Loading...
HomeMy WebLinkAboutNCD986175644_20040420_Davis Park Road TCE Site_FRBCERCLA LTAR_LTAR Feb 2004 Semiannual Sampling Event Report-OCRI I I I I I I I I I I I I I I I I I I Document Control No. RFW138-2A-APIM Revision 0 {R) rsc [: ~ ... :. r~ nl LONG TERM RESPONSE AC ~» MAY 2 5 ZJ04 ;! ~1 FEBRUARY 2004 SEMIANN AU'L... __ ._.,. , SAMPLING EVENT REPO m.lPERFUi~D1aJ,u,~ DA VIS PARK ROAD TCE SITE GASTONIA, NORTH CAROLINA Work Assignment No. 138-RALR-04PN APRIL 2004 REGION 5 U.S. EPA CONTRACT NO. 68-W7-0026 Weston Solutions, Inc. Suite 100 5430 Metric Place Norcross, Georgia 30092 WESTON W.O. No. 20064.138.100.0930 I I I I I I I I I I I I I I I I I I LONG TERM RESPONSE ACTION FEBRUARY 2004 SEMIANNUAL SAMPLING EVENT REPORT Prepared By: Approved By: . Approved by: Approved by: REVISION0 DA VIS PARK ROAD TCE SITE GASTONIA, NORTH CAROLINA U.S. EPA Contract No. 68-W?-0026 Work Assignment No. 138-RALR-04PN Document Control No. RFW138-2A-APIM April 2004 ;! ~~ /•' ?Un! .. u,,,..,,, irKris Spik~ ~ Project Geologist Date: _ _,_r+/4.L·1=·~f-'0,_,__f __ _ Teresa Offner, P. WESTON Wo Assignment Manager James . Burton, P.E. WESTON Program Man Jennifer Wendel U.S. EPA Remedial Project Manager Date: r,ftufiY Date: -------- WESTON W.O. No. 20064.138.100.0930 K:\20064\138\Secood Semiamual\Feb04Semlanoua1Apt.doc RFW138-2A-APIM I I I I I I I .. , I I I I I I D D u m I I This document was prepared by Weston Solutions, Inc., expressly tor EPA. It shall not be disclosed, in whole or in part, without the express written pennission of EPA. Section 2 3 February 2004 Semiannual Sampling Event Report Davis Park Road TCE Site Section: Table of Contents Revision: O Date: April 2004 TABLE OF CONTENTS Title INTRODUCTION .............................................................................................. 1-1 I. I 1.2 1.3 1.4 Purpose ..................................................................................................... 1-I Background .............................................................................................. 1-I Groundwater Contaminant Description ................................................... 1-3 1.3.1 Contaminant Source Area .................................................................. 1-6 1.3.2 Groundwater Plume Concentration and Extent. ................................. 1-8 Site Geology and hydrogeology ............................................................... 1-9 LONG TERM RESPONSE ACTION .............................................................. 2-1 2.1 Quarterly and Semiannual Groundwater Monitoring .............................. 2-2 2.2 First year Quarterly LTRA Sampling Events (2002/2003) ...................... 2-5 2.3 Semiannual L TRA Sampling Event (August 2003) ................................. 2-7 FEBRUARY 2004 LTRA SUMMARY ............................................................. 3-1 3.1 Groundwater Sampling ............................................................................ 3-I 3.2 3.3 3.4 3.1.1 Monitor Weli Sampling Procedures ................................................... 3-1 3. l.2 Community and Private Well Sampling Procedures ......................... .3-8 3.1.3 Field Quality Assurance/Quality Control Samples ............................ 3-9 Groundwater Elevation .......................................................................... 3-12 Groundwater Analytical Results ............................................................ 3-12 3.3.1 Groundwater Samples ...................................................................... 3-12 Passive Diffusion Bag Samplers ............................................................ 3-23 3.4. l Methodology .................................................................................... 3-24 3.4.2 Comparison with Low-Flow Samples .............................................. 3-25 K:\20064\ 1 381S econd Semiannual\F eb04 SemiannualRpl. doc RFW138·2A·APIM I I I I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shalt not be disclosed, in whole or in part, 'Mthout the express lNritten permission of EPA. Section 4 February 2004 Semiannual Sampling Event Resx:>rt Davis Park Road TCE Site Section: Table of Contents Revision: O Date: April 2004 TABLE OF CONTENTS (Continued) Title Page CONCLUSIONS AND RECOMMENDATIONS ........................................... 4-1 4.1 4.2 4.3 LTRA Results Summary ......................................................................... .4-I Conclusions ............................................................................................. .4-7 Recommendations ................................................................................. .4-l I K:\20064\138\Second Semiannual\Feb04SemiarmuaIRpl.doc II RFW138·2A·APIM I I I I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. lt shall not be disclosed, in whole or in part, without the express written permission of EPA. :Figure Figure 1-1 Figure 1-2 Figure 1-3 Figure 1-4 Figure 1-5 Figure 2-1 Figure 3-1 Figure 3-2 Figure 3-3 Figure 4-1 Figure 4-2 Figure 4-3 Figure 4-4 Figure 4-5 Figure 4-6 Figure 4-7 February 2004 Semiannual Sampling Event Report Davis Park Road TCE Site Section: Table of Contents Revision: O Date: April 2004 TABLE OF CONTENTS (Continued) LIST OF FIGURES Title Site Map ................................................................................................................ 1-2 Residences Connected to City Water, September 2000 ....................................... I -4 Residences Supplied with Carbon Filtration Units, August 2000 ........................ 1-5 Street Address Location Map ............................................................................... 1-7 Water Supply Sources Following RA ................................................................ 1-10 LTRA Monitor Well Sampling Network .............................................................. 2,3 Potentiometric Contour Map, Bedrock Aquifer Febmary 2004 ........................ .3-I 3 _ TCE Concentrations in Groundwater Fcbmary 2004 ......................................... 3-21 PCE Concentrations in Groundwater February 2004 ......................................... 3-22 Trichloroethene Concentration vs. Time, 2419 Davis Park Road, MW-5 ........... 4-2 Trichloroethene Concentration vs. Time, 2403 Davis Park Road, MW-14 .· ....... .4-3 Trichloroethene and Tetrachloroethene Concentration vs. Time, 2719 Davis Park Road, MW-12 ............................................................................................... 4-4 Trichloroethene and Tetrachloroethene Concentration vs. Time, 2232 Tate Street, MW-15 ..................................................................................................... .4-6 Trichloroethene and Tetrachloroethene Concentration vs. Time, 2639 Springbrook Street, MW-9 ................................................................................... 4-8 Trichloroethene and Tetrachloroethene Concentration vs. Time, 2816 Davis Park Road, MW-17 .............................................................................................. .4-9 Trichloroethene and Tetrachloroethene Concentration vs. Time, 2800 Davis Park Road, MW-18 ............................................................................................ .4-l0 K:\200641138\Second Semiannual\Feb04 Semiannual Apt.doc Ill RFW138·2A·APIM I I I I I I I I I I I I ,0 6 I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. Table 1-1 Table 2-1 Table 3-1 Table 3-2 Table 3-3 Table 3-4 Table 3-5 February 2004 Semiannual Sampling Event Report Davis Park Road TCE Site Section: Table of Contents Revision: O Date: April 2004 TABLE OF CONTENTS (Continued) LIST OF TABLES Title Residential Well Historical Analytical Results .................................................. 1-l I LTRA Monitor Well Sampling Network .............................................................. 2-4 Field Parameter Measurement Summary -April, September, December 2002,March , August 2003, and February 2004 ................................................... 3-2 Passive Diffusion Bag Sampler Placement .......................................................... 3-9 February 2004 Semiannual LTRA QA/QC Laboratory Analytical Results Summary, ............................................................................................................ 3-l I LTRA Laboratory Analytical Results Summary, April, September, December 2002, March, August 2003, and February 2004 ................................................ .3-l 5 Laboratory Analytical Results Summary, Low Flow Purging vs. Passive Diffusion Bag Samplers ...................................................................................... 3-26 LIST OF APPENDICES APPENDIX A -Certificate of Analysis, Deionized Water APPENDIX B -Laboratory Analytical Reports K :\200641 I 3B\Second Semiannual\F eb04 ScmiannualRpl. doc IV RFW138-2A-APIM ... _. ,J,..._. ~. -·:· ·• :;., .... ' ·.,·,;, ·, · .. .... ·----1 __ ,•':; _,~•-.,_-~•\:: ... _..,,, .. ,: .,•., . ' •• 1 _, ., ... ,;, -.'. ,·'..,,_ , ,_J. '·-t·· ·,: C ,. . ) '' , ·1.~·.··.: :~ },. \. ::.· .-..... \\ ·. :" :-~ · ..... ;· ~··\ •.• -~ ! • , .•. '•.-' ··;:• .-, "I ,,, '' ... ,,:_ . ·-,.- . ..,_ .. ,. . _,. .. ,. . , ', .~'.-:: i.···\, '' '' .. • '\:' 11 tr! l[l 1n lfl I I: 1;1 I I l:1 I: I 1:i 11 I I\ 1;.J ) l'.1 tJ 1J 11 This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. I.I PURPOSE SECTION 1 INTRODUCTION February 2004 Semiannual Sampling Event Report Davis Park Road TCE Site Section: 1 Revision: 0 Date: April 2004 Weston Solutions, Inc., (WESTON@) has been tasked by the U.S. Environmental Protection Agency (EPA) Region 4 to perform the Long Term Response Action (LTRA) 31 the Davis Park Road Trichloroethcne (TCE) Site in Gastonia, North Carolina. The work is conducted under the Region 5 Remedial Action Contract (RAC) Program and implemented as a contract crossover to Region 4, Contract Number 68-W7-0026, Work Assignment Number 138-RALR-04PN. The current LTRA includes monitoring the bedrock aquifer contaminant plume by sampling a network of bedrock wells for volatile organic compounds (VOCs) on a quarterly basis for one year, semiannually for two years, and annually thereafter for 27 years, pending review of analytical results, to ensure the plume is in fact naturally attenuating. 1.2 BACKGROUND The Davis Park Road TCE Site is located within the Gastonia Extra Territorial Jurisdiction area along Davis Park Road, south of Hudson Boulevard and north of Blackwood Creek in the southwestern portion of Gastonia, Gaston County, North Cmolina. The site consists of an area of reportedly contaminated soil behind a building that is located at 2307 Davis Park Road (Davis Park Auto Repair), and a plume of contaminated groundw.ater that emanates from this property and extends south along Davis Park Road to Blackwood Creek. The site.also includes the Cedar Oak Park subdivision located on the east side of Davis Park Road within the confines of Cedar Oak Circle as well as areas along the western side of Davis Park Road, Figure 1-1 presents a site map for the Davis Park Road TCE Site. K:\20064\ 138\Second Semiann ual\F eb04Semiannual Rpt. doc I -l RFW138-2A-APIM ~ z -L_ [l --- - ----~ 0 G D ~ FIGURE 1.1° □ D ! SITE~ i DAVIS PARK ROAD TCE SITE - --- GAST~tA CITY uuns G ElEJ EJ RICHLAND AVENUE ---' D -:.:....:.J -~ Approximate Scale In Feet ~ GASTONIA, NORTH CAROLINA O GOO " 1200 .....__ ______ ----:--_____________________ _J - 11 .~, 1:1 1:·1 1-1 •• 1·1 ILJ 1:1 1: I 1:1 ,·1 11 1:J 1:1 ,_1 1:1 11 1J 1!J This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. February 2004 Semiannual Sampling Event Report Davis Park Road TCE Site Section: 1 Revision: O Date: April 2004 The plume of contaminated groundwater underlies residential areas along the plume's entire horizontal extent. The contaminant levels and aerial extent are further described in Sec1ion 1.3.2. Al lhe lime of lhe discovery of conlaminants in the groundwater (March 1990), a majority of lhe residences throughoul the sile were supplied water by residential water supply wells. As a result of the continued migration of the plume, groundwater supplying many of lhese residential waler wells became contaminated with the chlorinated hydrocarbons found in the plume. Since that time, several neighborhoods within the site have been connected to the Gastonia public water supply lo reduce lhe polential health threat from the contaminants. In 1996, many of lhe houses within the Hedgewood Circle neighborhood, which borders the northern edge of the site, were connected to the public water supply. In late 1997 and early 1998, after petitioning the city for water services, all of the homes in the Cedar Oak Circle subdivision, which dominates the eastern side of the site, were connected to the public water supply. Approximately 130 homes within the site were receiving water from residential water supply wells prior to Remedial Action (RA) activities. Over half of these homes (approximately 75) had water supply wells that were or could potentially be affected by the contaminant plume as depicted in the 1998 Remedial Investigation (RI) report. In August 2000, five of these residences were supplied with carbon filtration units, and in September 2000, sixty-four (64) of the residences were connected to the Gastonia public water supply as part of the RA to execute the provisions of the Record of Decision (ROD) for the site. The locations of the residences connected to the Gastonia public water supply and lhc carbon filtration units are presented in Figures 1-2 and 1-3, respectively. 1.3 GROUNDWATER CONTAMINANT DESCRIPTION This section describes the potential source area of the contamination, current knowledge of the groundwater plume. and the extent of the plume. K :120064\ 1 30\Second Serniannual\F eb04Semia nnua1Rp1, doc 1-3 RFW138·2A-APIM ~ {.'J -0 I ... a Di af I -- - c:...:...: L_ --r ·-- - --..., --· --r· ._, -=-:..J LEGEND --__ 1 O 0 D -RESIDENCE DAVIS PARK ROAD <; D t:::, [I 0 fj q u 0 0 a [/ 0 a fJ [] (f 0 0 0 \\ (/ 0 CJ MOORE'S ffiANSMISSION SHOP 0 '1 CJ I f D C oo : 0 • D DAW. PARK ROAD ~ C ◊ ~ C 0 1 <::> • 0 ◊ 0 0 DAVIS PARK ROAD TCE SITE GASTONIA, GASTON COUNTY, NORTH CAROLINA RESIDENCE CONNECTED TO CITY WATER SEPTEMBER 2000 00 l ' -A • • ~ ~ ~ • • C ., ◊ ~ 0 <> ~ ... /J 1"'~ ~ go -1"'"'"~ 0 O' □ DESIGNE~S/CONSLn...TANTS DRAWN: DATE: W.O. NO.: RESIDENCES CONNECTED TO CITY WATER SEPTEMBER 2000 J. MILLER 2/12/07 20064-138-100-0930 DES. ENG.: DA TE: FIGURE 1-2 CAD NAME: fig-1-2.dw I ln --,_•·_ - - - c.:_: ~ - - r_·_ -- - - 1 __ , LEGEND O 0 CJ -RESIDENCE OAVIS PARK ROAD c::::, ri ? Z) 0 D D 0 w 0 aO og 0 0 DI /J g 0 rJ 0 0 /j Q 0 0 0 (? CJ 0 DO □ D - CJ 0 E'loo □ ODO OD 0 CJ c::i DAVIS PARK ROAD MOORE'S TRANSMISSION SHOP 2419DPR □ Q Oe:,a -Q ',] c:::, 2717DPR 0 \J [?" 0 □co 'i'::J PURITAN ST. CJ CJ □ D 0 1 0 i 0 oo ~ ◊ 1 0 0 0 1 ~ • • D [:J ◊ Q 0 DAVIS PARK ROAD TCE SITE GASTONIA, GASTON COUNTY, NORTH CAROLINA RESIDENCES SUPPLIED WITH CARBON FILTRATION UNITS AUGUST 2000 FIGURE 1-3 RESIDENCE SUPPLIED Wini CAASON FILTRATION UNITS t::, D 0 D " 0 ORA\.VN· t:J 0 C:i J. MILLER J lo DES. ENG.: DATE: 00 J ¾ J J </' 2837DPR ~ - ~ 100-0930 11 1J ,~1 ,:-, 1:-1 1· 1 ,: ) 1'.l 1.1 ,:-1 1·1 11 1:I 1: I ,u 1:J 1l ,_1 1U This document was prepared by Weston Solutions, lnc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. 1.3.1 Contaminant Source Area February 2004 Semiannual Sampling Event Report Davis Park Road TCE Site Section: 1 Revision: O Date: April 2004 According to preliminary site investigation reports (see RI Report, 1998, for summary), a groundwater sample was collected on 31 March 1990 from a supply well within the Cedar Oak Park subdivision by Gaston County Environmental Health representatives as part of a routine sampling procedure in accordance with "Community Well Rules." Analysis of the sample revealed concentrations of TCE (34.9 micrograms per liter fµg/1]), tetrachloroethene (PCE) (23.7 ftg/1), and chloroform (9.2 µg/1). Analytical results for a confirmation sample collected from this well on 17 April 1990 were similar to the original sample. Groundwater samples collected from three nearby private wells in May 1990 by the Gaston County Health Department indicated that the groundwater was contaminated with TCE. The highest concentration of TCE (IO I .4 µg/1) was detected in a sample collected from the private well located at 2419 Davis Park Road, 200 feet south of the Davis Park Auto Repair facility (located at 2307 Davis Park Road). The current EPA Drinking Water Maximum Contaminant Level (MCL) for TCE and PCE is 5 µg/1. Current ·State (North Carolina Department of Environment an·d Natural Resources [NCDENR]) MCLs for TCE and PCE are 2.8 µg/1 and 0.7 µg/1 respectively. Street address locations are shown in Figure 1-4. The Environmental Services Division of EPA collected groundwater samples from the contaminated wells along Davis Park Road and within the Cedar Oak Park subdivision in July 1990. TCE was detected at concentrations of 82 µg/1 and 31 µg/1 in groundwater sampled from the private well located at 24 I 9 Davis Park Road and a Cedar Oak Park subdivision well (27 I 9 Davis Park Road), respectively. ·-. Additional investigations and groundwater sampling events prior to the initiation of the RI continued to reveal levels of contaminants above State and Federal drinking water standards. Investigation activities focused on a possible source location(s). Several potential sources of the K:\20064\138\Second Semiannuar'IFeb04SemiannualRp1.doc 1-6 RFW138-2A-APIM I -.J <r ~ ' ~ z ~ --_,_-_ [)-- ~ ' FIGURE 1-4 ;:: SITE MAP -- - 0 G ~ -- - 0,~ ,m - GAST0'1u\ CITY UMITS p C:J El D ICHlANO AVENUE • I EJ C, I \ -__1 __ , RK T~CIDCJDCJO PArlf GLENRAVEN AVENUE ;::;==~==~1 Q 02634S O a o □ ,,ci if!407 ,, 2S9Sp .Jf 5ysttUTl 1eWff'' tii ' " is I a ~ 0 0 '§ <l~ 0 □~ z Om 0 □ 0 D 0 CJD 0 GOt'.J O ) ,-,:------,?""-""--- 14 rl< f,;/r Cl Dallis Park \ □ <::, ' [J <:, r 2916 "PS/k 0 ::=:---::-:'bi:;--__,,.----~, r-~- Approximate Scale In Feet __ , I DAVIS PARK ROAD TCE SITE ,, GASTONIA, NORTH CAROLINA o 600 1200 Sc.__ ____ ---:--_______________________ __j 11 .~, ,·1 1:-1 1:-1 11 1J 1: I ,:1 1:I 1· 1 11 1:.J 1l 1J ,~1 1-I 1-j 11J This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. February 2004 Semiannual Sampling Event Report Davis Park Road TCE Site Section: 1 Revision: O Date: April 2004 contamination at the Davis Park Road TCE Site were reviewed. Consideration of proximity, regional and local groundwater flow directions, and groundwater sample analytical data indicated that the Davis Park Road Auto Repair facility was the most likely contaminant source at the Davis Park Road TCE Site (NCDENR Site Inspection, 1993). As a result of these findings and in an effon 10 further define the source area for the water supply well contaminants, environmental assessments were conducted, including the Site Inspection Addendum (SI) (May 1993), Expanded Sile Investigation (ESI) (May 1994), and RI (1996- 1998). The RI report summarizes the source investigation as follows: " ... according lo data generated from this and previous investigations, solvents such as PCE or TCE were introduced lo the environment from the property al 2307 Davis Park Road. This 'spill' migrated through the vadose zone and the saprolite/partially weathered rock aquifer, and into the bedrock aquifer. Once introduced into the environment, various biophysiochemical processes acted on the contaminants lo reduce the overall concentration as well as spread the contaminant mass throughout various matrices. Currently, the VOC contaminants, principally TCE and PCE, appear to be present only within the bedrock aquifer and may continue lo be drawn towards active residential wells scattered throughout the site, specifically those wells to the west of Davis Park Road." 1.3.2 Groundwater Plume Concentration and Extent Five potential sources for waler supply were identified in the Davis Park Road Area and presented in the RI report. These include the following: City of Gastonia Public Water Supply System; City of Gastonia Restricted Use Water Line; water supply well._as part of a Community Water System; a water supply well as part of a Private Well System, and private water supply wells. Nine monitor wells were installed during completion of the RI (MW-IS, MW-ID, MW- 2S, MW-2D, MW-3S, MW-3D, MW-4S, MW-4D, and MW-SS). Following connection to City K:12006411 38\Second Serniannual\F eb04 Semi .innualR p1. doc 1-8 RFW138·2A-APIM 11 1: I ,··-, .~ 1 ,:1 11 1· I 1'.·1 1: l 1: l 1·1 1. I 1:1 1l 11 1J This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. February 2004 Semiannual Sampling Event Report Davis Park Road TCE Site Section: 1 Revision: 0 Date: April 2004 Water in August 2000, seventeen private wells were abandoned, seven wells were converted into monitor wells (CW-I through CW-7), and five residences were supplied with carbon filtration units (2400 Skyland, 2419 Davis Park Road, 2717 Davis Park Road, 2839 Davis Park Road, and 2639 Springbrook). Figure 1-5 details the locations and water supply source of residences within the vicinity of the Davis Park Road TCE Site updated to include activities completed as part of the 1998 RI and as part of the 200 I RA to execute the provisions of the ROD for the site. A summary of analytical data for the primary constituents of concern (PCE and TCE) detected in groundwater sampled at the Davis Park Road TCE Site is presented in Table 1-1. Analytical data was obtained for groundwater sampled after August 200 I from tile 5 residences supplied with carbon filtration units as pa11 of the RA to execute the provisions of the ROD. This data is included for PCE and TCE in Table 1-1. As described in the 1998 RI, the contaminant plume was centered along Davis Park Road from Glenraven to Blackwood Creek and underlies areas approximately 500 feet to the east and west of Davis Park Road. 1.4 SITE GEOLOGY AND HYDROGEOLOGY The geologic profile across the site generally consists of a saprolite layer, underlain by a partially weathered rock zone and the underlying fractured crystalline bedrock. The saprolite is a silty, clay-rich, residual material derived from in-place weathering of rock. The saprolite zone appears to be thickest (approximately 80 feet) near the ridge crest along the northern edge of the site, thinning towards the lower elevations or stream valleys to approximately 20 feet in thickness. A partially weathered rock layer typically underlies the saprolite, and ranges in thickness from approximately 5 to 25 feet. This layer is composed of saprolite and fragments of weathered bedrock. The bedrock is generally observed to be a fractured quartz biotite granite or granitic gneiss. K:\200641138\Second Semiannual\F eb04 Semiannual R p1. doc 1-9 RFW138-2A-APIM ,-1 ,~1 11 l~l 1:l 11 .. ! IJ 1:J 1'.] liJ 11 l 11 1J 'l'J 1J 1'J , I 1.1 1J iJ N W --{fflll)--. E s 0 [] 0 0 Cl c::i Cl ~-"' 0 c;\ •. -, B .,.,.,\ \.--' C) y· 0 ~~ _...,.,-::;:::::-::::-----••"'~ -~-'<>~ i;P 0 ...-,\ ..., e;· y-:,, h ; 00 0 .. </ . ;::-!) t:::::J O y\ <-' C 0 0 "' ◊ .;::,□ # ® ,..... ~ 0 \j ~-'" ◊ ® GARAGE b D : 0 ~ ◊ ◊ ,;;:,® ,....,, <:> <:> <? <? oo<:> ~ 0 ,=--00 Oo .,..,, C ,....., ®~I' r::; oi!:ioc:,ooo 0 C] --0 ,_ !] oi, □• ..... ~ ~ □~ r' ~ ,-, ~ !::: r::: \~oJ '),<i>. · v: (".) ~ --GOtl-UCCT. \.\ I I □ . ' :,__I -_, _, :..___; -I ~-RICHL..AND AVENUE ' I -_c ' c_,' I --· I_J __ , _ _; ~I -=-I ;..:_1 __=1 _:_1 GLENRAVEN AVENUE I -I i ... :..J ~ --· Cl -~·: _I I :.J ... -; r::: D '=J t::i CEDAR OAK CIRCI..£ '!'.'~.,._ ) t, n <:, \) 0 ) \:' n <'1 t.\~ f \ c::=J _·_1 c=J c:::::::J c:::::::J c:::::::J '\ ,\ ·. ,. \ <? <:> (> <> ◊ 0 ,z ---jr_ • ' . cl ...-'® I I 0◊ <> <!) 0 0 0 ®□ ...... a C C G a 0 .--() .... '""' D D Y.'<.+-• 0 > D z z ll ~ /) D oo a 0 ◊ c::, CJ t::rCJOD 0 I I .,..:'-' \ -~, II . □ () "Cl ~ tr" :'i} () !....i#'\1 ~ \ )i,® I I 0 I "® 0 LEGEND RESIDENCES CONNECTED TO CITY WATER RESIDENCES ON RESTRICTED USE WATER LINE-CITY OF GASTONIA RESIDENCES ON COMMUNITY WELLS > OR= 15 SUBSCRIBERS RESIDENCES ON PRIVATE WELL SYSTEM WITH 2-1-4 SUBSCRJBERS RESIDENCES ON PRfVATE WELLS RESIDENCES WITH CARBON FD..TRATION UNIT □ ~ CJ w -f->-_f-(J) z :::) w O <( S:: u z _J ozo <( 0 er: of-<C er: (J) u <( :,,:0 :r: er: -f-<( <( er: Q_ z 0 oz (J) f-> (J) <( <( 00 0 n a, 0 II~ 0 0 I l"-ro o n I g ~I" .o e:1 OQ I 3: N I.fl ~ 3 -0 >, CL N .. 0. 0 ~ :) ' -"' '"-~ WIJ)oQ) 1-'----.0 ....... <t:<..0<CO o U 3 a:: w _J ~ .. ....J.,:..: I ~~ 3 N <C >-" . <C 0-, J (J) w u er: :::) <( 0 er: (J) >-0 _J z Q_ 5 o..o :::) _J (J) _J 0 er: LL w f-<( 5 1-10 "' I w a:: :::, 0 G: z 0 vi 5 w a:: w >-<l'. 0 0 > a:: (l_ <l'.. - - - - - -This document was prepared by Weston Solulions, Inc. expressly for EPA. It shall not be disclosed, in whole or in part, withol/1 the express written permission of EPA. Table 1·1 Residential Well Hlstorlcal Analytical Results Davis Park Road TCE Site Address 2501 Briaroak 2510 Briar Oak 2241 Cedar Oak 2326 Cricket 148 Grassy Date 6/14/90 5/6/96 PCE ND ND TCE NO NO Address 2302 Hedgewood 2314 Hedgewood Date 5/7/96 1/14/98 PCE .66AJ NO TCE NO NO 111-1ooress 2618 Puritan 2612 Puritan ln,1e PCE TCE 10 Screen Date PCE TCE Address Date PCE TCE Address Date PCE TCE J · Estimated Value A . Average Value NO = not detected 4/27/90 517/96 NO NO NO NO MW-1S MW-10 20-30 40-75 1/13/98 1/13/98 NO NO NO NO 2329 Skyland 7/10/90 5ll/96 trace NO trace 18A 2407 Sky1and 4/27/90 5/7/96 NO NO NO 2.6A All results reported in microgram~ per liter 6/9/92 1K NO 2322 Hedgewood sn195 ND NO 2704 Puritan 5/6/96 NO NO MW-2S 5-15 1/14/98 NO NO 2304 Skyland 3!7/95 J 0.91 2415 Sky1and 517/96 NO NO K .\2():)f;4\J .l~\<;ccond ScmiannuaN'eh04.SciniannualRflHhl~.~I~ 517/96 517/96 5/7/96 ND ND NO NO NO NO 2347 Hedgewood 2363 Hedgewood 2375 Hedgewood 1511 Jackson 6/14/90 Sn/96 6/27/91 1/13/98 5/6/96 NO NO 1.1 NO ND NO NO ND NO 0.97AJ 2720 Puritan 2725 Puritan 2230 Richland 2425 Rotan 517/96 4/27/90 5/7/96 2/3/93 Sll/96 NO trace ND NO NO NO trace NO NO NO MW-20 MW-3S MW-30 MW-4S MW-40 21-54 64-74 87-150 36-46 130-142 1/13/98 1/13/98 2/25/98 1/15/98 1/15/98 6 NO NO NO NO 17 ND NO NO NO 2308 2314 Skyland Skyland 2309 Skyland 3/7/95 5/23/94 4/19/93 Sfl/90 5/6/96 NO NO NO 0.85 0.52J 0.75 0.72 NO NO 2634 Sky1and Skyland Community Well 4/27/90 5/6/96 4/27/90 7/18/93 9/8/93 trace ND NO NO 1K trace NO NO 2.4 1K 1-11 8/24/00 10/17/00 NO ND 7.4 8.2 MW-5S 9·19 1/14/98 NO NO 2400 Skyland 8/24/00 10/17/00 NO NO NO NO - 2639 Springbrook 2232 Tate 1/24/01 5/9/01 8/10/01 11/20/01 2/25/98 NO NO ND NO NO 8.8 10 8.6 6.8 34 1/24/01 5/9/01 8/10/01 11/20/01 NO NO NO NO NO NO NO NO ---- - - ---·--This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or In part, without the express ~itten permission of EPA. Address 627 DPR 2212 DPR 2231 DPR Date 6/11/90 6/11/90 6/14190 7113/90 1125194 PCE ND trace ND 1K ND TCE ND 1K ND trace ND Address 2307 DPR Date 818191 8113192 4119193 2110/98 2110198 PCE ND ND ND ND ND TCE 301 0.75 172 ND ND Address Date 4/27/90 5/7/90 6/21/90 716190 8123190 PCE 1K 0.85 1K ND 1K TCE 101.4 NA 134.3 82 116.3 Address 2425 DPR Date 5/7/90 5115/90 PCE 0.31 trace TCE 8.4 6.8 Address 2509 DPR 2603 DPR Date 5/7/96 6/11190 PCE ND 1K TCE NO 1K Address 2723 DPR Date 6/11/90 PCE NO TCE ND E,J • Estimated Value A -Average Value 516196 .76AJ ND 7113/90 213193 ND J 7.0 30E 6/14/90 516196 ND ND NO NO 2800 OPR 5123190 518196 NO 0.62AJ NO NO K -Actual value is knOwn to be less than value given ND • Not detected K :\2()()6411 J8\Sccond SemiannuaTIFch04SemiaMualRpt-tt,ls.ds --- 3119193 trace 8.0 8/24/00 2.2 2.8 6114190 1K 1.2 5/7/96 5/7/90 ND 0.25 ND 5115190 5120190 trace trace 44.5 24.3 1019190 1/30191 ND 1K 68AJ 84.2 1/25/94 5130195 ND ND 11 NA 2717 DPR 10117100 1124101 0.68 1.8 0.79 2.1 2816 OPR 516196 2110198 6.4A 10 14A 18 Table 1·1 (continued) Resldentlal_Well Historical Analytical Results Davia Park Road TCE Site 2301 DPR 2304 DPR 5115190 7113190 1125194 5/7/96 1114198 5123194 trace trace ND ND ND ND 44.5 37.1 ND ND ND 0.91 2403 DPR 7112190 1130191 7123192 4119193 9124193 1/25/94 . trace trace ND ND ND ND 37.1 28 17 12 7.3 10 2419 DPA 5120191 213193 6121193 9124193 1/25/94 8/5/94 1K 0.48 0.56E ND ND ND 66.2 54 23 30 38 NA 2503 DPR 5/7/96 5115190 3119193 5123194 ND ND ND ND 3.0A ND 1.5 0.65 519/01 8/10/01 11/20/01 3131/90 5/1190 6/21/90 1.3 1.2 0.96 23.7 18.9 1.4 1.2 1.1 34.9 51.8 51.8 2839 OPR 8124/00 10117100 1/24/01 519101 8110101 11120/01 ND NO NO NO NO ND ND ND NO NO NO NO 1-12 5130195 1/16/98 ND ND NA ND 5/30195 5/7/96 2110198 8124100 ND ND ND ND NA 15A 8 2.4 2719 DPR 7/6/90 8123190 1019/90 5117193 12 20.9 14 13.7 31 56.1 41 44,6 - -- - 10/17/00 1/24/01 519101 8/10/01 11/20/01 ND ND ND ND ND 2.4 2.6 2.6 2.2 1.8 1/25/94 1/25/94 5/7/96 1114/98 18 17 10 14 51 so 32 32 . -:•·•;••.:\ •:•o•;.•: ·;••:.. : . ~ ·. ; . . .•• .. -.. wl. <"'<:.. /• ·1 ! ;. :,. .. I " . ' ,,/, . . ., :,-·•·· ·, --· .. ' • ~-: '·, "J •• /":i-•.~• .... ~ !w':,";:,f: . .. •,.·., , ' "': . ' ., -~·-.:i:{~:;-< t:.:,._. c, ·~ ~1•'-:.'':-' ::;_ ~. r' •. :" :· . l. - . '· --~. ': ~-•: ·. ' ·:·>·t·~• .. ,:·:.:.1 ..... ···-::-·.: ·_,!_ '!,~?<." r ~ •; ,j ·.J /:.,• ..... ~,. ::_.. ):•,',. ·,?'.• . ·,~ ... ,:• , .. ' .. '·. Cl")/' -. ;-•• '·'r . '.,.: · . . { •.. , .·,· · .... !''• :-: ·:: ~- '. ·. ,·.· .. .. -;:_: • {1 :, •• t· .. ,..... ·.· .... _.'. .. , -1·, ~·j·_ .'--1. •. ',· • ~,. • r. ··-:-1. ... ·,. ' r·. ··.· ,-r. I I I I I I I I I I I I I I I ,-. I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. SECTION 2 February 2004 Semiannual Sampling Event Report Davis Park Road TCE Site Section: 2 Revision: 0 Date: April 2004 · LONG TERM RESPONSE ACTION The ROD for the Davis Park Road TCE Site (September 1998) states that following initiation of a natural attenuation study, groundwater monitoring will be conducted on a quarterly basis for three years and annually for the next 27 years. First year LTRA sampling results indicated a continued decrease in contaminant concentrations as the plume migrates south and away from the source area. Additionally; contamination concentrations did not vary significantly between sequential quarters for any of the wells in the monitoring network. It was therefore recommended that the s·ampling program be reduced from quarterly to semiannual monitoring. Results from the second semiannual event are summarized in Section 3.0. Data obtained from the long term groundwater monitoring will be used to evaluate natural attenuation of contaminant constituents within the bedrock aquifer plume at the Davis Park Road Site following provision of city water to 64 residences in August 2000. In April 2002 a baseline sampling event was conducted to establish current conditions and to evaluate the need for installation of additional wells for the LTRA. Based on analytical results, it was determined that natural attenuation was occurring at rates consistent with expectations, and that the wells currently available for sampling were sufficient to evaluate natural attenuation in long term performance monitoring. A Monitored Natural Attenuation Plan (submitted to EPA in October 2002) was developed to include sampling a network of bedrock wells for VOCs to effectively characterize contaminant levels (VOCs) in the bedrock aquifer within the contaminant plume as well as the surrounding area for the potential migration of contaminants from within the existing groundwater plume. K:\200641138\Second Semiannual\Feb04 Semiannual Rpi. doc 2-1 RFW 138·2A·APIM I I I I I I I I I I ' I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. February 2004 Semiannual Sampling Event Report Davis Park Road TCE Site Section: 2 Revision: O Date: April 2004 The eighteen bedrock wells initially included for groundwater sampling in · each L TRA monitoring event included four bedrock monitor wells installed in December I 997 (MW-I through MW-4), the five private wells provided with carbon filtration units in August 2000 (MW-5 through MW-9), two community wells located west of Davis Park Road (MW-10 and MW-I I), four converted wells (MW-12 through MW-I 5), and three private wells (MW-I 6 through MW-18). Monitor wells MW-2, MW-5, MW-6, MW-9, MW-12, MW-15, MW-16, MW-17, and MW-18 were selected to provide groundwater quality information within the contaminant plume. The remaining monitor wells (MW-I, MW-3, MW-4, MW-7, MW-8, MW- 10, MW-I I, MW-13, and MW-14), located outside the contaminant plume, were selected to provide evidence of potential contaminant migration. Beginning with the first year fourth quarter sampling event, MW-I 3 was removed from the sampling network and replaced with MW-19, located south of the site, just outside the contaminant plume. Additionally, following the fourth quarter sampling event, two bedrock weUs were installed west of the plume to monitor the area between the plume and the.currently pumping community wells to the west of the site (MW-IO and MW-11). ll1ese wells were incorporated into the monitoring network and are designated MW-20 and MW-21. Figure 2-1 provides the locations of the monitor well sampling netw·ork. Table 2-1 provides monitored natural attenuation sample designations cross-referenced with addresses and former designations. 2.1 OUARTERL Y AND SEMIANNUAL GROUNDWATER MONITORING The purpose of quarterly and semiannual groundwater monitoring is to verify the following: • That natural attenuation is occurring at rates according to expectations, • No changing conditions arise that might reduce efficacy of this remedy, • ll1e continued absence of toxic and/or mobile transformation products, • Verification that the plume is not expanding, K:120064\ 1 38\Second Semiannual\F~ScmiannualRpt. doc 2-2 RFW138·2A·APIM <) <) ◊ 0 CJ 0 \® 0 0 CJ '\ CJ 0 11 \ / :>\'i'\~:::-..... CJ 0 0 N 111----+---+---------I <.,, APRVD. DATE: REVISION D C> CJ 0 <:> 0 0 <:::> ~ \) \) ~ ~ \) \) \) ® \ • 0 ~ \ p ~ ~ 0 ' \) 0 0 0 G □ 0 io d\~ ~ D 0 <? -· /-/~ -:, □ DAVIS PARK ROAD TCE SITE GASTONIA, GASTON COUNTY, NORTH CAROLINA L TRA MONITOR WELL SAMPLING NETWORK FIGURE 2-1 --· -·-..... -.•... -. --· ~-----: : .. ·! :-: :., ::.. ·-~:..; C/l () 0 = 0 D IT D 1 □ D ~□ D i □ CJ D D D 'i) D D ! □ 0 D i □ D □ □ □ □ D a ========0::::::::-"""" """"""'" D ----·-··-· ~ r r r § r ~ m (j) m z 0 DRAWN: DATE: W.0. NO.: J. MILLER 6/5/02 20064-138-100-0930 LAYOUT: CAD□ FILE: SHEET: OF 2-1 DAVISPARK.dw I I I I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly tor EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. Sample ID Status MW-I monitor well MW-2 monitor well MW-3 monitor well MW-4 monitor well MW-5 carbon unit MW-6 carbon unit MW-7 carbon unit MW-8 carbon unit MW-9 carbon unit MW-IO community well MW-II community well v!W-12 converted well MW-13 converted well v!W-14 converted well MW-15 converted well MW-16 private MW-17 private MW-18 private MW-19 private MW-20 monitor well IMW-21 monitor well Table 2-1 L TRA Monitor Well Sampling Network Davis Park Road TCE Site Former Designation(s) Street Address MW-ID S of Cedar Oak MW-2D 2816 Davis Park MW-3D Leodora Drive MW-4D 2415 Skyland CO-I, PW-2, 121 2419 Davis Park CO-13, 235 2717 Davis Park 298 2839 Davis Park 252 2400 Skyland 182 2639 Springbrook CO-2, 300 2634 Skyland CO-3, 269 Briar Oak CW-5 Cedar Oak Subdivision 2719 Davis Park CW-6 Cedar Oak Subdivision 2241 Cedar Oak CW-4, 49 2403 Davis Park CW-7, 175 2232 Tate CO-5, 195 2725 Puritan CO-14, 286 2816 Davis Park 192 2800 Davis Park 277 2833 Penny Park -Leodora Drive (north of Skyland) -Leodora Drive (south of Skyland) K:\20064\138\Second Semiannual\Feb04Semiannua1RpHbls.x.L'i 2-4 Total Depth (feet below vronnd surface l 75 54 150 142 187 Unknown Unknown Unknown Unknown Unknown 270 112 125 74 145 Unknown Unknown Unknown Unknown 173 135 I I I I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed. in whole or in part, without the express written permission of EPA. February 2004 Semiannual Sampling Event ReJX)rt Davis Park Road TCE Site Section: 2 Revision: O Date: April 2004 • Verification that there is no impact downgradient, • Detection of any new releases, and • Verification of attainment of remediation objectives. The samples are collected in accordance with the following documents: • Final Monitored Natural Attenuation Plan, dated October 2002, • U.S. Environmental Protection Agency Science and Ecosystem Support Division (EPA- SESD), Region 4, revised Environmental Investigation Standard Operating procedure and Quality Assurance Manual (EISOPQAM), May 1996, and • U.S. Geological Survey, User's Guide for Polyethylene-Based Passive Diffusion 13ag Samplers to Obtain Volatile Organic Compound Concentrations in Wells, 2001. All samples are analyzed by laboratories in the Contract Laboratory Program. Samples are analyzed for VOCs using EPA Method 8260. 2.2 FIRST YEAR OUARTERL Y LTRA SAMPLING EVENTS (2002/2003) The first quarter sampling event, performed in April 2002, was originally developed as the baseline event to establish current conditions and to evaluate the need for installation of additional wells. Based on analytical results, it was determined that the wells currently available for sampling were sufficient to evaluate natural attenuation in long .term performance monitoring. Thirteen of the I 8 wells selected for the sampling network and two additional wells were sampled in the baseline-sampling event. All 18 wells in the LTRA sampling network were sampled during the second and third quarter sampling events, performed in September and December 2002, respectively. During the fourth quarter sampling event, performed in March 2003, monitor well MW-13 could not be sampled due to hostile property owners. The residence at 2833 Davis Park Road was K:1200641138\Second Somiannual\Feb04SerninnnuaIRpt.doc 2-5 RFW138-2A-APIM I I I I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, Vvithout the express written permission of EPA. February 2004 Semiannual Sampling Event Report Davis Park Road TCE Site Section: 2 Revision: O Date: April 2004 sampled. instead, and incorporated into the monitor well network as MW-I 9. Because the current owners of the property were not willing to allow samplers to pass through their yard to access the well, and because VOCs have not historically been detected in groundwater sampled from the well, MW-13 was removed from the monitor well network permanently and replaced with MW- 19. All of the remaining 17 wells in the LTRA sampling network were sampled during the fourth quarter sampling event. Depth to water was recorded where possible (MW-I through MW-4, MW-12 through MW-15) prior to sampling. Field parameters (pH, specific conductivity, temperature, dissolved oxygen, oxidation reduction potential, and turbidity) were also recorded. The potentiometric map for the bedrock aquifer in first through fourth quarter LTRA sampling events indicated a groundwater flow direction in the bedrock aquifer ranging from south to east across the site, with the strongest component of flow to the southeast. This is consistent with previously reported data. TCE and PCE concentrations detected in groundwater during the first through fourth quarter sampling events suggest the contaminant plume is migrating slightly to the west and also southeast. Concentrations were significantly less than those detected in 1990 for wells in the northern portion of the plume. However, concentrations increased slightly in wells to the west and southeast. Levels were consistent with a naturally attenuating plume that is shifting due to pumping (community wells on Skyland Drive and Briar Oak Drive located west of the site) and to a groundwater flow direction trending to the southeast and Blackwood Creek. First through fourth .quarter analytical results are detailed in the LTRA Second; Third, and Fourth Quarter Sampling Event Reports submitted to EPA in January, April, and June 2003, respectively. K:\200641138\Second Semiannuaf\F eb04 SemiannuaIRp1. doc 2-6 RFW 138-2A-APIM I I I I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. February 2004 Semiannual Sampling Event Report Davis Park Road TCE Site Section: 2 Revision: 0 Date: April 2004 2.3 SEMIANNUAL LTRA SAMPLING EVENT (AUGUST 2003) Following the first year of quarterly sampling at the Davis Park Road Site, two additional monitor wells were installed between the contaminant plume and the currently pumping community wells MW-IO and MW-11. These wells, designated MW-20 and MW-21, were incorporated into the L TRA monitoring well network and sampled in August 2003, along with the remaining I 8 monitor wells previously included in the sampling program. Also during this sampling event, passive diffusive bag (PDB) samplers were placed in seven monitor wells (MW-I through MW-4, MW-12, MW-14, and MW-15) two weeks prior to the August 2003 sampling event. The PDB samplers were pulled and sampled concurrently with low-flow sampling to evaluate PDBs as an effective sampling alternative for the remaining duration of the LTRA. Sampling procedures otherwise were identical to previous quarterly sampling events described in Section 2.2. The potentiometric map for the bedrock aquifer in the first semiannual sampling event indicated a groundwater flow direction in the bedrock aquifer ranging from south to east across the site, with the strongest component to the southeast, consistent with· previously reported data. However, the addition of three new survey points (MW-15, MW-20, and MW-21) provided data indicating that there is also a west to southwest component to the groundwater flow. This flow component may be attributed to the actively pumping community wells to the west of the site. TCE and PCE concentrations detected in groundwater during the August 2003 semiannual LTRA sampling event continued to suggest the contaminant plume is migrating slightly to the west and also to the south. Trace TCE and PCE concentrations were confirmed in private well MW-19, which was added to the monitor well network during the fourth quarter sampling event. MW-19 is located at the south-southwestern portion of the site. Additionally, TCE was detected in newly installed monitor wells MW-20 and MW-21 at concentrations below the ROD K:\20064\ 1 38\Second Semiannual\F eb04 ScmiannualRp1. doc 2-7 RFW138-2A-APIM I I I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. February 2004 Semiannual Sampling Event Report Davis Park Road TCE Site Section: 2 Revision: 0 Date: April 2004 Remediation Goal. MW-20 and MW-21 are located between the contaminant plume and the actively pumping community wells west of the site. The semiannual analytical results are detailed in the LTRA August 2003 Semiannual Sampling Event Report submitted to EPA in December 2003. Analytical results for PDB samples generally corresponded well with the results of the samples collected using low-flow technology. The average relative percent difference. for COCs (excluding MTBE) detected above the reporting limit using low-flow and the PDB sampler placed closest to low-flow intake depth was 18 percent. All constituents detected above the reporting limit in the low-flow samples were also detected in the PDE sampler at similar concentrations, and all reported detections exceeding the remedial goal in the low-flow sampler were also detected at concentrations exceeding the remedial goal in the PDE sampler. Because the PDBs provide representative samples of the principle COCs in groundwater at the Davis Park Road Site, while at the same time being more easily implemented and cost-effective than low- flow sampling methods, it was recommended that PDBs be used to sample accessible wells in the monitor well network for the duration of the L TRA. K:\20064\ 1 38\Second Scmiannual\Feb04 Semiannual Rp1. doc 2-8 RFW138-2A-APIM ,·,1, -.. I. ••• ,,, •. . . I •• I I ,, ' . ' ·' -' ,, ,, '•.- ·,.,, .I... ·~-'· Sect ioi1. ·3. -!. ·r -' · .... , .... " I' I I I I I I a I I I I I I I ! I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written pennission of EPA. February 2004 Semiannual Sampling Event Report Davis Park Road TCE Site Section: 3 Revision: O Date: April 2004 SECTION 3 FEBRUARY 2004 LTRA SUMMARY Section 3 of this report summanzes activities conducted as part of the second semiannual sampling event for the Davis Park Road TCE LTRA. 3.1 GROUNDWATERSAMPLING 3.1.1 Monitor Well Sampling Procedures WESTON mobilized to the site the week of 3 February 2004. Groundwater samples were collected from the 20-monitor well network from 3 February through 5 February 2004. During the February 2004 sampling event, recently installed monitor wells MW-20 and MW-21 were sampled using low-flow techniques and also with PDB samplers. A comparison of the low-flow samples with the PDB samples will be discussed in Section 3.4.2. Low-flow groundwater samples were collected in accordance with Puls and Barcelona (1996) Low-Flow (Minimal Drawdown) Groundwater Sampling Procedures published by the EPA Superfund Technology Support Center for Ground Water using a MicroPurge bladder pump. Water level and field parameter measurements (pH, specific conductivity, temperature, dissolved oxygen, and oxidation/reduction potential) are summarized in Table 3-1. All downhole equipment was decontaminated prior to use in each well. Pump intake was lowered to well screen depth, and the well was micro-purged until field parameters stabilized. Laboratory samples for YOC analysis were then collected in pre-labeled, pre-preserved sample bottles. Bottles were capped appropriately, placed in a Ziploc-type bag, and stored in an ice-cooled K:\20064\ 138\Second Semiannual\F eb04 Semiannual Rp1 ,doc 3-1 RFW138·2A-APIM ------Thi1 document was prepared by Wu ton Solul>Onl, Inc., OPrHtly for EPA.!\ 1haU not bt dltcloted, In 'M)Qle or In part, ~lhout Iha np1n1 ....,.ir11n p11TT1,.1'0n ot EPA, Sample ID: Former 10: Street Location: Screened Interval: Total Depth (record): Dale: Total Depth (measured): Top ct Casing ElevaUon (It msl): Depth to Water: Water Elevation m msl : Temperature ("C): Conductivity (µSiem): pH: Eh (mV): 0.0. _(mgll): Turt:Jidilv INTU)· Nein: ft mil • feel above mean 1ea level ll•fnt •c "degi.es Centigrade µSiem= micr0Si1m1r11 per ceritimatar mV • mil~Volta mg/\.. • millitram1 per lilar NTU • mtphalomalric turbidity uriitl NM., r-.ot manured 4116/02 I 78.0 I 4.80 682.70 22.00 174 5.41 126.2 2.84 47.5 MW-1 MW-10 S of Cedar Oak 40-75 ft 75 9/24/02 I 12/19102 I 3/12/03 79. \ I NM I 78.9 687.50 5.90 4.50 4.35 681.60 683.00 683.15 16.88 15.02 15.37 245 155 175 7.02 7.21 5.59 ·23.4 ... , 87.5 3.88 7.49 3.72 61.82 NM NM Table 3·1 Field Parameter Measurement Summary April, September, December 2002, March, August 2003, and February 2004 Davis Park Road TCE Site MW-2 MW-20 2816 OPA 21·54 " 8/20/03 2/4104 4119102 I 9/25102 I 12/19/02 I 3/12/03 I 8/20/03 I 2/4/04 78.67 NM 55.40 I 55.6 I NM I 55.44 I 55.48 I NM 684.60 4.89 4.20 5.28 7.10 NM 4.39 5.46 3" 682.61 683.30 679.32 677.50 NM 680.21· 679.14 681.06 18.16 NM 15.66 16.55 15.31 15.24 17.1 NM 100 NM $84 593 639 $27 $19 NM ,., NM 11.40 12.17 12.59 10.7 11,62 NM •2.4 NM 289.6 67.6 130.5 223.1 •34.6 NM 42.9 NM 3.91 3.35 5.58 2.47 70.4 NM NM NM 8.87 11.61 NM NM NM NM J.z liiii -- - - MW-3 MW-30 N or 2400 Skytand 87-150 '50 4117102 9/24/02 I 12/19/02 I 3/12/QJ I 8/20/03 7 2/4104 140.35 147.40 I NM I 137.00 I 139.10 7 NM 746.29 26.69 3\.\0 30.20 28.60 23.51 24.07 719.60 715.19 716.09 717.69 722.78 722.22 19.06 17.05 14.23 15.65 16.91 NM 135 156 127 151 147 NM 5.80 8.29 7.01 6.27 6.33 NM 486.2 69.1 12$ 278.2 81.6 NM 3.57 2.98 9.28 3.66 35 NM 111 663 NM NM NM NM --- --- -- -Thia document wu prep,u&d by WHton Soluliont, Inc., uprenty lor EPA. lt thllU not be dlsclo,&c:1, in v.Mle 01 in pert. 'Mtho\.11 the expreu wnn,n perminion of EPA. Sample ID: Former !D: Street Location: Screened Interval: Total Depth (record): Data: Total Depth (measured): Top o! Casing Elevation (It msl): Depth to Water: Water ElevaUon flt msl : Temperatura ("CJ: Conductivity (µSiem): pH: Eh (mV): D.O. (mg/l): Turbldlt" (NTU · Notn: 1l mil .. !eat ebove mean na lava\ tt .. faat "c • dagreu Cantigred& 1,151cm • mleroSlemen, p111 canhmt!er mV • milhVol!t m1,-1... millitram1 per fit1r NTU • nephelometric Nl'bidity urli!I NM• not m .. 1urecl K :\2()064\1.l~\\cmnd S~rn.-.nnu.1~t,04Scrri.um1111JRrt-1hl1.,1, 4/lB/02 I 9/24102 I 143 I 142.20 I 38.21 40.10 701.76 699.87 18.15 16.81 67 198 7.83 8.16 393.6 -124.7 3.17 2.39 60.3 19,4 Table 3-1 Field Parameter Measurement Summary April, September, December 2002, March, August 2003, and February 2004 Davia Perk Road TCE Site MW-4 MW•S MW-40 C0-1/PW-2 2415 Skyland 2419 DPA 130-142 187 142 Unknown 12/19102 I 312103 I B/20/03 I 2/4/04 9/23/02 I 12/17102 3/12/QJ I 8/19/03 I 142.20 I 142.20 I 142.26 I NM NM 739.97 NM 39.60 37.68 32.78 33.12 NM 700.37 702.29 707.19 706.85 NM 14.96 16.06 23.17 NM 17.88 15.5 NM 16.37 64 68 82 NM 263 175 NM 92 8.21 7.01 9.11 NM 6.12 6.44 NM 6.13 -19.6 124.6 99.2 NM 160.2 307 NM 218.3 7.26 4.32 46.1 NM 6.61 9.49 NM 71.7 NM NM NM NM NM NM NM NM 3.3 liilil -- - - MW-6 CO-13 2717 OPR Unknown Unknown 2/3/04 9123/02 t 12/17/02 I 3112/03 I 8/19103 I ~~04 NM NM NM NM 16.7 17.91 10.9 15.69 18.37 13.84 204 150 " 105 92 86 6.32 6.25 6.57 6.06 6.13 6.29 234 140.7 307.6 452.9 218.3 162 6.3 7.79 10.3 6.23 71.00 8 o., 10.5 NM NM NM 0.2 -------This document wii, prepared by Wu1on Solutions, lrx:., •~prenly !or EPA. It 1h1n not bt dl.ck> .. d, 111 M'!Ole ()r In part, l',jthout the upre11 'Min,11 perml .. ion of EPA. Sample ID: Former ID: Streel Location: Screened Interval: Total Depth (record): Date: Total Depth (measured): Top ot Casing Elevauon (ft msl): Depth to Weter: Water Elevation 1ft msl': Temperature ("C): ConductMty (µSiem): pH: Eh(mV): o.o. (mgfl): Turt>lditv !NTU): Nolu: fl msl ■ IH1 above mun 1aa 19Vtf ft,./11! °C • CMgJHI Centigrade µSiem ■ mlcroSiemene par cenllme!ar mV ■ m,niVolts mg\. • mil!itr1ma per lite, NTU ■ nephelometric turbidity Ul'l\tl NM■ not m111ured K :\20064\1 J!\Scaxid S~Scr!aaMm.J.Rpt-tbla.xla 9123/02 I 17.00 193 8.11 142.6 B.09 NM Table 3-1 Fleld ParamGter Measurement Summary April, September, December 2002, March, August 2003, and February 2004 Davia Park Road TCE Site MW•7 MW•8 2837 OPA 2400 Skyland Unknown Unknown Unknown Unknown 12/17/02 I 3/12/03 I 8/19/03 I '213104 9/23/02 I 12/17/02 3/12/03 6/19103 '2/3104 NM NM NM NM NM NM NM NM 12.40 12.50 16.58 14.20 17.22 13.32 14.05 17.31 14.45 112 152 147 "' 179 n 100 " 111 6.04 5.49 5.71 5.81 8.61 6.65 7.29 17.31 6.88 281.8 493.2' 194.6 287 160.4 295 360.1 195.6 247.5 9.94 6.75 74.1 7.01 8.87 9.68 8.21 95.6 a.n NM NM NM 0.15 12.22 NM NM NM 0.25 -- MW-9 2639 Springbrook Unknown Unknown 9/23102 I 12/17102 l 3/12/03 I 8/21/03 I '2/3104 NM NM NM NM 17.18 14.77 NM 17.01 15.99 "' "' NM 135 204 6.36 6.66 NM 6.42 6.32 158.9 288.1 NM 170.8 197.6 7.84 9.72 NM 89 7.43 12.57 NM NM NM 0.45 ----- --- -This document was prepared by Wea ton SOlulion1. Irie., exprtuly ror EPA. It 1hd !'IOI bt dieelo1ed, In \OhQlt or in p.1n, ....,:hotlt Ille a~pre■s ""10en permi11ion ol EPA, Sample to: Former to: Street Location: Screened Interval: Total Depth (record): Date: Total Depth (measured): Top or Casing Efevauon (It msl): Depth to Water: Water ElevaUon (I\ msll: Temperature ("CJ: Conductivity (µSiem): pH: En(mV): D.O. (mg,'L): Turbldltv !NTU1: NO!H: Jt mil .. rut 1bo~e mean HI le~•I ft•IHt •c • degr&H Centigrade µSiem • mieroSiem1111 per c1n11met,r mV • mil~Volta m9'1-• mlUitr1m1 P•• Utei NTU • nephalomatrlc turbidity unlta NM• ll<lt maHure-d 4/16102 I 16.75 165 6.56 315 8.57 0.01 MW-10 C0-2 2634 Sk),tand Uaknown 270 9124102 I \2/\9/Q2 I 3/\2/QJ I NM NM NM NM 16.62 16.12 NM "' 155 NM 6.65 7.21 NM 163.0 260.6 NM 7.95 ,., NM NM NM NM Table 3-1 Field Parameter Measurement Summary April, September, December 2002, March, August 2003, and February 2004 Davie Park Road TCE Sita MW•11 CO·3 Unknown Unknown S/21/03 I 2/3/04 4/17/02 I 9124102 I 12/17/02 I 3/12/03 I 6119103 I NM NM NM NM 16.47 16.27 19.56 16.86 14.55 16.15 19. 19 169 175 122 199 119 127 115 6.67 6.73 5.53 6.38 6.81 6.5 6.17 202.8 242.0 690.6 162.1 277.1 406.5 192.5 80.00 7.00 8.35 9.26 9.69 7.57 99 NM 0.2 5.69 NM NM NM 9 3-5 -- MW-12 CW-5 Cedar Oak SutxHvlslon 70-112 112 2/3/04 4/18/02 I 9125/02 I 12/20/02 I 3/13103 I 8/22/03 2/4/04 112.35 I 111.80 I NM I 112.10 I 111.96 I NM 707.21 15.80 21.40 16.20 12.54 11.61 I 15.17 691.41 695.B1 691.01 694.67 695.60 692.04 15.72 17.15 17.01 16.31 16.47 17.71 NM 119 59 123 58 57 42 NM 6.48 6.02 604 6.7 5.86 6.35 NM 204.8 543.9 153.4 271.6 578.2 214.7 NM 8.6\ 8.03 8.Q7 8.43 8.43 91.5 NM 0.25 23.14 148.1 NM NM NM NM --.. - - -----Thia document waa prepared by Wea ton Solut1on1, Inc., upreuly tor EPA. It aha II no1 be d111clo1ed, in ....nole or in part. "Mthout the upre11 1M1:ten permi11lon o1 EPA. Sample ID: MW•13 Former 10: CW-6 Street Location: Cedar Oal\ SuodMslon Screened Interval; Total Dep1h (record)· Date· Total Depth (measured): Too of Casing Elevation (ft msl); Depth to Water· Water Elevation m msl: Temperature ("C): Conductivity (µ$/cm): pH: Eh (mV); D.0. (mg/L): Turbldltv INTU): Noln: 11 mil a fetl above mu11 HI level flo,fHt •c • degrees Ce11bgrad1 µSiem • mlcroSlemens per cent1meter mV • milliVotta m!>'l -miUl17amt per liter NTU • nephelomelric turtildlty Uni\$ NM• not manured 4116/02 I 124.5 11.9 693.86 18.75 \17 6.59 237.3 5.14 387.6 K:~0064\ I .1~\~ccnod Semiannu:iN"-ch04Sc!Tl1111n1JalRp1-1bl<.~b 90-124.5 124.5 9126/02 I 12/20/02 124.5 I NM 705.76 17.1 11.2 688.66 694.57 16.51 16.51 155 155 7.36 7.36 ·16.0 ·18.0 2.61 2.61 7.16 7.16 Table 3·1 Field Parameter Measurement Summary April, September, December 2002, March, August 2003, end February 2004 Davis Park Road TCE Site MW-14 MW-15 CW-4 CW-7 2403 DPR 2332 Tate Unknown Unknown 74 143.3 9/25/02 I 12/19/02 I 3/13/03 I 8/21/03 I 2/4/04 9126/02 I 12/20102 3/13/03 . n.2 NM 73.9t I 74.03 NM 143.3 I NM 143.26 768.75 720.99 53.50 53.49 51.35 44,52 45.50 12,4 ,., 6.11 715.25 715.26 717.40 724.23 723.25 NM NM 714.88 16.90 15.04 15.89 18.20 NM 17.66 16.67 16.19 178 176 205 148 NM 210 22, 25' 6.08 6.25 6 5.16 NM 6.17 6.46 6.16 123.9 244.7 374.6 57.5 NM 95.4 26' 481.9 3.90 6.66 7.64 35.40 NM 7,17 7.86 7.63 319.4 NM NM NM NM 531.0 NM NM 3-6 ------ MW-16 C0-5 Unknown Unknown 8/21/03 I 2/4104 9126/02 I 12/17/02 1 3/12/03 I 8/19/03 I 2/3/04 143.3 NM NM NM 4.17 4.83 NM 716.82 716.16 NM 18.37 NM 17.18 15.\8 NM 17.52 16.2 195 NM 2\3 69 NM 115 12, 6.39 NM 5.93 6.42 NM 6.21 6.24 117.2 NM 113.8 106.2 NM 53.6 80.2 81.9 NM 5.70 7.49 NM 64.00 5.2 NM NM 19,04 NM NM NM 30 ---- - - - --Thit document wat prepared by Wu ton Sotuliona, Inc,. txp1euly 101 EPA. It thd not b,e dlaclo .. d, In 'M!Ole or In ~rt. without tt,, txp••u Ylfll!en permi .. ion of EPA. Sample ID: Former ID: Street Location: Screened Interval: Total Depth (record)· Date: Total Depth (measured): Top ol Casing Elevation (ft msl): Depth to Water: Water Elevation ltt msl: Temperature fCJ: Conductwity (11S/cm): pH: Eh(mV): 0.0. {mo,'L)· Turbidity /NTUl: Noles· 11 msl" feel at>ove m1tan sea level ft• feet °C ., degren Cenngrade 1151cm" mic:10S1emen1 per centimete1 mV = mitliVott1 mgtl -millitrams per liter NTU .. nephelometric turt>id,ry units NM= no\ meuur1d 4119/02 9/24/02 I 16.25 15.93 111 185 7.34 6.09 523.3 "' 8.18 10.7 0.01 5.56 K:\2006411,8\<ieawid Smun:,uaN',:t,O-C~1;11IRp1-1bls.UI MW·17 C0-14 2816 DPR Unknown Unknown 12/17/02 I 3/11103 ' NM NM NM NM 14.17 NM 95 NM ,., NM 285.6 NM 9.51 NM NM NM Table 3-1 Field Parameter Moaaurement Summary April, September, December 2002, March, Auguat 2003, and February 2004 Davia Park Road TCE Site MW-18 2800 DPR Unknown Unknown 8/19/03 2/3104 4118/02 9125102 12/17/02 3/12103 8/19/03 215104 NM NM NM NM 19.3 14.69 18.67 17.05 15.08 NM 19.3 10.55 105 109 "' "' "' NM "' "' 6.18 6.~9 5.65 6.15 6.13 NM 6.01 6.91 166.1 2'1 618.5 157.2 212.9 NM 79.7 130.7 66.9 7.35 5.42 5.03 11.55 NM 46.2 4.92 NM 0.45 23.32 143, 1 NM NM NM >1000 3.7 --- MW•19 MW-20 MW-21 2833 Penny Park Lendora N Lendora S Unknown 163-173 125-135 Unknown 173 135 4/18/02 I 8/19/QJ I 2/3/04 8/26/03 I 215104 8/26/03 I '214104 NM 173.4 135.5 NM 750.85 743.72 NM 30,14 29.70 28.21 27.75 NM 720.71 721.15 715.51 715.97 17.73 16.11 13.8 17.11 14.56 16.78 15.56 "' 135 "' 112 1'3 "' 1007 6.06 6.43 6.67 7.01 9.23 7.69 12.87 647.5 190.6 "' 66.4 23.2 110.9 -n.3 7.89 86.3 7.47 "·' '·" 33.8 5.9 1.11 NM 0.25 17 23 9 ,., I I I I I I I I I I I I I I I I I I I This OOC:ument was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written pem,ission of EPA. February 2004 Semiannual Sampling Event Report Davis Park Road TCE Site Section: 3 Revision: O Date: April 2004 container prior to shipment to the CLP designated laboratory, A4 Scientific located m The Woodlands, Texas. PDB samplers were used to sample the nine monitor wells that can be directly accessed at the Davis Park Road Site (MW-I through MW-4, MW-12, MW-14, MW-15, MW-20, and MW-21). The PDBs, polymer membrane bags, were filled with laboratory grade deionized water, attached to a polypropylene rope connected to the well cap, and lowered downhole 9 January 2004 at select depths (see Table 3-2). The samples were collected no sooner than two weeks later by pulling the PDB samplers from the wells, and decanting them into pre-labeled, pre-preserved sample bottles. After the sampler bag was disconnected from the rope, a new filled PDB sampler was attached and placed downhole at the same depth, to equilibrate with the surrounding groundwater for the next sampling event (scheduled for June 2004). 3.1.2 Community and Private Well Sampling Procedures Community wells MW-10 and MW-I I and private wells MW-5 through MW-9 and MW-16 through MW-19 were purged and sampled from the in-situ pumping system, but prior to any filter mechanism that may have been in place. Wells were purged at approximately I gallon per minute for a period of approximately 15 minutes. Specific conductivity, pH, temperature, dissolved oxygen, and oxidation/reduction potential were measured approximately every 5 minutes during the purge process. Purging continued until parameters were stable for three successive readings, and samples were collected as described above. Final readings for stabilized parameters are summarized in Table 3-1. K:\20064\138\Second Semiannuaf\Feb04Semiannua1Rpt.doc 3-8 RFW138-2A-APIM I I I I I I n I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. Table 3-2 Passive Diffusion Bag Sampler Placement Davis Park Road TCE Site Well ID Former ID MW-1 MW-1D MW-2 MW-2D MW-3 MW-3D MW-4 MW-4D MW-12 CW-5 MW-14 CW-4 MW-15 2232 Tate MW-20 North Lendora Dr. MW-21 South Lendora Dr. ft bgs = feet below ground surface ft msl ::: feet above mean sea level K:\20064 \ 138\Second Semiannual\Feb04Semiannua1Rpt-tbls Screened Interval (ft bgs) 40-75 21-54 86-150 130-142 68-103 ?-74 ?-143 163-173 125-135 3-9 Sampler Elevation Depth (ft msl) (ft bgs) 688 58.5 685 36 746 108 740 129.5 707 75 768 68 721 135 768 165; 170 721 127, 132 Sampler Elevation (ft msl) 629.5 662 659 610 627 705 591 603; 598 594;589 I I I I I I I I I I I I I I I I I ,'Y.. I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. February 2004 Semiannual Sampling Event Report Davis Park Road TCE Site Section: 3 Revision: O Date: April 2004 3.1.3 Field Quality Assurance/Quality Control Samples One rinse blank, one PDB field blank, one duplicate, and one trip blank were collected during the sampling event. The rinse blank was collected by pouring laboratory-grade deionized water over the low-flow sampling equipment. The PDB field blank was collected by pouring laboratory-grade deionized water into an unused PDB sampler prior to collecting the water in the sample vial. The trip blank was collected by pouring lab-grade deionized water directly from a container into the sample vial. A certificate of analysis for the deionized water is included in Appendix B. 1l1e trip blank was stored with collected samples throughout the sampling event. The duplicate sample was collected from well MW-15, using two PDB samplers. All samples were analyzed for VOCs using EPA Method 8260. Analytical results for the QNQC samples arc summarized in Table 3-3. Chloromethane and toluene were detected in the rinse, field, and .trip blanks at estimated concentrations below the reporting limit. Chloromethane was detected in groundwater samples collected from monitor wells MW-I, MW-4, MW-5, MW-6, MW-9, and MW-17 at estimated concentrations below the reporting limit. Toluene was detected in the low-flow and PDB samples collected from monitor well MW-20 at estimated concentrations below the reporting limit, and in the low-flow and PDB samples collected from monitor well MW-21 at low levels above the reporting limit. Chloromethane and toluene have been detected limitedly, in similar concentrations in groundwater sampled from various wells at the Davis Park Road Site, and may be the result of sample handling or conditions in the field. Analytical results have been flagged appropriately. Duplicate results were within acceptable relative percent differences (<15%).for all constituents identified at concentrations above the reporting limit, with the exception of methyl ethyl ketone. Methyl ethyl ketone was detected at 9.3 µg/l in the original groundwater sample collected from MW-15, but was not detected above the reporting limit (5.0 µg/1) in the duplicate sample. The K:\20Cl64\ 1 38\Second Semiannual\Feb04Semiannual Apt.doc 3-10 RFW138-2A-APIM I I I I I I I I I u I I I I I I I I This document was prepared by Weston SolutionS, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. Table 3-3 February 2004 Semiannual LTRA QA/QC Laboratory Analytical Results Summary February 2004 Davis Park Road TCE Site Sample Identification: Trip FB EB MW-15 Blank PDB Low-Flow Blank Rinse Blank Date Sampled: 213/04 2/5/04 2/5/04 2/4/04 Volatile Organic Compounds (ug/1) duplicate Chloromethane 0.33J 0.29J 0.29J <0.50 <0.50 Acetone <0.50 <0.50 <0.50 15 15 1, 1-Dichloroethane <0.50 <0.50 <0.50 0.27J 0.23J cis 1,2-0ichloroethene <0.50 <0.50 <0.50 4.9 4.3 T richloroethene <0.50 <0.50 <0.50 50 44J Methyl Ethyl Ketone <0.50 <0.50 <0.50 9.3 <0.50 Toluene 0.42J 0.29J 0.26J <0.50 <0.50 T etrachloroethene <0.50 <0.50 <0.50 0.22J 0.35J Miscellaneous Volatile Organic Compounds (ug/1) Freon 141 ND 0.58JN ND ND ND 3 Unknowns ND ND 2.2J ND ND 12 Unknowns ND ND ND 2.0J 2.1J Cyclotrisiloxane, Hexamethyl· ND 1.1JN ND 0.63JN ND Cyclotetrasiloxane. Octamethyl-ND 0.85JN 0.84JN ND ND Notes: Only constituents that were detected in at least one sample during the baseline sampling event are included in this table J indicates estimated value Bolded values exceed EPA MCLs PDB = Passive Diffusion Bag JN = Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. Samples were analyzed following CLP protocol. K:\20064\ 138\Second Semiannual\Feb04Semiannual Rpl·tbls.xls 3-11 I I I I I I i I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. February 2004 Semiannual Sampling Event Report Davis Park Road TCE Site Section: 3 Revision: O Date: April 2004 diffusion sampler method is not considered appropriate for sampling organic compounds with high aqueous solubility, such .as methyl ethyl ketone, and the discrepancy in results indicates that detections of this constituent should be considered suspect. 1,1-Dichloroethane and PCE were detected below the reporting limit at an estimated concentration (below the reporting limit) in both the original and duplicate groundwater samples. 3.2 GROUNDWATER ELEV A TION WESTON collected water level measurements referenced to the top of the well casing for monitor wells MW-I through MW-4, MW-12, MW-14, MW-15, MW-20 and MW-21 on the 3'd and 4th of February 2004. Depth to water was measured using an electronic water level meter. The water level probe and tape were decontaminated prior to each measurement. Field measurements, including depth to water and water elevation, are summarized in Table 3-1. Figure 3-1 provides a potentiometric surface map of the bedrock aquifer. Consistent with previously reported data, groundwater flow direction in the bedrock aquifer appears to be predominantly to the southeast, while to the north of the site, groundwater flow is also to the west and southwest, towards the actively pumping community wells MW-10 and MW-I I. 3.3 GROUNDWATER ANALYTICAL RESULTS 3.3.1 Groundwater Samples TCE and PCE were the only VOC constituents to exceed the ROD Remediation Goal in groundwater samples collected during the February 2004 Semiannual L TRA sampling event. TCE and/or PCE were detected in groundwater sampled from 12 of the 20 wells sampled. The Remediation Goal of 2.8 µg/1 (TCE) and/or I µg/1 (PCE) was exceeded in seven groundwater samples. TCE exceeded the ROD Remediation Goal in the following samples: MW-2 (4.0 µg/1), K:\20064\138\Secorn:I Semiannual\Feb04SemiannuaIRpt.doc 3-12 RFW138-2A-APIM vi I vi 0 0 0 D D [:, I 0 ENNy t::J "" 0 ·-0 ·~ Do 0 ◊ '0 <::J D D 00 CJ CJ \0 □®" ® '-1 '- '- 0 CJ 0 0 C> □ <) ◊ \) ® \ • ~ ,P ~ 0 ~ \) 0 0 <> 0 0 0 oi \ \) 0 i D o io 'ii>\®□ ~ D c:r~o 0 <? DAVIS PARK ROAD TCE SITE GASTONIA, GASTON COUNTY, NORTH CAROLINA □ ------+---+---------< POTENTIOMETRIC CONTOUR MAP BEDROCK AQUIFER FEBRUARY 2004 APRVD. DATE: REVISION ◊ IT 0 • D 0 lo D i □ CJ D D 0 'i) D D 0 0 0 (\ n 0 ! i Q :,,<• #-'" a """' QQ 0 0 0 I D D i □ D .□ D D D □ D ---.-- I ~ !il I 8~ ;;18 §--< 118 ~~ _c ""' ;; ~~ 0 = 8 0 c::> ,;>• ~ ~ 0 ~ ? """" """'""'" - ::: * ~ ~ r r r m "' r m ~ Ci) ~-m z ~ if 0 if s ! ORA\AIN: DATE: W.O. NO.: J. MILLER 6 5/02 20064-138-100-0930 LAYOUT: CADD FILE: SHEET: OF Fi -3-1 DAVISPARK.dw 1 1 I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc .. expressly for EPA. lt shall not be disclosed, in whole or in part, without the express written pennission of EPA February 2004 Semiannual Sampling Event Report Davis Park Road TCE Site Section: 3 Revision: o Date: April 2004 MW-6 (3.0 µg/1), MW-9 (7.8 µg/1), MW-12 (3.5 µg/1), MW-15 (50 µg/1), MW-17 (17 µg/1), and MW-18 (4.2 µg/1). PCE exceeded the ROD Remediation Goal in the following samples: MW-2 (1.3 µg/1), MW-6 (2.8 µg/1), MW-12 (1.4 µg/1), MW-17 (9.0 µg/1), and MW-18 (9.9 µg/1). Laboratory analytical results for first year quarterly and first year semiannual LTRA sampling events are summarized in Table 3-4. The results are summarized graphically in Figures 3-2 and 3-3 for TCE and PCE, respectively. Laboratory analytical reports are included in Appendix B. The highest TCE concentration (50 µg/1) was detected in groundwater ·sampled from monitor well MW-15, located at the west central portion of the site. The second highest TCE concentration ( 17 µg/1) was detected in groundwater sampled from monitor well MW-17, located on the southern side of the site. The highest PCE concentration (9.9 µg/1) was detected in groundwater sampled from MW-18, located near the south southeastern corner of the site. The second highest PCE concentration (9.0 µg/1) was detected in groundwater sampled from MW-17, also on the southern side of the site. Although TCE and PCE concentrations increased slightly in the majority of wells sampled in I . February 2004 when compared to the August 2003 groundwater sampling results, PCE and TCE concentrations in groundwater have generally remained stable or decreased at sampling locations I I I I I I during the first two years of the Davis Park Road TCE Site LTRA .. There are two areas where PCE and TCE concentrations continue to exceed guidance concentrations. One area is downgradient of the original groundwater contaminant plume center at the southern and eastern portion of the site. The second area is located in the central and western portion of the site. PCE and TCE concentrations in both these locations remain lower than historical detections in the former plume center. Trace concentrations of PCE were confirmed in groundwater sampled from locations west and north of the former plume boundaries, where formerly these constituents were not detected (i.e., K:\20064\ 138\Secood Semiannual\Feb04$emiarmua1Rpt.doc 3-14 RFW138-2A-APIM I. I i~ill6 ~jtff1Iillifi .-;: ;; ::: I~ 'if~ g_ ~-~;::; ~ g ;::;-;; ::: il.~i•~bttit~b[~i 66"' _--s.!~-:10:1 o-·-lll!lliil~~~•-·~i 1 1 !fg:~axi :,'f--s.gJog:g...:.., g_'S.')'-g:g:--s. --s.-s.gg.~~i -< o --s." ,. o -i ., ll omoi-., -< ~i!;"'" lf!3 i!I i!liillf "f"[j•ii'•• "'io 0~0~~2••-~~mi~ i:13g ] i;S'!t~! iJ;i ~ ~~.,N ~'f:Jam g'S. i " " I< • 8 ,. '8 s ., 5 }~~I iitt~ ~,1~ .:.:0 i~~~iii? !i2!!i ~ ! ~ :, :, ., g .. :, :, S' ~ 0 ~.~,1 !!!! .. ! .... i ! .. .. ., < i ;-::.. i .. ~ i ~ , • I 0 • i i ! • a I I I ! l If f H I I aafaaaaaaaaaaaa665 ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ! 0 s 666666666666~65665 ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ! z I zzzzzzzzzzzZZzzzzz ' ' ' ' s 000000000000000000 q.~ ~ - aaaaaaaa6aaaaaaaaE ' . ' ' ' ' ' i 666666666666666666 ' ' ' ' ' i --0 " z~z~zzzzzzzzzzzzzz ' ' ' ' ~· ' -' ~ 0~0~00000000000000 -. E ! z z • wo " 0 0 ' 666 a 66 6 66 6 66 6 66 a~~ ' r;:, ' ' ' o· •· t' ' ' ' ' ' ! zzz zzzzz zzzzz z z zz z w ~. ~' 0 ~· s 000 000 000 0 00 0 0000 0 ' ' ' R; ' ' ! • ! I f • • 3 I ie . " . . w· • i; oag .. i;;; <. - • -0 I ~ g-< ;;;[;' :11,.~2 ljii: i=l ~ ~ m~ • I i~~ g r .':' 3 ~ ~ ., 0 0 0 s zzzzzzzzzzzzzzzzzz ' ' ~· e, ' t?' ~· ' ' ' E 000000000000000000 ! • i~! ~ I ~ , ~ 66~6666666666666~6 ~ ' ~. 0 0 ' ' ' ' ' ' ' ' ~· g; ' ' § I b• "· 0 0 0 i 666 66 666 666 6 666 6 66 ' ' ' ' . ~· ~· ' ' ~· 00 0 0 " 66 566 666 aa aaeJ a 656 a ' ' E~C• ' ' ' ~· ' ~· ~:, §, ' ! I 666666666666666666 ' ' ' ' ' ' ' ' ' ;;:;, ' & I 0 ' 66lili66666666666666 ' ~· ' ' ' ' ' ' ' ,:, ! 666666666666666666 0 0 0 ~,:i ;;· t' ;;· ' ' ' ' ' ;; ' ' ' Hi· I aaaaaa5aaaaaaaaaaE 0 0 ' ' -' ~t ' ' ' ' .. ~ C I 0 -0 0 . i 66666666666666666~ ' <.n' ;;· ' ' ' E , g: : ' ' ' i;:' ' E' ' I I I I <.:C: r.:~'~' 6 6 z ±[ff J ±!f [i ~ ·: C.: [ 2 ~ !e. ~ 11.-t;:;; t n ;; i.: l =>' t .. o1 ::: .: f ~ f f ,:g,gtf . ~ 0 --.,, .. ,.i"""" . '12 66~ ~~,~~s-a1~~~~~s,~~66'f'' ~ ~ ~ ~ 11(~~.j l!!!fllcl • ;g~2xa ~¥s~ O · ~~i~~-,w~ ~~ ~~~~ "'oi~ 2~•-.~mo~ ~~ ~~ fl~ ~;I g 1~9 1§[ fg~ lti~~ 0 e D Q iii•1a•··•••I• l•i! &f~ =~; [ ~ ... i•Q ~i~ii~~~~ 2 I ~i ~•N ,."'9-0m 9-~ ~~2 ~ ~ ~&il i ~ [f'm~o• i D e ~ 1g2~~ ~ti11 ~fli NNO ~ .. ~ ~ 9 g ~'5-•a: !!:!!:2 " .sg~• • .. ·I .... · . f ·•p .... . -.. i !·· i ·i i ~~-. ti;! f g • •S 0 . . i ;s i ~ ~ . ' I n I ~ I • ! i ii I ! H ! I I I I zzzzzzzzzzzzzzzzz~ 0 0 ~ oooooooooooooooooE ' ' ' ' ' ' E' ' ' ~· ' ' ' ' ' ij w s 66a6aaaaaa66~66666 ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' § z I zzzzzzzzzzzzzzzzzz 0 § 000000000000000000 ' ~· ' ' ' ' ' ' ~;::: ~ ' [-= I,. 666666666666666666 ' ' ' ' ' ~ zzzzzzzzzzzzzzzzzz 0 0 s 0000000~0000000000 ' ' ' ' ' ' ' ' ' g; : E ~ 0 0 0 • 66f~6aaaaaaaa6a6aa ' t' ' ' ' ' ' ' .. ' -e ! . -z • 0 -~ 666 666 666 6 66 66 6 66 ~ ' ' ' ' . ' ' ' ' ' ... ' ' ' ' ' ! zzzzzzzzzzzzzzzzzz ' ' ' ' ' i;;' ' ' s 00 000 0 00 0 000 00 000 0 ~ j I ~ " • 3 :.~ I -~ -~ ~-~. o•g s. ii ; g~ I ;. !'! E ~ :u ;i:: -!Z Ii:~ -:i. .. 0.? ~ t'. c=;r:u :;:,g ! I i' ~ ii •m !i· --3 • 3 , . -~ 666666666666666666 ' ' ' ' ' ' -' I t' o•• .,, ! :f; 2) ..... 66~666666666666666 -0 0 ' ' ' ' ' ' ' ' ' ' ' :..' ;;· ;;· ! l I • ~ ~ I 666666666666666666 ;;, ~ ' ' • ' ' ' ' ' ' ' § I 0 0 0 0 0 ! 666~6666666666666~ ' ' ' ' ' ' ' ~--' ' -, ' ' ' ' ' ' ~ • ~ Z C • 0 -0 • 66666666666666666~ ' ' ' ' "'@:: ;;, ' ' ' ;;; ' ' i I 666666666666666666 ' ' ' ' ' ' -' 0 ' ' s ;., ~ ~ I 0 ~' ~ 0 ' 666666666666666~66 ' ' ' ' ' ' ' ' ' ' ~· i i:H ·-• -0 0 ' ' 66666~666~6666666t E' ' ' ' i:;, ' ' r, ' ' ' ~· ' ' ! I ,, -0 0 ~ 666666666666666666 ' ' ' ' ' ' ' io i ' ' ' ' ' ' E' t § I 0 ?P 0 0 ! 6a;~66666666666666 EE' ' ' ' t: I ' ' 1:::: ' ' ' ~t ' e z • I I Z Z Z Z Z·z Z Z Z Z Z Z Z Z Z Z Z Z 000 000 0000 00 0 00 0 0 0 zz~zzzzzzzzzzzzzzz 00~000000000000000 z z zzz zz z z zz zzz zz zz 000 0 00 0000 00 0 DO O O 0 0 zzzzzzzzzzzzzzz~zz 000000000000000~00 : I I ! , , , , , , , , , , , 0 , E, 0 ! § I 0 I~ l Pe , ~~· 0 , t' , , , 0 E' , , , , 0 , , §' , , , , ~, , 0 , ~~' 0 , , ~' , , ;.!~ L , , , , , , 0 , , §' , , 0 ' ~ : ' I I I I 0 : ~ t I ! ! I ! I I 0 e ! I l 1 I ~ I , , , t ; I I l I 1 I i 0 'e , ;: I , , , , i i I ~ 0 • 3 I i e , " -. w· •• cag • g; •--~iff3 I $.!'!l-' ::uf-<2: 2-. -Cl n ;, ~ Q.-='" !. "" ti r ::u mo: I i!~ gg, .":' 3 • 3 .. , -, , , , , , , , , , s C ~ ., l I • ~ , ~ 9 a, -0 0 :1 2! , t~e· §. §' , , , , , , 0 0 0 • , f' ;, E: E' , , , , ! 0 s , , , e· , , , , , , , , , § ,1 I 0 0 0 0 i , E ~ : , , i'' , , , , e • I ~ , , , , , , , , , , § s , , , , , , , , , , , , § I , , 0 ~ , , , , , , , , , , ~ L I • ii. 0 lo!. i 0 , , , E' , , , , , , § , , , , , , , , I I B , , , , , , i I B . I ! ' ;! , ~00000000000000000 ' ' ' ' ' ' •• ' ' .~ ' ' ' ' ' ' ' ' ' ' • 0 _;Z ZZ Z ZZ ZZ Z ZZZ Z Z Z Z Z I ' ' ' ' ' ' ' ' ' ' ' ' ' ' .~ ' ' ' ' ' ' ' ' ' ' 000000000000000000 0 z zzz zzz z z z zzz zz zzz I iu~ ' ' ' ' ' ' ' ' ' ' ' .~ ' ' ' ' ' ' ' 000000000000000~00 !iNQi 0 zzzzzzzzzzzzzzzNzz I § ' il m ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ·~ ' ' ' 000000000000000000 § zz zz z z z z z z z:z:z zz zzz 0 0 ~ ' ' ' ' ' ' ' ' ' ' ' ' .~ ' ' ' ' ' ' ' ' ' ' ~@@@@@@@@@@@@@@j@@ s 0 0 1. I ,m , ' ' ' ' ' ' ' ' '" e ,g:6 ' ,3 g@@~@~@@@@g@ii@@ii ' ' ' ' ' ' ,. ' 0 0 ci ~ 0 N 0 I ~~H .~ .~ ZZz ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ~@@i~~@@@@@@~@~g~g 0 0 OON § , @@@@@@@@@i@@@@i~@@ ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' '" ' ' ' ' ' ' • 0 •· ! ' ' ·~ ' ' ' ' ' ' ,N ' ' ' ,::; ' ' ' ' ,: ' ' ' ' 0 00 000 00 000 000 00 0 0 • ' zz z z zz zzz z zz zzz zzz I ~ < 1 l •• ~ ' ' ' ' ' ' ' ' ' I~ ' ' . ' ' ' 000000000000000000 i; ' ' '6 ' zzzz zz z zz z zz zzz zzz ! ' ' ' ' ' ' ' ' ' ' I~ e ' ' ' @@@@@ @@@@@@@@@ ~n~ @@ • ' ' ' , :; ' I p E;.; oo •& ~-~ oo< c,t j :.a I I~ ,;! , ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' I ~ ' ' ' ' ' ' ,, @i@@@@j@@@@@@@@@@@ 0 0 0 : ~w ••" ,. ii .c ~- I ~ i ~ ~ !J~i ~ g Q. o•• -• > • B • I ie 0 ~. -~ . . ". •! § ' ' ' ' ' ' ' ' ' ' ' ' ' ,::] ' ' " ' ' ' ' 000000000000000000 s -zzz zzz z :z: z zz z zzz zzz § ' ' ' ' ' ' ' ' ' ' .~ 1::; ' ' ' ,: ' ' ' ' Mooooooooooooooooo • 0 ..: zz zzz z z z zzz zzz zzz I ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' .~ ' ' ' ' ~i@@@@i@@@@@i@i@@i 0 - E i I • • ¼ 11 , oaoooooooooooooaoo ' ' ' ' ' .~ ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' • 0 zzz z zz zz z:zz z zzz zzz ~ ' ' ' ' ' ' .~ ' ' ' ' ' ' ' ' ' ' ' ' ,c ' ' ' ' ' 3@@iiiiiiiiiiiiiii •• 0 0 I c§~ "! ~ m .~ ¥ a ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ,_ ' ' ' ' aa oo a oo a oo a oo ooa oo s 0 0 zzz :zzz :z z z :z zz zzz zzz 0 I ~ ' ' ' ' ' ' .~ ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' 00 00 0 00 00 0 000 00 0 00 s 0 zzzzzz:zzzzzzzzzzzz ~ ' ' ,c ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ~i-iiiiiiiiiiiiiiii • 0 I I u j H t ! 0 I ' ! • i ! ! 8 • I I t ii: • ! 5[ 0 .. 5. . £ .. ! > • • ' -' "'5 ti E !a'., .... Q :: i~ ., .. 8i ; .... ~~~ ~~-~ !8}§~ " ; i :,,,:; ! i '!'~ ' ••• j~:. ~I~~~ r~ &§ ~ .... {i .. ~w~,Sl!e g •!I "'t "" iii •• 6 •"" ·,818 !l~>fi w2£M_..;._ . N~ ~j!i SOjf~eti~~~ l!ie~JtJ~ ii!E~t~ fui~ ~}~~~~g-9a~ u ~j§l!•~~o,:.~.2i~~ ~~ .. ~1~~ ~ .. ~~>of-:l!~ •!'"•]"-'• .!,,gpj ~ tiij5515ii-~510,f-;~~ 5~5~<:~]X~~iM --"<: ~Cij<=J'!o,o,~ • C i"" ~~;1t ~r~-~ i;~f\ ~ ~ !{~~ ti!:;i ~i~ ~ ~i~ ~C~8i·f~N~ia~ 22ttt ::,. i, ,n -,, --',n -,., -:::; -ui.: <D ---:i :g:;?:; ir: .i3 l l ! z ~-2~ .~.~::i ~:.> I D I I ' ' I I I I ~ I < i ~ ,. .. E • I §§ 0. §;~ ii~ l~~~ I ·~· a !l •::li:g: I-~;.;'£ 08• ... 'e!~ I 3 ~c ~~ " -~i I • I 0 i I I I I I I I ~ m ~ : ~ • .~ ~ c:i 0 0 ·~ ·~ ·I @gggggggggggggg3gg i ~ .~ ~ .~ <i ·I 000000000000000000 ,, • • 0 0 0 0 zzzzzzzzzzzzzzzzzz H ·~ ' ' , .. ,~.re.~ ,: ':;; I t I 1 I ·I ~00000000000000000 ci ci 0 ~zzzzzzzzzzzzzzzzz ~ :~ H m ~ ~ ~ " ~ ' I: : I ! "':"': ... ·~ ': ' ' ' ' I •I ggg g i gg ggg gg g gg gg g 0 ci O ci § '~ m " I~ : ~ ·~ ':;; I ' I ·I @@@ @@ @@ @@@@@@@i gg g ~ 0 0 0 i ! I I I I I I~ : ~ I~ I I 1 I I:;:; I I I I I I gggg~i@@gggggigggg • 0 0 i .~~ z I ! t I I ! I I @££££@~£@@@@@@@@~@ c:i ci C ~ • ~ " ·~ ' il 0 ggg g g gg ggggg g gg gg g ; "~ I! t ~ .:_ ' ' I : C I I I g 0 3@@ fVil !Vil@@@@@@@@@@@ ~ § ,g 0 .~ 0 gggggggggggggggggg -§ ~ .~ 0 I I I I : .~ goooaooaoooaoooooo 0 zzzzzzzzzzzzzzzzz -! ·~ : ~I::;; : ~ " z .~ @@@@@@@@@@@@@ij@~@@ 0 0 -~ s ·~ " coo o a 00000 oo a oo oo o I : I~ :N 0 zzzzzzzzzzzzzzzzzz -=" • § 1~·;t ~ C -0 3 " ,::; ;a ~ ~"' '; :dci"' '~ : ~ " .~ 0 ·~ ~a., ' "' -. ~ ooc .~ 0 222 2 2 22 222 22 2 22~2 2 22@~2~~2222222222@ I -----r ! 1 I 1· : j • t ~ 1l •~:~,~ ·~ " ',;;' ' ' ' 0 z z •I ~22~2~222222222@@@ 0 ~ Ii i l -u • • § ~ J I f " • • 0 >' t· • "-•· •· l • ,.,a ·• . o ••••• =i. · •Iii •• ;: • -~.. 8 1,,! ,}i•!iil! ! J.iJ~i ' 11:il!~ tf;gg !.ill 1111 l~llllllri 111.,'l•II 1,,, ~1i•1111 ~1•~~-.. 1t!~II ·11···• -·•·0•·••1• 11• '" !•I~ ,. I ---;§6' •"ii! l61~lffll~~i~flJ~l~l1~i~llf:1~!!i!1iiJlill!tllll11~ ~~::i. u. o..~ ~,.,:,.,:_,_,_,,,.,,,,_,~_ : ' ' I , ' , . ' ! i ,. ~i f .i-ll " " .~ •• i ·1'l P •••1·• ! • si .,, !!? .s ! ~l ti i !l5A1 -: ia. 'a i ~~•i ~p! d •11"Zi.l ~-II ,e~ a. r5ir o.[jj , •• ,2~ !H i.1id,U lHHn .. 1,n,. d•P•l :& ~~!A2 !•:!211. q:·1i,,q -,·fl!:!! !!' E..i~lll !·a.ri ll.l!~:i~i i ~j[f2,-l ,5 -.z:::i zloJ,~ i s ; I ' i i § I I I ~~~lJHfilHfi{Hlf §'[ ~f!lit~~~-Ef~; ::~&> ff';f~f sx ~,.~f~~,~s•a~ ii~ t '!.~~~!i lll~ . J·•••l·•• · n f H i iii'!~ f;~ -,: O••o 011•!6••·,,•f" i;1! ' •f h ·[ X q, • 1 ii1 ~ ~-~ ~~~ ; 5'~ & ~ ~xj!• s ' i~~ • 5' ... 11~~ iili~ ~1~1 "'"8§.,"'•~ ~ i ~ . ' ~ ' ii ••f" -·~ i ., .. < i ~ ;i ~!1 ~ i a: ~ ~ ~ ' • I f I I I ~ I • ' C l ~ I H ~ ! 666666666666666666 !: ' t> ' ' ' ' ' ' ' ' ' ' ' ' ' ' § I • I • F • • ~ 3 zzzzzzzzzzzzzzzzzz ' ' ' ' ' ' ~. ' ' ' ' ' s 0000Cl O 0000 0 00 0 0 0 0 0 o' ~ l,r I , . -. 0 ► § • 0 ~· ~· 0 g 66666666666666666~ ' ' ' ' ' ' ' ' 2' ' ' ij C" f :U;: 66666666666666666f ~ ' t, 0 ~ ' ' ' ' ' ' ' ~' ' ' ! ag ~i .c ga I ~r I! . . 666666666666666666 ~· t ' ' ' ' ' § t• '@ ~ I ~~ "• 8" .. 3 6~6666666666666666 :, C~• 0 I ' ' ' ' t' ' ' 666666666666666666 0 r ~ ' i1' ' ' ' ' ' ' ' ' ! 666666666666666666 0 0 £ d-f ' ,,, ' ' ' ' e' ' ' ' ' fi l'. e' 0 0 0 I 66666666666666666~ ' ~· ' ' ' ' ~· ' ' • 3 , . "• ~ I • ~ , I I 666666666666666666 oO "· !": ' ' ' ' 8E' ' ' ' ' ' ' ' s· ' -1hf ~zz~zaaaa~Eazzzzzz 00 0 P• ~00 0 000000 ' ~~· ~· ' ' ' ' ' ' ' ' ':_: I z ,z • 666666666666666666 Oo 0 ~· E;: ' ' !~' ' ' ~· ' ' ' §;. f ---b~~~• 1•~ 666666~~~66666666~ ' ' ' ~· ' ' ~ ' ' ~· ' ~· ' i zzz I I D B I I C> CJ ◊ <) 0 <> \) <:::;, 0 \) <:::;, <:::;, <> <> 0 \) D \) \) ® i\ G ◊ ~p 1~ 0 0 ~ 0 CJ I ~ D i\ Q"' ® Q L~~\ \\ "'==d\=~~;;;: -;\ 0 □-o-= a 7' a □□ oo □□□ 0 sPRN smEET 0 0 D 0 \\® D □ 0 o I] i "'i\ 0 0 0 CJ (.,J Q 0 "i 0 0 I N----.---1---------t 0 □ DAVIS PARK ROAD TCE SITE GASTONIA, GASTON COUNTY, NORTH CAROLINA TCE CONCENTRATIONS IN GROUNDWATER FEBRUARY 2004 0 D [j' ! □ 0 oo 0 D I □ □ i □ D i □ D Ci D □ D □ D □ D 'i) D OD D D ---· -· -· DRAWN: DATE: J. MILLER 6/5/02 LAYOUT: CADD FILE: - APRVD. DATE: REVISION Fi -3-2 DA~SPARK.dw 0 0.¢.y' ~ ~ " ~ 3,',,MJ (]l:tO:il'INH - -♦ z z --!!l .9 ~ ~ z z ~ 0 " r ... :i: r i 0 r r 0 0 ~ ,, " 0 ~ ~ " ~ 2 0 ~ r m m z G') m " m 0 z z " CJ m ~ i z ~ W.0. NO.· 20064-138-100-0930 SHEET: DF .. C> CJ ◊ <) 0 ◊ \) \) \> 0 0 \) \) \> \) \> ® i\ ~· D ~ -.,\ p ·--~ u 0 CJ 0 \\® D 0 D 0 o ·◊ D D D o o 0 D '· 0 0 (,J I N----+---+---------1 N APRVD. DATE: REVISION D □ DAVIS PARK ROAD TCE SITE GASTONIA, GASTON COUNTY, NORTH CAROLINA PCE CONCENTRATIONS IN GROUNDWATER FEBRUARY 2004 -.. , 11111) lllliill! liiiiil; -····-· .' .. C/l 0 ◊ 0 0 0 G = 0 IT I □ 0 ·o D I □ D I □ D I □ D D Ci D D 0 D □ D 'i) D Do D 3MKl O'ttCl:!..Urt'H D ------ * z z ,!? 9 i ~ z z "'l 0 .... ..., .... ~ 0 .... i :,: 8 .... ~ 0 ~ ~ 0 r ~ z m G) m m z m z 0 0 ~ 0 m ~ i z f DRA'Af\J: DATE: W.O. NO.: J. MILLER 6/5/02 20064-138-100-0930 LAYOUT-CADD FILE: SHEET: OF Fi -3-3 DA~SPARK.dw D m I m I I I I I I I I I I I I I I .I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written pemiission of EPA. February 2004 Semiannual Sampling Event Report Davis Park Road TCE Site Section: 3 Revision: O Date: April 2004 MW-3, MW-8, MW-10, and MW-11). Low levels ofTCE and trace PCE were also continned in groundwater samples from monitor well MW-21 (located between the former contaminant plume and the currently pumping community wells. No PCE or TCE was detected in monitor well MW-20, located north of MW-21. Trace concentrations ofTCE and PCE continue to be detected in private well MW-19 located at the south-southwestern portion of the site. 3.4 PASSIVE DU'FUSION BAG SAMPLERS Low-flow techniques were used to sample the seven directly accessed wells at the Davis Park Road Site for first through fourth quarters of the LTRA. Although minimizing purge water when compared to traditional purges of at least 3 well volumes, the low-flow sampling technique still produced approximately 55 gallons of purge water and decontamination fluids per sampling event. Additionally, trnnsporting sampling equipment and contained purge water through residents' yards, as well as staging, sampling, and arranging for transport and disposal of the purge water following each sampling event presented new challenges with every sampling event. It was recommended that PDB samplers replace low-flow groundwater sampling procedures for the Davis Park Road TCE Site LTRA sampling events to maximize sampling efficiency, minimize inconvenience to residents, and eliminate the need to contain, sample, and dispose of purge water. During the August 2003 sampling event, the seven directly accessed wells were sampled both using low-flow methods and PDB samplers. Results are discussed in the August 2003 Semiannual Sampling Event Report. Monitor wells MW-20 and MW-21 were installed during the August sampling event and were not equipped with PDB samplers prior to groundwater sampling. To verify that the PDB samplers are appropriate for LTRA monitoring in these two wells, they were sampled using both low-flow methods and PDB samplers during the February 2004 sampling event. K:\200641138\Second Semiannual\F eb04Semiannua1Rpt. doc 3-23 RFW138-2A-APIM D I I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed. in whole or in part;'Nithout the express written permission of EPA. 3.4.1 Methodology February 2004 Semiannual Sampling Event Rep:,rt Davis Park Road TCE Site Section: 3 Revision: O Date: April 2004 Both MW-20 and MW-21 were constructed with IO feet of open corehole at the base. In order to assess potential stratification of COCs within the IO foot corehole, one PDB sampler was placed in the top 5 feet and one PDB sampler was placed in the lower 5 feet of the open corehole of each well (see Table 3-1 ). Assemblies for the PDBs were prepared prior to mobilization to the site and stored in plastic bags. Stainless steel weights were attached to braided polypropylene ropes that measured the length of each of the monitor wells. Hanger assemblies to·which PDBs in protective mesh could easily be attached, were placed at th_e selected depths (calculated from the bottom of the well) along each of the polypropylene ropes. Each well was provided a locking cap to which the ropes could easily be attached. Three weeks prior to a scheduled sampling event, PDBs were attached to the polypropylene ropes and placed down the two newly installed bedrock monitor wells. Samplers were approximately 18 inches in length and filled with approximately 200 milliliters of deionized water, sealed with no visible air bubbles, and connected to the rope at_ the appropriate attachment. Following a three-week period, each of the PDBs was pulled and pierced with a small discharge tube which allowed the transfer of the groundwater to 40 milliliter septa vials that contained hydrochloric acid preservative. Following collection of the PDB samples, a sample was collected from the well using low-flow techniques as described in Section 3.1. I of this report. All samples were placed on ice prior to shipment under CLP protocol to A4 Scientific, located in The Woodlands, Texas, for VOC analysis using EPA Method 8260. K:120064\138\Second Semiannual\Feb04Semiannua1Rpt.doc 3-24 RFW138-2A·APIM I I I I I I I I I I I I I I .I I I This document was preP8red by Weston Solutions, Inc., expressly for EPA. II shall not be disclosed, in whole or in part, without the express wtitten permission of EPA. 3.4.2 Comparison with Low-Flow Samples February 2004 Semiannual Sampling Event Report Davis Park Road TCE Site Section: 3 Revision: O Date: April 2004 Laboratory analytical results for low-flow and PDB samples are summarized in Table 3-5. Laboratory analytical reports are included in Appendix B. TCE, reported in groundwater sampled from MW-I at levels below the ROD Remediation Goal of 2.8 µg/1, was the only COC (other than MTB.E) detected at levels above the reporting limit in both low-flow and PDB samples. PDB results from both depths sampled were identical (0.90 µg/1), indicating no significant vertical stratification of COCs within the IO foot corehole interval. Additionally, the relative percent difference between PDB and low-flow sample results for TCE is I. I, indicating good correlation between PDB and low-flow sampling techniques. PCE was detected in MW-21 at estimated concentrations below the reporting limit in the low- flow and both PDB samplers, indicating good correlation between the two sampling methods, even at these low concentrations. However, I, 1-DCE was detected in MW-21 at estimated concentrations below the reporting limit in both PDB samplers, but not in the low-flow sample. In general, when low level COCs (i.e., below the reporting limit) have been reported, they have been detected in samples collected using both PDBs and low-flow methods. This exception may indicate that this constituent is present at levels approximating the laboratory analytical detection limit. With the exception of MTBE, no other COCs were detected in either the PDB or low-flow samples collected from MW-20 and MW-21. MTBE was detected in both MW-20 and MW-21, in low-flow and PDB samples. As with previous sampling for this constituent, the PDB results equal approximately 25 percent of the low-flow sample concentration. While PDBs will not provide replicate samples for low-flow sampling of this constituent, MTBE has historically never occurred at levels exceeding the ROD Remediation Goal. If MTBE concentrations were to suddenly rise significantly, it would likely K:\20064\138\Second Semiannual\Feb04SemiannuatRpt doc 3-25 RFW138-2A·APIM D 0 D I I I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. Table 3-5 Laboratory Analytical Results Summary Low Flow Purging vs. Passive Diffusion Bag Samplers February 2004 Davis Park Road TCE Site Sample Location: MW-20 Lendora Drive Location Address: (north of Skyland) Sampling Method: Elevation of Sample Depth (ft msl): Sample Collection Depth (ft btoc): Date Sampled: Volatile Organic Compounds {ug/1) Chloromethane 1, 1-Dichloroethene !Acetone Cyclohexane Melhyl T-Butyl Ether (MTBE) Methyl Ethyl Ketone (MEK) 1, 1, 1-T richloroethane Toluene Ethylbenzene Total Xylenes T richloroethene T etrachloroethene Notes: Only constituents that were detected in at least one sample are included in this table J indicates estimated value Samples were analyzed following CLP protocol. µg/1 = micrograms per liter ft btoc = feet below top of casing ft msl = feet above mean sea level --= not detected (<0.50 µg/1) PDB = passive diffusion bag B indicates constituent was also detected in blank{s) low flow 170 -- -- -- -- 84 -- -- 0.42JB 0.31J 0.48J -- -- K:\20064\J 38\Second Semiannual\Feb04Semiannual Rpt-1bls.xls 3-26 PDB PDB 165 170 2/5/04 -- -- ---- 16 13 0.14J -- 23 22 11 8.8 ---- 0.49JB 0.44JB 0.27J 0.26J 0.40J 0.39J ---- -- -- MW-21 Lendora Drive (south of Skyland) low flow PDB PDB 132 127 132 2/4/04 --0.19JB -- --0.35J 0.34J 28J 13 12J ---- -- 2.6 0.64 0.62 6.2 8.8 7.7 --0.27J 0.31J 1.1B 1.0B 1-1B 0.48J 0.38J 0.38J 2.0 1.6 1.5 0.91 0.90 0.90 0.35J 0.26J 0.25J D u I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written pennission of EPA. February 2004 Semiannual Sampling Event Re(X)rt Davis Park Road TCE Site Section: 3 Revision: o Date: April 2004 be the result of an unrelated source release, but the use of PDB samplers at the site would have to be reconsidered. Toluene, ethylbenzene, and xylenes were detected at estimated concentrations below the reporting limit in groundwater sampled from MW-20 in the low-flow and both PDB samplers. Ethylbenzene was also detected at an estimated concentration below the reporting limit in groundwater sampled from MW-21 m the low-flow and both PDB samplers. Toluene was detected in both the low-flow and PDB sampler for MW-21 at low levels, with an average relative percent difference of 4.8. Xylenes were also detected in both the low-flow and PDB sampler for MW-21 at low levels, with an average relative percent difference of 25.4. The low level detection of these constituents in PDB and low-flow samples provides additional support for the use of PDB samplers as a valid replacement for the low-flow sampling technique at this site Acetone and methyl ethyl ketone were detected in PDBs from both wells MW-20 and MW-21, and also in the low-flow sample collected from MW-21. The diffusion sampler method is not considered appropriate for accurately characterizing the presence of acetone and methyl ethyl ketone, organic compounds with high aqueous solubiliiy. Both acetone and methyl ethyl ketone were detected in all PDB samples. Their ubiquitous occurrence in these samples may be due in part to laboratory contamination, either during analysis, or in preparation of the deionized water used in the PDB samplers. However, neither constituent was detected in the trip, equipment, or field blank. Levels detected are well below guidance concentrations (the NCDENR standards are 700 µg/1 and 170 µg/1 for acetone and methyl ethyl ketone, respectively; acetone and methyl ethyl ketone are not listed in EPA drinking water regulations) and neither is considered a COC for the Davis Park Road TCE site. As with MTBE, if concentrations were to suddenly rise significantly, it would likely be the result of an unrelated source release, and the use of PDB samplers at the site would have to be reconsidered. Additionally, a different laboratory batch of K:\20064\ 138\Second Semiannual\Feb04Semiannua1Rpt.doc 3-27 RFW138-2A·APIM I u D I I D 6 I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. February 2004 Semiannual Sampling Event Report Davis Park Road TCE Site Section: 3 Revision: O Date: April 2004 deionized water will be used to fill the PDB samplers for the 2nd semiannual, third year L TRA sampling event (first semiannual, third year L TRA PDB samplers have already been placed down hole). K.\200641138\Second Semiannuaf\Feb04Semiannua1Rpt.cloc 3-28 RFW138-2A-APIM I I I .'- . ,- } -·.-·,, I . , • 1. . , .. . ' , -I ;,..- I . ,. ,· DI ur-1 1n 11"1 I] 11 (I .:-1 -I] 1:1 ll 11 1.J IJ IJ I 1J 11 IJ I iJ I This document was prepared by Weston Solutions. Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. SECTION 4 February 2004 Semiannual Sampling Event Report Davis Park Road TCE Site Section: 4 Revision: O Dale: April 2004 CONCLUSIONS AND RECOMMENDATIONS 4.1 LTRA RESULTS SUMMARY The source for the TCE/PCE contamination in groundwater at the Davis Park Road TCE Site is depleted or removed hased on groundwater sampling results reported from the time of contaminant discovery ( 1990) to the current LTRA second semiannual sampling event in February 2004. Water sampled from wells north of Skyland Drive (MW-5, MW-14) and in the Cedar Oak Circle Subdivision (MW-12) contained concentrations of between 44 and 134 µg/1 TCE and up to 24 µg/1 PCE when sampled in 1990. Water sampled from these MW-5 and MW- 14 in February 2004 did not contain concentrations ofTCE or PCE at concentrations greater than the ROD remediation goals of 2.8 ~tg/1 and I µg/1, respectively. Water sampled from MW-12 contained TCE at 3.5 µg/1 and PCE at 1.4 µg/1 (see figures 4-1 through 4-3). Although TCE and PCE concentrations in some wells located south and west of the source area have slightly increased, contaminant concentrations are significantly lower than those detected in the source area at the time of the initial discovery in all but one well location. Groundwater sampled from monitor well MW-I 5, located southwest of the source area, contained 50 µg/1 TCE during the current sampling event. Excluding this groundwater sample, the maximum TCE concentration for groundwater samples collected this sampling event is 17 µg/1 in groundwater sampled from well MW-17. The maximum PCE concentration is 9.9 µg/1 in groundwater sampled from well MW-I 8. Both wells MW-17 and MW-I 8 are located on the south and · southeast portion of the site approaching Blackwood Creek, suggesting groundwater K:\200641138\Second Semiannual\F eb04SemiannuatRp1. doc 4-1 RFW138-2A-APIM - - -- --- -- - -- -- ---1!!11!1 -'a, ~ Q) C Q) ~ -Q) 0 ~ 0 :c u ·;: I- 1000 100 10 r-r r· l Figure 4-1 Trichloroethene Concentration vs. Time 2419 Davis Park Road, MW-5 Davis Park Road TCE Site Gastonia, North Carolina .-------------------------------------------------------------------------------- (ROD Remediation Goal = 2.8 µg/I) 0.1 L, --~--~--~--~--~--~---~--~--~--~----,----~--~- Feb-90 Mar-91 Mar-92 Apr-93 May-94 Jun-95 Jul-96 Aug-97 Aug-98 Sep-99 Oct-00 Nov-01 Dec-02 Dec-03 Date K:\20064\ 138\ Third Ouarter\table_figures.xls\fig4-1 -- - -- - - 100 10 -'§, I ~ ., C: ., r. - -- -- - Figure 4-2 Trichloroethene Concentration vs. Time 2403 Davis Park Road, MW-14 Davis Park Road TCE Site Gastonia, North Carolina - --- - ., -----------------------------------------------------------------------------------------------------------------· 0 ~ 0 :c " ·;: I- ' [ 0.1 Feb-90 Mar-91 (ROD Remediation Goal = 2.8 µg/1) Mar-92 Apr-93 May-94 Jun-95 Jul-96 Note: Non-Detect in Jan. 1998 reported as 2.5 ug/I (half the deletion limit) K:\20064\ 138\Third Quarter\tabte_ligures.xls\fig4-2 Aug-97 Date Aug-98 Sep-99 Oct-00 Nov-01 Dec-02 Dec-03 l!!!!l!!!I -- - -- - -- -- - -- - 100 Figure 4-3 Trichloroethene and Tetrachloroethene Concentration vs. Time 2719 Davis Park Road, MW-12 Davis Park Road TCE Site Gastonia, North Carolina ♦ -10 f ~ [ Q) C Q) .s:: -Q) 0 ~ ..5! .s:: 0 ·.: I- I 0.1 • ♦ ... . ' . . .. . . . ~-•······· .. ···· .. ·-♦•• .. ·•. ♦ ---------------------------------------------------------(ROD Remediation Goal for TCE = 2.8 µg/1) ·•. (ROD Remediation Goal for PCE = 1 µg/1) • '' '• ♦ I!!!!!!!!!! • .. ... Feb·90 Mar·91 Mar•92 Apr·93 May-94 Jun·95 JuI•96 Aug•97 Aug·98 Sep-99 Oct•00 Nov•01 Dec·02 Dec·03 Date K:\20064\ 138\Third Ouarter\table_ligures.xls\lig4-3 l!!!!I l!!!!!!!I I .. -♦ .. PCE I ■ TCE m 1:1 1:·1 1:·1 ,:~1 11 11 1] 1: I 1: I ,1 11 1'.l 11 1-' 1J 11 11 iJ This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. February 2004 Semiannual Sampling Event Report Davis Park Road TCE Site Section: 4 Revision: O Date: April 2004 contamination continues to attenuate as it migrates toward this natural groundwater discharge area. Concurrently with the migration toward Blackwood Creek, there appears to be contaminant migration southwest of the source area, as evidenced by groundwater elevations and the detection of trace TCE and PCE concentrations in this area where previously there was none. · Although pumping of groundwater has been discontinued over most of the Davis Park Road TCE Site area, two community wells (MW-10 and MW-! I) are currently still active near Briar Oak Drive, west of the site. Community well MW-I 0, located on Skyland Drive, supplies between 30 and 40 people, and MW-I I, located on Briar Oak Drive, supplies approximately nine people, according to Mr. Doc Thompson of the Gaston County Health Department. Pumping of these wells may facilitate migration of groundwater contaminants in a westerly direction. Two monitor wells (MW-20 and MW-21) were recently installed and sampled in the area between the contaminant plume and the community wells. Currently there are low levels of TCE and trace levels of PCE in groundwater sampled from MW-21, the well located between MW-15 (the well with the highest TCE concentration) and the currently pumping community wells. The data from sampling of wells MW-20 and MW-21 should provide sufficient warning that COCs in groundwater are migrating toward the pumping wells at concentrations exceeding the ROD guidance concentrations, should this occur. Monitor well MW-15 is located southwest of the source area, with Davis Park Road to the cast and well MW-9 to the southwest. Concentrations of TCE detected in monitor well MW-15 have nuctuated between 36 µg/1 and 50 ~tg/1 since September 2002, similar to historical levels detected in groundwater sampled from converted community well MW-12 (located east and downgradient of the source area) (see Figures 4-3 and 4-4). TCE conceillrations nuctuated between ·approximately 30 and 50 µg/1 in groundwater sampled from M\v-12 from 1990 through 1998. TCE was detected at 3.5 µg/1 in groundwater sampled from MW-12 during .this groundwater sampling event. TCE concentrations in groundwater sampled from well MW-9 (currently supplied with a carbon filtration unit) have nuctuated since August 2000 when first K:120064\138\Second Semiannual\Feb04Semiannua1Rp1 doc 4-5 RFW138-2A-APIM --1!!!!11!1 1!!!!11!1 l!!!!!!I 100 10 •.. !!!!!!!I l!!l!l!!!!I l!!!!l!!!!I I!!!!!! !!!!I !!!!I I!!!!! I!!!!! Figure 4-4 Trichloroethene and Tetrachloroethene Concentration vs. Time 2232 Tate Street, MW-15 Davis Park Road TCE Site Gastonia, North Carolina (ROD Remediation Goal for TCE = 2.8 µg/1) (ROD Remediation Goal for PCE = 1 µgil). · • • ••. . ... _ l!!!!!I l!!!!!I •.. . ..• 0.1 !-. ---~---~~---~---~---~---~---~----,-------,------, Jan-98 Aug-98 Apr-99 Nov-99 Jul-00 Feb-01 Oct-01 Jun-02 Jan-03 Sep-03 Apr-04 Note: PCE Non-Detect in Feb. 1998 reported as 2.5 µg/I (half the deletion limit) Date PCE Non-Detect in Mar. 2003 reported as 1.0 µg/I (half the detection limit) K:\20064\ 138\ Third Ouarter\table_tigures.xls\fig4-4 gl u:·1 o:I u:I lfl El 11 1:J 1:·1 , I I ,1 tl ., 11 11 1.l I ) ' i 1J 1J This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. February 2004 Semiannual Sampling Event Report Davis Park Road TCE Site Section: 4 Revision: O Date: April 2004 sampled, but have ranged from 6.8 µg/1 (detected in November 2001) to 16 µg/1 (detected in March 2003). These levels are similar to groundwater samples collected from wells MW-17 and MW-I 8, located further south and downgradient of the source area toward Blackwood Creek (see Figures 4-4 through 4-7). 4.2 CONCLUSIONS TCE and PCE concentrations continue to decrease in the contaminant plume as it migrates south and away from the source area. No additional degradation products of these two constituents were detected at any significant level in any of the groundwater samples collected historically or during the LTRA quarterly/semiannual sampling events. Graphs of historical TCE and PCE concentrations from key monitor wells are presented as Figures 4-1 through 4-7. Figures 4-1 through 4-3 shows the decline of COCs in groundwater sampled near the original plume center from levels well above EPA MCLs to levels either approaching or consistently below the MCLs and ROD Remediation Goals from 1990 through the current sampling event. Figures 4-4 through 4-7 illustrate the fluctuating COC levels in wells located at and downgradient of the current plume center. These values are significantly lower than levels detected at the plume center in the early 1990s, following discovery of the plume. Figures 4-1 through 4-7 support the groundwater concept model (EPA Memorandum, 25 September 2000) that the primary mechanism for the observed natural attenuation of the TCE plume at Davis Park Road is dilution as contamination essentially flushes through the bedrock aquifer. The analytical results are consistent with the proposed cleanup time of I 3 years (by the year 20 I 7) to altain EPA MCLs. '· . In conclusion, the February 2004 Semiannual LTRA sampling event results confirmed that natural attenuation is occurring at rates according to expectations, no changing conditions have K: \200641138\Second Semiannual\F eb04 SamiannualRp1. doc 4-7 RFW138·2A-APIM - - - -- - - - - -- -- - Figure 4-5 Trichloroethene and Tetrachloroethene Concentration vs. Time 2639 Springbrook Street, MW-9 Davis Park Road TCE Site Gastonia, North Carolina 10 t ___________________________________________________ _ (ROD Remediation Goal for TCE = 2.8 µg/I) (ROD Remediation Goal for PCE = 1 µg/I) . •· .... •···•······•······•·····•······•··········•·· 0.1 Jun·00 Oct·00 Feb·01 Jun•01 OC1·01 Feb·02 Jun•02 Date Note: TCE Non-Detect in August 2003 reported as 2.5 µg/1 (half the detection limit) K:\20064\ 138\Third Ouarter\table_figures.xls\fig4-5 •. ♦• •...•.. Ocl·02 Feb·03 Jun·03 -l!!!!!I l!!!!!I == . .. ·• Oct·03 Feb·04 --liiiil liiiiii'I 100 liiiiiil -~ == Figure 4-6 Trichloroethene and Tetrachloroethene Concentration vs. Time 2816 Davis Park Road, MW-17 Davis Park Road TCE Site Gastonia, North Carolina l!!!!!I -10 1. :--:--_-__ -__ -_-_-_-_ ------.-.-.-.-.-.. -.-.-.-.-.-.--------------------11 ........ -----•'--i .... ~ ~ ············· Cl) C: Cl) .r:. - ··········•·····-♦ • ••• . .•. Cl) ------------------------------------------------------------------e 0 :E " ·;: I- 0.1 Jan·98 (ROD Remediation Goal for TCE = 2.8 µg/I) (ROD Remediation Goal for PCE = 1 µg/I) Aug•98 Apr•99 Nov•99 Jul·00 Feb·01 Date K:\20064\ 138\ Third Quarter\table_figures.xls\lig4-6 OCt·01 Jun·02 Jan·03 Sep·03 Apr·04 l!!!!!I l!!l!I l!!l!!I -liii'L -. \ 1 liiiiiil_ iiliil. ;___J liiii1 ·- -'a, ~ Cl) C Cl) .c -Cl) 0 ~ 0 :c u ·.: I- 100 10 1 0.1 Mar-90 '---_, --__ , Figure 4-7 Trichloroethene and Tetrachloroethene Concentration vs. Time 2800 Davis Park Road, MW-18 Davis Park Road TCE Site Gastonia, North Carolina (ROD Remediatio;1. Goal for TCE = 2.8 µg/1) (ROD Remediation Goal for PCE-~ ·r µg/0 ..• -o· r Jul-91 Dec-92 Apr-94 Sep-95 Jan-97 Date Jun-98 Oct-99 Feb-01 Note: PCE Non-Detect in May 1990 and TCE Non-Detects in May 1990 and May 1996 reported as 2.5 ug/l (half the detction limit) K:\20064\ 138\Third Quarter\table_figures.x:ls\fig4-7 Jul-02 11!!!!1 . . ' --' Nov-03 ll R~l gr-1 O~I ri . I B l U.l 1·.1 ll ILi tl Ii I.I 1J ll ll II 1.J iJ This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed. in whole or in part, without the express written permission of EPA. February 2004 Semiannual Sampling Event Report Davis Park Road TCE Site Section: 4 Revision: 0 Date: April 2004 arisen that might reduce efficacy of this remedy, no toxic and/or mobile transformation products are being produced, the plume is not expanding, there is no impact downgradient, there is no evidence of a new release, and source area wells have attained remediation objec1ivcs . 4.3 RECOMMENDATIONS Analytical results from quarterly and semiannual sampling of the monilor well network at the Davis Park Road Site indicate decreasing levels of COCs. Perimeter wells located outside the plume continue to monitor for potential migration of plume constituents. To reduce the cost and streamline the L TRA sampling at the Davis Park Road Site, PDB samplers arc recommended to replace low-flow sampling techniques in the newly installed wells MW-20 and MW-21. PDBs provide representative samples of the principle COCs (PCE and TCE) in groundwater at the Davis Park Road Site based on a comparison with low-flow samples. PDBs arc easier and less expensive to deploy than sampling using a submersible pump. The total cost of assemblies for PDBs for 9 wells was less than $1,500. Additional sampling costs will include only the deionized water and the PDBs ($ I 5.00/ea) that are clipped on the existing assembly. PDBs at the Davis Park Road Site can be installed in one day and sampled in one day for a total of two days in the field. If the PDBs for the next sampling event are deployed immediately following sample collection, sampling time in the field can be further reduced. By comparison, low-flow sampling equipment (tubing, pump, field parameter instrnments) can cost close to $ I ,000 per sampling event, and sampling can take between 3 and 5 days in the field, dependent on accessibility, field conditions, and instrnmcnt performance. The cost of staging, sampling, and disposing of IDW is eliminated with the use of PDBs. Any water that might be accumulated from the PDBs following sampling is minimal and can be allowed to evaporate. PDB samplers should replace low-flow sampling for the nine existing accessible wells in the monitor well network. PDBs should be placed downhole to equilibrate for the next successive K:\20064\138\Second Semiannual\FelJ04SemiannualRpt.doc 4-11 RFW138·2A-APIM 11 1:·1 lrl m~I lrl 01 DI U"I u· I 11 I 1r 11 1J I .l 1J ll This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. February 2004 Semiannual Sampling Event Report Davis Park Road TCE Site Section: 4 · Revision: O Date: April 2004 sampling event immediately following the collection of a previously placed PDB bag. If levels of MTBE are detected at concentrations that appear to be anomalously high, sampling methods should be reconsidered. K:\20064\138\Second Semiannual\Feb04Sem,annuaIRpt.doc 4-12 RFW138·2A·APIM ··\ I I I I I n D I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly lor EPA. It shall not be disclosed, in whole or in part, without the express written pennission of EPA. APPENDIX A February 2004 Semiannual Sampling Event Report Davis Park Road TCE Site Section: Appendices Revision: O Date: April 2004 L CERTIFICATE OF ANALYSIS, DEIONIZED WATER K:\20064\138\Secood Semiannual\Feb04SemiannuaIRpt.doc RFW138-2A-APIM FROM: EON PRODUCTS FAX NO. : 770 978 8661 I Nf'.RL Diagnostic-, -l '.r,m~1c,ate C'lt Anaiys1s -l\.t::SllllS Mar. 08 2004 12:06PM P3 u I I n 0 0 D D D D I I 1 3)a-~ Certificate of Analysis ·ittUIPIIII~----------- Product: Lot No: 9800-5 1113103 Release Date: 11/17/2003 Expiration Date: 11-2004 Description: Reagent Grade Water, C.A.P., A.C.S., USP/NF and N.C.C.LS Components Ammonia {ppm) Bacteriological Purity* (CFU/ml) Calcium carbon Dioxide Chloride (ppm) Colfforms (per Liter) Copper (ppm) Heavy Metal (ppm) Iron (ppm) Conduaiv~y• (umhos/cm) Silicates (ppm) Sodium {ppm) Total Organic Carbon* (mg C/L) organics** Sulfate Volatile Organics Resistivity• (megohm-cm) •Meets statod values at the time of manufacture. "'--Substance reduction by KMn04, ACS Method. Data <0.3 <l Passtaear Pass/Clear <0.5 <l <l <0.01 ~.-tOOO <l 1.1 <0.01 <0.1 0.0500 Passes Test Pass/Clear Pass 18.00000 Specification < 0.3 < 10 Pass/Clear Pass/Clear < 0.5 < 1 < l < 0.01 S.O ~o 7.0 < I S 2.0 < 0.01 < 0.1 < 0.5 Passes Test Pass/Clear Passes Test > 10 Over 45 additional trihalomethanes and volatile organics are assayed. For a list of these substances, clLcLI!ea.. Prepared typically at lB megohm/cm specific resistance using reverse osmosisj mixed bed deionization, activated carbon filtration, to 0,2 micron. Dare: 11/17/2003 Lynn Rogler NERL Diagnostics Quality Assurance For more information, please call us toll-free at (800) 556-7575. or contact us via email at http://www.nerl.com/certificate/results/coa_template.aspx 3/8/2004 I FROM: EON PRODUCTS Volatile Organics FAX NO. 770 978 8661 I Definine RP.ttP.r Rusiness Partnerships with: Mar. 08 2004 12:06PM P2 J. U5'-' l, VI ut.vEtOPt.~E:NT, 0:PEP.IE.NCL flEX131L:l~, QLJALTY • ~ESOIJRC[ · J>HOZ>l:CT\01\" c::i~.IMITM[Ni I g u 0 D D D I I I I Volatile OrganiCS./Trihalomethanes for Ccrtifieace of An;:,Jysis Bromoform Bromodichloromethane Chloroform Dibromochloromethanc Benzene Vinyl Chloride Carbon Tetrachloride 1,2-0ichloroethane Trichloroethylene 1,4-Dichloroben:z:ene 1, 3-Dichloroethylene 1,1, 1-Trichloroethane Acrolein Acrylonitrile Bromobenzene Btomoathane Chlurvl.li::r1.:.~1·11o1 Chloroethane Oiloroethyvinyl Ether O,loromethane 1, 1-Chlor-otol.Jene 1, 3-Chlorotoluene Dibromochloropropane (DBCP) Dlb1omomell1c.111i:: l, 4-Dichlorobenzene 1,3-Dic:hlorobenzene DichlorodiHuoromethane l, 1-Dichloroethane irans-1,2-dichloroethylene Cis-1, 2-dichloroethylene Dichloromethane 1, i-Dichloroethane l, 2-0ichloropropane Trans--1, 3-dichloropropane Cis--1, 3-dichloropropane 2,2-Dichloropropane 1, 1-Dichloropropane as-1,3-dichloropropane Ethylbcnzene Ethylenedibromide (EDB) Styrene 1,1,1,2-Tetr.i.chlorog,than,,1 l, 1,2,2-T ctrach loroethane Tetrachloroethylene Trichlorobe nzene(s) 1, 1,2• Tri ch f('lrr.u;,t:h~n"" Trichlorofluoromethane 1,2, 3-Trichloropropane Tolucnt:. Xylene for more information, please call us toll-free at (800) 556-7575, or contact us via e-mail at !_e_c;_ha$si.s.ta.n..ce@nerl.com. · lnopJ ------------------------- : ; Products & ~m:_yicc:is I ~t,nical Informat.lo11 I N~ &, Eyents I CoQ½'_~ I :: Ceaificate Qf !n.alysis :: http://www.nerl.com/certificate/volatileorganics.html 3/8/2004 -~· .. ;~ · . .:,. ~ ~ ·;·-· : ~ .. ~~/ ,,: ::.-:,-:: ~ '.' -. ~ •, )·. ,._, ..... -·: :- ·--. }~· r. • • • • ~• •~ '' T · .. :t· .\:, .; .. ' .--,·· . . ":/. ',,·• ,r-~ •" . .· - ;;/.~:~\ _;:.)i ~;,' ,• -· . ,, -.,_.. ,,' ... -<};: ·-,~:.: ! .. (->:• .-,rr ,-.. :.--; I -.... •, . -·.t. . •. ' • ~ ,. • •::<, :-c: '. . .. ·• : .• '• . ... .::-.·••\i .. ::·.·.:',Y·{:f /. · : •. --~~·:,_._J•." ·. ··-·,--.·. '-, _1 _., •• i __ -~,: .. " . . ,:,. . , •. ·-,_.,.. -.~ • . . •. • -~ ,J-. " ... . ' -. . . .• · •. -.;_..-·, . " .. -;~•:·-·. -; . \. ,._. ~ •··:::·, .... ·"/ :;·:. '{/>t~'.i:~:-"::: :'. :.-,. '.' \· '.,',. '. . ,',· .,:;'• ..... ,,: • ... " . ,i.: >' ,;· ~ .. · .. -. ·-.. ~~--.. :··::-<--" ~.-, , ," -.-:i • ·i ,,_, ~ ~-.:. . ' .. ,.; .,... ·.,•'. ::)'.:::~_-·.·:·I'.>' :~· .• ,I ·-. ; ,: ;. ' .. ; 'I n D D I I I I I I I I I I I I I I I This document was prepared by Weston Solutions. Inc., expressly for EPA. It shall not be disclosed, in whole or in part, Vvilhout lhe express written permission of EPA. APPENDIX B February 2004 Semiannual Sampling Event Report Davis Park Road TCE Site Section: Appendices Revision: 0 Date: April 2004 LABORATORY ANALYTICAL REPORTS K:\20064\138\Second Semiannuaf\Feb04SemiannuaIRpl.doc RFW138-2A-APIM -·-- - -- - -- - - _, l!l!!!!!!!I l!!!l!!!I I!!!!! == == VOLATILES SAMPLE ANALYSIS EPA-REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2908 FY 2004 Project: 04-0323 Volatiles Scan Facility: Davis Park Rd Program: SF Id/Station: EB/ Gastonia, NC Case No: 32568 Media: EQUIPMENT RINSE BLANK D No: 2AC8 RESULTS 0.50 U 0.29 J 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 0.50 UJ 0.50 U 0.50 UJ 0.50 U 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 U 5.0 U 0.26 J 0.50 U 0.50 U 0.50 UJ 5.0 U UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Oichlorodifluoromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane {Freon 11) 1, 1-Dichloroethene ( 1, 1-Dichloroethylene) 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) Acetone Carbon Disulfide Methyl Acetate Methylene Chloride trans-1,2-Dichloroethene Methyl T-Butyl Ether (MTBE) 1, 1-Dichloroethane cis-1,2-Dichloroethene Methyl Ethyl Ketone Bromochloromethane Chloroform 1, 1, 1-Trichloroethane Cyclohexane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethane (Trichloroethylene) Methylcyclohexane 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Methyl lsobutyl Ketone Toluene trans-1,3-Dichloropropene 1, 1,2-Trichloroethane Tetrachloroethene (Tetrachloroethylene) Methyl Butyl Ketone Org Contractor: A4 RESULTS 0.50 U 0.50 U 0.50 U 0.50 UJ 0.50 UJ 0.50 UJ 0.50 U 0.50 UJ 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/05/2004 10:20 Ending: UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dibromochloromethane 1,2-Dibromoethane (EDB) Chlorobenzene Ethyl Benzene Total Xylenes Styrene Bromoform lsopropylbenzene 1, 1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4-Trichlorobenzene 1,2,3-Trichlorobenzene U•Analyte not detected at or above reporting limit. I J•ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence ana!yte is present; analyte reported as tentative identification. j NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K•ldentification of anatyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. l-ldenlification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA•Not Analyzed. I NAI-Not Analyzed due to Interferences. I A•Analyte analyzed in replicate. Reported value is "average" of replicates. R•Presence or absence of analyte can not be determined from data due to severe quality ·control problems. Data are rejected and considered unusable. Page 1 of 1 llliil: ----·-l!!!!!!!!!I 1!11!!1 - - - - - VOLATILES SAMPLE ANALYSIS - - - - - EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2908 FY 2004 Project: 04-0323 MISCELLANEOUS COMPOUNDS Facility: Davis Park Rd Program: SF Id/Station: EB/ Media: EQUIPMENT RINSE BLANK RESULTS UNITS ANALYTE 2.2 J UG/L 3 UNKNOWNS Gastonia, NC Case No: 32568 D No: 2AC8 0.84 JN UG/L CYCLOTETRASILOXANE, OCTAMETHYL- Data Reported as Identified by CLP Lab -IDs Not Verified Org Contractor: A4 Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/05/2004 10:20 Ending: U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-tdentificalion of analyte is acceptable; reported value may be biased high. Actual value exPected to be less than the reported value. l•ldenlification of analyte is acceptable; reported value may be biased low. Actuat value expected to be greater than reported value. NA-Not Analyzed. I NAl•Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is ~average" of replicates. R-Presence or absence of ~nalyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 -111111 - - -- -- -- ---. l!!!!!!!!!I l!!!!!!!!!I l!!!!!!I VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2909 FY 2004 Volatiles Scan Facility: Davis Park Rd Program: SF Id/Station: FB / Media: FIELD BLANK Project: 04-0323 Gastonia, NC Case No: 32568 D No: 2AC9 Org Contractor: A4 Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/05/2004 10: 15 Ending: -------------------------------------------------------------------RESULTS 0.50 U 0.29 J 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UGIL UG/L UGIL UGIL UG/L UG/L UG/L UGIL UGIL UG/L UG/L UG/L UG/L UG/L UG/L UGIL UG/L UG/L UG/L UG/L UG/L UG/L UG/L UGIL UG/L UG/L UG/L UG/L 5.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 0.50 UJ 0.50 U 0.50 U 0.50 U 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 U 5.0 U 0.29 J 0.50 U 0.50 U 0.50 UJ 5.0 U ANALYTE Dichlorodifluoromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichloronuoromethane (Freon 11) 1, 1-Dichloroethene ( 1, 1-Dichloroethylene) 1, 1,2-Trichloro-1,2,2.Trinuoroethane (Freon 113) Acetone Carbon Disulfide Methyl Acetate Methylene Chloride trans-1,2-Dichloroethene Methyl T-Butyl Ether (MTBE) 1, 1-Dichloroethane cis-1,2-Dichloroethene Methyl Ethyl Ketone Bromochloromethane Chloroform 1, 1, 1-Trichloroethane Cyclohexane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene (Trichloroethylene) Methylcyclohexane 1,2-0ichloropropane Bromodichloromethane cis-1,3-Dichloropropene Methyl lsobutyl Ketone Toluene trans-1,3-Dichloropropene 1, 1,2-Trichloroethane Tetrachloroethene (Tetrachloroethylene) Methyl Butyl Ketone RESULTS 0.50 U 0.50 U 0.50 U 0.50 UJ 0.50 UJ 0.50 UJ 0.50 U 0.50 UJ 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dibromoch!oromethane 1,2-Dibromoethane (EDB) Chlorobenzene Ethyl Benzene Total Xylenes Styrene Bromoform lsopropylbenzene 1, 1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4-Trichlorobenzene 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present: analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present: analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte iS acceptable; reported value may be biased high. Actual Value expected to be less than the reported value. l-ldentifrcation of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is "average" of repllcates. R-Presence or absence of analyte can not be determined from data due to severe quality control problenis. Data are rejected and considered unusable. Page 1 of 1 !!l!I ---: -- -- - - l!!l!!I l!!!!!l!!!!I - - - - - VOLATILES SAMPLE ANALYSIS EPA -REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2909 FY 2004 Project: 04-0323 MISCELLANEOUS COMPOUNDS Facility: Davis Park Rd Program: SF Id/Station: FB / Media: FIELD BLANK Gastonia, NC Case No: 32568 D No: 2AC9 RESULTS UNITS ANALYTE 1.1 JN UG/L 0.85 JN UG/L CYCLOTRISILOXANE, HEXAMETHYL- CYCLOTETRASILOXANE, OCTAMETHYL- Data Reported as Identified by CLP Lab· IDs Not Verified ------------------ Org Contractor: A4 Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/05/2004 10:15 Ending: U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acc.eptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present: analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAl-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates. R-Presence or ab ... sence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 l!!!!!I --·-- ---·----.. l!!l!I VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/200413:00 Sample 2910 FY 2004 Project: 04-0323 Volatiles Scan Facility: Davis Park Rd Program: SF Id/Station: MW 1 / Gastonia, NC Case No: 32568 Media: GROUNDWATER D No: 2AD0 RESULTS 0.50 U 0.28 J 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 11 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 7.6 0.50 U 0.50 U 0.50 U 0.50 UJ 0.50 U 0.50 UJ 0.50 U 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 U 5.0 U 0.50 UJ 0.50 U 0.50 U 0.50 UJ 5.0 U UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dichlorodifluoromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane (Freon 11) 1, 1-Dichloroethene (1, 1-Dichloroethylene) 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) Acetone Carbon Disulfide Methyl Acetate Methylene Chloride trans-1,2-Dichloroethene Methyl T-Butyl Ether (MTBE) 1, 1-Dichloroethane cis-1,2-0ichloroethene Methyl Ethyl Ketone Bromochloromethane Chloroform 1, 1, 1-Trichloroethane Cyclohexane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene (Trichloroethylene) Methylcyclohexane 1,2-Dichloropropane Bromodichloromethane cls-1,3-0ichloropropene Methyl lsobutyl Ketone Toluene trans-1,3-Dichloropropene 1, 1,2-Trichloroethane Tetrachloroethene (Tetrachloroethylene) Methyl Butyl Ketone Org Contractor: A4 RESULTS 0.50 U 0.50 U 0.50 U 0.50 UJ 0.50 UJ 0.50 UJ 0.50 U 0.50 UJ 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/04/2004 11 :45 Ending: UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dibromochloromethane 1,2,Dibromoethane (EDS) Chlorobenzene Ethyl Benzene Total Xylenes Styrene Bromoform lsopropylbenzene 1, 1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4-Trichlorobenzene 1,2,3-Trichlorobenzene U•Analyte not detected at or above reporting limit. I J•ldentification of analyte is acceptable; reported value is an estimate. I UJ·Analyte not detected at or above reporting limit. Reporting limit is an estimate. N•Presumptive evidence analyte Is present; analyte reported as tentative identification. I -NJ.Presumptive evidence analyte is present: anatyte reported as tentative identification. Reported value is an estimate. K•ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L•ldentification of analyte is acceptable; reported value may be biased tow. Actual value expected to be greater than reported value. NA•Not Analyzed. I NAl•Not Analyzed due to Interferences. I A•Analyte analyzed in replicate. Reported value is Maverage" of replicates. R•Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page1of1 l!!!!l!!!!I '. - -- -- --------VOLATILES SAMPLE ANALYSIS ------EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 291 0 FY 2004 Project: 04-0323 MISCELLANEOUS COMPOUNDS Facility: Davis Park Rd Program: SF Id/Station: MW1 / Media: GROUNDWATER ANALYTE Gastonia, NC Case No: 32568 D No: 2ADO RESULTS 2.9 J 1.1 JN UNITS UG/L UG/L. 3 UNKNOWNS CYCLOTETRASILOXANE, OCTAMEHYL Data Reported as Identified by CLP Lab· IDs Not Verified Org Contractor: A4 Produced by: Appleby, Charlie Request or: Project Leader: JWENDEL Beginning: 02/04/2004 11 :45 Ending: U-Analyte not detected at or above reporting limit. I J-ldentification of anatyte is acceptable: reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is Present; analyte reported as tentative identification. j NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable: reported value may be biased high. Actual value expected lo be less than the reported value. l-ldenlification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 l!!l!!!!!!I -- ----- -- --- -.. --- --VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2911 FY 2004 Project: 04-0323 Volatiles Scan Facility: Davis Park Rd Program: SF Gastonia, NC Case No: 32568 Id/Station: MW10 I Media: GROUNDWATER D No: 2AD1 RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 0.24 J 5.0 U UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dichlorodifluoromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane (Freon 11) 1, 1-Dichloroethene ( 1, 1-Dichloroethylene) 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) Acetone Carbon Disulfide Methyl Acetate Methylene Chloride trans-1,2-0ichloroethene Methyl T-Butyl Ether (MTBE) 1, 1-Dichloroethane cis-1,2-Dichloroethene Methyl Ethyl Ketone Bromochloromethane Chloroform 1, 1, 1-Trichloroethane Cyclohexane C_arbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene (Trichloroethylene) Methylcyclohexane 1,2-Dichloropropane Bromodichloromethane cis-1,3-0ichloropropene Methyl lsobutyl Ketone Toluene trans-1,3-0ichloropropene 1, 1,2-Trichloroethane Tetrachloroethene (Tetrachloroethylene) Methyl Butyl Ketone Org Contractor: A4 RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/03/2004 12: 17 Ending: UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dibromochloromethane 1,2-Dibromoethane (EDB) Chlorobenzene Ethyl Benzene Total Xylenes Styrene Bromoform lsopropylbenzene 1, 1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4-TrichlOrobenzene 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-Jdentification of analyte is acceptable; reported value is an estimate. j UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence anatyte is present; analyte reported as tentative identification. ! NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analy1e is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates, R-Presence or absence of analyte can not be determined from data due to severe quality control_ problems. Data are rejected and considered unusable. Page 1 of 1 - -- -- - -- - -- - -- -- - l!!!!!!!!I VOLATILES SAMPLE ANALYSIS EPA-REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2911 FY 2004 Project: 04-0323 MISCELLANEOUS COMPOUNDS Facility: Davis Park Rd Program: SF Id/Station: MW10 / Media: GROUNDWATER ANALYTE Gastonia, NC Case No: 32568 D No: 2AD1 RESULTS 2.2 JN 0.61 J 1.3 JN UNITS UGIL UGIL UG/L CYCLOTRISILOXANE, HEXAMETHYL UNKNOWN CYCLOTETRASILOXANE, OCTAMETHYL Data Reported as Identified by CLP Lab· IDs Not Verified Org Contractor: A4 Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/03/2004 12:17 Ending: U-Analyte not detected al or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Nol Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 l!l!!I -- --- --- - -- -- --- --VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2912 FY 2004 Project: 04-0323 Volatiles Scan Facility: Davis Park Rd Program: SF Gastonia, NC Case No: 32568 Id/Station: MW11 / Media: GROUNDWATER D No: 2AD2 ----------------·--- RESULTS 0.50 UJ 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 UJ 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 0.17 J 5.0 U UNITS UG/L UGIL UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UGIL UGIL ANALYTE Dichlorodifluoromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane (Freon 11) 1, 1-Dichloroethene (1, 1-Dichloroethylene) 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) Acetone Carbon Disulfide Methyl Acetate Methylene Chloride trans-1,2-Dichloroethene Methyl T-Butyl Ether (MTBE) 1, 1-Dichloroethane cis-1,2-Dichloroethene Methyl Ethyl Ketone Bromochloromethane Chloroform 1, 1, 1-Trichloroethane Cyclohexane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene (Trichloroethylene) Methylcyclohexane 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Methyl lsobutyl Ketone Toluene trans-1,3-Dichloropropene 1, 1,2-Trichloroethane Tetrachloroethene (Tetrachloroethylene) Methyl Butyl Ketone •Org Contractor: A4 RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U Produced by: Appleby, Charlie Request or: Project Leader: JWENDEL Beginning: 02/03/2004 16:01 Ending: UNITS UG/L UG/L UG/L UGIL UG/L UGIL UG/L UG/L UG/L UGIL UG/L UG/L UGIL UG/L UG/L ANALYTE Dibromochloromethane 1,2-Dibromoethane (EDB) Chlorobenzene Ethyl Benzene Total Xylenes Styrene Bromoform lsopropylbenzene 1, 1,2,2-Tetrachloroethane 1,3-0ichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4-Trichlorobenzene 1,2,3-Trichlorobenzene U·Analyte not detected at or above reporting limit. I J·ldentification or analyte is acceptable; reported value is an estimate. l LJJ.Analyte not detected at or above reporting limit. Reporting limit is an estimate. N·Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ.Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K·ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. l•ldentification of anatyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA•Not Analyzed. I NAl•Not Analyzed due to Interferences. I A·Analyte analyzed in replicate. Reported value is "average" of replicates. R•Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. . Page 1 of 1 - -- -- --- ------VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2912 FY 2004 Project: 04-0323 MISCELLANEOUS COMPOUNDS Facility: Davis Park Rd Program: SF Id/Station: MW11 / Media: GROUNDWATER RESULTS UNITS 1.9J UG/L ANALYTE UNKNOWN Gastonia, NC Case No: 32568 D No: 2AD2 Data Reported as Identified by CLP Lab -IDs Not Verified Org Contractor: A4 Produced by: Appleby, Charlie Requestor: Project Leader:.JWENDEL Beginning: 02/03/2004 16:01 Ending: U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present: analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present: analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentifrcation of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 - ----------·---·-·-VOLATILES SAMPLE ANALYSIS EPA-REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2913 FY 2004 Project: 04-0323 Volatiles Scan Facility: Davis Park Rd Program: SF Gastonia, NC Case No: 32568 Id/Station: MW 12 / Media: GROUNDWATER D No: 2AD3 RESULTS 0.50 UJ 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 15 J 0.50 U 0.50 UJ 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 7.2 0.50 U 0.50 U a.sou 0.50 U 0.50 U 0.50 U a.sou 3.5 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U a.sou 0.50 U 1.4 5.0 U UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Oichlorodifluoromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane (Freon 11) 1, 1-Dichloroethene (1, 1-Dichloroethylene) 1, 1,2-Trichloro-1,2,2-Trifiuoroethane (Freon 113) Acetone Carbon Disulfide Methyl Acetate Methylene Chloride trans-1,2-Dichloroethene Methyl T-Butyl Ether (MTBE) 1, 1-Dichloroethane cis-1,2-Dichloroethene Methyl Ethyl Ketone Bromochloromethane Chloroform 1, 1, 1-Trichloroethane Cyclohexane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethane (Trichloroethylene) Methylcyclohexane 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Methyl lsobutyl Ketone Toluene trans-1,3-Dichloropropene 1, 1,2-Trichloroethane Tetrachloroethene (Tetrachloroethylene) Methyl Butyl Ketone Org Contractor: A4 RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/04/2004 15:40 Ending: UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dibromochloromethane 1,2-Dibromoethane (EDS) Chlorobenzene Ethyl Benzene Total Xylenes Styrene Bromoform lsopropylbenzene 1, 1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4-Trichlorobenzene 1,2,3-Trichlorobenzene U•Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N·Presumplive evidence analyte is present; analyte report_ed as tentative identification. j NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. l A-Analyte analyzed in replicate. Reported value is "average" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejecte~ and considered unusable. Page 1 of 1 - -- -·--l!!l!!I ; -l!!!!!!!I l!l!!!!I l!!!!!I l!!!!!I -:-.-·-VOLATILES SAMPLE ANALYSIS EPA-REGION IV SESD, ATHENS, GA Production Date: 03/03/200413:00 Sample 2914 FY 2004 Project: 04-0323 Volatiles Scan Facility: Davis Park Rd Program: SF ld/Station:MW14 / Media: GROUNDWATER Gastonia, NC Case No: 32568 D No: 2AD4 RESULTS 0.50 UJ 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 14 J 0.50 U 0.50 UJ 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 6.9 0.50 U 0.50 U 0.50 U .0.50 U 0.50 U 0.50 U 0.50 U 0.22 J 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Oichlorodifluoromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane (Freon 11) 1, 1-Dichloroethene ( 1, 1-Dichloroethylene) 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) Acetone Carbon Disulfide Methyl Acetate Methylene Chloride trans-1,2-0lchloroethene Methyl T-Butyl Ether (MTBE) 1, 1-Dichloroethane cis-1,2-Dlchloroethene Methyl Ethyl Ketone Bromochloromethane Chloroform 1, 1, 1-Trichloroethane Cyclohexane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene (Trichloroethylene) Methylcyclohexane 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Methyl lsobutyl Ketone Toluene trans-1,3-Dichloropropene 1, 1,2-Trichloroethane T etrachloroethene (T etrachloroethylene) Methyl Butyl Ketone Org Contractor: A4 RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/04/2004 13:30 Ending: UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dibromochloromethane 1,2-Dibromoethane (EDS) Chlorobenzene Ethyl Benzene Total Xylenes Styrene Bromoform lsopropylbenzene 1, 1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4-Trichlorobenzene 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte ls acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. 1 A-Analyte analyzed in replicate. Reported value is "average" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and cons_idered unusable. Page 1 of 1 1!!111!11 ------ --l!!!!!!!!!I l!!l!!!!!I -- - - - VOLATILES SAMPLE ANALYSIS EPA-REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 ------------------------------------------------------------Sample 2914 FY 2004 Project: MISCELLANEOUS COMPOUNDS Facility: Davis Park Rd Program: SF Id/Station: MW14 / Media: GROUNDWATER RESULTS UNITS 1.8 J UG/L ANALYTE UNKNOWN 04-0323 Gastonia, NC Case No: 32568 D No: 2AD4 Data Reported as Identified by CLP Lab -IDs Not Verified Org Contractor: A4 Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/04/2004 13:30 Ending: U-AnaJyte not detected at or above reporting limit. [ J-ldentification of analyte is acceptable: reported value is an estimate. f UJ-Anafyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable: reported value may be biased high. Actual value expected to be less than the repcrted value. L-Jdentification of analyte is acceptable; reported value may be bi_ased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 B!!I --- --- ---·-- - ---VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2915 FY 2004 Project: 04-0323 Volatiles Scan Facility: Davis Park Rd Program: SF Id/Station: MW 15 / Media: GROUNDWATER Gastonia, NC Case No: 32568 D No: 2AD5 Org Contractor: A4 Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/04/2004 11: 15 Ending: --------------------------------------------------------------------------- RESULTS 0,50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 15 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.27 J 4.9 9.3 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 50 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 0.22 J 5.0 U UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dichlorodifluoromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane (Freon 11) 1, 1-Dichloroethene ( 1, 1-Dichloroethylene) 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) Acetone Carbon Disulfide Methyl Acetate Methylene Chloride trans-1,2-0ichloroethene Methyl T-Butyl Ether (MTBE) 1, 1-Dichloroethane cis-1,2-Dichloroethene Methyl Ethyl Ketone Bromochloromethane Chloroform 1, 1, 1-Trichloroethane Cyclohexane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene (Trichloroethylene) Methylcyclohexane 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Methyl lsobutyl Ketone Toluene trans-1,3-Dichloropropene 1, 1,2-Trichloroethane Tetrachloroethene (Tetrachloroethylene) Methyl Butyl Ketone RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dibromochloromethane 1,2-Dibromoethane (EDS) Chlorobenzene Ethyl Benzene Total Xylenes Styrene Bromoform lsopropylbenzene 1, 1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4-Trichlorobenzene 1,2,3-Trichlorobenzene U•Ana1yte not detected at or above reporting limit. I J•ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present analyte reported as tentative identification. j NJ-Presumptive evidence analyte is present; analyle reported as tentative identification. Reported value is an estimate. K•ldentification of anatyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. l-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAl•Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates. R•Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 - - - -- - -.. VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2916 FY 2004 Project: 04-0323 Volatiles Scan Facility: Davis Park Rd Program: SF Gastonia, NC Case No: 32568 Id/Station: MW 15C / Media: GROUNDWATER D No: 2AD6 RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 15 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.23 J 4.3 5.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 44 J 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 0.35 J 5.0 U UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Oichlorodifluoromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane (Freon 11) 1, 1-Dichloroethene ( 1, 1-Dichloroethylene) 1, 1,2-Trichloro-1,2,2-Trifiuoroethane (Freon 113) Acetone Carbon Disulfide Methyl Acetate Methylene Chloride trans-1,2-Dichloroethene Methyl T-Butyl Ether (MTBE) 1, 1-Dichloroethane cis-1,2-Dichloroethene Methyl Ethyl Ketone Bromoch1oromethane Chloroform 1, 1, 1-Trichloroethane Cyclohexane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene (Trichloroethylene) Methylcyclohexane 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Methyl lsobutyl Ketone Toluene trans-1,3-Dichloropropene 1, 1,2-Trichloroethane Tetrachloroethene (Tetrachloroethylene) Methyl Butyl Ketone Org Contractor: A4 RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/04/2004 11:15 Ending: UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dibromochloromethane 1,2-Dibromoethane (EDB) Chlorobenzene Ethyl Benzene Total Xylenes Styrene Bromoform lsopropylbenzene 1, 1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2•0ichlorobenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4• Trichlorobenzene 1,2,3• Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldenlification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present: analyte reported as tentative identification. j NJ-Presumptive evidence analyte is present; analyle reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldenlificalion of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is ~average" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page1of1 - - - - - -- - -- -- --- - - - - VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESO, ATHENS, GA Production Date: 03/03/200413:00 Sample 2916 FY 2004 Project: 04-0323 MISCELLANEOUS COMPOUNDS Facility: Davis Park Rd Program: SF ld/Station:MW15C / Media: GROUNDWATER RESULTS UNITS ANALYTE 2.1 J UG/L 2 UNKNOWNS Gastonia, NC Case No: 32568 D No: 2AD6 Data Reported as Identified by CLP Lab -IDs Not Verified Org Contractor: A4 Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/04/2004 11: 15 Ending: U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. j NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable: reported value may be biased high. Actual value expected to be less than the reported value. · L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. j A-Analyte analyzed in replicate. Reported value is "average" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 -- --- -- ---1!!1!11 --··-~-·-VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2917 FY 2004 Project: 04-0323 Volatiles Scan Faclllty: Davis Park Rd Program: SF Gastonia, NC Case No: 32568 Id/Station: MW 16 / Media: GROUNDWATER D No: 2AD7 RESULTS 0.50 UJ 0.50 U 0.50 U 0.50 U a.sou a.sou 0.50 U 0.50 U 5.0 U 0.50 U 0.50 UJ 0.50 U 0.50 U 0.50 U 0.50 U a.sou 5.0 U a.sou a.sou 0.50 U 0.50 U 0.50 U a.sou 0.50 U 0.50 U a.sou a.sou 0.50 U a.sou 5.0 U 0.50 U 0.50 U a.sou a.sou 5.0 U UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dichlorodifluoromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofiuoromethane (Freon 11) 1, 1-Dichloroethene (1, 1-Dichloroethylene) 1, 1,2-Trichloro-1,2,2-Trifiuoroethane (Freon 113) Acetone Carbon Disulfide Methyl Acetate Methylene Chloride trans-1,2-Dlchloroethene Methyl T-Butyl Ether (MTBE) 1, 1-Dichloroethane cis-1,2-0ichloroethene Methyl Ethyl Ketone Bromochloromethane Chloroform 1, 1, 1-Trichloroethane Cyclohexane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene (Trichloroethylene) Methylcyclohexane 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Methyl lsobutyl Ketone Toluene trans-1,3-Dichloropropene 1, 1,2-Trichloroethane Tetrachloroethene (Tetrachloroethylene) Methyl Butyl Ketone Org Contractor: A4 RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.35 J 0.34 J 0.50 U 0.50 U 0.50 U 0.50 U Produced by: Appleby, Charlie Request or: Project Leader: JWENDEL Beginning: 02/03/2004 14:44 Ending: UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dibromochloromethane 1,2-Dibromoethane (EDB) Chlorobenzene Ethyl Benzene Total Xylenes Styrene Bromoform lsopropylbenzene 1, 1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4•Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4· Trichlorobenzene 1,2,3· Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value ls an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual vaiue expected to be less than the reported value. L-ldenlification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. j A-Analyte analyzed in replicate. Reported value is "averageN of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 l!!!!!I ---- -- - ---·-- -·-VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2917 FY 2004 Project: 04-0323 MISCELLANEOUS COMPOUNDS Facility: Davis Park Rd Program: SF Id/Station: MW 16 / Media: GROUNDWATER ANALYTE 3 UNKNOWNS Gastonia, NC Case No: 32568 D No: 2AD7 RESULTS 2.3 J 0.90 JN UNITS UG/L UG/L BENZENE, 1-ETHYL-3-METHYL- Data Reported as Identified by CLP Lab -IDs Not Verified Org Contractor: A4 Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/03/2004 14:44 Ending: U•Analyte not detected at or above reporting limit. I J-ldentification of analyte is acc·eptable; reported value is an estimate. UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. j NJ-Presumptive eVidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-fdentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. l•ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA•Not Analyzed. I NAl•Not Analyzed due to Interferences. I A·Analyte analyzed in replicate. Reported value is "average" of replicates. R•Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 - - - -- ---- -----l!!l!!!!I VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2918 FY 2004 Project: 04-0323 Volatiles Scan Facility: Davis Park Rd Program: SF Id/Station: MW17 / Gastonia, NC Case No: 32568 Media: GROUNDWATER D No: 2AD8 RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.98 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.57 0.50 U 0.50 U 0.50 U 0.50 U 17 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 9.0 5.0 U UNITS UG/L UG/L UGIL UG/L UG/L UG/L UG/L UGIL UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UGIL UG/L UG/L UG/L UG/L UGIL UG/L UG/L UGIL UG/L ANALYTE Dichlorodifluoromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane (Freon 11) 1, 1-Dichloroethene (1, 1-Dichloroethylene) 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) Acetone Carbon Disulfide Methyl Acetate Methylene Chloride trans-1,2-0ichloroethene Methyl T-Butyl Ether (MTBE) 1, 1-Dichloroethane cis-1,2-Dichloroethene Methyl Ethyl Ketone Bromochloromethane Chloroform 1, 1, 1-Trichloroethane Cyclohexane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene (Trichloroethylene) Methylcyclohexane 1,2-Dichloropropane Bromodichloromethane cis-1,3-0ichloropropene Methyl lsobutyl Ketone Toluene trans-1,3-0ichloropropene 1, 1,2-Trichloroethane Tetrachloroethene (Tetrachloroethylene) Methyl Butyl Ketone Org Contractor: A4 RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U Produced by: Appleby, Charlie. Requester: Project Leader: JWENDEL Beginning: 02/03/2004 11: 19 Ending: UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UGIL UG/L UG/L UG/L UG/L ANALYTE Oibromochloromethane 1,2-Dibromoethane (EDB) Chlorobenzene Ethyl Benzene Total Xylenes Styrene Bromoform lsopropylbenzene 1, 1,2,2-Tetrachloroethane 1,3-0ichlorobenzene 1,4-0ichlorobenzene 1,2-0ichlorobenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4-Trichlorobenzene 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of anatyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to lnterf8rences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 l!!!!!!!I --·-·--·--11!!!!!!!!1 • - l!!!!!!I . . I!!!! . -· -· --- - VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2918 FY 2004 Project: 04-0323 MISCELLANEOUS COMPOUNDS Facility: Davis Park Rd Program: SF ld/Station:MW17 / Media: GROUNDWATER RESULTS UNITS ANALYTE 1.4 J UG/L 2 UNKNOWNS Gastonia, NC Case No: 32568 D No: 2AD8 Data Reported as Identified by CLP Lab -IDs Not Verified Org Contractor: A4 Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/03/2004 11:19 Ending: U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA•Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 1!11!1 ·-------VOLATILES SAMPLE ANALYSIS -·----EPA· REGION IV SESD, ATHENS, GA ---Production Date: 03/03/2004 13:00 Sample 2919 FY 2004 Project: 04-0323 Volatiles Scan Facility: Davis Park Rd Program: SF Gastonia, NC Case No: 32568 Id/Station: MW19 / Media: GROUNDWATER D No: 2AD9 RESULTS 0.50 UJ 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 UJ 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.43 J 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 0.39 J 5.0 U UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dichlorodifluoromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane (Freon 11) 1, 1-Dichloroethene ( 1, 1-Dichloroethylene) 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) Acetone Carbon Disulfide Methyl Acetate Methylene Chloride trans-1,2-0ichloroethene Methyl T-Butyl Ether (MTBE) 1, 1-Dichloroethane cis-1,2-Dichloroethene Methyl Ethyl Ketone Bromochloromethane Chloroform 1, 1, 1-Trichloroethane Cyclohexane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene (Trichloroethylene) Methylcyclohexane 1,2-Dichloropropane Bromodichloromethane cis-1,3-0lchloropropene Methyl lsobutyl Ketone Toluene trans-1,3-Dichloropropene 1, 1,2-Trichloroethane T etrachloroethene (T etrachloroethylene) Methyl Butyl Ketone Org Contractor: A4 RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/03/2004 14:16 Ending: UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Oibromochloromethane 1,2-Dibromoethane (EDB) Chlorobenzene Ethyl Benzene Total Xylenes Styrene Bromoform lsopropylbenzene 1, 1,2,2-Tetrachloroethane 1,3-Dlchlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4-Trichlorobenzene 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. ! UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported Value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAl-Not Analyzed due to lnterlerences. I A-Analyte analyzed in _replicate. Reported value is "average" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 1!!!!!11!1 -- --·--- --11111!11 .. _, l!l!!I ~ l!!!!!!!I l!l!!!h VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/200413:00 ---------------------------------------------------- Sample 2919 FY 2004 Project: 04-0323 MISCELLANEOUS COMPOUNDS Facility: Davis Park Rd Program: SF Id/Station: MW19 I Gastonia, NC Case No: 32568 Media: GROUNDWATER D No: 2AD9 Org Contractor: A4 Produced by: Appleby. Charlie Requester: Project Leader: JWENDEL Beginning: 02/03/2004 14:16 Ending: ------------------------------------------------------------------------------------------------------------------ RESULTS UNITS 0.97 J UG/L ANALYTE UNKNOWN Data Reported as Identified by CLP Lab· IDs Not Verified ------------------------------------------------------------------------------------U-Analyte not detected at or above reporting limit. I J-ldentifrcation of analyte is acceptable; reported value is an estimate. UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptlve evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-tdentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA.Not Analyzed. I NAf•Not Analyzed due to Interferences, I A-Analyte analyzed in replicate. Reported value is "average" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 - ------- -- --- - --VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2920 FY 2004 Project: 04-0323 Volatiles Scan Facility: Davis Park Rd Program: SF Id/Station: MW2 I Gastonia, NC Case No: 32568 Media: GROUNDWATER D No: 2AE0 RESULTS 0.50 UJ 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 10 J 0.50 U 0.50 UJ 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 6.9 0.50 U 0.40 J 0.35 J 0.50 U 0.50 U 0.50 U 0.50 U 4.0 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 1.3 5.0 U UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Oichlorodifluoromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofiuoromethane (Freon 11) 1, 1-Dichloroethene ( 1, 1-Dichloroethylene) 1, 1,2-Trichloro-1,2,2-Trifiuoroethane (Freon 113) Acetone Carbon Disulfide Methyl Acetate Methylene Chloride trans-1,2-Dichloroethene Methyl T-Butyl Ether (MTBE) 1, 1-Dichloroethane cis-1,2-Dichloroethene Methyl Ethyl Ketone Bromochloromethane Chloroform 1, 1, 1-Trichloroethane Cyclohexane Carbon Tetrachloride Benzene · 1,2-Dichloroethane Trichloroethene (Trichloroethylene) Methylcyclohexane 1,2-Dichloropropane Bromodichloromethane cis-1,3-0ichloropropene Methyl lsobutyl Ketone Toluene trans-1,3-Dichloropropene 1, 1,2-Trichloroethane Tetrachloroethene (Tetrachloroethylene) Methyl Butyl Ketone Org Contractor: A4 RESULTS 0.50 U 0.50 U 0.50 U 0.23 J 0.19 J 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/04/2004 14:00 Ending: UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dibromochloromethane 1,2-Dibromoethane (EDS) Chlorobenzene Ethyl Benzene Total Xylenes Styrene Bromoform lsopropylbenzene 1, 1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4-Trichlorobenzene 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. 1 J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence anatyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable:·reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. l NAI-Not Analyzed due to lnterlerences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 - -- -- -- -- -- -- - ---VOLATILES SAMPLE ANALYSIS EPA -REGION IV SESD, ATHENS, GA Production Date: 03/03/200413:00 Sample 2921 FY 2004 Project: 04-0323 Volatiles Scan Facility: Davis Park Rd Program: SF Gastonia, NC Case No: 32568 Id/Station: MW20 / Media: GROUNDWATER D No: 2AE1 RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 0.50 U 84 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0,50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.42 J 0.50 U 0.50 U 0.50 U 5.0 U UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UGIL UG/L UG/L UG/L UG/L UG/L UG/L UG/L UGIL UG/L UGIL UG/L UG/L UG/L UG/L UG/L UG/L UG/L UGIL UGIL UG/L UGIL UGIL UGIL UG/L UG/L ANALYTE Oichlorodifluoromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofiuoromethane (Freon 11) 1, 1-Dichloroethene (1, 1-Dichloroethylene) 1, 1,2-Trichloro-1,2,2-Trifiuoroethane (Freon 113) Acetone Carbon Disulfide Methyl Acetate Methylene Chloride trans-1,2-Dichloroethene Methyl T-Butyl Ether (MTBE) 1, 1-Dichloroethane cis-1,2-Dichloroethene Methyl Ethyl Ketone Bromochloromethane Chloroform 1, 1, 1-Trichloroethane Cyclohexane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene (Trichloroethylene) Methylcyclohexane 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Methyl lsobutyl Ketone Toluene trans-1,3-Dichloropropene 1, 1,2-Trichloroethane Tetrachloroethene (Tetrachloroethylene) Methyl Butyl Ketone Org Contractor: A4 RESULTS 0.50 U 0.50 U 0.50 U 0.31 J 0.48 J 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/05/2004 Ending: UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Oibromochloromethane 1,2-Dibromoethane (EDB) Chlorobenzene Ethyl Benzene Total Xylenes Styrene Bromoform lsopropylbenzene 1, 1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2.4-Trichlorobenzene 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present anatyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; ana1yte reported as tentative identification. Reported value is an estimate. K-tdentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is ~average" of raplicates. R-Presence or absence of analyte can no_t be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 111!!1 - -----·---- --VOLATILES SAMPLE ANALYSIS -EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/200413:00 Sample 2921 FY 2004 Project: 04-0323 MISCELLANEOUS COMPOUNDS Facility: Davis Park Rd Program: SF Id/Station: MW20 / Media: GROUNDWATER ------------------------ ANALYTE 4 UNKNOWNS Gastonia, NC Case No: 32568 D No: 2AE1 RESULTS 3.7 J 2.0 JN 0.53 JN 0.59 JN UNITS UG/L UG/L UG/L UG/L CYCLOTETRASILOXANE, OCTAMETHYL BENZENE, 1,2,4-TRIMETHYL- BENZENE, 1,2,3-TRIMETHYL- Data Reported as Identified by _CLP Lab -IDs Not Verified Org Conlractor: A4 Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/05/2004 Ending: -----~---------------------~------------------------------------U-Analyte not detected at or above reporting limit. [ J-ldentification of analy\e is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable: reported value may be biased high. Actual value expected to be less than the reported value. l-ldentification of analyte is acceptable: reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. J NAJ-Not Analyzed due to Interferences. I A-Anatyte analyzed in replicate. Reported value is ~averageN of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 - --- - - -- - -- -- --- - VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/200413:00 Sample 2922 FY 2004 Volatiles Scan Facility: Davis Park Rd Program: SF Id/Station: MW20L / Media: GROUNDWATER Project: 04-0323 Gastonia, NC Case No: 32568 D No: 2AE2 Org Contractor: A4 Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/05/2004 09:20 Ending: -------------------------------------------------------- RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 13 0.50 U 0.50 U 0.50 U 0.50 U 22 0.50 U 0.50 U 8.8 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.44 J . 0.50 U 0.50 U 0.50 U 5.0 U UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dichlorodifluoromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane (Freon 11) 1, 1-Dichloroethene ( 1, 1-Dichloroethylene) 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) Acetone Carbon Disulfide Methyl Acetate Methylene Chloride trans-1,2-Dichloroethene Methyl T-Butyl Ether (MTBE) 1, 1-Dichloroethane cis-1,2-Dichloroethene Methyl Ethyl Ketone Bromochloromethane Chloroform 1, 1, 1-Trichloroethane Cyclohexane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene (Trichloroethylene) Methylcyclohexane 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Methyl lsobutyl Ketone Toluene trans-1,3-0ichloropropene 1, 1,2-Trichloroethane Tetrachloroethene (Tetrachloroethylene) Methyl Butyl Ke.tone RESULTS 0.50 U 0.50 U 0.50 U 0.26 J 0,39 J 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ·uG/L UG/L UG/L ANALYTE Dibromochloromethane 1,2-Dibromoethane (EDS) Chlorobenzene Ethyl Benzene Total Xylenes Styrene Bromoform lsopropylbenzene 1, 1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4-Trichlorobenzene 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of ana!yte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. l-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page1of1 - --·-- -- --·---- --VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2922 FY 2004 Project: 04-0323 MISCELLANEOUS COMPOUNDS Facility: Davis Park Rd Program: SF Id/Station: MW20L I Media: GROUNDWATER RESULTS UNITS 3.2 J UG/L ANALYTE 3UNKNOWNS Gastonia, NC Case No: 32568 D No: 2AE2 Data Reported as Identified by CLP Lab -IDs Not Verified Org Contractor: A4 Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/05/2004 09:20 Ending: U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence anatyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to lnterierences. I A-Analyte analyzed in replicate. Reported value is NaverageN of replicates. R-Presence or absence of ana1yte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 - -·--- --·--- ---·--VOLATILES SAMPLE ANALYSIS Sample 2923 FY 2004 Project: 04-0323 EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Produced by: Appleby, Charlie Volatiles Scan Facility: Davis Park Rd Program: SF Gastonia, NC Case No: 32568 Id/Station: MW20U / Media: GROUNDWATER D No: 2AE3 RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 16 0.50 U 0.50 U 0.50 U 0.50 U 23 0.50 U 0.50 U 11 0.50 U 0.50 U 0.50 U 0.14 J 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.49 J 0.50 U 0.50 U 0.50 U 5.0 U UNITS UG/L UG/L UG/L UGIL UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dichlorodifluoromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane (Freon 11) 1, 1-Dichloroethene ( 1, 1-Dichloroethylene) 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) Acetone Carbon Disulfide Methyl Acetate Methylene Chloride trans-1,2-Dichloroethene Methyl T-Butyl Ether (MTBE) 1, 1-0ichloroethane cis-1,2-Dichli::>roethene Methyl Ethyl Ketone Bromochloromethane Chloroform 1, 1, 1-Trichloroethane Cyclohexane Carbon Tetrachloride Benzene 1,2-0ichloroethane Trichloroethene (Trichloroethylene) Methylcyclohexane 1,2-0ichloropropane Bromodichloromethane cis-1,3-Dichloropropene Methyl lsobutyl Ketone Toluene trans-1,3-0ichloropropene 1, 1,2-Trichloroethane Tetrachloroethene (Tetrachloroethylene) Methyl Butyl Ketone Org Contractor: A4 RESULTS 0.50 U 0.50 U 0.50 U 0.27 J 0.40J 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U Requester: Project Leader: JWENDEL Beginning: 02/05/2004 09: 15 Ending: UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dibromochloromethane 1,2-Dibromoethane (EDB) Chlorobenzene Ethyl Benzene Total Xylenes Styrene Bromoform lsopropylbenzene 1, 1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4-Trlchlorobenzene 1,2,3-Trichlorobenzene U-Ana!yte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. J NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate, K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 - -- -- - -- - --- --- ----VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2923 FY 2004 Project: 04-0323 MISCELLANEOUS COMPOUNDS Facility: Davis Park Rd Program: SF Id/Station: MW20U I Media: GROUNDWATER RESULTS UNITS ANALYTE 5.7 J UG/L 5 UNKNOWNS Gastonia, NC Case No: 32568 D No: 2AE3 Data Reported as Identified by CLP Lab· IDs Not Verified Org Contractor: A4 Produced by: Appleby, Charlie Requester; Project Leader: JWENDEL Beginning: 02/05/2004 09:15 Ending: U-Analyte not detected at or above reporting limit. I J-ldentificatlon of analyte is acceptable: reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative·idenlification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reiported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 - -- -- - -- -- -- - ---- --VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2924 FY 2004 Project: 04-0323 Volatiles Scan Facility: Davis Park Rd Program: SF Gastonia, NC Case No: 32568 Id/Station: MW21 / Media: GROUNDWATER D No: 2AE4 RESULTS 0.50 UJ 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 28 J 0.50 U 0.50 UJ 0.50 U 0.50 U 2.6 0.50 U 0.50 U 6.2 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.91 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 1.1 0.50 U 0.50 U 0.35 J 5,0 U UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L. UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Oichlorodlfluoromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane (Freon 11) 1, 1-Dichloroethene ( 1, 1-Dichloroethylene) 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) Acetone Carbon Disulfide Methyl Acetate Methylene Chloride trans-1,2-0ichloroethene Methyl T-Butyl Ether (MTBE) 1, 1-Dichloroethane cis-1,2-Dichloroethene Methyl Ethyl Ketone Bromochloromethane Chloroform 1, 1, 1-Trichloroethane Cyclohexane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene (Trichloroethylene) Methylcyclohexane 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Methyl lsobutyl Ketone Toluene trans-1,3-Dichloropropene 1, 1,2-Trichloroethane Tetrachloroethene (Tetrachloroethylene) Methyl Butyl Ketone Org Contractor: A4 RESULTS 0.50 U 0.50 U 0.50 U 0.48J 2.0 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/04/2004 Ending: UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L. UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dibromochloromethane 1,2-Dibromoethane (EDS) Chlorobenzene Ethyl Benzene Total Xylenes Styrene Bromoform lsopropylbenzene 1, 1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-0ichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4-Trichlorobenzene 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit Repcrting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present: analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte Is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-tdentificalion of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is Haverage" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 11!!!1 -- - -- - --- -- - ---... -VOLATILES SAMPLE ANALYSIS EPA• REGION IV SESD, ATHENS, GA Production Date: 03/03/200413:00 Sample 2924 FY 2004 Project: MISCELLANEOUS COMPOUNDS Facility: Davis Park Rd Program: SF Id/Station: MW21 / Media: GROUNDWATER RESULTS 1.3 J 1.6 JN 1.7 JN 1.7 JN UNITS UG/L UG/L UG/L UG/L ANALYTE UNKNOWN 2-HEPTANONE 2-NONANONE 2-DECANONE 04-0323 Gastonia, NC Case No: 32568 D No: 2AE4 Data Reported as Identified by CLP Lab -IDs Not Verified Org Contractor: A4 Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/04/2004 Ending: U•Ana!yte not detected at or above reporting limit. [ J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. l NJ-Presumptive evidence analyte is present: analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Nol Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 - ------------ - -- - -- -- ------ --VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/200413:00 Sample 2925 FY 2004 Project: 04-0323 Volatiles Scan Facility: Davis Park Rd Program: SF Id/Station: MW21 L / Media: GROUNDWATER Gastonia, NC Case No: 32568 D No: 2AE5 Org Contractor: A4 Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/04/2004 16:40 Ending: ------------------------------------------------------------------------------ RESULTS 0.50 UJ 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 12 J 0.50 U 0.50 UJ 0.50 U 0.50 U 0.62 0.50 U 0.50 U 7.7 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.90 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 1.1 0.50 U 0.50 U 0.25 J 5.0 U UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dichlorodifluoromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane (Freon 11) 1, 1-Dichloroethene (1, 1-Dichloroethylene) 1, 1,2-Trichloro-1,2,2-Trifiuoroethane (Freon 113) Acetone Carbon Disulfide Methyl Acetate Methylene Chloride trans-1,2-Dichloroethene Methyl T-Butyl Ether (MTBE) 1, 1-Dichloroethane cis-1,2-Dichloroethene Methyl Ethyl Ketone Bromochloromethane Chloroform 1, 1, 1-Trichloroethane Cyclohexane Carbon Tetr"achloride Benzene 1,2-Dichloroethane Trichloroethene (Trichloroethylene) Methylcyclohexane 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Methyl lsobutyl Ketone· Toluene trans-1,3-Dichloropropene 1, 1,2-Trichloroethane Tetrachloroethene (Tetrachloroethylene) Methyl Butyl Ketone RESULTS 0.50 U 0.50 U 0.50 U 0.38 J 1.5 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dibromochloromethane 1,2-Dibromoethane (EDS) Chlorobenzene Ethyl Benzene Total Xylenes Styrene Bromoform lsopropylbenzene 1, 1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4-Trichlorobenzene 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of anatyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentiflcation of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is Maverage" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 - -·-- --- - ---·----- --VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2925 FY 2004 Project: 04-0323 MISCELLANEOUS COMPOUNDS Facility: Davis Park Rd Program: SF Id/Station: MW21 L / Media: GROUNDWATER RES UL TS UNITS 5.7 J UG/L 1.5 JN UG/L ANALYTE 5 UNKNOWNS 2-NONANONE Gastonia, NC Case No: 32568 D No: 2AE5 Data Reported as Identified by CLP Lab -IDs Not Verified Org Contractor: A4 ------------------------------------------------------------------ Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/04/2004 16:40 Ending: U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable: reported value is an estimate. UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present: analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable: reported value may be biased high. Actual V?lue expected to be less than the reported value. L-ldentification of analyte is acceptable: reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is ffaverage" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 - ------ . ---:, l!l!!!!!!!!I l!!!l!!!!!!I l!!!!!!!!!!!I-1!!!!!!!!!!!1-- VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2926 FY 2004 Volatiles Scan Facility: Davis Park Rd Program: SF Id/Station: MW21 U / Media: GROUNDWATER Project: 04-0323 Gastonia, NC Case No: 32568 D No: 2AE6 Org Contractor: A4 Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/04/2004 16:30 Ending: -----------------------------------------------------------------------~ RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 13 0.50 U 0.50 U 0.50 U 0.50 U 0.64 0.50 U 0.50 U 8.8 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.90 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 1.0 0.50 U 0.50 U 0.26 J 5.0 U UNITS UG/l UG/L UG/l UG/L UG/L UG/L UG/L UG/L UG/L UGIL UG/L UG/L UG/L UGIL UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dichlorodifluoromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane (Freon 11) 1, 1-Dichloroethene (1, 1-Dichloroethylene) 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) Acetone Carbon Disulfide Methyl Acetate Methylene Chloride trans-1,2-Dichloroethene Methyl T-Butyl Ether (MTBE) 1, 1-Dichloroethane cis-1,2-0ichloroethene Methyl Ethyl Ketone Bromochloromethane Chloroform 1, 1, 1-Trichloroethane Cyclohexane Carbon Tetrachloride s·eni.ene 1,2-Dichloroethane Trichloroethane (Trichloroethylene) Methylcyclohexane 1,2-Dichloropropane Bromodlchloromethane cis-1,3-Dichloropropene Methyl lsobutyl Ketone Toluene trans-1,3-Dichloropropene 1, 1,2-Trichloroethane Tetrachloroethene (Tetrachloroethylene) Methyl Butyl Ketone RESULTS 0.50 U 0.50 U 0.50 U 0.38 J 1.6 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U UNITS UGIL UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UGIL UGIL UG/L UG/L UG/L ANALYTE Dibromochloromethane 1,2-Dibromoethane (EDB) Chlorobenzene Ethyl Benzene Total Xylenes Styrene Bromoform lsopropylbenzene 1, 1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2.4-Trichlorobenzene 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte ls acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentirication of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 - - - - - - -- - - VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 --------------·----------------------------Sample 2926 FY 2004 Project: MISCELLANEOUS COMPOUNDS Facility: Davis Park Rd Program: SF Id/Station: MW21U / Media: GROUNDWATER ANALYTE 3 UNKNOWNS 04-0323 Gastonia, NC Case No: 32568 D No: 2AE6 RESULTS 2.1 J 1.4 JN 0.83 JN 0.50 JN 0.72 JN UNITS UGIL UGIL UGIL UGIL UGIL 2-HEPTANONE CYCLOTETRASILOXANE, OCTAMETHYL 2-OCTANONE 2-NONANONE Data Reported as Identified by CLP Lab· IDs Not Verified Org Contractor: A4 --------------------------Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02104/2004 16:30 Ending: U-Anatyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; anatyte reported as tentative identification. j NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldent1ficat1on of analyte 1s acceptable; reported value may be biased high Actual value expected to be less than the reported value l-ldenlification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. ] NAI-Not Analyzed due to Interferences. J A-Analyte analyzed in replicate. Reported value is Naverage" of replicates. R-Presence or absence of anafyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 ---l!!!!I -- - --- --1!!!!11 IZiiiil VOLATILES SAMPLE ANALYSIS EPA-REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2927 FY 2004 Volatiles Scan Facility: Davis Park Rd Program; SF . Id/Station: MW3 / Media: GROUNDWATER Project: 04-0323 Gastonia, NC Case No: 32568 D No: 2AE7 Org Contractor: A4 Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/04/2004 10:00 Ending: -------------------------------------------------------------------------------- RESULTS 0.50 UJ 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 8.9 J 0.50 U 0.50 UJ 0.50 U 0.50 U 3.0 0.50 U 0.50 U 6.6 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.49 J 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 UJ 5.0 U 0.50 U 0.50 UJ 0.50 UJ 0.18 J 5.0 U UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UGIL UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UGIL UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Oichlorodifluoromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofiuoromethane (Freon 11) 1, 1-Dichloroethene ( 1, 1-Dichloroethylene) 1, 1,2-Trichloro-1,2,2-Trifiuoroethane (Freon 113) Acetone Carbon Disulfide Methyl Acetate Methylene Chloride trans-1,2-Dichloroethene Methyl T-Butyl Ether (MTBE) 1, 1-Dichloroethane cis-1,2-Dichloroethene Methyl Ethyl Ketone Bromochloromethane Chloroform 1, 1, 1-Trichloroethane Cyclohexane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethane (Trichloroethylene) Methylcyclohexane 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Methyl lsobutyl Ketone Toluene trans-1,3-Dichloropropene 1, 1,2-Trichloroethane Tetrachloroethene (Tetrachloroethylene) Methyl Butyl Ketone RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 1,5 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dibromochloromethane 1,2-Dibromoethane (EDS) Chlorobenzene Ethyl Benzene Total Xylenes Styrene Bromoform lsopropylbenzene 1, 1,2,2-Tetrachloroethane 1,3-0ichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4-Trichlorobenzene 1,2,3~ Trichlorobenzene U-Analyte not detected al or above reporting limit. I J-ldentification of analyte is acceptable: reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldenllfication of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 liiil -' - --·-- - - - -... --- - -VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2927 FY 2004 Project: MISCELLANEOUS COMPOUNDS Facility: Davis Park Rd Program: SF Id/Station: MW3 I Media: GROUNDWATER RESULTS UNITS 0.88 J UG/L ANALYTE UNKNOWN 04-0323 Gastonia, NC Case No: 32568 D No: 2AE7 Data Reported as Identified by CLP Lab -IDs Not Verified Org Contractor: A4 Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/04/2004 10:00 Ending: U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit_. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. J NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable: reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 - --·-- -- --·--!!!!!I VOLATILES SAMPLE ANALYSIS EPA -REGION IV SESD, ATHENS, GA Production Date: 03/03/200413:00 Sample 2928 FY 2004 Project: 04-0323 Volatiles Scan Facility: Davis Park Rd Program: SF Id/Station: MW4 / Gastonia, NC Case No: 32568 Media: GROUNDWATER D No: 2AE8 RESULTS 0.50 U 0.33 J 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 11 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 8.6 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U UNITS UGIL UG/L UG/L UG/L UGIL UG/L UGIL UG/L UG/L UGIL UG/L UGIL UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dichlorodifluoromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichloronuoromethane (Freon 11) 1, 1-Dichloroethene (1, 1-Dichloroethylene) 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) Acetone Carbon Disulfide Methyl Acetate Methylene Chloride trans-1,2-Dichloroethene Methyl T-Butyl Ether (MTBE) 1, 1-Dich!oroethane cis-1,2-Dichloroethene Methyl Ethyl Ketone Bromochloromethane Chloroform 1, 1, 1-Trichloroethane Cyclohexane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene (Trichloroethylene) Methylcyclohexane 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Methyl lsobutyl Ketone Toluene trans-1,3-Dichloropropene · 1, 1,2-Trichloroethane Tetrachloroethene (Tetrachloroethylene) Methyl Butyl Ketone Org Contractor: A4 RESULTS 0.50 U 0.50 U 0.50 U 0.14 J 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U Produced by: Appleby, Charlie Requestor: Project Leader: JWENDEL Beginning: 02/04/2004 14:30 Ending: UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Oibromochloromethane 1,2-Dibromoethane (EDB) Ch!orobenzene Ethyl Benzene Total Xylenes Styrene Bromoform lsopropylbenzene 1, 1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4-Trichlorobenzene 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Anatyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; anatyte reported as tentative identification. Reported value is an estimat_e. K-ldentification of ana1yte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to lnterierences. I A-Analyte analyzed in replicate. Reported value is ·average· of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unus~ble. Page 1 of 1 l!!!!!!!I !!!!!! l!!!!!I == 11111;1 ;;;;;; ;;;;;; iiiii liiii liiii -VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/200413:00 Sample 2928 FY 2004 Project: MISCELLANEOUS COMPOUNDS Facility: Davis Park Rd Program: SF Id/Station: MW4 / Media: GROUNDWATER ANALYTE 2 UNKNOWNS 04-0323 Gastonia, NC Case No: 32568 D No: 2AE8 RESULTS 1.6 J 0.74 JN UNITS UG/L UG/L CYCLOTETRASILOXANE, OCTAMETHYL Data Reported as Identified by CLP Lab -IDs Not Verified Org Contractor: A4 Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/04/2004 14:30 Ending: U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. 1 UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte iS present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentificalion of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. l NAI-Not Analyzed due to Interferences. I A-Anatyte analyzed in replicate. Reported value is ~average" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered-unusable. Page 1 of 1 - ---l!!!!!!!!!I I!!!!!! !!!! iiiii iiiii -- - -VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2929 FY 2004 Project: 04-0323 Volatiles Scan Facility: Davis Park Rd Program: SF Id/Station: MW5 / Gastonia, NC Case No: 32568 Media: GROUNDWATER D No: 2AE9 RESULTS 0.50 U 0.32 J 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.11 J 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 1.4 0.50 U 0.50 U 0.50 U 0.13 J 5.0 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dichlorodifluoromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane (Freon 11) 1, 1-Dichloroethene ( 1, 1-Dichloroethylene) 1, 1,2-Trichloro-1,2,2-Triftuoroethane (Freon 113) Acetone Carbon Disulfide Methyl Acetate Methylene Chloride trans-1,2-0ichloroethene Methyl T-Butyl Ether (MTBE) 1, 1-Dichloroethane cis-1,2-0ichloroethene Methyl Ethyl Ketone Bromochloromethane Chloroform 1, 1, 1-Trichloroethane Cyclohexane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene (Trichloroethylene) Methylcyclohexane 1,2-Dichloropropane Bromodichloromethane cis-1.3-0ichloropropene Methyl lsobutyl Ketone Toluene trans-1,3-Dichloropropene 1, 1,2-Trichloroethane Tetrachloroethene (Tetrachloroethylene} Methyl Butyl Ketone Org Contractor: A4 RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/03/2004 10:40 Ending: UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dibromochloromethane 1,2-Dibromoethane (EDB) Chlorobenzene Ethyl Benzene Total Xylenes Styrene Bromoform lsopropylbenzene 1, 1,2,2-Tetrachloroethane 1,3-0ichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4-Trichlorobenzene 1,2,3-Trii::hlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. 1 UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present: analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analy1e is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analy1e is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 -11111111 --I!!!!!!! == liiiiiiil iiii ---VOLATILES SAMPLE ANALYSIS· EPA -REGION IV SESD, ATHENS, GA Production Date: 03/03/200413:00 Sample 2929 FY 2004 Project: MISCELLANEOUS COMPOUNDS Facility: Davis Park Rd Program: SF Id/Station: MWS / Media: GROUNDWATER 04-0323 Gastonia, NC Case No: 32568 D No: 2AE9 Org Contractor: A4 Produced by: App_leby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/03/2004 10:40 Ending: -----------------------------------------------------------------------------------------------------------------------------------------RESULTS UNITS 0.91 J UG/L 0.77 JN UGIL ANALYTE UNKNOWN CYCLOTETRASILOXANE, OCTAMETHYL Data Reported as Identified by CLP Lab -IDs Not Verified ----------------------------------------- U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present: analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is NaverageN of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 - --I!!!!!!! m!!!I lliiiiiil iiiii -- - - -- -VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2930 FY 2004 Project: 04-0323 Volatiles Scan Facility: Davis Park Rd Program: SF Id/Station: MW6 / Gastonia, NC Case No: 32568 Media: GROUNDWATER D No: 2AF0 RESULTS 0.50 U 0.30 J 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.31 J 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 3.0 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 2.8 5.0 U UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UGIL UG/L UG/L UG/L UG/L UG/L UG/L UGIL UG/L UG/L UG/L ANALYTE Dichlorodifluoromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane (Freon 11) 1, 1-Dichloroethene (1, 1-Dichloroethylene) 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) Acetone Carbon Disulfide Methyl Acetate Methylene Chloride trans-1,2-Dichloroethene Methyl T-Butyl Ether (MTBE) 1, 1-Dichloroethane cis-1,2-0ichloroethene Methyl Ethyl Ketone Bromochloromethane Chloroform 1, 1, 1-Trichloroethane Cyclohexane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethane (Trichloroethylene) Methylcyclohexane 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Methyl lsobutyl Ketone Toluene trans-1,3-Dichloropropene 1, 1,2-Trichloroethane Tetrachloroethene (Tetrachloroethylene) Methyl Butyl Ketone Org Contractor: A4 RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.11 J 0.11 J 0.50 U 0.50 U 0.50 U 0.50 U Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/03/2004 15:10 Ending: UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dibromochloromethane 1,2-Dibromoethane (EDB) Chlorobenzene Ethyl Benzene Total Xylenes Styrene Bromoform lsopropylbenzene 1, 1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4-Trichlorobenzene 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present: analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldenlification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 - ----l!l!!!!!I liiii fiiil - ---- --VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2930 FY 2004 Project: 04-0323 MISCELLANEOUS COMPOUNDS Facility: Davis Park Rd Program: SF Id/Station: MW6 / Media: GROUNDWATER ANALYTE 2UNKNOWNS Gastonia, NC Case No: 32568 D No: 2AF0 RESULTS 1.7 J 0.59 JN UNITS UG/L UG/L CYCLOTETRASILOXANE, OCTAMETHYL Data Reported as Identified by CLP Lab· IDs Not Verified Org Contractor: A4 Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/03/2004 15:10 Ending: U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. [ NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L•ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA•Not Analyzed. I NAl•Not Analyzed due to Interferences. ] A-Analyte analyzed in replicate. Reported value is "average" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 - -- - - l!!!!!!!I . !!!!I -= liiii1 - - --·--VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2931 FY 2004 Project: 04-0323 Volatiles Scan Facility: Davis Park Rd Program: SF Id/Station: MW? / Gastonia, NC Case No: 32568 Media: GROUNDWATER D No: 2AF1 RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.23 J 0.50 U 0.50 U 5.0 U 0.50 U 0.24 J 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UGIL UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UGIL UG/L UG/L UG/L ANALYTE Dich1orodifluoromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane (Freon 11) 1, 1-Dichloroethene ( 1, 1-Dichloroethylene) 1, 1,2-Trichloro-1,2,2-Trifiuoroethane (Freon 113) Acetone Carbon Disulfide Methyl Acetate Methylene Chloride trans-1,2-Dichloroethene Methyl T-Butyl Ether (MTBE) 1, 1-Dichloroethane cis-1,2-Dichloroethene Methyl Ethyl Ketone Bromochloromethane Chloroform 1, 1, 1-Trichloroethane Cyclohexane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene (Trichloroethylene) Methylcyclohexane 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Methyl lsobutyl Ketone Toluene trans-1,3-Dichloropropene 1, 1,2-Trichloroethane Tetrachloroethene (Tetrachloroethylene) Methyl Butyl Ketone Org Contractor: A4 RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02103/2004 11 :48 Ending: UNITS UG/L UG/L UG/L UG/L UG/L UG/L. UG/L UGIL UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dibromochlorornethane 1,2-Dibromoethane (EDB) Chlorobenzene Ethyl Benzene Total Xylenes Styrene Bromoform lsopropylbenzene 1, 1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4-Trlchlorobenzene 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence.analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present: analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable: reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. l A-Analyte analyzed in replicate. Reported value is "average" of replicates. R-Presence or absence of analyle can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 - -l!l!!!!I l!!!!!!I !!!!!I == a; iiiiii iiiil - - -----VOLATILES SAMPLE ANALYSIS EPA-REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2931 FY 2004 Project: MISCELLANEOUS COMPOUNDS Facility: Davis Park Rd Program: SF Id/Station: MW? I Media: GROUNDWATER RESULTS UNITS ANALYTE 2.4 J UG/L 3 UNKNOWNS 04-0323 Gastonia, NC Case No: 32568 D No: 2AF1 Data Reported as Identified by CLP Lab -IDs Not Verified Org Contractor: A4 Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/03/2004 11 :48 Ending: U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limlt is an estimate. N-PrEisumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. j NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate, Reported value is "average~ of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 - -- --- --== liiii -... - --VOLATILES SAMPLE ANALYSIS EPA-REGION IV SESD, ATHENS, GA Production Date: 03/03/200413:00 Sample 2932 FY 2004 Project: 04-0323 Volatiles Scan Facility: Davis Park Rd Program: SF Id/Station: MWS / Gastonia, NC Case No: 32568 Media: GROUNDWATER D No: 2AF2 RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 0.50 U 1.2 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 0.16 J 5.0 U UNITS UGIL UG/L UG/L UG/L UG/L UG/L UG/L UG/L UGIL UG/L UGIL UGIL UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dichlorodifluoromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofiuoromethane (Freon 11) 1, 1-Dichloroethene ( 1, 1-Dichloroethylene) 1, 1,2-Trichloro-1,2,2-Trifiuoroethane (Freon 113) Acetone Carbon Disulfide Methyl Acetate Methylene Chloride trans-1,2-Dichloroethene Methyl T-Butyl Ether (MTBE) 1, 1-Dichloroethane cis-1,2-Dichloroethene Methyl Ethyl Ketone Bromochloromethane Chloroform 1, 1, 1-Trichloroethane Cyclohexane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene (Trichloroethylene) Methylcyclohexane 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Methyl lsobutyl Ketone Toluene trans-1,3-0ichloropropene 1, 1,2-Trichloroethane Tetrachloroethene (Tetrachloroethylene) Methyl Butyl Ketone Org Contractor: A4 RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/03/2004 10:21 Ending: UNITS UGIL UG/L UG/L UG/L UG/L UGIL UG/L UG/L UG/L UG/L UGIL UG/L UG/L UG/L UG/L ANALYTE Dibrom6chloromethane 1,2-Dibromoethane (EDS) Chlorobenzene Ethyl Benzene Total Xylenes Styrene Bromoform lsopropylbenzene 1, 1,2,2-Tetrachloroethane 1,3-0ichlorobenzene 1,4-0ichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4-Trichlorobenzene 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. l NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is ftaverage" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 -I!!!!!!!!!! --liii iiiil ------VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2932 FY 2004 Project: MISCELLANEOUS COMPOUNDS Facility: Davis Park Rd Program: SF Id/Station: MW8 / Media: GROUNDWATER RESULTS UNITS ANALYTE 1.5 J UG/L 2 UNKNOWNS 04-0323 Gastonia, NC Case No: 32568 D No: 2AF2 Data Reported as Identified by CLP Lab; IDs Not Verified Org Contractor: A4 Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/03/2004 10:21 Ending: U-Anafyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present: analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present: analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is Haverage" of replicates. R-_Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 - --- - --I!!!!! == &iii iiiii --_, --·---VOLATILES SAMPLE ANALYSIS EPA· REGION IV SES□, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2933 FY 2004 Volatiles Scan Facility: Davis Park Rd Program: SF Id/Station: MW9 / Media: GROUNDWATER Project: 04-0323 Gastonia, NC Case No: 32568 D No: 2AF3 Org Contractor: A4 -·····------------------------------------- RESULTS 0.50 U 0.30 J 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.16 J 0.50 U 0.88 5.0 U 0.50 U 0.14 J 0.50 U 0.50 U 0.50 U 0.50 U 0.52 7.8 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 0.39 J 5.0 U UNITS UG/L UGIL UG/L UGIL UG/L UG/L UG/L UGIL UG/L UG/L UG/L UGIL UG/L UGIL UG/L UG/L UGIL UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dichlorodifluoromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane (Freon 11) 1, 1-Dichloroethene (1, 1-Dichloroethylene) 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) Acetone Carbon Disulfide Methyl Acetate Methylene Chloride trans-1,2-Dichloroethene Methyl T-Butyl Ether (MTBE) 1, 1-Dichloroethane cis-1,2-Dichloroethene Methyl Ethyl Ketone Bromochloromethane Chloroform 1, 1, 1-Trichloroethane Cyclohexane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene (Trichloroethylene) Methylcyclohexane 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Methyl lsobutyl Ketone Toluene trans-1,3-Dichloropropene 1, 1,2-Trichloroethane Tetrachloroethene (Tetrachloroethylene) Methyl Butyl Ketone RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0,50 U Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/03/2004 15:37 Ending: UNITS UGIL UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UGIL UG/L UG/L UG/L UG/L ANALYTE Oibromochloromethane 1,2-Dibromoethane (EDB) Chlorobenzene Ethyl Benzene Total Xylenes Styrene Bromoform lsopropylbenzene 1, 1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-0ichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1 ;2,4-Trichlorobenzene 1,2,3-Trichlorobenz.ene --------------------·-····-··------------------------------------------------------------- U-Analyte not detected at or above reporting limit. J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. j NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceplable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldenlification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. J A-Analyte analyzed in replicate. Reported value is "average" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 - -----l!!!!!I &iii iiii - -- - -VOLATILES SAMPLE ANALYSIS EPA-REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2933 FY 2004 Project: MISCELLANEOUS COMPOUNDS Facility: Davis Park Rd Program: SF Id/Station: MW9 / Media: GROUNDWATER RESULTS UNITS ANALYTE 2.8 J UG/L 4 UNKNOWNS 04-0323 Gastonia, NC Case No: 32568 D No: 2AF3 Org Contractor: A4 Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/03/2004 15:37 Ending: ---------------------------------·-------- Data Reported as Identified by CLP Lab -IDs Not Verified U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. j NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due lo Interferences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 --- - - l!!!l!!!!I . !!!!II liiii -· --·----·-VOLATILES SAMPLE ANALYSIS EPA -REGION IV SESD, ATHENS, GA Production Date: 03/03/200413:00 Sample 2934 FY 2004 Project: 04-0323 Volatiles Scan Facility: Davis Park Rd Program: SF Id/Station: TB I Gastonia, NC Case No: 32568 Media: TRIP BLANK -WATER D No: 2AF4 RESULTS 0.50 U 0.33 J 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U. 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.42 J 0.50 U 0.50 U 0.50 U 5.0 U UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UGIL UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UGIL UG/L UG/L UG/L UG/L UG/L ANALYTE Oichlorodifluoromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichloronuoromethane (Freon 11) 1, 1-Dichloroethene (1, 1-Dichloroethylene) 1, 1,2-Trichloro-1,2,2-Triftuoroethane (Freon 113) Acetone Carbon Disulfide Methyl Acetate Methylene Chloride trans-1,2-Dichloroethene Methyl T-Butyl Ether (MTBE) 1, 1-Dichloroethane cis-1,2-0ichloroethene Methyl Ethyl Ketone Bromochloromethane. Chloroform 1, 1, 1-Trichloroethane Cyclohexane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethene (Trichloroethylene) Methylcyclohexane 1,2-Dichloropropane Bromodichloromethane cis-1,3-0ichloropropene Methyl lsobutyl Ketone Toluene trans-1,3-Dichloropropene 1, 1,2-Trichloroethane T etrachloroethene (T etrachloroethylene) Methyl Butyl Ketone Org Contractor: A4 RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 0210312004 09:00 Ending: UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dibromochloromethane 1,2-Dibromoethane (EDB) Chlorobenzene Ethyl Benzene Total Xylenes Styrene Bromoform lsopropylbenzene 1, 1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4-Trichlorobenzene 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. j J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 - liiiii ---- --- - -----VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2934 FY 2004 Project: 04-0323 MISCELLANEOUS COMPOUNDS Facility: Davis Park Rd Program: SF Id/Station: TB/ Media: TRIP BLANK. WATER RESULTS UNITS ANALYTE Gastonia, NC Case No: 32568 D No: 2AF4 2.0 J UG/L 0.79 JN UG/L 3UNKNOWNS CYCLOTETRASILOXANE, OCTAMETH Data Reported as Identified by CLP Lab -IDs Not Verified Org Contractor: A4 Produced by: Appleby, Charlie Requester; Project Leader: JWENDEL Beginning: 02/03/2004 09:00 Ending: U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable: reported value is an estimate. I UJ-Analyte not detected at or above reporting limit Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-Jdentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAl-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 - __ : --!!!!!! . !!!!! == liiiii liiii iiiil ------ --VOLATILES SAMPLE ANALYSIS EPA· REGION IV SESD, ATHENS, GA Production Date: 03/03/2004 13:00 Sample 2936 FY 2004 Project: 04-0323 Volatiles Scan Facility: Davis Park Rd Program: SF Gastonia, NC Case No: 32568 Id/Station: MW 18 I Media: GROUNDWATER D No: 2AF5 RESULTS 0.50 U 0.50 U 0,50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.14 J 5.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.15 J 4.2 0.50 U 0.50 U 0.50 U 0.50 U 5.0 U 0.50 U 0.50 U 0.50 U 9.9 5.0 U UNITS UG/L UG/l UG/L UG/l UG/l UG/l UG/l UG/l UG/l UG/l UG/l UG/l UG/L UG/l UGIL UGIL UG/l UG/l UG/l UG/l UG/l UG/L UGIL UG/l UG/l UG/l UG/l UG/l UG/l UG/L UG/l UG/l UG/l UG/l UG/l ANALYTE Oichlorodifluoromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane (Freon 11) 1, 1-Dichloroethene (1, 1-Dichloroethylene) 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) Acetone Carbon Disulfide Methyl Acetate Methylene Chloride trans-1,2-Dichloroethene Methyl T-Butyl Ether (MTBE) 1, 1-Dichloroethane cis-1,2-Dichloroethene Methyl Ethyl Ketone Bromoch!oromethane Chloroform 1, 1.1-Trichloroethane Cyclohexane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethane (Trichloroethylene) Methylcyclohexane 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Methyl lsobutyl Ketone Toluene trans-1,3-Dichloropropene 1, 1,2-Trichloroethane T etrachloroethene (T etrachloroethylene) Methyl Butyl Ketone Org Contractor: A4 RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02105/2004 11 :03 Ending: UNITS UG/L UG/l UG/l UG/L UG/L UG/L UG/l UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Oibromochloromethane 1,2-Dibromoethane (EDS) Chlorobenzene Ethyl Benzene Total Xylenes Styrene Bromoform lsopropylbenzene 1, 1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-0ichlorobenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4-Trichlorobenzene 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable: reported value is an estimate. UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. - N-Presumptive evidence analyte is present: analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentificalion of analyte is acceptable: reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 Ii.iii iiiiiii liiiil - - ---- - - ----VOLATILES SAMPLE ANALYSIS EPA -REGION IV SESD, ATHENS, GA Production Date: 03/03/200413:00 Sample 2936 FY 2004 Project: 04-0323 MISCELLANEOUS COMPOUNDS Facility: Davis Park Rd Program: SF Id/Station: MW 18 / Media: GROUNDWATER RESULTS UNITS ANALYTE 3.3 J UG/L 3 UNKNOWNS Gastonia, NC Case No: 32568 D No: 2AF5 Data Reported as Identified by CLP Lab -IDs Not Verified Org Contractor: A4 Produced by: Appleby, Charlie Requester: Project Leader: JWENDEL Beginning: 02/05/2004 11 :03 · Ending: U-Analyte not detected at or above reporting limit. I J-tdentification of analyte is acceptable: reported value is an estimate. 1 UJ-Anatyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present: analyte reported as tentative identification. I NJ-Presl.Jmptive evidence analyte is present; analyte reported as tentative Identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L•ldentiftcation of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. ] A·Analyte analyzed in replicate. Reported value is "average" of replicates. R-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 -