RA-7781_39876_CA_LSA_20160610 LSA2

LIMITED SITE ASSESSMENT (PHASE II)

FRIENDLY MART
3055 Stantonsburg Road
Wilson, Wilson County, NC 27893
Facility ID #: 0-024589; UST Incident #: 39876
LATITUDE: N 35.69099167o; LONGITUDE: W 77.88775o (From GPS)
JUNE 10, 2016
UST OWNER:
Rose Oil Company, Inc., 613 US 158 Bypass, Henderson, NC 27537-6825
Phone Number: [phone]
PROPERTY OWNER/OCCUPANT:
Owner: SMW, Inc. – Occupant: Rose Oil Company, Inc., 613 US 158 Bypass
Henderson, NC 27537; Phone Number: [phone]
CONSULTANT: Henry Nemargut Engineering Services, 2211 Chestnut Street, Wilmington, NC 28405 Phone Number: [phone]
LABORATORY: Pace Analytical Services, Inc., 9800 Kincey Ave, Suite 100, Huntersville, NC 28078 Phone Number: [phone]; State Certification #12
RELEASE INFORMATION: Date Discovered: 12/17/15 Estimated Quantity of Release: Unknown; Cause of Release: Corrosion Source of Release: UST; Size and Contents: (1) 4,000 Gallon Diesel UST
The Limited Site Assessment Report for this site has been prepared by Henry Nemargut Engineering Services (sole proprietorship) under the direct supervision of a licensed engineer. I certify that the information contained in this report is correct and accurate to the best of my knowledge:
Henry Nemargut, P.E. North Carolina License #17669

June 10, 2016

Raymond Bartholomew
Rose Oil Company, Inc.
P.O. Box 706
Raleigh, NC 27536

Reference: Limited Site Assessment Report (Phase II)
Friendly Mart
3055 Stantonsburg Road
Wilson, Wilson County, North Carolina 27893
Facility ID#: 0-024589; Incident #39876

Dear Mr. Bartholomew:

In accordance with the requirements of March 1, 2007 Guidelines of the North Carolina Department of Environment and Natural Resources (NCDENR), contained herein is a Phase II Limited Site Assessment Report for the release which occurred at the above referenced facility. These activities have been conducted following the release of petroleum which occurred in the vicinity of underground storage tank (USTs) removed from this site. All activities were conducted in accordance with NCDEQ guidelines and the requirements of 15A NCAC 2N.
Mr. Bartholomew, if you have questions regarding this report please contact my office..
Sincerely,

Henry Nemargut, P.E.
Henry Nemargut Engineering Services

TABLE OF CONTENTS

Page

1.0 Site History, Source Characterization & Initial Abatement 1

2.0 Risk Characterization 1

3.0 Receptor Information 5

4.0 Site Geology and Soil Assessment 6

5.0 Groundwater Investigation 8

6.0 Conclusions and Recommendations 9

LIST OF FIGURES

Figure 1: Project Location/U.S.G.S. Topographic Map
Figure 2: Site Layout and Former UST Locations
Figure 3: Subsurface Utilities Map
Figure 4: Adjacent Properties Map
Figure 5: Receptor Map
Figure 6: Site Layout, Soil Sample Locations & Soil Contaminant Maps
Figure 7: Site Layout and Monitor Well Locations
Figure 8: Monitor Well Location & Potentiometric Surface Map
Figure 9: Benzene Concentration Map
Figure 10: C5-C8 Aliphatics Concentration Map

LIST OF TABLES

Table 1: Site History
Table 2: Adjacent Property Owners
Table 3: Supply Well Information
Table 4: Laboratory Analytical Results –Risk Based Soil Samples
Table 5: Monitoring Well Information and Groundwater Elevations
Table 6: Laboratory Analytical Results – Water Samples

APPENDICES

Appendix A: Laboratory Analytical Laboratory Results
Appendix B: Well Construction Records
Page - 1
LIMITED SITE ASSESSMENT (PHASE II)
Friendly Mart
3055 Stantonsburg Road, Wilson, North Carolina
Facility ID#: 0-024589; GW Incident #: 39876

1.0 - SITE HISTORY, SOURCE CHARACTERIZATION & INITIAL ABATEMENT

Rose Oil Company, Inc. owns USTs which are operated at the Friendly Mart facility
located at 3055 Stantonsburg Road in Wilson, North Carolina. Figure 1 illustrates the
location of this facility on the Wilson Quadrangle U.S.G.S. Topo Map. This facility
contains one permanent structure which is used as a gasoline convenience store. The site
formerly contained (2) 6,000 gallon gasoline, (1) 4,000 gallon gasoline, & (1) 4,000
gallon diesel USTs. All of the gasoline USTs are still in use at this facility. The 4,000
gallon diesel UST, which was last used at this facility in November, 2015, was removed
on December 17, 2015. Figure 2 illustrates the overall layout of this site and the UST
locations. Table 1 summarizes the UST history for the Friendly Mart site.

A release from the UST system was suspected on 12/17/15 based on elevated PID
readings observed in soil samples collected from around the UST and the presence of a
floating layer of diesel in the UST excavation. Groundwater was observed at a depth of
approximately 4’ to 5’ below surface in the UST pit during soil abatement activities. The
site and adjacent properties are used for commercial, residential and industrial purposes.
Municipal water supplies are available to properties within 1,500’; however, adjacent
properties are served by a local water supply well.

A Limited Site Assessment (LSA) has been conducted in response to this release in order
to classify the risk of the site for the release source originating at the USTs owned by
Rose Oil Company, Inc. The findings of the LSA conducted for this site are contained
herein.

2.0 - RISK CHARACTERIZATION AND LAND USE FORM

Part I Groundwater/Surface water/Vapor impact
Low Risk

1. Has discharge or release contaminated any water supply wells including any used
for non-drinking purposes?

UNKNOWN

2. Is a water supply well used for drinking water located within 1,000 feet of the
source area the discharge or release?

YES

Page - 2
3. Is a water supply well used for any purpose (e.g., irrigation, washing cars,
industrial cooling water, filling swimming pools) located within 250 feet of the
source area of the discharge or release?

YES

4. Does groundwater within 500 feet of the source area of the discharge or release
have the potential for future use in that there is no other source of water supply
other than the groundwater?

NO

5. Do vapors from the discharge or release pose a threat of explosion because of
accumulation of the vapors in a confined space or pose any other serious threat to
public health, public safety or the environment?

NO

6. Are there any factors that would cause the discharge or release to pose an
imminent danger to public health, public safety or the environment?

NO

Intermediate Risk

7. Is a surface body located within 500 feet of the source area of the discharge or
release?

NO

If yes, does the maximum groundwater contaminant concentration exceed the
surface water quality standards and criteria found in 15A NCAC 2B .0200 by a
factor of 10?

N/A

8. Is the source area of the discharge or release located within a designated wellhead
protection area as defined in 42 USC 300h-7(e)?

NO

9. Is the discharge or release located in the Coastal Plain physiographic region as
designated on a map entitled "Geology of North Carolina" published by the
Department in 1985?

Page - 3
YES

If yes, is the source area of the discharge or release located in an area in which
there is recharge to an unconfined or semi-confined deeper aquifer that is being
used or may be used as a source of drinking water?

UNKNOWN

10. Do the levels of groundwater contamination for any contaminant exceed the gross
contamination levels established (see Table 7 in guidelines) by the department?

NO

Part II-Land Use

Property containing Source Area of Discharge or Release

The questions below pertain to the property containing the source area of the release.

1. Does the property contain one or more primary or secondary residences
(permanent or temporary)?

NO

2. Does the property contain a school, daycare center, hospital, playground, park,
recreation area, church, nursing home, or other place of public assembly?

NO

3. Does the property contain a commercial (e.g., retail, warehouse, office/business
space, etc.) or industrial (e.g., manufacturing, utilities, industrial research and
development, chemical/petroleum bulk storage, etc.) enterprise, an inactive
commercial or industrial enterprise, or is the land undeveloped?

YES

4. Do children visit the property?

YES

Explain.

THE FACILITY IS USED AS A GASOLINE CONVENIENCE STORE

5. Is access to the property reliably restricted consistent with its use?
Page - 4

YES

6. Do pavement, buildings, or other structures cap the contaminated soil?

YES

If yes, what mechanisms are in place or can be put into place to insure that the
contaminated soil will remain capped in the foreseeable future?

CURRENT PLANS ARE TO CONTINUE CONVENIENCE STORE OPERATIONS

7. What is the zoning status of the property?

COMMERCIAL

8. Is the use of the property likely to change in the next 20 years?

NO

Property Surrounding Source Area of Discharge or Release.

9. What is the distance from the source area of the release to the nearest primary or
secondary residence (permanent or temporary)?

160’

10. What is the distance from the source area of the release to the nearest school,
daycare center, hospital, playground, park, recreation area, church, nursing home,
or other place of public assembly?

THERE ARE NO PLACES OF PUBLIC ASSEMBLY WITHIN 1,500’ OF THE
RELEASE SOURCE.

11. What is the zoning status of properties in the surrounding areas?

COMMERCIAL, LIGHT INDUSTRIAL & RESIDENTIAL

12. Briefly characterize the use and activities of the land in the surrounding area.

COMMERCIAL, LIGHT INDUSTRIAL, RESIDENTIAL & UNDEVELOPED

Page - 5
3.0 - RECEPTOR INFORMATION

3.1 Water Supply Wells

A supply well survey has been conducted within a 1,500' radius of the release area. This
survey was conducted by interviews conducted with owners and occupants of properties
located within 1,500’ of the release sources. During this reconnaissance (2) water supply
wells (1 in-use potable and 1 out of service potable) were found to be located within A
1,000’ radius. The in-use supply well is located 140’ from the UST release source and is
used to supply water for the adjacent private residence at 3043 Stantonsburg Road and
also the Ready Contractors office building at 3041 Stantonsburg Road. Table 3 lists
information for the wells identified during this investigation. Figure 5 depicts the
approximate locations of these wells on a Wilson County parcel map.

3.2 Public Water Supplies

Public water supplies are available to all properties within 1,500’ of the release site.

3.3 Surface Water

The partial Wilson Quadrangle U.S.G.S. Topographic Map included as Figure 1 indicates
that the release site is located on a slight ridge at an approximate elevation of 122’ amsl.
Surface waters in the vicinity of the release area generally drain towards the
north/northeast towards an unnamed intermittent stream. This intermittent stream
empties into the Contentnea Creek which lies within the Neuse River Basin.

3.4 Wellhead Protection Areas

No wellhead protection areas are known to exist within the area of this release.

3.5 Deep Aquifers in the Coastal Plain Physiographic Region

This release is located in the coastal plain. It is unknown if the shallow groundwater in
the release area feeds deep aquifers.

3.6 Subsurface Structures

Subsurface lines/structures are not present within the petroleum affected area at this site.
Subsurface utilities are present in the form of water & sewer. Underground water and
sewer lines enter the store building on the south side from Stantonsburg Rd, outside of
the impacted areas within the property boundaries. Figure 3 illustrates the locations of
subsurface utilities near the subject property.
Page - 6

3.7 Land Use

The possibility of human exposure to soil contamination at 3055 Stantonsburg Road site
is minimal. Petroleum impacted soils were remediated in the diesel UST area.
Contamination at this facility lies within a commercial site.

3.8 Property Owners and Occupants

Figure 4 illustrates the surrounding properties, and Table 2 contains information
regarding the adjacent property owners. This information was obtained from Wilson
County Tax records.

4.0 - SITE GEOLOGY AND SOIL INVESTIGATION

4.1 Site Geology

The site is situated in the Coastal Plain. According to the Geological Map of North
Carolina local geology of the region is classified as the Yorktown Formation, underlain
by fossiliferous clay with varying amounts of fine-grained sand. Bedrock was not
encountered to a depth of 15 feet below surface which was the maximum depth explored
during the subsurface investigation.

4.2 Soils Investigation

The soils at the project site consist of silt with varying clay & sand content. Soil boring
logs are contained on well construction records included as Appendix B.

Soil samples were collected from the perimeter of the UST excavation where over-
excavation was conducted to obtain risk-based analytical data for the site during IAA
activities. Results from the risk-based and TPH soil samples were below NCDEQ lowest
MSCCs or Action Levels for all 8260/8270/VPH/EPH/TPH compounds for pit wall
samples. The soil samples were obtained as specified in the collection, preservation, and
handling section of the specific method. Each container was labeled with sample
location, analyses to be performed, time, date, and the sampler's name. They were then
placed in a cooler and chilled with ice to approximately 4oC in preparation for
transportation to the analytical laboratory utilizing EPA approved chain of custody
procedures. Additional samples from each pit wall were containerized for possible
analyses via risk-based methods. A copy of the soil analytical report and the chain of
custody records for the risk-based soil samples collected at 3055 Stantonsburg Road is
contained in the previously submitted IAA report. Figure 6 depicts soil analytical results
on a site map of the over-excavation area for the diesel UST.

Page - 7
5.0 – GROUNDWATER INVESTIGATION

5.1 Monitoring Well Installation

A total of (4) North Carolina Type II groundwater monitoring wells was installed on-site
to complete LSA activities. A source area monitoring wells was installed during IAA
activities, with (3) additional monitoring wells installed during the Phase II LSA
activities. Figure 7 illustrates the locations of the monitor wells, denoted as MW-1
through MW-4 which were installed to complete LSA activities. The monitoring wells
installed at the site were constructed of 2-inch Schedule 40 PVC pipe with 4’ feet of
casing and 10’ of 0.010 inch slotted screen. Based on the assumption that the
contaminants being addressed were primarily hydrocarbon constituents with specific
gravities of less than 1.0, the Type II monitoring wells were installed so that the screened
interval intersected the shallow groundwater table at the time of installation. Well
construction records for the monitor wells constructed at this site for LSA activities are
included in Appendix B.

Free product was not detected in any of the monitoring wells installed at the site during a
check conducted on June 7, 2016.

5.2 Groundwater Flow Direction and Gradient

Figure 8 illustrates the shallow groundwater potentiometric surface as measured on
November 10, 2015. Groundwater is noted to be flowing in multiple directions on this
map. The UST pit is apparently a source of groundwater mounding which diverts the
natural groundwater flow patterns. Table 5 summarizes monitoring well information and
groundwater elevations as measured on June 7, 2016.

5.3 Monitor Well Sampling and Analyses

On January 28, 2016, source area monitor well MW-1 was sampled for analyses utilizing
EPA Methods 6200B, 625 + 10 peaks, Lead, and MADEP Methods for VPH/EPH as
appropriate based on UST contents. On April 20, 2016, Phase II LSA monitor wells
MW-2, MW-3, and MW-4 were sampled for analyses utilizing EPA Methods 6200B, 625
+ 10 peaks, Lead, and MADEP Methods for VPH/EPH as appropriate based on UST
contents. Before sampling, the monitor wells were developed and purged using
disposable balers. Following development of the groundwater monitoring well, samples
were obtained from the disposable balers. The supply well was also sampled with a
disposable baler. All samples were placed in laboratory supplied glassware, labeled with
sample location, analysis to be performed, time, date and sampler's name. The sample
jars were then immediately placed in a cooler, chilled with ice to approximately 4oC in
preparation of transportation to an analytical laboratory utilizing EPA approved chain-of-
custody procedures.

Page - 8
Laboratory analytical results from the monitoring well network installed at the site
indicate the presence of 14 compounds/compound groups above 15 NCAC 2L Standards.
Benzene was noted at a concentration of 3,830 ug/l in MW-4, above its 2L Standard of 1
ug/l but below its GCL Standard of 5,000 ug/l. C5-C8 Aliphatics were noted at a
concentration of 23,000 ug/l in MW-4 above their 2L Standard of 400 ug/l. No
compounds were detected at levels above GCLs. Table 6 summarizes the laboratory
analytical results for the groundwater samples collected for LSA Activities. Appendix A
contains a copy of the laboratory analytical report and chain of custody record for the
groundwater samples collected during LSA activities at this site.

6.0 - CONCLUSIONS AND RECOMMENDATIONS

6.1 General Summary

Limited Site Assessment activities at 3055 Stantonsburg Road have been completed.
From a review of all information gathered during this project, Henry Nemargut
Engineering Services makes the following conclusions:

o A well reconnaissance of the site was performed within 1,500’ of the release
source area. (2) water supply wells (1 in-use potable and 1 out of service potable)
were found to be located within a 250’ radius. The in-use supply well is located
140’ from the UST release source and is used to supply water for the adjacent
private residence at 3043 Stantonsburg Road and also the Ready Contractors
office building at 3041 Stantonsburg Road.

o Results from the risk-based samples obtained during IAA activities were below
current NCDEQ lowest MSCCs for all compounds/compound groups for samples
collected in the walls of the diesel UST remedial excavation. Soil excavation
during IAA resulted in remediation of all contaminated soils in the former diesel
UST location.

o (4) groundwater monitoring wells, MW-1 through MW-4, were installed during
IAA/LSA activities. These wells were screened to intersect the top of the shallow
water table observed at the site. Free product was not detected in any of these
monitoring wells during a site check conducted on June 7, 2016.

o Laboratory analytical results from LSA monitoring well network indicate the
presence of 14 compounds/compound groups above 15 NCAC 2L Standards.
Benzene was noted at a concentration of 3,830 ug/l in MW-4, above its 2L
Standard of 1 ug/l but below its GCL Standard of 5,000 ug/l. C5-C8 Aliphatics
were noted at a concentration of 23,000 ug/l in MW-4 above their 2L Standard of
400 ug/l. No compounds were detected at levels above GCLs.

Page - 9

6.2 Recommendations

Based upon a review of all information gathered during this project, Henry Nemargut
Engineering Services makes the following recommendations:

o A site ranking should be assigned by the NCDEQ to determine the need for any
further action at this site.

o A copy of this report has been forwarded to the following address: Mr. John Maloy NCDEQ – UST Section 3800 Barrett Drive Raleigh, NC 27609 6.3 Limitations

This report has been prepared for the exclusive use of Rose Oil Company, Inc. for the
specific application to the referenced site located in Wilson County, North Carolina. The
evaluation was conducted based on the scope of work and level of effort desired by the
client and with resources adequate only for the scope of work. Our findings have been
developed in accordance with generally accepted standards for Limited Site Assessments
in the State of North Carolina, available information and our professional judgment. No
other warranty is expressed or implied.

The data presented in this report are indicative of conditions at the precise locations
sampled and the time the sample was collected. Additionally, the data obtained from the
samples would be interpreted as meaningful with respect to the parameters in the
laboratory reports. No additional information can be logically inferred from this data.

FIGURES

TABLES
TABLE 1: SITE HISTORY
Plainview Grocery
3055 Stantonsburg Road, Wilson, NC 27565

Property Ownership:

S.M.W., Inc.
P.O. Box 706
Henderson, NC 27536-0706
9/4/1985 to present

Previous Property Owners:

Lawrence & Annie Jones
1/31/1974 to 9/4/1985

UST Information:

Tank Inst. Size Closure UST Tank
No Date (Gal) Date Status Contents
1 8/19/81 6,000 N/A In-use Gasoline
2 8/19/81 6,000 N/A In-use Gasoline
3 8/19/81 4,000 1/6/99 Closed Gasoline
3A 7/14/99 4,000 N/A In-use Gasoline
4 1/1/64 4,000 12/17/15 Closed Diesel

Tank owner:

Rose Oil Company, Inc.
P.O. Box 706
Henderson, NC 27536-0706
9/4/1985 to present
TABLE 2: ADJACENT PROPERTY OWNERS
FRIENDLY MART
3055 STANTONSBURG ROAD
WISLON, NORTH CAROLINA 27893

MAP ID PARCEL ID OWNER INFORMATION

Project 3730-08-2189.000 S.W.M., Inc.
Site 613 US 158 Bypass
Henderson, NC 27537-6825

1 3730-18-6502.000 City of Wilson
P.O. Box 10
Wilson, NC 27894-0010

2 3730-08-5691.000 Lawrence Thomas Jones
4570 Aaron Court
Elm City, NC 27822-8600

3 3730-17-5223.000 McCall Farms, Inc.
6615 Irby Street South
Effingham, SC 29541

4 3730-98-0830.000 Alliance One International, Inc.
P.O. Box 650
Farmville, NC 27828-0650

5 3730-08-1453.000 Larene Bass Radford
3043 Stantonsburg Rd SE
Wilson, NC 27893-7865

WellIdentification IW-1 SW-2Owner Name Larene Bass Radford Lawrence Thomas JonesProperty Address3043 Stantonsburg Rd 3041 Stantonsburg RdWilson, NC 27893 Wilson, NC 27893Occupant Larene Bass Radford Ready Contractors, Inc.PARID # 3730-08-1453.000 3730-08-5691.000Use Out of Service Potable Potable for 3041 & 3043 Distance 120' 140'City Water? NO NODepth of WellUnknownUnknown3055 STANTONSBURG RD, WILSON, NC 27893TABLE 3SUPPLY WELL INFORMATION1,500' RADIUSFRIENDLY MARTDepth of WellUnknownUnknownWell Diameter 6" 6"Well Yield Unknown UnknownDepth to Pump Unknown UnknownDepth of Casing Unknown UnknownStatic Water Unknown UnknownFriendly Mart
Sample Location E W Lowest MSCC Ind/Comm MSCC Residential MSCCDate12/17/2015 12/17/2015 (note units) (note units) (note units)Sample depth3' 3' Method 8260 (ug/kg)Benzene BDL BDL 5.6 164,000.0 18,000Methylene Chloride BDL 18.6 20 763,000 85,000n-Butylbenzene BDL BDL 4,300 16,350,000 626,000sec-Butylbenzene BDL BDL 3,300 16,350,000 626,000Ethylbenzene BDL BDL 4,900 40,000,000 1,560,000Isopropylbenzene BDL BDL 2,000 40,880,000 1,564,000p-Isopropyltoluene BDL BDL NSE NSE NSENaphthalene BDL BDL 160 8176000 313,000Acetone BDL BDL 24,000 360,000,000 14,000,000n-Propylbenzene BDL BDL 2,000 16,350,000 626,000Toluene BDL BDL 4,300 32,000,000 1,200,0001,2,4-Trimethylbenzene BDL BDL 8,500 20,440,000 782,0001,3,5-Trimethylbenzene BDL BDL 8,300 20,440,000 782,000MTBE BDL BDL 91 3,100,000 350,000sec-butylbenzene BDL BDL 3,400 16,350,000 626,000Xylenes (total) BDL BDL 4,600 81,760,000 3,129,000Method 8270 (ug/kg)FluoreneBDLBDL47,00016,400,000620,000Fluoranthene BDL BDL 290,000 16,400,000 620,000Phenanthrene BDL BDL 56,000 12,264,000 469,0001-Methylnaphthalene BDL BDL 4 100,000 20,0002-Methylnaphthalene BDL BDL 3,600 1,635,000 63,000Naphthalene BDL BDL 160 8176000 313,000Aliphatic Fraction Classes (mg/kg) C5 - C8 Volatile Aliphatics BDL BDL 68 24,528 939C9 - C12 Volatile Aliphatics BDL BDL NSE NSE NSEC9-C18 Extractable Aliphatics BDL BDL NSE NSE NSEC9-C18 Aliphatics (total) BDL BDL 540 40,000 1,500C19-C36 Extractable AliphaticsBDLBDLNSE810,00031,000Aromatic Fraction Classes (mg/kg) C9 - C10 Volatile AromaticsBDLBDLNSENSENSEC11 - C22 Extractable Aromatics BDL BDL NSE NSE NSEC9 - C22 Aromatics (total)BDLBDL3112264469BDL = below detection limits NR = analyses not requestedNSE = no standard establishedTABLE 4Laboratory Analytical Results - Risk Based Soil SamplesFriendly Mart, 3055 Stantonsburg Road, Wilson, NC
TABLE 5Monitoring Well Information and Groundwater ElevationsFriendly Mart, 3055 Stantonsburg, NC 27893Well Number Top of Casing Elevation Top of Screen Elevation Bottom of Screen Elevation Depth to Water Groundwater ElevationMW-1 99.79 95.79 85.79 5.12 94.67MW-2 100.00 96.00 86.00 6.49 93.51MW-3 99.19 95.19 85.19 6.16 93.03MW-4 99.88 95.88 85.88 5.86 94.02All measurements taken in feet and based on an arbitrary benchmark of 100 ft. established at MW-1Groundwater levels measured on 6/7/2016Friendly
Constituent MW-1 MW-2 MW-3 MW-4 GCL 2L Standard

Date 1/28/2016 4/20/2016 4/20/2016 4/20/2016
Standard Method 6200B (ug/L)
Benzene 37.9 10 202 3830 5,000 1
Toluene 4.1 24.5 BDL 1480 260,000 600
Ethylbenzene 64.5 155 6.6 973 84,500 600
Xylenes (total) 38.6 380 19 2815 85,500 500
BTEX (total) 145.1 569.5 227.6 9098 NSE NSE
p-Isopropyltoluene BDL BDL BDL BDL NSE NSE
Isopropylbenzene 124 18 4.3 99.7 25,000 70
Diisopropyl Ether (DIPE) BDL 1.3 BDL 287 70,000 70
Naphthalene 21.8 113 42.8 369 6,000 6
n-propylbenzene BDL 55.9 BDL 158 30,000 70
Bromodichloromethane BDL 21.5 BDL BDL NSE NSE
Bromoform BDL 8 BDL BDL 4,000 4
tetrachloroethene BDL 9.3 BDL BDL 700 0.7
Carbon Tetrachloride BDL 23.7 BDL BDL NSE 0.3
Trichloroethene BDL 1.6 BDL BDL 3,000 3
Chloroform BDL 255 48.3 BDL 70,000 70
Methylene Chloride BDL 8.6 16.8 131 5,000 5
dibromochloroethane BDL 9.3 BDL BDL 400 0.4
n-butylbenzene BDL 8 BDL BDL 6,900 70
sec-butylbenzene BDL 4.3 2.7 BDL 8,500 70
Methyl-tert-butyl-ether (MTBE) 6.4 18.2 970 6540 20,000 20
1,2,4-Trimethylbenzene BDL 321 33.6 1030 28,500 400
1,3,5-Trimethylbenzene BDL 98.5 7.8 259 25,000 400
Styrene BDL 1.1 BDL BDL 70,000 70
Acetone BDL BDL BDL BDL 6,000,000 6000
Lead (EPA 6010) BDL BDL BDL BDL 15,000 15
Method 625 (ug/L)
Acenaphthene BDL BDL BDL BDL 2,120 80
Naphthalene 8 29.8 9.4 196 6,000 6
TOTAL TICs 292.1 445.8 581.9 4599 NSE NSE
MADEP Aliphatic Fraction Classes (ug/L)
C5-C8 Volatile Aliphatics 330 910 1200 23000 NSE 400
C9-C12 Volatile Aliphatics 584 2600 360 15000 NSE NSE
C9-C18 Extractable Aliphatics 106 BDL BDL 880 NSE 700
C9-C18 Aliphatics (total) 690 2600 360 15880 NSE 700
C19-C36 Extractable Aliphatics BDL BDL BDL BDL NSE 10,000
MADEP Aromatic Fraction Classes (ug/L)
C9-C10 Volatile Aromatics 508 1600 200 4400 NSE NSE
C11-C22 Extractable Aromatics BDL BDL 176 744 NSE NSE
C9-C22 Aromatics (total)508 1,600 376 5,144 NSE 200
N/A = Not Analyzed BDL = Below Detection Limits BDL = Below Detection Limits
TABLE 6
SUMMARY OF GROUNDWATER ANALYTICAL RESULTS
Friendly Mart
3055 Stantonsburg Rd, Wilson, NC 27893

APPENDIX A

LABORATORY ANALYTICAL RESULTS
#=CL#
May 06, 2016
LIMS USE: FR - HENRY NEMARGUT
LIMS OBJECT ID: 92294881
92294881
Project:
Pace Project No.:
RE:
Henry Nemargut
Henry Nemargut Engineering
2211 Chestnut Street
Wilmington, NC 28405
FRIENDLY MART
Dear Henry Nemargut:
Enclosed are the analytical results for sample(s) received by the laboratory on April 21, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
Some analyses have been subcontracted outside of the Pace Network. The subcontracted
laboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 39
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92294881
FRIENDLY MART
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Page 2 of 39
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92294881
FRIENDLY MART
Lab ID Sample ID Matrix Date Collected Date Received
92294881001 MW 2 Water 04/20/16 18:55 04/21/16 16:09
92294881002 MW 3 Water 04/20/16 19:10 04/21/16 16:09
92294881003 MW 4 Water 04/20/16 19:30 04/21/16 16:09
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 3 of 39
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92294881
FRIENDLY MART
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92294881001 MW 2 MADEP EPH 7 PASI-CBJL
EPA 6010 1 PASI-ACDF
EPA 625 68 PASI-CRES
SM 6200B 63 PASI-CNB
92294881002 MW 3 MADEP EPH 7 PASI-CBJL
EPA 6010 1 PASI-ACDF
EPA 625 68 PASI-CRES
SM 6200B 63 PASI-CNB
92294881003 MW 4 MADEP EPH 7 PASI-CBJL
EPA 6010 1 PASI-ACDF
EPA 625 68 PASI-CRES
SM 6200B 63 PASI-CNB
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Page 4 of 39
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92294881
FRIENDLY MART
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92294881001 MW 2
Aromatic (C11-C22) 321 ug/L 04/27/16 19:34 N2100MADEP EPH
Naphthalene 29.8 ug/L 04/26/16 05:265.0EPA 625
5.257:Ethylbenzene 55.4 ug/L 04/26/16 05:26 NEPA 625
5.616:o-Xylene 50.9 ug/L 04/26/16 05:26 NEPA 625
6.298:Benzene, 1-ethyl-3-methy 38.2 ug/L 04/26/16 05:26 NEPA 625
6.375:Benzene, 1,3,5-trimethyl 36.5 ug/L 04/26/16 05:26 NEPA 625
6.598:Benzene, 1,2,3-trimethyl 125 ug/L 04/26/16 05:26 NEPA 625
6.834:Benzene, 1-ethyl-2-methy 30.2 ug/L 04/26/16 05:26 NEPA 625
6.963:Indane 34.0 ug/L 04/26/16 05:26 NEPA 625
7.104:Benzene, 2-ethyl-1,4-dim 27.3 ug/L 04/26/16 05:26 NEPA 625
7.322:Benzene, 4-ethyl-1,2-dim 27.9 ug/L 04/26/16 05:26 NEPA 625
7.816:Benzene, 2-ethenyl-1,4-d 20.4 ug/L 04/26/16 05:26 NEPA 625
Benzene 10.0 ug/L 04/25/16 19:501.0SM 6200B
Bromodichloromethane 21.5 ug/L 04/25/16 19:501.0SM 6200B
Bromoform 8.0 ug/L 04/25/16 19:501.0SM 6200B
n-Butylbenzene 8.0 ug/L 04/25/16 19:501.0SM 6200B
sec-Butylbenzene 4.3 ug/L 04/25/16 19:501.0SM 6200B
Carbon tetrachloride 23.7 ug/L 04/25/16 19:501.0SM 6200B
Chloroform 255 ug/L 04/25/16 19:501.0SM 6200B
Dibromochloromethane 9.3 ug/L 04/25/16 19:501.0SM 6200B
Diisopropyl ether 1.3 ug/L 04/25/16 19:501.0SM 6200B
Ethylbenzene 155 ug/L 04/25/16 19:501.0SM 6200B
Isopropylbenzene (Cumene) 18.0 ug/L 04/25/16 19:501.0SM 6200B
Methylene Chloride 8.6 ug/L 04/25/16 19:50 C94.0SM 6200B
Methyl-tert-butyl ether 18.2 ug/L 04/25/16 19:501.0SM 6200B
Naphthalene 113 ug/L 04/25/16 19:504.0SM 6200B
n-Propylbenzene 55.9 ug/L 04/25/16 19:501.0SM 6200B
Styrene 1.1 ug/L 04/25/16 19:501.0SM 6200B
Tetrachloroethene 9.3 ug/L 04/25/16 19:501.0SM 6200B
Toluene 24.5 ug/L 04/25/16 19:501.0SM 6200B
Trichloroethene 1.6 ug/L 04/25/16 19:501.0SM 6200B
1,2,4-Trimethylbenzene 321 ug/L 04/25/16 19:501.0SM 6200B
1,3,5-Trimethylbenzene 98.5 ug/L 04/25/16 19:501.0SM 6200B
m&p-Xylene 243 ug/L 04/25/16 19:502.0SM 6200B
o-Xylene 137 ug/L 04/25/16 19:501.0SM 6200B
92294881002 MW 3
Aromatic (C11-C22) 176 ug/L 04/27/16 20:01 N2100MADEP EPH
Naphthalene 9.4 ug/L 04/26/16 05:545.0EPA 625
7.104:Unknown 135 ug/L 04/26/16 05:54 NEPA 625
7.434:Unknown 78.7 ug/L 04/26/16 05:54 NEPA 625
9.004:o-Tolylacetic acid 16.8 ug/L 04/26/16 05:54 NEPA 625
9.510:Unknown 27.1 ug/L 04/26/16 05:54 NEPA 625
9.981:Unknown 27.7 ug/L 04/26/16 05:54 NEPA 625
10.245:4-Isopropylphenylacetic 35.1 ug/L 04/26/16 05:54 NEPA 625
10.463:Unknown 20.5 ug/L 04/26/16 05:54 NEPA 625
10.934:Unknown 14.2 ug/L 04/26/16 05:54 NEPA 625
11.775:2-Naphthylpropionic aci 179 ug/L 04/26/16 05:54 NEPA 625
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Huntersville, NC 28078
[phone]
Page 5 of 39
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92294881
FRIENDLY MART
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92294881002 MW 3
12.686:Octadecanoic acid 47.8 ug/L 04/26/16 05:54 NEPA 625
Benzene 202 ug/L 04/25/16 20:072.5SM 6200B
sec-Butylbenzene 2.7 ug/L 04/25/16 20:072.5SM 6200B
Chloroform 48.3 ug/L 04/25/16 20:072.5SM 6200B
Diisopropyl ether 9.4 ug/L 04/25/16 20:072.5SM 6200B
Ethylbenzene 6.6 ug/L 04/25/16 20:072.5SM 6200B
Isopropylbenzene (Cumene) 4.3 ug/L 04/25/16 20:072.5SM 6200B
Methylene Chloride 16.8 ug/L 04/25/16 20:07 C910.0SM 6200B
Methyl-tert-butyl ether 970 ug/L 04/25/16 20:072.5SM 6200B
Naphthalene 42.8 ug/L 04/25/16 20:0710.0SM 6200B
1,2,4-Trimethylbenzene 33.6 ug/L 04/25/16 20:072.5SM 6200B
1,3,5-Trimethylbenzene 7.8 ug/L 04/25/16 20:072.5SM 6200B
m&p-Xylene 6.2 ug/L 04/25/16 20:075.0SM 6200B
o-Xylene 12.8 ug/L 04/25/16 20:072.5SM 6200B
92294881003 MW 4
Aliphatic (C09-C18) 880 ug/L 04/27/16 20:29 N2100MADEP EPH
Aromatic (C11-C22) 774 ug/L 04/27/16 20:29 N2100MADEP EPH
Naphthalene 196 ug/L 04/26/16 09:4010.0EPA 625
3.899:3-Pentanol, 3-methyl- 350 ug/L 04/26/16 06:21 NEPA 625
4.063:Toluene 801 ug/L 04/26/16 06:21 NEPA 625
4.422:Cyclopentanol, 1-methyl- 243 ug/L 04/26/16 06:21 NEPA 625
5.075:Unknown 410 ug/L 04/26/16 06:21 NEPA 625
5.263:Ethylbenzene 838 ug/L 04/26/16 06:21 NEPA 625
5.622:Benzene, 1,3-dimethyl- 517 ug/L 04/26/16 06:21 NEPA 625
6.298:1,3-Cyclopentadiene, 5-( 311 ug/L 04/26/16 06:21 NEPA 625
6.375:Benzene, 1,2,3-trimethyl 184 ug/L 04/26/16 06:21 NEPA 625
6.604:1,2,4-Trimethylbenzene 616 ug/L 04/26/16 06:21 NEPA 625
6.963:Indane 228 ug/L 04/26/16 06:21 NEPA 625
Benzene 3830 ug/L 04/25/16 20:2420.0SM 6200B
Diisopropyl ether 287 ug/L 04/25/16 20:2420.0SM 6200B
Ethylbenzene 973 ug/L 04/25/16 20:2420.0SM 6200B
Isopropylbenzene (Cumene) 99.7 ug/L 04/25/16 20:2420.0SM 6200B
Methylene Chloride 131 ug/L 04/25/16 20:24 C980.0SM 6200B
Methyl-tert-butyl ether 6540 ug/L 04/25/16 20:2420.0SM 6200B
Naphthalene 369 ug/L 04/25/16 20:2480.0SM 6200B
n-Propylbenzene 158 ug/L 04/25/16 20:2420.0SM 6200B
Toluene 1480 ug/L 04/25/16 20:2420.0SM 6200B
1,2,4-Trimethylbenzene 1030 ug/L 04/25/16 20:2420.0SM 6200B
1,3,5-Trimethylbenzene 259 ug/L 04/25/16 20:2420.0SM 6200B
m&p-Xylene 2190 ug/L 04/25/16 20:2440.0SM 6200B
o-Xylene 625 ug/L 04/25/16 20:2420.0SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 39
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92294881
FRIENDLY MART
Sample: MW 2 Lab ID: 92294881001 Collected: 04/20/16 18:55 Received: 04/21/16 16:09 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: MADEP EPH Preparation Method: MADEP EPHMADEP EPH NC Water
Aliphatic (C09-C18) ND ug/L 04/27/16 19:34 N204/22/16 14:32100 1
Aliphatic (C19-C36) ND ug/L 04/27/16 19:34 N204/22/16 14:32100 1
Aromatic (C11-C22)321 ug/L 04/27/16 19:34 N204/22/16 14:32100 1
Surrogates
Nonatriacontane (S) 78 % 04/27/16 19:34 7194-86-704/22/16 14:3240-140 1
o-Terphenyl (S) 66 % 04/27/16 19:34 84-15-104/22/16 14:3240-140 1
2-Fluorobiphenyl (S) 89 % 04/27/16 19:34 321-60-804/22/16 14:3240-140 1
2-Bromonaphthalene (S) 92 % 04/27/16 19:34 580-13-204/22/16 14:3240-140 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Lead ND ug/L 04/26/16 20:33 7439-92-104/25/16 17:405.0 1
Analytical Method: EPA 625 Preparation Method: EPA 625625 MSSV
Acenaphthene ND ug/L 04/26/16 05:26 83-32-904/25/16 13:005.0 1
Acenaphthylene ND ug/L 04/26/16 05:26 208-96-804/25/16 13:005.0 1
Anthracene ND ug/L 04/26/16 05:26 120-12-704/25/16 13:005.0 1
Benzo(a)anthracene ND ug/L 04/26/16 05:26 56-55-304/25/16 13:005.0 1
Benzo(a)pyrene ND ug/L 04/26/16 05:26 50-32-804/25/16 13:005.0 1
Benzo(b)fluoranthene ND ug/L 04/26/16 05:26 205-99-204/25/16 13:005.0 1
Benzo(g,h,i)perylene ND ug/L 04/26/16 05:26 191-24-204/25/16 13:005.0 1
Benzo(k)fluoranthene ND ug/L 04/26/16 05:26 207-08-904/25/16 13:005.0 1
4-Bromophenylphenyl ether ND ug/L 04/26/16 05:26 101-55-304/25/16 13:005.0 1
Butylbenzylphthalate ND ug/L 04/26/16 05:26 85-68-704/25/16 13:005.0 1
4-Chloro-3-methylphenol ND ug/L 04/26/16 05:26 59-50-704/25/16 13:005.0 1
bis(2-Chloroethoxy)methane ND ug/L 04/26/16 05:26 111-91-104/25/16 13:0010.0 1
bis(2-Chloroethyl) ether ND ug/L 04/26/16 05:26 111-44-404/25/16 13:005.0 1
bis(2-Chloroisopropyl) ether ND ug/L 04/26/16 05:26 108-60-104/25/16 13:005.0 1
2-Chloronaphthalene ND ug/L 04/26/16 05:26 91-58-704/25/16 13:005.0 1
2-Chlorophenol ND ug/L 04/26/16 05:26 95-57-804/25/16 13:005.0 1
4-Chlorophenylphenyl ether ND ug/L 04/26/16 05:26 7005-72-304/25/16 13:005.0 1
Chrysene ND ug/L 04/26/16 05:26 218-01-904/25/16 13:005.0 1
Dibenz(a,h)anthracene ND ug/L 04/26/16 05:26 53-70-304/25/16 13:005.0 1
3,3'-Dichlorobenzidine ND ug/L 04/26/16 05:26 91-94-104/25/16 13:0025.0 1
2,4-Dichlorophenol ND ug/L 04/26/16 05:26 120-83-204/25/16 13:005.0 1
Diethylphthalate ND ug/L 04/26/16 05:26 84-66-204/25/16 13:005.0 1
2,4-Dimethylphenol ND ug/L 04/26/16 05:26 105-67-904/25/16 13:0010.0 1
Dimethylphthalate ND ug/L 04/26/16 05:26 131-11-304/25/16 13:005.0 1
Di-n-butylphthalate ND ug/L 04/26/16 05:26 84-74-204/25/16 13:005.0 1
4,6-Dinitro-2-methylphenol ND ug/L 04/26/16 05:26 534-52-104/25/16 13:0020.0 1
2,4-Dinitrophenol ND ug/L 04/26/16 05:26 51-28-504/25/16 13:0050.0 1
2,4-Dinitrotoluene ND ug/L 04/26/16 05:26 121-14-204/25/16 13:005.0 1
2,6-Dinitrotoluene ND ug/L 04/26/16 05:26 606-20-204/25/16 13:005.0 1
Di-n-octylphthalate ND ug/L 04/26/16 05:26 117-84-0 L304/25/16 13:005.0 1
bis(2-Ethylhexyl)phthalate ND ug/L 04/26/16 05:26 117-81-704/25/16 13:005.0 1
Fluoranthene ND ug/L 04/26/16 05:26 206-44-004/25/16 13:005.0 1
Fluorene ND ug/L 04/26/16 05:26 86-73-704/25/16 13:005.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/06/2016 02:26 PM
Pace Analytical Services, Inc.
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Huntersville, NC 28078
[phone]
Page 7 of 39
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92294881
FRIENDLY MART
Sample: MW 2 Lab ID: 92294881001 Collected: 04/20/16 18:55 Received: 04/21/16 16:09 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 625 Preparation Method: EPA 625625 MSSV
Hexachloro-1,3-butadiene ND ug/L 04/26/16 05:26 87-68-304/25/16 13:005.0 1
Hexachlorobenzene ND ug/L 04/26/16 05:26 118-74-104/25/16 13:005.0 1
Hexachlorocyclopentadiene ND ug/L 04/26/16 05:26 77-47-404/25/16 13:0010.0 1
Hexachloroethane ND ug/L 04/26/16 05:26 67-72-104/25/16 13:005.0 1
Indeno(1,2,3-cd)pyrene ND ug/L 04/26/16 05:26 193-39-504/25/16 13:005.0 1
Isophorone ND ug/L 04/26/16 05:26 78-59-104/25/16 13:0010.0 1
Naphthalene 29.8 ug/L 04/26/16 05:26 91-20-304/25/16 13:005.0 1
Nitrobenzene ND ug/L 04/26/16 05:26 98-95-304/25/16 13:005.0 1
2-Nitrophenol ND ug/L 04/26/16 05:26 88-75-504/25/16 13:005.0 1
4-Nitrophenol ND ug/L 04/26/16 05:26 100-02-704/25/16 13:0050.0 1
N-Nitrosodimethylamine ND ug/L 04/26/16 05:26 62-75-904/25/16 13:005.0 1
N-Nitroso-di-n-propylamine ND ug/L 04/26/16 05:26 621-64-704/25/16 13:005.0 1
N-Nitrosodiphenylamine ND ug/L 04/26/16 05:26 86-30-604/25/16 13:0010.0 1
Pentachlorophenol ND ug/L 04/26/16 05:26 87-86-504/25/16 13:0010.0 1
Phenanthrene ND ug/L 04/26/16 05:26 85-01-804/25/16 13:005.0 1
Phenol ND ug/L 04/26/16 05:2604/25/16 13:005.0 1
Pyrene ND ug/L 04/26/16 05:26 129-00-004/25/16 13:005.0 1
1,2,4-Trichlorobenzene ND ug/L 04/26/16 05:26 120-82-104/25/16 13:005.0 1
2,4,6-Trichlorophenol ND ug/L 04/26/16 05:26 88-06-204/25/16 13:0010.0 1
Surrogates
Nitrobenzene-d5 (S) 34 % 04/26/16 05:26 4165-60-004/25/16 13:0010-120 1
2-Fluorobiphenyl (S) 32 % 04/26/16 05:26 321-60-804/25/16 13:0015-120 1
Terphenyl-d14 (S) 86 % 04/26/16 05:26 1718-51-004/25/16 13:0011-131 1
Phenol-d6 (S) 14 % 04/26/16 05:26 13127-88-304/25/16 13:0010-120 1
2-Fluorophenol (S) 21 % 04/26/16 05:26 367-12-404/25/16 13:0010-120 1
2,4,6-Tribromophenol (S) 86 % 04/26/16 05:26 118-79-604/25/16 13:0010-137 1
Tentatively Identified Compounds
Ethylbenzene 55.4 ug/L 04/26/16 05:26 100-41-4 N04/25/16 13:001
o-Xylene 50.9 ug/L 04/26/16 05:26 95-47-6 N04/25/16 13:001
Benzene, 1-ethyl-3-methy 38.2 ug/L 04/26/16 05:26 620-14-4 N04/25/16 13:001
Benzene, 1,3,5-trimethyl 36.5 ug/L 04/26/16 05:26 108-67-8 N04/25/16 13:001
Benzene, 1,2,3-trimethyl 125 ug/L 04/26/16 05:26 526-73-8 N04/25/16 13:001
Benzene, 1-ethyl-2-methy 30.2 ug/L 04/26/16 05:26 611-14-3 N04/25/16 13:001
Indane 34.0 ug/L 04/26/16 05:26 496-11-7 N04/25/16 13:001
Benzene, 2-ethyl-1,4-dim 27.3 ug/L 04/26/16 05:26 1758-88-9 N04/25/16 13:001
Benzene, 4-ethyl-1,2-dim 27.9 ug/L 04/26/16 05:26 934-80-5 N04/25/16 13:001
Benzene, 2-ethenyl-1,4-d 20.4 ug/L 04/26/16 05:26 2039-89-6 N04/25/16 13:001
Analytical Method: SM 6200B6200B MSV
Benzene 10.0 ug/L 04/25/16 19:50 71-43-21.0 2
Bromobenzene ND ug/L 04/25/16 19:50 108-86-11.0 2
Bromochloromethane ND ug/L 04/25/16 19:50 74-97-51.0 2
Bromodichloromethane 21.5 ug/L 04/25/16 19:50 75-27-41.0 2
Bromoform 8.0 ug/L 04/25/16 19:50 75-25-21.0 2
Bromomethane ND ug/L 04/25/16 19:50 74-83-910.0 2
n-Butylbenzene 8.0 ug/L 04/25/16 19:50 104-51-81.0 2
sec-Butylbenzene 4.3 ug/L 04/25/16 19:50 135-98-81.0 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/06/2016 02:26 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 39
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92294881
FRIENDLY MART
Sample: MW 2 Lab ID: 92294881001 Collected: 04/20/16 18:55 Received: 04/21/16 16:09 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
tert-Butylbenzene ND ug/L 04/25/16 19:50 98-06-61.0 2
Carbon tetrachloride 23.7 ug/L 04/25/16 19:50 56-23-51.0 2
Chlorobenzene ND ug/L 04/25/16 19:50 108-90-71.0 2
Chloroethane ND ug/L 04/25/16 19:50 75-00-32.0 2
Chloroform 255 ug/L 04/25/16 19:50 67-66-31.0 2
Chloromethane ND ug/L 04/25/16 19:50 74-87-32.0 2
2-Chlorotoluene ND ug/L 04/25/16 19:50 95-49-81.0 2
4-Chlorotoluene ND ug/L 04/25/16 19:50 106-43-41.0 2
1,2-Dibromo-3-chloropropane ND ug/L 04/25/16 19:50 96-12-82.0 2
Dibromochloromethane 9.3 ug/L 04/25/16 19:50 124-48-11.0 2
1,2-Dibromoethane (EDB) ND ug/L 04/25/16 19:50 106-93-41.0 2
Dibromomethane ND ug/L 04/25/16 19:50 74-95-31.0 2
1,2-Dichlorobenzene ND ug/L 04/25/16 19:50 95-50-11.0 2
1,3-Dichlorobenzene ND ug/L 04/25/16 19:50 541-73-11.0 2
1,4-Dichlorobenzene ND ug/L 04/25/16 19:50 106-46-71.0 2
Dichlorodifluoromethane ND ug/L 04/25/16 19:50 75-71-81.0 2
1,1-Dichloroethane ND ug/L 04/25/16 19:50 75-34-31.0 2
1,2-Dichloroethane ND ug/L 04/25/16 19:50 107-06-21.0 2
1,1-Dichloroethene ND ug/L 04/25/16 19:50 75-35-41.0 2
cis-1,2-Dichloroethene ND ug/L 04/25/16 19:50 156-59-21.0 2
trans-1,2-Dichloroethene ND ug/L 04/25/16 19:50 156-60-51.0 2
1,2-Dichloropropane ND ug/L 04/25/16 19:50 78-87-51.0 2
1,3-Dichloropropane ND ug/L 04/25/16 19:50 142-28-91.0 2
2,2-Dichloropropane ND ug/L 04/25/16 19:50 594-20-71.0 2
1,1-Dichloropropene ND ug/L 04/25/16 19:50 563-58-61.0 2
cis-1,3-Dichloropropene ND ug/L 04/25/16 19:50 10061-01-51.0 2
trans-1,3-Dichloropropene ND ug/L 04/25/16 19:50 10061-02-61.0 2
Diisopropyl ether 1.3 ug/L 04/25/16 19:50 108-20-31.0 2
Ethylbenzene 155 ug/L 04/25/16 19:50 100-41-41.0 2
Hexachloro-1,3-butadiene ND ug/L 04/25/16 19:50 87-68-34.0 2
Isopropylbenzene (Cumene)18.0 ug/L 04/25/16 19:50 98-82-81.0 2
Methylene Chloride 8.6 ug/L 04/25/16 19:50 75-09-2 C94.0 2
Methyl-tert-butyl ether 18.2 ug/L 04/25/16 19:50 1634-04-41.0 2
Naphthalene 113 ug/L 04/25/16 19:50 91-20-34.0 2
n-Propylbenzene 55.9 ug/L 04/25/16 19:50 103-65-11.0 2
Styrene 1.1 ug/L 04/25/16 19:50 100-42-51.0 2
1,1,1,2-Tetrachloroethane ND ug/L 04/25/16 19:50 630-20-61.0 2
1,1,2,2-Tetrachloroethane ND ug/L 04/25/16 19:50 79-34-51.0 2
Tetrachloroethene 9.3 ug/L 04/25/16 19:50 127-18-41.0 2
Toluene 24.5 ug/L 04/25/16 19:50 108-88-31.0 2
1,2,3-Trichlorobenzene ND ug/L 04/25/16 19:50 87-61-64.0 2
1,2,4-Trichlorobenzene ND ug/L 04/25/16 19:50 120-82-14.0 2
1,1,1-Trichloroethane ND ug/L 04/25/16 19:50 71-55-61.0 2
1,1,2-Trichloroethane ND ug/L 04/25/16 19:50 79-00-51.0 2
Trichloroethene 1.6 ug/L 04/25/16 19:50 79-01-61.0 2
Trichlorofluoromethane ND ug/L 04/25/16 19:50 75-69-42.0 2
1,2,3-Trichloropropane ND ug/L 04/25/16 19:50 96-18-41.0 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/06/2016 02:26 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 39
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92294881
FRIENDLY MART
Sample: MW 2 Lab ID: 92294881001 Collected: 04/20/16 18:55 Received: 04/21/16 16:09 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
1,2,4-Trimethylbenzene 321 ug/L 04/25/16 19:50 95-63-61.0 2
1,3,5-Trimethylbenzene 98.5 ug/L 04/25/16 19:50 108-67-81.0 2
Vinyl chloride ND ug/L 04/25/16 19:50 75-01-42.0 2
m&p-Xylene 243 ug/L 04/25/16 19:50 179601-23-12.0 2
o-Xylene 137 ug/L 04/25/16 19:50 95-47-61.0 2
Surrogates
1,2-Dichloroethane-d4 (S) 102 % 04/25/16 19:50 17060-07-070-130 2
4-Bromofluorobenzene (S) 97 % 04/25/16 19:50 460-00-470-130 2
Toluene-d8 (S) 98 % 04/25/16 19:50 2037-26-570-130 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/06/2016 02:26 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 39
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92294881
FRIENDLY MART
Sample: MW 3 Lab ID: 92294881002 Collected: 04/20/16 19:10 Received: 04/21/16 16:09 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: MADEP EPH Preparation Method: MADEP EPHMADEP EPH NC Water
Aliphatic (C09-C18) ND ug/L 04/27/16 20:01 N204/22/16 14:32100 1
Aliphatic (C19-C36) ND ug/L 04/27/16 20:01 N204/22/16 14:32100 1
Aromatic (C11-C22)176 ug/L 04/27/16 20:01 N204/22/16 14:32100 1
Surrogates
Nonatriacontane (S) 76 % 04/27/16 20:01 7194-86-704/22/16 14:3240-140 1
o-Terphenyl (S) 77 % 04/27/16 20:01 84-15-104/22/16 14:3240-140 1
2-Fluorobiphenyl (S) 101 % 04/27/16 20:01 321-60-804/22/16 14:3240-140 1
2-Bromonaphthalene (S) 99 % 04/27/16 20:01 580-13-204/22/16 14:3240-140 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Lead ND ug/L 04/26/16 20:45 7439-92-104/25/16 17:405.0 1
Analytical Method: EPA 625 Preparation Method: EPA 625625 MSSV
Acenaphthene ND ug/L 04/26/16 05:54 83-32-904/25/16 13:005.0 1
Acenaphthylene ND ug/L 04/26/16 05:54 208-96-804/25/16 13:005.0 1
Anthracene ND ug/L 04/26/16 05:54 120-12-704/25/16 13:005.0 1
Benzo(a)anthracene ND ug/L 04/26/16 05:54 56-55-304/25/16 13:005.0 1
Benzo(a)pyrene ND ug/L 04/26/16 05:54 50-32-804/25/16 13:005.0 1
Benzo(b)fluoranthene ND ug/L 04/26/16 05:54 205-99-204/25/16 13:005.0 1
Benzo(g,h,i)perylene ND ug/L 04/26/16 05:54 191-24-204/25/16 13:005.0 1
Benzo(k)fluoranthene ND ug/L 04/26/16 05:54 207-08-904/25/16 13:005.0 1
4-Bromophenylphenyl ether ND ug/L 04/26/16 05:54 101-55-304/25/16 13:005.0 1
Butylbenzylphthalate ND ug/L 04/26/16 05:54 85-68-704/25/16 13:005.0 1
4-Chloro-3-methylphenol ND ug/L 04/26/16 05:54 59-50-704/25/16 13:005.0 1
bis(2-Chloroethoxy)methane ND ug/L 04/26/16 05:54 111-91-104/25/16 13:0010.0 1
bis(2-Chloroethyl) ether ND ug/L 04/26/16 05:54 111-44-404/25/16 13:005.0 1
bis(2-Chloroisopropyl) ether ND ug/L 04/26/16 05:54 108-60-104/25/16 13:005.0 1
2-Chloronaphthalene ND ug/L 04/26/16 05:54 91-58-704/25/16 13:005.0 1
2-Chlorophenol ND ug/L 04/26/16 05:54 95-57-804/25/16 13:005.0 1
4-Chlorophenylphenyl ether ND ug/L 04/26/16 05:54 7005-72-304/25/16 13:005.0 1
Chrysene ND ug/L 04/26/16 05:54 218-01-904/25/16 13:005.0 1
Dibenz(a,h)anthracene ND ug/L 04/26/16 05:54 53-70-304/25/16 13:005.0 1
3,3'-Dichlorobenzidine ND ug/L 04/26/16 05:54 91-94-104/25/16 13:0025.0 1
2,4-Dichlorophenol ND ug/L 04/26/16 05:54 120-83-204/25/16 13:005.0 1
Diethylphthalate ND ug/L 04/26/16 05:54 84-66-204/25/16 13:005.0 1
2,4-Dimethylphenol ND ug/L 04/26/16 05:54 105-67-904/25/16 13:0010.0 1
Dimethylphthalate ND ug/L 04/26/16 05:54 131-11-304/25/16 13:005.0 1
Di-n-butylphthalate ND ug/L 04/26/16 05:54 84-74-204/25/16 13:005.0 1
4,6-Dinitro-2-methylphenol ND ug/L 04/26/16 05:54 534-52-104/25/16 13:0020.0 1
2,4-Dinitrophenol ND ug/L 04/26/16 05:54 51-28-504/25/16 13:0050.0 1
2,4-Dinitrotoluene ND ug/L 04/26/16 05:54 121-14-204/25/16 13:005.0 1
2,6-Dinitrotoluene ND ug/L 04/26/16 05:54 606-20-204/25/16 13:005.0 1
Di-n-octylphthalate ND ug/L 04/26/16 05:54 117-84-0 L304/25/16 13:005.0 1
bis(2-Ethylhexyl)phthalate ND ug/L 04/26/16 05:54 117-81-704/25/16 13:005.0 1
Fluoranthene ND ug/L 04/26/16 05:54 206-44-004/25/16 13:005.0 1
Fluorene ND ug/L 04/26/16 05:54 86-73-704/25/16 13:005.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/06/2016 02:26 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 39
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92294881
FRIENDLY MART
Sample: MW 3 Lab ID: 92294881002 Collected: 04/20/16 19:10 Received: 04/21/16 16:09 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 625 Preparation Method: EPA 625625 MSSV
Hexachloro-1,3-butadiene ND ug/L 04/26/16 05:54 87-68-304/25/16 13:005.0 1
Hexachlorobenzene ND ug/L 04/26/16 05:54 118-74-104/25/16 13:005.0 1
Hexachlorocyclopentadiene ND ug/L 04/26/16 05:54 77-47-404/25/16 13:0010.0 1
Hexachloroethane ND ug/L 04/26/16 05:54 67-72-104/25/16 13:005.0 1
Indeno(1,2,3-cd)pyrene ND ug/L 04/26/16 05:54 193-39-504/25/16 13:005.0 1
Isophorone ND ug/L 04/26/16 05:54 78-59-104/25/16 13:0010.0 1
Naphthalene 9.4 ug/L 04/26/16 05:54 91-20-304/25/16 13:005.0 1
Nitrobenzene ND ug/L 04/26/16 05:54 98-95-304/25/16 13:005.0 1
2-Nitrophenol ND ug/L 04/26/16 05:54 88-75-504/25/16 13:005.0 1
4-Nitrophenol ND ug/L 04/26/16 05:54 100-02-704/25/16 13:0050.0 1
N-Nitrosodimethylamine ND ug/L 04/26/16 05:54 62-75-904/25/16 13:005.0 1
N-Nitroso-di-n-propylamine ND ug/L 04/26/16 05:54 621-64-704/25/16 13:005.0 1
N-Nitrosodiphenylamine ND ug/L 04/26/16 05:54 86-30-604/25/16 13:0010.0 1
Pentachlorophenol ND ug/L 04/26/16 05:54 87-86-504/25/16 13:0010.0 1
Phenanthrene ND ug/L 04/26/16 05:54 85-01-804/25/16 13:005.0 1
Phenol ND ug/L 04/26/16 05:5404/25/16 13:005.0 1
Pyrene ND ug/L 04/26/16 05:54 129-00-004/25/16 13:005.0 1
1,2,4-Trichlorobenzene ND ug/L 04/26/16 05:54 120-82-104/25/16 13:005.0 1
2,4,6-Trichlorophenol ND ug/L 04/26/16 05:54 88-06-204/25/16 13:0010.0 1
Surrogates
Nitrobenzene-d5 (S) 65 % 04/26/16 05:54 4165-60-004/25/16 13:0010-120 1
2-Fluorobiphenyl (S) 71 % 04/26/16 05:54 321-60-804/25/16 13:0015-120 1
Terphenyl-d14 (S) 83 % 04/26/16 05:54 1718-51-004/25/16 13:0011-131 1
Phenol-d6 (S) 28 % 04/26/16 05:54 13127-88-304/25/16 13:0010-120 1
2-Fluorophenol (S) 40 % 04/26/16 05:54 367-12-404/25/16 13:0010-120 1
2,4,6-Tribromophenol (S) 100 % 04/26/16 05:54 118-79-604/25/16 13:0010-137 1
Tentatively Identified Compounds
Unknown 135 ug/L 04/26/16 05:54 N04/25/16 13:001
Unknown 78.7 ug/L 04/26/16 05:54 N04/25/16 13:001
o-Tolylacetic acid 16.8 ug/L 04/26/16 05:54 644-36-0 N04/25/16 13:001
Unknown 27.1 ug/L 04/26/16 05:54 N04/25/16 13:001
Unknown 27.7 ug/L 04/26/16 05:54 N04/25/16 13:001
4-Isopropylphenylacetic 35.1 ug/L 04/26/16 05:54 4476-28-2 N04/25/16 13:001
Unknown 20.5 ug/L 04/26/16 05:54 N04/25/16 13:001
Unknown 14.2 ug/L 04/26/16 05:54 N04/25/16 13:001
2-Naphthylpropionic aci 179 ug/L 04/26/16 05:54 1000129-24- N04/25/16 13:001
Octadecanoic acid 47.8 ug/L 04/26/16 05:54 57-11-4 N04/25/16 13:001
Analytical Method: SM 6200B6200B MSV
Benzene 202 ug/L 04/25/16 20:07 71-43-22.5 5
Bromobenzene ND ug/L 04/25/16 20:07 108-86-12.5 5
Bromochloromethane ND ug/L 04/25/16 20:07 74-97-52.5 5
Bromodichloromethane ND ug/L 04/25/16 20:07 75-27-42.5 5
Bromoform ND ug/L 04/25/16 20:07 75-25-22.5 5
Bromomethane ND ug/L 04/25/16 20:07 74-83-925.0 5
n-Butylbenzene ND ug/L 04/25/16 20:07 104-51-82.5 5
sec-Butylbenzene 2.7 ug/L 04/25/16 20:07 135-98-82.5 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/06/2016 02:26 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 39
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92294881
FRIENDLY MART
Sample: MW 3 Lab ID: 92294881002 Collected: 04/20/16 19:10 Received: 04/21/16 16:09 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
tert-Butylbenzene ND ug/L 04/25/16 20:07 98-06-62.5 5
Carbon tetrachloride ND ug/L 04/25/16 20:07 56-23-52.5 5
Chlorobenzene ND ug/L 04/25/16 20:07 108-90-72.5 5
Chloroethane ND ug/L 04/25/16 20:07 75-00-35.0 5
Chloroform 48.3 ug/L 04/25/16 20:07 67-66-32.5 5
Chloromethane ND ug/L 04/25/16 20:07 74-87-35.0 5
2-Chlorotoluene ND ug/L 04/25/16 20:07 95-49-82.5 5
4-Chlorotoluene ND ug/L 04/25/16 20:07 106-43-42.5 5
1,2-Dibromo-3-chloropropane ND ug/L 04/25/16 20:07 96-12-85.0 5
Dibromochloromethane ND ug/L 04/25/16 20:07 124-48-12.5 5
1,2-Dibromoethane (EDB) ND ug/L 04/25/16 20:07 106-93-42.5 5
Dibromomethane ND ug/L 04/25/16 20:07 74-95-32.5 5
1,2-Dichlorobenzene ND ug/L 04/25/16 20:07 95-50-12.5 5
1,3-Dichlorobenzene ND ug/L 04/25/16 20:07 541-73-12.5 5
1,4-Dichlorobenzene ND ug/L 04/25/16 20:07 106-46-72.5 5
Dichlorodifluoromethane ND ug/L 04/25/16 20:07 75-71-82.5 5
1,1-Dichloroethane ND ug/L 04/25/16 20:07 75-34-32.5 5
1,2-Dichloroethane ND ug/L 04/25/16 20:07 107-06-22.5 5
1,1-Dichloroethene ND ug/L 04/25/16 20:07 75-35-42.5 5
cis-1,2-Dichloroethene ND ug/L 04/25/16 20:07 156-59-22.5 5
trans-1,2-Dichloroethene ND ug/L 04/25/16 20:07 156-60-52.5 5
1,2-Dichloropropane ND ug/L 04/25/16 20:07 78-87-52.5 5
1,3-Dichloropropane ND ug/L 04/25/16 20:07 142-28-92.5 5
2,2-Dichloropropane ND ug/L 04/25/16 20:07 594-20-72.5 5
1,1-Dichloropropene ND ug/L 04/25/16 20:07 563-58-62.5 5
cis-1,3-Dichloropropene ND ug/L 04/25/16 20:07 10061-01-52.5 5
trans-1,3-Dichloropropene ND ug/L 04/25/16 20:07 10061-02-62.5 5
Diisopropyl ether 9.4 ug/L 04/25/16 20:07 108-20-32.5 5
Ethylbenzene 6.6 ug/L 04/25/16 20:07 100-41-42.5 5
Hexachloro-1,3-butadiene ND ug/L 04/25/16 20:07 87-68-310.0 5
Isopropylbenzene (Cumene)4.3 ug/L 04/25/16 20:07 98-82-82.5 5
Methylene Chloride 16.8 ug/L 04/25/16 20:07 75-09-2 C910.0 5
Methyl-tert-butyl ether 970 ug/L 04/25/16 20:07 1634-04-42.5 5
Naphthalene 42.8 ug/L 04/25/16 20:07 91-20-310.0 5
n-Propylbenzene ND ug/L 04/25/16 20:07 103-65-12.5 5
Styrene ND ug/L 04/25/16 20:07 100-42-52.5 5
1,1,1,2-Tetrachloroethane ND ug/L 04/25/16 20:07 630-20-62.5 5
1,1,2,2-Tetrachloroethane ND ug/L 04/25/16 20:07 79-34-52.5 5
Tetrachloroethene ND ug/L 04/25/16 20:07 127-18-42.5 5
Toluene ND ug/L 04/25/16 20:07 108-88-32.5 5
1,2,3-Trichlorobenzene ND ug/L 04/25/16 20:07 87-61-610.0 5
1,2,4-Trichlorobenzene ND ug/L 04/25/16 20:07 120-82-110.0 5
1,1,1-Trichloroethane ND ug/L 04/25/16 20:07 71-55-62.5 5
1,1,2-Trichloroethane ND ug/L 04/25/16 20:07 79-00-52.5 5
Trichloroethene ND ug/L 04/25/16 20:07 79-01-62.5 5
Trichlorofluoromethane ND ug/L 04/25/16 20:07 75-69-45.0 5
1,2,3-Trichloropropane ND ug/L 04/25/16 20:07 96-18-42.5 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/06/2016 02:26 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 39
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92294881
FRIENDLY MART
Sample: MW 3 Lab ID: 92294881002 Collected: 04/20/16 19:10 Received: 04/21/16 16:09 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
1,2,4-Trimethylbenzene 33.6 ug/L 04/25/16 20:07 95-63-62.5 5
1,3,5-Trimethylbenzene 7.8 ug/L 04/25/16 20:07 108-67-82.5 5
Vinyl chloride ND ug/L 04/25/16 20:07 75-01-45.0 5
m&p-Xylene 6.2 ug/L 04/25/16 20:07 179601-23-15.0 5
o-Xylene 12.8 ug/L 04/25/16 20:07 95-47-62.5 5
Surrogates
1,2-Dichloroethane-d4 (S) 101 % 04/25/16 20:07 17060-07-070-130 5
4-Bromofluorobenzene (S) 100 % 04/25/16 20:07 460-00-470-130 5
Toluene-d8 (S) 100 % 04/25/16 20:07 2037-26-570-130 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/06/2016 02:26 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 39
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92294881
FRIENDLY MART
Sample: MW 4 Lab ID: 92294881003 Collected: 04/20/16 19:30 Received: 04/21/16 16:09 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: MADEP EPH Preparation Method: MADEP EPHMADEP EPH NC Water
Aliphatic (C09-C18)880 ug/L 04/27/16 20:29 N204/22/16 14:32100 1
Aliphatic (C19-C36) ND ug/L 04/27/16 20:29 N204/22/16 14:32100 1
Aromatic (C11-C22)774 ug/L 04/27/16 20:29 N204/22/16 14:32100 1
Surrogates
Nonatriacontane (S) 58 % 04/27/16 20:29 7194-86-704/22/16 14:3240-140 1
o-Terphenyl (S) 60 % 04/27/16 20:29 84-15-104/22/16 14:3240-140 1
2-Fluorobiphenyl (S) 95 % 04/27/16 20:29 321-60-804/22/16 14:3240-140 1
2-Bromonaphthalene (S) 79 % 04/27/16 20:29 580-13-204/22/16 14:3240-140 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Lead ND ug/L 04/26/16 20:49 7439-92-104/25/16 17:405.0 1
Analytical Method: EPA 625 Preparation Method: EPA 625625 MSSV
Acenaphthene ND ug/L 04/26/16 06:21 83-32-904/25/16 13:005.0 1
Acenaphthylene ND ug/L 04/26/16 06:21 208-96-804/25/16 13:005.0 1
Anthracene ND ug/L 04/26/16 06:21 120-12-704/25/16 13:005.0 1
Benzo(a)anthracene ND ug/L 04/26/16 06:21 56-55-304/25/16 13:005.0 1
Benzo(a)pyrene ND ug/L 04/26/16 06:21 50-32-804/25/16 13:005.0 1
Benzo(b)fluoranthene ND ug/L 04/26/16 06:21 205-99-204/25/16 13:005.0 1
Benzo(g,h,i)perylene ND ug/L 04/26/16 06:21 191-24-204/25/16 13:005.0 1
Benzo(k)fluoranthene ND ug/L 04/26/16 06:21 207-08-904/25/16 13:005.0 1
4-Bromophenylphenyl ether ND ug/L 04/26/16 06:21 101-55-304/25/16 13:005.0 1
Butylbenzylphthalate ND ug/L 04/26/16 06:21 85-68-704/25/16 13:005.0 1
4-Chloro-3-methylphenol ND ug/L 04/26/16 06:21 59-50-704/25/16 13:005.0 1
bis(2-Chloroethoxy)methane ND ug/L 04/26/16 06:21 111-91-104/25/16 13:0010.0 1
bis(2-Chloroethyl) ether ND ug/L 04/26/16 06:21 111-44-404/25/16 13:005.0 1
bis(2-Chloroisopropyl) ether ND ug/L 04/26/16 06:21 108-60-104/25/16 13:005.0 1
2-Chloronaphthalene ND ug/L 04/26/16 06:21 91-58-704/25/16 13:005.0 1
2-Chlorophenol ND ug/L 04/26/16 06:21 95-57-804/25/16 13:005.0 1
4-Chlorophenylphenyl ether ND ug/L 04/26/16 06:21 7005-72-304/25/16 13:005.0 1
Chrysene ND ug/L 04/26/16 06:21 218-01-904/25/16 13:005.0 1
Dibenz(a,h)anthracene ND ug/L 04/26/16 06:21 53-70-304/25/16 13:005.0 1
3,3'-Dichlorobenzidine ND ug/L 04/26/16 06:21 91-94-104/25/16 13:0025.0 1
2,4-Dichlorophenol ND ug/L 04/26/16 06:21 120-83-204/25/16 13:005.0 1
Diethylphthalate ND ug/L 04/26/16 06:21 84-66-204/25/16 13:005.0 1
2,4-Dimethylphenol ND ug/L 04/26/16 06:21 105-67-904/25/16 13:0010.0 1
Dimethylphthalate ND ug/L 04/26/16 06:21 131-11-304/25/16 13:005.0 1
Di-n-butylphthalate ND ug/L 04/26/16 06:21 84-74-204/25/16 13:005.0 1
4,6-Dinitro-2-methylphenol ND ug/L 04/26/16 06:21 534-52-104/25/16 13:0020.0 1
2,4-Dinitrophenol ND ug/L 04/26/16 06:21 51-28-504/25/16 13:0050.0 1
2,4-Dinitrotoluene ND ug/L 04/26/16 06:21 121-14-204/25/16 13:005.0 1
2,6-Dinitrotoluene ND ug/L 04/26/16 06:21 606-20-204/25/16 13:005.0 1
Di-n-octylphthalate ND ug/L 04/26/16 06:21 117-84-0 L304/25/16 13:005.0 1
bis(2-Ethylhexyl)phthalate ND ug/L 04/26/16 06:21 117-81-704/25/16 13:005.0 1
Fluoranthene ND ug/L 04/26/16 06:21 206-44-004/25/16 13:005.0 1
Fluorene ND ug/L 04/26/16 06:21 86-73-704/25/16 13:005.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/06/2016 02:26 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 39
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92294881
FRIENDLY MART
Sample: MW 4 Lab ID: 92294881003 Collected: 04/20/16 19:30 Received: 04/21/16 16:09 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 625 Preparation Method: EPA 625625 MSSV
Hexachloro-1,3-butadiene ND ug/L 04/26/16 06:21 87-68-304/25/16 13:005.0 1
Hexachlorobenzene ND ug/L 04/26/16 06:21 118-74-104/25/16 13:005.0 1
Hexachlorocyclopentadiene ND ug/L 04/26/16 06:21 77-47-404/25/16 13:0010.0 1
Hexachloroethane ND ug/L 04/26/16 06:21 67-72-104/25/16 13:005.0 1
Indeno(1,2,3-cd)pyrene ND ug/L 04/26/16 06:21 193-39-504/25/16 13:005.0 1
Isophorone ND ug/L 04/26/16 06:21 78-59-104/25/16 13:0010.0 1
Naphthalene 196 ug/L 04/26/16 09:40 91-20-304/25/16 13:0010.0 2
Nitrobenzene ND ug/L 04/26/16 06:21 98-95-304/25/16 13:005.0 1
2-Nitrophenol ND ug/L 04/26/16 06:21 88-75-504/25/16 13:005.0 1
4-Nitrophenol ND ug/L 04/26/16 06:21 100-02-704/25/16 13:0050.0 1
N-Nitrosodimethylamine ND ug/L 04/26/16 06:21 62-75-904/25/16 13:005.0 1
N-Nitroso-di-n-propylamine ND ug/L 04/26/16 06:21 621-64-704/25/16 13:005.0 1
N-Nitrosodiphenylamine ND ug/L 04/26/16 06:21 86-30-604/25/16 13:0010.0 1
Pentachlorophenol ND ug/L 04/26/16 06:21 87-86-504/25/16 13:0010.0 1
Phenanthrene ND ug/L 04/26/16 06:21 85-01-804/25/16 13:005.0 1
Phenol ND ug/L 04/26/16 06:2104/25/16 13:005.0 1
Pyrene ND ug/L 04/26/16 06:21 129-00-004/25/16 13:005.0 1
1,2,4-Trichlorobenzene ND ug/L 04/26/16 06:21 120-82-104/25/16 13:005.0 1
2,4,6-Trichlorophenol ND ug/L 04/26/16 06:21 88-06-204/25/16 13:0010.0 1
Surrogates
Nitrobenzene-d5 (S) 79 % 04/26/16 06:21 4165-60-004/25/16 13:0010-120 1
2-Fluorobiphenyl (S) 82 % 04/26/16 06:21 321-60-804/25/16 13:0015-120 1
Terphenyl-d14 (S) 88 % 04/26/16 06:21 1718-51-004/25/16 13:0011-131 1
Phenol-d6 (S) 32 % 04/26/16 06:21 13127-88-304/25/16 13:0010-120 1
2-Fluorophenol (S) 49 % 04/26/16 06:21 367-12-404/25/16 13:0010-120 1
2,4,6-Tribromophenol (S) 107 % 04/26/16 06:21 118-79-604/25/16 13:0010-137 1
Tentatively Identified Compounds
3-Pentanol, 3-methyl-350 ug/L 04/26/16 06:21 77-74-7 N04/25/16 13:001
Toluene 801 ug/L 04/26/16 06:21 108-88-3 N04/25/16 13:001
Cyclopentanol, 1-methyl-243 ug/L 04/26/16 06:21 1462-03-9 N04/25/16 13:001
Unknown 410 ug/L 04/26/16 06:21 N04/25/16 13:001
Ethylbenzene 838 ug/L 04/26/16 06:21 100-41-4 N04/25/16 13:001
Benzene, 1,3-dimethyl-517 ug/L 04/26/16 06:21 108-38-3 N04/25/16 13:001
1,3-Cyclopentadiene, 5-(311 ug/L 04/26/16 06:21 3141-02-4 N04/25/16 13:001
Benzene, 1,2,3-trimethyl 184 ug/L 04/26/16 06:21 526-73-8 N04/25/16 13:001
1,2,4-Trimethylbenzene 616 ug/L 04/26/16 06:21 95-36-3 N04/25/16 13:001
Indane 228 ug/L 04/26/16 06:21 496-11-7 N04/25/16 13:001
Analytical Method: SM 6200B6200B MSV
Benzene 3830 ug/L 04/25/16 20:24 71-43-220.0 40
Bromobenzene ND ug/L 04/25/16 20:24 108-86-120.0 40
Bromochloromethane ND ug/L 04/25/16 20:24 74-97-520.0 40
Bromodichloromethane ND ug/L 04/25/16 20:24 75-27-420.0 40
Bromoform ND ug/L 04/25/16 20:24 75-25-220.0 40
Bromomethane ND ug/L 04/25/16 20:24 74-83-9200 40
n-Butylbenzene ND ug/L 04/25/16 20:24 104-51-820.0 40
sec-Butylbenzene ND ug/L 04/25/16 20:24 135-98-820.0 40
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/06/2016 02:26 PM
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[phone]
Page 16 of 39
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92294881
FRIENDLY MART
Sample: MW 4 Lab ID: 92294881003 Collected: 04/20/16 19:30 Received: 04/21/16 16:09 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
tert-Butylbenzene ND ug/L 04/25/16 20:24 98-06-620.0 40
Carbon tetrachloride ND ug/L 04/25/16 20:24 56-23-520.0 40
Chlorobenzene ND ug/L 04/25/16 20:24 108-90-720.0 40
Chloroethane ND ug/L 04/25/16 20:24 75-00-340.0 40
Chloroform ND ug/L 04/25/16 20:24 67-66-320.0 40
Chloromethane ND ug/L 04/25/16 20:24 74-87-340.0 40
2-Chlorotoluene ND ug/L 04/25/16 20:24 95-49-820.0 40
4-Chlorotoluene ND ug/L 04/25/16 20:24 106-43-420.0 40
1,2-Dibromo-3-chloropropane ND ug/L 04/25/16 20:24 96-12-840.0 40
Dibromochloromethane ND ug/L 04/25/16 20:24 124-48-120.0 40
1,2-Dibromoethane (EDB) ND ug/L 04/25/16 20:24 106-93-420.0 40
Dibromomethane ND ug/L 04/25/16 20:24 74-95-320.0 40
1,2-Dichlorobenzene ND ug/L 04/25/16 20:24 95-50-120.0 40
1,3-Dichlorobenzene ND ug/L 04/25/16 20:24 541-73-120.0 40
1,4-Dichlorobenzene ND ug/L 04/25/16 20:24 106-46-720.0 40
Dichlorodifluoromethane ND ug/L 04/25/16 20:24 75-71-820.0 40
1,1-Dichloroethane ND ug/L 04/25/16 20:24 75-34-320.0 40
1,2-Dichloroethane ND ug/L 04/25/16 20:24 107-06-220.0 40
1,1-Dichloroethene ND ug/L 04/25/16 20:24 75-35-420.0 40
cis-1,2-Dichloroethene ND ug/L 04/25/16 20:24 156-59-220.0 40
trans-1,2-Dichloroethene ND ug/L 04/25/16 20:24 156-60-520.0 40
1,2-Dichloropropane ND ug/L 04/25/16 20:24 78-87-520.0 40
1,3-Dichloropropane ND ug/L 04/25/16 20:24 142-28-920.0 40
2,2-Dichloropropane ND ug/L 04/25/16 20:24 594-20-720.0 40
1,1-Dichloropropene ND ug/L 04/25/16 20:24 563-58-620.0 40
cis-1,3-Dichloropropene ND ug/L 04/25/16 20:24 10061-01-520.0 40
trans-1,3-Dichloropropene ND ug/L 04/25/16 20:24 10061-02-620.0 40
Diisopropyl ether 287 ug/L 04/25/16 20:24 108-20-320.0 40
Ethylbenzene 973 ug/L 04/25/16 20:24 100-41-420.0 40
Hexachloro-1,3-butadiene ND ug/L 04/25/16 20:24 87-68-380.0 40
Isopropylbenzene (Cumene)99.7 ug/L 04/25/16 20:24 98-82-820.0 40
Methylene Chloride 131 ug/L 04/25/16 20:24 75-09-2 C980.0 40
Methyl-tert-butyl ether 6540 ug/L 04/25/16 20:24 1634-04-420.0 40
Naphthalene 369 ug/L 04/25/16 20:24 91-20-380.0 40
n-Propylbenzene 158 ug/L 04/25/16 20:24 103-65-120.0 40
Styrene ND ug/L 04/25/16 20:24 100-42-520.0 40
1,1,1,2-Tetrachloroethane ND ug/L 04/25/16 20:24 630-20-620.0 40
1,1,2,2-Tetrachloroethane ND ug/L 04/25/16 20:24 79-34-520.0 40
Tetrachloroethene ND ug/L 04/25/16 20:24 127-18-420.0 40
Toluene 1480 ug/L 04/25/16 20:24 108-88-320.0 40
1,2,3-Trichlorobenzene ND ug/L 04/25/16 20:24 87-61-680.0 40
1,2,4-Trichlorobenzene ND ug/L 04/25/16 20:24 120-82-180.0 40
1,1,1-Trichloroethane ND ug/L 04/25/16 20:24 71-55-620.0 40
1,1,2-Trichloroethane ND ug/L 04/25/16 20:24 79-00-520.0 40
Trichloroethene ND ug/L 04/25/16 20:24 79-01-620.0 40
Trichlorofluoromethane ND ug/L 04/25/16 20:24 75-69-440.0 40
1,2,3-Trichloropropane ND ug/L 04/25/16 20:24 96-18-420.0 40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/06/2016 02:26 PM
Pace Analytical Services, Inc.
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Huntersville, NC 28078
[phone]
Page 17 of 39
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92294881
FRIENDLY MART
Sample: MW 4 Lab ID: 92294881003 Collected: 04/20/16 19:30 Received: 04/21/16 16:09 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
1,2,4-Trimethylbenzene 1030 ug/L 04/25/16 20:24 95-63-620.0 40
1,3,5-Trimethylbenzene 259 ug/L 04/25/16 20:24 108-67-820.0 40
Vinyl chloride ND ug/L 04/25/16 20:24 75-01-440.0 40
m&p-Xylene 2190 ug/L 04/25/16 20:24 179601-23-140.0 40
o-Xylene 625 ug/L 04/25/16 20:24 95-47-620.0 40
Surrogates
1,2-Dichloroethane-d4 (S) 100 % 04/25/16 20:24 17060-07-070-130 40
4-Bromofluorobenzene (S) 100 % 04/25/16 20:24 460-00-470-130 40
Toluene-d8 (S) 101 % 04/25/16 20:24 2037-26-570-130 40
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/06/2016 02:26 PM
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Huntersville, NC 28078
[phone]
Page 18 of 39
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92294881
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/21489
EPA 3010A
EPA 6010
6010 MET
Associated Lab Samples: 92294881001, 92294881002, 92294881003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1718352
Associated Lab Samples:92294881001, 92294881002, 92294881003
Matrix: Water
Analyzed
Lead ug/L ND 5.0 04/26/16 20:18
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1718353LABORATORY CONTROL SAMPLE:
LCSSpike
Lead ug/L 478500 96 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1718354MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92294667002
1718355
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Lead ug/L 500 84 75-12591 7 20500ND 424 456
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/06/2016 02:26 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 39
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92294881
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/36535
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples: 92294881001, 92294881002, 92294881003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1717843
Associated Lab Samples:92294881001, 92294881002, 92294881003
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 04/25/16 12:26
1,1,1-Trichloroethane ug/L ND 0.50 04/25/16 12:26
1,1,2,2-Tetrachloroethane ug/L ND 0.50 04/25/16 12:26
1,1,2-Trichloroethane ug/L ND 0.50 04/25/16 12:26
1,1-Dichloroethane ug/L ND 0.50 04/25/16 12:26
1,1-Dichloroethene ug/L ND 0.50 04/25/16 12:26
1,1-Dichloropropene ug/L ND 0.50 04/25/16 12:26
1,2,3-Trichlorobenzene ug/L ND 2.0 04/25/16 12:26
1,2,3-Trichloropropane ug/L ND 0.50 04/25/16 12:26
1,2,4-Trichlorobenzene ug/L ND 2.0 04/25/16 12:26
1,2,4-Trimethylbenzene ug/L ND 0.50 04/25/16 12:26
1,2-Dibromo-3-chloropropane ug/L ND 1.0 04/25/16 12:26
1,2-Dibromoethane (EDB) ug/L ND 0.50 04/25/16 12:26
1,2-Dichlorobenzene ug/L ND 0.50 04/25/16 12:26
1,2-Dichloroethane ug/L ND 0.50 04/25/16 12:26
1,2-Dichloropropane ug/L ND 0.50 04/25/16 12:26
1,3,5-Trimethylbenzene ug/L ND 0.50 04/25/16 12:26
1,3-Dichlorobenzene ug/L ND 0.50 04/25/16 12:26
1,3-Dichloropropane ug/L ND 0.50 04/25/16 12:26
1,4-Dichlorobenzene ug/L ND 0.50 04/25/16 12:26
2,2-Dichloropropane ug/L ND 0.50 04/25/16 12:26
2-Chlorotoluene ug/L ND 0.50 04/25/16 12:26
4-Chlorotoluene ug/L ND 0.50 04/25/16 12:26
Benzene ug/L ND 0.50 04/25/16 12:26
Bromobenzene ug/L ND 0.50 04/25/16 12:26
Bromochloromethane ug/L ND 0.50 04/25/16 12:26
Bromodichloromethane ug/L ND 0.50 04/25/16 12:26
Bromoform ug/L ND 0.50 04/25/16 12:26
Bromomethane ug/L ND 5.0 04/25/16 12:26
Carbon tetrachloride ug/L ND 0.50 04/25/16 12:26
Chlorobenzene ug/L ND 0.50 04/25/16 12:26
Chloroethane ug/L ND 1.0 04/25/16 12:26
Chloroform ug/L ND 0.50 04/25/16 12:26
Chloromethane ug/L ND 1.0 04/25/16 12:26
cis-1,2-Dichloroethene ug/L ND 0.50 04/25/16 12:26
cis-1,3-Dichloropropene ug/L ND 0.50 04/25/16 12:26
Dibromochloromethane ug/L ND 0.50 04/25/16 12:26
Dibromomethane ug/L ND 0.50 04/25/16 12:26
Dichlorodifluoromethane ug/L ND 0.50 04/25/16 12:26
Diisopropyl ether ug/L ND 0.50 04/25/16 12:26
Ethylbenzene ug/L ND 0.50 04/25/16 12:26
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/06/2016 02:26 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 39
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92294881
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1717843
Associated Lab Samples:92294881001, 92294881002, 92294881003
Matrix: Water
Analyzed
Hexachloro-1,3-butadiene ug/L ND 2.0 04/25/16 12:26
Isopropylbenzene (Cumene) ug/L ND 0.50 04/25/16 12:26
m&p-Xylene ug/L ND 1.0 04/25/16 12:26
Methyl-tert-butyl ether ug/L ND 0.50 04/25/16 12:26
Methylene Chloride ug/L ND 2.0 04/25/16 12:26
n-Butylbenzene ug/L ND 0.50 04/25/16 12:26
n-Propylbenzene ug/L ND 0.50 04/25/16 12:26
Naphthalene ug/L ND 2.0 04/25/16 12:26
o-Xylene ug/L ND 0.50 04/25/16 12:26
sec-Butylbenzene ug/L ND 0.50 04/25/16 12:26
Styrene ug/L ND 0.50 04/25/16 12:26
tert-Butylbenzene ug/L ND 0.50 04/25/16 12:26
Tetrachloroethene ug/L ND 0.50 04/25/16 12:26
Toluene ug/L ND 0.50 04/25/16 12:26
trans-1,2-Dichloroethene ug/L ND 0.50 04/25/16 12:26
trans-1,3-Dichloropropene ug/L ND 0.50 04/25/16 12:26
Trichloroethene ug/L ND 0.50 04/25/16 12:26
Trichlorofluoromethane ug/L ND 1.0 04/25/16 12:26
Vinyl chloride ug/L ND 1.0 04/25/16 12:26
1,2-Dichloroethane-d4 (S) % 102 70-130 04/25/16 12:26
4-Bromofluorobenzene (S) % 100 70-130 04/25/16 12:26
Toluene-d8 (S) % 101 70-130 04/25/16 12:26
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1717844LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.550 101 60-140
1,1,1-Trichloroethane ug/L 52.550 105 60-140
1,1,2,2-Tetrachloroethane ug/L 50.250 100 60-140
1,1,2-Trichloroethane ug/L 51.550 103 60-140
1,1-Dichloroethane ug/L 51.450 103 60-140
1,1-Dichloroethene ug/L 52.950 106 60-140
1,1-Dichloropropene ug/L 51.650 103 60-140
1,2,3-Trichlorobenzene ug/L 54.150 108 60-140
1,2,3-Trichloropropane ug/L 51.750 103 60-140
1,2,4-Trichlorobenzene ug/L 51.050 102 60-140
1,2,4-Trimethylbenzene ug/L 49.850 100 60-140
1,2-Dibromo-3-chloropropane ug/L 50.950 102 60-140
1,2-Dibromoethane (EDB) ug/L 53.250 106 60-140
1,2-Dichlorobenzene ug/L 50.650 101 60-140
1,2-Dichloroethane ug/L 46.350 93 60-140
1,2-Dichloropropane ug/L 52.450 105 60-140
1,3,5-Trimethylbenzene ug/L 50.150 100 60-140
1,3-Dichlorobenzene ug/L 52.350 105 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/06/2016 02:26 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 39
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92294881
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1717844LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichloropropane ug/L 49.550 99 60-140
1,4-Dichlorobenzene ug/L 49.150 98 60-140
2,2-Dichloropropane ug/L 55.950 112 60-140
2-Chlorotoluene ug/L 50.650 101 60-140
4-Chlorotoluene ug/L 49.250 98 60-140
Benzene ug/L 50.750 101 60-140
Bromobenzene ug/L 48.750 97 60-140
Bromochloromethane ug/L 54.350 109 60-140
Bromodichloromethane ug/L 53.150 106 60-140
Bromoform ug/L 51.050 102 60-140
Bromomethane ug/L 53.750 107 60-140
Carbon tetrachloride ug/L 52.950 106 60-140
Chlorobenzene ug/L 48.650 97 60-140
Chloroethane ug/L 51.850 104 60-140
Chloroform ug/L 51.350 103 60-140
Chloromethane ug/L 48.150 96 60-140
cis-1,2-Dichloroethene ug/L 51.450 103 60-140
cis-1,3-Dichloropropene ug/L 53.550 107 60-140
Dibromochloromethane ug/L 54.450 109 60-140
Dibromomethane ug/L 52.450 105 60-140
Dichlorodifluoromethane ug/L 47.450 95 60-140
Diisopropyl ether ug/L 51.050 102 60-140
Ethylbenzene ug/L 48.550 97 60-140
Hexachloro-1,3-butadiene ug/L 50.650 101 60-140
Isopropylbenzene (Cumene) ug/L 48.250 96 60-140
m&p-Xylene ug/L 97.8100 98 60-140
Methyl-tert-butyl ether ug/L 52.050 104 60-140
Methylene Chloride ug/L 51.550 103 60-140
n-Butylbenzene ug/L 52.050 104 60-140
n-Propylbenzene ug/L 47.350 95 60-140
Naphthalene ug/L 53.250 106 60-140
o-Xylene ug/L 48.150 96 60-140
sec-Butylbenzene ug/L 48.150 96 60-140
Styrene ug/L 51.050 102 60-140
tert-Butylbenzene ug/L 41.050 82 60-140
Tetrachloroethene ug/L 47.350 95 60-140
Toluene ug/L 50.950 102 60-140
trans-1,2-Dichloroethene ug/L 51.650 103 60-140
trans-1,3-Dichloropropene ug/L 52.650 105 60-140
Trichloroethene ug/L 50.150 100 60-140
Trichlorofluoromethane ug/L 54.050 108 60-140
Vinyl chloride ug/L 57.950 116 60-140
1,2-Dichloroethane-d4 (S) % 102 70-130
4-Bromofluorobenzene (S) % 99 70-130
Toluene-d8 (S) % 101 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/06/2016 02:26 PM
Pace Analytical Services, Inc.
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Huntersville, NC 28078
[phone]
Page 22 of 39
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92294881
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1718869MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92294680002
1718870
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 99 60-14095 4 3020ND 19.8 19.0
1,1,1-Trichloroethane ug/L 20 107 60-140103 4 3020ND 21.3 20.5
1,1,2,2-Tetrachloroethane ug/L 20 91 60-14092 1 3020ND 18.3 18.4
1,1,2-Trichloroethane ug/L 20 100 60-14097 4 3020ND 20.1 19.4
1,1-Dichloroethane ug/L 20 104 60-14099 6 3020ND 20.9 19.7
1,1-Dichloroethene ug/L 20 112 60-140109 3 3020ND 22.5 21.8
1,1-Dichloropropene ug/L 20 106 60-140102 3 3020ND 21.1 20.4
1,2,3-Trichlorobenzene ug/L 20 102 60-14097 4 3020ND 20.3 19.5
1,2,3-Trichloropropane ug/L 20 95 60-14095 1 3020ND 19.1 18.9
1,2,4-Trichlorobenzene ug/L 20 92 60-14097 5 3020ND 18.3 19.3
1,2,4-Trimethylbenzene ug/L M120 168 60-140104 16 302054.8 88.5 75.7
1,2-Dibromo-3-
chloropropane
ug/L 20 98 60-14092 6 3020ND 19.5 18.4
1,2-Dibromoethane (EDB) ug/L 20 102 60-14099 3 3020ND 20.5 19.8
1,2-Dichlorobenzene ug/L 20 93 60-14089 4 3020ND 18.5 17.8
1,2-Dichloroethane ug/L 20 88 60-14087 1 3020ND 17.7 17.6
1,2-Dichloropropane ug/L 20 105 60-140101 4 3020ND 21.0 20.1
1,3,5-Trimethylbenzene ug/L 20 111 60-14097 9 302010.2 32.5 29.6
1,3-Dichlorobenzene ug/L 20 97 60-14094 3 3020ND 19.4 18.9
1,3-Dichloropropane ug/L 20 94 60-14093 2 3020ND 18.9 18.6
1,4-Dichlorobenzene ug/L 20 90 60-14086 5 3020ND 18.1 17.2
2,2-Dichloropropane ug/L 20 104 60-140101 3 3020ND 20.8 20.1
2-Chlorotoluene ug/L 20 71 60-14067 7 3020ND 14.3 13.3
4-Chlorotoluene ug/L 20 95 60-14091 4 3020ND 18.9 18.2
Benzene ug/L 20 99 60-14097 2 30201.3 21.1 20.7
Bromobenzene ug/L 20 106 60-140100 6 3020ND 21.2 20.0
Bromochloromethane ug/L 20 106 60-140103 3 3020ND 21.1 20.5
Bromodichloromethane ug/L 20 104 60-140100 4 3020ND 20.8 20.1
Bromoform ug/L 20 95 60-14087 9 3020ND 19.0 17.4
Bromomethane ug/L M120 59 60-14062 5 3020ND 11.8 12.4
Carbon tetrachloride ug/L 20 105 60-140104 1 3020ND 21.0 20.7
Chlorobenzene ug/L 20 95 60-14094 1 3020ND 19.0 18.8
Chloroethane ug/L 20 112 60-140130 15 3020ND 22.3 26.0
Chloroform ug/L 20 101 60-14099 2 3020ND 20.2 19.8
Chloromethane ug/L 20 88 60-14087 1 3020ND 17.5 17.4
cis-1,2-Dichloroethene ug/L 20 103 60-140100 3 3020ND 20.5 19.9
cis-1,3-Dichloropropene ug/L 20 100 60-14095 5 3020ND 20.1 19.0
Dibromochloromethane ug/L 20 99 60-14098 1 3020ND 19.7 19.5
Dibromomethane ug/L 20 99 60-14094 5 3020ND 19.7 18.9
Dichlorodifluoromethane ug/L 20 100 60-14099 1 3020ND 20.0 19.8
Diisopropyl ether ug/L 20 103 60-14098 5 3020ND 20.6 19.6
Ethylbenzene ug/L 20 107 60-14099 5 30207.7 29.1 27.6
Hexachloro-1,3-butadiene ug/L 20 94 60-14097 3 3020ND 18.8 19.3
Isopropylbenzene (Cumene) ug/L 20 98 60-14093 5 30203.5 23.1 22.1
m&p-Xylene ug/L 40 110 60-140100 6 304019.3 63.2 59.2
Methyl-tert-butyl ether ug/L 20 102 60-14098 4 30201.3 21.8 20.9
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/06/2016 02:26 PM
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[phone]
Page 23 of 39
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92294881
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1718869MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92294680002
1718870
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Methylene Chloride ug/L 20 100 60-14099 1 3020ND 20.6 20.3
n-Butylbenzene ug/L 20 104 60-14098 5 30203.0 23.8 22.6
n-Propylbenzene ug/L 20 120 60-14095 12 302019.6 43.6 38.5
Naphthalene ug/L 20 100 60-14092 6 30206.8 26.8 25.2
o-Xylene ug/L 20 95 60-14092 3 3020ND 19.4 18.8
sec-Butylbenzene ug/L 20 100 60-14095 4 30202.9 22.9 21.9
Styrene ug/L 20 94 60-14092 2 3020ND 18.8 18.5
tert-Butylbenzene ug/L 20 81 60-14080 2 3020ND 16.2 16.0
Tetrachloroethene ug/L 20 95 60-14092 3 3020ND 19.1 18.4
Toluene ug/L 20 101 60-14097 4 3020ND 20.3 19.5
trans-1,2-Dichloroethene ug/L 20 105 60-140103 2 3020ND 20.9 20.6
trans-1,3-Dichloropropene ug/L 20 95 60-14094 2 3020ND 19.1 18.8
Trichloroethene ug/L 20 100 60-14097 4 3020ND 20.1 19.4
Trichlorofluoromethane ug/L 20 119 60-140114 4 3020ND 23.8 22.8
Vinyl chloride ug/L 20 116 60-140114 2 3020ND 23.3 22.8
1,2-Dichloroethane-d4 (S) % 99 70-13099
4-Bromofluorobenzene (S) % 98 70-13099
Toluene-d8 (S) % 100 70-130100
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/06/2016 02:26 PM
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[phone]
Page 24 of 39
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92294881
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/42183
EPA 625
EPA 625
625 MSS
Associated Lab Samples: 92294881001, 92294881002, 92294881003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1718748
Associated Lab Samples:92294881001, 92294881002, 92294881003
Matrix: Water
Analyzed
1,2,4-Trichlorobenzene ug/L ND 5.0 04/26/16 03:38
2,4,6-Trichlorophenol ug/L ND 10.0 04/26/16 03:38
2,4-Dichlorophenol ug/L ND 5.0 04/26/16 03:38
2,4-Dimethylphenol ug/L ND 10.0 04/26/16 03:38
2,4-Dinitrophenol ug/L ND 50.0 04/26/16 03:38
2,4-Dinitrotoluene ug/L ND 5.0 04/26/16 03:38
2,6-Dinitrotoluene ug/L ND 5.0 04/26/16 03:38
2-Chloronaphthalene ug/L ND 5.0 04/26/16 03:38
2-Chlorophenol ug/L ND 5.0 04/26/16 03:38
2-Nitrophenol ug/L ND 5.0 04/26/16 03:38
3,3'-Dichlorobenzidine ug/L ND 25.0 04/26/16 03:38
4,6-Dinitro-2-methylphenol ug/L ND 20.0 04/26/16 03:38
4-Bromophenylphenyl ether ug/L ND 5.0 04/26/16 03:38
4-Chloro-3-methylphenol ug/L ND 5.0 04/26/16 03:38
4-Chlorophenylphenyl ether ug/L ND 5.0 04/26/16 03:38
4-Nitrophenol ug/L ND 50.0 04/26/16 03:38
Acenaphthene ug/L ND 5.0 04/26/16 03:38
Acenaphthylene ug/L ND 5.0 04/26/16 03:38
Anthracene ug/L ND 5.0 04/26/16 03:38
Benzo(a)anthracene ug/L ND 5.0 04/26/16 03:38
Benzo(a)pyrene ug/L ND 5.0 04/26/16 03:38
Benzo(b)fluoranthene ug/L ND 5.0 04/26/16 03:38
Benzo(g,h,i)perylene ug/L ND 5.0 04/26/16 03:38
Benzo(k)fluoranthene ug/L ND 5.0 04/26/16 03:38
bis(2-Chloroethoxy)methane ug/L ND 10.0 04/26/16 03:38
bis(2-Chloroethyl) ether ug/L ND 5.0 04/26/16 03:38
bis(2-Chloroisopropyl) ether ug/L ND 5.0 04/26/16 03:38
bis(2-Ethylhexyl)phthalate ug/L ND 5.0 04/26/16 03:38
Butylbenzylphthalate ug/L ND 5.0 04/26/16 03:38
Chrysene ug/L ND 5.0 04/26/16 03:38
Di-n-butylphthalate ug/L ND 5.0 04/26/16 03:38
Di-n-octylphthalate ug/L ND 5.0 04/26/16 03:38
Dibenz(a,h)anthracene ug/L ND 5.0 04/26/16 03:38
Diethylphthalate ug/L ND 5.0 04/26/16 03:38
Dimethylphthalate ug/L ND 5.0 04/26/16 03:38
Fluoranthene ug/L ND 5.0 04/26/16 03:38
Fluorene ug/L ND 5.0 04/26/16 03:38
Hexachloro-1,3-butadiene ug/L ND 5.0 04/26/16 03:38
Hexachlorobenzene ug/L ND 5.0 04/26/16 03:38
Hexachlorocyclopentadiene ug/L ND 10.0 04/26/16 03:38
Hexachloroethane ug/L ND 5.0 04/26/16 03:38
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/06/2016 02:26 PM
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Huntersville, NC 28078
[phone]
Page 25 of 39
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92294881
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1718748
Associated Lab Samples:92294881001, 92294881002, 92294881003
Matrix: Water
Analyzed
Indeno(1,2,3-cd)pyrene ug/L ND 5.0 04/26/16 03:38
Isophorone ug/L ND 10.0 04/26/16 03:38
N-Nitroso-di-n-propylamine ug/L ND 5.0 04/26/16 03:38
N-Nitrosodimethylamine ug/L ND 5.0 04/26/16 03:38
N-Nitrosodiphenylamine ug/L ND 10.0 04/26/16 03:38
Naphthalene ug/L ND 5.0 04/26/16 03:38
Nitrobenzene ug/L ND 5.0 04/26/16 03:38
Pentachlorophenol ug/L ND 10.0 04/26/16 03:38
Phenanthrene ug/L ND 5.0 04/26/16 03:38
Phenol ug/L ND 5.0 04/26/16 03:38
Pyrene ug/L ND 5.0 04/26/16 03:38
2,4,6-Tribromophenol (S) % 95 10-137 04/26/16 03:38
2-Fluorobiphenyl (S) % 80 15-120 04/26/16 03:38
2-Fluorophenol (S) % 42 10-120 04/26/16 03:38
Nitrobenzene-d5 (S) % 78 10-120 04/26/16 03:38
Phenol-d6 (S) % 27 10-120 04/26/16 03:38
Terphenyl-d14 (S) % 82 11-131 04/26/16 03:38
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1718749LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1718750
1,2,4-Trichlorobenzene ug/L 37.550 75 44-1427738.3 2 30
2,4,6-Trichlorophenol ug/L 46.850 94 37-1449547.6 2 30
2,4-Dichlorophenol ug/L 44.450 89 1-1919145.5 2 30
2,4-Dimethylphenol ug/L 43.350 87 32-1199045.1 4 30
2,4-Dinitrophenol ug/L 110 R1250 44 1-18163158 36 30
2,4-Dinitrotoluene ug/L 50.650 101 39-13910652.8 4 30
2,6-Dinitrotoluene ug/L 49.150 98 50-15810050.0 2 30
2-Chloronaphthalene ug/L 42.250 84 60-1188441.9 1 30
2-Chlorophenol ug/L 39.550 79 23-1348140.3 2 30
2-Nitrophenol ug/L 44.950 90 29-1829447.1 5 30
3,3'-Dichlorobenzidine ug/L 116100 116 1-262120120 4 30
4,6-Dinitro-2-methylphenol ug/L 68.7100 69 1-1819090.4 27 30
4-Bromophenylphenyl ether ug/L 43.450 87 53-1278844.1 2 30
4-Chloro-3-methylphenol ug/L 87.1100 87 22-1479089.7 3 30
4-Chlorophenylphenyl ether ug/L 46.250 92 25-1589447.2 2 30
4-Nitrophenol ug/L 84.9250 34 1-1323791.9 8 30
Acenaphthene ug/L 44.350 89 47-1458944.3 0 30
Acenaphthylene ug/L 47.250 94 33-1459447.2 0 30
Anthracene ug/L 44.350 89 1-1669145.4 3 30
Benzo(a)anthracene ug/L 47.050 94 33-1439848.9 4 30
Benzo(a)pyrene ug/L 47.950 96 17-1639949.7 4 30
Benzo(b)fluoranthene ug/L 44.150 88 24-1599748.5 9 30
Benzo(g,h,i)perylene ug/L 46.950 94 1-2199748.7 4 30
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/06/2016 02:26 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 39
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92294881
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1718749LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1718750
Benzo(k)fluoranthene ug/L 45.250 90 11-1629045.1 0 30
bis(2-Chloroethoxy)methane ug/L 40.350 81 33-1848341.7 4 30
bis(2-Chloroethyl) ether ug/L 39.650 79 12-1588140.4 2 30
bis(2-Chloroisopropyl) ether ug/L 40.850 82 36-1668241.2 1 30
bis(2-Ethylhexyl)phthalate ug/L 50.050 100 8-15811657.8 14 30
Butylbenzylphthalate ug/L 47.550 95 1-15211054.8 14 30
Chrysene ug/L 44.050 88 17-1688944.6 1 30
Di-n-butylphthalate ug/L 56.150 112 1-11811658.1 4 30
Di-n-octylphthalate ug/L 70.2 L050 140 4-14614974.3 6 30
Dibenz(a,h)anthracene ug/L 47.450 95 1-2279949.7 5 30
Diethylphthalate ug/L 50.750 101 1-11410150.6 0 30
Dimethylphthalate ug/L 49.050 98 1-1129849.1 0 30
Fluoranthene ug/L 52.650 105 26-13710954.5 3 30
Fluorene ug/L 47.750 95 59-1219648.2 1 30
Hexachloro-1,3-butadiene ug/L 35.150 70 24-1167135.4 1 30
Hexachlorobenzene ug/L 44.050 88 1-1529044.9 2 30
Hexachlorocyclopentadiene ug/L 16.650 33 25-1504522.5 30 30
Hexachloroethane ug/L 35.450 71 40-1137035.2 1 30
Indeno(1,2,3-cd)pyrene ug/L 48.850 98 1-17110351.3 5 30
Isophorone ug/L 43.750 87 21-1968844.1 1 30
N-Nitroso-di-n-propylamine ug/L 39.050 78 1-2308140.6 4 30
N-Nitrosodimethylamine ug/L 19.350 39 25-1504120.4 6 30
N-Nitrosodiphenylamine ug/L 40.050 80 25-1508140.5 1 30
Naphthalene ug/L 40.650 81 21-1338341.3 2 30
Nitrobenzene ug/L 40.050 80 35-1808240.8 2 30
Pentachlorophenol ug/L 84.2100 84 14-1769696.5 14 30
Phenanthrene ug/L 43.750 87 54-1209044.9 3 30
Phenol ug/L 17.750 35 5-1123618.1 2 30
Pyrene ug/L 35.350 71 52-1158140.6 14 30
2-Fluorobiphenyl (S) % 90 15-12089
2-Fluorophenol (S) % 47 10-12047
Nitrobenzene-d5 (S) % 81 10-12085
Phenol-d6 (S) % 32 10-12032
Terphenyl-d14 (S) % 69 11-13179
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/06/2016 02:26 PM
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9800 Kincey Ave. Suite 100
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[phone]
Page 27 of 39
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92294881
FRIENDLY MART
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/42150
MADEP EPH
MADEP EPH
MADEP EPH NC Water
Associated Lab Samples: 92294881001, 92294881002, 92294881003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1717716
Associated Lab Samples:92294881001, 92294881002, 92294881003
Matrix: Water
Analyzed
Aliphatic (C09-C18) ug/L ND 100 N204/25/16 19:27
Aliphatic (C19-C36) ug/L ND 100 N204/25/16 19:27
Aromatic (C11-C22) ug/L ND 100 N204/25/16 19:27
2-Bromonaphthalene (S) % 98 40-140 04/25/16 19:27
2-Fluorobiphenyl (S) % 100 40-140 04/25/16 19:27
Nonatriacontane (S) % 117 40-140 04/25/16 19:27
o-Terphenyl (S) % 87 40-140 04/25/16 19:27
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1717717LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1717718
Aliphatic (C09-C18) ug/L 178 N2300 59 40-14051152 16 50
Aliphatic (C19-C36) ug/L 281 N2400 70 40-14064255 10 50
Aromatic (C11-C22) ug/L 707 N2850 83 40-14074630 12 50
2-Bromonaphthalene (S) % 89 40-14085
2-Fluorobiphenyl (S) % 95 40-14085
Nonatriacontane (S) % 91 40-14089
o-Terphenyl (S) % 95 40-14076
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/06/2016 02:26 PM
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[phone]
Page 28 of 39
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92294881
FRIENDLY MART
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Common Laboratory Contaminant.C9
Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0
Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in
associated samples. Results unaffected by high bias.
L3
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
Tentatively identified compound (TIC) based on mass spectral library search. Result is estimated.N
The lab does not hold TNI accreditation for this parameter.N2
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/06/2016 02:26 PM
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Page 29 of 39
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92294881
FRIENDLY MART
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92294881001 OEXT/42150 GCSV/24794MW 2 MADEP EPH MADEP EPH
92294881002 OEXT/42150 GCSV/24794MW 3 MADEP EPH MADEP EPH
92294881003 OEXT/42150 GCSV/24794MW 4 MADEP EPH MADEP EPH
92294881001 MPRP/21489 ICP/19304MW 2 EPA 3010A EPA 6010
92294881002 MPRP/21489 ICP/19304MW 3 EPA 3010A EPA 6010
92294881003 MPRP/21489 ICP/19304MW 4 EPA 3010A EPA 6010
92294881001 OEXT/42183 MSSV/12168MW 2 EPA 625 EPA 625
92294881002 OEXT/42183 MSSV/12168MW 3 EPA 625 EPA 625
92294881003 OEXT/42183 MSSV/12168MW 4 EPA 625 EPA 625
92294881001 MSV/36535MW 2 SM 6200B
92294881002 MSV/36535MW 3 SM 6200B
92294881003 MSV/36535MW 4 SM 6200B
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/06/2016 02:26 PM
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[phone]
Page 30 of 39
Page 31 of 39
Page 32 of 39
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Page 7 of 7Page 39 of 39

APPENDIX B

WELL CONSTRUCTION RECORDS

---
---
-----
--------------
6/10/2016
NONRESIDENTIAL WELL CONSTRUCTION RECORD
North Carolina Department of Environment and Natural Resources-Division of Water Quality
WELL CONTRACTOR CERTIFICATION # ---"3_42.:....6:..- _
1. WELL CONTRACTOR:
Henry Nemargut
Well Contractor (Individual) Name
Henry Nemargut Engineering Services
Well Contractor Company Name
STREET ADDRESS 2211 Chestnut Street
Wilmington NC 28405
City or Town State Zip Code

(910 )_ 762-5475

Area code-Phone number

2. WELL INFORMATION:
SITE WELL ID #(il applicable) MW-2
STATE WELL PERMIT#(il applicable) _
DWQ or OTHER PERMIT #(if applicable) _
WELL USE (Check Applicable Box) Monitoring iKJ Municipal/Public D
Industrial/Commercial D Agricultural D Recovery D Injection D
IrrigationD Other D (list use) _
DATE DRILLED_4/_20_1_20_1_6 _
TIME COMPLETED_2_:0_0 AM D PM ~
3. WELL LOCATION:
CITY: Wilson COUNTy_W_i_ls_o_n _
3055 Stantonsburg Rd, Wilson, NC 27893
(Street Name, Numbers, Community, Subdivision. Lot No., Parcel, Zip Code)
TOPOGRAPHIC I LAND SETTING
OSlope oValley KJFlat ORidge OOther _
(check appropriate box)
LATITUDE .l _ 3569099167 May be in degrees,
minutes. seconds or
LONGITUDE 77.88775 in a decimal formal
Latitude/longitude source: Jill GPS 0 Topographic map
(location of well must be shown on a USGS tapa map and
attached to this form if not using GPS)
4. FACILITY. is the name of the business where the well is located.
FACILITY ID #(if applicable)_0_-_0_24_5_8_9 _
NAME OF FACILITY Friendly Mart---'-----------­
STREET ADDRESS 3055 Stantonsburg Road

Wilson NC 27893

City or Town State Zip Code
CONTACT PERSON Raymond Bartholomew
MAILING AD DR ESS_P_O_.B_o_x_7_0_6 _
Henderson NC 2753&
City or Town State

(252 )__4_3_8_.7_1_4_1 _

Area code -Phone number

5. WELL DETAILS:
a. TOTAL DEPTH:_14_' _
b. DOES WELL REPLACE EXISTING WELL?
c, WATER LEVEL Below Top of Casing: 6.43'
(Use "+" if Above Top of Casing)
Zip Code
YES D NO IKJ
FT.
d. TOP OF CASING IS 0' FT. Above Land Surface'
'Top of casing terminated atlor below land surface may require
a variance in accordance with 15A NCAC 2C .0118.
e. YIELD (gpm) METHOD OF TEST
f. DISINFECTION: Type Amount
g, WATER ZONES (depth):
From To___ From To _
From To___ From To _
From To___ From To _
6. CASING:
Depth
From_O_'__ To_4_'__
From To___
From--­To--­
7, GROUT: Depth
0' 3'From---To___
From To___
From---To___
8. SCREEN: Depth
From_4_'--To_1_4_'_
From---To---
From To___
9. SANDIGRAVEL PACK:
Depth
From._3.:....'__To_1_4'__
From, To

From To

10. DRILLING LOG
From To
0' 2'
2' 8'
8' 11'
11' 15'
11. REMARKS:
100 HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH
15A NCAC 2C. WELL CONSTRUCTION STANDARDS. AND THAT A COpy OF THIS
RECOR AS BEEN PROVIDED TO TH ' NER.
DATE
Ft. _
Ft. _
Formation Description
gray, Silt w/clay
orange·tan brown, Clay w/sil!
red-white, Silt w/clay & sand
orange-tan, Silt w/clay & sand
Thicknessl
Qiameter
Ft. 2' WeighbSch 4 Material PV
Ft.
Ft.
Material Method
Ft. Portland Pour
Ft.
Ft.
Diameter Slot Size Material
2Ft.___in. 0.01 in. PVC
in. in.Ft --­
Ft.in. in.

Size Material
Ft. #2 Filter Sand
_
_
Submit the original to the Division of Water Quality within 30 days. Attn: Information Mgt., Form GW-1b 1617 Mail Service Center-Raleigh, NC 27699-1617 Phone No. [phone] ext 568. Rev. 7/05
---
---
---
---
---
NON RESIDENTIAL WELL CONSTRUCTION RECORD
North Carolina Department of Environment and Natural Resources-Division of Water Quality
WELL CONTRACTOR CERTIFICATION # --=3---'-42::..:6=--­
1. WELL CONTRACTOR:
Henry Nemargut
Well Contractor (Individual) Name
Henry Nemargut Engineering Services
Well Contractor Company Name
STREET ADDRESS 2211 Chestnut Street
Wilmington NC 28405
City or Town State Zip Code

(910 )_ 762-5475

Area code-Phone number

2. WELL INFORMATION:
SITE WELL 10 #(if appliCable),_M_W_-_3 _
STATE WELL PERMIT#(if applicable) _
DWQ or OTHER PERMIT #(if applicable) _
WELL USE (Check Applicable Box) Monitoring iKJ Municipal/Public D
Industrial/Commercial D Agricultural D Recovery D Injection D
IrrigationD Other D (list use)
DATE DRILLED_4/_2_0/_2_01_6
TIME COMPLETED_4_:0_0
3. WELL LOCATION:
CITY: Wilson
3055 Stantonsburg Rd, Wilson, NC
_
_
AM D PM ~
COUNTY_W_i_ls_o_n
27893
_
(Street Name, Numbers, Community, Subdivision, Lot No., Parcel, Zip Code)
TOPOGRAPHIC I LAND SETTING:
DSlope DValley KJFlat DRidge D Other _
(check appropriate box)
LATITUDE ...L _ 35.69099167 May be in degrees,
minutes, seconds or
LONGITUDE 7788775 in a decimal fonnal
Latitude/longitude source: 0GPS DTopographic map
(location of well must be shown on a USGS tapa map and
attached to this form if not using GPS)
4. FACIL1TY-is the name ofthe business where the well is located.
FACILITY ID #(if applicable)_0_-_02_4_5_8_9 _
NAME OF FACILITY Friendly Mart------'-----------­
STREET ADDRESS 3055 Stantonsburg Road
Wilson NC 27893
City or Town State Zip Code
CONTACT PERSON Raymond Bartholomew
MAILING ADDRESS PO Box 706._-----------­
Henderson NC 2753&
City or Town State
(252 )_-:4::73_8-_7_14_1--,-_

Area code· Phone number

5. WELL DETAiLS:
a. TOTAL DEPTH:_1_4_' _
b. DOES WELL REPLACE EXISTING WELL?
c. WATER LEVEL Below Top of Casing: 5.56'
(Use "+" if Above Top of Casing)
Zip Code
YES D NO IZl
FT.
_
d. TOP OF CASING IS 0' FT. Above Land Surface*
*Top of casing terminated at/or below land surface may require
a variance in accordance with 15A NCAC 2C .0118.
e. YIELD (gpm): METHOD OF TEST
f. DISINFECTION: Type Amount
g. WATER ZONES (depth):
_
_
From To
From
From
To
To
6. CASING:
Depth
Fr.om_O_'__ To_4_'__
From To___
From To___
7. GROUT: Depth
0' 3'From___ To___
From To___
From To___
8. SCREEN: Depth
From_4_'__ To_1_4_'_
From--­To___
From To___
9. SAND/GRAVEL PACK:
Depth
_ From To _
_ From To _
_ From To _
Thicknessl
Diameter weigh6 ~O'crialSch 4Ft. 2"

Ft.

Ft.

Material Method
Portland PourFt.
Ft.
Ft
Diameter
Ft._2__in.
Ft --­in.
Ft.-­in.
Slot Size
0.01 in.
in.
in.
Material
PVC
Size Material
From_3:...'__To_1_4'__ Ft. #2 Filter Sand
From To
From To
10. DRILLING LOG
From To
0' 2'
2' T
T 10'
10' 14'
11. REMARKS:
Ft. _
Ft. _
Formation Description
gray. gray Gravel w/silt & sand
gray-brown, Clay w/silt
orange-tan-brown, clay w/silt & little sand
tan, Silt w/clay &sand
I DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH
15A NCAC 2C, WELL CONSTRUCTION STANDARDS, AND THAT A COpy OF THIS
RECORD H S BEEN PRO OED TO THE WELL OWNER.
6/10/2016
DATE
TRUCTING THE WELL
Submit the original to the Division of Water Quality within 30 days. Attn: Information Mgt., Form GW-1b 1617 Mail Service Center-Raleigh, NC 27699-1617 Phone No. (919) 733·7015 ext 568. Rev. 7105
--- ---
---
---
---
---
---
NON RESIDENTIAL WELL CONSTRUCTION RECORD
North Carolina Department of Environment and Natural Resources-Division of Water Quality
WELL CONTRACTOR CERTIFICATION # -=3~42::..:6:....-
1. WELL CONTRACTOR:
Henry Nemargut
Well Contractor (Individual) Name
Henry Nemargut Engineering Services
Well Contractor Company Name
STREET ADDRESS 2211 Chestnut Street
Wilmington NC 28405
City or Town State Zip Code
(910 )_ 762-5475
Area code-Phone number
2. WELL INFORMATION:
SITE WELL ID #(if applicable)_M_W_-4
STATE WELL PERMIT#(if applicable),
DWQ or OTHER PERMIT #(if applicable)
WELL USE (Check Applicable Box) Monitoring IX] Municipal/Public 0
IndustriallCommercialD AgriculturalD Recovery 0 Injection 0
IrrigationD Other 0 (list use) _
DATE DRI LLE D_4/_2_0/_20_1_6 _
TIME COMPLETED_6_:0_0 AM 0 PM 1:9
3. WELL LOCATION:
CITY: Wilson COUNTy_W_i_ls_o_n _
3055 Stantonsburg Rd, Wilson, NC 27893
(Street Name, Numbers, Community, Subdivision, Lot No., Parcel, Zip Code)
TOPOGRAPHIC I LAND SETTING:
DSlope DValley K]Flat DRidge DOther _
(check appropriate box)
LATITUDE -l.. _ 35.69099167 May be in degrees,
minutes. seconds or
LONGITUDE 77.88775 in a decimal fonnat
Latitude/longitude source: J0GPS o Topographic map
(location of well must be shown on a USGS tapa map and
attached to this form if not using GPS)
4. FACILlTY-is the name of the business where the well is located.
FACILITY ID #(if applicable)_0_-_0_24_5_8_9 _
NAME OF FACILlTY_Fr_ie_n_d....:ly_M_art _
STREET ADDRESS 3055 Stantonsburg Road
Wilson NC 27893
City or Town State Zip Code
CONTACT PERSON Raymond Bartholomew
MAILING ADDRESS_P_._O_B_o_x_7_0_6 _
Henderson NC 2753&
City or Town State
(252 )_---:4::-3_8_-7_1_4_1 _

Area code -Phone number

5. WELL DETAiLS:
a. TOTALDEPTH:_14_' _
b. DOES WELL REPLACE EXISTING WELL?
c. WATER LEVEL Below Top of Casing: 5,46'
(Use "+" if Above Top of Casing)
Zip Code
YES 0 NO IX]
FT.
_
_
_
_
d. TOP OF CASING IS 0' FT. Above Land Surface*
*Top of casing terminated at/or below land surface may require
a variance in accordance with 15A NCAC 2C .0118.
e. YIELD (gpm) METHOD OF TEST__-­__
f. DISINFECTION: Type Amount _
g. WATER ZONES (depth)
From To___ From To _
From To___ From To _
From To___ From To _
6. CASING:
Depth
From_O_'__ To_4_'__
From To

From
To___
7. GROUT: Depth

0' 3'
From___ To___
From To___
From To___
8. SCREEN: Depth
From_4_'__ To_1_4_'_
From To___
From To___
9. SAND/GRAVEL PACK:
Depth
From_3,---'__To_1_4'__
From To
From To
10. DRILLING LOG
From To
0' 2'
2' 6'
6' 8'
8' 14'
11, REMARKS:
I DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH
15A NCAC 2C, WELL CONSTRUCTION STANDARDS, AND THAT A COPY OF THIS
REC H BEEN PR ED TO THE WELL OWNER.
6/10/2016
DATE
RUCTING THE WELL
Formation Description
tan-brown. Silt w/clay & sand
gray, Clay w/sil!
tan-brown, clay w/silt
white-gray, Clay w/stlt &trace sand
Thicknessl
Diameter weigh6 MaterialSch4 PVFt. 2"

Ft.

Ft.

Material Method
Portland PourFt.
Ft.
Ft.
Diameter Slot Size Material
Ft._2 __in. 0.01 in. PVC
Ft.--­in. in.
Ft.-­in. in.
Size Material
Ft._#'---2=---_ -,F-,i",,-lte::::.r:.....::::S.:::a.:...:n.:::.d__

Ft. _

Ft. _

Submit the original to the Division of Water Quality within 30 days. Attn: Information Mgt., Form GW-1b 1617 Mail Service Center -Raleigh, NC 27699-1617 Phone No. [phone] ext 568. Rev. 7/05