RA-5451_26996_CA_MRP_20160216

TABLE 1
FIELD DATA MEASUREMENTS
PANTRY #3187
804 DURHAM ROAD
ROXBORO, NORTH CAROLINA
NCDEQ INCIDENT NO: 26996
Date of AFVR: January 27, 2016
Date Time
Unit-Vacuum(inches of Hg)
Well-Head -Vacuum-(inches of Hg)
Velocity
(ft/min)Pipe ID(in)Temp(deg F)Rel. Humid(%)
Water Vapor(%)Qstd(flow)Wells Used
8/21/2014 8:30 -19.5 -19.5 1,912 3 121.6 12.6 0.874 10.7
8/21/2014 8:45 -19.5 -19.5 1,876 3 124.7 11.7 0.883 9.7
8/21/2014 9:00 -19.5 -19.5 1,888 3 132.2 10.2 0.898 8.4
8/21/2014 9:15 -19.5 -19.5 1,905 3 139.6 9.0 0.91 7.4
8/21/2014 9:30 -19.5 -19.5 1,876 3 140.6 9.6 0.904 7.8
8/21/2014 9:45 -19.5 -19.5 1,812 3 144.3 9.4 0.906 7.3
8/21/2014 10:00 -19.5 -19.5 1,788 3 145.8 9.3 0.907 7.1
8/21/2014 10:15 -19.5 -19.5 1,727 3 147.7 9.0 0.91 6.6
8/21/2014 10:30 -19.5 -19.5 1,692 3 148.7 9.7 0.903 7.0
8/21/2014 11:00 -19.5 -19.5 1,682 3 154.8 7.6 0.924 5.4
8/21/2014 11:30 -19.5 -19.5 1,677 3 160.6 4.7 0.953 3.3
8/21/2014 12:00 -19.5 -19.5 1,705 3 170.2 4.5 0.955 3.2
8/21/2014 12:30 -19.5 -19.5 1,703 3 174.7 4.1 0.959 2.8
8/21/2014 13:30 -19.5 -19.5 1,694 3 179.1 4.0 0.96 2.7
8/21/2014 14:30 -19.5 -19.5 1,707 3 182.4 3.7 0.963 2.58/21/2014 16:30 -19.5 -19.5 1,693 3 184.7 3.6 0.964 2.4
Well MW-1 stinger set at 24
feet bgs
TABLE 2
TOTAL EMISSIONS CALCULATIONS
PANTRY #3187
804 DURHAM ROAD
ROXBORO, NORTH CAROLINA
NCDEQ INCIDENT NO: 26996
Date of AFVR Event: 1/27/16Time
(min)
Flow
(DSCFM)
PPM M easured
(ppm)
K
(#C-gas)PPMg
Cg:m
(mg/dsm^3)
Cg
(lb/dscf)
PMRg
(lb/hr)
PMR
(lb)
0 10.7 111.6 1 111.6 593 0.00004 0.024 0.006
15 9.7 149.7 1 149.7 796 0.00005 0.029 0.007308.4 140.2 1 140.2 746 0.00005 0.024 0.006
45 7.4 137.3 1 137 730 0.00005 0.020 0.005607.8 135.6 1 136 721 0.00005 0.021 0.005
75 7.3 126.7 1 127 674 0.00004 0.018 0.005907.1 108.5 1 109 577 0.00004 0.015 0.0041056.6 87.6 1 88 466 0.00003 0.012 0.0031207.0 69.9 1 70 372 0.00002 0.010 0.0051505.4 68.8 1 69 366 0.00002 0.007 0.0041803.3 68.0 1 68 362 0.00002 0.004 0.0022103.2 59.6 1 60 317 0.00002 0.004 0.002
240 2.8 60.2 1 60 320 0.00002 0.003 0.0033002.7 61.6 1 62 328 0.00002 0.003 0.003
360 2.5 62.4 1 62 332 0.00002 0.003 0.0064802.4 46.8 1 47 249 0.00002 0.002 0.000
485 Total emissions in pounds 0.067
Total Emissions Converted into Gallons: 0.011869558
TABLE 3MONITORING WELL MW-1 GROUNDWATER ANALYTICAL DATA
PANTRY #3187
804 DURHAM ROAD
ROXBORO, NORTH CAROLINA
NCDEQ INCIDENT NO. 26996
2/7/2006 LSA 16,500 27,600 4,320 22,500 7,360 1,310
5/15/2012 CSA
11/4/2012 Pre-CAP Mon 2,900 10,000 2,100 11,100 <20 540
2/18/2014 Pre-CAP Mon 4,800 6,900 1,100 5,300 1,800 410
8/25/2015 Pre-CAP Mon 17,100 27,000 2,600 13,370 3,270 1,300
2/2/2016 Pre-CAP Mon 5,800 9,400 1,300 6,300 870 510
1 600 600 500 20 6
5,000 260,000 84,500 85,500 20,000 6,000
Notes:
1. "<" denotes compound not detected above method detection limit
2. NC 2L GW Standard = Title 15A NCAC 2L .0202 Groundwater Standard
3. GCL = Gross Contaminant Level established by NCDEQ
4. Values in BOLD indicate levels above GCLs.
5. MTBE = Methyl tertiary butyl ether
6. All concentrations in micrograms per liter (ug/L)
Not Sampled - Free Product
MW-1
GCL
2L GW Standard
Analytical Methods:EPA METHOD 6200B
WellDate SampledIncident PhaseBenzeneNaphthaleneTolueneEthylbenzeneMTBETotal Xylenes

1
1
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
February 9, 2016
Maureen Jackson
ATC Group Services LLC - Raleigh NC
2725 East Millbrook Road, Ste 121
Raleigh, NC 27604
Project Location: 804 Durham Rd. Roxboro, NC
Client Job Number:
Project Number: PANT 31876
Laboratory Work Order Number: 16B0156
Enclosed are results of analyses for samples received by the laboratory on February 2, 2016. If you have any questions
concerning this report, please feel free to contact me.
Sincerely,
Lisa A. Worthington
Project Manager
Page 1 of 17
Table of Contents
Table of Contents
Sample Summary 3
Case Narrative 4
Sample Results 5
16B0156-01 5
Sample Preparation Information 7
QC Data 8
Volatile Organic Compounds by GC/MS 8
B141450 8
Flag/Qualifier Summary 12
Certifications 13
Chain of Custody/Sample Receipt 15
Page 2 of 17
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYTICAL SUMMARY
2/9/2016
ATC Group Services LLC - Raleigh NC
2725 East Millbrook Road, Ste 121
Raleigh, NC 27604
ATTN: Maureen Jackson
PANT 31876
16B0156
The results of analyses performed on the following samples submitted to the CON-TEST Analytical Laboratory are found in this report.
PROJECT LOCATION:
PURCHASE ORDER NUMBER:
PROJECT NUMBER:
REPORT DATE:
WORK ORDER NUMBER:
FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB
804 Durham Rd. Roxboro, NC
MW-1 16B0156-01 Ground Water SM21-22 6200B
[TOC_1]Sample Summary[TOC]
Page 3 of 17
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CASE NARRATIVE SUMMARY
All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report.
[TOC_1]Case Narrative[TOC]
SM21-22 6200B
Qualifications:
Laboratory fortified blank/laboratory control sample recovery and duplicate recoveries outside of control limits. Data validation is not
affected since all results are "not detected" for associated samples in this batch and bias is on the high side.
Analyte & Samples(s) Qualified:
L-02
Ethanol
B141450-BS1, B141450-BSD1
Trichlorofluoromethane (Freon 11)
B141450-BS1, B141450-BSD1
Laboratory fortified blank/laboratory control sample recovery and duplicate recovery are outside of control limits. Reported value for this
compound is likely to be biased on the low side.
Analyte & Samples(s) Qualified:
L-04
2,2-Dichloropropane
16B0156-01[MW-1], B141450-BLK1, B141450-BS1, B141450-BSD1
Elevated reporting limit due to high concentration of target compounds.
Analyte & Samples(s) Qualified:
RL-11
16B0156-01[MW-1]
The results of analyses reported only relate to samples submitted to the Con-Test Analytical Laboratory for testing.
I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed
in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the
best of my knowledge and belief, accurate and complete.
Johanna K. Harrington
Manager, Laboratory Reporting
Page 4 of 17
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 2/2/2016
Work Order: 16B0156Sample Description:Project Location: 804 Durham Rd. Roxboro, NC
Sample ID: 16B0156-01
Field Sample #: MW-1
Sample Matrix: Ground Water
Sampled: 2/2/2016 12:15
[TOC_2]16B0156-01[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Sample Flags: RL-11 Volatile Organic Compounds by GC/MS
ND 10000 2/5/16 9:29 MFFg/L970 2/4/16SM21-22 6200B200Acetone
5800 100 2/5/16 9:29 MFFg/L24 2/4/16SM21-22 6200B200Benzene
ND 100 2/5/16 9:29 MFFg/L30 2/4/16SM21-22 6200B200Bromobenzene
ND 100 2/5/16 9:29 MFFg/L45 2/4/16SM21-22 6200B200Bromochloromethane
ND 100 2/5/16 9:29 MFFg/L18 2/4/16SM21-22 6200B200Bromodichloromethane
ND 200 2/5/16 9:29 MFFg/L42 2/4/16SM21-22 6200B200Bromoform
ND 200 2/5/16 9:29 MFFg/L190 2/4/16SM21-22 6200B200Bromomethane
ND 1000 2/5/16 9:29 MFFg/L470 2/4/16SM21-22 6200B2002-Butanone (MEK)
ND 100 2/5/16 9:29 MFFg/L30 2/4/16SM21-22 6200B200n-Butylbenzene
ND 100 2/5/16 9:29 MFFg/L26 2/4/16SM21-22 6200B200sec-Butylbenzene
ND 100 2/5/16 9:29 MFFg/L22 2/4/16SM21-22 6200B200tert-Butylbenzene
ND 200 2/5/16 9:29 MFFg/L24 2/4/16SM21-22 6200B200Carbon Tetrachloride
ND 100 2/5/16 9:29 MFFg/L32 2/4/16SM21-22 6200B200Chlorobenzene
ND 20000 2/5/16 9:29 MFFg/L5600 2/4/16SM21-22 6200B200Ethanol
ND 100 2/5/16 9:29 MFFg/L20 2/4/16SM21-22 6200B200Chlorodibromomethane
ND 100 2/5/16 9:29 MFFg/L56 2/4/16SM21-22 6200B200Chloroethane
ND 100 2/5/16 9:29 MFFg/L44 2/4/16SM21-22 6200B200Chloroform
ND 200 2/5/16 9:29 MFFg/L65 2/4/16SM21-22 6200B200Chloromethane
ND 100 2/5/16 9:29 MFFg/L24 2/4/16SM21-22 6200B2002-Chlorotoluene
ND 100 2/5/16 9:29 MFFg/L28 2/4/16SM21-22 6200B2004-Chlorotoluene
ND 100 2/5/16 9:29 MFFg/L24 2/4/16SM21-22 6200B2001,2-Dibromoethane (EDB)
ND 100 2/5/16 9:29 MFFg/L34 2/4/16SM21-22 6200B2001,2-Dichlorobenzene
ND 100 2/5/16 9:29 MFFg/L34 2/4/16SM21-22 6200B2001,3-Dichlorobenzene
ND 100 2/5/16 9:29 MFFg/L30 2/4/16SM21-22 6200B2001,4-Dichlorobenzene
ND 100 2/5/16 9:29 MFFg/L36 2/4/16SM21-22 6200B200Dichlorodifluoromethane (Freon 12)
ND 100 2/5/16 9:29 MFFg/L32 2/4/16SM21-22 6200B2001,1-Dichloroethane
ND 100 2/5/16 9:29 MFFg/L39 2/4/16SM21-22 6200B2001,2-Dichloroethane
ND 100 2/5/16 9:29 MFFg/L42 2/4/16SM21-22 6200B2001,1-Dichloroethylene
ND 100 2/5/16 9:29 MFFg/L29 2/4/16SM21-22 6200B200cis-1,2-Dichloroethylene
ND 200 2/5/16 9:29 MFFg/L30 2/4/16SM21-22 6200B200trans-1,2-Dichloroethylene
ND 100 2/5/16 9:29 MFFg/L26 2/4/16SM21-22 6200B2001,2-Dichloropropane
ND 100 2/5/16 9:29 MFFg/L26 2/4/16SM21-22 6200B2001,3-Dichloropropane
ND 100 2/5/16 9:29 MFFg/L32 2/4/16SM21-22 6200B200L-042,2-Dichloropropane
ND 100 2/5/16 9:29 MFFg/L26 2/4/16SM21-22 6200B2001,1-Dichloropropene
ND 100 2/5/16 9:29 MFFg/L24 2/4/16SM21-22 6200B200cis-1,3-Dichloropropene
ND 100 2/5/16 9:29 MFFg/L22 2/4/16SM21-22 6200B200trans-1,3-Dichloropropene
260 100 2/5/16 9:29 MFFg/L36 2/4/16SM21-22 6200B200Diisopropyl Ether (DIPE)
1300 100 2/5/16 9:29 MFFg/L26 2/4/16SM21-22 6200B200Ethylbenzene
ND 1000 2/5/16 9:29 MFFg/L300 2/4/16SM21-22 6200B2002-Hexanone (MBK)
ND 100 2/5/16 9:29 MFFg/L24 2/4/16SM21-22 6200B200Isopropylbenzene (Cumene)
ND 100 2/5/16 9:29 MFFg/L30 2/4/16SM21-22 6200B200p-Isopropyltoluene (p-Cymene)
870 100 2/5/16 9:29 MFFg/L18 2/4/16SM21-22 6200B200Methyl tert-Butyl Ether (MTBE)
ND 1000 2/5/16 9:29 MFFg/L640 2/4/16SM21-22 6200B200Methylene Chloride
ND 1000 2/5/16 9:29 MFFg/L290 2/4/16SM21-22 6200B2004-Methyl-2-pentanone (MIBK)
[TOC_1]Sample Results[TOC]
Page 5 of 17
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 2/2/2016
Work Order: 16B0156Sample Description:Project Location: 804 Durham Rd. Roxboro, NC
Sample ID: 16B0156-01
Field Sample #: MW-1
Sample Matrix: Ground Water
Sampled: 2/2/2016 12:15
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
DL Units
Date
PreparedMethod
Sample Flags: RL-11 Volatile Organic Compounds by GC/MS
510 100 2/5/16 9:29 MFFg/L24 2/4/16SM21-22 6200B200Naphthalene
170 100 2/5/16 9:29 MFFg/L26 2/4/16SM21-22 6200B200n-Propylbenzene
ND 100 2/5/16 9:29 MFFg/L30 2/4/16SM21-22 6200B200Styrene
ND 100 2/5/16 9:29 MFFg/L32 2/4/16SM21-22 6200B2001,1,2,2-Tetrachloroethane
ND 100 2/5/16 9:29 MFFg/L34 2/4/16SM21-22 6200B200Tetrachloroethylene
9400 100 2/5/16 9:29 MFFg/L34 2/4/16SM21-22 6200B200Toluene
ND 100 2/5/16 9:29 MFFg/L28 2/4/16SM21-22 6200B2001,2,3-Trichlorobenzene
ND 100 2/5/16 9:29 MFFg/L38 2/4/16SM21-22 6200B2001,2,4-Trichlorobenzene
ND 100 2/5/16 9:29 MFFg/L19 2/4/16SM21-22 6200B2001,1,1-Trichloroethane
ND 100 2/5/16 9:29 MFFg/L23 2/4/16SM21-22 6200B2001,1,2-Trichloroethane
ND 200 2/5/16 9:29 MFFg/L40 2/4/16SM21-22 6200B200Trichloroethylene
ND 100 2/5/16 9:29 MFFg/L29 2/4/16SM21-22 6200B200Trichlorofluoromethane (Freon 11)
ND 100 2/5/16 9:29 MFFg/L38 2/4/16SM21-22 6200B2001,2,3-Trichloropropane
1300 100 2/5/16 9:29 MFFg/L36 2/4/16SM21-22 6200B2001,2,4-Trimethylbenzene
350 100 2/5/16 9:29 MFFg/L26 2/4/16SM21-22 6200B2001,3,5-Trimethylbenzene
ND 1000 2/5/16 9:29 MFFg/L290 2/4/16SM21-22 6200B200Vinyl Acetate
ND 100 2/5/16 9:29 MFFg/L27 2/4/16SM21-22 6200B200Vinyl Chloride
4200 200 2/5/16 9:29 MFFg/L50 2/4/16SM21-22 6200B200m+p Xylene
2100 100 2/5/16 9:29 MFFg/L26 2/4/16SM21-22 6200B200o-Xylene
Surrogates % Recovery Recovery Limits Flag/Qual
1,2-Dichloroethane-d4 100 2/5/16 9:2970-130
Toluene-d8 98.2 2/5/16 9:2970-130
4-Bromofluorobenzene 88.8 2/5/16 9:2970-130
Page 6 of 17
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Sample Extraction Data
Prep Method: SW-846 5030B-SM21-22 6200B
Lab Number [Field ID]Batch DateInitial [mL]Final [mL]
B141450 02/04/160.025 5.0016B0156-01 [MW-1]
[TOC_1]Sample Preparation Information[TOC]
Page 7 of 17
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
[TOC_2]Volatile Organic Compounds by GC/MS[TOC]
Batch B141450 - SW-846 5030B
[TOC_3]B141450[TOC]
Blank (B141450-BLK1) Prepared: 02/04/16 Analyzed: 02/05/16
Acetone g/L50ND
Benzene g/L0.50ND
Bromobenzene g/L0.50ND
Bromochloromethane g/L0.50ND
Bromodichloromethane g/L0.50ND
Bromoform g/L1.0ND
Bromomethane g/L1.0ND
2-Butanone (MEK)g/L5.0ND
n-Butylbenzene g/L0.50ND
sec-Butylbenzene g/L0.50ND
tert-Butylbenzene g/L0.50ND
Carbon Tetrachloride g/L1.0ND
Chlorobenzene g/L0.50ND
Ethanol g/L50ND
Chlorodibromomethane g/L0.50ND
Chloroethane g/L0.50ND
Chloroform g/L0.50ND
Chloromethane g/L1.0ND
2-Chlorotoluene g/L0.50ND
4-Chlorotoluene g/L0.50ND
1,2-Dibromoethane (EDB)g/L0.50ND
1,2-Dichlorobenzene g/L0.50ND
1,3-Dichlorobenzene g/L0.50ND
1,4-Dichlorobenzene g/L0.50ND
Dichlorodifluoromethane (Freon 12)g/L0.50ND
1,1-Dichloroethane g/L0.50ND
1,2-Dichloroethane g/L0.50ND
1,1-Dichloroethylene g/L0.50ND
cis-1,2-Dichloroethylene g/L0.50ND
trans-1,2-Dichloroethylene g/L1.0ND
1,2-Dichloropropane g/L0.50ND
1,3-Dichloropropane g/L0.50ND
2,2-Dichloropropane g/L0.50 L-04ND
1,1-Dichloropropene g/L0.50ND
cis-1,3-Dichloropropene g/L0.50ND
trans-1,3-Dichloropropene g/L0.50ND
Diisopropyl Ether (DIPE)g/L0.50ND
Ethylbenzene g/L0.50ND
2-Hexanone (MBK)g/L5.0ND
Isopropylbenzene (Cumene)g/L0.50ND
p-Isopropyltoluene (p-Cymene)g/L0.50ND
Methyl tert-Butyl Ether (MTBE)g/L0.50ND
Methylene Chloride g/L5.0ND
4-Methyl-2-pentanone (MIBK)g/L5.0ND
Naphthalene g/L0.50ND
n-Propylbenzene g/L0.50ND
Styrene g/L0.50ND
1,1,2,2-Tetrachloroethane g/L0.50ND
Tetrachloroethylene g/L0.50ND
Toluene g/L0.50ND
1,2,3-Trichlorobenzene g/L0.50ND
1,2,4-Trichlorobenzene g/L0.50ND
[TOC_1]QC Data[TOC]
Page 8 of 17
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B141450 - SW-846 5030B
Blank (B141450-BLK1) Prepared: 02/04/16 Analyzed: 02/05/16
1,1,1-Trichloroethane g/L0.50ND
1,1,2-Trichloroethane g/L0.50ND
Trichloroethylene g/L1.0ND
Trichlorofluoromethane (Freon 11)g/L0.50ND
1,2,3-Trichloropropane g/L0.50ND
1,2,4-Trimethylbenzene g/L0.50ND
1,3,5-Trimethylbenzene g/L0.50ND
Vinyl Acetate g/L5.0ND
Vinyl Chloride g/L0.50ND
m+p Xylene g/L1.0ND
o-Xylene g/L0.50ND
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 10225.4
g/L 25.0 70-130Surrogate: Toluene-d8 96.724.2
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 86.721.7
LCS (B141450-BS1) Prepared: 02/04/16 Analyzed: 02/05/16
Acetone g/L50 100 70-13099.999.9
Benzene g/L0.50 10.0 70-13010310.3
Bromobenzene g/L0.50 10.0 70-13091.99.19
Bromochloromethane g/L0.50 10.0 70-13010410.4
Bromodichloromethane g/L0.50 10.0 70-13010410.4
Bromoform g/L1.0 10.0 70-13092.49.24
Bromomethane g/L1.0 10.0 60-14012412.4
2-Butanone (MEK)g/L5.0 100 70-13095.295.2
n-Butylbenzene g/L0.50 10.0 70-13097.39.73
sec-Butylbenzene g/L0.50 10.0 70-13010510.5
tert-Butylbenzene g/L0.50 10.0 70-13010010.0
Carbon Tetrachloride g/L1.0 10.0 70-13010610.6
Chlorobenzene g/L0.50 10.0 70-13010210.2
Ethanol g/L50 100 L-0270-130170*170
Chlorodibromomethane g/L0.50 10.0 70-13095.99.59
Chloroethane g/L0.50 10.0 60-14012512.5
Chloroform g/L0.50 10.0 70-13010810.8
Chloromethane g/L1.0 10.0 60-14081.08.10
2-Chlorotoluene g/L0.50 10.0 70-13094.19.41
4-Chlorotoluene g/L0.50 10.0 70-13093.49.34
1,2-Dibromoethane (EDB)g/L0.50 10.0 70-13010010.0
1,2-Dichlorobenzene g/L0.50 10.0 70-13010810.8
1,3-Dichlorobenzene g/L0.50 10.0 70-13010410.4
1,4-Dichlorobenzene g/L0.50 10.0 70-13010310.3
Dichlorodifluoromethane (Freon 12)g/L0.50 10.0 60-14075.47.54
1,1-Dichloroethane g/L0.50 10.0 70-13099.59.95
1,2-Dichloroethane g/L0.50 10.0 70-13010210.2
1,1-Dichloroethylene g/L0.50 10.0 70-13010110.1
cis-1,2-Dichloroethylene g/L0.50 10.0 70-13096.29.62
trans-1,2-Dichloroethylene g/L1.0 10.0 70-13010010.0
1,2-Dichloropropane g/L0.50 10.0 70-13096.49.64
1,3-Dichloropropane g/L0.50 10.0 70-13010610.6
2,2-Dichloropropane g/L0.50 10.0 L-0470-13062.0 *6.20
1,1-Dichloropropene g/L0.50 10.0 70-13010210.2
cis-1,3-Dichloropropene g/L0.50 10.0 70-13091.09.10
trans-1,3-Dichloropropene g/L0.50 10.0 70-13087.18.71
Page 9 of 17
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B141450 - SW-846 5030B
LCS (B141450-BS1) Prepared: 02/04/16 Analyzed: 02/05/16
Diisopropyl Ether (DIPE)g/L0.50 10.0 70-13092.09.20
Ethylbenzene g/L0.50 10.0 70-13010110.1
2-Hexanone (MBK)g/L5.0 100 70-13094.694.6
Isopropylbenzene (Cumene)g/L0.50 10.0 70-13097.89.78
p-Isopropyltoluene (p-Cymene)g/L0.50 10.0 70-13099.79.97
Methyl tert-Butyl Ether (MTBE)g/L0.50 10.0 70-13090.59.05
Methylene Chloride g/L5.0 10.0 70-13099.49.94
4-Methyl-2-pentanone (MIBK)g/L5.0 100 70-13093.693.6
Naphthalene g/L0.50 10.0 70-13096.99.69
n-Propylbenzene g/L0.50 10.0 70-13010110.1
Styrene g/L0.50 10.0 70-13010310.3
1,1,2,2-Tetrachloroethane g/L0.50 10.0 70-13011111.1
Tetrachloroethylene g/L0.50 10.0 70-13097.89.78
Toluene g/L0.50 10.0 70-13010010.0
1,2,3-Trichlorobenzene g/L0.50 10.0 70-13097.19.71
1,2,4-Trichlorobenzene g/L0.50 10.0 70-13010010.0
1,1,1-Trichloroethane g/L0.50 10.0 70-13097.89.78
1,1,2-Trichloroethane g/L0.50 10.0 70-13010210.2
Trichloroethylene g/L1.0 10.0 70-13097.79.77
Trichlorofluoromethane (Freon 11)g/L0.50 10.0 L-0270-130144*14.4
1,2,3-Trichloropropane g/L0.50 10.0 70-13094.39.43
1,2,4-Trimethylbenzene g/L0.50 10.0 70-13010010.0
1,3,5-Trimethylbenzene g/L0.50 10.0 70-13092.59.25
Vinyl Acetate g/L5.0 100 70-13092.592.5
Vinyl Chloride g/L0.50 10.0 60-14010210.2
m+p Xylene g/L1.0 20.0 70-13096.519.3
o-Xylene g/L0.50 10.0 70-13010010.0
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 10025.0
g/L 25.0 70-130Surrogate: Toluene-d8 99.324.8
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 90.722.7
LCS Dup (B141450-BSD1) Prepared: 02/04/16 Analyzed: 02/05/16
Acetone g/L50 100 2570-130104 4.16104
Benzene g/L0.50 10.0 2570-130103 0.19410.3
Bromobenzene g/L0.50 10.0 2570-13094.0 2.269.40
Bromochloromethane g/L0.50 10.0 2570-130102 1.7410.2
Bromodichloromethane g/L0.50 10.0 2570-13095.7 8.229.57
Bromoform g/L1.0 10.0 2570-13084.5 8.938.45
Bromomethane g/L1.0 10.0 2560-140132 6.2613.2
2-Butanone (MEK)g/L5.0 100 2570-13098.2 3.0898.2
n-Butylbenzene g/L0.50 10.0 2570-13097.9 0.6159.79
sec-Butylbenzene g/L0.50 10.0 2570-130103 2.5010.3
tert-Butylbenzene g/L0.50 10.0 2570-130101 0.69710.1
Carbon Tetrachloride g/L1.0 10.0 2570-13098.4 6.969.84
Chlorobenzene g/L0.50 10.0 2570-130104 2.6310.4
Ethanol g/L50 100 25 L-0270-130160 5.76*160
Chlorodibromomethane g/L0.50 10.0 2570-13094.1 1.899.41
Chloroethane g/L0.50 10.0 2560-140127 1.8312.7
Chloroform g/L0.50 10.0 2570-130104 3.8710.4
Chloromethane g/L1.0 10.0 2560-14077.9 3.907.79
2-Chlorotoluene g/L0.50 10.0 2570-13094.5 0.4249.45
4-Chlorotoluene g/L0.50 10.0 2570-13093.8 0.4279.38
Page 10 of 17
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
QUALITY CONTROL
Batch B141450 - SW-846 5030B
LCS Dup (B141450-BSD1) Prepared: 02/04/16 Analyzed: 02/05/16
1,2-Dibromoethane (EDB)g/L0.50 10.0 2570-13096.1 4.189.61
1,2-Dichlorobenzene g/L0.50 10.0 2570-130105 2.9110.5
1,3-Dichlorobenzene g/L0.50 10.0 2570-130107 2.6610.7
1,4-Dichlorobenzene g/L0.50 10.0 2570-130103 0.58310.3
Dichlorodifluoromethane (Freon 12)g/L0.50 10.0 2560-14071.9 4.757.19
1,1-Dichloroethane g/L0.50 10.0 2570-13098.1 1.429.81
1,2-Dichloroethane g/L0.50 10.0 2570-13097.5 4.719.75
1,1-Dichloroethylene g/L0.50 10.0 2570-13095.0 6.129.50
cis-1,2-Dichloroethylene g/L0.50 10.0 2570-13099.7 3.579.97
trans-1,2-Dichloroethylene g/L0.50 10.0 2570-130102 2.0810.2
1,2-Dichloropropane g/L0.50 10.0 2570-13090.2 6.659.02
1,3-Dichloropropane g/L0.50 10.0 2570-130106 0.094110.6
2,2-Dichloropropane g/L0.50 10.0 25 L-0470-13060.9 1.79*6.09
1,1-Dichloropropene g/L0.50 10.0 2570-13098.2 4.299.82
cis-1,3-Dichloropropene g/L0.50 10.0 2570-13090.3 0.7729.03
trans-1,3-Dichloropropene g/L0.50 10.0 2570-13084.4 3.158.44
Diisopropyl Ether (DIPE)g/L0.50 10.0 2570-13087.2 5.368.72
Ethylbenzene g/L0.50 10.0 2570-13098.3 2.819.83
2-Hexanone (MBK)g/L5.0 100 2570-13095.1 0.45395.1
Isopropylbenzene (Cumene)g/L0.50 10.0 2570-13093.1 4.929.31
p-Isopropyltoluene (p-Cymene)g/L0.50 10.0 2570-13099.8 0.1009.98
Methyl tert-Butyl Ether (MTBE)g/L0.50 10.0 2570-13092.9 2.629.29
Methylene Chloride g/L5.0 10.0 2570-13096.7 2.759.67
4-Methyl-2-pentanone (MIBK)g/L5.0 100 2570-13095.2 1.7495.2
Naphthalene g/L0.50 10.0 2570-130104 6.7810.4
n-Propylbenzene g/L0.50 10.0 2570-13094.8 6.439.48
Styrene g/L0.50 10.0 2570-130101 1.9710.1
1,1,2,2-Tetrachloroethane g/L0.50 10.0 2570-130105 5.9310.5
Tetrachloroethylene g/L0.50 10.0 2570-13098.5 0.7139.85
Toluene g/L0.50 10.0 2570-13099.5 0.9009.95
1,2,3-Trichlorobenzene g/L0.50 10.0 2570-13099.5 2.449.95
1,2,4-Trichlorobenzene g/L0.50 10.0 2570-130101 0.59810.1
1,1,1-Trichloroethane g/L0.50 10.0 2570-13091.5 6.669.15
1,1,2-Trichloroethane g/L0.50 10.0 2570-13096.8 5.439.68
Trichloroethylene g/L1.0 10.0 2570-13092.0 6.019.20
Trichlorofluoromethane (Freon 11)g/L0.50 10.0 25 L-0270-130133 7.30*13.3
1,2,3-Trichloropropane g/L0.50 10.0 2570-13090.0 4.679.00
1,2,4-Trimethylbenzene g/L0.50 10.0 2570-13095.7 4.899.57
1,3,5-Trimethylbenzene g/L0.50 10.0 2570-13090.7 1.979.07
Vinyl Acetate g/L5.0 100 2570-13094.8 2.4094.8
Vinyl Chloride g/L0.50 10.0 2560-140102 0.68510.2
m+p Xylene g/L1.0 20.0 2570-13094.8 1.8319.0
o-Xylene g/L0.50 10.0 2570-13096.7 3.859.67
g/L 25.0 70-130Surrogate: 1,2-Dichloroethane-d4 98.224.6
g/L 25.0 70-130Surrogate: Toluene-d8 97.024.2
g/L 25.0 70-130Surrogate: 4-Bromofluorobenzene 88.222.0
Page 11 of 17
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
FLAG/QUALIFIER SUMMARY
*QC result is outside of established limits.
Wide recovery limits established for difficult compound.
Wide RPD limits established for difficult compound.
#Data exceeded client recommended or regulatory level
Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the
calculation which have not been rounded.
No results have been blank subtracted unless specified in the case narrative section.
RL Reporting Limit
DL Method Detection Limit
MCL Maximum Contaminant Level
ND Not Detected
Laboratory fortified blank/laboratory control sample recovery and duplicate recoveries outside of control limits.
Data validation is not affected since all results are "not detected" for associated samples in this batch and bias is
on the high side.
L-02
Laboratory fortified blank/laboratory control sample recovery and duplicate recovery are outside of control limits.
Reported value for this compound is likely to be biased on the low side.
L-04
Elevated reporting limit due to high concentration of target compounds.RL-11
[TOC_1]Flag/Qualifier Summary[TOC]
Page 12 of 17
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
SM21-22 6200B in Water
NCAcetone
NCBenzene
NCBromobenzene
NCBromochloromethane
NCBromodichloromethane
NCBromoform
NCBromomethane
NC2-Butanone (MEK)
NCn-Butylbenzene
NCsec-Butylbenzene
NCtert-Butylbenzene
NCCarbon Tetrachloride
NCChlorobenzene
NCEthanol
NCChlorodibromomethane
NCChloroethane
NCChloroform
NCChloromethane
NC2-Chlorotoluene
NC4-Chlorotoluene
NC1,2-Dibromoethane (EDB)
NC1,2-Dichlorobenzene
NC1,3-Dichlorobenzene
NC1,4-Dichlorobenzene
NCDichlorodifluoromethane (Freon 12)
NC1,1-Dichloroethane
NC1,2-Dichloroethane
NC1,1-Dichloroethylene
NCcis-1,2-Dichloroethylene
NCtrans-1,2-Dichloroethylene
NC1,2-Dichloropropane
NC1,3-Dichloropropane
NC2,2-Dichloropropane
NC1,1-Dichloropropene
NCcis-1,3-Dichloropropene
NCtrans-1,3-Dichloropropene
NCDiisopropyl Ether (DIPE)
NCEthylbenzene
NC2-Hexanone (MBK)
NCIsopropylbenzene (Cumene)
NCp-Isopropyltoluene (p-Cymene)
NCMethyl tert-Butyl Ether (MTBE)
NCMethylene Chloride
NC4-Methyl-2-pentanone (MIBK)
NCNaphthalene
NCn-Propylbenzene
NCStyrene
[TOC_1]Certifications[TOC]
Page 13 of 17
Table of Contents
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
SM21-22 6200B in Water
NC1,1,2,2-Tetrachloroethane
NCTetrachloroethylene
NCToluene
NC1,2,3-Trichlorobenzene
NC1,2,4-Trichlorobenzene
NC1,1,1-Trichloroethane
NC1,1,2-Trichloroethane
NCTrichloroethylene
NCTrichlorofluoromethane (Freon 11)
NC1,2,3-Trichloropropane
NC1,2,4-Trimethylbenzene
NC1,3,5-Trimethylbenzene
NCVinyl Acetate
NCVinyl Chloride
NCm+p Xylene
NCo-Xylene
The CON-TEST Environmental Laboratory operates under the following certifications and accreditations:
Code Description Number Expires
100033AIHA-LAP, LLCAIHA 02/1/2018
M-MA100Massachusetts DEPMA 06/30/2016
PH-0567Connecticut Department of Publilc HealthCT 09/30/2017
10899 NELAPNew York State Department of HealthNY 04/1/2016
2516 NELAPNew Hampshire Environmental LabNH-S 02/5/2016
LAO00112Rhode Island Department of HealthRI 12/30/2016
652North Carolina Div. of Water QualityNC 12/31/2016
MA007 NELAPNew Jersey DEPNJ 06/30/2016
E871027 NELAPFlorida Department of HealthFL 06/30/2016
LL015036Vermont Department of Health Lead LaboratoryVT 07/30/2016
C2065State of Washington Department of EcologyWA 02/23/2016
2011028State of MaineME 06/9/2017
460217Commonwealth of VirginiaVA 12/14/2016
2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2016
Page 14 of 17
Table of Contents
Page 15 of 17
Table of Contents
xxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxx
Page 1 of 2
CLIENT NAME:RECEIVED BY:DATE:
1) Was the chain(s) of custody relinquished and signed?Yes X No
2) Does the chain agree with the samples?Yes X No
If not, explain:
3) Are all the samples in good condition?Yes X No
If not, explain:
4) How were the samples received:
On Ice X Direct from Sampling Ambient In Cooler(s)X
Were the samples received in Temperature Compliance of (2-6°C)?Yes X No N/A
Temperature °C by Temp blank Temperature °C by Temp gun 4
5) Are there Dissolved samples for the lab to filter?Yes No X
Who was notified _____________Date ____________Time ___________
6) Are there any RUSH or SHORT HOLDING TIME samples?Yes No X
Who was notified _____________Date ____________Time ___________
Permission to subcontract samples? Yes No
7) Location where samples are stored:(Walk-in clients only) if not already approved
Client Signature: _______________________
8) Do all samples have the proper Acid pH: Yes No N/A X
9) Do all samples have the proper Base pH: Yes No N/A X
10) Was the PC notified of any discrepancies with the CoC vs the samples: Yes N/A X
40 mL vials:# HCl 3 # Methanol Time and Date Frozen:
# Bisulfate # DI Water
# Thiosulfate UnpreservedRev. 4 August 2013
Doc# 277
Encore Other
Dissolved Oxygen bottle Other glass jar
Colisure / bacteria bottle Flashpoint bottle
40 mL Vial - type listed below 3 Perchlorate Kit
250 mL plastic SOC Kit
500 mL Plastic Plastic Bag / Ziploc
1 Liter Plastic 2 oz amber/clear jar
250 mL Amber (8oz amber)4 oz amber/clear jar
500 mL Amber 8 oz amber/clear jar
1 Liter Amber 16 oz amber
2/3/2016
No COC Incl.
Containers received at Con-Test
# of containers # of containers
39 Spruce St.
East Longmeadow, MA. 01028
P: 413-525-2332
F: 413-525-6405
www.contestlabs.com Sample Receipt Checklist
ATC-Raleigh RLF
Page 16 of 17
Table of Contents
Page 2 of 2
Login Sample Receipt Checklist
(Rejection Criteria Listing - Using Sample Acceptance Policy)
Any False statement will be brought to the attention of Client
Question Answer (True/False)Comment
T/F/NA
1) The cooler's custody seal, if present, is intact.
3) Samples were received on ice.
4) Cooler Temperature is acceptable.
5) Cooler Temperature is recorded.
6) COC is filled out in ink and legible.
7) COC is filled out with all pertinent information.
8) Field Sampler's name present on COC.
10) Samples are received within Holding Time.
11) Sample containers have legible labels.
12) Containers are not broken or leaking.
13) Air Cassettes are not broken/open.
14) Sample collection date/times are provided.
15) Appropriate sample containers are used.
16) Proper collection media used.
17) No headspace sample bottles are completely filled.
19) Trip blanks provided if applicable.
21) Samples do not require splitting or compositing.
Doc #277 Rev. 4 August 2013 Log-In Technician Initials: RLF
T
18) There is sufficient volume for all requsted
analyses, including any requested MS/MSDs.
N/A
T
T
Date/Time: 2/3/16 9:45
T
20) VOA sample vials do not have head space or
bubble is <6mm (1/4") in diameter.
T
Who notified of False statements? Date/Time:
T
T
N/A
T
T
T
9) There are no discrepancies between the
sample IDs on the container and the COC.
T
T
T
T
T
T
T
T
T
2) The cooler or samples do not appear to have
been compromised or tampered with.
Page 17 of 17
Table of Contents