NCD003446721_20050705_Celeanse Corporation - Shelby Fiber_FRBCERCLA SAP QAPP_Monitored Natural Attenuation Demonstration Project Data Report for Quarterly Sampling Event 4 OU-1-OCR

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Post Office Box 273210
Tampa, FL 33688-32 I 0
[phone]
FAX [phone]
Mr. Kenneth Lucas
Remedial Project Manager
U.S. Environmental Protection
Agency, Region IV
61 Forsyth Street
Atlanta, GA 30303
Dear Mr. Lucas:
Kubal-Furr & Associates
Environmental Management Services
July 5, 2005
Post Office Box 8024 7
Simpsonville, SC 29680-0247
[phone]
FAX [phone]
On behalf of CNA Holdings, Inc., we are pleased to enclose two copies of the report entitled:
"Monitored Natural Attenuation Demonstration Project-Data Report for Quarterly Sampling
Event #4 (1st Quarter 2005)-Operable Unit 1-CNA Holdings, Inc.fficona-Shelby, North
Carolina." By way of this letter, we have also transmitted a copy of the report to Mr. David
Mattison with NCDENR for his review.
Please contact me at 813-265-2338, to discuss any questions you may have following your
review of this document.
Sincerely,
Kubal-Furr & Associates
df)!'--~
Jerry i/Kubal, P.G.
President
cc: Mr. David Mattison, NCDENR
Mr. Rick Ramirez, Celanese Americas
Ms. PEM Carter, Ticona-Shelby ESHA
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CNA Holdings, lnc./Ticona-Shelby, NC-MNA Data Report for Sampling Event #4 (Qi 2005) I Page i
Contents
Page
Acronyms/ Abbreviations ............................................................................................................................. iii
1.0 Introduction .......................................................................................................................................... 1
2.0 Work Performed .................................................................................................................................. y Z--
3.0 Discussion of Findings ........................................................................................................................ %' 5
3.1 Ground-Water Movement .......................................................................................................... 5 '.1
3.2 Ground-Water Quality ............................................................................................................... £" J
3.2.1 Data Quality Assessment ............................................................................................. % 4-
3.2.2 Discussion of Analytical Test Results ......................................................................... % 4-
4.0 Summary and Recommendations ........................................................................................................ 8
Table I.
Table 2.
Table 3.
Table 4.
Table 5.
Figure I.
Figure 2.
Figure 3.
Figure 4.
Figure 5.
Figure 6.
Tables
Water-Quality Data (Laboratory Parameters)-MNA Quarterly Sampling #4/Ql 2005
Water-Quality Data (Field Parameters)-MNA Quarterly Sampling #4/Ql 2005
MNA Screening Parameters-MNA Quarterly Sampling #4/Ql 2005
Comparison of Ethylene Glycol Concentrations vs. Total Organic Carbon Concentrations
Summary of Selected Natural Attenuation Indicator Parameters
Figures
Site Location Map-CNA Holdings, Inc./Ticona-Shelby, NC
Potentiometric Surface Map-Shallow Saprolite-February IO, 2005
Potentiometric Surface Map-Deep Saprolite/Upper Bedrock-February 10, 2005
Hydrogeologic Cross Section-February I 0, 2005
Anaerobic Biodegradation Screening Parameters-February 16-23, 2005
Ethylene Glycol Concentrations-February 16-23, 2005
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CNA Holdings, Inc./Ticona-Shelby, NC-MNA Data Report for Sampling Event #4 ( QI 2005) I Page ;;
Figure 7. Inferred Total Organic Carbon Distribution-February 16-23, 2005
Figure 8. Inferred Methane Distribution-February 16-23, 2005
Figure 9. Inferred Alkalinity (Total) Distribution-February I 6-23, 2005
Figure I 0. Inferred Manganese (Total) Distribution-February I 6-23, 2005
Figure 11. Inferred Ferrous Iron Distribution-February 16-23, 2005
Figure I 2. Inferred Nitrate Distribution-February I 6-23, 2005
Figure I 3. Inferred Sulfate Distribution-February I 6-23, 2005
Attachments
Attachment I. Analytical Data Package, Data Assessment Summary and Field Sampling Logs-MNA
Quarterly Sampling #4/QI 2005
Attachment 2. Time vs. Concentration Water-Quality Plots
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CNA Holdings, lnc./Ticona-Shelby, NC-MNA Data Report for Sampling Event #4 (Ql 2005) I Page iii
CERCLA
CFO
CNA
DENR
DO
EPA
mg/L
µg/L
MNA
NFG
NPL
NTUs
ORP
OU-I
SOPs
TOC
Acronyms/ Abbreviations
Comprehensive Environmental Response and Liability Act
Celanese Fiber Operations
CNA Holdings, Inc.
(North Carolina) Department of Environment and Natural Resources
Dissolved Oxygen
U.S. Environmental Protection Agency
Milligrams per Liter
Micrograms per Liter
Monitored Natural Attenuation
National Functional Guidelines (for organic/inorganic data review)
National Priorities List
Nephelometric Turbidity Units
Oxidation Reduction Potential
Operable Unit l
Standard Operating Procedures
Total Organic Carbon
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CNA Holdings, lnc./Ticona-Shelby, NC-MN A Data Report/or Sampling Event #4 (QI 2005) I Page I
1.0 Introduction
Ticona, an operating subsidiary of Celanese, owns and operates a polyester and engineering plastics
production facility in Shelby, North Carolina. CNA Holdings, Inc. (CNA"), also a subsidiary of Celanese,
retains management of and is responsible for environmental matters for the corporation. The Shelby site
consists of an approximate 450-acre piece of property which includes the main plant production area,
wastewater treatment area, former waste disposal areas, and recreational areas. The plant is located in
south-central Cleveland County, bordered by NC Highway 198 to the west and Lavender Road to the
south, approximately one mile north of Earl and six miles south of Shelby. A site plan showing the
location of production areas, monitor wells, extraction wells and other significant features is shown on
Figure I.
In June 2004, Kubal-Furr & Associates submitted to the Environmental Protection Agency (EPA) and
the North Carolina Department of Environment and Natural Resources (DENR) on behalf of CNA a
document entitled: "Monitored Natural Attenuation Demonstration Project Work Plan-Operable Unit
1-CNA Holdings, lnc/Ticona-Shelby, North Carolina." This plan was the second revision to the
original document prepared December 200 I and followed a series of written comments and responses,
telephone conferences and site visits between CNA, EPA and DENR in the development of an approvable
work plan.
In a letter from Mr. Ken Lucas, EPA, to Mr. Steve Olp, CNA dated May 20, 2004, EPA authorized
implementation of the Monitored Natural Attenuation (MNA) Demonstration Project, based on CNA's
agreement to modify the work plan to address comments summarized in the letter and discussed in a May
19, 2004 meeting and site visit. The above described plan incorporated the EPA's comments and the
revisions are currently under agency review. Based on the contingent EPA authorization, initiation of data
collection activities (i.e., MNA Quarterly Sampling #I) took place during the 2nd Quarter of 2004 in
accordance with the revised MNA work plan. The results of the initial sampling were submitted to the
agencies in a September 2004 MNA data report. The current document represents the fourth data report
summarizing the I st Quarter 2005 sampling event (i.e., MNA Quarterly Sampling #4).
1/ The CNA Holdings, Inc./Ticona Shelby site has alternately been known as HNA Holdings, Inc.,
Hoechst Celanese Corporation, and Celanese Fiber Operations (CFO), the latter being the site name as
listed on the National Priorities List (NPL). The site will be referred to herein as the CFO site.
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CNA Holdings, lnc./Ticona-Shelby, NC-MNA Data Report/or Sampling Event #4 /QI 2005) I Page 2
2.0 Work Performed
As part of the MNA demonstration project, samples are collected at selected monitor wells and Inner
Tier extraction wells in accordance with the June 2004 work plan. Samples were collected from 21
monitor and extraction wells (including 2 duplicates and a field blank) during the period February 16-23,
2005. Samples were collected by Kubal-Furr & Associates and analyzed by Davis & Floyd Laboratories
of Greenwood, South Carolina. Analysis of dissolved gases (methane and carbon dioxide) were
performed by Microseeps of Pittsburgh, PA under subcontract to Davis & Floyd. Samples were collected
during the I st Quarter of 2005 from the following locations:
• Monitor wells: F-55, Tl-I, U-38, J-28, Y-23, Y-65, CC-33, 0-25, K-28, N-29, W-23, and Q-33
• Inner Tier extraction wells: IT-I, IT-2, IT-3, IT-4, IT-5, IT-6, IT-7, IT-SR, and IT-9
All monitoring wells were sampled usmg low flow purging and sampling procedures with the
exception of well F-55 which was evacuated and sampled using a disposable bailer. A peristaltic pump, or
a decontaminated Grundfos® pump, each with dedicated tubing and a Horiba U-22 meter with flow
through cell were used throughout low flow sampling. Drawdown and field measurements of temperature,
pH, specific conductivity, turbidity, DO (dissolved oxygen) and ORP (oxidation reduction potential) were
recorded at 5-minute intervals at each monitoring well during purging. Measurements of ferrous iron were
also collected in the field.
In addition to the field parameters, the samples were analyzed by the laboratory for selected water
quality and MNA indicator parameters consisting of: ethylene glycol, total organic carbon (TOC),
alkalinity, nitrate, iron, sulfate, sulfide, manganese, methane, and carbon dioxide. The analytical data
package for the I st Quarter 2005 is provided in Attachment I along with the data assessment summary
and field sampling logs. A summary of the laboratory and field data are provided in Tables I and 2,
respectively.
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CNA Holdings, lnc./Ticona-Shelby, NC-MNA Data Report/or Sampling Event #4 /Ql 2005) I Page 3
3.0 Discussion of Findings
3.1 Ground-Water Movement
The shallow saprolite potentiometric surface map (Figure 2) shows water-level contours and ground-
water movement in the uppermost water-bearing zone beneath the site. The direction of movement in this
zone is to the east, northeast and southeast from upgradient areas along NC 198, towards discharge areas
along the unnamed tributaries of Buffalo Creek.
An attempt was made to separate the uppermost water-bearing zone from the deeper saprolite and
upper bedrock zone. While this map (Figure 3) presents a reasonable picture of ground-water movement
in the deep saprolite/upper bedrock, it should be pointed out that it is giving a somewhat more generalized
picture of ground-water movement because of the well construction techniques used in many of the wells
and piezometers. The typical construction for most of these wells was to have relatively long screens and
extremely long sand packs in the annular space above the screens. As a result, the lower saprolite/upper
bedrock maps have a number of composite head values measured along a longer screened interval.
Nonetheless, the maps are felt useful for determining the general direction of ground-water movement
which is inferred to the east, northeast and southeast, similar to the shallow saprolite configuration.
A hydrogeologic cross section was also constructed from the I st Quarter data and is shown in Figure
4. The location of the cross section A-A' is shown on the site location map, Figure 1, and is constructed
through the plant from upgradient areas west of the plant to downgradient, off-site areas east of the plant.
The east-west hydrogeologic cross section indicates flow is predominantly horizontal across the site, from
upgradient areas west of the plant toward downgradient areas to the east.
3.2 Ground-Water Quality
The analytical data for the I st Quarter of 2005 were evaluated using method specific quality control
criteria and, for additional guidance when necessary, the EPA's National Functional Guidelines (NFGs)
for organic and inorganic data review. Analytical test results, field sampling logs, chain-of-custody forms,
and the data assessment summary are contained in Attachment 1. A summary of selected analytical data
for the I st Quarter is presented in Tables I and 2.
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CNA Holdings, lnc.!Ticona-Shelby, NC -MNA Data Report for Sampling Event #4 ( QI 2005) I Page 4
3,2.1 Data Quality Assessment
Regarding sample collection, the sampling logs and field information provided were complete. The
field sampling logs indicate that 9 of the 21 wells sampled were within the sampling guidelines for
turbidity of 10 NTUs (nephelometric turbidity units) but that all Inner Tier extraction wells and monitor
wells F-55, TI-I and K-28 exceeded this criteria. While the turbidities at these wells generally stabilized
before sample collection, they did so at levels above the IO NTU guideline. In the case of the Inner Tier
extraction wells, it appears that degradation of ethylene glycol and other constituents from the former
source area has caused biofouling and bacterial build-up outside the well casings and along the well
screens and it's likely that the Inner Tier wells may not be capable of producing samples meeting the
guidelines for turbidity. For the most part, the parameters being analyzed during the demonstration project
would not be significantly affected by slightly elevated turbidities and CNA is prepared to request a
variance to the very specific IO NTU criteria. This need will continue to be evaluated during subsequent
sampling events and will be proposed, if necessary, at an appropriate time.
All I st Quarter data were considered quantitative with several exceptions as noted in the data
assessment summary report. Based on the data-quality assessment, qualifiers were placed on selected
analytical results as noted in Table I. Methane was detected in the field blank and all four trip blanks at
concentrations ranging from 0.005 mg/L to 0.022 mg/L. As a result, methane results for samples from
wells J-29, DUP-2, DUP-3, W-23, Q-33, TI-I and U-38 were assigned a "U" qualifier. Sulfate results for
samples from wells U-38, lT-4 and K-28, and nitrate (as N) results for samples from wells F-55, IT-6
and V-23 were assigned an "X" qualifier by the laboratory to indicate a higher reporting limit due to
matrix interference. The X qualifier had no effect on data usability.
3.2.2 Discussion of Analytical Test Results
A summary of the laboratory data and field parameters are summarized in Tables I and 2,
respectively. The I st Quarter 2005 MNA data, including the anaerobic biodegradation screenmg
parameters, are shown on Figures 5-13.
In its review of the work plan, the EPA suggested that the MNA data set be reviewed with respect to
the screening process contained in EPA MNA guidance documents (Technical Protocol for Evaluating
Natural Attenuation of Chlorinated Solvents [U.S. EPA, /998, EPA/600/R-98//28]. The process involves
comparing the site data to a screening table which assigns a numerical value to each data point, higher
values being more indicative of the potential for anaerobic degradation of constituents. The values for
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CNA Holdings, Inc.!Ticona-Shelby, NC-MNA Data Report for Sampling Event #4 (QI 2005) I Page 5
each parameter for each well are then summed up and produce a total score which, if high enough, is
suggestive of conditions conducive to anaerobic biodegrad/.on-:-'Although not directly applicable to
ethylene glycol degradation, the screening criteria were appliec!_t/ I st Quarter 2005 data set to produce
the numerical results (Table 3) which are shown on Figure 5. As provided in the guidance document, the
screening values would indicate that conditions in the former source area are favorable for anaerobic
biodegradation.
The data on Figures 6-9 are presented as isoconcentration plots except for ethylene glycol (Figure 6)
which has too few contourable data points, and the respective values were just posted to the figure. Of the
21 wells sampled during the I st Quarter 2005, only 4 had any reportable concentrations of ethylene glycol
(F-55, IT-SR, K-2S and V-23). All other locations sampled reported ethylene glycol below the detection
level of 7.0 mg/L (milligrams per liter). It should be noted that earlier Inner Tier ethylene glycol data
were collected under pumping conditions whereas the current data set represents non-pumping conditions
under which the water levels in most Inner Tier wells have recovered by 15 to 20 feet since pumping
stopped on March I, 2004. The general absence of any reportable ethylene glycol at the Inner Tier may be
affected by the depth and length of the Inner Tier screens and the current, non-pumping position of water
levels in the shallow saprolite.
The highest ethylene glycol concentration and TOC (6740 mg/Land 10,700 mg/L, respectively) were
reported in monitor well V-23, at the former OU-2 source area. Monitor well F-55 reported the next
highest ethylene glycol and TOC values (5500 mg/L and 4770 mg/L, respectively), but this area is
interpreted as a small, isolated source not related to the former OU-2 source area at V-23 and the Inner
Tier. The other wells reporting the presence of ethylene glycol included K-28 (244 mg/L), and IT-SR
(42.0 mg/L).
There is an indication of movement of ethylene glycol from the former source area to nearby
downgradient areas (well K-2S) although it has been limited in extent (less than 100 feet). This movement
is expected as the ground-water system equilibrates in response to shutting down the Inner Tier extraction
well system. The migration of ethylene glycol will be evaluated during subsequent monitoring events, and
a ground-water flow and contaminant transport model is scheduled to be developed in early 2006 to assist
in predicting the rate of movement, extent and degradation rates of ethylene glycol and other constituents
from the former source area.
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CNA Holdings, Inc./Ticona-Shelby, NC-MNA Data Report for Sampling Event #4 (QI 2005) I Page 6
In this report, the distribution of total organic carbon has also been plotted (Figure 7) and appears to
present a more reasonable, although indirect, picture of the distribution of ethylene glycol and the residual
contaminant mass in the vicinity of the former source area and Inner Tier. The relationship between
ethylene glycol concentrations and total organic carbon is shown in Table 4. This table summarizes the
data from monitor well locations in which ethylene glycol has been reported as present during the MNA
demonstration project. These data would indicate a positive relationship between ethylene glycol and
TOC and, the R2 value of 0.8653 indicates a high degree of correlation. The value R2 quantifies goodness
of fit. It is a unitless fraction between 0.0 and 1.0; the higher the R2 value, the better the fit. When R2
equals 1.0, all the data points would lie exactly on the line with no scatter.
Ethylene glycol is readily degradable both aerobically and anaerobically. Under aerobic conditions,
ethylene glycol (C2H6O2) will degrade into carbon dioxide and water. Under anaerobic conditions,
ethylene glycol can degrade into ethanol, acetate and methane. The ethanol produced can be further
oxidized to acetate, with methane being the final end product. Reviewing the I st Quarter MNA data set
presents strong evidence that ethylene glycol is being anaerobically degraded in the subsurface using
nitrate, manganese and iron as terminal electron acceptors.
Further indication of ethylene glycol degradation is apparent in the methane production in the most
highly contaminated portions of the aquifer (Figure 8). The monitoring data show that the ground water
contains elevated levels of methane in the areas with high ethylene glycol, indicating an active
methanogenic population. Additionally, the very high alkalinity values (Figure 9) reported around the
former source area are indicative of increased microbial activity.
The 1st Quarter 2005 MNA data set contains multiple lines of evidence that natural attenuation of the
ethylene glycol is occurring at the site. Tabulated in Table 5 is a summary of the selected natural
attenuation indicators, from upgradient areas at well TI-I, through the "plume" as shown in wells V-23
and K-28, to downgradient areas as shown by wells 0-25 and W-23. These results are generally
consistent with the expected findings that as ethylene glycol increases, nitrate will decrease, while ferrous
iron (Fe2+), manganese, and methane will increase. While sulfate would be expected to decrease along
with nitrate, the elevated sulfate levels reported in the downgradient wells are inconsistent with respect to
this constituent.
Attachment 2 contains plots of selected constituents (ethylene glycol, TOC, methane and manganese)
for the MNA monitor wells. These plots have been prepared to show changes in the concentration of
constituents with time as an indicator of progress in remediating ethylene glycol during the MNA
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CNA Holdings, Inc.!Ticona-Shelby, NC-MNA Data Report for Sampling Event #4 ( QI 2005) I Page 7
demonstration project. While trendlines have been added to the plots, for the most part, the database
currently consists of too few data points to establish statistically significant trends in concentrations
except in a general sense as described above. These plots will be updated as new data become available
during the remainder of the project.
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CNA Holdings, lnc.!Ticona-Shelby, NC-MNA Data Report for Sampling Event#4 (QI 2005) I Page 8
4.0 Summary and Recommendations
This data report presents the results of the fourth quarterly sampling for the MNA Demonstration
Project at the CFO site. The numerical results of the anaerobic biodegradation screening procedure
contained in EPA MNA guidance would indicate that conditions in the former source area are favorable
for anaerobic degradation (Table 3 and Figure 5). Reviewing the I st Quarter 2005 MNA data set presents
strong evidence that ethylene glycol is being anaerobically degraded in the subsurface using nitrate,
manganese and iron as terminal electron acceptors. Further indication of ethylene glycol degradation is
apparent in the methane production in the most highly contaminated portions of the aquifer. The
monitoring data show that the ground water contains elevated levels of methane in the areas with high
ethylene glycol, indicating an active methanogenic population. Additionally, the very high alkalinity
values reported around the former source area are indicative of increased microbial activity.
There is an indication of movement of ethylene glycol from the former source area to nearby
downgradient areas (well K-28) although it has been limited in extent (less than 100 feet). This movement
is expected as the ground-water system equilibrates in response to shutting down the Inner Tier extraction
well system in March of 2004. The migration of ethylene glycol will be evaluated during subsequent
monitoring events, and a ground-water flow and contaminant transport model is scheduled to be
developed in early 2006 to assist in predicting the rate of movement, extent and degradation rates of
ethylene glycol and other constituents from the former source area.
The revised work plan submitted to the agencies in June 2004 is currently under review and the EPA
has subsequently requested, and been supplied with, geologic cross sections and other information
concerning construction details of selected monitor wells and/or piezometers that may be sampled to
establish the extent of the ethylene glycol "plume." In addition, responses have been submitted to the
EPA and DENR in response to comments concerning earlier quarterly data reports. Pending agency
review of the supplemental information, no modifications to the sampling program are planned for the
fifth quarterly sampling event (i.e., 2nd Quarter 2005).
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Tables
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I Kubal-Furr & Associates
- - -- -
Ethylene Carbon
Well Gltcol Dioxide
CC-33 <7.0 75.0 ·
F-55 5500 57.0 ·
IT-1 <7.0 9.5.0
IT-2 <7.0 320 ,
IT-3 <7.0 · 37.0 ·
IT-4 <7.0 · 26.0
IT-5 <7.0 260 ·
IT-6 <7.0 320
IT-7 <7.0 280
IT-SR 42.0 230 ·
IT-9 <7.0 200
.J-29 <7.0 . 150
K-28 244 · 160
N-29 <7.0 · 110 ·
0-25 <7.0, 44.0
Q-33 <7.0 · 85.0
Tl-1 <7.0, 78.0.
.. ~:.38 <7.0 ' 76.0 ... '.
V-23 6740 230
V-65 <7.0 110
W-23 <7.0 -190
DUP-2 (Q-33) <7.0 · 88.0
DUP-3 (J-29) <7.0 · 150 ·
FB-01 <7.0 <0.60
-- - - - - - -
Table 1. Water Quality Data (Laboratory Parameters)
MNA Quarterly Sampling #4 I Ql 2005
CNA Holdings, Inc. / Ticona -Shelby, NC
( all results reported in mg/L)
Total Total Total
Methane Total Iron Manganese Sulfide Alkalinity
0.43 · 49.5 2.9 <0.050 61.6
2.8 594 208 <0.050 1200
23.0 156 2.1 <0.050 167
9.3 64.0 7.4 <0.050 • 301
21.0· 54.8, 0.79 <0.050 207
13.0 · ............... 70.3 .... ..... 1 .2 ........ <0.050 ... · ............. ..1.1.0 .. 17.0 74.6 3.6 · 0.069 709
8.9 1000 · 452 · 0.72 1720 ·
14.0 ......... ........... 1?.2 · 25.7 <0.050 · 650
16.0 404 46.6 <0.050 762 ·
20.0 74.9 60.2 <0.050 364
0.0089U · <0.10 · 0.30 · <0.050 ................. 9.57.. .. 16.0 613 · 10.5 <0.050 ' 770
0.95 <0. 10 0.20 · <0.050 4.3
0.76 51.4_ • 0.42 · <0.050 70.2
0.048U <0.10 0.091 • <0.050 98.6 ·
O.llU· 3.4. 0.069-<0.050 · 22.8
.................. 9.,9.0?.6V. <0.1.9: ................... .Q.054 · .......... <9.,0?9 : 1.9
16.0· 1740 · 772 <0.050 • 2800
22.0 23.4 1.2 <0.050 . 250
0.030~ .... <0.10 · 1.9 <0.050 88.2
0.048U' <0.10, 0.093' <0.050 · 98.6 ·
0.0086U · <0.10 -0.30 <0.050 951 0.022 <0.10 <0.010 <0.050 <1.0
U = The analyte was analyzed for, but was not detected above the reported sample quantitation limit.
X = Sample diluted due to matrix interference (applied by the laboratory), no affect on data useability.
-- - - -
Nitrate Total Organic
Nitrogen Sulfate Carbon
<0.10 6.0 1.2
<0.50X 1.2 4770
<0.10 <0.50 7.8
<3.0 <0.10 7.3
<3.0 <0.10 4.5
.... , ................. 5.9-10 <2.SX ··················6.7 ... <0.10 <0.50 17.4
<0.SOX 12.9 2760
5.3 ..... '. .... ··············-· :~9.-..1.9 37.2
6.4
<3.0
19.2
<0.10
0.51
.......... ---~0.1 0
<0.10 ·
2.3
0.91
<0.50X ·
<0.10
0.41
<0.10
19.9
<0.10
<0.10 · 413
<0.10 31.3
40.7 1.6
<2.SX 60.4
0.91 <1.0
217 · 21.3 ·
91.6 1.9 -
1.5 <1.0 -
........ ____ <2.SX -<1.0 -
75.1 10700
1.1 1.1
62.2 3.6
90.4 2.3
40.0 1.9
<0.50 <0.50
CNA Holdings, lnc.!Tico11a-Shelby. NC
MNA Quarterly Sampling #4 (QI '05)
-
-- - - --
Well ORP (Final)
(Units) mV
CC-33 -63.4
F-55 -13.9
IT-1 -160.8
IT-2 -18.0
IT-3 -178.3
IT-4 ....... :J?.4-5
IT-5 -111.2
IT-6 -19.6
IT-7 -116.3
IT-BR -120.4
IT-9 -105.0
):.29 148.3
K-28 -122.7
N-29 566.7
0-25 -132.0
Q-33 -3.8
Tl-1 262.1
U-38 117.0
V-23 31.2
V-65 -98.0
W-23 43.1
- -- - - -
Table 2. Water Quality Data (Field Parameters)
MNA Quarterly Sampling #4 / Ql 2005
CNA Holdings, Inc. / Ticona -Shelby, NC
Temperature
~H (Final) (Final) Cond (Final) DO (Initial)
SU 'C µSiem mg/L
6.76 1 5.79 199 1.51
5.21 18.73 2054 0.46
6.51 15.77 366 0.80
6.27 17.14 458 0.24
6.83 17.55 265 0.24
....... 6.&? .................... J6j1 ...... ·····•········· P>? ······························OJJ .... 6.52 16.60 732 0.19
5.14 17.94 2849 a.so
6.31 17.42 ...................... 901 ............................... .0.J .. B 6.33 17.59 1189 0.55
6.38 16.41 652 0.69
6.67 17.11 ····························1··2·~·4···· 2.80
6.19 18.13 830 0.20
5.35 16.11 35 3.67
.... 6.51 15.99 ... 611 ··················o.65 6.47 16.91 492 0.40
5.1 Z • 18.03 · 59 · 1.05
4.62 17,79 .. 31 2.06
4.91 15.88 3864 0.90
6.46 16.61 328 0.93
6.09 17.11 349 4.77
- --- --
-la, (,,,!, ~ DO (Final) Ferrous Iron
mg/L mg/L
0.14 >40 4 .0
1.03 >40 14
0.13 >40 -SC
0.12 >40 ll,~-
0.10 >40 s-~
0.01 ··················•······.?.'.~9 .... 4-" 0.13
0.03
0.15
0.13
0.22
0.14
0.45
0.31
0.22
0.27
1.37'
1.22
0.13
0.27
0.88
>40 ,4
>40 -z. I c,
>40 'l 0
>40 -,5
>40 z.4
____ .:-::9.-.. 1 .... 0.\.-..S-
>40 z. '1
<0.1 J.O
>49 .... s-: B
<0.1 I. S
<0.1 370
<0.1 o.O
>40 ~ I,
20 ?. I
<0.1 /. "I
CNA Holdings, lnc.rricona-Shelby. NC
MNA Quarterly Sampling #4 (QI '05)
-
- - - ---- --- - - -
Table 3. MNA Screening Parameters
MNA Quarterly Sampling #4 I Q1 2005
CNA Holdings, Inc./ Ticona -Shelby, NC
(all results reported in mg/L unless otherwise noted)
... """' Pk>xlM SY SY ""' SY AA;afinlty $Y Nttrpgcn SY SY Total o.-gllllc:
Carbon $ V 0RP Cf[Jal) {rnY) $ Y pH /Bn,0 {$l1\ S V
CC-33 75.0 0 0-43 <0.050 61.6 <0.10 2 6.0 2 1.2 0 ·63.4 1 6.76 0 F·SS 57.0 0 2.8 ) <0.0S0 0 1200 1 <0.S0X 2 1.2 2 4770 2 ·13.9 1 5.21 0 IT_-_\__ _ ___ 95,0 ______ O •..• ____ 23.0 .•.. , ... _l, ____ ,<0.QSO ____ Q ____ , __ 167 ____ ..•. .1 __ 50.10 2 ________ <0.50 ____ z_ __
IT-2 320 l 9.3 3 <0.050 0 301 1 <3.0 0 <0.10 2 . 1,a ________ o ____ ... ~160.8 --· 2 ..• 6.s1 _ .. o
IT-3 37.0 0 21.0 3 <0.050 0 207 <3.0 0 <0.10 2 7.3 0 ·18.0 1 6.27 0
4.5 0 -178.3 2 6.83 0 IT:,_ 26.0,,__ 0 _13.0. . .. 3-. __ <0.0SQ .•. 0 ____ 1_\.Q _________ 1 ___________ <Q.10 _ ,. . .,. 2. ______ <2,SX ______ 2
rr-s 260 11.0 3 0069 o 709 1 <0.10 2 <0.S0 z . __ 6.7_ .. o _.:.17.4,$.. 2._ ..•...• 6.87... _o._
IT-6 no 8.9 3 0.72 0 1720 1 <0,SOX 2 12.9 17.4 0 -111.2 2 6.52 0
2 2760 2 ·19.6 1 S.14 O IT-7 280. . .. 1,.Q ...... 3.. <0,050 ..... 0 .. 650 ....... 1 _S.3 ....•.... 0
IT-SR 230 16.0 3 <0.050 0 762 6.4 O
IT -9 200 1 20.0 3 <0.050 0 364 1 <3.0 0
H9___ __150 .•. __ . o._._ o.oos~ ····-·o···· __ <o.oso_ •••.• o ••• _____ 9s1 ____ •.•. 1 _J.9.2 .. _.o_ ...... _
K-28 160 1 16.0 3 <0.050 0 770 l <0.10 2
~29 110 0 0.95 3 <0.050 0 4.3 l 0.Sl 2 0-25 ______ ._ --44.0., --··-·o· •. ______ 0,l6-.•. __ 3 __ • ., .• _ .dl QS0 _____ o. ____ , __ _70.2_. __ ,__L -,. .•••.. <0.)0 _____ 2
Q-33 85.0 0 0.048U O <0.050 0 98.6 1 <0.10 2
TI-1 78.0 0 0.1 lU 0 <0.050 0 22.B l 2.3 0
\.l-38 _ 76.0... . .. 0.. Q.Q026U ....... 0. ..<.0,050 ........ 0.... 1.9_ ....... 0. 0,91 ......... 2 .. . V-23 230 1 16.0 3 <0.050 0 2800 <0.50)( 2
V·65 110 O 22.0 3 <0.050 O 250 <0.10 2
W-23 190 0.030U 0 <0.0SO 0 86.2 0.41 2
"""'
.<0.10 ..
<0.10 .... 2 .31.2 ...•.... Z ... :.116,L. 2.. 6,31 .o
2 413 2 ·120.4 2 6.33 0
<0.10 2 31.3 2 -105.0 2 6.38 0 .40,7 __ . ., .• o_ .. ______ 1,6_. __ .o. 1.48,3_._._.o _6,67.. o
<2.SX 2 60.4 2 ·122.7 2 6.19 0
0.91 2 <l.0 0 S66.7 0 5.35 0
.217 ___ , __ Q ___ . ___ 711 -·-··-·2··-·-.•...• ~132.0 2 _____ ... _6.51 ....•...• _,O
91.6 0 1.9 0 -3.B 1 6.47 0
1.5 2 <1.0 o 262.1 o s.12 o
<2.S'\.. 2... <1,0. . 0 117.0 0 .~,62. ·2
7S.1 0 10700 2 31.2 1 4.91 -2
1.1 2 1.1 0 ·98.0 0 6.46 0
62.2 0 3,6 43. \ 6.09
s..v. • Scrl!f!fW><I v~ b/lsedon EPA "'INA<IUidxlce document ·rechlJicalProtocolforfvi/lluat111QN.2turlllAtlH1Wt.G'lof~1«1 Solw~ts" ru.s. EPA. 1998. EPA/600/R·98/\28l
U • The analytft was ilt\lllyzed !01, but wa• not detected abo"" !he reported ,..,mp1e qu1nlttation \omit.
)(•Sample diluted due tomato• •nterlereoce (aP!lbed by the laboratory). no affect on dau useatmty.
- - -
Temperal""
(Rn1D C:Cl s.v 00 fflnnO SY
15.79 0 0.14 3
18.73 O 1.03 O
15.77.. 0 0.13 -----.3
17.14 0 0.12 3
17.SS 0 0.10 3
J6.s1 .. _. ··-o._ ,. ... .,.0,01 3
16.60 0 0.13 3
17.94 0 0.03 3
. 17,42 0 . ··-·. 0,15,.. 3 17.59 O 0.13 3
16.41 0 0.22 3
1711 _0 _____ 014 3
18.13 0 0.45 3
16.11 0 0.31 3
.. 15,99 .o. 0.22 ____ 3
\6.91 0 0.27 3
18.03 0 1.37
.. 17.79. 0 ... uz.
15.88 0 0.13
16.61 O 0.27
17.11 0 0.88
-
ffflll\l$lron SY
>40 3
>40 3
>40 3_
>40 3
>40 3
.... >40 ,_ 3
>40 3
>40 3
..... >40 .•...... 3 ...
>40 3
>40 3
... <0 .. 1. ___ .o
>40 3
<0.1 0
>40 3_
<0.1 0
<0.1 0
.. <0.1 O
>40 3
" ' <0.1 0
-
~
" " " ,. ,.
"" " " " " " ·----,4-··-" " _ _ 16_
' ' .z ....
" " '
CNA Holdi11xs, liic.mcona-Shelby, NC
MNA QuarterlySwnpli111t #4 (QI '05)
-
- -- -
F-55
Ethylene
Date Glycol
9/20/01 155
5/26/04 1990
8/11/04 3790
11/10/04 5300
2/18/05 5500
IT-BR
Ethylene
Date Glycol
9/24/01 368 J
5/26/04 < 7.0
8/11/04 < 7.0
11/10/04 < 7.0
2/22/05 42.0
K-28
Ethylene
Date Glycol
9/18/01 384
5/25/04 < 35.0
8/10/04 < 35.0
11/9/04 227
2/22/05 244
V-23
Ethylene
Date Glycol
9/18/01 5040
5/26/04 7230
8/16/04 8200
11/10/04 6460
2/23/05 6740
- - - - --- - - - - -- -
Table 4. Comparison of Ethylene Glycol Concentrations vs. Total Organic Carbon Concentrations
( all results reported in mg/L}
Total Organic
Carbon
730 14000
3590
4260
4810
4770 12000
Total Organic 10000 Carbon
3 1420 ..._
C,
883 5
583 C 0 8000
210 ~ 413 u
·" C ~ e 6000
0
Total Organic
.,.
0 Carbon I-
1110 4000
1230
2110 ♦ 2710
60.4 2000
♦
Total Organic 0
Carbon 0
7850
11200
9840
12700
10700
♦ EG vs. TOC
-Trend
1000 2000 3000
♦
♦
♦
♦
y = 1 .268x + 777.42
♦ ♦
♦
4000 5000
Ethylene Glycol (mg/L)
R2 = 0.8653
6000 7000 8000 9000
CNA Holdings, lnc.11icona-Shelby, NC
MNA Quarterly Sampling #4 (Ql '05)
-
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Table 5. Summary of Selected Natural Attenuation Indicator Parameters
( all results reported in mg/L)
Back round Plume Area Down radient
Well Tl-1 U-38 V-23 K-28 0-25 W-23
Eth. Glycol <7.0 <7.0 6740 244 <7.0 <7.0
Nitrate 2.3 0.91 <0.50X <0.10 <0.10 0.41
Manganese 0.069 0.054 772 10.5 0.42 1.9
FeZ+ <0.1 <0.1 >40 >40 >40 <0.1
Sulfate 1.5 <2.5X 75.1 <2.5X 217 62.2
Methane 0.1 lU 0.0026U 16.0 16.0 0.76 0.030U
Alkalinity 22.8 1.9 2800 770 70.2 88.2
U = The analyte was analyzed for, but was not detected above the reported sample quantitation limit.
X = Sample diluted due to matrix interference (applied by the laboratory), no affect on data useability.
CNA Holdings. /nc./Tico11a-She/by, NC
MNA Quarterly Sampling #4 (QI '05)
I
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I Figures
I
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I Kubal-Furr & Associates
- - --- --
I
-
i---. -, \
-- -
I • ,
"°"""'°'.,.,.,.1" •
\ 0 oo•
0 350 700
- - - - -• ...
- -
Legend
Monitor Well
Piezometer
• Surface Water Location
♦ Outer Tier Ell:traction Well
• Inner Tier Extraction Well
■ PEW Extraction Well
D Residential Vvell
~ Creek I Stream
D Building / Structure
A=A' Location of Geologic
Cross Section
Kubal-Furr & Associates
-Environmental Consultants-
Figure I. Site Location Map
CNA Holdings, /nc/Ticona
She/b_v, North Carolina
-
- - -\ -0 Legend Monitor Well Wate<-level (ft ms!) • Inner roe, Extraction Well /78/V' w:i~;:.~~Uf ,,,,......_.,,, Creek / Stream ■ Building/ Structure _.. Inferred DirectJon of Ground-water Flow -- --... - -. ,, ... I ,. -• ' .., 'S \ \ \ 0 \ -' i \ \ llt·w.n~ ,., .. I .....,. \ -1 I~ f w,;.,~ --· 350 700 --lounCIIJ .> ✓ .. ?,, \ \ \ --( d'/::5~ ' ..... ... 'I ' ... ,,.. ..... ..... ..... - -- - - -' \ loner Tier Extraction Well Water-Level Elevations IT-1 = 804.21 IT-2 = 805.25 IT-3 = 802.94 IT-4 = 802.59 IT-5 = 803.74 IT-6 = 804.08 IT-7 = 803.82 IT-8R = 800.54 IT-9 = 798.05 '/} \ \ \ \ J \ \ .-l. \ I "' I:! "' I • I •' IC.~ C . I I ' I I • -:--."'I-I .. I .... Kubal-Furr & Associates -E11t>1ronmenta/ Cons11/ta11ts-Figure 2. Potentiometric Surface Map Shallow Saprolite--February JO, 2005 C.\'.,.J Holdings. Inc. T1cona Shelby. l'lorlh Carolina
-------- - - - - -\ J \ ... --,, ... I ,----. \ I • ?,~ t 0 3150 700 --- --.... , -!-,, - --0 .. ❖ • Legend MQnllcrJO/eJJ Water-Level (ft msl) PM!zometer Outer Tier Extraction Wea PEW Extraction Wen /7so/ Water-Level Contour (dl5h•O~ lnttfnd} Creek I Stream ? ' QJ~5 --....., 7Hl2-' ,,,,......_,,,, G] ,,,..,, Building/ Structure Inferred Direction of Ground-Water Flow \ \ ' ' \ A' \ \ \ \ \ \ \ \ \ I I I \ \ \ I • Water level tor we:11 F•SS WH measured on 2/18/05 I I • I I I t / I -11 I I ~Q,;:~,-/ ~-..... I I pZ.1 NW. ......... ,.., ~ -HM I I ' ,.. L \. \ "" ~ '~ '& ... y .... \ '> ,,,, ... --Kubal-Furr & Associates -Environmental Co11s11/tants-Figure J. Poteotiometric Surface Map Deep SaproUte/Upper Bedrock-Febniary 10, 2005 C.\:4 Holdmgs. lnc. Ticona Shelby, .Vorth Caro/ma
-- ---- - - - - ---
850.00 A -i~'=-=-=-=-=-=-=-=-=-=-=-=~P~l•'.'._'.:"'~"'~•:::========::!-f:::::::------------'Nastewater Treatment Area--------------<I
830.00
810.00
790.00
no.oo
750.00
730.00
710.00
690.00
670.00
D-56
827.16
Legend
-810., Line of equal fluid potential {ft msl) c:;:J Bedrock
(dahed v.Nte interred)
• • Potentiometric Surface Saprolite
G-50
813.61
Inferred direction of ground-water
movement
Screened Interval of Well
J•29
808.12
Horizontal Scale in Feet
0 400
- - ---
A' 850.00
630.00
810.00
790.00
770.00
750.00
730.00
710.00
690.00
670.00
Kubal-Furr & Associates
-Environmental Consultan.ts -
Flgure 4. Hydrogeologic C~ Section
A·A'-Febrnary 10, 2005
CNA Holdings, lnc.if'icona
Shelby, North. Carolina
-
-- ----Legend
O MoniorWell
A Piezomater
L:::.. Surface Water Location
❖ Outer T1<1r Extraction Well
• I nne< r l9f Extraction Well
■ PEW Extracllon Wei
Creek I Stream
--
I
'ft .
IL2 • 14
lI,3 • 14 ~. 16
•
--=-
t,1,29
0 11
&211 0 19
lL5 17 0
ll,230l,650e [Yi
0 L55 14
-c tt
'
-----
/ lh1
I O 3
Recreation Pond
14114 18
1L.Z •
17
JI:aB •
[_ 17 l.I-9 •
17 0 Cff3
,----
I
-
Q=25
16
-- -
""' .__.._, ... ,. Pond
W,23 o. 5 ,, I ---\
I I
' -.....
::,...__ -__..J
\
_0=33
7 0
-- -
•
--Anaerobic B1odegradation
Screening Parameters
0
!>-9
10-14
~15
Scale In Feet
200 400
Kubal-Furr & Associates
-Environmental Consultants-
Figure 5. Anaerobic Blodegradatlon Screening Parameters
Sample Date: February 16-23, 2005
CSA Holdings, !nc. Ticona
Shelbv .. Vorth Caro/ma
- -
- ---Legend
0 Monitor Well
A Piezometer
L:J.. Surface water location
❖ Outer Tier Extraction Wei
• Inner Tier Extraction Well
■ PEW Extraction WeQ
r-J Creek I Stream
0 Building I Structure
D
- -
,
I= <7.0
I
/ lh1
0 <7.0
Recreation Pond
- --
I
/ ,
- ---- - - -
--
Polishing Pond
lOlaZl <7.0 I
...... -....
C
\
~ ,,
'·~
0
Seale In Feet
0 200
Oe33 <7.0 0
\
c?
'
\ I
/
I
Kubal-Furr & Associates
-Environmental Consultants-
Figure 6. Ethylene Glycol Concentrations
Sample Date: February 16-23, 2005
(results reporled in mgll)
CNA Holdings, lnc.!Ticona
Shelby, North Carolina
--
- - -- - - - -- - --Legend
o Mon~orWell
• Poezometo,
L:>. Surface water Location
❖ Outer rier Extraction Wei
e Inner T,er Extraction Woll
■ PEW Extraction WeR
Creek / Stream
tt •
'
--------
ti9 0
I
Recreation Pond
I ~ )~~ 'ff O <1.0
lI:.1 • 7.8
IL2 . &2B 7-3 0 60.4 lL3 . 4.5
'tr .
JL5 e 17.4
~O•II:S 10700/1.1 2760
1I:Z .
37.2
JLaB •
L 413 e
LI,9
31.3
0-..25 0 213
cc,JJ 0 1.2
I
Poll,hlng Pond
W:23 0 3.6 ---\ '\ .
I
...... .. ...... -,......_ •
\
_J
Q,33
1.9 0
-- - - -
Concentrations
(mg/L)
0.001-0 01
0.01-0.1
0.1-1
1-10
10-100 • >100
~
Scale in Faot
0 200
Kubal-Furr & Associates
-Environmental Consultants-
400
Figure 7. Inferred Total Organic Carbon DlstrlbuUon
Sample Date: February 16-23. 2005
(results reported m mg,LJ
C,\JI Holdings, lnc.lTicona
Shelby. Vortlr C arolim
--
- ---Legend 0 Monitor Well ... Piezometer C. Surface Water Locabon ❖ Outer Tier Extraction Wei - - - - ------ - - -Concentrations (mg/L) 0.001-0.01 0.01-0.1 OH • Inner Tl8r Extraction Well • PEW Extraction WeU Creek I Stream I 111,29 0 0.95 ', -~-7 1-10 10-100 tJ >100 \ 0 &S5 2.8 tl ' □ -----/ lI:1. 23.0 IL2. 9.3 lL.'.l. 21.0 K,2B 0 16.0 Polr.hlng Pond / J,29 u o 13.o IL5 i ~. I o.0089tlbZ!,/JU:;5 o•• 1: 0,25 0 0.76 \ 16.0/22.0 8.9 / lhl \1/o e I o o.11u e 0 u,aa l.b3826U C_16.0 e ~~ •• 'ooo lL9 ....,.., . 20.0 0 0.43 r--4 ~ J;.cJOW ~r---.,, £ :!I' :2 .,, l I I I I - j ..... ..... .,., • Recreation Pond Q,J3 0.048lP _J ' -~ Scale in Feet 0 200 ~s / Kubal-Furr & Associates -Environmental Consultants-Figure 8. Inferred Methane Distribution Sample Date: February 16-23, 2005 (results reported 111 mg l) CNA Holdings, Inc. Ticona Shelby .. Vorth Carolina - -400
----- --- ---Legend
0 Monitor Well
• Piezometer
.c. Surface Water Location
❖ Outer lier Extraction Wei
• Inner T,er Extraction Well
■ PEW Extraction Well
,-.J Creek/ Stream
■ Building / Structure
o&ss 1200
tt
'
----
I J,.29 0 957
I
I
0 lli J :1,,:
Recreation Pond
I
;W •
-::
~ 0 43
II:2 . &21!
3)1 0 770
IL3 • 207 ~-!LS
~
e 709 0-..25 0 70.2
ll:23lll,B5 o e IL6 2800/250 1720 ~-ltJl,23 0 88.2
IIdlB e
762 [[,9 .
364 c.c:33 'I '. 0 616
I ..,
l ,
~ l
.....
.. ..... -..-"I
I
\
I
-
7
Q,3J
96.6 0
- - - --Concentrations
(mg/L)
0.001-0.01
0.01-0.1
0.1-1
1-10
10-100
>100
\
Scale In Feet
0 200
Kubal-Furr & Associates
-Fnvrronmenta/ Consultants-
400
Figure 9. Inferred AlkaUnlty (Total) Distribution
Sample Date: February 16-23, 2005
(results reported in mg L)
C,\'.4 Holdings, Inc. Ticona
Shelby, .Vorth Caro/ma
--
- -- -
Legend
O MonlorWell
.A Piezometer
,o. Surface Water Location
❖ Outer Tier Extraction Wei
e Inner T,er Extraction Well
■ PEW Extraction Wei
__..,, Creek I Stream
■ Blilding / Strue1ure
--
/
/ .k2ll 0 0.30
I
-
lL1 . 2.1
-
N,29
0 0.20
-
lL2 . K:28 7.4 0 10.5
lL3 . 0 79
1f1 .
1L5 e 3.6 Q,25
0 0.42
ll.,.2Jlll,6S o e IL6
772/1 .2 452
.. ---... ---
Recreation Pond
1U • 25.7
LLa8 •
46.6 e lL9 60.2
I l ... ~ ... :, iii
♦
CC:33 0 2.9
-
/
I
j
... l
if :a ... l
..._ .
•
-
llll,23
0 1.9
...... . ....
\
--
Oc33 0.0910
-- - - -
Conoentrations
{mg/L)
0 001-0.01
0.01-0 1
0 1-1
1-10
10-100 • >100
\
Seale on Feet
0 200
Kubal-Furr & Associates
-Environmental Consultants-
400
Figure 10. Inferred Manganese (Total) Distribution
Sample Date: February 16-23, 2005
(results reported m mg l)
C.\'A Holdings, Inc. Ticona
Shelby . .Vorth Caro/ma
--
--- -Legend O MonlorWell .a. Piezometer A Surface water Locabon ❖ Outer T,er Extraction Wei • Inner Tier Extraction Well ■ PEW Extraction Wei Creek I Stream 0 E.,55 >40 .. • • ---------/ -I .h2ll <0.1 I / lh1 0 <0.1 -- --- ----- - -Concentrations (mg/L) 0.001-0.01 0.01--0.1 0.1-1 1-10 I ,:::::= N,29 0 <0.1 -s~~\~ 10-100 • >100 \ 1L.1. >40 l.I:2. >40 1L3. >40 lI,4. >40 K,.28 0 >40 P0Hsbln1 Pond i ' lL5 • >40 0,25 0 >40 . L lI:.Z • >40 ILll8 • >40 IL9. >40 ~ 0 >40 /4.W,23 ~T ---1 r I l I I I -j .... ..... ,.., • \ Q.,J3 <0.1 0 -' \ 0 Scale in Feet 200 11 / ~s / Kubal-Furr & Associates -Environmental Consultants-Figure I 1. Inferred Ferrous Iron Distribution Sample Date: February 16-23, 2005 (results reported m mg lJ C\:.l Holdmgs, Inc. Tirona Shelby . .Vorth Caro/ma --400
- - - -- ------ -
Legend
O MonlorWell
A PiezometeJ
A Surface Water LocabOn
Q Outer Tier Extraction Wei
• Inner Tier Extraction Well
■ PEW Extraction WeN
Creek / Stream
ogx
H o
11
'
•
-----
/
I J,2a
19.2
I Il.,,l
0 2.3
Recreation Pond
I .-:Y: 1ffl II:1~ 0 PolW.lna Pond
/<0.10 f"' 1L2 . &21! ~
<J.o~~o.1~=r--,=======~, ===::,
0 ~-~ \LJ e <0.10
~o • lLc6 <0.SOX/<0.10 <O.SOX
/
W,23
0 0.41
1/
\
Q,JJ
<0.100
-- - - -
Concentrations
(mg/L)
0.001-0.01
0.01-0.1
0.1-1
1-10
10-100 • >100
\
Scale in Feet
0 200
Kubal-Furr & Associates
-Environmental Consultants-
Figure 12. Inferred Nitrate Distrlbudon
Sample Date: February 16-23, 2005
(resulu reported in mg l )
C.\:.J Holdings, Inc. T1cona
Shelby, .Vorrh Carolina
--
400
-- - -
Legend
O MonlorWoll
A Piezometer
~ Surface Water Location
❖ Outer roe, Extraction Wei
e Inner roer Ex!raellon Well
■ PEW Extraction Wei
Creek/ Stream
0 12
H • 1\
'
.. -------
-
/ J,29
I
/ Dd.
0 1.5
40.7
- - -
lb23lllc65 0 . IL6
75.1/1 .1 12.9
JLZ •
<0.10 -~
-
Q,25 0 217
I • IL9 CC,33 ~---<0.10 e o 6.0
Recreation Pond /
.....
-
PolisJ.'
lt,1,23 0 62.2
\
.. ........ . ....,
• I
\
- -
_J
Q,JJ
91.6 0
-- -- -
ConoentratJons
(mg/L)
0 001-0 01
001-0.1
01-1
1-10
10-100
>100
\
Scale In Feet
0 200
Kubal-Furr & Associates
-Environmental Consultants-
Figure 13. Inferred Sulfate Distribution
Sample Date: February 16-23, 2005
(results reported i11 mgll )
CNA Holdi11gs, /11c., Tico11a
Shelby, .Vorth Carolina
--
400
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Attachment 1
Analytical Data Package, Data Assessment Summary and
Field Sampling Logs-MNA Quarterly Sampling #4/Q1 2005
-----------Kubal-Furr & Associates -----------
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DATA ASSESSMENT SUMMARY CHECKLIST AND REPORT-LEVEL II
Client ID:
Project Number:
Project Description:
Ticona. Shelby. NC
26NA01
Q.1LQ2
Sample Delivery Group (SDG) Description:
Prepared By: Robert DeGaetano
Date: 04/20/05
Twenty-one aqueous samples, two field duplicates, four trip blanks and a field blank were
collected by Kubal-Furr & Associates and submitted to Davis & Floyd of Greenwood, SC for
analysis. The samples were tested for ethylene glycol, carbon dioxide, methane, metals (total
iron and manganese), sulfide, alkalinity, nitrate (as N), sulfate and total organic carbon. The
methane and carbon dioxide testing was subcontracted to Microseeps Laboratories in Pittsburgh,
PA. The D&F login numbers were L05021802, L05022006, L05022301 and L05022402.
CONTENTS LEVEL COMMENTS
II
Sample Results ✓ Most data considered Class A as
reported. Some data are considered
Class B, and are assigned qualifiers.
Chain(s) of Custody (COCs) ✓ Satisfactory
Master Tracking List ✓ Satisfactory
Method Conformance Summary ✓ Satisfactory
Batch Quality Control Report " Satisfactory
Trip/Field/Equipment Blank Report " Methane detected in the field blank and
trip blanks
Field Notes/Logbook ✓ Not reviewed
Discussion:
Methane was detected in the field blank and all four trip blanks at concentrations ranging from 0.005
mg/L to 0.022 mg/L. Consequently, methane results for the four trip blanks, the field blank and for
samples from J-29, DUP-2, DUP-3, W-23, Q-33, TI-I and U-38, were assigned a "U" qualifier.
Sulfate results for samples from wells U-38, IT-4 and K-28, and Nitrate (as N) results for samples
from wells F-55, IT-6 and V-23 were assigned an "X" qualifier by the laboratory to indicate a higher
reporting limit due to matrix interference. All remaining results were Class A.
Class A = quantitative Class B = qualitative Class C = unuseable
Kubal-Furr & Associates
.. '
DAYIS
FLtrYD
March 15, 2005
STEVE OLP
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Report ID : AC690
Page I of 136
1fil l1: © l1: ll W l1: 1ffi
ffi MAR 2 1 2005 illJ
BY:.Q:f.~2/t:f~}.
LABORATORY ANALYSIS REPOR'f
Login Number
Project Number
Description
:L05021802, L05022006, L05022301, L05022402 :61621.03
:GROUNDWATER-PROJECT #TF026NA99
Dear Steve Olp:
We are pleased to provide the enclosed analytical results for the samples received by Davis & Floyd, Inc. on February 17, 2005 through February 23, 2005.
A formal Quality Assurance/Quality Control program is maintained by Davis & Floyd, which is designed to meet or exceed the EPA, NELAC or other appropriate regulatory requirements. All analytical analyses for this project met QA/QC criteria and the results are within the 99% confidence interval for each method unless otherwise stated in the footnotes. This report is to be reproduced only in full.
Feel free to contact our Client Services Representative at [phone] if further explanation of the analysis is required. Unless other arrangements have been made, samples will be disposed of or returned 14 days from the date of the report. We appreciate the opportunity to provide services to your firm.
Sincerely,
DAVIS & P/4NC✓.·,,.,.;--1-
ohn H. McCord, Jr.
Laboratory Manager
Davis & Floyd, Inc. ]' PO Drawer 428 / Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax \864) 229-7119
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Df\VIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TICON.A, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
Master Sample Tracking List
Sample ID Client ID
L05021802-01 TI•l
~{\@W~~~¾~iRftd4##@W Mttw:nrMA itttt?.¥.,~ :jl,l;W;~,
Gas Chromatography
SW846 8015
Subcontract Work
AM20GAX
Trace Metals
SW846 6010B T
Wet Chem.iotry
EPA 376.2
SM 2320B
SW846 9056
SW846 9056
SW846 9060
L05021802-02
NC Cenijication Number: 25
Project Number: 61621.03
Report Date
Page 2 of 136
March 15, 2005
Report ID: AC690
Date Collected Date Received
0211,12005 1552 02/17/2005
ifa1JWfFWt~~Jij;~~:ffW¥"':,:< tw:~#t;r::~~,~l:wrw{rttmt
02/22/2005 1208
02/24/2005 0000
02/24/2005 0226
02/23/2005 1526
02/23/2005 1538
02/18/2005 1147
02/26/2005 1358
03/02/2005 1740
02;1,;2005 1734 02/17/:2005 UHFiIM;!fft.4¥%/i.;WW. @f/'IJtHtfHH:WfJHi\¥:;tI#.it; :lftlIERAAtt!tU:~ti
Gas Chromatography
SWB46 8015
Subcontract Work
AM20GAX
Trace Metals
SW846 601 OB T
Wet Chemistry
EPA 376.2
SM 2320B
SW846 9056
SW846 9056
SW846 9060
Gas Chromatography
SW846 8015
02/22/2005 1240
02/24/2005 0000
02/24/2005 0231
02/23/2005 1527
02/23/2005 1549
02/18/2005 1207
03/01/2005 0932
03/02/2005 1804
02/22/2005 1311
I Davis & Floyd, Inc. :i PO Drawer 428 J Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 ! [phone] I fax [phone]
Df\YIS
FL.WO
Client
Contact
LABORATORY ANALYSIS REPORT
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Cenification Number: 25
Project Number, 61621.03
Report Date
Page 3 of 136
March 15, 2005
Report ID: AC690
Master Sample Tracking List
Sample ID
Subcontract Hark
AM20GAX
Trace Metala
SW846 6010B T
Wet Cbamiatry
EPA 376.2
SM 23208
SW846 9056
SW846 9056
SW846 9060
L05021802-04
Gas Chromatography
SW846 8015
Subcontract Work
AM20GAX
Trnce Metala
SW84 6 601 OB T
_Wet Chemistry
EPA 376.2
SM 2320B
SW846 9056
SW846 9056
SW846 9060
L050lll02·05
11?@!#~:tf~i?.;}t:,lffitK
Gas ChrOillatography
SW846 8015
Subcontract Work
AM20GAX
Trace Metals
SW846 6010B T
Client ID
DUP-2
Date Collected
0000
Ol/17/2005 1J51
tt/)h\WI@lrff~J;J;..ij\ij~1itt\
Date Received
02/17/2005
Ol/17/l005
02/24/2005 0000
02/24/2005 0237
02/23/2005 1528
02/23/2005 1556
02/18/2005 1306
02/18/2005 1)25
03/03/2005 0909
02/22/2005 1342
02/24/2005 0000
02/24/2005 0243
02/23/2005 1529
02/23/2005 1610
02/18/2005 1345
02/18/2005 1404
03/02/2005 1853
JtJ:~1:a£;:h~Ji~:i::,t·=:·
02/22/2005 1413
02/24/2005 0000
02/24/2005 0249
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Davis & Floyd, Inc. ··I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I (864) 229•4413 ! Fax (864) 229·7119 I
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DAYIS
FLtwD LABORATORY ANALYSIS REPORT
Client
contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
Master Sample Tracking List
Sample ID
Wet Chemistry
EPA 376-2
SM 2320B
SWB46 9056
SW846 9056
SW846 9060
L05021802-06
Gas Chromatography
SW846 8015
Suhcontract Work
AM20GAX
Trace Metals
SW846 6010B T
Wet Chemistry
EPA 376.2
SM 23208
SW846 9056
SW846 9060
L0S021802-07
Gas Chromatography
SW846 8015
Subcontract Work
AM20C.AX
Trace Metals
SW846 6010B T
Wet Chemistry
EPA 376.2
SM 2320B
SW846 9056
SW84G 9056
SW846 9060
Client ID
DUP-3
W-23
NC Cenijication Number: 25
Project Number: 61621.03
Report Date
Page 4 of 136
Date Collected
02/17/2005 1548
March 1s, 2 oos
Report 1D: AC690
Date Received
02/23/2005 1530
02/23/2005 1619
02/18/2005 1424
02/28/2005 1615
03/03/2005 0935
02/22/2005 1444
02/24/2005 0000
02/24/2005 0254
02/23/2005 1531
02/23/2005 1629
02/18/2005 1542
03/02/2005 1941
02/22/2005 1515
02/24/2005 0000
Q:?./24/2005 0312
02/23/2005 1532
02/23/2005 1638
02/18/2005 1602
02/18/2005 1621
03/02/2005 2008
I Davis & Floyd, Inc. · f PO Drawer 428 I Greenwood, SC 29648 [ B 16 E. Ours! Avenue I Creenwood, SC 29649 I [phone] l Fax [phone]
DAYIS
FLtJfD LABORATORY ANALYSIS REPORT
sample ID
L05021802-08
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
Master Sample Tracking List
Client ID
TRIP BLANlt
NC Cenijicalion Number: 25
Project Number: 61621. 03
Report Date
Page 5 of 136
Date Collected
02/14/2005 0910
March 15, 2005
Report ID: AC690
Date Received
02/17/100!1 i%%£IflQl~ $.ff!fijii#g~f tr~w Itt!.5:;wm,~Y##.~:r:: ~:rn::;:;:;:.Jf)@IfitN~:~:!~~!'.£~~!: fi~i: ::tm;!.t.~.¥illf1.ii'IHWI Subcontract Work
AM20GAX
L05022006-01 0-25
i#}tK~~Af#?.itl\~·t~~-f.tt '.?K~itd\ f?J@Iif!¥f~~@M.ijf
Gas ChrOlllatography
SW846 8015
Subcontract work
AM20GAX
Trace Metals
SW84 6 601 OB T
Wet Chemistry
EPA 376. 2
SM 2320B
SWB46 9056
SW846 9056
SW846 9060
L05022006-02
Gas Chromatography
SW846 8015
Subcontract Work
AM20GAX
Trace Metals
SW846 6010B T
Wet Chemistry
EPA 376.2
SM 23208
SW846 9056
SW846 9056
SW846 9060
IT-1
02/11/JOOS 1100
1235
02/24/2005 0000
02/18/2005 :t{IJ@j@f}.~ftiil:Igft{}ff'PCcC·C:
02/22/2005 1822
02/24/2005 0000
02/28/2005 1914
02/25/2005 1013
02/23/2005 1647
02/19/2005 1627
02/19/2005 1745
03/03/2005 0106
02/22/2005 1924
02/24/2005 0000
02/28/2005 1943
02/25/2005 1014
02/23/2005 1659
02/19/2005 1509
03/01/2005 0005
03/0)/2005 QI))
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Davis & floyd, Inc. ·1 PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax (86 4) 229·7119 I
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DAYIS
FLtwD LABORATORY ANALYSIS REPORT
Client.
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number, 61621.03
Report Date
Page 6 of 136
March 15, 2005
Report 1D: AC690
Master Sample Tracking List
Sample ID Client ID
L05022006-03 F-55 ttf@\oot;lt~:&&iitt.f9iil)f:1Mf ,;;/·: .,,:.,· NI:JJWiif/jJ#:!#i@?t
Gas Chromatography
SW846 8015
Subcontract Work
AM20GAX
Trace Metals
SW846 6010B T
W~t Chemistry
EPA 376.2
SM 2320B
SW846 9056
SW846 9056
SW846 9060
L05022006-04
Gas Chromatography
SW846 8015
Subcontract Work
AM20GAX
Trace Metals
SW846 60108 T
Wet Chemistry
EPA 316.2
SM 23208
SW846 9056
SW846 9056
SW846 9060
L05022006-05 N-29
lt.~P£UI;XJiiA~;.~1ur@Mti@t
Gas Chromatography
SW846 8015
Date Collected
02/11/2005 1355
,,,-,,,,,,,,,,,,,,,,tffrtt?iti#.ilJ#.;,t;if&MHm@
1019
02/11/2005 1229
Date Received
02/18/:il00!S
tkff;;:~~ @W@i!_ic,.t'-:f:.§!#f
02/22/2005 2232
02/24/2005 0000
02/28/2005 2358
02/25/2005 1015
02/23/2005 1711
02/19/2005 1824
02/19/2005 1904
03/03/2005 0201
02/18/2005
02/11/2005
02/22/2005 2027
02/24/2005 0000
02/28/2005 1955
02/25/2005 1016
02/23/2005 1751
02/19/2005 1213
02/28/2005 2227
03/03/2005 0224
ttti/%Et:I i@tiiiilBi?r··. r:==:z12tt MTW=fM'.g~Jfld'· :P.,~:~:;;r;;,:~
02/22/2005 2129
I Davis & Floyd, Inc. · t ·po Drawer 428 l Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
Dl\YIS
FLtn'D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
252S BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
Master Sample Tracking List
Sample J:D
Subcontract Work
AM20GAX
Trace Metals
SW846 60108 T
Wet Chemistry
EPA 376.2
SM 23208
SW846 9056
SW846 9056
SW846 9060
L05022006-06
Subcontract Work
AH20GAX
L05022301-01
Gas Chromatography
SW846 8015
Subcontract Work
AM20GAX
Trace .Metals
SWB46 601 OB T
Wet Chemistry
EPA 376.2
SM 23208
SW846 9038
SW846 9056
SW846 9060
L05022301-02
Gas Chromatography
SW846 8015
. Client ID
TRIP BLJ\NK-2
IT-9
IT-BR
NC Certification Number: 25
Project Number: 61621.03
Report Date
Page 7 of 136
Date Collected
02/14/2005 0910
0953
1120
March 15, 2005
Report ID: AC690
Date Received
02/24/2005 0000
02/28/2005 2001
02/25/2005 1017
02/23/2005 1801
02/19/2005 1350
02/28/2005 2345
03/03/2005 0249
02/24/2005 0000
02/24/2005 1143
03/01/2005 0000
03/01/2005 0010
02/25/2005 1018
02/23/2005 1 B 14
03/11/2005 101B
02/23/2005 2023
03/03/2005 1749
02/24/2005 1245
Davis & Floyd, Inc. ·r PO Drawer 428 j Greenwood. SC 29648 I 816 E. Durst Avenue j Greenwood, SC 29649 I (H64) 229-4413 I Fax (R64J 229-7119
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DAYIS
FLtJfD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
Master Sample Tracking List
Sample ID
Subcontract Work
AM20GAX
Trace Metals
SW846 6010B T
Wet Chel!listry
EPA 376.2
SM 2320B
SW846 9038
SW846 9056
SW846 9060
Client ID
LOS022301-03 IT·2
\A:Ji~#.!t.iti.f§li:ii:!!.@ki MW
Gas Chro~atography
SW846 8015
Subcontract Work
AM20GAX
Trace Meta.la
SW846 6010B T
Wet Chemistry
EPA 376.2
SM 23208
SW846 9038
SWB46 9056
SW846 9060
L05022301-04,
Gas Chromatography
SW846 8015
Subcontract Work
Af120GAX
Trace Metals
SW846 6010B T
IT-3
NC Certificarion Number: 25
Project Number: 61621.03
Report Date
Page a of 136
Date Collected
March 15, 2005
Report ID: AC690
Date Received
03/01/2005 0000
02/28/2005 2024
02/25/2005 1019
02/23/2005 1825
03/11/2005 1027
02/23/2005 2102
03/03/2005 1819
Ol/22/2O05 1039 02/22/2005 '.@}Wtkfa%;it~tffM1@llW/M\H\IM%%%\~ftH¥.tiiltW}fl
12-45
02/24/2005 13'l B
0)/01/2005 0000
02/28/2005 2030
02/25/2005 1020
02/23/2005 1834
03/11/2005 1035
02/23/2005 2300
03/03/2005 1844
02/24/2005 1450
0)/01/2005 0000
02/28/2005 2053
I. Davis & Floyd, Inc. ·j PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] J Fax [phone]
DL\YIS
FLtn'D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
Master Sample Tracking List
Sample ID
Wet Chemistry
EPA 376.2
SM 2320B
SW846 9038
SW846 9056
SW846 9060
L05022301-05
Gas Chromatography
SW846 8015
Subcontract Work
AM20GAX
Trace Metals
SW846 6010B T
Wet Chemistry
EPA 376.2
SM 2320B
SW846 9038
SW846 9056
SW846 9060
L05022301-06
Subcontract Work
AM20GAX
L05022402-0l
Gaa Chromatography
SW846 8015
Subcontract Work
AM20GAX
Trace Metals
SW846 601 OB T
Client ID
IT-7
TRIP BLANF>3
ITM6
NC Certificacion Number: 25
Project Number: 61621.03
Report Date
Page 9 of 136
Date Collected
1245
1645
March 15, 2005
Report ID: AC690
Date Received
0✓./25/2005
02/23/2005
03/11/2005
02/24/2005
03/03/2005
1021
184 7
1044
0018
1909
02/24/2005 1552
03/0.1/2005 0000
02/28/2005 2059
02/25/2005 1022
02/23/2005 1855
03/11/2005 1057
02/24/2005 0057
03/04/2005 0841
03/01/2005 0000
02/28/2005 1717
03/01/2005 0000
03/01/2005 001~
Davis & floyd, Inc. :! PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] ! Fax [phone]
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
Master Sample Tracking List
Sample ID
Wet Chemistry
EPA 376.2
SM 2320B
SW846 9056
SW846 9056
SW846 9060
L0S022402-02
Gas Chro:inatography
SW846 8015
Subcontract Work
AM20GAX
Trace Metals
SW846 6010B T
Wet Chemistry
EPA 376.2
SM 2320B
SW846 9055
SW846 9056
SW846 9060
Gas Chromatography
SW846 8015
Subcontract Work
AM20GAX
Trace Metals
SW846 6010B T
Wet Chemistry
EPA 376.2
SM 2320B
SWB46 9056
SW846 9056
SW846 9060
Client ID
IT-4
NC Certification Number: 25
Project Number; 61621.03
Report Date March 15, 2005
Page 10 of 136 Report ID: AC690
Date Collected
1027
Date Received
02/25/2005 1027
03/02/2005 1445
02/24/2005 1342
03/01/2005 0143
03/03/2005 2053
02/28/2005 1410
03/01/2005 0000
02/28/2005 2111
02/25/2005 1028
03/02/2005 1456
02/24/2005 1717
03/01/2005 0340
0)/03/2005 2119
02/28/2005 1512
03/01/2005 0000
02/28/2005 2117
02/25/2005 1029
03/02/2005 1509
02/24/2005 1520
03/01/2005 0320
03/03/2005 2147 I Davis & Floyd, Inc. ·t·ro Drawer428 Greenwood, SC 29648 j 816 E. Durst Avenue I Greenwood. SC 29649 I [phone] I Fax [phone]
D}\VIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
Master Sample Tracking List
Sa.raplc ID
L0S022402-04
Gas Chromatography
SW846 8015
Subcontract Work
AM20GAX
Trace Metals
SW846 6010B T
Wet Chemistry
EPA 376.2
SM 2320B
SW846 9056
SW846 9056
SW846 9060
L05022402-0S
Gas Chromatography
SW846 8015
Subcontract Work
AM20GAX
Tro.cc Metals
SWB46 60108 T
Wet Chemistry
EPA 376.2
SM 2320B
SW846 9056
SW846 9056
SW846 9060
L05022402-06
Gas Chromatography
SW846 8015
Client ID
V-23
V-65
NC Certification Number: 25
Project Number: 61621.03
Report Date
Page 11 of 136
Date Collected
1120
1745
March 15, 2005
Report ID: AC690
Date Received
02/28/2005 1922
03/01/2005 0000
03/01/2005 0021
02/25/2005 1030
03/02/20-05 1518
02/24/2005 1914
03/01/2005 0400
03/03/2005 2002
02/28/2005 1615
03/01/2005 0000
02/28/2005 2128
02/25/2005 1031
03/02/2005 1529
02/24/2005 2033
03/01/2005 0518
03/03/2005 2351
02/28/2005 1339
Davis & r!oyd, Inc. :j PO Drawer 428 I Greenwood, SC 29648 j 816 E. Dursl Avenue / Greenwood, SC 29649 I (864) 229·4413 ! Fax [phone]
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Di\YIS
FLtn'D
Client
Contact
LABORATORY ANALYSIS REPORT
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 12 of 136 Report ID: AC690
Master Sample Tracking List
Salllple ID
Subcontract Work
AM20GAX
Trace Metals
SW846 6010B T
Wet CbE!IIU.s try
~PA 376.2
SM 2320B
SWB46 9056
SW846 9056
SW846 9060
L05022402-07
Gas Chromatography
SW846 8015
Subcontract Work
AMZOGAX
Trace Metals
SW846 6010B T
Wet Chemistry
EPA 376.2
SM 2320B
SW846 9056
SW846 9056
SW846 9060
LOS022402-08
Subcontract Work
AM2DGAX
Client ID Date Collected
IC-28 02/22/2005 1715
TRIP BLANK-4
Date Received
03/01/2005 0000
02/28/2005 2134
02/25/2005 1032
03/02/2005 1541
02/24/2005 1500
03/01/2005 0301
03/04/2005 OOH
02/28/2005 1819
03/01/2005 0000
02/28/2005 2209
02/25/2005 1033
OJ/02/2005 1611
02/24/2005 1421
03/01/2005 0222
03/03/2005 2027
03/01/2005 0000
Davis & Floyd, Inc. ··j PO Drawer 428 I Greenwood, SC 29648 j 816 E. Durst Avenue I Greenwood, SC 29649 j {864) 229-4413 I Fax [phone]
\
Df\YIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC
Steve Olp
28152
Client ID: TI-1
Matrix
Parameter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
Subcontract Work
AM20GAX
CARBON DIOXIDE
METHANE
Trace Metals
SW846 6010B T
IROU, TOTAL
MANGANESE, TOTAL
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL
SM 2320B
ALKALINITY, TOTAL
SW846 9056
NITRATE NITROGEN (AS N)
SULFATE
SW846 9060
ORGANIC CARBON, TOTAL
Sample Collllllents: L05021802-0l
GW/Chemw
<
Result
7.0
78.0
0.11
3 ••
0. 0 6 !1
0.050
22.8
2. 3
1.5
1.0
Qual
NC Cenijicarion Number: 25
Project Number, 61621.03
Report Date March 15, 2005
Page 13 of 136 Report ID: AC690
Sample ID L05021802-01
Date Collected, 02/16/2005 1552
Date Received
RDL Units
7.0
0.60
0.000015
0. 10
0. 010
0.050
1.0
0. 10
o. 50
1.0
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
02/17/2005
Ana1yi;t
JMT
JL
JL
BDL
BDL
CDC
MPM
DHR
DHR
CDC
Date
02/22/2005 1208
02/24/2005 0000
02/24/2005 0000
02/24/2005 0226
02/24/2005 0226
02/23/2005 1526
02/23/2005 1538
02/18/2005 1147
02/28/2005 1)58
03/02/2005 1740
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedurea:
METHAL PREP ICP SM 3030C BDL 02/18/2005 1120
Davis & Floyd, Inc. 'f PO Drawer 428 J Greenwood, SC 29648 I Bl 6 E. Durst Avenue I Greenwood, SC 2~J649 I [phone] l fax (8fi4) 229-71 f 9
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Di\YIS
FLMD
Client
Contact
Client
Matrix
Para.Illeter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
Subcontract Work
AM20GAX
CARBON DIOXIDE
METHANE
Trace Metals
SW84.6 6010B T
IRON, TOTAL
MANGANESE, TOTAL
Wet ChCJ11istry
EPA 376.2
SULFIDE, TOTAL
SM 2320B
ALKALINITY, TOTAL
SW846 9056
NITRATE NITROGEN (AS NJ
SULFATE
SW846 9060
ORGANIC CARBON, TOTAL
ID:
Sample Comments: L05021802-02
LABORATORY ANALYSIS REPORT
NC Cenijication Number: 25
TICONA, LLC Project Number: 61621.03
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date March 15, 2005
Steve Olp Page 14 of 136 Report ID: AC690
U•38 Sample ID L05021802 ~ 02
Date Collected: 02/16/2005 1734
GW/Chemw Date Received 02/17/2005
Result Qual RDL Units Analyst Date Tiine
< 7.0 7.0 mg/1 JMT 02/22/2005 1240
76.0 0.60 mg/1 JL 02/24/2005 0000
0.0026 0 .000015 mg/1 JL 02/24/2005 0000
< 0.10 0.10 mg/1 BOL 02/24/2005 02]1
0. 054 0. 010 mg/1 BOL 02/24/2005 0231
< 0.050 0.050 mg/1 CDC 02/23/2005 1527
1.' 1.0 mg/1 MPM 02/23/2005 1549
0.91 0.10 mg/1 OHR 02/18/2005 1207
< 2.5 X 2.5 mg/1 OHR 03/01/2005 0932
< 1.0 1.0 mg/1 CDC 03/02/2005 1804
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METHAI, PREP I CP SM 3030C BOL 02/18/2005 1120
Davis & Floyd, Inc. :'I PO Drawer428 I Greenwood, SC 29648 I 816 E. Durst Avenue j Greenwood, SC 29649 I [phone] I fax [phone]
Dl\VIS
FLtfYD LABORATORY ANALYSIS REPORT
NC Certification Number: 25
Client TICONA, LLC Project Number: 61621.03
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date March 15, 2005
Contact Steve Olp Page 15 of 136 Report ID: AC690
Client ID: Q-33 Sample ID L05021802-03
Date Collected: 02/17/2005 1122 Matrix CW/Chemw Date Received 02/17/2005
Parameter Result Qual RDL Units Analyst D.i.te Time
Gaa Chromatography
SW846 8015
ETHYLENE GLYCOL < 7.0 7 .o mg/1 JMT 02/22/2005 1)11
Subcontract Work
AM20GAX
CARBON DIOXIDE 85,0 0.60 mg/1 RW 02/24./2005 0000
METHANE 0.048 o. 000015 mg/1 RW 02/24/2005 0000
Trace Metals
SW846 6010B T
IRON, TOTAL < 0.10 0 .10 mg/1 BOL 02/24/2005 0237
MANGANESE, TOTAL 0.091 0.010 mg/1 BOL 02/24./2005 0237
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL < o.oso 0. 050 mg/1 coc 02/23/2005 1528
SM 2320B
ALKALINITY, TOTAL 98.6 2.0 mg/1 MPM 02/2)/2005 1556
SW846 9056
NITRATE NITROGEN (AS N) 0.10 0.10 mg/1 OHR 02/18/2005 1306
SULFATE 91. 6 2.5 mg/1 DHR 02/18/2005 1325
SW846 9060
ORGANIC CARBON, TOTAL 1.' 1.0 mg/1 coc 03/03/2005 0909
sample Col!Wlents: L05021802-03
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METHAL PREP ICP SM 3030C BDL 02/18/2005 1120
Dav·1s & Floyd, lnc. :I PO Drawer 428 ] Greenwood, SC 29648 l 816 E. Durst Avenue j Greenwood, SC 29649 I (864) 229-441 3 I Fax [phone]
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DAYIS
FLtn'D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2 5 2 5 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
Client ID: DUP-2
Matrix
Parameter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
Subcontract Work
AM20GAX
CARBON DIOXIDE
METHANE
Trace Metals
SW846 6010B T
IRON, TOTAL
MANGANESE, TOTAL
Wet Chemistry
EPA 376.2
SUL FI DE, TOTAL
SM 2320B
ALKALINITY, TOTAL
S"1846 9056
NITRATE NITROGEN (AS N)
SULFATE
SW846 9060
ORGANIC CARBON, TOTAL
: GW/Chemw
Sample Comments: LOS021802-04
<
<
<
<
Result
,.o
88.0
0.048
0.10
0. 093
0.050
98.6
0.10
90.4
2. 3
Qual
NC Cenification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 16 of 136 Report ID: AC690
Sample ID L05021802-04
Date Collected: 02/17/2005 0000
Date Received
RDL
,.o
0.60
0.000015
0.10
0.010
0 .050
2.0
0.10
2. 5
1. 0
Units
mg/1
mg/1
rng/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
02/17/2005
\. Analyst
JMT
RW
RW
BOL
BOL
CDC
MPM
OHR
OHR
CDC
Date TUiie
02/22/2005 1342
02/24/2005 0000
02/24/2005 0000
02/24/2005 0243
02/24/2005 0243
02/23/2005 152 9
02/23/2005 1610
02/18/2005 1345
02/18/2005 1404
03/02/2005 1853
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
.Analytical Prep Procedures:
METHAL PREP I CP SM J0J0C BOL 02/18/2005 1120
I Davis & Floyd, Inc. ·r PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue j Greenwood, SC 2%49 I [phone] f Fax [phone]
DAYIS
FLtffD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
Client ID: J~29
Matrix
Parameter
Gas Chro~atography
SW846 8015
ETHYLENE GLYCOL
Subcontract Work
AM20GAX
CARBON DIOXIDE
METHANE
Trace Metals
SW846 6010B T
IRON, TOTAL
MANGANESE, TOTAL
Wot Cbe1nistry
EPA 376.2
SULFIDE, TOTAL
SM 2320B
ALKALINITY, TOTAL
SW846 9056
NITRATE NITROGEN (AS N)
SULFATE
SW846 9060
ORGANIC CARBON, TOTAL
GW/Chemw
SII.Illple Comments: L05021802-0S
<
Result
7.0
150
0.0089
0.10
0. 30
0. 050
957
19.2
40. 7
l. 6
Qual
NC Certification Number: 25
Project Number, 61621.03
Report Date
Page 17 of 136
March 15, 2005
Report ID: AC690
Sample ID LOS021802-0S
Date Collected: 02/17/2005 1358
Date Received
RDL Units
7.0
0.60
0.000015
0 .10
0.010
o.oso
2.0
.o
2 .s
1.0
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/l
mg/1
02/17/2005
Analyst
JMT
RW
RW
BDL
BDL
CDC
MPM
DHR
DHR
CDC
Date Time
02/22/2005 1413
02/24/2005 0000
02/24/2005 0000
02/24/2005 0249
02/24/2005 0249
02/23/2005 1530
02/23/2005 1Gl9
02/18/2005 1124
02/2B/2005 1615
03/03/2005 09)5
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METHA.L PREP ICP SM 3030C BDL 02/18/2005 1120
Davis & floyd, Inc. :1 PO Dr.iwer 428 I Greenwood, SC 2'.)641::1 I 816 E. Durst Avenue j Greenwoo·d, SC 29649 I [phone] I f,ix (ll64) 229-7119
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Di\YIS
FLMD LABORATORY ANALYSIS REPORT
NC Certification Number: 25
Client TICONA, LLC Project Number: 61621. 03
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date March 15, 2005
Contact Steve Olp Page 18 of 136 Report ID: AC690
Client ID: Dl.JF-3 Sample ID L05021802-06
Date collected: 02/17/2005 0000
Matrix GW/Chemw Date Received 02/17/2005
Parameter Result Qual RDL Units Analyst Date Time
Gas Chromatography
SW846 8015
ETI{YLENE GLYCOL < 7.0 7.0 mg/1 JMT 02/22/2005 1444
Subcontract Work
AM20GAX
CARBON DIOXIDE 150 0.60 mg/1 RW 02/24/2005 0000
METHANE 0.0086 0 . 000015 mg/1 RW 02/24/2005 0000
Trace Metals
SW846 6010B T
IRON, TOTAL < 0.10 0.10 mg/1 BDL 02/24/2005 02 54
MANGANESE, TOTJ\L o. JO 0.010 mg/1 BDL 02/24/2005 0254
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL < 0.050 0. 050 mg/1 CDC 02/23/2005 1531
SM 2320B
ALKALINITY, TOTAL ,Sl 6.7 mg/1 MPM 02/23/2005 1629
SW846 9056
NITRATE NITROGEN (AS N) H.9 0.50 mg/1 DHR 02/1B/2005 1542
SULFATE 40.0 2.5 mg/1 DHR 02/1B/2005 154 2
SW846 9060
ORG.W IC CARBON, TOTAL 1.' 1.0 mg/1 CDC 03/02/2005 1941
Sample C0111D1ents: L05021802-06
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METHAL PREP ICP SM 3030C BDL 02/18/2005 1120
I Davis & f-loyd, lnc. l PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] ! Fax (864) 229·7119
"
Di\YIS
FLfwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC
Steve Olp
28152
Client ID: W-23
Matrix
Paro.meter
Gas Chromatography
SWB<J6 8015
ETHYLENE GLYCOL
Subcontract Work
AM20GA.X
CARBON DIOXIDE
METHANE
Trace Metals
SWB-16 60108 T
IRON, TOTAL
MANGANESE, TOTAL
Wet ChCI11istry
EPA 376.2
SULFIDE, TOTAL
SM 2320B
ALKALINITY, TOTAL
SW846 9056
NITRATE NITROGEN (AS NJ
SULFATE
SW846 9060
ORGANIC CARBON, TOTAL
GW/Chemw
Sample Comments: L05021802-07
Result
7.0
190
0. 030
0.10
1.'
0.050
88.2
0.41
62.2
J.'
Qual
NC Cenification Number: 25
Project Number, 61621.03
Report oate March 15, 2005
Page 19 of 136 Report ID: AC690
Sample ID LOS021802-07
Date Collected: 02/17/2005 1548
Date Received
RDL
7.0
0.60
0. 000015
0.10
0. 010
o. 050
2.0
0.10
2.5
1.0
Units
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
02/17/2005
Analyst
JMT
RW
RW
BDL
BDL
CDC
MPM
OHR
DHR
CDC
Date Timo
02/22/2005 1515
02/24/2005 ODDO
02/24/2005 0000
02/24/2005 0312
02/24/2005 0312
02/23/2005 1532
02/23/2005 1638
02/18/2005 1602
02/18/2005 1621
0)/02/2005 2008
The subcontracted analyses were perfot·med by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METflAL PREP ICP SM 3030C BDL 02/18/2005 1120
Davis & Floyd, Inc. :1 PO Drawer 428 J Greenwood, SC 29648 / Bl 6 f. Durst Avenue ! Greenwood, SC 29649 l [phone] I Fax (B(i4) n 9-7 ii 9
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Dl-\YIS
FLtJfD LABORATORY ANALYSIS REPORT
Parameter
Subcontract Work
AM20GAX
CARBON DIOXIDE
METHANE
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
Client ID: TRIP BLANJ:
Matrix GW/ChemW
<
Silll\Ple COlflll'lents: LOS021802-08
Result
0.60
0.00054
Qual
NC Cenijication Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 20 of 136 Report ID, AC690
Sample ID L05021802-08
Date Collected: 02/14/2005 0910
Date Received
RDL
0.60
0.000015
Units
mg/1
mg/1
02/17/2005
Analyst
RW
RW
Date Ti.me
02/24/2005 0000
02/24/2005 0000
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
I 2297119 Davis & Floyd, Inc. 'I PO Drawer 428 I Greenwood, SC 2%48 I 816 E. Durst Avenue I Greenwood, SC 29649 l {8(J4) 2294413 I Fax (8li4l -
DAYIS
FLMD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC
Steve Olp
28152
Client ID: 0-25
Matrix
Parameter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOl,
Subcontract Work
AM20GAX
CARDON DIOXIDE
METHANE
Trace Metals
SW846 6010B T
IRON, TOTAL
MANGANESE, TOTAL
Wet CbClllistry
EPA 376.2
SULFIDE, TOTAL
SM 2320B
ALKALINITY, TOTAL
SW846 9056
NITRATE NITROGEN (AS NJ
SULFATE
SW846 9060
ORGANIC CARBON, TOTAL
GW/Chcmw
So.mple Comments: L05022006-0l
<
'
Result
7.0
44.0
0. 76
51. 4
0.42
0.050
70.2
0 .10
217
21.3
Qual
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 21 of 136 Report ID, AC690
Sample ID L0S022006-01
Date Collected: 02/18/2005 1100
Date Received
RDL Units
7.0
0.60
0.000015
0 .10
0. 010
0 .050
1.0
0.10
5.0
2.0
rng/1
mg/1
mg/!
mg/1
mg/!
mg/1
mg/1
mg/1
mg/1
mg/1
02/18/2005
Analyst
JMT
RW
RW
BDL
BDL
CDC
MPM
OHR
OHR
CDC
Date Time
02/22/2005 1822
02/24/2005 0000
02/24/2005 0000
02/28/2005 1914
02/28/2005 1914
02/25/2005 1013
02/2)/2005 164 7
02/19/2005 1627
02/19/2005 1745
03/03/2005 0106
Ttle subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METHAI, PREP ICP SM JOJOC BDL 02/21/2005 1700
Davis & Floyd, Inc. ·j' PO Or<1wer 428 I Greenwood, SC 29648 I H If> E. Durst Avenue I Greenwood, SC 2%49 ! (864} 229-4413 I Fax (Bfi4l 229-7119
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Df\YIS
FLtrfD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 2B152
Steve Olp
Client ID, IT-1
Matrix
Para.meter
Gas Chromatography
SW84.6 8015
ETHYLENE GLYCOL
Subcontract Work
AM20GAX
CARBON DIOXIDE
METHANE
Trace Metals
SW84.6 6010B T
IRON, TOTAL
MANGANESE, TOTAL
Wet Chemistry
EPA 376.2
SULF'IDE, TOTAL
SM 2320B
ALKALINITY, TOTAL
SW846 9056
NITRATE NITROGEN (AS NJ
SULFATE
SW846 9060
ORGANIC CARBON, TOTAL
GW/Chemw
Sample Comments: L05022006-02
'
'
'
'
Result
7.0
95.0
23.0
o.
0
0
156
2.1
050
167
.10
. 50
,.,
Qual
NC Cenification Number: 25
Project Number: 61621.03
Report Date March 15. 2005
Page 22 of 136 Report ID: AC690
Sample ID L05022006-02
Date Collected: 02/18/2005 1235
Date Received
RDL
7.0
0.60
0.000015
0.50
0.050
0. 050
4.0
0 .10
0 . 50
1.0
Units
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
02/18/2005
Analyst
JMT
RW
RW
BDL
BDL
CDC
MPM
OHR
OHR
CDC
Date Time
02/22/2005 1924
02/24/2005 0000
02/24/2005 0000
02/28/2005 1943
02/28/2005 1943
02/25/2005 1014
02/23/2005 1659
02/19/2005 1509
03/01/2005 0005
03/03/2005 0133
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METHAL PREP ICP SM 3030C BDL 02/21/2005 1700
I Davis & Floyd, Inc. ·j PO Drawer 428 I Greenwood, SC 29648 I 8 I 6 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax (B641229•7119
DAYIS
FLtfvD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG .ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
Client ID: F-55
Matrix
Para.JI1eter
Gas Chromatography
SWB-16 8015
ETHYLENE GLYCOL
Subcontract work
Af120GAX
CARBON DIOXIDE
MI>Tlw,.JE
Trace Metals
SW846 6010B T
IRON, TOTAL
MANGANESE, TOTAL
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL
SM 2320B
ALKALINITY, TOTAL
SW84.6 9056
NITRATE NITROGEN (AS N)
SULFATE
SW846 9060
ORGANIC CARBON, TOTAL
GW/ChemW
Sample Comments: L05022006~03
<
<
Result
5500
57.0
2.8
594
208
0.050
1200
0.50
1.'
4770
Qual
X
NC Certification Number: 25
Project Number: 61621.03
Report Date
Page 23 of 136
March 15, 2005
Report ID: AC690
Sample ID LOS022006-03
Date Collected: 02/18/2005 1355
Date Received
RDL Units
350
0.60
0.000015
5.0
a.so
0.050
4.0
o. 50
0 .so
500
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
02/16/2005
Analyst
JMT
RW
RW
BDL
BDL
CDC
MPM
DHR
DHR
CDC
Date Time
02/22/2005 2232
02/24/2005 0000
02/24/2005 0000
02/28/2005 2358
02/2B/2005 235B
02/25/2005 1015
02/23/2005 1?11
02/19/2005 1904
02/19/2005 1824
0)/0)/2005 0201
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METHAL PREP ICP SM 3030C BDL 02/21/2005 1700
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Dav;s & floyd, Inc. ·.-1 PO Drawer 4211 I Greenwood. SC 29648 I 8 I 6E. Durst Avenue I Greenwood, SC 29649 I [phone] I fax [phone] I
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DAYIS
FLtn'D LABORATORY ANALYSIS REPORT
NC Certification Number: 25
Client TICONA, LLC Project Number: 61621.03
2525 BLACKSBURG ROAD
HWY 198
SHELBY. NC 28152 Report Date March 15, 2005
Contact Steve Olp Page 24 o( 136 Report ID: AC690
Client ID: CC-33 Sample ID L05022006-04
Date Collected: 02/18/2005 1019
Matrix GW/ChemW Date Received 02/18/2005
Parameter Result Qual RDL Units Analyst Date Time
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL ' 7.0 7.0 mg/1 JMT 02/22/2005 2027
Subcontract Work
AM20GAX
CARBON DIOXIDE 75.0 0.60 mg/1 RW 02/24/2005 0000
METHANE 0.43 0 .000015 mg/1 RW 02/24/2005 0000
Trace Metals
SW846 6010B T
IRON, TOTAL 49.5 0. l 0 mg/1 BDL 02/28/2005 1955
MANGANESE, TOTAL 2.9 0. 010 mg/1 BDI, 02/28/2005 1955
. Wet CbClllistry
EPA 376.2
SULFIDE, TOTAL ' 0. 050 0.050 mg/1 CDC 02/25/2005 1016
SM 2320B
ALKALINITY, TOTAL 61.6 1.0 mg/1 MPM 02/23/2005 1751
SW846 9056
NITRATE NITROGEN (AS N} ' 0.10 0.10 mg/1 DHR 02/19/2005 1213
SULFATE 6. 0 0.50 mg/1 OHR 02/28/2005 2227
SW846 9060
ORGANIC CARBON, TOTAL 1. 2 1 . 0 mg/1 CDC OJ/03/200S 0224
Sample ~OJJllllents: L05022006-04
The subcontracted analyses were performed by MICROSEEPS, PittsOurg, PA.
Prep Procedure Method Analyst Prep Date
Analytical _Prep Procedures:
METHAL PREP ICP SM 3030C BDL 02/21/2005 1700
I Davis & Floyd, Inc. ··J PO Drawer 428 1 Greenwood, SC 29648 I 816 E. Durst Avenue ] Creenwoorl, SC 29649 I [phone] I Fax [phone]
D~IS
FLMD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
Client ID: N-29
Matrix
Parameter
Gae Chromatography
SWB4.6 8015
ETHYLENE GLYCOL
Subcontract Work
AM20GAX
CARBON DIOXIDE
METilANE
Trace Metals
SW846 6010D T
IRON, TOTAL
MANGANESE, TOTAL
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL
SM 2320B
ALKALINITY, TOTAL
SW84.6 9056
NITRATE NITROGEN (AS N)
SULFATE
SW846 9060
ORGANIC CARBON, TOTAL
GW/ChemW
Sample Co=ents: L05022006-05
Result
7.0
llO
0.95
0.10
0.20
o. 050
4.3
0.51
0.91
1.0
Qual
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 25 of 136 Report ID: AC690
Sample ID LOS022006-0S
Date Collected: 02/18/2005 1229
Date Received
RDL
7.0
0.60
0.000015
0. 10
0. 0 l 0
0.050
1.0
o. 10
0. 50
1.0
Units
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/l
mg/1
mg/1
02/18/2005
Analyst
JMT
RW
RW
BDL
BDL
CDC
MPM
DHR
DHR
CDC
Date Time
02/22/2005 2129
02/24/2005 0000
02/7.4/2005 0000
02/28/2005 2001
02/28/2005 2001
02/25/2005 1017
02/23/2005 1801
02/19/2005 1350
02/28/2005 2345
03/03/2005 0249
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METHAL PRF.P ICP SM 3030C BDL 02/21/2005 1700
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Davis & Floyd, Inc. :/ PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 j [phone] ) Fax [phone] I
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Di\YIS
FLtJ\:D LABORATORY ANALYSIS REPORT
Para.meter
subcontract Work
AM20GAX
CARBON DIOXIDE
METHANE
Client
Contact
TlCONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 2B152
Steve Olp
Client ID: TRIP BLANlC-2
Matrix GW/ChemW
<
SillIIPle Comments, L05022006-06
Result
0.60
0.0050
Qual
NC Cenification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 26 of 136 Report ID: AC690
Sample IO L05022006-06
Date Collected: 02/14/2005 0910
Date Received 02/18/2005
RDL
0.60
0.000015
Units
mg/1
mg/1
Analyst
RW
RW
Date Time
02/24/2005 0000
02/24/2005 0000
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
I Davis & Floyd, Inc. ·,t PO Drawer 428 I Greenwood, SC 29648 I 816 E. Dursl Avenue I Greenwood, SC 29649 I [phone] l Fax [phone]
DAYIS
FLtrYD LABORATORY ANALYSIS REPORT
Client
contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
Client ID: IT-9
Matrix
Parameter
Gas Chromatography
SW845 8015
ETHYLENE GLYCOL
subcontract Work
AM20GAX
CARBON DIOXIDE
METI!ANE
Trace Metals
SW845 60108 T
IRON, TOTAL
MANGANESE, TOTAL
wet Chamistry
El'A 376.2
SU!,F'J DE, TOTAL
SM 23208
ALKALINITY, TOTAL
SW846 9038
SULFATE
SW846 9056
NITRATE NITROGEN (AS N)
SW846 9060
ORGANIC CARBON, TOTAL
GW/Chemw
Sample CoDUnents: L05022301-0l
<
<
<
<
Result
7.0
200
20.0
74. 9
60.2
o. 050
364
) . 0
0.10
31.3
Qual
NC Certification Number: 25
Project Number: 61621.03
Report Date March IS, 2005
Page 27 of 136 Report ID, AC690
Sample ID L05022301-01
Date Collected: 02/22/2005 0953
Date Received
RDL
7.0
0.60
Q.000015
1.0
0.10
o. 050
4.0
l.0
0.10
2.5
Units
nig/1
mg/]
mg/1
mg/1
mg/1
mg/l
mg/1
mg/1
mg/1
02/22/2005
Analyst
JMT
SL
SL
BDL
BDL
CDC
MPM
OHR
OHR
CDC
Date Time
02/24/2005 1143
03/01/2005 0000
03/01/2005 0000
03/01/2005 0010
03/01/2005 0010
02/25/2005 l 018
02/23/2005 1814
03/11/2005 1018
02/23/2005 2023
03/03/2005 1749
The subcontracted analyses were performed by MICRDSEEPS, Pittsburg, PA.
Prop Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METHAL PREP ICP SM 3030C BDL 02/24/2005 1200
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DJvis & Floyd, Inc. t PO Drawer 428 I Greenwood, SC 29648 I 8 I 6 E. Durst Avenue I Greenwood, SC 29649 I [phone] ! Fax (a64) 229-7119 I
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Df\VIS
FLtJfD LABORATORY ANALYSIS REPORT
NC Certification Number: 25
Client TrCONA, LLC Project Number, 61621.03
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date March 15. 2005
Contact Steve Olp Page 28 of 136 Report ID: AC690
Client ID: IT-BR Sample ID L0S022301-02
Date Collected, 02/22/2005 1120
Matrix GW/Chemw Date Received 02/22/2005
Para.II1eter Result Qual RDL Units Analyst Date Time
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL 42.0 7.0 mg/1 JMT 02/24/2005 1245
Subcontract Work
AM20GAX
CARBON DIOXIDE 230 0.60 mg/1 JL 0)/01/2005 0000
METHANE l.6. 0 0 000015 mg/1 JL 03/01/2005 0000
Trace Metals
SW846 6010B T
IRON, TOTAL 404 1. 0 mg/1 BOL 02/28/2005 2 024
MANGANESE, TOTAL 46.6 0.10 mg/1 BOL 02/28/2005 2024
Wet CheJ11istry
EPA 376.2
SULFIDE, TOTAL 0.050 0.050 mg/1 coc 02/25/2005 1019
SM 2320B
Al.KALINITY, TOTAL 762 4.0 mg/1 MPM 02/23/2005 1825
SW846 9038
SULFATE 6.4 6.0 rng/1 OHR 03/11/2005 1027
SW846 9056
NITRATE NITROGEN {AS N) ' 0.10 0 .10 mg/1 OHR 02/23/2005 2102
SW846 9060
ORGANIC CARBON, TOTAL 413 12.S mg/1 coc 03/03/2005 1819
Sample Co=ents: L05022l01·02
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METHAL PREP ICP SM 3030C BOL 02/24/200S 1200
I Davis & Floyd, Inc. ·[-PO Drawer 428 I Greenwood, SC 29648 I 816 E. Dues! Avenue I Greenwood, SC 29649 I (864) 229-44 I 3 I Fax [phone]
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Cl icnc
Contact
Matrix
Parameter
Gas Cbrom.atography
SWB46 8015
ETHYLENE GLYCOL
Subcontract Work
AM20GAX
CARBOU DIOXIDE
METHANE
Trace Metals
SW846 6010B 7'
IRON, TOTAL
MANGANESE, TOTAL
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL
SM 2320B
AI,KALJNITY, TOTAL
SWB46 9038
SULF]\.TE
SW846 9056
NITRATE NITROGEN (AS NJ
SW846 9060
ORGANIC CARBON, TOTAL
TICONA, LLC
·2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
GW/ChemW
<
<
<
<
Sample Comments: LOS022301-03
Result
7.0
320 ,.,
64.0
7.4
o. 050
301
3. 0
0. l 0
7. 3
Qual
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 29 of 136 Report ID: AC690
Sample ID L05022301-03
Date Collected: 02/22/2005 1039
Date Received
RDL Units
7.0
0.60
0.000015
0. 10
.o. 010
0 .oso
4.0
3. 0
0.10
0.50
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
02/22/2005
Analyst
JMT
SL
SL
BDL
BDL
CDC
MPM
DHR
DHR
CDC
Date Time
02/24/2005 1348
03/01/2005 0000
03/01/2005 0000
02/2B/2005 2030
02/28/2005 2030
02/25/2005 1020
02/23/2005 1B34
03/11/2005 1035
02/23/2005 2300
03/03/2005 1B44
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METHAL PREP ICP SM 3030C BDL 02/24/2005 1200
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Davis & Floyd, Inc. :t PO Drawer 428 l Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 J (BU4) 229-4413 I Fax [phone] I
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Df\VIS
FLffi'D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
Client ID: IT-3
Matrix
ParilIIleter
Gas Chr0111atography
SW846 8015
ETHYLENE GLYCOL
Subcontract Work
AM20GAX
CARBON DIOXIDE
METHANE
Trace Metals
SW846 6010B T
IRON, TOTAL
MANGANESE, TOTAL
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL
SM 2320B
ALKALINITY, TOTAL
SW846 9038
SULFATE
SW846 9056
NITRATE NITROGEN (AS NJ
SW846 9060
ORGANIC CARBON, TOTAL
GW/Chemw
Sal!lple Comments: L05022301-04
<
<
<
<
Result
7.0
37.0
:.n. 0
54. B
o. 79
o. 050
207
3.0
0.10
LS
Qual
NC Certification Number: 25
Project Number, 61621.03
Report Date March 15, 2005
Page 30 of 136 Report ID, AC690
Sample ID L05022301-04
Date Collected: 02/22/2005 1245
Date Received
RDL
7.0
0.60
0.000015
0. 10
0.010
0.050
2.0
3.0
0.10
0.50
Units
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
02/22/2005
Analyst
JMT
SL
SL
BDL
BDL
CDC
MPM
OHR
OHR
CDC
Date Time
02/24/2005 1450
03/01/2005 0000
03/01/2005 0000
02/28/2005 2053
02/28/2005 2053
02/25/2005 1021
02/23/2005 1847
03/11/2005 1044
02/24/2005 0018
03/03/2005 1909
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method .Analyst Prep Date
.Analytical Prep Procedures:
METHAL PREP ICP SM 3030C BDL 02/24/2005 1200
I Davis & Floyd, Inc. 'j' PO Drawer 428 I Greenwood, SC 29648 l 816 E. Durst Avenue j Greenwood, SC 29649 I [phone] I Fax (864) 229·7119
Di\VIS
FLtJfD LABORATORY ANALYSIS REPORT
NC Cenijication Number: 25
Client TICONA, LLC Project Number: 61621.03
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date March 15, 2005
Contact Steve Olp Page 31 of 136 Report ID, AC690
Client ID: IT-7 Sample ID L05022301-05
Date Collected: 02/22/2005 1245
Matrix GW/Chemw Date Received 02/22/2005
Parameter Result Qual RDL Units Analyst Date Time
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL < 7.0 7.0 mg/1 JMT 02/24/2005 1552
Subcontract Work
AM20GAX
CARBON DIOXIDE 280 0.60 mg/1 SL 03/01/2005 0000
METHANE 14.0 0 .000015 mg/1 SL 03/01/2005 0000
Trace Metals
SW846 6010B T
IRON, TOTAL 122 0. 40 mg/1 BDL 02/28/2005 2059
r-w.1GANESE, TOTAL 25.7 0. 040 mg/1 BDL 02/28/2005 2059
Wet Chemistry
EPA J76.2
SULF'IDE, TOTAL < 0 .050 0.050 mg/1 CDC 02/25/2005 1022
SM 2320B
ALKALINITY, TOTAL 650 4.0 mg/1 MPM 02/23/2005 1855
SW846 9038
SULF'ATE 5.3 3.0 mg/1 DHR 03/11/2005 1057
SW846 9056
NITRATE NITROGEN (AS N) 0.10 0.10 mg/1 DHR 02/24/2005 0057
Sh'846 9060
ORGANIC CARBON, TOTAI., 37.2 2.5 mg/1 CDC 03/04/2005 084 1
Sample Comments: L0502230I~OS
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method ADalyst Prep Date
Analytical Prep Procedures:
METHAL PRF.P ICP SM 3030C BDL 02/24/2005 1200
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229~7119 I Davis & Floyd, Inc. ·.I PO Dr.iwcr 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I (8(J4) 229-4413 I Fax (B64)
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Df\VIS
FLOYD LABORATORY ANALYSIS REPORT
Parameter
Subcontract Work
AM20GAX
CARBON DIOXIDE
METHANE
Client
contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
Client ID, TRIP BLANK-3
Matrix GW/ChemW
<
SIUllple Comments: L05022301-06
Result
0.60
0.02:Z
Qual
NC Cer1ification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 32 of 136 Report ID: AC690
Sample ID L05022301-06
Date Collected: 02/14/2005 0910
Date Received
RDL
0.60
0.000015
Units
mg/1
mg/1
02/22/2005
Analyst
SL
SL
Date Time
03/01/2005 0000
03/01/2005 0000
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
I Davis & Floyd, Inc.: I PO Drawer 428 [ Greenwood, SC 29648 ] 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] j Fax (864) 229·7119
Df\YIS
FLMD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
Client ID: IT-6
Matrix
Parameter
Gas Chromatography
SW816 8015
ETHYLENE GLYCOL
Subcontract work
AM20GAX
CARBON DIOXIDE
METHANE
Trace Metals
SW846 6010B T
IRON, TOTAL
MANGANESE, TOTAL
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL
SM 2320B
ALKALINITY, TOTAL
SW846 9056
NITRATE NITROGEN (AS N)
SUU'ATE
SW846 9060
ORGANIC CARBON, TOTAL
GW/Chemw
Sample Comments: L05022402-01
'
Result
7.0
320 ,.,
1000
452
0.72
1720
0.50
12.9
2760
Qual
X
NC Cenification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 33 of 136 Report ID; AC690
Sample IO L05022402-0l
Date Collected: 02/22/2005 1645
Date Received
RDL
7.0
0.60
0.000015
10.0
1.0
0.050
20.0
0.50
2.5
250
Units
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/l
mg/1
mg/1
02/23/2005
Analyst
JMT
SL
SL
BDL
BDL
CDC
MPM
DHR
OHR
CDC
Date Time
02/2B/2005 1717
03/01/2005 0000
03/01/2005 0000
03/01/2005 0016
03/01/2005 0016
02/25/2005 1027
03/02/2005 1445
02/24/2005 1342
03/01/2005 014 3
03/03/2005 2053
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METilAL PREP ICP SM 3030C BDL 02/24/2005 1200
I
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Davis & Floyd, Inc. ·,( f'O Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue J Greenwood, SC 29649 I (864) 229-44 U I filX (864) 229-71 19 I
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DL\YIS
FLtwD LABORATORY ANALYSIS REPORT
NC Cenification Number: 25
Client TICONA, LLC Project Number: 61621.03
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date March 15, 2005
Contact Steve Olp Page 34 of 136 Report ID: AC690
Client ID: IT-4 Sample ID L05022402-02
Date Collected: 02/23/2005 1027
Matrix ' GW/ChemW Date Received 02/23/2005
Parat11eter Result Qual RDL Units Analyst Date Time
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL < 7.0 7.0 mg/1 JMT 02/28/2005 1410
Subcontract Work
AM20GAX
CARBON DIOXIDE 26.0 0.60 mg/1 SL 03/01/2005 0000
METHANE 13 .0 o. 000015 mg/1 SL 03/01/2005 0000
Trace Metals
SWB46 6010B T
IRON, TOTAL 70.3 0.10 mg/1 BDL 02/28/2005 2111
MANGANESE, TOTAL 1.2 0.010 mg/1 BDL 02/28/2005 2111
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL < 0 .050 0.050 mg/1 CDC 02/25/2005 1028
SM 23208
ALKALINITY, TOTA.L 110 2.0 mg/1 MPM 03/02/2005 1456
SW846 9056
NITRATE NITROGEN (AS N) < 0.10 0.10 mg/1 OHR 02/24/2005 1717
SULfA.TE < 2. 5 X 2.5 mg/1 DHR 03/01/2005 0340
SW846 9060
ORGANIC CARBON, TOTAL 6. 7 a.so mg/1 CDC 03/03/2005 2119
Sample Cotlllll.ents: L05022402-02
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METHAL PREP ICP SM 3030C BDL 02/24/2005 1200
I Davis & Floyd, lnc. ) PO Dcawer 428 I Greenwood, SC 29648 I 816 E. Du,st Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
Di\YIS
FLtfi'D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHEI,BY, NC 26152
Steve Olp
Client ID: IT-5
Matrix
Parrunuter
Gas Chromatography
SW846 8015
ETHYLE:NE GLYCOL
Subcontract Work
AM20GAX
CARBON DIOXIDE
METHANE
Trace Metals
SW846 6010B 1'
IRON, TOTAL
MAfJGANESE, TOTAL
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL
SM 2320B
ALK/1.LINITY, TOTAL
SW8'16 9056
NITRATE NITROGEN {AS N)
SULFATE
Sf-,'846 9060
ORGANIC CARBON, TOTAL
Sample Comments: LOS022402-03
GW/Chemw
<
<
Result
7.0
260
17.0
74. 6
3. 6
0. 069
709
o. 10
0 . 50
17.4
Qual
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 35 of 136 Report ID: AC690
Sample ID L05022402-03
Date Collected: 02/23/2005 1220
Date Received
RDL
7.0
0.60
0.000015
0. 10
0.010
0.050
4.0
0 . 10
0 .so
0.50
Units
mg/1
rrg/1
mg/1
rng/1
rrg/1
mg/1
mg/1
rrg/1
rrg/1
02/23/2005
Analyst
JMT
SL
SL
BDL
BDL
CDC
MPM
DHR
DHR
CDC
Date Time
02/28/2005 1512
03/01/2005 0000
03/01/2005 0000
02/28/2005 2117
02/29/2005 2117
02/25/2005 102 9
03/02/2005 150 9
02/24/2005 1520
03/01/2005 0320
03/03/2005 214 7
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analyticnl Prep Procedures:
METHAL PREP ICP SM 3030C BDL 02/24/2005 1200
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Davis & Floyd, Inc. ·j, PO Drawer 428 I Greenwood, SC 29648 / 816 E. Durst Avenue I Greenwood, SC 29649 j [phone] / Fax [phone] I
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DAYIS
FLtn'D
Client
Contact
Client ID:
Matrix
Parameter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
Subcontract Work
AM20GAX
CARBON DIOXIDE
METHANE
Trace Metals
SW846 60108 T
IRON, TOTAL
MANGANESE, TOTAL
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL
SM 2320B
ALKALINITY, TOTAL
SW846 9056
NITRATE NITROGEN (AS N)
SULFATE:
SW846 9060
ORGANIC CARBON, TOTAL
Sample Comments: L05022402-04
LABORATORY ANALYSIS REPORT
NC Certification Number: 25
TICONA, LLC Project Number: 61621.03
2 5 2 5 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date March 15, 2005
Steve Olp Page 36 of 136 Report ID: AC690
V-23 Sample ID L05022402-04
Date Collected: 02/23/2005 0945
GW/ChemW Date Received 02/23/2005
Result Qual RDL Units lulalyst Date Ti111e
674.0 280 mg/1 JMT 02/28/2005 1922
230 0.60 mg/1 SL 03/01/2005 0000
16 .o 0. 000015 mg/1 SL 03/01/2005 0000
1740 20. 0 mg/1 BDL 03/01/2005 007. l
772 2 .0 mg/1 BDL 03/01/2005 0021
< 0.050 0. 050 mg/1 CDC 02/25/2005 103 0
2800 8.0 mg/1 MPM 03/02/2005 1518
< 0.50 X 0.50 mg/1 DHR 02/24/2005 1914
75.1 2.5 mg/1 DIIR 03/01/2005 0400
10700 500 mg/1 CDC 03/03/2005 2002
The subcontracted analyses ~ere performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METH.AL PREP ICP SM JOJOC BDL 02/24/2005 1200
I Davis & Floyd, Jnc. ·/ PO Drawer 428 j Greenwood, SC 29648 I 816 E. Durst Avenue j Greenwood, SC 29649 I [phone] ! Fax [phone]
DAYIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
Client ID: V'-65
Matrix
Parameter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
Subcontract Work
AM20GAX
CARBON DIOXIDE
METHANE
Trace Metals
SW846 6010B T
IRON, TOTAL
l'-WJGANESE, TOTAL
Wet Chemistry
BPA 376.2
SULFIDE, TOTAL
SM 2320B
ALKALINITY, TOTAi,
SW846 9056
NITRATE NITROGEN (AS NJ
SULFATE
SW846 9060
ORGANIC CARBON, TOTAL
Sample COilllIICnts: L05022402-0S
GW/Chemw
Result
7.0
110
22.0
23.4
1. 2
0. 050
250
0. 10
1.1
1.1
Qual
NC Cenijicarion Numher: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 37 of 136 Report ID: AC690
Sample ID LOS022402-05
Date Collected: 02/23/2005 1120
Date Received
RDL
7.0
0.60
0.000015
0.10
0. 010
0 .oso
2.0
o. 10
0 . 50
0.50
Units
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
02/23/2005
A.Daly.st
JMT
SL
SL
BDL
BDL
CDC
MPM
DHR
DHR
CDC
Date Time
02/28/2005 1615
03/01/2005 0000
03/01/2005 0000
02/28/2005 2128
02/28/2005 2128
02/25/2005 1031
03/02/2005 1529
02/24/2005 203]
OJ/01/2005 0518
0)/0)/2005 2)51
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Pt·ep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METHAL PREP I CP SM 30JOC BDL 02/24/2005 1200
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Davis & Floyd, Jnc. · .. 1 PO Drawer 428 I Greenwood, SC 29648 I B 16 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fttx [phone] I
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D~IS
FLMD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
Client ID: FB-01
Matrix
Parameter
Gas Chromatography
SW84.6 8015
ETHYLENE GLYCOL
Subcontract Work
AM20GAX
CARBON DIOXIDE
METHANE
Trace Metals
SW846 601GB T
I ROtl, TOTAL
MANGANESE, TOTAL
Wet Chemistry
EPA J76.2
SULFIDE, TOTAL
SM 2320B
ALKALINITY, TOTAL
·SW846 9056
NITRATE NITROGEN (AS N)
SULFATE
SW846 9060
ORGANIC CARBON, TOTAL
: GW/Chemw
Sample Comments: L05022402-06
<
<
<
<
<
<
<
<
<
Result
7.0
0.60
0.022
0.10
0.010
0. 050
1. 0
0. 10
o. 50
0.50
Qual
NC Certification Number: 25
Project Number, 61621.03
Report Date March 15, 2005
Page 38 of 136 Report ID: AC690
Sample ID L05022402-06
Date Collected: 02/22/2005 1745
Date Received
RDL
7.0
0.60
0.000015
0. l 0
0. 010
0.050
1.0
0 . 10
0. 50
0.50
Units
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
02/23/2005
Anillyst
SL
SL
BDL
BDL
CDC
MPM
DHR
DHR
CDC
Date Time
02/28/2005 1339
03/01/2005 0000
03/01/2005 0000
02/28/2005 2134
02/28/2005 2134
02/25/2005 1032
03/02/2005 1541
02/24/2005 1500
03/01/2005 0301
03/04/2005 0014
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METIIAL PREP ICP SM 3030C BDL 02/24/2005 1200
Davis & Floyd, Inc. ·j PO Drawer 428 j Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I fax [phone]
DAYIS
FLtJ\7D LABORATORY ANALYSIS REPORT
NC Certification Number: 25
Client TICONA, LLC Project Number: 61621.03
2525 BLACKSBURG ROAD
HWY 198
SHEl,BY. NC' 28152 Report Date Murch 15, 2005
Contact Steve Olp Page 39 of 136 Report ID: AC690
Client ID: X-28 Sample ID L05022402-07
Date Collected: 02/22/2005 1715
Matrix GW/ChemW Date Received 02/23/2005
Para.meter Result Qual RDL Units Analyst Date Time
Gao Chromatography
SW846 8015
ETHYLENE GLYCOL 244 140 mg/1 JMT 02/28/2005 1819
Subcontract Work
AM20GAX
CARBON DIOXIDE 160 0.60 mg/1 SL 03/01/2005 0000
METHANE 16.0 0. 000015 mg/1 SL 0)/01/2005 0000
Traco Metals
SWB46 6010B T
IRON, TOTAL 613 1.0 mg/1 BDL 02/28/2005 2209
MANGANESE, TOTAL 10.5 0.10 mg/1 BDL 02/28/2005 2209
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL 0 .050 0.050 mg/1 CDC 02/25/2005 1033
SM 2320B
ALKALINITY, TOTAL 770 4.0 mg/1 MPM 03/02/:2005 1611
S1-1846 9056
NITRATE NITROGEN (AS NJ ' 0.10 0.10 mg/1 DHR 02/24/2005 1421
SULFATE ' 2.5 X 2.5 mg/1 OHR 03/01/2005 0222
SW846 9060
ORGANIC CARDON, TOTAL 60.4 12.5 mg/1 CDC 03/03/2005 2027
Sample Comments: L05022402-07
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Do.ta
A.nalytical Prep Procedures:
METHAI .. PREP ICP SM 3030C BDL 02/24/2005 1200
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Davis & Floyd, Inc. "I. PO Drawer 428 I Greenwood, SC 29648 j 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone] I
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DAYIS
FLtwD LABORATORY ANALYSIS REPORT
Para.meter
Subcontract Work
AfJ20GAX
CARBON DIOXIDE
METHANE
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
Client ID, TRIP BLANX-4
Matrix GW/Chemw
<
Sample Comments: L05022402-08
0.60
o.o:.io
Qual
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 40 of 136 Report ID: AC690
Sample ID LOS022402-08
Date Collected: 02/14/2005 0910
Date Received
RDL
0.60
0.000015
Units
mg/1
mg/1
02/23/2005
Analyst
SL
SL
Date Time
03/01/2005 0000
03/01/2005 0000
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
I Davis & Floyd, Inc. ·.1. PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax (B64) 229-7119
DAYIS
FLlwD LABORATORY ANALYSIS REPORT
Client : TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 2B152
Contact Steve Olp
NC Certificarion Number: 25
Project Number: 61621.03
Report Date
Page 41 of 136
March 15, 2005
Report ID: AC690
QC Summary Data
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Davis & Floyd, Inc. :.1 PO D,awe, 428 I G,eenwood, SC 29648 I 816 E. Du,st Avenue I G,eenwood, SC 29649 I [phone] I fax (864) 229·7119 I
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Di\YIS
FLbYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Repor-t Date
Page 42 of 136
March 15, 2005
Report ID: AC690
QC Batch Report -Batch Sample List
Sample J:D
LOS021802-01
LOS021802-02
L05021802-03
L05021802-04
L05021802-0S
L05021802-06
L05021802-07
LOS022006-0l
L05022006-02
L05022006-03
LOS022006-04
L05022006-0S
MB40367:l
LCS40367:l
MS05021802-07
WorkGroup WG40367
Description: GC/EG --0221JA
Client ID
TI-1
U-3B
Q-33
DUP-2
J-29
DUP-3
W-23
0-25
11·-1
F-55
CC-33
N-29
Method Blank
Laboratory Control
:40367 Matrix Spike
Spike
MSD05021802-07:40367 Matrix Spike Duplicate
1
1
1
1
Matrix GW/ChemW
Prep Method
Analtyical Method, SW846 8015
PREP J.NALYTICAL
Da.te TilDe Date Ti.Jne Alla.lyst
02/22/2005 1208 JMT
02/22/2005 1240 JMT
02/22/2005 1311 JMT
02/22/2005 1342 JMT
02/22/2005 1413 JMT
02/22/2005 1444 JMT
02/22/2005 1515 JMT
02/22/2005 1822 JMT
02/22/2005 1924 JMT
02/22/2005 2232 JMT
02/22/2005 2027 JMT
02/22/2005 2129 JMT
02/22/2005 1106 JMT
02/22/2005 1137 JMT
02/22/2005 1649 JMT
02/22/2005 1720 JMT
Dilution
1
1
1
1
1
1
50
1
1
l
I Davis & Floyd, Inc ·:f PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue j Greenwood, SC 29649 I [phone] l Fax [phone]
Df\VIS
FLtfi'D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 19B
SHELBY, NC 28152
Steve Olp
QC Batch Report -Method Blanks
WorkGroup: WG40367
Blank
Para.meter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
MB40367:l
Result Ou.al
< 7.0
NC Certification Number: 25
Project Number, 61621.03
Report Date March 15, 2005
Page 43 of 136 Report ID: AC690
Matrix: GW/Chemw
RDL Units Analyst Date Time
7.0 JMT 02/22/2005 1106
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Davis & Floyd, Inc. ·].PO Drawer 428 I Greenwood, SC 29648 I 816 [. Durst Avenue I Greenwood, SC 29649 I [phone] I Frlx (864} 229-7119 I
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DAYIS
FLtfi'D LABORATORY ANALYSIS REPORT
ETIIYLENE GLYCOL
ETI-lYLENE GLYCOL
Client
Contact
TJ:CONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 44 of 136 Report ID: AC690
QC Batch Report -Matrix Spikes and Duplicates
workGroup: WG40367 Matrix GW/ChemW
MS/MSD MS05021802-07:40367 Prep Method
MSD05021802-07:40367 Analtyical Method: SWB46 8015
50.00 < 7.00 48. 23 mg/1 96 57-158
50.00 52. 09 10, 8 24 57-158
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc.: I PO Drawer 428 J Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fc1x (864) 229·7119
DAYIS
FLMD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 45 of 136 Report ID, AC690
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup; WG40367 Matrix GW/ChemW
LCS LCS40367:1 Prep Method
Analtyical Method: SW846 8015
ETHYLENE GLYCOL 50.00 48.06 96 77-126
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Davis & Floyd, Inc. ·J PO Drawer 428 I Greenwood, SC 29648 j 816 E. Durst Avenue ] Greenwood, SC 29649 I (864) 229-441J I Fax [phone] I
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Di\YIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 46 of 136 Report ID, AC690
QC Batch Report -Batch Sample List
WorkGroup WG40432 Matrix GW/ChemW
Description: GC/EG --022(JA Prep Method
Analtyical Method: SW846 8015
PREP ANALYTICAL
Sample ID Client ID •=• Date Time Date TiD1e Analyst
L05022301-01 IT-9 02/24/2005 1143 JMT
LOS022301-02 IT-BR 02/24/2005 1245 JMT
L05022301-03 IT-2 02/24/2005 1348 JMT
L05022301-04 IT-3 02/24/2005 1450 JMT
L05022301-05 IT-7 02/24/2005 1552 JMT
MB40432: 1 Method Blank 02/24/2005 1041 JMT
LCS40432:l Laboratory Control Spike 02/24/2005 1112 JMT
MS05022301-04 :40432 Matrix Spike 02/24/2005 1726 JMT
MSD0502230l-04:40432 Matrix Spike Duplicate 02/24/2005 1828 JMT
Dilution
1
1
l
1
l
1
1
Davis & Floyd, Inc.· I PO Drawer 428 I Greenwood, SC 29648 j 816 E. Durst Avenue I Greenwood, SC 29649 I (864) 229-44 IJ / Fax [phone]
DAYIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TI:CONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
QC Batch Report -Method Blanks
workGroup: WG40432
Blank
Parilllleter
Gas Cbro=atography
SW846 8015
ETHYLENE GLYCOL
MB40O2 :1
Result Qual
7.0
NC Cenijication Number: 25
Project Number: 61621.03
Report Date
Page 47 of 136
Matrix: GW/Chemw
RDL Units
March 15, 2005
Report ID: AC690
Analyst Date Time
7.0 JMT 02/24/2005 1041
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Davis & floyd, Jnc. 'I. PO Drawer428 J Greenwood, SC 2%48 I 816 E. Durst Avenue l Greenwood, SC 29649 I [phone] l Fax (8b4J 229·7119 I
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DL\VIS
FL0\1D LABORATORY ANALYSIS REPORT
ETHYLENE GLYCOL
ETHYLENE GLYCOL
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 4B of 136 Report ID: AC690
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG40432 Matrix GW/ChemW
MS/MSD MS0502230l-04:40432 Prep Method
MSD05022301-04:40432 Analtyical Method: SW846 8015
50.00 < 7.00 49. 23 mg/1 98 57-158
50.00 47.14 mg/1 94 4 24
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. ·,t PO Drawer 428 I Greenwood, SC 29648 ] 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
Df\VIS
FLOYD LABORATORY ANALYSIS REPORT
ETHYLENE GLYCOl,
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date
Page 49 of 136
March 15, 2005
Report ID, AC690
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: wG40432 Matrix GW/Chemw
LCS LCS40432:l Prep Method
Analtyical Method: SW846 8015
50.00 47.78 mg/1 96 77-12 6
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Davis & floyd, Inc. ·.I PO Dr,1wer 428 J Greenwood, SC 29648 I ~ I 6 E. Durst Avenue ! Greenwood, SC 29649 I [phone] I Fax [phone] I
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Di-\YIS
FLlWD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number, 61621.03
Report Date March 15, 2005
Page 50 of 136 Report JD: AC690
QC Batch Report -Batch Sample List
workGroup WG(0465
Description: GC/EG --0228JA
Sample ID Client ID
LOS022402-01 IT-6
L0S022402-02 IT-4
L05022402-03, IT-5
L05022402-04 V-23
L05022402-05 V-65
L05022402-06 FB-01
I,050224 02-07 K-28
MB40465:l Method Blank
LCS40465:1 Laboratory Control Spike
MS050224 02 03 :40465 Matrix Spike
MSD05022402-03:40465 Matrix Spike Duplicate
1
1
1
Matrix GW/ChemW
Prep Method
Analtyical Method: SW846 8015
PREP ANALYTICAL
Date Time Date Time Analyst
02/28/2005 1717 JMT
02/28/2005 1410 JMT
02/28/2005 1512 JMT
02/28/2005 1922 JMT
02/28/2005 1615 JMT
02/28/2005 1339 JMT
02/28/2005 1819 JMT
02/28/2005 1237 JMT
02/28/2005 1308 JMT
02/28/2005 2127 JMT
02/28/2005 2229 JMT
Dilution
1
1
,o
1
20
1
1
I Davis & Floyd, Inc. '·j PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue j Greenwood, SC 29649 I [phone] I Fax {864) 229-ll 19
l'
DAYIS
FLtrfD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2S25 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
QC Batch Report -Method Blanks
WorkGroup: WG40465
Blank
Parameter
Gas ChrOJ11atography
SW846 8015
ETHYLENE GLYCOL
MB4.0465:l
Result Qual
7.0
NC Cenification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 51 of 136 Report ID, AC690
Matrix: GW/ChemW
RDL tJui ts Analyst· Date Time
7.0 mg/l JMT 02/28/2005 1237
Davis & Floyd, Inc. PO.Drawer 428 f Greenwood, SC 29648 / BI() E. Durst Avenue I Greenwood, SC 29649 / [phone] I Fax [phone]
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DAYIS
FLM:1D LABORATORY ANALYSIS REPORT
ETHYLENE GLYCOL
ETHYLENt GLYCOL
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 52 of 136 Report ID: AC690
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG40465 Matrix GW/Chemw
MS/MSD HS05022402-03:40465 Prep Method
MSD05022402-03:40465 Analtyical Method: SW846 8015
SO.DO < 7.00 54.36 mg/1 109 57-158
50.00 53.81 mg/1 108 24 57-158 I NOTE, MS/MSD \-recoveries are riot evaluated if the sample concentration is greater than four times the spike added.
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I Davis & Floyd, lnc. ~I PO Drawer 428 I Greenwood, SC 29648 I Bl 6 E. Durst Avenue j Greenwood, SC 29649 I [phone] ! Fnx /864) 229-7119
DAYIS
FLm'D LABORATORY ANALYSIS REPORT
ETifYLENE GLYCOL
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date
Page 53 of 136
March 15, 2005
Report ID, AC690
QC Batch Report -Laboratory Control Standards and Duplicates
workGroup: WG40465 Matrix GW/Chemw
LCS LCS40465:1 Prep Method
Analtyical Method, SW846 8015
50.00 49.15 mg/1 98 77-126
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D,vis & Floyd, Inc. 'I PO Drawer 428 I Greenwood, SC 29648 I 816 f. Durst Avenue I Greenwood, SC 2%49 I 1864) 229-4413 I fax [phone]·7119 I
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Di\YIS
FLbYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number.· 25
Project Number: 61621.03
Report Date March 15, 2005
Page 54 of 136 Report ID: AC690
QC Batch Report -Batch Sample List
WorkGroup Matrix GW/ChemW
Description: 3030C (5) Prep Method
Analtyical Method: SW846 60108 T
PREP ANALYTICAL
Sill!lple ID Client ro Run# Date Ti.me Date Time Analyst
L05021802-01 TI-1 1 02/24/2005 0226 BDL
L0S021802-02 U-38 02/24/2005 ()231 BDL
L05021802-03 Q-33 02/24/2005 023 7 BDL
L05021802-04 DUP-2 02/24/2005 0243 BDL
L05021802-05 J-29 02/24/2005 024 9 BDL
LOS021802-06 DUP-3 02/24/2005 0254 BDL
L05021802-07 W-23 02/24/2005 0312 BDL
MD40441:l Method Blank 02/24/2005 0214 BDL
LCS40441:l Laboratory Control Spike 02/24/2005 0220 BDL
MS05021802-07:40441 Matrix Spike 02/24/2005 0318 BDL
MSD05021802-07:40441 Matrix Spike Duplicate 02/24/2005 0323 BDL
Dilution
1
1
1
1
1
1
Davis & Floyd, Inc. PO Drawer 428 I Greenwood, SC 29648 I Bl 6 E. Durst Avenue I Greenwood, SC 29649 ! [phone] f Fax [phone]
'\
DAYIS
FLMD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HwY 198
SHELBY, NC 28152
Steve Olp
QC Batch Report -Method Blanks
WorkGroup: WG40441
Blank MB40441:l
Para.meter
Trace Metals
SW846 6010B T
IRON, TOTAL
MANGANESE, TOTAL
Prep Procedure
Analytical Prep Procedures1
METHAL PREP JCP
Method
SM ]OJOC
Result Qua]
0.10
0. 010
Analyst
BDL
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 55 of 136 Report ID: AC690
Matrix: GW/ChemW
RDL
0.10
0.010
Units
mg/1
mg/1
Prep Date
02/18/2005 1120
Analyst
BDL
BDL
Date Time
02/24/2005 0214
02/24/2005 0214
Davis & r-loyd, Inc. 'j' PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue ] Greenwood, SC 2%49 j [phone] I Fax [phone]
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Di-\YIS
FLtrYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLA.CKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Cenijication Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 56 of 136 Report ID: AC690
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG40441
MS/MSD MS05021802-07:40441
IRON, TOTAL
MANGANESE, TOTAL
IRON, TOTAL
MANGANESE, TOTAL
MSD05021B02-07:40441
1.00
0.100
1.00
0.100
Matrix GW/Chemw
Prep Method
Analtyical Method: SW846 60108 T
< 0.100 0. 984 mg/1
Not Evaluated -See Note Below.
1.01
2.00
mg/1
rrg/1
101
120
98 76-125
10
10
76-125
82-115
NOTE: MS/MSD t recoveries are not evaluated if the sample concentration is greater than four times the spike added.
I Davis & Floyd, Inc. I PO Drawer 428 j Greenwood, SC 29648 j 816 E. Durst Avenue I Greenwood, SC 29649 J [phone] I Fax (864) 2l9~?l 19
Dl\VIS
FLtn'D LABORATORY ANALYSIS REPORT
Client
Contact
Tl:CONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date
Page 57 of 136
March 15, 2005
Report ID; AC690
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG40441
LCS LCS40441:l
IRON, TOTAL
MANGANESE, TOTAL
2.00
0. 200
2.02
0.200
Matrix GW/Chemw
Prep Method
Analtyical Method: SW846 6010B T
mg/1
mg/1
101
100
89-111
87-110
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Davis & Floyd, Inc. .. ,. PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue j Greenwood, SC 29649 [ [phone] I F,1x [phone] I
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DAYIS
FLMD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Cenijication Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page SB of 136 Report ID: AC690
QC Batch Report -Batch Sample List
WorkGroup WG40442 Matrix GW/ChemW
Description, 3030C (5) Prep Method
Analtyical Method: SW846 6010B T
PREP ANALYTICAL
S8.ll!plC ID Client ID •=• Date Time Date Time Analyst
L0S022006-0l 0-25 02/28/2005 1914 BDL
LOS022006-02 IT-1 02/28/2005 194) BDL
LOS022006-03 F-55 02/28/2005 235B BDL
LOS022006-04 CC-33 02/28/2005 1955 BDL
LOS022006-05 N-29 02/28/2005 2001 BDL
MB40442:l Method Blank 1 02/28/2005 1902 BDI,
LCS40442:l Laboratory Control Spike 02/28/2005 1906 BDL
MS05022006-0l :40442 Matrix Spike 02/28/2005 1920 BDL
MSD05022006-01:40442 Matrix Spike Duplicate 02/28/2005 1925 BDL
Dilution
5
50
1
1
1
I Davis & Floyd, Inc. ··r PO Drawer 428 I Greenwood, SC 29648 I 816 E. Ours! Avenue j Greenwood, SC 29649 I [phone] I Fax [phone]
Dl\_YIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
QC Batch Report -Method Blanks
workGroup: WG40442
Blank
Para.meter
Trace Metals
SW846 6010B T
IRON, TOTAL
MAJlGANESE, TOTAL
Prep Procedure
Analytical Prep Procedures,
MET!lAL PREP ICP
MB40442:l
Method
SM 3030C
Result Qual
0.10
0.010
Analyst
BDL
NC Certification Number: 25
Project Number: 61621.03
Report Date
Page 59 of 136
Matrix: GW/Chemw
RDL
0.10
0.010
Units
mg/1
mg/I
Prep Date
02/21/2005 1700
March 15, 2005
Report ID: AC690
Analyst
BDL
BDL
Date Till:lc
02/28/2005 1902
02/2B/2005 1902
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Davis & r:loyd, Inc. ·r PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29&49 I [phone] I Fax [phone] I 9 I
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DAYIS
FLtJfD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 60 of 136 Report ID: AC690
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG-40442
MS/MSD MS05022006-01:40442
IRON, TOTAL
MANGANESE, TOTAL
IRON, TOTAL
MANGANESE, TOTAL
MSD05022006-01:40442
1.00
0.100
1. 00
0. 100
Matrix GW/Chemw
Prep Method
Analtyical Method: SW846 60108 T
Not Evaluated -See Note Below.
0. 419 0. 521 102 82-115
Not Evaluated See Note Below.
0.519 mg/1 100 0 10 82 115
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
I Davis & Floyd, Inc. :I PO Drawer42B I Greenwood, SC 29648 I 816 E_ Durst Avenue ! Greenwood, SC 29649 j [phone] I Fax [phone]
Df\VIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number, 61621.03
Report Date March 15, 2005
Page 61 of 136 Report ID: AC690
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG40442
LCS LCS40442,l
IRON, TOTAL
MANGANESE, TOTAL
2.00
0.200
1.90
0 .187
Matrix GW/ChemW
Prep Method
Analtyical Method: SWB46 6010B T
mg/1
mg/1
95
94
89-111
87-110
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Davis & Floyd, Inc. I' PO Drawer 428 f Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 j {864) 229-4413 I Fax [phone] I
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Dl\YIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 62 of 136 Report ID: AC690
QC Batch Report -Batch Sample List
WorkGroup WG40485 Matrix GW/Chemw
Description: JOJOC (5) Prep Method
Analtyical Method: SW846 60108 T
Sample :ID Client ID
PREP
Date Time
ANALYTICAL
Date Time Analyst Dilution
L050223 01-01
L05022301-02
L05022301-03
LOS022301-04
L05022301-05
L05022402-0l
L05022402-02
L05022402-03
L05022402-04
L05022402-0S
L05022402-06
L05022402-07
D05022301 03:40485
MB40485:l
LCS40485:l
MS05022402 06:40485
MSD05022402-06:40485
IT-9
IT-BR
IT-2
IT-3
IT-7
IT-6
IT-4
IT-5
V-23
V-65
FB-01
K-28
Duplicate
Method Blank
Laboratory Control Spike
Matrix Spike
Matrix Spike Duplicate
03/01/2005
1 02/26/2005
02/26/2005
02/28/2005
02/28/2005
03/01/2005
1 02/28/2005
02/28/2005
03/01/2005
1 02/28/2005
02/28/2005
02/28/2005
02/28/2005
02/28/2005
02/2 B/2005
02/2B/2005
1 02/28/2005
0010
2024
2030
2053
2059
0016
2111
2117
0021
2128
2134
2209
2036
2006
2012
214 0
214 6
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BOL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
10
10
100
1
200
10
Davis & Floyd, Inc PO Drawer428 I Greenwood, SC 29648 I 816 E. Durst Avenue j Greenwood, SC 29649 I [phone] I Fax (864) 229-ll l9
Df\YIS
FLMD LABORATORY ANALYSIS REPORT
Client
Contuct
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
QC Batch Report -Method Blanks
workGroup: WG40485
Blank
Parameter
Trace Metals
SW846 60108 T
IRON, TOTAL
MANGANESE, TOTAL
Prep Procedure
Analytical Prep Procedures:
MET!IAL PREP ICP
MB40485:1
Method
SM 3030C
Result
< 0.10
< 0. 010
Analyst
BDL
NC Certificalion Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 63 of 136 Report ID: AC690
Matrix: GW/Chemw
RDL
0. 10
0.010
Units
mg/1
mg/1
Prep Date
02/24/2005 1200
Analyst
BDL
BDL
Date Time
02/28/2005 2006
02/28/2005 2006
Davis & rloyd, Inc. PO Drawer 428 [ Greenwood, SC 2%46 ] 81 & E. Durst Avenue I Greenwood, SC 29649 I [phone] j Fax [phone]
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D1\YIS
FLtlYD LABORATORY ANALYSIS REPORT
Client
contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Cenification Number: 25
Project Number, 61621.03
Report Date
Page 64 of 136
March 15, 2005
Report ID: AC690
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG40485
MS/MSD MS05022402-06:40485
IRON, TOTAL
MANGANESE, TOTAL
IRON, TOTAL
MANGANESE, TOTAL
MSD05022402-06:40485
1.00
0 .100
1.00
0 .100
< 0.100
< 0.0100
0.957
0. 09l0
Matrix GW/Chemw
Prep Method
Analtyical Method: SWB46 60108 T
0.958
0.0920
mg/1
mg/1
mg/1
mg/1
96
93
96
92
0
76-125
82-115
10
10
76-125
82-115
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
I Davis & Floyd, Inc. ·1· PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 [ (864} 229-4413 I Fax [phone]
\
D1\YIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number, 61621.03
Report Date March 15, 2005
Page 65 of 136 Report ID: AC690
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG40485
I,CS LCS40485: l
IRON, TOTAL
1'-WJGANESE, TOTAL
2.00
0. 200
2.02
0. 215
Matrix GW/ChcmW
Prep Method
Analtyical Method: SW846 6010B T
mg/l
rrg/1
101
108
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Davis & Floyd, Inc. ·1 PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue J Greenwood, SC 29649 I [phone] I fax [phone] I
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Df\VIS
FLtffD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621. 03
Report Date
Page 66 of 136
March 15, 2005
Report ID: AC690
QC Batch Report -Sample Duplicates
workGroup: WG40t85
Duplicate, D05022301-03:40485
IRON, TOTAL
MANGANESE, TOTAL
64 .00
7.43
69.00
8.01
Matrix GW/ChemW
Prep Method
Analtyical Method: SW846 6010B T
0 10
0.010
mg/1
mg/1
8
8
10
10
NOTE: Calculation of \RFD is not required for concentrations less than lOX the RDL.
Davis & Floyd, Inc. PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] l fax (8(,4) 229-7119
D1\VIS
FLtlYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 67 of 136 Report ID: AC690
QC Batch Report -Batch Sample List
WorkGroup WG40490 Matrix GW/ChemW
Description: Sulfide Prep Method
Analtyical Method: EPA 376.2
Sill!lplc ID Client ID •=#
PREP
Date Time
ANALYTICAL
Date Tilne Analyst Di1ution
LOS021802-01 Tl-1
L05021802-02 U-38
L05021802-03 Q-33
L05021802-04 DUP-2
LOS021802-05 J-29
LOS021802-06 OUP-3
L05021802-07 W-23
MB40490:l Method Blank
MB40490:2 Method Blank
LCS40490:1 Laboratory Control Spike
LCS40490:2 Laboratory Control Spike
MS05022009-03:40490 Matrix Spike
MS05022009-09:40490 Matrix Spike
MS005022009-03:40490 Matrix Spike Duplicate
MSD05022009-09:40490 Matrix Spike Duplicate
02/23/2005 l 52 6
02/23/2005 1527
02/23/2005 1528
02/23/2005 1529
02/23/2005 153 0
02/23/2005 1531
02/23/2005 1532
02/23/2005 153 9
02/23/2005 1548
02/23/2005 1538
02/23/2005 154 7
02/23/2005 1536
02/23/2005 1545
02/23/2005 153 7
02/23/2005 1546
CDC
CDC
CDC
CDC
CDC
CDC
CDC
CDC
CDC
CDC
CDC
CDC
CDC
CDC
CDC
1
1
1
1
1
Davis & Floyd, Inc. ··r PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue j Greenwood," SC 29649 I [phone] J rax [phone]
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DAYIS
FLtJ\7D LABORATORY ANALYSIS REPORT
Parameter
Wet ChCllliStry
EPA 376.2
SULFIDE, TOTAL
Client
contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
QC Batch Report -Method Blanks
WorkGroup: WG40490
Blank MB40490:1
Result Qual
0.050
NC Certijica1ion Number: 25
Project Number, 61621.03
Report Date March 15, 2005
Page 68 of 136 Report ID: AC690
Matrix: GW/ChemW
RDL Units Analyst Date Time
0.050 mg/1 CDC 02/23/2005 1539
I Davis & Floyd, Inc. ··1 PO Drawer 428 j Greenwood, SC 29648 I 816 E. Durst Avenue J Greenwood, SC 29649 ] [phone] I Fax (864) 229·7119
Df\¥1S
FLMD LABORATORY ANALYSIS REPORT
Parameter
Wet Ch~iotry
EPA J76.2
SULFIDE, TOTAL
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
QC Batch Report -Method Blanks
workGroup: WG40490
Blank MB40H0:2
Result Qual
0.050
NC Certifica1ion Number: 25
Project Number: 61621.03
Report Date
Page 69 of 136
Matrix: GW/ChemW
RDL Units
March 15, 2005
Report ID, AC690
An'alyst Date Time
o. 050 mg/1 CDC 02/23/2005 1518
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Davis & Floyd, Inc. ··1· PO Orawer428 l Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] J Fc1x [phone] I
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D1\YIS
FLtwD LABORATORY ANALYSIS REPORT
SULFIDE, TOTAL
SULFIDE, TOTAL
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 19B
SHELBY, NC 28152
Steve Olp
NC Cenification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 70 of 136 Report ID: AC690
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG40490
MS/MSD MS05022009-03:40490
MSD05022009-03:40490
0.670
0.670
< 0.0500
0 623
Matrix GW/Chemw
Prep Method
Analtyical Method: EPA 376.2
B9 88-113
mg/1 93 5 10 88-113 I NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
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I Davis & Floyd, Inc. ·r PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
D1\VIS
FLtwD LABORATORY ANALYSIS REPORT
SULFIDE, TOTAL
SUl,FIDE, TOTAL
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 71 of 136 Report ID, AC690
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG40490 Matrix GW/ChemW
MS/MSD MSOS022009-09:40490 Prep Method
MSD05022009-09:40490 Analtyical Method: EPA 376.2
0.670 < 0.0500 0.609 mg/1 91 8B-113
0. 670 0.618 92 10 88-113
NOTE: MS/MSD \ recoveries ill"C not evaluated if the sample concentration is greater than [our times t;he spike added.
Davis & Floyd, Inc. ··1 PO Drawer 428 I Greenwood, SC 29648 j 816 £,. Durst Avenue I Greenwood, SC 29649 l (U(i4) 229-4413 / fax [phone]
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Df\YIS
FLtffD LABORATORY ANALYSIS REPORT
SULFIDE, TOTAL
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Cenification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 72 of 136 Report ID: AC690
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG40490 Matrix GW/ChemW
LCS LCS4049D:1 Prep Method
Analtyical Method: EPA 376.2
0. 500 0. 490 mg/1 98 90-110
I Davis & Floyd, Inc.· 'f PO Drawer 428 I Greenwood, SC 29648 l 81 & E. Durst Avenue j Greenwood, SC 29649 I [phone] I Fc1x [phone]
Di\YIS
FLMD LABORATORY ANALYSIS REPORT
SULFIDE, TOTAL
Client
Contact
TJ:CONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Cenijication Number: 25
Project Number: 61621.03
Report Date
Page 73 of 136
March 15, 2005
Report ID: AC690
QC Batch Report -LaboraJory Control Standards and Duplicates
WorkGroup: WG40490 Matrix GW/ChemW
LCS LCS40490:2 Prep Method
Analtyical Method: EPA 376.2
0.500 0. 490 mg/1 98 90-110
.·. -(4 2:297119 Davis&Floyd,lnc:. J PODrawer428 I Grccnwood,SC29648 I 816E.DurstAvenue j Greenwood,SC29649 I (864}229-4413 I 1·.ix(B, 1 -
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Df\YIS
FLtrfD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15. 2005
Page 74 of 136 Report ID: AC690
QC Batch Report -Batch Sample List
WorkGroup WG40515 Matrix GW/Chemw
Description, Sulfide Prep Method
Analtyical Method: EPA 376.2
PREP ANALYTICAL
sample ID Clieut ID •=• Date Ti.Jne Date Time Analyst
L05022006-0l 0-25 02/25/2005 1013 CDC
L05022006-02 rr-1 02/25/2005 1014 CDC
L05022006-03 F-55 02/25/2005 1015 CDC
L05022006-04 CC-33 02/25/2005 l 016 CDC
L05022006-05 N-29 02/25/2005 1017 CDC
L05022301-0l I'I'-9 1 02/25/2005 1018 CDC
L05022301-02 IT-SR 02/25/2005 1019 CDC
L05022301-03 IT-2 02/25/2005 1020 CDC
L05022301-04 IT-3 02/25/2005 1021 CDC
L05022301-0S IT-7 02/25/2005 1022 CDC
L05022402-0l IT-6 02/25/2005 1027 CDC
L05022402-02 IT-4 1 02/25/2005 1028 CDC
LOS0224 02-03 IT-5 02/25/2005 1029 CDC
L05022402-04 V-23 02/25/2005 1030 CDC
L05022402-05 V-65 02/25/2005 103 1 CDC
L05022402-06 FB-01 02/25/2005 1032 CDC
L05022402-07 K-28 02/25/2005 1033 CDC
MB40515:l Method Blank 02/25/2005 1026 CDC
MB40515:2 Method Blank 02/25/2005 1037 CDC
LCS40515: 1 Laboratory Control Spike 02/25/2005 1025 CDC
LCS40515; 2 Laboratory Control Spike 02/25/2005 1036 CDC
MS05022301-05 :40515 Matrix: Spike 02/25/2005 1023 CDC
MS05022402-07:40515 Matrix Spike 02/25/2005 1034 CDC
MSD05022301-05 :40515 Matrix Spike Duplicate 02/25/2005 1024 CDC
MSD05022402-07 :40515 Matrix Spike Duplicate 02/25/2005 1035 CDC
Dilution
1
1
1
1
1
1
1
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1
I Davis & Floyd, Inc.: l PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I {864) 229-4413 I fax [phone]
DL\VIS
FLtrfD LABORATORY ANALYSIS REPORT
Parameter
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL
Client
contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY. NC 28152
Steve Olp
QC Batch Report -Method Blanks
WorkGroup: WG40515
Blank MB40515:1
Result Qual
< Q.050
NC Certification Number: 25
Project Number, 61621.03
Report Date
Page 75 of 136
Matrix, GW/Chcmw
RDL Unito
March 15, 2005
Report ID: AC690
Analyst Date Time
0.050 mg/1 CDC 02/25/2005 1026
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Dav;, & Floyd, Inc.' I PO Drawe, 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 2%49 I 1864) 229-4413 I fax [phone]·7119 I
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D/U11S
FLtwD LABORATORY ANALYSIS REPORT
Parameter
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL
Client
Contact
TlCONA, LLC
2525 BLACKSBURG ROAD
HWY 19B
SHELBY, NC 28152
Steve Olp
QC Batch Report -Method Blanks
WorkGroup: WG40515
Blank MB40515:2
Result Quil.l
' 0.050
NC Cenification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 76 of 136 Report 10: AC690
Matrix: GW/ChemW
RDL vnits Analyst Date Time
0.050 mg/1 CDC 02/25/2005 1037
I Davis & Floyd, Inc. ··r PO Drawer 428 I Greenwood, SC 29648 [ 816 E. Durst Avenue I Greenwood, SC 29649 l {864) 229-4413 I fax [phone]
D}\VIS
FLtwD LABORATORY ANALYSIS REPORT
SULFIDE, TOTAL
SUI.FIDE, TOTAL
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY .198
SHELBY, NC 28152
Steve Olp
NC Cenification Number: 25
Project Number, 61621.03
Report Date
Page 77 of 13 6
March 15, 2005
Report ID: AC690
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG40515 Matrix GW/ChemW
MS/MSD MS05022301-05:40515 Prep Method
MSD05022301-05:40515 Analtyical Method; EPA 376.2
0.670 < 0.0500 0.623 mg/1 93 88-113
0.670 0. 656 mg/1 98 5 JO 88-113
NOTE: MS/MSD l n'.!COveries are not evaluated if the sample concentration is greater than four t.imes the spike added.
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Dav;, & Floyd, Inc. 'l PO Drawer 428 I Greenwood, SC 2%48 I 81 b E. Durst Avenue I Greenwood, SC 2%49 I (864) 229-44 t J I fax [phone]·7119 •.
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DAJ[IS
FLtfYD LABORATORY ANALYSIS REPORT
SULFIDE, TOTAL
SULFIDE, TOTAL
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HW"f 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number, 61621.03
Report Date March 15, 2005
Page 78 of 136 Report ID: AC690
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG40515 Matrix GW/ChemW
MS/MSD MS05022402-07:4051S Prep Method
MSD05022402-07:40515 Analtyical Method: EPA 376.2
0.670 < 0.0500 0.649 97 88-113
0.670 0. 663 mg/1 99 2 10 88-113
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
I Davis & Floyd, Inc. .:I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 j [phone] I Fax (864) 229·7119
Di\YIS
FLM1D LABORATORY ANALYSIS REPORT
SULFIDE, TOTAL
client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD.
HWY 198
SHELBY, NC 28152
Steve Olp
NC CenijicaJion Number: 25
Project Number: 61621. 03
Report Date
Page 79 of 136
March 15, 2005
Report ID: AC690
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG40515 Matrix GW/Chemw
LCS LCS40515:l Prep Method
Analtyical Method: EPA 376.2
0.500 0.524 mg/1 105 90-110
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Davis & Floyd, Jnc. ·1 PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue l Greenwood, SC 29649 I [phone] I Fax [phone] I
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Di\VIS
FLtfi'D LABORATORY ANALYSIS REPORT
SULFIDE, TOTAL
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Cenijication Number: 25
Project Number: 61621.03
Report Date March 15, 200s
P,,ge 80 of 136 Report ID: AC690
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG40515 Matrix GW/ChemW
LCS LCS40515:2 Prep Method
Analtyical Method: EPA 376.2
o.soo 0. 481 mg/1 96 90-110
I Davis & Floyd, Inc.' I PO Drawer 428 I Greenwood, SC 29648 I 816 [. Du,st Avenue I Greenwood, SC 29649 I (864) 229-44 I 3 I fax [phone]
Di\YIS
FLM'D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date
Page 81 of 136
March 15, 2005
Report ID: AC690
QC Batch Report -Batch Sample List
WorkGroup WG40513 Matrix GW/Chemw
Description, Total Alkalinity Matrix S Prep Method
Analtyical Method: SM 2320B
PREP ANALYTICAL
Sample ID Client ID R=# Date Time Date Tillie Analyst
L05021802-01 TI-1 02/23/2005 1538 MPM
I,05021802-02 U-38 02/23/2005 1549 MPM L05021802-03 Q-33 02/23/2005 1556 MPM L05021802-04 DllP-2 02/23/2005 1610 MPM L05021802-05 J-29 02/23/2005 1619 MPM
L05021802-06 DUP-3 02/23/2005 1629 MPM
L05021802-07 W-23 02/23/2005 1638 MPM
L05022006-0l 0-25 02/23/2005 1647 MPM
L05022006-02 IT-I 02/23/2005 1659 MPM
LOS022006-03 F-55 02/23/2005 1711 MPM
LOS022006-04 CC-33 02/23/2005 1751 MPM
L05022006-05 N-29 02/23/2005 1801 MPM
L05022301-01 IT-9 02/23/2005 1814 MPM
L05022301-02 IT-BR 02/23/2005 1825 MPM
LOS022301-03 IT-2 02/23/2005 1834 MPM
L05022301-04 IT-3 02/23/2005 1847 MPM
L05022301-05 IT-7 02/23/2005 18 55 MPM
D05021802-06:40513 Duplicate 02/23/2005 1722 MPM
D05022006-0S : 4 0513 Duplicate 02/23/2005 1911 MPM
MB40513:1 Method Blank 02/23/2005 1512 MPM
LCS40513: 1 Laboratory Cont:r,ol Spike 02/23/2005 1739 MPM
LCS40Sl3:2 Laboratory Control Spike 02/23/2005 1955 MPM
Dilution
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Davis & Floyd, Inc. "} PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue J G~eenwood, SC 29649 I [phone] I Fax [phone] I
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D1\YIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
QC Batch Report -Method Blanks
Parameter
Wet Chemistry
SH 2J2DB
workGroup: WG40513
Blank MB40513:1
ALKALINITY, TOTAL
Result Qual
1.0
NC Cenijication Number: 25
Project Number: 61621.03
Report Date
Page 82 of 136
Matrix: GW/Chemw
RDL units
March 15, 2005
Report ID: AC690
Analyst Date Timo
1.0 mg/1 MPM 02/23/2005 1512
I Davis & Floyd, Inc.· =1 PO Drawer 428 I Greenwood, SC 29648 [ 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] f F.ix (864) 229-71 l 9
Di\YIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
keport Date
Page 83 of 136
March 15, 2005
Report ID: AC690
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG40513 Matrix GW/ChemW
I.CS LCS40513,l Prep Method
Analtyical Method: SM 2320B
ALKALINITY, TOTAL 994. 0 967. 0 mg/1 97 89-103
Davis & Floyd, Inc. "t PO Drawer 428 I Greenwood, SC 2%48 J 816 E. Durst Avenue I Greenwood, SC 2%49 I [phone] I F<1x (8b4l 229·7119
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Di\YIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2 5 2 5 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 84 of 136 Report ID, AC690
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG40513 Matrix GW/ChernW
LCS LCS40513:2 Prep Method
Analtyical Method, SM 2320B
ALKALINITY, TOTAL 994. 0 957.5 mg/1 96 89-103
I Davis & Floyd, Inc. '1 PO Drawer 428 I Greenwood, SC 29648 I 81 b E, Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
Df\YIS
FL6YD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLA.CKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number; 61621.03
Report Date
Page 85 of 136
March 15, 2005
Report 1D: AC690
QC BaJch Report -Sample Duplicates
WorkGroup: WG40513 Matrix GW/Chernw
Duplicate, D05021802-06:40513 Prep Method
Analtyical Method: SM 23208
ALKALINITY, TOTAL 951.2 954.3 6.7 0 10
NOTE: Calculation of \RPO is not required for concentrations less than lOX the RDL.
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Davis & Floyd, Inc.·:! PO Drawer428 j Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I {864) 229-4413 ! Fax (864) 229·7119 I
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DAYIS
FLMD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 86 of 136 Report ID: AC690
QC Batch Report -Sample Duplicates
WorkGroup: WG40513 Matrix GW/Chemw
Duplicate: D05022006-05:40513 Prep Method
Analtyical Method: SM 2320B
ALKALINITY, TOTAL 4.27 4.27 1.0 mg/1 10
NOTE: Calculation of %.RPD is not required for concentrations less than !OX the RDL.
I Davis & Floyd, Inc. l'PO D,awe, 428 I G,eenwood, SC 29648 I 816E, Dtnst Avenue I G,eenwood, SC 29649 I (8641229-4413 I Fax [phone]
Di\YIS
FLtn'D LABORATORY ANALYSIS REPORT
Srunple ID
L05022402 01
L050224 02-02
L05022402-03
L05022402-04
L05022402-0S
L05022402-06
L0S022402-07
D05022406-01
D05022406-05
MB40519:l
l,CS40519:
LCS40519: 2
Davis & Floyd, Inc.
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Cenification Number: 25
Project Number: 61621.03
Report Date
Page 87 of 136
March 15, 2005
Report ID: AC690
QC Batch Report -Batch Sample list
WorkGroup WG40519: Matrix GW/ChcmW
Description: Total Alkalinity Matrix 5 Prep Method
Analtyical Method: SM 23208
PREP ANALYTICAL
Client XO R=# Date Time Date Time Analyst
IT-6 03/02/2005 1445 MPM
IT-4 03/02/ioos 1456 MPM
IT-5 03/02/2005 1509 MPM
V-23 03/02/2005 1518 MPM
V-65 03/02/2005 1529 MPM
FB-01 03/02/2005 1541 MPM
K-28 03/02/2005 1611 MPM
:40519 DupJicate 03/02/2005 1701 MPM
:40519 Duplicate 03/02/2005 1 910 MPM
Method Blank 03/02/2005 1409 MPM
Laboratory Control Spike 03/02/2005 1729 MPM
Laboratory Control Spike 03/02/2005 1921 MPM
Dilution
1
1
1
PO Drawer 428 / Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 j {864} 229-4413 I Fax [phone]
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Df\YIS
FLtJfD LABORATORY ANALYSIS REPORT
Client
Contact
T:ICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
QC Batch Report -Method Blank~
workGroup, WG40519
Blank
Para.meter
Wet Chemistry
SM 2320B
ALKALINITY, TOTAL
MB40519:l
Rotiult Qual
1.0
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page BB of 136 Report ID, AC690
Matrix: GW/ChemW
RDL Units Analyst Date
1.0 rng/1 MPM 03/02/2005 1409
I Davis & Floyd, Inc ... ·[ PO Drawer 428 I Greenwood, SC 29648 l 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
Df\VIS
FLtn'D LABORATORY ANALYSIS REPORT
Client
Contact
TJ:CONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15, 200s
Page 89 of 136 Report ID: AC690
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WGt0519 Matrix GW/Chemw
LCS LCS405U:l Prep Method
Analtyical Method: SM 2320B
ALKALINITY, TOTAL 991.0 967.0 mg/1 98 89-103
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Davis & Floyd, Inc. ·1· PO Drawer428 I Grc-enwood, SC 29648 I 816 E. Durst Avenue l Greenwood, SC 29649 I [phone] I Fax [phone] I
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D1\VIS
FLtiYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLA.CKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number, 61621.0J
Report Date March 15, 2005
Page 90 of 136 Report ID: AC690
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG405l9 Matrix GW/ChemW
LCS LCS40519:2 Prep Method
Analtyical Method: SM 2320B
ALKALINITY, TOTAL 991. 0 957.5 rng/1 97 89-103
•. Davis & Floyd, lnc. ':I PO Drawer 428 [ Greenwood, SC 29648 I 816 E. Durst Avenue l Greenwood, SC 29649 j {864) 229-4413 l Fax [phone]
DL\VIS
FLtJfD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 91 of 136 Report ID: AC690
QC Batch Repo,t -Sample Duplicates
WorkGroup: WG40519 Matrix GW/Chemw
Duplicate: D05022406-01:40519 Prep Method
Analtyical Method: SM 23208
ALKALINITY, TOTAL 343.2 343.2 2.0 mg/1 0 10
NOTE: Calculation of 1-RPD is not required for concentrations less than lOX the RDL.
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Davis & Floyd, Inc.· i PO Drawer 428 I Greenwood, SC 29648 j 816 E. Durst Avenue I Greenwood, SC 29649 I (864) 229-44 I 3 I f,1x [phone] I
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Df\VIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 26152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 92 of 136 Report ID: AC690
QC Batch Report -Sample Duplicates
WorkGroup: WG40519 Matrix GW/ChemW
Duplicate, DOS022406-05:40519 Prep Method
Analtyical Method: SM 23208
ALKALINITY, TOTAL 0.00 0. 474 l.O mg/1 10
NOTE: Calculation of \RPO is not required for concentrations less than lOX the RDL.
I Davis & Floyd, Inc. ~, PO Drawer 428 I Greenwood, SC 29648 J 816 E. Durst Avenue I Greenwood, SC 29649 I (864} 229-4413 I Fox (864) 229-71 l<J
DAYIS
FLtfYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve 01p
NC Cenification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 93 of 136 Report ID, AC690
QC Batch Report -Batch Sample List
WorkGroup WG40599 Matrix GW/ChemW
Description, Sulfate GW Prep Method
Analtyical Method: SW846 9038
Samplo ID Client ID •=#
PREP
Date Time
ANALY'.I'ICAL
Date Ti.ulc Analyst Dilution
L05022301-0l IT-9
I.05022301-02 IT-BR
L05022301-03 IT-2
LOS0✓.2301-04 IT-3
L05022301-0S IT-7
MR40599:l Method Blank
LCS4 0599: 1 Laboratory Control Spike
MS0502230l-04 :40599 Matrix Spike
MSD05022301-04:40599 Matrix Spike Duplicate
1 03/11/2005 l 018
03/11/2005 1027
03/11/2005 1035
1 03/11/2005 1044
03/11/2005 1057
1 OJ/11/2005 1146
1 OJ/11/2005 1140
1 03/11/2005 1107
03/11/2005 1117
OHR
OHR
OHR
OHR
OHR
DHR
DUR
OHR
OHR
2
1
.11
. 11
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,Davis & Floyd, Inc. ''t PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 J [phone] j Fax {8641 229·7119 I
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Df\VIS
FLtn'D LABORATORY ANALYSIS REPORT
Parameter
Wet Chem.is try
SW846 9038
SULFATE
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
QC Batch Report -Method Blanks
WorkGroup: WG40599
Blank MB40599,1
Result Qual
' 3.0
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 94 of 136 Report ID: AC690
Matrix, GW/ChemW
RDL Units Analyst Date Time
3.0 mg/1 DHR 03/11/2005 1146
I Davis & Floyd, Inc.·· 1 PO Drawer 428 I Greenwood, SC 29648 j 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
D1\VIS
FLMD LABORATORY ANALYSIS REPORT
SULFATE
Client TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
contact · Steve Olp
NC Certification Number: 25
Project Number: 61621. 03
Report Date
Page 95 of 136
March 15, 2005
Report ID: AC690
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG40599 Matrix GW/ChemW
MS/MSD MS05022301-04:40599 Prep Method
MSD05022301-04:40599 Analtyical Method: SW846 903B
11. 10 < 3.00 10. 31 mg/1 93 70-130
11. 10 10.10 mg/! 91 2 20 70-130
NOTE: MS/MSD l recoveries are not evaluated if the sample concentration is greater than four times the spike added.
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Davis & Floyd, Inc .. ·r PO Drawer 428 I Greenwood, SC 29648 j 816 E. Durst Avenue I Greenwood, SC 29649 I (864) 229-441.1 I Fax {864) 229-7119 I
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Dl\_VIS
FLtiYD LABORATORY ANALYSIS REPORT
Client
contact
TICONA, LLC
2525 BLA.CKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number, 61621.03
Report Date March 15, 2005
Page 96 of 136 Report ID: AC690
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG40599 Matrix GW/Chemw
LCS LCS40599:l Prep Method
Analtyical Method: SWB46 9038
I. Davis & Floyd, Inc. "'i PO Drawer 428 j Greenwood, SC 29648 l 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax (864) 229•7119
DAYIS
FLtJfD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 97 of 136 Report ID: AC690
QC Batch Report -Batch Sample List
workGroup WG40364 Matrix GW/ChemW
Description: IC RUN GW Prep Method
Analtyical Method: SW846 9056
ANALYTICAL
Samplo ID Client ID •=•
PREP
Date Time Date Time Analyst Dilution
LOS021802-0l TI-1
L05021802-0l Tl-1
L050218 02-02 U-38
LOS021802-02 U-38
LOS021802-03 Q-33
LOS021802-0J Q-33
LOS021802•04 DUP-2
LOS021802-04 DUP-2
L0S021802-0S J-29
L05021802-05 J-29
LOS021802-06 DUP-3
LOS021802-07 W-23
LOS021802-07 W-23
MB40364: 1 Method Blank
MB40364:2 Method Blank
LCS40364: 1 Laboratory Control Spike
LCS40364:2 Laboratory Control Spike
MS05021802-02:40364 Matrix Spike
MS05021806-07:40364 Matrix Spike
MSD0502l802-02 :40364 Matrix Spike Duplicate
MSD05021806-07 : 4 OJ 64 Matrix Spike Duplicate
02/18/2005 1147
2 02/28/2005 1358
02/18/2005 1207
2 03/01/2005 0932
02/18/2005 1306
2 02/18/2005 1325
02/18/2005 1345
2 02/18/2005 14 04
02/18/2005 1424
2 02/28/2005 1615
02/18/2005 1542
02/18/2005 16 02
2 02/18/2005 1621
02/18/2005 1128
02/28/2005 1240
02/18/2005 1108
02/28/2005 1339
02/18/2005 122 6
02/28/2005 2148
02/18/2005 1246
02/28/2005 2207
DHR
DHR
DHR
OHR
OHR
Dl!R
OHR
DHR
OHR
DHR
DHR
DHR
D1-!R
DJIR
OHR
DHR
DHR
DHR
DHR
DHR
OHR
1
1
5
1
s
5
10
5
5
s
1
. 05
. 05
.OS
. 05
Davis & Floyd, Inc. TPO Drawer 428 j Greenwood, SC 29648 I 816 E. Ours! Avenue I Greenwood, SC 29649 / [phone] I Frix fB 64l 229-7119
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DL\VIS
FLfWD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2 5 2 5 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
QC Batch Report -Method Blanks
WorkGroup: WG40364
Parameter
Wet Chemistry
sws4,:; 9056
Blank
NITRATE NITROGEN (AS N)
SULFATE
MB(0364: 1
<
<
Result Qual
0.10
1.0
NC Cenification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 98 of 136 Report ID: AC690
Matrix: GW/ChemW
RDL
0 .10
1.0
Units
mg/1
mg/1
Analyst
OHR
DHR
Date Time
02/18/2005 1128
02/18/2005 1128
I Davis & Floyd, Inc. .. I 'po Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I fax [phone]
DAYIS
FLMD LABORATORY ANALYSIS REPORT
Parameter
Wet Chemistry
SWB46 9056
CHLORIDE, TOTAL
SULFATE
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
QC Batch Report -Method Blanks
WorkGroup: WG40364
Blank MD40364:2
Result Qual
0.50
0 50
NC Cenification Number: 25
Project Number: 61621.03
Report Date
Page 99 of 136
Matrix: GW/Chemw
RDL
0.50
0.50
Units
mg/1
mg/1
March 15, 200s
Report ID: AC690
Analyst
DHR
DHR
Date Time
02/28/2005 1240
02/28/2005 1240
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Davis & Floyd, Inc. ~.! PO Drawer 428 I Greenwood, SC 29648 j 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone] I
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Di\YIS
FLtJfD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 100 of 136 Report ID: AC690
QC Batch Report-Matrix Spikes and Duplicates
WorkGroup: WG-40364 Matrix GW/ChemW
MS/MSO MS05021802-02:40364 Prep Method
MSD05021802-02:40364 Analtyical Method: SWB46 9056
NITRATE NITROGEN (AS N) 5.25
NITRATF. NITROGEN (AS N) 5.25 5. 89 mg/1 ., 3 10 80-115
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than [our times the spike added.
I Davis & Floyd, Inc.·· I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Dursl Avenue I Greenwood, SC 29649 j [phone] I Fax (~64) 229·7119
Di\YIS
FLMD LABORATORY ANALYSIS REPORT
CHLORIDE, TOTAL
SULFATE
CHLORIDE, TOTAL
SULFATE
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 1518
SHELBY, NC 28152
Steve Olp
NC Cenification Number: 25
Project Number, 61621.03
Report Date
Page 101 of 136
March 15, 2005
Report ID: AC690
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG40364
MS/MSD MS05021806-07,40364
MSD05021806-07:40364
5.25
5.25
5.25
5.25
3.37
2.60
7. 93
6.97
Matrix GW/Chemw
Prep Method
Analtyical Method: SW846 9056
8.16
7. 40
mg/1
mg/1
mg/1
mg/1
87
83
91
91
3
6
10
10
85 131
74 135
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Oav·1s & Floyd, Inc. -r 'po Drawer 428 I Greenwood, SC 29648 I 816 F.. Durst Avenue I Greenwood, SC 29649 I [phone] f Fax W64l 229-7119
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Di\YIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY. NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date : March 15, 2005
Page 102 of 136 Report ID: AC690
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG40364
LCS LCS40364:1
NITRATE NITROGEN (AS N)
SULFATE
5.00
25. 00
5.07
26. 35
Matrix GW/Chemw
Prep Method
Analtyical Method: SW846 9056
mg/1
mg/1
101
105
95-105
95-105
I Davis & Floyd, lnc. -[ PO Drawer 428 I Greenw(X)d, SC 29648 I 816 £. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
Di\YIS
FLMD LABORATORY ANALYSIS REPORT
CHLORIDE, TOTAL
SULFATE
Client
Contact
TICONA, LLC
2525 BLA.CKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number, 61621.03
Report Date March JS, 2005
Page 103 of 136 Report ID, AC690
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG40364
LCS LCS40364:2
10.00
25.00
9.73
24.35
Matrix GW/ChemW
Prep Method
Analtyical Method: SW846 9056
mg/1
mg/1
97
97
95-105
95-105
Davis & Floyd, Inc. -! PO Drawer428 [ Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, .SC 29649 I [phone] I Fax W64l 229-7119
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Dl\YIS
FLtJ\'D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 19B
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 104 of 136 Report ID: AC690
QC Batch Report -Batch Sample List
WorkGroup WG4043J Matrix GW/ChemW
Description: IC RUN GW Prep Method
Analtyical Method: SW846 9056
PREP ANALYTICAL
Sample ID Client ID Run# Date Time Date Time AD.a.lyst
L05022301-0l IT-9 02/23/2005 2023 DHR
L05022301-02 IT-BR 02/23/2005 2102 DHR
L05022]01-03 IT-2 02/23/2005 2300 DHR
L0S022301-04 IT-3 02/24/2005 0018 DHR
LOS022301-05 IT-7 02/24/2005 0057 Dl!R
MB40433:l Method Blank 02/23/2005 2004 DHR
LCS40433: 1 Laboratory Control Spike 1 02/23/2005 194'1 DHR
MS05022301 02:40433 Matrix Spike 02/23/2005 2141 DHR
MSD05022301-02:40433 Matrix Spike Duplicate 02/23/2005 2221 DHR
Dilution
1
1
1. 05
.05
I Davis & Floyd, Inc.' ·i PO Drawer 428 J Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 l [phone] I Fax (864) 229·7119
DAYIS
FLMD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
QC Batch Report -Method Blanks
Parameter
Wet Chemistry
SW846 9056
WorkGroup: WG40433
Blank MB40433:l
NITRATE NITROGEN (AS N)
Result Qual
0.10
NC Certification Number: 25
Project Number: 61621.03
Report Date
Page 105 of 136
Matrix, GW/ChemW
RDL Units
March 15, 2005
Report ID: AC690
Analyst Date Time
0.10 mg/1 DHR 02/23/2005 2004
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Davis & Floyd, lnc. ·1 PO Drawer428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I {864) 229-4413 I Fax {864) 229-7119 I
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D1\VIS
FLtJfD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Cenification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 106 of 136 Report ID: AC690
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup, WG40433 Matrix GW/Chemw
MS/MSD MS0502230l-02:40433 Prep Method
MSD05022301-02:40433 Analtyical Method, SW846 9056
NITRATE NITROGEN (AS N) 5.25 < 0 .100 4.75 90 80-115
NITRATE NITROGEN (AS N) 5.25 4.79 mg/1 91 10 80-115
NOTE: MS/MSD l recoveries are not evaluated if the sample concentration is greater than fou1· times the spike added.
I Davis & Floyd, Inc. '1 PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue 1 Greenwood, SC 29649 I (864) 229-441 J j Fax [phone]
DAJ!IS
FLOVD LABORATORY ANALYSIS REPORT
Client:
contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Cenification Number: 25
Project Number: 61621.03
Report Date
Page 107 of 136
March 15, 2005
Report ID: AC690
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG40433 Matrix GW/ChemW
LCS LCS40433:1 Prep Method
Analtyical Method: SW846 9056
NITRATE NITROGEN (AS N) 5.00 5.06 101 95-105
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Davis & Floyd, Inc.· I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 2%49 I [phone] I Fax (864) 229·7119 I
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Df\YIS
FLtrfD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number, 61621.03
Report Date March 15,'2005
Page 108 of 136 Report 1D: AC690
QC Batch Report -Batch Sample List
WorkGroup WG-40451 Matrix GW/Chemw
Description, IC RUN GW Prep Method
Analtyical Method: SW846 9056
PREP ANALYTICAL
Sample ID Client ID Run# Date Time Date Time Analyst
L0S022402-0l IT-6 02/24/2005 1342 OHR
L05022402-01 IT-6 2 03/01/2005 0143 DHR
L0S022402-02 IT-4 02/24/2005 1717 OHR
L05022402·02 IT-4 2 03/01/2005 0340 OHR
L0S0224 02-03 JT-5 1 02/24/2005 1520 OHR
L0S0224.02-03 IT-5 2 03/01/2005 0320 OHR
LOS022402-04 V-23 1 02/24/2005 1914 OHR
L05022402-04 V-23 2 03/01/2,005 0400 OHR
LOS022402-05 V-65 02/24/2005 2033 OHR
L05022402-05 V-65 2 03/01/2005 0518 OHR
L05022402-06 FB-01 1 02/24/2005 1500 OHR
LOS022402-06 FB-01 2 03/01/2005 0301 OHR
L05022402-07 K-28 02/24/2005 14 21 OHR
L05022402-07 K-28 2 03/01/2005 0222 OHR
MB40451: 1 Method Blank 1 02/24/2005 1223 OHR
MB40451:2 Method Blank 03/01/2005 0024 DHR
MB40451:3 Method Blank 03/08/2005 1621 OHR
LCS40451: 1 Laboratory Control Spike 1 02/24/2005 1204 DHR
LCS40451: Laboratory Control Spike 1 OJ/01/2005 0044 DHR
LCS40451: ) Laboratory Control Spike 03/08/2005 1540 OHR
MS050224 06-02 :40451 Matrix Spike 02/24/2005 2131 OHR
MS05022406-02 :40451 Matrix Spike 2 03/01/2005 0617 OHR
MS05022407-0S :40451 Matrix Spike 02/25/2005 0146 OHR
MS050224.07-05 :40451 Matrix Spike 2 03/08/2005 2134 OHR
MSOOS022406-02:40451 Matrix Spike Duplicate 02/24/2005 2151 OHR
MSOOS022406-02:40451 Matrix Spike Duplicate• 2 03/01/2005 0636 OHR
MSD05022407-05:40451 Matrix Spike Duplicate 02/25/2005 0205 OHR
Dilution
5
5
5
1
1
5
5
1
1
5
1
. 05
5
1. 05
. 05
.05
5
.05
I Davis & Floyd, Inc. ··1 PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax (864) 229·7119
DAYIS
FLtn'D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
QC Balch Report -Method Blanks
WorkGroup, WG40451
Blank
Parameter
Wet CbClllistry
SW846 9056
CHLORIDE. 'l'OTJ\L
NITRATE NITROGEN (AS N)
NITRITF. NITROGEN (AS N)
MB40451:1
'
'
Result Qual
a.so
0 .10
0 .10
NC Cenification Number: 25
Project Number: 61621.03
Report Date
Page 109 of 136
Matrix: GW/ChemW
RDL
0.50
0.10
0.10
Units
mg/1
m9/1
mg/1
March 15, 2005
Report ID; AC690
Analyst
DHR
OHR
DHR
Date Time
02/24/2005 1223
02/24/2005 122]
02/24/2005 1223
Davis & Floyd, Inc:."] f'O Drawer 428 I Greenwood, SC 29()48 I 816 E. Dursl Avenue I Greenwood, SC 29649 I (8(J4) 229-4413 I Fax (8(,4) 229-7119
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D/WIS
FLm'D LABORATORY ANALYSIS REPORT
Parameter
Wet CheJD.istry
SW846 9056
CHLORIDE, TOTAL
SULFATE
Client
contact
TICONA, LLC
2525 BLA.CKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
QC Batch Report-Method Blanks
workGroup: WG40451
Blank MB40451:2
<
<
o.so
0.50
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 110 of 136 Report 1D: AC690
Matrix: GW/ChemW
RDL
o.so
0.50
Units
mg/1
mg/1
Analyst
OHR
OHR
Date Time
03/01/2005 0024
03/01/2005 0024
I Davis & Floyd, Inc. "I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Dues! Avenue I Greenwood, SC 29649 I [phone] I Fa, [phone]
.
'
Df\YIS
1FLtf¥D LABORATORY ANALYSIS REPORT
Parameter
Hct Chemistry
SW846 9056
SULFATE:
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
QC Batch Report -Method Blanks
WorkGroup: WG40451
Blank MB40451:3
Result Oual
0.50
NC Certification Number: 25
Project Number: 61621. 03
Report Date
Page 111 of 136
Matrix: GW/Chemw
RDL Units
March 15, 2005
Report ID: AC690
Analyst Date Time
0.50 mg/1 DHR 03/08/2005 1621
O;ivis & Floyd, Inc. ··] PO Dr;:iwer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] ! Fax (MJ4) 229-7119
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Df\VIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
T:ICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number, 61621.03
Report Date March 15, 20_05
Page 112 of 136 Report ID: AC690
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG40451 Matrix GW/ChemW
MS/MSD MS05022406-02:40451 Prep Method
MSD05022406-02:404Sl Analtyical Method: SW846 9056
CHLORIDE, TOTAL 25.00 Not Evaluated -see Note Below.
CHLORIDE, TOTAL 5.25 Not Evaluated See Note Below.
NITRATE NITROGEN {AS N) 5.25 ' 0. 100 4.70 mg/1 90 80-115
NITRITE !HTROGEN {AS N) 5.25 o. 170 4.86 mg/1 89 80-114
SULFATE 25. 00 Not Evaluated -See Note Below.
CHLORIDE, TOTAL 25.00 Not Evaluated -See Note Below.
CHLORIDE, TOTAL 5.25 Not Evaluated -See Note Below.
NITRATE NITROGEN {AS N) 5.25 4 .70 mg/1 90 0 10
NITRITE NITROGEN {AS N) 5. 25 4.84 mg/1 89 0 10
SULFATE 25.00 Not Evaluated -see Note Below.
80-115
80-114
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
I Davis & Floyd, Inc. ·-1 PO Drawer 428 I Grnenwoo<l, SC 29648 [ 816 E. Durst Avenue I Greenwood, SC 29649 j [phone] I filX [phone]
Di\YIS
l?LlWD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Cenification Number: 25
Project Number: 61621 .OJ
Report Date March 15, 2005
Page 113 of 136 Report ID: AC690
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG404Sl
MS/MSD MS05022407-05:40451
OILORIDE, TOTAL
NITRATE NITROGEN (AS N)
NITRITE NITROGEN (AS N)
SULFATE
CHLORIDE, TOTAL
NITRATE NITROGEN (AS N)
NITRITE NITROGEN {AS N)
MSD05022407-05:40451
5. 25
5 . 25
5 . 25
5 .25
5.25
5. 25
5.25
'
5.65
0. 2B0
0.100
0.00
10.60
5 .17
5.02
Matrix GW/ChemW
Prep Method
Analtyical Method: SWB46 9056
10.51
5.06
4.91
18. 34
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
94
93
96
93
91
94
76
1
2
2
85-131
80-115
80-114
74-l] 5
10
10
10
85-131
80-115
80-114
NOTB, MS/MSD \-recoveries are not evaluated if the sample concentration is greater than (our times the spike added.
Davis & Floyd, Inc. ··] PO Drawer 428 f Greenwood, SC 29648 j 816 E. Durst Avenue I Greenwood, SC 29649 I (H64) 229-4413 I Fax [phone]
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Df\VIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
T:ICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 2Bl52
Steve Olp
NC Cenification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 114 of 136 Report ID: AC690
QC Batch Report -Laboratory Control Standards and Duplicates
workGroup: WG40451
LCS LCS40451:1
CHLORIDE, TOTAL
NITRATE NITROGEN {AS N)
NITRITE NITROGEN (AS N)
10.00
5.00
5.00
9.79
5.04
4.77
Matrix GW/Chemw
Prep Method
Analtyical Method: SW846 9056
mg/1
mg/1
mg/1
98
101
95
95-105
95-105
95-105
I Davis & Floyd, Inc. 'f PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] 1 Fax {864) 229-7119
Di\YIS
FLbYD LABORATORY ANALYSIS REPORT
OILORIDE, TOTAL
SULFATE
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number, 61621.03
Report Date : March 15, 2005
Page 115 of 136 Report !D: AC690
QC Batch Report -Laboratory Control Standards and Duplicates
workGroup: WG40451
LCS LCS40451:2
10.00
25.00
9.53
23.73
Matrix GW/ChemW
Prep Method
Analtyical Method: SW846 9056
mg/1
mg/1
95
95
95-105
95-105
Davis & floyd. Inc •i PO Drawer 428 I Creenwood, SC 29648 I 81 GE. Ours! Avenue I Greenwood, SC 29649 I [phone] I fax (8f,4) 229-71 19
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Di\VIS
FLtfi'D LABORATORY ANALYSIS REPORT
SULFATE
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date : March 15, 2005
Page 116 of 136 Report ID: AC690
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG40451 Matrix GW/ChemW
LCS LCS404Sl:3 Prep Method
Analtyica] Method: SW846 9056
25.00 24.77 mg/1 99 95-105
I Davis&Floyd,lnc. ·] P0Drawer428 j Creenwood,SC29648 I 816E.Durs1Avenue I Greenwood,$(29649 I [phone] I Fax[phone]
' '
Di\VIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date
Page 117 of 136
March 15, 2005
Report ID: AC690
QC Batch Report -Batch Sample List
WorkGroup WG40467
Description: IC RUN. GW
Sample ID Client ID •=•
L05022006-0l 0-25
L05022006-0l 0-25 2
L05022006-02 IT-1
LOS022006-02 IT-1 2
LOS022006-03 F-55
L05022006-03 F-55 2
L05022006-04 CC-33
L05022006-04 CC-33 2
L05022006-05 N-29 1
L05022006-05 N-29 2
MB40467 '1 Method Blank. 1
MB4 04 67: 2 Method Blank
LCS40467: 1 Laboratory Control Spike
LCS40467:2 Laboratory Control Spike 1
MS05022006-04 :40467 Matrix Spike
MSOS022006-04:40467 Matrix Spike 2
MS005022006-04:40467 Matrix Spike Duplicate
MSD05022006-04:40467 Matrix Spike Duplicate 2
Matrix GW/Chemw
Prep Method
Analtyical Method: SW846 9056
PREP ANALYTICAL
Date Time Date Time Analyst Dilution
02/19/2005 1627
02/19/2005 1745
02/19/2005 1509
03/01/2005 0005
02/19/2005 1824
02/19/2005 1904
02/19/2005 1213
02/28/2005 2227
02/19/2005 13 50
02/28/2005 2345
02/19/2005 1054
02/28/2005 1240
02/19/2005 1035
02/2B/2005 1339
02/19/2005 1232
02/2B/2005 2246
02/19/2005 12 52
02/28/2005 2306
DHR
DHR
DHR
DHR
DHR
OHR
DHR
DHR
DHR
OHR
DHR
DHR
DHR
DHR
OHR
DHR
Dl!R
DHR
10
5
1
l . 05
. 05
. 05
. 05
Davis & Floyd, Inc. 'f PO Drnwer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue j Greenwood, SC 2%49 I [phone] I Fax [phone]
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
Tl:CONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
QC Batch Report -Method Blanks
WorkGroup: WG40467
Parameter
Wet ChC111iatry
SW846 9056
Blank
NITRATE NITROGEN (AS N)
SULFATE
MB40467:1
Result Qual
0.10
0.50
NC Cenijication Number: 25
Project Number, 61621.03
Report Date March 15, 2005
Page 118 of 136 Report 1D: AC690
Matrix: GW/Chemw
RDL
0.10
0.50
Units
mg/1
mg/1
Analyst
OHR
OHR
Date Time
02/19/2005 1054
02/19/2005 1054
I Davis & Floyd, Inc. ·1 PO Drawer 428 [ Greenwood, SC 29648 I 816 E. Durst Avenue j Greenwood, SC 29649 I [phone] I Fax {864) 229-7119
DAYIS
FLlWD LABORATORY ANALYSIS REPORT
Parameter
Wet Chemistry
S11'846 9056
SULFATE
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 1~8
SHELBY, NC 28152
Steve Olp
QC Batch Report -Method Blanks
WorkGroup, WG40467
Blank MB40467 :2
Result Qual
< o.so
NC Certification Number: 25
Project Number: 61621.03
Report Date
Page 119 of 136
Matrix: GW/ChemW
RDL Units
March 15, 2005
Report ID: AC690
.Analyst Date Time
0.50 DHR 02/28/2005 1240
Davis & Floyd, Inc. T PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] l Fax (864} 229-7119
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Di\YIS
FLtn'D LABORATORY ANALYSIS REPORT
Client
Contact
TI:CONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number, 61621.03
Report Date March 15, 2005
Page 120 of 136 Report ID, AC690
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG40467
MS/MSD MS05022006-04:40467
NITRATE NITROGEN (AS N)
SULFATE
NITRATE NITROGEN (AS N)
SULFATE
MSDO5O220O6-O4:4O467
5.25
5 25
5. 25
5.25
< 0.100
5 99
4.90
10.83
Matrix GW/ChemW
Prep Method
Analtyical Method: SW846 9056
4.85
10.79
mg/1
rng/1
93
92
92
91
0
80-115
74-135
10
10
B0-115
74-135
NOTE: MS/MSD \-recoveries are not evaluated if the sample concentration is greater than four times the spike added.
I Davis & Floyd, Inc. '(PO Drawer 428 J Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29&49 l [phone] I r:ax {864) 229-7119
' '
Di\YIS
FLMD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Cenificarion Number: 25
Project Number, 61621.03
Report Date
Page 121 of 136
March 15, 2005
Report ID: AC690
QC Batch Report -LaboraJory Control Standards and Duplicates
WorkGroup: WG40467
LCS LCS40467:l
NITRATE NITROGEN (AS N)
SULFATE
5.00
25.00
5-04
26.03
Matrix GW/ChemW
Prep Method
Analtyical Method, SWB46 9056
mg/1
mg/1
101
104
95-105 ·
95-105
Davis & Floyd, Inc. .:I PO Drziwer 428 I Greenwood, SC 29648 I 81 (} E. Durst Avenue I Greenwood, SC 29&49 J i8(J4) 229-4413 I F;ix {8G4) 229-7119
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Di\YIS
FLMD LABORATORY ANALYSIS REPORT
Client
Contact
T.ICONA, LtC
2525 BLACKSBURG ROAD
HWY 198
SHELBY. NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date : March 15, 2005
Page 122 of 136 Report ID: AC690
QC Batch Report -Laboratory Control Standards and Duplicates
workGroup: WG40f67 Matrix GW/ChemW
LCS LCS40467:2 Prep Method
lmaltyical Method: SW846 9056
25.00 24.35 mg/1 97 95-105
I Davis & Floyd, Inc. ·1 PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 2%49 I [phone] I fax [phone]
Dl\VIS
FLMD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 2B152
Steve Olp
NC Cenification Number: 25
Project Number: 61621.03
Report Date
Page 123 of 136
March 15, 2005
Report TD: AC690
QC Batch Report -Batch Sample List
WorkGroup WG40531 Matrix GW/Chemw
Description: TOC GW Prep Method
Analtyical Method, SW846 9060
PREP ANALYTICAL
sample :ro Client ID •=# Date Tl.llle Date Time Analyst
1.05021802-01 TI-1 03/02/2005 1740 CDC
L05021B02-02 U-38 03/02/2005 1804 CDC
L05021802-03 Q-33 03/03/2005 0909 CDC
L05021802-01 DUP-2 03/02/2005 1853 CDC
L05021802-05 J-29 03/03/2005 0935 CDC
1,05021802-06 DUP-3 03/02/2005 1941 CDC
L05021802-07 W-23 03/02/2005 2008 CDC
L05022006-0l 0-25 03/03/2005 0106 CDC
L05022006-02 IT-1 03/03/2005 0133 CDC
I,05022006-03 F-55 03/03/2005 0201 CDC
L05022006-04 CC-33 03/03/2005 0224 CDC
I,05022006-05 N-29 03/03/2005 0249 CDC
M!340531:1 Method Blank 03/02/2005 2302 CDC
MB40531:2 Method Blank 03/03/2005 0'132 CDC
LCS40531: l Laboratory Control Spike 03/02/2005 2232 CDC
I,CS4053l:2 Laboratory Control Spike 03/03/2005 0401 CDC
MS05021806-03:40531 Matrix Spike 03/02/2005 2139 CDC
MS05022006-05:40531 Matrix Spike 03/03/2005 0307 CDC
MSD05021806-03 :40531 Matrix Spike Duplicate 03/02/2005 2157 CDC
MSD05022006-05:40531 Matrix Spike Duplicate 03/03/2005 0325 CDC
Dilution
1
1
2
500
1
1
Davis & Floyd, Inc. ··1 PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I r=ax (864) 229-71 19
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DAYIS
FLtn'D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
QC Batch Report -Method Blanks
Para.meter
Wet Chemistcy
SW846 9060
WorkGroup, WG40531
Blank HB40531:l
ORGANIC CARBON, TOTAL
Result Qual
< 1.0
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 124 of 136 Report ID: AC690
Matrix, GW/Chemw
RDL Units Analyst Date Time
1. 0 mg/1 CDC 03/02/2005 2302
Davis & Floyd, Inc. ·-1 PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue j Greenwood, SC 29649 I [phone] ] Fax [phone]
Di\VIS
FLMD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
QC Batch Report -Method Blanks
Para.meter
Wet Chemiatry
SW846 90G0
WorkGroup: WG40531
Blank MB40531:2
ORGANIC CARBON, TOTAL
Result Qual
' l . 0
NC Certification Number: 25
Project Number, 61621.03
Report Date
Page 125 of 136
Matrix: GW/ChemW
RDL Units
March 15, 2005
Report ID, AC690
Analyst Date Ti.me
1.0 mg/1 CDC 03/03/2005 0432
0Jvis & Floyd, Inc.· 1 PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 l {864) 229-4413 I Fax (8(>4) 229-7119
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Df\YIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact.
TICONA, LLC
2525 BLACKSBURG ROAD
HwY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 126 of 136 Report ID: AC690
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG40531 Matrix GW/Chemw
MS/MSD MS05021806-03:40531 Prep Method
MSD05021806-03:40531 Analtyical Method, SWB46 9060
ORGANIC CARBON, TOTAL
ORGANIC CARBON, TOTAL 10. 00 10.00 100 0 11 74-125
NOTE: MS/MSD \; recoveries are not evaluated if the sample concentration is greater than four times the spike added.
I Dav;s & Floyd, Inc. · i PO Drawer 428 I Greenwood, SC 29648 I 816 E. Dues! Avenue I Greenwood, SC 29649 I [phone] I fax (864J 229-7119
Df\VIS
FLtfYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Nwnber: 25
Project Number: 61621.03
Report Date
Page 127 of 136
March 15, 2005
Report ID: AC690
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG40531 Matrix GW/ChemW
MS/MSD MS05022006-05:40531 Prep Method
MSD05022006-05:40531 Analtyical Method: SW846 9060
ORGANIC CARBON, TOTAL 10.00 < 1. 00 l O. 40 104 74-125
ORGANIC CARBON, TOTAL 10.00 10. 4 0 mg/1 104 0 11 74-125
NOTE: MS/MSD l recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. 'f PO Drawer 428 I Greenwood, SC 29648 I 816 E. Dursl Avenue I Greenwood, SC 29649 I [phone] l Fax [phone]
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Df\_VIS
FLtJ\'D LABORATORY ANALYSIS REPORT
Client
Contact
TrCONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 26152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date : March 15, 2005
Page 12B of 136 Report ID: AC690
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG40531 Matrix GW/Chemw
LCS LCS40531:l Prep Method
Analtyical Method: SW846 9060
ORGANIC CARBON, TOTAL 10.00 9.85 mg/1 99
I Davis & Floyd, Inc. <J PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
Di\YIS
FLtwD LABORATORY ANALYSIS REPORT
Client TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Contact ; Steve Olp
NC Certification Number: 25
Project Number, 61621. 03
Report Date : March 15, 2005
Page 129 of 136 Report ID: AC690
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG40531 Matrix GW/Chemw
LCS LCS40531:2 Prep Method
Analtyical Method: SW846 9060
ORGANIC CARBON, TOTAL 10.00 10.10 mg/1 101 90-110
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Davis & Floyd, Inc.·•/ PO Drawer 428 I Greenwood, SC 29648 j 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] ! Fax [phone] I
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Df\YIS
FLtfYD LABORATORY ANALYSIS REPORT
Client
contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY. NC 28152
St.eve Olp
NC Cenification Number: 25
Project Number, 61621.03
Report Date
Page 130 of 136
March 15, 2005
Report ID, AC690
QC Batch Report -Batch Sample List
WorkGroup WG40535 Matrix GW/ChemW
Description: TOC GW Prep Method
Analtyical Method, SW846 9060
PREP ANALYTICAL
Sauiple ID Client ID •=# Date Ti.me Date Time Analyst
L05D22301-01 IT-9 l 03/03/2005 1749 CDC
LOS022301-02 IT-BR 03/03/2005 1819 CDC
L05022301·03 IT-2 03/03/2005 1844 CDC
LOS022301-04 IT-3 0)/03/2005 1909 CDC
L05022301-0S IT-7 03/04/2005 0841 CDC
L05022402-0l IT-6 03/03/2005 2053 CDC
LOS022402-02 IT-4 03/03/2005 2119 CDC
L05022402-03 IT-5 03/03/2005 2147 CDC
L05022402-04 V-23 03/03/2005 2002 CDC
L05022402-05 V-65 03/03/2005 2351 CDC
LOS022402-06 FB-01 03/04/2005 0014 CDC
L050224 02 07 K-28 03/03/2005 2027 CDC
MB40535: Method Blank 03/03/2005 2327 CDC
MB40535: 2 Method Blank 03/04/2005 0435 CDC
LCS40535: Laboratory Control Spike 03/03/2005 2255 CDC
LCS40535: 2 Laboratory Control Spike 03/04/2005 0404 CDC
MS05022402-02 :40535 Matrix Spike 03/03/2005 2205 CDC
MS05022407-05: 40535 Matrix Spike 03/04/2005 0311 CDC
MSDOS022402-02:40535 Matrix Spike Duplicate 03/03/2005 2223 CDC
MSDOS022407-05:405J5 Matrix Spike Duplicate 03/04/2005 0328 CDC
Dilution
5
25
5
500
1000
l
25
I Davis & Floyd, Inc. •.j PO Drawec 428 I Greenwood, SC 29648 I 816 [. Durst Avenue I Greenwood, SC 29649 I [phone] I fax (864) 2l9-7l 19
Di\YIS
FLMD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 2B152
Steve Olp
QC Batch Report -Method Blanks
Parameter
Wet Cbamistry
SW84.6 9060
WorkGroup: WG40535
Blank MB40535:1
ORGANIC CARBON, TOTAL
Result Qual
0.50
NC Certification Number: 25
Project Number: 61621.03
Report Date
.Page 131 of 136
Matrix: GW/Chemw
RDL Units
March 15, 2005
Report ID: AC690
Analyst Date Tillie
o.so mg/1 CDC 03/DJ/2005 2327
Davis & Floyd, Inc. ··1 PO Drawer 428 J Greenwood, SC 29648 [ 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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Di\VIS
FLtlYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLA.CKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
QC Batch Report -Method Blanks
Parameter
Wet Chemistry
SW846 9060
WorkGroup: WG4053S
Blank MB40535:2
ORGANIC CARBON, TOTAL
Result Qual
0.50
NC Certification Number: 25
Project Number: 61621.03
Report Date March 15, 2005
Page 132 of 136 Report ID: AC690
Matrix: GW/ChemW
RDL Units Analyst Date Time
0.50 mg/1 CDC 03/04/2005 0435
I Davis & Floyd, Inc.· •t PO Drawer 428 I Greenwood, SC 29648 ] 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I fax [phone]
Df\¥1S
FLtJfD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date
Page 133 of 136
March 15, 2005
Report ID: AC690
QC Batch Report -Matrix Spikes and Duplicates
workGroup: WG40535 Matrix GW/ChemW
MS/MSD MSOS022402-02,40535 Prep Method
MSD05022402-02:40535 Analtyical Method: SWB46 9060
ORGANIC CARBON, TOTAL 10.00 6.69 17.00 103
ORGANIC CARBON, TOTAL 10.00 16. so mg/1 98 3 11 74-125
NOTE: MS/MSD \-recoveries are not evaluated if the sample concentration is greater than four times the spike added.
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Davis & floyd, Inc. "f. PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue ! Greenwood, SC 29649 I [phone] I Fax [phone] I
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Df\YIS
FLtJ\'D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Steve Olp
NC Certification Number: 25
Project Number, 61621.03
Report Date March 15, 2005
Page 134 of 136 Report ID: AC690
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG40535 Matrix GW/Chemw
MS/MSD MS05022f07-05:40535 Prep Method
MSD05022407-05:40SJS Analtyical Method, SW846 9060
ORGANIC CARBON, TOTAL 10.00 1. 66 12.20 mg/! 105 74 -125
ORGANIC CARBON, TOTAL 10.00 ll. 80 mg/! 101 3 11 74-125 I NOTE: MS/MSD \-recoveries are not evaluated if the sample concentration is greater than [our times the spike added.
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I Davis & Floyd, Inc. · r PO Drawer 428 l Greenwood, SC 29648 I 816 E. Durst Avenue j Greenwood, SC 29649 I [phone] I Fax [phone]
DAYIS
FLt5¥D LABORATORY ANALYSIS REPORT
Client TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Contact ; Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date
Page 135 of 136
March 15, 2005
Report ID, AC690
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG40535 Matrix GW/Chemw
LCS LCS4053S:l Prep Method
Analtyical Method: SWB46 9060
ORGANIC CARBON, TOTAL 25. OD 9. 92 99 90-110
Davis & r-loyd, Inc. ".'I PO Drawer 428 I Greenwood, SC 29h48 I 816 E. Durst Avenue I Greenwood, SC 2%49 ! [phone] I f;ix (864) 229-7! 19
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Df\VIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 29152
Steve Olp
NC Certification Number: 25
Project Number: 61621.03
Report Date ; March 15, 2005
Page 136 of 136 Report ID: AC690
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG40535 Matrix GW/ChemW
LCS LCS4053S:2 Prep Method
Analtyical Method: SWB46 9060
ORGANIC CARBON, TOTAL 25.00 9.96 100 90-110
I Davis & Floyd, Inc. · I• PO Drawer 428 I Gret:nwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I {864) 229-4413 I Fax (864) 229·7119
DAYIS
FLtwD LABORATORY ANALYSIS REPORT
Method Conformance Summary
Client: Ticona, LLC
Login(s): L0502 ! 802, l...0502206, l...05022301, L05022402
Criteria Metals
Sample Holding Time ✓
Standards Preoaration ✓
Instmment Tuning NIA
Instrument Calibration ✓
Calibration Verification ✓
Degradation Check NIA
Interference ✓ Sample/Standard
Blanks Results ✓
Method Accuracy ✓
Method Precision ✓
· Surrogate Recovery NA
PDS/SD/MSA NIA
TCLP Preparation NIA
Key ✓
NIA
Method Criteria Met
Not Applicable
Alkalinity
✓
✓
NIA
✓
✓
NIA
NIA
✓
✓
✓
NA
NIA
NIA
Sulfide
✓
✓
NIA
✓
✓
NIA
NIA
✓
✓
✓
NIA
NIA
NIA
*
PDS
SD
MSA=
Method Criteria Not Met -Seefootnote(s) below.
Post Digestion Spike
Serial Dilution
Method of Standard Additions
Project Number: 61621.03
Report Date: March I 5, 2005
Nitrate TOC
✓ ✓
✓ ✓
NIA NA
✓ ✓
✓ ✓
NIA NA
NIA NA
✓ ✓
✓ ✓
✓ ✓
NIA NA
NIA NA
NIA NA
Foon1otes: . Metals-The recovery for manganese (120%) exceeded the acceptance criteria (82-
115%) for the MSD. Post-spike was performed and passed criteria.
Prepared by. ---t_ IJ () ;~_,,._)_
( I \ Davis & Floyd, Inc.
QA02_0! (03105)
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. 229 7119 I Davis l<, Floyd. Inc. L PO Drawer 428 j Greenwood, SC 29648 I 816 [. Durst Avenue I Greenwood, SC 29649 f (864) 229-441 J I fax (864.l -
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DAYIS
FLtwD LABORATORY ANALYSIS REPORT
Method Conformance Summary
Client Ticona, LLC
Log;n(s)c L0502 l 802, L0502206, L05022301. L05022402
Criteria Sulfate
Sample Holding Time ✓
Standards Preparation ✓
Instrument Tuning NIA
Instrument Calibration ✓
Calibration Verification ✓
Degradation Cheek NIA
Interference ✓ Sample/Standard
Blanks Results ✓
Method Accuracy ✓
Method Precision ✓
Surrogate Recovery NIA
PDSISD/MSA NIA
TCLP Preparation NIA
Key ✓
NIA
Method Criteria Met
Not Applicable
Ethylene
Glycol
✓
✓
NIA
✓
✓
NIA
NIA
✓
✓
✓
NIA
NIA
NIA
*
PDS =
SD =
MSA=
Method Criteria Not Met -See footnote(s) below.
Post Digestion Spike
Serial Dilution
Method of Standard Additions
Project Number: 61621.0J
Report Date: March 15, 2005
Footnotes: Sulfate -Method EPA 9038 was used to analyzed login L050233301. All other
logins were analyzed by EPA 9056.
Davis & Floyd, Inc.
QA02_01 (03/05)
I Davis & Floyd, Inc.. f .PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I (BIA) 229-4413 ! fax [phone]] l 9
~ SHEALY ~
Client
Chain of Custody Record
SHEALY ENVIF,!f),NMi;;_NTAL SERVICES, INC.
106 Vantage Point Drive
Cayce, South Carolina 29033
Telephone No. [phone] Fax No. [phone]
Report to Contact
~Jt;>i/,
Waybill No.
(
Number
Quote No.
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Matrix
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Sample Disposal
□ Return to Client G·'lJisposa/ by Lab
Note: Afl samples are retained for six weeks from receipt
unless other arrangements are made. '{~m Aroun~T~Required (Prior la'},8-PPJc/val required for expedited TAT.) JZi Standtt~-ESAush (Specf!Y). / ./
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Sample ID I Description -.. Dare·· ,·
(Containers for each sample may be combined on one line.)
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-------SHEALY ENVIRONl\(l~N,T~J.. SERVICES, INC.
1os·vanta9e Point Drive
Cayce, South Carolina 29033
Telephone No. [phone] Fax No. [phone]
.. 1111111
Report to Contact
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Pn'nted Na,~! _. -·
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Possible Hazard Identification ,' Sample Disposal Note: All samples are retained for six weeks from receipt □ Non-Hazard Q-Ffammabfe □·ikin,f;ritant □ Poison □ Unknown □ Return to Client (tJ Disposal by Lab unless other arrangements are made Tum Arou7,fne Required (Pri9( tab pf;;proval required tor expedited TAT.) QC Requirements (Specify) l i-1 ,...--·-, .. -----··-iii,, / , ;: , ,.-··, , Stancjs' urRush (§p6cilr) / :
/ --c·_:/ /· '-· _ _;_1--
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3. Relinquished by Date Time 3_L.aboratory received by . / i q~re Time .. ! i.:. ct -~ tJ CC, 6-(_. ' . ,:· ,.. {/.:_; ~-·: I • (,-.,/ , ,' Comments LAB USE ONLY --Received on ice (Circle) Yes No Ice Pack Receipt Temp. ·c .
DISTRIBUTION: WHITE & YELLOW•Retum to laboratory wt/h Sample{s); PINK-Field/Client Copy
-
~ SHEALY ~ Chain of Custody Record
SHEALY ENVll,0,N!Y[~TAL SERVICES, INC.
106 Vantage Point Drive
Cayce. South Carolina 29033
Telephone No. [phone] Fax No. [phone]
Repor1 to Contact
.JD1.jlt,
Waybill No.
,-
!,. l-1
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Quote No.
' ,
' ' Page_-' _ot---t....-
Analysis (Attach list if more space is needed.)
Sample ID I Oescn·ption
(Containers for each sample may be combined on one line.)
PO. No.
, Time'
,/-/J;k /i2D
/(/39
I
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Possible Hazard /dentificarion / / □ Non-Hazard /6}1ammable □ s✓irrit{l,,{ □ Poison O Unknown
3. Relinquisheci by Date
Comments
-~ gf t8 ~
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□ Re tum to Client _B· Disposal by Lab
Note: All samples are retained tor six weeks from receipt
unless other arrangements are made.
QC Requirements (Speedy) /
,,,. / v6Vc'"l-_-;zz::
1. Receivedbji~ ./ • .., ______ •·--
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2. Aeceilled by Date
Time
LAB USE ONLY
Lot No.
Remarks I Cooler I.D.
·, -·
Time
Time
Recei11Pri no ice (Ci""'~ Yes lli ....!.:::E Pac/<"_ -~iptTe~ --.ii;TRIB,._ WHl~LLO\~ tola~with ~(s); P~d/Clie1~ ------ --
-~ SHFALY
~ ---------Chain of Custody Record
SHEALY ENVIRONM_ENTAL SERVICES, INC.
106~ahtage Point Drive
Cayce, South Carolina 29033
Telephone No. [phone] Fax No. [phone]
-! /· L -.,,.,.-) /.·. :L,,.: ... __ ,1
I
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-----J.-~~o':in ...... ~.: ....... ._, ·--
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I
Page '
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Project No. ,J0,U1J ~ P.O. No.· -~ ~[ .
·-----~· ~ Sample ID I Descn'ption ;Date ' Time &~ ·'-· ~ (Containers tor each samp{e may be combined on one line.) 0 • ----,
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Possible Hazard Jde~'.iJiCBtio~/_ ./ /,, Sample Disposal Note: All samples are_ f~tained for six weeks from receipt
unless other ar"!ngements are made.
□ Non•Hazard c;r'Flamm.dble □ Skin lrrit,v,t 0,Poison □ Unknown □ Re tum to Client -~ Disposal by Lab Tum Around Tillie Requiled (Prior lab appro:/al rf!f!dired for expedited TAT.) trs,anda'J"'Jfq_R6"sh /Speci/vl I..-I ,/ I'" I -
QC Requirements (Specify}
2. Receiv8d by ~
3. Relinquished by Date Time 3. Laboratory received by
-,1: ~ ,1 ,;·· i1.1. Cominents
LAB USE.ONLY .. --. •
Received on ice (Circle) ie§..,( No Ice Pack DISTRIBUTION: WHITE & YELLOW-Return lo laboratory with Sample(s); PINK-FielcVCfient Copy
Date • Time p;iJ,; .
Date Time -.
(
Date Time
Receipt Temp.
/ ' ~:. C:
. --,·,., L
I t, • ;
"C
.
..
Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Lab Sample# Client Sample ID
P0502369-01 L05021802-01 T 1-1
P0502369-02 L05021802-02 U-38
P0502369-03 L05021802-03 Q-33
POS02369-04 L05021802-04 DUP-2
P0502369-05 L05021802-05 J-29
P0502369-06 L05021802-06 DUP-3
P0502369-07 L05021802-07 W-23
POS02369-08 LOS021802-08 trip blank
P0502369-09 L05022006-01 0-25
P0502369-10 LOS022006-02 IT-1
POS02369-11 L05022006-03 F-55
P0502369-12 LOS022006-04 CC-33
P0502369-13 LOS022006-05 N-29
P0502369-14 L05022006-06 trip
blank-2
Page:
Lab Project#:
Report Date:
Client Proj Name:
Client project #:
Page 1 of 20
P0502369
02/25/05
61621 01
61621_01
Laboratory Results -·, -, Total# of pages in client package ~O'<~Ct-~--
The analytical results reported here are reliable and usable to the precision expressed in this report. As required by some regulating authorities, a full discussion of the uncertainty in our analytical results can be obtained at our web site or through customer service. Unless otherwise specified, all results are reported on a wet weight basis.
220 William Pitt Way• Pittsburgh, PA 15238 • Tel [phone] • Fax [phone]
website www.microseeps.com email [e-mail]
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-------------- -
Chain of Custody Record Page 1 of 1 ClienC Project I Site Location 816 E. Durst Avenue, Greenwood, SC 29649 {864) 229-4413 Fax: (864) 229-i119 ice use nw Davis & Floyd, Inc. Laboratory Certifcatlon Numbers: SC-24110, NC-25, TN· 2923, VA-77 Greenwood SC 29649 61621 01 Contact Repon To Copy To Reporting Requirements:°' Standard ( J Data Package (Specify Level) Purchase Order John H. McCord, Jr. John H. McCord, Jr. NA Collected By Atmospheric Conditions Reauired Parameters, Containers and Preservatives Stafe Quote
_j NC Tisa S. McCall/Sample Custodian ~~
0~ 10 ional • > LO'Jln Special Instructions NOTICE: e ~ 0
i~ :;: ~
0 • ~ 0 "' .§ ~ t 0 8 w 0 "' ,._" .., .,, 0 < °'' ~ "tl.:; ", • 0 il b
0 "
VI ,!? g_
-0
a. D .• D ~
-~ i ~~~ E • b E ~ Samo!e Collection 8 /,; .1 , w z a. .J .s Samnle Oescriotion Date Time Time Type Total lt"f:JCIJOn HOT ommems L05021802-01 Tl-1 16-Feb 15:52 X 5 2 2
L05021802-02 U-38 16-Feb 17:34 X 5 2 2
L05021802-03 Q-33 17-Feb 11:22 X 5 2 2
L05021802-04 OUP-2 17-Feb 11:22 X 5 2 2
L05021802-05 J-29 17-Feb 13:58 X 5 2 2
L05021802-06 DUP-3 17-Feb 13:58 X 5 2 2
L05021802-07 W-23 17-Feb 15:48 X 5 2 2
L05021802-08 TRIP BLANK 14-Feb 9:10 X 5 2 2
.
Re/iquisfled By Date Time Reliquisfled By Date Time Reliquisfled By Osle Time ou;,0 Shipped By 'i~A S. ht t,/" f/ :l~J.ll• 11/-3 0 y N 6 cwn
' w·· \.J &At/ w1:. Time Received By Date Time Received in Laboratory By Date Time lfY, SP : Airb,~uer ~ llo? -day, 1.,omments ( I ... PERM_GASES FOR METHANE & CO2 ONLY"""SAMPLES FOR KUBAL & FURR AND ARE NOT TO EXCEED THE 14 DAY HOLDING TIME. Cooler l~il_able):
On Ice: Yes No Temp(C) ___
Custodv Seal: Intact I Broken / None Matnx Type Definitions 1 -Ormk1ng Water 2. Clean Water 5 • Groundwater 7 -Soil/Sediment 6 • L,qukl Sludge 9 • 011 12 • Air Davis & Floyd, Inc. Preservative Definitions A -None B. H2S04 C · HCI D · HN03 E • NaOH F • Filtered G • Other
FLOZ _01 (02/99)
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D~JS K,alne~l•I
::r:'. Ard!it~re FL YD Ellril'onme!!lal4i!Labotll!J!~rlce!
Client
Davis & Floyd, Inc.
Greenwood SC 29649
Comacr
John H. McCord, Jr. CoJlectec1 By
Project I Site Location
61621 01
Report To
John H. McCord, Jr.
Tisa S. McCall/Sample Custodian
\(ruoc>Co9
Chain of Custody Record
816 E. Dursl Avenue, Greell'WOod, SC 29649 [phone] Fax: [phone]
Copy To
NA
Atmosp/Jeric Condi/ions
Labora/oty Certilcation Numbers: SC• 24110, Ne• 25, TN. 2923, VA -77
Reporting Requirements: (1'J Standard { ) Data Pack.age (Spec,ty Lave!)
Required Parameters, Containers and Preservatives
_;
Page 1 of 1
Office Use Only
Purchase Order
State
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NOTICE: e t .
Samole Collection
g i~ E v; g ~ 8c: w ""'~ ~ ~~ 0 c3 ~"g ~ ~I Si I ~ It ~ & ...J ] 0,, Samole Oescrintion Date Time Time Tvoe Total Fraction HOT .... omments L05022006-01 0-25 18-Feb 11 :00 X 5 2 2
L05022006-02 IT-1 18-Feb 12:35 X 5 2 2
L05022006-03 F-55 18-Feb 13:55 X 5 2 2
L05022006-04 CC-33 18-Feb 10:19 X 5 2 2
L05022006-05 N-29 18-Feb 12:29 X 5 2 2
L05022006-06 TRIP BLANK-2 14-Feb 9:10 X 5 2 2
Dale Time Reliquished By Date Time refiquished By
Received By Dale ,ime Recerved By Date Time Received in Laboratory By
l.Ommenls
... PERM_GASES FOR METHANE & CO2 ONLY"""SAMPLES FOR KUBAL & FURR AND ARE NOT TO EXCEED THE 14 DAY HOLDING TIME.
Matrix Type Defin1tt0ns
Preservative Definitions
1 -Drinking Water 2 -Clean Water 5 • Groundwater 7 -S0I1/Sed1ment 8 -Liquid Sludge 9 -011 12. Air A -None B • H2SO4 C -HCI D • HNO3 E -NaOH F • Filtered G -Other
-
Dato
Date
Time
Time
Ouick~A Sllippea By
O&F CUENT YN ~F£08i:
If Y, spe I y: CAc;,~b::!m~=,:at,,~,~,~=~-
.::::::_ days
Cooler r~aR.able): ,
On lee:~ No Temp(C) ___ I
Custoc!v Seal: Intact f Broken / None
Dav,s & Floyd, Inc.
FL02 _01 (02199) -

-
--

-
-------------
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Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Page:
Lab Project#:
Report Date:
Client Proj Name:
Client project #:
Page 2 of 20
P0502369
02/25/05
61621_01
61621_01
1-----------,-----------
Lab Sample#: P0502369-01
Sample Description
L05021802-01 Tl-1
Analyte(s)
riskAnalysis
Carbon dioxide
I
I
I
I
I
I
I
I
I
I
Methane
Matrix
Water
Result
78
110
Flag PQL
0.60
0.015
Units
mg/L
ug/L
Sampled Date/Time
16 Feb. 05 15:52
Received
22 Feb. 05
Method# Analyst Analysis Date & nme
AM20GAX
AM20GAX
jl
jl
2/24/2005
2/24/2005
f a Qualifiers: J -estimated value, U -Non detect. R -Poor surrogate recovery. M -Recovery/RPO poor for MS/MSD, SAMP/DUP. B -detected in hlank, S -field pie as received did not meet NELAC sample acceptance criteria. L -Subcontracted Lab used.
i-NELAC certified analysis ·
I
I
Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Page:
Lab Project #:
Report Date:
Client Proj Name:
Client project#:
Page 3 of 20
P0502369
02/25/05
61621_01
61621_01
Lab Sample #: P0502369-02
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Sample Description Matrix Sampled DatefTime Received I
L05021802-02 U-38 Water 16 Feb. 05 17:34 22 Feb. 05 ----------------------------------------An a I yt e ( s) Result
RiskAnalysis
Carbon dioxide
Methane
76
2.6
Flag PQL
0.60
0.015
Units
mg/L
ug/L
Method#
AM20GAX
AM20GAX
Analyst Analysis Date & Time
jl 2/24/2005
jl 2/24/2005
Data Qualifiers: J -estimated value, U -Non detect, R -Poor surrogate recovery, M -RecoverynlJlD poor for MS/MSD, SAMP/DUP. B -detected in blank, S -field
sample as received did not meel NELA~~ sample acceptance criteria,. L -Subcontracted Lab U$ed.
ii_-NELAC certified analysis
I
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Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Sample Description I L05021802-03 Q-33
Analyte(s)
IRiskAnalysis
Carbon dioxide
I
I
I
I
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I
I
I
I
I
Methane
Greenwood, SC 29649
85
48
Matrix
Water
Result Flag POL
0.60
0.015
Page:
Lab Project #:
Report Date:
Client Proj Name:
Client project#:
Page4 of 20
P0502369
02/25/05
61621_01
61621_01
Lab Sample #: P0502369-03
Units
mg/L
ug/L
Sampled Daterrime
17 Feb. 05 11:22
Received
22 Feb. 05
Method # Analyst Analysis Date & Time
AM20GAX
AM20GAX
rw
rw
2/24/2005
2/24/2005
f ata Qualifiers: J -estimated value, U -Non detect, R -Poor surrogate recovery. M -Recovery/RPO poor for MS/MSD, SAMP/DUP. B -detected in blank, S -field ample as received did not meet NELAC sample acceptance criteria, L -Suhcontracted Lab used.
!:i-NELAC certified analysis
I
I
Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Sample Description
L05021802-04 DUP-2
Matrix
Water
Analyte(s)
RiskAnalysis
Carbon dioxide
Methane
88
48
Result Flag PQL
0.60
0.015
Page: Page 5 of 20
Lab Project#: P0502369
Report Date: 02/25/05
Client Proj Name: 61621_01
Client project #: 61621_01
Lab Sample#: P0502369-04
Units
mg/L
ug/L
Sampled Datemme
17 Feb. 05 11 :22
Received
22 Feb. 05
Method # Analyst Analysis Date & Time
AM20GAX
AM20GAX
rw
rw
2/24/2005
2/24/2005
Data Qualifiers: J -estim::iled value, U -Non detect, R -Poor surrogate recovery, M -Recovery/RPO poor for MS/MSD, SM1P/DUP, B -detected in blank, S -fir.::ld sample as recc·rved did not mec\ NELAt; sample 1.1cceptancc criteria. L -Subcontracted Lnb used.
~-NELAC certified analysis
I
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Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
J-29
Greenwood, SC 29649
Matrix
Water
Analyte(s)
liskAnalysis
Result
I
I
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I
I
Carbon dioxide
Methane
·,
150
8.9
Flag PQL
0.60
0.015
Page:
Lab Project #:
Report Date:
Client Proj Name:
Client project #:
Page 6 of 20
P0502369
02/25/05
61621_01
61621_01
Lab Sample #: P0502369-05
Units
mg/L
ug/L
Sampled DatefTime
17 Feb. 05 13:58
Received
22 Feb. 05
Method # Analyst Analysis Date & Time
AM20GAX
AM20GAX
rw
rw
2/24/2005
2/24/2005
l ata Qualifiers: J -estimated value, U -Non detect, R -Poor surrogate recovery, M -Recovery/RPO poor for MS/MSD, SAMP/DUP, B -detected in blank, S -field
mple as received did not meel NELAC sample acceptance criteria. L -Subcontracted Lab used.
,-NELAC certified analysis
I
Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
" Greenwood, SC 29649
Sample Description Matrix
L05021802-06 OUP-3 Water
Analyte(s) Result Flag
RiskAnalysis
Carbon dioxide 150
Methane 8.6
POL
0.60
0.015
Page: Page 7 of 20
Lab Project #: P0502369
Report Date: 02/25/05
Client Proj Name: 61621_01
Client project #: 61621_01
Lab Sample #: P0502369-06
Units
mg/L
ug/L
Sampled Datemme
17 Feb. 05 13:58
Rece·,ved
22 Feb. 05
Method # Analyst Analysis Date & Time
AM20GAX
AM20GAX
rw
rw
2/24/2005
2/24/2005
Data Qualifiers: J -estimated value, U -Non detect. R -Poor surrogate recovery, M -Recovery/RPO poor for MS/MSD, SAMPIDUP. B -detected in blank. S -field sample as received did not meet NELA-;: sample acceptance criteria, L -Subcontracted Lab used .
.!:i-NELAC certified analysis
I
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Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Page: Page 8 of 20
Lab Project #: P0502369
Report Date: 02/25/05
Client Proj Name: 61621 01
Client project#: 61621_01 1-------------
Lab Sample #: P0502369-07
•
Sample Description
L05021802-07 W-23
Analyte(s) f iskAnalysis
~arbon dioxide
I
I
I
I
I
I
I
I
I
I
Methane
Matrix
Water
Result
190
30
Flag POL
0.60
0.015
Units
mg/L
ug/L
Sampled Date/Time
17 Feb. 05 15:48
Received
22 Feb. 05
Method# Analyst Analysis Date & Time
AM20GAX
AM20GAX
rw
rw
2/24/2005
2/24/2005
lt,ta Qualifiers: J -estimated value. U -Non detect. R -Poor surrogate recovery, M -Recovery/RPO poor for MS/MSD, SAMP/DUP, B -detected in blank. S -field ample as received did not meet NELAC sample acceptance criteria. L -Subcontracted Lab used.
£i. NE LAC certified analysis
I
I
Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Sample Description
L05021802-08 trip blank
Analyte{s)
RiskAnalysis
Carbon dioxide
Methane
Matrix
Water
Result
< 0.60
0.54
Flag
u
PQL
0.60
0.015
Page:
Lab Project #:
Report Date:
Client Proj Name:
Client project#:
Page 9 of 20
P0502369
02/25/05
61621_01
61621_01
Lab Sample #: P0502369-08
Units
mg/L
ug/L
Sampled Date!Time
14 Feb. 05 9:10
Received
22 Feb. 05
Method# Analyst Analysis Date & Time
AM20GAX
AM20GAX
rw
rw
2/24/2005
2/24/2005
Data Qualifiers: J. estimated value, U -Non detect, R. Poor surrogate recovery, M -Recovery/RPO poor for MS/MSD. SAMP/DUP. B -detected in blank. S • field sample as received did nol meet NELAC. sample acceptance criteria., L • Subcontracted Lab used.
Ci-NJ::LAC certified analysis
I
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Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
I Sample Description
L05022006-01 0-25
Anatyte(s) I RiskAnalysis
Carbon dioxide
I
I
I
I
I
I
I
I
I
I
Methane
Greenwood, SC 29649
Matrix
Water
Result
44
760
Flag PQL
0.60
0.015
Page:
Lab Project #:
Page 10 of20
P0502369
Report Date: 02/25/05
Client Proj Name: 61621_01
Client project#: 61621_01
Lab Sample #: P0502369-09
Units
mg/L
ug/L
Sampled Datemme
18Feb. 05 11:00
Received
22 Feb. 05
Method# Analyst Analysis Date & Time
AM20GAX
AM20GAX
rw 2/24/2005
rw 2/24/2005
aata Qualifiers: J -estimated value, U -Non detect, R -Poor surrogate recovery, M -Recovery/R.PD poor for MS/MSD, SAMP/DUP, B -detected in blank, S -field ■ample as received did nol meet NELAC sample acceptance criteria, L -Subcontracted Lah used. ·ti.· NELAC ccnified analysis
I
Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Sample Description
L05022006-02 IT-1
Analyte(s)
RiskAnalysis
Carbon dioxide
Methane
Greenwood, SC 29649
Matrix
Water
Result
95
23000
Flag PQL
0.60
0.015
Page:
Lab Project#:
Report Date:
Client Proj Name:
Client project#:
Page 11 of 20
P0502369
02/25/05
61621_01
61621_01
Lab Sample#: P0502369-1 O
Units
mg/L
ug/L
Sampled Date/Time
18 Feb. 05 12:35
Received
22 Feb. 05
Method# Analyst Analysis Date & Time
AM20GAX
AM20GAX
rw
rw
2/24/2005
2/24/2005
Data Qualifiers: J -estimaled value, U -Non detect, R -Poor surrogate recovery, M -Recovery/RPO poor for MS/MSD, SA1v1P/DUP, B -detected in blank, S -field sample as received did not meet NELA<; sample acceptance criteria, L -Subcontracted Lab used.
~ -NELAC certified analysis
I
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Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Page: Page 12 of 20
Lab Project #: P0502369
Report Date: 02/25/05
Client Proj Name: 61621_01
• ________________________ c_ne_n_t_p_ro_je_c_t_#_: __ 6_1_6_2_1 __ 0_1_~---------
I Sample Description
L05022006-03 F-55
Analyte(s)
JiskAnalysis
Carbon dioxide
I
I
I
I
I
I
I
I
I
I
Methane
Matrix
Water
Result
57
2800
Flag PQL
0.60
0.015
Units
mg/L
ug/L
Lab Sample#: P0502369-11
Sampled DatefTime
18 Feb. 05 13:55
Received
22 Feb. 05
Method# Analyst Analysis Date & Time
AM20GAX
AM20GAX
rw 2/24/2005
rw 2/24/2005
■ .. ,a Qualifiers: J • estimated v.ilue, U -Non detect. R -Poor surrogate recovery, M -Recovery/RPD poor for MS/l\1SD, SAMP/DUP. B -detected in blank. S · field
.-;pie as received did nol meet NELAC sample acceplaoce criteria, L -Subcontracted Lab used.
,-NEI.AC certified analysis
I
Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Sample Description Matrix
L05022006-04 CC-33 Water
Analyte(s) Result Flag
RiskAnalysis
Carbon dioxide 75
Methane 430
PQL
0.60
0.015
Page: Page 13 of20
Lab Project #: P0502369
Report Date: 02/25/05
Client Proj Name: 61621_01
Client project #: 61621_01
Lab Sample #: P0502369-12 ·
Units
mg/L
ug/L
Sampled Date/Time
18 Feb. 05 10:19
Received
22 Feb. 05
Method # Analyst. Analysis Date & Time
AM20GAX
AM20GAX
rw
rw
2/2412005
2/24/2005
Data Qualifiers: J -estimated value, lJ-Non detect, R -Poor surrogate recovery, M -RecOvery/RPD poor for MS/MSD, SAMP/DUP, B · detected in blank, S -field sample as received did not meet NELAC sample acceptance criteria, L -Subcontracted Lab used.
rs_-NELAC certified analysis
I
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I
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I
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Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Page: Page 14 of 20
Lab Project#: P0502369
Report Date: 02/25/05
Client Proj Name: 61621_01
I------------------------C-lie_n_t_p_ro_i_ec_t_#_: __ 6_1_6_2_1 __ 0_1_---'----------
Analyte(s)
tiskAnalysis
Carbon dioxide
I
I
I
I
I
I
I
I
I
I
Methane
Matrix
Water
Result
110
950
Flag PQL
0.60
0.015
Units
mg/L
ug/L
Lab Sample#: P0502369-13
Sampled Daterrime
18 Feb. 05 12:29
Received
22 Feb. 05
Method# Analyst Analysis Date & Time
AM20GAX
AM20GAX
rw 2/24/2005
rw 2/24/2005
&ta Qualifiers: J -estimated value, U -Non detect, R -Poor surrogate recovery. M -Recovery/RPO poor for MS/MSD, SAMP/DUP,. B -detected in blank, S -field anple as received did not meet NH.AC sample acceptance criteria. L -Subcontracted Lab used.
1. NElAC a:nified analysis
I
Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Sample Description
l05022006-06 trip blank-2
Analyte(s)
RiskAnalysis
Carbon dioxide
Melhane
Matrix
Water
Result
< 0.60
5.0
Flag
u
PQL
0.60
0.015
Page:
lab Project #:
Report Date:
Client Proj Name:
Client project #:
Page 15 of 20
P0502369
02/25/05
61621_01
61621_01
lab Sample#: P0502369-14
Units
mg/l
ug/l
Sampled Date/Time
14 Feb. 05 9:10
Received
22 Feb. 05
Method # Analyst Analysis Date & Time
AM20GAX
AM20GAX
rw
rw
2/24/2005
2/24/2005
Data Qualifiers: J -estimated value. U -Non detect, R -Poor surrogate recovery, M -Recovery/RPO poor for MS/MSD. SAMP/DUP, B -detected in blank, S -field sample as received did not meet NELAC sample acceptance cri1eria, L -Subcontracted Lab used.
ri_-NELAC certified analysis
I
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Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
M050224018-MB
Result
Methane < 0.015 ug/L
M050224018-LCS
Methane 73 ug/L
M050224018-LCSD
Methane 72 ug/L
Page:
Lab Project#:
Report Date:
Client Proj Name:
Client project #:
Page 16 of 20
P0502369
02/25/05
61621_01
61621_01
Prep Method: In House Dissolved Gas Sample Preparation
Analysis Method: Analysis of Dissolved Methane in Water
TrueSpikcConc. RDL %Recovery Ctl Limits
0.015 -NA
TrueSpikeConc. %Recovery Ctl Limits
71.93 101 75 -125
TrueSpikeConc. %Recovery Ctl Limits RPD RPD Ctl Limits
71.93 100 75 -125 1.38 0 -20
j j Outlined Results indicate results outside of Control limits
&ata Qualifiers: J -estimated value, U -Non detect, R -Poor surrogate recovery, M -Recovery/RPO poor for MS/MSD, SAMP/DUP. B -detected in blank, S -field
~iplc as received did not meet NELAC sample acceptance criteria.. L -Subcontracted Lab used.
,--NELAC ce";fied analys;s
I
Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
M050224019-MB
Carbon dioxide
M050224019-LCS
Carbon dioxide
M050224019-LCSD
Greenwood, SC 29649
Result
< 0.60 mg/L
100 mg/L
Page:
Lab Project #:
Report Date:
Client Proj Name:
Client project#:
Page 17 of20
P0502369
02/25/05
61621_01
61621_01
Prep Method: Analysis of Dissolved Permanent Gases in Water
Analysis Method: Analysis of Dissolved Permanent Gases in Water
TrueS12ikeConc. RDL %Recovery CII Limits
0.60 -NA
TrueS12ikcConc. %Recovery Ctl Limits
106.20 94 75 -125
I
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I
TrueSpikcConc. %Recovery CII Limits RPD RPD Ctl Limits
Carbon dioxide 100 mg/L 106.20 94 75 -125 0.00 0-20
~----~I Outlined Results indicate results outside of Control limits
Data Qualifiers: J -estimated value, U -Non detect, R -Poor surrogate recovery, M -Recovery/R.PD poor for MS/MSD. SAMI'/DUP, f3 • detected in blank. S • field sample as received did not meet NELAC sample acceptance criteria. L -Subcontracted Lab used.
ti_-NELAC certified analysis
I
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I!
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I
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I
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Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
M050224022-MB
Result
Methane < 0.015 ug/L
M050224022-LCS
Methane 73 ug/L
M050224022-LCSD
Methane 73 ug/L
Page:
lab Project#:
Report Date:
Client Proj Name:
Client project#:
Page 18 of20
P0502369
02/25/05
61621_01
61621_01
Prep Method: In House Dissolved Gas Sample Preparation
Analysis Method: Analysis of Dissolved Methane in Water
TrueSpikeConc. RDl %Recovery Ct! limits
0.015 -NA
TrueSpikeConc. %Recovery Ct! Limits
71.93 101 75 -125
TrueSpikeConc. %Recovery Ct! limits RPO RPO Ctl limits
71.93 101 75 -125 0.00 0-20
. I joutlined Results indicate results outside of Control limits a .. ,~ Qualifiers: J -estimated value, U. Non detect, R -Poor surrogate recovery, M. Recovery/RPD poor for MS/MSD, SAMP/DUP. B -detected in blank. S -field a:ple as received did not meet NELAC sample acceplance criteria, L -Subcontracted Lab used.
,-NELAC cenified analysis
I
Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
M050224023-MB
Carbon dioxide
M050224023-LCS
Carbon dioxide
M050224023-LCSD
Greenwood, SC 29649
Result
< 0.60 mg/L
100 mg/L
Page:
Lab Project#:
Report Date:
Client Proj Name:
Client project#:
Page 19 of 20
P0502369
02/25/05
61621_01
61621_01
Prep Method: Analysis of Dissolved Permanent Gases in Water
Analysis Method: Analysis of Dissolved Permanent Gases in Water
TrueSpikeConc. RDL %Recovery Ctl Limits
0.60 -NA
TrueSpikeConc. %Recovery Ctl Limits
106.20 94 75 -125
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TrueSpikeConc. %Recovery Ctl Limits RPO RPO CU Limits
Carbon dioxide 100 mg/L 106.20 94 75 -125 0.00 0-20
Outlined Results indicate results outside of Control limits
Dala Qualifiers: J -estimated value. lJ -Non detect, R -Poor surrogate recovery, M -Recovery/RPO poor for MS/MSD, SAMPffiUP. B -detected in blank, S -field sample as received did not meet NE~C sample acceptance criteria, L -Subcontracted Lab used.
f:i: NELAC certified analysis
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Client Name: Davis & Floyd Page: Contact: John McCord Lab Project #: Address: 816 E. Durst Avenue Report Date:
Greenwood, SC 29649 Client Proj Name:
Client project#:
Case Narrative:AII samples must be run within 14 days of collection.
Page 20 of 20
P0502369
02/25/05
61621_01
61621_01
f ata Qualifiers: J -estimated value. U -Non detect, R -Poor surrogate recovery, M -Recovery/RJ. >D poor for MS/MSD, SAMP/DUP, B -detected in blank. S -field ample as received did not meet NEL~C sample acceptance criteria, L -Subcontracted Lab used
ri-NELAC cenified analysis
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Client Name: Davis & Floyd Page: Page 1 of 18
Lab Proj #: P0502445
Report Date: 03/03/05
Client Proj Name: Kubal & Furr
Client Proj #: 61621_01
Lab SamQle #
1'0502445-01
P0502445-02 ·
P0502445-03
P0502445-04
P0502445-05
P0502445-06
P0502445-07
P0502445-08
?0502445-09
P0502445-10
?0502445-11
1'0502445-12
P0502445-13
?0502445-14
,1pprovedBy:
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Client Sample ID
L05022402-01 IT-6
L05022402-02 IT-4
L05022402-03 IT-5
L05022402-04 V-23
L05022402-05 V-65
L05022402-06 FB-01
L05022402-07 K-28
L05022402-08 TRIP
BLANK-4
L05022301-01 IT-9
L05022301-02 IT-8R
L05022301-03 IT-2
L05022301-04 IT-3
L05022301-05 IT-7
L05022301-06 TRIP
BLANK-3
Laboratory Results
Total pages in data package:
1t :h'leet all the requirements of the NELAC standards.
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. I The analytical results reported here are reliable and usable to the precision expressed in this report. As required by some regulating authorities, a full I discussion of the uncertainty in our analytical resu!ls can be obtained at our web site or through customer service. Unless otherwise specified, all results
are reported on a wet weight basis.
As a valued client we would appreciate your comments on our service. I Please call customer servce at [phone] or email [e-mail]
Case Narrative The analytical results for samples L05022301-01 IT-3 and L05022301-05 IT-7 were confirmed by reanalysis at the laboratory. Although 1he sample identification were different the dates and times of collection were the same indicating that the samples I may be field duplicates.
220 William Pitt Way. Pittsburgh, PA 15238. Tel [phone]. Fax [phone]
website www.rnicroseeps.com email [e-mail]
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--
Client
Davis & Floyd, Inc.
Greenwood, SC 29649
Contac/
-
John H. McCord, Jr.
Collec/ed By
---
Project I Sile Location
61621 01
Report To
John H. McCord, Jr.
Tisa S. McCall/Sample Custodian
Samole Collectlon
---- ---------
Chain of Custody Record Page 1 of 1
816 E. Durst Avenue, Greenwood, SC 29649 [phone] Fax: [phone] ice Lse I imy Laboratory Certlfcation Numbers: SC -24110, NC. 25, TN -2923, VA -77
Copy To Repor1inr; Requirements: J(J Standard { J Data Package (Specify Level) Purchase Order NA
Atmospheric Conditions Required Parameters, Containers and Preservatives State ouore
_j ,~
C '.£ •>
NC
01 w 01 ~
~I
"" w ~ Samole Oescric tion Date Time 1ime Total Fraction HOT c .amments L05022402-01 IT-6 22-Feb 16:45 X 5 2 2
L05022402-02 IT-4 23-Feb 10:27 X 5 2 2
L05022402-03 IT-5 23~Feb 12:20 X 5 2 2
L05022402-04 V-23 23-Feb 9:45 X 5 2 2
L05022402-05 V-65 23-Feb 11 :20 X 5 2 2
L05022402-06 FB-01 22-Feb 17:45 X 5 2 2
L05022402-07 K-28 22-Feb 17:15 X 5 2 2
L05022402-08 TRIP BLANK-4 14-Feb 9:10 X 5 2 2
Date Time Reliquished By Date Time Reliquished By '.lil"' /1/,,Lt=;, 17 Received By Date Time Received By Date Time
1,.,,,omments
--•PERM_GASES FOR METHANE & CO2 ONLY"""SAMPLES FOR KUBAL & FURR AND ARE NOT TO EXCEED THE 14 DAY HOLDING TIME.
Malm: Type OefinItIons
Preservative Definitions
1 -Drinking Water 2 -Clean Water 5 -Groundwater 7 • Soil/Sediment 8 -Liquid Sludge 9 -011 12 -l-.Ir A -None B -H2S04 C -HCI O -HN03 E • NaOH F -FUtered G -Other
Date Time Quic~T T
y N
If Y, sp 1 :
___.-days
Shipped By
·~ CUEN!
Airr,,;;...ur;rmt:ier
Cooler tO~Uable):
On lea: ~,No Tamp(C) __ _
custody Seal: Intact I Broken I None
Davis & Floyd, Inc.
FL02 _ 01 (02199)
D~YIS ''11
'"'
1
'1
~ .lrd!Utt:tnre FL YD ·-klabot•"T"'""' Chain of Custody Record Client Project I Site Location 816 E. Durst Avenue, Greenwood, SC 29649 (864) 229•4413 Fax: [phone] Davis & Floyd, Inc,
Laboratory Certifcation Numbers: SC-24110, NC-25, TN-2923, VA-77 Greenwood, SC 29649 61621 01 Contact Report To Copy To Reporting Requirements:!)(] Standard ( J Data Package (Specify Level) John H. McCord, Jr. John H. McCord Jr. NA CoJtec/ed By
Atmospheric Condilk:ins Required Parameters, Containers and Preservatives Tisa S. _; McCa/llSampla Custodian
~J 0" ro Iona! ~> NOTICE: e 0 C :,: ·a
~ " "' I C 8 "' 0
"' • -~ 0 ., E ·~ " "~ 0 8. • ' i 3 Q,_ D .g 11 ~ E ,g ~ E "' Samele Cof!ectlon 0 e " " "' i= :s ~ u " ~ z "-Samele Descriotion Date Time Time Tvoe Total
L05022301-01 IT-9 22-Feb 9:53 X 5 2 2 L05022301-02 IT-8R 22-Feb 11 :20 X 5 2 2
L05022301-03 IT-2 22-Feb 10:39 X 5 2 2 L05022301-04 IT-3 22-Feb 12:45 X 5 2 2 L05022301-05 JT-7 22-Feb 12:45 X 5 2 2 L05022301-06 TRIP BLANK-3 14-Feb 9:10 X 5 2 2
Refiquisfled By Date nme Reliqutshe(! By Date Time Reliquished By 775a S' htC:r.11 II .'J.I.J..fl' I /J.JU, Received By Date Time 1-teceived By Dale Time vr:;;;J~OY!t;k 1.,,ommen/s -•••PERM_GASES FOR METHANE & CO2 ONLY ... SAMPLES FOR KUBAL & FURR AND ARE NOTTO EXCEED THE 14 DAY HOLDING TIME.
vla\m: Type Definitions
:oreservative Definitions
1 -Drinking Water 2 -Clean Water 5 • Groundwater 7 -So!llSedimenl 8 • Liquid Sludge 9 -011 12 -Air A -None B -H2S04 C -HCI D • HN03 E -NaOH F -Filtered G -Other ------------
Date
2/;J;/&5
--
Time
1610
-
Page 1 of 1
ice use n,y
Purchase Order
srate Quote
NC
i...O~Jn Special Instructions
is ~~
0 " C S ~" "~ °'" " . 0 'tl 3 ~ ~ ~ ..J
Frac1ion HOT omments
QuQ Shipped By a CLIENT y N ••o~~ /f Y, specify: Airb1.,...,u,,muer -days --
Coole~aaab!e):
on !c Ye No Temp(C) ___
custody Seal: Intact I Broken I None
Davis & Floyd, Inc.
FL02 _01 (02199) ----
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Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Matrix Lab Sample#
Page: Page 2 of 18
Lab Proj #: P0502445
Report Date: 03/03/05
Client Proj Name: Kubal & Furr
Client Proj #: 61621_01
Samgled Date/Time Received
Sample Description
L05022402-01 IT-6 I Analyte(s)
RiskAnalysis
Water P0502445-01 22 Feb. 05 16:45 27 Feb. 05 11:20
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Carbon dioxide
Methane
Flag Result PQL
320 0.60
8900 0.015
Units Method# Analysis Date
mg/L AM20GAX 3/1/05
ug/L AM20GAX 3/1/05
alita Qualifiers: J -estimated value, U -Non detect, R -Poor surrogate recovery, M -Recovery/RPO poor for MS/MSD, SAMP/DUP, B -detected in blank. S -field lample as received did not meet NELAC sample acceptance criteria. L -Subcontracted Lab used, N -NELAC certified analysis
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Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
SamQle DescriQlion Matrix
L05022402-02 IT -4 Water
Analyte(s) Flag Result
RiskAnalysis
Carbon dioxide 26
Methane 13000
Lab Sample#
P0502445-02
PQL
0.60
0.015
Units
mg/L
ug/L
Page: Page 3 of 18
Lab Proj #: P0502445
Report Date: 03/03/05
Client Proj Name: Kubal & Furr
Client Proj #: 61621_01
Sampled Datemme Received
23 Feb. 05 10:27 27 Feb. 05 11 :20
Method#
AM20GAX
AM20GAX
Analysis Date By
3/1/05
3/1/05
sl
sl
Data Qualifiers: J -estim:ited value, U -Non detect, R -Poor surrogate recovery, M -Recovery/RPO poor for MS/MSD, SAMP/DUP, B -detected in blank, S · field sample as received did not meet NELAC sample acceptance criteria, L-Subcontracted Lab used, N -NELAC certified analysis
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Client Name:
Contact:
Address:
SarTjple Description
Davis & Floyd
John McCord
816 E. Durst Avenue
Greenwood, SC 29649
Matrix Lab Sample#
Page: Page 4 of 18
Lab Proj #: P0502445
Report Dale: 03/03/05
Client Proj Name: Kubal & Furr
Client Proj #: 61621_01
Sampled Date/Time Received
I L05022402-03 IT-5
Analyte(s)
Water P0502445-03 23 Feb. 05 12:20 27 Feb. 05 11 :20
RiskAnalysis
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Carbon dioxide
Methane
Flag Result PQL
260 0.60
17000 0.015
Units Method# Analysis Date
mg/L AM20GAX 3/1/05
· ug/L AM20GAX 3/1/05
Ila Qualifiers; J • .estimated value, U -Non detccl, R-Poor surrogate recovery, M -Recovery/RPO poor for MS/MSD, SAMP/DUP,.B -detecled in blank. S -field mp\e as received did not meet NELAC sample acceptance criteria, L -Subcontracted Lab used, N -NELAC certified analysis
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Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Page: Page 5 of 18
Lab Proj #: P0502445
Report Date: 03/03/05
Client Proj Name: Kubal & Furr
Client Proj #: 61621_01
Received
Sample Description
L05022402-04 V-23
Matrix
Water
Lab Sample#
P0502445-04
Sampled Date/Time
23 Feb. 05 9:45 27 Feb. 05 11 :20 Analyte(s)
RiskAnalysis
Carbon dioxide
Methane
Flag Result PQL Units
230
16000
0.60
0.015
mg/L
ug/L
Method#
AM20GAX
AM20GAX
Arialysis Date
3/1/05
3/1/05
Da!a Qualifiers: J -estimated value, U • Non detect. R -Poor surrogate recovery, M -Recovery/RPO poor for MS/MSD, SAMP/DUP, B -detected in blank, S -field sample as received did not meet NELAC sample ncccptance criteria, L -Subcontrach.-<l Lab used, N -NELAC certified analysis.
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Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
I .. Sample Description Matrix • Lab Sample#
Page: Page 6 of 18
Lab Proj #: P0502445
Report Date: 03/03/05
Client Proj Name: Kubal & Furr
Client Proj #: 61621_01
Sam[:!led Date/Time Received
I L05022402-05 V-65 Water P0502445-05 23 Feb. 05 11 :20 27 Feb. 05 11:20 Analyte(s)
RiskAnalysis
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Carbon dioxide
Methane
Flag Result PQL
110 0.60
22000 0.015
Units Method# Analysis Date
mg/L AM20GAX 3/1/05
ug/L AM20GAX 3/1/05
Ila Qualifiers; J -estimated value, U -Non detect, R -Poor surrogate recovery, M -Recovery/RPO poor for MS/MSD, SAMP/DUP, B -detected in blank, S -fidd
nplc as received did not meet NELAC sample acceptance criteria, L -Subcontracted Lab used, N -NELAC certified analysis
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Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Page: Page 7 of 18
Lab Proj #: P0502445
Report Date: 03/03/05
Client Proj Name: Kubal & Furr
Client Proj #: 61621_01
Received
Sample Description
L05022402-06 FB-01
Matrix
Water
Lab Sample#
P0502445-06
Sampled Date/Time
22 Feb. 05 17:45 27 Feb. 05 11 :20 Analyte(s)
RiskAnalysis
Carbon dioxide
Methane
Flag
J
Result PQL Units
0.35
22
0.60
0.015
mg/L
ug/L
Method#
AM20GAX
AMZOGAX
Analysis Date
3/1/05
3/1 /05
Dala Qualifiers: J -cstimaled value, U -Non detect, R -Poor surrogate recovery, M -Recovery/RPO poor for MS/MSD, SAMP/DVP, B -detected in blank, S · field sample as received did not meet NELAC sample acceptance crileri.1, L -Subcontracted Lub used, N -NELAC certified analysis
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Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
San)Ple Description Matrix Lab Sample#
Page: Page 8 of 18
Lab Proj #: P0502445
Report Date: 03/03/05
Client Proj Name: Kubal & Furr
Client Proj #: 61621_01
Sampled Date!Time Received I L05022402-07 K-28
Analyte(s)
Water P0502445-07 22 Feb. 05 17:15 27 Feb. 05 11 :20
RiskAnalysis
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Carbon dioxide
Methane
Flag Result
160
16000
PQL Units Method# Analysis Date
0.60 mg/L AM20GAX 3/1/05
0.015 ug/L AM20GAX 3/1/05
l tu Qualifiers: J -estimated value, U -Non detect, R -Poor surrogate recovc1y, M. Recovery/RPO poor for MS/MSD, SAMP/DUP, B -detected in blank, S -field nplc as received did not meet NELAC sample .icceptancc criteria, L-Subcontracted Lab used, N -NELAC certified analysis
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Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Page: Page 9 of 18
Lab Proj #: P0502445
Report Date: 03/03/05
Client Proj Name: Kubal & Furr
Client Proj #: 61621_01
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Sample Description Matrix Lab Sample# Sampled Date!Time Received I L05022402-08 TRIP BLANK-4 Water P0502445-08 14 Feb. 05 9: 10 27 Feb. 05 11 :20 ~------=-----=--~~---,--,----~~~----.: Analyte(s) Flag Result PQL Units Method # Analysis Date RiskAnalysis
Carbon dioxide
Methane
u < 0.60
20
0.60 mg/L
0.015 ug/L
AM20GAX
AM20GAX
3/1/05
3/1/05
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Data Qualifiers: J -estimated value. U -Non detect, R-Poor surrogate recovery, M -Recovery/RPO poor for MS/MSD, SAMP/DUP, B -detected in bl;ink, S -field I sample as received did not meet NELAC sample acceptance criteria, L-Subcontracted L.1b used, N -NELAC certi_fied analysis
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Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Sample Description • Matrix Lab Sample#
Page: Page 10 of 18
Lab Proj #: P0502445
Report Date: 03/03/05
Client Proj Name: Kubal & Furr
Client Proj #: 61621_01
Sam pied Date!Time Received L05022301-01 IT-9 Water P0502445-09 22 Feb. 05 9:53 27 Feb. 05 11 :20 nalyte(s)
RiskAnalysis
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Carbon dioxide
Methane
Flag Result PQL
200 0.60
20000 0.015
Units Method# Analysis Date
mg/L AM20GAX 3/1/05
ug/L AM20GAX 3/1/05
lta Qualifiers: J -estimated value, U -Non detect, R -Poor surrogate recovery. M -Recovery/RPO poor for MS/MSD, SAMP/DUP, B -detected in blank, S · field 1ple as received did not meet NELAC sample acceptance criteria, L-Subcontracted Lab used, N -NELAC certified analysis
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Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
SamQle Description Matrix • L05022301-02 IT-BR Water
Analyte(s) Flag Result
RiskAnalysis
Carbon dioxide 230
Methane 16000
Lab Sample#
P0502445-10
PQL
0.60
0.015
Units
mg/L
ug/L
Page: Page 11 of 18
Lab Proj #: P050244 5
Report Date: 03/03/05
Client Proj Name: Kubal & Furr
Client Proj #: 61621_01
Sampled DatefTime Received
22 Feb. 05 11 :20 27 Feb. 05 11 :20
Method#
AM20GAX
AM20GAX
Analysis Date
3/1/05
3/1/05
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Data Qualifiers: J -estimated value, U -Non detect, R -Poor surrogate rccoveiy, M -Recovery/RPO poor for MS/MSD, SAMP/DUP, B -detected in blank, S -fit:ld I sample as recc:ivCO did not meet NELAC sample ncceptance criteria, L -Subcontracted L.1b used, N -NELAC certified analysis
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Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Sam[)le Descri[)tion Matrix Lab Sample#
Page: Page 12 of 18
Lab Proj #: P0502445
Report Date: 03/03/05
Client Proj Name: Kubal & Furr
Client Proj #: 61621_01
Sam[)led Date!Time Received
L05022301-03 IT-2 Water P0502445-11 22 Feb. 05 10:39 27 Feb. 05 11 :20 l~:--------;=;-~~-.----.-.=---;-;-~~c-;::-...,-----
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Analyte(s)
RiskAnalysis
Carbon dioxide
Methane
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Flag Result PQL Units Method# Analysis Date
320 0.60 mg/L AM20GAX 3/1/05
9300 0.015 ug/L AM20GAX 3/1/05
~ata Qualifiers: J -estimated value, U -Non detect, R. Poor surrogate recovery, M -Recovery/RPO poor for MS/MSD, SAMP/DUP, B -detected in blank, S · field ■ample as received did not meet NELAC sample acceptance criteria, L -Subcontracted Lab used, N -NELAC certified am1lysis
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Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
SamQle DescriQtion Matrix Lab Sample#
Page: Page 13 of 18
Lab Proj #: P0502445
Report Date: 03/03/05
Client Proj Name: Kubal & Furr
Client Proj #: 61621 01
SamQled Date!Time Received L05022301-04 IT-3 Waler P0502445-12 22 Feb. 05 12:45 27 Feb. 05 11 :20 Analyte(s) Flag Result PQL
RiskAnalysis
Carbon d·1oxide 37 0.60
Methane 21000 0.015
Units
mg/L
ug/L
Method#
AM20GAX
AM20GAX
Analysis Date
3/1 /05
3/1/05
Dat;i Qualifiers: J -estimated value, U -Nau detect, R -Poor surrogate recovery, M -Recovery/RPO poor for MS/MSD, SAMP/DUP, B -detected in blank, S -field sample as received did not meet NELAC sample .:1cceptance criteria, L-Subcontracted Lah used, N -NELAC certified analysis
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Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
SamQle DescriQlion Matrix • Lab Sample#
Page: Page 14 of 18
Lab Proj #: P0502445
Report Dale: 03/03/05
Client Proj Name: Kubal & Furr
Client Proj #: 61621_01
Sampled Date/Time Received L05022301-05 IT-7 Water P0502445-13 22 Feb. 05 12:45 27 Feb. 05 11 :20 1 ~.,---------;:,;------;c:----;:----;:~~~~~----==-Analyte(s)
RiskAnalysis
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Carbon dioxide
Methane
Flag Result PQL Units Method# Analysis Date
280 0.60 mg/L AM20GAX 3/1/05
14000 0.015 ug/L AM20GAX 3/1/05
aata Qualifiers: J -estima1ed value, U. Non detect, R-Poor surrogate recovery, M -Recovery/Rl'D poor for MS/MSD, SAMP/DUP, B -detected in blank. S -field ■;:imple as received did not meet NELAC sample acceptance criteria, L -Subconlrncted Lab used, N · NELAC certified analysis
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Clienl Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Sample Description Matrix Lab Sample#
Page: Page 15 of 18
Lab Proj #: P0502445
Report Date: 03/03/05
Client Proj Name: Kubal & Furr
Client Proj #: 61621 01
Sampled DaterTime Received L05022301-06 TRIP BLANK-3 Water P0502445-14 14 Feb.05 9:10 27 Feb. 05 11 :20 Anatyte(s) Flag Result
RiskAnalysis
Carbon dioxide u < 0.60
Methane 22
PQL Units
0.60 mg/L
0.015 ug/L
Method#
AM20GAX
AM20GAX
Analysis Date
3/1 /05
3/1/05
Data Qualifiers: J -estimated value, U -Non detect, R -Poor surrogate recovery, M -Recovery/RPD poor for MS/MSD, SAMP/DUP, B -detected in blank, S -field sample as received did not mecl NELAC sample acceptance criteria, L-Subcontracted Lab used, N -NELAC certified analysis
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Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Page: Page 16 of 18
Lab Proj #: P0502445
Report Date: 03/03/05
Client Proj Name: Kubal & Furr
Client Proj #: 61621_01
M050301018-MB
Result
Methane < 0.015 ug/L
M050301018-LCS
Result
Methane 73 ug/L
M050301018-LCSD
Result
Methane 72 ug/L
Prep Method: In House Dissolved Gas Sample Preparation
Analysis Method: Analysis of Dissolved Methane in Waler
TrueSpikeConc. RDL %Recovery Ctl Limits
0.015 -NA
TrueSpikeConc. %Recovery Ctl Limits
71.93 101.00 75 -125
TrueSnikeConc. %Recove[Y Ctl Limits RPD RPD Ctl Limits
7 l.93 100.00 75 -125 1.38 0 -20
'-------'' Outlined Results indicate results outside of Control limits
l ata Qualifiers: J -estimated value, U -Non detect, R -Poor surrogate recove,y, M -Recovery/RPO poor for MS/MSD, SAMP/DUP, B -detected in hlank, S -field mple as received did not meet NELAC sample acceptance criteria, L -Subcontr.icted Lab used, N -NELAC certified analysis
I
Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
M050301019-MB
Page: Page 17 of 18
Lab Proj #: P0502445
Report Date: 03/03/05
Client Proj Name: Kubal & Furr
Client Proj #: 61621_01
Prep Method: Analysis of Dissolved Permanent Gases in Water
Analysis Method: Analysis of Dissolved Permanent Gases in Water
Result TrucSnikeConc. RDL %Recove!:Y CU Limits
Carbon dioxide
M050301019-LCS
Carbon dioxide
M050301019-LCSD
< 0.60
Result
100
mg/L
mg/L
0.60 -NA
TrueSgikeConc. %RecoverY._ CU Limits
106.20 94.00 75 -125
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Result TrueSgikeConc.
Carbon dioxide 100 mg/L 106.20
%Recovery CU Limits
94.00 75 -125
RPD
0.00
RPO Ctl Limits I
0 -20
!outlined Results indicate results outside of Control limits ~----~
Datu Qualifiers: J -estimated value, U -Non detect, R -Poor surrogate recovery, M -Recovery/RPO poor for MS/MSD, SAMP/DUP, 8 -detected in blank, S -field
sample as received did not meet NELAC sample acceptance criteria, L -Subcontmcted Lab used, N -NELAC certified an:1lysis
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Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Page: Page 18 of 18
Lab Proj #: P0502445
Report Date: 03/03/05
Client Proj Name: Kubal & Furr
Client Proj#: 6162(_01
a:>ata Quillifiers: J • estimated value, U • Non detect, R -Poor surrogate recovery, M -Recovery/RPO poor for MS/MSD. SAMP/DUP, B -detected in bhmk, S -field aample as received did not meet NELAC sample acceptance criteria, L-Subcontracted Lab used, N -NELAC certified analysis
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Kubal·Furr & Associates
-Em·irL,11111,·ntal Co11s11ltm1ls-
Purged Well Sampling Log
Project No. o<i
Site Location CNA Holdings/Ticona,
Field Personnel _____ _,6"'·,.,_';k._~----
Well I Sample ID -r:J: -f
P-,. / / Weather Condition 'l4r2rL7 J..1y'"7 f;{;
Sample Dale ' fl/,: (tS A,ri,al Time;=::!/'::.:::Jd::::::6:::;'-9 ____ ~:'.:Sa:m'.'.'.p:'.:le:_T:im.'.'.e:'._-----'-/-'.S'..-,:::~:::;2.===
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'------' lrlC~.e1
Total Death ot Well Belowl MP? L/J. 7), ,.,,I
Depth to Water Below MP?I ,? ~s, ( C, I
;=:::· ~====<! ~··"
I a .. r'J_ I Column of Wah;r in Well? /, '"-4
:=· =====±:::====='=;'···
Gallons of Water pe_r Foot I /j J /3 I
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:======:::9::a'="a=;o'
Gallons of Water in Well?
Gallons of \Noter ro be
Purged (3X)?
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Initial
Time
T emperoture
Specific Conductance
2
Common Gallons per Foot Conversions
1 1 / 1 in Well Cosing = 0.06~ gal / foot
1 1/i in Well Cosing= 0.092 gal/ foot
2 in Well Casing= 0.163 gal/ foot
3 in Well Casing= 0.367 gal/ foot
3 1/2 in Well Casing= C.SCO gel/ foot
4 in 'Nell Cosing = 0.653 gal / foot
6 in Well Casino= 1.469 aol / foot
Purge Stop Time ~~~er-<<--->~--~
DO
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Samples Collected Container Description Preservative
TI/:f
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Revise 5/28/02
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Kubal-Furr & AssociJtes
-Eu~·ir,'1:1.•:~·1!1,1/ Co11;;1dt,.111ts-
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Purge•j :J:<J?
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Tirne
Temperature
Specific Conductance
pH
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S•:implei Collected
'
Parameter Conditions: pH
Turbidity
I
Purged Weil Scmpling Log
/) . ·//_ ✓---r,:~-Project No. I
Site Location
Field Personnel
CNA Holdings/Ticona, Shelby. NC
o/fs-s-
2 in Well Co;ir.g = C. i .:3 g:::I / foot
3 in ','/el: Cc1in;i = C.3::7 g..::I / fvor
10:01 Gclloni Purged/ <S, -,S-J
Pur9e Slop Time I ('f''f J2...
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Container De~cription Preservo\i,:B
+/. 0.1 standard unit
+/-10'.';above 10NTU
COND/Temp +/-3~ DO
+/-1 r--nu below 10 NTU
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I
I Attachment 2
I Time vs Concentration Water-Quality Plots
I
I
I
I
I
I
I
I
I
I
I
I
I Kubal-Furr & Associates
I
I CC-33 Plots
I
I Ethylene Glycol Total Oryanic C.-.
8.0 3.0
V
I ,...., 6.0 i i 20
C ~ i 4.0
I I ,o -----·
J --
2.0
I 0.0 0.0
May-04 Jul-04 Sep-04 Nov-04 Jan.OS May-04 Jul-04
Dato
I Manganese
I 3.6 2
'.} ..... 1.5 ~ I } 32 }
C ~ 0 ., s s ~ 2.8 -J I 8 0.5
2.4 0 I May-04 Jul-04 Sflp-04 Nov-04 Jan-OS May-04 Jul-04 -
I Date ffi TOC Mar,ga--"""' Methane
mg/L mg/L mg/L mg/L
5/24/04 <7.0 <1.0 3.3 0.63 I 8/10/04 <7.0 1.2 3.1 O.SSJ
11 /9/04 <7.0 2.8 2.9 0.35J
2/18/05 <7.0 1.2 2.9 0.43
Notes:
I J = The anatyte was positively identified: the associated numerical value is the approximate concentration of the analyte in the sample.
* Trend line shown as a dashed gray line
I
I
I
I
Sep-04 No,-04
Dato
Methane
V
Sep-04 Nov-04
Dato
Jan-OS
Jan-OS
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
F-55 Plots
Ethylene Glycol Total Organic Carbon
7000
6000
i 5000
~ 4000
i 3000
2000 -~
1000
0
May-04
216
212
i 7.08
I
J 204
200
196
May-04
Date ~
mg/L
5/26/04 1990
8/11/04 3790
11/10/04 5300
2/18/05 5500
Notes:
__....---::.---~---
Jul-04
--
Jul-04
roe
mg/L
3590
4260
4810
4770
Sep-04
Date
--
Nov-04
--
Sep-04 Nov-04
Date
Ma~nese Methane
mg/L mg/L
215 2.6
204 2.GJ
205 4.0J
208 2.8
I 6000
I --I -I
5000
i 4000
I
I
I
I 3000
C j 2000
1000
I
' 0
Jan-OS May-04 Jul--04
4
i 3
i I 2
0
Jan-OS May-04 Jul-04
J "' The analyte was positively identified; the associated numerical value is the approximate concentration of the analyte in the sample. * Trend line shown as a dashed gray line
---
Sep-04 Nov-04 Jan-05
Date
Methane
/~-
~
Sep-04
Date
Nov-04
.....
..tan-05
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT-1 Plots
EthyleneGlyt:ol Total Or!lanic Dubon
36
30
124
B 18 s
J 12
6
0
May-04
10
8
1 6
i 4
2
0
May-04
!1o!o ~
mg/l
5/25/04 16.8
8/11/04 31.2
11 /9/04 <7.0
2/18/05 <7.0
Notes:
Jul-04
Jul-04
IQ!;
mg/L
678
329
2.8
7.8
Sep--04
Date
Manganese
Sep-04
Date
Magnese
mg/l
5.6
8.9
2.8
2.1
750
600
i 450
B s 300 I
150
0
Noe-04 Jan-OS May-04 Jul-04
30.0
24.0
~ _. 18.0
-i 12.0 J
6.0
0.0
Nov-04 Jan-OS May-04 Jul--04
Methane
mg/L
18.0
11.0J
17.0J
23.0
J = The analyte was poslttvely identified; the associated numerical value is the approximate concentration of the analyte in the sample. * Trend 6ne shown as a dashed gray line
..._ ..._
Sep---04 Nov-04
Date
Methane
Scp-04 Nov-04
Date
..._ ..._
Jan-OS
Jan-OS
I
I IT-2 Plots
I
I Ethylene Glycol Total Organic Carbon
I
I
I
I
I
8.0
0.0
May--04 Jul-04 Sep-04
Date
Manganese
Nov-04
I
Jan-OS
8 ,--------------------------
~6+------------=--P--~ r ---
500
400
i 300
C
i 200 J '
100
0
May-04 Jul--04
18.0
'.]
]: 12.0 I ~ ---j s
I I 2 .\------------------:
I May-04 Jul-04
I ~ ~ roe
mg/L mg/L
5/25/04 <7.0 408
I 8/11 /04 <7.0 76.4
11/10/04 <7.0 3.1
2/22/05 <7.0 7.3
Notes:
Sep-04
Date
Maooanese
mg/L
5.2
4.1
4.0
7.4
Nov--04 Jan-OS
Methane
mg/L
13.0
5.9J
6.4J
9.3
6.0
0.0
May-04 Ju\-04
I J ., The analyte was positively identified; the associated numerical value is the approximate concentration of the analyte in the sample.
* Trend line shown as a dashed gray line
I
I
I
I
'
' '
Sep-04 Nov--04
Date
Methane
------
Sep-04 Nov-04
Date
'
Jan-OS
Jan-OS
I
I IT-3 Plots
I
I Ethylene Glycol
8.0 ·--------------------------
T-Organic Cari>on
30
I i 6.0
I I 40
2.0 +-------------------------~
i
C l! ~
J
24
18 -12 ------
I
I
I
I
I
I
I
I
I
I
I
0.0 .L-------------------------.1
1.6
0
!10!0
5/25/04
8/11 /04
11/10/04
2/22/05
Notes:
Jul-04
-~
Sep-04
Date
Manganese
~----
May-04 Jul-04
!'!, roe
mg/L mg/L
<7.0 28.3
<7.0 8.5
<7.0 10
<7.0 4.5
.._ ...
Sep-04
Date
Nov--04
Manaanese Methane
mg/L mg/L
1.6 18.0
1.1 14.0J
0.62 9.4J
0.79 21.0
Jan-OS
I ---.
Jan-OS
6 -Q.
May-04 Jul-04 Sep-04 No,-04 Jan-OS
Date
24.0 -------------------------
118.0
1120
6.0 l---------------------_J
0.0 ·+-------------------------'
May-04 Sep-04
Date
Nov-04 Jao-05
J .. The analyte was positively identified; the associated numerical value is the approximate concentration of the analyte in the sample.
• Trend line shown as a dashed gray line
I
I
I
I 8.0
I ..-. 6.0 ;;. g
,§ 4.0
I s
J 2.0
I 0.0
May-04 Jul-04
I
Ethylene Glyool
SeJ>-04
Date
Manganese
No,-04 Jan-OS
IT-4 Plots
16
-
I
0
.__ -----
May-04 Jul-04
Total °'1lanic Camon
-------
Sei>-04
Date
Methane
No,-04
---~
I
Jao-05
I 1.6 ~----------------------~ 24.0 ~---------------------~
,.., 18.0
------I i 1.2 i ------B 0.8 .§ 12.0 s s
I J 0.4 J 6.0
I 0 0.0
May-04 Jul-04 Sep-04 Nov-04 Jan.OS May-04 Jul-04
Date
I Date §, TOC Ma~nese Methane
mg/L mg/L mg/L mg/L
5/25/04 <7.0 12.8 1.1 15.0
18/11/04 <7.0 8.6 1.3 19.0J
11/10/04 <7.0 7.9 0.60 8.SJ
2/23/05 <7.0 6.7 1.2 13.0
Notes:
I J .. The analyte was positively identified; the associated numerical value is the approximate concentration of the analyte in the sample.
'"Trend line shown as a dashed gray line
I
I
I
I
Sep-04
Date
Nov-04 Jan-OS
I
I
I
I 8.0
I ,... 6.0
i
I
§ 4.0
! 20
I 0.0
May-04 JuH)4
I
I 10
8 -s-
~-
I 0
May-04 Jul--04
1-~
mg/L
TOC
mg/L
5/25/04 <7.0 200 18/11/04 <7.0
11/10/04 <7.0
2/23/05 <7.0
12.6
17.4
17.4
I
I
I
I
I
Ethylene Glycol
S.p-04
Date
Manganese
----
S.o-{)4
Date
Manganese
mg/L
7,8
3,6
2.9
3,6
No•-04 Jan-OS
----
Nov--04 Jan-OS
Methane
mg/L
17.0
13.0J
270J
17.0
IT-5 Plots
Total Organic Carbon
250
200
i 150
i 100 J
50
0
\ -,\:, I
\ ' ' I ' ' ' \_ ' ' I ' ' '
May-04 Jul-04 S.p-04 Nov-04 Jan-OS
Date
Methane
300
....... 225 i
C i 150
-J -------
75 --
I
---
0
May-04 Jul-04 S.p-04 Noe-04 Jan-OS
Date
I
I IT-6 Plots
I
I Ethylene Glycol Total Organic Carbon
150 6000
.--5000 I 120
i i 4000
-~
I
I
I
I
I
I
I
90
i 60
30
0
750
600
1450 I 300
150
0
•~
5/26/04
18/11/04 11/10/04
2/22/05
Notes:
May-04 Jul-04
.
May-04 Jul-04
g; roe
mg/L mg/L
<70.0 5240
<140 4740
<35.0 3920
<7.0 2760
Sep--04
Date
Manganese
Sep--04
Date
Ma!!Q@nese
mg/L
699
624
553
452
No.--04 Jan-OS
-------
No,-04 Jan.-05
Methane
mg/L
8.8
9.0J
340J
8.9
-B 3000
I 2000
1000
0
May-04 Jw--04
360
300
i 240
-B 160
I 120
60
0
May-04 Ju!-04
I J .. The analyte was positively identified; the associated numerical value is the approximate concentration of the analyte in the sample.
* Trend fine shown as a dashed gray line
I
I
I
I
Sep--04
Date
Methane
Sep--04
Date
--..,,,_________ -
No,-04 Jao-05
--
Nov-04 Jao-05
....
I
I
I IT-7 Plots
I
I 40.0
Ethylene Glycol Total Organic Carbon
2500
--I 32.0
i ....., 24.0
~ I s 16.0 J
8.0
-' '\
'\ I
'\ •
--2000
~ ----! 1500 ----I 1000 J
500
I 0.0
May-04 Jul-04 Sep--04 Nov-04 Jan-OS
0
May-04 Jul-04 5ep--04 Nov-04 Jan.-05
Date Date
I Manganese -500 16 . I ----400 / -----
I l 300 ----~ -7 ----s 200
I J --
100 ·
I 0
May.Q4 Ju\-04 Sep--04 No,-04 Jan-OS
Dote
0
May-04 Jul-04
I Date ~ TOC Manaanese Methane
mg/L mg/L mg/L mg/L
5/26/04 <28.0 1980 389 9.3
I 8/11/04 <35.0 2170 373 7.9J
11/10/04 <35.0 808 292 !SJ
2/22/05 <7.0 37.2 25.7 14.0
Notes:
I J • The analyte was positively identified; the associated numerical value is the approximate concentration of the analyte in the sample .
.. Trend line shown as a dashed gray line
I
I
I
I
Sep--04
Date
Nov-04 Jan+OS
-~
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
50.0
40.0
~ ...., 30.0
I 20.0 J
10.0
0.0
56.0
48.0
i 40.0
~ 32.0
I 24.0 J 16.0
8.0
0.0
!lm
5/26/04
8/11/04
11/10/04
2/22/05
Notes:
May-04 Jul-04
..__
Ethylene Glycol
Sep-04
Dote
Manganese
• 7
/
7 ,
No,-04 Jan-OS
---..,,,______ -----/
----_/
~
May-04 Jul-04 Nov--04 Jan-OS
,;i; TOC --mg/L mg/L mg/L mg/L
<7.0 883 51.0 11.0
<7.0 583 43.9 13.0J
<7.0 210 31.5 17.0J
42.0 413 46.6 16.0
IT-8R Plots
I
1000
800
'.J t 600
C I 400 J
200 ·
0
May-04
18.0
15.0
I i 12.0 -C
I I 9.0
6.0
3.0
I 0.0
May-04
Jul-04
Total Organic Camon
Sep-04
Dote
Nov--04
Methane
__,/ ---~----
Jul-04 Sep-04 -Nov-04
J .. The analyte was positively identified; the associated numerical value is the approximate concentration of the analyte in the sample.
* Trend line shown as a dashed gray line
-
Jan-OS
---
JarrOS
I
I
I
I 8.0
Ethylene Glycol
I
~ 4.0
I j
2.0
I 0.0
May-04 Jul-04 Sep-04 Nov--04 Jan-OS
Dote
Manganese
I 100 . ----"-.. 80 • ---
IT-9 Plots
I
100
80
I
0
30
24
T otaJ Organic Carbon
. __ / "' -----~--
May-04 Jul-04 Sep-04 -
Methane
'
Nov-04
---
Jan-OS
I
'.] -------]'. 18 60 ------~ --· ----
s
e I -~----I !
40 12 !
20 6
-.,.
I 0 0
May-04 Jul-04 Ser>()4 Nov--04 Jan-05 -May--04 Jul-04
I Date ~ roe ~nQ!:!nese Methane
mg/L mgll mg/L mg/L
5/26/04 <7.0 49.7 77.3 11.0
18/16/04 <7.0 84.0 91.6 16.0J
11/10/04 <7.0 30.5 65.3 23.0J
2/22/05 <7.0 31.3 60.2 20.0
Notes:
I J .. The analyte was JX)Sitively identified: the associated numerical value is the approximate concentration of the analyte in the sample .
... Trend line shown as a dashed gray line
I
I
I
I
Ser>()4 -No,-04 Jan-OS
I
I
I
I
I
I
I
I
I
8.0
0.0
May-04 M-04
Ethylene Glycol
Sep-04
Date
Manganese
.
Nov-04 Jail-OS
J-29 Plots
120
I
90 i
j 60
30
0
' ,\
May-04
1.2 .-----------------------~ 0.0200
Total °'1lanic Cart,on
\'',,
\ -
JC-04
'
Sep-04
Date
Methane
' ' -.
No,-04
~ '
i 0.0150
-I 0.0100
J 0.0050 ~-
----
I 0
May-04 Jul-04 Sep-04 Nov-04 Jan-OS
Date
0.0000
May-04 Jul-04
I Date ~ TOC --mg/L mg/L mg/L mg/L
5/25/04 <7.0 96.9 0.83 0.0020
18/9/04 <7.0 S.3 0.69 0.0028J
11 /9/04 <7.0 11.6 0.33 0.0071J
2/17/05 <7.0 1.6 0.30 0.0089U
Notes:
I U = The analyte was analyzed for, but was not detected above the reported sample quantitation limit.
J = The analyte was positively identifl_ed; the associated numerical value is the approximate concentration of the analyte in the sample.
'"Trend tine shown as a dashed gray hne
I
I
I
I
--
Sep--04
Date
Nov-04
Jan-OS
~
Jan-OS
I
I
I
I 300.0
I 250.0
j 200.0
~ 150.0
I ~ C j 100.0
50.0
I 0.0
~ _,
I
Ethylene Glycol
_,/
_,,,,,..,,,,.,,,,..·/
,
Jul-04 Sep,-04
Date
Manganese
/ /.,,,,.'
Nrn,-04
K-28 Plots
Total CJ,yan.: Camon
3000
2400 _, _, i 1800
I I 1200
600
I 0
Jan-OS May-04 Jul-04 Sep,-04 """-04 Jan-OS -
Methane
20.0 I ~---
I I 30 +------------:~~~~-------1
16.0
i 12.0
-/ -------
I 1::.f----.---___ ________._, J 8.0
4.0
I
I
I
I
I
I
I
I
0 0.0
May-04 JuH)4 Sep-.-04 Nov-04 Jan-05 May-04 Jut.-{)4 -
Q<l!! ~ TOC Maim!leSe Methane
mg/L mg/L mg/L mg/L
5/25/04 <35.0 1230 17.8 13.0
8/10/04 <35.0 2110 32.3 12.0J
11 /9/04 227 2710 41.3 19.0J
2/22/05 244 60.4 10.5 16.0
Notes:
J .. The analyte was positively identified; the associated numerical value is the approximate concentration of the analyte in the sample.
* Trend line shown as a dashed gray line
Sep-04 -Nov-04
.
Jan-OS
I
I N-29 Plots
I
I
I
8.0
Ethylene Glycol
I
Total Organic Carbon
i 1.5
I
i 60
I 40
! 20
j 1.0 +-______ .-,,,.::_ _________ _::,~--j
J 0.5 +------------------------l
I
I
I
0.0
Jut-04 Sep-04
Date
Nov--04 Jan-OS
0.4 ~----------------------~
,..,, 0.3 +--------------------------l
I f 02l-!e=~-----,._j s I ! 01 +-------~
0 I May-04 JuH)4 Sep-04 No,-04 Jan-OS
Date
I Date ~ TOC Manaane,e Methane
mg/L mg/L mg/L mg/L
5/24/04 <7.0 <1.0 0.21 0.66
I 8/10/04 <7.0 <1.0 0.20 0.47J
11/9/04 <7.0 1.6 0.20 l.SJ
2/18/05 <7.0 <1.0 0.20 0.95
Notes:
May-04 Jul-04
2
1.6
i 1.2
I 0.8 !
0.4
0
May-04 Jul-04
I J • The analyte was positively identified; the associated numerical value is the approximate concentration of the analyte in the sample.
" Trend line shown as a dashed gray line
I
I
I
I
Sep--04
Date
Sep-04
Date
Nov-04
No,-04
Jan-OS
Jan-05
I
I 0-25 Plots
I
I Ethylene Glyrol Total Organic Carbon
I
I
I
I
I
I
I
I
'.J'
8.0
0.0
May-04 Jul--04 Se,,.04
Dato
Manganese
N~-04
I
I
Jan-OS
0.6 ------------------------
0.51----------------------
r o•
C I 0.3
C j 0.2
0.1
0
May--04 Jul--04 Se,,.04 Nov-04 Jan-OS
Dato
30
. -
0
May-04 JuHJ4
3
2.5
0.5
0
May-04 Jul--04
•~ ~ TOC Ma~~ Methane
mg/L mg/L mg/L mg/L
I
I
I
I
I
I
5/25/04 <7.0 21.4 0.46 1.2
8/10/04 <7.0 22.0 0.44 1.1J
11/9/04 <7.0 27.0 0.44 1.3J
2/18/05 <7.0 21.3 0.42 0.76
Notes:
J • The analyte was positively identified; the associated numerical value is the approximate concentration of the analyte in the sample. * Trend line shown as a dashed gray line
----
Seo-()4
Dato
Methane
Se,,.04
Dato
~ ....__
------
--04
I
Jan-OS
-
Jan-OS
I
I
I
I
I
I
I
I
I
I
I
I
Q-33 Plots
8.0
0.0
May-04 Jul--04
Ethylene Glycol
'
Sep-04
Date
Manganese
Nov--04 Jan--05
0.80 ~----------------------
i 0.60
! 0.40
J 0.20 ---------
0.00
May-04 Jul--04 Sep-04 Nov-04 Jan--05
Date
I
I
Total °'1lanic Camon
i 6+.----------------------
a•+--------_,,,=-_-.,,,_. ___ _
j21-=-=_;:..-=------~
May-04
0.1
0.08
i 0.06
i J 004
0.02
0
May-04
Jul-04
----
Jul-04
Sep-04
Date
Nov-04
_/-----
Sep-04
Date
--04
Jan-OS
~ I -
;.m-OS
I Date ~ IQ!; Manaanese Methane
mg/L mg/l mgll
I
I
I
I
I
I
mg/L
S/24/04 <7.0 1.5 0.10 0.0037
8/9/04 <7.0 2.7 0.44 0.0014J
11/9/04 <7.0 4.8 0.090 0.036J
2/17/05 <7.0 1.9 0.091 0.048J
Notes:
J • The analyte was positively identifled; the associated numerical value is the approximate concentration of the analyte in the sample. * Trend line shown as a dashed gray line
I
I
I
I Ethylene Glycol
8.0
I ....... 6.0 J }
I 4.0
I J 2.0
I 0.0
May-04 Jul--04 Sep-04 No,-04 Jan--05
Date
I Manganese
I 0.2
.-.. 0.1 S
I i
I 0.1
I J 0.05
I 0
May-04 Jul-04 Se.,.04 Nov-04 Jan--05
Date
Tl-1 Plots
Total °'lJanic Carbon
4.0 ,------------------------
i 30
----i 20
1.0 +-+-------<?.----------___c,._-j
0.0 +-------------~----------s
May-04 J"-04
0.15
0.12
~ ..... 0.09 i 0.06
O.D3 -
0 . .-
May-04 Jul-04
-
Sep-04
Date
Methane
No,-04 Jao-05
/
-✓--
__ .,,,..,,..,,,,...,,,,../
-
Sep-04
Date
Nov-04 Jan-OS
I Date ~ TOC Ma, II08I ,ese Methane
mg/L mg/L mg/L mg/L
I
I
I
I
I
I
5/24/04 <7.0 <1.0 0.026 0.0066
8/11/04 <7.0 <1.0 0.088 0.01 lU
11/9/04 <7.0 2.6 0.12 0.026U
2/16/05 <7.0 <1.0 0.069 O.llU
Notes:
U • The analyte was analyzed for, but was not detected above the reported sample quantitation limit.
.. Trend line shown as a dashed gray line
I
I
I
I 10.0
I 8.0
I
2.0
I 0.0
May-04
I
I 0.2
I
I
i 0.15
! 01
J 005
I 0
May-04
I Date ~
mg/L
5/24/04 <7.0
<7.0
8.8
Ju\-04
Jul-04
TOC
mg/L
<1.0
<1.0
1.4
Ethylene Glycol
-
Sep-04
Date
Manganese
Sep-04
Date
Manaanese
mg/L
0.055
0.058
0.058
-~
Nov-04
Nov-04
Methane
mg/L
0.0012
0.00049U
0.021U
<7.0 <1.0 0.054 0.0026U 18/9/04
11/9/04
,2,_/_cl 6e,/.e0.e_S __ -'c""----"""----""~--'""""""-
Notes:
Jan-05
Jan-OS
U-38 Plots
I
i 15
! 1.0
Total Organic Carbon
j 0.5 +------------------------a
May-04 Jul-04 Sep-04
Date
Methane
N<w-04 Jan-05
0.04 -----------------------
i 0.03
,§ 0.02 +--------------'"----------' s
J 0.01 +-----------+-------'"=~---a
May-04 Jul-04
--
Sep-04
Date
------
Nov-04 Jan-OS
I U = The anatyte was analyzed for, but was not detected above the reported sample quantitation limit.
• Trend line shown as a dashed gray line
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
V-23 Plots
10000
8000
i 6000 i 4000
2000
0
..
May-04 Jul-04
Ethylene Glycol
---
Sep-04
Date
I
Nov-04 Jan-OS
1250 -----------------------
1000
750
500 +-------------------------'
250 +-------------------------'
l!i!!o
5/26/04
8/16/04
11/10/04
2/23/05
Notes:
o+-------------------------'
May-04 Jul-04
§i TOC
mg/L mg/L
7230 11200
8200 9840
6460 12700
6740 10700
Sep-04
Date
MaOO@n!l!H
mg/L
963
933
884
772
Nov-04 Jao---05
Methane
mg/L
11.0
12.0J
13.0J
16.0
i
I j
15000
12000 -
9000
6000
3000
0
May-04
Total Organic Carbon
Jul--04 Sep-04
Date
Methane
Nov-04 Jan-OS
20.0 -----------------------
16.0 +--------------------~->-, --i 12.0 6=~-'=='::-===-:::!::--=--~---1 i 80 +--------------------1
4.0 +-------------------------,
0.0 +----~---~----~-------~
May-04 Jul-04 Sep-04
Date
No,-04
J • The analyte was positively identified; the associated numerical value is the approximate concentration of the analyte in the sample.
.. Trend line shown as a dashed gray line
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
V-65 Plots
Ethylene Glycol
8.0 ------------------------
i 60
i 40
j ,ol---------------------_J
0.0 +---------~---~--------
May-04 Jul--04 Seo-04
Date
Nov--04 Jan-OS
1.6 ,------------------------
0 +-----------------~-----;
May-04 Jul-04
Date §, TOC
mg/L mg/L
5/26/04 <7.0 1.5
8/16/04 <7.0 1.8
11/10/04 <7.0 4.4
2/23/05 <7.0 1.1
Notes:
Seo-04
Date
Ma~~
mg/L
1.1
0.96
0.84
1.2
Nov-04 Jan-05
Methane
mg/L
15.0
18.0J
19.0J
22.0
Total Organic Carbon
}3+---------/-------7
j,t--==:::::::--~--~--------"-"'
o+---------~-------~----
May-04 Jul-04 Sep--04
Date
Methane
Nov--04 Jan-OS
24.0 ,-----------------------
i 18.0 i 12.0
6.0 ./-----------------------1
0.0 +-------------~----------;
May-04 Jul-04 Seo-04
Date
No,-04 Jan-05
J .. The analyte was positively identified; the associated numerical value is the approximate concentration of the anatyte in the sample.
* Trend line shown as a dashed gray line
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
W-23 Plots
Ethylene Glycol
8.0 ~--------------------~
i 60
i 40
J 20-1-------------------------~
0.0 -1----~----~---~---~-------s
2.5
2
i 1.5
i
J
0.5
0
Date
5/24/04
8/10/04
11/9/04
2/17/05
Notes:
May--04 Jul-04 Sep-04
Date
Manganese
-~---
May-04 Jul--04
~ TOC
mg/L mg/L
<7.0 2.3
<7.0 1.3
<7.0 3.0
<7.0 3.6
Sep--04
Date
Maaganese
mg/L
1.5
1.9
2.1
1.9
No,--04 Jan-OS
...
No,--04 Jan-OS
Methane
mg/L
0.0081
0.0069U
0.62J
0.03U
Total Organic Carbon
i3+-----------;;..-=------1
i2+-----~-----------j
May--04 J~--04 Sep-04
Date
Methane
Nov--04 Jan-OS
0.8 -1---------------------------j
i ...., 0.6 -1--------------~"'"----------j i 04 -I----------L_---------',.,__-___ --1
0.2 +--------------/--~~~--~-=~--:.c:...,,'<-----1
o-1------~-~!'...,.---~------~
"ay--04 JC--04 Sep--04
Date
No,,-04 Jan-OS
U = The analyte was analyzed for, but was not detected above the reported sample quantitation fimit.
J .. The analyte was positively identifled; the associated numerical value is the approximate concentration of the anatyte in the sample.
• Trend line shown as a dashed gray line