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HomeMy WebLinkAboutNCD981927502_19961023_Geigy Chemical Corporation_FRBCERLA FS_Remedial Investigation Feasibility Study-OCROctober 23, 1996 MEMORANDUM TO: FROM: RE: File Randy McElveen Environmental Engineer NC Superfund Section Meeting with EPA and Duracell Representatives Phase II RI/FS Work Plan Duracell-Lexington Site NCD 000 648 402 Lexington, Davidson County, North Carolina On 11 October 1996, representatives of the NC Superfund Section participated in meetings with the EPA, EPA oversight personnel, Bechtel Corporation, and Duracell representatives to review and discuss the proposed Phase II Remedial Investigation Work Plan. The State participated through a conference call to EPA Region IV in Atlanta, Georgia. The primary issue to be worked out with the Duracell representatives is the extent of additional groundwater investigation. Specifically the number and location of additional shallow and deep wells to be placed around the Site. The State encouraged additional deep wells to the northeast of the property to evaluate the extent of Volatile Organic Compound contamination in groundwater. cc: Grover Nicholson, NC Superfund Section • Ciba-Geig_y Corporation May JJ, 1996 Ms. Julie Keller US. Environmental Protection Agency Region IV 345 Courtland Street NE Atlanta, GA 30365 Dear Julie: RECE1vPo MAY 14 1996 SlJPmRUIND:SECTION Ciba-Geigy Corporation P.O. Box 18300 Greensboro, NC 27 419-8300 Telephone 910 632-6000 Attached for your review are samples of the letters we plan to send to the neighbors involved in the Rt. 211 Downgradient Study. The first letter is to Lester Davis. The second is a sample of the letter to the well owners who represent the six other minor detection points. We reference the agencies in these seven letters. The third sample letter is to the 17 well owners who had non-detects, and the fourth letter is correspondence we plan to send to the two well owners whose wells were too shallow to sample. Finally, the fifth letter is to Southern States Galvanizing, in which we make a continued offer to sample their well. If you have any edits to propose to these letters, I would appreciate hearing from you by May 16, 1996. Otherwise, we will assume you are satisfied with the correspondence and will proceed accordingly. Thank you for your review. Sincerely, ~~ Harold Moats Project Coordinator Attachments cc: Bernie Hayes, E;P A 'Raiidy-1v[cE1~NG-'DEHNR:;;, ·• May 13, 1996 Mr. and Mrs. Lester Davis P.O. Box 222 Aberdeen, NC 28315 Dear Mr. and Mrs. Davis: • Route 211 Area APDS Committee Correspondence As you may recall, a sampling team from Rust Environment & Infrastructure, on behalf of Ciba-Geigy Corporation and Olin Corporation, collected a groundwater sample from your well on April 10, 1996. The sample was analyzed for a standard list of pesticides. The analysis of your water sample detected trace amounts of a chemical compound, gamma BHC, at 0.047 parts per billion (ppb). This level is within the acceptable drinking water standard of 0.2 ppb established by the North Carolina Department of Environment, Health, and Natural Resources (NC DEHNR). Trace amounts of other chemical compounds, for which there are no state or federal standards, were also detected in the water.sample. These levels are within the acceptable risk range for consumption as determined by the NC DEHNR and the U.S. Environmental Protection Agency. A summary of the laboratory results for your well is attached to this letter. Thank you for your cooperation in this matter. Should you have any questions or concerns, please do not hesitate to contact Mary Ann Gillis with Ciba-Geigy Corporation located in Greensboro, North Carolina at (910) 632-7819, Randy McElveen with the NC DEHNR in Raleigh at (919) 733-2801, ext. 341, or Julie Keller of the Environmental Protection Agency in Atlanta at (404) 347-7791, ext. 2029. Sincerely, Harold Moats Project Coordinator Attachment • • SL SAVANNAH LABORATORIES & ENVIRONMENTAL SERVICES. INC. 2846 Industrial Plaza Drive (32301) • P.O. Box 13056 • Tallahassee, FL 32317-3056 • (904) 878-3994 • Fax (904) 878-9504 LOG NO: T6-11026 Received: 11 APR 96 Reported: 16 APR 96 Ms. Evelyn Rogers RUST Env. & Infrastructure, Inc. 15 Brendan Way Greenville SC 29616 CC: Ms. Diana Baldi Project: RTE 211 Downgradient Receptor Study Area Sampled By: Client REPORT OF RESULTS DATE/ LOG NO SAMPLE DESCRIPTION, LIQUID SAMPLES TIME SAMPLED 11026-3 PRW23 04-10-96/0955 PARAMETER )rganochlorine Pesticides (508) Aldrin, ug/1 alpha-BHC, ug/1 beta-BHC, ug/1 delta-BHC, ug/1 gamrna-BHC, ug/1 alpha-Chlordane, ug/1 gamma-Chlordane, ug/1 4,4' -DDD, ug/1 4,4' -DDE, ug/1 4,4' -DDT, ug/1 Dieldrin, ug/1 Endosulfan I, ug/1 Endosulfan II, ug/1 Endosulfan Sulfate, ug/1 Endrin, ug/1 Endrin Aldehyde, ug/1 Endrin ketone, ug/1 Heptachlor, ug/1 Heptachlor Epoxide, ug/1 Methoxychlor, ug/1 Toxaphene, ug/1 Surrogate Tetrachloro-m-xylene Surrogate -Decachlorobiphenyl Surrogate -Dibutyl Chlorendate Date Extracted Date Analyzed Batch ID 11026-3 <0.0050 0.023 0.018 0.020 0.047 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <1.0 26 %- 118 %- 98 % 04 .11.96 04.12.96 0411B Page 1 1boratories in Savannah, GA • Tallahassee, ·FL • Tampa, FL • Deerfield Beach, FL • Mobile, AL • New Orleans, LA • May 13, 1996 Mr. and Mrs. Lynn Baker 495 Carolina Road Aberdeen, NC 283 I 5 Dear Mr. and Mrs. Baker: • Route 211 Area APDS Committee Correspondence As you may recall, a sampling team from Rust Environment & Infrastructure, on behalf of Ciba-Geigy and Olin Corporation, collected a ground water sample from your well on April 11, 1996. The sample was analyzed for a standard list of pesticides. The analysis of your water sample detected trace amounts of a chemical compound, gamma-BHC, at 0.13 parts per billion (ppb ). This level is within the acceptable drinking water standard of0.2 ppb established by the North Carolina Department of Environment, Health, and Natural Resources. Trace amounts of other chemical compounds, for which there are no state or federal standards, were also detected in the water sample. A summary of the laboratory results for your well is attached to this letter. It is our understanding that your drinking water is currently being supplied by the Town of Aberdeen and that you do not use your groundwater well for drinking water. We would recommend that you continue to use the Town water for all your needs. Thank you for your cooperation in this matter. Should you have any questions or concerns, please do not hesitate to contact Mary Ann Gillis with Ciba-Geigy Corporation located in Greensboro, North Carolina at (910) 632-7819, Randy McElveen with the North Carolina Department of Environment, Health, and Natural Resources in Raleigh at (9 I 9) 733-280 I, ext. 341, or Julie Keller of the Environmental Protection Agency in Atlanta at (404) 347-7791, ext. 2029. Sincerely, Harold Moats Project Coordinator Attachment SL SAVANNAH • LABORATORIES • & ENVIRONMENTAL SERVICES. INC. 2846 Industrial Plaza Drive (32301) • P.O. Box 13056 • Tallahassee, FL.32317-3056 • (904) 878-3994 • Fax (904) 878-9504 LOG NO: T6-11046 Received: ·12 APR 96 Reported: 17 APR 96 Ms. Evelyn Rogers RUST Env. & Infrastructure, Inc. 15 Brendan Way Greenville SC 29616 CC: Ms. Diana Baldi Project: 89550.202/Rt. 211 Downgradient Receptor Area Sampled By: Client LOG NO 11046-2 PARAMETER REPORT OF RESULTS SAMPLE DESCRIPTION, LIQUID SAMPLES PRW50 11046-2 Page 1 DATE/ TIME SAMPLED 04-11-96/1250 ------------------------------------------------------------------------------- Organochlorine Pesticides (508) Aldrin, ug/1 alpha-BHC, ug/1 beta-BHC, ug/1 delta-BHC, ug/1 gamma-BHC, ug/1 alpha-Chlordane, ug/1 gamma-Chlordane, ug/1 4,4' -DDD, ug/1 4,4' -DDE, ug/1 4,4' -DDT, ug/1 Dieldrin, ug/1 Endosulfan I, ug/1 Endosulfan II, ug/1 Endosulfan Sulfate, ug/1 Endrin, ug/1 Endrin Aldehyde, ug/1 Endrin ketone, ug/1 Heptachlor, ug/1 Heptachlor Epoxide, ug/1 Methoxychlor, ug/1 Toxaphene, ug/1 Surrogate Tetrachloro-m-xylene Surrogate -Decachlorobiphenyl Surrogate -Dibutyl Chlorendate Date Extracted Date Analyzed Batch ID <0.0050 0.18 0.16 0.14 0 .13 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <l.O 54 % 119 %- 59 %- 04.12.96 04.15.96 0412E Laboratories in Savannah, GA • Taffahassee, FL • Tampa, FL • Deerfield Beach, FL • Mobile, AL • New Orleans, LA • Route 211 Area APDS Committee Correspondence May 13, 1996 Mr. and Mrs. Cleveland McNeill 265 Lena Circle Aberdeen, NC 28315 Dear Mr. & Mrs. McNeill: • As you may recall, a sampling team from Rust Environment & Infrastructure, on behalf of Ciba-Geigy Corporation and Olin Corporation, collected a ground water sample from your well on April 8, 1996. The sample was analyzed for a standard list of pesticides. The analysis of your water sample detected no pesticides. A summary of the laboratory results for your well water is attached to this letter. Thank you for your cooperation in this matter. Should you have any questions concerning the results of your well sample, please do no hesitate to contact Mary Ann Gillis with Ciba-Geigy Corporation located in Greensboro, North Carolina at (910) (?32-7819. Sincerely, Harold Moats Project Coordinator Attachment • • SL SAVANNAH LABORATORIES & ENVIRONMENTAL SERVICES. INC. 2846 Industrial Plaza Drive (32301) • P.O. Box 13056 • Tallahassee, FL 32317-3056 • (904) 878-3994 • Fax (904) 878-9504 LOG NO: T6-10995 Received: 09 APR 96 Reported: 12 APR 96 Ms. Evelyn Rogers RUST Env. & Infrastructure, Inc. 15 Brendan Way Greenville SC 29616 CC: Ms. Diana Baldi Project: Route 211 Downgradient RJceptor Area Sampled By: Client LOG NO 10995-1 PARAMETER REPORT OF RESULTS SAMPLE DESCRIPTION, LIQUID SAMPLES PRW26 Organochlorine Pesticides {508) Aldrin, ug/1 alpha-BHC, ug/1 beta-BHC, ug/1 delta-BHC, ug/1 gamrna-BHC, ug/1 alpha-Chlordane, ug/1 gamma-Chlordane, ug/1 4,4'-DDD, ug/1 4,4'-DDE, ug/1 4,4'-DDT, ug/1 Dieldrin, ug/1 Endosulfan I, ug/1 Endosulfan II, ug/1 Endosulfan Sulfate, ug/1 Endrin, ug/1 Endrin Aldehyde, ug/1 Endrin ketone, ug/1 Heptachlor, ug/1 Heptachlor Epoxide, ug/1 Methoxychlor, ug/1 Toxaphene, ug/1 Surrogate Tetrachloro-m-xylene Surrogate -Decachlorobiphenyl Surrogate -Dibutyl Chlorendate Date Extracted Date Analyzed Batch ID ? ~ct. ~< izath ~Schneider 10995-1 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <_0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0. 0050 <0.0050 <0.0050 <l. a 47 %- 111 % 101 %- 04 .11.96 04.12.96 0411D Page 1 DATE/ TIME SAMPLED 04-08-96/1040 Laboratories in Savannah, GA • Tallahassee, FL • Tampa, FL • Deerfield Beach, FL • Mobile, AL • New Orleans, LA May 13, 1996 Mr. Elden McNeill 200 Lena Circle Aberdeen, NC 28315 Dear Mr. McNeill: • • Route 211 Area APDS Committee Correspondence As you may recall, a sampling team from Rust Environment & Infrastructure, on behalf of Ciba-Geigy Corporation and Olin Corporation, measured your well on April 8, 1996, to determine whether to collect a sample for analysis. A measurement of your well (3 9 .25 feet) determined its depth to be too shallow to draw from the aquifers of concern in our study area. Therefore, it was not necessary to collect a water sample from your well. Thank you for your cooperation in this matter. Should you have any questions concerning our study, please do not hesitate to contact Mary Ann Gillis with Ciba-Geigy Corporation located in Greensboro, North Carolina at (910) 632-7819. Sincerely, Harold Moats Project Coordinator • Route 211 Area APDS Committee Co"espondence May 13, 1996 Mr. Cary Peterson Southern States Galvanizing Company RR I, Box 60 Aberdeen, NC 28315 RE: Request for Sampling of Southern States Galvanizing Company's Well Dear Mr. Peterson: As you may know, Ciba-Geigy Corporation and Olin Corporation (the "Companies") have been conducting a groundwater study in the area south of Rt. 211 and to the east of Aberdeen. As part of that effort, the Companies' representatives have attempted to meet with you to schedule a sampling of your well. It is our understanding that Southern States Galvanizing has declined to allow the Companies to sample its well. Should Southern States Galvanizing change its position on the sampling of its well, we would appreciate your letting us know in order to add this information to the Companies' database. If you have any questions, or wish to schedule well sampling, please phone Mary Ann Gillis of Ciba-Geigy Corporation in Greensboro, North Carolina at (910) 632-7819. Sincerely, Harold Moats Project Coordinator ' • ·• ~.-" ID CHEMICALS P.O. BOX 248, LOWER RIVER ROAD, CHARLESTON. TN 37310 PHONE: (615) 3:l6-4000 December 2, 1991 Giezelle Bennett Remedial Project Manager Waste Management Division U.S. Environmental Protection Agency, Region IV 345 Courtland Street, N.E. Atlanta, GA 30365 via Federal Express Re: Draft Responses to EPA Comments on the RI/RNFS for the Geigy Chemical Corporation Site, Aberdeen, North Carolina Dear Ms. Bennett: Introduction On behalf of the PRPs, enclosed are draft responses to EPA comments of November 6, 13 and 14, 1991 on the Remedial Investigation/Risk Assessment/Feasibility Study (RI/RNFS) for the Geigy Site. Per our conversation of November 20, 1991, we have responded as completely as possible given the short time frame. Because of the complexity of the subject, responses to several comments could not be completely addressed in the enclosed responses. These key issues require further discussion among the PRPs and technical consultants. Additional information about these key issues will be provided to you at the December 1 oth meeting in the form of a more complete response to EPA comments. In addition, complete responses to several RNFS comments depend on the outcome of the RI. Remedial Investigation The PRPs do not agree with the comments expressed in EPA's RI cover letter of November 6, 1991. There is insufficient evidence to conclude that pesticides in MW-11 D originate at the site. In addition, as discussed in RI response 20, there are sufficient soils data to demonstrate that the Geigy Site is not a source of TCE in groundwater. While we are confident that the data in the RI report support our conclusions, the PRPs are prepared to collect additional field data which will clarify these issues. OLIN CORPORATION • Ms. Giezelle Bennett December 2, 1991 Page 2 Feasibility Study • We believe we have addressed each of the Agency's comments appropriately. We believe incorporation of the attached response will not require a complete rewrite of the FS. Please clarify your comment in your cover letter of November 13, 1991 that "the basic assumptions of the document are incorrect." As noted above, incorporation of these responses will not involve significant changes in the basic assumptions. The FS will be revised per the attached FS responses and the discussions to be held December 10, 1991 .. Key Issues For your convenience, RI/RNFS key issues are listed below. Since the three Geigy documents (RI/RNFS) are scheduled to be discussed during the December 1 0, 1991 meeting at your office, judicious use of meeting time is imperative. Therefore, we suggest that the following list of key issues also serve as the meeting agenda: (1) The source of TCE in groundwater (2) Groundwater flow direction in the southern and eastern vicinity of the Site (3) Lateral extent of contamination in the groundwater (4) EPA and North Carolina groundwater classifications (5) Remediation of former concrete foundation/floor (6) Soil remediation levels (7) Future residential risk assessment scenario (8) Risk assessment exposure assumptions (9) Air emissions and dispersion modeling/monitoring. Responses to comments on the Draft Risk Assessment will be sent to you today from Clement under separate cover. Please call me at 615-336-4381 if you have any questions or comments. Sincerely, r,f,~, for Olin Corporation CIBA-GEIGY Corporation Kaiser Aluminum & Chemical Corporation ' Ms. Giezelle Benne, December 2, 1991 Page 3 CC: Jim Cloonan, Sirrine Dave Cummings, Olin Steve Goldfarb, Ciba-Geigy Howard Grubbs, Womble & Carmichael Elaine Harmon, ERM Keith Harold, Ciba-Geigy Rob Lannan, Robinson & McElwee Don Paulson, Ciba-Geigy Lorraine Pearsall, Clement Lester Rapp, Kaiser Deborah Winthrop, Olin Catherine Winokur, EPA • \. • • RESPONSE TO U.S. EPA COMMENTS TO THE GEIGY CHEMICAL CORPORATION SITE DRAFT RI/FS REPORTS Response to Cover Letter Transmitting RI Comments Dated November 6. 1991 As noted in the Agency's November 6, 1991 cover letter, EPA does not agree with our conclusions that both the pesticides detected in the intermediate aquifer, and the trichloroethene detected in the intermediate and deep aquifers, are due to off-site sources. While we are confident that the data in the RI Report support our conclusions, we propose that additional limited field investigations be conducted in order to reconcile our conflicting positions on these issues. During our December 10, 1991 meeting, we wish to discuss the need to collect an additional round of ground water samples from monitoring wells MW-4D, MW-6D, MW-14D, MW-15D, and PZ-1 for the analysis of trichloroethene. The PRPs propose that analytical and potentiometric data from this and previous sampling efforts would be evaluated with EPA in order to determine if the presence of TCE in the intermediate and deep aquifers is site related. Resampling and analytical efforts would be conducted on an as soon as possible basis. Response to RI Comments Dated November 6. 1991 Comment No. 1 . 2. 3. 4. 5. Response The figures and tables will be incorporated into the report as requested. The error will be corrected. An executive summary will be prepared. There are no surface water bodies on-site. The ditch that traverses the Site collected stormwater and is generally dry (except after storm events). This point will be clarified in the report. There is no knowledge of past enforcement actions; DEM or DNR inspections or violation citings at the site. The NUS investigation was the only sampling conducted. The NUS investigation was preliminary in nature and was not intended to take precedence over the Remedial Investigation. Since the sampling points and data collected during the NUS study cannot be reproduced, the data are not suitable for inclusion in the RI report. Extensive sampling in accordance with the RI/FS work plan was conducted and these results are presented in the Draft RI report. Draft Geigy RI Responses Page 1 December 2, 1991 Comment No. 6. 7. • • Response The soils data presented in the Draft RI Report represent existing site soil concentrations. The data were intentionally presented in this manner to avoid confusion over pre-removal conditions versus current conditions. In order to make the Draft RI Report more complete, the Field Activities Report for Building Demolition and Soil Removal (October 4, 1991) will be included as an Appendix. Pre-removal conditions may be referenced in that report. In early February 1989, the governor of South Carolina issued an executive order which precluded any hazardous waste from the state of North Carolina to be disposed in South Carolina after March 1, 1989. Consequently, the PRPs decided that an accelerated action should be pursued to execute the removal prior to March 1, 1989. This action was a major effort involving several parties. A critical approval involved the State of South Carolina. A standard time allotment of 14 calendar days is required for State approval both for land disposal and incineration. Since the bulk of the soils were intended for land disposal, attention focused on approval for that aspect of the plan. It was expected that the contractor, GSX, could store the containerized soils intended for incineration at the ThermalKem facility in Rock Hill, SC. However, ThermalKem had a substantial backlog of materials for incineration and storage periods would be significant. Incineration of the soils prior to the South Carolina disposal ban deadline was, therefore, impossible. The only solution was to accumulate and store several containers at the site until appropriate approvals could be obtained. EPA representatives expressed their extreme concern about any storage of excavated materials in containers on-site. EPA would agree to allow the PRPs to store these containers on-site for a matter of days, but any term beyond two to three days would be totally unacceptable. The PRPs contacted other incinerators and found that on-site storage for four to eight weeks would also be required due to their backlog. On February 23, 1989, the PRPs submitted a letter to EPA which stated that all excavated soils would be mixed for land disposal at GSX's Pinewood, SC facility. EPA representatives expressed a further concern regarding the regulatory controls on land disposal of the wastes in question. After several conference calls with the EPA project manager and EPA council, it was finally agreed that there were no regulatory restraints or concentration limitations and the initial soil removal could proceed. However, the delays resulted in completion of only a portion of the planned removal prior to the March 1, 1989 disposal ban. Once legal issues with respect to the ban of North Carolina wastes were resolved, the remaining wastes were removed. Draft Geigy RI Responses Page 2 December 2, 1991 Comment No. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. • • Response The AOC limits of 500 mg/kg toxaphene and 1 00 ppm gamma-BHC will be included in the report. In some cases the areas excavated in the initial removal were widened and the maps show some overlap. The maps do show the approximate limits of excavations. The maps will be refined, as appropriate, to more clearly indicate the excavation limits. It is felt that the word "document" is more appropriate since support seems to imply a pre-_conceived conclusion about the HRS evaluation. The section will be updated to include a discussion about demography and land use within a one-mile radius of the site. The change will be made. The 1990 census data will be included. The change will be made. A discussion of the residential areas near the site will be included. The PRPs acknowledge that th_e low elevation of the water table in monitoring well MW-6S, along with the thinning of the uppermost clay aquitard, could be interpreted to suggest that ground water is flowing from the uppermost aquifer to the intermediate aquifer at this location. As recognized in the Agency's comment, however, analy1ical ·data from monitor wells MW-6S and MW-6D demonstrate that leakage of contaminants has not occurred at this location. The PRPs therefore believe that a hydraulic connection between the shallow and intermediate aquifers at this location is highly unlikely and that the water table depression at well MW-6S can be more properly explained by the ground water flow map presented in Figure 3-5 of the RI report. A discussion of the quality assurance sample results as presented in Appendix 3-D will be included in this section. At this point in time, the owners have not been provided with the results of the ground water analyses. The data can be made available to the owners. The discrepancies will be corrected. Rounding according to the criteria presented in the CLP Statement of Work was utilized resulting in a discrepancy between the results indicated for MW-4S. The figures and the text in the revised report will use consistent language. The result indicated on the Figure for MW-2S is a typographical error and will be corrected. Draft Geigy RI Responses Page 3 December 2, 1991 Comment No. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. • • Response Remedial investigations conducted at the Geigy Chemical Corporation Site have produced a large body of data on site environmental and hydraulic conditions. Collectively, this information demonstrates that trichloroethene (TCE) is not present above detection levels in site surface soils, subsurface soils, ditch sediments, or ground water in the uppermost aquifer. Analytical and potentiometric data also demonstrate that TCE is present in the intermediate aquifer at locations hydraulically upgradient of the site. Given the above, the PRPs disagree with the Agency's conclusion that the presence of TCE in the intermediate aquifer is due to spillage from railroad cars or, as stated in Ms. Giezelle Bennett's November 6, 1991 letter to Ms. Lorraine Miller, is site related. Because TCE was detected in groundwater collected from well PZ-1 at an estimated value of 8 ug/I, reference to this information was omitted from the Draft RI Report. The estimated TCE concentration for this well will be noted in the revised RI report. The figures will be revised as appropriate. The March 1990 Statement of Work refers to the Contract Laboratory Program (CLP) Statement of Work which became effective in July 1991. The change will be made. These sample locations were removed during 1991 removal action. The figure represents existing site conditions. Pre-removal conditions and results will be provided in an Appendix to the report. The figure will be revised to include soil concentrations greater than 1 0 mg/kg. SS-83 will be included on the revised map. SS-103 is located in close proximity to highway. The clarification will be made. Rounding according to the criteria presented in the CLP Statement of Work was utilized. The figures and the text in the revised report will use consistent language. The PRPs concur that the lateral extent of contamination to the south and east of the site appears to have not been completely defined. The referenced paragraph will be reworded to eliminate confusion regarding the vertical extent of pesticide contamination. Draft Geigy RI Responses Page 4 December 2, 1991 ' " Comment No. 30. 31. 32. 33, 34. • • Response Available hydraulic and geologic data does not support a relationship to the site. The PRPs therefore disagree with removal of the referenced paragraph and wish to discuss this issue further during our December 1 0, 1991 meeting. See response to comment number 20, above. No clean up goals are stated orimplied in the RI. Phase 3 soil sampling was conducted on the basis of Phase 2 soil sampling results. Phase 2 sampling grid locations exhibiting total BHC, DDT and toxaphene concentrations between 1 0 ppm and 100 ppm were resampled at two-foot and five-foot depth intervals. Likewise, sample grid locations with concentrations greater than 100 ppm were sampled at two, five and ten- foot depth intervals. The reference to pesticide concentrations of 1 00 ppm in the second paragraph of Section 6.2 on page 6-5 is in context with the EPA approved Phase 3 soil sampling rationale discussed above and in Section 4.3.3. The second paragraph of Section 6.2 will be revised to more clearly summarize the extent of pesticide concentration in site soils and to alleviate any misunderstanding. The last sentence in Section 7.2.3.1 on page 7-5 will be modified to read, "The maximum delta-and gamma-BHC concentrations in groundwater are 29 µg/I and 30 µg/I, respectively, in monitor well MW-6S while the maximum beta-BHC concentration in groundwater is 25 µg/I in monitor well MW-10S." Conclusion #4: Conclusion #6: Conclusion #7: This conclusion is in accordance with professional opinions expressed by Mr. Ron Coble, USGS, and Mr. Benford Graham, Graham and Currie Well Drilling, regarding the suitability of the uppermost aquifer as a water source. Therefore, this statement is applicable to the site. This statement will be reworded to emphasize that it applies to the area immediately underlying the Site property only. The PRPs see no relation between this conclusion and the Agency's comments. Therefore, this statement is applicable to the site. Draft Geigy RI Responses Page 5 December 2, 1991 • · Conclusion #12: Conclusion #13: Conclusion #15: Conclusion #16: Conclusion #17: Conclusion #18: Conclusion #21: Conclusion #22: Conclusion #23: Conclusion #24: Draft Geigy RI Responses • This statement will be reworded to emphasize that ground water flow patterns in the shallow aquifer preclude the possibility of pesticide contamination migrating to the municipal well via the shallow aquifer. The PRPs see no relation between this conclusion and the Agency's comments. Therefore, this statement is applicable to the site. This statement will be reworded to emphasize that it applies to the area immediately underlying the Site property only. This statement will be revised as appropriate to reflect the findings of the proposed additional investigations to be conducted as a separate phase of the RI. This statement will be revised as appropriate to reflect the findings of the proposed additional investigations to be conducted as a separate phase of the RI. See response to comment number 20, above. See response to comment number 32. This statement is merely reiterating findings of the RI from which a general conclusion is made. The PRPs are in agreement that this general conclusion reflects site conditions. See. response to comment number 32. This statement accurately reiterates findings of the RI. The PRPs have no records indicating that copper, lead, or zinc were used in formulating the pesticides handled at the Site. Moreover, these metals are within the range of background levels at the site. Therefore, this statement is applicable to the site. This statement accurately reiterates findings of the RI. Therefore, this statement is applicable to the site. Page 6 December 2, 1991 • Response to Department of Interior Comments The RI report will be modified to include the Federally listed endangered species included in the Department's comments. While the Department is correct that Section 2.7 is very general, it should be noted that the areal extent of the Site is very small (approximately 1 to 2 acres), contains relatively few trees, borders an active railway, a high traffic road (Highway 211), and presents very limited habitats for plants or animals. Accordingly, we believe that expansion of this section would mislead the reader into believing that the site represents a significant habitat for wildlife. Draft Geigy RI Responses Page 7 December 2, 1991 • • Responses to November.13 & 14. 1991 EPA comments about the Geigy FS: General FS Comments (Dated November 13, 1991) 1. Soil Cleanup Remedial Alternatives Soil cleanup levels are site-specific. Therefore, it is not appropriate ·to compare soil remediation levels at the Geigy Site to other sites as stated in the EPA comment. Every site should be evaluated separately, as was done in the Geigy Risk Assessment (RA) and FS. This concept of site-specific remediation levels is obviously supported by the EPA. Furthermore, it is inappropriate to use health-based, direct contact risk assumptions to calculate subsurface remediation levels. In summary, both the suriace and subsurface soil conditions at the Geigy Site were considered in the Geigy RA and FS. Based on the reasons presented in these site-specific documents, additional soil remediation at the Geigy Site is not necessary. 2. Concentrations of BHC isomers and toxaphene beneath the concrete flooring are approximately the same level as soils in the remainder of the Site. For example, average concentrations of total BHC isomers and toxaphene in soil at former areas of active use . are 0.365 and 9.662 mg/kg, respectively. Under the concrete floor, average concentrations of total BHC isomers and toxaphene are 1.733 and 1.525 mg/kg, respectively. If necessary, the concrete flooring would be removed to provide access to those soils. Otherwise, the concrete· has been steam cleaned and would only be removed for aesthetic purposes. 3. Contamination of the uppermost aquifer has been attributed to the Site and corresponding remedial alternatives were presented in the draft FS. The source of groundwater contamination in the second uppermost aquifer has not been determined at this time and is a subject for discussion during review of the RI comments. To require remediation of the second uppermost aquifer at this time, without sufficient characterization and outside the purview of public comment, is inappropriate. Presumed contamination of the third uppermost aquifer is based on one qualified (J-flagged) value below the quantitation limits and should first be evaluated through resampling. Specific FS Comments 1 . The ranking was given as documentation of the site's determination as a CERCLA site and to note the site's relative stature within the NPL. The date was given to mark the ranking at a point in time, with the realization that the ranking may change. However, the statement will be deleted if desired. 2. It is important to state the goals of the FS clearly and early in the document. Please explain the rationale for deletion of the sentence. Draft Geigy FS Responses Page 1 December 2, 1991 • • 3. Section 2 (Summary of Remedial Investigation) will be revised to reflect changes with the RI. 4. Section 3 (Summary of Risk Assessment) will be revised to reflect changes in the RA. 5. As stated, the uppermost aquifer is correctly classified as Class Ill since it would not consistently provide an adequate quantity of drinking water. The second uppermost aquifer is IIA (currently used} according to EPA guidance (Guidance on Remedial Actions for Contaminated Groundwater at Superfund Sites, EPN540/G-88/003, December 1988). It is not correct to classify the second uppermost aquifer as Class I, as suggested by the EPA, since it does not meet the definition of a Class I aquifer, as defined below: "Special ground water (Class I) is (1) highly vulnerable to contamination because of the hydrological characteristics of the areas in which it occurs, and (2) characterized by either of the following factors: • • The ground water is irreplaceable; no reasonable alternative source of drinking water is available to substantial populations. The ground water is ecologically vital; the aquifer provides the base flow for a particularly sensitive ecological system that, if polluted, would destroy a unique habitat." (EPA, December 1988) The second uppermost aquifer is neither highly vulnerable to contamination from the Site nor are either of the other characteristics outlined above applicable. That is, the third uppermost aquifer could be used as a potential drinking water source (first bullet) and the second uppermost aquifer is not ecologically vital (second bullet). Therefore, the second uppermost aquifer is not Class I but is Class IIA. 6. The text will be revised as requested. 7. The text will be revised as requested. 8. The second sentence of the first paragraph in Section 2.1.1 on page 2-1 will be modified to read "The property boundaries of the vacant Site, bounded by Highway 211 and the Aberdeen and Rockfish Railroad, comprise approximately one acre. 9. The second sentence of the third paragraph in Section 2.4.1 on page 2-9 will be modified to read: "Concentrated surface materials were visually identified in each area, excavated, and packed in six 30 gallon fiber pack containers (approximately one ton of soil total)." Additionally, the first sentence of Section 2.4.3 on page 2-1 0 will be modified to read: "Approximately 3071 tons of. contaminated soil and 460 tons of debris have been removed from the Site and properly disposed." Draft Geigy FS Responses Page 2 December 2, 1991 • • \ I 10. The North Carolina groundwater classification system will be described in the revised FS. 11 . The following will be added to the legend of Figure 5-2: SURFICIAL AQUIFER CONTOUR (DASHED WHERE INFERRED) 12. The text will be revised as requested. 13. The text will be revised as requested. 14. EPA guidance specifies the use of a five percent interest rate (Guidance for Conducting Remedial Investigations and Feasibility Studies Under CERCLA, Interim Final, EPA/540/G- 89/004, October 1988, p. 6-12). 15. Preliminary discussions with the North Carolina Department of Transportation -Division of Highways Records Department (Mr. Ted McDuffie; November 14, 1991) indicate that buried utilities including water, sewer and/or television cable may be located in the Highway 211 right-of-way. A utility location check would be required to locate and identify buried utilities. Additionally, three wooden utility poles are within the confines of the proposed slurry wall and cap. It would not be acceptable for any utilities to be located within the confines of the proposed cap and slurry wall. as their presence would breech the containment provided by the cap and their maintenance would require excavation of the cap. Consequently, these utilities would be rerouted if Alternative 2 were selected. Rerouting is considered extensive as the utilities would be rerouted either north of Highway 211 , south of the slurry wall and cap, or above the slurry wall and cap. The proposed relocation of the Aberdeen and Rockfish Railroad indicated in Figure 5.3 is conceptual and is provided for the purpose of illustrating the spatial relationship of the proposed slurry wall and cap, and the Aberdeen and Rockfish railroad tracks. The porous railroad bed would form a preferential conduit for infiltration and defeat the purpose of the cap, which is to prevent excessive water accumulation within the slurry wall. To maintain the integrity' of the cap, the railroad track must be relocated, presumably to the south. The exact location of the relocated section of track can only be determined after appropriate railroad engineering studies and design are completed. 16. Retained alternatives for the discharge of treated groundwater are discharge to the POTW and an on-site infiltration gallery. The cost of remedial alternatives involving the discharge of treated groundwater were conservatively estimated using the POTW discharge option, which has both higher construction and operating costs than discharge to an infiltration gallery. Groundwater treatment alternatives that potentially involve disposal of treated groundwater will be revised to include the cost of both discharge options. Preliminary and detailed cost estimates for remedial alternatives are presented in Appendices E and F, respectively, and are in accordance with EPA guidance. Draft Geigy FS Responses Page 3 December 2, 1991 • • 17. EPA guidance specifies the use of a five percent interest rate (Guidance for Conducting Remedial Investigations and Feasibility Studies Under CERCLA, Interim Final, EPN540/G- 89/004, October 1988 p. 6-12) and an inflation rate of zero percent (Remedial Action Costing Procedures Manual, OSWER Dir. 9355.0-10, September 1985, p 3-21 ). 18.. The second sentence of the first paragraph in Section 7.2.1 on page 7-5 will be modified to read "Approximately 3071 tons of contaminated soil have been disposed of or treated at RCRA TSO facilities". 19. Deed restrictions will be included in the discussion of alternatives. Institutional controls would be implemented until the remedial goals were achieved. 20. Alternatives 2 and 3 would control the flow of pesticides at MW-1 OS. Remediation would attempt to contain or remediate groundwater to the remediation goals listed in Table 4.2 (e.g., MCLs). 21. The 180-foot source area used in the VIP modeling (Appendix C, Table C.2) corresponds to area of active operations at the facility. This approach minimizes the area for infiltration and is therefore conservative in the determination of potential pesticide concentrations in groundwater. The justification will be provided in the revised FS. 22. This comment will be addressed in the RA and summarized in Section 3 of the FS. Additional Draft FS Comments (Dated November 14, 1991) • Page 4-3 As discussed in Specific Response No. 5 (above), the uppermost aquifer is correctly identified as a Class Ill aquifer. Because of the low potential yield of the uppermost aquifer, it is not used by local well drillers in the vicinity of the Site (personal communication with Benford Graham of Graham and Currie Well Drilling Company, West End, North Carolina, September 1991 ). In addition, Mr. Ron Coble (USGS, Raleigh, November 21, 1991) states that the uppermost aquifer may not be a major or significant source of water since more productive aquifers exist (i.e., second and third uppermost aquifers). Therefore, water supply wells are likely to be drilled into the lower units. Furthermore, Mr. Ron Coble (personal communication, November 1991) stated that the nearest homeowner wells in the uppermost aquifer are one to two miles north of the Site. The aquifer characteristics that distance from the Site are apparently more conducive to homeowner wells than near the Site. In summary, the uppermost aquifer is Class Ill while the second uppermost aquifer is Class IIA. Despite the unproductive nature of the uppermost aquifer, remedial alternatives were presented in the FS that would attain groundwater levels that were protective of other aquifers and off-site groundwater (e.g., MCLs). Draft Geigy FS Responses Page 4 December 2, 1991 • • • Section 4.2.1 Current evidence indicates that there is no hydraulic communication between the uppermost and second uppermost aquifers at the Site. However, additional borings would be required to confirm this. • Section 5.3.1 The reference will be changed as requested. The Phase IV wells (MW-7S through 13S, MW-11 D, MW-14D and MW-15D) were installed in August 1991 and seasonal water level measurements are not available at this time. • VIP Model As discussed in the Geigy FS, the vadose zone interactive processes (VIP) model is the most applicable model available for predicting the fate of pesticides in the vadose zone. The VIP model was developed from the RITZ model by the Civil and Environmental Engineering Department of Utah State University (Logan, Utah) and EPA's Kerr Environmental Laboratory (Ada, Oklahoma). The VIP model and assumptions used for the Geigy Site are described in Appendix C of the FS. In summary, the VIP model: • was developed with input from the EPA • is an enhancement of the RITZ model • based on field data, has accurately predicted the fate of PNAs in the vadose zone • has been accepted by EPA Region IV for the Macon/Dockery Site, 25 miles from the Geigy Site • is applicable for modeling the fate of pesticides in vadose zone soil • uses site-specific input parameters to more accurately predict the fate of contaminants • was diligently and appropriately applied at the Geigy Site at considerable expense • is applicable for use at the Geigy Site. Draft Geigy FS Responses Page 5 December 2, 1991 • • North Carolina DEHNR Comments North Carolina Groundwater Quality Standards (NCGQS) were considered in the FS (e.g., Table 4.2}. The only NCGQS was 0.0265 ug/1 for gamma-BHC. However, the CERCLA contract required quantitation limit is 0.05 ug/1. Therefore, according to the NCGQS, the detection limit would be the allowable groundwater limit. However, the NCGQS states that "The goal of actions taken to restore groundwater quality shall be restoration to the level of the standards, or as close thereto as is economically and technologically feasible." Remediation goals were therefore set at the more reasonable MCL for gamma-BHC of 0.2 ug/1 (Table 4.2). The comment about lead, copper, and zinc was appropriate for the scoping phase of the RI Work Plan but is no longer appropriate since site-specific data were collected during the RI. The RI data do not indicate any significantly elevated levels of these metals at the Site and metals were not used for facility blending operations. Metals were determined to be at background levels during the RI and thus no further evaluation is necessary. Draft Geigy FS Responses Page 6 December 2, 1991 • • State of North Carolina Department of Environment, Health, and Natural Resources Division of Solid Waste Management P.O. Box 27687 · Raleigh, North Carolina 27611-7687 James G. Martin, Governor William W. Cobey, Jr., Secretary MEMORANDUM TO: FROM: RE: 31 October 1991 Perry Nelson, Chief Groundwater Section Division of Environmental Management Lee Crosby. Chief p C/ Superfund Sectionf, : Draft Remedial Investigation and Feasibility Study Geigy Chemical Corporation N Pl Site. NCD981927502 William L. Meyer Director EPA is in the process of completing a Remedial Investigation (RI) and Feasibility Study (FS) for the Geigy Chemical Corporation Superfund Site, a National Priority List site. Attached is one copy of the Draft RI and FS Reports for the subject site. It is requested that these documents be forwarded to the appropriate sections of DEM and comments be submitted to the North Carolina Superfund Section. The North Carolina Superfund Section will be reviewing these documents and submitting comments to EPA Region IV in the near future. It is our desire to include the comments and views of the Division of Environmental Management. If you or your staff have any questions, please call Jack Butler or me at (919) 733- 2801. LC/JB/dk/4 Attachment M Equal Opportunity Affinnatlve Acdon Employer • 3 May 1990 'IO: File FRCT-1: Jack Butler SUBJECT: Geigy C11emical, NCD981927502 Fact Sheet • A Superfurrl Renroial Iiwestigation,IFeasibility Study (RI/FS) Fact Sheet was received by FAX frcan Kay Crane on this date. 'Ihis d=ument was reviewed and the following two editorial camments were transferred to Kay Crane by telephone. 1. 'lhe sentence in lines 5, 6, 7 of the right column on page 2 should be changed to read "'lhe Sandhills Aquifer is potentially threatened due to the high penneability of the unsaturated zone." 2. '!he sentence in lines 29 and 30 of the right column on page 3; "An evaluation of the no-action is necessary" should be deleted and the sentence that follows this sentence should be modified to read "An evaluation of the no-action alternative is required and will assess the risk ..• " JB/ds/geigy.chmj3 ,·• ,