NCD095458527_20001108_FCX Inc. (Statesville)_FRBCERCLA RA_Performance Test Plan for the Phase I Air Sparging and Soil Vapor Extraction System OU-3-OCR

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Performance Test Plan for the
Phase I Air Sparging and
Soil Vapor Extraction System
FCX-Statesville Superfund Site OU3
Statesville, North Carolina
November 2000
27-18895.015
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I P: \PROJ\ 18895\ 18 895.015\Cvr.doc
Performance Test Plan for the
Phase I Air Sparging and
Soil Vapor Extraction System
FCX-Statesville Superfund Site OU3
Statesville, North Carolina
Prepared For:
EL PASO ENERGY CORPORATION
1001 Louisiana Street
Houston, Texas
Prepared By:
BROWN AND CALDWELL
227 French Landing Drive
Nashville, Tennessee 37228
[phone]
November 2000
27-18895.015
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Environmental Engineering & C011su//ing
227 French Landing Drive
Suite 500
Nashville, TN 37228-1605
Tel: [phone]
Fax: [phone]
November 8, 2000
Mr. McKenzie Malla,y
North Site Management Branch
EPARegion4
Atlanta Federal Center
61 Forsyth Street
Atlanta, GA 30303
RE: Performance Test Plan for the Phase I AS/SVE System
FCX-Statesville Superfund Site OU3, Statesville, North Carolina
Dear Ken:
27-18895.015
Enclosed are three copies of the document entitled "Performance Test Plan for the
Phase I Air Sparging and Soil Vapor Extraction System, FCX-Statesville Superfund Site
OU3, Statesville, North Carolina". For your convenience, one copy of this document is
provided unbound.
If you have any questions or comments regarding this document, please call me at
[phone] or call Mr. Roger Towe of El Paso at [phone].
Sincerely,
Brown and Caldwell
Kenton H. Oma, P.E.
Assistant Technical Director
Design and Solid Waste
cc: N. Testerman, NCDENR
R. Towe, El Paso
H Mitchell, Jr., Beaunit
M. Garlick, Burlington
N. Prince, ESC
P: \PROJ\ 18895\ 18895.0 t5\L 110800.doc
(1 copy)
(2 copies)
(1 copy)
(1 copy)
(1 copy)
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CONTENTS
LETTER OF 1RANSMITTAL
CONTENTS
LIST OF TABLES
LIST OF FIGURES
1.0 Introduction
1.1 Background Information .............................................................................. .
1. 1. 1 Site Location and Description ........................................................... .
1.1.2 Site Conditions ................................................................................. .
1.2 Description of Air Sparging/Soil Vapor Extraction System ........................... .
1.3 Objectives of Performance Testing ............................................................... .
1.4 Overview of Performance Testing ................................................................ .
1.5 Report Organization .................................................................................... .
2.0 Description of Source Area ..................................................................................... .
Ill
IV
1-1
1-2
1-2
1-3
1-3
1-5
1-6
1-7
2-1
2.1
2.2
2.3
2.4
2.5
Source Area Geology.................................................................................... 2-1
3.0
Source Area Groundwater voe Results........................................................ 2-2
Source Area Soil voe Results....................................................................... 2-3
Source Area Vapor voe Results................................................................... 2-4
Evaluation of Source Area voe Results........................................................ 2-5
Preliminary SVE Performance Data ......................................................................... .
3.1 SVE Well Performance Data ........................................................................ .
3.2 SVE Area of Influence ................................................................................. .
3.3 Evaluation of Preliminary SVE Performance Data ........................................ .
3-1
3-1
3-2
3-2
4.0 Phase I Performance Test Plan ................................................................................ . 4-1
4-2
4-2
4-3
4-4
4-5
4-5
4 .1 Calibrate Instrumentation ............................................................................ .
4.2 Conduct Source Area Groundwater Sampling ............................................... .
4.3 Conduct Permeability Testing at Monitoring Probes ...................................... .
4.4 Conduct Vapor Sampling ............................................................................. .
4.5 Perform Monitoring of the System ............................................................... .
4.6 Conduct Air Sparging With Helium Tracer Testing ....................................... .
5.0 Reporting 5-1
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CONTENTS (continued)
APPENDICES
Appendix A.
Appendix B.
Appendix C.
Groundwater voe Analytical Reports
Soil Voe Analytical Reports
Vapor Voe Analytical Reports
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LIST OF TABLES
No.
Follows
Page
2-1 Well and Monitoring Probe Screen Intervals ............................................................ 2-1
2-2 Source Area Groundwater Sampling Results for PCE and Selected Daughter
Products................................................................................................................ 2-2
2-3 Soil Sampling Results for PCE and Selected Daughter Products............................... 2-3
2-4 Vapor Sampling Results for PCE and Selected Daughter Products........................... 2-5
4-1 Source Area Groundwater Sampling Parameters...................................................... 4-2
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LIST OF FIGURES
Follows
No. Page
1-1 Site Location Map.................................................................................................. 1-2
1-2 Site Layout............................................................................................................. 1-2
2-1 Cross-Section Location Map................................................................................... 2-1
2-2 Cross-Section A-A'................................................................................................. 2-1
2-3 Cross-Section B-B' ................................................................................................. 2-1
2-4 Cross-Section C-C' ................................................................................................. 2-1
2-5 Cross-Section D-D' ................................................................................................ 2-1
2-6 Cross-Section E-E'................................................................................................. 2-1
2-7 Isoconcentration Map for PCE in Groundwater...................................................... 2-3
3-1 Preliminary Vacuum-Flow Relationships for SVE Extraction Wells.......................... 3-1
3-2 Vacuum Isa-Bars During SVE ................................................................................ 3-2
4-1 Schedule for Phase I Performance Test . . .. . .. ...... .. . .. .. . . .. .. . .. . .. . .. . .. . . . . .. . .. . . . . ... . .. . ....... .. 4-1
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1.0 INTRODUCTION
The United States Environmental Protection Agency (USEPA), United States Department of
Justice, Beaunit Corporation, Burlington Industries, Inc., and El Paso Natural Gas d/b/ a El Paso
Energy Corporation (El Paso) have entered into an agreement (Consent Decree) for the
performance of response work at the FCX-Statesville Superfund Site (Site) Operable Unit 3 (OU3)
in Statesville, North Carolina consistent with the National Contingency Plan. This response work
includes performance of a Remedial Action (RA) for soil and groundwater at the Site.
The RA is being performed by El Paso to implement the response actions selected for the Site. The
RA Work Plan CTuiy 2000) provided a plan of action for completing the RA activities and presented
a discussion of the tasks to be performed, a Project Delivery Strategy, a Construction Management
Plan, and a Construction Quality Assurance Plan (CQAP). The RA Work Plan addressed the
technical requirements of the September 30, 1996 Record of Decision (ROD) issued by the USEPA
and incorporated work elements and deliverables previously specified in the Consent Decree,
Statement of Work, and in the approved Remedial Design (RD) Work Plan.
The RA for the treatment of groundwater and soil contamination at the Site is an air sparging/ soil
vapor extraction (AS/SVE) system with monitored natural attenuation for areas down gradient of
the AS/SVE system. An observational approach has been incorporated into the RD and RA for
implementation of the AS/SVE system due to the heterogeneity of the soil at the Site as identified
during the Pre-Design Investigation. The observational approach calls for a Phase I AS/SVE
design, construction, and testing and allows for a Phase II design, construction, and operation at a
later time if determined appropriate. The construction of the Phase I AS/SVE system has been
completed and is documented in the report entitled "Construction Completion Report for the Phase
I Air Sparging and Soil Vapor Extraction System, FCX-Statesville Superfund Site OU3, Statesville,
North Carolina" dated November 2000 by Brown and Caldwell (hereafter referred to as the
Construction Completion Report). If the Phase I AS/SVE system is found to be adequate without
modification, the system will be operated to address the groundwater and soil contamination in the
source area without the need to implement Phase IL
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This report presents the Phase I Performance Test Plan for testing the Phase I AS/SVE system and
for evaluating the need for Phase II. The balance of Section 1.0 presents background information
for the Site, a description of the AS/SVE system, the objectives of the Phase I performance testing,
an overview of the performance testing, and the report organization.
1.1 BACKGROUND INFORMATION
The following includes a brief description of the Site as well as Site conditions.
1.1.1 Site Location and Description
The OU3 Site is located in Iredell County approximately 1.5 miles west of downtown Statesville,
North Carolina (see Figure 1-1). The Site consists of the soil, groundwater, sediment, and surface
water contamination emanating from the textile plant property currently owned by Burlington. The
property is approximately 15 acres in size. Two large buildings consisting of a warehouse
(approximately 60,000 square feet in size) and a textile plant building (approximately 275,000 square
feet in size) are located on the Burlington property (see Figure 1-2).
Land immediately surrounding the Site is predominantly industrial with a variety of other uses
ranging from commercial to residential with associated school and church facilities. Farther from
the Site, rural land in the Statesville area is used for timber farming, grain crops farming, and dairy
farming.
The Site lies within the geologic belt known as the Blue Ridge-Inner Piedmont Belt, which is
situated in the Inner Piedmont Physiographic Province in western-central North Carolina. This
province is characterized as gently rolling slopes. The Blue Ridge-Inner Piedmont Belt consists of
metamorphic rocks including gneisses and schists. These rocks have weathered to form a relatively
thin overburden of saprolite, which is observed throughout the Site.
Groundwater at the Site is observed within the saprolite and underlying bedrock. Saprolite forms
the uppermost hydrogeologic unit. Groundwater occurs within the pore spaces of the saprolite
under water table conditions. Groundwater within the fractured bedrock unit occurs under
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SOURCE: U.S.G.S. TOPOGRAPHIC MAP, STATESVILLE WEST QUADRANGLE, NC
FIGURE 1-1
SITE LOCATION MAP
FCX-STATESYILLE SUPERFUND SITE
STATESVlLLE, NORTH CAROLINA
18895.013 2/00
BROWN AND
CALDWELL Nash'rille, Tonnes:!lae
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SITE LAYOUT
200 400
ERFUND SITE, OUJ FCX-STATESVILLEE SNU6RTI-1 CAROLINA 2/00 STATESVILL '
18895.013
FEET BR Q WN AND No,h,illo, Team,~ CALDWELL
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unconfined or semi-confined conditions. Site information indicates that the two units are in
hydraulic communication. Groundwater gradients observed on-Site indicate that groundwater in the
saprolite and bedrock appears to be flowing both to the north and to the south from the textile
plant.
1.1.2 Site Conditions
Several media and constituents of interest are associated with OU3. The primary constituents of
interest present within OU3 include perchloroethylene (PCE), also called tetrachloroethene, and
other chlorinated hydrocarbons. The groundwater contains primarily PCE and other volatile
organic compounds (VOCs). On-Site soil contains primarily VOCs and to a lesser extent,
inorganics and polynuclear aromatic hydrocarbons (PAHs). Groundwater and soil contamination
are being remediated by AS/SVE with monitored natural attenuation for areas down gradient of the
AS/SVE system. Surface water and sediment associated with an intermittent stream originating
from a seep to the north of the Burlington textile plant also contain some inorganic constituents,
polychlorinated biphenyls (PCBs), and VOCs; however, it was determined that the constituent
concentrations posed no risk and no remediation is required.
1.2 DESCRIPTION OF AIR SPARGING/SOIL VAPOR EXTRACTION SYSTEM
The AS/SVE process that was installed during the Phase I construction consists of the following
components:
• twenty-five triple-purpose wells
• SVE system
• air sparging system
• Supervisory Control and Data Acquisition System (SCADA) system
• security measures.
While each of the wells has a specific purpose now, the wells were designed and constructed so that
any of them can be used for SVE, air sparging, monitoring, or any combination of the three. The
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above-ground piping and instrumentation have been installed so that the wells can be used as
follows for the performance test:
• two wells for both air sparging and SVE
• eight wells for SVE only
• fifteen wells for monitoring probes.
The SVE system consists of piping from the SVE wells, a packaged blower system, a heat
exchanger, and two granular activated carbon (GAC) vessels. The piping includes a 6-inch diameter
common extraction header and 2-inch connecting pipe branches to the wells selected for SVE. The
SVE header and branch piping are fabricated from high-density polyethylene (HDPE). The SVE
blower system is skid-mounted and includes a liquid separator, a particulate filter, provisions for
bypass air, and two blowers piped to operate individually or in parallel. The blowers operate to draw
the soil gas out of the selected SVE wells, through the heat exchanger, and through two GAC
vessels that are operated in series to capture organic vapors before the exhaust gas is discharged to
the atmosphere. The heat exchanger reduces the vapor temperature to about 90°F or less, which
improves the GAC absorptive capacity. The GAC in the vessels can be exchanged when the carbon
in one vessel reaches its adsorptive capacity. The treated air is checked by an in-line gas analyzer and
subsequently exits the carbon vessels and the building through a vent pipe that extends above the
roof.
The air sparge system consists of an oil-free air compressor. The piping consists of 1-inch HDPE,
which is rated for compressed air. The piping runs from the air compressor to the two wells
selected for air sparging. The system forces air into groundwater through the screened section of
the air sparging wells. Solenoid valves, located in the air piping to each of the air sparging wells,
allow for the sparged air to be injected in pulses and at a desired frequency and duration.
The SCADA system consists of instrumentation connected to the process piping and equipment.
These instruments provide necessary operation data to the programmable logic controller (PLC).
The controls for the system are housed in two cabinets located in the same area as the equipment.
One cabinet houses the motor starters, PLC, hand switches, alarm lights and other process electrical
components. The other houses a computer that enables an operator to visually monitor the system
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and control it. Data acquisition and system operation can also be accomplished from a remote
computer.
The AS/SVE process equipment and control cabinets are located within an equipment area, which
is secured inside an eight-foot tall chain-link fence with locking gates. The equipment area is
accessible from the outside using a key-operated, overhead coiling door. The wells and piping
throughout the plant are protected by bollards that are set into the concrete floor and connected by
chains.
The City of Statesville provides electric service to the AS/SVE system that is independent of the
building's main power. BellSouth provides telephone service using a telephone line from a terminal
outside the building to allow remote access to the SCAD A system via modem.
1.3 OBJECTIVES OF PERFORMANCE TESTING
Three primary objectives have been identified for the Phase I performance testing. These objectives
are:
• assess the effectiveness of SVE
• assess the effectiveness of air sparging
• provide design information and evaluate the need for a Phase II design, construction, and
operation.
To help assess the effectiveness of SVE, the testing will be performed to collect the following
information:
0 the mass of PCE removed from the vadose zone versus time
• the flow and radius of influence of SVE versus time
• the vapor phase PCE concentrations at the wells/ probes versus time.
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To help assess the effectiveness of air sparging in conjunction with SVE, the testing will be
performed to collect the following information:
• the mass of PCE removed from the saturated zone versus time
• the flow and radius of influence of air sparging versus time
• the effectiveness of sparge air capture by SVE
• the affect, if any, of air sparging on monitored natural attenuation in the saturated zone.
The third objective of the Phase I performance test is to provide design information and evaluate
the need for a Phase II design, construction, and operation. The overall objective of AS/SVE is to
remove VOC mass from the Site source area. The second part of the remedy is monitored natural
attenuation outside the source area as a means to remove VOC mass from the down gradient
saturated zone. The Phase I performance test data will be evaluated to determine if any changes to
the system are recommended to address the source area VOCs. The recommended changes could
include the addition or elimination of SVE wells or air sparging wells. Additional monitoring probes
could also be included as part of the recommended changes. If changes to the system are not
warranted, then AS/SVE would be started and operated without proceeding to a Phase II design,
construction, and operation.
1.4 OVERVIEW OF PERFORMANCE TESTING
The Phase I performance testing will involve operation of the SVE system using the ten extraction
wells for approximately two months followed by two weeks of operation of AS/SVE. After the two
weeks of AS/SVE operation, SVE will be continued for approximately one month using the ten
extraction wells. Groundwater samples will be collected before, during, and after the test to monitor
any changes in VOCs or selected natural attenuation parameters. Vapor samples will be collected
shortly after startup, during SVE only, immediately prior to air sparging, during air sparging, and
after the last month of SVE. These vapor samples will be collected at each extraction well, at the
blower inlet, and between the GAC vessels to monitor changes in VOC concentrations and the
mass removed. Vapor samples will also be collected from selected monitoring probes before and
after SVE. A helium tracer test will be conducted during air sparging to check the effectiveness of
capture of sparged air by the SVE system. During the operation of the SVE and air sparging
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systems, both remote and on-Site monitoring of the process will be performed to maintain the
system and monitor the overall system performance.
1.5 REPORT ORGANIZATION
The Phase I performance test plan is organized into the following sections:
Section 1.0 -
Section 2.0 -
Section 3.0 -
Section 4.0 -
Section 5.0 -
Introduction
Description of Source Area
Preliminary SVE Performance Data
Phase I Performance Test ,Plan
Reporting
Analytical laboratory reports for results presented for groundwater samples, soil samples, and vapor
samples are included in Appendices A, B, and C, respectively. The description of the source area
presented in Section 2.0 and the preliminary SVE performance data presented in Section 3.0 are
based on information obtained during the Phase I Construction and the Phase I Operational
Acceptance Testing (OA1).
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2.0 DESCRIPTION OF SOURCE AREA
This section describes information that was obtained during the Phase I construction and OAT that
has added to the understanding of the PCE source area. This information provides a baseline of
existing conditions within the source area for the Performance Test Plan,
2.1 SOURCE AREA GEOLOGY
As part of the Phase I construction, 10 wells and 15 monitoring probes were installed within the
source area, Table 2-1 provides information about the wells and monitoring probes including the
well or monitoring probe identification number and the screen interval depths within the vadose
zone and saturated zone. The construction well logs are included as Appendix F to the
Construction Completion Report, A description of the Site location and Site wide geology is
presented in Section LL
Five geologic cross-sections have been prepared based on the well logs, Figure 2-1 shows the
locations chosen for the cross-sections. Two north-south and three west-east cross-sections are
shown in Figures 2-2 through 2-6. The cross sections provide information on the zones that are
predicted to have higher pneumatic and hydraulic permeabilities. The predicted permeabilities are
based upon visual observation of direct-push Geoprobe® samples collected prior to installation of
the wells and monitoring probes. Also, the permeable zones indicated on the cross-sections
between the wells and monitoring probes are inferred and not directly measured. The approximate
depth of the groundwater is 42 feet based on visual inspection of the soil moisture during the
Geoprobe® investigation and a groundwater level measurement at W-17s.
The saprolite has generally been characterized as heterogeneous reddish-brown, clayey silts with little
fine sand. Zones of dark brown silt and fine sand, which constitute zones of somewhat higher
relative permeability, are distributed throughout the clayey silts. Zones of gray-white silty and gray-
white fine sand and silt were also identified and are believed to be associated with quartz pegmatite
veins that were intruded into the original metamorphic rock. The weathered remnants of these
;,,eins were observed throughout the saprolite beneath the textile plant. The gray-white silts
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Table 2-1. Well and Monitoring Probe Screen Intervals
Well ID Number
EW-1/SW-1
EW-2/SW-2
EW-3
EW-4
EW-5
EW-6
EW-7
EW-8
EW-9
EW-10
111'-1
111'-2
111'-3
111'-4
111'-5
111'-6
111'-7
111'-8
111'-9
111'-10
111'-11
111'-12
111'-13
111'-14
111'-15
Screen Interval'
Vadose Zone Screen6
(Depth, ft)
17,0 -42,0
15,0 -40,0
16,5 -41,5
20,0-40.5
16.5 -41,5
18,0-43,0
18.5-43.5
17.5-42.5
17,0-42,0
17,0-42,0
17,0-42,0
17,0-42.0
17.5 -42.5
17,0 -42,0
17.5 -42.5
18,0 -43,0
17,0-42,0
17,0-42,0
16,0-41,0
15,0-40,0
17.0-42,0
17,0 -42,0
20.5-40.5
16,0 -41,0
17.5 -42,0
Groundwater Screen'
(Depth, ft)
50,0-52.5
52.5 -55,0
56.5-59,0
55,5 -58,0
50,0-52.5
54,0-56.5
56,0-58.5
53,0 -55,5
53,0-55.5
53,0-55,5
53,0-55,5
52.5 -55,0
52,5 -55,0
52,0-54.5
47,5 -50,0
58,0-60.5
53,0 -55.5
52,0-54.5
5L0 -53.5
45,0-47,5
53,0-55,5
59.5 -62,0
48,0-50.5
56,0 -58,5
52,5 -55,0
'Depth data are reported relative to the floor slab elevation except for EW-10 and 111'-13, which are
outside the building and the depth data are relative to the pavement elevation,
bFour inch outer well,
'Two inch inner well.
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50 0 50 100 -----. SCALE FEET
LEGEND:
0 l>S/SVE WELL
EB SVE WELL
T MONITORING PROBE
FIGURE 2-1
CROSS-SECTION LOCATION MAP
FCX STATESVILLE SUPERFUND SITE OU3
STATESVILLE, NORTH CAROLINA
18895.015 09/00
BROWN AND
CALDWELL Nashville, Tennessee
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'I 0
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ci z
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NORTH SOUTH
A A'
0 _M_P7-,14 __________ EW_-rs ___ M_P,-_,o _______ E_w_-72/rs_w_-_2 _____ M_P,-_9 _______ E_w_-_7 ____________ ___::M:.,P---=8
--------------Bu ii ding
Floor
Grade
1 Q _ __,__
3 0 _ L.tfif----~
70
Zones af Generally Higher Saprolite Permeability
(Continuity between wells and monitoring probes is inferred.)
Vadose Zone Screen Interval
Groundwater Screen Interval
Horizontal Scale: 1 "=30'
Vertical Scale: 1 "= 1 o•
Vertical Exaggeration: 3: 1
FIGURE 2-2
Approximate
Location of
Water Table
CROSS-SECTION A-A'
FCX-STATESVILLE SUPERFUND SITE OU3
STATESVILLE, NORTH CAROLINA
18895.015 09/00
BROWN AND
CALDWELL Nashville, Tennessee
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>--0 ;I _,
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00 00
0 z
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B
SOUTH
B'
0 __ M_P_-_13 __________ M_P
1
-_1_2 __________ ---=EW_-_1:_/s7wr-~1 ~M~P_-~1:__5 __________ _:M'._P~5--------------~M~P~l'.___
~ Building
Floor
Grade
--.---Grade
Outside
Building
30 ----
4 0 --------tti--------
70 __ _
--------------------1+1-------------
Zanes of Generally Higher Saprolite Permeability
(Continuity between wells and monitoring probes is inferred.)
Vadose Zone Screen Interval
Groundwater Screen Interval
-
____--:
Horizontal Scale: 1 "=30'
Vertical Scale: 1"=10'
Vertical Exaggeration: 3: 1
::::>-
FIGURE 2-3
Approximate
Location of
Water Table
CROSS-SECTION B-B'
FCX-STATESVILLE SUPERFUND SITE OU3
STATESVILLE, NORTH CAROLINA
18895.015 09/00
BROWN AND
CALDWELL Ne.sbville, Tennessee
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I w _,
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I "' I a, co co
c:i z
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WEST
C
EAST
c'
Q __ EW_-r3 _________ M_Pr-_12 _____ E_WT-_4 _____ MTP-_11 ________ Ew
7
-r5-------------~M:::_P,-__:1 __________ _
~ Building
Floor
Grade
40 __ _
j
Zones of Generally Higher Saprolite Permeability
(Continuity between wells and monitoring probes is inferred.)
Vadose Zone Screen Interval
Groundwater Screen Interval
Horizontal Scale: 1 "=30'
Vertical Scale: 1 "= 1 o·
Vertical Exaggeration: 3: 1
FIGURE 2-4
CROSS-SECTION C-C'
FCX-STATESVILLE SUPERFUND SITE OU3
STATESVILLE, NORTH CAROLINA
18895.015 09/00
BROWN AND
CALDWELL Nashville, Tenne!lsee
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.-1 w _, -< u V)
f--0
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0 0 '-" I 0 '-
w ~
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I "' I O>
<O <O
0 z
I '-' z
j: -< "' 0
I
WEST
20
D
-~-Grade
Outside
Building
60 _____ _
70
EW-2/SW-2
- - - - - - - -
EAST
D'
EW-6
~ Building
Floor
Grade
Approximate
Location of
Water Table
--. - --~--::_ -_--=-·-----~-------------·--------·
Zones of Generally Higher Saprolite Permeability
(Continuity between wells and monitoring probes is inferred.)
Vadose Zone Screen Interval
Groundwater Screen Interval
Horizontal Scale: 1 "=30'
Vertical Scale: 1 "=10'
Vertical Exaggeration: 3:1
FIGURE 2-5
CROSS-SECTION D-D'
FCX-STATESVILLE SUPERFUND SITE OU3
STATESVILLE, NORTH CAROLINA
18895.015 09/00
BROWN AND
CALDWELL Nashville, Tennes9ee
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0
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c:i z
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<( °' 0
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WEST
E
EAST
E'
0 __ E_Wr-_9 _____ M
7
P_-_5 ______ E_WT-_a ______ M_P_-r6 ________ E_W_-r7 _______________ M_P-r--3 _____________ _
~ Building
Floor
Grade
10 ____ ·~------+--------4-----------~----------------------------------~------------------
30 __
40
I: :l .. ,
- - - - --- -
-= = = = = = = = = =~ H
Approximate
Location of
Water Table
- - -. --~-=---=ii.,=:---_
60 _____________ ~-:;:_==~=~=::11i,_1:::-======~==~~~~.:....:-_::.-_2_:=.::::J~=====-~=--------------------
70 ----··
Zones of Generally Higher Saprolite Permeability
(Continuity between wells and monitoring probes is inferred.)
Vadose Zone Screen Interval
Groundwater Screen Interval
Horizontal Scale: 1 "=30'
Vertical Scale: 1 "=1 o·
Vertical Exaggeration: 3: 1
FIGURE 2-6
CROSS-SECTION E-E'
FCX-STATESVILLE SUPERFUND SITE OU3
STATESVILLE, NORTH CAROLINA
18895.015 09/00
BROWN AND
CALDWELL Nashville, Tennessee
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exhibited higher permeability similar to the reddish brown clayey silts. The gray-white fine sand and
silt zones exhibited the highest relative permeability of that observed within the saprolite.
The distribution of the gray-white fine sand and silt zones is presented in the cross-section maps
(Figures 2-2 through 2-6). In general, the region of higher relative permeability within the saturated
zone extends diagonally from northwest to southeast beneath the textile plant. One air sparging
well, EW-2/SW-2, is located within this region of higher relative permeability, while the other air
sparging well, EW-1/SW-1, appears to be located in a region of lower relative permeability. The
source area underneath the textile plant has a calculated groundwater seepage velocity of
approximately 40 feet per year. At this velocity, oxygen introduced into the groundwater during air
sparging may take several years to migrate beyond the source area, and thus should have minimal
short-term impact on anaerobic biodegradation.
2.2 SOURCE AREA GROUNDWATER VOCRESULTS
Table 2-2 presents a summary of the source area groundwater sampling results for PCE and selected
natural attenuation daughter products of trichloroethene (TCE), cis-1,2-dichloroethene (DCE), and
vinyl_ chloride. The analytical laboratory reports by Eckenfelder Laboratory, LLC are included in
Appendix A; the reports include the results for other VOCs not shown in Table 2-2. The results for
other VOCs are generally below their detection limits or at very low concentrations. Groundwater
samples were collected and analyzed using sampling and analysis methods consistent with the
ongoing semiannual monitored natural attenuation sampling that is being performed according to
the RA Wora Plan. The sampling was performed in accordance with a Quality Assurance Project
Plan (QAPP) that outlines quality assurance/quality control (QA/QC) samples required. Two
QA/QC duplicate samples were collected and are included with the summary results in Table 2-2.
Groundwater samples were collected from each of the AS/SVE wells, the SVE wells, and the
monitoring probes. Table 2-2 presents sample numbers and the sampling dates for each well and
monitoring probe.
The PCE concentrations in the source area groundwater ranged from 37 µg/L in MP-3 to
52,000 µg/L in EW-2/SW-2. Nine of the well/probe locations had TCE sample results of
non-detect; the detected results ranged from 1.2 µg/L in MP-3 to 1,600 µg/L in MP-13. Seven
\ \Ba!SH0J\PROJECTS\PROJ\18895\!8895.015\502.doc 2 · 2
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I Table 2-2. Source Area Groundwater Sampling Results for PCE and Selected Daughter Products
FCX-Statesville Superfund Site OU3
I PCE and Daughter Product Concentrations'
Well ID Well Sample ID Sampling T etrachloro-Trichloro-cis-1,2-Dichloro-Vinyl
Number Function Number Date ethene ethene ethene chloride I (mmldd/yy) (µgll) (µgll) (µgll) (µg/L)
I EW-1/SW-1 AS/SVE EW-16 07119100 770D 32 JD 79 JD 200 UD
EW-2/SW-2 AS/SVE EW-2/SW-2 06/22/00 52,000 D 1,000 UD 110 JD 2,000 UD
I EW-3 SVE EW-3 06/30100 170 3.1 J 10 U 20 U
EW-3 dupe 06130/00 180 3.3 J 1.7 J 20 U
EW-4 SVE EW-4 06130100 770D 10 JD 18 JD 100 UD
I EW-5 SVE EW-5 06123100 22,000 D 2,500 UD 2,500 UD 5,000 UD
EW-6 SVE EW-6 06122100 640 D 50 UD 50 UD 100 UD
I EW-7 SVE EW-7 06121100 1,400 D 100 UD 100 UD 200 UD
EW-8 SVE EW-8 06121100 3,400 D 70 D 160 D 100 UD
I EW-9 SVE EW-9 07111100 4,500 D 500 UD 190 JD 1,000 UD
EW-10 SVE EW-10 07/13100 570 D 5.9 JD 50 UD 100 UD
MP-1 Monitoring MP-1 07120100 850 D 5.0 JD 50 UD 100 UD
I MP-2 Monitoring MP-2 07113/00 920 D 10 JD 30 JD 100 UD
MP-3 Monitoring MP-3 07112100 37 1.2 J 10 U 20 U
I MP-4 Monitoring MP-4 07119100 2,800 D 14 JD 12 JD 200 UD
MP-5 Monitoring MP-5 07113100 4,700 D 500 UD 87 JD 1,000 UD
I MP-6 Monitoring MP-6 07120100 3,800 D 170 JD 250 D 400 UD
MP-7 Monitoring MP-7 07/12/00 6,200 D 61 JD 220 D 400 UD
I MP-8 Monitoring MP-8 06123100 690 D 11 JD 7.0 JD 100 UD
MP-9 · Monitoring MP-9 06123100 5,200 D 500 UD 500 UD 1,000 UD
I
MP-10 Monitoring MP-10 06123100 13,000 D 1,000 UD 230 JD 2,000 UD
MP-11 Monitoring MP-11 07119100 960 D 16 JD 33 JD 100 UD
MP-11 dupe 07119100 1,200 D 22 JD 46 JD 100 UD
I MP-12 Monitoring MP-12 07119100 1,800 D 67 JD 140 D 200 UD
MP-13 Monitoring MP-13 07111100 29,000 D 1,600 JD 3,300 D 5,000 UD
I MP-14 Monitoring MP-14 06123100 15,000 D 1,000 UD 1,000 UD 2,000 UD
MP-15 Monitoring EW-1/SW-1 06130100 230 7.7 J 14 20 U
I 'Data qualifiers are as follows:
B indicates that this compound was also detected in the method blank and the data should be interpreted with caution.
D indicates that this sample was diluted because one of the compound concentrations exceeded the highest concentration range for
the standard curve.
I J indicates that the reported result is estimated because the result is less than the estimated quantitation limit (EQL).
U indicates that the result was not detected above the method detection limit (MDL).
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locations had cis-1,2-DCE results of non-detect; the detected results ranged from 1.7 µg/L in EW-3
to 3,300 µg/L in MP-13. Each of the 25 well/probe locations had vinyl chloride results of
non-detect (see Table 2-2).
Figure 2-7 shows an isoconcentration (isocon) map for PCE in the source area groundwater. The
isocon map is an estimation based on sampling results for PCE that are presented in Table 2-2 along
with sampling results from previous sampling of existing wells at the Site in and adjacent to the
source area. The PCE isocon lines represent baseline conditions prior to the Phase I performance
testing of the AS/SVE system. One area of high concentration is around the AS/SVE well,
EW-2/SW-2, which had a PCE result of 52,000 µg/L; this well is near monitoring well W-17s which
has historically had the highest PCE concentration within OU3. In general, the PCE contours on
Figure 2-7 show that there was probably more than one area with higher PCE concentrations.
2.3 SOURCE AREA SOIL voe RESULTS
Soil sampling was performed at selected locations prior to the installation ofthe 25 wells/probes.
The soil samples were collected from some of the direct push Geoprobe ® cores that were obtained
at the well and monitoring probe locations prior to their installation. Soil samples for voe analysis
were collected only from Geoprobe® core locations and depth intervals that had elevated voe
concentrations as measured by a portable voe monitor during the Geo probe® coring operation.
Eight of the wells and monitoring probes were chosen for soil sampling and subsequent chemical
analysis for voes.
Table 2-3 presents the soil sampling results for PCE and selected natural attenuation daughter
products of TCE, cis-1,2-DCE, and vinyl chloride. For each of the Geoprobe® samples analY7.ed
for Voes, PCE was detected for at least one of the soil depths. The PCE concentrations were
generally higher for the deeper sample depths. The PCE concentrations were highest at MP-13,
ranging from 2.8 mg/kg (dry) to 36 mg/kg (dry) at the depths of 10.5 feet and 35.5 feet,
respectively. PCE was detected in one or more of the samples anal}'7.ed for Voes from each of the
other wells/ probes. The detectable PCE concentrations for the other wells/ probes ranged from
0.11 mg/kg (dry) at 3.5 feet in MP-10 to 12 mg/kg (dry) at 51 feet in EW-2/SW-2. Of the eight
\ \BCNSH0J\PROJECTS\PROJ\18895\li895.015\S02doc 2-3
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0 0 ;:::-
~
"' 0
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"' "' <O <O
ci z
"' z
!
0
100 ---SCALE
0
LEGEND:
AS/SVE WELL
SVE WELL
EB TER MONITORING WELL $ GROUNDWA
._, MONITO CONTOUR (JJg RING PROBE /L)
T ISCONCENTRATION GROUNDWATER -10-/L
PCE RESULTS IN µg {37 D)
NOTES: _ _ ., D" indicotes that 1
_ PCE data qu~l~f~e~iluted be~~~~~tions
this saf mth~e compountd co~~~ntrotion one o h"ghes c
exceeded tthee ~tandard curve.
range for . are based
ation contours wells installed 2. lsococncEe~~ta obtainedft fhr~mAS/SVE systtemg
on P t uction o pre-exis ,n . g cons r . d from dunn d ta obtaine
11 and PCE t a monitoring we s. groundwa er
FIGURE 2-l
N MAP FOR ISOCONCENTG~6LON DWATER PCE IN
RFUND SITE OU3
FCX STATESVIILLC~ ti.g'R~ CAROLINA 09/00 STATESY •
18895.015 200 ,o_o . --W N AND Tennessee BRODWELL Nashville, CAL
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Table 2-3. Soil Sampling Results for PCE and Selected Daughter Products
FCX-Statesville Superfund Site OU3
PCE and Daughter Product Concentrations"
Well ID Sample Sample ID Sampling Tetrachloro-Trichloro-cis-1,2-Dichloro-Vinyl
Numbera Depth Number Date ethene ethene ethene chloride
(ft) (mm/dd/yy) (mg/kg dry) (mg/kg dry) (mg/kg dry) (mg/kg dry)
EW-1/SW-1 11.5 SW-1 11.5 ft. 05/18/00 0.24 J 0.077 U 0.077 U 0.15 U
38 SW-1 38 ft. 05/18/00 0.11 U 0.11 U 0.11 U 0.22 U
EW-2/SW-2 5 EW-2 5 ft. 05/18/00 0.20 J 0.060 U 0.060 U 0.12 U
39 EW-2 39 ft. 05/18/00 2.1 0.069 U 0.069 U 0.14 U
51 EW-2 51 ft. 05/18/00 12 0.060 U 0.060 U 0.12 U
EW-4 42 EW-442ft 05/22/00 0.65 0.057 U 0.10 J 0.11 U
56 EW-4 56ft 05/22/00 0.064 U 0.064 U 0.064 U 0.13 U
EW-6 35 EW-6 35ft 05/19/00 0.25 J 0.066 U 0.066 U 0.13 U
59 EW-6 59ft 05119/00 0.056 U 0.056 U 0.056 U 0.11 U
MP-6 4 to 8 MP-6 4-8ft 05/23/00 0.074 J 0.062 U 0.062 U 0.12 U
MP-9 3.5 MP-9 3.5ft 05/24/00 0.11 J 0.061 U 0.061 U 0.12 U
3.5 MP-9 3.5ft dupe 05/24/00 0.13 J o.064 u· 0.064 U 0.13 U
41 MP-9 41ft 05/24/00 3.3 0.059 U 0.059 U 0.12 U
MP-10 19 MP-10 19ft 05/22/00 0.076 U 0.076 U 0.076 U 0.15 U
39 MP-10 39ft 05/23/00 1.3 0.067 U 0.067 U 0.13 U
55 MP-10 55ft 05/23/00 0.12 J 0.054 U 0.054 U 0.11 U
MP-13 10.5 MP-10 10.5' 06/06/00 2.8 0.074 U 0.074 U 0.15 U
31 MP-10 31 ft.' 06/06/00 5.5 0.060 U 0.063 J 0.12 U
35.5 MP-13 35.5 ft. 06/07/00 36 0.070 J 0.093 J 0.14 U
'Only wells that were sampled for VOC analyses are listed.
"Data qualifiers are as follows:
8 indicates that this compound was also detected in the method blank and the data should be interpreted with caution.
D indicates that this sample was diluted because one of the compound concentrations exceeded the highest concentration range for
the standard curve.
J indicates that the reported result is estimated because the result is less than the estimated quantitation limit (EQL).
U indicates that the result was not detected above the method detection limit (MDL).
'Sample was labeled incorrectly as MP-10; correct label would be MP-13.
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well/probes sampled, only one (MP-13) had a detectable concentration of TCE; the rest had TCE
results of non-detect. Two well/probe locations had detectable quantities of cis-1,2-DCE: EW-4 at
42 feet and MP-13 at 31 and 35.5 feet. Each of the eight well/probe locations had vinyl chloride
results of non-detect at the depths sampled. The results for samples collected in the vadose zone
(down to approximately 42-feet), were typically higher than in the deeper saturated zone. The VOC
results in the saturated zone were typically low or non-detect; however, PCE was detected at as high
as 12 mg/kg (dry) at 51 feet in EW-2/SW-2.
The analytical laboratory reports for the VOC analysis by Eckenfelder Laboratory, LLC are included
in Appendix B; the reports include the results for other VOCs not shown in Table 2-3.
2.4 SOURCE AREA VAPOR VOC RESULTS
During the Phase I OAT, vapor samples for VOC analysis were collected from each of the ten
extraction wells, from the blower inlet, and from the midpoint between the two GAC vessels. The
SVE system was operated (without air sparging) and each SVE well was tested individually with the
other nine wells closed. Vapor samples were collected at each of the ten SVE wells first, then the
system was operated with all ten of the SVE wells opened. After the SVE system had been operated
with all ten wells, one sample was collected at.the inlet to the SVE blower, and one at the midpoint
between the two GAC vessels. One QA/Q!:, replicate sample was collected at the blower inlet for a
total of thirteen samples for VOC analysis.
The vapor sampling procedure was as follows. Vapor samples were collected in lL Tecllar bags with
stainless steel fittings and Teflon septa. A diaphragm pump with an explosion-proof motor was
used to draw vapor from the sample port at each sampling location. Each Tedlar bag was purged
twice with vapor from the chosen sample location and then was filled to approximately one-half to
three-fourths capacity and sealed closed. Two Tedlar bag samples were collected from each well;
one was for the primary sample and one was for backup in case something happened to the primary
sample. On the same day the samples were collected, they were shipped in coolers at room
temperature to the laboratory for analysis.
\ \B(NSHOJ \PROJECfS\PROJ\ 18895\ 18895.015\S02doc 2-4
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Table 2-4 presents the vapor sampling results for PCE and selected natural attenuation daughter
products including TCE, cis-1,2-DCE, and vinyl chloride. The analytical laboratory reports by
Eckenfelder Laboratory, LLC are included in Appendix C; the reports include the results for other
VOCs not shown in Table 2-4. The PCE concentrations in the vapor from the extraction wells
ranged from 720 µg/L in EW-10 to 14,000 µg/L in EW-2. In the extraction wells, TCE
concentrations ranged from 4.6 µg/L at EW-10 to 150 µg/L at EW-4; cis-1,2-DCE concentrations
ranged from 1.2 µg/L at EW-10 to 120 µg/L at EW-4. Vinyl chloride was not reported as detected
for any of the extraction wells.
The PCE concentrations reported for the two samples at the SVE blower inlet (sample numbers
BL-lA and QA/QC replicate sample BL-2A) that represent the combined vapor flow from all ten
SVE wells were 5,600 and 5,400 µg/L, respectively. The TCE results at the blower inlet were 42
and 41 µg/L; the cis-1,2-DCE results were 33 and 32 µg/L. Vinyl chloride was not detected at the
inlet to the blower. The PCE concentration at the midpoint between the GAC vessels was
130 µg/L (sample number GAC-lA); the TCE, cis-1,2-DCE, and vinyl chloride results were
non-detect. These VOC results indicate that the first GAC vessel is removing over 97.5 percent of
the PCE from the extracted vapor and essentially 100 percent of the TCE and cis-1,2-DCE from the
extracted vapor.
2.5 EVALUATION OF SOURCE AREA voe RESULTS
The VOC data from the groundwater, soil, and vapor samples is consistent with the known
heterogeneity of the soils at the Site. In some cases, the locations of the higher PCE concentrations
in the groundwater correlate with the locations of the higher concentrations in the soil and/ or
vapor. In other cases, there is not a clear correlation between the VOC data. At least two areas of
higher PCE concentrations are indicated; one at or near EW-1/SW-1 (W-17s) and a second at or
nearMP-13.
\ \BCNSH03\PROJECTS\PROJ\ 18895\ 18895.015\502.doc 2-5
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Table 2-4. Vapor Sampling Results for PCE and Selected Daughter Products
FCX-Statesville Superfund Site OU3
Sample
Sample Location Number
Equipment Area
Blower Inlet BL-1A
BL-2A
GAG Midpoint GAC-1A
Extraction Well
EW-1/SW-1 EW-1A
EW-2/SW-2 EW-2A
EW-3 EW-3A
EW-4 EW-4A
EW-5 EW-5A
EW-6 EW-6A
EW-7 EW-7
EW-8 EW-8A
EW-9 EW-9A
EW-10 EW-10A
'Data qualifiers are as follows:
Sampling
Date
(mm/dd/yy)
08/31/00
08/31/00
08/31/00
08/29/00
08/30/00
08/29/00
08/30/00
08/30/00
08/30/00
08/30/00
08/29/00
08/29/00
08/29/00
PCE and Daughter Product Concentrations'
Tetrachloro-Trichloro-cis-1,2-Dichloro-Vinyl
ethene ethene ethene chloride
(µg/L) (µg/L) (µg/L) (µg/L)
5,600 42 33 2.0 U
5,400 41 32 2.0 U
130 1.0 U 1.0 U 2.0 U
2,600 77 74 2.0 U
14,000 48 40 2.0 U
4,400 85 68 2.0 U
4,800 150 120 2.0 U
4,300 25 13 2.0 U
3,600 11 4.2 J 2.0 U
12,000 20 5.7 J 2.0 U
8,200 31 25 2.0 U
1,600 13 8.7 J 2.0 U
720 4.6 1.2 J 0.40 U
B indicates that this compound was also detected in the method blank and the data should be interpreted with caution.
D indicates that this sample was diluted because one of the compound concentrations exce_eded the
highest concentration range for the standard curve.
J indicates that the reported result is estimated because the result is less than the estimated quantitation limit (EQL).
U indicates that the result was not detected above the method detection limit (MDL).
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3.0 PRELIMINARY SVE PERFORMANCE DATA
Preliminary SVE performance data were generated during the OAT that was conducted at the end
of the Phase I construction of the AS/SVE system. For the OAT, each extraction well was
operated independently for approximately one hour to check instrument performance at the well
and to check for proper relay of information back to the SCADA system. The run time for each
well was dependent on the actual flow achieved and the time required to collect the performance
data from each well. After each extraction well was operated independently, the wells were operated
together for approximately six hours to check overall SVE system performance and to identify any
punch list items that needed to be completed for the system installation to be satisfactory. This
section presents the preliminary SVE performance data for each of the extraction wells operated
individually and the SVE area of influence while operating all ten of the extraction wells. These data
should be considered preliminary because, as the system is operated over a longer period of time, it
is anticipated that some changes will occur such as a possible drying out of the vadose zone which
could change some of the performance data.
3.1 SVE WELL PERFORMANCE DATA
Figure 3-1 presents graphs for each of the extraction wells that show the measured relationship
between applied vacuum [ reported as inches water column (in.W.C.)l and resulting extraction air
flow rates [reported as standard cubic feet per minute (scfm)]. The data for each well were obtained
from readings at the SCADA operator display. During the OAT, each well was operated
independently. In order to obtain the data presented in Figure 3-1, three vacuum set points were
used: approximately 30, 50, and 75 in.W.C. The resulting extracted air flow rates were measured at
each of the applied vacuum set points and these data were used to plot the graphs shown on
Figure 3-1. Due to the heterogeneity of the Site geology, there is a range of flow rates that can be
achieved with the same applied vacuum, depending on the location of the extraction well. For
example, for the maximum applied vacuum of approximately 75 in. W.C. the following flow rates
were measured at the different well locations:
• 16 to 18 scfm for EW-4 and EW-5
• 14 to 16 scfm for EW-1 and EW-2
\\BCNSH03\PROJECI"S\PROJ\1889S\18895.015\SOJ.doc 3-1
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I 80 80 u u S: 60 s: 60
I .!: .E E4o EW-1 E 40 EW-2
:, :, il 20 :, 20 " "' "' > 0 > 0 I 0 2 4 6 8 10 12 14 16 18 20 0 2 4 6 8 10 12 14 16 18 20
Flow Rate, scfm Flow Rate, scfm
I 80 80 cj cj
I s: 60 s: 60
.E .E
E 40 EW-3 E 40 EW-4 :, :, :, 20 :, 20 " " I "' "' > > 0 0
0 2 4 6 8 10 12 14 16 18 20 0 2 4 6 8 10 12 14 16 18 20
I Flow Rate, scfm Flow Rate, scfm
80 80,
I cj cj s: 60 s: 60,
C: .!: -~ 40 E 40. EW-6
:, :,
I :, 20 :, 20 " " "' "' > 0 > 0
0 2 4 6 8 10 12 14 16 18 20 0 2 4 6 8 10 12 14 16 18 20 I Flow Rate, scfm Flow Rate, scfm
80 80 I u u s: 60 s: 60
.E .!:
E 40 EW-7 E 40 EW-8
I :, :, :, 20 :, 20 " " "' "' > 0 > 0
I 0 2 4 6 8 10 12 14 16 18 20 0 2 4 6 8 10 12 14 16 18 20
Flow Rate, scfm Flow Rate, scfm
I 80 80
cj cj s: 60 s: 60 •
.E .!: I E 40 EW-9 E 40 • EW-10
:, :, :, 20 :, 20 " " "' ~ > 0 . . . .
I 0
0 2 4 6 8 10 12 14 16 18 20 0 2 4 6 8 10 12 14 16 18 20
Flow Rate, scfm Flow Rate, scfm
I Figure 3-1. Preliminary Vacuum-Flow Relationships for SVE Extraction Wells
I P:/proj/18895/18895. 015/F0301.xls Page 1 of 1
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• 12 to 13 scfm for EW-8 and EW-9
• 6 scfm for EW-3
• 0 scfm (no measured flow) for EW-6, EW-7, and EW-10.
The vacuum-flow graphs in Figure 3-1 indicate that some of the picot tube flow transmitters could
be out of calibration since the flow curves intersect the y-axis at a vacuum greater than zero
(specifically for EW-3, EW-4, and EW-9). It is possible that air flow was achieved for EW-6, EW-7,
and EW-10 but that the flow could not be measured because of the calibration range of the
mstruments.
3.2 SVE AREA OF INFLUENCE
Figure 3-2 presents an isobar map that shows the measured vacuum data collected at the extraction
wells and monitoring probes after approximately six hours of SVE operation with all of the ten
extraction wells operating. These data give a preliminary indication of the area of influence that can
be expected from the SVE system. The SVE area of influence, as indicated by soil vacuum
measurements of 0.1 in.W.C or greater, appears to extend between the SVE wells and beyond the
monitoring probes with the exception of MP-1, MP-8, and MP-14, which are located some distance
away from the SVE wells.
3.3 EVALUATION OF PRELIMINARY SVE PERFORMANCE DATA
The vacuum and flow data obtained for each SVE well during the OAT provide an indication of the
heterogeneity of pneumatic permeabilities within the vadose zone. This heterogeneity was
previously identified during the AS/SVE pilot test that was conducted during the pre-design
investigation in 1998. Although the instrumentation was calibrated during construction, it is
appropriate to periodically calibrate them as part of the routine system operation and maintenance
(O&M). The routine system O&M is provided in the document entitled "O&M Marual for the Air
Sparging and Soil Vapor Extraction System, FCX-Statesville Superfund Site OU3, &atesville, North
Carolina" dated November 2000. The low flow or non-measurable flows are not anticipated to be
significant to the overall effectiveness of SVE to capture sparge air based on the potential zone of
influence exhibited by the measured vacuum data during the SVE test.
I IBCNSH0JIPROJECTSIPROJ\18895\18895.015\S0J.doc 3 · 2
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/ / Q:' / i I ci / / I o '; "' !;' ,. f
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50 0 50 100
SCALE FEET
N -.. :..4..f---_,,1i-~ -
LEGEND:
~ >S/SVE WELL
EB SVE WELL
T MONITORING PROBE
-,o-VACUUM ISO-BAR (IN.W.C.)
(76.9) MEASURED VACUUM (IN.W.C.)
FIGURE 3-2
VACUUM ISO-BARS
DURING SVE
FCX STATESVILLE SUPERFUND SITE OU3
STATESVILLE, NORTH CAROLINA
18895.015 09/00
BROWN AND
CALDWELL Nashville, Tennessee
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4.0 PHASE I PERFORMANCE TEST PLAN
This section describes the performance test plan for testing the Phase I AS/SVE process and
evaluating its performance. The performance test will consist of operating the SVE system for a
defined period of time followed by operating the combined AS/SVE system for a brief period of
time. Selected data will be collected before, during, and after operation of the process to aid in the
performance evaluation. Figure 4-1 provides a schedule for the testing which includes the operation
schedule for SVE and AS/SVE and the work activities to be conducted before, during, and after
operation of the system. The work activities are as follows:
• Calibrate instrumentation (before operation).
• Conduct source area groundwater sampling and water level measurements
(before, during, and after operation).
• Conduct permeability testing at monitoring probes (before operation).
• Conduct vapor sampling (before and during operation).
• Perform remote monitoring of system (during operation) .
• Perform on-Site monitoring of system (during operation).
• Conduct helium tracer testing (during operation).
As shown in the schedule (Figure 4-1), some of these work act1vmes will be conducted
simultaneously. These activities are described in the following sections. Brown and Caldwell will
conduct the on-Site work in accordance with the Site-specific health and safety plan (HASP) entitled
"Health and Safety Plan for Remedial Action of Operable Unit Three, FCX-Statesville Superfund
Site" dated May 2000 by Brown and Caldwell. This HASP was used during the Phase I
construction.
I IBCNSH03\PROJECTS\PROJl18895\18895.015\SD4.doc 4-1
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Figure 4-1. Schedule for Phase I Performance Test
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Task Name
Operation Schedule
Operate Soil Vapor Extraction System
Operate Air Sparge System
Work Activities
Calibrate Instrumentation
Conduct Source Area Groundwater Smnpling:
Event 1
Event 2
Event 3
Event 4
Conduct Permeabilitv Testing at Monitoring Probes
Conduct Vapor Sampling:
Event 1
Event 2
Event 3
Event 4 .
Event 5
Perform Monitoring of System
Conduct Air Sparging with Helium Tracer Testing
Laboratory Analyses and Data Validation :
Reoortin2
Prepare Phase I Performance Test Report .
Submit Report to USEPA and NCDENR
Start End
Jan/25/01 May/03/01
Jan/25/01 May/03/01
Mar/26/01 Apr/06/01
Dec/04/00 Jul/16/01
Jan/22/01 Jan/24/01
Dec/04/00 Jun/06/01
Dec/04/00 Dec/06/00
Mar/21/01 Mar/23/01
Apr/10/01 Apr/11/01
Jun/04/01 Jun/06/01
Jan/23/01 Jan/24/01
Jan/23/01 May/03/01
Jan/23/01 Jan/26/01
Feb/21/01 Feb/22/01
Mar/21/01 Mar/22/01
Apr/05/01 Apr/06/01
May/02/01 May/03/01
Jan/25/01 May/03/01
Mar/26/01 Apr/06/01
Jan/23/01 Jul/16/01
May/07/01 Au!!:110/01
May/07/01 Aug/10/01
Aug/10/01 Aug/10/01
I Note: Actual start date is dependent upon Agency review and approval of Performance Test Plan.
Duration of operation schedule will be evaluated based on test data. I P:/PROJ/18895.015/SCHED.TLP
I
2000 2001
Dec Jan Feb Mar Apr May
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4.1 CALIBRATE INSTRUMENTATION
Prior to system start-up, the instrumentation will be calibrated or calibration checks will be
performed according to the O&M Manual for the system ("Operation and Maintenance Manual for
the Air Sparging and Soil Vapor Extraction System, FCX-Statesville Superfund Site, Statesville,
North Carolina" dated November 2000 by Brown and Caldwell). The instruments to be calibrated
include the pressure and vacuum gages; pressure, vacuum, and flow transmitters; and in-line gas
analyzers. An overall system checkout will be performed based on the O&M Manual.
4.2 CONDUCT SOURCE AREA GROUNDWATER SAMPLING
Source area groundwater sampling will be conducted before, during, and after the Phase I
performance test to monitor the affects of AS/SVE on the groundwater in the source area. Four
groundwater-sampling events are scheduled as shown in Figure 4-1. Both the extraction wells and
monitoring probes will be sampled. Table 4-1 shows which wells/ probes will be sampled in each
event and which parameters will be measured or analyzed for. For sampling event 2, the selection of
wells to be sampled was based on the results of the OAT and the relationship between the sampling
intervals and the lithology at that sampling location and depth (wells screened substantially below
the water table in regions of apparent low permeability were not considered for sampling event 2).
As sample results are obtained from the early sampling events, the analyte list and wells to be
sampled may be modified. Sampling event 1 will be performed prior to SVE operation.
Groundwater sampling events 2 and 3 will be performed just prior to and just after air sparging,
respectively. Sampling event 4 will be performed approximately two months after air sparging. The
wells/ probes for sampling events 1 and 4 were selected as those most likely to show overall impact
due to AS/SVE. Sampling event 2 will be used to determine if SVE has an effect on groundwater
quality. Sampling event 3 is most critical and will be used to determine the impact of air sparging on
VOC concentrations and natural attenuation in the groundwater. All 25 wells/ probes will be
sampled during event 3. Event 4 will be used to check rebound after AS/SVE shutdown. Only
those wells showing a change from the baseline concentrations following the AS/SVE testing will be
sampled during event 4.
\ \BOJSH0JWROJECTS\rROJ\ 18895\18895.015\S04.doc 4-2
Well ID
Number voes
AS/SVE Well
EW-1/SW-1 X
EW-21SW-2 X
SVE Well
EW-3
EW-4
EW-5
EW-6 X
EW-7
EW-8 X
EW-9
EW-10 X
Monitoring Probe
MP-1
MP-2 X
MP-3
MP-4 X
MP-5 X
MP-6 X
MP-7
MP-8
MP-9 X
MP-10 X
MP-11
MP-12 X
MP-13
MP-14
MP-15 X
l!!!iil -l!i!!!i!J i!l!!!!l -~ l!!!!il ==1
Table 4-1. Source Area Groundwater Sampling Parameters
FCX-Statesville Superfund Site OUJ
Event 1 Event 2• Event 3'
DO, ORP, Fe, Mn, DO, ORP, Fe, Mn, DO, ORP, Fe, Mn,
temp., pH, and temp., pH, and temp., pH, and
and cond. CO2 voes and_cond. CO2 voes and cond. CO2
X X X X X X X
X X X X X X X
X X X X X X
X X X
X X X X X X
X X X X
X X X
X X X X X X X
X X X
X X X X X X X
X X X
X X X X X X X
X X X
X X X X
X X X X X X X
X X X X X X X
X X X
X X X
X X X X
X X X X X X X
X X X
X X X X X X X
X X X
X X X
X X X X X X X
Event 4a
DO, ORP, Fe, Mn,
temp., pH, and
voes and cond. CO2
X X
X X
X X
X X
X X
X X
X X
X X
X X
X X
X X
X X
X X
lliii=l ·=:I
'Sampling parameters and wells selected for sampling may be modified based on results of previous groundwater sampling event(s).
P:/proi/18895/18895.01 5/T0401.Jds Page 1 of 1
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Groundwater samples will be collected following the sampling procedures in the QAPP. Analysis of
the samples either in the field or by the laboratory will be according to methods and procedures
consistent with the ongoing semiannual monitored natural attenuation sampling. Eckenfelder
Laboratory, LLC will conduct the analyses. QA/QC samples will be collected and analyzed for each
sampling event according to the QAPP and using the QA/QC sampling frequency indicated in the
O&M Manual. The voe data will be validated by a third party that specializes in data validation.
Groundwater level measurements will be made during each sampling event and during the air
. . spargmg operauons.
4.3 CONDUCT PERMEABILITY TESTING AT MONITORING PROBES
Prior to start-up of the SVE system, pneumatic permeability tests of the vadose zone will be
conducted at each of the 15 monitoring probes. Since one of the objectives of the Phase I
performance test is to determine if the Phase I AS/SVE system is adequate or if Phase II design and
construction is warranted, one important piece of information is the pneumatic permeability at
locations other than the existing SVE wells. The monitoring probes were installed identically to the
extraction wells with the exception of the piping and instrumentation that connect the extraction
wells to the AS/SVE system. One potential use of the monitoring probes in Phase II, if warranted,
is to convert the probe to an extraction well. Prior to making that decision, it is important to know
the pneumatic permeability of the probes, especially since the preliminary performance data from
the OAT show that there is significant variation in SVE flow due to heterogeneity at the Site.
The pneumatic permeability testing will be conducted by using the existing SVE blower system to
extract air from a given monitoring probe. A length of PVC pipe that has a picot tube with
differential pressure gauge, a thermocouple, a vacuum gauge, and a sample port mounted on it, will
be attached to a monitoring probe. A flexible vacuum hose will be connected from the PVC piping
to one of the spare flange locations on the main 6-inch SVE header pipe. The permeability test will
be conducted by setting the vacuum at the blower at three different points (30, 50, and 75 in.W.C.)
and measuring the resulting flow rates. At the highest vacuum set point, the neighboring extraction
wells and monitoring probes will be checked for vacuum influence. Vapor samples for voe
analysis will also be collected from each monitoring probe during the permeability test as described
in Section 4 .4.
I IBCNSH0JIPROJECTSIPROJ\18895\18895.015\SO-l.doc 4-3
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4.4 CONDUCT VAPOR SAMPLING
Five vapor sampling events are scheduled as part of the Phase I performance test. These events are
shown in Figure 4-1. The samples will be collected following the same procedure and QA/QC
sampling type and frequency as was used during the OAT (see Section 2.3). The samples will be
analyzed for VOCs by Eckenfelder Laboratory, LLC using USEP A method 8260.
Sampling event 1 consists of sampling the monitoring probes, the extraction wells, the SVE blower
inlet, and the midpoint between the two GAC vessels. Nine of the monitoring probes, primarily
along the perimeter of the source area, will be sampled for VOCs during the permeability testing
prior to the start-up of the SVE system. These probes are MP-1,-3, -4, -7, -8, -9, -12, -13, and -14.
As the permeability testing is performed, the probe sample locations may be revised based on the
extracted air flow rates achievable. Immediately after start-up of the SVE system, vapor samples will
be collected from each extraction well, the SVE blower inlet, and the midpoint between the two
GAC vessels. After approximately one month of SVE operation, sampling event 2 will be
conducted to collect vapor samples from the extraction wells, the SVE blower inlet, and the
midpoint between the two GAC vessels. The same locations will be sampled during sampling
event 3 just prior to the initiation of air sparging and during sampling' event 4 during air sparging.
Sampling event 5 will be conducted at the end of SVE operation approximately one month after air
sparging. For sampling event 5, the extraction wells, the SVE blower inlet, and the midpoint
between the two GAC vessels will be sampled as weH as the same monitoring probes that were
sampled in sampling event 1. An estimated 55 vapor samples will be collected and analyzed for
VOCs as part of the Phase I performance test.
In addition to vapor samples collected for laboratory analysis, vapor samples will also be collected
and evaluated on-Site using Draeger tubes specific for PCE. As laboratory analytical data are
available, the Draeger tube results will be compared with the laboratory data to check for correlation
between the PCE results. If the results correlate reasonably well, Draeger tubes will be used to
monitor concentration of PCE in the system.
\ \BCNSH03\PROJECTS\PROJ\18895\18895.015\S04.doc 4-4
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4.5 PERFORM MONITORING OF lHE SYSTEM
Monitoring of the system will be performed when the system is operating. On-Site monitoring of
the system will be performed during three on-Site events of two days duration each as shown on
Figure 4-1. These visits will be used to inspect the SVE system, make adjustments if required, and
to collect vapor samples as scheduled. The system data will be checked to monitor system
performance and allow for response to any system operating problems that might occur.
Adjustments to system parameters such as applied vacuum will be performed as necessary during
these events. Personnel will be on-Site during operation of the air sparging system.
Remote off-Site monitoring will be performed when the system is not manned. The remote-dial
feature of the SCADA system allows monitoring and control from a remote computer location. The
remote monitoring will be performed during the operation of SVE; personnel will be on-Site during
operation of air sparging, The system data will be checked a minimum of three times per week to
monitor system performance and allow for response to any system operating problems that might
occur,
4.6 CONDUCT AIR SPARGING WilH HELIUM TRACER TESTING
The air sparging test will be conducted over a two week period and SVE will be performed
continuously during the test as well as for approximately one month after the air sparging has ended,
During operation of the air sparging system, helium tracer tests will be performed with each of the
two air sparging wells. The purpose of the helium tracer test is to track (or trace) the transport of
sparged air from the groundwater sparge point to the vadose zone, This will help determine the
overall success of capture of sparged air by the SVE system. The helium tracer test will be
conducted by injecting a measured quantity of helium into the sparge air stream for a short period of
time. The helium flow into the sparge air will only be a "short pulse" in the overall stream of sparge
air, A portable helium gas monitor will be used to check for the presence of helium at the SVE
extraction wells and at the monitoring probes. Both helium concentration and time of travel will be
recorded as the data are collected.
\ \BGISH0J\PROJECTS\PROJ\18895\18895.015\S04.doc 4-5
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The helium tracer test will be performed at EW-1/SW-1 first with no sparging at EW-2/SW-2. On
the day that air sparging is begun, helium will be injected into the sparge well SW-1 for a short time
and then the sparging will be continued for approximately two days while monitoring for helium at
the extraction wells and monitoring probes. Other performance data such as the vacuum at each
monitoring probe will also be recorded to check on the potential changes due to air sparging. After
the helium concentrations have dissipated in the vadose zone, the helium test will be repeated for
EW-2/SW-2 with no sparging at EW-1/SW-l.
After the second helium test is completed, both sparge wells will be run simultaneously to check on
the overall effect on the system. The vacuum at each monitoring probe will be checked during this
time. Both sparge wells will be operated for approximately four days and then turned off with SVE
still operating. As described in Section 4.4, vapor samples will be collected from the extraction
wells, the SVE blower inlet, and the midpoint between the two GAC vessels during air sparging with
both sparge wells and while SVE is operating. The SVE system will be shut down approximately
one month after air sparging is discontinued. Two months after the air sparging, groundwater
samples will be collected as described in Section 4.2.
\ \BCNSH03\PROJECTS\PROJ\ 18895\ 18895.015\S04.doc 4-6
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5.0 REPORTING
The Phase I Performance Test report, as described in the RA Work Plan, will include the following:
• Presentation and evaluation of results of the Phase I source area groundwater sampling
(4 sets of data). This evaluation will include a review of the data for natural attenuation
indicators.
• Presentation and evaluation of results of the Phase I source area vapor sampling
(5 sets of data).
• Presentation and evaluation of results of the heliwn tracer test.
• A summary of the Phase I test results including tabulated pressure and flow measurements,
radii of influence, and estimated mass removal of VCX:::s from the SVE wells.
• Conclusions and recommendations from the Phase I test such as the need for adjustment
of operating parameters or the need for implementation of Phase II design and
construction.
\ \BCNSH0J\PROJECTS\PROJ\18895\18895.015\S05.doc 5-1
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APPENDIXA
GROUNDWATER VOCANALYTICALLABORATORYREPORTS
'\ '\BCNSH03\PROJECTS'\PROJ'\18895\ I88!Hi.0 15\APPcvr .doc
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2. >
ORGANIC SUMMARY DATA PACKAGE
PRE-DESIGN INVESTIGATION
OPERABLE UNIT THREE (OU3)
FCX-STATESVILLE SUPERFUND SITE
Prepared for:
EL PASO ENERGY CORPORATION
1001 Louisiana Street
Houston, Texas 77002
Prepared by:
Eckenfelder Laboratory, LLC
227 French Landing Drive
Nashville, Tennessee 37228
August 7, 2000
Manager
John H. C nsidder, Organic Laboratory Manager
K:\2000Reporu\FCX\TOCSUM06137.doc
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Table of Contents
Case Narrative
Chain of Custody
Cooler Receipt Forms
Parameters Requested
Data Summary Reports
Summary Forms
TABLE OF CONTENTS
Internal Standard Summary Forms
Jt\2000Reports\FCX\TOCSUM06137.doc
Page No.
1
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ORGANIC CASE NARRATIVE
El Paso Energy #60313.006
Work Orders
0006137,0006144,0007001
•1 COOOl
GC/MS Volatiles Method: The samples were analyzed by USEPA Contract
Laboratory Program Statement of Work (CLP SOW) for Organics Low
Concentration Water Method OLC03.2(5ml purge and trap followed by capillary
column GC/MS).
Volatiles Comments: The volatile analyses were completed and satisfactorily met
method requirements with the following exceptions:
• The method indicates an internal standard mixture contalillilg
1,4-dichlorobenzene-d4, chlorobenzene-d5 and 1,4-difluorobenzene. The
internal standard mixture used contained fluorobenzene and pentafluorobenzene
in place of 1,4-difluorobenzene.
• The method indicates a system monitoring compounds of 1,2-dichloroethane-
d4, toluene-dB and p-bromofluorobenzene. System monitoring compound
(SMC) of dibromofluorobenzene was used in addition. No flags were applied
to the data based on this additional SMC.
• The trap used for analysis of the samples was a VOCARB 3000 packed with
10cm Carbopack B, 6 cm Carboxen 1000 and 1 cm Carboxen 1001.
• The 07 /03/00 initial calibration curve for the compounds bromoform,
bromodichloromethane and trans-1,3-dichlorpropene exceeded the allowed
20.5% relative standard deviation (RSD) at 21.2%, 32.0%, and 20.6% RSD,
respectively. Two compounds are allowed to exceed 20.5% RSD within a
calibration curve. These compounds were not detected in any of the samples.
• Calibration points for tetrachlorethene ·. were added to the 07 /03/00 initial
calibration curve at 500 ug/L and 1000 ug/L.
• The SMC 1,2-dichloroethane-d4 exceeded upper recovery limit of 114% for
several samples. These samples were not flagged due to minimal effect on the
sample results.
K:\2000Reports\FCX\ocn0006137.doc
Eckenfelder Laboratory, LLC Chain of Custody Record
Send Results to:
Name--&t""-'&,=M"-"'-'-----
Company -1-/36"""'~-'------Address _· ___ ...;_ ___ _
City & State _______ _
Phone
Fax-,----,---,-----,.,----
Sample
Matrix
STOl<.A6C lAtJK..
Send Invoice To: '
Name
Company
Address
City & State
Phone
Purchase Order .
atnre •
Cond.
\JfXJ.
Date/fime REMARKS
6-/'fc,JJ
:l:l)
• Signature required to ensure validity
-
N~ ._ 214 97
Details:
Page_/_of__l_
Cooler No. -/-of_/_
Date Shipped '2 / z 'l--lNl
Shipped By . '
Turnaround
(Std. turn unless noted otherwise/There
may be a surcharlle for RUSH-contact Lab)
- - - -
/&'i9S,0/2
Time
by: (Signature)
-- - - - - - - -·-· Eckenfelder Laboratory, LLC Chain of Custody Record
Send Results to: Send Invoice To:
Name KeAJ ONA Name __________ _
Company ~/3~~=----'------Company -------~-Address _________ _ Address ________ _
City & State _______ _ City & State _______ _
Phone _________ _ Phone -----------Fax ___________ _ Purchase Order
R!X &U3
O>mpJ
Grab
Sample Location/Description
£ -5
MP-9
MP-14
MP-10
Date/fimc Received By: (Signature)
Sample
Matrix
GW
tJPr
REMARKS
110
• Signature required to ensure validity
.. ----N~ _ 21498
Details:
Page_/_ of _j_
Cooler No. / of /
Date Shipped(,,/ 2 WO:
Shipped By_·_• ____ _
Turnaround ----,-----
(Std. tum unless noted otherwise/There
may be a suicharr,e for RUSH-contact Lab)
•·. Send ResuUs 11>:
Name~l{~~~/J_'~0~"1~A~---
O>mpany __._8_,_,_{_.,_1 , ____ _
Address ----------C ii y & Stale ________ _
Phone ----------Fax ------------
Sample Location/Description Sample
Malrix
Send Invoice To:
Name ----------
Company ---------
Address ----------C il y & State _______ _
Phone ------~----
Purchase Order
Som lei.,; (SI •nature •
Field Field
Cond.
Detnils:
Pogt _/_ <,i _J_
Cooler No. _L of /
Dale Shipped 4 3()(=(.J(=J __ _
Shipped By /.L,t,._,l'.f'-'· ____ _
Turnaround --------
(Std. turn unless uoleJ othcrwisc/rl1crc
may be a surcharge for RlJSll-cout:u:l Lab)
-----+----+-----+------------+-----t-----t-----+------,----------+---1•
REMARKS
• Signature required lo ensure validity
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ECKENFELDER INC~
COOLER RECEIPT FOR,v(
t1--UP "1 C · c O &:.
USE OTHE.~ s:oe er 7"H!S trJR..',f 70 ,vc-:-:: ':JF:7".-1.Jl..S .J..J'JDtCR COMP!..27'Z A COR.R.ZC7'[V"E: ACTfCN CCNCZ.9...'ffNG CF..EC:<-iN ?RCSC..Z.',fS.
A. PRELlML'lA.."-Y EX.-\..\lI:'iAT!Oci PHASE:
by (?rlntl _ _;:{-:..,-:-/"'a'-'<-=;7e---1./--,;_,,.::..,_~_,2'-'i~f--'-+-..:i..,.=---------"lsignl _______________ _
I I
CA,E CCOLE:c( OPSNEC:(,-Zf"~ C-or-C Number Zl"-/'17
1. Did cooler come With a shipping: slliJ {air bUl. etc.)? _________________ @ NO
If YES. enter carrier Name & air blil number here: £-?(-Ex -#= Jl'lf 3 "i:(,,'{ 71:Z, I
2. Were: C'.!Stody seals on outside of cooler? _____________________ ·€> :-re
How many & where: 'Z. • C-;-J , soal date __ {,,=._·_,-Z,:;..:-Z..:;_-_-_0_, seal name ,/. t/,,</4'7
3. Were custody seals unbroken and lntact at the date and tlme o( arrtval? _________ @ NO
4. Did you screen samples for radtoacttvl.ty uslng the Gelger Counter? _________ _ Y--a.S ®
NO 5. Were custody papers sealed L, a plastic bag & taped Inside to the Hd? ________ _ I 6. Were custody papers filled out properly (Ink. signed, etc.)? _____________ _
@
© NO
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7. Did you sign C'.lstody papers tn the approprtate place? _______________ '-" y:=-NO
8. Was project lde~tlfiable from custody papers? l( yes, enter project name at the top or th.ts ror.n . .G::) NO
9. 1f requlred, was enough ice used? ________ Type of lce: ____ Ter.ip 7.-oc __ . ~ NO
lO. Have designated person lnltlal here to acknowledge receipt of cooler: ~ (date! 4,--z:;-.o-,,
B. LOG-IN PHASE: Date samples were !ogge<.I ln:_~4,---=z_'-'G,=---=='----,---------.------
by (prlnt)_~/)_. --'f'-"-'-1·=c-k=_,.;._ ____ --'(slgnl,_.L/h:::.L....i:::...c0°"'"""'--L../2,=-,2,;....b/='-'-----,-
l l. Describe type or pack~1g In cooler:_6t..t.£i<=/4<:.:/..,.:?:.....i.k>?=<::..:'f,=t', ... , .....J.~=-;t-· ~-j:1-<K=-&=. =---------
.12. Were all bottles scaled In separate plastic bags? __________________ @ NO
'13. Did a.II bottles a:rrtve unbroken & were labels In guv<l condition? ____________ @. NO
14.-Vb:.re all b<?ttle label's complete OD, date,· Ume, signature, preservative, ·etc.)? @> NO
15. Did ail bottle labels agree wlth custody papers? e) NO
16. Were correct containers used for the tests Indicated? ________________ ~ NO
17. Were corrt:cl preservatives added to samples? ___________________ @ NO
·-18. Was a sufficient amount of sample sent for tests Indicated ______________ @ NO
19. Wore bubble~ absent In volatile samples? If NO, list by Sample~ (!!:> NO
20. Was the project mann-:t~r c:.i.lled and status d\scusse<l? 1rr:s. g\ve c!ctalls or. the ~ck or this Car.-;,, Y-:..3 . . .
21. \.Viio ·...-:-cs -:::.!!-:-c!? _______________ 3y •.••hom? ___________ (C:ate), ____ _
LII.CC\SiCOtCCOLDOC
~~----~-·:+~ CCCGG
ECKENFELDER INC~
COOLER RECEIPT FOR.\!
PROJECT:~ft!._-_f.J_,;_l_. _(._,-_-_c_v._)'--#-/~8~"8~~ .... S:~--o_,'--z_· _· ______ LIMS# oc:c"'l9 <1-e 1--=t-c 7
us;;; OTHER SIDE: OF" THIS FORM TO NOTE DE:TAII..S AND /OR COMPLETE A COR!~.ECT!VE:"ACTION CONCERNING CHECK-1..'1 PROBLEMS.
A. PREL.IML'IARY EXA.'dli'IATION PHASE:
by (print) '1 . tlo-....Y?
1. Did cooler come With a shipping sllp (alr bill. etc.)? __ -t,'-------------g) NO
lfYES·, enter carrier Name & alr ·biU _number here:...;r◄c.....:=--=-'-'---'--:-'"3'--)'-<,:-,g=-;'-"j..,i,:...<J.,_,7c,/.:..l_:"2=---'-""
2. W~re cus.tody-sea!s on outside or cooler? ____________________ ® NO
How many & where: ___ L_-_L_;---'eP'-'-----• seal date (, -Z. 3-0 o seal name J:, fd...._sJ,IV(
3. Wer_e custody seals unbroken and intact at the date and time of arrival? _______ ~@ NO
4. Did you screen samples for radloactMty using the Geiger Counter? __________ Y-c.S ~
5. Were custody papers sealed in a plastic.bag & taped inside to the lid? _________ . us) NO
s: Were custody papers filled out properly (Ink. signed. etc.)? G · NO
7. Did you sign custody papers ln the approprlate place? ______________ .._@_..r NO
8. Was project lde~tlfiable from custody papers? If yes, enter project name at the_ top of this form_~ NO
9. !{required, was enough Ice used? · · Type or Ice:;~ Tem~-l·c __ :@ NO
l 0. Have designated person initial here to acknowledge receipt or cooler: p(,--(date) C,. Z-{, -oo '
B, LOG-IN PHASE: Date samples were logged ln:.__,?"--'~c...::Z;.:(.,:.....--";;;_;-0;;_-,,r-------------
by (printJ, _ __,_6.,;.,...-..... /l,=1-',.:.r/c..,~===<-------'(slgn) &-::.5 d-, J
11. D.escrlbe type or pa~klng In cooler:_,J,,,,...,..,/1,=-'£.,...._,,..,.1-c,"-'""'J/L~I-' _,'7=-=-p'-ri?.e,.J><....,t...:·==~---------
12. Were.all bottles sealed In separate plastic bags? __________ _,-,-----@ NO
13. Did all bottles arrh·e unbroken & were labels In gwd condition? __________ _, ~ NO
14. Were-all bottle labels complete (ID, date, time, signature, preservative, etc.)? _____ _ ® NO
15. Did all bottle labels agree with custody papers? ________________ -,c;::,, NO
16. Were conect containers used Cor the._tests Indicated?_·_· _____________ _ r@ NO
($) 17'. Were correcl preservatives added to samples? _________ _, _______ _ NO
18. Was a sufficient amount of sar~ple sent fC?r tests\ndlcated _____________ ~ NO
19. Were bubbles absent In volatile samples? If NO, list by Sample_# __________ ® NO
20. Was the project manng~r c:.i.Ued and st::i.tus diScussed? If :,·cs. give dctalls on the b.."'lck of thts form Y-~ @
2 l. \Vho ·.v:i.s C;:!.!!~cl? ______________ ay -.vhom? __________ ,(C:ate) ____ _
L:\I..CCI:-r\COECOOI...DOC
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~~
ECKENt-t:LDER INC~
COOL:::?-P2C:::l?T FOR.!,f
LIMS# 0::c,7 ccf .. lO I -, -c S-
use: OTHE'~ SiD~ CF' 7':-:rs ?()p_•,< :-o N07'Z Oc7'A1LS AND/OR COMPr..z:-:,; A COR.R.ZW1V~ ACTlCN CONCZR.N[NG C.''-:ZCK-iN ?,q_CBC..Z.',IS.
A. PRELIMINARY EXA .. ,J:INATION ?:'--I.SE: DA,E COOLER OPSNE:D: 7-1-oc C-of-C Number 7 ''(qt;
by (pr:ntl __ _,,J_,_ . ....1..t.Lcl 0"-!...i!c.c5z:\',._ _______ .......c(slgr.) ______________ _
1. Did cooler come With a shipping sU;:, (a.!r blll. etc.)? _________________ @ NC
If YES, enter carr1er Name & alr blU :,umber here: Fy-£ X .H' ){I 1./ 'l) 'i'li <.I 701< \,
2. Were custody seals on outside orc::ioler? _____________________ YES NO
How many & whe.re: __ z._ .. _(.....;,-...;do...----· seal date __ /cc..·_--'-}-'o'--....,:,-,:;~·--,, seal n~e A:. J/'4<: k.J!./
3. Were custody seals unbroken a.."1d lntact at the date and ttme of a.rrtval? ________ __.@ NO
4. Did you screen samples for rad!oactlvtty ustng the Gelger Counter?~---------Y-w €)
5. Were custody papers sealed l.n a plastic bag & taped lns\de to the lid? ________ _ e) NO I s·. Wer_e custody papers ulled out properly (Ink. slgned, etc.]? _____________ _ @ NO
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7. Did you sign c•.1stody papers ln the appropr!ate place? ______________ _ § NO .
8. Was project lcie~tlf12.b\e from custody papers? lfyes, enter project nar.ie at the tcp·orthls ror.n.@ NO . . . ), "91, d ,,--._,· 9. lf requ1r:d, was enough ice used? ________ Type of lee: '--1 ¼ Temp Z. ,'1°C __ ~ NO
10. Have designated person lnitlal here to acknowledge r-:c:tpt of cooler:_~6z:-..;,.<~~--(date) 7-J-ao
B. LOG.IN PH.ASE: Date samples were logged !n:_~-~---"(J'-a ________________ _
by (prlnt] __ ""/3'-'_'-..t./?_,"'-'-',-~s::La-==::::../...._ ____ __,(slgn],_-4~=="'--'/4,'--"-"-'-c;""L'-'-"'.....,/2'--· __
l l. Describe type of packlng In cooler:....,.&-,=,.,,.,e,i,:..f"""t'-.. l"'H"-1:.C='"'wo,.,__...&.="'!"-"'5,-<<'--",~-"bC....:""--------/' =,,-,
12. Were all bottles sealed ln separate plastic bags? __________________ :tp NO
13 .. Did all bottles arrtve unbroken & were labels In gvv<l. condition? @ NO
l~-~#ere all b~ttle-labcls complete (ID, date, time, signature, preservative, etc.}? @ NO
15: ·Dtd·· .tll bo_ttle labels agree w\th cu.:stody papers? @ NO
16'. W~,re_co_rrect containers used for the tests Indicated? ~ NO
1 T-: W.ere corn~·cl preservatives added to samp\es? ___________________ W NO
' _18. Was a su·fficlent amount of sample. sent ror tesls Indicated ______________ (@ NO
·. rn. Were bubbled absent In volatile samples? If NO, 11st by Sample~ (S) NO
• 20. Was the p.roj=ct manug~=-ca.lied and st.it us discussed? Jr :,:i:s. g1·.-.: CetaUs on lhe c.,ck o( u:is (o:-m Y-:.S
21. \\'i10 ·.v;;,.s :::~t!~ct? _______________ 8y •.vham? ___________ (C.ite) ____ _
L: \ L::IG l:'i\ CO ECOO l..OOC
Laboratory
Sample ID
0006137-01
0006137-02
0006137-03
0006137-04
0006137-05
0006137-06
Brown & Caldwell (WM, WW, HYD)
Parameters Requested
Client Matrix Date and Time Parameters
Field ID Sampled Requested
EW-8 Groundwater 6/21/2000 2:15:00 PM VOA 8260A (Water)
EW-7 Groundwater 6/21/2000 2:30:00 PM VOA 8260A (Water)
EW-2 Groundwater 6/22/2000 3:15:00 PM VOA 8260A (Water)
EW-6 Groundwater 6/22/2000 3 :25 :00 PM VOA 8260A (Water)
Trip Blank #1625 Groundwater 6/21/2000 VOA 8260A (Water)
Storage Blank Groundwater 6/23/2000 VOA 8260A (Water)
"
Page 1 of!
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I Brown & Caldwell (WM, WW, HYD)
I Parameters Requested
I Laboratory
Sample ID
Client Matrix Date and Time Parameters
Field ID Sampled Reqnested
I 0006144-01
0006144-02
EW-5 Groundwater 6/23/2000 3:35:00 PM VOA 8260A (Water)
MP-9 Groundwater 6/23/2000 3:55:00 PM VOA 8260A (Water)
I 0006144-03 MP-14 Groundwater 6/23/2000 3:45:00 PM VOA 8260A (Water)
0006144-04 I 0006144-05
MP-10 Groundwater 6/23/2000 3:25:00 PM VOA 8260A (Water)
. MP-8 Groundwater 6/23/2000 4:30:00 PM VOA 8260A (Water)
I 0006144-06 Trip Blank #1626 Groundwater 6/23/2000 VOA 8260A (Water)
0006144-07 Storage Blank 062 Aqueous 6/26/2000 VOA 8260A (Water)
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Page 1 of!
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Laboratory
Sample ID
0007001-01
0007001-02
0007001-03
0007001-04
0007001-05
Brown & Caldwell (WM, WW, HYD)
Parameters Requested
Client Matrix Date and Time Parameters
Field ID Sampled Requested
EW-3 Groundwater 6/30/2000 2:25:00 PM VOA 8260A (Water)
EW-3 dupe Groundwater 6/30/2000 2:25:00 PM VOA 8260A (Water)
EW-4 Groundwater 6/30/2000 2:40:00 PM VOA 8260A (Water)
EW-1/ SW-I Groundwater 6/30/2000 2:50:00 PM VOA 8260A (Water)
Trip Blank #1616 Groundwater 6/30/2000 VOA 8260A (Water)
00010
Pagel of!
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Client: FCX.#18895.006
Date Reported: 07/13/00
Eckenfelder
Laboratory, LLC
' ·~-~->':'-'
r : ........ ~ .,
..i. ...
I ECKENFELDER SAMPLE NUMBER I V1BLK0704 10006137-0iDI0006137-02D]0006137-03D]0006137-04DI
1----------------------------------------------1-----------1-----------1-----------1-----------1-----------1
I DATE SAMPLED I NA I 06/01/00 I. 05/21/00 I 06/22/00 \ 06/22/00 \
\ DATE RECEIVED \ NA I 06/23/00 \ 05/23/00 \ 06/23/00 I 06/23/00 I
\ DATE ANALYZED I 07/04/00 I 07/04/00 I 07/04/00 \ 07/05/00 \ 07/04/00 I
I----------------------------------------------I-----------I----------.l-----------1-----------\-----------I
I . \ M.BLANK \ EW-8 \ EW-7 I EW-2 \ EW-6 I
I CLIENT SAMPLE DESCRIPr!ON I \· . I I I I
I I I I I I • I
· 1----------------------------------------------I-----------I-----------I-----------I----------1-----------1
I VO!ATILE ORGANICS \ \ I \ 5.0 X(l) I 10 X(l) I 100 X(l) \ 5.0 X(l) I
\ BY USEPA CLP sow OLM03 . 2 \ MDL \ EQL \ CO>IC \ CO>IC \ CO>IC \ CO>IC I CONC I
1----------------------------------------------1-----------1-----------1-----------1-----------1-----------1
\ Acatcne -I 5.0 \· SO \< 5.0 \< 25 D\< SO □I< 500 DI 35 JOI
I Banzene I 1.0 I 10 I< 1.0 I< S.O D\< .10 DI< 100 DI< s.o DI
[ Brcmcdicb..lorcmathane 1 1.0 [ 10 I< 1.0 I< 5.0 D[< 10 DI< 100 DI< S.O DI
\ Bromoform · I 1.0 \ 10. \< LO \< s.o DJ< 10 D\< 100 □I< s.o □I
] 8rotnQ't[l8thene I 2.0 ] 20 J< 2.0 I< 10 DJ< 20 DI< J.oo· D[< 10 DI
I 2-Butanona J 10 I 100 I<. to l< so D[< 100 DI<_ 1000 D]< so DI
\ carbon disulfida I 1.0 \ 10 \< 1.0 \< s.o □I< 10 □I< 100 DI< s.o c\
\ carbon totracblorlda \ 1.0 I 10 I< 1.0 \ 6.4 JOI 10 JD\ 130 JD\ 11 JD\
I Cblorobonzane \ l.O· I 10 I< 1.0 \< 5.0 DI< 10 D\< 100 D]< 5.0 DI
\ Cbloroatbana I :2.0 I 20 ]<-2.0 I< 10 DI< 20 DI< 200 D[< 10 DI
\ _ Chloroform \ LO I 10 \< 1.0 \< · 5.0 DI< 10 D\< 100 DI< 5.0 DI
[ Chlorcmethena I 2.0 I 20. I< 2.0 I< 10 DI< 20 DI< 200 DJ< 10 DI
I Dibrcroochlorcmetbane I l.O I ·10 I< 1.0 I< 5.0 DI< 10 DI< 100 DI< 5,0 DJ
\ 1,1-Dichloroathana I 1.0 I 10 I< 1.0 I< 5.0 D[< 10 D\< 100 DI< 5.0 D[
I 1,2-Dichlqro•thane I 1.0 I 10 I< 1.0 [< 5.0 DI< 10 .DI< 100 DI< s.o DI.
\ 1,1-Dicbloroathene \ LO \ 10 I< 1.0 \< s.o D\< 10 DJ< 100 _. _01:_._: S.l .ic\
I cis-1,2-Dichloroethena I LO I 10: I< 1.0 I. 160 · · .. D\< _10 Dj 110 JD[< s.o c[-
1 trana..::1,2-01chloroathene I 1.0 I 10 ]< 1.0 I< ·5.0 DI< 10 DI< 100 DI< 5.o DI
I 1,2-Dicbloropropane \ 1.0 \ 10 \< LO \ 11 JD\<.10 -DJ< 100 DI< s.o D\
I cis-1,3-Dichlorcpropane I 1.0 I 10 I< 1.0 I< 5.0 D/< 10 Di< 100 DI< 5.0 D[
I tr=e-1,3-Dicbloropropana I 1.0 \ 10 I<-1.0 \< s.o _ DI< 10 D\< 100 D\< s.o D\ \ ____________ _c _______________ l
ALL OJMPOtJNDS EAPRESSED IN MICROGRAMS/LITER UNLESS_ OTHERWISE NOTED.
ALL NON-DETECT VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLEcr DILtrrIONS/SAMPLE VOLUME).
SEE ATIACHED PAGE FOR DEFINITIONS OF TERMS AND. QUALIFIERS.
(1) • SAMPLES WERE DILUTED BY THE NUMERICAL VALUE DISPLAYED.
·DETECTION LIMITS HAVE BEEN INCREASED BY THE. SAME FAcroR •
.. • SOME ASPECT OF QTJ1!.LITY CONTROL WAS NOT WITHIN LIMITS,
RESULTS SHOULD BE CONSIDERED AS ESI'IMATED.
227 French Landing Drive Nashville, Tennessee 37228 615-345-1115 FAX [phone]
-.-.. :•.~.
Ecken.fe1der Laboratory, LLC
Client: FCX #18895.006
Date Reported: 07/13/00
t· i" •" ~ ~, vv·v-t.,,
I ECKENFELDER SAMPLE NUMBER \ VlBLK0704 100061~7-0lD[0006137-02DI0006137-03Dj0006137-04D[
1----------------------------------------------1-----------1-----------1-----------1-----------1-----------1
I DATE SAMPLED I . NA I 06/21/00 I 06/21/00 I 06/22/00 I. 06/22/00 I
I DATE RECEIVED I NA I 06/23/00 I 06/23/00 I 06/23/00 J 06/23/00 I
I DATE ANALYZEO i 07/04/00 I 07/04/00 I 07/04/00 I 07/05/00 J 07/04/00 J
1-------------------.--·-----------------------1 ----------I-----------I-----------I-----------I-----------I
1· I M.BIJINK I EW-8 I EW-7 I EW-2 I EW-6 I
I CLIENT SAMPLE DESCRIPTION I I I I I I
I I I I I I • I
1--------------------------------· -----------·-1-----------1-----------1-----------1-----------1-----------1
I VOIATILE ORGANICS I I [ I 5.0 X(l) I 10 X(l) I 100 X(l) I 5.0 X(l) I
I BY USEPA CLP sow OLM03 • 2 I MDL I ECIL I CONC I CONC I CONC I CONC I CONC I
1----------------------------------------------1-----------1-------. ---1-----------1-----------1 ____ . ---. --1
I Ethyl.benzene 1. l.O ] 10 I< 1.0 I< s.o' DI< 10 DI< 100 D]< s.o DI
I 2-Hoxanone I 2.0 I 20 I< 2.0 I< 10 DI< 20 DI< 200 DI< 10 DI
I ·Mechylene ~orlda I 1.0 I 10 · I< 1.0 I< S.O D[< 10 DI< 100 D[< s.o DI
I 4-Methyl-2-pantanone l 2.0 I 20 [< 2.0 · I< 10 D[< 20 DI< 200 D[< 10 DI
·1 Styrene I 1.0 I 10 I< 1.0 I< 5.0. DI< 10 DI< 100 DI< 5.0 DI
] 1,1,::2,2-Tetrachloroethane ·I l.O [ ·10 I< 1.0 I< S.O D\< 10 D[< 100 DJ< S.O DI
I Tetrachloroethene 1 1.0 I 10 \< 1.0 I 3400 DI 1400 DI 52000 DI 640 DI
I Toluane I 1.0 I 10 I< 1.0 I 11 JDJ< 10 DI< 100 DI< 5.0 DI
I 1,1,1-Trtchloroethanit I l.O · I 10 I< l.O I< s.o D\< 10 D[< 100 DJ< s.o D\
I 1,1.,2-Trichlo_roethane I 1.0 I 10 I< 1.0 l< 5.0 DI< 10 DI< 100 D[< 5.0 DI
I Trichloroethane I· 1.0 I 10 I< 1.0 I 70 DI< 10 DI< 100 DI< 5.0 D[
I Vinyl·chloride I 2.0 I 20 I< 2.0 I< 10 DI< 20· DI< 200 DI< 10 Di
I X.ylena(total) I. 1.0 I 10 \"< LO 1.< 5.0 DI< 10 DI< 100 D[< 5.0 DI I _________________________________ _,
ALL COMPOUNDS EXPRESSED IN MICROGRAMS/LITER UNLESS OTHERWISE NOTED.
ALL NON-DETECT VALUES ARE REPORTED-AS <MDL (OODIFIED TO REFLECT DILurIONS/SAMPLE VOLUME) ,
SEE ATTACHED PAGE FOR DEFINITIONS di TERMS:AND OUALiFIERS,
{l) • SAMPLES WERE DILUTED BY THE NUMERICAL VALUE DI SPLAYED.
DETECTION LIMITS HAVE BEEN INCREASED BY TRE SAME FACTOR,
• -so~ ASPECT OF Qtn\LITY CONTROL WAS NOT WITHIN LIMITS,
RESULTS SHOULD BE CONSIDERED AS ESiIMATED.
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.. -.
Eckenfelder Laboratory, LLC
Client: FCX #18895.006
Date Reported: 07/13/00
I ECKENFELlJER SAMPLE NUMBER I 0005137-05 I
l··---------------.----------------------------1-----------I.
I DATE SAMPLED I 06/21/00 I
I DATE RECEIVED I 06/23/00 I
I· DATE ANALTIED I 07/04/00 ·1
1------------------------------.------------. --!---------· -I
I I Trip Blank!
I CLIENT SAMPLE DESCRI!'rION I #1.6:is I
I I I
!-·-----·---------------------c.·-------------1-----------1 I VOlATILE ORGANICS I I. I I
I BY USEPA CLP sow OLM03 • 2 I MDL I EQL 1. C:ONC I
1--------------------------------------~ ------!-----------, I Acetone I s.o j so I< 5.0 j
j Benzene I 1. O I 10 I< · 1. 0 I
j Bromcdichloromethane j 1.0 I 10 I< 1.0 I
I Bromcform 1 · 1.0 I 10 I.< 1.0 I
I Brcmcmathane I 2.0 I 20 I< 2.0 I
j 2-Butanona I 10. I 100 I< 10 I
I carbon disulfide I 1.0 1. 10 I< 1.0 I
I Carbon tetrachloride I l.O I 10 I< LO ·I
j Chlorobonzene j 1.0 j 10 [< 1.0 I
[ Chloroothone j 2.0 [ 20 I< 2.0 I
·I Chloroform [ 1.0 ·1 10 I< LO I
[ Chloromothane I 2.0 j 20 I< 2.0 I
I Dibromochlorcmathan8 I l. o I 10 I< l. o I .
I 1,1-Dichloroethane I l.O I 10 I< 1.0-I
1 · 1,2-Dichloroethane I l.O I 10 ·I<. l.O \
I 1,"1-01chioroethane · I l.O I 10 I< : 1.0 I
I cis-1,2-0ichloroathene I 1.0 _I 10 i<. 1.0 I
I trans-1,:l-Dichloroethene I l.O I· 10 J< l.O \ ·
j 1,2-Dichloropropane. I 1.0 I 10 I< 1.0 I
I cis-1,3-Dichloropropene I 1.0 I 10 I< 1.0 I
I trans-1,3-Dichloropropeno I 1.0 I 10 I<. 1.0 I [ ___________ ....:.. ___ ,
ALL COMPOUNDS EXPRESSED IN MICROGRAMS/LITER UNLESS OTHERWISE NOTED.
ALL NON-DETEC! VALUES ARE REPORI'ED AS dIDL (MODIFIED TO REFLEcr DILU!IONS/SAMPLE VOLUME).
SEE ATl'AarED·PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
;""'· :-~ i"' ; '.,
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' -'::D.';,c: =
Eckenfelder Laboratory, LLC
-...... ?•> Client: FCX #18895.006
Date Reported: 07/13/00
I ECI<ENFEUJER SAMPLE NUMBER j 0006137-0S I
1------------------------~--------------------1 ~---------1
I DATE SAMPLED I 06/21/00 I
I DATE !<ECEIVED I 06/23/00· I
I DATE l\Nl\LYZED t 07/04/00 I
1--. -------------------. ------------·· -------. ·-1-----------1
I I Trip Blank!
[ CLIENT SAMPLE OESCRIJ?TION I #1625 I
I I I
· I------------------------· --· ------------------1---· -------1
I VOLATILE ORGANICS I I I I
I BY USEPA CLP sow OLM03 • 2 I MDL I EQL ·1 CONC I
1-------------· --------------. .----------------1-. --------1
I Ethylbenzene •I LO I 10 I< LO I
I 2-H=ooe I 2.0 I 20 I< 2.0 I
I Methylene chloride I 1.0 I 10 I<· 1.0 I
I 4-Mathyl-2-pentanooe I 2.0 .1 :ao I< :a.o I
I Styrene I 1.0 I ·10 I< 1.0 I
I 1,1,2,2-Tetrachloroethane I" l.O I 10 I< 1.0• I
I Tatrachloroathena I 1.0 1 10 I< 1.0 I
I Toluene I 1.0 I 10 I< 1.0 I
I .1,1,l•Trichloroethane J 1.a· I ·10 I< 1.0_ I
\ ·1,1,:l-Trichloroet~• I 1.0 I_. 10 I< 1,0 I
I Trichloroethene J 1,0 I 10 \< 1.0 J
I Vinyl chloride I :a.a. I 20 I< 2.0 I
I Xylena(total) I 1.0 I 10 I< 1.0 I [ _______________ _,
ALL COMPOUNDS EXPRESSED. IN MICRCGRAMS/LITER UNLESS OTHERWISE NOTED,
. . .
t, 00014
ALL NON-DETECT VALUES ARE REPO~ AS <MDL (mDIFiED TO REFl.Ecr DILtrrION;/~LE-~L~l ..
SEE A1TAC8ED PAGE FOR _DEFINITIONS OF TERMS AND_ OUALIFI~;
~a~
D. Rick Davis
Vice President
, LLC
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Client: FCX #18895. 3'66
Date Reported: 07/13/00
~
. Eckenfelder
Laborator"¼ LLC
t"uf'ili::: u v.i.V
I ECKENFEUlER SAMPLE NL"MBER I VlBLK0704 I VlBLK0705 I VlBLK070f5 [ 0006'144-0lD I 0006144-02D[
1----------------------------------------------1-----------1-----------1-----------1-----------1-----------1
I DATE SAMPLED I NA I NA I NA I 06/23/00 I 06/23/00 I
I DATE RECEIVED I NA I NA I NA I OG/24/00 I OG/24/00 I
I DATE ANALTIED I 07/04/00 I 07/05/00 I 07/06/00 I 07/05/00 I 07/05/00 I
1--------------------------------------------· 1-----------1-----------1----------· 1-----------1-----------1
I I M,BLANK I M,BLANK I M.BLANK I EW-5 I MP-9 I
I CLIENT SAMPLE DESCRIPTION I I I I I I
I I I I I • I • I
1----------------------------------------------1-----------1-----------1-----------1-----------1-----------1
1 voIATILE aRGANIcs r 1 1 1 1 1 250 x1111 20 x1111
I BY USEPA CLP SOW OLM03 , 2 I MDL I EQL I CCNC I CCNC I CONC I CCNC I CCNC I
1---------------------------------------------1-----------1----------1-----------1-----------1-------. ___ I
I Acat;,,,_a I 5.0 I SO I< s.o · I< 5.0 • ' I< 5.0 I< 1200 DI< 100 DI
I Banzana I 1.0 I 10 I< 1.0 I< 1.0 I.< .l.O I< 250 DI.<· 20 □I
· I Bromodichlorcmathana I l.O ] 10 I< l.O I< 1.0 I< 1.0 I< 250 DI< 20 DJ
I Bromoform l 1.0 I 10 I< 1.0 I< 1.0 I< 1.0 I< 250 □I< 20 DI
I Brom:,methana I 2.0 I 20 • I< 2.0 I< 2.0 I< 2.0 I< 500 DI< 40 DI
I 4-Butancne I.· 10 I 100 I< 10 I< 10 I< 10 I< 2500 DI< 200 D]
I carbon disulfide I 1.0 •I 10 I< 1.0 I< 1.0 I< 1.0 I< 250 □I< ao DI
\ carbon tetrachloride I l.O \ 10 I< l.O I< 1.0 [< 1.0 I< 250 DI 110 JD]
I Chlorobenzene I l.O I 10 ]< l.O I< l.O I< 1..0 I< 250 DI< 20 DI
I Chloroethana I 2.0 I 20 ·[< 2.0 I<. 2.0 I< 2.0 I< 500 DI< .40 DI
I Chloroform T l.O \ 10 !< 1.0 I< l.O I< 1.0 I< 250 D[ 22 .mj
I Chloraaethane I 2.0 I 20 1< 2.0 ]< ::z.o t< 2.0 ]< soo DI< 40 D[
I Dibrouxx:hloromathana I 1.0 I 10 I< 1.0 I< 1.0 I< l.O I< 250 DI< 20 □I
I _1,1-Dichloroethana 1 · l.O I 10 I< 1.0 I< 1.0 I< 1.0 I< 250 DI< 20 D\
I 1,:2-Dichlo:c:oethane \ 1.0 ·I lO I< 1.0 I< 1.0 I·< 1.0 I< 250 _DI< 20 DI
I l,l-Diclll.or041thene I 1.0 1 10 i< ·1.0 !< LO ]·< 1.0 I< 250 . DI< 20 DI
l cis-1,2-Dichloro·athana ] 1.0 I 10 J< 1.0 \< 1.0 I< 1.0 I< 250 D\< 20 DI
I trana-1,2-Dichloroethene I 1.0 I 10 I< 1.0 I< l.O I< 1.0 I< 250 DI< 20 DI
I 1,2-Dichloroprcpane I 1.0 I 10 I< 1.0 I< 1.0 ]< 1.0 I< 250 DI< 20 D]
I cis-l,3-Dic:~oropropena I 1.0 I 10 I< 1.0 I<· 1.0 I< 1.0 I< 250 D[< 20 DI
I trano-1,3-Dichloropropona I 1.0 I 10 I< 1.0 I< 1.0 L< 1.0 I< 250 DI< 20 DI 1 ____________________________ 1
ALL COMPOUNDS ~RESSED IN !-!ICROGRAMS/I.ITER ~S OTHERWISE NOTED.
ALL NON-DETECT VAL:tJES ARE REPORTED AS <MDL {MODIFIED TO_ REFLECT DILUTIONS/SAMPLE VOLUME).
SEE ATl'ACHED· PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
{l} • SAMPLES WERE DILUl'ED BY THE. NL"'MERI CAL VlU.tJE DISPIAYED.
DETECTION LIMITS HAVE BEEN INCREASED BY THE SAME FACTOR.
• • SOME ASPECT OF QUALITY CONTROL WAS NOT WITHIN LIMITS,
RESULTS SHOULD BE CONSIDERED AS ESTIMATED.
227 French Landing Drive Nashville, Tennessl?ll 37228 615-345-1115 FA."i'. 615-846-5426
Eckenfelder Laboratory, LLC
Client: FCX #18895.006
Date Reported: 07/13/00
r. ,..,, f°' •l -. v· UV~ D
I ECI<ENFEllJER SAMPLE NUMBER I V1BLK0704 I V1BLK0705 I VlBLK0706 I 0006144-0lDI 0006144-0201
1----------------------------------------------I-----------I-----------I-----------I-----------I-----------I
I DATE SAMPLED \ NA I NA \ NA I 06/23/00 \ 06/23/00 I
\ DATE RECEIVED I NA I NA I NA I 06/24/00 I 06/24/00 I
I DATE ANALY2ED I 07/04/00 I 07/05/00 I 07/06/00 I 07/05/00 I 07/05/00 I
1---------------------------------------------1-----------1-----------r-----------1-----------1-----------1
I I M.BLANK I M.BLANK I M.SLANK I EW-5 . I MP-9 I
I CLIENT _Sl\MPLE DESCRIPTION I I I I I . I
1. I I I I • I • I
1----------------------------------------------1-----------1-----------1-----------1-----------1-----------1
I VOIATILE ORGANICS I I I I I I 250 X(l) I 20 X(l) \
I BY USEPA CLP sow OLM03 . 2 I MDL I EOL I aJNC I aJNC I aJNC I CONC I CONC I
I ·--------------------------------------------1-----------1------, ---1-. ---------1-----------1-----------1
I Ethylbenzan• I 1.0 I 10 I< 1.0 I•· 1.0' I< 1.0 I< 250. DI< 20 DI
I 2-H=on• I 2.0 I 20 I< 2.0 I< 2.0 I< 2.0 I< 500 DI< 40 DI
j Methylane chloride I l.O I 10 J< l.O I< l.O I< l.O I< 2S0 DI< 20 DI
J 4-Methyl-.2-pantanone I 2.0 I 20 I< 2.0 I< 2.0 I< 2.0_ I< S00 DI< 40 DJ
I Styrene I 1.0 I 10 I< 1.0 ·1< 1.0 I< 1.0 I< 250 DI< 20 DI
] l,l,2,2-Tetrac:hloroetbane I l.O I 10 I< l.O I< l.O ]< 1.0 I< 2S0. DI< 20 D[
I Tetrachloroethena I 1.0 J 10 [< l.O I< l.O I< l.O I· 22000 DI S000 DI
l Toluene I l.O I 10 I< 1.0 .I< l.O I< l.O I< 2S0. D]< 20 DI
\ 1,1,1-Trtc:hloroethana I l.O I 10 I< l.O I< l.O I< l.0 I< 2S0 DI<· 20 DI
I l,l,2-Trtchloroethane \. l.O I 10 J< 1.0 I<. 1.0 I< l.O I< 2so DI< 20 c/
I Trichloroethane 1· 1.0 .1. 10 I< 1.0 I< 1.0 I< 1.0 I< 250 DI 25 JDI
I ·v1nyl chloride I 2.0 I 20 I< 2.0 I< 2.0 I~ 2.0 I< 500 DI< 40 DI
I Xylene(totall I 1.0 I 10 I< 1.0 I< 1.0 I< 1.0 I< 250 DI< 20 DI
I I
ALL. co~s EXPRESSED IN MICROGRAMS/LITER UNLESS OTHERWISE NOTED.
~ -~~~ETE~ VALUES ~ ~~ .AS <MDL. (MODIF~ED ~ REFLECT O;LtirI;N~iSAMPLE VO~UME) •
SEE ATTA~ PAGE FOR DEFINITIONS.OF TERMS AND QUALIFIERS.
{1} • SAMPLES WERE DILUTED BY THE NUMERICAL VJ\.LUE DISPLAYED,
DETECTION LIMITS HAVE SEEN INCREASED BY THE SAME FACTOR.
• • SOME ASPECT OF QUALITY CONTROL WAS NOT WITHIN LIMITS,
RESULTS SHOUID BE CONSIDERED AS ESTIMATED,
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Eckellfelder Laboratory, LLC
: .. ,
Client: FCX #1889J':oo6
Date Reported: .07/13/00
I ECI<ENFEWER SAMPLE NUMBER 10006144-02DI0006144-03D[0006144-04D!0006144-04D]0006144-0SD[
1----------------------------------------------1-----------1-----------1-----------1-----------1-----------1
I DATE SAMPLED I 00/23/00 I 00/23/00 I 06/23/00 ·1 06/23/00 I 06/23/00 I
I DATE RECEIVED I 06/24/00 I 06/24/00 I 00/24/00 I 06/24/00 I 06/24/00 I
I DATE ANALY2Ell I 07/05/00 I 07/05/00 I 07/05/00 I 07/06/00 I 07/04/00 I
1-------------------------------. -------------1-----------1-----------1-----------1-----------1 ----------1 I I MP-9 I MP-14 I MP-10 I MP-10 I MP-B I
I CLIENT SAMPLE DESCRIPTION I I I I I I
I I I. I • I I I
1----------------------------------------------1-----------1-----------1----------1-----------1-----------1
I VOLATILEORGANICS I I I 50 X(lll -.100 X(lll 50 X(lll 100 X(lll 5.0 X(lll
I BY USEPA CLP sow OLM03. 2 I MDL I EQL I CONC I CCNC I OONC I CONC I OONC I
1----------------------------------------------1-----------1----------1-----------1---------1-----------1
I Acetone I 5.0 I 50 I< 250 DI< 500 ·• DI< 250 DI-< 500 DI< 25 DI
I Ben2one I LO I 10 I< 50 DI<• 100. DI< 50 Di•< 100 DI< 5.0 Di
I Bromodichloromsthana I 1.0 I 10 l< so DI< 100 DI< SO DI< 100 Dj< s.o DI
j Bromofo:rm I 1.0 I 10 I< so DI< 100 DI< so D[<.100 Dl<·s.o DI
I aromomatha.no I 2.0 ]· 20 I< 100 DI< 200 DI< 100 D[< 200 D[< 10 DI
J· 2-Butanona ] 10 I 100 I< 500 DI< 1000 D[< 500 DI< 1000 D!< so DI
I. carbon disulfide I l.O I ·10 [< so DI< 100 DI< so D]< 100 D]< s.o D[
I carbon.tatrachlorlda. I 1.0 \ 10 I 98 JDJ< 100 D]< so DI< 100 D[< s.o DI
\ · Chloroben:ana I 1.0 I 10 ]< so DI< 100 DI< so DI< 100 D!< s.o DI
I Chloroathana' I 2.0 I· 20 I< 100 DI< 200 DI< 100 D]< 200 DI< 10 D[
I . Chloroform I 1.0 I 10 I< SO· ·DJ< 100 D] < so DI< 100 D[ s.o JDI
I Chloromathan• I 2.0 I 20 ]< 100 DI< 200 D[< 100 DI< :;ioo DI< 10 Dj
I Dibromochlorometbane I 1.0 I 10 I< SO DI< 100 DI<. 30 DI< 100 DJ< S.O DI
[. 1,1-DichlOroethana [ 1.0 I 10 I< SO DI< 100 DI.< 50 DI< 100 ~I 5.0 _JD!
I ·1,:2-Dic;hloroe~hane .I 1.0 I 10 ]< SO _DI< 100 DI< SO DI< 100 D!< 5.0 DI
I · 1,1-Dichlorooth&ne I 1.0 1· 10 I< SO DI< 100 DI< 30 DJ"<. -100 DI 35 JDI
I · cio-1,2-Dichlor<>etluma I LO j 10 I< 50 DI< 100 · DI 250 JD! 230 JD! 7.0 JD!
I ·trans-l,2-Dichloroethena I 1.0 I 10. J.< SO DI<. 100 DI< 50 DI< 100 · DI< s.o D[
\ 1,2-Dichloropropane ] LO I 10 I<· 50 DI< 100 DJ< SO DI< 100 DI< 5.0 DI
I cis-1,3-Dichloropropene · I. 1.0 I 10 I< SO· DI< 100 DI< ·SO D!< 100 DI< S.O D\
[ trans-1,3-Dichloropropene I' l.O I 10 I< 50 Dj< 100 DI·< 50 DI< 100 DI< 5.0 DI
'-----------------------------' ALL OJMPOUNDS EXPRESSED _IN MICROGRAMS/LITER UNLESS OTHERWISE NOTEO.
ALL NON-DETEcr VALUES ARE REPORI"ED AS <MDL (MODIFIED TO REFLECT Dit.trrIONS/SAMPLE VOLUME).
SEE ATl'ACHED PAGE FOR DEFINITIONS OF TERMS AND QtDU.IFIERS.
(1) • SAMPLES WERE DILUTED BY THE NUMERICAL VALUE OISPIAYED.
DETECTION LIMITS HAVE BEEN INCREASED BY THE SAME FACTOR.
• • SOME ASPECT OF _QUALITY CONTROL W\S NOT WITHIN LIMITS,
RESULTS SHOUID BE CONSIDERED AS ESTIMATED.
Eckellfeldei-Laboratory, LLC
Client: FCX #18894':006
Date Reported: 07/13/00
t ":". ;-:· ~ ;~,
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[ ECXENFELIJER SAMPLE NUMBER [ 0006144-02!) [ 0006144-030 [ 0006144-040 [ 0006144-040 [ 0006144-0SO [
1----------------------------------------------1-----------1-----------1-----------1----------1-----------1
[ DATE SAMPLED [ 06/23/00 [ 06/23/00 [ 06/:.3/00 [ 06/23/00 [ 06/23/00 [
I DATE RECEIVED 1: 06/24/00 [ 06/24/00 [ 06/24/00 [ 06/24/00 [ 06/24/00 I
[ DATE ANAL= [ 07 /OS/00 [ 07 /05/00 [ 07 /OS/00 1 · 07 /06/00 I. 07 /04/00 [
I -------------------------------------------. --I-----------I -----------1-----------1-----------1-----.-----1
[ [ MP-9 . [ MP-14 I MP-10 I MP-10 [ MP-8 I
I CLIENT SAMPLE DESCRIPTION I I I I I I
I I I I • I I I · 1----------------------------------------------1--------. --1-----------1-----------1 -------· ---1-----------1
I VOLATILE ORGI\NICS I I I 50 X(l) I · 100 X(l) I 50 X(l) I 100 X(l) I 5.0 X(l) I
[ BY USEPA CLP SOW OLM03 • 2 I MDL I EQL I CONC [ CONC I CONC [ CONC I CONC I
1----------------------------------------------1-----------1-----------1-----------1 --------· --1-----------1
[· Ethylbenzene I LO I 10 I< 50 DI< 100; DI< .~o DI< 100 DI< 5.0 DI
I 2-H,wmcne I 2.0 I 20 I< 100 DI< 200 DI< 100 DI< 200 DI< 10 DI
I Methylene chloride I 1.0 \ 10 \< SO DJ< 100 DI< SO 0[< 100 DI< 5.0 DI
I 4-Methyl-2-pantanone l 2.0 I 20 I< 100 DI< :ZOO DI< 100 DI< 200 DI< 10 DI
I Styrene I LO I 10-I< SO DI< 100 DI< SO DI< 100 D]< 5.0 □I
I 1,1,2,2-Tetrachloroel:bane. I 1.0 \ 10 I< SO DI< 100 DI<. 50 DI< 100 DI< 5.0 DI
[ Tetrachloroetb.ena I 1. O ~ 10 I 5200 DI 15000 DI 16000 DI 13000 DI 690 DI
I Toluene I 1.0 I 10 l< _so DI< 100 DI< so DI< 100 DI< s.o o[
\ 1,1,l-Tri~Oroethane I 1,0 I 10 [< SO DI< 100 DI< 50 D[< .100 DI< 5.0 DI
I 1,1,2-Trichloroathane I LO I 10 .I< 50 DI< 100 D[< SO DI< 100 DI< S.O DI
I Trichloroathene I 1.0 I 10 \< 50 DJ<· 100 DI 130 ·JD!< 100 Dj 11 JOI
I Vinyl chloride I 2.0 I 20 .1< 100 DI<· 200 DI< 100 DI< 200 .Oj< 10 DI
I · Xylene[total) I LO I 10 I< 50 D[< 100 DI< SO D[< 100 DI< 5.0 DI , _____________________________ !
ALL COMPOUNDS EXPRESSEC IN ~ICROGRAMS/LITER ,UNLESS OTHERWISE NOTED.
ALL NON-DETEcr VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLEcr DILt.rrIONS/SAMPLE VOLUME} .
SEE ATrACHED PAGE FOR DEFUITTIONS OF TERMS ANO. QtllU.rFIERS .
. (l) -SAMPLES WERE or LUI'ED BY" TSE NUMERICAL VALtm DISPLAYED.
DETECfION LIMITS HAVE BEEN INCREASED BY THE SAME FACTOR.
• • SOME ASPECl' OF QUALITY CONTROL m-S NOT WITHIN LIMITS,
RESULTS SHOULD BE CONSIDERED AS ESl'IMATED,
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Eckenfeider Laboratory, LLC
1:
Client: FCX #18895.006
Date Reported: 07/13/00
I ECI<ENFELbER SAMPLE NUMBER I 0006144•06 j
1----------------------------------------------I-----------I
I DATE SAMPLED I 06/23/00 I
I DATE RECEIVED I 06/l4/00 I
I DATE ANALYZED I 07/04/00 I
1---------------------. -----. ------------------1-----------1
I I Trip Blankl
I CLIENT SAMPLE DESCRIPTION. 1. #1626 . I
. : _· _______ · ·_ ._ .. ______ . -. ---·_. _____ · .. _ ..... ·.s'' ·:···_ · ________ :
I VOIATILE ORGANICS I I I I
I BY USEPA CLP SOW OIM03 . 2 I MDL I EQL I OO>IC I
1---------------------------------------------1-----------1. I Acetone I s.o I so I< s.o I
I Benzene I 1.0 I 10 I< 1.0 I
I Brom::ldichlorcmethane I 1.0 I 10 I< 1.0 I
I Bre=form \ 1.0 I 10 I< 1.0 \
I Brcmcmothane I 2.0 \ lO I< 2.0 I
I 2-Butonona \ 10 I 100 I< 10 I
I carbon disulfide I l.O I 10 I< l.O I
I carbon tetrachloride I· 1.0 · I 10 I< 1.0 I
I Chlorobenzene \ ,1.0 · 1 10 ] < 1.0 ·I
I Chloroethane I 2.0 \ 20 · \< 2.0 I
I Chloroform · \ 1 .. o I 10 \ < 1.0 \
I Chloromathane I 2.0 I 20 I< 2.0 \
I Dibromochloromathono I l.O I 10 I< 1.0 I
I l, l-Dichloroethone I 1.0 I 10 I< 1.0 I.
I 1,2-Dichloroethana I 1.0 I 10 [< l,O J
I 1;1-Dichloroetheno I 1.0 I 10 I< 1.0 I
I c1S-1,2-Dic:hloroetbime. I 1.0 \ 10. I<· 1.0 I
I trans-1,2-Dichloroothene I 1.0 I 10 I< 1.0 I
I 1,2-Dichloropropan• · I 1.0 I 10 I< 1.0 I
I cie-l,3-Dichloropropono I 1.0 I 10 I< 1.0 I
. I trana-1,3-Dichloropr,,pona .1 1.0 I 10 I< 1.0 1.
1 _______________ 1
ALI. COMPOUNDS EXPRESSED. IN MICROGRAMS/LITER UNLESS OTHERWISE NOTED,.
ALL NON-DETECT VAl.,UES ARE REPORI'ED AS <MDL (MODIFIED TO REFLECT DILU!IONS/SAM!?LE" VOLUME),
SEE .ATTACHED PAGE FOR DEFINITIONS OF TERMS AND ~!FIERS.
' f" ,"l _.~, -("' 'vV'-..: ..&. ';J
. . . ' ·-,,±-•"
Eckellfeider Laboratory, LLC
Client: FCX #18895.006
Date Reported: 07/13/00
I ECJ<ENFELlJER SAMPLE NUMBER 10006144-06 I
1------------------------------. ---------------1-----------1
I DATE SAMPLED I 06/23/00 I
I DATE RECEIVED I 06/24/00 I
I DATE ANALTIED . I 07/04/00. I
1-------------------· -------------------------1-----------1.
I .1 Trip Blankl
I CLIENT SAMPLE DESCRIPTION I #1626 I
I I I
l----------------------·------.----------------I-----------I
I VO!ATILE ORGANICS I I I I
I BY USEPA CLP sow OLM03 . 2 [ MDL [ EQL I CONC I
I----------------------------------------------I -----------I
I Ethylhenzone . I LO l 10 I< LO· I
I >-Ha><ancne ·1 2.0 I ·20 I<·2.0 I
I Methylene chloride I l.O I 10 I< LO J.
[ 4-Methyl-2-pant:.anon• I" 2.0 I 20 . I< 2.0 I
I Styrene I LO I 10 I<. LO I
I l,l,2,2-Tatraehloroethane [ 1.0 · I 10 ]< 1.0 I
I Tetrachloroethene I 1.0 I 10 I< 1.0 I
I Toluene I LO I 10. I< LO 1·
_ I 1,1,l-Trichloroetbane I l.O I 10 [< l~o· I
I 1,1,2-Trtchloroethana I l.O ] 10 I< l.O I
I Trichloroethane I l. O I 10 · J. < l .-o I
I Vlnyl chloride I 2.0 I 20 I< 2.0 I
I Xylona(total) I · LO I 10 I< LO ·1
1--------~------1 ALL COMPOUNDS EXPRESSED IN MICROGRAMS/LITER UNLESS OTHERWISE NOTED,
ALL NON-DETEcr VJU.UES · ARE REPORrED AS <MDL (MODIFIED ~ REFLEcr ;rLurIONs/SAMPLE VO~l.
SEE_ ATTACHED PAGE FOR DEFINITIONS OF TERMS AND QtmLIFIERS·.
Eckenfelder .Laborat ry, -p1~-,_·· I .
D. Rick Davis
Vice President
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I·, r:•-t•·-.,.. vvv,~-u
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Client: FCX #18895 .3'66
Date Reported: 07/14/00
~
Ecksnfelder
Laborato"¾ LLC
1-: .... ,; r. :--, 1vv 1v..:.1
I ECKENFELIJER SAMPLE NUMSER .1 VlBLK0704 I VlBLK0705 I VlBLK0706 10001001-01 10001001-02 I
1----------------------------------------------1-----------1-----------1-----------1-----------1-----------1
I DATE SAMPLEll I NA I NA I NA I 06/30/00 I 06/30/00 I
I DATE RECEIVED I NA I NA I NA I 07/01/00 I 07/0l/OO I
I DATE ANAL'lZEIJ I 07 /04/00 I 07 /05/00 I 07 /06/00 I 07 /04/00 I 07 /05/00 I
I---· ------------------------------· --------. ·--1--------· -1----------1-----------1-----------1-----------I
I J. M,BU\NK I M.BLANK I M.BU\NK I EW-3 I EW-3 .;,;.,. I
I . CLIENT SAMPLE DESCRIPTION . J' . I I I I I
I I I I I I I
· 1---------------------------------------------1-----------I-----------I -----------I -----------I -----------I
I VOLATILE ORGANICS I . I I I I I I I
I BY USEPA CLP srnf OL.~03 , 2 I · MDL I EQL I OJNC I CONC I OJNC I OJNC I OJNC I
1------------------------------· --------------1-----------1-----------1-----------1-----------1-----------1
I Acetone I 5.0 I 50 I.< 5.0 I< 5.0 ',. I< 5,0 I 6.l Ji< 5.0 I
·1 Benzene I l.O I 10 I< l.O J< l.O I< l.O I< l.O I< l.O I
I Bromodichloromethano I l.O I 10 I< l.O I< LO I< LO I 4,0 Ji 3.9 Ji
I Bromoform I LO I lO I< LO I< LO I< l.O I< l.O I< l.O I
I Bromomathano I >.O I 20· I< >.O I< 2,0 I< 2.0 I< 2.0 I< 2.0 I
J 2-Butanone I 10· I 100 I< 10 I< 10 I< 10 I 24 Ji< 10 I
I carbon disulfide I LO I 10 I< l.O I< LO I< LO I< l.O I·, l.O I
1· carbon tatrachlortds ] 1.0 I 10 f<. 1.0 .I< l.O I< 1.0 l < 1.0 I< l.O [
I Chloroben:z:ene I l.O I 10_ I< l.O I"< l.O I< 1.0 I.< 1.0 I< 1.0 I
j Chloroeehane l 2.0 \ 20 \< 2.0 I< 2.0 r< 2.0 I< 2.0 I< 2.0 [
I Chloroform I l.O I lO I< l.O I<· l.O I< l.O I 35 I 37 I
I Chloromethane ·I >.O J 20 I< 2.0 I< >.O J< 2.0 I< 2,0 I< 2,0 I
] D1branochlorcmDtbane I 1.0 I 10 I< 1.0 \< 1.0 I< 1.0 I< 1.0 I< l.O I
I 1,1-Dichloroatbane I l.O I 10 I< 1.0 I< 1.0 I< l.O I< 1.0 I< LO I
I 1,2-Dichloroethane ·1 1.0 I 10 1< l.O I< 1.0 ]< 1.0 I~ 1.0 I< 1.0 I
I· · l,l-Cichloro•t~ene ·1 ·:LO· I 10 I< 1.0 I< 1.0 I< 1.0 I< 1.0 ]< 1.0 I
I cia-1,2-01chioroeehena r-·1.0 i 10 ·1<·1.0 I< LO· I< 1.0 \< 1.0· I 1.7 Jj
I trane-1,2-Di~oroet.heno I 1.0 r 10 I< 1.0 I'< 1.0 1< 1.0 I< .1.0 I< t.O I
I 1,2.-Dichloropropane I l.O I 10 I< l.O I< l.O I< LO I<· l.O I< l.O I
I cie-l,3-Dichloropropane i l.O I .10 I< l.O I<· l.O I< l.O ·I< l.O [< l.O I
I trane-1,3-Dichloropropene J l.O I 10 I< l.O I< LO I< l,O I< l,O I< l.O I
I I
ALL COMPOUNDS EAPRESSED IN-MICROGRAMS/LITER UNLESS OI'HERW!SE NOTED.
ALL NON-DE'rEC! VALUES ARE REPORTED AS dIDL (MODIFIED TO REFLEC! DILlJTIONS/SAMPLE VOLUME).
SEE A'I'.TAcm:D. PAGE· FOR DEFINITIONS OF TERMS AND QUALIFIERS.
227 French Landing Drive Nashville, Tennessee 37228 615-345-1115 FAX [phone]
....
i .. ·: ·...;:. . ..-·
Eckenfe!der Laboratory, LLC
Client: FCX #18895.006
Date Reported: 07/14/00
I ECKENFELbER SA."1PLE NUMBER . I VlBLK0704 I VlBLK0705 I VlBLK0706 I 0007001-0l · 10007001-02 I
1----------------------------------------------1-----------1-----------1-----------1-----------1-----------1
I DATE SAMPLED I NA I NA I NA I 06/30/00 I 06/30/00 I
I DATE RECEIVED I NA I NA I NA I 07/01/00 I 07/01/00 I
I DATE ANALYZED I 07/04/00 I 07/05/00 I 07/06/00 I 07/04/00 I 07/05/00 I
1----------------------------------.-------. --1 --------. --1-----------1-----------1-----------1-----------1
I I M.BLANK I M.BLANK I M.BLANK I IDM I EW-3 dupe I
I CLIENT SAMPLE DESCRIPTION I r I I I I I
I I I I I I I
r----------------------------------------------I-----------I-----------1-----------I-----------I-----------I
I VOIATILE ORGANICS I I I I I I I I
I BY USEPA CLP SOW OLM03 .2 I MDL I EOL I CONC [ CONC I CONC I CONC I. CONC I
1----------------------------------------------1-----------1------. ---1-----------1-. ---------1-----------1
I Ethylbenzena I 1.0 l 10 I< 1.0 I< 1.0 ,. I< 1.0 I< 1.0 I< 1.0 I
I 2-Haxanona · I: 2.0 I 20 I<. 2.0 I< ,.o I< ,.o I< 2.0 I< 2.0 I
I Methylene chloride I l.0 I 10 I< l.0 I< l.0 I< 1.0 I< 1.0 I< 1.0 I
t" 4-Methyl-2-pentanone ,I 2.0 -I 20 l< 2.0· I< 2.0 I< 2.0 I< 2.0 I< 2.0 I
I Styrene I 1.0 I 10 I< 1.0 I< 1.0 I< 1.0 I< l.O I< 1.0 I
I 1,1,2,2-Tetrachloroethane ] 1.0 I 10 I< 1.0 I< 1.0 1< l.0 I< 1.0 I< 1.0 I
I Tetrachloroethena I l.0 I 10 I< l.0 [< 1.0 [< 1.0 I 170 [ 180 I
I Toluene I 1.0 I 10 I< 1.0 I< 1.0 I< 1.0 I< 1.0 I< 1.0 I
I 1,1,1-Trichloroethane l 1.0 I. 10 I< l.0 I'< 1.0 ·J< 1.0 I< 1.0 I< 1.0 l
f l,l,2-Trichloroethana I 1.0 I 10 I< 1.0 I<. 1.0 I< 1.0 I< 1.0 I< 1.0 I
I Trichloroathene I 1.0 I 10 I< 1.0 I< 1.0 I< 1.0 I 3.1 JI 3.3 JI
1· Vinyl chloride I ,.o I 20 I< 2.0 I< 2.0 I< 2.0 I< 2.0 I< 2.0 I
I Xylene(total) I 1.0 I 10 I< 1.0 I< 1.0 I< 1.0 I< 1.0 I< 1.0 · I 1 __ ___;'-________ _;_ ______ ~ _________ 1
ALL COMPOUNDS EXPRESSED IN MICROGRAMS/LITER UNLESS OTHERWISE NOTED.
. . . .
ALL NON-DETECT VlU.UES ARE .REPOR'I'El) AS <MDL (MODIFIED TO REFLECT DILt.Tl"IONS/SAMPLE VOLUME).
·SEE ATrACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
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Eckenfelder Laboratory, LLC
Client: FCX #18895.006
Date Reported: 07/14/00
[ ECKENFELbER SAMPLE NUMBER [0001001-030[0001001-04 [0001001-040[0001001-os 1
1----------------------------------------------1-----------1-----------1-----------1-----------1
j DATE SAMPLED I 06/30/00 I 06/30/00 I 06/30/00 I 06/30/00 I
j DATE RECEIVED j 07/01/00 I 07/01/00 j 07/01/00 I 07/01/00 I
j DATE ANALY2ED I 07 /04/00 I 07 /05/00 j 07 /06/00 I 07 /04/00 I
1------------------------------------------. --1-----------1-----------1-----------1-----------1
I I EW-4 IEW-1/ sw-1 IEW-1/ sw-1 I Trip Blankl
j CLIENT SAMPLE DESCRIPTION I I I . I #1616 I
I I I I I I
1----------------------------------------------1-----------1-----------1-----------1--·--------1 I VO!ATILE ORGANICS l I I 5.0 X(l) I I 5.0 X(l) I I
I "/IT USEPA CLP sow OLM03 • 2 I MDL I EQL I CllNC I CllNC I CONC I CllNC I
1-------· -----------------· --------------------1-----------1 · -----,----1-----------1-----------1
I Acetone I 5.0 I 50 I< 25 Di< 5.0' I< 25 DI< 5.0 I
I Boru:one ·1 1.0 I 10 I< 5.0 DI< 1.0 I< 5.0 DI< 1.0 I
I Bromodichlorcmsthane I l.O I 10 I< S.O Di 1.4 Ji< 5.0 DI< 1.0 I
I Bromcform I l.O I 10 I< 5.0 DI< ·l.O · I< 5.0 DI< l.O I
I Br=cmothano I 2.0 I 10 I< 10 DI< a.o I< 10 DI< a.o I
r (\ r-· r·, c-, i__,v·J~j
I 2-Butancne I 10 I 100 1 < so DI.<-10 I< so DI< 10 I
I carbon disulfide I l.O I 10 I< 5,0 DI< l.O I< 5.0 Di< l.O I
[ carbon tetrachlorida \ l.O I 10 I< 5.0 DI< 1.0 I<. 5.0 D[< 1.0 I
I Chloroben:z:ene I 1.0 I 10 !< S,O Dj< 1.0 I< S.O DI< 1.0 I
j Chloroethane I 2,0 1 20 I< 10 DI<: 2.0 [< 10 DI< 2.0 I
I Chloroform I 1.0· I 10 I 47 JDI 38 . I so DI< 1.0 I
I Chlorom,,thano I 2.0 I 20 I< 10 DI< l.O I< 10 DI< 2.0 I
I Dibrcmochloromethane [ 1.0 I 10 I< 5.0 D\< l .. o I< 5.0 DI< 1.0 1.
] 1,1-Dichloroethane I 1.0 1 10 I< 5.0 DI< 1.0 [< _s.o DI< 1.0 I
I-l,J:-Dich.loroethane \ 1.0 I · 10 I< s.o DI< 1.0 I< 5,0 D]< 1.0 ]
I 1,1-Dichloroatheno I l.O I 10 I< s.o DI< l.O I<-5.0' DI< l.O I
I cis-1,2-Dichlorcechana I 1.0 I 10 I 18 JDI. -14 / :20 JD!< 1.0 f
I trans-l,2-Dichloroethane \ 1.0 ·[ 10 I< s.o oj·<· 1.0 I< s.o DI< 1.0 I
I _l,2-Dichloropropon• I l.O I 10 I.< 5.o DI< l.O I< 5.0 D\< l.O I·
I cia-1,3-Dichloropropena I LO ] 10 I< 5.0 DI< 1.0 t< S.O DI< LO I
[ trans-1,3-Dichloropropane I 1.0 I ·10 I< 5.0 D]< LO I< S.O D]< LO ] 1 _________ ;_ _______________ 1
ALL COMPOUNDS EXPRESSED IN MICRCGRAMS/LITER UNLESS OTHERWISE NQI'ED.
ALL NON-DETECT VALUES ARE REF0RTED AS <MDL (MOCIF!ED TO.REF_LECT DILUTIONS/SAMPLE VOLUME}.
SEE ATTACRED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
(1) • SAMPLES WERE DILUTED BY THE NUMERICAL VALUE DISPIAYED.
DETECTION LIMITS HAVE BEEN INCREASED BY THE SAME FAC!OR.-
Eckenfelder Laboratory, LLC
;.'.-
Client, FCX #1889l:oo6
Date Reported: 07/14/00
r (\ .-, r, ~
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I ECKENFELbER SAMPLE NUMBER 10001001-03ojooo1001-04 !0001001-04010001001-os I
I----------------------------· -----------------l'-----------1---------·-1-----------1-----------1
I DATE SAMPLED I 05/30/00 I 05/30/00 I 05/30/00 I 05/30/00 I
I DATE RECEIVED I 07/01/00, I 07/01/00 I 07/01/00 I 07/0l/OO I
I DATE ANAL"lZE!l I 07/04/0o I 01/05/0o I 01/05/00. I 01/04/0o I
1--. ----------------------------------------. --1-----------1-----------1-----------1-----------1
I I EW-4 IEW-1/ sw-1 IEW-1/ sw-1 I Trip Blankl
I CLIENT SAMPLE DESCRIPTION I I I I #1515 I
. :-. ···· .. i i .. · .... ·· . -------. ---. •,. -.. -.·. - -:--------:-----------: -----------: -----------:
I VOLATILE ORGANICS I I I 5.0 X(l) I I 5.0 X(l) I I
I . BY USEPA CLP SOW OLM03 . 2 I MDL 1 · EQL I CONC I CONC I CONC I OONC I
l----------------------------------------------1-----------I ------.. --1----------1---. -------I
1·. Ethylllenzen• I 1.0 I 10 I< 5.o DI< l.O · I< 5.0 DI< 1.0 I
J 2-H-=n0t1• . J 2.0 I 20 I< 10 DI< 2.0 I< 10 DI< 2.0 I
I Methylene chloride I 1.0 I 10 I< s.o DI< 1.0 I< 5.o· DI 4.5 Ji
[.. 4-Methyl-2-pentancne ·I 2.0 I ·20 ]<. 10 ·DI< 2.0 I< 10 DI< 2.0 I
I Styron• I 1.0 I 10 I<. 5;0 DI< 1.0 I< 5.0 DI< 1.0 I
✓ I 1,1,2,2-Tetrachlorcethane i 1.0 t 10· I< ·S.O DI< 1.0 I< S.O DI<_ 1.0 I
\ Tetra.chloroethene I 1.0 I 10 I 770 DI 230 I 290 D]< 1,0 I
I Toluen• I 1.0 I 10 I< 5.0 DI< 1.0 I< 5.0 DI< 1.0 I-
I" 1,1,1-Trichloroethana · I 1.0 I 10 I< s.o· Df< 1.0 \< s.o DI< 1.0 I
[ 1,1,2-Trichloroetbane I 1.0-I 10 ]< 5.0 D[< 1.0 I< s.o DI< 1.0 _]
I Trichloroethane .1 l. O I· 10 I . 10 JD I 7. 7 Ji 9 • 8 JD I< l. 0 I
I. Vinyl chloride I 2.0 I 20 I< 10 Di< 2.0 I< 10 Di< 2.0 I
I Xylene(total) I' 1.0 I 10 I< 5.0 DI< 1.0 [< 5.0 DI< 1.0 1.
1 _________________________ ,1
. ALL. COMPOUNDS EXPRESSED IN MICROGRAMS/LITER UNLESS OTHERWI~ NOTED.
ALL NON-oETEcr V1WJES ARE. REPORTED ~ <MDL (MODr-FlED TO ~~er o.iLtJTIONS>SAMFLE VOL~).
SEE AITACHED PAGE FOR DEFINITIONS-OF TERMS AND Qtm.LIFIERS.
(1) • SAMPLES_ WERE DILUTED BY THE NUMERICAL VALUE DISPIAYED,
DETECTION LIMITS BA.VE BEEN INCREASED BY THE SAME FAcr_oR.
Eckenfelder
-1f[tµc;a
D. Rick Davis
Vice President
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ANALYTICAL REPORT TERMS AND QUALIFIERS (GC/MS)
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The methoci"f;detection limit (MDL) is defined as the mm1mum
concentration of a substance that can be measured and reported with
~9% confidence that the analyte concentration· is greater than zero. · The · .
MDL is determined from analysis of a sample containing the analyte in a
given matrix.
The estimated quantitation limit· (EQL) is defined as the estimated
concentration above which quantitative results. can be obtained with a
specific degree of confidence. Eckenfelder Laboratory, LLC .. defines the
EQL to be ten times the MDL. ·
The presence of a "B" to the right of an analytical value indicates that
this compound was also detected in the method blank and the data
should be interpreted with caution. One should consider the possibility
that the correct sample result might be less than the reported result and,
perhaps, zero. · · ·
When a sample (or sample extract) is rerun diluted because one of the
compound concentrations exceeded the highest concentration range for
the standard curve, all of the values obtained in the dilution run will be
flagged with a "D".
The concentration for any compound found· which exceeds the highest
concentration level on the standard curve for that compound will be
flagged with an "E". . Usually the sample will be rerun at a dilution to
quantitate the flagged compound. · ·
. .
The presence of a "J" to the right of an analytical result indicates that the
reported result· is estimated ... The mass spectral data pass the
identification criteria showing that the. compound is present, but the
calculated result is less than the EQL. One should feel confident that
the result is greater than zero and less tlian the EQL.
CC02G FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET
EW-8 Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No.: NA SAS No.: NA SDG No.: FCX.V06137
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/rnL) ML
LOW
ID: 0. 53 (mm)
Lab Sample ID: 0006137-01
Lab File ID: 0613701D
Date Sampled: 06/21/00
Date Analyzed: 07/04/00
Dilution Factor: 5.0
Soil Extract Volurne: ____ (uL) Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q
67-64-1---------Acetone 250 UD
71-43-2---------Benzene 50 UD
75-27-4---------Bromodichloromethane 50 UD
75-25-2---------Bromoforrn 50 UD
74-83-9---------Brornomethane 100 UD 78-93-3---------2-Butanone 500 UD 75-15-0---------Carbon disuI:Eia:e 50 UD
56-23-5---------Carbon tetrachloria:e 6.4 JD
108-90-7--------Chlorobenzene 50 UD
75-00-3---------Chloroethane 100 UD
67-66-3---------Chloroforrn 50 UD
74-87-3---------Chloromethane 100 UD
124-48-1--------Dibromochloromethane 50 UD
75-34-3---------1,1-Dichloroethane 50 UD
107-06-2--------1,2-Dichloroethane 50 UD
75-35-4---------1,1-Dichloroethene 50 UD
156-59-2--~--~-~cis~l,2~Dichloroethene 160 D
156-60-5--------trans-l,2-Dichloroethene __ 50 UD
78-87-5---------1,2-Dichloropropane 11 JD
10061-01-5------cis-l,3-Dichloropropene 50 UD
10061-02-6------trans-l,3-Dichloropropene_ 50 UD
100-41-4--------Ethylbenzene 50 UD
591-78-6--------2-Hexanone· 100 UD
75-09-2---------Methylene chloria:e 50 UD
108-10-1-----~--4-Methyl-2-pentanone 100 UD
100-42-5--------Styrene 50 UD
79-34-5---------1 1 2 2-Tetrachloroethane 50 UD •/ ' , , -3400 D,t ii 127-18-4--------Tetrachloroethene
108-88-3--------Toluene 11 JD
71-55-6---------1,1,1-Trichloroethane 50 UD
79-00-5---------1,1,2-Trichloroethane 50 UD
79-01-6---------Trichloroethene 70 D
FORM I VOA
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FORMl ,., {':~,,•17 CLIENTSAMPLENO.
VOLATILE ORGAl.'1ICS ANALYSIS DATA SHEEt' v " ..
EW-8
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No. : NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
Soil Extract Volume : ____ (uL)
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
SAS No.: NA SDG No.: FCX.V06137
Lab Sample ID: 0006137-01
Lab File ID: 0613701D
Date Sampled: 06/21/00
Date Analyzed: 07/04/00
Dilution Factor: 5 .. 0
Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
100 UD
so UD
FORM I VOA
FORM 1 C C Q 2 3 CLIENT SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET
EW-7
Lab Name : ECKENFELDER LLC Contract : EL PASO ENERGY
Lab Code: NA Batch No. : NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
5.000 (g/mL) ML
LOW
----
SAS No.: NA SDG No.: FCX.V06137
Lab Sample ID: 0006137-02
Lab File ID: 0613702D
I
GC Column: DB-624 ID: 0.53 (mm)
Soil Extract Volume: ____ (uL)
Date Sampled: 06/21/00
Date Analyzed: 07/04/00
Dilution Factor: 10.0
Soil Aliquot Volume: ---(uL) ,,
CONCENTRATION UNITS:
CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q
67-64-1---------Acetone 500 UD 71-43-2---------Benzene 100 UD
75-27-4---------Bromodichloromethane 100 UD 75-25-2---------Bromoform 100 UD 74-83-9---------Bromometharie 200 UD
78-93-3---------2-Butanone 1000 UD 75-15-0---------Carbon disuI:fiae 100 UD 56-23-5---------Carbon tetrachloriae 10 JD 108-90-7--------Chlorobenzene 100 UD
75-00-3---------Chloroethane 200 UD
67-66-3---------Chloroform 100 UD 74-87-3---------Chloromethane 200 UD
124-48-1--------Dibromochloromethane 100 UD
75-34-3---------1,1-Dichloroethane 100 UD
107-06-2--------1,2-Dichloroethane 100 UD
75-35-4~--------l,1-Dichloroethene 100 UD
156-59-2-----:---cis-1, 2-Dichloroethene 100 UD
156-60-5-~------trans-l,2-Dichloroethene __ 100 UD
78-87-5---------1,2-Dichloropropane 100 UD
10061-01-5------cis-1,3-Dichloropropene 100 UD
10061-02-6------trans-1,3-Dichloropropene_ 100 UD
100-41-4--------Ethylbenzene 100 UD
591-78-6--------2-Hexanone 200 UD
75-09-2---------Methylene chloride 100 UD
108-10-1--------4-Methyl-2-pentanone 200 UD
100-42-5--------Styrene 100 UD
79-34-5---------1,1,2,2-Tetrachloroethane_ 100 UD
127-18-4--------Tetrachloroethene 1400 D
108-88-3--------Toluene 100 UD
71-55-6---------1,1,1-Trichloroethane 100 UD
79-00-5---------1,1,2-Trichloroethane 100 UD
79-01-6---------Trichloroethene 100 UD
FORM I VOA
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FORM 1 r .-. ' r• :-CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET •~ -., -_; ~ J
EW-7
Lab Name : ECKENFELDER LLC Contract : EL PASO ENERGY
Lab Code: NA Batch No.: NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
UJW
----
ID: 0 • 53 (mm)
Soil Extract Volume: ____ (uL)
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
SAS No.: NA SDG No.: FCX.V06137
Lab Sample ID: 0006137-02
Lab File ID: 0613702D
Date Sampled: 06/21/00
Date Analyzed: 07/04/00
Dilution Factor: 10.0
Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
200 UD
100 UD
FORM I VOA
FORM 1 . . CLIENT SAMPLE NO.
VOIATILE ORGANICS ANALYSIS DATA SHEET CC ;;3 0
EW-2
Lab Name : ECKENFELDER LLC Contract : EL PASO ENERGY
Lab Code: NA Batch No.: NA SAS No.: NA SDG No.: FCX.V06137
Matrix: (soil/water) WATER Lab Sample ID: 0006137-03
Sample wt/vol: 5.000 (g/mL) ML
LOW
Lab File ID: 0613703D
Level: (low/med)
% Moisture: not dee.
Date Sampled: 06/22/00
Date Analyzed: 07/05/00
Dilution Factor: 100.0 GC Column: DB-624 ID: 0. 53 (mm)
Soil Extract Volume: ____ (uL) Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q
67-64-1---------Acetone 5000 UD
71-43-2---------Benzene 1000 UD
75-27-4---------Bromodichloromethane 1000 UD
75-25-2---------Bromoform 1000 UD
74-83-9---------Bromometharie 2000 UD
78-93-3---------2-Butanone 10000 UD
75-15-0---------carbon disulfide 1000 UD
56-23-5---------carbon tetrachloride 130 JD
108-90-7--------Chlorobenzene 1000 UD
75-00-3---------Chloroethane 2000 UD
67-66-3---------Chloroform 1000 UD
74-87-3---------Chloromethane 2000 UD
124-48-1--------Dibromochloromethane 1000 UD
75-34-3---------1,1-Dichloroethane 1000 UD
107-06-2--------1,2-Dichloroethane 1000 UD
75-35-4---------1,1-Dichloroethene 1000 UD
156-59-2--------cis-1,2-Dichloroethene 110 JD
156-60-5--------trans-1 2-Dichloroethene ·· · 1000 UD ' --78-87-5---------1,2-Dichloropropane 1000 UD
10061-01-5------cis-1,3-Dichloropropene 1000 UD
10061-02-6------trans-1,3-Dichloropropene_ 1000 UD
100-41-4--------Ethylbenzene 1000 UD
591-78-6--------2-Hexanone 2000 UD
75-09-2---------Methylene chloride 1000 UD
108-10-1--------4-Methyl-2-pentanone 2000 UD
100-42-5--------Styrene 1000 UD
79-34-5---------1,1,2,2-Tetrachloroethane 1000 UD
127-18-4--------Tetrachloroethene -52000 Dt g/, I
108-88-3--------Toluene 1000 UD
71-55-6---------1,1,1-Trichloroethane 1000 UD
79-00-5---------1,1,2-Trichloroethane 1000 UD
79-01-6---------Trichloroethene 1000 UD
FORM I VOA
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FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET r, " .~ ~ ,
'vV'JV.L
EW-2
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No. : NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
5.000 (g/mL) ML
LOW
GC Column: DB-624 ID: 0.53 (mm)
Soil Extract Volume: ____ (uL)
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
SAS No.: NA SDG No.: FCX.V06137
Lab Sample ID: 0006137-03
Lab File ID: 0613703D
Date Sampled: 06/22/00
Date Analyzed: 07/05/00
Dilution Factor: 100.0
Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
2000 UD
1000 UD
FORM I VOA
FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET r-•"t~-:-i--. r-.1 ',,.,· '-' V ~
Lab Name : ECKENFELDER LLC Contract : EL PASO ENERGY
EW-6
Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FCX.V06137
Matrix: (soil/water) WATER Lab Sample ID: 0006137-04
Sample wt/vol: Lab File ID: 0613704D
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
Date Sampled: 06/22/00
Date Analyzed: 07/04/00
Dilution Factor: 5.0
Soil Extract Volume: ____ (uL) Soil Aliquot Volume: ----
CONCENTRATION UNITS:
CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q
67-64-1---------Acetone 35 JD
71-43-2---------Benzene so UD
75-27-4---------Bromodichloromethane so UD
75-25-2---------Bromoform so UD
74-83-9---------Bromomethane 100 UD
78-93-3---------2-Butanone 500 UD
75-15-0---------Carbon disuifioe so UD
56-23-5---------carbon tetrachlorioe 11 JD
108-90-7--------Chlorobenzene so UD
75-00-3---------Chloroethane 100 UD
67-66-3---------Chloroform so UD
74-87-3---------Chloromethane 100 UD
124-48-1--------Dibromochloromethane so UD
75-34-3---------1,1-Dichloroethane so UD
107-06-2--------1,2-Dichloroethane so UD
75-35-4---------1,1-Dichloroethene 5.1 JD
156-59-2--------cis-1,2-Dichloroethene so UD
156-60-5--------trans-1,2-Dichloroethene __ so UD
78-87-5---------1,2-Dichloropropane so UD
10061-01-5------cis-1,3-Dichloropropene so UD
10061-02-6------trans-1,3-Dichloropropene __ so UD
100-41-4--------Ethylbenzene so UD
591-78-6--------2-Hexanone 100 UD
75-09-2---------Methylene chlorioe so UD
108-10-1--------4-Methyl-2-pentanone 100 UD
100-42-5--------Styrene so UD
79-34-5---------1,1,2,2-Tetrachloroethane __ so UD
127-18-4--------Tetrachloroethene 640 D
108-88-3--------Toluene so UD
71-55-6---------1,1,1-Trichloroethane so UD
79-00-5---------1,1,2-Trichloroethane so UD
79-01-6---------Trichloroethene so UD
FORM I VOA
(uL)
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VOLATILE ORGANICS ANALYSIS DATA SHEET
EW-6
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No. : NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
Soil Extract Volume: (uL) ----
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
SAS No.: NA SDG No.: FCX.V06137
Lab Sample ID: 0006137-04
Lab File ID: 0613704D
Date Sampled: 06/22/00
Date Analyzed: 07/04/00
Dilution Factor: 5.0
Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
100 UD
50 UD
FORM I VOA
FORM 1
VOLATILE ORGANICS ANALYSIS DATA SHEET r:: ,"\ , .... .-. ,,
'-.,V~~"
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
CLIENT SAMPLE NO.
TRIP BLA
NK #1625
Lab Code: NA Batch No. : NA SAS No.: NA. SDG No.: FCX.V06137
Matrix: (soil/water) WATER Lab Sample ID: 0006137-05
Sample wt/vol: Lab File ID: 0613705
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
----
ID: 0. 53 (mm)
Date Sampled: 06/21/00
Date Analyzed: 07/04/00
Dilution Factor: 1.0
Soil Extract Volume: (uL) ---Soil Aliquot Volume: __ _
CAS NO. COMPOUND
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
67-64-1---------Acetone
71-43-2---------Benzene
75-27-4---------Bromodichloromethane
75-25-2---------Bromoform
74-83-9---------Bromomethane
78-93-3---------2-Butanone
75-15-0---------Carbon disulfiae
56-23-5---------Carbon tetrachloriae
108-90-7--------Chlorobenzene
75-00-3---------Chloroethane
67-66-3---------Chloroform
74-87-3----~----Chloromethane
124-48-1--------Dibromochloromethane
75-34-3---------1,1-Dichloroethane
107-06-2--------1,2-Dichloroethane
75-35-4---------1,1-Dichloroethene
156-59-2--------cis-1,2-Dichloroethene
156-60-5--------trans-1 2-Dichloroethene ' --78-87-5---------1,2-Dichloropropane
10061-01-5------cis-1,3-Dichloropropene
10061-02-6------trans-1,3-Dichloropropene_
100-41-4--------Ethylbenzene
591-78-6--------2-Hexanone
75-09-2---------Methylene chloriae
108-10-1--------4-Methyl-2-pentanone
100-42-5--------Styrene
79-34-5---------1,1,2,2-Tetrachloroethane_
127-18-4--------Tetrachloroethene
108-88-3--------Toluene .
71-55-6---------1,1,1-Trichloroethane
79-00-5---------1,1,2-Trichloroethane
79-01-6---------Trichloroethene
FORM I VOA
Q
so u
10 u
10 u
10 u
20 u
100 u
10 u
10 u
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20 u
10 u
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FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET /' :°' ,·, ':l .:;
V V V V,., TRIP ELA
NK #1625 Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No.: NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0. 53 (mm)
Soil Extract Volume: ____ (uL)
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
SAS No.: NA SDG No.: FCX.V06137
Lab Sample ID: 0006137-05
Lab File ID: 0613705
Date Sampled: 06/21/00
Date Analyzed: 07/04/00
Dilution Factor: 1.0
. Soil Aliquot Volume: ___ {uL)
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
20
10
Q
u u
FORM I VOA
FORM 1 CLIENT SAMPLE NO.
VOIATILE ORGANICS ANALYSIS DATA SHEET
EW-5
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FCX.V06144
Matrix: (soil/water) WATER Lab Sample ID: 0006144-01
Sample wt/vol: Lab File ID: 0614401D
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0, 53 (mm)
Soil Extract Volume:. (uL) ----
Date Sampled: 06/23/00
Date Analyzed: 07/05/00
Dilution Factor: 250.0
Soil Aliquot Volume:
CAS NO. COMPOUND
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
67-64-1---------Acetone
71-43-2---------Benzene
75-27-4---------Bromodichloromethane
75-25-2---------Bromoform
74-83-9---------Bromomethane
78-93-3---------2-Butanone
75-15-0---------Carbon disulfide
56-23-5---------Carbon tetrachloride
108-90-7--------Chlorobenzene
75-00-3---------Chloroethane
67-66-3---------Chloroform .
74-87-3---------Chloromethane
124-48-1--------Dibromochloromethane
75-34-3---------1,1-Dichloroethane
107-06-2--------1,2-Dichloroethane
75-35-4---------1,1-Dichloroethene
156-59-2--------tis~l,2-Dichloroethene
156-60-5--------trans-1,2-Dichloroethene
78-87-5---------1,2-Dichloropropane --
10061-01-5------cis-1,3-Dichloropropene
10061-02-6------trans-1,3-Dichloropropene_
100-41-4--------Ethylbenzene
591-78-6--------2-Hexanone
75-09-2---------Methylene chlorioe
108-10-1--------4-Methyl-2-pentanone
100-42-5--------Styrene
79-34-5---------1,1,2,2-Tetrachloroethane
127-18-4--------Tetrachloroethene -
108-88-3--------Toluene
71-55-6---------1,1,1-Trichloroethane
79-00-5---------1,1,2-Trichloroethane
79-01-6---------Trichloroethene
FORM I VOA
Q
12000 UD
2500 UD
2500 UD
2500 UD
5000 UD
25000 UD
2500 UD
2500 UD
2500 UD
5000 UD
2500 UD
5000 UD
2500 UD
2500 UD
2500 UD
.2500 UD
2500 UD
2500 UD
2500 UD
2500 UD
2500 UD
2500 UD
5000 UD
2500 UD
5000 UD
2500 UD
2500 UD
22000 D
2500 UD
2500 UD
2500 UD
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FORMll CLIENT SAMPLE NO. r. I'){'; r;; ~ VOLATILE ORGANICS ANALYSIS DATA SHEETv v.,.., I
EW-5
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No.: NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
5.000 (g/mL) ML
LOW
GC Column: DB-624 ID: 0.53 (mm)
Soil Extract Volume: ____ (uL)
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
SAS No.: NA SDG No.: FCX.V06144
Lab Sample ID: 0006144-01
Lab File ID: 0614401D
Date Sampled: 06/23/00
Date Analyzed: 07/05/00
Dilution Factor: 250.0.
Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
5000
2500
Q
UD
UD
FORM I VOA
FORM 1 C. " (; ~ 8 CLIENT SAMPLE NO. I VOLATILE ORGANICS ANALYSIS DATA SHEET v "
MP-9
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No. : NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/rnL) ML
LOW
ID: 0.53 (mm)
SAS No.: NA SDG No.:·FCX.V06144
Lab Sample ID: 0006144-02
Lab File ID: 0614402D
Date Sampled: 06/23/00
Date Analyzed: 07/05/00
Dilution Factor: 20.0
Soil Extract Volurne: ____ (uL) Soil Aliquot Volume:
. CONCENTRATION UNITS:
___ (uL)-,I
CAS NO. COMPOUND (ug/L or ug/Kg) UG/L
67-64-1---------Acetone
71-43-2---------Benzene
75-27-4---------Brornodichlorornethane
75-25-2---------Brornoforrn
74-83-9---------Brornornethane
78-93-3---------2-Butanone
75-15-0---------carbon disulfide
56-23-5---------carbon tetrachloride
108-90-7--------Chlorobenzene
75-00-3---------Chloroethane
67-66-3---------Chloroforrn
74-87-3---------Chlorornethane
124-48-1--------Dibrornochlorornethane
75-34-3---------1,1-Dichloroethane
107-06-2--------1,2-Dichloroethane
75-35-4---------1,1-Dichloroethene
156-59~2-.-------cis-1, 2-Dichloroethene
156-60-5--------trans:l,2-Dichloroethene __
78-87-5---------1,2-Dichloropropane •
10061-01-5------cis-l,3-Dichloropropene
10061-02-6------trans-l,3-Dichloropropene_
100-41-4--------Ethylbenzene
591-78-6--------2-Hexanone
75-09-2---------Methylene chloride
108-10-1--------4-Methyl-2-pentanone
100-42-5--------Styrene
79-34-5---------1,1,2,2-Tetrachloroethane_
127-18-4--------Tetrachloroethene
108-88-3--------Toluene
71-55-6---------1,1,1-Trichloroethane
79-00-5---------1,1,2-Trichloroethane
79-01-6---------Trichloroethene
FORM I VOA
1000
200
200
200
400
2000
200
110
200
400
22
400
200
200
200
200
200
200
200
200
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I FORM 1 C ..... -. ,;· 9 . ,. . ' V V V CLIENT SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET
MP-9 Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No.: NA
Matrix: (soil/water) WATER
Sample wt/vol: 5.000 (g/mL) ML
LOW Level: (low/med)
% Moisture: not dee.
GC Column: DB-624 ID: 0.53 (mm)
Soil Extract Volume: ____ (uL)
CAS NO. COMPOUND
75-01-4--------·-vinyl chloride
1330-20-7-------Xylene(total)
SAS No.: NA SDG No.: FCX.V06144
Lab Sample ID: 0006144-02
Lab File ID: 0614402D
Date Sampled: 06/23/00
Date Analyzed: 07/05/00
Dilution Factor: 20.0
Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
400 UD
200 UD
FORM I VOA
FORM 1 .-.-, -·' ~-CLIENT SAMPLE NO. I VOLATILE ORGANICS ANALYSIS DATA SHEE\17 ',.; '.; '-. V
MP-9
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FClC.V06144
Matrix: (soil/water) WATER Lab Sample ID: 0006144-02
Sample wt/vol: Lab File ID: 0614402D
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
Soil Extract Volume: (uL) ----
Date ~ampled: 06/23/00
Date Analyzed: 07/05/00
Dilution Factor: 50.0
Soil Aliquot Volume:
CAS NO. COMPOUND
67-64-1---------Acetone
71-43-2---------Benzene
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
75-27-4---------Bromodichloromethane
75-25-2---------Bromoform
74-83-9---------Bromomethane
78-93-3---------2-Butanone
75-15-0---------Carbon disulfide
56-23-5---------Carbon tetrachloride
108-90-7--------Chlorobenzene
75-00-3---------Chloroethane
67-66-3---------Chloroform
74-87-3---------Chloromethane
124-48-1--------Dibromochloromethane
75-34-3---------1,1-Dichloroethane
107-06-2--------1,2-Dichloroethane
75-35-4---------1,1-Dichloroethene
156-59-2--------cis-1,2-Dichloroethene
156-60-5--------trans:1,2-Dichloroethene __
78-87-5---------1,2-Dichloropropane .
10061-01-5------cis-1,3-Dichloropropene
10061-02-6------trans-1,3-Dichloropropene_
100-41-4--------Ethylbenzene
591-78-6--------2-Hexanone
75-09-2---------Methylene chloride
108-10-1--------4-Methyl-2-pentanone
100-42-5--------Styrene
79-34-5---------1,1,2,2-Tetrachloroethane_
127-18-4--------Tetrachloroethene
108-88-3--------Toluene
71-55-6---------1,1,1-Trichloroethane
79-00-5---------1,1,2-Trichloroethane
79-01-6---------Trichloroethene
FORM I VOA
Q
2500 UD
500 UD
500 UD
500 UD
1000 UD
5000 UD
500 UD
98 JD
500 UD
1000 UD
500 UD
1000 UD
500 UD
500 UD
500 un·
500 UD
500 UD
·500 UD
500 UD .
500 UD
500 UD
500 UD
1000 UD
500 UD
1000 UD
500 UD
500 UD
5200 D
500 UD
500 UD
500 UD
500 UD
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FORM 1 . ,, .~ ., .; 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET--",_;'• .i.
MP-9
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No.: NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0. 53 (mm)
Soil Extract Volume: ____ (uL)
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
SAS No.: NA SDG No. : FOC. V06144
Lab Sample ID: 0006144-02
Lab File ID: 0614402D
Date Sampled: 06/23/00
Date Analyzed: 07/05/00
Dilution Factor: so.a
Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
1000 UD
500 UD
FORM I VOA
FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET,-•~ ,-, .' ') . '>J'v-.,·•N
MP-14
Lab Name: ECI<ENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FCX.V06144
Matrix: (soil/water) WATER Lab Sample ID: 0006144-03
Sample wt/vol: Lab File ID: 0614403D
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0. 53 (mm)
Soil Extract Volume: (uL)
Date Sampled: 06/23/00
Date Analyzed: 07/05/00
Dilution Factor: 100.0
Soil Aliquot Volume: ---
CAS NO. COMPOUND
67-64-1---------Acetone
71-43-2---------Benzene
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
75-27-4---------Bromodichloromethane
75-25-2---------Bromoform
74-83-9---------Bromomethane
78-93-3---------2-Butanone
75-15-0---------carbon disulfide
56-23-5---------carbon tetrachloride
108-90-7--------Chlorobenzene
75-00-3---------Chloroethane
67-66-3---------Chloroform
74-87-3---------Chloromethane
124-48-1--------Dibromochloromethane
75-34-3---------1,1-Dichloroethane
107-06-2--------1,2-Dichloroethane
75-35-4---------1,1-Dichloroethene
.J,.56-59-2--------cis-1,2-Dichloroethene
156-60-5--------trans-1 2-Dichloroethene ' --78-87-5---------1,2-Dichloropropane
10061-01-5-----~cis-1,3-Dichloropropene
10061-02-6------trans-1,3-Dichloropropene_
100-41-4--------Ethylbenzene
591-78-6--------2-Hexanone
75-09-2---------Methylene chloride
108-10-1--------4-Methyl-2-pentanone
100-42-5--------Styrene
79-34-5---------1,1,2,2-Tetrachloroethane_
127-18-4--------Tetrachloroethene
108-88-3--------Toluene
71-55-6---------1,1,1-Trichloroethane
79-00-5---------1,1,2-Trichloroethane
79-01-6---------Trichloroethene
.
FORM I VOA
Q
5000 UD
1000 UD
1000 UD
1000 UD
2000 UD
10000 UD
1000 UD
1000 UD
1000 UD
2000 UD
1000 UD
2000 UD
1000 UD
1000 UD
1000 UD
1000 UD
.1000 UD
1000 UD
1000 UD
1000 UD
1000 UD
1000 UD
2000 UD
1000 UD
2000 UD
1000 UD
1000 UD
15000 D
1000 UD
1000 UD
1000 UD
1000 UD
(uL)
I
I
I
I
' I
I
I
I
m
fl
g
m
1·
I
I
I
I
I
I
I
I
I
I
I
g
D
m
I
I
I
I
I
I
I
I
I
FORM 1 _ ,.. , . CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEE'l' v ;v c; J
MP-14
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No. : NA
Matrix: (soil/water) WATER
Sample wt/vol: 5.000 (g/mL) ML
Level: (low/med) LOW
% Moisture: not dee.
GC Column: DB-624 ID: 0.53 (mm)
Soil Extract Volume: ____ (uL)
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
SAS No.: NA SDG No.: FCX.V06144
Lab Sample ID: 0006144-03
Lab File ID: 0614403D
Date Sampled: 06/23/00
Date Analyzed: 07/05/00
Dilution Factor: 100.0
Soil Aliquot Volume:
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
2000
1000
___ (uL)
Q
UD
UD
FORM I VOA
FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEE'l'. ,, .~ . 1 C0.,;:l11
Lab Name : ECKENFELDER LLC Contract : . EL PASO ENERGY
MP-10
I
I
Lab Code: NA Batch No.: NA
Matrix: (soil/water) WATER
SAS No.: NA SDG No.: FCX.V06144 I
Lab Sample ID: 0006144-04
Sample wt/vol: 5.000 (g/mL) ML
LOW
Lab File ID: 0614404D I
Date Sampled: 06/23/00 Level: (low/med)
% Moisture: not dee.
GC Column: DB-624 ID: 0. 53 (mm)
Date Analyzed: 07/05/00 I
Dilution Factor: 50.0
Soil Extract Volume: (uL) ----Soil Aliquot Volume: ___ (uL) m
CAS NO. COMPOUND
67-64-1---------Acetone
71-43-2---------Benzene
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
75-27-4---------Bromodichloromethane
75-25-2---------Bromoform
74-83-9---------Bromomethane
78-93-3---------2-Butanone
75-15-0---------carbon disulfide
56-23-5---------carbon tetrachloride
108-90-7--------Chlorobenzene
75-00-3---------Chloroethane
67-66-3---------Chloroform
74-87-3-~-------Chloromethane
124-48-1--------Dibromochloromethane
75-34-3---------1,1-Dichloroethane
107-06-2--------1,2-Dichloroethane
75-35-4---------1,1-Dichloroethene
156~59-2--------cis-l 2-Dichloroethene . ' 156-60-5--------trans:l,2-Dichloroethene __
78-87-5---------1,2-Dichloropropane
10061-01-5------cis-l,3-Dichloropropene
10061-02-6------trans-l,3-Dichloropropene_
100-41-4--------Ethylbenzene
591-78-6--------2-Hexanone
75-09-2---------Methylene chloride
108-10-1--------4-Methyl-2-pentanone
100-42-5--------Styrene
79-34-5---------1,1,2,2-Tetrachloroethane
· 127-18-4--------Tetrachloroethene -
108-88-3--------Toluene
71-55-6---------1,1,1-Trichloroethane
79-00-5---------1,1,2-Trichloroethane
79-01-6---------Trichloroethene
FORM I VOA
2500
500
500
500
1000
5000
500
500
500
1000
500
1000
500
500
500
500
250
500
500
500
500
500
1000
500
1000
500
500
16000
500
500
500
130
Q
UD
UD
UD
UD
UD
UD
UD
UD
UD
UD
UD
UD
UD
UD
UD
UD
JD
UD
UD
UD
UD
UD
UD
UD
UD
UD
UD
DJ(
UD
UD
UD
JD
/oo ~/,
D
0
g
I
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I
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0
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m
I
I
I
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I
I
FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEE'J;'-. .~ , ~
' ~\,I~:.~
MP-10
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No.: NA
Matrix: (soil/water) WATER
Sample wt/vol: 5.000 (g/mL) ML
LOW Level: (low/med)
% Moisture: not dee.
GC Column: DB-624 ID: 0.53 (mm)
Soil Extract Volume: ____ (uL)
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
SAS No.: NA SDG No.: FCX.V06144
Lab Sample ID: 0006144-04
Lab File ID: 0614404D
Date Sampled: 06/23/00
Date Analyzed: 07/05/00
Dilution Factor: 50.0
Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
1000 UD
500 UD
FORM I VOA
FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET c co 4 6
MP-10
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No. : NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
SAS No.: NA SDG No.: FCX.V06144
Lab Sample ID: 0006144-04
Lab File ID: 0614404D
Date Sampled: 06/23/00
Date Analyzed: 07/06/00
Dilution Factor: 100.0
I
I
I
I
I
Soil Extract Volume: ____ (uL) . Soil Aliquot Volume: ___ (uL) I
CAS NO. COMPOUND
67-64-1---------Acetone
71-43-2---------Benzene
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
75-27-4---------Bromodichloromethane
75-25-2---------Bromoform
74-83-9---------Bromomethane
78-93-3---------2-Butanone
75-15-0---------Carbon disulfide
56-23-5---------Carbon tetrachloride
108-90-7--------Chlorobenzene
75-00-3---------Chloroethane
67-66-3---------Chloroform
74-87-3---------Chloromethane
124-48-1--------Dibromochloromethane
75-34-3---------1,1-Dichloroethane
107-06-2--------1,2-Dichloroethane
75-35-4---------1, 1-Dichloroethene .
156-59-2--------cis-1, 2-Dichloroethene ··
156-60-5--------trans-1 2-Dichloroethene , --78-87-5---------1,2-Dichloropropane
10061-01-5------cis-1,3-Dichloropropene
10061-02-6------trans-1,3-Dichloropropene_
100-41-4--------Ethylbenzene
591-78-6--------2-Hexanone
75-09-2---------Methylene chloride
108-10-1--------4-Methyl-2-pentanone
100-42-5--------Styrene
79-34-5---------1,1,2,2-Tetrachloroethane_
127-18-4----~---Tetrachloroethene
108-88-3--------Toluene
71-55-6---------1,1,1-Trichloroethane
79-00-5---------1,1,2-Trichloroethane
79-01-6---------Trichloroethene
FORM I VOA
5000
1000
1000
1000
2000
10000
1000
1000
1000
2000
1000
2000
1000
1000
1000
1000
230
1000
1000
1000
1000
1000
2000
1000
2000
1000
1000
13000
1000
1000
1000
1000
Q
UD
UD
UD
UD
UD
UD
UD
UD
UD
UD
UD
UD
UD
UD
UD
UD
JD
UD
UD
UD
UD
UD
UD
UD
UD
UD
UD
D
UD
UD
UD
UD
0
D
I
I
I
I
I
I
I
D
D
g
I
I
I
I
I
I
I
I
I
I
I
I
I
I
VOLATILE ORGANI~~~YSIS DATA SHEET C CC ,i 7 CLIENT SAMPLE NO.
MP-10
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No. : NA
Matrix: (soil/water) WATER
Sample wt/vol: 5.000 (g/mL) ML
LOW Level: (low/med)
% Moisture: not dee.
GC Column: DB-624 ID: 0.53 (nnn)
Soil Extract Volume: ____ (uL)
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
SAS No.: NA SDG No.: FCX.V06144
Lab Sample ID: 0006144-04
Lab File ID: 0614404D
Date Sampled: 06/23/00
Date Analyzed: 07/06/00
Dilution Factor: 100.0
Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
2000 UD
1000 UD
FORM I VOA
FORM 1 :-'' , •. .; " CLIENT SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET'v v' ·.; '• ◊
MP-8
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No.: NA SAS No.: NA SDG No.: FCX.V06144
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0 .53 (mm)
Lab Sample ID: 0006144-05
Lab File ID: 0614405D
Date Sampled: 06/23/00
Date Analyzed: 07/04/00
Dilution Factor: 5.0
Soil Extract Volume: ____ (uL) Soil Aliquot Volume:
.. CONCENTRATION UNITS:
CAS NO. COMPOUND (ug/L or ug/Kg) UG/L
67-64-1---------Acetone 250
71-43-2---------Benzene so
75-27-4---------Bromodichloromethane so
75-25-2---------Bromoform so
74-83-9---------Bromomethane 100
78-93-3---------2-Butanone 500 75-15-0---------Carbon disulfiae so
56-23-5---------Carbon tetrachloriae so
108-90-7--------Chlorobenzene so
75-00-3---------Chloroethane 100
67-66-3---------Chloroform 5.0
74-87-3---------Chloromethane 100
124-48-1--------Dibromochloromethane so
75-34-3---------1,1-Dichloroethane s.o
107-06-2--------1,2-Dichloroethane so
75-35-4---------1,1-Dichloroethene 35
156-59-2-------.-cis-1, 2-Dichloroethene 7.0
156-60-5--------trans~l,2-Dichloroethene __ so
78-87-5---------1,2-Dichloropropane so
10061-01-5------cis-l,3-Dichloropropene so
10061-02-6------trans-l,3-Dichloropropene __ so
100-41-4-~------Ethylbenzene so
591-78-6--------2-Hexanone 100
75-09-2---------Methylene chloriae so
108-10-1--------4-Methyl-2-pentanone 100
100-42-5--------Styrene · so
79-34-5----~----l,l,2,2-Tetrachloroet~ __ so
127-18-4--------Tetrachloroethene 690
108-88-3--------Toluene so
71-55-6---------1,1,1-Trichloroethane so
79-00-5---------1,1,2-Trichloroethane so
79-01-6---------Trichloroethene 11
FORM I VOA
___ (uL)
Q
UD
UD
UD
UD
UD
UD
UD
UD
UD
UD
JD
UD
UD
JD
UD
JD
.JD
UD
UD
UD
UD
UD
UD
UD
UD
UD
UD
D
UD
UD
UD
JD
g
g
n
0
D
E
I
I
I
I
I
I
I
I
0
0
0
0
u
I
D
D
0
0
D
I
H
D
0
I
D
0
D
FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEE'l'.: G G :! g
MP-8
Lab Name : ECKENFELDER LLC Contract.: EL PASO ENERGY
Lab Code: NA Batch No. : NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5. 000 (g/rnL) ML
LOW
ID: 0. 53 (mm)
Soil Extract Volurne: ____ (uL)
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
SAS No.: NA SDG No.: FCX.V06144
Lab Sample ID: 0006144-05
Lab File ID: 0614405D
Date Sampled: 06/23/00
Date Analyzed: 07/04/00
Dilution Factor: s.o
Soil Aliquot Volume: ___ {uL)
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
100 so
Q
UD
UD
FORM I VOA
FORM 1 CLIENT SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA ~C' ,-, ~ v,-. vvvV TRIP ELA
NK #1626 Lab Name: ECKENFEWER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No. : NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0. 53 (mm)
SAS No.: NA SDG No.: FCX.V06144
Lab Sample ID: 0006144-06
Lab File ID: 0614406
Date Sampled: 06/23/00
Date Analyzed: 07/04/00
0
0
0
D
0
Soil Extract Volume: ____ (uL)
Dilution Factor: 1.0
Soil Aliquot Volume: ___ (uL) 0
CAS NO. COMPOUND
67-64-1---------Acetone
71-43-2---------Benzene
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
75-27-4---------Bromodichloromethane
75-25-2---------Bromoform
74-83-9---------Bromomethane
78-93-3---------2-Butanone
75-15-0---------Carbon disulfiae
56-23-5---------Carbon tetrachloriae
108-90-7--------Chlorobenzene
75-00-3---------Chloroethane
67-66-3---------Chloroform
74-87-3---------Chloromethane
124-48-1--------Dibromochloromethane
75-34-3---------1,1-Dichloroethane
107-06-2--------1,2-Dichloroethane
75-35-4---------1,1-Dichloroethene
156-59-2--------cis-l,2-Dichloroethene
156-60-5--------trans:l,2-Dichloroethene __
78-87-5---------1,2-Dichloropropane
10061-01-5------cis-l,3-Dichloropropene
10061-02-6------trans-l,3-Dichloropropene __
100-41-4--------Ethylbenzene
591-78-6--------2-Hexanone
75-09-2---------Methylene chloriae
108-10-1--------4-Methyl-2-pentanone
100-42-5--------Styrene
79-34-5---------1,1,2,2-Tetrachloroethane __
127-18-4--------Tetrachloroethene
108-88-3--------Toluene
71-55-6---------1,1,1-Trichloroethane
79-00-5---------1,1,2-Trichloroethane
79-01-6---------Trichloroethene
FORM I VOA
50
10
10
10
20
100
10
10
10
20
10
20
10
10
10
10
10
10
10
10
10
10
20
10
20
10
10
10
10
10
10
10
u u u u
u
u u u
u u
u
u u u
u u
u u u u
u
u
u
u
u
u u u u
u
u
u
Q D
D
D
D
D
D
D
D
D
0
0
0
I
u
I
0
D
0
D
D
0
I
0
0
0
0
0
u
0
D
0
0
FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS Al.w.LYSIS DATA SHEETC ;: G 51
TRIP BIA
NK #1626
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No.: NA
Matrix: (soil/water) WATER
Sample wt/vol: 5.000 (g/mL) ML
WW Level: (low/med)
% Moisture: not dee.
GC Column: DB-624 ID: 0.53 (mm)
Soil Extract Volume: ____ (uL)
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
SAS No.: NA SDG No. : FCJ{. V06144
Lab Sample ID: 0006144-06
Lab File ID: 0614406
Date Sampled: 06/23/00
Date Analyzed: 07/04/00
Dilution Factor: 1.0
Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
20 u
10 u
FORM I VOA
FORM 1 CLIENT SAMPLE NO. VOLATILE ORGAt'IICS ANALYSIS DATA SHEET r ,-,, ,. . ., -=: ~
1,.;·v~'-'~
EW-3
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No.: NA SAS No.: NA SDG No. : FCl{. V07001
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0 . 53 (rmn)
Lab Sample ID: 0007001-01
Lab File ID: 0700101
Date Sampled: 06/30/00
Date Analyzed: 07/04/00
Dilution Factor: 1.0
Soil Extract Volume: (uL) ----Soil Aliquot Volume:
CAS NO. COMPOUND
67-64-1---------Acetone
71-43-2---------Benzene
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
75-27-4---------Bromodichloromethane
75-25-2---------Bromoform
74-83-9---------Bromomethane
78-93-3---------2-Butanone
75-15-0---------carbon disulfiae
56-23-5---------carbon tetrachloriae
108-90-7--------Chlorobenzene
75-00-3---------Chloroethane
67-66-3---------Chloroform
74-87-3---------Chloromethane
124-48-1--------Dibromochloromethane
75-34-3---------1,1-Dichloroethane
107-06-2--------1,2-Dichloroethane
75-35-4---------1,1-Dichloroethene
156-59-2--------cis-l,2-Dichloroethene
156-60-5--------trans:l,2-Dichloroethene __
78-87-5---------1,2-Dichloropropane
10061-01-5------cis-l,3-Dichloropropene
10061-02-6------trans-l,3-Dichloropropene __
100-41-4--------Ethylbenzene
591-78-6--------2-Hexanone
75-09-2---------Methylene chloriae
108-10-1--------4-Methyl-2-pentanone
100-42-5--------styrene
79-34-5---------1,1,2,2-Tetrachloroethane __
127-18-4--------Tetrachloroethene
108-88-3--------Toluene
71-55-6---------1,1,1-Trichloroethane
79-00-5---------1,1,2-Trichloroethane
79-01-6---------Trichloroethene
FORM I VOA
6.1
10
4.0
10
20
24
10
10
10
20
35
20
10
10
10
10
10
10
10
10
10
10
20
10
20
10
10
170
10
10
10
3.1
___ {uL)
Q
J
U.
J u u
J u
u u u
u
u u u
u
u u
u u u
u
u
u u
u u
u
u u
J
D
0
0
0
0
0
0
0
0
0
0
0
0
D
D
0
0
0
0
D
D
I
0
I
D
I
D
0
I
I
I
u
a
g
I
I
m
I
FORM 1 r .-, ·. = 0 CLIENT SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA StmET 'v v :; ~ J
EW-3
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No. : NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0. 53 (mm)
Soil Extract Volume: ____ (uL)
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
SAS No.: NA SDG No.: FCX.V07001
Lab Sample ID: 0007001-01
Lab File ID: 0700101
Date Sampled: 06/30/00
Date Analyzed: 07/04/00
Dilution Factor: 1.0
Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
20 u
10 u
FORM I VOA
FORM 1 r :, .-. r-, CLIENT SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET' v :; :; 'A
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY EW-3 DUPE
Lab Code: NA Batch No.: NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
----
ID: 0.53 (mm)
SAS No.: NA SDG No.: FCX.V07001
Lab Sample ID: 0007001-02
Lab File ID: 0700102
Date Sampled: 06/30/00
Date Analyzed: 07/05/00
Dilution Factor: 1.0
u
0
0
D
0
Soil Extract Volume: ____ (uL) Soil Aliquot Volume: ___ (uL) o
CAS NO. COMPOUND
67-64-1---------Acetone
71-43-2---------Benzene
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
75-27-4---------Bromodichloromethane
75-25-2---------Bromoform
74-83-9---------Bromomethane
78-93-3---------2-Butanone
75-15-0---------Carbon disuB:1oe
56-23-5---------Carbon tetrachlorioe
108-90-7--------Chlorobenzene
75-00-3---------Chloroethane
67-66-3---------Chloroform
74-87-3---------Chloromethane
124-48-1--------Dibromochloromethane
75-34-3---------1,1-Dichloroethane
107-06-2--------1,2-Dichloroethane
75-35-'4---------1, 1-Dichloroethene
156-59-2--------cis-1,2-Dichloroethene
156-60-5--------trans:1,2-Dichloroethene __
78-87-5---------1,2-Dichloropropane
10061-01-5------cis-1,3-Dichloropropene
10061-02-6------trans-1,3-Dichloropropene_·_
100-41-4--------Ethylbenzene
591-78-6--------2-Hexanone
75-09-2---------Methylene chlorioe
108-10-1--------4-Methyl-2-pentanone
100-42-5--------Styrene
79-34-5---------1,1,2,2-Tetrachloroethane_
127-18-4--------Tetrachloroethene
108-88-3--------Toluene
71-55-6---------1,1,1-Trichloroethane
79-00-5---------1,1,2-Trichloroethane
79-01-6---------Trichloroethene
FORM I VOA
so
10
3.9
10
20
100
10
10
10
20
37
20
10
10
10
10
1.7
10
10
10
10
10
20
10
20
10
10
180
10
10
10
3.3
u
u
J u u
u u
u u
u
u
u u
u u
J u
u u u
u u
u u
u
u
u
u
u
J
Q 0
D
D
0
0
0
D
0
D
u
u
D
D
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•
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FORMl __ _
VOLATILE ORGANICS ANALYSIS DATA SHEEJC '.; j::,
CLIENT Sh"!PLE NO.
EW-3 DUPE Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No.: NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
----
ID: 0. 53 (mm)
Soil Extract Volume: ____ (uL)
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
SAS No.: NA SDG No.: FCX.V07001
Lab Sample ID: 0007001-02
Lab File ID: 0700102
Date Sampled: 06/30/00
Date Analyzed: 07/05/00
Dilution Factor: 1.0
Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
20 u
10 u
FORM I VOA
FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET :-(' ,: ~ 1:::
'.I "' <J V U
EW-4 Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No.: NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0. 53 (mm)
SAS No.: NA SDG No.: FCX.V07001
Lab Sample ID: 0007001-03
Lab File ID: 0700103D
Date Sampled: 06/30/00
Date Analyzed: 07/04/00
Dilution Factor: 5.0
0
0
0
D
0
Soil Extract Volume: ____ (uL) Soil Aliquot Volume: ___ (uL) U
CONCENTRATION UNITS:
CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q m
67-64-1---------Acetone
71-43-2---------Benzene
75-27-4---------Bromodichloromethane
75-25-2---------Bromoform
74-83-9---------Bromometharie
78-93-3---------2-Butanone
75-15-0---------Carbon disulfide
56-23-5---------Carbon tetrachloride
108-90-7--------Chlorobenzene
75-00-3---------Chloroethane
67-66-3---------Chloroform
74-87-3---------Chloromethane
124-48-1--------Dibromochloromethane
75-34-3---------1, 1-Dichloroe.thane
107-06-2--------1,2-Dichloroethane
75-35-4---------1,1-Dichloroethene
156-59-2--------cis-l,2-Dichloroethene
156-60-5--------trans-l,2-Dichloroethene
78-87-5---------1,2-Dichloropropane --
10061-01-5------cis-l,3-Dichloropropene
10061-02-6------trans-l,3-Dichloropropene __
100-41-4--------Ethylbenzene .
591-78-6--------2-Hexanone
75-09-2---------Methylene chloride
108-10-1--------4-Methyl-2-pentanone
100-42-5--------Styrene
79-34-5---------1,1,2,2-Tetrachloroethane __
127-18-4--------Tetrachloroethene
108-88-3--------Toluene
71-55-6---------1,1,1-Trichloroethane
79-00-5---------1,1,2-Trichloroethane
79-01-6---------Trichloroethene
FORM I VOA
250
50
50
50
100
500
50
50
50
100
47
100
50
50
50
50
18
50
50
50
50
50
100
50
100
50
50
770
50
50
50
10
UD
UD
UD
UD
UD
UD
UD
UD
UD
UD
JD
UD
UD
UD
UD
UD
JD
UD
UD
UD
UD
UD
UD
UD
UD
UD
UD
D
UD
UD
UD
JD
D
n
u
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n
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0
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FORM 1 _ . . CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEETi, C O 5 7
EW-4
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No.: NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
Soil Extract Volume: ____ (uL)
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330~20-7-------Xylene(total)
SAS No.: NA SDG No.: FCX.V07001
Lab Sample ID: 0007001-03
Lab File ID: 0700103D
Date Sampled: 06/30/00
· Date Analyzed: 07/04/00
Dilution Factor: 5.0
Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
100 UD
50 UD
FORM I VOA
FORM 1 CLIENT SAl"!PLE NO. VOLATILE ORGANICS ANALYSIS DATA illIBf c i.; :; 8
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY EW-1/ SW-1
Lab Code: NA Batch No.: NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
1/JW
ID: 0.53 (mm)
SAS No.: NA SDG No.: FCX.V07001
Lab Sample ID:
Lab File ID:
Date Sampled:
0007001-04
0700,~
06/30/00
Date Analyzed: 07/05/00
Dilution Factor: 1.0
D
0
Soil Extract Volume: ____ (uL) Soil Aliquot Volume: ___ (uL) 0
CONCENTRATION UNITS:
CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q
67-64-1---------Acetone 50 u
71-43-2---------Benzene 10 u 75-27-4---------Bromodichloromethane 1.4 J 75-25-2---------Bromoform 10 u 74-83-9---------Bromomethane 20 u
78-93-3---------2-Butanone 100 u 75-15-0---------Carbon disuifia:e 10 u 56-23-5---------Carbon tetrachloria:e 10 u 108-90-7--------Chlorobenzene 10 u
75-00-3---------Chloroethane 20 u
67-66-3---------Chloroform 38
74-87-3---------Chloromethane 20 u
124-48-1--------Dibromochloromethane 10 u
75-34-3---------1,1-Dichloroethane 10 u
107-06-2--------1,2-Dichloroethane 10 u
75-35-4---------1,1-Dichloroethene 10 u
156-59-2--------cis-1 2-Dichloroethene . , 14
156-60-5--------trans-1 2-Dichloroethene 10 u . , --78-87-5----~-._~-1,2-Dichloropropane 10 u
10061-01-5------cis-1,3-Dichloropropene 10 u
10061-02-6------trans-1,3-Dichloropropene __ 10 u
100-41-4--------Ethylbenzene 10 u
591-78-6--------2-Hexanone 20 u
75-09-2---------Methylene chloria:e 10 u
108-10-1--------4-Methyl-2-pentanone 20 u
100-42-5--------Styrene 10 u
79-34-5---------1 1 2 2-Tetrachloroethane 10 u • , , , --.E" git, 127.-18-4-- - --- --Tetrachloroethene 230
108-88-3--------Toluene 10 u
71-55-6---------1 1 1-Trichloroethane , ,. 10 u
79-00-5---------1,1,2-Trichloroethane 10 u
79-01-6---------Trichloroethene 7.7 J
FORM I VOA
0
D
D
0
g
I
m
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g
m
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a
u
I
D
0
0
D
D
D
'
0
u
FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHPz:'C ,J 5 '3
EW-1/ SW-1 Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No. : NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
----
ID: 0 .53 (mm)
Soil Extract Volume: ____ (uL)
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
SAS No.: NA SDG No.: FCX.V07001
Lab Sample ID: 0007001-04
Lab File ID: 0700104
Date Sampled: 06/30/00
Date Analyzed: 07/05/00
Dilution Factor: 1.0
Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
20 u
10 u
FORM I VOA
FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA ,-~~ ,] S J
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY EW-1/ SW-1
Lab Code: NA Batch No.: NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0. 53 (mm)
SAS No.: NA SDG No.: FCX.V07001
Lab Sample ID: 0007001-04
Lab File ID: 0700104D
Date Sampled: 06/30/00
Date Analyzed: 07/06/00
Dilution Factor: 5.0
B
m
m
D
I
Soil Extract Volume: ____ (uL) Soil Aliquot Volume: ___ (uL) u
CONCENTRATION UNITS:
CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q
67-64-1---------Acetone 250 UD
71-43-2---------Benzene so UD 75-27-4---------Bromodichloromethane so UD 75-25-2---------Bromoform so UD 74-83-9---------Bromomethane 100 UD
78-93-3---------2-Butanone 500 UD 75-15-0---------Carbon disuI:fiae so UD 56-23-5---------Carbon tetrachloriae so UD
108-90-7--------Chlorobenzene so UD
75-00-3---------Chloroethane 100 UD
67-66-3---------Chloroform so D 74-87-3---------Chloromethane 100 UD
124-48-1--------Dibromochloromethane so UD
75-34-3---------1,1-Dichloroethane so UD 107-06-2--------1,2-Dichloroethane so UD
75-35-4---------1,1-Dichloroethene so UD
156-59-2--------cis-1 2-Dichloroethene . , . 20 JD
156-60-5--------trans-1,2-Dichloroethene __ so UD 78-87-5---------1,2-Dichloropropane so UD
10061-01-5------cis-1,3-Dichloropropene so UD
10061-02-6------trans-1,3-Dichloropropene_ so UD
100-41-4--------Ethylbenzene so UD
591-78-6----~---2-Hexanone 100 UD
75-09-2---------Methylene chloriae so UD
108-10-1--------4-Methyl-2-pentanone 100 UD
100-42-5--------Styrene so UD 79-34-5---------1,1,2,2-Tetrachloroethane_ so UD
127-18-4--------Tetrachloroethene 290 D
108-88-3--------Toluene . so UD
. 71-55-6---------1,1,1-Trichloroethane so UD
79-00-5---------1,1,2-Trichloroethane so UD
79-01-6---------Trichloroethene 9.8 JD
FORM I VOA
D
u
D
0
D
0
0
D
0
0
0
D
g
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•
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FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS Al'JALYSIS DATA SHEET,-,-.-.,., , · vvV'Oi
EW-1/ SW-1 Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No . : NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
----
ID: 0 • 53 (mm)
Soil Extract Volume : ____ (uL)
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
SAS No.: NA SDG No.: FCX.V07001
Lab Sample ID: 0007001-04
Lab File ID: 0700104D
Date Sampled: 06/30/00
Date Analyzed: 07/06/00
Dilution Factor: 5.0
Soil Aliquot Voluine:
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
100
50
___ (uL)
Q
UD
UD
FORM I VOA
FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEE't C ,J ~ 2
TRIP BLA
NK #1616
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No.: NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/rnL) ML
LOW
ID: 0.53 (mm)
SAS No.: NA SDG No.: FCX.V07001
Lab Sample ID: 0007001-05
Lab File ID: 0700105
Date Sampled: 06/30/00
· Date Analyzed: 07 /04/00
Dilution Factor: 1.0
D
D
u
fl
u
Soil Extract Volurne: ____ {uL) Soil Aliquot Volume:
CONCENTRATION UNITS:
__ (uL) m
CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q
67-64-1---------Acetone 50 u
71-43-2---------Benzene 10 u
75-27-4---------Bromodichloromethane 10 u 75-25-2---------Bromoforrn 10 u
74-83-9---------Brornomethane 20 u
78-93-3---------2-Butanone 100 u
75-15-0---------Carbon disuil:iae 10 u
56-23-5---------Carbon tetrachloriae 10 u
108-90-7--------Chlorobenzene 10 u
75-00-3---------Chloroethane 20 u
67-66-3---------Chloroforin 10 u
74-87-3---------Chloromethane 20 u
124-48-1--------Dibrornochloromethane 10 u
75-34-3---------1,1-Dichloroethane 10 u
107-06-2--------1,2-Dichloroethane 10 u
75-35-4---------1,1-Dichloroethene 10 u
156-59-2--------cis-l,2-Dichloroethene 10 u
156-60-5-------~trans-l 2-Dichloroethene 10 u , --78-87-5---------1,2-Dichloropropane 10 u
10061-01-5------cis-l,3-Dichloropropene 10 u
10061-02-6------trans-1,3-Dichloropropene __ 10 u
100-41-4----~---Ethylbenzene 10 u
591-78-6--------2-Hexanone 20 u
75-09-2---------Methylene chloriae 4.6 J
108-10-1--------4-Methyl-2-pentanone 20 u
100-42-5--------Styrene 10 u
79-34-5---------1,1,2,2-Tetrachloroethane __ 10 u
127-18-4----- --.-Tetrachloroethene 10 u
108-88-3--------Toluene 10 u
71-55-6-------~-l,l,l-Trichloroethane 10 u
79-00-5---------1,1,2-Trichloroethane 10 u
79-01-6---------Trichloroethene 10 u
FORM I VOA
m
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FORM 1 CLIENT SAl"IPLE NO.
VOLATILE ORGANICS AJ.W\LYSIS DATA SHEETr r, ;, ~ ~ 1.Jv-.,-.IV TRIP BLA
NK #1616 Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No.: NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0. 53 (mm)
Soil Extract Volume: ____ (uL)
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
SAS No.: NA SDG No.: FCX.V07001
Lab Sample ID: 0007001-05
Lab File ID: 0700105
Date Sampled: 06/30/00
Date Analyzed: 07/04/00
Dilution Factor: 1.0
Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
20 u
10 u
FORM I VOA
FORM 2
WATER VOLATILE SYSTEM MONITORING COMPOUND RECOVERY r ,"\ "". ,-, .:, \.,".J'J-r...:i
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No.: NA SAS No.: NA SDG No.: FCX.V06137
page 1 of 1
CLIENT SMCl SMC2 SMC3 SMC4 TOT
SAMPLE NO. (DFM) # (DCE) # (TOL)# (BFB) # our
============ ======= ====== ====== ====== === V1BLK0704 101 111 100 99 0 TRIP BLANK# 103 112 101 97 0 EW-6 106 118* 102 101 1 EW-8 104 114 103 99 0
EW-7 100 111 102 103 0
01
02
03
04
05
06 EW-2 104 114 · · 101 · 97 0 07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
SMCl
SMC2
SMC3
SMC4
(DFM)
(DCE)
(TOL)
(BFB)
= Dibromofluoromethane
= 1,2-Dichloroethane-d4
= Toluene-dB
= Bromofluorobenzene
-
-
-
-
-------------------
-
QC LIMITS
(86-118)
(76-114)
(88-110)
(86-115)
# Column to be used to flag recovery values
* Values outside of contract required QC limits
D System Monitoring Compound diluted out
FORM II VOA
I
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FORM 2
WATER VOLATILE SYSTEM MONITORING COMPOUND RECOVERY
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA
page 1 of 1
Batch No.: NA SAS No.: NA SDG No.: FCX.V06144
CLIENT SMCl SMC2 SMC3 SMC4 TOT
SAMPLE NO. (DFM) # (DCE)# (TOL)# (BFB) # OUT ============ ====== ====== ====== ====== === V1BLK0704 101 111 100 01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
TRIP BLANK# 104 112 101
MP-8
MP-9
MP-10
EW-5
VlBLK0705
MP-9
MP-14
VlBLK0706
MP-10
SMCl
SMC2
SMC3
SMC4
(DFM)
(DCE)
(TOL)
(BFB)
102 114 100
102 115* 103
104 117* 102
105 117* . 103
98 107 .94
100 108 95
95 104 93
99 111 95
100 112 98
.
= Dibromofluoromethane
= l,2-Dichloroethane-d4
= Toluene-de ·
= Bromofluorobenzene
99 0
99 0
98 0
101 1
102 1
104 1
90 0
88 0
88 0
87 0
91 0
-
-
--
--------
---
QC LIMITS
(86-118)
(76-114)
(88-110)
(86-115)
# Column to be used to flag recovery values
* Values outside of contract required QC limits
D System Monitoring Compound diluted out
FORM II VOA
FORM 2
WATER VOLATILE SYSTEM MONITORING COMPOUND RECOVERY
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA
page 1 of 1
Batch No.: NA SAS No.: NA SDG No.: FCX.V07001
CLIENT SMCl SMC2 SMC3 SMC4 TOT
SAMPLE NO. (DFM) # (DCE) # (TOL)# (BFB) # OUT =--==:;;:====== ====== ====== ::;;==::::::== ====== === V1BLK0704 101 111 100 01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
TRIP BLANK# 105 112 99
EW-3 104 110 99
EW-4 102 113 103
V1BLK0705 98 107 94
EW-3 DUPE 101 104 92
EW-1/ SW-1 98 105 95
V1BLK0706 99 111 95
EW-1/ SW-1 100 112 98
EW-3MS
EW-3MSD
SMCl
SMC2
SMC3
SMC4
(DFM)
(DCE)
(TOL)
(BFB)
98 106 96
98 110 96
= Dibromofluoromethane
= l,2-Dichloroethane-d4
= Toluene-dB
= Bromofluorobenzene
99 0
98 0
97 0
104 0
90 0
86 0
95 0
87 0
100 0
90 0
89 0
------
----
-
-------
-
QC LIMITS
(86-118)
(76-114)
(88-110)
(86-115)
# Column to be used to flag recovery values
* Values outside of contract required QC limits
D System Monitoring Compound diluted out
FORM II VOA
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ff
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FORM 3
WATER VOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY , ....... , _.., _,,.. ~
1..,;.,·~-C(
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA
Matrix Spike
Batch No.: NA SAS No.: NA SDG No.: FCX.V07001
Client Sample No.: EW-3 Lab Sample ID: 0007001-01
SPIKE SAMPLE MS MS QC.
ADDED CONCENTRATION CONCENTRATION % LIMITS COMPOUND (ug/L) (ug/L) (ug/L) REC # REC. ======================== ========= =:::::=========----=========== ====== ==:::;::=== Benzene 50.00 0.0000 48.12 96 76-127 . · Chlorobenzene 50.00 0.0000 47.61 95 75~130 1,1-Dichloroethene ·so.co 0.0000 49.10 98 61-145 Toluene 50.00 0.0000 45.45 91 76-125 Trichloroethene 50.00 3.076 53.04 100 71-120
SPIKE MSD MSD
ADDED CONCENTRATION % % QC LIMITS
COMPOUND (ug/L) (ug/L) REC # RPD # RPD ======================== =::;;======= ============= ====== ====== ====== Benzene 50.00 48.14 96 0 11 Chlorobenzene 50.00 48.16 96 1 13
1,1-Dichloroethene 50.00 48.47 97 1 14 Toluene 50.00 45.59 91 0 13 Trichloroethene 50.00 52.87 100 0 14
# Column to be used to flag recovery and RPD values with an asterisk
* Values outside of QC limits
RPD: 0 out of 5 outside limits
Spike Recovery: 0 out of 10 outside limits
COMMENTS:
· FORM III VOA
REC.
:;;::;::::;::::;::::;::::;::
76-127
75-130
61-145
76-125
71-120
FORM 4
VOLATILE METHOD BLANK SUMMARY
r ..-, ,-; ~ ~
'v 'v >J ..,0 CLIENT SAMPLE NO. u
V1BLK0704
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No.: NA
Lab File ID: VlBLK0l
_ Date Analyzed: 07/04/00
GC Column: DB-624
Instrument ID: VOAl
ID: 0. 53 (mm)
SAS No.: NA SDG No.: FCX.V06137
Lab Sample ID: V1BLK0704
Time Analyzed: 1745
Heated Purge: (Y/N) N
THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, _MS and MSD:
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
_16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
COMMENTS:
page 1 of 1
SAMPLE NO.
------------TRIP BLANK #
EW-6
EW-8
EW-7
EW-2
LAB LAB TIME.
SAMPLE ID FILE ID ANALYZED
-------------------------------.------
0006137-05 0613705 1816
0006137-04 0613704D 2155
0006137-01 0613701D 2227
0006137-02 0613702D 2329
0006137-03 0613703D 0135
.
FORM IV VOA
fl
m
m
0
u
D
D
D
D
D
0
D
D
D
D
D
D
D
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FORM 4 CLIENT SAMPLE NO.
VOLATILE METHOD BLANK SUMMARY
V1BLK0704
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No.: NA SAS No.: NA SDG No.: FCX.V06144
Lab File ID: VlBLK0l
Date Analyzed: 07/04/00
GC Column: DB-624
Instrument ID: VOAl
ID: 0. 53 (mm)
Lab Sample ID: V1BLK0704
Time Analyzed: 1745
Heated Purge: (Y/N) N
THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS and MSD:
COMMENTS:
01
02
03
04
05
06
07
08
09
10
11
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13
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page 1 of 1
SAMPLE NO.
------------TRIP BLANK #
MP-8
MP-9
MP-10
EW-5
LAB LAB 'TIME
SAMPLE ID FILE ID ANALYZED ============== ============== ==========
0006144-06 0614406 1847
0006144-05 0614405D 2258
0006144-02 0614402D 0001
0006144-04 0614404D 0032
0006144-01 0614401D 0206
FORM IV VOA
FORM 4
VOLATILE METHOD BLANK SUMMARY CLIENT 811.MPLE NO.
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY V1BLK0704
Lab Code: NA Batch No.: NA SAS No.: NA SDG No.: FCX.V07001
Lab File ID: VlBLK0l
Date Analyzed: 07/04/00
GC Column: DB-624
Instrument ID: VOA1
ID: o. 53 (mm)
Lab Sample ID: VlBLK0704
Time Analyzed: 1745
Heated Purge: (Y/N) N
THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS and MSD:
COMMENTS:
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
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page 1 of 1
SAMPLE NO.
============
TRIP BLANK # EW-3
EW-4
.
LAB LAB TIME
SAMPLE ID FILE ID ANALYZED ============== ============== ========== 0007001-05 0700105 1919
0007001-01 0700101 1950
0007001-03 0700103D 2124
.
FORM IV VOA
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FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET CC iJ 71
V1BLK0704
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA . Batch No.: NA SAS No.: NA SDG No.: FCX.V06137
Matrix: (soil/water) WATER Lab Sample ID: V1BLK0704
Sample wt/vol:
Level: (low/med)
5.000 (g/mL) ML
LOW
Lab File ID: VlBLK0l
Date Sampled:
% Moisture: not dee. Date Analyzed: 07/04/00
GC Column: DB-624 ID: 0. 53 (mm)
Soil Extract Volume: (uL) ----
Dilution Factor: 1.0
Soil Aliquot Volume:
CAS NO. COMPOUND
67-64-1---------Acetone
71-43-2---------Benzene
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
75-27-4---------Bromodichloromethane
75-25-2---------Bromoform
74-83-9---------Bromomethane
78-93-3---------2-Butanone
75-15-0---------Carbon disulfioe
56-23-5---------Carbon tetrachlorioe
108-90-7--------Chlorobenzene
75-00-3---------Chloroethane
67-66-3---------Chloroform
74-87-3---------Chloromethane
124-48-1--~-----Dibromochloromethane
75-34-3---------1,1-Dichloroethane
107-06-2--------1,2-Dichloroethane
75-35-4---------1,1-Dichloroethene
156-59-2------~-cis-1,2-Dichloroethene
156-60-5--------trans-1,2-Dichloroethene __
78-87-5---------1,2-Dichloropropane
10061-01-5------cis-1,3-Dichloropropene
10061-02-6--~---trans-1,3-Dichloropropene __
100-41-4--------Ethylbenzene
591-78-6--------2-Hexanone
75-09-2---------Methylene chlorioe
108-10-1--------4-Methyl-2-pentanone
100-42-5--------Styrene
79-34-5---------1,1,2,2-Tetrachloroethane __
127-18-4--------Tetrachloroethene
108-88-3--------Toluene
71-55-6---------1,1,1-Trichloroethane
79-00-5---------1,1,2-Trichloroethane
79-01-6---------Trichloroethene
FORM I VOA
50
10
10
10
20
100
10
10
10
20
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20
10
10
10
10
10
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10
10
10
20
10
20
10
10
10
10
10
10
10
___ (uL)
Q
u
u u
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u u u
u u
u u u u
u u u u
u
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u u
u u
u u u
u
u
u u
u
u
FORM 1 CLIENT SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET ,-'' ··~ '"7 0
'.., 'v 1
"' Ii M
Lab Name : ECKENFELDER LLC Contract : EL PASO ENERGY
VlBLK0704
Lab Code: NA Batch No.: NA SAS No.: NA SDG No.: FCX.V06137
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
5.000 (g/mL) ML
LOW
----
GC Column: DB-624 ID: 0. 53 (mm)
Soil Extract Volurne:~~--(uL)
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
Lab Sample ID: VlBLK0704
Lab File ID: VlBLKOl
Date Sampled:
Date Analyzed: 07/04/00
Dilution Factor: 1.0
Soil Aliquot Volume: __ _
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
20
10
Q
u u
FORM I VOA
(uL)
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FORM 4 CLIENT SAMPLE NO. VOLATILE MET'dOD BLANK SUMMARY
V1BLK0705
Lab Name : ECI<ENFELDER LLC Contract : EL PASO ENERGY
Lab Code: NA Batch No.: NA SAS No.: NA SDG No.: FCX.V07001
Lab File ID: V1BLK03
Date Analyzed: 07/05/00
GC Column: DB-624
Instrument ID: VOAl
ID: 0.53 (mm)
Lab Sample ID: V1BLK0705
Time Analyzed: 1313
Heated Purge: (Y/N) N
THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS and MSD:
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
.19 . 20
COMMENTS:
21
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29
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page 1 of 1
SAMPLE NO.
============
EW-3 DUPE
EW-1/ SW-1
LAB LAB TIME
SAMPLE ID FILE ID ANALYZED
;;============= ========::;;:====== =====:;::::====
0007001-02 0700102 1359
0007001-04 0700104 1446
FORM IV VOA
FORM 4
VOLATILE METHOD BLANK SUMMARY CLIENT SAMPLE NO. I
V1BLK0705
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No.: NA
Lab File ID: V1BLK03
Date Analyzed: 07/05/00
GC Column: DB-624
Instrument ID: VOAl
ID: 0.53 (mm)
SAS No.: NA SDG No.: FCX.V06144
Lab Sample ID: V1BLK0705
Time Analyzed: 1313
Heated Purge: (Y/N) N
THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS and MSD:
COMMENTS:
01
02
03
04
05
06
07
08
09
10
11
12
13
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16
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18
19
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page 1 of 1
SAMPLE NO.
============ MP-9
MP-14
LAB LAB TIME
SAMPLE ID FILE ID ANALYZED
============== =======-----------------0006144-02 0614402D 1637
0006144-03 0614403D 1708
.
FORM IV VOA
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FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET
VlBLK0705
Lab Name: ECKENFEWER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FCX.V06144
Matrix: (soil/water) WATER Lab Sample ID: VlBLK0705
Sample wt/vol:
Level: (low/med)
5.000 (g/mL) ML
LOW
Lab File ID:
Date Sampled:
VlBLK03
% Moisture: not dee. Date Analyzed: 07/05/00
GC Column: DB-624 ID: 0.53 (rran)
Soil Extract Volume: ____ (uL)
Dilution Factor: 1.0
Soil Aliquot Volume:
CONCENTRATION UNITS:
___ (uL)
CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q
67-64-1---------Acetone 50 u
71-43-2---------Benzene 10 u
75-27-4---------Bromodichloromethane 10 u
75-25-2--~------Bromofo:rm 10 u
74-83-9---------Bromomethane 20 u
78-93-3---------2-Butanone 100 u
75-15-0---------Carbon disulfiae 10 u
56-23-5---------Carbon tetrachloriae 10 u
108-90-7--------Chlorobenzene 10 u
75-00-3---------Chloroethane 20 u
67-66-3---------Chlorofo:rm 10 u
74-87-3---------Chloromethane 20 u
124-48-1--------Dibromochloromethane 10 u
75-34-3---------1,1-Dichloroethane 10 u
107-06-2--------1,2-Dichloroethane 10 u
75-35-4---------1 1-Dichloroethene 10 u ' . . 156-59-2------~-cis-l,2-Dichloroethene .10 u
156-60-5--------trans~l,2-Dichloroethene __ 10 u
78-87-5-------~-l,2-Dichloropropane 10 u
10061-01-5------cis-l,3-Dichloropropene 10 u
10061-02-6------trans-l,3-Dichloropropene __ 10 u
100-41-4--------Ethylbenzene 10 u
591-78-6--------2-Hexanone 20 u
75-09-2---------Methylene chloriae 10 u
108-10-1--------4-Methyl-2-pentanone 20 u
100-42-5--------Styrene 10 u
79-34-5---------1,1,2,2-Tetrachloroethane __ 10 u
127-18-4--------Tetrachloroethene 10 u
108-88-3--------Toluene 10 u
71-55-6---------1,1,1-Trichloroethane 10 u
79-00-5---------1,1,2-Trichloroethane 10 u
79-01-6---------Trichloroethene 10 u
FORM I VOA
FORM 1 CLIENT SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET
V1.BLK0705 Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No.: NA SAS No.: NA SDG No.: FClLV06144
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
Soil Extract Volume , ____ (uL)
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
Lab Sample ID: V1.BLK0705
Lab File ID: V1BLK03
Date Sampled:
Date Analyzed: 07/05/00
Dilution Factor: 1.0
Soil Aliquot Volume: __ _
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
20
10
Q
u u
FORM I VOA
(uL)
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FORM 4 CLIENT SAMPLE NO. VOLATILE METHOD BLANK SUMMARY
V1BLK0706
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FCX.V06144
Lab File ID: VlBLK0l
Date Analyzed: 07/06/00
GC Column: DB-624
Instrument ID: VOA1
ID: 0.53 (mm)
Lab Sample ID: V1BLK0706
Time Analyzed: 1005
Heated Purge: (Y/N) N
THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS and MSD:
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
COMMENTS:
page 1 of 1
SAMPLE NO.
------------MP-10
LAB LAB TIME·
SAMPLE ID FILE ID ANALYZED
--------------===::;:;========== ========== 0006144-04 0614404D 1112
FORM IV VOA
FORM 4 CLIENT SAMPLE NO. VOLATILE METHOD BLANK SUMMARY
V1BLK0706
Lab Name : ECKENFELDER LLC Contract : EL PASO ENERGY
Lab Code: NA Batch No. : NA
Lab File ID: V1BLK01
Date Analyzed: 07/06/00
GC Column: DB-624 ID: 0.53 (mm)
Instrument ID: VOA1
SAS No.: NA SDG No.: FCX.V07001
Lab Sample ID: V1BLK0706
Time Analyzed: 1005
Heated Purge: (Y/N) N
THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS and MSD:
COMMENTS:
page 1 of 1
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
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28
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30
SAMPLE NO.
------------EW-1/ SW-1
EW-3MS
EW-3MSD
.
LAB LAB TIME
SAMPLE ID FILE ID ANALYZED
============== =======-------========== 0007001-04 0700104D 1040
0007001-01 700101MB 1216
0007001-01 700101.MD 1248
FORM IV VOA
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FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEE'.( ,: ,: i 9
V1BLK0706 Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No.: NA SAS No.: NA SDG No.: FCX.V06144
Matrix: (soil/water) WATER Lab Sample ID: V1BLK0706
Sample wt/vol:
Level: (low/med)
5.000 (g/mL) ML
LOW
Lab File ID: VlBLK0l
Date Sampled:
% Moisture: not dee.
GC Column: DB-624 ID: 0.53 (mm)
Date Analyzed: 07/06/00
Dilution Factor: 1.0
Soil Extract Volume: ____ (uL) Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q
67-64-1---------Acetone so u
71-43-2---------Benzene 10 u
75-27-4---------Bromodichloromethane 10 u
75-25-2---------Bromoform 10 u
74-83-9---------Bromomethane 20 u
78-93-3---------2-Butanone 100 u
75-15-0---------Carbon disuifiae 10 u
56-23-5---------Carbon tetrachloriae 10 u
108-90-7--------Chlorobenzene 10 u
75-00-3---------Chloroethane 20 u
67-66-3---------Chloroform 10 u
74-87-3---------Chloromethane 20 u
124-48-1--------Dibromochloromethane 10 u
75-34-3---------1,1-Dichloroethane 10 u
107-06-2--------1,2-Dichloroethane 10 u
75-35-4-------~-1,1-Dichloroethene 10 u
156-59-2-------~cis-1,2-Dichloroethene . 10 u
156-60-5--------trans-1 2-Dichloroethene 10 u , . --78-87-5---------1,2-Dichloropropane 10 u
10061-01-5------cis-1,3-Dichlorbpropene 10 u
10061-02-6------trans-1,3-Dichloropropene __ 10 u
100-41-4--------Ethylbenzene . 10 u
591-78-6--------2-Hexanone 20 u
75-09-2---------Methylene chloriae 10 u
108-10-1--------4-Methyl-2-pentanone 20 u
100-42-5--------Styrene 10 u
79-34-5---------1 1 2 2-Tetrachloroethane 10 u , , ' --127-18-4--------Tetrachloroethene 10 u
108-88-3--------Toluene 10 u
71-55-6---------1,1,1-Trichloroethane 10 u
79-00-5---------1,1,2-Trichloroethane 10 u
79-01-6---------Trichloroethene 10 u
FORM I VOA
FORM 1 r , ... ;-~ f.'; 0
V V V 0 CLIENT SAMPLE NO•
VOLATILE ORGANICS ANALYSIS DATA SHEET
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY V1BLK0706
Lab Code: NA Batch No.: NA SAS No.: NA SDG No.: FCX.V06144
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
Soil Extract Volume: (uL) ---
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
Lab Sample ID: V1BLK0706
Lab File ID: VlBLK0l
Date Sampled:
Date Analyzed: 07/06/00
Dilution Factor: 1.0
Soil Aliquot Volume: __ _
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
20
10
Q
u u
FORM I VOA
(uL)
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FORM 8
VOLATILE INTERNAL STANDARD AREA AND RT SUMMARY
Lab Name : ECKENFELDER LLC Contract : EL PASO ENERGY
r..-,-;O'l ·v ·v'v ~ i.
Lab Code: NA Batch No.: NA SAS No.: NA SDG No.: FCJ{.V06137
Lab File ID (Standard): VlSTDX3
Instrument ID: VOAl
Date Analyzed: 07/04/00
Time Analyzed: 1642
Heated Purge: (Y/N) N GC Column: DB-624 ID: 0. 53 (mm)
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
------------12 HOUR STD
UPPER LIMIT
LOWER LIMIT
============ CLIENT
SAMPLE NO.
------------VlBLK0704
TRIP
EW-6
EW-8
EW-7
EW-2
ISl
IS2
IS3
BLANK
(PFB)
(FLB)
(CBZ)
#
ISl(PFBJ IS21FLB1
AREA # RT # AREA #
========== ======= ========== 279331 6.73 586029
558662 7.23 1172058
139666 6.23 293015
===;;::;::;:;::;::;:=== ======= ==========
----------======= ----------278512 6.74 578919
279912 6.74 580622
266350 6.74 553292
270552 6.74 556415
246465 6.74 530106
260155 6.73 550242
= Pentafluorobenzene
= Fluorobenzene
= Chlorobenzene-dS
RT #
=======
7.65
8.15
7.15
=======
=======
7.65
7.64
7.64
7.65
7.64
7.64
AREA UPPER LIMIT= +100% of internal standard area
AREA LOWER LIMIT= -50% of internal standard area
IS3 (CBZ)
AREA # -=========
371142
742284
185571
=:::======-=
==========
375439
368835
362061
368752
352403
357629
RT UPPER LIMIT=+ 0.50 minutes of internal standard RT
RT LOWER LIMIT= -0.50 minutes of internal standard RT
RT #
=======
12.11
12.61
11.61
===::::;;;;::::::::
===::===
12.10
12.11
12.11
12.11
12.11
12.11
# Column used to flag values outside QC limits with an asterisk.
* Values outside of QC limits.
page 1 of 2
FORM VIII VOA
FORM 8
VOLATILE INTERNAL STANDARD AREA AND RT SUMMARY
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No.: NA SAS No.: NA SDG No.: FCX.V06137
Lab File ID (Standard) : V1STDX3
Instrument ID : VOA1
GC Column: DB-624 ID: 0. 53 (mm)
IS4(DCB)
AREA # RT #
Date Analyzed: 07/04/00
Time Analyzed: .1642
Heated Purge: (Y/N) N
AREA # RT # AREA # ============ ==::;;::======= ===:;;:;=== ----------======= ==========
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
12 HOUR STD 164331 15.65
UPPER LIMIT 328662 16.15
LOWER LIMIT 82166 15.15
----------------------======= ========== ======= CLIENT
SAMPLE NO.
============ ----------======= ========== ======= VlBLK0704 160281 15.65
TRIP BLANK # 150501 15.65
EW-6 151085 15.64
EW-8 149065 15.65
EW-7 147532 15.65
EW-2 155877 15.65 .
IS4 (DCB) = l,4-Dichlorobenzene-d4
AREA UPPER LIMIT= +100% of internal standard area
AREA LOWER LIMIT= -50% of internal standard area
==========
==========
RT UPPER LIMIT=+ 0.50 minutes of internal standard RT
RT LOWER LIMIT= -0.50 minutes of internal standard RT
RT # ==;:;:====
=======
=======
# Column used to flag values outside QC limits with an asterisk.
* Values outside of QC limits.
page 2 of 2
. FORM VIII VOA
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FORM 8
VOLATILE INTERNAL STANDARD AREA AND RT SUMMARY ,-'"' , .... Q ':'"J 'v •v:..; U J
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No.: NA SAS No.: NA SDG No.: FCX.V06144
Lab File ID (Standard): V1STDX3
Instrument ID: VOA1
Date Analyzed: 07/04/00
Time Analyzed: 1642
Heated Purge: (Y/N) N GC Column: DB-624 ID: 0. 53 (mm)
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
------------12 HOUR STD
UPPER LIMIT
LOWER LIMIT
------------CLIENT
SAMPLE NO.
------------V1BLK0704
TRIP
MP-8
MP-9
MP-10
EW-5
ISl
IS2
IS3
BLANK
(PFB)
{FLB)
(CBZ)
#
ISl(PFB) IS2(FLB)
AREA # RT # AREA #
========== ======= ========== 279331 6.73 586029
·. 558662 7.23 1172058
139666 6.23 293015 ========== ======= ----------
========== ======= ===:====== 278512 6.74 578919
272758 6.74 580985
259711 6.73 557467
260352 6.73 542144
256205 6.73 540560
249291 6.74 517738
.
= Pentafluorobenzene
= Fluorobenzene
= Chlorobenzene-dS
RT #
======= 7.65
8.15
7.15
=:;:;:=====
=======
7.65
7.64
7.65
7.64
7.64
7.64
AREA UPPER LIMIT= +100% of internal standard area
AREA LOWER LIMIT= -50% of internal standard area
IS3 (CBZ)
AREA # ========== 371142
742284
185571
=======:;:==
=;;::::=========
375439
368949
354069
358927
359797
343923
RT UPPER LIMIT=+ 0.50 minutes of internal standard RT
RT LOWER LIMIT= -0.50 minutes of internal standard RT
RT #
======= 12.11
12.61
11.61
=======
======= 12.10
12.11
12.10
12.11
12.10
12.10
# Column used to flag values outside QC limits with an asterisk.
* Values outside of QC limits .
page 1 of 2
FORM VIII VOA
FORM 8
VOLATILE INTERNAL STANDARD AREA AND RT SUMMARY
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FCX.V06144
Lab File ID (Standard): V1STDX3
Instrument ID: VOAl
Date Analyzed: 07/04/00
Time Analyzed: 1642
Heated Purge: (Y/N) N GC Column: DB-624 ID: 0. 53 (mm)
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
IS4 (DCB)
AREA # RT # AREA # RT # ------------========== ======= ----------======= 12 HOUR STD 164331 15.65 '
UPPER LIMIT 328662 16.15
LOWER LIMIT 82166 15.15
============ ========== ======= ----------======= CLIENT
SAMPLE NO.
------------========== ======= ----------::::::;;:::=:===
V1BLK0704 160281 15.65
TRIP BLANK # 156777 15.65
MP-8 152115 15.64
MP-9 157942 15.65
MP-10 144646 15.65
EW-5 145275 15.65
IS4 (DCB) = l,4-Dichlorobenzene-d4
AREA UPPER LIMIT= +100% of internal standard area
AREA LOWER LIMIT= -50% of internal standard area
AREA # ---=======
==========
=========::;;::
RT UPPER LIMIT=+ 0.50 minutes of internal standard RT
RT LOWER LIMIT= -a.so minutes of internal standard RT
RT #
=======
========
=======
# Column used to flag values outside QC limits with an asterisk. * Values outside of QC limits.
page 2 of 2
FORM VIII VOA
I
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I
I
n
g
I
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1·
I
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I
I FORM 8
VOLATILE INTERNAL STANDARD AREA AND RT SUMMARY
I Lab Name: ECKENFELDER LLC Contract : EL PASO ENERGY
I'
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I
B
D
u
I
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•
I
Lab Code: NA Batch No.: NA SAS No.: NA SDG No.: FCX.V07001
Lab File ID (Standard): V1STDX3
Instrument ID: VOAl
GC Column: DB-624 ID: 0.53
ISl (PFB)
AREA #
(mm)
RT #
Date Analyzed: 07/04/00
Time Analyzed: 1642
Heated Purge: (Y/N) N
IS2\FLBJ IS3 (CBZ)
AREA # RT # AREA # ------------=--======= ======= ----------======= =====-====
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
12 HOUR STD
UPPER LIMIT
LOWER LIMIT
------------CLIENT
SAMPLE NO.
========:;;:===
V1BLK0704
TRIP
EW-3
EW-4
ISl
IS2
IS3
BLANK
(PFB)
(FLB)
(CBZ)
#
279331 6.73 586029
558662 7.23 1172058
139666 6.23 293015
=---====== ======= ----------
========== ======= ========== 278512 6.74 578919
275164 6.74 579179
277347 6.74 584839
257656 6.74 541597
= Pentafluorobenzene
= Fluorobenzene
= Chlorobenzene-dS
7.65
8.15
7.15
=;;:=====
======= 7.65
7.65
7.65
7.65
AREA UPPER LIMIT= +100% of internal standard area
AREA LOWER LIMIT= -50% of internal standard area
371142
742284
185571
==========
==========
375439
375817
370083
352668
RT UPPER LIMIT=+ a.so minutes of internal standard RT
RT LOWER LIMIT= -a.so minutes of internal standard RT
RT # ======= 12.11
12.61
11.61
===::;;:====
===::::::=== 12.10
12.11
12.11
12.10
# Column used to flag values outside QC limits with an asterisk. * Values outside of QC limits.
page 1 of 2
FORM VIII VOA
FORM 8
VOLATILE INTERNAL STANDARD AREA AND RT SUMMARY
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FCX.V07001
Lab File ID (Standard): V1STDX3
Instrument ID: VOAl
Date Analyzed: 07/04/00
Time Analyzed: 1642
Heated Purge: (Y/N) N GC Column: DB-624 ID: 0.53 (mm)
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
'17
18
19
20
21
22
IS4 (DCB)
AREA # RT # AREA # RT # ============ =========== ======= ========== ======= 12 HOUR STD 164331 15.65
UPPER LIMIT 328662 16.15
LOWER LIMIT 82166 15.15 .. =------=----========== ======= ========== ======= CLIENT ,
SAMPLE NO.
========-==== ========== ====:;;::== ====-=--== ======= V1BLK0704 160281 15.65
TRIP BLANK # 156397 15.65 EW-3 156569 15.65
EW-4 155788 15.65
. '
IS4 (DCB) = l,4-Dichlorobenzene-d4
AREA UPPER LIMIT= +100% of internal standard area
AREA LOWER LIMIT= -50% of internal standard area
AREA #
--====-===
=====::::====
==========
RT UPPER LIMIT=+ a.so minutes of internal standard RT
RT LOWER LIMIT= -a.so minutes of internal standard RT
RT #
=======
=======
=======
# Column used to flag values outside QC limits with an asterisk. * Values outside of QC limits.
page 2 of 2
FORM VIII VOA
ll
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Im
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1·
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FORM 8
VOLATILE INTERNAL STANDARD AREA AND RT SUMMARY
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
r (' :"'; ~ i-: \.,vvv,
Lab Code: NA Batch No.: NA SAS No.: NA SDG No.: FCX.V06144
Lab File ID (Standard) : V1CCV01
Instrument ID: VOAl
GC Column: DB-624
12 HOUR STD
. UPPER. .LIMIT
LOWER LIMIT
::;::::;::::=========
CLIENT
SAMPLE NO.
============ 01 V1BLK0705
02 MP-9
03 MP-14
ID: 0.53 (mm)
ISl (PFB)
AREA #
==========
240669
481338
120335
==========
==========
233681
247089
243639
RT #
=======
6.73
7.23
6.23
=======
6.74
6.73
6.74
Date Analyzed: 07/05/00
Time Analyzed: 1016
Heated Purge: (Y/N) N
IS2 (FLB)
AREA #
497742
995484
248871
514203
507566
517239
RT #
======= 7.64
8.14
7.14
====:;:;:==
======= 7.65
7.64
7.64
IS3(CBZ)
AREA #
========== 366498
732996
183249
==========
========== 358311
348817
348276
RT #
======= 12.11
12.61
11.61
======= 12.11
12.11
12.11
~:1------1-----1---·-,---------1-----1----
06 -----------------------1---------
07 ------1-----------------1---------08 ------
09 ------1------1---------------------10 ------11 , _____ , ___ -----
---12 ______ , -----1 13 ,----
14 --------
15 ------1------1---------------------
16 -----·-1-----1---1-----------------'--
17 ------1------1----1-----------------18 ______ , ______ ,
19 ---20 l-----
1----
21 ------1----------1-----1---------1----22 ______ , __________ , _____ , _________ , ___ _
ISl
IS2
IS3
(PFB)
(FLB)
(CBZ)
= Pentafluorobenzene
= Fluorobenzene
= Chlorobenzene-d5
AREA UPPER LIMIT= +100% of internal standard area
AREA LOWER LIMIT= -SO% of internal standard area
· RT UPPER LIMIT = + 0. SO minutes of internal standard RT
RT LOWER LIMIT= -a.so minutes of internal standard RT
# Column used to flag values outside QC limits with an asterisk. * Values outside of QC limits.
page 1 of 2
FORM VIII VOA
FORM 8
VOLATILE INTERNAL STAJ.'IDARD AREA AND RT SUMMARY
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No.: NA SAS No.: NA SDG No.: FCX.V06144
Lab File ID (Standard) : VlCCV0l
Instrument ID: VOA1
GC Column: DB-624 ID: 0. 53 (rmn)
IS4(DCBJ
AREA # RT #
Date Analyzed: 07/05/00
Time Analyzed: 1016
Heated Purge: (Y/N) N
AREA # RT # AREA # ------------========== ======= ----------======= ---=======
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
12 HOUR STD 155679 15.65
UPPER LIMIT 311358 16.15
LOWER LIMIT 77840 15.15
============ ----------======= ----------======= CLIENT
SAMPLE NO.
============ ========== ======= =::;::======== =======
VlBLK0705 150239 15.65
MP-9 153435 15.65
MP-14 150784 15.66
IS4 (DCB) = l,4-Dichlorobenzene-d4
AREA UPPER LIMIT= +100% of internal standard area
AREA LOWER LIMIT= -50% of internal standard area
==========
==========
RT UPPER LIMIT=+ 0.50 minutes of internal standard RT
RT LOWER LIMIT= -0.50 minutes of internal standard RT
RT # =======
=======
=======
# Column used to flag values outside QC limits with an asteri.sk.
* Values outside of QC limits.
page 2 of 2
FORM VIII VOA
I
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FORM 8
VOLATILE INTERNAL STANDARD AREA AND RT SUMMARY
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No.: NA SAS No.: NA SDG No.: FCX.V07001
Lab File ID (Standard): VlCCV0l
Instrument ID: VOAl
Date Analyzed: 07/05/00
Time Analyzed: 1016
Heated Purge: (Y/N) N GC ColUIIIIl: DB-624 ID: 0.53 (mm)
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
============ 12 HOUR STD
UPPER LIMIT
LOWER LIMIT
=======:;;;:===::;::
CLIENT
SAMPLE NO.
============ V1BLK0705
EW-3
EW-1/
.
ISl
IS2
IS3
DUPE
SW-1
(PFB)
(FLB)
(CBZ)
ISl(PFB) IS2(FLB)
AREA # RT # AREA # ========== ======= ----------240669 6.73 497742
481338 7.23 995484
120335 6.23 248871
========== =:;;;:;;;:::;:=== ======::;:===
======::::=== ======= ========== 233681 6.74 514203
249226 6.74 546625
232999 6.74 496765
.
= Pentafluorobenzene
= Fluorobenzene
= Chlorobenzene-dS
RT #
======= 7.64
8.14
7.14
=======
======= 7.65
7.65
7.65
AREA UPPER LIMIT= +100% of internal standard area
AREA LOWER LIMIT= -50% of internal standard area
IS3 (CBZ)
AREA # ========== 366498
732996
183249
=========::;:
========== 358311
359736
351745
RT UPPER LIMIT=+ a.so minutes of internal standard RT
RT LOWER LIMIT= -0.50 minutes of internal standard RT
RT #
=======
12.11
12.61
11.61
=======
=======
12.11
12.11
12.11
# ColUIIIIl used to flag values outside QC limits with an asterisk.
* Values outside of QC limits.
page 1 of 2
FORM VIII VOA
FORM 8
VOLATILE INTERNAL STANDARD AREA AND RT SUMMARY
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FCX.V07001
Lab File ID (Standard): VlCCV0l
Instrument ID: VOA1
Date Analyzed: 07/05/00
Time Analyzed: 1016
Heated Purge: (Y/N) N GC Column: DB-624 ID: 0. 53 (mm)
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
IS4lDCB)
AREA # RT # AREA # RT # ============ ========== ======= ========== ======= 12 HOUR STD 155679 15.65
UPPER LIMIT 311358 16.15
LOWER LIMIT 77840 15.15 ============== ==--====== ======= ========== ======= CLIENT
SAMPLE NO.
============ ========== ======= ==--------======= VlBLK0705 150239 15.65 EW-3 DUPE 145540 15.65
EW-1/ SW-1 155134 15.65
.
IS4 (DCB) = l,4-Dichlorobenzene-d4
AREA UPPER LIMIT= +100% of internal standard area
AREA LOWER LIMIT= -50% of internal standard area
AREA # =-========
==========
======:;;:===
RT UPPER LIMIT=+ 0.50 minutes of internal standard RT
RT LOWER LIMIT,; -a.so minutes of internal standard RT
RT #
===::;;===
=======
=======
# Column used to flag values outside QC limits with an asterisk.
* Values outside of QC limits.
page 2 of 2
FORM VIII VOA
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FORM 8
VOLATILE INTERNAL STANDARD AREA AND RT SUMMARY :-'. ... t; C :J
',, v •1 V j,
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No.: NA SAS No.: NA SDG No. : FCX. V06144
Lab File ID (Standard) : VlCCV0l
Instrument ID: VOAl
Date Analyzed: 07/06/00
Time Analyzed: 0815
Heated Purge: (Y/N) N GC Column: DB-624 ID: 0.53 (mm)
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
=-----------12 HOUR STD
UPPER LIMIT
LOWER LIMIT
==::;::=========
CLIENT
SAMPLE NO.
============ VlBLK0706
MP-10
ISl
IS2
IS3
(PFB)
(FLB)
(CEZ)
ISltPFB)
AREA # RT # ----------=======
235258 6.73
470516 7.23
117629 6.23
=======:;;== =======
========== ======= 252302 6.74
238977 6.74
= Pentafluorobenzene
= Fluorobenzene
= Chlorobenzene-dS
IS2tFLB)
AREA # RT #
========== ======= 492245 7.65
984490 8.15
246123 7.15
===:::==::::=== =======
----------======= 539356 7.64
502000 7.64
AREA UPPER LIMIT= +100% of internal standard area
AREA LOWER LIMIT= -50% of internal standard area
IS3(CBZ)
AREA # =======:===
351271
702542
175636
======::;;:::::::;:::;:
========== 359904
354650
RT UPPER LIMIT=+ 0.50 minutes of internal standard RT
RT LOWER LIMIT= -0.50 minutes of internal standard RT
RT #
======= 12.11
12.61
11.61
=======
=======
12.11
12.11
# Column used to flag values outside QC limits with an asterisk.
* Values outside of QC limits.
page 1 of 2
FORM VIII VOA
FORM 8
VOLATILE INTERNAL STANDARD AREA AND RT SUMMARY
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
.--:"lt;•~~
·,,.1 V ·-.1 VG
Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FC:X.V06144
Lab File ID (Standard): VlCCV0l
Instrument ID: VOAl
Date Analyzed: 07/06/00
Time Analyzed: 0815
Heated Purge: (Y/N) N GC Column: DB-624 ID: 0.53 (mm)
01
02
03
04
05
06
07
08
09
10
11
12
13
14
,15
16
17
18
19
20
21
22
IS4 (DCB)
AREA # RT # AREA # RT # =====----=== ========== ======= =------=== ======= 12 HOUR STD 163527 15.66
UPPER LIMIT 327054 16.16
LOWER LIMIT 81764 15.16 ============ ==--====== ======= ========== ======= CLIENT
SAMPLE NO.
==:::=:::======= ========== ======= ========== ======= V1BLK0706 155615 15.65 MP-10 148315 15.66
,-
IS4 (DCB) = 1, 4-Dichlorobenzene-d4
· AREA UPPER LIMIT = +100% of internal standard area
AREA LOWER LIMIT= -50% of internal standard area
AREA # ==========
=----=====
==========
RT UPPER LIMIT=+ 0.50 minutes of internal standard RT
RT LOWER LIMIT= -0.50 minutes of internal standard RT
RT # =====::::=
=======
=======
# Column used to flag values outside QC limits with an asterisk.
* Values outside of QC limits.
page 2 of 2
FORM VIII VOA
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1· ,,,
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FORM 8
VOLATILE INTERNAL STANDARD AREA AND RT SUMMARY 00093
Lab Name: ECKENFELDER LLC Contract: EL PASO ENERGY
Lab Code: NA Batch No.: NA SAS No.: NA SDG No.: FCX.V07001·
Lab File ID (Standard) : VlCCV0l
Instrument ID: VOAl
GC Column: DB-624 ID: 0.53 (mm)
ISl(PFB)
AREA # RT #
Date Analyzed: 07/06/00
Time Analyzed: 0815
Heated Purge: (Y/N) N
IS2(FLB) IS3 (CBZ)
AREA # RT # AREA # ------------========== ======= ----------======= ---=======
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
12 HOUR STD
UPPER LIMIT
LOWER LIMIT
------------CLIENT
SAMPLE NO.
=======:;::====
V1BLK0706
EW-1/ SW-1
EW-3MS
EW-3MSD
ISl (PFB)
IS2 (FLB)
IS3 (CBZ)
235258 6.73 492245
470516 7.23 984490
117629 6.23 246123
=--==:;;:==== ======= ----------
========== ======= ----------252302 6.74 539356
225687 6.74 469647
263211 6.74 543917
260967 6.74 548225
= Pentafluorobenzene
= Fluorobenzene
= Chlorobenzene-d5
7.65
8.15
7.15
=======
===:;::===
7.64
7.65
7.65
7.65
AREA UPPER LIMIT= +100% of internal standard area
AREA LOWER LIMIT= -50% of internal standard area
351271
702542
175636
==========
========== 359904
332446
364660
362859
RT UPPER LIMIT=+ 0.50 minutes of internal standard RT
RT LOWER LIMIT= -0.50 minutes of internal standard RT
RT #
=======
12.11
12.61
11.61
=======
======= 12.11
12.11
12.11
12.11
# Column used to flag values outside QC limits with an asterisk.
* Values outside of QC limits.
page 1 of 2
FORM VIII VOA
FORM 8
VOLATILE INTERNAL STANDARD AREA AND RT SUMMARY
Lab Name: ECKENFELDER LLC Contract : EL PASO ENERGY
Lab Code: NA Batch No.: NA SAS No.: NA SDG No.: FCX.V07001
Lab File ID (Standard): Vl.CCV0l
Instrument ID: VOAl
GC Column: DB-624 ID: 0. 53 (mm)
IS4 {DCB)
AREA # RT #
Date Analyzed: 07/06/00
Time Analyzed: 0815
Heated Purge: (Y/N) N
AREA # RT # AREA # ============ ==--====== ======= =======:;:=== ======= ==========
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
12 HOUR STD 163527 15.66
UPPER LIMIT 327054 16.16 LOWER LIMIT 81764 15.16
==· . ·==· ==== ===-====== :;:::===== =========== ======= CLIENT
SAMPLE NO.
=========:;;;;:;;:;;:: ==-======= ======= ========== ======= Vl.BLK0706 155615 15.65 EW-1/ SW-1 151810 15.65
EW-3MS 160323 15.66
EW-3MSD 157944 15.65
IS4 (DCB) = l,4-Dichlorobenzene-d4
AREA UPPER LIMIT= +100% of internal standard area
AREA LOWER LIMIT= -50% of internal standard area
==========
=----=====
RT UPPER LIMIT=+ 0.50 minutes of internal standard RT
RT LOWER LIMIT= -0.50 minutes of internal standard RT
RT #
=======
=======
=====::;::=
# Column used to flag values outside QC limits with an asterisk. * Values outside of QC limits.
page 2 of 2
FORM VIII VOA
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1. •
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-··
ORGANIC SUMMARY DATA PACKAGE
PRE-DESIGN INVESTIGATION
OPERABLE UNIT THREE (OU3)
FCX-STATESVILLE SUPERFUND SITE
Prepared for:
EL PASO ENERGY CORPORATION
1001 Louisiana Street
Houston, Texas 77002
Prepared by:
Eckenfelder Laboratory, LLC
227 French Landing Drive
Nashville, Tennessee 37228
September 5, 20000
ager
John H. onsidder, Organic Laboratory Manager
K:\2000Report.sWCX\TOCSUM07050.doc
I
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Table of Contents
Case Narrative
Chain of Custody
Cooler Receipt Forms
Parameters Requested
Data Summary Reports
Summary Forms
TABLE OF CONTENTS
Internal Standard Summary Forms
K:\2000Report:i\FCX\TOCSUM07050.doc
Page No.
1
1
2
5
8
11
22
72
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ORGANIC CASE NARRATIVE
El Paso Energy #60313.006
Work Orders
0007050,0007069,0007108
GC/MS Volatiles Method: The samples were analyzed by USEPA Contract
Laboratory Program Statement of Work (CLP SOW) for Organics Low
Concentration Water Method OLC03.2(5ml purge and trap followed by capillary
column GC/MS).
Volatiles Comments: The volatile analyses were completed and satisfactorily met
method requirements with the following exceptions:
• The method indicates an internal standard mixture contammg
1,4-dichlorobenzene-d4, chlorobenzene-d5 and 1,4-difluorobenzene. The
internal standard mixture used contained fluorobenzene and pentafluorobenzene
in place of 1,4-difluorobenzene.
• The method indicates a system monitoring compounds of 1,2-dichloroethane-
d4, toluene-d8 and p-bromofluorobenzene. System monitoring compound
(SMC) of dibromofluorobenzene was used in addition. No flags were applied
to the data based on this additional SMC.
• The trap used for analysis of the samples was a VOCARB 3000 packed with
10cm Carbopack B, 6 cm Carboxen 1000 and 1 cm Carboxen 1001.
• The 07 /20/00 initial calibration curve for the compound bromoform exceeded
· the allowed 20.5% relative standard deviation (RSD) at 24.3% RSD Two
compounds are allowed to exceed 20.5% RSD within a calibration curve. This
compound was not detected in any of the samples.
• A calibration point for tetrachlorethene was added to the 07 /20/00 initial
calibration curve at 500 ug/L.
• The 07 /28/00 continuing calibration exceeded 25 % drift for bromomethane and
vinyl chloride at 41.1 % and 25.5%, respectively. These compounds were not
detected in the associated samples. _
• The 07/23/00 method blank contained acetone at 19 ug/L. Reported
concentrations for acetone in the associated samples were appropriately flagged
with a "B".
• The internal standard/surrogate spike bulb on the archon autosampler was
depleted before spiking the MSD on sample MP-3. The internal standard areas
used for the calculation of the matrix spike compounds for sample MP-3 (MSD)
matrix spike duplicate (0007505-03) came from the previous sample MP-3
(MS) matrix spike (0007050-03). The surrogate recoveries were not available.
MSD analyte recoveries were within limits .
.
K.:\2000Reporta\FCX\ocn0007050.doc
·Project No./Name FC'f Oll3
Eckenfelder Laboratory, LLC Chain of Custody Record·
Send Results to:
Name_,/(e....µ.,~~/'--'a~-~'/l{~Jl---'-----
Company __,8=-..::(!.,,=-------
Address · -----------City & State ________ _
Phone ------------Fax -------------
Send Invoice To:
Name ___________ _
Company ________ _
Address __________ _
City & State ________ _
Phone __________ _
Purchase Order
ature • /2
N~ .. 2167 O
Details:
Page. / of)
Cooler No. __ / of /
Date Shipped -,-------
Shipped By _______ _
Turnaround ---,--,----,--
(Std. tum unless noted otherwise/There
may be a surcharge for RUSH-contact Lab)
Date lime CompJ .Sample Location/Description Sample
Matrix
ANALYSIS REQUIRED
Sam led Grab
Grob EW-9 c..w
/hi/~ MP-13
Ji/oo Mf-3
Jt/;o HP-7-
Ti? IP G'l,4-f'JK.. # (,!Ji/ Wt!W.
Date/fime REMARKS
• Signature required to ensure validity
Date/Time Received By: (Signature)
;~el™vedtiitlliilm . •· .J!Y.:db1dw,0 ,,.,,'. , tlzi]~;; t~:!·~~;!;!i~:!Y!;~~
tai •
3
VDCs., 2-
Ship lo: ~-· .. :,,,,,,'--"~--+
F.--l.,nf,l,l" \ •1,.••"'') 11.C
227 French Ln,ulin~ l>rll•t•
N,1sh\'illc, TN 37228
Altu: Airnlylk1il Lnhornlory
(615) 345-illS (phone) ·
[phone] (fax)
(615) 400-0iSJ (mobile)
l'u,jc<·( Nn./Name
~
Oalc
Sam )led
'lime Comp./
Grnh
I loou
.
(Signat11rr:)
~ --~■--~· Fckcnfrldc1· Lahoratory, .C Chain of Custody Record
Senti Hesulls to:
Namr .. J<e "JD . .,.b.-=A.c.· ----
Company 12,C __,
Address ----------City & Sia le ________ _
Phone
Fax ------------
Sample I.-OC1lion/l)c5criplion
EW-10
Sample
Matrix
Send Invoice To:
Name -----------
0, mp any ----------
Address _________ _
City.& State ________ _
Phone __________ _
Purchase Order
VOCs
VOG
REMARKS
• Signature required lo ensure validity
Dale/rime Received By: (Signature)
~;'¼~to•·
'~dL-~;:}:,,· . ~· •.. :, ... ,: ...
...... IiJiiitta1mf
. A x ilii l2?~222i.)~1v:.o:.'>""J ===
, .... :· .... 1 .... ,I .,,.11,,.,., .-,u,ir<: :in·,1mnanv .<::lmt>IP _c;hipmr.nl lo l:ihornlnry;
~ .. -N~ 2] '! fl 0
Dctnils:
Pagc_/_of _J__
Cooler No. _/_ of _J_
Date Shipped 7 / 1 LJ I Do
-
Shipped By _______ _
Turnaround
(Std. tum unless noted olhcrwisc/I11crc
may be a surcharge for RUSll-conlacl Lib)
3
Sample Kit Prep'd by: (Signature)
: (Signature)
Eckenfelder Laboratory; LLC Chain of Cnstody Record
Send Results to:
Name 0r£~ cL,sf-i,~
Company bC_.
Address
City & Sta-te-,,{;~~-5-t_w-,_' /-[..,_----
Phone ------------Fax ____________ _
Send Invoice To:
Name ------------
Company ---------
Address
City & State _______ _
Phone--------~--
Purchase Order
•
Details:
Ctr ft/2, .,_ v
. /Jrra z~ .,/
21781 _
-row -'3rd. 1·J. 5-0<..
Page _J_ of _j_
Cooier No. --I-,_ of _l__
Date Shipped y"]_J--00
Shipped By ~S~~--=&J:..= ___ _
Turnaround
less noted otherwise/There
,IJ'tiJay-l,e-<Hu{charge for RUSH-contact Lab)
ANALYSIS REQUIRED
u
/rlP-lf {)v,,fE
(
Date/fime MARKS
• Signature required to ensure validity
Dal Received By: (Signature) .. --
I
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PROJECT: /;e--ML u Ct ) }
b,,...,-""~"---· -~-... t-:_ ~ ·_
ECKENFELDER INC~
COOLER RECEIPT FORI,!
t:f: 11]1..s-· D /7
GOOG5
USE OTHER SIDE OF' THIS FOR.\! TO NOTE DETAILS AlW!OR COMP!.ZTE A CORR.ECT!YE ~CTFON CONCERNING CP.ECK·l'N PROBLE,\fS.
A. PREL!ML'IARY EXA.'d:INATION PHASE: DATE COOLER OPENED: -1:1,}-4:C.of-C Number 7../(,Jy
by (pr!nll IL j cb r:rP {sign I ,{n,-o /4, if CJ
l, Did.cooler come with a shipping slip (air bill. etc.I? _________________ @ NO
If YES, enter carrier Name & alr bill number here: ,kd, £x # f?I'/ i3 Z'1.'/ 70 t;, '{
2. Were custody seals on outside of cooler7 ___________ ~ _________ 6;s) NO
How many & where: _ _.-z."--__,L"-'-i~,C~--~· seal date 1-/'2 -.:, <> . seal name A. d'<rb 1 3. Were custody seals unbroken and intact at the date and tlme of arrtval? _________ ,mi) NO
4. Did you screen samples for radloactlvtty uslng the Cetger Counter? _____ ~----YES <II§.:)
5. Were custody papers sealed ln a p\astlc bag & taped inside to the lid? ________ _ ~-NO
6. Were custody papers niled out properly link. signed. etc.)? ____________ _ @ NO
7. Did you sign custody papers ln the approprlate place? ______________ _ ~ NO
NO 8. Was proJe_ct_ ide~tlflable from custody papers? If yes, enter project -~e top of th1s form, -@
9. If required, was enough lee used? ________ Type of lee: Temp2.o '"C __ ~ NO
10. Have designated person inlttal here to acknowledge receipt of cooler: G-rE: (date) 7'::1';:.--6>
B, LOG-IN PHASE: Date samples were logged ln: __ .c7:...-__,/_l/,,__-o_o;c_ ______ ~------
by (pr!nt), _ __.o:;t_. _/l'---'--,--=c,,-L.__.,.'--£::;..., _____ (slgnl /4v /2ziJ',.__/?
11. Describe type of packh1g In cooler:,..L&ao.,.M~& ........ wd<.JtJe;""e::,:,.~;,-c.-k...,,o/j"'"l",,,,u?'i'...,'---J/'-'C1.i' .... ________ _
12. Were all bottles seal~d In separate plastic bags? ___________ __,,.-----~~ c@ NO,
13. Did all.bottles arrlve unbroken & were labels ln govd condition? ___________ _ {@ NO
14. Were all bottle labels complete {ID, date, time, signature, preservative, etc.)? ______ _ ,.@ NO
15. Did all bottle labels agree with custody papers? _________________ _ (§ NO
16. 'w'ere correct containers used for the tests indicated? ______________ _ @ NO
17. Were corre-:l preservatives added to samples? __________________ _ ~ NO
® 18. Was a sufficient amount of sample sent for tests Indicated _____________ _ NO
19. Were bubble~ absent In volatile samples? If NO. list by Sample.# __________ __, @ NO
2p. Was the project.man.1g~.-c.1lled and stJ..tus d!scussed? If yes. gtve detalls on the ~ck of this form r.:.S'3
L:\LOCtN\COECOOl..OOC
lke,, .--·~·Rt,,.._--~'..: .... ··=---=l,a;.,.i-
ECKENFELD ER INC~
COOLER RECElPT FOR.'v!
OOOGG
PRO,JECT: 'f:x, -}JsJ.._ ( ,c:.c.i) LlMS# 0co7&'9-q I➔ -cs
USE OiH~ SIDE OF' THIS F'OR..\i TO.NOTE DEi'.AILS AND/OR COMP!..ETE A COR.RECitvE ACTION CONCZR.NrNG CHECK-IN ?ROBf..EMS.
A. PREL!Mh'IARY EXA.'-IlNAT!ON PHASE: DATE COOLER OPENED: 1-1£-o<Z;,of•C Number 'Z.I '\'l"f
by (printl __ ~:J"-'--~\.l=c..::u.,_<,.,z=--------~l.slgnl @,·
!. •Did cooler come With a shipping slip (aJr bill. etc.I? __ ...,_/ __ ·-----------~ NO
lfYES, enter carrier Name & air bill number here: f-2-( -£.,s If: 3/l/J 336</ ?cc?
2. Were custody seals on outside of cooler? ___________________ ..../@ NO
How many & where: 1,,-L;J . s0al date __ 1.,_-.Ll.=</ ... -<l=-=o,___. seal name / H,,-f/e/
3. Were custody seals unbroken and intact at the date and tlme of arrival? ________ ~ NO
4, Dld you screen samples for radloactlvity using the Gelger Counter? Y-c.S ,@
5. Were custody papers scaled ln a plastic bag & taped lnslde to the Hd? _________ tE) NO
s: Were custody papers fl.lled out properly (ink. signed. etc.)? 6) NO
7. Did you sign custody papCrs ln the appropriate place? @ NO
8. Was project lde~ttflable from custody papers? lf yes, enter project name at the top of th.ls form. @ NO . ·. . . ,~~ . 9. If required. was enough ice uscd? _______ fype of Ice: ~(l'cmpZ:2."C __ (£> NO
10. Have designated person lnltl_al here to acknowledge receipt of cooler: m;?l-(date) 7-17.-i'T:.?
B. LOG-IN PHASE: Date samples were logged ln:. __ 7,_-..;/c.7.,_-o __ 0 __ ~-----------
by {prlnt) _ __,f;,.,_._""ti+-,.,,,c..~k,.""""'"'-",.P.__ _____ (slgnl 7t,:;J /2,?/4---e
.,(,_ " 11. Describe type of pack~,g In coolcr:•_,i.Ml,¢"~-· "'-"½.._,W=>:'.)'-'":;~~---'k;=::~7;,,;,,e"""✓c__~t<->'cg=---------f . ·J2. Were all bottles scaled In separate plastic bags? ___________ ,_-----~ NO
13. Did all bottles arrive unbroken & were labels In gw<l condition? 6) NO
14. Were all botUc labels complete {ID, date, time, signature, preservative. etc.)? 0 NO
15. Did all bottle labels agree with custody papers? -® NO
16. Were correct contalncrs used for the tests Indicated? @ NO
17. Were corr~cl preservatives added to samples? __________________ § NO
' 18. Was a s"ufficlent amount of sample sent for tests Indicated _____________ ~ NO
19. Were bubbles absent In volatile samples? If NO. list by Sanfplc ~ @ NO
20. Was the project manng-'!r caJled and sto.tus discussed? If yi:s. give Cctalls on the b..,ck of this form. YES @
21. Who ·.•::"..s C:::l!lo:·d? ______________ By •. ,,.-hom? _________ ~[Ca.te) ____ _
l..;\LCCIN\COE:CCOL.OOC
D
I
I
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I
I
i
I
'I
I
I
I
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I
I
I'
I ~----~ r-..... ~ I
ECKENFELDER INC~
, COOLE.R RECE.IPT FORM
PROJECT:._~/2 .... -'C_·_-_'1/-C..--',_L~-~· ..,G_,_rz:~;,t'-c7,;-) __ . ____ · __ · ~• ___ LIMS~ Oc<2Z10'.r'.-0/--y-O~
USE OTHER SiDE O'f' THIS f'OR.',f TO NOTZ DETACLS AND/OR COMP!.E:TE: A COR.RECTiYE ACTION.CONCZRNfNG C.'-!ECK•fN ?RCB!.E.',fS,
A. PRELIM!l'!ARY EXA..,m/AT!ON PHASE: DATECOOLE:R OP!::NED: 7· Z"-.(O•of-C Numl:er 'Z./7 'il/
by l~rlnt) q n,.--5'{ft,.g_ . . (sign) c.::;.:::----A¥ ·
l. Did cooler come·With a shipping slip (air bill. etc:.l? _______ --,--:-------y,:-._s @)
lfYES, enter carrier Name & alr b!ll number here~__,_/t_._,~===-~M'-'='-·----------
2. · Were custody seals on outside or cooler? ____________________ YES ~
How many & where: __ __:::::==::_: __ ;..., seal date ___ -______ .. seal n<lme, ____ _
3. Were custody seals unbroken and Intact at the date and time or arr!val?J.M-"-'~-'------Y'ES NO
4. Did you screen samples ror rad\~actlvtty uslng the Gelger Counter? __________ YW G)
5. Were custody papers sealed ln a plastic .bag & taped lnslde to the lid? @> NO
6. Were custody ?apers filled out properly (Ink, signed. etc.)? ~ NO
7. Did you sign custody po.pers In the appr0pr!ate place? ______ '--________ .(? NO
8. Was project ldenttnable from custody paper"s? lfyes. enter project name at t e top oft.his form.~ NO.
. ~ U? 9. If required, was enough Ice used? ________ Type of lce:_·~~~LTemp.L:.L"C_· _ ~ NO
10, Have designated person lnlttal here to acknowledge receipt orcooler:_..::~=·=r ___ ,(date·l 7-·Z'{-<kJ
B. LOG-IN P,USE; Date samples were logged In: J--Zj-Oo · ~
by (print)· C,. F,,.,-rj,l-f/4, (sign) _ ~;
11. Describe type of packing In cooler: 4,,-6)/e.. (,d>:,1/, ~/,,,/ /c,i__ ·
12. Wer_e all bottles sea.led 1ri separate plastlc bags? __ --'--------------~ NO
13. Did all bottles ~rrtve unbrOken & were lab.els In gV<.:rd. condition? :@) NO
14. Were all b~ttle labels complete (10, date; Ume. slgnature,.prescr:vallvc, etc.)? _______ @) NO
15. Did all bottle labels agree with custody papers? ~ NO
16. Were correct contaln:::rs used for the tests Indicated? e NO
17. Were corr~::l_prcservatives addCd to s3.mpies? \® NO
' 18. Was a sufficient ainoLint of sample sent for ~cs.ls Indicated _____________ ~ NO
19. Were.bubbles absent ln vo!atlle samples? If NO, Hst by Sample JI. e NO
20. \Vas the project manng~r called and stiltlis discussed? If i'cs. g1·,c Cctalls on t.t-,c ~"lck or thts (or.;t I.:.S
,2 l, Who ·s:-.s C:l!!-:-d? ______________ F3.y •. ,.·hom7 __________ ,(c!atc) ____ _
L;\LCCIS\COtCOOLCCC
I
Brown & Caldwell (WM, WW, HYD)
Parameters Requested
Laboratory Client Matrix Date and Time Parameters
Sample ID Field ID Sampled Requested
0007050-01 EW-9 Groundwater 7/11/2000 4:30:00 PM VOA 8260A (Water)
0007050-02 MP-13 Groundwater 7/11/2000 4:45:00 PM VOA 8260A (Water)
0007050-03 MP-3 Groundwater 7/12/2000 2:00:00 PM VOA 8260A (Water)
0007050-04 MP-7 Groundwater 7/12/2000 2:10:00 PM VOA 8260A (Water)
0007050-05 Trip Blank #1604 Groundwater 7/11/2000 VOA 8260A (Water)
0007050-06 Storage Blank Water 7/13/2000 VOA 8260A (Water)
Page I of I I\
I
I GOOG9
,, Brown & Caldwell (WM, WW, HYD)
I Parameters Requested
I Laboratory
Sample ID
Client Matrix Date and Time Parameters
Field ID Sampled Requested
0007069-01 -I 0007069-02
MP-5 Groundwater 7/13/2000 3:45:00 PM VOA 8260A (Water)
MP-2 Groundwater 7/13/2000 4:00:00 PM VOA 8260A (Water)
II 0007069-03 EW-10 Groundwater 7/13/20004:10:00 PM VOA 8260A (Water)
0007069-04 Trip Blank # I 607 Trip Blank 7/13/2000 VOA 8260A (Water) ,,,
0007069-05 Storage Blank Water 7/17/2000 VOA 8260A (Water)
I C
I ,.
I
I,
·1\
j;
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I
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:11
rr'~'(, vll\J:..:J u
Brown & Caldwell (WM, WW, BYD)
I'
B
Parameters Requested. I
Laboratory Client Matrix Date and Time Parameters
Sample ID Field ID Sampled Requested
0007108-01 MP-12 Groundwater 7/19/2000 9:45:00 AM VOA 8260A (Water)
g
0007108-02 MP-11 Groundwater 7/19/2000 12:10:00 PM VOA 8260A (Water) u
0007108-03 EW-16 Groundwater 7/19/2000 4:40:00 PM VOA 8260A (Water)
0007108-04 MP-4 Groundwater 7/19/2000 3:25:00 PM VOA 8260A (Water) 11
0007108-05 MP-6 Groundwater 7/20/2000 10:15:00 AM VOA 8260A (Water) u
0007108-06 MP-I Groundwater 7/20/2000 3:40:00 PM VOA 8260A (Water)
0007108-07 MP-11,DUPE Groundwater 7/19/2000 12:10:00 PM VOA 8260A (Water)
'" 0007108-08 STORAGE BLAN Groundwater 7/22/2000 VOA 8260A (Water) D
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Page I of I ' 'I
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Client: FCX #18895.006
Date Reported: 07/31/00
Eckenfelder
Laboratory, LLC
G0011
I ECKENFELDER SAMPLE NUMBER I v1BLK0723 l VlBLKo724 10001oso-01010001oso-02010001oso-0201
I · ---------------------------------------------1-----------1-----------1-----------1 ··· --------1-------· ---1
I DATE SAMPLED I NA I NA I 07/ll/00 I 07/ll/00 I 07/ll/00 I.
I DATE RECEIVED I NA · I NA I 07/13/00 I 07/13/00 I 07/13/00 I
I DATE ANALYZED I 07/23/00 I 07/24/00 I 07/23/00 I 07/23/00 I 07/24/00 I
L · · ----------------------· --------------------1----· · · ---· I ----------· I -· -------··I ·----------1------· ----1
I I M.BI.ANK I M.BI.ANI( I EW-9 · I MP-13 I MP-13 I
I CLIENT SAMPLE DESCRIPTION I I I I I I
I I I I I I I
1-----,.---·-----------·----------------------1-----------1·····------I ··-······-I···-·-····· 1-----------1 I VOLATILE ORGANICS I I I I I 5o X(ll I 5o x(1J I 250 ·x<11 I
I BY USEPA CLP sow 0~03.2 I MDL l EQL I CONC I CONC I CONC I CONC I CONC 1
1--------------------------------······--···---l--------·-·l-----------l-----------l--·---·----I-----------I
I Acetone J 5.0 I 50 I 19 JI< 5.0 I 720 JEDI 700 JBD[ 1900 JDI
I Benzene I 1.0 I 10 I< 1.0 I< 1.0 I< SO DI< SO D!< 250 DI
I Bromodichloromethane I 1.0 I 10 I< 1.0 ° I< .1.0 !< 50 DI< 50 DI< 250 DI
I Bramoform I 1.0 I 10 I< 1.0 I< 1.0 I< 50 DI< 50 DI< 250 D\
j Bromornethana I 2.0 I 20 I< 2.0 I< 2.0 I< 100 DI< 100 DI< 500 DI
I 2-Butanone I 10 I 100 !< 10 I< 10 I 2400 JOI< 500 DI< 2500 DI
I Carbon disulfide I 1.0 I 10 I< 1.0 [< 1.0 [< 50 DI< SO DJ< 2S0 DI
I carbon teerachloride I 1.0 I 10 I< 1.0 l< 1.0 I< so DI< 50 DI< 250 DI
I Chlorobenzano I 1.0 J 10 I< 1.0 I< 1.0 I< SO DI< 50 DI< 250 D[
I Chloroethano ! 2.0 I 20 [< 2.0 I< 2.0 I< 100 DI< 100 DI< 500 DI
I Chloroform ! 1.0 I 10 I< 1.0 I< 1.0 I 65 JOI 59 JOI< 250 DI
I Chloramethane I 2.0 I 20 1< 2.0 [< 2.0 I< 100 DI< 100 DI< 500 DI
I Dibromochloromethane I 1.0 I 10 I< 1,0 I< 1.0 I< 50 D!< 50 DI< 250 DI
I 1,1-Dichloroethane I 1.0 ! 10 I< 1.0 ]< 1.0 I< 50 DI< 50 DI< 250 DI
I 1,2-Dichloroethane I 1.0 l 10 I< 1.0 I< 1.0 ]< SO DI< 50 DI< 250 DI
l l,l-Dichloroethene I 1.0 I 10 I< l.O I< 1.0 I< SO DI< 50 DI< 250 DI
I cia-1,2-Dichloroethene I 1.0 I 10 I< l.O I< 1.0 I 190 JOI 4000 DI 3300 DI
I trans-1,2-Dichloroethene I 1.0 I 10 I< 1.0 ]< 1.0 ]< 50 DJ< 50 DI< 250 □I
I 1,2-Dichloropropane I 1.0 j 10 I< l.O I< 1.0 I< 50 DI 370 JOI 280 JD!
I cis-1,3-Dichloropropene I 1.0 I 10 !< 1.0 I< 1.0 I< SO DI< 50 D!< 250 Dj
I tram1-l,3-D1chloropropene 1 1.0 I 10 I< 1.0 i< 1.0 I< SO "DI< 50 D]< 250 DI
l--------'-------------------------1
ALL COMPOUNDS EXPRESSED IN MICROGRAMS/LITER ~LESS OTHERWISE NOTED.
ALL NON-DETECT VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLECT. DILt.rrIONS/SAMPLE VOLUME).
SEE ATI'ACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
(1) • SAMPLES WERE DILt.rI'ED BY THE NUMERICAL VALUE DISPLAYED.
DETECTION LIMITS HAVE BEEN INCREASED BY THE SAME FACTOR.
227 French Landing Drive Nashville, Tennessee 37228 615-345-1115 FAX [phone]
Eckenfelder Laboratory, LLC
Client: FCX #18895.006
Date Reported: 07/31/00
00012
I ECKENFELDER SAMPLE NUMBER I VlBLK0723 I VlBLK0724 I0001oso-01OI0001oso-020J.0001oso-020I
I ----------------------------------------------1-----------1-----------I -----------1-----------1-----------1
I DATE SAMPLED I NA I NA I 07/11/00 I 07/11/00 I 07/11/00 I
I DATE RECEIVED I NA I NA I 07/13/00 I 07/13/00 I 07/13/00 I
I DATE ANALYZED I 07/23/00 I 07/24/00 I 07/23/00 I 07/23/00 I 07/24/00 I
1------------------------------------------. ---l-----------l-----------1-----------1-----------1-----------I
I I M.BLANK I M,BLANK I EW-9 I MP-13 I MP-13 I
I CLIENT SAMPLE DESCRIPTION I I I I I I
I I I I I I I
-----~ -~--------· --------------------------1-----------1-----------1----------1-----------1-----------1
VOLATILE ORGANICS I I I I I so X(lll so X(lll 250 X(lll
BY USEPA CLP SOW OLM.03.2 I MDL I EQL I CONC I CONC. I CONC I CCNC I CONC I
----------------------------------------------1-· ---------l-----------l-----------1-----------1-----------1
Ethylbenzene
2-Hexanone
Methylene chloride
4-Methyl-2-pentanone
Styrene
I i.o
I 2.0
I i.o
I 2.0
I i.o
1,1,2,2-Tetrachloroethane I 1.0
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethane
Vinyl chloride
Xylene (total)
I i.o
I i.o
I i.o
I i.o
I i.o
I 2.0
I i.o
10
20
10
20
10
10
10
10
10
10
10
20
10
I< 1.0
!< 2.0
I< 1.0
I< 2.0
I< 1.0
I< 1.0
I< 1.0
I< 1.0
I< 1.0
I< 1.0
I< 1.0
I< 2.0
I< 1.0
I< LO
I< 2,0
I< 1.0
I< 2.0
I< 1.0
I< 1.0
I< 1.0
I< 1.0
I< 1.0
I< 1.0
I< 1.0
I< 2.0
I< 1.0
I< so
I< 100
l< so
I< 100
I< so
I< so
I 4500
I< so
I< so
I< so
I< so
I< 100
I< 50
DI< 50
DI< 100
DI< 50
DI< 100
DI< 50
DI< 50
DI 35000
DI< 50
D]< 50
DI< so
DI 2000
DI< 100
DI< 50
DI<
DI<
DEi
DI<
DI<
DI<
DI
DI<
250
500
250
500
250
250
29000
250
250
250
1600
500
250
DI
DI
DI
DI
DI . DI
DI
DI
DI
DI
JOI
DI
DI
----------------------------~-1 ALL COMPOUNDS EXPRESSED IN MICROGRAMS/LITER UNLESS OTHERWISE NOTED.
ALL NON-DETECT VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLECT DIL'lirIONS/SAMPLE VOLUME).
SEE ATTACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
(1) "' SAMPLES WERE DILtrrED BY TIIE NUMERICAL VALUE DISPLAYED.
DETECTION LIMITS HAVE BEEN INCREASED BY THE SAME FACTOR,
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Eckenfelder Laboratory, LLC
Client: FCX #18895.006
Date Reported: 07/31/00
I ECKENFELDER SAMPLE NUMBER (0001oso-03 10001oso-040!0001oso-os I
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I DATE SAMPLED I 07/12/00 I 07/12/00 I 07/11/00 I
I DATE RECEIVED I 07/13/00 I 07/13/00 I 07/13/00 I
I DATE ANALYZED I 07/24/00 I 07/24/00 I 07/24/00 I
1----------------------------------------------1-----------1-----------1-----------1
I I MP-3 I MP-7 I
I CLIENT SAMPLE DESCRIPTION I I I
Trip Blankl
I #1604
I I I I I
1------.---· -----. -----------------------------1-----------1----. ·. ----1-----------1 I VOIATILE ORGANICS I I I I 20 X(l) I I
I BY USEPA CLP sow OLM03. 2 j MDL j EQL I CONC I CONC j CONC )
1----------------------------------------------1-----------1-----------1-----------1
I Acetone I 5.0 I 50 I< s.o l 120 JDI< 5.0 1
I Benzene I 1.0 I 10 I< 1.0 I< 20 D[< 1.0 I
I Brcmodichlorom.athane I 1.0 I 10 \< 1.0 I< 20 D!< 1.0 I
I Brcmoform. \ 1.0 I 10 ]< 1.0 I< 20 DJ< 1.0 I
I Bromom.eehane I 2.0 ] 20 I< 2.0 I< 40 DI< 2.0 I
[ 2-Butancno I 10 I 100 I< 10 ! < 200 DI< 10 1
! Carbon disulfide I 1.0 I 10 I< 1.0 ]< 20 DI< 1.0 I
I Carbon tetrachloride I 1.0 I 10 I 3.0 JI 46 JDI< 1.0 •,I
I Chlorobenzene I 1.0 I 10 !< 1.0 I< 20 DI< 1.0 I
I Chloroethane I 2.0 [ 20 I< 2.0 [< 40 D[< 2.0 I
I Chloroform I 1.0 I 10 1 1.8 JI 68 JD!< 1.0 [
I Chlcromethane I 2.0 J 20 [< 2.0 I< 40 D!< 2.0 [
l Dibromochlorcmethane I 1.0 I 10 I< 1.0 I< 20 DI< 1.0 I
I 1,1-Dichloroethane I 1.0 I 10 I< 1.0 I< 20 DI< 1.0 I
I l,2-Dichloroethane I 1.0 ! 10 I< 1.0. I< 20 DI< 1.0 I
! 1,1-Dichloroethene I 1.0 l 10 I 9.6 JI< 20 D\< 1.0 I
I cis-l,2-Dichloroet~one I 1.0 1 10 I< LO I 220 DI< 1.0 j
1 trans-1,2-Dichloroothene [· 1.0 I 10 I< 1.0 I< 20 DI< 1.0 I
I l,2-Dichloropropane I 1.0 I 10 _ 1< 1.0 I< 20 D[< 1.0 I
I cie-1,3-Dichloropropene I 1.0 I 10 I< 1.0 I< 20 Dj< 1.0 !
I trans-1,3-0ichloropropene I 1.0 I 10 I< 1.0 -!< 20 DI< 1.0 l
1--------------------~---I
ALL COMPOUNDS EXPRESSED IN MICROGRAMS/LITER UNLESS OTHERWISE NOTED.
ALL NON-DETECT VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLECT. OILtTI'IONS/SAMPLE VOLUME).
SEE ATI'ACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
(l) • SAMPLES WERE OILUI'ED BY TIIE NUMERICAL VALUE DISPLAYED.
DETECTION LIMITS HAVE BEEN INCREASED BY THE SAME FACTOR.
Eckenfelder Laboratory, LLC
Client: FCX #18895.006
Date Reported: 07/31/00
I ECKENFELDER SAMPLE NUMBER I 0007050-03 I 00070S0-04D) 0007050-05 I
1----------------------------------------------I-----------I-----------I-----------I
I DATE SAMPLED I 07/12/00 I 07/12/00 I 07/11/00 I
.1 DATE RECEIVED I 07/13/00 I 07/13/00 I 07/13/00 I
I DATE ANALYZED I 07/24/00 I 07/24/00 I 07/24/00 I
1----------------------------------------------1-----------1-----------1-----------1
I I MP-3 I MP-7 I Trip Blank!
I CLIENT SAMPLE DESCRIPTION I I I #1604 I
I I I I I
1-------------------. -------------------------1-----------1-.----------I -----------I I VOLATILE ORGANICS I I I I 20 X(l) I I
I BY USEPA CLP sow OLM03.2 I MDL I EQL I CONC I C:ONC j CONC I
1----------------------------------------------1-----------1-----------1-----------1 I Ethylbenzene I 1.0 I 10 I< 1.0 I< 20 Dj< 1.0 J
I 2-Haxanone I 2.0 J 20 I< 2.0 I< 40 Dj< 2.0 I
I Methylene chloride I 1.0 I 10 I< l.O I< 20 DJ< 1.0 I
I 4-Methyl-2-pentanone I 2.0 j 20 I< 2.0 I< 40 D1< 2.0 I
I Styrene ! 1.0 j 10 I< 1.0 I< 20 Dj< 1.0 I
I 1,1,2,2-Tetrachloroethane I 1.0 I 10 I< 1.0 ]< 20 D!< 1.0 l
l Tetrachloroethene I 1.0 I 10 I 37 l 6200 DI< 1.0 I
I Toluene I 1.0 I 10 I< 1.0 J< 20 D[< 1.0 !
I 1,1,1-Trichloroethane I 1.0 I 10 I< 1.0 !< 20 DI< 1.0 !
I l,l,2-Trichloroethane I 1.0 I 10 I< 1.0 !< 20 DI< 1.0 I
I Trichloroethane I 1.0 I 10 I 1.2 Jj 151 JD[< 1.0 I
! Vinyl chloride [ 2.0 I 20 I< 2.0 I< 40 DI< 2.0 I
! Xylene{total) [ 1.0 I 10 I< 1.0 l< 20 DI< 1.0 ) ! _______________________ !
ALL COMPOUNDS EXPRESSED IN MICROGRAMS/LITER UNLESS OTHERWISE NOTED,
ALL NON-DETECT VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLECT DILUTIONS/SAMPLE VOLUME).
SEE ATTACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS,
(1) • SAMPLES WERE DILTJrED BY THE NUMERICAL VALUE DISPLAYED,
DETECTION LIMITS HAVE BEEN INCREASED BY THE SAME FACTOR,
Eckenfelder Laborat~LLC
-;11/Lcit-Ca ~ .. l 2ffo
D. Rick Davis (____
Vice President
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Client: FCX #18895.006
Date Reported: 07/31/00
Eckenfelder
Laboratory, LLC
C0015
[ ECKENFELDER SAMPLE NUMBER I VlBLK0724 I 0007069-0lD I 0007069-020 I 0007069-03D I 0007069-04 I
1----------------------------------------------1-----------1-----------1-----------1-----------1----------1
I DATE.SAMPLED I NA I 07/13/00 I 07/13/00 I 07/13/00 I 07/13/00 I
I DATE RECEIVED I NA I 07/15/00 I 07/15/00 I 07/15/00 I 07/15/00 I
I DATE ANALYZED I 07/24/00 I 07/24/00 I 07/24/00 I 07/24/00 I 07/24/00 I
1----------------------------------------------I--------· --l-----------l-----------1-----------1-----------1
I I M.BLANK I MP-5 I MP-2 I EW-10 I
I CLUlNT SAMPLE DESCRIPTION I I I I I
Trip Blankl
I #1607
I . . I I I . I I I
1-------------------. --------------------------1-----------1-----------1-----·_ ---1-----------1-----------1 I VOLATILE ORGANICS I I I I 50 X(l) I 5.0 X(l) I 5.0 X(l) I I
I BY USEPA CLP SOif 011>!03. 2 I MDL I EQL I CONC I CONC I CONC I CONC I CONC I
1---------------------------------------------1-----------1-----------1-----------1-----------1-----------1
I Acetone I 5.0 I 50 I< s.o I 440 JDI 40 JDI 36 JOI< 5.0 I
I Benzene I 1.0 I 10 I< 1.0 I< 50 D!< 5.0 DI< 5.0 DI< 1.0 j
I Bromodichloromethane I 1.0 [ 10 I< 1.0 I< 50 DI< S.o D[< s.o D[< 1.0 I
I Bromoform I l.O l 10 I< 1.0 [< so DI< s.o DI.,. s.o oj.< 1.0 I
I Bromcmethano I 2.0 I 20 I< 2.0 !< 100 D[< 10 DI< 10 DI< 2.0 I
I 2-But:anone l 10 I 100 I< 10 I< 500 DI< 50 . DI< 50 D[< 10 I
I carbon disulfide I 1.0 I 10 I< l.O I< so DI< s.o □I< s.o □I< 1.0 I
I carbon tetrachloride I 1.0 I 10 I< 1.0 I< SO DI< 5.0 DI< 5.0 DI< 1.0 I
Chlorobenzene I 1.0 I 10 I< 1.0 I< 50 DI< S.o DI< 5.o DI< 1.0 I
Chloroethane I 2.0 I 20 I< 2.0 !< 100 DI< 10 DI< 10 DI< 2.0 I
Chloroform j l.O I 10 I< l.O ]< 50 DI 61 DI 5.5 JDI< l.O I
Chlorcmethane I 2.0 I 20 I< 2.0 I< 100 DI< 10 D[< 10 DI< 2.0 I
Dibromochloromethane I 1.0 I 10 I< l.O I< so DI< 5,o DI< 5.0 DI< l.O I
l,l-Dichloroethane I l.O ] 10 I< l.O I< 50 DI< 5.0 DI< 5.0 DI< l.O I
l,2-Dichloroethane ] 1.0 I 10 l< 1.0 I< 50 DI< 5.0 DI< 5.0 DI< l.O I
1,1-Dichloroethene I l.O I 10 I< l.O I< SO DI< 5.0 DI< 5.0 DI< l.O \
cis-1,2-Dichloroethene I l.O I 10 I< l.O I 87 JOI 30 JDJ< 5.0 DI< 1.0 ]
trane-1,2-Dichloroethene I l.O I 10 I< l.O I< 50 DI< 5.0 DI< 5.0 DI< l.O I
1,2-Dichloropropane ! l.O I 10 I< l.O I< 50 DI< 5.0 DI< 5.0 DI< 1,0 !
cie-1,3-Dichloropropene I 1.0 I 10 I< 1.0 I< SO DI< 5.0 D\< 5.0 DI< 1.0 I
trans-1,3-Dichloropropene ] l.O I · 10 I< 1.0 I< 50 DI< 5.0 DI< 5.0 Dj< l.O I ___________________________________ I
ALL COMPOUNDS EXPRESSED IN MICROGRAMS/LITER UNLESS OTHERWISE NarED,
ALL NON-DETECT VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLECT DILl.Tl'IONS/SAMPLE VOLUME).
SEE ATTACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
(l} • SAMPLES WERE DILl.Tl'ED BY THE NUMERICAL VALUE DISPLAYED.
DETECTION LIMITS HAVE BEEN INCREASED BY THE SAME FACTOR.
227 French Landing Drive Nashville, Tennessee 37228 615-345-1115 FAX [phone]
Eckenfelder Laboratory, LLC
Client: FCX #18895.006
Date Reported: 07/31/00
G0016
I ECI<ENFELDER SAMPLE NUMBER I VlBLK0724 I 0007069-01D 0007069-020 I 0007069-03D j 0007069-04 I
1----------------------------------------------I-----------I----------------------1-----------1-----------1 I DATE SAMPLED I NA I 07/13/00 07/13/00 I 07/13/00 I 07/13/00 I
I DATE RECEIVED I NA I 01/1s/oo 01/1s/oo I 07/15/oo I 01/1s/oo I
I DATE ANALYZED I 07/24/00 I 07/24/00 07/24/00 1· 07/24/00 I 07/24/00 I
!---------------------------------------------1-----------I----------------------1-----------1-----------1 I I M.BLANK I MP-5 MP-2 I EW-10 I Trip Blank!
I CLIENT SAMPLE DESCRIPTION I I I I #1607 I
I I I I I I
1----------------------------------------------I-----------I---------------------1-----------1-----------1 I VOLATILE ORGANICS I I I I so X(ll s.a· x11> I s.a x11> I I
I BY USEPA CLP sow OLM03. 2 I MDL 1 ~QL I CONC I CONC CONC ,I CONC I CONC I
1------------------------------------------.· --1-----------1-----------1-----------I-----------I-----------I I Ethylbenzene l 1.0 10 I< 1.0 I< SO DI< 5.0 DI< 5.0 Dj< 1.0 I'
! 2-HaJtanone I 2.0 20 I< 2.0 !< 100 DI< 10 Dj< 10 DI< 2.0 I
I Methylene chloride I 1.0 10 I< l.O !< 50 DI< 5.0 DI< s.o DI 1.1 J!
I 4-Methyl-2-pentanone I 2.0 20 I< 2.0 J< l_OO DI< 10 D[< 10 D[< 2.0 l
I Styrene I 1.0 10 I< 1.0 J< 50 DI< s.o DI< 5.0 DI< 1.0 I
I 1,1,2,2-Tetrachloroethane I 1.0 10 I< 1.0 I< 50 DI< 5.0 □I< 5.0 D[< 1,0 J
! Tetrachloroethene [ 1.0 10 ]< 1.0 I 4700 DI 920 DI 570 DI< 1.0 I
l Toluene I 1.0 10 I< 1.0 I< 50 D[< 5.0 D[< 5.0 DJ< 1.0 I
I 1,1,1-Trichloroethane I 1.0 10 I< 1.0 [< 50 D[< 5.0 D!< 5.0 DJ< 1.0 I
I 1,1,2-Trichloroethane I 1.0 10 I< 1.0 I< 50 D[<. 5.0 DI< 5.0 DJ< 1.0 I
I Trichloroethene I 1.0 10 I< 1.0 I< 50 DI 10 JDI 5.9 JDI< 1.0 I
1 Vinyl chloride I 2.0 20 I< 2.0 1< 100 DI< 10 DI< 10 DI<· 2.0 !
I Xylene(total) I 1.0 10 I< 1.0 I<. 50 DI< 5.o DI< 5.0 DI< 1.0 I ! _____________________________ !
ALL COMPOUNDS EXPRESSED IN MICROGRAMS/LITER UNLESS OTI!ERWISE NOTED.
ALL NON-DETECT VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLE0CT DILUIIONS/SAMPLE VOLUME).
SEE ATTACHED PAGE FOR DEFINITIONS OF_ TERMS AND QUALIFIERS.
(1) • SAMPLES WERE DILlTI'ED BY TiiE NUMERICAL VALUE DISPLAYED.
DETECTION LIMITS HAVE BEEN INCREASED BY THE SAME FACTOR.
Eckenfelder
//ll!CbiLA
D. Rick Davis
Vice President
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Client: FCX #18895.006
Date Reported: 08/07/00
Eckenfelder
Laborato!"¾ LLC
.. I
cor:17
[ ECI<ENFELDER SAMPLE NUMBER I v1aLK012a 100011oe-010[00011oa-02ofooo11oa-030[00011oa-040[
1----------------------------------------------I-----------I-----------I----------1-------:--1-----------1 I DATE SAMPLED I NA I 07/19/00 I 07/19/00 I 07/19/00 I 07/19/00 I
I DATE RECEIVED I NA I 07/22/00 I 07/22/00 I 07/22/00 I 07/22/00 I
I DATE ANALYZED I 07/28/00 I 07/28/00 I 07/28/00 I 07/28/00 I 07/28/00 I
1------------------------------------------·---1-----------1-----------1-----------1-----------1-----------1
I I M.BLANK I MP-l2 I MP-ll I EW-15 I MP-4 I
I CLIENT SAMPLE DESCRIFr!ON I I I I I I
I I I I I I I
1-------------------------------·--------------1-----------1-----------1-----------1-----------1-----------1 I VOLATILE ORGANICS I I I I 10 X(l) I 5.0 X(l) I 10 X(l) I 10 X(l) I
[ BY USEPA CLP sow OLM03. 2 [ MDL j EQL j CONC [ CONC I C:ONC [ CONC [ CONC j
1--------------------------·-------------------1-----------1-----------1-----------1-----------1-----------1
I Acetone I 5.0 I 50 I< s.o I 210 JD] 93
] Benzene I 1.0 I 10 I< 1.0 I< 10 D[< s.o
I Bromodichloromethane I 1.0 I 10 I< 1.0 I< 10 D[< 5.0
I Bromcfonn ! 1.0 I 10 I< 1.0 I< 10 D[< 5.0
I Bromomethane l 6.0 I 60 I< 6.0 I< 60 D[< 30
I 2-But:anone I 10 I 100 l<· 10 I< 100 DI< 50
I Carbon disulfide I 1.0 l 10 I< 1.0 I< 10 DJ< 5.0
carbon tetrachloride I 1.0 I 10 I< l.O I< 10 D[< 5.0
Chlorobenzene I 1.0 I 10 I< 1.0 I< 10 D[< 5.0
Chloroethano I 2.0 I 20 [< 2.0 I< 20 DI< 10
Chloroform I 1.0 I 10 [< 1.0 I 36 JOI 52
Chloromethane I 2.0 I 20 I< 2.0 ]< 20 D[< 10
Dibromochloromethane J 1.0 I 10 )< 1.0 I< 10 DI< 5.0
l,l-Dichloroethane I 1.0 I 10 I< 1.0 I< 10 DI< s.o
1,2-DichlOroethane .I 1.0 I 10 I< 1.0 I< 10 DI< 5.0
·1,1-Dichloroethene I 1.0 I 10 I< 1.0 [< 10 DI< 5.0
cie-1,2-Dichloroothene I 1.0 I 10 I< 1.0 I 140 DI 33
trana-l,2-Dichloroethcno I 1.0 I 10 I< 1.0 l< 10 DI< 5.0
1,2-Dichloropropane I l.O l 10 I< 1.0 ]< 10 DI< 5.0
cie-1,3-Dichloropropena 1 1.0 l 10 1< 1.0 I< 10 DI< S.O
trane-1,3-Dichloropropene I 1.0 I 10 I< 1.0 . I< 10 D]< 5.0
JDI 230
DJ< 10
DI< 10
Di< 10
DI< 60
Di 810
10
DI< 10
DI< 10
DI< 20
Di 30
□I< 20
□I< 10
10
10
79
DI< 10
DI< 10
DI< 10
DI< 10
170
10
Di< 10
DI< 60
JDI< 100
□I< 10
□I< 10
DI< 10
□I< 20
JDI 82
Df < 20
DI< 10
DI< 10
DI< 10
D] < 10
JDI 12
10
10
10
JDI
Di
Di
Di
DI
□I
□I Di
Di
DI
JDI
DI
Di
Di
□I
01 JDI
DI
Di
DI
Di __________________________________ !
ALL COMPOUNDS EXPRESSED IN MICROGRAMS/LITER UNLESS OTiiERWISE NOTED.
ALL NON-DETECT.VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLECT DILUI'IONS/SAMPLE VOLUME).
SEE ATTACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
(1) • SAMPLES WERE DILlITED BY THE NUMERICAL VALUE DISPLAYED.
DETECTION LIMITS HAVE BEEN INCREASED BY THE SAME FACTOR.
227 French Landing Drive Nashville, Tennessee 37228 615-345-1115 FAX [phone]
Eckenfelder Labo~atory, LLC
Client: FCX #18895.006
Date Reported: 08/07/00
COO!B
I ECKENFELDER SAMPLE NUMBER I VlBLK.0728 ] 0007108-0lDj 0007108-020 I 0007108-03D 0007108-04D I
1----------------------------------------------1-----------1-----------1-----------1----------------------1
I DATE SAMPLED I NA I 07/19/00 I 07/19/00 I 07/19/00 07/19/00 I
1· DATE RECEIVED I NA I 07/22/00 I 07/22/00 I 07/22/00 07/22/00 I
I DATE ANALYZED I 07/28/00 I 07/28/00 I 07/28/00 I 07/28/00 07/28/00 I
1----------------------------------------------1-----------1-----------1-----------1----------------------1
I I M.BLANK I MP-12 I MP-ll I EW-16 MP-4 I
I CLIENT SAMPLE DESCRIPTION I I I I I
I I I. I I I
1------c-----------------____ . --------------1-----------1-----------1-----------1----------------------1
I VOLATILE ORGANICS I I I I 10 X(l) I 5.0 X(l) I 10 X(l) 10 X(l) I
! BY USEPA CLP sow OLM03, 2 I MDL I EOL I CONC I CONC I CONC I CONC CONC I
1----------------------------------------------1·-----------1-----------1-----------1-----------1-----------1
I Ethylbenzene I 1.0 10 1< 1.0 I< 10 DI< s.o DI< 10 DI< 10 Dj
I 2-He.xanone I 2.0 20 I< 2.0 I< 20 DI< 10 DI< 20 D!< 20 DI
I Methylene chloride I 1.0 10 I< 1.0 I< 10 DI< 5.0 DI< 10 DI< 10 D]
j 4-Methyl-2-pentanone [ 2,0 20 I< 2.0 I< 20 DI< 10 DI< 20 DI< 20 DI
1 Styrene I 1.0 10 I< 1.0 I< 10 DI< 5,0 DI< 10 D1< 10 DI
I 1,1,2,2-Tetrachloroethane I 1.0 10 I< 1.0 l< 10 Dj< 5.0 D[< 10 DI< 10 DI
l Tetrachloroethene [ 1.0 10 I< 1.0 1 1800 DI 960 DI 770 DI 2800 DI
I Toluene I 1.0 10 I< 1.0 I< 10 DJ< 5.0 D[< 10 D[< 10 DI
I 1,1,1-Trichloroethane I 1.0 10 I< 1.0 I< 10 DJ< 5.0 DI< 10 DI< 10 DI
I l,1,2-Trichloroethane I 1.0 10 ]< 1.0 I< 10 DI< 5.0 D[< 10 DI< 10 DJ
I Trichloroethene I 1.0 10 ] < 1.0 I 67 JDI 16 JDI 32 JD[ 14 JDI
I Vinyl chloride I 2.0 20 I< 2.0 [< 20 DI< 10 Dj< 20 D)< 20 DI
I Xylene(total) I 1.0 10 I< 1.0 I< 10 DI< 5.0 DJ< 10 DI< 10 D[
1 ________________________________ 1
ALL COMPOUNDS EXPRESSED IN MICROGRAMS/LITER UNLESS OTIIERWISE NOTED.
ALL NON-DETECT VALUES ARE REFORI'ED AS <MDL (MODIFIED. TO REFLECT ·D1LlJTIONS/SAMPLE VOLUME).
SEE AITACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
· (1) .. SAMPLES WERE DILTJl'ED BY THE NUMERICAL VALUE DISPLAYED.
DETECTION LIMITS HAVE BEEN INCREASED BY THE SAME FACTOR.
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Eckenfelder Laboratory, LLC
Client: FCX #18895.006
Date Reported: 08/07/00
I ECKENFELDER SAMPLE NUMBER 100011oe-osn100011oe-asn100011oa-01010001100-oa I
l----------------------------------------------1-----------I-----------I-----------I-----------I I DATE SAMPLED I 07/20/00 I 07/20/00 I 07/19/00 I 07/22/00 I
I DATE RECEIVED I 07/22/00 I 07/22/00 I 07/22/00 I 07/J2/00 I
I DATE ANALYZED I 07/28/00 I 07/J8/00 I 07/28/00 I 07/28/00 I
I---------------------------------------.------l-----------1-----------1-----------1---~ ------1 I I MP-6 I MP-l IMP-ll, DUFEI SfORAGE I
I CLIENT SAMPLE DESCRIPTION I I I I BLANK I
I I I I I I
1------~ -------------~---------~-----------l-----------l-----------1-----------1-----------1
I VOLATILE ORGANICS I I I 20 X(l) I 5.0 X(l) I s.o X(l) I I
I BY USEPA CLP SOW OLM.03.2 I MDL ] EQL j CONC [ CONC I CONC I CONC j
1----------------------------------------------1-----------1-----------1-----------1-----------1
\ Acetone ! , 5.0 I 50 I 420 JOI 88 JOI 71 JD!< 5.0 I
Benzene I 1.0 I 10 I< 20 DI< 5.0 DI< s.o Dj< 1.0 I
Bromodichloromethane I l.O l 10 I< 20 DI< 5.0 D! 8.2 JOI< 1.0 [
Brcmoform I 1.0 I 10 !< 20 DI< s.o Dj< 5.0 DI< 1.0 l
Bromornethane I 6.0 I 60 I< 120 D!< 30 DI< 30 DI< 6.0 I
2-Butanone ] 10 I 100 I< 200 DI< 50 DI< 50 DI< 10 I
Carbon disulfide I 1.0 I 10 [< 20 DI< s.o DI< 5.o DI< 1.0 I
carbon tetrachloride I 1.0 I 10 ! 450 DI< s.o DI< s.o DI< 1.0 I
Chlorobonzene I 1.0 l 10 l< 20 D[< 5.0 Di< 5.0 D[< 1.0 l
Chloroothane ! 2.0 I 20 ]< 40 D!< 10 D[< 10 DI< 2.0 I
Chloroform. j 1.0 I 10 I 130 JOI< 5.0 D[ 74 DI< 1.0 •I
Chlorornathana I 2.0 [ 20 I< 40 DJ< 10 DI< 10 DI< 2.0 I
Dibromochloromathana I 1,0 I 10 I< 20 DI< 5.0 DJ< s.o DI< 1.0 I
1,1-Dichloroethane I l.O I 10 !< 20 DI< 5.0 DI< 5.0 DI< 1.0 1
1,2-Dichlorcethane I 1.0 I 10 1< 20 DI< 5.0 DI< s.o DI< 1.0 I
1,1-Dichloroethene I 1.0 I 10 I< 20 DI< 5.0 D[< 5.0 Dj< 1.0 I
cie-1,2-Dichloroethene I 1,0 I 10 I 250 DI< 5.0 DI 46 JOI< 1.0 I
trans-1,2-Dichlorcethene I 1.0 I 10 I< 20 DI< 5.0 DI< 5.0 D[< 1.0 I
1,2-Dichloroprcpane [ 1.0 I 10 I 97 JDI< 5.0 DI< 5.0 DI< 1.0 1
cis-l,3-Dichloropropene l 1.0 I 10 I< 20 DI< 5.0 DI< 5.0 DI< 1.0· I
trans-1,3-Dichlcroprcpene I 1.0 I 10 [< 20 DI< 5.0 DI< 5.0 DI< 1.0 I ______________________________ I
ALL COMPOUNDS EXPRESSED IN MICROORAMS/LITER UNLESS OTHERWISE NOTED.
ALL NON-DETECT VALUES ARE REPORI'ED AS <MDL (MODIFIED TO REFLECT DILtrI'IONS/SAMPLE VOLUME).
SEE ATTACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
{l) • SAMPLES WERE DILtrrED BY THE NUMERICAL VALUE DISPLAYED.
DETECTION LIMITS HAVE ·BEEN INCREASED BY THE SAME FACTOR.
G00!9
Eckenfelder Laboratory, LLC
Client: FCX #18895.006
Date Reported: 08/07/00
I ECKENFELDER SAMPLE NUMBER 00071oe-osojooa,1oe-000100071oa-o,0[00011oe-oa I
1---------------------------------------------------------1-----------1-----------1-----------1
I DATE SAMPLED 07/20/00 I 07/20/00 I 07/19/00 I 07/22/00 I
I DATE RECEIVED 07/22/00 I 07/22/00 I 07/22/00 I 07/22/00 I
I DATE ANALYZED 07/28/00 I 07/28/00 I 07/28/00 I 07/28/00 I
1--------------------------------------------------------1-----------1-----------1-----------1.
I MP-6 I MP-1 IMP-11, DUPEI STORAGE I
I CLIENT SAMPLE DESCRIPTION I I I BLANK I
:---------------------------------. --------------. -- --: .: . --... ··. _[ ---.· _f -....• -:
I VOLATILE ORGANICS I I 20 X(l) I 5,0 X(l) I 5.0 X(l) I I
I BY USEPA CLP SOW OLM03. 2 [ MDL J EQL CONC I CONC [ CONC j CONC [
1---------------------------------------------------------l-----------1-----------1-----------1 I Ethylbenzene I 1.0 I 10 1< 20 DI< 5.0 DJ< 5.0 Dj< 1.0 ]
I 2-Hexanone I 2.0 I 20 I< 40 DI< 10 □I< 10 D!< 2.0 I
I Methylene chloride I 1.0 I 10 I< 20 DI< 5.0 D]< 5.0 DJ 4.0 JI
I 4-Methyl-2-pentanone J 2.0 I 20 I< 40 DI< 10 DJ< 10 DJ< 2.0 I
[ Styrene I 1.0 I 10 [< 20 DI< 5.0 D[< 5.0 D]< 1.0 I
I 1,1,2,2-Tetrachloroetbane I 1.0 1 10 I< 20 DI< 5.0 Dj< 5.0 DJ< 1.0 I
I Tetrachloroethene I l.O I 10 I 3800 DJ 850 DI 1200 Dj < 1.0 I
I Toluene I 1.0 I 10 [< 20 DI< s.o D[< 5.0 D[< 1.0 I
I 1,1,1-Trichloroethane l 1.0 I 10 [< 20 DI< 5.0 DI< s.o DI< 1.0 I
· I 1,1,2-Trichloroethane j 1.0 I 10 I< 20 D]< s.o D[< s.o DI< 1.0 I
I Trichloroethane I 1.0 I 10 I 170 JDI s·.o JDI 22 JDI < 1.0 I
I Vinyl chloride I 2.0 I 20 I< 40 DI< 10 D[< 10 DI< 2.0 I
. I Xylene(total) I 1.0 I 10 I< 20 DI< s.o DI< 5.0 DI< 1.0 I
1 _________________________ 1
ALL COMPOUNDS Ex.PRESSED IN MICROGRAMS/LITER UNLESS OTHERWISE NOTED.
ALL NON-DETECT VALUES ARE REPORI'ED AS <MDL (MODIFIED TO REFLECT DILUTIONS/SAMPLE VOLUME).
SEE A'ITACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
(1) • SAMPLES WERE DILtrrED BY THE NUMERICAL VALUE DISPLAYED.
DETECTION LIMITS HAVE BEEN INCREASED BY THE SAME FACTOR.
Eckenfelder Laboratory, LLC
»7£0~
D. Rick Davis
Vice President
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GOG20 I
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ANALYTICAL REPORT TERMS AND QUALIFIERS (GC/MS)
" 0 ,'• ,, 1 v V r.._
MDL: The method detection limit (MDL) is defined as the minimum
. concentration of a substance that can be measured and reported with
99% confidence that the analyte concentration is greater than zero. The
MDL is determined from analysis of a sample containing the analyte in a
given matrix.
EQL: The estimated quantitation limit (EQL) is defined as the estimated
concentration above which quantitative results can be obtained with a
specific degree of confidence. Eckenfelder Laboratory, LLC. defines the
EQL to be ten times the MDL.
B: The presence of a "B" to the right of an analytical value indicates that
this compound was also detected in the method blank and the data
should be interpreted with caution. One should consider the possibility
that the correct sample result might be less than the reported result and,
perhaps, zero.
D: When a sample (or sample extract) is rerun diluted because one of the
compound concentrations exceeded the highest concentration range for
the standard curve, all of the values obtained in the dilution run will be
flagged with a "D".
E: The concentration for any compound found which exceeds the highest
concentration level on the standard curve for that compound will be
flagged with an "E". Usually the sample will be rerun at a dilution to
quantitate the flagged compound.
J: The presence of a" J" to the right of an analytical result indicates that the
reported result is estimated. The mass spectral data pass the
identification criteria showing that the compound is present, but the
calculated result is less than the EQL. One should feel confident that
the result is greater than zero and less than the EQL.
L:'-REPORTS'\ABT&QLT.DOC
FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET
EW-9 COG:22
Lab Name: ECKENFELDER LLC Contract: FCX
Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FCX.V07050
Matrix: (soil/water) WATER
Sample wt/vol: ,
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
Soil Extract Volume: ____ (uL)
Lab Sample ID: 0007050-01
Lab File ID: 0705001D
Date Sampled: 07/11/00
Date Analyzed: 07/23/00
Dilution Factor: 50.0
Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q
67-64-1---------Acetone 720 BJD
71-43-2---------Benzene 500 UD
75-27-4---------Bromodichloromethane 500 UD
75-25-2---------Bromoform 500 UD
74-83-9---------Bromomethane 1000 UD
78-93-3---------2-Butanone 2400 JD
75-15-0---------Carbon disull:1.cle 500 UD
56-23-5---------Carbon tetrachloricle 500 UD
108-90-7--------Chlorobenzene 500 UD
75-00-3---------Chloroethane 1000 UD
67-66-3---------Chloroform 65 JD
74-87-3---------Chloromethane 1000 UD
124-48-1--------Dibromochloromethane 500 UD
75-34-3---------1,1-Dichloroethane 500 UD
107-06-2--------1,2-Dichloroethane 500 UD
75-35-4---------1,1-Dichloroethene 500 UD
156-59-2--------cis-1,2-Dichloroethene 190 JD
156-60-5--------trans-1,2-Dichloroethene __ 500 UD
78-87-5---------1,2-Dichloropropane 500 UD
10061-01-5------cis-1,3-Dichloropropene 500 UD
10061-02-6------trans-1,3-Dichloropropene __ 500 UD
100-41-4--------Ethylbenzene 500 UD
591-78-6--------2-Hexanone 1000 UD
75-09-2---------Methylene diioricle 500 UD
108-10-1--------4-Methyl-2-pentanone 1000 UD
100-42-5--------Styrene 500 UD
79-34-5---------1,1,2,2-Tetrachloroethane __ 500 UD
127-18-4--------Tetrachloroethene 4500 D
108-88-3--------Toluene 500 UD
71-55-6---------1,1,1-Trichloroethane 500 UD
79-00-5---------1,1,2-Trichloroethane 500 UD
79-01-6---------Trichloroethene 500 UD
FORM I VOA
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FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET
Lab Name: ECKENFELDER LLC Contract: FCX -______ ,,_, p 2 3 EW-9 I
Lab Code: NA Batch No.: NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
5.000 (g/mL) ML
LOW
GC Column: DB-624 ID: 0.53 (mm)
Soil Extract Volume: ____ (uL)
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
SAS No.: NA SOO No.: FCX.V07050
Lab Sample ID: 0007050-01
Lab File ID: 0705001D
Date Sampled: 07/11/00
Date Analyzed: 07/23/00
Dilution Factor: 50.0
Soil Aliquot Volume:
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
1000
500
___ (uL)
Q
UD
UD
FORM I VOA
FORM 1
VOLATILE ORGANICS ANALYSIS DATA SHEET
Lab Name: ECKENFELDER LLC Contract: FCX
CLIENT SAMPLE
NO. I'" ,I ',) , ~ lj
MP-13 --I
Lab Code: NA Batch No.: NA SAS No.: NA SDG No.: FCX.V07050
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
Soil Extract Volume: (uL) ---
Lab Sample ID: 0007050-02
Lab File ID: 0705002D
Date Sampled: 07/11/00
Date Analyzed: 07/23/00
Dilution Factor: 50.0
Soil Aliquot Volume:
CAS NO. COMPOUND
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
___ (uL)
Q
67-64-1---------Acetone 700 BJD 71-43-2---------Benzene 500 UD
75-27-4---------Bromodichloromethane 500 UD
75-25-2---------Bromoform 500 UD 74-83-9---------Bromomethane 1000 UD 78-93-3---------2-Butanone 5000 UD
75-15-0---------Carbon disulfiae 500 UD
56-23-5---------Carbon tetrachloride 500 UD 108-90-7--------Chlorobenzene 500 UD
75-00-3---------Chloroethane 1000 UD
67-66-3---------Chloroform 59 JD
74-87-3---------Chloromethane 1000 UD
124-48-1--------Dibromochloromethane 500 UD 75-34-3---------1,1-Dichloroethane 500 UD
107-06-2--------1,2-Dichloroethane 500 UD
75-35-4---------1,1-Dichloroethene 500 UD 156-59-2--------cis-1,2-Dichloroethene 4000 D
156-60-5--------trans-1,2-Dichloroethene __ 500 UD
78-87-5---------1,2-Dichloropropane 370 JD
10061-01-5------cis-1,3-Dichloropropene 500 UD 10061-02-6------trans-1,3-Dichloropropene __ 500 UD 100-41-4--------Ethylbenzene 500 UD
591-78-6--------2-Hexanone 1000 UD
75-09-2---------Methylene chloride 500 UD 108-10-1--------4-Methyl-2-pentanone 1000 UD
100-42-5--------Styrene 500 UD
79-34-5---------1,1,2,2-Tetrachloroethane __ 500 UD
127-18-4--------Tetrachloroethene 35000 DE
108-88-3--------Toluene 500 UD
71-55-6---------1,1,1-Trichloroethane 500 UD
79-00-5---------1,1,2-Trichloroethane 500 UD
79-01-6---------Trichloroethene 2000 D
FORM I VOA
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FORM 1
VOLATILE ORGANICS ANALYSIS DATA SHEET
CLIENT SAMPLE NO.
-----04+10, G 2 5
MP-13
Lab Name: ECKENFELDER LLC Contract: FCX
Lab Code: NA Batch No.: NA
Matrix: (soil/water) WATER
Sample wt/vol: 5.000 (g/mL) ML
LOW Level: (low/med)
% Moisture: not dee.
GC Column: DB-624 ID: 0.53 (mm)
Soil Extract Volume: ____ (uL)
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
SAS No.: NA SDG No.: FCX.V07050
Lab Sample ID: 0007050-02
Lab File ID: 0705002D
Date Sampled: 07/11/00
Date Analyzed: 07/23/00
Dilution Factor: 50.0
Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
1000 UD
500 UD
FORM I VOA
FORM 1
VOLATILE ORGANICS ANALYSIS DATA SHEET
CLIENT SAMPLE NO. I
MP-13 00026
Lab Name: ECKENFELDER LLC Contract: FCX
Lab Code: NA Batch No.: NA SAS No.: NA SDG No.: FCX.V07050
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0. 53 (mm)
Soil Extract Volume: (uL) ---
Lab Sample ID: 0007050-02
Lab File ID: 0705002D
Date Sampled: 07/11/00
Date Analyzed: 07/24/00
Dilution Factor: 250.0
Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q
67-64-1---------Acetone 1900 JD
71-43-2---------Benzene 2500 UD
75-27-4---------Bromodichloromethane 2500 UD 75-25-2---------Bromoform 2500 UD
74-83-9---------Bromomethane 5000 UD
78-93-3---------2-Butanone 25000 UD 75-15-0---------Carbon disulfide 2500 UD
56-23-5---------Carbon tetrachloride 2500 UD
108-90-7--------Chlorobenzene 2500 UD
75-00-3---------Chloroethane 5000 UD 67-66-3---------Chloroform 2500 UD 74-87-3---------Chloromethane 5000 UD
124-48-1--------Dibromochloromethane 2500 UD
75-34-3---------1,1-Dichloroethane 2500 UD
107-06-2--------1,2-Dichloroethane 2500 UD 75-35-4---------1,1-Dichloroethene 2500 UD
156-59-2--------cis-1,2-Dichloroethene 3300 D
156-60-5--------trans~l,2-Dichloroethene __ 2500 UD
78-87-5---------1,2-Dichloropropane 280 JD
10061-01-5------cis-1,3-Dichloropropene 2500 UD
10061-02-6------trans-1,3-Dichloropropene __ 2500 UD
100-41-4--------Ethylbenzene 2500 UD
591-78-6--------2-Hexanone 5000 UD
75-09-2---------Methylene chloricie 2500 UD 108-10-1--------4-Methyl-2-pentanone 5000 UD 100-42-5--------Styrene 2500 UD
79-34-5---------1,1,2,2-Tetrachloroethane __ 2500 UD
127-18-4--------Tetrachloroethene 29000 D
108-88-3--------Toluene 2500 UD
71-55-6---------1,1,1-Trichloroethane 2500 UD
79-00-5---------1,1,2-Trichloroethane 2500 UD
79-01-6---------Trichloroethene 1600 JD
FORM I VOA
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FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET
Lab Name: ECKENFELDER LLC Contract: FCX -------\,; p G 2 7 MP-13 I
Lab Code: NA Batch No. : NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
Soil Extract Volume: (uL) ----
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
SAS No.: NA SDG No.: FCX.V07050
Lab Sample ID: 0007050-02
Lab File ID: 0705002D
Date Sampled: 07/11/00
Date Analyzed: 07/24/00
Dilution Factor: 250.0
Soil Aliquot Volume:
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
5000
2500
___ (uL)
Q
UD
UD
FORM I VOA
FORM 1
VOLATILE ORGANICS ANALYSIS DATA SHEET
CLIENT SAMPLE NO. R
()n•~
MP-3 r• •~. Lab Name: ECKENFELDER LLC Contract: FCX
Lab Code: NA Batch No.: NA SAS No.: NA SDG No.: FCX.V07050
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
Lab Sample ID: 0007050-03
Lab File ID: 0705003
Date Sampled: 07/12/00
Date Analyzed: 07/24/00
Dilution Factor: 1.0
Soil Extract Volume: (uL) ----Soil Aliquot Volume:
CAS NO. COMPOUND
67-64-1---------Acetone
71-43-2---------Benzene
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
75-27-4---------Bromodichloromethane
75-25-2---------Bromoform
74-83-9---------Bromomethane
78-93-3---------2-Butanone
75-15-0---------Carbon disulfiae
56-23-5---------carbon tetrachloriae
108-90-7--------Chlorobenzene
75-00-3---------Chloroethane
67-66-3---------Chloroform
74-87-3---------Chloromethane
124-48-1--------Dibromochloromethane
75-34-3---------1,1-Dichloroethane
107-06-2--------1,2-Dichloroethane
75-35-4---------1,1-Dichloroethene
156-59-2--------cis-1,2-Dichloroethene
156-60-5--------trans~l,2-Dichloroethene __
78-87-5---------1,2-Dichloropropane
10061-01-5------cis-1,3-Dichloropropene
10061-02-6------trans-1,3-Dichloropropene
100-41-4--------Ethylbenzene --
591-78-6--------2-Hexanone
75-09-2---------Methylene cnloriae
108-10-1--------4-Methyl-2-pentanone
100-42-5--------Styrene ·
79-34-5---------1,1,2,2-Tetracnloroetnane __
127-18-4--------Tetrachloroethene
108-88-3--------Toluene
71-55-6---------1,1,1-Tricnloroetl'iane
79-00-5---------1,1,2-Trichloroethane
79-01-6---------Trichloroethene
FORM I VOA
50
10
10
10
20
100
10
3.0
10
20
1.8
20
10
10
10
9.6
10
10
10
10
10
10
20
10
20
10
10
37
10
10
10
1.2
___ (uL)
Q
u u u u u u u
J u u
J u u u u
J u u u u u u u u u u u
u u u
J
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FORM 1
VOLATILE ORGANICS ANALYSIS DATA SHEET
CLIENT SAMPLE NO.
______ _.,!''--'. n",(l 2 9
MP-3
Lab Name: ECKENFELDER LLC Contract: FCX
Lab Code: NA Batch No. : NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
5.000 (g/mL) ML
LOW
GC Column: DB-624 ID: 0.53 (mm)
Soil Extract Volume: ____ (uL)
CAS NO. COMPOUND
75-01-4-----~---Vinyl chloride
1330-20-7-------Xylene(total)
SAS No.: NA SDG No.: FCX.V07050
Lab Sample ID: 0007050-03
Lab File ID: 0705003
Date Sampled: 07/12/00
Date Analyzed: 07/24/00
Dilution Factor: 1.0
Soil Aliquot Volume:
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
20
10
___ (uL)
Q
u
u
FORM I VOA
FORM 1
VOLATILE ORGANICS ANALYSIS DATA SHEET CLIENT SAMPLE NO. I
cop:o
Lab Name: ECKENFELDER LLC Contract: FCX MP-7 I I
Lab Code: NA Batch No.: NA SAS No.: NA SDG No.: FCX.V07050
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
Soil Extract Volume: ____ (uL)
Lab Sample ID: 0007050-04
Lab File ID: 0705004D
Date Sampled: 07/12/00
Date Analyzed: 07/24/00
Dilution Factor: 20.0
Soil Aliquot Volume: ___ (uL)
CAS NO. COMPOUND
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
67-64-1---------Acetone 120 JD 71-43-2---------Benzene 200 UD
75-27-4---------Bromodichloromethane 200 UD
75-25-2---------Bromoform 200 UD
74-83-9---------Bromomethane 400 UD 78-93-3---------2-Butanone 2000 UD
75-15-0---------Carbon disulria:e 200 UD
56-23-5---------Carbon tetrachloria:e 46 JD
108-90-7--------Chlorobenzene 200 UD
75-00-3---------Chloroethane 400 UD
67-66-3---------Chloroform 68 JD
74-87-3---------Chloromethane 400 UD
124-48-1--------Dibromochloromethane 200 UD
75-34-3---------1,1-Dichloroethane 200 UD
107-06-2--------1,2-Dichloroethane 200 UD
75-35-4---------1,1-Dichloroethene 200 UD
156-59-2--------cis-1,2-Dichloroethene 220 D
156-60-5--------trans~l,2-Dichloroethene __ 200 UD
78-87-5---------1,2-Dichloropropane 200 UD
10061-01-5------cis-1,3-Dichloropropene 200 UD
10061-02-6------trans-1,3-Dichloropropene __ 200 UD 100-41-4--------Ethylbenzene 200 UD
591-78-6--------2-Hexanone 400 UD
75-09-2---------Methylene chloria:e 200 UD
108-10-1--------4-Methyl-2-pentanone 400 UD
100-42-5--------Styrene 200 UD
79-34-5---------1,1,2,2-Tetrachloroethane __ 200 UD 127-18-4--------Tetrachloroethene 6200 D~ 8/1 108-88-3--------Toluene 200 UD
71-55-6---------1,1,1-Trichloroethane 200 UD
79-00-5---------1,1,2-Trichloroethane 200 UD
79-01-6---------Trichloroethene 61 JD
FORM I VOA
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FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET
lj VU 31
MP-7
Lab Name: ECKENFELDER LLC Contract: FCX
Lab Code: NA Batch No. : NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
5.000 (g/mL) ML
LOW
GC Column: DB-624 ID: 0.53 (mm)
Soil Extract Volume: ____ (uL)
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
SAS No.: NA SDG No.: FCX.V07050
Lab Sample ID: 00070500 04
Lab File ID: 0705004D
Date Sampled: 07/12/00
Date Analyzed: 07/24/00
Dilution Factor: 20.0
Soil Aliquot Volume:
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
400
200
___ (uL)
Q
UD
UD
FORM I VOA
FORM 1
VOLATILE ORGANICS ANALYSIS DATA SHEET CLIENT SAMPLE NO. I
f"'(\;,'\"l""I --,,,TR=IP;s--cB"'LA..---+1:,,-l)i-l,u.; G
Lab Name: ECKENFELDER LLC Contract: FCX
NK #1604
Lab Code: NA Batch No.: NA SAS No.: NA SDG No.: FCX.V07050
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
Lab Sample ID: 0007050-05
Lab File ID: 0705005
Date Sampled: 07/11/00
Date Analyzed: 07/24/00
Dilution Factor: 1.0
Soil Extract Volume: ____ (uL) Soil Aliquot Volume:
CAS NO. COMPOUND
67-64-1---------Acetone
71-43-2---------Benzene
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
75-27-4---------Bromodichloromethane
75-25-2---------Bromoform
74-83-9---------Bromomethane
78-93-3---------2-Butanone
75-15-0---------Carbon disulfiae
56-23-5---------Carbon tetrachloriae
108-90-7--------Chlorobenzene
75-00-3---------Chloroethane
67-66-3---------Chloroform
74-87-3---------Chloromethane
124-48-1--------Dibromochloromethane
75-34-3---------1,1-Dichloroethane
107-06-2--------1,2-Dichloroethane
75-35-4---------1,1-Dichloroethene
156-59-2--------cis-1,2-Dichloroethene
156-60-5--------trans-1,2-Dichloroethene __
78-87-5---------1,2-Dichloropropane
10061-01-5------cis-1,3-Dichloropropene
10061-02-6------trans-1,3-Dichloropropene
100-41-4--------Ethylbenzene .--
591-78-6--------2-Hexanone
75-09-2---------Methylene chloriae
108-10-1--------4-Methyl-2-pentanone
100-42-5--------Styrene ·
79-34-5---------1,1,2,2-Tetrachloroethane __
127-18-4--------Tetrachloroethene
108-88-3--------Toluene
71-55-6---------1,1,1-Trichloroethane
79-00-5---------1,1,2-Trichloroethane
79-01-6---------Trichloroethene
FORM I VOA
50
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___ (uL)
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FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET
TRIP BLA L p O 3 3
Lab Name: ECKENFELDER LLC Contract: FCX NK #1604 I
Lab Code: NA Batch No. : NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
5.000 (g/mL) ML
LOW
GC Column: DB-624 ID: 0.53 (mm)
Soil Extract Volume: ____ (uL)
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
SAS No.: NA SDG No.: FCX.V07050
Lab Sample ID: 0007050-05
Lab File ID: 0705005
Date Sampled: 07/11/00
Date Analyzed: 07/24/00
Dilution Factor: 1.0
Soil Aliquot Volume:
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
20
10
___ (uL)
Q
u u
FORM I VOA
FORM 1
VOLATILE ORGANICS ANALYSIS DATA SHEET
CLIENT SAMPLE NO. I
Lab Name: ECKENFELDER LLC Contract: FCX __ M_P_-5 __ 0_0 p J JI
Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FCX.V07069
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
5.000 (g/mL) ML
LOW
GC Column: DB-624 ID: 0.53 (mm)
Soil Extract Volume: ____ (uL)
Lab Sample ID: 0007069-01
Lab File ID: 0706901D
Date Sampled: 07/13/00
Date Analyzed: 07/24/00
Dilution Factor: 50.0
Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q
67-64-1---------Acetone 440 JD
71-43-2---------Benzene 500 UD
75-27-4---------Bromodichloromethane 500 UD 75-25-2---------Bromoform 500 UD
74-83-9---------Bromomethane 1000 UD
78-93-3---------2-Butanone 5000 UD
75-15-0---------Carbon disull:ia:e 500 UD
56-23-5---------Carbon tetrachloria:e 500 UD
108-90-7--------Chlorobenzene 500 UD
75-00-3---------Chloroethane 1000 UD
67-66-3---------Chloroform 500 UD
74-87-3---------Chloromethane 1000 UD
124-48-1--------Dibromochloromethane 500 UD
75-34-3---------1,1-Dichloroethane 500 UD
107-06-2--------1,2-Dichloroethane 500 UD
75-35-4---------1,1-Dichloroethene 500 UD
156-59-2--------cis-1,2-Dichloroethene 87 JD
156-60-5--------trans-1,2-Dichloroethene __ 500 UD
78-87-5---------1,2-Dichloropropane 500 UD
10061-01-5-~----cis-1,3-Dichloropropene 500 UD
10061-02-6------trans-1,3-Dichloropropene __ 500 UD
100-41-4--------Ethylbenzene 500 UD
591-78-6--------2-Hexanone 1000 UD
75-09-2---------Methylene chloria:e 500 UD
108-10-1--------4-Methyl-2-pentanone 1000 UD
100-42-5--------Styrene 500 UD
79-34-5---------1,1,2,2-Tetrachloroethane __ 500 UD
127-18-4--------Tetrachloroethene 4700 D
108-88-3--------Toluene 500 UD
71-55-6---------1,1,1-Trichloroethane 500 UD
79-00-5---------1,1,2-Trichloroethane 500 UD
79-01-6---------Trichloroethene 500 UD
FORM I VOA
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FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET
Lab Name: ECKENFELDER LLC Contract: FC:X ___ M_P_-_5 __ c_o_r J 5
SDG No.: FC:X.V07069 Lab Code: NA Batch No.: NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
5.000 (g/mL) ML
LOW
GC Column: DB-624 ID: 0.53 (mm)
Soil Extract Volume: ____ (uL)
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
SAS No.: NA
Lab Sample ID: 0007069-01
Lab File ID: 0706901D
Date Sampled: 07/13/00
Date Analyzed: 07/24/00
Dilution Factor: 50.0
Soil Aliquot Volume:
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
1000
500
---
Q
UD
UD
FORM I VOA
(uL)
FORM 1
VOLATILE ORGANICS ANALYSIS DATA SHEET
CLIENT SAMPLE NO. I
Lab Name: ECKENFELDER LLC Contract: FCX
MP-2 I
-----"'-"'GO b 3 GI
Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FCX.V07069
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID : 0 . 53 ( mm)
Soil Extract Volume: ____ (uL)
Lab Sample ID: 0007069-02
Lab File ID: 706902D
Date Sampled:. 07/13/00
Date Analyzed: 07/24/00
Dilution Factor: 5.0
Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q
67-64-1---------Acetone 40 JD
71-43-2---------Benzene 50 UD
75-27-4---------Bromodichloromethane 50 UD 75-25-2---------Bromoform 50 UD
74-83-9---------Bromomethane 100 UD
78-93-3---------2-Butanone 500 UD
75-15-0---------Carbon disulfiae 50 UD 56-23-5---------Carbon tetrachloriae 50 UD
108-90-7--------Chlorobenzene 50 UD
75-00-3---------Chloroethane 100 UD
67-66-3---------Chloroform 61 D
74-87-3---------Chloromethane 100 UD
124-48-1--------Dibromochloromethane 50 UD
75-34-3---------1,1-Dichloroethane 50 UD
107-06-2--------1,2-Dichloroethane 50 UD 75-35-4---------1,1-Dichloroethene 50 UD
156-59-2--------cis-l,2-Dichloroethene 30 JD
156-60-5--------trans-l,2-Dichloroethene __ 50 UD
78-87-5---------1,2-Dichloropropane 50 UD 10061-01-5------cis-l,3-Dichloropropene 50 UD
10061-02-6------trans-l,3-Dichloropropene __ 50 UD
100-41-4--------Ethylbenzene 50 UD
591-78-6--------2-Hexanone 100 UD
75-09-2---------Methylene chloriae 50 UD
108-10-1--------4-Methyl-2-pentanone 100 UD
100-42-5--------Styrene 50 UD
79-34-5---------1,1,2,2-Tetrachloroethane __ 50 UD
127-18-4--------Tetrachloroethene 920 D
108-88-3--------Toluene 50 UD
71-55-6---------1,1,1-Trichloroethane 50 UD
79-00-5---------1,1,2-Trichloroethane 50 UD
79-01-6---------Trichloroethene 10 JD
FORM I VOA
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FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET
MP-2
Lab Name: ECKENFELDER LLC Contract: FCX
Lab Code: NA Batch No. : NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
5.000 (g/mL) ML
LOW
GC Column: DB-624 ID: 0.53 (mm)
Soil Extract Volume: ____ (uL)
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
SAS No.: NA SDG No.: FCX.V07069
Lab Sample ID: 0007069-02
Lab File ID: 706902D
Date Sampled: 07/13/00
Date Analyzed: 07/24/00
Dilution Factor: 5.0
Soil Aliquot Volume:
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
100
50
___ (uL)
Q
UD
UD
FORM I VOA
FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET
Lab Name: ECKENFELDER LLC Contract: FCX
Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FCX.V07069
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
5.000 (g/mL) ML
LOW
GC Column: DB-624 ID: 0.53 (mm)
Soil Extract Volume: ____ (uL)
Lab Sample ID: 0007069-03
Lab File ID: 706903D
Date Sampled: 07/13/00
Date Analyzed: 07/24/00
Dilution Factor: 5.0
Soil Aliquot Volume: ____ (uL)
CONCENTRATION UNITS:
CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q
67-64-1---------Acetone 36 JD
71-43-2---------Benzene 50 UD
75-27-4---------Bromodichloromethane 50 UD 75-25-2---------Bromoform 50 UD
74-83-9---------Bromomethane 100 UD
78-93-3---------2-Butanone 500 UD
75-15-0---------Carbon disulfide 50 UD 56-23-5---------Carbon tetrachloride 50 UD
108-90-7--------Chlorobenzene 50 UD
75-00-3---------Chloroethane 100 UD
67-66-3---------Chloroform 5.5 JD
74-87-3---------Chloromethane 100 UD 124-48-1--------Dibromochloromethane 50 UD 75-34-3---------1,1-Dichloroethane 50 UD 107-06-2--------1,2-Dichloroethane 50 UD
75-35-4---------1,1-Dichloroethene 50 UD
156-59-2--------cis-1,2-Dichloroethene 50 UD
156-60-5--------trans-1,2-Dichloroethene __ 50 UD
78-87-5---------1,2-Dichloropropane 50 UD 10061-01-5------cis-1,3-Dichloropropene 50 UD
10061-02-6------trans-1,3-Dichloropropene __ 50 UD
100-41-4--------Ethylbenzene 50 UD
591-78-6--------2-Hexanone 100 UD
75-09-2---------Methylene chloride 50 UD
108°10-1--------4-Methyl-2-pentanone 100 UD
100-42-5--------Styrene 50 UD
79-34-5---------1,1,2,2-Tetrachloroethane __ 50 UD
127-18-4--------Tetrachloroethene 570 D
108-88-3--------Toluene 50 UD 71-55-6---------1,1,1-Trichloroethane 50 UD 79-00-5---------1,1,2-Trichloroethane 50 UD
79-01-6---------Trichloroethene 5.9 JD
FORM I VOA
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FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET
Lab Name: ECKENFELDER LLC Contract: FCX EW-lO G0~39
SDG No.: FCX.V07069 Lab Code: NA Batch No. : NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/rnL) ML
LOW
ID: 0.53 (mm)
Soil Extract Volume: ____ (uL)
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
SAS No.: NA
Lab Sample ID: 0007069-03
Lab File ID: 706903D
Date Sampled: 07/13/00
Date Analyzed: 07/24/00
Dilution Factor: 5.0
Soil Aliquot Volume:
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
100
50
___ (uL)
Q
UD
UD
FORM I VOA
FORM 1
VOLATILE ORGANICS ANALYSIS DATA SHEET
CLIENT SAMPLE NO. I
Lab Name: ECKENFELDER LLC Contract: FCX
TRIP BLA I,,
NK #1607 C Op~ 01
Lab Code: NA Batch No.: NA SAS No.: NA SDG No.: FCX.V07069
Matrix: (soil/water) WATER Lab Sample ID: 0007069-04
Lab File ID: 0706904
Date Sampled: 07/13/00
Date Analyzed: 07/24/00
Dilution Factor: 1.0
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
Soil Extract Volume: (uL) ----Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q
" 67-64-1---------Acetone 50 u
71-43-2---------Benzene 10 u
75-27-4---------Bromodichloromethane 10 u
75-25-2---------Bromoform 10 u
74-83-9---------Bromomethane 20 u
78-93-3---------2-Butanone 100 u
75-15-0---------Carbon disulfide 10 u
56-23-5---------Carbon tetrachloride 10 u
108-90-7--------Chlorobenzene 10 u
75-00-3---------Chloroethane 20 u
67-66-3---------Chloroform 10 u
74-87-3---------Chloromethane 20 u
124-48-1--------Dibromochloromethane 10 u
75-34-3---------1,1-Dichloroethane 10 u
107-06-2--------1,2-Dichloroethane 10 u
75-35-4---------1,1-Dichloroethene 10 u
156-59-2--------cis-1,2-Dichloroethene 10 u
156-60-5--------trans-1,2-Dichloroethene 10 u
78-87-5---------1,2-Dichloropropane --10 u
10061-01-5------cis-1,3-Dichloropropene 10 u
10061-02-6------trans-1,3-Dichloropropene 10 u 100-41-4--------Ethylbenzene --10 u
591-78-6--------2-Hexanone 20 u
75-09-2---------Methylene chloride 1.1 J
108-10-1--------4-Methyl-2-pentanone . 20 u
100-42-5--------Styrene 10 u
79-34-5---------1,1,2,2-Tetrachloroethane __ 10 u
127-18-4--------Tetrachloroethene 10 u
108-88-3--------Toluene 10 u
71-55-6---------1,1,1-Trichloroethane 10 u
79-00-5---------1,1,2-Trichloroethane 10 u
79-01-6---------Trichloroethene 10 u
FORM I VOA
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FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET
TRIP BLA ri
Lab Name: ECKENFELDER LLC Contract: FCX NK #1607 C '.10 4 l
Lab Code: NA Batch No. : NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
Soil Extract Volume: (uL) ----
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
SAS No.: NA SDG No.: FCX.V07069
Lab Sample ID: 0007069-04
Lab File ID: 0706904
Date Sampled: 07/13/00
Date Analyzed: 07/24/00
Dilution Factor: 1.0
Soil Aliquot Volume:
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
20
10
---
Q
u u
(uL)
FORM I VOA
FORM 1
VOLATILE ORGANICS ANALYSIS DATA SHEET
CLIENT SAMPLE NO. I
Lab Name: ECKENFELDER LLC Contract: FCX ___ M_P_-_1_2 __ ,-_~ , ;; 1
Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FCX.V07108
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0. 53 (mm)
Soil Extract Volume: (uL) ----
Lab Sample ID: 0007108-01
Lab File ID: 0710801D
Date Sampled: 07/19/00
Date Analyzed: 07/28/00
Dilution Factor: 10.0
Soil Aliquot Volume:
CAS NO. COMPOUND
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
67-64-1---------Acetone 210 JD 71-43-2---------Benzene 100 UD 75-27-4---------Bromodichloromethane 100 UD 75-25-2---------Bromoform 100 UD 74-83-9---------Bromomethane 600 UD
78-93-3---------2-Butanone 1000 UD 75-15-0---------Carbon disulfide 100 UD 56-23-5---------Carbon tetrachlon.de 100 UD 108-90-7--------Chlorobenzene 100 UD 75-00-3---------Chloroethane 200 UD 67-66-3---------Chloroform 36 JD 74-87-3---------Chloromethane 200 UD 124-48-1--------Dibromochloromethane 100 UD 75-34-3---------1,1-Dichloroethane 100 UD 107-06-2--------1,2-Dichloroethane 100 UD
75-35-4---------1,1-Dichloroethene 100 UD 156-59-2--------cis-1 2-Dichloroethene 140 D ' . 156-60-5--------trans-1,2-Dichloroethene 100 UD 78-87-5---------1,2-Dichloropropane --100 UD 10061-01-5------cis-1,3-Dichloropropene 100 UD 10061-02-6------trans-1,3-Dichloropropene __ 100 UD 100-41-4--------Ethylbenzene 100 UD 591-78-6--------2-Hexanone 200 UD 75-09-2---------Methylene chloride 100 UD 108-10-1--------4-Methyl-2-pentanone 200 UD 100-42-5--------Styrene 100 UD 79-34-5---------1,1,2,2-Tetrachloroethane __ 100 UD 127-18-4--------Tetrachloroethene 1800 D 108-88-3--------Toluene 100 UD
71-55-6---------1,1,1-Trichloroethane 100 UD 79-00-5---------1,1,2-Trichloroethane 100 UD 79-01-6---------Trichloroethene 67 JD 75-01-4---------Vinyl chloride 200 UD
FORM I VOA
(uL)
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FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET
Lab Name: ECKENFELDER LLC Contract: FCX
Lab Code: NA Batch No. : NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
Soil Extract Volume: ____ (uL)
CAS NO. COMPOUND
SAS No.: NA SDG No.: FCX.V07108
Lab Sample ID: 0007108-01
Lab File ID: 0710801D
Date Sampled: 07/19/00
Date Analyzed: 07/28/00
Dilution Factor: 10.0
Soil Aliquot Volume: ___ (uL)
CONCENI'RATION UNITS:
(ug/L or ug/Kg) UG/L Q
1330-20-7-------Xylene(total) ______ _ 1ool_uo __
FORM I VOA
FORM 1
VOLATILE ORGANICS ANALYSIS DATA SHEET CLIENT SAMPLE NO. I
Lab Name: ECKENFELDER LLC Contract: FCX ___ MP_-_1_1 __ C_~ Q ~ 'I
Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FCX.V07108
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
Lab Sample ID: 0007108-02
Lab File ID: 0710802D
Date Sampled: 07/19/00
Date Analyzed: 07/28/00
Dilution Factor: 5.0
Soil Extract Volume: (uL) ----Soil Aliquot Volume:
CAS NO. COMPOUND
67-64-1---------Acetone
71-43-2---------Benzene
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
75-27-4---------Bromodichloromethane
75-25-2---------Bromoform
74-83-9---------Bromomethane
78-93-3---------2-Butanone
75-15-0---------Carbon disulfiae
56-23-5---------Carbon tetrachloride
108-90-7--------Chlorobenzene
75-00-3---------Chloroethane
67-66-3---------Chloroform
74-87-3---------Chloromethane
124-48-1--------Dibromochloromethane
75-34-3---------1,1-Dichloroethane
107-06-2--------1,2-Dichloroethane
75-35-4---------1,1-Dichloroethene
156-59-2--------cis-1,2-Dichloroethene
156-60-5--------trans-1,2-Dichloroethene
78-87-5---------1,2-Dichloropropane --
10061-01-5------cis-1,3-Dichloropropene
10061-02-6------trans-1,3-Dichloropropene
100-41-4--------Ethylbenzene --
591-78-6--------2-Hexanone
75-09-2---------Methylene chloriae
108-10-1--------4-Methyl-2-pentanone
100-42-5--------Styrene
79-34-5---------1,1,2,2-Tetrachloroethane __
127-18-4--------Tetrachloroethene
108-88-3--------Toluene
71-55-6---------1,1,1-Trichloroethane
79-00-5---------1,1,2-Trichloroethane
79-01-6---------Trichloroethene
75-01-4---------Vinyl chloride
FORM I VOA
93
50
50
50
300
500
50
50
50
100
52
100
50
50
50
50
33
50
50
50
50
50
100
50
100
50
50
960
50
50
50
16
100
___ (uL)
Q
JD
UD
UD
UD
UD
UD
UD
UD
UD
UD
D
UD
UD
UD
UD
UD
JD
UD
UD
UD
UD
UD
UD
UD
UD
UD
UD
D
UD
UD
UD
JD
UD
I
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I
I
I
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I
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FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET
Lab Name: ECKENFELDER LLC Contract: FCX ___ MP_-_1_1 __ G p Q ,j 5
S!Xl No.: FCX.V07108 Lab Code: NA Batch No.: NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
Soil Extract Volume: (uL) ----
CAS NO. COMPOUND
SAS No.: NA
Lab Sample ID: 0007108-02
Lab File ID: 0710802D
Date Sampled: 07/19/00
Date Analyzed: 07/28/00
Dilution Factor: 5.0
Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
1330-20-7-------Xylene (total) _____________ 5_0 l_uo __
FORM I VOA
FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET
Lab Name: ECKENFELDER LLC Contract: FCX
Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FCX.V07108
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
Soil Extract Volume: ____ (uL)
Lab Sample ID: 0007108-03
Lab File ID: 0710803D
Date Sampled: 07/19/00
Date Analyzed: 07/28/00
Dilution Factor: 10.0
Soil Aliquot Volume:
CAS NO. COMPOUND
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
67-64-1---------Acetone 230 JD
71-43-2---------Benzene 100 UD
75-27-4---------Bromodichloromethane 100 UD
75-25-2---------Bromoform 100 UD
74-83-9---------Bromomethane 600 UD
78-93-3---------2-Butanone 810 JD
75-15-0---------Carbon disulfiae 100 UD
56-23-5---------Carbon·tetrachloriae 100 UD
108-90-7--------Chlorobenzene 100 UD ·75-00-3----- ----Chloroethane 200 UD
67-66-3---------Chloroform 30 JD
74-87-3---------Chloromethane 200 UD 124-48-1~-------Dibromochloromethane 100 UD 75-34-3---------1,1-Dichloroethane 100 UD
107-06-2--------1,2-Dichloroethane 100 UD
75-35-4---------1,1-Dichloroethene 100 UD
156-59-2--------cis-1,2-Dichloroethene 79 JD
156-60-5--------trans-1,2-Dichloroethene __ 100 UD 78-87-5---------1,2-Dichloropropane 100 UD
10061-01-5------cis-1,3-Dichloropropene 100 UD
10061-02-6------trans-1,3-Dichloropropene __ 100 UD
100-41-4--------Ethylbenzene 100 UD
591-78-6--------2-Hexanone 200 UD
75-09-2---------Methylene chloriae 100 UD
108-10-1--------4-Methyl-2-pentanone 200 UD
100-42-5--------Styrene 100 UD
79-34-5---------1,1,2,2-Tetrachloroethane __ 100 UD
127-18-4--------Tetrachloroethene 770 D 108-88-3--------Toluene 100 UD
71-55-6---------1,1,1-Trichloroethane 100 UD
79-00-5---------1,1,2-Trichloroethane 100 UD
79-01-6---------Trichloroethene 32 JD 75-01-4---------Vinyl chloride 200 UD
FORM I VOA
:~
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(uL) I
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FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET
EW-16 I
Lab Name: ECKENFELDER LLC Contract: FCX -----~t'~1 D~@ ij 7
Lab Code: NA Batch No.: NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
Soil Extract Volume: ____ (uL)
CAS NO. COMPOUND
SAS No.: NA SDG No.: FCX.V07108
Lab Sample ID: 0007108-03
Lab File ID: 0710803D
Date Sampled: 07/19/00
Date Analyzed: 07/28/00
Dilution Factor: 10.0
Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
1330-20-7-------Xylene(total) ______ _
FORM I VOA
FORM 1
VOLATILE ORGANICS ANALYSIS DATA SHEET CLIENT SAMPLE NO. I
Lab Name: ECKENFELDER LLC Contract: FCX MP-41 •
------'----1+<0 d O Ii t.11
Lab Code: NA Batch No. : NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
SAS No.: NA SDG No.: FCX.V07108
Lab Sample ID: 0007108-04
Lab File ID: 0710804D
Date Sampled: 07/19/00
Date Analyzed: 07/28/00
Dilution Factor: 10.0
Soil Extract Volume: (uL) ----Soil Aliquot Volume: ____ (uL)
I
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I
I
I
I
I
I
CAS NO. COMPOUND
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
67-64-1---------Acetone
71-43-2---------Benzene
75-27-4---------Bromodichloromethane
75-25-2---------Bromoform
74-83-9---------Bromomethane
78-93-3---------2-Butanone
75-15-0---------Carbon disulfide
56-23-5---------Carbon tetrachloride
108-90-7--------Chlorobenzene
75-00-3---------Chloroethane
67-66-3---------Chloroform
74-87-3---------Chloromethane
124-48-1--------Dibromochloromethane
75-34-3---------1,1-Dichloroethane
107-06-2--------1,2-Dichloroethane
75-35-4---------1,1-Dichloroethene
156-59-2--------cis-l,2-Dichloroethene
156-60-5--------trans-l,2-Dichloroethene __
78-87-5°--------1,2-Dichloropropane
10061-01-5------cis-l,3-Dichloropropene
10061-02-6------trans-l,3-Dichloropropene
100-41-4--------Ethylbenzene --
591-78-6--------2-Hexanone
75-09-2---------Methylene chloride
108-10-1--------4-Methyl-2-pentanone .
100-42-5--------Styrene
79-34-5---------1,1,2,2-Tetrachloroethane __
127-18-4--------Tetrachloroethene
108-88-3--------Toluene
71-55-6---------1,1,1-Trichloroethane
79-00-5---------1,1,2-Trichloroethane
79-01-6---------Trichloroethene
75-01-4----c----Vinyl chloride
FORM I VOA
170
100
100
100
600
1000
100
100
100
200
82
200
100
100
100
100
12
100
100
100
100
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200
100
200
100
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2800
100
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200
Q
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FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET
Lab Name: ECKENFELDER LLC Contract: FCX ___ MP_-_4 ___ G p O Ii 9
Lab Code: NA Batch No.: NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
Soil Extract Volume: ____ (uL)
CAS NO. COMPOUND
SAS No.: NA SDG No.: FCX.V07108
Lab Sample ID: 0007108-04
Lab File ID: 0710804D
Date Sampled: 07/19/00
Date Analyzed: 07/28/00
Dilution Factor: 10.0
Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
1330-20-7-------Xylene(total) ____________ 1_o_ol_un __
FORM I VOA
FORM 1
VOLATILE ORGANICS ANALYSIS DATA SHEET
Lab Name: ECKENFELDER LLC Contract: FCX
CLIENT SAMPLE NO. I
,~),e:01 MP-6 _______ ,_.,Jr V
Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FCX.V07108
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
Soil Extract Volume: (uL) ----
Lab Sample ID: 0007108-05
Lab File ID: 710805D2
Date Sampled: 07/20/00
Date Analyzed: 07/28/00
Dilution Factor: 20.0
Soil Aliquot Volume:
CAS NO. COMPOUND
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
67-64-1---------Acetone 420 JD
71-43-2---------Benzene 200 UD 75-27-4---------Bromodichloromethane 200 UD 75-25-2---------Bromoform 200 UD
74-83-9---------Bromomethane 1200 UD
78-93-3---------2-Butanone 2000 UD 75-15-0---------Carbon disulfioe 200 UD 56-23-5---------Carbon tetrachlorioe 450 D
108-90-7--------Chlorobenzene 200 UD
75-00-3---------Chloroethane 400 UD 67-66-3---------Chloroform 130 JD
74-87-3---------Chloromethane 400 UD 124-48-1--------Dibromochloromethane 200 UD 75-34-3---------1,1-Dichloroethane 200 UD 107-06-2--------1,2-Dichloroethane 200 UD
75-35-4---------1,1-Dichloroethene 200 UD
156-59-2--------cis-l,2-Dichloroethene 250 D
156-60-5--------trans~l,2-Dichloroethene __ 200 UD
78-87-5---------1,2-Dichloropropane 97 JD 10061-01-5------cis-l,3-Dichloropropene 200 UD
10061-02-6------trans-l,3-Dichloropropene __ 200 UD
100-41-4--------Ethylbenzene 200 UD
591-78-6--------2-Hexanone 400 UD
75-09-2---------Methylene chlorioe 200 UD
108-10-1--------4-Methyl-2-pentanone 400 UD 100-42-5--------Styrene 200 UD
79-34-5---------1,1,2,2-Tetrachloroethane __ 200 UD
127-18-4--------Tetrachloroethene 3800 D 108-88-3--------Toluene 200 UD 71-55-6---------1,1,1-Trichloroethane 200 UD 79-00-5---------1,1,2-Trichloroethane 200 UD 79-01-6---------Trichloroethene 170 JD
75-01-4---------Vinyl chloride 400 UD
FORM I VOA
(uL)
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FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET
Lab Name: ECKENFELDER LLC Contract: FCX MP-6 I O t". ____ p •0-,1
Lab Code: NA Batch No. : NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
Soil Extract Volume: ____ (uL)
CAS NO. COMPOUND
SAS No.: NA SDG No.: FCX.V07108
Lab Sample ID: 0007108-05
Lab File ID: 710805D2
Date Sampled: 07/20/00
Date Analyzed: 07/28/00
Dilution Factor: 20.0
Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
1330-20-7-------Xylene(total) ______ _ 200I_UD __
FORM I VOA
FORM 1
VOLATILE ORGANICS ANALYSIS DATA SHEET CLIENT SAMPLE NO. I
G010521 MP-1
Lab Name: ECKENFELDER LLC Contract: FCX -------
Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FCX.V07108
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
Soil Extract Volume: ____ (uL)
Lab Sample ID: 0007108-06
Lab File ID: 0710806D
Date Sampled: 07/20/00
Date Analyzed: 07/28/00
Dilution Factor: 5.0
Soil Aliquot Volume:
CAS NO. COMPOUND
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
67-64-1---------Acetone 88 JD
71-43-2---------Benzene so UD
75-27-4---------Bromodichloromethane so UD
75-25-2---------Bromoform so UD
74-83-9---------Bromomethane 300 UD
78-93-3---------2-Butanone 500 UD
75-15-0---------Carbon disulficle so UD
56-23-5---------Carbon tetrachloricle so UD
108-90-7--------Chlorobenzene so UD
75-00-3---------Chloroethane 100 UD
67-66-3---------Chloroform so UD
74-87-3---------Chloromethane 100 UD
124-48-1--------Dibromochloromethane so UD
75-34-3---------1,1-Dichloroethane so UD
107-06-2--------1,2-Dichloroethane 50 UD
75-35-4---------1,1-Dichloroethene so UD
156-59-2--------cis-l,2-Dichloroethene so UD
156-60-5--------trans-l,2-Dichloroethene __ 50 UD
78-87-5---------1,2-Dichloropropane 50 UD
10061-01-5------cis-l,3-Dichloropropene so UD
10061-02-6------trans-l,3-Dichloropropene __ so UD
100-41-4--------Ethylbenzene so UD
591-78-6--------2-Hexanone 100 UD
75-09-2---------Methylene chloride so UD
108-10-1--------4-Methyl-2-pentanone 100 UD
100-42-5--------Styrene so UD
79-34-5---------1,1,2,2-Tetrachloroethane __ 50 UD
127-18-4--------Tetrachloroethene 850 D
108-88-3--------Toluene so UD
71-55-6---------1,1,1-Trichloroethane 50 UD
79-00-5---------1,1,2-Trichloroethane so UD
79-01-6---------Trichloroethene 5.0 JD
75-01-4---------Vinyl chloride 100 UD
FORM I VOA
(uL)
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FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET
Lab Name: ECKENFELDER LLC Contract: FCX ___ M_P_-_i ___ r O G 5 3
Lab Code: NA Batch No. : NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0. 53 (mm)
Soil Extract Volume: ____ (uL)
CAS NO. COMPOUND
SAS No.: NA SDG No.: FCX.V07108
Lab Sample ID: 0007108-06
Lab File ID: 0710806D
Date Sampled: 07/20/00
Date Analyzed: 07/28/00
Dilution Factor: 5.0
Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
1330-20-7-------Xylene(total) _____________ 5_ol_UD __
FORM I VOA
FORM 1
VOLATILE ORGANICS ANALYSIS DATA SHEET
CLIENT SAMPLE NO. I
Lab Name: ECKENFELDER LLC Contract: FCX
q",c· r:4
MP-11, DUPE :
1
l, "'1
Lab Code: NA Batch No . : NA SAS No.: NA SDG No.: FCX.V07108
Matrix: (soil/water) WATER Lab Sample ID: 0007108-07
Sample wt/vol: Lab File ID: 0710807D
Level: (low/med)
% Moisture: not dee.
·GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
Soil Extract Volume: (uL) ----
Date Sampled: 07/19/00
Date Analyzed: 07/28/00
Dilution Factor: 5.0
Soil Aliquot Volume:
CAS NO. COMPOUND
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
67-64-1---------Acetone
71-43-2---------Benzene
75-27-4---------Bromodichloromethane
75-25-2---------Bromoform
74-83-9---------Bromomethane
78-93-3---------2-Butanone
75-15-0---------Carbon disulfide
56-23-5---------Carbon tetrachloride
108-90-7--------Chlorobenzene
75-00-3---------Chloroethane
67-66-3---------Chloroform
74-87-3---------Chloromethane
124-48-1--------Dibromochloromethane
75-34-3---------1,1-Dichloroethane
107-06-2--------1,2-Dichloroethane
75-35-4---------1,1-Dichloroethene
156-59-2--------cis-l,2-Dichloroethene
156-60-5--------trans-l,2-Dichloroethene __
78-87-5---------1,2-Dichloropropane
10061-01-5------cis-l,3-Dichloropropene
10061-02-6------trans-l,3-Dichloropropene __
100-41-4--------Ethylbenzene
591-78-6--------2-Hexanone
75-09-2---------Methylene chloride
108-10-1--------4-Methyl-2-pentanone .
100-42-5--------Styrene
79-34-5---------1,1,2,2-Tetrachloroethane
127-18-4--------Tetrachloroethene --
108-88-3--------Toluene
71-55-6---------1,1,1-Trichloroethane
79-00-5---------1,1,2-Trichloroethane
79-01-6---------Trichloroethene
75-01-4---------Vinyl chloride
FORM I VOA
Q
71 JD
50 UD
8.2 JD
50 UD
300 UD
500 UD
50 UD
50 UD
50 UD
100 UD
74 D
100 UD
50 UD
50 UD
50 UD
50 UD
46 JD
50 UD
50 UD
50 UD
50 UD
50 UD
100 UD
50 UD
100 UD
50 UD
50 UD
1200 D~ 11/
50 UD
50 UD
50 UD
22 JD
100 UD
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FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET · qoo55
Lab Name: ECKENFELDER LLC Contract: FCX MP-11, DUPEI
Lab Code: NA Batch No. : NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
Soil Extract Volume: (uL) ----
CAS NO. COMPOUND
SAS No.: NA SDG No.: FCX.V07108
Lab Sample ID: 0007108-07
Lab File ID: 0710807D
Date Sampled: 07/19/00
Date Analyzed: 07/28/00
Dilution Factor: 5.0
Soil Aliquot Volume:
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
___ (uL)
Q
1330-20-7-------Xylene (total) _____________ 5_0 l_uo __
FORM I VOA
FORM 1
VOLATILE ORGANICS ANALYSIS DATA SHEET CLIENT SAMPLE NO.~ r· J n,.,.., lj
STORAGE BLANK Lab Name: ECKENFELDER LLC Contract: FCX
Lab Code: NA Batch No.: NA SAS No.: NA SDG No.: FCX.V07108
Matrix: (soil/water) WATER Lab Sample ID: 0007108-08
Sample wt/vol: Lab File ID: 0710808
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
Soil Extract Volume: (uL) ----
Date Sampled: 07/22/00
Date Analyzed: 07/28/00
Dilution Factor: 1.0
Soil Aliquot Volume:
CAS NO. COMPOUND
67-64-1---------Acetone
71-43-2---------Benzene
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
75-27-4---------Bromodichloromethane
75-25-2---------Bromoform
74-83-9---------Bromomethane
78-93-3---------2-Butanone
75-15-0---------Carbon disull:icle
56-23-5---------Carbon tetrachlor1.cle
108-90-7--------Chlorobenzene
75-00~3---------Chloroethane
67-66-3---------Chloroform
74-87-3---------Chloromethane
124-48-1--------Dibromochloromethane
75-34-3---------1,1-Dichloroethane
107-06-2--------1,2-Dichloroethane
75-35-4---------1,1-Dichloroethene
156-59-2--------cis-1,2-Dichloroethene
156-60-5--------trans~l,2-Dichloroethene __
78-87-5---------1,2-Dichloropropane
10061-01-5------cis-1,3-Dichloropropene
10061-02-6------trans-1,3-Dichloropropene
100-41-4--------Ethylbenzene --
591-78-6--------2-Hexanone
75-09-2---------Methylene chloricle
108-10-1--------4-Methyl-2-pentanone
100-42-5--------Styrene
79-34-5---------1,1,2,2-Tetrachloroethane __
127-18-4--------Tetrachloroethene
108-88-3--------Toluene
71-55-6---------1,1,1-Trichloroethane
79-00-5-----~---l,1,2-Trichloroethane
79-01-6---------Trichloroethene
75-01-4---------Vinyl chloride
FORM I VOA
Q
50 u
10 u
10 u
10 u
60 u
100 u
10 u
10 u
10 u
20 u
10 u
20 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
20 u
4.0 J
20 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
20 u
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FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET
Lab Name: ECKENFELDER LLC Contract: FCX
STORAGE BLANK 1 Q Q 5 7
SDG No.: FCX.V07108 Lab Code: NA Batch No.: NA
Matrix: (soil/water) WATER
Sample wt/vol: 5.000 (g/mL) ML
Level: (low/med) LOW
% Moisture: not dee.
GC Column: DB-624 ID: 0.53 (mm)
Soil Extract Volume: ____ (uL)
CAS NO. COMPOUND
SAS No.: NA
Lab Sample ID: 0007108-08
Lab File ID: 0710808
Date Sampled: 07/22/00
Date Analyzed: 07/28/00
Dilution Factor: 1.0
Soil Aliquot Volume: ____ (uL)
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
1330-20-7-------Xylene(total) -------1olu
--------------------------------
FORM I VOA
FORM 2
WATER VOLATILE SYSTEM MONITORING COMPOUND RECOVERY
Lab Name: ECKENFELDER LLC Contract: FCX
Lab Code: NA
page 1 of 1
Batch No. : NA SAS No.: NA SDG No.: FCX.V07050
LAB SMCl SMC2 SMC3 SMC4 TOT
SAMPLE NO. (DFM) # (DCE)# (TOL)# (BFB) # OUT
------------;;;:===== =====;;;: ====== ==:::::=== ---01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
V1BLK0723
EW-9
MP-13
V1BLK0724
TRIP BLANK
MP-3
MP-7
MP-13
MP.-3MS
MP-3MSD
SMCl
SMC2
SMC3
SMC4
(DFM) =
(DCE) =
(TOL) =
(BFB) =
107 101 96
105 100 92
103 98 96
94 96 106
# 94 99 106
93 96 106
102 105 104
96 102 105
104 99 104
** ** **
Dibromofluoromethane
1,2-Dichloroethane-d4
Toluene-dB
Bromofluoroberizene
93 0
96 0
89 0
100 0
104 0
107 0
98 0
99 0
99 0
** 0
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
----
--
--
QC LIMITS
(86-118)
(76-114)
(88-110)
(86-115)
# Column to be used to flag recovery values
* Values outside of contract required QC limits
D System Monitoring Compound diluted out
**=SEE CASE NARRATIVE.
FORM II VOA
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FORM 2
WATER VOLATILE SYSTEM MONITORING COMPOUND RECOVERY
Lab Name: ECKENFELDER LLC Contract: FCX
Lab Code: NA Batch No.: NA SAS No.: NA SDG No.: FCX.V07069
page 1 of 1
CLIENT SMCl SMC2 SMC3 SMC4 TOT
SAMPLE NO. (DFM)# (DCE)# (TOL)# (BFB) # OUT
============ ====== ====== :::::::::::::::::;::::;::::::: ;::;:;:;;;;;::;;:;::: ---
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
VlBLK0724
TRIP BLANK
MP-5
MP-2
EW-10
SMCl
SMC2
SMC3
SMC4
(DFM)
(DCE) =
(TOL) =
(BFB)
94 96 106
# 96 99 103
97 106 106
102 104 102
105 102 103
Dibromofluoromethane
l,2-Dichloroethane-d4
Toluene-dB
Bromofluorobertzene
100 0
100 0
102 0
98 0
100 0
--
--
--
--
--
--
----
--
--
----
--
--
--
--
--
--
--
--
--
--
----
QC LIMITS
(86-118)
(76-114)
(88-110)
(86-115)
# Column to be used to flag recovery values
* Values outside ·of contract required QC limits
D System Monitoring Compound diluted out
FORM II VOA
FORM 2
WATER VOLATILE SYSTEM MONITORING COMPOUND RECOVERY oooso I
Lab Name: ECKENFELDER LLC Contract: FCX I Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FCX.V07108
page 1 of 1
CLIENT SMCl SMC2 SMC3 SMC4 TOT
SAMPLE NO. (DFM) # (DCE)# (TOL)# (BFB) # OUT ======::;;===== =====::; :;;:;::;;:;;::;;:;:::;:: :;;:===== :::::::::::;;:;;;;;;;;:: ===
VlBLK0728 103 98 101
MP-12 97 94 101
MP-4 95 95 101
EW-16 98 98 104
MP-11 96 92 99
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
MP-11, DUPE 96 99 103
MP-1 94 97 102
MP-6 97 101 106
STORAGE BLAN 97 95 102
SMCl
SMC2
SMC3
SMC4
(DFM) =
(DCE)
(TOL) =
(BFB) =
Dibromofluoromethane
l,2-Dichloroethane-d4
Toluene-dB
Bromofluorobenzene
100 0
96 0
98 0
96 0
98 0
97 0
97 0
94 0
97 0
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
QC LIMITS
(86-118)
(76-114)
(88-110)
(86-115)
# Column to be used to flag recove:ry values
* Values outside of contract required QC limits
D System Monitoring Compound diluted out
FORM II VOA
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FORM 3
WATER VOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY (11)f'{i1 ., t, V
Lab Name: ECKENFELDER LLC Contract: FCX
Lab Code: NA
Matrix Spike
Batch No. : NA SAS No.: NA SDG No.: FCX.V07050
Client Sample No.: MP-3 Lab Sample ID: 0007050-03
SPIKE SAMPLE MS MS QC.
ADDED CONCENTRATION CONCENTRATION % LIMITS
COMPOUND (ug/L) (ug/L) (ug/L) REC # . REC.
======================== -----------------------------------====:;:;;;: ======
Benzene 50.00 0.0000 52.79 106 76-127
Chlorobenzene 50.00 0.0000 47.56 95 75-130
1,1-Dichloroethene 50.00 9.598 69.67 120 61-145
Toluene 50.00 0.0000 51.30 103 76-125
Trichloroethene 50.00 1.152 55.20 108 71-120
SPIKE MSD MSD
ADDED CONCENTRATION % % QC LIMITS
COMPOUND (ug/L) (ug/L) REC # RPD # RPD
======================== ----------------------====== ====== ======
Benzene 50.00 48.48 97 9 11
Chlorobenzene 50.00 47.42 95 0 13
1,1-Dichloroethene 50.00 61. 64 104 14 14
Toluene 50.00 50.92 102 1 13
Trichloroethene 50.00 51. 02 100 8 14
# Column to be used to flag recovery and RPD values with an asterisk
* Values outside of QC limits
RPD: 0 out of 5 outside limits
Spike Recovery: 0 out of 10 outside limits
COMMENTS: SEE CASE NARRATIVE CONCERNING 0007050-03MSD.
FORM III VOA
REC.
======
76-127
75-130
61-145
76-125
71-120
FORM 4
VOLATILE METHOD BLANK SUMMARY
Lab Name: ECKENFELDER LLC Contract: FCX
CLIENT SAMPLE NO. I
V1BLK072; ,) ,if 2 I
Lab Code: NA Batch No. : NA
Lab File ID: BLANK02
Date Analyzed: 07/23/00
GC Column: DB-624
Instrument ID: VOAl
ID: 0.53 (mm)
SAS No.: NA SDG No.: FCX.V07050
Lab Sample ID: V1BLK0723
Time Analyzed: 2138
Heated Purge: (Y/N) N
THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS and MSD:
COMMENTS:
page 1 of 1
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
SAMPLE NO.
::::;;:========;::::;::;
EW-9
MP-13
LAB LAB TIME
SAMPLE ID FILE ID ANALYZED
----------------------------======:::;::::== 0007050-01 0705001D 2310
0007050-02 0705002D. 2341
FORM IV VOA
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FORM 1
VOLATILE ORGANICS ANALYSIS DATA SHEET
CLIENT SAMPLE NO.
"",fi3
V1BLK0723
Lab Name: ECKENFELDER LLC Contract: FCX
Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FCX.V07050
Matrix: (soil/water) WATER Lab Sample ID: V1BLK0723
Sample wt/vol:
Level: (low/med)
5.000 (g/mL) ML
LOW
Lab File ID:
Date Sampled:
BLANK02
%'Moisture: not dee.
GC Column: DB-624 ID: 0.53 (mm)
Date Analyzed: 07/23/00
Dilution Factor: 1.0
Soil Extract Volume: (uL) ----Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q
67-64-1---------Acetone 19 J
71-43-2---------Benzene 10 u
75-27-4---------Bromodichloromethane 10 u
75-25-2---------Bromoform 10 u
74-83-9---------Bromomethane 20 u
78-93-3---------2-Butanone 100 u
75-15-0---------Carbon disulfiae 10 u
56-23-5---------Carbon tetrachloriae 10 u
108-90-7--------Chlorobenzene 10 u
75-00-3---------Chloroethane 20 u
67-66-3---------Chloroform 10 u
74-87-3---------Chloromethane 20 u
124-48-1--------Dibromochloromethane 10 u
75-34-3---------1,1-Dichloroethane 10 u
107-06-2--------1,2-Dichloroethane 10 u
75-35-4---------1,1-Dichloroethene 10 u
156-59-2--------cis-1,2-Dichloroethene 10 u
156-60-5--------trans-1,2-Dichloroethene __ 10 u
78-87-5---------1,2-Dichloropropane 10 u
10061-01-5------cis-1,3-Dichloropropene 10 u
10061-02-6------trans-1,3-Dichloropropene 10 u
100-41-4--------Ethylbenzene --10 u
591-78-6--------2-Hexanone 20 u
75-09-2---------Methylene chloriae 10 u
108-10-1--------4-Methyl-2-pentanone 20 u
100-42-5--------Styrene 10 u
79-34-5---------1,1,2,2-Tetrachloroethane __ 10 u
127-18-4--------Tetrachloroethene 10 u
108-88-3--------Toluene 10 u
71-55-6---------1,1,1-Trichloroethane 10 u
79-00-5---------1,1,2-Trichloroethane 10 u
79-01-6---------Trichloroethene 10 u
FORM I VOA
FORM 1
VOLATILE ORGANICS ANALYSIS DATA SHEET
CLIENT SAMPLE NO. I
Lab Name: ECKENFELDER LLC Contract: FCX
Lab Code: NA Batch No. : NA SAS No.: NA
V1BLK0723 Q f O 6'
SDG No.: FCX.V07050
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
Soil Extract Volume: (uL) ----
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
Lab Sample ID: V1BLK0723
Lab File ID: BLANK02
Date Sampled:
Date Analyzed: 07/23/00
Dilution Factor: 1.0
Soil Aliquot Volume: __ _
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
20
10
Q
u u
FORM I VOA
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FORM 4
VOLATILE METHOD BLANK SUMMARY
Lab Name: ECKENFELDER LLC Contract: FCX
Lab Code: NA Batch No. : NA SAS No.: NA
CLIENT SAMPLE NO.
------·~~·.., -11 n G 5
V1BLK0724
SDG No.: FCX.V07050
Lab File ID: V1BLK02
Date Analyzed: 07/24/00
GC Column: DB-624
Instrument ID: VOAl
ID: 0.53 (mm)
Lab Sample ID: V1BLK0724
Time Analyzed: 1208
Heated Purge: (Y/N) N
THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS and MSD:
COMMENTS:
page 1 of 1
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
SAMPLE NO.
------------TRIP BLANK#
MP-3
MP-7
MP-13
MP-3MS
MP-3MSD
LAB LAB TIME
SAMPLE ID FILE ID ANALYZED
--------------:;:============== ----------0007050-05 0705005 1240
0007050-03 0705003 1342
0007050-04 0705004D 1414
0007050-02 0705002D 1445
0007050-03 705003MB 1814
0007050-03 705003MD 1845
FORM IV VOA
FORM 4
VOLATILE METHOD BLANK SUMMARY
Lab Name: ECKENFELDER LLC Contract: FCX
CLIENT SAMPLE NO. I
VlBLK0724 Go r (i 61
Lab Code: NA Batch No;: NA
Lab File ID: V1BLK02
Date Analyzed: 07/24/00
GC Column: DB-624
Instrument ID: VOAl
ID: 0.53 (mm)
SAS No.: NA SDG No.: FCX.V07069
Lab Sample ID: V1BLK0724
Time Analyzed: 1208
Heated Purge: (Y/N) N
THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS and MSD:
COMMENTS:
page 1 of 1
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
SAMPLE NO.
------------TRIP BLANK # MP-5
MP-2
EW-10
LAB LAB TIME
SAMPLE ID FILE ID ANALYZED
======::::::::::;;:;:::;:::::::::::::::::::: ==========;;:::::::::::::::: ::::::::::::::::;:::;::;;::::::::::::::::::::::
0007069-04 0706904 1311
0007069-01 0706901D 1516
0007069-02 706902D 1710
0007069-03 706903D 1741
FORM IV VOA
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FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET
Lab Name: ECKENFELDER LLC Contract: FCX
V1BLK0724 ~ "! Ii G 7
Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FCX.V07050
Matrix: (soil/water) WATER Lab Sample ID: V1BLK0724
Sample wt/vol:
Level: (low/med)
5.000 (g/mL) ML
WW
Lab File ID: V1BLK02
Date Sampled:
% Moisture: not dee.
GC Column: DB-624 ID: 0.53 (mm)
Date Analyzed: 07/24/00
Dilution Factor: 1.0
Soil Extract Volume: (uL) ----Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q
67-64-1---------Acetone 50 u
71-43-2---------Benzene 10 u
75-27-4---------Bromodichloromethane 10 u
75-25-2---------Bromoform 10 u
74-83-9---------Bromomethane 20 u
78-93-3---------2-Butanone 100 u
75-15-0---------Carbon disulric!e 10 u
56-23-5---------Carbon tetrachloric!e 10 u
108-90-7--------Chlorobenzene 10 u
75-00-3---------Chloroethane 20 u
67-66-3---------Chloroform 10 u
74-87-3---------Chloromethane 20 u
124-48-1--------Dibromochloromethane 10 u
75-34-3---------1,1-Dichloroethane 10 u
107-06-2--------1,2-Dichloroethane 10 u
75-35-4---------1,1-Dichloroethene 10 u
156-59-2--------cis-1,2-Dichloroethene 10 u
156-60-5--------trans-1,2-Dichloroethene __ 10 u
78-87-5---------1,2-Dichloropropane 10 u
10061-01-5------cis-1,3-Dichloropropene 10 u
10061-02-6------trans-1,3-Dichloropropene 10 u
100-41-4--------Ethylbenzene --10 u
591-78-6--------2-Hexanone 20 u
75-09-2---------Methylene chloric!e 10 u
108-10-1--------4-Methyl-2-pentanone 20 u
100-42-5--------Styrene 10 u
79-34-5---------1,1,2,2-Tetrachloroethane __ 10 u
127-18-4--------Tetrachloroethene 10 u
108-88-3--------Toluene 10 u
71-55-6---------1,1,1-Trichloroethane 10 u
79-00-5---------1,1,2-Trichloroethane 10 u
79-01-6---------Trichloroethene 10 u
FORM I VOA
FORM 1
VOLATILE ORGANICS ANALYSIS DATA SHEET CLIENT SAMPLE NO. I
V1BLK0724(1()1
68 1
SDG No.: FCX.V07050
Lab Name: ECKENFELDER LLC Contract: FCX
Lab Code: NA Batch No. : NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0. 53 (mm)
Soil Extract Volume: (uL) ---
CAS NO. COMPOUND
75-01-4---------Vinyl chloride
1330-20-7-------Xylene(total)
SAS No.: NA
Lab Sample ID: V1BLK0724
Lab File ID: V1BLK02
Date Sampled:
Date Analyzed: 07/24/00
Dilution Factor: 1.0
Soil Aliquot Volume:
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
20
10
Q
u u
FORM I VOA
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FORM 4 CLIENT SAMPLE NO.
VOLATILE METHOD BLANK SUMMARY
Lab Name: ECKENFELDER LLC Contract: FCX
VlBLK0728 G orj 6 9
Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FCX.V07108
Lab File ID: VlBLK0lCLP
Date Analyzed: 07/28/00
GC Column: DB-624
Instrument ID: VOAl
ID: 0.53 (mm)
Lab Sample ID: V1BLK0728
Time Analyzed: 1057
Heated Purge: (Y/N) N
THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS and MSD:
COMMENTS:
page 1 of 1
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
SAMPLE NO.
------------MP-12
MP-4
EW-16
MP-11
MP-11, DUPE
MP-1
MP-6
STORAGE BLAN
LAB LAB TIME
SAMPLE ID FILE ID ANALYZED
-------------- --------------
::;:==========
0007108-01 0710801D 1242
0007108-04 0710804D 1313
0007108-03 0710803D 1345
0007108-02 0710802D 1416
0007108-07 0710807D 1448
0007108-06 0710806D 1519
0007108-05 710805D2 1551
0007108-08 0710808 1757
'
FORM IV VOA
FORM 1
VOLATILE ORGANICS ANALYSIS DATA SHEET I CLIENT SAMPLE NO.
Lab Name: ECKENFELDER LLC Contract: FCX v1BLK072a O c!o 7 °I
Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FCX.V07108
Matrix: (soil/water) WATER Lab Sample ID: VlBLK0728
Sample wt/vol:
Level: (low/med)
5.000 (g/mL) ML
LOW
Lab File ID: VlBLK0lCLP
Date Sampled:
% Moisture: not dee.
GC Column: DB-624 ID: 0.53 (mm)
Soil Extract Volume: (uL) ----
Date Analyzed: 07/28/00
Dilution Factor: 1.0
Soil Aliquot Volume:
CAS NO. COMPOUND
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
67-64-1---------Acetone
71-43-2---------Benzene
75-27-4---------Bromodichloromethane
75-25-2---------Bromoform
74-83-9---------Bromomethane
78-93-3---------2-Butanone
75-15-0---------Carbon disulfide
56-23-5---------Carbon tetrachloride
108-90-7--------Chlorobenzene
75-00-3---------Chloroethane
67-66-3---------Chloroform
74-87-3---------Chloromethane
124-48-1--------Dibromochloromethane
75-34-3---- --- --1, 1.-Dichloroethane
107-06-2--------1,2-Dichloroethane '
75-35-4---------1,1-Dichloroethene
156-59-2--------cis-l,2-Dichloroethene
156-60-5--------trans-l,2-Dichloroethene __
78-87-5---------1,2-Dichloropropane
10061-01-5------cis-l,3-Dichloropropene
10061-02-6------trans-l,3-Dichloropropene __
100-41-4--------Ethylbenzene
591-78-6--------2-Hexanone
75-09-2---------Methylene chloride
108-10-1--------4-Methyl-2-pentanone
100-42-5--------Styrene
79-34-5---------1,1,2,2-Tetrachloroethane __
127-18-4--------Tetrachloroethene
108-88-3--------Toluene
71-55-6---------1,1,1-Trichloroethane
79-00-5---------1,1,2-Trichloroethane
79-01-6---------Trichloroethene
75-01-4---------Vinyl chloride
FORM I VOA
Q
50 u
10 u
10 u
10 u
60 u
100 u
10 u
10 u
10 u
20 u
10 u
20 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
20 u
10 u
20 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
20 u
(uL)
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FORM 1 CLIENT SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET
V1BLK0728
Lab Name: ECKENFELDER LLC Contract: FCX
Lab Code: NA Batch No.: NA
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column: DB-624
5.000 (g/mL) ML
LOW
ID: 0.53 (mm)
SAS No.: NA SDG No.: FCX.V07108
Lab Sample ID: V1BLK0728
Lab File ID: VlBLK0lCLP
Date Sampled:
Date Analyzed: 07/28/00
Dilution Factor: 1.0
n"-n·'"'· .Ji, J I J
Soil Extract Volume: ____ (uL) Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q
1330-20-7-------Xylene(total) _____________ i_ol_u __
FORM I VOA
FORM 8
VOLATILE INTERNAL STANDARD AREA AND RT SUMMARY
COG72
Lab Name: ECKENFELDER LLC Contract: FCX
Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FCX.V07050
Lab File ID (Standard): VlSTD0l
Instrument ID: VOAl
Date Analyzed: 07/23/00
Time Analyzed: 2037
Heated Purge: (Y/N) N GC Column: DB-624 ID: 0.53 (mm)
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
:::::========:;;:== 12 HOUR STD
UPPER LIMIT
LOWER LIMIT
===========::;; CLIENT
SAMPLE NO.
=========;:::::;;:::;
V1BLK0723
EW-9
MP-13
ISl (PFB)
IS2 (FLB)
IS3 (CBZ)
ISl(PFB)
AREA # RT # =======:;;:== =====:::::;;;;
238519 6.74
477038 7.24
119260 6.24
=====::;::;;::;;::;:::;:: =======
=====::::::==== ======= 368897 6.74
360025 6.74
387601 6.74
Pentafluorobenzene
= Fluorobenzene
= Chlorobenzene-d5
IS2\FLB/
AREA # RT # ----------:;::::;::::;;;:;;:;:::;::
127898 7.66
255796 8.16
63949 7.16
----------====:::;;;;::;::
----------=====:== 178828 7.64
183518 7.65
188623 7.64
AREA UPPER LIMIT= +100% of internal standard area
AREA LOWER LIMIT= -50% of internal standard area
IS3(CBZ)
AREA #
:;:::;::::;;;;;;:;:::;;::;:::;:::;::::;;
382689
765378
191345
----------
----------558527
551034
568877
RT UPPER LIMIT=+ 0.50 minutes of internal standard RT
RT LOWER LIMIT= -0.50 minutes of internal standard RT
RT #
;;:::;:::;:::;:::;:::;::::;;:
12.11
12.61
11.61
=====:::::=
======= 12.11
12.11
12.11
# Column used to flag values outside QC limits with an asterisk.
* Values outside of QC limits.
page 1 of 2
FORM VIII VOA
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FORM 8
VOLATILE INTERNAL STANDARD AREA AND RT SUMMARY
Lab Name: ECK.ENFELDER LLC Contract: FCX
Lab Code: NA Batch No.: NA SAS No.: NA SDG No.: FCX.V07050
Lab File ID (Standard): VlSTD0l
Instrument ID: VOAl
GC Column: DB-624
12 HOUR STD
UPPER LIMIT
LOWER LIMIT
CLIENT
SAMPLE NO.
01 VlBLK0723
02 EW-9
03 MP-13
04
ID: 0.53 (mm)
IS4 (DCB)
AREA # RT #
::=========
185665
371330
92833
::;:;::::::::;;::;;::;;::;;::;;::;;::;;::
248400
252468
249133
======::;
15.66
16.16
15.16
=::;;;:::;;::;:;;;::;::
15.66
15.66
15.66
05 -----------06 , ___ _
Date Analyzed: 07/23/00
Time Analyzed: 2037
Heated Purge: (Y/N) N
AREA # RT # AREA #
::;;:;;=::;;:::::::;;:::;;::
07 -----
08 ----
09 -----
RT #
=======
====::::::::;::;
====:::::::;:::;
----10 ------1-------------------_____ , ___ _
11 ------'-----12 ,_ ---
13 -----
14 ----
15 -----16 __; __
17 ------'-----18 ,. ---
19 -----
20 I---------
21 -------------------------------22 ______ , ______ , _________ , ____ --------
IS4 (DCB) = l,4-Dichlorobenzene-d4
AREA UPPER LIMIT= +100% of internal standard area
AREA LOWER LIMIT= -50% of internal standard area
RT UPPER LIMIT=+ 0.50 minutes of internal standard RT
RT LOWER LIMIT= -0.50 minutes of internal standard RT
# Column used to flag values outside QC limits with an asterisk. * Values outside of QC limits.
page 2 of 2
FORM VIII VOA
FORM 8
VOLATILE INTERNAL STANDARD AREA AND RT SUMMARY
Lab Name: ECKENFELDER LLC Contract: FCX
Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FCX.V07050
Lab File ID (Standard): V1CCV02
Instrument ID: VOAl
GC Column: DB-624 ID: 0.53
ISl(PFB)
(mm)
AREA # RT #
Date Analyzed: 07/24/00
Time Analyzed: 1034
Heated Purge: (Y/N) Y
IS2 (FLB) IS31CBZ)
AREA # RT # AREA #
==::;;:;;::;;;:=::::==== ----------======= ----------::;:;:;::;;::;;::;;::;;::;; ==::::::;:;:::;;::;;::;;::;;::;;
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
12 HOUR STD 416089 6.74
UPPER LIMIT 832178 7.24
LOWER LIMIT 208045 6.24
------------CLIENT
SAMPLE NO.
------------V1BLK0724
TRIP BLANK
MP-3
MP-7
MP-13
MP-3MS
MP-3MSD
ISl
IS2
IS3
(PFB)
(FLB)
(CEZ)
#
==----=::;;:::;;:;; =======
----------=======
335247 6.74
350886 6.73
344498 6.74
358164 6.74
340391 6.74
355449 6.74
355449 6.74
= Pentafluorobenzene
= Fluorobenzene
= Chlorobenzene-d5
211955 7.65
423910 8.15
105978 7.15
----------:;;:;;:;;::;::::;;::;;:;;
----------:::;;;:::::::::;;:::::::::;;
169915 7.64
178450 7.64
173164 7.64
182275 7.64
172170 7.64
186000 7.64
186000 7.64
AREA UPPER LIMIT= +100% of internal standard area
AREA LOWER LIMIT= -50% of internal standard area
606203
1212406
303102
----------
----------549187
556009
538803
561636
548826
572932
572932
RT UPPER LIMIT=+ 0.50 minutes of internal standard RT
RT LOWER LIMIT= -0.50 minutes of internal standard RT
RT #
:;;:;::;;;;;::;;:;;::;;::;;
12.11
12.61
11.61
=======
;;;:=:::::====
12.11
12.11
12.11
12.11
12.11
12.11
12.11
# Column used to flag values outside QC limits with an asterisk.
* Values outside of QC limits.
page 1 of 2
FORM VIII VOA
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FORM 8
VOLATILE INTERNAL STANDARD AREA AND RT SUMMARY
Lab Name: ECKENFELDER LLC Contract: FCX
Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FCX.V07050
Lab File ID (Standard): V1CCV02
Instrument ID: VOAl
Date Analyzed: 07/24/00
Time Analyzed: 1034
Heated Purge: (Y/N) Y GC Column: DB-624 ID: 0.53 (mm)
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
IS4(DCB)
AREA # RT # AREA # RT # ------------=====::;;==== ======= ----------======= 12 HOUR STD 258000 15.65
UPPER LIMIT 516000 16.15
LOWER LIMIT 129000 15.15
============ ::;;;;:;::;;::;;::;;::;;::;;::;;::;;::;; ::;;:;;:;::::::;;:;;:::::::;; ----------=======
CLIENT
SAMPLE NO.
------------:;;:;::::;;:::;;:;;:::;;::;;::;;::;;::;; ::;;::;;::;;::;;;:::::;;;;:: ----------:;;::::::::;;:::;;;;:::;;:;;:
V1BLK0724 241924 15.65
TRIP BLANK # 248765 15.65
MP-3 249158 15.65
MP-7 238288 15.66
MP-13 234890 15.66
MP-3MS 246758 15.66
MP-3MSD 246758 15.66
IS4 (DCB) = 1,4-Dichlorobenzene-d4
AREA UPPER LIMIT= +100% of internal standard area
AREA LOWER LIMIT= -50% of internal standard area
AREA #
----------
::;;::;;::;;::;;::;;::;;:::;;;;;;;;:;;:
----------
RT UPPER LIMIT=+ 0.50 minutes of internal standard RT
RT LOWER LIMIT= -0.50 minutes of internal standard RT
RT #
::;:;;:;;;::;;::;;::;;::;;
:::::======
:::::::;;::;::;;::;;;;;;:=
# Column used to flag values outside QC limits with an asterisk. * Values outside of QC limits.
page 2 of 2
FORM VI I I VOA
FORM 8
VOLATILE INTERNAL STANDARD AREA AND RT SUMMARY
Lab Name: ECKENFELDER LLC Contract: FCX
Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FCX.V07069
Lab File ID (Standard): V1CCV02
Instrument ID: VOAl
Date Analyzed: 07/24/00
Time Analyzed: 1034
Heated Purge: (Y/N) Y GC Column: DB-624 ID: 0.53 (mm)
. 01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
ISl(PFB)
AREA # RT # ------------::;::;;::;::;::;::;::;::;:;;;;;;: =======
12 HOUR STD 416089 6.74
UPPER LIMIT 832178 7.24
LOWER LIMIT 208045 6.24 ------------========== =======
CLIENT
SAMPLE NO.
============ ======::::=== :::;:::;:::;:::;:;::::;:::;:;;;
V1BLK0724 335247 6.74
TRIP BLANK # 356917 6.73
MP-5 336268 6.73
MP-2 363072 6.74
EW-10 331453 6.74
ISl
IS2
IS3
(PFB)
(FLB)
(CBZ)
= Pentafluorobenzene
= Fluorobenzene
= Chlorobenzene-d5
IS2(FLB)
AREA # RT #
::::::;:;;:;:;:::;;;;;;:::;;:;:;;;;;; =======
211955 7.65
423910 8.15
105978 7.15
----------:;;;:;::;:;;::;;;:::;::;::;
----------=======
169915 7.64
179035 7.64
170020 7.64
187775 7.64
175345 7.65
AREA UPPER LIMIT= +100% of internal standard area
AREA LOWER LIMIT= -50% of internal standard area
IS3(CBZ)
AREA #
:;:;:;::;:;::::;::;::;::;:::;:;:;::;::
606203
1212406
303102
==========
::::;:;::::;:::;:::;:::;:::;:::;:::;:::;
549187
558533
552677
576623
557402
RT UPPER LIMIT=+ 0.50 minutes of internal standard RT
RT LOWER LIMIT= -0.50 minutes of internal standard RT
RT #
=====:::;=
12.11
12.61
11.61
:::;:;::;:::;::::::;::::;:::;
======;;:=
12.11
12.11
12.11
12.11
12.10
# Column used to flag values outside QC limits with an asterisk. * Values outside of QC limits.
page 1 of 2
FORM VI I I VOA
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FORM 8
VOLATILE INTERNAL STANDARD AREA AND RT SUMMARY
Lab Name: ECKENFELDER LLC Contract: FCX
Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FCX.V07069
Lab File ID (Standard): V1CCV02
Instrument ID: VOAl
Date Analyzed: 07/24/00
Time Analyzed: 1034
Heated Purge: (Y/N) Y GC Column: DB-624 ID: 0.53 (mm)
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
IS4(DCB)
AREA # RT # AREA # RT # ============ ========== ======-----------=======
12 HOUR STD 258000 15.65
UPPER LIMIT 516000 16.15
LOWER LIMIT 129000 15.15
::;:::;::::;::;::;::::;;;:;::::;:::;:::;:::;:::;: ::;:::;:::;:::;:::;::;:::::;::::;:::;:::;: ::;:::;:::;:::;:::;:::;::;; ----------=======
CLIENT
SAMPLE NO.
::;:::;:::;:::;:::;:::;:;;;;::;;::;;:::;:::;:::;: ::;:::;:::;:::;:::;:;::;:;::::;:::;:::;: ======= ----------======= V1BLK0724 241924 15.65
TRIP BLANK # 239325 15.66
MP-5 234641 15.66
MP-2 243708 15.66
EW-10 240689 15.65
IS4 (DCB) = 1,4-Dichlorobenzene-d4
AREA UPPER LIMIT= +100% of internal standard area
AREA LOWER LIMIT= -50% of internal standard area
AREA #
::;:::;:::;;::;::;:::;:::;:::;:::;:::;:
::;:::;:::;:::;::;;::;:::::;::;::::;:::;:
::;:::;:::;:::;::;::;;::;::::;:::;:::;:
RT UPPER LIMIT=+ 0.50 minutes of internal standard RT
RT LOWER LIMIT= -0.50 minutes of internal standard RT
RT #
::;:;::;;;::;:::;:::;:::;:
=======
====::::==
# Column used to flag values outside QC limits with an asterisk. * Values outside of QC limits.
page 2 of 2
FORM VI I I VOA
FORM 8
VOLATILE INTERNAL STANDARD AREA AND RT SUMMARY I
Lab Name: ECKENFELDER LLC Contract: FCX <500781
Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FCX.V07108
Lab File ID (Standard): VlCLP50
Instrument ID: VOAl
Date Analyzed: 07/28/00
Time Analyzed: 0727
Heated Purge: (Y/N) N GC Column: DB-624 ID: 0.53 (mm)
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
I
ISl(PFB)
AREA # RT #
:;;:::;;:::=======;:;;= ========:::= ======= 12 HOUR STD 411603 6.74
UPPER LIMIT 823206 7.24
LOWER LIMIT 205802 6.24
=======::::::;;::;:;:::;;:::;;: ========== =======
CLIENT
SAMPLE NO.
=====:;:::::::::;:::::::::;;:::;;: =====::::==== ::;;:::;;:::;;:::;;::;;;:::;;:::;;
VlBLK0728 391739 6.74
MP-12 403503 6.74
MP-4 402510 6.75
EW-16 382914 6.74
MP-11 376504 6.74
MP-11, DUPE 401002 6.74
MP-1 391824 6.74
MP-6 388978 6.74
STORAGE BLAN 381155 6.75
..
ISl (PFB)
182 (FLB)
183 (CBZ)
; Pentafluorobenzene
; Fluorobenzene
; Chlorobenzene-d5
182 (FLB)
AREA # RT #
----------=======
213605 7.65
427210 8.15
106803 7.15
----------::;:;;:;;;::::;;::;;:::;;:::;;:
----------=======
204255 7.65
205862 7.65
205860 7.65
191277 7.66
197160 7.65
197327 7.65
196642 7.64
190483 7.65
192457 7.65
AREA UPPER LIMIT; +100% of internal standard area
AREA LOWER LIMIT; -50% of internal standard area
IS3(CBZ)
AREA #
==========;;;
514059
1028118
257030
::;;:::;;:::;;:::;;:::;;:::;:::;:::;;::::::;;:
::;;:::;;:::;;:::;;:::;;:::;:::;::;:::;;::;:
501018
504812
504733
488986
483385
500745
487933
494209
475184
RT UPPER LIMIT;+ 0.50 minutes of internal standard.RT
RT LOWER LIMIT; -0.50 minutes of internal standard RT
RT #
=======
12.11
12.61
11.61
=======
=======
12.12
12.12
12.12
12.12
12.12
12.12
12.12
12.12
12.11
# Column used to flag values outside QC limits with an asterisk. * Values outside of QC limits.
page 1 of 2
FORM VI I I VOA
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FORM 8
VOLATILE INTERNAL STANDARD AREA AND RT SUMMARY
Lab Name: ECKENFELDER LLC Contract: FCX
Lab Code: NA Batch No. : NA SAS No.: NA SDG No.: FCX.V07108
Lab File ID (Standard): VlCLP50
Instrument ID: VOAl
Date Analyzed: 07/28/00
Time Analyzed: 0727
Heated Purge: (Y/N) N GC Column: DB-624 ID: 0.53 (mm)
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
IS4(DCB)
AREA # RT # AREA # RT # ----------------------======= ----------=======
12 HOUR STD 216942 15.66
UPPER LIMIT 433884 16.16
LOWER LIMIT 108471 15.16
----------------------======= ----------======= CLIENT
SAMPLE NO.
===========:::: ========== ======= =======:::;:::::::; ;;:::;:::::::::::::::::::::
V1BLK0728 213664 15.66
MP-12 213260 15.66
MP-4 211001 15.66
EW-16 194025 15.66
MP-11 208430 15.66
MP-11, DUPE 208556 15.66
MP-1 204911 15.66
MP-6 197380 15.66
STORAGE BLAN 201278 15.67
IS4 (DCB) = l,4-Dichlorobenzene-d4
AREA UPPER LIMIT= +100% of internal standard area
AREA LOWER LIMIT= -50% of internal standard area
AREA #
;;;::;:;;:::;::::;::::;::::;::::;:::;;;;::
:;;;:;;;:::;;::;;::::;::::;::::;::::;::::;:
==========
RT UPPER LIMIT=+ 0.50 minutes of internal standard RT
RT LOWER LIMIT= -0.50 minutes of internal standard RT
RT #
=========
========
=======
# Column used to flag values outside QC limits with an asterisk. * Values outside of QC limits.
page 2 of 2
FORM VI I I VOA
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APPENDIXB
SOIL VOCANALYTICALLABORATORYREPORTS
\ \BCNSH03\PROJECTS\PROJ\. 18895\ 18895.015'\APPcvr.doc
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Client: FCX #18895.006
Date Reported: 06/16/00
~--~ ~
Eckenfelder
Laboratory, LLC
I ECKENFELDER SAMPLE NUMBER I VlMBLK0530 I 0005109-01 I 0005109-02"' I 0005109-03 I 0005109-04 [
1----------------------------------------------1-----------1-----------1-----------1-----------1-----------1
I DATE SAMPLED I NA I 05/1B/OO I 05/1B/OO I 05/1B/OO I 05/1B/OO I
__ I DATE RECEIVED I NA I 05/19/00 I 05/19/00 I 05/19/00 I 05/19/00 I
! DATE ANALYZED [ 05/30/00 I 05/30/00 j 05/30/00 [ 05/30/00 [ 05/30/00 !
1----------------------------------------------1-----------1-----------1-----------1-----------1-----------1
I I M.BLANK IEW-2 s fe. IEW-2 39 fe. lEW-2 51 fe.1 sw-1 I
I CLIENT SAMPLE DESCRIPTION I I I I I 11. s fe. I
I I I I I I I
1----------------------------------------------1-----------1-----------1-----------1-----------1-----------1
I VOLATILE ORGANICS I I I I I I I 1-
1 BY USEPA METHOD 8260 I MDL I EQL I CONC I CONC I CONC I CONC I CONC I
1----------------------------------------------1-----------1-----------1-----------1-----------1-----------1
l Acetone I 0.25 I 2.5 I< 0.25 I< 0.30 J< 0.34 I< 0.30 I< 0.39 !
! Benzene I o.oso 1 a.so I< o.oso I< o.oso l< 0.069 I< o.060 \< 0.077 ]
I Bromodichloromethane I o.oso I a.so I< o.oso !< o.060 I< 0.069 [< 0.060 I< 0.077 I
l Bromofo:rm I o.oso I a.so I<, o.oso I< 0.060 I< 0.069 ]< 0.060 I< 0.077 I
I Brornomethane I 0.10 I 1.0 I< 0.10 ]-< 0.12 I< 0.14 1< 0.12 I< 0.15 I
I 2-sutanone I a.so I s.o I< a.so I< a.so I< o.69 1< a.so I< o.77 I
I Carbon disulfide j o.oso I a.so 1< o.oso I< 0.060 I< 0.069 I< 0.060 I< 0.077 I
[ carbon tetrachloride ] 0.050 I 0.50 I< 0.050 I< 0.060 I< 0.069 I< 0.060 I< 0.077 I
I Chlorobenzene 0.050 I a.so I< o.oso I< 0.060 !< 0.069 I< 0.060 [< 0.077 l
j Chloroethane 0.10 l l.O I< 0.10 I< 0.12· J< 0.14 I< 0.12 !< 0.15 I
I Chlorof.i:::irm o.oso I a.so !< o.oso I< 0.060 I< 0.069 /< 0.060 I< 0.077 I
I Chloromethane 0.10 I l.O I< 0.10 I< 0.12 I< 0.14 I< 0.12 I< 0.15 I
I Dibromcchlorornethane o.oso I a.so I< 0.050 I< 0.060 I< 0.069 I< 0.060 I< 0.077 I
! 1,2-Dichlorobenzene o.oso ! a.so I< 0.050 I< 0.060 I< 0.069 I< 0.060 I< 0.077 I
I 1,3-Dichlorobenzene 0.050 1 a.so I< 0.050 I< 0.060 !< 0.069 I< 0.060 !< 0.077 I
I 1,4-Dichlorobenzene 0.050 I a.so I< 0.050 I< 0.060 !< 0.069 [< 0.060 !< 0.077 ]
I Dichlorodifluorcmtethanc 0.10 I 1.0 I< 0.10 I< 0.12 !< 0.14 I< 0.12 !< 0.15 I
I 1,1-Dichloroothane 0.050 I 0.50 I< 0.050 I< 0.060 l<.0,069 !< 0.060 I< 0.077 I
I 1,2-Dichloroethane o.oso I a.so I< 0.050 I< 0.060 I< 0.0159 ]< 0.060 I< 0.077 I
[ 1,1-Dichloroethene o.oso I a.so ]< o.oso [< 0.060 I< o.069 I< 0.060 I< 0.077 I
l cis-1,2-Dichloroethene o.oso I a.so I< 0.050 I< 0.060 [< 0.069 I< 0.060 I< 0.077 I
] trana-1,2-Dichloroethene 0.050] a.so I< o.oso . ]< 0.060 I< 0.069 I< 0.060 !< 0.077 ]
1 _____________________________ 1
ALL COMPOUNDS EXPRESSED IN MILLIGRAMS/KILOGRAM DRY UNLESS qtHERWISE NOTED,
ALL NON-DETECT VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLECT DILtJI'IONS/DRY WEIGHT/SAMPLE WEIGHT}.
SEE ATTACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
• • SOME ASPECT OF QUALITY CONTROL WAS NOT WITHIN LIMITS,
RESULTS SHOULD BE CONSIDERED AS ESrIMATED.
227 French Landing Drive Nashville, Tennessee 37228 615-345-1115 FAX [phone]
Eckenfelder Laboratory, LLC
Client: FCX #18895.006
Date Reported: 06/16/00
I ECKENFELDER SAMPLE NUMBER IVlMBLKOSJO 1ooos109-01 1aaos109-02•1ooos109-03 1ooos109-04 I
l-c--------------------------------------------1-----------I-----------I-----------I-----------I-----------I
I DATE SAMPLED I NA I 05/18/00 I 05/18/00 I 05/18/00 I 05/1B/OO I
•· I DATE RECEIVED I NA I 05/19/00 I 05/19/00 I 05/19/00 I 05/19/00 I
I DATE ANALYZED I 05/30/00 I 05/30/00 I 05/30/00 I 05/30/00 I 05/30/00 I
1----------------------------------------------1-----------1-----------1-----------1-----------1-----------1
I I M.8LANK IEW-25ft.lEW-239ft.lEW-25lft.l SW-l I
I CLIENT SAMPLE DESCRIPrION I I I I I ll.5 ft. I
I I I I I I I
1----------------------------------------------1-----------1-----------1-----------1-----------1-----------1
I VOLATILE ORGANICS I I I I I I I I
I BY USEPA METHOD 8260 I MDL I EQL I OONC I OONC I OONC I CONC I CONC I
l-------------------------------------------0 --I-----------I-----------I-----------I-----------I-----------I
I 1,2-Dichloropropane I o.oso I a.so ]< o.oso 1< o.OISO !< 0.069 I< 0.060 [< a.on I
I cia-1,3-Dichloropropene j 0.050 I a.so I< 0.050 ]< 0.060 I< 0.069 I< 0-,060 I< 0.077 I
[ trans-1,3-0ichloropropene J 0.050 I a.so I< o.oso I< 0.060 I< o.069 I< 0.060 J< 0.077 I
I Ethylbenzene I o.oso I a.so l<·o.oso I< 0.060 I< 0.069 [< 0.060 !< 0.077 I
I 2-Hexanone I 0.10 I 1.0 I< 0.10 I< 0.12 I< 0.14 I< 0.12 !< 0.15 I
I Methylene chloride I 0.050 I a.so I< o.oso I< 0.060 I< 0.069 I< 0.060 I< 0.077 I
I 4-Methyl-2-pentanone I 0.10 j l.O I< 0.10 I< 0.12 I< 0.14 I< 0.12 I< 0.15 I
I Styrene [ 0.050 I 0.50 [< 0.050 I< 0.060 l<-0.069 I< 0.060 J< 0.077 I
I· 1,1,2,2-Tetrachloroethane I 0.050 1 o.50 I< 0.050 I< 0.060 I< 0.069 l< 0.060 I< 0.077 I
I Tetrachloroethene I o.oso I 0.50 l< 0.050 I 0.20 JI 2.1 I 12 I 0.24 JI
I Toluene I 0.050 I 0.50 I< 0.050 I< 0.060 I< 0.069 I< 0.060 I< 0.077 I
! 1,1,1-Trichloroethane I o.oso I a.so I< 0.050 [< 0.060· I< 0.069 I< 0.060 I< 0.077 [
I 1,1,2-Trichloroethane I 0.050 I 0:50 I< 0.050 I< 0.060 I< 0.069 I< 0.060 I< 0.077 j
I Trichloroethene I 0.050 I 0.50 I< 0.050 I< 0.060 I< 0.069 I< 0.060 I< 0.077 ]
I Trichlorofluoromethane I 0.10 I 1.0 !< 0.10 I< 0.12 [< 0.14 I< 0.12 I< 0.15 ]
I Vinyl acetate I 0.25 I 2,5 I< 0.25 I< 0:30 [< 0.34 I~ 0.30 I< Q.39 l
I Vinyl chloride I 0.10 I-1.0 ]< 0.10 I< 0.12 I< 0.14 I< 0.12 !< 0.15 I
I Xylene(total) I o.oso I a.so I 0.13 Jj 0.099 JB\ o.093 JB[ o.079 JB\< 0.077 I I _____________________________ I
ALL COMPOUNDS EXPRESSED IN MILLIGRAMS/KILOGRAM DRY UNLESS OTHERWISE NOTED.
ALL. NON-DETECT VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLECT DILU!IONS/DRY WEIGHT/SAMPLE WEIGHT).
SEE ATTACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS. ·
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Eckenfelder Laboratory, LLC
Client: FCX #18895.006
Date Reported: 06/16/00
l ECKENFELDER SAMPLE NUMBER )ooos109-os Jooos113-01 1ooos11J-02•iooos121-01•looos121-02 I
1----------------------------------------------1-----------1-----------1-----------1-----------1-----------1 I DATE SAMPLED I 05/18/00 I 05/19/00 I 05/19/00 I 05/22/00 I 05/22/00 I
•. I DATE RECEIVED I 05/19/00 I 05/20/00 I 05/20/00 I 05/23/00 I 05/23/00 I
I DATE ANALYZED I 05/30/00 I 05/30/00 I 05/30/00 I 05/30/00 I 05/31/00 I
1----------------------------------------------1-----------1-----------1-----------1------·----1-----------1 I lsw-1 30 ft -I EW-6 35ft I EW-6 59ft I EW-4 •2ft I EW-4 56ft I
I CLIENT SAMPLE DESCRIPTION I I I I I I
I I I I I I I
1----------------------------------------------1-----------1-----------1---------·-1-~--------1-----------1 I VOLATILE ORGANICS I I I I I I I I
j BY USEPA ME'IliOD 8250 I MDL I EQL [ CONC I CONC I CONC I CONC j CONC I
1----------------------------------------------1-----------1-----------1-----------1-----------1-----------1
I Acetone 0.25 I 2.5 I< 0.56 I< 0.33 I< 0.2B I< 0.28 I< 0,32 I
I Benzene 0.050 \ a.so I< 0.11 I< 0.066 !< 0.056 I< 0.057 I< 0.064 !
I Bromodichloromethane o.oso I a.so I< 0.11 I< 0.066 I< 0.056 I< 0.057 I< 0.064 1
I Bromcform. o.oso I a.so I<· 0.11 I< 0.066 I< 0.056 I< 0.057 /< 0.054 I
I Bromomethane 0.10 I LO [< 0.22 !< 0.13 I< 0.11 I< 0.11 l< o._13 I
I 2-Butanone a.so I s.o !< 1.1 1< 0.66 I< o.56 ]< 0.57 I< 0.64 I
·1 Carbon disulfide o.oso [ a.so I< 0.11 I< 0.066 I< o.055 I< 0.057 I< 0.054 I
I Carbon tetrachloride o.oso ! a.so I< 0.11 I< 0.066 \< 0.056 I< 0.057 I< 0.064 I
I Chlorobenzene o.oso I o.50 I< 0.11 [< 0.066 I< 0.056 [< 0.057 I< 0.064 1
I Chloroethane 0.10 I 1.0 !< 0.22 I< 0.13 I< 0.11 I< 0.11 1< 0.13 I
I Chlorof.orm o.oso I a.so 1< 0.11 I< o.066 I< 0.056 l< 0.057 I< 0.064 I
I Chloromethane 0.10 I 1.0 J< 0.22 I< 0.13 I< 0.11 I< 0.11 I< 0.13 I
I Dibromochloromethane 0.050 ! a.so I< 0.11 I< o.066 [< 0.056 I< 0.057 I< 0.064 I
I 1,2-Dichlorobenzene 0.050 j a.so I< 0.11 I< 0.066 !< 0.056 I·< 0.057 I< 0.064 I
! 1,3-Dichlorobenzene 0.050] a.so I< 0.11 I< 0.066 I< 0.056 I< 0.057 I< 0.064 I
! 1,4-Dichloroberizene o.oso.f o.so I< 0.11 (< 0.066 I< 0.056 I< 0.057 I< 0.064 I
I Dichlorodifluoromethane 0.10 I l.O I< 0.22 I< 0.13 I< 0.11 !< 0.11 \< 0.13 I
I 1,1-Dichloroethane o.oso I a.so I< 0.11 I< 0.066 I< 0.056 1< 0.057 ]< 0.064 I
I 1,2-Dichloroethane o.oso I a.so I< 0.11 I< 0.066 I< 0.056 I< 0.057 I< o.064 I
I 1,1-Dichloroethene o.oso ! o.50 I< 0.11 I< 0.066 !< 0.056 I< 0.057 I< 0.064 l
I cie-1,2-Dichloroethene 0.050 j 0.50 I< 0.11 l<,0,066 ]< 0.056 I 0.10 J(< 0.064 I
I trans-1,2-Dicliloroethene o.oso I a.so I< 0.11 I< 0.066 I< 0.056 j< 0.057 I< 0.064 I
1 _____________________________ 1
ALL COMPOUNDS EXPRESSED IN MILLIGRAMS/KILOGRAM DRY UNLESS OTHERWISE NOTED.
ALL NON-DETECT VALUES ARE REPORTED AS <MDL {MODIFIED TO REFLEqI DILUTIONS/DRY WEIGHT/SAMPLE WEIGHT}.
SEE ATTACHED PAGE FOR DEFINITIONS OF TE~ AND QUALIFIERS.
• .. SOME ASPECT OF QUALITY CONTROL WAS NOT WITHIN LIMITS,
RESULTS SHOULD BE CONSIDERED AS ESTIMATED.
Eckenfelder Laboratory, LLC
Client: FCX #18895.006
Date Reported: 06/16/00
J ECKENFELDER SAMPLE NUMBER 1oaos109-os 1ooos113-01 jooos1iJ-02•1ooos121-01•1ooos121-02 I
1----------------------------------------------1-----------1-----------1-----------1-----------1-----------1
I DATE SAMPLED I 05/18/00 I 05/19/00 I 05/19/00 I 05/22/00 I 05/22/00 I
•· I DATE RECEIVED I 05/19/00 I 05/20/00 I 05/20/00 I 05/23/00 I 05/23/00 I
I DATE ANALYZED I 05/30/00 I 05/30/00 I 05/30/00 I 05/30/00 I 05/31/00 I
1----------------------------------------------1-----------1-----------1-----------1-----------1-----------1
I ISW-1 38 ft.f EW-6 35ft 1· EW-6 59ft I EW-4 42ft I EW-4 56ft I
I CLIENT SAMPLE DESCRIPTION I I I I I I
I I I I I I I
1----------------------------------------------1-----------1-----------1-----------1----------1-----------1
I VOLATILE ORGANICS I I I I I I I I
I BY USEPA METHOD 8260 I MDL -1 EQL I CONC I CONC I CONC I CONC I CONC I
1----------------------------------------------1-----------1-----------1-----------1-----------1-----------1 I 1,2-Dichloropropane I o.oso ] a.so I< 0.11 I< o.066 1< 0.056 I< 0.057 I< o.064 I
I cia-1,3-Dichloropropene I o.oso j 0.50 !< O.ll I< 0.066 /< 0.056 ]< 0.057 I< 0.064 I
1 · trana-1,3-Dichloropropene I o.oso I a.so !<,0.ll I< 0.066 .(< 0.056 !< 0.057 I< 0.064 ·1
I Ethylbenzene [ o.oso I a.so l<'· 0.11 I< 0.066 I< a.ass l< o.OS7 1< o.064 !
I 2-Hexanone I 0.10 I l.O !< 0.22 I< 0:13 I< 0.11 I< O.ll I< 0.13 j
I Methylene chloride I o.oso I a.so I< 0.11 I< 0.066 I< 0.056 1< 0.057 I 0.10 JI
[ 4-Methyl-2-pantanone ! 0.10 I 1.0 I< 0.22 I< 0,13 !< O.ll I< 0.11 I< 0.13 I
I Styrene ! o.oso I a.so I< 0.11 I< 0.066 I< a.ass I< 0.057 I< o.064 I
I 1,1,2,2-Tatrachlorcathano 1 0.050 I a.so I< 0.11 .!< 0.066 I< 0.056 I< 0.057 I< 0.064 I
I Tetrachlcroethene I 0.050 I a.so I< 0.11 ] 0.25 JI< 0.056 [ 0.65 I< 0.064 I
I Toluene I o.oso I a.so I< 0.11 I< 0.066 I< 0.056 I< 0.057 I< 0.064 I
[ 1,1,1-Trichloroethane I 0.050 I a.so I< 0.11 I< 0.066 I< 0,056 [< 0.057 [< 0,064 I
I 1,1,2-Trichloroothane j 0.050 I a.so I< 0.11 I< 0.066 I< 0.056 I< 0.057 !< 0.064 I
[ Trichloroethcne I 0.050] 0.50 I< 0.11 I< 0.066 I< 0.056 I< 0.057 !< 0.064 I
I Trichlorofluoromethane I 0.10 I 1.0 [< 0.22 I< 0.13 I< 0.11 I< 0.11 I< 0.13 I
1 Vinyl acetate I 0.25 I 2.5 I~ 0.56 I< 0.33 l<_0.28 I< 0.20 !< 0.32 I
I Vinyl chloride [ 0.10 I 1.0 l< 0.22 I< 0.13 I< 0.11 I< 0,11 I< 0.13 !
.1 Xylene(total) I o.oso I a.so ]< 0.11 [< 0.0615 I< o.oss I< 0.057 I< 0.064 I
1---------------------------~-I ALL COMPOUNDS EXPRESSED IN MILLIGRAMS/KILOGRAM DRY UNLESS OTHERWISE NOTED.
ALL NON-DETECT VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLECT DILUTIONS/DRY WEIGHT/SAMPLE WEIGHT).
SEE ATTAOIED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
• • SOME ASPECT OF QUALITY CONTROL WAS NOT WITHIN LIMITS,
RESULTS SHOULD BE CONSIDERED AS ESI'IMATED.
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Eckenfelder Laboratory, LLC
Client: FCX #18895.006
Date Reported: 06/16/00
I ECKENFELDER SAMPLE NUMBER I 0005121-04* (
1----------------------------------------------1-----------1
I DATE SAMPLED I 05/22/00 I
I DATE RECEIVED I 05/23/00 I
I DATE ANALYZED I 05/31/00 I
1----------------------------------------------I-----------I
I IMP-10 19ft I
I CLIENT SAMPLE DESCRIPTION I I
I I I
1---------------------------------------------1-----------I
I VOLATILE ORGANICS I I I I
I BY USEPA METHOD B260 I MDL I EQL I CONC I
1----------------------------------------------1-----------1
J Acetone I 0.25 l 2.5 I< 0.38 I
J Benzene [ O. oso I O. SO I< O. 076 I
I Bromcdichloromathane I O. 050 I O. 50 I< O. 076 [
I Bromoform I o.oso I a.so l<-_0.076 I
I Bromomethane ! 0.10 I 1.0 I< 0.15 I
.1 2-Butanone I a.so I s.o !< o.76 J
I Carbon disulfide I o.oso I a.so I< 0.076 I
I carbon tetrachloride I o. oso I o. so ] < a. 076 I
I Chlorobanzene I 0.050 l a.so I< _0.076 [
] Chloroethane I 0.10. I 1.0 [< 0.15 I
I Chlorof.orm I o.oso I a.so I< 0.076 I
I Chloromethane l 0.10 I 1.0 !< 0.15 j
I Dibromochloromethane I o.050 I a.so I< 0.076 I
! 1, 2-Dichlorobenzene I o. oso I O. SO I< a. 076 I
j 1, 3-Dichlorobenzene I o. oso I o. SO ] < O. 076 I
I 1,4-Dichlorobenzene · 1 o.oso I a.so I< 0.076 I
I Dichlorodifluorom.ethane [ 0.10 I 1.0 I< 0.15 I
I l,l-Dichloroothane l 0.050 I 0.50 I< 0.076 I
\ 1,2-Dichloroathana I o.oso I a.so I< 0.076' ·1
I l,l-Dichloroethene I o.oso I a.so I< 0.076 I
I cis-1_,2-Dichloroethene I 0.050 I ·a.so I< 0.076 I
I trana-1,2-Dichloroethone I o.oso I a.so I< o.076 I
1 ________________ 1
ALL COMPOUNDS EXPRESSED IN MILLIGRAMS/KILCGRAM DRY UNLESS OTHERWISE NOTED.
ALL NON-DETECT VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLECT DILtrrIONS/DRY WEIGHT/SAMPLE WEIGHT) .
SEE ATTACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
• .. SOME ASPECT OF QUALITY CONTROL WAS NOT WITHIN LIMITS,
RESULTS SHOULD BE OJNSIDERED AS EsrIMATED.
Eckenfelder Laboratory, LLC
Client: FCX #18895.006
Date Reported: 06/16/00
I ECKENFELDER SAMPLE NUMBER I 0005121-04" I
I ------' ---------------------------------------1-----------1
I DATE SAMPLED I 05/22/00 I
•· I DATE RECEIVED I 05/23/00 I
I DATE ANALYZED I 05/31/00 I
l----------------------------------------------1-----------I I MP-10 19ft I
I CLIENT SAMPLE DESCRIPTION I
: .. · ____ · ·. ___ . ----.. -----------.. -------------------:
I VOLATILE ORGANICS I I I
j BY USEPA MErnOD 8260 I MDL [ EQL CONC I
1-----------------------------------------------------·--1
I 1,2-q1chloropropane I o.oso I a.so < 0.076 ]
I cis-1,3-Dichloropropene I 0.050 [ a.so < 0.076 I
I trane-1,3-Dichloropropene ! o.oso I a.so, < 0.076 I
I Ethylbenzene j O. 050 I O. 50 <'·. O. 076 I
I 2-He.x.anone l 0.10 I 1.0 < 0.15 I
I Methylene chloride 1 O. 050 I O. SO O .10 JI
I 4-Methyl-2-pentanone 0.10 j 1.0 < 0.15 I
I Styrene o.oso I a.so < 0.076 I
I 1,1,2,2-Tetrachloroethane 0.050] a.so < 0.076 I
I Tetrachloroethene o.oso] 0.50 I< 0.076 [
l Toluene o.oso I a.so I< o.076 I
J 1,1,l-Trichloroethane o.oso I a.so I< 0.076 I
I 1,1,2-Trichloroethane o.oso J a.so I< o.□76 I
! Trichloraathena 0.050 j a.so I< 0.076 I
I Trichlorofluoromathane 0.10 I l.O I< 0.15 I
j Vinyl acetate 0.25 I 2.5 \< 0.38 I
I Vinyl chloride 0.10 I l.O l< 0.15 I
I Xylene (total) O. 050 [ O. 50 I< O. 076 l
1 ________________ 1
ALL COMPOUNDS EXPRESSED IN MILLIGRAMS/KILOGRAM DRY UNLESS OTHERWISE NOTED.
ALL NON-DETECT VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLECT DILUTIONS/DRY WEIGlIT/SAMPLE WEIGHT).
SEE AT'.I'AClIED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
• .• SOME ASPECT OF QUALITY CONTROL WAS NOT WITHIN LIMITS,
RESULTS SHOULD BE CONSIDERED AS ESTIMATED.
Eckenfelder Laboratory, LLC
1)~
· D. Rick Davis
Vice President
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ANALYTICAL REPORT TERMS AND QUALIFIERS (GC/MS)
MDL: The method detection limit (MDL) is defined as the minimum
concentration of a substance that can be measured and reported with
99% confidence that the analyte concentration is greater than zero. The
MDL is determined from analysis of a sample containing the analyte in a
given matrix.
EQL: The estimated quantitation limit (EQL) is defined as the estimated
concentration above which quantitative results can be obtained with a
. specific degree of confidence. Eckenfelder Laboratory, LLC. defines the
EQL to be ten times the MDL.
B: The presence of a "B" to the right of an analytical value indicates that
this compound was also detected in the method blank and the data
should be interpreted with caution. One should consider the possibility
that the correct sample result might be less than the reported result and,
perhaps, zero.
D: When a sample (or sample extract) is rerun diluted because one of the
compound concentrations exceeded the highest concentration range for
the standard curve, all of the values obtained in the dilution run will be
flagged with a "D".
E: The'concentration for any compound found which exceeds the highest
concentration level on the standard curve for that compound will be
flagged with an "E". Usually the sample will be rerun at a dilution to
quantitate the flagged compound. ·
J: The presence of a "J" to the right of an analytical result indicates that the
reported result is estimated. The mass spectral data pass the
identification criteria showing that the compound is present, . but the
calculated result is less than the EQL. One should feel confident that
the result is greater than zero and less than the EQL.
L:\JIBPORTS\ART&QLT.DOC
~, ~rlY:-~p-l1l~°JI
SOIL vou:{tiLE SYS~
0
:NiTORING COMPOUNiJ'RECOVERY
Lab Name: ECKENFELDER LLC Contract: FCX
Lab Code: NA Batch No.: SAS No.: NA SDG No.: FCX.V05109
Level: (low/med) MED
SMCl (DFM)
SMC2 (DCE)
SMC3 (TOL)
SMC4 (BFB)
01
02
03
04
05
06
. 07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
'122
23
24
25
26
27
28
29
30
LAB
SAMPLE NO.
=----======= EW-2 5 FT.
EW-2 39 FT.
EW-2 51 FT.
SW-1 11.5 FT
SW-1 38 FT.
EW-6 35FT
E'w-.6 59FT
EW-4 42FT
EW-4 56FT
MP-10 19FT
SMCl SMC2 SMC3
(DFM) # (DCE) # (TOL) #
====== ====== ====== 91 108 104
88 104 101
100 110 97
90 109 99
90 107 · 99
90 104 96
84 102 94
86 100 94
86 99 92
84 101 90
ECK.
QC LIMITS
= Dibrornofluoromethane (80-120)
= l,2-Dichloroethane-d4 (80-120)
= Toluene-dB (82-117)
= Bromofluorobenzene (89-118)
SMC4 TOT
(BFB) # OUT
====== ===
76* 0
72*@ 1
83* 0
78* 0
77* 0
76* 0
·.70*@ 1
66*@ 1
77* 0
67*@ 1
---
------
-----------
8260A
QC LIMITS
(80-120)
(80-120)
(81-117)
(74-121)
# Column to be used to flag recovery values
* Values outside of Eckenfelder QC limits
@ Values outside of 8260A required QC limits
-D System Monitoring Compound diluted out
page 1 of 1 FORM II VOA
SPIKE
CONC (mg/Kg)
3.0
3.0
3.0
3.0
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.) FORM 3 ... SOIL VOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY
Lab Name: ECKENFELDER LLC Contract: FCX
Lab Code: NA
Matrix Spike
Batch No.: SAS No.: NA
Client Sample No.: MP-10 19ft
SDG No.: FCX.V05109
Lab Sample ID: 0005121-04 I Level: (low/med) MED
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SPIKE SAMPLE MS MS QC. ADDED CONCENTRATION CONCENTRATION % LIMITS COMPOUND (mg/Kg) . (mg/Kg) (mg/Kg) REC # REC. ==================----== =======--============= -----======== ====== ====== Benzene 2.500 0.0000 1.771 71 66-142 Chlorobenzene 2.500 0.0000 1.753 70 60-133 1,1-Dichloroethene 2.500 0.0000 1.621 65 59-172 Toluene 2.500 0.0000 1.727 69 59-139 Trichloroethene 2.500 0.0000 1. 744 70 62-137
SPIKE MSD MSD
ADDED CONCENTRATION % % QC LIMITS COMPOUND • (mg/Kg) (mg/Kg) REC # RPD # RPD ======================== ========= ============= ====== ====== ====== Benzene 2.500 1. 731 69 3 21 Chlorobenzene 2.500 1.801 72 3 21
1,1-Dichloroethene 2.500 1.649 66 2 22 Toluene 2.500 1. 752 70 1 21 Trichloroethene 2.500 1.714 68 3 24
# Column to be used to flag recovery and RPD values with an asterisk
* Values outside of QC limits
RPD: 0 out of 5 outside limits
Spike Recovery: 0 out of 10 outside limits
COMMENTS:
FORM III VOA
REC.
====== 66-142
60-133
59-172
59-139
62-137
Eckenfelder
Laboratory, LLC
Client: FCX -El Paso #18895.006
Date Reported: 06/08/00
I ECKENFELDER SAMPLE NUMBER [ VlBLK0531 [ 0005109-06 j
l----------------------------------------------1-----------I-----------I I DATE SAMPLED I NA I 05/18/00 I ·
.. I DATE RECEIVED I NA I 05/19/00 I
I DATE ANALYZED I 05/31/00 I 05/31/00 I
1----------------------------------------------1-----------1-----------1 I I M.BLANK I Trip Blank!
I CLIENT SAMPLE DESCRIPTION 1 ! #1589 I
I I I I
1----------------------------------------------I-----------I-----------I I VOLATILE ORGJWICS I I I I I
I . BY USEPA METHOD 8260 I MDL I EQL I CONC. I CONC I
1----------------------------------------------I-----------I-----------I
[ Acetone I 5.0 I SO I< 5.0 I< s.o I
[ Benzene I l.O I 10 I< 1.0 I< 1.0 I
I Bromod.ichloromethane ] . 1. O I 10 ! < 1. O I< 1. O I
I Bromoform I 1.0 I 10 j<. l.O [< 1.0 I
I Bromomethane I 2.0 ! 20 I< 2.0 I< 2.0 I
I 2-Butanone [ 10 J 100 j < 10 I< 10 I
I Carbon disulfide I 1.0 I 10 I< 1.0 1< 1.0 I
1 carbon tetrachloride I 1.0 I 10 I< 1.0 I< 1.0 l
] Chlorobenzene [ 1. O I 10 I< 1. O I< 1. O ]
I Chloroethano I 2,0 I 20 I< 2.0 I< 2.0-I
[ Chloroform I 1.0 I 10 I< 1.0 I< 1.0 ]
I Chloromethane I 2.0 I 20 I< 2.0 I< 2.0 I
I Dibrcmochloromsthane ] 1.0 I 10 I< 1.0 I< 1.0 I
I 1,2-Dichlorobenzene I 1.0 I 10 I< 1.0 I< 1.0 I
I 1,3-Dichlorobenzene I 1.0 1 10 1< 1.0 I< 1.0 I
I 1,4-DichlorobenZene I 1.0 I 10 I< 1.0 I< 1.0 [
I D1chiorodifluoromethane I 2.0 I 20 I< 2.0 I< 2.0 I
1 l,1-Dichloroechape I 1.0 I 10 I< 1.0 I< 1.0 j
I 1,2-Dichloroethana l 1.0 [ 10 [< 1.0 I< 1.0 I
I 1, l-DichloroeChene I 1.0 I 10 I< 1.0 I< 1.0 I
[ cia-1,2-Dichloroethene I l.O l 10 J< 1.0 I< 1.0 I
I crana-1,2-Dichloroechene I 1.0 I 10 I< l.O J·< 1.0 I
'-------------------' ALL COMPOUNDS EXPRESSED IN MICROGRAMS/LITER UNLESS OTif~WIS_E NOTED.
ALL NON-0:ETECT VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLECT DILtITIONS/SAMPLE VOLUME).
SEE ATTACHED PAGE FO_R DEFINITIONS OF TERMS AND QUALIFIERS.
227 French Landing Drive Nashville, Tennessee 37228 615-345-1115
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FAX [phone]
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Eckenfelder Laboratory, LLC
Client: FCX -El Paso #18895.006
Date Reported: 06/08/00
·1 ECKENFELDER SAMPLE NUMBER I V1BLK0531 I 0005109-06 I
1----------------------------------------------1-----------1-----------1
I DATE SAMPLED I NA I 05/18/00 I
-·1 DATE RECEIVED I NA I 05/19/00 I
I DATE ANAlYZED I 05/31/00 I 05/31/00 I
1-------------------------.--------------------1-----------1-----------I
I I M.BLANK I Trip Blankl
1 CLIENT SAMPLE DESCRIPTION I I #1589 I
I . . I I I 1-----------------· ______________ ·. ----. -------1-----------1-----------1
I VOLATILE ORGANICS I I I I I
I BY USEPA METHOD 8260 I MDL. I EQL I C:ONC I C:ONC I
1----------------------------------------------1-----------1-----------1
I 1,2-Dichloropropane I 1.0 I 10 I< 1.0 I< 1.0 I
I cis-1,3-Dichloropropene J 1.0 [ 10 I< 1.0 I< 1.0 I
I trans-1,3-Dichloropropene I 1.0 · I 10 I< 1.0 I< 1.0 I
1 Ethylbenzene I 1.0 I 10 I<'· 1.0 1 < 1.0 ]
I 2-Hexanone ] 2.0 I 20 I< 2.0 I< 2.0 I
I Methylene chloride I 1.0 I 10 I< 1.0 I 1.8 J[
] 4-Methyl-2-pentanone I 2.0 ] 20 ].< 2.0 I< 2.0 I
I Styrene I 1.0 I 10 I< 1.0 I< 1.0 I
I 1,1,2,2-Tetrachloroethane I 1.0 I 10 I< 1.0 I< 1.0 I•
I Tetrachloroethene I 1.0 I 10 · I< 1.0 I< 1.0 I
I Toluene I 1.0 I 10 I< 1.0 \< 1.0 I
I 1,1,1-Trichloroethane \ 1.0 I 10 I< 1.0 I< 1.0 I
I 1,1,2-Trichloroethane I 1.0 I 10 I< 1.0 I< 1.0 I
I Trichloroethane I 1.0 I 10 I< 1.0 I< 1.0 I
I Trichlorofluoromethano I 2.0 l 20 I< 2.0 I< 2.0 I
I Vinyl acetcite \ 5.o I 50 I< s.o I< 5.0 I
I Vinyl chloride 1 2.0 I 20 I< 2.0 I< 2,0 I
I Xylene(total) I 1.0 I 10 I< 1.0 I< 1.0 I
1 ___________________ 1
ALL COMPOUNDS EXPRESSED IN MICROGRAMS/LITER UNLESS OTHERWISE NOTED.
ALL NON-DETECT VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLECT DILTJrIONS/SAMPLE VOLUME),
SEE ATTACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
Eckenfelder Laboratory, LLC WW~
D. Rick Davis
Vice President
ANALYTICAL REPORT TERMS AND QUALIFIERS (GC/MS)
MDL: The method detection limit (MDL) is defined as the minimum
concentration of a substance that can be measured and reported with
99% confidence that the analyte concentration is greater than zero. The
MDL is determined from analysis of a sample containing the analyte in a
given matrix.
EQL: The estimated quantitation .· limit (EQL) is defined as the estimated
concentration above which quantitative results can be obtained with a
. specific degree of confidence. Eckenfelder Laboratory, LLC. defines the
EQL to be ten times the MDL.
B: The presence of a "B" ·to the right of an analytical value indicates that
this compound was also detected in the method blank and the data
should be interpreted with caution. One should consider the possibility
that the correct sample result might be less than the reported result and,
perhaps, zero.
D: When a sample (or sample extract) is rerun diluted because .one of the
compound concentrations exceeded the highest concentration range for
the standard curve, all of the values obtained in the dilution run will be
flagged with a "D".
E: The concentration for any compound found which exceeds the highest
concentration level on the standard curve for that compound will be
flagged with an "E". Usually the sample will be rerun at a dilution to
quantitate the flagged compound.
J: The presence of a "J" to the right of an analytical result indicates thatthe
reported result is estimated. The mass spectral data pass the
identification criteria showing that the compound is present, but the
· calculated result is less than the EQL. One should feel confident that
the result is greater than zero and less than the EQL.
L:\REPORTS\ART&QLT.DOC
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Client: FCX #18995.006
Date Reported: 06/16/00
~
Eckenfelder
Laboratory, LLC
I ECKENFELDER SAMPLE NUMBER I V1BLKos31 I ooos1:u-03 I
1----------------------------------------------1-----------1-----------1 I DATE SAMPLED I NA I 05/22/00 I
•. I DATE RECEIVED I NA I 05/23/00 I
I DATE ANALYZED I ·05/31/00 I 05/31/00 I
1----------------------------------------------1-----------1-----------1
I I M.BlANK IEB O MP-10 I
I CLIENT SAMPLE DESCRIFrION I I I
I I I I
1----------------------------------------------1-----------1-----------1
I VOLATILE ORGANICS I I I I I
I BY USEPA METIIOD 8260 I MDL I EQL I OONC I QQNC I
1-------------.--------------------------------1-----------1-----------1
] Acet:one ! 5.0 I 50 I< 5.0 I< 5.0 I
I Benzene I 1.0 I 10 I< 1.0 I< 1.0 1
I Bromodichloromethane 1.0 I 10 I< 1.0 I< 1.0 J
I Bromoform 1.0 I 10 I<-1.0 ]< 1.0 1
I Bromomethano 2.0 I 20 I< 2.0 I< 2.0 I
! 2-Butanone 10 I 100 I< 10 I< 10 I
I carbon disulfide 1.0 I 10 I< l.O I< 1.0 I
I Carbon tetrachloride 1.0 I 10 [< 1.0 I< 1.0 I
I Chlorobenzeno 1.0 I 10 I< 1.0 I< 1.0 I
[ Chloroethane 2.0 l 20 I< 2.0 I< 2.0 I
I Chlorof.prm 1.0 l 10 1< 1.0 I< 1.0 I
] Chloromethane 2.0 I 20 I< 2.0 I< 2.0 I
J Dibromochloromethane 1.0 I 10 I< 1.0 I< 1.0 I
I l,2-D1chloroben2ene 1.0 I 10 I< 1.0 \< 1.0 I
I 1,3-Dichlorobenzene 1.0 I 10 !< 1.0 I< 1.0 !
I 1,4-Dichlorobenzene 1.0 I 10 I< 1.0 I< 1.0 I
1 Dichlorodifluoromethane 2.0 I 20 I< 2.0 I< ·2.0 I
I 1,1-Dichloroethane 1.0 I 10 I< 1.0 I< 1.0 I
I 1,2-Dichloroethane l.O I 10 [< 1.0 !< 1.0 I
I 1,1-Dichloroethene 1.0 I 10 I< 1.0 I< 1.0 I
I cia-1,2-Dichloroethene 1.0 I 10 \< 1.0 J< 1.0 I
I trans-1,2-Dichloroethene 1.0 I 10 I< 1.0 I< 1.0 J
1 ___________________ 1
ALL COMFOUNDS EXPRESSED IN MICROGRAMS/LITER UNLESS OTHERWISE NOrED,
ALL NON-DETECT VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLECT DILUl'IONS/SAMPLE VOLUME).
SEE ATTACHED PAGE FOR DEFINITIONS OF TEF.MS AND QUALIFIERS.
227 French Landing Drive Nashville, Tennessee 37228 615-345-1115 FAX [phone]
Eckenfelder Laboratory, LLC
Client: FCX #18995.006
Date Reported: 06/16/00
I ECKENFELDER SAMPLE NUMBER I v1sLKosJ1 jooos121-03 j
1----------------------------------------------1-----------1-----------1
I DATE SAMPLED I NA I 05/22/00 I
•. I DATE RECEIVED I NA I 05/23/00 I
I DATE ANALYZED I 05/31/00 I 05/31/00 I
1----------------------------------------------1-----------1-----------1
I I M.BLANK IEE O MP-10 I
I CLIENT SAMPLE DESCRIIi'r!ON I I I
I I I I
1----------------------------------------------1-----------1-----------1
I VOLATILE ORGANICS I I I I I
I BY USEPA METHOD B260 I MDL I EOL I CXJNC I CXJNC I
1----------------------------------------------I---------·-1-----------I
I 1,2-Dichloropropane I 1.0 I 10 [ < 1.0 < 1.0 I
j cis-1,3-Dichloropropene I 1,0 I 10 l< 1.0 < 1.0 [
I trans-1,3-Dichloropropene I 1.0 I 10 I< 1.0 < 1.0 I
l Ethylbenzene I 1.0 I 10 I<·-1.0 < 1.0 I
I 2-Haxanone I 2.0 I 20 I< 2.0 < 2.0 j
I Methylene chloride I 1.0 I 10. ]< 1.0 < 1.0 I
[ 4-Methyl-2-pentanone I 2,0 I 20 I< 2.0 < 2.0 I
I Styrene [ 1.0 I 10 [< 1.0 < 1.0 J
I 1,1,2,2-Tetrachloroethane I 1.0 I 10 I< 1.0 < 1.0 .I
I Tetrachloroethone I 1.0 I ·10 I< 1.0 < 1.0 I
I Toluene I 1.0 ! 10 I< 1.0 < 1.0 1·
[ 1,1,1-Trichloroethane I 1.0 I 10 I< 1.0 < 1.0 I
I 1,1,2-Trichloroethane I 1.0 I 10 I< 1.0 < 1.0 I
I Trichloroethene I 1.0 .I 10 I'< 1.0 [< 1.0 I
I Trichlorofluoromethane I 2.0 I 20 I< 2.0 I< 2.0 I
I Vinyl acetato I ·5.0 I 50 I< 5.0 I< 5,0 I
I Vinyl chloride I 2.0 I 20 I< 2.0 J< 2.0 I
I Xylene{total) I 1.0 I 10 -1< 1.0 I< 1.0 ! 1 ____________________ 1
ALL COMPOUNDS EXPRESSED IN MICROGRAMS/LITER UNLESS OTHERWISE NOTED.
ALL NON-DETECT VALUES ARE REPORTED AS <MDL {MODIFIED TO REFLECT DILUTIONS/SAMPLE VOLUME).
SEE ATTACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
. Ecke~ .. );atory, J) \ ..
D. Rick Davis
Vice President
LLC
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ANALYTICAL REPORT TERMS AND QUALIFIERS (GC/MS)
MDL: The method detection limit (MDL) is defined as the minimum
concentration of a substance that can be measured and reported with
99% confidence that the analyte concentration is greater than zero .. The
MDL is determined from analysis of a sample containing the analyte in a
given matrix.
EQL: The estimated quantitation limit (EQL) is defined as the estimated
concentration above which quantitative results can be obtained with a
. specific degree of confidence. Eckenfelder Laboratory, LLC. defines the
EQL to be ten times the MDL.
B: The presence of a "B" to the right of an analytical value indicates that
this compound was also detected in the method blank and the data
should be interpreted with caution. One should consider the possibility
that the correct sample result might be less than the reported result and,
perhaps, zero.
D: When a sample (or sample extract) is rerun diluted because one of the
compound concentrations exceeded the highest concentration range for
the standard curve, all of the values obtained in the dilution run will be
flagged with a "D".
E: The ·concentration for any compound found which exceeds the highest
concentration level on the standard curve for that compound will be
flagged with an "E". Usually the sample will be rerun at a dilution to
quantitate the flagged compound.
J: The presence of a "J" to the right of an analytical result indicates that the
reported result is .estimated. The mass spectral data pass the
identification criteria showing that the compound is present, but the
calculated result is less than the EQL. One should feel confident that
the result is greater than zero and less than the EQL.
L:'\REPORTS'\ART&QLT .DOC
Client: FCX #18995.006
Date Reported: 06/16/00
~ llliiF
Eckenfelder
Laboratof¼ LLC
I ECKENFELDER SAMPLE NUMBER I VlBLK052B !ooos121-as I
1-----------------------------------------·----I-----------I-----------I I DATE SAMPLED I NA I 05/22/00 I
I DATE RECEIVED I NA I 05/23/00 I
I DATE ANALYZED I 05/28/00 I 05/28/00 I
1---. ------------------------------------------1----------1-----------1 I I M. BLANK I Trip Blank I
I CLIENT SAMPLE DESCRIPTION I I #1602 I
I I I I
l---------------·------------------------------1-----------I-----------I I VOLATILE ORGANICS I I I I I
I BY USEPA METIIOD 8260 I MDL [ EQL ( CONC I CXlNC I
1----------------------------------------------1-----------1-----------1
I Acetone I 5.0 I 50 I< 5.0 I< 5.0 I
I Benzene I 1.0 I 10 I< 1.0 I< 1.0 I
1 Brorncdichloromethane I 1. O ! 10 J < · 1. o I< 1. O I
l Bromoform I 1.0 10 J<, 1.0 I< 1.0 I
I Bromomathane I 2.0 20 I< 2.0 I< 2.0 I
I 2-Butanone ! 10 100 I< 10 I< 10 I
I carbon disulfide I 1.0 10 I< 1.0 I< 1.0 I
I Carbon tetrachloride I 1.0 10 I< 1.0 I< 1.0 I
j Chlorobenzene I 1.0 10 I< 1.0 I< 1.0 I
I Chloroethane I 2,0 20 J< 2.0 I< 2.0-[
I Chlorof,prm I 1.0 10 I< 1.0 I<. 1.0 I
I Chloromethane I 2.0 20 I< 2.0 I< 2.0 I·
I Dibromochlcrornethane I 1. O 10 I< 1. O [ < 1. O I
J 1,2-Dichlorobenzene 1. 1.0 10 I< 1.0 I< 1.0 I
] 1,3-Dichlarobenzene ] 1.0 10· I< 1.0 I< l.O l
l 1,4-Dichlorobenzene I 1,0 10 I< 1.0 I< 1.0 I
I Dichlorodifluoromethane I 2.0 20 \< 2.0 I< 2.0 I
I 1,1-Dichlorcethane I l.0 10 J< 1.0 [·< l.O I
I l,2-Dichloroethane I l.O 10 I< l.O [< l.O I
I 1,1-Dichloroethene I l.O 10 I< l,O I< l.O I
I cia-1,2-Dichloroethene I 1.0 · 10 I< 1.0 I< 1.0 I
I trana-1,2-Dichloroethene I 1.0 10 I< 1.0 I< 1.0 ]
1 ___________________ 1
ALL COMPOUNDS EXPRESSED IN MICROGRAMS/LITER UNLESS OTHERWISE NarEO.
ALL NON-DETECT VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLECT DILllrIONS/SAMPLE VOLUME),
SEE ATTACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
227 French Landing Drive Nashville, Tennessee 37228 615-345-1115
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FAX [phone]
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Eckenfelder Laboratory, LLC
Client: FCX #18995.006
Date Reported: 06/16/00
I ECKENFELDER SAMPLE NUMBER I V1BLK0528 ! 0005121-05 [
1----------------------------------------------1-----------1-----------1 I DATE SAMPLED I NA I 05/22/00 I
.. I DATE RECEIVED I NA I 05/23/00 I
I DATE ANALYZED I 05/28/00 I 05/28/00 I
l----------------------------------------------1-----------I-----------I I I M. BLANK I Trip Blank I
I CLIENT SAMPLE DESCRIPTION I I #11502 !
I I I I
1----------------------------------------------I----------1-----------1 I VOLATILE ORGANICS I I I I I
· 1 BY USEPA METHOD 82150 I MDL I EQL I CONC I CONC I
l----------------------------------------------1-----------I-----------I
J 1,2-Dichloropropane I 1.0 I 10 I< 1.0 I< 1.0 I
1 cis-1,3-Dichloropropene I 1.0 I 10 ]< 1.0 I< 1.0 I
I trana-1,3-Dichloropropene I 1.0 I 10 J< 1.0 1< 1.0 I
I Ethylbanzene I 1.0 I 10 I<· 1.0 I< 1.0 I
I 2-Hexanone I 2.0 I 20 I< 2.0 I< 2.0 I
I Methylene chloride I 1.0 I 10 I< 1.0 I< 1.0 I
I 4-Methyl-2-pentanone I 2.0 [ 20 !< 2.0 I< 2.0 I
I Styrene I 1.0 I 10 I< 1.0 I< 1.0 I
I 1,1,2,2-Tetrachloroethane I 1.0 ! 10 I< 1.0 ]< 1.0 I
I Tetrachloroethene ] 1.0 J 10 I< 1.0 I< 1.0 I
I Toluene I 1.0 I 10 I< 1.0 I< 1.0 I
I 1,1,1-Trichloroethane I 1.0 I 10 I< 1.0 I< 1.0 I
I 1,1,2-Trichloroethane I 1.0 I 10 I< 1.0 I< 1.0 I
I Trichloroethane I 1.0 I 10 I< 1.0 I< 1.0 I
I Trichlorofluorometharie I 2.0 [ 20 I< 2.0 /< 2.0 I
[ Vinyl acetate I 5.0 I 50 ]< s.o I< _5.0 I
I Vinyl chloride J 2.0 ] 20 I< 2.0 I< 2.0 I
l Xylene(total) I l.O I 10 I< l.O I< 1.0 I
1 ___________________ 1
ALL COMPOUNDS EXPRESSED IN MICROGRAMS/LITER UNLESS OTHERWISE NOTED.
ALL NON-DETECT VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLECT DILtrrlONS/SAMPLE VOLUME).
SEE AITACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS,
Eckenfelder Laboratory, LLC
J)~o==S:
D. Rick Davis
Vice President
ANALYTICAL REPORT TERMS AND QUALIFIERS (GC/MS)
MDL: The method detection limit (MDL) is defined· as the minimum
concentration of a substance that can be measured and reported with
99% confidence that the analyte concentration is greater than zero. The
MDL is determined from analysis of a sample containing the analyte in a
given matrix.
EQL: The estimated quantitation limit (EQL) is defined as the estimated
concentration above which quantitative results can be obtained with a
. specific degree of confidence. Eckenfelder Laboratory, LLC. defines the
EQL to be ten times the MDL.
B: The presence of a "B" to the right of an analytical value indicates that
this compound was also. detected in the method blank and the data
should be interpreted with caution. One should consider the possibility
that the correct sample result might be less than the reported result and,
perhaps, zero.
D: When a sample (or sample extract) is rerun diluted because one of the
compound concentrations exceeded the highest concentration range for
the standard curve, all of the values obtained in the dilution run will be
flagged with a "D".
E: The ·concentration for any compound found which exceeds the highest
concentration level on the standard curve for that compound will be
flagged with an "E". Usually the sample will be rerun at a dilution to
quantitate the flagged compound.
J: The presence of a "J" to the right of an analytical result indicates that the
reported result is estimated. The mass spectral data pass the
identification criteria showing that the compound is present, but the
calculated result is less than the EQL. One should feel confident that
the result is greater than zero and less than the EQL.
L:\REPORT'S\.ART&QLT.DOC
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Eckenfelder
Laboratory, LLC
Client: FCX #18895.006
Date Reported: 06/16/00
I ECKENFELDER SAMPLE NUMBER j MEDBLK05132) MEDBLK05141 I 0005132-0l • I 0005132-02 I 0005132-03 I
1----------------------------------------------1-----,-----1-----------1-----------1-----------1-----------1
I DATE SAMPLED I NA I NA I 05/23/00 I 05/23/00 I 05/23/00 I
•. I DATE RECEIVED l NA j NA I OS/24/0o I OS/24/oo I os/24/00 I
I DATE ANALYZED I 05/31/00 I 05/31/00 I 05/31/00 I 05/31/00 I 05/31/00 I
----------------------------------------------1------.---1-----------1-----------1-----------1-----------1
j M.Bl.ANK j M.BLANK IMP-10 39ft IMP-10 55ft IMP-6 4-8ft I
CLIEN1' SAMPLE DESCRIPI'ION I 0005132 I 00051<1 I I I I
I I I I I I
---------------------------------------------1-----------1-----------1-----------1-----------1-----------1
VOLATILE ORGANICS
BY USEPA METHOD 8260
I I I I I I I I
I ~LI -I= I= I= I= I= I
----------------------------------------------1-----------1-----------1-----------1-----------1-----------1
Acetone
Benzene
Bromod.ichloromethane
Bromoform
Bromomathane
2-Butanone
Carbon diaulfido
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chlorofarm
Chloromsthane
Dibromochloromethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cie-1,2-Dichloroethene
trane-1,2-Dichloroethone
I 0.2s I 2.s I< 0.2s I< 0.2s I< o.34 I< 0.21 I< o.31 I
I o.oso I a.so_ I< o.oso I< o.oso I< o.os1 I< o.os4 I< 0.062 I
I o.oso I a.so I< o.oso I< o.oso I< 0.061 I< o.os4 I< o.os2 1
I o.oso I a.so lc.o.oso I< o.oso I< a.as, I< o.os4 I< o.os2 I
I 0.10 I 1.0 I< 0.10 le 0.10 I< 0.13 I< 0.11 I< 0.12 I
I a.so I s.o I< a.so I< a.so I< o.67 I< o.s4 I< 0.62 I
I o.oso I a.so I< o.oso !c o.oso I< a.as, I< o.os4 I< o.os2 I
I o.oso I a.so !< o.oso !< o.oso I< a.as, I< o.os4 I< o.os2 I
t o.oso I a.so I< o.oso I< o.oso I< 0.061 I< o.os4 [< 0.062 I
0.10 l 1.0 I< 0.10 I< 0.10 I< 0.13 l< 0.11 I< 0.12 I
o.oso I a.so I< o.oso I< o.oso ]< 0.061 I< o.os4 I< 0.062 I
0.10 I 1.0 I< 0.10 I< 0.10 1< 0.13 I< 0.11 I< 0.12 1
o.oso I a.so I< o.oso I< o.oso I< 0.061 I< o.os4 I< 0.062 I
o.oso I a.so I< o.oso I< o.oso I< 0.061 I< o.os4 I< 0.062 I
o.oso I a.so I< o.oso I< o.oso I< 0.061 I< o.os4 I< 0.062 I
o.oso I a.so I< o.oso I< o.oso I< 0.061 I< o.os4 I< 0.062 I
0.10 I 1.0 I< 0.10 I< 0.10 I< 0.13 I< 0.11 I< 0.12 I
o.oso I a.so I< o.oso I< o.oso I< 0.061 I< o.os4 !< 0.062 I
o.o5o I a.so 1< o.oso I< o.oso I< 0.061 \< o.os4 I< 0.062 I
o.oso l a.so I< o.o5o I< o.oso l< 0.061 I< o.os4 I< 0.062 !
o.oso I o.5o I< o.o5o I< o.oso l< 0.061 I< o.os4 I< o.os2 I
o.o5o I o.5o I< o.oso I< o.oso I< 0.061 I< o.os4 I< o.os2 I __________________________________ I
ALL COMPOUNDS EXPRESSED IN MILLIGRAMS/KILOGRAM DRY UNLESS OTHERWISE NOTED.
ALL NON-DETECT VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLECT DILurIONS/DRY WEIGHT/SAMPLE WEIGHT).
SEE ATTACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
* -so~ ASPECT OF QUALITY CONTROL WAS Nar WITHIN LIMITS,
RESULTS SHOULD BE CONSIDERED AS ESTIMATED.
227 French Landing Drive Nashville, Tennessee37228 615-345-1115 FAX [phone]
.---
Eckenfelder Laboratory, LLC
Client: FCX #18895.006
Date Reported: 06/16/00
I ECKENFELDER SAMPLE NUMBER JMEDBLK05132IMEDBLK0514 !ooos132-01•10005132-02 jooo5132-03 I
l··············································l···········l···········l···········l···········l···········I
I DATE SAMPLED . I NA I NA I 05/23/00 I 05/23/00 I 05/23/00 I
•. I DATE RECEIVED I NA I NA I 05/24/00 I 05/24/00 I 05/24/00 I
I DATE ANALYZED I 05/31/00 I 05/31/00 I 05/31/00 I 05/31/00 I 05/31/00 I
· l··············································l·····•·····l···········l···········l···········l···········I
I I M.BLANK I M.BLANK IMP-10 39ft IMP-10 55ft IMP-6 4-Bft I
I CLIENT SAMPLE DESCRIPTION I 0005132 I 0005141 I I I )
··············.································l···········l···········l···········l···········l···········I
VOLATILE ORGAN I CS I I I I I I I I
BY USEPA METHOD 8260 I MDL I EQL I CONC I CONC I CONC I CCNC I CCNC I
··············································l···········l···········l···········l···········l···········I
1,2-Dichloropropane
cis-1, 3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
2-He..-.anone
Methylene chloride
4-Methyl-2-pcntanone
Styrene
I o.oso I a.so I< o.oso I< o.oso ]< 0.061 I< o.os4 I< 0.062 1·
I o.a5o I a.so I< o.o5o I< o.oso I< 0.061 I< o.os4 !< 0.062 I
I o.oso I a.so !< o.oso I< o.oso I< 0.061 I< 0.054 !< 0.062 I
I o.oso I a.so I< o.oso I< o.oso I< 0.061 I< o.os4 I< 0.062 I
I 0.10 l 1.0 l<--□.10 I< 0.10 I< a.13 I< 0.11 I< 0.12 I
I o.oso I a.so ]< o.oso [< o.oso I< a.061 I 0.061 JI< 0.062 I
I 0.10 I 1.0 I< 0.10 I< d.10 I< 0.13 I< 0.11 I< 0.12 I
I o.oso I o.so I< o.o5o 1< o.o5o !< 0.061 I< 0.054 I< 0.062 I
1,1,2,2-Tetrachloroethane I o.aso I a.so I< o.o5o I< o.oso I< 0.067 I< 0.054 I< o.062 I
Tetrachloroethene
Toluene
l,1,1-Trichlocoethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
Vinyl acetate
_Vinyl chl,oride
Xylene {total)
I 0.050 I a.so I< o.oso I< o.oso l 1.3 l 0.12 J[ 0.014 JI
I o.oso I a.so J< o.oso I< o.oso I< 0.061 I< 0.054 !< 0.062 I
I o.o5o I a.so l< o.oso I< o.o5o I< 0.061 I< 0.054 l< 0.062 I
I o.oso 1 o.5o I< o.oso I< o.o5o I< 0.061 I< 0.054 1~ 0.062 I
1 a.oso I a.so I< o.oso I< o.oso I< 0.061 [< 0.054 I< 0.062 J
I 0.10 I. 1.0 I< 0.10 I< 0.10 [< 0.13 I< 0.11 I< 0.12 I
I 0.25 I 2.s [< 0.25 I< 0.2s I< o.34 I< 0.21 I< o.31 I
I 0.10 ! 1.0 !< 0.10 [< 0.10 I< 0.13 I< 0.11 !< 0.12 I
I 0,050 l a.so I< o.oso I< 0.050 I< 0.061 I< 0.054 !< 0.062 I ____________________________________ I
ALL COMPOUNDS EXPRESSED IN MILLIGRAMS/KILOGRAM DRY UNLESS OTHERWISE NOTED •.
ALL NON-DETECT VALUES ARE REPORTED AS <MDL {MODIFIED TO REFLECT DILtrrlONS/DRY WEIGHT/SAMPLE WEIGHT),
SEE ATTACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
• • SOME ASPECT OF QUALITY O:,N'I'ROL WAS NOT WITHIN LIMITS,
RESULTS SHOULD BE CONSIDERED AS ESTIMATED.
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Eckenfelder Laboratory, LLC
Client: FCX #18895.006
Date Reported: 06/16/00
I ECKENFELDER SAMPLE NUMBER 10005141-01 10005141-02 /0005141-03 I
I·······. --------------·····----------------···l·······----1·-·-···-·-·l--··--···--I I DATE SAMPLED I 05/24/00 I 05/24/00 I 05/24/00 I .
.. I DATE RECEIVED I 05/25/00 I 05/25/00 I 05/25/00 I
I DATE ANALYZED I 05/31/00 I 05/31/00 I 05/31/00 I
l-----------------------·····---------------·-·l-----------1-----------1-----------I I IMP·• 3 .5ft I MP-9 I MP-9 41ft I
I CLIENT SAMPLE DESCRIPTION I 13.5ft DUPE I I
I I I I I
l-------------·····---------·------------------1--------·-·l·--··-·····l·-··-------I I VOLATILE ORGANICS I I I I I I
j BY USEPA METHOD 9260 I MDL I EQL I CONC I CONC I CONC I
1--· ----------------········-------------------1-----------1-----------1-----------1
I Acetone ! 0.25 I 2.5 I< 0.31 I< 0.32 I< 0.29 I
I Benzene I o.oso I a.so I< 0.0151 I< 0.064 I< 0.059 I
_I Bromodichlorometbane ] o. oso [ O. SO I< O. 061 I< O. 064 I< o. 059 I
I BromClform I o.oso I a.so I·'" 0.061 I< 0.064 I< o.os9 I
1 Bromomethane I 0.10 I 1.0 I< 0.12 I< 0.13 I< 0.12 I
I 2-Butanona a.so I s.o I< 0.61 I< 0.64 I< o.59 I
I carbon disulfide o.oso I a.so I< 0.061 I< 0.064 I< o.OS9 I
I Carbon tetrachloride 0.050 I a.so l< 0.061 I< 0.064 I< 0.059 I
j Chlorobenzene o.oso I a.so I< 0.061 I< 0.064 I< 0.059 I
I Chloroethane 0.10 I 1.0 I< 0.12 I< 0.13 [< 0.12 !
I Chlorof.orm o.oso I a.so I< 0.061 I< 0.064 I< o.059 I
I Chloromethane 0.10 I 1.0 [< 0.12 1< O.l3 I< 0.12 I
I Dibrcmochloromathano o.oso I a.so I< 0.06l I< 0.064 ]< 0.059 I
I l,2-Dichlorobenzene o.oso j a.so I< 0.061 I< 0.064 I< 0.059 [
I 1,3-Dichlorobenzene 0.050 I 0.50 I< 0.061 I< 0.064 I< 0.059 I
I 1,4-0ichlorobenzene 0.050 I a.SO I< 0.061 I< 0.064 I< 0.059 1
I Dichlorodifluoromethane 0.10 I l.O I< 0.12 I< 0.13 !< 0.12 I
I . 1,1-oichloroethane o.oso I a.so I< 0.061 I< o.064 I< 0.059 I
I 1,2-Dichloroethane 0.050 I a.so I< 0.061 I< 0.064 I< 0.059 I
I 1,1-Dichloroethene o.oso I a.so I< 0.061 · I< 0.064 [< 0.059 1
I cie-1,2-DichloroethBile o.oso I a.so I< 0.061 I< 0.064 I< 0.059 I
I trane-1,2-Dichloroethene o.oso [ a.so I< 0.061 ]< 0.064 I< 0.059 I
1 _______________________ 1
ALL COMPOUNDS EXPRESSED IN MILLIGRAMS/KILOGRAM DRY UNLESS OTHERWISE NOTED.
ALL NON-DETECT VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLECT DILllrIONS/DRY WEIGHT/SAMPLE WEIGITT).
SEE AlTACHEO PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
·--·
Eckenfelder Laboratory, LLC
Client: FCX #18895.006
Date Reported: 06/16/00
I ECKENFELDER SAMPLE NUMBER I 0005141-0l I 0005141-02 I 0005141-03 I
1----------------------------------------------1-----------1-----------1-----------1
I DATE SAMPLED I 05/24/00 I 05/24/00 I 05/24/00 I
•. I DATE RECEIVED I 05/25/00 I 05/25/00 I 05/25/00 I
I DATE ANALYZED I 05/31/00 I 05/31/oo I 05/31/00 I
1---------------------------------· ------------1-----------1-----------1--~-------1
I IMP-9 3 .5ft I MP-9 I MP-9 41ft I
I CLIENT SAMPLE DESCRIPTION I 13.5ft DUPE I I
I I I I I
1--------·-------------------------------------1-----------1-----------1-----------1
I VOLATILE ORGANICS I I I I I I
I BY USEPA METHOD 8260 I MDL I EQL I CONC I CXlNC I CXlNC I
1----------------------------------------------l------~----I---------. -1-----------
1 l, 2-Dichloropropane I o. 050 I O. SO I< O. 061
I cia-l_,3-Dichloropropene I 0.050 I a.so
I trana-l,3-Dichloropropene l 0.050 I 0.50
I Ethylbenzene I o.oso I a.so
I 2-Hexanone I 0.10 ! 1.0
I Methylene chloride I o.oso l o.50
I 4-Methyl-2-pentanone I 0.10 I 1.0
[ Styrene I 0.050 I 0.50
! . 1,1,2,2-Tetrachloroethane I o.oso I 0.50
I Tetrachloroethene I 0.050 I a.so
I Toluene I o.oso I a.so
I l,1,l-Trichloroethane ] 0.050 I 0.50
I 1,1,2-Trichloroethane J o.oso [ a.so
I Trichloroethane I o.oso I a.so
I Trichlorofluoromethane ] 0.10 I 1.0
I Vinyl acetate I O. 25 I . 2. 5
I Vinyl chloride I 0.10 I 1,0
I Xylene(total) I 0.050 I 0.50
I< 0.061
I< 0.061
I< 0.001
I< o. 12
I< 0.061
l < o .12
I< 0.061
I< 0.061
I 0.11
I< 0.061
I< 0.061
I< 0.061
I< 0.061
I< 0.12
I< 0.31
I< 0.12
I< 0.061
I<
I<
I<
I' 1,
I'
I<
1,
1,
JI
I<
1,
0.064
0.064
0.064
0.064
0.13
0.064
0.13
0.064
0.064
0.13
0.064
0.064
I< _0.054
I< 0.064
1, 0.13
·I< 0.32
I' 0.13
1, 0.064
1,
1,
. I.<
1,
I<
I<
1,
1,
1,
JI
1,
0.059
0.059
0.059
0.059
0.12
0.059
O·, 12
0.059
0.059
3.3
0.059
I< 0.059
1, 0.059
1, 0.059
1, 0.12
0.12
0.059 I ___________________________ _
ALL COMPOUNDS EXPRESSED IN MILLIGRAMS/KILOGRAM DRY UNLESS OTHERWISE NOTED.
ALL NON-D~CT VALUES ARE REPORTED AS <MDL {MODIFIED TO REFLECT DILtrrIONS/DRY WEIGHT/SAMPLE WEIGHT).
SEE ATTACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
Eckenfelder Laboratory, LLC
L>\1lU.:S.
D. Rick Davis
Vice President
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ANALYTICAL REPORT TERMS AND QUALIFIERS (GC/MS)
MDL: The method detection limit (MDL) is defined as the minimum
concentration of a substance that can be measured and reported with
99% confidence that the analyte concentration is greater than zero. The
MDL is determined from analysis of a sample containing the analyte in a
given matrix.
EQL: The estimated quantitation limit (EQL) is defined as the estimated
concentration above which quantitative results can be obtained with a
. specific degree of confidence. Eckenfelder Laboratory, LLC. defines the
EQL to be ten times the MDL.
B: The presence of a "B" to the right of an analytical value indicates that
this compound was also detected in the method blank and the data
should be interpreted with caution. One should consider the possibility
that the correct sample result might be less than the reported result and,
perhaps, zero.
D: When a sample (or sample extract) is rerun diluted because one of the
compound concentrations exceeded the highest concentration range for
the standard curve, all of the values obtained in the dilution run will be
flagged with a "D".
E: The ·concentration for any compound found which exceeds the highest
concentration level on the standard curve for that compound will be
flagged with an "E". Usually the sample will be rerun at a dilution to
quantitate the flagged compound.
J: The presence of a "J" to the right of an analytical result indicates that the
reported result is estimated. · The mass spectral data pass the
identification criteria showing that the compound is present, but the
calculated result is less than the EQL. One should feel confident that
the result is greater than zero and less than the EQL.
L:\REPORTS\.ART&QLT.DOC
·.} FORM 2
SOIL VOLATILE SYSTEM MONITORING COMPOUNb'RECOVERY
Lab Name: ECKENFELDER LLC Contract: FCX
Lab Code: NA Batch No.: SAS No.: NA SDG No.: FCX.V05132
Level: (low/med) MED
SMCl
SMC2
SMC3
SMC4
(DFM)
(DCE)
(TOL)
(BFB)
LAB SMCl SMC2 SMC3
SAMPLE NO. (DFM) # (DCE) # (TOL) #
============ ------------====== ------------01
02
03
04
05
06
.07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
.22
23
24
25
26
27
28
29
30
MP-10
MP-10
MP-6
MP-9
MP-9
MP-9
39FT 87
55FT 95
4-SFT 91
3.5FT 96
3.5FT D 93
41FT 86
=.Dibromofluoromethane
= l,2-Dichloroethane-d4
= Toluene-dB
= Bromofluorobenzene
'
102
110
102
107
105
104
ECK.
QC LIMITS
(80-120)
(80-120)
(82-117)
(89-118)
93
100
94
97
98
96
SMC4 TOT
(BFB)# OUT
====== ---71*@ 1
78* 0
77* 0
77* 0
80* 0
79* 0
----
-------
-
---
---
-
8260A
QC LIMITS
(80-120)
(80-120)
(81-117)
(74-121)
# Column to be.used to flag recovery values
* Values outside of Eckenfelder QC limits
@ Values outside of 8260A required QC limits
D System Monitoring Compound diluted out
page 1 of 1 FORM II VOA
SPIKE
CONC (mg/Kg)
3.4
3.4
3.4
3.4
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Client: FCX #18895.006
Date Reported: 06/16/00
Eckenfelder
Laboratory, LLC
I ECKENFELDER SAMPLE NUMBER I V1BLK0531 [ 0005132-04 I 000_5141-04 I
1----------------------------------------------I-----------I-----------I-----------I I DATE SAMPLED I NA I 05/23/00 I 0S/24/00 I
.. I DATE RECEIVED I NA I 05/24/00 I 05/25/00 I
I DATE ANALYZED I 05/31/00 I 05/31/00 I 05/31/00 I
1----------------------------------------------I-----------I-----------I-----------I I I M.BLANK !Trip Blank !Trip Blank I
I CLIENT SAMPLE DESCRIPTION I 1#1602/1601 I #1601 I
I I I I I
1----------------------------------------------1-----------1-----------1-----------I VOLATILE ORGANICS I I I I I
j BY USEPA METHOD 8260 j MDL [ EQL [ CONC [ CONC I CONC
1----------------·----------------------------1-----------1-----------I-----------
I Acetone I 5.0 I 50
I Benzene I 1.0 I 10
\ Brom::idichloromethane I 1.0 I 10
I Bromoform \ 1.0 ! 10
I Bromcmethano I 2. o j 20
I 2-Butanone I 10 I 100
1 Carbon disulfide I 1.0 I 10
I Carbon tetrachloride I 1.0 I 10
I Chlorobenzene 1 1. O I 10
I Chloroethano I 2. o I 20
I Chlorof,prm I 1. o I 10
1 Chloromethano I 2.0 I 20
I Dibromochloromethane j 1.0 ! 10
I 1,2-Dichlorobenzene I 1.0 I 10
I 1,3-Dichlorobenzene I 1.0 I 10
! 1,4-Dichlorobonzene I 1,0 I 10
] Dichlorodifluoromothane [ 2.0 I 20
1. 1,1-Dichloroethane I 1.0 j 10
I 1,2-Dichloroethane I. 1.0 I 10
I 1,1-Dichloroethene I 1.0 I 10
I cia-1,2-Dichloroethene I 1.0 I 10
I trana-1,2-Dichloroethene ! 1.0 ! 10
1,
1,
I<
1 ❖
1,
5,0
1. 0
1.0
1.0
2.0
I< 10
1, 1. 0
I< i.o
1, 1.0
1, 2.0
1, 1. 0
1, 2.0
1, 1.0
1, 1.0
1, 1. 0
I< 1.0
1, 2.0
1, 1.0
1, 1.0
I< t.o
I< 1.0
1, 1.0
I< 5.o
I< 1.0
I' 1.0
1.0
2,0
10
1.0
1.0
1.0.
1.0
2.0
1.0
1.0
1.0
1.0
2.0
1.0
1.0
!< 1.0
1, 1.0
I< 1.0
I<
I<
I<
1,
1,
5.0
1.0
1.0
1.0
2.0
I< 10
I< 1.0
I< i.o
1, 1.0
1, 2.0
1, 1.0
1, 2.0
I< l.O
1, 1.0
1, 1.0
I< 1.0
I< 2.0
1, 1.0
1, 1.0
1, 1.0
1, 1.0
1, 1.0
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I ! __________________________ _ I
ALL .COMPOUNDS EXPRESSED IN MICROGRAMS/LITER UNLESS OTHERWISE NOTED.
ALL NON-DETECT VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLECT DILUTIONS/SAMPLE VOLUME).
SEE ATTACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
227 French Landing Drive Nashville, Tennessee 37228 615-345-1115 FAX [phone]
' ';
·:.;.:./
ANALYTICAL REPORT TERMS AND QUALIFIERS {GC/MS)
MDL: The method detection limit (MDL) is defined as the minimum
concentration of a substance that· can be measured and reported with
99% confidence that the analyte concentration is greater than zero. The
MDL is determined from analysis of a sample containing the analyte in a
given matrix.
EQL: The estimated quantitation limit (EQL) is defined as the estimated
concentration above which quantitative results can be obtained with a
. specific degree of confidence. Eckenfelder Laboratory, LLC. defines the
EQL to be ten times the MDL.
B: The presence of a "B" to the right of an analytical value indicates that
this compound was also detected in the method blank and the data
should be interpreted with caution. One should consider the possibility
that the correct sample result might be less than the reported result and,
perhaps, zero.
D: When a sample (or sample extract) is rerun diluted because one of the
compound concentrations exceeded the highest concentration range for
the standard curve, all of the values obtained in the dilution run will be
flagged with a "D".
E: The ·concentration for any compound found which exceeds the highest
concentration level on the standard curve for that compound will be
flagged with an "E". Usually the sample will be rerun at a dilution to
quantitate the flagged compound.
J: . The presence of a "J" to the right of an analytical result indicates that the
reported result is estimated. The mass spectral data pass the
identification criteria showing that the compound is present, but the
calculated result is less than the EQL. One should feel confident that
the result is greater than zero and less than the EQL.
Lc\REPORTS\ART&QLT.DOC
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Client: FCX #18895.006
Date Reported: 06/28/00
Eckenfelder
Laboratory, LLC
ECKENFELDER SAMPLE NUMBER I MBLK0608 I 0006030-0l I 0006030-02 I
----------------------------------------------1-----------1-----------1-----------1
DATE SAMPLED I NA I 06/06/00 I 06/06/00 I
DATE RECEIVED I NA I 06/07/00 I 06/07/00 I
DATE ANALYZED I 06/11/00 I 06/11/00 I 06/11/00 I
----------------------------------------------1-----------1-----.-----1-----------1
I M.BLANK IMP-10 10.5 I MP-10 I
CLIENT SAMPLE DESCRIPTION I I I 31 ft. I
I I I I
----------------------------------------------1-----------I-----------I-----------I
VQ[ATJLE ORGANICS I I I I I I
BY USEPA METHOD 8260 I MDL I EQL I OJNC I CDNC I CONC f
---------------------------------------------1-----------1-----------1-----------1
I Acetono j 0.25 I 2,5 I< 0.25 I< 0.37 I 1.1 J[
I Benzene I o.oso I a.so ]< o.aso I< 0.074 I< o.oso I
I Bromodichlorcmethane I o.oso I a.so ]< o.oso I< o.074 I< 0.060 I
l Bromoform I o.oso I a.so I< o.oso I< 0.074 I< 0.060 I
] Bromomethane I 0.10 J 1.0 I< 0.10 I< 0.15 I< 0.12 J
2-Butanone I -0.so I s.o I< a.so 1< 0.74 I< 0.60 I
Carbon disulfide L o.oso ] a.so I< o.oso I< 0.074 !< 0.060 I
carbon tetrachloride I o.oso I a.so [< o.oso I< 0,074 j< 0.060 [
Chlorobenzene I o.oso I a.so I< o.oso I< 0.074 I< 0.060 I
Chloroethana I 0.10 I 1.0 I< 0.10 I< 0.15 I< 0.12 I
Chloroform. j o.o5o I o.so I< o.oso [< 0.074 I< 0.060 I
Chloromathane I 0.10 I 1.0 ]< 0.10 I< 0.15 I< 0.12 I
Dibromochloromethane I o. oso l o. so I< o. oso I< o. 074 I < o. 060 I
1,2-Dichlorobenzene I 0.050 I a.so I< 0.050 I< 0.074 !< 0.060 [
1,3-Dichlorobenzene I 0.050 I 0.50 I< 0.050 I< 0.074 I< 0.060 1·
1,4-Dichlorobenzene I 0.050 I a.so I< o.oso I< 0.074 . I.< 0.060 I
Dichlorodifluoromethane I 0.10 I 1.0 ]< 0,10 I< 0.15 I< 0.12 1
1,1-Dichloroethane I 0.050 I 0.50 I< 0.050 I< 0.074 I< 0.060 1
1,2-Dichloroeth_ane I 0.050 I 0.50 I< 0.050 I< 0.074 I< 0.060 ]
1,1-Dichloroethene I 0.050 J a.so I< o.oso I< 0.074 I< 0.060 I
cis-1,2-Dichloroethene I 0.050 I 0.50 I< 0.050 I< 0.074 ! 0.063 JI
trane-1,2-Dichloroethene I o.oso I o.so I< o.aso I< 0.074 I< 0.060 I __________________________ !
ALL COMPOUNDS EXPRESSED IN MILLIGRAMS/KILOGRAM DRY UNLESS OTHERWISE NOTED.
ALL NON-DETECT VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLECT DILtTI'IONS/DRY WEIGHT/SAMPLE WEIGHT).
SEE AITACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
227 French Landing Drive Nashville, Tennessee 37228 615-345-1115 FAX [phone]
r '--
Eckenfelder Laboratory, LLC
Client: FCX #18895.006
Date Reported: 06/28/00
I ECKENFELDER SAMPLE NUMBER I MBLK0608 10006030-01 100050~0-02 I
1----------------------------------------------1-----------1-----------1-----------1 I DATE SAMPLED I NA I 06/06/00 I 06/06/00 I
·· I DATE RECEIVED I NA I 06/07/00 I 06/07/00 I
I DATE ANALYZED I 06/11/00 I 06/11/00 I 06/11/00 I
1----------------------------------------------I-----------I-----------I---_-------1
I I M.BLANK IMP-10 10.5 I MP-10 I
I CLIENT SAMPLE DESCRIPTION I I I 31 ft. I
I I I I I
1----------------------------------------------1-----------1-----------1-----------1 I VOLATILE ORGANICS I I I I I I
I BY USEPA METHOD 8260 I MDL I EQL I CONC I CONC ! CONC [
1----------------------------------------------1-----------1-----------1-----------1 I l,2-Dichloropropana I o.oso I a.so ]< o.oso I< 0.074 I< 0.060 I
I cia-1,3-Dichloropropene I o.oso I a.so ]< o.oso I< 0.074 I< 0.060 I
trana-1,3-Dichloropropene I o.oso I a.so l< o.oso I< 0.074 I< 0.060 l
Ethylbenzene I o.oso I a.so I< o.oso I< 0.074 I< 0.060 I
2-He,;,:anone I 0.10 I 1.0 I< 0.10 I< 0,15 I< 0.12 I
Methylene chloride [ O. 050 I O. 50 I< O. 050 I< O. 074 [ < O. 060 I
4-Methyl-2-pentanone I 0.10 j 1.0 [< 0.10 I< 0,15 !< 0.12 f
styrene I o.oso I a.so I< o.oso I< 0.074 l< o.oso I
1,1,2,2-Tetrachloroethane l o.oso I a.so I< o.oso I< 0.074 l< 0.060 I
Tetrachloroethene 1 0.050 I o.so I< 0.050 I 2.8 l 5.5 I
Toluene I o.oso I 0.50 I< o.oso I< 0.074 I< 0.060 I
1,1,1-Trichloroethane I o.oso I a.so I< 0.050 I< 0.074 I< 0.060 I
1,1,2-Trichloroethane I o.oso I a.so l< 0.050 I< 0.074 I< 0.060 1
Trichloroethane I o. oso I o. so I< o. a.so I< o. 074 I< o. 060 I
Trichlorofluoromethane I 0.10 I 1.0 I< 0.10 I< 0,15 I< 0.12 I
Vinyl acetate I 0.25 j 2.5 I< 0,25 I< 0.37 I< 0.30 I
Vinyl chloride I 0.10 ] 1.0 I< 0.10 I< 0.15 I< 0.12 I
Xylene(total) I o.oso I a.so I< o.oso I< 0.074 J< 0.060 I
---------------------~----I
ALL COMPOUNDS EXPRESSED IN MILLIGRAMS/KILOGRAM DRY UNLESS OTHERWISE NOTED.
ALL NON-DETECT VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLECT DILUTIONS/DRY WEIGHT/SAMPLE WEIGHT).
SEE ATTACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
Eckenfelder }'~oratory,
Y.Ul0.ce::::
D. Rick Davis
Vice President
LLC
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'\:_,
ANALYTICAL REPORT TERMS AND QUALIFIERS (GC/MS)
MDL: The method detection limit (MDL) is defined as the minimum
concentration of a substance that can be measured and reported with
99% confidence that the analyte concentration is greater than zero. The ·
MDL is determined from analysis of a sample containing the analyte in a
given matrix.
EQL: The estimated quantitation limit (EQL) is defined as the estimated
concentration above which quantitative results can be obtained with a
. specific degree of confidence. Eckenfelder Laboratory, LLC. defines the
EQL to be ten times the MDL.
B: The presence of a "B" to the right of an analytical value indicates that
this compound was also detected in the method blank and the data
should be interpreted with caution. One should consider the possibility
that the correct sample result might be less than the reported result and,
perhaps, zero.
D: When a sample (or sample extract) is rerun diluted because one of the
compound concentrations exceeded the highest concentration range for
the standard curve, all of the values obtained in the dilution run will be
flagged with a "D".
E: · The concentration for any compound found which exceeds the highest
concentration level on the standard curve for that compound will be
flagged with an "E". Usually the sample will be rerun at a dilution to
quantitate the flagged compound.
J: The presence of a "J" to the right of an analytical result indicates that the
reported result is estimated. The mass spectral data pass the
identification criteria showing that the compound is present, but the
calculated result is less than the EQL. One should feel confident that
the result is greater than zero and less than the EQL.
l.~RTS\ART&QLT.DOC
Client: FCX #18895.006
Date Reported: 06/29/00
~
Eckenfelder
Laborato'"¼ LLC
I ECKENFELDER SAMPLE NUMBER I MBLK6043 I 0006043-01 j
1----------------------------------------------1-----------1-----------1 I DATE SAMPLED, I NA I 06/07/00 I
'· I DATE RECEIVED I NA I 06/08/00 I
I DATE ANALYZED . I 06/12/00 I 06/12/00 I
1· ---------------------------------------------1-----------I-----------I I I M.BLANK I MP-l3 3 I
I CLIENT SAMPLE DESCRIPTION I I ,.s ft. I
I . · I · ·· I· . ·.·· · . ·. I
1----------------------------. ----------. --. ---1 ---·-------1 · __ · ----·_ · 1
I VOLATILE ORGANICS I I I I I
I BY USEPA METilOD B260 1 MDL I EQL I CONC I CONC I
1----------------------------------------------I-----------I ·----------1
[ Acetone J 0.25 I ::z.s I< 0.25 I l.5 JI
I Benzene ] o.oso I a.so I< o.oso I< 0.070 I
I Bromodichloromothane I 0.050 I 0.50 1< 0.050 J< 0.070 I
I Bromoform I o.oso I a.so I< o.oso I< 0.010 I
I Bromomathane I 0.10 I LO J< 0.10 ]< 0.14 I
I 2-Butanone I a.so I s.o I< a.so I< 0.10 I
I carbon disulfide I o.oso I a.so I< o.oso I< 0.010 l
I carbon tetrachloride I o.oso I a.so I< o.oso I< 0.010 I
\ Chlorobenzene l o.oso I a.so I< o.oso I< 0.010 I
I Chloroethane l 0.10 I 1.0 l< 0.10 I< 0.14 I
I Chloroform. I o.oso ] a.so I< o.oso I< 0.010 I
I Chloromethane I 0.10 I LO I< 0.10 I< 0.14 I
I Dibromochloromethane I o.oso I a.so I< o.oso l< 0.010 I
] l,2-Dichlorobenzene I o.oso I a.so I< O.OSO I< 0.070 I
I 1,3-Dichlor~enzene I o.o5o I a.so I< o.oso I< 0.070 I
I 1,4-Dichlorobenzane I o.oso I a.so I< o.oso I< 0.070 ]
I Dichlorodifluoromethane I Q.10 I 1.0 I< 0.10 I< 0.14 I
I 1,1-Dichloroethane I 0.050 I o.so I< O.OSO I< 0.070 I
I 1,2-Dichloroethane ] o.oso I a.so !< o.oso I< 0,070 [
j 1,1-Dichloroethene I o.oso ] a.so I< o.oso I< 0.070 I
1. cia-1,2-Dichloraethene I 0.050 I a.so I< 0.050 I 0.093 Jj
I trana-1,2-Dichloroethene I o.a5o I a.so I< o.oso I< 0.010 I
1----------------~-I
ALL COMPOUNDS EXPRESSED IN MILLIGRAMS/KILOGRAM DRY UNLESS OTHERWISE NOTED.
ALL NON-DETECT VALUES ARE· REPORI'ED AS <MDL (MODIFIED TO REFLECT DILU!IONS/DRY WEIGHT/SAMPLE. WEIGHT),
SEE AITACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
227 French Landing Drive Nashville, Tennessee 37228 615-345-1115 FAX [phone]
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Eckenfelder Laboratory, LLC
Client: FCX #18895.006
Date Reported: 06/29/00
I ECKENFELDER SAMPLE NUMBER I MBLK6043 j 00060-43-01 I
1------· ---------------------------------------1-----------1-----------1
I DATE SAMPLED I NA I 06/07/00 I
.. I· DATE RECEIVED I NA I 06/08/00 I
I DATE ANALYZED I 06/12/00 I 06/12/00 I
1----------------------------------------------1-----------1-----------1 I I M.BLANK I MP-13 3 I
I CLIENT SAMPLE DESCRIPTION I I s.s ft. I
I · I .. , · l . I
1-----. ------------------------------------. -.. I---. ___ --1-----------1
I VOLATILE ORGANICS I I I I I
I BY USEPA METHOD 8260 I MDL I EQL I CONC j CONC j
1----------------------------------------------1-----------1-----------1 I 1,2-Dichloropropano I o.oso I a.so I< o.oso I< 0.010 I
] cia-1,3-Dichloropropene I o.oso I a.so I< o.oso [< 0.070 I
I trans-1,3-Dichloropropeno I o.oso I a.so I< o.oso I< 0.070 I
I Ethylbenzene I o.oso I a.so I< o.oso I< o.070 l
I 2-Hwtanone · I 0.10 I 1.0 I< 0.10 I< 0.14 I
I Methylene chloride I o.aso I a.so I< o.oso I 0.073 JI
I 4-Methyl-2-pentanone I 0.10. [ 1.0 I< 0.10 I< 0.14 I
I Styrene I o.oso I a.so I< o.oso I< 0.010 l
I 1,1,2,2-Tetrachloroethane I 0.050 1 a.so I< 0.050 I< 0.07~ I
I Tetrachloroathena I 0.050 I a.so I< 0.050 I 36 I
I Toluene I 0.050 I 0.50 I< o.oso I< 0.070 I
I 1,1,1-Trichloroethane ] 0.050 I a.so I< 0.050 I< 0.070 I
I 1,1,2-Trichloroetbane ] 0.050 [ 0.50 I< 0.050 J< 0.070 I
I Trichloroethene I 0.050 I a.so I< 0,050 I 0.010 Jj
I Trichlorofluoromethan• I 0.10 ] 1.0 I< 0.10 I< 0.14 I
I Vinyl.acetate I 0.25 I 2.5 I< 0.25 I< 0.35 I
I Vinyl chloride I 0,10 [ 1.0 I< 0.10 1< 0.14 I
I Xylene(total) I o.oso I a.so I 0.053 JI< 0.010 I
1 ___________________ 1
ALL COMPOUNDS EXPRESSED IN MILLIGRAMS/KILCGRAM DRY UNLESS OI'HERWISE NOTED.
ALL NON-DETECT VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLECT DILU!IONS/DRY WEIGHT/SAMPLE WEIGHT).
SEE AITACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
Ecke der Laboratory, LLC
D. D. Rick a~"""'"'-
Vice President
,,
MDL:
EQL:
8:
D:
E:
J:
ANALYTICAL REPORT TERMS AND QUALIFIERS (GC/MS)
The method detection limit (MDL) is defined as the minimum
concentration of a substance that can be measured and reported with
99% confidence that the analyte concentration is greater than zero. The
MDL is determined from analysis of a sample containing the analyte in a
given matrix.
The estimated quantitation limit (EQL) is defined as the estimated
concentration above which quantitative results can be obtained with a
specific degree of confidence. Eckenfelder Laboratory, LLC. defines the
EQL to be ten times the MDL.
The presence of a •s• to the right of an analytical value indicates that
this compound was also detected in the method blank and the data
should be interpreted with caution. One should consider the possibility
that the correct sample result might be less than the reported result and,
perhaps, zero.
When a sample (or sample extract) is rerun diluted because one of the
compound concentrations exceeded the highest concentration range for
the standard curve, all of the values obtained in the dilution run will be
flagged with a "D".
The concentration for any compound found which exceeds the highest
concentration level on the standard curve for that compound will be
flagged with an "E". Usually the sample will be rerun at a dilution to
quantitate the flagged compound ..
The presence of a "J" to the right of an analytical result indicates that the
reported result is estimated. The mass spectral data pass the
identification criteria showing that the compound is present, but the
calculated result is less than the EQL. One should feel confident that
the result is greater than zero and less than the EQL.
L:\REPORTS\ART&QLT.DOC
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--------------------Eckcnfcldcr Laboratory,._ ~C Chain of Custody Record
Send Results lo: Send Invoice To:
Name ~" ,:ri 5 Name
Compau;~;:~ -stCa-kfr,;e/( Compa-ny _______ _
Address zi3;--f-t:<0:l~ l;_Mddre.5s ________ _
City & State /4.~b,'/I-=.-IN City & State --------
Phone Gl5-Z55-Zz8p; Phone _________ _
Fax 1£,15-2.5 Co -R,3,3;:;,__ Purchase Order
/66CfS,u0~,
Project No./Name Fc.;,z. OLL.2) Rf-'\
Dale
Sam led
Time Comp./ Sample Location/Description
Grab
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3.8, I
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Sample
Matrix
REMARKS
• Signature required to ensure validity
·1 L... s c,.J --z.. ,.,,, qr iu.ol o" k
e-,,~co<:c.. "'""-r''"'::l ::d,.~_,\d
Le. sw-/ ,GhCl-,
N° 214 O 0
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Page _J_ of_/_
Cooler No. _j_ of _J_
Date Shipped 5 -18-00
Shipped By ~F~J=_><-~----
d
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H-rontact Lab)
3
/989'.S-: 0/cL
Project No./Name Fi
Time
Eckcnfcl<ler Laboratory, ~ .:: Chain of Custody Record
Send Results to: Send Invoice To:
Name &tu~~ Name
Companyt~~:t:A Company ________ _
Address __ _..,,_~--=-'~e--'--'r,,,_.,:...___"'-"--U,",Address
City & State 1---'½h.-v• ((,z,, }zC1/ City & State _______ _
Phone ___________ Phone __________ _
Fax Purchase Order ------------
_ Comp./ Sample Location/Description Sample
Matrix Grab
REMARKS
* Signature required to ensure validity
N~ , 2 l 3 9 9
Details:
Page __ of __
Cooler No. of
Date Shipped ______ _
Shipped By _______ _
Turnaround --------(Std. turn unless noted othcrwise{There
a surcharge for RUSH-contact Lab)
No.of
- -.......... :. --·--

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.. --.. .. --N~ 2 l J 9 8
I B 61 > Q O I;,.__
Project No./Name R)( {)Ll3
CompJ
Grab
Eckcnfeldcr Laboratory, l Chain of Custody Record
Send Results to: Send Invoice To:
Name G ~ {,,l,.,..-,:,f,,v-5 Name c;;. ry {;["':',)st,)...p
OJmpany B~ ~t:;)Vve// OJmpany ______ _
Address 2.-Z..'r F,..,,,__J,,__ ~IN, Address _________ _
City & State Af,,d,,.u, '//e, ~ City & State _______ _
Phone 4215-w5"°-,2_2Bf3 Phone _________ _
Fax____________ Purchase Order
Sample Location/Description.
,.
Sample
Matrix
-
REMARKS
Field
Coad.
Voe..
\)cc_
* Signature required to ensure validity
Details:
by: (Sign•
A
Eckcnfeldcr Laboratory, L
Send Results to:
Company .1-.-L.:=-~---,--,---,t--
Address ...t2sb,f:;._'.'::::µ""""~/..,,:;dJ~
City & Slate LLa:2<!2..l,:~..1..lf4-"lL'.=:::.
Phone ,:e,s+-'-/Z.o Fax ___________ _
0
; Chain of Custody Record
Send Invoice To:
Name ----"'c;;""--'':e~§>--'=C~b"'-'-·~~~'-=L./=--
Company _1.;;t,,.,c...----==· =:::_ ___ ~
Address _________ _
City & Slate _______ _
Phone _________ _
Purchase Order
-oe,_ -
-----t/00
• Signature required to ensure validity
Received By: (Signaturn)
'l'<)t~ Otdot No./'tiin1p ('4'):'. -' ' '' \ -, ' '' . ' , .
A ,._;__ 1tflC> t'lb ,.,,,j.. ':, o~
/9 B pp........-.
~q' ?1b -::. I 0-s-'y~r
:i { p I b ~ ,;a~ ft'....-
Details:
Page_/ _of_/_
Cooler No. l of I
Date Shipped > -z;:, -oO
Shipped By _6L,QeJJ"'--'-, _:_..,c,_ ____ _
ed otherwise/There
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--. ---• ·•-•--~ ., ~,.., "r"• , "'" ~,.,,,
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O!Jbl o/1-J--,?-S:.. ~"'q_--------=-~----11--,""'--=--___.: ---;-/-,-9 -o75_:-,,-Z,,~-1•~-.•
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--, ----~,~2J B8/ fl '"'"'Y ✓;,.J,t~C<>i~-,J'-j~-,-___s;~·•=~~l--dH~c=--.5-,,__-_.5, _ _;;0_ ~ -
c /0 [1 ClJI ::::_a ~ F ¢J) ct:_,=, ,,-Lc.__ ___ W._8_(1 cw-A 'l-S 1>0 _ •
h ~'-F·,,,,j?+----:)0[1, /_to<; //-, 6-dl-7 ..5-SOI =---h2-S<i_o~
-h--.mr•,,,,J; -+ N{) 1 _'".'> cff s•,: b-dR c?oic/ O0-nc-3;;--ic-1~.,
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____!___ ______________ , ,,
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-flaos-z3o
Eckcnfclder Laboratory, LLC Chain of Custody Record
Send Results lo: Send Invoice To:
Na me f@;12 6 ~ ( ).___.,;_ ,'f-:r,,_____,, Name (Q, c,/.___,,...,:_,-
Company 5 C ✓ Company ________ _
Address ' Address City & Slale,,t'.-£ v,'--0,.{le .. 711) City & Sla_l_e _______ _
Phone ___________ Phone __________ _
Fax Purchase Order ------------
/ :, [-iy 0, OCJ6
Project No./Namc ~
N~ 216 6 5
Details:
Page_j__ofL
Cooler No. _J__ of _L
Date Shipped 6-<,,,, ~
Shipped By ttEdl'/
f!ffi.qIJ!M\Sfillf} Time Comp./ Sample Location/Description Sample
:ttf(J-:".·:·_lfifff).,,,)t,t-: --~-+---+--G_ra_b-+-----------+-~M-'--a!_ri_x-+~='-'--+---+--------------+-==cc.-
C ,JI
Date/Time REMARKS
* Signc1ture required to ensure validity
Received By: (Signature)
Received I3y: (Signature)
----·-----·---..
;f3895-,ov0
Projecf No./Name Fa 00{3
lime
Eckcnfeldc1· Laboratory, LLC Chain of Custody Record
Send Results to:
Name C -· c.lL~0,~-c,VVS
Company,_._ fi2i~t-~L==---,---r---,o------
Addrcss &7-2: f=k~
City & State~ /4_~"'-='-~h=u-=•'_/l="=~riJI~~--:;;;,-
Phonc -----------Fax ------------
Sample Loc::ation/Description Sample
Matrix
"'
Send Invoice To:
Company
Address ----------City & State ________ _
Phone -----------Purchase Order
s· nature).
Field
Cond.
-----Joe_,.,, --......---
..z.-------
Vo
REMARKS
Received By: (Signature)
-----N~ 214 5 8
Delilils:
Page_j_or_{_
Cooler No. __l__ of_(_
Date Shipped fo-'r-oc:>
Shipped By b¥)_ :X,
Turnaround
_ tur nless noted otherwise/There
-....-1~a surcharge for RUSH-contact Lab)
No.of
Bottles
L-f
cl-
c9.-
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APPENDIXC
VAPOR voe ANALYTICAL LABORATORY REPORTS
\ \BCNSH03\PROJECTS\PROJ\ 18895\ 18895.0 I 5\APPcvr .doc
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Client: FCX #18895.012
Date Reported: 09/18/00
·--
Eckenfelder
Laboratory, LLC
I ECKENFELDER SAMPLE NUMBER I VlBLK0831 0008180-01**0008180-02 1oooe1ao-03
1----------------------------------------------I---------------------------------1-----------
I DATE SAMPLED I NA 08/29/00 08/29/00 I 08/29/00
I DATE RECEIVED I NA 08/30/00 08/30/00 I 08/30/00
I DATE ANALYZED I 08/31/00 09/31/00 08/31/00 I 08/31/00
----------------------------------------------1---------------------------------1-----------
I M. BLANK EW-lOA EW-lA I EW-3A
CLIENT SAMPLE DESCRIPTION I I
I I
----------------------------------------------1---------------------------------1-----------
VOLATILE ORGANICS I I I I
BY USEPA METHOD 8260 I MDL I EQL I CONC CONC CONC I CONC
---------------------------------------------\---------------------------------\-----------
[0008180-04 I
-----------1
08/29/00 I
08/30/00 I
08/31/00 I
-----------1
EW-BA I
I
I
-----------1
I
CONC I
-----------\
Acetone 5.0 50 I 16 JI 5.9 JBI 21 JB\ 21 JBI 27 JBI
Benzene 1.0 10 \< 1.0 I< 0.20 I< 1.0 I< 1.0 I< 1.0 I
Bromod1chloromethane 1. 0 10 I< 1.0 I< 0.20 I< 1.0 I< 1.0 I< 1.0 I
Bromoform 1.0 10 I< 1.0 I< 0.20 I< 1.0 I< 1.0 I< 1.0 I
Bromomethane 3.0 30 < 3.0 I< 0.60 I< 3.0 I< 3.0 1, 3.0 I
2-Butanone 10 100 < 10 I< 2.0 1, 10 1, 10 1, 10 I
Carbon disulfide 1.0 10 < 1.0 1, 0.20 1, 1.0 1, 1.0 1, 1. 0 I
carbon t et rachl ori de 1.0 10 < 1 . 0 I 0.30 JI' 1.0 1, 1.0 I 11 I
Chlorobenzene 1.0 10 < 1.0 I' 0.20 I< 1.0 I< 1.0 1, 1. 0 I
Chloroethane ,.o 20 < 2.0 1, 0.40 1, 2.0 1, 2 .0 1, 2.0 I
Chloroform 1.0 10 < 1.0 I 0.41 JI 2.0 JI 2.3 J 11 I
Chloromothane 2.0 20 < ,.o I< 0.40 1, 2.0 1, 2 .o ' 2.0 .1
Dibromochloromethane 1. 0 10 < 1.0 1, 0.20 1, 1.0 1, 1.0 < 1.0 I
1,2-Dichlorobenzene 1.0 10 < 1.0 1, 0.20 1, 1.0 1, 1.0 < 1.0 I
1,3-D1chloroben2ene 1.0 10 < 1.0 1, 0.20 1, 1.0 1, .o < 1.0 I
1,4-Dichlorobenzene 1.0 10 < 1.0 1, 0.20. 1, 1.0 1, 1.0 < 1. 0 I
Dlchlorodifluoromcthane 2.0 20 < 2.0 1, 0.40 1, 2.0 I' 2.0 < 2.0 I
1,1-Dichloroethane 1.0 10 < 1.0 1, 0.20 1, 1.0 1, 1.0 < 1. 0 I
l,2-01chloroethane 1.0 10 I< 1.0 1, 0.20 1, 1.0 I' 1.0 < 1.0 I
1,1-Dichloroethcne 1.0 10 1, 1.0 1, 0.20 1, 1.0 1, 1.0 < 1.0 I
cis-1,2-Dichloroethene 1.0 10 1, 1.0 I 1. 2 JI 74 I 68 25 I
trans-1,2-Dichloroethene 1.0 10 1, 1.0 1, 0.20 1, 1.0 1, 1.0 < 1 . 0 I
I
ALL COMPOUNDS EXPRESSED IN MICROGRAMS/LITER (AIR).
ALL NON-DETECT VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLECT DILUTIONS/SAMPLE VOLUME).
SEE ATTACHED PAGE F'OR DEFINITIONS OF TERMS ANO QUALIFIERS.
**•ALL DETECTION LIMITS REFLECT A XS CONCENTRATION DUE TO ANALYZING 25ML OF SAMPLE.
227 French Landing Drive Nashville, Tennessee 37228 615-345-1115 FAX [phone]
Eckenfelder Laboratory, LLC
Client: FCX #18895.012
Date Reported: 09/18/00
I ECKENFELDER SAMPLE NUMBER I V1BLK0831 0008180-01 **0008180-02 I 0008180-03 I 0008180-04 I
l----------------------------------------------1----------------------l-----------1-----------1-----------1
j DATE SAMPLED I NA 08/29/00 I 08/29/00 [ 08/29/00 I 08/29/00 I
I DATE RECEIVED j NA 08/30/00 I 08/30/00 / 08/30/00 j 08/30/00 )
I DATE ANALYZED j 08/31/00 08/31/00 I 08/31/00 j 08/31/00 I 08/31/00 I
l----------------------------------------------1 ----------------------l-----------1-----------1-----------1
I I M.BLANK EW-lOA I EW-lA j EW-3A I EW-BA J
I CLIENT SAMPLE DESCRIPTION j I I I I
I I I I I I
l----------------------------------------------1----------------------l-----------1-----------1-----------1
I VOLATILE ORGANICS I I I I I I I
I BY USEPA METHOD 8260 I MDL I EQL I CONC CONC I CONC I CONC I CONC I
1---------------------------------------------1----------------------1-----------1-----------1 -----------1
I 1,2-Dichloropropane 1,0 I 10 I< 1.0 < 0.20 I 2.5 JI 4.6 JI 1.2 JI
cia-l,J-D1chloropropene 1.0 ! 10 I< 1.0 < 0.20 I< 1.0 I< 1.0 I< 1.0 I
trane-1,3-Dichloropropene 1.0 I 10 I< 1.0 < 0.20 I< 1.0 I< 1.0 I< 1,0 I
Ethylbonzene 1.0 I 10 I< 1.0 I< 0,20 I< 1,0 I< 1.0 I< 1,0 I
2-Hexanone 2 .o 20 I, I 2.0 ' 0.40 1, 2.0 1, 2.0 1, 2.0
Methylene chloride 1.0 10 I, I 1.0 0.47 JI' I. 0 1, I . 0 1, 1.0
4-Methyl-2-pentanone 2.0 20 I,· I 2.0 ' 0.40 I' 2.0 I' 2 .o I' 2.0
Styrene 1.0 10 I, I 1.0 ' 0.20 1, 1.0 I' 1.0 1, 1.0
1,1,2,2-Tetrachlorocthanc 1.0 10 I, I 1. 0 ' 0.20 1, 1.0 I' 1.0 1, 1.0
Tetrachloroethene• 1.0 10 I, I 1.0 720 I 2600 I 4400 I 8200
Toluene 1.0 10 I, I 1.0 ' 0.20 1, 1.0 1, 1.0 1, 1. 0
1,1,1-Trichloroethane 1.0 10 I, I 1.0 ' 0.20 I' 1.0 I' 1.0 1, 1.0
1,1,2-Trichloroethane 1.0 10 I, I 1.0 ' 0.20 I, 1.0 1, 1.0 1, I. 0
Trichloroethene 1.0 10 I, I 1.0 4.6 I 77 I 85 I 31
Tr1chlorofluoromethane 2.0 20 I, JI 2.0 6.6 I 2.3 JI 3.2 JI 5.4
Vinyl acetate 5.0 50 I, I 5.0 ' 1.0 1, 5.0 1, 5.0 1, 5.0
Vinyl chloride 2.0 20 I, I 2.0 ' 0.40 1, 2.0 1, 2.0 1, 2.0
Xylene (total) 1.0 10 I, I 1.0 ' 0.20 1, 1.0 1, I. 0 1, l. O ____________________________________ I
ALL COMPOUNDS EXPRESSED IN MICR03RAMS/LITER (AIR).
ALL NON-DETECT VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLECT DILUTIONS/SAMPLE VOLUME).
SEE ATTACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
* ,. TETRAOIWROETHENE CONCENTRATIONS WERE CALCULATED USING ADDITIONAL HIGH CONCENTRATION CALIBRATION
STANDARDS ANALYZED AFTER THE SAMPLES. RESULTS MAY BE CONSIDERED AS ESTIMATED,
**,. ALL DETECTION LIMITS REFLECT A XS CONCENTRATION DUE TO ANALYZING 25ML OF SAMPLE.
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Eckenfelder Laboratory, LLC
Client: FCX #18895.012 Date Reported: 09/18/00
j ECKENFELDER SAMPLE NUMBER I 0008180-05 I l----------------------------------------------1----------
-
I

) DATE SAMPLED
j 08/29/00 / j DATE RECEIVED
j 08/30/00 / I DATE ANALYZED I 08/31/00 I 1----------------------------------------------I----------
-
I

I I EW-9A I I CLIENT SAMPLE DESCRIPTION I I I I I l----------------------------------------------1-------
-
-
-
-
I

I VOLATJ LE ORGANJCS I I I I I BY USEPA METHOD 8260 / MDL I EQL ) CONC / 1----------------------------------------------I----------
-
I

I Acetone I 5.0 I 50 / 24 JB/ I Benzene I 1.0 I 10 I< 1.0 I I Bromodichloromethane / 1.0 I 10 I< 1.0 J / Bromofonn / 1.0 / 10 /< 1.0 / / Bromomethanc I 3.0 I 30 I< 3.0 / I 2-Butanone J 10 j 100 I< 10 I I carbon disulfide I 1.0 I 10 I< 1.0 I J Carbon tetrachloride I 1.0 I 10 I 2.4 JI I Chlorobenzene I 1. 0 I 10 J < 1. 0 j / chloroet:hane I 2.0 / 20 /< 2.0 / I Chlorofonn I 1.0 / 10 / 2.1 J/ I Chlorornethane I 2.0 I 20 f< 2.0 f / Dibromochloromethane I 1. 0 I 10 I< 1 . 0 I / 1,2-Dichlorobenzene / 1.0 ) 10 /< 1.0 ) f l,3-D1chlorobenzene j 1.0 j 10 I< 1.0 / I 1,4-Dichlorobenzene I 1.0 I 10 /< 1.0 / I Dichlorod1fluoromechane I 2.0 I 20 I< 2.0 I I 1,1-Dichloroethano I 1.0 I 10 I< 1.0 I I 1,2-Dichloroethane I 1.0 I 10 I< 1.0 I I 1,1-Dichloroethene j 1.0 I 10 I< 1.0 I / cia-1,2-Dichloroethene 1.0 I 10 I 8.7 JI / trans-1,2-0ichloroothene 1.0 I 10 I< 1.0 I '-----------------' ALL COMPOUNDS EXPRESSED IN MICROGRAMS/LITER (AIR).
ALL NON-DETECT VALUES ARE REPORTED AS <:MDL (MODIFIED TO REFLECT DILl.lrIONS/SAMPLE VOLUME).
SEE ATTACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
-
Eckenfelder Laboratory, LLC
Client: FCX #18895.012
Date Reported: 09/18/00
] ECKENFELDER SAMPLE NUMBER I 0008180-05 [
l----------------------------------------------1-----------
I

[ DATE SAMPLED I 08/29/00 I
\ DATE RECEIVED
\ 08/30/00 \
I DATE ANALYZED I 08/31/00 I
1----------------------------------------------I-----------
I

I I EW-9A I
I CLIENT SAMPLE DESCRIPTION I I
I I I
l----------------------------------------------1-----------
I

I VOLATILE ORGANICS I I l l
I BY USEPA METHOD 8260 I MDL I EQL I CONC I
l----------------------------------------------1-----------I
I 1,2-Dichloropropane I 1.0 ! 10 [< 1.0 I
\ cie-1,3-Dichloropropene \ 1.0 \ 10 I< 1.0 I
I trane-1,3-Dichloropropene l 1.0 l 10 \< 1.0 \
\ Ethylbenzene ] 1.0 l 10 \< 1.0 \
\ 2-Hexanone I 2.0 I 20 [< 2.0 l
\ Methylene chloride I 1. O ! 10 I< 1. o I
\ 4-Methyl-2-pentanone \ 2.0 \ 20 [< 2,0 I
I Styrene \ 1.0 \ 10 I< 1.0 I
I 1,1,2,2-Tetrachloroethane \ 1.0 l 10 \< 1.0 I
I Tetrachloroethcne• I 1.0 I 10 \ 1600 I
I Toluene I 1.0 I 10 I< 1.0 \
I 1,1,1-Tnchloroethane I 1.0 I 10 I< 1.0 I
I 1,1,2-Trtchloroethane I 1.0 I 10 I< 1.0 I
I Trichloroethene I 1. 0 I 10 \ 13 I
\ Trichlorofluoromethane \ 2.0 \ 20 I 9.3 J\
\ Vinyl acetate I 5.0 I 50 I< 5.0 \
1 Vinyl chlonde I 2.0 I 20 I< 2.0 I
I Xylene(total) I 1.0 \ 10 I< 1.0 I
1 _________________
1
ALL COMPGUNDS EXPRESSED IN MICROORAMS/LlTER (AIR).
ALL NON-DETECT VALUES ARE REFORTED AS <MDL (MODIFIED TO REFLECT DILUTIONS/SAMPLE VOLUME).
SEE ATTACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
• • TETRACHLOROETHENE CONCENTRATIONS WERE CALCULATED USING ADDITIONAL HIGH CONCENTRATION CALIBRATION
STANDARDS ANALYZED AFTER THE SAMPLES. RESULTS MAY BE CONSIDERED AS ESTIMATED.
Eckenfelder Labora:j/\ LLC
c/J11tZ4'tl ~-1t~ r::;· _
D. Rick Davis ~ ;;,-...._
· Vice President
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ANALYTICAL REPORT TERMS AND QUALIFIERS (GC/MS)
MDL: The method detection limit (MDL) is defined as the minimum
concentration of a substance that can be measured and reported with
99% confidence that the analyte concentration is greater than zero. The
MDL is determined from analysis of a sample containing the analyte in a
given matrix.
EQL: The estimated quantitation limit (EQL) is defined as the estimated
concentration above which quantitative results can be obtained with a
specific degree of confidence. Eckenfelder Laboratory, LLC. defines the
EQL to be ten times the MDL.
B: The presence of a "B" to the right of an analytical value indicates that
this compound was also detected in the method blank and the data
should be interpreted with caution. One should consider the possibility
that the correct sample result might be less than the reported result and,
perhaps, zero.
D: When a sample (or sample extract) is rerun diluted because one of the
compound concentrations exceeded the highest concentration range for
the standard curve, all of the values obtained in the dilution run will be
flagged with a "D".
E: The concentration for any compound found which exceeds the highest
concentration level on the standard curve for that compound will be
flagged with an "E". Usually the sample will be rerun at a dilution to
quantitate the flagged compound.
J: The presence of a "J" to the right of an analytical result indicates that the
reported result is estimated. The mass spectral data pass the
identification criteria showing that the compound is present, but the
calculated result is less than the EQL. One should feel confident that
the result is greater than zero and less than the EQL.
L:\REPORTS\.ART&QLT.DOC
Eckenfelder Laboratory, LLC Chain of Custody Record
Send Results to:
1/1. 1 1;1 ,1 Name lf'lfdf•::,,,,. 1Pif4 lh,"f" _.
Company ;j, ,QJb \i-~i4J;
Address ----------City & State ________ _
Phone ----------Fax ------------
Send Invoice To:
Name /::ef,N !J.,,,z..
Company /,j,L/i-/)L ,;{;.,J,y.J
Address ----------City & State _______ _
Phone ----------Purchase Order
<!;,f:.r/r✓.2, ,¥, ,.,
&,£;'2-·
N~ ._ 21662
Details: T\) IA)• 3' <>-9-S -0 tl
Page_(_or_i__
Cooler No. _L_ of ;:>
Date Shipped .?/..z.;',0'-'
Shipped By .:CV~--==,---,----
Turnaround S:::-4; ... ,i~:-,,,.,-L
(Std. turn unless noted otherwise/There
may be a surcharne for RUSH-contact Lab)
lilll~l:l~j Sa~,"~ed lime arnplewcation/Description ~:~~ ! ANALYSJ · EQUJRFJ) ,,JJQ~~!IL111&111
E#t§fi-fui\r,*t{*'II'9/ -1.-'-' ~=, 'l,=v o.=,, ✓-) +A-,,.,-1-+G-;ti._,::;4=h'--t-J;:-ilo/----t1-?.A------,1--!f...:;A.:::. .. ' ✓=L,::,_· -+-"_===-+-_-= ____ =_:..+-U:-0<-..... --~-5----'------,.....::::::1=..:.
f'/J') bi,v'·-A I
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Date/rime Received By: (Signature) REMARKS
_.,___5, ~)_[ Q~ ~ _ -~---... ____ .. * Signature required to ensure validity
) -/Date/firne Received By: (Signature) t.'/. ''A ii I ,, £1, .·:;,,,. L/ , "" ,t; ,(4.,:., -, O,...iA(/1"'-(J,,✓ ,r .. , ... , ·--,~_ .• , . . I ,y2'!,-,._ l'J,'rJ' ,. JJ, :? /X/ i:;,.~tY,,------/tt.· I I) I. l--...!,.-.!-.::...,...~c--;c-"'-='---:----+--':~-::;:;:----t-;;--:--;~~--=----7 /,,rJ, «i,' 11 / • /I /. ,/4 V RellnquiShed 1:iy/(Signature) Date/fime Received By: (Signature) r/1/,C..,V o ..:;vp~ c,._,✓,;/ l_?<.:0:-"-JC' _
v' /
~ .. ) ~_; ---(.. ~ .• , <111!11 (_~
Eckenfelder Laboratory, LLC Chain of Custody Record
Send Results to:
11 /;1 I
Name ff.:;;"--1/! •e/t.:?e_.
Company Aicb'\~ J_-6/_!t.;,,//
Address
City & State ________ _
Phone ~----------Fax ------------
Send Invoice To:
Name K'c,,,1 {fu _,,__.
Company hit-1-Jn +,(!.r,j/4,,-,,//
Address ----------City & State ________ _
Phone -----------Purchase Order
Details:
Page_/_or__l__
Cooler No. Z-of -~
Date Shipped;?/ ~.-_,,63
Shipped By }-::;__/,,,e,,
Turnaround 5 ,i, ~,./~, ..-,i
(Std. turn unless noted otherwise{fhere
may be a surcharge for RUSH-contact Lab)
Project No./Name l't"!t;S, o; z/ftt:x L] ~/.,_,4-,.,,.,,,/ -r;> r
; ;
' I
I ,l/
Time
A->11
p,1r,
Sample Kit Prep'd by: (Signature)'i/PU
Relinquished by:,(Signature) ., ! ,,
,;
O,mp./ Sample Location/Description Sample
Grab Matrix _ ~0! ti!!!Yi!RmiH
----+--'==::..--t-'==-t-='-f---------F==--t
Field
OJnd.
ANALYSIS REo/lRED
c:;:.,; b Fi,/-·• f? I . A-r , ' -I
' ii 1,/ -. ;, ! 15 I I
i I ! ii:01-3B I I
I I I I
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Dateffime Received By: (Signature) REMARKS
d-3.;)''F.-t-·-----• Signature required to ensure validity
.Date/fime
ftfJJ:J I 1:q,
Received By: (Signature)
'Date/fime Received By: (Signature)
/1
Distribution: Original and yellow copies accompany sample shipment to laboratory~ Pink retained by samplers
Client: FCX #18895.012
Date Reported: 09/19/00
Eckenfelder
Laboratory, LLC
I ECKENFELDER SAMPLE NUMBER I v1BLKD901 ooos19s-01 )0000190-02 jooos190-03 1000019a-04 I
1----------------------------------------------1----------------------1----------------------1-----------1
I DATE SAMPLED I NA 09/30/00 I 08/30/00 08/30/00 I 08/30/00 I
1 □ATE RECEIVE□ 1 NA .oa;31;00 1 00131;00 os/31/00 1 oa/31/00 r
I DATE ANALYZED I 09/01/00 09/01/00 I 09/01/00 09/01/00 ! 09/01/00 I
I ----------------------------------------------1----------------------1----------------------1-----------1
I 1 M.BLANK EW-2A I EW-4A EW-SA I EW-6A I
I CLIENT SAMPLE DESCRIPTION l I I I
I I I I I
l----------------------------------------------1----------------------1------------'---------1-----------1
I VOLATILE ORGANICS I I I I I I
BY USEPA METHOD 8260 I MDL I EQL j CONC CONC I CONC CONC [ CONC I
----------------------------------------------1----------------------1----------------------1-----------1
Acetone
Benzene
Bromodichloramethane
Bromoform
Bromomethane
2-Butanone
Carbon disulfide
Carbon tetrachloride
Chlorobanzane
Chloroethane
Chloroform
Chloromethane
Dibrornochloromethane
1,2-Dichlorobenzene
l,3-D1chlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cia-1,2-Dichloroethene
trana-1,2-Dichloroethene
I 5.o I 50 I
I 1.0 I 10
1.0 I 10
1.0 / 10
3. a I Jo
10 I 100
1.0 I 10
1.0 j 10
1.0 I 10
2.0 I 20
1.0 I 10
2.0 1 20
1 . o I 10
1 . o I 10
1.0 1 10
1.0 1 10
2.0 I 20
1. o I 1 o
1.0 ! 10
1.0 I 10
1.0 I 10
1.0 I 10
18
< 1.0
< 1.0
< 1.0
< 3. O
< 10
< · 1 . 0
< 1.0
< 1.0
< 2. 0
< 1.0
< 2. 0
< 1 . 0
< 1 . 0
< 1 . 0
< 1.0
< 2. 0
< 1.0
< 1.0
< l.O
< 1.0
< 1.0
I<
I<
I<
I<
I
I<
I<
I
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14
1.0
1.0
1.0
3.0
10
1.0
3.7
1.0
2.0
4.2
2.0
1.0
1. 0
1.0
1.0
2.0
1.0
1.0
5.1
40
1.0
14
1.0
1.0
1.0
3.0
10
1.0
1.0
1.0
2.0
2.8
I< 2.0
l. 0
1.0
1.0
1.0
2.0
1.0
1.0
1.0
120
1.0
12
1.0
1.0
1.0
3.0
10
1.0
2.3
1.0
2.0
1. 3
2.0
1.0
1.0
1.0
1. 0
2 .o
1.0
1.0
2.2
13
1.0
14
1.0
1. 0
1.0
3.0
10
1.0
1.4
1. 0
2.0
1.0
2.0
1.0
1.0
1.0
1.0
2.0
1.0
1.0
1.0
4.2
1.0
JBI
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I ___________________________________ I
ALL COMPOUNDS EXPRESSED IN MICROGRAMS/LITER (AIR).
ALL NON-DETECT VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLECT DILUTIONS/SAMPLE VOLUME).
SEE ATTACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
227 French Landing Drive Nashville, Tennessee 37228 615-345-1115 FAX [phone]
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Eckenfelder Laboratory, LLC
Client: FCX #18895.012
Date Reported: 09/19/00
I ECKENFELDER SAMPLE NUMBER I VlBLK0901 0008198-01 10008198-02 1 □008198-03 IOOOB198-04 I
1----------------------------------------------I----------------------1-----------1-----------1 -----------1
I DATE SAMPLED I NA 08/30/00 I 08/30/00 I 08/30/00 I 08/30/00 I
j DATE RECEIVED I NA 08/31/00 I 08/31/00 I 08/31/00 I 08/31/00 I
DATE ANALYZED I 09/01/00 09/01/00 I 09/01/00 I 09/01/00 I 09/01/00 j
----------------------------------------------1----------------------1-----------1-----------1-----------1
I M.BLANK EW-2A I EW-4A I EW-SA j EW-6A I
CLIENT SAMPLE DESCRIPTION I I I I I
I I I I I
----------------------------------------------1----------------------1-----------1-----------1 -----------
VOLATILE ORGANICS 1 I I I I I
BY USEPA METHOD 8260 I MDL I EQL I CONC CONC I CONC I CONC I CONC
----------------------------------------------1 ----------------------1-----------1-----------1-----------
1,2-Dichloropropane
cia-l,3-D1chloropropene
trans-1,3-Dichloropropene
Ethylbenzene
2-Hexanone
Methylene chloride
4-Methyl-2-pentanone
Styrene
1,1,2,2-Tetrachloroethane
Tetrachloroethene•
Toluene
l,l,l-Tr1chloroethane
1,1,2-Tr1chloroethane
Trichloroethane
Tr1chlorofluoromethane
Vinyl acetate
Vinyl chloride
Xylene (total)
I 1.0 I 10 I< 1.0 2.1 JI 13 I 2. 1
I 1.0 I 10 I< 1.0 I< 1.0 I< 1.0 I< 1.0
I 1.0 _I 10 )< 1.0 I< 1.0 Jc 1.0 Jc 1.0
I 1.0 I 10 I< 1.0 I< 1.0 !c 1.0 I< 1.0
I 2.0 I 20 Jc 2.0 I< 2.0 le 2.0 I< 2.0
I 1.0 j 10 j 1.6 Jlc 1.0 !c 1.0 I< 1.0
I 2.0 I 20 le 2.0 I< 2.0 I< 2.0 I< 2.0
I 1.0 I 10 I< 1.0 I< 1.0 I< 1.0 I< 1.0
I 1.0 I 10 le 1.0 I< 1.0 Jc 1.0 le 1.0
I 1.0 I 10 I 2.1 JI 14000 I 4000 I 4300
I 1.0 I 10 le 1.0 ic 1.0 ic 1.0 le 1.0
I 1.0 I 10 le 1.0. le 1.0 /c 1.0 le 1.0
I 1.0 I 10 le 1.0 le 1.0 ic 1.0 Jc 1.0
I 1.0 I 10 le 1.0 I 48 I 150 I 25
I 2.0 I 20 I< 2.0 Jc 2.0 /c 2.0 Jc 2.0
I 5.0 I 50 I< 5.0 le 5.0 I< s.o le 5.0
I 2.0 I 20 ic 2.0 le 2.0 le 2.0 le 2.0
I 1. o I 10 l c 1. o I c 1. o I c 1. o I c 1. o
ALL COMPOUNDS EXPRESSED IN MICROGRAMS/LITER (AIR).
ALL NON-DETECT VALUES ARE REPORTED AS cMDL (MODIFIED TO REFLECT DILt.rrIONS/SAMPLE VOLUME).
SEE ATTACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
J < 1. 0
c 1 . 0
c 1. 0
c 1. 0
c 2.0
c 1. 0
< 2.0
c 1 . 0
< 1.0
3600
c 1 . 0
c 1. 0
c 1 . 0
11
c 2.0
c 5.0
2.0
1.0
• -TETRACHLOROETHENE CONCENTRATIONS WERE CALCULATED USING ADDITIONAL HIGH CONCENTRATION CALIBRATION
STANDARDS ANALYZED,AF"TER THE SAMPLES. RESULTS MAY BE CONSIDERED AS ESTIMATED.
Eckenfelder Laboratory, LLC
Client: FCX #18895.012
Date Reported: 09/19/00
I ECKENFELDER SAMPLE NUMBER 0008198-05 I
1---------------------------------------------------------!
DATE SAMPLED
DATE RECEIVED
DATE ANALYZED
CLIENT SAMPLE DESCRIPTION
VOLATILE ORGANICS
BY USEPA METHOD 8260
Acetone
Benzene
MDL
5.0
1.0
Bromodichloromethane 1.0
Bromoform
Bromomethane
2-Butanone
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
ChlorofoITn
Chloromothane
Dibromochloromethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
1.0
3.0
10
1.0
1.0
1.0
2.0
1.0
2.0
1.0
1.0
1.0
1.0
2.0
1.0
1.0
1.0
1.0
trans-1,2-Dichloroethene 1.0
EQL
50
10
10
10
30
100
10
10
10
20
10
20
10
10
10
10
20
10
10
10
10
10
oa/30/00 I
os/31/00 I
09/01/00 j
-----------1
EW-7A I
I
I
-----------!
I
CONC I
-----------1
18 JBI
' 1.0 I
' 1. 0 I
' 1.0 I
' 3.0 I
' 10 I
' 1.0 I
6.1 JI
' 1 . 0 I
' 2.0 I
3.0 JI
' 2.0 I
' 1.0 I
' 1. 0 I 1, 1. 0 I
1, 1.0 I
1, 2 .o I 1, 1.0 I
1, 1.0 I
1, 1.0 I
I 5.7 JI
1, 1.0 I
I
ALL COMPOUNDS EXPRESSED IN MICROORAMS/LITER (AIR),
ALL NON-DETECT VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLECT DILUTIONS/SAMPLE VOLUME).
SEE ATTACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
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Eckenfelder Laboratory, LLC
Client: FCX #18895.012
Date Reported: 09/19/00
I ECKENFELDER SAMPLE NUMBER IOOOB198-05 I
··1
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----------------------------------------------1-----------I
DATE SAMPLED
DATE RECEIVED
DATE ANALYZED
I 08/30/00 I
I 08/31/00 I
I 09/01/00 I
----------------------------------------------1-----------I
I EW-7A I
CLIENT SAMPLE DESCRIPTION I I
I I
----------------------------------------------1-----------I
VOLATILE ORGANICS I I I I
BY USEPA METHOD 8260 I MDL I EQL I CONC I
----------------------------------------------1-----------1
1,2-Dichloropropane
c1s-l,3-D1chloropropene
trana-1,3-Dichloroprapene
Ethylbenzene
2-Hcxanone
Methylene chloride
4-Methyl-2-pentanone
Styrene
1,1,2,2-Tetrachloroethane
Tetrachloroethenc*
Toluene
l,l,l-Tr1chloroethane
1,1,2-Trichloroethane
Trichloroethane
Trichlorofluoromothanc
Vinyl acetate
Vinyl chloride
Xylene (total)
I 1.0 10 I< 1.0 I
I 1.0 10 I< 1.0 I
I 1.0 10 I< 1.0 I
I 1.0 10 I< 1.0 I
I 2. o 20 I< 2. o I
I 1.0 10 )< 1.0 I
I 2.0 20 I< 2.0
I i.o
I i.o
I i.o
I i.o
I i.o
I 1.0
I i.o
I 2. o
I 5. o
I 2. o
I i.o
10
10
10
10
10
10
10
20
50
20
10
1,
1,
I
1.0
1.0
12000
1.0
1.0
1.0
20
2.0
5.0
1.0
I __________________ _
ALL COMPOUNDS EXPRESSED IN MICROGRAMS/LITER (AIR).
ALL NON-DETECT VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLECT DILllrIONS/SAMPLE VOLUME).
SEE ATTACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
• • TETRACHLOROETHENE CONCENTRATIONS WERE CALCULATED USING ADDITIONAL HIGH CONCENTRATION CALIBRATION
STANDARDS ANALYZED AFTER THE SAMPLES. RESULTS MAY BE CONSIDERED AS ESTIMATED.
Eckenfelder Labora/•
'7/ll({/t(7:,d h ..
D. Rick Davis
Vice President
y, LLC
ANALYTICAL REPORT TERMS AND QUALIFIERS (GC/MS)
MDL: The method detection limit (MDL) is defined as the minimum
concentration of a substance that can be measured and reported with
99% confidence that the analyte concentration is greater than zero. The
MDL is determined from analysis of a sample containing the analyte in a
given matrix.
EQL: The estimated quantitation limit (EQL) is defined as the estimated
concentration above which quantitative results can be obtained with a
specific degree of confidence. Eckenfelder Laboratory, LLC. defines the
EQL to be ten times the MDL.
B: The presence of a "B" to the right of an analytical value indicates that
this compound was also detected in the method blank and the data
should be interpreted with caution. One should consider the possibility
that the correct sample result might be less than the reported result and,
perhaps, zero.
D: When a sample (or sample extract) is rerun diluted because one of the
compound concentrations exceeded the highest concentration range for
the standard curve, all of the values obtained in the dilution run will be
flagged with a "D".
E: The concentration for any compound found which exceeds the highest
concentration level on the standard curve for that compound will be
flagged with an "E". Usually the sample will be rerun at a dilution to
quantitate the flagged compound.
J: The presence of a "J" to the right of an analytical result indicates that the
reported result is estimated. The mass spectral data pass the
identification criteria showing that the compound is present, but the
calculated result is less than the EQL. One should feel confident that
the result is greater than zero and less than the EQL.
L:\REPORTS\ART&QLT.DOC
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Relinquished by:'(Sigaature) ,
~--> ·c;;r -·:: ~ c;:;; =;'< ~J (->
Eckenfelder Laboratory,'•LLC Chain of Custody Record
Send Results to: Send Invoice To:
Name_~~~'~/=t=,/~;~,~~··-+"m~fm;~·e=t~~~?~e ; CJ Company _________ _ Company ________ _
Address _________ _ Address __________ _
City & State ________ _ City & State ________ _
Phone __________ _ Phone __________ _
Fax Purchase Order ------------
Sample Location/Description Sample
Matrix
, W-24 ~ .:.¥.A --,---I C. (✓ {} '_-;
.--4 I I\ ✓
A I
0A , I
i ;
A ii i . ,/ v ;/ I
Date/fime Received By: (Signature) REMARKS
, . Date{fime Received By: (Signature)
"t/._.;,/ 1'1•,i•) I //V ,..,_
' Date/fime Received By: (Signature)
* Signature required to ensure validity _ ,Q . r·"' /l-1.,!·,,.7
I I ,t/.') it · i _' / -:/ !./ili , -, ):;,u; 5 c<c> .a,.~"'J-
r. , .......
Details:
Page_/_of_{_
Cooler No. _j__ of ?-
Date Shipped ~ / .s ,; / ,.;cJ
Shipped By -'--1--",!'"'}-"-.-'"'~-_,_t ____ _
Turnaround Si-,,,,, -i,, /-i
(Std. turn unless n~ted otherwise/Ibere
may be a surcharge for RUSH-contact Lab)
Eckenfelder Laboratory, LLC Chain of Custody Record
Send Results to: Send Invoice To:
Name /Y/ CT(.'&. Meqld1ee-,_ Name __ ..,}c..(.:.' .. /'"-h'--()=c...Lt-"'1'"'t,.L--=.. __
Company ________ _ Company ________ _
Address _________ _ Address ----------City & State _______ _ City & State _______ _
Phone _________ _ Phone -----------Fax Purchase Order ------------
Details:
10'-<) -3'd_q-s,oo
N~ 22150
Page / of I
Cooler No. 2 of 2
Date Shipped ~ J rti/,:.,,..J
Shipped By -'1--':::'"',_""J ___ . ,.:.;;;,__)~· ____ _
Turnaround ,e:-·fv."',-L,"-L
(Std. turn unless noted otherwise/There
may be a surcharge for RUSH<0ntact Lab)
t~!i•v~ltQl!!im Time Comp./ Sample Location/Description Sample UIRED N<J.t,('!. _ •.·.•··•··••;·J·'•··~~iJ.!~. Bmt. iI.•.•.•.'.•.·•. FJJW!Wt· n '--'===-+--+-'=G:,:ra:,b:......_1------------+-"M"'a"'tn:.:,·x,_+-<=="'--,l--==-+------------~-Blii=i=--+ ·
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Sample Kit Prep'd by: (Signature) Date/fime Received By: (Signature) REMARKS
* Signature required to ensure validity
Date/fime
<f3J/ j -t 'OQ _/Vo ,.
Received By: (Signature)
Date/Time Received By: (Signature) h ,;1/ s ,;. s p1->-~//,
V .
I
'
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Client: FCX #18895.012
Date Reported: 09/19/00
Eckenfelder
Laborator"¼ LLC
I ECKENFELDER SAMPLE NUMBER I VlBLK0901 I 0009005-01 I 0009005-02 j 0009005-03 I
1----------------------------------------------1-----------1-----------1-----------1 -----------1
I DATE SAMPLED I NA I 08/31/00 I 08/31/00 I 08/31/00 I
I DATE RECEIVED I NA I 09/01/00 I 09/01/00 I 09/01/00 I
I DATE ANALYZED I 09/01/00 I 09/01/00 I 09/01/00 I 09/01/00 \
1----------------------------------------------1-----------1-----------1-----------1-----------1
I I M.BLANK I BL-lA j BL-2A I GAC-lA I
I CLIENT SAMPLE DESCRIPTION I I I I I
I I I I I I
1----------------------------------------------1-----------1-----------1-----------1-----------1
I VOLATILE ORGANICS I I I I I I I
I BY USEFA METHOD 8260 ) MDL j EQL I CONC I CONC I CONC I CONC [
1---------------------------------------------------------1-----------1-----------1-----------I
I Acetone s.o I so
I Benzene 1.0 I 10
I Bromod1chloromethane 1.0 I 10
I Bromoforrn 1 . O I 1 o
I Bromomethane 3.0 I 30
I 2-Butanone 10 I 100
1 Carbon disulfide 1.0 I 10
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromochloromethanc
l,2-D1chlorobenzene
1,3-Dichlorobenzene
1,4-D1chloroben2ene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
I
I
I
I
I
1.0 1 10
1 . o I 10
2 .o 1 20
1.0 1 10
2.0 I 20
1.0 1 10
1.0 1 10
1.0 1 10
1. o I 10
2.0 I 20
1.0 1 10
1.0 1 10
1. o I 10
1.0 I 10
1.0 1 10
18
l. 0
< 1.0
< 1.0
< 3. 0
< 10
< 1.0
< 1.0
< 1.0
< 2. 0
LO
< 2 .0
< 1.0
LO
LO
1.0
2.0
LO
l. 0
LO
l . O
l . O
J 12 JBI
< 1.0
< 1.0
< 1.0
< 3.0
< 10
< 1.0
2.2
< 1.0
< 2.0
2.8
2.0
LO
LO
LO
1.0
2.0
1.0
1.0
1.0
33
1.0
13
1.0
1.0
1.0
3.0
10
1.0
2.3
1.0
2.0
2.6
2.0
1.0
1.0
1.0
1.0
2.0
1.0
1.0
1.0
32
l. 0
12
l . 0
1.0
1.0
3.0
10
1.0
1.0
1.0
2.0
1.0
2.0
1.0
1.0
1. 0
1.0
2.0
1.0
1.0
1.0
1.0
1.0
JBI
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I ___________________________________ I
ALL COMPOUNDS EXPRESSED IN MICROGRAMS/LITER (AIR}.
ALL NON-DETECT VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLECT DILUTIONS/SAMPLE VOLUME).
SEE ATTACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
227 French Landing Drive Nash ville, Tennessee 37228 615-345-1115 FAX [phone]
Eckenfelder Laboratory, LLC
Client: FCX #18895.012
Date Reported: 09/19/00
I ECKENFELDER SAMPLE NUMBER V18LK0901 10009005-01 10009005-02 10009005-03 I
1---------------------------------------------------------1-----------1-----------1-----------I
I DATE SAMPLED NA I 08/31/00 f 08/31/00 I 08/31/00 I
I DATE RECEIVED NA I 09/01/00 [ 09/01/00 I 09/01/00 I
I DATE ANALYZED 09/01/00 I 09/01/00 I 09/01/00 / 09/01/00 I
1---------------------------------------------------------1-----------1-----------1-----------I
I M.BLANK I BL-lA I BL-2A I GAC-lA )
I CLIENT SAMPLE DESCRIPTION I I I I
I I I I I
1---------------------------------------------------------1-----------1-----------1-----------1
I VOLATILE ORGANICS I I I I I
I BY USEPA METHOD 8260 I MDL I EQL CONC I CONC I CONC I CCNC
1---------------------------------------------------------1-----------1-----------1-----------
l 1,2-Dichloropropane I 1.0 I 10 )< 1.0 I 2.7 JI 2.6
cis-1,3-Dichloropropene I 1.0 I 10 j< 1.0 I< 1.0 I< 1.0
trans-1,3-Dichloropropene J 1.0 10 I< 1.0 j< 1.0 I< 1,0
Ethylbenzene j 1.0 10 < 1.0 I< 1,0 )< 1.0
2-Hexanone j 2.0 20 < 2.0 I< 2.0 I< 2.0
Methylene chloride I 1.0 10 1.6 JI< 1.0 I< 1.0
4-Methyl-2-pentanonc I 2.0 20 < 2.0 I< 2.0 I< 2.0
Styrene \ 1.0 10 < 1.0 I< 1.0 I< 1.0
1,1,2,2-Tetrachloroethane I 1.0 10 < 1.0 I< 1.0 I< 1.0
Tetrachloroethene* I 1.0 10 2.1 JI 5600 I 5400
Toluene I 1.0 10 < 1.0 I< 1.0 I< 1.0
l,l,l-Tr1chloroethane
1,1,2-Tr1chloroethane
Trichlorocthene
Trichlorofluoromethane
Vinyl acetate
Vinyl chloride
XylenC! (total)
I i.o
I i.o
I i.o
I 2.0
I 5. o
I 2.0
I i.o
10 < 1.0
10 < 1.0
10 < 1.0
20 < 2.0
50 < 5.0
20 < 2.0
10
ALL COMPOUNDS EXPRESSED IN MICR08RAMS/LITER (AIR).
I<
I<
I
I<
1.0
1.0
42
2.0
5.0
2.0
1.0
I<
I<
I
I
1.0
1.0
41
2.7
5.0
2.0
1.0
1.0
1.0
1.0
1.0
2.0
1.0
2.0
1.0
1. 0
130
1.0
1.0
1.0
1.0
2.0
5.0
2.0
1.0
ALL NON-DETECT VALUES ARE REPORTED AS <MDL (MODIFIED TO REFLECT DILUTIONS/SAMPLE VOLUME).
SEE ATTACHED PAGE FOR DEFINITIONS OF TERMS AND QUALIFIERS.
* -TETRACHLOROETHENE CONCENTRATIONS WERE CALCULATED USING ADDITIONAL HIGH CONCENTRATION CALIBRATION
STANDARDS ANALYZED AFTER THE SAMPLES. RESULTS MAY BE CONSIDERED AS ESTIMATED.
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ANALYTICAL REPORT TERMS AND QUALIFIERS (GC/MS)
MDL: The method detection limit (MDL) is defined as the minimum
concentration of a substance that can be measured and reported with
99% confidence that the analyte concentration is greater than zero. The
MDL is determined from analysis of a sample containing the analyte in a
given matrix.
EQL: The estimated quantitation limit (EQL) is defined as the estimated
concentration above which quantitative results can be obtained with a
specific degree of confidence. Eckenfelder Laboratory, LLC. defines the
EQL to be ten times the MDL.
B: The presence of a "B" to the right of an analytical value indicates that
this compound was also detected in the method blank and the data
should be interpreted with caution. One should consider the possibility
that the correct sample result might be less than the reported result and,
perhaps, zero.
D: When a sample (or sample extract) is rerun diluted because one of the
compound concentrations exceeded the highest concentration range for
the standard curve, all of the values obtained in the dilution run will be
flagged with a "D".
E: The concentration for any compound found which exceeds the highest
concentration level on the standard curve for that compound will be
flagged with an "E". Usually the sample will be rerun at a dilution to
quantitate the flagged compound.
J: The presence of a "J" to the right of an analytical result indicates that the
reported result is estimated. The mass spectral data pass the
identification criteria showing that the compound is present, but the
calculated result is less than the EQL. One should feel confident that
the result is greater than zero and less than the EQL.
L:\REPORTS\ART&QLT.DOC
Project No./Name
Eckenfelder Laboratory, LLC Chain of Custody Record
Send Results to:
Name i/;/t,l,l<1. /J1-eg.f},ee.---'-'--====-=-,-,, =='--
Company _____ •:.; ____ _
Address _________ _
City & State ________ _
Phone __________ _
Fax ------------
Send Invoice To:
Company ________ _
Address __________ _
City & State _______ _
Phone-~---------
Purchase Order
Details:
Page_/_or_L
Cooler No. / of
Date Shipped >,--'/7,,/,;,U
Shipped By _·,-....,"'~;-,r,._·--=e'-';X'------
Tumaround ,""'\-f..-.wi,J,,,.J..
(Std. turn unless noted otherwise/Ibere
may be a surcharge for RUSH-contact Lab)
IJljllill Sa~t~ed Time ~:~': ANALYSIS REQ(,1IRED ~ li!i/1,~IY~!~il!filI !$-------~-+---+--'-'=-+-----------+--'-'='---!-'==~-t--'-''----!------------+-'==-
(,;; ,1 ,4,;i 0>;11, BL-i.-1
by: (Signature) --
Relinquished by: (Signature)
'll ;?/ ,£/ ~,/4'-'
Reiinquished by: (!'i/gnature)
'
f3L -zA
G.4 c-iA
Date/rime Received By: (Signature)
Received By: (Signature)
Date/fime Received By: (Signature)
--I
1
V
REMARKS
* Signature required to ensure validity
' • .-, // ,, /, .. , ,,, r.,<e:: /J.,~/0'1a,,'J /A,Jf, ,. . 1~x11> ~,, I •
/J\.~-e ,, ;; ·, ?1~ d,~' /;££U:"1)
-■-!I
Sample Kit Prep'd by: (Signature) •
----·_jll!Jil"' ---.... -~ ~i
Eckenfelder Laboratory, LLC Chain of Custody Record
Send Results to:
Name /V/ 0.1/01 Ill/ '3' ~Ae L
Cpmpany Arw1v..<:1-CdJk>Jf
Address _________ _
City & State ________ _
Phone _________ _
Fax ------------
Send Invoice To:
Company ________ _
Address _________ _
City & State _______ _
Phone _________ _
Purchase Order ______ _
0:impJ Samp e Location/Description Sample
Grab Matrix
Date/Time ----Received By: (Signature)
('
/ I
REMARKS
• Signature required to ensure validity
N~ 22152
Details: T•..:,-.3 •d-'i-S-o~
Page _J_ of _i _
Cooler No. ;:!.. of 2
Date Shipped :? /J//,tl
Shipped By _/,__-::c __ ;,"-.f~.,.f"'i.-_· ___ _
Turnaround ,:S::Ld u c t,,.,.J
(Std. tum unless noted otherwise/There
may be a surcharge for RUSH-contact Lab}
Received By: (Signature) U.~-=~3--...'i ba,:;.:s a.s btu~
Received By: (Signature) bhc-'/} ,1 h'Jf:; ,;~ /'r' L.-/