NCD003200383_20100624_Koppers Co. Inc._FRBCERCLA RA_2010 First Semiannual Groundwater Monitoring Report-OCR

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FTS Field & Technical Services
200 Third Avenue• Carnegie, PA 15106 • Phone: [phone] • Fax: [phone]
June 24,2010
Ms. Beverly Stepter, Remedial Project Manager
US EPA -Region IV
North Superfund Remedial Branch
Waste Management Division
61 Forsyth Street, S.W.
Atlanta, Georgia 30303-8960
RE: 2010 First Semi-Annual Groundwater Monitoring Report for the
Former Koppers Company Site, Morrisville, North Carolina
Dear Ms. Stepter:
On behalf of Beazer East, Inc. (Beazer), Field & Technical Services, LLC (FTS) hereby submits
the results of the 20 IO first semi-annual groundwater monitoring event at the former Koppers
Company Site in Morrisville, North Carolina (Site). This report summarizes the field and
laboratory results of the groundwater monitoring event perfonned on February I 5 through
February 17, 2010.
Groundwater Monitoring Program -First Semi-Annual 2010
As of the December 2007 groundwater monitoring event, the Groundwater Monitoring Program
has been modified based on certain recommendations made in the United States Environmental
Protection Agency's (US EPA 's) Second Five-Year Review Report (U.S. Anny Corps of
Engineers, 2007)1.
Based on the requirements in the Proposed Remedial Action Groundwater Monitoring Program
(Thern10Retec, 1999),2 as modified with USEPA approval in 2003 (Retec, 2003)3
1 Final Five-Year Review Report, Second Five-Year Revie1,v Report for Koppers Co. Inc. (Morrisville Plant),
A1orrisvil/e, Wake County, North Carolina. Prepared by U.S. Army Corps. of Engineers for Region 4 U.S.
Environmental Protection Agency. August 2007.
2 ThcrmoRctcc, 1999. Proposed Remedial ActhJn Groundwater Monitoring Program. Prepared by ThcrmoRctcc
Consulting Corporation. August 1999.
3 Rctcc, 2003. Letrer to Beverly Hudson, USEPA, RE: Request for A1od(fications to the Groundll'ater Sampling
Program at the Former Koppers Company Site, Morrisville, North Carolina. Retcc, December 17, 2003.
~
FTS
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Ms. Beverly Stepter, Remedial Project Manager
USEPA -Region IV
Page 2 June 24, 2010
and the USEPA Second Five-Year Review recommendations, the first semi-annual groundwater
monitoring event of2010 included the following:
• Gauging of 36 monitoring wells (Figure I): i.e., 31 on-Site wells and 5 off-Site wells.
• Sampling of twelve (12) on-Site wells: C-I0B, C-12A, C-13B, C-14A, C-14B, C-15B,
C-27A, C-27B, C-28A, C-29B, M-04, PW-01.
Under the current program, 12 program wells are to be sampled annually for pentachlorophenol
in the first semi-annual event of the year. Wells with pentachlorophenol detections above the
remedial goal of I microgram per liter (µg/L) will be sampled for pentachlorophenol in the
second semi-annual event. In addition, wells with detections of pentachlorophcnol above the
remedial goal are to be sampled semi-annually for dioxins and furans. Once the concentrations
of pentachlorophenol for a given well meet the remedial goal for four consecutive sampling
events, that well will move to the annual sampling program for pentachlorophenol.
At the request of the property owner and with the concurrence of USEPA and NCDENR,
monitoring wells C-11 A and C-1 I B were removed from the current program and abandoned in
November 2009.
Groundwater Elevation and Direction of Flow
Groundwater elevations for the A-and B-zone wells, measured on February 15, 20 I 0, are
presented in Table I. The groundwater elevations in Table l were used to construct the A-and
B-zone groundwater potentiometric surface elevation contour maps included as Figures 2 and 3.
Historically, groundwater elevations for well C-1 OB have differed significantly from the
groundwater elevations in the other B-zone wells. ln addition, groundwater purging and
recovery data indicate that this well is installed in a very low permeability formation. The
consistently different groundwater elevations in this well, in conjunction with the fact that this
well is 55 feet deeper than the neighboring B-zone wells, indicate that C-1 OB does not
communicate with the same section of the B-zone aquifer as the other B-zone monitoring wells.
Due to this lack of communication, C-1 OB will continue to be gauged but will not be included in
the data set used to construct the potentiometric surface map for the B-zone (Figure 3) in
accordance with recommendations presented in the USEPA Second Five-Year Review.
Figures 2 and 3 show the cone of depression that exists around the groundwater extraction well
PW-01 and indicate that, outside the zone of influence a groundwater mound exists beneath the
northern section of the Site. From the groundwater mound, groundwater flow in the A-zone is
generally to the northeast, with some flow to the southwest toward C-08A and C-25A.
tJ
FTS
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Ms. Beverly Stepter, Remedial Project Manager
USEPA -Region IV
Page 3 June 24, 20 I 0
Groundwater flow from the groundwater mound in the B-zone is generally to the southwest with
an eastern and northwestern component.
Pcntachlorophenol Analytical Results
Each groundwater sample was analyzed for pentachlorophenol us111g the USEPA SW-846
Method 8270C; the analytical results are summarized in Table 2. FTS personnel evaluated the
groundwater analytical results and applied any necessary data qualifiers, as summarized in
Table 2. Complete copies of the data evaluation summary and laboratory analytical results are
included in Appendix A. Figures 4 and 5 present isoconcentration contour maps for
pentachlorophenol.
As shown in Table 2, pentachlorophenol was detected in groundwater from four wells (C-l 4A,
C-14B, C-29B, and PW-01) ranging from 2.4 µg/L (C-14B) to 100 µg/L (C-14A) during the
20 IO first semi-annual sampling event. All four of these pentachlorophenol detections exceeded
the remedial goal of I µg/L. These results are consistent with historical data. Appendix B
provides a summary of the historical groundwater analytical results for the Site.
In accordance with the revised program, C-14A, C-14B, C-29B, and PW-01, those wells with
detections of pentachlorophenol above the remedial goal, will be sampled for pentachlorophenol
and dioxin and furans in the 20 IO second semi-annual groundwater monitoring event.
Dioxin and Furan Analytical Results
The Groundwater Monitoring Program requires that dioxin and furan samples be collected semi-
annually and analyzed by USEPA SW-846 Method 8290 from wells that had concentrations of
pentachlorophenol at or above the specified remedial goal during the previous sampling event, or
wells with two or more pentachlorophenol detections in the previous four sampling events.
Therefore, the 20 IO first semi-annual dioxin and furan sampling event included wells C-l 4A, C-
14B, C-29B, M-04, and PW-01. M-04 could not be sampled during the first and second semi-
annual 2009 groundwater monitoring events and therefore was sampled for dioxins and furans
during this event. The dioxin and furan results are summarized in Table 2.
Two monitoring wells, M-l 4A and M-04, historically go dry and/or have turbid samples when
sample collection occurs due the dewatering of the aquifer by the pumping of PW-0 I. The FTS
technicians collected both non-filtered and field filtered samples from these wells (M-14A and
M-04) for dioxin and furans during this sampling event (Table 2).
FTS personnel evaluated the groundwater analytical results and applied any necessary qualifiers
(Table 2). A copy of the lab report is included in Appendix A. Table 3 shows the detected
concentrations of dioxins and furans with their calculated toxicity equivalent quotient (TEQ)
concentration. The TEQ concentration is calculated by multiplying the concentration of each
It
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Ms. Beverly Stepter, Remedial Project Manager
USEPA -Region IV
Page 4 June 24, 2010
dioxin or furan by its respective tox1c1ty equivalent factor (TEF). The resulting TEQ
concentrations are then summed for each sample to detennine the total TEQ.
As presented in Tables 2 and 3, 1,2,3,4,6,7,8-HpCDD, OCDD, OCDF, total HpCDD, and total
HpCDF were detected in the non-filtered samples from wells C-14A, M-04, and PW-01.
1,2,3,4,6,7,8-HpCDF was also detected in well M-04. OCDD was detected in the non-filtered
sample collected from well C-14B and in the filtered samples collected from wells M-I 4A and
M-04. No other dioxin or furan compounds were detected in any of the other samples. As
shown in Table 3, the calculated total TEQ from the non-filtered samples for C-14A, C-14B, M-
04, and PW-0 I were 2.849 picograms per liter (pg/L), 0.057 pg/L, 5.008 pg/L, and 2.1891 pg/L,
respectively. In comparison, the calculated total TEQ values from the filtered samples for C-
14A (0.036 pg/L) and M-04 (0.081 pg/L) were significantly lower. All of the TEQ values
reported were well below the remedial goal of 30 pg/L.
In accordance with the Groundwater Monitoring Program, dioxin and furan sampling are
scheduled to occur semi-annually from wells with pentachlorophenol detections above the
remedial goal or wells with two or more pentachlorophenol detections in the previous four
sampling events. Therefore, wells C-l 4A, C-l 4B, C-29B, and PW-0 I will be scheduled for
sampling during the second semi-annual 2010 sampling event. Beazer requests that USE PA
respond to Beazer's July 2007 request to eliminate dioxins and furans from the Groundwater
Monitoring Program, as there hasn't been a TEQ exceedance since 2006.
Operational Summary
The groundwater extraction system was designed to extract 5 gallons per minute (gpm), but
currently operates at only approximately 1.5 gpm. The extraction well is completed in fractured
bedrock (30 to 49 feet bgs) and the current pumping rate represents the maximum pumping rate
for the bedrock fonnation. Potentiometric maps (Figures 2 and 3) and isoconcentration figures
(Figures 4 and 5) indicate that the groundwater extraction and treatment plant captures the
pentachlorophenol plume. Fluctuations in pentachlorophenol concentrations are attributed to
fluctuating groundwater elevations. Review of the Site groundwater data indicates that while the
pentachlorophenol plume is stable, the current extraction system appears to be at steady state and
unable to significantly reduce the residual Site plume 4.
Beazer has proposed to enhance the groundwater remedy by using in-situ chemical oxidation
(ISCO) in a pilot test to accelerate the remediation of residual pentachlorophenol plume (Work
Plan)5. USEPA has approved the Work Plan, and the NCDENR has issued an Underground
4 GcoTrans, 2010, Revised Pilot Test Work Plan to Enhance the Groundwater Remedy, Former Koppers Company
Site, Morris,·ille, North Carolina, submitted to USEPA, April 30, 2010.
5 Sec Footnote 4.
■ FTS
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Ms. Beverly Stepter, Remedial Project Manager
USEPA -Region IV
Page 5 June 24, 2010
Injection Control (UJC) pennit6 which is required for the implementation of this remedy. The
pilot study was initiated the week of May 24, 20 IO with pumping well PW-0 I being turned off.
Baseline (pre-injection) sampling of wells (C-l 4A, C-14B, C-29B, and PW-0 I) is scheduled to
occur the week of June 21, 20 IO with the sodium persulfate injections to occur the week of
June 28, 2010. Post-injection sampling of wells (C-14A, C-14B, C-29B, and PW-01) will follow
at the frequency of I week, 2 weeks, 6 weeks, and IO weeks and for a maximum of three
quarterly events described in the Work Plan. The results of the pilot test monitoring will be used
to evaluate remediation effectiveness and will be evaluated to detennine potential need for a
reapplication. The pilot test results will be presented in an effectiveness evaluation report.
If you have any questions regarding these results, analytical review, and requested revision to the
Groundwater Monitoring Program, please call Angie Gatchie of FTS at [phone] or
Michael Tischuk, Beazer Environmental Manager at [phone].
Sincerely,
Field & Technical Services, LLC
Y'rY?.A~
Angie Gatchie
Project Scientist
Attachments
cc: D. Mattison, NC DENR
M. Tischuk, Beazer
J. Abrahams, GeoTrans
6 NCDENR, 2010, Issuance of Injection Permit W/0500155, Former Koppers Company Site, A1orris11ille, North
Carolina. submitted to Beazer, March 12, 20 I 0.
II
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2010 First Semi-Annual Groundwater Monitoring Report for the
Former Koppers Company Site, Morrisville, North Carolina
TABLES
ii
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Table 1
Groundwater Elevations
2010 First Semi-Annual Groundwater Monitoring Event
Former Koppers Company Site
Morrisville, North Carolina
Top of Casing
Gauging Elevation
Well ID Date (feet msl)
A-ZONE
C-01A 02/15/10 383.06
C-02A 02/15/10 380.76
C-04A 02/15/10 385.31
C-05A 02/15/10 386.59
C-06A 02/15/10 383.90
C-07A 02/15/10 374.30
C-08A 02/15/10 376.34
C-09A 02/15/10 372.98
C-10A 02/15/10 373.88
C-11A 02/15/10 363.28
C-12A 02/15/10 375.00
C-13A 02/15/10 367.31
C-14A 02/15/10 371.13
C-15A 02/15/10 357.08
C-25A 02/15/10 365.52
C-26A 02/15/10 382.12
C-27A 02/15/10 372.10
C-28A 02/15/10 372.40
C-30A 02/15/10 379.11
C-31A 02/15/10 379.98
C-33A 02/15/10 354.37
M-04 02/15/10 368.83
PW-01 02/15/10 371.29
B-ZONE
C-02B 02/15/10 381.72
C-09B 02/15/10 374.76
C-10B 02/15/10 373.58
C-11B 02/15/10 363.28
C-12B 02/15/10 375.75
C-13B 02/15/10 367.02
C-14B 02/15/10 371.66
C-15B 02/15/10 357.62
C-25B 02/15/10 364.85
C-26B 02/15/10 382.21
C-27B 02/15/10 372.01
C-28B 02/15/10 373.07
C-29B 02/15/10 369.00
C-33B 02/15/10 352.84
C-34B 02/15/10 376.31
Notes:
feet msl = feet above mean sea level
feet TOG = feet below top of inner casing
NA= not available, well was abandoned
• = well abandoned November 2009
Depth to
Groundwater
(feet TOC)
21.90
23.58
18.58
16.52
13.90
8.80
26.50
10.40
19.49
NA'
14.09
9.38
27.32
2.16
16.62
17.64
20.95
9.09
23.49
17.22
7.01
15.40
34.97
8.81
18.52
42.96
NN
14.58
5.11
27.38
2.38
15.25
22.15
36.89
9.20
34.28
6.22
15.39
Q:\Projec!s\Beazer Projects\Raleigh\MoniloringDAT A-Reporting\Groundwa!er\Reports\Reports\Reports 2010\ 1 SA 201 O\T ables\ Table 1 • 1 SA 1 O.xls
Groundwater
Elevation
(feet msl)
361.16
357.18
366.73
370.07
370.00
365.50
349.84
362.58
354.39
NA
360.91
357.93
343.81
354.92
348.90
364.48
351.15
363.31
355.62
362.76
347.36
353.43
336.32
372.91
356.24
330.62
NA
361.17
361.91
344.28
355.24
349.60
360.06
335.12
363.87
334.72
346.62
360.92
FTS
1 of 1
-----... - -------
Sample Location
Same le Date
Method 8270C
Pentachloroohenol
Method 8290
1,2,3,4,6, 7 ,8-HPCDD
1,2,3,4,6, 7 ,8-HPCOF
1,2,3,4,7 ,8,9-HPC0F
1,2,3,4,7,8-HXCDD
1,2,3,4,7,8-HXCDF
1,2,3,6,7,8-HXC0D
1,2,3,6,7,8-HXCDF
1,2,3,7,8,9-HXC00
1,2,3,7,8,9-HXCDF
1,2,3,7,8-PECOD
1,2,3,7,8-PECOF
2,3,4,6, 7 ,8-HXCDF
2,3,4,7,8 PECDF
2,3,7,8-TCDD
2,3,7,8-TCOF
OCDD
OCDF
Total HPCDD
Tota! HPCDF
Total HXCDD
Total HXCOF
Total PECDD ·
Total PECOF
Total TCDD
Total TCDF
Notes:
pg/L = picograms per liter
µg/L = micrograms per ~ler
Units
uofl..
oolL
DOIL
oolL
oolL
oalL
oolL
oolL
oolL
oolL
oolL
DOIL ~,
oolL
oolL
DOIL
DOIL
oolL
oolL
oolL
DOIL
oolL
oolL
oolL
oolL
DOIL
Bold values represent detections.
□UP indicates duplicate sample.
Table 2
Groundwater Sampling Analytical Results
2010 First Semi-Annual Groundwater Monitoring Event
Former Koppers Company Site
ROD
Ground-
water C-108 C-12A C-13B C-14A
Standard• 2/16/2010 2/16/2010 2/16/2010 2/16/2010
1 0.97 U 1 U 0.98 U
NA NA NA NA
NA NA NA NA
NA NA NA NA
NA NA NA NA
NA NA NA NA
NA NA NA NA
NA NA NA NA
NA NA NA NA
NA NA NA NA
NA NA NA NA
NA NA NA NA
NA NA NA NA
NA NA NA NA
NA NA NA NA
NA NA NA NA
NA NA NA NA
NA NA NA NA
NA NA NA NA
NA NA NA NA
NA NA NA NA
NA NA NA NA
NA NA NA NA
NA NA NA NA
NA NA NA NA
NA NA NA NA
U indicates compound was analyLed for, but not detected.
J indicates estimated vah.Je less than reporting limil
NA indicates not analyzed.
"Record of Decision Groundwater Cleanup Standard
•• Sample was field ffitered
100
230
57 u
57 u
57 u
57 u
57 u
57 u
57 u
57 u
57 u
57 u
57 u
57 u
11 u
11 u
1700
130
380
96
57 U
57 U
57 U
57 U
11 u
11 U
Morrisville, North Carolina
C-14A .p• C-14B C-15B C-27A C-27B
2/16/2010 2/16/2010 2116/2010 2/16/2010 2116/2010
NA 2.4 1 U 0.99 U 0.99 U
51 u 48 U NA NA NA
51 u 48 U NA NA NA
51 u 48 U NA NA NA
51 u 48 U NA NA NA
51 u 48 U NA NA NA
51 u 48 U NA NA NA
51 u 48 U NA NA NA
51 u 48 U NA NA NA
51 u 48 U NA NA NA
51 u 48 u NA NA NA
51 u 48 u NA NA NA
51 u 48 u NA NA NA
51 u 48 u NA NA NA
10 U 9.6 U NA NA NA
10 U 9.6 U NA NA NA
120 190 NA NA NA
100 U 96 U NA NA NA
51 u 48 U NA NA NA
51 u 48 U NA NA NA
51 u 48 U NA NA NA
51 u 48 U NA NA NA
51 u 48 U NA NA NA
51 u 48 U NA NA NA
10 u 9.6 U NA NA NA
10 u 9.6 U NA NA NA
0:\f'rojeds\Bea.!er Pr~\Raleq1\McnlalrgOA T A-Re;,at111g\Gn,.rm3ler\Reports\Reports\Reports 201!P. 1SA 201!P. T atiles\T atile 2 · 1 SA 10.ds
C-28A C-29B
2/1612010 2/1612010
1.1 U I 11
NA 48 U
NA 48 U
NA 48 U
NA 48 U
NA 48 U
NA 48 U
NA 48 U
NA 48 U
NA 48 U
NA 48 U
NA 48 U
NA 48 U
NA 48 U
NA 9.5 U
NA 9.5 U
NA 95 U
NA 95 U
NA 48 U
NA 48 U
NA 48 U
NA 48 U
NA 48 U
NA 48 U
NA 9.5 U
NA 9.5 U
--- -
FTS
C-29B CUP M-04 M--04-P* PW--01
2/16/2010 2/1612010 2/17/2010 2/1612010
11 1 U NA 38
51 u 330 51 u 150
51 u 55 51 u 48 U
51 u 55 U 51 u 48 U
51 u 55 U 51 u 48 U
51 u 55 U 51 u 48 U
51 u 55 U 51 u 48 U
51 u 55 U 51 u 48 U
51 u 55 U 51 u 48 U
51 u 55 U 51 u 48 U
51 u 55 U 51 u 48 U
51 u 55 U 51 u 48 U
51 u 55 U 51 u 48 U
51 u 55 U 51 u 48 U
10 U 11 U 10 U 9.7 U
10 U 11 U 10 U 9.7 U
100 U 3700 270 2200
100 U 160 100 U 97
51 u 530 51 u 260
51 u 190 51 u 62
51 u 55 U 51 u 48 U
51 u 55 U 51 u 48 U
51 u 55 U 51 u 48 U
51 u 55 U 51 u 48 U
10 U 11 u 10 U 9.7 u
10 U 11 U 10 U 9.7 U
1 of 1
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Analyte
1,2,3,4,6, 7,8-HPCDD
1,2,3,4,6, 7,8-HPCDF
1,2,3,4,7,8,9-HPCDF
1,2,3,4,7,8-HXCDD
1,2,3,4,7,8-HXCDF
1,2,3,6,7,8-HXCDD
1,2,3,6,7,8-HXCDF
1,2,3,7,8,9-HXCDD
1,2,3, 7,8,9-HXCDF
1,2,3,7,8-PECDD
1,2,3, 7,8-PECDF
2,3,4,6,7,8-HXCDF
2,3,4,7,8-PECDF
2,3,7,8-TCDD
2,3,7,8-TCDF
OCDD
OCDF
otal HPCDD
Total HPCDF
otal HXCDD
otal HXCDF
otal PECDD
otal PECDF
Total TCDD
otal TCDF
rrotal TEO:
Notes:
pg/L = picograms per liter
TEF = Toxicity Equivalent Factor
TEO= Toxicity Equivalent Quotient
Bold values represent detections.
DUP indicates duplicate sample.
TEFt
0.01
0.01
0.01
0.1
0.1
0.1
0.1
0.1
0.1
1
O.Q3
0.1
0.3
1
0.1
3E-04
3E-04
0
0
0
0
0
0
0
0
t World Health Organization (WHO) 2005 TEF Values
Units
nn/L
nn/L
nn/L
nn/L
nn/L
nn/L
nn/L
nn/L
nn/L
nn/L
nn/L
nn/L
nn/L
nn/L
nn/L
nn/L
nn/L
nn/L
nn/L
nn/L
nn/L
nn/L
nn/L
nn/L
nn/L
nn/L
Table 3
Calculation of Toxicity Equivalent Quotients for Dioxins/Furans
2010 First Semi-Annual Groundwater Monitoring Event
Former Koppers Company Site
Morrisville, North Carolina
ROD
Groundwater C-14A C-14A-F
Standard* Result TEQ Result
NA 230 2.3 51 u
NA 57 U 0 51 u
NA 57 u 0 51 u
NA 57 u 0 51 u
NA 57 u 0 51 u
NA 57 u 0 51 u
NA 57 u 0 51 u
NA 57 u 0 51 u
NA 57 u 0 51 u
NA 57 u 0 51 u
NA 57 u 0 51 u
NA 57 U 0 51 u
NA 57 U 0 51 u
NA 11 U 0 10 U
NA 11 U 0 10 U
NA 1700 0.51 120
NA 130 0.039 100 U
NA 380 0 51 u
NA 96 0 51 u
NA 57 u 0 51 u
NA 57 u 0 51 u
NA 57 u 0 51 u
NA 57 u 0 51 u
NA 11 u 0 10 u
NA 11 u 0 10 u
30 2.849
U indicates compound was analyzed for, but not detected.
J indicates estimated result less than reporting limit
NA indicates not applicable.
TEQ
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.036
0
0
0
0
0
0
0
0
0
0.036
Result
48 u
48 U
48 U
48 U
48 u
48 U
48 u
48 u
48 u
48 U
48 U
48 U
48 U
9.6 U
9.6 U
190
96 U
48 u
48 U
48 u
48 u
48 U
48 U
9.6 U
9.6 U
Laboratory results that were LI-qualified were assigned a value of 0 for this calculation.
"Record of Decision Groundwater Cleanup Standard
C-14B C-29B
TEQ Result
0 48 U
0 48 U
0 48 u
0 48 U
0 48 U
0 48 U
0 48 U
0 48 U
0 48 U
0 48 U
0 48 U
0 48 U
0 48 U
0 9.5 U
0 9.5 U
0.057 95 u
0 95 U
0 48 u
0 48 U
0 48 U
0 48 U
0 48 U
0 48 U
0 9.5 U
0 9.5 U
0.057
TEQ
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
O:\Pl"Ojec:S\Beazer ProjectslR2!eigh\Morn:olir,gDATA-ReporJng\Groundwater,Repor:s\Repor.s\Repon.s 2010\lSA 2010\Tables\Table J -1SA 10 xis
FTS
C-29B DUP M-04 M-04-F PW-01
Result TEQ Result TEQ Result TEQ Result TEQ
51 u 0 330 3.3 51 u 0 150 1.5
51 u 0 55 0.55 51 u 0 48 U 0
51 u 0 55 U 0 51 u 0 48 U 0
51 u 0 55 U 0 51 u 0 48 U 0
51 u 0 55 U 0 51 u 0 48 u 0
51 u 0 55 u 0 51 u 0 48 U 0
51 u 0 55 u 0 51 u 0 48 U 0
51 u 0 55 U 0 51 u 0 48 U 0
51 u 0 55 U 0 51 u 0 48 U 0
51 u 0 55 U 0 51 u 0 48 u 0
51 u 0 55 u 0 51 u 0 48 U 0
51 u 0 55 U 0 51 u 0 48 U 0
51 u 0 55 U 0 51 u 0 48 U 0
10 U 0 11 U 0 10 U 0 9.7 U 0
10 U 0 11 U 0 10 U 0 9.7 U 0
100 U 0 3700 1.11 270 0.081 2200 0.66
100 U 0 160 0.048 100 U 0 97 0.0291
51 u 0 530 0 51 u 0 260 0
51 u 0 190 0 51 u 0 62 0
51 u 0 55 U 0 51 u 0 48 U 0
51 u 0 55 u 0 51 u 0 48 U 0
51 u 0 55 U 0 51 u 0 48 U 0
51 u 0 55 U 0 51 u 0 48 U 0
10 U 0 11 u 0 10 U 0 9.7 u 0
10 U 0 11 U 0 10 U 0 9.7 U 0
0 5.008 0.081 2.1891
Page 1 of 1
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2010 First Semi-A1111ua/ Grou11dwater Monitoring Report for the
Former Koppers Company Site, Morrisville, North Carolina
FIGURES
~
FTS
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• / }
f e < 11
0
0
= []
II
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c=J I
~) ~ J ? ---•--· ◊ □
0
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,,_ C26A
Tc26B
D
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:+C31A
/
0
7
co2e+
PW-01 ♦
I I~------------.---,;;~==------------------------------------------------~
J-lf4H=+--=-=:-:-=:-,_::,,:-, :-,_::,,:-, ---+ ... ~ ~ lf4'-+'='l---'==--'c==-,'--"'~'-:::-:-,~=~~;;----t-:._::::-I §' /\ A£MCNED wnL C--018, C-108, -------v~ ,.,.,
z---:;;__-+
LEGEND
0
MONITORING WEI..L
PUMPING WELL
RAILROAD TRACKS
FENCEUNE
DRAJNAGE/S1REAM
PROPERTY BOUNDARY -BEAZER
EAST, INC.
PROPERTY BOUNDARY -UNIT
STRUCTIJRES INC.
PROPERTY BOUNDARY -UNKNOWN
400
BEAZER EAST, INC.
800
FEET
PITTSBURGH, PENNSYLVANIA = :. :~ :~:~:~ " FIELD • T>'.C><NK:M_ S[IMCES, u.c
N>PO: JSZ. DATE: 03/12/10 200 THIRD AVENUE
SCALE: AS SHOWN FTB CARNEGIE. PA 1:1106
ISSUE DATE:
2010 FlRST SEMI-ANNUAL GROUNDWATER MONITORING REPORT FORMER KOPPERS COMPANY RALEIGH SITE
MORRISVIL1£, NORTH CAROLINA
PROJECT NO: Olil053010 I
sm: MAP FiGU RE!
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C33A
♦
347.36
CJ
/
I
0
0
0
.C02A
357.18
-+-PW-01
z---=:::-1-
LEGEND
MONITORING WELL
AND GROUNDWATER ELEVATION
PUMPING WELL
RAILROAD TRACKS
FENCELINE
DRAINAGE/STREAM
~~f.E~1Z. BOUNDARY _ BEAZER
PROPERTY BOU STRUCTURES IN~DARY -UNIT
PROPERTY BOUNDARY -UNKNOWN
35Q - ----POTENTIOMETRIC s (ONTOUR 5' INTER~~[ACE ELEVATION
DASHED WHERE INFERRED)
0 --3□0 600
FEET
BEAZER EAST INC
PITTSBURGH, PENNSYLVANIA = KC DATE: 03/12/10 ■
N'P0:0
:: :: :;:~,o fil FlElD .t TECHNICM.
SCAI.£: AS SHOWN 10 -SEJMCES, LLC
ISSUE O.,.TE: 200 lHIRO AVENUE FTS CARNEGIE. PA 1!)106
2010 FlRST SEMI ANN ---UAL GROUNDWATER
I
FORMER KOPPERS COM MONITORING REPORT
RALEJGH SITE PANY
MORRJSVIL1£, NORTH ,. • ., '-""'CUNA
POTENTIOMETRIC s CONTOUR t.t.JRFACE ELEVATION ~_!0"~~10 -A ZONE .,._,,_ ..., ........ FIGURE 2
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1 C33B i ♦
/ 346.62
z ---:::_--1-
LEGEND
_,;,_ CO2B
T 372.91
... PW-O1
MONITORING WELL
AND GROUNDWATER ELEVATION
PUMPING WELL
-t--f---+---1--RAILROAD TRACKS
--~-~-FENCELINE
DRAINAGE/STREAM
· - -· - -· -PROPERTY BOUNDARY -BEAZER
EAST, INC.
- ---- -PROPERTY BOUNDARY -UNIT
STRUCTURES INC.
- - - - - - - -PROPERTY BOUNDARY -UNKNOWN
350----
0
POTENTIOMETRIC SURFACE ELEVATIO
CONTOUR 5' INTERVAL
(DASHED WHERE INFERRED)
300
BEAZER EAST, INC.
600
FEIT
PITTSBURGH, PENNSYLVANIA
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0
7
/
C14A •
PW-01
♦
z---=:::..........J_
LEGEND
MONITORING WELL
PUMPING WELL
RAILROAD TRACKS
FENCELINE
g~l~:itSTREAM
EAST, INC. BOUNDARY _ BEAZER
PROPERTY STRUCTURE~Ol~~DARY -UNIT
-PROPERTY . BOUNDARY PENTACH -UNKNOWN
coNCENT'r8.~PoPNHENOL _ u~L
-10---PENTAC ISOCON~~~;OPHENOL
100
RATION CONTOURS
U INDICATES ANAL YlED CFOOMPOUND WPS R BUT N OT DETECTED
ug/L MICROGRAMS PER LITER
0 300
BEAZER EAS
600
FEET
PITTSBURGH T, INC.
ORWN, ' PENNSYLVANIA
CHKO: ~ OAlE: 03/17/10
APPi> -"'Z OA1" o,/H/10 TI """" OA1" '-'/H/10 FlEI.O • TECHNICAL
AS SHOWN SERVIC[S ISSUE OA1" 200 THIRD ' L1.C
2010 FlRST S EI!! CARNm~ ,:~~,;,
EMI-ANNUAL
I
FORM GROUNDWATER ER =ERS COMP:;:NrrORlNG REPORT
MORRISv1Ll.E H SITE • NORTH CAROLINA
I PENTACHL SOCONCENTRATIO OROPHENOL N C0'1TOURS "'°""" '°' ""'°"' -A ZONE llR,l,lll'NG P'lJM8ER
10
FIGURE 4
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r===J; ~
-;-·-) ◊
0 ()
REMCMD WEll C-018
00,C~PllOH
I \
0
z---==--'
LEGEND
C14B -+ MONITORING WELL
RAILROAD TRAC
FENCELINE KS -= ~~l~t~-if STREAM
EAST, INC. BOUNDARY _ BEAZ
-PROPERTY ER
-STRUCTURE~01¼~DARY -UNIT
-PROPERTY BOUN~ARY
2.4 PENTA -UNKNOWN
_ _ CONCECN~~~~~:r~NOL
--1----PENTACH g/L ISOCONC~~~OPHENOL RATION CONTOU
U RS
INDICATES ANALYlED ~gMPOUND WAS R BUT NOT
MICROGRAMS DETECTED
ug/L PER LITER
0 300 600
FEET
BEAZER PITTSBURGH ~ST, INC.
DRWN, O<C ' ENNSYLVANIA
CHKD: RMW DATE: 03/17/10 ■ N'PD: JSZ. DATE: OJ/17/10 II SCAl!, o,.m OJt,7t,o FlElD • TECHNICAL
ISSU ,s ""°"" SEJMC~ E DATE, 200 ~• 11.C
2010 FlRST SEM EI!! CAANE':~"°p:~~~
6
I-ANNUAi..
I
FORMER K~~~W~p MONITORING REPO
MORRISVl~GH SITE ,m RT
PENI ' NORTH CAROLINA
ISOCONCENTRA~LOROPHENOL N co~,,.,.., , PROJECT NO: ,~,,.,.,,RS - 8 ZONE DRAWNC. ~10 FIGURES
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u
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CJ
/
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_,i,,C02A
T357_ 18
.PW-01
350----
z
LEGEND
MONITORING WELL
AND GROUNDWATER ELEVATION
PUMPING WELL
RAILROAD TRACKS
FENCEUNE
DRAINAGE/STREAM
PROPERTY BOUNDARY -BEAZER EAST, INC.
PROPERTY BOUNDARY -UNIT
STRUCTURES INC.
PROPERTY BOUNDARY -UNKNOWN
POTENTIOMETRIC SURFACE ELEVATION
CONTOUR 5' INTERVAL
(DASHED WHERE INFERRED)
PENTACHLOROPHENOL ---10----ISOCONCENTRATION CONTOURS
0 300 600
FEET
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r-=---'I I
c=J /
__ ._,________.J
C
' ' C
~
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~
-
0
$
~ • i ,
s
' ,
]
z---=::..-'
LEGEND
1--C02B MON
372.91 AND 1l0Rig~~D WELL
... PW-01 PUMPING W WATER ELEVATION
=:==~-=--=-::_-=-~::_--RAILROAD T:: FENCELINE KS
-DRAINAGE/STREA
PROPERlY M EAST, INC. BOUNDARY -BEAZ
PROPER ER
STRUCTJ;\'E~Ol~~DARY _ UNIT
-PROPERlY BOUN~ARY
35Q - ----POTENTIOM -UNKNOWN CONTOUR EJRIC SURFA (DASHED JH INTERVAL CE ELEVATIO
ERE INFERRED)
PENTACHLO - --1--ISOCONCENfOPHENOL RATION CONTOURS
0 300 600
FEET
BEAZER PITTSBURGH, EAST, INC °"""' KC PENNSYLVANIA
CHKD; RWW OATE: ll.l/12/10
""""' .., ... TE, <llj,,/,o ,, SCALE: DATE: ll.l/12/10 flELD &'. TEQ-INICAI..
ISSUE °'"" ,s "'°"" S<RVlCES. LLC
F 200 THIRD ,._
2010 FlRST S ...I!!! CARNEGIE. PA ~UE EMI-ANNUAL 1 oe
I
FORMER GROUNOWAlER •ORRISV1~~~ ~O•P,:,NITORING REPORT
POTENTI ' NORTH CARO
CONTOUR OMETRIC SURF UNA
JSOCONC~TlO/tN PENTA~T..o ~ROPATION CONTOURS HD/Ol ~ NO: Olrim,JOIO -8 ZON Fl .....,. GURE 7
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2010 First Semi-Annual Groundwater Monitoring Report.for the
Former Koppers Company Site, Morrisville, North Carolina
APPENDIX A
Analytical Data
~ FTS
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FTS, LLC
DATE: March 11, 2010
FROM: Kendra Chintella
SUBJECT: Raleigh GW
SAMPLE DELIVERY GROUP (SDG): C0B170457
SAMPLES: C-12A, C-15B, C-28A, C-14B, C-29B, C-99A(C-29B), C-27B, C-27A, C-13B, C-10B, PW-
01C, M-04, EB-01, C-14A, C-14A-F
ANALYSES: Method 8270C SIM (Pentachlorophenol), 8290 (Dioxins/Furans)
LABORATORY: TestAmerica Laboratories, Inc.
The data contained in this SDG were evaluated with regard to the following parameters:
o Data Completeness
Noncompliances: None
D
D
D
D
D
D
Holding Times
Noncompliances: None
Laboratory Blank Contamination
Noncompliances: None
Field Blank Contamination
Noncompliances: None
Field Duplicate Precision
Noncompliances: See attached page for details.
Surrogate Recoveries
Noncompliances: None
Matrix Spike and Matrix Spike Duplicate
Noncompliances: The MS/MSD recovery of OCDD was above the control limits. No action was
taken as the LCS recovery was compliant.
D Laboratory Control Sample
Noncompliances: None
Field Duplicate Precision:
FIELD DUPLICATE PRECISION
ANALYTE I C-29B I QUAL I C-99A I QUAL I RPO
Pentachlorophenol I 11 I I 11 I I 0
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Test America
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
Raleigh, Morrisville
Lot#: COB170457
Angie Gatchie
Field and Technical Services,
TKSTAMBRI.CA LABORATORIES, INC.
Veronica Bertot
Project Manager
F~ruary 25, 2010
TestAmerica Laboratories, Inc.
I COBl 70457
301 Alpha Drive Pittsburgh, PA 15238 tel [phone] fax [phone] www.testamericainc.com
1 of 37
NELAC REPORTING:
At the time of analysis the laboratory was in compliance with the current NELAC standards and held
accreditation for all analyses performed unless noted by a qualifier. The labs accreditation numbers are listed
below. The format and contents of the report meets all applicable NELAC standards except as noted in the
narrative and shall not be reproduced except in full, without the written approval of the laboratory. The table
below presents a summary of the certifications held by TestAmerlca Pittsburgh. Our primary accreditation
authortty for the Non-potable water and Solid & Hazardous waste programs is Pennsylvania DEP. A more
detailed parameter list is available upon request. Please ask your project manager for this information when
required.
Certifying Certificate# Program Types TestAmerlca State/Program
NFESC NA NAVY X
US Dept of Aqriculture l#P330-07-00101 \ Forei□n Soil lmnort Permit X
Arkansas (#88-0690) WW X
HW X
CaH!omia -NELAC 04224CA WW X
HW X
Connecticut (#PH-0688) WW X
HW X
Florida -NELAC (#E871008--04) WW X
HW X
Illinois -NELAC (#002064) WW X
HW X
Kansas -NELAC (#E-10350) WW X
HW X
Louisiana -NELAC (#04041) WW X
HW X
New Hampshire -NELAC (#203008) WW X ---
New Jersey-NELAC (PA-005) WW X
HW X
New Yori< -NELAC (#11182) WW X
HW X
North Carolina (#434) WW X
HW X
Pennsylvania -NELAC (#02-00416) WW X
HW X
South Carolina (#89014002) WW X
HW X
Utah-NELAC (STLP) WW X
HW X
West Virginia (#142) WW X
HW X
Wisconsin 998027800 WW X
HW X
The codes utilized for program ,types are desClibed below:
HW Hazardous Waste certification
VWv Non-potable Water and/or Wastewater certification
X Laboratory has some fom, of certification under the specific program. Many states certify laboratories for specific parameters or
tests IMthln a category. The information In the table indicates the lab is certified in a general category of testing. Please contact
the laboratory If parameter specific certification lnfonnation is required.
Updated: 2/5/2009 C:\Documents and Settings'<leruboisn\My Documents\NELAC NARRATIVE Pttsb~.doc
COB170457 2
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CASE NARRATIVE
Field and Technical Services
Lot# COB 170457
Sample Receiving:
TestAmerica's Pittsburgh laboratory received samples on February 17, 2010. The coolers
were received within the proper temperature range.
If project specific QC was not required for samples contained in this report, when batch
QC was completed on these samples, anomalous results will be discussed below.
GC/MS Semivolatiles:
Due to the concentration of target compounds detected, sample C-14A was analyzed
undiluted and at a dilution. Both sets of results are reported.
All non-CCC compounds that have> 15% RSD were evaluated to see if a better curve
could be drawn using a quadratic curve. All compounds <30% RSD will use an average
response factor curve if no visible improvement is accomplished using a quadratic curve.
A quadratic curve will be used for a compound where it is determined to be the "best-fit"
evaluation.
Dioxins:
TestAmerica's West Sacramento laboratory performed the dioxin analysis. All results are
included in the report.
The matrix spike duplicate of sample PW-0IC recovered outside control limits for
OCDD.
COB170457 3 of 37
n
0 to
f-'
-J
0 .,.
Vl
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0
H,
w
-J -
Chain of
Custody Record
Temperature on Receipt __ _ Test America
TAL-4124 (1007)
Drinking Water? Yes□ No~ THE LEADER IN ENVIRON.MENTAL TESTING
CIHJnl PmjsctManager fia.o '\" ~lt\N\'"" S~'.'i-\I,\,, \I. P/if,h-T
A&:tm.s:s TeMphone Numbsr (An;ia Code)IFax Num/Jt!Jr
,.ob -rl-l•'-t> -~f ~12.-~1..I\-:Z.C.1• 't,~1-2. 1'1-'1S"ll.
City I Shlta I Z-tp Code Sile Contact Lab Contact
~tflolof p l'I \S'ID(. A. 111,1. 1/. l.,._'TO,
Profecl Nam,g and Location (State) ~. Conf8r/Wsybll/ Number
ltllU-"11 ..... !=<jUT A"~•~ /1._"-"" c,i;.~ ~T 1-p k'IE\. ; Con/nld;PU«:llas8 Orr/er;Ouo/8 No. Containers & ..
l>M.•Sloto -o'I I Metnx P/'8Sl1/'Vlllives ,J
sample I.D. No. and Oescn'ption ! l ~ ; iS •& Q
Date . Time ~ ~ ~ :. (Containers torsach sample may be combintJd on one liM) ~ "' t ~t ...
C.-II. A zhi.110 IO'IS l( 2. I 2.
C -1511, 2.IU1ho I'll(" ll l· I l.
C-'1$1 A r.hl4IO · l'IIS" )( z. I 2 . C.-11.\' 2 hi.lic:t 1300 )( '2. I '2.
C -Z'I g :z. hlol.., ·~~ 1' 1. :li 2..
l.-'111 A · t.htolic, Z.Oao l(. 2.. ' 1 1.
C-Z.7 6 2.111,1 .... 11"\-' 11. '2.. -J l..
C -1,7 A 2'1~1,0 1~0 '( '2.. I l
C-11~ Z.li<-ho \O'IO ll . ' I ~
c.-,o \', 2ll~h• l•lo 'II. 'Z.. I 2 I
""-ol<. ~IU.ltcr _ l'ISb 'II. 4 I 2.
••• • ~hi.to> ... l'ISo l( I\. I 't I ,-s1 ... so ·o I
Poss//Jlq Hazerd ldenlificallon
&I Non-Hsrsnf D FlammalJls □ Skinlm'l8nt 0 PolsonB
- ~ I Sample OisposaJ " □ Unknown □ Ro/um To Cl/m,t uu Oi$/X}s8/ By lBb □ ArchivsFor
"flimArotmd Tll'T18 Requited
0 24 Hour., 0 48 Houts
1. Rslinqui'f..:;By~====:!> >
2 Relinqwshed By
3. Rt1knquished By
Comments
0 7Days □ 1408ys □ 2108ys i;Q.Olher St 1\-,.,.H.b
Dais Tm,e
"" ., 11s-.i
Da/8 TH118
0818 Tims
DISTRIBIJTION: WHITE. Retvmed to Client with Report; CANARY -Stays with lfltl Sample; PINK -Field Copy - - -- --- --
QC Rsqwrsmsnts (Spscily)
1. RectJived By
- --
0818 CMino1c41 ;01 Ll11.l,o
la.bNumber
'111.-'1<-l -,cs!e Page \ of 2.
Analysis (Attacn list it
more space is nood8d)
V Special tnstlllCtfons/
/ Conditions of Receipt
/
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,~'-' I
I -~
J I I ~
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Montns
(A 199maybt1a~it samplssammtsimJd
longsr than t month)
Date
)
-- -- - -
-n
0
~ -J
0
,I>
Vl
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Vl
0
H,
---Chain of
Custody Record
TAL-4124 (1007)
Client
F\"-'> + ~.,..,. .... A,.._
'2.oo "t"'-'"!) '-"t
O!>' 'f.A t.111tlu,
'=iill " (AU 14 lf
Projtlcf N8me end l.ocetlon {Stats)
- --
it!t.lo•~
I S1818 I Zip Cod~
~I\-l~I°"
- - -- - - - - ----Temperature on Receipt __ _ Test America
Drinking Water? Yes □ No llil THE LEADER IN ENVIRONMENTAL TESTING
Project Manager O,,r, CA,;,147300 ~NIii-pl,l♦h.l 1.fi1,i to
Tt1/tlpllont.1 Number (Artlll CodtJ)IFu NumbtJr l.81JMHnJ;er
41t.-41.-'\-'241"1 •u1.-"L-l'\ -"{&°11. ~11--tb3 ·1..SS Page "l--of L
Sits Contact l81J Contact Analysis (Attach list If
/!, • l\lL'-v,. ,....:__,.. more space is needed)
Cenier/Wayt,1/1 NtnT!ber I ~I\, Nl &:. "4T /ll>ltlt#-/st,.1 . c.1..-$ Evttiri.i. i ~ell ~ Special Instructions/ Cont~ Cm/er/Quote No.
0 "1,oflo(I> -M I MatnX
Semple t.D. No. end Dsscnpfion Date Time (Containo,s tor saeh .sample may bs combined on one !inti) ~ l ~ ~
1'1·0'1 1.lu.lte o&,u ~
t;g -01 ?lw,11.,-c,q'IO K
c.-1~ A 1.f11tha !¢lo IC.
_)---1.,.,-
... ...... ..-~
<>.> -
......-i------
. ............---
-/JOSSiele Hazard ldentilication I Semple 0/SfXJSBI
(li Non-Hazatrt D Flammab/8 □ S/dnlm'l8nl □ PoisonB □ Unknown □ RBtvm To CPent
Tum Around runt, Rsqulrod
□ 24Hotns □ 48Hou,s □ ?Days □ 1-IDays □ 2/Days llil. 0/ller Sl ft¥Mf.l,
1. Reiir,quishtJd By
t',re.:; Oate T,me
z.11~110 ns-u
2. Re!inquish9d By Oa/8 r,,,,.
3. Relinquished By Oalrl Time
Containe,s & I Conditions of Receipt
PlllSetvatives _,
I i " I ; ~ ~ l~ ::; ..,
I I I I
2. -· 1. I
1-;. I I . i...-;:.. . l~ I ... i...-
v-, I -,
; i, ~t
I ~
. '<'/
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{A tee may /J8 assessud if samples 81"8 rr,14/ned (li D-.,SI By l.81> 0 An:hivoFor __ Monlhs longer than 1 mcnlh)
OC Roqu,mments (Specify/
I. Received By Oa/9 Time
' T,me
lo
Ost• r,..
l,J
-J
OISTRIBUT10N: WHITE· Rstumed to Client wtth Report: CANARY· Stays wft/J the Sample; PINK· ABld Copy
METHODS SUMMARY
C0B170457
PARAMETER
Dibenzodioxins and Dibenzofurans, HRGC/HRMS
Semivolatile Organics GCMS BNA 8270C
References:
ANALYTICAL
METHOD
SW846 8290
SW846 8270C
PREPARATION
METHOD
SW846 8290
SW846 ''Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods", Third Edition, November 1986 and its updates.
C0B170457 6
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SAMPLE SUMMARY
C0B170457
WO# SAMPLE# CLIENT SAMPLE ID
LVRNL 001 C-12A
LVRNN 002 C-15B
LVRNQ 003 C-28A
LVRNR 004 C-14B
LVRNO 005 C-29B
LVRN3 006 C-99A
LVRN6 007 C-27B
LVRN7 008 C-27A
LVRN9 009 C-13B
LVRPD 010 C-10B
LVRPE 011 PW-OlC
LVRPF 012 M-04
LVRPG 013 EB-01
LVRPH 014 C-14A
LVTNE 015 C-14A-F
NOTE (S) :
-The analytical results of the ~mples listed above are presented on the following pages.
• All calculations are perrormed before rounding to avold round-off errors in calculated results.
-Results noted as "ND" were not detected at or above the stated limit.
• This report must not be reproduced, except in full, without the written approval or the laboratory .
• Results for the following parameters are never reported on a dry weight basis: color, corrosivity, density, flashpoint, ignitability, layers, odor,
paint filter test. pH, porosity pressure, reactivity, redox potential, specific gravity, spot tests, solids, solubility, temperature, viscosity, and weight.
C0B170457 7
SAMPLED SAMP
DATE TIME
02/16/10 10: 4 5
02/16/10 14:40
02/16/10 14:15
02/16/10 13:00
02/16/10 13:50
02/16/10 20:00
02/16/10 13:40
02/16/10 12:40
02/16/10 10:40
02/16/10 11: 30
02/16/10 14:50
02/16/10 08:00
02/16/10 09:40
02/16/10 08:20
02/16/10 08:20
of 37
Field & Technical Services, LLC
Client Sample ID: C-12A
GC/MS Semivolatiles
Lot-Sample .... : C0B170457-001 Work Order # ••. : LVRNLlAA
Date Sampled ... : 02/16/10 Date Received .. : 02/17/10
Prep Date ...... : 02/18/10 Analysis Date .. : 02/19/10
Prep Batch f ... : 0049174 Analysis Time .. : 12:03
Dilution Factor: 1.01
Method ......... : SW846 8270C
REPORTING
PARAMETER RESULT LIMIT
Pentachlorophenol ND 1.0
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-d5 64 (23 -112)
Terphenyl-d14 51 I 10 -132)
2-Fluorobiphenyl 58 (19 -107)
2-Fluorophenol 57 (10 -111)
Phenol-d5 58 I 15 -112)
2,4,6-Tribromophenol 64 (16 -122)
COB170457 8
Matrix ......... : WATER
MS Run i ....... : 0 0 4 9 0 9 4
UNITS
ug/L
of 37
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Field & Technical Services, LLC
Client Sample ID: C-15B
GC/MS Semivolat.i.les
Lot-Sample I ... : C0B170457-002 Work Order t. .. : LVRNNlAA Matrix ......... : WATER
Date Sampled ... : 02/16/10 Date Received .. : 02/17/10 MS Run #. ...... : 0049094
Prep· Date ...... : 02/18/10 Analysis Date .. : 02/19/10
Prep Batch .... : 0049174 Analysis Time .. : 12:24
Dilution Factor: 1. 01
Method ......... : SW846 8270C
REPORTING
PARAMETER RESULT LIMIT UNITS
Pentachlorophenol ND 1.0 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 65 (23 -112)
Terphenyl-dl4 77 (10 -132)
2-Fluorobiphenyl 60 I 19 -107)
2-Fluorophenol 60 (10 -111)
Phenol-d5 61 (15 -112)
2,4,6-Tribromophenol 67 (16 -122)
COB170457 9 of 37
Field & Technical Services, LLC
Client Sample ID: C-28A
GC/MS Semivolatiles
Lot-Sample .... : C0B170457-003 Work Order .... : LVRNQlM
Date Sampled ... : 02/16/10 Date Received .. : 02/17/10
Prep Date ...... : 02/18/10 Analysis Date .. : 02/19/10
Prep Batch f ... : 0049174 Analysis Time .. : 12:45
Dilution Factor: 1. 0 6
Method ......... : SW846 8270C
REPORTING
PARAMETER RESULT LIMIT.
Pentachlorophenol ND 1.1
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 56 (23 -112)
Terphenyl-dl4 73 I 10 -132)
2-Fluorobiphenyl 54 (19 -107)
2-Fluorophenol 54 (10 -111)
Phenol-d5 56 (15 -112)
2,4,6-Tribromophenol 61 (16 -122)
COB170457 10
Matrix ......... : WATER
MS Run f ....... : 0049094
UNITS
ug/L
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Field & Technical Services, LLC
Lot-Sample t ... : COBl.70457-004
Date Sampled ... : 02/16/10
Prep Date ...... : 02/18/10
Prep Batch t ... : 0049174
Dilution Factor: 1.04
PARAMETER
Pentachlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribrornophenol
COB170457
Client Sample IO: C-14B
GC/MS Semivolatiles
Work Order t ... : LVRNRlAC
Date Received .. : 02/17/10
Analysis Date .. : 02/19/10
Analysis Time .. : 13:05
Method ......... : SW846 8270C
REPORTING
RESULT LIMIT
2.4 1.0
PERCENT RECOVERY
RECOVERY LIMITS
52 (23 -112)
42 ( 10 -132)
49 (19 -107)
48 I 10 -111)
50 I 15 -112)
55 (16 -122)
11
Matrix .... _ .... : WATER
MS Run #. ...... : 0049094
UNITS
ug/L
of 37
Field & Technical Services, LLC
Client Sample ID: C-29B
GC/MS Semivolatiles
Lot-Sample t. .. : C0B170457-005 Work Order t. .. : LVRN0lAC
Date Sampled ... : 02/16/10 Date Received._: 02/17 /10
Prep Date .... __ : 02/18/10 Analysis Date .. : 02/19/10
Prep Batch t ... : 0049174 Analysis Time._; 13:26
Dilution Factor: 0.94
Method ......... : SW846 8270C
REPORTING
PARAMETER RESULT LIMIT
Pentachlorophenol 11 0.94
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 61 (23 -112)
Terphenyl-dl4 56 (10 -132)
2-Fl uorobiphenyl 56 (19 -107)
2-Fluorophenol 53 (10 -111)
Phenol-d5 54 (15 -112)
2,4,6-Tribromophenol 68 (16 -122)
COB170457 12
Matrix. _______ .; WATER
MS Run# ....... : 0049094
UNITS
ug/L
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Field & Technical Services, LLC
Client Sample ID: C-99A
GC/MS Semivolatiles
Lot-Sample i ... : C0B170457-006 Work Order i. .. : LVRN31AC Matrix ......... : WATER
Date Sampled ... : 02/16/10 Date Received .. : 02/17/10 MS Run i. ...... : 0049094
Prep Date ...... : 02/18/10 Analysis Date .. : 02/19/10
Prep Batch i ... : 0049174 Analysis Time .. : 13:47
Dilution Factor: 0.98
Method ......... : SW846 8270C
REPORTING
PARAMETER RESULT LIMIT UNITS
Pentachlorophenol 11 0.98 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 62 (23 -112)
Terphenyl-d14 76 ( 10 -132)
2-Fluorobiphenyl 57 (19 -107)
2-Fluorophenol 56 (10 -111)
Phenol-d5 60 ( 15 -112)
2,4,6-Tribromophenol 65 (16 -122)
COB170457 13 of 37
Field & Technical Services, LLC
Client Sample ID: C-27B
GC/MS Sernivolatiles
Lot-Sample t ... : C0B170457-007 Work Order JI. .. : LVRN61AA
Date Sampled ... : 02/16/10 Date Received .. : 02/17/10
Prep Date ...... : 02/18/10 Analysis Date .. : 02/19/10
Prep Batch I.. - : 0049174 Analysis Time .. : 14:08
Dilution Factor: 0.99
Method ......... : SW84 6 8270C
REPORTING
PARAMETER RESULT LIMIT
Pentachlorophenol ND 0.99
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 65 (23 -112)
Terphenyl-d14 54 (10 -132 I
2-Fluorobiphenyl 61 (19 -107)
2-Fluorophenol 62 (10 -111)
Phenol-d5 62 (15 -112)
2,4,6-Tribromophenol 68 ( 16 -122)
C0B170457 14
Matrix ......... : WATER
MS Run JI. ...... : 004 9094
UNITS
ug/L
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Field & Technical Services, LLC
Client Sample ID: C-27A
GC/MS Semivolatiles
Lot-Sample .... : C0B170457-008 Work Order .... : LVRN71AA
Date Sampled ... : 02/16/10 Date Received .. : 02/17/10
Prep Date ...... : 02/18/10 Analysis Date .. : 02/19/10
Prep Batch .... : 0049174 Analysis Time .. : 14:29
Dilution Factor: 0.99
Method ......... : SW846 8270C
REPORTING
PARAMETER RESULT LIMIT
Pentachlorophenol ND 0.99
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-d5 63 (23 -112)
Terphenyl-dl4 57 I 10 -132 I
2-Fluorobiphenyl 59 I 19 -107)
2-Fluorophenol 61 (10 -111)
Phenol-d5 63 (15 -112)
2,4,6-Tribromophenol 65 (16 -122)
COB170457 15
Matrix ......... : WATER
MS Run #. ...... : 0049094
UNITS
ug/L
of .37
Field & Technical Services, LLC
Lot-Sample t ... : C0B170457-009
Date Sampled ... : 02/16/10
Prep Date ...... : 02/18/10
Prep Batch# ... : 0049174
Dilution Factor: 0.98
PARAMETER
Pentachlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
C0B170457
Client Sample ID: C-13B
GC/MS Semivolatiles
Work Order# ... : LVRN91AA
Date Received .. : 02/17/10
Analysis Date .. : 02/19/10
Analysis Time .. : 14:50
Method ......... : SW846 8270C
REPORTING
RESULT LIMIT
ND 0.98
PERCENT. RECOVERY
RECOVERY LIMITS
66 (23 -112)
83 (10 -132)
62 (19 -107)
63 (10 -111)
63 (15 -112)
70 ( 16 -122)
16
Matrix ......... : WATER
MS Run f. ...... : 0049094
UNITS
ug/L
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Lot-Sample I. - - : COBl 70457-010
Date Sampled ... : 02/16/10
Prep Date ...... : 02/18/10
Prep Batch i ... : 0049174
Dilution Factor: ·o. 97
PARAMETER
Pentachlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
1• C0B170457
Client Sample ID: C-10B
GC/MS Semivolatiles
Work Order ff. - - :
LVRPDlAA
Date Received .. : 02/17/10
Analysis Date .. : 02/19/10
Analysis Time .. : 15: 11
Method ......... : SW846 8270C
REPORTING
RESULT LIMIT
ND 0. 97
PERCENT RECOVERY
RECOVERY LIMITS
64 (23 -112)
54 (10 -132)
61 ( 19 -107)
58 ( 10 -111)
59 (15 -112)
70 (16 -122)
17
Matrix ......... : WATER
MS Run i. ...... : 0049094
UNITS
ug/L
of 37
Field & Technical Services, LLC
Client Sample ID: PW-0lC
GC/MS Semivolatiles
Lot-Sample ff. .. : COBl 70457-011 Work Order L .. : LVRPElAE
Date Sampled ... : 02/16/10 Date Received .. : 02/17/10
Prep Date ...... : 02/18/10 Analysis Date .. : 02/19/10
Prep Batch t ... : 0049174 Analysis Time .. : 15:32
Dilution Factor: 0. 96
Method ......... : SW846 8270C
REPORTING
PARAMETER RESULT LIMIT
Pentachlorophenol 38 0.96
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 57 (23 -112)
Terphenyl-dl4 50 (10 -132)
2-Fluorobiphenyl 54 (19 -107)
2-Fluorophenol 55 ( 10 -111)
Phenol-d5 56 (15 -112)
2,4,6-Tribromophenol 65 (16 -122)
COB170457 18
Matrix ......... : WATER
MS Run f. ...... : 004 9094
UNITS
ug/L
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Field & Technical Services, LLC
Lot-Sample .... : COB170457-012
Date Sampled ... : 02/16/10
Prep Date ...... : 02/18/10
Prep Batch t. .. : 0049174
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
Nitrobenzene-d5
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
COB170457
Client Sample ID: M-04
GC/MS Semivolatiles
Work Order .... : LVRPFlAC
Date Received. .. : 02/17/10
Analysis Date .. : 02/19/10
Analysis Time .. : 16:34
Method ......... : SW846 8270C
REPORTING
RESULT LIMIT
ND 1. 0
PERCENT RECOVERY
RECOVERY LIMITS
61 (23 -112)
27 I 10 -132)
54 (19 -107)
55 I 10 -111)
53 (15 -112)
60 (16 -122 I
19
Matrix ......... : WATER
MS Run t. ...... : 004 9094
UNITS
ug/L
of 37
Field & Technical Services, LLC
Lot-Sample# ... : C0B170457-013
Date Sampled ... : 02/16/10
Prep Date ...... : 02/18/10
Prep Batch# ... : 0049174
Dilution Factor: 0.99
PARAMETER
Pentachlorophenol
SURROGATE
Nitrobenzene-d5
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
C0B170457
Client Sample ID: EB-01
GC/MS Semivolatiles
Work Order JI ... : LVRPGlAC
Date Received .. : 02/17/10
Analysis Date .. : 02/19/10
Analysis Time .. : 16:55
Method ......... : SW846 8270C
REPORTING
RESULT LIMIT
ND 0.99
PERCENT RECOVERY
RECOVERY LIMITS
59 (23 -112)
57 (10 -132)
54 (19 -107)
56 (10 111)
58 (15 -112)
61 ( 16 -122)
20
Matrix ......... : WATER
MS Run f. ...... : 0049094
UNITS
ug/L
of 37
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F.i.eld & Technical Services, LLC
Lot-Sample t ... : C0B170457-014
Date Sampled .. -: 02/16/10
Prep Date •••••• : 02/18/10
Prep Batch t ... : 0049174
Dilution Factor: 1. 04
PARAMETER
Pentachlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE(S):
Client Sample ID: C-l.4A
GC/MS Sem.ivolatiles
Work Order t. .. :
Date Received .. :
Analysis Date .. :
Analysis Time .. :
Method ......... :
RESULT
84 E
PERCENT
RECOVERY
73
48
66
67
68
79
LVRPHlAC
02/17/10
02/19/10
17:16
SW846 8270C
REPORTING
LIMIT
LO
RECOVERY
LIMITS
(23 -112)
(10 -132)
( 19 -107)
(10 -111)
(15 -112)
(16 -122)
E Estimated result. Result concentration exceeds the calibration range.
COB170457 21
Matrix •.....•.. : WATER
MS Run f. ...... : 0049094
UNITS
ug/L
of 37
Field & Technical Services, LLC
Client Sample ID: C-14A
GC/MS Semivolatiles
Lot-Sample .... : C0B170457-014 Work Order #. .. : LVRPH2AC
Date Sampled ... : 02/16/10 Date Received .. : 02/17/10
Prep Date ...... : 02/18/10 Analysis Date .. : 02/19/10
Prep Batch .... : 0049174 Analysis Time .. : 17:58
Dilution Factor: 5.2
Method ......... : SW846 8270C
REPORTING
PARAMETER RESULT LIMIT
Pentachlorophenol 100 5.2
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-d5 76 (23 -112)
Terphenyl-dl4 55 (10 -132)
2-Fluorobiphenyl 77 (19 -107)
2-Fluorophenol 70 (10 -111)
Phenol-d5 76 (15 -112)
2,4,6-Tribromophenol 84 (16 -122)
COB170457 22
~
Matrix ......... : WATER
MS Run •....... : 0049094
UNITS
ug/L
of 37
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METHOD BLANK REPORT
GC/MS Semivolatiles
Client Lot f ... : COB170457 Work Order t ... : LVTQNlAA
MB Lot-Sample t: COB180000-174
Prep Date ...... : 02/18/10
Analysis Date .. : 02/19/10 Prep Batch i ... : 0049174
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-d14
2-Fluorobiphenyl
2-Fl uorophenol
Phenol-dS
2,4,6-Tribromophenol
NOTE(S):
RESULT
ND
PERCENT
RECOVERY
74
73
67
74
78
75
Calculations are performed before rounding to avoid round-off errors in calculated results.
COB170457
REPORTING
LIMIT
1.0
RECOVERY
LIMITS
(23 -112)
(10 -132)
( 19 -107)
(10 -111)
(15 -112)
(16 -122 I
23
Matrix ......... : WATER
Analysis Time .. : 11:22
UNITS METHOD
ug/L SW846 8270C
of 37
LABORATORY CONTROL SAMPLE EVALUATION REPORT
Client Lot t ... ; C0B170457
LCS Lot-Samplet: COBlS0000-174
Prep Date ...... : 02/18/10
Prep Batch JI ••• ; 0049174
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
Nitrobenzene-d5
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE (S) :
GC/MS Semivolatiles
Work Order t. .. ; LVTQNlAC
Analysis
Analysis
PERCENT
RECOVERY
74
Date .. : 02/19/10
Time .. : 11: 43
RECOVERY
LIMITS
(15 -111)
PERCENT
RECOVERY
77
75
71
80
78
82
Calculations are performed before rounding to avoid round-off errors in calculated results.
Bold print denotes control parameters
C0B170457 24
Matrix ••••••••• : WATER
METHOD
SW846 8270C
RECOVERY
LIMITS
(23 -112.)
(10 -132)
(19 -107)
(10 -111)
(15 -112)
(16 -122)
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MATRIX SPIKE SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot I ... : C0B170457 Work Order I ... : LVRPElAF-MS Matrix ••••••••• : WATER
MS Lot-Sample I: C0B170457-011
Date Sampled ... : 02/16/10
LVRPElAG-MSD
Date Received .. : 02/17/10
Analysis Date .. : 02/19/10
Analysis Ti.me .. : 15: 52
MS Run i. ...... : 004 9094
Prep Date ...... : 02/18/10
Prep Batch t ... : 0049174
Dilution Factor: 0. 98
PARAMETER
Pentachlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE(S):
PERCENT
RECOVERY
36
34
RECOVERY
LIMITS
(15 -111)
(15 -111)
PERCENT
RECOVERY
60
57
45
44
56
53
57
53
57
52
65
63
Calculations are performed before rounding to avoid round-off errors in calculated results.
Bold print denotes control parameters
COB170457 25
RPO
RPD LIMITS METHOD
SW846 8270C
1.1 (0-42) SW846 8270C
RECOVERY
LIMITS
(23 -112)
(23 -112)
(10 -132)
(10 -132)
I 19 -107 I
I 19 -107)
(10 -111)
(10 -111)
(15 -112)
(15 -112)
I 16 -122)
(16 -122)
of 37
Field & Technical Services, LLC
Client Sample ID: C-14B
Trace Level Organic Compounds
Lot-Sample t ... : C0B170457-004 Work Order# ... : LVRNRlM
Date Received .. : 02/17/10
Analysis Date .. : 02/19/10
Analysis Time .. : 21:08
Date Sampled ... : 02/16/10
Prep Date ...... : 02/18/10
Prep Batch I ... : 0049339
Dilution Factor: 0.95
DETECTION
PARAMETER RESULT LIMIT
2,3,7,8-TCDD ND 9.6
Total TCDD ND 9.6
1,2,3,7,8-PeCDD ND 48
Total PeCDD ND 48
1,2,3,4,7,8-HxCDD ND 48
1,2,3,6,7,8-HxCDD ND 48
1,2,3,7,8,9-HxCDD ND 48
Total HxCDD ND 48
1,2,3,4,6,7,8-HpCOD ND 48
Total HpCDD ND 48
OCDD 190 96
2,3,7,8-TCDF ND 9.6
Total TCDF ND 9.6
1,2,3,7,8-PeCOF ND 48
2,3,4, 7,8-PeCOF ND 48
Total PeCDF ND 48
1,2,3,4,7,8-HxCDF ND 48
1,2,3,6,7,8-HxCDF ND 48
2, 3, 4., 6, 7, 8-HxCDF ND 48
1,2,3,7,8,9-HxCDF ND 48
Total HxCDF ND 48
1,2,3,4,6,7,8-HpCDF ND 48
1,2,3,4,7,8,9-HpCDF ND 48
Total HpCDF ND 48
OCDF ND 96
PERCENT RECOVERY
INTERNAL STANDARDS RECOVERY LIMITS
13C-2,3,7,8-TCDD 77 (40 -135)
13C-1,2,3,7,8-PeCDD 86 I 4 o -135)
13C-1,2,3,6,7,8-HxCDD 88 I 40 -135)
13C-l,2,3,4,6,7,8-HpCDD 90 I 40 -135)
13C-OCDD 83 I 40 -135)
13C-2,3,7,8-TCDF 69 I 40 -135)
13C-l,2,3,7,8-PeCDF 81-I 40 -135)
13C-1,2,3,4,7,8-HxCDF 88 I 40 -135)
13C-l,2,3,4,6,7,8-HpCDF 87 I 40 -135)
COB170457 26
Matrix ......... : WATER
MS Run ll ....... : 0049208
UNITS METHOD
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pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
of 37 I
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Field & Technical Services, LLC
Cl..ient Sample ID: C-29B
Trace Level Organic Compounds
Lot-Sample f. .. : C0B170457-005 Work Order .... : LVRNOlM
Date Sampled ... : 02/16/10 Date Received .. : 02/17 /10
Prep Date ...... : 02/18/10 Analysis Date .. : 02/19/10
Prep Batch .... : 0049339 Analysis Time .. : 21:50
Dilution Factor: 0. 95
DETECTION
PARAMETER RESULT LIMIT
2,3,7,8-TCDD ND 9.5
Total TCDD ND 9.5
1,2,3, 7,8-PeCDD ND 48
Total PeCDD ND 48
1,2,3,4,7,8-HxCDD ND 48
1,2,3,6,7,8-HxCDD ND 48
1,2,3, 7,8,9-HxCDD ND 48
Total HxCDD ND 48
1,2,3,4,6,7,8-HpCDD ND 48
,otal HpCDD ND 48
OCDD ND 95
2,3,7,8-TCDF ND 9.5
Total TCDF ND 9.5
1,2,3,7,8-PeCDF ND 48
2,3,4,7,8-PeCDF ND 48
Total PeCDF ND 48
1,2,3,4,7,8-HxCDF ND 48
1,2,3,6,7,8-HxCDF ND 48
2,3,4,6,7,8-HxCDF ND 48
1,2,3,7,8,9-HxCDF ND 48
Total HxCDF ND 48
1,2,3,4,6,7,8-HpCDF ND 48
1,2,3,4,7,8,9-HpCDF ND 48
Total HpCDF ND 48
OCDF ND 95
PERCENT RECOVERY
INTERNAL STANDARDS RECOVERY LIMITS
13C-2,3,7,8-TCDD 65 (40 -135)
13C-l,2,3,7,8-PeCDD 74 (40 -135)
13C-l,2,3,6,7,8-HxCDD 72 (40 -135)
13C-l,2,3,4,6,7,8-HpCDD 75 (40 -135)
13C-OCDD 75 I 40 -135)
13C-2,3,7,8-TCDF 59 I 40 -135)
13C-l,2,3,7,8-PeCDF 70 ( 40 -135)
13C-l,2,3,4, 7,8-HxCDF 72 I 40 -135)
13C-l,2,3,4,6,7,8-HpCDF 70 I 4 O -135)
COB170457 27
Matrix ......... : WATER
MS Run i ....... : 0049208
UNITS . METHOD
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 8290
of 37
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Field & Technical Services, LLC I
Client Sample ID: C-99A I Trace Level Organic Compounds
Lot-Sample I ... : C0B170457-006 Work Order i ... : LVRN31AA Matrix .... __ ... : WATER I Date Sampled ... : 02/16/10 Date Received .. : 02/17/10 MS Run f ....... : 0049208
Prep Date ...... : 02/18/10 Analysis Date .. : 02/19/10
Prep Batch f ... : 0049339 Analysis Time .. : 22:33 I Dilution Factor: 1.01
DETECTION
PARAMETER RESULT LIMIT UNITS METHOD I 2,3,7,8-TCDD ND 10 pg/L SW846 8290
Total TCDD ND 10 pg/L SW846 8290
1,2,3,7,8-PeCDD ND 51 pg/L SW846 8290 I Total PeCDD ND 51 pg/L SW846 82 90
1,2,3,4,7,8-HxCDD ND 51 pg/L SW846 82 90
1,2,3,6,7,8-HxCDD ND 51 pg/L SW846 8290
1,2,3,7,8,9-HxCDD ND 51 pg/L SW846 82 90 I Total HxCDD ND 51 pg/L SW846 82 90
1,2,3,4,6,7,8-HpCDD ND 51 pg/L SW846 8290
Total HpCDD ND 51 pg/L SW846 8290 I OCDD ND 100 pg/L SW846 82 90
2,3,7,8-TCDF ND 10 pg/L SW846 82 90
Total TCDF ND 10 pg/L SW846 82 90
1,2,3,7,8-PeCDF ND 51 pg/L SW846 8290 I 2,3,4,7,8-PeCDF ND 51 pg/L SW846 8290
Total PeCDF ND 51 pg/L SW846 8290
1,2,3,4,7,8-HxCDF ND 51 pg/L SW846 8290 I 1,2,3,6,7,8-HxCDF ND 51 pg/L SW846 8290
2,3,4,6,7,8-HxCDF ND 51 pg/L SW846 8290
1,2,3,7,8,9-HxCDF ND 51 pg/L SW846 8290
Total HxCDF ND 51 pg/L SW846 82 90 I 1,2,3,4,6,7,8-HpCDF ND 51 pg/L SW846 82 90
1,2,3,4,7,8,9-HpCDF ND 51 pg/L SW846 82 90
Total HpCDF ND 51 pg/L SW846 8290
OCDF ND 100 pg/L SW846 8290 I
PERCENT RECOVERY
INTERNAL STANDARDS RECOVERY LIMITS I 13C-2,3,7,8-TCDD 78 (40 -135)
13C-l,2,3,7,8-PeCDD 92 (40 -135)
13C-l,2,3,6,7,8-HxCDD 84 I 40 -135)
13C-l,2,3,4,6,7,8-HpCDD 88 I 40 -135) I 13C-OCDD 91 I 40 -135)
13C-2,3,7,8-TCDF 74 I 40 -135)
13C-l,2,3,7,8-PeCDF 85 I 40 -135) I 13C-l,2,3,4,7,8-HxCDF 87 I 40 -135)
13C-l,2,3,4,6,7,8-HpCDF 84 I 40 -135 I
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COB170457 28 of 37 I
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Field & Technical Services, LLC
Client Sample ID: PW-0lC
Trace Level Organic Compounds
Lot-Sample I ... : C0B170457-011 Work Order# ... : LVRPElM
Date Received .. : 02/17/10
Analysis Date .. : 02/19/10
Analysis Time .. : 23:15
Date Sampled ... : 02/16/10
Prep Date ...... : 02/18/10
Prep Batch I ... : 0049339
Dilution Factor: 0.96
DETECTION
PARAMETER RESULT LIMIT
2,3,7,8-TCDD ND 9.7
Total TCDD ND 9.7
1,2,3,7,8-PeCDD ND 48
Total PeCDD ND 48
1,2,3,4,7,8-HxCDD ND 48
1,2,3,6,7,8-HxCDD ND 48
1,2,3,7,8,9-HxCDD ND 48
Total HxCDD ND 48
1,2,3,4,6,7,8-HpCDD 150 48
Total HpCDD 260 48
OCDD 2200 97
2,3,7,8-TCDF ND 9.7
Total TCDF ND 9.7
1,2,3,7,8-PeCDF ND 48
2,3,4,7,8-PeCDF ND 48
Total PeCDF ND 48
1,2,3,4,7,8-HxCDF ND 48
1,2,3,6,7,8-HxCDF ND 48
2,3,4,6,7,8-HxCDF ND 48
1,2,3,7,8,9-HxCOF ND 48
Total HxCDF ND 48
1,2,3,4,6,7,8-HpCDF ND 48
1,2,3,4,7,8,9-HpCDF ND 48
Total HpCDF 62 48
OCDF 97 97
PERCENT RECOVERY
INTERNAL STANDARDS RECOVERY LIMITS
13C-2,3,7,8-TCDD 79 (40 -135)
13C-l,2,3,7,8-PeCDD 86 (40 -135)
13C-1,2,3,6,7,8-HxCDD 88 (40 -135)
13C-1,2,3,4,6,7,8-HpCDD 91 (40 -135)
13C-OCDD 96 ( 4 0 -135)
13C-2,3,7,8-TCDF 71 ( 40 -135)
13C-1,2,3,7,8-PeCDF 81 ( 40 -135)
13C-l,2,3,4, 7,8-HxCDF 88 (40 -135)
13C-l,2,3,4,6,7,8-HpCDF 84 (40 -135)
COB170457 29
Matrix .... ___ .. : WATER
MS Run# ....... : 0049208
UNITS METHOD
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
of 37
Field & Technical Services, LLC
Client Sample ID: M-04
Trace Level Organic Compounds
Lot-Sample .... : C0B170457-012 Work Order j/ ••• : LVRPFlAA
Date Sampled ... : 02/16/10 Date Received .. : 02/17/10
Prep Date ...... : 02/18/10 Analysis Date .. : 02/20/10
Prep Batch t ... : 0049339 Analysis Time .. : 01:22
Dilution Factor: 1.1
DETECTION
PARAMETER RESULT LIMIT
2,3,7,8-TCDD ND 11
Total TCDD ND 11
1,2,3,7,8-PeCDD ND 55
Total PeCDD ND 55
1,2,3,4,7,8-HxCDD ND 55
1,2,3,6,7,8-HxCDD ND 55
1,2,3,7,8,9-HxCDD ND 55
Total HxCDD ND 55
1,2,3,4,6,7,8-HpCDD 330 55
Total HpCDD 530 55
OCDD 3700 llO
2,3,7,8-TCDF ND 11
Total TCDF ND 11
1,2,3,7,8-PeCDF ND 55
2,3,4,7,8-PeCDF ND 55
Total PeCDF ND 55
1,2,31 4 1 7 1 8-HxCDF ND 55
1 1 2 1 3 1 6,7,8-HxCDF ND 55
2,3,4,6,7,8-Hx~DF ND 55
1,2 1 3,7 1 8 1 9-HxCDF ND 55
Total HxCDF ND 55
1,2,3,4,6,7,8-HpCDF 55 55
1,2,3,4,7,8,9-HpCDF ND 55
Total HpCDF 190 55
OCDF 160 llO
PERCENT RECOVERY
INTERNAL STANDARDS RECOVERY LIMITS
13C-2,3,7,8-TCDD 81 I 40 -135)
13C-l,2,3,7,8-PeCDD 86 I 40 -135)
lJC-1,2,3,61 7 1 8-HxCDD 91 I 40 -135)
13C-1,2,3,4,6,7,8-HpCDD 93 I 40 -135)
13C-OCDD 97 I 40 -135)
13C-2,3,7,8-TCDF 71 I 4 0 -135)
13C-l,2,3,7,8-PeCDF 79 I 40 -135)
13C-l,2,3,4,7,8-HxCDF 90 I 40 -135)
lJC-1,2,3,4 1 6 1 71 8-HpCDF 88 I 40 -135)
COB170457 30
Matrix ......... : WATER
MS Run JI. ...... : 0049208
UNITS METHOD
pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 8290
pg/L SW846 8290
of 37
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Field & Technical Services, LLC
Client Sample ID: EB-01
Trace Level Organic Compounds
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Lot-Sample t ... : C0B170457-013 Work Order •... : LVRPGlAA
Date Received .. : 02/17/10
Analysis Date .. : 02/20/10
Analysis Time .. : 02:04
Date Sampled ... : 02/16/10
Prep Date ...... : 02/18/10
Prep Batch# ... : 0049339
Dilution Factor: 0.99
DETECTION
PARAMETER RESULT LIMIT
2,3,7,8-TCDD ND 10
Total TCDD ND 10
1,2,3,7,8-PeCDD ND 50
Total PeCDD ND 50
1,2,3,4,7,8-HxCDD ND 50
1,2,3,6,7,8-HxCDD ND 50
1,2,3,7,8,9-HxCDD ND 50
Total HxCDD ND 50
1,2,3,4,6,7,8-HpCDD ND 50
Total HpCDD ND 50
OCDD ND 100
2,3,7,8-TCDF ND 10
Total TCDF ND 10
1,2,3,7,8-PeCDF ND 50
2,3,4,7,8-PeCDF ND 50
Total PeCDF ND 50
1,2,3,4,7,8-HxCDF ND 50
1,2,3,6,7,8-HxCDF ND 50
2,3,4,6,7,8-HxCDF ND 50
1,2,3,7,8,9-HxCDF ND 50
Total HxCDF ND 50
1,2,3,4,6,7,8-HpCDF ND 50
1,2,3,4,7,8,9-HpCDF ND 50
Total HpCDF ND 50
OCDF ND 100
PERCENT RECOVERY
INTERNAL STANDARDS RECOVERY LIMITS
13C-2,3,7,8-TCDD 86 (40 -135)
13C-l,2,3,7,8-PeCDD 92 (40 -135)
13C-l,2,3,6,7,8-HxCDD 91 (40 -135)
13C-1,2,3,4,6,7,8-HpCDD 95 (40 -135 I
13C-OCDD 91 (40 -135)
13C-2,3, 7,8-TCDF 76 I 40 -135)
13C-1,2,3,7,8-PeCDF 89 I 40 -135)
13C-l,2,3,4,7,8-HxCDF 91 I 40 -135)
13C-l,2,3,4,6,7,8-HpCDF 86 (40 -135)
1 • COBl 70457 31
Matrix ......... : WATER
MS Run f. ...... : 0049208
UNITS METHOD
pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 8290
pg/L SW846 8290
of 37
Field & Technical Services, LLC
Client Sample ID: C-14A
Trace Level Organic Compounds
Lot-Sample JI ... : C0B170457-014 Work Order t. .. : LVRPHlAA
Date Sampled ... : 02/16/10 Date Received .. : 02/17/10
Prep Date. -----: 02/18/10 Analysis Date .. : 02/20/10
Prep Batch JI ••• : 0049339 Analysis Time .. : 02: 4 6
Dilution Factor: 1.14
DETECTION
PARAMETER RESULT LIMIT
2,3,7,8-TCDD ND 11
Total TCDD ND 11
1,2,3,7,8-PeCDD ND 57
Total PeCDD ND 57
1,2,3,4,7,8-HxCDD ND 57
1,2,3,6,7,8-HxCDD ND 57
1,2,3,7,8,9-HxCDD ND 57
Total HxCDD ND 57
1,2,3,4,6,7,8-HpCDD 230 57
Total HpCDD 380 57
OCDD 1700 110
2,3,7,8-TCDF ND 11
Total TCDF ND 11
1,2,3,7,8-PeCDF ND 57
2,3,4,7,8-PeCDF ND 57
Total PeCDF ND 57
1,2,3,4,7,8-HxCDF ND 57
1,2,3,6,7,8-HxCDF ND 57
2,3,4,6,7,8-HxCDF ND 57
1,2,3,7,8,9-HxCDF ND 57
Total HxCDF ND 57
1,2,3,4,6,7,8-HpCDF ND 57
1,2,3,4,7,8,9-HpCDF ND 57
Total HpCDF 96 57
OCDF 130 110
PERCENT RECOVERY
INTERNAL STANDARDS RECOVERY LIMITS
13C-2,3,7,8-TCDD 77 I 40 -135)
13C-l,2,3,7,8-PeCDD 87 I 4 o -135)
13C-l,2,3,6,7,8-HxCDD 88 I 40 -135)
13C-l,2,3,4,6,7,8-HpCDD 88 I 4 O -135)
13C-OCDD 89 I 40 -135 I
13C-2,3,7,8-TCDF 71 I 4 O -135)
13C-l,2,3,7,8-PeCDF 82 I 40 -135)
13C-l,2,3,4,7,8-HxCDF 83 I 4 0 -135 I
13C-l,2,3,4,6,7,8-HpCDF 82 I 4 0 -135)
C0B170457 32
Matrix ......... : WATER
MS Run JI ....... : 0049208
UNITS METHOD
pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 82 90
. pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
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I Field & Technical Services, LLC
I Client Sample IO: C-14A-F
Trace Level Organic Compounds
I Lot-Sample I ... : C0B170457-015 Work Order 4J ..• : LVTNElAA
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Date Sampled ... : 02/16/10
Prep Date ...... : 02/18/10
Prep Batch t ... : 0049339
Dilution Factor: 1. 01
PARAMETER
2,3,7,8-TCDD
Total TCDO
1,2,3,7,8-PeCDD
Total PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
Total HxCDD
1,2,3,4,6,7,8-HpCDD
Total HpCDD
ocoo
2,3,7,8-TCDF
Total TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
Total PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
Total HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
Total HpCDF
OCDF
INTERNAL STANDARDS
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-1,2,3,4,7,8-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
1 • COBl 70457
Date Received .. : 02/17/10
Analysis Date .. : 02/20/10
Analysis Time .. : 03:29
DETECTION
RESULT LIMIT
NO 10
ND 10
ND 51
ND 51
ND 51
ND 51
NO 51
ND 51
· ND 51
ND 51
120 100
ND 10
ND 10
ND 51
ND 51
ND 51
ND 51
ND 51
ND 51
ND 51
ND 51
ND 51
ND 51
ND 51
ND 100
PERCENT RECOVERY
RECOVERY LIMITS
85 I 4 O -135)
93 I 4 O -135)
98 I 4 O -135)
102 (40 -135)
104 I 40 -135)
76 I 40 -135)
89 (40 -135)
93 I 40 -135)
99 I 40 -135)
33
Matrix ......... : WATER
MS Run i. ...... : 0049208
UNITS METHOD
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 82 90
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 82 90
of 37
METHOD BLANK REPORT
Trace Level Organic Compounds
Client Lot i ... : C0B170457 Work Order i ... : LVVL81AA
MB Lot-Sample i: G0B180000-339
Prep Date ...... : 02/18/10
Analysis Date .. : 02/19/10 Prep Batch i ... : 0049339
Dilution Factor: 1
PARAMETER
2,3,7,8-TCDD
Total TCDD
1,2,3,7,8-PeCDD
Total PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
Total HxCDD
1,2,3,4,6,7,8-HpCDD
Total HpCDD
OCDD
2,3,7,8-TCDF
Total TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
Total PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
Total HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
Total HpCDF
OCDF
INTERNAL STANDARDS
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
, 13C-1,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-1,2,3,4,6,7,8-HpCDF
NOTE(S):
RESULT
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
PERCENT
RECOVERY
80
93
95
104
97
70
87
88
87
Calculations are performed before rounding to avoid round-off errors in calculated results.
COB170457
DETECTION
LIMIT
10
10
50
50
50
50
50
50
50
50
100
10
10
50
50
50
50
50
50
50
50
50
50
50
100
RECOVERY
LIMITS
(40 -135)
(40 -135)
(40 -135)
( 40 -135)
(40 -135)
(40 -135)
( 40 -135)
(40 -135)
(40 -135)
34
UNITS
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
Matrix ......... : WATER
Analysis Time .. : 19:43
METHOD
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 82 90
SW846 82 90
SW846 82 90
SW846 82 90
SW846 8290
SW846 82 90
SW846 82 90
SW846 8290
SW846 82 90
SW846 8290
SW846 82 90
SW846 82 90
SW846 8290
SW846 8290
SW846 82 90
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
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LABORATORY CONTROL SAMPLE EVALUATION REPORT
Trace Level Organic Compounds
Client Lot i ... : C0B170457
LCS Lot-Samplei: G0B180000-339
Prep Date ...... : 02/18/10
Prep Batch i ... : 0049339
Dilution Factor: 1
PARAMETER
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
OCDF
INTERNAL STANDARD
13C-2,3,7,8-TCDD
13C-1,2,3,7,8-PeCDD
13C-1,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-1,2,3,4,7,8-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
NOTE(S):
Work Order# ... : LWL81AC
Analysis Date .. : 02/19/10
Analysis Time .. : 2 0: 2 6
PERCENT RECOVERY
RECOVERY LIMITS
103 (64 -142)
104 (71 -140)
107 (56 -146)
111 (73 -144)
101 (71 -151)
106 (78 -139)
108 (80 -132)
100 (71 -142)
105 (76 -135)
105 (74 -137)
114 (75 -131)
115 (76 -133)
118 (80 -137)
107 (77 -142)
106 (79 -133)
105 (83 -130)
94 (72 -140)
PERCENT
RECOVERY
81
91
92
89
93
72
86
85
85
Calculations are performed before rounding to avoid round-off errors in calculated results.
Bold print denotes control parameters
COB170457 35
Matrix ......... : WATER
METHOD
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
RECOVERY
LIMITS
( 40 -135)
I 40 -135)
I 40 -135)
I 40 -135)
I 4 O -135)
I 40 -135)
I 4 0 -135 I
I 4 0 -135)
(40 -135 I
of 37
MATRIX SPIKE SAMPLE EVALUATION REPORT
Trace Level Organic Compounds
Client Lot I ... : C0B170457 Work Order f ... : LVRPElAC-MS
MS Lot-Sample i: C0B170457-011 LVRPElAD-MSD
Date Received .. : 02/17/10
Analysis Date .. : 02/19/10
Analysis Time .. : 23:57
Date Sampled ... : 02/16/10
Prep Date ...... : 02/18/10
Prep Batch f ... : 0049339
Dilution Factor: 0.95
PARAMETER
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
OCDF
COB170457
PERCENT
RECOVERY
103
102
100
100
110
104
105
106
96
96
107
97
148 a
100
97
98
102
102
102
104
104
110
101
102
107
111
101
101
108
105
104
104
99
94
RECOVERY
LIMITS
(64 -142)
(64 -142)
(71 -140)
(71 -140)
(56 -146)
(56 -146)
(73 -144)
(73 -144)
(71 -151)
(71 -151)
(78 -139)
(78 -139)
(80 -132)
(80 -132)
(71 -142)
(71 -142)
(76 -135)
(76 -135)
(74 -137)
(74 -137)
(75 -131)
(75 -131)
(76 -133)
(76 -133)
(80 -137)
(80 -137)
(77 -142)
(77 -142)
(79 -133)
(79 -133)
(83 -130)
(83 -130)
(72 -140)
RPD
RPD LIMITS
1.2 (0-45)
0.41 (0-35)
5.8 (0-45)
0.51 (0-35)
0. 45 (0-36)
8.5. (0-28)
21 (0-26)
0. 48 (0-35)
0. 02 (0-33)
1.2 (0-39)
5. 9 (0-26)
0. 95 (0-32)
3.5 (0-28)
0. 02 (0-30)
2.6 (0-25)
0.19 (0-25)
(72 -140) 4.6 (0-35)
(Continued on next page)
36
Matrix ......... : WATER
MS Run# ....... : 0049208
METHOD
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
of 37
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MATRIX SPIKE SAMPLE EVALUATION REPORT
Trace Level Organic Compounds
Client Lott ... : C0B170457 Work Order f ... : LVRPElAC-MS Matrix ......... : WATER
MS Lot-Sample t: C0B170457-011 LVRPElAD-MSD
PERCENT RECOVERY
INTERNAL STANDARDS RECOVERY
13C-2,3,7,8-TCDD 80
78
13C-l,2,3,7,8-PeCDD 94
89
13C-l,2,3,6, 7,8-HxCDD 87
92
13C-l,2,3,4,6,7,8-HpCDD 95
94
13C-OCDD 98
98
13C-2,3,7,8-TCDF 74
72
13C-1,2,3,7,8-PeCDF 89
85
13C-1,2,3,4,7,8-HxCOF 87
88
13C-l,2,3,4,6,7,8-HpCDF 88
88
NOTE(S):
Calculations are performed before rounding to avoid round-off errors in calculated results.
Bold print denotes control parameters
a Spiked analyte recovery is outside stated control limits.
COB170457 37
LIMITS
(40 -135)
( 40 -135)
( 40 -135)
(40 -135)
· ( 40 -135)
( 40 -135)
( 40 -135)
I 40 -135)
I 40 -135)
I 40 -135)
I 4 0 -135)
I 4 0 -135)
I 40 -135)
I 40 -135)
(40 -135)
(40 -135)
( 40 -135)
( 40 -135)
of 37
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FTS,LLC
DATE: March 11, 2010
FROM: Kendra Chintella
SUBJECT: Raleigh GW
SAMPLE DELIVERY GROUP (SDG): C0B180543
SAMPLES: M-04-F
ANALYSES: Method 8290 (Dioxins/Furans)
LABORATORY: TestAmerica Laboratories, Inc.
The data contained in this SDG were evaluated with regard to the following parameters:
□ Data Completeness
Noncompliances: None
□
□
□
□
Holding Times
Noncompliances: None
Laboratory Blank Contamination
Noncompliances: None
Surrogate Recoveries
Noncompliances: None
Laboratory Control Sample
Noncompliances: None
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Test America
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
Raleigh, Morrisville
Lot II: C0Bl.80543
Angie Gatchie
Field and Technical Services,
TKSTAMERICA Ll\BORATORIBS, INC.
~ Veronica Bortot
Project Manager
Karch 8, 2010
TestAmerica Laboratories, Inc.
301 Alpha Drive Pittsburgh, PA 15238 tel [phone] fax [phone] www.testamerlcalnc.com
CObl80543 1 of 8
CASE NARRATIVE
Field and Technical Services
Lot# COB I 80543
Dioxins:
TestAmerica's West Sacramento laboratory performed the dioxin analysis. All results arc
included in the report.
CObl80543 2 of 8
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-n
0 t,
r'
CX)
0
lJ1
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CX)
-V\ ~
-----;-. ~. . . -·:: . . . .
Chain of
Custody Record
TAl-412 7 4 (100 I
C.V.nl
f1f\J) 1" tC¼I-.Jllt\~ t t'(\V\lfl
Add,...
~(.) .-tt,pS> A-of
c;,y I SIBie I Zip Codo
~If t~ tSIIII.
Projet;I_NameandLocation{StaJIJJ
-- --- -----Temperaturs on Receipt __ _ TestAmerica
Drinking Wal9r? Yes O No~ · T.HE LEADER IN ENVIRONMENTAL TESTING
. __ ,
0111, Chain o11c.;~ t7'l
...,~w1,c j),\l,t',<.T -2-1 ,il,o
Talaphane N111t1Nr (Area CoM)IFtu Numbitlf WINumbor
4 •t.-"11-'l-26'1• •-Hl--Ll'i-•p·,t p-I of I
5il6Contacr lAl>Cooract AnaJys/s (AttJJch 11st if
A --tt,u.. -I'-. t,\-1\L -more spacs ts nd/ll -IA,-,
CarrietJWaybill Numbor /
g.N,,l\ Ll'\.,K. . flf,U .-.. w Kf-'11~••"'"-C\.,1 €\,L\AIT 2<.>1., J::(!) t;,{. 11
I Speclsl Instructions/
Contlat:I/Purt:hllso Ord&r~ No.
6 Mi>!iluto -o'l• Matrix
Sampls J.D. No. ancl D9SCliption Date TITTie i l (Contam/1 lrx uch sampfB may be combinflCi on Qf18 /ine} ~ J
,...-oY-F l.lf)IIO 0'"130 )(
[_.,, .---
,,,..,. .,,.
-·~ .,,.
~ -__...,.,,,..,.
./"
_,.,/.
__...,.,,,..,.
·-,..ossiblt, Hazard lcJantilaliOn I ; BmJ 16 Dl5pogal ~-0 Flammable □ 5'inkrlmnt 0 PoisonB 0 Unkno>m D Rowm To C6snl
TumAIOIJnd Tune Rtiquued
D 24Hcurs O 4SHOU1'9 0 7 Days D 14 Days D 27 o..,, fie. Otho, S't,.....l\'-l'
2. Relinqulslled By
3. Rallnquished By . !Dalo
c»sTRIBUTlON: WHffE • Rt1tum<Ki 1.0 Client 11.,tt> RtJPOt1; CANAff'I • Suafs wdt1 the Samp1a; PINK. Fl6id C0py
ContaJne,s & Conditions of RBCelpl
Pnlservatives
l i i ~ ~!f J ..
I I I J"\·oY-F ~l
,,,..,. ...... I l'I l,,_. Ptqi:,.,-. ...... , J v
,,,..,. V I I
~ I
I._, I .
. ' 7 7
I ;:f'
J -~
, . .,,
I/ , J
I J
!ill DlsposoJ By t..,b D "'"""'° ""' __ Moo""'
(A fH may bS 8flasa$C/ if samples are 1'&181nod
tongtJr lhan t IT'IOflth)
OC Rsquin>m,ms (Spooty)
1. Recatvrl!!d 8y I Oats
1
rmie
2. Rec.dived By 'Dal~. !"'"'
3. Roce/l.lea By 1"""' 1
nme
-
PARAMETER
METHODS SUMMARY
C0B180543
ANALYTICAL
METHOD
PREPARATION
METHOD
Dibenzodioxins and Dibenzofurans, HRGC/HRMS SW846 8290 SW846 8290
References:
SW846
COb180543
''Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods", Third Edition, November 1986 and its updates.
4
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SAMPLE SUMMARY
C0B180543
WO# SAMPLE# CLIENT SAMPLE ID
LVVKF 001 M-04-F
NOTE(S):
-The a,alytica rerults of the Sc1T1ples liSIOO ctove a-e pre;e:ited on the following pa;;ies.
-All C3rula:ions ae pet"forma:::I baore rounding to a,,,oid round-Off e-rors in C3rulaed rerults.
-Rerults note:J as "ND" wEre not d!:ie::100 at or OCOVe the !tated limit.
-This report mus. not be rE9roduce.:l, ec:~ in full, withcut the writta1 ~CNi:I of the 1a:x:,raory.
-Res.lits for the following pmnlEia-sae ne..er reporta:l on a dry weight basis: cdor, corrosivity, demty, fla:tipoint, ignitblity, layers, o::lcr,
paint fi I \Er lei, pH, pcrnsi ty presrure, roo::t.ivi ty, redox potential, ~ fie gra.,i ty, ~ tes:s. rol ids, s:ol ubi lity, ta-rrpenture, vi ocosi ty, a"ld weight.
CObl80543 5
SAMPLED SAMP
DATE TIME
02/17/10 07:30
of 8
I
Field & Technical Services, LLC I
Client Sample ID: M-04-F
Trace Level Organic Compounds I
Lot-Sample t. .. : C0B180543-001 Work Order t. .. : LWKFlAA
Date Sampled ... : 02/17/10 Date Received .. : 02/18/10
Prep Date ...... : 02/24/10 Analysis Date .. : 03/01/10
Matrix ......... : WATER
MS Run # .•••••• : I
Prep Batch .... : 0055213 Analysis Time .. : 17:22
Dilution Factor: 1. 02 I
DETECTION
PARAMETER RESULT LIMIT UNITS METHOD
2,3,7,8-TCDD ND 10 pg/L SW846 8290
Total TCDD ND 10 pg/L SW846 82 90 I
1,2,3,7,8-PeCDD ND 51 pg/L SW846 82 90
Total PeCDD ND 51 pg/L SW846 8290
1,2,3,4,7,8-HxCDD ND 51 pg/L SW846 82 90 I
1,2,3,6,7,8-HxCDD ND 51 pg/L SW846 82 90
1,2,3,7,8,9-HxCDD ND 51 pg/L SW846 82 90
Total HxCDD ND 51 pg/L SW846 8290
1,2,3,4,6,7,8-HpCDD ND 51 pg/L SW846 8290 I
Total HpCDD ND 51 pg/L SW846 8290
OCDD 270 100 pg/L SW846 8290
2,3,7,8-TCDF ND 10 pg/L SW846 8290 I
Total TCDF ND 10 pg/L SW846 82 90
1,2,3,7,8-:PeCDF ND 51 pg/L SW846 82 90
2,3,4,7,8-PeCDF ND 51 pg/L SW846 82 90
Total PeCDF ND 51 pg/L SW846 8290 I
1,2,3,4,7,8-HxCDF ND 51 pg/L SW846 82 90
1,2,3,6,7,8-HxCDF ND 51 pg/L SW846 82 90
2,3,4,6,7,8-HxCDF ND 51 pg/L SW846 8290 I
1,2,3,7,8,9-HxCDF ND 51 pg/L SW846 8290
Total HxCDF ND 51 pg/L SW846 8290
1,2,3,4,6,7,8-HpCDF ND 51 pg/L SW846 8290
1,2,3,4,7,8,9-HpCDF ND 51 .pg/L SW846 8290 I
Total HpCDF ND 51 pg/L SW846 8290
OCDF ND 100 pg/L SW846 8290 I
PERCENT RECOVERY
INTERNAL STANDARDS RECOVERY LIMITS
13C-2,3,7,8-TCDD 77 (40 -135)
13C-l,2,3,7,8-PeCDD 64 (40 -135) I
13C-l,2,3,6,7,8-HxCDD 95 (40 -135)
13C-1,2,3,4,6,7,8-HpCDD 98 (40 -135)
13C-OCDD 87 (40 -135)
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13C-2,3,7,8-TCDF 78 (40 -135)
13C-l,2,3,7,8-PeCDF 75 (40 -135)
13C-l,2,3,4,7,8-HxCDF 88 (40 -135)
13C-l,2,3,4,6,7,8-HpCDF 92 (40 -135) I
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COb180543 6 of 8 I
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METHOD BLANK REPORT
Trace Level Organic Compounds
Client Lot i ... : C0B180543 Work Order i ... : LV1551M
MB Lot-Sample i: G0B240000-213
Prep Date ...... : 02/24/10
Analysis Date .. : 02/25/10 Prep Batch i ... : 0055213
Dilution Factor: 1
PARAMETER
2,3,7,8-TCDD
Total TCDD
1,2,3,7,8-PeCDD
Total PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
Total HxCDD
1,2,3,4,6,7,8-HpCDD
Total HpCDD
OCDD
2,3,7,8-TCDF
Total TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
Total PeCDF
1,2,3,4,7,8-HxCDF
1,2,-3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
Total HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
Total HpCDF
OCDF
INTERNAL STANDARDS
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
NOTE(S):
RESULT
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
PERCENT
RECOVERY
64
61
75
77
75
62
68
71
80
Ca'rulaionsae pa-formed b€1ore rounding to a,.,oid round-off a-rors in ca'rulatEd rerults.
COb180543
DETECTION
LIMIT
10
10
50
50
50
50
50
50
50
50
100
10
10
50
50
50
50
50
50
50
50
50
50
50
100
RECOVERY
LIMITS
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
7
UNITS
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
Matrix ......... : WATER
Analysis Time .. : 17:29
METHOD
SW846 8290
SW846 8290
SW846 8290
SW846 82 90
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 82 90
SW846 8290
SW846 8290
SW846 82 90
SW846 82 90
SW846 82 90
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 82 90
SW846 8290
of 8
LABORATORY CONTROL SAMPLE EVALUATION REPORT
Trace Level Organic Compounds
Client Lot f ... : C0B180543
LCS Lot-Samplef: G0B240000-213
Prep Date ...... : 02/24/10
Prep Batch# ... : 0055213
Dilution Factor: 1
PARAMETER
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDO
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
OCDF
INTERNAL STANDARD
13C-2,3,7,8-TCDD
13C-1,2,3,7,8-PeCDD
13C-1,2,3,6,7,8-HxCDD
13C-1,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-1,2,3,4,7,8-HxCDF
13C-1,2,3,4,6,7,8-HpCDF
NOTE(S):
Work Order t ... : LV1551AC
Analysis Date .. : 02/25/10
Analysis Time .. : 18:11
PERCENT RECOVERY
RECOVERY LIMITS
99 (64 -142)
101 (71 -140)
120 (56 -146)
101 (73 -144)
106 (71 -151)
103 (78 -139)
101 (80 -132)
98 (71 -142)
105 (76 -135)
106 (74 -137)
115 (75 -131)
112 (76 -133)
114 (80 -137)
116 (77 -142)
109 (79 -133)
100 (83 -130)
100 (72 -140)
PERCENT
RECOVERY
72
70
68
78
73
70
75
68
78
Ca'rula:ionsae performed before rounding to a,.,oid round-off a-rors in cirula:OO resits
Bold print denotes control paaneta-s
COb180543 8
Matrix •.•..•••• : WATER
METHOD
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
RECOVERY
LIMITS
I 4 O -135)
I 4 o -135)
( 4 0 -135)
I 4 O -135)
I 4 o -135)
I 4 o -135)
I 4 O -135)
I 4 o -135)
I 4 0 -135)
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2010 First Semi-Annual Groundwater Monitoring Report/or the
Former Koppers Company Site, Morrisville, North CaroHna
APPENDIXB
Summary of
Historical Groundwater Analytical Results
I)
FTS
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Analyte
PENTACHLOROPHENOL
1,2,3,4,6,7,8-HpCOD
1,2.3,4,6,7,8-HpCOF
1,2,3,4,7,8,9-HpCOF
1,2,3,4,7,8-HxCDD
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDD
1,2,3,6,7,8-HxCDF
1,2,3,7,8,9-HxCDD
1,2,3,7,8,S-HxCDF
1,2,3,7,8-PeCDD
1,2.3,7,8-PeCDF
2,3,4,6,7,8-HxCDF
2,3,4,7,8-PeCDF
2,3,7,8-TCDD
2,3,7,8-TCDF
OCDD
OCDF
TOTAL HPCDD
TOTAL HPCDF
TOTAL HXCOD
TOTAL HXCDF
TOTAL PECDD
TOTAL PECDF
TOTAL TCDD
TOTAL TCDF
Notu:
pg/L -picograms per liter
µg/L -micrograms per liter
NA indicates not applicab~
ROD
Unlu Ground-
water
Standard"
Sample Type:
,o/L
pg/I_ NA
pg/I_ NA
pg/I_ NA
pg/L NA
pg/L NA
pg/I_ NA
pg/L NA
pg/I_ NA
pg/I_ NA
pg/I_ NA
pg/I_ NA
pg/L NA
pg/I_ NA
pg/I_ NA
pg/I_ NA
pg/I_ NA
pg/I_ NA
pg/I_ NA
pg/L NA
pg/L NA
pg/I_ NA
pg/I_ NA
pg/I_ NA
pg/I_ NA
pg/I_ NA
6 indicates rompound was a!so deteded in Ille blank
D indicates compound was diluted
J indicat,n ,ntimated result
~ ~
N
1 U
U indicates compoond was analyzed /or. but llOt detected
"Record ol Decision Groundwater Cleanup Standard
DUP indicates Duplicate Sample
N indicatas Normal Sample
REA indicates sample was reanalyzed
-indicates not analyzed
Bold Font lndlcal11s detacUon
Red Font indicates e~caedance
a il
N
1 U
C-018
1 ~ ~ ~ ~ ; ~ ~ ,o • ; ; .,
N N N N N N N
1.1U 0.98 U 0.32 J 1.5 U 1 U 0.98 1.0 U "
20 U
1.6 U
1.7 U
2 U
1.6 u
2.2 u
1.6 u
2 U
1.7 u
34 u
1 6 u
1.7 u
1,6 u
1.6 u
1,2 u
360
7.9 U
29
3.7 U
2.2 u
1.7 u
3.4 u
19 u
1.6 U
1.2 U
~ a ' ; ; ; 9 8 e ' •
N N N N N
1 U 1 U 1 u 0.96 U 1 U
C-098
' ~
N
Appendix B
Historical Groundwater Sampling Analytical Results
Remedial Action Groundwater Monitoring Program
Former Koppers Company Site
Morrisville, North Carolina
C-10A
; s ~ I: 0 8 ' i e ' ' ~
Ma,--05 Mar-00 ; ., • ; ;
N DUP DUP N N oue N N N N N N
0.96 U 0.96 U 0.95 U 0.97 U 0.96 U 1 LI 1 u 1 u 1 u 0.96 U 1.2 U 0.96 U 0.97 U
~
C-108
I ~ 2 ~ a ~ ~ 2 2 ~ ~ " " 8 g 0 l § ~ i 1 ' i • il • 1 ~ ; S.0.00 ~ • ; ~ ., • ro ..
N N N N N oue N N N N N N N N N N N N N N N
0.97 U 1 u 1 u 1 u 1 u 1 u 1 u 1 u 1 u 1 u lU 1 u 0.95 U 0.98 U 1.6 ,, 0.95 U 0.3 J 0.96U 0.94 U 0.97 U
7.7 U 2 U 7.3 U 6.5 U ... u
5U 1,4 U 3.7 U 33 U <SU
6.1 U 0.85 U 2.7 U , u ... u
6.5 U 0.43 U , u 36 U "1U
"u 041 U ,au "u "1U
eu 0.6 U 1.8 U "u "1U
3.7 U 025 U 2.8 U 3.7 U "1U
5.2 U 048 U 1.8 U 2.7 U "1U
"u 0.34 U 1.4 U 2,5 U ... u
6.3 U 081 U 1.7 U OU "u
"u 0.28 U 1.6 U 4,6 U ... u
"u 0.45 U 1.2 U ' u ... u
4,6 U 0.45 U 0.57 U 5 U ... u
,u 0.33 U 1.5 U 1.3 u 9.6 U
2.5 U 0.24 U 0.18 U 1.5 U 9.6 U
" , 23 U '" ,,, 96U
1S u 1.3 U ,u 6.7 U 96U
7.9 U , u 7.3 U 6.5 U "1U
6.1 U "u 3.8 U 33 U "1U
6.5 U 06 U ,u 36 U "1U
"u 045 U 2.8 U "u "1U
6.3 U 0.81 U 1.7 U OU ... u
4,7 U 0.45 U 1.6 U 5 U "LI
,u 0.41 U 1.5 U 1.3 U 9.6 U
2.5 U 0.24 U 0.26 U 1.5 U 9.6U
1 of 6
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Analyte Units
ROO
Ground•
wat■r
Standard•
Sampl•Typ<1:
PENTACHLOROPHENOL
1,2.3,4,6,7.8-HpCDD
1,2,3,4,6,7,8-HpCOF
1,2,3,4, 7,8,9-HpCOF
1,2,3,4,7,8-HxCDD
1,2,3,4,7,8--H:<CDF
1,2,3,6,7,8-HxCDO
1,2,3,6,7,8-HxCDF
1,2,3,7,8,9-HxCDO
1,2,3, 7,8,9-HxCDF
1,2,3,7,8-PeCDD
1,2,3,7,8-PeCDF
2,3,4,6,7,8-HxCDF
2,3,4,7,8--PeCDF
2,3,7,8-TCDD
2,3,7,8--TCDF
ocoo
OCOF
TOTALHPCDD
TOTALHPCOF
TOTALHXCOD
TOTAL HXCOF
TOTAL PECOO
TOTAL PECOF
TOTAL TCOD
TOTAL TCDF
Notes:
pg/I.• picograms p8f l~er
f'9/L -micrograms per liter
NA indicates not applicable
,,g/L
pg/l NA
pg/l NA
pg/L NA
pg/l NA
pg/l NA
pg/L NA
pg/l NA
pg/l NA
pg/L NA
pg/l NA
pg/L NA
pg/L NA
pg/l NA
pg/l NA
pg/L NA
pg/l NA
pg/L NA
pg/L NA
pg/l NA
pg/l NA
pg/L NA
pg/l NA
pg/l NA
pg/L NA
pg/l NA
B indicates compound was also detected in ttia blank
D inch::ates compound was diluted
J indicates esumated result
U indicates compound was analyzed /Of, bu1. not dete
·Record ol Decision Groundwater Cleanup Standard
DUP indicates Duplicate Sample
N indicates Normal Sample
REA indk:ates sample was reanalyzed
-iOOicates not analyzed
Bold Font indicates detection
Red Font indicates exceedance
i
N
1 u
C-11B
9 8 8 ~ , 9 ; ~ ~ , i , ~ ., .• , ·" •
N N N N N N N N N
1 u 1 u 0.95 U 1 U 1 u 0.97 U 1 u 0.98 u 0.98 U
Appendix B
Historical Groundwater Sampling Analytical Results
Remedial Action Groundwater Monitoring Program
Former Koppers Company Site
Morrisville, North Carolina
C-12A
9 ~ • a i i 8 ~ ~ ~ a " ' i i • , • • Mar-08
N N N N N N N N N N N OUP
1 " 1 u 1 u 1 u 0.98 U 1.2 U .99 U 0.99 U 0.97 U 1 u 0.98 U 0.98 U
,.,.,,,
N OUP
0.96 U ,u
C-13B
8 a ~ i ~ '1 0 ~ ~ 9 0
i " " ~ 0 " i, :i • • , • • • ., .,
N N N N N N N N N N N N N
1 U 1 u 1 u 1 u 0.95 U 0.098 J 0.99 U 0.55 U 0.99 U 0.97 U 1 U 0.96 U 0.98 U
2of 6
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Analyte Units Ground-
Waler
Standard"
Sampl• Type:
PENTACHLOROPHENOL
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8-HpCOF
1,2,3,4,7,8,9-HpCOF
1,2.3,4,7,8-HxCOO
1,2.3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDD
1,2,3,6,7,8-HxCDF
1,2,3,7,8,9-HxCDO
1,2,3,7,8,9-HxCOF
1,2,3,7,S-PeCDO
1,2,3,7,8-PeCDF
2,3,4,6,7,8-HxCDF
2,3,4,7,8-PeCDF
2,3,7,8-TCOO
2.3,7,8-TCOF
OCDD
OCOF
TOTALHPCDD
TOTALHPCOF
TOTAL HXCOD
TOTAL HXCDF
TOTAL PECO□
TOTAL PECDF
TOTAL TCOD
TOTAL TCDF
Notas:
pgll -picograms per liter
µgit. -miaograms per liter
NA indica1es not appl~ble
,,~ 1
pg~ NA
pg~ NA
pg~ NA
pg~ NA
p~ NA
P9~ NA
pg~ NA -NA -NA -NA
pg/L NA
P9~ NA
pg~ NA
pg~ NA -NA
pg~ NA
pg~ NA
pg~ NA
pg~ NA
pg~ NA -NA
pg/L NA -NA
pg~ NA
pg~ NA
9 ndicates compoond W<IB a'SQ d!!lecled in the blank
D ,nchcates compound was diluted
J indicates estimated resut
U indicates compound was analyzed for. but not dete
"Reoord of Decision Groundwater Cleanup Standard
DUP mdicates Duplicate Sample
N indicates Normal Sample
REA indicates sample was reanalyzed
-indicates not an.alyzed
Bold Font indicates detection
Red Font indicates exceedance
8 ~ ~ J
N "
16 21
-2530
-537
-36.1
-22.4 J
-17.4 J
-138
-25.9 J
-70.2
-7.64 u
-11.1 J
-2.46 u
-20.4 J
-2.41 u
-2.13 u
-1.64 u
-23200 B
-1930
-3990
-1850
-481
-555
-11.1
-90.1
-2.13 u
-1.64 u
8 a 8 9 9 ' ; C p § • a a
N N N N N
3.6 U 4.4 1.4 180 D 96 D
-1100 -55 200
-97 -7.8 U 26 U
-15 u -0.98 U 4.3 u
-12 u -1.7 U 4.5 u
-,.3 u -1.5 U 3.2 U
-43 J -2.7 u 6.9 U
-7.3 U -1-' u 3.2 U
-77 -1.6 u 4.3 u
-8.6 UJ -1.6 u 3.6 U
-9.2 u -2.1 u 5.6 U
-7.2 u -1.4 u 3.6 U
-8.1 UJ -1.6 u 3.3 U
-7.1 u -1.3 u 3.6 u
-32 u -1.3 u 3.9 u
-3 U -0.94 U 2.8 u
-3900 -660 1200
-260 -56 J 84 J
-1400 -92 300
-240 -16 U 52
-180 -3 U 11 u
-26 U -2.1 u 7,5 u
-9.2 U -2.1 u 5.6 U
-7.2 U --1.5 u 3.6 u
-3.2 U -1.3 u 3.9 U
-3 U -0.94 U 2.8 U
C-14A
~ i i ~ ~ ~ ~ 9
~ . , ~ ., ., ., ~
" " N N N N " "
34 D 79 85 D 8.3 17 76 28 , .•
230 110 82 2300 210 1700 110 ,,
16 U 11 u 98 u 390 22 U 280 " u 9.3 U
1.6 u 2.7 U 1.6 u 50 J,U 3.1 u 11 u 2.4 u 1.9 U
2.1 u 3 U 2.8 U ,, u 2.6 U 11 u 1.6 u 1.2 U
1.2 u 2.5 U 2.1 u 14 u 4 U " u 1.8 u 0.9 U
7 U 3.8 U 5.2 U 86 56 u 47 J 4.4 u 2.7 U
1.1 u 24 u 1.8 U 8.2 U 2.3 u 13 U 1.2 U 0.57 U
9.2 u 2.8 U 4 U 52 6 U 18 U 3.1 u 4,6 U
1.2 u 3 U 2.2 U 0.98 U 2.2 U 16 U 1.4 u 0.69 U
1.6 u 4.5 U ,.8 u 10 U 3 U 9, u 2.3 U 1.9 U
1 u 3 U 2.1 u 1.3 U 1.7 u ,4 u 1.3 U 0 42 U
1.2 U 2.6 U 2.1 u 9.1 u 2 U 14 U 1.4 u 0.77 U
1 u 2.8 u 2.1 u 1.1 u 1.6 u , u 14 u 0.41 U
0.85 U 2.9 u 1.8 u 0.9 U 1.5 u 6.7 U 1 u 0 52 U
0.75 U 2.4 u 2.4 u 0.59 U 1.3 u , u 0.84 0 26 U
680 610 330 20000 920 16000 820 1'0
56 J 36 U 26 U 1800 76 J 1400 54J 14 U
300 160 110 3700 280 2700 170 ,,
32 22 U 12 U 1500 38 1100 34 28
9.4 u 6.6 U 5.2 U 270 11 u 110 7 U '2U
4,6 u 3.7 U 3.1 u 190 6.2 U 160 3.2 u 2.5 U
1.6 u 4.5 U 4.8 u 10 U 3 U 9.7 U 2.3 u 1.9 U
1 u 3 U 32 u 5.8 U 1.8 u 12 U 1.4 u 0 '8 U
0.91 u 2.9 u 1.8 u 1.4 U 1.5 u 6.7 U 1 u 0'2 u
0.75 u 2.4 u 2.4 u 0.59 U 1.3 u 7 U 0.84 0 33 U "
Appendix B
Historical Groundwater Sampling Analytical Results
Remedial Action Groundwater Monitoring Program
Former Koppers Company Sile
Morrisville, North Carolina
~ ~ g 0 0 g ~ 8 ~ a • • 9 C '-" • ~ ' ., ., ., ., " ., • § 3
N " N N F N N N N N N N
"" " " "' NA ., 1 u 15 8.9 D 12 1.4 1 u
" u ,. 9'U '" 51 u -150 - -10 U -6.2 U
3U 6.8 U 9'U s, u 51 u -34 - -4.4 u -2 U
u u 1.2 U 94U s, u 51 u -2.1 u ---4.7 U -0.97 U
u u 4,7 U 94U s, u 51 U -4.8 u - -5.1 u -1.5 u
"'u 0.57 U .. u s, u 51 U -32 u --5.7 U -11 u
0.38 U 3.8 U .. u ,, u 51 U -6.8 U --6 U -1.6 u
O.BS U 1.2 U 9'U s, u 51 U -2.4 u - -5.6 U --11 u
0.61 U 3.9 U .. u s, u 51 U -4.2 u - -5.3 U --1.4 u
0.27 U 0.32 U 94U s, u 51 U -3.3 U ·--6.7 --1,2 u
0.63 U 1.2 U .. u s, u 51 U -9.8 U ·--10 U -2.9 U
0.31 U 0.38 U .. u s, u 51 U -5 U - -2.3 U -1.6 u
0.71 u 1.8 U .. u s, u 51 U -3.3 U - -
6.3 --1.2 u
0.5 U 04 U .. u s, u 51 U -5.1 u - -2.3 U -1.6 u
0.43 U 1 U 19 U 11 U 10 U -4.1 u ---5.7 U --1.2 u
0.17 U 0.66 U 19 U 11 U 10 U -2.8 U - -3.2 U -1 u
"'u 120 500 U 1700 120 -1000 - -82 J -55 J
7.1 U 12 U 190U 13' 100 U -24 U - -9 u --6.6 u
13U ,. 9'U '" 51 U -220 - -10 U -6.2 u
6.3 U ,, u .. u " 51 u -34 - -4.7 U -2 U
1.1 U 16 U 9'U s, u 51 U -11 u - -6 U --1.6 U
0.85 U ''" .. u s, u 51 U -,.8 u ---6.7 U -1.2 U
0.63 U 1.2 U "1U s, u 51 U -9.8 U - -10 U -2.9 U
0.5 U 0.56 U 9'U s, u 51 U -5.1 u --2.3 U -1.6 u
043 U 1 U 19 U " u 10 U -4.1 u - -5.7 U -1.2 u
0.18 U 1.3 U 19 U " u 10 U -2.8 U - -3.2 U -1 u
~ ~ ; ~ 0 ' ;_ • ., " • Mar-04
N N N N N N OUP
1 u 1.2 1.1 0.96 U 6.4 11 10
-·-- - -18 U " u
-·-- - -4 U 3.2 u
- - - - -0.72 U 1.4 u
- - - - -1 u 1.5 u
- - - - -0.97 u 1.4 u
- - - - -0.97 u 1.5 u
---- - -0.95 u 13 u
- - - --· 0.93 U 1.4 u
-·-- - -1 u 1.4 u
-----1.1 u 1.8 u
- - - --0.7 U 1 u
- - - ---0.99 U 1.4 U
- - - ---0.71 u 1 u
- - - - -0.61 U 0.82 U
---- - -0.63 U 0.68 U
- - - - -170 130
- - - - -11 u 8.6 U
- - - - -28 18 U
- - - - -6.6 u 5.7 U
---- ---24 u 2 u
- - - - -1 u 1.4 U
- ----1.6 U 1.8 U
- -- - -0.79 U 1 u
- ----0.95 U 1.6 U
- - - ---0.63 U 0.68 U
C-148
' ~ 'l g ~ ; 8 0 % '-" • ~ ., " Seo-05 ., .M-06 ., =~, " i< ,,
N N N i OUP N N OUP N " CUP N N N N N ,., 0.97 1.5 1.6 3.1 2.2 1.5 1.5 3., 3.3 1.3 3.5 3.4 ,., ,.
15 U 4, u 6.4 U 6.3 U 11 u ,.1 u 6 U 4.3 U 5.9 U 4,1 U 4.5 U " u 3,J 51 U " u
3.5 U 2.1 u 2.3 U 2.3 U 7.2 U 3.2 U 3.8 u 2.3 u 2.4 U 1.6 U 1.9 U 6.3 U 9.2U 51 U " u
2.8 U 1.1 u 0.38 U 0.59 U 1.3 U 3.7 u 4.4 u 2 U 2.8 U 1.9 U 1.8 U 0.84 U 0.95U 51 U " u
3 U 3.6 U 0.64 U 0.58 U 1.8 U 7.8 u 9.5 u 2 U 3.3 U 1.6 U 1.2 U 0.85 U 1.7U 51 U "u
2.5 U 2.1 u 1.1 u 1.2 U 2 U 98 u 11 u 1.8 u 1.9 U 1.6 U 1.0 U 044 U 1.4 U 51 U " u
2J u 2.8 u 0.59 U 0.61 u 1,6 u 6.9 U 8.5 U 1,9 u "u 1.7 u 1.0 U 095 U 2.1 U 51 U 48 U
2.3 U 1.8 u 0.54 u 0.5 U 1.2 u 8.9 u 99 u 1.1 u 1.8 U 1.5 U 0.78 U 0.42 U 1.7U 51 U "u
2.7 u 2.9 u 0.57 U 0.52 u 1.5 U 6.8 u 8.4 u 1,8 u 2.7 U "u 0.94 U 0.98 U 1.8U 51 U 48 U
2.9 u 2.2 u 0.63 U 0.57 u 1.4 U 11 u 12 U 2.2 U 1.9 U 1.7 u 1.1 U 045 U 0.93U 51 U "u
4.4 u 5.3 u 0.74 U 0.91 U 2.6 U 8.9 U 8.1 u 1.9 U 3.4 U 2.7 U 1.2 U 0.63 U 0.78U 51 U "u
3 U 2.8 u 0.54 U 0.58 U 1.4 u 5.6 U 5.3 U 11 u 1.9 U "u 0.42 U 0.48 U 0.84 U 51 U "u
2.6 U 2.1 u 058 U 0.53 U 1.4 u 10 U 11 u 1.6 u 1.9 U 1,6 U 0.91 U 0.46 U 1.1 U 51 U " u
2.9 U 2.9 U 0.53 U 0.56 U 1.4 u 5.3 U 5 U 1.2 u ,u 1.4 U 0.41 U 0.37 U 1 U 51 U " u
2.6 U 1.9 u 0.45 u1o.48 u 1 u 5 U 6 U 1 u 2.1 U \,2 U 0.40 U 022 U ,u 10U 9.6 U
2 U 3.3 U 0.48 U 0.48 U 0.74 6.4 U 7.4 U 0.93 U 1.2 U 24 U 0.38 U 0.14 U 0.43 U 10U 9.6 U
100 41 u 39 U 39 U 63 U 44 U 49 u 24 U "u "'u "'u "" 280 1BOU "" " u 5.1 u 3.6 U 3.8 U 9.8 U 9.7 U 17 u 5.3 U 8.5 U 5.3 U 3.2 U 20 U nu 100 U 00 U
15 u 4.7 u 6.4 U 6.3 U 11 u 4.7 u 6 U 4.3 u 5.9 U 6 U 4,5 U " u " 51 U " u
9 u 2.1 u 2.3 U 2.3 U 7.2 u 3.7 u 4.4 U 2.3 u 2.8 U 2.6 U 24U '3U HU 51 U "u
3 U 3.6 U 0.82 U 0.61 u 1.8 u 7.8 u 9.5 U 2 U 3,6 U uu 1.2 U 0.98 U 24U 51 U "u
2.9 u 2.2 U 1.1 u 1.2 U 2 U 11 u 12 U 2.2 U 1.9 U 1.7 U 1.1 U 1.7 U 2.8U 51 U "u
4.4 u 53 u 0.74 U 0.91 u 2.6 U 8.9 U 8.1 u 2.3 U 16 U 2.7 U 1.3 U 0.63 U 0.78 U 51 U " u
3 U 2.9 u 0,69 U;0.73 U 1.4 U 8.2 U 9 U 1.2 U 58 U 22 U 0 57 U 0.48 U 1 U 51 U '" u
2.6 U 1.9 u 0.45 U 0.48 U 1 u 5 U 6 U 1 u 23 U "u 0.53 U 023 U 1 U 10U 9.6 U
2 U 3.3 U 0.48 U 0.48 U 0.74 6.4 U 7.4 U 0.93 U 1.2 U 24 U 0.38 U 0.19 U 0.43 U 10U 9.6 U "
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Analyte Units
ROD
Ground-
water
Standard"
Sampl• Type:
PENTACHLOROPHENOL
1,2,3.4,6,7,8-HpCDD
1,2,3,4,6,7,8-HpCOF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,7,8-HxCDD
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDD
1,2,3,6,7,8-HxCOF
1,2,3,7,8,9-HxCDD
1,2,3,7,8,9-HxCOF
1,2,3,7,8-PaCDD
1,2,3,7,8-PeCOF
2,3,4,6,7.8-HxCDF
2,3,4,7,8--PeCOF
2,3,7,8-TCOO
2,3,7,6-TCOF
OCDD
OCDF
TOTAL HPCDO
TOTAL HPCDF
TOTAL HXCDD
TOTAL HXCOF
TOTAL PECO□
TOTAL PECOF
TOTAL TCDD
TOTAL TCOF
Notn:
pg,\.. picograms per litar
µgA.. micrograms per liter
NA indicates nOI applicable
,.,
pglL NA ,., NA
pglL NA
pg/L NA
pg/L NA
pg/L NA
pg/L NA
pglL NA
pglL NA
pglL NA ,., NA
pglL NA ,., NA
pglL NA ,., NA
pglL NA
pg/L NA
pglL NA
pglL NA
pglL NA
pglL NA ,., NA
pglL NA
pg/L NA
pglL NA
B indicates compound was also detected in the blank
D indicates compouncl was diluted
J irv;Hcates estimated res.ult
U indicates compound was an.ily.:ed for. bul not Cele
"Record of Decision Groundwater Cleanup Standard
DUP indicates Duplicate Sample
N ind,cates Normal Sample
REA indicates sample was reanalyzed
-indicates not analyzed
Bold Font Indicates Cetitetion
Red F onc indicates exc"9dance
~ 9 a g
~ , .6 < ., .,
N N N N
' u ' u ' u ' u
C-158
, 5 a " ~ 0 ~ ; ~ ~ ~ .6 ~ 0 • ~ • Feb-06 ., ,, ,, ~ <
N N N N ou, N N N N N N N
1.1 U 0.99 U 0.95 U 0.97 U 0.99 U ' u 0.99 U 0.95 U 'u 1 u ' u ' u '
Historical Groundwater Sampling Analytical Results
Remedial Action Groundwater Monitoring Program
Former Koppers Company Site
Morrisville, North Carolina
C-27A
% g ' ~ I: ~ g 0 g g 9 a 1 , ' ~ , ' § ~ ;\ ., • < , , ; , , ;
N N N N N " " N " N " " "
u 1.1 U 0.97 U 0.1 u 0.99 U 0.99 U '" u ,u 0,99 U ' u ' u ' u ' u
C-278
g g
i ~ ~ •
" N N
0.96 U 0.44J 0.99 U '
C-28A
" " a ~ 1 0 ~ s 0 ~ ' ~ ; a • i 0
~ ;\ i i ~ ' i :, ~ , , , 0 " • , ,
N " " " " " N N N " " " " N " " N "
u 0.99 U 0.98 U 0.97 U 1.1 U p" u ' u ' u ' u 0.97 U 'u 0.98 U 0.98 u ' u 0.99 U 0.96 U 'u 1.1 U
4 of 6
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ROD
Analyte Units Ground•
water
Standard•
Sample Type:
PENTACHLOROPHENOL
1,2.3,4,6,7,8-HpCOD
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7 ,8,9-HpCDF
1,2,3,4,7,8-HxCDD
1,2,3,4,7,8-HxCDF
1,2,3,6, 7 ,8-HxCOD
1,2,3,6,7,8-HxCDF
1,2,3,7,8,9-HxCOO
1,2,3,7,8,9-HxCDF
1,2.3,7,8-PeCOD
1,2.3.7,8-PeCOF
2.3,4.6, 7 .8-HxCOF
2,3,4,7,8-PeCOF
2,3.7,8-TCDO
2.3,7,8-TCOF
OCDD
OCDF
TOTAL HPCOO
TOTAL HPCOF
TOTAL HXCDO
TOTALHXCDF
TOTAL PECDO
TOTALPECDF
TOTAL TCDD
TOTAL TCOF
Nclu:
pg/L -pi cog rams per liter
µg/1. -micrograms per lijer
NA iro:licates ncC applicable
µgil 1
pg/L NA
pgil NA
pgil NA
pg/L NA
pg/L NA
pg/L NA
pg/L NA
pg/L NA
pg/L NA
pg/L NA
pg/L NA
pg/L NA
pg/L NA
pg/L NA
pg/L NA
pg/L NA
pg/L NA
pg/L NA
pg/L NA
pg/L NA
pg/L NA
pg/L NA
pg/L NA
pg/L NA
pg/L NA
8 ,ndicates comprn.md was also detected in the blank
D indicates compo.md was diJuted
J indicates estimated result
U indicates compaund was analyzed for. but not dell!
·Racou of Decision Groundwater Cleanup Staro:lard
DUP indicates Duplicate Sample
N indicates Normal Sample
REA iro:lica!es sample was reanalyzed
-indicates 001 aNl/yzed
Bcld Fent indh;atu det9Ctlon
Red Foot indicates exceedance
Mar--00
N REA
9.3 110 D
- -
---
- -
- -
---
--
---
----
- -
- -
---
- -
- -
---
- -
- -
----
- -
- -
---·
---
- -
- -
- -
- -
i ~ ~ ~ 0 . , • •
N N N N
51 0 80 51 0 sa
98 u 344 -19 U
3.4 u 55.1 -6.4 u
3.1 u 6.68 u -1.9 u
4.8 u 14.5 J -4 u
3 U 2.25 U -4.1 u
4.6 U 15 J -46 u
2.2 U 2.39 U -4.1 u
4.2 u 4.23 U -' u
3.1 u 3.68 U --,.8
'-' u 2.18 U --4.8 U
4.1 u 2.24 u --5 U
3.1 u 256 u --,.5
4.2 u 2.19 u --5 U
3.2 u 1.21 u --1.8 U
2.2 u 0.819 U -2 U
"J 3650 B --200
65 u 249 --21 u
9.8 U 606 -19 u
3A u 245 --8.9 u
,.8 u "-' --4.6 u
3.1 u 62.4 --48 u
16 u 2.18 U --4.8 U ,., u 6.23 --5 U
3.2 u 1.21 u --1.6 U
22 u 0.819 U -2 U
~ ~ 0 0 I!. ~ • " ' ' • • 3 • Feb-03
N N N N N N N N DUP
56 D " 0 41 0 27 41 0 39 0 45 28 32
-4.2 u 14 U --12 u -9.4 U ---
-2.6 u 2J u --2.7 u --3.6 u ---
-28 u 1.5 u -· 1.5 U --1.2 u - -
-9.8 u 1.2 u --1.8 u -0.51 u ---
-3 U 0.88 U --1.1 u --0.79 u ---
-11 u 1.6 U --1.9 u --0.6 U ---
--2.9 U 0.47 U -1.1 u -1.1 u ---
-9.3 U 1.1 u --1.7 u -0.62 u ·---
·-3.7 u 0.57 U --1.2 u --0.48 u ·---
--3.8 U 2 U -2.7 u -1.6 u ----
-1.9 U 0.64 u -1.6 u -1.1 u ----
--3A u 0.52 u -1.2 u --1.1 u ---
--1.9 u 0.62 u -1.6 u -1.1 u - -
--1.8 u 0.82 u -1.4 u -0.81 ---
-1.7 u 0.97 u -1.1 u --1.1 UJ - -
--7.3 u 64 J --99 U --140 - -
-5.7 u 6.9 U -6.1 u -19 u - -
-4.2 u 14 U -12 U -22 u ---
--28 u 4.6 u -3.7 U -7.8 U - -
--11 u 1.6 u -2.2 u -1 u ---
--3.7 U 1.3 u --1.2 u --1.1 u ----
--4.3 u 3.3 u --27 u --1.6 u --
--3.1 u 1 u --1.8 u -1.1 u --
-1.8 u 0.82 u --1.4 u --0.81 ---
--1.7 u 0.97 u -· 1.1 u --1.1 UJ - -
Appendix B
Historical Groundwater Sampling Analytical Results
Remedial Action Groundwater Monitoring Program
Former Koppers Company Site
Morrisville, North Carolina
C-298
0 ~ 'l. 1 ~ 0 1 , I ~ ~ Mar-05 ~ Feb-06 a ,.,..1
N N N N N N DUP N N DUP N N DUP
31 0 36 34 0 51 0 38 18 0 15 0 20 12 -13 9 11
8.8 U -12 U 2.3 U 6.3 u 1.6 u 2.1 u 50 U 7.3 u 8.1 u 6.1 u 3.2 U 2.9 U
4 U -4.1 u 1.3 U 4.4 u 1.4 u 1.3 U 5.6 u 4.7 u ,.8 u 3.6 U 2 U 1.4 u
49 u -3.2 U 0.9 U 5.4 u 1.6 u 1.4 u 3.2 u 1.5 u '-' u 4.2 U 2.4 u 1.7 u ... u -2.9 U 1.2 U 5.7 U 4 U 3.8 u 5.2 U 2.2 U 2.8 U 8.5 U 1.7 u 1.6 U
35 u -2.5 U 1 u 4.8 U 2.3 U 2.2 U 2.6 U 1.4 U 1.9 u 11 u 1.3 u 1.1 u
4.5 u -3.1 u 1.2 U 5.1 u 3 u 2.9 U 4.2 U 2 U 2.5 u 7.6 U 1.6 u 1.5 u
3.4 u -2.5 U 1 u 4.5 U 2 U 1.9 U 2.4 U 1.2 u 1.7 U 10 U 1.2 u 1 u
42 u -2.8 U 1.1 u 5.3 U 3.2 U 3.1 u 4.5 U 1.9 u 2.4 U 7.5 U 1.6 u 1.4 u
3.9 u -3.1 u 1.1 u 5.7 U 2.4 U 2.3 U 3 U 1A u 2 U 13 U 1.4 u 1.2 u
6.2 U -3.9 U 1.5 U 11 u 5.1 u 4.9 u 4.6 u 3.9 u 3.2 U 9.7 U 2.1 u 2 U
4.2 u -2.9 U 0.83 U 7.9 U 2.5 U 2.7 u 2.6 U 2.3 u 1.6 U 6.2 U 1.3 u 1.2 u
3.6 U -2.8 u 1.1 u 5 U 2.3 U 2.2 u 2.6 U 1.4 u 1.9 U 12 U 1.4 U 1.2 u
4.2 U -2.9 u 0.84 U 7.6 U 2.6 U 2.7 U 2.5 U 2.2 u 1.5 U 5.9 U 1.3 U 1.2 u
4.5 u -2.2 u 0.73 U 3.4 u 1.7 u 2 U 2.8 U 1.1 u 1.3 U 7.7 U 1.2 u 0.91 u
3.3 U -1.9 u 0.67 U 4.2 u 2.5 u 2.3 U 1.5 U 0.89 U 1 u 2 U 0.77 U 0.7 U
30 U -180 43 U 31 u 7.5 u 22 U 220 53 U 76 u 62 JB 30 U 28 U
8.8 u -19 U 45 u 8 U 3.7 u '-' u 100 U 6.9 U 13 u 15 u 3.9 U '-4 u
8.8 u -18 U 6.3 U 6.3 U 1.6 u 2.1 u 57 7.3 U 8.2 u 6.1 u 3.2 u 3.3 U
4.9 U -7.4 u 2 U SA u 1.6 u 1.4 u 8 U 4.7 U ,.8 u 4.2 u 2.4 u 1.7 U
4.5 U -3.1 u 2.4 u 5.7 u 4 U 3.8 U 5.2 U 2.2 U 2.8 u 8.5 U 1.7 U 1.6 U
3.9 U -3.1 u 1.1 u 5.7 u 2.4 u 2.3 U 3 U 1.4 U 2 u 13 U 1.4 u 1.2 U
6.2 U -3.9 u 1.5 u 11 u 5.1 u 4.9 U ,.6 u 3.9 U 3.2 u 97 U 2.6 U 2.3 U
4.2 U -3 U 0.64 U 79 u 3 U 2.7 U 2.6 U 2.3 U 1.7 u 11 u 1.3 U 1.2 U
4.5 U -2.2 u 1.1 u 3.4 u 1.7 u 2 U 2.8 u 1.1 u 1.3 u 7.7 U 1.2 U 0.91 u
3.3 U -1.9 u 0.67 U 42 u 2.5 U 2.3 U 1.5 U 0.89 U 1 u 2 U 0.77 U 0.7 U
M-04
~ ~ g ~ a a ,, 0 9 9 0 0
' ~ ~ § J; J; 1 i , • • Oct~• Fet;.09 Seo·09 Feb-10 ' 0 ' .,
N N N DUP N DUP N DUP N DUP N N N N N N N N N N ' ,., 12 " " 7.6 7 6.1 9.9 11 11 1 u 1.1
"
1.1 12 1 u 0.97 U 1 " u 1 u ' 1U NA
2.8 U OU "u 3,9 U 3.7 U "u 49U 4'U " u 51 U - - - - - - ----"" 51 U
1.5 U 1.5 U 2.1 U 3 U 1.5 U 1.2 U 49U 47 U " u 51 U - - - ---- - --" 51 U
1.8 U 0.69 U 0.78 U 06-'U 0.57 U 026 U 49U '7U "' u 51 U --- - - - - -- -55 U 51 U
1.9 U 0.53 U 1.1 u "u 1.5 U 0.51 U 49U 47 U " u 51 U - - - - - - ----55 U 51 U
16 U 0.45 U 0 8-1 U 0 28 U 0.73 U 027 U '9U '7U " u 51 U --------- -- -55 U 51 u
"u 0.44 U 0.95 U 0 37 U 1,2 U 0.38 U '9U '7U ~8 U 51 U - - - -- - - - -55 U 51 u
1.5 U 029 U 0 9' U 0 26 U 0.44 U 0 29 U "u '7U " u 51 U - - - - -- -- -55 U 51 U
1.6 U 041 U 0.73 U 0 52 U 0.72 U 0.59 U '9U '7U " u 51 U ---- - --- - -55 U 51 u
1.7 U 0.39 U 0.77 U 029 U 0.3 U 0 22 U '9U '7U 4' u 51 U ------- - - - -55 U 51 u
25 U 0.48 U 0 61 U 0.55 U 0.93 U 1.1 U '9U '7U 4' u 51 U --- --- - - - -55 U 51 u
1.4 U 0 31 U 0.52 U 0 21 U 0.42 U 0.37 U '9U '7U " u 51 U --- - - - ----55 U 51 U
1.6 U 0.33 U 0,!,4 U 0 29 U 0.57 U 0 29 U 49U '7U " u 51 u -· --- - - - ----55 U 51 u
1.4 U 0.31 U 0 39 U 0.32 U o« u 0 39 U '9U '7U "' u 51 u - - - - - - ----55 U 51 U
1.1 U 028 U 0 58 U 0.16 U 1.1 U 'u 9.8 U 95U 9.5 U 10 U - - - - - - ----11 u 10 U
2.3 U 0.23 U 0.37 U 022 U 0.5 U 0.42 U 9.8 U 95 U ,:_5 U 10 U -- - - - - ----11 u 10 U
25 U " u 56 J " u "u ,eu 160 U 170U 95 U 100 U ---- - - - - --3700 270
3 U 2.2 U "u 7.3 U "u 2.8 U 9'U 95U ;,5 U 100 U - - - ---- ---1"' 100 U
2.8 U 4,7 U 4.9 U 4' u 38 U 3.3 U sou "u "u 51 u ----- ---- -- -530 51 U
1.8 U 16 U 3 U 3 U 1.5 U 1.9 U '9U "u " u 51 U ---- - -- - - -"" 51 U
1.9 U 0.53 U 1.1 U 0.52 U 1.5 U 0.77 U '9U '7U " u 51 U ---- ---- - - -55 U 51 U
1.7 U 0 45 U 09' U 0.62 U 0.73 U 0.59 U '9U '7U " u 51 U -------- - - -55 U 51 U
25 U 0 48 U 0.61 U 0.55 U 0.93 U 1.1 U 49U 47 U " u 51 u - -- - - - - - -55 U 51 U
2.3 U 0.31 U 0.52 U 0.32 U 0 55 U 0.44 U 49 U 47 U " u 51 u - - - - - - ----55 U 51 U
"u 0.38 U 0 58 U 0.27 U 1.1 U 1 U 9.8U 9.5 U 9.5 U 10 U --- ---- ----11 u 10 U
2.3 U 0.23 U 0.37 U 0.24 U 0.5 U 0.42 U 98U 9.5 U 95 U 10 U - - - - - - - - -11 u 10 U
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ROO
Analyte Units Ground-
water
Standard"
Mar--00
Sample Type: N
PENTACHLOROPHENOL "~ 1 36 OJ
1,2,3,4,6,7,B•HpCOD
1,2,3,4,6,7,8--HpCDF
t ,2,3.4 ,7,8,9-HpCDF
1.2.3.4.7,8-HxCDD
1.2.3.4,7.8-HxCOF
1,2,3,6,7.8-HxCOD
1.2,3,6, 7.8-HxCDF
1.2.3,7,8,9-HxCOD
1.2.3,7,8,9-HxCOF
1.2,3,7,8-PeCDD
1,2,3.7,8-PeCDF
2,3.4,6.7,8-HxCOF
2,3.4.7,8-PeCDF
2,3,7,8-TCDD
2,3.7.8-TCDF
OCDD
OCDF
TOTAL HPCDD
TOTAL HPCDF
TOTAL HXCDD
TOTAL HXCDF
TOTAL PECDD
TOTAL PECOF
TOTAL TCDD
TOTAL TCDF
Notes:
pgll... -picograms per liter
µg/L -micrograms per liter
NA indicates not applicable
pg~ NA
pg~ NA
pg;L NA
pg~ NA
"~ NA
psJL NA
"~ NA
pg~ NA
pg~ NA
pg~ NA
pg/L NA
pg~ NA
,,~ NA
pg;L NA
pg/L NA
pg~ NA
pg;L NA
pg~ NA
psJL NA
psJL NA
psfl NA
pg;L NA
pg~ NA
pg;L NA
pg;L NA
B indicates compound was also detected ,n the blank
D indicates compound was diluted
J indicates estimated result
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
U ind~tes compound was analyzed for. but not detected
"Record of Deasmn Groundwater Cleanup Standard
DUP indicates Duplicate Sample
N indicates Normal Sample
REA indjcates sample was reanalyzed
-indicates not analyzed
Bold Font indicates detection
Red Font indicates exceedance
OUP
50 D
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
i " Jun--00 Dec-00
N DUP N N DUP
20 OJ '2 OJ 30 16 DJ 14D
5.8 U 4.4 U 13.9 U - -
2.6 U ,., u 2.88 U - -
2.8 U 2.1 u 4.39 U - -
4.2 U ,.1 u 5 1 u - -
2.9 U 2.5 u 2 U - -
4.1 u 39 u 5.78 U - -
2.1 u 1.8 U 2.34 U - -
3.7 U 3.6 u 5.11 u - -
3 U 2.6 u 3.31 u - -
7.2 U 7A u 2.48 U - -
3.6 U 3.7 u 1.72 U - -
3 U 2.6 u 2 09 U - -
3.7 U 3.7 u 1.9 U - -
3.3 U 3.8 u 1.24 U - -
2 U 2.4 U 1.67 U --
8.9 U 7.3 u 69.2 B - -
5.4 U 5.7 u 7.7 U -~
5.8 U " u 13.9 U --
2.8 U 2.1 u 3.54 U - -
"u ,.1 u 5 33 U --
3 U 2.6 u 2.4 U - -
12 U 15 U 2 48 U --
,.1 u 3., u 181 u --
3.3 U 3.8 u 1.24 U - -
2 U 24 u 1.67 U - -
Qc\Pro1et1S\Bea,e< Pro1etts\Raleig~\Mon,tonngDA TA•Report1ng\G,oundwaler\Reports\Rep0,ts\Reoons lOtO\lSA 2010\AopendL< B\
Mar--01 Jun--01
N OUP N DUP
33 DJ 34 D 24 DJ 30 D
4.2 U " u - -
3.8 U " u - -
,.1 u 7.6 U - -
5.9 U 16 U - -
4.3 UJ 12 u - -
6.7 U 18 u - -
4.3 U 12 u - -
5.9 U 16 U - -
5 1 U3 14 UJ - -
11 u 7.7 U - -
5 U 5.9 U - -
4.8 UJ 13 UJ - -
5 UJ 5.9 U - -
5.6 U 5.3 U - -
5.8 U 4,3 U - -
97 U3 13 U - -
11 u 9.4 U - -
4,2 U 4,8 U - -
,.1 u 12 U --
67 u 18 U - -
5.1 u " u - -
11 u 7.7 U - -
5.6 u 9.7 U - -
5.6 u 5.3 u - -
5.8 U 4.3 U - -
Au --01 Dec--01
N DUP N DUP
35 D 29 D 27 DJ 2' D ,., u 2., u 9.9 U ,.2 u
1.3 U 0.76 U 1.8 U 2., u
1.3 U o.s u 2.2 U 2.5 U
1.7 U 1.4 U 0.67 U 3.5 U
1.6 U 1-3 U 0.85 U 3.1 u
1.8 U 1.5 U 0.9 U 3.9 U
1.5 U 1.3 U 0.54 U 2.9 U
1.6 U " u 0.62 u 3.5 U
1.7 U 14 u 0.65 U 3.5 U
2.6 U 2.2 u 17 U 5.5 U
1.3 U 12 U 0.85 U 3.2 U
1.6 U 1.4 U 06 U 3.2 U
1.3 U 1.1 u 0.85 U 3.2 U
1.3 U 1.5 U 0.61 u 2.3 U
0.96 U 0.89 U 1 u 1.8 U
17 U 7.6 U " u 15 U
3.6 U 1.8 U 5.2 U 4.8 U
2.1 u 2.1 u 99 U 4.2 U
1.3 U 0.8 U 3.7 U 2.5 U
1.8 U 1.5 U 1.1 u 3.9 U
1.7 U 1.4 U 0.85 U 3.5 U
2.6 U 2.2 U 2.5 U 5.5 U
1.3 U 1.5 U 0.97 U 3.7 U
13 U 1.5 U 1.4 U 2.3 U
0.96 U 0.89 U 1 u 18 U
Appendix B
Historical Groundwater Sampling Analytical Results
Remedial Action Groundwater Monitoring Program
Former Koppers Company Site
Morrisville, North Carolina
PW-01
Feb--02 Mav--02 Au --02 Dec-02 Feb-03 Jun--03
N DUP N OUP N DUP N DUP N DUP N DUP
4.2 D 7.6 '8 D 20 D 21 D '6 D 22 0 22 D 21 19 '7 D 17D
- -3.3 U 3.2 U --1.9 U 2.6 U --6.4 U 1., u
- -2.8 U 2 U - -2., u 2 U - -nu 5.6 u
- -3.2 U 2A u --0.79 U 0.81 u - -4.3 U 3.8 u
- -3.4 U 2.8 u - -0 89 U 0.57 U --'3U ,.1 u
- -2.5 U 2 U - -1.8 U 17 U --32 U ,.1 u
- -3.7 U 3.1 u --094 U 1.1 u - -4.5 U 4.3 U
- -2.5 U 2 U - -1.1 u 0 74 U - -3.1 u 29 U
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- -7.2 U ,.6 u - -1.6 U 1.4 U --6' u 5.6 U
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- -4.4 U 2.8 U - -0.94 U 0.93 U --" u 3.7 U
- -5.2 U 3 U - -0.59 UJ 0.93 UJ - -3.5 U 32 U
- -2.9 U 1.7 U - -1 U3 1 u - -2.1 u 2 1 u
- -" u 21 u - -8.7 U 78 u --16 U 15 U
- -4.4 U 3.5 u - -2.8 U 3.2 u - -10 U 9 U
- -3.3 U 3.2 u - -1.9 U 26 u - -" u 7.4 U
- -3.2 U 2.4 U - -2.1 u 2 U --4.7 U 5.6 U
- -3.7 U 31 u - -1.1 u 1.1 u - -4,5 U ,.3 u
- -2.7 U 2.2 u - -1.8 U 1.7 U - -3.5 u ,.1 u
- -7.2 U 6.4 U - -2.4 U 1.4 U - -6.2 u 5.6 U
- -5 U 2.8 U - -1 u 0.97 U - -3.5 U 3.7 u
- -5.2 U 3 U - -0.69 UJ 0.93 UJ - -3.5 U 3.2 u
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N DUP N DUP N DUP N DUP N N N N N N N N N N DUP N
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- -3.5 U ,.3 u 1.3 U 1.1 u 5.2 U 2.9 U 16 u 0.62 U 1.7 U 4,3 U 2 U 2.9 U 0.71 u 0.5 U 0.26 U "u ,eu ,a u
- -3 U 3.7 U 15 u 1.4 U 6.9 U 2.7 U 4,8 U 0.62 U 2.7 U 8.6 U 1A u 3 U 0.47 U 0.72 U 0.3 U "u "u " u
- -1.8 u 2.9 U 1A u 1.3 U 5.2 U 2.2 U 2.6 u 1.3 U 2 U 9.8 U 1.2 u 1.9 U 0.38 U 0.66 U 0.17 U "u "u " u
- -32 u ' u 1A u 1.3 U 6.2 U 2.4 U 3.7 u 0.57 U 2.5 U 7.7 U 1.3 U 3.2 U 0.39 U 0.4 U 0.43 U "u "u " u
- -18 u 2.8 u 1A u 1.3 U 4.9 U 2.1 u 2.2 u 0.54 U 1.8 U g u 1 u 1.8 U 03 U 0.69 U 0.24 U "u '8U " u
- -2.9 U 3.7 u 1.4 U 1.3 U 6' u 2.4 U ' u 0.56 U 2A u 7.6 U 1.3 U 2.4 U 0.36 U 12 U 0.24 U "u '8U " u
- -22 U 3.5 u 1.5 U 1.4 U 6.2 U 2.6 U V u 0.62 U 2.1 u 11 u 1.2 U 2 U 0.41 u 0.75 U 0.17 U "u "u " u
- -3.8 U 7A u 1.8 U 1.7 U 12 U 4.2 U 6.9 u 1 u 3.6 U 86 U 3.9 U 3.6 u 0.46 U 0.47 U 0.75 U "u "u " u
- -2.1 u ' u 1.1 u 1 u 8.2 U 2.9 U 3.1 u. 0.59 U 1.7 U 6 U 2.1 u 16 u 0.28 U 0.19 U 0.24 U "u "u " u
- -2 U 3.2 U 1.5 U 1.3 U 5.4 U 2.3 U 2.6 u 0.57 U 2 U 10 U 1.2 U 1.9 U 0.35 U 0.32 U 0.15 U "u "u " u
- -2.1 u ' u 1.1 u 1 u 7.9 U 2.8 U 3.1 u 0.58 U 1.6 U 5.7 U 2.2 U 1.7 U 0.38 U 0.2 U 0.26 U "u "u " u
- -2.2 u 3.2 u 0.87 U 0.75 U 3.5 U 2.5 U 2.6 u 0.57 U 1.3 U 5' u 0.86 U 2 u 0.32 U 0.24 U 0.91 u 9.6 U 9.6 U 9.7 U
- -1.4 U 19 u 0.84 U 0.7 U 4.4 U 1.9 U 34 u 0.58 U 0.95 U 7.3 U 0.88 U 1 u 0.25 U 0.095 U 0.52 U 9.6 U 9.6 U 9.7 U
--13 U 8.2 U 6.7 U 6.9 U 26 U 11 u 93 u 10 U 21 u " u 72 U 33 U " u 93 J 9.7 U 96 U 96U 2200
- -4.6 U 6.6 u 1.8 U 2.4 U 7.5 U 4.2 U 5.7 u 1A u 2.5 U 9.1 u 2.6 U 9.9 U 1.8 U 3.1 u 1 u 96 U 96 U 97
- -3.8 U 4.9 U 1.5 U 1.3 U 5.9 U 3.3 U 1.7 u 2.6 u 4.8 U "u 1.B U 4.8 U 4.2 U 12 U 1.9 U "u "u 260
- -3.5 U 4.3 U 1.3 U 1.1 u 5.2 U 2.9 U 16 u 19 U 3.3 U 4.3 U 2 U 2.9 U 1.7 U 3.3 u 0.5 U "u "u 62
- -32 U ' u 2 U 2.4 U 6.9 U 2.7 U '8 u 0.52 U 2.7 U 8.6 U 1.4 U 32 U 05' U ,.. u 0.64 U "u '8U " u
- -2.2 U 3.5 U 1.5 U 1.4 U 6.2 U 2.6 U 2.7 U 1 3 U 2.1 u 11 U 1.2 U 2 U 0,41 u 0.75 U 0.24 U "u "u " u
- -3.8 U 7.4 U 1.8 U 1.7 U 12 U 4.2 U 6.9 U 1 u 3.6 U 86 U 3.9 U 15 U 0.46 U 0.47 U 0.75 U "u "u " u
--2.5 U 4.9 U 1.1 u 1 u 8.2 U 2.9 U 4 2 l! 0.77 U 1.7 U 9.7 U 2.2 U 6.6 u 038 U 0.2 U 0.42 U "u '8U " u
- -2.2 U 3.2 U 0.87 U 0.75 U 9 U 2.5 U 2.6 U 0.57 U 1.3 U 5.4 U 0.86 U 3.2 u 0 46 U 0.31 u 0.91 u 9.6 U 9.6 U 9.7 U
- -1.4 U 1.9 U 0.84 U 0,7 U 8.4 U 1.9 U 3.4 U 0.58 U 0.95 U 7.3 U 0.88 U 1 u 0.25 U 0.12 u 0.52 U 9.6 U 9.6 U 9.7 U
6of 6