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GWMR-11-30-14 92p
11/19/14 Technical Report for GRI (Geological Resources Inc.) Cannady's; 3963 NC Hwy 24, Bonnetsville, NC 3136 Accutest Job Number: FA19734 Sampling Date: 11/05/14 Report to: GRI 3502 Hayes Rd Monroe, NC 28110 nml@geologicalresourcesinc.com; carriekennedy@geologicalresourcesinc.com; jjr@geologicalresourcesinc.com ATTN: Nicole Long Total number of pages in report: Certifications: FL (E83510), LA (03051), KS (E-10327), IA (366), IL (200063), NC (573), NJ (FL002), SC (96038001) DoD ELAP (L-A-B L2229), CA (2937), TX (T104704404), PA (68-03573), VA (460177), AK, AR, GA, KY, MA, NV, OK, UT, WA This report shall not be reproduced, except in its entirety, without the written approval of Accutest Laboratories. Test results relate only to samples analyzed. Southeast • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: 407-425-6700 • fax: 407-425-0707 • http://www.accutest.com Test results contained within this data package meet the requirements of the National Environmental Laboratory Accreditation Program and/or state specific certification programs as applicable. Client Service contact: Muna Mohammed 407-425-6700 Norm Farmer Technical Director Southeast 11/19/14 e-Hardcopy 2.0 Automated Report 55 Accutest Laboratories is the sole authority for authorizing edits or modifications to this document. Unauthorized modification of this report is strictly prohibited. 1 of 55 FA19734 Table of Contents -1- Sections: Section 1: Sample Summary ...................................................................................................3 Section 2: Summary of Hits ....................................................................................................4 Section 3: Sample Results ........................................................................................................6 3.1: FA19734-1: MW-4 ........................................................................................................7 3.2: FA19734-2: MW-6 ........................................................................................................10 3.3: FA19734-3: MW-7 ........................................................................................................13 3.4: FA19734-4: MW-9 ........................................................................................................16 3.5: FA19734-5: MW-13 ......................................................................................................19 3.6: FA19734-6: MW-14 ......................................................................................................22 3.7: FA19734-7: MW-15 ......................................................................................................25 3.8: FA19734-8: MW-17 ......................................................................................................28 3.9: FA19734-9: RW-1 .........................................................................................................31 3.10: FA19734-10: WSW-8 .................................................................................................34 Section 4: Misc. Forms ............................................................................................................35 4.1: Chain of Custody ...........................................................................................................36 Section 5: GC/MS Volatiles - QC Data Summaries ..............................................................39 5.1: Method Blank Summary ................................................................................................40 5.2: Blank Spike Summary ...................................................................................................43 5.3: Matrix Spike Summary ..................................................................................................46 5.4: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................48 Section 6: Metals Analysis - QC Data Summaries ................................................................49 6.1: Prep QC MP28182: Pb ..................................................................................................50 1 2 3 4 5 6 2 of 55 FA19734 Accutest Laboratories Sample Summary GRI (Geological Resources Inc.) Job No:FA19734 Cannady's; 3963 NC Hwy 24, Bonnetsville, NC Project No: 3136 Sample Collected Matrix Client Number Date Time By Received Code Type Sample ID FA19734-1 11/05/14 13:14 DB 11/06/14 AQ Ground Water MW-4 FA19734-2 11/05/14 12:14 DB 11/06/14 AQ Ground Water MW-6 FA19734-3 11/05/14 12:28 DB 11/06/14 AQ Ground Water MW-7 FA19734-4 11/05/14 15:03 DB 11/06/14 AQ Ground Water MW-9 FA19734-5 11/05/14 14:49 DB 11/06/14 AQ Ground Water MW-13 FA19734-6 11/05/14 12:59 DB 11/06/14 AQ Ground Water MW-14 FA19734-7 11/05/14 14:26 DB 11/06/14 AQ Ground Water MW-15 FA19734-8 11/05/14 14:06 DB 11/06/14 AQ Ground Water MW-17 FA19734-9 11/05/14 13:51 DB 11/06/14 AQ Ground Water RW-1 FA19734-10 11/05/14 13:33 DB 11/06/14 AQ Ground Water WSW-8 3 of 55 FA19734 1 Summary of Hits Page 1 of 2 Job Number:FA19734 Account:GRI (Geological Resources Inc.) Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC Collected:11/05/14 Lab Sample ID Client Sample ID Result/ Analyte Qual RL MDL Units Method FA19734-1 MW-4 Lead 19.7 5.0 ug/l SW846 6010C FA19734-2 MW-6 Lead 7.6 5.0 ug/l SW846 6010C FA19734-3 MW-7 Lead 103 5.0 ug/l SW846 6010C FA19734-4 MW-9 n-Butylbenzene 35.2 J 50 10 ug/l SM 6200B sec-Butylbenzene 20.5 J 50 10 ug/l SM 6200B Ethylbenzene 1160 50 10 ug/l SM 6200B Isopropylbenzene 106 50 10 ug/l SM 6200B p-Isopropyltoluene 10.9 J 50 10 ug/l SM 6200B Naphthalene 529 50 10 ug/l SM 6200B n-Propylbenzene 412 50 10 ug/l SM 6200B Styrene 16.3 J 50 10 ug/l SM 6200B 1,2,4-Trimethylbenzene 2740 50 10 ug/l SM 6200B 1,3,5-Trimethylbenzene 786 50 10 ug/l SM 6200B Toluene 2070 50 10 ug/l SM 6200B m,p-Xylene 4060 100 10 ug/l SM 6200B o-Xylene 1690 50 10 ug/l SM 6200B Lead 37.9 5.0 ug/l SW846 6010C FA19734-5 MW-13 Lead 6.7 5.0 ug/l SW846 6010C FA19734-6 MW-14 Lead 10.9 5.0 ug/l SW846 6010C FA19734-7 MW-15 Lead 1250 5.0 ug/l SW846 6010C FA19734-8 MW-17 Benzene 38.4 2.5 0.50 ug/l SM 6200B Chloroethane 2.4 J 2.5 0.61 ug/l SM 6200B 4 of 55 FA19734 2 Summary of Hits Page 2 of 2 Job Number:FA19734 Account:GRI (Geological Resources Inc.) Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC Collected:11/05/14 Lab Sample ID Client Sample ID Result/ Analyte Qual RL MDL Units Method Ethylbenzene 90.1 2.5 0.50 ug/l SM 6200B Isopropylbenzene 4.0 2.5 0.50 ug/l SM 6200B Naphthalene 32.8 2.5 0.50 ug/l SM 6200B n-Propylbenzene 8.5 2.5 0.50 ug/l SM 6200B Styrene 1.2 J 2.5 0.50 ug/l SM 6200B 1,2,4-Trimethylbenzene 90.4 2.5 0.50 ug/l SM 6200B 1,3,5-Trimethylbenzene 23.0 2.5 0.50 ug/l SM 6200B Toluene 586 13 2.5 ug/l SM 6200B Xylene (total)749 38 5.0 ug/l SM 6200B m,p-Xylene 460 25 2.5 ug/l SM 6200B o-Xylene 290 13 2.5 ug/l SM 6200B Lead 3420 5.0 ug/l SW846 6010C FA19734-9 RW-1 Benzene a 14.1 2.5 0.50 ug/l SM 6200B n-Butylbenzene a 4.4 2.5 0.50 ug/l SM 6200B sec-Butylbenzene a 3.9 2.5 0.50 ug/l SM 6200B Chloroethane a 2.5 2.5 0.61 ug/l SM 6200B Ethylbenzene a 200 2.5 0.50 ug/l SM 6200B Isopropylbenzene a 20.4 2.5 0.50 ug/l SM 6200B Methyl chloride a 1.9 J 2.5 0.50 ug/l SM 6200B Methylene chloride a 13.6 10 5.0 ug/l SM 6200B Naphthalene a 66.3 2.5 0.50 ug/l SM 6200B n-Propylbenzene a 49.9 2.5 0.50 ug/l SM 6200B 1,2,4-Trimethylbenzene a 136 2.5 0.50 ug/l SM 6200B 1,3,5-Trimethylbenzene a 14.7 2.5 0.50 ug/l SM 6200B Toluene a 5.5 2.5 0.50 ug/l SM 6200B m,p-Xylene a 184 5.0 0.50 ug/l SM 6200B o-Xylene a 9.2 2.5 0.50 ug/l SM 6200B FA19734-10 WSW-8 Methyl Tert Butyl Ether 0.25 J 0.50 0.10 ug/l SM 6200B (a) Internal standard areas outside method criteria. 5 of 55 FA19734 2 Accutest Laboratories Sample Results Report of Analysis Southeast Section 3 6 of 55 FA19734 3 Accutest Laboratories Report of Analysis Page 1 of 2 Client Sample ID:MW-4 Lab Sample ID:FA19734-1 Date Sampled:11/05/14 Matrix:AQ - Ground Water Date Received:11/06/14 Method:SM 6200B Percent Solids:n/a Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 A0190492.D 1 11/17/14 EG n/a n/a VA1582 Run #2 Purge Volume Run #1 10.0 ml Run #2 VOA 6200B List CAS No.Compound Result RL MDL Units Q 71-43-2 Benzene ND 0.50 0.10 ug/l 108-86-1 Bromobenzene ND 0.50 0.10 ug/l 74-97-5 Bromochloromethane ND 0.50 0.10 ug/l 75-27-4 Bromodichloromethane ND 0.50 0.10 ug/l 75-25-2 Bromoform ND 0.50 0.10 ug/l 104-51-8 n-Butylbenzene ND 0.50 0.10 ug/l 135-98-8 sec-Butylbenzene ND 0.50 0.10 ug/l 98-06-6 tert-Butylbenzene ND 0.50 0.10 ug/l 108-90-7 Chlorobenzene ND 0.50 0.10 ug/l 75-00-3 Chloroethane ND 0.50 0.12 ug/l 67-66-3 Chloroform ND 0.50 0.10 ug/l 95-49-8 o-Chlorotoluene ND 0.50 0.10 ug/l 106-43-4 p-Chlorotoluene ND 0.50 0.10 ug/l 56-23-5 Carbon tetrachloride ND 0.50 0.10 ug/l 75-34-3 1,1-Dichloroethane ND 0.50 0.10 ug/l 75-35-4 1,1-Dichloroethylene a ND 0.50 0.10 ug/l 563-58-6 1,1-Dichloropropene ND 0.50 0.10 ug/l 96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.17 ug/l 106-93-4 1,2-Dibromoethane ND 0.50 0.10 ug/l 107-06-2 1,2-Dichloroethane ND 0.50 0.10 ug/l 78-87-5 1,2-Dichloropropane ND 0.50 0.10 ug/l 142-28-9 1,3-Dichloropropane ND 0.50 0.10 ug/l 108-20-3 Di-Isopropyl ether ND 0.50 0.10 ug/l 594-20-7 2,2-Dichloropropane ND 0.50 0.10 ug/l 124-48-1 Dibromochloromethane ND 0.50 0.10 ug/l 75-71-8 Dichlorodifluoromethane ND 0.50 0.10 ug/l 156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.10 ug/l 10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.10 ug/l 541-73-1 m-Dichlorobenzene ND 0.50 0.10 ug/l 95-50-1 o-Dichlorobenzene ND 0.50 0.10 ug/l 106-46-7 p-Dichlorobenzene ND 0.50 0.10 ug/l 156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.10 ug/l ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 7 of 55 FA19734 3 3 . 1 Accutest Laboratories Report of Analysis Page 2 of 2 Client Sample ID:MW-4 Lab Sample ID:FA19734-1 Date Sampled:11/05/14 Matrix:AQ - Ground Water Date Received:11/06/14 Method:SM 6200B Percent Solids:n/a Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC VOA 6200B List CAS No.Compound Result RL MDL Units Q 10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.10 ug/l 100-41-4 Ethylbenzene ND 0.50 0.10 ug/l 87-68-3 Hexachlorobutadiene ND 0.50 0.10 ug/l 98-82-8 Isopropylbenzene ND 0.50 0.10 ug/l 99-87-6 p-Isopropyltoluene ND 0.50 0.10 ug/l 74-83-9 Methyl bromide ND 0.50 0.10 ug/l 74-87-3 Methyl chloride ND 0.50 0.10 ug/l 74-95-3 Methylene bromide ND 0.50 0.10 ug/l 75-09-2 Methylene chloride ND 2.0 1.0 ug/l 1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.10 ug/l 91-20-3 Naphthalene ND 0.50 0.10 ug/l 103-65-1 n-Propylbenzene ND 0.50 0.10 ug/l 100-42-5 Styrene ND 0.50 0.10 ug/l 630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.10 ug/l 71-55-6 1,1,1-Trichloroethane ND 0.50 0.10 ug/l 79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.10 ug/l 79-00-5 1,1,2-Trichloroethane ND 0.50 0.11 ug/l 87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.10 ug/l 96-18-4 1,2,3-Trichloropropane ND 0.50 0.12 ug/l 120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.10 ug/l 95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.10 ug/l 108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.10 ug/l 127-18-4 Tetrachloroethylene ND 0.50 0.10 ug/l 108-88-3 Toluene ND 0.50 0.10 ug/l 79-01-6 Trichloroethylene ND 0.50 0.10 ug/l 75-69-4 Trichlorofluoromethane a ND 0.50 0.10 ug/l 75-01-4 Vinyl chloride ND 0.50 0.10 ug/l 1330-20-7 Xylene (total)ND 1.5 0.20 ug/l m,p-Xylene ND 1.0 0.10 ug/l 95-47-6 o-Xylene ND 0.50 0.10 ug/l CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits 1868-53-7 Dibromofluoromethane 108%70-130% 17060-07-0 1,2-Dichloroethane-D4 113%70-130% 2037-26-5 Toluene-D8 93%70-130% 460-00-4 4-Bromofluorobenzene 97%70-130% (a) Associated BS recovery outside control limits. ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 8 of 55 FA19734 3 3 . 1 Accutest Laboratories Report of Analysis Page 1 of 1 Client Sample ID:MW-4 Lab Sample ID:FA19734-1 Date Sampled:11/05/14 Matrix:AQ - Ground Water Date Received:11/06/14 Percent Solids:n/a Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC Total Metals Analysis Analyte Result RL Units DF Prep Analyzed By Method Prep Method Lead 19.7 5.0 ug/l 1 11/10/14 11/10/14 LM SW846 6010C 1 SW846 3010A 2 (1) Instrument QC Batch: MA12024 (2) Prep QC Batch: MP28182 RL = Reporting Limit 9 of 55 FA19734 3 3 . 1 Accutest Laboratories Report of Analysis Page 1 of 2 Client Sample ID:MW-6 Lab Sample ID:FA19734-2 Date Sampled:11/05/14 Matrix:AQ - Ground Water Date Received:11/06/14 Method:SM 6200B Percent Solids:n/a Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 A0190493.D 1 11/17/14 EG n/a n/a VA1582 Run #2 Purge Volume Run #1 10.0 ml Run #2 VOA 6200B List CAS No.Compound Result RL MDL Units Q 71-43-2 Benzene ND 0.50 0.10 ug/l 108-86-1 Bromobenzene ND 0.50 0.10 ug/l 74-97-5 Bromochloromethane ND 0.50 0.10 ug/l 75-27-4 Bromodichloromethane ND 0.50 0.10 ug/l 75-25-2 Bromoform ND 0.50 0.10 ug/l 104-51-8 n-Butylbenzene ND 0.50 0.10 ug/l 135-98-8 sec-Butylbenzene ND 0.50 0.10 ug/l 98-06-6 tert-Butylbenzene ND 0.50 0.10 ug/l 108-90-7 Chlorobenzene ND 0.50 0.10 ug/l 75-00-3 Chloroethane ND 0.50 0.12 ug/l 67-66-3 Chloroform ND 0.50 0.10 ug/l 95-49-8 o-Chlorotoluene ND 0.50 0.10 ug/l 106-43-4 p-Chlorotoluene ND 0.50 0.10 ug/l 56-23-5 Carbon tetrachloride ND 0.50 0.10 ug/l 75-34-3 1,1-Dichloroethane ND 0.50 0.10 ug/l 75-35-4 1,1-Dichloroethylene a ND 0.50 0.10 ug/l 563-58-6 1,1-Dichloropropene ND 0.50 0.10 ug/l 96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.17 ug/l 106-93-4 1,2-Dibromoethane ND 0.50 0.10 ug/l 107-06-2 1,2-Dichloroethane ND 0.50 0.10 ug/l 78-87-5 1,2-Dichloropropane ND 0.50 0.10 ug/l 142-28-9 1,3-Dichloropropane ND 0.50 0.10 ug/l 108-20-3 Di-Isopropyl ether ND 0.50 0.10 ug/l 594-20-7 2,2-Dichloropropane ND 0.50 0.10 ug/l 124-48-1 Dibromochloromethane ND 0.50 0.10 ug/l 75-71-8 Dichlorodifluoromethane ND 0.50 0.10 ug/l 156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.10 ug/l 10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.10 ug/l 541-73-1 m-Dichlorobenzene ND 0.50 0.10 ug/l 95-50-1 o-Dichlorobenzene ND 0.50 0.10 ug/l 106-46-7 p-Dichlorobenzene ND 0.50 0.10 ug/l 156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.10 ug/l ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 10 of 55 FA19734 3 3 . 2 Accutest Laboratories Report of Analysis Page 2 of 2 Client Sample ID:MW-6 Lab Sample ID:FA19734-2 Date Sampled:11/05/14 Matrix:AQ - Ground Water Date Received:11/06/14 Method:SM 6200B Percent Solids:n/a Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC VOA 6200B List CAS No.Compound Result RL MDL Units Q 10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.10 ug/l 100-41-4 Ethylbenzene ND 0.50 0.10 ug/l 87-68-3 Hexachlorobutadiene ND 0.50 0.10 ug/l 98-82-8 Isopropylbenzene ND 0.50 0.10 ug/l 99-87-6 p-Isopropyltoluene ND 0.50 0.10 ug/l 74-83-9 Methyl bromide ND 0.50 0.10 ug/l 74-87-3 Methyl chloride ND 0.50 0.10 ug/l 74-95-3 Methylene bromide ND 0.50 0.10 ug/l 75-09-2 Methylene chloride ND 2.0 1.0 ug/l 1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.10 ug/l 91-20-3 Naphthalene ND 0.50 0.10 ug/l 103-65-1 n-Propylbenzene ND 0.50 0.10 ug/l 100-42-5 Styrene ND 0.50 0.10 ug/l 630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.10 ug/l 71-55-6 1,1,1-Trichloroethane ND 0.50 0.10 ug/l 79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.10 ug/l 79-00-5 1,1,2-Trichloroethane ND 0.50 0.11 ug/l 87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.10 ug/l 96-18-4 1,2,3-Trichloropropane ND 0.50 0.12 ug/l 120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.10 ug/l 95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.10 ug/l 108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.10 ug/l 127-18-4 Tetrachloroethylene ND 0.50 0.10 ug/l 108-88-3 Toluene ND 0.50 0.10 ug/l 79-01-6 Trichloroethylene ND 0.50 0.10 ug/l 75-69-4 Trichlorofluoromethane a ND 0.50 0.10 ug/l 75-01-4 Vinyl chloride ND 0.50 0.10 ug/l 1330-20-7 Xylene (total)ND 1.5 0.20 ug/l m,p-Xylene ND 1.0 0.10 ug/l 95-47-6 o-Xylene ND 0.50 0.10 ug/l CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits 1868-53-7 Dibromofluoromethane 110%70-130% 17060-07-0 1,2-Dichloroethane-D4 114%70-130% 2037-26-5 Toluene-D8 92%70-130% 460-00-4 4-Bromofluorobenzene 98%70-130% (a) Associated BS recovery outside control limits. ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 11 of 55 FA19734 3 3 . 2 Accutest Laboratories Report of Analysis Page 1 of 1 Client Sample ID:MW-6 Lab Sample ID:FA19734-2 Date Sampled:11/05/14 Matrix:AQ - Ground Water Date Received:11/06/14 Percent Solids:n/a Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC Total Metals Analysis Analyte Result RL Units DF Prep Analyzed By Method Prep Method Lead 7.6 5.0 ug/l 1 11/10/14 11/10/14 LM SW846 6010C 1 SW846 3010A 2 (1) Instrument QC Batch: MA12024 (2) Prep QC Batch: MP28182 RL = Reporting Limit 12 of 55 FA19734 3 3 . 2 Accutest Laboratories Report of Analysis Page 1 of 2 Client Sample ID:MW-7 Lab Sample ID:FA19734-3 Date Sampled:11/05/14 Matrix:AQ - Ground Water Date Received:11/06/14 Method:SM 6200B Percent Solids:n/a Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 A0190494.D 1 11/17/14 EG n/a n/a VA1582 Run #2 Purge Volume Run #1 10.0 ml Run #2 VOA 6200B List CAS No.Compound Result RL MDL Units Q 71-43-2 Benzene ND 0.50 0.10 ug/l 108-86-1 Bromobenzene ND 0.50 0.10 ug/l 74-97-5 Bromochloromethane ND 0.50 0.10 ug/l 75-27-4 Bromodichloromethane ND 0.50 0.10 ug/l 75-25-2 Bromoform ND 0.50 0.10 ug/l 104-51-8 n-Butylbenzene ND 0.50 0.10 ug/l 135-98-8 sec-Butylbenzene ND 0.50 0.10 ug/l 98-06-6 tert-Butylbenzene ND 0.50 0.10 ug/l 108-90-7 Chlorobenzene ND 0.50 0.10 ug/l 75-00-3 Chloroethane ND 0.50 0.12 ug/l 67-66-3 Chloroform ND 0.50 0.10 ug/l 95-49-8 o-Chlorotoluene ND 0.50 0.10 ug/l 106-43-4 p-Chlorotoluene ND 0.50 0.10 ug/l 56-23-5 Carbon tetrachloride ND 0.50 0.10 ug/l 75-34-3 1,1-Dichloroethane ND 0.50 0.10 ug/l 75-35-4 1,1-Dichloroethylene a ND 0.50 0.10 ug/l 563-58-6 1,1-Dichloropropene ND 0.50 0.10 ug/l 96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.17 ug/l 106-93-4 1,2-Dibromoethane ND 0.50 0.10 ug/l 107-06-2 1,2-Dichloroethane ND 0.50 0.10 ug/l 78-87-5 1,2-Dichloropropane ND 0.50 0.10 ug/l 142-28-9 1,3-Dichloropropane ND 0.50 0.10 ug/l 108-20-3 Di-Isopropyl ether ND 0.50 0.10 ug/l 594-20-7 2,2-Dichloropropane ND 0.50 0.10 ug/l 124-48-1 Dibromochloromethane ND 0.50 0.10 ug/l 75-71-8 Dichlorodifluoromethane ND 0.50 0.10 ug/l 156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.10 ug/l 10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.10 ug/l 541-73-1 m-Dichlorobenzene ND 0.50 0.10 ug/l 95-50-1 o-Dichlorobenzene ND 0.50 0.10 ug/l 106-46-7 p-Dichlorobenzene ND 0.50 0.10 ug/l 156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.10 ug/l ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 13 of 55 FA19734 3 3 . 3 Accutest Laboratories Report of Analysis Page 2 of 2 Client Sample ID:MW-7 Lab Sample ID:FA19734-3 Date Sampled:11/05/14 Matrix:AQ - Ground Water Date Received:11/06/14 Method:SM 6200B Percent Solids:n/a Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC VOA 6200B List CAS No.Compound Result RL MDL Units Q 10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.10 ug/l 100-41-4 Ethylbenzene ND 0.50 0.10 ug/l 87-68-3 Hexachlorobutadiene ND 0.50 0.10 ug/l 98-82-8 Isopropylbenzene ND 0.50 0.10 ug/l 99-87-6 p-Isopropyltoluene ND 0.50 0.10 ug/l 74-83-9 Methyl bromide ND 0.50 0.10 ug/l 74-87-3 Methyl chloride ND 0.50 0.10 ug/l 74-95-3 Methylene bromide ND 0.50 0.10 ug/l 75-09-2 Methylene chloride ND 2.0 1.0 ug/l 1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.10 ug/l 91-20-3 Naphthalene ND 0.50 0.10 ug/l 103-65-1 n-Propylbenzene ND 0.50 0.10 ug/l 100-42-5 Styrene ND 0.50 0.10 ug/l 630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.10 ug/l 71-55-6 1,1,1-Trichloroethane ND 0.50 0.10 ug/l 79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.10 ug/l 79-00-5 1,1,2-Trichloroethane ND 0.50 0.11 ug/l 87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.10 ug/l 96-18-4 1,2,3-Trichloropropane ND 0.50 0.12 ug/l 120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.10 ug/l 95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.10 ug/l 108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.10 ug/l 127-18-4 Tetrachloroethylene ND 0.50 0.10 ug/l 108-88-3 Toluene ND 0.50 0.10 ug/l 79-01-6 Trichloroethylene ND 0.50 0.10 ug/l 75-69-4 Trichlorofluoromethane a ND 0.50 0.10 ug/l 75-01-4 Vinyl chloride ND 0.50 0.10 ug/l 1330-20-7 Xylene (total)ND 1.5 0.20 ug/l m,p-Xylene ND 1.0 0.10 ug/l 95-47-6 o-Xylene ND 0.50 0.10 ug/l CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits 1868-53-7 Dibromofluoromethane 110%70-130% 17060-07-0 1,2-Dichloroethane-D4 113%70-130% 2037-26-5 Toluene-D8 87%70-130% 460-00-4 4-Bromofluorobenzene 99%70-130% (a) Associated BS recovery outside control limits. ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 14 of 55 FA19734 3 3 . 3 Accutest Laboratories Report of Analysis Page 1 of 1 Client Sample ID:MW-7 Lab Sample ID:FA19734-3 Date Sampled:11/05/14 Matrix:AQ - Ground Water Date Received:11/06/14 Percent Solids:n/a Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC Total Metals Analysis Analyte Result RL Units DF Prep Analyzed By Method Prep Method Lead 103 5.0 ug/l 1 11/10/14 11/10/14 LM SW846 6010C 1 SW846 3010A 2 (1) Instrument QC Batch: MA12024 (2) Prep QC Batch: MP28182 RL = Reporting Limit 15 of 55 FA19734 3 3 . 3 Accutest Laboratories Report of Analysis Page 1 of 2 Client Sample ID:MW-9 Lab Sample ID:FA19734-4 Date Sampled:11/05/14 Matrix:AQ - Ground Water Date Received:11/06/14 Method:SM 6200B Percent Solids:n/a Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 A0190495.D 100 11/17/14 EG n/a n/a VA1582 Run #2 Purge Volume Run #1 10.0 ml Run #2 VOA 6200B List CAS No.Compound Result RL MDL Units Q 71-43-2 Benzene ND 50 10 ug/l 108-86-1 Bromobenzene ND 50 10 ug/l 74-97-5 Bromochloromethane ND 50 10 ug/l 75-27-4 Bromodichloromethane ND 50 10 ug/l 75-25-2 Bromoform ND 50 10 ug/l 104-51-8 n-Butylbenzene 35.2 50 10 ug/l J 135-98-8 sec-Butylbenzene 20.5 50 10 ug/l J 98-06-6 tert-Butylbenzene ND 50 10 ug/l 108-90-7 Chlorobenzene ND 50 10 ug/l 75-00-3 Chloroethane ND 50 12 ug/l 67-66-3 Chloroform ND 50 10 ug/l 95-49-8 o-Chlorotoluene ND 50 10 ug/l 106-43-4 p-Chlorotoluene ND 50 10 ug/l 56-23-5 Carbon tetrachloride ND 50 10 ug/l 75-34-3 1,1-Dichloroethane ND 50 10 ug/l 75-35-4 1,1-Dichloroethylene a ND 50 10 ug/l 563-58-6 1,1-Dichloropropene ND 50 10 ug/l 96-12-8 1,2-Dibromo-3-chloropropane ND 50 17 ug/l 106-93-4 1,2-Dibromoethane ND 50 10 ug/l 107-06-2 1,2-Dichloroethane ND 50 10 ug/l 78-87-5 1,2-Dichloropropane ND 50 10 ug/l 142-28-9 1,3-Dichloropropane ND 50 10 ug/l 108-20-3 Di-Isopropyl ether ND 50 10 ug/l 594-20-7 2,2-Dichloropropane ND 50 10 ug/l 124-48-1 Dibromochloromethane ND 50 10 ug/l 75-71-8 Dichlorodifluoromethane ND 50 10 ug/l 156-59-2 cis-1,2-Dichloroethylene ND 50 10 ug/l 10061-01-5 cis-1,3-Dichloropropene ND 50 10 ug/l 541-73-1 m-Dichlorobenzene ND 50 10 ug/l 95-50-1 o-Dichlorobenzene ND 50 10 ug/l 106-46-7 p-Dichlorobenzene ND 50 10 ug/l 156-60-5 trans-1,2-Dichloroethylene ND 50 10 ug/l ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 16 of 55 FA19734 3 3 . 4 Accutest Laboratories Report of Analysis Page 2 of 2 Client Sample ID:MW-9 Lab Sample ID:FA19734-4 Date Sampled:11/05/14 Matrix:AQ - Ground Water Date Received:11/06/14 Method:SM 6200B Percent Solids:n/a Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC VOA 6200B List CAS No.Compound Result RL MDL Units Q 10061-02-6 trans-1,3-Dichloropropene ND 50 10 ug/l 100-41-4 Ethylbenzene 1160 50 10 ug/l 87-68-3 Hexachlorobutadiene ND 50 10 ug/l 98-82-8 Isopropylbenzene 106 50 10 ug/l 99-87-6 p-Isopropyltoluene 10.9 50 10 ug/l J 74-83-9 Methyl bromide ND 50 10 ug/l 74-87-3 Methyl chloride ND 50 10 ug/l 74-95-3 Methylene bromide ND 50 10 ug/l 75-09-2 Methylene chloride ND 200 100 ug/l 1634-04-4 Methyl Tert Butyl Ether ND 50 10 ug/l 91-20-3 Naphthalene 529 50 10 ug/l 103-65-1 n-Propylbenzene 412 50 10 ug/l 100-42-5 Styrene 16.3 50 10 ug/l J 630-20-6 1,1,1,2-Tetrachloroethane ND 50 10 ug/l 71-55-6 1,1,1-Trichloroethane ND 50 10 ug/l 79-34-5 1,1,2,2-Tetrachloroethane ND 50 10 ug/l 79-00-5 1,1,2-Trichloroethane ND 50 11 ug/l 87-61-6 1,2,3-Trichlorobenzene ND 50 10 ug/l 96-18-4 1,2,3-Trichloropropane ND 50 12 ug/l 120-82-1 1,2,4-Trichlorobenzene ND 50 10 ug/l 95-63-6 1,2,4-Trimethylbenzene 2740 50 10 ug/l 108-67-8 1,3,5-Trimethylbenzene 786 50 10 ug/l 127-18-4 Tetrachloroethylene ND 50 10 ug/l 108-88-3 Toluene 2070 50 10 ug/l 79-01-6 Trichloroethylene ND 50 10 ug/l 75-69-4 Trichlorofluoromethane ND 50 10 ug/l 75-01-4 Vinyl chloride ND 50 10 ug/l m,p-Xylene 4060 100 10 ug/l 95-47-6 o-Xylene 1690 50 10 ug/l CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits 1868-53-7 Dibromofluoromethane 108%70-130% 17060-07-0 1,2-Dichloroethane-D4 114%70-130% 2037-26-5 Toluene-D8 96%70-130% 460-00-4 4-Bromofluorobenzene 96%70-130% (a) Associated BS recovery outside control limits. ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 17 of 55 FA19734 3 3 . 4 Accutest Laboratories Report of Analysis Page 1 of 1 Client Sample ID:MW-9 Lab Sample ID:FA19734-4 Date Sampled:11/05/14 Matrix:AQ - Ground Water Date Received:11/06/14 Percent Solids:n/a Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC Total Metals Analysis Analyte Result RL Units DF Prep Analyzed By Method Prep Method Lead 37.9 5.0 ug/l 1 11/10/14 11/10/14 LM SW846 6010C 1 SW846 3010A 2 (1) Instrument QC Batch: MA12024 (2) Prep QC Batch: MP28182 RL = Reporting Limit 18 of 55 FA19734 3 3 . 4 Accutest Laboratories Report of Analysis Page 1 of 2 Client Sample ID:MW-13 Lab Sample ID:FA19734-5 Date Sampled:11/05/14 Matrix:AQ - Ground Water Date Received:11/06/14 Method:SM 6200B Percent Solids:n/a Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 A0190499.D 1 11/17/14 EG n/a n/a VA1582 Run #2 Purge Volume Run #1 10.0 ml Run #2 VOA 6200B List CAS No.Compound Result RL MDL Units Q 71-43-2 Benzene ND 0.50 0.10 ug/l 108-86-1 Bromobenzene ND 0.50 0.10 ug/l 74-97-5 Bromochloromethane ND 0.50 0.10 ug/l 75-27-4 Bromodichloromethane ND 0.50 0.10 ug/l 75-25-2 Bromoform ND 0.50 0.10 ug/l 104-51-8 n-Butylbenzene ND 0.50 0.10 ug/l 135-98-8 sec-Butylbenzene ND 0.50 0.10 ug/l 98-06-6 tert-Butylbenzene ND 0.50 0.10 ug/l 108-90-7 Chlorobenzene ND 0.50 0.10 ug/l 75-00-3 Chloroethane ND 0.50 0.12 ug/l 67-66-3 Chloroform ND 0.50 0.10 ug/l 95-49-8 o-Chlorotoluene ND 0.50 0.10 ug/l 106-43-4 p-Chlorotoluene ND 0.50 0.10 ug/l 56-23-5 Carbon tetrachloride ND 0.50 0.10 ug/l 75-34-3 1,1-Dichloroethane ND 0.50 0.10 ug/l 75-35-4 1,1-Dichloroethylene a ND 0.50 0.10 ug/l 563-58-6 1,1-Dichloropropene ND 0.50 0.10 ug/l 96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.17 ug/l 106-93-4 1,2-Dibromoethane ND 0.50 0.10 ug/l 107-06-2 1,2-Dichloroethane ND 0.50 0.10 ug/l 78-87-5 1,2-Dichloropropane ND 0.50 0.10 ug/l 142-28-9 1,3-Dichloropropane ND 0.50 0.10 ug/l 108-20-3 Di-Isopropyl ether ND 0.50 0.10 ug/l 594-20-7 2,2-Dichloropropane ND 0.50 0.10 ug/l 124-48-1 Dibromochloromethane ND 0.50 0.10 ug/l 75-71-8 Dichlorodifluoromethane ND 0.50 0.10 ug/l 156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.10 ug/l 10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.10 ug/l 541-73-1 m-Dichlorobenzene ND 0.50 0.10 ug/l 95-50-1 o-Dichlorobenzene ND 0.50 0.10 ug/l 106-46-7 p-Dichlorobenzene ND 0.50 0.10 ug/l 156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.10 ug/l ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 19 of 55 FA19734 3 3 . 5 Accutest Laboratories Report of Analysis Page 2 of 2 Client Sample ID:MW-13 Lab Sample ID:FA19734-5 Date Sampled:11/05/14 Matrix:AQ - Ground Water Date Received:11/06/14 Method:SM 6200B Percent Solids:n/a Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC VOA 6200B List CAS No.Compound Result RL MDL Units Q 10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.10 ug/l 100-41-4 Ethylbenzene ND 0.50 0.10 ug/l 87-68-3 Hexachlorobutadiene ND 0.50 0.10 ug/l 98-82-8 Isopropylbenzene ND 0.50 0.10 ug/l 99-87-6 p-Isopropyltoluene ND 0.50 0.10 ug/l 74-83-9 Methyl bromide ND 0.50 0.10 ug/l 74-87-3 Methyl chloride ND 0.50 0.10 ug/l 74-95-3 Methylene bromide ND 0.50 0.10 ug/l 75-09-2 Methylene chloride ND 2.0 1.0 ug/l 1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.10 ug/l 91-20-3 Naphthalene ND 0.50 0.10 ug/l 103-65-1 n-Propylbenzene ND 0.50 0.10 ug/l 100-42-5 Styrene ND 0.50 0.10 ug/l 630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.10 ug/l 71-55-6 1,1,1-Trichloroethane ND 0.50 0.10 ug/l 79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.10 ug/l 79-00-5 1,1,2-Trichloroethane ND 0.50 0.11 ug/l 87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.10 ug/l 96-18-4 1,2,3-Trichloropropane ND 0.50 0.12 ug/l 120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.10 ug/l 95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.10 ug/l 108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.10 ug/l 127-18-4 Tetrachloroethylene ND 0.50 0.10 ug/l 108-88-3 Toluene ND 0.50 0.10 ug/l 79-01-6 Trichloroethylene ND 0.50 0.10 ug/l 75-69-4 Trichlorofluoromethane a ND 0.50 0.10 ug/l 75-01-4 Vinyl chloride ND 0.50 0.10 ug/l 1330-20-7 Xylene (total)ND 1.5 0.20 ug/l m,p-Xylene ND 1.0 0.10 ug/l 95-47-6 o-Xylene ND 0.50 0.10 ug/l CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits 1868-53-7 Dibromofluoromethane 109%70-130% 17060-07-0 1,2-Dichloroethane-D4 115%70-130% 2037-26-5 Toluene-D8 95%70-130% 460-00-4 4-Bromofluorobenzene 99%70-130% (a) Associated BS recovery outside control limits. ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 20 of 55 FA19734 3 3 . 5 Accutest Laboratories Report of Analysis Page 1 of 1 Client Sample ID:MW-13 Lab Sample ID:FA19734-5 Date Sampled:11/05/14 Matrix:AQ - Ground Water Date Received:11/06/14 Percent Solids:n/a Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC Total Metals Analysis Analyte Result RL Units DF Prep Analyzed By Method Prep Method Lead 6.7 5.0 ug/l 1 11/10/14 11/10/14 LM SW846 6010C 1 SW846 3010A 2 (1) Instrument QC Batch: MA12024 (2) Prep QC Batch: MP28182 RL = Reporting Limit 21 of 55 FA19734 3 3 . 5 Accutest Laboratories Report of Analysis Page 1 of 2 Client Sample ID:MW-14 Lab Sample ID:FA19734-6 Date Sampled:11/05/14 Matrix:AQ - Ground Water Date Received:11/06/14 Method:SM 6200B Percent Solids:n/a Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 A0190500.D 1 11/17/14 EG n/a n/a VA1582 Run #2 Purge Volume Run #1 10.0 ml Run #2 VOA 6200B List CAS No.Compound Result RL MDL Units Q 71-43-2 Benzene ND 0.50 0.10 ug/l 108-86-1 Bromobenzene ND 0.50 0.10 ug/l 74-97-5 Bromochloromethane ND 0.50 0.10 ug/l 75-27-4 Bromodichloromethane ND 0.50 0.10 ug/l 75-25-2 Bromoform ND 0.50 0.10 ug/l 104-51-8 n-Butylbenzene ND 0.50 0.10 ug/l 135-98-8 sec-Butylbenzene ND 0.50 0.10 ug/l 98-06-6 tert-Butylbenzene ND 0.50 0.10 ug/l 108-90-7 Chlorobenzene ND 0.50 0.10 ug/l 75-00-3 Chloroethane ND 0.50 0.12 ug/l 67-66-3 Chloroform ND 0.50 0.10 ug/l 95-49-8 o-Chlorotoluene ND 0.50 0.10 ug/l 106-43-4 p-Chlorotoluene ND 0.50 0.10 ug/l 56-23-5 Carbon tetrachloride ND 0.50 0.10 ug/l 75-34-3 1,1-Dichloroethane ND 0.50 0.10 ug/l 75-35-4 1,1-Dichloroethylene a ND 0.50 0.10 ug/l 563-58-6 1,1-Dichloropropene ND 0.50 0.10 ug/l 96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.17 ug/l 106-93-4 1,2-Dibromoethane ND 0.50 0.10 ug/l 107-06-2 1,2-Dichloroethane ND 0.50 0.10 ug/l 78-87-5 1,2-Dichloropropane ND 0.50 0.10 ug/l 142-28-9 1,3-Dichloropropane ND 0.50 0.10 ug/l 108-20-3 Di-Isopropyl ether ND 0.50 0.10 ug/l 594-20-7 2,2-Dichloropropane ND 0.50 0.10 ug/l 124-48-1 Dibromochloromethane ND 0.50 0.10 ug/l 75-71-8 Dichlorodifluoromethane ND 0.50 0.10 ug/l 156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.10 ug/l 10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.10 ug/l 541-73-1 m-Dichlorobenzene ND 0.50 0.10 ug/l 95-50-1 o-Dichlorobenzene ND 0.50 0.10 ug/l 106-46-7 p-Dichlorobenzene ND 0.50 0.10 ug/l 156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.10 ug/l ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 22 of 55 FA19734 3 3 . 6 Accutest Laboratories Report of Analysis Page 2 of 2 Client Sample ID:MW-14 Lab Sample ID:FA19734-6 Date Sampled:11/05/14 Matrix:AQ - Ground Water Date Received:11/06/14 Method:SM 6200B Percent Solids:n/a Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC VOA 6200B List CAS No.Compound Result RL MDL Units Q 10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.10 ug/l 100-41-4 Ethylbenzene ND 0.50 0.10 ug/l 87-68-3 Hexachlorobutadiene ND 0.50 0.10 ug/l 98-82-8 Isopropylbenzene ND 0.50 0.10 ug/l 99-87-6 p-Isopropyltoluene ND 0.50 0.10 ug/l 74-83-9 Methyl bromide ND 0.50 0.10 ug/l 74-87-3 Methyl chloride ND 0.50 0.10 ug/l 74-95-3 Methylene bromide ND 0.50 0.10 ug/l 75-09-2 Methylene chloride ND 2.0 1.0 ug/l 1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.10 ug/l 91-20-3 Naphthalene ND 0.50 0.10 ug/l 103-65-1 n-Propylbenzene ND 0.50 0.10 ug/l 100-42-5 Styrene ND 0.50 0.10 ug/l 630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.10 ug/l 71-55-6 1,1,1-Trichloroethane ND 0.50 0.10 ug/l 79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.10 ug/l 79-00-5 1,1,2-Trichloroethane ND 0.50 0.11 ug/l 87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.10 ug/l 96-18-4 1,2,3-Trichloropropane ND 0.50 0.12 ug/l 120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.10 ug/l 95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.10 ug/l 108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.10 ug/l 127-18-4 Tetrachloroethylene ND 0.50 0.10 ug/l 108-88-3 Toluene ND 0.50 0.10 ug/l 79-01-6 Trichloroethylene ND 0.50 0.10 ug/l 75-69-4 Trichlorofluoromethane a ND 0.50 0.10 ug/l 75-01-4 Vinyl chloride ND 0.50 0.10 ug/l 1330-20-7 Xylene (total)ND 1.5 0.20 ug/l m,p-Xylene ND 1.0 0.10 ug/l 95-47-6 o-Xylene ND 0.50 0.10 ug/l CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits 1868-53-7 Dibromofluoromethane 110%70-130% 17060-07-0 1,2-Dichloroethane-D4 116%70-130% 2037-26-5 Toluene-D8 94%70-130% 460-00-4 4-Bromofluorobenzene 98%70-130% (a) Associated BS recovery outside control limits. ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 23 of 55 FA19734 3 3 . 6 Accutest Laboratories Report of Analysis Page 1 of 1 Client Sample ID:MW-14 Lab Sample ID:FA19734-6 Date Sampled:11/05/14 Matrix:AQ - Ground Water Date Received:11/06/14 Percent Solids:n/a Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC Total Metals Analysis Analyte Result RL Units DF Prep Analyzed By Method Prep Method Lead 10.9 5.0 ug/l 1 11/10/14 11/10/14 LM SW846 6010C 1 SW846 3010A 2 (1) Instrument QC Batch: MA12024 (2) Prep QC Batch: MP28182 RL = Reporting Limit 24 of 55 FA19734 3 3 . 6 Accutest Laboratories Report of Analysis Page 1 of 2 Client Sample ID:MW-15 Lab Sample ID:FA19734-7 Date Sampled:11/05/14 Matrix:AQ - Ground Water Date Received:11/06/14 Method:SM 6200B Percent Solids:n/a Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 A0190501.D 1 11/17/14 EG n/a n/a VA1582 Run #2 Purge Volume Run #1 10.0 ml Run #2 VOA 6200B List CAS No.Compound Result RL MDL Units Q 71-43-2 Benzene ND 0.50 0.10 ug/l 108-86-1 Bromobenzene ND 0.50 0.10 ug/l 74-97-5 Bromochloromethane ND 0.50 0.10 ug/l 75-27-4 Bromodichloromethane ND 0.50 0.10 ug/l 75-25-2 Bromoform ND 0.50 0.10 ug/l 104-51-8 n-Butylbenzene ND 0.50 0.10 ug/l 135-98-8 sec-Butylbenzene ND 0.50 0.10 ug/l 98-06-6 tert-Butylbenzene ND 0.50 0.10 ug/l 108-90-7 Chlorobenzene ND 0.50 0.10 ug/l 75-00-3 Chloroethane ND 0.50 0.12 ug/l 67-66-3 Chloroform ND 0.50 0.10 ug/l 95-49-8 o-Chlorotoluene ND 0.50 0.10 ug/l 106-43-4 p-Chlorotoluene ND 0.50 0.10 ug/l 56-23-5 Carbon tetrachloride ND 0.50 0.10 ug/l 75-34-3 1,1-Dichloroethane ND 0.50 0.10 ug/l 75-35-4 1,1-Dichloroethylene a ND 0.50 0.10 ug/l 563-58-6 1,1-Dichloropropene ND 0.50 0.10 ug/l 96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.17 ug/l 106-93-4 1,2-Dibromoethane ND 0.50 0.10 ug/l 107-06-2 1,2-Dichloroethane ND 0.50 0.10 ug/l 78-87-5 1,2-Dichloropropane ND 0.50 0.10 ug/l 142-28-9 1,3-Dichloropropane ND 0.50 0.10 ug/l 108-20-3 Di-Isopropyl ether ND 0.50 0.10 ug/l 594-20-7 2,2-Dichloropropane ND 0.50 0.10 ug/l 124-48-1 Dibromochloromethane ND 0.50 0.10 ug/l 75-71-8 Dichlorodifluoromethane ND 0.50 0.10 ug/l 156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.10 ug/l 10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.10 ug/l 541-73-1 m-Dichlorobenzene ND 0.50 0.10 ug/l 95-50-1 o-Dichlorobenzene ND 0.50 0.10 ug/l 106-46-7 p-Dichlorobenzene ND 0.50 0.10 ug/l 156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.10 ug/l ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 25 of 55 FA19734 3 3 . 7 Accutest Laboratories Report of Analysis Page 2 of 2 Client Sample ID:MW-15 Lab Sample ID:FA19734-7 Date Sampled:11/05/14 Matrix:AQ - Ground Water Date Received:11/06/14 Method:SM 6200B Percent Solids:n/a Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC VOA 6200B List CAS No.Compound Result RL MDL Units Q 10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.10 ug/l 100-41-4 Ethylbenzene ND 0.50 0.10 ug/l 87-68-3 Hexachlorobutadiene ND 0.50 0.10 ug/l 98-82-8 Isopropylbenzene ND 0.50 0.10 ug/l 99-87-6 p-Isopropyltoluene ND 0.50 0.10 ug/l 74-83-9 Methyl bromide ND 0.50 0.10 ug/l 74-87-3 Methyl chloride ND 0.50 0.10 ug/l 74-95-3 Methylene bromide ND 0.50 0.10 ug/l 75-09-2 Methylene chloride ND 2.0 1.0 ug/l 1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.10 ug/l 91-20-3 Naphthalene ND 0.50 0.10 ug/l 103-65-1 n-Propylbenzene ND 0.50 0.10 ug/l 100-42-5 Styrene ND 0.50 0.10 ug/l 630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.10 ug/l 71-55-6 1,1,1-Trichloroethane ND 0.50 0.10 ug/l 79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.10 ug/l 79-00-5 1,1,2-Trichloroethane ND 0.50 0.11 ug/l 87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.10 ug/l 96-18-4 1,2,3-Trichloropropane ND 0.50 0.12 ug/l 120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.10 ug/l 95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.10 ug/l 108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.10 ug/l 127-18-4 Tetrachloroethylene ND 0.50 0.10 ug/l 108-88-3 Toluene ND 0.50 0.10 ug/l 79-01-6 Trichloroethylene ND 0.50 0.10 ug/l 75-69-4 Trichlorofluoromethane a ND 0.50 0.10 ug/l 75-01-4 Vinyl chloride ND 0.50 0.10 ug/l 1330-20-7 Xylene (total)ND 1.5 0.20 ug/l m,p-Xylene ND 1.0 0.10 ug/l 95-47-6 o-Xylene ND 0.50 0.10 ug/l CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits 1868-53-7 Dibromofluoromethane 112%70-130% 17060-07-0 1,2-Dichloroethane-D4 118%70-130% 2037-26-5 Toluene-D8 93%70-130% 460-00-4 4-Bromofluorobenzene 97%70-130% (a) Associated BS recovery outside control limits. ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 26 of 55 FA19734 3 3 . 7 Accutest Laboratories Report of Analysis Page 1 of 1 Client Sample ID:MW-15 Lab Sample ID:FA19734-7 Date Sampled:11/05/14 Matrix:AQ - Ground Water Date Received:11/06/14 Percent Solids:n/a Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC Total Metals Analysis Analyte Result RL Units DF Prep Analyzed By Method Prep Method Lead 1250 5.0 ug/l 1 11/10/14 11/10/14 LM SW846 6010C 1 SW846 3010A 2 (1) Instrument QC Batch: MA12024 (2) Prep QC Batch: MP28182 RL = Reporting Limit 27 of 55 FA19734 3 3 . 7 Accutest Laboratories Report of Analysis Page 1 of 2 Client Sample ID:MW-17 Lab Sample ID:FA19734-8 Date Sampled:11/05/14 Matrix:AQ - Ground Water Date Received:11/06/14 Method:SM 6200B Percent Solids:n/a Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 A0190502.D 5 11/17/14 EG n/a n/a VA1582 Run #2 A0190518.D 25 11/18/14 TD n/a n/a VA1583 Purge Volume Run #1 10.0 ml Run #2 10.0 ml VOA 6200B List CAS No.Compound Result RL MDL Units Q 71-43-2 Benzene 38.4 2.5 0.50 ug/l 108-86-1 Bromobenzene ND 2.5 0.50 ug/l 74-97-5 Bromochloromethane ND 2.5 0.50 ug/l 75-27-4 Bromodichloromethane ND 2.5 0.50 ug/l 75-25-2 Bromoform ND 2.5 0.50 ug/l 104-51-8 n-Butylbenzene ND 2.5 0.50 ug/l 135-98-8 sec-Butylbenzene ND 2.5 0.50 ug/l 98-06-6 tert-Butylbenzene ND 2.5 0.50 ug/l 108-90-7 Chlorobenzene ND 2.5 0.50 ug/l 75-00-3 Chloroethane 2.4 2.5 0.61 ug/l J 67-66-3 Chloroform ND 2.5 0.50 ug/l 95-49-8 o-Chlorotoluene ND 2.5 0.50 ug/l 106-43-4 p-Chlorotoluene ND 2.5 0.50 ug/l 56-23-5 Carbon tetrachloride ND 2.5 0.50 ug/l 75-34-3 1,1-Dichloroethane ND 2.5 0.50 ug/l 75-35-4 1,1-Dichloroethylene a ND 2.5 0.50 ug/l 563-58-6 1,1-Dichloropropene ND 2.5 0.50 ug/l 96-12-8 1,2-Dibromo-3-chloropropane ND 2.5 0.86 ug/l 106-93-4 1,2-Dibromoethane ND 2.5 0.50 ug/l 107-06-2 1,2-Dichloroethane ND 2.5 0.50 ug/l 78-87-5 1,2-Dichloropropane ND 2.5 0.50 ug/l 142-28-9 1,3-Dichloropropane ND 2.5 0.50 ug/l 108-20-3 Di-Isopropyl ether ND 2.5 0.50 ug/l 594-20-7 2,2-Dichloropropane ND 2.5 0.50 ug/l 124-48-1 Dibromochloromethane ND 2.5 0.50 ug/l 75-71-8 Dichlorodifluoromethane ND 2.5 0.50 ug/l 156-59-2 cis-1,2-Dichloroethylene ND 2.5 0.50 ug/l 10061-01-5 cis-1,3-Dichloropropene ND 2.5 0.50 ug/l 541-73-1 m-Dichlorobenzene ND 2.5 0.50 ug/l 95-50-1 o-Dichlorobenzene ND 2.5 0.50 ug/l 106-46-7 p-Dichlorobenzene ND 2.5 0.50 ug/l 156-60-5 trans-1,2-Dichloroethylene ND 2.5 0.50 ug/l ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 28 of 55 FA19734 3 3 . 8 Accutest Laboratories Report of Analysis Page 2 of 2 Client Sample ID:MW-17 Lab Sample ID:FA19734-8 Date Sampled:11/05/14 Matrix:AQ - Ground Water Date Received:11/06/14 Method:SM 6200B Percent Solids:n/a Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC VOA 6200B List CAS No.Compound Result RL MDL Units Q 10061-02-6 trans-1,3-Dichloropropene ND 2.5 0.50 ug/l 100-41-4 Ethylbenzene 90.1 2.5 0.50 ug/l 87-68-3 Hexachlorobutadiene ND 2.5 0.50 ug/l 98-82-8 Isopropylbenzene 4.0 2.5 0.50 ug/l 99-87-6 p-Isopropyltoluene ND 2.5 0.50 ug/l 74-83-9 Methyl bromide ND 2.5 0.50 ug/l 74-87-3 Methyl chloride ND 2.5 0.50 ug/l 74-95-3 Methylene bromide ND 2.5 0.50 ug/l 75-09-2 Methylene chloride ND 10 5.0 ug/l 1634-04-4 Methyl Tert Butyl Ether ND 2.5 0.50 ug/l 91-20-3 Naphthalene 32.8 2.5 0.50 ug/l 103-65-1 n-Propylbenzene 8.5 2.5 0.50 ug/l 100-42-5 Styrene 1.2 2.5 0.50 ug/l J 630-20-6 1,1,1,2-Tetrachloroethane ND 2.5 0.50 ug/l 71-55-6 1,1,1-Trichloroethane ND 2.5 0.50 ug/l 79-34-5 1,1,2,2-Tetrachloroethane ND 2.5 0.50 ug/l 79-00-5 1,1,2-Trichloroethane ND 2.5 0.53 ug/l 87-61-6 1,2,3-Trichlorobenzene ND 2.5 0.50 ug/l 96-18-4 1,2,3-Trichloropropane ND 2.5 0.59 ug/l 120-82-1 1,2,4-Trichlorobenzene ND 2.5 0.50 ug/l 95-63-6 1,2,4-Trimethylbenzene 90.4 2.5 0.50 ug/l 108-67-8 1,3,5-Trimethylbenzene 23.0 2.5 0.50 ug/l 127-18-4 Tetrachloroethylene ND 2.5 0.50 ug/l 108-88-3 Toluene 586 b 13 2.5 ug/l 79-01-6 Trichloroethylene ND 2.5 0.50 ug/l 75-69-4 Trichlorofluoromethane a ND 2.5 0.50 ug/l 75-01-4 Vinyl chloride ND 2.5 0.50 ug/l 1330-20-7 Xylene (total)749 b 38 5.0 ug/l m,p-Xylene 460 b 25 2.5 ug/l 95-47-6 o-Xylene 290 b 13 2.5 ug/l CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits 1868-53-7 Dibromofluoromethane 113%108%70-130% 17060-07-0 1,2-Dichloroethane-D4 123%115%70-130% 2037-26-5 Toluene-D8 91%95%70-130% 460-00-4 4-Bromofluorobenzene 95%98%70-130% (a) Associated BS recovery outside control limits. (b) Result is from Run# 2 ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 29 of 55 FA19734 3 3 . 8 Accutest Laboratories Report of Analysis Page 1 of 1 Client Sample ID:MW-17 Lab Sample ID:FA19734-8 Date Sampled:11/05/14 Matrix:AQ - Ground Water Date Received:11/06/14 Percent Solids:n/a Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC Total Metals Analysis Analyte Result RL Units DF Prep Analyzed By Method Prep Method Lead 3420 5.0 ug/l 1 11/10/14 11/10/14 LM SW846 6010C 1 SW846 3010A 2 (1) Instrument QC Batch: MA12024 (2) Prep QC Batch: MP28182 RL = Reporting Limit 30 of 55 FA19734 3 3 . 8 Accutest Laboratories Report of Analysis Page 1 of 2 Client Sample ID:RW-1 Lab Sample ID:FA19734-9 Date Sampled:11/05/14 Matrix:AQ - Ground Water Date Received:11/06/14 Method:SM 6200B Percent Solids:n/a Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 a A0190503.D 5 11/17/14 EG n/a n/a VA1582 Run #2 b E034409.D 2.5 11/11/14 EG n/a n/a VE1148 Purge Volume Run #1 10.0 ml Run #2 10.0 ml VOA 6200B List CAS No.Compound Result RL MDL Units Q 71-43-2 Benzene 14.1 2.5 0.50 ug/l 108-86-1 Bromobenzene ND 2.5 0.50 ug/l 74-97-5 Bromochloromethane ND 2.5 0.50 ug/l 75-27-4 Bromodichloromethane ND 2.5 0.50 ug/l 75-25-2 Bromoform ND 2.5 0.50 ug/l 104-51-8 n-Butylbenzene 4.4 2.5 0.50 ug/l 135-98-8 sec-Butylbenzene 3.9 2.5 0.50 ug/l 98-06-6 tert-Butylbenzene ND 2.5 0.50 ug/l 108-90-7 Chlorobenzene ND 2.5 0.50 ug/l 75-00-3 Chloroethane 2.5 2.5 0.61 ug/l 67-66-3 Chloroform ND 2.5 0.50 ug/l 95-49-8 o-Chlorotoluene ND 2.5 0.50 ug/l 106-43-4 p-Chlorotoluene ND 2.5 0.50 ug/l 56-23-5 Carbon tetrachloride ND 2.5 0.50 ug/l 75-34-3 1,1-Dichloroethane ND 2.5 0.50 ug/l 75-35-4 1,1-Dichloroethylene c ND 2.5 0.50 ug/l 563-58-6 1,1-Dichloropropene ND 2.5 0.50 ug/l 96-12-8 1,2-Dibromo-3-chloropropane ND 2.5 0.86 ug/l 106-93-4 1,2-Dibromoethane ND 2.5 0.50 ug/l 107-06-2 1,2-Dichloroethane ND 2.5 0.50 ug/l 78-87-5 1,2-Dichloropropane ND 2.5 0.50 ug/l 142-28-9 1,3-Dichloropropane ND 2.5 0.50 ug/l 108-20-3 Di-Isopropyl ether ND 2.5 0.50 ug/l 594-20-7 2,2-Dichloropropane ND 2.5 0.50 ug/l 124-48-1 Dibromochloromethane ND 2.5 0.50 ug/l 75-71-8 Dichlorodifluoromethane ND 2.5 0.50 ug/l 156-59-2 cis-1,2-Dichloroethylene ND 2.5 0.50 ug/l 10061-01-5 cis-1,3-Dichloropropene ND 2.5 0.50 ug/l 541-73-1 m-Dichlorobenzene ND 2.5 0.50 ug/l 95-50-1 o-Dichlorobenzene ND 2.5 0.50 ug/l 106-46-7 p-Dichlorobenzene ND 2.5 0.50 ug/l 156-60-5 trans-1,2-Dichloroethylene ND 2.5 0.50 ug/l ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 31 of 55 FA19734 3 3 . 9 Accutest Laboratories Report of Analysis Page 2 of 2 Client Sample ID:RW-1 Lab Sample ID:FA19734-9 Date Sampled:11/05/14 Matrix:AQ - Ground Water Date Received:11/06/14 Method:SM 6200B Percent Solids:n/a Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC VOA 6200B List CAS No.Compound Result RL MDL Units Q 10061-02-6 trans-1,3-Dichloropropene ND 2.5 0.50 ug/l 100-41-4 Ethylbenzene 200 2.5 0.50 ug/l 87-68-3 Hexachlorobutadiene ND 2.5 0.50 ug/l 98-82-8 Isopropylbenzene 20.4 2.5 0.50 ug/l 99-87-6 p-Isopropyltoluene ND 2.5 0.50 ug/l 74-83-9 Methyl bromide ND 2.5 0.50 ug/l 74-87-3 Methyl chloride 1.9 2.5 0.50 ug/l J 74-95-3 Methylene bromide ND 2.5 0.50 ug/l 75-09-2 Methylene chloride 13.6 10 5.0 ug/l 1634-04-4 Methyl Tert Butyl Ether ND 2.5 0.50 ug/l 91-20-3 Naphthalene 66.3 2.5 0.50 ug/l 103-65-1 n-Propylbenzene 49.9 2.5 0.50 ug/l 100-42-5 Styrene ND 2.5 0.50 ug/l 630-20-6 1,1,1,2-Tetrachloroethane ND 2.5 0.50 ug/l 71-55-6 1,1,1-Trichloroethane ND 2.5 0.50 ug/l 79-34-5 1,1,2,2-Tetrachloroethane ND 2.5 0.50 ug/l 79-00-5 1,1,2-Trichloroethane ND 2.5 0.53 ug/l 87-61-6 1,2,3-Trichlorobenzene ND 2.5 0.50 ug/l 96-18-4 1,2,3-Trichloropropane ND 2.5 0.59 ug/l 120-82-1 1,2,4-Trichlorobenzene ND 2.5 0.50 ug/l 95-63-6 1,2,4-Trimethylbenzene 136 2.5 0.50 ug/l 108-67-8 1,3,5-Trimethylbenzene 14.7 2.5 0.50 ug/l 127-18-4 Tetrachloroethylene ND 2.5 0.50 ug/l 108-88-3 Toluene 5.5 2.5 0.50 ug/l 79-01-6 Trichloroethylene ND 2.5 0.50 ug/l 75-69-4 Trichlorofluoromethane c ND 2.5 0.50 ug/l 75-01-4 Vinyl chloride ND 2.5 0.50 ug/l m,p-Xylene 184 5.0 0.50 ug/l 95-47-6 o-Xylene 9.2 2.5 0.50 ug/l CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits 1868-53-7 Dibromofluoromethane 117%124%70-130% 17060-07-0 1,2-Dichloroethane-D4 124%124%70-130% 2037-26-5 Toluene-D8 92%67%70-130% 460-00-4 4-Bromofluorobenzene 95%97%70-130% (a) Internal standard areas outside method criteria. (b) Confirmation run for internal standard areas. (c) Associated BS recovery outside control limits. ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 32 of 55 FA19734 3 3 . 9 Accutest Laboratories Report of Analysis Page 1 of 1 Client Sample ID:RW-1 Lab Sample ID:FA19734-9 Date Sampled:11/05/14 Matrix:AQ - Ground Water Date Received:11/06/14 Percent Solids:n/a Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC Total Metals Analysis Analyte Result RL Units DF Prep Analyzed By Method Prep Method Lead a <10 10 ug/l 1 11/10/14 11/10/14 LM SW846 6010C 1 SW846 3010A 2 (1) Instrument QC Batch: MA12024 (2) Prep QC Batch: MP28182 (a) Elevated reporting limit(s) due to matrix interference. Manually elevated. RL = Reporting Limit 33 of 55 FA19734 3 3 . 9 Accutest Laboratories Report of Analysis Page 1 of 1 Client Sample ID:WSW-8 Lab Sample ID:FA19734-10 Date Sampled:11/05/14 Matrix:AQ - Ground Water Date Received:11/06/14 Method:SM 6200B Percent Solids:n/a Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 A0190504.D 1 11/17/14 EG n/a n/a VA1582 Run #2 Purge Volume Run #1 10.0 ml Run #2 Purgeable Aromatics, Full List CAS No.Compound Result RL MDL Units Q 71-43-2 Benzene ND 0.50 0.10 ug/l 108-90-7 Chlorobenzene ND 0.50 0.10 ug/l 108-20-3 Di-Isopropyl ether ND 0.50 0.10 ug/l 541-73-1 m-Dichlorobenzene ND 0.50 0.10 ug/l 95-50-1 o-Dichlorobenzene ND 0.50 0.10 ug/l 106-46-7 p-Dichlorobenzene ND 0.50 0.10 ug/l 100-41-4 Ethylbenzene ND 0.50 0.10 ug/l 1634-04-4 Methyl Tert Butyl Ether 0.25 0.50 0.10 ug/l J 91-20-3 Naphthalene ND 0.50 0.10 ug/l 108-88-3 Toluene ND 0.50 0.10 ug/l 1330-20-7 Xylene (total)ND 1.5 0.20 ug/l CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits 1868-53-7 Dibromofluoromethane 108%70-130% 17060-07-0 1,2-Dichloroethane-D4 116%70-130% 2037-26-5 Toluene-D8 94%70-130% 460-00-4 4-Bromofluorobenzene 96%70-130% ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 34 of 55 FA19734 3 3 . 1 0 Accutest Laboratories Misc. Forms Custody Documents and Other Forms Includes the following where applicable: • Chain of Custody Southeast Section 4 35 of 55 FA19734 4 FA19734: Chain of Custody Page 1 of 3 36 of 55 FA19734 4 4 . 1 FA19734: Chain of Custody Page 2 of 3 37 of 55 FA19734 4 4 . 1 FA19734: Chain of Custody Page 3 of 3 38 of 55 FA19734 4 4 . 1 Accutest Laboratories GC/MS Volatiles QC Data Summaries Includes the following where applicable: • Method Blank Summaries • Blank Spike Summaries • Matrix Spike and Duplicate Summaries Southeast Section 5 39 of 55 FA19734 5 Method Blank Summary Page 1 of 2 Job Number:FA19734 Account:GRINCC GRI (Geological Resources Inc.) Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch VA1582-MB A0190485.D 1 11/17/14 EG n/a n/a VA1582 The QC reported here applies to the following samples:Method: SM 6200B FA19734-1, FA19734-2, FA19734-3, FA19734-4, FA19734-5, FA19734-6, FA19734-7, FA19734-8, FA19734-9, FA19734-10 CAS No.Compound Result RL MDL Units Q 71-43-2 Benzene ND 0.50 0.10 ug/l 108-86-1 Bromobenzene ND 0.50 0.10 ug/l 74-97-5 Bromochloromethane ND 0.50 0.10 ug/l 75-27-4 Bromodichloromethane ND 0.50 0.10 ug/l 75-25-2 Bromoform ND 0.50 0.10 ug/l 104-51-8 n-Butylbenzene ND 0.50 0.10 ug/l 135-98-8 sec-Butylbenzene ND 0.50 0.10 ug/l 98-06-6 tert-Butylbenzene ND 0.50 0.10 ug/l 108-90-7 Chlorobenzene ND 0.50 0.10 ug/l 75-00-3 Chloroethane ND 0.50 0.12 ug/l 67-66-3 Chloroform ND 0.50 0.10 ug/l 95-49-8 o-Chlorotoluene ND 0.50 0.10 ug/l 106-43-4 p-Chlorotoluene ND 0.50 0.10 ug/l 56-23-5 Carbon tetrachloride ND 0.50 0.10 ug/l 75-34-3 1,1-Dichloroethane ND 0.50 0.10 ug/l 75-35-4 1,1-Dichloroethylene ND 0.50 0.10 ug/l 563-58-6 1,1-Dichloropropene ND 0.50 0.10 ug/l 96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.17 ug/l 106-93-4 1,2-Dibromoethane ND 0.50 0.10 ug/l 107-06-2 1,2-Dichloroethane ND 0.50 0.10 ug/l 78-87-5 1,2-Dichloropropane ND 0.50 0.10 ug/l 142-28-9 1,3-Dichloropropane ND 0.50 0.10 ug/l 108-20-3 Di-Isopropyl ether ND 0.50 0.10 ug/l 594-20-7 2,2-Dichloropropane ND 0.50 0.10 ug/l 124-48-1 Dibromochloromethane ND 0.50 0.10 ug/l 75-71-8 Dichlorodifluoromethane ND 0.50 0.10 ug/l 156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.10 ug/l 10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.10 ug/l 541-73-1 m-Dichlorobenzene ND 0.50 0.10 ug/l 95-50-1 o-Dichlorobenzene ND 0.50 0.10 ug/l 106-46-7 p-Dichlorobenzene ND 0.50 0.10 ug/l 156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.10 ug/l 10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.10 ug/l 100-41-4 Ethylbenzene ND 0.50 0.10 ug/l 87-68-3 Hexachlorobutadiene ND 0.50 0.10 ug/l 98-82-8 Isopropylbenzene ND 0.50 0.10 ug/l 40 of 55 FA19734 5 5 . 1 . 1 Method Blank Summary Page 2 of 2 Job Number:FA19734 Account:GRINCC GRI (Geological Resources Inc.) Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch VA1582-MB A0190485.D 1 11/17/14 EG n/a n/a VA1582 The QC reported here applies to the following samples:Method: SM 6200B FA19734-1, FA19734-2, FA19734-3, FA19734-4, FA19734-5, FA19734-6, FA19734-7, FA19734-8, FA19734-9, FA19734-10 CAS No.Compound Result RL MDL Units Q 99-87-6 p-Isopropyltoluene ND 0.50 0.10 ug/l 74-83-9 Methyl bromide ND 0.50 0.10 ug/l 74-87-3 Methyl chloride ND 0.50 0.10 ug/l 74-95-3 Methylene bromide ND 0.50 0.10 ug/l 75-09-2 Methylene chloride ND 2.0 1.0 ug/l 1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.10 ug/l 91-20-3 Naphthalene ND 0.50 0.10 ug/l 103-65-1 n-Propylbenzene ND 0.50 0.10 ug/l 100-42-5 Styrene ND 0.50 0.10 ug/l 630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.10 ug/l 71-55-6 1,1,1-Trichloroethane ND 0.50 0.10 ug/l 79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.10 ug/l 79-00-5 1,1,2-Trichloroethane ND 0.50 0.11 ug/l 87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.10 ug/l 96-18-4 1,2,3-Trichloropropane ND 0.50 0.12 ug/l 120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.10 ug/l 95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.10 ug/l 108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.10 ug/l 127-18-4 Tetrachloroethylene ND 0.50 0.10 ug/l 108-88-3 Toluene ND 0.50 0.10 ug/l 79-01-6 Trichloroethylene ND 0.50 0.10 ug/l 75-69-4 Trichlorofluoromethane ND 0.50 0.10 ug/l 75-01-4 Vinyl chloride ND 0.50 0.10 ug/l 1330-20-7 Xylene (total)ND 1.5 0.20 ug/l m,p-Xylene ND 1.0 0.10 ug/l 95-47-6 o-Xylene ND 0.50 0.10 ug/l CAS No.Surrogate Recoveries Limits 1868-53-7 Dibromofluoromethane 105%70-130% 17060-07-0 1,2-Dichloroethane-D4 109%70-130% 2037-26-5 Toluene-D8 96%70-130% 460-00-4 4-Bromofluorobenzene 98%70-130% 41 of 55 FA19734 5 5 . 1 . 1 Method Blank Summary Page 1 of 1 Job Number:FA19734 Account:GRINCC GRI (Geological Resources Inc.) Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch VA1583-MB A0190517.D 1 11/18/14 TD n/a n/a VA1583 The QC reported here applies to the following samples:Method: SM 6200B FA19734-8 CAS No.Compound Result RL MDL Units Q 108-88-3 Toluene ND 0.50 0.10 ug/l 1330-20-7 Xylene (total)ND 1.5 0.20 ug/l m,p-Xylene ND 1.0 0.10 ug/l 95-47-6 o-Xylene ND 0.50 0.10 ug/l CAS No.Surrogate Recoveries Limits 1868-53-7 Dibromofluoromethane 108%70-130% 17060-07-0 1,2-Dichloroethane-D4 115%70-130% 2037-26-5 Toluene-D8 96%70-130% 460-00-4 4-Bromofluorobenzene 98%70-130% 42 of 55 FA19734 5 5 . 1 . 2 Blank Spike Summary Page 1 of 2 Job Number:FA19734 Account:GRINCC GRI (Geological Resources Inc.) Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch VA1582-BS a A0190483.D 1 11/17/14 EG n/a n/a VA1582 The QC reported here applies to the following samples:Method: SM 6200B FA19734-1, FA19734-2, FA19734-3, FA19734-4, FA19734-5, FA19734-6, FA19734-7, FA19734-8, FA19734-9, FA19734-10 Spike BSP BSP CAS No.Compound ug/l ug/l %Limits 71-43-2 Benzene 10 11.1 111 70-130 108-86-1 Bromobenzene 10 10.6 106 70-130 74-97-5 Bromochloromethane 10 10.7 107 70-130 75-27-4 Bromodichloromethane 10 11.4 114 70-130 75-25-2 Bromoform 10 9.7 97 70-130 104-51-8 n-Butylbenzene 10 10.7 107 70-130 135-98-8 sec-Butylbenzene 10 11.9 119 70-130 98-06-6 tert-Butylbenzene 10 11.7 117 70-130 108-90-7 Chlorobenzene 10 11.6 116 70-130 75-00-3 Chloroethane 10 10.1 101 60-140 67-66-3 Chloroform 10 11.5 115 70-130 95-49-8 o-Chlorotoluene 10 11.4 114 70-130 106-43-4 p-Chlorotoluene 10 11.5 115 70-130 56-23-5 Carbon tetrachloride 10 12.7 127 70-130 75-34-3 1,1-Dichloroethane 10 11.4 114 70-130 75-35-4 1,1-Dichloroethylene 10 13.3 133*70-130 563-58-6 1,1-Dichloropropene 10 12.5 125 70-130 96-12-8 1,2-Dibromo-3-chloropropane 10 9.8 98 70-130 106-93-4 1,2-Dibromoethane 10 10.8 108 70-130 107-06-2 1,2-Dichloroethane 10 11.8 118 70-130 78-87-5 1,2-Dichloropropane 10 11.0 110 70-130 142-28-9 1,3-Dichloropropane 10 10.4 104 70-130 108-20-3 Di-Isopropyl ether 10 10.8 108 70-130 594-20-7 2,2-Dichloropropane 10 12.6 126 70-130 124-48-1 Dibromochloromethane 10 10.8 108 70-130 75-71-8 Dichlorodifluoromethane 10 13.4 134 60-140 156-59-2 cis-1,2-Dichloroethylene 10 11.2 112 70-130 10061-01-5 cis-1,3-Dichloropropene 10 10.6 106 70-130 541-73-1 m-Dichlorobenzene 10 11.5 115 70-130 95-50-1 o-Dichlorobenzene 10 11.3 113 70-130 106-46-7 p-Dichlorobenzene 10 10.5 105 70-130 156-60-5 trans-1,2-Dichloroethylene 10 12.0 120 70-130 10061-02-6 trans-1,3-Dichloropropene 10 11.2 112 70-130 100-41-4 Ethylbenzene 10 10.8 108 70-130 87-68-3 Hexachlorobutadiene 10 10.5 105 70-130 98-82-8 Isopropylbenzene 10 11.8 118 70-130 * = Outside of Control Limits. 43 of 55 FA19734 5 5 . 2 . 1 Blank Spike Summary Page 2 of 2 Job Number:FA19734 Account:GRINCC GRI (Geological Resources Inc.) Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch VA1582-BS a A0190483.D 1 11/17/14 EG n/a n/a VA1582 The QC reported here applies to the following samples:Method: SM 6200B FA19734-1, FA19734-2, FA19734-3, FA19734-4, FA19734-5, FA19734-6, FA19734-7, FA19734-8, FA19734-9, FA19734-10 Spike BSP BSP CAS No.Compound ug/l ug/l %Limits 99-87-6 p-Isopropyltoluene 10 11.5 115 70-130 74-83-9 Methyl bromide 10 11.1 111 60-140 74-87-3 Methyl chloride 10 11.7 117 60-140 74-95-3 Methylene bromide 10 11.5 115 70-130 75-09-2 Methylene chloride 10 12.1 121 70-130 1634-04-4 Methyl Tert Butyl Ether 10 9.9 99 70-130 91-20-3 Naphthalene 10 10 100 70-130 103-65-1 n-Propylbenzene 10 12.0 120 70-130 100-42-5 Styrene 10 10.2 102 70-130 630-20-6 1,1,1,2-Tetrachloroethane 10 11.0 110 70-130 71-55-6 1,1,1-Trichloroethane 10 12.4 124 70-130 79-34-5 1,1,2,2-Tetrachloroethane 10 9.9 99 70-130 79-00-5 1,1,2-Trichloroethane 10 10.7 107 70-130 87-61-6 1,2,3-Trichlorobenzene 10 10.3 103 70-130 96-18-4 1,2,3-Trichloropropane 10 10.9 109 70-130 120-82-1 1,2,4-Trichlorobenzene 10 10.1 101 70-130 95-63-6 1,2,4-Trimethylbenzene 10 10.4 104 70-130 108-67-8 1,3,5-Trimethylbenzene 10 10.5 105 70-130 127-18-4 Tetrachloroethylene 10 11.7 117 70-130 108-88-3 Toluene 10 10.6 106 70-130 79-01-6 Trichloroethylene 10 12.1 121 70-130 75-69-4 Trichlorofluoromethane 10 14.1 141*60-140 75-01-4 Vinyl chloride 10 11.4 114 60-140 1330-20-7 Xylene (total)30 33.8 113 70-130 m,p-Xylene 20 22.4 112 70-130 95-47-6 o-Xylene 10 11.4 114 70-130 CAS No.Surrogate Recoveries BSP Limits 1868-53-7 Dibromofluoromethane 106%70-130% 17060-07-0 1,2-Dichloroethane-D4 109%70-130% 2037-26-5 Toluene-D8 97%70-130% 460-00-4 4-Bromofluorobenzene 97%70-130% (a) No MSD available for this run. * = Outside of Control Limits. 44 of 55 FA19734 5 5 . 2 . 1 Blank Spike Summary Page 1 of 1 Job Number:FA19734 Account:GRINCC GRI (Geological Resources Inc.) Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch VA1583-BS A0190527.D 1 11/18/14 TD n/a n/a VA1583 The QC reported here applies to the following samples:Method: SM 6200B FA19734-8 Spike BSP BSP CAS No.Compound ug/l ug/l %Limits 108-88-3 Toluene 10 10.4 104 70-130 1330-20-7 Xylene (total)30 33.3 111 70-130 m,p-Xylene 20 22.1 111 70-130 95-47-6 o-Xylene 10 11.2 112 70-130 CAS No.Surrogate Recoveries BSP Limits 1868-53-7 Dibromofluoromethane 110%70-130% 17060-07-0 1,2-Dichloroethane-D4 113%70-130% 2037-26-5 Toluene-D8 96%70-130% 460-00-4 4-Bromofluorobenzene 95%70-130% * = Outside of Control Limits. 45 of 55 FA19734 5 5 . 2 . 2 Matrix Spike Summary Page 1 of 2 Job Number:FA19734 Account:GRINCC GRI (Geological Resources Inc.) Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch FA19781-6MS A0190496.D 50 11/17/14 EG n/a n/a VA1582 FA19781-6 A0190489.D 50 11/17/14 EG n/a n/a VA1582 The QC reported here applies to the following samples:Method: SM 6200B FA19734-1, FA19734-2, FA19734-3, FA19734-4, FA19734-5, FA19734-6, FA19734-7, FA19734-8, FA19734-9, FA19734-10 FA19781-6 Spike MS MS CAS No.Compound ug/l Q ug/l ug/l %Limits 71-43-2 Benzene 2690 E 500 3200 102 70-130 108-86-1 Bromobenzene ND 500 529 106 70-130 74-97-5 Bromochloromethane ND 500 541 108 70-130 75-27-4 Bromodichloromethane ND 500 582 116 70-130 75-25-2 Bromoform ND 500 462 92 70-130 104-51-8 n-Butylbenzene 6.7 J 500 536 106 70-130 135-98-8 sec-Butylbenzene 7.2 J 500 599 118 70-130 98-06-6 tert-Butylbenzene ND 500 588 118 70-130 108-90-7 Chlorobenzene ND 500 589 118 70-130 75-00-3 Chloroethane ND 500 611 122 60-140 67-66-3 Chloroform ND 500 597 119 70-130 95-49-8 o-Chlorotoluene ND 500 573 115 70-130 106-43-4 p-Chlorotoluene ND 500 576 115 70-130 56-23-5 Carbon tetrachloride ND 500 638 128 70-130 75-34-3 1,1-Dichloroethane ND 500 582 116 70-130 75-35-4 1,1-Dichloroethylene ND 500 670 134*70-130 563-58-6 1,1-Dichloropropene ND 500 643 129 70-130 96-12-8 1,2-Dibromo-3-chloropropane ND 500 469 94 70-130 106-93-4 1,2-Dibromoethane ND 500 544 109 70-130 107-06-2 1,2-Dichloroethane ND 500 610 122 70-130 78-87-5 1,2-Dichloropropane ND 500 552 110 70-130 142-28-9 1,3-Dichloropropane ND 500 522 104 70-130 108-20-3 Di-Isopropyl ether 16.9 J 500 571 111 70-130 594-20-7 2,2-Dichloropropane ND 500 593 119 70-130 124-48-1 Dibromochloromethane ND 500 532 106 70-130 75-71-8 Dichlorodifluoromethane ND 500 789 158*60-140 156-59-2 cis-1,2-Dichloroethylene ND 500 569 114 70-130 10061-01-5 cis-1,3-Dichloropropene ND 500 516 103 70-130 541-73-1 m-Dichlorobenzene ND 500 579 116 70-130 95-50-1 o-Dichlorobenzene ND 500 568 114 70-130 106-46-7 p-Dichlorobenzene ND 500 525 105 70-130 156-60-5 trans-1,2-Dichloroethylene ND 500 611 122 70-130 10061-02-6 trans-1,3-Dichloropropene ND 500 555 111 70-130 100-41-4 Ethylbenzene ND 500 547 109 70-130 87-68-3 Hexachlorobutadiene ND 500 531 106 70-130 98-82-8 Isopropylbenzene 40.3 500 640 120 70-130 * = Outside of Control Limits. 46 of 55 FA19734 5 5 . 3 . 1 Matrix Spike Summary Page 2 of 2 Job Number:FA19734 Account:GRINCC GRI (Geological Resources Inc.) Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch FA19781-6MS A0190496.D 50 11/17/14 EG n/a n/a VA1582 FA19781-6 A0190489.D 50 11/17/14 EG n/a n/a VA1582 The QC reported here applies to the following samples:Method: SM 6200B FA19734-1, FA19734-2, FA19734-3, FA19734-4, FA19734-5, FA19734-6, FA19734-7, FA19734-8, FA19734-9, FA19734-10 FA19781-6 Spike MS MS CAS No.Compound ug/l Q ug/l ug/l %Limits 99-87-6 p-Isopropyltoluene ND 500 579 116 70-130 74-83-9 Methyl bromide ND 500 703 141*60-140 74-87-3 Methyl chloride ND 500 691 138 60-140 74-95-3 Methylene bromide ND 500 586 117 70-130 75-09-2 Methylene chloride ND 500 676 135*70-130 1634-04-4 Methyl Tert Butyl Ether 673 500 1160 97 70-130 91-20-3 Naphthalene 181 500 707 105 70-130 103-65-1 n-Propylbenzene 20.9 J 500 623 120 70-130 100-42-5 Styrene ND 500 512 102 70-130 630-20-6 1,1,1,2-Tetrachloroethane ND 500 555 111 70-130 71-55-6 1,1,1-Trichloroethane ND 500 632 126 70-130 79-34-5 1,1,2,2-Tetrachloroethane ND 500 502 100 70-130 79-00-5 1,1,2-Trichloroethane ND 500 542 108 70-130 87-61-6 1,2,3-Trichlorobenzene ND 500 512 102 70-130 96-18-4 1,2,3-Trichloropropane ND 500 550 110 70-130 120-82-1 1,2,4-Trichlorobenzene ND 500 507 101 70-130 95-63-6 1,2,4-Trimethylbenzene 96.5 500 621 105 70-130 108-67-8 1,3,5-Trimethylbenzene ND 500 526 105 70-130 127-18-4 Tetrachloroethylene ND 500 596 119 70-130 108-88-3 Toluene 29.6 500 557 105 70-130 79-01-6 Trichloroethylene ND 500 614 123 70-130 75-69-4 Trichlorofluoromethane ND 500 852 170*60-140 75-01-4 Vinyl chloride ND 500 629 126 60-140 1330-20-7 Xylene (total)98.7 1500 1820 115 70-130 m,p-Xylene 56.6 1000 1200 114 70-130 95-47-6 o-Xylene 42.1 500 621 116 70-130 CAS No.Surrogate Recoveries MS FA19781-6 Limits 1868-53-7 Dibromofluoromethane 109%106%70-130% 17060-07-0 1,2-Dichloroethane-D4 112%111%70-130% 2037-26-5 Toluene-D8 97%95%70-130% 460-00-4 4-Bromofluorobenzene 96%98%70-130% * = Outside of Control Limits. 47 of 55 FA19734 5 5 . 3 . 1 Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1 Job Number:FA19734 Account:GRINCC GRI (Geological Resources Inc.) Project:Cannady's; 3963 NC Hwy 24, Bonnetsville, NC Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch FA19862-6MS A0190528.D 50 11/18/14 TD n/a n/a VA1583 FA19862-6MSD A0190529.D 50 11/18/14 TD n/a n/a VA1583 FA19862-6 A0190522.D 50 11/18/14 TD n/a n/a VA1583 The QC reported here applies to the following samples:Method: SM 6200B FA19734-8 FA19862-6 Spike MS MS Spike MSD MSD Limits CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD 108-88-3 Toluene 1320 500 2270 190* a 500 1990 134* a 13 70-130/20 1330-20-7 Xylene (total)5650 1500 13900 550* a 1500 12300 443* a 12 70-130/20 m,p-Xylene 4400 1000 10600 620* a 1000 9460 506* a 11 70-130/20 95-47-6 o-Xylene 1250 500 3240 398* a 500 2830 316* a 14 70-130/20 CAS No.Surrogate Recoveries MS MSD FA19862-6 Limits 1868-53-7 Dibromofluoromethane 97%98%107%70-130% 17060-07-0 1,2-Dichloroethane-D4 139%*135%*119%70-130% 2037-26-5 Toluene-D8 108%108%96%70-130% 460-00-4 4-Bromofluorobenzene 114%119%99%70-130% (a) Outside control limits due to high level in sample relative to spike amount. * = Outside of Control Limits. 48 of 55 FA19734 5 5 . 4 . 1 Accutest Laboratories Metals Analysis QC Data Summaries Includes the following where applicable: • Method Blank Summaries • Matrix Spike and Duplicate Summaries • Blank Spike and Lab Control Sample Summaries • Serial Dilution Summaries Southeast Section 6 49 of 55 FA19734 6 BLANK RESULTS SUMMARY Part 2 - Method Blanks Login Number: FA19734 Account: GRINCC - GRI (Geological Resources Inc.) Project: Cannady's; 3963 NC Hwy 24, Bonnetsville, NC QC Batch ID: MP28182 Methods: SW846 6010C Matrix Type: AQUEOUS Units: ug/l Prep Date: 11/10/14 MB Metal RL IDL MDL raw final Aluminum 200 15 15 Antimony 6.0 2 2.3 Arsenic 10 2 2.4 Barium 200 1 1 Beryllium 4.0 .5 .5 Cadmium 5.0 .5 .5 Calcium 1000 50 50 Chromium 10 1 2 Cobalt 50 .5 .5 Copper 25 1 1 Iron 300 17 17 Lead 5.0 1.1 1.1 -0.10 <5.0 Magnesium 5000 50 56 Manganese 15 .5 1 Molybdenum 50 .5 .5 Nickel 40 .5 .5 Potassium 10000 200 200 Selenium 10 2.3 2.3 Silver 10 .65 .77 Sodium 10000 500 500 Strontium 10 .4 .4 Thallium 10 1.5 2 Tin 50 .7 1 Titanium 10 .9 1 Vanadium 50 .5 .5 Zinc 20 3 3 Associated samples MP28182: FA19734-1, FA19734-2, FA19734-3, FA19734-4, FA19734-5, FA19734-6, FA19734-7, FA19734-8, FA19734-9 Results < IDL are shown as zero for calculation purposes (*) Outside of QC limits (anr) Analyte not requested _________________________________________________________________________________________________________ Page 1 50 of 55 FA19734 6 6 . 1 . 1 MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY Login Number: FA19734 Account: GRINCC - GRI (Geological Resources Inc.) Project: Cannady's; 3963 NC Hwy 24, Bonnetsville, NC QC Batch ID: MP28182 Methods: SW846 6010C Matrix Type: AQUEOUS Units: ug/l Prep Date: 11/10/14 11/10/14 FA19729-6 QC FA19729-6 Spikelot QC Metal Original DUP RPD Limits Original MS MPFLICP2 % Rec Limits Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron anr Lead 0.0 0.0 NC 0-20 0.0 486 500 97.2 80-120 Magnesium Manganese anr Molybdenum Nickel Potassium Selenium Silver Sodium Strontium Thallium Tin Titanium Vanadium Zinc Associated samples MP28182: FA19734-1, FA19734-2, FA19734-3, FA19734-4, FA19734-5, FA19734-6, FA19734-7, FA19734-8, FA19734-9 Results < IDL are shown as zero for calculation purposes (*) Outside of QC limits (N) Matrix Spike Rec. outside of QC limits (anr) Analyte not requested _________________________________________________________________________________________________________ Page 1 51 of 55 FA19734 6 6 . 1 . 2 MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY Login Number: FA19734 Account: GRINCC - GRI (Geological Resources Inc.) Project: Cannady's; 3963 NC Hwy 24, Bonnetsville, NC QC Batch ID: MP28182 Methods: SW846 6010C Matrix Type: AQUEOUS Units: ug/l Prep Date: 11/10/14 FA19729-6 Spikelot MSD QC Metal Original MSD MPFLICP2 % Rec RPD Limit Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron anr Lead 0.0 483 500 96.6 0.6 20 Magnesium Manganese anr Molybdenum Nickel Potassium Selenium Silver Sodium Strontium Thallium Tin Titanium Vanadium Zinc Associated samples MP28182: FA19734-1, FA19734-2, FA19734-3, FA19734-4, FA19734-5, FA19734-6, FA19734-7, FA19734-8, FA19734-9 Results < IDL are shown as zero for calculation purposes (*) Outside of QC limits (N) Matrix Spike Rec. outside of QC limits (anr) Analyte not requested _________________________________________________________________________________________________________ Page 2 52 of 55 FA19734 6 6 . 1 . 2 SPIKE BLANK AND LAB CONTROL SAMPLE SUMMARY Login Number: FA19734 Account: GRINCC - GRI (Geological Resources Inc.) Project: Cannady's; 3963 NC Hwy 24, Bonnetsville, NC QC Batch ID: MP28182 Methods: SW846 6010C Matrix Type: AQUEOUS Units: ug/l Prep Date: 11/10/14 BSP Spikelot QC Metal Result MPFLICP2 % Rec Limits Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron anr Lead 491 500 98.2 80-120 Magnesium Manganese anr Molybdenum Nickel Potassium Selenium Silver Sodium Strontium Thallium Tin Titanium Vanadium Zinc Associated samples MP28182: FA19734-1, FA19734-2, FA19734-3, FA19734-4, FA19734-5, FA19734-6, FA19734-7, FA19734-8, FA19734-9 Results < IDL are shown as zero for calculation purposes (*) Outside of QC limits (anr) Analyte not requested _________________________________________________________________________________________________________ Page 1 53 of 55 FA19734 6 6 . 1 . 3 SERIAL DILUTION RESULTS SUMMARY Login Number: FA19734 Account: GRINCC - GRI (Geological Resources Inc.) Project: Cannady's; 3963 NC Hwy 24, Bonnetsville, NC QC Batch ID: MP28182 Methods: SW846 6010C Matrix Type: AQUEOUS Units: ug/l Prep Date: 11/10/14 FA19729-6 QC Metal Original SDL 1:5 %DIF Limits Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron anr Lead 0.00 0.00 NC 0-10 Magnesium Manganese anr Molybdenum Nickel Potassium Selenium Silver Sodium Strontium Thallium Tin Titanium Vanadium Zinc Associated samples MP28182: FA19734-1, FA19734-2, FA19734-3, FA19734-4, FA19734-5, FA19734-6, FA19734-7, FA19734-8, FA19734-9 Results < IDL are shown as zero for calculation purposes (*) Outside of QC limits (anr) Analyte not requested _________________________________________________________________________________________________________ Page 1 54 of 55 FA19734 6 6 . 1 . 4 POST DIGESTATE SPIKE SUMMARY Login Number: FA19734 Account: GRINCC - GRI (Geological Resources Inc.) Project: Cannady's; 3963 NC Hwy 24, Bonnetsville, NC QC Batch ID: MP28182 Methods: SW846 6010C Matrix Type: AQUEOUS Units: ug/l Prep Date: 11/10/14 Sample Final FA19729-6 PS Spike Spike Spike QC Metal ml ml Raw Corr.** ug/l ml ug/ml ug/l % Rec Limits Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead 9.8 10 49.6 0.2 2.5 50 99.2 80-120 Magnesium Manganese Molybdenum Nickel Potassium Selenium Silver Sodium Strontium Thallium Tin Titanium Vanadium Zinc Associated samples MP28182: FA19734-1, FA19734-2, FA19734-3, FA19734-4, FA19734-5, FA19734-6, FA19734-7, FA19734-8, FA19734-9 Results < IDL are shown as zero for calculation purposes (*) Outside of QC limits (**) Corr. sample result = Raw * (sample volume / final volume) (anr) Analyte not requested _________________________________________________________________________________________________________ Page 1 55 of 55 FA19734 6 6 . 1 . 5