Loading...
HomeMy WebLinkAboutNCD991278953_19970603_National Starch & Chemical Corp._FRBCERCLA RA_Response to EPA & DENR Comments on RD RA Field Investigations Summary & Conceptual Design Reports-OCRI u u I I I I I I I I I I I I I I I 0.tlonal Starch and Chem/cal Company 10 Finderne Avenue P. 0. Box 6500 Bridgewater, New Jersey 08807-0500 908-685-5000 Cable Address: NASPAOD,BRlDGEWATER/IEWJERSEY Writer's Direct Dial Number: Fax Number: 908-685-6991 908-707-3763 Mr. Jon Bornholm Remedial Project Manager United States Environmental Protection Agency Region IV 100 Alabama Street, SW Atlanta, Georgia 30303 -3104 June 3, 1997 R12c121v120 :JUN 26 1997 SUPERFUNO SECT/ON Subject: Cedar Springs Road Plant Site, Salisbury, North Carolina Superfund Project Operable Unit 3 Response to USEPA and NCDEHNR Comments on RD/RA Field Investigations Summary Report and RD/RA Conceptual Design Report Dear Mr. Bornholm: Attached please find seven copies ofNSCC"s response to USEPA and NCDEI-INR comments on the RD/RA Field Investigations Summary Report and RD/RA Conceptual Design Report for Operable Unit 3. This response will be bound in these two reports. We sincerely thank you for your continued assistance and USEPA's guidance. Please do not hesitate to call me at 908-685-6991 if there are any questions. Very Truly Yours, National Starch and Chemical Company <5,.~,~~ Corporate Director of Environmental Projects CC: D. Cregar, NSCC A. Samson, NSCC R. Paradowski, NSCC S. Velicheti, NSCC M. Ford, NSCC C:\PROJECTS\SALSBRY\L TRBRN 12.AA I I g H 0 D D D I I I I I I I Responses to U.S. EPA Comments (05/12/97) on the Remedial Design/Remedial Action Field Investigations Report for the Third Operable Unit (OU3) National Starch & Chemical Company Cedar Springs Road Plant, North Carolina A. Field Investigations Summary Report Contents Comment No. 1 Page 45, Section 5.1, Second Paragraph, Seventh Sentence: This sentence states that the pumps were placed IO feet above the bottom of the well except at NS-54 where it was placed 30 feet above the bottom of the well. A short explanation needs to be added to this paragraph stating why the alteration in well NS-54. Response No. 1 At the Bedrock Well NS-54 the Driller had considerable difficulty during drilling and installing the well. Initially the 6-1/8" bore hole for this well was completed down to 201 feet.below the ground surface. After increasing the bore hole diameter to 9-7/8" with an Air Hammer Bit the Driller encountered obstruction at 70 to 80 feet below the ground. This obstruction was removed by using the Cable Tool Method and to prevent any further obstruction in the borehole, a 6" galvanized pipe casing was installed down to 120 feet below ground surface (the Driller and the Geologist established that the top of bedrock at this location is at 111 feet below the ground surface). After installation of the casing the Driller encountered a second obstruction in this well at 178 feet below the ground surface. This obstruction could not be removed in spite of several attempts by the Driller and as a result the submersible pump could not be lowered below this obstruction. To avoid damage to the pump in this well it was installed at 171 feet below the ground surface ( 31 feet above the bottom of the bore hole). Since the total drawdown in this well under pumping condition is only about 26.31 feet, installation of the pump 31 feet above the bottom of the well will not affect designed extraction rate from this well. C:\PROJECTS\SALSBRY\OUJRES4.AA I I I I I I I I Comment No. 2 Page 56, Table 5-11: Oversight, in the rest of the accompanying tables providing the drawdown observations for the step tests the well tested itself was included in the table. In Table 5-11 well NS-45 was omitted from the table. Response No. 2 This was indeed an oversight. The observed drawdown in Well NS-45 during the Step- Drawdown Test at the end of the 57 minutes test was 44 feet from the top of the casing. Table 5-11 has been modified to include this data. Comment No. 3 Page 93, Section 8.0, fifth sentence: Typo, the beginning of this sentence starts, "Tables 6-1 and 6-1 ..... " Response No. 3 This sentence should read as," Tables 6-1 and 6-2 show respectively the detected organic compounds and the inorganic substances found in samples collected from monitoring and extraction wells during the groundwater sampling event performed in January 1997." Comment No. 4 Page 93, Section 8.1; Based on the text presented in this section, it appears that the vertical extent of the contamination was not defined in Area 2. Response No. 4 It is correct that the vertical extent of groundwater contamination of the bedrock zone in Area 2 of the Plant could not be confirmed from the sampling and analysis of the Bedrock Wells conducted during the Packer Tests. However, during the drilling of the boreholes in Area 2, the Bedrock in this area was found to be C:\PROJECTS\SALSBRY\OU3RES4.AA 2 11!!1 --!!!!!I l!!!!!!!!I !!!!!!!!I I!!!!!!!!!! l!!!il!!I l!!!i!!iil l!!!!!i!iil l!iiiii!I liiiil liiliill ---liiiiill ;;;; == =:a .w~11 .r nf ~f~;,_g;;:t . . ··••trc:iiti i.i-s~4·.···· NS-24 604 NS-35 231. 0 NS-36 219.7 NS-45 0.25 NS-46 177.7 NS-47 183.3 Table 5-11 Drawdown Observations for Step Test NS-45 Monitoring Wells and Extraction Well OU3 RD/RA Field Investigation • Drawdown (ft.) ·After 57 min. 0 0 0 44 0 0 Note: The screened interval is measured from the ground surface. Interval 55 to 75 6.5 to 11.5 25.8 to 40.8 12.7 to 52.7 50 to 200 11.7 to 41.7 g u I a • I I I I I I I I very competent with little or no fractures. The pumping rates and specific capacities of the two boreholes NS-46 and NS-48 in the bedrock in Area 2 were found to be small at depths I 03 to 111 feet below the ground surface. Analysis of groundwater samples taken from the two bore holes NS-46 and NS-48 during the Packer Tests indicated that the contamination in the groundwater at depths ( over 144 feet in NS-46 and over 131 feet in NS-48) is very small. Thus, from about 130 feet to the bottom of the two Bedrock Wells groundwater is found to be only slightly contaminated. This detected low level contamination in the lower portion of the boreholes in this area might be due to either of the two following reasons: 1. Groundwater at the bottom of the Bedrock Extraction Wells in Area 2 may have been contaminated by migration of contaminated groundwater from above through the open bore holes during the drilling and well installation operations. This contaminated water may not have been completely removed during purging of the borehole while conducting the Packer Tests. As a result low level contamination remained in the bottom portion of the two boreholes . If the bottom groundwater contamination in the Bedrock Wells in Area 2 is the result of upper contaminated water migrating downwards, then this contamination will be temporary and will disappear after these Extraction Wells are operated for three to six months; or 2. Groundwater in Area2 of the Plant is contaminated beyond the 200 feet (from the ground surface) depth of drilling and installation of the two Bedrock Extraction Wells. In that case, the low level contamination found in the bottom groundwater of the two Extraction Wells in Area 2 will persist even after operation of these wells for three to six months. Then the contamination of the bedrock in this area may be deeper than the 200 feet estimate made during the conduct of the Remedial Investigations. In such a case, additional Drilling and Packer Testing will be needed to determine the vertical extent of groundwater contamination in Area 2. At this time, based on review of the available data, National Starch and Chemical Company (NSCC) believes that the low level contamination detected in the lower portion of the two bore holes in the bedrock in Area 2 may have been caused by vertical migration of contaminated groundwater from the upper Saprolite and Bedrock zones through the open boreholes. To verify this, NSCC proposes to conduct the Pump and Treat operations at the two Bedrock Extraction Wells in Area 2 for a period of six months. At the end of six months of operation of the Bedrock Extraction Wells, NSCC will review the groundwater contamination data from these two bedrock wells. If the groundwater contamination persists in Area 2 bedrock wells, NSCC proposes to drill a new deeper bedrock well in this area. The upper 150 feet of this bedrock well will be cased to prevent migration of contaminated groundwater from above to the lower levels of the bedrock. Drilling of the new C:\PROJECTS\SALSBRY\OUJRES4.AA 3 0 H D g g a I I I I I I I I bedrock well beyond the 150 feet depth will be extended in 50 feet intervals up to 250 feet. Each 50 feet depth of the new bedrock well will be Packers Tested and samples of groundwater will be collected to determine whether the groundwater within this interval is contaminated or not. If the groundwater from this 150 to 200 feet interval is found to be contaminated, then the borehole will be extended another 50 feet (from 200 feet to 250 feet). Packer Tests of this zone will then be conducted and samples will be collected for analysis. Based on available data NSCC expects the 200 to 250 feet zone of the bedrock to be uncontaminated. Comment No. 5 Page 93, Section 8.2; Based on the text presented in this section, it appears that the vertical extent of the contamination was not defined in Lagoon 2 area. Response No. 5 It is correct that the vertical extent of groundwater contamination of the bedrock zone in the Lagoon 2 Arca could not be confirmed from the sampling and analysis of the three Bedrock Wells NS-50, NS-52 and NS-54 during the Packer Tests. However, during the drilling of the boreholes in the Lagoon 2 area, except for bore hole NS-54 the Bedrock in the NS-50 and NS-52 boreholes were found to be competent with some fractures at different depths. The pumping rates and specific capacities of the two boreholes NS-50 and NS-52 were found to be small at depths beyond 140 to 150 feet below the ground surface. But the pumping rate and specific capacity of bore hole at NS-54 beyond depth 175 feet below the ground surface were high. Analysis of the groundwater samples taken from the three bore holes NS-50, NS-52 and NS-54 during the Packer Tests indicated that the contamination in the groundwater at depths beyond 170 feet was high and the groundwater is contaminated down to the bottom of all three Bedrock Wells in the Lagoon 2 Area. This detected contamination might be due to either of the two . following reasons: l. Groundwater in the Lagoon 2 Area of the Plant is contaminated beyond the 200 feet depth (from the ground surface) of drilling and installation of these Extraction Wells. Additional Drilling and Packer Testing will be needed to determine the vertical extent of groundwater contamination in the Lagoon 2 Area; or 2. Groundwater at the bottom of the Bedrock Extraction Wells in the Lagoon 2 Area may have been contaminated by vertical migration of contaminated groundwater from above through the open bore holes during the drilling and well installation operations. If the bottom groundwater contamination in the Bedrock Wells in the C:\PROJECTS\SALSBRY\OUJRES4.AA 4 I u g g I • I I I D D D Lagoon 2 Area is the result of upper ~ontaminated water migrating downwards through the open bore holes, then this contamination will disappear after these Extraction Wells are operated for three to six months. However, if the contamination of the bottom groundwater in these Extraction Wells persist after operation of these Extraction Wells for three to six months, then additional deeper Bedrock Wells will be needed to define the vertical extent of groundwater contamination in the Lagoon 2 Area. At this time National Starch and Chemical Company (NSCC) is not fully convinced that the detected contamination at the bottom of the Extraction Wells in the Lagoon 2 area is due to groundwater contamination extending beyond the 200 feet depth from the ground surface. However, it is likely that groundwater contamination in the Lagoon 2 area extends beyond the 200 feet estimate developed by IT Corporation during the Remedial Investigations ofOU3. To verify this, NSCC proposes to operate the Pump and Treat System for the Bedrock Extraction Wells in the Lagoon 2 area for a period of six months. At the end of six months of operation of the three Bedrock Extraction Wells, NSCC proposes to drill an additional deeper bedrock well in the Lagoon 2 area to determine the vertical extent of groundwater contamination in this area. This deeper borehole will be cased from the ground surface to 200 feet below the ground to prevent movement of contaminated upper level groundwater to the lower depths. After installation of the casing, the borehole will be extended. Drilling of the new bedrock well beyond the 200 feet depth will be extended in 50 feet intervals up to 300 feet. Each 50 feet depth of the new bedrock well will be Packer Tested and samples of groundwater will be collected to determine whether the groundwater within this interval is contaminated or not. If the groundwater from this 200 to 250 feet interval is found to be contaminated, then the borehole will be extended another 50 feet (from 250 feet to 300 feet). Packer Tests of this zone will then be conducted and samples will be collected for analysis. Following review of the data from this depth, need for further drilling beyond the 300 feet depth will be established after consultation with the USEPA and the NCDEHNR. C:\PROJECTS\SALSBRY\OU3RES4.AA 5 I u g I n I g I I I I I Responses to U.S. EPA ,Comments (05/12/97) on the Remedial Design/Remedial Action Conceptual Design Report for the Third Operable Unit (OU3) National Starch & Chemical Company Cedar Springs Road Plant, North Carolina Conceptual Design Report Contents Comment No. 1 Page 16, Section 2.6, second paragraph, third sentence: Typo, "aand". Response No. 1 Correction made. Thanks. Comment No. 2 Tables 2-3 through 2.6 (where applicable): Define the data qualifiers "D" and "E". The temperature of the water for each trail should be incorporated into each table. Response No. 2 Qualifiers "D" and "E" have been defined and are as follows: D E Dilution Performed Exceeds Calibration Range Temperature data for each trial have now been added to the data in Tables 2-3 through 2-6. Comment No. 3 Tables 2-3 through 2-6: What parameter(s), if any, were changed/altered between the two tests incorporated into each table. For example, in Table 2-3, what is the difference between Trail B (8 scfm) and Trail C (8 scfm)? Or were these two trails duplicates? C:\PROJECTS\SALSBRY\OU3RES4.AA 6 a g a g I I I I I I I I Response No. 3 In each of Tables 2-3 through 2-6 two sets of test results are presented for two separate Trial Runs. Same volume of contaminated groundwater and same air flow rate were used during both of these tests. Only differences between the two tests presented in each table are that two different samples with different quality characteristics were used in these two tests conducted on two different days and the temperature of the groundwater in the Aerator varied somewhat during the two tests due to variations of ambient conditions. The intent of the two tests using the same air flow rate but different quality characteristics was to demonstrate that the system is equally effective with groundwater of different quality characteristics. Comment No. 4 Page 25, Section 3.1 This section lists the designed pumping rates (gpm) for each of the Extraction Wells, however, there are no calculations and rationale for deriving these pumping rates. This information needs to be incorporated into the document. Response No. 4 The design pumping rates (gpm) presented in Section 3.1 are based on computerized modeling and analysis of the drawdown characteristics of the Saprolite and Bedrock Aquifers in Area 2 and in the Lagoon 2 area of the Plant. These drawdown characteristics were measured during the Step-Drawdown Tests in the ten newly installed Extraction Wells (5 Wells in Saprolite and 5 Wells in the Bedrock) and nine previously installed Monitoring Wells ( NS-I 3, NS-14, NS-24, NS-35, NS-36, NS-39, NS-40, NS-41 and NS-42). Data collected during the Step-Drawdown Tests were used together with computer simulation to determine the cumulative drawdowns and groundwater surface contours in Area 2 and in the Lagoon 2 area at various rates of pumping from the ten Extraction Wells. Table 3-2 presents the drawdown measured during the Step-Drawdown Tests and calculated cumulative drawdowns at all Extraction Wells under design pumping rates. Computer analysis was then used to calculate the areal extent of the cumulative drawdown (Area of Influence) due to pumping from the Extraction Wells at various locations. The Design Pumping Rates given in Table 3-1, are the pumping rates at which sufficient drawdowns are created in Area 2 and in the Lagoon 2 area so that the Area of Intl uence extends over the entire Contaminant Plume in both locations. This allows efficient extraction of the Contaminant Plume without inducing excessive migration of uncontaminated groundwater from outside the Contaminant Plume into the Contaminant Plume. Figure 3-2 illustrates the Area of Influence in Area 2 of the Plant while Figure 3-3 illustrates the Area of Influence in the Lagoon 2 area under design pumping rates and conditions. C:\PROJECTS\SALSBRY\OU3RES4.AA 7 l!!!!!I I!!!!!!! 1!!!!!!11 l!!!!!!il ll!!!!!!I 1!!!11!!!1 l!!!l!!!iil -lilil -liili lililiil ;a; -;;;;a liiii1 i;;;;;i == == Table 2-4 Results of Pilot Test Trials D and E Salisbury Plant Groundwater Remediation System -Operable Unit 3 1 n,n1n,rn1,:;a Trial (Flowrate/femp.) Trial D !12 scfm//l 3.4°C1 Sample ID D-1 D-2 0-3 Sample Interval (hr.) 0 3 6 Parameter (ug/1) Methylene Chloride 2000 JB 40 JB 2 Acetone 2500 u 20 JB 9 I ,2-dichloroethane 36000 I I 00 78 Total Concentration(ug/1) 40500 1160 89 Percent Removal 97.14 99.78 Notes: 2000 J = Reported value is an estimate 2000 B = The paramter was also detected in the method blank 10000 U = The value is less than the detection limit. D = Dilution performed E = Exceeds calibration range C:\PROJECTS\SLSBRY\OUJ\OUJCNDES.SV JB JB Trial E !12 scfm/16.4°C) 0-4 E-1 E-2 E-3 9 0 3 6 2 JB l000 JB 300 J 30 J D 6 JB l000 .TB 200 JB 40 JB D 9 J 90000 ED 8800 790 17 92000 9300 860 99.96 89.89 99.07 22 E-4 9 3 J 8 JI3 91 102 99.89 liiiiiil liiiiiil == == == == 1111,1 == 1111,1 1111,1 l!!!!I l!!!!!!I l!!!!I !!!!!!!!!I I!!!!!!!!! -l!!!!!!!i l!!!!!!!i!I - Table 2-5 Results of Pilot Test Trials F and G Salisbury Plant Groundwater Remediation System -Operable Unit 3 I J/1 nl 14.{)1t::O Trial (Flowrate/Temp.) Trial F (16 scfm/16.8°C) Sample ID F-1 F-2 F-3 Sample Interval (hr.) 0 3 6 Parameter (ug/1) Methylene Chloride 1400 J u Acetone u 48 DJ 17 B 1,2-dichloroethane 67000 2000 30 Total Concentration(ug/1) 68400 2048 47 Percent Removal 97.01 99.93 Notes: 2000 J = Reported value is an estimate 2000 B = The paramter was also detected in the method blank I 0000 U = The value is less than the detection limit. D = Dilution performed E_ = Exceeds calibration range C:\rROJECTS\SLSBRY\OUJ\OUJCNDES.SV Trial G (I 6 scfm/18.0°C) F-4 G-1 G-2 G-3 9 0 3 6 u 3 J 3100 J u u B 27 B 2800 JB 63 DJ IO JB B 2 120000 3400 51 32 125900 3463 61 99.95 97.25 99.95 23 G-4 9 3 J 10 JB 3 J 16 99.99 --!!!!!I l!!!!!!I l!!!!!!!!!I !!!!!!!!!I l!!!!!!!!!I l!!!!!il!!I l!!!!ii!!I liiilil --liiiii liiiiliilliil liiiiil lllilil -= -= - Table 2-6 Results of Pilot Test Trials Hand I Salisbury Plant Groundwater Remediation System -Operable Unit 3 I I 11 ~ •t\01.hO Trial (Flowrate/Temp.) Trial H (20 scfm/16.6°C) Sample ID H-1 H-2 H-3 Sample Interval (hr.) 0 3 6 Parameter ( ug/1) Methylene Chloride u u Acetone 970 JB u 84 DB 12 1,2-dichloroethane 61000 510 D 6 .. Total Concentration(ug/1) 61000 594 18 Percent Removal 99.03 99.97 Notes: 2000 J = Reported value is an estimate 2000 B = The paramter was also detected in the method blank 10000 U = The value is less than the detection limit. D = Dilution performed E = Exceeds calibration range C:\PROJECTS\SLSBRY\OU3\0UJCNDES.SV u B J Trial I (20 scfm/14.3°C) H-4 1-1 1-2 1-3 9 0 3 6 u u u u 13 B 1300 JB 83 B 76 B u 140000 1400 E 76 13 141300 1483 152 99.98 98.95 99.89 24 1-4 9 u 66 B u 66 99.95 I H n a TABLE 3-2 SALISBURY PLANT GROUNDWATER REMEDIATION SYSTEM· OPERABLE UNIT 3 EXTRACTION WELL DRAWDOWN CALCULATIONS Drawdowns at Ste;, Test Pumping,_.R_.,a.._.t,ces,,_ ________ ~====-=--------------~ Pumping Pt=J;>ing DRAWDOWNS Well : RaTE. g,"pm"'--'-'N-"S_-4c:5_..cN.:.S=.·.c.46=--''-"Nc:Sc..-4cc.7...;.l ..cN.:.S=.·..c48,,_...;.Nc:Sc..·4c:9:_;.I _N:.:S,c·.=5.::.0_..cN::.,Sc..·5=-1:....c-'-'N-=S•.=5:::.2--.--'N"'S'-'·5::.:3:.:..c_.:.:N,cS·.=5.:.4...: I I I NS-53 .110 2.141 0.291 0.61 1.•./¥t26,74' 17.131 fl NS-54 30 1.47! 1.6, 0.311 0.5, 11.91 ?$1\1:48,22 II Total :99 53.13 136.96 59.27 106.12 42.49 167.46 i 35.54 117.51 12.36 96.37 I Static Waler Deptr Pump lnlake Dept:'", Max. Allowed Dra-wdown 8.37 54.45 46.08 15.15 23.84 188 40.55 172.85 16.71 16.43 187 170.57 8.72 107.12 98.4 8.03 186.12 178.09 6.39 107.22 100.83 5.89 186.12 180.23 9.06 107.22 98.16 8.14 174.12 165.98 I Drawdowns at Design PumJ)ing-'R_.,a,.,te,cs,,_ _________ --=====.--------------~ Pumping 1 , Ptr.iping DRAWDOWNS Well Rat:. gpm NS-45 NS-46 NS-47 NS-48 ! NS-49 NS-50 NS-51 NS-52 NS-53 NS-54 I I I NS-45 NS-46 NS-47 NS-48 NS-49 NS-50 NS-51 NS-52 NS-53 NS-54 ; .8 5 2 ·,4 ;5 5 ;o 5 20 5 1.81 :xc,,10.42 0.15· 0.31 · 0.151 o.08i 0.22 0.22 ,,,20.64: 2.72, o 02 i o I 0.34' 0.34 1.41 ,~-f.• 17:-18 I I o.89, o.94 o.o7; 0.18 ~'1fL12,13 6.59 0.14 1 o.17 o.04: 0.06 1 1.43 f·•n9,32 Total 83.8 40 151.68 12.36 123.26 17.96 18.62 22.52 21.18 14.27 26.31 m Static Water Levels & Well Elevations Well No. NS-45 NS-46 NS-47 ! NS-48 ' NS-49 NS-50 NS-51 NS-52 NS-53 ! NS-54 I m i I I ,Top of Casing Elevation, f 754.85 768.99 I 769.621 770.22! 766.98 766.08 764.98' 764.67: 770.131 770.28 i Initial Depth to Water, ft 8.37 15.151 23.841 16.43 I 8.72; 8.03 6.39• 5.89' 9.061 8.14 I Static Water Level. ft 746.48 753.84 i 745.78 ! 753.79 i 758.26 758.05 758.59' 758.78 i 761.07 I 762.14 I m Water Levels at Design PUmf)ing,..'.R_.,a.._.tcies:a-, ... ~=~--.--cc.-c~c-c==--.-~~~~=~-==~~=~~=~~ Well No. NS-45 NS-46 NS-47 I NS-48 NS-49 ' NS-50 · NS-51 NS-52 NS-53 I NS-54 I m ,Water Level Elev .. ft I D D D OU3DDN.WK4 706.48 602. 16: I I I 733.421 630.53 740.3' 739.43 736 07; 737.6, 746.8 I 735.83 I Page 1 06/03/9708'.38 AM Ir- I I I I I I I I I I I I I I I I I IL DRAWDOWN CONTOURS EXTENT OF CONTAMINATION -- () N. C. GRID NORTH (NAO BJ) [NJ,tlonal Starch and Chem/col Company SALISBURY, NC PLANT V .x X X AREA 2 EXTRACTION WELLS AREA OF -INFLUENCE JUNE 1997 FIGURE 3-2 7 _J ---~· -----.---------------:;,--~----------,-------------,7 I I I I I I I I I I I I I I I I I I 0 • N. C. GRID NORTH (NAO BJ) * DRAWDOWN CONTOURS EXTENT OF CONTAMINATION \ cP )\ ¥-0 / * V .x X X X X J ~~G~ \ \'--' \ /\ / * / r I- 0 50 100 150 JOO FEET {Nj,tlonal Slorch and Chem/co/ Company LAGOON AREA EXTRACTION WELLS AREA OF INFLUENCE. SALISBURY, NC PLANT JUNE 1997 FIGURE 3-3 _J I I I I I I g u u D D Comment No. 5 Page 25, Section 3. I, second paragraph, first sentence: This sentence states "120,000 gallons of contaminated groundwater" however it does not give a time frame (i.e., gallons per hour, gallons per day, etc.). Response No. 5 This sentence is now corrected to read " A total of 120,000 gallons of contaminated groundwater will be pumped each day from these ten newly installed Saprolite and bedrock Extraction Wells installed for OU3.". Comment No. 6 Page 26, Table 3-1: This table should also account for other parameters (general water chemistry) such as pH, hardness, etc. that will need to be measured and controlled. Response No. 6 Table 3-1 lists the critical VOC, SVOC and inorganic metal contaminants and their expected concentrations in the Influent to the Air Stripping System and expected concentrations of these contaminants in the Effluent from the Air Stripping System. Besides the contaminants listed in Table 3-1, NSCC will measure and record other general chemistry parameters such as pH, Temperature, COD, TSS, TDS, etc. in the Effluent from the Air Stripping Treatment System. However, these are not critical parameters for air stripping. Because of this they are not listed in Table 3-1. Since the Effluent from the Air Stripping System will be treated further together with other wastewater and contaminated groundwater in the Salisbury Plant's existing Combined Pretreatment System it is not necessary to measure the suggested parameters for the Diffused Air Stripping System. These parameters are now measured in the Combined Pretreatment System for both the influent and effluent streams. However, if USEP A requires these measurements NSCC will measure and report these parameters together with the VOC, SVOC and metals. C:\rROJECTS\SALSBRY\OU3RES4.AA 8 I I I I I I I I I I I I n D m I I Comment No. 7 Page 27, Section 3.2, first sentence: Typo, this sentence contains two typos. Response No. 7 Typos noted and corrected. Thanks. Comment No. 8 Page 27, Section 3.3, fourth paragraph: Is there a point in time when NSCC anticipates being able to by-pass the thermal oxidizer and discharge the exhaust air from the Diffused Air Stripper Tanks straight into the atmosphere? If so, this situation needs to be discussed in this section. This discussion should include the pertinent parameters that will lead NSCC to propose by passing the thermal oxidizer. Response No. 8 At this time NSCC does not anticipate bypassing the Thermal Oxidizer because of the presence of Acrylonitrile in the contaminated groundwater from the Trench Area. In order to meet NSCC's Air Permit Discharge requirements it will be necessary to thermally oxidize the Acrylonitrile and other VOC's and SVOC's that might be present in the exhaust air from the three Diffused Air Stripper Tanks. Comment No. 9 Page 27, Section 3.3, fifth paragraph: Will the treated groundwater from OU #3 and the Trench Arca be combined prior to being pumped to Lagoon #I? Response No. 9 The Diffused Aeration Treatment System proposed in the Conceptual Design Report uses separate Reactors for treating these two contaminated groundwater streams because of the significant difference between the quality characteristics of the two streams. After treatment the air stripped effluent from each Reactor will be pumped separately to Lagoon No. I. The two separate streams will then combine and mix in Lagoon No. I with other wastewater and contaminated groundwater from the Plume Periphery Extraction Wells. C:\PROJECTS\SALSBRY\OUJRES4.AA 9 I I I I I I I I I I I I I I I I D 6 E Comment No. IQ Figures 3-1 A and 3-1 B: The estimated flow rates should be incorporated into these figures. Response No. I 0 Estimated flow rates will be included in the two Process Flow Diagrams (Figures 3-1 A and 3-lB). C:\PROJECTS\SALSBRY\OU3RES4.AA 10 r I I I I I I I I I I I I I I I I I I L- ---------------------------------------------,7 ' ~ NS-47 2""" NS-40 . """ NS-45 1.8 GPM AREA 2 SURGE TANK 2,000 GAL I CONTAINMENT FROM TRENCH ARtA WELLS ~ g NS-48 14 CPU ' ~ NS-49 ,. """ - ' I:: --NS-50 . """' EXISTING PUMPS ' ~ NS-51 10 GPV [XISTlNC TRENCH WA TEA SUMP ' ' ' ~ NS-5.J 20"""' I= .... ~ ~ ~ ----NS-52 NS-S4 . """ . """ 25,000 CPO R(V. ABO ii.2. xt<Li, Sc.b., P.E. IIOtTH CAIIICUuo fl' L. NO. ~ "'"""""" . TRENCH WA T!R EQUALIZATION TANK (EXISTING Sl.UOCE TANK) 11,JOO CAL I -- - 003 RAW WATER ECUAUZATION TANK (EXISTING HYORO. YSIS TANK) 19,900 GAL ~ TRENCH WA TEA TRANSFER PUwPS EXISTING CONTAINMENT RAW WATER TRANsrtR PUMPS EXISTING CONTAINMENT DATE Clf-»IP. $CAL[: lilOJrl[ {Ngttonal Starch and Chemical Company SALISBURY PLANT OPERABLE UNIT 3 GROUNDWATER REMEDIATION SYSTEM TO AERATION TANK NO. ◄ 25,000 CPO 120.960 CPO TO AERATION TANKS 1, 2, 3 PROCESS FLOW DIAGRAM SHEET 1 JUNE 1997 I FIGURE 3-1A _J rr=-----------~--- 1 I I I I I I I I I I I I I I I FROM TRENCH WATER ECUAUZA TION TANK 25,000 GPO 120,960 GPO FROM OUl EOUAUZATION TANK D--"-'<--0 C & C N " 0 • -I D--"-'<--0 • OV9 MOV, T MOVll MOV21 MOV10 MOV2 T MOV,4 MOV22 -- AERATION TANK NO. 1 .. . . . . .. ., . . . AERA TICIN BLOWERS "' / --~--------~_______,,/ ~ EXISTING LACOON NO. 1 . MOV,7 I-<~>- I .L ' D , ...... ·-I TR[A TtD WATER TRAN5r[R PUMPS ~ - AERATION TANK NO. 2 .. , • • .. , • • .. ., .. i .L .L ' l . ~ h,) ~ - MOV,B . ~>-l] I I REORCULATlON PUMPS .L ( ,.-' ~ C & C N " ~ -I D--"-'<--0 MOV11 MOVJ T MOV15 - AERATION TANK NO. 3 .. ., .. ., . " .. UP TO 350 CPM REOROJLA TION "" MOV2l MOV,9 ~>-k[l • I NA l\JRAI. CAS g § ~ MOV,2 MOV4 T MOV16 D--"-'<--0 '<--0 -- AERATION TANK NO. 4 . . . . . . TO ATMOSPHERE EXHAUST STAO< HEAT EXCHANGER THERMAL Q)(IOIZ£R I ACV. DESCRIPTION DATE ._"' ~ =~ L..,..,onal Storch and Chemical Company '<--0 MOV24 . . . M9V20 " . ~;s:7 •""'- I (:----1---~ PROCESS FLOW DIAGRAM SHEET 2 -~ SALISBURY PLANT OPERABLE UNIT 3 ~-------------------------------------J_m_0_..::_~_-,_::-_.·_.~~~~·~~--··_'·....L-J_ ______ ..-J. __ .L__""" __ '-_ __J __ G_R_O_u_N_D_w_A_T_E_R __ R_E_M_E_D_IA_T_I_O_N_S_Y_S_T_E_M_..L._ ___ J_uN_E_19_9_7 ___ .L_ __ FI_G_U_R_E_3_-_,_B_==1._J I I I I I I I I I I I I I I I I I I I Responses to NCDEHNR Comments (05/09/97) on the Remedial Design/Remedial Action Field Investigations Summary Report for the Third Operable Unit (OU3) Comment No. I Figures 2-2, 2-3 Response No. 1 Figures 2-2, 2-3 Comment No. 2 Sect. 2.4 Response No. 2 Section 2.4 A:\OU3RES4.AA National Starch & Chemical Company Cedar Springs Road Plant, North Carolina These figures should be amended to include a legend to identify the scale of the map, symbols, location of plant, contour interval, and reference datum. These figures already contain a scale (l" =500') at the bottom of the figures. Additional text and notations will be added to make the scale clearer. The first paragraph of this section indicates that the "Summary of site Characteristics" portion of the report does not include the data collected as part of the OU3 RD/RA Field Investigations. It is recommended that National Starch & Chemical Company (NSCC) amend the summary of site characteristics to include the data collected as part of the RD/RA Field Investigations. Section 2 of the RD/RA Field Investigations Report presents background information and data collected during the Remedial Investigations. The intent of this section is to inform the reader of the background of the site and results of past investigations. The data collected during the RD/RA Field Investigations should not be presented in this section. NSCC agrees with NCDEHNR that the data collected from past Field Investigations should be combined with data collected during the RD/RA Field Investigations to evaluate and determine current site characteristics. Table 6-4 has been added in the RD/RA Field Investigations Summary Report to summarize the current site characteristics for Groundwater together with site characteristics determined during the OU3 Remedial Investigations. 11 ~----------------- 1 I I I I I I I I I I I I I I _, 'J-':---, V 'v ,) "' ' <>D /2 N + ◊ ' 500 0 500 I -250 Scale 1 inch ~ 500 ft. TRENCH AREA 750 _.., I.T. LAG I NO + + & + ( ~ ,, ~ =+-O.~ 1/ SITE MAP ' I {ij..JlolXJI Sfort:h and Chemical Company CEDAR SPRINGS, NC PLANT '---------------------------------------------'---"-••_•·_._"'°___,_· _____________ __,_ __ M_AR_CH_1_99_1 _ __J __ r...:;g'-ur_e_2_-2_~ I rr=-----~--------- 1 I I I I I I I I I I I I I I I N + _, 0o ''."'-. ) 'v , ,..., AIRPORT ROAD 500 0 500 ---------250 750 + + 1/ {ilj,tlonaf Slarch and Chem/co/ Company WATERSHED MAP I Scale 1 inch = 500 ft. -~ CEDAR SPRINGS, NC PLANT c___~=------------------------------------------.L""'_••_·._,oo_·L_ ____________ ._J_ __ M_AR_CH_19_97 __ .J._ __ Fi.e,:.gu:....re:....2::_-...:.3_~ I I I I I I I I I I I I I I I I I I I Table 6-4 Range and Frequency of Detection of Organic Contaminants and Inorganic Constituents Phase I and II OU3 RI and Field Investigation of OU3 RD/RA Compound Volatile Organic Compounds Acetone Bromodichloromethane 2-Butanone Carbon Disulfide Chloroethane Chloroform Dibromochloromethane 1,2-Dichloroethane 1, 1-Dichloroethene 1,2-Dichloroethene 1,2-Dichloropropane Ethylbenzene · Methylene Chloride Tetrachloroethene Toluene 1, 1,2-Trichloroethane Trichloroethene Total Xylenes Vinyl Chloride Groundwater from RI 9-4,200 (15) 1 4-8 (3) 3-35 (6) 7-8,900 (2) 1-660,000 (30) 1-14 (3) 1-200(4) 5 9-36 (2) 1-160 (5) 107 (4) 1-120 (3) 1-5 (10) 2-90 (4) 1-120 (8) Groundwater from RD/RA 4-2000 J (9) 130-260,000 (I 0) 2-3000 J (8) Concentrations for water samples are reported in micrgrams per liter (ug/1) or in parts per billion (ppb.) Number appearing in parenthesis is the frequency of detection. . The reported values for Groundwater RD/RA are only from the ten new extraction wells. C:' PROJ ECTS\SLSBR Y\OU3\0U3CNDES. S V 8 I I I I I I I I I I I I I I I I I I I Table 6-4 (Continued) Range and Frequency of Detection of Organic Contaminants and Inorganic Constituents Phase I and II OU3 RI and Field Investigation of OU3 RD/RA Compound Groundwater from RI Groundwater from RD/RA Semi-Volatile Organic Compounds Bis(2-chloroethyl) ether Bis(2-ethylhexyl)phthalate Di-n-butyl Phthalate 2-Methyl Phenol N-Nitrosodiphenyllarnine Pesticide Delta-1-lexachlorocyclohexane 13-32 (2) 8 2-17 (3) 0.16 3-I 6 (7) 2 J (I) 2 J (I) NA Concentrations for water samples are reported in micrgrams per liter (ug/1) or in parts per billion (ppb.) Number appearing in parenthesis is the frequency of detection. The reported values for Groundwater RD/RA are only from the ten new extraction wells. \ C:\PROJ ECTS\SLS 13 R Y\OU 31QU3CNDES. S V 9 I I I I I I I I I I I I I I I I I I I Comment No. 3 Sect. 2.4.1 Response No. 3 Section 2 .4 .1 Comment No. 4 Table 2-1 Response No. 4 Table 2-1 A:\OU3RES4.AA This section, titled "Site Soil Characteristics", lists the contaminants and their concentrations in the soil. This section should also contain a description of the type of soil (from ground surface to water table) including properties such as chemistry, permeability, classification, grain size, etc. Section 2 of the RD/RA Field Investigations Report presents background information and data collected during the OU3 Remedial Investigations. The intent of this section is to inform the reader of the background of the site and results of past investigations. The requested data were presented in the two OU3 Remedial Investigations Reports. The purpose of the RD/RA Field Investigations is to collect data necessary to conduct design of the facilities for Groundwater Remediation at OU3. No soils data such as background chemistry, classification, grain size, etc. were collected during the RD/RA Field Investigations because it was not necessary for design. The term "frequency of detection" should be more clearly defined. The term "frequency of detection" in Table 2-1 is meant to indicate the number of times that particular VOC, or SVOC, or Pesticide, or Inorganic Constituent was detected during the Remedial Investigations conducted for O U3. 12 I I I I I I I I I I I I I I I I I I I Comment No. 5 Table 2-l Response No, s Table 2-1 Comment No. 6 Sect. 2.4.2 Response No,6 Section 2.4.2 A:\OU3RES4.AA It is recommended that the inorganic analytical results be grouped to distinguish up-gradient ( or background) concentrations from down- gradient concentrations. This may help NSCC examine the inorganic constituents that are naturally occurring. Table 2-1 of the RD/RA Field Investigations Report presents background information and data collected during the OU3 Remedial Investigations. The intent of this section is to inform the reader of the background of the site and results of past investigations. Evaluation of this data in terms of up-gradient and down-gradient wells were conducted during the conduct of the Feasibility Study. Further analysis of the data in terms of up-gradient and down-gradient wells are unnecessary and will not be done. This section titled "Site Groundwater Characteristics" provides information on the number and types of sampling points and the name and concentration of contaminants ( excluding the information generated during this investigation). It is recommended that the section be amended to include (1) the information generated during the RD/RA Field Investigations for OU3, as noted above, and (2) a description of the up- • gradient (or background) groundwater quality conditions. Section 2 of the RD/RA Field Investigations Report presents background information and data collected during the OU3 Remedial Investigations. The intent of this section is to inform the reader of the background of the site and results of past investigations. The data collected during the RD/RA Field Investigations should not be presented in this section. NSCC agrees with NCDEHNR that the data collected from past Field Investigations should be combined with data collected during the RD/RA Field Investigations to evaluate and determine current site characteristics. Groundwater data from past Remedial Investigations at OU3 are now summarized with groundwater data from the RD/RA Field Investigations in Table 6-4 of Sections 6 of the RD/RA Field Investigations Summary Report. 13 I I I I I I I I I I I I I I I I I I I Comment No. 7 Sect. 2.4.4 Response No. 7 Section 2.4.4 A:\OU3RES4.AA This section titled "Hydrogeological Setting", provides a brief description of some of the aquifer characteristics. As noted above, it is recommended that NSCC include the information developed during this investigation. It is recommended that this section also include: I. 2. 3. 4. 5. Potentiometric maps for the different zones of the aquifer, and cross-sectional flownets of the site; An analysis and discussion of fracture trends and other preferential pathways for groundwater flow; A description of discharge and recharge zones at the site; Descriptions of different aquifer zones (e.g., shallow, saprolite, & deep); An interpretation of contaminant flow in the aquifer. Section 2 of the RD/RA Field Investigations Report presents background information and data collected during the OU3 Remedial Investigations. The intent of this section is to inform the reader of the background of the site and results of past investigations. The data collected during the RD/RA Field Investigations should not be presented in this section. NSCC agrees with NCDEHNR that the hydrogeological data collected from past Field Investigations should be combined with hydrogeological data collected during the RD/RA Field Investigations to evaluate and determine current site characteristics. Section 5 of the RD/RA Field Investigations Summary Report has been modified to include the updated evaluation of site hydrogeological data. NCDEHNR's recommended item 1 for providing the Potentiometric Maps for the Saprolite and Bedrock zones and item 5 for providing an interpretation of contaminant flow are presented in section 5. Table 5-23 presents the groundwater elevations for the saprolite and bedrock wells collected during the RD/RA Field Investigations and Figures 5-1 and 5-2 show the potentiometric surface elevations for the saprolite and the bedrock aquifers. NCDEHNR's recommendation to include items 2, 3 and 4 is unnecessary, does not contribute any information to the Remedial Design and will require substantial additional effort including additional field work. These recommended items are not be included. 14 I I I I I I I I I I I I : I I I 'I I I I Well I.D. Saprolite Wells NS-03 NS-12 NS-13 NS-14 NS-33 NS-35 NS-37 NS-39 NS-42 NS-43 NS-45 NS-47 NS-49 NS-51 NS-53 Bedrock Wells NS-24 NS-34 NS-36 NS-38 NS-40 NS-41 NS-44 NS-46 NS-48 NS-50 NS-52 NS-54 Table 5-23 Groundwater Elevations for Saprolite and Bedrock Wells RD/RA Program Cedar Srpings Road Plant Depth to Elev. of Elev. of Water (ft.) TOC (ft.) Groundwater (ft.) 12.2 774.28 762.08 12.8 777.36 764.56 5.8 762.69 756.89 5.3 765.36 760.06 10.25 776.36 766.11 4 746.11 742.11 30.95 746.11 715.16 9.2 769.91 760.71 7.35 766.16 758.81 IO.OS 759.38 749.33 8.25 754.85 746.6 23.8 769.62 745.82 8.3 766.98 758.68 6.7 764.98 758.28 8.55 770.13 761.58 21 758.32 737.32 11.55 776.27 764. 72 3.85 745.59 741.74 30.35 745.61 715.26 8.55 769.34 760.79 7.2 766.03 758.83 9.65 759.3 749.65 16. 15 768.99 752.84 15.95 770.22 754.27 7.3 766.08 758.78 5.85 764.67 758.82 8.4 770.28 761.88 Notes: Water level readings recorded on February 6, 1997. I : I I tp 0 C -z_ 0 1 --< L I NOTE: ELEVATIONS 8ASEO ON N.G.V.0. Of 1929 MOH. I •10 JAS 1966 790• -El..EVATION: 789.4~' Vl£ll SlRVEY SY SHULENEIJRGEA SURVEYING COIIPANY 516 N. MAIN ST., SAUS8URY, N.C. PHONE: (704) 6J7-N2J LEGEND IO NS-39 (760.71) I~ I Saprolite .,.. Locotion a: Gr11Undwot11r Oevotion (II. MSl.) Grounctwoter Counlor (ft. USL) 730 740 PROPERTY LINE (APPROX) ,., ,., \ I ) ■ ■ • ■ • f ■ • • • • 0 U)O 200 <00 000 800 Figure 5-1 Groundwater Elevation Contours Saprolite Wells NATIONAL STARCH & CHEMICAL CO. L__ ________ ..1_ _______________________________________ ----'-------------------~ I I I I I I NS-oii o:J 0 C -z t:J J;> ;Q -< L NOTE: ELEVA TJONS BASED ON N.G. V.0. ~ 1'1:nil YON. "10 JA5 1966 790" -[l£VATION: 7811.452' WEll ~y 8Y SHULENBURCER SURVEYING COMPANY 516 N. ~ ST .. SAUSEIURY. N.C. PHOfril(: (704) 6J7-962J l1--~L=-EG=E=N-"D'----'-------; 0 NS-39 Beo,od,; w.n Locotlon 6: (760.71) Potenllom■trlc Surfoc■ (It. 1151..) I ~ Potenliom11trlc Counlor (ll. IISL) -~ 720 730 L ~ -------· .. // ;,-/ /,/ /✓1/ /, 1/ // ;'. / I I. \I 0 \ NS-45 PROPERTY LINE (APPROX) 740 NS-r (764.72) NS-JJ .,., .,., \ I ) ;i ~ ~ ~ ! z Q s u z ..... .,... ..... -. ■■■■■--0 100 200 600 800 Figure 5-2 Potentiometric Surface Contours Bedrock Wells NATIONAL STARCH & CHEMICAL CO. iL__ ___ ----1. _____________________ ..___ ______ ___, I I I I I I I u I I I I I I I I I Comment No. 8 Figs. 2-7, 2-8 The cross-section and cross-section location map are missing. Response No. 8 Figs. 2-7, 2-8 These two figures are attached to this response. Comment No. 9 Sect 4 3 Response No. 9 Section 4.3 A:\OU3RES4.AA This section describes each of the packer tests, however, it does not include an explanation of how the data relate to the conceptual model of the site. It is recommended that NSCC include a description of any patterns that relate geologically different zones with different specific capacities. If any such patterns existed, this information would help NSCC understand preferential pathways for groundwater movement, and if these zones may be used to help remediate the contaminated groundwater. The Packer Tests were conducted to determine locations of (a) fracture zones, (b) layers or depths where groundwater is contaminated and (c) the extent of groundwater contamination in the bedrock aquifer. This assists the Remedial Design. The Specific Capacities are used in the Remedial Design to determine pumping rates from different Extraction Wells, and the extent of drawdowns and Areas of Influence due to pumping at different rates from different Extraction Wells. NSCC respectfully disagrees with the recommendations of NCDEHNR because the requested investigations are unnecessary and do not contribute or assist the Remedial Design. These recommendations will not be included in the RD/RA Field Investigations Summary Report. 15 - - - - - - - - - - -I!!!! 1!1.15 r:aa lilli1i - - - - P-02 ♦ PLANT EAST (ft) C.\.:irojectslcd"pmglouJ..wp\lig 1-7. pr• SCALE (n) 0 100 200 300 ,oo S00 ■ SBA2-2 ♦ NS-14 LEGEND LOCATIONS WI-IERE REFUSAL WAS REACHED lilONITOAlt«i WELL WHERE REFUSAL WAS RE.ACHED r-OEOROCK ELEV.t. HON CONTOUR NA T/ONAL STARCH AND CHEMICAL COMPANY SALISBURY N.C. - - - - - - --- --I!!!! !!!Iii == lilii iiiil -- - ,oo 500 - 400 ·, 0 A ~ • l " P-04 P-01 LEGEND T Water Table ElevebOfl c:""°jectsv;drspmg'ou3--...,:i'l,g 1-8. pre NS-OS NS--17 NS--25 I NS-21 I .. 1000 2000 Oi5tance (feet) Vertical Exeggera!Jon: 4X NS-24 3000 ~ • 8 l ~ " ~ I [ w • z 1l u • ,ooo A' FIGURE 2-8 HYDROGEOLOGIC CROSS SECTION A-A' NATIONAL STARCH AND CHEMICAL COMPANY SALISBURY N.C. B I I I I I I I I I I I I I I I I Comment No. JO Sect. 4.4 Response No. 10 Section 4.4 Comment No. 11 Sect. 5.2 A:\OU3RES4.AA The tables in this section on "Groundwater Quality Results" indicate that significant amounts of contaminants (specifically l ,2-DCA) were detected in the l 60-200' zone in the bedrock wells NS-50, NS-52, and NS-54, which are downgradient of the lagoons. Further characterization of the aquifer and further delineation of the extent of contamination are necessary. Results of Packer Tests, sampling and analysis indicate significant levels of contamination in Extraction Wells NS-50, NS-52, and NS-54. Further drilling, installation of deeper bedrock wells, and sampling and analysis might be necessary to delineate the vertical extent of groundwater contamination in the Lagoon 2 area. NSCC proposes to first operate the bedrock Extraction Wells and the Pump and Treat System for six months to determine whether or not the detected contamination in the lower depths is due to real contamination or due to contaminated groundwater moving down from above. If the groundwater contamination in the lower depths continues after six months of operation, NSCC proposes to install an additional deeper bedrock well in the Lagoon 2 area to determine the vertical extent of groundwater contamination in the Lagoon 2 area. Please see details in Response to USEPA Comment No. 5. In section 5.2, titled "Results of Step-Drawdown Tests", tables 5-11 through 5-20 contain drawdown and distance measurements from pumping and observation wells. According to these-tables, seven of the ten wells influenced at least three observation wells. However, the distance/drawdown plots (Figs. 5.1 through 5.9) only illustrate the two end points used to determine the slope. The slope should be determined from a line that best fits the drawdown data from all affected observation wells. Furthermore, examining the data from all the observation wells may provide NSCC with information about preferential interconnections (e.g., fractures) between wells. 16 D u B I I I I I I I I I I I I I I I Response No, 11 Section 5.2 Comment No. 12 Sect. 8.1, 8.2 Response No, 12 Sections 8.1,8.2 A:\OU3RES4.AA Drawdown data from all Extraction Wells and Observation Wells were used to design the Extraction System and pumping rates. The distance drawdown plots are modified to include the measured drawdowns in the Observation Wells. Chapter 8.0 is titled "Vertical Extent of Groundwater Contamination", and sections 8.1 and 8.2 specifically describe Area 2 and the Lagoon 2 area, respectively. These sections of the document report the facts of the investigation, but contain no description of the extent of groundwater contamination. The report should include up-to-date contaminant plume maps/cross-sections and a discussion of the movement of the plume: lfNSCC is to meet their objective of determining the extent of groundwater contamination, additional characterization of the aquifer and delineation of the contaminant plume are necessary. NSCC could not determine with certainty the extent of vertical groundwater contamination from the data collected during the RD/RA Field Investigations. Available data seems to indicate that the groundwater contamination in depths exceeding 130 feet from the ground surface in Area 2 of the Plant may be due to contaminated groundwater from above that depth migrating down. In the Lagoon 2 area of the Plant groundwater contamination below 160 feet from the ground surface may be due to actual contamination of this groundwater. Available data collected during the RD/RA Field Investigations do not permit updating the Plume Maps/Cross-Sections developed from more extensive Field Investigations conducted during the OU3 Remedial Investigations. Because of these reasons NSCC did not present any conclusions in the RD/RA Field Investigations Summary Report. 17 --- - - - - - - - - - - - --I!!!!!! l!!llm - C 3:: 0 "O 3:: ~ 0 ---------------- FIGURE 5-2 Step Drawdown Test at NS-47 Distance-Drawdown Graph 0 ~--.-----------,--,-.....,.....,....,....,.-,-----,------,------,---,-,--,-,--,-11--t-,------,------,---,------,--.,....,.., --1----·---·--·---___ , __ _,_ __ ·-___ _I_I_ --____ ,l---l----+---1---1--l--~·-----+--! -1-----'I-I : I ! I I --·--1- 1 --·· -----· -· ___ ,_ -- - ---, -----·---------__ ,_ -_ _I __ __I __ _I_ - -... --. -14 ~----~~---'---'---'--'-'-----''----'- . l I 0.1 1 10 100 1000 Distance from Pumped Well (ft.) I ■-58 Min.) - - - - - - - - - - - - ---l!!!!!!!!I I!!!!! !!!!It - FIGURE 5-4 Step Drawdown Test at NS-49 Distance-Drawdown Graph 0 ----------------,--,-.,....,.....,....,..-,------,----,--,--,--.--,--ft,,_...,...,...,........r,--,........,--,---,--,--,-, ~~ ~ .. : i II -10 ---··-·- C 3: 0 -20 - "O 3: rn ~ 0 • ◊ lJ --·-·-··--·--------·-·· ·---· .... I ' ti i i I , I Al -~ ~ u C1j ·---1·· I --. -; -. j ------·---·-.. -· ----·--~ ----------i--..... . i I ' . ·1 I I I -40 '-----' --'----'---'---"--'-' -'-,...._----'---'--'----'-'---'-'--'--'-----'---'---'--'--'-'-'-'-'---....... -'---'---'--'c...;...-'--'-' 0.1 1 10 100 1000 Distance from Pumped Well (ft.) [ ■ 60 Min. ---◊ 120 Min. A 180 Min. o 240 Min. I - - - - - - - - - - - - - - - -l!!!!l!I !!!!!!I l!!!!!I C FIGURE 5-5 Step Drawdown Test at NS-50 Distance-Drawdown Graph 0 ~--,----,-----,-~,-~-----------·----,-----,----,----,--,-,-,-llml!-, -' r-_____ r ------------_________ _1_, ____ ---------·'- i 1--------- ----1----'--■ -50 ◊ ~ -100 ,---·~----··-----------·--------------· ----------··---··-·--·-----··--·---·--·---· --·-----1 -0 ;;: ~ 0 -150 !----,~·---------1----1--0 -----·----·-··-------_(-__ --·· --·--,---·---·-· -- -200 ~-----'--'-'-...;_'-'-'-----'---'-_..:.,_..:.,_-'-_:_:__J__ --'---'--'--'-..l.-:-'-'-'----'---"----'--'--'-'-...:....:....J 0.1 1 10 100 1000 Distance from Pumped Well (ft.) I ■ 60 Min. ◊ 120 Min. 1,,. 180 Min. [J 240 Min. I ------------------------- - - - - - - - - - - - - - - - --l!!!!I !!!!!!I FIGURE 5-6 Step Test at NS-51 Distance-Drawdown Graph 0 ~-----------------------------,--,--,--,._.-,-.,....,., __ ---rn-f,-----,--,--,-...,...., I,: I I ■ <> I <> <> -------------------f----_L __ -20 --------■----------- -40 __ J_ -------------------------------- -60 '------'----'---'---'--'------'---...!...'-L----'---'--------'-'----'---'-'---'----'---'----'---'---'-'--'-..:....C.-------'---'---'---'-------'---'---...!....!..J 0.1 1 10 100 1000 Distance from Pumped Well (ft.) - - - - - - - - - - - - - - --!!!!!I I!!!! 11!1111 ~ ~ C ;: 0 -0 ;: "' ~ 0 FIGURE 5-7 Step Test at NS-52 Distance-Drawdown Graph 0 ~---------,-------,--,---~,-~-----,,----;--,---,-----,-,---,-!"!,----O--ffl---,--,----,------,--,-,--,-, I I ! • ~4 ~ -I I i r I i!. I ! <> !---i --------i------·--·------------~ -------------i·-i-----i- -------------------; I I I i -40 -----------·-· ---~---------_-__ , ~~-_-___ -____ , _____ -_ ~ ~ -~ ~~~~~ -___ -_ ~----~ ---~-~~---~ ~~~~:~~~~~--/----------'-_ = ~[~ -- I _,_, __ ,_ ------------t-l-1-------I --- ___ ---. -----------·--· ----------.. ------+----I--•------f------C-1~-'-1-7-- -20 ---------·------- -60 -80 ------------------------I ◊ -100 --I - I ------------------------------------------•---1-----------------·-1----__ T _________ ------------------ -120 '--------'---'---'---'--'---'--J. .!..I..----'---'--I I I 0.1 10 100 1000 Distance from Pumped Well (ft.) I ■ 60 Min. ◊ 120 Min. I - - - - - - - - - - - - - - - -I!!!!!! l!!!!!I !!!!!II FIGURE 5-8 Step Test at NS-53 Distance-Drawdown Graph ------------------ 0 ,----,----------------~~--------,-----,---,-----,---,----,--,--,-,------,--,~1-:----,----,---,---;-:-:-, I T"I ..... -. ■-· -10 --------·-----------·····----·-.. --· .. -·----------- ◊ ! __ _]__ -. -20 ----; -30 '------'-----'--'---'--'--C..:..'-'------'-----'--'--'--'--'-'--'-'-- 0.1 1 10 Distance from Pumped Well (ft.) ,:-IJ ' 1◊ :6. • <> -[-~ --- □ _I --------1 ·· . ---·-----~ ----- 1 ' 100 I ! I 1000 -- - - - - - - - - - - - - - -II!!!!! !!!!I 1!!111!1 ~ FIGURE 5-9 Step Test at NS-54 Distance-Drawdown Graph 0 ~--.---------~-~ ---,---~~--~-~--r.1,i_..,....., __ --,-____ .,........--,---,-.,-,-...,....,..., i I ! ''-' ~, ~ - ■ I l I ': 1----+---1--l ___ -- ---!------+-----------------_,_I_L__._, -------·• -i---·-◊ I ' -50 __ ,., __ ··---------.. , .. ,_ --1----------------- - _ _I_ -------_, __ ----L----'--------·-----i_ -- :S • i -100 ------_ .. ______ I __ -------- j l:! 0 -150------__ I J --------r---·--------------·--------- i -- . I I , I I -200 '----'----'--"--'-'--'-' --'-'-----'---'---'----'----'-'--'-'--'-----'----'-----'--'-----'-'--'-'----'----'---'----'--'--'---'--'-' 0 .. 1 1 10 100 1000 Distance from Pumped Well (ft.) M I I I I I I I I I I I I I I I I I I A:\OU3RES4.AA If it becomes necessary, NSCC will conduct additional drilling and installation of deeper bedrock wells in both Area 2 and the Lagoon 2 area. However, NSCC plans to conduct these additional drilling and installation of deeper bedrock wells after operating the Groundwater Extraction System for six months to ascertain that the detected groundwater contamination in the lower portion of the bedrock is real and not temporary. 18 I I I I I I I I I I I I I I I I I Responses to NCDEHNR Comments (05/09/97) on the Remedial Design/Remedial Action Conceptual Design Report for the Third Operable Unit (OU3) Comment No. 1 Sect. 3.1 Response No, 1 Section 3.1 A:\OU3RES4.AA National Starch & Chemical Company Cedar Springs Road Plant, North Carolina This section, titled "Design Basis", states that 120,000 gallons of contaminated groundwater will be pumped from the new extraction wells for OU3. NSCC should specify that the proposed extraqion rate is 120,000 gals/day. This portion of the draft design report also states that"[A]t this rate of pumping the groundwater extraction system is expected to have an area of influence covering the contaminated groundwater plume". It is recommended that NSCC amend or omit this sentence for the following reasons: l) in the draft RD/RA report, NSCC demonstrates that the extent of ground-water contamination has not been delineated; and 2) the 10 extraction wells have not pumped simultaneously to evaluate the cumulative effect that the system will have on the aquifer. Consequently, NSCC has not provided information to substantiate this claim about the performance of their ground-water extraction system. The Design extraction rate is indeed 120,000 gals/day. Correction is made to indicate proper unit. NSCC respectfully disagrees with NCDEHNR's recommendation to delete the statement on Areas of Influence covering the two Contaminant Plumes. NSCC's statement for extraction rate is based on computer analysis and simulation of cumulative drawdowns and Areas of Influence in Area 2 of the Plant and the Lagoon 2 area using data collected during the RD/RA Field Investigations. Table 3-2 presents the calculated cumulative drawdowns at the ten Extraction Wells under design pumping rates. Figure 3-2 illustrates the Area of Influence of pumping in Area 2 of the Plant while Figure 3-3 illustrates the Area of Influence of pumping in the Lagoon 2 area under design pumping rates and conditions. Based on the above information NSCC believes that the statement is correct. 19