NCD003200383_19900914_Koppers Co. Inc._FRBCERCLA RA_Dioxin Furan Data Validation-OCR

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PGH-90-TMJ-340
DATE
TO
FROM
SUBJECT
Overview
September 14, 1990
Mr. Roberts. Markwell
Program Manager -Environmental Services
Beazer Materials and Services, Inc.
436 Seventh Avenue
Pittsburgh, Pennsylvania 15219
Thomas Jackman
AWD Technologies, Inc.
Dioxin/Furan Data Validation
Keystone Environmental Job #M90-06.95
AWD
TECIINOI.OGIES
The set of samples for Beazer (sampled 5/30-31/90) contained 8
water samples including 1 pair of duplicates and two blanks.
Samples were analyzed for polychlorinated dibenzo-p-dioxins and
dibenzofurans by high-resolution gas chromatography /high-resolution
mass spectrometry.
summary
All elements were successfully analyzed in all samples with the
exception of those qualified as unreliable, ''R". Areas of concern
with respect to data usability are listed according to the
seriousness of the problem. These include:
Major Issues
OCDD was detected in the TLI and field blanks. Therefore positive
results are qualified ''R'', unreliable.
Minor Issues
In.the comparison of Field Duplicates (Table 1), 1234678 HpCDD and
2378-TCDF exceeded quality control criteria. Therefore positive
results are qualified ''J", estimated.
AWD Technologies, Inc. Penn Center West. Building Ill. Suite 400 Pittsburgh Pennsylvania 15276 Telephone [phone] Telecopier 412 788 1316
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AWD Technologies, Inc.
PGH-90-TMJ-340
Mr. Roberts. Markwell
Beazer Materials and Services, Inc.
September 14, 1990 -Page 2
Notes
All samples were reextracted due to low internal standard
recoveries.
Triangle Laboratories adopted a new procedure for calculating
analyte specific detection limits. This procedure uses 2
representative noise height determinations which are summed and
multiplied by an empirically determined factor before applying the
detection limit equations. The effect of this approach is to
increase the detection limits of the DB-5 column by a factor of 5
and that of the DB-225 column by 3.5. The laboratory states that
the new procedure produces a more accurate estimate of detection
limits.
The laboratory performed the required 5 point initial calibrations
but did not supply raw data and chromatograms for the individual
calibrations. Checks of response factors and retention times
could, therefore, not be performed.
The data were reviewed according to Method 8290 (June 1987), an
isotope-dilution high resolution mass spectrometric version of RCRA
Method 8280 (SW846), Triangle Laboratories' Data User Manual and
the National Functional Guidelines for Evaluating Organic Analyses.
The text of this report addresses only those problems affecting
usability.
Information Regarding Report Content
Table 1 presents results of the Field Duplicate Analysis.
Attachments:
1.
2 •
3 •
. 4.
Glossary of data qualifier codes.
Data Summary. This includes:
a) All positive results with qualifier codes, if applicable;
b) All unusable detection limits qualified with an "R"; and
c) All estimated detection limits qualified with UJ or UL.
Appendix A -results as reported by the laboratory (no
corrections were made during data validation).
Appendix B -Support Documentation includes details to support
the statement in this report.
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AWD Technologies, Inc.
GLOSSARY OF DATA QUALIFIER CODES (DIOXINS)
CODES RELATING TO IDENTIFICATION
(confidence concerning presence or absence of compounds)
< = Not Detected. The associated number indicates approximate
sample concentration necessary to be detected.
(NO CODE) = Confirmed Identification
R = Unreliable Result. Analyte may or may not be present in the
sample. Supporting data necessary to confirm result.
CODES RELATED TO OUANTITATION
(can be used for positive results and sample quantitation limits):
J = Analyte present.
precise.
Reported value may not be accurate or
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AWD Technologies, Inc.
COMPOUND
1234678-HpCDD
2378-TCDF
TOTAL-HpCDD
TOTAL-TCDF
FIELD
27A-FL
(ppt)
0.04
ND
0.07
ND
TABLE 1
DUPLICATE ANALYSIS
27A-FL-DUP
(ppt)
ND
0.006
ND
0.006
RPO
( % )
200
200
200
200
I
I OATA SUMMARY
DIOXIN DATA FOR WATER SAMPLES COLLECTED 5/30-31/1990 I KEYSTONE WORK ORDER I M90-08.95
I Sample No. 27A-FL 27A-FL-DUP
Ii COMPOUND
Field Oupl icates
UNITS EMPC
:2378-TCOO ppt <0.003 <0.005 I: 12378-PeCDD ppt <0.003 <0.008
: 123478-HxC0O ppt <0.003 <0.01
: 123978-HxCDD ppt <0.003 <0.008
1;123789-HxCDD ppt <0.003 <0.01
: 1234978-HpCD0 ppt 0.04 J <0.008
:cx:oo ppt 0.85 R 0.02
'
1;2378-TCDF ppt <0:001 0.008
: 12378-PeCDF ppt <0.003 <0.005
: 23•'78-PeC0F ppt <0.003 <0.008 I : 1234 78-HxCDF ppt <0.003 <0.008
: 123678-HxCDF ppt <0.003 <0.005
:234678-HxCOF ppt <0.003 <0.008
1:123789-HxCDF ppt <0.003 <0.01
: 1234878-HpCDF ppt <0.003 <0.008
: 1234789-HpCDF ppt <0.003 <0.01
:ocoF ppt <0,003 <0.04
I ;TOTAL TCDD ppt <0,003 <0.005
; TOTAL PECDD ppt <0.003 <0.008
1:TOTAL HxCOD ppt 0.008 <0.01
:TOTAL HpCOD ppt 0.07 J <0.02
I : TOTAL TCDF ppt <0.001 0.008
;TOTAL PECOF ppt <0.003 <0.008
:TOTAL H,xCDF ppt <0.003 <0.008
:roTAL HpCDF ppt <0.003 <0.01
I EMPC = ESTIMATED MAXIMUM POSSIBLE CONCENTRATION
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AQUEOUS DIOXIN/FURAN RESULTS
(ppt)
C-30-CF
EMPC EMPC
<0.008
<0.008
<0.01
<0.01
<0.01
0.04 J
R R 0.2:
J 0. 01 J
<0,01
0. 01
0.03
0. 01
0.02
<0.02
0.08
<0,02
<0.04
<0.008
<0.008
0.01
0.04 J
J 0.01 J
0.04 0.07
0.07 0.09
0.08
C-4-TP
EMPC
<0.005
<0.005
<0.008
<0.008
<0.01
<0.02
0.31 R
<0.005
<0.008
<0.008
<0.008
<0.005
<0.01
<0.01
<0.008
<0.01
<0.03
<0.005
0.02
<0.008
<0.02
<0.005
<0.008
<0.008
<0.01
I
I DATA s.-ARY
DIOXIN DATA FOR WATER SAMPLES COLLECTED 5/30-31/1990 I KEYSTONE WORK ORDER• M90-08.95
I
'
l!CONPOUND
:2378-TC00
I: 12378-PeCOO
: 123478-HxC0D
: 123578-HxCD0
: 123789-HxCOO 1:1234878-HpCOO
:ocoo
' . I! 2378-TCOF
: 12378-PeCOF
:23'78-PeCDF
I: 123,78-HxCOF
: 123878-HxC0F
:234878-HxCOF
: 123789-HxC0F
1!1234878-HpCOF
! 1234 789-HpCOF
:ocoF
l:TOTAL TCDD
!TOTAL PECOO
•
:TOTAL HxCDD
!TOTAL HpCOO
• .
:TOTAL TCDF
•
:TOTAL PECDF
:TOTAL HxCDF
: TOTAL HpCOF
Sample No.
Un1ta
ppt
ppt
ppt
ppt
ppt
ppt
ppt
ppt
ppt
ppt
ppt
ppt
ppt
ppt
ppt
ppt
ppt
ppt
ppt
ppt
ppt
ppt
ppt
ppt
ppt
C-28A-CP
0.01
<0.005
<0.008
0.01
(0.01
0. 42 J
5.0 R
<0.003
<O.OO5
<0.005
<0.005
<0.005
<0.008
<0.008
o. 11
(0.01
0.88
o. 01
<0.005
EMPC
0.04 0.08
0.72 J
<0.003
0.02
0.09
0.14 0.35
EMPC: ESTIMATED MAXIMUM POSSIBLE CONCENTRATION
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C-52-A
<0.003
<0.003
<0.003
(0.003
<0,003
<0.005
AQUEOUS OIOXIN/FURAN RESULTS
(ppt)
EMPC
FIELD
BLANK
EMPC
0.08 R
(0,008
<0.008
<0.01
<0.01
<0.01
<O.O2
o. 10
<0.003
<0.003
<0.003
<0.003
<0.003
<0.003
<0.005
<0.003
<0.005
<0.01
<0.003
<0.003
(0.005
<0.003
(0.003
(0.003
<O.OO3
0.009
<0.005
<0.008
<0.008
<0.008
<0.005
<0.01
<0.01
<0.008
(0.02
<0.04
(0.008
<0.008
<0.01
<0.02
<0,005
<0.008
<0.008
co. 01
C-FIELD
BLANK
<0.005
<0.005
<0.008
<0.005
<0.008
<0.01
0.09
<0.003
<0.005
<0,005
<0.005
<0.003
<0.005
<0.008
<O.OO5
<0.008
<0.02
<0.005
<0.005
<0.005
0.01
<0.003
<0.005
<0.005
<O. 005
EMPC
I AWD Technologies, Inc.
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APPENDIX A
I RESULTS AS REPORTED BY THE LABORATORY
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FILE NAME .... : T903334
CONCAL ....... : T903333
ANALYST ...... : JA
SAMPLE SIZE .. : 975.00 ml
ICAL DATE .... : 07/17/90
SPIKE FILE ... : SPX2372K
TRIANGLE LABORATORIES, INC.
PCDD/PCDF 2378X ANALYSIS (b)
CLIENT ID .... : KEYSTONE
SAMPLE ID .... : C-4-TP
ANALYSIS DATE: 07/27/90
SAMPLE MATRIX: WATER
SAMPLE ORIGIN: MORR!SVIL
Page 1 of 2
07/31/90
TLI NUMBER .... : 32-92-5
PROJECT NUMBER: 15882R
DATE RECEIVED.: 05/31/90
DATE COLLECTED: 05/30/90
SHIPMENT NO ... : 17 982004
-=--------------------------------------------------------------------------==
NAME CONC(ppt) NUMBER DL EMPC RATIO RT FLAGS
------------------------------------------------------------------------------
2378-TCDD NO 0.005
12378-PeCOD NO 0.005
123478-HxCDO NO 0.008
123678-HxCDO NO 0.008
123789-HxCDD NO 0.01
1234678-HpCDD ND 0.02
OCDO 0.31 0.94 54:24 -B..
2378-TCDF NO 0.005
12378-PeCDF NO 0.008
23478-PeCOF NO 0.008
123478-HxCDF NO 0.008
123678-HxCDF NO 0.005
234678-HxCDF ND 0.01
123789-HxCDF NO 0.01
1234678-HpCDF ND 0.008
1234789-HpCDF ND 0.01
OCDF NO 0.03
TOTAL TCDO NO 0.005
TOTAL PeCDD EMPC 0.02 g_
TOTAL HxCOD NO 0.008
TOTAL HpCOO ND 0.02
TOTAL TCOF NO 0.005
TOTAL PeCOF ND 0.008
TOTAL HxCDF ND 0.008
TOTAL HpCDF ND 0.01
_J_J_! X237_RPT rev:3.03
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FILE NAME. .•. : T903325
CONCAL ....... : T903319
ANALYST ...... : SB
SAMPLE SIZE .. : 970.00 ml
ICAL DATE .... : 07/15/90
SPIKE FILE ... : SPX2372K
TRIANGLE LABORATORIES, INC.
PCOO/PCOF 2378X ANALYSIS (b)
CLIENT IO .... : KEYSTONE
SAMPLE ID .... : C-27A-FL
ANALYSIS DATE: 07/27/90
SAMPLE MATRIX: WATER
SAMPLE ORIGIN: MORRISVIL
Page 1 of 2
07/31/90
TLI NUMBER .... : 32-92-2
PROJECT NUMBER: 15882R
DATE RECEIVED.: 05/31/90
DATE COLLECTED: 05/30/90
SHIPMENT NO ..• : 17928004
====-===---------------------------------------------------------=========----
NAME CONC(ppt) NUMBER DL EMPC RATIO RT FLAGS ------------------------------------------------------------------------------
2378-TCDD ND 0.003
12378-PeCOO NO 0.003
123478-HxCDO NO 0.003
123678-HxCDO NO 0.003
123789-HxCOO NO 0.003
1234678-HpCDO 0.04 0.89 45:32
OCDO 0.65 o. 79 50:45 .Jl
2378-TCOF NO 0.001
12378-PeCOF ND 0.003
23478-PeCOF NO 0.003
12347B-HxCDF NO 0.003
123678-HxCOF NO 0.003
234678-HxCOF NO 0.003
123789-HxCDF NO 0.003 .
1234678-HpCOF NO 0.003
1234789-HpCDF NO 0.003
OCOF ND 0.005
TOTAL TCOO NO 0.003
TOTAL PeCOD ND 0.003
TOTAL HxCDO EMPC 0.006
TOTAL HpCDO 0.07 2 0.93
TOTAL TCOF NO 0.001
TOTAL PeCOF ND 0.003
TOTAL HxCOF ND 0.003
TOTAL HpCDF ND 0.003 ----------------------------------------------------------
·.~ l/l..J'io: X237_RPT rev:3.03
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FILE NAME .... : T903324
CONCAL ....... : T903319
ANALYST ...... : SB
SAMPLE SIZE .. : 980.00 ml
!CAL DATE .... : 07/15/90
SPIKE FILE ... : SPX2372K
TRIANGLE LABORATORIES, INC.
PCDD/PCDF 2378X ANALYSIS (b)
CLIENT ID .... : KEYSTONE
SAMPLE ID .... : C-27A-FL DUP
ANALYSIS DATE: 07/27/90
SAMPLE MATRIX: WATER
SAMPLE ORIGIN: MORR!SVIL
Page 1 of 2
07/31/90
TL! NUMBER .... : 32-92-1
PROJECT NUMBER: 15882R
DATE RECEIVED.: 05/31/90
DATE COLLECTED: 05/30/90
SHIPMENT NO ... : 17928004
---=-----------------------------------------------------------------====-----
NAME CONC(ppt) NUMBER DL EMPC RATIO RT FLAGS
------------------------------------------------------------------------------
2378-TCOD NO 0.005
12378-PeCDO NO 0.008
123478-HxCOO NO 0.01
123678-HxCOO NO 0.008
123789-HxCOO NO 0.01
1234678-HpCOO NO 0.02
ocoo 0.09 0.78 50:44 Jr
2378-TCDF 0.006 o. 77 29:29
12378-PeCOF NO 0.005
2 34 78-PeCOF NO 0.008
123478-HxCOF NO 0.008
123678-HxCOF NO 0.005
234678-HxCOF ND 0.008
123789-HxCOF NO a.a,
1234678-HpCDF NO 0.008
1234789-HpCOF NO 0.01
OCDF ND 0.04
TOTAL TCDO ND 0.005
TOTAL PeCOO NO 0.008
TOTAL HxCOO NO 0.01
TOTAL HpCOO NO 0.02
TOTAL TCOF 0.006 , o. 77
TOTAL PeCOF NO 0.008
TOTAL HxCOF NO 0.008
TOTAL HpCOF NO 0.01
-------------------------------------------------------------------
IN l.J W"• : X237_RPT rev:3.03
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FILE NAME. •.• : T903335
CONCAL ....... ; T903333
ANALYST ...... : JA
SAMPLE SIZE..: 970.00 ml
!CAL DATE .... : 07/17/90
SPIKE FILE ... : SPX2372K
TRIANGLE LABORATORIES, INC.
PCDO/PCOF 2378X ANALYSIS (b)
CLIENT IO .... : KEYSTONE
SAMPLE ID .••• : C-30-CF
ANALYSIS DATE: 07/27/90
SAMPLE MATRIX: WATER
SAMPLE ORIGIN: MORRISVIL
Page 1 of 2
08/02/90
TLI NUMBER .... : 32-92-10
PROJECT NUMBER: 15882R
DA TE RECEIVED.: 05/31/90
DATE COLLECTED: 05/30/90
SHI PM ENT NO ..• : 17982004
====--==-==-==------------------------------------------------------------==--
NAME CONC(ppt) NUMBER DL EMPC RATIO RT FLAGS
------------------------------------------------------------------------------
2378-TCDD ND 0.008
12378-PeCDD ND . o. 008
123478-HxCDD ND 0.01
123678-HxCDD ND 0.01
123789-HxCDD ND 0.01
1234678-HpCDD 0.04 0.99 48: 20
OCDD EMPC 0.20 .:a_
2378-TCDF 0.01 0.65 31:56
12378-PeCDF ND 0.01
23478-PeCDF EMPC 0.01
123478-HxCDF 0.03 1. 12 41:54
123678-HxCOF 0.01 1. 26 42:04
234678-HxCDF 0.02 1.29 42: 52
123789-HxCDF ND 0.02
1234678-HpCDF 0.06 1. 10 46:39
1234789-HpCOF ND 0.02
OCDF ND 0.04
TOTAL TCDD ND 0.008
TOTAL PeCDD ND 0.008
TOTAL HxCOD EMPC 0.01
TOTAL HpCDO 0.04 1 0.99
TOTAL TCDF 0.01 1 0.65
TOTAL PeCDF 0.04 2 0.07 1. 67
TOTAL HxCOF 0.07 3 0.09 1. 22
TOTAL HpCDF 0.08 1 1. 10
---------------------------------------------------------------
~ LJJJ'fo: X237_RPT rev:3.03
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FILE NAME .... : T903326
CONCAL ....... : T903319
ANALYST ...... : SB
SAMPLE SIZE .. : 975.00 ml
!CAL DATE .... : 07/15/90
SPIKE FILE ... : SPX2372K
TRIANGLE LABORATORIES. INC.
PCDD/PCDF 2378X ANALYSIS (bl
CL! ENT ID .... : KEYSTONE
SAMPLE ID .... : C-28A-CP
ANALYSIS DATE: 07/27/90
SAMPLE MATRIX: WATER
SAMPLE ORIGIN: MORRISVIL
Page 1 of 2
08/01/90
TL! NUMBER .... : 32-92-3
PROJECT NUMBER: 15882R
DATE RECEIVED.: 05/31/90
DATE COLLECTED: 05/30/90
SHIPMENT NO ... : 17928004
=---=-------------------------------------------------------------=-==========
NAME CONC(ppt) NUMBER DL EMPC RATIO RT FLAGS
------------------------------------------------------------------------------
2378-TCDD 0.01
12378-PeCDD ND
123478-HxCDD ND
123678-HxCDD 0.01
123789-HxCDD ND
1234678-HpCDD 0.42
OCDD 5.0
2378-TCDF ND
12378-PeCDF ND
23478-PeCDF ND
123478-HxCDF ND
123678-HxCDF ND
234678-HxCDF ND
123789-HxCDF ND
1234678-HoCDF 0. 11
1234789-HpCDF ND
OCDF 0.66
TOTAL TCDD 0.01
TOTAL PeCDD ND
TOTAL HxCDD 0.04
TOTAL HpCDD o. 72
TOTAL TCDF ND
TOTAL PeCDF EMPC
TOTAL HxCDF EMPC
TOTAL HpCDF 0. 14
2
2
0.005
0.008
0.01
0.003
0.005
0.005
0.005
0.005
0.008
0.008
0.01
0.005
0.003
0.06
0.02
0.09
0.66
1. 29
1. 02
0.88
0.89
0.96
0.66
1. 36
1. 07
0.35 0.89
30: 17
40:43
45:34
50:45
44:02
50:59
------------------------------------------------------------------------------v X237_RPT rev:3.03
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FILE NAME. ... : T903337
CONCAL. ...... : T903333
ANALYST ...... : JA
SAMPLE SIZE .. : 980.00 ml
!CAL DATE .... : 07/17/90
SPIKE FILE ... : SPX2372K
TRIANGLE LABORATORIES, INC.
PCDD/PCDF 2378X ANALYSIS (b)
CU ENT ID .... : KEYSTONE
SAMPLE ID .•.. : C-52-A
ANALYSIS DATE: 07/27/90
SAMPLE MATRIX: WATER
SAMPLE ORIGIN: MORRISVIL
Page 1 of 2
07/31/90
TLI NUMBER .... : 32-92-12
PROJECT NUMBER: 15882R
DA TE RECEIVED. : 05/31/90
DATE COLLECTED: 05/30/90
SHIPMENT NO ... : 17982004
------------------------------------------------------------------------------
NAME CONC(ppt) NUMBER DL EMPC RATIO RT FLAGS
------------------------------------------------------------------------------
2378-TCDD ND 0.003
· 12378-PeCDD ND 0.003
123478-HxCDD ND 0.003
123678-HxCDD ND 0.003
123789-HxCDD ND 0.003
1234678-HpCDD ND 0.005
OCDD 0.08 0.83 54:23 ..a.
2378-TCDF ND 0.003
12378-PeCDF ND 0.003
23478-PeCDF ND 0.003
123478-HxCDF ND 0.003
123678-HxCDF ND 0.003
234678-HxCDF ND 0.003
123789-HxCDF ND 0.005
1234678-HpCDF ND 0.003
1234789-HpCDF ND 0.005
OCDF ND 0.01
TOTAL TCDD ND 0.003
TOTAL PeCDD EMPC 0.009 _g_
TOTAL HxCDD ND 0.003
TOTAL HpCDD ND 0.005
TOTAL TCDF ND 0.003
TOTAL PeCDF ND 0.003
TOTAL HxCDF ND 0.003
TOTAL HpCDF ND 0.003
------------------------------------------------------------------------------
_J_j_: X237_RPT rev:3.03
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FILE NAME .... : T903336
CONCAL ....... : T903333
ANALYST ...... : JA
SAMPLE SI Z E .. : 1 0 2 0 . 00 ml
!CAL DATE .... : 07/17/90
SPIKE FILE ... : SPX2372K
TRIANGLE LABORATORIES, INC.
PCOD/PCDF 2378X ANALYSIS (b)
Page 1 of 2
07/31/90
CLIENT JD .... : KEYSTONE TLJ NUMBER .... : 32-92-11
SAMPLE JD .... : C-FJELO BLANK
ANALYSIS DATE: 07/27/90 PROJECT NUMBER: 15882R
SAMPLE MATRIX: WATER DATE RECEIVED.: 05/31/90
SAMPLE ORIGIN: MORRISVIL DATE COLLECTED: 05/30/90
SHIPMENT NO ... : 17982004
=========================================================================---==
NAME CONC(ppt) NUMBER DL EMPC RATIO RT FLAGS
------------------------------------------------------------------------------
2378-TCOO NO 0. 005
12378-PeCDD ND 0. 005
123478-HxCDD NO 0.008
123678-HxCDD NO 0.005
123789-HxCDD ND 0.008
1234678-HpCDD ND 0.01
OCDD 0.09 1.01 54:24 ..B...
2378-TCOF ND 0.003
12378-PeCOF ND 0.005
23478-PeCDF ND 0. 005
123478-HxCDF NO 0.005
123678-HxCOF NO 0.003
234678-HxCDF ND 0.005
123789-HxCOF NO 0.008
1234678-HpCDF NO 0.005
1234789-HoCDF NO 0.008
OCDF NO 0.02
TOTAL TCDO NO 0.005
TOTAL PeCOO ND 0.005
TOTAL HxCDD ND 0.005
TOTAL HpCOO NO 0.01
TOTAL TCOF NO 0.003
TOTAL PeCOF ND 0.005
TOTAL HxCOF NO 0.005
TOTAL HpCOF NO 0.005
------------------------------------------------------------------------------____ t<,_v~ '!.._;R; 'fl: X237_RPT rev:3.03
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FILE NAME .... : T903328
CONCAL ....... : T903319
ANALYST ...... : SB
SAMPLE SIZE .. : 980.00 ml
!CAL DATE .... : 07/15/90
SPIKE FILE ... : SPX2372K
TRIANGLE LABORATORIES. INC.
PCDD/PCDF 23i8X ANALYSIS (bl
CLIENT ID .... : KEYSTONE
SAMPLE ID .... : FIELD BLANK
ANALYSIS DATE: 07/27/90
SAMPLE MATRIX: WATER
SAMPLE ORIGIN: MORRISVIL
Page 1 of 2
Oe/C1/~0
TL! NUMBER .... : 3.?-;2-4
PROJECT NUMBER: 155E2R
DATE RECEIVED.: 05/31/90
DATE COLLECTED: 05130/90
SHIPMENT NO ... : 179"3004
----------------------------------------------------------------------========
NAME CONC(potl NUMBER DL EMPC RATIO RT FLAGS
-------------------------------,-----------------------
2378-TCDD ND 0.008
12378-PeCDD ND 0.008
123478-HxCDD ND 0.01
123678-HxCDD ND 0.01
123789-HxCDD ND 0.01
1234678-HpCDO NO 0.02
OCDD 0. 10 0.90 50:45 y
2378-TCDF ND 0.005
12378-PeCDF ND 0.008
23478-PeCDF ND 0.008
123478-HxCDF NO 0.008
123678-HxCDF ND 0.005
234678-HxCDF ND 0.01
123789-HxCDF ND 0.01
12346 78-HpCDF ND 0.008
1234789-HpCOF ND 0.02
OCDF ND 0.04
TOTAL TCDO ND 0.008
TOTAL PeCDO ND 0.008
TOTAL HxCDO NO 0.01
TOTAL HpCOO ND 0.02
TOTAL TCOF NO 0.005
TOTAL PeCOF NO 0.008
TOTAL HxCOF NO 0.008
TOTAL HpCOF ND 0.01
X237_RPT rev:3.03
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AWO Technologies, Inc.
APPENDIX B
SUPPORT DOCUMENTATION
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FILE NAME .... : T903323
CONCAL ....... : T903319
ANALYST ...... : SB
SAMPLE SIZE .. : 1000.00 ml
!CAL DATE .... : 07/15/90
SPHE FILE ... : SPX2372K
TRIANGLE LABORATORIES. INC.
PCDO/PCOF 2378X ANALYSIS ,o,
CL! ENT ID .... : KEYSTONE
SAMPLE ID .... : TL! BLANK
ANALYSIS DATE: 07/27/90
SAMPLE MATRIX: n/a
SAMPLE ORIGIN: n/a
Page 1 of 2
07/31/90
Tl! NU"1BER .... : n/a
PROJECT NUMBER: 15882R
DATE RECEIVE[,,: I I
DATE COLLECTED: I I
SHIPMENT NO.,.: n/a
-----------------------------------------------------------------------=======
NAME CONC(pptl NUMBER DL EMPC RATIO RT FLAGS
2378-TCDD ND 0.003
12378-PeCDD ND 0.003
123478-HxCDD ND 0.003
12367e-HxCDD ND 0.003
123789-HxCDD ND 0.003
1234678-HoCDD ND 0.003
OCDD 0.09 0.84 50: 45
2378-TCDF ND 0.003
12378-PeCDF ND 0.003
23478-PeCDF ND 0.003
123478-HxCDF ND 0.003
123678-HxCDF ND 0.003
234678-HxCDF ND 0.003
123789-HxCDF ND 0.003
1234678-HpCDF ND 0.003
1234789-HoCDF -ND 0.003
OCOF ND 0.005
TOTAL TCDD ND 0.003
TOTAL PeCDD EMPC 0.007
TOTAL HxCDD ND 0.003
TOTAL HpCDO ND 0.003
TOTAL TCDF ND 0.003
TOTAL PeCOF ND 0.003
TOTAL HxCDF ND 0.003
TOTAL HpCDF ND 0.003
_____ .,.jc....cl.Jc... Lfl_!_/~o: X237_RPT rev:3.03
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PGH-90-TMJ-340
DATE September 14, 1990
TO Mr. Robert S. Markwell
Program Manager -Environmental Services
Beazer Materials and Services, Inc.
436 Seventh Avenue
Pittsburgh, Pennsylvania 15219
FROM Thomas Jackman
AWD Technologies, Inc.
toy,:;, J It; /f/fel;f1
SUBJECT "1>ioxi o/Fu£an Data Validation
Keystone Environmental Job #M90-06.9
Overview
AWD
TECHNOLOGIES
The set of samples for Beazer (sampled 6/2-6/90) contained 52 soil
samples including 6 pairs of field duplicates. No field blanks
accompanied the data package. Samples were analyzed for Isopropyl
Ether, Phenols,· Silver, Arsenic, Barium, Cadmium, Chromium,
Mercury, Lead and Selenium. Isopropyl ether was analyzed by EPA
Method 602; phenols were analyzed by Method 8040; metals were
analyzed by methods of the EPA's Contract Laboratory Program (CLP).
summary
All compounds were successfully analyzed in all samples with the
exception of those qualified as unreliable "R". Areas of concern
with respect to data usability are listed according to the
seriousness of the problem. These include:
Major Issues
The matrix spike recovery for selenium (-6.4%) was below the 30%
quality control limit. Therefore detection limits are qualified
"R", unreliable.
AWD Technolooies. Inc. Penn Center West. Buildina Ill. Suite 400 Pittsburoh Pecnsvlvania 15276 Te!eoho,e 412 788 2717 Telecooie• 41? 7/ .. q , "'
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AWD Technologies, Inc.
PGH-90-TMJ-359
Mr. Roberts. Markwell
Beazer Materials and Services, Inc.
September 14, 1990 -Page 2
Minor Issues
Phenol, 2, 4-dimethylphenol and 4-ni trophenol were detected in
laboratory blanks at concentrations greater than required detection
limits. Therefore sample results less than five times the highest
blank concentrations of these compounds are qualified ''U". Note
that the laboratory subtracted the blank concentrations from sample
results (see Appendix B Support Documentation). These
subtractions were taken into account when qualifying data.
Serial dilution
control limit.
estimated.
results for chromium exceeded the 10% quality
Therefore positive results are qualified "J",
Notes
Appendix A, results
of metals results.
correct results.
as reported by the laboratory, contains 2 sets
The pages stamped "REVISION" contain the
The data were reviewed according to the National Functional
Guidelines for Evaluating Organic Analyses. The text of this
report addresses only those problems affecting usability.
Information Regarding Report Content
Attachments:
1.
2.
3.
4.
Glossary of data qualifier codes.
Data Summary. This includes:
a) All positive results with qualifier codes, if applicable;
b) All unusable detection limits qualified with an ''R"; and
c) All estimated detection limits qualified with UJ or UL.
Appendix A -results as reported by the laboratory (no
corrections were made during data validation).
Appendix B -Support Documentation includes details to support
the statement in this report.
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AWD Technologies, Inc.
GLOSSARY OF DATA QUALIFIER CODES (ORGANIC)
CODES RELATING TO IDENTIFICATION
(confidence concerning presence or absence of compounds)
< = Not Detected. The associated number indicates approximate
sample concentration necessary to be detected.
u = Not detected substantially above the level reported in
laboratory or field blanks.
(NO CODE) = Confirmed Identification
R = Unreliable Result. Analyte may or may not be present in the
sample. Supporting data necessary to confirm result.
CODES RELATED TO QUANTITATION
(can be used for positive results and sample quantitation limits):
J = Analyte present.
precise.
Reported value may not be accurate or
UJ = Not detected. Quantitation limit may be inaccurate or
imprecise.
OTHER CODES
NA= Not Analyzed
I AWO Technologies, Inc.
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I DATA SUMMARY FORMS
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I DATA SUMMARY
NON CLP DATA FOR SAMPLES COLLECTED 6/2/90 -6/6/90
BEAZER -RALEIGH
I Keystone Envir0f"lffl9ntal Job. f M90-06.09
I Suph1 No. C-9C-OSN C-9C-OSN S-7-FP S-8-FP S-8-FP S-8-FP
2-4' e-a· 0-2· 2-4' 0-0.5' 2-4'
I COMPOUND Unita
Phenol ug/kg 77.9 U 83.0 u <88.0 <68.0 <78,5 <87.0
I 2-Chlorophenol ug/kg <150.0 <80.5 <86.0 <88.0 <78.5 <87.0
2-Nitrophanol ug/kg <80.0 <60.5 94.4 <158.0 <78.5 <67.0
2,4-0imathylphenol ug/kg <60.0 <60.5 <66.0 <68.0 <78.5 (67.0
I 2,4-0ichlorophenol ug/kg <60.0 <150.5 <66.0 (68.0 <78.5 98.6
4-Chloro-3-mathylphenol ug/kg <80.0 <60.5 <1515.0 <88.0 <78.5 <67.0
2,4,15-Trichlorophanol ug/kg <120 < 121 < 132 < 1315 < 157 < 134
I 2,4-Dinitrophenol ug/kg < 120 < 121 < 132 <1315 < 157 < 134
4-Nitrophanol ug/kg <120 522 u 375 u 787 u 504 u 341 u
2,3,5,15-Tetrachlorophenol ug/kg < 120 <121 < 132 <136 <157 < 134
2-Methyl-4,15-dinitrophenol ug/kg < 120 < 121 < 132 <136 < 157 < 134
Pantachlorophenol ug/kg <120 < 121 < 132 < 138 <157 < 134
Percent Solids 83.3 82.7 75.7 73.8 83.6 7'.4
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I Sample No. S-11-FP S-11-FP S-11-FP-OUP S-12-FP S-12-FP S-13-FP
0-0.5' 2-4' 2-,· 0-2· 2-4' 0-0.5"
I COMPOUND Unite Fie1d Duplicates
I Phenol ug/kg 217 u <64.5 <154.0 <67.5 <83.0 186 U
2-Chlorophanol ug/kg <125 <84.5 <84.0 <87.5 <63.0 <93.0
2-N1trophenol ug/kg <125 <154.5 <84.0 <87.5 <83.0 <93.0
2,4-Dimethylphenol ug/kg < 125 (64.5 <64.0 <97.5 94.1 u <93.0
I 2,4-Dichlorophenol ug/kg <125 <94. 5 <84,0 <87.5 <63.0 <93.0
4-Chloro-3-nethylphenol u9/k9 < 125 <84.5 <64.0 <67.5 <83.0 <93.0
2,4,6-Trichlorophenol ug/kg <250 < 129 < 128 <135 < 126 < 186
I 2,4-0initrophenol ug/kg <250 < 1 29 < 128 < 135 < 128 < 188
,4-N1tropheno1 ug/kg 723 u 262 u 226 U 249 u 262 U < 188
2,3,5,8-Tatrachlorophenol ug/kg <250 <129 < 128 < 135 < 128 < 188
I 2-Methy1-4,8-d1n1trophanol ug/kg <250 < 129 < 128 <135 < 129 233
Pantachlorophenol ug/kg 357 < 129 < 128 < 135 <128 5040
Percent Solids 40.0 77. 5 78.1 74.1 79.3 53.9
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I DATA SUMMARY
NON CLP DATA FOR SAMPLES COLLECTED 8/2/90 -6/6/90
I BEAZER -RALEIGH
Keystone EnvironJHntal Job. I M90-06.09
I Sample No. S-13-FP S-13-FP-OUP S-14-FP S-14-FP S-2-FP S-2-FP
2-4' 2-4' 0-2· 2-4' 0-0.5' 2-4'
I Field Oupl 1cataa
COMPOUND Un1ta
I Phenol ug/kg 67.7 U <59.5 91. 7 u 77.0 U <78.0 (59.5
2-Chlorophenol ug/kg <59.0 <59.5 <68.5 <59.0 <78.0 <59.5
2-Nitrophenol ug/kg <59.0 <59.5 <6B.5 <59.0 <7B.O <59.5
2,4-0imethylphenol ug/kg 150 u <59.5 102 u 82.7 U <7B.O <59.5 I 2,4-01chlorophenol ug/kg <59.0 <5S.5 <88.5 <59,0 <78.0 <59. 5
4-Chloro-3-methylphenol ug/kg <59.0 <59.5 <68.5 <59.0 <78.0 <59.5
2,4,6-Trichlorophenol ug/kg <118 < 119 < 137 <118 <158 < 119
I 2,4-0initrophenol ug/kg < 118 < 119 < 137 <118 <158 < 119
4-Nitrophanol ug/kg < 118 <119 182 u <118 <158 <119
2,3,5,6-Tetrachlorophenol ug/kg < 118 < 119 < 137 < 11 B < 158 < 119
I 2-Methyl-4,6-dinitrophenol ug/kg <118 < 119 <137 <118 < 158 < 119
Pantachlorophenol ug/kg < 118 <119 < 137 < 118 239 < 119
Percent Salida 84.7 83.8 I 73.0 84.4 64.2 84.3
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Sample No. S-3-FP S-3-FP S-5-FP S-5-FP S-6-FP S-8-FP
I 0-2· 2-4' 0-0.5' 2-4' 0-2' 2-4'
COMPOUND Un1ta
I Phenol ug/kg 77.8 U 103 U <77 .o <5B,5 cee.o <65.0
2-Chlorophenol ug/kg <62.5 <62.0 <77 .o <58.5 <68.0 (65.0
I 2-Nitrophenol ug/kg <82.5 <82.0 <77.0 <58.5 <88.0 <65.0
2,4-01methylpheno1 ug/kg <52.5 <52.0 <77.0 144 u <55.0 <55.0
2,,-01ch1oropheno1 ug/kg <82.5 <52.0 <77.0 <58. !5 <fUI. 0 <55.0
I •-ch1oro-3-methy1pheno1 ug/kg <82. !5 <62.0 <77.0 <58.5 <55.0 <55.0
2,4,5-Trich1orophano1 ug/kg < 125 < 12• < 154 < 117 < 132 < 130
2,4-01n1tropheno1 ug/kg < 125 <12. <154 < 117 < 132 < 130
4-Nitrophenol ug/kg <125 < 124 < 15-' 283 u 13B U 173 u
I 2,3,5,5-Tetrach1oropheno1 ug/kg < 125 < 12, < 154 < 117 < 132 <130
2-Methy1-4,6-d1n1tropheno1 ug/kg <125 < 12• < 154 <117 < 132 < 130
Pentach1oropheno1 ug/kg < 125 < 12• 752 (117 < 132 < 130
I Percent Solids 79.7 80. 7 64.9 85.2 75.5 78.7
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I DATA SUMMARY
NON CLP DATA FOR SAMPLES COLLECTED 6/2/90 -6/6/90
I BEAZER -RALEIGH
Keystone Environmental Job. I M90-06.09
Sample No. S-9-FP S-9-FP S-16A-EA S-16B-EA 9-17-EA S-23-EA I 0-2· 2-•·
I COMPOUND Unite
Phenol ug/kg <e•.o <82.5 <93.0 <78.0 <81.0 <175
I 2-Chlorophenol ug/kg <64.0 <82.5 <93.0 <78.0 <81.0 < 175
2-Hitrophanol ug/kg <64.0 <82.5 <93.0 <78.0 <81.0 < 175
2,4-0imethylphanol u9/k9 <64.0 <82.5 139 u 294 U (81.0 <175
2,,-0ichlorophanol ug/kg <84.0 <82.5 <93.0 <78.0 <81.0 <175 I 4-Chloro-3-methylphenol ug/kg <64.0 <82.5 <93.0 <78.0 <81. 0 <175
2,4,8-Trichlorophenol ug/kg <128 <125 <188 <158 <182 <350
2,4-0initrophenol ug/kg <128 < 125 < 188 < 158 < 182 <350
I 4-Hitrophenol ug/kg < 128 130 u 225 u 240 U <182 <350
2,3,5,8-Tetrachlorophenol ug/kg <128 < 125 < 188 <158 < 182 <350
2-Methyl-4,8-dinitrophanol u9/k9 <128 < 125 <188 < 158 <182 <350
I Pentach 1 oropheno 1. u9/k9 <128 <125 1540 555 630 <350
Percent So1ida 78.2 79.9 53.9 84. 1 81. 7 28.6
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I Sample No. C-11-0SE C-11-0SE X-1-0SN X-1-0SN X-1-0SN-OUP X-7-LF
0-2· 4-4.5" 0-2· 8-8' 8-8' 0-2·
I Field Oupl icatea
COMPOUND Unit■
I Phenol ug/kg 80.3 U 94.3 u 60.8 u 83.8 u <5 •. 4 < 57. 5
2-Chlorophanol ug/kg <82.0 <55. 0 <59.0 <54.0 (54.5 <57.5
2-Nitrophenol ug/kg <82.0 <55.0 <59.0 <54,0 <5 •• 5 <57.5
I 2,4-0lmethylphenol ug/kg <82.0 < 55. 0 <59.0 <54.0 <54.5 <57.5
2,4-01ch1oropheno1 ug/kg <82.0 <55. 0 <59.0 <54.0 <54.5 <57.5
4-Ch1oro-3-Nthy1pheno1 ug/kg <82.0 < 55.0 <59.0 <54.0 <54.5 <57.5
I 2,4,e-Trich1orophano1 ug/kg < 124 <110 <118 <108 < 109 <115
2,4-Dinitropheno1 ug/kg <124 <110 <118 <108 <109 < 115
4-Nltrophenol ug/kg < 124 < 11 0 <118 <108 < 109 <n5
2,3,5,e-Tetrachloropheno1 ug/kg < 124 < 110 <118 < 108 < 109 < 115
I 2-Methyl-4,8-dinitrophenol ug/kg < 124 < 11 a < 118 <108 < 109 < 115
Pantachlorophenol ug/kg < 124 <110 <118 <108 < 109 < 115
I Isopropy1 Ether ug/kg NR NR NR <108 NR NR
Percent Solids 80.7 90.9 84.8 92.4 91. 7 87. 0
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I DATA SUMMARY
NON CLP DATA FOR SAMPLES COLLECTED 8/2/90 -8/8/90
I BEAZER -RALEIGH
Keystone Envirorunenta1 Job. • M90-06.09
I Sample No.X-7-LF-DUP X-7-LF X-7-LF-DUP X-7-LF X-10-TP X-10-TP
0-2· 2-4' 2-4" B-10' 0-2· 4-8'
Duplicate Field Dup11catea
I COMPOUND Units of X-7-LF
0-2·
I Phenol ug/kg <57. 0 89.0 u NR 85.8 u <58. 5 <81. 0
2-Chlorophenol ug/kg <82.0 <55.0 NR <54.0 (54.5 <81. 0
2-Nitrophanol ug/kg <82.0 <55.0 NR <54.0 (54.5 <81. 0
I 2,4-0imethylphenol ug/kg <82.0 <55.0 NR <54.0 157 u <81. 0
2,4-0ichlorophenol ug/kg <82.0 <55,0 NR <5.a.o <54,5 <61. 0
4-Chloro-3-aethylphenol ug/kg <82.0 <55.0 NR <!54.0 <54.5 <81. 0
2,4,8-Trichlorophenol ug/kg < 114 < 128 NR < 118 <117 < 122
I 2,4-Dinitrophenol ug/kg <114 < 128 NR < 118 <117 <122
4-Nitrophenol ug/kg < 114 < 128 NR <1HS <117 < 122
2,3,51 8-Tetrachlorophenol ug/kg <114 <128 NA <118 <117 < 122
I 2-Methyl-4,8-dinitrophenol ug/kg < 114 < 128 HR <118 <117 <122
Pentachlorophenol ug/kg <114 < 128 NA <118 <117 < 122
I Iaopropy1 Ether ug/kg HR < 128 < 128 HR NA HR
Silver ug/kg NA NR NA NA NA <2430
Areenic ug/kg NR NR NA NA HR <2430
I Bari._. ug/kg NR NA NA NA NA 398000
c.adllil.111 ug/kg HR NA NR NA NA <1220
Chrcaium ug/kg NA NA HR NA NA 30300 J
I Mercury ug/kg NA HR NR HR NR < 122
Lead ug/kg NA NR NR NR NR 18300
Selanh.aa ug/kg NR NR NA NA HR < 1220 R
I Percent Salida B7,7 79.8 NA B8.5 85.3 B2.3
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I DAT A SUMMARY
HON CLP CATA FOR SAMPLES COLLECTED 6/2/90 -6/6/90
I BEAZER -RALEIGH
Kayatone Env1ronHntal Job. I M90-06.09
•--------SUpla No. X-10-TP X-12-EA X-12-EA X-46-WA X-48-WA X-48-WA-OlF
8-10' 2-•· B-10' 0-2· ,-,.a· 4-4.B'
Field Ouplicatas •-------COMPOUND Units
Phenol u9/k9 <55.0 <81. 5 <54.5 <59.5 UJ <53. 5 <53.5
I 2-Chlorophenol u9/k9 <55.0 <81. 5 <54.5 <59.5 UJ <53.5 <53.5
2-Nitrophenol ug/kg <55.0 (81. 5 <54.5 <59.5 UJ <53.5 <53.5
2,4-Dimathylphanol u9/k9 <55.0 775.0 U 88.3 u 889 u <53.5 <53.5
2,4-Dichlorophenol ug/kg <55.0 <81. 5 <54.5 <59.5 UJ <53.5 <53.5
I 4-Chloro-3-methylphenol u9/k9 <55.0 <81. 5 <54. 5 <59.5 UJ <53.5 < 53. 5
2,4,8-Trichlorophanol u9/k9 < 110 141 <109 300 J <107 < 107
2,4-0tnttrophenol ug/kg <110 <123 <109 < 119 UJ <107 < 107
I 4-Nitrophenol u9/k9 < 110 < 123 < 109 < 119 UJ < 107 < 107
2,3,5,6-Tetrachlorophenol u9/k9 <110 <123 <109 < 119 UJ < 107 < 107
2-Methyl-4,8-dtnttrophenol ug/kg <110 < 123 < 109 < 119 UJ (107 < 107
I Pantachlorophenol u9/k9 <110 < 123 <109 < 119 UJ < 107 < 107
Isopropyl Ether u9/k9 NR <123 NR < 119 NA NA
I Silver ug/kg <2210 NA NA NA NA < 1220
Arsanic ug/kg <2210 UJ NA NA NA NA <1220
Bartl.a u9/k9 382000 NA NA NA NA 39600
I Cadlllium ug/kg < 1100 NA NA NA NA <608
Chromium u9/k9 17700 J NA NA NA NA 30200 J
Mercury u9/k9 < 111 NA NA NA HR <122
Lead ug/kg 15800 NA NA NA NA 16280
Stllantum u9/k9 <1100 R HR HR HR HR <808 R I _______ _
Percent Solids 90.5 81.1 91. 4 84.3 93.3 93. 1
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I DATA SUMMARY
NON CLP DATA FOR SAMPLES COLLECTED 6/2/90 -6/6/90
I BEAZER -RALEIGH
Keystone Environaental Job. I M90-06.09
9up1e No. X-49-CP X-50-FL SS-1-TP SS-2-TP •------------0-4' 4-8' 0-0.5' 0-0.5'
•------------COMPOUND Unite
Phenol ug/kg <59.0 <56.0 <58.5 <60.0
I 2-Chlor-ophanol ug/kg <59.0 99.4 101 <60.0
2-N1tr-ophenol ug/kg <59.0 <56.0 <58,5 <80.0
2,4-D1mathylphenol ug/kg 121 u <56,0 (58.5 <80.0
2,4-Dichlorophenol ug/kg <59.0 <56.0 <58,5 <60.0
I 4-Chloro-3-methylphenol ug/kg <59.0 185 <58.5 <80.0
2,4,B-Trichlorophanol ug/kg < 118 <112 <117 <120
2,4-D1n1trophanol ug/kg <118 <112 <117 <120
I 4-Nitrophenol ug/kg < 118 < 112 < 117 <120
2,3,5,e-Tatrachlorophenol ug/kg <118 2680 <117 <120
2-Methyl-4,8-dinitrophenol ug/kg <118 < 122 <117 <120
I Pantachlorophenol ug/kg 4990 560000 163 133
Iaopropyl Ether ug/kg <118 < 112 NR MR
I Silver ug/kg NR NR <2340 <2340
Arsenic ug/kg MR MR <2340 <2340
6ar1i.a ug/kg MR MR 64800 59200
I Cadmium ug/kg MR MR < 1170 <1200
Chromh• ug/kg MR MR 11200 J 16900 J
Me,-cury ug/kg MR MR < 117 < 121
•------------Lead ug/kg NR MR 11700 12600
9elan1um ug/kg MR MR <1170 R <1200 R
Percent S011da 84.7 88.9 85.3 83.0 93.3 93.1
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APPENDIX A
I RESULTS AS REPORTED BY THE LABORATORY
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l 1;• JUL· 1990
Su11oa,.ry of /m;lyncil Resdts
Dite rece1veo: 4-JUli-1990
t:aystone ll, 9·003 9·((14 9-(:05 9·1i<J.I 9·007 9-006
D,te Sa•plea 2-JUtl·1990 2-jLJt,-1991) 2-JUN·19'i'O 2-JlffH'l'IO 2-JUN·l'l90 2·JUN·199C
Cust011er rn C·9C-OSN ;:-4' C·9C-OSN o-8' 5· ?·FP 0-2' S· 7·FP 2·4' 5·8-FP 0·0.5' 5·8·FP 2•4'
Parueters Units
-------------------------------------------------------------------------------------------------------------------------------
lSolids at 1/J3'C l 83.3 --, 75.1 73.8 b'.3,6 74,4
O.:'., I
0040l
Ph.r,ol ug/Kg 77.9 83,0 :,6o,0 <68.0 (78,5 167.0
2-Chlorophenol ug/f.g <o(,. 0 ~.oo.5 \t,b, (; <68,0 (78.5 \67.0
2-Nitrophenol ug/~g ,bO.O ',bl),5 94.4 ,bB.O (78.5 \b7,0
2,4-Dl.fflethylpnenol Ug/Kg <o<),0 :_t,(i,5 \oi,,(J <68,0 (78.5 <67.0
2 ,4·Dicr,lorophenol ugJ~.g (o:),O (61),5 r..b6.0 (o,3,0 08.5 98.6
4·Chloro· 3-,,ethy !phenol ug/t.g <.t.CJ,(, {_6(;. 5 (oi,, () (68.0 (78.5 (b7,(J
21416· Tr 1cnloropher,ol ug;Kg q21) ( l 21 (132 \l3b (157 <b7,(I
214-0iriitrophenol ug/Kg \ 120 <121 \132 (136 \157 (134
4·Ni trophenol ugiKg <120 CO, 375 7b7 504 341
.._l~L
2,3,5,b-Tetrachl0rophen"l ug/Kg \120 <.121 ,132 {136 (157 (134
2·~,;thyl·4,6·din1troph.anol ug/Kg <120 <121 \i32 (136 (157 :134
~·er,t acnlor opneroo 1 ug/tg (120 <.121 (132 <136 q57 (134
8040X SURWGArES
Z-Fluurophenol l Ri:CC.VHY 70.0 77,b :A. I 51).0 47.0 58.1
2, 416-T r 1bror;i0ptti::nc• l ., fieco.ery 86,2 08,b o~.9 67,2 71 .0 oii.6
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0
D
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H
g
;V-JIJL -1990
Date rece1vcu: 4-JLJN-1990
~.eyst"r," ![I
0,tll San,pled
Cust!lller IO
'!Solids at lOJ'C
8040X
,•nenol
2-Cr,lorc,ph,mol
2·1l11 rc,pher,ol
214-Di•ethylpnenol
2,4-Dichlorophenol
4-Chloro-3-n,ethy lp.i\;no l
214 ,tr Tr ichloropheriol
214-Dirii trc,pt1enol
4-r-i it ropher1ol
2131516-Tc tn.ci":lor0pncr10 l
2-t-iethy 1-4, b·dini tri::,pr1enol
Pent.,ch loropheno 1
8040X SUf-hVGATES
2-fluoropnenol
214,b-ir ibron,c,phenul
51',ples
9·00'1
2-JUt;-1990
5·11-FP
0-0.5'
' 4(>,0
ug/,g 217
ug;~g <12:,
ug/K.g <125
ug/f.g <.1;:5
ug/~.g <125
ug/Kg ( 1 ;::,
ugifg 1.:25◊
ug/f.g <2~•l}
''gi~(J 723
ug,',g (:'SC,
ug1,g ,_;:50
Ugifg 357
: Rtc1:is,try 37.7
:.'. ~:ecc,;:cry tj,j
9-01(1
2-Jlli· 1990
S-11-FP 2-4'
77.5
;_t,4,5
<.t,4.5
(64,5
::e,4,5
\b-4,5
<b4.5
~:1:"1
( 1::t
io2
q~'9
,18
<1?,
% , •4
72.3
9-t)l 1 9-012 9·01b 9-017
2-JUN-1990 2· JUN-1990 2-JUN-1990 2-JUN-1990
S· 11 -FP 2-4 • 5·12-FP 0·2' 5-12-H• 2·4' S-13-FP
DUPLICATE 0-0.5'
78.l 74. l 79.3 53.9
<o4.0 (67 . .5 <b3.0 181,
(b-4.(/ <.b 7, 5 (b3.0 (93.0
<o4.0 (b7.5 103.0 <.93.0
(t,4.1) <.67 -~ 1>4.1 <93.0
,:64.1) 167.5 <t,3,0 ,93.0
<64.(1 {./:,7 .:, (63.0 <93.v
<.1:::-S \1}5 ,126 <.18b
'.128 -:.t}:, <12b <.!Sb
226 149 262 lBo-;,:.~ctL
<.l~'B <135 <.12b '-loo
(128 ,.135 (12b 233
::J28 ~ 1j5 (126 :,1)4(1
51.5 38.2 67.4 68.6
77.2 59.3 78.0 71),4
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R
6
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I
lO-JUL-19'/ll
Keystone JD
Date Sa•pled
CustOliler l[J
Paraeti?.rs
Date received: 4-JUN-1990
S<Mary of Analyt1cal fi.sults
Custo,,er: Beazer -Raleigh
s,~ples
9-018 9-0!'1 9-020
:-JUN-I'm 2-JUIH990 2-JIJN-I 991)
S-13-fi• :-: ' S-13-fP 2-4' S-14-~~· tJ-2'
f.dfaLICAH
Ur.its
Page J
9-021 9-022 9-023
:-JUN-1990 4-JlJN-1990 4-JUN-190,:,
S-14-fP 2-4' s-2-FP o-o.s· 5-2-f~• ;:-~·
-------------------------------------------------------------------------------------------------------------------------------
lSolids at 103'C ' 84 , ., 8'.i.8 73.0 84.4 b4,2 &.\ -,J
B040X
Phenol Ulj/Kg o7.7 ,.59.5 ~I, 7 ;7,0 (78.0 ,.59.5
:-Cnloropner,c;I ug/kg (59.0 (:,9 .:. <.68.:', '.59.0 <76.(1 {.59. :,
2-N1trophenol Ulj/~g <..59.U \59.5 :_t,8,5 \.59,0 i78.0 <59.5
2 ,4-Diaetny lphe.,ol ug/t.g 1:.0 (C'~• C 1(:2 82,7 \78.0 <59.5 -.·7 • .J
2, 4-[iichlorophenol •cgiKg (7.8.V :;59 .5 (b8.5 \~9.0 \78.0 <59.5
4-Chloro-3-mc tn'y" lpher1ol ug/Kg <5'1.(1 <59.~, (b8.5 <59.0 (;8.0 (59.5
214 ,b-T r ichlc,ropnenol ugiK9 ,.118 , 119 (!37 ( 118 i156 (119
214-Dini t rophenol ug/Kg <.! 18 ,119 <137 (118 (15b (119
4-Nitroph,nol ugiKg ~49 <. I l 9 H32 ,118 il56 (119
213, 516-T nrachloropr,enol u,j/Kg <118 (119 (137 ,118 (156 (119
2-~ethy 1-4, 6-dmi tropner.ol ugi,.g i 11a '119 -<.137 (118 (156 019
Per,tach lo r opheno 1 ug/Kg <. l 18 ( 1 I 9 (137 ,118 239 (119
il040X SURROGATES
2-f luoropher,ol l RiCGYHY 74.~, 68.2 71.1 68.4 b7.b 74.9
Z,4,b-Tribrornuphe.nol l RecDVH'f 75,4 b.: .. 0 72.b 69.4 72.2 K,.2
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IO·JUL·l'NO
Keyston, lu
Oite Sa•pled
Custooer ID
Pa.ru.etr.rs Units
S.nopies
9-1):7
4-Joo-1-m
S-3·fP 0-2'
9-028 9-0L'I
4·JltH9'10 4·JUfh990
5·3·fe 2-4· S-5-F~ V-0.5'
9-/JJ(/ 9-031 9·032
4·JlJl·l990 4·JUh-l'l90 4-JLN-I 9-1:;
S-5-fP 2-4' S-6-fP 0-2' S-6-fP :-,·
-------------------------------------------------------------------------------------------------------------------------------
lSollds at 103'C ' 79.7 B0.7 b4,9 85.2 75.5 76. 7
B040X
i'her,ol ug/~g 77.o 103 (77,0 <.58.5 (66,0 <o5.0
2-Chlo~o~henol ug/lig (62.:, \b2.0 \77.0 <:.a. 5 (66.0 (65.0
2-Nitrophenol ug/Kg <o2.5 <.62.0 (77.0 <.58.S (66.0 <o-5.0
214-D1methy lpher,ol ug/Kg ::62.5 <.02.0 ,77.0 144 (66.0 (65.0
214-Dicnlorc,phenol ug;lg (62.5 <62.0 <.77.0 <.58.5 (66.0 (65.IJ
4-Chloro-3-methy lpheno l ug;lig <62.5 <.o2.0 <77.0 <.58.5 (66.0 <65,(;
21416·ir1cnlorophenol ug!l(g '-l ~"5 '124 <1'54 <.117 (132 <.130
2, 4-(1ir11 tropner1ol ug/Kg <125 <.~24 (1 ~,4 <.I 17 <.132 <130
4-Nitr.;phenol ug/~g <r25 <124 <.154 2b3 138 173
2, 3,5,b-1 ctncr1lorophencl ug/Kg <125 <.124 <.154 <.117 \l32 {lj,)
2-~;;tny 1-410-air,1 troph;;nol ug/~.g <125 ~124 <154 '117 <:32 (13\l
Pentacnloroph1:T1c.l ug/Kg <12~, ,.124 ,r .. , q~{ :.132 (13(1 I .•L
80-IOX SUJ;iD&AH5
2-F luoropnenol ,, ~·ec,,-.,·cry 57 .(: o;.o 41.3 in.3 57.4 5i.8 •
2, 4 ,tr i r iorc,wupr.er,,,l ' Rc,:c,,er·r 77.4 ~-~.4 8,). (; 74.7 71.4 74.(i
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D
H
IO·JUL·19'10
Keystone ID
Date Su,pled
Cust011,er ID
Parlllleters ur,its
Sa.pies
9-1)33
4·JUN·1990
S-9-F~ 0-2'
9-034
4-JUIH'/90
5-9-F" 2·4'
HJ:3'5
4·JlJN-lqqi)
5-lbA·EA
9-1)36
4-JUN-1990
S-loB-EA
9-037
4-JUN-19'10
S· 17·EA
9-038
4-JUN-19~J
S-23-EA
-------------------------------------------------------------------------------------------------------------------------------
lSolidS it !03'C ., 76.: 7'i. 9 :J.9 64. 1 bl. 7 28,o •
8040X
Phenol ug/Kg (o4.0 (b.i,5 (9j,0 (78,0 (81 .o \i ?-5
,-Chlorophenol ug/,.9 <.64.0 <bi.~, \93.V (78,0 ,a1 .c, <.175
2-Ni trav11:no l uij;Kg <64.0 <.62.5 ,93.0 <.78 ,t) ,.81 .o (175
2, 4· Di.oHhy lphenoi uglKg (64.(, ;:o2.5 13'i 294 (81.0 ,:175
i ,4-0icnloropt-rcnol u~l.g ,a4.0 \b2,5 (93.0 {.78.0 (81.0 -.175
4·Chloro· 3-,,ethy !phenol Jgl,.g (64.(, (62.5 <.93.0 <78.0 (81 .o \175
2,4 16-ir1ci1lvrophenol ug;sg ~i28 \l~ <16b <1~'6 <102 i.350
214-0ini tr oph1:nol Uij/Kg s.128 '12:, '.186 <. l:-6 (162 (JC.,(J
4-Ni trophrnol ug/,g \-l~~ 13') ,,, ... ,::-24◊ <tb2 <:3~.,0 LLO
213,5,b-T etr acnloropileno l u;;f.g (1Z8 '1:-s (186 <1.:,6 (lb2 (JC.,0
2-~.thy l ·4 ,o-aini tropher,ol ug;~g :.1~'8 <125 <186 <156 (1b2 <350
Pentachlorophenol ug/Kg <.il6 <.1 ~--5 1540 CCC ,.}<J-.J 630 ( 3:.0
0040 X SlJf,j;1J6A TES
2-f luorophenol l Reco,·er)· 40.5 49.5 44.3 44.2 44.0 b3.3
2,4,b-Trioroffivphenol ~ R1:co·,i::r·t b4,8 64.8 67,3 b8 ", •L 65.3 78.9
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!O·JUL·1990
Keystoroe ID
Date S•epleo
Cust0&er ID
,Solios at 103'C
802ilX
!sopropyl Ether
8020X ~ilGATES
Benzotri fluoride
8040X
Pherool
2-Chloropherool
2-Nitropher,ol
2, 4-t,u,etny lpher,ol
~,4-Dicnlorophenol
4-Ch lo ro-3 ·eetr.y lpner,o I
214,0-Tric:hloropr.enol
2, 4-Drni tropntnol
HH tropher,ol
2 ,3, ~.,o-T etr achlorc.phenol
2-~etr,y 1-4 ,6-dir.1 tropnerool
Per,t achloropheno I
8041)X StJ!;,ilGATES
2-Flu,irc,phenol
2,4,6-Tr1br""opnenol
9-039 9-(,41)
o·JUN-1990 o-JlJN-1 ~iO
C·ll·OSE 0·2' C·ll·OBE
4-4.5'
l av. 1 90.9
ugiK9 NR tlR
• Recovery NR NR •
ugJKg 80.3 94.3
ug/Kg (62,0 <.55.0
ug/Kg (62,0 ,55.0
ug/Kg (62,(., <.55,0
ug/1.g <b2.0 ,.55.0
uyj~g <.b'.2.0 (:',5.(1
ug;lg '1i4 t.110
ug/Kg (124 <.11 (,
ug;fg <1~4 (110
ug/Kg (12A <.1!(1
ug/1\g <li4 s:11,)
uljJ'Kg <l:'4 ; 111)
.: Reco·,cry 01.7 ol.8
l Recovery 8J.◊ 81.2
Job r,.-e: ~9t)-06. 9
9-041 ~--('42 9-(143 9-044
5-JUN· 199tl 5-JUN-1990 5-JUto-1990 5-JUN-l 9'11)
1-1-0SN 0·2' l-:-OSN b·B' l·HlSN o-8' X-7-lf 0-::·
i«'llCATE
84.8 92.4 91.7 87.0
NR (11)8 rfi NR
NR 97.7 t.R NR
60.8 63.6 (54.5 (57.5
<59.0 (54.0 <:-4.5 (57 .5
(59.0 (!:,4.0 (54.5 <.~,7 -~
(:-9.◊ (!:4.0 <.54.5 (57.5
<.59.0 (54.0 (:.4.5 <..57 .5
(59.C, (54.0 (54.5 (57.5
<118 q,)8 ,109 <115
<118 '108 <JO'i <.115
(I 18 (11)8 <1(N \1 lS
<11& ,:1(18 :l(ri d 1~,
<.l 18 ;108 <IOI <115
<113 '.1('8 <.109 (11 ~.
:8.b ~.a. 7 6S.4 67. l
78.b 76.4 74.5 7;,8
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D
H
u
I
g
r.t·fst1Ji1€ I[s
[1.i;c 5u,p1cd
Cu:tvi11cr ID
·.:s~-lia: Gt H:::lc
Sil'.,;c.r
A, ;e_r,iC
[:or ::.i.F:
~:":.'"t;IJ!"";"
Lt.;-::!
f:;):;::1).1.
I:,:,pr::-;y1 f :~--:~
~~i4i)X
~·Mr1.:-l
2 •Cfil(,r L•jjf'IE:,:-i.
i-r•1 trc.pt1ff1•:• l
: , 4-[1,.,l!!e ~: !7· ~ .... :-:11t.•l
2, 4-.C 1cnlor0v,t.itC1i
~-Cnlor ,:.-j•n:1:.~:-,"r' lp,1er:.:, i
:-, 4 ,c,-r r icii lVrL'p/11::r.ui
i, 4-[, ini tr .:•pii€.i1ol
4-N i tr~1pt1tnol
~, 31 ::, ,6-1 o:. tr G-:r!iur(,pnc.~,c,l
i-M:;:r,;· l -4 1 b·omi -croprieno l
;-er, taci,lo r c.phcr1c, 1
8(\..!;)~. S\Jf$"JGA TES
i-F lu.:-ropr1tr!"l
21416· l r ibrOii·:'.'•j:,nl:.ru~ l
IJrrit5
dy/• .. g
;.ig,:~.~
Uoj/F.g
'''li•g
L;,;/!:.,;
,,.i,q
:.:;:''···;
;.i~jk.~
1_;g/l'.g
ug,:ty
v9i~.;
ug;,.g
cp.9
ag/,g
il·~:'~-.g
ug;lg
cgft..g
~ Rccv;;c.ry
~ ~E~Ji~?'"y'
~-,A:, -;•-(At-
tr·Ji.JN· ! ~ ~::: 5-Jur~-;-?90
A-7-Lf 0-2· i-7-LF 2-4·
[:U~1lCAlt
87.7
.. ,
,:'.., .•. '· _, / . ·.
·:-; ,,
·, •· 1. ••·
, C"'"! :.
· .• 'I.\'
•1!4
'·; 14
<. l i4
,114
:.1 t 4
7~·.o
r~~:
:.t3.(,
;_t,),(;
'._12&
•.l2b
•.lii:r
. , ....
•. l..:.•:l
:.1::e
,. -,~. j
ij-(~7
S-JUN-19·~1)
,.-7-LF i-4·
;,,Ji:'L!CATE
S-(;48 -;•-;).1~ 9-0:.(i
5-J•JtVi9'1◊ o-JL~•-199{1 o-Jut,-;o.::,:
~-?-LF 8-l0" A-10-TP 0•2' X-10·T~ 4·:·
o5.b
;j;j,(;
i.58. (:
::,B.(•
\-~.(i
dlo
'.l l t,
;_ 116
;.11~
:.J lo
<:116
71.8
i(,C:
85,j
NR
,.:.&. ~
<:.f.:.
;_117
'117
\.ll7
<:17
::JJ7
77.b
<.l:'.iC
l 'ifitjt)
<e(."8
!51:)(l
tl40
·:o::r3
\tit • :::
:_ t-l , ::;
;01.(1
<.61,(j
:, 122
;_ 122
.. -.-. ,_ i ,;_,;_
7o.:·
8: .. 7
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D
B
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h:y::toric. I[;
Date Sar.,p~:C!
;:u;toon:r ~[1
5ihcr
Ar-si:.r11•:
6-ir!.U~
C;u;n;,11
Ct"1r C•i'i, llin1
tlcrcury
Lc.30
S.tle:!1u;
81)201.
Isoprwp7·l Erner
8(12(;~. SUHFiC~~:'.i:'E~.
8<'4Di
~·r1t.nol
i-C!,ioropf1Er1,:i l
2-N1tr0pnt.ri-:il
:: , ~-[: iri11: lri"f lpi,tl!•:• l
;: , 4 • 0ict-1 k•r(•µtler,c, l
~-Cr, lur ,J · 3-fi.~ tff1· ~~i,i.r1c-1
2, 4, o-T r 1cr1lur,;.pr,cr,,:, i
2, 4-[11r11 tr,:,~r;~i1,:,i
4-~ 1 t r,:,~r,0::-1,:i l
Z 12, :',16-i l:i:.r ~~:11,:,r 0~·!"\C.\tC•i
.2-~t. tt"1y 1-.! 1-:r Gi.r.1 Tr opr,e.riol
~-i:.r:t1i:r1 l .::,: ,:,p:--,~nc-1
d(1~{:X SU~f.1)3~iE5
.2-~ lLiC•r+:,p!1i:r,c,l
i, 41 c · Tr 1 ~r ·:•,:1+:,pn1:.r1•:• l
;.:g/~.g
:_;~:\;,~
;_;,i,-~.-;
;j~/t-.g
IJ,i/~-~
;_;,;/t..ij
~g,:\~
ij~/~.g
ug;tg
,;g/,.g
ug>,g
ug/r.g
i.1,J/tg
IJ-i,'~.g
i,i,;/f .. g
•Jg/'.•J
iJ~/!'.g
ug1Kg
t.g/F.g
\ E:.CC1"HY
~ ~.Ee,,·:.~ y"
·1-(:) 1
o-JUN·i~,;-:::
•.11 (i
•.11:::
q 11}
61.1 ., ... -' ~. :
' .. ..........
~ <-~~ 1-0-S.3 ~-::~,4 ;<:S:, ~-(;:,c
•~·JJt,·l19(i t,-Jut◄-i9'r1) 5-J:Jt;-1990 o-Jut~-1¥~1) 5-J~ ... ;<~-:
:_t·l ,:',
:iI.5
<6 l, :,
'· ~_ij
, 12.i
:. ~ :J
16:-
rm
z:-4.5
:54,:,
(54.5
B8 • .J
(54.5
;.1(;'-j
:._ j(:'?"
(59.5
1:1
oB9
88.3
j,j.)
:_;. l S·
;_n't
:,119
: i: 9
16.2
"'I:' ·' /·.••-
9j,3
NR
N~:
!IR
r~:
t~
NR
t.53.5
<53.1S
\:~.J.5
(.53. 5
<1(:(
:..1(;"7
:1G7
o4.5
67.~
t.<.
NR
<':Lj, =•
:.:.J. =·
(1(17
. , ... "":
'. ;,., ..
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H
0
' -. --j ; • ~._;:... • 'f':''i,.I
H.f;~,:.;,e l[:
(1ne 5ampi,::,:;
Cus tCmie.r 1 [1
~Svlios H l(;J'C
S1lvH
Ar;H,lC
Bar llJlii
1: . .; ,:;ii, l Uli:
C~1r0&iUii1
f:iHC:.iry
LCiU
::':,:ler1l1Ju·
.~:)~~).i,
!si:,pr•~~,.{1 E~r,er
~:::;:(;i su~:ADG~.:ts
&t:i:zotr l i lu.:,r 1,:;e
&·.:14;),-.
!:'i1H1C• l
2-Cr,lc,r c,phe:-,-:• l
:-~~i tr-.:-~-her,c,l
: I!· Dlt,t. ~ii'r' lp;,::,::,l
: 14-(1 l i:ir l,;,r C•~•i:iin:, l
4-Cr, l..:, rv-3-,;:: t r•r' lp:,t.:,,:, l
;: 1416-Tr l~iilc,rc,~,ner • .:il
2,!-~i~itropt:nol
4-~11 t rophe.n0l
1, j 15;ei-1 i::tr-1c,l..:,rL'p;-i!:.i10i
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ugi'.•J
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REVISION.
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~.l!';s l cnt l D
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lsovopyi Ether
G02◊1 SI.JhtQL;;.1[5
B1nzvtr1t!uor1de
il\1401
Phen~l
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: ·Nl ~rC?i~wru~l
2. 4 • ~1111ie ~n1 lphcr-o i
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REVISION
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~:1yiT.('T:i 1[,
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Stn,otcil !•,~rid~
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1-r~1 :,opher,lj l
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:1 4,b· ~rii:~l1Jri.1p:-:er .. !i
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4-~41 tr~pher11:il
2 ,J, 5, b· T etnchL,ro!]heno l
2-~eth'f l ·:l I l1 ·d 1r,1 ttupntr,.;!
Pent ithlor.;.pr1cno l
8'>4•iX 5Li-iiOGATES
l·F 1"o•ophenol
~ 44, b· l r 1brta,l'.\pt,,1,J1
u;/Kg
u:,i/t-g
•19/~~
ug:kg
ug/•g
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ugilg
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·; .:)!,U
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SG· ~-T►·
~--o.~·
8:i,,,,
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.:J2!
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08.·l
7:J.i
I AWO Technologies, Inc.
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APPENDIX B
SUPPORT DOCUMENTATION
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~~y1tN,~ il;
s~r,p l H•~ , .. ,,nt
Cu~t"1f,jr ![,
4Soli~= n ~r;J•c
Sii',er
Arc;e:,1c
8~r1U11
C;dt.H,•
C~ro•,u:n
Mercur)
lC~d
Silli"•1UA.
80401
Phu,~!
2-Chloropt,.r,c,l
2·N1 trcphenol
2, 4-[; 1rae thy lp~h?' ,J ~
;·, 4 · 0 !C:1"1foropn(niJ !
~-cr,lor,,-J-,;-ethy ipher.:-1
l 14,6-Tr 1c•lorJprfr,cJ
2, ~ · br,i trop~er,~ I
4-N1tr,ipl11nol
2,~1;,b-i~tr1~nl~ropr.e~~l
2-riEthy l ·4 ,O·,l 1n i. tr?ph-2r11Jl
~cr,tach lc,r opn.,,r-1
0041)J SUfcRO{j~TfS
'2-f luoroprenul
Z, 4 1 t· 1 r i br~i:•i:,!":t',.;,, l
i-::01
QA .J::
L,-,f' [l~L?~i,
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··-··· -----------···-····--····-·-··-········-······· -------··· , ,io:
,µ_QC
i_~[; [QN'!f..i,)~
i,;4r,,Lf
.:;-. :)iJ
Q~-~~
~-0)4 9-Ct5 ;-o:i
QA_ QC Q;e _ ~C ;;a _Q:: ,-::-re•,:,:· s-:: ;,, ,:,.:· ,.,.;; >!
~ ~SD L!r
.... ,, ''" ....... ·--·-·· ... ·--... --· .. --....... ·-----...... .,_
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METALS QAQC REPORT
ICP Serial Dilutions
KEYSTONE ENVIROMENTAL RESOURCES INC.
Tjatime: 9006221503 SampleID: SS2005L Sample Type: SD (S)
:-----------------------------------------------:
Analyte
Initial
( I )
Dilution :x Diff-
(S) :erence :----.------------------------------------------:
Aluminum 30605.1
Antimony_: <22.0
Arsenic <21.0
Barium 245.6
Beryllium __ : <1.0
Cadmium <LO
Calcium 2880.0 ' Chromium __ 70.2
Cobalt 24.2
Copper 25.6
Iron 103075.3
Lead 72.3
Magnesium __ 1850.2
Manganese __ 822.6
Mercury
Nickei <12.0
Potassium __ 1939.7
Selenium __ 979.8
Silver <2.0
Sodium 388.3
Thallium __ < Vanadium __ 177.3
Zinc 112.4
Cyanide
33044.51
<22.0
<21.0
258.01
<LO
<1.0
3256.5
80.0
27.0
41.0
112404.0
<26.0
2108.0
897.5 o.o
<12.0
2043.5
1070.0
<2.0
730.5 o.o
192.5:
226.0:
o.o:
8.0
' ' 5.0 /:
~J..,
~'. ' ' 60.2
9.1
13.9
9.1
9.2
\)OID
8.6
10Ll
:-----------------------------------------------
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METALS QAQC REPORT
Spike Sample Recovery
KEYSTONE ENVIROMENTAL RESOURCES INC,
Tjatime: 9006221511 SampleID: SS200SS Sample Type: SPIKE (SSR
:-------------------------------------------------------------------:
Analyte
: Ctrl ,Lmt.:
¼R
Spiked
(SSR)
Sample
(SR)
: Sp.Added
(SA) ¼R :-------------------------------------------------------------------: Aluminum 75-125 30632.4 --30605.1 2000 1.4:
Antimony __ : 75-125 119.7 <22.0 500 23.9:
Arsenic 75-125 1714.9 <21.0 2000 85.7:
Barium 75-125 2094.2 245.6 2000 92.4 :'-"'
Beryllium __ : 75-125 47.4 <1.0 so 94.B:
Cadmium 75-125 43.6 <1.0 so 87.2:/
Calcium 75-125 2599.3 2880.0 ' ' Chromium 75-125 227.3 70.2 200 78.6:-/
Cobalt 75-125 476.3 24.2 500 90.4:
Copper 75-125 254.0 25.6 250 91.4:
Iron 75-125 90552.2 103075.3 1000 -1252,2
Lead 75-125 491.9 72.3 500 83.9:
Magnesium __ : 75-125 1738.1 1850.2
Manganese __ : 75-125 1216.0 822.6 500 78.7:
Mercury 75-:125
Nickel 75-125 451.0 (12.0 500 90.2:
Potassium __ 75-125 ' 1395.4 1939.7 @ Selenium __ 75-125 849.7 979.8 2000
Silver 75-125 42.2 <2.0 so 04. 4.:votlJ
Sodium 7S-12S S43.3 388,3
Thallium __ 7S-12S -188.1 -226.7
Vanadium_ 7S-12S 611.S 177.3 soo 86,8:
Zinc 7S-12S S28,0 112,4 soo 83.ll
Cyanide 7S-12S :-------------------------------------------------------------------:
0
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KEYSTONE ENVIRONMENTAL RESOURCES, INC,
CASE NARRATIVE
I GENERAL
A, WORK ORDER
8, SAMPLE NUMBERS
C. SHIPPING PROBLEMS
II ANALYS_IS
A, ANALYSIS PROBLEMS
B, COMMENTS
M90-06,9
001-063
None __________________ _
None __________________ _
All eo20 and 8040 identifications are from
retention time only, All soil results are
on a dry weight basis. On the 8040"s:
The Lab Control Blank for samples 00?-012
contained Phenol at a concentration above the
detection limit, This value was subtracted
out of samples 003-012, The Lab Control Blani
for samples 014-016: 030-038 contained Phenc,
and 4-Nitrophenol at a concentration above the
detection limit, These values were subtracte1
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out of samples 014-016 and 030-038. The Lat
Control Blank for sam~•les 05~-063 ~onta1nej
Phenol and 2,4-Dimethylphenol at a concen-
tration above the d~tectio~ limit. These
values were subtracted out of samples 052-06],
1. AWD I TECHNotOGIES
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PGH-90-DAL-351
DATE
TO
FROM
SUBJECT
overview
September 14, 1990
Mr. Robert S. Markwell
Program Manager -Environmental Services
Beazer Materials and Services, Inc.
436 Seventh Avenue
Pittsburgh, Pennsylvania 15219
David A. Lan~
AWD Technologies, Inc.
Organic Data Validation
Keystone Environmental Work Order No. M90-06.107
The set of samples for Beazer (sampled 6/21/90) contained four soil
samples, one field blank, and one trip blank. The samples were
analyzed for isopropyl ether and phenols. Isopropyl ether was
analyzed by U.S. EPA Method 8020 and phenols were analyzed by
U.S. EPA Method 8040.
Summary
All elements were successfully analyzed in all samples. Areas of
concern with respect to data usability are listed according to the
seriousness of the problem.
Quality control criteria were met for all parameters.
Notes
2, 4-Dimethylphenol was detected in a laboratory blank. This
concentration was then subtracted out for other sample results.
The practice of subtracting out to adjust for blank contamination
is not consistent with U.S. EPA methodology.
National Functional
The text of this
usability.
The data were reviewed according to the
Guidelines for Evaluating Organic Analyses.
report addresses only these problems affecting
I AWD Technologies, Inc. Penn Center West Building Ill Suite 400 Pittsburgh Pennsylvania 15276 Telephone [phone] Telecopier 412 788 1316
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AWD Technologies, Inc.
PGH-90-DAL-351
Mr. Robert S. Markwell
Beazer Materials and Services, Inc.
September 14, 1990 -Page 2
Information Regarding Report Content
Attachments:
1. Glossary of data qualifiers.
2. Data Summary. This includes:
a. All positive results with qualifier codes, if applicable.
b. All unusable detection limits qualified with an "R."
c. All estimated detection limits qualified with ''UJ.11
3. Appendix A -Results as reported by the laboratory (no
corrections were made during data validation).
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GLOSSARY OF DATA QUALIFIER CODES
(ORGANICS)
Codes Relating to Identification
(confidence concerning presence or absence of compounds)
u = Not Detected. The associated number indicates
approximate sample concentration necessary to be
detected, or not detected substantially above the level
reported in laboratory or field blanks.
(NO CODE) = confirmed Identification.
R = Unreliable Result. Analyte may or may not be present in
the sample. Supporting data necessary to confirm result.
codes Related to ouantitation
(can be used for positive results and sample quantitation limits)
J =
UJ =
Analyte present. Reported value may not be accurate or
precise.
Not detected.
imprecise.
Quantitation limit may be inaccurate or
Other Codes
Q = No analytical result.
I AWD Technologies, Inc.
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n DATA SUMMARY FORMS
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lrA SUMMARY
lcH CLP DATA FOR SAMPLES COLLECTEO 6i11/90
IAZER • RALEIGH
ystone Environmtal Job. I N90·06.10l
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Suple No. X·II
!-10'
:OMPOUND Units
X·II
16-18'
HI
H'
HI
H'
1;~;;····························;;i;;··········;;;:;·········;;;:;·········;;;:;·········;;;:;···
i·Ch1oropheno1 ug/kg <20.l <18.8 <20.6 <18.l
a·Nitrophenol ug/kg <20.3 <18.8 <20.6 <18.l
.,4·Di1ethylphenol ug/kg <20.l <18.8 <10.6 <18.l
.,4·Dichlorophenol ug/kg <20.3 <18.8 <20.6 <18.l
l·Chloro·3·1ethylphenol ug/kg <10.3 <18.8 <20.6 118.l
1,1,6-lrichlorophenol ug/kg <40.6 <ll.6 <11.2 ill.I
,Hinitrophenol ug/kg 140.6 <ll.6 <41.2 <ll.l
l·Mitrophenol ug/kg 50.9 ll.8 56.9 79.2
lt,l,l,6·Tetrachloropheno1 ug/kg <40.6 <ll.6 <ll.2 <ll.4
ltMethyH,Hinitrophenol ug/kg <10.6 <ll.6 <ll.2 <31.1
?entach1oropheno1 ug/kg <40,6 137.6 <11.1 <ll.l
-;;;;;;:;;~;;;'. ................... '.:'.'.: ........... ;;:;··········;;:;··········;;:;··········;;'.; .. .
u
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1~~'.~~~~··························~'.'.:'. ............................. .
?henol ug/l <0.500
-
·Ch loropheno 1 ug/l <0, 500
·litrophenol ug/l <0.500
.,4·Di1ethy1pheno1 ug/l 10.500
',l·0ich1oropheno1 ug/l <0.500 l ·Ch1oro·3·1ethy1pheno1 ug/L 10.500
.,l,6·Trich1orophenol ug/L <1.00
l,4·Dinitropheno1 ug/l <1.00
ll·Nitrophenol ug/l 11.00
IJ,3,5,6-letrachlorophenol ug/l <1.00
l·Methy1·1,6·dinitropheno1 ug/l <1.00
mentach loropheno I ug/l < I. 00
1sopropyl Ether __ ug/l <1.00 <1.00
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APPENDIX A
R RESULTS AS REPORTED BY THE LABORATORY
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AWD Technologies, Inc.
APPENDIX B
SUPPORT DOCUMENTATION
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k,7s:0;,, II•
Date 5H:;-i.e~
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Par.11ncter;
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6G20:. SJf.:;DGA~tS
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1'."-•U u, ._ 1= ,t'I •LI
:~ ,n t
If! •LI I-'
:-I·• HI •LI ,-.:, ~ :L. L.-:':I l_l
1!!111 -- - -- - - -
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F.c1·;t,:i1ic it
Detc SH,pl:a
Cu;tonicr ff
i· Ni ':~•:•v··F:d
2 ! ~-[!j]rf: "::fri l~•Tr::iiC•l
2, 4-[;i,::r,:c-r 0~·t11:.::.:-l
4-Cril:ir:--J· r-ic:;-1';" :i)t1Ci1c-l
2, 410-Tr i~tL,r.:-~tio:r:.:•l
: 14 -t•1r1i tr-:,p!1l:.!n:, l
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PGH-90-DAL-352
DATE
TO
FROM
SUBJECT
overview
September 14, 1990
Mr. Roberts. Markwell
Program Manager -Environmental Services
Beazer Materials and Services, Inc.
436 Seventh Avenue
Pittsburgh, Pennsylvania 15219
David-A. Lang~
AWD Technologies, Inc.
Inorganic Data Validation
Keystone Environmental Work Order No. M90-06.22
AWD
TECHNOLOGIES
The set of samples for Beazer-Raleigh (sampled 6/6/90 -6/7/90)
contained 15 samples. These included 3 water samples, 10 soil
samples, and 2 rinsate blanks. The samples were analyzed for
metals and cyanide by methods of the U.S. EPA's Contract Laboratory
Program (CLP).
Summary
All elements were successfully analyzed with the exception of those
qualified as unreliable "R". Areas of concern with respect to data
usability are listed according to the seriousness of the problem.
Note that the Summary of Data Qualifiers (Table 1) lists the
specific samples which were affected. These include:
Major Issues
The matrix spike recovery was less than 30 percent for antimony,
selenium, and cyanide. Detection limits of associated samples are
flagged as unreliable, "R''· Positive results of associated samples
are qualified as estimated, ''J".
Minor Issues
Aluminum, arsenic, barium, calcium, chromium, cobalt, copper, iron,
manganese, sodium, and zinc were detected in laboratory blanks at
levels which required qualification of data. Positive sample
results with concentrations less than 5 times the amounts present
in the blanks are qualified ''U".
AWOTechnologies, Inc. Penn Genier Wesl. Building Ill. Suite 400 Pittsburgh Pennsylvania 15276 Telephone [phone] Telecopier 412 788 13:6
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AWO Technologies, Inc.
PGH-90-DAL-352
Mr. Robert S. Markwell
Beazer Materials and Services, Inc.
September 14, 1990 -Page 2
The post-digestion spike recovery for thallium was greater than
115 percent. Therefore, the detection limits of associated samples
are qualified "UJ'', estimated.
Serial dilution results
calcium and magnesium.
"J", estimated.
exceeded quality control criteria for
Associated sample results are qualified
Notes
The data were reviewed according to the National Functional
Guidelines for Evaluating Organic Analyses. The text of this
report addresses only those problems affecting usability.
Information Regarding Report Content
Table 1 is a summary of qualifiers added to the laboratory's
results during data validation.
Attachments:
1.
2 •
3 •
4 .
Glossary of data qualifiers.
Data Summary. This includes:
a. All positive results with qualifier codes, if applicable.
b. All unusable detection limits qualified with an ''R.''
c. All estimated detection limits qualified with "UJ."
Appendix A -Results as reported by the laboratory (no
corrections were made during data validation).
Appendix B -Support Documentation includes details to support
the statement of this report.
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GLOSSARY OF DATA QUALIFIER CODES
( INORGANICS)
Codes Relating to Identification
(confidence concerning presence or absence of compounds)
u = Not Detected. The associated number indicates
approximate sample concentration necessary to be
detected, or not detected substantially above the level
reported in laboratory or field blanks.
(NO CODE)= Confirmed Identification.
R = Unreliable Result. Analyte may or may not be present in
the sample. Supporting data necessary to confirm result.
codes Related to ouantitation
(can be used for positive results and sample quantitation limits)
J =
UJ =
Analyte present. Reported value may not be accurate or
precise.
Not detected.
imprecise.
Quantitation limit may be inaccurate or
Other Codes
Q = No analytical result.
TABLE I
Ii SURIARY Of om QU!l!F!ERS 11 .......................... ·-··································································-
' lnalyte Suples Affected Positive Results Non·Oetects Bias Co11ents
1·······················································································································
Alu1inu1 C90A U H[GH
Onti10ny All BUT C91A R 2
CIIA 2
Orsenic CIOA, 11002, 11018, l10680 u HIGH
11224, 11S02, 11901, 15011
lllf21
lariu1 193 u HIGH
1,lciua CIOA, C91A, cm u HIGH
11002, 11068, l10680, 11221 J
11S02, 11602, 11901, 15018
lllf21
lhr01iu1 cm, 193 u HIGH
lobalt 11S02, 11901, lllf21 u HIGH
Copper c90A, cm, 193 u H[GH
lyanida All BUT 11221 ANO CIIA R
11224, CIIA
Iron CIOA u HIGH
!a9mlu1 11002, 11018, 110680, 11221 J
I 11S02, 11602, 11901, 15018
lllf21
ianganesa 193 u H!GH
eleniu1 All BUT C91A R
C91A
lodiu• CIOA, CIIA, cm, 11068 u H[GH
110680, 11221, 11S02, 11602
~halliua
11904, 15018, lllf21, 193
193, !1S02, 11068, 110680 UJ I
I Xllf21, 11002, 11221, 11602
11904, 15018
Zinc CIOA, C91A, cm, 11002 u H[GH
m 11224, 11S02, 11602, 14904
lllf21,193 ---------------------------------------------------------------------------------------------------
~OKNEIIS
• Laboratory blank conta1ination. , 1. LOI 11tril spike recovery,
1 • Serie! dilution results exceed quality control criteria.
' . Post digestion spike is greater than 115l.
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I QATI SUMIIRY
smLES COLLECm 6/6/90 • 6/1/90
BEIZER·RALHGH IIEYSIONE IORK ORDER 1110·06.11
PIGE10Fl
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[NORGAN[C SO[l RESULIS
(19/kg)
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RESUL I
---------------------------------------------------------I SANPLE NO. ----------------------------------------------------------------------------------------------------------------------------
lnalyta [DL CRDL X 1002 11068 X10680 X 1221 11S01 I (19/kg) (19/kg) Field duplicates ----------------------------------------------------------------------------------------------------------------------------
llu1inui 1.2 10 6160.00 5100,00 5810.00 16100.00 11100.00 I Int iaony u
Arsenic o. 2
8ariu1 0. 2
Berylliu1 0.2
1cad1iu1 0. 2
CalciUI 2.8
Chr01iu1 0. 6
.Cobalt 0. 6
Capper 0. 2
[ran 0. 8
Lead 0. 2
1Nagnesiu1 u
Manganese 0. 2
Mercury 0.1
.Nickel 1.,
Patmiu1 13.2
Seleniu1 0. 2
Si her u I S0diu1 10. 8
Thalliu1 u
vanadiu1 0. 2
.Zinc 1.0
Cyanide 0. 5
.Percent solids:
[DL: [n1tru1ent Detection Li1it
ICRDL : Contract Required Detection L i1it
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12 5.20 R
2 1.10 U ,o · 110.00 U
1 0. ,2
1 0.24 U
1000 ll5.00 J
2 11.20
10 12. 60
5 1.60
20 29000.00
0. 6 12 .20
1000 Ill.DO J
l '31.00
0.1 0. 12 U
8 2.80 U
1000 550.00
1 0.21 R
2 0. ,1 U
1000 98 .10 U
2 0.17 UJ
10 37.10
' 30.00 U
0. 5 0. 59 R
90, 1
UO R UO R 5. 60 R 5 .20 R
1. 10 U 0. 80 U 2. lO U 0. 91 U
US.00 151.00 56. 60 '3.10
0. 66 1. 10 U9 O.ll
0. 22 U 0 .12 U 0. 26 U 0. 2, U
1120.00 J 11l0.00 J 113.00 J 215.00 J
16. 10 16, 60 1'.10 1.60
ll. 00 IUO uo uo u
11.40 13. 10 5. 80 uo
29100.00 10600.00 llS00.00 11900.00
12. 20 11. 80 1'.00 11.50
1"0.00 J 1180.00 J 818.00 J 618.00 J
50UO 313. 00 11. 50 59.60
0.11 U 0. 11 U 0. ll U 0. 12 U
1.10 6. 00 l. 10 U 2. 80 U
1010,00 1160. 00 530.00 563.00
0.12 R 0 .12 R 0. 26 R 0.21 R
0.14 U o.u u 0, 51 U 0.17 U
213.00 U 318.00 U 128.00 U 128.00 U
0 .14 UJ 0.14 UJ 0.51 UJ D.17 UJ
57.70 50.10 ,uo 1UO
15.50 11.60 15. 10 U 20.10 U
0.55 R 0. 56 R I. 80 J 0. 59 R
91.6 90. 0 71.9 BU
I om SU!MIRY
ISl!PLES COLLECTED 6/6/90 -6/7 /90
BE!ZER-RILEIGH
KEISTONE IOR! ORDER 1!90-06.22
.PAGE 2 OF 3
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INORGIN!C SO!l RESULTS
(19/kg)
--------------------------------------------------------------------------------------------------------------
1
IOL
(19/kg)
l llu1inu1 2.2
lnti10ny U
Arsenic 0.2
IBariui 0.2
Berylliu1 0.2
Cad1iu1 0.2
Calciu1 2.8
UChro1iui 0.6
Cobalt 0.6
Copper 0.2 nlron 0.8
Lead 0.2
!agnesiu1 4.0
U!anganm 0.2
Mercury 0.1
Nickel 2.4
Potassiu1 73.2
1Seleniu1 0.2
Silver 0.4
Sodiu1 10.8
1Thalliu1 0.4
Vanadiui 0.2
Zinc 1.0
CROL
(19/kg)
40
12
2
40
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2
10
5
20
0. 6
1000
3
0. I
8
1000
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2
1000
2
10
4
mo2
1730.00 12100.00
1.40 R 5. 30 R
3. 10 1.40 U
45. TO 62. 80
0. 41 0.35
0.25 U 0.24 U
149.00 J 322.00 J
17. 10 10.70
4.90 2.80 U
4.90 5.50
21100.00 18300.00
15. 00 10. 80
317 .00 J 596.00 J
176 .00 111. 00
0. 12 U 0. 12 U
3. 10 2. 90 U
231.00 374.00
0. 25 R 0.24 R
0.49 U 0.48 U
Ill.DO U It I. 00 U
0.49 UJ 0.48 UJ
43. 20 34.20
20.10 U 18. 30 U
RESULT
Si!PLENO.
!5048 Xllf24
15300.00 15000.00 188. 00
UO R 5.50 R 5. 00 R
2.30 U 1.90 U 0.23 U
199. 00 73. 50 0. 56 U
3.50 0.52 0. 23 U
0. 22 U 0. 25 U 0.23 U
3510.00 J 889.00 J 40.00 U
15. 40 12. 90 1.30 U
22. 80 3.00 U 0. 68 U
16.10 7.20 1.80 U
26200.00 28500.00 225.00
14.80 13.90 1.00
t 0000. 00 J 909.00 J 17.90 U
1060.00 191.00 1.20 U
0. 11 U 0. 13 U 0. 11 U
27.60 4. 10 2.70 U
1230.00 544.00 83. 00 U
0. 22 R Q.25 R 0. 23 R
0.45 U 0. 50 U 0.45 U
798.00 U 505.00 U 65. 00 U
0. 45 UJ 0. 50 UJ 0.45 UJ
12.70 39.90 1.20
81. 10 22.10 U 1.20 U
0. 56 R 0.63 R 0. 57 R Cyanide 0.5 I;;~~;~~-~~;;;~;---------------------------------;;:;----------;;:;-----------;;:~----------;;:;----------;;:;---0.5 0. 61 R 0.60 R
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SA!PLES COLLECTED 6/6/90 -6/7/90
-
EAZER-RALEIGH
1EYSTONE ICR! ORDER 1190-06.22
AGE 3 OF 3
I IMORGANIC AQUEOUS RESULTS
I ug/1 l
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I ug/1 l
CROL
(ug/1)
DAlu1inu1 11.0 200
Anti my 22.0 60
Arsenic 1.0 10
RB1riu1 1.0 100
Berylliu1 1.0 5
Cad1iua 1.0 l
1Calciu1 IU 5000
Chro1iu1 3.0 10
Cobalt 3.0 50
Copper LO 15 llrron u 100
IILead 1.0 3
!agnesiu1 10.0 5000
l !anganese LO 15
Mercury 0.1 0.1
licke 1 11.0 40
1Potassiu1 366.0 5000
Seleniu1 1.0 5
Silver 2.0 10
Sodiu1 54.0 5000
1Thalliu1 2.0 10
Va.nadiu1 1.0 50
Zinc 5.0 20
C90A
11.80 U
22. 00 R
1.60 U
I.DO U
1.00 U
1.00 U
21.00 U
3. 00 U
3. 00 U
1.90 U
13.90 U
1.00 U
20.00 U
LOO U
0. 20 U
11.00 U
366,00 U
1.00 R
1.00 U
Ill.DOU
1.00 U
I.DOU
49. 80 U
10.00 R
RESULT
SAMPLE NO. -------------------------------------
C91A cm mm mm
Field blank Field blank
791.00 83400.00
150.00 J 22, 00 R
19.70 Q
148. 00 1.00 U
17. 10 I.DO U
17.20 1.00 U
27. 70 U 36. so U
21. 00 11.00 U
53.00 3.00 U
58.00 uo u
m.oo 115000.00
15.40 Q
767.00 21.40 U
23.70 I.DO U
2.00 Q
49,80 11.00 U
366.00 U 366.00 U
IUD J Q
2.00 U 1.00 U
187.00 U 243.00 U
12.50 Q
74.80 LOO U
40.70 U 15.70 U
19.00 J Q 10.00 R 10.00 R 1::~~~~----------------------~~:~----------------~-0 --------------------------------------------------------------
1 lOl : Instrmnt Detect ion L i1it
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CROL: Contract Required Detection Li1it
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• APPENDIX A
I RESULTS AS REPORTED BY THE LABORATORY
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U.S. EPA -CLP
l
INORGANIC ANALYSIS DATA SHEET
Lab Name: KEYSTONE-MONROEVILLE Contract:
•. 00003
EPA SAMPLE NO.
:---------------:
C91A
Lab Code: KEYPA Case No.:
Matrix (soil/water): WATER
Level (low/med): LOW
SAS No.: SDG No.: X4602
Lab Sample ID: 6.22-006
Date Received: 06/07/90
% Solids: 0.0
Concentration Units (ug/L or mg/kg dry weight): ug/L
CAS No. Analyte :concentration c: Q
7429-90-5 Aluminum 791.00
7440-36-0 Antimony_: 150.00
7440-38-2 Arsenic 19.70
7440-39-3 Barium__ 148.00 B
7440-41-7 Beryllium: 17.10
7440-43-9 ,Cadmium_ 17.20
7440-70-2 Calcium_ 27.70 ,B
7440-47-3 Chromium : 21.00
7440-48-4 Cobalt__ 53.00
7440-50-8 Copper __ : 58.00
7439-89-6 Iron___ 495.00
/7439-92-1 Lead___ 15.40
:7439-95-4 Magnesium: 767.00 :e
:7439-96~5 Manganese: 23.70
'7439-97-6 Mercury_: 2.00
7439-02-0 Nickel 49.80
7440-09-7 Potassium: 366.00 u:
7782-49-2 Selenium_: 14.90
7440-22-4 Silver__ 2.00 U'
7440-23-5 Sodium__ 187.00 B
7440-28-0 Thallium_: 12.50
7440-62-2 IV.nadium : 74.80 -. •. ,·ztdc -: 40. 70 ~:cv-:anide_: ____ 1_9_._o_o_
Color Before: COLORLESS·.•·· Clarity Before: CLEAR
Color After: COLORLESS Clarity After: CLEAR
Comments:
FORM I -IN
M
p
p
F
p
,P
p
p
p
p
p
p
F
p
p
CV
p
p
F
p
p
F
p
p
AS
Texture:
Artifacts:
3/90
I
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u
D
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R
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U.S. EPA -CLP
1
• OC1'04
EPA SAMPLE NO.
INORGANIC ANALYSIS DATA SHEET :---------------·
Lab Name: KEYSTONE-MONROEVILLE
Lab Code: ~EYPA Case No.:
Matrix (soil/water): WATER
Level (low/med): LOW
%. Solids: 0.0
Contract:
SAS No.:
C92A
SDG No.: X4602
Lab Sample ID: 6.22-007
Date Received: 06/07/90
Concentration Units (ug/L or mg/kg dry weight): ug/L
' ' ' ' CAS No. Analyte :concentration tCI Q M
' ' ' ' 7429-90-5 Aluminum -83400.00 p
7440-36-0 Antimony_: 22.00 :u p
7440-38-2 Arsenic: NR
7440-39-3 Barium --1.00 :u ,P
7440-41-7 ,Ber-yllium: 1.00 IU :P -~
7440-43-9 Cadmium -1.00 IU :p f
7440-70-2 Calc:ium 36.50 :e: :p T ., -• 7440-47-3 Chromium ' 12.00 ' ' :p ' ' ' 7440-48-4 Cobalt 3.00 :u: :P
7440-50-8 Copper __ : 4.00 :e, IP
7439-89-6 Iron 115000.00 ' ' p ' ' 7439-92-1 Lead ' ' NR ' ' 7439-95-4 I Magnesium I 21.40 Bl p
7439-96-5 I Manganese: 1.00 UI p
7439-97-6 :Mercury_: NR
7439-02-0 lNickel 12.00 UI p
7440-09-7 :Potassium I 366.00 UI p
77B2-49-2 I Selenium ' NR -' 7440-22-4 ;Silver 2.00 •u p
7440-23-5 !Sodium --243.00 B p
7440-28-0 I Thallium ' NR -' 7440-62-2 I Vanadium ' 1.00 u p ' 74i0-6"-6-t'rlnc -: 15.70 B p
:--~: ')Ciani de : NR
,_ ,if .... r··· ,.'~---. . ~ . •·., I
. . ..!-..
Color Before:
-. _;:
Clarity Before: CLEAR Texture:
Color After: YELLOW Clarity After: CLEAR Artifacts:
Comments:
FORM I -IN
3/90
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U.S. EPA -CLP
1
.. OOC14
EPA SAMPLE NO.
INORGANIC ANALYSIS DATA SHEET :---------------:
Lab Name: KEYSTONE-MONROEVILLE
Lab Code: KEYPA Case No. :
Matrix (soil/water): SOIL
Level (low/med): LOW
1/. Solids: 88.2
Contract:
SAS No. :
X93
SDG No,: X4602
Lab Sample ID: 6,22-008
Date Received: 06/07/90
Concentration Units (ug/L or mg/kg dry weight): MG/KG
CAS No. Analyte :concentration :c: Q M
7429-90-5 lAlumint.1m 188.00 :p
7440-36-0 Antimony_: 5.00 u: N :p
7440-38-2 Arsenic 0.23 u: IF
7440-39-3 Barium 0.56 B: :p
' 7440-41-7 Ber-yllium: 0.23 u: :p i 7440-43-9 Cadmium 0.23 u: IP f 17440-70-2 Calcium 40.00 s: E :p
17440-47-3 ChromiL1m -: 1.30 Bi IP
7440-48-4 Cobalt 0.68 u: IP
7440-50-8 Copper __ : 1.80 Bi IP
7439-89-6 Iron 225.00 * p
7439-92-1 Lead 1.00 w F
7439-95-4 Magnesium: 17.90 :s E p
7439-96-5 'Manganese: 1.20 :s p
,7439-97-6 Mercury_: 0.11 :u CV
:7439-02-0 Nickel 2.70 :u p
'7440-09-7 Potassium: 83.00 :u: p
7782-49-2 Selenium ' 0.23 :u: N F -' 7440-22-4 Silver 0.45 :u: p
7440-23-5 Sodium 65.00 :B: p --7440-28-0 Thallium ' 0.45 :u; w F ' 7440-62-2 Vanadium ' 1.20 :s: p -' 7440-66-6 1 z1·nc 4.20 :e: ,P l"~ !Cyanide : 0.57 :u: N :AS ·-.: -j-'' I
... ,.
Color Before: BRO : Clarity Before: Texh1re: FINE
Color After: WHITE Clarity After: Artifacts:
Comments:
FORM I -IN
3/90
I
n
D
D
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U.S. EPA -CLP
1
•·00992
EPA SAMPLE NO.
INORGANIC ANALYSIS DATA SHEET :---------------:
Lab Name: KEYSTONE-MONROEVILLE
Lab Code: ,:EYPA Case No.:
Matrix (soil/water): WATER
Level (low/med):
% Solids:
LOW
o.o
Contract:
SAS No.:
C90A
SDG No. : X 4602
Lab Sample ID: 6.22-005
Date Received: 06/07/90
Concentration Units (ug/L or mg/kg dry weight): ug/L
:CAS No. Analyte :concentration c: Q M
:7429-90-5 Aluminum 11.80 Bi :P
:7440-36-0 Antimony_: 22.00 u: :P
:7440-38-2 Arsenic 1.60 Bi IF
17440-39-3 Barium 1.00 u: :P •
:7440-41-7 Beryl l ic1m: 1.00 u: p ,
:7440-43-q :Cadmium -1.00 u: p t
:7440-70-2 :Calcium 27.00 Bi p "'
:7440-47-3 :Chromium ' 3.00 u: p ' ' -7440-48-4 :{:oba l t 3.00 U' p
7440-50-8 :Copper __ : 1.90 B p
7439-89-6 : Iron 13.90 B p
7439-92-1 Lead 1.00 u F
7439-95-4 Magnesium I 20.00 u p
7439-96-5 Manganese: 1.00 u p
7439-97-6 Mercury_: 0.20 u CV
7439-02-0 Nickel 12.00 u IP
:7440-09-7 Potassium: 366.00 U, :p
17782-49-2 Selenium ' 1.00 u: IF ' -:7440-22-4 Silver 2.00 u: :P
17440-23-5 Sodium --171.00 Bi IP
:7440-28-0 :Thallium • 2.00 u: IF • -17440-62-~ :vanadium ' 1.00 u: IP •
17440-66-6 IZ.tnc • 49.80 IP •
:f-::CfAnide_: 10.00 u: :AS
I •I'"' : t •-I
Color Before: ~OLO ·-E~S . Clarit~ Before: CLEAR Texture:
Color After: COLORLESS Clarity After: CLEAR Artifacts:
Comments:
FORM I -IN
3/90
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U.S. EPA -CLP
1
• ·oceoe
EPA SAMPLE NO.
INORGANIC ANALYSIS DATA SHEET :---------------:
Lab Name: KEYSTONE-MONROEVILLE
Lab Code: KEYF'A Case No.:
Matrix (soil/water): SOIL
Level (low/med): LOW
'.I. Solids: 91.6
Con trac: t:
SAS No.:
X1068
SDG No.: X4602
Lab Sample ID: 6.22-010
Date Rec:eived: 06/07/90
Conc:entration Units (ug/L or mg/kg dry weight): MG/KG
:cAS No.
' ' ' ' Analyte :Concentration :c; Q
' '
M
-------------' ' ---
:7429-90-5
:7440-36-0
:7440-38-2
:7440-39-3
17440-41-7
:7440-43-9
:7440-70-2
:7440-47-3
17440-48-4
:7440-50-8
:7439-89-6
:7439-92-1
:7439-95-4
:7439-96-5
Aluminum_ 5100.00 : :
Color Before:
7439-97-6
7439-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
Color After: BROWN
Comments:
Antimony_: 4.80
Arsenic: 1.10
Barium__ 148.00
Beryllium: 0.66
Cadmium_ 0.22
Calcium 1120.00
Chromium_: 16.10
Cobalt 33.00
Copper __ : 11.40
Iron __ _
'Lead __ _
Magnesium:
Manganese:
Mercury_:
Nic:kel
Potassium I
Selenium :
Silver __
Sodium __
29100.00
12.20
1440.00
504.00
0.11
7.20
1070.00
0.22
0.44
273.00
0.44
57.70
46.50
0.55
Clarity After:
3X DILTUION FOR PB BY MSA
FORM I -IN
lUI N
:e:
' ' ' ' :e:
U,
s:
B:
E
• s
E
u: WN
u:
s:
u: w
u: N
p
p
F
p
p
p
p
p
p
p
p
F
p
,P
CV
p
p
F
p
p
F
p
,P
:AS
Texture:
Artifac:ts:
I I
MEDIUM
3/90
I
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U.S. EPA -CLP
1
.. oo,os
EPA SAMPLE NO.
INORGANIC ANALYSIS DATA SHEET :---------------:
Lab Name: KEYSTONE-MONROEVILLE
Lab Code: KEYPA Case No.:
Matrix (soil/water): SOIL
Level (low/med): LOW
7. Solids: 85.0
Contract:
SAS No.:
X1002
SDG No. : X 4602
Lab Sample ID: 6.22-013
Date Received: 06/07/90
Concentration Units (ug/L or mg/kg dry weight): MG/KG
Color Before1
Color After:
Comments:
:CAS No. Analyte :concentration c: Q
17429-90-5
:7440-36-0
17440-38-2
:7440-39-3
17440-41-7
17440-43-9
:7440-70-2
17440-47-3
17440-48-4
17440-50-8
:7439-89-6
7439-92-1
7439-95-4
7439-96-5
7439-97-6
7439-02-0
7440-09-7
Aluminum
Antimony_:
Arsenic:
Barium __
1 Beryllium:
Cadmium_
Calcium_
Chromium :
Cobalt
Copper __ :
Iron __ _
Lead __ _
Magnesium:
Manganese I
Mercury_:
Nickel
.Potassium I
7782-49-2 :Selenium_:
7440-22-4 :Silver __
7440-23-5 !Sodium __
:7440-28-0 :Thallium :
:7440-62-2 !Vanadium :
I _·. !::~· I Cyanide_:
6.360. 00
5.20
1.70
110.00
0.42
0.24
335.00
14.20
12.60
7.60
29000.00
12.20
443.00
431.00
0.12
2.80
550.00
0.24
0.47
98.70
0.47
37.40
30.00
0.59 : 11~6-b l·z!:flc -:
: ' ·.,:i-tt·. .., .. ' : _______ _
~',_.;',.. . -..
BROWN Clarity Before:
BROWN Clarity After:
FORM I -IN
u: N
Bl
B:
u:
Bi E
*
B E
u
u
B
,U WN
:u,
:e:
:u: w
• • • • • • ' • :u: N
' • ' '
M
p
p
F
p
p
p
p
p
p
p
p
F
p
p
CV :p
IP
IF
:P
IP
:F
IP :p
:As
Texture:
Artifacts:
'
MEDIUM
3/90
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U.S. EPA -CLP
1
ocnos
EPA SAMPLE NO.
INORGANIC ANALYSIS DATA SHEET :---------------:
Lab Name: KEYSTONE-MONROEVILLE
Lab Code: KEYPA Case No.:
Matrix (soil/water): SOIL
Level (low/med): LOW
% Solids: 77.9
Contract:
SAS No.:
X1224
SDG No.: X4602
Lab Sample ID: 6.22-016
Date Received: 06/07/90
Concentration Units (ug/L or mg/kg dry weight): MG/KG
' ' '
CAS No. Analyte lConcentration c: Q M
7429-90-5 :Aluminum_ 16200.00 :P
7440-36-0 :Antimony_: 5.60 u N :P
7440-38-2 /Arsenic .2.30 B :F
7440-39-3 \Barium --56.60 :P i 7440-41-7 lBerylliuml 0.49 B :P
7440-43-9 !Cadmium_ 0,26 u :P I '7441)-70-2 :calcium_ 173.00 Bi E IP
7440-47-3 lChr-omium_: 14.10 ' ' :P ' '
7440-48-4 :cobalt __ 4.00 :e· :P
7440-50-8 :copper __ : 5.80 :e :P
7439-89-6 'Iron 33500.00 • :P
7439-92-1 Lead 14.00 :F
7439-95-4 Magnesium: 818.00 B E :p
7439-96-5 Manganese: 72.50 :P
7439-97-6 Mercury_: 0.13 u :cv
7439-02-0 Nickel 3.10 u lP
7440-09-7 Potassium I 530.00 B IP
l7782-49-2 Selenium ' 0.26 u WN IF -' 17440-22-4 Silver 0,51 u p
17440-23-5 Sodium 128.00 B p
17440-28-0 Thal Iium ' 0.Sl u w F -' 17440-b2-2 ,V.anadium ' 44.30 p ' -· ., -~-. _,._ : 7 440-66;,.6,-,I Z f;'nc 25.10 p , tt"'· ~:-•,:nide_: 1.B0 N AS
I • ,.5 . I, ~ I
Color Before: BRoJt;''--, ~ ·:.~/Clarity Befor-e: Texture: MEDIUM
. . ~ .
Color-After-: BROWN Clar-ity After-: Ar-ti facts:
Comments:
FORM I -IN
3/90
I
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U.S. EPA -CLP
1
► OC009
EPA SAMPLE NO.
INORGANIC ANALYSIS DATA SHEET :---------------:
Lab Name: KEYSTONE-MONROEVILLE
Lab Code: KEYPA Case No.:
Matrix (soil/water): SOIL
Level (low/med): LOW
1/. Solids: 84.3
Contract:
SAS No.:
X1S02
SDG No.: X4602
Lab Sample ID: 6,22-009
Date Received: 06/07/90
Concentration Units (ug/L or mg/kg dry weight): MG/KG
lCAS No. Analyte :Concentration c: G M
17429-90-5 :Aluminum 11100.00 :p
:7440-36-0 : Antimony_: 5.20 u: N IP
:7440-38-2 Arsenic 0.97 e: IF
:7440-39-3 Barium --43.70 B' :p
'7440-41-7 Beryllium: 0.37 B IP i
7440-43-9 Cadmium -0.24 ,U IP i 7440-70-2 Calcium 275.00 :s E IP
7440-47-3 Chr-omit1m ' 7.60 IP ' -7440-48-4 Cobalt 2.40 :s :p
7440-50-8 Copper_·_: 5.40 :s 'P
7439-89-6 Iron 11900.00 * p
7439-92-1 Lead 11.50 F
7439-95-4 Magnesium: 678.00 B E p
:7439-96-5 Manganese: 59.60 p
'7439-97-6 Mercury_: 0.12 u CV
7439-02-0 Nickel 2.80 u p
7440-09-7 Potassium: 563.00 B 'P
7782-49-2 Selenium ' 0.24 u N F ' 7440-22-4 Silver 0.47 u p --7440-23-5 Sodium --128.00 B p
7440-28-0 Thallium ' 0.47 U, w F ' 7440-62-2 ,Vanadium ' 24.80 p -' 744 --66-6. tz.Cnc 20.70 p
· JCyanide_: 0.59 u: N AS
I
Color Before: Clarity Before: Texture: MEDIUM
Color After: BROWN Clarity After: Artifacts:
Comments:
FORM I -IN
3/90
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U.S. EPA -CLP
1
•·00010
EPA SAMPLE NO.
INORGANIC ANALYSIS DATA SHEET :---------------:
Lab Name: KEYSTONE-MONROEVILLE
Lab Code: fc:.EYF'A Case No.:
Matrix (soil/water): SOIL
Level (low/med): LOW
% Solids: 81.4
Contract:
SAS No.:
X46(>2
SDG No.: X4602
Lab Sample ID: 6.22-017
Date Received: 06/06/90
Concentration Units (ug/L or mg/kg dry weight): MG/KG
' ' ' ' :CAS No. Analyte :concentr-ation :c: Q M
' ' ' '
:7429-90-5 :Aluminum 7730.00 ' ' p ' '
\7440-36-0 :Antimony_: 5.40 :u: N p
:7440-38-2 :Arsenic 3.10 F
:7440-39-3 :Barium --45. 70 :a: p I :7440-41-7 /Beryllium: 0.41 /B' p
:7440-43-9 :Cadmium 0.25 :u p
:7440-70-2 :Calcium 149.00 :s E p
:7440-47-3 :Chromium ' 17 .10 p ' :7440-48-4 :Cobalt 4.90 :s p
:7440-50-8 :copper __ : 4. 90 :s p
:7439-89-6 : Iron 27700.00 ' * p
:7439-92-1 :Lead 15.00 s F
:7439-95-4 :Magnesium: 317.00 B: E p
:7439-96-5 :Manganese: 176.00 p
:7439-97-6 'Mercury_: 0.12 U' CV
l7439-02-0 Nickel 3.90 B p
:7440-09-7 Potassium: 231.00 B p
:7782-49-2 Selenium ' 0.25 u WN F ' :7440-22-4 Silver 0.49 ,U p
:7440-23-5 Sodium --111.00 :s p
:7440-28-0 Thallium ' 0.49 :u w F •
:7440-62-2 V.•nadium_: 43.20 • p • •
1744t-66.,.b 1,rti\c: 20.10 • • p ' •
I ,,. . .• lCy~nide_: 0.61 :u: N AS
15·-I . -~ I • • . . ' • s~ BRO .. ,., _:;,.
Color Before: ~ Clarity Before: Texture: MEDIUM
Color After: BROWN Clarity After: Artifacts:
Comments:
3X DILUITON FOR PB BY MSA
FORM I -IN 3/90
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U.S. EPA -CLP
1
t OOOJJ
EPA SAMPLE NO.
INORGANIC ANALYSIS DATA SHEET :---------------:
X4904
Lab Name: f:.EYSTONE-MONROEVILLE Contract:
Lab Code: KEYF'A Case No.: SAS No.: SDG No.: X4602
Lab Sample ID: 6.22-018
Date Received: 06/06/90
Matrix (soil/water): SOIL
Level ( low/ med ) : LOW
'.I. Solids: 83.2
Concentration Units (ug/L or mg/kg dry weight): MG/KG
iCAS No. Analyte :concentration c: Q M
17429-90-5 :Aluminum 12100.00 p
'7440-36-0 :Antimony_: 5.30 u N p
7440-38-2 :Arsenic 1.40 B F
7440-39-3 :Barium 62.80 p
7440-41-7 lBeryllium: 0.35 B p
' 7440-43-9 :Cadmium -0.24 u p
7440-70-2 :Calcium 322.00 B E p
7440-47-3 :Chr-omium • 10.7(1 p •
7440-48-4 :Cobalt 2.80 s: p
7440-50-8 :Copper __ : 5.50 B' p
7439-89-6 I ran 18300.00 p
7439-92-1 Lead 10.90 F
7439-95-4 Magnesium: 596.00 s: E p
7439-96-5 Manganese: 111.00 p
7439-97-6 Mercury_: 0.12 u: CV
7439-02-0 Nickel 2.90 u: p
7440-09-7 Potassium: 374.00 19; p
7782-49-2 Selenium • 0.24 u: WN ,F •
7440-22-4 Silver __ 0.48 u: IP
7440-23-5 Sodium --111.00 s: IP
:7440-28-0 Thallium • 0.48 u: w :F -' 17440-62-2 I Vanadium • 34.20 IP -•
-66-6, lZUic 18.30 :P
,. I Cyanide_: 0.60 .u: N :AS
' l. : • • • •
Color Before: Clarity Before: Texture: MEDIUM
Color After: BROWN Clarity After: Artifacts:
Comments:
FORM I -IN 3/90
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U.S. EPA -CLP
1
• 00012
EPA SAMPLE NO.
INORGANIC ANALYSIS DATA SHEET :---------------,
Lab Name: KEYSTONE-MONROEVILLE
Lab Code: f::EYPA Case No.:
Matrix (soil/water): SOIL
Level (low/med): LOW
'Y. Solids: 89.0
Contract:
SAS No.:
X5048
SDG No.: X4602
Lab Sample ID: 6.22-019
Date Received: 06/06/90
Concentration Units (ug/L or mg/kg dry weight): MG/KG
' ' ' ' ICAS No. Analyte :Concentration lCI Q M
:7429-90-5 !Aluminum 15300.00 • ' p ' :7440-36-(1 Antimony_: 4.90 u: N p
:7440-38-2 Arsenic 2.30 F
:7440-39-3 Barium 199.00 'P I :7440-41-7 Beryllium: 3.50 p
7440-43-9 Cadmium 0.22 u: p
7440-70-2 Calcium 3510.00 E p i 7440-47-3 Chromium ' 15.40 p ' -7440-48-4 :cobalt --22.80 p
7440-50-8 :Copper __ : 16 .1(1 p
7439-89-6 : Iron 26200.00 * p
7439-92-1 ILead 14.80 F
7439-95-4 :Magnesium: 10000.00 E p
7439-96-5 :Manganese: 1060.00 p
7439-97-6 :Mercury_: 0.11 u CV
7439-02-0 lNickel 27.60 p
7440-09-7 :Potassium: 1230.00 ,P
7782-49-2 :SeleniL1m ' 0.22 u WN :F ' -7440-22-4 tSilver 0.45 u :P
7440-23-5 :sodium 798.00 B lP --7440-28-0 :Thallium ' 0.45 u. w :F -' 17440-62-2 !_Vanadium_: 42.70 IP
174'\0-66-6 tMnc 84 .10 :p
' • . I Cyanide_: 0.56 u: N lAS ' ' . ,.
I ,. . -I ' ' ' ,,_ . • •
Color Before: BROWf°' Clarity Before: Texture: MEDIUM
Color After: BROWN Clarity After: Artifacts:
Comments:
2X DILUTION FOR PB
FORM I -IN
3/90
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U.S. EPA -CLP
1
• OOCJ3
EPA SAMPLE NO.
INORGANIC ANALYSIS DATA SHEET :---------------:
Lab Name: KEYSTONE-MONROEVILLE
Lab Code: ,:EYPA Case No.:
Matrix (soil/water): SOIL
Level (low/med): LOW
'1/. Solids: 79.8
Contract:
SAS No. :
X7LF24
SDG No. : X4602
Lab Sample ID: 6.22-012
Date Received: 06/06/90
Concentration Units (ug/L or mg/kg dry weight): MG/KG
:CAS No. Analyte :concentration :c: Q M
:7429-90-5 Aluminum 15000.00 /P
:7440-36-0 Antimony....:.: 5.50 :u: N :P
7440-38-2 Arsenic 1.90 :s: F
7440-39-3 BariLtm 73. 50 p
7440-41-7 Beryllium: 0.52 :e: p t 7440-43-9 Cadmium -0.25 :u: p
7440-70-2 Calcium -889.00 'B: E p
7440-47-3 Chromium ' 12.90 p -' 7440~48-4 Cobalt 3.00 B: p
7440-5(1-8 Copper __ : 7.20 p
7439-89-6 . Iron 28500.00 * p
7439-92-1 Lead 13.90 F
7439-95-4 Magnesium I 909.00 s: E p
17~39-96-5 Manganese: 191. 00 p
17439-97-6 Mercury_: 0.13 u CV
:7439-02-0 Nickel 4.10 B p
'7440-09-7 Potassium: 544.00 B p
7782-49-2 Selenium ' 0.25 u WN F ' -7440-22-4 :Silver o.so u p
7440-23-5 :Sodium __ 505.00 B p
7440-28-0 :Thallium ' 0.50 U, w F ' -
7440-62-2 .• t'tfnadium_: 39.90 p
7 4 ·66-6 C t"1uic · : 22.90 p
. : ··::":~-"a~ide_: 0.63 u: N AS
. -~-tJ, -~-:-:. :
Color Beforet -~ ~~: ·. · l:larity Before: Texture: MEDIUM
Color After: BROWN Clarity After: Artifacts:
Comments:
FORM I -IN 3/9(1
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U.S. EF'A -CLP
3
BLANKS
Lab Name: kEYSTONE-MONROEVILLE Contract:
Lab Code: KEYPA -Case No.: SAS No,:
Preparation Blank Matrix (soil/water): WATER
I Preparation Blank Concentration Units (ug/L or mg/kg): ug/L
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:Analyte
:Aluminum
: Antimony_:
:A,,-senic
:Barium
: Beryl l iL1m:
'Cadmium
Calcium_
Chromic1m ' ' Cobalt
Copper __ :
Iron
Lead
Magnesium
Manganese
Mercury_
Nickel
•Potassium:
Selenium ' ' -Silver
Sodium
' Thallium ' -Vanadium ' ' ,Zinc
:cyanide_:
Initial
Calib.
Blank
(ug/L) c:
1.0 u
1.0 u
I I w: . 'i"·t .· I . ,, ,.. ,
Continuing Calibration
Blank (ug/L)
1 C ~ C 3 c: "-
c%f5w ' ' ' 2--0 :u:
. :u: 1.0 u: 1.0 :u
~ 5=i 3.0 u:
3.0 u:
-1.0 1.0 u -1.0 B:
74,4
-4.5
0.2 u 0.2 u:
12.0 u
366.0 u ' ' '
1.0 :u 1.0 u:
2.0 :u:
.. 54.0 u:
~ ... -.·· -~ ~~:'.'\. ''.2.0 u: 2.0 u 2.0 :u
>-: ·. ,;1.0 u:
~.·, · ;5.0 u:
..:-.
FORM III -IN
1• 00021
SDG No.: X4602
'' ' ' '' ' ' F'repa-'' ''
ration '' ' ' Blank C '' M! '' ' ' ' ' : :p
' : :p ► ~ 1 lF i::P
1.000 I: P
' : :p ' : lP
: :p
: :P
: :P
: /P
1.000: U: : F
: :P
l JP
: :cv:
: :p
: :P
: :F
: /P
: :P
2,000 u: :F
: :P
: :P
10.000 U: :As
' ' ''
3/90
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U.S. EPA -CLP
1
~ OC,007
EPA SAMPLE NO.
INORGANIC ANALYSIS DATA SHEET :---------------:
Lab Name: KEYSTONE-MONROEVILLE
Lab Code: KEYPA Case No.:
Matrix (soil/water): SOIL
Level (low/med): LOW
% Solids: 90.0
Contract:
SAS No.:
X1068D
SDG No.: X4602
Lab Sample ID: 6.22-011
Date Received: 06/07/90
Concentration Units (ug/L or mg/kg dry weight): MG/KG
' ' ' '
:CAS No. Analyte : Cone en tra.tion :c: Q M
' ' ' ' :7429-90-5 :Aluminum 5870.00 ' ' IP ' '
:7440-36-0 Antimony_: 4.90 :u: N IP
:7440-38-2 Arsenic 0.80 B: F
:7440-39-3 Barium --251.00 p
:7440-41-7 Beryllium: 1.10 a: p ~
:7440-43-9 Cadmium (1.22 u: p ' :7440-70-2 Calcium -1230.00 E p 5
:7440-47-3 Chromium ' 16.60 p -' :7440-48-4 ,Cobalt 14.20 p
:7440-50-8 Copper __ : 13 .10 p
:7439-89-6 Iron 30600,00 * p
:7439-92-1 Lead 11,80 F
:7439-95-4 Magnesium: 1480.00 E p
:7439-96-5 Manganese: 313.00 p
:7439-97-6 Mercury_: 0.11 u CV
:7439-02-0 Nickel 6.00 B p
17440-09-7 Potassium: 1160.00 p
:7782-49-2 Selenium_:: 0.22 u WN F
'7440-22-4 Silver --0.44 u p
7440-23-5 Sodium __ 318.00 B p
7440-28-0 Thallium ' 0.44 :u, w F -' 7440-62-2 1 Van_adium_: 50.40 ' • p ' '
7440-66~6 IZii'tf: 47.60 ' ' p ' ' ,, . ~.,, !Cyanide_: 0.56 :u: N AS ,~=r,_:-I ' ' ' '
.J{.;.
Color Before: BROWN Clarity Before: Texture: MEDIUM
Color After: BROWN Clarity After: Arti tac ts:
Comments:
FIELD DUPLICATE
FORM I -IN
3/90
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U.S. EPA -CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSIS DATA SHEET :---------------!
Lab Name: KEYSTONE-MONROEVILLE
Lab Code: ,::EYPA Case No.:
Matrix (soil/water): WATER
Level (low/med): LOW
% Solids: o.o
Contract:
SAS No.:
XBLV65
SDG No.: X4602
Lab Sample IO: 6.22-003
Date Received: 06/07/90
Concentration Units (ug/L or mg/kg dry weight): ug/L
Color Before:
Color After:
Comments:
:CAS No. Analyte :concentration c: Q
17429-90-5
:7440-36-0
:7440-38-2
:7440-39-3
:7440-41-7
:7440-43-9
17440-70-2
:7440-'47-3
17440-48-4
:Aluminum
1 Antimony_:
Arsenic
Bari1.tm
Beryllium/
Cadmium
Calcium_
Chromium:
Cobalt
17440-50-8 Copper __ :
17439-89-6 Iron __ _
17439-92-1 'Lead __ _
17439-95-4 Magnesium:
:7439-96-5 Manganese/
: 7439-97-6 Mercur-y_:
17439-02-0 Nickel
17440-09-7 Potassium:
17782-49-2 Selenium_:
17440-22-4 Silver
17440-23-5 Sodium __
:7440-28-0 Thallium:
17440-62-2 !Vanadium:
..,.1,6-6 /-ttu,c __ _
,.,-,--...,..•·. l~anide_:
.. : ,.-II': :
,:;._ ... ~ •. :J·
10.00
--------
i~Clarity Before: CLEAR
Clarity After:
FORM I -IN
u:
M
:NR
:NR
INR
:NR
! lNR
:NR
:NR
lNR
:NR
:NR
lNR
:NR
lNR
:NR
:NR
:NR
lNR
lNR
NR
NR
NR
NR
NR
AS
Textc,re:
Artifacts:
3/90
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U.S. EPA -CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSIS DATA SHEET :---------------:
Lab Name: KEYSTONE-MONROEVILLE
Lab Code: KEYPA Case No.:
Matrix (soil/water): WATER
Level (low/med): LOW
% Solids: o.o
Contract:
SAS No.: SDG No. : X4602
Lab Sample ID: 6,22-004
Date Received: 06/07/90
Concentration Units (ug/L or mg/kg dry weight): ug/L
CAS No. Analyte :Concentration c: Q M
7429-90-5 :Aluminum NR
7440-36-0 : Antimony_: NR
7440-38-2 :Arsenic NR
7440-39-3 :Barium --NR I 7440-41-7 :Beryllium: NR '
7440-43-9 :Cadmium -NR
7440-70-2 :Calcium NR
7440-47-3 :chromium ' NR ' 7440-48-4 :cobalt NR
7440-50-8 :copper __ : NR
7439-89-6 : Iron NR
7439-92-1 lLead NR
7439-95-4 :Magnesium: NR
7439-96-5 :Manganese: NR
7439-97-6 :Mercury_: NR
7439-02-0 :Nickel NR
7440-09-7 :Potassium: NR
7782-49-2 :selenium ' NR ' 7440-22-4 :Silver NR
7440-23-5 :sodium NR --7440-28-0 :Thallium ' NR ' 7440-62-2. I Vanadium ' NR -' 7·1r-• ..... , NR
. :,_'.· ICyilnide_: 10.00 :u AS
.,. . -I •· I
• ' I I
Color Before: COLO ~~Sa' -' ' ·cl a..-i ty Before: CLEAR Texture:
Color After: Cla..-ity Af te..-: Artifacts:
Comments:
FORM I -IN 3/90
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AWD Technologies, Inc.
APPENDIX B
SUPPORT DOCUMENTATION
U.S. EPA -CLP ~ 00025
BLANKS
Lab Name: KEYSTONE-MONROEVILLE Contract:
I
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I Lab Code: KEYPA Case No.: SAS No. : SDG No.: X4602
Preparation Blank Matrix (soil/water): SOIL
I Preparation Blank Concentration Units (ug/L or mg/kg): MG/KG
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:Analyte
: AluminL1m
:Antimony_:
:Arsenic
:Barium
:Beryllium:
:Cadmium
Calcium -Chromic1m ' ' Cobalt
Copper __ :
Iron
Lead
Magnesium:
Manganese:
Mercur-y_:
:Nickel
:Potassium:
lSelenium ' '
lSilver --:Sodium --:Thallium ' ' -:vanadium ' ' :Zinc
:Cyanide_:
Initial
Calib.
Blank
(ug/L) c:
11.0 :u:
22.0 u:
1.0 u:
1.0 u:
1.0 u:
1.0 u:
14.0 u: .
3.0 ,u:
3.0 :u:
1.0 :u:
4.0 :u:
1.0 :u:
20.0 :u
-4.3 :B
0.2 :u
12.0 :u
366.0 :u
1.0 :u
2.0 :u
54.0 :u
2.0 IU 1:1;.•~ :l; .'IU1,
10·~ IUI
'':· I
'' ' ' ' ' ''
Continuing Calibration ' ' '' Blank (ug/L) ' ' ''
1 C 2 C 3 C'' '' '' --;): 6.4_.~ ~: ''
G,6.6 ~ :a) l
22.0 :u: 22.0 :u: 22.0 :u: f
1.0 I u: 1.0 :u: ~ (1.o ?i: D.O IE! '
'
1.0 :u: 1.0 u: ' ' ' '
1.0 :u: 1 ~ ;~ ~ ('IB...
' 3.0 :u: f ' 3.0 :u: u: 3.6 :s:
~'1J ;~ ~ JE ~~ a= c" ... ~.I~
1.0 :u: 1. :u: : I ~ -4.3 :e
0.2 :u: 0.2 :u
12.0 :u: 12.0 :u: 12.0 :u
366.0 :u: 366.0 :u: 366.0 :u '
1.0 :u· 1 'UI LO :u
2.0 :u 3.1 :e 2.0 :u
54.0 :u 67.8 :B 54.0 IUI
:, 2,0 :u 2.0 :u: 2.
.· 1.0 :u 1.0 :u: • 1
,.: ,. 0 :u 5.0 :u: 5.
10.0 :u 10.0 :u: 10.0 :u:
FORM I I I -IN
Prepa-
ration
Blank C t1
4.368:B: p
4.400~U: p
o. 2001): F
o.200~: P
0.200 : P
-0.376, I IP
3 .152 l B: : P
0.600: u: : P
0.600: U:: P
0.200 :u: :P
~6621'g) :P
0.200 :u:: F
4.ooo:u: :P
-1.674:B: :P
0 . 100 : U : : C'J :
2.400:u: :P : .
73.200:U: :P
-0 • 360 : B : : F
0.200:U: :P
1.000:U: :P
0. 500: U:: AS:
' ' ' '
3/90
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U.S. EPA -CLP
BLANKS
Lab Name: KEYSTONE-MONROEVILLE Con trac: t:
Lab Code: kEYPA Case No,: SAS No,:
Preparation Blank Matrix (soil/water): WATER
00027
SDG No. : X 46(12
I Preparation Blank Conc:entration Units (ug/L or mg/kg): ug/L
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:Analyte
:Aluminum
/Antimony_:
lArsen1c
:aar-ium
: Beryl 1 ium:
:Cadmium
: CalciLtm -:chr-omium ' ' :cobalt
/Copper __ :
:tr-on
:Lead
lMagnesium:
:Manganese:
:Mercury_:
:Nickel
: Potassi1..tm:
:Selenium ' ' lSilver
:sodium
!Thallium ' ' fVanadium ' ' /Zinc
:Cyanide_:
Initial
Calib, Continuing Calibration
Blank Blank (ug/LJ
(ug/L) C 1 C 2 C
11.0 :u: 11.0 :u: 11.0 :u:
22.0 :u 22.0 'U: 22.() :u:
1.0 :u 1.0 u: 1.(1 :u:
1.0 :u 1.0 u: 1.0 :u:
1.0 :u 1.0 u 1.0 :u:
14.0 :u 14.0 u 14.0 :u:
3.(1 :u 3. (I u 3.0 :u:
3. (l :u. 3.0 u :u:
1.0 :u: 1.0 u :u:
4.0 :u: 4.(1 u :e·
' ' 1.0 U' ,B: ' 20.0 :u 20.0 u 20.0 :u:
1.0 :u 1.0 u 1.0 :u'
(l • 2 :u 0.2 u C>.2 :u
12.0 :u 12.0 u 12.0 :u
366.0 :u 366.0 u 366.0 :u
1.0 :e 1.0 u 1.0 :u
2.(1 :u 2.0 u 2.0 :u
54.0 IU, . 54.0 U, 54.0 :u
. -: I I -\-1-..i~\'"\. 1B1 · ~}~i\o u: 1.0 :u
5 · · l I · ··. 5. O u: 5.0 :u
it'1··1 · ... . I I ..
' '
FORM Ill -IN
'' ''
Prepa-
ration
3 c: Blank C P1:
p
2 .000 LU: p
1.1 B : 1 . 000 rl.J: F 1.000t; p
,P
IP
: :F
:-o . 000 : U : : P
1.000: U:: P
0. 200 : U : : CY :
12.000:U: JP
366. 000 : U : : P
1. 0001 U: :F
2.000 :u:: F'
~:P
' ' ' ' ' 1
'' ''
3/90
. 1
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U.S. EPA -CLP
5A
SPIKE SAMPLE RECOVERY
Lab Name: KEYSTONE-MONROEVILLE Contract:
Lab Code: KEYF'A
Matri::: SOIL
'l. Solids for Sample:
Case No.: SAS No.:
85.0
• 00932
EF'A SAMPLE NO.
:---------------:
X 1CH)2S
SDG No.: X4602
Level (low/med}: LOW
Concentration Units (ug/L or mg/kg dry weight}: MG/KG
: Cori tr-al:
Limit :Spiked Sample Spike
Analyte 'l.R Result (SSR)
Sample
C: Resu l t (SR} C Added (SA} 'l.R : Q :M
Aluminum_
Antimony_:75-125
Arsenic :75-125
Barium :75-125
Beryllium:75-125
:Cadmium_:75-125
:Calcium
:Chromium :75-125
:Cobalt :75-125
:Copper __ :75-125
: Ir-on __ _
lLead ___ l75-125
:Magnesium:
:Manganese:75-125
:Mercury_:75-125
:Nickel :75-125
:Potassium:
:Selenium :75-125
:Silver :75-125
:Sodium __
32.4965:
9.0353:
582.8847
11.3718
11.4094
53.1435
131. 2753
65.2212
15.8588
559.7200
o. 5353
114.6494:
0.2353:u:
10.5906:
5.1765:U,
1.7176:B:
109.9035: :
o.4212:s:
o.23s3•u·
14.2306
12.5835
7.5906
12.2118
431.3694
0.1176 U
2.82351U
0.2353/U
0.4706:U
117. 65
9.41
470.59
11.76
11.76
' ' ____ ,'
: :NR:
.:N:P :
il :F :
100.5t :P :
93 .1 tl IP :
97 .0 I :P :
:NRl
47.06: 82.7
117 .65: 100.9
58. 821 98. 0 :p :
4.71:
117 .65:
0.59'
117. 65
2.35
11. 76
77. 4 : F :
:NR:
1(>9 .1 : P :
90. 7 : CV:
97. 4 : P :
~ l : NR :
~:N!F ·:
90 .1 : P :
:Thallium :75-125 , ;12.6588: 0.47061U 11.76
!NR:
107.6 :F :
87 .9 : P : :vanadium_:75-1251_. · 140.8047: 37.42121 , 117.65
:zinc ___ :75-12s-136.54121 29.96001 : 117.65, ~°'\: :P :
:cyanide_l75-125. . O.5002:u: o.s002:u: s.sa: ~:N:As:
I I I I I I I I ------------' , _______ , , ______ -----' ' '
Comments:
FORM V (PART 1) -IN
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U.S. EPA -CLP
9
ICP SERIAL DILUTIONS
Lab Name: KEYSTONE-MONROEVILLE Contract:
or.o:a
EPA SAMPLE NO. :---------------:
X1002L
Lab Code: KEYPA Case No.: SAS No. : SDG No.: X4602
Matrix (soil/water): SOIL Level (low/med): LOW
Concentration Units: ug/L
'' ' ' Serial ' ' % '' ' ' '' '' lni tial Sample ' ' Dilution : :Differ-: ' ' ' '
:Analyte '' Result ( I ) C'' Result ( s) C'' ence O:M '' ' ' . '
' ' ' ' ' ' '' ' ' ' '
:Alt..tminum '' 27015.37 ' ' 28651.15 '' 6.1 :p '' ' ' ''
:Antimony_ ' ' ' ' 22.01) U'' ' ' 110.00 U': :p
:Arsenic '' ' ' :NR '' ' '
: Bar iL1m ' ' 467.09 ' : 473.20 B 1.3 :P ' ' ' :Beryllium '' 1.79 B 5.00 u 100.0 'P '' :Cadmium ' ' 1.00 u 5.00 u p ' ' :Calcium '' 1421.72 ,B 1639.20 B 15.3 : ,E p ;,,
'' ,i
:Chromium : : 60.48 70.95 17.3 ' ' p t ' ' :Cobalt '' 53.48 69.60 B 30.1 ' ' p ,. '. '' ' :Copper __ ' ' 32.26 45.40 ,8,: 40.7 ' ' p '' . '
: I ran '' 123182.90 133267.75 ' ' 8.2 ' ' p '' . ' . '
:Lead '' . ' '' NR '' ' ' '' :Magnesium 1881.97 B 2106.90 B', 12.0 lElP ' '
:Manganese 1833.32 1968.60 '' 7.4 :p ''
:Mercur-y_ ' ' '' !NR ' ' '' :Nickel 12.00 U'' ' ' 60.00 U'' '' :p
:Potassium 2339.33 B'' 3239.75 e: I 38.5 :P ' ' '
:selenium ' ' • ' 'NR ' ' •
:Silver 2.00 U'' ' ' 10.00 u: p
:sodium --419.31 :e:: 699.90 e: 66.9 p
:Thallium ' . NR ''
: VanadiLlffl 159.04 ' ' 168.20 e: 5.8 p '' :Zinc 127.33 ' ' 149.50 17.4 p ' ' ' ' ' '
·• -·-•• !'" :., ...
-. .,;;.. : ·-··. ~:,_:-'"" I(· ... .,., · ......
_ .. _.:.
FORM IX -IN
3/90
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Lab Name: KEYSTONE-MONROEVILLE
Lab Code: KEYPA Case No.
Instrument ID Number: Z3030-l
U.S. EPA CLP
14
ANALYSIS RUN LOG
Contract:
SAS No.
Method: F
I • 0<'068
SDG No. X4602
Start Date: 06/20/90 End date: 06/20/90
EPA
Sample
No.
D/F :Time: 'l. R
Analytes
:A:s:A:B:B:c:c:c:c:c:F:P:M
:L:B:s:A:EJD:A:R:□:u:E!B:G
M:H:N:K:s:A:N:r:v:z:c:
:--------:--------:----:-------:-:-:-:-:-:-:-:-:-:-:-:--:-:-:-:-'-:-:-:-:-:-:
:so
:s10
:540
:S60
!CV
!CB
:CRA
:ccv1
:cce1
:PBS
:PBSA
:LCSS
:LCSS
:LCSSA
:ccv2
lCCB2
:x93
'X93A
X1S02
X1S02A
X1068
X1068A
X1068D
X1068DA
X7LF24
IX7LF24A
:CCV3
:CCB3
:x1002
:X1002A
:X1002D
:X1002DA
1 . (l(l : 1740 :
1.00:
1.(H) l
1 . ()(l :
1.00:
1 . (1(1 :
1 . (l(I :
1.00:
1.(u):
1.00:
1.00'
1.00
10.00
10.00
1.00
1. 00
1.00
1.00
1.00
1.00:
1.00:
1.00.1. ·
1.001 r
1.90:(.'
1.~ 1.00
1.00:
1.00:
1.00:
1.00:
1.00:
1.00:
107.5:
88.5:
@i
~ ' (§.~
~ ~-~
'
' ~ .
:
' '
:
: X:
: X:
: X:
; X
:x
:x
X
x:
X
X
X
X x:
x:
:x
:x
: X
X
X
X
X x:
:x
; X
: X
: X
X
--------------------------------------------------------------------------------
FORM XIV IN 3/90
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D
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L2b Name: fEYSTDNE-MONROEVILLE
U.S. EF'A CLF'
14
ANALYSIS RUN LOG
Contract:
0(1069
Lab Code: Case No.: SAS No. SDG No. X460:2
Instrument ID Number: 23030-1 Method: F
EF'A
Sample
No.
D/F :Time: 1/. R
End date: 06/20/90
Analytes
:A:S:A:B:B:c:c:c:c:c:F:P:M:M:H:N:K
:L:B:s:A:E:D:A:R:□:u:E:B:G:N:G:I:
--------:--------:----:-------:-:-:-:-:-:-:-:-:-·-:-:-:-·-:-:-:-
1002S
Xl224
X1224A
X4602
X4602A
lCCV4
iCCB4
X4904
X4904A
X5048
X5048A
:F'BW
iF'BWA
:PBWA
:LCSW
:LCSW
lLCSWA
:ccvs
CCB5
C90A
C90AA
C91A
C91AA
CCV6
CCB6
1.00:
1 . 00:
1.00:
1.00:
1.00:
1.00:
1. (H) l
1.00:
1.00:
1.00:
1.00:
1.00:
1. (H)
1.00
l. 00
2.(10
2.00
1.00
1.00
1.00:
1.00:
1.00:
1.00J
1 • O()l' '.~~· 1 • Oo__l:1700
Q
~
103.5:
104.0:
101.6:
102.0
97.0
s:A:N:r:v:::c:
:r .. :N:
-:-:-:-:-:-:
l X:
: X:
:.x:
r):
X
X
X
X
X
X
:x
:x
X
X
: X:
X:
X
X
X
X
--------------------------------------------------------------------------------
FORM XIV IN 3/90