NCD003200383_20040316_Koppers Co. Inc._FRBCERCLA RA_Fourth Quarter 2003 Groundwater Monitoring Report-OCR

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The RETEC Group, Inc.
300 Baker Avenue, Suite 302
Concord, MA01742
6RETEC
March 16, 2004
Ms. Beverly Hudson
Remedial Project Manager
USEPA-Region IV
North Superfund Remedial Branch
Waste Management Division
61 Forsyth Street, S.W.
Atlanta, Georgia 30303-8960
RE: Fourth Quarter 2003 Groundwater Monitoring Report for the
Former Koppers Company Site, Morrisville, North Carolina
RETEC Project No.: BEAZ7-03624-l03
Dear Ms. Hudson:
[phone] Phone
[phone] Fax
www.retec.com
The RETEC Group, Inc. (RETEC), on behalfofBeazer East, Inc. (Beazer), hereby submits the
results of the fourth quarter 2003 grnundwater monitoring event at the former Koppers Company
Site in Morrisvil1~, North Carolina (Site). This report documents the field and laboratory results•·
of the groundwater monitoring event performed on December 15 through 17, 2003.
Groundwater Monitoring Program-Fourth Quarter 2003
Based on the requirements in the Proposed Remedial Action Groundwater Monitoring Program
(ThermoRetec, 1999), 1 the fourth quarter 2003 groundwater monitoring event included the
following:
• Gauging of 50 monitoring wells (Figure 1): 35 on-site wells and 15 oft~site wells
• Sampling of two on-site wells: C-298 and the pumping well PW-01
Although wells C-14A and M-04 were scheduled to be sampled in this event, RETEC field
personnel determined that the volume of water present in these wells was not sufficient to
generate a sample.
At the same time as the fourth quarter 2003 event, RETEC collected samples from 12 additional
wells for a Monitored Natural Attenuation (MNA) study, including samples for analysis of 2,4-
dichlorophenol and pentachlorophenol by the United States Environmental Protection Agency
(USEPA) Method 8270C-Select Ion Monitoring (SIM). RETEC will report the results of the
MNA sampling under separate cover.
Groundwater Elevation and Direction of Flow
Groundwater elevations for the A-, 8-, and C-zone wells, as measured on December 15, 2003, are
presented in Table I. The groundwater elevations presented in Table I were used to construct the
A-, 8-, and C-zone groundwater potentiometric surface maps shown in Figures 2 through 4.
1 ThcrmoRctec, 1999. Proposed Remedial Action Groundwater Monitoring Program. Prepared by ThcrmoRctec
Consulting Corporation. August, 1999.
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Ms. Beverly Hudson
March 16, 2004
Page 2
Historic groundwater elevations for wells C-0 I B and C-1 OB differ significantly from the historic
groundwater elevations in the other B-zone wells. These consistently different groundwater
elevations, in conjunction with the fact that these wells are 30 to 55 feet deeper than the
neighboring B-zone wells, indicate that wells C-0 I Band C-1 OB do not communicate with the rest
of the B-zone aquifer. Because of this lack of communication, wells C-018 and C-1 OB will
continue to be gauged, but will not be included in the data set used to construct the potentiometric
surface map for the B-zone (Figure 3).
Figures 2 and 3 show the cone of depression that exists around PW-01 and indicate that, outside
of the zone of influence, groundwater flow is generally to the northeast and south-southwest. The
high variability in the C-zone groundwater elevations indicate that these wells are screened tn
isolated fracture zones within the bedrock, as seen on Figure 4.
Phenolic Analytical Results
Each groundwater sample was analyzed for 2,4-dichlorophenol and pentachlorophenol using the
USEPA 8270C-SIM method. RETEC personnel validated the groundwater analytical results
and applied the necessary data qualifiers, as summarized in Table 2. A complete copy of the
laboratory analytical results and data evaluation report is provided in Appendix A. Table 2 also
includes a summary of the 2,4-dichlorophenol and pentachlorophenol results for the wells
sampled in the MNA program.
' The Record of Decision (ROD) for this Site requires that groundwater meet the following cleanup
standards:
• 20 micrograms per liter (µg/L) for 2,4-dichlorophenol
• 1 µg/L for pentachlorophenol
As shown in Table 2, pentachlorophenol was detected in groundwater sampled from wells C-29B
and PW-01. Both of these pentachlorophenol detections exceeded the cleanup standard of I
µg/L. However, 2,4-dichlorophenol was not detected in any of the samples analyzed during this
event.
As approved by the USEPA, a modification to the Groundwater Monitoring Program from a
quarterly to a semiannual basis (Bauer, R., 2004)2 was made, based on the stabilization of the
number of constituents detected in the groundwater sampled from this site (as well as the
concentration of those constituents). RETEC will begin to collect semiannual samples in the first
half of 2004. Under the revised program, 16 program wells will be sampled annually for 2,4-
dichlorophenol and pentachlorophenol in the first semiannual event of the year. Wells with 2,4-
dichlorophenol and pentachlorophenol detections above the cleanup criteria will be sampled for
2,4-dichlorophenol and pentachlorophenol in the second semiannual event. In addition, wells with
detections of pentachlorophenol above its cleanup criteria will be sampled semiannually for
dioxins and furans. For a given well, once the concentrations of 2,4-dichlorophenol and
pentachlorophenol meet the cleanup standards for four consecutive sampling events, that well
will move to the annual sampling program for 2,4-dichlorophenol and pentachlorophenol.
' -Bauer. R .. 2004. Letter to Beverly Hudson, US EPA, RE: Request for Modifications to the Groundwater Sampling
Program at the Former Koppers Company Site, Morrisville, North Carolina. December 17, 2003.
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Ms. Beverly Hudson
March 16, 2004
Page 3
Since pentachlorophenol was detected in groundwater sampled from wells C-29B and PW-0 I
above the cleanup standard, these wells will be sampled for 2,4-dichlorophenol and
pentachlorophenol as part of the first semiannual 2004 groundwater monitoring event. In
addition, pentachlorophenol was detected above its cleanup criteria in samples from well C-14B,
which was sampled under the MNA program. As a result, well C-14B will be sampled
semiannually for 2,4-dichlorophenol and pentachlorophenol until the results from four
consecutive sampling events are below the cleanup criteria. Therefore, all 16 program wells
(including C-29B and PW-01) will be sampled for 2,4-dichlorophenol and pentachlorophenol in
the first semiannual 2004 groundwater monitoring event.
Wells C-14A and M-04 were scheduled to be sampled in the fourth quarter 2003 event, but both
wells had an insufficient quantity of water to sample. For that reason, in the first semiannual 2004
groundwater monitoring event, RETEC will attempt to sample wells C-14A and M-04. Well C-
14A is now on the semiannual sampling schedule (because its last detection ofpentachlorophenol
in the second quarter of 2003 was above the cleanup standard), and M-04 is on the annual
sampling schedule.
Dioxin and Furan Analytical Results
Dioxin and furan sampling by USEPA Method 8290 occurs on a semiannual basis in a subset of
wells. The Groundwater Monitoring Program requires dioxin and furan samples be collected
semiannually from wells that had concentrations of pentachlorophenol at or above the specified
cleanup levels during the previous sampling event, or wells with two or more quarterly
pentachlorophenol detections in the previous four quarters. Therefore, the fourth quarter 2003
semiannual dioxin and ·furan sampling event included wells C-29B and PW-0 I. RETEC
personnel validated the groundwater analytical results and applied the necessary data qualifiers,
as summarized in Table 2. Table 3 shows the detected concentrations of dioxins and furans with
their calculated toxicity equivalent quotient (TEQ) concentration. The TEQ concentration is
calculated by multiplying the concentration of each dioxin or furan by its respective toxicity
equivalent factor. The resulting TEQ concentrations are then summed to determine the total
TEQ.
The ROD for this Site requires that groundwater meet the following cleanup standards:
• 30 picograms per liter (pg/L) for dioxins and furans
As presented in Tables 2 and 3, the dioxin OCDD was detected in groundwater sampled from
well C-29B. No dioxins or furans were detected in well PW-01. As shown in Table 3, the C-29B
TEQ was significantly lower than the associated cleanup standard.
Under the revised Groundwater Monitoring Program, dioxin and furan sampling will occur
semiannually from wells with pentachlorophenol detections above its cleanup standard.
Therefore, in the first semiannual 2004 sampling event wells C-14A, C-14B, C-29B and PW-01
will be sampled for dioxins and furans.
During the first semiannual sampling event of 2004, RETEC will also attempt to sample well C-
l 4A for dioxins and furans. This well is typically dry and has not supplied a sufficient sample
volume in the previous two monitoring events.
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Ms. Beverly Hudson
March 16, 2004
Page 4
Operational Summary
The groundwater extraction system is currently pumping at its optimum. The aquifer's low yield
will not support a pumping rate greater than 2 gallons per minute, nor will the low yield of the
aquifer support the "pulsing" of the system.
Quarterly review of the groundwater analytical results indicate that the concentrations of
constituents of interest are fluctuating in groundwater collected from four remaining wells with
groundwater impact (C-14A, C-14B, C-298, and PW-01). Monitoring will continue in order to
determine the rate at which the levels of impact are fluctuating.
If you have any questions regarding these results, please call Michael Helbling of Beazer at (412)
208-8858 or Rita Bauer at [phone].
Sincerely,
The RETEC Group, Inc.
8~ c:., µa-a
Stefanie D. Young
Environmental Scientist
Enclosure
The RETEC Group, Inc.
ter Monitoring Program Manager
cc: D. Mattison-North Carolina Department of Environment and Natural Resources
M. Helbling-Beazer East, Inc.
M. Westray-The RETEC Group, Inc.
F:\PROJECTS\03624\Rcports\Quarter!y\2003\4Q03 Report.doc
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Tables
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Table 1
Groundwater Elevations
Fourth Quarter 2003
Former Koppers Company Site
Morrisville, North Carolina
Top of Casing _ Depth to
Well ID Gauging Date Elevation Groundwater
A-Zone
C-01A 15-Dec-03
C-02A 15-Dec-03
C-03A 15-Dec-03
C-04A 15-Dec-03
C-05A 15-Dec-03
C-06A 15-Dec-03
C-07A 15-Dec-03
C-08A 15-Dec-03
C-09A 15-Dec-03
C-10A 15-Dec-03
C-11A 15-Dec-03
C-12A 15-Dec-03
C-13A 15-Dec-03
C-14A 15-Dec-03
C-15A 15-Dec-03
C-25A 15-Dec-03
C-26A 15-Dec-03
C-27A 15-Dec-03
C-28A 15-Dec-03
C-30A 15-Dec-03
C-31A 15-Dec-03
C-33A 15-Dec-03
M-04 15-Dec-03
B-Zone
C-018 15-Dec-03
C-028 15-Dec-03
C-038 15-Dec-03
C-098 15-Dec-03
C-108 15-Dec-03
C-118 15-Dec-03
C-128 15-Dec-03
C-138 15-Dec-03
C-148 15-Dec-03
C-158 15-Dec-03
C-258 15-Dec-03
C-268 15-Dec-03
C-278 15-Dec-03
C-288 15-Dec-03
C-298 15-Dec-03
C-338 15-Dec-03
C-348 15-Dec-03
C-Zone
C-09C 15-Dec-03
C-12C 15-Dec-03
C-16C 15-Dec-03
C-19C 15-Dec-03
C-20C 15-Dec-03
C-21C 15-Dec-03
C-22C 15-Dec-03
C-32C 15-Dec-03
C-33C 15-Dec-03
C-34C 15-Dec-03
Note:
msl = mean sea level
3/16/2004
F:\PROJECTS\03624\Reports\Quarter1y\2003\4Q-03Tables.xls
(feet msl) (feet)
383.06 21.70
380.76 23.40
380.21 14.60
385.31 16.01
386.59 15.51
383.90 11.43
374.30 9.04
376.34 26.97
372.98 10.43
373.88 19.67
363.28 9.03
375.00 15.87
367.31 9.87
371.13 28.85
357.08 2.71
365.52 16.15
382.12 11.75
372.10 20.00
372.40 13.05
379.11 22.37
379.98 16.61
354.37 7.81
368.83 15.07
383.35 98.68
381.72 9.93
380.69 17.38
374.76 17.72
373.58 68.89
363.28 9.88
375.75 14.44
367.02 6.85
371.66 27.92
357.62 0.67
364.85 15.01
382.21 26.18
372.01 37.37
373.07 5.15
369.00 34.49
352.84 6.92
376.31 10.33
374.34 11.46
376.11 68.03
368.37 16.38
365.84 10.85
378.17 23.13
361.04 31.39
355.24 3.48
368.88 21.67
353.54 11.95
376.39 11.28
Groundwater
Elevation
(feet msl)
361.36
357.36
365.61
369.30
371.08
372.47
365.26
349.37
362.55
354.21
354.25
3i;;~"'(.
357.44
342.28
354.37
349.37
370.37
352.10
359.35
356.74
363.37
346.56
353.76
284.67
371.79
363.31
357.04
304.69
353.40
361.31
360.17
343.74
356.95
349.84
356.03
334.64
367.92
334.51
345.92
365.98
362.88
308.08
351.99
354.99
355.04
329.65
351.76
347.21
341.59
365.11
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ROD Sample Location Sample Units
Date Groundwater Standard*
Method 8270C SIM
2,4-Dichlorophenol
Pentachlorophenol
Method 8290
1.2,3,4,6,7,8-HPCDD
1,2,3,4,6,7,8-HPCDF
1,2,3,4, 7,8,9-HPCDF
1,2,3,4,7,8-HXCDD
1,2,3,4,7,8-HXCDF
1,2,3,6, 7,8-HXCDD
1,2,3,6,7,8-HXCDF
1,2,3,7,8,9-HXCDD
1,2,3,7,8,9-HXCDF
1,2,3, 7,8-PECDD
1,2,3,7,8-PECDF
2,3,4,6,7,8-HXCDF
2,3,4,7,8-PECDF
2,3, 7,8-TCDD
2,3,7,8-TCDF
OCDD
OCDF
Total HPCDD
Total HPCDF
Total HXCDD
Total HXCDF
Total PECDD
Total PECDF
Total TCDD
Total TCDF
Notes:
pg/L = picograms per liter
µg/L = micrograms per liter
ua/L I
ua/L
pg/L
pg/L
pq/L
pail
pg/L
pg/L
pg/L
pg/L
pg/L
pail
pq/L
p91L
pg/L
PQ/L
pc/L
P{ L
P( L
pg/L
pail
p(/L
P\ L
P( L
pg/L
pg/L
pq/L
Bold values represent detections.
DUP indicates duplicate sample.
D indicates result is from a secondary dilution.
J indicates estimated result.
NA indicates not applicable.
NS indicates not sampled.
RB indicates Rinse Blank
20
1
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
U indicates compound was analyzed for, but not detected.
*Record of Decision Groundwater Cleanup Standard
3/16/2004
F:\PROJECTS\03624\Reports\Quarterly\2003\40-03Tables.xls
C-01B C-09B
12/18/03 12/18/03
0.2 U · 0.21 U • I
0.32 J 1 U • I
NS NS
NS NS
NS NS
NS NS
NS NS
NS NS
NS NS
NS NS
NS NS
NS NS
NS NS
NS NS
NS NS
NS NS
NS NS
NS NS
NS NS
NS NS
NS NS
NS NS
NS NS
NS NS
NS NS
NS NS
NS NS
Table 2
Groundwater Sampling Analytical Results
Fourth Quarter 2003
Former Koppers Company Site
Morrisville, North Carolina
C-10A C-10B C-11B C-12A C-13B
12/16/03 12/16/03 12/17/03 12/16/03 12/16/03
0.24 U 0.21 U • o.a u · I 0.23 u · I 0.21 U •
1.2 U 1 U 1 U 1.2 U 0.098 J ·
NS NS NS NS NS
NS NS NS NS NS
NS NS NS NS NS
NS NS NS NS NS
NS NS NS NS NS
NS NS NS NS NS
NS NS NS NS NS
NS NS NS NS NS
NS NS NS NS NS
NS NS NS NS NS
NS NS NS NS NS
NS NS NS NS NS
NS NS NS NS NS
NS NS NS NS NS
NS NS NS NS NS
NS NS NS NS NS
NS NS NS NS NS
NS NS NS NS NS
NS NS NS NS NS
NS NS NS NS NS
NS NS NS NS NS
NS NS NS NS NS
NS NS NS NS NS
NS NS NS NS NS
NS NS NS NS NS
♦RETEC
PW-01 -
C-14B C-15B C-27A C-27B C-28A C-29B PW-01 DUP RB-01
12/16/03 12/17/03 12/16/03 12/16/03 12/17/03 12/16/03 12/17/03 12/17/03 12/15/03
0.21 U • 0.22 U· 0.21 U · 0.22 U, 0.21 U • 0.2 U • I 0.2 U • 0.2 U · 0.21 U•
6.4 1.1 U • 1.1 U · 0.44 J• 1 U 34 D · 15 J I 17 • I 1 U ,
NS NS NS NS NS 12 U 3.8 U 4.9 u 6.4 u
NS NS NS NS NS 4.1 u 2.9 U 3.7 U 4.2 U
NS NS NS NS NS 3.2 U 3.5 U 4.3 u 4.9 u
NS NS NS NS NS 2.9 u 3 U 3.7 U 4.7 U
NS NS NS NS NS 2.5 U 1.8 U 2.9 U 3.5 U
NS NS NS NS NS 3.1 u 3.2 U 4 U 5 U
NS NS NS NS NS 2.5 u 1.8 U 2.8 u 3.4 U
NS NS NS NS NS 2.8 U 2.9 U 3.7 u 4.6 U
NS NS NS NS NS 3.1 u 2.2 u 3.5 U 4.2 u
NS NS NS NS NS 3.9 u 3.8 U 7.4 U 6.9 U
NS NS NS NS NS 2.9 u 2.1 U 4 U 4.6 U
NS NS NS NS NS 2.8 u 2 U 3.2 U 3.9 U
NS NS NS NS NS 2.9 u 2.1 U 4 U 4.6 U
NS NS NS NS NS 2.2 u 2.2 U 3.2 u 3.1 U
NS NS NS NS NS 1.9 U 1.4 U 1.9 U 2.6 U
NS NS NS NS NS 180 . 13 U 8.2 U 7.7 U
NS NS NS NS NS 19 U 4.6 U 6.6 U 8.7 U
NS NS NS NS NS 18 U 3.8 U 4.9 U 6.4 U
NS NS NS NS NS 7.4 u 3.5 U 4.3 U 4.9 U
NS NS NS NS NS 3.1 u 3.2 u 4 U 5 U
NS NS NS NS NS 3.1 u 2.2 U 3.5 u 4.2 U
NS NS NS NS I NS 3.9 u 3.8 U 7.4 u 6.9 U
NS NS NS NS NS 3 U 2.5 u 4.9 U 4.6 U
NS NS NS NS NS 2.2 U 2.2 u 3.2 U 3.1 U
NS NS NS NS NS 1.9 U 1.4 U 1.9 U 2.6 U
1 ol 1
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Table 3 G,RETEC
Calculation of Toxicity Equivalent Quotients for Dioxins/Furans
Fourth Quarter 2003
Former Koppers Company Site
Morrisville, North Carolina
ROD C-29B PW-01
Analyte TEF Units Groundwater
Standard* Result TEQ Result
1,2,3,4,6,7,8-HPCDD 0.01 v/L
1,2,3,4,6,7,8-HPCDF 0.01 v/L
1,2,3,4,7,8,9-HPCDF 0.01 nn/L
1,2,3,4,7,8-HXCDD 0.1 nn/L
1,2,3,4,7,8-HXCDF 0.1 nn/L
1,2,3,6,7,8-HXCDD 0.1 n, /L
1,2,3,6,7,8-HXCDF 0.1 nn/L
1,2,3,7,8,9-HXCDD 0.1 pall
1,2,3,7,8,9-HXCDF 0.1 nn/L
1,2,3,7,8-PECDD 0.5 nn/L
1,2,3,7,8-PECDF 0.05 pa/L
2,3,4,6,7,8-HXCDF 0.1 nn/L
2,3,4,7,8-PECDF 0.5 nn/L
2,3,7,8-TCDD 1 nn/L
2,3,7,8-TCDF 0.1 nn/L
OCDD 0.001 n, /L
OCDF 0.001 "/L
Total HPCDD 0 nn/L
Total HPCDF 0 nn/L
Total HXCDD 0 nn/L
Total HXCDF 0 n, /L
Total PECDD 0 nn/L
Total PECDF 0 nn/L
Total TCDD 0 nn/L
Total TCDF 0 nn/L
Totals: I nn/L
Notes:
pg/L = picograms per liter
TEF = Toxicity Equivalent Factor
TEO= Toxicity Equivalent Quotient
Bold values represent detections.
DUP indicates duplicate sample.
J indicates estimated result.
NA indicates not applicable.
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
30
U indicates compound was analyzed for, but not detected.
12 U 0
4.1 U 0
3.2 U 0
2.9 U 0
2.5 u 0
3.1 U 0
2.5 u 0
2.8 U 0
3.1 U 0
3.9 U 0
2.9 U 0
2.8 U 0
2.9 U 0
2.2 U 0
1.9 U 0
180 0.18
19 U 0
18 U 0
7.4 U 0
3.1 U 0
3.1 U 0
3.9 U 0
3 U 0
2.2 U 0
1.9 U 0
I 0.18
Laboratory results that were U-qualified were assigned a value of O for this calculation.
*Record of Decision Groundwater Cleanup Standard
3/16/2004
F:\PROJECTS\03624\Reports\Quarterly\2003\4Q-03Tables.xls
3.8 U
2.9 U
3.5 U
3 U
1.8 U
3.2 U
1.8 U
2.9 U
2.2 U
3.8 U
2.1 U
2 U
2.1 U
2.2 U
1.4 U
13 U
4.6 U
3.8 U
3.5 U
3.2 U
2.2 U
3.8 U
2.5 U
2.2 U
1.4 U
.I
PW-01 -DUP
TEQ Result TEQ
0 4.9 U 0
0 3.7 U 0
0 4.3 U 0
0 3.7 U 0
0 2.9 U 0
0 4 U 0
0 2.8 U 0
0 3.7 U 0
0 3.5 U 0
0 7.4 U 0
0 4 U 0
0 3.2 U 0
0 4 U 0
0 3.2 U 0
0 1.9 U 0
0 8.2 U 0
0 6.6 U 0
0 4.9 U 0
0 4.3 U 0
0 4 U 0
0 3.5 U 0
0 7.4 U 0
0 4.9 U 0
0 3.2 U 0
0 1.9 U 0
0 0
1 of1
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BEAZER EAST, INC.
FORMER KOPPERS COMPAN1 Morrisville, NC (BEAZ7-03624-103)
DATE: 03/01 /04 ORWN: C.C./DM
/
7
200
LEGEND:
MONITORING WELL
PUMPING WELL
RAILROAD TRACKS
FENCELINE
DRAINAGE/STREAM
PROPERTY BOUNDARY -BEAZER
EAST, INC.
PROPERTY BOUNDARY -UNIT
STRUCTURES INC.
PROPERTY BOUNDARY -UNKNOWN
0 400
I""'\ w -SCALE: 1 "=400'
SITE MAP
FOURTH QUARTER 2003.
FIGURE 1 REVISION I A
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BEAZER EAST, INC.
FORMER KOPPERS COMPANY.
368.53
200
LEGEND:
MONITORING WELL
GROUNDWATER CONTOUR
GROUNDWATER ELEVATION
AT WELL (FEET MSL)
0 400
-w
I -SCALE: 1 H=400'
NOTE: WELLS GAUGED DECEMBER 15, 2003
A-ZONE GROUNDWATER CONTOURS
FOURTH QUARTER 2003 t.RETEC
i ~-----------------------------------------------------------------.EM~T~E~0~3~/~0~1/~D~•==])o~RWN~•~C~.C~./~D~M~==r:======1============□F~l@G~U~R~EJ2[:]),~~~s~1o~s~l~A~. Morrisville, NC {BEAZ7•03624-103)
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BEAZER EAST, INC.
FORMER KOPPERS COMPANY
Morrisville, NC (BEAZ?-03624-103)
0
7
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353.73
NOTES:
LEGEND:
MONITORING WELL
GROUNOWATER CONTOUR
INFERRED GROUNDWATER CONTOUR
GROUNDWATER ELEVATION
AT WELL (FEET MSL)
200
~
0
SCALE: 1 "=400'
400
WELLS C-018 AND C108 NOT USED IN CONTOURING.
WELLS GAUGED DECEMBER 15, 2003
/
8-ZONE GROUNDWATER CONTOURS
FOURTH QUARTER 2003
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I BEAZER EAST, INC.
FORMER KOPPERS COMPANY
Morrisville, NC (BEAZ?-03624-103)
DATE: 0J/01/04 I DRWN: C.C./DM I
CJ
LEGEND:
MONITORING WELL
INFERRED GROUNDWATER CONTOUR
353.73 GROUNDWATER ELEVATION
AT WELL (FEET MSL)
200 0 400
I
SCALE: 1 "=400'
NOTE: WELLS GAUGED DECEMBER 15, 2003
C-ZONE GROUNDWATER CONTOURS
FOURTH QUARTER 2003
I FIGURE 4 7 R<"'SION I A
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Appendix A
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Data Evaluation Report
Site: _B~azer/Balejgh __
Program/Event: CERCLA Groundwater Monitoring/Q4-03
Laboratory: Severn Trent Laboratories, Inc. -Pittsburgh and
West Sacramento
Laboratory Project Numbers: C3L200122, G3L160317,
G3L 180309
Analyses: Pentachlorophenol and 2,4-Dichlorophenol by SW-
846 Method 8270C SIM
Dioxins and Furans by SW-846 Method 8290
Evaluator: Gregory A. Malzone
Date: January 21, 2004
The Raleigh Q4-03 data reports from Severn Trent Laboratories, Inc. were evaluated
using the USEPA National Functional Guidelines and USEPA method specifications.
Each issue requiring comment and/or data qualification is addressed below. Qualified
results are listed in bolded text.
II
Sample Collection, Receipt, and Log-In
Sample Collection: Wells C-14A and M-04 were dry. Samples could not be
collected for these wells.
Sample Log-In: Sample collection records verified that the sample identified as
"M-28A" on chain-of-custody record 149354 was sample M-29B. The data
reports were revised to indicate sample M-29B.
Pentachlorophenol and 2,4-Dichlorophenol by SW-846 Method
8270C SIM
Dilutions/Reporting Limits: Sample C-29B was analyzed at a secondary three-fold
dilution to bring the pentachlorophenol concentration into the calibration range of
the instrument For this reason, the pentachlorophenol result from the original
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11
Beazer/Raleigh
Q4-03
Client Work Product
Private and Confidential
Ill
IV
analysis was qualified "E" by the laboratory. The pentachlorophenol result from
the secondary dilution was acceptable and must be used. 2,4-0ichlorophenol
should be reported from the original ana_lxsis.
Matrix Spike Recoveries: The PW-0 I MS/MSO recoveries for pentachlorophenol
were greater than the upper advisory limit of 140%. The positive
pentachlorophenol result for sample PW-01 was qualified "J," as and
estimated concentration, because of the high bias attributable to matrix
effects.
Dioxins and Furans by SW-846 Method 8290
No data quality issues were noted. No data qualifications were required.
Field Duplicate Samples
Samples PW-01 and OUP-01 were the primary and field duplicate samples
collected for this sampling event. No data qualifications are required based on
the relative percent difference (RPO) of field duplicate sample data alone.
However, the positive• results are presented in the table below to evaluate
precision and sample homogeneity. An RPO greater than the advisory limit of
30% is an indication of sample heterogeneity with respect to that compound, poor
field precision, and/or poor laboratory precision. Field and laboratory precision
were acceptable.
Parameter
Field Duplicate Comparison
Raleigh Q4-03
PW-01 DUP-01 RPD (%)
Pentachloroohenol 15 ua/L 17 11n/L 13
\\Retec-boston\USERSISYoung\Beazer\Raleiglz\Reports\2003 -4Q\RA_Q4-03.doc 2
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ANALYTICAL REPORT
PROJECT NO -BEAZER
Raleigh, Morrisville
Lot JI, C3L200l22
Gregory Malzone
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC -
veronica Bertot
Project" Manager
January 2, 2004
sn. Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238
STL
Tel, 412 820.8380 Fax, 412 820 2080
www.stl~inc.com
Severn Trent Laboratories, Inc.
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Morrisville
STL Lot# C3L200122
STL West Sacramento,-California received the samples on December 16, 2003. The
cooler _was received within the proper temperature range. The samples were then sent to
STL Pittsburgh. STL Pittsburgh received the samples on December 19, 2003. The
cooler was received within the proper temperature range.
If project specific QC was not required for samples contained m this report and batch QC
was completed on these samples, anomalous results will be discussed below.
GC/MS Semivolatiles SIM:
The reporting limits were adjusted according to the amount of sample extracted.
Due to the concentration of target compounds detected, sample C-28A was analyzed
undiluted and at a dilution. Both sets of result~·are reported.
The matrix spike and matrix spike duplicate recovered outside of the control limits for
pentachlorophenol.
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s
Ghflin of
C:ustody Record --~s,-L.--- -
Severn Trent Laboratories, Inc.
STL 4124 (0901)
Cfien( Project Manager Dille C/J,1111 nl Cu.'il!l<fV Nt1111be1
,gdc"'-? f?,et\ z,2.e_ R . 8<\.\,\0< 12/ l S/o7J 1 fl 1L3__5.J
Acldras,<; ~ li1 k vJ:\ 1./ ,;,-1 ' '.:Miic /LO
Telep/Jone Number {ltrea Godel/Fax Number lfl/; Nrm1/1cr
I 'G 7--z_ -\::._ \V:. '1/1 '--l'oc/-;)Joo 9/l,· J?-J-4?!,1 Page I of I
C/Jy IN~ I '121e-=r-r 3
Sile Con/acr 1/. CBn;~+ I/(, D:lh \ Annlysis (At/ilCh /isl ii
DL.\r \y::;c(V1 cJ , ,; f e.. v' e,ys. mo,e sl)ace 1s neecfed)
Projecl Name and Local/on (Stnte) Gamer.Waybill Number I ~ \ ,, ~ f, ~ 0601.1 · 03'o'l-~, oq I ~ 12 /a > Spec1r,I /11s/mcl,onsl
Contmc!IPurchase Order/0110/e No. Containers & <::-Conditions of Receipt
Matrix Preservatives
1& ~
Sample 1.0. No. and Description I ~ ' Dale Time Q 8 a u ;§ c; ti • ~ ~ (Cu11/a1nots /or each s,1mpla may be comhined on one fine) • ' J; § < 1 ~-' ~ ~ "''
C· 26A 1-z,,11:; /67, 1,ris 2 I 2 I x_ K_ (:;t,\..-\l.'.Jo 2,\::/
[:::>vv,o\ l'5lo
~l R,p 0/ /(c,CX:, C----
_LiS /5'1-o I
___t1jjl) 152o = -----·------···---------··-·· t)lJP Ol \ I/ ' I,, ' j r:r. cl\/ Tl I I GI. on :()Nfl\Tl()~t -IJ I· 1EI Gt i~ ----·-·-----· -·-·• -····-·
\_j f( ~L tL DlD-
·---
., / ,_ -:
~ ---. ~---------·--
Possible /-fa:rnrd /cfentilica/ion I Sample Disposal (4 ftlO 1::,1)' /,o il.~S(l.~.5r!d d 5i!'l1f)lt>~ ,11(1 f8/illfHJrl
D No11-flaza((f D Flammable D Sirin lrntant D Poison 8 0 Unknown D Return ro Client D Dispos,1! By Lab D Aicl11ve For Mont/ls longer //1,1n I monll!J
Tum Around Tune Requ,red OC Reqwemen/s (SpacJfy)
D 7 Days O 14 Days 0 21 Days
DISTRIBUTION: WHITE· nel1Jfnad lo Clion/ WIii) Report: CANAH'r' • Stays wilh Iha Sample; PINK· Field Copy
-
METHODS SUMMARY
C3L200122
ANALYTICAL PREPARATION
PARAMETER METHOD ~M=E=T~H=O=D ____ _
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods", Third Edition, November 1986 and its updates.
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IWO #
F66NS
F66N7 I F66N8
F66N9
SAMPLE# CLIENT SAMPLE ID
001 C-29B
002 PW-01
003 RB-01
004 DUP-01
SAMPLE SUMMARY
C3L200122
INOTE(S):
• The analytical results of the samples listed above are presented on the following pages.
-All calculations are performed before rounding to avoid round-off errors in calculated results.
-Results noted as "ND" were not detected at or above lhe stated limit.
I . This repon must not be reproduced, except in full, without the written approval of the laboratory .
• Results for the following parameters are never reported on a dry weight basis: color, corrosivity, density, flashpoint. ignitability, layers, odor,
paint filter test, pH, porosity pressure, reactivity, redox potential, specific gravity, spot tests, solids, solubility, temperature, viscosity, and weight.
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SAMPLED SAMP
DATE TIME
12/15/03 14:18
12/15/03 15:20
12/15/03 16:00
12/15/03
THE RETEC GROUP INC
Client Sample ID: C-29B
GC/MS Semivolatiles
Lot-Sample t. .. : C3L200122-001 Work Order .... : F66N51AA Matrix •.•••.... : WATER Date Sampled ... : 12/15/03 Date Received .. : 12/19/03 MS Run t. ...... : 3356256 Prep Date. __ ... : 12/22/03 Analysis Date .. : 12/31/03
Prep Batch i ... : 3256515 Analysis Time .. : 11 :05
Dilution Factor: 0.98
Method ......... : SW846 8270C SIM
REPORTING
PARAMETER RESULT LIMIT UNITS 2,4-Dichlorophenol ND 0.20 ug/L
Pentachlorophenol 34 E 0.98 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 65 (30 -121 I Terphenyl-dl4 53 (11 -119)
2-Fluorobiphenyl 65 (39 -115)
2-Fluorophenol 57 (37 -115)
Phenol-d5 60 (41 -115)
2,4,6-Tribromophenol 59 I 40 -115)
NOTE (SI:
E Estimated result. Result concentration exceeds the calibration range.
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I Lot-Sample i ... :
Date Sampled ... :
C3L200122-001
12/15/03
Prep Date ...... : 12/22/03
I Prep Batch i ... : 3356515
Dilution Factor: 2.94
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PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
THE RETEC GROUP INC
Client Sample ID: C-29B
GC/MS Semivolati.les
Work Order t ... : F66N52AA
Date Received .. : 12/19/03
Analysis Date .. : 01/02/04
Analysis Time .. : 10:09
Matrix ......... : WATER
MS Run J. ...... : 3356256
Method ......... : SW84 6 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.59 ug/L
34 2.9 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
71 (30 -121)
60 Ill -119)
74 (39 -115)
56 (37 -115)
61 I 41 -115)
63 I 40 -115)
Lot-Sample i ... : C3L200122-002
Date Sampled ... : 12/15/03
Prep Date ...... : 12/22/03
Prep Batch i ... : 3356515
Dilution Factor: 0.98
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
SURROGATE
Nitrobenzene-d5
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
THE RETEC GROUP INC
Client Sample ID: PW-01
GC/MS Sernivolatiles
Work Order i ... : F66N71AA
Date Received .. : 12/19/03
Analysis Date .. : 12/31/03
Analysis Time .. : 11:32
Matrix ......... : WATER
MS Run i. ...... : 3356256
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
15 0.98 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
64 (30 -121)
64 111 -119)
64 (39 -115)
56 (37 -115)
61 (41 -115)
57 I 40 -115)
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I Lot-Sample t ... : C3L200122-003
Date Sampled ... : 12/15/03
Prep Date ...... : 12/22/03
I Prep Batch t ... : 3356515
Dilution Factor: 1.04
I PARAMETER
2,4-Dichlorophenol
1 Pentachlorophenol
SURROGATE
I Nitrobenzene-d5
Terphenyl-dl4
2-Fluorobiphenyl
I 2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
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THE RETEC GROUP INC
Client Sample ID: RB-01
GC/MS Semivolatiles
Work Order i ... : F66N81AA
Date Received .. : 12/19/03
Analysis Date .. : 12/31/03
Analysis Time .. : 12:00
Matrix ......... : WATER
MS Run i. ...... : 3356256
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.21 ug/L
ND 1.0 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
54 (30 -121)
59 (11 -119)
54 I 39 -115)
51 (37 -115)
54 I 41 -115)
46 (40 -115)
Lot-Sample J ... : C3L200122-004
Date Sampled ... : 12/15/03
Prep Date ...... : 12/22/03
Prep Batch t ... : 3356515
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
THE RETEC GROUP INC
Client Sample ID: DUP-01
GC/MS Semivolatiles
Work Order# ... : F66N91AA
Date Received .. : 12/19/03
Analysis Date .. : 12/31/03
Analysis Time .. : 12:28
Matrix ......... : WATER
MS Run L ...... : 3356256
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
17 1.0 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
64 (30 -121 I
70 (11 -119)
65 (39 -115)
55 (37 -ll5)
62 ( 41 -ll5)
58 (40 llS)
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I Client Lott ... : C3L200122
MB Lot-Sample i: C3L220000-515
I Analysis Date .. : 12/31/03
Dilution Factor: 1
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PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE (S) :
METHOD BLANK REPORT
GC/MS Semivolatiles
Work Order t ... : F68HV1AA
Prep Date ...... : 12/22/03
Prep Batch t ... : 3356515
REPORTING
RESULT LIMIT
ND 0.20
ND 1.0
PERCENT RECOVERY
RECOVERY LIMITS
68 (30 -121)
72 (11 -119)
71 (39 -115)
62 (37 -115)
65 ( 41 -115)
62 ( 40 -115)
I Calculations are performed before rounding to avoid round-off errors in calculated results.
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Matrix ......... : WATER
Analysis Time .. : 09:16
UNITS METHOD
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
LABORATORY CONTROL SAMPLE EVALUATION REPORT
Client Lot f ... : C3L200122
LCS Lot-Sample#: C3L220000-515
Prep Date ...... : 12/22/03
Prep Batch i ... : 3356515
Dilution Factor: 1
PARAMETER
Pentachlorophenol
2,4-Dichlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE (S):
GC/MS Semivolatiles
Work Order f ... : F68HV1AC
Analysis Date .. : 12/31/03
Analysis Time .. : 09:43
PERCENT RECOVERY
RECOVERY LIMITS
81 (10 -140)
64 ( 42 -ll5)
PERCENT
RECOVERY
70
67
71
57
64
64
Calculations are performed before rounding to avoid round-off errors in calculated results.
Matrix •........ : WATER
METHOD
SW846 8270C SIM
SW846 8270C SIM
RECOVERY
LIMITS
(30 -121)
I 11 -ll9)
(39 -ll5)
(37 -ll5)
( 41 -ll5)
( 40 -115)
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I MATRIX SPIKE SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
I Client Lot i ... : C3L200122 Work Order i ... : F66N71AC-MS Matrix ......... : WATER
MS Lot-Sample i: C3L200122-002
Date Sampled .... : 12/15/03
F66N71AD-MSD
Date Received .. : 12/19/03
Analysis Date .. : 12/31/03
Analysis Time .. : 10:10
MS Run# ....... : 3356256
I Prep Date ...... : 12/22/03
Prep ~atch i ... : 3356515
Dilution Factor: 1
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PERCENT RECOVERY
PARAMETER RECOVERY LIMITS
Pentachlorophenol 187 a (10 -140)
239 a (10 -140)
2,4-Dichlorophenol 61 (42 -115)
61 I 42 -ll5)
PERCENT
SURROGATE RECOVERY
Nitrobenzene-dS 63
62
Terphenyl-dl4 62
65
2-Fluorobiphenyl 64
63
2-Fluorophenol 54
58
Phenol-d5 56
55
2,4,6-Tribromophenol 59
59
NOTE(S):
Calculations are performed before rounding to avoid round-off errors in calculated results.
a Spiked analyte recovery is outside stated comrol limits.
RPO
RPO LIMITS METHOD
SW846 8270C SIM
9.6 (0-56) SW846 8270C SIM
SW846 8270C SIM
1. 3 (0-44 I SW846 8270C SIM
RECOVERY
LIMITS
(30 -121)
(30 -121)
Ill -ll9)
(ll -ll9)
(3 9 -115)
(39 -ll5)
(37 -ll5)
(37 -115)
(41 -ll5)
I 41 -ll5)
I 4 o -ll5)
I 40 -ll5)
January 23, 2004
STL SACRAMENTO PROJECT NUMBER: G3L160317R
PO/CONTRACT:
Gregory Malzone
The RETEC Group
3040 William Pitt Way
Pittsburgh, PA 15238
Dear Mr. Malzone,
•
STL Sacramento
880 Riverside Parkway
West Sacramento,CA 95605
STL
Tel:[phone] Fax: [phone]
www.stl-inc.com
This report contains the revised analytical results for the samples received under chain of
custody by STL Sacramento on December 16, 2003. These samples are associated with your
Beazer -Raleigh project. As requested on 1/21/04, the identification on sample C-28A was
changed to C-29B.
If you have any questions, please feel free to call me at [phone].
Sincerely,
Karen Dahl
Project Manager
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TABLE OF CONTENTS
STL SACRAMENTO PROJECT NUMBER G3L160317
Case Narrative
STL Sacramento Quality Assurance Program
Sample Description Information
Chain of Custody Documentation
WATER, 8290, Dioxins/Furans, HRGC/HRMS
Samples: 1, 2, 3, 4
Sample Data Sheets
Method Blank Reports
Laboratory QC Reports
Amended
CASE NARRATIVE
STL SACRAMENTO PROJECT NUMBER G3L160317R
General Comments
The ambers for sample C-28A were labeled C-29B.
listed on the bottles were used in the report.
Per client request, the identifications
I
There were no other anomalies associated with this project.
G3l160317 Amended STL Sacramento (916) 373 -5600
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1 of 19 I
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id®IW STL
STL Sacramento Certifications/Accreditations
~trnl~Hllilllli:' ·r \i.'1 l --·· . NewJ
:iJ~L.~i( "o !i!lllli!HlJ)l!lr,!?i,iill]~~ffiliffii " ·. ~~: :;: ~ J w"iSijllli~ ~1!~~il~-SWfi ~ .. ~rF.iifJ[~/M
*NELAP accredited. A more detailed parameter list is available upon request.
QC Parameter Definitions
QC Batch: The QC batch consists of a set of up to 20 field samples that behave similarly (i.e., same matrix)
and are processed using the same procedures, reagents, and standards at the same time.
~,tlethod Blank: An analytical control consisting of all reagents, which may include internal standards and
surrogates, and is carried through the entire analytical procedure. The method blank is used to define the level
of laboratory background contamination.
Laboratory Control Sample and Laboratory Control Sample Duplicate (LCS/LCSD):
An aliquot of blank matrix spiked with known amounts of representative target analytes. The LCS (and LCSD
as required) is carried through the entire analytical process and is used to monitor the accurncy of the
analytical process independent of potential matrix effects. If an LCSD is performed, it may also used to
evaluate the precision of the process.
Duplicate Sample (DU): Different aliquots of the same sample are analyzed to evaluate the precision of
an analysis.
Surrogates: Organic compounds not expected to be detected in field samples, _which behave similarly to
target analytes. These are added to every sample within a batch at a known concentration to determine the
efficiency of the sample preparation and analytical process.
Matrix Spike and Matrix Spike Duplicate (MS/MSD): An MS is an aliquot of a matrix fortified
with known quantities of specific compounds and subjected to an entire analytical procedure in order to
indicate the appropriateness of the method for a particular matrix. The percent recovery for the respective
c:ompound(s) is then calculated-The MSD is a second aliquot of the same matrix as the matrix spike, also
spiked, in order to determine the precision of the method.
Xsotope Dilution: For isotope dilution methods, isotopically labeled analogs (internal standards) of the
native target analytes are spiked into the sample at time of extraction. These internal standards are used for
quantitation, and monitor and correct for matrix effects. Since matrix effects on method peiformance can be
judged by the recovery of these analogs, there is little added benefit of performing MS/MSD for these methods.
MS/MSD are only performed for client or QAPP requirements.
Control Limits: The reported control limits are either based on laboratory historical dat1, method
requirements, or project data quality objectives. The control limits represent the estimated uncertainty of the
test results.
1810h3rr1~7------------------S-T_L_S_a_c_,a_m_e_n_to_9_1_6_-3_7-3--5-60_0 _____________________ 2-"of 19
Amended
WO# Saml)le#
F6R91 1
F6TAD 2
F6TAG 3
F6TAK 4
Notes(s):
Sample Summary
G3L160317R
Client Sam12le ID SamQling Date
C-29B 12/15/2003 02:18 PM
PW-01 12/15/2003 03:20 PM
RB-01 12/15/2003 04:00 PM
DUP-01 12/15/2003
The analytical results of the samples listed above are presented on the following pages.
All calculations are performed before rounding to avoid rouod~ff errors in calculated results.
Results noted as "ND" were not detected at or above the stated !imit.
This report must not be reproduced, except in full, without 1he written approval of the laboratory.
Received Date
12/16/2003 09:20 AM
12/16/2003 09:20 AM
12/16/2003 09:20 AM
12116/2003 09:20 AM
Results for the following parameters are never reported on a dry wcight basis: color, co.rrosivity, density, flashpoint, ignitability, layers,
odor, paint filter test, pH, porosity, pressure, reactivity, redox potential, specific gravity, spot tests,. solids, solubility, temperature, viscosity,
and weight
G3L 160317 Amended STL Sacramento (916) 373 -5600
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3 of 19 I
--- ---sTt--- --Severn Trent Laboratories, Inc.
STL 4124 (0901)
C!i:;,1: Projecr Manager Date
12./ tS/o7J Chain o1ujf'q N~m~r L1 ., /f,ec,,za_e. 'jc. 134.¼e<
Address .J-/i1kW::1.\/ 5,fi Su.i-k IW
Telephons Number {Area Code)/Fax Number Lab Number
/g-z,-z_ £_ \\.:t. CJ/ 1· '-104-c)J.DO q/{,,· 31'-l-'t~'/ P8ge I of I
c;1y IN~ I Zi2~:'.rf 3 Site Contact -Lab Contact Analysis (Attach list if
Dl,\C~<Y\ J . ~+e .. v' e,,y;. V. ~ ~-1:hhl more s ace is needed
Project Name and Location (State) Cartier/Waybill Number ' I\
&01119-O%'Z. ~ · O"I I '' . ':! Special Instructions/
Contract/Purchase Order/Quote No. Containe1s & ~ Conditions of Receipt
Matrix Preservatives
Sample I. 0. No. and Description l ~ 0 2 a ii z Date Time 0 l ! ~ ~ (Containers tor each sample may be combined on one liile) ~ ll ~ , i N~
C· 26A j7J15'/~ l'tiB IJ -;I. X X
P\IV·OI . I 1'520 (f) --i
~ ~, RR:,·DI /'=,CD
n IA<:, ~ IS?.o 3 ~ ~ M'b11 l'5ZO
"' blJP·Dl 1J/ . I• ' E EIV DI GI 00 ~ONDITION "' --' i., --, l1 11E I t;I ,.; w
0, "' 0 I ;,-, 1 ~ ,nn'I 0
" ,, v
Possi!)I~ Hazard Identification I Sample Disposal 1A !!:':! n-:.:?" t~ ess:::sscd it ssm~:es a;;:; :c:air:c:d -U Flammable D $Kin Irritant O Poison B D Un/l.nown IO Return To Client O Disposal By Lab O Afchive For
' , Months longer than I month)
QC Requirements (Specify)
D 7 Days O 14 Days D 21 Days
Time
JGOCJ
Time
Time 3. Received By
Comments x-I~ 'Ir &t e:--'Z.-9 6 · ... =====-,,-==--=-...:.....:..,.~"---=~-=--....:::=:.,....,...=:..,,...--'---'-'~-~~~c-cc----------------------------~--------Dl5TRIBUTJON: WHITE -Returned to Client with Report: CANARY -Stays with the Samp/9: PINK -Field Copy "-
.•· STL Sacramento
CLIENT e-e,d::ce (' c PM ~ LOG ff z_. Y sC( (.??
LOT# (QUANTIMS ID) G ':?l-1 !RO J() QUOTE# lf I ,a t '? LOCATION ' (;,J 1o .D
DATE RECEIVED lQ..-1 0-v'J TIME RECEIVED __ q"+-'zo~_· ·_
/'.JFEDEX
0 AIRBORNE
0 UPS
•·. ,.... , . ·, . r
DELIVERED BY 0 CA OVERNIGHT . · 0 CU.ENT
0 GOLDENSTATE ,, 0 DHL
0 STL COURIER-
0 BAX GLOBAL.·· · • O.G0·GITTERS
0 COURIERS ON DEMAND,
□ OTHER ,
CUSTODY SEAL STATUS O INTACT □BROKEN ~/A
CUSTODY SEAL #(SJ _______________ _
SHIPPPING CONTAINER(Sl O STL , £1'cLJENT . □ N/A
TEMPERTURE RECORD ON 'Cl IR )0' 2 0 0 OTHER ___ _
COC #(Sl /l-f q 3 'L:-f
TEMPERATURE BLANK -Y
SAMPLE TEMPERATURE _____ --'----~--
COLLECTOR'S NAME: D Verified from coc 'Jaiiot on coc
pH MEASURED QYES 0 ANOMALY j2(N/A
LABELED BY,, .. ,,,,,,,., ..... ,, .. ,, ... ,,,,,,,,,.,,,,.,,, .. ,,,,,,,,,,,.,,,,,, .. ,,,, .... ,,,,,,,,,,,.,,,
LABELS CHECKED BY,,,,,,,: .... , .... ,,,,,.,, .. ,,., .... ,,,,,,, ... ,,,.,,,,,,,,,, .. ,,,,.,.,.,, ...
SHORT HOLD TEST NOTIFICATION SAMPLE RECEIVING
WETCHEM fJ N/A
VOA• Encores~/A
0 METALS NOTIFIED OF FILTER/PRESERVE VIA VERBAL & EMAll;,l2l N/A
0 COMPLETE SHIPMENT RECEIVED IN GOOD CONDITION WITH Ja'N!A
APPROPRIATE TEMPERATURES, CONTAINERS, PRESERVATIVES
_,P-ciouseau O TEMPERATURE EXCEEDED (2 '·6 'C)
0 WET ICE O BLUE ICE · 0 GEL PACK
~-NOTIFIED O NO COOLING AGENTS USED
ON/A
Initials Date
i'k rz-l~-v1
: '
I j ' v
\
Notes: ___ _,,.-=---,.------,----,,-,,---~--.,.,,,,.------------
C,-Ufi--/tJ. 6.Jc,1 C-~qf>
OA1 BS S100 NEK
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I ' ' ' /Q)., 1/ / / /1/1/ / / VI/ //i/ //v 1/1/ /l/1 ;Jh -,: / / /I// I/ / V// /i/1/ /1/ I// /]/
AGB I ). I /,., I () I ::l. I I I I I I I I I I I I I -
:,, s I I I I I I I I I I .
'.SOAC□ I I I I I I I
: AGBS I I I I I I 2soAG□n I I I I I I ,, AGBna I I
AGJ I --
J AGJ
-' AGJ
1AGJ I I
CGJ I -
~ CGJ I I
CGJ I I ~EGJ I I I
PS/PJ I I I 1· I PBn/PJn I I I I I -
5 PB/PJ I I I
500P8n/PJn
-PBna
-" PBznina I I IPB I -
_ PBn
.21 PBna .
1 PBzn/na
"CT·
-ore
"older/Filter
:J
0ecri/Filter
Trap I
Z!ploc I
I ·1
11 I 2 3 4 s I s I 1 s I g 10 11 12 13 14 15 16 17 j 18 19 20
•n' h'/drocntoric acid . s = sulfuric acid na ~ .sodium hydroxide n = nitric acid zn = zinc acetate
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11.imber of VOA's with air bubbles present I total number of VOA's 5600 .0317 STL Sacramento "!:116-373· 6 of 19
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WATER, 8290, I
I Dioxins/Fu rans,
I HRGC/HRMS
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33Li60317 STL Sacramento 916-373-5600 70119 I i
lnended
I THE RETEC GROUP INC
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Client Sample ID: C-29B
Trace Level organic Compounds
I Lot-Sample # ... : G3Ll60317-001 Work Order # ••• : F6R911AA Matrix ......... : WATER
Date Sampled ... : 12/15/03 Date Received. _ : 12/16/03
Prep Date .•.... : 12/19/03 Analysis Date .. : 12/22/03
Prep Batch # ..• : 3353588
I Dilution Factor: 1
DETECTION
I PARAMETER RESULT LIMIT UNITS METHOD
2,3,7,8-TCDD ND 2.2 pg/L SW846 8290
Total TCDD ND 2.2 pg/L SW846 8290
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1,2,3,7,8-PeCDD ND 3.9 pg/L SW846 8290
Total PeCDD ND 3.9 pg/L SW846 8290
1,2,3,4,7,8-HxCDD ND 2.9 pg/L SW846 8290
1,2,3,6,7,8-HxCDD ND 3.1 pg/L SW846 8290
I 1,2,3,7,8,9-HxCDD ND 2.8 pg/L SW846 8290
Total HxCDD ND 3.1 pg/L SW846 8290
1,2,3,4,6,7,8-HpCDD ND 12 pg/L SW846 8290
Total HpCDD ND 18 pg/L SW846 8290
I OCDD 180 pg/L SW846 8290
2,3,7,8-TCDF ND 1. 9 pg/L SW846 8290
Total TCDF ND 1. 9 pg/L SW846 8290
I 1,2,3,7,B-PeCDF ND 2. 9 pg-/L SW846 8290
2,3,4,7,8-PeCDF ND 2.9 pg/L SW846 8290
Total PeCDF ND 3.0 pg/L SW846 8290
1,2,3,4,7,B-HxCDF ND 2.5 pg/L SW846 8290
I 1,2,3 1 6 1 7,8-HxCDF ND 2.5 pg/L SW846 8290
2,3,4,6,7,8-HxCDF ND 2.8 pg/L SW846 8290
1,2,3,7,8,9-HxCDF ND 3.1 pg/L SW846 8290
I Total HxCDF ND 3.1 pg/L SW846 8290
1,2,3,4,6,7,8-HpCDF ND 4.1 pg/L SW846 8290
1,2,3,4,7,8,9-HpCDF ND 3.2 pg/L SW846 8290
Total HpCDF ND 7.4 pg/L SW846 8290
I OCDF ND 19 pg/L SW846 8290
PERCENT RECOVERY
I INTERNAL STANDARDS RECOVERY LIMITS
13C-2,3,7,8-TCDD 92 (40 -135)
13C-l,2,3,7,B-PeCDD 99 (40 -135)
13C-l,2,3,6,7,8-HxCDD 91 (40 -135)
I 13C-l,2,3,4,6,7,8-HpCDD 88 (40 135)
13C-0CDD 73 (40 -135)
13C-2,3,7,8-TCDF 87 (40 -135)
I 13C-l,2,3,7,8-PeCDF 97 (40 -135)
13C-l,2,3,4,7,8-HxCDF 75 (40 -135)
13C-1,2,3,4,6,7 1 8-HpCDF 94 (40 135)
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13L 160317 Amended STL Sacramento (916) 373 • 5600 8 of 19
THE RETEC GROUP INC
Client Sample ID: PW-01
Trace Level Organic Compounds
Lot-Sample# •.. : G3Ll60317-002
Date Sampled •.. : 12/15/03
Prep Date ...... : 12/19/03
Prep Batch# ... : 3353588
Dilution Factor: 1
PARAMETER
2 1 3,7 1 8-TCDD
Tot.al TCDD
1,2,3,7,8-PeCDD
Total PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
Total HxCDD
1,2,3,4,6,7,8-HpCDD
Total HpCDD
OCDD
2,3,7,8-TCDF
Tdtal TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
Total PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
Tot.al HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
Total HpCDF
OCDF
INTERNAL STANDARDS
13C-2r3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
l3C-OCDD
13C-2,3,7,8·TCDF
13C-1,2,3,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
)3L 160317
Work Order # .•. : F6TAD1AA
Date Received .. : 12/16/03
Analysis Date .. : 12/22/03
DETECTION
RESULT LIMIT
ND 2.2
ND 2.2
ND 3.8
ND 3.8
ND 3.0
ND 3.2
ND 2.9
ND 3.2
ND 3.8
ND 3.8
ND 13
ND 1.4
ND 1.4
ND 2.1
ND 2.1
ND 2.5
ND 1.8
ND 1.8
ND 2.0
ND 2.2
ND 2.2
ND 2.9
ND 3.5
ND 3.5
ND 4.6
PERCENT RECOVERY
RECOVERY LIMITS
95 (40 . 135)
99 (40 . 135)
83 (40 . 135)
94 (40 . 135)
79 (40 . 135)
92 (40 . 135)
94 (40 . 135)
71 (40 . 135)
96 (40 . 135)
STL Sacramento 916-373-5600
Matrix ......... : WATER
UNITS METHOD
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
9 of 19
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THE R.ETEC GROUP INC
Client Sample ID: RB-01
Trace Level Organic compounds
Lot-Sample# ... : G3Ll60317-003
Date Sampled ... : 12/15/03
Prep Date ...... : 12/19/03
Prep Batch# ... : 3353588
Dilution Factor: 1
PARAMETER
2,3,7,8-TCDD
Total TCDD
1,2,3,7,8-PeCDD
Total PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
Total HxCDD
1,2,3,4,6,7,8-HpCDD
Total HpCDD
OCDD
2,3,7,8-TCDF
Total TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
Total PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
Total HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
Total HpCDF
OCDF
INTERN..lU. STANDARDS
13C-2,3,7,8-TCDD
13C-1,2,3,7,B-PeCDD
13C-1,2,3,6,7,8-HxCDD
13C-1,2,3,4,6,7,B-HpCDD
13C-OCDD
l3C-2, 3, 7, 8-TCDF
13C-l,2,3,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-1,.2,3,4,6,7,8-HpCDF
Work Order# ... : F6TAG1AA
Date Received .. : 12/16/03
Analysis Date .. : 12/22/03
DETECTION
RESULT LIMIT
ND 3.1
ND 3.1
ND 6.9
ND 6.9
ND 4.7
ND 5.0
ND 4.6
ND 5.0
ND 6.4
ND 6.4
ND 7.7
ND 2.6
ND 2.6
ND 4.6
ND 4.6
ND 4.6
ND 3. 5
ND 3.4
ND 3.9
ND 4.2
ND 4.2
ND 4.2
ND 4.9
ND 4.9
ND 8.7
PERCENT RECOVERY
RECOVERY LIMITS
77 (40 -135)
80 (40 -135)
78 (40 -135)
75 (40 -135)
61 (40 -135)
71 (40 -135)
77 (40 -135)
61 (40 -135)
79 (40 -135)
STL Sacramento 916-373-5600
Matrix ......... : WATER
UNITS METHOD
pg/L SW846 8290
pg/L SW846 8290
pg/L SWB46 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SWB46 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
10 ol 19
THE RETEC GROUP INC
Client Sample ID: DUP-01
Trace Level Organic Compounds
Lot-Sample# ••. : G3Ll60317-004
Date Sampled ... : 12/15/03
Prep Date .....• : 12/19/03
Prep Batch# ... : 3353588
Dilution Factor: 1
PARAMETER
2,3,7,B-TCDD
Total TCDD
1,2,3,7,8-PeCDD
Total PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
Total HxCDD
1,2,3,4,6,7,8-HpCDD
Total HpCDD
OCDD
2,3,7,8-TCDF
Total TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
Total PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1, 2 ,·3, 7, 8, 9-HxCDF
Total HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
Total HpCDF
OCDF
INTERNAL STANDARDS
13C-2, 3, 7, 8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-l,.2,3,4,7,8-Hx.CDF
l3Col,2,3,4,6,7,8-HpCDF
G3L 160317
Work Order# ... : F6TAK1AA
Date Received .. : 12/16/03
Analysis Date .. : 12/22/03
DETECTION
RESULT LIMIT
ND 3.2
ND 3.2
ND 7.4
ND 7.4
ND 3.7
ND 4.0
ND 3.7
ND 4.0
ND 4.9
ND 4.9
ND 8.2
ND 1. 9
ND 1.9
ND 4.0
ND 4.0
ND 4.9
ND 2.9
ND 2.8
ND 3.2
ND 3.5
ND 3.5
ND 3.7
ND 4.3
ND 4.3
ND 6.6
PERCENT RECOVERY
RECOVERY LIMITS
84 (40 -135)
84 (40 135)
90 (40 -135)
83 (40 -135)
64 (40 -135)
82 (40 -135)
84 (40 -135)
73 (40 -135)
91 (40 -135)
STL Sacramento 916-373-5600
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Matrix ......... : WATER I
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UNITS METHOD
pg/L SW846 8290 I
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290 I
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290 I
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290 I
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290 I pg/L SW846 8290
pg/L SW846 8290·
pg/L SW846 8290
pg/L SW846 8290 I
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290 I
pg/L SW846 8290
pg/L SW846 8290 I
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I QC DATA ASSOCIATION SUMMARY
I G3L160317
I Sample Preparation and Analysis Control Numbers
I SAMPLE#
ANALYTICAL LEACH PREP
MATRIX METHOD BATCH # BATCH # MS RUN/le
001 WATER SW846 8290 3353588 4002112
I 002 WATER SW846 8290 3353588 4002112
I 003
004
WATER SW846 8290 3353588 4002112
WATER SW846 8290 3353588 4002112
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1"1317 STL Sacramento 916-373-5600 12 of 19
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METHOD BLANK REPORT
Trace Level Organic Compounds I
Client Lot# ... : G3L160317 Work Order# ... : F65VH1AA
MB Lot-Sample#: G3L190000-588 Matrix .....•.. _ : WATER I Prep Date ....•. : 12/19/03
Analysis Date .. : 12/22/03 Prep Batch # .•. : 3353588
Dilution Factor: 1 I
DETECTION
PARAMETER RESULT LIMIT UNITS METHOD 2,3,7,8-TCDD ND 2.8 pg/L SW846 8290 Total TCDD ND 2.8 pg/L HW846 8290.
I
1,2,3,7,8-PeCDD ND 5.5 pg/L SW846 8290 Total PeCDD ND 5.5 pg/L SW846 8290
1,2,3,4,7,8-HxCDD ND 3.7 pg/L HW846 8290 I
1,2,3,6,7,8-Hx.CDD ND 3.9 pg/L HW846 8290
1,2,3,7,8,9-HxCDD ND 3.6 pg/L SW846 8290
Total HxCDD ND 3.9 pg/L SW846 8290
1,2,3,4,6,7,8-HpCDD ND 4.4 pg/L HW846 8290 Total HpCDD ND 4.4 pg/L SW846 8290 OCDD ND 6.7 pg/L SW846 8290
2,3,7,8-TCDF ND 1.8 pg/L SWB46 8290
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Total TCDF ND 1.8 pg/L SW846 8290
1,2,3,7,8-PeCDF ND 3.7 pg/L SW846 8290
2,3,4,7,8-PeCDF ND 3.6 pg/L 8W846 8290 Total PeCDF ND 4.0 pg/L .SW846 8290 I
1,2,3,4,7,8-HxCDF ND 2.4 pg/L ~iW846 8290
1,2,3,6,7,8-HxCDF ND 2.4 pg/L .SW846 8290
2,3,4,6,7,8-HxCDF ND 2.7 pg/L .SW846 8290 I
1,2,3,7,8,9-HxCDF ND 2.9 pg/L ~iW846 8290
Total HxCDF ND 2.9 pg/L .SW846 8290
1,2,3,4,6,7,8-HpCDF ND 4.2 pg/L SW846 8290
1,2,3,4,7,8,9-HpCDF ND 5.0 pg/L SW846 8290 Total HpCDF ND 5.0 pg/L SW846 8290
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OCDF ND 7.4 pg/L ~:W846 8290 I
PERCENT RECOVERY
INTERNAL STANDARDS RECOVERY LIMITS
13C-2,3,7,8-TCDD 96 (40 -135)
13C-l,2,3,7,8-PeCDD 101 (40 -135) I
13C-l,2,3,6,7,8-HxCDD 94 (40 -135)
13C-1,2,3,4,6,7,8-HpCDD 91 (40 -135)
13C-OCDD 68 (40 -135) I 13C-2,3,7,8-TCDF 92 (40 -135)
13C-1,2,3,7,8-PeCDF 98 ( 4 0 -135)
13C-l,2,3,4,7,8-HxCDF 83 (40 -135)
13C-1,2,3,4,6,7,8-HpCDF 104 (40 -135) I
NDTE(S),
Calculations are performed Defore rounding 10 avoid rOUOO-off erro~ in calculated results. I
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i3L 160317 STL Sacramento 916-373-5600 13 of 19 I
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LABORATORY CONTROL SAMPLE DATA REPORT
Trace Level Organic Compowids
Client Lot# ... : G3L160317 Work Order# ... : F65VH1AC Matrix ......... : WATER
LCS Lot-Sample#: G3L190000-588
Prep Date ...... : 12/19/03 Analysis Date .. : 12/22/03
Prep Batch# ... : 3353588
Dilution Factor: 1
SPIKE MEASURED PERCENT
PARAMETER AMOUNT AMOUNT UNITS RECOVERY METHOD
2,3,7,8-TCDD 200 165 pg/L 83 SW846
1,2,3,7,8-PeCDD l.000 853 pg/L 85 SW846
1,2,3,4,7,8-Hx.CDD 1000 847 pg/L 85 SW846
1,2,3,6,7,8-HxCDD 1000 935 pg/L 94 SW846
1,2,3,7,8,9-IDtCDD 1000 935 pg/L 93 SW846
1, 2, 3 ,-4, 6, 7, 8-HpCDD l.000 950 pg/L 95 SW846
OCDD 2000 2480 pg/L 124 SW846
2,3,7,-8-TCDF 200 205 pg/L 103 SW846
1,2,3,7,8-PeCDF 1000 989 pg/L 99 SW846
2,3,4,'7,8-PeCDF 1000 957 pg/L 96 SW846
1, 2, 3, ·l, 7, 8-HxCDF 1000 901 pg/L 90 SW846
1,2,3,6,7,8-HxCDF 1000 996 pg/L lOO SW846
2,3,4,15,7,8-HxCDF 1000 1060 pg/L l.06 SW846
1,2,3,7,8,9-HxCDF l.000 1040 pg/L 104 SW846
1,2, 3,•i,6, 7 ,8-HpCDF 1000 904 pg/L 90 SW846
1,2, 3,•l, 7, 8, 9-HpCDF 1000 876 pg/L 88 SW846
OCDF 2000 2320 pg/L 116 SW846
PERCENT RECOVERY
INTERNi>.L STANDARD RECOVERY LIMITS
13C-2,3,7,8-TCDD 93 (40 -135)
13C-l,2,3,7,8-PeCDD 98 (40 -135)
13C-1,2,3,6,7,8-HxCDD 97 (40 -135)
13C-l,2,3,4,6,7,8-HpCDD 95 (40 -135)
13C-OCDD 80 (40 -135)
13C-2,3,7,8-TCDF 90 (40 -135)
13C-l,2,3,7,8-PeCDF 94 (40 -135)
13C-l,2,3,4,7,8-HxCDF 82 (40 -135)
13C-l,2,3,4,6,7,8-HpCDF 106 (40 -135)
NOTE(S),
Calculalions are performed before rounding to avoid round-off errors in calculated results.
Bold print denotes control parameters
STL Sacramento 916-373-5600
8290
8290
8290
8290
8290
8290
8290
8290
8290
8290
8290
8290
8290
8290
8290
8290
8290
14 at 19
LABORATORY CONTROL SAMPLE KV1\LUATION REPORT
Trace Level Organic Compounds
Client Lot# ... : G3L160317 Work Order# ... : F65VH1AC LCS Lot-Sample#: G3Ll90000-5BB
Prep Date ...... : 12/19/03 Analysis Date .. : 12/22/03 Prep Batch# •.. : 3353588
Dilution Factor: 1
PARAMETER
2,3,7,8-TCDD
1,2,.3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,41 6,7,8-HpCDD
OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-IDcCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,71 8-HpCDF
1,2,3,4,7,8,9-HpCDF
OCDF
INTERNAL STANDARD
13C-2,3,7,8-TCDD
13C-l,:2,3,7,8-PeCDD
13C-l,2,3,6,7,8-HxCDD
13C-l, 2, 3, 4,61 7, 8-_HpCDD
13C-OCDD
13C-2, 3, 7, 8-TCDF
13C-1,2,3,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
NOTE (S):
PERCENT
RECOVERY
83
85
85
94
93
95
124
103
99
96
90
100
106
104
90
88
116
Calculations are performed before rounding to avoid roun:1-off errors in calculated results.
Bold print der.ntes control parameters
RECOVERY
LIMITS
(72 -137)
(65 -141)
(54 -147)
(70 -133)
(68 -147)
(75 -130)
(78 -127)
(67 -140)
(77 -131)
(65 -137)
(75 -131)
(69 -141)
(68 -170)
(65 -158)
(77 -129)
(69 -139)
(67 -140)
PERCENT
RECOVERY
93
98
97
95
80
90
94
82
106
l3L160317 STL Sacramento 916·373-5600
Matrix ....•.... : WATER
METHOD
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
RECOVERY
LIMITS
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
15 of 19
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I MATRIX SPIXB SAMPLE DATA REPORT
Trace Level Organic Compounds
I Client Lot# •.• : G3Ll60317 Work Order# ..• : F6TAD1AC-MS Matrix. __ .... __ : WATER
MS Lot-Sample#: G3Ll60317-002 F6TAD1AD-MSD
Date Sampled .•. : 12/15/03 . Date Received .. : 12/16/03
I Prep Date ...... : 12/19/03 Analysis Date .. : 12/22/03
Prep Batch # ... , 3353588
Dilution Factor: 1
I SAMPLE SPIKE MEASRD PERCNT
PARAMETER AMOUNT AMT AMOUNT UNITS RECVRY ;RPD METHOD
2,3,7,8-TCDD ND 205 166 pg/L Bl SWB46 8290
I ND 201 165 pg/L 82 0 .50 SW846 8290
1,2,3,7,8-PeCDD ND 1020 855 pg/L 83 SW846 8290
ND 1010 821 pg/L 82 3.9 SW846 8290
1, 2, 3,-41, 7, 8-HxCDD ND 1020 800 pg/L 78 SWB46 8290
I ND 1010 841 pg/L 84 5.0 SW846 8290
1,2,3,6,7,8-HxCDD ND 1020 1010 pg/L 99 SW846 8290
ND 1010 972 pg/L 97 4.0 SW846 8290
I l.,2,3,7,8,9-BxCDD ND 1020 981 pg/L 96 SW846 8290
ND 1010 909 pg/L 90 7.6 SW846 8290
1,2,3,4,6,7,8-HpCDD ND 1020 973 pg/L 95 SW846 8290
ND 1010 920 pg/L 92 .5. 6 SW846 8290
I OCDD ND 2050 2590 pg/L 126 SW846 8290
ND 2010 2450 pg/L 122 5.6 SW846 8290
2,3,7,8-TCDF ND 205 207 pg/L 101 SW846 8290
I ND 201 191 pg/L 95 8.2 SW846 8290
1,2,3,"i',8-PeCDF ND 1020 992 pg/L 97 SW846 8290
ND 1010 970 pg/L 97 2.2 SW846 8290
2,3,4,7,8-PeCDF ND 1020 950 pg/L 93 SW846 8290
I ND 1010 938 pg/L 93 :l.2 SW846 8290
1, 2, 3 ,-4,, 7, 8-HXCDF ND 1020 959 pg/L 94 SW846 8290
ND 1010 904 pg/L 90 .5.9 SW846 8290
I 1,2,3,6,7,8-HxCDF ND 1020 1090 pg/L 107 SW846 8290
ND 1010 1010 pg/L 100 1:3 .0 SW846 8290
2,3,4,6,7,8-HxCDF ND 1020 1130 pg/L 110 SW846 8290
ND 1010 998 pg/L 99 12 SW846 8290
I l.,2,3,7,8,9-HxCDF ND 1020 1150 pg/L 112 SW846 8290
ND 1010 997 pg/L 99 :L4 SW846 8290
1, 2, 3, 4,, 6, 7, 8-HpCDF ND 1020 941 pg/L 92 SW846 8290
I ND 1010 898 pg/L 89 1.7 SW846 8290
l, 2, 3, 4,, 7, 8, 9-HpCDF ND 1020 933 pg/L 91 SW846 8290
ND 1010 875 pg/L 87 G.4 SW846 8290
OCDF ND 2050 2340 pg/L 114 SW846 8290
I ND 2010 2250 pg/L 112 1.7 SW846 8290
{Continued on next page)
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,,60317 STL Sacramento 916-373-5600 16 of 19
MATRIX SPIKE SAMPLE DATA REPORT
Trace Level Organic Compounds
Client Lot# ... : G3Ll60317 work Order# .•• : F6TADlAC-MS Matrix .•...•... :_WATER MS Lot-Sample#: G3Ll60317-002 F6TAD1AD-MSD
PERCENT RECOVERY INTERNAL STANDARDS RECOVERY 13C-2,3,7,8-TCDD 98
94
13C-l,2,3,7,8-PeCDD 102
104
13C-1,2,3,6,7,8-HxCDD 94
99 13C-l,2,3,4,6,7,8-HpCDD 89
95 13C-OCDD 75
80 13C-2,3,7,8-TCDF 92
95 13C-l,2 1 3,7,8-PeCDF 99
100 13C-1,2,3,4,7,8-HxCDF 74
85
13C-l,2,3,4,6,7,8-HpCDF 96
105
NOTE(S):
Calculations are performed before rounding to avoid round-off errors in calculated results.
Bold print denotes control parameters
l3L160317 STL Sacramento 916-373-5600
LIMITS
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
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I MATRIX SPIKE SAMPLE EVALUATION REPORT
Trace Level Organic Compounds
I Client Lot # ... : G3Ll60317
MS Lot··Sample ·#: G3Ll60317-002
Date Sampled •.. : 12/15/03
Work Order# ... : F6TAD1AC-MS
F6TAD1AD-MSD
Date Received .. : 12/16/03
Analysis Date .. : 12/22/03 I Prep Date ...... : 12/19/03
Prep Batch# ... : 3353588
Dilution Factor: 1
I PARAMETER
PERCENT RECOVERY RPD
RECOVERY LIMITS RPD LIMITS
2,3,7,8-TCDD 81 (72 -137)
I 1,2,3,7,8-PeCDD
82 (72 -137) 0.50 (0-20)
83 (65 -141)
82 (65 -141) 3.9 (0-20)
1,2,3,4,7,8-HxCDD 78 (54 -147)
I 1,2,3,6,7,8-Hx.CDD
84 (54 -147) 5.0 (0-20)
99 (70 -133)
97 (70 -133) 4.0 (0-20)
I 1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
96 (68 -147)
90 (68 -147) 7.6 (0-33)
95 (75 -l.30)
92 (75 -130) 5.6 (0-20)
I OCDD 126 (78 -127)
122 (78 -127) 5.6 (0-20)
2,3,7,8-TCDF 101 (67 -140)
I 1,2,3,7,8-PeCDF
95 (67 -140) 8.2 (0-23)
97 (77 -131)
97 (77 -131) 2.2 (0-20)
2,3,4,7,8-PeCDF 93 (65 -137)
Ma.tr.ix ....•.... : . WATER
METHOD
SW846 8290
SW846 8290
HW846 8290
SW846 8290
SW846 8290
HW846 8290
SW846 8290
flW846 8290
!iW846 8290
SW846 8290
.8W846 8290
SW846 8290
HW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
I 93 (65 -137) 1.2 (0-32). SW846 8290
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1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1, 2, 3, 4 ., 7, 8, 9-HpCDF
OCDF
94
90
l.07
l.00
110
99
112
99
92
89
91
87
l.l.4
112
(75 -131) SW846 8290
(75 -l.3l.) 5.9 (0-24) SW846 8290
(69 -141) SW846 8290
(69 -l.41) 8.0 (0-32) SW846 8290
(68 -170) SW846 8290
(68 -170) 12 (0-49) SW846 8290
(65 -l.58) SW846 8290
(65 -158) 14 (0-54) SW846 8290
(77 -129) SW846 8290
(77 -129) 4.7 (0-20) SW846 8290
(69 -139) SW846 8290
(69 -139) 6.4 ( 0-21) SW846 8290
(67 -140) SW846 8290
(67 -140) 3.7 (0-23) SW846 8290
(Continued on next page)
STL Sacramento 916-373-5600 18 ol 19
MATRIX SPIK!l SAMPLE EVALUATION REPORT
Trace Level Organic Compounds .
Client Lot# ... : G3Ll60317 Work Order# ... : F6TADlAC-MS Matrix ......... : . WATER MS Lot-Sample#: G3Ll60317-002 F6TADlAD-MSD
INTERNAL STANDARDS
l3C-2,3,7,8-TCDD
l3C-l,2,3,6,7,8-HxCDD
l3C-l,2,3,4,6,7,8-HpCDD
l3C-OCDD
l3C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
l3C-l,2,3,4,7,8-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
NOTE(S):
PERCENT
RECOVERY
98
94
102
104
94
99
89
95
75
80
92
95
99
100
74
85
96
105
Calculations are performed before rOWlding to avoid rourxl•off errors in calculated results.
Bold print denotes control parameters
i3L160317 STL Sacramento 916-373-5600
RECOVERY
LIMITS
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
19 of 19
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ANALYTICAL REPORT
Morrisville, Raleigh MNA
Lot#, C3Ll90237
Gregory Malzone
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
Veronica Bertot
Project Manager
January 13, 2004
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238
STL
Tel, 412 820 8380 Fax, 412 820 2080
www.stl•inc.com
Severn Trent Laboratories, Inc.
NELAC REPORTING:
The foI'IDat and coritent of the attached report meets NELAC Standards and gti.idelineS except as noted in the narrative. The table below
presents a.~a.ri of the certificati.Oils held by. S~ Pittsb\lfgh. Our primary accreditation authority for the Noll-potable water and Solid
& Hazardous waste programs is N6W York State DOR A moie detailed parameter liSt is available upon request. Please ask your project
manager for this information when reqUlred.
The codes utllii.ed for program types are described below:
HW
WW
X
Hazardous Waste ~ertifi.cation
Non-potable Water and/or Wastewater certification . .
LaboratOry has some form of certifica"tiOn under the specific program. Many states certify laboratories for specific parameters or
tests within a category. The informa"tion in the table indicates the lab is certified in a fleneral category of testing. Piease contact
the laboratory if parameter specific certification information Is required.
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CASE NARRATIVE
THE RETEC GROUP
Raleigh, Morrisville
STL Lot# C3L190237
Sample Receiving:
STL Pittsburgh, PA received one sample on December 19, 2003 in good condition. The.
cooler was received within the proper temperature range.
If project specific QC was not required for samples contained in this report and batch QC
was completed on these samples, anomalous results will be discussed below.
GC/MS Semivolatiles:
The reporting limits were adjusted accorrnng to the amount of sample extracted.
GC/MS Semivolatiles SIM:
The reporting limits were adjusted according to the amount of sample extracted.
Dissolved Gases:
The STL North Canton, OH laboratory analyzed the rnssolved gases.
There were no problems associated with the analysis.
Metals:
Comparison of the total and dissolved rngestate results of sample C-O!B, the
concentrations of iron and/or manganese were higher in the dissolved analysis than in the
total analysis. The raw samples were analyzed and confirmed the results of the
digestates.
General Chemistry:
The STL North Canton, OH laboratory analyzed the ferrous iron.
The sulfide was analyzed outside the holding time by one day.
-
Chain of
Cµstoqy Record
STL·4124 (0901)
Clienr
Re+tc.
ProJec/ Manager v, ,z.," ,+ o+
STL
Severn Trent Laboratories, Inc.
/ YL vJes+r v-~/
Date Cham of Custody N/Jmber
+, \ZI t~l 0:3 1 Ll.711~/J .. . Address Telephone Number (Area Coddj/Fax Number ' . Lab Number { \v·y P. l~CSi.t 91.A.dc loo "I l 'l-i.\-l?ilt ' 2.,''Jif)() Vl Page I of I
City I State 1 Zip Code Site Contac/ :r~;~+o\-~ Analysis (At_tach list if
°1)1,lVV\l\.v~ ~c., '2"141-:z, ,. SIA .A '"' more s □ace 1s needed
Projr:cl Name and Location (Slate) Carrier/Waybill Number ']: th 1 i D ' 2 ~ P,ea,:;zp y . r(\ l'lYYISvHl n (NC\ -J I~~ \; d1 Special Instructions/ (-l r\il r{!
Contracl/Purchase Order/Ouo/e No. 6fll ·C ~ . ,f3 0 :1 LI , ucr. f Containers & _;\ sb ._) \:£1 ' ,r! Conditions of Receipt
Matrix Preservatives i ' ~ i Q ~ Cl -!! ':j r ·O -..I) t ! " • > b> ~ ~ -~ @. Sample /.0. No. and Description Date Time • 0 8 ~ C'\ ! ,; ~ § ~ ijl 0 ,o (Containers for each sample may be combined on one line) s , ~ i :l ~1 ~
(-nil"\ 12)15/~ o13o ¥,. ) J ,,r .. I I I I I I I 3 2 ool\/ 1 ~2=k>C.•51,'YI
C· f\CJ p, 12/ib/6?, 0915 i l I ( 2 I ( ( 3 -:i
7f1... i (., I fl31 ti'; -' ' I
Possible Hazard ldentificarion I Sample Disposal (A !efJ may be assossed if samples are 1etained 0 Non-Hazard D Flammable D Skin Im/ant 0 Poison B D Unknown D Return To Client 0 Disposal By Lab D Archive For Months longer lhan 1 month}
Turn Around Time Required □ Olher '.){A(\dev~d DC Requirements (Specify}
D 24 ltpurs D •18Hou~ D 7Days 0 14 Days D 21 Days
,.~ ""hr::, c I J ;1 A 112/eJlflr lt:io-o I. Received By
1
Dale
1
Time
-
2rynql ished By l) v I°"·' I
1
Time 2. Received By
1
Dale
1
Time
3. Relinqwshed By
1
Date
1
Time 3.Rece1V7 Ajn H~ {)
1
Date
1
Time
/1..-/ r-vJ 1/.! (f J
Comments
DISTRIBUTION: WHITE· Re/urned lo Client wrlh Report; CANARY -Stays with the Sample; PINK· Field Copy - - ------- --- --- - -
--
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METHODS SUMMARY
PARAMETER
Alkalinity, Total
Bicarbonate alkalinity
Carbonate Alkalinity
C3Ll90237
Chloride (Colorimetric, Automated Ferricyanide)
Dissolved Gases in Water
Ferrous Iron {Phenanthroline Method)
Nitrate as N
Semivolatile Organic Compounds by GC/MS
Sulfate
ANALYTICAL
METHOD
SM18 2320 B
SM18 2320 8
SM18 2320 8
MCAWW 325.2
RSK SOP-175
SMlB 3500-FE
SW846 9056
SW846 8270C
SW846 9056
D
Sulfides, Total 90308/9034 SW846 9030B/903
Total Organic Carbon SW846 90 60
Trace Inductively Coupled Plasma (ICP) Metals SW846 60108
Trace Inductively Coupled Plasma (ICP) Metals SW846 60108
8270C (SIM) SW846 8270C SIM
References:
MCAWW
RSK
"Methods for Chemical Analysis of Water and Wastes",
EPA-600/4-79-020, March 1983 and subsequent revisions.
Sample Prep and Calculations for Dissolved Gas Analysis
PREPARATION
METHOD
SM18 2320 8
SMlB 2320 8
MCAWW 325. 2
RSK RSKSOP-175
SW846 9056
SW846 3520C
SW846 9056
SW846 90308/903
SW846 9060
SW846 3005A
SW846 3010A
SW846 3520C
i~ Water Samples Using a GC Headspace Equilibration
Technique, RSKSOP-175, REV. 0, 8/11/94, USEPA Research Lab
SM18
SW846
"Standard Methods for the Examination of Water and
Wastewater", 18th Edition, 1992.
''Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods", Third Edition, November 1986 and its updates.
WO# SAMPLE# CLIENT SAMPLE ID
F64KX
F64K8
F64LD
NOTE(S):
001
002
003
C-OlB
C-09B
TB-121803
SAMPLE SUMMARY
C3Ll90237
-The analytical results of the samples listed above are presented on the following pages.
-All calculations are performed before rounding to avoid round-off errors in calculated results.
-Results noted as "ND" were not detected at or above the stated limit.
-This report must not be reproduced, except in full, without the written approval of the laboratory.
-Results for the following parameters are never reported on a dry weight basis: color, corrosivity, density, flashpoint, ignitability, layers, odor,
paint filter test, PH, porosity pressure, reactivity, redox potential, specific gravity, spot tests, solids, solubility, temperature, viscosity, and weight.
SAMPLED
DATE
12/18/03
12/18/03
12/18/03
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SAMP
TIME I
09:30
09:25 I
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Lot-Sample t. .. : C3Ll90237-001
Date Sampled ... : 12/18/03
Prep Date ...... : 12/22/03
Prep Batch ll ... : 3356515
Dilution Factor: 1. 02
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
NOTE(S):
J Estimated result. Result ls less than RL.
THE RETEC GROUP INC
Client Sample ID: C-01B
GC/MS Semivolatiles
Work Order t ... : F64KX1AP Matrix ......... : WATER
Date Received .. : 12/19/03 MS Run f ....... : 3356256
Analysis Date •. : 12/31/03
Analysis Time .. : 12:55
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
0.32 J 1.0 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
56 (30 -121)
33 (11 -119)
54 (39 -ll5)
48 (37 -ll5)
51 I 41 -ll5)
49 I 40 -115)
Lot-Sample t ... : C3L190237-002
Date Sampled ... : 12/18/03
Prep Date. -.... : 12/22/03
Prep Batch t ... : 3356515
Dilution Factor: 1. 04
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
SURROGATE
Nitrobenzene-d5
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
THE RETEC GROUP INC
Client Sample ID: C-09B
GC/MS Semivolatiles
Work Order JI •.. : F64K81AP Matrix ......•.. : WATER
Date Received .. : 12/19/03 MS Run I. ...... : 3356256
Analysis Date .. : 01/02/04
Analysis Time •. : 10:35
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.21 ug/L
ND 1.0 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
77 (30 -121)
93 (11 -119)
81 (39 115)
71 (37 -115)
78 I 41 -115)
67 (40 -115)
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METHOD BLANK REPORT
GC/MS Sernivolatiles
Client Lot# ... : C3Ll90237 Work Order t ... : F68HV1AA
MB Lot-Sample f: C3L220000-515
Prep Date ...... : 12/22/03
Analysis Date .. : 12/31/03 Prep Batch t ... : 3356515
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE(S):
RESULT
ND
ND
PERCENT
RECOVERY
68
72
71
62
65
62
Calcu!atlons are performed before rounding to avoid round-off errors in calculated results.
REPORTING
LIMIT
0.20
1.0
RECOVERY
LIMITS
(30 -121)
Ill -1191
(39 -115)
(37 -115)
I 41 -115)
I 4 D -115)
Matrix ......... : WATER
Analysis Time .. : 09:16
UNITS METHOD
ug/L SW846 8270C SIM
ug/1 SW846 8270C SIM
ANALYTICAL REPORT
Morrisville, Raleigh MN.A
Lot #, C3Ll80138
Gregory Malzone
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
veronica Bertot
Project Manager
January 14, 2004
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238
STL
Tei, 412 820 8380 Fax, 412 820 2080
www.stl~inc.com
Severn Trent Laboratories, Inc.
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Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Morrisville
SIL Lot# C3L180138
SIL Pittsburgh, PA received samples on December 18, 2003. The cooler was received
within the proper temperature range.
The dissolved metals bottle for sample C-28A was received un-preserved. The
laboratory prior to digestion preserved the sample.
The chain of custody did not list total and dissolved metals analysis for sample PW-01.
Samples bottles were received for these analyses. The sample was logged in for total and
dissolved analyses.
If project specific QC was not required for samples contained in this report and batch QC
was completed on these samples, anomalous results will be discussed below.
GC/MS Semivolatiles:
The reporting limits were adjusted according to the amount of sample extracted.
GC/MS Semivolatiles SIM:
The reporting limits were adjusted according to the amount of sample extracted.
Dissolved Gases:
STL North Canton, Ohio performed the dissolved gases analysis. All results are included
in the report.
There were no problems associated with the analysis.
Metals:
There were no problems associated with the analysis.
General Chemistry:
SIL North Canton, Ohio performed the ferrous iron analysis. All results are included in
the report.
The samples were analyzed outside of the holding time for sulfide due to a laboratory
error.
-
Serial Number · 2 4 0 9 4
ANALYSIS REQUEST AND CHAIN OF CUSTODY RECORD
PROJECT NO. PROJECT LOCATION
1, 'iA 7.Cf -o?;<,;)J-{-o'II ISTATEI N (._..
Q'BU fB I
01)\0 pw -o \
MATRIX
1YPE
C)~).venue
~404
0 Alternate Laboratory Name/Location
Phone:
Fax:
REQUIRED ANALYSIS
r'f -~ ~ ,.,
NUMBER OF CONTAINERS SUBMITTED
I ~
3 J
;;i n :/, ,,
::i ~ -I-LI 4,,::,A-c...:cl'--+_C_-..QLUCfi_ _________ +l+H-j--+--f----l--'-+-'-+=--+-'--+-;J ).
1335 -I I°!)
RELINQUISHED BY: \S!GNl'ITUREl
1::ii!lt·'Tl f:f)f,IIT!\ft1U::Hg
f"lECElVED BY: !SIGNATURE)
li'l,W IV CONTi\!i'll,HS
- -
DME
DATE
- -
TIME
TIME
----
~ I ·, 2.
DATE TIME RELINQUISHED BY: !SIGNATURE)
-- ----
IJ.inc.com
4-7858
0165
PAGE I OF
STANDARD REPORT
DEUVERY Q
DATE DUE ____ _
EXPEDITED REPORT
DELIVERY 0
{SURCHARGE)
DATE DUE
NUM□ER OF COOLERS SUBMITTED
PER SHIPMENT:
-
DATE
. DATE
!Z-1 J'.-0
-
TIME
STL8240-680 (l 2/02) -------
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D
D
METHODS SUMMARY
PARAMETER
Alkalinity; Total
Bicarbonate alkalinity
Carbonate Alkalinity
C3Ll80138
Chloride (Colorimetric, Automated Ferricyanide)
Dissolved Gases in Water
Ferrous Iron (Phenanthroline Method)
Nitrate as N
Semivolatile Organic Compounds by GC/MS
Sulfate
ANALYTICAL
METHOD
SMlB 2320 B
SMlB 2320 B
SMlB 2320 B
MCAWW 325.2
RSK SOP-175
SM18 3500-FE
SW846 9056
SW846 8270C
SW846 9056
D
Sulfides, Total 9030B/9034
Total Organic Carbon
SW846 9030B/903
SW846 9060
Trace Inductively Coupled Plasma (ICP) Metals
Trace Inductively Coupled Plasma (ICP) Metals
8270C (SIM)
SW846
SW846
SW846
6010B
6010B
8270C SIM
References:
MCAWW
RSK
SM18
"Methods for Chemical Analysis of Water and Wastes",
EPA-600/4-79-020, March 1983 and subsequent revisions.
Sample Prep and Calculations for Dissolved Gas Analysis
in Water Samples Using a GC Headspace Equilibration
Technique, RSKSOP-175, REV. 0, 8/11/94, USEPA Research Lab
"Standard Methods for the Examination of Water and
Wastewater'', 18th Edition, 1992.
PREPARATION
METHOD
SMlB 2320 B
SM18 2320 B
MCAWW 325.2
RSK RSKSOP-175
SW846 9056
SW846 3520C
SW846 9056
SW846 9030B/903
SW846 9060
SW846 3005A
SW846 3010A
SW846 3520C
SW846 ''Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods", Third Edition, November 1986 and its updates.
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SAMPLE SUMMARY I
C3Ll80138 I
SAMPLED SAMP
WO# SAMPLE# CLIENT SAMPLE ID
F60TO 001 PW-01
DATE TIME I 12/17/03 08:10
F60WA 002 C-15B
F60WF 003 C-28A
F60WH 004 C-11B
12/17/03 09:03 I 12/17/03 14:24
12/17/03 13 :35
F60WM 005 RB02 12/17 /03 09:20
F60WR 006 FBl
F60WX 007 TB-121703
12/17/03 09:30 I 12/17 /03
NOTE(S)
-The analytical results of the samples listed above are presented on the following pages.
• All calculations are performed before rounding to avoid round-off errors in calculated results. I
-Results noted as "ND" were not detected at or above the stated limit.
-This repon must not be reproduced, except in full, without the written approval of the laboratory.
-Results for the following parameters are never reported on a dry weight basis: color, corrosivity, density, flashpoint, ignitability, layers, odor,
paint filter test, pH, porosity pressure, reactivity, redox potential, specific gravity, spot tests, solids, solubility, temperature, viscosity, and weight. I
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Lot-Sample i ... : C3Ll80138-002
Date Sampled ... : 12/17/03
Prep Date.·.· ... : 12/21/03
Prep Batch i ... : 3356504
Dilution Factor: 1.08
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
THE RETEC GROUP INC
Client Sample ID: C-15B
GC/MS Semivolatiles
Work Order i ... : F60WA1AP
Date Received .. : 12/18/03
Analysis Date .. : 01/02/04
Analysis Time .. : 16:29
Matrix ......... : WATER
MS Run t ....... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.22 ug/L
ND 1.1 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
64 (30 -121)
61 (11 -119)
68 (39 -115)
55 (37 -115)
56 I 41 -115)
58 I 40 -115)
Lot-Sample .... : C3Ll80138-003
Date Sampled ... : 12/17/03
Prep Date ...... : 12/21/03
Piep Batch .... : 3356504
Dilution Factor: 1. 03
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
THE RETEC GROUP INC
Client Sample ID: C-28A
GC/MS Semivolatiles
Work Order .... : F60WF1AP Matrix •.•••.••• : WATER '
Date Received .. : 12/18/03 MS Run f. ...... :
Analysis Date .• : 01/05/04
Analysis Time .. : 10:13
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.21 ug/L
ND 1.0 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
59 (30 -121)
71 Ill -119)
62 (39 -115)
52 (37 -115)
55 I 41 -115)
53 I 40 -115)
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I THE RETEC GROUP INC
I Client Sample ID: C-11B
GC/MS Semivolat.iles
I Lot-Sample t ... : C3Ll80138-004 Work Order I. .. : F60WH1AP
Date Sampled ... : 12/17/03 Date Received .. : 12/18/03
Matrix ...•..••• : WATER
MS Run t ....... :
Prep Date ...... : 12/21/03 Analysis Date .. : 01/02/04
I Prep Batch t. .. : 3356504 Analysis Time •. : 17:24
Dilution Factor: 1. 01
Method ......... : SW846 8270C SIM
I REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 0.20 ug/L
I Pentachlorophenol ND 1.0 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
I Nitrobenzene-d5 47 (30 -121)
Terphenyl-dl4 55 Ill -119)
2-Fluorobiphenyl 53 (39 -115)
I 2-Fluorophenol 45 (37 -115)
Phenol-d5 47 I 41 -115)
2,4, 6-Tribromophenol 48 (40 -115)
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ANALYTICAL REPORT
Morrisville, Raleigh MNA
Lot#, C3Ll70252
Gregory Ma.lzone
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
Veronica Bortot
Project Manager
Jahuary l2, 2004
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238
STL
Tel, 412 820 8380 Fax, 412 820 2080
www.st!-inc.com
Severn Trent laboratories, Inc.
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NELAC REPORTING:
The foTIDat and content Of the attached report meets NELAC standards and guidelines eX.cept as noted in the narrative. The table below·
presents a rurninary of the certifications h~ld by STL Pittsburgh. Our primary accreditation authority for the Non-potable water and Solid
& HizardoUS waste pi:"ograms is NeW York State DOH. A mot'e detailed parameter list is available upOn request. Please ask your project
manager for_thiS information when requireci ·
The codes utilized for program types are described below:
HW
WW
X
Hazardous Waste certification
Non-potable Watr::r and/or Wastew"ater certification .
l:aboratory has some form of certification under the specific program. Many states certify laboratories for specific parametCrs or
tests within a category. The information in the table indicates the !ab is certified in a general category of testing. Please contact
the laboratory if parameter specific certification information is required.
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Morrisville
STL Lot# C3Ll 70252
STL Pittsburgh, PA received one sample on December 17, 2003 in good condition. The
coolers were received within the proper temperature range.
Three samples were received labeled B-14B. The samples were logged in according to
the chain of custody as C-14B.
If project specific QC was not required for samples contained in this report and batch QC
was completed on these samples, anomalous results will be discussed below.
GC/MS Semivolatiles:
The reporting limits were adjusted according to the amount of sample extracted.
Sample C-27 A was spiked with SIM surrogate and had the surrogate recovery of
nitrobenzene-d5 outside control limits.
The LCS/LCSD for batch 3357187 have the recovery of 4-nitrophenol below control
limits. This LCS/LCSD was spiked at the SIM levels. Therefore, this compound is likely
to recover low.
GC/MS Semivolatiles SIM:
The reporting limits were adjusted according to the amount of sample extracted.
Dissolved Gases:
The STL North Canton, OH laboratory analyzed the dissolved gases.
C-29B was analyzed within hold time but had to be reanalyzed due to a lab prep error.
The first reanalysis was not the correct dilution. The third reanalysis which is reported
was outside of hold time and was prepped from a compromised vial since the original 2
vials received had already been opened.
Metals:
Comparison of the total and dissolved digestate results of sample C-1 OA, the
concentrations of iron and/or manganese were higher in the dissolved analysis than in the
total analysis. The raw samples were analyzed and confirmed the results of the
digestates.
General Chemistry:
The STL North Canton, OH laboratory analyzed the ferrous iron.
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CASE NARRATIVE
THE RETEC GROUP
Raleigh, Morrisville
STL Lot# C3Ll 70252
Sample C-27 A was analyzed at a dilution for chloride.
-
STL Chain of
Cqstody Record Severn Trent Laboratories, Inc.
STL 4124 (0901)
Cflent Prof~~~~-\< "-1
Date Chain of Custodv Number
~e,-\--ec.-/<f3Ul1..LR. 12/t&/t:>3 1/17/177
Address -I-I lq~ "'-'-1 <; 'i Sw k._ J(51) TelephDne Number (Area Code)/Fax Number Lab Number.
\0J). 6. \\)c., 9\'i. '-J-v'-L z;z,,,,c, • <t/Z•eZO,B3<oo Page of
City ,~•(_ /"P'Z,~~?J Site Contact Lab Contact i:i Analysis (Attach list if
1),..\ ( ~ "" .J·S.Je-vui.; V.)5~ more soace is needed
P~C:{ an} l~c~;;~~:e: I k_ Carrier/Waybill Number
V
l t,,.Jc,,) -1 -"' "0.tJA --'t 0 ~ .'/? 7 Special Instructions/ -fl C\ l:. ' ~ Contract/Purchase Order/Ouo/e No. 2 Ii Conditions-of Receipt
&A 'l-:t . 6"'3(,, 2 '-{' oq/ Matrix Containers & I I Jj -Preservatives jfj IQ tjl i ., 0
Samp/~ 1.0. No. and Description 1 ~ ~ " , ,, Q_s <, ~ ~ Date Time ~ ;g i G 0 io -j ~ ]'.Ji.,., IJ"" (Containers for each sample may be combined on one line) ~ < ~ § , ~ ~~
C.-loA 121\1,,/0 3 /o3o )<l ' I/ I'' ,,; I l I 1 I .2. l 3 2
C.-· /06 11>~5
C· 12-A 1125
{. J9A-o©o
,,.. · 11-B CB35
r / 'J.i r;i, 13?)5 '.
G-/lfB /3W 'I-
C· 2iB v l'ft2.. \ 1 ( V X )o )o
Possible Hazard Identification I Sample Disposal (A fee may be assessed ii samples are retained
0 Non-Hazard D Flammable D Skin Im/ant D PoisonB D Unknown D Return To Client 0 Disposal By Lab D -Archive For Months longer than t month)
QC Requirements (Specify)
0 70ays D 14 Days D 21 Days D Other
Time· 1t';od Date
/5150 18 oo
Oat Time 2. Received By Date
3. Re/inqwshed By Date Time ·3. Received By Date
Comments
DISTRIBUTION: WHITE· Returned lo Client wllh Report: CANARY -Stays with the Sample; PINK· Field Copy -------------
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METHODS SUMMARY
PARAMETER
Alkalinity, Total
Bicarbonate alkalinity
Carbonate Alkalinity
C3Ll70252
Chloride (Colorimetric, Automated Ferricyanide)
Dissolved Gases in Water
Ferrous Iron (Phenanthroline Method)
Nitrate as N
Semivolatile Organic Compounds by GC/MS
Sulfate
ANALYTICAL
METHOD
SM18 2320 B
SM18 2320 B
SM18 2320 B
MCAWW 325.2
RSK SOP-175
SM18 3500-FE
SW846 9056
SW846 8270C
SW846 9056
D
Sulfides, Total 9030B/9034
Total Organic Carbon
SW846 9030B/903
Trace Inductively Coupled Plasma (ICP) Metals
Trace Inductively Coupled Plasma (ICP) Metals
8270C (SIM)
References:
SW846
SW846
SW846
SW846
90 60
6010B
6010B
8270C SIM
MCAWW ''Methods for Chemical Analysis of Water and Wastes'',
EPA-600/4-79-020, March 1983 and subsequent revisions.
RSK Sample Prep and Calculations for Dissolved Gas Analysis
PREPARATION
METHOD
SM18 2320 B
SM18 2320 B
MCAWW 325.2
RSK RSKSOP-175
SW846 9056
SW846 3520C
SW846 9056
SW846 9030B/903
SW846 9060
SW846 3005A
SW846 3010A
SW846 3520C
in Water Samples Using a GC Headspace Equilibration
Technique, RSKSOP-175, REV. 0, 8/11/94, USEPA Research Lab
SM18
SW846
''Standard Methods for the Examination of Water and
Wastewater11 , 18th Edition, 1992.
"Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods'', Third Edicion, November 1986 and its updates.
I
SAMPLE SUMMARY I
C3Ll70252
I SAMPLED SAMP
WO# SAMPLE# CLIENT SAMPLE ID
F6WRC 001 C-lOA
DATE TIME I 12/16/03 10:30
F6WOD 002 C-108 12/16/03 -10: 25
F6WOF 003 C-12A
F6WOJ 004 C-27A
12/16/03 11: 25 I 12/16/03 08:50
F6WOL 005 C-13B 12/16/03 13: 35
F6WOQ 006 C-14B
F6W05 007 C-29B
F6W3L 008 C-27B
12/16/03 13:20 I 12/16/03 14: 42
12/16/03 08:35
NOTE(S):
• The analytical results of the samples listed above are presented on the following pages. I
• All calculations are performed before rounding to avoid round-off errors in calculated results.
• Results noted as "ND" were not detected at or above the stated limit.
-This report must not be reproduced, except in full, without the written approval of the laboratory.
-Results for thl? following parameters are never reported on a dry weight basis: color, corrosivity, density, flashpoint, tgnitability, layers, odor, I
paint filter test, pH, porosity pressure, reactivity, redox potential, specific gravity, spot tests, solids, solubility, temperature, viscosity, and weigh!.
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I Lot-Sample t ... : C3Ll70252-001
Date Sampled ... : 12/16/03
Prep Date ...... : 12/18/03
Prep Batch t ... : 3352335
Dilution Factor: 1. 19 I
I PARAMETER
2,4-Dichlorophenol
I Pentachlorophenol
SURROGATE
I Nitrobenzene-dS
Terphenyl-d14
2-Fluorobiphenyl
I 2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
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THE RETEC GROUP INC
Client Sample ID: C-lOA
GC/MS Semivolatiles
Work Order .... : F6WRC1AP
Date Received_ . : 12/17 /03
Analysis Date ... : 12/31/03
Analysis Time .. : 17: 01
Method ......... : SW846 8270C
REPORTING
RESULT LIMIT
ND 0.24
ND 1.2
PERCENT RECOVERY
RECOVERY LIMITS
55 (30 -121)
65 Ill -119)
58 (39 -115)
47 (37 -115)
50 I 41 -115)
50 I 40 -115)
Matrix .•••••... : WATER
MS Run J ..•.... :
SIM
UNITS
ug/L
ug/L
Lot-Sample t ... : C3Ll70252-002
Date Sampled ... : 12/16/03
Prep Date ...... : 12/18/03
Prep Batch t ... : 3352335
Dilution Factor: 1.04
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
SURROGATE
Nitrobenzene-d5
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
THE RETEC GROUP INC
Client Sample ID: C-10B
GC/MS Semivolatiles
Work Order i. .. : F6WOD1AP Matrix ...•....• : WATER
Date Received .. : 12/17/03 MS Run i ....... :
Analysis Date .. : 01/02/04
Analysis Time .. : 11: 03
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.21 ug/L
ND 1.0 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
54 (30 -121)
79 Ill -119)
55 (39 -115)
48 (37 -115)
54 (41 -115)
49 (40 -115)
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I THE RETEC GROUP INC
I Client Sample ID: C-12A
GC/MS Semivolatiles
I Lot-Sample i. .. : C3L170252-003 Work Order i. .. : F6WOF1AP
Date Sampled ... : 12/16/03 Date Received __ : 12/17/03
Matrix ......... : WATER
MS Run i ....... :
Prep Date ...... : 12/18/03 Analysis Date .. : 01/02/04
I Prep Batch t ... : 3352335 Analysis Time .. : 11: 30
Dilution Factor: 1.16
Method ......... : SW846 8270C SIM
I REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 0.23 ug/1
I Pentachlorophenol ND 1. 2 ug/1
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
I Nitrobenzene-dS 55 (30 -121)
Terphenyl-d14 95 (11 -119)
2-Fluorobiphenyl 60 (39 -115)
I 2-Fluorophenol 50 (37 -115)
Phenol-dS 56 I 41 -115)
2,4,6-Tribromophenol 60 I 40 -115)
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THE RETEC GROUP INC I
Client Sample ID: C-27A
GC/MS Semivolatiles I
Lot-Sample i ... : C3L170252-004 Work Order JI ••• : F6WOJ1AP
Date Sampled ... : 12/16/03 Date Received .. : 12/17/03
Prep Date ...... : 12/18/03 Analysis Date .. : 01/02/04
Matrix ......... : WATER
MS Run t ....... : I
Prep Batch t ... : 3352335 Analysis Time .. : 11: 57
Dilution Factor: 1.06
Method ......... : SW846 8270C SIM I
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 0.21 ug/L I
Pentachlorophenol ND 1.1 ug/L
PERCENT RECOVERY I
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 47 (30 -121)
Terphenyl-d14 90 111 -119)
2-Fluorobiphenyl 51 (39 -115) I
2-Fluorophenol 44 (37 -115)
Phenol-d5 49 I 41 -115)
2,4,6-Tribromophenol 53 I 40 -115) I
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Lot-Sample i ... : C3Ll70252-005
Date Sampled ... : 12/16/03
Prep Date ...... : 12/18/03
Prep Batch i ... : 3352335
Dilution Factor: 1.06
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
SURROGATE
Nitrobenzene-d5
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE (S):
J Estimated result. Result is less than RL.
THE RETEC GROUP INC
Client Sample ID: C-13B
GC/MS Semivolatiles
Work Order i ... : F6WOL1AP
Date Received .. : 12/17/03
Analysis Date .. : 01/02/04
Analysis Time .. : 12: 24
Matrix ... ___ ... : WATER
MS Run f ...•... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.21 ug/L
0.098 J 1.1 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
54 (30 -121)
84 Ill -119)
58 (3 9 -115)
48 (37 -115)
54 I 41 -115)
55 I 40 -115)
Lot-Sample t ... : C3Ll70252-006
Date Sampled ... : 12/16/03
Prep Date ...... : 12/18/03
Prep Batch# ... : 3352335
Dilution Factor: 1.04
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
SURROGATE
Nitrobenzene-d5
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4 1 6-Tribromophenol
THE RETEC GROUP INC
Client Sample ID: C-14B
GC/MS Semivolatiles
Work Order t ... : F6WOQ1AP
Date Received .. : 12/17/03
Analysis Date .. : 01/02/04
Analysis Time .. : 12:52
Matrix ...•••.•• : WATER
MS Run i ....... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.21 ug/L
6.4 1.0 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
46 (30 -121)
73 (11 -119)
51 (39 -115)
45 (37 -115)
41 I 41 -115)
49 I 40 -115)
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Lot-Sample i ... : C3Ll70252-008
Date Sampled ... : 12/16/03
Prep Date ...... : 12/18/03
Prep Batch •-.. : 3352335
Dilution Factor: 1.1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE (SI:
J Estimated result. Result is less than RL.
THE RETEC GROUP INC
Client Sample ID: C-27B
GC/MS Sernivolatiles
Work Order i. .. : F6W3LlAP Matrix ....•.... : WATER
Date Received .. : 12/17/03 MS Run J ....... :
Analysis Date .. : 01/02/04
Analysis Time .. : 13:19
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
NO 0.22 ug/L
0.44 J 1.1 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
63 (30 -121)
84 Ill -1191
73 (39 -115)
57 (37 -115)
66 I 41 -115)
67 (40 -115)