HomeMy WebLinkAboutNCD981021157_20050525_New Hanover County Airport Burn Pit_FRBCERCLA LTRA_Monitoring Report - May 2005 Sampling Event-OCRI
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1{B) [g @ & n w [g m)
u-n[ MM 2 ;;005 I~
MONITORING REPORT SUPERFUND SECT/OIV
MAY 2005 SAMPLING EVENT
NEW HANOVER COUNTY AIRPORT
BURN PIT SUPERFUND SITE
WILMINGTON, NORTH CAROLINA
MAY 25,2005
PREPARED FOR:
NEW HANOVER COUNTY, THE CITY OF WILMINGTON AND CAPE FEAR
COMMUNITY COLLEGE
WILMINGTON, NORTH CAROLINA
CATLIN PROJECT NO.194-040
PREPARED BY:
CATLIN ENGINEERS AND SCIENTISTS
P. O. BOX 10279
WILMINGTON, NORTH CAROLINA 28404-0279
(910) 452-5861
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TABLE OF CONTENTS
LIST OF ACRONYMS
1.0 PURPOSE
2.0 SITE GROUNDWATER MONITORING WELLS
3.0 SITE MONITORING PLAN
4.0 SITE ACTIVE REMEDIATION ACTIVITIES
4.1 PULSE AIR SPARGE (PAS)
4.1.1 Pulse Air Sparge Description
4.1.2 Performance
5.0 SUMMARY OF SURFICIAL GROUNDWATER TABLE DATA
6.0 SUMMARY OF GROUNDWATER QUALITY TESTING
6.1 FIEW MEASUREMENT (DISSOLVED OXYGEN)
6.2 GROUNDWATER SAMPLING
6.3 GROUNDWATER QUALITY -EPA METHOD 602
7.0 CONCLUSION AND RECOMMENDATIONS
7.1 CONCLUSIONS
7.2 RECOMMENDATIONS
8.0 LIMITATIONS
TABLES
PAGE
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TABLE 1
TABLE2
TABLE3
TABLE4
SUMMARY OF MONITORING WELL CONSTRUCTION DATA AND
GROUNDWATER TABLE ELEVATIONS AS OF MAY 2, 2005
HISTORICAL GROUNDWATER TABLE ELEVATIONS
SUMMARY OF CURRENT GROUNDWATER LABORATORY RESULTS
SUMMARY OF HISTORICAL GROUNDWATER LABORATORY
RESULTS
New Hano,•er County Burn Pit; 94040_mon_rpt_MAY05.doc
CATUN Project No. 194-040
CATUN Engineers and Scientists
May2005
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FIGURE 1
FIGURE2
FIGURE3
FIGURE4
FIGURES
FIGUJRE 6
FIGURES
GENERAL LOCATION USGS TOPOGRAPHIC QUADRANGLE
SITE MAP WITH CURRENT MONITORING WELL LOCATIONS
SITE MAP WITH CURRENT PULSE AIR SPARGE (PAS) LOCATIONS
SITE MAP WITH GROUNDWATER TABLE CONTOURS AS OF
MAY2,2005
SITE MAP WITH BENZENE CONCENTRATIONS AS OF
MAY 2,2005
SITE MAP WITH LOCATIONS OF PULSE SPARGE ZONES
APPENDICES
APPENDIX A
APPENDIXB
LABORATORY ANALYTICAL REPORTS AND CHAIN OF
CUSTODY DOCUMENTS
BENZENE CONCENTRATIONS VS. TIME GRAPH
New Hanover County Burn Pit; 94040_mon_rpt_MAY0S.doc
CATLIN Project No. 194-040
CATLIN Engineers and Scientists
May2005
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2000 Guidelines
2001 Guidelines
2LGWQS
ARO
AS
AST
BDL
BN
BNA
BQL
BLS
BTEX
CAP
CATLIN
CFR
Cr
CSA
CNP
CPT
DEM
DIPE
DO
DOD
DPT
DWQ
DWM
DTW
EAD
EDB
EMD
EPA
EPH
EQB
Fe
FID
FOD
FRO
FT
GCL
GIS
GPS
LIST OF ACRONYMS
Groundwater Section Guidelines for Investigation and Remediation of Soil and
Groundwater.
Guidelines for Assessment and Corrective Action, North Carolina Underground Storage
Tank Section (Effective July I, 2001)
NCAC Tl5A:02L Groundwater Quality Standards
Asheville Regional Office
Air Sparge
Aboveground Storage Tank
Below Detection Limit
Base/Neutral (extractables)
Base/Neutral/Acid (extractables)
Below Quantitation Limit
Below Land Surface
Benzene, Toluene, Ethylbenzene, Xylenes
Corrective Action Plan
CATLIN Engineers and Scientists (Formerly RC&A)
Code of Federal Regulations
Chromium
Comprehensive Site Assessment
Carbon Nitrogen Phosphorous
Cone Penetrometer Test
Division of Environmental Management
Diisopropyl Ether
Dissolved Oxygen
Department of Defense
Direct Push Technology
Division of Water Quality
Division of Waste Management
Depth to Water
Environmental Affairs Department
Ethylene di-bromide
Environmental Management Division
Environmental Protection Agency
Extractable Petroleum Hydrocarbons
Environmental Quality Branch
Iron
Flame Ionization Detector
Foreign Object Debris
Fayetteville Regional Office
Feet
Gross Contaminant Level
Geographic Information System
Global Positioning System
New Hanover County Burn Pit; 94040_mon_rpt_MAY0S.doc
CATUN Project No. 194-040
CATUN Engineers and Scientists
May2005
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Guidelines Vol. I
Guidelines Vol. II
HDPE
1/C
ID
I&E
IGWQS
!PE
LANTDIV
LSA
LUST
m-
m
MADEP
MCALF
MCAS
MCB
MCOLF
MDL
mg/Kg
mg/L
MRO
MSCC
MSL
MTBE
µg/Kg
µg/L
NA
NIA
NC
NCAC
NCDENR
NCDOC
NCDOT
NCSP
NCSPA
NE-
NM
NMT
NS
0-
OVA
Groundwater Section Guidelines for Investigation and Remediation of Soil and Groundwater,
Volume I, Sources Other Than Petroleum Underground Storage Tanks (May 1998)
Groundwater Section Guidelines for Investigation and Remediation of Soil and Groundwater,
Volume II, Petroleum Underground Storage Tanks (January 2, 1998)
High Density Polyethylene
Industrial/Commercial
Identification
Installations and Environment Department
Interim Groundwater Quality Standards
Isopropyl Ether
Atlantic Division
Limited Site Assessment
Leaking Underground Storage Tank
meta
meter
Massachusetts Department of Environmental Protection
Marine Corps Auxiliary Landing Field
Marine Corps Air Station
Marine Corps Base
Marine Corps Outlying Landing Field
Method Detection Limit
Milligrams per Kilogram
Milligrams per Litre
Mooresville Regional Office
Maximum Soil Contaminant Concentration
Mean Sea Level
Methyl tertiary butyl ether
Micrograms per Kilogram
Micrograms per Litre
Not Analyzed
Not Applicable
North Carolina
North Carolina Administrative Code
North Carolina Department of Environment and Natural Resources
North Carolina Department of Corrections
North Carolina Department of Transportation
North Carolina State Plane
North Carolina State Ports Authority
None Established
Not Measured
No Measurable Thickness
Not Sampled
ortho
Organic Vapor Analyzer
New Hanover County Burn Pit; 94040_mon_rpt_MAY0S.doc
CATLIN Project No. 194-040 ii
CATLIN Engineers and Scientists
May2005
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p-
PAS
PAH
Pb
PPB
PPM
PIO
PQL
PVC
RBCA
RCRA
Res
ROI
RRO
sow
STGW
SVE
SVOC
TDHF
TCLP
TIC
TKN
TOC
TPH
us
uses
USEPA
USGS
UST
voe
VPH
WaRO
WiRO
WSRO
para
Pulse Air Sparge
Polynuclear Aromatic Hydrocarbons
Lead
Parts Per Billion
Parts Per Million
Photo Ionization Detector
Practical Quantitation Limit
Polyvinyl chloride
Risk-Based Corrective Action
Resource Conservation and Recovery Act
Residential
Radius of Influence
Raleigh Regional Office
Scope of Work
Soil-to-Groundwater
Soil Vapor Extraction
Semi Volatile Organic Compound
Toxicologically Defined Hydrocarbons Fractions
Toxicity Characteristic Leaching Procedure
Tentatively Identified Compound
Total Kjeldahl Nitrogen
Top of Casing
Total Petroleum Hydrocarbons
United States
Unified Soil Classification System
United States Environmental Protection Agency
United States Geological Survey
Underground Storage Tank
Volatile Organic Compounds
Volatile Petroleum Hydrocarbons
Washington Regional Office
Wilmington Regional Office
Winston-Salem Regional Office
New Hanover County Burn Pit; 94040_mon_rpt_MAY0S.doc
CATLIN Project No. 194-040 l1I
CATLIN Engineers and Scientists
May2005
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1.0
2.0
MONITORING REPORT
MAY 2005 SAMPLING EVENT
NEW HANOVER COUNTY AIRPORT BURN PIT SUPERFUND SITE
WILMINGTON, NORTH CAROLINA
MAY 25,2005
CATLIN PROJECT NO. 194-040
PURPOSE
The purpose of this report is to present data regarding surficial groundwater quality and
remediation efforts (July 2004 through May 2005) at the New Hanover County Airport Bum
Pit Superfund Site on Gardner Drive, Wilmington, North Carolina (see Figure 1). Historic
usage of the site has impacted the site surficial groundwater with dissolved Volatile Organic
Compounds (VOC) in excess of current NCAC Tl 5A:02L North Carolina Groundwater
Quality Standards (2L GWQS). This report focuses on site groundwater remediation and
monitoring efforts completed since the July 2004 sampling event.
SITE GROUNDWATER MONITORING WELLS
Currently, there are sixteen monitoring wells selected to monitor groundwater characteristics on
site (see Figure 2). They are positioned to encompass the compliance boundary to ensure
effective monitoring of the contaminant' plume. The monitoring wells are screened at depths
ranging from approximately one to twenty-eight feet below land surface (BLS). Monitoring
well construction data is provided in Table 1. Monitoring wells within the historic dissolved
benzene plume boundary have been designated performance verification wells and are intended
to provide data points to monitor the reduction of groundwater contaminants. Performance
verification wells include: MWD-001, PVSMW-002, MWD-002, MWS-003, PVMW-010,
PVMW-011, PVMW-014 and PVMW-015. Wells outside the historic dissolved benzene
plume boundary have been designated compliance monitoring wells and are used to evaluate
potential dissolved plume migration. Compliance monitoring wells currently employed to
monitor the groundwater plume boundary include: MWS-004, MWD-006, CMW-007,
CMW-008, CMW-009, CMW-012, CMW-013 and CMW-016.
Performance verification monitoring wells are located in interstitial zones between sparge
points and are used to obtain data regarding contaminant reduction and dissolved oxygen levels,
generally within the deeper portion of the surficial aquifer. One performance verification
monitoring well (PVSMW-002, located in the bum pit source area) is screened from one to ten
feet BLS and is used to verify contaminant reduction within the shallow portion of the surficial
aquifer.
New Hanov,er County Burn Pit; 94040_mon_rpt_MAY0S.doc CA TUN Engineers and Scientists
May2005 CATUN Project No. 194-040 1
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3.0
4.0
SITE MONITORING PLAN
Monthly
CA TUN personnel conduct the following activities on a monthly basis:
• Check and adjust system to ensure proper operation.
• Measure dissolved oxygen (DO) in MWD-002.
Semi-Annually (May and November)
In addition to the monthly activities, CATLIN personnel also conduct the following activities
on a semi-annual basis:
• Check system operation.
•
•
•
Gauge and sample performance verification and compliance monitoring wells per
EPA Method 602.
Measure DO in MWD-002 .
Prepare a monitoring report for submission to USEPA, NCDENR and PRPs. The
report includes:
system status ,
groundwater table contour map
updated groundwater contaminant isoconcentration map
tabulated laboratory analysis summary table
independent laboratory reports
SITE ACTIVE REMEDIATION ACTIVITIES
ln accordance with the site Final Design Remedial Report, the performance goal for
remediating non-compliant VOC concentrations within the impacted site surficial aquifer is 1
ug/L of benzene or as agreed to by involved entities. A pulse air sparge system consisting of
79 injection wells has been designed and installed at the site to remediate the dissolved VOC
groundwater plume. The locations of the current pulse air sparge (PAS) injection wells are
shown on Figure 3.
New Han01•er County Burn Pit; 94040_mon_rpl_MAY0S.doc CAT UN Engineers and Scientists
May2005 CATUN Project No. 194-040 2
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4.1 PULSE AIR SPARGE (PAS)
4.1.1 Pulse Air Sparge Description
Pulse Air Sparge consists of injecting a pulse of ambient air within or below
the contaminated zone of the impacted aquifer, through an air sparge well.
As air is injected into the aquifer, a de-watered sphere grows around the
sparge point. This spherical volume of air continues to grow displacing
groundwater until just before the top of the sphere "breaks through" the
surface of the ground water table. Prior to "breakthrough", the air injection is
terminated and the aquifer is allowed to recharge before the next "pulse".
The intent of this activity is to volatilize dissolved gasoline compounds
within the impacted aquifer, and supply oxygen to indigenous aerobic
microbes. Indigenous aerobic microbe species important in dissolved
gasoline compound degradation utilize dissolved oxygen (DO) from the
aquifer as an electron acceptor to convert dissolved gasoline compounds to
CO2, water, and biomass. Aeration efforts of the PAS system replenish
dissolved oxygen into the aquifer. Studies have repeatedly shown aerobic
microbes, as opposed to anaerobic microbes, biodegrade dissolved gasoline
compounds more rapidly.
4.1.2 Performance
The PAS system performance was optimized during system calibration.
Calibration of the PAS system occurred for approximately two weeks
following system start-up. The calibration period consisted of adjusting
airflow to specific zones in order to optimize performance and abandoning
and re-drilling air sparge wells that were short-circuiting. In addition, during
site visits, CATLIN personnel monitor compressor run times. Since the July
2004 sampling event, the PAS system has operated approximately 70 % of
the time. Periodic power outages have disrupted system operation.
Ultimately, site remediation performance is evaluated by reviewing the
groundwater dissolved gasoline compound concentrations trend over time.
5.0 SUMMARY OF SURFICIAL GROUNDWATER TABLE DATA
Each of the site monitoring well top of casing (TOC) elevations has been surveyed in relation
to mean sea level (MSL). The latest groundwater table depths were obtained at all site
monitoring wells on May 2, 2005. The depth to groundwater table data has been subtracted
from the TOC elevation to determine the site groundwater table elevations as of May 2,
2005. This latest groundwater table data has been summarized on Table 1. To evaluate
surficial groundwater flow direction and gradient, the groundwater elevation data was
entered into a contouring software program (AutoCAD Land Development). Current data
indicates a relatively flat groundwater table beneath the site with noticeable influence from
the pulsed air sparging system. Overall, groundwater flow direction is toward the southwest.
New Hanover County Burn Pit; 94040_mon_rpt_MAY05.doc
CATUN Project No. 194-040 3
CATUN Engineers and Scientists
May2005
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6.0
Groundwater apparent gradient calculated between MWD-002 and MWD-006 is 0.0024
(southwest). Historically, groundwater flow directions have been generally similar to current
observations; however, a northeasterly component of flow normally observed beneath the
northeastern portion of the property was not observed during this event. The latest (May 2,
2005) surficial groundwater table contour data has been illustrated on Figure 4.
SUMMARY OF GROUNDWATER QUALITY TESTING
Prior to system installation, CATLIN personnel conducted a site groundwater sampling event to
provide a pre-construction baseline of the dissolved contaminant plume. As of May 2, 2005,
CA TUN has performed five post system installation sampling events. During each sampling
event, CA TUN personnel recorded selected groundwater field parameter data and obtained
groundwater samples in general accordance with the following procedures.
6.1
6.2
FJEW MEASUREMENT (DISSOLVED OXYGEN)
A groundwater DO measurement was taken from within MWD-002 at a depth of
approximately twenty-one feet BLS on May 2, 2005. The DO measurement was
obtained using a YSI Model 650 multi-parameter water quality instrument and Model
600XL sonde. MWD-002 was chosen to gauge performance of the pulse air sparge
system due to its central location in relation to the site, its position in an interstitial
zone between sparge points and the depth of its screened interval. A DO
measurement of 4.60 mg/L was recorded for MWD-002. The May 2005 DO
measurement of 4.60 mg/L represents an increase from the 3.25 mg/L DO level
recorded during the July 2004 sampling event. DO levels for MWD-002 will
continue to be monitored at the site as proposed.
GROUNDWATER SAMPLING
Prior to sampling, each well was purged to ensure the collected sample was
representative of the surficial aquifer. Purging was performed by first removing a
minimum of three well volumes from each monitoring well using disposable hailers. A
pump was then used to extract groundwater from each well. The extracted groundwater
was delivered to a flow-through cell via clean polyethylene tubing and temperature,
conductivity, and pH were measured using a YSI Model 650 multi-parameter water ' quality instrument with Model 600XL sonde. Measurements were recorded at one
minute intervals until the readings had equilibrated. Once stabilized, the well was
sampled and the recorded data was used to document the selected field parameters.
New Hanover County Burn Pit; 94040_mon_rpt_MAY05.doc CATLIN Engineers and Scientists
May2005 CATLJN Project No. 194-040 4
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6.3
Groundwater samples were obtained from new polyethylene tubing attached to the
discharge end of the test cell. The Model 600XL sonde, as well as the test cell were
cleaned after each sample was collected in accordance with the manufacturer's
instructions. A new set of disposable gloves and bailer were utilized for each sample
collected.
Each sample was placed in laboratory prepared sample glassware labeled with the well
ID, sample date, site name, sampler, and placed in an iced cooler. Samples were
delivered to Paradigm Analytical Laboratories, Inc. (Paradigm; North Carolina
Certification #481) in Wilmington, North Carolina for analysis. To determine
groundwater concentrations (in ug/L) of remnant-dissolved gasoline compounds, all
groundwater samples were analyzed for volatile compounds per EPA Method 602.
GROUNDWATER QUAUTY -EPA METHOD 602
The only EPA Method 602 analyte detected above 2L GWQS was benzene at a
concentration of23.6 ug/L in the groundwater sample collected from monitoring well
MWD-002.
Benzene concentrations as evaluated from latest sample event (May 2, 2005) data,
can be summarized as follows:
~/-'it·;.{M~ \»lf:l;?.··_:/r t~~'.:t•~;,;:;.·; :;,.;r1.:~"ncnze·,1e·,concentra tiOrif ill\ll --"' .,
.C!
?k,·,I?.wen ~ID\ ~!,::tt-,.:m,i,frical;Hilili:.:. ; -'HiSthriC·a1;LO\V:It ~11+~.;::,i-.:n8S"-e11ne~0~ ~i;'JltaiCSt~~;~;
MWD-001 15 <0.5 <0.5 <I
MWD-002 136 4.3 18.6 23.6
MWD-006 3.4 <0.5 3.4 <I
PVMW-011 2.6 <I 2.6 <I
PVMW-014 5 1.5 4.4 0.925 J
PVMW-015 4.1 <I 4.1 0.779 J -J = Estimated concemrat1on, below cahbrat1on range and above Method Detectmn Limit
Figure 5 illustrates the benzene concentrations within the site surficial groundwater as
of May 2, 2005.
The latest groundwater sample analytical results have been summarized on Table 3.
Historical EPA Method 602 analysis results have been summarized on Table 4. A copy
of the Paradigm laboratory report for the latest sample event has been provided in
Appendix A. To illustrate the historical groundwater remediation trend, a graphical
representation of historical benzene concentrations at site monitoring wells MWD-001,
MWD-002, MWS-003, MWD-006, PVMW-011, PVMW-014 and PVMW-015 has
been prepared (see Appendix B).
New Hanm•er County Burn Pit; 94040_mon_rpt_MAY05.doc CATLIN Engineers and Scientists
May2005 CATUN Project No. 194-040 5
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7.0 CONCLUSION AND RECOMMENDATIONS
7.1
7.2
CONCLUSIONS
Based on the field and laboratory data obtained during the most recent monitoring
period, the following conclusions are provided:
Active Remediation System Operation
• The PAS system has been operating properly for approximately 70% of the
period from the July 2004 sampling event to the present.
Surficial Groundwater Quality
The latest groundwater analyses revealed the site surficial groundwater contains
minor concentrations of benzene in excess of applicable 2L GWQS.
In reviewing the historical dissolved contaminant concentration data (Table 4 and
graph in Appendix B), the overall trend indicates a progressive decline in benzene
concentrations at all· monitoring well locations. Compared to the baseline data,
MWD-002 exhibited a rise to 23.6 ug/L from 18.6 ug/L and PVMW-014 decreased to
<1 ug/L from 4.4 ug/L. In contrast to the July 2004 sampling event, MWD-002
decreased to 23.6 ug/L from 69 ug/L. Currently, only MWD-002 contains a non-
compliant concentration of benzene.
Benzene concentrations do not appear to be migrating upwards in the water column
as evidenced from the sample results collected from monitoring wells MWD-002 and
PVSMW-002. PVSMW-002 (screened to 10 feet below land surface (BLS)), which
is in close proximity to MWD-002 (screened to 27 feet BLS), continued to display
benzene concentrations below 2L GWQS.
RECOMMENDATIONS
CA TUN recommendations are based on a review of the current site conditions and
are as follows:
• Continue with the monitoring and maintenance schedule outlined in the Final
Remedial Design Report.
• Focus remediation efforts of the pulsed air sparge system to zones southwest of
PVMW-011, specifically zones 1, 2, 3, 6, 7, 8, 9, 12, 13, and 14 (see Figure 6).
• Continue semi-annual monitoring activities as outlined in Section 3.0 Site
Monitoring Plan.
New Hanover County Burn Pit; 94040_mon_rpt_MAY05.doc CATUN Engineers and Scientists
May2005 CATUN Project No. 194-040 6
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8.0 LIMITATIONS
The field and groundwater data evaluated as part of this monitoring report provide isolated
data points and may not represent conditions at every location in the project area. Analyses
and conclusions of this report, being based on interpolation between data points at the project
area, may not be completely representative of all site conditions. Conclusions and
recommendations of this monitoring program and report are based on the best available data
in an effort to comply with current regulatory requirements.
New Hanover County Burn Pit; 94040_mon_rpt_MAY0S.doc CATLIN Engineers and Scientists
May2005 CATLIN Project No. 194-040_ 7
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TABLES
New Hanol'er County Burn Pit; 94040_mon_rpt_MAY05.doc
CATUN Project No. 194-040
CATLJN Engineers and Scientists
May2005
-- - - -- - - -- --- -- - -- -
TABLE 1 SUMMARY OF MONITORING WELL CONSTRUCTION DATA AND GROUNDWATER TABLE ELEVATIONS AS OF MAY 2, 2005
New Hanover County Airport Burn Pit Superfund Site Page 1 of 3
MWD-001 1992 5/2/2005 17.5 17.5-27.5 27.5 33.51
MWD-002 1992 5/2/2005 17 17-27 27 33.27
PVSMW-002 5/28/02 5/2/2005 1-10 10 33.46
MWS-003 1992 5/2/2005 5 5-15 15 33.34
MWS-004 1992 5/2/2005 5 5-14.5 15 32.31
MWD-005 1/4/00 5/2/2005 12 12-22 22 32.21
MWD-006 4/4/01 5/2/2005 14 14-24 24 32.06
CMW-007 1/4/01 5/2/2005 12 12-22 22 33.16
CMW-008 5/31/02 5/2/2005 3 3-23 23 34.27
NHC Airport Burnpit Superfund Site; 194040_mw canst-water elev data MAY OS.xis
CATLIN Project No. 194-040
31.26 6.03 0
30.72 5.72 0
30.38 6.20 0
30.76 6.59 0
29.81 5.21 0
29.86 4.94 0
30.26 5.59 0
30.40 5.67 0
31.50 6.71 0
27.48
27.55
27.26
26.75
27.10
27.27
26.47
27.49
27.56
Performance Verification
Monitoring Well
Performance Verification
Monitoring Well
Performance Verification
Monitoring Well
Performance Verification
Monitoring Well
Compliance Monitoring
Well
Monitoring Well···
Compliance Monitoring
Well
Compliance Monitoring
Well
Compliance Monitoring
Well
CATLIN Engineers and Scientists
May2005
- --- -- - - -- - - - -- ----TABLE 1 SUMMARY OF MONITORING WELL CONSTRUCTION DATA AND GROUNDWATER TABLE ELEVATIONS AS OF MAY 2, 2005
New Hanover County Airport Burn Pit Superfund Site Page 2 of 3
CMW-009 5/30/02 5/2/2005 3 3-23 23 33.22
PVMW-010 5/30/02 5/2/2005 4 4-24 24 32.78
PVMW-011 5/30/02 5/2/2005 4 4-24 24 33.43
CMW-012 5/30/02 5/2/2005 3 3-23 23 32.85
CMW-013 5/30/02 5/2/2005 2 2-27 27 33.53
PVMW-014 5/28/02 5/2/2005 4 4-24 24 32.16
PVMW-015 5/28/02 5/2/2005 4 4-23 23 31.51
CMW-016 6/3/02 5/2/2005 3 3-23 23 32.53
P-1 1998 5/2/2005 0 0-7 7 32.41
NHC Airport Burnpit Superfund Site; 194040_mw const-water elev data MAY OS.xis
CATLIN Project No. 194-040
30.46 5.82 0
30.10 5.39 0
30.69 6.04 0
30.11 5.42 0
30.86 6.21 0
29.39 5.98 0
28.77 4.58 0
29.85 5.73 0
29.54 7.35 0
27.40 Compliance Monitoring
Well
27.39 Performance Verification
Monitoring Well
27.39 Performance Verification
Monitoring Well
27.43 Compliance Monitoring
Well
27.32 Compliance Monitoring
Well
26.18 Performance Verification
Monitoring Well
26.93 Performance Verification
Monitoring Well
26.80 Compliance Monitoring
Well
25.06 Piezometer ***
CATLIN Engineers and Scientists
May2005
--- --- -- -- --- --- ---TABLE 1 SUMMARY OF MONITORING WELL CONSTRUCTION DATA AND GROUNDWATER TABLE ELEVATIONS AS OF MAY 2, 2005
New Hanover County Airport Burn Pit Superfund Site Page 3 of 3
P-2 1998 5/2/2005 0 0-8 8 31.55 30.28 4.69 0 26.86 Piezometer ***
T-12 11/25/98 NM 2 2-14.5 14.5 33.59 NM NM NM NM Monitoring Well •••
T-13 12/22/98 5/2/2005 5 5-15 15 32.19 29.61 6.06 0 26.13 Monitoring Well •••
T-14 12/22/98 5/2/2005 5 5-15 15 33.10 30.10 6.61 0 26.49 Monitoring Well ··•
T-15 12/22/98 5/2/2005 5 5-15 15 32.44 29.99 6.31 0 26.13 Monitoring Well ··•
T-16 1/3/01 5/2/2005 17 17-27 27 32.39 30.39 5.51 0 26.88 Monitoring Well ··•
TMW-1 9/30/94 NM 40 40-45 45 33.02 NM NM NM NM Telescoping Monitoring
we11 •••
TMW-2 9/30/94 NM 38.5 38.5-43.5 43.5 33.21 NM NM NM NM Telescoping Monitoring
we11 ••• ·
* Reference pol!1t for all elevations is based on Mean Sea Level
*" If free product is present in a we11, ground water elevation should be calculated by: [Top of Casing Elevation• Depth to Water]+ [free product thickness x (specific gravity of free product)]
*"* Well is not being sampled as part of current monitoring network.
ft BLS = feet below land surface
NM = Not Measured
NHC Airport Burnpit Superfund Site; 194040_mw const-water elev data MAY OS.xis CA TUN Engineers and Scientists
CATUN Project No. 194-040 May 2005,
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TABLE 2 HISTORICAL GROUNDWATER TABLE ELEVATIONS Page J of 3
Date: May 2, 2005 New Hanover County Airport Burn Pit Superfund Site
-····-~\J'2,:t1Q.f!J;;~ : NT
if,1.PJ\~!~-~;! ·:irfABLE jifi1ilf,· G'iioUNnwATER 000 vTf ,,~ii;l~,;_q!_~,~tl1:-1;1,.!'""--: _-,-'t:.": \11'.!!!E~ .
ll:"Jl;f.\'3'iol ,~-~(Fl\) ,
6/11/2002 33.51 9.43 NMT 24.08
9/4/2003 33.51 4.39 NMT 29.12
11/3/2003 33.51 3.77 NMT 29.74
MWD-001 1/712004 33.51 4.57 NMT 28.94
4/1/2004 33.51 4.41 NMT 29.10
7/21/2004 33.51 8.73 NMT 24.78
5/2/2005 33.51 6.03 NMT 27.48
6/11/2002 33.27 9.21 NMT 24.06
9/4/2003 33.27 4.50 NMT 28.77
11/3/2003 33.27 3.69 NMT 29.58
MWD-002 1nl2004 33.27 4.46 NMT 28.81
4/1/2004 33.27 4.29 NMT 28.98
7/21/2004 33.27 8.42 NMT 24.85
512/2005 33.27 5.72 NMT 27.55
6/11/2002 33.46 9.52 NMT 23.94
9/4/2003 33.46 5.17 NMT 28.29
11/3/2003 33.46 4.08 NMT 29.38
PVSMW-002 117/2004 33.46 4.92 NMT 28.54
4/1/2004 33.46 4.60 NMT 28.86
7/21/2004 33.46 8.84 NMT 24.62
5/2/2005 33.46 6.20 NMT 27.26
6/11/2002 33.34 9.36 NMT 23.98
9/4/2003 33.34 4.69 NMT 28.65
11/312003 33.34 4.24 NMT 29.10
MWS-003 1n/2004 33.34 5.26 NMT 28.08
4/1/2004 33.34 4.54 NMT 28.80
7/21/2004 33.34 9.31 NMT 24.03
5/2/2005 33.34 6.59 NMT 26.75
6/11/2002 32.31 8.52 NMT 23.79
9/4/2003 32.31 3.27 NMT 29.04
11/3/2003 32.31 3.34 NMT 28.97
MWS-004 1n/2004 32.31 3.67 NMT 28.64
4/1/2004 32.31 3.75 NMT 28.56
7/21/2004 32.31 7.67 NMT 24.64
5/2/2005 32.31 5.21 NMT 27.10
11/312003 32.21 2.85 NMT 29.36
1n/2004 32.21 3.92 NMT 28.29
MWD-005 4/1/2004 32.21 3.86 NMT 28.35
7/21/2004 32.21 8.17 NMT 24.04
5/2/2005 32.21 4.94 NMT 27.27
6/11/2002 32.06 8.75 NMT 23.31
9/4/2003 32.06 3.50 NMT 28.56
11/3/2003 32.06 3.45 NMT 28.61
MWD-006 1n/2004 32.06 3.96 NMT 28.10
4/1/2004 32.06 3.94 NMT 28.12
712112004 32.06 7.96 NMT 24.10
51212005 32.06 5.59 NMT 26.47
6/11/2002 33.16 9.64 NMT 23.52
9/4/2003 33.16 3.66 NMT 29.50
11/3/2003 33.16 3.78 NMT 29.38
CMW-007 ln/2004 33.16 4.27' NMT 28.89
4/112004 33.16 4.13 NMT 29.03
712112004 33.16 8.82 NMT 24.34
512/2005 33.16 5.67 NMT 27.49
NHC BurnpiJ; 194040_J1ist gw elev MAY OS.xis
CATLJN Project No. 194-040
CATLJN Engineers and Scientists
May2005
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TABLE 2 HISTORICAL GROUNDWATER TABLE ELEVATIONS
Date: May 2, 2005 New Hanover County Airport Bum Pit Superfund Site
___ , . 11 KNESS -:•
CMW-008
CMW-009
PVMW-010
PVMW-011
CMW-012
CMW-013
PVMW-014
NHC Burnpit; 194040_1,ist gw elev MAY OS.xis
CA TUN Project No. 194-040
6/11/2002
9/4/2003
11/3/2003
117/2004
4/1/2004
7/21/2004
5/2/2005
6/11/2002
9/4/2003
11/3/2003
117/2004
4/1/2004
7/21/2004
5/2/2005
6/11/2002
9/4/2003
11/3/2003
lfi/2004
4/1/2004
7/21/2004
5/2/2005
6/11/2002
9/4/2003
11/3/2003
117/2004
4/1/2004
7/21/2004
5/212005
6/11/2002
9/4/2003
11/3/2003
117/2004
4/1/2004
7/21/2004
5/2/2005
6/11/2002
9/4/2003
1113/2003
117/2004
4/1/2004
7/21/2004
5/2/2005
6/11/2002
9/4/2003
11/3/2003
117/2004
4/1/2004
7/21/2004
5/212005
34.27 10.51 NMT
34.27 4.58 NMT
34.27 4.67 NMT
34.27 5.32 NMT
34.27 5.17 NMT
34.27 9.79 NMT
34.27 6.71 NMT
33.22 9.22 NMT
33.22 3.25 NMT
33.22 3.42 NMT
33.22 4.21 NMT
33.22 4.22 NMT
33.22 8.57 NMT
33.22 5.82 NMT
32.78 8.65 NMT
32.78 3.25 NMT
32.78 2.87 NMT
32.78 3.94 NMT
32.78 3.67 NMT
32.78 7.91 NMT
32.78 5.39 NMT
33.43 9.37 NMT
33.43 4.49 NMT
33.43 1.19 NMT
33.43 4.62 NMT
33.43 4.49 NMT
33.43 8.63 NMT
33.43 6.04 NMT
32.85 8.92 NMT
32.85 3.42 NMT
32.85 2.63 NMT
32.85 3.93 NMT
32.85 3.96 NMT
32.85 8.25 NMT
32.85 5.42 NMT
31.95 9.53 NMT
31.95 4.44 NMT
33.53 3.42 NMT
33.53 4.67 NMT
33.53 4.61 NMT
33.53 8.65 NMT
33.53 6.21 NMT
32.16 8.63 NMT
32.16 4.45 NMT
32.16 3.18 NMT
32.16 4.74 NMT
32.16 3.45 NMT
32.16 9.10 NMT
32.16 5.98 NMT
23.76
29.69
29.60
28.95
29.10
24.48
27.56
24.00
29.97
29.80
29.01
29.00
24.65
27.40
24.13
29.53
29.91
28.84
29.11
24.87
27.39
24.06
28.94
32.24
28.81
28.94
24.80
27.39
23.93
29.43
30.22
28.92
28.89
24.60
27.43
22.42
27.51
30.11
28.86
28.92
24.88
27.32
23.53
27.71
28.98
27.42
28.71
23.06
26.18
Page 2 of 3
.,
CATUN Engineers and Scientists
May 2005
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TABLE 2 HISTORICAL GROUNDWATER TABLE ELEVATIONS Page 3 of 3
Date: May 2, 2005 New Hanover County Airport Burn Pit Superfund Site
B''"'""'l"~"·,~·~·-rc:i-:·•.e:~~1;tpf".
'"< .. , ' --r:l. . ;· !,"-l'• ' •cfi<'J '-;,·->·" . ~·~~,u~:i:~~1 ~,t"CASING ~•-r . ..1~,t< .. ,,,-;o,~ i t.iF · .~ ....... · --'" j 'I» PTH-10 J!IIL • ·ECEVATIONI '~ ,~-1. -· ~At:"' _;'1PRO ~~?li\+t8~~: ;,~\;,i:~1 •• ~ GROI!I''DWATI;_~ .. ~•-=--• r~•t..:'!J/0~ -~~ ~, ~ "4:~i ~ ~1,£ =-~ ~i(' "" ~,~h~•~ -~ ,;(FJ';), ,1. jk'h(fTS~:;.;/ b~~ni~;! • _ ,~~ :.z:JliO'J'! . i17(1'>1tl1lti.1i1.'...,'~-r,
6/11/2002 31.51 8.32 NMT 23.19
9/4/2003 31.51 2.77 NMT 28.74
PVMW-015 1n12004 31.51 3.07 NMT 28.44
4/1/2004 31.51 3,02 NMT 28.49
7/21/2004 31.51 6.98 NMT 24.53
512/2005 31.51 4.58 NMT 26,93
6/11/2002 32.53 8,90 NMT 23,63
9/4/2003 32,53 3,37 NMT 29.16
11/3/2003 32,53 3.40 NMT 29.13
CMW-016 1/712004 32,53 4.13 NMT 28.40
4/1/2004 32,53 4.23 NMT 28.30
7/21/2004 32.53 8.16 NMT 24.37
5/2/2005 32.53 5.73 NMT 26,80
11/3/2003 32.41 5.29 NMT 27.12
1/7/2004 32.41 5.82 NMT 26.59
P-1 4/1/2004 32.41 5,96 NMT 26.45
7/21/2004 32.41 9.60 NMT 22.81
5/2/2005 32.41 7.35 NMT 25.06
11/3/2003 31.55 2.60 NMT 28,95
1/7/2004 31.55 3.29 NMT 28.26
P-2 4/1/2004 31.55 3.04 NMT 28.51
7/21/2004 31.55 6.61 NMT 24.94
5/2/2005 31.55 4.69 NMT 26.86
11/3/2003 32.19 3.44 NMT 28.75
lll/2004 32.19 4.37 NMT 27.82
T-13 4/1/2004 32.19 4.51 NMT 27.68
7/21/2004 32.19 8.40 NMT 23.79
512/2005 32.19 6.06 NMT 26.13
11/3/2003 33.10 4.48 NMT 28.62
1/7/2004 33.10 5.00 NMT 28.10
T-14 4/1/2004 33.10 4.95 NMT 28.15
7/21/2004 33.10 9.00 NMT 24.10
5/2/2005 33.10 6.61 NMT 26.49
11/3/2003 32.44 3.78 NMT 28.66
lll/2004 32.44 4.21 NMT 28.23
T-15 4/1/2004 32.44 4.09 NMT 28.35
7/21/2004 32.44 8.19 NMT 24.25
512/2005 32,44 6.31 NMT 26.13
11/3/2003 32.39 3,62 NMT 28.77
lll/2004 32,39 4.20 NMT 28.19
T-16 4/1/2004 32.39 3.91 NMT 28.48
7/21/2004 32.39 7.31 NMT 25,08
5/2/2005 32.39 5.51 NMT 26.88
• Top of casing elevation is referenced to mean sea level (Top of casing is elevated above ground level.)
NMT • No Measurable Thickness
NHC Burnpit; JJ14040_1,ist gw elev MAY OS.xis
CATUN Project No. 194-040
CATLJN Engineers and Scientists
Moy ZOOS
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Page I of I
TABLE 3 SUMMARY OF CURRENT GROUNDWATER LABORATORY RESULTS
Date: May 2005 New Hanover County Airport Burn Pit Superfund Site
w z w N z w w z m w ..J N > z :c w I-m w
J!lt,Sir;,ll,(0Eliill:1~"1,, -.. · 2f'Gwas· "·' 1 29 .,, --c:"~-.i<lfl-..:..,,,:;,~.l;r.;,1; .~·, .'11:',d''.::c ._:__
2.32
MWD-002 MWD-002 7.46
PVSMW-002 PVSMW-002 5/2/2005 <1.00 <1.00
MWS-003 MWS-003 5/2/2005 <1.00 <1.00
MWS-·004 MWS-004 5/2/2005 <1.00 <1.00
MWD-006 MWD-006 5/2/2005 <1.00 <1.00
CMW-007 CMW-007 5/2/2005 <1.00 <1.00
CMW-008 CMW-008 5/2/2005 <1.00 <1.00
CMW-009 CMW-009 5/2/2005 <1.00 <1.00
PVMW-010 PVMW-010 5/2/2005 <1.00 0.310 J
PVMW-011 PVMW-011 5/2/2005 <1.00 <1.00
CMW-012 CMW-012 5/2/2005 <1.00 <1.00
CMW-013 CMW-013 5/2/2005 <1.00 <1.00
PVMW-014 PVMW-014 5/2/2005 0.925 J 0.306 J
PVMW--015 PVMW-015 5/2/2005 0.779 J 0.311 J
CMW-016 CMW-016 5/2/2005 <1.00 <1.00
All results in u1:JIL
BQL = Below Quantitation Limits
Shaded areas indicate concentrations greater than the 2L GWQS.
< -Less than quantitation limits.
J = Estimated ,::oncentration, below calibration range and above Method Detection Limit
Client; 194040_cu"ent GW results MAY OS.xis
CATUN Project No. 194-040
w z w ::::,
..J 0 I-
1000
0.832 J
1.28
0.921 J
1.60
1.47
0.490 J
0.736 J
0.810 J
0.876 J
0.866 J
0.976 J
0.980 J
1.24
2.29
2.33
2.31
(IJ w z w IC !IJ ..J > Ww X ~!;: ..J < 0 ..J
I-..J < 0 ..J z
I-<<
530 Varies
<4.00 BOL
3.44J BQL
<4.00 BQL
<4.00 BQL
<4.00 BOL
<2.820 J BQL
<4.00 BOL
<2.618 J BQL
<4.00 BQL
<4.00 BQL
<4.00 BQL
<4.00 BQL
1.290 J BQL
1.346 J BQL
1.349 J BQL
<2.666 J BQL
CAT UN Engineers and Scientists
May2005
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TABLE 4 SUMMARY OF HISTORICAL GROUNDWATER LABORATORY RESULTS
Date: May 2005
MWD-001
MWS-001
MWD-002
MWS-002
New Hanover County Airport Burn Pit Superlund Site
w z w ~ w m
29 1,000
"' w z ~ ► ><
-' ~
530
MW0•001 4/17/1991 ~~~-~};. 8.5J 2.0J 25.3J
MW0-001 51711991 f~i7.J~S,-ai·~f--'7-'-.4'-+---"1.::SJ:.._+-·:::2.:c9·c.1J'-/
MW0-001 11/19/1991 8.8 1.1J <0.5
1.4J <0.5
<0.5 <0.5
MWD-001 6/8/1993 00,,,,~5~ 19 1.3J <0.5
MWD-001 10/5/1994 <0.5 <0.5 <0.5 <0.5
MWD-001 6/11/2002 <0.5 6.0 <0.5 <1.5
MWD-001 9/5/2003 <1 3.3 <1 <4
MWD-001 1n12004 <1 3.5 <1 <4
MWD-001 4/1/2004 <1 3.3
MWD-001 7/21/2004 <1 2.92 <1
MWD-001 5/2/2005 <1 2.32 0.832 J <4
MWS-001 6/11/2002 <0.5 <0.5 <0.5 <1.5
MWD-002 4/17/1991 '.?'?f;b!Ql.rn f~34!~l 14J 82J
MWD-002 517/1991 ',)Jil{!J1111i,j !!ll!i3)J]i( 13J 82J
2.0J
35.9
MWD-002 6122/1998 f;\l!(fa'j:lf! 1!!¥_3r9~ 4.1 23.2
MWD-002 6/25/1998 ~f~~ ~~~\ 2.5 27.4
115
21.6
MWD-002 7/23/1998 ~~~ 26.9 2.1 20.8
MWD-002 7/30/1998 ~4J~-1.1 2.3 <1.5
MWD-002 1/16/2001 ~36'.,?~ 14.8 <0.5 17.8
MWD-002 6/11/2002 6.8 <0.5 4.8
MWD-002 4/1/2004 ;(3?.IW 10 <1 <4
MWD-002 7/21/2004 ~&Jft~ 18.2 <1 23.68
1.28 3.44 J
MWS-002 6/11/2002 <0.5 <0.5 <0.5 <1.5
NHC Burnpil; 194040_historical GW MAY OS.xis
CA.TUN Project l\'o. 194.fJ40
Page I o/4
CA TUN Engineers and Scientists
May2005
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TABLE 4 SUMMARY OF HISTORICAL GROUNDWATER LABORATORY AESUL TS
Date: May 2005
ANALYTICAL METHOD· EPA Method 602
~/i!7-'lffl ~-!\ !l.i\\t,. ; .f,
1:/9<?mp()und ofC~nCeni('
~'~:,(·· ~~:: '£·.•'-·-(:!.'::ht,¾iio¼s,~
~_:1t&i·' '7i11n~ti,Ji"A ' l'' , a · 1• .. ::JJ·,,-~ I :coii~· _k..," .. ,. ' ~ • ..ir,,.,:;-t.
·>t'~,1.:-·;\v21fGWOS.·~~1:,~-Jtt-l>?eV'-:.11,l-t,\d:;.,'1~'4il-,,r:t:;,2!::;;m:~;;<.i;hli ,, , ;;1
PVSMW-002 6/11/2002
PVSMW-002 9/4/2003
PVSMW-002 tn/2004 PVSMw-oo:~ PVSMW-002 4/1/2004
PVSMW-002 7/21/2004
PVSMW-002 512/2005
MWS-003 4/17/1991
MWS-003 Sn/1991
MWS-003 11/19/1991
MWS-003 7n/1992
MWS-003 12/9/1992
MWS-003 6/9/1993
MWS-003 10/5/1994 MWS-003
MWS-003 1/16/2001
MWS-003 6/11/2002
MWS-003 9/4/2003
MWS-003 1n12004
MWS-003 4/1/2004
MWS-003 7/21/2004 ' .
MWS-003 5/2/2005
MWS-004 4/17/1991
MWS-004 5n/1991
MWS-004 7n/1991
MWS-004 11/19/1991
MWS-004 12/9/1992
MWS-004 6/9/1993
MWS-004 10/5/1994 MWS-004
MWS-004 1/16/2001
MWS-004 6/11/2002
MWS-004 9/4/2003
MWS-004 1/8/2004
MWS-004 4/1/2004
MWS-004 7/21/2004
MWS-004 512/2005
MWD-005 MWD-005 1/16/2001
MWD-005 6/11/2002
Nl/C Burnpit; /94040_historical GW MAY OS.xis
CATUN Project No. 194-040
w z w N z w m
1
<0.5
<1
<1
<1
<1
<1
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<5
k.~~~~11:~
<0.5
<1
<1
<1
<1
<1
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<1
<1
<1
<1
<1
<0.5
<0.5
New Hanover County Airport Burn Pit Superfund Site
w u, z w
w z
N w z ... w w ► m z >< ... w ... ► ::, "' :c ... I-I-0 0 w I-I-
29 1,000 530
<0.5 <0.5 <1.5
<1 <1 <4
<1 <1 <4
<1 <1 <4
<1 <1 <5.54
<1 0.921 J <4
<0.5 0.89J <1.5
<0.5 <0.5 0.77J
<0.5 <0.5 <1.5
<0.5 <0.5 <1.5
<0.5 <0.5 <1.5
<0.5 <0.5 <1.5
<5 <5 <10
0.5 <0.5 2.4
<0.5 <0.5 <1.5
<1 <1 <4
<1 <1 <4
<1 <1 <4
<1 <1 <4
<1 1.50 <4
<0.5 <0.5 <1.5
<0.5 <0.5 <1.5
<0.5 0.52J <1.5
<0.5 <0.5 <1.5
<0.5 <0.5 <1.5
<0.5 <0.5 <1.5
<0.5 <0.5 <1.5
<0.5 <0.5 <1.5
<0.5 <0.5 <1.5
<1 <1 <4
<1 <1 <4
<1 <1 <4
<1 <1 <4
<1 1.47 <4
<0.5 <0.5 <1.5
<0.5 <0.5 <0.5
Page 2 of 4
CA TUN Engineers and Scientists
May2005
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TABLE 4 SUMMARY OF HISTORICAL GROUNDWATER LABORATORY RESULTS
Date: May 2005 New Hanover County Airport Burn Pit Superfund Site
ANALYTICAL METHOD· EPA Method 602
".-'j::~:: "''""F~'! ~.l:-,_;· .:~i'~g '1~ Jr f.Concern · .\,.t •
1 ,*\\1' :;i' •··''-"4*rJV-'' .~.i;u,,,,-·~·1;,
.!\l;"'~ ;J 1§!,Tple;/ : •~tl?~~i. "i~ .;-il!1Dlft t'C liected" ,,:f.....,'"' -•'--',;½/ ~! .\: 0 r . • •-. ! .,, . -~~ '"'~'
~-"("•~,;~~1,:;,~, ,.;.·-,;;,,A. ~,.,-~;.r-r:r,;,.,.'i;' ,._ • -r 1, 2t: GWQS'(Jig/1.:) ifll:-'-," -, ; ',i1 p:~'4'!'.* ]l,i;'"l¾'f!Q~••:k'~J+~•-t,,~< " W ,,.me ,, , '., • , ,,.,.,, 1"" •<
MWD-006 4/12/2001
MWD-006 6/11/2002
MWD-006 9/4/2003
MWD-006 MWD-006 1/8/2004
MWD-006 4/1/2004
MWD-006 7/21/2004
MWD-006 5/2/2005
CMW-007 6/11/2002
CMW-007 9/5/2003
CMW-007 1n/2004 CMW-007
CMW-007 4/1/2004
CMW-007 7/21/2004
CMW-007 5/2/2005
CMW-008 6/11/2002
CMW-008 9/5/2003
CMW-008 ,n12004 CMW-008 CMW-008 4/1/2004
CMW-008 7/21/2004
CMW-008 5/2/2005
CMW-009 6/11/2002
CMW-009 9/5/2003
CMW-009
CMW-009 1/7/2004
CMW-009 4/1/2004
CMW-009 7/21/2004
CMW-009 5/2/2005
PVMW-010 6/11/2002
PVMW-010 9/5/2003
PVMW-010
PVMW-010 1/7/2004
PVMW-010 4/1/2004
PVMW-010 7/21/2004
PVMW-010 5/2/2005
NIIC Burnpil; J9,t040_historical GW MAY OS.xis
CATUN Project No. /94-040
w "' z w w z
N w z ... w w w ► z ID z >< w ... w ... N ► :, " z :,: ... .... w .... 0 0 ID w .... ....
1 29 1,000 530
<0.5 <0.5 <0.5 <1.5
~;t3j~Ji <0.5 <0.5 3.8
:~0:,;sJr~ <1 <1 <4
<1 <1 <1 <4
<1 <1 <1 <4
<1 <1 <1 <4
<1 <1 0.490 J <2.820 J
<0.5 <0.5 <0.5 <1.5
<1 <1 <1 <4
<1 <1 <1 <4
<1 <1 <1 <4
<1 <1 <1 <4
<1 <1 0.736J <4
<0.5 <0.5 <0.5 <1.5
<1 <1 <1 <4
<1 <1 <1 <4
<1 <1 <1 <4
<1 <1 <1 <4
<1 <1 0.810J <2.618 J
<0.5 <0.5 <0.5 <1.5
<1 <1 <1 <4
<1 <1 <1 <4
<1 <1 <1 <4
<1 <1 <1 <4.29
<1 <1 0.876J <4
<0.5 <0.5 <0.5 <1.5
<1 <1 <1 <4
<1 <1 <1 <4
<1 <1 <1 <4
<1 1.57 <1 <4.73
<1 0.310 J 0.866 J <4
Page 3 of 4
GATUN Engineers and Scientists
May2005
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TABLE 4 SUMMARY OF HISTORICAL GROUNDWATER LABORATORY RESULTS
Date: May 2005 New Hanover County Airport Bum Pit Superfund Site
ANALYTICAL METHOD· EPA Method 602 ,.
w z
!!{iii~ w N z ·,'iCOI~ w [,..,,,,.~-m
i,~\~~"~".-:~~aill .(\!,ti •... ~ 1&~~:W-""'#""wl.Ji',,,ffef;i, '" ,:w~-' 1
PVMW-011 6/11/2002 ~Ii{fffl
PVMW-011 9/5/2003 <1
PVMW-011 lll/2004 <1 PVMW-011
PVMW-011 4/1/2004 <1
PVMW-011 7/21/2004 <1
PVMW-011 512/2005 <1
CMW-012 6/11/2002 <0.5
CMW-012 9/5/2003 <1
CMW-012 1n/2004 <1
CMW-012
CMW-012 4/1/2004 <1
CMW-012 7/21/2004 <1
CMW-012 5/2/2005 <1
CMW-013 6/1112002 <0.5
CMW-013 9/5/2003 <1
CMW-013 1/7/2004 <1 CMW-013 CMW-013 4/1/2004 <1
CMW-013 7/21/2004 <1
CMW-013 5/2/2005 <1
PVMW-014 6/11/2002 W#:fJ~~
PVMW-014 9/4/2003 i'Ft.;~;-b'jj
PVMW-014 tn/2004 iill.t. a:~ll! PVMW-014 i4ii'J;i\~lil PVMW-014 4/1/2004
PVMW-014 7/21/2004 <1
PVMW-014 5/2/2005 0.925 J
PVMW-015 6/11/2002 ~
PVMW-015 9/4/2003 <1
PVMW-015 1/8/2004 <1 PVMW-015
PVMW-015 4/22/2004 <1
PVMW-015 7/21/2004 <1
PVMW-015 5/2/2005 0.779J
CMW-016 6/11/2002 <0.5
CMW-016 9/5/2003 <1
CMW-016 1/8/2004 <1
CMW-016
CMW-016 4/1/2004 <1
CMW-016 7/21/2004 <1
CMW-016 5/2/2005 <1
All results in ugA...
J • Esbmated Value
Shedod areas lndiea:e concentrations greater lhBn the 2L GWQS.
-< -L1155 than quan~tlllon limits.
NIIC Burnpit; J9,1()40_historical GW MAY 05.xls
CATLJN Project No. 194-040
w " z w
w z
N w z -' w w ► m z >< -' w -' ► :, .,
:c -' I-I-0 0 w I-I-
29 1,000 530
2.7 <0.5 2.8
<1 <1 <4
<1 <1 <4
<1 <1 <4
<1 <1 <4
<1 0.976 J <4
<0.5 <0.5 <1.5
<1 <1 <4
<1 <1 <4
<1 <1 <4
<1 <1 <4
<1 0.980J <4
<0.5 <0.5 <1.5
<1 <1 <4
<1 <1 <4
<1 <1 <4
<1 <1 <6.84
<1 1.24 1.290J
1.6 <0.5 2.1
<1 <1 <4
<1 <1 <4
<1 <1 <4
<1 <1 <4
0.306 J 2.29 1.346J
1.4 <0.5 2.1
<1 <1 <4
<1 <1 <4
<1 <1 <4
<1 <1 <4
0.311 J 2.33 1.349J
<0.5 <0.5 <1.5
<1 <1 <4
<1 <1 <4
<1 <1 <4
<1 <1 <4
<1 2.31 <2.666 J
Page4o/ 4
CATLJN Engineers and Scientists
May2005
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FIGURES
New Hanover County Burn Pit; 94040_mon_rpt_MAY05.doc
CATLJN Project No. 194-040
CATLIN Engineers and Scientists
May2005
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i~:f. !a--"------~""'""'.:::"'.="'.'.:" :rr;iti]
))1' /. 1/IU ~ ~,r~~~.~~~~ -~ ~-!~ ~~~-f·n f, ,.: :.? , tf{\1
i ==~~ ~ ) ,~-\,:-
.,
f ' ;tiJ ~•S' t}ff;~~\" tr~-:-:~ rf, ~ ,,..,-,, '''! X (til1~it -
j .• ·;;~.{\
;-C'.f "'il'ic,'iJJ ~:,l{tJ.•/;
~fill,
~ .t !:.. --' ·• .. ~ l
~ . - . -:29 ,. • ~,:~~·:·,_,,'·
·-~ --=, < ' ·,•')> ~ 7,,f_:,.~°;'~~l;f'~l,>< ~
-' ;:\' ,??/', '>
SCALE 124 000
½ O 1 MILE E====E1'=0=00====,==f:::="10"0"0===20=00====3=0"00'=====,=,oo'='='=':',00=0=='='=6000="'':"='='=,':ooo'::'~,:'EE"r'='=='
UTM GRID AND 1970 MAGNETIC NORTH
DECLINATION AT CENTER OF SHEET
111.MINGlOO, NOR111 CAROLINA
""'-£CT
0
CASTLE HAYNE, N.C.
SW/4 ROCKY POINT 15' QUADRANGLE
N 3415-W7752.5/ 7 .5
1970
Till£
1 KILOMETER
QUADRANGLE LOCATION
GENERAL LOCATION NEW HANOVER COUNTY AIRPORT
BURN PIT S\JPERFUND SH£
WILMINGTON, N.C. USGS TOPOGRAPHIC QUADRANGLE
94040 re OCT 2003 SCALE: 1"=2000' t1RA11,1 SY: HCS Q{Er.lm) SY: GRG
FIGURE
1
94040-SEPT 200J--STA 5-0f
11
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T-13 EB
CMW-016 •
8
PVMW-015
(FORMERLY PVMW-7) 8
PVMW-014
DENSE WOODS
E9T-i5
RR SPIKE AT
NOTE:
'l. PAVEMENT INTERSECTION
ELEV -31.08' MSL
1. THIS DRAWING WAS ADAPTED FROM EXISTING
EPA ORA'MNGS AND AERIAL MAPPING.
2. WELL LOCATIONS AND ELEVA TlONS LOCATED
BY STOCKS LAND SURVEYING, P .C. DA TED 24 APRIL 2001.
3. WELLS IN BOLD ARE INCLUDED IN CURRENT MONITORING
NETWORK AND ARE SAMPLED ON A SEMI-ANNUAL BASIS
NO. DESCRIPTION
REVISIONS
T-12 EB
BY DATE
TMW-1
r~
MWS-00
fB MWO 005
BLOCK BLDG. a
Q PVSMW-002 ff MWD-002
DENSE WOODS
TMW-2ffi PVMW-011 8
CMW-013
TREATMENT
BLOCK BLOG.
t::::;J
DENSE WOODS
OESIGNEO BY:
ORA\llt,I BY:
CHEa<EO BY:
APPR0',£0 BY:
OATE:
WJW
H~S
WJW
GRQ:
MAY 2005
PANEL BOX AND
METER BASE 3
PHASE 100 AMP
0 BLOCK BLDG.
194040-MA YOS-02
EN»EEriB ... WWWIIBi8
'MUIINGT()I, N~lli C>.RCUNA
GARDNER DRIVE RR g'IKE
PR<>l'CT
NEW HANOVER COUNTY
AIRPORT BURN PIT SUPERFUND
SITE WILMINGTON, N.C.
CMW-008 •
• CMW-007
(FORMERLY T -17)
LEGEND
EXISTING
E9
[]
8 • 0
SCAIL
DESCRIPTION
80
TYPE II MONITORING WELL (NOT CURRENTLY SAMPLED)
PIEZOMETER
PERFORMANCE VERIFICATION MONITORING WELL
COMPLIANCE MONITORING WELL
POWER POLE
0 80
SCALE IN FEET
SITE MAP WITH CURRENT
MONITORING WELL LOCATIONS
JOO NO. 194-040
'"''"
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\
NOTE:
T-13
$
DENSE WOODS
RR SPIKE AT i PAVEMENT INTERSECTION
ELEV = 31.08' MSL
1. THIS DRA'NING WAS ADAPTED FROM EXISTING
EPA DRAWINGS AND AERIAL MAPPING.
2. 'WELL LOCATIONS AND ELEVATIONS LOCATED
BY STOCKS LAND SURVEYING, P.C. DATED 24 APRIL 2001.
NO. DESCRIPTION
REVISIONS
T-12 $
P-1
\
BY om
CJ J ,{
J';
DESIGNED
ORAY,t,j
CHECKED
BY:
BY:
BY:
APPROVED BY:
DATE
DENSE WO•JDS
CMW-013 .
TREATMENT
PANEL BOX AND
METER BASE 3
PHASE 100 AMP
P-2 0 BLOCK BLOG.
WJW
HCS
WJW
GR!::i
MAY 2005
194040-MA Y05-0J
DENSE WOODS
ENCIIEERS 111d SCENl618
llllMINGTCJ,1, NCIITH CARCllNA
GARDNER DRIVE RR g"' 5>
PRo..ECT
NEW HANOVER COUNTY
AIRPORT BURN PIT SUPERFUND
SITE WILMINGTON, N.C.
®
CMW-007
(FORMERLY T-17)
LEGEND
EXISTING
(J'.
0
~
[QI
0
TITLE
SCALE:
80
DESCRIPTION
TYPE II MONITORING WELL (NOT CURRENTLY SAMPLED)
PERFORMANCE VERIFICATION MONITORING WELL
COMPLIANCE MONITORING WELL
PIEZOMETER
POWER POLE
SPARGE WELL Willi BOX
CONTROL VALVE BOX
0
SCALE IN FEET
80
SITE MAP WITH CURRENT
PULSE AIR SPARGE (PAS)
LOCATIONS
1''=80' JOB NO. 194-040
"""
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NOTE:
1. THIS ORA'MNG WAS ADAPTED FROM EXISTING EPA □RA'MNGS AND
AERIAL MAPPING.
2. 'NELL LOCATIONS AND ELEVATIONS LOCATED BY STOCKS LAND
SURVEYING, P.C. DATED 24 APRIL 2001.
3. DATA FROM MW'D-005 (NOT SHOWN) WAS USED FOR CONTOURING.
4. CONTOUR INTERVAL = 0.20 FOOT
NO. DESCRIPTION
REVISIONS
RR SPIKE AT <i. PAVEMENT INTERSECTION
ELEV = 31.08' MSL
DESIGNED BY:
ORAl'IN BY:
CHEC!<£0 BY:
APPRO'.EO BY:
DATE·
' OATE
I
I
REAH/ENT
I PAN[l BOX AND
MET[R BASE 3
PH .tl3E l 00 AMP I
P-2 ~-~-----
(26.86) w
WJW
J<;.W
WJW
QRQ
BLOCK BLDG.
T-16
(26.88)
MAY 2005
194040-MAYOS-04
CMW-008
(27.56).
---------
• CMW-007
(FORMERLY T-17)
(27.49)
--------------LEGEND ---
DENSE WOODS
ENGi RS.nd9CENl618
YIILM:NGTOO, NOOTH CARll.JNA
GARDNER DRIVE
PRQ.ECT
RR SPIKE "
NEW HANOVER COUNTY
AIRPORT BURN PIT SUPERFUND
SITE WILMINGTON, N.C.
EXISTING
EB
BJ
8 • 0
( )
NM
~
nnr
DESCRIPTION
TYPE II MONITORING WELL (NOT CURRENTLY SAMPLED)
PIEZOMETER
80
PERFORMANCE VERIFICATION MONITORING WELL
COMPLIANCE MONITORING WELL
POWER POLE
GROUNDWATER ELEVATION IN FEET
NOT MEASURED
GROUNDWATER FLOW DIRECTION
GROUNDWATER CONTOUR
0 80
SCALE IN FEET
SITE MAP WITH GROUNDWATER
TABLE CONTOURS AS OF
MAY 2, 2005
JOB NO. 194-040
4
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\ T-L'
(NS) El)
CMW-016
(<1).
8
PVMW-015
(FORMERLY PVMW-7)
(0.779J)
DENSE WOODS
RR SPIKE AT
NOTE:
1l_ PAVEMENT INTERSECTION
ELEV ~ 31.08' MSL
1. THIS DRAWING WAS ADAPTED FROM EXISTING
EPA □RA'MNGS AND AERIAL MAPPING.
2. WELL LOCATIONS AND ELEVATIONS LOCA TEO
BY STOCKS LAND SURVEYING, P .C. DA TED 24 APRIL 2001.
3. WELLS IN BOLD ARE INCLUDED IN CURRENT MONITORING
NETWORK AND ARE SAMPLED ON A SEMI-ANNUAL BASIS.
4. WELLS HIGHLIGHTED IN RED INDICATE LOCATIONS OF NON
COMPLIANT BENZENE CONCENTRATIONS.
NO. 0ESCRIPTI0N
REVISIONS
8
PVMW-014
(0.925J)
T-12
(NS) ffi
BY om
DENSE WOODS
• MWS-004 (<1) BLOCK BLDG.
G
l
"~
TM -~ •
(~ ··~.
MWS-003
DENSE
WOODS ~ (<1)
C
"
PVSMW-0028
(<l) 8 MWD-002
(23.6)
TMW-2E9 (NS)
PVMW-011 .c,
(<1) ..,,
CMW-013 ( < 1)
BLOCK BLDG.
•
CMW-009
( < 1)
t:::}
J
DENSE WOODS
P-, 0
BLOCK BLOG. v-"e
\(NS)
OESIGNEO BY: WJW
ORA'llt-l BY: H!:;:5
CHECKED BY: WJW
APPROVED BY: !:iBG
DATE: MAY 2005
194040-MAYOS-05
\
C£&J'sMB1J
BIOIEERSllldSCENIBI&
'MLMINGTON, NDRTH CAROLINA
GARDNER DRIVE RR KIKE
PRD.ECT
NEW HANOVER COUNTY
AIRPORT BURN PIT SUPERFUND
SITE WILMINGTON, N.C.
CMW-008
(<1) •
• CMW-007
(FORMERLY T -17)
(<1)
LEGEND
EXISTING
El)
8 • □
0
( )
NS
J
TillE
80
DESCRIPTION
TYPE 11 MONITORING WELL (NOT CURRENTLY SAMPLED)
PERFORMANCE VERIFICATION MONITORING WELL
COMPLIANCE MONITORING WELL
PIEZOMETER
POWER POLE
BENZENE CONCENTRATION IN µg/L
NOT SAMPLED
ESTIMATED CONCENTRATION
0 80
SCALE IN FEET
SITE MAP WITH """' BENZENE CONCENTRATIONS AS OF
MAY 2, 2005 5
"' NO. 194-040
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\ T-13 Ell
CM\'V-016
NOTE:
PVMW-OiS
(FORMERLY
1. THIS DRA'MNG WAS ADAPTED FROM EXISTING
EPA DRA'MNGS AND AERIAL MAPPING.
2. WELL LOCATIONS ANO ELEVATIONS LOCATED
@
BY STOCKS LAND SURVEYING, P .C. DA TED 24 APRIL 2001.
3. WEU.S IN BOLO ARE INCLUDED IN CURRENT MONITORING
NETWORK AND ARE SAMPLED ON A SEMI-ANNUAL BASIS
4. ALL EXISTING TEMPORARY OR PERMANENT MONITORING WELLS
INSIDE PLUME BOUNDARY NOT DESIGNATED AS PERFORMANCE
VERIFICATION WELLS SHALL BE PROPERLY ABANDONED TO
PREVENT SHORT CIRCUITING OF SPARGING.
NO. DESCRIPTION
REVISIONS
0 0
ZONE 6
0
@ MWS-004
0
DENSE WOODS
BLOCK BLOG.
0
0
~ONE2 ONE ~ II 8
0 •
CMW-01 3
RR SPIKE AT
PAVEMENT INTERSECTION
ELEV -31.08' MSL
DESIGNED
ORA'NN
CHECKED
BY:
BY:
BY:
APf'RO\!Ol BY:
DATE: BY OATE
TREATMENT
PANEL BOX AND
METER BASE 3
PHASE 100 AMP
P-2 0
WJW
H!;;;S
WJW
GR~
BLOCK BLDG
T-16
MAY 2005
19404-0--MAYOS-06
DENSE WOODS
Bm:WU ..no SCIENIISI&
WIIJHNGTCJI, N~lH CAROJNA
0
ZONE16
0
E)CMW-009
GARDNER DRIVE ~R SPIKE "'
NEW HANOVER COUNTY
AIRPORT BURN PIT SUPERFUND
SITE WILMINGTON, N.C.
(D
CMW-007
(FORMERLY T-I 7)
LEGEND
EXISTING
El
[QI
8
@
0
0
nnr
DESCRIPTION
TYPE II MONITORING WELL (NOT CURRENTLY SAMPLED)
PIEZOMETER
80
PERFORMANCE VERIFICATION MONITORING WELL
COMPLIANCE MONITORING WELL
SPARGE WELL
POWER POLE
0 80
SCALE IN FEET
SITE MAP WITH LOCATIONS
OF PULSE SPARGE ZONES
.OINO. 194-040
"""
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APPENDIX A
LABORATORY ANALYTICAL REPORTS AND
CHAIN OF CUSTODY DOCUMENTS
New Hanover County Burn Pit; 94040_mon_rpt_MAY05.doc
CATLJN Project No. 194-040
CA TUN Engineers and Scientists
May2005
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PARADIGM ANALYTICAL LABORATORIES, INC.
5500 Business Drive
Wilmington, North Carolina 28405
Mr. Rick Garrett
Richard Catlin & Associates
220 Old Dairy Rd.
Wilmington NC 28405
Report Number: Gl28-1506
Client Project: NHC Burnpit
Dear Mr. Garrett: I
(9 I 0) 350-I 903
Fax (910) 350-1557
Enclosed are the results of the analytical services performed under the referenced
project. The samples are certified to meet the requirements of the National
Environmental Laboratory Accreditation Conference Standards. Copies of this report
and supporting data will be retained in our files for a period of five years in the event
they are required for future reference. Any samples submitted to our laboratory will
will be retained for a maximum of thirty (30) days from the date of this report unless
other arrangements are requested.
If there are any questions about the report or the services performed during this project,
please call Paradigm at (910) 350-1903. We will be happy to answer any questions or
concerns which you may have.
Thank you for using Paradigm Analytical Labs for your analytical services. We look
forward to working with you again on any additional analytical needs which you may have.
tical Laboratories, Inc.
N.C. Certification #481 S.C. Certification #99029
\
1 of 30
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PARADIGM ANALYTICAL LABORATORIES, INC.
CASE NARRATIVE
Date: May 11, 2005
Catlin and Associates Project ID: NHC Burnpit
Paradigm Analytical ID: Gl28-1506
Sixteen water samples were received at the laboratory May 3 for analysis of volatile
organic compounds by method 602. The samples were in good condition, within holding
time and temperature limits.
All analyses were completed within holding time and without quality control exception.
Enclosed are the data summary reports with the batch quality control summaries.
N.C. Certification #48 I S.C. Certification #99029
2 of 30
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PARADIGM ANALYTICAL LABORATORIES, INC.
Client Sample ID; CMW-016
Client Project ID: NHC Burnplt
Lab Sample ID: G128-1506-1A
Lab Project ID: G128-1506
Analyte
Benzene
Chlorobenzene
1,2-Dlchlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Ethylbenzene
Toluene
m/p-Xylene
o-Xylene
Surrogate Spike Recoveries
Trifluorotoluene
Comments:
All values corrected for dilution.
BQL = Below quantitation limit.
Results for Volatlles
by GC 602
Result
ug/L
BQL
BQL
BQL
BQL
BQL
BQL
2.31
0.666
BQL
Analyzed By: DCS
Date Collected: 5/2/2005 12:31
Date Received: 513/2005
Matrix: Water
RL MDL Dilution
ug/L ug/L Factor
1.00 0.316 1
1.00 0.298 1
2.00 0.608 1
1.00 0.281 1
2.00 0.56 1
1.00 0.299 1
1.00 0.302 1
2.00 0.608 1
2.00 0.596 1
Spike Spike
Added Result
40 39.5
Date
Analyzed Flags
51512005
51512005
51512005
51512005
515/2005
515/2005
5/512005
51512005 J
5/5/2005
Percent
Recovery
98.8
Reviewed By: Jb-\11
Ge.LIMB.~ Of 3Q
N.C. Certification #481 S.C. Certification #99029
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PARADIGM ANALYTICAL LABORATORIES, INC.
Client Sample ID: PVMW-015
Client Project ID: NHC Burnpit
Lab Sample ID: G128-1506-2A
Lab Project ID: G128-1506
Analyte
Benzene
Chlorobenzene
1,2-Dichlorobenzene
1,3-Dlchlorobenzene
1,4-Dichlorobenzene
Ethylbenzene
Toluene
m/p-Xylene
o-Xylene
Surrogate Spika Recoveries
Trifluorotoluene
Comments:
All values corrected for dilution.
BOL = Below quantitation limit.
Results for Volatiles
byGC602
Result
ug/L
0.779
BQL
BQL
BQL
BQL
0.311
2.33
0.634
0.715
RL
Analyzed By: DCS
Date Collected: 5/212005 12:55
Date Received: 5/3/2005
Matrix: Water
MDL DIiution Date
ug/L ug/L Factor Analyzed
1.00 0.316 1 5/5/2005
1.00 0.298 1 5/5/2005
2.00 0.608 1 5/5/2005
1.00 0.281 1 5/5/2005
2.00 0.56 1 5/5/2005
1.00 0.299 1 5/5/2005
1.00 0.302 1 5/5/2005
2.00 0.608 1 5/5/2005
2.00 0.596 1 5/5/2005
Spika Spika Percent
Added Result Recovery
40 39.0 97.6
Flags
J
J
J
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Reviewed By: lb,,'
GC_LIMS.~ Of 3Q
N.C. Certification #481 S.C. Certification #99029
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PARADIGM ANALYTICAL LABORATORIES, INC.
Client Sample ID: PVMW-014
Client Project ID: NHC Burnpit
Lab Sample ID: G128-1506-3A
Lab Project ID: G128-1506
Analyte
Benzene
Chlorobenzene
1,2-Dlchlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Ethyl benzene
Toluene
m/p-Xylene
o-Xylene
Surrogate Spike Recoveries
Trifluorotoluene
Comments:
All values corrected for dilution.
BQL = Below quantitation limit.
Results for Volatiles
by GC 602
Result
ug/L
0.925
BQL
BQL
BQL
BQL
0.306
2.29
0.632
0.714
Analyzed By: DCS
Date Collected: 5/2/2005 13:20
Date Received: 5/3/2005
Matrix: Water
RL MDL DIiution Date
ug/L ug/L Factor Analyzed
1.00 0.316 1 5/5/2005
1.00 0.298 1 5/5/2005
2.00 0.608 1 5/5/2005
1.00 0.281 1 5/5/2005
2.00 0.56 1 5/5/2005
1.00 0.299 1 5/5/2005
1.00 0.302 1 5/5/2005
2.00 0.608 1 5/5/2005
2.00 0.596 1 5/5/2005
Spike Spike Percent
Added Result Recovery
40 39.0 97.6
Flags
J
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Reviewed By: lb,,,"
GC_UMS.~ Qf 3Q
N.C. Certification #481 S.C. Certification #99029
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PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Volatiles
by GC602
Client Sample ID: MWS-003
Client Project ID: NHC Burnpit
Lab Sample ID: G128-1506-4A
Lab Project ID: G128-1506
Analyte Result RL
Analyzed By: DCS
Date Collected: 5/2/2005 13:40
Date Received: 5/312005
Matrix: Water
MDL Dilution Date
ug/L ug/L ug/L Factor Analyzed
Benzene BQL 1.00 0.316 1 515/2005
Chlorobenzene BQL 1.00 0.298 1 5/512005
1,2-Dichlorobenzene BQL 2.00 0.608 1 51512005
1,3-Dichlorobenzene BQL 1.00 0.281 1 5/512005
1,4-Dichlorobenzene BQL 2.00 0.56 1 515/2005
Ethylbenzene BQL 1.00 0.299 1 51512005
Toluene 1,60 1.00 0.302 1 515/2005
mlp-Xylene BQL 2.00 0.608 1 51512005
o-Xylene BQL 2.00 0.596 1 515/2005
Surrogate Spike Recoveries Spike Spike Percent
Added Result Recovery
Trifluorotoluene 40 37.9 94.6
Comments:
All values corrected for dilution.
BQL = Below quantitation limit.
Flags
Reviewed By: ,z,,_.,,
GC_LIMS_"e' Of 3Q
N.C. Certification #481 S.C. Certification #99029
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PARADIGM ANALYTICAL LABORATORIES, INC.
Client Sample ID: MWS-004
Client Project ID: NHC Burnpit
Lab Sample ID: G 128-1506-5A
Lab Project ID: G128-1506
Analyte
Benzene .
Chloroberzene
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Ethylbenzene
Toluene
m/p-Xylene
a-Xylene
Surrogate Spike Recoveries
Trifluorotoluene
Comments:
All values corrected for dilution.
BQL = Below quantitation limit.
Results for Volatiles
by GC 602
Result
ug/L
BQL
BQL
BQL
BQL
BQL
BQL
1.47
BQL
BQL
RL
Analyzed By: DCS
Date Collected: 5/2/2005 14:00
Date Received: 5/3/2005
Matrix: Water
MDL DIiution Date
ug/L ug/L Factor Analyzed
1.00 0.316 1 5/5/2005
1.00 0.298 1 5/5/2005
2.00 0.608 1 5/5/2005
1.00 0.281 1 5/5/2005
2.00 0.56 1 5/5/2005
1.00 0.299 1 5/5/2005
1.00 0.302 1 5/5/2005
2.00 0.608 1 5/5/2005
2.00 0.596 1 5/5/2005
-Spike Spike Percent
Added Result Recovery
40 37.1 92.8
Flags
Reviewed By: "Nf
GC_LIMS_"7° Qf 3Q
N.C. Certification #481 S.C. Certification #99029
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PARADIGM ANALYTICAL LABORATORIES, INC.
Client Sample ID: CMW-013
Client Project ID: NHC Burnpit
Lab Sample ID: G128-1506-6A
Lab Project ID: G128-1506
Analyte
Benzene
Chlorobenzene
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Ethylbenzene
Toluene
m/p-Xylene
o-Xylene
Surrogate Spike Recoveries
Trifluorotoluene
Comments:
All values corrected for dilution.
BQL = Below quanlitation limit.
Results for Volatiles
by GC602
Result
ug/L
BQL
BQL
BQL
BQL
BQL
BQL
1.24
0.642
0.648
RL
Analyzed By: DCS
Date·collected: 5/2/2005 14:20
Date Received: 5/3/2005
Matrix: Water
MDL DIiution Date
ug/L ug/L Factor Analyzed
1.00 0.316 1 5/5/2005
1.00 0.298 1 5/5/2005
2.00. 0.608 1 5/5/2005
1.00 0.281 1 5/5/2005
2.00 0.56 1 5/5/2005
1.00 0.299 1 5/512005
1.00 0.302 1 5/5/2005
2.00 0.608 1 515/2005
2.00 0.596 1 515/2005
Spike Spike Percent
Added Result Recovery
40 38.7 96.7
Flags
J
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Reviewed By: sz-,.,.,
GC.UMS_"a' Qf 3Q
N.C. Certification #481 S.C. Certification #99029
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PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Volatiles
by GC 602
Client Sample ID: MWD-002
Client Project ID: NHC Bumpit
Lab Sample ID: G128-1506-7A
Lab Project ID: G128-1506
Result
Analyzed By: DCS
Date Collected: 5/2/2005 14:45
Date Received: 5/3/2005
Matrix: Water
RL MDL Dilution Date Analyte
uglL ug/L ug/L Factor Analyzed
Benzene 23.6 1.00 0.316 1 5/5/2005
Chlorobenzene BQL 1.00 0.298 1 5/5/2005
1,2-Dichlorobenzene BQL 2.00 0.608 1 5/5/2005
1,3-Dichlorobenzene BQL 1.00 0.281 1 5/5/2005
1,4-Dichlorobenzene BQL 2.00 0.56 1 5/5/2005
Ethylbenzene 7.46 1.00 0.299 1 5/5/2005
Toluene 1.28 1.00 0.302 1 5/5/2005
m/p-Xylene 1.05 2.00 0.608 1 5/5/2005
o-Xylene 2.39 2.00 0.596 1 5/5/2005
Surrogate Spike Recoveries Spike Spike Percent
Added Result Recovery
Trlfluorotoluene 40 37.5 93.9
Comments:
All values corrected for dilution.
BQL = Below quantitation limit.
Flags
J
Reviewed By: ,..,_.,,
GC.LIMS_~ Of 30
N.C. Certification #481 S.C. Certification #99029
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PARADIGM ANALYTICAL LABORATORIES, INC.
Client Sample ID: PVSMW-002
Client Project ID: NHC Burnplt
Lab Sample ID: G128-1506-8A
Lab Project ID: G128-1506
Analyte
Benzene
Chlorobenzene
1,2-Dichlorobenzene
1,3-Dlchlorobenzene
1,4-Dichlorobenzene
Ethylbenzene
Toluene
m/p-Xylene
a-Xylene
Surrogate Spike Recoveries
Trifluorotoluene
Comments:
All values corrected for dilution.
BQL = Below quantltalion limit.
Results for Volatlles
by GC602
Result
ug/L
BQL
BQL
BQL
BQL
BQL
BQL
0.921
BQL
BQL
RL
Analyzed By: DCS
Date Collected: 5/2/2005 15:05
Date Received: 5/3/2005
Matrix: Water
MDL DIiution Date
ug/L ug/L Factor Analyzed
1.00 0.316 1 5/5/2005
1.00 0.298 1 5/5/2005
2.00 0,608 1 5/5/2005
1.00 0.281 1 5/5/2005
2.00 0.56 1 5/5/2005
1.00 0.299 1 5/5/2005
1.00 0.302 1 5/5/2005
2.00 0.608 1 5/5/2005
2.00 0.596 1 5/5/2005
Spike Spike Percent
Added Result Recovery
40 38.3 95.7
Flags
J
Reviewed By: r;,.,,t
oc_u••-4'0 of 30
N.C. Certification #481 S.C. Certification #99029
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PARADIGM ANALYTICAL LABORATORIES, INC.
Client Sample ID: CMW-012
Client Project ID: NHC Burnplt
Lab Sample ID: G128-1506-9A
Lab Project ID: G128-1506
Analyte
Benzene
Chlorobenzene
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1 .4-Dichlorobenzene
Ethyl benzene
Toluene
m/p-Xylene
a-Xylene
Surrogate Spike Recoveries
Trifluorotoluene
Comments:
All values corrected for dilution.
BQL = Below quantitation limit.
Results for Volatiles
by GC 602
Result
Analyzed By: DCS
Date Collected: 5/2/2005 15:30
Date Received: 5/3/2005
Matrix: Water
RL MDL Dllutlon Date
ug/L ug/L ug/L Factor Analyzed
BOL 1.00 0.316 1 5/5/2005
BOL 1.00 0.298 1 5/5/2005
BQL 2.00 0.606 1 5/5/2005
BQL 1.00 0.281 1 5/5/2005
BQL 2.00 0.56 1 5/5/2005
BQL 1.00 0.299 1 5/5/2005
0.980 1.00 0.302 1 5/5/2005
BQL 2.00 0.608 1 5/5/2005
BOL 2.00 0.596 1 5/5/2005
Spike Spike Percent
Added Result Recovery
40 39.0 97.4
Flags
J
Reviewed By: lZ:Nf
GC.LIMS.'2' 1 Of 30
N.C. Certification #481 S.C. Certification #99029
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PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Volatllea
byGC 602
Client Sample ID: PVMW-011
Client Project ID: NHC Burnpil
Lab Sample ID: G128-1506-10A
Lab Project ID: G128-1506
Result RL
Analyzed By: DCS
Dale Collected: 5/2/2005 16:10
Dale Received: 5/3/2005
Matrix: Water
MDL DIiution Date Analyte
ug/L ug/L ug/L Factor Analyzed
Benzene BQL 1.00 0.316 1 5/5/2005
Chlorobenzene BQL 1.00 0.298 1 5/5/2005
1,2-Dichlorobenzene BQL 2.00 0.608 1 5/5/2005
1,3-Dichlorobenzene BQL 1.00 0.281 1 5/5/2005
1,4-Dichlorobenzene BQL 2.00 0.56 1 5/5/2005
Ethylbenzene BQL 1.00 0.299 1 5/5/2005
Toluene 0.976 1.00 0.302 1 5/5/2005
m/p-Xylene BQL 2.00 0.608 1 5/5/2005
o-Xylene BQL 2.00 0.596 1 5/5/2005
Surrogate Spike Recoveries Spike Spike Percent
Added Result Recovery
Trifluorotoluene 40 38.7 96.8
Comments:
All values corrected for dilution.
BQL = Below quantitalion limit.
Flags
J
Reviewed By: sh»'
GC.LIMS.'212 Of 3Q
N.C. Certification #48 I S.C. Certification #99029
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PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Volatiles
byGC602
. Client Sample ID: PVMW-010
Client Project ID: NHC Burnpll
Lab Sample ID: G128-1506-11A
Lab Project ID: G128-1506
Analyte Result
ug/L
Benzene BQL
Chlorobenzene BQL
1,2-Dichlorobenzene BQL
1,3-Dichlorobenzene BQL
1,4-Dichlorobenzene BQL
Ethylbenzene 0.310
Toluene 0.866
m/p-Xylene BQL
o-Xylene BQL
Surrogate Spika Recoveries
Trifiuorotoluene
Comments:
All values corrected for dilution.
BQL = Below quantitalion limit.
Analyzed By: DCS
Dale Collected: 5/2/2005 0:00
Date Received: 5/3/2005
Matrix: Water
RL MDL DIiution
ug/L ug/L Factor
1.00 0.316 1
1.00 0.298 1
2.00 0.608 1
1.00 0.281 1
2.00 0.56 1
1.00 0.299 1
1.00 0.302 1
2.00 0.608 1
2.00 0.596 1
Spike Spike
Added Result
40 37.3
N.C. Certification #481 S.C. Certification #99029
Data
Analyzed Flags
5/5/2005
5/5/2005
5/5/2005
5/5/2005
5/5/2005
5/5/2005 J
5/5/2005 J
5/5/2005
5/5/2005
Percent
Recovery
93.2
Reviewed By: '\CW'
GC_LIMS_"2'f'3 Of 30
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PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Volatiles
by GC 602
Client Sample ID: CMW-009
Client Project ID: NHC Burnpit
Lab Sample ID: G128-1506-12A
Lab Project ID: G128-1506
Analyte Result
ug/L
Benzene BQL
Chlorobenzene BQL
1,2-Dichlorobenzene BQL
1,3-Dichlorobenzene BQL
1,4-Dichlorobenzene BQL
Ethylbenzene BQL
Toluene 0.876
m/p-Xylene BQL
o-Xylene BQL
Surrogate Spike Recoveries
Trifluorotoluene
Comments:
All values corrected for dilution.
BOL = Below quantitatlon limit.
Analyzed By: DCS
Date Collected: 5/2/2005 0:00
Date Received: 5/3/2005
Matrix: Water
RL MDL DIiution
ug/L ug/L Factor
1.00 0.316 1
1.00 0.288 1
2.00 0.608 1
1.00 0.281 1
2.00 0.56 1
1.00 0.299 1
1.00 0.302 1
2.00 0.608 1
2.00 0.596 1
Spike Spike
Added Result
40 38.3
N.C. Certification #481 S.C. Certification #99029
Date
Analyzed Flags
5/5/2005
5/5/2005
5/5/2005
5/5/2005
5/5/2005
5/5/2005
5/5/2005 J
5/5/2005
5/5/2005
Percent
Recovery
95.8
Reviewed By: lb-(
GC_LIMS.44 Qf 30
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PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Volatiles
by GC 602
Client Sample ID: MWD-001
Client Project ID: NHC Burnpit
Lab Sample ID: G128-1506-13A
Lab Project ID: G128-1506
Analyte Result
ug/L
Benzene BQL
Chlorobenzene BQL
1,2-Dichlorobenzene BQL
1,3-Dichlorobenzene BQL
1,4-Dichlorobenzene BQL
Ethylbenzene 2.32
Toluene 0.832
m/p-Xylene BQL
o-Xylene BOL
Surrogate Spike Recoveries
Trifluorotoluene
Comments:
All values corrected for dilution.
BQL " Below quantitation limit.
Analyzed By: DCS
Date Collected: 5/2/2005 0:00
Date Received: 5/3/2005
Matrix: Water
RL MDL Dllutlon
ug/L ug/L Factor
1.00 0.316 1
1.00 0.298 1
2.00 0.608 1
1.00 0.281 1
2.00 0.56 1
1.00 0.299 1
1.00 0.302 1
2.00 0.608 1
2.00 0.596 1
Spike Spike
Added Result
40 38.6
Date
Analyzed Flags
5/5/2005
5/5/2005
5/5/2005
5/5/2005
5/5/2005
5/5/2005
5/5/2005 J
5/5/2005
5/5/2005
Percent
Recovery
96.5
Reviewed By: l":r,11
GC.LIMS_'2.015 Qf 30
N.C. Certification #481 S.C. Certification #99029
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PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Volatiles
byGC602
Client Sample ID: CMW-007
Client Project ID: NHC Burnpit
Lab Sample ID: G128-1506-14A
Lab Project ID: G128-1506
Analyte Result
ug/L
Benzene BQL
Chlorobenzene BQL
1,2-Dlchlorobenzene BQL
1,3-Dichlorobenzene BQL
1,4-Dlchlorobenzene BQL
Ethylbenzene BOL
Toluene 0,736
m/p-Xylene BOL
a-Xylene BQL
Surrogate Spike Recoveries
Trlfluorotoluene
Comments:
All values corrected for dilution.
BQL = Below quantitation limit.
Analyzed By: DCS
Date Collected: 5/2/2005 0:00
Date Received: 5/3/2005
Matrix: Water
RL MDL DIiution
ug/L ug/L Factor
1.00 0.316 1
1.00 0.298 1
2.00 0.608 1
1.00 0.281 1
2.00 0.56 1
1.00 0.299 1
1.00 0.302 1
2.00 0.608 1
2.00 0.596 1
Spike Spike
Added Result
40 38.4
N.C. Certification #481 S.C. Certification #99029
Date
Analyzed Flags
5/5/2005
5/5/2005
5/5/2005
5/5/2005
5/5/2005
5/5/2005
5/5/2005 J
5/5/2005
5/5/2005
Percent
Recovery
96.1
Reviewed By: JZ,:¥'
GC.LIMS."'16 Of 3Q
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PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Volatiles
by GC 602
Client Sample ID: CMW-008
Client Project ID: NHC Burnpit
Lab Sample ID: G128-1506-15A
Lab Project ID: G128-1506
Analyte Result
ug/L
Benzene BQL
Chlorobenzene BQL
1,2-Dichlorobenzene BQL
1,3-Dichlorobenzene BQL
1,4-Dichlorobenzene BQL
Ethylbenzene BQL
Toluene 0.810
m/p-Xylene 0.618
a-Xylene BQL
Surrogate Spike Recoveries
Trifluorotoluene
Comments:
All values corrected for dilution.
BQL = Below quantitation limit.
Analyzed By: DCS
Date Collected: 5/2/2005 0:00
Date Received: 5/3/2005
Matrix: Water
RL MDL DIiution
ug/L ug/l Factor
1.00 0.316 1
1.00 0.298 1
2.00 0.608 1
1.00 0.281 1
2.00 0.56 1
1.00 0.299 1
1.00 0.302 1
2.00 0.608 1
2.00 0.596 1
Spike Spike
Added Result
40 40.0
N.C. Certification #481 S.C. Certification #99029
Date
Analyzed Flags
5/6/2005
5/6/2005
5/6/2005
5/6/2005
5/6/2005
5/6/2005
5/6/2005 J
5/6/2005 J
5/6/2005
Percent
Recovery
100
Reviewed By: WI'
GC.LIMS.'2."17 Of 3Q
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PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Volatiles
by GC 602
Client Sample ID: MWD-006
Client Project ID: NHC Burnpit
Lab Sample ID: G128-1506-16A
Lab Project ID: G128-1506
Analyte Result
ug/L
Benzene BQL
Chlorobenzene BQL
1,2-Dichlorobenzene BQL
1,3-Dichlorobenzene BQL
1,4-Dichlorobenzene BQL
Ethylbenzene BQL
Toluene 0.490
m/p-Xylene BQL
o-Xylene 0.820
Surrogate Spike Recoveries
Trlfluorotoluene
Comments:
All values corrected for dilution.
BQL = Below quantitation limit.
Analyzed By: DCS
Date Collected: 5/2/2005 0:00
Date Received: 5/3/2005
Matrix: Water
RL MDL DIiution
ug/L ug/L Factor
1.00 0.316 1
1.00 0.298 1
2.00 0.608 1
1.00 0.281 1
2.00 0.56 1
1.00 0.299 1
1.00 0.302 1
2.00 0.608 1
2.00 0.596 1
Spike Spike
Added Result
40 37.6
N.C. Certification #481 S.C. Certification #99029
Date
Analyzed Flags
5/10/2005
5/10/2005
5/10/2005
5/10/2005
5/10/2005
5/10/2005
5/10/2005 J
5/10/2005
5/10/2005 J
Percent
Recovery
94
Reviewed By: lh,¥'
OC_LIMS_'2.°l 8 Of 30
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PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Volatiles
byGC602
Client Sample ID: Method Blank
Client Project ID:
Lab Sample ID: VBLK1050505A
Lab Project ID:
Analyte Result
ug/L
Benzene BQL
Chlorobenzene BQL
1,2-Dichlorobenzene BQL
1,3-Dichlorobenzene BQL
1,4-Dichlorobenzene BQL
Ethylbenzene BQL
Toluene BQL
m/p-Xylene BQL
o-Xylene BQL
Surrogate Spike Recoveries
Trifluorotoluene
Comments:
All values corrected for dilution.
BQL = Below quantitation limit.
Analyzed By: DCS
Date Collected:
Date Received:
Matrix: Water
RL MDL DIiution
ug/L ug/L Factor
1.00 0.316 1
1.00 0.298 1
2.00 0.608 1
1.00 0.281 1
2.00 0.56 1
1.00 0.299 1
1.00 0.302 1
2.00 0.608 1
2.00 0.596 1
Spike Spike
Added Result
40 37.4
N.C. Certification #481 S.C. Certification #99029
Date
Analyzed Flags
5/5/2005
5/5/2005
5/5/2005
5/5/2005
5/5/2005
5/5/2005
5/5/2005
5/5/2005
5/5/2005
Percent
Recovery
93.5
Reviewed By: ~
OC_UMS.'2.°19 Qf 3Q
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PARADIGM ANALYTICAL LABORATORIES, INC.
Control Limits for QC Check/ Laboratory Control Spike
Method: 602 SplkelppbJ : 10
Instrument: gc1
Filename· 050405\040r0101 IXt
QC Limits LCS limits
Comoound
Benzene
Chlorobenzene
1,2-0lchlorobenzene
1,3-Dlchlorobenzene
1,4-Dichlorobenzene
Dllsopropyl ether
Ethylbenzene
MTBE
Toluene
m,1>-Xyiene
o-Xvlene
Flags:
+ = out of QC limits.
, = lab generated limtts.
o = Detected
nnb Qf%1
8.8 88.0
8.7 87.1
8.3 82.7
8,7 87.3
8.0 89.8
10,1 101.0
8,3 BU
8.6 86.6
10.0 88.B
17.2 86.8 a., au
Lower Unner P,(%) Lower u--r
77.0 123.0 88 38 160
80.6 118.S 87 66 136
88.0 132.0 83 37 164
72.6 127.6 87 60 1,1
BU 130.6 80 ,2 1,3
.3.1 168.8 101 30 170
83.0 137.0 83 32 180
,6.B 163.2 88 36 166
77.6 127.0 100 46 148
11.2 188.8 86 D 238
47.8 162A 84 38 184
Reviewed by: r,,.,P
N.C. Certification #481 S.C. Certification #99029
20 of 30
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PARADIGM ANALYTICAL LABORATORIES, INC.
Control Limits for MS-MSD
Method: 602 Splke(ppb] : 10
Instrument: gc1
Sample: 050405\043rtl101.txl
MS: 050505\006rtl101.txl
MSD · 050505\007rtl101 txl
Compound
Benzene
Chlorobenzene
1,2-0lchlorobenzene
1,3-Dlchlorobenzene
1,4-Dlchlorobenzene
Ollsopropyl ether
Ethytbenzene
MTBE
Toluene
m,p-Xylene
o-Xy1ane
Flags:
+ = out of QC limits.
• = lab generated limits.
o = Detected
ND = None Detected
Sam.
1.8
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
pnu
MS MSD MS
10.3 10.1 88
10.7 8,8 107
10.4 10.4 89
9.9 8.6 88
10.1 9.8 101
10.4 10.2 104
10.7 9.1 107
8.8 10.0 88
10.8 10.3 108
20.7 18.4 101
10.0 9.0 100
PIii P Limits
MSD Lower Un=r
u 38 160
99 66 136
88 37 164
86 60 141
88 42 143
102 30 170
86 32 180
80 36 186
103 48 148
82 D 238
80 38 111-4
Reviewed by: ~
N.C. Certification #48 I S.C. Certification #99029
21 of 30
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PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Volatiles
byGC 602
Client Sample ID: Method Blank
Client Project ID:
Lab Sample ID: VBLK1050405C
Lab Project ID:
Analyte Result
ug/L
Benzene BQL
Chlorobenzene BOL
1,2-Dichlorobenzene BQL
1,3-Dlchlorobenzene BQL
1,4-Dichlorobenzene BQL
Ethyl benzene BQL
Toluene BOL
m/p-Xylene BQL
a-Xylene BQL
Surrogate Spike Recoveries
Trifluorotoluene
Comments:
All values corrected for dilution.
BQL = Below quantitation limit.
Analyzed By: DCS
Date Collected:
Date Received:
Matrix: Water
RL MDL DIiution
ug/L ug/L Factor
1.00 0.316 1
1.00 0.298 1
2.00 0.608 1
1.00 0.281 1
2.00 0.56 1
1.00 0.299 1
1.00 0.302 1
2.00 0.608 1
2.00 0.596 1
Spike Spike
Added Result
40 37.1
N.C. Certification #481 S.C. Certification #99029
Date
Analyzed Flags
5/5/2005
5/5/2005
5/5/2005
5/5/2005
5/5/2005
5/5/2005
5/5/2005
5/5/2005
5/5/2005
Percent
Recovery
92.8
Reviewed By: <>,,,I
GC_UMS_,,.22 Of 3Q
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PARADIGM ANALYTICAL LABORATORIES, INC.
Control Limits for QC Check/ Laboratory Control Spike
Method: 602 Spike[ppbj : 10
Instrument: gc1
Filename : 050505\010r{)101 txt
QC Limlt1 LCS LlmH1
Compound
Benzene
Chlorobenzene
1,2-Dlchlorobenzene
1,3-0lchlorobenzene
1,4-Dichlorobenzene
Olisopropyl ether
Ethylbenzene
MTBE
Toluene
m,p-Xylene
o-Xvlene
Fiag1:
+ = out of QC limits.
• = lab generated limits.
o = Detected
nnb Ql%l
10.3 102.7
10.& 105.1
10.2 101.7
8.8 89.2
10.1 100.8
10.4 104.3
10.4 104.1
10.6 104.5
10.6 105.2
20.1 100.7
8.8 88.1
Lower Unna, P,(%1 Lower Uooer
77.0 123.0 103 38 150
80.5 119.5 105 aa 135
68.0 132.0 102 37 154
72.5 127.5 88 50 141
BU 130,5 101 42 143
43.1 158.9 104 30 170
63.0 137.0 104 32 180
46.8 163.2 105· 36 186
77.6 127.0 105 48 148
11.2 188.8 101 D 238
47.6 152.4 88 38 154
Reviewed by: fl->.JI'
N.C. Certification #48 I S.C. Certification #99029
23 of 30
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PARADIGM ANALYTICAL LABORATORIES, INC.
Control Limits for MS-MSD
Method: 602 Splke[ppb]: 10
Instrument: gc1
Sample: 0505051022r0101.txt
MS : 0505051024r0101.txt
MSD • 050505\025r0101 txt
Compound
Benzene
Chlorobenzene
1,2-Dichlorobenzene
1,3-0lchlorobenzene
1,4-0ichlorobenzene
Olisopropyt ether
Ethylbenzene
MTBE
Toluene
m.p-Xylene
o.Xylene
Flags:
+ = out of QC limits.
• = lab generated limits.
D = Detected
No = None Detected
Sam.
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
UO/L PIil
MS MSD MS
10.1 8.8 100
10.6 8.0 106
10.1 8.9 87
10.1 8.8 101
10.2 8.8 100
10.4 10.2 104
10.3 u 103
10.6 9.9 106
10.4 8.8 87
20.4 18.1 98
10.1 8.1 BB
P Limits
MSD Lower UnnAr ·
87 39 150
80 H 131
Bl 37 184
88 60 141
88 42 143
102 30 170
84 32 180
89 36 186
88 48 148
BO D 238
78 38 184
Reviewed by: fir'
N.C. Certification #481 S.C. Certification #99029
24 of 30
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PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Volatiles
by GC602
Client Sample ID: Method Blank
Client Project ID:
Lab Sample ID: VBLK1051005A
Lab Project ID:
Analyte Result
ug/L
Benzene BQL
Chlorobenzene BQL
1,2-Dichlorobenzene BQL
1,3-Dichlorobenzene BQL
1,4-Dlchlorobenzene BQL
Ethylbenzene BQL
Toluene BQL
m/p-Xylene BQL
o-Xylene BQL
Surrogate Spike Recoveries
Trifluorotoluene
Comments:
All values corrected for dilution.
BQL = Below quantitation limit.
Analyzed By: DCS
Date Collected:
Dale Received:
Matrix: Water
RL MDL Dilution
ug/L ug/L Factor
1.00 0.316 1
1.00 0.298 1
2.00 0.608 1
1.00 0.281 1
2.00 0.56 1
1.00 0.299 1
1.00 0.302 1
2.00 0.608 1
2.00 0.598 1 .
Spike Spike
Added Result
40 38.9
N.C. Certification #481 S.C. Certification #99029
Date
Analyzed Flags
5/10/2005
5/10/2005
5/10/2005
5/10/2005
5/10/2005
5/10/2005
5/10/2005
5/10/2005
5/10/2005
Percent
Recovery
97.3
Reviewed By: 'b!f
GC.LIMS.'225 Of 3Q
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PARADIGM ANALYTICAL LABORATORIES, INC.
Control Limits for QC Check/ Laboratory Control Spike
Method: 602 Splk•IPPbl: 10
Instrument : gc1
FIiename • 051005\0101{)101 txt
QC Limit• LCS Limit■
Compound
Benzene
Chlorobenzane
1,2-0lchlorobenzene
1,J.Dlchlorobenzene
1,4-Dlchlorobenzene
Oilsopropyl ether
Ethyl benzene
MTBE
Toluene
m,p-Xylana
o-Xylene
Flags:
• = out of QC limits.
• = lab generated limits.
o = Detected
DDb Ql\11
10.0 100.0
10.1 100.7
10.8 107.8
9.8 98.1
8.1 99.3
10.0 100.4
B.8 98.2
8.8 98.8
10.3 103.3
18.7 93.8
8.3 83.4
Lower Unner P,1%1 Lower Unnar
77.0 123.0 100 31 110
80.S 118.5 101 la 131
BB.O 132.0 108 37 114
72.1 127.1 88 10 141
BU 130.1 88 42 143
43.1 116.8 100 30 170
83.0 137.0 88 32 180
48.8 113.2 88 31 181
77.1 127.0 103 48 148
11.2 188.8 94 D 238
47.8 112.4 13 38 194
Reviewed by: ~I'
N.C. Certification #481 S.C. Certification #99029
26 of 30
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PARADIGM ANALYTICAL LABORATORIES, INC.
Control Limits for MS-MSD
Method: 602 Splke(ppb] : 10
Instrument: gc1
Sample: 051005\018r0101 .txl
MS: 051005\025r0101.txt
MSD • 051005\026r0101 txl
Comaound
Benzene
Chlorobenzene
1,2-0lchlorobenzene
1,3-0lchlorobenzene
1,4-Dlchlorobenzene
Dllsopropyl ether
Ethyl benzene
MTBE
Tcluene
m,p-Xylene
o-Xviene
Flags:
+ " out of QC limits.
• " lab generated limits.
D " Detected
ND " None Detected
Sam.
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ua/L
MS MSD MS
8.8 10A 88
8.7 10.4 87
8.8 10.8 88
8.7 10.8 87
10.0 11.0 100
10.0 10.S 100
8.3 10.S 83
10.2 11.0 102
I.I 10.4 88
18.1 21.3 81
8.1 10.7 81
p %1 P Limits
MSD Lower U···r
104 39 ,so
104 H 135
108 37 184
108 so 141
110 42 143
105 30 170
105 32 180
110 35 181
104 48 148
108 D 238
107 38 184
Reviewed by: 't:l:l"
N.C. Certification #481 S.C. Certification #99029
27 of 30
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PARADIGM ANALYTICAL LABORATORIES, INC.
List of Reporting Abbreviations
and Data Qualifiers
B = Compound also detected in batch blank
BQL = Below Quantitation Limit
DF = Dilution Factor
Dup = Duplicate
E = Estimated concentration, exceeds calibration range.
J = Estimated concentration, below calibration range and above MDL
LCS(D) = Laboratory Control Spike (Duplicate)
MDL = Method Detection Limit
MS(D) = Matrix Spike (Duplicate)
POL = Practical Quantitation Limit
RL = Reporting Limit
RPD = Relative Percent Difference
mg/kg = milligram per kilogram, ppm, parts per million
ug/kg = micrograms per kilogram, ppb, parts per billion
mg/L = milligram per liter, ppm, parts per million
ug/L = micrograms per liter, ppb, parts per billion
% Rec = Percent Recovery
% soilds = Percent Solids
Special Notes:
1) Metals and mercury samples are digested with a hot block, see the standard
operating procedure document for details.
2) Uncertainty for all reported data is less than or equal to 30 percent.
N.C. Certification #48 I S.C. Certification #99029
MI34.011404.1
28 of 30
0 -PARADIGM ANALYTICAL LABORATORIES, INC.
5500 Business Drive, Wilmington, NC 28405 Chain-of Custody Record & Analytical Request COC# 46573 ~
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Client: CJ}O~la/6ERS (
Address: Z 7f> ctr> ;r»11i,\P' RP,
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Quote#: .
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Project ID: NHC. Bl R,J{>[C
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5500 Business Drive, Wilmington, NC 28405 Chain-of Custody Record & Analytical Request Phone: (910)-350-1903 FAX: (910)-350-1557
Oient: CIITU>J ~ltJEiSt~ ~~ject ID: \,.It\ f, !I IBN&
Address• 2 2?> ol.l) tf'l\13.'I ict>
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Page z_ of 2
Report To: Bill$ Gf\RBe1r
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500 Business Drive, Wilmington, NC 28405 Chain-of Custody Record & Analytical Request
hone: (910)-350-1903 FAX: (910)-350-1557
lient: C,gJDr,; h,,,;1,1«,r-:: 'il.
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COC# 46573
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Please specify any special .reporting
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SEE REVERSE FOR
TERMS AND CONDITIONS
iiiil -liiil ---- - - - - - - - - - - - -PARADIGM ANALYTICAL LABORATORIES, INC.
5500 Business Drive, Wilmington, NC 28405 Chain-of Custody Record & Analytical Request
Phone: (910)-350-1903 FAX: (910)-350-1557
Quote#: __________________ _
Contact: 1-RicJs -Gf\\?K\"7T
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Page ____.c-;;':l:,,=----of 2.._
Comments: ,_,. . ..
Please specify any special reporting-.;
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· State Certification Requestea'.
NC __ SC ___ Other __ _
SEE REVERSE FOR
TERMS AND CONDITIONS
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APPENDIXB
BENZENE CONCENTRATIONS VS. TIME GRAPH
New Hanover County Burn Pit; 94040_mon_rpt_MAY05.doc
CATUN Project No. 194-040
CATLIN Engineers and Scientists
May2005
- -
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(1) ... -C:
8 C: 0
0
-l!!!!!!!!I I!!!!!! !!!!I 1!!1111!! liiiiiil ;.;a liiiiii liiii iiiii -- --
Benzene Concentrations vs. Time
New Hanover County Airport Burnpit Superfund Site '"""=====~
100
80
60
40
20
0
Date
:•·,.:~i'.~~:~t-fi .. -~'.~{f~ ,·-.·1t
'" -j~flf',t11ti:,::,'..·~--.~.}};,,:
-~i,~.. ' ~
f!iti; , · · .,,-;ti~l:
PVMW-011
PVMW-014
& RS ..._'{t ~
NOTE: Only wells exhibiting Benzene concentrations
above the 2L GWQS are shown.
.• t~
~,;. ·;~
.;-1,. -24'i::; ·~t5
-