NCD003446721_20050121_Celeanse Corporation - Shelby Fiber_FRBCERCLA SAP QAPP_Monitored Natural Attenuation Demonstration Project Data Report for Quarterly Sampling Event 2 (3rd Quarter 2004) OU-1-OCR

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Kubal-Furr & Associates
-----------Environmental Management Services
Post Office Box 273210
Tampa, FL 33688-3210
[phone]
FAX [phone]
Mr. Kenneth Lucas
Remedial Project Manager
U.S. Environmental Protection
Agency, Region IV
61 Forsyth Street
Atlanta, GA 30303
Dear Mr. Lucas:
January 21, 2005
Post Office Box 80247
Simpsonville, SC 29680-0247
[phone]
FAX [phone]
On behalf of CNA Holdings, Inc., we are pleased to enclose two copies of the report entitled:
"Monitored Natural Attenuation Demonstration Project-Data Report for Quarterly Sampling
Event #2 (3rd Quarter 2004)-Operable Unit 1-CNA Holdings, Inc./Ticona-Shelby, North
Carolina." By way of this letter, we have also transmitted a copy of the report to Mr. David
Mattison with NCDENR for his review.
Please contact me at 813-265-2338, to discuss any questions you may have following your
review of this document.
Sincerely,
Kubal-Furr & Associates
.JU4?1<-{__
Jerry J. Kubal, P.G.
President
cc: Mr. David Mattison, NCDENR
Mr. Steven F. Olp, Celanese Americas
Ms. PEM Carter, Ticona-Shelby ESHA
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Contents
Page
1.0 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
2. 0 Work Performed . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
3.0 Discussion of Findings . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
3.1 Ground-Water Movement ........................................ 3
3.2 Ground-Water Quality ........................................... 4
3.2.1 Data-Quality Assessment ................................... 4
3.2.2 Discussion of Analytical Findings . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
4. 0 Closing Comments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
Tables
Table 1. Water-Quality Data (Laboratory Parameters)-MNA Demonstration Project-Quarterly
Sampling #2/Q3 2004-CNA Holdings, Inc./Ticona-Shelby, NC
Table 2. Water-Quality Data (Field Parameters)-MNA Demonstration Project-Quarterly
Sampling #2/Q3 2004-CNA Holdings, Inc./Ticona-Shelby, NC
Figures
Figure 1. Site Location Map
Figure 2. Potentiometric Surface Map-Shallow Saprolite-August 5, 2004
Figure 3. Potentiometric Surface Map-Deep Saprolite/Upper Bedrock-August 5, 2004
Figure 4. Hydrogeologic Cross Section-August 5, 2004
Figure 5. Ethylene Glycol Concentrations-August 9-16, 2004
Figure 6. Inferred Methane Distribution-August 9-16, 2004
Figure 7. Anaerobic Biodegradation Screening Parameters-August 9-16, 2004
Figure 8. Inferred Alkalinity (Total) Distribution-August 9-16, 2004
Figure 9. Inferred Manganese (Total) Distribution-August 9-16, 2004
Figure 10. Inferred Ferrous Iron Distribution-August 9-16, 2004
Figure 11. Inferred Nitrate Distribution-August 9-16, 2004
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Figure 12. Inferred Sulfate Distribution-August 9-16, 2004
Attachments
Attachment 1. MNA Q3 '04 Water-Quality Data Report, Data Assessment Summary and Field
Sampling Logs
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CNA Holdings, /11c.-Shelby, NC-MNA Data Report for Sampling Event #2 (Q3 2004) -Page I
1.0 Introduction
In June 2004, Kubal-Furr & Associates submitted to the Environmental Protection Agency (EPA)
and the North Carolina Department of Environment and Natural Resources (DENR) on behalf of
CNA Holdings, Inc. (CNAI!) a document entitled: "Monitored Natural Attenuation Demonstration
Project Work Plan-Operable Unit 1-CNA Holdings, Inc{ficona-Shelby, North Carolina." This
plan was the second revision to the original document prepared December 2001 and followed a series
of written comments and responses, telephone conferences and site visits between CNA, EPA and
DENR in the development of an approvable work plan.
In a letter from Mr. Ken Lucas, EPA, to Mr. Steve Olp, CNA dated May 20, 2004, EPA
authorized implementation of the Monitored Natural Attenuation (MNA) Demonstration Project,
based on CNA's agreement to modify the work plan to address comments summarized in the letter
and discussed in a May 19, 2004 meeting and site visit. The above described plan incorporated the
EPA's comments and the revisions are currently under agency review. Based on the contingent EPA
authorization, initiation of data collection activities (i.e., MNA Quarterly Sampling #1) took place
during the 2nd Quarter of 2004 in accordance with the revised MNA work plan. The results of the
initial sampling were submitted to the agencies in a September 2004 MNA data report. The current
document represents the second data report summarizing the 3rd Quarter 2004 sampling event (i.e.,
MNA Quarterly Sampling #2).
1/ The CNA Holdings, Inc.(Ticona Shelby site has alternately been known as HNA Holdings, Inc.,
Hoechst Celanese Corporation, and Celanese Fiber Operations (CFO), the latter being the site name as
listed on the National Priorities List (NPL). The site will be referred to herein as the CFO site.
Kubal-Furr & Associates
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CNA Holdings, /nc.---She/by, NC-MNA Data Report for Sampling Event #2 (Q3 2004) -Page 2
2.0 Work Performed
As part of the MNA demonstration project, samples were collected at selected monitor wells and
Inner Tier extraction wells in accordance with the June 2004 work plan. Samples were collected from
21 monitor and extraction wells (including 2 duplicates and a field blank) during the period August
9-16, 2004. Samples were collected by Kubal-Furr & Associates and analyzed by Davis & Floyd
Laboratories of Greenwood, South Carolina. Analysis of dissolved gases (methane and carbon
dioxide) were performed by Microseeps of Pittsburgh, PA under subcontract to Davis & Floyd.
Samples were collected during the 3rd Quarter of 2004 from the following locations:
• Monitor wells: F-55, Tl-1, U-38, J-28, V-23, V-65, CC-33, 0-25, K-28, N-29, W-23, and Q-33
Inner Tier extraction wells: IT-1, IT-2, IT-3, IT-4, IT-5, IT-6, IT-7, IT-SR, and IT-9
All monitoring wells were sampled using low flow purging and sampling procedures with the
exception of well F-55 which was evacuated and sampled using a disposable bailer. A peristaltic
pump, or a decontaminated Grundfos® pump, each with dedicated tubing and a Horiba U-22 meter
with flow through cell were used throughout low flow sampling. Drawdown and field measurements
of temperature, pH, specific conductivity, turbidity, DO (dissolved oxygen) and ORP (oxidation
reduction potential) were recorded at 5-minute intervals at each monitoring well during purging.
Measurements of ferrous iron were also collected in the field.
In addition to the field parameters, the samples were analyzed by the laboratory for selected water
quality and MNA indicator parameters consisting of: ethylene glycol, total organic carbon (TOC),
alkalinity, nitrate, iron, sulfate, manganese, methane, and carbon dioxide. The analytical data package
for the 3rd Quarter 2004 is provided in Attachment 1 along with the data assessment summary and
field sampling logs. A summary of the laboratory and field data are provided in Tables 1 and 2,
respectively.
As part of CNA's CERCLA quarterly ground-water monitoring program, water levels are
collected at over 100 monitor wells, extraction wells and piezometers. During the 3rd Quarter 2004,
water levels were measured on August 5, 2004 at 116 locations including 20 of the 21 monitor and
extraction wells that are part of the MNA demonstration project monitoring network. Water levels
were not collected at monitor well F-55 due to the presence of free product DowTherm which
accumulates at this location and presents problems decontaminating the water level probe. The water-
level data collected during the 3rd Quarter 2004 were used to construct the potentiometric surface
maps and hydrogeologic cross section which are presented in Figures 2, 3, and 4.
Kubal-Furr & Associates
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CNA Holdings, lnc.---Shelby, NC-MNA Data Report for Sampling Event #2 (Q3 2004) -Page 3
3.0 Discussion of Findings
3.1 Ground-Water Movement
The shallow saprolite potentiometric surface map (Figure 2) shows water-level contours and
ground-water movement in the uppermost water-bearing zone beneath the site. The direction of
movement in this zone is to the east, northeast and southeast from upgradient areas along NC 198,
towards discharge areas along the unnamed tributaries of Buffalo Creek.
An attempt was made to separate the uppermost water-bearing zone from the deeper saprolite and
upper bedrock zone. While this map (Figure 3) presents a reasonable picture of ground-water
movement in the deep saprolite/upper bedrock, it should be pointed out that it is giving a somewhat
more generalized picture of ground-water movement because of the well construction techniques
used in many of the wells and piezometers. The typical construction for most of these wells was to
have relatively long screens and extremely long sand packs in the annular space above the screens. As
a result, the lower saprolite/upper bedrock maps have a number of composite head values measured
along a longer screened interval. Nonetheless, the maps are felt useful for determining the general
direction of ground-water movement which is inferred to the east, northeast and southeast, similar to
the shallow saprolite configuration.
A hydrogeologic cross section was also constructed from the 3rd Quarter data and is shown in
Figure 4. The location of the cross section A-A' is shown on the site location map, Figure 1, and is
constructed through the plant from upgradient areas west of the plant to downgradient, off-site areas
east of the plant. The east-west hydrogeologic cross section indicates flow is predominantly
horizontal across the site, from upgradient areas west of the plant toward downgradient areas to the
east.
The Inner Tier extraction well system was shut down on March 1, 2004 in accordance with
recommendations in EPA's Five-Year Review Report for OU-1 and while the MNA demonstration
project is being implemented. Water levels in most Inner Tier wells were noted to have recovered by
15-ft to 20-ft since shutdown. The August 5, 2004 potentiometric surface maps presented in this
report represent non-pumping conditions. While actively pumping, only a very narrow cone of
depression was developed, centered along the axis of the Inner Tier, and the area influenced by the
Inner Tier was spatially very limited. A shorf distance away, the potentiometric surface resorted to an
easterly, northeasterly and southeasterly direction of movement away from the Inner Tier. Comparing
pumping to non-pumping potentiometric surface maps, the small cone of depression is gone but the
overall direction of movement downgradient of the Inner Tier remains virtually unchanged in both
cases.
Kubal-Furr & Associates
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CNA Holdings, /nc.-Shelby, NC-MNA Data Report for Sampling Event #2 (Q3 2004) -Page 4
3.2 Ground-Water Quality
3.2.1 Data-Quality Assessment
The analytical data for the 3rd Quarter 2004 were evaluated using method specific quality control
criteria and, for additional guidance when necessary, the EPA's National Functional Guidelines for
organic and inorganic data review. Analytical test results, field sampling logs, chain-of-custody forms,
and the data quality assessment are contained in Attachment l. A summary of selected analytical data
for the 3rd Quarter is presented in Tables 1 and 2.
Regarding sample collection, the sampling logs and field information provided were complete.
The field sampling logs indicate that most of the wells sampled were within the sampling guidelines
for turbidity of 10 NTUs (nephelometric turbidity units) with the principal exception of the Inner
Tier extraction wells. While the turbidities at these wells generally stabilized before sample collection,
they did so at levels above the 10 NTU guideline. It appears that degradation of ethylene glycol and
other constituents from the former source area has caused biofouling and bacterial build-up outside
the well casings and along the well screens and it's likely that the Inner Tier wells may not be capable
of producing samples meeting the guidelines for turbidity. For the most part, the parameters being
analyzed during the demonstration project would not be significantly affected by slightly elevated
turbidities and CNA is prepared to request a variance to the very specific 10 NTU criteria. This need
will be evaluated during subsequent sampling events and will be proposed, if necessary, at an
appropriate time.
All 3rd Quarter data were considered quantitative with several exceptions as noted in the data
assessment summary report. Based on the data-quality assessment, qualifiers were placed on selected
analytical results as noted in Table 1. The gases methane and carbon dioxide were analyzed outside
the subcontract laboratory (Microseeps) standard operating procedure (SOP) guidance of 14 days
and therefore were assigned a "J" qualifier as being an estimated value. Methane reported as present
in the field blank, FB-01, resulted in assigning "U" qualifiers, non-detect, to samples from J-29, Q-
33, TI-1, U-38 and W-23. Although estimated, it is felt these values represent background
concentrations and support a "U" qualification. In addition, Davis & Floyd indicates laboratory
contamination as a probable cause for the reported 27.7 mg/L of ethylene glycol in the field blank
(FB-01) resulting from carry over of a prior sample containing high concentrations of ethylene
glycol (F-55). This data point was assigned a "U" qualifier as being non-detect. This qualification is
also supported by the reported non-detect ( <1.0 mg/L) for TOC in the same sample.
3.2.2 Discussion of Analytical Findings
A summary of the laboratory data and field parameters are summarized in Tables 1 and 2,
respectively. The 3rd Quarter 2004 MNA data, including the anaerobic biodegradation screening
Kubal-Furr & Associates
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CNA Holdings, [11c.-She/by, NC-MNA Data Report for Sampling Eve11t #2 (Q3 2004) ---Page 5
parameters, are shown on Figures 5-12. The data are presented as isoconcentration plots except for
ethylene glycol (Figure 5) which had too few contourable data points, and the respective values were
just posted to the figure.
The highest ethylene glycol concentration (8200 mg/L [milligrams per liter]) was reported in
monitor well V-23, at the former OU-2 source area. Monitor well F-55 reported the next highest
ethylene glycol value (3790 mg/L), but this area is interpreted as a small, isolated source not related to
the former OU-2 source area at V-23 and the Inner Tier. In several instances, the ethylene glycol
detection levels are slightly elevated due to matrix interferences, but in the case of most Inner Tier
wells, the ethylene glycol values are reported below the detection level of 7.0 mg/L. It should be
noted that earlier Inner Tier ethylene glycol data were collected under pumping conditions whereas
the current data set represents non-pumping conditions under which the water levels in most Inner
Tier wells have recovered by 15-to 20-ft since pumping stopped on March 1, 2004. The general
absence of any reportable ethylene glycol at the Inner Tier may be affected by the depth and length
of the Inner Tier screens and the current, non-pumping position of water levels in the shallow
saprolite.
Ethylene glycol is readily degradable both aerobically and anaerobically. Under aerobic
conditions, ethylene glycol (C2H6O2) will degrade into carbon dioxide and water. Under anaerobic
conditions, ethylene glycol can degrade into ethanol, acetate and methane. The ethanol produced can
be further oxidized to acetate, with methane being the final end product. Reviewing the 3rd Quarter
MNA data set presents strong evidence that ethylene glycol is being anaerobically degraded in the
subsurface using nitrate, manganese and iron as terminal electron acceptors.
Further indication of ethylene glycol degradation is apparent in the methane production in the
most highly contaminated portions of the aquifer (Figure 6). The monitoring data show that the
ground water contains elevated levels of methane in the areas with high ethylene glycol, indicating an
active methanogenic population. The numerical results of the anaerobic biodegradation screening
procedure contained in EPA MNA guidance (Figure 7) would indicate that conditions in the former
source area are favorable for anaerobic degradation. Additionally, the very high alkalinity values
(Figure 8) reported around the former source area are indicative of increased microbial activity.
The 3rd Quarter 2004 MNA data set contains multiple lines of evidence that natural attenuation
of the ethylene glycol is occurring at the site. Tabulated below is a summary of the selected natural
attenuation indicators, from upgradient areas at well TI-1, through the "plume" as shown in wells V-
23 and IT-1, to downgradient areas as shown by wells 0-25 and W-23. These results are generally
consistent with the expected findings that as ethylene glycol increases, nitrate will decrease, while
ferrous iron (Fe2+ ), manganese, and methane will increase. While sulfate would be expected to
decrease along with nitrate, the data are inconsistent and it's possible that elevated sulfate levels
reported in the downgradient wells may reflect leakage from the polishing ponds into the saprolite.
Kubal-Furr & Associates
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CNA Holdings, /nc.---Shelby, NC-MNA Data Report for Sampling Event #2 (Q3 2004) -Page 6
--------Background---------------Plume Area--------------Downgradient-------
Well TI-1 U-38 V-23 IT-1 0-25 W-23
Eth.Glycol < 7.0 < 7.0 8200 31.2 < 7.0 < 7.0
Nitrate 2.2 1.1 0.43 0.13 < 0.10 1.9
Manganese 0.088 0.058 933 8.9 0.44 1 .9
Fe2+ < 0.1 < 0.1 > 40 > 30 > 30 < 0.1
Sulfate 0.82 0.83 36.5 3.8 179 63.8
Methane 0.0llU 0.00049U 12.0J 11.0J 1.11 0.0069U
Alkalinity 27.0 4.0 3130 1000 40.0 10.4
(All concentrations reported in milligrams per liter. "J" qualifier indicates analyte positively
identified but the associated numerical value is the approximate concentration of the analyte in the
sample. "U" qualifier indicates analyte was not detected above the reported sample quantitation
limit)
Kubal-Furr & Associates
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CNA Holdings, /nc.--She/by, NC-MNA Data Report for Sampling Event #2 (QJ 2004) -Page 7
4.0 Closing Comments
This data report presents the results of the second quarterly sampling for the MNA
Demonstration Project at the CFO site. Reviewing the 3rd Quarter 2004 MNA data set presents strong
evidence that ethylene glycol is being anaerobically degraded in the subsurface using nitrate,
manganese and iron as terminal electron acceptors. Further indication of ethylene glycol degradation
is apparent in the methane production in the most highly contaminated portions of the aquifer. The
monitoring data show that the ground water contains elevated levels of methane in the areas with high
ethylene glycol, indicating an active methanogenic population. The numerical results of the
anaerobic biodegradation screening procedure contained in EPA MNA guidance would indicate that
conditions in the former source area are favorable for anaerobic degradation. Additionally, the very
high alkalinity values reported around the former source area are indicative of increased microbial
activity.
The revised work plan submitted to the agencies in June 2004 is currently under review and the
EPA has subsequently requested, and been supplied with, geologic cross sections and other
information concerning construction details of selected monitor wells and/or piezometers that may be
sampled to establish the extent of the ethylene glycol "plume." Pending agency review of the
supplemental information, no modifications to the sampling program are planned for the third
quarterly sampling event (i.e., 4th Quarter 2004).
Kubal-Furr & Associates
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I Kubal-Furr & Associates
-- - -- -- - - -- --
Ethylene
Well Glycol Methane
CC-33 <7.0 · 0.55J ·
F-55 3790 2.6J
IT-1 31.2 1 l.OJ
IT-2 <7.0 5.9J
IT-3 <7.0 14.0J
IT-4 <7.0 19.,.Q.J ·
IT-5 <7.0 13.0J
IT-6 <140 9.0J
IT-7 <~.?-0 7.9J
IT-BR <7.0 13.0J
IT-9 <7.0 16.0J
.J-29 <7.0 ...... 0.0028U .
K-28 <35.0 12.0J
N-29 <7.0 -0.47J ·
,.Q-25 <7.0 1. lJ
Q-33 <7.0 0.0014U
Tl-1 <7.0 0.01 lU
U-38 <7._9 0.00049U
V-23 8200 12.0J
V-65 <7.0 18.0J
_W-23 <7.0 · 0.0069U ·
FB-01 27.?U 0.0053U
DUP-1 (CC-33) <7.0 0.66J
DUP-3 (V-65) <7.0 16.0J
Table 1. Water Quality Data (Laboratory Parameters)
MNA Quarterly Sampling #2 / Q3 '04
CNA Holdings, Inc. / Ticona -Shelby, NC
( all results reported in mg/L)
Carbon Total Total
Dioxide Total Iron Manganese Alkalinity
95.0J 51.7 3.1 44.5
67.0J . 580 204 1170
19QJ 611 8.9 1000
370J 203 4.1 1210
36.0J 106 1.1 187
18.0J 56.3 1_,_3 118
220J 85.7 3.6 620
250J 1630 624 2110
280.J. .. 432 373 ..1.1.90
160J 616 43.9 900
21 OJ 141 91.6 580
24QJ <0.10 -0.69 ... 1,230
160J 1810 32.3 2100
1 lOJ · <0.10 · 0.20 4.0 -
42.0J , 54.8 0.44 40,0 ....
ll0J 0.10 0.095 88.0
98.0J 3.6 0.088 · 27.0
Bl.OJ· <0.10 0.058 4.,0
180J 2050 933 3130
83.0J 20.4 0.96 · 250
97.0J <0.10 1.9 10.4
<0.60UJ <0.10 · <0.010 <1.0
B2.0J 52.1 3.1 45.0
79.0J 19.8 0.94 260
U = The analyte was analyzed for, but was not detected above the reported sample quantitation limit.
X == Sample diluted due to matrix interference (applied by the laboratory), no affect on data useability
Nitrate
Nitrogen
<0.10
<0.020
0.13
0.058
<0.10
<0.10
0.12
<0.ZOX
Q,O?S
<0.10
<0.10
76.7
<0.SOX
0.69
<0.10
<0.10
2.2
1.1
0.43
<0.10
1.,.9
<0.10
<0.10
<0.10
- -
Sulfate
5.9
3.8
3.8
<2.SX
<0.50
<0.5.9 ...
<0.50
<3.0 ·
<3.0
19.6
<0.50
63.3
5.8
1.2
179
88.5
0.82
o ... ~.3
36.5
2.8
63.8
<0.50
6.0
2.7
J = The analyte was positively identified; the associated numerical value is the approximate concentration of the analyte in the sample.
UJ = The analvte was not detected above the reported sample quantitation limit. However, the reported auantitatlon limit is approximate and may or may not
represent the actual limit of quantitatlon necessary to accurately and precisely measure the analvte in the sample.
- --
Total Organic
Sulfide Carbon
<0.050 1.2
<0.050 4260
<0.050 329
0.052 76.4
<0.050 8.5
<0.059 8.6
<0.050 12.6
<0.050 4740
<0.050 21_70_
<0.050 583
<0.050 84.0
<0.050 5.3
<0.050 2110.
<0.050 <1.0 -
<0.050 22.0
<0.050 2.7
<0.050 <1.0
<0.0,?.9 · <1.0
<0.050 9840
<0.050 1.8
.... <0.050 .... 1.3 ...
<0.050 <1.0
<0.050 · 1.1
<0.050 1.6
CNA Holdings. Inc JTicmm-Shelhy, NC
MNA Quarterly Samplin,: #2 (Q3 '(J4)
-
-- - -
Wcll
(Units)
CC-33
· F-55
IT-1
IT-2
IT-3
IT-4
, IT-5
IT-6
IT-7
IT-BR
IT-9
J-29
K-28
N-29
0-25
Q-33
Tl-1
U-38
V-23
V-65
W-23
L...__
--------- - - - - -
ORP (Final)
mV
-27.8
12.9
-181.8
-108.5
-231.2
-1 55.0
-101.8
7.7
58.5
-128.8
-90.4
20.5
-143.5
593.6
-102.8
22.7
57.7
279.9
57.9
-79.1
259.9
Table 2. Water Quality Data (Field Parameters)
MNA Quarterly Sampling #2 / Q3 '04
CNA Holdings, Inc. / Ticona -Shelby, NC
Temperature
eH (Final) (Final) Cond (Final) DO (Initial)
SU 'C µSiem mg/L
6.16 18.16 270 1.28
5.65 23.07 2611 0.75
6.69 19.,48 1579 0.27
6.39 22.99 2020 4.23
6.96 22.27 486 0.54
7.44 20.91 350 0.15
6.69 21.32 1282 0.46
4.92 22.19 5106 0.53
5.00 21.26 2551 2.23
6.63 20.26 1931 0.33
6.89 20.15 1004 3.40
6.38 19.10 2293 o .. ~'.I .. ..
5.95 21.00 4043 0.49
4.62 19.02 49 0.99
6.55 18.14 777 0.65
5.69 19.59 583 0.41
5.33 18.79 83 1.65
4.74 19.23 42 2.60
5.05 20.10 5423 0.80
6.70 20.59 389 1 .51
5.09 20.01 166 4.58
DO (Final)
mg/L
0.39
2.64
0.08
0.10
0.07
0.06
0.15
0.20
0.51
0.16
0.27
0.26
0.12
0.72
0.24
0.24
1.87
LBS
0.28
0.32
4.04
Ferrous Iron
mg/L
>30
>40
>30
>30
>30
>30
>40
>40
.. >30 ..
>40
>40
<0.1
>30
<0.1
>30
<0.1
<0.1
<0.1
>40
16
<0.1
CNA Holdings, lncJTicona-Shelby, NC
MNA Quarterly Sampling #2 (Q3 '04)
-
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-- - - - -
.... 0
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, -,
i-. -.
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-
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Recreation Pond .... --' -........ -. -\. -
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0 350 700
- -- - -
•
Legend
Monitor Well
Piezometer
.._ Surface Water Location
♦ Outer Tier Extraction Well
• Inner Tier Extraction Well
■ PEW Extraction Well
C Residential Well
.,,,,,..-..-,,, Creek I Stream
D Building / Structure
A-A1 Location of Geologic
Cross Section
Kubal-Furr & Associates
-Environmental Consultants-
Figure 1. Site Location Map
CNA Holdings, lnc./Ticona
Shelby, North Carolina
-
-- - - - -- -
"
I
0
Legend
• Monitor Well Water-Le11el (ft msl)
• Inner Tier Extraction Well ,,,.,,..,, Water-Level Contour 1---l
,,,---../ Creek/ Stream
□ Building I Structure
-
\
\
'
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-
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□
Inner Tier Extraction Well
.Wate~al ElevatiQOS
IT-1 = 800.01
IT-2 = 801 .48
IT-3 = 800.25
IT-4 = 800.68
IT-5 = 801.82
IT-6 = 802.30
IT-7 = 802.34
IT-8R = 799.49
IT-9 = 797.70
Kubal-Furr & Associates
-Environmental Consultants-
Figure 2. Potentiometric Surface Map
Shallow Saprolitc--August 5, 2004
CNA Holdings, /nc./'Ficona
Shelby, North Carolina
-
-- - --
I
- --
' ,-. ' ,
Recreation Pond
,
-- ---
t' ,,----'
.-::::---..... =21 PZ-11 o"
:~•lb
~-::J!
' . , j . -'~~--~ -, -~ L
I -~ __ u
~
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Scale in Feet
0 350 700
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Legend
MorutoLWell water-Level (n msl}
Plezometer
♦ Outer Tier Extraction Well
■ PEW E)ctraction Well
/780/ W~~l!;~e! :~!~ur
~ Creek I Stream
0 Building I Structure
~ '
Kubal-Furr & Associates
-Environmental Consultants-
Figure 3. Potentiometric Surface Map
Deep Saprolite/Upper Bedrock-August 5, 2004
CNA Holdings, /nc.!Ticona
Shelby, North Carolina
-
-- - - - --
850.00 A
---------Plant Are
830.00
D-27 827.08
0-35 810.00 826.73
G-50
813.38
790.00 D-56
826.73
770.00
750.00
730.00
710.00
690.00
67000
Legend
-ern,.I line of equal fluid potential (ft msl) ~ Bedrock
(011$h9d wi.. infemJd)
z
......,..
Potentiometric Surface
Inferred direction of ground-water movement
CJ Saproute
i Screened Interval of Well
-
J-29
806.7
-- - -- -
Wastewater Treatment Area-----------•
• C .::;
~ :!. e Q.
I
Horizontal Scale in Feel
0 400 800
- ---
A' 650.00
830.00
810.00
790.00
770.00
750.00
730.00
710.00
690.00
670.00
Kubal-Furr & Associates
-Environmental Consultants -
Figure 4-Hydrogoologk Cross Section A-A'-August S, 2004
CNA Holdings, lnc.mcona
Shelby, Norlh Carolina
-
-- - -
Legend
0 MonrtorW811 ... Piezometar ,,. Surface Water Location
❖ Outer Tier Extraction VVell
• Inner Tier Extraction Wall
■ PEW Extraction well ,,....,, Creek/ Stream
□ Building/ Structure
D
ED -'[).
-
I
= <7.0
/ Ih1"
0 <7.0
-
t:."'.'J,
Recreation Pond
-
HP ·r
--
:-v, ~
/
-
A
I'/ p.
-
. '
Pollsbin11 Pond
' -..... -...,
C
/
---- - -
AA -· r,1. '.t, \
r,1ri_,, ,,-c.·Mr,1 · r,,,1 ,, Scale in Feet
,, c?
0 0 200
Kubal-Furr & Associates
-Environmental Consultants-
Figure 5. Ethylene Glycol Concentrations
Sample Date: August 9-16, 2004
(results reported in mg/L)
CNA Holdings, lnc./Ticona
Shelby, North Carolina
400
- -
-- - -- -
0
....
.c,.
❖
•
•
r-"
D
Legend
Monitor Well
Piezometer
Surface Water location
Outer Tier Extraction \J\lell
Inner Tier Extraction Well
PEW Extracboo \NeD
Creek/ Stream
Building I Structure
0 EaS5 2.6J
-. -
/
Recreation Pond
-
lfii,•
lL2. 5.9J
Lia3.
14.0J
-
I
l'lc29
0 0.47J
=· 0 12.0J
,
= 0 0.55.J
/
- - - - -
Pollshl1111 Pond
\
~ r"
-~
- -
0
0
--Concentrations
(mg/L)
0.001-0.01
0.01-0.1
0.1-1
1-10
10-100
>100
\
Seale in Feet
200
/
t?
'
Kubal-Furr & Associates
-Environmental Consultants-
Figure 6. lnfured Methane Distribution
Sample Date: August 9-16, 2004
(results reported in mg!L)
CNA Holdings, /nc.lI'icona
Sh.elby, North Carolina
--
400
-- - - -
0 ...
,,.
❖
•
■
;---/
~
Legend
Monitor Welt
Piezometer
Surface Water Location
Outer Tier Extraction WeD
Inner Tier Extraction Well
PEW Extraction WeH
Creek I Stream
Building/ Structure
/
( J,29
-----
I
/ Ih1 a o 3
6
- - - -
~
0
lJ.:.1·. ~
ilI:2. K:28
+~; 0 19 <LI:3. '
I_J_7j ~.
!7J lL5
e 1 __ 1_81
~ Oe·rr_i
16111? _: LJlj
1I:Z •
15
ILllB•
l 191. _ e II,9
19'
c_
0:,25 '·~ 0 16
·= 0 15
Recl'eation Pond , /
-
c.
... ... . ...
"' I
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- - - -- - -
Anaerobic Biodegradation
Screening Parameters
5-9
10-14
>15
~
\ Scale in Feet
0,33 7 0
J
-~-
0 200
-\
i /
/
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-Environmental Consultants-
400
Figure 7. Anaerobic Blodegradation Scrttning Parameters
Sample Date: August 9-16, 2004
CNA Holdings, lnc./Ticona
Shelby, North Carolina
- -
--- -
Legend
0 Monitor Well
.... Piezometer
,>. Surface Water location
❖ Outer Tier Extraction Well
• Inner Tier Extraction Well
• PEW Extraction WeU
,-, Creek I Stream
"1 Building/ Structure
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0 27.0
-- - -
~
).I:1'. 11000
N,29
0 4.0
'IL2ie K:28
J~!0 O (_2100 ;J.L3 •
t.!~I.i
L~ • ,118 ·JLS. -~ .·.,;2~~1 oe rrr..::e:
-_) ~
-JI:ii
1190 e
ruiR •
900' i_i;s,.
580
I
=· 0 40.0
CCa33 0 44.5
/
.....
-
= 0 10.4
\
.. .... -.....
I
\
- - - - - --
/
Concentrations
(mg/L)
0.001-0.01
0.01-0.1
0.1-1
1-10
~ A\
10.100
>100
\
Q,33
88.0 0
'
A~
Scale in Feet
0 200
.. l
/
Kubal-Furr & Associates
-Environmental Cont--ultants-
400
Figure 8. Inferred Alkalinity (Total) Distribution
Sample Date: August 9-16, 2004
(results reported in mg!L)
CNA Holdings, Inc./Ticona
Shelby, North Carolina
- -
-- - -- -
Legend
0 Monitor Well ... Piezometer
L,. Surface water Location
❖ Outer Tier Extraction WeD < • Inner Tier Extraction Well
■ PEW fatraction Well ,,_, Creek I Stream
D Building / Structure
/
I = .. 0.69 0
I
/ lb1
□
. ·:t
"
D
---
Recreation Pond
- - -
=· 89
N,29 0 0.20
lL2 • Kc28. 4-1 0 32.3 =• 1.1 =· 1.3 lL5 e 3.6
~ O • IL-6 9~0.96 ~624
1H.
373
illlR.
43.9 1H.
91.6
,
0,25-'·
0 0.44
=-0 3.1
/
....
-
= 0 1.9
-~
.. .... -....
CJ
\
--- - -- -
/
~
Oc33 0.0050
J
Concentrations
(mg/L)
0.001-0.Q1
0.01..Q.1
0.1-1
1-10
10-100
0 >100
\
A~
\
Scale in Feet
0 200
l \ I
/
Kubal-Furr & Associates
-Environmental Consultants-
<00
Figure 9. Inferred Mangan~ (Total) Distribution
Sample Date: August S).16, 2004
(results reported in mg!L)
C\'A Holdings, !nc.!Ticona
Shelby, North Carolina
- -
-- --Legend
0 Monitor Well
A. P\ezometer
L::,,,. Surface Water Location
❖ Outer Tier Extraction Well
• Inner Tier Extraction Well
■ PEW Extraction WeU
,,,.....,,, Creek f Stream
I!) Building/ Structure
a
-----
-
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0 <0.1
.b29 <0.1
-
Recreation Pond
-
I
-
I
~ 1',29
0 <0.1
- - ---
~
A \
- -- -
Concentrations
(mg/L)
0.001-0.01
0.01-0.1
0.1-1
1-10
10-100
i >100
\
;Tu}. Polishing Pond "\ l
Scale in Feet
1L2. K..:28.•: >30 0 >30 =• >30
IL<e >30 = • >40
~ 0. ~
>40/1~ >_4Q
l
=• >30
lLllB • >40 ·1r.,..9 •
>40
/ ,
Oc25' --~ 0 >30
.... .. ..... -....
"' I
\
Oc33 <0.1 0
0 200
\ I
/
I
Kubal-Furr & Associates
-Environmental Consultants-
Figure 10. Inrerred Ferrous Iron Distribution
Sample Date: August 9-16, 2004
(results reported in mg!L)
CNA Holdings, /nc.!Ticona
Shelby, North Carolina
- -
400
--- -
Legend
0 Monitor Well
.... Piezometer ,,. Surface Water Location
❖ Outer Tier Extraction WeK
• Inner Tier Extraction Well
■ PEW Extraction Well ,,.....,, Creek I Stream
I!) Building/ Structure
-
I
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I lb1
0 2.2
-
/
J,29 -,~
76.7 0
-
LT.:.1 • 0.13 =· 0.058 =• <0.10
<1t'fo •
-
,.,,,
0 0.69
=· 0 <0.50
-
= e 0.12 =s·
0 <0.10
~ 0 • lI=6
0.431<0.10 <0.20
lU • 0.025 =· <0.10 e
1H <0.10 = 0 <0.10
....
-
= 0 1.9
I
A
.. ...... -....
"' I
\
- - - -- - -
Concentrations
(mg/L)
0.001-0.01
0.01-0.1
~ .... ~,.. . -l 0.1-1
1-10 ~ 10-100
® >100
.
\ A
0,33 <0.100
\\
Scale in Feet
0 200
··,: .,.,,
\1 I
/
I
Kubal-Furr & Associates
-Environmental Consultants-
Figure 11. Inferred Nitrate Dtstrtbudon
Sample Date: August 9-16, 2004
(results reported in mg/L)
C\~4 Holdings, /nc//'icona
Shelby, North Carolina
--
400
-- --Legend
0 Monitor Well ,. Piezometer ,,. Surface Water Location
❖ Outer Tier Extraction \NeU
• Inner Tier Extraction WeH
• PEW Extraction WeD
r./ Crook I Stream
~ Building/ Structure
D
-----
-
I
,,,.
'= 63.3
/ ill .. ·
0 0,82
-
,
'o
--
'"29 0 1.2 =· 3.8
lL2 • &28~
.s2..5 0 5.8
lLl • <0.50 <~· = • <0.50
~ oe lH
36.512.8 <3.0
JU.
<3.0 ~ •
= 0 5.9
J_
/ ,
-
.....
-
A
- - -
~
i A "
0:33 88.5 0
A~
- -
l \ I LJ W,2:3~'.::=::::::::::::::.::::::::::::-
0. 63.8 )/
I
/ -..... -......
- -
Concentrations
(mg/L)
0.001-0.01
0.01-0.1
0.1-1
1-10
10-100
>100
\
Scale in Feet
0 200
"' I
\
/ '
Kubal-Furr & Associates
-Eni>ironmental Consultants-
Figure 12. Inferred Sulfate Distribution
Sample Date: August 9-16, 2004
(results reported in mg!L)
CN.4 Holdings, Jnc.!Ticona
Shelb.v, North Carolina
--
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Attachment 1
MNA Q3 '04 Water-Quality Data Report
Data Assessment Summary and Field Sampling Logs
Kubal-Furr & Associates
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DATA ASSESSMENT SUMMARY CHECKLIST AND REPORT-LEVEL II
Client ID:
Project Number:
Project Description:
Ticona, Shelby, NC
26NA01
03/04
Sample Delivery Group (SDG) Description:
Prepared By: Robert DeGaetano
Date: 01/19/05
Twenty-four aqueous samples, including two field duplicates and a field blank, were collected by
Kubal-Furr & Associates and submitted to Davis & Floyd of Greenwood, SC for analysis. The
samples were tested for ethylene glycol, carbon dioxide, methane, metals (total iron and
manganese), sulfide, alkalinity, nitrate (as N), sulfate and total organic carbon. The methane and
carbon dioxide testing was subcontracted to Microseeps Laboratories in Pittsburgh, PA.
CONTENTS LEVEL COMMENTS
II
Sample Results ✓ Most data considered Class A as
reported. Some data are considered
Class B, and are assigned qualifiers.
Chain(s) of Custody (COCs) ✓ Chemical preservatives not identified
on COC.
Master Tracking List ✓ Satisfactory
Method Conformance Summary ✓ Satisfactory
Batch Quality Control Report ✓ Satisfactory
Trip/Field/Equipment Blank Report ✓ Ethylene glycol and Methane detected
in the field blank
Field Notes/Logbook ✓ Satisfactory
Discussion:
Ethylene glycol was detected in the field blank at 27.7 mg/L due to carry-over from sample F-55.
The ethylene glycol result for the field blank was assigned a U qualifier. Methane was also detected in
the field blank at 0.0053 mg/L. The methane results for the field blank and for samples from J-29,
Q-33, TI-I, U-36 and W-23 were assigned a U qualifier. Methane results for all remaining samples
were assigned a J qualifier due to analyses exceeding the hold time requirement of fourteen days. In
addition, all Carbon Dioxide results were assigned a J qualifier (UJ for the Field Blank) due to analyses
exceeding the fourteen-day hold time requirement. All remaining results were Class A.
Class A = quantitative Class B = qualitative Class C = unuseable
-------------Kubal-Furr & Associates
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D1\VIS
FLOYD LABORATORY ANALYSIS REPORT
September 11, 2004
PEM CARTER
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Report ID : AB24838
Page 1 of 125
Login Number
Project Number
Description
Dear Pem Carter:
:L04081013, L04081201, L04081304, L04081704
:61621.01
:CNA TICONA-SHELBY, NC
lID ~©~TIW~ffil
I DEC O 1 2004 J1!l
BY: .QJ...?.5.£?.:_l.-~2.
We are pleased to provide the enclosed analytical results for the samples received by
Davis & Floyd, Inc. on August 10, 2004 through August 17, 2004.
A formal Quality Assurance/Quality Control program is maintained by Davis & Floyd,
which is designed to meet or exceed the EPA, NELAC or other appropriate regulatory
requirements. All analytical analyses for this project met QA/QC criteria and the
results are within the 99 % confidence interval for each method unless otherwise
stated in the footnotes. This report is to be reproduced only in full.
Feel free to contact our Client Services Representative at [phone] if further
explanation of the analysis is required. Unless other arrangements have been made,
samples will be disposed of or returned 14 days from the date of the report. We
appreciate the opportunity to provide services to your firm.
Sincerely,
DAVI~YD, C.
. ~rt,u,U
hn H. McCord, Jr.
Laboratory Manager
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
I
Di\YIS
FLOYD LABORATORY ANALYSIS REPORT
Sample IO
L04081013-01
L04081013-02
L04081013-03
L04081013-04
L04081013-05
L040B1013-06
L0408120l-Ol
L04081201-02
L04081201-03
L04081201-04
L04081201-05
L04081201-06
L040B1201-07
L04081201-0B
L04081201-09
L04081201-10
L04081201-ll
L04081304-01
L040B1304-02
L04081304-03
L04081704-0l
L04081704-02
L040B1704-03
L04081704-04
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
Sample Tracking List
Client IO
Q-33
J-29
t.r-38
CC-33
DUP-1
W-23
N-29
0-25
K-28
TI-1
F-55
FB-01
IT-1
IT-2
IT-3
IT-4
IT-5
IT-6
IT-7
IT-SR
IT-9
V-23
V-65
DUP-3
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 2 of 125
Date Collected
08/09/2004 1615
08/09/2004 1730
08/09/2004 1755
08/10/2004 0855
08/10/2004 0000
08/10/2004 1300
08/10/2004 1430
08/10/2004 1600
08/10/2004 1915
08/11/2004 0940
08/11/2004 1320
08/11/2004 0835
OB/11/2004 1020
08/11/2004 1220
08/11/2004 1505
08/11/2004 1210
08/11/2004 1440
08/11/2004 1703
08/11/2004 1710
08/11/2004 1840
08/16/2004 1000
08/16/2004 1130
08/16/2004 1300
08/16/2004 0000
September 11, 2004
Report ID: AB24838
Date Recei vcd
08/10/2004
08/10/2004
08/10/2004
08/10/2004
08/10/2004
08/10/2004
0B/12/2004
08/12/2004
08/12/2004
08/12/2004
08/12/2004
08/12/2004
OB/11/2004
OB/12/2004
08/12/2004
08/12/2004
08/12/2004
08/12/2004
OB/12/2004
08/12/2004
OB/17/2004
08/17/2004
08/17/2004
08/17/2004
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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DAYIS
FLtJ\'D
Client
Contact
Client
Matrix
Parameter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
Subcontract Work
AM20GAX
CARBON DIOXIDE
METHANE
Trace Metals
SW846 6010B T
IRON, TOTAL
MANGANESE, TOTAL
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL
SM 2320B
ALKALINITY, TOTAL
SW846 9056
NITRATE NITROGEN (AS NJ
SULFATE
SW846 9060
ORGANIC CARBON, TOTAL
ID:
Sample Comments: L04081013-01
LABORATORY ANALYSIS REPORT
NC Certification Number: 25
TICONA,LLC Project Number: 61621.01
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date September 11, 2004
Pem Carter Page 3 of 125 Report ID: AB24838
Q-33 Sample ID L04081013-0l
Date Collected, 08/09/2004 1615
GW/Chemw Date Received 08/10/2004
Result Qual RDL Units Analyst Date Time
< 7.0 7.0 mg/1 MGB 08/11/2004 1829
110 0.60 mg/1 AS 08/24/2004 0000
1. 4 0.015 ug/1 AS 08/24/2004 0000
0.10 0.10 mg/1 BDL 08/12/2004 0232
0.095 0.010 mg/1 BDL 08/12/2004 0232
< 0.050 0.050 mg/1 CDC 08/16/2004 1554
88.0 1.0 mg/1 MPM 08/17/2004 0840
< 0.10 0 .10 mg/1 OHR 08/10/2004 1814
88.5 2.5 mg/1 OHR 08/10/2004 1831
2.7 1.0 mg/1 CBN 08/18/2004 1751
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METHAL PREP ICP SM 3030C BDL 08/10/2004 1530
Davis & Floyd, Inc. I PO Drawer 428 J Greenwood, SC 29648 I 816 E. Durst Avenue 1 Greenwood, SC 29649 I [phone] I Fax [phone]
Di\YIS
FLOYD. LABORATORY ANALYSIS REPORT
Client
Contact
T.ICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
Client ID: J-29
Matrix
Parameter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
Subcontract Work
AM20GAX
CARBON DIOXIDE
METHANE
Trace Metals
SW846 6010B T
IRON, TOTAL
MANGANESE, TOTAL
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL
SM 2320B
ALKALINITY, TOTAL
SW846 9056
NITRATE NITROGEN (AS N)
SULFATE
SW846 9060
ORGANIC CARBON, TOTAL
Sample Comments: L04081013-02
GW/Chemw
<
<
<
Result
7.0
240
2.8
0. 10
0. 69
0.050
1230
76.7
63.3
5.3
Qual
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 4 of 125
Sample ID
Date Collected:
Date
RDL
7.0
0.60
0.015
0.10
0.010
0.050
10.0
. 0
5. 0
1.0
Received
units
mg/1
mg/1
ug/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
'
September 11, 2004
Report ID: AB24838
L04081013-02
08/09/2004
08/10/2004
Analyst
MGB
AS
AS
BDL
BDL
CDC
MPM
OHR
OHR
CBN
1730
Date Time
08/11/2004 1855
08/24/2004 0000
08/24/2004 0000
08/12/2004 0301
08/12/2004 0301
08/16/2004 1555
08/17/2004 0B4 9
08/10/2004 2027
08/11/2004 2244
08/18/2004 1819
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METHAL PREP ICP SM 3030C SOL 08/10/2004 1530
Davis & Floyd, Inc. f PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
I
I
I
I
I
I
I
I
I
I
I
I
I
Ii
11
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Df\VIS
FLtlYD LABORATORY ANALYSIS REPORT
NC Certification Number: 25
Client TICONA,LLC Project Number: 61621.01
2525 BLACKSBURG ROAD
H\"/Y 198
SHELBY, NC 28152 Report Date September 11, 2004
Contact Pem Carter Page 5 of 125 Report ID: AB24838
Client ID: U-38 Sample ID L04081013-03
Date Collected: 08/09/2004 1755
Matrix GW/ChemW Date Received ' 08/10/2004
Parameter Result Qual RDL Units Analyst Date Time
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL < 7.0 7.0 mg/1 MGB OB/11/2004 1921
Subcontract Work
AM20GAX
CARBON DIOXIDE 81. 0 0.60 mg/1 AS 08/24/2004 0000
METHANE 0. 49 0.015 ug/1 AS 08/24/2004 0000
Trace Metals
SW846 6010B.T
IRON, TOTAL < 0. l 0 0. 10 mg/1 BOL 08/12/2004 0307
MANGANESE, TOTAL 0. 058 0.010 mg/1 BDL 08/12/2004 0307
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL < 0.050 0.050 mg/1 CDC 08/16/2004 1556
SM 2320B
ALKALINITY, TOTAL 4.0 1.0 mg/1 MPM 08/17/2004 0857
SW846 9056
NITRATE NITROGEN (AS N) 1.1 o. 10 mg/1 OHR 08/10/2004 1725
SULFATE 0.83 o. so mg/1 OHR 08/io/2004 1725
SW846 9060
ORGANIC CARBON, TOTAL < 1.0 1.0 mg/1 CBN 08/18/2004 1847
Sample Comments: L04081013-03
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METHAL PREP ICP SM 3030C BDL 08/10/2004 1530
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I (864) 229◄4413 I Fax [phone]
D}\VIS
FLtJ\1D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
Client ID: cc.33
Matrix
Parameter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
Subcontract Work
AM20GAX
CARBON DIOXIDE
METIW1E
Trace Metals
SW846 6'010B T
IRON, TOTAL
MANGANESE, TOTAL
Wet Chemistry
EPA 376.2
SULFIDE, TOT AI,
SM 2320B
ALKALINITY, TOTAL
SW846 9056
NITRATE NITROGEN [AS N)
SULFATE
SW846 9060
ORGANIC CARBON, TOTAL
Sample Co=enta: L04081013-04
GW/Chernw
<
Result
7.0
• 9 5. 0
550
51. 7
3.1
0.050
44.5
0.10
5.'
1. 2
Qual
NC Certijica1ion Number: 25
Project Number: 61621.01
Report Date
Page 6 of 125
September 11, 2004
Report ID: AB24838
Sample ID L04081013-04
Date Collected: 08/10/2004 0955
Date Received
RDL
7.0
0.60
0. 015
0.50
0.050
o.oso
1.0
o. 10
0 .50
1.0
Units
mg/1
mg/1
ug/1
mg/1
mg/1
rng/1
mg/1
mg/1
mg/1
mg/1
08/10/2004
Analyst
MGB
AS
AS
BDL
BDL
CDC
MPM
OHR
OHR
CBN
Date Time
08/11/2004 1948
08/24/2004 0000
08/24/2004 0000
08/12/2004 0313
08/12/2004 0313
08/16/2004 1557
08/17/2004 0909
08/10/2004 1921
08/10/2004 1921
08/18/2004 1916
The subcontracted analyses were performed by MICROSEEPS, Pittsburg; PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METHAL PREP ICP SM 3030C BDL 08/10/2004 1530
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
11
11
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Di\YIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
Client ID: DUP-1
Matrix GW/ChemW
Parameter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
Subcontract Work
AM20GA.X
CARBON DIOXIDE
METHANE
Trace Metals
SW846 6010B T
IRON, TOTAL
MANGANESE, TOTAL
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL
SM 2320B
ALKALINITY, TOTAL
SW846 9056
NITRATE NITROGEN {AS N)
SULFATE
SW846 9060
ORGANIC CARBON, TOTAL
Sample Comments: L04081013-05
<
<
<
Result
7.0
. 82. 0
660
52.1
3. 1
0. 050
45.0
0. 10
6. 0
l. l
Qual
NC Certification Number: 25
Project Number, 61621.01
Report Date
Page 7 of 125
September 11, 2004
Report ID: AB24838
Sample ID L04081013-05
Date Collected, 08/10/2004 0000
Date Received
RDL
7.0
0.60
0.015
0.50
0.050
0.050
1.0
o. 10
0. so
1.0
Units
mg/1
mg/1
ug/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
08/10/2004
Analyst
MGB
AS
AS
BDL
BDL
CDC
MPM
DHR
DHR
CBN
Date Time
08/11/2004 2014
08/24/2004 0000
08/24/2004 0000
08/12/2004 031B
08/12/2004 0318
08/16/2004 1558
08/17/2004 0917
08/10/2004 1937
08/10/2004 1937
08/18/2004 1944
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure
Analytical Prep Procedures,
METHAL PREP ICP
Method
SM 3030C
Analyst Prep Date
BDL 08/10/2004 1530
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
DA,YIS
FLo\'D LABORATORY ANALYSIS REPORT
NC Certification Number: 25
Client TICONA, LLC Project Number: 61621.01
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date September 11, 2004
Contact Pem Carter Page 8 of 125 Report ID: AB24838
Client ID: W-23 Sample ID L04081013-06
Date Collected: 08/10/2004 1300
Matrix GW/Chemw Date Received 08/10/2004
Parameter Result Qual RDL units Analyst Date Time
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL ' 7.0 7.0 mg/1 MGB 09/11/2004 2041
Subcontract Work
Af120GAX
CARBON DIOXIDE . 97 .o 0.60 mg/1 AS 08/24/2004 0000
METHANE ,., 0.015 ug/1 AS 08/24/2004 0000
Trace Metals
SW846 6010B T
IRON, TOTAL ' 0. 10 0. 10 mg/1 BDI, OB/12/2004 0324
1'-WIGANESE, TOTAL 1. 9 0.010 mg/1 SOL 08/12/2004 0324
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL ' 0.050 0.050 mg/1 CDC 08/16/2004 1559
SM 2J20B
ALKALINITY, TOTAL 10.4 0. 80 mg/1 MPM 08/17/2004 0929
SW846 9056
NITRATE NITROGEN (AS NJ 1. 9 0. 10 mg/1 DHR 08/10/2004 184 7
SULFATE 63.8 ' . 5 mg/1 DHR 08/10/2004 1904
SW846 9060
ORGANIC CARBON, 'TOTAL 1. 3 .o mg/1 CBN 08/18/2004 2 012
Sample COIIIIIICDtB: L04081013-06
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METHAL PREP I CP SM 3030C BDL 08/10/2004 1530
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] [ Fax [phone]
I
I
I
I
I
I
I
I
I
I
I
I
I
I,
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
DAYIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
Client ID: N-29
Matrix
Parameter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
Subcontract Work
AM20GAX
CARBON DIOXIDE
METHANE
Trace Metals
SW84 6 601 OB T
IRON, TOTAL
MANGANESE, TOTAL
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL
SM 2320B
ALKALINITY, TOTAL
SW846 9056
NITRATE NITROGEN (AS N)
SULFATE
SW846 9060
ORGANIC CARBON, TOTAL
GW/ChemW
Sample COIIIIIlents: L04081201-0l
<
Result
7.0
110
470
0. 10
0.20
0.050
4,0
0.69
1.2
1.0
Qual
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 9 of 125
September 11, 2004
Report ID: AB24838
Sample ID L04081201-01
Date Collected: 08/10/2004 1430
Date Received
RDL
7.0
0.60
0.015
0. 10
0.010
0 .050
1.0
o. 10
0 .50
1.0
Units
mg/1
mg/1
ug/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
08/12/2004
Analyst
MGB
AS
AS
BDL
BDL
CDC
MPM
OHR
OHR
CBN
Date Time
08/12/2004 1651
08/24/2004 0000
08/24/2004 0000
08/16/2004 1400
08/16/2004 1400
08/16/2004 1600
08/17/2004 0954
08/12/2004 1032
08/12/2004 1032
08/18/2004 2041
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METHAL PREP ICP SM 3030C BDL 08/13/2004 1100
I Davis & Floyd, Inc. l PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 f [phone] I Fax [phone]
I
D1\VIS
FLiWD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 19B
SHELBY, NC 28152
Pem Carter
Client ID: 0-25
iMatrix
Para.meter
Gas Chromatography
SW846 8015
ETHYLENE.GLYCOL
Subcontract Work
AM20GAX
CARBON DIOXIDE
METHANE
Trace Metals
·sW846 6010B T
IRON, TOTAL
MANGANESE, TOTAL
Wot Chemistry
EPA 376.2
SULFIDE, TOTAL
SM 23208
ALKAJ,INITY, TOTAL
SW846 9056
NITRATE NITROGEN (AS NJ
SULFATE
SW846 9060
ORGANIC CARBON, TOTAL
Sample Comments: L04081201-02
GW/ChemW
Result
7.0
· 42. 0
1100
54.8
0.44
0.050
40.0
0. 10
179
22.0
Qual
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 10 of 125
September 11, 2004
Report ID: AB24838
Sample ID L04081201-02
Date Collected: 08/10/2004 1600
Date Received
RDL
7.0
0.60
0. 015
0. 10
0.010
0.050
1.0
0.10
5.0
.o
Units
mg/1
mg/1
ug/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
08/12/2004
Analyst
MGB
AS
AS
BDL
BDL
CDC
MPM
OHR
OHR
CBN
Date Time
08/12/2004 1718
08/24/2004 0000
08/24/2004 0000
08/16/2004 1429
08/16/2004 1429
08/16/2004 1601
08/17/2004 1005
08/12/2004 1457
08/12/2004 1530
08/18/2004 2111
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METHAL PREP ICP SM J0J0C BDL 08/13/2004 1100
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I Bl 6 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
I
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I
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I
11 I
I
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I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Di\VIS
FLiwD LABORATORY ANALYSIS REPORT
NC Certiflcatio11 Number: 25
Client TICONA,LLC Project Number: 61621.01
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date September 11, 2004
Contact Pem Carter Page 11 of 125 Report ID: AB24838
Client ID: K-28 Sample ID L04081201-03
Date Collected: 08/10/2004 1915
Matrix GW/ChemW Date Received 08/12/2004
Parruneter Result Qual RDL Units Analyst Date Time
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL < 35.0 35.0 mg/1 MGB 08/16/2004 1406
Subcontract Work
AM20GAX
CARBON DIOXIDE 160 0.60 mg/1 AS 08/24/2004 0000
METHANE 12000 0.015 ug/1 AS 08/24/2004 0000
Trace Metals
SW846 6010B T
IRON, TOTAL 1810 1.0 mg/1 BDL 08/16/2004 1434
MANGANESE, TOTAL 32.3 0.10 mg/1 BDL 08/16/2004 1434
Wet Chemistry
EPA 353.2
NITRATE NITROGEN {AS N) < a.so X 0.50 mg/1 DHR 08/19/2004 1723
EPA 376.2
SULFIDE, TOTAL < 0. 050 0.050 mg/1 CDC 08/16/2004 1602
SM 2320B
ALKALINITY, TOTAL 2100 20. 0 mg/1 MPM 08/17/2004 1017
SW846 9056
SULFATE 5. 8 2.5 mg/1 DHR 08/17/2004 · 2 333
SW846 9060
ORGANIC CARBON, TOTAL 2110 50.0 mg/1 CBN 08/18/2004 2142
Sample Comments: L04081201-03
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method ·Analyst Prep Date
Analytical Prep Procedures:
METHAL PREP ICP SM 3030C BDL 08/13/2004 1100
Davis & Floyd, Inc. I PO Drawer 428 ) Greenwood, SC 29648 / 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
Dl\VIS
FLOVD LABORATORY ANALYSIS REPORT
NC Certification Number: 25
Client TICONA,LLC Project Number, 61621.01
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date September 11, 2004
Contact Pem Carter Page 12 of 125 Report ID: AB24838
Client 1D: TI-1 Sample ID L04081201-04
Date Collected, 08/11/2004 0940
Matrix GW/Chemw Date Received 08/12/2004
Parameter Result Qual RDL Units Analyst Date Time
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL < 7.0 7.0 mg/1 MGB 08/16/2004 12 22
Subcontract Work
AM20GAX
CARBON DIOXIDE 98.0 0.60 mg/1 AS 08/24/2004 0000
METHANE 11. 0 0.015 ug/1 AS 08/24/2004 0000
Trace Metals
SW846 6010B T
IRON, TOTAL 3.' 0 .10 mg/1 BDL 08/16/2004 144 0
MANGANESE, TOTAL 0. 088 0.010 mg/1 BDL 08/16/2004 1440
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL < 0.050 0. 050 mg/I CDC 08/16/2004 1603
SM 2320B
ALKALINITY, TOTAL 27.0 1.0 mg/1 MPM 08/17/2004 102 9
SW846 9056
NITRATE NITROGEN (AS NI 2. 2 0.10 mg/1 DHR 08/12/2004 1122
SULFATE 0.82 0.50 mg/1 DHR 08/12/2004 1122
SW846 9060
ORGANIC CARBON, TOTAL < 1 . 0 1.0 mg/1 CBN 08/18/2004 7.210
Sample Cownonts: L04081201-04
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prop Procedures:
METHAL PREP ICP SM 3030C BDL 08/13/2004 1100
Davis & Floyd, Inc. j PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue ! Greenwood, SC 29649 I [phone] I Fax [phone]
I
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I
I
I
I
I
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I
I
I
ll
I .,
i
I
I
I
!
I
I l
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
D1\YIS
FLOYD LABORATORY ANALYSIS REPORT
NC Certification Number: 25
Client TICONA,LLC Project Number: 61621.01
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date September 11, 2004
Contact. Pem Carter Page 13 of 125 Report ID; AB24838
Client ID, F-55 Sample ID L04081201-05
Date Collected, 08/11/2004 1320
Matrix GW/ChemW Date Received 08/12/2004
Parameter Result Qual RDL Units Analyst Date Time
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL 3790 280 mg/1 MGB 08/16/2004 1433
Subcontract Work
AM20GAX
CARBON DIOXIDE . 67. 0 0.60 mg/1 AS 08/24/2004 0000
METHANE 2600 0. 015 ug/1 AS 08/24/2004 0000
Trace Metals
SW846 60108 T
IRON, TOTAL 580 10 .o ·mg/1 BDL 08/16/2004 1616
MANGANESE, TOTAL 204 .0 mg/1 BDL 08/16/2004 1616
Wet Chemistry
EPA 353.2
NITRATE NITROGEN (AS N) < 0.020 0.020 mg/1 DHR 08/19/2004 1604
EPA 376.2
SULFIDE, TOTAL < 0.050 0.050 mg/1 CDC 08/16/2004 16 08
SM 232GB
ALKALINITY, TOTAL 1170 10.0 mg/1 MPM 08/17/2004 1059
SW846 9056
SULFATE 3.8 2.5 mg/1 DHR 08/18/2004 -0006
SW846 9060
ORGANIC CARBON, TOTAL 4260 100 mg/1 CBN 08/19/2004 1054
Sample Comments: L04081201-05
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METHAL PREP ICP SM 3030C BDL 08/13/2004 1100
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
D1\1'1S
FLffi'D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY. NC 28152
Pem carter
Client ID: FB-01
Matrix
Parameter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
Subcontract Work
AM20GAX
CARBON DIOXIDE
METHANE
Trace Metals
SW846 6010B T
IRON, TOTAL
MANGANESE, TOTAL
Wet Chemistry
EPA 376.2
SULF' I DE, TOTAL
SM 2320B
ALKALINITY, TOTAL
SW846 9056
NITRATE NITROGEN (AS N)
SULFATE
SW845 9060
ORGANIC CARBON, ·TOTAL
GW/Chemw
Sample Comments: L04081201-06
<
<
<
<
<
<
<
<
Result
27,7
0.60
5.3
0. 10
0. 010
0 .050
1.0
o. 10
0. 50
1.0
Qual
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 14 of 125
September 11, 2004
Report ID: AB24838
Sample ID L04081201-06
Date Collected: 08/11/2004 0835
Date Received
RDL
7.0
0.60
0. 015
0. 10
0.010
0.050
1.0
D. 10
0 . 50
1.0
Units
mg/1
mg/1
ug/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
08/12/2004
Analyst
MGB
AS
AS
BDL
BDL
CDC
MPM
OHR
OHR
CBN
Date Time
08/12/2004 1903
08/24/2004 0000
08/24/2004 0000
08/16/2004 1452
08/16/2004 1452
08/16/2004 .1609
08/17/2004 1108
08/12/2004 1138
08/12/2004 1138
08/19/2004 1122
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METHAL PREP ICP SM 3030C BDL 08/13/2004 1100
Davis & Floyd, Inc. ) PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
Client ID: IT-1
Matrix
Parameter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
Subcontract Work
AM20GAX
CARBON DIOXIDE
METHANE
Trace Metals
SW846 6010B T
IRON, TOTAL
MANGANESE, TOTAL
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL
SM 2320B
ALKALINITY, TOTAL
SW846 9056
NITRATE NITROGEN {AS N)
SULFATE
SW846 9060
ORGANIC CARBON, TOTAL
GW/ChemW
Sample Comments: L04081201-07
Result
31. 2
190
11000
611 ,.,
0.050
1000
0.13
3.8
329
Qual
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 15 of 125 Report ID: AB24836
Sample ID L04081201-07
Date Collected: 08/11/2004 1020
Date Received
RDL
7.0
0.60
0.015
0.50
0.050
o.oso
10.0
0.10
2.5
25.0
Units
mg/1
mg/1
ug/l
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
08/12/2004
Analyst
MGB
AS
AS
BDL
BDL
CDC
MPM
DHR
DHR
CBN
Date Time
08/12/2004 2115
08/24/2004 0000
08/24/2004 0000
08/16/2004 1503
08/16/2004 1503
08/16/2004 1610
08/17/2004 1117
08/12/2004 1815
08/18/2004 0039
08/19/2004 1152
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METHAL PREP ICP SM 3030C BDL 08/13/2004 1100
I Davis & Floyd, Inc. l PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] j Fax [phone]
D1\VIS
FLOYD
Client
Contact
Client ID:
Matrix
Parameter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
Subcontract Work
AM20GAX
CARBON DIOXIDE
METHANE
Trace Metals
SW846 6010B T
IRON, TOTAL
MANGAflESE, TOTAL
Wet Chemistry
EPA 353.2
NITRATE NITROGEN (AS N)
EPA 376.2
SULFIDE, TOTAL
SM 23208
ALKALINITY, TOTAL
SW846 9056
SULFATE
SW846 9060
ORGANIC CARBON, 'TOTAL
Sample Comments: L04081201-08
LABORATORY ANALYSIS REPORT
NC Certification Number: 25
TICONA,LLC Project Number: 61621.01
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date September 11, 2004
Pem Carter Page 16 of 125 Report ID: AB24838
IT-2 Sample ID L04081201-08
Date Collected: 0B/11/2004 122 0
GW/ChemW Date Received ' 08/12/2004
Result Qual RDL Units Analyst Date Time
' 7.0 7.0 mg/1 MGB 08/12/2004 2142
370 0.60 mg/1 AS 08/24/2004 0000
5900 0.015 ug/1 AS 08/24/200<! 0000
203 0.50 mg/1 BDL 08/16/2004 1509
4.1 0. 050 mg/1 BDL 08/16/2004 1509
0.058 0.020 mg/1 DHR 08/19/2004 1631
0.052 0.050 mg/1 CDC 08/16/2004 1611
1210 10.0 mg/1 MPM 08/17/2004 1126
' 2.5 X 2.5 mg/1 DHR 08/18/2004 ·0112
76. 4 10.0 mg/1 CBN 08/19/2004 1221
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method ·Analyst Prep Date
Analytical Prep Procedures:
METHAL PREP ICP SM 3030C BDL 08/13/2004 1100
Davis & Floyd, Inc. I PO Drawer 428 ! Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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D1\VIS
FLbYD LABORATORY ANALYSIS REPORT
Client
contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
Client ID: IT-3
Matrix
Parameter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
Subcontract Work
AM20GAX
CARBON DIOXIDE
METHANE
Trace Metals
SW846 6010B T
IRON, TOTAL
MANGAN"ESE, TOTAL
GW/ChemW
Result
7.0
36.0
H000
106
1.1
Qual
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 17 of 125 Report ID: AB24838
Sample ID L04081201-09
Date Collected: OB/11/2004 1505
Date Received
RDL
7 0
0.60
0.015
0.50
0. 050
Units
mg/1
mg/1
ug/1
08/12/2004
Analyst
MGB
AS
AS
BDL
BDL
Date Time
08/12/2004 2208
08/24/2004 0000
08/24/2004 0000
08/16/2004 1526
08/16/2004 1526 I Wet Chemistry
I
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I
EPA 376.2
SULFIDE, TOTAL
SM 23208
ALKALINITY, TOTAL
SWB46 9056
NITRATE NITROGEN (AS N)
SULFATE
SW846 9060
ORGANIC CARBON, TOTAL
Sample Comments: L04081201-09
<
<
0.050
187
o. 10
0 .50
8.5
0. 050 mg/1 CDC
2.0 mg/1 MPM
o. 10 mg/1 OHR
0. 50 mg/1 DHR
1. 0 mg/1 CBN
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METHAL PREP ICP SM 3030C BDL 08/1)/2004 1100
08/16/2004 1612
08/17/2004 1139
08/12/2004 1155
08/12/2004 1!55
08/19/2004 1250
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 j [phone] I Fax [phone]
Di\YIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
Matrix
Parameter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
Subcontract Work
AM20GAX
CARBON DIOXIDE
METHANE
Trace Metals
SW846 6010B T
IRON, TOTAL
MANGANESE, TOTAL
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL
SM 2320B
ALKALINITY, TOTAL
SW846 9056
NITRATE NITROGEN (AS N)
SULFATE
SW846 9060
ORGANIC CARBON, TOTAL
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
GW/Chemw
<
<
<
<
Sample Comments: L04081201-10
Result
7.0
-18. 0
19000
56.3
1.3
o. 050
118
0.10
0.50
,.,
Qual
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 18 of 125 Report ID: AB24838
Sample ID L04081201-10
Date Collected: 08/11/2004 1210
Date Received
RDL
7.0
0.60
0.015
0.10
0.010
0.050
1.0
o. 10
0 . 50
1.0
Units
mg/1
mg/1
ug/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
08/12/2004
Analyst
MGB
AS
AS
BDL
BDL
CDC
MPM
OHR
OHR
CBN
Date Time
08/12/2004 2234
08/24/2004 0000
08/24/2004 0000
08/16/2004 1532
08/16/2004 1532
08/16/2004 1613
08/17/2004 1146
08/12/2004 1211
08/12/2004 1211
08/19/2004 1319
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METHAL PREP ICP SM 3030C BDL 08/13/2004 1100
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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DAYIS
FLt1YD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHEL~Y. NC 28152
Pem Carter
Client ID: IT-5
Matrix
Parameter
Gas Chromatography
sr-.rs46 ao1s
ETHYLENE GLYCOL
Subcontract Work
AM20GAX
CARBON DIOXIDE
METHANE
Trace Metals
SW846 6010B T
IRON, TOTAL
MANGANESE, TOTAL
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL
SM 23208
ALKALINITY, TOTAL
SW846 9056
NITRATE NITROGEN (AS N)
SULFATE
SW846 9060
ORGANIC CARBON, TOTAL
GW/ChernW
Sample Comments: L04081201-11
<
<
<
Result
7.0
220
13000
85.7
3.'
0. 050
620
0.12
a.so
12.6
Qual
NC Certification Number: 25
Project Number, 61621.01
Report Date September 11, 2004
Page 19 of 125 Report ID: AB24838
Sample ID L04081201-ll
Date Collected: 08/11/2004 1440
Date Received
RDL
7.0
0.60
0. 015
0.10
0.010
0.050
4.0
o. 10
0 .50
l . 0
Units
mg/1
ug/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
08/12/2004
Analyst
AS
AS
BDL
BDL
CDC
MPM
OHR
DHR
CBN
.,..
Date Titne
08/12/2004 _2301
08/24/2004 0000
08/24/2004 0000
08/16/2004 1537
08/16/2004 1537
08/16/2004 1614
OB/17/2004 1154
08/12/2004 1228
0B/12/2004 1228
08/19/2004 1348
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METHAL PREP ICP SM 3030C BDL 08/13/2004 1100
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue ! Greenwood, SC 29649 I [phone] I Fax [phone]
Di\VIS
FLOYD LABORATORY ANALYSIS REPORT
NC Certification Number: 25
Client TICONA,LLC Project Number; 61621.01
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date September 11, 2004
Contact Pem Carter Page 20 of 125 Report ID: AB24838
Client ID: IT-6 Sample ID L04081304-01
Date Collected, 08/11/2004 1703
Matrix GW/ChemW Date Received 08/12/2004
Parameter Result Qual RDL Units Analyst Date Time
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL < 140 140 mg/1 MGB 08/16/2004 1129
Subcontract Work
AM20GAX
CARBON DIOXIDE 250 0.60 mg/1 AS 08/27/2004 0000
METHANE 9000 0.015 ug/1 AS 08/27/2004 0000
Trace Metals
SW846 6010B T
IRON, TOTAL 1630 20. 0 mg/1 BDL 08/16/2004 1629
MANGANESE, TOTAL 624 2 .0 mg/1 BDL 08/16/2004 162 9
Wet Chemistry
EPA 353.2
NITRATE NITROGEN (AS N) < 0.20 X 0. 20 mg/1 DHR 08/19/2004 1635
EPA 375.2
SULFIDE, TOTAL < 0. 050 0.050 mg/1 CDC 08/17/2004 1206
SM 2320B
ALKALINITY, TOTAL 2110 20.0 mg/1 MPM 08/17/2004 12 02
SW846 9038
SULFATE 3.0 3.0 mg/1 DHR 08/26/2004 1350
SW845 9050
ORGANIC CARBON, :TOTAL 4740 100 mg/1 CBN 08/19/2004 142 0
Sample CoDlIIlents: L0408l304~01
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method ·Analyst Prep Date
Analytical Prep Procedures:
METHAL PREP ICP SM 3030C BDL 08/13/2004 1100
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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D1\VIS
FLtwD LABORATORY ANALYSIS REPORT
NC Cenijicalion Number: 25
Client TICONA, LLC Project Number: 61621.01
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 2B152 Report Date September 11, 2004
Contact Pem Carter Page 21 of 125 Report ID: AB24838
Client IO: IT-7 Sample ID L04081304~02
Date Collected: 08/11/2004 1710
Matrix GW/ChemW Date Received 08/12/2004
Parameter Result Qual RDL units Analyst Date Time
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL < 35.0 35. 0 mg/1 MGB 08/16/2004 1340
Subcontract Work
AM20GAX
CARBON DIOXIDE 280 0.60 mg/1 AS 08/27/2004 0000
METHANE 7900 0.015 ug/1 AS 08/27/2004 0000
Trace Metals
SW846 6010B T
IRON, TOTAL 432 10 .o mg/1 BDL 08/16/2004 1604
MANGANESE, TOTAL 373 .0 mg/1 BDL 08/16/2004 1604
Wet Chemistry
EPA 353.2
NITRATE NITROGEN (AS N) 0.025 0.020 mg/1 DHR 08/19/2004 1610
EPA 376.2
SULFIDE, TOTAL < 0.050 0.050 mg/1 CDC 08/17/2004 12 07
SN 23208
ALKALINITY, TOTAI, 1190 10 .o mg/1 MPM 08/17/2004 1212
SW846 9038
SULFATE < 3.0 3. 0 mg/1 DHR 08/26/2004· 1359
SWB46 9060
ORGANIC CARBON, TOTAL 2170 50.0 mg/1 CBN 08/19/2004 14 50
Sample Comments: L04081304-02
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METHAL PREP I CP SM 3030C BDL 08/13/2004 1100
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue J Greenwood, SC 29649 I [phone] I Fax [phone]
Di\VIS
FLtJfD LABORATORY ANALYSIS REPORT
NC Certification Number: 25
Client T:ICONA,LLC Project Number: 61621.01
2525 BLACKSBURG ROAD
HWY 198
SHELBY I NC 28152 Report Date September 11, 2004
Contact Pem Carter Page 22 of 125 Report ID: AB24838
Client ID: IT-BR Sample ID L04081304-03
Date Collected: 08/11/2004 184 0
"Matrix GW/ChemW Date Received 08/12/2004
Parameter Result Qual RDL Units Analyst Date Time
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL < 7.0 7.0 mg/1 MGB 08/16/2004 1248
Subcontract Work
AM20GAX
CARBON DIOXIDE 160 0.60 mg/1 AS 08/27/2004 0000
METHANE 13000 0.015 ug/1 AS 08/27/2004 0000
Trace Metals
SW846 6010B T
IRON, TOTAL 616 2.0 mg/1 BDL 08/16/2004 1610
MANGANESE, TOTAL 43. 9 0.20 mg/1 BDL 08/16/2004 1610
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL < 0. 050 0.050 mg/1 CDC 08/17/2004 1208
SM 2320B
ALKALINITY, TOTAL 900 10.0 mg/1 MPM 08/17/2004 1221
SW846 9038
SULFATE 19. 6 12.0 mg/1 OHR 08/26/2004 14 08
SW846 9056
NITRATE NITROGEN (AS N) < 0.10 0.10 mg/1 OHR 08/13/2004 1333
SW846 9060
ORGANIC CARBON, TOTAL 583 20.0 mg/1 CBN 08/19/2004 1521
Sample Comments: L0408l304-03
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure
Analytical Prep Procedures 1
METHAL PREP ICP
Method
SM 3030C
"Analyst Prep Date
BDL 08/13/2004 1100
Davis & Floyd, Inc. I PO Drawer 426 I Greenwood, SC 29646 I 616 E. Durst Avenue I Greenwood, SC 29649 / [phone] I Fax [phone]
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
NC Cenijication Number: 25
Client TICONA,LLC Project Number: 61621.01
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date September 11, 2004
Contact Pem Carter Page 23 of 125 Report ID: AB24838
Client ID: IT•9 Sample ID L04081704-01
Date Collected: 08/16/2004 1000
Matrix ' GW/ChemW Date Received 08/17/2004
Parameter Result Qual RDL units Analyst Date Time
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL ' 7.0 7.0 mg/1 MGB 08/25/2004. 1924
Subcontract Work
AM20GAX
CARBON DIOXIDE 210 0.60 mg/1 AS 08/27/2004 0000
METHANE 16000 0. 015 ug/1 AS 08/27/2004 0000
Trace Metals
SWB46 6010B T
IRON, TOTAL 141 2.0 mg/1 SOL 08/23/2004 2134
MANGANESE, TOTAL 91.6 0.20 mg/1 SOL 08/23/2004 2134
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL ' 0. 050 o.oso mg/1 CDC 08/23/2004 0954
SM 2320B
ALKALINITY, TOTAL 580 4.0 mg/1 MPM 08/17/2004 1944
SWB46 9056
NITRATE NITROGEN (AS NJ ' 0.10 0.10 mg/1 OHR 08/17/2004 2014
SULFATE ' a.so 0.50 mg/1 OHR 08/17/2004 2014
SWB46 9060
ORGANIC CARBON, TOTAL 84. 0 l.O mg/1 CBN 08/19/2004 1811
Sample Co=ents: L04081704-0l
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METHAL PREP ICP SM 3030C SOL 08/18/2004 0815
1 Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
D}\VIS
FLtf¥D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
Client ID: V-23
;Matrix
Parameter
Gaa Chromatography
SW846 8015
ETHYLENE GLYCOL
Subcontract Work
AM20GAX
CARBON DIOXIDE
METHANE
Trace Metals
SW846 6010B T
IRON, TOTAL
MANGANESE, TOTAL
Wet Chemistry
EPA 353.2
NITRATE NITROGEN {AS N)
EPA 376. 2
SULFIDE, TOTAL
SM 2320B
ALKALINITY, TOTAL
SW846 9056
SULFATE
SW846 9060
ORGANIC CARBON, TOTAL
Sample Comments: L040B1704-02
GW/Chemw
<
Result
8200
180
12000
2050
933
0.43
0. 050
3130
36.5
9840
Qual
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 24 of 125
September 11, 2004
Report ID, AB24838
Sample ID L04081704-02
Date Collected: 08/16/2004 1130
Date Received
RDL
280
0.60
0. 015
20.0
2.0
0.10
0.050
20.0
0.50
250
Units
mg/1
mg/1
ug/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
08/17/2004
Analyst
MGB
AS
AS
BDL
BDL
DHR
CDC
MPM
DHR
CBN
Dato Time
08/25/2004 2042
08/27/2004 0000
08/27/2004 0000
08/23/2004 2140
08/23/2004 2140
08/31/2004 1523
08/23/2004 0955
08/17/2004 1952
08/17/2004 2047
08/19/2004 1840
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method · Analyst Prep Date
Analytical Prop Procedures:
METHAL PREP ICP SM 3030C BDL 08/18/2004 0815
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I fax [phone]
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DAYIS
FLtwD LABORATORY ANALYSIS REPORT
NC Certification Number: 25
Client TICONA,LLC Project Number: 61621. 01
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date September 11, 2004
Contact Pem Carter Page 25 of 12s Report ID: AB24838
Client ID: v-65 Sample ID L04081704-03
Date Collected: 08/16/2004 1300
Matrix ' GW/ChemW Date Received 08/17/2004
Parameter Result Qual RDL Units Analyst Date Time
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL < 7.0 7.0 mg/1 MGB 08/25/2004 1950
Subcontract Work
AM20GAX
CARBON DIOXIDE 83.0 0.60 mg/1 AS 08/27/2004 0000
METHANE 18000 0.015 ug/1 AS 08/27/2004 0000
Trace Metals
SW846 6010B T
IRON, TOTAL 20.4 0.10 mg/1 BDL 08/23/2004 1937
MANGANESE, TOTAL 0.96 0.010 mg/1 BDL 08/23/2004 1937
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL 0.050 0.050 mg/1 CDC 08/23/2004 0956
SM 2320B
ALKALINITY, TOTAL 250 4.0 mg/1 MPM 08/17/2004 2000
SW846 9056
NITRATE NITROGEN (AS N) < 0.10 0 .10 mg/1 DHR 08/17/2004 2121
SULFATE 2.8 0.50 mg/1 DHR 08/17/2004 2121
SW846 9060
ORGANIC CARBON, TOTAL 1.a 1.0 mg/1 CBN 08/19/2004 1908
Sample COllln'lenta: L04081704-03
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
METHAL PREP ICP SM 3030C BDL OB/18/2004 0815
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I fax [phone] I -
DAYIS
FL6i'D
Client
Contact
Client
Matrix
Parameter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
Subcontract Work
AM20GAX
CARBON DIOXIDE
METHANE
Trace Metals
SW846 6010B T
IRON, TOTAL
MANGANESE, TOTAL
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL
SM 2320B
ALKALINITY, TOTAL
SW846 9056
NITRATE NITROGEN (AS N)
SULFATE
SW846 9060
ORGANIC CARBON, TOTAL
ID:
Sample Comments: L0408l704-04
LABORATORY ANALYSIS REPORT
NC Certification Number: 25
TICONA,LLC Project Number: 61621.01
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date September 11, 2004
Pem Carter Page 26 of 125 Report ID: AB24838
DUP-3 Sample ID L04081704-04
Date Collected: 08/16/2004 0000
GW/ChemW Date Received 08/17/2004
Result Qual RDL Units Analyst Date Time
' 7.0 7.0 mg/1 MGB 08/25/2004 2016
79.0 0.60 mg/1 AS 08/27/2004 0000
16000 0. 015 ug/1 AS 08/27/2004 0000
19.8 0.10 mg/1 BOL 08/23/2004 1946
0.94 0. 010 mg/1 BOL 08/23/2004 1946
' 0 .050 0.050 mg/1 CDC 08/23/2004 0957
260 4.0 mg/1 MPM 08/17/2004 2008
' 0.10 0.10 mg/1 OHR 08/17/2004 2154
2.7 0.50 mg/1 OHR 08/17/2004 2154
1. 6 1.0 mg/1 CBN 08/19/2004 1937
The subcontracted analyses were performed by MICROSEEPS, Pittsburg, PA.
Prep Procedure
Analytical Prep Proccdurcs1
METI-iAL PREP ICP
Method
SM 3030C
Analyst Prep Date
BOL 08/18/2004 0815
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 J [phone] I Fax [phone]
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DAYIS
FLtwD LABORATORY ANALYSIS REPORT
Client TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Contact ,.Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 27 of 125 Report ID: AB24838
QC Summary Data
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
DAYIS
FLtrfD LABORATORY ANALYSIS REPORT
Client
Contact
TJ:CONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenijication Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 28 of 125 Report ID: AB24838
QC Batch Report -Batch Sample List
WorkGroup WG38587 Matrix GW/Chemw
Description: GC/EG Prep Method
Analtyical Method: SW646 8015
PREP ANALYTICAL
Sample ID Client ID Run# Date Time Date Time Analyst
L04081013-0l Q-33 1 08/11/2004 1829 MGB
L04081013-02 J-29 1 08/11/2004 1855 MGB
L04081013-03 U-38 1 08/11/2004 1921 MGB
L04081013-04 CC-33 1 08/11/2004 1948 MGB
L04D81013-05 DUP-1 08/11/2004 2014 MGB
L04081013-06 W-23 1 08/11/2004 2041 MGB
MB39587: 1 Method Blank 1 08/11/2004 1711 MGB
LCS38587:1 Laboratory Control Spike 1 08/11/2004 1737 MGB
MS04081013-0l:38587 Matrix Spike 08/11/2004 2133 MGB
MSD04081013-01:38587 Matrix Spike Duplicate 1 08/11/2004 2159 MGB
Dilution
1
1
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 81 6 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
QC Batch Report -Method Blanks
WorkGroup: WG3B587
Blank MB38587:l
Para.I11eter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
Result Qual
7.0
NC Cenijication Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 29 of 125 Report ID: AB24838
Matrix: GW/ChemW
RDL Units Analyst Date Time
7.0 mg/1 MGB 08/11/2004 1711
Davis & Floyd, Inc. I PO Drawer 428 l Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] l Fax [phone]
DAYIS
FLtJfD LABORATORY ANALYSIS REPORT
ETHYLENE GLYCOL
ETHYLENE GLYCOL
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenification Number: 25
Project Number, 61621.01
Report Date September 11, 2004
Page 30 of 125 Report ID: AB24838
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG38587 Matrix GW/Chemw
MS/MSD MS04081013-0l:38587 Prep Method
MSD04081013-0l:38587 Analtyical Method: SW846 8015
50. 00 < 7.00 51. 47 mg/1 103 57-158
SO.OD 52-43 mg/1 105 2 24 57-158
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 81 6 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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Df\YIS
FLtwD LABORATORY ANALYSIS REPORT
ETHYLENE GLYCOL
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 31 of 125
September 11, 2004
Report ID: AB24838
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG38587 Matrix GW/ChemW
LCS LCS38587:l Prep Method
Analtyical Method: SW846 8015
50.00 53.00 mg/1 106 77-126
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
Di\VIS
FLfflrD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certijicalion Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 32 of 125 Report ID: AB2483B
QC Batch Report -Batch Sample List
WorkGroup WG38623 Matrix GW/Chemw
Description; GC/EG Prep Method
Analtyical Method: SWB46 8015
PREP ANALYTICAL
Sample ID Client ID •=• Date Time Date Time Analyst
L04081201-01 N-29 l 08/12/2004 1651 MGB
L040B1201-02 0-25 l 08/12/2004 1718 MGB
L04081201-06 FB-01 l 08/12/2004 1903 MGB
L0408120l-07 IT-1 08/12/2004 2115 MGB
L040B1201-08 IT-2 l 08/12/2004 2142 MGB
L04081201-09 IT-3 l 08/12/2004 2208 MGB
L04081201-10 IT-4 l 08/12/2004 2234 MGB
L04081201-ll IT-5 08/12/2004 2301 MGB
MB38623:l Method Blank l 08/12/2004 1532 MGB
LCS38623:l Laboratory Control Spike l 08/12/2004 1558 MGB
MS04081201-01 38623 Matrix Spike 08/12/2004 2354 MGB
MSD0408120l-Ol:38623 Matrix Spike Duplicate l 08/13/2004 0020 MGB
Dilution
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I (8641 229-4413 I Fax [phone]
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Df\171S
FLo\1D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,t.LC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
QC Batch Report -Method Blanks
WorkGroup: WG38623
Blank
Parameter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
MB38623:l
Result Qual
< 7.0
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 33 of 125 Report ID: AB24838
Matrix: GW/Chemw
RDL Units Analyst Date Time
7.0 mg/1 MGB 08/12/2004 1532
•1 Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
DAYIS
FLffi.7D LABORATORY ANALYSIS REPORT
ETHYLENE GLYCOL
ETHYLENE GLYCOL
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
NC Certification Number: 25
Project Number: 61621.01
'Report Date September 11, 2004
Page 34 of 125 Report ID: AB24838
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG38623 Matrix GW/Chemw
MS/MSD MS04081201-0l:38623 Prep Method
MSD0408120l·Ol:38623 Analtyical Method: SW846 8015
50.00 < 7.00 SJ .13 mg/1 106 57-158
50.00 50.75 102 5 24 57-158
NOTE: MS/MSD t recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 J [phone] I fax [phone]
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D1\:VIS
FLtwD LABORATORY ANALYSIS REPORT
ETHYLENE GLYCOL
Client
contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 35 of 125 Report ID: AB24838
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup, WG38623 Matrix GW/Chemw
LCS LCS38623:l Prep Method
Analtyical Method: SWB46 8015
50.00 53.16 106 77-126
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
D1\VIS
FLtJfD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 36 of 125
September 11, 2004
Report ID: AB24838
QC Batch Report -Batch Sample List
workGroup WGJ8639 Matrix GW/Chemw
Description: GC/EG Prep Method
Analtyical Method; SW846 8015
PREP ANALYTICAL
Sample ID Client ID Run# Date Time Date Time Analyst
L04081201-03 K-28 1 08/16/2004 1406 MGB
L04081201-04 TI-1 1 08/16/2004 1222 MGB
L04081201-0S F-55 1 08/16/2004 1433 MGB
L04081304-0l IT-6 1 08/16/2004 1129 MGB
L04081304-02 IT-7 1 08/16/2004 .1340 MGB
L04081304-03 IT-BR 1 08/16/2004 1248 MGB
MB38639:l Method Blank 1 08/16/2004 1104 MGB
LCS38639:l Laboratory Control Spike 1 OB/16/2004 1131 MGB
MS04081201-04:38639 Matrix Spike 08/16/2004 1525 MGB
MSD04081201-04:38639 Matrix Spike Duplicate 1 08/16/2004 1551 MGB
Dilution
5
40
20
5
Davis & Floyd, Inc. J PO Drawer 428 J Greenwood, SC 29648 J 816 E. Durst Avenue J Greenwood, SC 29649 I [phone] I Fax [phone]
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D1\VIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
QC Batch Report -Method Blanks
WorkGroup: WG38639
Blank
. Parameter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
MB38639; 1
Result Qual
< 7.0
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 37 of 125
Matrix, GW/Chemw
RDL Units
September ll, 2004
Report ID: AB24838
Analyst Date Time
7.0 mg/1 MGB 08/16/2004 1104
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
D1\:VIS
FLtJfD LABORATORY ANALYSIS REPORT
ETHYLENE GLYCOL
ETHYLENE GLYCOL
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 38 of 125 Report ID: AB24838
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG38639 Matrix GW/Chemw
MS/MSD MS0408120l-04:38639 Prep Method
MSD04081201-04_1 38639 Analtyical Method: SW846 8015
50. 00 < 7.00 46.08 mg/1 92 57-158
50.00 49. 29 99 7 24 57-158
NOTE: MS/MSD t recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29646 I Bl 6 E. Durst Avenue I Greenwood, SC 29649 I [phone] I fax [phone]
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
ETHYLENE GLYCOL
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 39 of 125 Report ID: AB24838
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG38639 Matrix GW/Chemw
LCS LCS38639:l Prep Method
Analtyical Method: SW846 8015
SO.OD
1 Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 40 of 125 Report ID: AB24838
QC Batch Report -Batch Sample List
Sample ID
L04081704-0l
L04081704-02
L04081704-03
L04081704-04
MB38774:l
LCS38774: 1
WorkGroup WG38774
Description: GC/EG
Client ID
IT-9
V-23
V-65
DUP-3
Method Blank
Laboratory Control
MS04081704-01:38774 Matrix Spike
Spike
MSD04081704-0l:38774 Matrix Spike Duplicate
Run#
1
1
1
1
1
1
Matrix GW/ChernW
Prep Method
Analtyical Method: SW846 8015
PREP ANALYTICAL
Date Time Date Time Analyst
08/25/2004 1924 MGB
08/25/2004 2042 MGB
08/25/2004 1950 MGB
08/25/2004 2016 MGB
08/25/2004 .1807 MGB
08/25/2004 1833 MGB
08/25/2004 2200 MGB
08/25/2004 2226 MGB
Dilution
40
1
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I Bl 6 E. Durst Avenue I Greenwood, SC 29649 J (864) 229-441 3 I Fax [phone]
11
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DAYIS
FLtJ\'D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
QC Batch Report -Method Blanks
WorkGroup: WG38774
Blank
Parameter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
MB38774: l
Result Qual
' 7.0
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 41 of 125 Report ID: AB24838
Matrix: GW/ChernW
RDL Units Analyst Date Time
7.0 mg/1 MGB 08/25/2004 1807
Davis & Floyd, Inc. J PO Drawer 428 I Greenwood, SC 29648 J 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
DAYIS
FLtJ\1D LABORATORY ANALYSIS REPORT
ETHYLENE GLYCOL
ETHYLENE GLYCOL
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HwY 198
SHELBY, NC 28152
Pem Carter
NC Cenijication Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 42 of 125 Report ID: AB2483B
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG38774 Matrix GW/Chemw
MS/MSD MS04081704-0l:38774 Prep Method
MSD04081704-0l:38774 Analtyical Method: SW846 8015
50.00 < 7. 00 46. 29 mg/1 93 57-158
50.00 48 .13 mg/1 96 4 24 57-158
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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DL\VIS
FLtJfD LABORATORY ANALYSIS REPORT
ETHYLENE GLYCOL
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Fem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 43 of 125 Report ID: AB24838.
QC Batch Report -Laboratory Control Standards and Duplicates
workGroup: WG38774 Matrix GW/ChemW
LCS LCS38774:l Prep Method
Analtyical Method: SW846 8015
50.00 48.98 98 77-126
' I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
D}\VIS
FLtJ\'D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HwY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 44 of 125
September 11, 2004
Report IO: AB24838
QC Batch Report -Batch Sample List
WorkGroup WG38614 Matrix GW/ChemW
:Description: 3030C (5) Prep Method
Analtyical Method: SW846 6010B T
PREP ANALYTICAL
Sample ID Client ID Run# Date Time Date Time Analyst
L04~81013-01 Q-33 1 08/12/2004 0232 BDL
L04081013-02 J-29 08/12/2004 0301 BDL
L04081013-03 U-38 08/12/2004 0307 BDL
L04081013-04 CC-33 1 08/12/2004 0313 BDL
L040810ll-05 DUP-1 1 08/12/2004 ,0318 BDL
L04081013-06 W-23 08/12/2004 0324 BDL
MB38614: 1 Method Blank 08/12/2004 0221 BDL
LCS38614:l Laboratory Control Spike 1 08/12/2004 0227 BDL
MS04081013-01 · 38614 Matrix Spike 1 08/12/2004 0238 BDL
MSD04081013-0l:38614 Matrix Spike Duplicate 1 08/12/2004 0244 BDL
Dilution
1
5
5
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I fax [phone]
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DAYIS
FLtfYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
QC Batch Report -Method Blanks
WorkGroup: WG38614
Blank
Parllllleter
Trace Metals
SW846 6010B T
IRON, TOTAL
MANGANESE, TOTAL
Prep Procedure
Analytical Prep Procedures:
METHAL PREP ICP
MB38614:l
Method
SM 3030C
'
'
Result Qual
0.10
0.010
Analyst
BDL
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 45 of 125 Report ID: AB24B38
Matrix: GW/Chemw
RDL
0.10
0.010
Units
mg/1
mg/1
Prep Date
OB/10/2004 1530
Analyst
BDL
BDL
Date Time
08/12/2004 0221
08/12/2004 0221
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I fax [phone] I .
Di\VIS
FLtJfD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenijication Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 46 of 125 Report ID: AB24838
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG38614
.MS/MSD MS0408101J-Ol:38614
IRON, TOTAL
MANGANESE, TOTAL
IRON, TOTAL
MANGANESE, TOTAL
MSD04081013-0l:38614
1.00
0.100
1.00
0.100
0 .103
0.0950
1.10
0.187
Matrix GW/Chemw
Prep Method
Analtyical Method: SW846 6010B T
1.10
0.186
mg/1
rng/1
mg/1
mg/1
100
92
100
91
0
l
76-125
82-115
10
10
76-125
82-115
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I fax [phone]
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D1\VIS
FLfWD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenijica1ion Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 47 of 125 Report ID; AB24838
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG38614
LCS
IRON, TOTAL
MANGANESE, TOTAL
LCS38614:l
2.00
0.200
2. 02
0.194
Matrix GW/ChemW
Prep Method
Analtyical Method: SW846 6010B T
mg/1
mg/1
101
97
89-111
87-110
Davis & Floyd, Inc. I PO Drawer428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax {864) 229-7119.
Dl\VIS
FL(fyo LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.0l
Report Date September 11, 2004
Page 48 of 125 Report ID: AB24838
QC Batch Report -Batch Sample List
WorkGroup WG38664
.Description: )OJOC (5)
Sample ID
L04081201-01
L04081201-02
L04081201-03
L04081201-04
L04081201-05
L04081201-06
L04081201-07
L04081201-08
L0408l201-09
L04081201-10
I.04081201-11
L04081304-0l
L04081304-02
L04081304-03
004081201-06:38664
MB38664: 1
LCS38664:l
MS04081201-01:38664
MSD04081201-0l:38664
Client ID
N-29
0-25
K-28
TI-1
F-55
FB-01
IT-1
IT-2
IT-3
IT-4
IT-5
IT-6
IT-7
IT-SR
Duplicate
Method Blank
Laboratory Control Spike
Matrix Spike
Matrix Spike Duplicate
1
1
1
1
1
1
1
1
1
Matrix GW/ChemW
Prep Method
Analtyical Method: SW846 60108 T
PREP ANALYTICAL
Date Time Date Time Analyst
08/16/2004 1400 BDL
08/16/2004 1429 BDL
08/16/2004 1434 BDL
08/16/2004 1440 BDL
08/16/2004 1616 BDL
08/16/2004 1452 BDL
08/16/2004 1503 BDL
08/16/2004 1509 BDL
08/16/2004 1526 BDL
08/16/2004 1532 BDL
08/16/2004 1537 BDL
08/16/2004 1629 BDL
08/16/2004 1604 BDL
08/16/2004 1610 BDL
08/16/2004 1457 BDL
08/16/2004 1348 BDL
08/16/2004 1354 BDL
08/16/2004 1417 BDL
08/16/2004 1423 BDL
Dilution
1
10
100
5
5
5
1
200
100
20
1
1
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 / [phone] I Fax [phone]
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Di\VIS
FLtiYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
QC Batch Report -Method Blanks
WorkGroup: WG38664
Blank
Parameter
Trace Metals
SW846 6010B T
IRON, TOTAL
MANGANESE, TOTAL
Prop Procedure
Analytical Prep Procedures:
METHAL PREP ICP
MB38664:1
Method
SM 3030C
Result Qual
0.10
0. 010
Analyst
BDL
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 49 of 125 Report ID: AB24838
Matrix: GW/ChemW
RD"
0.10
0.010
Units
mg/1
mg/1
Prep Date
08/13/2004 1100
Analyst
BDL
BDL
Date Time
08/16/2004 1348
08/16/2004 1348
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 ! ·[phone] I Fax [phone].
Di\VIS
FLt1YD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certificalion Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 50 of 125 Report IO: AB24838
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG38664
MS/MSD MS04081201-0l:38664
IRON, TOTAL
MANGANESE, TOTAL
IRON, TOTAL
MANGANESE, TOTAL
MSD04081201-01:38664
1.00
0.100
1.00
0 .100
< 0. 100
0 .195
1.04
0 298
Matrix GW/Chemw
Prep Method
Analtyical Method: SW846 6010B T
1.05
0. 301
mg/1
mg/1
mg/1
mg/1
104
101
105
106
1
76-125
82-115
10
10
NOTE: MS/MSD I recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 81 6 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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Dl\VIS FLmro LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenification Number: 25
Project Number; 61621.01
Report Date September 11, 2004
Page 51 of 125 Report ID: AB24838
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG38664
LCS
IRON, TOTAL
MANGANESE, TOTAL
LCS38664:l
2.00
0.200
2.03
0. 197
Matrix GW/ChemW
Prep Method .
Analtyical Method: SW846 60108 T
mg/1
mg/1
102
99
89-111
87-110
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 296~8 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
Di\YIS
FLtJfD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 52 of 125 Report ID: AB24838
QC Batch Report -Sample Duplicates
WorkGroup: WG38664
Duplicate: D04081201-06:38664
IRON, TOTAL
MANGANESE, TOTAL
0.0150
0.00500
0.00
0.00
Matrix GW/Chemw
Prep Method
Analtyical Method: SW846 60108 T
0.10
0. 010
mg/1
mg/1
10
10
NOTE: Calculation of \RPD is not required for concentrations less than lOX the RDL.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I fax [phone]
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I
I
DAYIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number, 61621.01
Report Date September 11, 2004
Page 53 of 125 Report ID: AB24838
QC Batch Report -Batch Sample List
WorkGroup WG38748
Description: 3030C (5)
Slllllple ID Client ID
L04081704-0l IT-9
L04081704-02 V-23
L04081704-03 V-65
L04081704-04 DUP-3
MB38748:l Method Blank
LCS38748:l Laboratory Control Spike
MS04081704-04 :38748 Matrix Spike
MSD04081704-04:38748 Matrix Spike Duplicate
Run#
1
1
1
Matrix GW/Chemw
Prep Method
Analtyical Method: SW846 60108 T
PREP ANALYTICAL
Date Time Date Time Analyst
08/23/2004 2134 BDL
08/23/2004 2140 BDL
08/23/2004 1937 BDL
08/23/2004 1946 BDL
08/23/2004 1903 BDL
08/23/2004 1908 BDL
08/23/2004 1952 BDL
08/23/2004 1958 BDL
Dilution
20
200
1
1
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
D1\VIS
FLlwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
QC Batch Report -Method Blanks
WorkGroup: WG38748
,Blank
Parameter
Trace Metals
SWBH 6010B T
IRON, TOTAL
MANGANESE, TOTAL
Prep Procedure
Analytical Prep Procedures:
METHAL PREP ICP
MB38748:l
Method
SM ]0]0C
Result Qual
0.10
0.010
Analyst
BDL
NC Cer1ijica1ion Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 54 of 125 Report ID: AB24838
Matrix: GW/ChemW
RDL
0.10
0.010
Units
mg/1
mg/1
Prep Date
08/18/2004 0815 ·
Analyst
BDL
BDL
Date Time
08/23/2004 1903
08/23/2004 1903
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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Di\VIS
FLfWD LABORATORY ANALYSIS REPORT
Client
Contact
TrCONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 55 of 125 Report ID; AB2483B
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG38748
MS/MSD MS04081704-04:38748
IRON, TOTAL
MANGANESE. TOTAL
IRON, TOTAL
MANGANESE, TOTAL
MSD04081704-04:38748
1.00
0 .100
1.00
0 .100
Matrix GW/ChemW
Prep Method
Analtyical Method: SW846 60108 T
Not Evaluated See Note Below.
Not Evaluated See Note Below.
Not Evaluated See Note Below.
Not Evaluated See Note Below.
NOTE: MS/MSD t recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, lnc. ] PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
Di\YIS
FLtrfD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 56 of 125 Report ID: AB24838
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG38748
.LCS LCS38748:l
IRON, TOTAL
MANGANESE, TOTAL
2.00
0.200
2.09
0.201
Matrix GW/ChemW
Prep Method
Analtyical Method: SW846 60108 T
mg/1
mg/1
105
101
Davis & Floyd, Inc. I PD Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
I
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I
DAYIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 57 of 125
September 11, 2004
Report ID; A824838
QC Batch Report -Batch Sample List
WorkGroup WG38716 Matrix GW/ChemW
Description; Nitrate GW Prep Method
Analtyical Method: EPA 353.2
ANALYTICAL
Sample ID Client IO Run#
PREP
Date Time Date Time Analyst Dilution
L04081201-03 K-28
L0408120l-05 F-55
L04081201-08 IT-2 1
L04081304-0l IT-6 1
L04081304-02 IT-7
MB38716:l Method Blank l
MB38716: 1 Method Blank 2
MB38716;l Method Blank 3
LCS38716:1 Laboratory Control Spike 1
LCS38716:l Laboratory Control Spike 2
LCS38716:l Laboratory Control Spike 3
MS04081304-02 : 38716 Matrix Spike
MSD04081304-02:38716 Matrix Spike Duplicate 1
08/19/2004 1723
08/19/2004 1604
08/19/2004 1631
08/19/2004 1635
08/19/2004 1610
08/19/2004 1618
08/19/2004 1639
08/19/2004 1727
08/19/2004 1616
08/19/2004 1637
08/19/2004 1725
08/19/2004 1612
08/19/2004 1614
OHR
OHR
OHR
OHR
OHR
OHR
OHR
OHR
OHR
OHR
OHR
OHR
OHR
25
1
10
l
l
l
l
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816E. Durst Avenue I G,eenwood, SC 29649 I [phone] I Fax [phone]
DAJ'IS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
T:ICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
QC Batch Report -Method Blanks
Para.meter
Wot Chemistry
EPA 353.2
WorkGroup: WG38716
Blank MB38716:l
NITRATE NITROGEN (AS N)
NITRATE NITROGEN (AS N)
NITRATE NITROGEN (AS N)
'
'
'
Result Qual
0.020
0.020
0. 020
NC Cenification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 58 of 125 Report ID: AB24.838
Matrix: GW/Chemw
RDL
0.020
0.020
o. 020
Units
mg/1
mg/1
mg/1
Analyst
DHR
OHR
OHR
Date Time
08/19/2004 1727
08/19/2004 1639
OB/19/2004 1618
Davis & Floyd, Inc. I PO Drawer 428 / Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 / [phone] I Fax [phone]
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DAYIS
FLtJ\7D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenijicaiion Number: 25
Project Number: 61621.01
Report Date
Page 59 of 125
September 11, 2004
Report ID: AB24838
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG38716 Matrix GW/ChemW
MS/MSD MS04081304-02:38716 Prep Method
MSD04081304-02:38716 Analtyical Method: EPA 353.2
NITRATE NITROGEN (AS N) 0. 500 0.0250 0.522 mg/1 99 90-110
NITRATE NITROGEN (AS N) 0.500
NOTE: MS/MSD t recoveries are not evaluated if the sample concentration is greater than four times the spike added.
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816E. Durst Avenue I Greenwood, SC 29649 I [phone] I fax [phone]
Di\VIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number, 61621.01
Report Date September 11, 2004
Page 60 of 125 Report ID: AB24838
QC Batch Report -Laboratory Control Standards and Duplicates
workGroup: WG38716
LCS
NITRATE NITROGEN (AS N)
NITRATE NITROGEN {AS N)
NITRATE NITROGEN (AS N)
LCS38716: 1
1.00
1.00
1.00
1.01
1. 01
1 . 01
Matrix GW/ChemW
Prep Method
Analtyical Method: EPA 353.2
101
100
99
90-110
90-110
90-110
Davis & Floyd, Jnc. I PO Drawer 428 I Greenwood,_SC 29648 I 816 E. Durst Avenue l Greenwood, SC 29649 I [phone] I Fax {864) 229-7119
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Dl\VIS
FLtJ\1D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 61 of 125 Report ID: AB24838
QC Batch Report -Batch Sample List
WorkGroup WG38818 Matrix GW/Chemw
Description: Nitrate GW Prep Method
Analtyical Method: EPA 353.2
ANALYTICAL
Sample ID Client ID •=# PREP
Date Time Date Time Analyst Dilution
L04081704-02 V-23
MB38818:l Method Blank
MB38818:1 Method Blank
LCS38818:1 Laboratory Control Spike
LCS38818: l Laboratory Control Spike
MS04082303-06 ·38818 Matrix Spike
MSD04082303-06:38818 Matrix Spike Duplicate
1 08/31/2004 1523
1 08/31/2004 1520
2 09/01/2004 0841
1 OB/3°1/2004 1518
2 09/01/2004 .0839
1 08/31/2004 1512
08/31/2004 1514
DHR
DHR
DHR
DHR
OHR
DHR
OHR
5
1
5
5
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 j [phone] I Fax [phone]
D1\VIS
FLtrfD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
QC Batch Report -Method Blanks
WorkGroup: WG38818
Parruneter
Wet Chemistry
EPA 353.2
Blank
NITRATE NITROGEN (AS N)
NITRATE NITROGEN (AS N)
MB38818:l
<
Result Qual
0.020
0.020
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 62 of 125 Report ID: AB24838
Matrix: GW/Chemw
RDL
0.020
0.020
Units
mg/1
mg/1
Analyst
DHR
DHR
Date Time
09/01/2004 0841
08/31/2004 1520
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 j [phone] I Fax (864) 229•7119
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Dl\YIS
FLtrfD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 63 of 125 Report ID: AB24838
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG38818 Matrix GW/ChemW
MS/MSD MS04082303-06:38818 Prep Method
MSD04082303-06:38818 Analtyical Method: EPA 353.2
NITRATE NITROGEN (AS N) 2.50 Not Evaluated -See Note Below.
NITRATE NITROGEN (AS N) 2.50 Not Evaluated -See Note Below.
NOTE: MS/MSD l recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. l PO Drawer 428 J Greenwood, SC 29648 ] 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
Df\VIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 64 of 125 Report ID: AB2483B
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG38818
LCS LCS38818:l
NITRATE NITROGEN (AS N)
NITRATE NITROGEN {AS N)
1.00
1.00
0. 952
0. 952
Matrix GW/ChemW
Prep Method
Analtyical Method: EPA 353.2
mg/1
mg/1
95
9B
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I fax [phone]
I
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I,
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I
D1\YIS
FL6YD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11. 2004
Page 65 of 125 Report ID: AB2483B
QC Batch Report -Batch Sample List
WorkGroup WG38698 Matrix GW/Chemw
Description: Sulfide-G Prep Method
Analtyical Method: EPA 376.2
ANALYTICAL
Sample ID Client ID •=# PREP
Date Time Dato Time Analyst Dilution
L04081013-01 Q-33 1
L04081013-02 J-29
L04081013-03 U-38
L04081013-04 CC-33 1
L04081013-05 DUP-1
L04081013-06 W-23
L04081201-01 N-29 1
L04081201-02 0-25
L0408120l-03 K-28 1
L04081201-04 TI-1 1
L04081201-05 F-55 1
L04081201-06 FB-01
L04081201-07 IT-1
L04081201-08 IT-2 1
L04081201-09 IT-3
L04081201-10 IT-4 1
L04081201-11 IT-5 1
MB38698:l Method Blank 1
MB38698:2 Method Blank 1
LCS38698,l Laboratory Control Spike 1
LCS38698:2 Laboratory Control Spike 1
MS04081201-04 :38698 Matrix Spike 1
MS04081302-03:38698 Matrix Spike
MSD04081201-04 :38698 Matrix Spike Duplicate 1
MSD04081302-03:38698 Matrix Spike Duplicate
08/16/2004 1554
08/16/2004 1555
08/16/2004 1556
08/16/2004 1557
08/16/2004 1558
08/16/2004 1559
08/16/2004 1600
08/16/2004 1601
08/16/2004 1602
08/16/2004 1603
08/16/2004 1608
08/16/2004 1609
08/16/2004 1610
08/16/2004 1611
08/16/2004 1612
08/16/2004 1613
08/16/2004 1614
08/16/2004 1607
08/16/2004 1621
08/16/2004 1606
08/16/2004 1620
08/16/2004 1604
08/16/2004 1618
08/16/2004 1605
08/16/2004 1619
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CDC
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CDC
CDC
CDC
CDC
CDC
CDC
CDC
CDC
CDC
CDC
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CDC
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CDC
CDC
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CDC
CDC
CDC
1
1
1
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1
1
Davis & Floyd, Inc. ! PO Drawer 428 I Greenwood, SC 29648 I 81_6 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
Dl\VIS
FLtJ\1D LABORATORY ANALYSIS REPORT
Parameter
Wet CbCillistry
EPA 376.2
SULFIDE, TOTAL
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
QC Batch Report -Method Blanks
workGroup: WG3869B
Blank MB38698:l
Result Qual
0.050
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 66 of 125 Report ID: AB24838
Matrix: GW/Chemw
RDL Units Analyst Date Time
0.050 mg/1 CDC 08/16/2004 1607
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I Bl 6 E. Durst Avenue I Greenwood, SC 29649 ·1 [phone] I Fax [phone]
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D}\VIS
FLtwD LABORATORY ANALYSIS REPORT
Parameter
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
QC Batch Report -Method Blanks
WorkGroup: WG38698
Blank MB38698:2
Result Qual
0.050
NC Certification Number: 25
Project Nu_mber: 61621. 01
Report Date
Page 67 of 125
Matrix: GW/ChemW
RDL Units
September 11, 2004
Report IO: AB24838
.Analyst Date Time
0.050 CDC 08/16/2004 1621
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
Di\VIS
FLtrfD LABORATORY ANALYSIS REPORT
SULFIDE, TOTAL
SULFIDE, TOTAL
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 68 of 125
September 11, 2004
Report ID: ~24838
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WGJ8698
•MS/MSD MS04081201-04:38698
MSDO4O81201-O4:38698
0.670
0. 670
< 0.0500
0.676
Matrix GW/Chernw
Prep Method
Analtyical Method: EPA 376.2
0.690 103 88-113
101 2 10 88-113
NOTE: MS/MSD \: recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I (864) 229-441 3 I Fax [phone]
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I
Di\VIS
FLtfYD LABORATORY ANALYSIS REPORT
SULFIDE, TOTAL
SULFIDE, TOTAL
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenijication Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 69 of 125 Report ID: AB24B38
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG38698 Matrix GW/ChemW
MS/MSD MS04081302-03:38698 Prep Method
MSD04081302-03:38698 Analtyical Method: EPA 376.2
0.670 <: 0.0500 0.616 mg/1 92 88-113
0.670 0.658 98 7 10 88-113
NOTE: MS/MSD t recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] ! Fax [phone]
D1\VIS
FLOYD LABORATORY ANALYSIS REPORT
SULFIDE, TOTAL
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenijicarion Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 70 of 125 Report ID, AB24838
QC Batch Report -uiboratory Control Standards and Duplicates
WorkGroup: WG38698 Matrix GW/ChemW
LCS LCS38698:l Prep Method
Analtyical Method: EPA 376.2
0. 500 0.497 mg/1 99 90-110
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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DAYIS
FLM:D LABORATORY ANALYSIS REPORT
SULFIDE, TOTAL
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 71 of 125 Report ID: AB24838
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG38698 Matrix GW/ChemW
LCS LCS38698:2 Prep Method
Analtyical Method: EPA 376.2
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I Bl 6 E. Durst Avenue I Greenwood, SC 29649 I [phone] I fax [phone]
Dl\VIS
FLtJ\1D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 72 of 125 Report ID: AB24838
QC Batch Report -Batch Sample List
workGroup WG38699 Matrix GW/ChemW
Description: Sulfide-G Prep Method
Analtyical Method, EPA 376.2
ANALYTICAL
Sample ID Client ID
PREP
Date Tbne Date Time Analyst Dilution
L04081304-01 IT-6 1 08/17/2004 1206 CDC 1 L04081304-02 IT-7 08/17/2004 1207 CDC
L04081304-03 IT-BR 1 08/17/2004 1208 CDC
MB38699: 1 Method Blank 08/17/2004 1212 CDC
LCS38699:l Laboratory control Spike 08/17/2004 1211 CDC 1 MS04081304-03:J8699 Matrix Spike 08/17/2004 '1209 CDC
MSD04081304-03:38699 Matiix Spike Duplicate 1 08/17/2004 1210 CDC
Davis & Floyd, Inc. I PD Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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Di\YIS
FLfWD LABORATORY ANALYSIS REPORT
Pa:r:amoter
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
QC Batch Report -Method Blanks
WorkGroup: WG38699
Blank MB38699:l
Result Oual
< 0.050
NC Cenification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 73 of 125 Report ID: AB24838
Matrix: GW/ChernW
RDL Units Analyst Date Time
0.050 mg/1 CDC 08/17/2004 1212
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
D1\VIS
.FLtJ\'D LABORATORY ANALYSIS REPORT
SULFIDE, TOTAL
SULFIDE, TOTAL
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pern carter
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 74 of 125 Report ID: AB2483B
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG38699 Matrix GW/Chemw
MS/MS□ MS04081304-03,38699 Prep Method
MSD04081304-03:38699 Analtyical Method: EPA 376.2
0.670 < 0.0500
0.670 0. 681 102 6 10 88-113
NOTE: MS/MSD -\ recoveries are not evaluated if the sample concentration is greater than four t'imes the spike added.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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I
I
Df\VIS
FLtwD LABORATORY ANALYSIS REPORT
SULFIDE, TOTAL
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number, 61621.01
Report Date September 11, 2004
Page 75 of 125 Report ID: AB24838
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG38699 Matrix GW/ChemW
LCS LCS38699:l Prep Method
Analtyical Method, EPA 376.2
0.500 0.470 mg/1 94 90-110
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
DAYIS
FLtrYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 76 of 125 Report ID: AB2483B
QC Batch Report -Batch Sample List
WorkGroup WGJ8753 Matrix GW/Chemw
Description: Sulfide Prep Method
Analtyical Method: EPA 376.2
PREP ANALYTICAL
Sample ID Client ID Run# Date Time Date Time Analyst
L04081704-01 IT-9 1 08/23/2004 0954 CDC
L04081704-02 V-23 08/23/2004 0955 CDC
L04081704-03 V-65 1 08/23/2004 0956 CDC
L04081704-04 DUP-3 1 08/23/2004 0957 CDC
MB38753:l Method Blank 0B/23/2004 1001 CDC
LCS38753:l Laboratory Control Spike 1 08/23/2004 '1000 CDC
MS04081704-04 38753 Matrix Spike 08/23/2004 0958 CDC
MSD04081704-04: 38753 Matrix Spike Duplicate 08/23/2004 0959 CDC
Dilution
1
1
1
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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D1\YIS
FLtJfD LABORATORY ANALYSIS REPORT
Parameter
Wet Chemistry
EPA 376.2
SULFIDE, TOTAL
Client
contact
TJ:CONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
QC Batch Report -Method Blanks
WorkGroup: WG38753
Blank MB3875311
Result Qual
0.050
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 77 of 125
Matrix: GW/ChemW
RDL Units
September 11, 2004
Report ID: AB24838
Analyst Date Time
0.050 CDC 08/23/2004 1001
Dav;s & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone].
DAYIS
FLtiYD LABORATORY ANALYSIS REPORT
SULFIDE, TOTAL
SULFIDE, TOTAL
Client
Contact
TrCoNA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 78 of 125
September 11, 2004
Report ID: A824838
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG3B753 Matrix GW/Chemw
MS/MSD MS04081704-04:38753 Prep Method
MSD04081704-04:38753 Analtyical Method: EPA 376.2
0.670 < 0. 0500 0.607 mg/1 91 88-113
0.670 0 638 mg/1 95 5 10 88 113
NOTE: MS/MSD I recoveries are not evaluated if the sample concentration is greater than four Cimes the spike added.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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I
I
Di\YIS
FLtfYD LABORATORY ANALYSIS REPORT
SULFIDE, TOTAL
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 79 of 125 Report ID, AB24838
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup, WGJ8753 Matrix GW/ChemW
LCS LCS38753:l Prep Method
Analtyical Method, EPA 376.2
0. 500 0. 475 mg/1 95 90-110
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] j Fax [phone]
Dl\VIS
FLtrfD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Fem Carter
NC Cenijication Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page BO of 125 Report ID: AB24838
QC Batch Report -Batch Sample List
WorkGroup WG38705 Matrix GW/ChemW
Description: Alkalinity Total Groundwater Prep Method
Analtyical Method: SM 2320B
PREP ANALYTICAL
Sample ID Client ID Run# Date Time Date Time Analyst
L04081013-01 Q-33 1 08/17/2004 0840 MPM
L04081013-02 J-29 1 08/17/2004 0849 MPM
L04081013-03 U-38 08/17/2004 0857 MPM
L04081013-04 CC-33 1 08/17/2004 0909 MPM
L04081013-05 DUP-1 08/17/2004 0917 MPM
L04081013-06 W-23 08/17/2004 ·0929 MPM
L04081201-0l N-29 08/17/2004 0954 MPM
L04081201-02 0-25 1 08/17/2004 1005 MPM
L04081201-03 K-28 08/17/2004 1017 MPM
L04081201-04 TI-1 08/17/2004 1029 MPN
L04081201-05 F-55 1 08/17/2004 1059 MPM
L04081201-06 FB-01 1 08/17/2004 1108 MPM
L04081201-07 IT-1 1 08/17/2004 1117 MPM
L04081201-08 IT-2 1 08/17/2004 1126 MPM
L04081201-09 IT-3 08/17/2004 1139 MPM
L04081201-10 IT-4 1 08/17/2004 1146 MPM
L04081201-ll IT-5 1 08/17/2004 1154 MPM
L04081304-01 IT-6 1 08/17/2004 1202 MPM
L04081304-02 IT-7 1 08/17/2004 1212 MPM
L04081304-03 IT-SR 1 08/17/2004 1221 MPM
004081013-02 :38705 Duplicate 1 08/17/2004 1037 MPM
D04081201-07 :38705 Duplicate 1 08/17/2004 1229 MPM
MB38705:l Method Blank 1 08/17/2004 0815 MPM
LCS38705:l Laboratory Control Spike 1 08/17/2004 104 6 MPM
LCS38705:l Laboratory control Spike 2 08/17/2004 1239 MPM
Dilution
1
1
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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D1\VIS
FLtn'D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Career
QC Batch Report -Method Blanks
Para.meter
Wet Chemistry
SM 2J20B
WorkGroup: WG38705
Blank lra38705:1
ALKALINITY, TOTAL
Result Qual
' 1.0
NC Cenijication Number: 25
Project Number: 61621.01
Report Date
Page Bl of 125
Matrix: GW/ChemW
RDL Units
September 11, 2004
Report ID: AB24838
Analyst Date Time
1.0 mg/1 MPM 08/17/2004 0815
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I fax [phone]
DAYIS
FLffi'D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
NC Cenification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 82 of 125 Report ID: AB24838
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG38705
LCS LCS38705:l
ALKALINITY, TOTAL
ALKALINITY, TOTAL
1037
1037
1020
1020
Matrix GW/ChemW
Prep Method
Analtyical Method: SM 23208
mg/1
rng/1
98
98
89-103
89-103
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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D1\VIS
FLtJ\'D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 83 of 125 Report ID: AB2483B
QC Batch Report -Sample Duplicates
WorkGroup, WG38705 Matrix GW/ChemW
Duplicate: D04081013-02:38705 Prep Method
Analtyical Method: SM 2320B
ALKALINITY, TOTAL 1225 1240 10.0 rng/1 10
NOTE: Calculation of \RPO is not required for concentrations less than 1ox the RDL.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 81 6 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone].
D1\VIS
FL(1fD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 84 of 125 Report ID: AB24838
QC Batch Report -Sample Duplicates
WorkGroup: WG38705 Matrix GW/Chemw
Duplicate: D04081201·07:38705 Prep Method
Analtyical Method: SM 23208
ALKALINITY, TOTAL 1000 990. 0 10.0 mg/1 1 10
NOTE: Calculation of IRPD is not required for concentrations less than lOX the RDL.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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Di\YIS
FLtJ\1D LABORATORY ANALYSIS REPORT
Sample ID
L04081704-01
L04 081704-02
L04081704-03
L04081704-04
D04081704-03
MB38707:l
LCS38707:l
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenijication Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 85 of 125 Report ID: AB24838
QC Batch Report -Batch Sample List
WorkGroup WG38707 Matrix GW/Chemw
Description: Alkalinity Total Groundwater Prep Method
Analtyical Method: SM 23208
PREP ANALYTICAL
Client ID Run# Date Time Date Time Analyst
IT-9 08/17/2004 1944 MPM
V-23 1 08/17/2004 1952 MPM
V-65 1 08/17/2004 2000 MPM
DUP-3 08/17/2004 2008 MPM
,38707 Duplicate 1 08/17/2004 2017 MPM
Method Blank 08/17/2004 1919 MPM
Laboratory Control Spike 08/17/2004 2030 MPM
Dilution
1
1
1
1
1
1
Davis & Floyd, Inc. I PO Drawer 428 J Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
DAYIS
FLtrYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
QC Batch Report -Method Blanks
workGroup: WG38707
Blank MB)B70711
Parameter
Wet Chemistry
SM 2320B
ALKALINITY, TOTAL
Result Qual
1. 0
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 86 of 125 Report ID: AB2483B
Matrix: GW/ChemW
RDL Units Analyst Date Time
1.0 mg/1 MPM 08/17/2004 1919
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
I
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11
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11
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I
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I
I
I
I
I
I
D1\VIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY,. NC 28152
Pem Carter
NC Cenijication Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 87 of 125 Report ID: AB24838
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG38707 Matrix GW/Chemw
.LCS LCS38707:l Prep Method
Analtyical Method:. SM 2320B
ALKALINITY, TOTAL 1037 1020 mg/1 98 89-103
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.0l
Report Date September 11, 2004
Page 88 of 125 Report ID: AB2483B
QC Batch Report -Sample Duplicates
WorkGroup: WG38707 Matrix GW/Chemw
Duplicate: D04081704-03:38707 Prep Method
Analtyical Method, SM 23208
ALKALINITY, TOTAL 250. 0 252.0 ,.o mg/1 1 10
NOTE: Calculation of \RPO is not required for concentrations less than lOX the RDL.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] l Fax [phone]
I
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I
D1\VIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page B9 of 125 Report ID: AB24838
QC Batch Report -Batch Sample List
WorkGroup WG38799 Matrix GW/ChemW
Description, Sulfate GW Prep Method
Analtyical Method: SW846 9038
PREP ANALYTICAL
Sample ID Client ID Run# Date Time Date Tiine Analyst
L04081304-01 IT-6 08/26/2004 1350 DHR
L04081304-02 IT-7 08/26/2004 1359 DHR
L04081304-03 IT-SR 08/26/2004 1408 DHR
MB38799: 1 Method Blank 08/26/2004 1444 DHR
LCS38799:l Laboratory Control Spike 08/26/2004 143 9 DHR
MS04081304-02 :38799 Matrix Spike 1 08/26/2004 "I420 DHR
MSD04081304-02:38799 Matrix Spike Duplicate 08/26/2004 143 0 DHR
Dilution
1
l
4
1 .11
1.11
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
Di\VIS
FLtrYD LABORATORY ANALYSIS REPORT
Parameter
Wet Chemistry
SWB46 9038
SULFATE
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
QC Batch Report -Method Blanks
WorkGroup: WG38799
Blank MB38799:l
Result Qual
' J. 0
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 90 of 125 Report ID: AB24838
Matrix: GW/Chemw
RDL Units Analyst Date Time
3.0 mg/1 OHR 08/26/2004 1444
Davis & Floyd, Inc. I PO Drawer 428 l Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 j [phone] I Fax [phone]
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DL\VIS
FLOYD LABORATORY ANALYSIS REPORT
SULFATE
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenification Number: 25
Project Number, 61621.01
Report Date September 11, 2004
Page 91 of 125 Report ID: AB24838
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG38799 Matrix GW/ChemW
MS/MSD MS04081304-02:38799 Prep Method
MSD04081304-02:38799 Analtyical Method: SW846 9038
11.10 < 3.00 10.38 mg/1 93 70-130
NOTE: MS/MSD % recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
Di\YIS
FLtwD LABORATORY ANALYSIS REPORT
SULFATE
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 92 of 125 Report ID: AB24B38
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG38799 Matrix GW/ChemW
.LCS LCS38799:l Prep Method
Analtyical Method: SW846 9038
20.00 21. 53 mg/1 108 90-110
Davis & Floyd, Inc; I PO Drawer 428 I ·Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 / [phone] I Fax [phone]
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
NC Cenification Number: 25
Project Number: 61621. 01
Report Date September 11, 2004
Page 93 of 125 Report ID: AB24838
QC Batch Report -Batch Sample List
WorkGroup WG38585 Matrix GW/ChemW
Description: IC RUN GW Prep Method
Analtyical Method: SW846 9056
PREP ANALYTICAL
Sample ID Client ID •=• Date Time Date Time Analyst
L04081013-01 Q-33 1 08/10/2004 181-4 OHR
L04081013-01 Q-33 ' 0B/10/2004 1831 OHR
L040B1013-02 J-29 1 08/10/2004 2027 OHR
L04081013-02 J-29 ' 08/11/2004 2244 DHR
L04081013-03 U-38 1 08/10/2004 1725 OHR
L04081013-04 CC-33 08/10/2004 ·1921 OHR
L04081013-0S DUP-1 1 08/10/2004 1937 DHR
L04081013-06 W-23 1 08/10/2004 1847 OHR
L04081013-06 W-23 ' 08/10/2004 1904 DHR
MB38585:l Method Blank 08/10/2004 1346 DHR
MB38585:2 Method Blank 1 08/11/2004 1852 DHR
LCS38585:l Laboratory Control Spike 08/10/2004 1330 DHR
LCS38585:2 Laboratory Control Spike 1 08/11/2004 1836 DHR
M$04081013-03:38585 Matrix Spike 1 08/10/2004 1741 DHR
MSD04081013-03:38585 Matrix Spike Duplicate 1 08/10/2004 1758 DHR
Dilution
1
5
10
10
5
1
1.05
1.05
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
D1\YIS
FLtJ\'D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HwY 198
SHELBY, NC 28152
Pem Carter
QC Batch Report -Method Blanks
Parameter
Wet Chemistry
SW846 9056
WorkGroup: WG38585
Blank MB38585:1
NITRATE NITROGEN (AS N)
SULFATE
Result
0.10
0.50
Qual
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 94 of 125 Report ID: AB24838
Matrix, GW/Chemw
RDL Units
0.10
o.so
mg/1
mg/1
Analyst
DHR
DHR
Date Time
08/10/2004 1346
08/10/2004 1346
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 ·I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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Df\VIS
FLtffD LABORATORY ANALYSIS REPORT
Parameter
Wet Chemistry
SW846 9056
SULFATE
Client
Contact
'l'ICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Fem Carter
QC Batch Report -Method Blanks
WorkGroup: WG38585
Blank MB3858S:2
Result Qual
0.50
NC Certification Number: 25
Project Number, 61621.01
Report Date September 11, 2004
Page 95 of 125 Report ID: AB2483B
Matrix: GW/Chemw
RDL Units Analyst Date .Time
a.so mg/1 OHR 08/11/2004 1852
Davis & Floyd, Inc. I PO Drawer 428 . I Greenwood, SC 29648 I 81 6 E. Durst Avenue I Greenwood, SC 29649 J [phone] I Fax [phone]
DAYIS
FLtiYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenijication Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 96 of 125 Report ID: A824838
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG38585
MS/MSD MS04081013-0J:3858S
NITRATE NITROGEN (AS N)
SULFATE
NITRATE NITROGEN (AS N)
SULF'ATE
MSD04081013-03:38585
5 25
5.25
5.25
5.25
1.13
0. 830
6 44
6 26
Matrix GW/Chemw
Prep Method
Analtyical Method: SW846 9056
6.47
6 43
mg/1
mg/1
mg/1
mg/1
101
103
102
107
0
3
80-115
74-135
80-115
74-135
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue ) Greenwood, SC 29649 j [phone] I Fax [phone]
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DAYIS
FLtfvD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 19B
SHELBY, NC 28152
Pem Carter
NC Cenijication Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 97 of 125 Report ID: AB24838
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG385BS
LCS
NITRATE NITROGEN (AS NJ
SULFATE
LCS38585:l
5.00
25 .00
4.97
23. 98
Matrix GW/ChemW
Prep Method
Analtyical Method: SWB46 9056
mg/1
mg/1
99
96
95-105
95-105
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
DAYIS
FL(jyD LABORATORY ANALYSIS REPORT
SULFATE
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 98 of 125
September 11, 2004
Report ID; AB24838
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG38585 Matrix GW/ChemW
LCS LCS38585:2 Prep Method
Analtyical Method: SW846 9056
100 95-105
Davis & Floyd, Inc, I PO Drawer 428 l Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax {864) 229-7119
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D1\VIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 99 of 125 Report ID: AB24838
QC Batch Report -Batch Sample List
WorkGroup WG38628
Description: IC Run GW
Sample ID Client ID Run#
L04081201-0l N-29 1
L04081201-02 0-25
L04081201-02 0-25 2
L04081201-03 K-28
L04081201-04 TI-1 1
L04081201-05 F-55 1
L04081201-06 FB-01
L04081201-07 IT-1 1
L04081201-07 IT-1 2
L04081201-08 IT-2 1
L04081201-09 IT-3 1
L04081201-10 IT-4 1
L04081201-11 IT-5
MB38628: 1 Method Blank 1
MB38628:3 Method Blank 1
LCS38628: 1 Laboratory Control Spike 1
LCS38628:3 Laboratory Control Spike
MS04081201-01:38628 Matrix Spike 1
MS04081201-ll:38628 Matrix Spike 1
MSD04081201-01 :38628 Matrix Spike Duplicate 1
MSD04081201-ll:38628 Matrix Spike Duplicate 1
Matrix GW/Chemw
Prep Method
Analtyical Method: SW846 9056
PREP ANALYTICAL
Date Time Date Time Analyst Dilution
08/12/2004 1032
08/12/2004 1457
08/12/2004 1530
08/17/2004 2333
08/12/2004 1122
08/18/2004 '0006
08/12/2004 1138
OB/12/2004 1815
08/18/2004 0039
08/18/2004 0112
08/12/2004 1155
08/12/2004 1211
08/12/2004 1228
08/12/2004 1016
08/17/2004 1354
08/12/2004 0959
08/17/2004 1300
08/12/2004 1049
08/12/2004 1244
08/12/2004 1105
08/12/2004 1301
OHR
DHR
OHR
OHR
OHR
OHR
OHR
OHR
OHR
OHR
OHR
OHR
OHR
OHR
OHR
OHR
OHR
DHR
OHR
OHR
OHR
10
5
5
5
5
1
1
1
1
1.05
1.05
1.05
1.05
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. D_urst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
D1\VIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC
Pem carter
28152
QC Batch Report -Method Blanks
Parameter
Wet Chemistry
SW846 9056
workGroup: WG38628
Blank MB38628:l
NITRATE NITROGEN (AS NJ
SULFATE
Result
0 .10
a.so
Qual
NC Cenijication Number: 25
Project Number: 61621.01
Report Date
Page 100 of 125
Matrix; GW/ChemW
RDL Units
Q.10
0.50
mg/1
mg/1
September 11, 2004
Report ID: AB24838
Analyst
DHR
DHR
Date Till'le
08/12/2004 1016
08/12/2004 1016
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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D}\VIS
FLtfvD LABORATORY ANALYSIS REPORT
Parameter
Wet Chemistry
SWB46 9056
·SULFATE
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
QC Batch Report-Method Blanks
Wor~Group: WG38628
Blank MB38628:3
Result Qual
0.50
NC Certification Number: 25
Project Number, 61621.01
·Report Date September 11, 2004
Page 101 of 125 Report ID: AB24938
Matrix: GW/Chemw
RDL Units Analyst Date Time
0.50 mg/1 OHR 08/17/2004 1354
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
D1\VIS
FL(j\1D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenijication Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 102 of 125 Report ID: AB24838
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG3862B
MS/MSD MS04081201-0l:38628
NITRATE NITROGEN (AS NJ
SULF'ATE
NITRATE NITROGEN (AS N)
SULFATE
MSD04081201-0l:38628
5 25
5.25
5.25
5 25
0.690
1. 24
5.57
6.16
Matrix GW/Chemw
Prep Method
Analtyical Method: SW846 9056
5.59
6.13
mg/1
mg/1
mg/1
mg/1
93
94
93
93
0
0
80-115
74-135
10
10
80-115
74-135
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 103 of 125 Report ID: AB24838
QC Batch Report -Matrix Spikes and Duplicates
workGroup: WG38628
MS/MSO MS0408120l-ll:38628
NITRATE NITROGEN (AS NJ
SULFATE
NITRATE NITROGEN (AS N)
SULFATE
MSD04081201-ll:38628
5.25
5.25
5.25
5 25
0.120
<: 0. 500
5.13
5 .11
Matrix GW/ChemW
Prep Method
Analtyical Method: SW846 9056
5.00
4.97
mg/1
mg/1
mg/1
mg/1
95
97
93
95
3
3
80-115
74-135
10
10
a6-11s
74-135
NOTE: MS/MSD % recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I Bl 6 E. Durst Avenue [ Greenwood, SC 29649 [ [phone] [ Fax [phone]
D1\VIS
FLtrYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 104 of 125 Report ID, AB24838
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG38628
LCS LCS38628:l
NITRATE NITROGEN (AS N)
SULFATE
5.00
25. 00
4.75
25.22
Matrix GW/ChemW
Prep Method
Analtyical Method: SW946 9056
mg/1
mg/1
95
101
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I fax [phone]
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D1\VIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 105 of 125 Report ID: AB24838
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup, WG38628 Matrix GW/ChemW
LCS LCS38628:3 Prep Method
Analtyical Method: SW846 9056
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
Di\YIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 199
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 106 of 125 Report ID: AB24838
QC Batch Report -Batch Sample List
WorkGroup WG38638 Matrix GW/ChemW
Description: IC RUN GW Prep Method
Analtyical Method: SW846 9056
PREP ANALYTICAL
SaDlplo ID Client ID R=# Date Time Date Time Analyst
L04081304-03 IT-SR 1 08/13/2004 1333 DHR
MB386JB: 1 Method Blank 1 08/13/2004 1138 DHR
LCS38638: 1 Laboratory Control Spike 08/13/2004 1022 DHR
MS04081304-03 :38638 Matrix Spike 1 08/13/2004 1350 DHR
MSD04081304-03:38638 Matrix Spike Duplicate 1 08/13/2004 1406 DHR
Dilution
1 . 05
1.05
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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Di\VIS
FLfWD LABORATORY ANALYSIS REPORT
Client
contact
TI:CONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pern Carter
QC Batch Report -Method Blanks
Parameter
Wet Chemistry
SW846 9056
WorkGroup: WG38638
Blank MB38638:1
NITRATE NITROGEN {AS N)
Result Qual
0.10
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 107 of 125 Report ID: AB24839
Matrix: GW/ChemW
RDL Units Analyst Date Time
0.10 mg/1 DHR 08/13/2004 1138
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Fem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 108 of 125
September 11, 2004
Report ID: AB24838
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG38638 Matrix GW/ChemW
MS/MSD MS04081304-03:38638 Prep Method
MSD04081304-03:38638 Analtyical Method: SW846 9056
NITRATE NITROGEN (AS N) 5.25 < 0 .100 5.02 mg/1 96 80-115
NITRATE NITROGEN (AS NJ 5.25 5.04 96 0 10 80-115
NOTE: MS/MSO % recoveries are not evaluated if the sample concentration is greater than four fimes the spike added.
Davis & Floyd, Inc. J PO Drawer 428 J Greenwood, SC 29648 J 816 E. Durst Avenue J Greenwood, SC 29649 J [phone] I Fax [phone]
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Dl\VIS
FLtn'D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number, 61621.01
Report Date September 11, 2004
Page 109 of 125 Report ID: AB24B38
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG38638 Matrix GW/Chemw
LCS LCS38638:l Prep Method
Analtyical Method: SW846 9056
NITRATE NITROGEN (AS N) 5.00
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
DAYIS
FLtrfD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
NC Cenijication Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 110 of 125 Report ID: AB24838
QC Batch Report -Batch Sample List
workGroup WG38679 Matrix GW/Chernw
Description: IC RUN GW Prep Method
Analtyical Method: SW846 9056
PREP ANALYTICAL
Sample ID Client ID Run# Date Time Date Time Analyst
L04081704-0l ·IT-9 1 08/17/2004 2014 DHR
L04081704-02 V-23 1 08/17/2004 2047 OHR
l,04081704-03 V-65 08/17/2004 2121 OHR
L04081704-04 DUP-3 1 08/17/2004 2154 DHR
MB38679: 1 Method Blank 08/17/2004 1354 OHR
MB38679:2 Method Blank 1 OB/18/2004 1612 DHR
LCS38679:l Laboratory Control Spike 08/17/2004 1300 OHR
LCS38679:2 Laboratory Control Spike 08/18/2004 1556 OHR
MS04081703-l0; 38679 Matrix Spike 1 08/17/2004. 1819 DHR
MS04081703-10:38679 Matrix Spike 2 08/18/2004 1629 OHR
MS04081703-ll:38679 Matrix Spike 08/17/2004 1908 DHR
MS04081703-ll:38679 Matrix Spike 2 08/18/2004 1702 OHR
MSD04081703-10: 38679 Matrix Spike Duplicate 1 08/17/2004 1835 OHR
MSD04081703-10: 38679 Matrix Spike Duplicate 2 08/18/2004 1646 OHR
MSD04081703-ll :38679 Matrix Spike Duplicate 1 08/17/2004 1925 OHR
MSD04081703-ll: 38679 Matrix Spike Duplicate 2 08/18/2004 1719 OHR
Dilution
1
1. 05
1. 05
. OS
.OS
.05
1. 05
1.05
1.05
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] · I fax [phone]
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Di\YIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC
Pem Carter
28152
QC Batch Report -Method Blanks
Parameter
Wet Chemistry
SW846 9056
WorkGroup: WG38679
Blank MB38679:l
NITRATE NITROGEN (AS NJ
NITRITE NITROGEN (AS N)
SULFATE
Result
0.10
0.10
0.50
Qual
NC Certificarion Number: 25
Project Number: 61621.01
Report Date
Page 111 of 125
Matrix: GW/ChemW
RDL Units
0.10
0.10
0.50
mg/1
mg/1
rng/1
September 11, 2004
Report ID: AB2483B
Analyst
OHR
OHR
OHR
Date Time
08/17/2004 1354
08/17/2004 1354
08/17/2004 1354
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
D1\VIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
QC Batch Report -Method Blanks
WorkGroup: WG38679
Parameter
Wet Chemistry
SWS46 9056
Blank
NITRATE NITROGEN (AS N)
NITRITE NITROGEN (AS N}
MB38679:2
<
<
Result Qual
0.10
0.10
NC Certificmion Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 112 of 125 Report ID: AB24838
Matrix: GW/Chemw
RDL
0.10
0.10
Units
mg/1
mg/1
Analyst
DHR
DHR
Date Time
OB/18/2004 1612
08/18/2004 1612
Davis & Floyd, Inc. I PO Drawer 428 J Greenwood, SC 29648 J 816 E. Durst Avenue J Greenwood, SC 29649 J [phone] I Fax [phone]
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Df\VIS
FLtJ\1D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC
Pem Carter
28152
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 113 of 125
September 11, 2004
Report ID; AB24838
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG38679
MS/MSD MS04081703-10:38679
NITRATE NITROGEN (AS N)
NITRITE NITROGEN (AS NJ
SULFATE
NITRATE NITROGEN (AS N)
NITRITE NITROGEN (AS N)
SULFATE
MSDO4O817O3-10:38679
5 25
5 25
5.25
5 . 25
5 25
5. 25
NOTE: MS/MSD • recoveries are not evaluated if the
Matrix GW/ChemW
Prep Method
Analtyical Method: SW846 9056
1.08
< Q.100
0. 840
6.06
4-92
6 56
6.06
4.94
6.52
mg/1
mg/1
mg/1
sample concentration is
mg/1
mg/1
mg/1
95
94
109
greater than
95
94
108
0
0
1
four times
80-115
80-114
74-135
10
10
10
80-115
80-114
74-135
the spike added.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
Df\VIS
FLtn'D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 114 of 125 Report ID: AB24838
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG38679
MS/MSD MS04081703-11:38679
NITRATE NITROGEN (AS N)
NITRITE NITROGEN {AS N)
SULFATE
NITRATE NITROGEN (AS NJ
NITRITE NITROGEN (AS N)
SULFATE
MSD04081703-11:38679
5 25
5.25
5.25
5.25
5. 25
5.25
0.460
< 0.100
0.620
5.36
4.95
6.81
Matrix GW/Chemw
Prep Method
Analtyical Method: SW846 9056
5 37
4. 95
6 49
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
93
94
118
94
94
112
0
0
5
80-llS
80-114
74-135
10
10
10
80-115
80-114
74-135
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
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DAYIS
FL6YD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 115 of 125 Report ID: AB24838
QC Batch Report -Laboratory Control Standards and Duplicates
workGroup: WG38679
LCS
NITRATE NITROGEN (AS N)
NITRITE NITROGEN (AS N)
SULFATE
LCS38679:l
5.00
5.00
25.00
4.84
4.74
25. 42
Matrix GW/ChemW
Prep Method
Analtyical Method: SW846 9056
mg/1
mg/1
mg/1
97
95
102
95-1 OS
95-105
95-105
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
D1\VIS
FLtJ\1D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cerrification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 116 of 125 Report ID: AB24838
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup, WG38679
LCS LCSJ8679:2
NITRATE NITROGEN (AS N)
NITRITE NITROGEN (AS N)
s.oo
s.oo
4.82
4.84
Matrix GW/Chemw
Prep Method
Analtyical Method: SW846 9056
mg/1
mg/1
96
97
95-105
95-105
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Av_enue I Greenwood, SC 29649 I [phone] I Fax [phone]l 19
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DAYIS
FLtiYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number, 61621.01
Report Date September 11, 2004
Page 117 of 125 Report ID: AB24838
QC Batch Report -Batch Sample List
WorkGroup WG387ll
Description, TOC GW
Sa.lllplO ID
L04081013 01
L04081013-02
L04081013-03
L04081013-04
L04081013-0S
L04081013-06
L04081201-01
L04081201-02
L04081201-03
L04081201-04
MB38711: 1
LCS38711: 1
MS04081201-02:38711
MSD04081201-02:38711
Client ID
Q-33
J-29
U-38
CC-33
DUP-1
W-23
N-29
0-25
K-28
TI-1
Method Blank
Laboratory Control Spike
Matrix Spike
Matrix Spike Duplicate
1
1
1
1
1
1
Matrix GW/Chemw
Prep Method
Analtyical Method: SW846 9060
PREP ANALYTICAL
Date Tl.llle Date Time Analyst
08/18/2004 1751 CBN
08/18/2004 1819 CBN
08/18/2004 1847 CBN
08/18/2004 1916 CBN
08/18/2004 1944 CBN
08/18/2004'2012 CBN
08/18/2004 2041 CBN
08/18/2004 2111 CBN
08/18/2004 2142 CBN
08/18/2004 2210 CBN
08/18/2004 2346 CBN
08/18/2004 2328 CBN
08/18/2004 2230 CBN
08/18/2004 2249 CBN
Dilution
1
1
1
50
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. D~rst Av.enue I Greenwood, SC 29649 I [phone] I Fax [phone]
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
QC Batch Report -Method Blanks
Parameter
Wet Chemistry
SW846 9060
WorkGroup: WG38711
Blank MB38711:1
ORGJ\NIC CARBON, TOTAL
Result Qual
1. 0
NC Certification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 118 of 125 Report ID: AB24838
Matrix, GW/Chemw
RDL Units Analyst Date Time
1.0 mg/1 CBN 09/18/2004 2346
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 j 816 E. Durst Av.enue I Greenwood, SC 29649 I [phone] j Fax [phone]
II
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Dl\_VIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number, 61621.01
Report Date September 11, 2004
Page 119 of 125 Report ID: AB2483S
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG38711 Matrix GW/ChemW
MS/MSD MS04081201-02:38711 Prep Method
MSD04081201-02:387ll Analtyical Method: SW846 9060
ORGANIC CARBON, TOTAL 20. 00 21.95 40. 60 mg/1 93 74 -125
ORGANIC CARBON, TOTAL 20. 00 42.10 101 4 11 74-125
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. I PO Drawer 428 / Greenwood, SC 29648 l 816 E. Durst Av.enue I Greenwood, SC 29649 / [phone] I Fax (864) 229~7119
DAYIS
FLfWD LABORATORY ANALYSIS REPORT
Client
contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC
Pem Carter
28152
NC Cenification Number: 25
Project Number: 61621.01
Report Date
Page 120 of 125
September 11, 2004
Report ID: AB24838
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG38711 Matrix GW/ChemW
LCS LCS38711:l Prep Method
Analtyical Method; SW846 9060
ORGANIC CARBON, TOTAL 25.00 23.10 mg/1 92 90-110
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
11
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Df\VIS
FLtJ\'D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
NC Cenification Number: 25
Project Number, 61621.01
Report Date September 11, 2004
Page 121 of 125 Report ID: AB24838
QC Batch Report -Batch Sample List
WorkGroup WG38734
Description: TOC GW
Sample ID
L04081201-05
L04081201-06
L04081201-07
L04081201-08
L04081201-09
L04081201-10
L04081201-11
L04081304-0l
L04081304-02
L04081304-03
L04081704-0l
L04081704-02
L04081704-03
L04081704-04
MB38734:l
MB38734:l
MB38734:l
LCS38734: 1
LCS38734:l
LCS3873-4: 1
MS04081201-09:38734
MS04081704-01:38734
MSD04081201-09:38734
MSD04081704-01:38734
Client ID
F-55
FB-01
IT-1
IT-2
IT-3
IT-4
IT-5
IT-6
IT-7
IT-SR
IT-9
V-23
V-65
DUP-3
Method Blank
Method Blank
Method Blank
Laboratory Control Spike
Laboratory Control Spike
Laboratory Control Spike
Matrix Spike
Matrix Spike
Matrix Spike Duplicate
Matrix Spike Duplicate
Run#
1
1
1
1
1
1
1
1
1
1
' 3
1
2
3
1
1
Matrix GW/ChemW
Prep Method
Analtyical Method: SW846 9060
PREP ANALYTICAL
Date Time Date Time Analyst
08/19/2004 1054 CBN
08/19/2004 1122 CBN
08/19/2004 1152 CBN
08/19/2004 1221 CBN
08/19/2004 1250 CBN
08/19/2004 1319 CBN
08/19/2004 1348 CBN
08/19/2004 1420 CBN
08/19/2004 1450 CBN
08/19/2004 1521 CBN
08/19/2004 1811 CBN
08/19/2004 1840 CBN
08/19/2004 1908 CBN
08/19/2004 1937 CBN
08/19/2004 1737 CBN
08/19/2004 2113 CBN
08/20/2004 0956 CBN
08/19/2004 1701 CBN
08/19/2004 2055 CBN
08/20/2004 0917 CBN
08/19/2004 1540 CBN
08/20/2004 0811 CBN
08/19/2004 1559 CBN
08/20/2004 0832 CBN
Dilution
100
1
25
10
1
1
1
100
50
20
250
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I fax [phone]
DAYIS
FLMD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
QC Batch Report-Method Blanks
WorkGroup: WG38734
Parameter
Wet Chemistry
SW846 9060
Blank
ORGANIC CARBON, TOTAL
ORGANIC CARBON, TOTAL
ORGANIC CARBON, TOTAL
MB387H: l
<
<
<
Result Qual
1.0
1.0
1. 0
NC Cenification Number: 25
Project Number: 61621.01
Report Date September 11, 2004
Page 122 of 125 Report ID: AB24838
Matrix: GW/ChemW
RDL
1. 0
1.0
1.0
units
mg/1
mg/1
mg/1
Analyst
CBN
CBN
CBN
Dato Time
08/20/2004 0956
08/19/2004 2113
08/19/2004 1737
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Av.enue I Greenwood, SC 29649 I [phone] I Fax [phone]
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Dl\VIS
FLtJ\'D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.0l
Report Date September 11, 2004
Page 123 of 125 Report ID: AB24838
QC Batch Report -Matrix Spikes and Duplicates
workGroup: WG38134 Matrix GW/ChemW
MS/MSD MS0408120l-09:38734 Prep Method
MSD04081201-09:38734 Analtyical Method: SW846 9060
ORGANIC CARBON, TOTAL 15.00 8.54 24.50
ORGANIC CARBON, TOTAL 15.00 25.70 mg/1 114 5 11 74-125
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
1)1\VIS
FLtJYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenijicalion Number: 25
Project Number: 61621.0l
Report Date September 11. 2004
Page 124 of 125 Report ID: AB24838
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG38734 Matrix GW/ChemW
MS/MSD MS04081704-01:38734 Prep Method
MSD04081704-0l:38734 Analtyical Method: SW846 9060
ORGANIC CARBON, TOTAL 20.00 83-95 103.4 mg/1 97 74-125
ORGANIC CARBON, TOTAL 20.00 103.0 95 0 11 74-125
NOTB: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
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II
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DAYIS
FLtlYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number, 61621.01
Report Date September 11, 2004
Page 125 of 125 Report ID: AB24838
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG38734
LCS
ORGANIC CARBON, TOTAL
ORGANIC CARBON, TOTAL
ORGANIC CARBON, TOTAL
LCS38734:l
25.00
25.00
25.00
24. 30
24 . 30
24.30
Matrix GW/ChemW
Prep Method
Analtyical Method: SW846 9060
mg/1
mg/1
mg/1.
98
93
97
90-110
90-110
90-110
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I fax [phone]
DAYIS
FLtn'D LABORATORY ANALYSIS REPORT
Method Conformance Summary
Client: Ticona, LLC
Log;n(s/ L0408 l 013, L04081201, L0408 I 304, L0408 I 704
Criteria Metals
Sample Holding Time
Standards Preoaration
Instrnment Tuning
Instmment Calibration
Calibration Verification
De2:radation Check
Interference
Sample/Standard
Blanks Results
Method Accuracy
Method Precision
Surrogate Recovery
PDSISD/MSA
TCLP Prenaration
✓
NIA
Met Criteria Met
Not Applicable
✓
✓
✓
✓
✓
NIA
✓
✓
✓
✓
NA
NIA
NIA
Alkalinity
✓
✓
NIA
✓
✓
NIA
NIA
✓
NA
✓
NA
NIA
NIA
Sulfide
✓
✓
NIA
✓
✓
NIA
NIA
✓
✓
✓
NIA
NIA
NIA
*
PDS =
SD =
MSA=
Method Criteria Not Met -Seefoot1101e(s) below.
Posl Digestion Spike
Serial Dilution
Method of Standard Additions
Footnotes:
Project Number: 61621.01
Report Date: September 14, 2004
Nitrate TOC
✓ ✓
✓ ✓
✓ NA
✓ ✓
✓ ✓
NIA NA
NIA NA
✓ ✓
✓ ✓
✓ ✓
NIA NA
NIA NA
NIA NA
I ' . I -
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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Di\YIS
FLtwD LABORATORY ANALYSIS REPORT
Method Conformance Summary
Client: Ticona, LLC
Login(s): L0408! 013, L0408!201, L0408 I 304, L04081704
Criteria Sulfate
Sample Holding Time
Standards Preparation
Instrument Tunin2:
Instrument Calibration
Calibration Verification
DePradation Check
Interference
SamolelStandard
Blanks Results
Method Accuracy
Method Precision
SurroPate Recoverv
PDSISDIMSA
TCLP Prenaration
✓
NIA
Met Criteria Met
Not Applicable
✓
✓
NIA
✓
✓
NIA
✓
✓
✓
✓
NIA
NIA
NIA
Ethylene
Glvcol
✓
✓
NIA
✓
✓
NIA
NIA
✓
✓
✓
NIA
NIA
NIA
*
PDS =
SD =
MSA=
Method Criteria Not Met -See footnote(,) below.
Post Digestion Spike
Serial Dilution
Method of Standard Additions
Project Number: 61621.01
Report Date: September 13, 2004
Footnotes: Ethylene Glycol -Possible carryover contamination in FB-01 due to analysis of high
concentration sample immediately before analysis ofFB-01. (Revised 1/18105)
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] j Fax [phone]
Explanation of Symbols and Abbreviations
The following defines common symbols and abbreviations used in reporting technical data:
RDL Report Detection Limit MDL Method Detection Limit
TOP Top of Pipe MSL Mean Sea Level
TNTC Too Numerous To Count MPN Most Probable Number
BTU British Thermal Units NTU Nephelometric Turbidity Units
C Degrees Centigrade F Degrees Fahrenheit
umhos/cm micromhos/cm meq milliequivalents
kg kilogram(s) g gram(s)
mg milligram(s) ug microgram(s)
I liter(s) ml milliliters(s)
ul microliter(s) m3 cubic meter(s)
lb pound(s) ft3 cubic foot(feet)
ft foot(feet) TIC Tentatively Identified Compounds
mg/I, mg/kg Units of concentration in milligrams per liter for liquids and milligrams per kilogram for solids. Also
referred to as Parts Per Million or "ppm" when the assumption is made that the specific gravity or
density is one (1 g/ml).
ug/1, ug/kg Units of concentration in micrograms per liter for liquids and micrograms per kilograms for solids.
Also referred to as Parts Per Billion or "ppb" when the assumption is made that the specific gravity
or density is one (1 g/ml).
wt%
<
>
Units of concentration expressed on a weight/weight basis (e.g. grams per 100 grams).
Less Than -The number following the sign is the limit of quantitation, the smallest amount of
analyte that can be reliably determined using this test.
Greater Than
Data Qualifiers:
A
B
C
E
J
p
X
•
TIC is a possible aldol-condensation product resulting from sample extraction, (Organics)
Analyte also detected in the method blank.
Amendable Cyanide is a negative value due to an unknown interference.
Estimated concentration due to interference.
Estimated value below RDL or estimated value for TIC. (Organics)
Concentration difference between primary and confirmation columns >25%. (Organics) The lower result is
reported.
Matrix interference which requires dilution or prevents the reporting of a result. Detection limits have been
adjusted where applicable.
Defined in report comments .
Solid samples (i.e. soil, sludge, and solid waste) are reported on a dry weight basis unless otherwise noted.
Test results relate only to the sample tested. Clients should be aware that a critical step in a chemical or biological
analysis is the collection of the sample. Unless the sample analyzed is truly representative of the bulk of the material
involved, the test results will be meaningless. If you have any questions regarding the proper techniques of collecting
samples, please contact us. However, we cannot be held responsible for sample integrity unless sampling has been
performed by a member of our staff.
REPRESENTATION AND LIMITATION OF LIABILITY The accuracy of all analytical results for samples begins as
it is received by the laboratory. Integrity of the sample begins at the time it is placed in the possession of authorized
Davis & Floyd, Inc. Laboratories personnel. All other warranties, expressed or implied, are disclaimed. Liability is
limited to the cost of the analysis.
Davis & Floyd. Inc.
AD07_02 (09/04)
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------------Chain of Custody Record Page -j_ of j_ CUen/ Project I Site Location 816 E. Durst Avenue, Greenwood, SC 29649 [phone] Fax: [phone] ,ca use vn,y Kubal-Furr & Associates 61621.01 Laboratory Certifcatlon Numbers: SC• 24110, NC-25, TN-2923, VA-77 Simpsonville,SC CNA Ticona -Shelby, NC Contact Report To ..I';,,t,jU','hl,,,;l"'C Copy To Reporting Requirements: [ J Standard {} Data Package (Specify Lave/) Pun;;hase Order Greg Kinsman ..::r-1 ..... rv?J.-Jcr.,1,, ...re ?&<f{)f,qz,!.-,/c~A-t,Pt,--,, ..zz:::_, CollectedBy &~· f::,,<>rl<fr,j ~ Required Parameters, Containers and Preservatives ~ Quote f:A-r'-t I
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Coo~able):
On r Ye o Temp(C) 11
Custody Seal; Intact I Broken G..J Matnx Type Defintbons 1 -Drinking Water 2 -Clean Water 5 • Groundwater 7 • Soll/Sediment B • Liquid Sludi;ie 9 • Od 12 • Air
Davis & Floyd, Inc.
PreseNative Definltions A -None B -H2S04 C • HCJ O -HN03 E • NaOH F • Filtered G • Other
FL0'2_01 (02199)
D~IS ""'"'"' . ""'"""" FL YD IJrir,m•lll<Laixnur!!,,rlCPJ
--
Chain of Custody Record Pagej_of / Client Project I Sile Location 816 E. Durst Avenue, Greenwood, SC 29649 {864) 229-4413 Fax: [phone] ice vse vniy Kubal-Furr & Associates 61621.01 LaboratoryCertifcation Numbers: SC-24110, NC-25, TN-2923, VA· i7 Simpsonville,SC CNA Ticona -Shelby, NC Contact Report To Copy To Reporting Requirements: [ J Standard {} Data Package (Specify Level) Purchase Order Greg Kinsman ::J/)1. fl&-J:::n.4-fi.,4ZJ:,:,,,=,:" Jc ti:."1 Dfe.77--"?. -77c,,.</.+ c6/e2-ZZ:: Collected By ~,;, fc;,v,J" ,.<,./PJ Required Parameters, Containers and PraseNatives State Quote b'.,(:x f:'"1-ry JZ1itf-AJS
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...J Samole Description Date Time Time Type Total -FracUon HOT vomments IJ~:19 i/,./4y 1'(30 K s-J2 X X' X X X )"." 01 .5,a~ 0 --:)::;-?/,o/, '{ /&x> X --5'" <{-X y )( y IC X Ori aJ"4fl-"' ,2 ldA-5? r:-') g, , <')bl, , 'lb ,IL 19/~ :x-,S J:-)( y X )( K Iv (}3 TI-I .r-/,/4~ 09tfo X ,,,;-II' y y 'I }( y )( ()LL 'F-s S" ~;/,( 13k X r ,f-')( V X: I/ ;,( y OS rB-o I J>/11/4~ ~ f 2 cf" )C '( )( y X. >( ()I.,, .:i::, -I ,gh/;;,r lo;lo x \) <f' x )( K' y X: 'f-07 .:rT-'J ?)t/c'( ;;;J),o X s-,p. X X y K K ){ Op Pl'.l:ASr-~~-,._,,-,, ,,.,. --5 J. I -lr/;;/,>'{ t~aS )( s-,f' y x )( X )( X OQ n:"'o,s, U/4-1~~"'-'i"J ...L• -'I 'tj;; /,,,J (J;i:, )( 0 ,:f--)( y:, X X: X ;<. 10 'ptf"i'?L./F -?£t'l'fi,U(; ) r /-'" -s-<f"/4/o'-t l</t(o x ,5 p )( X )( X -y:-X JI ,t,.11r-!lt"1]F'&,?fL~ d -v, -
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-
R 17; oY . i. Date nme eceived By Date Time Received in Laboratory By Date Time If Y, specify: Airbill Number J / ,4n,,,,/ _-.=-~;.lu; l_s-"'.1/-'; Ifs It. £. ht &(,pj P.n fit 07!iJ. _c:::days
,~
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Cooler ID (if available):
On l~o Temp(C) _J__;:,,__L.
Custody SeaJ: Intact f Broken {None) Matrix Type DefiniUons 1 -Drinking Water 2 -Clean Water 5 -Groundwater 7 • SoiVSediment 8 • Liquid Sludge 9 -Oil 12-Alr Davis & F1c,yrr; me. Preservative DefinlUons A-None 8 -H2S04 C • HCI D • HN03 E. NaOH F. Altered G • Other
FL02_01 (0vY9) ------------------

-
------------Client
Kubal•Furr & Associates
Simpsonville,SC
Contact
Project I Site Location
61621.01
CNA Ticona -Shelby, NC
Report To
Chain of Custody Record
816 E. Durst Avenue, Greenwood, SC 29649 {864) 229-4413 Fax: [phone]
Laboratory Certifcation Numbers: SC-24110, NC -25, TN-2923, VA -77
Copy To Reporting Requirements: [ J Standard [19 Data Package (Specify Level) g Kinsman Lt;Vt..:Z... IC ,]7,,.i h/,1/L -F", 'h« C,t-,l7e'Z., -°J/&YtJ.I.
Page __ /_ of __
ice use vn,y
urchase OrrJer
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NOTICE:'
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J-T-b
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Sample Collection
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Matrix Type Definitions 1 -Drinking Water 2 Clean Water 5 Groundwater 7 Soll/Sediment B Liquid Sludge 9 011 12 Air Preservative Oeflnlllons A -None 8 • H2S04 C • HCI D • HN03 E • NaOH F • Filtered G • Other
Time
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l--days
CoolerlD~able); ____ _
On/ee: ~o Temp(C)~
Custody Seal: Intact / Broken /~
Davis & Floyd, Inc.
FL02 _01 (02199)
----
Chain of Custody Record Page l of I Client Project I Site Location 816 E. Durst Avenue, Greenwood, SC 29649 [phone] Fax: [phone] ice use uniy Kubal-Furr & Associates 61621.01 Laboratory Certifcalion Numbers: SC-24110, NC-25, TN-2']23, VA -77 Simpsonviile,SC CNA Ticona -Shelby, NC Contact Report To Copy To Reporting Requirements: [} Standard [ J Data Package (Specify Level) Purchase Order Greg.Kinsman :::r;~ fv:U-/C/-r,r.li~,_,~:,.r .... :J'<_.:,<f =/6,c, _ k'c ,,.;,L Lc-VC--'L JC. Collected By
Required Parameters, Containers and Preservatives Sta/8(.tf'I::. Quote bzc-&-/:JJJS,l,(,f-0 ,.,,,
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Custody Seal: intact / Broken ~ Matrix Type Deflnitions 1 -Dnnking Waler 2 -Clean Water 5 -Groundwa\er 7 -So!l/Sed1ment 8-liquid Sludge 9 -011 12 -Air Dav,s & Floyd, Inc.
Preservative Definitions A -None 8 -H2S04 C • HCJ D -HN03 E -NaOH F -Filtered G -Other
FL02_01 (02199) ------------------
MICROSEEPS::=== ; : ; : : : ; : : ; : : : : • : : : ; : ; : : • : : : : : • : ; : : : : .. -:;•.:•o • • • • • • • • • • • • • • • • • • • • • ••••••••••••••• • ••• 0 :::::::::::: :::::: :: :::::::::::::::: ~. eeeooeooeeoo eooeeo •• ••••••••••••••oo
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Client Name: Davis & Floyd Page: Page 1 of?
P0408232
08125104
61621_01
61621_01
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Lab Sample# Client Sample ID I P0408232-01 L04081013-01 Q-33
P0408232-02 L04081013-02 J-29
P0408232-03
I P0408232-04
P0408232-05
P0408232-06
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L04081013-03 U-38
L04081013-04 CC-33
L04081013-05 DUP-1
L04081013-06 W-23
Lab Proj #:
Report Date:
Client Proj Name:
Client Proj #:
Laboratory Results C
Total pages in data package: -~~---
IMicroseeps test results meet all the rcquireme ts oft e,N0,1-4''\?Standards.
Approved By:
I The analytical results reported here are reliable and usable to the precision expressed in this report. As required by some regulating authorities, a full discussion of the uncertainty in our analytical results can be obtained at our web site or through customer service. Unless otherwise specified, all results
I As a valued client we would appreciate your comments on our service.
Please call customer servce at [phone] or email [e-mail]
Case Narrative:
I
I
I 220 William Pitt Way, Pittsburgh, PA 15238 • Phone [phone], Fax [phone]
)/
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'c:ife11
Da·,is & Floyd, Inc.
Gn1enwood, SC 29649
Con/act
John H. McCord, Jr.
Col/ !Cled By
Tis 3 S. McCall
NOTICE:
Same le Oescriotion
Lo,.os1013.01 0-33
Lo,.os1013.02 J-29
LO, 081013-03 U-38
LQt.081013-04 CC-33
Lo,.os1013-os DUP-1
Lo, 081012>-06 W-23
f--
f--
-
--
f--
Project I Site Location
61621 01
Report To
John H. McCord, Jr.
:;; ~ 0 ,[ 0
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11" •• Samole Collection ~~~
Date Time Time
9-Auc 16:15
9-Auc 17:30
9-Auc 17:55
10-Auc 8:55
10-Auo 0:00
10-Auq 13:00
Chain of Custody Record
816 E. Durst Avenue. Greenwood, SC 29649 [phone] Fax: [phone]
Laboratory Certifcation Numbers: SC· 24110, NC-25, TN-2923, VA-77
Copy To Reporting Requirements: f)fJ Standard { J Data Package (Specify Level)
NA
Atmospheric Conditions Required Parameters, Containers and Preser.-atives
_j "" ~<
ro ·ona oO •>
" g ·a c "' 0 w u "' .. 0 < ·a; " 0 0 ' 0. X ~ ~ E ~ ·o E " 0 e lj , w u " z 0. Tvpe Total
X 5 2 2
-X 5 2 2
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X 5 2 2
X 5 2 2
X 5 2 2
: -
E~·"· Date Time Reliquished By Date Time Reliquished By Dale Time ·.5~5. tnxWI p /7,.f)t I ,c/),-,
/> .. :ived By Date Time V"eceNed By Oafe Time i~:?1-Jd":;f J!cifK 511.''V, // Time
;3. "~ Jo;o
THANE & CO2 ONLY.
Em,nt,
Mat1 ,x Type Definillons
Pret ervn\ive Definitions
-
1 Dnn!ong Water 2 -Clean Water 5. Groundwater 7. SoiVSed1ment 8 -L1qu1d Sludge g -011 12 • Air A -None B · H2S04 C -HCI D · HN03 E -NaOH F -Filtered G -Other
-------------
Page 1 of 1
/Ce LSe UnlY
urrhase Order
State Quote
NC
I.QC In Special Jnstroctions
~ ~~ 0 • 0 N ~ . ,._~
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\on lee: @No· Temp(C) ___
rustody Seal: Intact I Brok:en / None
Davis & Floyd, Inc.
FL02_01 (02199) ----
I
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I Client Name: Davis & Floyd
Contact: John McCord
I Address:
Sample Description
04081013-01 Q-33
RiskAnalysis
I Carbon dioxide
Methane
I
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I
1-NELAC certified analysis
I
816 E. Durst Avenue
Greenwood, SC 29649
Matrix
Water
Result
110
1.4
PQL
0,60
0.015
Page:
Lab Proj #:
Report Date:
Client Proj Name:
Cli,ent Proj #:
Page 2 of?
P0408232
08/25/04
61621_01
61621_01
Lab Sample #: P0408232-01
Sampled Datemme Received
09 Aug. 04 16:15 13 Aug. 04
Units Method# Anal
mg/L AM20GAX as 8/24/04
ug/L AM20GAX as 8/24/04
Client Name:. Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Sam12le Descri12tion ~atrix· · ...... " :'
L04081013-02 J-29 Water
Analyte(s) Result
RiskAnalysis
Carbon dioxide 240
Methane 2.8
ti-NELAC certified analysis
PQL
0.60
0.015
Page:
Lab Proj #:
Report Date:
Client Proj Name:
Cli,ent Proj #:
Page 3 of7
P0408232
08/25/04
61621_01
61621_01
P0408232-02
Sam12led DatefTime Received
09 Aug. 04 17:30 13 Aug. 04
Units Method# Analyst Analysis Date
mg/L AM20GAX as 8/24/04
ug/L AM20GAX as 8/24/04
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Client Name:. Davis & Floyd
Contact: John McCord
I Address· 816 E. Durst Avenue
. . · Greenwood, SCM29649
Sample Description atnx
L04081013-03 U-38 Water
RiskAnalysis
I Carbon dioxide
Methane
I
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I
I
I
I
I
I
I
I
,-NELAC certified analysis
I
81
0.49
PQL
0.60
0.015
Page:
Lab Proj #:
Report Date:
Client Proj Name:
Client Proj #:
Page 4 of?
P0408232
08/25/04
61621_01
61621_01
Lab Sample#: P0408232-03
Sampled Date!Time Received
09 Aug. 04 17:55 13Aug. 04
Units Method#
mg/L AM20GAX as 8/24/04
ug/L AM20GAX as 8/24/04
Client Name:. Davis & Floyd
Contact: John McCord
Address: 816 E, Durst Avenue
Greenwood, SC 29649
Sam~le Descri~tion · .. : , Matrix
L04081013-04 CC-33 Water
Analyte(s) Result
RiskAnalysis
Carbon dioxide 95
Methane 550
li_-NELAC certified analysis
PQL
0.60
0.015
Page:
Lab Proj #:
Report Date:
Client Proj Name:
Cli,ent Proj #:
Page 5 of 7
P0408232
08/25/04
61621_01
61621_01
Lab Sample #: P0408232-04
Sam~led ti'~ie/Time Received
10 Aug. 04 8:55 13Aug. 04
Units Method# Analyst Analysis Date
mg/L AM20GAX as 8/24/04
ug/L AM20GAX as 8/24/04
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1:
!
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Client Name:. Davis & Floyd
Contact: John McCord
~ Address: 816 E. Durst Avenue
Greenwood, SC 29649
ample Description Matrix
04081013-05 DUP-1 Water
RiskAnalysis
I Carbon dioxide
Methan~
I
I
I
I
I
I
I
I
I
I
I
1· NELAC certified analysis
I
Result
82
660
PQL
0.60
0.015
Page:
Lab Proj#:
Report Date:
Client Proj Name:
Cli,ent Proj #:
Page 6 of7
P0408232
08/25/04
61621_01
61621_01
Lab Sample #: P0408232-05
Sampled Datemme Received
10 Aug. 04 0:00 13 Aug. 04
Units Method#
mg/L AM20GAX as 8/24/04
ug/L AM20GAX as 8/24/04
Client Name: . Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Samgle Descri12tion ·Matrix-···-· ' · ·-· .
L04081013-06 W-23 Water
Analyte(s) Result
RiskAnalysis
Carbon dioxide 97
Methane 6.9
N: NfiLAC certified analysis
PQL
0.60
0.015
Page:
Lab Proj #:
Report Date:
Client Proj Name:
Cli~nt Proj #:
Page 7 of?
P0408232
08/25/04
61621_01
61621_01
Lab Sample #: P0408232-06
Sam12led Datemme Received
10 Aug. 04 13:00 13 Aug. 04
Units Method# Analyst Analysis Date
mg/L AM20GAX as 8/24/04
ug/L AM20GAX as 8/24/04
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Client Name: Davis & Floyd
John McCord Contact:
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Lab Sample# Client Sample ID
I
P0408233-01 L04081201-01 N-29
P0408233-02 L04081201-02 0-25
P0408233-03
I P0408233-04
P0408233-05
P0408233-06
IP0408233-07
P0408233-08
P0408233-09
P0408233-10
r0408233-11
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I
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I
L04081201-03 K-28
L04081201-04 Tl-1
L04081201-05 F-55
L04081201-06 FB-01
L04081201-07 IT-1
L04081201-08 IT-2
L04081201-09 IT-3
L04081201-10 IT-4
L04081201-11 IT-5
IMicroseeps test results meet all the requirements of
Approved By:
Page: Page 1 of 12
Lab Proj #: P0408233
Report Date: 08/25/04
Client Proj Name: .... 61621_01
Client Proj #: 61621_01
Laboratory Results
Total pages in data package: _..JsL_j"---
I The analytical results reported here are reliable and usable to the precision expressed in this report. As required by some regulating authorities, a full iscussion of the uncertainty in our analytical results can be obtained at our web site or through customer service. Unless otherwise specified. all results
• Case Narrative:
As a valued client we would appreciate your comments on our service . Please call customer servce at [phone] or email [e-mail]
I
I
I 220 William Pitt Way, Pittsburgh, PA 15238 • Phone [phone], Fax [phone]
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Gmenwood, SC 29649
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John H. McCord, Jr.
Co/,ected By
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Project I Site Location
61621 01
Report To
John H. McCord, Jr.
Chain of Custody Record Page1of1
816 E. Durst Avenue. Greenwood, SC 29649 [phone] Fax: [phone] ice use ,n,y Laboratory Certifca/ion Numbers: SC-24110, NC -25. TN -2923, VA -77
Copy To Reporting Requirements:/)() Standard { J Data Package (Specify Level) IPurr;;hase Order NA
Atmospheric Conditions Required Parameters, Containers and Preservatives State Quote
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L0,!081201-01 N-29 10-Aua 14:30 X 5 2 2
L0,1081201-02 0-25 10-Auc 16:00 X 5 2 2
L0,:081201-03 K-28 10-Auc 19:15 X 5 2 2
L0,,081201-04 Tl-1 11-Auc 9:40 X 5 2 2
L0•:081201-05 F-55 11-Aua 13:20 X 5 2 2 ~
~,081201-06 FB-01 11-Auc 8:35 X 5 2 2
L0,:081201-07 IT-1 11-Aua 10:20 X 5 2 2 -L0,_.081201-08 /T-2 11-Auc 12:20 X 5 2 2 ~
~,081201-09 IT-3 11-Auc 15:05 X 5 2 2
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L0•081201-11 IT-5 11-Aua 14:40 X 5 2 2 -
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Date
Time
150n
Time Received By Date
Reliquished By Dale Time
Time E~~;~E & CO2 ONLY
/,t,-'.11)( Typ,.-, Def1n,tIons
Pre: ~rvolive Definitions
1 Dnoklng Waler 2 Clean Water 5-Groundwater 7 -S01!/Sed1ment 8 • L1qt.:1d Sludge 9-011 12 -Air A-None 8 -H2SO4 C -HCI D -HNO3 E -NaOH F -Filtered G -Other
-------

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Reliquished By
---
Date Time
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On Ice: Yes No · Temp(C) __ _
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Davis & Floyd, Inc.
FL02 _01 (02199)
------
I
I
I Client Name:. Davis & Floyd
Contact: John McCord
I Address: 816 E. Durst Avenue
Greenwood, SC 29649
Sample Description
04081201-01 N-29
nal te s
RiskAnalysis I ~:;~~~:ioxide
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1¥ NELAC certified analysis
I
Matrix
Water
Result
110
470
PQL
0.60
0.015
Page:
Lab Proj #:
Report Date:
Client Proj Name:
Cli,ent Proj #:
Page 2 of 12
P0408233
08/25/04
61621_01
61621_01
Lab Saml)le #: P0408233-01
Sampled Date/Time Received·
10 Aug. 04 14:30 13 Aug. 04
Units Method#
mg/L AM20GAX as 8/24/04
ug/L AM20GAX as 8/24/04
Client Name:. Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Sample Description•· · • ··,
'L04081201-02 0-25
Analyte(s)
RiskAnalysis
Carbon dioxide
Methane
,ti-NELAC certified analysis
.. ,.••Matrix · "
Water
Result
42
1100
PQL
0.60
0.015
Page:
Lab Proj #:
Report Date:
Client Proj Name:
Cli~nt Proj #:
Page 3 of 12
P0408233
08/25/04
61621_01
61621_01
Lab Sample #: P0408233-02
Sampled Daterrime Received
10 Aug. 04 16:00 13Aug.04
Units Method# Analyst Analysis Date
mg/L AM20GAX as 8/24/04
ug/L AM20GAX as 8/24/04
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Contact: John McCord
I Address:
Sample Description
04081201-03 K-28
RiskAnalJ1sis
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I
Carbon dioxide
Methane
I NELAC certified analysis
I
816 E. Durst Avenue
Greenwood, SC 29649
Matrix
Water
Result
160
12000
PQL
0.60
0.015
Page:
Lab Proj #:
Report Date:
Client Proj Name:
Clii)nt Proj #:
Page 4 of 12
P0408233
08/25/04
61621 01
61621_01
Lab SamJ)le #: P0408233-03
Sampled Date/Time Received
10Aug.04 19:15 13Aug. 04
Units Method#
mg/L AM20GAX as 8/24/04
ug/L AM20GAX as 8/24/04
Client Name:. Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
SamQle DescriQtiOn Matrix
L04081201-04 Tl-1 Water
Analyte(s) Result
RiskAnalysis
Carbon dioxide 98
Methane 11
1i ~ NELAC certified analysis
PQL
0.60
0.015
Page:
Lab Proj #:
Report Date:
Client Proj Name:
Clijclnt Proj #:
Page 5 of 12
P0408233
08/25/04
61621_01
61621_01
Lab Sam~le #: P0408233-04
SamQled Date/Time Received
11 Aug. 04 9:40 13 Aug. 04
Units Method# Analyst Analysis Date
mg/L AM20GAX as 8/24/04
ug/L AM20GAX as 8/24/04
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I Client Name: . Davis & Floyd
Contact: John McCord
'
Address: 816 E. Durst Avenue
Greenwood, SC 29649
ample Description Matrix.
04081201-05 F-55 Water
RiskAnalysis
I Carbon dioxide
Methane
I
I
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I
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I
I
I
I
1· NELAC certified analysis
I
Result
67
2600
PQL
0.60
0.015
Page:
Lab Proj #:
Report Date:
Client Proj Name:
Cli~nt Proj #:
Page 6 of 12
P0408233
08/25/04
61621_01
61621_01
Lab Sample#: P0408233-05
Samgled Daterrime Received
11 Aug. 04 13:20 13 Aug. 04
Units Method#
mg/L AM20GAX as 8/24/04
ug/L AM20GAX as 8/24/04
Client Name:. Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Sam12le Descrii,tioh .' • Matrix
L04081201-06 FB-01 Water
Analyte(s) Result
RiskAnalysis
Carbon dioxide <0.60
Methane 5.3
ii-NELAC certified analysis
PQL
0.60
0.015
Page:
Lab Proj #:
Report Date:
Client Proj Name:
Cli,ent Proj #:
Page 7 of 12
P0408233
08/25/04
61621_01
61621_01
Lab Sam~le #: P0408233-06
Sami,led Dateffime Received
11 Aug.04 8:35 13 Aug. 04
Units Method# Analyst Analysis Date
mg/L AM20GAX as 8/24/04
ug/L AM20GAX as 8/24/04
II
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Client Name:. Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue l Greenwood, SC 29649
ample Description Matrix
L04081201-07 IT-1 Water
I Methane
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,-NELAC certified analysis
I
Result
190
11000
PQL
0.60
0.015
Page:
Lab Proj #:
Report Date:
Client Proj Name:
CHent Proj #:
Page 8 of 12
P0408233
08/25/04
61621_01
61621_01
Lab Sample #: P0408233-07
Sampled Date/Time Received
11 Aug. 04 10:20 13 Aug. 04
Units Method# Anal st Anal sis Date
mg/L AM20GAX as 8/24/04
ug/L AM20GAX as 8/24/04
Client Name: . Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Sample Description
L04081201-08 IT-2
Analyte(s)
RiskAnalysis
Carbon dioxide
Methane
Ii-NELAC certified analysis
Matrix.-.......... ··
Water
Result
370
5900
PQL
0.60
0.015
Page:
Lab Proj #:
Report Date:
Client Proj Name:
Cli!3nt Proj #:
Page 9 of 12
P0408233
08/25/04
61621_01
61621_01
Lab SamJ)le #: P0408233-08
Units
mg/L
ug/L
Sampled Date/Time
11 Aug. 04 12:20
Method#
AM20GAX
AM20GAX
Received
13Aug. 04
Analyst Analysis Date
as
as
8/24/04
8/24/04
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Client Name:
Contact: I Address:
"3ample Description
04081201-09 IT-3
RiskAnalysis
I Carbon dioxide
Methane
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I
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I
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I
,-NELAC certified analysis
I
Davis & Floyd
John McCord
816 E. Durst Avenue
Greenwood, SC 29649
Matrix
Water
Result
36
14000
PQL
0.60
0.015
Page:
Lab Proj #:
Report Date:
Client Proj Name:
Cli,ent Proj #:
Page 10 of 12
P0408233
08/25/04
61621_01
61621_01
Lab Sample #: P0408233-09
Sampled Date/Time Received
11 Aug. 04 15:05 13Aug.04
Units Method#
mg/L AM20GAX as 8/24/04
ug/L AM20GAX as 8/24/04
Client Name: _ Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Sample Description-··~·-·:· •
L04081201-10 IT-4
Analyte(s)
RiskAnalysis
Carbon dioxide
Methane
li_. NELAC certified analysis
-.... Matrix
Water
Result
18
19000
PQL
0.60
0.015
Page:
Lab Proj #:
Report Date:
Client Proj Name:
Cli~nt Proj #:
Page 11 o/12
P0408233
08/25/04
61621_01
61621_01
Lab Sample#: P0408233-10
Sam12fed Date/Time Received
11 Aug. 04 12:10 13 Aug. 04
Units Method# Analyst Analysis Date
mg/L AM20GAX as 8/24/04
ug/L AM20GAX as 8/24/04
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•• l I I I I I
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Client Name:. Davis & Floyd
Contact: John McCord
'
Address: 816 E, Durst Avenue
Greenwood, SC 29649
ample Description Matrix
04081201-11 IT-5 Water
RiskAnalysis
I Carbon dioxide
Methane
I
I
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I
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I
I
1· NELAC cenified analysis
I
Result
220
13000
PQL
0,60
0.015
Page:
Lab Proj #:
Report Date:
Client Proj Name:
Cli,ent Proj #:
Page 12 of 12
P0408233
08/25/04
61621_01
61621_01
Lab Sample #: P0408233-11
Sam11led Date/Time Received
11 Aug, 04 14:40 13 Aug, 04
Units Method#
mg/L AM20GAX as 8/24/04
ug/L AM20GAX as 8/24/04
.................. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . •••••••••o•••••••• •••••••••••••••••• oeooeoeeooeoe$oeee
Client Name·: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
. ... •••• •••• aeeo
Page:
Lab Proj #:
Report Date:
Client Proj Name:
Client Proj #:
Page 1 of 4
P0408342
08/31/04
61621_01
61621_01
Laboratory Results Lab Sample# Client Sample ID
P0408342-01
P0408342-02
P0408342-03
L04081304-01 IT-6
L04081304-02 IT-7
L04081304-03 IT-BR
Microseeps test results meet al t requirements oce NELAC
Approved By: {,
Total pages in data package: 5
nd usable to the precision expressed in this report. As required by some regulating authorities, a full discussion of the uncertainty in our analytical results can be obtained at our web site or through customer service. Unless otherwise specified, all results
As a valued client we would appreciate your comments on our service.
Please call customer servce at [phone] or email [e-mail]
Case Narrative:
220 William Pitt Way, Pittsburgh, PA 15238 • Phone [phone], Fax [phone]
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Contact:
I Address:
Sample Description
04081304-01 IT-6
RiskAnalysis
I Carbon dioxide
Methane
I
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I
I
I
I
I
I
I
I
t· NELAC certified analysis
I
John McCord
816 E. Durst Avenue
Greenwood, SC 29649
Matrix
Water
Result
250
9000
PQL
0.6
0.015
Page:
Lab Proj #:
Report Date:
Client Proj Name:
Cljent Proj #:
Page 2 of4
P0408342
08/31/04
61621_01
61621_01
Lab Sample #: P0408342-01
Sampled Date/Time Received
11 Aug. 04 17:03 20 Aug. 04
Units Method# Anal st Anal sis Date
mg/L AM20GAX as 8/27/04
ug/L AM20GAX as 8/27/04
Client Name:. Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
SamQle DescriQtiow Matrix'
L04081304-02 IT-7 Water·
Analyte(s) Result
RiskAnalysis
Carbon dioxide 280
Methane 7900
tl· NELAC certified analysis
PQL
0.6
0.015
Page:
Lab Proj #:
Report Date:
Client Proj Name:
Cli,ent Proj #:
Page 3 of 4
P0408342
08/31/04
61621_01
61621_01
Lab Sample#: P0408342-02
SamQled ·Datefrime Received
11Aug.0417:10 20 Aug. 04
Units Method# Analyst Analysis Date
mg/L AM20GAX as 8/27/04
ug/L AM20GAX as 8/27/04
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Client Name:. Davis & Floyd
Contact: I Address:
'!,ample Description
04081304-03 IT-BR
RiskAnalysis
I Carbon dioxide
Methane
I
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I
I
I
I
I
I
I
I
I
1-NELAC certified analysis
I
John McCord
816 E. Durst Avenue
Greenwood, SC 29649
Matrix
Water
Result
160
13000
PQL
0.6
0.015
Page:
Lab Proj #:
Report Date:
Client Proj Name:
Cli,ent Proj #:
Page4 of4
P0408342
08/31/04
61621_01
61621 01
Lab Sample #: P0408342-03
Sampled Date/Time Received
11 Aug. 04 18:40 20 Aug. 04
Units Method# Anal
mg/L AM20GAX as 8/27/04
ug/L AM20GAX as 8/27/04
61
en,,
67
D~I S ''I'""''' Aniitft'.Ul'e
FL YD '"''"'"""' """"""' ...... Chain of Custody Record
Client Project/ Site Location 816 E. Durst Avenue, Greenwood. SC 29649 [phone] Fax: [phone] Davis & Floyd, Inc. Laboratory Certifcation Numbers: SC-24110, NC-25, TN-2923, VA-77 Greenwood, SC 29649 61621 01
Contact Report To Copy To Reporting Requirements: V' Standard { J Data Package (Specify Level) John H. McCord, Jr. John H. McCord, Jr. NA Collected By Atmospheric Conditions
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0 ·,i : * t 0 D -~ D E 0 ~ Samole Collection E :;: o 0 e ~ ' ~ :c ~ u ('J z C: Same le Descriotion Date Time Time Tvpe Total
L04081304-01 IT-6 11-Auc 17:03 X 5 2 2
L04081304-02 IT-7 11-Aua 17:10 X 5 2 2
L04081304-03 -IT-BR 11-Auc 18:40 X 5 2 2
'
ffi;;" 6 . h1..f-W { Date Time Reliquished By Date Time R.1q_ OJ/. 1500
Received By Date Time Received By Date Time
]Comments
... PERM GASES: METHANE AND CO2 ONL y• .. -
Matnx Type Defirullons
Preservative Definitions
1 -Dr1nk1ng Water 2 -Clean Water 5 -Groundwater 7. Soil/Sediment 8. UquId Sludge 9 -Oil 12. Air A -None 8 · H2S04 C -HCI D. HN03 E -NaOH F. Filtered G. Other
----------
Requi::ec! Parameters, Containers and PreseNatives
Reliquished By Date Time
Rreived in Labora1 By j;,) (!_ S[ c1,d/~--"
-zl,, Date Jt•(o'-1
Time
( 11"'1 <J
----

-
Page 1 of i
~
il::urchase Order
State IQuo,e
NC
1 or in Special fnstructio a ~~ 0 • O N ~ . ~~ Ob •• • u -. • 0 -'=! >< b • .J .e
Fraction HOT comments
Q"l~) Shipped By
y N ~ ' ' If Y, s y: Air~1ber
l(IH -days --
Cooler ID (if avai1<1ble):
On Ice: 8 No Temp(C) _
Custody Seal:
-
Intact I Broken ,
Davis & F1Jyd,
FL02_0I (02
--
. . . . . I I • a I ••••• ooooe
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Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Lab Sample# Client Sample ID I P0408341-01 L04081704-01 IT-9
P0408341-02 L04081704-02 V-23
P0408341-03 I P0408341-04
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L04081704-03 V-65
L04081704-04 DUP-3
I Microseeps test results meet
Approved By:
. ' .... . . . . . . . . . . . . I I I I I I •••••• oeoe•o
. .... ..... • •••• oo•••
Page: Page 1 of 5
Lab Proj #: P0408341
Report Date: 08/31 /04
-Client Proj Name:----61621_01
Client Proj #: 61621_01
Laboratory Results / _
Total pages in data package: __ Lt1 __ _
I The analytical results reported here are relia I and usable to the precision expressed in this report. As required by some regulating authorities, a full discussion of the uncertainty in our analytical results can be obtained at our web site or through customer service. Unless otherwise specified, all results
I Case Narrative:
As a valued client we would appreciate your comments on our service.
Please call customer servce at [phone] or email [e-mail]
I
I
I 220 William Pitt Way, Pittsburgh, PA 15238 • Phone [phone], Fax [phone]
Client Name:. Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Sam12le Descri12tion Matrix
L04081704-01 IT-9 Water
Analyte(s) Result
RiskAnalysis
Carbon dioxide 210
Methane 16000
ii.· NELAC certified analysis
PQL
0.6
0.015
Page:
Lab Proj #:
Report Date:
Client Proj Name:
Cli,ent Proj #:
Page 2 of 5
P0408341
08/31/04
61621_01
61621_01
Lab Sample #: P0408341-01
Sam12led Date/Time Received
16 Aug. 04 10:00 20 Aug. 04
Units Method# Analyst Analysis Date
mg/L AM20GAX as 8/27/04
ug/L AM20GAX as 8/27/04
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Client Name:. Davis & Floyd
Contact:
Address:
.Sample Description
L04081704-02 V-23
I ·Methane
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I
I 1· NELAC certified analysis
I
John McCord
816 E. Durst Avenue
Greenwood, SC 29649
Matrix
Water
Result
180
12000
PQL
0.6
0.015
Page:
Lab Proj #:
Report Date:
Client Proj Name:
Client Proj #:
Page 3 of 5
P0408341
08/31/04
61621_01
61621_01
Lab Sample #: P0408341-02
Sampled Date/Time Received
16 Aug. 04 11:30 20 Aug. 04
Units Method# Anal
mg/L AM20GAX as 8/27/04
ug/L AM20GAX as 8/27/04
Client Name: Davis & Floyd
Contact: John McCord
Address: 816 E. Durst Avenue
Greenwood, SC 29649
Sample Description
L04081704-03 V-65
Analyte(s)
RiskAnalysis
Carbon dioxide
Methane
N_ ~ NELAC certified analysis
Matrix
Water
Result
83
18000
PQL
0.6
0.015
Page:
Lab Proj #:
Report Date:
Client Proj Name:
Cl(ent Proj #:
Page 4 of 5
P0408341
08/31/04
61621_01
61621_01
Lab Sample #: P0408341-03
Sampled. Datemme Received
16 Aug. 04 13:00 20 Aug. 04
Units Method# Analyst Analysis Date
mg/L AM20GAX as 8/27/04
ug/L AM20GAX as 8/27/04
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Client Name:
Contact: I Address:
~ample Description
04081704-04 DUP-3
RiskAnalysis
I Carbon dioxide
Methane
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,-NELAC certified analysis
I
Davis & Floyd
John McCord
816 E. Durst Avenue
Greenwood, SC 29649
Matrix
Water
Result
79
16000
PQL
0.6
0.015
Page:
Lab Proj #:
Report Date:
Client Proj Name:
Client Proj #:
Page 5 of 5
P0408341
08/31/04
61621_01
61621_01
Lab Sample #: P0408341-04
Sampled Daterrime Received
16Aug.04 0:00 20 Aug. 04
Units Method#
mg/L AM20GAX as 8/27/04
ug/L AM20GAX as 8/27/04
DA~·-IS"'•=•• ,trdiltmll'e FL YD KIITlmrunectll Hmn!rryffletJ! Chain of Custody Record
Client Project I Site Location 815 E. Durst Avenue, Greenv,,'Ctod, SC 29649 [phone] Fax; [phone] Davis & Floyd,_lnc. Laboratory Cer'!ifcationNumber.s: SC-24110, NC-25, TN-2923, VA -77
Greenwood, SC 29649 61621 01
Contact Report To Copy To Reporting Requirements: l;(J Standan;J { J Data PacJ..-age (Specify Level) John H. McCord, Jr. John H. McCord, Jr. NA Collected By Atmospheric Conditions
fO ·onal
_j "' " ~ oO v> NOTICE: " • .e :,: ~ .f C "' C 0 w • 0 u "' C. .,, .,, 0 ~ E -a " m -a ~ 0 • ,,, "' ~ n. 0 D ' e ~ .<:. E E "' Sample Collection .= :g .§_ 0 e ~ !! w u " 0 Samole Oescriotion Date Time Time Tvoe Tota!
L04081704-01 IT-9 16-Aur 10:00 X 5 2 2
L04081704-02 V-23 16-Au, 11 :30 X 5 2 2
L04081704-03 V-65 16-Aut 13:00 X 5 2 2
L04081704-04 DUP-3 16-Au• 0:00 X 5 2 2
Re/iquished By frti' ( Ai I Date Time Reliquished By Date Time l/6P-,r;;. C.1a ou 1500 Received By uate Time Received By Dare Time
Comments
... PERM GASES: METHANE AND CO2 ONL r .. -
Matrix Type Defimtions
Preservative Definitions
1 -Dnnking Water 2-Clean Water 5-Groundwater 7 -So11/Sed1ment 8-L1qu1d Sludge 9. Oil 12. Air A -None B -H2S04 C · HCI D -HN03 E -NaOH F -Filtered G. Other
· Required Parameters, Containers and Preservatives
Reliquished By Date
Rerive~ in Laborat~<A lri9r;L_; d)D?, . .'J,J D'f-
-

-
----------
. -
-
.
Time
' · Time
/v30
-
Page1of1 f DR,""'"
Purchase Order
Stale Quote
NC
L001n Special lnstruc/ior -0 .
l_ i -e 0 • C N ~ . "~ Cb •• ~ l: -~ ~ b • ..J .s
Fraction HOT ornmen1s
Qu;,0 Shipped By
y N ~ ' " If Y, spec y: Airb~,,,ber
JfNT
.---days
Cooler ID (if available): ___
Onlce:~No Temp(C)_
Custody eal: lntc1ct / Broken I None
Davis & F/, iyd, In
FL02 _ 0 ' (02/9
---
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Kubal-Furr & Associates
-[1111inlllllll'llial Co11:;11/t1111t.~-
Low-Flow Groundwater Sampling Log
Project No. ·7...C, l\!S 17 / 'k:b r-JA:}CJ
Sile loco/ion CNA/Ticona -Shelby, NC
Field Personnel --~f<IL--______ _
Well I Sample ID C C-:33
We,9.lber Condi/ion _,_i-\r,;7"-lir~,,,_..__ ___ _
Sample Date _-'l,.<..L.1-':='~±::=---, Airival Time [) a,-4s Sample Time
·coc.,, CasingType~ LockingCapl J I :=====-~-~ ~-~~ r,""'' M""'""l= isfu1 b cl Somplinp MCIIH"'i rcn shtl·h (, I
PurgeSta/1 Tirne.~J PurgeS!opTimel o4"30 I Pu1gcRa1ef':70:Un1,min/
Waler-Level Measurements Field Parameters
1nte1Yal
0
I
2
3
4
5
6
7
8
9
ID
II
"
13
14
15
16
17
18
19
20
Elapse Time
(mins)
0(
·c:,
1D
1c;
'7f) ,,., c;
-;!,[)
·:; o:::;
l!()
ti s
q;
..
orw (feet)
:2o,t6
'.11, '.l-t
·71, ii
? 1.9. 1
'2-1.91
,2 l.9l
_i{.9t.
21.q~
--7(_Dfi
:Z.2-0\
:22.07
Sornp1es Collected
pH
Tu1bidity
hilervol
D
I l'l .s-4 ( q-c;-
2 Ill. 3,, 1'.'.l-?
3 I 'i<, z_<;"' l -:i,<.
4 \<k ')'.'.l-,,.,_ Li '7,
5 \~,?_9( "2.1::,2..
6 1 9,.'J.-..'5' ?-0Y
7 19:,"'°3 u-:r
8 I 9,,7_/_ 1-'1-o
9 42.:, z_q-:2--:::\--1
ID i.u:.., 2-w
II
"
13
14
15
16
17
18
19
20
Conlrnner O escnp110n
pH (su)
5.=vz..
C:-J-3
-=:;-.r:...v.
Go. oc.:;-
i i~
r.. .. 13
,,..__ ,c;
c..,~
~-t S<
l, . I ?..
Turbidily
(NTUJ
-2.".r
i ::}
1c;
7-. '-I
sS(
7 . .:r.
,? .ri
I • c:::;
IY
? • I
Preservotwe
Dissolved
Oxygen
(mg/L)
i ?~
0 (, -2.
n''.l-3
r S<ll
l. ~~
("\ (;,,'7
n ,c;ri
r, 4:;
()_l.{t,
n 3q
ORP/mV)
lci~.n
w?_q
ioo.S"
~':2,
-t If. I
i--2Z-
,-.z~.l'
-2£,_l
-2,..C(; 2..
-.:2-1-S<'
+/• 10% above !O NTU +/-I NTU below 10 NTU J, ORP +/-!OmV
> 30 rr-.il L
c·/ 3 t:> \ LlY'flor-i)
CNA/Ticona
tow-FlowGroundwo/er Somp~ng Log
Kubal-Furr & Associates
-E11vinm111t'11/11{ Co11~1,lt1111t:;-
Low-Flow Groundwater Sampling Log
Project No. 2.Uv; [ S { '2 b Nff'.l']
Sile Location CNA/Ticona -Shelby, NC
Field Personnel _.,_k,.e.--'-''---------
We/1 / Sample 10 _ _JKc::..-::..aZSOd.L..~-----
Weother Condition ~ qQ~
Sample Dale _ ____,.-'--1:-'::::::!:':~±:::-----, Arrival Time ( G::>l/ 5 Sample Time 7'ff 5" ,, ·
Casing Type~ Locking C□pi ✓ I o;;~~:;;;j 7 (' I '==="'----'~ . . 1nch'!I Pu,gcMelhod~ 1>:t(ci SumphngMclhodl(?:YisfuH5c:. I
Purge Start T1mcuk%f ' Purge St~p TlmeL_ __ _J Purge Role) '-1 'i"niim,nl
Wafer-Level Measuremenfs Field Paramefers
Jn1erval
Q
2
Elapse Tlme DTW (feel) (mins) Interval
Specific Temperature Conduc!once
(QC) (µS/cm) pH (SU) Turbidity
(NTUJ
Dissolved
Oxygen
(mg/LJ
ORP {mY)
3
c,_-z.c; 4
5
6
7
8
9
II
12
13
14
15
16
17
18
I'/
20
Parame1er Condilions: pH
Turbidi!y +/• 10% above 10 NTU +/• 1 NTU below 10 NIU
/j.2.',0ML
3i< 1io "' L
ID'a"tAN ·To
CNA/Ticona
Low-FlowGroundwa1er Sampijng Log
°1f/L
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Kubal-Furr & Associates
-E11vinm111,:11t11/ G111~11/f1111l5-
Low-Flow Groundwater Sampling Log
Project No.
Site Location
f'/\6..,E-1., Of? 1--,
:2-i?g 513 \ z.G t\Bl'XI
CNA/Ticona · Shelby, NC
Field Personnel _..,l?/L--~-------
Wel/ I Sample ID _...,('-'<:."-. -~2;"'S{.,_,, _____ _ o\ I WJ_WherCondition l-¼:T 49 2 Sample Date V ( 0 t,'f Arrival Time [G,4:~ Sample Time f (OJ]<
Description ol Measuring~ Cosing Type~ Lo kin Co I / . I .Cosing~ Point (MP) • V c g P V 01omeler £,../' . ,ni;M<
Pu,ge Melhodl @'-¥ ~fui:h (., I Sampling Melhod[ ~isk lfi'c, I
Purge Star! Time I Purge Stop Time) I J,--l{$'. I Purge Ro1e/.3--(5Q,1,m,~/
Wafer-Level Measuremenfs Field Parameters
!n!ervol
0
I
2
3
'
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
Elapse Time
[mins)
IN;"
I 10
11<"
i IJ....1~
/ 11t:
I~)
1~5
.
DTW (leet)
•1'7,S
--12 .i.f
NM.
'7'7 :zl
22.2(;
72:ll
"]/'}_ ."Jr.
Samples Col!ec!ed
ln!ervol
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
Temperature Specific (c-C) Conductance pH (su)
{µS/cm)
71.~'? lfl':~ 5,05"
·71.tiO {.J L ,q c:-q[.,
2t\'1Y Lf 14z. 1c;-,q.;-
:;LO ,9;'?. '-ti% 5_qc;
".2..(.00 lft ",'1 .c;-,95
-?l,QI L{IOO 6?14
Z/,oo t{o'('J ~9<
.
.
Container Description
Turbidi!y
{NTUJ
\q
jQ .
~JIii'
(c.
It;
IG
/0
Prese1vaflvc
Dissolved
Oxygen
(mg/LI
/1 I LI
r, I r,,
0,1'2, ·
0,1~
ti.I'/
0.13
0-(2
ORP [mV)
H <1;1,C:..
-I c:;/. l
( ",'?,
,.../<fo ~
-ll.fl. t:;'"
-(q2,2,
-;'f5.>r
Pamrnele, ~ilions, pH +/-0.1 slandordunil
Turbidity +/-10% above 10 NTU
COND/Temp +/-3%
+/-1 NTU below 10 NTU
DO +/-10%
ORP +/-10mV
\f ()05
CNA/TICona
low-FlowGroundwater SampQng log
Purged Well Sampling Log
Project No. Kubal-Furr & Associates
-E11viro11111c11fal Co11.~11lfm1ts-Sile Location
Field Personnel
CNA Holdings/Ticona, Shelby, NC
C-K
Well I Sample ID r~,,;-...S-
, j /! Weather Condition ..f'v., ,.J'J rf'O ./
Sample Dale
2/IJ Rf Arrival Time /vo:f Sample Time / '.7'2,.o
Description of Measuring I..,.,-,--I . ~-/ . CJ CasingQJ Point [MPI / "C... CaS1ng Type J· vt:'.'.-Lockrng ca __ P . ..,.---, Diameter ·, inches
Total Depth of Well Below!
MP? S-<f,~t/ , • .,I CQmmQn Gol/Qns QfaI Foot CQnversiQns
Depth lo Waler Below MP?I rSr 10 , • .,I ! 1/~ in Well Casing= 0.064 gal/ foot
' l 1/2 in Well Casing= 0.092 gal/ foot
Col~mn of Water in Well?! {)_ /. ytf · feet! 2 in Well Casing= 0.163 gal/ fool
Gallons of Waler per Fool I 0, /t,3
QOlll=II
3 in Well Casing= 0.367 gal/ fool [see chart)?
3 1 Ii in Well Cosing = 0.500 gal/ foot Gallons of Water in Well? s I L/z; ~al) 4 in Well Cosing= 0.6.53 gal/ fool
Gallons of Water to be /o.t(7 QJ 6 in Well Casing = 1 .469 gal / fool Purged J3X)?
Purge Method? (6't4-7 <--efL I Total Gallons Purged[ :?, :Js '.i,101!
Purge Start Time I //J';l/ I Purge Stop Time I /p:J.)
Volume Purged
Time
T emperoture
Specific Conduclonce
pH
DO
Turbilidy
ORP
Initial
C) ool
/6J I
1),f-S:c
1'3iJ1,.s
~-\~unils
0 ,75,;a/r
'3 &-IIIU
~(,mv
Samples Collected
Remarks tf,vr;r;t<, <:.
'Dc>-.. )eo) ·;o
Parameter Condilion .
I ft);.,-, A,\1v6-A>;t<r <--
),J.,-,)11),J,7-,, C(1.,_
s v '-;::, ()c
pH
Turbidity
2 3 4
J.JsJ .I gol ool oal
/o:JC>
'J, ')_, (1c "C Jt ( _,,,,,, ;:,c
2-f°/7 µS µ$ \~\i. /Aus
~ J~1':urnl$ IL,~ /
s1dl<ni!\ std unils
J.'J2.mq/l / ' mg/l /' mg/L mr,fL
Ere _... /
..._) NTU WLJ NlU MIIJ
& 1 '1 mV /mv mV mV
Contafner Description
I k (L
+/-0.1 standard unit
+( 10%above 10 NTU
I /n r-t1J1/
2 )( '(c,,,,
I X 2,-,,,.,
+/-I NTU below 10 NTU
5
oal
/ /
/
"C
µS
std units
mn/L
NTU
mV
Preservative
1-J.c(
tl'-t
ORP
t1,11 (J:,
2Gi \
c;, -05
:2. (o y
3~
l 1,'l
+/-10%
+/-lOmV
Revise 5/28/02
'lN ( c,t C4. )i P.i "ii
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Kubal-Furr & Associates
-E1wiro11111,:11/r1l Ctm:,11/ln11ts-
0
3
5
6
7
Elapse Time OTW {/eel)
(n1im)
0
Low-Flow Groundwater Sornpling Loy
Project No. 2?,tJ.A-ceJ
Temperalure
[Ci
Site Location
Field Personnel
Well/ Sample 10
Specific
Cornluclnncr1
(pS/Clll)
CNA/Ticona -Shelby, NC
\T-l
Turbidity
{NIU)
Dissolved
Oxygen
(mg/L)
ORI' {mV)
I K.JTJ
T'fgT= .1£->f 1----•.:.__~.l-/-~c..L+-----+1-~.,_,!.-µ~:L.....+~(21J_~L.......f~.ll..-p..b,!L:!-I ) ?'.'.> M6 I l ,._ 1--9 _..,_:p_µ.:i.a.:::z..L.1-----+-J....!..:....,_.!.......+---'--!..,L...J....-1--"u...t_,.,__-+...c:::-+1-~~--+''---'-"<..!....Lj CY-,, p I ll/7io,-.) 10
12
13
14
16
17
18
19
20
Preservative --
4? ~ 'IT+!, coi)2-/J1'<0t-\
L&.'11,,(,,, -
Turbidi!y +/-10%above 1\1,..l!J., S"D~ll'.:.TUbelow lONfU
l),~'li,.,.-, fl,' evt"-f\,,.,"7 S·l,{'54,z.i: -fl-t-«:J//c-rl.. flilf<,'tM{;;,;,:J ~ l)Nt.c -?>cc., Oi>) 'TC -fMl't-,-:--
CNA/Ticona
Low-FlowGroundwa!er Somp~ng Log
Kubal~Furr & Associates
-E11vircm11w1111f Co11j11/t1111fj-
low-Flow Groundwater Sampling log
Purge RofeF::(tQml/minl
Interval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
Elapse Time
frnim)
,t:)
s
0
r-6"
1-V
:2..,C:
"3.,()
.-z.,t;
tfo
'-c;
,rn
5'7
Go
(,..,'5
orw /feet)
i2.~G 0
iJ.ol I
I~, L/,Z~ 2
l~,97 3
[( :1q 4
j\ _q,i, 5
5,1'{ 6
5.<tl 7
iC,.1 i 8
It .. 1-~ 9
\'.f,-vr 10
l•"."Ll II
( 5'1 12
q,()l ,, 13
"
15
16
17
18
19
20
Tempera lure Specific Conductance !'CJ (µS/cm)
I" Ntv\
2.'9[17: :1-0b:3
2-3,-:z.:r ,., 1'\4ll
zq,I c.. ·7o:;iC...
2:-:3·l ·?1,~
2-. '-/3 '2-o'-/9
;2...5,~2-. '7 r-. GD
2-B {;'1---2.1)(;3
?;"'3 .'ln l/'JJ,'1--o
23. i1..... "2/1 (, lo
7'2.~ 7('-.-?(()
1'2:Z.'b6 ).') I ~
122. ,C,9' ?..c2.JJ
pH (su)
0, '.3 :,-
L -:,4
lo~~
1;..,.-~Fi
r _-7,c;
r✓, .3".f
G.'3'.f-
b,35?
G,.3~
G.3~
<o. :;°(
<;,0q .
Turbidity
(NIU)
Ito
~
·~ --S -
( n
i oO ·
I l 0
i '2 ..ll
1-:30
i~
·100
i-::ro
Samples Collected Container Descnplion Pwservative -
1./0\'lvl.,,
Remo,b 'f e,irof \N 6, 'T~9 SLOY,tj r,r,Q W l:CT'f:lZ... f':1 i'l)/I) yZJ
Dissolved
Oxygen
fmg/L)
4,1-3
i.o5
;,_c;z
o:?,-:=t-· .
6-29
n.Z.3
0.1...b
0./7 ·
0 i<;
(),1'2-
n, I ·1
0-10
ORP (mV)
-·-
-I [.b.f;
-UI.(_
_, 1n:z.
.,{ n 9'.'<
-104 .\/
-10"1.z.
-loC/,3
--toq_;;r
-/o'I.?!
-loi,6
'105\,..,
-/r,~~
Purarneter Condilions: pH +/-0.1 \landord unit CON0/Temp +/-3% DO +/-10%
Turbidity +/-10% above 10 NTU +-/-I NTU below 10 NTU ~RPO. f +~;f_~f ct\
3
CD.zJ-, ,.~/\()t\ Sut.f\O'f i x2-.st:ir11i , \..J ='\v ,_
CNA/Ticono
Low-FlowGroundwoter Sampling Log
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pB711:
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low-Flow Groundwater Sampling Log
Kubal-Furr & Associates Project No. 2C.('J /'\9:1
-£11vinmmc11tafC011::.11lt1mt~-Site Location CNA/Tlcona -Shelby, NC
Field Personnel _,_k-'3--:.=c· ~~~-----
Well/ Sample ID -~'~:t~-~7~-----
I Weather Condition ~;i51-.<t()::S:
Sample Dale fJ\ ( ( t~ Arrival lime \'340 Somp!eTime_~_._l5bS.,_._,c..,_ _____ _
Demiplion ol~~i~~np~~ CmingType~ ~~GZJ Di;~~;';,Ci:l
Pu,ge Melhodl(bt.\~JALJiJ Sampling Melhodlffit2._iS!A)f l ( I
Pu,geSlml Timel i '3\:,0 I Pu,geSlop lime/ j 9l-O] I Pu,ge Role/•~1i?m'fm;el
Water-Level Measurements Field Parameters
lnlervol
0
I
2
3
4
s
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
Elapse Time
(mim)
<f)
s
/D
15
1o ·y::,
-?iV ~s
l.\O
~
<;o
I;h
Go
C-,Cj
:,-I)
DTW (feet)
q,,1-:3
[',>',7
I r,,2 .. "1
I 6 _e.:;3
1· 0, <ii'
/I.OS
·11. '7,0
i I ,1., r'i'
1.1---1-
-'13
'7 .I c..
('7 a;q
\1..G1
12..~
I 2.9::
SanipltJs Collecled
Interval Temperature Specific
("CJ Co~is~~~;1ce pH /su)
0
I f LIN\
2 ,...,, r\J '-1'11 (D _g G
3· -?t'J .In 4'1-l 1;., "'I 0
4 2r,qq (.. 1-'-f ·::=r. 00
5 2L9C LI ::i-Y G_q\<'
6 Zl.1:.1 l\=ti:;-cm
7 z.2 .n I 4"-17 c;_9i
8 IJI ."lb ~q.-q 1-:00
9 72. 2rl t:fio ,. q1---
10 7 '7 , ,'"li l ~I r,. viri-
II ;!..2.-? 't i. 'i<-:0 G. 4g
12 122.2-1 LB('.; b.94-
13 22.IQ 1.jp,E, r 94
" )2. z,.::i-0~6 If, • "jl,,
IS
16
17
18
19
20
Container Descnphon
Turbidily
jNTUI
, .;-o
I r;,Q ,>,n
r-:2,n
icYJ
i 3')
\ .q--J
I~
\40
/GD
i z.o
\ '1/)
(L(O
Preservative
Dissolved
Oxygen
(mg/L)
ORP [mYJ
~
~
/),9-f. f--2rfl (
"· "3 · -2-10.S
D,? I '"21~;;
D. ?f -22/.r
c1 .Ljc 2'2 I _e:;
0. '6"-·-?'? { -'6
O,l(O -1 '7</:. '>
0, 2-\f --::n::r
0,\1--2Z3T
0.1~ ·2-2-~-'il
ri oq .. zz;-o
0, Ox' C.'c/. r
n.01--23).7
l tZotJ
TB<;T-:::
-;>?>or1iL
()'3 OI WT10J,l)
Tofl~1
t\Ji:h. 1::0 :
v-2. S" 61'1l.
CNA/Tlcona
Low-flowCroundwoter Sampling Log
Kubal-Furr & Associates
-E11uin111111!!11/11/ Co11~11{/1111b-
Low-Flow Groundwater Son1pling Log
Project No.
Site Location CNA(Ticona -Shelby, NC
. Field Personnel ___ ,,:(5;!;ae''iJ:::=. _____ _
Well I Sample 10 __ ......:'.J::,.._·_1_-_q_,_ ____ _ <f'I /ot-( WeotherCondition ___ s:_v_,,,,,_,,._,_JJc...,,.fO::.'......:.Jc.· __ _ Sample Dote __ _c/_ l,l/ __ 0______ Arrival Tlme,...1./.~~'..!..::-S'~-,-·..:':':"on"'.'P';''"'.:..'."Tir:':"ne~ ---~==1:r,Z~~(----
Descriplion or Memuring~ C:asing Typf'~ L k' C I •cl Casing~ Point (MP)~ ~ -~ oc ing up. 0-'i:f'--Oiomelcr~ ~===--~ Purge Me!hod/ {j0,1--<Sf:/l~c..,.. Sampling Melhodlr;::__.?'C,,-Jr,:{,.;,.,"'7,::_
Purge Slort Tirne/@.sr2 ) Purge Stop Tirnel / ,bl 1 Purge Ro1r;f'-'/2"'~"-a-"'ml"'/m""inl
Wafer-Level Measurements
Interval
0
I
Elapse Time
(mins)
(J)
,/ 0
DTW (feet}
f; --I ,.) J
1,qc,
lnlerval
0
I
Temperature
!°Cl
--
·-·
Field Parameters
Specific
Conductance
(µS/cm) ---
pH (su)
---
Turbidily
[NfUI
-
·-
Dissolved
Oxygen
(mg/LI
---
ORP {mY)
--2 lo /o,~o 2 Jo, 'i(,. 3?.'.3 7,'JJ' !'7 0. 1.S--lt<C7
3 I~ -/(_70 3 J.o ,3/ '3W-·7,:1(., Is" o. I I -(l,(,,.s'
4 7/-6 12,l(o 4 2a.lr.r 7:,(.;,{ '7, 19 /1 o,u9 -, 31,f
5 J0 /3-t~ 5 'l-o.J"o 3G,{ 7, '3'3 , --/0 o,uf 'tYlt
6 :!c-I 3, 9o 6 'µ)_'77 3C,,S' '7. J:l /0 0.0 '/ -/~.J
7 3·/ -~ /'(,<fo 7 '?./,Zf '3/v& 7, 2.-K' ,J.:)_ 0,/o ·-12,.(
8 . lf t' J:;'.o;{ 8 21.o) '3 (,'.5 7, ;.Is" 27 iJ,6 -7 -1:r,.9
9 '-{(j 1:(.73 9 7./,;o 3 :f'? 7-'f/ :3L/ o.o, ··t-:,6.o
10 So /4-,,3-5"' 10 . ?.,(, I/ 3:S-7 7.3 7 JC:,, 6.oC:, -,vz,'?
II S'S .I 7. /0 II 'l.c,. f"l '3-:,j 7. ,<;Y Jf O.d/c -17.S,C,
12 C>o /7.7<> 12 1o. 92 '3S3 7.3? t.( :s-O.Vb "'i,_r"O, ()
13 0->. ;-h,ro 13 ,'.JQ.~-J '?.>/ ?. 'IC, L/1 o. O(, -10S-, 0
14 ?o ;f,9~ 14 1&.9/ ·3 ~/) 7, '-f'-/ :::--::-o 0,0 (, ·-1-r.f; D
IS IS
16 16
17 17
18 18
19 19
20 20
Samples Collected Container Description Preservo11ve
· L . Ju", 1UOJ tA I[.
--
a.::~~ Sui...-fiOc--:-
/f'AIOi,G .f!".="'-l~!J02!'-"='.,__,,:__::"~'l~ccfc~-v<~·,'......:S,:--c'..:'.,..,::,6rl.=,!'.!..'·1,=:_-=...Lil""-..-'.'.Lt.ce;,'----'=='!,%1:.e:L:."-.'..,:;c,lc.,c'--~~--'i
)
~
<
s
;
:
'
"
l
'
.
e
:
-
•
+
·
•
~
c
'
-
'
~
'
C
!
.
.
)
....;.;<>!L..VA--t==~:..,<:.5((" ' ~-( > 3':J l. l'rnu111elc1 Condilions: µH +/-0.1 stan<Jrn<Junit
Turbidi1y +/-10% above 10 NTU
COND/Temp +/-3% DO +/• 10%
+/-I NTU below 10 NTU ORP +/• l0rnV
CNA/11cona
Low-FlowGroundwoter Sampling log
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Kubal-Furr & Associates
-E11virou111t•11t11{ Ctn1:,11/tm1t:--
Low-Flow Groundwater Sampling Log i.J
Projecf No. --"'-'c/t:=-:_=,/J..:....:.....7'._9 _
Sile Location --"C'-N-'-A-'-/-'-Ti-'c-'o-"n..:;o_--'S'-'h'-'e-'-lb"-y'-',-'N-'-Cc.-_
Field Personnel ___ _._6("'~'-"--------/ tr! Well I Sample ID X, ( ol . We9th~~Condition --===-l--"c-4----Sanip!e Date ,J Arrival Time J:Z.s-2-Jr 37J Sample Time,----;:==:::f:;f!:;~---
. Description of Measuring~-. ~-. g Casing J Point (MP) \LC-Cosing Type .5/ <.~ Lodang Cop Cl\ . .::?l-Diomete ~===;::!__ ___ :-----";o,eco-"!)••
Purge Mett,od/<fc.:rtt.5/l.t1c I Sampling Mel~odl . ,$<J.,t.1e·
Pv,ge S1~,I Timej /ft(1 Pv•ge Slop Timej /L!ff I Purge Rotef'1..-f.S-c) ml/mini
Water-level Measurements Field Parameters
Specific /n/ervol
0
I
2
3
4
s
6
7
B
9
10
II
12
13
14
15
16
17
18
19
20
Elapse Time
[mins)
C>
s--
//)
/.S-
'Jo
·"J-.s-
'3o
5,r-
t(o
l(,S"
or.v (feel)
is/lo
/4,?o
lb,r,,l,
JI,~
11:10
; 2,,;;tJ
jl-,'11
tJ..? I,
/2..9~
/3,30
Samples Collecled
,._,,_ .X,,l,ft i¥
Interval T emperoture
i'CI Conductance pH (su)
(µS/cm)
0 ---~
I --..--., 7,.f7 /3o) (.,' {,;;£1,,
3 '/../, c;t, i 3 'l-( f,.i-l
4 :? ?o3 13 '),f l . l r;,
s '/ (7q ( !)/ f t. •• w-
6 1, .. . '/0 13.91 l.w
7 :J..J37 I ',J<j,( {,,e,?
8 lt. 3 S-;')_ 9 / (. .. (,,, h~
9 Q/.3-J. I 'l-<f,J l. c,y
10
II
12
13
14
15
16
17
18
19
20
-Container Oescripllon
/KIL
/ l<ILJ'.,1
I '/:UH!
Turbidi!y
{NIU}
-
~
?-.R'
J_l/
:Js'
Jt./
:l(J
1.(..,
1,<?
_:!C(
Preservative --
Dissolved
Oxygen
[mg/L)
--o,</l.
0, ?1
0./7'
0,1.f
0,1.f
0,/(,
o.lb
0, /<J
ORP (mV)
----519..,--
-10,/_J
-lc,c/, (,
-,o3.6
-/4/. 9
-10 ;J, e:,
-IIJ 2:7
-/t!l.f-
111.a,.,, r ?.,.; lCth<c'-1~ ,t,/4.<;;J 1fes~.-ru.... 1) J.¼w L(,,V r...Ji .... M:) eft.;u ... <.lr.4DLilc'--~c/.l'ill. ,f',,(,>/M-,~---.r J"~-2"-1:x::?,, 'i> ra ·S#<IP~~-
Pa1ometer Conditions: pH +/-0.1 standard uni!
Turbidity +/-10% above 10 NTU
,c?JfLP.,;l("7 .~ fJ6-f'.,._,,-rr ~ "'I)
COND/Temp +/-3% DO +/-10%
+/-1 NTU below 10 NTU ORP +/-lQmV
CNA(Ticono
Low-Fk)wGroundwoler Samp~ng log
Kubal~Furr & Associates
-E11uira11111t'11l11/ Com,;11/faul:--
Low-Flow Groundwater Sampling Log /7/
Project No. ____ -4tJ,~z¢'--'-n_•'._P_._9 __ _
Site Location _ _cCc..Nc..A"-/-"Ti-"c-"o-"n-=a_-.cSc..hccec..lb=-y'-'.-'Nc..Cc.__
Field Personnel ~ ------'==-------
/4 Well I Sample 10 J.. T -(, _p, (; () { /4 Weather Condition ___ S,___:<"''11/'-'"'=.--:i.L._.li_.;;='-f_· ___ _
Sample Date ___ ~=~-----At1i11ol Time ~CJ) Sa111ple Time _____ ..,_/~7c.·~oLy'-----
Oescription of Meosuring~ . ~ g CosingCD Poin1 (MP)~~ Cming. Type .5:..1{:-z.,rz_ locking Cop CO,..{o,L--Diomele 1 nch-.,
Purge Method I PePL·.S1/fz.Vc Sampling Methodj---~~-4-,-;--. ----
Purge Slart Time I /beg I· Purge Stop Time I /Gs-.S,-! Purge Ra1e/(\..--/.Jt) ml/mini
Waler-Level Measurements
lnlcrvc1I
0
I
2
3
'
5
'
7
8
9
10
II
12
13
I'
15
16
17
18
19
20
F.laprn fimc
{n1i11s)
cJ
~
,b
IS"
Jc,
'l..s-
:Jo
"3..:1-
t/o
I/~
So
OJW(lccl)
/~OC)
l~K
11,.:, ~
I ').,f}o
/'l.C?r.;
i3,&>
/ t.f, Jo
/{,f6
IS", )o
I f.-S"o
1s-A0
/nlervc1/ Tcmperalurc
{°C/
0 -
I -
2 JJ. 3:r
3 2,. ff
' 2 /, 7 2
5 1/,76
6 JI, 7o
7 !JI-f7
8 'J.I.Jf
9 'J.,J.o 9
10 ,J),19'
II
12
13
"
15
16
17
18
19
20
Field Parameters
Specific
Conductance
(µS/crnJ --.
ot?f7
Q(/'37
SvJ3
5o J.t:1
So :I(
:sol//
.:(077
Cl/!>-
,S°ftl(:,
pH(w)
~--
S,67
Ii 9J
Lf.9/
t(.f7
. c(.9J
l.{_ Q 3
L{_9(
'-(, 93
i/. 9J.
Tllrbidily
(NTU)
,----
-S"-S
tl<
t/6
5c;
3,f
39
t{o
,S,f
'3'?
Diswlvod
Oxygen
(mg/LJ
,..---. -
tl,S3
8_33
o.~
o 2'3
o J. I
a. ;J6
Cl, :J.o
C,?,:,
a,20
ORP (mV)
--
·-
J3.7
Jo. C.O
11,6
ls,°f,
t 3,J
ti .y
1.f
J', J
7,7
Samples Collected Container Descnpl1on Preservative
!Ail
C--1\~ks Sl, c_.ft '5:-
1/1S T.:,L t.As, •t-,...J 4.1/lll\t'T fie.,._,,.,,,
Parameter Conditions: pH +/-0.1 standard unit
Turbidity +/-10% above 10 NTU
-z,J<,\i:, '"'-k -14cf _
o·;,,.,,..;1flf",<-7<-".f ST,;tt3,..e-0)8-•Dc->) m SA---,'l.i
-. D«z6t1\ ·'°'-...-u. -t-,~ l (.) L
COND/Temp +/-3% DO +/-10%
+/-I NTU below 10 NTU ORP +/-lOmV
CNA/Ticona
Low·flowG,oundwa!er Somping Log
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KubaJ-Furr & Associates
-E1wiro11111wt11l Co11:,11/t1111ts-
Low-Flow Groundwater Sarnpling log
Project No. 2k,(l.[A qC,
Site Location CNA/Ticona -Shelby, NC
Field Personnel ~
Well I Sample ID ==:tv:=-3::~============
• tyealher Condi/ion ---l:i::~(r--!--t-)-0,.UQ;$,1f'~--,,-------, Somple Dole B Arrival Time I S-'t't) Sample Time £11,;JL ~ ( ( 7 / o)
Description or Measuring Casing Type Jul Loe kine ~✓ . Casing~ Point (MP)~======-----!~ ~u,ic[~ D1an1eter~
Pu,ge Melhodl <?6!Z-IS'.[A \_..J1d Sampling Melhodl e@..\STM:fl ( , \
PurgeStartTimej \% / rurgeS!opTimej \·?t:?y ) PurgeRotef;l?£; ml/mini
Water-Level Measurements Field Paramelers
Interval
0
I
2
3
4
s
6
7
8
·9
10
II
12
13
14
15
16
17
18
19
20
Elapse Time
(mins)
,tJ
C
,o ,~
-11',
') c::;
7-,r-,
-::iC
l ,1)
l ")
SD
Ch
c;.,n
r~5
orw (feet)
t,43
i L"!---1-
\J..'.:1-?
l ~ ,\".f
0 <;3
'3 Fb1
I 4.{)Z,
13,91
\'-.'U)
I c.. ,elf
\L .95
c::;. '1 r
I c; c;-:1,
'~-~~
n So 1ples Co!lecled
Interval Temperature Specific ('C) Conduclance
(µS/cm)
pH !su)
0 .
I Fl'JM
2 22_,;i-.q-:2-1-3"2--S".o n
3 1,,,--,. S<:'.'.!· -,;::i2,__ C/ S-, CF>
4 1,--,. 9.<t' ·7;~--::1,"1,_ i::;-, ,.,~
5 J.;:l .'14 ·"J"l.".ld I. ·r\ u_o,c
6 :J.":3, ·? : '1 _'1,-<:;"'::, s-.o
7 '.2.-~ u:. /) 'J-Cj ~ Ll,9'
8 2-3,Gi=t '1. "61-19 s-. r,3
9 7lJ _::,5< :::z.~ S-.03
10 :J-1.9 2.. 2{,'5 '8' s-: 02-
II -, t:=tz.... :.2.c;-90 \.f C, (
12 :2.-1-Col' 2.<,5?'2 ~-I\\..
13 .21.1....6 -.2.. -c;-c;-) c;. oo
14
15
16
17
18
19
20
Conlo1ner DeKnpl1on
Turbidity
(NIU)
-:Z. l
r.C'
\1
I' ,
\Cf
:,,!-i
'/--".
iC
F-6
lu
i' ,
1<i<
Preservuhve
Dissolved
Oxygen
[mg/L)
2.-Z.3
O,Cfi
o. '9:1...
0Jo5'
0, LI
I\ \]L
/) :=re;
A rot:.
/\,c:;c;
0.01
Ii, c;?
n c:; I
· ORP (nN)
~
;_" .°)
,c..l_ '2...
/" c...
G t.3
r. r-:::J,-
/ 'ri ,'/
IA"I.?
~-0
r;;q_q-,
lcS?.1
~.'=,
?;<l ,t:;"
'1,)ullvi\,,-.,., W/L<-,ltl/e;R. Fv•,-, .r-:-;p,,,rz,z.-,. A-z_u,;7n;,Z f,W,lvt,-12.iU' ..,77n,_p -/.),c7.,,)c>) '7'c ..rAt.,,t,h ~ PorameterCond1tions: pH +/.Q.1 standard unit CONO/Temp +/-3% DO +/-JO%
Turbidity +/-10%above !ONTU +/-1 NTUbelow lONTU \ ~z. s-G ML
I~
-~-::
';> 1 o "'8' I L (_ Y 1, Cl L.UTto,;,)
l
KubalRFurr & Associates
-E1wirm1111t'11laf Co11s11/l1111ts-
Low-Flow Groundwater Sampling Log
Projec/No. ,2&:,ll)A 99 ------------
Site Location __ C_N_A~/_Ti_c~o~n_a_-_S_h_e_lb-y~,_N_C __
Field Personnel @-· ----,--=~----Well I Sample ID --~~;::;...-· ,_(_:.._;f::..,!..~.:.... __ _ .f / ! ,/ Weather Condition S'uNJV L, efC,/
Srnnpln Doi,~ (II 1 1 Arriv(if fit11•~,_/_7_J--"J'--,__:S:::"'::_"1:;:'''::.' l::_i'::.'"~•--=--=--=--=--=--=-~:~~,i-=~:/-i=,F:,,..'½f'.,,,tJ-'--=--=--=--=---
l)r.•\1:111Jlin11 ,,I M,1,1\11ri11<1~ c··. I I~/ ,u 1 , ,. C I .cu\i11u[ZJ;.' f'oinl (Ml') --; 6(:. rninu ypu vL,. uc 1110 up C'ct,,'-:-.(.__ D1ome!er '-;===='"----; ,nche, Purge Me!hodl?i~fTl't:.1 (._ Sampling Method I ~27
Purge Slort Time j /7i./,J--
Water-Level Measurement,s
Purge StoP Tirnu[ ./f.3..S-I Pc,ge Ra~/ ,-I) j ieu ~ ( ml/min
Interval
0
/~.1 .,,
3
4
5
6
7
8
9
ID
II
12
13
14
15 ~ ., 16
17
18
• 19 .
·" 20
.
Elaps~ Time .'Qrw (feel)
(m1111)
a~ /3.<rS'
S' I</_ 7-o
fo /lf..n; ,~ t<.f...rtJ
')J 1✓. /,,6
J...r-r<f:?a
5o 11.71
~ /'( ts'
L(,:1 /<(Js?
'-(,S' /'1,C/j
Sd l</.97
. ·~· ~-
Interval Temperature
!"CJ
0 --
I • _.,:' 'l.J,&l
2 J/.39
3 P.o, '1 I
4 ).0, ,f)
5 J,;_77
6 J.O.J'J
7 16: ?C.
8 Jo,(,,(
9 ;io ,-Sa
10 '/-IJ, :)_(.
II
12
13
14
15
16
17
18
19
20
Field Paramelers
Specific
CondUctance
,. (µS/dn)
-·
jo6,S'
/ 1,fs-
/t.tt 7
/?-59
l9s7
i7'-sy
;9s-J'-
; 9.S:-6
1711
I "/3/
pl-I (;u)
--
(p . .fO
(,,X,
l, 71/
l.71. t .r,, Cl
{,,, 1,,<r
(,,. {,f-
(,,_ {,~
l,.(,,f{
Iv,(;,)
Turbidily
(NTUJ
-
/QO
/tiO
/c,o
//0
lrJo ,
100
/06
/oc)
/cio
/00
Samples Collected Conlo1ner Descnphon Preservohve
Dissolved
Oxygen
(mg/LJ -
~,J'J
Cl. J,,
O.Jo
0, ;J-
C, t 7
Cl, ( 7
a, II(
0,/0
6,1-S-
o,/h
ORP (nlV)
-
·-13.f,7
-rJ,:,S'
-13i( o
-13;7.ci
-;;177 <,
-(3r:d1
-/ :fl. 'I
-12.'?S
-12'1,a
-;zy.,,f
. vlK-R)"'f□,b Sul-/ii)i'-I 1<:"-0-"'-I ·;;,,_, Cf/3Co, < /1-t. t/,r,&(1.,c,v., 1 ... .., '-"'•" ,-)(',' ✓.:nwli.2:: -.44. o71it1!-/7AKl>rL-t·'Tl-f --,;719, > L)c7',1)c>) 7tl .r,4-u>c ~ ·1o0<-P<-fl6,T> ,A-f--e ,~ ~ > 'o.'1 Porameler Condi lions: pH +/-0.1 stanfJord uni! CO NO/Temp +/· j% DO +/-10%
Twbidity +/-10% above 10 NTU +/-1 NTU below 10 NTU ORP +/-I0mV
CNA/TlcOna
Low-Flow Groundwater Sampling Log
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Kubal-Furr & Associates
Low-flow Groundwater Sampling Log
Project No.
-Enviro11111e11l11/ C(l11~11/tm1t!'>-Site Location CNA/Ticona -Shelby, NC
field Pe,sonnel (j1:.:.
Well!.Somple/D j:'7..-lj Jltb/u/ WeolherConcJilion -,<,1;.nv7 )P;
Sornpln Dul<"?____________ Ar11vnl lin1,i 09t,{;, Swnµlu !imu /00 c>
OescdpfonofMemuring~ Cosing Type~ Locking Cop! 1./_";-,. I Cosing~. ~~~---~------~ ~~ -·~ Purge Method\ 1{-"1'l o?;Jz,,17c:,_ Sampf1ng Method) f'dl-r✓(Zfl::i7c..
Purge Slar1 liri!l/~ Purge Stop Time I °'7...r(, I Purge Ro~4: -/2 ~/mini
Water-Level Measurements
lnteJVOI
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
Elapse Time
(mim)
0
~
/0
1:S
~
JS-
S"' ·s.s-
t/4
//./ ()
//, f-{
I /.L, 3o
IL-?()
(3.&r
I '1. ,:;,.:{'
!'3 .<1:i'
11,0 'I
;J,~•?
, Samp!es Collected
Paromeler Conditions: pH
fn!erval
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
remperolure
(~C)
--/9.91
1.o,06
I 7'. r;J..
} 9. 9{
Jo.uf
/<0.1(.,
:lo,/~
.
Field Parameters
Specific
Conduclonce pH (su)
(µS/cm) ----~1?'1 '7.o~
9 9-J. ?.o(
9-f't (,,. 9<(
C/9b (;,_ 9o
/()ol C,_'l(
loo? {,,, 9o
/0(1 ,1 G:,, ['9'
Conloiner Oescnpl1on
l>JL
/X/J,,i/(
+/-0.1 slondard unit
Turbidity +/-10% above 10 NTU +/-1 NTU below 10 NTU
Turbidity
INTUI
~ -
)if
'.5c>
;2.:>
;:.~
oi-1
:Zo
19
Preservative
f/C/
Dissolved
Oxygen
{mg/L) ---
"S. '/tJ
J, IS-
6, i//,;
0, 3,S-
0, 3 f
0,'Jo
d,J.1
/.J ,Jt) J
ORP +/-!OmY
ORP (mV) ---
-'l J..."J
-?'J.S'
-91_p
-9&)", 7
-rv, <(
-';lo, b
.. $1<,, lj
CNA/Ticona
Low-FlowGroUndwo1er Somping Log
· .. :
Kubal-Furr & Associates
-E11viru11111i:11ta/ Glll~lll/imt~-
Low-Flow Groundwater Sampling Log
Project No.
Site Location CNA/Ticona • Shelby, NC
Field Personnel {_,~
i . Well I Somple 10 --tJ"-~;&---:--~, -,-J---;;;~,,.~e,~1--.f' '9 / J, Weather Condition -JuN;J? d°OJ' Surnple Dole t}l, Arrival Time /~'/--5-Sample Time ______ __,_/_,_7__,s:_Cec'---
Descrip11an at ~~~:u1~n_r91~ Cosing Typo) We I locking Cop~ Cosing~ ~ ~ Oian1ete1~
Purge Melf)od/ '?&---iS"?(l7<.. / Sampling Methadl ___,r;'.ltf (:
Purge siart Ti.me) U~ I Purge Stop Timej / 721;,r Purge RatejA. ,Jc.,v ml/mini
Wafer-level Measurements Field Parameters
Interval
0
I
2
3
'
5
6
7
8
9
10
II
12
13
"
15
16
17
18
19
20
Elap~e Time
(min5)
c.)
~
/6
ls
Jo
JS"
~o
.
orw Ucci/
It:!£
/9.1/o
19</o
/'7,J 9
!'7 l{ I
;9. i.f(
I 9. 'II
Samples Callccled
Parameter Conditions; pH
Turbidity
ln!ervol
0
I
2
3
'
5
6
7
8
9
10
II
12
13
"
15
16
17
18
19
20
Temperature
i'CI
-
19.{(f
J"),Jy
/ o/,1 'l
19', 9k,
/J';?f
19, I 0
Specific
Cond1Jctance
(pS/cm) -
::Z;.o 3
-1. 1-o '-(
'J. '),.1'5'
/2J.1(.J
') ?-.r-S,
129'3
Container Descnpllon
pl I (~u)
~
(,, 'JL(
l,. JJ_
(,,, Jc,
L,, 3Lf
0,]C:,
C,_3[✓
+/-0.1 standard unit COND/TemP +/-3%
+/-10%obovc I0NfU +/-1 NTUbelow l0NTU
Tu1bidity
(NlUI
-
0,1S
I o
a, ;),f"
O,)!
o.3s-
6..S-S"
Preservallve
-
Dissolved
Oxygen
(nig/L)
-
0, t,'(
o,-ro
0, ;,3
0,30
0,)7
O', Jl
ORP (niV)
----
,J..&,, 7
J t;,.J..
J.f_ <f
'J./...s'
19, 7
,?c.\J"
DO +/-10%
ORP +/-l0mY
CNA/Tlcona
Low-flowGroundwnler Somping Log
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1:
j
I
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Kubal-Furr & Associates
-E11t.•irtJ11/llt'IIII/{ G111~11lt1111t~-
Low-Flow Groundwater Sampling Log
Project No. _,,,2"'G,"'-'t,J"'-'f\'-'--:fj.,__, _____ _
Site Location _C_N_A~/_Ti_c_o_n_a_-_S_h_e_lb~y~,_N_C __
Field Personnel -~\~Q==c--------
Well / Sample ID -~---~Zfi'~>--~------
Weofher Condition ~ L!ID1S
Sample0o1e __ __,-L;'I::::::::::\:::::!,---~ ArrivalTimc \ ',3Q SampleTimc_--1~1-"r-'.,_U=cc~-==----
Cming Type I P• 1 ( I Locking Cap~. Casing~ ~~~~---~ V ~~~~
Purge Mell,,xJ: -~5'.\-:c,..l,hcl Sornpling Mclhodl p&;sh &rJ
Purge Stor1 Time. fu.oJ Purge Slop Time/ { 4 'f5 / Purge Rote b 1a,?1tm,n/
Water-Level Measurements Field Parameters
ll1tr~JV(ll
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
[lop~e fo11c
(niirn)
tfi
C
lo
1C:
/J .P,
.g;;
,-:; {')
,:; 5
L, 0
l Fi
1< . I LI
\I . 'i-
l,j l..f"
'\ lf.']
t .U:G
il ,L/;'.f
\ 4.lf::i
4.ll'~
i4,4~
i 4-. lj'f
Somples_Collec1ed
lnlcrvul rcrnpcrolu1c
l'CI
0
I I( ,/,,)
2 It 1~
3 i Cf _'-It)
4 It/. "?l~
5 I ti.ii
6 'CJ. 19.
7 111-00
8 i~ .9q-
9 (q.07-
JO
II
12
13
14
15
16
17
18
19
20
Specific
CunUuctcmcc
(µSiem)
Wt'
~ ;c
Lf.£,
4ct
40
,,; D
L q
'fl 1
4q
Container Oescnp!1on
pl I (~U)
4.1--.~
4.10
U_tVJ
L/-r/J
LI.SI
4.r~'3
lf' t:;' ,;-
(~.c+,
L .D,1-
Turbidi!y
(~HU)
aoo
n.m
nnn
'Jr,:-)
nm
nl"ln
ri. co
n.rr-i
h IV\
Preservo11ve
Dissolvcci
OxyQ<.;ll
(rng/L)
O,qC,
n_qq
i,-:::i-q
1.1 •~·
0 -~ ()
(('\ 9:-1" o.-w
o.c;ci
/'\ ":J-"2-
ORP (mVJ
-
~":f-,2
,._,,..,z. D
lc:z:7 l I
t=A4::/
e:,tf '3:t
c;t/3.(
cac.,
gj<;,
q13 .lo
----i).lJ-1..L.U.Ll-L----1..,"'-..<-'="""-'-'-'-----l-UCl....!.-G""'-'>..L~~..L=-r/V/\D H-th 71 I
Parameter Conditions: • pH
Turbidity
tf'.!PI\I MT~ Z::0.1 ""g-11.--
.. I-0.1 standord uni! COND/Temp +/-3%
+/-10% above 10 NTU +/-1 NTU below 10 NTU
DO
aRP
TQ(Jlv f<./€€@7 -;""'3&1rl-.
+/-10%
+/-IOmY
CNA/Tlcona
Low-FlowGroundwolcr Somping Log
Low-Flow Groundwater SolYlpling log
Project No. Kubal-Furr & Associates
-E1winm111i:11l11/ Gm~11//tl11I~-Site Location CNA/Ticona -Shelby, NC
Well I Sample 10
Field Personnel _ _____.K12-,=....c:,c....,,~-----
D ~ 75: o( 1 o\ O" , c ~/her Condition Pcist c, o '5 Sample Dole __ ..,v=., .... _...,_-4_ =-_]...._____ . Arrival rime l .::i ~ Sample Time ; k:::oo l ,
Descriplion o/ Meosurin;~ Co. g T pe~· I/ L k" C CZ] 'Cosingw"l Point [MP) sin Y . oc ing np Diamete1 ,t.,,-,
1nchr,s Pu,geMelhOdl ~~\-lied-Somplin, di pt"v' sk\fit).
Purge Starl fin.;e~ffi~=~l · Purge S!~p Time'---'\""'-..L,L-_J Purge Ratef,-.z@1,m;nl Water-Level Measurements Field Parameters
Interval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
Elap>e finie
(mins)
01
:-c;
lo
I<'
// .f)
/)_5,
~D
-;,Ci
orw (feet)
l u, ":1]
(('_?,5"
1C:-,ljj
15, lf::t
1e;.w..::
\ !--,,( ~ .
IS,L [C
l~SD
un . ·~ ,c_;
Lfc 1cc
cy1) /S,c::;l
Samples Collected
Ternpcrature
l0Ci lnlcrval
0
I l9.4
2 [~1,g
3 i <;(' -:z,c;
4 1Q 7.,e;
5 l5CI ~
6 jq tG'
7 i½.-1
8 ,ar,::;
9 1'6.1'2-
10 1</,1\J
II
12
13
I'
15
16
17
18
19
20
Spec·rfic
Conduct once
(µS/cm)
·~1
-=t--1--61
:::,--,,,o
·:~()
/ K ✓J ,-
1-(()
::+--'.:)-Of
?-'.'.}'.'.}
·1-1-1-
-+::J--1---
pH (su)
l:,, 10
G,51-
r~-~
;: .I. c;
(,,, l !',<
G,,LV::\--
G~I
G LIQ
r. ~{'\
<:;_55"""
Turbidity
(NTU)
c;_s
..., . Cl,
l , "1
0.(
oi:b
n "0
n.An
(),r-(J
0,DD
0,00
Preservolive
Dissolved
Oxygen
(rng/l)
D. roe;
o.3~
fl l/ s-
(\, ~)l/
n~ r;;:f·
('),C.i
() ?,<;(
(() '7 :::t
f), ?C:
0.2J-I
ORP (rnV)
-!rf\.;;-
·--CjQ' ~
_q9--_
-Cfl/ -·-. ~ " 1-#
~-°11, ,
-9/. l
_QC
1--il--ri ,Q
-f,~'7 _'x
I
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--.:;;;z\,ll.,.L..JJl-'"------1-'"-"-'.:,J.,{J-'--"-'-"--------U..l-'-;-~--'.,1..-'-'-'-'J--"'-'-'+--'Z/'J"
0 f-t 0->'
-:-tr-->-35' 6.~"---1 Prnarneler Conditions: p
+/-I NTU below 10 NTU +/-lOmV
CNA/Ticono
Low-flowGroundwoter Somping Log
II
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Low-Flow Groundwater Sampling Log
Kubal-Furr & Associates
-E11viro11111e11tnl Co11s11/ln11t~ -
Project No.
Sile loco/ion CNA/Ticona -Shelby, NC
Field Personnel {,k___
:;;(
Well I Sample ID Q-J J gt:') -Weather Condi/ion .... Jl1.\),<..A1 ,fc:;,i Sample Dale --J, UL, Arrival nnic lrJ..{ Sample Time /6,...-;:\
DesoiplionolMeLdngl·•-r;-;. I Cosingfype[&J.~._,. LockingC□pi -__,,,,. CasingGz:J( Point (MP)_~ {.,L,===------~ '-~ Diameter . ,, '--~===:::'..---~ . rnchei Purge Method~tSJ'J1t.i~ Somplin/g Method[ri.J'i.,'.1/)'L,7.:.
Purge Start rime/ /S:'JL/ Purge Stop Time_l _/,_,~,'.,/4-2:!--,~-----P-u-,g-e_R_o_le"E,-.-~--, -,,m~.,1
Water-Level Measurements Field Parameters
111lcrvul
.
If
I
2
3
'
5
6
7
8
9
10
II
12
13
"
15
16
17
18 ,,
20
[lctJm..' li111c
(nlins)
0 --~
/0
1-..<
::0 X ;t so
Jr
OIWpcct)
lfl/o
/.l; 1,-t
t.f,'{)
,J.f)
/,r,C/3
~
I J-,¥ 3
IS,.'t3
Samples Collecled
Porame!er Conditiom: pH
Turbidity
tc
lnte1val le111µc1nlurc
rc1
If --
I I·;:; 71
2 /7.--S-\,\
3 i 9 (,,J
' I '/117
5 19.-.:;o
6 11.'17
7 /'ls'!
8
9
10
II
I 2
13
"
15
16
17
18
19
20
5pccilic
Conduclance
[µS/cm)
~
.S-lo1
.Sln .'.)
,; t, ~_...
.S?/
-~ 7]
S-7.Y
..:s-S3
Container Descr1phon
Ir Z 04 f Cteirx. <c:-t.;r. f
pH rsu)
-
~&(
s...s:7
S:sJ
s,s9
5-lo(
~ &,(
.s: 0?
Tu1bidily
[NJUJ -a,fo
lb
/, C)
6. 'r~
(3//.{
,;;ko
o.~o
Prescrvol1ve --
+/. 0. ! standard unit COND/Temp +/-3% J DO
+/-10% above 10 NTU +/-1 NTU below 10 NTU ORP
Dis~olvcU
Oxygen ORP [mV)
/mg/L)
·--
0.i(/
a hb
0. 31,/
(l.3c.,
0)7
[},').'/
tJ, J. l/
+/-10%
+/-IQmV
-
)'7,t.f
]7.4
:;-<. :J.
30.1
-;;9, 0
'7!.)
J1,7
CNA/Tlcono
Low-HowGroundwoter Somp!ng Log
Purged Well Sampling Lag
Kubal-Furr & Associates Project No.
Site Loco/ion CNA Holdings/Tlcona, Shelby, NC
Field Personnel 61:
-Enviromneutal Co11s11lta11ts-____ __,:.:.: _______ _
Well/ Sample ID --Y--::Z::--__j_
<f:~ ~ ll Wea'J;;dition S'uN>d7 1 ;t_,,~~ t:l-/
Sample Date __ L!_!!_ __ /_ c___ Arrival Time _________ Sample Time ~,t;L C,7 "/)
Description of Measuring~ . ~-. 8 Casing~ Paint {MP[ 0 C Casrng Type { v'C Locking Cap ...,--Diameter O'-
inches
fatal Depth of Well BeMIOPW?I t,/ 'I, 0. r lee,I _ 1 /-, q SJ _ Common Gallons per Foot Conversions
Depth to Water Below MP?I •'5 3, c; 3 leell
Column of Water in Well?I J-", 9 r) I
:=· =====.,t.==='•=e~•
Gallons of Water per Foot[ 0 /I_ J I
{see chart}? ·, It}
:====;::::::;:::::=g=ol/l~oot
Gallons of Water in Well?
Gallons of Water to be
Purged {3X}?
/,L/6 gall
l 1/4 in Well Casing= 0.064 gal/ foot
1 1 /2 in Well Casing = 0.092 gal / foot
2 in Well Casing= 0.163 gal/ foot
3 in Well Casing = 0.367 gal / foot
3 1/i in Well Casing= 0.500 gal/ foot
4 in Well Casing= 0.653 gal/ foot
6 in Well Casing= 1.469 gal/ foot
Purge Method? ~l,,:j7C 1· Total Gallons Purged I 7, ' ,-I
;=:· =::::;:·;::::\J==:=::gol
Purge Start lime ~I _ __,Oy7.--"-fr-'>V'"'-1-''.3'--_ ___,I Purge Stop lime LI ___ o_· _Y_3.o,6,:_ _ ____JI
Volume Purged
Time
Temperature
Specific Conductance
pH
DO
Turbitidy
ORP
6 got
OC)ci3
/J",!>l 0 c
t? µS
S:SJ std units
/ i &(,a/L
l I NTU
& /) V mV
Samples Collected
2 3
/.~ gal '3,o nol L(_ 0,
nol
(]708-rJ9 I '-f ocrr?
/ ~, 060 c If 1k;c /9,co oc
7f µS 7f µS '?(o µS ,,--'1 V • '-{ 1td units {. i td,n;t, ~19 " std units
:>, 56mo/L f 3.s:,n/L '1.9o mn/L
So NTU '37o NTU J:,oo NTU
.sf,~ mV foto mV &•{,). mV
Container Description
l/l{:;,J'cJ'(, ,U(/'.) //((L
4 5
l ool 7,<gol
rJ<;zt/ 011~'7
Ji ' . 9j oc /J,7/0 c
'7o µS S-J µS
51'> -----13
~ sld units ~, std units
~' f"J mo/L I)( mo/L
Jou NTU )i/t>O NTU
&I.O mV .£7 7 mV
Preservative
/I</
Remarks _____________ ~---------------'-~-.,,,,_-_s_-<;_·o_,"-/~•',,_71:.:t=-·-
h_ 1.i...ilMPwf-l(...{11.::iU1Jt...; f1.,·rtA"'hc.. ,":i)(:2,c,t'1)TV8tr1t--8111..-~7)_ ,f;i7;,,.;,t-&·J:'b-'tr-V...,t"lL
Parameter Conditions: pH +/-0.1 standard unit DO +/• 10%
Turbidity +/-10% above 10 NTU +/-1 NTU below 10 NTU ORP +/-tOmV
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Low-Flow Groundwotcr Snmpling log
Kubal-Furr & Associates Project No. '.2C/1J'l\'l9 -£11vinm11w1111l Co11s11ft11111.,-Site Location CNA/Tlcona. Shelby, NC
Field Personnel k:,R,
Well I Somple ID --,U,~--3""£"" . .-------
' 19 \ \ . Weather Condition r\ 1{: '.j () S Sonip/e Date D \ q oY Arr~vol Time l 1-o b Sample Tinie __ +t~_....,_.,,.._ ______ _
OescriplionofMe.asurlng~ Casin T pe. ~ockin Co EJ C .. asing~ Point (MP) 00 9 Y 9 I-' Diameter t--. 1nch"'1
Pu,ge Method: ~ Th (,I mpling Method) F 4\-a fu(, I
Purge Start Time._,µw,......~~~] Purge Slop TTme) \ 'QoS ) Purge Ro!rt.E,2.J2111mcnl Water-Level Measurements Field Parameters
111/ervol
0 r;( ·--t'lS<:
I 6 ,z_f , 7'.A-
2 (() 2./. LfC
3 IS '7.l ,{A'
4 20 1:i J C-,t·
5 2.5' hi l,q
6 "?-,0 "7 1,1"0
7 -::i,:;-..zl .':l-G
8 L () .21.:\D
9
10
II
12
13
14
15
16
17
18
19
20
Sornpl~s Cnll,~c.lcc.J
lnte1va/ Temperature
('C)
0
I l"?_o_on
2 19.SI
3 1q_30
4 \q_ '3 I
5 ill ~=t
6 l"'!,;-i
7 \ Cf' I l:;'
8 l'f.'2....'.J
9
10
II
12
13
14 .
IS
16
17
18
19
20
Specific
Conductance
/pS/cm)
Lil
/... 1.1
l . ·".2,
'' '=i U?
I l 0
i..l-',z.._
Y1-
Container 1.Jcscr1pl1on
pH (su)
Lf,6:J...
l./_<;(...,
4,io
4_q-ci
LI _-:=,--3
t-1 .:rs
,\{ ,q-c;
Lf-1--4
Turbidity
(NIU)
/-) ,{,
t,J)
n.n
n.n
n,o
ri,D
ri, ()
t"7 n -
I rescivulivc
Dissolved
Oxygen
(rng/L)
7_ 'C-t"J
'7 02
'7 , l '7
-~.S9
2. ?...1 j
2.03
i 'q c::;-
I. ~S<'
ORP (mV)
31./99
1 _=,71.f '2
'?, /\"./-, $
?_qx oc
21'1--,'
2-RR,x'
,QJ. ~
'-~.CJ
. 0 $1,I { 3 (), )~ 1 t,\~-\ pl-\>i -----~-=--,±,.,..-t----=.:-;r---t-t--------,,-....--,;a,--=-~ v-..z.t 6Al. J'urur11ctc, Co,1<.li!iom:
TurbicJHy +/-10% above 10 NTU
+/-3%
+/-I NTU below 10 Nru
+/-10%
ORP +/-I0mV
CNA/Ticona
Low-FlowGroundworerSompling log
I l
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Kul>al-Furr & Associates
-[11viro11111c11111{ Co11:,;11Jt1111/~ -
Low-Flow Groundwater Sampling Log
Project No.
Sile Localion CNA/Tlcona -Shelby, NC -~~7:2--~-~~-
Field Personnel L.7l\.,. --~~-,'~-----
! Well I Sample ID V-f:::,,S""' cf; . -/L Weather Condition ___ ..(';..c'-'c..cN~' fVi_,'---"<f-i_· _<' __ _ Sample Dote 3/IJ ( Arlivol Time (o3 ( Sample nme ____ ,_'3''-e,-=-"-----
Oesc,ipnon ol Mcmuringl ___, IC .1 1 p @z::._· L ,-C EJ Casing[L] Po·,n1 /MP) </, ri Q/ mu g y e . oc mg op ;,, '--Diameter ;,,ch-,i
Purge Melhodl 'f{~J ~Z../7C.
Purge Start lime I lzd?) -
Water-Level Measurements
Interval
0
I
2
3
'
'
6
Elopse lime
(mins)
()
s·
lo
rs-'
J.t>
2:{
'3o
OTW (feel)
/d3.s-
l/,i./J:'
/2..~-
12,9.s'
;'3,fcZ.
li~.'J.
(cf.&'7
lntc1vol
0
I
2
3
'
'
6
Sampling Method/--f,-~--_? ___ _
Purge Stop Time I t&s-I
Temperolure
('C)
.-
'J_O,)S
_;h,'7'-(
'2c,,7,J"
Zo_J-u -
~,s:i
'J.tJ,r-6
Field Parameters
Specific
Conductance
(µS/cm) -
'tf-11
lf9Z... s·.,,c;
1./,f,,
'-(;J t.,
3?1
pH (su)
-
0.99
&.ft/
C,, 7'1
&,17
(,,,-7,,
(c, r,,.s'
Purge Ra!e,k.J ~ ml/mini
Turbidity
(NTU)
--
L/.0
0,9'5"
i.7
O,l,,S"'
()_{£
o.s
Dissolved
Oxygen
(nig/l)
-
/ . ..S-/
0,7f,
d,'{3
,,, '5'-j
t',3tf
0.'3']
ORP (mV)
~
-f7.l
-;i--5.(.,
-:;,-s:-3
-?( {
-,f3,f
-79, ~
7 '3s-,~,~-7 ;Jt!,t/c 5«-(J l, &<o oss o.3"':> -79. '{
8 if rJ r.s.-, ~"
9 4,S 16,,•!
10 ,.)C i{p_ ~'I
II
12
13
14
15
16
17
18
19
20
Samples Collected
(. ,oc
Parameter Condit'ions: pH
lurbidity
8 ?-o. ti<{ ·'3-50 b..cP7
9 Jo,3S-'sJ-1 to, lo 'J
10 /0-~ 1-:f't' {,-,, 7o
II
12
13
14
15
16
17
18
, 19
20
Container Descnphon
txtC
+/-0.1 standard unit
+/-10% above 10 NTU
COND/Temp +/-3%
+/-l NTU below 10 NTU
0,&< 0, -3 ",I--78',7
0.fs-" 0, 32.. -7'i-: .9
Ci,\S'"o 0, 3;z -7?_ I
Preservallve
;pu~)
DO +/-10%
ORP +/-10mV
'
Cf'IA/Tlcona
low-FlowGroundwoler $amping Log
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Kubal-Furr & Associates
-E1miro11111c11t11! Co11s11/t1111b -
Low-Flow Groundwater Sampling Log
Project No.
Site Location
Field Personnel
CNA/Tlcona · Shelby, NC
RK
Well I Sample ID --"iA,.,l_--c'z..=3~-----
We21Per Condition \At"!. q t,':5
Sample Date -...LC=!.4-c~:±:~:!::;----~ Arrival Time { 2=-P~ Sample Time ~
OescriplionolMeasuring [(Or CasingType~f' Lockin Cu)I ✓-I _CmingG:J Point (MP) V -;J :) g I D1amelcr L-,,.
,nch~I
Pu,geMelhou[ ~\~
1\fjd SampllngMelhud/ p.:,,t1:Miil·-hc.J
Purge Slar1 Time/ (1;,$~ Purge Stop Time I ( '3 ! <: I Purge Ru1el5:"2.(f),I1minl
Water-Level Measurements Field Parameters
lnlervo!
0
I
2
3
4
5
6
7
8
9
10
If
12
13
14
15
16
17
18
19
20
Elapse Time
frnins)
,()
'5
lo
I~
1..o ?-<
~/')
DTW (feet/
l<;. -,pi
. C, '-t'1"
iS'} f
S.l 1
l5,\f9
I ,c .,r:
1~1.V
Samples Collected
Jnlervol
0
I
2
3
4
5
6
7
fJ
9
fO
If
It!
I]
14
15
16
17
18
19
20
Temperature
fCJ
')(\ _rq
.:2.o,I~
·20, I 7
\q tlc,
.-,,... ,, -:2
·::Z.o, o\
SpecHic
Conduclonce
f~1S/cm)
iC.~
{y~
I c;-q
, (,,--?
Ir. cl
1u..
Conto1ner Oescnphon
pH (su)
~ ,n-1.,
~-D'.7
S.c£..
c;.r\':)..-
c; .o:i-
S.n9
Turbidi1y
[NIU)
o.rn
,.., l"V',
o,e;0
n .t1r
n,nT\
D,CO
Preservative
-
Dissolved
Oxygen
(n1g/LJ
4-' c:;-p
4_.;z,c;
4.lr
4.0 1
t . l.~
l J\4
ORP (mY)
Rnn.l.J
2.q<f_t)
2-9:3:"J
21-l/.l
2C,b..
~_<
, ,
Remo,ks, _ __:;:>J..tf.J:..-1.IL.'-------'-"-"'-"'CL!..!.....,,_ ___ __.::i,=......,.:.!,"'"'-'--="-3-+C'-""Q,_.;.<».,i;:,.,1,.c,MAOH f h "? 7 ===============JJ;@~=::::ri2s:i~=~1~c:;;~~IT:======l~11;cJ[IGlfi2:-:: -2.... (s, At.. PorClrne!er Condi!ions: pH
Turbidity +/-10% above 10 NTU +/-1 NTU below 10 NTU
DO
ORP +/-lOmV
CNA/Tlcono
Low-FlowGroundwoter Sampling Log
Kubal-Furr & Associates
Low-Flow Groundwater Sampling Log
Project No,
-[11vircm111i:J1t11/ Cu11s11/tm1/~ -Site location CNA/Tlcona -Shelby, NC
Field Personnel ___ ...:6t:=---.c;>---=------
D~ /4 Welt I Sample ID If-)3 (J I/ e, 1· Weather Condi/ion .{' J,vl-'/ '7c; /' Sample Dole J Arrival nmc /03/ Sornple Time / 3 O
Desc<iplion ol ~~~~~~np~~~sing Type I .S'ffcL I Locking c□{~2] 0,;,;:~~~~ '2 ,o,J
Purge Method/ ?{?ltSr,....tpc..... Sampling Methodl~Pt'J/;t-z/7._ 7~;!-;:-.,-£.,.V
Purge Start Tirne) /4:?.J Purge Slop Time/ / / J 7 / i;::rge Ro1ek/SDml/min/
Water-Level Measurements .. Field Parameters J
Interval
0
I
2
3
'
Elapse Time orw (teet) (mins)
C> It ?o s-I l <(o
10 /,Jl,fc, ,~ /3,06
"'./--cl (3,of-
0
I
2
3
4
Temperature Specific (oCJ Conductance
[µS/cm)
pH {SU)
---
10,1( -.s3.r3 S", 17
19, 9~-S3-✓o i9l
/'i, "7{ c5""3 k> </, 9,f
/?,73 s'3b9 L/, f,
Turbidity
/NTUI
---"----
_s,(:,
0.3~
o.J..6
a.to
Dissolved
Oxygen
(mg/L)
~
o,fc
tJ-so
0,3£-
0,'3S-
ORP {mVJ
---
G, :3,-Y
t<{. 7
{,<f, 3
lb/. y
5 }-,: I 3, 17 5 I 'f,7'-{ s JS:3 tf 9i (J,(6 0,3o' 'J:c'-/.S
' <3c, 13.);)_
7 3-s-I J., 2\:-
8 .4"t? . ('3,2 3
9 «~ I 3,;;1;:J.
10 <S"O ;3,Z/
II
12
13
14
15
16 .
17
18
19
20
Sornplcs Colleclf!d voe,
Parameter Conditions: pH
Turbidity
6 I t;-,'7'-{ s'3f7 l{.99 G,(b tJ, ).9 .s-9,7
7 I L/, 'J(.,, s 39,S"" .5:oo ctro 0,) J-f,,o,)
8 /C/CJ.S-,S'lt9 S",o)., oJo 6, 1/c ho1 I
9 (10,i! 7 S'-{ 36 .:r-, ,, '( OJe O.l-7 S-9, I
10 2£;,10 ,Sl{l3 0:CJ••-{};2c (J, -Zf o7.C/
II
12
13
14
15
16
17
18
19
20
Container Dcscriplion Preserval1vc
'l<rtOa
+/• 0.1 standard unit
+/-10% above 10 NTU
COND/Temp +/· 3% DO +/-10%
+/• ! NTU below 10 NTU ORP +/-lOmV
CNA/Tlcona
Low-FlowGroundwoter Sampb'ng log
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