NCD003200383_19900907_Koppers Co. Inc._FRBCERCLA SAP QAPP_Organic and Physical-Chemical Data Validation-OCR

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AWD
TECHNOLOGIES
PGH-90-DAL-309
DATE
TO
FROM
SUBJECT
overview
September 7, 1990
Mr. Roberts. Markwell
Program Manager -Environmental Services
Beazer Materials and Services, Inc.
436 Seventh Avenue
Pittsburgh, Pennsylvania 15219
David A. Lang
AWD Technologies, Inc.
Organic and Physical/Chemical Data Validation
Keystone Environmental Job Nos. M90-06.37
and M90-06.78
The set (No. M90-06.37) of samples for Beazer (sampled 6/7/90,
6/12/90, and 6/13/90) contained 17 samples. These included
11 water samples, three trip blanks, and three field blanks. The
set (No. M90-06.78) sampled 6/14/90 contained six samples. These
included four water samples, one trip blank, and one field blank.
Samples for both sets were analyzed for total alkalinity, chloride,
carbonate alkalinity, bicarbonate alkalinity, sulfate, dissolved
calcium, dissolved potassium, dissolved magnesium, dissolved
sodium, isopropyl ether, and phenols. Isopropyl ether was analyzed
by EPA Method 8020 and phenols were analyzed by Method 8040.
Pentachlorophenol was analyzed by both Method 8040 and
Method GC515, and physical/chemical parameters were analyzed by
accepted EPA methods.
summary
All elements were successfully analyzed in all samples. Areas of
concern with respect to data usability are listed according to the
seriousness
Qualifiers
affected.
of the problem.___ Note that the Summary of Data
(Table 1) lists the specific samples which were
These include:
AWD Technolooies. Inc. Penn Center West Buildina Ill Suite 400 P!ttshurnh PP.nn<:vlv::ini::i 1ti?7R TPIPnhnnP .:f.1? 7JlA ?717 T"lornnior A1? 7RR 111&:.
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AWD Technologies, Inc.
PGH-90-DAL-309
Mr. Roberts. Markwell
Beazer Materials and Services, Inc.
September 7, 1990 -Page 2
Minor Issues
The surrogate
Therefore, the
qualified "J",
spike recovery for pentachlorophenol was high.
result for the associated sample, Well c-5A-WA, was
estimated.
The laboratory qualified from a peak for isopropyl ether that was
saturated. Therefore, the result for the associated sample,
Well C-14B-FL, was qualified "J", estimated.
Notes
Matrix interference prevented the
recoveries for pentachlorophenol for
Well C-14B-FL.
calculation of surrogate
samples Well C-14A-FL and
2-Methyl-4, 6-dini trophenol was detected in a laboratory blank.
This concentration was then subtracted out for other sample
results. The practice of subtracting out to adjust for blank
contamination is not consistent with EPA methodology.
Information Regarding Report Content
Table 1 is a summary of qualifiers added to the laboratory's
results during data validation.
Attachments:
1.
2.
3.
4 .
Glossary of data qualifiers.
Data Summary. This includes:
a. All positive results with qualifier codes, if applicable.
b. All unusable detection limits qualified with an ''R.11
c. All estimated detection limits qualified with "UJ."
Appendix A -Results as reported by the laboratory (no
corrections were made during data validation).
Appendix B -Support Documentation includes details to support
the statement of this report.
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AWD Technologies, Inc.
GLOSSARY OF DATA QUALIFIER CODES
(INORGANICS)
Codes Relating to Identification
(confidence concerning presence or absence of compounds)
u = Not Detected. The associated number indicates
approximate sample concentration necessary to be
detected, or not detected substantially above the level
reported in laboratory or field blanks.
(NO CODE)= Confirmed Identification.
R = Unreliable Result. Analyte may or may not be present in
the sample. Supporting data necessary to confirm result.
Codes Related to ouantitation
(can be used for positive results and sample quantitation limits)
J =
UJ =
Analyte present. Reported value may not be accurate or
precise.
Not detected.
imprecise.
Quantitation limit may be inaccurate or
Other Codes
Q = No analytical result.
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uA Tl SUMMARY INON CLP DATA FOR SAMPLES COLLECTED 6/14/90 BEAZER -RALEIGH
Keystone Environmental Job. I M90-06.78
I Sample No. ORGFREE C-15B-OSS C-25B-WA C-27B-Fl FB TB
1------------------------------------------------------------------------------------------------------------------------------
I COMPOUND · Units
------------------------------------------------------------------------------------------------------------------------------
Total Alkalinity as CaC03 mg/L NR 231 635 446 NR
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Chloride mg/L HR 22.8 18.0 114 NR Carbonate A I ka Ii n i ty as CaC03 mg/L NR 127 583 0. 000 NR Bicarbonate Alkalinity as CaC03 mg/L NR 104 52.0 446 NR Sulfate mg/L NR 7 .00 24.0 (1.00 NR loissolved Calcium ug/L NR 5850 108000 54500 NR 0 i sso I ved Potassium ug/ L NR 16600 144000 <5000 NR Dissolved Magnesium ug/L NR <5000 <5000 65200 NR tissolved Sodium ug/L NR 10700 101000 105000 NR
llsopropyl Ether ug/L NR <1.00 <1.00 21.9 <1.00
Phenol ug/L NR <0.500 2570 2.67 <0.500
< 1.00
-
-Chlorophenol ug/L NR <0.500 <0.500 <0.500 <0.500 -Nitrophenol ug/L NR <0.500 52.5 <0.500 <0.500 ,4-0mthylphenol ug/L NR <0.500 <0.500 <0.500 <0.500 2,4-Dichlorophenol ug/L NR <0.500 45.1 <0.500 <0.500 I-Chloro-3-nethylphenol ug/L NR <0.500 (0.500 <0.500 <0.500 ,4,6-Trichlorophenol ug/L NR <1.00 (1.00 <1.00 <1.00 2,4-Dinitrophenol ug/L NR <t.00 <t.00 <t.00 <1.00
1-!itrophenol ug/L NR <t.00 39. 7 <1.00 <1.00 .,1,,,!-fetrachlorophenol ug/L NR <1.00 <1.00 <1.00 <1.00 2-MethyH,6-dinitrophenol ug/L NR <1.00 57 .5 <1.00 <1.00 'entachlorophenol (8040) ug/L NR 1.60 155 4.23 <1.00 •=~~~~~:~~~~~=~~:_:~~:'.::: _________ '.~~~------'.~:~'.~-----------~:'.:: _________ ~:'.~~----------'.:'.: ________ '.~:~'.~-----------------
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'Ill SUMMARY IOi CLP om FOR SIMPLES COLLECTED 5/1/90-5/13/90
.EAZER -RALEIGH
•.eystone Environmtal Job. I !90-05.37
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Sa1ple No.Well C-5A-il Well C-51-WA Well C-14A-Fl Well C-118-FL
7otal Alkalinity as CaCOJ
l hloride
arbonate Alkalinity as CaCOJ
Bicarbonate Alkalinity as CaCOJ
l ulfate
issolved Calciu1
lissolved Potmiut
llliissolved Magnesiu1
lissolved Sodiu1
1sopropyl Ether
Pheno 1
--Ch loropheno 1
-Nitrophenol
, 1-0i1ethy lpheno 1
1, 1-0ich loropheno 1
-Ch 1 oro-3-iethy 1 pheno 1
, I, 5-lrich loropheno 1
1, 1-0 in i tropheno 1
1-Nitrophenol
, l, 5, 5-1 et rach loropheno 1
1-!ethyl-4,5-dinitrophenol
lentachlorophenol (8040)
_ entach loropheno 1 _ ( GC515))
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19/l
19/l
19/l
19/l
19/l
ug/L
ug/L
ug/l
ug/l
ug/l
u9/L
ug/l
ug/l
ug/l
ug/l
ug/L
ug/L
ug/L
u9/l
ug/L
ug/L
ug/L
ug/L
-----------------------
2IO 311 m 291
9, 93 38.1 63.5 52. I
0.000 0.000 0.000 0.000
210 318 m 291
I.ID 8, 50 2.40 2.00
moo 12800 63900 lBDOO
<5000 <5000 <5000 <5000
11500 35100 62200 29200 moo 48200 120000 19000
<I.DD (1.00 1140 810 J
<0.500 0. Ill (0.500 1.35
<0.500 (0, 500 <0.500 <0.500
<0.500 <0.500 (0, 500 <O. 500
(0. 500 (0, 500 <0.500 <0.500
<0.500 (0.500 <0.500 <0. 500
(0. 500 (0,500 <0.500 <D.500
<I.DD <1.00 <1.00 1.91
<1.00 <1.00 <1.00 <1.00
<I.DO <1.00 <1.00 <1.00
<1.00 <1.00 1.29 II.I
<I.DD <1.00 12 .1 4.30
<1.00 <1.00 889 499
0, 038 J <0. 010 mo 510
----------------
NR
NR
NR
NR
NR
NR
NR
NR
NR
(1.00
2.43
<0.500
<0.500
<0.500
(0.500
<0.500
<1.00
<1.00
(1.00
<I.DD
<1.00
<1.00
<0.010
161
30.1
0.000
151
3.10
35900
<5000
18100
23300
<1.00
0. 989
<0.500
<0. 500
<0.500
(0. 500
<0.500
<I.DD
<I.OD
(1.00
(1.00
(1.00
<1.00
0, Oil
Ii
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ii
IR
Ii
II
iR
IR
IR
<1.00
0,521
<0.500
<0.SOC
(0.500
<0.500
<0, 500
<1.00
< 1. 00
3,84
(1.00
(1.00
(1.00
0.02
18
6/1 /10
<1.00
IR
IR
IR
IR
IR
IR
IR
IR
IR
IR
IR
IR
I I Im SUMMARY ON CLP om fOR SAMPLES COLLECTED 5/7 /90-5/13/90 EIZER • RALEIGH !eystone Enviromntal Job. I !90-06.37 I Suple No. C-121-EA C-128-EA FB C-11A-OSS C-26B-IA c-31-IA fB TB TB 1 ______________________________________________________ 6/12/90____________________________ 6/13/90 _____ 6/12/90 ____ i/13/90 IONPOUND ______ Units -------------------------------------------------Total Alkalinity as CaC03 19/L 234 239 KR 231 164 18! NR lhloride 19/L 19.0 16.2 NR 21.8 11.4 33. 2 NR arbonate Alkalinity as CaC03 19/L 0.000 0.000 NR 0.000 0.000 0.000 NR Bicarbonate Alkalinity as CaC03 19/L 234 239 NR 231 164 18! NR -ulfate 19/L 11. 0 8.20 NR 11.0 <t.00 2.50 NR issolved C1lciu1 u9/l 38000 34200 NR 31400 moo 12400 NR issolved Pot1ssiu1 ug/l <1000 <1000 NR <1000 <5000 <1000 NR Dissolved Ma9nesiu1 ug/L 22400 18900 NR 18100 16200 18200 NR lissolved Sodiun ug/L 45300 55900 NR 11100 84!0 23900 NR lsopropyl Ether ug/L <t.00 (1.00 <1.00 <1.00 <1.00 NR <t.00 <t.00 <1.00 Phenol u9/L o.m 1. 06 0.139 0.101 <0.100 <0.500 <0.500 NR NR --Chlorophenol ug/L <0.500 <0.100 <0.500 <0.500 <0.500 <0.500 <0.500 NR NR -Kitropheno 1 ug/L <0. 500 <0.500 <0.500 <0.500 0.911 <0.500 <0. 500 KR NR ,4-Diiethylphenol ug/L <0.500 <0.500 <0.500 <0. 500 <0.500 <0.100 <0.100 NR NR 1,4-Dichlorophenol ug/L <0. 500 <0.500 <0.500 <0. 500 <0.500 <0. 500 <0.500 NR NR 1-Chloro-3-1ethylphenol ug/l <0.500 <0.500 <0.500 <0.100 <0.500 <0.100 <0.500 NR NR ,4,6-Trichlorophenol ug/L <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <t.00 NR NR 2,4-Dinitrophenol ug/L <t.00 (1.00 <1.00 <1.00 <1.00 <1.00 <1.00 NR NR 1·Nitropheno 1 ug/L 3. 46 3. 18 <1.00 I.IT 2 .21 10. 1 <1.00 NR NR ;3, 5, 6-1 et rach I oropheno 1 ug/L <1.00 <t.00 <1.00 (1.00 (1.00 <1.00 <1.00 NR NR 2-Nethyl-4,6-dinitrophenol ug/L <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 NR NR lentachlorophenol (8040) ug/L <1.00 <1.00 (1.00 <1.00 (1.00 <1.00 <1.00 NR NR entach loropheno 1 (GC515)) ug/L 0.032 0.012 <0.010 0.011 0. 018 0.018 <0.010 --------------------------------------------------I I I I I
-1 AWD Technologies, Inc.
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I APPENDIX A
RESULTS AS REPORTED BY THE LABORATORY
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5-JUL-19'10
s-ary oi Analytical Results
Keystone ID
Date Saapled
Custoeer ID
Paraete~
Date received: 8-JUi·l9'10
Units
Saaples
37-003
7-Jl.tH 9'10
WELL C-511-WA
37-004
7-Jlll-19'10
WELL C-6A-NA
Job nue: "90-06.37
37-00S 37-oOo 37-007
7-Jlll-1990 7-Jlll-19'10 7-Jlll-1990
WELL C-14A-FL WELL C-148-FL FB
------------------------------------------------------------------------------------------------------------------------------Tohl Allcilini ty as C.co:J llg/L 240 318 575 291 tfi
Chloride llg/L 9.93 38. 7 63.5 52.6 tfl
Carbonate Alkalinity as CaCO:l 1g/L 0.000 0.000 0.000 0.000 tfl
Bicarbonate Alkalinity as CaCO:l 1g/L 240 318 575 291 Ill
Sulhte 1g/L 4. 10 8.60 2.40 2.00 tfl
Dissolved Calcii.a ug/L 42700 72800 63900 38000 Ill
Dissolved Potassii.a ug/L (5000 (5000 (5000 (5000 tfl
Dissolved Nagnesii.a ug/L 17500 35400 62200 29200 Ill
Dissolved Sodii.a ug/L 44000 48200 120000 79000 Ill
6C515
Pentachlorophenol ug/L 0.038 (0.010 1490 570 (0.010
6C515 St.RAOC,AlES
Tr ibroaophenol %Recovery 135 138 Natrix Int. Matrix Int. 165
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5-JIA.-19'10
Sl.Miry of Anilyt1cil Results
Dite received: 8·Jl.tl·l'l90 Custoaer: Seizer· Raleigh Job nue: ""10-06,37
keystone ID
Dite Supled
Custoeer ID
Puueters Units
Suples
37-009
12· Jl.tH 990
C·2A·LF
37-013
12-JIJH '1'10
C·2A·LF
llJllJCATE
37-014
12· ,l\.tH 990
C·12A·EA
37-015
12· ,l\.tH 990
C·l2B·EA
---------------------------------------------------------------------------------------------------------------------------
Tohl Alkilinity as CaCOJ ag/L 167 tf! 234 239
Chloride ag/L 30.4 Ill 19.0 16.2
Cirbonate Alkalinity as Cilll3 •gll 0.000 Ill 0.000 0.000
Bicarbonate Alkalinity as CaC03 1g/L 167 tfl 234 239
Sulfate ag/l 3. 70 tfl 11.0 8.20
Dissolved Calciia ug/L 3o900 Ill 38000 3-4200
Dissolved Pohssiia ug/l (5000 Ill (5000 (5000
Dissolved "agnesiia ug/L 18100 Ill 22400 18900
Dissolved Sodiia ug/l 23300 Ill 45300 55900
6C515
Pentachlorophenol ug/L 0.017 0.020 0,032 0,012
6C5l5 Sl.m1XiATES
Tribroaophenol %Recovery 84.t 85.4 92,7 78.0
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5·J\Jl·l9'1<i
Keystone ID
Date Supled
Custoaer ID
Paraaeters
S<aaary oi Analytical Results
Date rece1veo: 8·JLN·l'l'10 Cust.:,aer: Beazer· Raleigh
Units
Suples
37-016
l2·JIIM9'10
f8
37-018
13· J\IH 9'10
C·l5A·OSS
37-019
13·,l\.tH 9'10
C·26B·1'A
lob naae: ll90·0b.37
37-020
13· J\IH 9'10
C·31·1'A
PalJI j
-----------------------------------------------------------------------------------------------------------------------------
Total Alkalinity as CaaxJ ag/L If! 231 164 187
Chloride ag/l Ni 21.8 11.4 33.2
Carbonate Alkalinity as CaC03 ag/l Ni 0.000 0.000 0.000
Bicarbonate Alkalinity as CaaxJ ag/l Ni 231 164 187
Sulfate ag/L Ni 11.0 (1.00 2.50
Dissolved Calciia ug/l Ni 37400 45900 52400
Dissolved Potassiia ug/L Ni <5000 (50()() (50()()
Dissolved Magnesiia ug/l Ni 18100 16200 18200
Dissolved Sodiia ug/l If! 55100 8470 23900
6CSl5
Pentachlorophenol ug/l <0.010 0.011 0.018 0,078
6C515 ~TES
Tribroaophenol %Recovery 82.9 Bb.6 92.7 76.8
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5-Jll-1990
51Mary o1 Analytical Results
Date received: B·Jl.N-1990 Custoaer: Beazer -Raleigh
Keystone ID
Dite Sapled
Custcaer ID
Paraeters
Totil Alkalinity IS CaC03
Chloride
Cubonate Alkalinity as CaCOJ
BicubonHe Alkalinity as CaCOJ
Sulhte
Dissolved Calcii.a
Dissolved Potassii.a
Dissolved Magnesii.a
Dissolved Sodii.a
6CS15
Pentachlorophenol
6CSIS ~TES
Tr ibroaophenol
Units
ag/L
1g/L
ag/L
ag/L
ag/L
ug/L
ug/L
ug/L
ug/L
ug/L
%Recovery
Saples
37-021
13· ,llJH 990
FB
lfl
lfl
lfi
lfl
Ill
lfl
lfi
lfl
lfl
(0.010
91.5
Job nae: ll90-06.37
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SlMiry of An.lytic.l Results
o.te received: 8·J1Jl·l9'10 Custo,,er: he.zer • Raleigh Job nae: MW·06.J7
Keystone 1D
Ode Supled
Cust011er ID
Parueters
8020
lsopropyl Ether
8020 SIJd,OC,ATES
Benzotrifluoride
8040
Phenol
2-Chlorophenol
2·Nitrophenol
2,4-Daethylphenol
214-Dichlorophenol
4·Chloro-3·aethylphenol
2,4,6-Trichlorophenol
214-Dinitrophenol
4·Nitrophenol
2131516-Tetrachlorophenol
2-Nethyl-416-dinitrophenol
Pent.chlorophenol
8040 su;:RO,ATES
2-F luorophenol
21416-Tribroaophenol
Units
ug/L
X Recovery
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
X Recovery
X Recovery
Suples
37·003
7·Jl.tH'l90
WELL C·5/HiA
(1.00
76.8
(0.500
(0.500
(0,500
(0,500
(0,500
(0.500
<t.00
(1.00
(1.00
(1.00
(1.00
(1.00
45.3
55.4
37·004
7-Jl.tH'/90
WELL C·6A·WA
(1.00
85.1
0.713
(0,500
<0.500
(0.500
(0.500
(0,500
(1.00
(1.00
(1.00
(1.00
<t.00
(1.00
40.7
51.7
37--005 37-oob 37-007
7-JI.N·IC/90 7·JI.N·l'l90 7·JI.N·l'l90
NELL C·l4A·FL NELL C-14B·FL FB
1140 810 (1,00
79.8 98.0 92.7
<0.500 1.35 2.43
(0,500 (0.500 (0,500
(0,500 (0.500 (0,500
(0,500 (0,500 <0.500
(0,500 (0,500 (0,500
(0.500 (0.500 (0,500
(1.00 1.94 (1.00
(1.00 (1.00 (1.00
(1.00 (1.00 (1.00
7.29 It.I (1.00
12.7 4.30 <t.00
889 499 (1.00
34.3 78.5 69.0
32.0 79.6 63.5
37-00S
7-JI.N-1'190
Ti
(1.00
102
NI
NI
NI
NI
NI
NI
NI
NI
NI
NI
NI
NI
NI
NI
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~-JIJl-1990
S\uiry of Anilytic1l Results
Oite received: 8·Jltl·19'IO
Keystone ID
Dite Saapled
Custoaer ID
Puuoeters
8020
lsopropyl Ether
8020 51.HlffiATES
Benzotritluor1de
8040
Phenol
2-Chlorophenol
2-Ni trophenol
214-Di.lethy !phenol
2,4-Dichlorophenol
4-Chloro·3·aethylphenol
2,416-Trichlorophenol
214-Dinitrophenol
4-Nitrophenol
2131516·Tetr1chlorophenol
2·"ethyl·4,6·dinitrophenol
Pent1chlorophenol
8040 S!JlROOATES
2-f luorophenol
2,4 16-Tribroeophenol
Units
ug/l
I Recovery
ug/L
ug/l
ug/l
ug/l
ug/L
ug/l
ug/l
ug/l
ug/l
ug/L
ug/l
ug/l
I Recovery
I Recovery
Saplu
37--00'1
12·,ll.tH 9'IO
C·2A·LF
(1.00
101
0.98'1
<0.500
(0.500
(0.500
(0.500
<0.500
(1.00
(1.00
(1.00
(1.00
(1.00
(1.00
56.0
68.9
Cust011er: Beazer· Raleigh
37-013
12· J\IH 9'IO
C·2A·LF
ru>LICATE
(1.00
100
0.529
(0.500
<0.500
(0,500
<0.500
(0.500
(1.00
(1.00
3.84
(1.00
(1 .00
(1.00
60. 7 n.e
37-014
12· J\JH 9'IO
C·12A·EA
(1.00
97.0
o.m
(0.500
(0.500
<0.500
(0.500
<0.500
(1.00
(1.00
3.46
(1.00
(1.00
(1.00
63.l
81.4
Joll nue: "90-06.37
37-015
12· J\JH 9'IO
C·12B·EA
(1.00
92.9
1.06
(0.500
(0.500
(0.500
<0.500
(0.500
(1.00
(1.00
3.18
(1.00
(1.00
(1.00
64.0
79,2
37-016
l2· Jl.tM990
FB
(1.00
101
o. 7.11
<0.500
<0.500
(0.500
<0.500
(0.500
(1.00
(1.00
(1.00
(1.00
(1.00
(1.00
21,7
66.6
37-017
12· Jl.tH 990
TB
(1.00
114
1ft
1ft
1ft
1ft
1ft
NI
NI
Ni
1ft
If!
1ft
NI
NI
1ft
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5· JIJI. • 19'10
StMary of Analytical Results
Date received: 8-Jltj-19'10 Custoaer: Beazer· Raleigh
Keystone ID
Ditt Supled
Custoau ID
Puueters
8020
lsopropyl Ether
8020 SUlRffiAlES
Benzotrifluoride
8040
Phenol
2-thlorophenol
2-Ni trophenol
214-Diaethylphenol
214-Dichlorophenol
4-Chloro-3·1ethylphenol
21416-Trichlorophenol
214-Dinitrophenol
4-Nitrophenol
2131516-Tetrachlorophenol
2-"ethyl-4 16-dinitrophenol
Pentachlorophenol
8040 srnR();A TES
2-F luorophenol
21416-Tribr011ophenol
ug/l
Suples
37-018
13-JI.ti-I 9'10
C·l5A-OSS
(1.00
% Recovery · 82.8
ug/l 0,501
ug/1. (0.500
ug/l (0.500
ug/l (0.500
ug/l (0,500
ug/l (0.500
ug/l (1.00
ug/l (1.00
ug/l I.S7
ug/l (1.00
ug/l (1.00
ug/L (1.00
% Recovery 65.2
I Recovery 80,4
37-01'1
13-Jl.N-19'10
C·26B·NA
<I .00
105
(0.500
(0,500
0.'177
(0,500
(0,500
(0.500
(1.00
(1.00
2.21
<1,00
(1.00
(1.00
49.8
58.5
37-020
13·.M·l'l'10
C·31·NA
(1.00
IOI
<0.500
(0.500
(0.500
<0.500
<0.500
(0.500
(1.00
(1.00
10.7
(1.00
(1.00
(1.00
35.'1
65.3
Job nue: ll90-o6,37
37"°21
13-.ll.tH 990
FB
(1.00
94.3
(0,500
(0.500
(0.500
(0.500
(0.500
(0.500
(1.00
(1.00
(1.00
(1.00
(1.00
(1.00
43.8
70.5
37-022
13-JUM990
111
(1.00
87.7
NI
NI
NI
NI
NI
NI
NI
NI
NI
NI
NI
NI
NI
lfl
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i,:,to.l Al~:-illi1lt"i ;: CoCJJ
Ci,lvr 1ac
Htar~0r,«i:c ?;.l~ 3lli1ity .:;.: [;CG~
Sulhi:c
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r;1;;c,h,·,:G r;grrC:li..7-,
D-.=:-v~,ei: Si:-~1~:
B:):-.;
: ;vprc.µ;: l E t1;t:r
8;;:1> SUFX:~~itS
t'H,zvi:r 1 t lu.:,r iYC
?:-,,mol
:-Cr,l.:.r c,~i,ci,c-l
::-~~it r,:,pt:n,:-1
:·' 4-[;~li1iti"!)'' l~i,C:"t\; l
: , :! -(:1.::i,l.:,ri:,v1c:,.:,i
t.•Li1l.::,r.:,-3-&Ci:ii':' l~,;;F,r l
2, 4 , ti· 7 ~ 1:,, l,:-r -:,pr;-:.ii.:• l
:,4·Di~~tr0p~c~~l
:!-tH trop:-,cr,,:,l
: ,~, ~,o-T c-: r;,::,l.:-r ,:,p~1:.i:-:.:
~-Ci, i: i;: :'1 ~ ,:.r ,:.V,ii,-:, l
C;.;4:) S:.;~.f.f.;;$iTL3
~ ·; l ~,:-r ,:.~,i:ir:-:• l
214 1 "J· i r i~r ,:~J,:-; .. ·-0::1-.'."·i
..... -c-, =-1." ...... •: J
~~ .. ·L
•~iL
ii:~/:.
;;..~.---
ug/~
:.:~; ~
:.;;;:.
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1,•.A •·-~
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··.'.' ...... _.
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. ' .-,.·.
•. I • \!\,
...... ·.-.-
-..
-. '·= ._,. J .. -
. '. .•:.-.. -. ,1--.._,._ ... _,
.. -·-·. '·" ..... .,
.. .,, .... ~ .. -.-
.: '. -·
.-. ,-:"'! .. ,, ... :,
;2.-.... _.,:
.. ' u,-:
0. (!(.(:
44(1
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• .. '. '·"·'
':.:: .. ·.: . .. ,.,.., .. .,._ .. _.
;_:;, :.ti;.::
\(;. :.(i(,
. _._ c.-. .-. •.v, ..... ~.,
. . .. ..... ._.,..,..,
. ' .-.. -. ._,, .... ., . -. '-,.:...;•
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ilo.4
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a:~i'~;
1 si:,~r ''Pl l ~ ti11H
e-..;;:0 m:GGAitS
Bcr,z,,t~ 1! hwr1~~
--. : .
--. _,.
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AWD Technologies, Inc.
APPENDIX B
SUPPORT DOCUMENTATION
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5-JUl.·19'10
St.Mary oi Analytical Results
hte received: B·J1JH990 Cir.;tour: &euer • Raleigh Job nae: "90·06.37
Keystont ID
!Utt SUj>led
Custoaer m
Parueters Units
Suplu
37-003
7·,Jl.fH'm
IIHL C·5A·IIA
37-004
7·JIJH990
WELL C·6A·IIA
37--005 37-()06 37-007
7-J\.N·1990 7·JUH'l'IO 7·.JIJH'l'IO
IIELL C·14A·FL WELL C·14B·fl FB
---------------------------------------------------------------------------------------------------------------------------
Tohl Alhlinity as CaCOJ tg/L 240 318 575 291 Ni
Chloride tg/L 9,93 38.7 63.5 52.6 Nl
Carbonate All:alinity as CaC03 1g/L 0.000 0.000 0.000 0.000 Nl
Bicarbonate Allalinity as CaC03 1g/L 240 318 575 291 Nl
Sulhtt tg/L 4.10 8.60 2.40 2.00 Nl
Dissolved ulcit.a ug/L 42700 72800 63'100 38000 lfl
Dissolved Potmit.a ug/L (5000 (5000 (5000 (5000 Nl
Dissolved 11.gnesit.a ug/L 17SOO 35400 62200 29200 Nl
Dissolved Svdit.a ug/L «ooo 48200 120000 79000 Nl
9:515
Pentachlorophenol ug/L 0,038 (0.010 1490 570 (0.010
Q:515 Sl.1,jWll ES G Tribrooopr,enol lRecovery 138 Matrix Int. Matrix Int. 165
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(HANN(L R
PM 1
8 6. '58
-<+-52
8. 38
2. 19
14. 28
PIJR',EABLE AR0!1AT IC PI llll<7
FI LE 1,
ANAL'tST: D DAIIIAHO
HA"E
1
2
3
4
!PE
6
7
8EHZ
5URR
PPR
e. "· 0.
A.
8119. 'SA9
e.
A,
0, A;><;
II, f.R7
PT
f.. 1 R
f.. '\R
;, • Wi?
R. <R
1 "· 1 q 11.,.
1 ?. 1
.. 4 • .,
1 "'· 1 '\
TMOFl( 78
1 ?4 A1
?R7 A1
1?RR A:>
1AR4 A<
1<1'.SlA7R AR
'\4'\ A!'\
JA'\ A'\ ?"~ A1
77?1 Rt
(j ,r. · • . r· I ~ ~ . . _/ .
r ,, , r
~ ..
i.>F RRT
e. 383
8,◄87 0.466
0.519
1 f.91!, 8, 6:31
0, 718
8. 70
~9R'5, 8.835
11241, 1.
f'