/
Primary Compounds of Concern
Laboratory
Method
Digestion Method
Reporting Limits
Laboratory
MS Percent
MSD RPD
Method Blank
Control Percent
Recovery
Percent
Acceptance Limits
Recovery
VOCs by Method 8260/SM6210
8260B
5035
ug/kg or ug/l
3
46-136
22
<1/2 RL
62-119
Benzene soil
Benzene water
8260B
0.5
62-129
19
<1/2 RL
70-141
Ethylbenzene soil
8260B
5035
5
51-135
23
<1/2 RL
57-128
Ethylbenzene water
8260B
0.5
58-133
20
<1/2 RL
80-139
Hexane soil
8260B
5035
NA
NA
NA
<1/2 RL
NA
Hexane water
8260B
10
70-130*
20*
<1/2 RL
70-130*
m,p-Xylenes soil
8260B
5035
10
51-136
20
<1/2 RL
54-132
m,p-Xylenes water
8260B
1
59-137
20
<1/2 RL
82-136
Methyl-t-butyl ether soil
8260B
5035
5
50-146
20
<1/2 RL
66-129
Methyl-t-butyl ether water
8260B
0.5
70-130*
20*
<1/2 RL
70-130*
Naphthalene soil
8260B
5035
5
45-147
24
<1/2 RL
48-140
Naphthalene water
8260B
1
54-127
24
<1/2 RL
40-136
o-Xylenes soil
8260B
5035
5
49-137
22
<1/2 RL
57-131
o-Xylenes water
8260B
0.5
65-129
21
<1/2 RL
73-134
Tetrachloroethene soil
8260B
5035
5
50-136
24
<1/2 RL
53-129
Tetrachloroethene water
8260B
0.5
55-130
22
<1/2 RL
67-124
Toluene soil
8260B
5035
1
60-131
21
<1/2 RL
78-130
Toluene water
8260B
0.5
60-131
21
<1/2 RL
78-130
Trichloroethene soil
8260B
5035
1
45-141
23
<1/2 RL
59-129
Trichloroethene water
8260B
0.5
52-128
18
<1/2 RL
78-124
TPH by EPA Method 8015
TPH - GRO soil
8015
5035
5 mg/kg
57-113
23
<1/2 RL
67-116
TPH - GRO water
8015
0.2 mg/L
69-130
24
<1/2 RL
60-138
TPH - DRO soil
8015
3550
10 mg/kg
52-119
25
<1/2 RL
53-118
TPH - DRO water
8015
1 m
51-145
22
<1/2 RL
53-135
EPH by MADEP Method
C9 - C18 Aliphatics
MADEP
10 mg/kg
40-140
50
<1/2 RL
40-140
C19 - C36 Aliphatics
10 mg/kg
40-140
50
<1/2 RL
40-140
C11 - C22 Aromatics
10 m
40-140
50
<1/2 RL
40-140
SVOCs and PAHs by EPA Method 8270C
8270C
3550B
ug/kg or ug/I
330
36-107
32
<1/2 RL
44-110
Acenaphthene soil
Acenaphthene water
8270C
3510C
10
47-145
17
<1/2 RL
47-145
Acenaphthylenesoil
8270C
3550B
330
33-110
32
<1/2 RL
43-114
Acenaphthylene water
8270C
3510C
10
33-145
17
<1/2 RL
33-145
Anthracene soil
8270C
3550B
330
48-120
25
<1/2 RL
59-120
Anthracene water
8270C
3510C
10
27-133
12
<1/2 RL
27-133
Benzo(a)anthracenesoil
8270C
3550B
330
31-128
31
<1/2 RL
46-125
Benzo(a)anthracene water
8270C
3510C
10
33-143
12
<1/2 RL
33-143
Benzo(a)pyrenesoil
8270C
3550B
330
50-123
23
<1/2 RL
60-124
Benzo(a)pyrene water
8270C
3510C
10
17-163
22
<1/2 RL
17-163
Benzo(b)fluoranthenesoil
8270C
3550B
330
45-125
25
<1/2 RL
55-125
Benzo(b)fluoranthene water
8270C
3510C
10
24-159
18
<1/2 RL
24-159
Benzo(g,h,i)perylene soil
8270C
3550B
330
38-124
25
<1/2 RL
41-133
Benzo(g,h,i)perylene water
8270C
3510C
10
10-219
22
<1/2 RL
10-219
Benzo(k)fluoranthenesoil
8270C
3550B
330
48-121
27
<1/2 RL
58-124
Benzo(k)fluoranthene water
8270C
3510C
10
11-162
27
<1/2 RL
11-162
Chrysene soil
8270C
3550B
330
29-129
32
<1/2 RL
44-128
Chrysene water
8270C
3510C
10
17-168
19
<1/2 RL
17-168
Dibenzo(a,h)anthracenesoil
8270C
3550B
330
34-130
25
<1/2 RL
46-129
Dibenzo(a,h)anthracene water
8270C
3510C
10
10-227
33
<1/2 RL
10-227
Fluoranthene soil
8270C
3550B
330
47-121
23
<1/2 RL
57-120
Fluoranthene water
8270C
3510C
10
26-137
11
<1/2 RL
26-137
Flumene soil
8270C
3550B
330
38-117
30
<1/2 RL
52-113
Flumene water
8270C
3510C
10
59-121
13
<1/2 RL
59-121
Indeno(1,2,3-c,d)pyrene soil
8270C
3550B
330
34-131
28
<1/2 RL
44-133
Indeno(1,2,3-c,d)pyrene water
8270C
3510C
10
10-171
22
<1/2 RL
10-171
Naphthalene soil
8270C
3550B
330
25-101
38
<1/2 RL
36-104
Naphthalene water
8270C
3510C
10
21-133
10
<1/2 RL
21-133
Phenanthrene soil
8270C
3550B
330
47-121
23
<1/2 RL
58-117
Phenanthrene water
8270C
3510C
10
54-120
10
<1/2 RL
54-120
Pyrene soil
8270C
3550B
330
45-133
27
<1/2 RL
54-131
Pyrene
8270C
3510C
10
52-115
10
<1/2 RL
52-115
Metals by EPA Method 6010
6010B
3050B
mg/kg or mg/L
0.5
75-125
20
:51/2 RL
80-120
arsenic soil
arsenic water
6010B
3010A
0.01
75-125
20
:51/2 RL
80-120
barium soil
6010B
3050B
0.5
75-125
20
:51/2 RL
80-120
barium water
6010B
3010A
0.01
75-125
20
:51/2 RL
80-120
cadmium soil
6010B
3050B
0.25
75-125
20
:51/2 RL
80-120
cadmium water
6010B
3010A
0.001
75-125
20
:51/2 RL
80-120
silver soil
6010B
3050B
0.25
75-125
20
:51/2 RL
80-120
silver water
6010B
3010A
0.005
75-125
20
:51/2 RL
80-120
mercury soil
7471
0.02
80-120
20
:51/2 RL
80-120
mercury water
7470A
0.0002
80-120
20
:51/2 RL
80-120
selenium soil
6010B
3050B
0.5
75-125
20
:51/2 RL
80-120
selenium water
6010B
3010A
0.02
75-125
20
:51/2 RL
80-120
chromium soil
6010B
3050B
0.25
75-125
20
:51/2 RL
80-120
chromium water
6010B
3010A
0.005
75-125
20
:51/2 RL
80-120
lead soil
6010B
3050B
0.25
75-125
20
:51/2 RL
80-120
lead water
I 6010B
1 3010A
1 0.005
1 75-125
1 20
1 :51/2 RL
1 80-120
S:\AAA-Master Projects\City of Rocky Mount - CRM\CRM-008 POM Cleanup Grant\SSQAPP\QAPP Tables
December 11, 2007 xon xkk.a„, x

Table 3
Summary of Primary Compounds of Concern and QA/QC Requirements
Brownfield Assessment
Former Planter's Oil Mill Site
Page 2 of 2
Rocky Mount, North Carolina
H&H Job No. CRM-008
Range of
Analytical
Extraction/
Primary Compounds of Concern
Laboratory
Method
Digestion Method
Reporting Limits
Laboratory
MS Percent
MSD RPD
Method Blank
Control Percent
Recovery
Percent
Acceptance Limits
Recovery
Pesticides - Oraanochorine
8081A
ug/kg or pg/I
2
ug/kg or pg/1
62-134
24
:51/2 RL
72-126
a-BHC soil
a-BHC water
8081A
50
52-130
31
:51/2RL
63-125
P-BHC soil
8081A
2
67-144
17
:51/2 RL
79-134
R-BHC water
8081A
50
31-166
29
:51/2RL
65-137
5-BHC soil
8081A
2
70-138
18
:51/2 RL
74-132
5-BHC water
8081A
50
20-171
27
:51/2RL
65-132
y-BHC (Lindane) soil
8081A
2
62-137
22
:51/2 RL
71-129
y-BHC (Lindane) water
8081A
50
45-140
32
:51/2 RL
66-129
a -chlordane soil
8081A
2
59-138
25
:51/2 RL
71-132
a -chlordane water
8081A
50
18-147
40
:51/2 RL
68-126
y-chlordane soil
8081A
2
59-139
27
:51/2 RL
71-132
y-chlordane water
8081A
50
35-136
34
:51/2 RL
66-126
4,4-DDD soil
8081A
2
57-152
29
:51/2 RL
72-142
4,4-DDD water
8081A
50
17-160
29
:51/2 RL
66-138
4,4-DDE soil
8081A
2
61-143
36
:51/2 RL
74-129
4,4-DDE water
8081A
50
10-158
38
:51/2 RL
67-127
4,4-DDT soil
8081A
2
56-163
38
:51/2RL
75-141
4,4-DDT water
8081A
50
15-171
30
:51/2RL
66-142
aldrin soil
8081A
2
57-137
29
:51/2 RL
66-132
aldrin water
8081A
50
24-142
35
:51/2 RL
62-124
chlordane soil
8081A
50
50-150
40
:51/2 RL
50-150
chlordane water
8081A
500
50-150
40
:51/2RL
50-150
dieldrin soil
8081A
2
60-141
30
:51/2 RL
72-136
dieldrin water
8081A
50
27-148
28
:51/2 RL
69-130
endosulfan I soil
8081A
2
66-137
32
:51/2 RL
74-134
endosulfan I water
8081A
50
40-141
40
:51/2 RL
71-129
endosulfan 11 soil
8081A
2
70-141
20
:51/2 RL
79-134
endosulfan 11 water
8081A
50
43-146
32
:51/2 RL
73-135
endosulfan sulfate soil
8081A
2
65-153
24
:51/2 RL
73-147
endosulfan sulfate water
8081A
50
37-153
36
:51/2 RL
72-137
endrin soil
8081A
2
65-164
21
:51/2 RL
74-147
endrin water
8081A
50
35-165
27
:51/2 RL
69-144
endrin aldehyde soil
8081A
2
63-147
35
:51/2 RL
73-138
endrin aldehyde water
8081A
50
15-165
33
:51/2 RL
68-139
endrin ketone soil
8081A
2
65-152
18
:51/2 RL
84-135
endrin ketone water
8081A
50
36-172
29
:51/2 RL
68-150
heptachlor soil
8081A
2
63-142
27
:51/2 RL
72-134
heptachlor water
8081A
50
38-150
36
:51/2 RL
61-136
heptachlor epoxide soil
8081A
2
63-136
18
:51/2 RL
73-132
heptachlor epoxide water
8081A
50
40-141
36
:51/2 RL
69-131
methoxychlor soil
8081A
2
60-179
30
:51/2RL
91-138
methoxychlor water
8081A
50
37-187
34
:51/2 RL
70-157
toxaphene soil
8081A
50
50-150
40
:51/2 RL
50-150
toxaphene water
8081A
500
50-150
40
:51/2 RL
50-150
Pesticides - Oraanophospherous'
8141A
ug/kg or pg/I
70
ug/kg or pg/l
40-140
40
:51/2 RL
40-140
0,0,0-triethylphosphorothioate soil
0,0,0-triethylphosphorothioate water
8141A
2
40-140
40
:51/2 RL
40-140
atrazine (Aatrex) soil
8141A
100
40-140
40
:51/2 RL
40-140
atrazine (Aatrex) water
8141A
1
40-140
40
:51/2 RL
40-140
Azinphos methyl soil
8141A
450
40-140
40
:51/2 RL
40-140
Azinphos methyl water
8141A
15
40-140
40
:51/2 RL
40-140
bolstar soil
8141A
100
40-140
40
:51/2 RL
40-140
bolstar water
8141A
1
40-140
40
:51/2 RL
40-140
chloropyrifos soil
8141A
100
40-140
40
:51/2 RL
40-140
chloropyrifos water
8141A
3
40-140
40
:51/2 RL
40-140
coumaphos soil
8141A
250
40-140
40
:51/2 RL
40-140
coumaphos water
8141A
15
40-140
40
:51/2RL
40-140
demeton soil
8141A
200
40-140
40
:51/2 RL
40-140
demeton water
8141A
6
40-140
40
:51/2 RL
40-140
diazinon soil
8141A
250
40-140
40
:51/2 RL
40-140
diazinon water
8141A
6
40-140
40
:51/2 RL
40-140
dichlorovos soil
8141A
100
40-140
40
:51/2 RL
40-140
dichlorovos water
8141A
1
40-140
40
:51/2RL
40-140
dimethoate soil
8141A
50
40-140
40
:51/2 RL
40-140
dimethoate water
8141A
5
40-140
40
:51/2RL
40-140
disulfoton soil
8141A
50
40-140
40
:51/2 RL
40-140
disulfoton water
8141A
2
40-140
40
:51/2 RL
40-140
EPN soil
8141A
100
40-140
40
:51/2 RL
40-140
EPN water
8141A
2
40-140
40
:51/2 RL
40-140
ethoprop soil
8141A
250
40-140
40
:51/2 RL
40-140
ethoprop water
8141A
3
40-140
40
:51/2RL
40-140
ethyl parathion soil
8141A
50
40-140
40
:51/2 RL
40-140
ethyl parathion water
8141A
2
40-140
40
:51/2 RL
40-140
famphur soil
8141A
50
40-140
40
:51/2RL
40-140
famphur water
8141A
2
40-140
40
:51/2 RL
40-140
fensulfothion soil
8141A
250
40-140
40
:51/2 RL
40-140
fensulfothion water
8141A
15
40-140
40
:51/2 RL
40-140
fenthion soil
8141A
100
40-140
40
:51/2 RL
40-140
fenthion water
8141A
1
40-140
40
:51/2 RL
40-140
malathion soil
8141A
100
40-140
40
:51/2 RL
40-140
malathion water
8141A
1
40-140
40
:51/2 RL
40-140
merphos soil
8141A
100
40-140
40
:51/2 RL
40-140
merphos water
8141A
13
40-140
40
:51/2 RL
40-140
methyl parathion soil
8141A
50
40-140
40
:51/2 RL
40-140
methyl parathion water
8141A
2
40-140
40
:51/2 RL
40-140
mevinphos soil
8141A
100
40-140
40
:51/2 RL
40-140
mevinphos water
8141A
3
40-140
40
:51/2RL
40-140
naled soil
8141A
100
40-140
40
:51/2 RL
40-140
naled water
8141A
1
40-140
40
:51/2 RL
40-140
phorate soil
8141A
50
40-140
40
:51/2 RL
40-140
phorate water
8141A
2
40-140
40
:51/2RL
40-140
ronnel soil
8141A
100
40-140
40
:51/2 RL
40-140
ronnel water
8141A
3
40-140
40
:51/2 RL
40-140
sulfotep soil
8141A
50
40-140
40
:51/2 RL
40-140
sulfotep water
8141A
2
40-140
40
:51/2RL
40-140
tetrachlorvinphos (stirofos) soil
8141A
100
40-140
40
:51/2 RL
40-140
tetrachlorvinphos (stirofos) water
8141A
50
40-140
40
:51/2 RL
40-140
thionazine soil
8141A
70
40-140
40
:51/2 RL
40-140
thionazine water
8141A
2
40-140
40
:51/2 RL
40-140
tokuthion (prothiophos) soil
8141A
150
40-140
40
:51/2 RL
40-140
tokuthion (prothiophos) water
8141A
5
40-140
40
:51/2 RL
40-140
trichloronate soil
8141A
100
40-140
40
:51/2 RL
40-140
trichloronate water
1 8141A
1
1 2
1 40-140
1 40
1 :51/2RL
1 40-140
Notes:
QC data presented in this table are provided by Prism Laboratories, Inc.
The laboratory precision requirements for laboratory method blanks, rinsate blanks and trip blanks is Non -Detect.
MS — Matrix spike
MSD - Matrix spike duplicate
RPD - Relative percent difference
' - Initial start-up limits (Prism Lab QAP
For additional QA/QC requirements and laboratory procedures for additional compounds refer to the Prism Laboratories QA Manual in Appendix B.
S:\AAA-Master Projects\City of Rocky Mount - CRM\CRM-008 POM Cleanup Grant\SSQAPP\QAPP Tables
December 11, 2007 a.n xwt. x

Table 4
Analytical Sensitivity and Project Criteria - Prism Laboratories
Brownfields Assessment
Former Planter's Oil Mill
Rocky Mount, NC
H Job No. CRM-008
Page 1 of 2
Project Criteria
Extraction)
DENR IHSB
Primary Compounds of Concern
Analytical
Digestion
Method
Reporting
Method
Detection Limit
Limit
EPA RSL for
DENR IHSB
Method
EPA RSL for
of
15A 2L GW
Residential
Industrial Soil
Health -Based
Ground Water
Standards
Soil
SRGsProtection
SRGs
PSRGs
Volatile Organics Compounds
8260B
5035
ug/kg or ug/I
1.3
ug/kg or ug/I
5.0
ug/kg
550
ug/kg
2,600
ug/kg
550
ug/kg
5
ug/L
tetrachloroethene soil
tetrachloroethene water
8260E
5030
0.12
0.50
0.7
trichloroethene soil
8260B
5035
1.4
5.0
2,800
14,000
2,800
18
trichloroethene water
8260E
5030
0.073
0.500
3
cis- 1,2-dichloroethene soil
8260B
5035
1.2
5.0
780,000
10,000,000
160,000
360
cis- 1,2-dichloroethene water
8260E
5030
0.054
0.500
70
trans- 1,2-dichloroethene soil
8260B
5035
0.99
5.0
150,000
690,000
31,000
510
trans- 1,2-dichloroethene water
8260E
5030
0.066
0.500
100
1,1-dichloroethane soil
8260B
5035
1.3
5.0
3,300
17,000
3,300
30.0
1,1-dichloroethane water
8260B
5030
0.053
0.500
6
1,2-dichloroethane soil
8260B
5035
1.3
5.0
430
2,200
430
2
1,2-dichloroethane water
8260B
5030
0.11
0.50
0.4
1,1-dichloroethene soil
8260E
5035
1.2
5.0
240,000
1,100,000
49,000
46
1,1-dichloroethene water
8260E
5030
0.046
0.500
7
1,1,1-trichloroethane soil
8260E
5035
1.2
5.0
8,700,000
38,000,000
640,000
1,200
1,1,1-trichloroethane water
8260E
5030
0.053
0.500
200
benzene soil
8260E
5035
1.3
3.0
1,100
5,400
1,100
7.3
benzene water
8260E
5030
0.044
0.500
1
toluene soil
8260E
5035
1.2
5.0
5,000,000
45,000,000
820,000
5,500
toluene water
8260E
5030
0.064
0.500
600
ethylbenzene soil
8260E
5035
1.0
5.0
5,400
27,000
5,400
8,100
ethylbenzene water
8260B
5030
0.085
0.500
600
xylenes (total) soil
8260B
5035
3.8
15
630,000
2,700,000
130,000
6,000
xylenes (total) water
8260B
5030
0.189
1.50
500
methyl-tert-butyl ether soil
8260B
5035
1.0
5.0
43,000
220,000
43,000
85
methyl-tert-butyl ether water
8260B
5030
0.11
0.50
20
vinyl chloride soil
8260B
5035
1.3
10
60
1,700
60
0.19
vinyl chloride water
8260B
5030
0.28
1.00
0.03
Polycyclic Aromatic Hydrocarbons
8270D
3540
ug/kg or ug/I
12
ug/kg or ug/I
330
ug/kg
3,400,000
ug/kg
33,000,000
ug/kg
690,000
ug/kg
8,400
ug/L
acenaphthene soil
acenaphthene water
8270D
3510
2.3
10
80
anthracene soil
8270D
3540
13
331
17,000,000
170,000,000
3,400,000
660,000
anthracene water
8270D
3510
0.62
10
2,000
benzo(a)anthracene soil
8270D
3540
12
330
150
2,100
150
180
benzo(a)anthracene water
8270D
3510
2.0
10
0.05
benzo(b)fluoranthene soil
8270D
3540
22
330
150
2,100
150
600
benzo(b)fluoranthene water
8270D
3510
1.2
10
0.05
benzo(g,h,i)perylene soil
8270D
3540
22
330
NS
NS
NS
360,000
benzo(g,h,i)perylene water
8270D
3510
1.5
10
200
benzo(k)fluoranthene soil
8270D
3540
29
330
1,500
21,000
1,500
5,900
benzo(k)fluoranthene water
8270D
3510
1.4
10
0.5
benzo(a)pyrene soil
8270D
3540
18
330
15
210
15
59
benzo(a)pyrene water
8270D
3510
1.2
10
0.005
chrysene soil
8270D
3540
18
330
15,000
210,000
15,000
18,000
chrysene water
8270D
3510
1.9
10
5
dibenz(a,h)anthracene soil
8270D
3540
25
330
15
210
15
190
dibenz(a,h)anthracene water
8270D
3510
1.5
10
0.005
fluoranthene soil
8270D
3540
18
330
2,300,000
22,000,000
460,000
330,000
fluoranthene water
8270D
3510
0.76
10
300
fluorene soil
8270D
3540
10
330
2,300,000
22,000,000
460,000
56,000
fluorene water
8270D
3510
1.7
10
300
indeno(1,2,3-cd)pyrene soil
8270D
3540
25
330
150
2,100
150
2,000
indeno(1,2,3-cd)pyrene water
8270D
3510
1.5
10
0.05
naphthalene soil
8270D
3540
26
330
3,600
18,000
3,600
210
naphthalene water
8270D
3510
3.2
10
6
pyrene soil
8270D
3540
26
330
1,700,000
17,000,000
340,000
220,000
pyrene water
8270D
3510
1.4
10
200
Pesticides - Oraanochorine
8081A
ug/kg or pg/I
0.18
ug/kg or pg/I
2
ug/kg or pg/I
77
270
77
NS
a-BHC soil
a-BHC water
8081A
0.0074
0.05
0.02
R-BHC soil
8081A
0.51
2
270
960
270
NS
R-BHC water
8081A
0.012
0
0.02
6-BHC soil
8081A
0.28
2
NS
NS
270
1.2
6-BHC water
8081A
0.0077
0.05
0.02
y-BHC (Lindane) soil
8081A
0.23
2
520
2,100
520
1.8
y-BHC (Lindane) water
8081A
0.0082
0.05
0.03
a -chlordane soil
8081A
0.35
2
NS
NS
1,600
68
a -chlordane water
8081A
0.0071
0.05
0.1
y-chlordane soil
8081A
0.32
2
NS
NS
1,600
68
y-chlordane water
8081A
0.0089
0.05
0.1
4,4-DDD soil
8081A
0.61
2
2,000
7,200
2,000
240
4,4-DDD water
8081A
0.014
0.05
0.1
4,4-DDE soil
8081A
0.43
2
1,400
5,100
1,400
NS
4,4-DDE water
8081A
0.0086
0.05
NS
4,4-DDT soil
8081A
0.72
2
1,700
7,000
1,700
340
4,4-DDT water
8081A
0.014
0.05
0.1
aldrin soil
8081A
0.4
2
29
100
29
NS
aldrin water
8081A
0.015
0.05
NS
chlordane soil
8081A
11.3
50
1,600
6,500
1,600
68
chlordane water
8081A
0.14
0.50
0.1
dieldrin soil
8081A
0.42
2
30
110
30
0.8
dieldrin water
8081A
0.0084
0.05
0.002
endosulfan I soil
8081A
0.36
2
NS
NS
73,000
5,600
endosulfan I water
8081A
0.0076
0.05
40
endosulfan II soil
8081A
0.45
2
NS
NS
73,000
5,600
endosulfan II water
8081A
0.0071
0.05
40
endosulfan sulfate soil
8081A
0.52
2
NS
NS
73,000
5,600
endosulfan sulfate water
8081A
0.0086
0.05
40
endrin soil
8081A
0.6
2
18,000
180,000
3,700
810
endrin water
8081A
0.0082
0.05
2
endrin aldehyde soil
8081A
0.56
2
NS
NS
3,700
810
endrin aldehyde water
8081A
0.016
0.05
2
endrin ketone soil
8081A
0.4
2
NS
NS
3,700
810
endrin ketone water
8081A
0.0094
0.05
2
heptachlor soil
8081A
0.47
2
110
380
110
6.6
heptachlor water
8081A
0.016
0.05
0.008
heptachlor epoxide soil
8081A
0.37
2
53
190
53
0.82
heptachlor epoxide water
8081A
0.0088
0.05
0.004
methoxychlor soil
8081A
1.4
2
310,000
3,100,000
NS
NS
methoxychlor water
8081A
0.017
0.05
40
toxaphene soil
8081A
11.2
50
440
1,600
440
46
toxaphene water
8081A
0.15
0.50
0.03
S:WAA-Master Projects\City of Rocky Mount- CRM\CRM-008 POM Cleanup Grant\SSOAPP\OAPP Tables

Table 4
Analytical Sensitivity and Project Criteria - Prism Laboratories
Brownfields Assessment
Former Planter's Oil Mill
Rocky Mount, NC
H Job No. CRM-008
Page 2 of 2
Pesticides - Organophospherous'
8141A
ug/kg or pg/1
14.6
ug/kg or pg/I
70
ug/kg or pg/1
NS
NS
NS
NS
0,0,0-triethylphosphorothioate soil
0,0,0-triethylphosphorothioate water
8141A
0.621
2
NS
atrazine (Aatrex) soil
8141A
33
100
2,100
7,500
2,100
25
atrazine (Aatrex) water
8141A
0.38
1
3
Azinphos methyl soil
8141A
33
450
180,000
1,800,000
NS
NS
Azinphos methyl water
8141A
0.164
15
NS
bolstar soil
8141A
33
100
NS
NS
NS
NS
bolstar water
8141 A
0.074
1
NS
chlorpyrifos soil
8141A
33
100
NS
NS
37,000
NS
chlorpyrifos water
8141A
0.18
3
NS
coumaphos soil
8141A
33
250
NS
NS
NS
NS
coumaphos water
8141 A
0.303
15
NS
demeton soil
8141A
66
200
2,400
25,000
490
NS
demeton water
8141A
2.48
6
NS
diazinon soil
8141A
33
250
43,000
430,000
8,600
NS
diazinon water
8141A
0.126
6
NS
dichlorovos soil
8141A
33
100
1,700
5,900
1,700
NS
dichlorovos water
8141 A
0.863
1
NS
dimethoate soil
8141A
24.9
50
12,000
120,000
2,400
NS
dimethoate water
8141A
1.25
5
NS
disulfoton soil
8141A
14.8
50
NS
NS
490
6.2
disulfoton water
8141A
0.5638
2
0.3
EPN soil
8141A
33
100
610
6,200
120
NS
EPN water
8141A
0.18
2
NS
ethoprop soil
8141A
33
250
NS
NS
NS
NS
ethoprop water
8141A
0.22
3
NS
ethyl parathion soil
8141A
11.9
50
15,000
150,000
73,000
NS
ethyl parathion water
8141A
0.267
2
NS
famphur soil
8141A
9.8
50
NS
NS
NS
NS
famphur water
8141A
0.6985
2
NS
fensulfothion soil
8141A
83.3
250
NS
NS
NS
NS
fensulfothion water
8141A
0.264
15
NS
fenthion soil
8141A
33
100
NS
NS
NS
NS
fenthion water
8141A
0.19
1
NS
malathion soil
8141A
33
100
1,200,000
12,000,000
24,000
NS
malathion water
8141A
0.05
1
NS
merphos soil
8141A
33
100
1,800
18,000
370
NS
merphos water
8141A
0.59
13
NS
methyl parathion soil
8141A
12.6
50
15,000
150,000
73,000
NS
methyl parathion water
8141A
0.484
2
NS
mevinphos soil
8141A
33
100
NS
NS
NS
NS
mevinphos water
8141A
0.58
3
NS
naled soil
8141A
33
100
120,000
1,200,000
24,000
NS
naled water
8141A
0.614
1
NS
phorate soil
8141A
20.6
50
12,000
120,000
2,400
13
phorate water
8141A
1.18
2
1
ronnel soil
8141A
33
100
3,100,000
31,000,000
610,000
NS
ronnel water
8141A
0.317
3
NS
sulfotep soil
8141A
15.8
50
31,000
310,000
NS
NS
sulfotep water
8141A
0.589
2
NS
tetrachlorvinphos (stirofos) soil
8141A
33
100
20,000
72,000
20,000
NS
tetrachlorvinphos (stirofos) water
8141A
0.059
50
NS
thionazine soil
8141A
21.9
70
NS
NS
NS
NS
thionazine water
8141A
0.691
2
NS
tokuthion (prothiophos) soil
8141A
33
150
NS
NS
NS
NS
tokuthion (prothiophos) water
8141A
0.27
5
NS
trichloronate soil
8141A
33
100
NS
NS
NS
NS
trichloronate water
8141A
0.59
2
NS
TPH by EPA Method 8015
8015C
5035
0.61 mg/kg
5 mg/kg
DENR UST Section Action Level (mg/kq)
TPH - GRO soil
10
TPH - GRO water
8015C
0.016 mg/L
0.2 mg/L
NS
NS
TPH - DRO soil
8015C
3550B
1.7 mg/kg
10 mg/kg
10
TPH - DRO water
8015C
3510C
0.039 mg/L
1 m /L
NS
NS
DENR UST
Section MCSS (mq/kg)
EPHbvMADEPMethod
Residential
Industrial Soil-to-GW
C9 - C18 Aliphatics
MADEP
10 mg/kg
1,500
40,000 540
700
C19 - C36 Aliphatics
10 mg/kg
31,000
810,000 NS
NS
10,000
C9 - C22 Aromatics
10 m
469
12,264 31
NS
200
TAL Metals
ug/kg or ug/L
ug/kg or ug/L
ug/kg
ug/kg
ug/kg
ug/kg
ug/L
arsenic soil
6010E
3050B
50
500
0.39
1.6
4.4
5.8
arsenic water
6010B
3010A
1.2
10
10
Notes:
Analytical and extraction/digestion method, method detection limit, and reporting limit data presented in this table are provided by Prism Laboratories, Inc.
DENR IHSB SRGs = NC Dept. of Environment and Natural Resources, Inactive Hazardous Sites Branch Soil Remediation Goals updated January 2010.
EPA RSL = Regional Screening Level (from USEPA Regional Screening Levels (RSL) for Chemical Contaminants at Superfund Sites. RSL Master Table Update (May 2010).
15A 2L GW Standards = NCAC Title 15A Subchapter 2L Groundwater Quality Standards
TAL = Target Analyte List; NA = Not Applicable; NS= Not Specified
For additional QA/QC requirements and laboratory procedures for additional compounds refer to the Prism Laboratories QA Manual in Appendix B.
For petroleum matters, appropriate NCDENR guidance will be followed and referenced in the site -specific QAPP.
S:WAA-Master Projects\City of Rocky Mount- CRM\CRM-008 POM Cleanup Grant\SSQAPP\QAPP Tables

Appendix A
Hart & Hickman, PC
Site -Specific Health & Safety Plan
(Attached on CD)
Hart & Hickman, PC
Standard Operating Procedures
(Attached on CD)

Appendix B
Prism Laboratories, Inc.
QA Manual
(Attached on CD)