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Home My WebLink AboutNCD003200383_19930831_Koppers Co. Inc._FRBCERCLA C_Demonstration of the Base-Catalyzed Decomposition Technology and the SAREX THERM-O-DETOX System-OCRI I I I I I I I I I I I I I I I I I I UNITED STATES ENVIRONMENT AL PROTECTION AGENCY Demonstration of the Base-Catalyzed Decomposition Technology and the SAREX® THERM-0-DETOX™ System Koppers Company Superfund Site EPA Region 4 August 31, 1993 Visitors' Day Packet SUPfRFUND INNOVATIVE TECHNOLOGY EVALUATION OFFICE OF RESEARCH AND DEVELOPMENT OFFICE OF SOLID WASTE AND EMERGENCY RESPONSE (i,_-+, -¢7 Photocopied on Recycled Paper TABLE OF CONTENTS SECTION PAGE Foreword ........................................................ . Visitors' Day Agenda .................... . EPA SITE Program .................................................. 2 Demonstration Site . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 Technology ........................................................ 9 Demonstration Approach . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13 Notes . . . . . . . . . . 18 SITE Document Order Form . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21 SITE Videotape Request Form . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25 FIGURES PAGE Figure I: Types of Technologies in the Demonstration Program ...................... 3 Figure 2: Site 2 Location Map . . . ........................ 7 Figure 3: BCD Technology and the SAREX® THERM-0-DETOX" System . . . . . . . 10 Figure 4: BCD Technology and the SAREX® THERM-0-DETOX" System Sampling Locations . 16 TABLES PAGE Table I: Sampling Locations and Descriptions ................................ 15 I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I Foreword The U.S. Environmental Protection Agency"s (EPA) Office of Research and Development (ORD), EPA Region 4. and the North Carolina Department of Environment. Health, and Natural Resources (NC-DEHNR) is sponsoring a Visitors' Day for the Superfund Innovative Technology Evaluation (SITE) demonstration of ETG Environmental, Inc. 's. (ETG) Base-Catalyzed Decomposition (BCD) technology and the SAREX® THERM-O-DETOX'" system. This Visitors' Day packet contains information about the SITE Program. the treatment process. Koppers Company Superfund site. and the criteria and methods for evaluating the technology. Contacts are listed at the end of each section. In addition. this packet includes a section for notes and order forms for SITE Program publications and videos. Visitors' Day Agenda 10:00 -10: 15 a.m. 10: 15 -10:45 a.m. 10:45 - l l: 15 a.m. 11:15-ll:45 a.m. l l :45 a.m. -12: 15 p.m. 12: 15 -12:30 p.m. 12:30 -1:15 p.m. 1:15 -1:30 p.m. 2:00 -2:45 p.m. Registration Welcome SITE Program Overview History and Description of the Demonstration Site Technology Description Technology Demonstration and Evaluation Approach General Question and Answer Period Lunch (available in cafeteria at visitors' own expense) Board Bus to Koppers Site Viewing of Technology Demonstration Cindy Loney PRC Environmental Management, Inc. Terry Lyons EPA SITE Project Manager Beverly Hudson EPA Region 4 Remedial Project Manager Dr. Yei-Shong Shieh ETG Environmental, Inc. Robert Hutcheson PRC Environmental Management. Inc. Terry Lyons -Moderator EPA SITE Project Manager EPA SITE Program ■ The Superfund Amendments and Reauthorization Act of 1986 (SARA) directed EPA to develop a program that promotes alternative or innovative technologies for remediating hazardous waste sites. 11 In response, EPA ORD established the SITE Program. which has four components: II ■ ■ • • • Demonstration Program -Conducts and evaluates demonstrations of promising innovative technologies to provide reliable performance, cost. and applicability information for site cleanup decision-making Emerging Technology Program -Provides funding to developers to continue research efforts at the bench-and pilot-scale levels to promote the development of innovative technologies Monitoring and Measurement Technologies Program -Develops technologies that detect. monitor. and measure hazardous and toxic substances to provide better, faster, and more cost-effective methods for producing real-time data during site characterization and remediation o Technology Transfer Program -Disseminates technical information on innovative technologies to remove impediments! for using these technologies I The evaluation of the BCD technology and the SAREX® THERM-O-DETOX" system is part of the SITE Demonstration Program. This program focuses ori evaluating a full-scale technology to: • • Develop credible, objective data on a technology's performance, operation . and cost Publicize these findings to EPA regions, remediation firms, responsible parties. and other interested parties. through publications and conferences • Encourage advancement of technologies for commercial use Each year. EPA ORD solicits proposals from technology developers for the Demonstration Program. Since the first solicitation in 1987, EPA ORD has accepted 94 technologies into the Demonstration Program and has demonstrated 46 of these technologies. Figure I shows the types of technologies currently participating in the Demonstration Program. For each technology accepted into the program, EPA ORD selects a hazardous waste site where the technology will be demonstrated. Technology-site matches are made through EPA regional nominations, developer nominations, other agency nominations, and database searches. 2 I I I I I I I I I I I I I I I I I I I I I EPA SITE Program Biological 18 Thermal Destruction 9 Physical/Chemical -===T,77-,._ 34 Solidification/ Stabilization 11 Materials Handling 3 Radioactive 2 Thermal Desorption 16 I I I I I I I I I I I I I I I I I Figure 1 -Types of Technologies in the Demonstration Program 3 EPA SITE Program ■ Technology demonstration activities generally fall into three categories: pre-demonstration. demonstration. and post-demonstration. These activities are listed by category below: Pre-demonstration: Activities • Site selection • Waste characteri1.ation • Treatability testing • Demonstration Plan preparation • Site preparation • Equipmt!nt mohilization Demonstration: Activities • Equipment operation • Process monitoring an<l measurement, an<l samplt! collection and analysis • Field audit • Visitors· Day Post-demonstration: Activities • Equipment demobilization • Site restoration • Laboratory audit • Technology evaluation • Technology trans for (bulletins, reports. videotape. and conferences) Resnonsihle Organizations EPA ORD, EPA regions, state agencies, and developer EPA ORD. EPA regions. and state agencies EPA ORD and developer EPA ORD EPA ORD Devdoper Responsible Organizations Developer EPA ORD EPA ORD EPA ORD, EPA regions. state agencies. developer, and other interested parties Resnonsihle Organizations Devd<iper EPA ORD EPA ORD EPA ORD EPA ORD 4 I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I EPA SITE Program SITE Program Contact For more information on this technology demonstration or the SITE Program, please contact: Terry Lyons U.S. EPA SITE Project Manager Risk Reduction Engineering Laboratory 26 West Martin Luther King Drive Cincinnati. Ohio 45268 (513) 569-7589 5 Demonstration Site Description ■ • ■ Historv ■ II ■ ■ • The Koppers Company site is located in the Shiloh community, several miles north of Morrisville, in Wake County, North Carolina. The site covers approximately 52 acres at the intersection of Highway 54 and Koppers Road . (see Figure 2). ETG's BCD technology and the SAREX® THERM-O-DETOX" system are being demonstrated at the Koppers Company site in August 1993. The Koppers Company site is a former wood treating facility. In 1961 the site was sold by Cary Lumber Company to Unit Structures. Inc. and again sold in 1962 to Koppers Company. In 1986, the majority of the site was sold to Unit Structures (unrelated to the previously mentioned Unit Structures. Inc.). In 1988 Koppers Company was bought by Beazer East, Inc. (Beazer). Between 1968 until 1975 a process called CELLON was used to treat wood in the southeastern section of the site. The area is called the CELLON processing area and the former lagoon area on Figure 2. The treatment consisted of steaming the wood after pentachlorophenol (PCP) had been pressure-applied to the wood. Water generated from the steam. known as rinsate. was collected and processed to remove the PCP by means of flocculation. The rinsate was then placed in two lagoons on the site for further treatment: however. the final rinsate did contain amounts of PCP. In 1976. the two lagoons at the site were dosed. The water from the lagoons was sprayed onto the ground at the north end of the site. and the lagoon bottom sludges were mixed with surrounding soil and spread to dry in the former lagoon area. Both areas were fertilized and seeded. In 1980. high levels of PCP were found in the soils of the former lagoon area and the CELLON processing area. PCP was also detected in the groundwater. During several separate actions between I 980 and I 986. over I. 710 cubic yards of contaminated soil was removed from the area by Koppers Company. Contaminated soil was reportedly hauled to a permitted facility for proper disposal. 6 I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I i I I Demonstration Site LEGEND • EXISTING WELLS -PROPERTY BOUNDARY --UNIT STRUCTURES/ KOPPERS SITE PROPERTY LINE FIRE POND Figure 2 -Site Location ivfap 7 ew-3 Demonstration Site ■ In June 1980. the NC-DEHNR conducted an inspection of the site. Seven monitoring wells were installed around the plant by Koppers Company in July 1980. ■ ■ a NC-DEHNR recommended in June 1988 that the site be included on EPA's National Priorities List (NPL). This was finalized in March 1989. In December 1992 the Record of Decision (ROD) was signed. A primary and contingency remedy was selected for soils. The primary remedy consists of soil excavation and off site incineration. The contingency remedy consists of using the BCD technology. For groundwater at the site. carbon adsorption was selected. For surface water at the site, pond dewatering was chosen. Treatability studies of the BCD process will he conducted on soils at the site. Based on the results from these studies. the BCD technology may be selected to remediate the site. Waste Characteristic.~ a Through a remedial investigation. contaminants identified at the site include PCP, polychlorinated dibenzo-p-dioxins (PCDD), polychlorinated dihenzofurans (PCDF), and isopropyl ether (!PE). Demonstration Contact for the Koppers Companv Superl'und Site For additional information about the site, please contact: Beverly Hudson. Remedial Project Manager or Diane Barrett. NC Community Relations Coordinator North Superfund Remedial Branch Waste Management Division U.S. Envrionmental Protection Agency, Region 4 345 Courtland Street. NE Atlanta, Gerogia 30365 (800) 435-9233 For written information concerning site activities and documents developed during the Superfund process, visit the information repository located at: Wake County Public Library Cary Branch 310 South Academy Street Cary, North Carolina 27511 8 I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I Technology Background • • EPA's Risk Reduction Engineering Laboratory (RREL) in Cincinnati. Ohio developed and patented the BCD technology. ETG and Separation and Recovery Systems, Inc. (SRS) developed the SAREX"' THERM-0-DETOX'" system to be used with the BCD technology. Through a cooperative effort between the EPA SITE Program, EPA Region 4, the NC-DEHNR, the BCD technology will be evaluated at the Koppers Company Superfund site in Morrisville. North Carolina. The technology demonstration will determine how effectively the BCD technology, in conjunction with the SAREX® THERM-0-DETOX'" system, removes PCP and furans from the soil at the site. Process Description • • II II The BCD physical/chemical process detoxifies and chemically decomposes contaminants by removing chlorine atoms. The BCD process can decompose polychlorinated biphenyls (PCB), PCP. chlorinated dibenzodioxins and tiirans. insecticides, and herbicides. The SAREX"' THERM-0-DETOX'" system is based on indirect-heat by low and medium temperature thermal desorption (L TTD and MTTD) units. The units are equipped with a multiple-shaft agitator for high heat transfer efficiency, excellent local mixing action, and retention-time variability (see Figure 3). TI1e process begins hy mixing an inorganic dechlorination reagent with the contaminated soil. sediment, or sludge. The mixture is heated in the MTTD unit for about I hour at 650 °F to 800 °F. Some of the chlorinated contaminants are decomposed during this step. The remaining organic contaminants are thermally desorbed and removed with the off-gas. Clean soil exiting the MTTD can be returned to the site. The remaining contaminants from the vapor condensate and residual dust are captured and treated for 2 to 4 hours at about 650 °Fin a liquid-tank reactor (L TR). The L TR uses a high-boiling-point hydrocarbon. a proprietary catalyst. and sodium hydroxide. Nitrogen is purged through the L TR to control oxygen levels. preventing the tank contents from oxidizing or igniting. 9 Technology CONTAMINATED MATERIALS OR SCREENED SOILS VAPOR RECOVERY SYSTEM r-----------, FEED HOPPER DECHLORINATION REAGENTS LOW TEMP. THERMAL DESORPTION UNIT (LTTD) VAPOR DISCHARGES I\ n c ~'CJ O V MEDIUM TEMP. THERMAL DESORPTION UNIT (MTTO) WATER SPRAY COOLING SCREVI CONVEYOR TO ATMOSPHERE ON-SrrE 0 ~ACKFILI_ __ _,',$i!B,V OFF-SITE DISPOSAL ~ DECONTAMINATED SCUDS CONTAINER CONDENSER UNIT ~~~-OIL ADDITIVE TRE,tTED WATER DECHLORINATION REAGENTS IBEATED ~- CONDENSER CONDENSATE TANK Figure 3 -The BCD Technology and the SAREX® THERr.1-0-DETOXr" System 10 I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I Technology • Oily residuals remaining in the L TR contain dust and sludge and are combustible. They can be burned in an oil-fired power plant, a cement kiln. or treated and reclaimed by waste oil recyclers. The aqueous condensate from the process can be discharged to a publicly-owned treatment works after being pumped through an activated carbon treatment process. Decontaminated sludge can be disposed of in the same manner as municipal sludge. Spent carbon from the water polishing can also he treated in this process. 11 The only by-products produced by the BCD process are nonchlorinated hydrocarbons. low- boiling olefinics. and sodium chloride. BCD Chemistry The base-catalyzed reaction to dehalogenate halogenated compounds can be generalized as follows: • • • • R' R-H + NaCl catalyst R-(Cl), represents halogenated compounds such as PCP, PCBs, 2,4-dichlorophenoxyactic or 2.4,5-trichlorophenol, and dioxins. R' represents the hydrogen donor. + R" Chloride on R-(Cl), is replaced by H to produce R-H. R, donates hydrogen and becomes R'' with the formation of sodium chloride (NaCl). This reaction rnmpktely dehalogenates halogenated compounds . II Technology Equipment ■ ■ ■ • The system includes the following components: (I) a medium-temperature thermal desorption (MTID) unit, (2) a vapor recovery system, and (3) a liquid-tank reactor (L TR), (see Figure 3). Off-gas emissions are extremely low, and organic vapors are condensed and removed. The technology has minimum environmental impact and few permitting requirements. The treated soil discharged from the MTID unit is free of organic contaminants, maintains its physical characteristics, and is suitable for on-site backtill. The system can he installed on two to three trailers for ease of mobilization . Operation ■ The system will he demonstrated owr a period of 3 weeks. Because this is a pilot-scale remediation. ETG will vary the operating parameters during the technology demonstration to determine optimal conditions for the project. ■ Operating temperature, feed rate. reagents. and off-gas tlow rate will he predetermined for each of the six test runs. Factors Affecting Performance • System performance could he affected by the following factors: • • • • • Degree of mixing Heat transfer Material temperature Retention time Reagent types and quantities ETG Technology Contact For more information on the system. please contact: Dr. Yei-Shong Shieh ETG Environmental. Inc. 660 Sentry Parkway Blue Bell. Pennsylvania I 9422 215-832-0700 12 I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I Demonstration Approach Technology Demonstration Objectives ■ The following objectives have been identified by the EPA SITE Program. EPA Region 4, NC-DEHNR. the technology developers (ETG and SRS). and Beazer (Koppers Company's owner). ■ • • • • Assess the technology's ability to treat contaminated soil to levels determined in the site's ROD Determine whether process effluents meet appl i<:able local. state. and federal standards for disposal or discharge Evaluate potential effects on PCP and furans, such as formation of other hazardous by-products resulting from the thermal reactions of chemicals in the BCD process. Develop capital and operating cost estimates Identify specific operating and maintenance concerns that may affect the system's long-term reliability Demonstration Program Test Runs II A total of eight test runs will be conducted to attain the above objectives. six runs using the solids reactor and two runs using the liquid reactor. ■ Operating conditions for the first four solids runs will be varied slightly to determine which exhibit the greatest contaminant reduction and meet cleanup levels. The last two solids runs will use the optimum operating conditions determined during the first four solids runs. Sampling and Analvsis Program ■ The overall sampling objective is to produce well-documented, defensible data that are of known quality and are reproducible. For this reason. EPA prepared a Category II quality assurance project plan (QAPP) that details sampling, analytical. quality assurance. and quality control procedures. Specific sampling objectives are as follows: • Collect samples that are representative of the sampled media • • Collect and analyze samples for target compounds necessary to determine the BCD system's performance Verify the reproducibility of the treatment system's performance 13 Demonstration Approach Sampling and Measurement Loca1ions II II Locations at which samples will be collected are discribed in Table I and shown in Figure 4. These samples will be analyzed for the target compounds and physical charac1eristics (for example moisture content) needed to document the system's performance. Various process measurements will be recorded on log sheets to document the operating conditions during each run. Examples of these measurements include waste feed rate and reactor temperature. ■ The process conditions to be varied include the lemperature settings of the solids reactors and lhe addition of lhe catalyst. The low tempera1ure and medium temperature thermal desorption units will operale at the same temperature. During test run I and 2 they will be operated at 800 "F, and during test runs 3 and 4 1hey will operate al 650 "F. The catalyst will be added during runs I and 3. Oualitv Assurance Ohjeclives and Audits II II The quality assurance objective for this demonstra1ion is to produce well-documented data of known quality. Quality is measured hy the da1a's precision, accuracy, completeness, representativeness, and comparabil icy. EPA will audit both 1he field demonstration and the laboratory analysis to verify the following: • • The sampling, analytical. quality assurance, and quality control procedures from the approved quality assurance project plan (QAPP) are properly implemented Modifications to 1he approved field or laboratory procedures are appropriate 14 I I I I I I I I I I I I I I I I I I I I I Demonstration Approach I Table 1 -Sampling Locations and Descriptions I I Sampling Description Location l Contaminated soil after si::e red11ction. The conlaminated soil will be excavated, screened to less than I 1/2-inch, and contained in 55-gallon drums. Random grab samples will be taken from the 55-gallon drums before and after the addition of the catalyst. One composite sample per two drums will be generated from the grab samples and submilted for analysis. I 2 Treated soil. Treated soil will be sampled as it is discharged from the tv1TID unit after cooling water is added in the cooling screw conveyor. One composite sample pL:r two drums will be generated from the grab samples and submitted for analysis. I 3 Reactor off-gas. The rea<.:tor off-gas wil! be sarnpkd from ports in th1: pipe exiting the reactor before discharge. 4 Stack gas. Gases from the L TIO and MTTD oil/watcr scrubber system and from thl.! L TR will be I sampled alter discharge from the carbon polishers. 5 LTR i11jlue11t. The L TR inHucnt will consist of 10 to 60 gallons oi oil collected from the soil scrubber system. The scrubber system oil in the LTR will be sampled before the addition of reagents. I 6 LTR ejJluent. After the L TR batch test is complete and allowed to cool, the reactor effluent will be sampled from the reactor tank. I 7 LTR ~!fgas. The L TR off-gas wil! be sampled al two stages of each batch test. The first reactor off-gas sall1ple will be collected aJkr the initial n.::actor heat-up. The second reactor off-gas sample will be colk:cted before completion of the batch tl.!st. The sample will be collected before condensing off-gas. I 8 Co,u/ensate waler. Condensate water will be colkcted from the condensate storage lank before treatment in the carbon unit. 9 Treated wasrewarer. The treated wastewater will be sampled from thc treated wastewater storage tank. I I I I I I 15 I Demonstration Approach CONTAMINATED MATERIALS OR SCREENED SOILS -----V_A_POR RECOVERY SYST=EM;;_ ___ ~ VAPOR DISCHARGES FEED HOPPER DECHLORINATION REAGENTS LOW TEMP. THERMAL DESORPTION UNIT (LTTD) 0 MEDIUM TEMP. THERMAL DESORPTION UNIT (MTTD) ON-SITE BACKFIU. OR OFF-SITE DISPOSAL WATER SPRAY TO ATMOSPHERE CARBON POLISHER V DECONTAMINATED SOLIDS CONTAINER 0 CONDENSER UNIT --''-~OIL ADDITIVE 0 ffiEATEO W.O.TER 0 LIQUID TANK REACTOR (LTR) DECHLORINATION REAGENTS ' CONDENSATE TANK Figure 4 -The BCD Technology and the SAREX® TI-IERJ\1-0-DETOX™ System Sampling Locations 16 I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I Demonstration Approach Documentation of Demonstration Results • EPA will publish the following reports documenting the technology demonstration results: • • • • Demonstration Bulletin Project Summary Technology Evaluation Report Applications Analysis Report These reports for the BCD technology and the SAREX" THERM-O-DETOX'" system demonstration will be available in 1994. EPA will also produce a technology demonstration video documenting the demonstration activities. Order forms listing all documents and videos available under the SITE Program are located at the end of this document. Demonstration Activities Contact For further information about the demonstration approach and activities. please contact: Robert Hutcheson PRC Project Manager 285 Peachtree Center Avenue. Suite 900 Atlanta. Georgia 30303 (404) 522-2867 17 Notes IS I I I I I I I I I I I I I I I I I I I I Notes I I I I I I I I I I I I I I I I 20 I I I I I I I I I I I I I I I I I I I I I oEPA .Documents Available from the. U.s: EPA Risk Reduction Engineering Laboratory Superfund Technology Demonstration Division• General Publications 0 0 0 SITE Program: Progress and Accomplishments for FY9I- A Fifth Report to Congress (EPA/540/R-92/076) SITE Profiles, Fifth Edition (EPA/540/R-92/077) · Survey of Materials Handling Technologies Used at Hazardous Waste Sites (EPA/540/2-91/010) Demonstration Project Results American Combustion- Oxygen Enhanced lncinemlion 0 Technology Evaluation (EP N540/5-89/008) 0 Applications Analysis (EPN540/A5-89Jl)()8) 0 Technology Demo. Summary (EP N540/S5-89/008) 0 Demonstration Bulletin (EP N540/M5-89/008) A WD Technologies, lnc.- l nlegrated Vapor Extraction and Steam Vacuum Stripping 0 Applications Analysis (EPN540/A5-91Jl)()2) 0 Demonstration Bulletin (EPN540/M5-91Jl)()2) Babcock and Wilcox-Cyclone Furnace Vitrification 0 Technology Evaluation Vol. I (EPA/540/R-92/017A) 0 Technology Evaluation Vol. II (EPN540/R-92/017B) 0 Applications Analysis (EPN540/AR-92/017) 0 Technology Demo. Summary (EPN540/SR-92/017) 0 Demonstration Bulletin (EP N540/MR-92/011) Bergmann USA-Soil/Sediment Washing System 0 Demonstration Bulletin (EPN540/MR-92/075) Biotrol--Biotreatnunt of Groundwater 0 Technology Evaluation (EPN540/5-91/001) PB92-110048** 0 Applications Analysis (EPN540/A5-91/001) 0 Technology Demo. Summary (EPN540/S5-91/001) 0 Demonstration Bulletin (EPN540/M5-91/001) Biotrol-Soil Washing Sysllm 0 Technology Evaluation Vol. I (EPN540/5-91/003a) PB92-l 15310 0 Technology Evaluation Vol. II Part A (EP N540/5-91Jl)()3b) PB92-115328 • Order documents free of charge by calling EPA's Center·for Environmental Research Information (CERI) at 513-569-7562. 0 Technology Ev'aluation Vol. II Part B (EP N540!5-91/003c) PB92-l 15336 0 Applications Analysis (EPN540/A5-91/003) PB92-115245 0 Technology Demo. Summary (EPN540/S5-91/003) 0 Demonstration Bulletin (EPN540/M5-91/003i CF Systems Corp.-Solvent Extraction 0 Technology Evaluation Vol. I (EPA/540/5-90/002) 0 Technology Evaluation Vol. II (EPN540/5-90/002a) PB90,186503 . 0 Applications Analysis (EPN540/A5-90Jl)()2) 0 Technology Demo. Summary (EP N540/S5-90Jl)()2) 0 Demonstration Bulletin (EP N540/M5-90/002) Chem.fix Technologies, Inc.- Chemical Fixation/Stabilization 0 Technology Evaluation Vol. I (EPN540/5-89/01 la) 0 Technology Evaluation Vol. II (EPN540/5-89/0llb) 0 Applications Analysis (EPN540/A5-89/0l 1) 0 Technology Demo. Summary (EP N540/S5-89/01 I) 0 Demonstration Bulletin (EPN540/M5-89/011) Dehydro-Tech-Carver-Greenfield 0 Technology Evaluation (EPN540/R-92Jl)()2) 0 Applications Analysis (EPA/540/AR-92/002) 0 Technol.ogy Demo. Summary (EP N540/SR-92/002) 0 Demonstration Bulletin (EPN540/MR-92/002) PB92-217462 Dupont!06er/in:._Miuofi/Jration System 0 Technology Evaluation (EPN540/5-90/007) PB92-153410 0 Applications Analysis (EPN540/A5-90Jl)()7) 0 Technology Demo. Summary (EPN540/S5-90/007) 0 Demonstration Bulletin (EP N540/M5-90/007) 0 Documents with a PB number must be ordered by that number at cost from National Technical Information Service 5285 Port Royal Road Springfield VA 22161 Telephone 703-487-4650. Demonstration ProJ!i!ct Results (continued) EPA-Design and Development of a Pilot-Scale Debris Decontamination System Q Technical Evaluation (EPN540/5-91/006a) Q Technical Evaluation Vol. II (EPN540/5-91,006b) PB9l-231464 Q Technology Demo. Swnmary (EPN540/S5-9l/006) Hazcon-Solidifi.calion Q Technology Evaluation Vol. I (EPN540/5-89/00la) Q Technology Evaluation Vol. II EPN540/5-89/00lb) PB89-l58828 Q Applications Analysis (EPN540/A5-89,001) a Technology Demo. Summary (EP N540/S.5-89/001) ._.,_ ·Q Demonstration Bulletin (EPN540/M5-89/()(Jl) Horsehead Resource Development Q Technology Evaluation Vol I (EPN540/5-9l,005) PB92-205855 Q Applications Analysis (EPN540/A5-91,005) Q Technology Demo, Summary (EPN540/S5-9!/005) Q Demonstration Bulletin (EPN540/M5-9l/005) International Technology Corporation-Sluny Biodegradalion Q Demonstration Bulletin (EPN540/M5-9lft)()9) lWT/GeoCon In-Situ StabiliZJllion Q Technology Evaluation Vol. I (EPN5_40/5-89/004a) Q Technology Evaluation Vol. II (EPN540/5-89ft)()4b) Q Technology Evaluation Vol. ill (EPN540/5-89/004c) PB90-269069 Q Technology Evaluation VoLIV (EPN540/5-89/004d) PB90-269077 Q Applications Analysis (EPN540/A5-89ft)()4) Q Technology Demo. Summary (EPN540/S5-89/004) Q Technology Demo, Summary., Update Report (EP N540/S5-89ft)()4a) Q Demonstration Bulletin (EPN540/M5-89ft)()4) McColl Superfund Site-Demonstration of a Trial Excavation Q Technology Evaluation (EPN540/R-92/015) PB92-226448 Q Applications Analysis (EPN540/AR-92iOl5) Q Technology Demo. Swnmary (EPN540/SR-92/015) Ogden Circu'/ating Bed Combustor-McCoU S~perfund SiJe Q Technology Evaluation (EPN540/R-92,00I) Q. Demonstration Bulletin (EP N540/MR-92/001) * Order ~ocuments free of charge by calling EPA's Center for Environmental Research Information (CERI) at 513-569-7562. Outboard Marin_e Corporation Site-Soiluch Anaerobic Thermal Processor Q Demonstration Bulletin (EP N540/MR-92/078) Retech Plasma Centrifugal Furntue Q Technology Evaluation Vol. I (EPN540/5-9l/007a) PB 92-216035 Q Technology Evaluation Vol. II (EPN540/5-9l,007b) PB92-216043 Q Applications Analysis (EPN540/A5-9l,007) Q Technology Demo. Swnmary (EP N540/S5-9!/007) Q Demonstration Bulletin_ (EPN540/M5-9l,007) ~ Resources Conservation Company---;The Basic Extractive Sludge TreaJment (B.A.SJ.C) , • Q Demonstration Bulletin (EPN540/MR-92/079) Roy F. Weston, lnc.-Low Temperature Thermal Treatment (LT3) System Q Demonstration Bulletin (EPN540/MR-92/019) SBP Technologies-Membrane Filtration Q Demonstration Bulletin (EPN540/MR-92/014) Shirco-lnfrared Incineration 0 Technology Evaluation-Peake Oil (EP N540/5-88/002a) 0 Technology Evaluation-Rose Township (EP N540/5-89/007a) 0 Technology Evaluation-Rose Township Vol. II (EP N540/5-89/007b) PB89-1679!0 Q Applications Analysis (EPN540/A5-89/0l0) Q Technology Demo. Swnmary (EP N540/S5-89/007) Q Demonstration Bulletin (EPN540/M5-88,002) SUicatt Technology Corporation-Solidif"ication/StabiliZJllion of Organic/Inorganic Contaminants Q Demonstration Bulletin (EP N540/MR-92/0!0) Soiltuh ATP Systems-Aostra-Soil-Teth Anaerobic Thermal Process Q Demonstration Bulletin (EPN540/MR-92/008) •• Documents with a PB number must be ordered by that number at cost from National Technical Information Service 5285 Port Royal Road Springfield VA 22161 Telephone 703-487-4650. I I I I I I I I I I I I I I I I I .I I I I .Al, :J, t; .•. _J I I I I I I I •• ;:J I I Demonstration Project Results (continued) SolidiJech, lnc.-Solidif,calion 0 Technology Evaluation Vol. I (EPA/540/5-89/005a) 0 Technology Evaluation Vol. II (EPN540/5-89/005b) PB90-191768 . 0 Applications Analysis (EPN540/A5-89/005) 0 Technology Demo. Summary (EPN540/S5-89/005) 0 Demonstration Bulletin (EPN540/M5-89/005) Terra Vac-Vacuum Extraction 0 Technology Evaluation Vol. I (EPN540/5-89/003a) 0 Technology Evaluation Vol. II (EPA/540/5-89/003b) PB89-192033 0 Applications Analysis (EPN540/A5-89/003) 0 Technology Demo. Summary (EPN540/S5-89/003) 0 Demonstration Bulletin (EPN540/M5-89/003) * Order documents free of charge by calling EPA' s Center for Environmental Research Information (CERI) at 513-569-7562. Thomeco, Jnc.-Enzyme•ActimJed Cellulose Technology 0 Treatability Study Bulle!in (EP N540/MR-92/018) Toronto Harbour CommissWners-Soil RecycUng Treatment Train 0 Demonstration Bulletin (EPN540/MR-92/015) Torie Tnatm,nts (USA}--ln-Situ Steam/Hot Air Stripping 0 Applications Analysis (EPN540/A5-90/008) 0 Demonstration Bulletin (EPN540/M5-90/003) Ultrox International-UV Ozone Treatment for Liquids 0 Technology Evaluation (EPN540/5-89/012) 0 Applications Analysis (EPN540/A5-89/012) 0 Technology Demo. Summary (EPN540/S5-89/012). 0 Demonstration Bulletin (EPN540/M5-89/012) ** Documents with a PB number must be ordered by that number at cost from National Technical Information SeIVice 5285 Port Royal Road Springfield VA 22161 Telephone 703-487-4650. Emerging Technologies Program Reports I I Atomic Energy of Canada ljmited-Chemictil Trtalmenl and UltraFiltraJion 0 · Emerging Tech. Bulletin (EPN540/F-92/002) Babcock and Wilcox-Cycloni Furnace Soil Vitrification 0 Emerging Tech. Bulletin (EPN540/F-92/0!0) Balle/le Memorial lnstitute-i.JevelopmenJ of Electro-Acoustic Soil DeconkJminaJion (ESDJ Process for In Situ ApplicaJions r1'1' 0 Em~fging Technology (EPN540/5-90/004) PB90'.204728 0 Emerging Tech. Summary (EPN540/S5-90/004) : \"' ':I) ... 1, ..• :W . Bio-Recovery Systems:.......Removal and Recovery of Metal Ions. from Groundwater 0 Emerging Technology (EP N540/5-90m5a) 0 Emerging Tech.-Appcndices (EPN540/5-90m5b) PB90-252602 0 Emerging Tech. Summary (EPN540/S5-90/005) 0 Emerging Tech. Bulletin (EPN540/F-92/003) • Order documents free of charge by calling EPA's Center for Environmental Research Wonnation (CERI) at 513-569-7562. · . ' • • . t Colorado School of Mines-Constructed Wetlands Treatment/or Toxic Me'tal Contamin~ted Waters ' 0 Emerging Tech. Bulletin (EPA/540/F-92/001) Ekctr~Pu~ Systems-Alternating Current Ek~trocoagulation 0 Emerging Tech. Bulletin (EPA/540/F-92/011) Energy and Environmental Engineering-Laser~lnduced Photochemical Oxidative Destruction 0 Emerging Tech. Bulletin (EPA/540/F-92/004) '\ffllorida International Universily-Ekctron Beam Treatment/or Jihe Trich/oretechykne and TetrachUJroethykne from Aqueous ,l..•stream 0 Emerging Tech. Bulletin (EPN540/F-92/009) SITE Emerging Techno/ogies-1.aser-lnduced Photochemical Oxidative Destruction of Toxic Organics in l..eachaJes and GroundwaJer 0 Emerging Tech. Bulletin (EPN540/SR-92/080 I I I I I I University of Washington-Metals Treatment aJ Superfund Sites I by Adsorptive Filtration 0 Emerging Tech. Bulletin (EPA/540/F-92/008) ** Documents with a PB nWllbcr must be ordered by that number at cost from National Technical Informatio·n ServiCC 5285 Port Royal Road Springfield VA 22161 Telephone 703-487-4650. I I I I I I I II ECOVA (SHIRCO) INFRARED INCINERATION SYSTEM Brandon, FL -8/87 ULTROX ULTRAVIOLET RADIATION AND OXIDATION San Jose, CA -3/89 E.I. DUPONT/ OBERLIN FILTER MEMBRANE MICROFILTRATION Palmerton, PA -5/90 SYNTHETIC SOILS MATRIX (SSM) PROGRAM ECOVA (SHIRCO) INFRARED INCINERATION SYSTEM Rose Twp., Ml -11 /87 BIOTROL BIOLOGICAL AQUEOUS TREATMENT EMTECH (HAZCON) SOLIDIFICATION PROCESS Douglassville, PA -10/87 BIOTROL SOIL WASHING SYSTEM New Brighton, MN -9/89 New Brighton, MN -9/89 Clackamas, OR -3/89 HORSEHEAD FLAME REACTOR Atlanta, GA -3/91 DIOXIN AND THE MOBILE INCINERATION SYSTEM San Pedro, CA -9/89 RETECH PLASMA CENTRIFUGAL FURNACE Butte, MT -7/91 MOBILE CARBON REGENERATION SYSTEM IWT/GEO-CON INSITU STABILIZATION/ SOLIDIFICATION Hialeah, FL -4/88 IT/AREL DEBRIS WASHING SYSTEM BABCOCK & WILCOX CYCLONE FURNACE Alliance, OH -11/91 MOBILE SOILS WASHING SYSTEM TERRAVAC VACUUM EXTRACTION SYSTEM Groveland , MA - 1 /88 MOBILE IN SITU CONTAINMENT/ TREATMENT UNIT CF SYSTEMS SOLVENT EXTRACTION UNIT New Bedford, MA -3/89 Videotape Order Form Ill, November, 1992 ------------------- I I I I I I I I I I I I I I I I I I I VIDEOTAPE REQUEST FORM ____ __, 1992 Foster Wheeler Enviresponse, Inc. Attn: Ms. Marilyn Avery 8 Peach Tree Hill Road Livingston, NJ 07039 Dear Ms. Avery, Please send us the following USEPA-produced videotapes. I have completed the address information below and enclosed a check in the amount of$, __ made payable to "Foster Wheeler Enviresponse" ($35.00 per tape, plus $10.00 additional per tape for international shipments]. Copies Number S1 Videotape Title SUPERFUND INNOVATIVE TECHNOLOGY EVALUATION (SITE) PROGRAM (6 technology demonstrations) S2 SUPERFUND INNOVATIVE TECHNOLOGY EVALUATION (SITE) PROGRAM (4 technology demonstrations) S3 SUPERFUND INNOVATIVE TECHNOLOGY EVALUATION (SITE) PROGRAM (4 technology demonstrations) S4 SUPERFUND INNOVATIVE TECHNOLOGY EVALUATION (SITE) PROGRAM (4 technology demonstrations) R1 RREURCB RESEARCH PROGRAM (5 programs) (Contents of each tape are listed on the reverse side of this sheet.) (Signed) _________ _ Title Tapes should be sent to the following (Please Print): NAME: COMPANY: ADDRESS: CITY: ________ STATE_ZIP _____ _ (NO REQUESTS WILL BE HONORED WITHOUT PREPAYMENT BY PERSONAL OR COMPANY CHECK.) ACKNOWLEDGMENT, WAIVER AND RELEASE Morrisville, North Carolina superfund Site August 31, 1993 I, the undersigned, have been invited by PRC Environment Management, Inc. ("PRC") and/ or ETG Environmental, Inc. ( "ETG") and/or the United States Environmental Protection Agency. ("EPA") to view today demonstration activities concerning the base- catalyzed decomposition (BCD) technology and THERM-0-DETOX™ system of ETG at the Morrisville Koppers Company, Inc. National Priorities List Site. Because of the configuration of the land owned by Beazer East, Inc. on which the demonstration activities are being conducted, access for the viewing must be had by route of and on land owned by Unit Structures, Inc. ( "USI'') . I understand, acknowledge and agree: (i) that USI is not responsible for the demonstration activities I am to view; (ii) that Beazer East, Inc. ( and not USI) is under an EPA order to remediate the subject site; and (iii) that USI's land over which I will gain access to, and on which I will, view the demonstration activities is largely unimproved industrial land not intended for public pedestrian or vehicular use on which may be located unmarked hazards and other potentially dangerous conditions. In consideration of my being invited by PRC and/or ETG and/or the EPA to view the demonstration activities, on my behalf and on behalf of my heirs and assigns, I hereby waive and release any claim I might otherwise have against USI arising in connection with my acceptance of the invitation of PRC and/or ETG and/or the EPA and my entry onto USI's land, and agree to hold harmless USI from all losses, claims, liabilities, expenses and costs asserted against or incur.red by USI in connection therewith. This acknowledgement, waiver and release is delivered under seal by the undersigned in, and shall be governed by the law of, North Carolina. SIGNATURE PRINTED NAME ADDRESS ADDRESS (CONTINUED)