Loading...
HomeMy WebLinkAbout12033 N Tryon Griffin Vapor Intrusion Evaluation 20130205 Vapor Intrusion Evaluation Former Ira Griffin & Sons Property 2205 and 2215 North Tryon Street Charlotte, North Carolina H&H Job No. CLT-300 February 5, 2013 Via Email February 5, 2013 NC DENR Brownfields Section 1314 Mallard Ridge Rd Tega Cay, SC 29708 Attn: Carolyn F. Minnich Re: Former Ira Griffin & Sons Property Vapor Intrusion Evaluation 2205 and 2215 North Tryon Street Charlotte, North Carolina H&H Job No. CLT-300 Dear Carolyn: This vapor intrusion evaluation was conducted to facilitate Brownfield planning. The 2.86-acre property consists of two buildings previously utilized as office and warehouse space. The buildings are currently vacant. Ira Griffin and Sons occupied the subject facility between 1983 and 2008 where they fabricated, assembled, and shipped textile manufacturing equipment. Prior to Ira Griffin & Sons, the property was utilized by Crawford Sprinkler System a trailer manufacturer, and a neon sign manufacturer. Step 1: Groundwater Screening Groundwater data collected in 2008 at the Former Ira Griffin & Sons Property and the adjacent Latimer property consisted of collecting six samples from temporary wells installed to a depth of approximately 30 ft below ground surface (bgs). Each well was constructed of a 1-inch diameter Schedule 40 PVC riser and a 15-ft length of 0.01-inch slot screen installed to bracket the water table. Groundwater was encountered at depths ranging between 17 and 19 ft bgs. Following depth-to-water measurement, each well was purged a minimum of one well volume using a peristaltic pump and dedicated tubing, and the water quality parameters (pH, conductivity, and temperature) were measured. After stabilization of the water quality parameters, ground water Carolyn F. Minnich February 5, 2013 Page 2 S:\AAA-Master Projects\City of Charlotte - CLT\CLT-300 Brownfield Grant Activities\North Tryon Vapor Intrusion Evaluations\Griffin Vapor Intrusion Evaluation\Griffin Vapor Intrusion Evaluation Text.docx samples were collected. All groundwater samples were analyzed for volatile organic compounds (VOCs) by EPA Method 6230D and polycyclic aromatic hydrocarbons (PAHs) by EPA Method 8270C. The three groundwater samples collected August 2008 were also analyzed for metals by EPA Method 6010B and 7470A/7471A. Following sampling, the temporary monitoring wells were properly abandoned. H&H compared the 2008 data with the current July 2012 IHSB Residential and Industrial/Commercial Vapor Intrusion Screening Criteria. The 2008 groundwater data and applicable screening criteria are shown on Table 1. A site map and sample location map are included as Figures 1 and 2, respectively. The groundwater samples collected from TMW-3 (179 µg/L), TMW-5 (55.3 µg/L), and TW-4 (43.9 µg/L) contained 1,1-DCE at concentrations exceeding the IHSB residential screening criteria. In addition, the concentration of 1,1-DCE from TMW-3 exceeded the IHSB industrial/commercial screening criteria. Step 2: Soil Vapor Assessment/Screening In the April 15, 2009 letter, DENR requested submittal of a work plan and collection of soil gas samples or subslab samples on the former Ira Griffin & Sons property and the adjacent Latimer property to determine if soil vapor poses a potential unacceptable risk to current or future site structures. H&H submitted a work plan for the soil vapor assessment on June 1, 2009. The work plan was subsequently approved with comments by DENR on June 22, 2009, which were incorporated into the sampling event. Two subsurface vapor points (VPs) labeled VP-3 and VP-5 and one subslab VP labeled VP-4 were installed on July 16, 2009 on the former Ira Griffin & Sons property. Sampling locations are depicted on Figure 2 and were installed on July 16, 2009 on the former Ira Griffin & Sons property. These locations corresponded with the previously discussed groundwater sample points. For the installation of VP-3 and VP-5, a hand auger was utilized to install a 3-inch diameter boring through the underlying soil to a depth of 5 feet below land surface (bls). A rotary Carolyn F. Minnich February 5, 2013 Page 3 S:\AAA-Master Projects\City of Charlotte - CLT\CLT-300 Brownfield Grant Activities\North Tryon Vapor Intrusion Evaluations\Griffin Vapor Intrusion Evaluation\Griffin Vapor Intrusion Evaluation Text.docx hammer drill was utilized to bore through the concrete slab at the VP-4 location. The building slab was observed to be approximately 6 inches thick at the VP-4 location and underlain by a gravel layer. A stainless steel AMS dedicated soil gas vapor point fitted with ¼-inch diameter Teflon tubing was installed into each borehole. With the exception of VP-4, the tip installed at this subsurface VP location was advanced to 5.5 feet bls. The tip installed at the VP-4 location was set approximately 1 to 2 inches beneath the slab using an AMS Gas Vapor Probe Kit and slide hammer. Filter sand was then poured through each borehole around the vapor point to approximately 4 to 6 inches above each subsurface point and approximately 5 inches below the top surface of the concrete slab at the VP-4 location. Each borehole was subsequently completed by installing hydrated bentonite from the top of the sand to the surface of the borehole. After allowing the bentonite to set for at least 24-hours in each borehole, H&H personnel collected vapor samples from VP-3 through VP-5 on July 17, 2009 using 6-liter Summa canisters. Prior to mobilizing to the site, the initial vacuum in each Summa canister was measured and recorded using a vacuum gauge provided by the lab. In the field, the following procedures were used to sample each VP. The VP was purged using a 60 mL syringe with a three-way valve to evacuate air in the probe annular space and tubing. After purging the VP, the Summa canister was connected to a flow regulator (set by the lab to limit the vapor intake rate to approximately 6-liters per hour) and the sample train was checked for leaks. Subsequently, the flow regulator was connected to the VP tubing using a ferrule to form an air-tight seal. The canister’s air intake valve was then opened to begin collection of the vapor sample. As approved by DENR in the June 2009 Work Plan, the samples were collected and analyzed for 1,2-DCA, cis-1,2-DCE, PCE, TCE, and vinyl chloride. However, the soil gas samples were not required to be analyzed for 1,1-DCE at that time. Subsequently, H&H requested the lab reissue the lab report to include 1,1-DCE. The lab report was revised and is included as Appendix A. The available analytical results, compared against the IHSB Residential and Carolyn F. Minnich February 5, 2013 Page 4 S:\AAA-Master Projects\City of Charlotte - CLT\CLT-300 Brownfield Grant Activities\North Tryon Vapor Intrusion Evaluations\Griffin Vapor Intrusion Evaluation\Griffin Vapor Intrusion Evaluation Text.docx Industrial/Commercial Vapor Intrusion screening criteria are provided on Table 2. PCE was detected in the samples from VP-4 and VP-5 at concentrations up to 50 µg/m3, which is below both the residential and industrial screening criteria for PCE. In addition, 1,1-DCE was detected in all three soil gas samples at concentrations up to 120 µg/mg3, which is below both the residential and industrial screening criteria for 1,1-DCE. Step 3: Indoor Air Sampling This step was not completed as available soil gas concentrations were not detected above applicable screening criteria. Step 4: Recommendations Based on the soil vapor results H&H does not recommend additional vapor intrusion assessment or mitigation at the Ira Griffin & Sons Property. Should you have any questions or require any additional information concerning this submittal, please feel free to contact me at (704) 586-0007. Sincerely, Hart & Hickman, PC Bruce Hickman Principal Engineer Attachments cc: David Wolfe, City of Charlotte (Electronic Copy) Cindy Nolan, US EPA (Hard Copy) Geoffrey Curme, Mount Vernon Asset Management, LLC (Hard and Electronic Copy) Peter McGrath, Moore & VanAllen (Electronic Copy) S:\AAA-Master Projects\City of Charlotte - CLT\CLT-300 Brownfield Grant Activities\North Tryon Vapor Intrusion Evaluations\Griffin Vapor Intrusion Evaluation\ 2008 Griffin Soil and GW Data 1/28/2013 Table 1 Hart & Hickman, PC Table 1 Summary of Groundwater Analytical Data Ira Griffin & Sons Property Charlotte, North Carolina H&H Project No. CLT-300 Sample ID TMW-3 TMW-4 TMW-5 TW-2 TW-3 TW-4 Date 6/25/08 6/25/08 6/25/08 8/8/08 8/8/08 8/8/08 1,1-Dichloroethane 2.94 <0.5 <0.5 <0.500 <0.500 1.50 65 330 1,2-Dichloroethane 1.37 <0.5 <0.5 <0.500 <0.500 <0.500 20 98 1,1-Dichloroethene (1,1-DCE)179 <0.5 55.3 1.21 1.19 43.9 38 160 cis-1,2-Dichloroethene <0.5 <0.5 <0.5 <0.500 <0.500 <0.500 NS NS Tetrachloroethene (PCE)<0.5 <0.5 0.790 <0.500 <0.500 <0.500 12 49 1,1,1-Trichloroethane 0.830 <0.5 0.720 <0.500 <0.500 <0.500 1,500 6,300 Trichloroethene (TCE)<0.5 <0.5 <0.5 <0.500 <0.500 <0.500 1.1 4.4 All Target Compounds ND ND ND ND ND ND ---- Barium NA NA NA 0.0844 0.566 0.475 NS NS Cadmium NA NA NA <0.00100 0.00160 0.00120 NS NS Chromium NA NA NA 0.00510 0.758 0.209 NS NS Notes: 1) NC DENR Inactive Hazardous Sites Branch (IHSB) Residential Vapor Intrusion Screening Levels (July 2012) 2) NC DENR IHSB Industrial/Commercial Vapor Intrusion Screening Levels (July 2012) 3) Has both carcinogenic and non-carcinogenic properties Only those compounds detected in at least one sample shown in above table. Bold indicates that concentration exceeds the residential screening levels. Bold and underlined indicates that concentration exceeds the industrial/commercial screening levels. VOCs=volatile organic compounds, PAHs = polycyclic aromatic hydrocarbons NA = Not Analyzed NS = Not Specified ND = Not Detected Total Metals (EPA Method 6010B and 7470A/7471A) mg/L IHSB Industrial/ Commercial Acceptable Groundwater Concentration 2 IHSB Residential Acceptable Groundwater Concentration 1 VOCs (EPA Method 8260B) µg/L PAHs (EPA Method 8270C) µg/L Table 2 Summary of Vapor Analytical Detections IRA Griffin Sons Property Charlotte, North Carolina Hart & Hickman Project No. CLT-300 S:\AAA-Master Projects\City of Charlotte - CLT\CLT-300 Brownfield Grant Activities\North Tryon Vapor Intrusion Evaluations\Griffin Vapor Intrusion Evaluation\ Soil Vapor Analytical DCE 10 30 2012 1/28/2013 Table 2 Hart & Hickman, PC1,1-Dichloroethene1,2-Dichloroethanecis-1,2-DichloroetheneTetrachloroetheneTrichloroetheneVinyl ChlorideVP-3 07/17/09 TO-15 120 <3.1 <3.0 <5.2 <4.1 <1.9 VP-4 07/17/09 TO-15 11 <3.0 <3.0 11 <4.0 <1.9 VP-5 07/17/09 TO-15 50 <3.2 <3.2 50 <4.3 <2.0 VP-5 (Dup)07/17/09 TO-15 32 <3.0 <3.0 32 <4.0 <1.9 1,760 47 NE 350 17.6 280 420 9.4 NE 83.4 4.2 16 TimeTemperature (oC)Initial 1130 29.2 Midpoint 1200 30.0Final124530.3 Notes: 1. NC DENR Inactive Hazardous Sites Branch Industrial/Commercial Vapor Intrusion Screening Table (July 2012) 2. NC DENR Inactive Hazardous Sites Branch Residential Vapor Intrusion Screening Table (July 2012)Bold value exceeds IHSB Residential Soil Gas Screening Level.Bold Underlined value exceeds IHSB Residential and Industrial/Commercial Soil Gas Screening Level. NE = Value not established µg/m3 IHSB Residential Vapor Intrusion Soil Gas Screening Level 2 Stage of SamplingVP-4 Ambient Air Temperature Meaurements Near Indoor VPs During Sample CollectionAnalytical MethodIHSB Industrial/Commercial Vapor Intrusion Soil Gas Screening Level 1Sample IDSampling Date (mm/dd/yy) 0 2000 4000 APPROXIMATE SCALE IN FEET N U.S.G.S. QUADRANGLE MAP QUADRANGLE 7.5 MINUTE SERIES (TOPOGRAPHIC) TITLE PROJECT SITE LOCATION MAP IRA GRIFFIN & SONS PROPERTY 2205 -2221 NORTH TRYON STREET CHARLOTTE, NORTH CAROLINA DATE: JOB NO: REVISION NO: FIGURE: 10-30-12 0 1 CLT-300 CHARLOTTE EAST, NC 1967 REVISED/INSPECTED 1988 DERITA, NC 1993 SITE   APP LABORA PENDIX A ATORY REPPORT 10/23/2012 Mr. Matt Ingalls Hart & Hickman 2923 South Tryon Street Suite 100 Charlotte NC 28203 Project Name: N. Tryon Hills Assemblege Project #: MVT-002 Dear Mr. Matt Ingalls The following report includes the data for the above referenced project for sample(s) received on 7/28/2009 at Air Toxics Ltd. The data and associated QC analyzed by Modified TO-15 are compliant with the project requirements or laboratory criteria with the exception of the deviations noted in the attached case narrative. Thank you for choosing Air Toxics Ltd. for your air analysis needs. Air Toxics Ltd. is committed to providing accurate data of the highest quality. Please feel free to contact the Project Manager: Ausha Scott at 916-985-1000 if you have any questions regarding the data in this report. Regards, Ausha Scott Project Manager Workorder #: 0907610R1 Page 1 of 13 Mr. Matt Ingalls Hart & Hickman 2923 South Tryon Street Suite 100 Charlotte, NC 28203 WORK ORDER #:0907610R1 CLIENT:BILL TO: PHONE: Accounts Payable Hart & Hickman 2923 South Tryon Street Suite 100 Charlotte, NC 28203 704-887-4617 704-586-0373 07/28/2009 DATE COMPLETED:08/12/2009 P.O. #MVT-002 PROJECT #MVT-002 N. Tryon Hills Assemblege Work Order Summary FAX: DATE RECEIVED: DATE REISSUED:10/23/2012 CONTACT:Ausha Scott NAMEFRACTION #TEST VAC./PRES. RECEIPT PRESSURE FINAL 01A VP-3 Modified TO-15 3.5 "Hg 5 psi 02A VP-4 Modified TO-15 3.0 "Hg 5 psi 02AA VP-4 Lab Duplicate Modified TO-15 3.0 "Hg 5 psi 03A VP-5 Modified TO-15 5.0 "Hg 5 psi 04A VP-5 (DUP)Modified TO-15 3.0 "Hg 5 psi 05A Lab Blank Modified TO-15 NA NA 06A CCV Modified TO-15 NA NA 07A LCS Modified TO-15 NA NA CERTIFIED BY: Technical Director DATE: Name of Accrediting Agency: NELAP/ORELAP (Oregon Environmental Laboratory Accreditation Program) Accreditation number: CA300005, Effective date: 10/18/2011, Expiration date: 10/17/2012. 180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 9563 (916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020 10/23/12 Page 2 of 13 This report shall not be reproduced, except in full, without the written approval of Eurofins Air Toxics, Inc. Eurofins Air Toxics Ltd. certifies that the test results contained in this report meet all requirements of the NELAC standards Certfication numbers: AZ Licensure AZ0775, CA NELAP - 12282CA, NY NELAP - 11291, TX NELAP - T104704434-12-5, UT NELAP CA009332012-3, WA NELAP - C935 LABORATORY NARRATIVEModified TO-15Hart & HickmanWorkorder# 0907610R1 Four 6 Liter Summa Canister samples were received on July 28, 2009. The laboratory performed analysis via modified EPA Method TO-15 using GC/MS in the full scan mode. This workorder was independently validated prior to submittal using 'USEPA National Functional Guidelines' as generally applied to the analysis of volatile organic compounds in air. A rules-based, logic driven, independent validation engine was employed to assess completeness, evaluate pass/fail of relevant project quality control requirements and verification of all quantified amounts. Method modifications taken to run these samples are summarized in the table below. Specific project requirements may over-ride the ATL modifications. Requirement ATL ModificationsTO-15 Daily CCV </= 30% Difference </= 30% Difference; Compounds exceeding this criterion and associated data are flagged and narrated. Sample collection media Summa canister ATL recommends use of summa canisters to insure data defensibility, but will report results from Tedlar bags at client request Method Detection Limit Follow 40CFR Pt.136 App. B The MDL met all relevant requirements in Method TO-15 (statistical MDL less than the LOQ). The concentration of the spiked replicate may have exceeded 10X the calculated MDL in some cases Receiving Notes Sample collection date was incomplete on the Chain of Custody (COC) for samples VP-4, VP-5 and VP-5 (DUP). The sampling date was taken from the tags. Tetrachloroethene in samples VP-5 and VP-5 (DUP) was outside of the 25% RPD crtieria for duplicate samples. These samples appear to be field duplcaies accroding to the COC. THE WORKORDER WAS REISSUED ON OCTOBER 23, 2012 TO REPORT 1,1-DICHLOROETHENE PER CLIENT'S REQUEST. Analytical Notes Eight qualifiers may have been used on the data analysis sheets and indicates as follows: B - Compound present in laboratory blank greater than reporting limit (background subtraction not performed). J - Estimated value. E - Exceeds instrument calibration range. Definition of Data Qualifying Flags Page 3 of 13 S - Saturated peak. Q - Exceeds quality control limits. U - Compound analyzed for but not detected above the reporting limit. UJ- Non-detected compound associated with low bias in the CCV and/or LCS. N - The identification is based on presumptive evidence. File extensions may have been used on the data analysis sheets and indicates as follows: a-File was requantified b-File was quantified by a second column and detector r1-File was requantified for the purpose of reissue Page 4 of 13 EPA METHOD TO-15 GC/MS FULL SCAN Summary of Detected Compounds Client Sample ID: VP-3 Lab ID#: 0907610R1-01A (ug/m3)(ug/m3)(ppbv)(ppbv)Compound AmountRpt. LimitAmountRpt. Limit 0.76 31 3.0 1201,1-Dichloroethene Client Sample ID: VP-4 Lab ID#: 0907610R1-02A (ug/m3)(ug/m3)(ppbv)(ppbv)Compound AmountRpt. LimitAmountRpt. Limit 0.74 1.7 5.0 11Tetrachloroethene Client Sample ID: VP-4 Lab Duplicate Lab ID#: 0907610R1-02AA (ug/m3)(ug/m3)(ppbv)(ppbv)Compound AmountRpt. LimitAmountRpt. Limit 0.74 1.7 5.0 11Tetrachloroethene Client Sample ID: VP-5 Lab ID#: 0907610R1-03A (ug/m3)(ug/m3)(ppbv)(ppbv)Compound AmountRpt. LimitAmountRpt. Limit 0.80 7.3 5.5 50Tetrachloroethene Client Sample ID: VP-5 (DUP) Lab ID#: 0907610R1-04A (ug/m3)(ug/m3)(ppbv)(ppbv)Compound AmountRpt. LimitAmountRpt. Limit 0.74 4.6 5.0 32Tetrachloroethene Page 5 of 13 Client Sample ID: VP-3 Lab ID#: 0907610R1-01A EPA METHOD TO-15 GC/MS FULL SCAN e080408r1File Name: Dil. Factor:1.52 Date of Collection: 7/17/09 12:30:00 PM Date of Analysis: 8/4/09 02:24 PM (ug/m3)(ug/m3)(ppbv)(ppbv)Compound AmountRpt. LimitAmountRpt. Limit 0.76 Not Detected 1.9 Not DetectedVinyl Chloride 0.76 31 3.0 1201,1-Dichloroethene 0.76 Not Detected 3.0 Not Detectedcis-1,2-Dichloroethene 0.76 Not Detected 3.1 Not Detected1,2-Dichloroethane 0.76 Not Detected 4.1 Not DetectedTrichloroethene 0.76 Not Detected 5.2 Not DetectedTetrachloroethene Container Type: 6 Liter Summa Canister Limits%RecoverySurrogates Method 100 70-1301,2-Dichloroethane-d4 100 70-130Toluene-d8 102 70-1304-Bromofluorobenzene Page 6 of 13 Client Sample ID: VP-4 Lab ID#: 0907610R1-02A EPA METHOD TO-15 GC/MS FULL SCAN e080409r1File Name: Dil. Factor:1.49 Date of Collection: 7/17/09 12:45:00 PM Date of Analysis: 8/4/09 03:14 PM (ug/m3)(ug/m3)(ppbv)(ppbv)Compound AmountRpt. LimitAmountRpt. Limit 0.74 Not Detected 1.9 Not DetectedVinyl Chloride 0.74 Not Detected 3.0 Not Detected1,1-Dichloroethene 0.74 Not Detected 3.0 Not Detectedcis-1,2-Dichloroethene 0.74 Not Detected 3.0 Not Detected1,2-Dichloroethane 0.74 Not Detected 4.0 Not DetectedTrichloroethene 0.74 1.7 5.0 11Tetrachloroethene Container Type: 6 Liter Summa Canister Limits%RecoverySurrogates Method 99 70-1301,2-Dichloroethane-d4 99 70-130Toluene-d8 101 70-1304-Bromofluorobenzene Page 7 of 13 Client Sample ID: VP-4 Lab Duplicate Lab ID#: 0907610R1-02AA EPA METHOD TO-15 GC/MS FULL SCAN e080425r1File Name: Dil. Factor:1.49 Date of Collection: 7/17/09 12:45:00 PM Date of Analysis: 8/5/09 07:43 AM (ug/m3)(ug/m3)(ppbv)(ppbv)Compound AmountRpt. LimitAmountRpt. Limit 0.74 Not Detected 1.9 Not DetectedVinyl Chloride 0.74 Not Detected 3.0 Not Detected1,1-Dichloroethene 0.74 Not Detected 3.0 Not Detectedcis-1,2-Dichloroethene 0.74 Not Detected 3.0 Not Detected1,2-Dichloroethane 0.74 Not Detected 4.0 Not DetectedTrichloroethene 0.74 1.7 5.0 11Tetrachloroethene Container Type: 6 Liter Summa Canister Limits%RecoverySurrogates Method 96 70-1301,2-Dichloroethane-d4 99 70-130Toluene-d8 101 70-1304-Bromofluorobenzene Page 8 of 13 Client Sample ID: VP-5 Lab ID#: 0907610R1-03A EPA METHOD TO-15 GC/MS FULL SCAN e080410r1File Name: Dil. Factor:1.61 Date of Collection: 7/17/09 12:20:00 PM Date of Analysis: 8/4/09 04:04 PM (ug/m3)(ug/m3)(ppbv)(ppbv)Compound AmountRpt. LimitAmountRpt. Limit 0.80 Not Detected 2.0 Not DetectedVinyl Chloride 0.80 Not Detected 3.2 Not Detected1,1-Dichloroethene 0.80 Not Detected 3.2 Not Detectedcis-1,2-Dichloroethene 0.80 Not Detected 3.2 Not Detected1,2-Dichloroethane 0.80 Not Detected 4.3 Not DetectedTrichloroethene 0.80 7.3 5.5 50Tetrachloroethene Container Type: 6 Liter Summa Canister Limits%RecoverySurrogates Method 92 70-1301,2-Dichloroethane-d4 101 70-130Toluene-d8 94 70-1304-Bromofluorobenzene Page 9 of 13 Client Sample ID: VP-5 (DUP) Lab ID#: 0907610R1-04A EPA METHOD TO-15 GC/MS FULL SCAN e080423r1File Name: Dil. Factor:1.49 Date of Collection: 7/17/09 12:20:00 PM Date of Analysis: 8/5/09 06:16 AM (ug/m3)(ug/m3)(ppbv)(ppbv)Compound AmountRpt. LimitAmountRpt. Limit 0.74 Not Detected 1.9 Not DetectedVinyl Chloride 0.74 Not Detected 3.0 Not Detected1,1-Dichloroethene 0.74 Not Detected 3.0 Not Detectedcis-1,2-Dichloroethene 0.74 Not Detected 3.0 Not Detected1,2-Dichloroethane 0.74 Not Detected 4.0 Not DetectedTrichloroethene 0.74 4.6 5.0 32Tetrachloroethene Container Type: 6 Liter Summa Canister Limits%RecoverySurrogates Method 93 70-1301,2-Dichloroethane-d4 100 70-130Toluene-d8 97 70-1304-Bromofluorobenzene Page 10 of 13 Client Sample ID: Lab Blank Lab ID#: 0907610R1-05A EPA METHOD TO-15 GC/MS FULL SCAN e080405File Name: Dil. Factor:1.00 Date of Collection: NA Date of Analysis: 8/4/09 12:08 PM (ug/m3)(ug/m3)(ppbv)(ppbv)Compound AmountRpt. LimitAmountRpt. Limit 0.50 Not Detected 1.3 Not DetectedVinyl Chloride 0.50 Not Detected 2.0 Not Detected1,1-Dichloroethene 0.50 Not Detected 2.0 Not Detectedcis-1,2-Dichloroethene 0.50 Not Detected 2.0 Not Detected1,2-Dichloroethane 0.50 Not Detected 2.7 Not DetectedTrichloroethene 0.50 Not Detected 3.4 Not DetectedTetrachloroethene Container Type: NA - Not Applicable Limits%RecoverySurrogates Method 97 70-1301,2-Dichloroethane-d4 98 70-130Toluene-d8 102 70-1304-Bromofluorobenzene Page 11 of 13 Client Sample ID: CCV Lab ID#: 0907610R1-06A EPA METHOD TO-15 GC/MS FULL SCAN e080403File Name: Dil. Factor:1.00 Date of Collection: NA Date of Analysis: 8/4/09 10:44 AM %RecoveryCompound 84Vinyl Chloride 861,1-Dichloroethene 87cis-1,2-Dichloroethene 861,2-Dichloroethane 87Trichloroethene 84Tetrachloroethene Container Type: NA - Not Applicable Limits%RecoverySurrogates Method 98 70-1301,2-Dichloroethane-d4 101 70-130Toluene-d8 101 70-1304-Bromofluorobenzene Page 12 of 13 Client Sample ID: LCS Lab ID#: 0907610R1-07A EPA METHOD TO-15 GC/MS FULL SCAN e080404File Name: Dil. Factor:1.00 Date of Collection: NA Date of Analysis: 8/4/09 11:25 AM %RecoveryCompound 97Vinyl Chloride 1131,1-Dichloroethene 103cis-1,2-Dichloroethene 1001,2-Dichloroethane 101Trichloroethene 101Tetrachloroethene Container Type: NA - Not Applicable Limits%RecoverySurrogates Method 98 70-1301,2-Dichloroethane-d4 99 70-130Toluene-d8 100 70-1304-Bromofluorobenzene Page 13 of 13