NCD980557656_20020508_NC State University (Lot 86 Farm Unit 1)_FRCBERCLA SAP QAPP_Groundwater Sampling Quality Assurance Plan 2001 - 2002-OCR

•
NC STATE U~IVERSITY·
Michael Townsend
North Carolina State Universit.and-
grant university and a constituent institution
of The University of North Carolina
AA Equal Opportunity/Affirmative Action Em~oyer
http} f,wM,2.ncru.eou/rcsu/ehs
May 8, 2002
Superfund Branch, Waste Managerner:it Division
US EPA Region IV
Atlanta Federal Center
I 00 Alabama Street, SW
Atlanta, GA 30303-3104
Dear Mi.,Townsend:
Enclosed please find two copies of the following final plans.
·• Ground_water Sampling and Analysis Plan, Lot 86, May 2002
• Groundwater Sampling Quality Assurance Plan, Lot 86, May 2002
Office of Finance and Business
Environmental Health and
Public Safety Division
Environmental Health and Safety Center
Campus Box 8007
Raleigh, North Carolina 27695-8007
Director 919.515.4238
Environmental Affairs 91_9.515.6859
Industrial Hygiene 919.515.6860
Health and Safety 919.515.6858
Radiation Protection 919.515.2894
!Fax) 919.515.6307
The plans follow the procedun;s used for previous similar work at the site. I believe that we have made the
corrections and additions requested by David Mattison (NCDENR-Superfund). The plans have also been
provided to Mr. Mattison.
The schedule is for sampling to occur around May 20th.
You had mentioned in a recent conversation the potential of sending an oversight contractor to the site during
he sampling process. To the extent hat I have the right to request anything from the Agency, I am requesting
that you not send an oversight contractor to view this activity. If the Agency has concerns about the sampling
process, it is suggested that Mr. Mattison (who is quite knowledgeable on the subject) provide agency
oversight. The reason for this request is simple economics. The State is in a severe fiscal crisis, and we are
all being called upon to find ways to reduce spending.
If you have any comments on this, please let me know.
Si~,ely,
Pu'~
Enclosure
r cc: __ !)avid.Matison, NCDENR (w/o enclosure)
NOTE
To: David Mattison
From: Duane Knudson ~K
Date: May 8, 2002
Subject: Lot 86 Final Groundwater SAP and QAP
Attached are the proposed final SAP and QAP for groundwater sampling at Lot 86 this
spnng.
I believe that your comments have been address and we have scheduled sampling for
about May 20th•
However, ( of course) if you find deficiencies in the plans, which have the potential to
affect the quality of the data or health and safety of the sampling team, please let me
know before that date and we will make corrections.
Thanks
Duane
Duane Knudson
Environmental Affairs Manager
NC State University
Raleigh, NC 27695
919-515-6859
North Carolina • Department of Environment and Natural
Resources
Michael F. Easley, Governor
William G. Ross Jr., Secretary
Dexter R. Matthews, Director
Mr. Michael Townsend
S uperfund Branch
Waste Management Division
US EPA Region IV
61 Forsyth Street, I 1th Floor
Atlanta, Georgia 30303
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April 29, 2002
RE: Groundwater Sampling Quality Assurance Plan
North Carolina State University Lot 86 NPL Site
Raleigh, Wake County
Dear Mr. Townsend:
The Superfund Section of the North Carolina Department of Environment and Natural
Resources (NC DENR) has received and reviewed the Groundwater Sampling Quality
Assurance Plan for the North Carolina State University (NCSU) Lot 86 National Priority
List Site. The Superfund Section offers the attached comments.
The Superfund Section appreciates the opportunity to comment on this document. If you
have any questions or comments, please feel free to contact me at (919) 733-280 I,
extension 349.
Attachment
Sincerely,
~-Yb#~ ;ell~~ £:v:a B. Mattison, CHMM
Environmental Engineer
Superfund Section
1646 Mail Service Center, Raleigh, North Carolina 27699-1646
Phone: [phone] \ FAX: [phone] \ Internet: www.enr.state.nc.us
AN EQUAL OPPORTUNITY\ AFFIRMATIVE ACTION EMPLOYER-50% RECYCLED/ 10% POST CONSUMER PAPER
Mr. Michael Townsend
April 29, 2002
Page 1
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GROUNDWATER SAMPLING QUALITY ASSURANCE PLAN
Section Al Title and Approval Sheet
I. Section A I was left unsigned. Please note that all future documents shall be signed,
sealed and notarized as appropriate by the proper signatories.
Section AS Background
2. Please revise Section AS to include a vicinity map and a site map depicting all
groundwater monitoring wells and surface water and sediment sampling locations.
Section A6 Project/Task Description
3. Please revise Section A6 to identify the 34 groundwater monitoring wells to be sampled.
AS Special Training/Certification
4. Please revise the second paragraph of Section AS to reference Appendix B -Pace
Analytical Services, Inc. Statement of Qualifications and Appendix C -Pace Analytical
Services, Inc. Quality Assurance Manual.
Section B.4.1 Field Based Analysis
5. Please revise Section B.4.1 to include provisions for the measurement of turbidity.
~ I
' ' ;
North Carolina A
Department of Environment 11\'d Natural
Resources
Michael F. Easley, Governor
William G. Ross Jr., Secretary
Dexter R. Matthews, Director
Mr. Michael Townsend
Superfund Branch
Waste Management Division
US EPA Region IV
61 Forsyth Street, 11 th Floor
Atlanta, Georgia 30303
January I 6, 2002
RE: Groundwater Sampling Quality Assurance Plan
North Carolina State University Lot 86 NPL Site
Raleigh, Wake County
Dear Mr. Townsend:
The Superfund Section of the North Carolina Department of Environment and Natural
Resources (NC DENR) has received and reviewed the document, Groundwater Sampling
Quality Assurance Plan, for the North Carolina State University (NCSU) Lot 86 National
Priority List Site. The Superfund Section offers the attached comments.
The Superfund Section appreciates the opportunity to comment on this document. lfyou
have any questions or comments, please feel free to contact me at [phone],
extension 349.
Attachment
CC: Mr. Duane Knudsen, NCSU
~J fJ/(,k:,.~"
David B. Mattison, CHMM
Environmental Engineer
Superfund Section
1646 Mail Service Center, Raleigh, North Carolina 27699-1646
Phone: [phone] \ FAX: [phone] \ Internet: www.enr.state.nc.us
AN EQUAL OPPORTUNITY\ AFFIRMATIVE ACTION EMPLOYER-SO% RECYCLED/ 10% POST CONSUMER PAPER
,1 Mr. Michael Townsend
January I 6, 2002
Page I
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GROUNDWATER SAMPLING QUALITY ASSURANCE PLAN
Section AI Title and Approval Sheet
1. The Title and Approval Sheet was left unsigned. Please note that all future documents
shall be signed, sealed and notarized as appropriate by the proper signatories.
Section A2 Table of Contents
2. Please correct the title of Section A in the Table of Contents to state, "Project
Management."
3. Please correct the Table of Contents to include the correct page numbers for Section A
and Section Al.
4. Please delete the phrase "List of Appendices" at the bottom of the Table of Contents.
Section A3 Distribution List
5. Please revise the second paragraph to state "This Groundwater Sampling Quality
Assurance Plan bas been prepared based on required elements outlined in the EPA
Requirements for Quality Assurance Project Plans (EPA QAIR-5), March, 2001.
Section A4 Projectffask Organization
6. Although it is recognized that several sections under this heading will require completion
upon the selection of contractors, please note that these sections will require completion
for approval by the appropriate regulatory agencies.
Section AS Background
7. Please revise Section AS to include a vicinity map and a site map depicting all
groundwater monitoring wells and surface water and sediment sampling locations.
Section A6 Projectffask Description
8. Please revise Section A6 to include the provision for the preparation of contaminant
plume (isoconcentration) maps for end users.
I '
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Mr. Michael Townsend
January I 6, 2002
Page 2
Section A8 Special Training/Certification
9. Although it is recognized that insertion of the laboratory certification number in Section
A8 cannot be completed until the contractors have been selected, please note that this
section will require completion for approval by the appropriate regulatory agencies.
Section B4 Analytical Methods
l 0. The first two sentences of Section B4 are incomplete. Please correct these oversights.
Section B.4.1 Field Based Analysis
11. Please revise Section B.4.1 to include provisions for the measurement of turbidity.
Section B.4. 1.3 Dissolved Oxygen
12. Please revise Section B.4.1.3 to state:
"Groundwater DO will be measured with a direct reading DO meter capable of
providing measurements to the nearest 0.01 mg/Lin accordance with manufacturer-
recommended procedures. The manufacturer's instructions for calibration in water-
saturated air will be followed. After calibration, the measurement system will be
checked in both air-saturated water (I 00% saturate) and a zero-oxygen solution (0%
saturated). For air-saturated water, a I-gallon plastic bottle will be filled less than
halfway with deionized or distilled water and shaken for several minutes. For a zero-
oxygen solution, an approximately 2% sodium sulfite solution will be used. DO
calibration check decision rules include:
• After calibration is completed, the air-saturated water and sodium
sulfite solution will be measured in the "percent saturation" mode.
If the readings are within +/-5% of I 00% and 0%, then the DO
measurement system's auto calibration is accepted.
• Calibration is checked mid-day and at the end of the day with the
l 00% and 0% solutions. Ifreading is not within 5%, then the system
will be auto-calibrated in water-saturated air."
Section B.4.2 Fixed Base Analysis
13. Please correct the first sentence of Section B.4.2 to state, "Fixed-base analyses are to be
performed for the following parameters using the methods listed in the table included in
Section B.3.1."
• • I
' Mr. Michael Townsend
January 16, 2002
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Page 3
Section B.5.6 Matrix Spike/Matrix Duplicate Samples
14. Please correct the first and second sentences of Section B.5.6 to state, "Additional sample
volumes for project-specific MS/MSD analyses will be performed by the Laboratory at a
frequency of 5% of all field samples. MS/MSD evaluations will be performed by the
Laboratory on project-specific samples for:"
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·DRAFT
GROUNDWATER SAMPLING QUALITY ASSURANCE PLAN
North Carolina State University
Lot 86 Sampling Site ·
Raleigh, Wake County, North Carolina
January 2002
Approvals
Project Coordinator: Duane Knudson, NCSU Date
??????????: ?????????????? Date
?????????????: ????????????????? Date
.undwater Sampling Quality Assurance Plan (R,sion I)
North Carolina State University Lot 86 Sampling Site
January 2002
A2 Table of Contents
. A · Project Managent ..................................................... :.Error! Bookmark not defined.
Al Title and Approval Sheet ..................... : ............. Error! Bookmark not defined.
A2 Table of Contents ................................................................................................ 2
A3 Distribution List .................................................................................................. 4
A4 Project/Task Organization .................................................................................. 5
AS Background ......................................................................................................... 7
A6 Project/Task Description ..................................................................................... 9
A 7 Quality Objectives and Criteria ........................................................................ I 0
A.7.1 Accuracy ................................................................................................... 11
A.7.2 Precision .................................................................................................... 11
A.7.3 Representativeness .................................................................................... 11
A.7.4 Completeness ............................................................................................ 12
A.7.5 Comparability ........................................................................................... 12
A.7.6 Traceability ............................................................................................... 12
A.7.7 Sensitivity ................................................................................................. 12
A8 Special Training/Certification ........................................................................... 13
A9 Documents and Records ................................................................................... 14
B DATA GENERATION AND ACQUISITION ........................... : ............................ 15
Bl Sampling Process Design: .......... .-...................................................................... 15
B2 Sampling Methods ................................................................. _. .......................... 16
B3 Sample Handling and Custody .......................................................................... 17
B.3.1 Sample Containers and Preservatives ....................................................... 17
B.3.2 Sample Identification and Designation ..................................................... 18
B.3.3 Sample Chain-of-Custody Documentation ............................................... 18
B.3.4 Sample Storage and Transport .................................................................. 19
B4 Analytical Methods ........................................................................................... 20
B.4.1 Field Base Analysis ................................................................................... 20
B.4.1.1 pH and Temperature ............................................................................ 20
B.4.1.2 Specific Conductivity ........................................................................... 21
B.4.1.3 Dissolved Oxygen .............. ., ................................................................ 21
B.4.1.4 Oxidation-Reduction Potential.. ........................................................... 21
B.4.2 Fixed Base Analysis .................................................................................. 22
BS Quality Control ................................................................................................. 23
B.5.1 Sampling and Analysis Plan ..................................................................... 23
B. 5 .2 Recordkeeping .......................................................................................... 23
B.5.3 Sample Trip Blanks ................................................................................... 24
B.5.4 Sample Equipment Rinseate Blanks ................................ : ........................ 24
B.5 .5 Field Duplicate Samples ........................................................................... 24
B.5.6 Matrix Spike/Matrix Duplicate Samples .................................................. 25
B.5.7 Field Completeness Evidence Audits ....................................................... 26
B6 Instrnment/Eguipment Testing, Inspection and Maintenance .......................... 27
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Andwater Sampling Quality Assurance Plan (R,sion I}
North Carolina State University Lot 86 Sampling Site
January 2002
B.6.1 Field Instmments and Equipment ............................................................. 27
B.6.2 Laboratory Instmments and Equipment.. .................................................. 27
B7 Instrument/Equipment Calibration and Frequency ........................................... 28
B. 7. I Field Instmments and Equipment.. ........................................................... 28
B.7.2 Laboratory Instmments and Equipment.. ............. : .................................... 28
B8 Inspection/Acceptance of Supplies and Consumables .................................. : ... 29
B9 Non-Direct Measurements ................................................................................ 30
BIO Data Management .......................... : .................................................................. 31
C ASSESSMENT AND OVERSIGHT ........................................................................ 32
Cl Assessments and Response Actions ................... _. ............................................... 32
C.1.1 Corrective Action -Field .......................................................................... 33
C.1.2 Corrective Action -Laboratory ................................................................. 33
C2 Reports to Management .................................................................................... 34
D DATA VALIDATION AND USABILITY .............................................................. 35
DI Data Review, Verification and Validation ........................................................ 36
D2 Verification and Validation Methods ................................................................ 3 7
D3 Reconciliation with User Requirements ........................................................... 38
LIST OF APPENDICES
3
Andwater Sampling Quality Assurance Plan (R,sion I)
North Carolina State University Lot 86 Sampling Site
January 2002
A3 Distribution List
This Groundwater Sampling Quality Assurance Plan (QAP) will be made available for
review to each individual identified in Section A.4, below. All persons involved in the
collection and interpretation of measurements and data under the Groundwater Sampling
and Analysis Plan (SAP), and the QAP are required to read and perform the sampling
activities at the Site in accordance with these documents. Additionally, participants are
referred to the following documents for further guidan'ce: the US EPA Environmental
Investigations and Standard Operating Procedures and Quality Assurance Manual
(USEPA EISOPQAM), May, 1996, with 1997 Revisions, the Draft EPA Region IV
Suggested Practices for the Evaluation of a Site For Natural Attenuation (Biological
Degradation) of Chlorinated Solvents, November, 1999 (EP A/600/R-98/128), and the
EPA Requirements for Quality Assurance Project Plans (EPA QAIR-5), March, 2001.
This Groundwater Sampling Quality Assurance Plan has been prepared based on
required elements outlined in the EPA Requirements for Quality Assurance Project Plans
(EPA QAIR-5), March, 2001.
4
.ndwater Sampling Quality Assurance Plan (R!ion I)
North Carolina State University Lot 86 Sampling Site
January 2002
A4 Project/Task Organization
Key project individuals and their responsibilities as they relate to the Groundwater
Sampling and Analysis and Quality Assurance Plan for the Site are outlined below:
Project Coordinator
Mr. Duane Knudson, North Carolina State University
Mr. Knudson acts as the Key Contact with US EPA and the North Carolina Department
of Environment and Natural Resources (NCDENR) -Division of Waste Management
(DWM), establishes overall scope for work, performance requirements and schedule for
project tasks, reviews all work plans and communications related to the performance of
the Groundwater Sampling and Analysis, authorizes the performance of the tasks
associated with the sampling activities for the Site, and, conducts submittals to the US
EPA and/or NCDENR-DWM, as required by law.
Regulatory Compliance-Federal
Mr. Michael Townsend, r./nited States Environmental Protection Agency, Region IV,
SuperfundBranch, Waste Management Division.
Mr. Townsend is the primary project contact for the US EPA, Region IV, Superfund
Branch. Mr. Townsend exercises regulatory authority related to issues at the Site
involving the US EPA.
Regulatory Compliance-State
Mr. David Mattison, North Carolina Department of Environment and Natural Resources,
Division of Waste Management, Superfund Section.
Mr. Mattison is the primary project contact for the NCDENR-DWM, Superfund Section.
Mr. Mattison exercises regulatory authority related to issues involving the NCDENR-
DWM, reviews all plans relating to sampling activities at the Site, and reviews all data
resulting from the sampling activities at the Site.
Project Manager
Key contact and liaison between NCSU and '(;ont,;actor-:Riime ("the Contractor"), .. --·•···,--· ~·· ·~-• ....... _.w ~----·-·_._ is responsible for overall technical responsibility and oversight for the
tasks associated with the performance of the Groundwater Sampling and Analysis for the
5
.ndwater Sampling Quality Assurance Plan (R!ion 1)
North Carolina State University Lot 86 Sampling Site
January 2002
Site. , '• ·'71 shall coordinate all activities to be performed at the Site in the
completion of the project, conduct technical reviews of all plans, documents and data sets
associated with the performance of the project, monitor activities to ensure compliance
with the S&A Plan for the Site, and ensure the implementation of appropriate corrective
actions for any QA/QC deficiencies identified in the performance of the project.
QA Task Manage~
Laboratory Project Manager
Project Manager, -laboratory_ "'-"'·•·-----'-·_.__ ___ ......._.,__,, ,_ I
Key contact and liaison between ~~~----('the Contractor") and
-· · ···· · ·-· ··· , ("the Laboratory"), . 1s responsible for fixed-based laboratory
analysis associated with the performance of the project, including the quality of data
generated by any subcontract laboratories. '<. •. · .. _· .. ,:·1 will ensure compliance with
"Standard Operating Procedures" (SOP's) and QA/QC requirements for fixed-based
laboratory analyses to be performed by the laboratory in the execution of the project, and
will bear responsibility for managing the technical accuracy and quality of work
performed by the laboratory. : . · 1 will also ensure that all laboratory records and
documentation thereof are maintained securely and reliably by the laboratory, report to
the Project Manager any deficiencies relating to QA/QC for the project, and initiate
corrective action for any deficiencies identified in the performance of the project.
Subcontract Laboratories
Field Operations Technicians
Field Operations Technicians noted above will bear responsibility for the performance of
Groundwater Sampling Tasks as outlined in the SAP. These individuals will be
responsible for executing work assignments necessary for the execution of the SAP in the
actual performance of the preparations, purging, and sampling of the wells associated
with the Site, performance of field-based measurements i11 the performance of the project,
and insurance of compliance with the SAP and SO P's associated with the performance of
the project.
6
.undwater Sampling Quality Assurance Plan (R,sion I}
North Carolina State University Lot 86 Sampling Site
January 2002
AS Background
Site Location .
The NCSU Lot 86 site is located on the west side of Raleigh, Wake County, North
Carolina, near Carter-Finley Stadium, immediately south of the southern right-of-way of
Wade Avenue Extension (Wade Avenue), a limited access highway. Wade Avenue
connects with Interstate 40 (I-40), which is a heavily traveled thoroughfare carrying
commuter traffic between Raleigh and Research Triap.gle Park, as well as interstate
traffic.
The approximatel.5 acre site is located on and surrounded by state-owned property. The
site is secured with a chain link fence with a padlock on the gate. The site is covered with
grass and no structures are present. A large grass-covered open area, west of the site and
north of Carter-Finley Stadium, is used for parking during stadium events. Trees along
the fence north of the site screen the view from Wade Avenue. The nearest water supply
well is located upgradient of groundwater flow approximately 2,000 feet southeast of the
site at the Medlin residence.
Site History
NCSU selected Lot 86 of Farm Unit No. I in 1969 as a burial site for hazardous chemical
waste generated in the University's educational and research laboratories. Burial of waste
was discontinued in November 1980 to comply with regulations promulgated under the
Resource Conservation and Recovery Act (RCRA).
The chemical wastes were placed in trenches located in the northwest portion of the site
The trenches were approximately 8 feet deep and varied from 50 to 150 feet long. After
filling, about 2 feet of native soil, which was excavated during trench construction, was
used as cover material. Later, the disturbed area was seeded with grass. The types of
chemicals reported to have been buried at the site include solvents, pesticides, inorganics,
acids, and bases. Although some of the liquid chemicals disposed of during the initial
site operations were poured into the trenches, both liquid and solid chemicals were
generally buried in metal, glass, or plastic containers.
The site was placed on the National Priority List (NPL) in October 1984, based on results
from an inspection completed in June of that year.
Present Situation and Extent of Contamination
During the period January 19 to September 21, 1999, remedial action activities were
conducted on the Lot 86 waste trench area. The remedial technology specified in the
Record of Decision to address waste material buried in the trenches, as well as
contaminated soils adjacent to the trenches, was in situ mixing and encapsulation. The
7
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.undwater Sampling Quality Assurance Plan (!ision I)
North Carolina State University Lot 86 Sampling Site
January 2002
goal of shallow soil mixing was to stabilize and or solidify the waste materials in the
disposal trenches and in the soils surrounding the trenches, thereby eliminating further
leaching from the former disposal area. During implementation of the remedy,
approximately 2,240 tons of cement was used to stabilize almost I 0,090 cubic yards of
waste material and impacted soil. . .
Sampling of groundwater in the vicinity of the site has been conducted (in some fashion)
for approximately 15 years. The most prevalent chemicals in groundwater continue to be
VOC' s, with chlorinated compounds ( chloroform, methylene chloride, and carbon
tetrachloride) found in the highest concentrations. _The sh<!llow groundwater has
evidenced the most impact with only trace levels of contaminants detected in the deep
wells. Highest concentrations have been consistently observed immediately downgradient
of the landfill waste trenches, with a rapid decrease with distance away from the site .
8
.undwater Sampling Quality Assurance Plan (!ision l)
North Carolina State University Lot 86 Sampling Site
January 2002
A6 Project/Task Description
This QAP is for the collection and analysis of groundwater samples from groundwater
monitoring wells associated with the Site. Elements necessary for the completion of the
groundwater sampling event at the Site include:
• Measurement of groundwater elevations for each well,
• Development and/or "purging" of each well prior-to sampling,
• Measurement of specified field-based parameters,
• Sampling of groundwater from each well,
• Laboratory analysis of groundwater samples,
• Integration of laboratory data into spreadsheets for use by end-users,
• Preparation of hydraulic gradient maps for end-users, and
• Management of the collected information, according to this Plan.
Additional tasks may be added to the scope of the project only after written approval
from the NCSU Project Coordinator. Similarly, task modifications require written
approval of the Project Coordinator.
9
.ndwater Sampling Quality Assurance Plan (R!ion I)
North Carolina State University Lot 86 Sampling Site
January 2002
A 7 Quality Objectives and Criteria
Groundwater sampling and analysis to be performed in accordance with the S&A Plan
will provide definitive water quality characterization data, based on established·
procedures for sampling, field data collection, chain-of-custody documentation, fixed-
based laboratory analyses, calibration(s), internal QC audits, preventive maintenance and
corrective action. Definitive data will be analyte-specific, with confirmation of analyte
identification and concentration documented completely with raw data and a
determination of analytical precision or total system measurement error.
In the determination of analytical precision and total measurement error, reliance will be
on the laboratory method Standard Operating Procedures, laboratory Quality Control
system(s), and field Quality Control submittal(s). Definitive data for the groundwater
sampling and analysis will be based on US EPA or American Society for Testing and
Materials (ASTM) reference methods, as applicable.
QA Objectives for field-based and fixed-based data for the project are acknowledged for
precision, accuracy, representativeness, completeness, comparability and sensitivity.
Field-based and fixed-based QC measures to assess data accuracy precision,
representativeness, completeness, comparability and sensitivity are established through
the use of "method blanks", "duplicates", "spikes", and conformance to the SOP and
QA/QC. Table 1 denotes the QC criteria for measurement data.
Table 1
QC Criteria for Measurement Data
Parameter Precision Accuracy Representativeness Completeness Sensitivity
PH ± 0.1 SU ± 0.2 SU in Stable repeated 100% 0.01 SU
continuing readings; ±0. l SU
calibration
verification
Temperature ± I °C NIA Stable repeated 100% 1 'C
readings;± 3 %
Conductivity ± 0.5%, ±1 ± 2 % in Stable. repeated 100 % 50 'us/cm2
digit continuing readings;± 3 %
calibration
verification
Dissolved Oxygen 10% ± 5 % in Stable repeated 100% 0.01 mg/I
continuing readings; l 0%
calibration
verification
Oxidation-Reduction 10% Functional Stable repeated 100% 1 mV
Potential check-readings; 50 mV
ZoBell's
solution
voes-MC/MS %RSD Statistical Blank< DL 95% 5 ktglL
<30% limits; Tbl.
%0<20% 5.5 of LQAP
DHGs-GC/FlD %0<20% 70<%R<135 Blank< DL 95% lo/ov/v
10
Methane/ethane/ethene
Metals-lCP
I-lg-CVAA
TOC
Chloride
Sulfate
Nitrate
Alkalinity
.mdwater Sampling Quality Assurance Plan (R,sion I)
North Carolina State University Lot 86 Sampling Site
January 2002
RSD <20% 75<%R<l25 Blank< DL 95%
RPD<!Oo/o
RPD <20% 90<%R<I I0 Blank <DL 95 %
%0<10%. 75<%R<l25 . Blank< DL 95 %
RPD <20% 85<%R<l 15 Blank <DL 95%
RPD<20% 80<%R<l20 Blank <DL 95 %
RPO <20% 80<%R<l20 Blank< DL 95 %
RPD <20% 90<%R<I I0 Blank< DL 95%
A.7.1 Accuracy
<0.5 mg/I
0.2 ug/1
0.1 mg/I
I mg/I
I mg/I
0.1 mg/I
5 mg/I
Accuracy is the agreement between a known sum or value and a measured sum or value.
Accuracy is normally expressed as a percent recovery (¾R) of a surrogate spike,
environmental matrix spike, and/or analytical control matrix spike. Accuracy objectives
for measurement data are presented in Table 1. The Laboratory Project Manager will be
responsible for ensuring compliance with accuracy objective(s). In the event that any
data should fail its accuracy criteria, corrective action shall be undertaken as described in
the method or relevant SOP(s).
A.7.2 Precision
Precision is the agreement among individual measurements of the same property under
similar conditions. Precision is measured through the use and testing field and laboratory
duplicate or replicate sample analyses. Precision is expressed as either relative percent
difference (RPD) or percent relative standard deviation (%RED).
The precision objectives for measurement data are noted in Table 1. The Laboratory
Managers will be responsible for compliance with precision objectives. Should any of
the data fail the precision criteria, corrective action will be taken as described in the
method, the relevant SOP's or Laboratory Quality Assurance Plan (LQAP).
A.7.3 Representativeness
Representativeness is a measure of the degree to which the measured values accurately
and precisely reflect the medium being sampled. Representativeness is largely the result
of the appropriate selection of sampling locations and sampling methods. It is assessed in
duplicate or population sample comparisons. Representativeness is a qualitative measure.
11
.undwater Sampling Quality Assurance Plan (R.sion I)
North Carolina State University Lot 86 Sampling Site
January 2002
A.7.4 Completeness
Completeness is a measure of the amount of valid data obtained compared to the amount
of valid data expected to be obtained under normal conditions. Valid data are data that
have met field and laboratory SOP QAJQC criteria. Independent data validation of
laboratory data is not planned, but may be performed if needed.
The completeness objectives for field and laboratory. data measurements are 100%.
Completeness of 95% is acceptable. Should any of the data fail the completeness criteria,
corrective actions will be taken, which may include resampling and/or reanalysis.
A.7.5 Comparability
Comparability is the confidence with which one data set can be compared to another.
Comparability will be controlled by using methods developed to standardize the
collection of samples and measurements. Consistent, proper calibration of all equipment
throughout the field exercises, as described in this QAPP, will help in maintaining the
comparability of measurements. Field documentation and QA evidence audits will be
used to establish that protocols for sampling and measurement follow appropriate SOP's.
Comparability is a qualitative measure. ·
A.7.6 Traceability
Traceability is the ability to trace the history of procedures; equipment and/or standards
used during an investigation and are evaluated through a completeness evidence audit of
the documentation supporting the activity performed or laboratory systems audits.
Completeness evidence audits will be performed for all field and data records.
Laboratory systems audits are not planned.
A.7.7 Sensitivity
Sensitivity is a quantitative statement that conveys the lowest level of measurement that
can be distinguished from background with a given level of confidence. Analytical
detection limits (sensitivity) should be low enough to confirm the presence o_r absence of
a given analyte at a concentration greater that remedial performance standards where
applicable, at specified levels of precision and accuracy. General reporting limits are
matrix-dependent. Specific detection limits are presented in the laboratory method SOPs.
12
.undwater Sampling Quality Assurance Plan (ii.ion I)
North Carolina State University Lot 86 Sampling Site
January 2002
AS Special Training/Certification
All personnel working on the site as part of the investigation will be required to have
completed Health and Safety Training ptirsuant to the 29 CFR 1910 Occupational Safety
and Health Administration (OSHA) regulations.
Chemical analyses will be performed by a North Carolina Department of Environment
and Natural Resources (NCDENR) Division of Water Quality (DWQ) certified
laboratory. The Laboratory will provide its Certification #'."'~.::l with the NCDENR-DWM,
expiration date, and its status.
Certification information will also be provided for any subcontract laboratory.
For parameters that are not certified by the State of North Carolina, the laboratory must
provide the complete SOP for the parameter(s), including instrument calibration
information, as necessary. The SOP will include QC data to allow comparison to DQO's.
13
.ndwater Sampling Quality Assurance Plan (.ion l)
North Carolina State University Lot 86 Sampling Site
January 2002
A9 Documents and Records
Bound field notebooks with numbered pages, field observation reports, calibration logs,
sampling records, non-conformance reports, and corrective action reports as applicable
will be used to provide complete and clear documentation of the purpose, scope,
conditions, procedures, conformance and non-conformance results of actions, activities,
persons, observations and time line of the sampling event in a manner appropriate for
evidence. All pages utilized within the field book(s) will.be numbered and entries will be
in ink, signed and dated. Correction to entries will be made by drawing a single line
through the incorrect entry, recording the correct information, and initialing and dating
the corrected entry. If the reasons for making the change are not immediately evident, an
explanation is required. Unused portions of notebook pages will be lined out, and bear
the statement in ink "no further entries this page".
Documentation of fixed base analysis by the Laboratory will be in accordance with
Contract Laboratory Protocols (CLP) established for the laboratory, and will be in
conformance will all laboratory QA and QC criteria.
At the conclusion of the sampling event, copies of all relative field notebook pages,
analytical data and electronic format data will be forwarded to NCSU. The original field
notebooks will be retained by the Contractor.
14
.ndwater Sampling Quality Assurance Plan (R-ion 1)
North Carolina State University Lot 86 Sampling Site
January 2002
B DATA GENERATION AND ACQUISITION
Bl SampHng Process Design
Groundwater sampling for each of the wells at the Site will be performed subsequent to
the adequate purging and recharge (targeted for approximately 75% of the initial static
level) of the water within the wells. Samples retained from each well will be submitted
for fixed based analysis.
Fixed based parameters will be measured for each well sampled through the analysis of
groundwater samples. Fixed-base parameters for these samples will include the analysis
of the sample(s) for:
a) Aromatic and Chlorinated hydrocarbons,
b) Nitrate,
c) Dissolved Iron (II),
d) Sulfate,
e) Methane, ethane, ethene,
f) Alkalinity,
g) Major cations (RCRA Metals) including Manganese (Mn),
h) Chloride, and
i) Total organic carbon
Sample analytical methods are provided in the Section B.3.1 table.
Samples retrieved from each well will be contained in pre-cleaned laboratory grade
containers to be provided by the Laboratory. The QC package will include a Method
Blank, Matrix Spike/Matrix Spike Duplicate, Laboratory Fortified Blank and Surrogate
Standard % Recoveries.
Fixed based chemi~1lysis for volatile organic compounds on groundwater samples
retained from the Site are to be conducted employing-the EPA Method 6230D. Resulting
data will be submitted in a Contract Laboratory Protocols (CLP) data set.
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lundwater Sampling Quality Assurance Plan (!sion 1)
North Carolina State University Lot 86 Sampling Site
January 2002
B2 Sampling Methods
Well purging and sampling will be conducted in accordance with the well sampling
procedure provided as the USEPA EISOPQAM, Section 7.0 -Groundwater Sampling.
Wells with adequate recovery rates will be purged using a Grundflos Redi-Flo 2
submersible pump (or equivalent). Wells with slow recovery rates will be purged and
sampled using a clean disposable bailer and new nylon line. Purging and sampling will
proceed from the unaffected ( clean) wells to the most impacted wells.
Between locations, the pump and controlling leads will be decontaminated in accordance
with the procedures described in USEP A EISOPQAM Appendix B -Standard Field
Cleaning Procedures.
Specific Sa~pling Equipment Quality Assurance Techniques
All equipment used to collect ground water samples shall be cleaned as specified in
USEPA EISOPQAM Appendix B -Standard Field Cleaning Procedures. Cleaning
procedures utilized in the field or field repairs shall be thoroughly documented in field
records.
In the case of wells for which purging is performed with an electric submersible pump,
samples will be retrieved from a sample port to be located on the flow through chamber
used in the collection of field measured parameters. In the case of wells requiring
purging utilizing a disposable bailer, samples will be collected from the bailer. Samples
for fixed base analyses will be contained in pre-washed, laboratory grade containers to be
provided by the Laboratory. A listing of containers and required preservatives (if
applicable) are discussed in B.3.1, below.
Subsequent to the collection of groundwater samples, the containers in which samples
have been contained will be placed on ice in a cooler, pending transportation to the lab
for analysis. All chain-of custody protocol and outlined in 8.3.3 will be strictly adhered
to in the performance of this sampling event.
Additional information related to sampling techniques are available m the USEP A
EISOPQAM, Section 7.0 -Groundwater Sampling.
16
.mdwater Sampling Quality Assurance Plan (ilion I}
North Carolina State University Lot 86 Sampling Site
January 2002
B3 Sample Handling and Custody
Procedures and criteria for sample handling and custody will be according to USEPA
EISOPQAM Section 3 -Sample Control, Field Records, and Document Control. Those
procedures are outlined below:
B.3.1 Sample Containers and Preservatives
Sample containers and preservatives for the fixed based parameters outlined in the S&A
Plan are presented in the following table:
Parameter Method(s) Cont. Cont. Pres. Hold
Vol. Matl. Time
Aromatic & Chlorinated (3)
Hydrocarbons 6230D 40 ml Glass HCL 14 days
Nitrate 353.2 250 ml HOPE None* 48
hours
Dissolved Iron 6010 250 ml HDPE HN03' 6-mo'.
Sulfate 375.4 500 ml HOPE None* 28 days
Methane, ethane & WAl.02 (3) Glass None 14 days
ethene 40 ml
Alkalinity 3 IO.I 250 ml HOPE None* 14 days
Major Cations SW6010 (As)
(8 RCRA Metals) SW6010 (Pb)
SW60 IO (Se) 500 ml HOPE HN03 28 days
SW6010 (Ba,Cd,Cr,Ag)
SW7470 (Hg)
Chloride 325.3 250 ml HOPE None* 28 days
Total Organic Carbon 9060 (3) HDPE H2S04° 28 days
40ml
* Although samples may not reqmre chemical preservatwn, each must be stored ma location with
a temperature not exceeding 4°C. ,
1 Dissolved Iron samples will be filtered in the field prior to preservation.
2 6-month hold time applies to sample after preservation by laboratory
3 Storage of sample required to be cool, dark location
Sample containers to be utilized in the performance of this sampling event will be
provided by the Laboratory. Sample containers requiring chemical preservation will be
prepared in advance by the Laboratory. ·
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-ndwater Sampling Quality Assurance Plan (R,sion I)
North Carolina State University Lot 86 Sampling Site
January 2002
B.3.2 Sample Identification and Designation
The method of sample identification used depends on the type of sample collected.
Samples collected for specific field analyses or measurement data ~re recorded directly in
bound field logbooks or recorded directly on the Chain-of-Custody Record, with
identifying information, while in the custody of the samplers. Examples include pH,
temperature, and conductivity. Samples collected for laboratory analyses are identified by
using standard sample tags which are attached to the sample containers. The sample tags
are sequentially numbered and are accountable documents after they are completed and
attached to a sample or other physical evidence. The following information shall be.
included on the sample tag using waterproof, non-erasable ink:
• project number;
• field identification or sample station number;
• elate and time of sample collection;
• designation of the sample as a grab or composite;
• type of sample (water, wastewater, leachate, soil, sediment, etc.) and a very brief
description of the sampling location;
• the signature of either the sampler(s) or the designated sampling team leader and
the field sample custodian (if appropriate);
• whether the sample is preserved or unpreserved;
• the general types of analyses to be performed (checked on front of tag); and
• any relevant comments (such as readily detectable or identifiable odor, color, or
known toxic properties).
Tags for blank or duplicate samples will be marked "blank" or "duplicate," respectively.
This requirement does not apply to blind-spiked or blank samples which are to be
•submitted for laboratory quality control purposes. Blind-spiked or blank samples shall not
be identified as such. This identifying information shall also be recorded in the bound
field logbooks and on the Chain-Of-Custody Record .
B.3.3 Sample Chain-of-Custody Documentation
Chain-of-custody procedures are comprised of the following elements; 1) maintaining
sample custody and 2) documentation of samples for evidence. To document chain-of-
custody, an accurate record mt1st be maintained to trace the possession of each sample
from the moment of collection to its introduction into evid_ence.
A sample or other physical evidence is in custody if:
• it is in the actual possession of an investigator;
• it is in the view of an investigator, after being in their physical possession;
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.ndwater Sampling Quality Assurance Plan (R-sion I)
North Carolina State University Lot 86 Sampling Site
January 2002
• it was in the physical possession of an investigator and then they secured it to
prevent tampering; and/or
• it is placed in a designated secure area.
· Sample Chain-of-Custody (COC) records are to be provided by the Laboratory. Each
COC will be separately numbered for each ten (I 0) or less samples noted on the
document. COC records wi 11 bear:
• the project name ("NCSU-Lot 86"),
• Sampler Name and Signature,
• Point of Contact and Phone Number, and
• Client Address
Specific information related to the samples obtained from the Site and noted on the COC
will include:
• the Sample(s) ID,
• Sampling Date(s) and Time(s),
• Sample Matrix,
• Sample Preservative(s),
• Notation as to whether the sample(s) were filtered,
• Number of sample container(s), and
• requested fixed-based analyses.
Additional information related to the sample(s) will be included m the
"Remarks/Comments" section of the COC
B.3.4 Sample Storage and Transport
Sample shipments for the project will occur as necessary to maintain established holding
times associated with the fixed-based sample analyses. Samples will be packed on ice
subsequent to collection, and will be transported from the Site to the Laboratory. either
by sampling or Laboratory personnel. In keeping with Chain-of-Custody requirements,
all samples transported to the laboratory will be i_dentified in accordance with Sections
B.3.2 and B.3.3, as noted above.
Subsequent to the collection of a sample from any given location (well), each container
will be placed on ice in a cooler within minutes of collection. Samples will be secured in
coolers with a sufficient amount of ice to ensure proper preservation, and shall, if
necessary, be secured within the cooler(s) utilizing bubbl_e wrap or foam packing, at the
discretion of either the sampling or Laboratory personnel. Care will be taken to ensure
that no samples reach a temperature which will cause the sample(s) to freeze.
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lundwater Sampling Quality Assurance Plan (!ision I)
North Carolina State University Lot 86 Sampling Site
January 2002
B4 Analytical Methods
Parameters for groundwater sampling and analysis to implement the protocol include
Field-based parameters measured directly in real time during sampling. Fixed-base
analytical parameters are to be performed off-site.
Method requirements for accurate measurements of the field-based and fixed-base and
parameters are established in this section of the QAP. The analytical methods designated
for use in the groundwater sampling and analysis program are, or are based on, EPA,
ASTM, or American Public Health Association (APHA) published methods. Laboratory
analytical methods are documented in SOP's, provided with the Sampling and Analysis
Plan.
B.4.1 Field Base Analysis
Groundwater pH, specific conductivity, temperature, DO, and ORP will be measured in
the field during sampling. All five parameters will be simultaneously monitored in real
time using direct reading meters with specific electrodes or probes .. Monitoring will be
performed on groundwater delivered without exposure to the atmosphere and with
minimal agitation through a flow-through chamber. The procedures and equipment for
delivery of the sample stream to the field parameter-monitoring chamber are established
in the SAP.
The use, care, maintenance, and troubleshooting of each piece of equipment will be
performed in accordance with the manufacturer's instructions.
The field parameters of DO and ORP are designated critical samples. The groundwater
sample stream from DO and ORP must not be exposed to the atmosphere to be
representative of the formal ion water.
B.4.1.1 pH and Temperature
Groundwater pH and temperature will be measured using a combination pH and
temperature meter in accordance with manufacturer-recommended procedures. pH will
be measured with automatic temperature compensation (ATC) to the nearest 0.1 Standard
Unit (SU).
Each day of use, the temperature of a pH calibration buffer solution will be
simultaneously measured with the thermistor/meter, and with a mercury-filled pocket
thermometer accurate to+/-l degree Celsius. pH calibration decision rules include:
20
clndwater Sampling Quality Assurance Plan CR.ion 1)
North Carolina State University Lot 86 Sampling Site
January 2002
• After the slope adjustment is made to the second calibration buffer (4.00 to 10.00
SU) in the initial calibration of the system the pH 7.00 calibration buffer (the first
buffer solution used) should be read again. If the reading is accurate to+/-0.1 SU
of7.00 (i.e., 9.9 to 7.1 SU)then the calibration is acceptable. ·
• Calibration is checked every two hours or every five monitoring· locations
(whichever condition occurs first). The calibration is checked in both buffer
solutions used. If the readings are outside +/-0.2 SU in either buffer, then the
system must be recalibrated.
B.4.1.2 Specific Conductivity
Groundwater specific conductivity will be measured with a direct reading conductivity
meter in accordance with manufacturer-recommended procedures. Specific conductivity
will be measured with the cell constant, temperature coefficient and reference
temperature properly established, and recorded to the nearest whole number (pS/cm or
mS/cm).
Specific conductivity calibration decision rules must include:
• After the initial c::ilibration is completed, the standard solution will be measured
again. If the reading is within+/-0.5 percent of the standard solution's value, I
digit, then the calibration is accepted.
• Calibration is checked every two hours or every five monitoring locations
(whichever condition occurs first). The calibration is checked in the standard
solution used for initial calibration. If the readings are outside+/-I percent of the
standard solution, then the system must be recalibrated.
B.4.1.3 Dissolved Oxygen
Groundwater DO will be measured with a direct reading DO meter capable of providing
measurements to the nearest 0.01 mg/L.
B.4.1.4 Oxidation-Reduction Potential
ORP will be measured with a direct-reading meter and ORP platinum band combination
electrode in accordance with the manufacturer's instructions. ORP electrodes undergo no
change of zero-point or of slope. The principal cause of the incorrect ORP potentials is
degradation of the platinum surface. The ORP electrode-will be kept clean with a daily
dilute hydrochloric acid soak (several minutes) followed by clean~water rinse, soap
solution rinse, and final clean water rinse. Short-term storage of the electrode will follow
the manufacturer's instructions. A 2-molar potassium chloride (2M KC!) solution will be
used for storage and soaking of the electrode. ORP measurements will be recorded to the
nearest millivolt (m V).
21
Gtndwater Sampling Quality Assurance Plan (R-ion I)
North Carolina State University Lot 86 Sampling Site
January 2002
To test the ORP electrode's accuracy, quinhydrone solutions are recommended. Because
of the toxicity and instability of the quinhydrone solutions, this test will not be performed
in the field. ORP functionality check decision rules include:
• If the ORP measurement falls within the m V range identified for the Zobel
solution used, then the system is functional. If the system fails the functionality
test, then the electrode will be cleaned as specified and retested.
B.4.2 Fixed Base Analysis
Fixed-base analyses to be performed for the following paramters using the methods listed
in the Section B.3.1 table.
a) Aromatic and Chlorinated Hydrocarbons,
b) Nitrate,
c) Dissolved Iron (field-filtered),
d) Sulfate,
e) Methane, ethane & ethene,
f) Alkalinity,
g) Major cations (RCRA Metals), including Manganese (Mn),
h) Chloride, and
i) Total Organic Carbon.
Methods to be employee! in the performance of these analyses are documented in the S&A
Plan.
Fixed based chemical analysis for volatile organic compounds on groundwater samples
retained from the Site are to be conducted employing the EPA Method 62300, rather
than the EPA Method 8260. The EPA 62300 analysis provides lower detection limits.
Resulting data will be submitted in a Contract Laboratory Protocols (CLP) data set.
Each Laboratory Method SOP will contain the specific QC criteria for the analysis, as
applicable. All samples will be analyzed by the Laboratory (and its subcontractors) in
strict accordance with the SOPs, to maintain QC as required. Laboratory and
subcontractor laboratory SOP's and QAP's are presented in the SAP.
22
olndwater Sampling Quality Assurance Plan (R-ion l)
North Carolina State University Lot 86 Sampling Site
January 2002
BS Quality Control
The known quality and defensibility of the results of field activities is supported by the
following QC elements:
The SAP for field activities, record keeping as documentation for evidence, calibration
and continuing verification of calibration for field equipment, collection of appropriate
field QC samples including trip blanks for VOCs, equipment rinsate blanks, blind field
duplicate samples, and matrix spike/matrix spike duplicate submittals. Table 2 contains
a summary of field QC samples.
TABLE2
Summary of Quality Control Samples
Control Item Frequency Notes
Field Duplicates 1 for each 20 samples, Field Duplicates to be analyzed by same methods as each
34 samples total -fixed-base method for all wells, field duplicates should
2 duplicates originate from historically contaminated location(s)
Trip Blanks 1 for each cooler Trip Blanks to be analyzed for aromatic and chlorinated
shipped or 4 total hydrocarbons by EPA-6230D
Equipment Rinse 1 for each 20 samples, Field Duplicates to be analyzed by same methods as each
Blanks 34 samples total -fixed-base method for all wells
2 rinse blanks
Matrix 1 for each 20 samples, MSIMSD Samples to be analyzed by same methods as
Spike/Matrix 34 samples total -each fixed-base method for all wells.
Spike Duplicates 2 MS/MSD Samples
B.5.1 Sampling and Analysis Plan
The SAP details the procedures, requirements, and standard of care for field activities to
be performed in groundwater sampling and analysis. The SAP is an integral part of
meeting the project's DQO's.
B.5.2 Recordkeeping
Bound field notebooks with numbered pages, field observation reports, calibration logs,
sampling records, non-conformance reports, and correctiye action reports as applicable
will be used to provide complete and clear documentation of. the purpose, scope,
conditions, procedures, conformance and non-conformance results of actions, activities,
persons, observations and time line of the sampling event in a manner appropriate for
evidence. All pages utilized within the field book(s) will be numbered and entries will be
in ink, signed and dated. Correction to entries will be made by drawing a single line
through the incorrect entry, recording the correct information, and initialing and dating
23
Andwater Sampling Quality Assurance Plan (R,sion I)
North Carolina State University Lot 86 Sampling Site
January 2002
the corrected entry. If the reasons for making the change are not immediately evident, an
explanation is required. Unused portions of notebook pages will be lined out, and bear
the statement in ink "no further entries this page".
B.5.3 Sample Trip Blanks
Trip Blanks for volatile organic analysis (VOA) will be provided by the Laboratory using
demonstrated analyte free (OAF) water. The VOA trip blanks will be preserved by the
Laboratory. Trip blanks are never to be opened in the field. Trip blanks are provided
with the empty VOA vials and are intended to simulate the trip any given set of VOA
sample vials undergoes. As such, the trip blanks remain in common storage with the
empty VOA vials.
Each day a set of trip blanks is pulled and goes to a sampling location with a set of actual
sample vials,. Those trip blanks remain with that set of sample vials as they return to
common cold sample storage.
All daily VOA samples will be combined into one cooler for shipment or transport to the
laboratory. This cooler will contain that day's trip blank QC submittal.
B.5.4 Sample Equipment Rinseate Blanks
Equipment rinsate blanks will be collected from sampling equipment that is
decontaminated and reused in the field at a frequency of one per 20 samples (5%). The
equipment used in sampling will be rinsed with laboratory provided OAF water and the
water running off the equipment will be collected into sample containers. Rinse blanks
will be filtered when obtaining dissolved metal fractions in accordance with methods
necessary for the collection of samples for metals analysis.
The electronic water level indicators used in sampling should not then be wetted much
beyond the water contact sensor and are therefore unlikely to cause cross-contamination
between locations if properly decontaminated after every use. No other non'dedicated or
single use equipment is expected to contact the sample water downwell except the
submersible pump and its electrical leads. Appropriate equipment rinsate blanks will be
determined by the QA Field Manager during the sampling event.
B.5.5 Field Duplicate Samples
Field duplicates are two samples taken with repeated sampling from the same location,
submitted, and analyzed separately. Differences in the results of field duplicate analyses
quantify the precision, reproducibility, and representativeness of sampling and analysis
systems. Duplicate samples will be taken from wells with historically high
24
l,ndwater Sampling Quality Assurance Plan (R,sion I)
North Carolina State University Lot 86 Sampling Site
January 2002
concentrations of analytes at a frequency equal to 5% of all field samples. Duplicates
will be collected as two wholly distinct sample collections. That is, one complete set of
samples will be collected and labeled as a sample, and a second set' of samples will be
collected immediately thereaft_er (the purge is not repeated) and. labeled to ensure. its
locations is unknown (blind) to the laboratory.
Field duplicate results are assessed by the data user.
B.5.6 Matrix Spike/Matrix Duplicate Samples
Additional sample volumes for project-specific MS/MSD analyses will be performed by
CompuChem at a frequency of 5% of all field samples.
MS/MSD evaluations will b~ performed by CompuChem on project-specific samples for:
a) Aromatic and Chlorinated Hydrocarbons,
b) Nitrate,
c) Dissolved Iron (field-filtered),
d) Sulfate,
e) Methane, ethane & ethene,
t) Alkalinity,
g) Major cations (RCRA Metals), including Manganese (Mn),
h) Chloride, and
i) Total Organic Carbon.
25
clndwater Sampling Quality Assurance Plan (R,sion I)
North Carolina State University Lot 86 Sampling Site
January 2002
B.5.7 Field Completeness Evidence Audits
The QA Task Manager will conduct a completeness evidence reviews at the end. of each
· day of field activity. · The review is to verify that all required and appropriate
documentation for the days events, including notebooks, calibration logs, sampling
records, observation reports, non-conformance reports, corrective action reports, COC,
etc., are complete and clear.
26
.ndwater Sampling Quality Assurance Plan (R.sion I)
North Carolina State University Lot 86 Sampling Site
January 2002
B6 Instrument/Equipment Testing, Inspection and Maintenance
B.6.1 Field Instruments and Equipment
Instruments and equipment utilized for field base measurements associated with the
performance of this project will be tested, inspected and maintained in accordance with
the instrument or equipment manufacturer's operating instructions. Testing, inspection
and maintenance of instruments and equipment will be performed at a frequency in
keeping with the manufacturer's operating instructions.
B.6.2 Laboratory Instruments and Equipment
Instruments and equipment utilized for laboratory base analyses associated with the
performance of this project will be tested, inspected and maintained in accordance with
the Standard Operating Procedures (SOP's) and Quality Assurance Plan (QAP) for the
laboratory performing the analyses. Labaoratory and subcontractor laboratory SOP's and
QAP's are presented in the SAP.
27
lundwater Sampling Quality Assurance Plan (R,sion l)
North Carolina State University Lot 86 Sampling Site
January 2002
B7 Instrument/Equipment Calibration and Frequency
B.7.1 Field Instruments and Equipment
Instruments and equipment utilized for field base measurements associated with the
performance of this project will be calibrated in accordance with the instrument or
equipment manufacturer's operating instructions. Calibration of instruments and
equipment will be performed at a frequency in keeping with the manufacturer's operating
instructions.
B.7.2 Laboratory Instruments and Equipment
Instruments and equipment utilized for laboratory base analyses associated with the
performance of this project will be calibrated in accordance with the Standard Operating
Procedures (SOP's) and Quality Assurance Plan (QAP) for the laboratory performing the
analyses. Labaoratory and subcontractor laboratory SOP's and QAP's are presented in
~SM. ·
28
.undwater Sampli~g Quality Assurance Plan olsion I)
North Carolina State University Lot 86 Sampling Site
January 2002
B8 Inspection/Acceptance of Supplies and Consumables
Sampling supplies and consumables to be utilized in the performance of this project· will
be inspected prior to acceptance and use by the Project Manager.
Laboratory consumables, including sample containers, shall be provided by the
Laboratory for use in fixed base analyses. Sample containers requiring chemical
preservation will be pre-preserved with the appropriate, media, as described in Section
B.3.1. Acceptance of these consumables will be based on assurances from the laboratory
as to the origin of the materials, and their ability to provide documentation as to the
condition of the materials delivered.
29
clndwater Sampling Quality Assurance Plan (R!ion 1)
North Carolina State University Lot 86 Sampling Site
January 2002
B9 Non-Direct Measurements
In. the performance of this project, non-direcnources for data necessary for performance
include the submittal of data in possession ofNCSU, including water level measurements
from at least one (I) event in which the wells were gauged, well construction information
including: top of casing (TOC) elevation, and location (x and y-coordinate)
measurements based on a survey of the wells, total depth and screened interval of each
well. It is requested that the well data be submitted in an editable Excel® Spreadsheet
format. Also necessary will be an editable map (in AutoCad® format) depicting the
locations of each well and physical features of the areas in which the wells are located.
30
Andwater Sampling Quality Assurance Plan (R,sion I)
North Carolina State University Lot 86 Sampling Site
January 2002
BlO Data Management
Data management for this project will be structured to ensure usability by NCSU, the
NCDENR-DWM, and the US EPA, while ensuring documentable validity in keeping with
quality assurance.
Generation of field data for field base measurements will first be logged into bound field
notebooks with numbered pages. Field observation reports, calibration logs, sampling
records, non-conformance reports, and corrective action reports as applicable will be used
to provide complete and clear documentation of the purpose, scope, conditions,
procedures, conformance and non-conformance results of actions, activities, persons,
observations and time line of the sampling event in a manner appropriate for evidence.
All pages utilized within the field books will be numbered and entries will be in ink,
signed and dated. Correction to entries will be made by drawing a single line through the
incorrect entry, recording the correct information, and initialing and dating the corrected
entry. If the reasons for making the change are not immediately evident, an explanation
is required. Unused portions of notebook pages will be lined out, and bear the statement
in ink "no further entries this page".
Generation of end-user information, including spreadsheets and graphics, will be
performed as described below:
•
•
•
Spreadsheets will be generated utilizing Microsoft Excel® format, with a numeric
precision ofno less than 0.01.
Data for modeling of groundwater hydraulic gradient and contaminant
isoconcentration maps will be first entered into Golden Software© Surfer! 6, a
surface modeling program, and exported for use as AutoCad® digital extract files
(DXF).
DXF files will be integrated into the AutoCad® base file provided by NCSU, and
plotted for use by NCSU.
Electronic data will be stored on a physical hard-drive located at the Contractor's office.
Backup copies of the data will be retained on a Compact Disk (CD) backup. A complete
copy of these data will be made available for use by NCSU.
Alterations to the methods by which the data are made available to NCSU, the NCDENR-
DWM or US EPA can be addressed as a function of the needs of these end-users. The
Contractor will make the data available to NCSU, the NCDENR-DWM or the US EPA in
alternate formats, as required.
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ltundwater Sampling Quality Assurance Plan (lsion I)
North Carolina State University Lot 86 Sampling Site
January 2002
C ASSESSMENT AND OVERSIGHT
Cl Assessments and Response Actions
Corrective action will be initiated upon identification of any condition that is unsafe, that
is not in conformance with quality management systems, or that prevents personnel from
performing their work with the quality or standard of care required.
Essential steps in the corrective action system are:
Identification and definition of the problem, assignment of responsibility for investigating
the problem, investigation and determination of the cause of the problem, determination
of a corrective action to eliminate the problem, assigning and accepting responsibility for
implementing the corrective action, implementing the corrective action and evaluating its
effectiveness and, verifying that the corrective action has eliminated the problem ..
The QA Task Manager will ensure that these steps are taken and that the problem which
led to the corrective action has been resolved, or cannot be resolved.
The QA Task Manager may issue a Stop Work Order if appropriate corrective actions are
not taken, and the non-conformance is considered significant. Prior to issuing a Stop
Work Order, the QA Task Manager and Project Manager will attempt to resolve any
outstanding nonconformance.
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!undwater Sampling Quality Assurance Plan (R,sion 1)
North Carolina State University Lot 86 Sampling Site·
January 2002
C.1.1 Corrective Action -Field
Project tasks or items that do not conform to the QA/QC requirements based cin working
documents or field procedures may be identified by project members who know or
suspect that an activity is not being performed in accordance with the applicable
requirements. The QA Task Manager will be informed of all such defects. The QA Task
Manager will act in a timely manner to verify whether corrective action is necessary.
If errors in field procedures are found, corrective action will be initiated. The QA Task
Manager will use the following protocol to ensure that the nonconforming activity is
addressed and new QA/QC requirements are established, if necessary.
The QA Task Manager, in conjunction with the Project Manager, will review the activity
to identify the source of the problem and develop a plan to correct the nonconforming
items. Corrective actions for field sampling and testing problems will be developed with
assistance from the field team.
No additional work dependent on the nonconforming activity will be performed until the
problem is corrected. The Project Manager will have the ultimate responsibility for
ensuring that corrective actions are fully implemented.
The QA Task Manager will notify the Project Manager when corrective actions are
completed and will conduct a follow-up audit.
If the problem(s) has been corrected to the satisfaction of the QA Task Manager, the
activity may be resumed.
C.1.2 Corrective Action -Laboratory
Laboratory corrective action procedures are provided in the Standard Operating
Procedures (SOP's) and Quality Assurance Plan (QAP) for the laboratory performing the
analyses. Labaoratory and subcontractor laboratory SOP's and QAP's are presented in
the SAP.
33
clndwater Sampling Quality Assurance Plan (R,sion I)
North Carolina State University Lot 86 Sampling Site
Janu.ary 2002
C2 Reports to Management
Laboratory data will be ·reported in accordance with the Laboratory Standard Operating
Procedures and the Laboratory Quality Assurance Plan, (presented in the SAP) for full
deliverables including all raw and processed data applicable to the analyses performed.
Reporting requirements for definitive data may include as appropriate:
• Narrative and sample identification cross-reference,
• COC documentation,
• Summary of analysis data sheets for samples and QC samples,
• Instruments tune,
• Initial and continuing calibrations,
• Method blank data,
• System monitoring compound/surrogate recovery data,
• MS/MSD evaluations data,
• QC check sample/LCS data,
• Raw data quantitation reports, chromatograms, and mass spectra scans,
• Analyst work sheets and run logs, and
• Chart recorder output traces.
Reports to management (including final analytical data, spreadsheets integrating
analytical data and water level measurements, groundwater hydraulic gradient maps, and
groundwater contaminant isoconcentration maps) will be submitted to at the completion
of the sampling event and analysis of the samples. The data associated with the event
will be submitted in Microsoft Excel® spreadsheet, with copies of the data in paper and
electronic form.
34
Andwater Sampling Quality Assurance Plan (R,ion 1)
North Carolina State University Lot 86 Sampling Site
January 2002
D DATA VALIDATION AND USABILITY
Data validation is documented for each report group and will be performed in accordance
with the Laboratory and subcontractor laboratory QAP's. The Laboratory Manager is
responsible for assuring the overall quality of the data. · ·
35
lmdwater Sampling Quality Assurance Plan (R,sion I)
North Carolina State University Lot 86 Sampling Site
January 2002
Dl Data Review, Verification and Validation
Laboratory .data will be reduced in accordance with the specific requirements of the
SOPs. The equations and calculations used in data reduction are instrument-, system-,
and method-specific. The SOPs discuss the method of quantitation and calculations for
quantitation. The analyst will perform the initial and most critical review c,f the data for
QC compliance to the protocols. Auxiliary data produced for internal records will
include laboratory worksheets, laboratory notebooks, sample tracking system forms,
instrument logs, standard records, maintenance records, calibrations records, and
associated QC. These sources will document data reduction and will be included in the
raw data deliverable (EPA Level IV) package required for groundwater sampling and
analysis analytical reports.
36
lundwater Sampling Quality Assurance Plan (R,sion I)
North Carolina State University Lot 86 Sampling Site
January 2002
D2 Verification and Validation Methods
The QA Task Manager or his/her designee will perform a completeness evidence audit of
the Laboratory and Coniractor reports of analyses. Full raw data support is required in
laboratory reporting. The report deliverables provided will be audited for completeness
in documented support for the analyses. A method-specific checklist of data support
elements will be used by the reviewer to document the completeness audit.
No data-use validation effort is designated at this time. The completeness evidence audit
of the reports of analyses will assure that the data will be validatable. Data validation, if
performed, will be done in accordance with guidelines established in EPA Contract
Laboratory Program (CLP) National Functional Guidelines for Organic Data Review
(February 1994) and EPA CLP National Functional Guidelines for Inorganic Data
Review (February I 994), as applicable.
37
.ndwatcr Sampling Quality Assurance Plan olsion I)
North Carolina State University Lot 86 Sampling Site
January 2002
D3 Reconciliation with User Requirements
Results of the groundwater sampling event to be conducted in accordance with the
Sampling and Analysis Plan will be reconciled with requirements of the end-users of the ·
data as necessary. Possible anomalies or departures from assumptions established in the
planning phase of the project will be brought to the attention of management,
documented, and forwarded to NCSU, the NCDENR-DWM, and US EPA, as applicable.
Issues documented as anomalies or departures will be addressed in accordance with the
provisions of the Sampling and Analysis Plan, and the requirements for corrective action
outlined in this Quality Assurance Plan.
Limitations on the use of the data will be documented and reported to NCSU, the
NCDENR-DWM and the US EPA as applicable.
Documentation of limitations, anomalies or departures as described herein will be
documented through notice by telephone, followed by confirmation through written
records.
38
.,
North Carolina A
Department of Enviro~nt and
Natural Resources
Division of Waste Management
Michael F. Easley, Governor
William G. Ross Jr., Secretary
William L. Meyer, Director
Mr. Michael Townsend
Superfund Branch
Waste Management Division
US EPA Region IV
61 Forsyth Street, I l '1' Floor
Atlanta, Georgia 30303
• &i,"A
MCDEMR
May 21, 2001
RE: Groundwater Sampling Quality Assurance Plan (Revision I)
North Carolina State University Lot 86 NPL Site
Raleigh, Wake County
Dear Mr. Townsend:
The Superfund Section of the North Carolina Department of Environment and Natural
Resources (NC DENR) has received and reviewed the document, Groundwater Sampling Quality Assurance Plan (Revision I), for the North Carolina State University (NCSU) Lot 86 National Priority List Site. The Superfund Section offers the attached comments.
The Superfund Section appreciates the opportunity to comment on this document. If you have any questions or comments, please feel free to contact me at [phone],
extension 349.
Attachment
Sincerely,
Do..vu:i. B. fl?_a.J:ti.su,-/ cUc
David B. Mattison, CH.MM
Environmental Engineer
Superfund·Section
------· ..... --.. --··· .. -·
1646 Mail Service Center. Raleigh. North Carolina 27699-1646
40 J Oberlin Road. Suite J 50, Raleigh. NC 27605
Phone: [phone] \ FAX: [phone]
AN EQUAL OPPORTUN!n' \ AFF'IRMAIB'E ACTION EMPLOYER -50% RECYCLED / 10% POST CONSUMER PAPER
Mr. Michael Townsend
May 21, 2001
Page I
• •
GROUNDWATER SAMPLING QUALITY ASSURANCE PLAN
(REVISION 1)
Section A Project Management
I. Please correct the title of Section A to state, "Project Management."
Section Al Title and Approval Sheet
2. Section Al was left unsigned. Please note that all future _documents shall be signed, sealed and notarized as appropriate by the proper signatories.
Section A2 Table of Contents
3. Please correct the title of Section A in the Table of Contents to state, "Project
Management."·
Section A4 Projectffask Organization
4. Please correct Footnote I on page 8 to state, "Standard Operating Procedures for
CompuChem, Inc. are presented in Appendix B of the Groundwater Sampling Quality
Assurance Plan."
Section AS Background
5. Please revise Section A5 to include a vicinity map and a site map depicting all groundwater monitoring.wells and surface water and sediment sampling loc·au_oIJ_s.
Sec!ion_A~ _ Projectffas_k Description
6. Please revise Section A6 to identify the 34 groundwater monitoring wells to be sampled.
Section AS Special Training/Certification
-· -·-·-·-7. Section.AB was inadvertently omitted. Please correct this oversight.
Section B2 · Sampling Methods
Peristaltic PumpNacuum Jug
8. Please revise the last sentence of the first paragraph of this section to state, "All equipment should be cleaned using the procedures described in Appendix B of the Groundwater Sampling and Analysis Plan."
Mr. Michael Townsend
May 21, 2001
Page 2
•
Trace Organic Compounds and Metals
•
9. Please correct the second sentence of this section to state, "All sampling equipment, including pumps, hailers, water level measurement equipment, etc., which comes into contact with the water in the well must be cleaned in accordance with the cleaning procedures described in Appendix B of the Groundwater Sampling and Analysis Plan."
Section B4 Analytical Methods
10. The first two sentences of Section B4 are incomplete. Please correct these oversights.
Section B.4.1 Field Based Analysis
.11. Please revise Section B.4.1 to include provisions for the measurement of turbidity.
Section B.4.2 Fixed Base Analysis
12. Please revise the third sentence of Section B.4.2 to state, "Methods to be employed in the performance of these analyses are documented in the Standard Operating Procedures contained in Appendix B.
NORTH CAROLINA • .
DEPARTMENT OF ENVIRO&NT AND NATURAL RESOURCES _ , .•
DIVISION OF WASTE MANA~ ENT
MICHAEL F. EASLEY, GOVERNOR
William G. Ross Jr., SECRETARY
WILLIAM L. MEYER, DIRECTOR
Mr. Michael Townsend
Superfund Branch
Waste Management Division
US EPA Region N
61 Forsyth Street, 11 th Floor
Atlanta, Georgia 30303
March 12, 2001
RE: Groundwater Sampling Quality Assurance Plan
North Carolina State University Lot 86 NPL Site
Raleigh, Wake County
Dear Mr. Townsend:
Alita
MCDEMR
The Superfund Section of the North Carolina Department of Environment and Natural
Resources (NC DENR) has received and reviewed the document, Groundwater Sampling
Quality Assurance Plan, for the North Carolina State University (NCSU) Lot 86 National
Priority List Site. The Superfund Section offers the attached comments.
The Superfund Section appreciates the opportunity to comment on this document If you
have any questions or comments, please feel free to contact me at [phone],
extension 349.
Attachment
Sincerely,
J: ewi.d 13. fY/~ /d.t..
David B. Mattison, CHMM
Environmental Engineer
Superfund Section
1646 MAIL SERVICE CENTER, RALEIGH, NORTH CAROLINA 27699-1646
401 OBERLIN ROAD, SUITE 15.0, RALEIGH, NC 27605
PHONE: 919-733·4996 \ FAX: 919-715·3605
AN EOUAL OPPORTUNITY/AFFIRMATIVE ACTION EMPLOYER -50% AECYCLED/10% POST-CONSUMER PAPER
Mr. Michael Townsend
March 12, 200 I
Page I
• •
GROUNDWATER SAMPLING QUALITY ASSURANCE PLAN
General
I. Please revise the Groundwater Sampling Quality Assurance Plan in accordance with the
document, EPA Requirements for Quality Assurance Project Plans (EPA QA/R-5). The
Groundwater Sampling Quality Assurnnce Plan should demonstrate unequivocal compliance
with the document, EPA Requirements for Quality Assurance Project Plans and should
include all elements described therein. Many required elements have been omitted or have
been rearranged in a haphazard fashion. It is suggested that the East Coast Environmental,
.. P.A._ (ECE) revise the Groundwater Sampling Quality Assurance Plan using the document,
EPA Requirements for Quality Assurance Project Plans, as a template and incorporating all
elements into the revised document.
2. Please revise the Groundwater Sampling Quality Assurance Plan to include the Quality
Assurance Plan for Compu-Chem as a separate appendix to this document.
3. The Groundwater Sampling Quality Assurance Plan makes many references to field standard
operating procedures (SOPs) and laboratory SOPs. Please revise this document to include
copies of all applicable SOPs.
4: Please revise the document t~ include page numbers on each page of the document.
Section 1.0 Introduction
5. Please correct the first sentence of the third paragraph of Section .LO to state, "This QA Plan
outlines the system of policies, organization, functional· activities, quality assurance and
quality control (QC) measures developed to ensure that data developed as a result of the
implementation of groundwater sampling and analysis at the Site are of a known quality and .
·content appropriate { or their intended use."
Section I.I Groundwater Sampling and Analysis
6. Please revise the frrst sentence of Section 1.1 to state, "Objectives of the sampling and
analysis of groundwater samples from the Site include providing for the continued
monitoring of the contaminant plume, augmentation of data for sampling events previously
conducted at the Site, and the provision of additional information for use by NCSU as to the
attenuation of the plume through natural processes."
7. Please revise the second paragraph of Section _LI to state, "To the extent possible,
procedures and analyses conducted in the performance of the sampling and analysis of
groundwater _samples from the Site should: 1) be representative of the conditions at the Site
.... ,--. ~.
• •
Mr. Michael Townsend
March 12,2001
Page 2
during the sampling event; 2) be consistent with the methods employed at the Site to conduct previous sampling events; 3) provide defensible data consistent with quality
assurance and quality control plans a,sociated with the analyses; and, 4) conform to the U.S. Environmental Protection Agency (US EPA) May 1996. Region IV Environmental Investigations Standard Operating Procedures and Quality Assurance Manual (ESD EISOP-
QAM), the Draft EPA Region IV Suggested Practices for Evaluation of a Site For Natural Attenuation (Biological Degradation) of Chlorinated Solvents, and the Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents in Groundwater
(EPA/600/R-98/128)1•
8. Please revise the-words "persons(s)" and "task(s)" to be plural in the third paragraph of Section I.I.
9. Please revise the footnote in Section I. I in accordance with the above comments regarding the second paragraph of Section 1.1.
Section 2.0 Project Organization and Responsibilities
10. Please revise the word "task(s)" to be plural in the first sentence of the second paragraph of· Section 2.0.
11. Please define the acronym "NCDENR-DWM'' in the first sentence of the second paragraph of Section 2.0.
12. Please revise the words "review(s)", "plan(s)", "document(s)", "set(s)", and "action(s)" to be plural in the third paragraph of Section 2.0.
13. Please revise Section 2.0 to identify the applicable regulator agencies and their involvement -with the site: ·
Section 3.1 QA Objectives for Measured Data
14. Please define the acronym "ASTM' in the last sentence of the second paragraph of Section 3.1.
Section 3.1.2 Precision
15. Please define the acronym "LQAP" in the last sentence of Section 3.1.2 .
Mr. Michael Townsend ·
March I 2, 200 I
Page 3
•
Section 3.1.5 Comparability
•
16. Please define the acronym "SON" in the second sentence of Section 3.1.5.
17. Please revise the fourth sentence of Section 3.1.5 to state, "Field documentation and QA evidence audits will be used to establish that protocols for sampling and measurement follow appropriate SOP's."
Section 3.2 Certifications
18. Please revise Section 3.2· to include· the laboratory's North Carolina Department ·of Environment and Natural Resources (NC DENR) certification number and certification status.
Section 4.0 Sampling Quality Assurance Procedures
19. Please revise Section 4.0 in accordance with Section 3.3.1 of the document, EPA Requirements for Quality Assurance Project Plans (EPA QA/R-5).
20. Please revise Section 4.0 to include the United States Environmental Protection Agency (US EPA) methodologies to be employed for all chemical/geochemical analyses.
Section 4.2 Preparations for Sampling
21. Please correct the indention for Section 4.2.
Section 5.0 Method Requirements '-Field & Fixed Base
22. Please define the acronym "ALPHA" in the second sentence of the second paragraph of Section 5.0.
23. Please revise Section 5.0 in accordance with Section 3.3.2, Section 3.3.4, Section 3.3.6, and Section 3.3. 7 of the document, EPA Requirements for Quality Assurance Project Plans (EPA QA/R-5).
Mr. Michael Townsend
March 12,2001
Page4
•
Section 6.1.6 Matrix Spike/Matrix Duplicate Samples
•
24. Section 6.1.6 indicates that analyses for aromatic and chlorinated hydrocarbons by US EPA Method 6230D are to be conducted. Please provide justification for not conducting analyses in accordance with Contract Laboratory Program (CLP) protocols, namely for volatile · organic compounds (VOCs) by US EPA Method 8260B, and semi-volatile organic compounds (SVOCs) by US EPA Method 8270C.
• North Carolina State Universit.land-
grant university and a· constituent institution
of The University of North Carolina
Office of Finance and Business
Business Division
An Equal Opportunity/Affirmative Action Employer Environmental Health & Safety Ce,
Campus Box 8007
Raleigh, North Carolina 27695-8007
"~, ~np(G; f ll WJ f '~hsD/
March 6,20,
MAR 1 2 2001
Director
Environmental Affairs
Industrial Hygiene
Health and Safety
Radiation Protection
!fax)
Mr. Michael Townsend
Superfund Branch, Waste Management Division
US EPA Region IV
Atlanata Federal Center
I 00 Alabama Street, SW
Atlanta, GA 30303-3104
SUPERFUNO SECTION
Subject: Sampling and Analysis and Quality Assurance Plans for Spring Groundwater Sampling at Lot 86
Michael:
Enclosed for your review are the subject plans, These plans were submitted to David Mattison on March I for
review.
Based upon my experience with the quality and thoroughness of David's review, we are planning to sample after
revising the Plans per his comments. We expect to be sampling before the end of the month.
If this presents any problems, please let me know.
\
Enclosures
cc: David Mattison
Sincerely,
(!
-!'~
Duane A. Knudson
Environmental Affairs Manager
919.515.423
919.515.685',
919.515.686•
919.515.685:
919.515.289
919.515.630
.. , •· •···~~! ,~;;~,~t:~'''.;;J2'·
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,1 i ,":/Objectiv¢fof.t~e sa_mpling arid analysis <J(gr~undwa_ter s~inples .f.rom_.the ~ite·inclt1de\ ...
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· ·• :'.J. "'-•. , .· ·-._• '. and Quality 'A_ssuraizce. Mdn'iwi O(ESD'EISOP~QAM)/ari_d the Tech~_icdl P.rotoco/ fqr. · ·· ...
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": o;. ' . ; _E~al,uali?g J'!~tzir.r,il Att~ii,iiat(cil!_ of_<;:~lor/_n~te1if:_olBe~ts in Gr,oundwat~r (EP1{6rWIJ-\
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. Furthe( objectives o(the sampling 'aiJd;a11l!ly_sis'of grqundwater-sari'iples,from the S_ite ,
--.••;i~~~;;~?~l:e ~:~~~-~~~f i o{ tf {~a~~ty,~f f e:·r~~s°-f 1f ~\~6·~1uc_ti~g; if t~iiriJ1i~~ ~v~/2t, 'ahd,·;
the mitigation of any. potential _for additional damage. to the _environment through· the
t ?i}jbt~ierpe;f~~;;:;~> ?f ;~e:i is~( s);}s~ci~i.at:1·wit~• th~ sainplirif tri{ :~~\~~i\ :·•.. C ·•
; : _:_, '}rhe S&A'Pt~n 'dev~i;;ped)oi th~ ;impl~-rii~~tat\on·6fth6 ~ampli~idfth~ \Ve.Jl~j{the ~i;e• · .
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. · associated with-field-based and fixed-based parameters .to be measured for each well at • :._~ _::;.:·-.. : ·:,_. __ ·:·.:,: .. :-.-: -_: -·/ :: ';·,;··~ :·· .• :~. __ -_: __ , .. _. :: ·.'.<:_-i_.-;.:: .'· .. ,7_""• .. ·::: -"~::..: _c·--•. -:·. ·:' ·., <~:-: .. <· .: · . .-, ·--· .. -·,·,:·, .. :'·> :
.. , . ., . , ·1he Sit~;'irie_t~ods for the; pro~ufe\llellt. 0J.·hy~ra11lic. gnidient. ~~ta; piirgi\l!s of.-,well~, ·, .. : ,. , ... ;;. •'..'_ .·_·.-: '.< --~ '·_ . -·-.. ';''. :.';\ .. :. '·: -.. :,, : \, --.. ~_ .. ,•. _;-: ,_ ::-, ,-.,' _: .. !_;; .-,.:.: ··. '. :, •::·. · .. \ -·, . '_.'-. _,.-; ... _. . ,; ;-.. _:_ '·-:: .. : ·., : ,' : ... : .. ·
.. ".. , • .. ·, · decQhta!J}iil~tiori proc~dtiies, sampling proce_clut'es; .Chain-of-Cus\ody docu_irientation'Jor _.· • . ,. · . .'_ -_ ,_ .. ·-,: .:.-.-:~?:. ·: ·I . :~· ,,.;:· .•· , ,'.· J ,._;;:;-\:. ·; .'., .. ' ., :_ .·_; .:, , :, -;;.::_ ~-: ,:····. <_> --: >>--, \-:-:\'>-:> ---. -' _.':" .· _-;!.,_:' .:_:~:;;:· . . , . , . . .
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.•. : Mr: Knudsen acts'as the _Key ,Contact with USEfA:arid the NCDEt,'R~DWM, ·establishes
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. ,, '.overall_-scope. for. :work,: perfoiiriance. requiremerits :and schedule.· for.· project task( s )/ •c,.~,:··:.--~ ... :~ .. · .. -~-~•·.:·~--;i_,: ,;.",·>:;_'.~'_'):.·'')t•\: .. :•<",·•;-/'\.".·.::,\··;:."' •.. ,·.-:, ·, .• ·; .. ·•··:,./._-•,' "_' _·_· . ·.-•·~:'. ·.· ,.·-\~·_/'.;:~·•. ·_: ·:~ ... _._. , ..
reviews ·all: work• plans: arid ,,commuriications.,related to>the .performance .ofthe::·, .
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·.; ··ct(iundwater Sampling and Analysis; :authorizes.'.the performance otthe \a~ks assciciated·:
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:::. with.the'samplirig activities for,the Site, arid, conducts submittalsto the.US EPkarid/or · ·:::·.·_,.,.-:·:.;.'//'.·./,:_::~----;',_;._::.:,.·-:-... : ·_-:,__: .. ··:''::-·: · ..... · :,:;:":_·.-,.•: :i:\·",:, ·.: .,. __ -_ ,·;::·\'::_":--·._ ··:>~·· .-;::•.:: · __ :-·.-~·.:_'<?: __ ;··.·;;' ..... ;:._.--::
· , NCDENR0D\VM, as.reqmred by law,·,.J .: , ·, : . . , .. -.... -•·':: . :."--~<~-'<<·'··:.i:··•,., .. ', :· .. ··-.·. :/~·~·.:,.::-'. ,_··:~·:~---.' ·. _._1:'· .. , ·.'. , ·,·~ . . .. . :--, : .. ·
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. : , . Mr.' Thomas R. Will, NC LG # 1164, Ea.st Coast' Eovir6nmental, P.A:,, .. •,... ··, ',.>> ,.,,·. •' : :,,,.;_,:-.:;. . .. ". .' . :·-,: ._ -'.(_\: :·. ,,.,_ . ,• '.. . / ...
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Contractor;'), M;.'wiil ·is respon.;ible-for overall.technic.al responsi'bilit{and ove~sjght for "i
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... the tasks associated with the performance of the 'Groundwater Sampling and Analysis for
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.. the Site ...• rv;Ir. }ijiJI. shall j;'oordin~t('. '. all ;<lctivities .t_ci ,1:Je performe,d at{the Sit~ .in the\.·· ; >> .. ~_::.:-: :;.'" · .... :·_: _·.· ·,:·.,~! .,::-'..' '.:-' ·:;.:--: \ /'·:;-_✓·:· ,_.-_·., ,'.'. ,-:.-._· ,:·.:,:~-•• _: :-.~·'._.).:-:". ;-: •• :, • ~-: :,•,"_:'( ':> · '. :•-.: -~----:-,--... -~.:7:~-_:.;. •.\' .'·'
; ·., ):oriipl~tio.n of th~. ·project; conduct :te~hriical_ /eyiew(s) 'of all pl~n(s);, dcic\!nient(s) .and·••··.·· . _:-/: .: ', .(. :·,:. '·<~<·.;-/ :·,:{ .... ·:: : ... · -~· ,:: -:···"'-;, ..... _::-·i-;,!;\i·.s'._,: ::.:_::' ~--:: •:_·:•'. ,, ·_ ;'.· :, y_:~_;:. :.: ,<,:-.:··.,' : __ ·_·: >} :·::-:,' ::~<\_;".<~-_:_: .~•:,:-,:.'-'; .;_-;:-.:,,r-;:·. _'·{:/ ,, .-
. : · :·\dat~, set(s)·,~SS()Ciated:,yith tpe_•pt:iJoima~c;e ()fJffe. troje9t, ,lll()!ljtor iictiyitiys J\l' e9sure., ,'
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)',\ ,/,'.; .. ". corrective .action(s) ,for· any·:QA/QC.'deficiehcies=.id\iniified ·in 'the',p~rfcirmance :of. the ;:,,, ,
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·c-· Mr.'Thomas R,-Will, NC LG# 1164, East Coast Eiwironmental;P,A., · ·
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. ·: ./teid.Operaiions_Te~hnii:idn!i notid ab6~c:.~illb~~_r'respon;i~i!itYf<)f tre'.pe~forihancfof .· \' . : -.;_, ,.: ,· :·.: .. ;: :·,.":. ·. ·:: '~'-.:• .... ; ,f, :~:::.'. ::-: ,' '.,, ·. '.~ .... ,:: -·-/··.:', \ ',, .. -·,;.,.", .-.-·<:· :" .: '·:"•:. :i,;::,:·'·-;,'.; .,,: ;· :,: :··-,'.·:.-: . ;. ·:· ,.' ::•: :· >..: ::. : _::; :(: ii ,: .. )<: 'CJroimd.yater Sqnipling}'askfas qtitlinediq the'.S&A,P/qll: :rhese.individuais:wiU be'
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·:1 ·, ':, ·._in· the actual P.ei'fohnance of:the ,preparations, p_urging; and-.:·s!lmpling ·_of,the;:\\'t:lls -;_:,,,
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\' associated with the Site;perfoririarice' of fieliFbased measurements in'the perfoima:rice of:/ li .... ·:·: ·,. :;_,;, :· ;·:_:• ·, .: ··•:i~~~Jr9J~~\-·a_n:f i~i~rli;{9(tomplj:ri;~~ii~:¥(~?1;rt;;:~~;:~$fa};fki~fl~i~~{iif :~:'; .. :.::' ·:
~.·. -. ;,_-·.0:-i·.: . :: theperfonnance of the 'project.: . :., ·:: ·' '::::-~ :,;"< -~, ·::': ,,_. .. , ·, \ .· :-' ' . '··· · '-r , ·:·· ·:... . ·.: . .:<.-·
"• · ,·:·:, . •. <. · '. .. , Standard Operating Procedures for'CompuChem, Inc:'are presented in Section B of the Sampling and . ' ·, · '·: ',' :t ·:;\/:f .?;:::;;r_A;t~}::f; ;:j:}? \'.'.:(~] )J ;7(iJf :!t~ i :~ Jjil~{bel}i ;;}~]:{\/);; tti:\,_~):;;::;i_·,: __ \~,_'.',_._:_:.· .. :_._:.i.i:'~ ·;::;'.:t
.; ·'·:·: ... •·,·. :, ·;· :" .:-: < · · c ::,.-···_,. ';. ·.(919)'772-0268•'Fax:'[phone]"', ·:. •·.,. ':·: ,. :: ··.,, ,, ' :{_;,. \:i.:, .. : ; :_-: <,,::i': ; ·. ·:::' . • . . '--~ :\: /:. >-~ !'._··_ .. :_:_:}}'~ .:'-: ,: .. )>; ' ._;,:,-:·-:·,; : -:> ·'. ' . ·: / } :<
. i. . ... --~ .. ,~ ' ·,'·.' ... , '.·_.·. . ' ~ ': .. , ,_ '" . . ··,. ~'. ; '·
1 -:·.•-··.> :Z .. :from·the·. 1\'erfrirrnai:Jce ·of the_ ,pfoject:'\QA'cibjectives,cati.':be: gualitative or .quantitative '.'.· ,·,: · '!. .r~, . :-.\/;•~·._-'. .... =•.::f /.-~:::~};:\:·:.,~·:}~_·>~·:_:::: .-.:.:-:·::\~_,;,::_; ~:.:,·:::·:;:,..~.:-_,:l::,_,_. ~~-·(_···:/ ·_:_._~~; (:-: :..·-/_:' :: -?.,_·.,. ·:~·;_-•; ·: / . .-:{;,-_.:~ ,:: .t _:, ·, _:: {\J.-_:;_, -~~-::·\'.-~/:t\: f/:~_-_,.'-_-. _ : > · /.'_,,,_,;' '.i ,statements": which 'specify the standa_rd of-qualityrequi~ed '.to support eac_h '~lemeht_ofthe \ _-
· •~•;::){:tCJtf Sf Q~i~!i~~tt!Jittt j:{~tli4ftJZ~Jf :~!j!f 12::f t;t:\
-,! geti_eriite'il by tlie"task,as outlined below:i•-t\·:,<' -. ·' ;<· '. ·:·:y :,·.·:,'; ·<··:· ·., .. -.:: ....... ~~-:_:-~(,:.·:;._ -~·.,: :· ':. ··< _,_·:~\_:_,_~:.-.-:·.'._-, :.·::_.(·~~-',': ,,: .· -·::·,: ... ;. /_ .. :.: ,., :-'::'.<· ··: -:~_,,:_ .. ,)-: -:·-·.:_: :\ ;:" ..:~.
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· --: : • '·: .. Perforni.ahce and docuine'ntation:ofthe Groundwater Sampling and Analysis shall "·<":· .. '.1.:,:'.-_i:;::.-:<.:\.: ;' . ·:-<~ _. <·:.'.'i .:<:>-:·.,_:.·.::_:_:;:f. : ':'_.-:_.', ~:::: '/\:·' -~·_·:··~' ->_; :-:·::>.:-: ,..,::_,_i' </._;· .. -~ / :/ ..... ,., ... _ .. <">
___ be·. conducted frd,uch. a,·nfariii.er' as. to_ erisure' the· resulting data areiof a known;-
, ••: . '• . !" • • , •·•,;• ~ : . , ' , • a ; •. • • ' s -•• '• : •; • > ••• •• • • • • •, \ • \ • ,••I • .-:, • ::• 1 '•" >
· · defensible.sua)ity;wpile 'in strict conformance to specifications of the work,'_· -, , _
-. • ' 'rvie~~~~e~~nt' ;;/field~~~~~d pa}aietert~iianb~ 66riduct~c{ i~ ·~u°bh'a ~an~e{iis:t~ / ··\:·_,_; .. .-;'\(>.\;:'.·-.::-,·-:::• ··-_.'_ ·.-·,-.-/,-:,.:·:\:::".·:;-:'.' _ .. :',·>t '// \·::··~ ,: ,:._::.'-·\ .. i.(•~· ~<: ·:\._.::·::-:·.:,_· . .'·\: ·:·· :-·· '• , .. \ .•
·. ehsurt! r~~ultmg data of a:kn0\v11,:defens1ble quality, •The perfon'nah_ce of field~--. ,,·
, -. ri,4~~~ ¥l~;;ini~~t~'. Si';, :}e _· ;erf {f ~(-~,;~;d Jn. a't~~-~~~f;t; to . (i~st~ten;)_;' _
; \mailt1facti.Ir~f: ~pepifi~ati()n,~}includi~g' ~~i ~~~}igiit~d to· tlie :u_se -iif ·calibrated -
equipineiit,_ and ·iri confomiartce ,with ::any\Standatd Op~~~ti~g:;,;ickitureS: !(
'';._:; .... · ~--· •.· .,. ,_ ..... ·· -~-,;. __ '.!., . .'._..:-. ;'._ .. •.::, .;,·: .. 1\:'·." . .".',:;·,, ;.•' :_:·;,;,·· , -.,-
., <~pplic~ble'.; ,' ;-•,, . ' _: ' . . . . ·:. _: . :, .: ' ,: , / . '. \,:: ·-· •· .,
--''? -All asp~cts iif ·11-{e .·Joi-k.are,to be'~ocuinerited·i~'ili~ ·e(tent"ri~"c~ssafy·:to· ~e~ify·:>
:·_/:,:/:',; .. ~ ·:_.<· < .:;-· ·_;: (. <".;..:·-:/·· -·. ->>.-...·.,-~-r\./:,/ ':.:.-;:,·:.:·.· .. ·,:2<·-<:./ /c:<·::."-_) -.'·.:;~----::·. ::·~·\ .. ·'.;./;· !;-~~--:-.·-: ',· .,-·. ,.. . . --· -
,o.::· )., adher~_nceto ,the_ s_cope of_wor~; aild provide d~fep~1_9le_ arid accurate_df!_ta:-
. :: ;~-•~·:_I_::/_._·.'~-'::.'.:··.:;_.,:::.·•. :r::. · ·-: .. :.: :·:·: ·_·:, _'.".· _/ .·'. .-'·•;"_·,.;.:.:·. ,:i._ <,-~-:~: _ _.:_.·;-·( ;,:.~.~ / ;, .:-:.i:_:·:" _··>..::·::·. ;.'~;:..,._-_."-·;. -:•·.
: • · ,D<1til fo,r _fix:ed_-base·d analyses ~_ill be ~o~sid_efod :'d.efinitive data'\'.
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: .' : · ,' •,' ,, •'. · .. , '.-·,•, ::-.<•:.GroundwaterSampllngQuahtyAssuranceP.!,', ,., .. · ... ,·' ,'. •' , .. ;,.. : : , · · · ,. 1, • ',' ",'•'• •_,~ •,t.;:" f •,, •e , , •, , , ••••~,. "•" '1 / ,• ••·" ! ' ~•,,
,. • .-1_ •• -,:. -' ;1 • :·: ~ ·f'--.~:;· • :· ... :_ ;_ •: 1, "':.. • :. ~ _-:~'?rt.h C~roJ~n<!-:State ,University_-Lqt 8§ S_ampling Site ·;. ·~ ', ~· ~. :;-, · --~-' .. '• ,.~ -, · :',--.. -· : _ , ,
:?:,..,; : _:,,'.',}; :, : ,: .'":, ,·;>.' J\ccur,acy,'_1s;,,normally · ~xpresse1 ·, as a pereent;.recoyery>('l;o.R) ·, of _:a. surrogate _:sp[kf; .,' \, ,.;·:·,:
··1·"•. ·:,:\;:\:;tDi~;~;iyi~{{7~1I;1'~~!~i;i;t~1:,i~f?:(l~ilY;;%1:c~ifht~~!,r(::~;/~({fc~fi?~f:{bJ~~~iJet})}i:/
:•, ·: /.:. ;:,,·for.measurement data aie,presented ii:i-Ta_ble L,·.Th(, Lah:orafory Project Miiiuiger will be -, ..
':r··• .;\:\;:.;:;;~~6:~~ihi~}i~ ~hsu~i~i~61};;il~~k ;i~Ji,~6\:ii/ac~' 6b)~~;;~i(s ).'>,ilJ11; ~t~tt'. t~it' aJ/,i:':", :
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' I -.,-._ :·. ' _: '' ., th~'i-rteth~ci' ~i--releva~t SOP(~)-''?·.· ;' : . ' >'.•, :,::..,_,)·-~\<.:,'_.'/-.'~)<-<;'/'./:~)::·-·; --~~---•' ·.· .... )·,~·-'/ '_:._,-' •,-.·; . ··: ::-~'.~; ~
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.. , · .. -· . ?e.nsit_ivity is -,i_ quantitative sta\einerit that conveys the lo'Y.est {eve! of measurement that' _ -. . .. . ·.:_,.·.· <, ..... ,_::,.··'/•.·. ,:·~--~:·~: ,._. .. ;.·_;'-··-'::.'..''.s;'-···--··: .;'-.·_ •. -'.:,,. ·-;,+, ·,:-:. ;_.~·-.• · .. '.:.· ... '.;>".'.:-'.::,..,_.,.,, ,; ,-·;·,. :·, •., _.:,;.,.
,;can b'e.<distiriguished froin background with a giyenlevel ofccihfidence.-Analytical-, ;· •' .. ·-<: . ··: · __ .-__ ·--.. :-_ ·_: .. :~>···· >~ <' .... ·\:·.::, : . -.·-·. ,< <· ... ,·: .·_::· ·--:.'./_. -~ ,-,_~/" <· ·:·~:·:· _·· .. ·,;.-~:·\.,': :_;./ .-. ':'::, · ... _·:.:;_ :·:.'°· : . ,.-•, .
dete<ctiof_lirriits .(sel\sitivity). sh_ould ~e)qweri?ugh to·confirin'the_ presence :or .absence of-
.... , . : ,., __ ~,. :_,:-:·:,/,.·".,-.. :, __ ._~r·,'·."·-"·.:-:• ... -,'.<-·'·_•_--···. ·-_.· _--~_···.-,'·· .··
--a: given \lrialyte_ ~t _·• a coricentrati_oh: gre~for: that remedial, per(onnance -standards where · :,
-~pplica!Jle: ·. ;t:sjlecified~ie\:~i/ bf)i~~isi6n-arid\Cciliacy;, Cieri~r~l \~pofii111i l_imits are .·
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-_ :matrix7deperident'.Specific detection limits are presented in the!abofatory rriethod S.QPs .. · . ,'•· ' . ·' . '· .. :· ·'. , . ·--. ' . ,
r-:;\;\:::\•~: '.}~'.-::};;'-} \;' ':·\}??. ;) :;{:/{;! ;,\;::.; ,//~:'):>\r '.\/:.; ,.:.:,;:···, --·:<:,·-;:;-:\~::::-::,:x ;,::~::: i\:~;;. ;_. ~ .·,._ -
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' • : ,~: ·: •;. ~; •. ·.-· ,, • -//·.,,:· ... 1~ ·, •• • ;:.~.:•North Carolina State University-Lot 86 Saffipling Site ·,, ·,, ·. ',:, ·-:'y, • \. · • -:. ',,' r ~ ,_.; ·,
!?:t~:,f ~ :);iSi:;t:i;}:t:;iii;:f 1ti•·~(Ef1 f Jf ;\)Y::tic'.I:,ti/r\i: \>Ji: , '-.
: : ,'. <<\: ;.<:'.:'-· ,:4.0)),: '.Sf\)\IPLING ,QUi\~ITY.:ASSURA~CE,PROCE;pU~s ·,:::-:· ,: 'f,_c.:/.:,. _. :1 , _:
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·, ;;;is'-:,:. ;":.·, ,/;_'dem\'mstratii>n' of,nahlfal aheiiuatiori'.at'the site is established ·in 'the SAP. ,·_Groundwater> ,:::c_ ·:_
. , r=-·:..::_ .-:: './S\~·;:>? _~:~~;--\·,~:::~_~.:•:_··._:.2.::·:(.>·::'.7:i:i::~:'~/i~-t.;::\?'. ?:'·.~-:<;-c;: ·;:_-:;.: :·:.\.:·:; '.,.:::\t_.';\:_:(:·_; :: .. _":.·.-.; .. \ ~:-: i,·/•: ':?·-~·_:;: '>·.:·_. :. ::·:_.···.::.:\\-:;:'.,i-: ._·:\:.~. ~--->./--:-:·:;-_;_: -:-'--~~/..;'.'_ ,· , ·-·
>i /,/,{ )'/.x:•:,Jrom)4,.wel_ls wiH be sampled oncejrithe spring'.oreafly summ'.er,.6f 2QOl •. f0r,i:C.:·., ::;C · \ \[:\. ..
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, . . 'f'ixed7bas_e laboratofy. analysis Ji>r .· aromatiC :arid chloririaied hydr6c~rboris) ··nitrate;-'·
...... ;-<:: .. :, ! • !·:··· .:-: -: _-· _ ... -7 · ·./ ,', •. -· .'_)'. ·,, .... ;_.-. ;/-/'.:-, · < ... _:.:._,< •_._:: /. ___ : .:. ·<-; ~-'.: ~ :. ;:." :,-_·:·, :·:,~ ·~_>-:·, · . .-·:;_[. __ : -.-\; .',,.}:---.. :' ·._,,: i. '.:, >> ~-J:y,. ;·.:\•;_.: ':;' :;\~
.. '· ·.', ; : di~~olyed . ir9n ·. (il); :.su~fat'e,'. 'ligh( hydrp~ar\Jon'. gases · (111ethane; ietharie,· a~d.-etheiie)/\
.... _i'_'•;,··.:.:• •. :· ~1·,.-.··;,__:,_.;':~.'':-:.;• .• ,. '.'.: :."•:·~· -·: . ·. :."•: -~--:".-:.-; .. _: ..... -:,::_;--,:··::·'''•: .. ~.---··.~:;/.-:.:.--,..:.·::·:,·. ·_.'.",.'•:.-: . .''. ' . alka\iriity', rnaj9r:'c~ti611s_·[Resou~c~ Conservatiqii and Recoxery Ac((RCRA) metills];'' .,
··.•::chlpfid{~iiftii!~l ~r~f~i2}iib.a.~ci-o1):' \: >· . ' . ; '. ,: ·. ' .
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'r . .··. . ... ,·.. pi-eparaiiqri fi>r' sa111pling and for,~ampling • fot_fi~ld-based: pa~am_eters,~nl fix'e~~base,
:1 .· .. ,'·:<,.•:\ .. -,_::•_::,:.;c'_:·-:,,:, .. , ... <••·•· :.· .. ·.,., .--:::,-.·.:· .. · ... ';'::':''.; ,·' ·•.·_'•;:::-":• .. ,, ··,.: ,· .. -. .-.·.-· ... :.-?··,··:<'••.: .. :-/.-'' .
·1 . , , :.::·: :· . : :analys'es 'are .established .iri :the ·SAP and referenced SOPs .. :QA requirements of ihe. ·.
,: . ' .: ' \-f~~i1;n~\ir6gfa0_~r~~st:i;i~h6ctinth,e·f~llowiH/~:cti~~~" .. ' . ' :: ,_•· . ,, ......... -,,, '
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-::· itl·, _, sa·mple,lderitifi_cations (UriiqueJQ ea.c.h Sample) ': ·_. '
.' ' ):·>•:;, ·,:ii> :\'i>\!:/_/;.,;,,\.,>,<.· .. ::;~\(.t, .. ':'., :·.-,::,-::::,,:, ,, ·.··. .,,.-·.: '': ',
. Groiindv:ater sampling _locations a~e known'(34 Iji9nitoririg wells). '.Each'moriitoririg well J f ·,,:--;:.,-.. ·-•. -.. -·.:,~·::, . \.;.:-: .}.: ~, ·L. -.: :-'·. •;. ,·_;\ ··_ .. ,•:: ,·( .. ·:/ . .-... : , -·,-, --.-\-:-, ·:-'1,_>_ ·' . .-.... • . ._.. ,\··!::.· ·: ~-,-' t;_}. ·: ... ~, .. _. ·: :, -_· •'/: .. :--.-'· ·, .. > -~ .,; ·.,:: >· •.. . . (s_arripling· locati_on). has a unique identification. irnmqer.:, -The 's'ample. id~ntificati_on ·_' ', i ..
J_};)::::·,:····. : , .. ·;'; .. hii~b~{~;;i:Ji,e.~h;,q;;~:~a~-~~,~~ :th6 itlb~;t~ri~{~~i(id~~;;~ca;(~h ~~~~~r'.-,Th~•s~~~[!i{;/ "> .. -
; 1:ii :,_.',:'i):i'.\;'.\ifttifNi1;\fsfl~;~:it?tc![~\~~~/ft~-~-·;;y~\~~ie::ifaeiil'.~fd'if~rlii:.::~~q'.iri:t{;"/'i
··.1 ;;:, ' '. (-, <: ','j '': ,~a.rnptn:igi,t~~ ~111q~~)'a!llJJ)e 1~entJfisat)Oll;\VIII, I:,~ e11,t9red 11119 th~ fi~,ld 1(lgard/or_sa1!1JJ11':f;''.';, ' -;;·;rt?.f §/l'/!i;\~Mi~?il6µ}~~.1t~cf' 1~f ())~t i~b~i ·/(irj~;~ii~tif{~j\~~t,ei{: i<1hlbiii4~ii1Jti2;ii~ii:Wi\f ~~\;,: _:,' : r: .•
, [ .( -\:~·:·:: ,-. i,·(~;ifo~6d'.in 'a~~6~dahie ;i;i?ECE';( so1{r~r si~r1t Hi~cii\ri~ 'ri~~:d~~~~-: ~~d :ih~:, >; . , .. , -.
,\ -..... ,/\-~:/--·'./: ~,1-\ /" ..... ~:;~· :· \_-,,~/( <~ ./·' : · < ,·_(,:.' ;)'., _:·. :.: ~-:·. :: . -~. _ .... ,,: "; , ,, ': ',.,;~ \ ~-'-_,.-,:_J, ·, ;:-. ·/:~ ".' ~; ~. ~-/ :~ t} ~-'' :: :,:i. -. ,-' ... -.-, .. ·, .... • · , --· project SAP as applicable··· -· · ,.,. . ,•. -· ·· · -·' · · ' ·, · · .,-, .. ·•· '· -· , · · · -· ' ·• ·, .. ·· ,
l~i-/'.;:}(:\;::·:ti;t~'.~-\?:f {\, /".;:.;•,t' ;' ;'.f ;\:r.'./\: /:'.':, ,::,,:•)){'.\~\f }f:·: S~\}-:._:/-:.·.\ \>~--;::::_\\:),~:·/.:::; j:(:'·
·• .• , >·:-:.'''. •' -~·-.·",,"·., ·: ,-,--, , ,, ... GroundwaterSamplingQuallcyAssuranceP··• ,,', ·, -',,,-.-.: :-,'_':,, .. ·,' -:: ,.: ,-_;' : : ; ·---~::~ . :_.:~: ~: .'_'; ,, :: :·· .:~,; ,: :, ::, , : .'. -,_,,, ·?-Nortb"Carolin'a State Univei-siiy-Lot 86 Sainpling'Site f ~';:-/. ~~r~, ... -, . -. . ·:'!.:,' _.! tt: ---: . ~-( . ,: · ~I{t~tf i1•ii~ ;{.1;:'.Jt1ititiiJ"!~t~'.I';~r~m'.tt-i;it;{f :l'};,J1/J}:ti/E:
: , .. _, ·/. ,_:.,_ ', '4.2-,0 , /Preparations for Samplmg,•,, '--'o· , r _,,: · ·---, ,.-_:--: -'. ,, · ·',··-.: :· ··-, . -· ,-_:: , • • •, -; ; . · ':'-'-..
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,_: ./( ': ::: > :: };;)'. :, ,~:.;-:::-.· :,·: ·'::':: ~-{~-::,,\~::>; :::/(:,::, )_·:·;;::~~'::c:_j'/\P/'.}_\_(: {i-;! '. :-::' :\-' ' ',f '' _;_:)<.: '_:,). '. .,' . ,[-':· · /:,, ~, ;:· ::_:-,> :t~e--'r~i1o~i~~ ;;;~n\;ei~'-mt~(~e:·~~~;;~~i\;teci' ;;i~(;~:~~b-i,;;~;'iio~' fo;:'i;r2u~~~~;~~---\--;•, ·.'
1', 1,,1 J,• ~• ~•,.-,•-~'•••'•,•,,•,,, z ', , ,-',• ,, •~ ~':_,• •J,--: I ( •',' ,,• •, ',:~• •~••",ct,•,,.:-, •,•~' \
. · / \.-;: :\:'.;,/:,::_s;;ir\pli~gto ¢iisiire'th~t1he'prepai-atit,iiffor sarilplirig and safeiy'i:irfcornpl~ii::-,·: ; \/ .· :t· _, ' ,:< •· .
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. , 'J\11 equipmerit_io be used f()r-the sa111pling eveiit _.ire gather~d and inspe~ted by·i• . , .. '. ;· ·:.'·~ .. -·.-,<·\ -~---:: ,;· -:• ·,>' .::•-: .. ,. :'.·:r._,,-,:.:-,· :_.' :,-:: .... ·'.:,"·,.,_' .. :'. .--... ,·: ._ :-:-:=~_.-_:_.._/ >: .:. : :: .: ·_,-,_ . .:.. . '•. 'J) .. : : .. ·-_:.<:~· · -. 'field jiet~oi:inel;, field,, meters; ,el~ctrod~~; p~obes,, 'efo:; tci be' used cduring •· :,,: , . -:: .< ... _:;_,_. ___ : ·:--,. .· ·-:·::x• <":· _·,,·:-·:· .. :::·-_ ,~r. t;: ·_: ~,:::.,.,_.-:·; -::,. >•/·; 7>r.::/>.-:'_; ::.::.· . ..-..--.··--.::,-/-.' : ... :-•-=.,--:<·:· . _•· __ ,,_ · ... ..=-: _, _ _.>·-·:,::;: groundwater sampling (pH •meter imdj:)ectrode,-theini1stor; ORP: m(,te_r .and,. '. ·:.' .: '.< ', ";'·;, · \ >.·'.::.~: :._ ... ~-..... _'..,.~·' ·,·,: . .::·:·:. -;'-, _.: ;, -: .. :_::\.\ ,J \::.::'{:> -':' .. [ .-:/:"_::)>_·>, _''. .: _:\,•, ,,·_-.. i<: · .. '· ,-:_._·; .. : ... :,:./ :·_: .. ·. ··: , :,, el~ctr9de,' sp~cific ccinduciiyity tester;: DO imeier;:aiid. prob~; w_ater, level
.• , :, /i;~J9~(1rs;. ~i6.f'JF}\ite,ci_tf 5)~S~;E ~~f sb~~\c~lfh,iatiif ~~~tt~~cisi:;n :';~d_ ':·•·
, _. . . respons~ ~re attainable, or the functionality 9f)he equipirienfjs verified: .. ::•. '''. :,:. -~:, ·: ;:, .. :· ·,'.·._'.·~-·:· .:.-:.-·,: '~ ·' :•:.: ·,.., ·; '' _' . :,(" ,.::,' ::.;,:\ ,; ,,; .. ·:,_I',' ·~ < ... ·..:/-·._--.,: .. -:·"'·'.· ., .. ·; ._".·:· ;;,_ ·-:;•.: ._,·, ·,,-...... . -.. 4-•::Ccipies \if all plans (SAP, QAP." Health and''Safety;Plah ,(HSP-); any fieid / .,<<<'>-; ... \ ·: '·.:;-~:· .. _:: • ...... ;_>_·:.;, : _:·.r·:: ~ ::) :.>·: :;\ :··-i/·:-/·">>.J.: .· .•, __ ; •:::.·._..-:-,: .~:'7· :,~ ·, ... .-· .,<;:--~~ ..... .-. •--·'.·;
,::_;_ :· _ , <,:proced!,li:~ SOP~. an<i: field f9rms toJ1e, u~ed 'in g'r;mnd~ater sampling are '
-\O: :i_is~~0;,~<l,-, .-._, . -~--'-•-·-;<,·"" : :.::·.-::::_ ;i{;f \\): :, .•• -',):-,>:::r-:. '-.. -\... · ..
. ·_ 5 .)fottle(are, ''pre~lab.~led" during t~e,'jir~limi~ary:phase for the,sampling event ,: -• .
.. _;;:_ ';-"":°.", .• ~;:):'_'..,_·.·\. ': :-_-.;•. ,·_,-. ;-;··:. ,.-_ .. ·>:<· .,-.:-·.::,-~·>:.;·,._.,.:. ·.:·-.;, j >·•'/ .,··./( -::-.:.:::···. ·.-\· ,·:·.: .· · ... ·.:}_, , .... : _.·, .·--· ..... ,,·'. :: .. ··,,.
,( •-: , . ;c /to re.duce confusiori_in the field,·ifpcissiQle:·Certainjnforrilatioh(e.g:";;sample :.:·.:· ·,
· I,,':', :·-i'\(-\;~;;ti~.2~ti6~·riJ~bi{t.~~}~ia'tiS;,:iR{J;~:~r;~;1ri1;t~~~/~~~Obe i\ffi~~d\b/:!-:>0 _,_,.:_.,·'.
_-? 0 ';. _ , _ ·' -: ,,; : :·,: ;thi i~b~,l ~ithJ~~~~~~_ti:i ~~~'.d~\h~, R~~2~{ifi~!i-✓i:i~( bth6r inf ~#~t'i~n . -...
, 1, ~,i(_;''·'.-· ;,,, ·, .. , ·,· .. '.' ,:-,,-· (e.g: :sample' time and ·d-atei sampler;s naine;'·e\c.)-can only be '.added"to--the ..
. -·1:. ·. -: ·.·::_~/:/-,->:· /.-:.'·-: ::_:}':··· :·,_.-,. / .;.::;-: .~.,."_::: :--·: .. :,//•_::>:-;{ \:;;·; _. ... ::?r·.~·/\~:.,:-:-.~·~.-,.,:./' ·.-·: . r ;;_'.'.-.• ,._: ~ .,. ·' • ··-;, >·· . .-· ·, ·. , __ .. -· ,. ; ,: . I '._;. ':.'·· -_ -,. <,::, ·\'.•/' .. ::C:; la_bel only afte(-the §a.i:iiple.)~ ·~oHe,c:t_ed. :,_:'.··::·· ._,;_ ;, > \,',. 'i•, 'i..<, . .:.,'\' :: ;;;~·•·
:}:·•1/::·_:,/>1i::.':-}":·•:;,:j'.•··i:-,,:fiitf'';.t,~i1_~.§;TRi\ri?::o:rdf •-i~·:ir;fb,s~d,;\~:~ti#~i~:·,r.~9~)~.~\tlfi~!~n{ifi~~d•:!,t·.r:i:-:: !l /. ;:::/)\ ;/ . ' •:,;_ ':. \ ', ~ofi".'co~tanii~ated :·b~-s~d :~ri '.thi ··1110s! redeni'. aiaillibl~-, i'.nciniforing :d~ia.', . '"'
_ '-~·-\>f ):2/:t\?,:\:{: ·-:,;·~ ~tl;~i~-tj~'.:~cif.:~~\i;d_~eii}:~r_i~cf t~: J:f ~_a~fi~'§.i,~~;fu~~~?i:i~if;~ • ,d:p~i_?tte',-~:,,; -~· :>
,"\l ·: .. ':,_.\ .. :, · <·-· · .-, ,:-, : ·' ,(MS/MSD)'s·ubmittals' ifre proposed bas'ed-on criticaLsample designations or :: , · ... --
,f : '. :(:' t·:-);;~~ \:i:(:;: :::·· :·o'. :'.· ::./.·,i· :)::i(\:t:·:;.ii _'\·. <. :::}:}: :t.;:? ··.,. ·.·. :':--:::: ':' -~: :·.::~_: ::~; ::: : . :;;: ·_.·i:,,; .
. _.:._-' ':,'.':· '. :-'.'--,·): ·.,·:~(: ):>\-,,;.Gr~~~~;_._;e~~a;;,pli~gQ~a!ify'A'is~i-~iic~-~I~"". :·/:-:;, :··.· .-', . •··:•<, ·C-.
·, : .... :•:,.'~•;,:', ·· .. /·1 ,;:<,:···,,? ":•'-~,:.,•·NoithCar6lin'a•stateUniversity~Lot86SaffipiingSite'. -'..'_\·,_', ·.-, -:· ·-·'.'. ; ·-.~-.
i:) .. )(=_':•: ;:: .( \· '·\:\-?/·>~ .. /.:~ii.::.'; ;.~_:\(:\_'):·,:(.,.;::~~~·<~,'~--Fe~;~~ 2Q?) · }/::'.:: ::~;:~::..?:._/.~--~ ;;{··,; :>,-~·:{: ·. ½, . .,·;· --~:":·.>_: '-~ :_ .. ~,~? _-_ ,
·_i •• :" ,·; :,-·;-/:-/".': },) ':',, <-~ 1 coll~ct1:d .fn;nji.'t~e.'same, .. w~l)s· for, th((sa_m'pling,,eyeri_t .'A str_ategy for .the:.\;:··•.,'_:'. . .
. ,.,;',1 1 ~ •,;~'\< -l',°''1••,:C. ••· :•,•1 •~)', ,','':.",;<', ,,•,-~,,,, ;• •,•, •~" _.;,,'"•1(••,~• .•~•,1--. ;'.,• ,,,,•~ ~ ••1•\~., .. ',> , .. _! ~••• • ••
r '.·' ) :: · _ :. ~ . ;,-!_ ,•:'. ;: ,-<)/oliectio~'ofequipriieni'lila\U{f1iil be\p\cipos_eii' b~sed:_cin tile )veil .sampling -:,:~ > ~' ·. ..
·1 ·---... : .... '.,i-''',,'".:·•,t1,::';,:i:_,:;~::::::··:·:·~·i'~;•:':·~•·J.::.~:·~•· ... _,...1 :-_.,· '(·(:, ....... :'~'.::' :,:, ... :'.·\-/ \_',.,:•}:".' ~ ..... ·,,.-,··, .'_ ••
••1 :,. :· •• :.;· • ·:·,_;.'-· ,._ .i'.., -,..-,· .. ,:-ord~r ancU:x.pected 'equipment ·usage: ;:Equipment blanks should ·be collected_' ' ··.: .'. . · ·. · ,.· .'>·'::'· ."-,,.''._.::· ::~f:~.-~,·-_··::,,·,.,.),.:·..,,.--,:-:.-.:,:t;..,_t ... ,,:,._~;·_\;•_.<.,.,_;,-. -~ .. ,-.~.,-_.!\· .. · .. _.~ ·:.·.·•/···,_·,. ·-. ~--~'-,.---.r. -.; ~··.·
, ;0• .::c': . .': ·' : •.. ; ,. __ :' ,', : ·., early'.·arid mid-way inJhe chronology of equipment use for the sampling event::. '·' .. ·
I 1 • . ~~ • • l • ' <C'\ • ,, •' -. ' ' •• 1 • • ' • ~ ' ' • • ' • • . __ ' -· :" ;':·. ,· ~ -: ._'..; · < t:~~h~ :fi~id ~~r~ci~~~i' iii1-r:;ie~~; sa~pii~;-~i~~~-;\ie~I;h\~d ~af~fy ~p~6;ocol~; .· , · •
• ' ... }--'•t• '' •• : .:. . <:·J--;:;•i·.·,_'.,.).'::0:~>,!,;-)_' _'?"/ i<<t•;.,_".'.c_i;:·.:::~>;-:: t_·.::~· .-. .:: -~ ·>r~:~\:.') ·.~·'.~;. '.--; . : .. .-.. _,.['. :->··.)--.*_!,'\ . ·,
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..... _:':/,)'and appropri~te $Qts b()fore)n~:sampling eve~L • ,, '. 0:, :.</, ' :; ·.; ~\t;:::}}ii});).;/;;t>,ii,/?-\/t:: ,: . . . \·J:( . : ?,:· .•
.. · .. f ,4't;t~¼t;t,~•;Irf ~ii{I0,if ;c, .... '' . ·;,: t;c.;,
.. .-:·~ .::-._ .. ,:-'..·\·?:/:-: .. ~:·.::·.> :· _..::.:/ >~-:i -·:•-I--.. :•_: .. :.:/~<.-:.:•. ·: __ . .· ·.· _. ·••:·~ {::,> /:::~.\_:···. -•.,_.:'::-:~.~ . ·.·, ::, .. ··. _. ... _: ,_ ... : ;--. .-:_ ... -.-:· .-··~ ... .-. , ·= .•
. fi~ld_:p~raineters will bi.measured a(each well during sarrip)ing on native grcimi.dwiiter:;:
',: . ·, j":.:· .. :/ ,,' · .. \:.; :_,,:\'_-:,:.":>.:\ '·. -_:, .. :•\ -';·"_::_ ·.·:-. ::: :, :-:_:; ._.-:_->-_'·, ·:--. ·. . . ·_. ... :·:,.' '-..,,: .. :~y. . :--... '"<· : ·t'.· ,;. , ·<·.-. '.'.· ,: . .: ,-:, .:. '·:'--~ .... ·.:_· :· ..
.. , }')le s_ampl~ pres~rvatio11.and hokling tinie_ reqtiireni~rits for:thc analy'ses .to ~e perfonn~d ; >·· .·,: '. <._ .. , •·: .· :. ' . ·--~· :,.· .,'. ;•_ ~ ." :· :'· ·. <·.}:': .. :_·/-/:_.:. '·-.-·\ :· .:~.-· _:. ' . .-. . . '.:.:.:-,.· _,_·;: ,' ·, ::-': :,;~7: .. .-\ '., ·.-: '·. ·. _ _.'. ~ ... ,~: :. : '. ',. ;./ ·,'-'=. ·• .•• : • .
• .. 'by fixed,base .analyses are :contained in· the ,S&A · Pllin. ,. The S&A Plan'..iilso. provides ...
";::·:.;. ·:.·:; :,''.,<t': .;_'.""•-> ".;. · ... ··.:; • ::::· :,;:; -~ .-.·_. .• < . _ _. ·, .·<f.--:--: :'_,;' z<!;-:._-1 _.' ·,:. . · ... , '.'< .... _ .. ., ... ;;)/.,:· :::: :.-: . ._·.-, _:_ ,_-,:·. ·:.:, ·: ... ,_... -·. ?: ·.· · · .;,,: ·
. · sample bottle and sample vohime recjmrements for each test method .. CompuChem, ltic.. . .
, .. ·· ·.· .. :·~ii/ ;d~;'e~;n;· th.~. mo_st ·,e;ti_c'i~rit :_.approach io, ~~;~~~t~r, vol~~e an~! sarri;ie. ;ar~ · .·· :;
t:, req~i;ei'i-ie~ts, . S~v~~al a~alyti~al p~rameters may -b_~ ~i~bin~d• into. ~ingl~ ~am~le ware ·, ..
• : ; •'. '' •' •: .. , • •,. •, , ,:,·-•,; \ ','.• ' • ,•, i ! 'I."\• ' , • • ""' • : ·.t·
· ; · ·· i)?tt)f,S :.ac,c:f?i~g. to: botiie typ~ .a~d :preservative: f~quiiegfonts/so; l_o~g as !he SOP. · .·
:-' . ;' '·:_; .. ·' • . ,',· ', . :-. : ·: ,: •, . :--•-.•.-. :,· '·: ·.. ~ > .-· ·. ) .. -' ; ; : :::-'. . ' ' . . ',-:. ' ,' .... ,_· -:· ';, . ' ·.. .. .. ,-..... ·:-.. :· . -·.:' ;-· :_. •::·.-: : ·: .
. ·. '· ·.. requireinen_t(s) forJhe ahaly'ses do n_of 9orifli~t, _or alter'tiJ~ 'QA/QC:re·quireriients of the :_ . _,:·. ':> .. ·-:. .. !\;i.. \ ·:":: ·; :·:: ,-:,· .,:. ·:.·: ·.-........ ,:_ ,,,:,_ '• '·. ·_: ;,·_-; . :. .-. ···< :.'. < ;·· .. :.-,·' '·.-.-(.-:.' '.; :_ .. ' ;:.,:;-:•·'-;-_ '· ·_:_;, '' ·_ .(.: '::--_;.
analyses.) GompuCheni,_ wiH_:provide sa_inple iare :.Jabels, irn:licating the. grouping·. of •..
: ' p~~~~eier~ ~nd pre;e;ativ~(s): if neces~~~-CompuChe~ will p~~vid~ ~ 0
IT1emor~nd~~ .·
.· \ . ·· · . · de~c;ibi~i th~ para~~te~ -~r~ups; ~~e1~~ativ~, a~~(6o;e~'i''ty;e, ;o;~ine ir{ci -n~:be~\f •:~!/~.:'.•_.<, -~;, _•••,.:·-~:,'·:·._:•<.,:-,:: .. _ .. _.',.,.,,_ .. .' .,,.'.•.,·•.··.:_'.,,•·,.•.-.:' .. -.:_,.·,._'•·,c,•._·~~-,,'),,_-, .. _·.:: ... _ ,· ·,<·-.,~)-:_••_·-,"i.'_· .. • :.
I . . _.. . . • : bcitt!e.sjo'r each (e:g,; 9fre.?OO: milliliter plastic,li9ule'\vitii nitricaci_d presetyati1e).:, . ,.
. ·,
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' br;~ttI:~~'.,;2 ~il"ifu,,~~', \
r -~::.. ': :. ·.• "· < .. : SufJcieh_t s~m.pI{}.o~lerf,a~:9}ce :~j!l; be jnad~::'~v~H~P]~ to\:1:11-~int!li_ll:,t~e . ~nalrti:al . ' ,_, ,,· ... ·.
' l ': • ,. • • '. sarilples .,~t '4 °:: G~I;iuf fioin '•the' 'ti~t;~t. ~olle6tibi-i', tinti(\tie'.. cod le;(~): ~hive; aithe ;[
.~ . tt .~ .. ·... . -:/ ·.~· ,-.:"::;;/· .. \t~:-<·::-:.\·: ;' /..::r.:·.:_;:·:\\\::_-.->::_. ;:':·:,'(•"; /'·.::\·~ . .":i. :,:·-.·. :_.·;-:~; .": ·/>>.:.'. :;.:"::(};)•·.).-·_,:· '~'.,_ ~":_:-)·/}_· ·/\-'.-: \\. :,_, ... _. .:].::::~·
, ,_ .. · . . . , :'. !aboratory'. ,:The requireinerit':for)ce .as a· compohent of sainple'pre~eryation•:is ·strict> ...
:.!s I)f ,'\;/j:t.:B ;f 1_;f 1fi\~i±r1i1:JW111:~i::i1\!ii'I;t {~ii~i h•~(t;;;~;;~~!0ir.~2f;f 6I1i~f 0t Jih{if ;~~i\ir.. . : :; ::: -_.
·, . 1 f:'/ •:, , ; . :, i i_sho~kl. be .contained. sqias to•miniiniz~:free water;wetti11g· thf contents, of the cci()_ler.!:The_ .' / ):; c ,, .·· ·
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. : ·:::;\~~/,:::?:):.~?:::::\:;::_:.:/:\; if.:; :::./-:tr{·:;~'_;-: i_:-:-,F\r-)>/);,.:r-· ' .. /t:::~~x}'.:-'.'.;'..\.>t :;r; :·.;· ._._:--~ ):,:,:. ·-_'. .. C .... ·;~·-:,,,: .-,:-:,._;' ... :, ·; .:•:: '.. >Gr'oundw~tcrSampllng QiuilityAsshr .. n~e-Pl•--;> '<· :.-,:· -. -; .. , ·: ,: •'/.' .. :·.·. -: : '
~ ,,., . ,,., ,·.•. '-'-.., ' ., ., , ..... , ..... · . -. •" . -,.,. ,. ,, ,,. -. ,._, ·,··:,:!• .. ·. ,-.~,,,•,., -·. ,: ·. ··.-.. , ,,,_"'.; "NorthCarOlinaStateUmvers1ty-Lot86SamphngS1te :,,...! •• -~,:•.·· ••·,· .-... t,,,· 1 '•:' • .• •
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! ·-·;;,:'.· · .. >:'::!-'4'.'4 ::,sample"StorageandTranspoi-t;;-,'::; ·::·:· ·-:·: '•,·.:_:;;:_:':;\:' .'::\:,': · .. ·-:. ·i,.·.
·~ "';-(~:i:'. t/f:-.::://;(:i:~·:::~:-,::.:;.::':'~(( ;'";~"~ :i:-{\:;)f': i/(t,\;}:'::\: .-:-:_<::\:<-·~;\'::·-\/;_: .. ::,.):,-:'.-::::-~::: __ ii_:~.'.:}:·;._ .
. ( , \ ··/:' '. --~ :: . -~/11>,a~~l.es ro_r; c~emi};_af_a~~l~~!t ~i_ll. ?_~ ·-~i?ifl, tj~~t~o-~ed'.. 0~ ~P!Pf~?.: !ri.'_(h~jal}~ i-::, .'·, ·,:---
. ;: -': · , ·_-,_. _ __;:_, ... ::,insulated coolers ·with' ice' iind-:cushioning'.inaierial to preverit breakage·. 'The. coolers \viii ._--··_-:-'
r,:i..•\•;.~:\'::,.'.;.~,, ,·,,t : __ ,:;_ ·_-,::·:. •. · •":·-~: ,·: .. :::--:'.~--'--· ··,.:·.,,:·,. · •.: · :_:· ... ::;:,,,: :; ,•_ -···'_:·~~---" ·/~":;,;',· ·,.-,.· \ _ :· • :i ·\,,~:2-: ·-.;\re· P.~-~hd:\ith_ ice_ tn se,al~.d plastif ~ags: :T~e ~9C,wi(l .. ?~-~(i~Je,<l_ in _a·:zip l<?.ck Blas.ti_~ ·< .
. · ·:·· ' /\ '"<tbkg arid taped ,to:'the'lid 'of.thd'. ~ool~r'·if p~ssibie: Tlie s~mpler .w1il retain i c:opy of the ' .
fi/.}?\\/~;l;}'t?,?;:}~~t~~?~~i1f~l}(t(f~~~,i'i~{~~i~~:;~~d\r4ii{l:i:fi1~i 2a,{1it .~~oie,rsji(l~r
_::,. :-, 0;, <;:;i: dearly, )abeled for _•transport_ :or,' );hipment--with preprinted mailing· labelsC-containirig ·.
·.J .. · .. :·. -~~p-iop~at~_-\e1~~hone ::,_:~~~bbri :cir: ap;;i~~~l~ ): :· ,~-~ainp;~ <co~le;s '. -'trins·p~~e/\o·
·: '. . /-'> ;_;;:;.: ,. ;t~¼Ji~Che~::b; --~Ju;ie/~ili 'be:.i~p~dc16s'~c1 :iiih: th~ co2' ro: ~hit ::c601~ti11~id{~~d r-<C'••·•··· ._ .. ,'·:: .... :'·•.'.·,.· .. -;·~;-,.:; ... ; -:,-.·_:,:;-_.·_:,. :::,· -_.~_··:.--..··._;_· i=_-~-:-·~, --~ ··=. _·-·.•-_, .· -~---·,'":->;-; ,.··_· . 'J:: custody seals ~tiached. Sampl_e corta_iners are. transported or shipped to tlie laboratory as ; · .
S ~ .;., 0' ~-:'•,:.:• ;• ' •• • • • ~• \,:• :;:_• < •;i-•: ,';. "/."'-I,. ••,..;_. • --~.::,:: -"_ •. ,' -'•:~"-•\. • .: _•, _' •.-:---:•:,_. •.•.•-: ''-, _,.. •-. • :::_,•,••••, ':!.", _; __ :, • ,:" • ." •,, ._-_., .'-.. •, • '• :
_ .... ·.:}.:soon-as· practical after·sainp!e .. collectipn; and iri,corripliance·•with ~PA recoinmended··-..
·:, • : .. _v. ·: _ :_.1;_ ·y:.:·:~',._·.: - . . . -,·. .• ·· -' .. .. 'i.
,· ··•> .;c-:•,holdirig tinieif-· · .... /',. , '.,.' .;.: .. -
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·'.• s~-~~i/c~;;J~y-will b/maintained :tail iimes in ac~-orl~~ce ~ith ~he ~;~~i~i~ns·ofth~--.
__ ;::;:iiA,PICln{o{~~~--f~-~--·•·.-.~.-.. u.}tod{,t:. . . ·,· :..'··· . ' . . .. •·. ; -,;;,
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. · ·, ,: '." • :' >t ,-iempenifure meter fo a2cordarice .with m~riiit'acfui'etrecorrimended i>i'oceduFes.\pH: win· ·-~ -__ -·.-·,. .• •;,::·'_·,1,_, .. ~--_:,.-.>·.,,,..;':,~:-'-·.•.:: .. ·_: ... · __ · .-,, ... _,.,,.· .. ,._· __ 1.·_,--_, ._--,---.'_. :·, ·_ •. -.. _. .·:,·.:· .. _•·_·-·-'~· ___ "t._.-.· __ .·~-i·, ..
·I ;':?)}:,'.>'.'.'.. he measu'rfd Jitii'J~tcici;tic iirii~~tafure' corriperiiatioii (ATc)'tb thenea~esi o: i'Stand~rd •·•>
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., . . -, .. .''.. / • E~ch ; day :of0,use;,. the•:•temp~r~tµre c>(;a : pH '.calibraiiciir/ buffer/ sql11iion will : be .• ,,:,:
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'.•: ' ; :;. '' _. .. _. siin'ultaneciusly'· me<!Sllr~d with the. therinistor/ineter, ··and with a mercury-filled ·pq'cket ..
. , .• >i.' ;, ;, ! ., .:. th~0rri16in~;Jr· ~c·c~iaitti+1~ I de~ree'c::elsi~s. p~ J[liibration decision ~1~ffi~~iude: .. : ; ' ..
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• . _After the slope adjtistm.ent is mad~ to 'the seccirid, calibration buffer ( 4.00 to I 0.00 ,
: ~{}) ili_d1:\~it;~, i:iilib;~tibri br th6 ;s~st~~°ih~ iil-i7:ob\11ibr~ti~d"1niffe; {the first,;-·. '.,
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;of7.Q0 (i:e.; 9,9'to 7:ISU) the_nthe'calibrat(on is 'acc~ptal:Jk .'·., ·:\ ... :·. ',/ < J::-.. __ ·,-::/::> ·:~.':·· :, :·/::·~\ <· : .. :· ·-~:·.-' . :· ",: .:·.: :.:\_·.-::· :;<: •., .'.' ..... ,.: < -.':.-/: • :,:, ,c .. •" .C:.ahbratiori :_ i~ _\checked ~ve_ry .Iv(~_: hours ·. or _'every . five. ~cimtonng locations .
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._;;. : \ •. s6lu\ions''.u~el )fthe:readings a~;~~t;ide+/-b.2 SU. ir(eith'er;b~ffer; the~'t!ie/:
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· Groundwater specific.conducfrvity'will be 'measured with'.a direct rnadmg conduchv1ty ,::'<,. ,
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•. (;· .. > Groundwater DO .will ~t~'eisurdci ~ith: a c!lr_ect ria~i;~, DQi~~i~r-a~a:t~J;a~i/oo ·.·.
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', 'c/ \ ,, · /_: :·,. ,po. c.on~entra.ti.ori bl!sed oh the relationship <\mong oxygen sol41)i!i.ty,:teipperatiir~,' anci , i: ·: '
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·. (: . ._.:;,: •. ; :tempernture~ of the:membrime and the sample~ 'and' is\:alibratedJo v,iaief~sahirat~d air::·; ;
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, '·' ·.·..:_ ... ,, -.;-.. . DO measurements will be· recorded t the nearest 0.0 I mg/L:, · · · ·. · ':'~-,""
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, , i ·, -\:.' .. :-·. sulfite solution .will be used.-.DO calibration check decision rules include: : -. <.--,--• . ·
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. ' ;-: ' ' • : :"After calibration, is :completed; .the ,airc_~a:iurated Water a)'id sodium _sulfite Sllhition.
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: > ,The: SA,P .. for field 'activiti_es;'.re~ordke,epjqg,a's documentation fqr evidenci;, calibratio_n '•-'·. _,-:;:;· .. :·: .. _ .: .. , . ·-~._-:: .. : .:: :· ·' '':-_,;·';~.,. . .. ·. ·.:_ :· > '.. \ r··:· ··::· :'· . -~: .--._.";, ·-·:_:,';:_·:-:> : _.~-:-;: . .-;•/:.~;.,: -._ .. · ;_ :-,:. .1.. ._._ .. : .. ----\ :,-. ..: :.:.-,_· '.-'' -_ ~;".°
'and ,COI]tinuiii.g verificatiOI)-, o'r :c·a_libratioi-1, for/field .equiprrieni,' chllecti.cin.•of-appropdate-.-.. · -:~ .-._ · .,...· . .,:., .-.. "'>: .-. : · ·-:-. ·-·.:·:'://:' =· •,"; .-./: >-:-, ·--~-;-.::·.--~ .. :·>-.'..:; ·_.-:,:. ~, :-. ,_ .-:·>r>:. ·.: _,)i\'.·~·-.. --:., >t J...:~::: ,':, .:--: .. ,>, ·\, -'.'. ,\:•·-... .-. .-,: ·.
-.field ·Qc sa111p)es. including trip'blank!( fo'r .VO(::s; e_qtiipment riiisate ;blanks, blind· field ,; >'::~z::;~~i:tt{~~ti:;,t&"t~' ;e,; ,;c,,,;;JiiiQ,;1,,, .,~kii'i,;A~,.., •. ·· ....... ·.·•.
cates "> · :·Field Duplicates io be.analyzed by same methods as each '.
'' 34 s:i'rriples total_;,;,. _-: ':' fii<ed-base'method fo;: ai'I Wells, field ci~plicates ~hould .,
· ,: . : 2 au licates ' . · :. ori .inat{frorti historic,i'II cil11talrii~aied io2ation ·s .
. ·',I for each cooler· /Trip Blanks'to lie'analyzed for aiorriatic,and-chlcirinafod :-:
shi. 'ed or 4 tot~i ·:' < .. :-;:· \:. : h 'dr~carb6'ns b EPA-6230D .• '':. . :•,'.
·. I for each 2o·samples; : •,· Field Duplicates to be analyzed,by ·s'ame methods as each.
·.c: 34 samples total~ ) / \ > ,,i.>t_fi.~~~?'b,ase iliethod for ail '."_ei_1~· !.;, .
': 2 rinse iiianks' . .
/1_ for•each 2,0 samples;":'. · · MS/MSD Samples to be analyzed by same methods as .,•
.
•· .. .-s··. _P' ,e/Matri"t,::.,: :34 samples fotal.=.·' •. :'-;. ·' ' 'each fixed-basern'eihoct'fo'r ali ;,_,ells: : ·,.
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• .... :;:-. .',. · ac.tivities· to· be'°perfomied i'n.-grounchvater.-sampl1ng and an'alysis.,: The· S&A'·Plan is ·an'·-· .
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1_, ,.' ·_6.1.2· R,ecor~ke~ping .•.: :·:_· '.··. '·;;:_'._·_.'.,: __ ·.·,•·.·.>,-"J
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. ·Bound field ri"otebociks .with numbered ·pages, field observation:reports, calibration logs,·
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· .. : ·.:" ;sampling records/,non0confon3uince,~ieppi)r'.a11d correstiv~ ~ctici11 -reports. a~·applicable .·'
·, will b{ used_ t~\ir;vide comp1eie ~nd ~-leaf a·;t~~-~~;atib~: cif · the piiqiose, scope,: , .. :-.: ·:·>·.:· ':',. ,_;-...... -:.,· ·. :·.:·, : :::,':"·,-•':··, _-... ., ... , . -:'•. ·j·• ,-:.,····· •. '<::·:·~-·•··
. conditions, procedures,' confcirmance ,arid rion,corifciimahce results cif,acticiris, acti_vities,':, ·.·; ,' ;. ·;:,: .::·· ;: _-:_-<.:--':. _ ... ;. :_ .. .-· _..-.~ . .-........ , . ;· :·. :. _: .. -'·· :::'-. : __ ··. ·. :-.· . _.-. ::~· ·.':. :· .' :.: .. -. ·:.r.· :. _ _. . -· .. :· . _; :·: _.-.:_. '_.'.. :·: ____ .. _._. :""-·;,_ · < . ·-: :·:·>: . . •.•. . -~
persons, -observations .arid time lirie oftlie sampling ;event in a :man11er approp_riate for .: -_-"'<" ·: . ~-: ,, ,'' .... '.· .-> <-; _:, -:'_:.'\.:/' ·-:-_ ·<. -.·< '· ~:-:·:_-·. -~ .<· .... ·.·~-·t . :\: . ' .. ·:,,: .-:: :-: "·::, < '.-: '.•' ; .. ··...-:. :· .-· .-. :--·· _.·: -_< . : -·< : .. : _;_ ,._
' evidence. :All pages utilized within the fielclhook(s) will be'inimbered ·and eritrieswill be
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· .. · ii(ink, signed and dated, Correction 'to entries will be made by drawing ·a. single line ..
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• ·:" • • •• 0 : common cold ·sample storage · .. ··· · · --·.-, . .-,,:. · · · · ,. · • .. ·. • .-.. · · .. ,. · · '" · ·l' ,. , · · ·; • · ,.. : · · , \ ~:.·T·'/::\·::'.;{.'.\l.. \(1 · .. :\\''~_:\ <>).;.-\> .;,.· £-?</: < '\: ;_:\>,\:!::_ ~:\ t~<·::<1~::_,~_:_fi,:_:.·)?;: ~)/:.: }--:.:-' ·::•''
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" ,: : , .• : ; .Equip'ment : ririsa_t( ;blanks ;'w.ill: ,be, ,coJk,cte,d' froiii. sampling' ,e_quipmynt 't~at. IS
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. ·,;, ;, ·, .. ' ' '•.: decontalllinate.d ·and reust:d:iri .the field at ~ frequency.·qfont: per 20 samples<f S'l:'o)_.: ::rhe·. · • • .:.:
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, ,"; ,:w.afer runni11g yff.th~/:cj~ipTent will_ ~ec~?ll.ecttd· irito saMpl.e; C:<ll)t~iner( Ri_nse bfan\(s : .·•
: · '.\\'.ili.1:ie filt~red \,h~i\". ~f;J;iningdiss6lved"in€t;J fra~tiiris i~-,~c'cordanci: with met~cidVi
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The .. electronic water level :indicators useg iri sampling shciuld riot• then b'e wetted rnuch.
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, smgk ,.use eqmj:>ment·-.is ::expected ·torcoritact :the .. sampJe·,watet.,:downwell ··except the. • ";••·.·:V :."• •-,:,; ,"• ,,':;:: .-•··:• .•,i·•, ,,;·,·:••-~••••, ''_:•"•~• ··' '.' ,,,, ,•• -~·•·•:·~,·•:•"_:·• ::•-:• ,·.·•'' ,~:
·. · subm~rsibl_e pu)11p and its ,electrical leads: Appropriate·ecjuipm~nt rins~te,blariks will bi,· . --,-,.,., .. , ,,, .. , .... ,,. ', -. -~-.· ',, ,, '.·• '' -·· --·~ .:;,·:
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··\ :{,\:-;;, __ /,':\; caJculated, iritc{firial ;~cinceritfa.tiori uriits,: results· are_:r~vie.wed .for .accurncy,;arid ;t_he i/ ic <.: ·.: ·. ~ ,:::-, ~.:{-'-.;, •• :. :.::-: -;: "~ _i ...,·:_· :·: '\·''-'.. :~-:/, :.:-:._· : ... ->:-,./-,-:·· .. ;:"~:·.;: ·.· ..... ,: :_:·_·:. '.-:: . ·~:; '.:• :::i ... -:-:-;' '·,:-''../· >_\:..,.:,·; ... --.'. ~ .'. ,.' ... _;:>)' -:: .. :•, .... <:./:,:·-~ ,_,.., .. _ '/ ... ! • : /·?--'· _;',•. ·. ~--.: .. ·:-.:-. \·: -... -~-.... ·, '< ·'. " -~ ··'">". __ .. _:
·'j ::.-///< ': 'i\ \iechiiitakrep9it' deliyefables are '.~sierribled. ':':!'his'. process· is a c;!ocurherifed ,multi'tier '.; ..
·~.1:. /,_;::·:, .. :>,. /'/V: · >~·;:--!:.-'~··:·t: ... ·/-.<'::'L".···.~-··· .. \:· :·;\::\:';:.-a:•:·.:_·_:~•::-_'.·~:~--'..·:·'•: .. :· . ..::···;:::/·~;., : .. :::',t· ;)~_-:/:>_ .. ,:~ :· ~ ... -_.-'. .. , ~-/.-. ~~-,, ... -·/.:/ . " .-•.·_ --~-·:_ .... : ._ , .<· . \ ·. '.;:. ·. {;..;;'review. process describ('.d in "detail iri St.:i:riclard, Operating Proceciures; preserite~ .\it S\:cti_on { ,
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1'.~ /.: ::.•:,:/-:·.!, :_;:/\:·;c_;; :·\;'::·:_ )\ /t:Y{:/::/:· .,~::t-_/i/:-\::,·\-?i \-. -:·.(t\ .i:\.:_::!, :·:,,.:: _.:-, :'. \.i :-_·-·
J .. ·;')}·_::' ··.\ Dit~t~\~a.~ion·.is ~?5~i~niet;?~/a~~ re~o~:~o.~fa,~~)y\l\~t;·~.erfojeo ·:~general.··· •
·. . · :,; ':' <!: >< accordance with Stahoard Operating Prci~edmes, presented in Sec\ion: B of the S&A Plan. •·. i .. · .. ,
. :1·· ··•:) if /::::;):\n:~:iib,a.i'.~n~i}~f:;J;f d~;i)~~; {i}ija~iof ::li{'j;fi:i;1y g:s.~:.6itef;~~\5i}~B'a'~~f ~':b.~1; ); I\-.. ·
•1 .. • · . "_met. .An independep.t technicaJ feyiew of the data'th~n is performed .. If.discrepancies·are
. : ·-.. . . . . ··:··r_•··· ,._,. .. ·-.. _. ·_;-,, ." .. _,<::;, ._',:: .. '.-;·:;:-. .-.--._,_:\ -:-_ .... :·-.-_·-: ~;> --. __ ,._ .... : ,-:··::_.:,.:_ ·: ~-:,--.-;~ ... :.~.---·,t;•:\_: -~-,.,,_:-\: ··/. _.>.·: :·:--:: ... :-:: .:-:. .. :).';•·· .> _ ... ·.--.. _.. :. -:. --=-~-: __ ·-
·1·. . .·c:·.':,: :/ . ,. •.obs.erved, the reviewer will :return the••data pi;ickage to·,'the. analyst 'for :darification or.· .-·,-~ ·_-, '.~, '_·.'··: :, , . -'.· ··>; .f.-.. \ •·:-·-~/,; ·:.,;:,?. ·•c<·· :-.,,-.,_'·-->./· _:·:· _.: ·\' ::-, · .' .'.1-:-:·;;,,.~: ··'::· .'•.:•,·__.: :.-_·,, ,. ··,·~-~-•··-:\ ,; :·. ,. ;:; · · ·· •~ · : ' . · •: .. ::,: t •• ; ~•: ",' , ', -,,.' • ··,', ,
I
/i\' .:':"correctioris:'{,'bnce a!! 'jssues have ;be,e°n res'c:\lv~d, the approved data pa_ckage will be '
•.• .· '; .. :--' '/. ; ·.-..: ..... .-.-: .":; : ·: ',. =., ~~:,_ : ·,· _·. . \··. {' ?~: ... ::_: ........ ' ..... ·. / -:. :_:·, { ·' ,./ _,.)-·•,/ . ..-_·;. ·.·. :-i:·. :::·· ' ::_"','_·:,, -. ,_·_._.,, -, .... , '·. . : .: .. :~·-"." /
:' provided to the Reportirig Departmen(for):orripilatiim iof. the fin~! rep()rt 'deliyerables -. ;' .
. ' ~:·-~.--.,.-~;,. -; ~ ,. ~-... " 'r ' . ·, ."···'·:~ ,::. :_' ~-'. ~ ~· ~ :··., ~--.'~ ;·'' ....• · -·,.'
·package. ·.A.final •n;view of the_:packiige .is performed by.the ,Op~raJions .~r Project or ,
. Laborat;ry Manag~r' or hisfu~r desighee. \:S~i/1h{~~nrig~r or ~i~/hbr cteiigii~~ ~~~th~ ··••·
. ·." • r·',.:, . / ,' •-,-', ~ .· • .. : .· .. __ ;~_ ·,· • . .'. · .. , ,• '~ '. . ' . ._ .'.• •~ .. ,.-~•-·._ -,'_ -. ·._/, i_-: ') ~-:';, <_-." ___ :,._'.·· , ·:. '-:' ,._:1"::.-"'.. ·; " ., ~-. : •· ·_-,_, \~>.-; _ _,_ :. : .· ·; ·::. :·· _;' .':i-..
... . authority,(() releas.e the.data ·packagei :The Manager isrespO(lSiblefor iissurmg·tre· overal.l ·~:_.~-:-._, .. _ . .-._.>·.;'•,:-:>.-:_.·':_'·, .• . •''• .. " ·.i:/•'" .. ,·. ·:·• :,··· ... •).:•,-
. ,quality of the data. .. .
-~-•• .,,· > - • , •• ·-. ,.
i,1.{:::{Dit~ Re.porting: > c-· -· ·
. ·,:-\_:\·~>
·L~b6i~\~ry:d~ta ~ill be ~eported in ·~ico~danc~-with ~t;rida;d o~~r;tjng';i6i~d~r6s: ... . ; .... ·.'. ' . ~.. . ' -,.,· ' , ·' : ·, ' . . ' . '• •. · .• ·,•.'_'',·:·.· ..•. ·. . ' ' . . . ' . . ' ' ~-. . . .·: ' .: .. , ~.. ' . .. ' .
• • ' C • • ' • , ' • •, • • •,a ', • ; .-•; • •' , :< • • • • s
· · presented in Section B of the S&A flan Jor •ful.l de)ivernbles including all raw and• _.::
v~OG~S~ed :d~ia'~bpti2~bie ~/th~~~!il;s~•~,perfo~ed. ,:-'_'/~. <.;: : .••
..t'•" >. :::'t-'..~·-"">;,:.:-·: . .. -;-::. ·i : ">"· .. ·• ..
' ·. . __ · _1_,,.-. : ---::· ... : ·:'<:· :-:'. ·. --,:,· ' ·•-:-:· -~-. ,_.,, ·-·. .. . ~ ~ ... _::-. ·-•;--,?;: -~-·-:..:·:\ _;·:. <"· ;<:· ._,._}. ·'·. -~--:~: ',:
..... ,Repoiting requirements for defiriitjve data inay iricltide as.appropriate:: .• .• ,-. ·, . -"::..:. ;:'; ,: ·. . .:.; .. •. ')/.:~ . . .-. ,., ' :'.:' <--t.-: -.:,,_,!·,::: . ~~>:."·) ··'\:,. ·.. ':.·-;,, J·: -•i ._:
',:--·:•,'\ .. ' i ;' .... ::,,: ·.·,' .•:, ,.;, .. :./· ... · .. :;,.· ,,:-·:':/ ..... ·.···· ... '•·· ..... ·\·;:;;,;,:,::<;::.\.) .... : .. , .. ·.·?··
·· .. ··: Narrative. ~nd sample identification ·cross-reference.·.· COG documen\atio'n• · Suiii.(nary of '.·: , .·. ··· ··; ; ·~/:.<·<·:-<\' : ;/t, _,. >-\· ' _ _;,:.-~-:_:-~/.-:-'.::-.:,~·-·::· :._:. ,_· :-._·.:-:,:.,_. ... ·:"_:,:.'./:· ._.·_ .: ,·_::_;.·<::·. -:-.-~::>:--:·:,::·t::.:;._,::.:._;;--;t -~·; :_:-~:.<--·>> .\: .. ·:: ·. ·. -.-.<<_.::-~_.·.)·,'.,-., -.. _· '
i . / '.:.< :::,: .;analxsis• datf sh.eels for: ,samp\es ~nd QC samples.: 'Ins1iuirierits. tune. ,)nitiill: and/.;;_; ' ' . C .
. ).,.,_ :••.:."-~: .,:.:,·:· ·'': <."·: . ,:<:·:, .::"'=>// ' .. _;:,:.,•; ,_·:,:,:-_-,:.t_:'.' -''. --t· ,...:.~·::,." '.'·: ~:.-..-·:·: ,~·::\':·"···:·;: _:·<·_'•:. :··•,,; .'_·//.':,,.._';.,'.'.\,·.,-.:•;·\ \._,:_:~-\: ·: /J: :-:·+-:--yt;,. ::.: :,:;-._'i)_·:;·:~}\;,,· .: '.-~;-:.--;. ,·.::::\, ,. ·~ ·:' .--.: .
. . · .. ·•·· . . .,, : ·: .. ·. , c9ntiriuirig~ca\ibratiohs::,:Method:bfank·'.clata. :,sys!e'.m monitoring. corripodrid/surriigate' \ ::, i· ..
:-1 · _:·;.\/·_:::('/ ~'.}{:.~\:~~~:\i :;:_:;;;•.}:::·;,:;:tit};;·;;~/~\_:/::.\:·~ '}:~~l~i;;'. i;j·:•: :•.:: .. :.,:--.:~·.:·:1;:-·_,,;;, __ .\f., .... , ,t-.\_,, ,
,•·;,_::,,:<·--:· ·~:· ,:'.'· • __ ,; ·•~t.:~,-' · . ,_ ,Groundw~_terSamplingQu_alityAssurancePI_ •. :. ~-~-• _::::,\;·. ,, .. -; .. ,
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·1 ::-.--. • ,,,<· . .,-,. ~-.7 4' .,. Evide'ncci'Audit·for Dafa Rep·o·rt(sj'.-:, ::·'.•:-> ·· :: ·•.7:· •i :··. ,_.-.' :\ ·: ·:.-"-~-· '·· ,.
j ·/ i It: :1ii{XJ::J:~ ;;; ii;~;ii:I~~. ~ii~i,;,::1~:;1:;;.;;:11;,: ;;: k · · ·. · ..
:1., ·. ·:;·---~·<the CorilpuChem ·and TH&HOiepcirts'cifahalyse's. :.'Full:raw·data;supportis requireo-in :·: 'J( _·, ·.:\ !::·_:·:-.::, 1:::· .. :>::><.·f/:~ \?~) :;·:i:,>':\:.;f·''..'._::-:::".:"\~/-.,;/_/Ci·;>.;::-;::,...;,)::?· ·:::·~.:i::-:·.~ .. t:\ ·•:{\: :" ·,::.\-._..---_i: /:·'. ~·,;.:: ... ·.:< :.--/:i:{, .. ·:~.-_( .; . ~'.::·/''.\-.' : ·•·•\aRO,r~,t?11' rtf~P!~~i}rre:r~~~:i:.?f1i~7;-~t\~5,;P~fXi,11?:;ji,\!,,?~ ~.~t~~df~f 5,omr,/e,'.:,~f}~_:& i .,.· '. :; ; in:·,doctimerited support .for· the:.analyses.' iA method-specific chec!disf of .data ·support { _. /,'.'. Y· : : .. , · ~i~l~~;i}ii(t~~;~d);t'.th{i~ti~iiffi·j~~~¥eiii1.~i'iirii;.iii~ri~is·:;ud} .... ----. .. . . .. ,
,· , b°:>i,: . ,; --:_ . _;_· -'.?}'.: :::··· ;/}c}:.'.;1<.·f ._,, ._ ·:::-,, '" . ,_ . : , , ,
.No;data-usevalidat_ioifeffoit is desigiiated at'th,is time,· .. The completeness evidence augit··
;. .'•~· 1•.--........ _,-·. ,_. ·_ •. ·'<: .' <:::.::;<: .. _.-<:.;:::·.:'.._,_·,_, ..... ~i.:•l.--:•::;.;_.:,··:-;,_,._,:·::·-. : .. :~ _.• .. -::.0 •.. ~?",'.": .. , ·.:' of'ih·e reports of analyses will assui-e. tliat the date will be -.validatable. Data validation/if ., "'
. p6if~~ed/ \\'.ill 'be 'di)~e:••iri_ a~c~rdance -~itli g~i~ei;nes ~:1·1a;lis~eti' ;fri iJf,\1.td~ir~~/···'
·••·· :•._: L;b_or~;~J 'rr~~riirri (CLPf:Naii;rijl· F~ri~tid~;i -~·uid~1fa6~ for. ()rg:nic Data R~v}ew
•·; ; (F~b;a;; .19,94{ an.~'iffA }:lt•1'1ati~n~l:;~i1~ti◊riai,$uidelihes 'for ~~oig~;i~\t>~tk:
.,'_.:•·_·,·,,_'·,. __ ·--·•-.":.·;)\'<·_-.. • .. r.•;,,::_-,::, ._>,.·, -~··1··•_···. ·•--;·,,-'\~: .. \·'.;,,.'--.~.·-• ··•~-,,,. .. . .. ,_, Re_vi~w (Febniaiy;,199_4), as'applicable. .. ' '' : ~>; ,. ·.--:: _.. ·:: . ·--.. · ,.' .-. ·' .. ·_. ·.-' .. -· ... -.. , ·--, .. _-.
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:-,-.?-::._:;_:.:J\;:~;:\:/2\ ?t\::·_//:.:\)::i:i:>,::~:1\-:;·'<::\:.<).; r:·,\ · -; .-; :,:::•>·, \:'..i!? ----~-i\:.j_ , .
l ... • ···•">'.'• '·-:,.,,·," • ,.'. · -· ,,GroundwaterSamphngQuahtyAssurancePI"· ,a•,-, ,' •· · -. · 1 :· • ·, ' ., , • le ' .,. 'j ' .J ' '• • '•, • • ' ' • • ' ,, + ' • ' ' ·-, • ,,;: • ' •,, •
I : : ~ • • -: " ·,~ ~. ' •• ~ ; , :-: • -' • -...-• ; ,: •• ,. .. ., • 1.~·~North Carolina State University-Lot 86 Sampling Site '. ·· ~ ~ ~· .:· , .I,•· ·_ /,• , '; ·• · _:; , , · ·
., •.:,; . ':<·.<;~,' ::. :_':(.'
.• -,._:/\.::• _ •• ,. ..... :j§ iiiif in.~qiiforyriaiice \Yith·_q\ialitym:an;igemeiiJ systems, or that jirjivents'persqn11el {rciaj _.;,
-)·.:-:::;::J:);;'./f \:·p~:r~~I~t ii~'.~:f p f~'-:i~{;t~:t~~ki;;·;; _st~n~:~~'f (~fr f/tt!i~ f }('}}•\;c;;·. , ... -. . ...
(.?' ,:•.·: < ;_·/ ~ ~js·~·~/;ai. ~;_e~~ 'in:~~::~o;~c'ii~e'~c~;?~:~~~t~~--;e::: :_::_: __ ·" ~:.::-.:·>···.
.f<:;.\\\);''.'i'.' . }\'{;,i):}. J;::-"/:,::::_-'./\-·::'. . '.: . . /i}.:,, ,:;:f :2;,>;· ,! ;-:.-\:· .. ··.· _., ... ·· i\:.
: . ',.. ' I<ientificati~ri. and definition cif the problem, assigiun~n.iofresponsibilityJoiiri.ves\igatiiig '.
".:,• _:' ';/:,/:·.·..=,.-,,': ',; ... ··.:J. -,, ·_ ,-:. ''i.:' '-.:° ,_';_~:.-:·.-:·: ... ::_: .. ·, ·. · .. '. .·· ,:_',' ··,,-:.-.:,"·:. •,::., ,. -·:·:_•.'-<:~::.::· ,:--:.: ·.,::·' _:-,' .:·· ~ .... > ·J:·,·.\ __ :;-, ! i· -; ...
·' .· : , . the problen;i;,:invesiigation and detemii11ati,ci11 of th_e cause ciftlie problem,, deierrnination· ; _ _-.'.'., ,,._ } .. , -: .. ; >:· /:•:-.,::-___ ,-., ~ <,: ·-:: ·-... ,.-:· ;\·. ,y·_ ··. _·_ ·:-. ·.: ... : :" .<.:·:< -✓-: •• ,·.I:_:_.,.:, : -~'. ·:._ : .. · -:--\ _. .• _ ~-,_'_; .. :. ·. __ ,_. :·t--· :.'. ::..):-·:_:;. _' -~-;/: ~-,;-,, : . _-_. ·_ ~ : _·: i ·· .iofa ·c.orrec~iv·e acti9n:to elimimite the"problem,'.assigning aµ<i acceptjng responsibilify for. _
i. >,:_ '· ... i · ;,\tJ~+i~0e?ti,ng;th~~id.;~;'.~;•<ic:;i,on,)niple;e;tin~'th{c~~i~iiv{~ctifh_~;?:•ev~·1ti~ink~ itS',· .
. ; . ,//,: ·· •· · eff~'ctiv,:iiess and, yerifyiµg that the corrective ad[on hasdiminate_d the protiJ~m. ·
f; •l~ .. •·,·.::,,·~· ;:•:,.1,'.''.•< .. •.: ... ·· .. · ·,<:•··_/,-. •, ... : .. ·,·.,,. ,._:.',' '·· :··:"-,:_ ... · .. ,,, •,,'', '..-;_·.· .. ··.:-.· ,:.:,:·,• .,_ ·,:,.-._-·;._
x:;,;.;:,. 'T;:;,:~,;~ ¥-~~'fn; ''.;"~ ~t '''""· ,;,ps "',f f d '.h:/,:, ,~;,,~ whkh .
. [: ,: \;/ l~?}~{te corr¥ctive action has been r~tJlve<l,;,:~r~~:~iioi be/es°cl~~d.:' . _ •. .
,:·>-;_ ·._•,:·_ ~:_··.··:.,·::._._ .. :_····· ··:->·.··.·:.' <,.::,. ·.· ... :·_: . .:~·-./,:·._ . ~ .·:· ···.::·_··._: ,-;:: __ ··.<:_/,_-:· .. :·_··._ .-:·_· i '':' • _ ..•. , The:QATi!Sk ~fanage~ 111ay IS§µe a Stop Wcirkbid_e{if a~propri'aie ~()rrective~a~ti<l~s' are'
: : · ;t'.r ~:i:~it~W1J~[l~7:1:i,?t1~ lit :~~1,:::~!:;1\1t:t:;;; · ·
'! · ·' outstandinfnoric()µfomianc_e. ;-.. ,. · .,_ · · '· >•-· ' .·· ''
·/\-:-_:_:,\,',;;:;-·-.. <(\'_:":<:·_:;;\, \<: ::"' ·-, ~
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; .. :•~ _.,--,.;. ~-.·,,·,··-·,···•:, __ .;•\-_·-~.:·. -., ... ·c.>·, ---~ ,-,·( 1 ;/.,',',' .(::~:c;, • ., •, ·• '-,. •,-.. •" • .'•,~. ,·.·-
1'!tf}tl'.;?t!!i:1;:;!i'.:;~!:i~:~1~]i:i~;••••• .· .•.,;::/'t~"~(;¾(tJc:, ,I) ;';•">1: .. i.•· ..
. ,);', :</-:j,':.•:'' .,/Projec:ft~sksb(itellls that_donot•_conform_tQ the QNQC.re.quifemeiits,based dn;workiiig \:•·· _.
l~f[;;;:t~i\(_f:f\}if~~~?~ii/f{:1~1~~ft~ff?Vri(1fo{:~i~: .. i~~irtfd,\ft:~Iitff{ff~~(ef~it~t)~~~-'.:~{:/(,:'.
.. ·.,/./'.:;::(•.'ii'>? ;,'.;;susp~ct .-. t~a(.a_il:. activity:is\ncit;'.being·. peifoi'niecl .·in .·acc/>rdanc~')vith.,t!fo;~pplicab,le.''/ '. 1;1;:.:?,r~:::;::;::1;;{X~;x{~~;ir~~~~f v\:rq~::sKt~~~-~iR,~i6:{¥11.1 ~~.\.?~~-~id;,gf;~I('~P.~:h:A~f ;_f J'~~":ih~:.ri~:-~'.~k:!r:i :: >
·• ···\' , : : f · -iJ:' , ,.: ;Manager .,will act .m a llmely ma1\'net to ·venfy whether correcllve acl!on' 1s necessary.' -·,:. ,0;-· -··
. .,,
';~ . :'_)~ \\(\ 'f<.:_., ~., ·.t ')-.: ://i'. ::}\.<:-.,::{/i'.;~;;r~\ :·.?i .. ,' ::./,:; <·>:::·:,·. :·-~:_, __ -.·: :~::-j.)::'· : : : ·
·( • ·:, ·~,'," .... ,1 ,· .,• • -·: '.'-',,· GroundwaterSam·J)lingQualityAssuianceP.'. ,·,·:.., ';'. · .. ;,~ .. ',,.· ,;,\ ~·•:.
f r:::,\{;\i\:i::'.il~·'\ :/L'1.{.~.)::j;;i: l1:1~[ .. !:::I~}~i:=:I:f ;~~~I!;'..~~rtpt~-T~:if :::~/) {,: :;(/\ //'.}.:::.:: __ ::·\::.::::·
:L::,/_:, r: -:;r:: ::_: ri)it~~~ )~ .fie_(~·;;;~~~i;e~'~f~·-rJti~;t_~~fi~~tiv~'-~;ii6l;in be, ·i~·i;i~t(i)rni o/-i:~~k\.:'\/;: .· c:
:r:1-.. ·::. ,:iJ~i1\:/:l;t:ffrij·~~~-:1!1i'.~•;(:_rii:·?i'\~Jlt~;\~i~i~c§t]?:-';~E~}t~'\~~{}~t£f~~fir~&!i~i\!¥ii{j{;;ii;J)./:_i:;" .. ,•
·:•( ·· \'.; · .. ,, ·:: a.d.~re_s_seij ~nd n.?~ Q~q~ ~~~~ire~e~ts ~r~}~t~blj~he_~, i'.necessa!'Y;·\·.:::::_'.: ./.,, , :_. ·;.-·,;· -.. · ·
:j'~i! i"?t;(:f it1t;{r~,1~lif '.If ir~lj*,:1it,~?~,i;j'i:rjN\;~;itii~f ~t'i,Yc
:· r·· /:i,__ itf~s_.''~~'.°1'~:tive;~~t,jon~:f~(veld sampling arid t~sJi.Iig probleriis.\fl\b~:?evelqr~ tith
' : : . '.· : assistance 'rr'cim ihe fieid tea'rrC ' /::" ,'i ·; ' . ·:·'.\-: '.-.•. . . -· . . . . :.·:'_ \ ... _, . '. •;.·--. .. ... -· ,, .
-: \:,:? :::,•,, :' '::· '.: ', ' .' .. :; \:_:i/,, : ; : .. ·.'< e··. ·: ,:, ·-· ,._ •·· -· ·· •<. : ' : ' ·•·
, , · -::"·No additional wcirk dependent on the noncoiifoi:ni.ing aciivity will.be'perforined uiltilthe .. ~----._·-~rt-. ·: · .. ·.";'.-_ ?-,_,_:·-r:>..-·--~·-.:· .-: : ..... ;-::; IJ,: .. : -.: __ ;_ .> _ -__ Y:-.-t ·.:.· ~-_'· _:·-:. ::·. <'.-_":. ... '. .· . . : ; :-.;:...-~/.< :.: :_· __ ..... _--.-__ ._., --. ; ~
.·.->problem'. is _,correcte~: The ·.Project Maiiager i;ill:haye the uJtima:te respo!]sibility for·
· >: .i.~~~:ririg t~a:i_c~;e;ti~~ :ac.t\oii_;•ii{tuj1y i_+pi~~;;i;~,L ,''. -· . . -... · ,. ;,: ,. · --·-·. · · . • .
. ' .. , _..,. ·::· .•.·, :::>_'' .·._.'.':: ~-\:••' .... ''.. . ..·, .. ' . . '-'·'
... : . .' . ·, Tlie QA Task Manager will notify_ the Project ·Manager when correcti\re achons are : · ,
. •,•: ::\",'., • ' ' • ~ ' ,-. ', ,•.• I•.~ ; , ••,• t •:. ,;::•,.•'·' _':~• il './): '·,> : • :: completed and ·wiBcondu'ct aJollmy-up audit. . . _ , __ ,
r> ... : if.the proble~(s). h~s' bee~ corr~ct~d· t~ :ihe sat·i~faction of th~ QA J:~~k/'Ma'.nag~r, ·tl~e
·" -: ·: activity ma~ be r~s~iri~<l. ': 't'.i . . . ·-. . .
. ~ ., . _,.''
·<:;orre~'it~~,:lctiori~Laborato,ry'i_' .. , ...
. ,: : ,,· _;:;-\ ·:: : . , ' • , . '. -~ !, .' ~: _,_. '. ', .. _' , '-