NCD003446721_20040827_Celeanse Corporation - Shelby Fiber_FRBCERCLA RA_OU-1 Semiannual Report January - June 2004-OCR

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Kubal-Furr & Associates
------------Environmental Man~gement Services
Post Office Box 273210
Tampa, FL 33688-3210
[phone]
FAX [phone]
Mr. Kenneth Lucas
Remedial Project Manager
U.S. Environmental Protection
Agency, Region IV
61 Forsyth Street
Atlanta, GA 30303
Dear Mr. Lucas:
August 27, 2004
Post Office Box 80247
Simpsonville, SC 29680-0247
[phone]
FAX [phone]
On behalf of CNA Holdings, Inc., we are pleased to enclose two copies of the report entitled:
"Operable Unit 1-Semiannual Report-January 2004-June 2004-CNA Holdings,
Inc.-Shelby, North Carolina." By way of this letter, we have also transmitted a copy of the
report to David Mattison with NCDENR for his review.
Please contact me at 813-265-2338, to discuss any questions you may have following your
review of this document.
Sincerely,
Kubal-Furr & Associates
.~~
Jer~y J. Kubal, P.G.
President
cc: Mr. David Mattison, NCDENR
Mr. Steven F. Olp, Celanese International
Ms. PEM Carter, Ticona-Shelby ESHA
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Contents
Page
Acronyms/Abbreviations .................................................. iii
Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
Work Performed . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
1st Quarter 2004 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
2nd Quarter 2004 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
System Performance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
Inner Tier Extraction Rates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
Ground-Water Movement .............................................. 6
Treatment Efficiencies . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
Maintenance Activities . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
Analytical Test Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
Review of Selected Historical Water-Quality Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10
Table 1.
Table 2.
Table 3.
Table 4.
Table 5.
Table 6.
Tables
2004 Sampling Matrix-CNA Holdings, Inc.-Shelby, NC
Inner Tier TOC (Total Organic Carbon) Data (January 2004 • February 2004)
Inner Tier Production Data (January 2004 · February 2004)
Summary of Selected CERCLA-related Water-Quality Data (1st Quarter 2004)
Summary of Selected CERCLA-related Water-Quality Data (2nd Quarter 2004)
Summary of Selected PEW-related Water-Quality Data (1st Quarter 2004)
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Figures
Figure 1. Site Location
Figure 2. Potentiometric Surface Map-Shallow Saprolite-March 1, 2004
Figure 3. Potentiometric Surface Map-Deep Saprolite/Upper Bedrock-March 1, 2004
Figure 4. Hydrogeologic Cross Section A-A', Marchl, 2004
Figure 5. Potentiometric Surface Map-Shallow Saprolite-May 20, 2004
Figure 6. Potentiometric Surface Map-Deep Saprolite/Upper Bedrock-May 20, 2004 I, Figure 7. Hydrogeologic Cross Section A-A', May 20, 2004
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Attachments
Attachment 1. Summary of Activities Performed During Decommissioning of the Ground-Water
Treatment System (Earth Tech)
Attachment 2. Operation and Maintenance Data (January 2004 -February 2004)
Attachment 3. Analytical Data for the 1st and 2nd Quarter 2004 Sampling Events
Attachment 4. Selected Water-Quality Plots
Attachment 5 (Back Cover). CD with pdf of Semiannual Report
ii
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I CERCLA
CFO
I CNA
DENR
I EPA
Fil
FP I, GC/FID
!MAC
I ITC!
ITEF
I LTRA
MCL
MEK
I mg/L
MNA
I NPL
OTC!
OTEF
I OU-1
OU-2
I PCE
PEW
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ppm
ROD
SBR
I svoc
TCE
I TCLP
TOC
voe
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Acronyms/Abbreviations
Comprehensive Environmental Response and Liability Act
Celanese Fiber Operations
CNA Holdings, Inc.
(North Carolina) Department of Environment and Natural Resources
U.S. Environmental Protection Agency
Fiber Industries, Inc.
Filter Press
Gas Chromatograph/Flame Ionization Detector
Interim Maximum Allowable Concentration (North Carolina)
Inner Tier Combined Influent
Inner Tier Effluent
Long Term Remedial Action
Maximum Contaminant Level
Methyl Ethyl Ketone (2-Butanone)
Milligrams per Liter
Monitored Natural Attenuation
National Priorities List
Outer Tier Combined Influent
Outer Tier Effluent
Operable Unit 1
Operable Unit 2
Tetrachloroethene
Polymer Extraction Well
Parts per Million
Record of Decision
Sequencing Batch Reactor
Semivolatile Organic Compound
Trichloroethene
Toxicity Characteristic Leaching Procedure
Total Organic Carbon
Volatile Organic Compound ·
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CNA Holdings, Inc./Ticona---Shelby, NC-Ql/Q2 2004 Semiannual Report Pagel
Introduction
Ticona, an operating subsidiary of Celanese, owns and operates a polyester and engineering
plastics production facility in Shelby, North Carolina. CNA Holdings, Inc. (CNA), also a subsidiary of
Celanese, retains management of environmental matters for the corporation and thus, is responsible
for the work performed during the semiannual reporting period. The Shelby site consists of an
approximate 450-acre piece of property which includes the main plant production area, wastewater
treatment area, former waste disposal areas, and recreational areas. The plant is located in south-
central Cleveland County, bordered by NC Highway 198 to the west and Lavender Road to the south,
approximately one mile north of Earl and six miles south of Shelby. A site plan showing the location
of production areas, monitor wells, extraction wells, and other significant features is shown on Figure
I.
Operations at the site began in 1960 by Fiber Industries, Inc. (FI!), a manufacturer of polyester
chips and filament yarn. Celanese Corporation bought the facility from FI! in 1983, renaming it
Celanese Fiber Operations (CFO), and continued the production and processing of polyester polymer
chips and fibers. The site has alternately been known as HNA Holdings, Inc., Hoechst Celanese
Corporation, and Celanese Fiber Operations, the latter being the site name as listed on the National
Priorities List (NPL).
CNA currently operates a long term remedial action (LTRA) system at the CFO site, designated as
Operable Unit 1 (OU-1) in the Record of Decision (ROD), which consists of two ground-water
extraction and treatment systems identified as the Inner Tier and Outer Tier systems. As noted below,
implementing recommendations in the August 2001 Five-Year Review Report, the Inner Tier was shut
down on March 1, 2004 during evaluation of an MNA (monitored natural attenuation) demonstration
project.
OU-1 became operational in August 1989. A second operable unit, OU-2, consisted of
excavation, incineration and reburial of stabilized incinerator ash and other inert waste materials. As
part of this effort, CNA maintains and monitors the effectiveness of the ground-water recovery and
treatment system; collects quarterly ground-water levels and samples from selected monitor wells and
process points; and, reports the status of these activities to the EPA (Environmental Protection
Agency) and DENR (State of North Carolina Department of Environment and Natural Resources) on
a semiannual basis.
On April 21, 1998, OU-2 and the Outer Tier portion of OU-1 were shut down as part of a partial
( delisting petition approved by the EPA effective April 17, 1998. Currently, active ground-water
recovery and treatment is only taking place at the Inner Tier, which was designed to extract
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contaminated ground water from around a former source area remediated as part of OU-2. Although
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CNA Holdings, lnc./Ticona-Shelby, NC-QJJQ2 2004 Semiannual Report Page2
the Outer Tier is not actively recovering ground water, Outer Tier well OT-lR is still pumped to
provide make-up water for the ground-water treatment system and for process water used for back-
flushing filters. The entire Outer Tier is being maintained in "stand-by status" as part of the delisting
process and can be brought on line within a relatively short period of time if it is found necessary to
provide hydraulic control along the property boundary. The Outer Tier wells and treatment system's
functionality is assured by performing routine monthly and quarterly system checks such as
energizing the well pumps, transfer pumps and blowers, verifying heater operation, etc. and
performing maintenance activities as required by the routine system checks.
Kubal-Furr & Associates (Kubal-Furr) has prepared this semiannual OU-1 operating summary
report for submittal to the EPA and DENR on behalf of CNA. It covers the period from January 1,
2004 through June 30, 2004 and includes information on system performance and the results of
analytical testing of samples collected during the period February 25 -March 8, 2004 and May 25-
26, 2004.
In addition to the routine quarterly sampling, several significant activities occurred during the
reporting period. These include:
•
•
•
On November 3, 2003, Kubal-Furr and Earth Tech prepared, on behalf of Celanese, a
document entitled: "Request to Modify Elements of the Record of Decision (ROD) for
Operable Unit 1 (OU-1) at the Celanese Fiber Operations Site, Shelby, North Carolina." This
document was submitted to the EPA and DENR in support of the request to modify selected
elements of the remedial alternative contained in the OU-1 ROD. The EPA found the
proposed change to be significant but not fundamental and an ESD (Explanation of
Significant Differences) was utilized to accomplish the modifications which became effective
on April 23, 2004.
Implementing EPA recommendations contained in an August 2001 Five-Year Review Report
for OU-1, CNA turned off the Inner Tier recovery well system on March 1, 2004 while it
implements and evaluates an MNA Demonstration Project (described below).
Subsequent to approval of the ESD and Inner Tier shut down, Earth Tech and Ticona
implemented a plan for decommissioning the SBR (sequencing batch reactor) and ground-
water treatment system. Details of. these activities are presented in the summary report
contained in Attachment 1.
In June 2004, Kubal-Furr submitted to EPA and DENR on behalf of CNA a document
entitled: "Monitored Natural Attenuation Demonstration Project Work Plan-Operable Unit
1-CNA Holdings, Inc./Ticona-Shelby, North Carolina." This plan was the second revision
to the original document prepared December 2001 and followed a series of written comments
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CNA Holdings, /nc./Ticona-She/by, NC-Ql IQ2 2004 Semiannual Report Page3
and responses, telephone conferences and site visits between CNA, EPA and DENR in the
development of an approvable MNA work plan. A sampling program contained in the work
plan was implemented with EPA and DENR concurrence during the 2nd Quarter of 2004. In
accordance with the work plan schedule, a data report summarizing the 2nd Quarter of 2004
MNA data set will be submitted to the agencies during the 3rd Quarter of 2004.
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CNA Holdings, lnc./Ticona------Shelby, NC-QJ /Q2 2004 Semiannual Report Page4
Work Performed
As part of the OU-1 remedy, samples are collected at selected monitor wells and at points in the
ground-water treatment system. In addition, samples are collected from the inactive polymer
extraction well (PEW) system and selected PEW-related monitor wells. The location of all monitor
and extraction wells is shown on Figure 1. A list of sampling locations and the parameters analyzed
during the 1st and 2nd Quarters are summarized in Table 1. A description of the work performed
during this reporting period is provided below.
1st Quarter 2004
On Marchl, 2004, water levels were measured by Kubal-Furr in a total of 104 monitor wells,
extraction wells, and piezometers. A total of 13 CERCLA-related ground-water quality samples and 2
process point samples were collected during the period February 25 -March 9, 2004, in accordance
with the sampling matrix shown in Table 1. All samples were collected by Kubal-Furr and analyzed
by Davis & Floyd Laboratories of Greenwood, South Carolina.
OU-1 Monitor Well Sampling
Thirteen monitor well samples were collected using low-flow sampling protocols. The samples
were analyzed in the field for pH, temperature, conductance, turbidity, dissolved oxygen (DO) and
oxidation reduction potential (ORP); and, by the laboratory for volatile organic compounds (VOCs)
using EPA Method 8260B. In addition to analysis of volatiles, samples from monitor wells K-28 and
V-23 were also analyzed by the laboratory for total organic carbon (TOC) using EPA Method 9060.
OU-1 Process Point Sampling
Samples of Inner Tier influent and effluent were collected for analysis of volatile organics by
Method 8260B. The Inner Tier influent and effluent samples were also analyzed by the laboratory
for TOC by Method 9060, and for ethylene glycol by GC/FID (gas chromatograph/flame ionization
detector).
During the reporting period, influent and effluent samples from the Inner Tier were also collected
by Earth Tech personnel for analysis of TOC by Davis & Floyd. These samples are collected weekly
to evaluate treatment efficiency, and the results are contained in the O&M reports provided in
Attachment 2. These results are also summarized in Table 2.
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CNA Holdi11gs, lnc./Tico11a-Shelby, NC-Ql/Q2 2004 Semiannual Report Page5
PEW Extraction @d Monitor Well Sampling
Three inactive PEW (polymer extraction well) grab samples were collected during the 1st Quarter.
These samples were analyzed in the field for pH, temperature, conductance, turbidity, DO and ORP;
and, in the laboratory for VOCs by EPA Method 8260B and for SVOCs (semivolatile organic
compounds) by EPA Method 8270C (including the DowTherm®A constituents 1,1-biphenyl and
biphenyl ether).
2nd Quarter 2004
On May 20, 2004, water levels were measured by Kubal-Furr in a total of 118 monitor wells,
extraction wells, and piezometers. Water-quality samples were collected from two monitor wells and
analyzed for the parameters summarized in Table 1. Samples were collected on May 25-26, 2004 by
Kubal-Furr and analyzed by Davis & Floyd. As noted earlier, the Inner Tier extraction well and
ground-water treatment systems were shut down on March 1, 2004, and therefore, no process point
samples were collected during the 2nd Quarter.
Monitor Well Sampling
Monitor wells K-28 and V-23 were sampled during the 2nd Quarter sampling event. These wells
were analyzed in the field for pH, temperature, conductance, turbidity, DO and ORP; and, by the
laboratory for TOC by Method 9060.
Free Product DowTherm®A Bailing-Well F-55
As discussed in earlier semiannual reports, free product DowTherm®A was found to be
accumulating in monitor well F-55 following a monitor well rehabilitation program implemented in
September 2001. Prior to the current semiannual reporting period, well F-55 was sounded/bailed on
11 separate occasions and the total volume of DowTherm®A recovered was approximately 2.14
gallons (8.08 liters). Well F-55 was tested during the 1st and 2nd Quarters using an interface probe
and was found to have accumulations of product of 0.14-ft on March 1, 2004 and 0.13-ft on May
20, 2004. Free product in F-55 was bailed on these two occasions and approximately 0.07 gallons
(0.27 liters) of free product was recovered, bringing to 2.21 gallons (8.35 liters) the total amount of
DowTherm®A recovered to date. This well will be tested again in the 3rd and 4th Quarters of 2004
and any further free product accumulations will be removed and recorded.
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CNA Holdings, Inc./Ticona---Shelby, NC-QI/Q2 2004 Semiannual Report Page6
System Performance
Detailed records of system maintenance are kept by CNA and are summarized monthly. The
monthly records for the current reporting period are contained in Attachment 2.
Inner Tier Extraction Rates
Prior to shut down on March 1, 2004, the Inner Tier wells extracted a total of 81,651 gallons
(Table 3). Inner Tier flows ranged from a low of 38,470 gallons in January 2004 to a high of 43181
gallons in February 2004. The sequencing batch reactor (SBR) treatment system is designed to
process a maximum of about 2,500 gallons of water per day from the Inner Tier extraction well
system. With 60 days in the reporting period, at design capacity, pumping from the Inner Tier would
have been some 150,000 gallons. Based on the pumpage during the reporting period, the Inner Tier
extraction system was producing at a rate of about 54% of the design capacity.
Ground-Water Movement
In order to accurately predict the direction of ground-water movement, water-level measurements
were collected from all accessible monitor wells, extraction wells and piezometers on March 1, 2004
by Kubal-Furr, and again on May 20, 2004. These data were used to construct potentiometric surface
maps and hydrogeologic cross sections (Figures 2 thru 7).
The shallow saprolite maps (Figures 2 and 5) show water-level contours and direction of ground-
water movement in the uppermost water-bearing zone beneath the site. The direction of movement in
this zone is to the east from upgradient areas along NC 198, towards discharge areas along the
unnamed tributaries of Buffalo Creek.·
An attempt was made to separate the uppermost water-bearing zone from the deeper saprolite and
upper bedrock zone. While these maps (Figures 3 and 6) present a reasonable picture of ground-
water movement in this zone, it should be pointed out that it is giving a somewhat more generalized
picture of ground-water movement because of the well construction techniques used in many of the
wells and piezometers. The typical construction of these wells was to have relatively long screens and
extremely long sand packs in the annular space above the screens. As a result, the lower
saprolite/upper bedrock maps have a number of composite head values measured along a longer
screened area. However, the maps may be useful for determining the general direction of ground-
water movement.
To confirm inferences made about the direction of movement and hydraulic control exerted by
the Inner Tier system, hydrogeologic cross sections were constructed from the March and May data
sets (Figures 4 and 7). The location of the cross section is shown on the site location map, Figure 1.
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CNA Holdings, Inc./Ticona-Shelby, NC-QI/Q2 2004 Semiannual Report Page7
The east-west cross section (A-A') is constructed through the plant from upgradient areas west of the
plant to downgradient, off-site areas east of the plant. The east-west hydrogeologic cross section
indicates flow is predominantly horizontal across the site, from upgradient areas west of the plant
toward downgradient areas to the east.
Treatment Efficiencies
Two aspects of the extraction system performance were reviewed for this semiannual report: the
production rates achieved during the reporting period, and the removal efficiencies for TOC from the
Inner Tier system.
Table 2 summarizes the treatment system effectiveness of the Inner Tier in removing TOC for
January and February of 2004, the two months of the current reporting period during which the
Inner Tier was in operation. This table was prepared from the individual monthly operation and
maintenance reports provided by the plant (Attachment 2), which contain water-quality data collected
weekly by Earth Tech personnel and analyzed by Davis & Floyd. During the reporting period, the
Inner Tier average removal efficiency for TOC was approximately 87%, with an average influent
concentration of 1293 ppm (parts per million), and an average effluent concentration of 162 ppm.
Maintenance Activities
As part of the Inner Tier shut down and implementation of the MNA Demonstration Project
Work Plan, the Inner Tier wells had the dedicated bladder/submersible pumps removed so that they
could be used as low-flow sampling points. The entire Inner Tier system is being maintained in the
interim in the event active recovery resumes as part of the site remedy.
In the request to modify selected elements of the OU-1 ROD which was summarized in the ESD, a
decommissioning plan was presented for the SBR and ground-water treatment system. This plan was
implemented following Inner Tier shut down on March 1, 2004 and the activities performed during
the decommissioning are summarized in Attachment 1.
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CNA Holdings, lnc./Tico11a-Shelby, NC-Ql /Q2 2004 Semia1111ual Report Page8
Analytical Test Results
Analytical test results, field sampling logs, and chain-of-custody forms for the 1st and 2nd
Quarter data sets are contained in Attachment 3. A summary of selected analytical data for the 1st
and 2nd Quarters is presented in Tables 4, 5 and 6.
CERCLA-Monitor Wells
Of the 13 CERCLA-monitor well samples analyzed during the reporting period, 8 had volatile
organics reported above the detection level (Table 4). Of these eight, six (K-28, T-35, V-23, CC-33,
HH-77 and EE-58) had two or more individual volatile constituents reported as present above the
detection level. The most frequently reported volatiles included benzene, trichloroethene and 2-
butanone (MEK).
2-Butanone and acetone were reported as present in trip blanks associated with samples collected
on March 3 and March 8, 2004, respectively. The associated sample results less than 10-times the trip
blank results were qualified as non-detect ("U") in accordance with the National Functional
Guidelines for Organic Data Revi ~ ected ihonitor well samples shown in Table 4 included K-28,
P-58, CC-33, FF-34, and GG-6 . y(, -v 7-.
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Monitor wells CC-33, T-35, HH-77 and V-23 reported the largest number of individual volatiles
at four each. Benzene was the constituent reported most frequently above a North Carolina 2L
ground-water quality standard (three instances) followed by TCE (two instances) and PCE (one
instance).
Monitor wells K-28 and V-23 were also analyzed for TOC during the 1st and 2nd Quarters. The
K-28 test results for the 1st and 2nd Quarters were 304 mg/Land 1230 mg/L, respectively. The TOC
test results for V-23 for the 1st and 2nd Quarters were 10,500 mg/L and 11,200 mg/L, respectively.
Process Point Samples
Inner Tier influent and effluent samples were analyzed during the 1st Quarter for ethylene glycol,
TOC, and volatile organics. The 1st Quarter Inner Tier influent sample reportedly contained the
volatiles benzene (0.018 mg/L) and chlorobenzene (0.022 mg/L). Inner Tier influent ethylene glycol
and TOC results for the 1st Quarters were reported at 1340 mg/L and 1820 mg/L, respectively.
The Inner Tier effluent sample for the 1st Quarter reportedly contained 2-butanone (0.0075
mg/L) and acetone (0.10 mg/L). Ethylene glycol for the 1st Quarter Inner Tier effluent sample was
reported below the detection limit for this constituent ( <7.0 mg/L) while TOC was reported at 19.6
mg/L
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CNA Holdings, !11c.(Ticona---Shelby, NC-QJ!Q2 2004 Semiannual Report Page9
The Filter Press (FP) and SBR sludges were tested for the full list of TCLP constituents during the
1st Quarter. Barium was the only constituent reported as present at 0.21 mg/L and 4.5 mg/L in the
SBR and FP sludges, respectively. One quality assurance-related issue was the analysis of pesticides
and herbicides outside the 14-day hold time for these constituents. The results for pesticides and
herbicides were all below detect and would be considered qualitative. Review of the historical record
indicates that no pesticides or herbicides have ever been reported as present in earlier TCLP sludge
analyses. Based on the TCLP test results, the sludges would not be considered characteristically
hazardous, nor would they exceed any applicable State standard for disposal in a North Carolina
landfill.
PEW-Related Samples
Three PEW-related samples were collected during the 1st Quarter. Well F-55 would normally be
sampled with the other PEW wells but as noted earlier, a small amount of free product had
accumulated and was removed from this well during the reporting period and no water quality sample
was collected.
2-Butanone was the only volatile constituent reported as present at PEW-3 (0.0065 mg/L). PEW-1
reportedly contained the volatiles cis-1,2-dichloroethene (0.0014 mg/L), chloroform (0.0017 mg/L)
and trichloroethene (0.0055 mg/L). PEW-4 reportedly contained the volatiles benzene (0.0026 mg/L)
and cis-1,2-dichloroethene (0.0080 mg/L) and trichloroethene (0.0064 mg/L).
Two of the three PEW wells (PEW-3 and PEW-4) had reportable quantities of DowTherm®A
constituents (i.e., 1,1-biphenyl or biphenyl ether). 1,1-Biphenyl was reported as present in well PEW-
3 (0.46 mg/L) and biphenyl ether was reported as present in both PEW-3 and PEW-4 (1.9 mg/Land
0.029 mg/L, respectively).
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CNA Holdi11gs, /11c./Tico11a-Shelby, NC-QI /Q2 2004 Semia1111ual Report Page /0
Review of Selected Historical Water-Quality Data
Attachment 4 contains plots of selected water-quality constituents for various monitor wells and
process points. The choice of locations and constituents was based on a review of the water-quality
database, in particular those locations having any meaningful data to plot. In general, only those
monitoring locations within a few hundred feet of the former OU-2 source area have any significant
number of water-quality constituents reported above the detection limits. In order to assess long-term
trends and improvement in water-quality conditions resulting from source removal and ground-water
recovery, the following locations and constituents were selected for review:
• Inner Tier Combined Influent TOC and .ethylene glycol test results. The Inner Tier TOC
increased to 1820 mg/L during the 1st Quarter of 2004. Inner Tier TOC has been fluctuating
within a range of 1,000 mg/L to 3,000 mg/L since 1995 but no long-term or seasonal trends
are apparent from the data set. Similar to TOC, the Inner Tier ethylene glycol concentrations
increased between the 4th Quarter 2003 and the 1st Quarter 2004 from 684 mg/L to 1340
mg/L. The ethylene glycol concentrations have generally fluctuated in a range from 500-
1500 mg/L since 1995 and no long-term or seasonal trends are apparent from the data set.
• Monitor Well V-23 TOC, 2-butanone (MEK-methyl ethyl ketone), acetone and benzene. The
V-23 TOC concentrations began trending downward from a high of 8000 mg/Lin mid-1989
to less than 1000 mg/L in early 1992. Since that time, the TOC data have shown several wide
swings in concentration, with a historic high of 11,800 mg/L achieved in October of 1997.
Since 1996, the TOC values at this well have fluctuated in the range of 3,000 mg/L to 12,000
mg/L, with it not being uncommon to note quarter-to-quarter changes of more than 4000
mg/L.
The V-23 MEK data have generally fluctuated in a narrow range below 1 mg/L, and the last
14 sample results have all been below 0.5 mg/L. The V-23 acetone test results have been
oscillating between 0.1 mg/Land 0.5 mg/L for the past four years, with the last three quarterly
samples reported below the detection level.
While more than half the benzene data for V-23 is flagged as estimated or below the detection
limit, 16 of the past 20 sampling events have been quantitative and show benzene to be
fluctuating in a narrow range of from 0.01 to 0.03 mg/L.
Monitor well K-28 TOC and benzene data. TOC and benzene have both shown a steady
decrease in concentration beginning about the time the OU-2 source remediation began in
January of 1991. The TOC concentrations at K-28 have shown several wide swings in
concentration up to 2000 mg/L during the past two years and these increases were thought to
be related to a well rehabilitation program undertaken in 2001. Although benzene had also
Kubal-Furr & Associates
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CNA Holdings, lnc./Ticona-Shelby, NC-QJJQ2 2004 Semiannual Report Page Jl
•
shown a general decline since OU-2 source remediation, the concentrations have increased
during the past year from 0.0057 mg/L to 0.011 mg/L.
Monitor well HH-48 and HH-77 TCE (trichloroethene) data. The HH-48 TCE test results had
shown a decline from 0.222 mg/L in August of 1995 to less than 0.1 mg/L during the 3rd
Quarter of 2000. Since that time, TCE concentrations at HH-48 had steadily increased to a
3rd Quarter 2003 value of 0.19 mg/L but have receded between the 3rd Quarter 2003 and 1st
Quarter 2004 to 0.015 mg/L.
TCE at HH-77 had been trending upward between 1989 and 1996 when it peaked during
July 1996 at 0.383 mg/L. TCE at HH-77 subsequently decreased substantially to 0.059 mg/L
during the 1st Quarter of 2001, however, the concentration was noted to increase to near
historic highs during the 3rd Quarter of 2001 (0.35 mg/L) and to achieve a historic high of
0.46 mg/L during the 3rd Quarter of 2002. The 3rd Quarter 2003 concentration of TCE at
HH-77 had reportedly receded to less than 0.05 mg/L, its lowest level since 1990, but during
the 1st Quarter 2004, the concentration rose again to 0.31 mg/L.
The presence of TCE at these locations (HH-48 and HH-77) are thought to be the result of a
localized source, unrelated to activities at CNA/Ticona or the former OU-2 source area.
Kubal-Furr & Associates
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-- --- -- - - --- - -
Table 1. 2004 Sampling Matrix-CNA Holdings, lnc.mcona-Shelby, NC
1st Quarter
Monitoring TOC voe Eth. Glycol roe
Location ---.liQ§QL {8260B) (GC/FID) ~
Process Pain ts
fTCI ..J ..J ..J
rm ..J ..J ..J
OT□
OTEF
SBR Sludge (Full TCLP)
FP Sludge (Full TCLP)
Monitor Wells
C-49 ..J
K-28 ..J ..J ..J
P-58
T-35 ..J
V-23 ..J ..J ..J
M-54
CC-33 ..J
EE-58 ..J
FF-34
FF-62 ..J
GG-61 ..J
HH-48
HH-77 ..J
voe svoc
(8260B) (8270C)
PEW-Related Samef!_s
PEW-1
PEW-3
PEW-4
f-55
Notes:
..J
..J
..J
TOC -Total Organic Carbon
voe .. Volatile Organic Compounds
Eth. Glycol = Ethylene Glycol
..J
..J
..J
GC/FID = Gas Chromatograph/Flame Ionization Detector
TCLP .. Toxicity Characteristic Leaching Procedure
SVOC = Semivolatile Organic Compounds
ITO • Inner ner Combined Influent
2nd Quarter 3rd Quarter
voe Eth. Glycol roe voe Eth. Glycol
(8260B) (GC/FID) ~ (8260B) {GC/FJD)
{IT Extraction Well System Shut Down on 3/1/04)
(OT PumE!ng Discontinued on 4/21/98)
..J
..J
ITEF ., Inner ner Effluent
OTCI = Outer Tier Combined Influent
OTEF "" Outer Tier Effluent
SBR = Sequencing Batch Reactor
FP • Filter Press
PEW .. Polymer Extraction Well
..J
..J
..J
..J
..J
..J
..J
..J
..J
voe svoc
{8260B) (8270C)
..J ..J
..J ..J
..J ..J
TOC
(9060)
..J
..J
-- - -
4th Quarter
voe Eth. Glycol
(8260B) (GC/FID)
CNA Hulding.{, /nc/Ticmui-Shelhy, NC
OU-I Semiannual Report (Jun. 'fJ.I -June '04)
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Table 2. Inner Tier TOC (Total Organic Carbon) Data
Jan. '04 --Feb. '04
CNA Holdings, lnc./Ticona-Shelby, North Carolina
( all results reported in parts per million [ppm])
Date Influent
1/7/04 1490
1/14/04 1140
1/20/04 1790
1/28/04 1000
2/4/04 913
2/11/04 999
2/18/04 1210
2/25/04 1800
Average: 1293
Effluent
90
192
177
235
7
222
231
140
162
% Reduction
94
83
90
77
99
78
81
92
87
CNA Holdings, lnc/Ticona-Shelby, NC
OU-I Semiannual Report (Jan. '04 -June '04)
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Well
IT-1
IT-2
IT-3
IT-4
IT-5
IT-6
IT-7
IT-BR
IT-9
Table 3. Inner Tier Production Data
Jan. '04 -Feb. '04
CNA Holdings, lnc./Ticona-Shelby, NC
January 2004 February 2004
Total Total
Gallons ADF* Gallons ADF*
4,447 143 3,853 133
791 26 1,180 41
···················1·&?.1 .... 59 ........ 1,Q78. 37
2,628 85 3,143 108
2,335 75 6,163 213
..................... 1.,1.47 ...... 37 699 24
6,888 222 4,419 152
4,191 135 10,490 362
14 222 459 12 156 419
38,470 43,181
V
•~: ~
Average Daily Flow based on CNA production records (Attachment~
Calculated as total fiow divided by the number of days in the month.
CNA Holdings, lncJTicona-Shelby, NC
OU-I Semiannual Report (Jan. '04 -June '04)
-- --- - -- -- - - - - - -- -
Table 4. Summary of Selected CERCLA-Related Water-Quality Constituents (1st Quarter 2004)
CNA Holdings, lnc./Ticona-Shelby, North Carolina
(All results reported in· milligrams per liter [mg/L])
/ ✓ /
EPA/NC K-28 T-35 V-23
Total Organic Carbon NE/NE ;,Q1 • NA 1Q.NQ
Ethylene Glycol NE/7.0 NA NA NA
Volatile Oroanics
2-Butanone(MEK) NE/0.17 QJ_Q lLll.1Jl • <0.0050
Acetone NE/0.7 Q.12.!..! • <0.0050 <0.0050
Benzene 0.005/0.001 M.ll <0.0010 MU·
Chlorobenzene 0.1/0.05 <0.0010 <0.0010 <0.0010
Cis-1,2-Dichloroethene 0.07/0.07 <0.0010 Q.QQll' <0.0010
Ethylbenzene ·0.110.029 <0.0010 <0.0010 =· T etrachloroethene 0.005/0.0007 <0.0010 =· <0.0010
Toluene 1.0/1.0 Q.llll22 • <0.0010 M.ll.
Trichloroethene 0.005/0.0028 <0.0010 =· <0.0010
Xylenes (total) 10/0.53 <0.0020 <0.0020 Q.Ql.1.
Notes: NA = Sample not analyzed for indicated constituents
EPA "' Environmental Protection Agency National Primary Drinking Water Standards
NC = North Carolina Groundwater Quality Standards (Subchapter ZL)
NE "" Not Established
U = Constituent not detected above the associated sample quantitation limit
/
P-58
NA
NA
0 0069LJ •
<0.0050
<0.0010
<0.0010
<0.0010
<0.0010
<0.0010
<0.0010
<0.0010
<0.0020
./
C-49
NA
NA
<0.0050 ·
<0.0050
<0.0010
<0.0010
<0.0010
<0.0010
<0.0010
<0.0010
<0.0010
<0.0020
.I / /
CC-33 FF-34 FF-62
NA NA NA
NA NA NA
=· 0 0079U • 0 00691) •
lLll.1fil.! ' <0.0050 <0.0050
ll.lllll.Z-<0.0010 <0.0010
<0.0010 <0.0010 <0.0010
Mll2.l· <0.0010 <0.0010
<0.0010 <0.0010 <0.0010
<0.0010 <0.0010 <0.0010
<0.0010 <0.0010 <0.0010
lLl!lU2. . <0.0010 <0.0010
<0.0020 <0.0020 <0.0020
CNA lloldin~_f, lnc/Ticmw-Shelby. NC
OU-I Semiunnuul Report (Jun. '04 -June '04)
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- -- --- - - - ----- --- -
Table 4. (Cont'd) Summary of Selected CERCLA-Related Water-Quality Constituents (1st Quarter 2004)
CNA Holdings, lnc./Ticona-Shelby, North Carolina
(All results reported in milligrams per liter [mg/L])
/ / /
EPA/NC AA-54 HH-48 HH-77
Total Organic Carbon NE/NE NA NA NA
Ethylene Glycol NE/7.0 NA NA NA
VQli:l.tile. Oraaai~
2-Butanone(MEK) NE/0.17 <0.0050 <0.0050 MQfil.
Acetone NE/0.7 <0.0050 <0.0050 MQfil·
Benzene 0.005/0.001 <0.0010 <0.0010 <0.0010
Chlorobenzene 0.1/0.05 <0.0010 <0.0010 <0.0010
Cis-1,2-Dichloroethene 0.0710.07 <0.0010 <0.0010 Q.QQTI .
Ethylbenzne ·o. 710.029 <0.0010 <0.0010 <0.0010
T etrachloroethene 0.005/0.0007 <0.0010 <0.0010 <0.0010
Toluene 1.0/1.0 <0.0010 <0.0010 <0.0010
Trichloroethene 0.005/0.0028 <0.0010 Q.U . Q.ll'
Xylenes (total) 10/0.53 <0.0020 <0.0020 <0.0020
Notes: NA = Sample not analyzed for indicated constituents
EPA = Environmental Protection Agency National Primary Drinking Water Standards
NC = North Carolina Groundwater Quality Standards (Subchapter 2L)
NE= Not Established
U = Constituent not detected above the associated sample quantitation limit
/
EE-58
NA
NA
Ml2..
Q.Ql)il·
<0.0010
<0.0010
<0.0010
<0.0010
<0.0010
<0.0010
<0.0010
<0.0020
./
GG-61
NA
NA
Q..QQZ.6..
Q.Ql1J,/.
<0.0010
<0.0010
<0.0010
<0.0010
<0.0010
<0.0010
<0.0010
<0.0020
/ v /
Inner Tier
Inner Tier Inner Tier Effluent
Influent Effluent Duplicate
J.l!ZQ • ll..6.. llJ. .
=-<7.0 · <7.0 ~
<0.0050 Mllli. . Q.Q.l.Q·
<0.0050 Q.J_Q • ~-~-<0.0010 <0.0010 =· <0.0010 <0.0010
<0.0010 <0.0010 <0.0010
<0.0010 <0.0010 <0.0010
<0.0010 <0.0010 <0.0010
<0.0010 <0.0010 <0.0010
<0.0010 <0.0010 <0.0010
<0.0020 <0.0020 <0.0020
CNA Holding~. Jrn:JTicona•Shelhy. NC
OU-/ Semiannual Reporl (Jun. '04 • June '(J4)
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Table 5. Summary of Selected CERCLA-Related Water-Quality Constituents (2nd Quarter 2004)
CNA Holdings, lnc./Ticona-Shelby, North Carolina
(All results reported in milligrams per liter [mg/L))
EPA/NC K-28 V-23 · ITCI
Total Organic Carbon NE/NE 1230 · 11200 NA
Notes: NA = Sample not analyzed for indicated constituent(s)
EPA= Environmental Protection Agency National Primary Drinking Water Standards
NC = North Carolina Groundwater Quality Standards (Subchapter 2L)
NE= Not Established
ITEF
NA
CNA Holdings. Inc /Ticona-Shelhy, NC
OU-I Semiannual Report (Jan. '04 -June '04)
-------- - - - - - -- -- - -
/_____
Table 6. Summary of Selected PEW-Related Water Quality Constituents (1st Quarter 2004)
CNA Holdings, lnc./Ticona-Shelby, North Carolina
Semivolatile Organics
1 , 1 Biphenyl
Biphenyl Ether
Volatile Organics
2-Butanone (MEK)
Benzene
Cis-1,2-Dichloroethene
Chloroform
Trichloroethene
(All results reported in milligrams per liter [mg/L])
EPA/NC
NE/0.35
NE/NE
NE/0.17
0.005/0.001
0.07/0.07
0.08/0.00019
0.005/0.0028
./
PEW-1
<0.010
<0.010
<0.0050
<0.0010
0.0014 ·
0.0017
0.0055 ·
../
PEW-3
0.0065 ·
<0.0010
<0.0010
<0.0010
<0.0010
/
PEW-4
<0.010 ·
0.029 -
<0.0050
QJlQ.2.6. .
Millill.
<0.0010
,OJ)021.
Notes: EPA= Environmental Protection Agency National Primary Drinking Water Standards
NC = North Carolina Groundwater Quality Standards (Subchapter 2L)
NE= Not Established
CNA Holdings. /ncJTicmza-Shelby. NC
OU-I Semiannual Report (Jan. '04 -June '04)
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-- - ------ - -
0 350 700
- -- - -
Legend
• Monitor Well
A Piezometer
.._ Surface Water Location
♦ Outer ner Extraction Well
• Inner Tier Extraction Well
■ PEW Elctractioo Well
IJ Residential 'Nell
~ Creek/ Stream
IIJ Building I Structure
Kubal-Furr & Associates
-Environmental Consi1ltants-
Figure I. Site Location Map
CNA Holding.~. lnc.11icona
Shelby, North Comlina
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•
--
..
Legend
MnoitotWeU
Water-Level (ft msl)
• lmer Tier Eictraction Well
.,....78Vw7:e~:::! ;.~ur
.,.,,...__.,.. Creek I Stream
ffiJ Building/ Structure
-- - ------
0 350 700
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a
"""""' El rt&w
Inner Tier Extraction Well
Water•Level Elevations
IT-1 = 800.00
IT-2 = 800.02
IT-3 = 806.76
IT -4 = 801.65
IT-5 = 803.25
IT-6 = 802.31
IT-7 = 802.97
IT-BR= 799.31
IT-9 = 798.15
Kubal-Furr & Associates
-Environmental Consultants-
Figure 2. Potentiometric Surface Map
Shallow Saprolite March I, 2004
CNA Holding.f, lnc.iTicnna
Shelhy, Nnrth Coro/ma
-
-- ---- -----
y e ~ :,. '& \
0 350 700
- - - - --- -
,,.
-'
• ....
• •
Legend -Water-level (fl msl)
Piezometltl'
Ou1er lillf Extraction Well
PEW Ertl'adlon Wei
Waler-level Contour ----->, o, Creek I S11eam
'
' Building I Slructur&
•"~ ,111118
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\ ' \ \
I ~ \
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I• ~~~I ;_f;'" ,'
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Kubal-Furr & Associates
-Environmental Consultants-
Figure 3. Potentiometric Surface Map
Deep Saprolite /Upper Bedrock-March I, 2004
CNA Holdings, lnc.lficona
Shelby, North Carolina
850.00 A _/~~~~~~~~~~~~::..'.~'•~n~t~A~r:•:•========!.f!:::::::::::----------Y.,astewaterTreatmentArea•------------<
830.00
810.00
790.00
no.oo
750.00
730.00
710.00
690.00
670.00
D-27
827.48
D-35
827.11
D-56
827.04
Legend
-a,o.J Line of equal fluid potential (ft msl) G:J Bedrock
(da~ wtlere inlffl'ed)
1 Potentiometric Surface Saprolite
G-50
813.67
~ Inferred direction of ground-water
movement
Screened Interval of Well
Horizontal Scale in Feet
0 400 800
:,:_
::;
" :,:_ e 0.
I
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A' 850.00
830.00
810.00
790.00
770.00
750.00
730.00
710.00
690.00
670.00
Kubal-Furr & Associates
-E11vira11111e11tnl Co11s11lfn11ts -
Figure 4-Hydrogeologic Cross-Section
A-A'-March I, 2004
CNA Holdin~s. lncfficona
Shelby, Nonh Carv/inu
-
I ..
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Legend
MaoitocWell water-level (ft mst) •
• Inner Tier Extraction Well
/18'V ,.-..-,,
Iii
water-Level Contour c--........... ,
Creek I Stream
Buik:ling f Structure
0 350 700
'
....
.... ....
.,.. ....
\
\
•'JJ-40 720.10
'
'J '
' ' /
\
\
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Water-Level Elevations
IT-1 = 799.81
IT-2 = 801 .45
IT-3 = 800.32
IT-4 = 800.64
IT-5= 801.69
IT-6 = 801 .99
IT-7 = 801.88
IT-8R= 798.86
IT-9 = 796.90
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• a
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~
Kubal-Furr & Associates
-Environmental Consultants-
Figure 5. Potentiometric Surface Map
Shallow Saprolite-May 20, 2004
CNA Holdings, /nc.lTicona
Shelby, North Carolina
0 350
• ...
♦
•
-Water-Level (ft msl)
Piezometer
Outer Tier Extraction Well
PEW Extraction Well '------~--,.,....-------, ,......rso/ ~:~;~e~ ~'!iour
~
700
'
~'
~•\\/~ ~"
• ~!
'
.,,-._.., CreekfStream
~ Building I Structure
·-' 118.113
'
\
\
\
\
~ \
\ \
\ \ \ \ \ \ I \ I
-1-.'
I I
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'~•""°' l!il ,-11uo I --
/ I "-:---..___ I ·;;, ,·-,~'
I I
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-Environmental Consultants-
Figure 6. Potentiometric Surface Map
Deep Saprolite/Upper Bedrock-May 20, 2004
CNA Holdings. lnc./Ticona
Shelby, North Carolina
850.00 A -~ •:-=-=-=-=-=-=-=-=-=-=-=-~~l~a:nt~A~,~•:::=======~-r::::::::~---------~wastewater Treatment Area,-----------•
830.00
810.00
790.00
no.co
750.00
730.00
710.00
690.00
670.00
D-27 ·
826.47,
0-35
826.13
0-56
826.17
Legend
-ew"' line of equal fluid potential (ft msl) G:J
{dashed wtien, interred)
I' Potentiometric Surface
---Inferred direction of ground-water
movement
Bedrock
Saprollte
G-50
813.39
Screened Interval of Well
J-29
806.37
Horizontal Scale in Feet
0 400 800
~ ::,
i e a.
I
A' 850.00
830.00
810.00
790.00
770.00
750.00
730.00
71000
690.00
670.00
Kubal-Furr & Associates
-E11viro11me11tal Co11s11/tm1ts -
Figure 7-Hydrogeologic Cross-Section
A-A'-May 20, 2004
CNA lloldings, lncfficonu
Shelby, North Carolina
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Attachment 1
Summary of Activities Performed During Decommissioning
of the Ground-Water Treatment System (Earth Tech)
Kubal-Furr & Associates
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Groundwater Treatment System
Ticona Facility, Shelby NC
Decommissioning Summary Report
Following is a summary of the work completed by Ticona and/or Earth Tech and final status of
the decommissioned Groundwater Treatment System and associated Inner Tier Wells. This work
was performed in March 2004.
1. Decontamination
Prepared a wash-down area within the Groundwater Treatment (GWT) Building that drained to
the sump and did not interfere with the decommissioning process.
Decontamination of equipment and tanks was performed using a pressure washer.
2. Inner Tier Wells
Turned off the Inner Tier Wells.
The air and circuit breaker for electricat·supply was locked out at the electric panel.
Ticona removed the Inner Tier well pumps. Earth Tech pressure washed the well pumps, rinsed
with tap water and allowed to air dry.
The pumps remain in the GWT Building.
3. pH and DO probes
Earth Tech removed the probes and left them stored in a container of water with wiring attached.
4. Intermediate Decant Tank (attached to SBR)
Earth Tech removed bolted down cover to intermediate decant tank, pumped out the tank
contents to the decant tank. The tank was then pressure washed and decontamination water was
pumped to the decant tank. Earth Tech disassembled and cleaned the strainer between decant
tank and pump.
Decon Summa!)' Reportl_eg_rO.doc 8/27/2004
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Groundwater Treatment Plant
Decommissioning Summary Report
CNA Holdings, Inc.fTicona Facility, Shelby, North Carolina
5. Decant Storage Tank
Earth Tech pumped the tank contents through air stripper and then pressure washed the decant
tank and drained the decon water to the floor sump.
6. Inner Tier Air Strippers
Earth Tech pumped the air stripper collection sump through the carbon canisters then pressure
washed the unit.
The air stripper media was left in place.
7. Inner Tier Carbon Filter
Earth Tech backwashed the carbon filter using the Outer Tier water and drained the carbon
completely.
The carbon filter media was left in place.
8. Outer Tier Storage Tanks
Earth Tech pressure washed the tank and drained it to the floor sump.
9. Sludge Treatment System
Pumped clarifier contents to sludge holding tank and then pressure washed the clarifier.
Earth Tech processed the contents of sludge holding tank through the filter press and pumped the
filtrate to SBR. The filter press was then cleaned.
Metering pump feed lines were flushed and the Polyblend system was flushed with water for 20
minutes.
10. Pumps and Valves
Clean water was pumped through all centrifugal pumps.
11. Floor Sump
Floor sump was pressure washed and pumped contents to Equalization Tank.
Decon Summary Reportl_eg_rO.doc 2 8/27/2004
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Groundwater Treatment Plant
Decommissioning Summary Report
CNA Holdings, Inc.fricona Facility, Shelby, North Carolina
12. Equalization Tank
The contents of the Equalization Tank were pumped to the SBR tank. The tank was pressure
washed, and the decon water was pumped to the SBR.
13. SBR Reactor Tank
Earth Tech treated the water remaining in the SBR following normal operating procedure then
decanted and wasted the SBR contents to the digester during the decommissioning process until
the level dropped below the outlet and all other equipment and tanks had been pressure washed
and flushed with clean water. The remaining contents were then removed using a vacuum truck
and taken to the digester basin.
The SBR tank was then pressure washed and left to air dry.
Miscellaneous
Remaining chemicals have been utilized throughout site.
Lock out and tag out specific breakers. Leave utility lights on and set heat at 55 degrees F.
Check building on a weekly basis
Decon Summary Reportl_eg_rO.doc ) 8/27/2004
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Attachment 2
I Operation and Maintenance Data
I January-February, 2004
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Kubal-Furr & Associates
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Jntitled 8110/04 9:39 AM
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I INNER TIER
DAILY FLOW
I
January I 2004 IT-1 IT-2 IT-3 IT-4 IT-5 IT-6 IT-7 IT-8 IT-9
01/01/04 I 01/02/04 318 89 249 286 331 80 545 105 565
01/03/04
01/04/04 I 01/05/04 463 107 374 398 453 115 507 332 536
01/06/04
01/07/04 316 55 257 258 275 83 531 273 579
01/08/04 I 01/09/04 329 52 257 207 282 85 539 289 1428
01/10/04
01/11/04 I 01/12/04 478 73 196 218 345 129 782 280 70
01/13/04
01/14/04 319 47 41 0 361 87 518 105 1187 I 01/15/04
01/16/04 311 45 48 0 288 80 498 78 1355
01/17/04 I 01/18/04 310 45 44 50 0 83 499 103 1384
01/19/04
01/20/04 331 47 53 241 0 89 520 185 1523
01/21/04 I 01/22/04 313 50 72 184 0 86 479 436 1575
01/23/04
01/24/04 323 50 56 245 0 81 496 667 1649 I 01/25/04
01/26/04
01/27/04 I 01/28/04 315 50 77 264 0 79 495 721 1679
01/29/04
01 /30/04 321 81 97 277 0 70 479 617 692 I 01/31/04
AVG: 342 61 140 202 180 88 530 322 1094
I TOTAL: 4447 791 1821 2628 2335 1147 6888 4191 14222
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I INNER TIER COMBINED INFLUENT #2 ITCI
PAGE NO.1
I January 2004
DATE: FLOW: PH: COD: TSS: TOC:
GPD pH ppm ppm ppm
I 01/01/04
01/02/04 2568 5.3 4600 4
I 01/03/04
01/04/04
01/05/04 3285 5.1 5600 36
I 01/06/04
01/07/04 2627 5.3 2010 7 1490
01/08/04
01/09/04 3468 5.2 4100
I 01/10/04
01/11/04
01/12/04 2571 5.2 5520 28
I 01/13/04
01/14/04 2665 5.3 2790 9 1140
01/15/04
I 01/16/04 2703 5.4 4500 19
01/17/04
01/18/04 2518 5.4 4470 25
01/19/04
I 01/20/04 2989 5.3 3740 6 1790
01/21/04
01/22/04 3195 5.3 2760 9
I 01/23/04
01/24/04 3567 5.4 2150 7
01/25/04
I 01/26/04
01/17/04
01/28/04 3680 5.7 2420 12 1000
I 01/29/04
01/30/04 2633 5.5 2610 11
01/31/04
I AVG: 2959 5.3 3636 13 1355
MAX: 3680 5.7 5600 36 1790
MIN: 2518 5.1 2010 1 1000
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I GROUNDWATER MONTHLY MONITORING:
INNER TIER EQUALIZATION TANK: ITEQT
PAGE NO. 2
I OCT.2003
DATE: PH: COD: OT WATER ADDED
pH ppm gal
I 01/01/04
01/02/04 6.6 4580 0
I 01/03/04
01/04/04
01/05/04 6.6 4070 0.0
I 01/06/04
01/07/04 6.7 3130 0
01/08/04
01/09/04 6.9 3300 0
I 01/10/04
01/11/04
01/12/04 6.7 4440 0
I 01/13/04
01/14/04 6.8 5150 0
01/15/04
I 01/16/04 7.2 4320 0.0
01/17/04
01/18/04 7.3 3050 0.0
01/19/04
I 01/20/04 7.1 2590 0
01/21/04
01/22/04 7.2 2540 0
I 01/23/04
01/24/04 6.7 2200 0
01/25/04
I 01/26/04
01/17/04
01/28/04 7.1 2920 0
I 01/29/04
01/30/04 7.2 3490 0.0
01/31/04
I AVG: 6.9 3522 0
MAX: 7.3 5150 0
MIN: 6.6 2200 0
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I GROUNDWATER MONTHLY MONITORING:
AFTER PLATE SEPARATOR BEFORE SBR: SBRI
PAGE NO. 3
I OCT.2003
DATE: PH: COD: TSS:
pH ppm ppm
I 01/01/04
01/02/04 4800 8
I 01/03/04
01/04/04
01/05/04 4440 46
I 01/06/04
01/07/04 3760 32
01/08/04
01/09/04 3510 60
I 01/10/04
01/11/04
01/12/04 3660 50
I 01/13/04
01/14/04 5110 84
01/15/04
I 01/16/04 3090 88
01/17/04
01/18/04 4040 46
01/19/04 I 01/20/04 4370 44
01/21/04
01/22/04 2710 60
I 01/23/04
01/24/04 2430 22
01/25/04
I 01/26/04
01/17/04
01/28/04 2640 50
I 01/29/04
01/30/04 2500 24
01/31/04
I AVG: #DIV/0! 3620 47
MAX: 0.0 5110 88
MIN: 0.0 2430 8
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I GROUNDWATER MONTHLY MONITORING:
SBR MIXED LIQUOR: SBRML
PAGE NO. 4
I OCT.2003 SETT. SLUDGE 5/DAY
DATE: PH: NH3N: PO4: DO: MLSS: MLVSS: SOLIDS: WASTED F/M: F/M:
pH ppm ppm ppm ppm ppm ml/I gal ratio ratio
I 01/01/04 #DIV/0!
01/02/04 112 4.70 6.4 3000 280 270 0.14
I 01/03/04 #DIV/0!
01/04/04 #DIV/0!
01/05/04 103 0.01 3.4 3352 340 270 0.12 #DIV/0!
I 01/06/04 #DIV/0! #DIV/0!
01/07/04 75 0.25 3.7 3095 2385 340 270 0.11 #DIV/0!
01/08/04 #DIV/0! #DIV/0!
01/09/04 78 0.10 1.8 3068 440 270 0.10 #DIV/0!
I 01/10/04 #DIV/0! #DIV/0!
01/11/04 #DIV/0! #DIV/0!
01/12/04 122 0.08 2.4 3240 440 270 0.10 #DIV/0!
I 01/13/04 #DIV/0! #DIV/0!
01/14/04 102 2.50 2.2 3404 2628 480 337 0.13 #DIV/0!
01/15/04 #DIV/0! #DIV/0!
I 01/16/04 125 5.00 9.9 3104 390 270 0.09 #DIV/0!
01/17/04 #DIV/0! #DIV/0!
01/18/04 98 2.50 8.3 2980 400 270 0.12 #DIV/0!
01/19/04 #DIV/0! #DIV/0!
I 01/20/04 118 0.35 9.6 3400 2506 440 270 0.11 #DIV/0!
01/21/04 #DIV/0! #DIV/0!
01/22/04 127 1.00 10.1 3347 420 270 0.07 #DIV/0!
I 01/23/04 #DIV/0! #DIV/0!
01/24/04 129 1.00 10.4 3387 420 270 0.06 #DIV/0!
01/25/04 #DIV/0! #DIV/0!
I 01/26/04 #DIV/0! #DIV/0!
01/17/04 #DIV/0! #DIV/0!
01/28/04 155 5.00 10.1 3360 2570 400 0 0.07 #DIV/0!
I 01/29/04 Frozen discharge? #DIV/0! #DIV/0!
01/30/04 118 1.00 10.6 3270 410 270 0.07 #DIV/0!
01/31/04 #DIV/0! #DIV/0!
I AVG: #DIV/0! 112 1.81 7 3231 2522 371 254 #DIV/0! #DIV/0!
MAX: 0.0 155 5.00 11 3404 2628 480 337 #DIV/0! #DIV/0!
MIN: 0.0 75 0.01 2 2980 2385 0 0 #DIV/0! #DIV/0!
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I GROUNDWATER MONTHLY MONITORING:
SBR EFFLUENT:(DECANT) #4SBRE
I PAGE NO. 5
OCT.2003 WAS. NH3N PHOS.
DATE: FLOW: COD: TSS: TSS ADDED: ADDED:
I
GPO ppm ppm ppm gal lbs
01/01/04
01/02/04 2715 189 40 2 0
I 01/03/04
01/04/04
01/05/04 2802 173 68.0 2 0
I 01/06/04
01/07/04 2811 281 136 3 0
01/08/04
I 01/09/04 2249 230 60 4 0
01/10/04
01/11/04
01/12/04 2600 153 64 2 0
I 01/13/04
01/14/04 1902 201 80 2 0
01/15/04
I 01/16/04 2727 225 92 2 0
01/17/04
01/18/04 2777 283 120 3 0
I 01/19/04
01/20/04 1838 344 260 2 0
01/21/04
I 01/22/04 2709 336 75 2 0
01/23/04
01/24/04 2850 355 300 2 0
01/25/04
·1 01/26/04
01/17/04
01/28/04 2609 515 320 2 0
I 01/29/04
01/30/04 2941 520 400 2 0
01/31/04
I AVG: 2579 293 155 #DIV/0! 2 0
MAX: 2941 520 400 0 4 0
MIN: 1838 153 40 0 2 0
I • DID NOT PROCESS SBR .
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I GROUNDWATER MONTHLY MONITORING
INNER TIER CARBON FILTER EFFLUENT #8ITEF
I PAGE NO. 7
OCT.2003
DATE: PH: COD: TOC: TSS:
pH ppm ppm ppm
I 01/01/04
01/02/04
I 01/03/04
01/04/04
01/05/04
I 01/06/04
01/07/04 244 90.3 120
01/08/04
01/09/04
I 01/10/04
01/11/04
01/12/04
I 01/13/04
01/14/04 185 192
01/15/04
I 01/16/04
01/17/04
01/18/04
01/19/04
I 01/20/04 8.7 290 177
01/21/04
01/22/04
I 01/23/04
01/24/04
01/25/04
I 01/26/04
01/17/04
01/28/04 8.8 4890 235
I 01/29/04 Called Johnny, will scrutinze next week's COD.
01/30/04
01/31/04
I AVG: 5.8 1402 174 120
MAX: 8.8 4890 235 120
MIN: 0.0 185 90 120
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lntitled /j/lUIU➔ ':>':.l"J 11.l\'l
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I INNER TIER
I DAILY FLOW
fEBRUARY
2004 IT-1 IT-2 IT-3 IT-4 IT-5 IT-6 IT-7 IT-8 IT-9
I 02/01/04
02/02/04 290 75 77 230 421 65 462 706 1579
02/03/04
I
02/04/04 270 85 180 219 419 54 411 669 1160
02/05/04
02/06/04 296 96 188 249 463 61 474 808 1720
02/07/04
I 02/08/04
02/09/04 464 135 496 540 902 95 734 1317 2786
02/10/04 120 38 75 100 205 21 175 345 660
I 02/11/04 13 4 7 10 23 2 20 41 72
02/12/04
02/13/04 273 86 23 209 485 48 387 844 1124
I 02/14/04
02/15/04
02/16/04 365 117 15 270 543 62 536 926 613
I 02/17/04
02/18/04 338 103 10 265 501 56 483 788 213
02/19/04
· 02/20/04 364 96 0 214 433 48 384 900 1613
I 02/21/04
02/22/04
02/23/04 363 139 0 307 650 71 352 1198 616
I 02/24/04
02/25/04 362 107 0 245 537 55 1 1048 0
02/26/04
I 02/27/04 335 99 7 285 581 61 0 900 0
02/28/04
02/29/04
I
AVG: 296 91 83 242 474 54 340 807 935
I TOTAL: 3853 1180 1078 3143 6163 699 4419 10490 12156
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I INNER TIER COMBINED INFLUENT #2 ITCI
PAGE NO.1
I February-04
DATE: FLOW: PH: COD: TSS: TOC:
GPD pH ppm ppm ppm
I 02/01/04
02/02/04 3905 5.6 1960 11
I 02/03/04
02/04/04 3467 5.5 2110 4 913
02/05/04
02/06/04 4355 5.6 2700 6
I 02/07/04
02/08/04
02/09/04 7469 5.5 3420 17
I 02/10/04 1739 5.5 3100 14
02/11/04 192 5.6 2700 13 999
02/12/04
I 02/13/04 3479 5.6 2560 1
02/14/04
02/15/04
02/16/04 3447 5.5 3690 1
I 02/17/04
02/18/04 2757 5.4 3660 6 1210
02/19/04
I 02/20/04 4052 5.5 2880 1
02/21/04
02/22/04
I 02/23/04 3696 5.4 3280 9
02/24/04
02/25/04 2355 5.5 4540 11 1800
I 02/26/04
02/27/04 2268 5.5 6110 8
02/28/04
02/29/04
I AVG: 3322 5.5 3285 8 1231
MAX: 7469 5.6 6110 17 1800
I MIN: 192 5.4 1960 1 913
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I GROUNDWATER MONTHLY MONITORING:
INNER TIER EQUALIZATION TANK: ITEQT
I PAGE NO. 2
February-04
DATE: PH: COD: OT WATER ADDED
pH ppm gal
I 02/01/04
02/02/04 7.3 3730 0
I 02/03/04
02/04/04 7.0 3380 0.0
02/05/04
I 02/06/04 7.1 3700 0
02/07/04
02/08/04
02/09/04 7.1 2530 0.0
I 02/10/04 6.8 2370 0
02/11/04 7.4 2780 0
02/12/04
I 02/13/04 7.4 2460 0.0
02/14/04
02/15/04
I 02/16/04 6.9 3960 0.0
02/17/04
02/18/04 7.1 4250 0.0
I 02/19/04
02/20/04 6.9 2450 0
02/21/04
02/22/04
I 02/23/04 7.0 4180 0.0
02/24/04
02/25/04 7.2 4100 0.0
I 02/26/04
02/27/04 7.2 4620 0.0
02/28/04
I 02/29/04
AVG: 7.1 3424 0
MAX: 7.4 4620 0
I MIN: 6.8 2370 0
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I GROUNDWATER MONTHLY MONITORING:
AFTER PLATE SEPARATOR BEFORE SBR SBRI
PAGE NO. 3
I February-04
DATE: PH: COD: TSS:
pH ppm ppm
I 02/01/04
02/02/04 3180 38
I 02/03/04
02/04/04 3120 28
02/05/04
02/06/04 2060 24
I 02/07/04
02/08/04
02/09/04 3100 36
I 02/10/04
02/11/04 1200 76
02/12/04
I 02/13/04 2050 38
02/14/04
02/15/04
I 02/16/04 4290 20
02/17/04
02/18/04 4060 16
02/19/04
I 02/20/04 3070 20
02/21/04
02/22/04
I 02/23/04 3620 26
02/24/04
02/25/04 4880 30
I 02/26/04
02/27/04 5110 26
02/28/04
02/29/04 I AVG: #DIV/0! 3312 32
MAX: 0.0 5110 76
I MIN: 0.0 1200 16
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I GROUNDWATER MONTHLY MONITORING:
SBR MIXED LIQUOR: SBRML
PAGE NO. 4
I February-04 SETT. SLUDGE 5/DAY
DATE: PH: NH3N: PO4: DO: MLSS: MLVSS: SOLIDS: WASTED F/M: F/M:
pH ppm ppm ppm ppm ppm ml/I gal ratio ratio
I 02101104 #DIV/0!
02102/04 165 0.7 10.3 3315 440 270 0.09
I 02103104 #DIV/0!
02104/04 95 3.5 10.1 3260 2505 440 324 0.09
02105/04 #DIV/0! #DIV/0!
02106/04 97 6.0 10.2 3320 430 324 0.06 #DIV/0!
I 02107/04 #DIV/0! #DIV/0!
02108/04 #DIV/0! #DIV/0!
02/09/04 96 1.3 10.7 3180 380 350 0.09 #DIV/0!
I 02/10/04 61 4.0 10.8 3360 0.00 #DIV/0!
02/11/04 128 5.0 2.4 3360 2605 450 324 0.03 #DIV/0I
02/12/04 #DIV/0! #DIV/0!
I 02113104 165 0.1 0.6 3220 890 270 0.06 #DIV/0!
02114104 #DIV/0! #DIV/0!
02115104 #DIV/0! #DIV/0!
02/16/04 123 0.8 0.7 2447 890 270 0.16 #DIV/0!
I 02/17/04 #DIV/0! #DIV/0!
02/18104 119 0.8 1.5 3288 2572 780 450 0.11 #DIV/0!
02/19104 #DIV/0! #DIV/0!
I 02/20104 160 0.8 1.5 3240 770 500 0.08 #DIV/0!
02/21/04 #DIV/0! #DIV/0!
02/22/04 #DIV/0! #DIV/0!
I 02/23/04 161 2.8 1.1 3140 780 500 0.10 #DIV/0!
02/24/04 #DIV/0! #DIV/0!
02/25104 111 0.4 1.1 3260 2624 760 500 0.13 #DIV/0!
I 02126/04 #DIV/0! #DIV/0!
02127104 102 0.4 1.4 3320 740 700 0.14 #DIV/0!
02/28104 #DIV/0! #DIV/0!
02/29104 #DIV/0! #DIV/0!
I AVG: #DIV/0! 122 2 5 3208 2577 646 399 #DIV/0! #DIV/0!
MAX: 0.0 165 6 11 3360 2624 890 700 #DIV/0! #DIV/0!
I MIN: 0.0 61 0 1 2447 2505 380 270 #DIV/0! #DIV/0!
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I GROUNDWATER MONTHLY MONITORING:
SBR EFFLUENT:(DECANT) #4 SBRE
PAGE NO. 5
I February-04 WAS. NH3N PHOS.
DATE: FLOW: COD: TSS: TSS ADDED: ADDED:
GPD ppm ppm ppm gal lbs
I 02/01 /04
02/02/04 2356 567 410.0 0 0
I 02/03/04
02/04/04 2922 626 360.0 2 0
02/05/04
02/06/04 3441 580 420.0 2 0
I 02/07/04
02/08/04 2/9/04 Did not release decant because influnet siphoned from EQ tank over weekend
02/09/04 0 447 380 2 0
I 02/10/04 3932 2 0
02/11/04 3421 461 260 2 0
02/12/04
I 02/13/04 2665 395 187.0 2 0
02/14/04
02/15/04
02/16/04 2580 386 153 1 0
I 02/17/04
02/18/04 2751 313 127 2 0
02/19/04
I 02/20/04 2711 330 120 2 0
02/21/04
02/22/04
I 02/23/04 2729 301 105 1 0
02/24/04
02/25/04 2745 340 140 2 0
I 02/26/04
02/27/04 1681 328 140 2 0
02/28/04
02/29/04
I AVG: 2424 423 234 #DIV/0! 2 0
MAX: 3932 626 420 0 2 0
I MIN: 0 301 105 0 0 0
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I GROUNDWATER MONTHLY MONITORING
INNER TIER CARBON FILTER EFFLUENT #8 ITEF
I PAGE NO. 7
February-04
DATE: PH: COD: TOC: TSS:
I
pH ppm ppm ppm
02/01/04
02/02/04
I 02/03/04
02/04/04 177 7 120
02/05/04
I 02/06/04
02/07/04
02/08/04
02/09/04
I 02/10/04
02/11/04 453 222
02/12/04
I 02/13/04
02/14/04
02/15/04
I 02/16/04
02/17/04
02/18/04 264 231
I 02/19/04
02/20/04
02/21/04
02/22/04
I 02/23/04
02/24/04
02/25/04 140
I 02/26/04
02/27/04
02/28/04
I 02/29/04
AVG: #DIV/0! 298 150 120
MAX: 0.0 453 231 120
I MIN: 0.0 177 7 120
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Attachment 3
I Analytical Data for the
I 1st and 2nd Quarter 2004 Sampling Events
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Kubal-Furr & Associates
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DAYIS
FLOYD
March 24, 2004
PEM CARTER
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Report ID : AB23157
Page 1 of 75
Login Number
Project Number
Description
Dear Pem Carter:
:L04030101, 104030402, 104030807, 104031504
:61621.01
:QI 2004 GROUNDWATER ANALYSIS
We are pleased to provide the enclosed analytical results for the samples received by
Davis & Floyd, Inc. on February 26, 2004 through March 12, 2004.
A formal Quality Assurance/Quality Control program is maintained by Davis & Floyd,
which is designed to meet or exceed the EPA, NELAC or other appropriate regulatory
requirements. All analytical analyses for this project met QA/QC criteria and the
results are within the 99 % confidence interval for each method unless otherwise ·
stated in the footnotes. This report is to be reproduced only in full.
Feel free to contact our;Client Services Representative at [phone] if further
explanation of the analysis is required. Unless other arrangements have been made,
samples will be disposed of or returned 14 days from the cfate of the report. We
appreciate the opportunity to provide services to your firm.
Sincerely,
DAVIS2~INC
hn H. McCord, Jr.
Laboratory Manager
I Davis & floyd. Inc. I PO Drawer 428 I Greenwood, SC 29648 I 81(, E. Dur~ Avenue I Greenwood, SC 2%49 I [phone] I Fax [phone]
Di\YIS
FLOYD
Client
Contact
LABORATORY ANALYSIS REPORT
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 2 of 75
March 24, 2004
Report ID: AB23157
Master Sample Tracking List
Sample ID Client ID Date Collected Date Received
L04030101-0l ITEF
Ga~ Chromatography
SW846 8015 03/09/2004 1123
Volatile Organics
SW846 8260B 03/08/2004 0903
Wet Chemistry
SW846 9060 03/02/2004 0206
L04.030101-02 ITEF DUP. 1030
Gas Chromatography
SW846 8015 03/09/2004 1149
Volatile Organics
SW846 8260B 03/08/2004 1049
Wet Chemistry
SW846 9060 03/02/2004 0237
L04030101-03 ITCI
Gas Chromatography
SW846 8015 03/09/2004 1332
Volatile Organics
SW846 8260B 03/08/2004 0920
Wet Chemistry
SW846 9060 03/02/2004 0310
L04030101-04 TRIP BLANK 0850
Volatile Organics
SW846 8260B 03/08/2004 0956
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 2%48 I 816 E. Durst Avenue I Greenwood, SC 29649 ! [phone] I Fax {864) 229-7119
2
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DAYIS
FLt1YD LABORATORY ANALYSIS REPORT
Client
Contact
TrCONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
Master Sample Tracking List
Sample ID
L04030402-0l
Semivolatile Organics
SW846 8270C
SWB46 8270C DOWTHERM
Volatile Organics
SW846 8260B
L04030402-02
Semivolatile Organics
SW846 8270C
SW846 8270C DOWTHERM
Volatile Organics
SW846 8260B
Client ID
SW846 3510C
SW846 3500B
SW846 3510C
SW946 35008
L04030402-03 PEW-03 DUP.
Semivolatile Organics
SW846 8270C SW846 3510C
SW846 8270C DOWTHERM SW846 35008
Volatile Organics
SW846 8260B
L04030402-04
Semivalatile Organics
SW846 8270C
SW846 8270C DOWTHERM
Volatile Organics
SW846 8260B
L04030402-05
Volatile Organics
SW846 8260B
PEW-04
HH-48
SW846 3510C
SW846 3500B
NC Cenijication Number: 25
Project Number: 61621.01
Report Date
Page 3 of 75
Date Collected
03/08/2004 0800
03/08/2004 0800
0825
03/08/2004 0800
03/08/2004 0800
03/03/2004 0825
03/08/2004 0800
03/08/2004 0800
0825
03/08/2004 0800
03/08/2004 0800
1025
March .24, 2004
Report ID: AB23157
Date Received
03/03/2004
03/16/2004 1507
03/16/2004 1507
03/08/2004 1124
03/16/2004 1727
03/17/2004 0033
03/08/2004 1142
03/16/2004 1842
03/17/2004 0111
03/08/2004 1228
03/16/2004 1922
03/16/2004 1922
03/08/2004 1322
03/08/2004 1340
I Davis & Floyd, Inc. I PO Drawer428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 l [phone] I Fax [phone]
3
D1\VIS
FLtn1D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
Master Sample Tracking List
Sample ID
L04030402-06
Volatile Organics
SW846 8260B
SW846 8260B
Volatile Organics
SW846 8260B
L04030402-08
Volatile Organics
SW846 8260B
L04030402-09
Volatile Organics
SW846 82608
L04030807-01
Volatile Organics
SW846 8260B
L04030807-02
Volatile Organics
SW846 8260B
L04030807-03
Volatile Organics
SW846 8260B
L04030807-04
Volatile Organics
SW846 8260B
Client ID
HH-77
EB-01
TRIP BLANK
AA-54
P-58
C-49
FP'-34
NC Cenification Number: 25
Project Number: .61621.01
Report Date
Page 4 of 75
Date Collected
1205
1755
0650
1530
1710
1105
1303
March 24, 2004
Report ID: AB23157
Date Received
03/05/2004
03/05/2004
03/08/2004 1357
03/08/2004 1543
03/08/2004 1415
03/08/2004 1432
03/08/2004 1014
03/08/2004 1640
03/08/2004 1732
03/08/2004 1749
03/08/2004 1807
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29646 I 816 E. Durst Avenue / Greenwood, SC 29649 I (864} 229-4413 I Fax /864) 229-7119
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DAYIS
FLtwD
Client
Contact
LABORATORY ANALYSIS REPORT
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
NC Cenification Number: 25
Project Number: 61621.01
Report Date
Page 5 of 75
March 24, 2004
Report ID: AB23157
Master Sample Tracking List
Sample ID Client ID Date Collected Date Received
L04030807-05 FF-62 1435
Volatile Organics
SW846 8260B 03/08/2004 1824
L04030807-06 TRIP BLANK o'aso
Volatile Organics
SW846 8260B 03/08/2004 1622
L04031504-0l K-28 03/08/2004 1705 03/12/2004
Volatile Organics
SW846 8260B 03/18/2004 1859
Wet Chemistry
SW846 9060 03/19/2004 1109
L04031504-02 CC-33 03/08/2004 1710
Volatile Organics
SW846 8260B 03/18/2004 1917
L04031504-03 GG-61 1410
Volatile Organics
SW846 8260B 03/18/2004 1934
L04'031504-04
Volatile Organics
SW846 8260B 03/18/2004 1952
L04031504-05 1705
Volatile Organics
SW846 8260B 03/10/2004 2009
Wet Chemistry
SW846 9060 03/19/2004 1140
.Davis & Floyd, Inc. I PO DrJwer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue ) Greenwood, SC 29649 / (864) 229-44 l 3 I Fax [phone]
5
Di\YIS
FLtWD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
.Master Sample Tracking List
Samplo ID
LO.f.031504-06
Volatile Organics
SW846 8260B
Client ID
TRIP BLANK
NC Cenijicalion Number: 25
Project Number: 61621,01
Report Date
Page 6 of 75
Date Collected
0850
March 24, 2004
Report ID: AB23157
Date Received
03/18/2004 1842
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 l 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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D~IS I LABORATORY ANALYSIS REPORT FL --,WYD
I NC Certification Number: 25
I Client TICONA,LLC Project Number: 61621.01
2525 BLACKSBURG ROAD
HWY 198
I SHELBY, NC 28152 Report Date March 24, 2004
Contact Pem Carter Page 7 of 75 Report ID: AB23157
Client IO: ITEI" Sample ID L04030101-0l I Date Collected: 02/25/2004 103 0
Matrix : GW/ChemW Date Received 02/26/2004
I Parameter Result Qual RDL units Ana.lyst Date Time
Gas Chromatography
SW846 8015
I ETHYLENE GLYCOL < 7.0 7.0 mg/1 MGB 03/09/2004 1123
Volatile Organics
SW846 8260B
I 1,1,1-TRICHLOROETHANE < o. 0010 0. 0010 mg/1 PAP 03/08/2004 .0903
1,1,2,2-TETRACHLOROETHANE < 0 .0010 0 .0010 mg/1 PAP 03/08/2004 0903
1,1,2-TRICHLOROETHANE < 0 .0010 0.0010 mg/1 PAP 03/08/2004 0903
I 1,1-0ICHLOROETHANE < 0. 0010 0. 0010 mg/1 PAP 03/08/2004 0903
1,1-DICHLOROETHENE < 0. 0010 0. 0010 mg/1 PAP 03/08/2004 0903
1,2-DICHLOROETHANE < 0 . 0010 0 .0010 mg/1 PAP 03/08/2004 0903
1,2-0ICHLOROPROPANE < 0 .0010 0. 0010 mg/1 PAP 03/08/2004 0903
I 2-BUTANONE 0.0075 0.0050 mg/1 PAP 03/08/2004 0903
2-HEXANONE < 0.0050 0.0050 mg/1 PAP 03/08/2004 0903
4-METHYL-2-PENTANONE < 0.0050 0.0050 mg/1 PAP 03/08/2004 0903
ACETONE 0.10 0.0050 mg/1 PAP 03/08/2004 0903 I BENZENE < 0 .0010 0 .0010 mg/1 PAP 03/08/2004 0903
BROMOOICHLORQMETHANE < 0 . 0010 0 . 0010 mg/1 PAP 03/08/2004 0903
BROMOFORM < o. 0010 0. 0010 mg/1 PAP 03/08/2004 0903
I BROMOMETHANE < 0 .0010 0.0010 mg/1 PAP 03/08/2004 0903
CARBON DISULFIDE < 0 . 0010 0.0010 mg/1 PAP 03/08/2004 0903
CARBON TETRACHLORIDE < 0.0010 0. 0010 mg/1 PAP 03/08/2004 0903
CHLOROBENZENE < 0 . 0010 o . 0010 mg/1 PAP 03/08/2004 0903
I CHLOROETHANE < 0 . 0010 0 . 0010 mg/1 PAP 03/08/2004 0903
CHLOROFORM < 0. 0010 0. 0010 mg/1 PAP 03/08/2004 0903
CHLOROMETJ-W.lE < 0. 0010 0 .0010 mg/1 PAP 03/08/2004 0903
CIS-1,2-DICHLOROETHENE < 0 .0010 0 .0010 mg/1 PAP 03/08/2004 0903 I CIS-1,3-DICHLOROPROPENE < o. 0010 o. 0010 mg/1 PAP 03/08/2004 0903
DIBROMOCHLOROMETHANE < 0. 0010 0.0010 mg/1 PAP 03/08/2004 0903
ETHYLBENZENE < 0. 001·0 0 .0010 mg/1 PAP 03/08/2004 0903
I METHYLENE CHLORIDE < 0. 0010 0. 0010 mg/1 PAP 03/08/2004 0903
STYRENE < 0. 0010 0 .0010 mg/1 PAP 03/08/2004 0903
TETRACHLOROETHENE < 0 .0010 0. 0010 mg/1 PAP 03/08/2004 0903
TOLUENE < 0.0010 0. 0010 mg/1 PAP 03/08/2004 0903
I TRANS-1,2-DICHLOROETHENE < o. 0010 0 .0010 mg/1 PAP 03/0B/2004 0903
TRANS-1,3-DICHLOROPROPENE < 0 .0010 0 .0010 mg/1 PAP 03/0B/2004 0903
TRICHLOROETHENE < 0 . 0010 o . 0010 mg/1 PAP 03/0B/2004 0903
VINYL ACETATE < 0.0010 0. 0010 mg/1 PAP 03/08/2004 0903 I VINYL CHLORIDE < o. 0010 o. 0010 mg/1 PAP 03/08/2004 0903
XYLENE (TOTAL) < 0 . 0020 0. 002 0 mg/1 PAP 03/08/2004 0903
.Davi; & Floyd, Inc: I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue l Greenwood, SC 29649 I [phone] I Fax [phone]
7
DAYIS
FLtrYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
Client ID: ITEF
ParAl!IOter
Wet Chemistry
SW846 9060
Matrix
ORGANIC CARBON, TOTAL
GW/Chemw
Result Qual
19.6
NC Certification Number: 25
Project. N~l!lbe,r: 61621. 01
Report Date
Page B of 75
March 24, 2004
Report ID: AB23157
Sample ID L04030101-01
Date Collected: 02/25/2004 1030
Date Received 02/26/2004
RDL Units Analyst
1.0 CBN
Date
03/02/2004 0206
Davis & Floyd, Inc. ) PO Drawer 428 / Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 / [phone] I Fax {864) 229-7119
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DAYIS
FLtfYD
Client
Contact
Client ID:
Matrix
Parameter
Gas Chromatography
SWB':16 8015
ETHYLENE GLYCOL
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOF'ORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DIQILOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
LABORATORY ANALYSIS REPORT
NC Certification Number: 25
TICONA,LLC Project Number: 61621.01
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Da~e March 24, 2004
Pem Carter Page 9 of 75 Report ID: AB23157
ITEF DUP, Sample ID L04030101-02
Date Collected: 02/25/2004 1030
GW/ChemW Date Received 02/26/2004
Result Qual RDL Units Analyst Date Time
' 7.0 7.0 mg/1 MGB 03/09/2004 114 9
' 0 .0010 0 .0010 mg/1 PAP 03/08/2004 1049
' 0 . 0010 o . 0010 mg/1 PAP 0)/08/2004 1049
' 0. 0010 0 . 0010 mg/1 PAP 03/08/2004 104 9
' o. 0010 0 . 0010 mg/1 PAP 03/08/2004 1049
' 0.0010 0. 0010 mg/1 PAP 03/06/2004 1049
' 0.0010 0.0010 mg/1 PAP 03/06/2004 1049
' 0.0010 0.0010 mg/1 PAP 03/08/2004 1049
0.010 o. 0050 mg/1 PAP 03/08/2004 1049
' 0.0050 0 .0050 mg/1 PAP 03/08/2004 1049
' 0.0050 o. 0050 mg/1 PAP 03/08/2004 1049
0.049 0 .0050 mg/1 PAP 03/0B/2004 1049
' 0 . 0010 0 .0010 mg/1 PAP 03/08/2004 1049
' 0 .0010 o. 0010 mg/1 PAP 03/08/2004 1049
' 0.0010 0 .0010 mg/1 PAP 03/08/2004 1049
' 0.0010 o. 0010 mg/1 PAP 03/08/2004 1049
' o. 0010 0.0010 rng/1 PAP 03/08/2004 1049
' o. 0010 0.0010 mg/1 PAP 03/08/2004 1049
' 0 .0010 0.0010 rng/1 PAP 03/08/2004 1049
' 0. 0010 0.0010 mg/1 PAP 03/08/2004 104 9
' 0. 0010 0 .0010 mg/1 PAP 03/08/2004 1049
' 0 . 0010 o . 0010 mg/1 PAP 03/08/2004 1049
' 0.0010 0 .0010 mg/1 PAP 03/08/2004 1049
' 0 .0010 0 .0010 mg/1 PAP 03/08/2004 1049
' 0 .0010 0.0010 mg/1 PAP 03/08/2004 1049
' o. 0010 0 .0010 mg/1 PAP 03/06/2004 1049
' 0.0010 o. 0010 mg/1 PAP 03/08/2004 l 04 9
' o. 0010 0. 0010 mg/1 PAP 03/08/2004 1049
' 0 .0010 0 . 0010 mg/1 PAP 03/08/2004 1049
' 0.0010 0 .0010 mg/1 PAP 03/08/2004 104 9
' 0.0010 o. 0010 mg/1 PAP 03/08/2004 1049
' 0 .0010 0 .0010 mg/1 PAP 03/08/2004 1049
' 0 . 0010 o . 0010 mg/1 PAP 03/08/2004 104 9
' 0. 0010 0. 0010 mg/1 PAP 03/08/2004 104 9
' 0 .0010 0 . 0010 mg/1 PAP 03/08/2004 1049
' 0. 0020 0 .0020 mg/1 PAP 03/08/2004 104 9
I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue / Greenwood, SC 29649 I [phone] I Fax [phone]
9
DAYIS
FLtfYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
Client ID: ITEF DUP.
Parameter
Wet Chemistry
SW846 9060
Matrix
ORGANIC CARBON, TOTAL
GW/ChemW
Result Qual
16.3
NC Certification Number: 25
Project Number, 61621.01
Report Date
Page 10 of 75
March 24, 2004
Report ID: AB23157
Sample ID L04030101-02
Date Collected: 02/25/2004 1030
Date Received 02/26/2004
RDL Units Analyst Date Time
1.0 mg/1 CBN 03/02/2004 0237
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue / Greenwood, SC 29649 I [phone] I Fax [phone]
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FLMD
Client
Contact
Client
Matrix
Parameter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
ID:
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
l,2~DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
.CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
LABORATORY ANALYSIS REPORT
NC Certification Number: 25
TICONA,LLC Project Number, 61621.01
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date March 24, 2004
Pem Carter Page 11 of 75 Report ID: AB23157
ITCI Sample ID L04030101-03
Date Collected, 02/25/2004 1040
GW/ChemW Date Received 02/26/2004
Result Qual RDL Units Analyst Date Time
1340 140 mg/1 MGB 03/09/2004 1332
< 0.0010 0.0010 mg/1 PAP 03/08/2004 0920
< 0.0010 0.0010 mg/1 PAP 03/08/2004 0920
< 0.0010 o. 0010 mg/1 PAP 03/08/2004 0920
< 0.0010 0. 0010 mg/1 PAP 03/08/2004 0920
< 0 .0010 o. 0010 mg/1 PAP 03/08/2004 0920
< 0. 0010 o. 0010 mg/1 PAP 03/08/2004 0920
< o. 0010 0 .0010 mg/1 PAP 03/08/2004 0920
< 0 . 0050 o. 0050 mg/1 PAP 03/08/2004 0920
< 0. 0050 0.0050 mg/1 PAP 03/08/2004 0920
< 0.0050 0. 0050 mg/1 PAP 03/08/2004 0920
< 0.0050 o. 0050 mg/1 PAP 03/08/2004 0920
0.018 o. 0010 mg/1 PAP 03/08/2004 0920
< o. 0010 0. 0010 mg/1 PAP 03/08/2004 0920
< 0 .0010 0 . 0010 mg/1 PAP 03/08/2004 0920
< 0. 0010 0.0010 mg/1 PAP 03/08/2004 0920
< 0.0010 0.0010 mg/1 PAP 03/08/2004 0920
< 0.0010 0.0010 mg/1 PAP 03/08/2004 0920
0.022 0 .0010 mg/1 PAP 03/0B/2004 0920
< o. 0010 0 . 0010 mg/1 PAP 03/08/2004 0920
< 0 . 0010 0. 0010 mg/1 PAP 03/08/2004 0920
< 0 .0010 0 .0010 mg/1 PAP 03/08/2004 0920
< o. 0010 o. 0010 mg/1 PAP 03/08/2004 0920
< o. 0010 0.0010 mg/1 PAP 03/08/2004 0920
< o. 0010 0.0010 mg/1 PAP 03/08/2004 0920
< o. 0010 0 . 0010 mg/1 PAP 03/08/2004 0920
< o. 0010 0. 0010 mg/1 PAP 03/08/2004 0920
< 0.0010 0 .0010 mg/1 PAP 03/08/2004 0920
< o. 0010 o. 0010 mg/1 PAP 03/08/2004 0920
< o. 0010 0. 0010 mg/1 PAP 03/08/2004 0920
0.0010 0 .0010 mg/1 PAP 03/08/2004 0920
< o. 0010 0.0010 mg/1 PAP 03/08/2004 0920
< o. 0010 0 .0010 mg/1 PAP 03/08/2004 0920
o. 0010 0 .0010 mg/1 PAP 03/08/2004 0920
< 0 .0010 0.0010 mg/1 PAP 03/08/2004 0920
< o. 0020 0. 002 0 mg/1 PAP 03/08/2004 0920
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
11
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
Client ID: ITCI
Parameter
Wet Chemistry
SW846 9060
Matrix
ORGANIC CARBON, TOTAL
GW/ChemW
Result Qual
1820
NC Certificarion Number: 25
Project Number: 61621 .. 0_1_
Report Date March 24, 2004
Page 12 of 75 Report ID: AB23157
Sample IO L04030101-03
Date Collected: 02/25/2004 1040
Date Received 02/26/2004
RDL Units Analyst
20.0 mg/1 CBN
Date Time
03/02/2004 0310
Davis & Floyd, Inc. ) PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
1 2
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D~S I LABORATORY ANALYSIS REPORT FL D
I NC Certification Number: 25
I Client TICONA, LLC Project Number, 61621.01
2525 BLACKSBURG ROAD
HWY 198
I SHELBY, NC 28152 Report Date March 24, 2004
Contact Pem Carter Page 13 of 75 Report ID: AB23157
Client ID: TRIP BLANK Sample ID L04030101-04
I Date Collected: 02/20/2004 0850
Matrix : GW/ChemW Date Received 02/26/2004
Parameter Re11ult Qual RDL units Analyst Date Time I Volatile Organics
SW846 8260B
I 1,1,1-TRICHLOROETHANE < o. 0010 0 .0010 mg/1 PAP 03/08/2004 0956
1,1,2,2-TETRACHLOROETHANE < o. 0010 0 .0010 mg/1 PAP 03/08/2004 0956
1,1,2-TRICHLOROETHANE < 0.0010 0. 001,0 mg/1 PAP 03/08/2004 0956
1,1-DICHLOROETHANE < 0 .0010 o. 0010 mg/1 PAP 03/08/2004 0956
I 1,1-DICHLOROETHENE < 0 .. 0010 0 .0010 mg/1 PAP 03/08/2004 0956
1,2-DICHLOROETHANE < o. 0010 0. 0010 mg/1 PAP 03/08/2004 0956
1,2-DICHLOROPROPANE < o. 0010 o. 0010 mg/1 PAP 03/08/2004 0956
2-BUTANONE < 0. 0050 0 . 0050 mg/1 PAP 03/08/2004 0956 I 2-HEXANONE < 0. 0050 o. 0050 mg/1 PAP 03/08/2004 0956
4-METHYL-2-PENTANONE < 0. 0050 0. 0050 mg/1 PAP 03/09/2004 0956
ACETONE < 0 .0050 0 . 0050 mg/1 PAP 03/08/2004 0956
I BENZENE < 0 . 0010 0 .0010 mg/1 PAP 03/08/2004 0956
BROMODICHLOROMETHANE < 0 . 0010 0.0010 mg/1 PAP 03/08/2004 0956
BROMOFORM < o. 0010 0.0010 mg/1 PAP 03/08/2004 0956
BROMOMETHANE < 0 . 0010 0.0010 mg/1 PAP 03/08/2004 0956
I CARBON DISULFIDE < o. 0010 0.0010 mg/1 PAP 03/08/2004 0956
CARBON TETRACHLORIDE < 0 .0010 0.0010 mg/1 PAP 03/08/2004 0956
CHLOROBENZENE < 0 .0010 0.0010 mg/1 PAP 03/08/2004 0956
CHLOROETHANE ' 0. 0010 0 .0010 mg/1 PAP 03/08/2004 0956 I CHLOROFORM < 0.0010 0. 0010 mg/1 PAP 03/08/2004 0956
CHLOROMETHANE < 0 .0010 0.0010 mg/1 PAP 03/08/2004 0956
CIS-1,2-DICHLOROETHENE < 0 . 0010 0. 0010 mg/1 PAP 03/08/2004 0956
I CIS-1,3-DICHLOROPROPENE < 0 .0010 o. 0010 mg/1 PAP 03/08/2004 0956
DIBROMOCHLOROMETHANE < 0 .0010 0 .0010 mg/1 PAP 03/08/2004 0956
ETHYLBENZENE < o. 0010 0. 0010 mg/1 PAP 03/08/2004 0956
METHYLENE CHLORIDE < 0. 0010 0.0010 mg/1 PAP 03/08/2004 0956
I STYRENE < 0.0010 0. 0010 mg/1 PAP 03/09/2004 0956
TETRACHLOROETHENE < 0.0010 0.0010 mg/1 PAP 03/08/2004 0956
TOLUENE < 0.0010 0 .0010 mg/1 PAP 03/08/2004 0956
I TRANS-1,2-DICHLOROETHENE < 0.0010 o. 0010 mg/1 PAP 03/08/2004 0956
TRANS-1,3-DICHLOROPROPENE < 0.0010 0. 0010 mg/1 PAP 03/08/2004 0956
TRICHLOROETHENE < 0 . 0010 0 .0010 mg/1 PAP 03/08/2004 0956
VINYL ACETATE < 0 .0010 0 .0010 mg/1 PAP 03/08/2004 0956
I VINYL CHLORIDE < 0 . 0010 0 . 0010 mg/1 PAP 03/08/2004 0956
XYLENE (TOTAL) < 0.0020 0.0020 mg/1 PAP 03/08/2004 0956
I
.Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 j 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
13
DAYIS
FLtfYD LABORATORY ANALYSIS REPORT
NC Certification Number: 25
Client TICONA,LLC Project Number: 61621.01
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date March 24, 2004
Contact Pem carter Page 14 of 75 Report ID: AB2J157
Client ID: PEW-01 Sample ID L04030402-01
Date Collected: 03/03/2004 0755
Matrix GW/ChemW Date Received 03/03/2004
Parameter Result Qual RDL Units Analyst Date Time
Semi volatile Organics
SW846 8270C
1, 2, 4-TRICHLOROBENZENE ' 0. OlO 0 .010 mg/1 DBC 03/16/2004 1507
1, 2 ,-DICHLOROBENZENE ' 0. 010 0. 010 mg/1 DBC 03/16/2004 1507
1,3-DICHLOROBENZENE ' 0. 010 0 .010 mg/1 DBC 03/16/2004 1507 1,4-0ICHLOROBENZENE ' 0.010 0 .010 mg/1 DBC 03/16/2004 1507 2,4,5-TRICHLOROPHENOL ' 0. 010 o. 010 mg/1 DBC 03/16/2004 1507
2,4,6-TRICHLOROPHENOL ' 0.010 0 .010 mg/1 DBC 03/16/2004 1507
2,4-0ICHLOROPHENOL ' 0.010 o. 010 mg/1 DBC 03/16/2004 1507
2,4-DIMETHYLPHENOL ' 0.010 0. 010 mg/1 DBC 03/16/2004 1507
2,4-DINITROPHENOL ' 0.025 0.025 mg/1 DBC 03/16/2004 1507
2,4-DINITROTOLUENE ' o. 010 0.010 mg/1 DBC 03/16/2004 1507
2,6-DINITROTOLUENE ' 0. 010 0. 010 mg/1 DBC 03/16/2004 1507
2-CHLORONAPHTHALENE ' o. 010 o. 010 mg/1 DBC 03/16/2004 1507
2-CHLOROPHENOL ' 0 .010 0. 010 mg/1 DBC 03/16/2004 1507
2 -METHYL-4, 6-DINITROPHENOI, ' o. 025 o. 025 mg/1 DBC 03/16/2004 1507
2-METHYLNAPHTHALENE ' 0 .010 0 .010 mg/1 DBC 03/16/2004 1507
2-METHYLPHENOL ' 0.010 0. 010 mg/1 DBC 03/16/2004 1507
2-NITROANILINE ' 0.010 0 .010 mg/1 DBC 03/16/2004 1507
2-NITROPHENOL ' 0. 010 0.010 mg/1 DBC 03/16/2004 1507
3,3'-DICHLOROBENZIDINE ' 0.010 0 .010 mg/1 DBC 03/16/2004 1507
3-NITROANI LINE ' 0.010 0.010 mg/1 DBC 03/16/2004 1507
4-BROMOPHENYL PHENYL ETHER ' o. 010 o. 010 mg/1 DBC 03/16/2004 1507
4-CHLOR0-3-METHYLPHENOL ' 0. 010 0. 010 mg/1 DBC 03/16/2004 1507
4-CHLOROANILINE ' 0 .010 0.010 mg/1 DBC 03/16/2004 1507
4-CHLOROPHENYL PHENYL ETHER ' 0.010 0.010 mg/1 DBC 03/16/2004 1507
4-METHYLPHENOL ' 0.010 0 .010 mg/1 DBC 03/16/2004 1507
4-NITROANILINE ' 0.010 0. 010 mg/1 DBC 03/16/2004 1507
4-NITROPHENOL ' 0. 025 0 .025 mg/1 DBC 03/16/2004 1507
ACENAPHTHENE ' 0 .010 0 .010 mg/1 DBC 03/16/2004 1507
ACENAPHTHYLENE ' 0 .010 0.010 mg/1 DBC 03/16/2004 1507
ANTHRACENE ' 0. 010 0 .010 mg/1 DBC 03/16/2004 1507
BENZO(A)ANTHRACENE ' 0 .010 0 .010 mg/1 DBC 03/16/2004 1507
BENZO {A) PYRENE ' 0 .010 0 .010 mg/1 DBC 03/16/2004 1507
BENZO(B)FLUORANTHENE ' o. 010 0 .010 mg/1 DBC 03/16/2004 1507
BENZO{G,H,I)PERYLENE ' 0 .010 0 .010 mg/1 DBC 03/16/2004 1507
BENZO(K)FLUORANTHENE ' o. 010 0 .010 mg/1 DBC 03/16/2004 1507
BENZOIC ACID ' 0 .050 0 .oso mg/1 DBC 03/16/2004 1507
BENZYL ALCOHOL ' 0. 010 0 .010 mg/1 DBC 03/16/2004 1507
BIS(2-CHLOROETHOXY)METHANE ' o. 010 o. 010 mg/1 DBC 03/16/2004 1507
BIS (2-CHLOROETHYL) ETHER ' 0 .010 0 .010 mg/1 DBC 03/16/2004 1507
B1S(2-CHLOROISOPROPYL)ETHER ' o. 010 0 .010 mg/1 DBC 03/16/200'1 1507
Davis & Floyd, Inc. I PO Drawer 428 / Greenwood, SC 29648 / 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
14
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Client TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
Contact
SHELBY, NC 28152
Pem Carter
Client ID: PEW-01
Matrix : GW/ChemW
Para.meter
BIS{2-ETHYLHEXYL)PHTHALATE
BUTYL BENZYL PHTHALATE
CHRYSENE
DI-,N-BUTYL PHTHALATE
DI-N-OCTYL PHTHALATE
DIBENZ(A,H)ANTHRACENE
DIBENZOFURAN
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
FLUORANTHENE
FLUORENE
HEXACHLOROBENZENE
HEXACHLOROBUTADIENE
HEXACHLOROCYCLOPENTADIENE
HEXACHLOROETHANE
INDENO(l,2,3-CD)PYRENE
ISOPHORONE
N-NITROSODI-N-PROPYLAMINE
N-NITROSODIPHENYLAMINE
NAPHTHALENE
NITROBENZENE
PENTACHLOROPHENOL
PHENANTHRENE
PHENOL
PYRENE
SW846 8270C DOWTHERM
1, l' -BI PHENYL
BI PHENYL ETHER
Volatile Organics
SW846 8260B
1, 1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
'
'
'
'
'
' '
'
'
'
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'
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'
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'
Result
0. 010
0 .010
0. 010
o. 010
0 .010
0. 010
0. 010
0 .010
0 .010
o. 010
0 .010
0. 010
o. 010
0 .010
0. 010
0 . 010
0 .010
o. 010
0. 010
0 .010
0. 010
0.025
0. 010
0. 010
0.010
0. 010
0.010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0. 0050
0. 0050
0 .0050
o. 0050
Qual
NC Certification Number: 25
Project Number: 61621.0l
Report Date
Page 15 of 75
March 24, 2004
Report ID: AB23157
Sample ID L04030402-0l
Date Collected: 03/03/2004 0755
Date Received 03/03/2004
RDL Units Analyst
0.010 mg/1 DBC
0.010 mg/1 DBC
0. 010 mg/1 DBC
o. 010 mg/1 DBC
0 .010 mg/1 DBC
0. 010 mg/1 DBC
0.010 mg/1 DBC
0 .010 mg/1 DBC
0 .010 mg/1 DBC
0. 010 mg/1 DBC
0.010 mg/1 DBC
0.010 mg/1 DBC
0.010 mg/1 DBC
0.010 mg/1 DBC
0 .010 mg/1 DBC
o . 010 mg/1 DBC
0. 010 mg/1 DBC
0. 010 mg/1 DBC
0.010 mg/1 DBC
0. 010 mg/1 DBC
0. 010 mg/1 DBC
0.025 mg/1 DBC
0.010 mg/1 DBC
0. 010 mg/1 DBC
0.010 mg/1 DBC
o. 010 mg/1 DBC
0. 010 mg/1 DBC
0.0010 mg/1 PAP
0.0010 mg/1 PAP
0. 0010 mg/1 PAP
0 .0010 mg/1 PAP
0 .0010 mg/1 PAP
0. 0010 mg/1 PAP
0. 0010 mg/1 PAP
0. 0050 mg/1 PAP
o. 0050 mg/1 PAP
0.0050 mg/1 PAP
0.0050 mg/1 PAP
Date
03/16/2004
03/16/2004
03/16/2004
03/16/2004
03/16/2004
03/16/2004
03/16/2004
03/16/2004
03/16/2004
03/16/2004
03/16/2004
03/16/2004
03/16/2004
03/16/2004
03/16/2004
03/16/2004
03/16/2004
03/16/2004
03/16/2004
03/16/2004
03/16/2004
03/16/2004
03/16/2004
03/16/2004
03/16/2004
03/16/2004
03/16/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
Time
1507
1507
1507
1507
1507
1507
1507
1507
1507
1507
1507
1507
1507
1507
1507
1507
1507
1507
1507
1507
1507
1507
1507
1507
1507
1507
1507
1124
1124
1124
1124
1124
1124
1124
1124
1124
1124
1124
.Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 / 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
15
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
Client ID: PEW-01
'Matrix
Parameter
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BRQMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1, 3-_DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
Prep Procedure
Analytical Prep Procedures:
DOWTHERM
BNA SEMIVOLATILES
GW/Chemw
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
Method
SW846 3500B
SW846 3510C
Result Qual
0 .0010
0. 0010
0. 0010
0. 0010
0 .0010
0.0010
0.0010
0.0010
0.0017
0.0010
0.0014
0 .0010
0. 0010
0 .0010
0. 0010
0 .0010
0 .0010
0.0010
0.0010
0.0010
o.ooss
0.0010
0.0010
0.0020
Analyst
DBC
bBC
NC Cenijication Number: 25
Project Number: 61621.01
Report Date
Page 16 of 75
March 24, 2004
Report ID: AB23157
Sample ID L04030402-0l
Date Collected: 03/03/2004 0755
Date Received 03/03/2004
RDL Units
0 .0010 mg/1
0. 0010 mg/1
0 .0010 mg/1
0.0010 mg/1
0 .0010 mg/1
0 . 0010 mg/1
0. 0010 mg/1
0.0010 mg/1
0.0010 mg/!
0.0010 mg/1
0.0010 mg/1
0.0010 mg/1
0.0010 mg/1
0.0010 mg/1
0.0010 mg/1
0.0010 mg/1
0.0010 mg/1
0.0010 mg/1
0.0010 mg/1
0.0010 mg/1
0.0010 mg/1
0.0010 mg/1
0.0010 mg/1
0.0020 mg/1
Prep Date
03/08/2004 0800
03/08/2004 0800
Analyst
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
Date
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
Time
1124
1124
1124
1124
1124
1124
1124
1124
1124
1124
1124
1124
1124
1124
1124
1124
1124
1124
1124
1124
1124
1124
1124
1124
Davis & Floyd, Inc. / PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I {864) 229-44 I 3 I Fax [phone]
16
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DM'IS
FLfwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
Client ID: PEW-03
Matrix
Parameter
Semivolatile Organics
SW846 8270C
1,2,4-TRICHLOROBENZENE
1,2-DICHLOROBENZENE
1,3-DICHLOROBENZENE
1,4-DICHLOROBENZENE
2,4,5-TRICHLOROPHENOL
2,4,6-TRICHLOROPHENOL
2,4-DICHLOROPHENOL
2,4-DIMETHYLPHENOL
2,4-DINITROPHENOL
2,4-DINITROTOLUENE
2,6-DINITROTOLUENE
2-CHLORONAPHTHALENE
2-CHI,OROPHENOL
2-METHYL-4,6-DINITROPHENOL
2-METHYLNAPHTHALENE
2 -METHYLPHENOL
2-NITROANILINE
2-NITROPHENOL
GW/ChemW
3, 3' -DICHLOROBENZIDINE
3-NITROANILINE
4-BROMOPHENYL PHENYL ETHER
4-CHLOR0-3-METHYLPHENOL
4-CHLOROANILINE
4-CHLOROPHENYL PHENYL ETHER
4-METHYLPHENOL
4-NITROANILINE
4-NITROPHENOL
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZO(A)ANTHRACENE
BENZO(A)PYRENE
BENZO(B)FLUORANTHENE
BENZO(G,H,I)PERYLENE
BENZO(K)FLUORANTHENE
BENZOIC ACID
BENZYL ALCOHOL
BIS(2-CHLOROETHOXY)METHANE
81S(2-CHLOROETHYL)ETHER
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Result Qual
0.010
0. 010
0.010
0.010
·o. 010
0 .010
0 .010
o. 010
0 .025
0.010
0.010
0.010
0 .010
0 .025
0 .010
0. 010
0. 010
0. 010
0.010
0. 010
0.010
0. 010
0 .010
0. 010
0.010
0 .010
0. 025
0 .010
0 . 01·0
0 .010
0 .010
0 .010
0. 010
0. 010
0 .010
0 .050
0.010
0.010
0.010
NC Cenijication Number: 25
Project Number: 61621.01
Report Date
Page 17 of 75
March 24, 2004
Report ID: AB23157
Sample ID L04030402-02
Date Collected: 03/03/2004 0825
Date Received 03/03/2004
RDL Units Analyst Date
0. 010 mg/1 □BC 03/16/2004
o. 010 mg/1 □BC 03/16/2004
0.010 mg/1 DBC 03/16/2004
0 .010 mg/1 DBC 03/16/2004
0 .010 mg/1 OBC 03/16/2004
0. 010 mg/1 DBC 03/16/2004
0.010 mg/1 DBC 03/16/2004
0 .010 mg/1 DBC 03/16/2004
0. 025 mg/1 DBC 03/16/2004
0.010 mg/1 □BC 03/16/2004
0. 010 mg/1 DBC 03/16/2004
0 .010 mg/1 DBC 03/16/2004
0.010 mg/1 DBC 03/16/2004
0. 025 mg/1 DBC 03/16/2004
0 .010 mg/1 DBC 03/16/2004
0. 010 mg/1 DBC 03/16/2004
0 .010 mg/1 DBC 03/16/2004
0. 010 mg/1 DBC 03/16/2004
0.010 mg/1 DBC 03/16/2004
0. 010 mg/1 DBC 03/16/2004
0. 010 mg/1 DBC 03/16/2004
0 .010 mg/1 DBC 03/16/2004
0 .010 mg/1 DBC 03/16/2004
0. 010 mg/1 DBC 03/16/2004
o. 010 mg/1 DBC 03/16/2004
0. 010 mg/1 DBC 03/16/2004
0.025 mg/1 DBC 03/16/2004
0. 010 mg/1 DBC 03/16/2004
0. 010 mg/1 DBC 03/16/2004
0 .010 mg/1 DBC 03/16/2004
0. 010 mg/1 □BC 03/16/2004
0. 010 mg/1 DBC 03/16/2004
0. 010 mg/1 DBC 03/16/2004
0 .010 mg/1 DBC 03/16/2004
0. 010 mg/1 □BC 03/16/2004
0 .050 mg/1 DBC 0)/16/2004
0. 010 mg/1 DBC 03/16/2004
0. 010 mg/1 DBC 03/16/2004
0. 010 mg/1 □BC 03/16/2004
Time
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
' 0.010 BIS(2-CHLOROISOPROPYL)ETHER 0.010 mg/1 DSC 03/16/2004 1727
I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 2%49 I [phone] I Fax (864} 229-7119 'Davis & Fluyd, Inc.
1 7
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
Client ID: PEW-03
,Matrix
Parameter
BIS(2-ETHYLHEXYL)PHTHALATE
BUTYL BENZYL PHTHALATE
CHRYSENE
DI-_N-BUTYL PHTHALATE
DI -N-OCTYL PHTHALATE
OIBENZ(A,H)ANTHRACENE
DIBENZOFURAN
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
FLUORANTHENE
FLUORENE
HEXACHLOROBENZENE
HEXACHLOROBUTADIENE
HEXACHLOROCYCLOPENTADIENE
HEXACHLOROETHANE
INDENO(l,2,3-CD)PYRENE
ISOPHORONE
N-NITROSODI-N-PROPYLAMINE
N-NITROSODIPHENYLAMINE
NAPHTHALENE
NITROBENZENE
PENTACHLOROPHENOL
PHENANTHRENE
PHENOL
PYRENE
SW846 8270C DOWTHERM
1,1'-BIPHENYL
BIPHENYL ETHER
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
GW/ChemW
<
<
<
<
<
<
<
<
<
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<
<
<
<
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<
<
<
<
<
<
<
<
<
<
Result Qual
0.010
0.010
0. 010
0. 010
0. 010
0 .010
-0. 010
0. 010
0 .010
0 .010
0. 010
0. 010
0 .010
0. 010
0 .010
0 .010
0.010
0.010
0. 010
0.010
0 . 010
0.025
0.010
0.010
0.010
0.46
1.'
0.0010
0.0010
0.0010
0.0010
0. 0010
o. 0010
0.0010
0,0065
0.0050
0 .0050
NC Cenijication Number: 25
Project Number: -~_?.?.21..9.~-
Report Date
Page 18 of 75
March 24, 2004
Report ID; AB23157
Sample ID L04030402-02
Date Collected: 03/03/2004 0825
Date Received 03/03/2004
RDL Units Analyst Date
0. 010 mg/1 DBC 03/16/2004
0.010 mg/1 DBC 03/16/2004
0. 010 mg/1 DBC 03/16/2004
0.010 mg/1 DBC 03/16/2004
0 .Ol'O mg/1 DBC 03/16/2004
0 .010 mg/1 DBC 03/16/2004
0 .010 mg/1 DBC 03/16/2004
0.010 mg/1 DBC 03/16/2004
0.010 mg/1 DBC 03/16/2004
0. 010 mg/1 DBC 03/16/2004
0 .010 mg/1 DBC 03/16/2004
0 .010 mg/1 DBC 03/16/2004
0. 010 mg/1 DBC 03/16/2004
o. 010 mg/1 DBC 03/16/2004
0 .010 mg/1 DBC 03/16/2004
0.010 mg/1 DBC 03/16/2004
0.010 mg/1 DBC 03/16/2004
0. 010 mg/1 DBC 03/16/2004
0. 010 mg/1 DBC 03/16/2004
o. 010 mg/1 DBC 03/16/2004
0.010 mg/1 DBC 03/16/2004
0.025 mg/1 DBC 03/16/2004
0.010 mg/1 DBC 03/16/2004
0.010 mg/1 DBC 03/16/2004
0.010 mg/1 DBC 03/16/2004
0 .20 mg/1 DBC 03/17/2004
0 .20 mg/1 DBC 03/17/2004
0.0010 mg/1 PAP 03/08/2004
0.0010 mg/1 PAP 03/08/2004
0.0010 mg/1 PAP 03/08/2004
0.0010 mg/1 PAP 03/08/2004
0.0010 mg/1 PAP 03/08/2004
o. 0010 mg/1 PAP 03/08/2004
o. 0010 mg/1 PAP 03/08/2004
0 . 0050 mg/1 PAP 03/08/2004
o. 0050 mg/1 PAP 03/08/2004
0.0050 mg/1 PAP 03/08/2004
Time
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
1727
0033
0033
1142
1142
1142
1142
1142
1142
1142
1142
1142
1142
ACETONE 0.0050 mg/1 PAP 03/08/2004 1142 < 0, 0050
D,ivis & Floyd, Inc. I PO Drawer 428 ) Greenwood, SC 29648 / 816 E. Durst Avenue ! Greenwood, SC 29649 I [phone] I Fax [phone]
18
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
Client ID: PEW-03
Matrix
Parameter
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
Prep Procedure
Analytical Prep Proceduresz
DOWTHERM
BNA SEMIVOLATILES
GW/ChemW
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
Method
SW846 3500B
SW846 3510C
Result Qual
0.0010
0 . 0010
0. 0010
0 . 0010
0. 0010
0. 0010
0 .0010
0 . 0010
0 .0010
0. 0010
0. 0010
0 .0010
0.0010
o. 0010
o. 0010
o. 0010
0. 0010
0. 0010
0 . 0010
0.0010
0 . 0010
0 .0010
0 .0010
0. 0020
Analyst
DSC
DBC
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 19 of 75
March 24, 2004
Report ID: AB23157
Sample ID L04030402-02
Date Collected: 03/03/2004 0825
Date Received
RDL Units
0 .0010 mg/1
0 . 0010 mg/1
0 .0010 mg/1
o . 0010 mg/1
0. 001 ,0 mg/1
0 .0010 mg/1
0 .0010 mg/1
0 .0010 mg/1
0 . 0010 mg/1
0.0010 mg/1
0 .0010 mg/1
0 .0010 mg/1
0. 0010 mg/1
0 .0010 mg/1
0 .0010 mg/1
0 .0010 mg/1
0.0010 mg/1
0.0010 mg/1
0 .0010 mg/1
0 . 0010 mg/1
o . 0010 mg/1
0.0010 mg/1
0.0010 mg/1
0. 0020 mg/1
Prep Date
03/08/2004 0800
03/08/2004 0800
03/03/2004
Analyst
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
Date
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
Time
1142
1142
1142
1142
1142
1142
1142
1142
1142
1142
1142
1142
1142
1142
1142
1142
1142
1142
1142
1142
1142
1142
1142
1142
I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue ( Greenwood, SC 29649 j [phone] I Fax [phone]
1 9
DAYIS
FLlWD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
Client ID: PEW-03 DUP.
Matrix
Parameter
Semivolatile Organics
SWB46 8270C
1,2,4-TRICHLOROBENZENE
1,2-DICHLOROBENZENE
1,3-DICHLOROBENZENE
1,4-DICHLOROBENZENE
2,4,5-TRICHLOROPHENOL
2,4,6-TRICHLOROPHENOL
2,4-DICHLOROPHENOL
2,4-DIMETHYLPHENOL
2,4-DINITROPHENOL
2,4-DINITROTOLUENE
2,6-0INITROTOLUENE
2-CHLORONAPHTHALENE
2-CHLOROPHENOL
2-METHYL-4,6-DINITROPHENOL
2-METHYLNAPHTHALENE
2-METHYLPHENOL
2-NITROANILINE
2-NITROPHENOL
3,3'-DICHLORQBENZIDINE
GW/Chemw
3 -NITROANILINE
4-BROMOPHENYL PHENYL ETHER
4 -CHLORO-3 -METHYLPHENOL
4-CHLOROANILINE
4-CHLOROPHENYL PHENYL ETHER
4-METHYLPHENOL
4-NITROANILINE
4-NITROPHENOL
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZO(A)ANTHRACENE
BENZO(A)PYRENE
BENZO(B)FLUORANTHENE
BENZO(G,H,I)PERYLENE
BENZO{K)FLUORANTHENE
BENZOIC ACID
BENZYL ALCOHOL
BIS(2-CHLOROET!-IOXY)METHANE
B1$(2-CHLOROETHYL)ETHER
BIS{2-CHLOROISOPR0PYL)ETHER
Result
0.010
0. 010
0. 010
0. 010
.o. 010
0. 010
0. 010
0.010
0. 025
0. 010
0. 010
0. 010
0.010
0. 025
0.010
0.010
0.010
0.010
0.010
0.010
0.010
0.010
0.010
0.010
0.010
0.010
0.025
0.010
O.OJ-0
0. 010
0.010
0.010
0.010
0. 010
0.010
0.050
0.010
0. 010
0.010
0.010
Qual
NC Cenification Number: 25
Project Number: 61621.01
Report Date
Page 20 of 75
March 24, 2004
Report ID: AB23157
Sample ID L04030402-03
Date Collected: 03/03/2004 0825
Date Received
RDL
0.010
0. 010
0. 01;0
0. 010
0.010
0.010
0.010
0. 010
0.025
0.010
0.010
0.010
0.010
0.025
0.010
0. 010
0.010
0. 010
0.010
0.010
0.010
0. 010
0.010
0. 010
0.010
0. 010
0.025
0.010
0.010
0.010
0.010
0.010
0.010
0.010
0. 010
0.050
0.010
0.010
0. 010
0.010
Units
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/I
mg/1
mg/1
mg/I
mg/1
mg/1
mg/1
mg/1
mg/I
mg/1
mg/I
03/03/2004
Analyst
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
Date Time
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
OJ/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
0)/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/20~4 1842
0)/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 / 816 E. Durst Avenue ! Greenwood, SC 29649 I [phone] I Fax [phone]
20
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DAYIS
FLtfYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
Client ID: PEW-03 DUP.
Matrix
Parameter
BIS(2-ETHYLHEXYL)PHTHALATE
BUTYL BENZYL PHTHALATE
CHRYSENE
DI-N-BUTYL PHTHALATE
DI-N-OCTYL PHTHALATE
DIBENZ{A,H)ANTHRACENE
DIBENZOFURAN
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
FLUORANTHENE
FLUORENE
HEXACHLOROBENZENE
HEXACHLOROBUTADIENE
HEXACHLOROCYCLOPENTADIENE
HEXACHLOROETHANE
INDENO(l,2,3-CD)PYRENE
ISOPHORONE
N-NITROSODI-N-PROPYLAMINE
N-NITROSODIPHENYLAMINE
NAPHTHALENE
NITROBENZENE
PENTACHLOROPHENOL
PHENANTHRENE
PHENOL
PYRENE
SW846 8270C DOWTHERM
1, l' -Bl PHENYL
BIPHENYL ETHER
Volatile Organics
SW846 826GB
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
GW/ChemW
Result
0. 010
0. 010
0.010
0. 010
0. 010
0.010
0.010
0. 010
0.010
0.010
0. 010
0.010
0. 010
0. 010
0. 010
0.010
0. 010
0.010
0. 010
0. 010
0. 010
0.025
0.010
o. 019
0. 010
o.u , ..
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0059
0.0050
0.0050
0.0050
Qual
NC Cenijication Number: 25
Project Number: 61621.01
Report Date
Page 21 of 75
March 24, 2004
Report ID: AB23157
Sample ID L04030402-03
Date Collected: 03/03/2004 0825
Date Received
RDL
0.010
0. 010
0. 010
0.010
0. 010
0. 010
0.010
0.010
0.010
0. 010
0.010
0.010
0. 010
0.010
0. 010
0.010
0.010
0. 010
0.010
0.010
0.010
0.025
0. 010
0. 010
0.010
0.20
0.20
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
o.ooso
o.ooso
0.0050
0.0050
units
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
03/03/2004
Analyst
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
Date Time
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/16/2004 1842
03/17/2004 0111
03/17/2004 0111
03/08/2004 1228
03/08/2004 1228
03/08/2004 1228
03/08/2004 1228
03/08/2004 1228
03/08/2004 1228
03/08/2004 1228
03/08/2004 1228
03/08/2004 1228
03/08/2004 1228
OJ/08/2004 1228 r•vis & Floyd. Inc. I PO Drawer 428 I Greenwood, SC 29648 I 81 6 E. Durst Avenue I Greenwood, SC 29649 I {864) 229-4413 I Fax [phone]
21
D1\VIS
FLtfi'D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pcm Carter
Client 10: PBW-03 DUP.
Matrix
Para.meter
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
Prep Procedure
Analytical Prep Procedures:
OOWTHERM
BNA SEMIVOLATILES
GW/ChemW
Method
SW846 35008
SW846 3510C
Result
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0020
Qual
Analyst
DBC
·nee
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 22 of 75
March 24, 2004
Report ID: AB23157
Sample ID L04030402-03
Date Collected: 03/03/2004 0825
Date Received
RDL
0.0010
0.0010
0.0010
0.0010
0.00!0
0.0010
0.0010
0.0010
0. 0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0020
Units
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
Prep Date
03/08/2004 0800
03/08/2004 0800
03/03/2004
Analyst
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
Date Time
03/08/2004 1228
03/08/2004 1228
03/08/2004 1228
03/08/2004 1228
03/08/2004 1228
03/08/2004 1228
03/08/2004 1228
03/08/2004 1228
03/08/2004 1228
03/08/2004 1228
03/08/2004 1228
03/08/2004 1228
03/08/2004 1228
03/08/2004 1228
03/08/2004 1228
03/08/2004 1228
03/08/2004 1228
03/08/2004 1228
03/08/2004 1228
03/08/2004 1228
03/08/2004 1228
03/08/2004 1228
03/08/2004 1228
03/08/2004 1228
Davis & Floyd, Inc. I PO Drawer 428 / Greenwood, SC 29648 I 81 6 E. Durst Avenue I Greenwood, SC 29649 I [phone] j Fax [phone]
22
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D~S I FL D LABORATORY ANALYSIS REPORT
I NC Certification Number: 25
I Client TICONA,LLC Project Number: 61621. 01
2525 BLACKSBURG ROAD
HWY 198
I SHELBY, NC 28152 Report Date March 24, 2004
Contact Pem Carter Page 23 of 75 Report ID: AB23157
Client ID: PEW-0-i Sample ID L04030402-04
I Date Collected: 03/03/2004 0825
Matrix GW/ChemW Date Received 03/03/2004
I Parameter Result Qual RDL Units Analyst Date Time
Semi volatile Organics
SW846 8270C
I 1,2,4-TRICHLOROBENZENE < 0.010 0.010 mg/1 DBC 03/16/2004 1922
1,2-DICHLOROBENZENE < 0.010 0. 010 mg/1 DBC 03/16/2004 1922
1,3-DICHLOROBENZENE < 0.010 0. 010 mg/1 DBC 03/16/2004 1922
1,4-DICHLOROBENZENE < 0 .010 0. 010 mg/1 DBC 03/16/2004 1922
I 2,4,5-TRICHLOROPHENOL < -0 .010 0. 010 mg/1 DBC 03/16/2004 1922
2,4,6-TRICHLOROPHENOL < 0.010 0 .010 mg/1 DSC 03/16/2004 1922
2,4-DICHLOROPHENOL < 0.010 0 .010 mg/1 DSC 03/16/2004 1922
I 2,4-DIMETHYLPHENOL < 0.010 0 .010 mg/1 DBC 03/16/2004 1922
2,4-DINITROPHENOL < 0.025 0 . 025 mg/1 DBC 03/16/2004 1922
2,4-DINITROTOLUENE < o. 010 0.010 mg/1 DBC 03/16/2004 1922
2,6-DINITROTOLUENE < 0 .010 0.010 mg/1 DBC 03/16/2004 1922
I 2-CHLORONAPHTHALENE < 0.010 0.010 mg/1 DBC 03/16/2004 1922
2-CHLOROPHENOL < o. 010 0. 010 mg/I DBC 03/16/2004 1922
2-METHYL-4,6-DINITROPHENOL < 0 . 025 0 .025 mg/1 DBC 03/16/2004 1922
2-METHYLNAPHTHALENE ' 0.010 0. 010 mg/1 DBC 03/16/2004 1922
I 2-METHYLPHENOL < 0.010 o. 010 mg/1 DBC 03/16/2004 1922
2-NITROANILINE < 0.010 0 .010 mg/1 DBC 03/16/2004 1922
2-NITROPHENOL < 0 .010 0. 010 mg/1 DBC 03/16/2004 1922
I 3,3'-DICHLOROBENZIDINE < 0 .010 0. 010 mg/1 DBC 03/16/2004 1922
3-NITROANILINE < 0. 010 0.010 mg/1 DBC 03/16/2004 1922
4-BROMOPHENYL PHENYL ETHER < 0 .010 0 .010 mg/1 DBC 03/16/2004 1922
4-CHLOR0-3-METHYLPHENOL < 0. 010 0 .010 mg/1 DBC 03/16/2004 1922
I 4-CHLOROANILINE < 0. 010 0. 010 mg/1 DBC 03/16/2004 1922
4 -CHLOROPHENYL PHENYL ETHER < 0.010 0.010 mg/1 DBC 03/16/2004 1922
4-METHYLPHENOL < 0.010 0.010 mg/1 DBC 03/16/2004 1922
4-NITROANILINE < 0 .010 0. 010 mg/1 DBC 03/16/2004 1922
I 4 -N ITROPHENOL < 0. 025 0. 025 mg/1 DBC 03/16/2004 1922
ACENAPHTHENE < 0 . 010 0 . 010 mg/1 DBC 03/16/2004 1922
ACENAPHTHYLENE < o. OIO o. 010 mg/1 DBC 03/16/2004 1922
I ANTHRACENE < o. 010 0 .010 mg/1 DSC 03/16/2004 1922
BENZO(A)ANTHRACENE < 0. 010 0 .010 mg/1 DBC 03/16/2004 1922
BENZO(A)PYRENE < 0 .010 0 .010 mg/1 DBC 03/16/2004 1922
BENZO(B)FLUORANTHENE < 0 .010 0. 010 mg/1 DBC 03/16/2004 1922
I BENZO(G,H,I)PERYLENE < 0. 010 0. 010 mg/1 DBC 03/16/2004 1922
BENZO(K)FLUORANTHENE < 0.010 o. 010 mg/1 DBC 03/16/2004 1922
BENZOIC ACID < 0.050 0. 050 mg/1 DBC 03/16/2004 1922
BENZYL ALCOHOL < 0. 010 0 .010 mg/1 DBC 03/16/2004 1922
I 81S(2-CHLOROETHOXY)METHANE < 0.010 0. 010 mg/1 DBC 03/16/2004 1922
815(2-CHLOROETHYL)ETHER 0 .010 0 .010 mg/1 DBC 03/16/2004 1922
BIS(2-CHLOROISOPROPYL)ETHER 0 .010 0. 010 mg/1 DBC 03/16/2004 1922 I Davis & Floyrl, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I i864J 229-4413 I fax [phone]
23
Di\YIS
FLtwD LABORATORY ANALYSIS REPORT
Client TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
Contact
SHELBY, NC 28152
Pem Carter
Client ID: PEW-04
Matrix : GW/Chemw
Parameter
BIS (2-ETHYLHEXYL) PHTHALATE
BUTYL BENZYL PHTHALATE
CHRYSENE
DI-.N-BUTYL PHTHALATE
D1-N-OCTYL PHTHALATE
DIBENZ(A,H)ANTHRACENE
DIBENZOFURAN
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
FLUORANTHENE
FLUORENE
HEXACHLOROBENZENE
HEXACHLOROBUTADIENE
-HEXACHLOROCYCLOPENTADIENE
HEXACHLOROETHANE
INDENO{l,2,3-CD}PYRENE
ISOPHORONE
N-NITROSODI-N-PROPYLAMINE
N-NITROSOOIPHENYLAMINE
NAPHTHALENE
NITROBENZENE
PENTACHLOROPHENOL
PHENANTHRENE
PHENOL
PYRENE
SW846 8270C DOWTHERM
1, 1' -Bl PHENYL
BIPHENYL ETHER
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
Result
0.010
0. 010
0.010
0.010
0.010
0. 010
·O .010
0.010
0.010
0. 010
0. 010
0 .010
0 .010
o. 010
0 .010
0.010
0 .010
0 . 010
0. 010
0 .010
o. 010
0 . 025
0. 010
0.010
0.010
0.010
0. 029
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0010
0.0050
0.0050
Qual
NC Certification Number: 25
Project Nul;Jl?.e_i;: 61621. 01
Report Date
Page 24 of 75
March 24, 2004
Report ID: AB23157
Sample ID L04030402-04
Date Collected: 03/03/2004 0825
Date Received 03/03/2004
RDL Units Analyst Date
0. 010 mg/1 DBC 03/16/2004
o. 010 mg/1 DBC 03/16/2004
0 .010 mg/1 DSC 03/16/2004
0 .010 mg/1 DSC 03/16/2004
0 .010 mg/1 DBC 03/16/2004
0 .010 mg/1 DBC 03/16/2004
0 .010 mg/1 DBC 03/16/2004
0 .010 mg/1 DBC 03/16/2004
0. 010 mg/1 DBC 03/16/2004
0. 010 mg/1 DBC 03/16/2004
0. 010 mg/1 DSC 03/16/2004
0 .010 mg/1 DBC 03/16/2004
0 .010 mg/1 DBC 03/16/2004
0 .010 mg/1 DBC 03/16/2004
o. 010 mg/1 DBC 03/16/2004
0. 010 mg/1 DBC 03/16/2004
o. 010 mg/1 DBC 03/16/2004
0 . 010 mg/1 DBC 03/16/2004
0. 010 mg/1 DSC 03/16/2004
0.010 mg/1 DBC 03/16/2004
0. 010 mg/1 DBC 03/16/2004
0.025 mg/1 DBC 03/16/2004
0.010 mg/1 DBC 03/16/2004
0.010 mg/1 DBC 03/16/2004
0. 010 mg/1 DSC 03/16/2004
0.010 mg/1 DBC 03/16/2004
0.010 mg/1 DBC 03/16/2004
0.0010 mg/1 PAP 03/08/2004
0.0010 mg/1 PAP 03/08/2004
0. 0010 mg/1 PAP 03/08/2004
0 .0010 mg/1 PAP 03/08/2004
0.0010 mg/1 PAP 03/08/2004
0.0010 mg/1 PAP 03/08/2004
0 . 0010 mg/1 PAP 03/08/2004
0 .0050 mg/1 PAP 03/08/2004
0.0050 mg/1 PAP 03/08/2004
Ti111e
1922
1922
1922
1922
1922
1922
1922
1922
1922
1922
1922
1922
1922
1922
1922
1922
1922
1922
1922
1922
1922
1922
1922
1922
1922
1922
1922
1322
1322
1322
1322
1322
1322
1322
1322
1322
4-METHYL-2-PENTANONE 0.0050 mg/1 PAP 03/08/2004 1322 < 0.0050
ACETONE 0.0050 mg/1 PAP 03/08/2004 1322 < 0 .0050
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I (864) 229-44 l 3 I Fax [phone]
24
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Dl\VIS
FLtJ\1D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
Client ID: PEW-04
Matrix
Parameter
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
Prep Procedure
Analytical Prep Procedures:
DOWTHERM
BNA SEMIVOLATILES
GW/ChemW
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
Method
SW846 3500B
SW846 3510C
Result Qual
0.0026
o. 0010
o. 0010
0. 0010
0. 0010
0 .0010
0 .0010
0. 0010
0 . 0010
0.0010
0.0080
0. 0010
o. 0010
0 .0010
0. 0010
0 .0010
0. 0010
0 .0010
0.0010
0.0010
0.0064
0.0010
0.0010
0.0020
Analyst
DSC
·osc
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 25 of 75
March 24, 2004
Report ID: AB23157
Sample ID L04030402-04
Date Collected: 03/03/2004 0825
Date Received
RDL units
0 .0010 mg/1
0 . 0010 mg/1
0.0010 mg/1
0 .0010 mg/1
0 . 0010 mg/1
0 .0010 mg/1
0. 0010 mg/1
o. 0010 mg/1
0 . 0010 mg/1
o. 0010 mg/1
0 . 0010 mg/1
0. 0010 mg/1
0.0010 mg/1
0.0010 mg/1
0.0010 mg/1
0 .0010 mg/1
0 .0010 mg/1
0 .0010 mg/1
0.0010 mg/1
0 .0010 mg/1
0 .0010 mg/1
0. 0010 mg/1
0.0010 mg/1
0.0020 mg/1
Prep Date
03/08/2004 0800
03/08/2004 0800
03/03/2004
Analyst
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
Date
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
03/08/2004
0]/08/2004
03/08/2004
03/08/2004
0]/08/2004
Time
1322
1322
1322
1322
1322
1322
1322
1322
1322
1322
1322
1322
1322
1322
1322
1322
1322
1322
1322
1322
1]22
1322
1322
1322
.Davis & Floyd, Inc. I PO Drawer 428 j Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I (864) 229A413 I Fax [phone]
25
Df\VIS
FLtJ\'D
Client
Contact
Client
Matrix
Parameter
Volatile Organics
SW845 8260B
1, 1, 1 -TRICHLOROETHANE
ID:
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE {TOTAL)
LABORATORY ANALYSIS REPORT
NC Cenijication Number: 25
TICONA,LLC Project Number: 61621.01
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date March 24, 2004
Pem Carter Page 26 of 75 Report 1D: AB23157
llli-48 Sample ID L04030402-0S
Date Collected: 03/03/2°004 1025
GW/ChemW Date Received 03/03/2004
Result Qual RDL Units Analyst Date Time
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1340
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1340
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1340
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1340
< 0 .. 0010 0.0010 mg/1 PAP 03/08/2004 1340
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1340
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1340
< 0.0050 0.0050 mg/I PAP 03/08/2004 1340
< 0.0050 0 .0050 mg/1 PAP 03/08/2004 1340
< 0. 0050 0 . 0050 mg/1 PAP 03/08/2004 134 0
< 0 .0050 0 .0050 mg/1 PAP 03/08/2004 134 0
< 0. 0010 0 .0010 mg/1 PAP · 03/08/2004 1340
< 0 .0010 0.0010 mg/1 PAP 03/08/2004 1340
< o. 0010 0.0010 mg/1 PAP 03/08/2004 1340
< 0. 0010 0.0010 mg/1 PAP 03/08/2004 1340
< o. 0010 0.0010 mg/1 PAP 03/08/2004 1340
< 0 . 0010 0. 0010 mg/1 PAP 03/08/2004 1340
< 0.0010 0. 0010 mg/1 PAP 03/08/2004 1340
< 0.0010 0. 0010 mg/1 PAP 03/08/2004 1340
< o. 0010 0 .0010 mg/1 PAP 03/08/2004 1340
< 0 .0010 0 .0010 mg/1 PAP 03/08/2004 1340
< 0. 0010 0 . 0010 mg/1 PAP 03/08/2004 1340
< o. 0010 0. 0010 mg/1 PAP 03/08/2004 1340
< 0 .0010 0 .0010 mg/1 PAP 03/08/2004 1340
< 0. 0010 o. 0010 mg/1 PAP 03/08/2004 134 0
< 0 .0010 0.0010 mg/1 PAP 03/08/2004 1340
< o. 0010 0 .0010 mg/1 PAP 03/08/2004 1340
< o. 0010 o. 0010 mg/1 PAP 03/08/2004 1340
< 0.0010 o. 0010 mg/1 PAP 03/08/2004 1340
< 0 .0010 0 .0010 mg/1 PAP 03/08/2004 1340
< 0 .0010 0 .0010 mg/1 PAP 03/08/2004 1340
0.15 0 .0010 mg/1 PAP 03/08/2004 1340
< 0.0010 0.0010 mg/I PAP 03/08/2004 1340
< o. 0 010 0.0010 mg/1 PAP 03/08/2004 1340
< 0. 0020 0.0020 mg/1 PAP 03/08/2004 1340
Davis & Floyd, Jnc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I {864) 229-4413 I Fax [phone]
26
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D~S I LABORATORY ANALYSIS REPORT FL D
I NC Cenijication Number: 25
I Client TICONA,LLC Project Number: 61621.01
2525 BLACKSBURG ROAD
HWY 198
I SHELBY, NC 28152 Report Date March 24, 2004
Contact Pem carter Page 27 of 75 Report ID: AE23157
Client ID: HH-77 Sample ID L04030402-06
I Date Collected: 03/03/2004 1205
Matrix : GW/ChemW Date Received 03/03/2004
Parameter Result Qual RDL Uuits Analyst Date Time I Volatile Organics
SW846 8260B
I 1,1,1-TRICHLOROETHANE < 0.0010 0 . 0010 mg/1 PAP 03/08/2004 1357
1,1,2,2-TETRACHLOROETHANE < 0. 0010 o. 0010 mg/1 PAP 03/08/2004 1357
1,1,2-TRICHLOROETHANE < 0.0010 o. 001,0 mg/1 PAP 03/08/2004 1357
1,1-DICHLOROETI-WJE < 0. 0010 0. 0010 mg/1 PAP 03/08/2004 1357
I 1,1-DICHLOROETHENE < 0.0010 0. 0010 mg/1 PAP 03/08/2004 1357
1,2-DICHLOROETHANE < 0.0010 0.0010 mg/1 PAP 03/08/2004 1357
1,2-DICHLOROPROPANE < 0.0010 0 . 0010 mg/1 PAP 03/08/2004 1357
2-BUTANONE 0.0061 0 .0050 mg/1 PAP 03/08/2004 1357 I 2-HEXANONE < 0. 0050 0.0050 mg/1 PAP 03/08/2004 1357
4-METHYL-2-PENTANONE < 0. 0050 0.0050 mg/1 PAP 03/08/2004 1357
ACETONE 0.0061 0.0050 mg/] PAP 03/08/2004 1357
I BENZENE < 0. 0010 0. 0010 mg/1 PAP 03/08/2004 1357
BROMOOICHLOROME~HANE < 0. 0010 0.0010 mg/1 PAP 03/08/2004 1357
BROMOFORM < 0. 0010 0 .0010 mg/1 PAP 03/08/2004 1357
BROMOMETHANE < 0. 0010 0. 0010 mg/1 PAP 03/08/2004 1357
I CARBON DISULFIDE < o. 0010 0.0010 mg/1 PAP 03/08/2004 1357
CARBON TETRACHLORIDE < 0. 0010 0 . 0010 mg/1 PAP 03/08/2004 1357
CHLOROBENZENE < 0. 0010 0 .0010 mg/1 PAP 03/08/2004 13 57
CHLOROETHANE < 0.0010 0.0010 mg/1 PAP 03/08/2004 1357 I CHLOROFORM < 0.0010 0.0010 mg/1 PAP 03/08/2004 1357
CHLOROMETHANE < 0.0010 0 .0010 mg/1 PAP 03/08/2004 1357
CIS-1,2-DICHLOROETHENE 0.0033 0 .0010 mg/1 PAP 03/0B/2004 1357
I CIS-1,3-DICHLOROPROPENE < 0. 0010 o. 0010 mg/1 PAP 03/08/2004 1357
DIBROMOCHLOROMETHANE < 0 .0010 0.0010 mg/1 PAP 03/08/2004 1357
ETHYLBENZENE < 0. 0010 0 .0010 mg/1 PAP 03/08/2004 1357
METHYLENE CHLORIDE < 0.0010 0. 0010 mg/1 PAP 03/08/2004 1357
I STYRENE < 0 .0010 0.0010 mg/1 PAP 03/08/2004 1357
TETRACHLOROETHENE < 0 .0010 0 .0010 mg/1 PAP 03/08/2004 1357
TOLUENE < 0. 0010 o. 0010 mg/1 PAP 03/08/2004 1357
TRANS-1,2-0ICHLOROETHENE < 0. 0010 o. 0010 mg/1 PAP 03/08/2004 1357 I TRANS-1,3-DICHLOROPROPENE < 0 .0010 0 . 0010 mg/1 PAP 03/08/2004 1357
TRICHLOROETHENE 0.31 0 .0030 mg/1 PAP 03/08/2004 1543
VINYL ACETATE < 0. 0010 o. 0010 mg/1 PAP 03/0B/2004 1357
I VINYL CHLORIDE < o. 0010 0.0010 mg/1 PAP 03/08/2004 1357
XYLENE (TOTAL} < 0 . 0020 0.0020 mg/1 PAP 03/08/2004 1357
I
ravis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 l [phone] I Fax [phone]
27
D1\VIS
FLt1YD
Client
Contact
Client ID:
Matrix
ParaU1etor
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYI,-2-PENTA.NONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHAf:lE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
LABORATORY ANALYSIS REPORT
NC Certification Number: 25
TICONA,LLC Project Number: 61621.0l
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date March 24, 2004
Pem Carter Page 28 of 75 Report ID: AB23157
EE-58 Sample ID L04030402-07
Date Collected: 03/03/2004 1503
GW/Chemw Date Received 03/03/2004
Result Qual RDL Units Analyst Dato Time
< 0.0010 0 .0010 mg/1 PAP 03/08/2004 1415
< 0.0010 0 .0010 mg/1 PAP 03/08/2004 1415
< 0.0010 0. 00~0 mg/1 PAP 03/08/2004 1415
< 0.0010 0 .0010 mg/1 PAP 03/08/2004 1415
< 0.0010 0. 0010 mg/1 PAP 03/08/2004 1415
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1415
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1415
0.012 0.0050 mg/1 PAP 03/08/2004 1415
< 0.0050 0.0050 mg/1 PAP 03/08/2004 1415
< 0.0050 0.0050 mg/1 PAP 03/08/2004 1415
0.0053 0.0050 mg/1 PAP 03/08/2004 1415
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1415
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1415
< o. 0010 0. 0010 mg/1 PAP 03/08/2004 1415
< 0 .0010 0. 0010 mg/1 PAP 03/08/2004 1415
< 0 .0010 0. 0010 mg/1 PAP 03/08/2004 1415
< 0. 0010 0.0010 mg/1 PAP 03/08/2004 1415
< 0. 0010 0.0010 mg/1 PAP 03/08/2004 1415
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1415
< 0. 0010 0.0010 mg/1 PAP 03/08/2004 1415
< 0 .0010 0.0010 mg/1 PAP 03/08/2004 1415
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1415
' 0.0010 0 .0010 mg/1 PAP 03/08/200.4 1415
< 0.0010 0 .0010 mg/1 PAP 03/08/2004 1415
< 0 . 0010 0.0010 mg/1 PAP 03/08/2004 1415
< o. 0010 0. 0010 mg/1 PAP 03/08/2004 1415
< 0.0010 0. 0010 mg/1 PAP 03/08/2004 1415
< 0.0010 0. 0010 mg/1 PAP 03/08/2004 1415
< 0 .ooro 0.0010 mg/1 PAP 03/08/2004 1415
< 0 . 0010 0.0010 mg/1 PAP 03/08/2004 1415
< 0.0010 0 . 0010 mg/1 PAP 03/08/2004 1415
0.0010 0 .0010 mg/1 PAP 03/08/2004 1415
< 0 .0010 0. 0010 mg/1 PAP 03/08/2004 1415
< o. 0010 0.0010 mg/1 PAP 03/08/2004 1415
0 . 0020 0.0020 mg/1 PAP 03/08/2004 1415
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax (t\64) 229-7119
28
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D~S I LABORATORY ANALYSIS REPORT FL D
I NC Cenijication Number: 25
I Client TICONA,LLC Project Number: 61621.01
2525 BLACKSBURG ROAD
HWY 198
I SHELBY, NC 28152 Report Date March 24, 2004
Contact Pem Carter Page 29 of 75 Report ID: AB23157
Client ID: EB-01 Sample 1D L04030402-08
I Date Collected, 03/02/2004 1755
Matrix GW/ChemW Date Received 03/03/2004
I Parameter Result Oual RDL Units Analyst Date Time
Volatile Organics
SW846 8260B
I 1,1,1-TRICHLOROETHANE < 0. 0010 0 .0010 mg/1 PAP 03/08/2004 1432
1,1,2,2-TETRACHLOROETHANE < 0 . 0010 o. 0010 mg/1 PAP 03/08/2004 1432
1,1,2-TRICHLOROETHANE < 0 . 0010 0.0010 mg/1 PAP 03/08/2004 1432
1,1-DICHLOROETHANE < 0.0010 0 . 0010 mg/1 PAP 03/08/2004 1432
I 1,1-DICHLOROETHENE < O·. 0010 0 .0010 mg/1 PAP 03/08/2004 1432
1,2-DICHLOROETHANE < 0.0010 0 .0010 mg/1 PAP 03/08/2004 1432
1,2-DICHLOROPROPANE < 0 .0010 0 . 0010 mg/1 PAP 03/08/2004 1432
I 2-BUTANONE < 0. 0050 0 .0050 mg/1 PAP 03/08/2004 1432
2-HEXANONE < 0. 0050 o. 0050 mg/1 PAP 03/08/2004 1432
4-METHYL-2-PENTANONE < 0 . 0050 o. 0050 mg/1 PAP 03/08/2004 1432
ACETONE < 0 . 0050 0 . 0050 mg/1 PAP 03/08/2004 1432
I BENZENE < 0. 0010 0 .0010 mg/1 PAP 03/08/2004 1432
BROMOOICHLOROMETHANE < 0.0010 o. 0010 mg/1 PAP 03/08/2004 1432
BROMOFORM < 0 .0010 0 .0010 mg/1 PAP 03/08/2004 1432
BROMOMETHANE < 0. 0010 o. 0010 mg/1 PAP 03/08/2004 1432
I CARBON DISULFIDE < 0 .0010 0. 0010 mg/1 PAP 03/08/2004 1432
CARBON TETRACHLORIDE < o. 0010 0 .0010 mg/1 PAP 03/08/2004 1432
CHLOROBENZENE < 0 .0010 0.0010 mg/1 PAP 03/08/2004 1432
I CHLOROETHANE < 0.0010 0 . 0010 mg/1 PAP 03/08/2004 1432
CHLOROFORM < 0.0010 0 . 0010 mg/1 PAP 03/08/2004 1432
CHLO ROME THANE < 0.0010 0 .0010 mg/1 PAP 03/08/2004 1432
CIS-1,2-DICHLOROETHENE < 0 . 0010 0 .0010 mg/1 PAP 03/08/2004 1432
I CIS-1,3-DICHLOROPROPENE < o. 0010 0. 0010 mg/1 PAP 03/08/2004 1432
DIBROMOCHLOROMETHANE < 0. 0010 0 .0010 mg/1 PAP 03/08/2004 1432
ETHYLBENZENE ' 0 .0010 0.0010 mg/1 PAP 03/08/2004 1432
METHYLENE CHLORIDE < 0 . 0010 0 . 0010 mg/1 PAP 03/08/2004 1432
I STYRENE < 0 . 0010 o. 0010 mg/1 PAP 03/08/2004 1432
TETRACHLOROETHENE < 0.0010 0 .0010 mg/1 PAP 03/08/2004 1432
TOLUENE < 0.0010 0 . 0010 mg/1 PAP 03/08/2004 1432
I TRANS-1,2-DICHLOROETHENE < 0.0010 0 .0010 mg/1 PAP 03/0B/2004 1432
TRANS-1,3-DICHLOROPROPENE < 0.0010 0 . 0010 mg/1 PAP 03/08/2004 1432
TRICHLOROETHENE < 0.0010 0 .0010 mg/1 PAP 03/0B/2004 1432
VINYL ACETATE < o. 0010 0 .0010 mg/1 PAP 03/0B/2004 1432
I VINYL CHLORIDE < 0. 0010 o. 0010 mg/1 PAP 03/08/2004 1432
XYLENE (TOTAL) < 0 . 0020 0 . 0020 mg/1 PAP 03/08/2004 1432
I
.Davis & Floyd, Inc. j PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 j [phone] I Fax [phone]
29
DAYIS
FLOYD
Client
Contact
Client ID,
Matrix
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHAflE
1,1-DICHLOROETHANE
1, 1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHI..OROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
LABORATORY ANALYSIS REPORT
NC Certification Number: 25
TICONA,LLC Project Number: 61621. 01
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date March 24, 2004
Pem Carter Page JO of 75 Report ID: AB23157
TRIP BLANK Sample ID L04030402-09
Date Collected: 02/20/2004 0850
GW/ChemW Date Received 03/03/2004
Result Qual RDL Units Analyst Date Time
' 0.0010 0 .0010 mg/1 PAP 03/08/2004 1014
' 0.0010 0 .0010 mg/1 PAP 03/08/2004 1014
' o. 0010 0 . 0010 mg/1 PAP 03/0B/2004 1014
' 0. 0010 0.0010 mg/1 PAP 03/08/2004 1014
' o. 0010 0.0010 rng/1 PAP 03/08/2004 1014
' 0. 0010 0 .0010 mg/1 PAP 03/08/2004 1014
' 0 .0010 0 . 0010 mg/1 PAP 03/08/2004 1014
' 0 . 0050 0 . 0050 mg/1 PAP 03/08/2004 1014
' 0 . 0050 0 . 0050 mg/1 PAP 03/08/2004 1014
' 0. 0050 0.0050 mg/1 PAP 03/08/2004 1014
' 0. 0050 0.0050 mg/1 PAP 03/08/2004 1014
' 0.0010 0.0010 mg/1 PAP 03/08/2004 1014
' o. 0010 o. 0010 mg/1 PAP 03/08/2004 1014
' 0 . 0010 0 . 0010 mg/1 PAP 03/08/2004 1014
' 0 .0010 0.0010 mg/1 PAP 03/08/2004 1014
' 0.0010 0.0010 mg/1 PAP 03/08/2004 1014
' 0.0010 0.0010 mg/1 PAP 03/08/2004 1014
' 0.0010 0.0010 mg/1 PAP 03/08/2004 1014
' 0.0010 0.0010 mg/1 PAP 03/08/2004 1014
' 0.0010 0.0010 mg/1 PAP 03/08/2004 1014
' 0.0010 0 . 0010 mg/1 PAP 03/08/2004 1014
' 0.0010 0 .0010 mg/1 PAP 03/08/2004 1014
' 0.0010 0.0010 mg/1 PAP 03/08/2004 1014
' 0.0010 0. 0010 mg/1 PAP 03/08/2004 1014
' 0.0010 0.0010 mg/1 PAP 03/08/2004 1014
' 0.0010 0.0010 mg/1 PAP 03/08/2004 1014
' 0.0010 0.0010 mg/1 PAP 03/08/2004 1014
' 0.0010 0 . 0010 mg/1 PAP 03/08/2004 1014
' O.OO!U 0. 0010 mg/1 PAP 03/08/2004 1014
' 0. 0010 0 .0010 mg/1 PAP 03/08/2004 1014
' 0. 0010 0.0010 mg/1 PAP 03/08/2004 1014
' 0. 0010 0.0010 mg/1 PAP 03/08/2004 1014
' 0 .0010 0.0010 mg/1 PAP 03/08/2004 1014
' 0. 0010 0.0010 mg/1 PAP 03/08/2004 1014
' 0.0020 0. 002 0 mg/1 PAP 03/08/2004 1014
Davis & Floyd, Inc. / PO Drawer 428 I Greenwood, SC 29648 / 816 E. Durst Avenue I Greenwood, SC 29649 l [phone] I Fax [phone]
30
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D~S I FL D LABORATORY ANALYSIS REPORT
I NC Certification Number: 25
I Client TICONA,LLC Project Number: 61621. 01
2525 BLACKSBURG ROAD
HWY 198
I SHELBY, NC 28152 Report Date March 24, 2004
Contact Pem Carter Page 31 of 75 Report ID: AB23157
Client ID: AA-54 Sample ID L04030807-01
I Date Collected: 03/03/2004 1530
Matrix : GW/ChemW Date Received 03/05/2004
Para.meter Result Qual RDL Uni ta Analyst Date Time I Volatile Organics
SW846 8250B
I 1,1,1-TRICHLOROETHANE ' 0 . 0010 0.0010 mg/1 PAP 03/08/2004 1640
1,1,2,2-TETRACHLOROETHANE ' 0. 0010 0.0010 mg/1 PAP 03/08/2004 1640
1,1,2-TRICHLOROETHANE ' 0 .0010 0 .0010 mg/1 PAP 03/08/2004 1640
1,1-DICHLOROETHANE ' 0. 0010 0. 0010 mg/1 PAP 03/08/2004 1640
I 1,1-DICHLOROETHENE ' o. 0010 0 .0010 mg/1 PAP 03/0B/2004 1640
1,2-DICHLOROETHANE ' 0 .0010 0 .0010 mg/1 PAP 03/08/2004 1640
1,2-0ICHLOROPROPANE ' 0 .0010 0.0010 ·mg/1 PAP 03/08/2004 1640
I 2-BUTANONE ' 0 .0050 0.0050 mg/1 PAP 03/08/2004 1640
2-HEXANONE ' o. 0050 0.0050 mg/1 PAP 03/08/2004 1640
4-METHYL-2 PENTANONE ' 0.0050 0.0050 mg/1 PAP 03/08/2004 1640
ACETONE ' o. 0050 0.0050 mg/] PAP 03/08/2004 164 0
I BENZENE ' o. 0010 0.0010 mg/1 PAP 03/08/2004 1640
BROMOOICHLOROMETHANE 0 . 0010 0.0010 mg/1 PAP 03/08/2004 1640
BROMOFORM ' 0 .0010 0. 0010 mg/1 PAP 03/08/2004 1640
BROMOMETHANE ' 0. 0010 0 .0010 mg/1 PAP 03/08/2004 1640
I CARBON DISULFIDE ' 0.0010 0.0010 mg/1 PAP 03/08/2004 1640
CARBON TETRACHLORIDE ' 0.0010 0 .0010 mg/1 PAP 03/08/2004 1640
CHLOROBENZENE ' o. 0010 0. 0010 mg/1 PAP 03/08/2004 1640
CHLOROETHANE ' o. 0010 0 .0010 mg/1 PAP 03/08/2004 1640 I CHLOROFORM ' 0. 0010 0 . 0010 mg/1 PAP 03/08/2004 1640
CHLOROMETHANE ' o. 0010 o. 0010 mg/1 PAP 03/08/2004 1640
CIS-1,2-DICHLOROETHENE ' 0.0010 0 .0010 mg/1 PAP 03/08/2004 1640
I CIS-1,3-0ICHLOROPROPENE ' 0 . 0010 0 .0010 mg/1 PAP 03/08/2004 1640
DIBROMOCHLOROMETHANE ' 0 .0010 o. 0010 mg/1 PAP 03/08/2004 1640
ETHYLBENZENE ' 0.0010 0. 0010 mg/1 PAP 03/08/2004 1640
METHYLENE CHLORIDE ' 0.0010 0.0010 mg/1 PAP 03/08/2004 1640
I STYRENE ' 0 . 0010 o . 0010 mg/1 PAP 03/08/2004 1?40
TETRACHLOROETHENE ' 0. 0010 0. 0010 mg/1 PAP 03/08/2004 1640
TOLUENE ' 0.0010 0 .0010 mg/1 PAP 03/08/2004 1640
I TRANS-1,2-DICHLOROETHENE 0.0010 0. 0010 mg/1 PAP 03/08/2004 1640
TRANS-1,3-DICHLOROPROPENE ' 0. 0010 0 .0010 mg/1 PAP 03/08/2004 1640
TRICHLOROETHENE ' 0 . 0010 o . 0010 mg/1 PAP 03/08/2004 1640
VINYL ACETATE ' o. 0010 0 .0010 mg/1 PAP 03/08/2004 1640
I VINYL CHLORIDE ' o. 0010 0. 0010 mg/1 PAP 03/08/2004 1640
XYLENE (TOTAL) ' 0 .0020 0 . 0020 mg/1 PAP 03/08/2004 1640
I
ravis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
31
DAYIS
FLtJ\7D
Client
Contact
Client ID:
Matrix
Para.meter
Volatile Organics
SW846 82608
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1, 1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
LABORATORY ANALYSIS REPORT
NC Cenificarion Number: 25
TICONA,LLC Project Number: 61621.01
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date March 24, 2004
Pem Carter Page 32 of 75 Report ID: AE23157
P-58 Sample ID L04030807-02
Date Collected: 03/03/2004 1710
GW/ChemW Date Received 03/05/2004
Result Qual RDL Units Analyst Date Time
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1732
< 0. 0010 0.0010 mg/1 PAP 03/08/2004 1732
< 0 .0010 0. 001:0 mg/1 PAP 03/08/2004 1732
< o. 0010 o. 0010 mg/1 PAP 03/08/2004 1732
< 0. 0010 o. 0010 mg/1 PAP 03/08/2004 1732
< 0 . 0010 0 . 0010 mg/1 PAP 03/08/2004 1732
< o. 0010 0. 0010 mg/1 PAP 03/08/2004 1732
0.0069 0. 0050 mg/1 PAP 03/08/2004 1732
< 0 .0050 0.0050 mg/1 PAP 03/0B/2004 1732
< o. 0050 0.0050 mg/1 PAP 03/08/2004 1732
< 0 . 0050 0.0050 mg/1 PAP 03/08/2004 1732
< 0. 0010 0.0010 mg/1 PAP 03/08/2004 1732
< o. 0010 0.0010 mg/1 PAP 03/08/2004 1732
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1732
< 0.0010 0. 0010 mg/1 PAP 03/08/2004 1732
< o. 0010 o. 0010 mg/1 PAP 03/08/2004 1732
< o. 0010 0. 0010 mg/1 PAP 03/08/2004 1732
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1732
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1732
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1732
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1732
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1732
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1732
o. 0010 0.0010 mg/1 PAP 03/0B/2004 1732
< o. 0010 0.0010 mg/1 PAP 03/08/2004 1732
< 0 .0010 0.0010 mg/1 PAP 03/08/2004 1732
< 0. 0010 0.0010 mg/1 PAP 03/08/2004 1732
< 0 .0010 0.0010 mg/1 PAP 03/08/2004 1732
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1732
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1732
< 0 .0010 0.0010 mg/1 PAP 03/08/2004 1732
< 0 .0010 0.0010 mg/1 PAP 03/08/2004 1732
< o. 0010 0.0010 mg/1 PAP 03/08/2004 1732
< 0 .0010 0.0010 mg/1 PAP 03/08/2004 1732
< 0. 002 0 0.0020 mg/1 PAP 03/08/2004 1732
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 l Bl 6 E. Durst Avenue J Greenwood, SC 29649 I [phone] I Fax [phone]
32
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I D~S FL D LABORATORY ANALYSIS REPORT
I NC Certification Number: 25
I Client TICONA,LLC Project Number, 61621. 01
2525 BLACKSBURG ROAD
HWY 198
I SHELBY, NC 28152 Report Date March 24, 2004
Contact Pem Carter Page 33 of 75 Report ID: AB23157
I Client ID: C-0 Sample ID L04030807-03
Date Collected: 03/04/2004 1105
Matrix GW/ChemW Date Received 03/05/2004
I Parameter Result Qual RDL units Analyst Date Time
Volatile Organics
SW846 8260B
I 1,1,1-TRICHLOROETHANE < 0.0010 0 .0010 mg/1 PAP 03/08/2004 1749
1,1,2,2-TETRACHLOROETHANE < 0. 0010 0. 0010 mg/1 PAP 03/08/2004 1749
1,1,2-TRICHLOROETHANE < 0. 0010 0.0010 mg/1 PAP 03/08/2004 1749
I 1,1-DICHLOROETHANE < 0.0010 0.0010 mg/1 PAP 03/08/2004 1749
1,1-DICHLOROETHENE < 0.0010 0.0010 mg/1 PAP 03/08/2004 1749
1,2-DICHLOROETHANE < 0.0010 0 .0010 mg/1 PAP 03/08/2004 1749
1,2-DICHLOROPROPANE < 0.0010 0 .0010 mg/1 PAP 03/08/2004 1749
I 2-BUTANONE < 0.0050 0.0050 mg/1 PAP 03/08/2004 1749
2-HEXANONE < 0 .0050 0. 0050 mg/1 PAP 03/08/2004 1749
4-METHYL 2-PENTANONE < 0 .0050 0.0050 mg/1 PAP 03/08/2004 1749
ACETONE < 0 .0050 0.0050 mg/1 PAP 03/08/2004 1749 I BENZENE < 0.0010 0.0010 mg/1 PAP 03/08/2004 1749
BROMODICHLOROMETHANE < 0. 0010 o. 0010 mg/1 PAP 03/08/2004 1749
BROMOFORM < 0. 0010 0 .0010 mg/1 PAP 03/08/2004 1749
BROMOMETHANE < 0 . 0010 0 .0010 mg/1 PAP 03/08/2004 1749 I CARBON DISULFIDE < 0 . 0010 0. 0010 mg/1 PAP 03/08/2004 1749
CARBON TETRACHLORIDE < 0 .0010 o. 0010 mg/1 PAP 03/08/2004 1749
CHLOROBENZENE < 0 . 0010 0 . 0010 mg/1 PAP 03/08/2004 1749
I CHLOROETHANE < 0 .0010 0 . 0010 mg/1 PAP 03/08/2004 1749
CHLOROFORM < 0. 0010 0.0010 mg/1 PAP 03/08/2004 1749
CHLOROMETHANE < 0 . 0010 0. 0010 mg/1 PAP 03/08/2004 1749
CIS-1,2-DICHLOROETHENE < 0 .0010 o. 0010 mg/1 PAP 03/08/2004 1749 I CIS-1,3-DICHLOROPROPENE < 0.0010 0 .0010 mg/1 PAP 03/08/2004 1749
DIBROMOCHLOROMETHANE < 0 . 0010 o . 0010 mg/1 PAP 03/08/2004 1749
ETHYLBENZENE < 0 . 0010 0. 0010 mg/1 PAP 03/08/2004 1749
I METHYLENE CHLORIDE < 0. 0010 0 .0010 mg/1 PAP 03/08/2004 1749
STYRENE < 0.0010 0.0010 mg/1 PAP 03/08/2004 1749
TETRACHLOROETHENE < 0.0010 0 .0010 mg/1 PAP 03/08/2004 1749
TOLUENE < 0. 0010 0 .0010 mg/1 PAP 03/08/2004 1749
I TRANS-1,2-DICHLOROETHENE < 0. 0010 o. 0010 mg/1 PAP 03/08/2004 1749
TRANS-1,3-DICHLOROPROPENE < 0. 0010 0 .0010 mg/1 PAP 03/08/2004 1749
TRICHLOROETHENE < 0.0010 0.0010 mg/1 PAP 03/08/2004 1749
VINYL ACETATE < 0. 0010 0. 0010 mg/1 PAP 03/08/2004 1749
I VINYL CHLORIDE < 0. 0010 0. 0010 mg/1 PAP 03/08/2004 1749
XYLENE (TOTAL) < 0. 0020 0 . 0020 mg/1 PAP 03/08/2004 1749
I
ravis & Floyd, Inc. j PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
33;
Dl\VIS
FLtiYD
Client
Contact
Client ID:
Matrix
Parameter
Volatile Organics
SW846 8260B
1,1,l-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1, 1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROf:THANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-0ICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL}
LABORATORY ANALYSIS REPORT
NC Cenijication Number: 25
TICONA,LLC Projec~. ~u:"?~.r.=, .!5~6?,1:0~.
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date March 24, 2004
Pem Carter Page 34 of 75 Report ID: AB23157
PP-34 Sample ID L04030807-04
Date Collected: 03/04/2004 1303
GW/Chemw Date Received 03/05/2004
Result Qual RDL Units Analyst Date Tiino
< 0.0010 0 .0010 mg/1 PAP 03/08/2004 1807
< 0.0010 0. 0010 mg/1 PAP 03/08/2004 1807
< 0.0010 0 . 001'0 mg/1 PAP 03/08/2004 1807
< 0.0010 0. 0010 mg/1 PAP 03/08/2004 1807
< 0.0010 0 .0010 mg/1 PAP 03/08/2004 1807
< 0.0010 0 . 0010 mg/1 PAP 03/08/2004 1807
< 0.0010 0. 0010 mg/1 PAP 03/08/2004 1807
0.0079 0 .0050 mg/1 PAP 03/08/2004 1807
< 0.0050 0.0050 mg/1 PAP 03/08/2004 1807
< 0.0050 0.0050 mg/1 PAP 03/08/2004 1807
< 0.0050 0.0050 mg/1 PAP 03/08/2004 1807
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1807
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1807
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1807
< 0. 0010 0.0010 mg/1 PAP 03/08/2004 1807
< 0. 0010 o. 0010 mg/1 PAP 03/08/2004 1807
< 0. 0010 0 . 0010 mg/1 PAP 03/08/2004 1807
< 0 .0010 0.0010 mg/1 PAP 03/08/2004 1807
< 0. 0010 o. 0010 mg/1 PAP 03/08/2004 1807
< 0.0010 0. 0010 mg/1 PAP 0)/08/2004 1807
< 0.0010 0. 0010 mg/1 PAP 0)/08/2004 1807
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1807
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1807
< 0 .0010 0.0010 mg/1 PAP 03/08/2004 1807
< 0. 0010 0.0010 mg/1 PAP 03/08/2004 1807
< 0 .0010 0.0010 mg/1 PAP 03/08/2004 1807
< 0. 0010 0.0010 mg/1 PAP 03/08/2004 1807
< 0. 0010 0.0010 mg/1 PAP 03/08/2004 1807
< 0 . 0010 0.0010 mg/1 PAP 03/08/2004 1807
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1807
< 0.0010 0 . 0010 mg/1 PAP 03/08/2004 1807
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1807
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1807
< 0.0010 0. 0010 mg/1 PAP 03/08/2004 1807
< 0.0020 0 . 0020 mg/1 PAP 03/08/2004 1807
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] ! Fax [phone]
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DAYIS
FLiWD
Client
Contact
Client ID:
Matrix
Para.111eter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BRO MO METHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-0ICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
LABORATORY ANALYSIS REPORT
NC Certification Number: 25
TICONA,LLC Project Number: 61621.01
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date March 24, 2004
Pem Carter Page 35 of 75 Report ID: AB23157
FF-62 Sample ID L04030807-05
Date Collected: 03/04/2004 1435
GW/ChemW Date Received 03/05/2004
Result Qual RDL units Analyst Date Time
< 0. 0010 0. 0010 mg/1 PAP 03/08/2004 1824
< 0.0010 0. 0010 mg/1 PAP 03/08/2004 1824
< 0 .0010 0. 0010 mg/1 PAP 03/08/2004 1824
< 0 .0010 0 .0010 mg/1 PAP 03/08/2004 1824
< 0 .0010 0.0010 mg/1 PAP 03/08/2004 1824
< 0.0010 0. 0010 mg/1 PAP 03/08/2004 1824
< 0.0010 0. 0010 mg/1 PAP 03/08/2004 1824
0.0069 0.0050 mg/1 PAP 03/08/2004 1824
< 0.0050 o. 0050 mg/1 PAP 03/08/2004 1824
< 0.0050 0.0050 mg/1 PAP 03/08/2004 1824
< 0.0050 0.0050 mg/1 PAP 03/08/2004 1824
< 0.0010 0. 0010 mg/1 PAP 03/08/2004 1824
< 0 .0010 0.0010 mg/1 PAP 03/08/2004 1824
< 0 .0010 0. 0010 mg/1 PAP 03/08/2004 1824
< 0 .0010 0. 0010 mg/1 PAP 03/08/2004 1824
< 0. 0010 0 .0010 mg/1 PAP 03/08/2004 1824
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1824
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1824
< 0.0010 o. 0010 mg/1 PAP 03/08/2004 1824
< o. 0010 0.0010 mg/1 PAP 03/08/2004 1824
< 0 .0010 o. 0010 mg/1 PAP 03/08/2004 1824
< 0 .0010 0. 0010 mg/1 PAP 03/08/2004 1824
< o. 0010 0. 0010 mg/1 PAP 03/08/2004 1824
< 0. 0010 0.0010 mg/1 PAP 03/08/2004 1824
< 0 .0010 0.0010 mg/1 PAP 03/08/2004 1824
< o. 0010 0. 0010 mg/1 PAP 03/08/2004 1824
< o. 0010 0. 0010 mg/1 PAP 03/08/2004 1824
< o. 0010 0 .0010 mg/1 PAP 03/08/2004 1824
< 0 .ooi"o 0.0010 mg/1 PAP 03/08/2004 1824
0 .0010 0.0010 mg/1 PAP 03/08/2004 1824
< o. 0010 0.0010 mg/1 PAP 03/08/2004 1824
< 0. 0010 0.0010 mg/1 PAP OJ/08/2004 1824
< 0 .0010 0.0010 mg/1 PAP 03/08/2004 1824
< 0 .0010 0. 0010 mg/1 PAP 03/08/2004 1824
< 0 .0020 0. 0020 mg/1 PAP 03/08/2004 1824
I Davis & Floyd, Inc. I P0Drawer428 I Greenwood,5(29648 / 816E.DurstAvenue I Greenwood,5(29649 I (8641229-4413 I Fax(864i229-7119
35
DAYIS
FLtJ\1D
Client
Contact
Client ID:
Matrix
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACIILORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
QILOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIDROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
LABORATORY ANALYSIS REPORT
NC Certification Number: 25
TICONA,LLC Project Number: 61621.01
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date March 24, 2004
Pem carter Page 36 of 75 Report ID: AB23157
TRIP BLANK Sample ID L04030807-06
Date Collected: 03/20/2004 0850
GW/Chemw Date Received 03/05/2004
Result Qual RDL Units Analyst Date Time
< 0 .0010 0.0010 mg/1 PAP 03/08/2004 1622
< 0. 0010 0.0010 mg/1 PAP 03/08/2004 1622
< 0 .0010 0 .ooi"o mg/1 PAP 03/08/2004 1622
< 0. 0010 0 .0010 mg/1 PAP 03/08/2004 1622
< 0 . 0010 0 . 0010 mg/1 PAP 03/08/2004 1622
< 0 .0010 0 .0010 mg/1 PAP 03/08/2004 1622
< 0 . 0010 0. 0010 mg/1 PAP 03/08/2004 1622
0.0051 0 .0050 mg/1 PAP 03/08/2004 1622
< 0.0050 0. 0050 mg/1 PAP 03/08/2004 1622
< 0.0050 0.0050 mg/1 PAP 03/08/2004 1622
< 0.0050 0 .0050 mg/1 PAP 03/08/2004 1622
< 0 .0010 0. 0010 mg/1 PAP 03/08/2004 1622
< 0. 0010 0 .0010 mg/1 PAP 03/08/2004 1622
< 0 .0010 0.0010 mg/1 PAP 03/08/2004 1622
< 0 .0010 0.0010 mg/1 PAP 03/08/2004 1622
< 0 .0010 0.0010 mg/1 PAP 03/08/2004 1622
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1622
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1622
< 0 . 0010 o. 0010 mg/1 PAP 03/08/2004 1622
< 0 .0010 0. 0010 mg/1 PAP 03/08/2004 1622
< 0. 0010 0 .0010 mg/1 PAP 03/08/2004 1622
< 0. 0010 o. 0010 mg/1 PAP 03/08/2004 1622
< 0 .0010 0. 0010 mg/1 PAP 03/08/2004 1622
< 0 .0010 0 .0010 mg/1 PAP 03/08/2004 1622
< 0. 0010 0. 0010 mg/1 PAP 03/08/2004 1622
< 0.0010 0 . 0010 mg/1 PAP 03/08/2004 1622
< 0. 0010 0. 0010 mg/1 PAP 03/08/2004 162 2
< 0 .0010 0.0010 mg/1 PAP 03/08/2004 1622
< o. 0010 0.0010 mg/1 PAP 03/08/2004 162 2
< o. 0010 0 .0010 mg/1 PAP 03/08/2004 1622
< 0 .0010 0.0010 mg/1 PAP 03/08/2004 1622
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1622
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1622
< 0.0010 0.0010 mg/1 PAP 03/08/2004 1622
< 0.0020 0.0020 mg/1 PAP 03/08/2004 1622
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
36
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Di\YIS
FL6YD
Client
contact
Client
Matrix
Para.meter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
ID:
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1, 1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DlCHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CH LOR IDE
XYLENE (TOTAL)
Wet Chemistry
SW846 9060
ORGANIC CARBON, TOTAL
LABORATORY ANALYSIS REPORT
NC Cenification Number: 25
TICONA,LLC Project Number: 61621.01
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date March 24, 2004
Pem Carter Page 37 of 75 Report ID: AB23157
K-28 Sample ID L04031504-0l
Date Collected: 03/08/2004 1705
GW/ChemW Date Received 03/12/2004
Result Qual RDL Units Analyst Date Time
' 0.0010 0 0010 mg/1 JRN 0)/18/2004 1859
' 0.0010 0 0010 mg/1 JRN 03/18/2004 1859
' 0.0010 0. oo;o mg/1 JRN 03/18/2004 1859
' 0 0010 o. 0010 mg/1 JRN 03/18/2004 1859
' 0 0010 0 0010 mg/1 JRN 03/18/2004 1859
' 0 . 0010 0.0010 mg/1 JRN 03/18/2004 1859
' 0 .0010 0.0010 mg/1 JRN 03/18/2004 1859
0.10 0.0050 mg/1 JRN 03/18/2004 1859
' 0 . 0050 0.0050 mg/1 JRN 03/18/2004 1859
' 0. 0050 0.0050 mg/1 JRN 03/18/2004 1859
0.12 0.0050 mg/1 JRN 03/18/2004 1859
0.011 0.0010 mg/1 JRN 03/18/2004 1859
' 0.0010 0.0010 mg/1 JRN 03/18/2004 1859
' 0.0010 0.0010 mg/1 JRN 03/18/2004 1859
' 0.0010 0.0010 mg/1 JRN 03/18/2004 1859
' 0.0010 0.0010 mg/1 JRN 03/18/2004 1859
' 0.0010 0. 0010 mg/1 JRN 03/18/2004 1859
' 0.0010 0.0010 mg/1 JRN 03/18/2004 1859
' 0.0010 0.0010 mg/1 JRN 03/18/2004 1859
' 0.0010· 0.0010 mg/1 JRN 03/18/2004 1859
' 0. 0010 0 0010 mg/1 JRN 03/18/2004 1859
' 0 0010 0. 0010 mg/1 JRN 03/18/2004 1859
' o. 0010 0 0010 mg/1 JRN 03/18/2004 1859
' o. 0010 0 0010 mg/1 JRN 03/18/2004 1859
' 0. 0010 0.0010 mg/1 JRN 03/18/2004 1859
' 0 0010 0.0010 mg/1 JRN 03/18/2004 1859
' 0.0010 0.0010 mg/1 JRN 03/18/2004 1859
' 0.0010 0 0010 mg/1 JRN 03/18/2004 1859
0.0022 0. 0010 mg/1 JRN 03/18/2004 1859
' 0.0010 0.0010 mg/1 JRN 03/18/2004 1859
' 0.0010 0.0010 mg/1 JRN 03/18/2004 1859
' 0 .0010 0.0010 mg/1 JRN 03/18/2004 1859
' 0.0010 0.0010 mg/1 JRN 03/18/2004 1859
' 0 0010 0.0010 mg/1 JRN 03/18/2004 1859
' o. 0020 0.0020 mg/1 JRN 03/18/2004 1859
,o, 5.0 mg/1 CBN 03/19/2004 1109
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
37
Df\VIS
FLlWD
Client
Contact
Client ID:
'Matrix
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,~.2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1, 3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL}
LABORATORY ANALYSIS REPORT
NC Certification Number: 25
TICONA,LLC Project Number: 61621. 01
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date March 24, 2004
Pem Carter Page 38 of 75 Report ID: AB23157
CC-33 Sample ID L04031504-02
Date Collected: 03/08/2004 1710
GW/ChemW Date Received 03/12/2004
Result Qual RDL Units Analyst Date Ti111e
' 0.0010 0 . 0010 mg/1 JRN 03/18/2004 1917
' 0. 0010 0 . 0010 mg/1 JRN 03/18/2004 1917
' 0. 0010 0.0010 mg/1 JRN 03/18/2004 1917
' 0.0010 0.0010 mg/1 JRN 03/18/2004 1917
' 0.0010 0.0010 mg/1 JRN 03/18/2004 1917
' 0.0010 0.0010 mg/1 JRN 03/18/2004 191 7
' 0.0010 0.0010 mg/1 JRN 03/18/2004 1917
0.0086 0.0050 mg/1 JRN 03/1B/2004 1917
' 0.0050 0.0050 mg/1 JRN 03/18/2004 1917
' 0.0050 0.0050 mg/1 JRN 03/18/2004 1917
0.018 0.0050 mg/1 JRN 03/18/2004 1917
0.0017 0.0010 mg/1 JRN 03/18/2004 1917
' 0. 0010 0.0010 mg/1 JRN 03/18/2004 1917
' 0 .0010 0.0010 mg/1 JRN 03/18/2004 1917
' 0 .0010 0 . 0010 mg/1 JRN 03/18/2004 1917
' 0. 0010 o. 0010 mg/1 JRN 03/18/2004 191 7
' 0. 0010 0. 0010 mg/1 JRN 03/18/2004 1917
' 0.0010 0 . 0010 mg/1 JRN 03/18/2004 1917
' 0 .0010 0 .0010 mg/1 JRN 03/18/2004 1917
' o. 0010 0 .0010 mg/1 JRN 03/18/2004 1917
' 0 .0010 0 . 0010 mg/1 JRN 03/18/2004 1917
0.0021 0 . 0010 mg/1 JRN 03/18/2004 1917
' 0. 0010 0. 0010 mg/1 JRN 03/1B/2004 1917
' 0. 0010 0 . 0010 mg/1 JRN 03/18/2004 1917
' 0 .0010 0.0010 mg/1 JRN 03/18/2004 1917
' 0.0010 0.0010 mg/1 JRN 03/18/2004 1917
' 0.0010 0.0010 mg/1 JRN 03/18/2004 1917
' 0.0010 0.0010 mg/1 JRN 03/18/2004 1917
< 0.0010 0 . 0010 mg/1 JRN 03/18/2004 1917
' 0.0010 0 . 0010 mg/1 JRN 03/18/2004 1917
' 0.0010 0 .0010 mg/1 JRN 03/18/2004 1917
0.0012 o. 0010 mg/1 JRN 03/18/2004 1917
' 0 .0010 0.0010 mg/1 JRN 03/18/2004 1917
' 0 .0010 0.0010 mg/1 JRN 03/18/2004 1917
' 0 . 0020 0.0020 mg/1 JRN 03/18/2004 1917
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816E. Durst Avenue I Greenwood, SC 29649 I [phone] I fax [phone]
38
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D1\VIS
FLtrYD
Client
Contact
Client
Matrix
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
ID:
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLO RO ETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE ~-TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
LABORATORY ANALYSIS REPORT
NC Certification Number: 25
TICONA,LLC Project Number: 61621.01
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date March 24, 2004
Pem Carter Page 39 of 75 Report ID: AB23157
GG-61 Sample ID L04031504-03
Date Collected: 03/08/2004 1410
GW/Chemw Date Received 03/12/2004
Rosult Qual RDL Units Analyst Date Time
< 0.0010 0. 0010 mg/1 JRN 03/18/2004 1934
< 0. 0010 0 .0010 mg/1 JRN 03/18/2004 1934
< 0.0010 0 001_ 0 mg/1 JRN 03/18/2004 1934
< 0.0010 0. 0010 mg/1 JRN 03/18/2004 1934
< 0.0010 0 .0010 mg/1 JRN 03/18/2004 1934
< 0.0010 0. 0010 mg/1 JRN 03/18/2004 1934
< 0.0010 0 0010 mg/1 JRN 03/18/2004 1934
0.0076 0. 0050 mg/1 JRN 03/18/2004 1934
' 0.0050 0. 0050 mg/1 JRN 03/18/2004 1934
< 0.0050 0 0050 mg/1 JRN 03/18/2004 1934
0.014 o. 0050 mg/1 JRN 03/18/2004 1934
' 0.0010 0 .0010 mg/1 JRN 03/18/2004 1934
< 0.0010 0 0010 mg/1 JRN 03/18/2004 1934
' 0. 0010 0 0010 mg/1 JRN 03/18/2004 1934
< 0 .0010 0.0010 mg/1 JRN 03/18/2004 1934
< o. 0010 0.0010 mg/1 JRN 03/18/2004 1934
' 0 0010 0.0010 mg/1 JRN 03/18/2004 1934
< 0. 0010 0.0010 mg/1 JRN 03/18/2004 1934
< 0. 0010 0.0010 mg/1 JRN 03/18/2004 1934
' 0. 0010 0.0010 mg/1 JRN 03/18/2004 1934
< o. 0010 0.0010 mg/1 JRN 03/18/2004 1934
' 0 .0010 0.0010 mg/1 JRN 03/18/2004 1934
' 0.0010 0.0010 mg/1 JRN 03/18/2004 1934
< o. 0010 0.0010 mg/1 JRN 03/18/2004 1934
< o. 0010 0.0010 mg/1 JRN 03/18/2004 1934
' 0. 0010 0. 0010 mg/1 JRN 03/18/2004 1934
< 0. 0010 0.0010 mg/1 JRN 03/18/2004 1934
< o. 0010 0.0010 mg/1 JRN 03/18/2004 1934
< 0 . 0010 0.0010 mg/1 JRN 03/18/2004 1934
o. 0010 0.0010 mg/1 JRN 03/18/2004 1934
< 0 0010 0.0010 mg/1 JRN 03/18/2004 1934
< 0 0010 0.0010 mg/1 JRN 03/18/2004 1934
' 0.0010 0 0010 mg/1 JRN 03/18/2004 1934
< 0. 0010 0 .0010 mg/1 JRN 03/18/2004 1934
' 0. 002 0 0. 0020 mg/1 JRN 03/18/2004 1934
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I {864) 229-4413 I Fax [phone]
39
Dl\VIS
FLtiYD
Client
Contact
Client ID:
Matrix
Parameter
Volatile Organics
SWB46 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1, 2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,)·DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-l,3·DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
LABORATORY ANALYSIS REPORT
NC Certification Number: 25
TICONA,LLC Project Number: 61621.01
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date March 24, 2004
Pem carter Page 40 of 75 Report ID: AB23157
T-35 Sample ID L04031504-04
Date Collected: 03/09/2004 1535
GW/Chemw Date Received 03/12/2004
Result Qual RDL Units Analyst Date Time
< 0. 0010 0 .0010 mg/1 JRN 03/18/2004 1952
< o. 0010 0 .0010 mg/1 JRN 03/18/2004 1952
< 0. 0010 o. 00~0 mg/1 JRN 03/18/2004 1952
< 0.0010 o. 0010 mg/1 JRN 03/18/2004 1952
< 0.0010 0. 0010 mg/1 JRN 03/18/2004 1952
< 0.0010 0 .0010 mg/1 JRN 03/18/2004 1952
< 0.0010 0. 0010 mg/1 JRN 03/18/2004 1952
0.010 o. 0050 mg/1 JRN 03/18/2004 1952
< 0.0050 0.0050 mg/1 JRN 03/18/2004 1952
< 0.0050 0.0050 mg/1 JRN 03/18/2004 1952
< 0 .0050 0.0050 mg/1 JRN 03/18/2004 1952
< 0 .0010 0.0010 mg/1 JRN 03/18/2004 1952
< 0.0010 0.0010 mg/1 JRN 03/18/2004 1952
< 0.0010 o. 0010 mg/1 JRN 03/18/2004 1952
< 0 . 0010 0 . 0010 mg/1 JRN 03/18/2004 1952
< o. 0010 0.0010 mg/1 JRN 03/18/2004 1952
< 0. 0010 0.0010 mg/1 JRN 03/18/2004 1952
< o. 0010 0.0010 mg/1 JRN 03/18/2004 1952
< 0.0010 0.0010 mg/1 JRN 03/18/2004 1952
< 0.0010 0. 0010 mg/1 JRN. 03/18/2004 1952
< 0.0010 0. 0010 mg/1 JRN 03/18/2004 1952
0.0011 0 .0010 mg/1 JRN 03/18/2004 1952
< 0 .0010 0 .0010 mg/1 JRN 03/18/2004 1952
< 0 .0010 0. 0010 mg/1 JRN 03/18/2004 1952
< 0 . 0010 0.0010 mg/1 JRN 03/18/2004 1952
< 0.0010 0.0010 mg/1 JRN 03/18/2004 1952
0.0010 0.0010 mg/1 JRN 03/18/2004 1952
0.0015 0.0010 mg/1 JRN 03/18/2004 1952
< o. ooro 0.0010 mg/1 JRN 03/18/2004 1952
< 0.0010 o. 0010 mg/1 JRN 03/18/200-. 1952
< 0.0010 0. 0010 mg/1 JRN 03/18/2004 1952
0.00ll 0.0010 mg/1 JRN 03/18/2004 1952
< 0 .0010 0.0010 mg/1 JRN 03/18/2004 1952
< 0. 0010 0.0010 mg/1 JRN 03/18/2004 1952
0 .0020 0.0020 mg/1 JRN 03/18/2004 1952
Davis & Floyd, Inc. I PO Dcawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I fax [phone]
40
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Di\VIS
FL(j\1D
Client
Contact
Client
Matrix
Parameter
Volatile Organics
SWB4r 82608
1,1,1-TRICHLOROETHANE
ID:
1, 1., 2, 2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-0ICHLOROETHENE
CIS-1,3-0ICHLOROPROPENE
OIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-0ICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
Wet Chemistry
SW846 9060
ORGANIC CARBON, TOTAL
LABORATORY ANALYSIS REPORT
NC Cenification Number: 25
TICONA,LLC Project Number: 61621.01
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date March 24, 2004
Pem Carter Page 41 of 75 Report ID: AB23157
V-23 Sample ID L04031504-05
Date Collected: 03/09/2004 1705
GW/ChemW Date Received 03/12/2004
Result Qual RDL Units Analyst Date Time
' 0 0010 o. 0010 mg/1 JRN 03/18/2004 2009
' o. 0010 o. 0010 mg/1 JRN 03/18/2004 2009
' 0. 0010 o. 0010 mg/1 JRN 03/18/2004 2009
' 0.0010 0. 0010 mg/1 JRN 03/18/2004 2009
' 0 0010 0.0010 mg/1 JRN 03/18/2004 2009
' 0.0010 0.0010 mg/1 JRN 03/18/2004 2009
' 0 .0010 0.0010 mg/1 JRN 03/18/2004 2009
' 0.0050 0.0050 mg/1 JRN 03/18/2004 2009
' o. 0050 0 0050 mg/1 JRN 03/18/2004 2009
' 0 .0050 0.0050 mg/1 JRN 03/18/2004 2009
' 0 0050 0.0050 mg/1 JRN 03/18/2004 2009
0.022 0.0010 mg/1 JRN 03/18/2004 2009
' 0 0010 0.0010 mg/1 JRN 03/18/2004 2009
' 0.0010 0.0010 mg/1 JRN 03/18/2004 2009
' 0 0010 0.0010 mg/1 JRN 03/18/2004 2009
' 0.0010 0.0010 mg/1 JRN 03/18/2004 2009
' 0.0010 0.0010 mg/1 JRN 03/18/2004 2009
' 0 0010 0. 0010 mg/1 JRN 03/18/2004 2009
' 0 0010 o. 0010 mg/1 JRN 03/18/2004 2009
' o. 0010 0 0010 mg/1 JRN 03/18/2004 2009
' 0. 0010 0 .0010 rng/1 JRN 03/18/2004 2009
' 0 0010 0. 0010 mg/1 JRN 03/18/2004 2009
' 0 0010 0. 0010 mg/1 JRN 03/18/2004 2009
' 0 .0010 0 0010 rng/1 JRN 03/18/2004 2009
0.0037 0 .0010 mg/1 JRN 03/18/2004 2009
' 0 0010 0.0010 mg/1 JRN 03/18/2004 2009
' 0.0010 o. 0010 mg/1 JRN 03/18/2004 2009
' 0.0010 0.0010 mg/1 JRN 03/18/2004 2009
0.011 0.0010 rng/1 JRN 03/18/2004 2009
' 0 0010 0.0010 rng/1 JRN 03/18/2004 2009
' 0.0010 0.0010 rng/1 JRN 03/18/2004 2009
' 0.0010 0.0010 mg/1 JRN 03/18/2004 2009
' 0.0010 0.0010 mg/1 JRN 03/18/2004 2009
' 0.0010 0.0010 mg/1 JRN 03/18/2004 2009
O.OH 0.0020 mg/1 JRN 03/18/2004 2009
10500 400 mg/1 CBN 03/19/2004 1140
.Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 l 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
41,
DL\VIS
FLtwD LABORATORY ANALYSIS REPORT
NC Cenification Number: 25
Client TICONA,LLC Project Number: 61621.01
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date March 24, 2004
Contact Pem Carter Page 42 of 75 Report ID: AB2315i
Client ID: TRIP BLANK Sample ID L04031504-06
Date Collected: 02/20/2004 0850
Matrix : GW/ChemW Date Received 03/12/2004
ParAI11eter Result Qual RDL units Analyst Date Time
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE < 0.0010 0. 0010 mg/1 JRN OJ/18/2004 1842
1,1,2,2-TETRACHLOROETHANE < 0 . 0010 0 . 0010 mg/1 JRN 03/18/2004 1842
1,1,2-TRICHLOROETHANE < 0. 0010 0. 001:_0 mg/1 JRN 03/18/2004 1842
1,1-DICHLOROETHANE < 0 .0010 0 .0010 mg/1 JRN 03/18/2004 1842
1,1-DICHLOROETHENE < 0 . 0010 0 .0010 mg/1 JRN 03/18/2004 1842
1,2-DICHLOROETHANE < 0 . 0010 0 . 0010 mg/1 JRN 03/18/2004 1842
1,2-DICHLOROPROPANE < 0.0010 0.0010 mg/1 JRN 03/18/2004 1842
2-BUTANONE ' 0.0050 0.0050 mg/1 JRN 03/18/2004 1842
2-HEXANONE < 0. 0050 0.0050 mg/1 JRN 03/18/2004 1842
4-METHYL-2-PENTANONE < 0 .0050 0.0050 mg/1 JRN 03/18/2004 1842
ACETONE 0.10 0.0050 mg/1 JRN 03/18/2004 1842
BENZENE < 0 .0010 0.0010 mg/1 JRN 03/18/2004 1842
BROMODICHLOROMETHANE < 0.0010 0.0010 mg/1 JRN 03/18/2004 1842
BROMOFORM ' o. 0010 0. 0010 mg/1 JRN 03/18/2004 1842
BROMOMETHANE < 0 .0010 0 .0010 mg/1 JRN 03/18/2004 1842
CARBON DISULFIDE < 0. 0010 0.0010 mg/1 JRN 03/18/2004 1842
CARBON TETRACHLORIDE ' 0.0010 0.0010 mg/1 JRN 03/18/2004 1842
CHLOROBENZENE ' 0 .0010 0.0010 mg/1 JRN 03/18/2004 1842
CHLOROETHANE < 0. 0010 0.0010 mg/1 JRN 03/18/2004 1842
CHLOROFORM < 0. 0010 0.0010 mg/1 JRN 03/18/2004 1842
CHLOROMETHANE < 0.0010 0 .0010 mg/1 JRN 03/18/2004 1842
CIS-1,2-DICHLOROETHENE < 0 . 0010 0 . 0010 mg/1 JRN 03/18/2004 1842
CIS-1,3-DICHLOROPROPENE < o. 0010 0 .0010 mg/1 JRN 03/18/2004 1842
DIBROMOCHLOROMETHANE < 0 .0010 0.0010 mg/1 JRN 03/18/2004 1842
ETHYLBENZENE < 0. 0010 0. 0010 mg/1 JRN 03/18/2004 1B42
METHYLENE CHLORIDE < 0 .0010 0 .0010 mg/1 JRN 03/18/2004 1842
STYRENE < 0. 0010 0 .0010 mg/1 JRN 03/1B/2004 1842
TETRACHLOROETHENE < 0 .0010 0.0010 mg/1 JRN 03/18/2004 1842
TOLUENE < 0 .0010 0.0010 mg/1 JRN 03/18/2004 1842
TRANS-1,2-DICHLOROETHENE < 0 .0010 o. 0010 mg/1 JRN 03/18/2004 1842
TRANS-1,3-DICHLOROPROPENE < o. 0010 0 .0010 mg/1 JRN 03/18/2004 1B42
TRICHLOROETHENE < 0 .0010 o. 0010 mg/1 JRN 03/18/2004 1842
VINYL ACETATE < 0 .0010 0 .0010 mg/1 JRN 03/18/2004 1842
VINYL CHLORIDE < 0. 0010 0.0010 mg/1 JRN 03/18/2004 1B42
XYLENE (TOTAL) < o. 0020 0.0020 mg/1 JRN 03/18/2004 1842
Davis & Floyd, Inc. j PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
42 ·
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DAYIS
FLMD LABORATORY ANALYSIS REPORT
Client TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Contact : Pern Carter
NC Cenijication Number: 25
Project Number: 61621.01
Report Date March 24, 2004
Page 43 of 75 Report ID: AB23157
QC Summary Data
., Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Du;~Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
DAYIS
FLtfYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenijication Number: 25
Project Number, 61621.01
Report Date
Page 44 of 75
March 24, 2004
Report ID: AB23157
QC Batch Report -Batch Sample List
workGroup WGJ6935
Description: V0/8260/TCL
Sample ID
L04030101-01
L04030101-02
l,Q40]0101-0]
I,04030101-04
L04030402-0l
L040]0402-02
L04030402-03
L04030402-04
L04030402-05
L04030402-06
L040J0402-06
L04030402-07
L04030402-08
L04030402-09
M836935: 1
LCSJ6935:l
MS04030402-01:36935
MSD04030402-0l:36935
Client ID
ITEF
ITEF DUP.
ITCI
TRIP BLANK
PEW-01
PEW-OJ
PEW-03 DUP.
PEW-04
HH-48
HH-77
HH-77
EE-58
EB-01
TRIP BLANK
Method Blank
LaboratOJY Control Spike
Matrix s'pike
Matrix Spike Duplicate
1
1
1
1
1
2
1
1
1
1
1
Matrix GW/Chemw
Prep Method
Analtyical Method: SW846 8260B
PREP ANALYTICAL
Date Time Date Ti:rne Analyst
03/08/2004 0903 PAP
03/08/2004 1049 PAP
03/08/2004 0920 PAP
03/08/2004 0956 PAP
03/08/2004 1124 PAP
03/08/2004 1142 PAP
03/08/2004 122 8 PAP
03/08/2004 1322 PAP
03/08/2004 1340 PAP
03/08/2004 1357 PAP
03/08/2004 1543 PAP
03/08/2004 1415 PAP
03/08/2004 1432 PAP
03/08/2004 1014 PAP
03/08/2004 0823 PAP
03/08/2004 1507 PAP
03/08/2004 124 7 PAP
03/08/2004 1304 PAP
Dilution
1
3
1
1
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue J Greenwood, SC 29649 I [phone] I Fax [phone]
44
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DAYIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenijication Number: 25
Project Number: 61621.01
Report Date
Page 45 of 75
March 24, 2004
Report ID: AB23157
QC Batch Report -Surrogates % Recovery
WorkGroup: WG36935 Matrix GW/ChemW
Prep Method
Analtyical Method: SW846 82608
L04030101-01 03/08/2004 0903 88 91 96
L04030101-02 03/08/2004 1049 94 93 97
L04030101-03 03/08/2004 0920 86 91 96
L04030101-04 03/08/2004 0956 82 89 97
L04030402-0l 03/08/2004 1124 95 92 94
L04030402-02 03/08/2004 1142 93 93 95
L04030402-03 03/08/2004 1228 95 94 94
L04030402-04 03/08/2004 1322 93 91 94
L04030402-05 03/08/2004 1340 92 92 95
L04030402-06 03/08/2004 1357 96 92 95
L04030402-06 03/08/2004 1543 95 92 97
L04030402-07 03/08/2004 1415 96 94 94
L04030402-0B 03/08/2004 1432 96 92 95
I,04030402-09 03/08/2004 1014 87 91 96
MB36935:1 03/08/2004 0823 83 91 97
LCS36935:1 03/08/2004 1507 95 93 96 • MS04030402-01 :36935 03/08/2(}04 124 7 96 93 97
MSD04030402-0l:36935 03/08/2004 1304 103 93 96
DCE 1,2-DICHLOROETHANE-D4
BFB BROMOFLUOROBENZENE
TOL TOLUENE-OS
ravis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I fax [phone]
45
DAYIS
FLtJ\7D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
QC Batch Report -Method Blanks
WorkGroup: WG36935
Blank MB36935:l
Para.mater Result Qual
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE < o. 0010
1,1,2,2-TETRACHLOROETHANE < 0 .0010
1,1,2-TRICHLOROETHANE < 0 . 0010
1,1-0ICHLOROETIWJE < 0 .0010
1,1-DICHLOROETHENE < 0.0010
1,2-0ICHLOROETHANE < 0.0010
1, 2-DICHLOROPROPANE < 0.0010
2~BUTANONE < 0.0050
2-HEXANONE < 0. 0050
4-METHYL-2-PENTANONE < o. 0050
ACETONE < 0 .0050
BENZENE < 0. 0010
BROMODICHLOROMETHANE < 0. 0010
BROMOFORM < 0.0010
BROMOMETHANE < 0 .0010
CARBON DISULFIDE < 0. 0010
CARBON TETRACHLORIDE < 0 .0010
CHLOROBENZENE < 0 . 0010
CHLOROETHANE < 0. 0010
CHLOROFORM < 0.0010
CHLOROMETHANE < 0.0010
CIS·l,2-DICHLOROETHENE < 0.0010
CIS-1,3-DICHLOROPROPENE < 0.0010
DIBROMOCHLOROMETHANE < 0 .0010
ETHYLBENZENE < 0 .0010
METHYLENE CHLORIDE < 0.0010
STYRENE < 0. 0010
TETRACHLOROETHENE < 0 .0010
TOLUENE < 0 .0010
TRANS-1,2-DICHLOROETHENE < o. 0010
TRANS-1,3-DICHLOROPROPENE < 0. 0010
TRICHLOROETHENE < 0 .0010
VINYL ACETATE < o. 0010
VINYL CHLORIDE < 0 .0010
XYLENE (TOTAL) < o. 0020
NC Certification Number: 25
Project Number, 61621.·01
Report Date
Page 46 of 75
Matrix: GW/Chemw
RDL Units
o.oo~o ing/1
0. 0010 mg/1
0 . 0010 mg/1
0 .0010 mg/1
0. 0010 mg/1
0.0010 mg/1
0.0010 mg/1
0.0050 mg/1
0.0050 mg/1
0.0050 mg/1
0.0050 mg/1
0.0010 mg/1
0.0010 mg/1
0.0010 mg/1
0.0010 mg/1
0. 0010 mg/1
0 .0010 mg/1
0 .0010 mg/1
0.0010 mg/1
0.0010 mg/1
0.0010 mg/1
0.0010 mg/1
0. 0010 mg/1
0.0010 mg/1
0.0010 mg/1
0.0010 mg/1
0.0010 mg/1
0.0010 mg/1
0.0010 mg/1
0.0010 mg/1
0. 0010 mg/1
0 .0010 mg/1
0 . 0010 mg/1
0.0010 mg/1
0. 0020 mg/1
March 24, 2004
Report ID: AB23157
Analyst Date
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
PAP 03/08/2004
Time
0823
0823
0823
0823
0823
0823
0823
0823
0823
0823
0823
0823
0823
0823
0823
0823
0823
0823
0823
0823
0823
0823
0823
0823
0823
0823
0823
0823
0823
0823
0823
0823
0823
0823
0823
Davis & Floyd, Inc. ! PO Drawer 428 I Greenwood, SC 29648 l 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
46
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DAYIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 47 of 75
March 24, 2004
Report ID: AB23157
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG36935 Matrix GW/ChemW
MS/MSD MS040)0402-01=36935 Prep Method
MSD04030402-01=36935 Analtyical Method: SWB46 82608
1,1,1-TR!CHLOROETHANE o. 0500 'o. 00100 0.0527 mg/1 105 88-124
1,1,2-TRICHLOROETHANE 0. 0500 'o. 00100 0. 047-4 mg/1 95 88-128
1,1-DICHLOROETHENE 0 . 0500 ' 0 .00100 o . 0627 mg/1 125 71-130
1,2-DICHLOROETHANE 0. 0500 -' 0 .00100 0. 0491 mg/1 90 78-143
1,2-DICHLOROPROPANE 0.0500 ' 0 .00100 0 . 0491 mg/1 98 91-118
2-BUTANONE 0.0500 ' 0 .00500 0 .0463 mg/1 93 28-199
BENZENE 0.0500 '0. 00100 0 .0502 mg/1 100 77-123
CARBON TETRACHLORIDE 0.0500 'o. 00100 0.0536 mg/1 107 63-135
CHLOROBENZENE 0.0500 ' 0 .00100 0.0476 mg/1 95 78-123
CHLOROFORM 0.0500 0. 00172 0 .0479 mg/1 92 75-135
DIBROMOCHLOROMETHANE 0.0500 ' 0 .00100 o. 0545 mg/1 109 88-133
TETRACHLOROETHENE 0.0500 ' 0 .00100 0 .0483 mg/1 97 69-123
TOLUENE 0.0500 ' 0. 00100 0.0474 mg/1 95 85-117
TRICHLOROETHENE 0. 0500 0 .00545 0.0553 mg/1 100 75-121
VINYL CHLORIDE 0. 0500 '0. 00100 0.0548 mg/1 110 47-136
1,1,1-TRICHLOROETHANE 0 .0500 0.0553 mg/1 1il 5 15 88-124
1, 1, 2-TRICHLOROETHANE 0. 0500 0.0522 mg/1 104 10 17 88-128
1,1-DICHLOROETHENE 0. 0500 0.0641 mg/1 128 2 17 71-130
1,2-DICHLOROETHANE 0 . 0500 0 . 0536 mg/1 99 9 20 78-143
1,2-DICHLOROPROPANE 0. 0500 0. 0518 mg/1 104 5 14 91-118
2-BUTANONE o. 0500 0 .0621 mg/1 124 29 31 28-199
BENZENE o. 0500 0 . 0521 mg/1 104 4 17 77-123
CARBON TETRACHLORIDE 0.0500 0. 0567 mg/1 113 6 20 63-135
CHLOROBENZENE 0.0500 0 .0490 mg/1 98 3 17 78-123
CHLOROFORM 0.0500 0.0506 mg/1 98 5 17 75-135
DIBROMOCHLOROMETHANE o. 0500 0 . 0586 mg/1 117 7 15 88-133
TETRACHLOROETHENE 0 . 0500 o. 0498 mg/1 100 17 69-123
TOLUENE 0 . 0500 0 . 0484 mg/1 97 2 15 85-117
TRICHLOROETHENE 0 .0500 0 .0577 mg/1 105 4 17 75-121
VINYL CHLORIDE 0 .0500 0 .0545 mg/1 109 19 47-136
NOTE: MS/MSD l recoveries are not evaluated if the sample concentration is greater than four times the spike added .
I Davis & Floyd, Inc. I PO Dcawe, 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I G,eenwood, SC 29649 I [phone] I fax [phone]
47
DAYIS
FLtiYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 48 of 75
March 24, 2004
Report ID: AB23157
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG36935 Matrix GW/ChemW
LCS LCS36935:1 Prep Method
Analtyical Method: SW846 82608
1,1,1-TRICHLOROETHANE 0.0200 0 0210 mg/1 105 79-127
1,1,2-TRICHLOROETHANE 0.0200 0 0205 mg/1 102 83-143
1,1-DICHLOROETHENE 0.0200 0 .0250 mg/1 125 63-141
1,2-DICHLOROETHANE 0.0200. o. 0209 mg/1 105 79-147
1,2-DICHLOROPROPANE 0. 0200 0 . 0205 mg/1 103 86-130
2-BUTANONE 0 0200 0 0226 mg/1 113 52-190
BENZENE 0.0200 0 . 0213 mg/1 107 78-123
CARBON TETRACHLORIDE 0 . 0200 0. 0216 mg/1 108 58-132
CHLOROBENZENE o. 0200 0.0201 mg/1 101 81-124
CHLOROFORM 0.0200 0.0194 mg/1 97 75-138
DIBROMOCHLOROMETHANE 0. 02 00 0. 0217 mg/1 108 82-13 7
TETRACHLOROETHENE 0.0200 0.0194 mg/1 97 71-120
TOLUENE 0. 0200 0.0201 mg/1 100 81-121
TRICHLOROETHENE 0.0200 0 0210 mg/1 105 76-120
VINYL CHLORIDE 0.0200 0.0229 mg/1 ll5 51-138
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
48
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Di\YIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 49 of 75
March 24, 2004
Report ID: AB23157
QC Batch Report -Batch Sample List
WorkGroup WG36988
Description: VO/8260/TCL
Sample ID
L04030807 01
L04030807 02
L04030807-03
L04030807-04
L04030807-05
L04030807-06
MB36988:1
LCS36988:1
MS04030807 01:36988
MSD04030807-01:36988
Client ID
AA-54
P-58
C-49
FF-34
FF-62
TRIP BLANK
Method Blank
Laboratory Control Spike
Matrix Spike
Matrix Spike Duplicate
Run#
1
1
1
1
Matrix GW/Chemw
Prep Method
Analtyical Method: SW846 82608
PREP ANALYTICAL
Date Time Date Time Analyst
03/08/2004 1640 PAP
03/08/2004 1732 PAP
03/08/2004 1749 PAP
03/08/2004 1807 PAP
03/08/2004 1824 PAP
03/08/2004 1622 PAP
03/08/2004 1601 PAP
03/08/2004 1842 PAP
03/08/2004 1657 PAP
03/08/2004 1715 PAP
Dilution
1
1
1
1
1
1
'Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I fax [phone]
49
DAYIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenijication Number: 25
Project Number: 61621.01
Report Date
Page so of 75
March 24, 2004
Report ID: AB23157
QC Batch Report -Surrogates % Recovery
WorkGroup: WG36988 Matrix GW/ChemW
Prep Method
Analtyical Method: SW846 82608
L04030807-01 03/08/2004 1640 92 92 ;95
L04030807-02 03/08/2004 1732 94 92 96
L04030807-03 03/08/2004 1749 89 91 95
L04030807-04 03/08/2004 1807 92 92 96
L04030807-05 03/08/2004 1824 90 92 96
L04030807-06 03/08/2004 1622 88 90 97
MB36988:l 03/08/2004 1601 BB 94 97
LCS36988:l 03/08/2004 1842 92 93 98
MS04030807-01 :36988 03/08/2004 1657 102 93 98
MSD04030807-01:36988 03/08/2004 1715 102 94 96
DCE 1,2-DICHLOROETHANE-D4
BFB BROMOFLUOROBENZENE
TOL TOLUENE-DB
Davis & Floyd, Inc. ! PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue J Greenwood, SC 29649 I [phone] ! Fax [phone]
50
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I D~S FL D LABORATORY ANALYSIS REPORT
I NC Certification Number: 25
I Client TICONA,LLC Project Number: 61621.01
2525 BLACKSBURG ROAD
HWY 198
I SHELBY, NC 28152 Report Date March 24, 2004
Contact Fem carter Page 51 of 75 Report ID: AB23157
I QC Batch Report -Method Blanks
workGroup: WG36988 Matrix: GW/Chemw
I Blank MB36Sl88:1
Parameter Result Qual RDL Units Analyst Date Time
I Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE < 0.0050 0. 005,0 mg/1 PAP 03/08/2004 1601
1,1,2,2-TETRACHLOROETHANE < 0. 0050 0.0050 rng/1 PAP 03/08/2004 1601 I 1,1,2-TRICHLOROETHANE < 0.0050 0 0050 mg/1 PAP 03/08/2004 1601
1,1-DICHLOROETHANE < 0.0050 0.0050 mg/1 PAP 03/08/2004 1601
1,1-DICHLOROETHENE < 0.0050 0.0050 mg/1 PAP 03/08/2004 1601
I 1,2-0ICHLOROETHANE < 0.0050 0.0050 mg/1 PAP 03/08/2004 1601
1,2-DICHLOROPROPANE < 0.0050 0.0050 mg/1 PAP 03/08/2004 1601
2-BUTANONE < 0.010 0. 010 mg/1 PAP 03/08/2004 1601
2-HEXANONE < 0.010 0.010 mg/1 PAP 03/08/2004 1601
I 4-METHYL-2-PENTANONE < 0.0050 0.0050 mg/1 PAP 03/08/2004 1601
ACETONE < 0.010 0. 010 mg/1 PAP 03/08/2004 1601
BENZENE < o.ooso 0.0050 mg/1 PAP 03/08/2004 1601
BROMODICHLOROMETHANE < 0.0050 0.0050 mg/1 PAP 03/08/2004 1601 I BROMOFORM < 0.0050 0.0050 mg/1 PAP 03/08/2004 1601
BROMOMETHANE ' 0.010 0. 010 mg/1 PAP 03/08/2004 1601
CARBON DISULFIDE < 0.0050 0. 0050 mg/1 PAP 03/08/2004 1601
I. CARBON TETRACHLORIDE < 0.0050 0.0050 mg/1 PAP 03/08/2004 1601
CHLOROBENZENE < 0.0050 0.0050 mg/1 PAP 03/08/2004 1601
CHLOROETHANE < 0.010 0.010 mg/1 PAP 03/08/2004 1601
CHLOROFORM < 0.0050 0.0050 mg/1 PAP 03/08/2004 1601
I CHLOROMETHANE < 0.010 0.010 mg/1 PAP 03/08/2004 1601
CIS-1,2-DICHLOROETHENE < 0.0050 0.0050 mg/1 PAP 03/08/2004 1601
CIS-1,3-DICHLOROPROPENE ' 0. 0050 0.0050 mg/1 PAP 03/08/2004 1601
DIBROMOCHLOROMETHANE < 0 . 0050 0. 0050 mg/1 PAP 03/08/2004 1601 I ETHYLBENZENE < o. 0050 0. 0050 mg/1 PAP 03/08/2004 1601
METHYLENE CHLORIDE < 0 0050 0.0050 mg/1 PAP 03/08/2004 1601
STYRENE < 0 0050 0 0050 mg/1 PAP 03/08/2004 1601
I TETRACHLOROETHENE < 0 0050 0.0050 mg/1 PAP 03/08/2004 1601
TOLUENE < 0. 0050 0 .0050 mg/1 PAP 03/08/2004 1601
TRANS-1,2-DICHLOROETHENE ' 0 .0050 0 . 0050 mg/1 PAP 03/08/2004 1601
TRANS-1,3-DICHLOROPROPENE < o. 0050 0.0050 mg/1 PAP 03/08/2004 1601
I TRICHLOROETHENE < 0 0050 0.0050 mg/1 PAP 03/08/2004 1601
VINYL ACETATE < 0.010 0.010 mg/1 PAP 03/08/2004 1601
VINYL CHLORIDE < 0.010 0. 010 mg/1 PAP 03/08/2004 1601
XYLENE
I
(TOTAL) < 0.0050 0.0050 mg/1 PAP 03/08/2004 1601
r•vis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 / 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
51
Df\YIS
FLtJ\1D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 2B152
Pem Carter
NC Cet1ijicatio11 Number: 25
Project Number: 61621.01
Report Date
Page 52 of 75
March 24, 2004
Report ID: AB23157
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG36988 Matrix GW/Chemw
MS/MSD MS04030807-01:36988 Prep Method
MSD04030807-0l:36988 Analtyical Method: SW846 82608
1, 1!1-TRICHLOROETHANE 0 . 0500 < 0.00100 0.0526 mg/1 105 88-124
1,1,2-TRICHLOROETHANE 0 . 0500 < 0.00100 0. 05,03 mg/1 101 88-128
1,1-DICHLOROETHENE 0. 0500 < 0 .00100 0 . 0609 mg/1 122 71-130
1,2-DICHLOROETHANE 0.0500 < 0. 00100 o. 0519 mg/1 95 78-143
1,2-DICHLOROPROPANE 0.0500 < 0 .00100 o. 0498 mg/1 100 91-118
2-BUTANONE 0.0500 < 0 .00500 0 .0632 mg/1 126 28-199
BENZENE 0.0500 < 0 .00100 o. 0505 mg/1 101 77-123
CARBON TETRACHLORIDE 0 . 0500 < 0. 00100 0 .0527 mg/1 105 63-135
CHLOROBENZENE 0 .0500 < 0.00100 0 . 0473 mg/1 95 78-123
CHLOROFORM 0. 0500 < 0 .00100 0 . 0461 rng/1 92 75-135
DIBROMOCHLOROMETHANE 0 . 0500 < 0 .00100 0 . 0554 mg/1 111 88-133
TETRACHLOROETHENE 0 .0500 < 0 .00100 0. 0468 mg/1 94 69-123
TOLUENE 0. 0500 < 0 .00100 0 . 0474 rng/1 95 85-117
TRICHLOROETHENE 0. 0500 < o. 00100 0. 0496 rng/1 99 75-121
VINYL CHLORIDE 0. 0500 < 0.00100 o. 0515 mg/1 103 47-136
1,1,1-TRICHLOROETHANE 0. 0500 0.0518 rng/1 104 l 15 88-124
1,1,2-TRICHLOROETHANE 0 .0500 0.0494 mg/1 99 2 17 88-128
1,1-DICHLOROETHENE 0. 0500 0.0609 mg/1 122 0 17 71-130
1,2-DICHLOROETHANE 0 .0500 0.0522 mg/1 96 l 20 78-143
1,2-DICHLOROPROPANE 0.0500 0.0488 mg/1 98 2 14 91-118
2-BUTANONE 0.0500 0 . 0622 mg/1 124 2 31 28-199
BENZENE 0.0500 0 . 0496 mg/1 99 2 17 77-123
CARBON TETRACHLORIDE 0.0500 0.0521 mg/1 104 l 20 63-135
CHLOROBENZENE 0 . 0500 0 . 0467 rng/1 93 l 17 78-123
CHLOROFORM o. 0500 0.0467 mg/1 93 17 75-135
DIBROMOCHLOROMETHANE 0 . 0500 0.0555 mg/1 111 0 15 88-133
TETRACHLOROETHENE 0 . 0500 0.0463 mg/1 93 l 17 69-123
TOLUENE 0. 0500 0 .0462 mg/1 92 2 15 85-117
TRICHLOROETHENE 0.0500 0 .0497 mg/1 99 0 17 75-121
VINYL CHLORIDE 0.0500 0 .0489 mg/1 98 5 19 47-136
NOTE: MS/MSD t recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue J Greenwood, SC 29649 I [phone] I Fax [phone]
5 2·
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Di\VIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 19B
SHELBY, NC 28152
Pem Carter
NC Cenification Number: 25
Project Number, 61621.01
Report Date
Page 53 of 75
March 24, 2004
Report IO, AB23157
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG36988 Matrix GW/ChemW
LCS LCS36988:l Prep Method
Analtyical Method: SW846 8260B
1,1,1-TRICHLOROETHANE 0.0200 0.0208 mg/1 104 79-127
1,1,2-TRICHLOROETHANE 0.0200 0 0199 mg/1 99 83-143
1,1-DICHLOROETHENE 0.0200 0. 0248 mg/1 124 63-141
1,2-DICHLOROETHANE 0. 0200 0. 0198 mg/1 99 79-147
1,2-DICHLOROPROPANE 0.0200 0 . 0202 mg/1 101 86-130
2-BUTANONE 0.0200 0 0203 mg/1 102 52-190
BENZENE 0.0200 0 . 0211 mg/1 105 78-123
CARBON TETRACHLORIDE 0.0200 0. 02 02 mg/1 101 58-132
CHLOROBENZENE 0. 0200 0.0199 mg/1 100 81-124
CHLOROFORM 0.0200 0.0190 mg/1 95 75-138
DIBROMOCHLOROMETHAfJE 0.0200 0. 0211 mg/1 106 82 -13 7
TETRACHLOROETHENE 0. 0200 0.0199 mg/1 100 71-120
TOLUENE 0.0200 0. 02 02 mg/1 101 81-121
TRICHLOROETHENE 0.0200 0 . 0204 mg/1 102 76-120
VINYL CHLORIDE 0.0200 0 0213 mg/1 107 51-138
.Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
53
Df\VIS
FLtiYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 54 of 75
Marcti 24, 2004
Report ID: AB23157
QC Batch Report -Batch Sample List
Sample ID
L04031504-0l
L04031504-02
L04 031504-03
L04 031504-04
L04031504-05
L04031504-06
MB37154:l
LCS37154:l
WorkGroup WG37154
.Description, V0/8260/TCL
Client ID
K-28
CC-33
GG-61
T-35
V-23
TRIP BLANK
Method Blank
Laboratory Control
MS04031504-02:37154 Matrix Spike
TIC-SHB
Spike
MSD04031504-02:37154 Matrix Spike Duplicate
•=#
1
1
1
1
1
1
1
Matrix GW/ChemW
Prep Method
Analtyical Method: SW846 8260B
PREP ANALYTICAL
Date Time Date Time Analyst
03/18/2004 1859 JRN
03/18/2004 1917 JRN
03/18/2004 1934 JRN
03/18/2004 1952 JRN
03/18/2004 2009 JRN
03/18/2004 1842 JRN
03/18/2004 1824 JRN
03/18/2004 2137 JRN
03/18/2004 2044 JRN
03/18/2004 2102 JRN
Dilution
1
1
1
1
1
1
Davis & Floyd, Inc. I PO Drawer 428 j Greenwood, SC 29648 j 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
54
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DAYIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 55 of 75
March 24, 2004
Report ID: AB23157
QC Batch Report -Surrogates % Recovery
WorkGroup: WG37154 Matrix GW/ChemW
Prep Method
Analtyical Method: SW846 8260B
L04031504-0l 03/18/2004 1B59 97 98 :98
L04031504-02 03/18/2004 1917 100 99 96
L04031504-03 03/18/2004 1934 99 99 96
L04031504-04 03/18/2004 1952 99 98 95
L04031504-05 03/18/2004 2009 86 98 96
L04031504-06 03/18/2004 1842 95 98 99
MB37154: 1 03/18/2004 1824 99 98 97
LCS37154:l 03/18/2004 2137 104 98 97
MS04031504-02 :37154 03/18/2004 2044 108 100 97
MSD04031504-02:37154 03/18/2004 2102 109 99 96
DCE 1,2-DICHLOROETHANE-D4
BFB BROMOFLUOROBENZENE
TOL TOLUENE-DB
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I Bl 6 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
55
Di\YIS
FLtJ\'D LABORATORY ANALYSIS REPORT
NC Certification Number: 25
Client TICONA,LLC Project Number: 61621.01
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152 Report Date March 24, 2004
Contact Pem Carter Page 56 of 75 Report ID: AB23157
QC Batch Report -Method Blanks
WorkGroup: WG37l54 Matrix: GW/ChemW
Blank MB37154:l
Parameter Result Qual RDL Units Analyst Date Timo
Volat.ile Organics
SW846 82608
1,1,1-TRICHLOROETHANE ' 0.0010 0.0010 mg/1 JRN 03/18/2004 1824
1,1,2,2-TETRACHLOROETHANE ' 0.0010 0 . 0010 mg/1 JRN 03/18/2004 1824
1,1,2-TRICHLOROETHANE ' 0.0010 o. 0010 mg/1 JRN 03/18/2004 1824
1,1-DICHLOROETHANE ' 0.0010 0. 0010 mg/1 JRN 03/18/2004 1824
1,1-DICHLOROETHENE ' 0 . 0010 0 . 0010 mg/1 JRN 03/18/2004 1824
1,2-0ICHLOROETHANE ' 0 . 0010 0.0010 mg/1 JRN 03/18/2004 1824
1,2-DICHLOROPROPANE ' 0 .0010 0.0010 mg/1 JRN 03/18/2004 1824
2-BUTANONE ' o. 0050 0.0050 mg/1 JRN 03/18/2004 1824
2-HEXANONE ' 0 .0050 0.0050 mg/1 JRN 03/18/2004 1824
4-METHYL-2-PENTANONE ' 0 . 0050 0 . 0050 mg/1 JRN 03/18/2004 1824
ACETONE ' 0. 0050 o. 0050 mg/1 JRN 03/18/2004 1824
BENZENE ' 0.0010 0. 0010 mg/1 JRN 03/18/2004 1824
BROMODICHLOROMETHANE ' 0.0010 0 . 0010 mg/1 JRN 03/18/2004 1824
BROMOFORM ' 0.0010 0 .0010 mg/1 JRN 03/18/2004 1824
BROMOMETHANE ' 0.0010 0.0010 mg/1 JRN 03/18/2004 1824
CARBON DISULFIDE ' 0.0010 0 . 0010 mg/1 JRN 03/18/2004 1824
CARBON TETRACHLORIDE ' 0.0010 0 .0010 mg/1 JRN 03/18/2004 1824
CHLOROBENZENE ' 0.0010 o. 0010 mg/1 JRN 03/18/2004 1824
CHLOROETHANE ' 0.0010 0.0010 mg/1 JRN 03/18/2004 1824
CHLOROFORM < 0 .0010 0.0010 mg/1 JRN 03/18/2004 1824
CHLO ROM ETHANE ' o. 0010 0.0010 mg/1 JRN 03/18/2004 1824
CIS-1,2-DICHLOROETHENE ' 0.0010 0.0010 mg/1 JRN 03/18/2004 1824
CIS-1,3-DICHLOROPROPENE ' 0.0010 0 .0010 mg/1 JRN 03/18/2004 1824
DIBROMOCHLOROMETHANE ' 0.0010 0 . 0010 mg/1 JRN 03/18/2004 1824
ETHYLBENZENE ' 0.0010 0.0010 mg/1 JRN 03/18/2004 1824
METHYLENE CHLORIDE ' 0.0010 0 . 0010 mg/1 JRN 03/18/2004 1824
STYRENE ' 0.0010 0. 0010 mg/1 JRN 03/18/2004 1824
TETRACHLOROETHENE ' 0.0010 0 .0010 rrg/1 JRN 03/18/2004 1824
TOLUENE ' 0.0010 o. 0010 mg/1 JRN 03/18/2004 1824
TRANS-1,2-DICHLOROETHENE ' 0.0010 0 .0010 mg/1 JRN 03/18/2004 1824
TRANS-1,3-DICHLOROPROPENE ' 0.0010 0. 0010 mg/1 JRN 03/18/2004 1824
TRICHLOROETHENE ' 0.0010 0 . 0010 mg/1 JRN 03/18/2004 1824
VINYL ACETATE ' 0.0010 0 .0010 mg/1 JRN 03/18/2004 1824
VINYL CHLORIDE ' 0 .0010 o. 0010 mg/1 JRN 03/18/2004 1824
XYLENE (TOTAL) ' 0 . 0020 0. 002 0 mg/1 JRN 03/18/2004 1824
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue ] Greenwood, SC 29649 [ [phone] ) Fax [phone]
56
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DAYIS
FLM:D LABORATORY ANALYSIS REPORT
Client
· Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 57 of 75
March 24, 2004
Report ID: AB23157
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG37154 Matrix GW/ChemW
MS/MSD MS04031504-02:)7154 Prep Method
MSD04031504-02:37154 Analtyical Method, SW846 8260B
1,1,1-TRICHLOROETHANE 0 .0500 < 0 .00100 0 . 0532 mg/1 106 88-124
1,1,2-TRICHLOROETHANE 0. 0500 < 0. 00100 0. 05_29 mg/1 106 88-128
1,1-DICHLOROETHENE 0 . 0500 < 0 . 00100 0.0546 mg/1 109 71-130
1,2-DICHLOROETHANE 0. 0500 < 0.00100 0.0546 mg/1 109 78-143
1,2-DICHLOROPROPANE 0.0500 < 0.00100 0.0526 mg/1 105 91-118
2-BUTANONE 0.0500 0 . 00863 0 . 0657 mg/1 114 28-199
BENZENE 0. 0500 0. 00166 0 . 0530 mg/1 103 77-123
CARBON TETRACHLORIDE o. 0500 < 0 . 00100 0 . 0522 mg/1 104 63-135
CHLOROBENZENE o. 0500 < o. 00100 0. 0513 mg/1 100 78-123
CHLOROFORM o. 0500 < 0 . 00100 0 . 0526 mg/1 105 75-135
DIBROMOCHLOROMETHANE 0 . 0500 < o . 00100 0 .0553 mg/1 111 88-133
TETRACHLOROETHENE 0. 0500 < 0 . 00100 0 . 0499 mg/1 100 69-123
TOLUENE 0.0500 < 0.00100 0 . 0503 mg/1 101 85-117
TRICHLOROETHENE 0 .0500 0 . 00118 0.0527 mg/1 103 75-121
VINYL CHLORIDE 0 .0500 < 0 .00100 0. 04 56 mg/1 91 47-136
1,1,1-TRICHLOROETHANE 0 .0500 0 . 0540 mg/1 108 l 15 88-124
1,1,2-TRICHLOROETHANE o. 0500 o. 0523 mg/1 105 1 17 88-128
1,1-DICHLOROETHENE 0 .0500 0 .0539 mg/1 108 1 17 71-130
1,2-DICHLOROETHANE 0 .0500 0 .0558 mg/1 112 2 20 78-143
1,2-DICHLOROPROPANE 0.0500 0 . 0527 mg/1 105 0 14 91-118
2-BUTANONE 0.0500 o. 0650 mg/1 113 1 31 28-199
BENZENE 0.0500 0 . 0527 mg/1 102 0 17 77-123
CARBON TETRACHLORIDE 0.0500 0 .0532 mg/1 106 2 20 63-135
CHLOROBENZENE 0.0500 0. 0509 mg/1 100 1 17 78-123
CHLOROFORM 0.0500 0.0532 mg/1 106 1 17 75-135
DIBROMOCHLOROMETHANE 0.0500 0.0563 mg/1 113 2 15 88-133
TETRACHLOROETHENE 0 .0500 0.0485 mg/1 97 3 17 69-123
TOLUENE 0 . 0500 0 . 0497 mg/1 99 15 B5-117
TRICHLOROETHENE o. 0500 0 . 0526 mg/1 103 0 17 75-121
VINYL CH LOR IDE 0 . 0500 0 . 0450 rng/1 90 19 47-136
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
'avis & Floyd, Inc. l PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
5 7:
DAYIS
FLt1YD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cerrijication Number: 25
Project Number: 61621.01
Report Date
Page 58 of 75
March 24, 2004
Report ID: AB23157
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG37154 Matrix GW/Chemw
LCS LCS37l54:l Prep Method
Analtyical Method: SW846 82608
1,1,1-TRICHLOROETHANE 0.0200 0. 0217 mg/1 109 79-127
1,1,2-TRICHLOROETHANE 0.0200 0. 0211 mg/1 105 83 -14 3
1,1-DICHLOROETHENE 0. 0200 0.0217 mg/1 108 63-141
1,2-DICHLOROETHANE 0 0200 · 0.0222 mg/1 111 79-147
1,2-DICHLOROPROPANE 0 0200 0.0217 mg/1 109 86-130
2-BUTANONE 0. 0200 0.0242 mg/1 121 52 -190
BENZENE 0. 0200 0.0217 mg/1 108 78-123
CARBON TETRACHLORIDE 0 0200 0.0209 mg/1 105 58-132
CHLOROBENZENE 0 0200 0. 0211 mg/1 106 81-124
CHLOROFORM 0 0200 0 . 0218 mg/1 109 75-138
DIBROMOCHLOROMETHANE 0.0200 0. 0215 mg/1 107 82-137
TETRACHLOROETHENE 0.0200 0.0205 mg/1 103 71-120
TOLUENE 0.0200 0.0206 mg/1 103 81-121
TRICHLOROETHENE 0. 02 00 0.0212 mg/1 106 76-120
VINYL CHLORIDE 0.0200 0.0200 mg/1 100 51-138
Davis & Floyd, Inc. I PO Drawer 428 j Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
I
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Sample ID
L04030402-01
L04030402-0l
L04030402-02
L04030402-02
L04030402-03
L04030402-03
L04030402-04
L04030402-04
·~
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenification Number: 25
Project Number: 61621.01
Report Date
Page 59 of 75
March 24, 2004
Report ID: AB23157
QC Batch Report -Batch Sample List
WorkGroup WG36982
Description: sv/8270/bna/tcl sv/dow
Client ID Run#
PEW-01 1
PEW-01
PEW-03 1
PEW-03
PEW-OJ DUP. 1
PEW-03 DUP. 1
PEW-04 1
PEW-04 1
Matrix
Prep Method
GW/Chemw
SW846 3510C
Analtyical Method: SW846 8270C
PREP ANALYTICAL
Date Time Date Time
03/08/2004 0800 03/16/2004 1507
03/08/2004 0800 03/16/2004 1507
03/08/2004 0800 03/16/2004 1727
03/08/2004 0800 03/17/2004 0033
03/08/2004 0800 03/16/2004 1842
03/08/2004 0800 03/17/2004 0111
03/08/2004 0800 03/16/2004 1922
03/08/2004 0800 03/16/2004 1922
Analyst
DBC
DBC
DBC
DBC
DBC
DBC
DBC
DBC
Dilution
1
1
20
1
20
I Davis & Floyd, Inc. I PD Drawer 428 / Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
59
Di\VIS
FLtJYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 60 of 75
March 24, 2004
R~port ID: AB23157
QC Batch Report -Surrogates % Recovery
WorkGroup: WG36982
L04030402-01 ,03/16/2004 1507
L04030402-02 03/16/2004 1727
L04030402-02 03/17/2004 0033
L04030402-03 03/16/2004 1842
L04030402-03 03/17/2004 0111
L04030402-04 03/16/2004 1922
TSP 2,4,6-TRIBROMOPHENOL
FBP 2-FLUOROBIPHENYL
2FP 2 -FLUOROPHENOL
NBZ NITROBENZENE-D5
PHL PHENOL-OS
TPH TERPHENYL-D14
NOTE:: *NE -Result was not evalua1;ect.
88 69
93 70
93 70
93 77
93 77
75 58
Matrix
Prep Method
GW/ChemW
SW846 3510C
Analtyical Method: SW846 8270C
/49 74 33
54 BS 35
54 85 35
55 83 40
55 83 40
37 63 35
92
76
76
75
75
96
Davis & Floyd, Inc. ! PO Drawer 428 I Greenwood, SC 29648 / 816 E. Durst Avenue I Greenwood, SC 29649 ! [phone] I Fax [phone]
60'
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Df\YIS
FLbYD LABORATORY ANALYSIS REPORT
Sample ID
L04030402-01
L04G30402-0l
L04030402-02
L04030402-02
L04030402-03
L04030402-03
L04030402-04
L04030402-04
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 61 of 75
March 24, 2004
Report ID: AB23157
QC Batch Report -Batch Sample List
WorkGroup WG36982 Matrix GW/ChemW
Description: sv/8270/bna/tcl sv/dow Prep Method SW846 3500B
Analtyical Method: SW846 8270C DOWTHERM
PREP ANALYTICAL
Client ID Run# Date Time Date Time Analyst
PEW-01 03/08/2004 0800 03/16/2004 1507 DBC
PEW-01 0)/08/2004 0800 03/16/2004 1507 DBC
PEW 03 03/08/2004 0800 03/16/2004 1727 DBC
PEW-03 03/08/2004 0800 03/17/2004 0033 DBC
PEW-03 DUP. 03/08/2004 0800 03/16/2004 1842 DBC
PEW-03 DUP. 03/08/2004 0800 03/17/2004 0111 DBC
PEW-04 03/08/2004 0800 03/16/2004 1922 DBC
PEW-04 03/08/2004 0800 03/16/2004 1922 DBC
Dilution
1
1
20
1
20
1
1
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
61'
DAYIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 62 of 75
March 24, 2004
Report ID: AB23157
QC Batch Report -Surrogates % Recovery
workGroup: WGJ6982
L04030402-01 03/16/2004 1507
L04030402-02 03/16/2004 1727
L04030402-02 03/17/2004 0033
L04030402-03 03/16/2004 1842
L04030402-03 03/17/2004 0111
L04030402-04 03/16/2004 1922
TBP 2,4,6-TRIBROMOPHENOL
FBP 2 -FLUOROBI PHENYL
2FP 2-FLUOROPHENOL
NBZ NITROBENZENE-05
PHL PHENOL-OS
TPH TERPHENYL-D14
NOTE1 *NE -Result was not evalua,rect.
88 69
93 70
'3 70
93 77
93 77
75 58
Matrix
Prep Method
GW/Chemw
SW846 35008
Analtyical Method: SW846 8270C DOWTHERM
,'49 74 33 92
54 85 35 76
54 85 35 76
55 83 40 75
55 83 40 75
37 63 35 96
Davis & Floyd, Inc. I PO Drawer 428 J Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 ! [phone] I Fax [phone]
62
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DAYIS
FLffi'D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 63 of 75
March 24, 2004
Report ID: AB23157
QC Batch Report -Batch Sample List
Sample ID
L04030101-01
L04030101-02
L04030101-03
MB37000:l
LCS37000:l
MS04030101-0l:
WorkGroup WG37000
Description: GC/EG
Client ID
ITEF
ITEF DUP.
ITCI
Method Blank
Laboratory Control
37000 Matrix Spike
Spike
MSD04030101-01:37000 Matrix Spike Duplicate
•=•
1
1
Matrix GW/Chemw
Prep Method
Analtyical Method: SW846 8015
PREP ANALYTICAL
Date Time Date Time Analyst
03/09/2004 1123 MGB
03/09/2004 1149 MGB
03/09/2004 1332 MGB
03/09/2004 1005 MGB
03/09/2004 1031 MGB
03/09/2004 1240 MGB
03/09/2004 1240 MGB
Dilution
1
20
1
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 j 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
63•
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
QC Batch Report -Method Blanks
WorkGroup: WG37000
Blank MB37000:l
Parameter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
Result Qual
< 7.0
NC Cenification Number: 25
Project Number: 61621.01
Report Date March 24, 2004
Page 64 of 75 Report ID: AE23157
Matrix: GW/ChemW
RDL Units Analyst Date Time
MGB 03/09/2004 1005
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
64
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DAYIS
FLtJvD LABORATORY ANALYSIS REPORT
ETHYLENE GLYCOL
ETHYLENE GLYCOL
Client
contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 65 of 75
March 24, 2004
Report ID: AB23157
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG37000 Matrix GW/Chemw
MS/MSD MS04030101-01137000 Prep Method
MSD04030101-0li37000 Analtyical Method: SW846 8015
50.00 < 7.00 71.10 mg/1 142 57-158
50.00 61. 08 mg/1 122 15 24 57 158
NOTE: MS/MSD I recoveries are not evaluated if the sample concentration is greater than four times the spike added.
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
65,
Di\YIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Fem Carter
NC Cenification Number: 25
Projec~ t:Ju;1:h_er: 61621.01
Report Date March 24, 2004
Page 66 of 75 Report ID: AB23157
QC Batch Report -Laboratory Control Standards and Duplicates
,workGroup: WG37000 Matrix GW/Chemw
;Les LCS37000:l Prep Method
Analtyical Method: SW846 8015
ETHYLENE GLYCOL 110 77-126
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 j [phone] I Fax [phone]
66
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Di\YIS
FLMD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 281S2
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 67 of 75
March 24, 2004
Report ID: AB23157
QC Batch Report -Batch Sample List
WorkGroup WG36924 Matrix GW/Chemw
Description: TDC GW Prep Method
Analtyical Method, SW846 9060
PREP ANALYTICAL
Sample ID Client ID Run# Date Time Date Time Analyst
L04030101-01 ITEF 1 03/02/2004 0206 CBN
L04030101-02 ITEF DUP. 1 03/02/2004 0237 CBN
L04030101-03 ITCI 03/02/2004 0310 CBN
MB36924: 1 Method Blank 03/01/2004 2316 CBN
MB36924: 1 Method Blank 2 03/02/2004 0518 CBN
LCS365124: 1 Laboratory Control Spike 1 03/01/2004 2256 CBN
LCS36924: 1 Laboratory control Spike 2 03/02/2004 0436 CBN
MS04022601-01:36924 Matrix Spike 1 03/01/2004 2150 CBN
MS04022601-ll:36924 Matrix Spike 1 03/02/2004 0331 CBN
MSD04022601-01 :36924 Matrix Spike Duplicate 03/01/2004 2212 CBN
MSD04022601-ll:36924 Matrix Spike Duplicate 03/02/2004 0353 CBN
Dilution
1
1
20
1
1
1
1
1
1
1
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I Bl 6 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
6 7-
DAYIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
QC Batch Report -Method Blanks
WorkGroup: WG36924
Parameter
Wet. Chemistry
SW846 9060
:Blank
ORGANIC CARBON, TOTAL
ORGANIC CARBON, TOTAL
MB36924: 1
<
<
Result Qual
1.0
1.0
NC Cenification Number: 25
Project Number: 61621.01
Report Date
Page 68 of 75
Matrix: GW/Chemw
RDL
.··o
.0
Units
mg/1
mg/1
March 24, 2004
Report ID: AB23157
Analyst
CBN
CBN
Date Time
03/01/2004 2316
03/02/2004 0518
Davis & Floyd, Inc. / PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
68
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Df\VIS
FLtfYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenijication Number: 25
Project Number: 61621.01
Report Date
Page 69 of 75
March 24, 2004
Report ID: AB23157
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG36924 Matrix GW/ChemW
MS/MSD MS04022601-0l:36924 Prep Method
MSD04022601-0l:36924 Analtyical Method: SW846 9060
ORGANIC CARBON, TOTAL 20.00 8.80 28.00 mg/1 96 74-125
ORGANIC CARBON, TOTAL 20.00 27.80 95 1 11 74-125
NOTE: MS/MSD t recoveries are not evaluated if the sample concentration is greater than four times the spike added.
.Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
69
Df\¥1S
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenijication Number: 25
Project Number: 61621.01
Report Date March 24, 2004
Page 70 of 75 Report ID, AB23157
QC Batch Report -Matrix Spikes and Duplicates
workGroup: WG36924 Matrix GW/Chemw
~MS/MSD MS04022601-ll:36924 Prep Method
MSD04022601-11:36924 Analtyical Method: SW846 9060
ORGANIC CARBON, TOTAL 20.00 ,:; 1.00 20. 40 mg/1 102
ORGANIC CARBON, TOTAL 20.00 21 . 40 mg/1 107 5 11 74-125
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. I PO Drawer 428 ] Greenwood, SC 29648 J 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
70
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DAYIS
FLtn'D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 2~152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date March 24, 2004
Page 71 of 75 Report ID: AB23157
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG3692'
LCS LCS36924:1
ORGANIC CARBON, TOTAL
ORGANIC CARBON, TOTAL
25 00
25 00
24 20
24 . 2 0
Matrix GW/ChemW
Prep Method
Analtyical Method: SW846 9060
mg/1
mg/1
98
97
90-110
90-110
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
71
Df\VIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certifica1ion Number: 25
Project Number: 61621.01
Report Date
Page 72 of 75
March 24, 2004
Report ID: AB23157
QC Batch Report -Batch Sample List
WorkGroup WG37172 Matrix GW/Chemw
.Description: Toc·GW Prep Method
Analtyical Method: SW846 9060
PREP ANALYTICAL
Sample ID Client ID Run# Date Time Date Timo Analyst
L04031504-01 K-28 1 03/19/2004 1109 CBN
L04 031504-05 V-23 1 03/19/2004 1140 CBN
MB37172: 1 Method Blank 1 03/19/2004 0518 CBN
MB37172:l Method Blank 2 03/19/2004 1423 CBN
LCS37172: 1 Laboratory Control Spike 1 03/19/2004 0436 CBN
LCS37172:1 Laboratory Control Spike 2 03/19/2004 1402 CBN
MS04031203-05:37172 Matrix Spike 1 03/19/2004 0330 CBN
MSD04031203 ➔05:37172 Matrix Spike Duplicate 1 03/19/2004 0352 CBN
Dilution
5
400
1
1
1
1
1
1
Davis & Floyd, lnc. I PO Drawer 428 j Greenwood, SC 29648 I 816 E. Durst Avenue j Greenwood, SC 29649 I (864} 229-4413 I Fax [phone]
72
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Dl\VIS
FLMD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
QC Batch Report -Method Blanks
WorkGroup: WG37172
Parameter
Wet Chemistry
SW846 9060
Blank
ORGANIC CARBON, TOTAL
ORGANIC CARBON, TOTAL
MB37172:l
Result Qual
1.0
1.0
NC Cenijication Number: 25
Project Number, 61621.01
Report Date
Page 73 of 75
Matrix: GW/ChemW
RDL Units
mg/1
mg/1
March 24, 2004
Report ID: AB23157
Analyst
CBN
CBN
Date Time
03/19/2004 0518
03/19/2004 1423
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
73
D~IS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenijication Number: 25
Project Number: 61621.01
Report Date March 24, 2004
Page 75 of 75 Report ID: AB23157
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG37172
LCS
ORGANIC CARBON, TOTAL
ORGANIC CARBON, TOTAL
LCS37l7.!:l
25 00
25 00
24 10
24. 10
Matrix GW/ChemW
Prep Method
Analtyical Method: SW846 9060
mg/1
mg/1
96
97
90-110
90-110
Davis & Floyd, Inc. I PO Drawer 428 j Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 j [phone] j Fax [phone]
74
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Df\YIS
FLffi1D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenijication Number: 25
Project Number: 51621.01
Report Date
Page 74 of 75
March 24, 2004
Report ID: AB23157
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG37172 Matrix GW/ChemW
MS/MSD MS04031203-05:37172 Prep Method
MSD04031203-05137172 Analtyical Method: SW846 9060
ORG.ANIC CARBON, TOTAL 20.00 10. 23 30.60 mg/1 102 74-125
ORGANIC CARBON, TOTAL 20.00 28. 70 92 6 11 74-125
NOTE: MS/MSD % recoveries are not evaluated if the sample concentration is greater than four times the spike added.
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
75
DAYIS
FLi1YD LABORATORY ANALYSIS REPORT
Method Conformance Summary
Client: Ticona, LLC
Log;n(s): L04030101, L04030402, L04030807, L04031504
Semi-Ethylene
Criteria Volatiles Volatiles Glvcol
Samn)e Holdine Time ✓ ✓ ✓
Standards Preparation ✓ ✓ ✓
Instrument Tunirnz ✓ ✓ NIA
Instrument Calibration ✓ ✓ ✓
Calibration Verification ✓ ✓ ✓
Degradation Check NIA NIA NIA
Interference NIA NIA NIA SamolelStandard
Blanks Results ✓ ✓ ✓
Method Accuracy ✓ ✓ ✓
Method Precision ✓ ✓ ✓
Surrogate Recovery ✓ ✓ NA
PDSISD/MSA NIA NIA NIA
TCLP Preparation NIA NIA NIA
Key ✓ = Met Criteria Met
NI A = Not Applicable
* = Method Criteria Not Met -Seefootnote(s} below.
PDS = Post Digestion Spike ·
SD = Serial Dilution
MSA = Method ofiStandard Additions
Footnotes:
Project Number: 61621.01·
Report Date: March 31, 2004
TOC
✓
✓
NIA
✓
✓
NIA
NIA
✓
✓
✓
NIA
NIA
NIA
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
76
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DAYIS
FLOYD
April 12, 2004
PEM CARTER
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Report ID : AB23275
Page 1 of 55
:L04022607
:61621.01
oz650-1451, r1\ •. ··.
[1,'•--.; .... '
I•!
: Ui JUN O 8 2004 / ,
LABORATORY AN~t'.Y§is~:Rfpcf~T
Login Number
Project Number
Description :Ql 2004 SLUDGE ANALYSIS FOR TCLP
Dear Pem Carter:
We are pleased to provide the enclosed analytical results for the samples received by
Davis & Floyd, Inc. on February 26, 2004. ·
A formal Quality Assurance/Quality Control program is maintained by Davis & Floyd,
which is designed to meet or exceed the EPA, NELAC or other appropriate regulatory
requirements. All analytical analyses for this project met QA/QC criteria and the
results are within the 99 % confidence interval for each method unless otherwise
stated in the footnotes. This report is to be reproduced only in full.
i
Feel free to contact our Client Services Representative at [phone] if further
explanation of the analysis is required. Unless other arrangements have been made,
samples will be disposed of or returned 14 days from the date of the report. We
appreciate the opportunity to provide services to your firm.
Sincerely,
DA~YD
n H. McCord, Jr.
Laboratory Manager
•
Davis & Floyd, Inc. I PO Drawer -428 I Greemvood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] 1 Fax [phone]
77
DAYIS
FLtrYD LABORATORY ANALYSIS REPORT
Client TICONA,LLC·
2525 BLACKSBURG ROAD
HWY 198
Contact
SHELBY, NC 28152
Pem Carter
Master Sample Tracking List
Sample ID Client ID
L04022607-01 SBR SLUDGE
Pesticides and Herbicides TCLP
SW846 1311/8081A
SW846 1311/B0BlA
SW846 1311/BlSlA
SW846 1311/BlSlA
SOJl'livolatile Organics TCLP
SW846 1311/8270C
Trace Metals TCLP
SW846 1311/6010B
SW846 l~ll/7470A
Volatile Organics TCLP
SW846 1311/8260B
L04022607•02 FP SLUDGE
Pesticides and Herbicides TCLP
5WB46 1311/B0BlA
SW846 1311/B0BlA
SW846 1311/BlSlA
SW846 1311/BlSlA
Semivolatile Organics TCLP
SW846 1311/8270C
Trace Metals TCLP
SW846 1311/6010B
SW846 1311/7470A
Volatile Organics TCLP
SW846 1311/8260B
SW846 1311/3510C
SWB46 1311/3510C
SW846 1311/BlSlA
SW846 1311/BlSlA
SW846 1311/JSOOA
SW846 3010
SW846 7470A
SW846 1311/3510C
SW846 1311/3510C
SW846 1311/BlSlA
$W846 1311/SlSlA
SW846 1311/3500A
SW846 3010
SW846 7470A
NC Cenification Number: 25
Project Number: 61621.01
Report Date
Page 2 of 55
Date Collected
03/16/2004 0830
03/17/2004 0930
03./17/2004 1130
03/17/2004 1130
03/03/2004 0900
03/03/2004 0915
03/04/2004 0900
ci2/25/2004 0940
03/16/2004 0830
03/17/2004 0930
03/17/2004 1130
03/17/2004 1130
03/03/2004 0900
03/03/2004 0915
03/04/2004 0900
April 12, 2004
Report ID: AB23275
Date Received
03/16/2004 2156
03/17/2004 2219
03/17/2004 1818
03/18/2004 1700
03/11/2004 1526
03/03/2004 1329
03/04/2004 1442
03/09/2004 1451
03/17/2004 0219·
03/18/2004 0240
03/17/2004 2051
03/18/2004 1828
03/11/2004 1721
03/03/2004 1358
03/04/2004 1450
03/09/2004 1543
Davis & Floyd, Inc. j PO Drawer 428 f Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I {864) 229-4413 I Fax [phone]
7 8 ·
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I DtA7IS FL ~YD LABORATORY ANALYSIS REPORT
I NC Certification Number: 25
I Client TICONA,LLC Project Number: 61621.01 I 2525 BLACKSBURG ROAD
I HWY 198
SHELBY, NC 28152 Report Date April 12, 2004
Contact Pem Carter Page 3 of 55 Report ID: AB23275
I Client ID: SBR SLUDGE Sample ID L04022607-01
Date Collected: 02/25/2004 0930
Matrix ' Leachate Date Received ' 02/26/2004
I Parameter Result Qual RDL Limit Units Analyst Date Time
Pesticides and Herbicides TCLP
I SW846 1311/B0BlA
CHLORDANE, TECI-mICAL < 0.0050 o.ooso 0.030 mg/1 JMT 03/17/2004 2219
CHLORDANE, TECHNICAL < 0.0050 0.0050 :0. 030 mg/1 JMT 03/16/2004 2156
ENDRIN < 0.00050 0. 00050 0.020 mg/1 JMT 03/17/2004 2219
I ENDRIN < 0. 00050_ 0.00050 0. 020 mg/1 JMT 03/16/2004 2156
HEPTACHLOR < 0.00050 0. 00050 0.010 mg/1 JMT 03/17/2004. 2219
HEPTACHLOR < 0. 00050 0. 00050 0. 010 mg/1 JMT 03/16/2004 2156
HEPTACHLOR EPOXIDE < 0.00050 0.00050 0.010 mg/l JMT 03/17/2004 2219 I HEPTACHLOR EPOXIDE < 0.00050 0.00050 0. 010 mg/1 JMT 03/16/2004 2156
LINDANE < 0.00050 0. 00050 0. 40 mg/1 JMT 03/17/2004 2219
LINDANE < 0.00050 0.00050 0. 40 mg/1 JMT 03/16/2004 2156
I METHOXYCHLOR < 0 0050 0.0050 10.0 mg/1 JMT 03/17/2004 2219
METHOXYCHLOR < 0. 0050 0.0050 10.0 mg/1 JMT 03/16/2004 2156
TOXAPHENE < 0 0050 0.0050 a.so mg/1 JMT 03/17/2004 2219
TOXAPHENE < o. 0050 0. 0050 a.so mg/1 JMT 03/16/2004 2156
I SW846 1311/BlSlA
2,4,5-TP (SILVEX) < 0. 0025 0 .0025 1.0 mg/1 JMT 03/18/2004 1700
2,4,5-TP (SILVEX) < o. 0025 0.0025 1.0 mg/1 JMT 03/17/2004 1818
2,4-D < 0.025 0.025 10.0 rng/l JMT 03/17/2004 1818 I 2,4-D < 0.025 0.025 10.0 mg/1 JMT 03/18/2004 1700
Semi volatile Organics TCLP
I SW846 1311/8270C
1,4-DICHLOROBENZENE < 0.10 0.10 7.5 mg/1 JRN 03/11/2004 1526
2,4,5-TRICHLOROPHENOL 0.10 0.10 400 mg/1 JRN 03/11/2004 1526
2,4,6-TRICHLOROPHENOL < 0.10 0.10 2.0 mg/1 JRN 03/11/2004 1526
I 2,4-DINITROTOLUENE < 0.10 0.10 0.13 mg/1 JRN 03/11/2004 1526
2-METHYLPHENOL ' 0.10 0.10 200 mg/1 JRN 03/11/2004 1526
3&4-METHYLPHENOL ' 0.10 0.10 200 mg/1 JRN 03/11/2004 1526
HEXACHLOROBENZENE < 0.10 0.10 0.13 mg/1 JRN 03/11/2004 1526 I HEXACHLOROBUTADIENE < 0.10 0.10 0.50 rng/1 JRN 03/11/2004 1526
HEXACHLOROETHANE ' 0.10 0.10 3.0 rng/l JRN 03/11/2004 1526
NITROBENZENE < 0.10 0.10 2.0 mg/l JRN 03/11/2004 1526
I PENTACHLOROPHENOL < 0 25 0. 25 100 mg/1 JRN 03/11/2004 1526
PYRIDINE < 0.10 0.10 5.0 mg/1 JRN 03/11/2004 1526
Trace Metals TCLP
I SW846 1311/6010B
ARSENIC, TOTAL < 0.20 0.20 5.0 mg/1 BDL 03/03/2004 1329
BARIUM, TOTAL 0.21 0.20 100 mg/1 BDL 03/03/2004 1329
CADMIUM, TOTAL < 0.050 0.050 1. 0 mg/1 BDL 03/03/2004 1329 I Davis & Floyd, Inc. \ PO Drawer 428 ! Greenwood, SC 29648 I 816 E. Durst Avenue Greenwood, SC 29fi49 I 18641229.4413 I Fax [phone]
79
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
Client ID: SBR SLUDGE
Para.Il1oter
CHROMIUM, TOTAL
LEAD, TOTAL
SELENIUM, TOTAL
SILVER, TOTAL
SW846 1Jll/7470A
MERCURY, TOTAL
Matrix
Volatile Organics TCLP
SW846 1311/8260B
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
2-BUTANONE
BENZENE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROFORM
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
Prep Procedure
Analytical Prep Procedures:
TCLP EXTRACTION
ZHE EXTRACTION
TCLP EXTRACTION
TCLP SEMI VOLATILES
TCLP PESTICIDES
TCLP PESTICIDES
TCLP HERBICIDES
TCLP HERBICIDES
METALS PREP ICP
METALS PREP HG
Leachate
Result
< 0.10
< o.oso
< 0.10
< 0.10
< 0.002~
< 0.050
< o.oso
< 0.10
< 0.050
< 0.050
< 0.050
< 0.050
< 0.050
< 0.050
< 0.10
Method
SWB46 1311
SW846 1311
SW846 1311
SW846 1311/3500A
SW846 1311/3510C
SW846 1311/3510C
SW846 1311/BlSlA
SW846 1311/8151A
SW846 3010
SW846 7470A
Qual
X
X
X
X
X
X
X
X
X
X
Analyst
MCR
DBC
MCR
DBC
MCR
MCR
MCR
MCR
BDL
ACW
RDL
0 .10
0. 050
0.10
0.10
0. 002 0
o.oso
0.050
0.10
0.050
0.050
0. 050
0.050
0 .oso
0. 050
0.10
NC Cenijicaiion Number: 25
Project Number: 61621.01
Report Date
Page 4 of 55
April 12, 2004
Report ID: AB23275
Sample ID L04022607-01
Date Collected: 02/25/2004 0930
Date Received: 02/26/2004
Limit Units Analyst
5.0 mg/1 BDL
5.0 mg/1 BDL
1.0 mg/1 BDL
5.0 mg/1 BDL
0.20 mg/1 ACW
0.70 mg/1 PAP
0.50 mg/1 PAP
200 mg/1 PAP
0.50 mg/1 PAP
a.so mg/1 PAP
100 mg/1 PAP
6.0 mg/1 PAP
0.70 mg/1 PAP
0.50 mg/1 PAP
0.20 mg/1 PAP
Prep Date
03/16/2004 1530
03/04/2004 0900
03/02/2004 1500
03/03/2004 0900
03/17/2004 0930
03/16/2004 0830
03/17/2004 1130
03/16/2004 1020
03/03/2004 0915
03/04/2004 0900
Date
03/03/2004
03/03/2004
03/03/2004
03/03/2004
03/04/2004
03/09/2004
03/09/2004
03/09/2004
03/09/2004
03/09/2004
03/09/2004
03/09/2004
03/09/2004
03/09/2004
03/09/2004
Time
1329
132 9
1329
1329
1442
1451
1451
1451
1451
1451
1451
1451
1451
1451
1451
Davis & Floyd, Jnc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] j Fax {864) 229-7119
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FLfwD LABORATORY ANALYSIS REPORT
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Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
Client ID: FP SLUDGE
Matrix Leachate
Parameter
Pesticides and Herbicides TCLP
SW846 1311/B0BlA
CHLORDANE, TECHNICAL
CHLORDANE, TECHNICAL
ENDRIN
ENDRIN
HEPTACHLOR
HEPTACHLOR
HEPTACHLOR EPOXIDE
HEPTAOU,OR EPOXIDE
LINDANE
LINDANE
METHOXYCHLOR
METHOXYCHLOR
TOXAPHENE
TOXAPHENE
SW846 1311/BlSlA
2,4,5-TP (SILVEX)
2,4,5-TP (SILVEX)
2,4-D
2,4-D
Semivolatile Organics TCLP
SW846 1311/8270C
1,4-DICHLOROBENZENE
2,4,5-TRICHLOROPHENOL
2,4,6-TRICHLOROPHENOL
2,4-0INITROTOLUENE
2-METHYLPHENOL
3 &4 -METHYL PHENOL
HEXACHLOROBENZENE
HEXACHLOROBUTADIENE
HEXACHLOROETHANE
NITROBENZENE
PENTACHLOROPHENOL
PYRIDINE
Trace Metals TCLP
SW846 1311/6010B
ARSENIC, TOTAL
BARIUM, TOTAL
CADMIUM, TOTAL
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
Result Qual
0.0050
0.0050
0.00050
0. 00050
0. 00050
0. 00050
0. 00050
0.00050
0. 00050
0.00050
0.0050
0.0050
0.0050
0 0050
0.0025
0.0025
0 025
0.025
0.10
0.10
0 .10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.25
0.10
0.20
LS
0.050
RDL
0.0050
0.0050
0.00050
0.00050
0.00050
0.00050
0.00050
0.00050
0. 00050
0.00050
0.0050
0.0050
0 0050
0.0050
0.0025
0.0025
0 025
0.025
0.10
0. 10
0.10
0.10
0.10
0.10
0. 10
0.10
0.10
0.10
0.25
0.10
0.20
0.20
0.050
loavis & Floyd, Inc. I PO Drawer 428 Greenwood, SC 29648 I 816 E. Durst Avenue
81
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 5 of 55
April 12, 2004
Report ID: AB23275
Sample ID L04022607-02
Date Collected: 02/25/2004 0940
Date Received: 02/26/2004
Limit
0. 030
p-030
0.020
0 020
0.010
0.010
0. 010
0.010
0.40
0.40
10.0
10.0
0.50
0.50
1. 0
1.0
10 0
10.0
7.5
400
2.0
0.13
200
200
0.13
a.so
3.0
2.0
100
s.o
5.0
100
1.0
Units
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/!
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
r,ng/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
Analyst
JMT
JMT
JMT
JMT
JMT
JMT
JMT
JMT
JMT
JMT
JMT
JMT
JMT
JMT
JMT
JMT
JMT
JMT
JRN
JRN··
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
BDL
BDL
BDL
Date Ti.me
03/18/2004 0240
03/17/2004 0219
03/18/2004·0240
03/17/2004 0219
03/18/2004 0240
03/17/2004 0219
03/18/2004 0240
03/17/2004 0219
03/18/2004 0240
03/17/2004 0219
03/18/2004 0240
03/17/2004 0219
03/18/2004 0240
03/17/2004 0219
03/18/2004 1828
03/17/2004 2051
03/18/2004 1828
03/17/2004 2051
03/11/2004 1721
03/11/2004 1721
03/11/2004 1721
03/11/2004 1721
03/11/2004 1721
03/11/2004 1721
03/11/2004 1721
03/11/2004 1721
03/11/2004 1721
03/11/2004 1721
03/11/2004 1721
03/11/2004 1721
03/03/2004 1358
03/03/2004 1358
03/03/2004 1358
G,eenwood. SC 29649 I [phone] I Fax [phone]
DAYIS
FLtfYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
Client rn •. FP SLUDGE
Parameter
CHROMIUM, TOTAL
LEAD, TOTAL
SELENIUM, TOTAL
SILVER, TOTAL
SW846 1311/7470A
MERCURY, TOTAL
Matrix
Volatile Organics TCLP
SW846 1311/8260B
1,1-0ICHLOROETHENE
1,2-DICHLOROETHANE
2-BUTANONE
BENZENE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROFORM
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
Prop Procedure
Analytical Prep Procoduros1
TCLP EXTRACTION
ZHE EXTRACT! ON
TCLP EXTRACTION
TCLP SEMIVOLATILES
TCLP PESTICIDES
TCLP PESTICIDES
TCLP HERBICIDES
TCLP HERBICIDES
METALS PREP ICP
METALS PREP HG
Leachate
Result
< 0.10
< 0.050
< 0. 10
< 0. 10
< 0.002Q
< 0.050
< 0.050
< 0.10
< 0.050
< 0. 050
< 0.050
< 0.050
< 0. 050
< 0. 050
< 0 .10
Method
SW846 1311
SW846 1311
SW846 1311
SW846 1311/3500A
SW846 1311/3510C
SW846 1311/3510C
SW846 1311/8151A
SW846 1311/8151A
SW846 3010
SW846 7470A
Qual
X
X
X
X
X
X
X
X
X
X
Analyst
MCR
DBC
MCR
DBC
MCR
.MCR
MCR
MCR
BDL
ACW
RDL
0.10
0. 050
0.10
0.10
0.0020
0.050
0. 050
0.10
0.050
0. 050
0.050
o.oso
0. 050
0. 050
0.10
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 6 of 55
April 12, 2004
Report ID: AB23275
Sample ID L04022607-02
Date Collected: 02/25/2004 0940
Date Received: 02/26/2004
Limit Units Analyst
5.0 mg/1 BDL
5.0 mg/1 BDL
1.0 mg/1 BDL
5.0 mg/1 BDL
0.20 mg/1 ACW
0.70 mg/1 PAP
0.50 mg/1 PAP
200 mg/1 PAP
0.50 mg/1 PAP
a.so mg/1 PAP
100 mg/1 PAP
6.0 mg/1 PAP
0.70 mg/1 PAP
a.so mg/1 PAP
0.20 mg/1 PAP
Prep Date
03/16/2004 1530
03/04/2004 0900
03/02/2004 1500
03/03/2004 0900
03/17/2004 0930
03/16/2004 0830
03/17/2004 1130
03/16/2004 1020
03/03/2004 0915
03/04/2004 0900
Date Time
0)/03/2004 13 58
03/03/2004 1358
03/03/2004 1358
03/03/2004 1358
03/04/2004 1450
03/09/2004 1543
03/09/2004 1543
03/09/2004 1543
03/09/2004 1543
03/09/2004 1543
03/09/2004 1543
03/09/2004 1543
03/09/2004 1543
03/09/2004 1543
03/09/2004 1543
Davis & Floyd, Inc. / PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I (8&4) 229-4413 I Fax [phone]
82
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DAYIS
FLtWD
Client
LABORATORY ANALYSIS REPORT
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
NC Cenification Number: 25
Project Number: 61621.01
Contact Pem Carter
Report Date
Page 7 of 55
April 12, 2004
Report ID: AB23275
QC Summary Data
•
Davis & Floyd, Inc. I PO Dr.1wer 428 I Greenwood, SC 29648 I 816 E. Ours! Avenue I Greenwood, SC 29649 / [phone] I Fax [phone]
83
Di\YIS
FLtWD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pern Carter
NC Cenification Number: 25
Project Number: 61621.01
Report Date
Page B of ss
April 12, 2004
Report ID: AB23275
,QC Batch Report -Batch Sample List
WorkGroup WG36955 Matrix Leachate
Description: op/tclp/zhe Prep Method
Analtyical Method: SW846 1311/82608
PREP ANALYTICAL
Sample ID Client ID Run# Date Time Date Time Analyst
L04022607-0l SBR SLUDGE 1 03/09/2004 1451 PAP
L04022607-02 FP SLUDGE 1 03/09/2004 1543 PAP
MB36955: 1 Method Blank 1 03/09/2004 1432 PAP
LCS36955:l Laboratory Control Spike 1 03/09/2004 1636 PAP
MS04022607-01 ·36955 Matrix Spike 1 03/09/2004 1508 PAP
MS04022607-02 36955 Matrix Spike 1 03/09/2004 1601 PAP
MSD04022607-0l,369SS Matrix Spike Duplicate l 03/09/2004 1526 PAP
MSD04022607-02,36955 Matrix Spike Duplicate 03/09/2004 1618 PAP
Dilution
10
10
1
1
10
10
10
10
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 ! [phone] ! Fc1x {864) 229-7119
84
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DAYIS
FLfWD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 9 of 55
April 12, 2004
Report ID: AB23275
QC Batch Report -Surrogates % Recovery
WorkGroup: WG36955 Matrix Leachate
Prep Method
Analtyical Method: SW846 1311/82608
L04022607-01 03/09/2004 1451 99 98 102
L04022607-02 03/09/2004 1543 99 95 100
M836955:l 03/09/2004 1432 100 99 101
LCS36955:1 03/09/2004 1636 102 98 101
MS04022607-01:36955 03/09/2004 1508 106 100 102
'MS04022607-02:36955 03/09/2004 1601 106 100 101
MS004022607-01:36955 03/09/2004 1526 107 100 102
MS004022607-02:36955 03/09/2004 1618 107 100 100
DCE 1,2-DICHLOROETHANE-D4
BFB BROMOFLUOROBENZENE
TOL TOLUENE-DB
tavis & Floyd, Inc. / PO Drawer 428 j Greenwood, SC 29648 I 81 b E. Durst Avenue / Greenwood, SC 29649 I (864) 229~4413 I Fax (864) 229~7119
85
DAYIS
FLtJYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
QC Batch Report -Method Blanks
. WorkGroup: WG36955
::Blank MB36955:l
Parameter Result Qual RDL
Volatile Organics TCLP
SW846 13ll/8260B
1,1-DICHLOROETHENE ' 0.0050 0.0050
1,2-DICHLOROETHANE ' 0.0050 0.0050
2-BUTANONE ' 0.010 0.010
BENZENE ' 0. 0050 0.0050
CARBON TETRACHLORIDE ' 0.0050 0.0050
CHLOROBENZENE ' 0.0050 0.0050
CHLOROFORM ' 0.0050 0.0050
TETRACHLOROETHENE ' 0.0050 0.0050
TRICHLOROETHENE ' 0.0050 0.0050
VINYL CHLORIDE ' 0.010 0. 010
Prep Procedure Method Analyst
Analytical Frap Procedures:
ZHE EXTRACTION ~W84 6 1311 DBC
NC Cenijication Number: 25
Project Number: 61621.01
Report Date April 12, 2004
Page 10 of 55 Report ID: AB23275
Matrix: Leachate
Limit Vnits Analyst Date
0.70 mg/1 PAP 03/09/2004
0.50 mg/1 PAP 03/09/2004
200 mg/1 PAP 03/09/2004
a.so mg/1 PAP 03/09/2004
a.so mg/1 PAP 03/09/2004
100 mg/1 PAP 03/09/2004
6.0 mg/1 PAP 03/09/2004
0.70 mg/1 PAP 03/09/2004
a.so mg/1 PAP 03/09/2004
0.20 mg/1 PAP 03/09/2004
Prep Date
03/04/2004 0900
Time
1432
1432
1432
1432
1432
1432
1432
1432
1432
1432
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue 1 Greenwood, SC 29649 I [phone] I Fax [phone]
86 ·
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 11 of 55
April 12, 2004
Report ID: AB23275
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG36955
MS/MSD MS04022607-01:36955
MSD04022607-0l:36955
l,l~DICHLOROETHENE o.soo ' 0 .0500
1,2-DICHLOROETHANE 0.500 ' 0 .0500
2-BtrrANONE 0.500 < 0.100
BENZENE o.soo < 0.0500
CARBON TETRACHLORIDE o.soo ' 0.0500
CHLOROBENZENE 0 .500 ' 0.0500
CHLOROFORM 0 .500 < 0.0500
TETRACHLOROETHENE o. 500 < 0.0500
TRICHLOROETHENE o. 500 < 0.0500
VINYL CHLORIDE 0. 500 < 0.100
1,1-DICHLOROETHENE o. 500 0 .595
1,2-DICHLOROETHAflE 0 .500 0 .557
2-BUTANONE o. 500 o. 632
BENZENE 0 .500 0. 515
CARBON TETRACHLORIDE 0 .500 0.530
CHLOROBENZENE 0 .500 o.soo
CHLOROFORM 0.500 0. 510
TETRACHLOROETHENE 0.500 0.501
TRICHLOROETHENE 0. 500 0. 522
VINYL CHLORIDE 0.500 0.503
Matrix Leachate
Prep Method
Analtyical Method: SW846 1311/82608
0. 593 mg/1
0 . 548 mg/1
0 . 649 mg/1
0 .516 mg/1
0.536 mg/1
0. 507 mg/1
0. 506 rng/1
0 .513 mg/1
0.525 mg/1
0.521 mg/1
mg/1 119
mg/1 111
mg/1 126
mg/1 103
mg/1 106
mg/1 100
mg/1 102
mg/1 100
mg/1 104
mg/1 101
119
110
130
103
107
101
l 01
103
105
104
0
2
3
0
2
1
3
66-134
82-126
30-190
81-117
71-129
77-123
81-119
72-126
77-119
45-144
14 66-134
13 82-126
30 30-190
10 81-117
13 71-129
11 77-123
10 81-119
15 72-126
11 77-119
21 45-144
NOTE: MS/MSD, recoveries are not evaluated if the sample concentration is greater than four times the spike added.
t,wis & Floyd, lnc. I PO Drawer 428 I Greenwood, SC 29648 ! 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
87
DAYIS
FLtfYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
NC Cenification Number: 25
Project Number: 61621.01
Report Date
Page 12 of 55
April 12, 2004
Report ID: AB23275
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG36955 Matrix Leachate
·MS/MSD MS04022607-02:36955 Prep Method
MSD0(022607-02:36955 Analtyical Method: SW846 1311/82608
1, l-DICHLOROETHENE 0. 500 <: 0.0500 0.592 mg/1 118 66-134
1,2-DICHLOROETHANE 0.500 < o.osoo o.sJ9 mg/1 114 82-126
2-BUTANONE 0. 500 < 0.100 0.586 mg/1 117 30-190
BENZENE 0.500 'o. 0500 0.529 mg/1 106 81-117
CARBON TETRACHLORIDE 0.500 ' o. 0500 0. 518 mg/1 104 71-129
CHLOROBENZENE 0.500 < 0.0500 0. 517 mg/1 103 77-123
CHLOROFORM 0. 500 < 0.0500 0.524 mg/1 105 81-119
TETRACHLOROETHENE 0.500 < o.osoo 0.509 mg/1 102 72-126
TRICHLOROETHENE 0.500 < 0.0500 0 528 mg/1 106 77-119
VINYL CHLORIDE 0.500 < 0.100 0. 482 mg/1 96 45-144
1,1-DICHLOROETHENE 0 500 0. 552 mg/1 110 7 14 66-134
1,2-DICHLOROETHANE 0 500 0. 540 mg/1 108 5 13 82-126
2-BUTANONE 0 500 0.608 mg/1 122 4 30 30-190
BENZENE 0 500 0.504 mg/1 101 5 10 81-117
CARBON TETRACHLORIDE 0 .500 0. 494 mg/1 99 5 13 71-129
CHLOROBENZENE 0 500 0.490 mg/1 98 5 11 77-123
CHLOROFORM 0 500 0.506 mg/1 101 4 10 81-119
TETRACHLOROETHENE 0 .500 0 .487 mg/1 97 4 15 72-126
TRICHLOROETHENE 0 500 0 499 mg/1 100 6 11 77-119
VINYL CHLORIDE 0.500 0 . 461 mg/1 92 5 21 45-144
NOTE1 MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. ! PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
88
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DA~IS
FLMD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenification Number: 25
Project Number: 61621.01
Report Date
Page 13 of 55
April 12, 2004
Report ID: AB23275
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG36955 Matrix Leachate
LCS LCS369SS:l Prep Method
Analtyical Method: SW846 1311/8260B
1, FDICHLOROETHENE 0.0200 0.0251 mg/1 126 64-130
1,2-DICHLOROETHANE 0. 0200 0.0234 mg/1 117 85-128
2-BUTANONE 0.0200 0. 0240 mg/1 120 42-194
BENZENE 0.0200 0.0226 mg/1 113 81-117
CARBON TETRACHLORIDE 0.0200 0.0215 mg/1 108 57-129
CHLOROBENZENE 0.0200 0.0222 mg/1 111 82-122
CHLOROFORM 0.0200 0.0222 mg/1 111 83-119
TETRACHLOROETHENE 0. 0200 0.0218 mg/1 109 74-119
TRICHLOROETHENE 0.0200 0.0229 mg/1 115 78-117
VINYL CHLORIDE 0.0200 0.0223 mg/1 111 48-134
I Davis & Floyd, Jnc. I PO Drawer 428 I Greenwood. SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 / [phone] ! Fax [phone]
89
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.~l
Report Date April 12, 2004
Page 14 of 55 Report ID: AB23275
QC Batch Report -Batch Sample List
WorkGroup WG36938 Matrix Leachate
:.Description: sv/tclp Prep Method SW846 1311/JSOOA
Analtyical Method: SW846 1311/8270C
PREP ANALYTICAL
Sample ID Client ID Run# Date Time Date Time Analyst
L04022607-0l ·SBR SLUDGE 03/03/2004 0900 03/11/2004 1526 JRN
L04022607-01 SBR SLUDGE 2 03/03/2004 0900 03/11/2004 1526 JRN
L04022607-02 FP SLUDGE 03/03/2004 0900 03/11/2004 1721 JRN
L04022607-02 FP SLUDGE 2 03/03/2004 0900 03/11/2004 1721 JRN
MB36938:l Method Blank 1 03/03/2004 0900 03/11/2004 1408 JRN
MB36938:l Method Blank 2 03/03/2004 0900 03/11/2004 1408 JRN
LCS36938:l Laboratory Control Spike 03/03/2004 0900 03/11/2004 1447 JRN
LCS36938:l Laboratory Control Spike 2 03/03/2004 0900 03/11/2004 1447 JRN.
MS04022607-01:36938 Matrix Spike 1 03/03/2004 0900 03/11/2004 1604 JRN
MS04022607-01:36938 Matrix Spike 2 03/03/2004 0900 03/11/2004 1604 JRN
MS04022607-02:36938 Matrix Spike 03/03/2004 0900 03/11/2004 1759 JRN
MS04022607-02:36938 Matrix Spike 2 03/03/2004 0900 03/11/2004 1759 JRN
MSD04022607-01:36938 Matrix Spike Duplicate 1 03/03/2004 0900 03/11/2004 1642 JRN
MSD04022607-01:36938 Matrix Spike Duplicate 2 03/03/2004 0900 03/11/2004 1642 JRN
MSD04022607-02:36938 Matrix Spike Duplicate 1 03/03/2004 0900 03/11/2004 1837 JRN
MSD04022607-02:36938 Matrix ~pike Duplicate 2 03/03/2004 0900 03/11/2004 1837 JRN
Dilution
1
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue ) Greenwood, SC 29649 I [phone] I Fax [phone]
90
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DAYIS
FLtlYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenijication Number: 25
Project Number: 61621.01
Report Date April 12, 2004
Page 15 of 55 Report ID: AB23275
QC Batch Report -Surrogates % Recovery
WorkGroup: WG36938 Matrix Leachate
Prep Method SW846 1311/JSOOA
Analtyical Method: SW846 1311/8270C
L04022607-01 03/11/2004 1526 80 78 51 84 30
L04022607-02 03/11/2004 1721 92 85 50 76 30
MB36938: 1 03/11/2004 1408 80 79 54 73 33
LCS36938:l 03/11/2004 1447 90 86 54 76 35
MS04022607-01 , 36938 03/11/2004 1604 86 " 51 90 31
MS04022607-02: 36938 03/11/2004 1759 94 85 54 84 31
MSD04022607-0l:36938 03/11/2004 1642 87 81 53 85 34
MSD04022607-02:36938 03/11/2004 1837 87 82 49 78 31
TBP 2,4,6-TRIBROMOPHENOL
FBP 2-FLUOROBIPHENYL
2SP 2 -FLUOROPHENOL
NBZ NITROBENZENE-D5
PHL PHENOL-D5
r•wis & Floyd, Inc. I PO Drawer 428 l Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] 1 Fax [phone]
91
DAYIS
FLbYD
Client
Contact
LABORATORY ANALYSIS REPORT
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 16 of 55
April 12, 2004
Report ID: AB23275
QC Batch Report -Method Blanks
WorkGroup: WG36938 Matrix: Leachate
·'.'Blank MB3693B:l
Parameter Result Qual RDL Limit Units Analyst Date
Semi volatile Organics TCLP
SW846 1311/8270C
1,4-DICHLOROBENZENE < 0.10 0.10 7.5 rng/1 JRN 03/11/2004
2,4,5-TRICHLOROPHENOL < o. 10 0 .10 . 400 mg/1 JRN 03/11/2004
2,4,6-TRICHLOROPHENOL < o. 10 0.10 2.0 mg/1 JRN 03/11/2004.
2,4-DINITROTOLUENE < o. 10 0.10 0.13 mg/1 JRN 03/11/2004
2-METHYLPHENOL < 0 .10 0.10 200 mg/1 JRN 03/11/2004
3&4-METHYLPHENOL < o. 10 0.10 200 mg/1 JRN 03/11/2004
HEXACHLOROBENZENE < 0.10 0.10 0.13 mg/1 JRN 03/11/2004
HEXACHLOROBUTADIENE < 0 .10 0.10 0.50 mg/1 JRN 03/11/2004
HEXACHLOROETHANE < 0.10 0.10 3.0 mg/1 JRN 03/11/2004
NITROBENZENE < o. 10 0.10 2.0 mg/1 JRN 03/11/2004
PENTACHLOROPHENOL < 0 . 25 0.25 100 mg/1 JRN 03/11/2004
PYRIDINE < o. 10 0.10 5.0 mg/1 JRN 03/11/2004
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
TCLP SEMIVOLATILES SW846 1311/3500A DBC 03/03/2004 0900
Time
1408
1408
1408
1408
1408
1408
1408
1408
1408
1408
1408
1408
Davis & Floyd. Inc. I PO Drawer 428 I Greenwood. SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I {864) 229-4413 I Fax [phone]
92
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DAYIS
FLt1YD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 17 of 55
April 12, 2004
Report ID: AB23275
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG36938
MS/MSO MS0(022607-01:36938
MSD04022607-0l:36938
1,4-DICHLOROBENZENE 0.500 ' 0 .100
2,4,5-TRICHLOROPHENOL 1 .oo ' 0 .100
2,4,6-TRICHLOROPHENOL l . 00 '0 . 100
2,4-DINITROTOLUENE 0.500 < 0.100
2-METHYLPHENOL 1.00 < 0.100
3&4-METHYLPHENOL 2.00 ' 0 .100
HEXACHLOROBENZENE o.soo ' 0 .100
HEXACHLOROBUTADIENE 0.500 'o. 100
HEXACHLOROETHANE 0.500 < 0.100
NITROBENZENE 0.500 < 0.100
PENTACHLOROPHENOL 1.00 < 0.250
PYRIDINE 0.500 < 0.100
1,4-DICHLOROBENZENE 0.500 0 . 368
2,4,5-TRICHLOROPHENOL 1.00 o. 928
2,4,6-TRICHLOROPHENOL 1 .oo 0.884
2,4-DINITROTOLUENE 0 .500 0. 381
2-METHYLPHENOL 1.00 o. 718
3&4-METHYLPHENOL 2.00 1.18
HEXACHLOROBENZENE 0. 500 0.421
HEXACHLOROBUTADIENE 0 .500 0.362
HEXACHLOROETHANE 0 .500 0.330
NITROBENZENE 0. 500 0. 390
PENTACHLOROPHENOL 1. 00 1 . 01
PYRIDINE 0 . 500 0 . 179
Matrix Leachate
Prep Method SW846 1311/JSOOA
Analtyical Method: SW846 1311/8270C
0 .348 mg/1
1. 05 mg/1
0. 984 mg/1
0 .413 mg/1
0 .627 mg/1
1. 06 mg/1
0 . 436 mg/1
0 .373 mg/1
0 .328 mg/1
0.390 mg/1
1.03 mg/1
0.160 mg/1
mg/1 74
mg/1 93
mg/1 BB
mg/1 76
mg/1 72
mg/1 59
mg/1 84
mg/1 72
mg/1 66
mg/1 78
mg/1 101
mg/1 36
70
105
98
83
63
53
87
75
66
78
103
32
6
13
11
8
13
11
0
2
11
30-79
45-101
40-101
52-96
25-107
2 9-83
36-118
24-87
27-79
42-105
31-133
11-73
27 30-79
2B 45-101
29 40-101
27 52-96
27 25-107
2B 29-83
22 36-118
36 24-87
31 27-79
25 42-105
29 31-133
37 11-73
NOTE: MS/MSD % recoveries are not evaluated if the sample concentration is greater than four times the spike added.
.Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] ! Fax [phone]
93
DAYIS
FLt1YD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 18 of 55
April 12, 2004
Report ID: AB23275
.QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG36938 Matrix Leachate
0MS/M8D MS0.f.022607-02:36938 Prep Method SW846 1311/JSOOA
MSD04022607-02:36938 Analtyical Method: SW846 1311/8270C
1, 4 '-DICHLOROBENZENE 0.500 < 0.100 0 .345 mg/1 69 30-79
2,4,5-TRICHLOROPHENOL 1.00 'o. 100 0. 98~ mg/1 98 45-101
2,4,6-TRICHLOROPHENOL 1.00 < 0 100 o. 897 mg/1 90 40-101
2,4-DINITROTOLUENE 0.500 < 0 .100 0. 380 mg/1 76 52-96
2-METHYLPHENOL 1.00 < o. 100 0 673 mg/1 67 25-107
3&4-METHYLPHENOL 2.00 < 0. 100 . 18 mg/1 59 29-83
HEXACHLOROBENZENE 0.500 < 0.100 0 .455 mg/1 91 36-118
HEXACHLOROBUTADIENE 0.500 'o. 100 0. 356 mg/1 71 24-87
HEXACHLOROETHANE 0. 500 < 0. 100 0.332 mg/1 66 27-79
NITROBENZENE 0.500 < o. 100 0 . 394 mg/1 79 42-105
PENTACHLOROPHENOL 1.00 < 0 250 . 03 mg/1 103 31-133
PYRIDINE 0. 500 < 0.100 o. 142 mg/1 28 11-73
1,4-DICHLOROBENZENE 0.500 0. 318 mg/1 64 8 27 3 0-7 9
2,4,5-TRICHLOROPHENOL 1.00 0. 955' mg/1 97 2 28 45-101
2, 4; 6-TRICHLOROPHENOL 1.00 0. 875 mg/1 87 2 29 40-101
2,4-DINITROTOLUENE 0.500 0.391 mg/1 78 3 27 52-96
2-METHYLPHENOL 1.00 0.631 mg/1 63 6 27 25-107
3&4-METHYLPHENOL 2.00 1.11 mg/1 56 6 28 29-83
HEXACHLOROBENZENE 0.500 0. 457 mg/1 91 0 22 36-118
HEXACHLOROBUTADIENE 0 .500 0.358 mg/1 72 1 36 24-87
HEXACHLOROETHANE 0. 500 0. 354 mg/1 71 7 31 27-79
NITROBENZENE 0. 500 0.372 mg/1 74 6 25 42-105
PENTACHLOROPHENOL 1.00 1. 01 mg/1 101 2 29 31-133
PYRIDINE 0.500 o. 162 mg/1 32 13 37 11-73
NOTE1 MS/MSD % recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
94 ·
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Di\.VIS
FLtfYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 19 of ss
April 12, 2004
Report ID: AB23275
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG36938 Matrix Leachate
LCS LCS36938:l Prep Method SWB46 1311/JSOOA
Analtyical Method: SW846 1311/8270C
l,4~DICHLOROBENZENE 0.500 0. 322 mg/1 64 20-91
2,4,5-TRICHLOROPHENOL 1.00 0.929 mg/1 93 27-104
2,4,6-TRICHLOROPHENOL 1.00 0 859 mg/1 86 19-104
2,4-DINITROTOLUENE 0.500 0 .376 mg/1 75 36-106
2-METHYLPHENOL 1.00 0 717 mg/1 72 25-107
3&4-METHYLPHENOL 2.00 1 22 mg/1 61 27-84
HEXACHLOROBENZENE 0. 500 0. 439 mg/1 88 39-112
HEXACHLOROBUTADIENE 0. 500 0 .275 mg/1 55 1B-89
HEXACHLOROETHANE 0.500 0.288 mg/1 SB 16-90
NITROBENZENE 0. 500 0 .355 mg/1 71 20-122
PENTACHLOROPHENOL 1.00 0 688 mg/1 69 1-92
PYRIDINE 0. 500 0 236 mg/1 47 11-77
.Davis & Floyd, Inc. I PO Drc1wer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 ) (864} 229-4413 I Fax [phone]
95
DAYIS
FLffi'D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 20 of 55
April 12, 2004
Report ID: AB23275
QC Batch Report -Batch Sample List
WorkGroup WG37104 Matrix Leachate
.,Description: PS/PEST --0316XP Prep Method SW846 1311/3510C
Analtyical Method: SW846 1311/SOSlA
PREP ANALYTICAL
Sample ID Client ID Run# Date Time Date Time Analyst
L04022607-01 -SBR SLUDGE 1 0J/1Ghoo4 0830 03/16/2004 2156 JMT
L04022607-02 FP SLUDGE 1 03/16/2004 0630 03/17/2004 0219 JMT
MB37104: 1 Method Blank 1 03/16/2004 0830 03/16/2004 2042 JMT
LCS37104: 1 Laboratory Control Spike 1 03/16/2004 0830 03/16/2004 2119 JMT
MS04022607-01:37104 Matrix Spike 1 03/16/2004 0830 03/16/2004 2234 JMT
MS04022607-02:37104 Matrix Spike 1 03/16/2004 0830 03/17/2004 0257 JMT
MSD04022607-01:37104 Matrix Spike Duplicate 1 03/16/2004 0830 03/16/2004 2312 JMT
MSD04022607-02:37104 Matrix Spike Duplicate 1 03/16/2004 0830 03/17/2004 0334 JMT
Dilution
1
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1
Davis & Floyd, lnc. I PO Dravver 428 / Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I (864) 229-441 J J Fax [phone]
9 6:
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DA~IS
FLiWD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
NC Cenijication Number: 25
Project Number: 61621.01
Report Date
Page 21 of 55
April 12, 2004
Report ID: AB23275
QC Batch Report -Surrogates % Recovery
WorkGroup: WG37104 Matrix Leachate
Prep Method SW846 1311/3510C
Analtyical Method: SW846 1311/SOBlA
L04022607-01 03/16/2004 2156 71 68
L04022607-02 03/17/2004 0219 77 66
M837104: 1 03/16/2004 2042 71 67
LCS37104:1 03/16/2004 2119 71 74
MS04022607-01:37104 03/16/2004 2234 75 67
MS04022607-02:37104 03/17/2004 0257 82 78
MSD04022607-01:37104 03/16/2004 2312 76 70
MSD04022607-02:37104 03/17/2004 0334 82 72
DCB DECACHLOROBIPHENYL
TCX TETRACHLORO-M-XYLENE
ravis & Floyd, Inc. I PO Dr,1wer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I (B64) 229-44 l 3 I Fax [phone]
97
DAYIS
FLMD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
QC Batch Report -Method Blanks
WorkGroup: WG37104
"Blank MB37104:1
Para.meter
Posticides and Herbicides TCLP
SW846 1311/BOBlA
CHLORDANE, TECHNICAL
ENORIN
HEPTACHLOR
HEPTACHLOR EPOXIDE
LINDA.NE
METHOXYCHLOR
TOXAPHENE
<
<
<
<
<
<
<
Prep Procedure Method
Result Qual RDL
0.0050 0.0050
0.00050 0.00050
0.00050 0. 00050
0.00050 0. 00050
0.00050 0.00050
0.0050 0.0050
o. 0050 0.0050
Aualyst
Analytical Prep Proceduresz
TCLP PESTICIDES SW846 1311/)SlOC MCR
NC Certification Number: 25
Project Number: _61621.01
Report Date
Page 22 of 55
Matrix: Leachate
April 12, 2004
Report ID: AB23275
Lindt Units Analyst
'o 030 mg/1 JMT
0 . 020 mg/1 JMT
0. 010 mg/1 JMT
0. 010 mg/1 JMT
0. 40 mg/1 JMT
10.0 mg/1 JMT
a.so mg/1 JMT
Prep Date
03/16/2004 0830
Date
03/16/2004
03/16/2004
03/16/2004
03/16/2004
03/16/2004
03/16/2004
03/16/2004
Time
2042
2042
2042
2 042
2042
2042
2042
Davis & Floyd, Inc. / PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
98
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DAYIS
FLt'JYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenification Number: 25
Project Number: 61621.01
Report Date
Page 23 of 55
April 12, 2004
Report ID: AB23275
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG37104 Matrix Leachate
MS/MSD MS04022607-01:37104 Prep Method SW846 1311/3510C
MSD04022607-01137104 Analtyical Method: SWB46 1)11/8081A
ENDRIN 0.00400 < 0.000500 0.00338 mg/1 84 74-119
HEPTACHLOR 0.00400 < 0. 000500 0.00326 mg/1 82 59-123
HEPTACHLOR EPOXIDE 0.00400 < 0.000500 0.00308 mg/1 77 70-117
LINDANE 0.00400 < 0.000500 0.00295 mg/1 74 65-114
METHOXYCHLOR 0.00400 < 0.00500 0.00500 mg/1 77 54-135
ENDRIN 0.00400 0.00362 mg/1 91 7 18 74-119
HEPTACHLOR 0.00400 0.00340 mg/1 85 4 20 59-123
HEPTACHLOR EPOXIDE 0.00400 0 .00324 mg/1 81 5 19 70-117
LINDANE 0.00400 0 .00306 mg/1 76 4 18 65-114
METHOXYCHLOR 0.00400 0 .00500 mg/1 77 0 16 54-135 I NOTE: MS/MSD \ recoveries are not evaluated if the sample cOncentration is greater than four times the spike added.
I
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I
.Davis & Floyd, Inc. I PO Drc1wer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] j Fax [phone]
99
Di\YIS
FLtfYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenijication Number: 25
Project Number: 61621.01
Report Date
Page 24 of 55
April 12, 2004
Report ID: AB23275
.QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG37104 Matrix Leachate
MS/MSD MSOt022607-02:37104 Prep Method SW846 1311/JSlOC
MSD04022607-02:37104 Analtyical Method: SW846 1311/BOBlA
ENDRIN 0.00400 < 0. 000500 0. 00358 mg/1 90 74-119
HEPTACHLOR 0.00400 < 0. 000500 0. 00353 mg/1 88 59-123
HEPTACHLOR EPOXIDE 0.00400 < 0. 000500 0.00334 mg/1 83 70-117
LINDANE 0.00400 ' 0 000500 0. 00314 mg/1 78 65-114
METHOXYCHLOR 0.00400 < 0.00500 0.00500 mg/1 82 54-13 5
ENDRIN 0.00400 0.00379 mg/1 95 6 18 74-119
HEPTACHLOR 0.00400 0. 00359 mg/1 90 2 20 59-123
HEPTACHLOR EPOXIDE 0.00400 .0.00349 mg/1 87 4 19 70-117
LINDANE 0.00400 0. 00322 mg/1 80 2 18 65-114
METHOXYCHLOR 0.00400 0.00500 mg/1 86 4 16 54-135
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 J 8 I 6 E. Durst Avenue j Greenwood, SC 29649 I {864) 229-4413 I Fax [phone]
100
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DAYIS
FLbYD LABORATORY ANALYSIS REPORT
client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenijication Number: 25
Project Number: 61621.01
Report Date April 12, 2004
Page 25 of 55 Report ID: AB23275
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG37104
LCS LCS37104=1
ENDRIN 0.00400 0.00364
HEPTACHLOR 0.00400 0.00338
HEPTACHLOR EPOXIDE 0.00400 0. 003H
LINDANE 0.00400" 0.00306
METHOXYCHLOR 0.00400 0.00500
Matrix Leachate
Prep Method SW846 1311/3510C
Analtyical Method: SW846 1311/SOSlA
mg/1 91 62~131
mg/1 84 54-115
mg/1 84 63-113
mg/1 76 58-116
mg/1 80 60-140
ravis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 / 816 E. Durst Avenue ) Greenwood, SC 29649 j [phone] I Fax [phone]
101
DAYIS
FL0\1D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198,
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date April 12, 2004
Page 26 of 55 Report ID: AB23275
QC Batch Report -Batch Sample List
WorkGroup WG37133 Matrix Leachate
Description: PS/TCLP/PEST --0317XP Prep Method SW846 1311/3510C
Analtyical Method: SW846 1311/B0BlA
PREP ANALYTICAL
Samplo ID Client ID Run# Date Time Date Time Analyst
L04022607-0l .SBR SLUDGE 2 0]/17/2004 0930 03/17/2004 2219 JMT
L04022607-02 FP SLUDGE 2 03/17/2004 0930 03/18/2004 0240 JMT
M837133: 1 Method Blank 1 03/17/2004 0930 03/17/2004 2105 JMT
LCS37133:l Laboratory Control Spike 03/17/2004 0930 03/17/2004 2142 JMT
MS04022607-0l:37133 Matrix Spike 03/17/2004 0930 03/17/2004 2256 JMT
MS04022607-02:37133 Matrix Spike 1 03/17/2004 0930 03/18/2004 0318 JMT
MSD04022607•01:37133 Matrix Spike Duplicate 1 03/17/2004 0930 03/17/2004 2333 JMT
MSD04022607•02:37133 Matrix Spike Duplicate 1 03/17/2004 0930 03/18/2004 0355 JMT
Dilution
1
1
1
1
1
1
Davis & Floyd, Inc. I PO Drawer 428 [ Greenwood, SC 29648 I 816 E. Durst Avenue l Greenwood, SC 29649 J [phone] I Fax [phone]
1 02
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1·
I
DAYIS
FLbYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 27 of 55
April 12, 2004
Report ID: AB23275
QC Batch Report -Surrogates % Recovery
WorkGroup: WG37133 Matrix Leachate
Prep Method SW846 1311/lSlOC
Analtyical Method: SW846 1311/BOBlA
L04022607-01 03/17/2004 2219 86 73
L04022607-02 03/18/2004 0240 89 70
M837133: 1 03/17/2004 2105 91 69
LCS37133:l 03/17/2004 2142 97 77
MS04022607-01:37133 03/17/2004 2256 84 72
MS04022607-02:37133 03/18/2004 0318 92 87
MSD04022607-01 :37133 03/17/2004 2333 89 84
MSD04022607-02:37133 03/18/2004 0355 90 81
DCB DECACHLOROBIPHENYL
TCX TETRACHWRO-M-XYLENE
IDavis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 ! [phone] I Fax [phone]
103
DAYIS
FLtJ\1D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
QC Batch Report -Method Blanks
WorkGroup: WG37133
Blank MB37133:l
Parameter
Pesticides and Herbicides TCLP
SW846 1311/BOBlA
CHLORDANE, TECHNICAL
ENDRIN
HEPTACHLOR
HEPTACHLOR EPOXIDE
LINDANE
METHOXYCHLOR
TOXAPHENE
<
<
<
<
<
<
<
Prop Procedure Mothod
Analytical Prep Procedures:
Result
0.0050
0. 00050
o. oooso·
0.00050
0.00050
0 0050
0.0050
TCLP PESTICIDES SW846 1311/3510C
Qual RDL
0. 0050
0 00050
0. 00050
o. 00050
0. 00050
0.0050
0.0050
Analyst
MCR
NC Cenijication Number: 25
Project Number: 61621.01
Report Date April 12, 2004
Page 28 of 55 Report ID: AB23275
Matrix: Leachate
Limit Units Analyst Date
0.030 mg/1 JMT 03/17/2004
0. 020 mg/1 JMT 03/17/2004
0.010 mg/1 JMT 03/17/2004
0. 010 mg/1 JMT 03/17/2004
0.40 mg/1 JMT 03/17/2004
10.0 mg/1 JMT 03/17/2004
a.so mg/1 JMT 03/17/2004
Prep Date
03/17/2004 0930
Time
2105
2105
2105
2105
2105
2105
2105
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone] I 9
104
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D~IS
FLm'D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
NC Cenijication Number: 25
Project Number: 61621.01
Report Date
Page 29 of 55
April 12, 2004
Report ID: AB23275
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup, WG37133 Matrix Leachate
MS/MSD MS04022607-01:37133 Prep Method SW846 1311/JSlOC
MSD04022607-01:37133 Analtyical Method: SWB46 1311/BOBlA
ENDRIN 0.00400 < 0.000500 0.00399 mg/1 100 74-119
HEPTACHLOR 0.00400 ' 0 000500 0. 00'353 mg/1 88 59-123
HEPTACHLOR EPOXIDE 0.00400 ' 0 000500 0.00353 mg/1 88 70-117
LINDANE 0.00400" ' 0. 000500 0.00322 mg/1 Bl 65-114
METHOXYCHLOR 0.00400 ' 0 00500 0.00500 mg/1 92 54-135
ENDRIN 0 00400 0. 00434 mg/1 108 8 18 74-119
HEPTACHLOR 0 00400 0. 00400 mg/1 100 12 20 59-123
HEPTACHLOR EPOXIDE o. 00400 0. 00386 mg/1 97 9 19 70-117
LINDANE 0 00400 0.00374 mg/1 93 15 18 65-114
METHOXYCHLOR 0.00400 o. 00500 mg/1 98 7 16 54-135
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] ! Fax {864) 229-711 Y
105
DAYIS
FLtiYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem ~arter
NC Cenification Number: 25
Project Number: 61621 01
Report Date
Page 30 of 55
April 12, 2004
Report ID: AB23275
QC Batch Report -Matrix Spikes and Duplicates
ENDRIN
HEPTACHLOR
WorkGroup: WG37133
'.'MS/MSD MS0f. 022607-02; 37133
MSDOf.022607-02:37133
0.00400
0.00400
HEPTACHLOR EPOXIOE 0.00400
LINDANE 0. 00400"
METHOXYCHLOR 0.00400
ENDRIN 0.00400
HEPTACHLOR 0.00400
HEPTACHLOR EPOXIDE 0.00400
LINDANE o. 00400
METHOXYCHLOR 0.00400
NOTB: MS/MSD \ recoveries are not evaluated if the
' 0 000500
'o. 000500
' 0 000500
'o. 000500
' 0 00500
0. 00412
0. 00391
0.00375
0 00349
0.00500
Matrix Leachate
Prep Method SW846 1311/JSlOC
Analtyical Method: SW846 1311/BOSlA
0. 00426 mg/1 106 74 -119
0 . 06402 mg/1 100 59-123
0 .00376 mg/1 94 70-117
o. 00363 mg/1 91 65-114
0 00500 mg/1 91 54-135
mg/1 103 3 18 74-119
rng/1 98 3 20 59-123
mg/1 94 0 19 70-117
mg/1 87 4 18 65-114
mg/1 90 0 16 54-135
sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 / 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
106
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DAYIS
FLti\'D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number, 61621.01
Report Date April 12, 2004
Page 31 of 55 Report ID: AB23275
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG37133 Matrix Leachate
LCS LCS37133:l Prep Method SW846 1311/3510C
Analtyical Method: SW846 1311/BOBlA
ENDRIN 0.00400 0.00433 mg/1 108 62-131
HEPTACHLOR 0.00400 0.00400 mg/1 100 54-115
HEPTACHLOR EPOXIOE 0.00400 0.00389 mg/1 97 63 -113
LINDANE 0.00400 0.00369 mg/1 92 58-116
METHOXYCHLOR 0.00400 0.00500 mg/1 98 60-140
I Davis & Floyd, Inc. I PO Drawer 428 ) Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] ] Fax [phone]
107 ·
DAYIS
FLMD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date April 12, 2004
Page 32 of 55 Report ID: AB23275
QC Batch Report -Batch Sample List
WorkGroup WG37105 Matrix Leachate
iDescription: PS/TCLP /HERB --0316XH Prep Method SW846 1311/BlSlA
Analtyical Method: SW846 1311/BlSlA
PREP ANALYTICAL
Sample ID Client ID Run# Date Time Date Time Analyst
L04022607-0l SBR SLUDGE 03/17/2004 1130 03/17/2004 1818 JMT
L04022607-01 SBR SLUDGE 2 03/17/2004 1130 03/17/2004 1818 JMT
L04022607-02 FP SLUDGE 1 03/17/2004 1130 03/17/2004 2051 JMT
MB37105:l Method Blank 1 03/16/2004 1020 03/17/2004 1735 JMT
LCS37105:l Laboratory Control Spike 1 03/16/2004 1020 03/17/2004 1756 JMT
MS04022607-0l 37105 Matrix Spike 03/16/2004 1020 03/17/2004 1840 JMT
MS04022607-0l:37105 Matrix Spike 2 03/16/2004 1020 03/17/2004 1840 JMT
MS04022607-02:37105 Matrix Spike 1 03/16/2004 1020 03/17/2004 2113 JMT
MSD04022607-01:37105 Matrix Spike Duplicate 03/16/2004 1020 03/17/2004 1903 JMT
MSD04022607-0l:37105 Matrix Spike Duplicate 2 03/16/2004 1020 03/17/2004 1903 JMT
MSD04022607-02:37105 Matrix Spike Duplicate 1 03/16/2004 1020 03/17/2004 2135 JMT
Dilution
1
1
1
1
1
1
1
1
1
1
Dav!s & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 ! [phone] I Fax [phone]
108
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Df\YIS
FLt1YD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenijication Number: 25
Project Number: 61621.01
Report Date
Page 33 of 55
April 12, 2004
Report ID: AB23275
QC Batch Report -Surrogates % Recovery
WorkGroup: WG37105 Matrix Leachate
Prep Method SW846 1311/SlSlA
Analtyical Method: SW846 1311/SlSlA
L04022607-01 .03/17/2004 1818 127
L04022607-02 03/17/2004 2051 106
MB37105:l 03/17/2004 1735 112
LCS37105:1 03/17/2004 1756 104
MS04022607-01:37105 03/17/2004 1840 127
MS04022607-02:)7105 03/17/2004 2113 94
MSD04022607-01:37105 03/17/2004 1903 117
MSD04022607-02:37105 03/17/2004 2135 110
OTHER -2,4-DICHLOROPHENYLACETIC ACID
,,vis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
109
DAYIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
QC Batch Report -Method Blanks
WorkGroup: WG37105
Blank MB37105:l
Para.meter
Pesticides and Herbicides TCLP
SW846. 13ll/8151A
2,4,5-TP {SILVEX)
2,4-D
<
<
Prep Procedure Method
Analytical Prep Procedures:
.Result Qual
0. 0025
0.025
Analyst
TCLP HERBICIDES SW846 1311/SlSlA MCR
RDL
0. 0025
0.025
NC Certification Number: 25
Project Number, 61621.01
Report Date
Page 34 of 55
Matrix: Leachate
April 12, 2004
Report ID: AB23275
Limit Units Analyst
) 1.0 mg/1 JMT
10.0 mg/1 JMT
Prep Date
03/16/2004 1020
Date Time
03/17/2004 1735
03/17/2004 1735
Davis & Floyd, Inc. l PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
11 0
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D~IS
FLffi'D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date April 12, 2004
Page 35 of 55 Report ID: AB23275
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG37105
MS/MSD MS04022607-01:37105
2,4,5-TP (SILVEX)
2,4-D
2,4,5-TP (SILVEX)
2, 4-D
MSD04022607-01:37105
0.0100
0.0500
0.0100
0.0500
< 0.00250
< 0.0250
0.0102
0.0483
Matrix Leachate
Prep Method SW846 1311/BlSlA
Analtyical Method: SW846 1311/BlSlA
0.0105
0.0508
mg/1
mg/1
mg/1
mg/1
102
97
105
102
8
4
53-108
61-112
20
20
53-108
61-112
NOTE: MS/MSD t recoveries are not evaluated if the sample concentration is greater than four times the spike added.
I PO Dravver 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
111
Df\YIS
FLtWD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenification Number: 25
Project Number: 61621.01
Report Date April 12, 2004
Page 36 of 55 Report ID, AB23275
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG37105
MS/MSD MS0t022607-02:37105
2,4,5-TP (SILVEX)
2, 4 -D
2,4,5-TP (SILVEX)
2,4-D
MSD04022607-02:37105
0.0100
0.0500
0.0100
0.0500
< 0.00250
< 0.0250
0.0106
0 0519
Matrix Leachate
Prep Method SW846 1311/SlSlA
Analtyical Method: SW846 1311/BlSlA
0. 00915
0.0433
mg/1
mg/1
mg/1
mg/1
106
104
92
87
15
18
53-108
61-112
20
20
53-108
61-112
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue / Greenwood, SC 29649 I [phone] I Fax [phone]
112
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DAYIS
FLtrYD LABORATORY ANALYSIS REPORT
Client
contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date April 12, 2004
Page 37 of 55 Report ID: AD23275
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG37105
LCS LCS37105:l
2,4,5-TP (SILVEX)
2,4-D
0.0100
0.0500
0.00952
0.0441
Matrix Leachate
Prep Method SW846 1311/BlSlA
Analtyical Method: SW846 1311/SlSlA
mg/1
mg/1
95
BB
50-119
57-128
I PO Drawer 428 / Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I {864) 229-4413 I Fax [phone] f 19
11 3
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TrCONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.0l
Report Date
Page 38 of 55
April 12, 2004
Report ID: AB23275
QC Batch Report -Batch Sample List
workGroup WG37135
Description: PS/TCLP/HERB --0317XH
Sample ID Client ID Run#
L04022607-01 SBR SLUDGE 3
L04022607-01 SBR SLUDGE 4
L04022607-02 FP SLUDGE. 2
MB37135:1 Method Blank 1
LCS37135:l Laboratory Control Spike 1
MS04022607-01 37135 Matrix Spike 1
MS04022607-01:37135 Matrix Spike 2
MS04022607-02:37135 Matrix Spike
MSD04022607-01:37135 Matrix Spike Duplicate 1
MSD04022607-01:37135 Matrix Spike Duplicate 2
MS004022607-02:37135 Matrix Spike Duplicate 1
Matrix Leachate
Prep Method SW846 1311/SlSlA
Analtyical Method: SW846 1311/BlSlA
PREP ANALYTICAL
Date Time Dato Time Analyst
03/17/2004 1130 03/18/2004 1700 JMT
03/17/2004 1130 03/18/2004 1700 JMT
03/17/2004 1130 03/18/2004 1828 JMT
03/17/2004 1130 03/18/2004 1616 JMT
03/17/2004 1130 03/18/2004 1638 JMT
03/17/2004 1130 03/18/2004 1722 JMT
03/17/2004 1130 03/18/2004 1722 JMT
03/17/2004 1130 03/18/2004 1850 JMT
03/17/2004 1130 03/18/2004 1744 JMT
03/17/2004 1130 03/18/2004 1744 JMT
03/17/2004 1130 03/18/2004 1912 JMT
Dilution
1
1
1
1
1
1
1
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue l Greenwood, SC 2%49 I [phone] ) Fax [phone]
11 4
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 39 of 55
April 12, 2004
Report ID: AB23275
QC Batch Report -Surrogates % Recovery
WorkGroup, WG37135 Matrix Leachate
Prep Method SW846 1311/SlSlA
Analtyical Method: SW846 1311/BlSlA
L04022607-01 03/18/2004 1700 96
L04D22607-02 03/18/2004 1828 104
MB37135:l 03/18/2004 1616 109
LCS37135: 1 03/18/2004 1638 1l0
MS04022607-01:37135 03/18/2004 1722 107
MS04022607-02:37135 03/18/2004 1850 105
MSD04022607-01:37135 03/18/2004 1744 100
MSD04022607-02:37135 03/18/2004 1912 100
OTHER -2,4-DICHLOROPHENYLACETIC ACID
ravis & Floyd, Inc. ) PO Dra\.ver 428 I Greenwood, SC 29648 I 816 E. Durst Avenue ! Greenwood, SC 29649 I [phone] I Fax [phone]
11 5
DAYIS
FLtlYD LABORATORY ANALYSIS REPORT
Client
contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
QC Batch Report -Method Blanks
WorkGroup: WGJ7135
'.·Blank MBJ7135:1
Parameter
Pesticides and Herbicides TCLP
SW846 1311/BlSlA
2,4,S-TP (SILVEX)
2, 4-D
Prep Procedure
Analytical Prep Procedures:
Method
Result Qual
0.0025
0.025
Analyst
TCLP HERBICIDES SW846 1311/8151A MCR
RDL
0. 0025
0.025
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 40 of 55
Matrix: Leachate
April 12, 2004
Report ID: AB23275
Limit Units Analyst
1.0
10.0
Prep Date
mg/1
mg/1
03/17/2004 1130
JMT
JMT
Date Time
03/18/2004 1616
03/18/2004 1616
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 J 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
11 6
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.0l
Report Date April 12, 2004
Page 41 of 55 Report ID: AB23275
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG37135
MS/MSD MS04022607-01:37135
2,4,5-TP (SILVEX)
2,4-D
2,4,5-TP (SILVEX)
2,4-D
MSD04D22607-0l:37135
0.0100
o.osoo
0.0100
0.0500
< 0.00250
< 0.0250
0.00993
0.0470
Matrix Leachate
Prep Method SW846 1311/SlSlA
Analtyical Method: SWB46 1311/SlSlA
0 0101
0.0479
mg/1
mg/1
mg/1
mg/1
99
94
101
96
l
7
53-108
61-112
20
20
53-108
61-112
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
11 7.
Di\YIS
FLtJYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
NC Cenijication Number: 25
Project Number: 61621.01
Report Date
Page 42 of 55
April 12, 2004
Report ID: AB23275
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG37135
MS/MSD MSOi022607-02i)7135
2,4,5-TP (SILVEX)
2, 4-D
2,4,5-TP (SILVEX)
2, 4-D
MSD04022607-02137135
0.0100
0.0500
0.0100
0.0500
< 0.00250
< 0.0250
0 0104
0. 04 93
Matrix Leachate
Prep Method 8WB46 1311/BlSlA
Analtyical Method: SW846 1311/SlSlA
0.0106
0 05°01
mg/1
mg/1
10,
99
106
100
2
2
53-108
61-112
20
20
53-108
61-112
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 j 816 E. Durst Avenue I Greenwood, SC 29649 I (B64) 229-4413 I Fax [phone]
1 1 8
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DAYIS
FLtfYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date April 12, 2004
Page 43 of 55 Report ID: AB23275
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG37135
LCS LCS37135:1
2,4,5-TP (SILVEX)
2,4-D
0.0100
0.0500
0.00986
0.0438
Matrix Leachate
Prep Method SWB46 1311/BlSlA
Analtyical Method: SW846 1311/BlSlA
mg/1
mg/1
99
88
50-119
57-128
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
11,9
DAYIS
FLtfYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Fem carter
NC Cenijication Number: 25
Project Number: 61621.01
Report Date April 12, 2004
Page 44 of 55 Report ID: AB23275
QC Batch Report -Batch Sample List
WorkGroup WG36943
Description: 3010A TCLP (6)
Sample ID Client ID Run#
L04022607-0l SBR SLUDGE
L04022607-02 FP SLUDGE 1
EB36943:l Extraction Blank 1
MB36943:l Method Blank
LCS36943: l Laboratory Control Spike
MS04022607-01:36943 Matrix Spike 1
MS04022607-02:36943 Matrix Spike
MSD04022607-01:36943 Matrix Spike Duplicate 1
MSD04022607-02:36943 Matrix Spike Duplicate
Matrix
Prep Method
Leachate
SW846 3010
Analtyical Method, SW846 1311/60108
PREP ANALYTICAL
Date Timo Date Time Analyst
03/03/2004 0915 03/03/2004 132 9 BDL
03/03/2004 0915 03/03/2004 1358 BDL
03/03/2004 0915 03/03/2004 1415 BDL
03/03/2004 0915 03/03/2004 1317 BDL
03/03/2004 0915 03/03/2004 1323 BDL
03/03/2004 0915 03/03/2004 1334 BDL
03/03/2004 0915 03/03/2004 1403 BDL
03/03/2004 0915 03/03/2004 1340 BDL
03/03/2004 0915 03/03/2004 1409 BDL
Dilution
1
1
1
1
1
1
1
1
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
120
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
QC Batch Report -Method Blanks
Parameter
Trace Metals TCLP
SW846 1311/6010B
ARSENIC, TOTAL
BARIUM, TOTAL
CADMIUM, TOTAL
CHROMIUM, TOTAL
LEAD, TOTAL
SELENIUM, TOTAL
SILVER, TOTAL
Prep Procedure
WorkGroup: WG36943
Blank EB36943:1
'
'
'
'
'
'
'
Method
Result
0.20
0.20
o.oso
0 .10
0.050
0.10
0.10
Analytical Prep Procedures1
METALS PREP ICP SW846 3010
RDL
0.20
0.20
0.050
0.10
0.050
0.10
0 .10
Analyst
BDL
NC Cenification Number: 25
Project Number: 61621.01
Report Date April 12, 2004
Page 45 of 55 Report ID: AB23275
Matrix: Leachate
Limit Units Analyst Date
5.0 mg/1 BDL 03/03/2004
100 mg/1 BDL 03/03/2004
1.0 mg/1 BDL 03/03/2004
5.0 mg/1 BDL 03/03/2004
5 .0 mg/1 BDL 03/03/2004
.o mg/1 BDL 03/03/2004
s.o mg/1 BDL 03/03/2004
Prep Date
03/03/2004 0915
Time
1415
1415
1415
1415
1415
1415
1415
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 / 816 E. Durst Avenue I Greenwood, SC 29649 I (864) 229-441 J I Fax [phone]
1 21
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
QC Batch Report -Method Blanks
Parameter
Trace Metals TCLP
SW846 1311/6010B
ARSENIC, TOTAL
BARIUM, TOTAL
CADMIUM. TOTAL
CHROMIUM, TOTAL
LEAD, TOTAL
SELENIUM, TOTAL
SILVER, TOTAL
Prep Procedure
WorkGroup: WG369t3
MB36943:l
'
'
'
'
'
'
'
Method
Result Qual
0. 20
0.20
0.050
0.10
o.oso
0.10
0.10
Analyst
Analytical Prep Procedures=
METALS PREP ICP SW846 3010 BDL
RDL
0.20
0. 20
0.050
0.10
0. 050
0. 10
0.10
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 46 of 55
Matrix: Leachate
April 12, 2004
Report ID: AB23275
Linlit Units Analyst
5.0 mg/1 BDL
100 mg/1 BDL
l .o mg/1 BDL
5.0 mg/1 BDL
5.0 mg/1 BDL
1.0 mg/1 BDL
5.0 mg/1 BDL
Prep Date
03/03/2004 0915
Date
03/03/2004
03/03/2004
03/03/2004
03/03/2004
03/03/2004
03/03/2004
03/03/2004
Time
1317
1317
1317
1317
1317
1317
1317
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 ) 816 E. Durst Avenue I Greenwood, SC 29649 I (864} 229-4413 I Fax [phone]
122
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DAYIS
FLtWD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 47 of 55
April 12, 2004
Report ID: AB23275
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG36943
MS/MSD MS04022607-01:36943
MSD04022607-0l:36943
ARSENIC, TOTAL 5.00
BARIUM, TOTAL 10. 00
CADMIUM, TOTAL 1.00
CHROMIUM, TOTAL 5 . 00
LEAD, TOTAL 5. 00
SELENIUM, TOTAL 5. 00
SILVER, TOTAL 1 . 00
ARSENIC, TOTAL 5.00
BARIUM, TOTAL 10.00
CADMIUM, TOTAL 1.00
CHROMIUM, TOTAL 5.00
LEAD, TOTAL 5.00
SELENIUM, TOTAL s.oo
SILVER, TOTAL 1.00
NOTE: MS/MSD \-recoveries are not evaluated if the
Matrix
Prep Method
Leachate
SW846 3010
Analtyical Method: SW846 1311/60108
< 0. 200 5.-40 mg/1 10B 84-114
O. 20B 11.10 mg/1 109 86-110
< 0.0500 1.10 mg/1 110 87-112
< o . 100 5. 39 mg/1 10B 86-110
< 0.0500 5.50 mg/1 110 87-112
< 0 .100 5.28 mg/1 106 86-113
< o . 100 1.10 mg/1 110 90-110
5.36 mg/1 107 1 10 B4-114
11. 08 mg/1 109 0 10 86-110
1.09 mg/1 109 1 10 87-112
5. 37 mg/1 107 0 10 86-110
5.48 mg/1 110 0 10 87-112
5.25 mg/1 105 0 10 86-113
1.10 mg/1 110 1 10 90-110
sample concentration is greater than four times the spike added.
I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
123
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Report Date April 12, 2004
Page 48 of 55 Report ID: AB23275
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG36943
'MS/MSD MS04022607-02:36943
MSD04022607-02:36943
ARSENIC, TOTAL 5.00
BARIUM, TOTAL 10.00
CADMIUM, TOTAL 1.00
CHROMIUM, TOTAL s.oo
I,EAD, TOTAL 5.00
SELENIUM, TOTAL 5.00
SILVER, TOTAL 1.00
ARSENIC, TOTAL 5.00
BARIUM, TOTAL 10.00
CADMIUM, TOTAL 1.00
CHROMIUM, TOTAL s.oo
LEAD, TOTAL 5.00
SELENIUM, TOTAL 5.00
SILVER, TOTAL 1.00
NOTE: MS/MSD \-recoveries are not evaluated if the
Matrix
Prep Method
Leachate
SW846 3010
Analtyical Method: SW846 1311/60108
< 0.200 5.20 mg/1 104 84-114
4. 46 14. 91 mg/1 105 86-110
< 0.0500 1.05 mg/1 105 87-112
<: 0 .100 5.16 mg/1 103 86-110
<: 0.0500 5.26 mg/1 105 87-112
< o. 100 5.11 mg/1 102 86-113
< 0. 100 1.07 mg/1 107 90-110
5.15 mg/1 103 10 84-114
14. 82 mg/1 104 l 10 86-110
1.04 mg/1 104 l 10 87-112
5.11 mg/1 102 l 10 86-110
5.21 mg/1 104 10 87-112
5. 10 mg/1 102 0 10 86-113
1. 06 . mg/1 106 10 90-110
sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. j PO Drawer 428 j Greenwood, SC 29648 I 816 E. Durst Avenue / Greenwood, SC 29649 I [phone] I Fax [phone]
124
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DAYIS
FLtJYD LABORATORY ANALYSIS REPORT
ARSENIC, TOTAL
BARIUM, TOTAL
CADMIUM, TOTAL
CHROMIUM, TOTAL
LEAD, TOTAL
SELENIUM, TOTAL
SILVER, TOTAL
Client
contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pern carter
NC Certification Number: 25
Project Number: 61621.01
Report Date April 12, 2004
Page 49 of 55 Report ID: AB23275
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG36943
LCS LCS36943:l
10.00 10.59
20. 00 21. 3 9
2.00 2.18
10. 00 10.62
10.00 10. 77
10.00 10. 40
2.00 2.17
Matrix
Prep Method
Leachate
SW846 3010
Analtyical Method: SW846 1311/6010B
mg/1 106 84-115
mg/1 107 86-110
mg/1 109 89-112
mg/1 106 87-110
mg/1 108 90-110
mg/1 104 85-116
mg/1 109 89-112
.-Davis & Floyd, lnc. PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
125
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenijication Number: 25
Project Number: 61621.01
Report Date April 12, 2004
Page 50 of 55 Report ID: AB23275
QC Batch Report -Batch Sample List
WorkGroup WG3696l
.. Description: Mercury -TCLP
Sample ID Client ID •=#
L04022607-01 · SBR SLUDGE 1
L04022607-02 FP SLUDGE
E836961: 1 Extraction Blank 1
MB36961: 1 Method Blank
LCS36961:l Laboratory Control Spike l
MS04022607-01:36961 Matrix Spike l
MS04022607-02:3696l Matrix Spike l
MSD04022607•01 :36961 Matrix Spike Duplicate l
MSD04022607•02:36961 Matrix Spike Duplicate l
Matrix
Prep Method
Leachate
SW846 7470A
Analtyical Method: SW846 1311/7470A
PRBP ANALYTICAL
Date Time Date Time Analyst
03/04/2004 0900 03/04/2004 1442 ACW
03/04/2004 0900 03/04/2004 1450 ACW
03/04/2004 0900 03/04/2004 1455 ACW
03/04/2004 0900 03/04/2004 1439 ACW
03/04/2004 0900 03/04/2004 1441 ACW
03/04/2004 0900 03/04/2004 1447 ACW
03/04/2004 0900 03/04/2004 1452 ACW
03/04/2004 0900 03/04/2004 144 9 ACW
03/04/2004 0900 03/04/2004 14 53 ACW
Dilution
1
1
1
l
l
l
l
l
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I {864) 229-4413 I Fax {864) 229-7119
126
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DAYIS
FLtwD LABORATORY ANALYSIS REPORT
Parameter
Trace Metals TCLP
SW846· 1Jll/7470A
MERCURY, TOTAL
Prep Procedure
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
QC Batch Report -Method Blanks
WorkGroup: WG36961
Blank EB36961:l
Result Qual RDL
0.0020 0.0020
Method Analyst
Analytical Prep Procedures:
METALS PREP HG SW846 7470A ACW
NC Cenijication Number: 25
Project Number: 61621.01
Report Date
Page 51 of 55
Matrix: Leachate
April 12, 2004
Report ID: AB23275
Limit units Analyst
0. 20 mg/1 ACW
Prep Date
03/04/2004 0900
Date Time
03/04/2004 1455
I Davis & Floyd, Inc. I PO Drawer 428 ! Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood. SC 29649 I [phone] I Fax [phone]
12 7
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Parameter
Trace Metals TCLP
SW845 1311/7470A
MERCURY, TOTAL
Prep Procedure
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Fem carter
_QC Batch Report -Method Blanks
WorkGroup: WG36961
Blank MB369611l
Result Qual RDL
< 0.0020 0.0020
Method Analyst
Analytical Prep Procedures:
METALS PREP HG SW846 7470A ACW
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 52 of 55
Matrix: Leachate
April 12, 2004
Report ID: AB23275
Limit Units Analyst
0.20 mg/1 ACW
Prep Date
03/04/2004 0900
Date Time
03/04/2004 1439
Q;wis & Floyd, Inc. I PO Drawer 428 J Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 2%49 I [phone] I Fax [phone]
128
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
MERCURY, TOTAL
MERCURY, TOTAL
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 53 of 55
April 12, 2004
Report ID: AB23275
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG36961 Matrix Leachate
MS/MSD MS04022607-0l:36961 Prep Method SW846 7470A
MSD04022607-0lz36961 Analtyical Method: SW846 1311/7470A
0.0100 < 0.00200 0.00971 mg/1 97 82-114
0.0100 0 0100 100 3 10 82-114
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
,-Davis & Floyd, Inc. I P0Drawer428 I Greenwood,SC29648 I 816E.DurstAvenue I Greenwood,SC29649) [phone] I Fax[phone]
12 9
DAYIS
FLt1YD LABORATORY ANALYSIS REPORT
MERCURY, TOTAL
MERCURY, TOTAL
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 54 of 55
April 12, 2004
Report 1D: AB23275
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG36961 Matrix Leachate
!MS/MSD MS04022607-02:36961 Prep Method SW846 7470A
. MSD04022607-02:3O61 Analtyical Method: SW846 1311/7470A
0.0100 < 0.00200 0 0110 mg/1 110 82-114
0.0100 0.0113 113 3 10 82-114
NOTE: MS/MSD t recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & F!oyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I (864} 229-4413 I Fax [phone]
130
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DAYIS
FLtlYD LABORATORY ANALYSIS REPORT
MERCURY, TOTAL
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenijication Number: 25
Project Number: 61621.01
Report Date April 12, 2004
Page 55 of 55 Report ID: AB23275
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup: WG36961
LCS LCS36961:l
0.0200 0.021B
Matrix
Prep Method
Leachate
SW846 7470A
Analtyical Method: SW846 1311/7470A
mg/1 109 90-110
.Davis & Floyd, Inc. I PO Drt1wer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
131
Dl\VIS
FLOYD LABORATORY ANALYSIS REPORT
CASE NARRATIVE
Account:
Project:
Date:
Ticona, LLC -Shelby, NC
61621.01
April l, 2004
OVERVIEW
On February 26, 2004, Davis & Floyd received two sludge samples from the Ticona plant in Shelby, NC. The
samples were extracted by Method 1311, Toxicity Characteristic Leaching Procedure (TCLP) using the appropriate
fluid and sample vessel. The TCLP extracts were then analyzed for volatile organics, semi volatile organics, trace
metals pesticides, and herbicides. This report contains the analytical data for the following login numbers:
Sample Number
L04022607-0 I
L04022607-02
Sample ID
SBR Sludge
•FP Sludge
The samples were transported to our laboratory o.n ice accompanied by documented Chain of Custody forms. Upon
receipt by the laboratory, the sample custodian checked samples against the Chain of Custody for agreement and
documented the pH of all preserved sample fractions on the sample login report. All samples were received intact
with no discrepancies noted by the sample custodian.
SAMPLE HOLD TIME DEVIATIONS
Sample holding times were exceeded for the analysis of the TCLP Pesticides and Herbicides. During sample login
the pesticides and herbicides were omitted. According to the Sample Custodian the samples were logged in by the
COC instead of the Task Order. The COC was documented "TCLP SVOCs" with a reference to the Task Order in
the comments section. This was D&F's oversight for not referring to the Task Order. Greg Kinsman of Kubal-Furr
was notified of the problem. Mr. Kinsman indicated that he would not be able to obtain additional sample because
the sludges were generated as a batch process vs. continuously.
According to SW846 method 131) TCLP paragraph 8.5, the maximum sample holding time from field collection to
TCLP extraction for the Semi-volatiles is 14 days. The maximum sample holding time from TCLP extraction to
Preparative extraction is 7 days.
Despite the sample holding time issues analyses were conducted on both the original sludge samples collected Feb.
25, 2004 and the TCLP extracts generated on Mar. 2, 2004
l. New TCLP extracts on the sludge samples were generated on Mar. 16, 2004 followed by the preparative
extraction on March 17, 2004. This represents a holding time of20 days from field collection to TCLP
extraction.
2. Preparative extractions on the original TCLP extracts generated March 2, 2004 were initiated on March 17,
2004. This represents a holding time of 15 days from TCLP extraction to preparative extraction.
130th analyses of the above 808 lA TCLP pesticides and 8 I 5 IA TCLP herbicides are included in the Laboratory
Analysis Report. The analytical results presented in this report as well as all historical results shows neither TCLP
pesticides nor TCLP herbicides to be present in the samples.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816E. D"{'3';i'enue I Greenwood, SC 29649 I [phone] I Fax [phone]
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FLlwD
VOLATILE ORGANICS
Sample Analysis
LABORATORY ANALYSIS REPORT
The samples and any associated QC were prepared and analyzed according to the procedure described in SW846
Method 8260B. Samples L04022607-0land L040022607-02 were analyzed at ambient temperature on instrnment
HP5972T, a Hewlett Packard 5973 GC/MS equipped with an 01 purge and trap system using a 5 ml purge volume.
An initial five-point calibration is performed covering a range of 5 µg/1 to 200 µg/1. For each compound with less
than 15% RSD, the relative response factor is assumed to be constant over the calibration range, and the average
response is used for quantitation. If the %RSD is greater than fifteen percent, then linear regression is used for
quantitation. Calibration is verified every twelve hours by checking the GC/MS tuning criteria using 50 ng of BFB
and analyzing a continuing calibration standard at 50 µg/1 and a method blank.
Quality Control
Each sample including QC samples and blanks are spiked with surrogate standards at the 50 µg/1 level. All surrogate
recoveries were within the acceptance criteria. A matrix spike and matrix spike duplicate were analyzed on both
samples. All recoveries on MS, MSD and LCS analyses were within QC acceptance criteria.
SEJ\11VOLATILE ORGANICS
Sample Analysis
The samples and any associated QC were analyzed according to the procedure described in SW846 8270C. Prior to
analysis, all samples were extracted by separatory funnel shake out with methylene chloride according to SW846
Method 3510C. Samples L04022607-01 and L04022607-02 were analyzed on instrument HP5972P, a Hewlett
Packard 5972 series system. Two calibration mixes are used for TCLP analysis. One mix contains our routine SW-
846 8270C target list. The other mix contains those TCLP compounds not included in the other mix. An initial five-
point calibration for each mix is performed covering a range of 10 ug/1 to 80 ug/1 (10 ug/1 to 120 ug/1 for the
additional compounds). For each compound with less than 15% RSD, the relative response factor is assumed to be
constant over the calibration range, and the average response is used for quantitation. If the %RSD was greater than
fifieen percent for any compound, then linear regression is used for quantitation. Calibration is verified every twelve
hours by checking the GC/MS tur,ing criteria using 50 ng ofDFTPP and analyzing a continuing calibration standard
at 50 µg/1 (60 ug/1 for the additional compounds) and a method blank.
Quality Control
Each sample including QC samples and blanks is spiked with surrogate standards at a concentration of 50 µg/1 for
the base-neutral compounds and I 00 µg/1 for the acid extractable compounds. All surrogate recoveries were within
acceptable limits. A matrix spike and matrix spike duplicate were analyzed on both samples. All recoveries on MS,
MSD and LCS analyses were within QC acceptance criteria.
2
••vis & Floyd, Inc. I PO Drawer 428 I Greenwood. SC 29648 I 816 E. Duf't:rnue I Greenwood, SC 29649 I [phone] I Fax [phone]
DAYIS
FLOYD
GAS CHROMATOGRAPHY
PESTICIDES
Sample Analysis ·
LABORATORY ANALYSIS REPORT
Prior to analysis, all samples were extracted by separatory funnel shake out with methylene chloride according to
SW846 Method 35 l0C. Samples L04022607-0l and L04022607-02 were analyzed on a Varian 3400 series system
designated as.YARK. An initial five-point calibr~tion covering a range of .005 mg/L to .016mg/L was performed
prior to analysis of samples and evaluated by linear regression using a least squares regression. The correlation
coefficient must be greater than or equal to .990. Calibration is verified daily by analyzing a continuing calibration
standard and evaluating the% drift of each compound which must be no more than+/-15%.
Quality Control
Each sample including QC samples and blanks arc spiked with decachlorobiphenyl (DCB) and tctrachloro-m-xylene
(TCMX) at a concentration of 1.0 µg/1 as the surrogate standard. All surrogate recoveries were within acceptable
limits. A matrix spike and matrix spike duplicate were analyzed on both samples. A LCS was analyzed at a
r:ninimum frequency often percent. All criteria for the QC samples were acceptable.
HERBICIDES
Sample Analysis
Prior to analysis, all samples were extracted by separatory funnel shake out with diethyl ether according to SW846
Method 815 l A. Samples L04022607-01 and L04022607-02 were analyzed on a Varian 3400 series system
designated as V ARE. An initial five-point calibration covering a range of .025mg/L to 2.0mg/L was perfonned prior
to analysis of samples and evaluated by linear regression using a least squares regression. The correlation coefficient
must be greater than or equal to .990. Calibration is verified daily by analyzing a continuing calibration standard and
evaluating the% drift of each compound which must be no more than+/-15%.
Quality Control
Each sample including QC samples and blanks are spiked with 2,4-dichlorophenylacetic acid (DCAA) at a
concentration of 2.0 µg/1 as the smrngate standard. Acceptable surrogate recovery was obtained. A matrix spike and
matrix spike duplicate were analyzed on both samples. A LCS was analyzed at a minimum frequency often percent.
All criteria on the QC samples wire within acceptable limits.
TRACE METALS
INDUCTIVELY COUPLED PLASMA /ICP)
Sample Analysis
Arsenic, barium, cadmium, chromium, lead, selenium and silver were analyzed on the TCLP extracts samples
L04022607-01 and L04022607-02 by Inductively Coupled Plasma (ICP) on a Thermo Jarrell Ash 61E Trace
simultaneous system according to the procedure described in SW846 Method 60!0B. Prior to the analysis, 25 ml of
a TCLP extract was digested in an acid matrix according to the sample preparation procedure described in SW846
Method 3010A. The calibration of the instiument was verified with a 1.0 mg/L initial calibration verification
standard (!CV), an initial calibration blank (!CB), a reportable detection limit standard (RDL), an interelement and
background correction check standard (ICSAB), a continuing calibration verification standard (CCV) and a
continuing calibration blank (CCB). The ICV was from a different source than the one used to calibrate the
instrnment. A continuing calibration verification standard (CCV) and a continuing calibration blank (CCB) were
analyzed after every ten samples for the duration of the analysis. The ICSAB was analyzed every eight hours. All the
calibration verification checks were within acceptable limits.
3
Davis & Floyd, Jnc. j PO Drawer 428 I Greenwood, SC 29648 I 816 E. Duft4enue l Greenwood, SC 29649 I [phone] I Fax [phone]
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D1\VIS
FLtlYD
Quality Control
LABORATORY ANALYSIS REPORT
A matrix spike (MS) and matrix spike duplicate (MSD) were analycLed on both samples. A laboratory control
standard (LCS), a method blank (MB) and an extraction blank (EB) were analyzed with each workgroup of20 or
fewer samples. All criteria on the QC samples were within acceptable limits.
MERCURY COLD VAPOR
Sample Analysis
The TCLP extracts for samples L04022607-01 and L04022607-02 were analyzed for mercury on a Perkin-Elmer
FIMS I 00 system according to the procedure described in SW846 Method 7470A. The initial calibration consisted
ofa linear regression curve ofa blank and six standards. Prior to analysis of the samples, the curve was verified with
an initial calibration verification standard (ICY) from a different source than the one used for the curve, an initial
calibration blank (!CB), a continuing calibration verification standard (CCV) and a continuing calibration blank
(CCB). After every IO samples, the CCV and the CCB were analyzed. All the calibration verification checks were
within acceptable limits. ·
Quality Control
A matrix spike (MS) and matrix spike duplicate (MSD) were analyzed on both samples. All criteria on the QC
samples were within acceptable limits.
4 I a vis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I fax [phone]
For Samples:
I CRITERIA
INSTRUMENT QC ASSESSMENT SUMMARY
FOR EPA METHOD 7470A/7471A
lab ID # L04022607-0 I
lab ID# L04022607-02
lab ID# ------lab ID# ------lab ID# ------lab ID# ------
lab ID# ____ _ lab ID#
lab ID# ____ _ lab ID#
lab ID# ____ _ lab ID#
lab ID#. ____ _ lab ID#
lab ID# ____ _ lab ID#
lab ID# ____ _ lab ID#
P/F I COMMENTS
-----
-----
-----
-----
-----
-----
INITIAL CALIBRATION:(a blank and at least 5 p Date of calibration: 3/04/04
standards with r > 0.995 daily)
All standards and solutions prepared/utilized within method p
required holdine times
. Second source initial calibration verification and initial p
calibration blank analyzed immediately after calibration curve
with results within method required control limits
CONTINUING CALIBRATION
A continuing calibration verification standard and continuing p
calibration blank analyzed every IO samples and at the end of
the analytical run with results within method required control
limits
SAMPLE CRITERIA
I. Analyzed within working range of the curve( <highest std) p
2. MSAs performed as needed and within method control
limits
p None required.
I hereby certify that all the above information is correct to the best ofmy knowledge. All out-of-
control measurements relating to the method required acceptance criteria have been documented
in the above table along with any known possible effects on the sample analytical data.
Name_: ___ M_a~ry.__P_.~M~a~u~s ______ _ Date: 3/30/04
(print)
Name:. ___ -11-----------"TY\~(? mO-Lk...,
sign)
Kubal-Furr & Associates
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INSTRUMENT QC ASSESSMENT SUMMARY
FOR EPA METHOD 6010B
For Samples: lab ID# 104022607-01 lab ID# ____ _ lab ID# ____ _
lab ID# 104022607-02 lab ID# ____ _ lab ID# ____ _
lab ID# ____ lab ID# ____ _ lab ID# ____ _
lab ID# ____ lab ID# ____ _ lab ID# ____ _
CRITERIA P/F COMMENTS
INITIAL CALIBRATION: (at least one ~td and blk daily) p Date of calibration: 3/03/04
All standards and solutions prepared/utilized within method required p
holding times
Cal Std anal,ned before sample analyses -95 -105% recovery limits p
Interference check solution analyzed at the beginning and the end of p More than 8 hours elapsed (12:35 -
the run (or every 8 hr-whichever is more frequent) with results within 3: 18). Method requires beginning of
method required control limits of 80 -120% lrun onlv.
Second source initial calibration verification and initial calibration p
blank analV7ed with results within method control limits
CONTINUING CALIBRATION
A continuing calibration verification standard (instrument check std) p
and continuing calibration blank analyzed every IO samples and at
the end of the analvtical run with results within method control limits
SAMPLE CRITERIA
l. Analyzed within linear range of the curve p
2. Serial Dilution (4X) oerformed if new matrix -(+/-) 10% of true p None reauired.
I hereby certify that all the above information is correct to the best ofmy knowledge. All out-of-control
measurements relating to the method required acceptance criteria have been documented in the above
table along with any known possible effects on the sample analytical data.
Name: _....,M=a"-ry=P.:... . .:..:M.:.:a=.:u:.osc__ ______ _ Date: _ _,3"-/"-3 0"'/~0...:.4 __ _
(print)
Name: "Jna.1 G' n7cu.:.,.,
(sign)
QA Officec s;gn,rure~W
Kubal-Furr & Associates
13 7
INSTRUMENT QC ASSESSMENT SUMMARY
FOR EPA METHOD 8270C
For Samples: lab ID# L04022607-0I
lab'fD # L04022607-02
lab ID# ____ _
lab ID# ____ _
lab ID# ____ _ lab ID# ------
I CRITERJA I PIF
INITIAL CALIBRATION:(at least 5 stds with one at or near MDL) p
All standards and solutions prepared/utilized within me_thod holding p times
DFTPP Tune Criteria(table 3) p
DDT degradation< 20% (applicable if determining pesticides) NA
Benzidine and/or pcntachlorophenol present at nonnal responses with p no peak tailing visible( chromato£raohv check std)
Components of interest with RTs of0.80-1.20 relative to one of the p Internal Standards
SPCCs -minimum avg. RFs = 0.05 p
%RSD for all analytes < 15%(use avg. relative RF for calc. or calculate p cal curve with r > 0.990)
%RSD for all analyt~s > l5%(calculate cal curve with r;, 0.990) 'NA
CCCs ave RFs %RSD < 30% p
DAILY OR CONTINUING CALIBRATION p (beginning of each day and every 12 hr)
DFTPP Tune Criteria(table 3) p
MidQoint calibration std run to verifx:
l. SPCCs -minimum avg. RFs = 0.05 p 2. CCCs %Drift in concentration< 20% p
3. Internal Standards RT within 30 sec oflast check std(or cal) p
4. EICP area for ISs -50% to+ I 00% from last check(or cal) p
SAMPLE CRITERIA
I. Run within 12hr of last in-control tuhe p
2. Surrogate% rec within laboratory control limits F
3. TICs -ions> 10% of most abundant ion and NA
relative intensities of major ions agree within 20%
4. Analyzed within-working range of the curve(<highcst std) p
lab ID# ____ _
lab ID# ____ _
lab ID# ____ _
I COMMENTS
Date of calibration: 3/10/04
Time(s) of tuning: 12:18
Pesticides analyzed by 8081 A.
No analytes w/ RSD >15%
Date analyzed: 03/1 1/04
Time(s) of tuning: 12:27
MS recovered 99% (UCL=95)
T!Cs not required.
I
I hereby certify that all the above mfonnat10n 1s correct to the best of my knowledge. All out-of-control measurements relatmg to the
method required acceptance criteria have been documented in the above table along with any known possible effects cin the sample
analytical data.
Name: Paula A. Pulley Date: 3/30/04
QA Officer Signature:
Kubal-Furr f§3'-ssociates
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INSTRUMENT QC ASSESSMENT SUMMARY
FOR EPA METHOD 8081A
For Samples: lab ID# L04022607-0l lab ID# ____ _ lab ID# ____ _
lab ID# L04022607-02 lab ID# ____ _ lab ID# ____ _
lab ID#_____ lab ID# ____ _ lab ID# ____ _
lab ID# _____ lab ID# ____ _ lab ID# ____ _
CRITERIA P/F COMMENTS
INITIAL CALIBRATION:(at least 5 std~ with one at p Date of calibration: 3/01/04
or near MDL and use of dual column for confinnation)
All standards and solutions prepared/utilized within method p
reauired holding times
External standard calculation used with r > 0.990 p
DDT and Endrin dePTadation < 15% p
DAILY OR CONTINUING CALIBRATION p Date analyzed: 3/16/04
/beeinnino of each dav and every 10 samples)
MidQoint calibration std run to verify:
1. Run midpoint cal std to check all analytes <15% Diff. p
2. DDT and Endrin degradation< 15% p
3. 1 of2 Surroeate % rec within laboratorv control limits p
SAMPLE CRITERIA
1. Bracketed by in-control CV s p
2. 1 of 2 Surrogates % rec within laboratory control limits p
3. Peak RT window+/-3X Std. Dev. of the standard's RT p
4. Anal=ed within working range of the curve(<highest std) p
I hereby certify that all the above information is correct to the best ofmy knowledge. All out-of-
control measurements relating to the method required acceptance criteria have been documented
in the above table along with any known possible effects on the sample .analytical data. i
Name: Paula A. Pulley Date: 3/30/04
(print)
Name: /&/Ar A.~/
(sign)
QA OfficecSigMlliaf Q kdL
Kubal-Furr & Associates
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INSTRUMENT QC ASSESSMENT SUMMARY
FOR EPA METHOD 8151A
For Samples:
I
lab ID# L04022607-0I
lab ID# 104022607-02
lab ID# ____ _
lab ID#.~•~~--
CRITERIA
lab ID# ____ _ lab ID# ------lab ID# ____ _ lab ID# ------lab ID# ____ _ lab ID# ------lab ID# ____ _ lab ID# ____ _
I PIF I COMMENTS
INITIAL CALIBRA TION:(at least 5 stds with one at p Date of calibration: 3/17/04
or near MDL and use of dual column for confirmation)
External standard calculation used with r > 0.990 p
DAILY OR CONTINUING CALIBRATION Date analyzed: 3/17/04
(beeinnine of run and every 10 samoles) p
Midpoint calibration std run to verify:
I. Run midpoint cal std to check all analytes within 15% of p
true value
2. Surrogate% rec within lab generated control limits p
SAMPLE CRITERIA
1. Bracketed by in control CV s p
2. Surrogate% rec within lab generated control limits p
3. AnalV?ed within working ranee of the curve(<hiehest std) p
I hereby certify that all the above information is correct to the best ofmy knowledge. All out-of-
control measurements relating to the method required acceptance criteria have been documented
in the above table along with any known possible effects on the sample analytical data.
Name:_-'-P..::a""u""la'-'A-"-'. P:...;u::.:l.:..:le"'y--,--=-------
(print)
Date: 3/30/04
Kubal-Furr & Associates
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INSTRUMENT QC ASSESSMENT SUMMARY
FOR EPA METHOD 82608
For Samples: lab ID # L04022607-0 I
lab ID# L04022607-02
lab ID# ____ _ lab ID# ____ _
lab ID# ____ _ lab ID# ____ _
lab ID# ____ _ lab ID# ____ _ lab ID# ____ _
lab ID# ____ _ lab ID# ____ _ lab ID# ------
I CRITERIA I P/F lcoMMENrs
INITIAL CALIBRATION:(at least 5 stds with one at p Date of calibration: 3LQ3LQ~
or near MDL)
All standards and solutions prepared/utilized within method p
required holding times
BFB Tune Criteria(table 3) p
SPCCs -criteria met in section 7.4.3.l in method 8260A p
¾RSD for all analytes < 15%(use avg. relative RF for calc. or
calculate cal curve with r ;,0.990)
p
%RSD for all analytes >15%(calculate cal curve with r
;,0.990) NA
CCCs ave RFs %RSD < 30 p
DAILY OR CONTINUING CALIBRATION p Date analyzed: 3/09/04
(beginning of each day and every 12 hr)
BFB Tune Criteria(table 3) p Time(s) of tuning: 07:08
Midpoint calibration std run to verify:
I. SPCCs -criteria met in section 7.4.3.1 in method 8260A p
2. CCCs %Drift < 20 p
3. Internal Standards RT within 30 sec of last check std(or cal) p
4. EICP area for !Ss -50% to + l 00% from last check( or cal) p
SAMPLE CRITERIA ~ p
l. Run within 12hr of last in-control tune p
2. Surrogate% rec within laboratory control limits p
3. TICs -ions> 10% of most abundant ion and NA
relative intensities of major ions agree within 20%
4. Analyzed within working range of the curve(<highest std) p
. I hereby certify that all the above information is correct to the best ofmy knowledge. All out-of-control
measurements relating to the method required acceptance criteria have been documented in the above table
along with any known possible effects on the sample analytical data.
Name: Paula A. Pulley Date: 3/30/04
(print)
N=, P@J:;;l ~
QA om~, Si,,.,rnre,&-
Kubal-Furr & Associates
Cf'ill"¥1' © t 996
I
.,,.,_,
PageJ_of
FL YD-•--Chain of Custody Record 1 17ec~/4voti-fi/f{Z_ Project I ;;;ite Location ;J../,C(.I JI 816 E. Durst Avenue, Greenwood, SC 29649 (864) 229--4413. Fax:_ [phone] ice use un,y 17 '-C,v,lit---%8'7, ~{_,, Laboratory Cerlifcation Numbers:, SC· 24110, NC: 25, TN· 2923, VA. 77
c3iti;,-,t..,,.r;,z _,i,-J RepjXt 10 Copy~ Reporting Requ=ents: { J Standard { } Data Pack.age (Specify Lave/) nsrchase Order ZA,;2,,, ~(8(_ c::.wc,1,1.~ Leve-z. p::::__ ..vueeied By Atmospfler1c Conditions Required Parameters, tainers and Preservatives State Quote &e& P-½.+J ,1_)G ro Jonaf. LOQJn Special Jn:11.tuctions NOTICE: " "'' ~ .J -• • i ~ ~ ~ -C" ICl j t! 8' f ! ~ . \J ,_ ~ ~ ~· 1, ,._ ~ '8. • .Ii '5 t,.._ ~ ) ~ al E } ~ ~ }l 1 } ~ ~ t . " ~ ~ '-.l )! ~~-·· 'i! E ~ ,., Sample Collection " .;i ;l
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' Cooler l~Mable): -On Ice: Ye No Temp(C) J.J.
Custody Seal: Intact / Broken ~ Matrix Definitions 1 -Drlnki Water 2 -Clean Water 5 • Groundwater 7 -SoiVSediment 8. L uid Slud e 9 -m ~ ~ -g 12 -Air -Davis & Flo d, Inc. y Preservative Oefinlllon,s A •None B • H2S04 C • HO O -HN03 E • NaOH F • Fltered G • Other
FLOZ _01 (02199) ----

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- - - - -- ------ - - - -- - -DAYIS:;:,::
FLB'YD lmr""""1Um1J"78'ni"1 Chain of Custody Record
Client Project I Site Location 816 E. Durst Avenue, Greenwood, SC 29649 [phone] Fax: [phone]
Kubal-Furr & Associates 61621.01 Laboratory Certifcation Numbers: SC-24110, NC-25, TN. 2923, VA-77
Simpsonville,SC
Contact Report To Copy To Reporting Requirements: [ J Standard { J Data Package (SJ?f!cify Level)
Greg Kinsman L.A<'i~v c/1,1,..,~= -_k,Fµ. ~ <,t12-;;>,,_ -7?c,,,,;d Cc'Vc!Z---.Z:Z::::-
Collects~& ~Al.r;,PI/ / k,'7 Required Parameters, Containers and PreseNatives
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//// I/
~;!111/P_ t;/1/ Time Reliquished By Date Time Rcrd By_e:_ 1-Date Time -r /CS-/{,, ,,Mo+.Lo4-1116" / )'tr 1,r,·/J • -----R•zrte2._ Date Time Received By Date Time Received in Laboratory By Date Time
,, .. ~ .. n ... rl /SIL I O,..,,,__ ... l"I I .fir ('J . ~ ' • -3.3.c,j I "'+-/ '5
1c;omments
f!.ou7t /\/ e ¼,I /!?2.,l..j"
Matri,c T e Definitions 1 -Drinkln Waler 2 -Clean Water 5 -Groundwater 7 -Soil/Sedimenl 8 • LI uid Slud e yp g q ' 9-OU 12 -Air
Preservative Definitions A-None B -H2S04 C -HCI D • HN03 E • NaOH F -Filtered G -Other
----Page / of
umce use Unly
Purchase Order
,,-State Quote --
~/\le
LOQln Speeial lnstroctions
c< :, I ; ~
0 • ~:;: ,._~
C ~ ii ~ " Fraction HOT omments
(JP ..f°Ee 1Ac</:. o, tJi/MV' lt,f,),//
()-;, -.
OU.. Pt.Gtr,,-&vi! s&..,,
OQ l;t.,n,,r 172'" .-<-r ,{~6( I
05 ·?.&ct-n 5t;-"t.,tiJl., wlj;<l.(,
0{,,
r"J7 oa
Quick TAT Ship~ "' CUEN'!
y~ "" fWEX
lfY, spe : Airbi/J Number
.,--days
Cooler ID (lf available): -Onlce: ~o Tem~{C)~
Custody Seal: Intact I Broken I tCn6'
Davis & F/ovrr inc. y,
FL02 _01 (0:W9)
D.AJ,7IS:=
FLB"YD lld1 I " ~ ltnlm:
~/on< :/4 , Pm;«t I Site Locat!M
UAL-fv.Z-1-~ I/Cw.A. -S;/~_"13'7, ,.Jc__,
Ch . am o fC us 0 y t d R ecor d
816 E. Durst Avenue, GreerM'OOd, SC 296-49 (86-4) 229--4-413 Fax: ( 864) 229-7119 Labofato,y C-ettifcation Numben: SC· 24110, NC. 25, TN· 2923, VA-n
. 't;:,:z.,.,,,. c,/A,vi) lef-,ff-g.
Report TO
L,.4v,!; FC /U,,/Jt&G Copy To ?<."I" Gf/272->2 -T/c c,..-/-
Reporting R&qUiremt:nts: { J Standard [ J Data Padcago (Sp«ly Utvel) ,:;.;,;c,1,-.,. ~ _..,.,,., -A Almospheric Condvons RMiuired Parameters. taine13 and Preservatives
~&J_k-.,-11>1<d>J /f<-r,7 lvk?;,,-12.J ✓l/4 p(./;zfl. C.-,n ,irvtaf
NOTICE:. j
I ~ ~ g -. .... 15. • .l! ~ ' E ~ =1J l ~ ~ D ~ D • E Samole Collection .§ -;, :!I :;a
Samnle Descriotion Date 11me Time Twe Total
AA--s-L/ 3/J/4{ /.s3o le -S 3 ?c P-s<f 3/2/4J!/ 1710 )( .< 5 ;,c
C-i<? 1fr /.-{ //oS' IC s 's ><---rrz,1p !5LA;l()f< 3J~,j,'( aR,z, )C l ,;2 ,>c rr-3'-I 3f'IJ,il {3o -~ 1( ~ 3 )<' f'F r::,;i 3/,141 1'(3.S" }<, ~-3 I'><--··
..
--,
// -I/
ff/ //
-~ ;r-:' By ~ /? f(-----:, j;t;f,/ TTme
~~vf?Zd ~~ T,me Reliqui::., ""'fr-~ Date . ,.,,. d.-A /"'" • )fl~ ,t' -P'f /o'(,:; \K -,. },< J r,,.l )-:> .1 n Rece)"' By/ dee T,me ReceNr:1.
oy ~ ,,,?~ ., ;., 1 L/
T,me 'E_• c,y~ Daffi 7,me ~ t:&i2r.At.cit-% '( 1f?< n~. .. ~ , /OMO 1/'s-w fr. . 1nJ/1 s 5. 5.otJ. tJi I 0 , '-'Ufnment.s ' -.
~.m,,iJe Wc:'¼.,J -Matro:: Type DefVlitions 1 -Drinksng Water 2 • Oean Waler 5. Grounctwater 7. Soa/Sed1ment 8. Liquid Sludge 9 -Oil 12 • A.-Preservative Oeflflition,s A -None B • H2S04 C • HCI D -HN03 E • NaOH F • F~tered G -Other
- ---

-
---

-
-------
Page of
e vse
Onto,
State Ooot•
/JC,;
LOQJn Special fnstllJClions
t--~
I U! 0 Q .:; . ,.~
Cb •• . " ;J ~ .s
~raction HOT ..r mmenLS
I') I .5-,; ,,,-----;;;Fi/-
o:z. d7a,l,,_ ;2(.6Js II
o:z.
01
1J11-
05
01.,
Qt12 ~~ = ~---
If Y, : Airbr7/ Number
._.-days
Cooler l~ilable): __..
On Ice: Yes No Temp(C) n---b
Custoctv Seal: Intact I Broken N
-
Davis & Floyd, Ir
FL02 _01 (0~
--
- - - --- --- - - - -
Chain of Custody Record PageLofj_
Client Project I Site Location .s;,fz..g 816 E. Durst Avenue, Greenwood, SC 2964!l {864) 229-4413 Fax: [phone] vu1ce vse uniy
Kubal-Furr & Associates 61979.00 -PCa,v.~ -71 MC-Laboratory Certifcalion Numbers: SC-24110, NC-25, TN. 2923, VA-77
Simpsonville,SC
Contact 7ArlTo Copy To Reporting Requirements: [ J Standarrt { J Data Package (Specify Level) Purchase Order
Greg Kinsman A,/?1r!' cf#vk/ft'.-~fci,1-9e"10¥1?<. -'7'=v1 C£VeL :zC'
Collected By . 1 Requimd Parameters, Containers and PreseNatNes State Quote
ffl& hN12r-W I t/f,1 l.J,Az,72:,z.J C. (__ . ~ 1...ogin Special Instructions
NOTICE: i . ::t-~ a; I ~~ ~ ~ \j ~g 0 •
C ~ C " ~ . . 5 g 0 ~~ 0. • ... u ? C " E ~ ~ ~ ;~ f;l 8. -~ a; ~ " X ~ ~ " • s E ~ E E 1 ~ Sample Collection ·~ 0 e ~ , u " z . ..J Samele Oescriction Date Time Time Type Total Fraction HOT ...,ommen,s c·-,2 g, 3/J-/,,</ /70-. X ..s Pjf'J, X X o, ~c=-~ Cc-33 3);-j,/ /7/o I'>< .s 3 X O'Ji olo:_cze-#' )(./,2r I I ,,<:,;:;. -{:,( '3/9,,,f,j lo/o IX .s '3 'x 05 ----r:..s-< !Y9/4</ JS¾ X .5 3 X OLJ...
V-)3 1-1/9/4( /?o~ ',( ..:5 l/ )( X OS ,,t.,1f :l?o,,Jt:. ;,, !'1 ~,-· ~ )C ) 1..2 If(_ O/,, " ~ 1.1/21/ of-sv
-~
/ /
/)/7 I
~ra;hedBy IJ -. ¾Pl Time Reliquished By ~ijf Time Rel:he~:Y ~ Date Time Quic0 Shipc!J' -i'.d!R'. '/'J /7't,J_. .SC-'c... ..,,z.c _f,M ofy3 -~1Z'oa: J/4.'{) y N "' CUEtIT / r ,r? .-.,
"' FEOEX Recaivpd i'y Date Time R•tt•dBy (2,,,A, . Dare Time eCeive(JLaboratory By vate Time ,,city: Airbill Number
(./.Sec:.,;,: ,+2;4 1/,jii Of(S-1/.KM"i 1v'1,¼¢-0?6 'ffi<,.._,. t9 }'he,._ OJ· 1.J. <l'{ /is '!0 days
11.,;omments
V iJ07c': -;u Td (, 1Vr71,,:; 'i3/-0J£,P ,,., 1<,~_,,4-f',2,,>cE-c;ro;W Md¢,) -!',!-,~ bM,✓ ~/7./j
'f,oi.JT,,.;;;-?A/t?c.-~G Cooler ID (if available): nc,u..
W1:::7--{..J CAN Pv1.-._ r,,..,-Tv<-~ 77h£ VG!C A!77zt-:f' • On Ice: (§}No Temp(C)_3_
Custody Seal: Intact / Broken Gone)
Matlix Type Definitions 1 •Dnnk1ng Waler 2 -Clean Water 5 -Groundwater 7 • S01VSed1ment 8. l1qu1d Sludge 9 • 011 12 -Air
Preservative OefiniUons A -None B -H2S04 C -HCI D -HN03 E -NaOH F -Filtered G -Other Davis & Floyd, Inc.
FL02_01 (02199)
Kubal-Furr& Associates
-£m•iro11111e11tal Co11::1tlta11ts-
Low-Flow Groundwater Sampling Log
Proiect No.
Site locc,'ion CNA/Tlcono • Shelby, NC
Field Personnel __ ...,(.:..-..._ • .!.Kc:·,.,l.!.\'.-::...·<-=j-----
Well/ Sample ID TI--Z...
l I , J_Veo_t~er Condition r Io 0,Jv 0 So<; Sample Dale ~ '1-, Q '~\ ArM,aicme C / / L/ I Sa/")"I lQ'4 L
DescdpHon ol ~~~:~~~~~ Cosing Type! r 1./ 0 \ Locking Cap · Di;~~~ij '2.,
0
,J
Pccge Melhodl (,1(1 Lf\ r.\ .t::[; 1:1 \ Sampang Method\ Cf, 1.,U'\ d f:z:G \
Purge Start Time( l ;5 CJ'3' j Purge Stop Time\ \ I {/C) j J Purge Rote\ ·3-z_,c:;-:,11m;n\ Water-Level Measurements Field Parameters
Interval
0
I
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
ll7
'18
• 19
20
Elcpse Time
(mim)
Yi' --:--,
[O
\ '7
'? r)
2.C:
DTW {lea~)
32.9,
·2c::: <;! :; -,c .• ,"'~ ~·, C,
·-:::1•\n(
·:J.,~ r,"j"
X:. ~q ·-,L
I
Samples Collected
fntervOI
0
I
2
3
4
5
6
7
8
9
10
It
12
13
I 4
15
16
t7
18
t9
20
Temperature
rci
i'],-J C/
i7,"7'1
;<,.i ".J--
IQ ,d.l/
i<Z 5.., . ' . ...,
Specific
Conductance
(µS/cm)
.,,,,,,--
--2, LL
~q
".3Y
-::i,L'
"Ai-
. Container Description
pH (su)
/
,,_, cJ.l
r;,. n I
r.,r:3
{,;, ,...,, ,0.:::,
c;_ ~ ,c,·,:_...
Turbidity
(NTU)
.,,,-.-
is ,:;-c;-
-~~
z:,
·6(: a
'
Dissolved
Oxygen
(mg/L)
/
i.J.~"/
4. S'C:
u. 1;c.
Lf .2.C::
Lf .c~;
Preser,otiva /" \
ORP /mV)
.
./
ii Li _(,,
I1?,.C)
;I',(.~ _I
01,<
°il.l\.
I
Remarks _____________________________________
_
Parameter Conditions: pH +/· 0.1 standard unit
Turbidity +/· 10% above 10 NTU
COND/Temp +/-3%
+/-I NTU below JO NTU
DO +/-10%
OR? +/-lOmV
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146 CNA/Tlcor.o
Low-FlowGroundwoter Samplng tog
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Kubal-Furr & Associ,1tes
-£1wiro11mi:11/ill G111m/111111~ -
Lew-flow Groundwcter Sampling Log
Project No.
Sire Locoticn
Field Personnel
CNA/Tlcona -Shelby, NC
: lj. Well I Sample ID TX -/ '3/ z, ti y _ t';eother Condition .Ctt J,
Sample Dote ___ ~-=-~----_ Arrival nme cJ ,..) C, Sample nme~-~-r--;--''--:,r:,~---
Casing
Diameter·
Description of ,\.le•.Jsuring~ Casing Type~ Loc',::mg Cop[2] Point (MPI~ ~ V
Purge Method! z~(..•~v);z J Sampling Methodl:=:Ji=a/::,'bt;:::;:t::;[;;==------;---==
Purge S,crl Time\ j/)/2_ \ Purge Slop Time\ /[! f 2.-\
Water-Level Measurements Field Parameters
lnlerval
0
I
2
3
4
5
6
. 7
8
9
10
II
12
13
14
15
16
17
18
19
20
Elapse Time
(mins)
C3
.s--
/u ,~
Jo 1-)
'21.:'
OTW {feet)
3),L/1
5'-1. D[-
5{ -) .~ l
:S'f.(. (.,
3'(,.r/
5"/,f(,
3,1,17
'
·-
Samples Collected
Remar'<s' • 1,.l/ · I;,)
Parameter Conditions: pH
ln1erval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
'T emperalure
(OC)
/7,ltJ
/9, ?,~
l;,-S-}..
:}o,tl-(
Jo,3).
79H7
Specific
Conductance
(µSiem) -
r-"7'7
&'-o
,;~
,,f(
fl f
7l
Container Descnptron
+/-0.1 standard unit
pH (su)
';. '1-,l
l,,uJ
._\. t--s-
--5,{o
~-s-? -,,.:) 5,-o •
Turbidity +/-10% above JO NTU
COND/Temp +/· 3%
+/-I NTU below 10 NTU
147
Purge Rateft. >c ,,1 mliminl
Turbidity
(NTUJ
--
/.C
'"' /l
lb
/~"J
/(,
Preservative
Dissolved
Oxygen
(mg/L)
2,')L/
277
"3_oJ-
-J,;3
q_o,~
'1/)f"
DO +/-10%
ORP +/-IOmV
ORP !mV)
Jt.,__c;,7
J 9r, I
I 'Jc, o
tf(., 9
lfs. J.
iff.-..r
CNA/TICOna
Low-FlowGroundwc!e< Somplng tog
Kubal-Furr & Associates
-E1111iro11m,mtal Co11:-1tlta11ts-
Low-Flow Groundwater Sampling Log
C..f'/... ?/
Project No. ---~...ZW=::,,S'll""-'_/ft....::..;;,J_GL_,c:J-'-/
Site Location CNA/Ticona • Shelby, NC
Field Personnel
I
I b K \ i''-1...-i . . TI -3 (:JP-7 (:(1 • l W!:,g!{'er Condition <; '-'-i'-:'0-( ( ¢ 5 Sample Date 312-C::} Arrival Time l Y ?~ Sample Time ~ {;-{ <
wall / Sample ID
De,criplion ot ~·~~:~~~p~[ill Cming Type I '(V cl locking Ccpw o,;~~;;,I 2""..I · •
. Pu,ge Melhodi -.1--i J. n c\ fii<; I So. mpling Method! cr::u, ;,\, cl-fus I
Pu•ge Slort Time. L __ .7 \ Pu•ge S',op Timej / C,3< I j Pcc;e Ro:ej 1. SU.,,,,m,0) I Water-Level Measurements Fie!d Parameters
Interval
0
t
2
3
4
5
6
7
6
9
,o
"
12
t3
14
t5
16
17
t6
t9
20
Elapse Time
(minsJ
,,--/
,.-....,
i ,-,
iS
") (\
,.., C,
·~o
-:C,'-,
4o 4S
'70 c:;_.,
&:O
OiVI \feet)
137, '-/7
::c,.; q..;
;,;~ 2.6
3\./ 75
''3'-l ·-y~
''4), 2i-
-::,,,1 2f
3./-,o'
·, (/ 'Ji.
7 '· -, ,.j . r:~ ., ' -
-~'1 °'"
-:z, s . u
J '-;'.',(
~
Samples Collected
1r::~fVa1
0
t
2
3
'
5
6
7
6
9
10
"
12
t3
14
15
t6
17
ts
t9
20
Temperature rCJ
I q ,-c;-G,
;.Zo,l/ '.i
? 2 7<;
'2 '.2-, "l ::1
·7? 21
-2'3 2Gi -2'3,0·
2::; ,G;?
-2,_l/,ll I
--;(_ .2,;-.
J,~ :• C ~ .. J
-z.c' i '7
Specilic
Conductance
(µS/cm)
'),(r,
:=,-\..\
·--:t---l,
'H-q--
;}Q
+S<
::i,<2
<;Zr,
<Zr,
<;?\.[
qc::
<1.-:Z,
Container Description
Turbidity +/-10% above 10 NTU
148
pH (SU)
L/, Cf-;+,
'-I' l]S
c;_o7 _
c;_ u'--f
c; .cc
c,-cJ;-
c;, r,c;
[,c;-, e,/
c;, C2-
-c;, (;c;-
•:::· .._ ,..-t ;'•-,
c; !'•➔
iubid1ty
[NTU)
,c:;
r,· -, <.J
C-l ,.
(J, C'
::;,i,
'7,L
-, I ~.
\ ,CJ
i -~ ,',
o -:~;s
I,"::;·
l, ·7
Dissolved
Oxygen
(mg/LJ
I , (,::}
i. ('.,1 I
I, ql.
l,S"".:1
1 ,7 $?
r, ·:., b
i,70
t. J:J..-
,.2-G
. I, O'f
1,n-~
/.02-
Preser:,otNe • /'. \ lfuj1)f (AJ
ORP {mV)
(; /. c..
(,.•') '1-s-x,c.:
S-:/-.7,
c~ .Ir
c:;q,c;-
c-" x' ..-.,-,,
-,.~ l/ -r. t
~>(2. 9
hC/, c1
·10.1;.,
e,~,-
I
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Kub.it-Furr & Associates
-E1wira1w1i:11ti1I Co11s1iltmW-
Water-Le11el Measurements
Interval
0
I
2
3
'
5
6
7
8
'
10
II
12
13
14
15
16
17
18
19
20
Etcpse fime
[mins)
0
,S
(D
/">
Jo
:Zr-
.Jc.1
JS"
i/o
'-1~-
&;
,.':N
OTV✓ (feet)
s3.9)
i,r.~t-'
sl.-s.1-
3[,,!i'f
~?y(
37,?u
s?,9o
3)7~-
3S-.t J
?,~IS
s.1~ ;c
3,\:-.'(o
f
Samples Collected
fl/f
Low-Flow Groundwater Sampling log
Project No.
Interval
0
I
2
3
'
5
6
i
8
'
10
II
12
13
14
15
16
17
18
19
20
Temperature
{OC)
-!?, ,_;-._s-
/Cts-3
/ 'l;(.,2
/1.17
fe.J..s
Jo,•IJ"
JIJ.J-;
k.-1J
;;b, x>
1(,,3.r
Jv.'/2
Site locativn
Field Paramelers
Specific
Conductance
(µSiem)
-'?6 , -
2"'7 ;-
Jr.,
4
J_{,
Js
7-S--
;zr
-~
).~-
pH (su)
-
"7, .23
l·. 'lo
{,o(,
.5;~;i
&fg
5-;Jr: .
.::,-:,f 6
~)1 ,..) '
~7J
-S;b,5
.s:(.f
Container Oescnpl!on
CNA/Tlcona -Shelby. NC
Turbidity
(NTU) -
00
S:<
So
if'-<('
S'o
S--< _;;o
i/.s,,
L ~
, .. )0
, ")'.::
PreseN□hve
Dissolved
Oxygen
{mg/l)
---
S:'/"I
·-'>,Cu
s; 3c.,
.s-,S).
S";l'-j
r:[ i/C:,
0--: 'l-I
L/.91 ,--7 IJ ~l1
tl_,y,;).
((.77
ORP (mY)
-
/J-J '<, , __ <',.
JG:i~ I
109,
11::::7
/-;b, _J
;U,,3
/t..~C.,
/)3(
/71/.G,
t?s:)
(77.0
Remarks .S/✓b;.-;ti) ?t,.-;uJvJC)rf" 1-[ i11rtrt ._,f,"'-;ZJ.-..i . ...fi-e,-...,t.·) p.,. ~1/)-'l.,(>· 6...,:~/'I.,'. 1CJ A 1.n.., ~-J_~p~~..,-:-~r ,IA,.; n, ?ti:lc~; :V/{lvL ,· v,·..1 ,:,"t. -,:..,c:?) UT ,1.,::,-,•;:_;z Iv.:.... sr;1;1~ ,(,;:..L ·,t_ ~ 't-J /tt,lre-"lL..._ 2/~ ,v,v C(.1c-J 1,E," ..Si' :J/rl./2€ ,.,.vµJ✓/0..:!2..<... 'D@ 'M) ·-p S"r,,1PL ,;-,v;,)L ?v,¼ "'--tf f:r Parameter CondHions: pH +/-0.1 standard unit COND/Temp +/-3% DO +/-10%
Turbidity +/-10% above 10 NTU +/-1 NTU be:ow 10 NTU
149
OK? +/-lOml/
CNA/TICcr.c
tow-FlowGroundwoter Scmplr,g leg
Sampling Log-Grab Water Samples
Project No. 26QS11
Sample ID 'Ycf lU -/ I
Weather Conditions _!~,,.,,,.,7
Sample Temp. (QC) i7,@ (
t)J-1 r ORP (mV)
Method(s)
(f.:ilJ
.. f/,1 c__,. /4J,u 77/~Z,<1
· Remarks
3/1 (u Sample Date-+--.,__~_'-' __ ! __ (
Sample ID ·?C0-3
Weather Conditions ..li..,,J,':J
Sample Temp. (QC) /fr, 9(; ·
ORP (mV) /lo, f
Method(s) lfx,,-
Remarks
Site Location CNA / Ticona -Shelby. NC
Arrival Time _G_·r_7_lf_,__f __ _ Sample Time cf),s-S-
Duplicate No. _____ _ Field Personnel _...,d/"-~--___ _
Sampling Method , ·a,v3 1¥t'ft -S~ 1,;,-r-
Spec. Conductivity(µS/cm) l(] pH_7_,s_2~
Turbidity (NTU) __ /_, 7__._ _ _..:DO(mg/L) _J_' _. s_· -~--_
Container Description
':ZK1/t;J-t/
Arrival Time __ C_)__::_;y_' _/_,.::_' _
Duplicate No. _____ _
Sampling Method
Preservative
/./y
Sample Time_o_-_f_/_0 __ _
Field Personnel __ U/<_~_<::.._· __ _
Spec. Conductivity(µS/cm) t( 9: pH _·1..L.L-, c;.L....-'-'1'---
Turbidity (NTU) _.:;..,.d,_, _3 __ -'DO(mg/L) --=c,,'--2-'-', f"-·_,_9 __
Container Description
3K<'<,Jt(
Kubal-Furr & Associates
15 0.
Preservative //c
Revised 7 /30/02
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Sampling Log-Grob Water Samples
Project No. 26QS 11 Site Location CNA / Ticona • Shelby. NC
Sample Date 3 l_~ /0•1 Arrival Time o'{ io Sample Time __ Q~S';~'=2-_<~-__
I Sample ID e CL,l;J -Lf Duplicate No. Field Personnel __ 1,_t-_w ___ _
Weather Conditions
Sample Temp. (°C)
0RP (mV)
M;Jod(s) vck· ,·
Remarks
0 L.~-"\ /\'/ "i"D0
5sampling Method I
i 9. CJ ( Spec. Conducf,vity(µS/cm) . S-0 pH _~_--::,_,1-_-_,_I __
Tu~bidity (NTU) __ Q_,~3~0_-, ___ D0(mg/L) __ y_,_,· __ '<;___c'f--__
Container Description
:?t0,;-,(
Arrival Time
Preservative
/fC./
Sample Date -------Sample Time ______ _
Sample ID Duplicate No. -------Field Personnel -------
Weather Conditions Sampling Method
Sample Temp. (°C) _____ Spec. Conductivity(µS/cm) pH ______ _
ORP (mV) Turbidity (NTU) ________ D0(mg/L) ______ _
Method(s) Container Description Preservative
Remarks
Kubal-Furr & Associates
Revised 7 /30/02
1 51
Purged Well Sampling Log
Kubal-Furr & Associates Project No. 26QS11
-E11virom11e11/ol Co11s11lto11ts-Site location CNA Holdings/Ticona, Shelby, NC
field Personnel C!.,k
Well I Sample ID HI/-L/12 _g / 1;· WeaEierCondition S<.;J,;v,<,L-/ (os
Sample Dote / 3 ;0'; Arrival Time O // 3, Sample Time ( /(J ,;J..s"
Description of MeosurintBJ·· · c • T I r I I · I . ~· 1 ;:ing[2:J Point (MP) /coC asing ype "-..)_J Locking Cop V Diameter ,
lnche~
Tolol Depth of Well Below/
MP? ,S-a, 7 f-,.J CommQn Gol!Qns. Qer FQQf CQnv~rsions.
:S<:r'-13 l 1/~ in Well Cosing= 0.064 gal/ foot Depth to Water Below MP?
feet 1 1/2 in Well Casing= 0.092 gal/ foot
Column of Water in Well? I J.,J-.r' lee"t 2 in Well Casing= 0.163 gal/ foot
Gallons of Woter per Fool[ a./t3 ,;al/faoll
3 in Well Cosing= 0.367 gal/ foot (see chart)?
3 1 /z in Well Cosing = 0.500 gal / foot Gallons of Water in Well? (9<]_ 2a1I 4 in Well Cosing= 0.653 gal/ foot
~97 J i Gallons of Water to be 6 in Well Casing= 1.469 gal/ foot Purged (3X)?
Purge Method? ?'f.n-tt.dl. I T otol Gallons Purged I 6 gall
Purge Start Time I
Volume Purged
Time
Temperature
Specific Conductance
pH
DO
Turbitidy
ORP
0<_7.,S-0
Initial I
0 aal a gol
o9-s-o /ooo
j'?_fb,c //://0 'C
'i-t' µS l/ ·3 µS
~7,1) Lll)J: ~' stdunHs std units
&,11mn/l ;,3, ~n/L
o:3~u 'Jt NTU
/7'/, 7 mV :J-JJ, j mV
I Purge Stop Time( /./J ;}a
,2 ,3 4 5
I L/
"°" &,
gol nal gal
/olo /o.2o
/£,(,f,c /(p,fr/ 'C 'C 'C
L(3 ,s tf'3 µS µS µS
Cf, Yi?unils L/. 9! ,nils s1dunits std units
/, 'f~n/L 1,-)sJmg/l mr-i/L mg/l
13 NTU /~'?' NTU NTU NfU
217.1v 1J'( i'mv mv mV
Samples Collected Container Description Preservative
Remarks 1//1 le) ,(,fll
Parameter Conditions: pH +/-0.1 standard unit '. COND/Temp +/-3% DO
Turbidity +/. 10%above lONTU +/-I NTU below 10 NTU ORP
152
I
+/-10%
+/-10mV
Revise 5/28/02
11
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Low-Fie\,: :;rc•Jndwater Samplir.g Leg
Kubal-Furr & Associates
-E11vir:J111t1i:11t,1f Cll!f11itmll~ -
Project No. 260S11 ----------Site Location CNA/Ticona • Shelby, NC
Field Personnel <Sic\ \'.:c..J
Well I Sample ID -id :\::I: -rt . --, l , , 1 · . "...(,~Ve;:}J'er Ccndllion ...-, t , .. n n ... ¥ i h, 1. (,L -st 'S Sample Dale . ,:1 '3 " f \)ii. ACNal Time I s ·o::, Samp,e Time I J.1:,,5 -~
Descrip!ionofMeasuring~~,;· CcsingT p 1 .. 1'__?.:1' p L k. C CZ] Cming[h] Point (M?j ,y-,l_... Y e _:......i--..,.-c.; oc ing ap Diameter .-_ . (...L,
--lf'C!'i,tl I
Pu,ge /,lelhodl Cjh,;.r.0.:\i/7 I Sampling Method) . s YL-{,,Y\.,cUi5S I
Purge Start Time\ (i..,oo I Purg: $'.:;p TI:-ne\ i ']. . .i)l::~ l Purge Rate] :2,Wiminl
Water-Level Measurements Field Parameters
Interval
0
t
2
3
4
*5
6
7
'li'f 8
I..,..,__ 9
10
ti
t2
13
t4
15
r t6
17
18
19
20
Elapse Time
{mins)
. .f5
5
\ (,'
}<::;"
-1-Q:,
'7e:.
~0
~c;-
'-{ D
lf "5
St>
q::,
(,-.i·~
{~.<
. :::i--1>
i<
';ii) ~-c:;
qo
vj c:;'
-= u-c,
,...,~ ___, . ' \ -...:,
-~q 9. 7.
1·~(2 C/-..7
~~-qc
-:;;';< "iF
<'l'1< ' . ', -~_c,c
~1-oc J' I -··o _., '.i ·J. c·,
I "i'l.SG
=3<;( C1 I )
;:; ~ <;,(}-
·4!, i2'::;
·::3){ -'1 I
3'3 ,'11
·3i .Cl':-·
l~I<' '°'" -£Q-, 5r-
'2i<;Z/"{(
li?1. 0/1
lnterYOI
0
t
2
3
4 5
6
7
8
9
10
ti
t2
13
t4
15
t6
17
18
19
20
Te,":'.;o:roti.:re
i'CJ
if, e,'?,
11.1-:;
I 'f,'. 'l --:Z,
1~-~
j Q,4 i.j
I Ci CJ'(
IA,oc
i (,( C-1(,
\ ':i ''?/"J
l<i. q,
10.c<.',
i"l.1.'.r'
i ") '-32~
\ '1, i I
I C/' . 1 '7_.,,
i 9, _C",(b
I ti ·ctJ
itJ.13
Specific
Conduct once
(µSiem)
(, I
l."7-2--
(o '--1
1;..✓,
(,(,.
(,, ."J.-'
0':i(
{,.._ Ci
( ,.J,:,
(1--
Cc,<;(
v>q
C:>vi
C,~
. (:..:.l----
r:q "-' G't
G'X
pH (>u)
c;,c,(
/~ ,-,:')
/ /Lt
'"7 (p.j:;,
I,, /:)--'
(., • I C-,
r;,, I ::y
I r,., •I &
(, . lf C,,:
c.,,2./,
C,, . 'J..i
0.? i
' G,, 2-b
r:, .·2-0
C, '\ 'i?'
G,. { ::}--
G .It..
G. i (:,
Turbidi:y
(NTUJ
-~<
'1--?
Ir',
~le:;
l I
·1-I.
7-, c:;---
41
<;; I
' C.·7
LI-,'-i
-~./'
,,, C Ac :0
? 3
:::l·, 9
LI q-----
:;,9
'3,-:Z,
Dissolved
O,(ygen
lmg/L)
c;-, ('.::Y
L/, ?,(
-~-+)
·::?. .qc;
;;;. 2.½·
·? ':<r~ ,,.;. -/" J
i 91
I.~
3,q<z
2 _c/1-'
2.Sf.
2, ·?2-
2,/~
.2 ,cPi
2 .(~.Ci
i.~
I 0 (:,
i-91
ORP (mV)
,.
uc,z..
U-~. 1;.
l/7 0
39 S'
Ur,L,
-~C;. /
:;<;, 9
3\./,1
°J,T'\
2C .i.f
:Z.1-.i
?t-, '7
7C:..7
'7 l/ 9 ~ ,.
2,C,.~
J,__Cj', l)
:2.Cf. 't?
:2..cr.o
---------------------·-'-'T's..-,-\:vi.c,.,.i ----,'f;i:""c~"'-\ -"fP"'-ir,'>fje"-',1 ..... ~__,_,._I s«-i, ----------------------//\
Parameter Conditions: 00
Turbidity +/. 10% above 10 Ni'...' +/-1 NTU below 10 NTU 0.:~P +/· !0r:,V _-a:~
G..e,h.£,1-G.~-ur S·h:;.\?f:"C._J, C\.3c.,1h. CV.An"'? <,;;it-.. i Kien-,o..l i-ec.clik~'_, ( Q Io: cf ctv~ . %~c,f-ed. (::0i o:4 2 off a. s_:.{li"-,..f-et,J ~ cc-nd.S o-,, if. ,a):1cc\-chf @2' ic/ '-13; uz,t--+o ~-¥ 01 l f{)r s:e,..__e,C'.:. ,, CNAmcono 1 5· 3· · Lc-w•FklwGroundworer Somplng Leg
--
_)
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Low-Flow Groundwater S_omoling Leg
Kubal-Furr & Associ;1tes Project No. ___ __:2:.:6c:Qo..:S.c..1.:..1 ___ _ -£11viro11111t?11tal Co11s11ltm1ts-Site Location CNA/Ticona -Shelby, NC
Field Personnel t:, k: / LW
Well I Sample ID /-+?+-/ 7
I . We_¢l)erCondition Sunni/ f.,l,' '-sample Dote -3 -3 / G --q Arriver nme Q Cj / S Sample nme i "1/.:. C..
. DescriplionolM~osuringc-:-:1 Cosing Type! er· \ locking Cap 1,/ _Casingr--:;-i Po1nt(t-.1?J~ ~ D1omete~
Purge Me/hod: :i r1.\i,d f:us I Sampling Melliodl -s·i::ii..;~d+-ii':::, 1
Purge Start Time / (X;C, \ · Purge Stop Time\ \ ?-C (-.. \ Purge Ratel 35D.,,11"',,,j
Waler-Level Measurements Field Parameters
Interval
0
I
'
3
4
k s
6
7
. . ')(;,_ 8
9
10
11
12
13
14
Elapse Time 0 lW ! feet) (mins)
y; ?0.4c
,,.-·
-7 ~o er:
; D l;z.( ,r,, ·1< -Ser ,CF
'7 0 l I~~ ?3
n.S ·::z.g ()"" . , 1 '->
,--; . ' '?L· :::;y: ,c;<
-~c;-·?.7 Cl{; ,,:,; '-I
i lr, ;2,Cf,r, C:
uc 3~,C[
c:,[) 1-qx",9 ( q:; 1:10,g']
kA-" I.; ;J ?.:< ·;
f.C:: :;r /ii
·70 I::; \0,
lnterv61
0
1
2
3
4
5
6
7
8
9
10
II
~J.12
13
14
Temperature
r='C!
I 1-,CS:'
1 ·'1-.'t"J
I Q,Lj"}
l~,K
/Q',L[(.j
I CZ .0 S'
i Cf. t:l)
rv ;10
/<(2..0
JC, ("(,
. CJ co I I •
ICJ,1:-('
i iJ. ::z,7
'
Specllic
Conductance
(µS/cm)
,,, .
i,,, I
(1<7
r:Oy
t:;r~
r;~6
&1
r;,9
(./·1
r C, \o -~
r,,z
c, </
c/1
(,., q
pH (su)
s,qb
G.ccr
G .. l4
(,., i '3
G,1 cr
C.U.o
r:::, I q-
(,.lb
,;, ✓5<:
--.·7fl
/_ 7 I ~·
I'.',,-?)
,_ ..., P-, ~
Turbidity
fNTUf
~
?,-5'
•"7 .//, ,,:...., .1-
/0
5,;;
\ I
I ::t--:;,-,,;
I w. f
'is,I , ·2,
Li,'-]
3/
7 . ./~
DiHolved
Oxygen
(mg/LI
~ ---·-----
c;-o'.t _,', .
U~0
~ =+-i
'7 ,C, r;
-1. 2\.J
7 (,-,0 . ~ )
I C-11
I. :rs ---
~.LjX'
,-,,,C,7·
?. c:?::,;
·7 -2'2-
·7_ . I c;'
ORP (mV)
-
Ir-,-,, i..-'.'"7i /-
u ~, C,,
U;z, 0
::,9, 7. ' ( 0 \_1 r-i ., r .. ;;;a ~ f, . ,
l~c;,
?5L/,. J,
-·
C, !)
1.,,/ t' i.. " 1-:i-. I
7.1,7--
2{,. 2--:K ~Ra" I I (S ,--; . c,O, '7 .. °l 15 15 IC/ r,.. . --;p, .-; ·3 :-), , r. , • ~· . 'J.
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:;. 01· 16 <JD >z,Q-Cir· 16 '10.1 z._. (:,1" (,,i<:;:( '.-;i.., Y> ? 'r.:,q l~.'.:17 · .. ' . J 17 QS 3g,9q 17 !<:<,'7v bq f_ ,11""
18 qo. ::,,q_ er, 18 1'161./ C/l (, .l G
19 qC: 3lZ,qi 19 in i~ {J.-,'/ 6 ,/ (()
20 20
Samples Col!ecled Container Description Voes
Remarks
Parameter Conditions: pH +/-0.1 standard unit
Turbidii'/ +/. 10% above 10 NTU
154
COtm/Temp +/· 3%
+/• I NTU below 10 NTU ·
uz I ' -:r,-:( '2-0.0
--:i,.c1 i ,9r~ f79,. ~
3,3 ( c; I f?C)'.f)
ittR
DO +/-10%
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I ORP +/· lOmV
CNAmcono I Low-flowGroundwoier Samping log
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Low-Flow Groundwater Sampling Log
Project No. Kubal-Furr & Associates
-£i:I'ira11me11tnl Consrtltmrts-Sife Le;cotion CNA/Tlcpno · Shelby, NC
\/~·'/. Field ?ersonnel .Di v
Well I Sample ID --l-""\="-\++---J-1 ___ _
·--:>.) .\ -?-._ ·) h \.J. Weather Ca.odllion £,v'.] (, o; Sample Date ---"--'-~./:._c_c; _ _,_______ Arrival Time O~\j-Serr.pie Time / Zc \j-
Descript;on ol Memuri~gl---,-::-. I Cosing Type! c-r I loc,tngCop[ZJ/ Cosing[2J2 . Point (MP) IL-'"'<-~ y Diameter , . ,.-,:~,ti
P•.;rge Melhad\ (5:lL'rJ'>;7'· f Sampling Method] {_~7 t,.'/V~ J
Purge Start Time! /ic) 0
Water-Level Measurements
Interval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
Elcp;e rime
{mins)
/ (_
/,
C·PN [feet)
---:-.
-./ /
'
!ntervol
0
I
2
3 ,_,
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
Purge S!op Time\ ))..c, (.,
Field Parameters
Temperature
rc1
I
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Specilic
Conductance
(µSiem)
I /J!--7-:L :;-
I / V '-..., I '-.
I
I
pH (su)
,
//
Purge Ratej '.3,J-0 m:Jm,,l
Turbidity
(NTUJ
Oissol·•ed
Oxygen
(mg/L)
ORP (mVJ
Samples Collected Container Descrtplion PreseNahve i _,,,.-,t---'--:r-:~:::-:=-c~----b=;-::--.---,-:::;,;=--y:---;:;--::;-~±;:-:::=-.::;-;::::r·_-::;:-::l. · -t'G --j
_J;~\
.,_.. tCr;:1-v i') ~,. .. , -=::1.-...L.!'-...:I::+:~...+.i.L.-¥~......J..Ll..l...._..:.l,~.......,.-,,:...,."-="'c!...l...',cl.i.!1_.,-'-Ll..!.U..c....,!.2-J"'--!.
.
+
-
'
s
,
;
:
,

,_
Parameter Conditions: pH +/. 0.1 standard unit
Turbidity +/-10% above 10 NTU
155
+/-3%
+/-I NTU below JO NTU
+/-JO%
+/-lOmV
CNA{TICono
Low-Flcw,Gr:Jvndw~te,SompJ09 log
Kubal•Furr & Associates
-E11vira11111,mtaf Co11s11/ta11ts-
Sample Dale S Yi
Low-flow Groundwater Sampling Log
Project No. ---~2~6_Q~S~ll ___ _
Sile location CNA/Tlcona -Shelby, NC
Field Personnel 73/< ---'-"--"-'"-----We /1 / Sample 10 __ ___:6:,,-_:E::__~· . .,S:c..~:..' ___ _
WeatherCondificn _£·:_J.,,,,,,,#7 .. ?e,-·,
Arrlvollime /"3,;20 SompleTime_...._c/...c--o,._"3=------
Description of MeasurinQ~ Casing r pe@Jr L I:" C 0 CasingQ::J Point {,\.t?J jOC--'<....-y -~-.l oc ing op V Diameter c;,,(. .
,r,cl\e1 Purge Method I Gz£.;,~·-J~/oJ · Sampling Methodjr==-l;:):;;=:f,1=c=---~-
Purge Start Time( ( 3 '{<f, j Purge Stop limel /L(--..ft'/ \ Purge Rotej.--1.-.Jc10 ml/mjnl Wafer-Leve! Measurements
Interval
G
I .,
3
4
5
6
7
. 8
'
10
II
12
13
14
15
16
17
18
'19
20
Elapse Time
(mins)
C>
,S-
/o
1S-
.Jo
9s-
So
3-.('
L/-o
l(._(
si,
~.s
b)
e,,_;
7u
0iW (feet)
3'{; J.
3t9.{
'37.t-1
~7,:).o
3'7 '/ ._ r ,..-
37-3.f"
'37,t.//
'3 .. li/l/
"!:;7,<(,s
~-:t'y
s?..rcf
37-&;
•rJ.(/J.
37,u;,
J7,(;f
• <
Samples Collec!ed
lntervbl
0
I
2
3
4
5
6
7
8
'
10
II
12
13
14
15
16
17
18
19
20
Field Parameters
Temperati.xe
(OC)
--
(7Jf-
/7,10
If, J.J.
/f\S--0
Jt,1:,·7
/f,f:;3
;f-", )3
/<f.St
lf,SJ,
/<l'.{.?
IJ'; 9 I
/f,93
I J. 5l,J~
1'~17'.41"
Specific
Conduct once
{µS/cm) -
53
-st./
st(
s-..,S-
a
S7
ho
too
ll
7.. ;}.
tf,J
&,,:,
(:,1
&i
. Conta1nor Descnpt1on
pH (su)
--
,5,7.r'
s-: Lft/ ss, t:,tf I
-5, fd
S:93
(;_oJ
/o I
c;.o9
&,_/V
(,.,, ;Lr_
G, }1
{:;J.J/
{,_ 37
{,,t/7
Turbidity
INTU)
3, I
s; ,.){
I I
I J..
/I
/o,o
/s, ()
7, ·;;J r;_;;,
0, 3
t/.G
:3. if'
3,?
·'3,,S""
Preservolive
O'tssolved
Oxygen ORP (mVJ
(mg/L)
.--
S.oo 19&.4
•! ·7 I ;9_;-; ()
t(.t/9 n?. '-I
'3 /'-I . -.) IG1,~
1,9ii l</1f
J,bsS 157. </
;J. ]o /JS,;J.
2,;f /13, 3
J.99 /o9.b
/,1--,, 90.o
/,7 ;J. 91;9
;.t:-t./ f--Zf
/,-rJ fl.f
/.39 7-S°,()
Remarks, ______________________
~---------
Parameter Conditions: pH +/-0.1 standard unit
Turbidity +/. 10% ab0'le 10 NTU
COND/Temp +/· 3%
+/-1 NTU below 10 NTU
DO +/• 10%
ORP +/• 10m'I
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156 CNA/Ticor,o
Low-flOwGround'.voter Somplr:g L09
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Kubal-Furr & Associates
-£m,iro111111'!11ral Co115ulta11B-
Low-Flow Groundwater Sampling Log
Project No. 260S11 -------'==-'----Site Location CNA/Tlcona · Shelby, NC
Field Personnel --.JJ.---"--'l.::.IJ_~-----
We/1 I Sample ID !fif..-S"i-1 -_ ...... ·1-3 lo Li Je9ther Cond,tron Si-' n n y I. [e, 'S ScmpleDc~e __ ~L.,.../.ee...;__:__:l ____ ArrivalTime \.2:f-.-() SampleTimt; _15 :;u
Descriprion ol Meosurin~oc Cosing Type I C. C I locking Cop\ LI I _Cosingr-::;-7 Point (MPl.l~ :::_::)J . 01amete~
Purge Melhodl cJ0-u-u:lf\:S Sampling Melhodl 91v.1~dJiS I feco••
Purge Start Time l 3 Y-j ! Purge Stop Time! } > =3 '2,.--! Purge Rote\ j :5() ml;m;,.J
Water-Level Measurements
lnte:-vol
0
2
3
4
5
6
7
8
9
II
12
13
14
IS
16
17
18
19
20
Elapse Time
(mins]
c;
ro
cto
DTW Pee:)
_2.Cf ,9-lj
Samples Collected
Interval
0
2
3
4
5 .
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
Temperature
(OC)
Ir .~3-L:,' ·.?
Field Parameters
Specific
Conductance
(µSiem)
pH {su)
S,tl
lj c,O,
C-nj
i..L C:C/' l, l ,
-j r.o I y. -, ')
LI C') 'x
liC/1/
Turbidity
(NTUJ
i ,0,
i 'Lj
I . \
Dissolved
Oxygen
(mg/l)
O~P{mV)
1.r, o.-i Cr Go. i
19,12_ s,cr, c,,e::,c; ri.20 "r/.O
Container 0escnpllon Prese:volive
-Be\
Remorks _____________________ -r--c---+'---,--'r---c--,-----ll-:; l/. r fu-\r\\ ~dd p,it;,:c c-----tv ------------------------------------a•·\. Parameter Conditions: pH
Turbidity
+/-0.1 standard unit
+/-!0% above 10 NTU
157
COND/Temp +/· 3%
+/-I NTU below 10 NTU
DO +/-10%
o.~P +/-JOmV
CNA/Tlcono
Low-FlowGroundwcler Sompfi11Q Log
Low-Flow Groundwater Sarr.piing Log
Kubal-Furr & Associates Project No. ----~2~6Q=S 1'--1 ___ _ -E1wirow11,mtalC,:ms1tlta11ts-Site Location CNA/Tlcona. Shelby, NC
Field Personnel 71,,t/ 1-i,,iZK-, C,;t:
Well I Sample ID )1-S-:f 1
·~-,;; -b'-f, WeotherCondifion .S-v.7 7o Sample Dote ___________ ArrivalTime {6:CJ ~ Sample Time l' • iO
Description of Measuring~( Cosing Type I L { I L k C ~-Co~ing I-/ Point. [MP] tCX:,, ~ oc ing op -L "z.-? Oiameie 7., inc/"l<ts '•Pu,ge Melhod[ &,/l <,rJ .4:, \ Sompnng Melhod[ :5':\-~~
Pu,geSlartTime[ /(J:f'i, I Pu,geSlopTime\ ft;.': /7: I<\, Pu,geRc1,;f/ ZS:,,m;c\ Water-Level Measurements
Interval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
II
18
·19
20
Elapse Time
(mins)
(>
~
/U
iC
Zo
Z.<
'3<>
"3< . ,
I.to
y,;-
~o
DTW (feet)
2I)f
,;1,/o;, ~~ b
21 '120
z..c, > ·1 '·· b
'3,c, 1:3
3/.f/l..
32.'15
6j qt-5
?,</ 1}0
s'-1. B~
3'-1~ ,
;
Samples Collected
\. {/ V _.,, -.,
lnterY61
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
II
18
19
20
Field Parameters
Temperature
l'CJ
I -
i[f.(C,.
I 1CJ..18
l°l.~Z.
rq, ':::, --1
/0. qt.,
;OJ. (;_°l tc;,c;?,
Jct. 9</
20.l,('
~?o.c>'-1
Speciric
Conductance
(µS/cm)
-
-:;: 7 C,
. ~62...
~~<P·,
>BB
~c.-
5°i I
Stt"J
5"~& s-~s-
5"x':,
Container Description -
-~ ~ '-l-: () ,;,, T, -
pH (su)
-
0./'j
rb -./)
/,.,_ '-I z.
. (,'_ ' 4· ~
0. <./ e,
&.5:7-
/_, ,:.>.-o;
(;.,7-D
t'.. "7-I
r" K
Parameter Condi/ions: pH +/-Q.1 standard unit CONO/Temp +/· 3%
+/· 1 NTU below 10 NTU Turbidi!y +/-10%above IONTU
Turbidity
(~:TU)
-
IS-
17-
; '1-
i°I
Ir
/~
/ 2,
I ;i.
{?
ii
Preser.-9tive
Dissolved
Oxygen
(mg/L)
.-
6-~
n, S--0
0,'.>9
n. (.,o
0,.~'1
{:?, 7(.,
().5{&
0,01
D,'?'f
h, °?2-
HI,-/ /
ORP +/. IOmV
ORP {mVJ
-
~tZ.7
~13,,9
-ZB,9
-~,,<,
-so.o
-"3:;-,S-
-?, ,...,,f ·-;) ..
-3(,,9
-3)',=/
•-37.2.
I
I
I
I
I
I
I
I
I
I
I
15 8 CNA/Ticcr.c
Low•FlowGrovndwo!e< Soi"Qp,ng tcg
I
I
I
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I
Kubal-Furr & Associates
Low-Flow Groundwater Sampling Log
Proiect No. 26QS 11 -E11uiro111m:ntnl Co11~11/ta,rts-Site Location CNA/Ticona -Shelby, NC
Field Personnel 6c
I / Well I Sample ID C--/2
Sample Oat. s/(~1 A,rival Time / ;_~;,~o/her ~:~=~i~::ri'<:7 S"°U,~;:;,~ :b.s
Descripfon al MemuMng~ ca,,ng Typ•I ~ r, / I locking Capl v-----· 1 Cosing~ Po1nt(M~ ( V (_, . c;c:mete~
Purge Method) 7'"JL::rc.1J"'J~L 'j7 c. I _ Sampling Metr,odl 72~1.,'c•"U~:iZ' ... · ~ I
Pvge Siert lime\ /0 f J. \ Pu,ge Slop Time\ 7/o<f \ Puc;, Ra1e\ '-IS-c m"m"\
Water-Level Measurements Field Parameters
Interval
0
I
2
3
'
5
6
7
8
9
10
II
12
13
"
15
16
17
18
19
20
Elapse Time orw (feet) (mins]
/J lb. b o s (7,JJ
/ZJ 7 7, '-/1 ,s (),,:f}
Jo i1,SL,
).s iZ&,1
3D 11.6/
-3~ 17.!v 3
i/p /7.t, 1
<ts i1,b'{
,:;() /7.~-3
'
Sampl~s Collected
1ntervCl1
0
I
2
3
'
5
6
7
8
9
10
II
12
13
"
15
16
17
18
19
20
Temperature Specific !oC) Conductance
{µSiem)
pH {su)
~ -----
17, 23 !2( '7,8-7
/'?I/{ Ji-? (;,,,s'u
(),:S"7 Ir 5,_'{0
/7, bl i t. '(/JS'
t1. r,;8 IG ,,,.K <t. ?e-
11. ;,f lu i(,,; J..
11.'?9 I& '-(, }CJ
i7,9S' ;t !/, '-1..S-
lf.oJ I& if vs
;f,l?Y /,; t{SI/
Container Descnption
ll.:rOidit·1
(NiUI
-
(;co
(i,il-5
O,c>o
d,.o0
cJ,c.0
U,Uo
O.vo
{}, Q;
(),CC)
C,c/)
.. Pres~rr:i"ve
1-/c,/
Disrn\ved
Oxygen
(mg/l)
-
'76:)
'7,o?
7,1-~
t,/)9
kf-f'
7.({,
1.Js
7/3
&,7J
6J1
ORP{mV)
--
;/t:!J.;2
, ~,¢"
'JJ.(?
'J/('(.y
'.2~ . .f
;}s',,,f
'Jti,/
J.w,tf
702.2
J~c(
Remar'<s _________________________________
_
i& Parameter Conditions: pH +/~0.1 standard unll
Turbicf1ly +/-10% above 10 NTU
159
COND{Temp +/-3'%
+/-I NTU below 10 NTU
DO +/-10%
o.:::? +/-l0mV
CNA{TIConc
Low-FlowGroundwotet SampUnQ Log
Kubal-Furr & Associates
-£11viro11111(11tal Cr.>niu/tant:5-
Low-Flow Groundwater Sampling Log
Project No.
Site Location
26QS11
CNA/Ticona · Shelby, NC
Field Personnel 6i;
½ /4/ Wei// Sample ID =====r:~r~~-~3=i:======== · · '3 'J tJ L / ,teather Condition _..c.__r,_=-=~..:'..,-'--,c,~71-'7'~,:,,c''f~----Somple Dcte _~ _ __,_l , _ __.__~----A;/1'1clnrr.ec/£-J--Scmplenme / J3c.;,3
Description ot Measuring!..-.----/ aj Casing Type I S7, q I locking Capl ' .,,--I Cosing(2J Point (MP) /6?..._ L,,,--"""" Oiomete _
,nc.~l!ll
Purge Methodl75atrJ7,;tz./?.:...... _ \· Sam.piing Method! P.cl)l,._;::;,,L,S(._~rz,:_ ... ,._;,
Pu,ge Sta,tnmel / '.l.J3 I
Water-Level Mea5urements
Pu,ge Stop omel /)-Sfc I Purge Rote]fL-;:2::,.-:.,ml/m;n!
Interval
0
t
2
3
4
5
6
7
8
9
10
It
12
13
14
15
16
t7
.ta
'19
20
Elapse Time DTW Peet) {mins]
0 t:&·-; -9,36 0
/(,) 9. 3s.i -
IS' '/JS-
:.Jo '-)_31
2-~ '7.31
So 9. '-10
3-< '1, </o
I
S~ves Collecled IA ts
lntervCll
0
t
2
3
4
5
6
7
8
9
10
It
12
13
14
15
16
t7
18
t9
20
Field Parameters
Temperature
l'Ci
-
/&.oo
IS','7'J
;.1,-,J-f
Jl:,_ 17
;S,<)J
/&,,r9
A~ .. 2v
Specific
Conductance
(µ$/cm)
---
'-io
{(c,
l/6
t/o
:sf?
s9
?.9
Conto1ner Descnption
pH (su)
--
_s-;3Cc,
t{(, f--
t../,t.f,f
L/,s7
1.'73
1-(,7'7
1../,70
TurbidHy
(NTUJ
---
.f':~
"J, I
5<. i../
J.---:7
/, 6
Cl, 7,K
I o.~<>
Preser,ot1ve
I/Cf
o;sso/ved
o~ygen
(mg/LJ
-
·7, .:s,-o
;5--: I-S.-
t{,'?}.
'-/ t/.S-
t./, S'f
1, 3--S-
L/, JC)'
ORP (mVJ
--
/77.t./
J.23.. fa
'J_]o_)_
11'(,3
15:,3.p
1.co. 3
JCJ7)
Remarks ___________________________________
_
Parameter Conditions: pH +/· 0.1 standard unit
Turbidity +/-10% above 10 NTU
COND/Temp +/· 3%
+/-1 NTU below 10 NTU
DO +/-10%
OR? +/-lOmV
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I
160 CNA/TTCOOO I Low-FlowGrour.dwoter Somp~ng Log
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Low-Flow Groundwater Sampling Log
Proiect No. 26QS11 Kt.ibal-Furr & Associates
-E11virv1111wital Con;;u!tanl~-Site Locotion CNA/Ticono • Shelby, NC
Purge Method\ fc;;z..,-J .,,')-fl_.7) (_
Purge Start Timej j J~[
Water-Level Measurements
Interval Elcprn Time
(mir.s) on-·, Peet) lntefVbl
0 () tJ.<::,'7 0
I -S I u,{,, '?-I
2 /t> /1, /o 2
3 /0 /l,f~-3
4 .2c, /'J.. i./"1 4
5 /r i}.,JJ 5
6 3c) /'l,_?.G 6
7 · 3_., I '3,'J,{ 7
8 '-(6 IL(, 9 8
9 t.JJ,r rl.uo 9
10 so /<{.9 J 10
11 ~~ i.£ 'J '.l. II
12 I:., t, I /s-;l, J 12
13 &Y l . ~ ,:.C(/:.l 13
I 4 14
15 15
16 ~ 16
17 17
18 18
19 19
20 20
So~callected
. Field Personnel
Field Parameters
Temperature Specilic Conductance
FCi (µS/cml
pH {su)
-~ ~
;i-,1-r / 3-;2. ;o.;'(
JC,.,So /33 9,f;l_
/S,5(:, ;J). 6",f:J
I ~'-f J. /o9 <f,f9
/~3S-Joo J,J7
1-.r:Jt 9b sf',<? f
1-.S": J ;l 90 d'-;&'7
1:.<: ?f' l/t J-, <Jeo
/S°, ~7 'l<f lj,1).
/.s,</J t?9 9. 31
1.S-. 3(,, /t? 3 9,t,,o
/S°:l<S° Jo_., '-/,-S'S
Jr..{, 9:) /df '-I, s i
Contorner Oescnption
Remarks 1/;.s i?,,i1Ul2-r..· .. "'() l..1JtU~)-v,v ;),::<.-:'SN,:; ·/l,•,.,..
'°µ/.,ltv0(.'1.-t-.J ~77t:f1,_,'-":'" 1),.,-?.,1. .. \:">) ·ru -J.-1t-:)h c.::-
Pcrameter Conditiom: pH +/-0.1 standard uni/
Turbidity +/· 10% above JO NiU
1 61
CON0/Temp +/· 3%
+/-I NTU below 10 NTU
e"A::·
Turbidity
(NTU)
--:
S.d
:J, 9-.
LI
0,(,,-.[
G ,J-o
C>.'7u
6,7a
/, 'J..
/,/
!o
/, d.
/c>
/, u
Presel'✓□t1ve
Diswlved
Oxygen
(mg/L)
--
9,oo
·7,3</
0,:l7
0-JG
:5--; 5'7
-Z.9/
'3',63
ORP {mV)
-
t(/f,
c(J.3
tl.l
{,Cl,;
GS'./ r,,,,,--s-~-{G_ '(
'.3 ,..r3 l'?i'. r
tl,ol 01,).
Lf,'7o <,,5,J
L(,77 013
l(, (, 9 .,"'9.3
cl, f'o 'I 6 3", 9
DO +/-10%
O~P +/-10mV
CNA{f.cor.c
Low-f'<lwGroundwoter Sompfi,o Leg
Lo\v.flow Groundwater Sampling Log {-r/:--., ,,, . Kubal-Furr & Associates
-£1wiro11111c:11Ml Co11$11lti11lls-
Projecf>Jo. l,o~ 4-.Slc• I
Site Loco/ion _C=:N:..:Ac.:/T.:..:ic:..:o:..:n:..:a:...•_S:..:h.:..:e::lb::.YL.!•..:.N.:..:C=--
Field Personnel --l'"-"'c)<\]_~-----
. Well/ Sample ID ·:-:r--2--~ . .
?\ a,, I c" ·1111~0/herCondilion ';,\; 1\0'{, i;.'i!]cl'/, C-.c,'s Sample Dote -----'-'·,J'-.?;i.2....L. =· .":1..1-__ Arrive! nme · ;J "::L Somp!e iime __ l,_·'-".'5.'-"(..,\')"---~----
Description of Me_osuringl /( cI J Cosing Tyoe~-. ;.-Locl:in Co CZJ· _CosingG:J ?otnl (MP) L) L. · f \,·l/ 9 P Q1;;:mete.
1nc~1
. Pu,ge Melhod: w--n~strd·n¢.d Sompl,ng M_:od\ re,-10:\::-0d:ti} .-e,~,,;e +-le,,)
Purge Start Time. f2d.5 j Purge Stop Time! f 12}> \ Purge Rcte '} :::::7 , ml/m;n
Water-Level Measurements
lnteNcl
0
I
2
3
4
5
6
7
8
9
10
If
12
13
14
15
16
17
18
19
20
, I
Elcpse Time or,•, {reel) !mins)
r,'./ IL-Sq
c /'L,C-:J
lo i"l-.C~
IS '+;1-c
I") [} I '.+":1-7
')_< i'l--,-:\-11.
30 1.-,-:W
·::,c;' . ,~'¼
'-lo \ l-:').-0
~
I
Samples Collec/ed
Field Parameters
lntervcl Temperature Specific r'CJ Conductance
(µS/cm)
pH (>U)
0
I lu,.s::.. i~Tl r. .. e,,::;
2 I 11_ (-< iC/ I~ r: <:r:.'
3 /I"+<" \ Cj 1-1·, {,_? CI -
4 ' _., '4 11.:-r {l1Y t,_y-1
5 \&, '1--'l,_... 1c1~17 (. 'c;r.:::
6 i r, '1--Ll /C(,1~ G. q__,
7 i(.: 01 iCJc10 1· •• sz
8 i(o c.< IC/l,::r r.C<J
9
10
If
12
13
14
IS
16
17
18
19
20
Container DeKnpt1on
4xl./o~
Turbidity +/-10% above 10 NTU +/· J NTU below 10 NTU
162
Turbidity
(NiU)
n'-lc
/i.-1~
0 I 'J.,(
01Q)
rl ,'lc
r· : S"G
. r, .£{.
, e;_c,K
Preser✓ahve
OR?
0iHolved
Oxygen
lmg/L)
I. '0 7
l. I l
OS(u
oCf-, -..., o,~"--
o,LJ I
·• lc1 u , ' .
n 77S : •I.
.
+/· lOmV
ORP (mV)
I c;-c,,lJ
il0,3
iou I
er::;,(,,
~r'. ·.·:r-
x'I ('
'.1{-,' 6
''.'.fl '1
I
I
I
I
I
I
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••
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low-Flow Groundwater Sampling Log
Kubal-Furr & Associates
-E11vira11111i:11ti1l Ca115,11/:1m!;;-
{il.
Projecu10. ..,26~ J{SL.c,/
Site Location CNA/Ticona • Shelby, NC
Field Penonnel f:..7
*
Well I Sample ID ..:_j. ,s-ct '5J {// 1.1,weatherCondition ._\,.;1,_.c .. ·'.:.le';
Sample Date--'--''---------Arrival T:me,-1--'--")',J/---~_::S:::□m_::p".:l:'..e.:'.nm:.:_e,--'-/.::··c./;c:-2~,=:0::· ===:;----
Description of Measuring~-.-Cosing Type~_ r.~ locking Ccpj , /'. I Point {/1.\P)~ ~ . /' .
Cosing
01ometer
Purge Method\-;~~'& 1·;-;(!. ·17..:::._ Sampring Me!hod] i2cv~2,~t..ft.:-,0,t.JI
PurgeStar1Timel (J..t'i I PurgeS~opTime( I ?1y· PurgeRotel-'--/::,·r:m11m:n\
Water-Leve! Measurements
Interval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
Elapse Time orw (teetJ (mim)
Q r7. 13 ,s-.,f7f
/-·1 /1.(,S-,.
/S-..-\,. . ·;p<,,1
/() j../j~r-
.),_s-:J...2,)C'
~{{) ..-) '] ..... --;._ ,.._.1,l
_.,.,. -~· · '3P -~-..) .,( . {1
tf u ,J,1.[?o
'f,!(" ¾,eJ
,-. ?-(!; _") {,,' ..-J •.
S.5-;✓,:,73
~
Parameter Conditions: pH
lnler1ol
0
I
2 I
3
4
5
6
7
8
9
10
II
12
/3
14
15
16
17
18
19
20
Temperature
(OC)
~
r • 1 li-)i ·v~·
_J.. • ,,1 .-L4C ;"-
Ir~, >" It l ·• i, .) )
/{,,!, (
f·. s (
i[ J-7
l{c-.k,
,. ).7 1l.
!.' ,(;'. ).,
It,;, 2 (,
Field Parameters
Specific
Ccnduc/cnce
(µSiem)
pH [Su)
·~-
~--,c~J -.fiJ,,. ( c:.t.. /!,_:,;
-~;?' 0,30-
(;.
;(; .-13 ·J,J
Jy '(.<?:l
.r:7 </,(,o
r;:,l j"'.,,-. ::.; if {• {c,
-~·q t(, '( 3
P3 '/J(3
f-3 u i(o I ' 'I
: '·1 ., .) . : { .-s.·1
.f3 l(,,Si.:
Conta1~er Descnption
+/-0.1 standard unit
Turbidity +/-10'7oabove IONTU
COND/Temp +/-3%
+/-1 NTU be!ow 10 NTU
Turt:t:::i:y
(N7U]
-
z::,,..,-/,.'Lt,,-;
/ j'
i!
IC)
'7,f"
S. 'I
'lf
.·) ii"(
~7c ·xn
.--~ J/ . ( ,.
Dissolved
Oxygen
(mg/L)
·-
Ll:.0 <,.. '-..-c•·i-
:; 2-r
/, 5.j'-
U,fo
[?J-':/
I c: (1 , ' ;; 1.:r
/. '(?
I ( (-. ' .
/, 71.::
. f .s· /,
DO +/. 10%
o.,.:i +/-IOmV
ORP (mV)
~
--··· -
. __ , 'I <\l,,'7
j c,. l_~,
jX;.J-
Tl,7
~;) (1
6-S°. I
'/o, 3
"(:J',(I
l/ .3' ")
if'(, u
CNA/Ilccr.::: 163 Low-F)OwGroi.Jndwoter Samp1i:ig t~
Kubal-Furr & Associates
-E1wirvnmt11tal Cims,1lta11ts-
Water-Leve/ Measurements
Interval
C
Elcpse Time
(mim)
·Y'f
orw (feet)
h.cl3
Low-Flow Groundwater Sampl"ing Log
Project No.
Site location
Field Personnel
Wei'/ I Semple ID
Field Parameters
Temperature
["CJ
lnler,al Specific
Ccnductance
(µS/cm/
pH (su)
0 I I
CNA/Tlcona · Shelby, NC
Turbidi\y
(NTU)
Dissolved
Oxygen
{mg/L)
ORP (mV)
I
I
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I
I
I
I
I ½ 1-ir,,liG I 1-::i;-c:;r,,_ :::z.,q I '--1-, S' 7 -I (U<:::' '7 .(, \ I~ l.'l I 2 i r· ,,.. . -; ::i ,{.,,", 2 i7-i·Sl) -~
3 iC:: 7f ·:}1 3 I~ . ; '"' .-,-, '-t --r ...,?-< •,'
4 ·7() 2c -·:v 4 l"'.l--,U.S-:i;i ' -
5 2< ~ :k. ~ 0; ·-5 /'J. \..[C: '2,'x
' 6 6
7 7
8 8
9 9
10 10
II II
12 12
13 13
14 14
15 15
16 I 16
17 17
18 ' 18
19 19
20 20
Samples Collecled Container 0e,;cnphon
Turbidity +/-10% above 10 NTU
164
Lj '4 -::i---o.cc~ 4, <;"" -;--o.oo
+,(,l/ 0,00
L{' '.t=; (',, 00
I
I
PreseNa!1ve
I 'x' I q~,0
I.'?-{" 7;3.~
I, <-v ·::i."-I
I ,G(. 'tr'. r':
CNA/Ticono
tow-i'lowGroundwoter SorTlPlng Leg
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I
I
Low-Flow Gr-:iundwoter Sampling Log
Kubal-Furr & Associates Project No. 26QS 11 -Em.'inmmenlal C(l/15-llltmits-
Sile Loco/ion CNA/Ticono • Shelby, NC
Field Personnel (/C" l~ /✓·. Well I Sample ID --g.,-,,,-.J~J~--, ,5 /.fjc) ~. /,',/,Yl'f'tnerConditian .i.ii_,,.,.cl. &;-, ,--, ,,SOf Semple Oate ___ -c=c'-=----Arrival iimd , 'r'{z Sample TTme 7~•-,C
Description ot ~~~;~~~~k~i( I Cosing Tyo•I · -;;>/ (~ I Loc<ing Cop~ 01;~~~.;~ d . I Ji ~ 1n<:Mo!!
Purge Melhod\.r'(~'i,.,f/;1~ ;/( \ Sampling Methodj ,,;>/ ]... .. .;·.4:S('" )1.,1(,,~d
Purge Start nm~\ / '{s: I Purge Stop Time\ / 7!..> I Purge Ratel-· L.1,SC ,,..1_,_..,.._,,,1 Water-Level Measurements
Interval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
LI
16
17
18
19
20
Elapse nme
{mins)
1)
.s-·
/J
/S"
;).c,
'/~-
<'(l :;,,
S.:{'
'iO If<,. ,_
,')0
,:(~~
0u
(o.:t
-;c
-7.(
~: ·) ·._) r..
:?,;-·, 1-;'F)
(r!s-
/{)(;
DTVI ffeel)
jLi c'i' " !(If
!S,:-.P
k,to
/to :1>j"
ft .rb
(t,7f r ,..., &;f I " ~,,, . ...,
! I,/ ,1.
/7, J'-t
(J,r)
i 7, '! 'I
/?.39
tfld
1,7,),{ ' r' ;r;,,;r
i'/, ;,y . ..,.~
t? 20, ',.,, c' ~ .' (. _:'(J
19:~-~
/t.31
Samples Collected
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
Field Parameters
Temperature
l'C/
-----
/(., (7
; {,rF--
It,, f!,
/!., ,3,,
/t,, JJ
/{_c,,~-
IL ·,' .-·, if
ll:)O
/!,;, Jc;'
//;,) ,;l I
( &, Jc·
/f.:,,Jl
/l,,(){
/(,cc,
!<(1;/ ...... , ( ..:
'(, / /,;.Q~
1<.·?1
I,{, ·i~\,.
I l:,./6
J{./G
Specilic
Conductance
(µSiem)
--
<<; --r-:-.--:-,_""'I :>.._"1 u
3.,Lf
'-'->) l/
!,)_ ;J
'7 it ) .,
s(i-
j// .--; u _.;t.:; I
-3';,3
~;1; ---n _'<. -; •1.s-
-5~-,2
-1;·77
L{aq
I./ 1/--C::
l/YO
,5'/C/
57-S
Container Descrrplton
pH {Su)
--
;--; ---..J,_,/
,,:;. 'f I _,--1/t _),
.. S',s-o
,;,S}
.S~-':,'{
t--·-•-),o C
,-{ ., ,J,, :· _)
r',7 ~ " ~-
5" 6 --... ' . .,_~
S,.)},
I{: Jj ... _ , '
a_;--; S' £-
s·:~-t/
/~I/Y , i / , 1
5<;). _, '·
';), r/11
.-...,l> .::) ,.~
t;.'/J
s-,t.(g
1urbidity
[NTU) -
:)<)
')-✓/ ,··1 • I ✓' . .
:../cl
/'!
/7
/1
//· ('./
/ ')
/,')
;,,__<(
//.,
J .:.1
:< ?-,
'/7 ,:< (J
')5' :.,,,
•✓,, ,:1 -:..,-..:..._·.:::----
J-1
Jy
Preservative
Dissolved
Oxygen
(mg/L) -I, ? ()
Q,{:,f
(), &-f'
()~ s7
(J{a
O(,f
U,,f{;
0 ,Sc.I
/J /._/ ·7, .... ' . _,
C, ''/
i .,,7 ( .)
u: 3-:,-
s·· c,,. 5
13J (_ .
O.:,~/
(j 5(J
O.J.'t
J 1'S .. rS
cl,Ji?
C,,)t
ORP !mV)
---?/ ~
, -· -fc,1 ,-s-'
-J"?,'/
-Is--::;_
-SC,'7
I ·-,s.;-,"
J-N,7
--77,f
~1--;l_ I
-7l(_ I
-· 7i/, k
-7/f, / ,_
")3,3
J-1s:-3
r75'.9'
-i/;)
-f3.3
-!,;'¥,J
-.&f-;3
··fr,(,
Remar',;s _________________________________
_
Porcme!er Conditions: pH +/-0.1 standard unit
Turbidity +/• lOo/o above 10 NTU
165
COND/Temp +/• 3% DO +/• 10%
+/-I NTU below 10 NTU ORP +/• 10mV
CNA/Tlcono
Low-F:owGrour.dworer Somp1ng Leg
Kubal-Furr & Associates
-E1wirv11111r1it11l Co11$1dta1tt,-
Low-Flow Groundwater Sampling Log
Project No.
Site location
26QS11
CNA/Ticona , Shelby, NC
Field Personnel (~:;:E:-i.,./ 1. We/1/Somp/e/D ---g....c.,-_-'«-. -.----3/f// ,/ W,;,plherCondiUon __ S_·~_,_,~_"-_'_,.'4,-c,t;,_-,~tc.~P~.2'.c.-;:,;,,,_, ~5c'-'-·,~s_· Sample Dore____________ Arrival Time iqf ;~ Somp!e Time_-----;='==::"=-'-==•~•-=----
Descriplicn cl Measuring!,-;-;/ l( C I Cosing T• pe(]u· l/ -l I( Co [2J Cming '/ Point (,\IP) · 'I / l · (_ oc ing P V Diomete 17'--
;,.ch~i
Purge Method( fb7!..1{i7!t7?c·· · SomPling Me/hodj Zl.-.{::.,2J2_::-¼:._,.
Purge Siert lime! 1t/-s-1_ · Pu,rge Stop limej /" (J / I :;,'.Jrge Rot-:"PL/.{-CJml/min)
' Waler-Level Measurements Field Parameters
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
,18
19
·20
Elcp5e Time
{mins)
Ii' ,,..., . 1,)
/11,
/; s-
,Jo
I /:s
1 :'>:
DiW fleet)
(1,1(0
/t'r,'-lt.i
/'(. l(J_
J<f:/-)
(I '/C
' ·" .•") ,.,/ /'I,)\
I
Samples Collected
lnterv61
0
I
2
3
4
5
6
7
8
9
10
II
12 ·
13
14
15
16
17
18
19
20
/l-,c > ;~y,-) '· 7 f (., ,Or.I
;S,"I(
iS-/r7
i r_.--'° 1 • ! _, (JC;'.,
Specific
Conductance
(µS/cm)
l;S-
{L('(
~;aµ,
7C(5
}'!-;
·;-y,'{
. Contorner Descnption
pH (su)
,<;", L( t/
S,r/S
,-r.;r
J, -
C,,l/(c
,/ l( / .__,,
s ,(/G
.
I
I
I
Turbic!it·1
(NTU)
17 lb
/i7
jl/
I ,; 7
/';
Dissolved
Oxygen
(mg/L}
0~)0
u,n
/0,/(.?
0, ;)(,
(I, Jr
a: ;,1..G
Pre,er1:itive
ORP (mV)
-Sb. 1(
ft,,::'
--/(1.j-
-9,),/
-•} ')?
' --·~ 1 ,,,.., 7-..,b
Re:-norks _____________________________________
_
Parameter Conditions: pH +/. 0.1 standard unit
Turbidity +/-10% above 10 NTU
COND/Temp +/-3%
+/-I NTU below 10 NTU
DO +/-10%
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
166 CNA/T!CCr.o
tow-FlowQ-cundwater Sorriplng lC9
I
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I
I
I
I
I
I
I
I
I
Kubal-Furr & Associates
-E11uiro11maitr1I Co11::-11ltn11ts-
Water'Level Measurements
Interval
0
I
2
3
4
5
6
7
8
'
10
It
12
l3
14
15
16
17
18
t9
20
E!cpse Time
(mins)
pf --,
iO
iS-
"0 -· '2..S
·~(;
..--~,-::::-
l. iJ
l S"
·t;O
<C:: ,....,
Gr• ,._ c::::
·1--r)
1.-C
q/,
~ s
c,tn
OTW (feet)
20,IC.
2./,,,;:,t_c;
;Zr_; i' I (.
2l ,r't\
/J i1 (./7
:2.)' f, ·2i I , ,, o·-,' ' ,
,:,/,r-:'.,
2.(, ti./
-Z.t, O'i
7 r,. <"t0J
') () 'cii.
7 /\ cir,
2◊ ,-¾,
-1 r; ,'!-,"' _/ ) ,, :-
7r,,<l~
11'1~
:20.'-K
J.o,'-10
Samples Collected
\/0(,:,
low-Flow Groundwater Sampling Log
Pu,ge Stop Time[ / 2::\ c; I
Field Parameters
lnterveil Terr.perorure Specific f'C) Conductance pH (>u) I Si I µ cm \
0 I
I 10. ;.,;,.} I c;z;-S-/1'1 I
2 if'.,' C, -:2, i ::\-c'i G obi
3 Ir-.4C-;2:2-(_j G .\ \
4 ((,,,lf'.f ~?,2-G.\ "'.a
5 ,r. Lil 7 7,lj (,,'I~
6 ' ·7 '.,< !( ,,. '7'?,(; (:, \ 'l--
7 :r,_ ~Cj .-,-?:,(; G ,\ 'Z
8 l( .~'-i 7--:>, 0 (;, IC-,
\f .. ' Z, I ,--,,}-' ' ' 1: ·7£1
10 i(;.,1,f' 2~:}-(-,j({
JI 1(; ,ti :2 ~::i:-1,: ,\Q
12 i ( t,--, I ,,. l ' "7 :2.... '.:3C, C . IS<'
13 ,c;-/'f i --J....1?, r;, I '.Y
14 iS,1-0 .'"J :z,C c.1sz .-
15 t'7,\('; "?~ r.:. . \ :i, -· 16 I c;, i;~ 2...-?>< i l~
17 ,~ ~ i --7,S-G.11--'
18 ic,,49 2 "3'--1 r;,, l 9
t9
20
Container Descnptior
Turbidity +/. 10% above 10 NTU +/• I NTU below 10 NTU
16 7
Ti.,;rbidity
(NTU)
2~
(1
I ,
L/, '.y
~ ,cl
-~ I
'7 "2 .
I, C:.
iJ)
().<JS"
o,cK
/. I
o,S'
i, C:
f,. 2..
L3
, .1
(') ';,{
Preserrntive rtc2
Dissolved
Oxygen
I ill mg
--:'\ .01
i,'t-f
0.11
o.r.r,,
D-~
D, 2.L\
~ n .'.":/, (_),,L
C·,·2-3
('. 7--,{_) --'.J
(),2.(/
() /Cf,-
0,-:3~
r"J, I ti
n .,_4
0 /Jf,J
0, t<?
0, 21.)
0 ,.., '7 '.,__
ORP {mVJ
Ss z
'7.\..j
-2,/. ")
--c.,-, . I
-:i.:;,-z..
·-((. {
-o:::."'
··?,',, 4
-'l!t.<l
-lC:,/l
-7C:.V
1--1GS.
I-9't, I,
-lei,"
_7c;· l~
-(t.3
-G/,9
-f.9./i
0.-1? +/· l0mV
CNA/Ticono
Low-FlowGrounCWoter Som ping Lo,;i
Low-Flow Groundwater Sampling Log
Project No. 26QS 11 Kubal-Furr & Associates
-Elwira11111,:ntal Co11s11!ta11ts-
Sile loco/ion CNA/Ticona • Shelby, NC
Field Personnel (~ <_-.
/ ,/ : We/1/Somple!D 6'6 -(,·,/ · I ·, / • I . _ . _ "'·~. '(.., / / Weather Condition (•ti' ... -;~., 5---::·:.:,:· j/1 /.,>t, '; ' Sample Dote ---I---"-''-./.-------Arrival Time~-----r_:S::o:m:Cp::'::_•.:_TI::m~•~ -----;==:'::j±:=:::;-----
Descripi;on ol Memurin~---~·:. ,._.. · 1 CcsingType[KJ .. <'(--· Locking Cap! ,,,--· Casing _,,./ Pomt {,\.IP) /(. l.,<.... -

.

·-➔-...>, L / Diameter C>< ;:::======-----:----''""'""'""'
Interval
0
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
Elapse Time
(i-nim)
/1
/J
/\.
orw !feel)
Samples Collected
V
lntervbl
0
2
3
4
5
6
7
8
9
·"
12
13
14
15
16
17
18
19
20
Sompflng Method! ~,,·~ ·\ ~ ~~J~-:-,:-,.~ , \./ )
Purge Slop rime\ ) q:~.!{
Field Parameters
Tempera:ure
(oq
/3, 1)
Specific
Conductance
{µS/cm)
. Container Descnption
pH (su)
r ,;,I .._') ''f
Turbidity
(NTU)
Dissolved
Oxygen
!mg/Ll
3,3 lif.s-j
,:;,-. ... -' .... 'J~ '(.)
Prese.--,a:1ve
,--7 ' I .:>,. Li,:•
ORP (mV)
:71.b
Remarks ___________________________________________
_
Porameler Conditions: pH +/-0.1 stcndard uni!
Turbidily +/. 10% above 10 NTU
COND/Temp +/· 3%
+/· 1 NTU below 10 NTU
DO +/. 10%
O?.P +/. IOmV
I
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I·
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I
I
168 CNAncono
Low•FlowGroundwo!er samp~('\9 Leg
I
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I
KubJl-Furr & Assoda_tes
-E1wirom11,11t,1l Co11s1ilt1111ts-
Purge Start Time] / ·'.,: :':./
I ' -( • , Water-Level Measurements
Interval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
I
I
I
Elapse Time
(mins}
? j
;_--
~ ..
V
/.c.: .
.-.::',,:_":
') ',
"J. .~ it ' . ' ,. __ .. .. --~
it{
li•-
r, ..,,.,
.) j
DTW {feet)
i/) / ~ ! ll
.'lr-~F!
I " .-. i :~,: . .' '.)
;:J,t,f
,' 1 I 1 _; r / /
/? ,J/
(),Jo
,·• i ,I,/ C
/) ,/t)
I 2,1c
1) i/l
J'i /' ,• I l,
j
f09'1p!e~ . .Coltected
Low-Flow Groundwater Sampling Log
Project No.
Interval
0
I
2
3
4
5
6.
7
8
9
10
II
12
13
14
15
16
17
18
19
20
Site Location
Field Personnel
Purge Stop Timel j_.5 ~: f /
Temperature
rci
--
J / ··1 /i ,( I
: ! ! ,. !I J .,, 7 ' .. / ¥1
j .I -, , . i I: ' J / I . _J
4' v ·1 ; I .,:.: ; ' ·, , l/ I , -, . .., ) _)
; ,;, 'j '3
) I/ l ;~ I./ _,).
)1/, ZS
;1{_ ?.L
l{ I , 3'7 . lf "I. I 'J 7
Field Parameters
Speciric
Conductance
(µ$/Cl':",)
-
,,.,_ I I :,;0,.,·
·-s-~1 .. )
,, ") I .:, ~
:)17
;" ;-cJ
·' I
!;;7
:,r7
3i7 3,,
'5(7
J/7
pH {suJ
--·-·--
,.-t/ ,j .c
_--;_:";c
,_,-, i')
1,/,y J. , ✓
l/ lLI I ' I 'fi{;7
' ) '·--·· 11" r f.1_"":· _j
t/, {-l •,/
l{, ((;
1/, bt/
t' I, t./
Container DeKnpt1on
26QS11
CNA/Tlcona · Shelby. NC
Tvr~idity
(NTU)
--.. -.. _) ' ; , ,
~II . ' -, :.··,.·.>'·
I 1,/
,f '): / ,{);
(J ti r: ' I(.
i\_,j(
(j . --·,· ✓--,, ·,,L-. _iF)-i\d·
r-: c• .'_: -_i
f'·'.(t'.1
' PreseN::::,:ve
Dissolved
Ox•1gen
lmglll
-·5··::;t;_, , --., -·-.\r,,\-.J
Ill :.J.
/; '17
L°'.:\'7
t.(;,[)
;r) ..-,-/ . : _, I
<\ t/,1
t'5. y,
{; jj
(1. 3"3
ORP (mV)
---
"\! tJ /I •
'7,J / J I, 0
IP'} .. I,
/ }S";S-
/J/ ,'-/
i/·1/f ,,._. __.
// /,..J
//Y-,7
~h:{_; I/, •
/'}_/,7
;)],I'
Remarks __________________________________
,:-__ _
.:. ·7 " ?Jr
Parameter Conditions: pH +/-0.1 standard unit
Turbidity +/-10% above JO NTU
169
COND/Temp +/-3% ' ' DO +/-10%
+/-1 NTU be!ow 10 NTU OKP +/-IOmV
CNA{Ticor.c
Low-flowGrolJf1dwater Scmp~ng Lc9
Kubal-Furr & Associates
Low-Flo•,•,: Groundwater Sampling Log
Project No. 260S11 -E11viro1111wital Cv11s11ftm11s-Site Location CNA/Tlcono -Shelby. NC
Field Personnel er
,7 I fat Well I Sample ID v-.,;:/3 '_:;;; 1/ ,(; . , Weather Condition Cle,-,~ 7 v6/ Semple Dare ___ __,_ _ _:_______ Arrival Time / {,. cX Sempre n:-ne i "7 ;:· ..:..:0
Description of MPo•·,an'1"1'M;P~I_/' "<A-I Casing Typel S;'7:'-7 -1 Locking Cap~ Casing 7
Purge Srort Timej / {-: /.S.-]
Water-Level Measurements
Interval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
Elapse Time· Dl"N (feet) (mins)
I 0 C (, f, ,·(!
I ·~':> / ;_.' I ---;{:, (.. I r a•
. ,. -I~·-/.:;
I ,.,,.-,-.':::. I I I 1' ,/-1J:2, 1/, l-r
I 1 c· J'-.• ) JI, }'f I /_1 . , ""../ :_} ' 7 l/ ; I, .J .
·1; s I ,, i., ; . ? -
U.,: ; I t/ (' , C 11, .
l(S 1 /,t/1
'
Samples Collected
Interval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
~ ~ Diameter ,:.A 1,,-:~'!1
Purge S rep Time LI~··~--:'-._;'-':_·.=·-_·__,
Field Parameters
Temperature rcr
----
•"I ·? ... /-:;,) ·S .. , .. , I :., ' I{,.
!//", 7 /:;,;_?
/':J,CJy
/II,! 7
i'(J/
I'!,;~ j
,, f s-ii ,_I
/if,},_1
Specific
Conductance
{µS/cm)
·-
r::c .-;, _; _).~·.J
·),)c7
·;!//.~~
~;LI )' ..
"-5'/7C)
'.. ~; .f) -~:::.··,
/7/
.r7 -':.. -:, / L~· J
'A(j ,sl/ /
Container Oescnption
pH (su)
--
,.-:,
_:,; j ,·,{. I,,
'-J, 'r ·7
?/,oo
3,;:y
:i ''/'/ , .--.,,,-·-
.J! '/-I
·" ~~1 '.), -.-, _.,.. ,.-
-~) '' 1 '·(
4,,:{
Turbidity
(NTUI
·-~---
{, ., ,;
, {,, 7
'7'/
S'.i ·; ')
'' ~-----. -', /., --r
i ;:-.' c·
(:,()
, _ .. ,
;,., ::,
_.
Preser✓0tive
I
Dissolved
Ox1gen
(mg/L)
--
/ './ i ••. , J .2
•"r i-£= l ·. C . .._
,.-; -(-; ()~
(), ~-:CJ
L? f/L/
( I, 1/t,
C, ~\(7
.·,·
<. ; '°:/ ,\,
D, )7
ORP (rnV)
--·-
,·?_ ·• ' C c;·s·· k' ,,
;,..LI :) I, 3
·fl/-,l
5·3_ 51
z---_i_ \-.._, -1 "
5.',), (,:,
,j-1, ,]
.57/l
Remori<s ________________________________________
_
Parameter Conditions: pH +/-O. ! standard unit
Turbidity +/-10% obo-,e 10 NTU
COND/Temp +/-3%
+/. 1 NTU betow JO NTU
od +1-10%
ORP +/-lOmV
I
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11
I
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I
I
11
I
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I
I
I
I
I 170 CNA/Ilcor.o
Lcw-FlowGrour,dwater So~p!_ng log
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I-
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I
Kubal-Furr & Associates
-E1wifonme11tal Consultants-
Purged Well Sampling Log
Project No. 26t;,r ;JtSZ rJ I
Site Location
Field Personnel
CNA Holdlngs/Tlcono, Shelby, NC
/:Z
Wei// Sample ID -S°'-/ / W th C d·t· ----J.--,~-\-_,--_,-c.,_,_ll~t_j-, _------,, 1 , / ea ,,e,I.., on ,,on 7 Sample Dote -3//r;/t,~ i..i Arrival Time G\j 1/t) Sample Time O,Y_s::-j
Description of Measuring1,~,--.
1
C . ~v. . ~ Cosing[TI. Point /MP) I ((_:r osing Type / tf~ Locking Cap 1.,,,/ Diameter >\, .
1r,ches
Total Depth of Well Below
MP?
Depth to Water Below MP?I / ~-,,; '/_ f I . .:.,7' ...,":" · _J / feet
Column of Water in Welt?;::!==, =7=_;=.:r=· =;===,= •• ~,!
:=========:
Gallons of Water per Fool! / , 7 I {seechartl? (!_ ;[· )
:==::::::;:;:=i,,=::;:::g::Co=//i~oo~,
Gallons of Water in Well?
Gallons of Water to be
Purged 13X)?
Purge Method?
I ______ 7-c;;-;, J2a,I
I 3. i, .. c:-I gel
I z~'1i icY. I
Purge Start nme'--1 ---"C'--·1l~J...,s,,_ __ _,I
Initial I
Turbitidy
ORP
Common Gallons oer Foot Conversions
1. 1/4 in Well Casing= 0.064 gal/ foal
I 1h in Well Cosing= 0.092 gal/ foot
2 in Well Casing= 0.163 gal/ fool
3 in Well Cosing= 0.367 gal/ foot
3 1/2 in Well Casing= 0.500 gal/ foot
4 in Well Casing= 0.653 gal/ foot
: 6 in Well Cosing= 1.469 gal/ foot
Total Gallons Purged) / I . 0 gol
Purge Stop Time~/~::::/fi~· ~7:'3~-~L:,:::~=1
2 3 4 5
NTU /~3. q mV /73 I mv j ][,, mV / m'/ Samples Collected Container Description Preservative
Parameter Conditions: pH +/-0.1 standard unit COND/Temp +/-3% DO +/-10% Turbidity +/-l0%obove l0NTU +/-I NTU below 10 NiU ORP +/-IOmV
1 71
Revise 5/28/02
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Di\YIS
FLtwD
June 22, 2004
PEM CARTER
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Report ID : AB23937
Page 1 of 11
LABORATORY ANALYSIS REPORT
Login Number
Project Number
Description
:L04052602, L04052707
:61621.01
:TASK ORDER TO-26QS12
Dear Pem Carter:
We are pleased to provide the enclosed analytical results for the samples received by
Davis & Floyd, Inc. on May 26, 2004 through May 27, 2004.
A formal Quality Assurance/Quality Control program is maintained by Davis & Floyd,
which is designed to meet or exceed the EPA, NELA C or other appropriate regulatory
requirements. All analytical analyses for this project met QA/QC criteria and the
results are within the 99 % confidence interval for each method unless otherwise
stated in the footnotes. This report is to be reproduced only in full. I .
Feel free to contact our Client Services Representative at [phone] if further
explanation of the analysis is required. Unless other arrangements have been made,
samples will be disposed of or returned 14 days from the date of the report. We
appreciate the opportunity to provide services to your firm.
Sincerely,
DA VIS & FLOYD INC.
r--f~<d,J
~t~Jatory Manager
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Dursl Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
1 7 2
DAYIS
FLtwD
Client
Contact
LABORATORY ANALYSIS REPORT
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 2 of 11
June 22, 2004
Report ID: AB23937
Master Sample Tracking List
Sample ID
L04052602-0l
wet Chemistry
SW846 9060
L04052707-01
Wet Cho.mistry
SW846 9060
L04052707-02
Wet Chamistry
SW846 9060
Client ID
V-23
DUP-2
Date Collected Date Received
05/25/2004 1315
06/03/2004 0334
0000
06/03/2004 0401
05/26/2004 0000 05/27/2004
06/03/2004 0428
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
173
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DAYIS
FLtJYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
Client ID: K-28
Parameter
Wet Chemistry
SW846 9060
Matrix
ORGANIC CARBON, TOTAL
GW/Chemw
Result Qual
1230
NC Cenification Number: 25
Project Number, 61621.01
Report Date
Page 3 of 11
June 22, 2004
Report ID: AB23937
Sample ID L04052602-0l
Date Collected: 05/25/2004 1315
Date Received 05/26/2004
RDL Units Analyst Date Time
20.0 CBN 06/03/2004 0334
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 / 816 E. Durst Avenue ! Greenwood, SC 2%49 I [phone] I Fax [phone]
174
D1\VIS
FLMD LABORATORY ANALYSIS REPORT
Client
contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
Client ID: V-23
Parameter
Wet Chemistry
SW846 9060
"Matrix
ORGANIC CARBON, TOTAL
GW/Chemw
Result Qual
11200
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 4 of 11
June 22, 2004
Report ID: AB23937
Sample ID L04052707-01
Date Collected: 05/26/2004 0000
Date Received 05/27/2004
RDL Units Analyst Date Time
200 mg/1 CBN 06/03/2004 0401
11
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Davis & Floyd, Inc. I PO Drawer 426 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone] I
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Df\VIS
FLtwD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
Client ID: DUP-2
Parameter
Wet Chemistry
SW846 9060
Matrix
ORGANIC CARBON, TOTAL
GW/Chemw
Result Qual
10900
NC Cenijication Number: 25
Project Number: 61621.01
Report Date June 22, 2004
Page 5 of 11 Report ID: AB23937
Sample ID L04052707-02
Date Collected: 05/26/2004 0000
Date Received 05/27/2004
RDL Units Analyst Date Time
200 CBN 06/03/2004 0428
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 81 b E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
1 76
Di\YIS
FLOYD
Client
Contact
LABORATORY ANALYSIS REPORT
TJ:CONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
NC Certification Number: 25
Project Numb'er: ·5152i.61
Report Date
Page 6 of 11
June 22, 2004
Report ID: AB23937
QC Summary Data
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D1\YIS
FLtJ\1D LABORATORY ANALYSIS REPORT
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 7 of 11
June 22, 2004
Report ID: AB23937
QC Batch Report -Batch Sample List
WorkGroup WG37835 Matrix GW/Chemw
Description: TOC GW Prep Method
Analtyical Method: SW846 9060
PREP ANALYTICAL
Sample ID Client ID Run# Date Time Date Time Analyst
L04052602-0l K-28 06/03/2004 0334 CBN
L04052707-01 V-23 06/03/2004 0401 CBN
L04052707-02 DUP-2 1 06/03/2004 0428 CBN
MB37835:1 Method Blank 06/03/2004 0016 CBN
MB37835:1 Method Blank 2 06/03/2004 0618 CBN
MB37835: 1 Method Blank 3 06/03/2004 0949 CBN
LCS37835:l Laboratory Control Spike 1 06/03/2004 0000 CBN
LCS37835:l Laboratory Control Spike 2 06/03/2004 0602 CBN
LCS37835:1 Laboratory Control Spike 3 06/03/2004 0933 CBN
MS04052601-04 :37835 Matrix Spike 1 06/02/2004 2309 CBN
MS04052601-09· 37835 Matrix Spike 1 06/03/2004 0841 CBN
MSD04052601-04 :37835 Matrix Spike Duplicate 06/02/2004 2326 CBN
MSD04052601-09:37835 Matrix Spike Duplicate 1 06/03/2004 0859 CBN
Dilution
20
200
200
'
'
I Davis & Floyd, Inc. I PO Drawer 428 j Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] j Fax [phone]
178
DAYIS
FLtrYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
QC Batch Report -Method Blanks
Parameter
Wet Chemistry
SW846 9060
WorkGroup, WG37835
Blank MB37835:l
ORGANIC CARBON, TOTAL
ORGANIC CARBON, TOTAL
ORGANIC CARBON, TOTAL
<
<
<
Result Qual
1.0
1.0
1.0
NC Cenijication Number: 25
Project Number, 61621.01
Report Date
Page a of 11
Matrix: GW/ChemW
RDL
1 '. 0
1.0
1.0
Units
mg/1
mg/1
mg/1
June 22, 2004
Report ID: AB23937
Analyst
CBN
CBN
CBN
Date Time
06/03/2004 0016
06/03/2004 0618
06/03/2004 0949
Davis & Floyd, Inc. j PO Drawer 428 I Greenwood, SC 29648 / 816 E. Durst Avenue I Greenwood, SC 29649 j [phone] I Fax [phone]
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DAYIS
FLt1YD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Cenijication Number: 25
Project Number: 61621.01
Report Date
Page 9 of 11
June 22, 2004
Report ID: AB23937
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG37835 Matrix GW/ChemW
MS/MSD MS04052601-04:37835 Prep Method
MSD04052601-04:37835 Analtyical Method, SW846 9060
ORGANIC CARBON, TOTAL 20.00 21. 38 40. 80 mg/1 97
ORGANIC CARBON, TOTAL 20.00 37.20 mg/1 79 9 11 74-125
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
180
DAYIS
FLtrYD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem carter
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 10 of 11
June 22, 2004
Report ID: AB23937
QC Batch Report -Matrix Spikes and Duplicates
WorkGroup: WG37835 Matrix GW/ChemW
1MS/MSD MS04052601-09:37835 Prep Method
MSD04052601-09:37835 Analtyical Method: SW846 9060
ORGANIC CARBON, TOTAL 40.00 96. 90 137.4 mg/1 101 74-125
ORGANIC CARBON, TOTAL 40.00 136.2 mg/1 98 11 74-125
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
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Davis & Floyd, Inc. I PO Dcawec 428 I Gceenwood, SC 29648 I 816 E. Ducst Avenue I Gceenwood, SC 29649 I 1864) 229-4413 I fax [phone] I
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DL\VIS
FLMD LABORATORY ANALYSIS REPORT
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Pem Carter
NC Certification Number: 25
Project Number: 61621.01
Report Date June 22, 2004
Page 11 of 11 Report ID: AB23937
QC Batch Report -Laboratory Control Standards and Duplicates
WorkGroup, WG37835
LCS
ORGANIC CARBON, TOTAL
ORGANIC CARBON, TOTAL
ORGANIC CARBON, TOTAL
LCS37835:l
25.00
25.00
25.00
25.10
25.10
25.10
Matrix. GW/ChemW
Prep Method
Analtyical Method: SW846 9060
mg/1
mg/1
mg/1
100
99
l 02
90-110
90-110
90-110
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I Bl 6 E. Durst Avenue I Greenwood, SC 29649 I {864) 229-4413 I Fax [phone]
182
DAYIS
FLtJ\'D LABORATORY ANALYSIS REPORT
Method Conformance Summary
Client: Ticona, LLC
Login(s/ L04052602, L04052707
Criteria
Sample Holding Time
Standards Preparation
Instrument Tuning
Instrument Calibration
Calibration Verification
Degradation Check
Interference
Sample/Standard
Blanks Results
Method Accuracy
Method Precision
Surrogate Recovery
PDS/SD/MSA
TCLP Prcoaration
Key ✓
NIA
-Met Criteria Met
Not Applicable
TOC
✓
✓
NIA
✓
✓
NIA
NIA
✓
✓
✓
NIA
NIA
NIA
!
•
PDS =
SD =
MSA=
Method Criteria Not Met -Seefootnote(s) below .
Post Digestion Spike
Footnotes:
Serial Dilution
Method of Standard Additions !
Project Nu.mber: 61621.01
Report Date: June 28, 2004
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183
D~IS iqi,"'•1
irdlittml'e FL YD lniMDouJ•-""""' Chain of Custody Record
Client Project I Site Location 816 E. Durst Avenue, Greenwood, SC 29649 [phone] Fax: [phone]
Kubat.Furr & Associates 61621-01 Laboratory CertJfcation Numbers: SC-24110, NC-25, TN-2923, VA-77
Simpsonville,SC
Contact Re'?:.irtTo Copy To Reporting Requirements: [ J Standarri { J Data Package (Specify Level)
Greg Kinsman f·fi St/,tf .So,.; v, L l f: (FU/ CH.72..11(_ .:::r(C,:,-VJ C._<V<-t-T
Collected By GttI; f:::.,~ ,4,f,...) Required Parameters, Containers and Prese,vatives
p T'7 I.,//,;(.:. r G'{..f'
NOTICE: 1 e • J ;i .. e C 0 t " n • ~ -. E -~ . " ·a • : ~ 0 X n ~ E ~ ·c E Sample Collection l§ 8 '~ • ~ ,, i Samole Descriotion Date Time Time Type Total
~-J-}(' 19'=/W /3~ >< ~ I l<
-~-·
R12·:ii 01,L,~ ::::(z;{di Time Reliquished By ~ Date Time Re/iquished By Date Time
f? 27 ~h ~--· _:_ ....--rl2s-l&1 Yn-,,
R"Qteive<J y I \',i~ Time r-w:ceived~ Date Time Received in Laboratory Ll>a.v Date Time °'~-. -lfc-:; -. .
" ' I /'5tt, n,._. ,~ .5: ~I,. Oi 0730
1.;ummenft._J
72--ou"T);,J{' /4 cYV , 7ot-->V6-
Matrix Type Definitions 1 -Drinking Water 2 -Clean Water 5 • Groundwater 7 -Soll/Sediment 8 • Li uid Slud e 9-0il 12 -Air -- - ---
.
----Page ( of (
~ .. ice use n,y
Purchase Order
' .
'~
Quote
L.091n Special Instructions
~ :,
-0 -S> ; ~ 0 • ~ C " ~ . "~ n, ~ ;~ .::j. ~ i ~
_J .s
Fraction HOT vornmenLs o, Sec· 't,fS/::
ofML<
1r:,as12
Qu;~0 Shi~
y N "' CUENT
"" FEOEX
lfY,s fy: ,Ajfbi/1 Number
..---days
Cooler (::;;::rble):
Onlce: Yes/ o Temp(C)~
Custody Seal: Intact f Broken ne
"""" co
--
Dav,._.,, lnc,111111
FL~02199
- -- ----- ------- ---D~IS ,., . .,..,
.lrdlitl'.duc FL YD ''"'""'""1, ~ !emtu Chain of Custody Record ----Page
Client Project I Site LocaUon 816 E. Durst Avenue, Greenwood. SC 29649 [phone] Fax·. [phone] ce Use vniy Kubal-Furr & Associates 61621-01 Laboratory Cerofcation Numbers: SC-24110, NC-25, TN· 2923, VA-77
Simpsonville,SC
Contact 'l:7;j.r i.AP.SoUvr tlF
Copy To Reporting Requirements: [ J Standard [ J Data Package (Specify Level) urchase Order Greg Kinsman <f&t C+t.,7l.:;<__ --Oeo v.J-Lc-V62.--zr-Collected By -:S-//4 ~ Required Parameters, Containers and Preservatives
r ,v'''' Quote
~
Tngm Special Instructions NOTICE: b
't"--:, • e ~ • I ~~ C \) }f ·s 0 • C ~ C N 0 ~ . u ~~ ~-,, 0 ~ Cb E ~ •• ~ ~ "8 • *I . ~ ~ ~ .~ ~ E E ~ i t Sample Collection ! 8 '~ e " ,
C> ::, z _J Samnle Descriotion Date Time Time Type Total Fraction HOT LommenTs l'~ 23 S/u/,,1/ )( o I X /) I 1--v:-c '1¥-e :\ uP-o2. s-/u/d( -/( s-. { K OJ-. dl).L,-
:)f, Q,J'( ;J.
//
/I II
/// II /a~& ~ oz Time Reliquished By Date Time IRt::'.".'.7' ·~ ),. Date Time Qu;Q shr;;, _sfe 11V o9o6 " CUENT -r -Z71M'f o<f I 2u:, y N
"" FEOEX Recetd~y/ d:J1 Time Re~B~rD_} Date Time Received in Laborato~ ' Date T,m, ~fy: Airbilf Number of2io ,-,.... , :5. ?-, 7.01/-.~ ec.-;z,c-,1plf-,/-/ 1., 27MA'(v1 0'7</V /J,s,-.. fl(.. ~ /7)~0 days
11,,,omments
</-ouT?-✓ve /f~,v,72:1l<ni&--
Cooler ~ilable):
On ice: Y No Temp(C) ~
Custol:!y Seal: Intact I Broken / W:::, Malrix Type DefinI\ions 1 Dnnking Water 2 Clean Water 5 Groundwater 7 S01VSed1ITienl 8 Liquid Sludge 9 -Od 12 -Air Dav,s & Floyd, Inc. Preservative Definitions A-None B -H2S04 C -HCI D -HN03 E • NaOH F -Filtered G • Other FL02_01 (02199)
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-E11viro1111w1tal Co11rnfomts-
Water-Level Measurements
Interval Elapse Time Di\'/ !f.ee!) (mim)
0 ,:;;/ 1/ '1 Od)
I . .,,-s '7\,tJ('.
2 [O f21 Jc/~
3 tc, .,i 1 (;,
' '7 r,') ·JJ~ I
5 ·?C, D. --:z i _cf;'V·
6 -?.·\ .,v. 2ls ·;,
7 -~/ 2,/ ~ 1-1 ,,,,...,
8 1111 -7\_C,,£
' 9
10
II
12
13
14
15
16
17
18
19
20
Sen.pies Collected
Parameter Conditions: pH
Low-Fiow Groundwater Sampl:r:g Log
\nlerva1
0
I
'
3
'
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
'Temperature
l'CJ
l(j 30 '
I
I
Specific
Conductance
(µS/cm)
Conla1ner Descnphon
+/-0.1 standard unit
'
pH (su] Turbidity
(NTU)
I I
DO
DiHolved
Oxygen
[mg/l)
ORP (mVJ
Turbidity +/· JOf. above 10 NTU
COND/Temp +/-3%
+/-1 NTU below 10 NTU OKP +,'-!OmV
186 CNA/Ticcr,o
Low-FlowGro~n?"'o:er Somplng tc9
Levi-Flow Groundwater Sarr.piing log
Kubal-Furr & Associates
-Em:irJ11me11tal Co11srdtr11itS-
Project No. ·J [1 t,()\kf':j
' ' s;1e locoNon CNA/Ticona -Shelby, NC
Field Personnel -----=,,.==·...,_"----------'7\ 1-'" "\j Well I Somple ID c..c-~ '"<, /\,., d-<(\. . ,., W?er Cond;t;on kc,f·1 w'\ , Scmple0c:e ~-Arrivcllime I½ J2L ScmpleT~r.ne 1.li'o5
oe,criplion of Memuring\.-r{, '\ ,-I Casing Tyo•~·')-l'"' 1::·~ C · [ZJ•. Casing~.-, Pain: (MP) UL, i.../. · ---. ..,c 1' ,g ap Dicmeie. · £.-_,r. / ,ncre,
Sampling Melhodl f'r:Ll'.J st:a lbt.L---
Pu,goSlcrtSmeLd:'...L:J~-LJ /'(fC ?~cgeSlopSmej \6\ (; I \ PurgeRo:ej ;;-6Dm,:,'-"I Wo1er-level Measurement~ Field Parameters
lnlervol Elapse Tirr.e
(mlr,s) DTW (!eel) , Temperature
{°CJ
Specific
Cond"Jclcnce
(µS/cm)
pH (su)
0.
2 /0
3
5
6
7
8
9
10
12
13 (· .. r( , ) ,
15
16
17
18
19
20
Scr,1ples Co\lec!ed
Remo~s
Parameter Conditions:
0
2
3
'
5
6
7
8
9
10
!l
12
13
" 7
15
16 I
17
ia I
" I ,o 1
Cor:'.01ner Descnpt1on
pH +/• 0.1 standard unit
Turbidity +/-10% above 10 NTU
COND/Temp +/. 3%
+/· I NTU below 10 NTU
187
Turbic:l\y
(NTU)
Dissolved
Oxygen
(mg/l)
ORP {mV)
I A, 2-c; Cl1. I
:z . s-I ::J-'2. 7
I i'>.c.in --i.lf
o.J2.. --LZ.
Preservative
ORP +/· IQmV
CNA/Ticona
· Low-FlowGroun~woier~.omping L09
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-E1wir.:m111e11tal Gmsu/trmls-
Lew-Flow Grc•,mdwo:er Sampling L:,;;
Prc.octNo. _,;J_/ b_M~j{f9~.· _
Water-Level Meosurernents
0
I
2
3
4
5
6
7
8
9
10
II
12
13
"
15
16
17
18
19
20
Elapse nme Oi','i (leet) (mins)
() fl, t3 ---< lf,Jo --
/O lf.J6
K 1f;lo
2n 1,f.1 J
2~ (f.)1
~ If.Jo
·3-.s IJ'.k
i/D /}',Jo
i/.s ;;, ?o
So /-f,}G
,'7J /f.J~
/40 1.f. J.~
t, ,s-if.Jo
70 lf,}-o
'7-s ,f ,!)c
.,S,o I.J',Zo
J:< !f,J.u
Scmples Collected
lr.!:rval
0
I
2
3
4
5
6
7
a
9
10
II
12
13
I 4
15
16
17
13
19
20
Site!.: :ction
Field Porome:ers
, Tempe:c~•-·~e
!~CJ
·-
/9 .,f( -
/9, 76
Jt;,c,?
~le, J&
I I_C;, 2f
I,; 36 l-1 . -.
r?. f3
/4,0o
/'7.?{:
:Jo.q 7
/C. :13
J.o. '/&
:2t,1(0
')JJ. ~~
;t,_31
J-0.YL
7.o.J,{
I
Specific
Conductance
(µSiem) -
'7'(7
-
I 7,;:f
'7St
771,
'77'/
7f3
77<?
'7yj,
?Jo
793
7J'?
7'7'</
75'7
'7'7:.s-
»r
79.1'
7"i't
-. ,. Container D:,c.1p,1on
_:.-. (su)
-
'.?. :S3 -'I. ,5;f
4.&'{
</. 9/
--6") ,.'.::) (
I S,1/
l~cf
I -<.o3
,S:-,t,S-
-.), 3;}
~3(,
~37
~ss-
'5,,..s2
~,(:.o
--S-:(3
-5,,.3
Paromeler Conditions: pH +/· 0.1 standard unit CONO/Temp +/-3::",
+/-l MTU below 10 N;'·J Twrbidity +/· ICG, above 10 NTU
188
Turbidil'f
(NTU)
-
Dissolved
Ox·rgen ORP (mV)
(mg/LJ --
/, ,f" I o,,f7 }JJ,o ---
/, I /. 'i? A:J},-.Jr
0,00 /. 'JO /'11./ o. :1 ,, 0,7!-. /76. r
0,;2f" 0.•S-u J-!'2..S
0.1 n {),~--{" ;13.t
0 00 O,'?cJ tS?r
u.oo c,f~ J'/[) . ._f'
I') (Jo o.f-1~ I S(;f..
0.c:o 0,9o ;7.J.o
G.C'c o.rf'/ 11,f,[l
0,()(1 0,7/ II 9. .J.
C2c1:_'1 C!,-S7 //41.3
Cl.00 o. {? /•'7. /
O,ct, :J.</ I 99, 7
C:<.:ti 0, 3'<f 9</_c
o,oo c. JG 7'3,(,
Pre~ervotive
DO +/-10?;.
ORP +/. 10m'I
CNA/Ticono
tow-F!owGrovndwoler Somping log
Kubal•Furr & Associates
Low-Fiow Groundwater Sampling Log
Project No.
-E1wiro11111r::11tal Co11~11/tm1ts-Sile Locolion CNA/Tlcona -Shelby, NC
Field Personnel is: l ;J 1 C, \ 2-'-\ ! Cl\ Well I Somp/e 10 ::?r (.,L• ~ L-;? _rl ,,.,~-~_J_,..di'C·'-/ , .. !;'~fherCondition b:9\-1 S(c;2_ Sample oa:e ___ ~~--~-~l I.>~'--~-Arrival Time \ (;. :h Sarr.pie Time I :1 ·z
Descripti~nofMe_osuring~.• •. ~J,~f,;P•I ::..,:-I lockin Co I v· /1;, _Cosing□·). Point (MP) · · • ~• -, /7 9 P D1omete :--. " ,..-:==::::::=;:::=_-.-,-~ ,r,c~~• Pu,ge Melhodl 1%.-n 71] i t1 c...-1 Sampling Method! r:t:,'.J c,fu I h (.., I
Purge Start nmel t C:J., lJ I Purge Stop Timej 8z5 I \ t i,l\, <' Purge Rote lb".:<' /mr, ...... ,.,1 Wafer-Level Measurements Field'f'b76me!ers
Interval
0
I
2
3
'
5
6
7
8
9
10
II
12
13
"
15
16
17
18
19
20
.
Elapse Time
(mins)
f'f <
!o
1<"
2..u
2-S
?.() ,,
DTV-/(feet)
1\,c;l
IS,SI
i0,Sl
l<::;",CI
It:. c::
it~.<
\C:,S
"
Samples Collected
Interval
"fc~.:.~o
,7..,::.-1
' 2 I
l 3
'
5
6
7
\\! 8
9
10
II
12
13
I'
15
16
17
18
19
20
TelTiperoture Specific Conductance
l"Ci [µSiem)
i ~l. ! 1-i (.,12-
iG. .99 1Cl I
!17 Ci( ~, .. c1n
'1c,,cR I c.12--,
I "1 nc:; i cir::
\ 9 ,I'{; 7-f)3
.-·· -
Con101ner Descnption
pH [su)
t:,, 9-1
c;, i../4
S.Lfr,
c;-,q (
f<;, y 0
S ,YI
Turbidity
(NTU)
I
Dissolved
Oxygen
(mg/L)
i ,(? I '-L 11./
0.GS y l,7 ' -0,c}i ~ t:;-:; ' -

-
0,.00 Y.S-1
n CiC:: 1.:_ ll l
(')_.'10 I i_ .~3
I
I
Preservative
ORP (mV)
11 c. -
\ !G..>
i lt-:l, -~
ii 1-.
IIS"f---
i I:,. v
--------------------'..!..LJ'-<+---1-'-""-',c'-'-"---:::.' 2,<; [f'i /.. Parameter Conditions: pH +/-0.1 standard unit COND/Temp +/. 3%
T•Jrbidity +/• 10% above 10 NTU +/-1 NTU below !0 NTU ORP
189
+/. 10mV
CNA/Ticono
Low-FlowGroundwot~r Sampling Log
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
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I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
low-Flow Grour1c!·...,oter Sampling Log
Kubal-Furr & Associates
-Em•inm111!!11fal Co11~11/ta11ts-
Project 1\10.
Site Location CNA ,NC
Field Personnel -""'~::.....S"-'-,--L...;,.?C=-"--"-''----
, / Well I Sample ID s5;; ,¼ ,;( . /i'f ,r ,Wpher Condi/ion ----==-=-c;',----/'-"-----=----
scmple Da:e '(v'f/l Arnvolnme lPf'-.J Samp:eiime __ ~-=------
Descrip:;onofMeasu,;ngl·~ I cos;nglypel ;D;,/c __ I Loce;ngCop~ cos;ng~ Po1nt(MP) 1-~ Dian1efe~
Purge Methodr,z1.1].,V;-Jtz...,-·-7c__ I Sc.--npling Melhodlr-·J""CA-7", .",-,-c:---, ----,
Water-Level Me
lr,!er•cl
0
'
2
3
4
5
6
7
a
9
,o
fl
" f3
14
f5
16
17
18
19
20
Elapse Time
(mins)
0
.... e:;"
/C-
(.~
.Jo
J..r-
&> :~s-
L/l\
q.;r
,So
~.~
OTW (reet) Interval
I 3. 36 0
i'3,u/ f
/3.t.,~ 2
i $1,& 3
;-rr:,7 4
/'3.1.:f' 5
t 3, [:.:( 6
I 3 (,S 7
l{ /; '{' 8
(3.& .• 9
I 'i (, .~ 10
/3.t~ fl
12
13
14
f 5
f6
17
f8
19
20
Purge Stop Ti,~·.=-] /;E:v
'
TemPeratwre
(OC)
-I
/ 7;79 I
I?/)•/ I
i7,9/ I
/~c)D I
/7.70 I
If,/ I I
,~.tf
/f, 11/
;r[,11
d'. 13
;,J., Jl
Field Parameters
I
Specific
Conductance
[\JS/cm)
--
Sfc
~S'"""K
,~Cj'
03
C7
0£'
'~:r-7
,,;:7
-r-1:::.
,5'(,
._s-C:,
I
pH (su)
·-
,:·;-cJ,S
l/. 7,-S
t/, S'CJ
'-/.t/ 7
:l{,i(-5"
L/ • tj ()
I/, 3f!;
t/. 3 7
l/_ 3'7
l/, 3.J"
L/,s,~
Samples Collecfed Conto1ner Descnp:1on
Paromeler Condi1ions: pH +/-0.1 standard unit
Turbidity +/-10% above 10 NTU
COND/Temp +/· 3%
+/. I NTU below IO NTU
190
Turbidity
(NTUJ -
D,clU
{),!o
0,(lc,
O.co
C>, Otl
0,co
0.0{,
CJ, C) c.,
I cJ,l>O
C>.ciO
{), t-'Li
Preservo11ve
Dissolved
Oxygen
Jmg/LJ
--
O,f~
/.f7
(), 77
OR? (mV)
1---
&7{ (.,
7d.V
7s'l,1
o,~:J l7ff.,.<
C!37 17r3','J
tJ. '-I 3 1792,)
O.c/L/ 7J?,/
0,</3 1730,L/
0 I 3fr' 17:ZR, 1
o,37 7 3/, f
{),37 7/t!,,
I
I
I
DO +/. 10%
ORP +/. lOmV
CNA/!icono
Low•FlowGrovndwo!~r Sompflng Log
'
Kubal-Furr & Associates
-E11~•irv11111.:11tal Co11s11ft,111t;;-
Low-Flow Groundwater Sampling leg /) /
ProjectNo. ___ ,/-{[;_· _M~A~V-+--
s;1e locct;on CNA/Ticono -Shelby, NC
Fieid PeGonnel L9i.C: f;✓✓1J.f;,l(~f0
Well/ Sample ID ==~:=:1:~:z::-::1========= · WeotherCond;tion ._{..;;,,;;.,7 Jc; rh,,o ----c-c'7-f--~~---Arrivc: Time ~ _ 1.1· Sample Time /.!.'/,..· ,~~-,.....::.:==.=::;----'-'";===:;----De,cCpl;onolMeo~uhng\.✓,-;L-1 Co,;ng!ypel ?l,) {., I Lock;ngCco\ __.--· I _Ccsing[LJ Po1n, /MP) !..,,/" 01cr..e::i, c;:,,( ..
"'C~<!! Pwcge Melhod\ (-;io;v C>F" 5 . Som~ling Mel hod\ (-i:z.,,. vfc S ,
Pucge s:orl-Timel / ~:;"o I Purge S•op Timel / J'59: I Purge Ro:e(:'--fcom""'"I 1;/ater-Level Measurements Field Parameters
0
I
2
3
4
5
6
7
8
9
JO
II
12
13
"
15
16
17
18
19
20
Elapse Time
!mins)
0
,-5
Iv
I :o,.,·
5t,
l-~
So
-:s.;-
4c
vs
-
DIW (/eel)
33}~
3{'20
3{1.t/
.) '(_ <I'[
$S,1J.
T5,J.t
Sr;s5:l
?ir;</1.,
3l,Qt
"Z :5 ,✓ -·. ·J
-
'
Sen.pies Collected
Interval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
I 6
17
18
19
20
'Tempe:=:1Jre
fq
~
21?/
"/.5. J .[
J'{I. 1
:LG,1 '3
17,sz.
2.7, 0{'
J-7. 9 (;
J-9,;s
.22, 7(
bbr.f'J.
I
Specific
Conductance
{µS/cm) -/o/
/,:;,.r-
/vi
le/(
/,,;-7 i
j/1)
//;}.
If{
9-<Y
7b
. ,· Container Descnpo1on
Ix IL /(Ar;;,,
pH (Su)
--
/, 9&
'3 y'J.
t./. 'l-7
'.5 ,J' ;;..
'i, 7'(
L/. fl(
er, 77
1././7
5. )f-
1(, F3
Turt:ic::,,
(NTU)
-
Cis1olved
· Ox·,';en
(.-ng/L)
--::5-; S' I ;, 'i 7
,'5,7 I. le (
S',/ ·,1__ 7/
.f-, I S.~7
/3 '.5 I .3
/ ,f ;l_t,;y
2.J. ;J.'{'.J
i; z , s-.l·
J:9 2 ··3 , ,I
I
0,2 jtf.ol I],_
I
Preservative
ORP (mV)
--
·~~'.</
2</'t.d
J/7.;
2/d.(J
lff,o•
I 7(,, ..
( 7'3. ?
//oJ,l/
;2;'{_/
'17G.,::,
I
11
I
I
I
I
I
I
I
I
I
I
I
I
Re.--norts ,· v..1;;71N6 )L-'61,,. · '];;-•, ... 1 t) To c"·" -;-1,.,,, .1 &· )i)JvJ') ·1.-...iU-,}; z t.'V 6,l.:,~)h f C<-'tv -;)le~ ~)( &P,,{11..·1) <ld.u .i.,., I -re /:u.-P 4H,~"/.<,d1F .J/c.-<1.::;i l-~Vj1A"'L fun . ..._,:<.,,w(_:-• 'i?ltj I V-<)0'-{?.J..f IIA·JC<.,:_qzfce-9 ,w-~/1 J _wcu. /,,.,, 'i7tg-f!tsf--!c,; )J a'r,!t'2Y..;k" G1:,3.r~ ~6<-(<1t1,.>,_,.) ''lJ.2<;,u C.-L/0 (:AU-v.\fi;J PvHP-t)~,~ci) w/It...;t,'-7Kvl;/rt ro ,:t.7=-r,J {'.Xv,·..-Wtilf f&,,./") j PcrometerConditiom: pH +/-0.1 slondord unit COND/Tcmp +/-3% DO +/. JO~ I.!._ I Ti.:rbid;ty +/-lO'foobove 10NTU +/-1 NiUbe!ow IONTU OR? +/-\Cm'I
l'V t..vldt<.. /Pv-0 lt.:.F i2£~/f/V"-t;~-4,';L<.. P·.:/.;it.tv i.f,L":'R. ,.-...JI).•/ lo
~~!, .r,VtPLc. .ti.so ?/1,;c<rA"-Tnui er,z4~T-"'''-<-c.11zc,1<w/.f·-n:,s
,I..~ {l,.c,;,c,,3/l;n1; ,;'~'.::~s)c,) · --i"cir.Lfvfl6,·iJ ,c.S(,-
9 c·NA/TicOr.a 1 1 Low-F\owGrou1:dwa"1er So_mPino LC<;
I
I
I
I
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I
I
I -,
I
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I
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I
Lew-Flow Groundwater Sampling Log
Kubal-Furr & Associates Project ,':o 2l, (,1') ·
-Euuiro11111rnt,1l Conrnltants-Site Locc:ion CNA/Ticona -Shelby, NC
Field Personnel _,_, J-(-S=.L..,_1 ~-----
Weil I Sample ID _v~-__,Z.~:-i.._~~...,.-,.-
,e_-~ <;> ') . U d /LI ,j";.sj'her Cond,tion ( I ()0. /.) ';/ __ ji O ~ f Sarr.pie Dale -~0~~L="-='=,--'-, Arrival Time(__...:])::> J Sample Time __ ~(20-'--'--l-_!f:_fc-~~'--==---
De,cription of ,\Ae_asurin"g ~c Cc,:n , ·1 '7"' = I Loe kin Ca 1i11 _Casing~ Point (MP) l--{) 9 yp £.· :-T.../ 9 PL.1,_____j 01an1ete~
Purge ,Y,elhod~=~~~~ Sampling Method!{ f) i Q f[{)\.J /
PurgeSlcnr.me[ oas-01 P•~•geSlopf,mel04 4'[1 PurgeRolel /€0_ --1
Water-Leve! Measurements Field Parameters
Interval
0
I
2
3
' s
6
7
8
9
10
II
12
13
14
IS
"
17
18
19
20
Elcpse Time
(mins)
()
~
~b
I S'"
;)o
;) ::;-
5 D
2i~
/.fb
lf~
~o
s-s-
DT\'I peel) !r.·ervol Temperature
(CJ
i/,(.,4 0 ,,, t £; 'C'.
t2,·12, I I~ _-z_:35
i6 ,-~ 2 \'1 _{,,_,?,
l3 ,2-f 3 17--2-9
l3.42 4 1 ·1-, 2+
L?:i.-fo s r::r. J_t
[~ &z. 6 \,-. '2,)
i·2>c, t 7 l-::,---z.:z,
i Q. ·10 8 11,2(,
I ').'11 9 1'.:f-"2-9
\~ 10 ·.o 1q.. U
l?. 11 11 1.7-; -z,,
; 2
;3
"
i ·, s
"
17
·,3
19
::,J
Specific
Conduclonce
(µS/cm)
--
553'-{-
'55'-I: '-f
S5'.,; r
~f--1''1
5°'l oo
Sb Le,;>,
56 t</-
t::.,(;J'f
'!;'bo,
Ss'&~
'.{570
pH (su)
-
'S' ,t?,
',",a I
4.C/C.,
'-I .q .,;-
Turbidity
INTUI
.-
I, 4
2.,. 0
i, 3
I, e
' Lf c,t.f. I 2. :;
<./93 /, 2,.
1../,qi-/ {, Cc,
'-/.9 3, o,q.,;
Lj_ '73 l, (.,O
4:'J'I (, '10
4,qt/ C), l,o
I
I
I
Dissol·,·c::
Oxyge-.,
[mg/LJ -
0, -f. /
0.3;;-
6.'J.7
0 d r . ,')
(.:), -Z.,2,
0.22...
0,2c,
0,µJ
C). ii!,
0, 17
0,/ 1-
ORP (mV)
-
~/-s
135':(o
3~,'3 3q_,
3C/, 'o
'1-o. I
l'fo.9
'-f I. t./
L//,5,-
'-f /. 9
½I.Ip
I
I
I
I
I
I
Samples Collec1ed Container Descnpt1on Preservative , :C<J C / V /lz.-,-1:it ~'¢ 111 1r '+t\..--fm..-f:t {.k
Turbidity +/-IC"'o above 10 NTU
COND/Temp +/. 3% DO +/· 10%
+/-1 NTU below 10 NTU
192
ORP +/-lQmV ---
CNA/iicono
Low-F:OwGroundwo1er Sampling Log
Kubal-Furr & Associates
-E11viro11111e11tnl C011s11/taufs-
Water-Level Measurements
Interval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
'
Elapse Time DTW (feet) (mins)
t1 i~.;,c;
~ l't12--
'.7 i'I 71
t1i' q {'Jj
w c1 J~l 2c:; 1Cf.G1
YJ . ·' ict I ·1
'7, C, t"I &),
4n \CJ.GS
~~ \ Cj ;:)-a .
"
Samples Collected
Low-Flow Groundwater S ::rnpling Log
tn!erval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
"
17
18
19
20
Field Parameters
Tem'peroture
rci
·1 1·,-. <., I
I~ Jib
19 LJ I
IS2,.~
·o.c:;'-1
iP, 9-f
( Pi .c.\ \.\
''ii, ',)I
. S5"C-
Spec:i;c
Condcc:cnce
lµS/cm)
:::cG 1?i
;Ll)cl;Yl
2'511
'2.59 i
1-Gc;O
21.d-b
7r;:.,71
::z_(:7<-;
2C 7~
Container Descnpt1on
pH (su)
I
I
I r-__ --i 1 , c;,,, (-,. ,
(,,c.'-f
1-. <"'G
'(, .. c:;ri
(:; 'C, (,
(a, q::;
r,.. S-A
G:,,c;--t
I
Parameter Conditions: pH +/. q. ! slondord unit COND/Temp +/-3%
+/. 1 NTU below 10 NTU Turbidity +/-i'9% above IO NTU
193
Turbic::y
(NTU)
. ,., I;.,_
II
l.O
u.91S
n c,r,
0, (,c;
::,~S' oerc; (\ (..s
Preservative
Dfssolved
Oxygen
(mg/L)
--
j •. 2.:2.
i. 19>
n.Ci9
r, lCl
0.G I
r, ci9.
' n ::,,q
0,30
o.~3
ORP (mVJ
e--
71?, C
1S'.'1
7 l/. /
71.7
13,l
12. Si'
7S,8
-,2.~
7:J2
Itq'.m,, F1.J£h'E D =-3 DO +/-10%
ORP +/-lOmV
CNA/!icono
t~-FlowGroundwot_c, Somp~ng log
I
I
I
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I
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I
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I
I
I
Low-Flow Groundwater Scmpling Log rJ /
Kubal-Furr & Associates
-E11viro11111mtal Cons11/tm1ts-
Pro;ect :. o. ---'-/_ lft JJ---'---'-¼__,_f9_
Site Lccc::.::r, CNA/Tlcona • Shelby, NC
Field Per:or,.·e/ i:::--;,;aE· f::✓,,,,.r,4·,fv ~~~-~~~--
Sample Date ._) /z II We II I Sorr:ple D -~-"CJ=• _.--';2'--'c•S°' ___ _
~eotherCondi::::n -/v......,,.;1.-7 l~r
Arrival nrr.e 1/o Sarr.pl;? -,'Tle=====/~D~/~-C,=:::;=====
DescriptionofMeasuring~c-.·nrType[k]i,,'/· l ,. C [:;] Ccsing ;:? Pa·,nt IMP) ... ~ /' us1 ~ '/"' oc ing op __...., . CL.,. <--......--Oiornete1 :,c~•• :======'--~L..-= Purge Method1·•!.ft,<17i/Z,/.,,t:... Sampling Me1hoal _::;;tc:'<--:;-
Pu,ge StmtTime\ dfS-3 I Purge Stop "me\ ,h; 5 I Pcrge Ratel L 1oucr-,.1
Water-Level Measurements Field Parameters
Oissolvej Interval Elapse Time
[mirn) DTW (feet) !nlerval TemPeroture
!'CJ
Specific
Conductance
[µS/cmj
pH (si.:) Turbidity
(NTU) Ox·,-gen ORP (mV)
0 0 it/_.f-5 0 ----1-
t ..s ;,S)3 t /6,% !'s-.r I ~J?
2 Jc) ir;&? 2 !~. 92. f32 ,5,r..:7
3 I~ /~7/ 3 /(.,,~l .f_z, 2 ·S-: I 6
4 .Jc-/(?/ 4 /(,,_ ~6 R3o Is-,;,~
5 )..~ f,{. 7 3 s /l·.f'I !J.f J,.~3(
6 3o 1-S",7 / 6 J(., tr. ,p }.h .<,3,
7 "3--S"' 1-{)c, 7 f&,7/ tz.g ,5,L/t/
8 ii,, {,•:f", 7e; 8 i7.o~ <f zc; ,{'_._('.}
9 lj~ 1.f. 1 I 9 !&.9~ d1.17 -5 ,-rJ
10 ")(! ;~7/ 10 l&.9.r: J17 5'", Ir'/
11 ss 1{, ?"J. 11 lfc .. 9f <f).r S:?c
12 C,o /~,7;; 12 Ii. f(: .fl& ,$, )"J
13 {},_<;" J:f.lo 13 /7.o) ;::x .s. f).
" 7t-IS.7D 14 /"7.o3 tJ.7 ~9/
15 ·'}~ 1( ?O. IS 1?. c•.P ,f' ;2{, ¢,' '/7
16 €0 ,...r, 7u' 16 ;7.o? ,f ,)b &-<>o
17 17
18 18 .
t9 19
20 20
Scmples Collected . ,. Con!o1ner Descnp,1on
Porameler Conditions:
I k IL fc'IJ/7C
pH +/· 0.1 standard unit
Turbidity +/-\0% above \0 NTU
COND/Temp +/-3~
+/-I NTU below 10 NiU
194
(mg/L)
---.--
/3 O.i(& -S-: I
,~,C) O,sj' /.(I, J
iL.6 O.t/,J 2·(:J.
S,7 o,3S-,S",?
t(..0 O,'(J .. ). 7
1/.f 0.ir'/ tl-S
"3.c~ /,</7 /,.s
J,,-f ; . JI Lf. I
·3,3 o,J(; -7 h
:2.f' {), (p(,, -i'/.3
Q,(.. a.,,t/ -1(0
:/,4 (', </ 3 -r1.;l.
:J. '3 O_i/o -20. 7
3, 0 'i/ -;t-,/
2.• 0, ~7 1-/~--;.f
)') o. 'J(, -,21,g
Preservative
/;l,,ut'J
DO +/-10;;,
ORP +/-lOmV
CNA{Ticono
Low-FJowGroundwo!~ Sompllng Log
C\ 0ia-
b
-...'.)
Kubal-Furr & Associates
-E1wiro11mlnt11l Co11rnltm1ts-
Low-Flow Groundwater Samplirig Log
Project No. -~'2.h=-"-'N..,1..:..ftCJ-'-, -..,_f...;)c.._ __ _
s;te locot;on CNA/Tlcona • Shelby, NC
F;eld Personnel _j~\~V~\J ______ _
Well I Sample ID ·:;cl -\ S\_,.,_.':7-\o·~ :YfotherCond;/;on -~-s=_0'-'--r-9,i-s, ~!/~-.-<:;----, \fl\·,..., ·'}IQ Sample Date_~-~-----Arrival Time l,-~ Sample Time _ _,__,__'-'-+-~~==-=cc---
De,cdpfon of Memucing\ ·1ro c\ Co,ing T• pel r, I r I lcckin Ca LJI . Ccsi~g[b:J. Poirit (,YIP) . '/ I.I V g p li Diameter ,, _ _.. -uic~,es
I
I
I
I
Pu,ge Me:hodiffip, \ '5(/\ Lil(,., I Sampling Method! t"J?)Z (STA Lf / C I I Pu,ge Ste,, ,rnel, \ O ~r1 Pu,ge Slop Tirnel ·, ') ;y-I Pu,ge Role I .., ,.,,... ,.,----1-->. L ov,'t'ei?r{ T:J · _,:..).J · ,_v--., · · ,, .. v . ..'m c,"1 , i'? <;p,L Pll/',, Water-Level Measurements Field Parameters ,.'.:::... , rJ=, · , ;
Interval
0
I
2
3
4
5
6
7
8
9
10
II
12
Elapse Time DT'vV [feet) (mim)
6 i L/ 1i·1
tq i 'J~IS°
10 j0,C)".:,-
iS (1Pl'6
00 ii:;c b'Z ..-iq . 1i'1LlO
0~ 1.n. I I
,;Jf::::; I).() .,'1)
40 :J.n ;:;.,c,
lj c:--9.0 .r.1 <;(
S'J ;:;i_l . -:i, \
7J li .G'1
C() :1,i , $; I
lnter✓al
0
2
3
5
6
8
9
10
II
12
,\, 1C{?.__ t 10.:.or:'-
I TemPe:ature Specific
(:q Conductance
(µSiem)
pH (su) Turbidity
(NTUJ
Dissolved
Oxygen
{mg/l)
ORP (mV)
----ilf----1----f----J--·-·-·-·-• I
0,11
n 10
"1-.10 o , nl\ --I 41. .&
0 [)3 -!l//./
I
I
I
I
I
13
14
.ii<oN I 13 -i----+---+---+---+----+---f----+------i----t/61~
14
' 15
16
?30r,,.,JJ; --+---+---+--15_+----+---+----+---+---t----l
('/3 (lt/c(1]l'1 --+---+---+--16-+-----+---+-----+---+---+-----1 Thl/\L.. 17
18
17 0.!.RE:i'-EP ~: --+---+---+~-1a-+----+----+---+----1c----+----125"~nL I
19
20
Samples Collecled ALt ,-,Jtl3 , J'dC/ '--n:,c.'
cl)/_ G.t.',,Cc•L
~Ar'-/ ;,;?1,i:l1f.cl" <
,4JF7Jf:+,...,E
h-"'j
-~
19
20
Container Descnpt1on Pre1er,at1ve
fie/
I
I
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L::-s-Flow Groundwater Sampling log
Kubal-Furr & Associates
-E11virc'w11wtal Co11~11/tai::s~
,0 roject No. _r_,_&"-tJ_4_q_q __
Site location CNA/Ticona -Shelby, NC
Field Personnel 5 S:+
We/I/ Sample ID -=tf--=·~'--"-.b-'S----,-, -cf(-Weather Condition Q O "-t)> 1 '6 S Samp',e Do',~ S:-· {_(,, .~ . Arrival Time l D-. Lf5 Sample Time ( 2.; ( S
Ce,cdplioc, of Mec,u•ingl -:-r.oc· I Ccsing h•I ,D d L 1 , ' C y Cosing@, I, Point (MP) · L { -· '· 1J v oc ing o.c Oiomete , ~:c=::::;==J,.. __ ....; ;,-,er><!\
C'c<ge Method I (/ Cc (l i--:>1 A Jtc I sa_m:_p"__:"9:_M_e_,ho_d_'---"'L-=-z'-=L<.-=-" )_:.._L'.:.cXJ)=--' ----
p. ·;-e-S!cr1 Time!( 0•. :SC> I ?urge Stop Timel l 2 ~ j ~ I Purge Ratel { ~Or;t.-r.;nl
Water-Level Measurements Field Paromelers
lnlelYOl
0
1
2
3
'
5
6
7
8
9
;o
11
12
13
14
IS
16
17
18
19
20
I
I
Elcpse Time
(mim)
c:>
~
I ID
I •r I ")h
I z. S"""
I 2,D
I '2,)5'
I +o
'-f5
SD
.-:-~
I r:....o
I (o'S"
I~ '-D
-11>
<co
'8"5""
DT\V(fee!)
U.t.-'5:
LZ,0c.
<31-2
[4. ~'i
j~ .4,S
tb.zz..
[1-,2-t>
~.;
t '2,, '.=),o
i '1 :2,, L
[Ci:-~:,
l.o .(/$"
'21. /D
Z.I _3:;
")l.71/
2Zf0,
2-Z. ~ {
·2:z.<f 4
Scmples Collected
1ntervcl
0
I
2
3
4
s
6
7
8
9
10
II
12
13
14
IS
16
17
18
19
20
Temperature
rci
I -I
I 'C,, 'tt,,
IIR.<;"S'"
1(9..C-t,
l(O,t.//
118.<,t,o
I i~ .+I
Ir< .• Cf--z__
[ .Tis
I • i.(. 0
I ,~_tl0
l 9. 52-
(tJ .. 5'G,
lV,,st,I
iB. l-i ,a 1 t
I ( b'.'7S
tcz_3f
Specific
Conductance
(µS/cm)
-
<(,Jq
-ro.:J
.l lf 'l-
l ,~
3, c; (o
?,<=z (.;
l.{,o I
t./-I 2..
41'1
l '2-~
(, 3o
'ft?~
4L/S"
4-so
L/,'5'f?
4 0'7
lf'12--
Con!ainer Description
. ;ye
pH (~u)
·-&,-;-o
I ,i.1-'t
G,.S-3
fo.'-1-fv
;G,_L/, L.
(o .1-'7--
/ __ '-f,S-
0 if't
G,,50
{_ .<ii
b. i/ <I
C::,, ,5' _',
(.;,, 'S s 7 __ <;7-
b. 5~
l,, GZ
C,. ~
Turbidity +/-10% above 10 NTU +/-1 NTU below 10 NTU
Turbidity
(NTU/
~
7-.z.
I 2-
f;;./
7-,s
.r-
~-0
7-5:
@7S
Bo
7D
'-/-5
.31
3b
3~
;)<;;
24
IC/
2,,?,
Preservol1ve
rf<--1
Dissolved
Oxygen
{mg/LI
-
0,'-1 ?.
O,~o
o-J?-
D-ZY
0.2-2
C>-Zo
0. IC/
01111
0,,0;
0.1<2,
0. rtv
CJ, t9,
o, ,-=i-
lo. i0
CJ, lH
o. 1e
O, rCj
DO +/-10%
ORP +,'· 10mV
OR? (mV) --'i;2,3
~~.-3
-7,q, 1"
-12, I
' G, 5:,1-
-{,3.7
-ti, I
~3-1
~.6
-C:,f?, D
-(,~,3
-'r-2,1
-13, I
. .,7-<f, I
;;µ/I I
-rj,:;'"
-~ ,t../-
I
196 CNA/1icona
tow•FlowGroundwoter scmp!ng tog
-Kubal-Furr & Associates
-E1n:it:n111i:11t.,! Ct,11$11/t1mts-
lnter,c:
0 1.
1
2
Elcpeiime
(.,•.i:-,s)
,1
,,,-
'~
IO
Di\'llfeet)
/0_,rJj . '.)
17.{-e,,
it. so
Low•Flow Groundwater Sampling log
ln'.eN0I
0
1
2
Specific Temperature Conductance
i'Ci (µS/cmJ
--· .JJ, 3 I ,) L/7,f/
'2/, ;).'{ '{'/..7 J...
pH (su)
-
,s. l·7
~L-3
Turbidity
INTUj
-· 2s
?;'j ,,_,
o:ssolved
Oxygen ORP (mVJ
{mg/L) --
/,. of" -:;/./
/() 'l. -c;; t. <f
3 ;C /t,t;;,c 3 '}C-/}7 u.y ·Si?/ ,'{; &Jl !LG C1• 7f ~.:-:,"f. I
4 l-c ;f.crJ.. 4 /-0,[6 r/.& 3 7 S:7/ :!(;, 0,7;2 -{, 3. 2.
5 J.~ 17.t.2 5 ·i:i. (,. 2. JL{<(_f :i{'/.,,'{ tJ-4 6,7c, -s~tf
6 ·so Jf/, Jh 6 :20.f-7 I J.L/ ~ .::,-:?& J. 3 o.c.'/ -rf,¥
7 1 .5~ /9.3~ 7 "Jo, ?--I 1-'-/3/ ,{"',? '} ;Ly cJ. 7o -[;/,9
8 I t(t) ;9.(:,'( 8 '/-&, 7/ J..3,77 &(;,6 3o ""-70 -cP(7
9 I i/.s-Jo.~'!> 9 7.o_ ·77 '/..1,7) f;',77 3,;z o.7/ -,:;-,{' 6 . .
10 i -!.>D ·)Jo'/. 10 J.o.y; J,/ 3 'l o':78' i/a (), (.;/? -61,3
11 ! ~--s-J.,/.(,_.S 11 ') I, 3~ '&J97 5,9L{ ...'.),<" o.f.9 -7r.f. 7
12 ! be 'J).o), 12 2/.)_{., /.( 3 ~ ,s.9,s 6.r-o.70 -;9.t/
13 I 6c-2).JJ. 13 11,13 J'Pli .5, 'l) b.S-CJ,(:, 7 -;)(),'(
14 '/cJ 2J..1J 14 i,. Jr :)t./'(L/ ). 9,... •, "' he r;J,(.fl7 -9-J.7
15 7{ .:J).,t 15 71./,f ;7!'6 .s-: 9 :J. S-.< 0 (p &, -~J(,
16 8o ;,i ;2,1.f 16 )I-¾ J."1-s-4 5 . .r(, <f-f' (). (I;<( -'l2. 9
17 2s· 1}.Jo 17 7 l.oS, J.o/S? S:f'? '/D ~ (.. '3 ---y /. fl.
18 , lfc j.1.2-3 18 :i. /. 'lie J. '7<.7 -s,9/ Sf' (!J. (: 'J. -[ &.{,
19 I '1,s-';!;L,2}. 19 ')../. 'I/ 1,C/J'( ,')°_ S'l 37 0,(pc, -f'f. 7 ' /c:o J, ).( 'r 20 1/{p/ J 7'o;r' ,:,. 13 3b a.,f"f? -9J.?. 20 I
S:::s:1ples Collected . ' Conto1ner Descrip,,on Preservol1ve
Remor<:, ____________________________ _
Parameter Ccr1.jilions: pH +/· 0. ! standard unit
Turbidity +/• IC%. above 10 NTU
COND/Temp +/• 3%
+/• 1 NTU below 10 NTU
197
DO +/. 10%
ORP +/-l0mv
CNA/Ticono
low•FlowGroundwo!er Samplng Log
I
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I
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I
~,2 df )_
Kubal-Furr & Associates
-E11vin111111i:nta/ Cons11lta1its-
Lew-Flow Groundwater Scmpling Log I} ),
Project•::. ;{£( J;;J /)blJ+7?
Sile loco tic .c _.:;C.:..N::.Ac,l.:.Tl:.::cc::o.:;n.=ac_•_:S:.:hc:e:.:I b::.Yr;•c:N..:.C.::..._
Field Persorr.a: -"'6'--l'"'[c"'' .'---F. f1._,•c.•.C-''--'l,,._,f?:-,L.C'-'----
/4 · Well I Sompie :0 {,(:: ;Z £
C ''} r I/ Weather Condijir-,c, ri.) · :--1 °~f
Sample Do:e '<> 1-.:::, /,1l, Arrive: Time @S-j Sample ;,,: __ ,_ '',,.(~3"-•,_,'_,--lc_J'_'" _____ _
Descrip:ionofMeosuring5&J . • · ~ . LJI CosingQ:J/ Po"1nt (MPJ ·7,.-"".-,/ Casing ,ype I 1· I;'/ loC'(1ngCap .-..... ..,..L,, "' c......,.., Diomete inc~~,
Purge Methodrrou, ... ·.:·1/2.i7 L Sampling Methodlr -a-=,=;,:=,,:=c.::="':=c_ __ ~
Purge Stcrl Time Purge Stop nmel /s / / I
Water-Level Measurements Field Parameters
In!e,,01 Elapse Time o:-,·: (fee11 [mins)
0 fo~ '/.J.1r
I :'/o 2'lJ3
2 il.f 'l-2,10
3 I ,z.,, J'l,f (
4 l /-S ? :) JS'
5
6 I
7
8
9
10
II
12
13
14
15 ' ' 16
17
18
19
20
Samples Collected
/a:.~, NC'·2 , Sc,/ , .
Interval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
"
20
Tempera:ure
(QC)
J/,'1/
;2 /,6t,,
1-lfo
1/'{/,,
11,-;;'(
Specific
Conductance
(µS/cm)
Contc1ne1 Description
()JL
Remo~sf'"" 1T::; ifv,1;/C -D/& v,t1'S 'T"-«'(.f
?i:'1,?l.v"6 16 ,fic:l.v/:j ?oSJ':/j(f -' ,._r;si>~.,f't..-/,S-c),"l ,.._,•
io-1,"'1p1 C _ ;JrJTt.lD,f..• '111/.o, vi'< //<OIi l"-7'/tt,v/Otl"-' -
pH jsu)
Parameter Conditions: +/-O. I standard unit
T'.J?idity +/-10% above 10 NTU
COND/Temp +/-3%
•/-l NTU below 10 NTU
198
?urge RatefL(,S"C,,,u_,,..:r.l
Turbidity
(NTU)
l3o
Frese/Votive
-
TlJT,
DO
Dissolved
Oxygen
[mg/L)
o.s-7
a,sy
6 . .:s-3
0, .JJ
O.,r-(
+/-10%
ORP (mV)
1-9 7.(.,
1-?t: ~
-;o ( C:,
-1w,/
-9J.O
ORP -+-/-10mV
CNA/Ticonc
low-FlowGroundwo1~r Somp!ng Lo~
.
Kubal-Furr & Associates
Low-Flow Groundwater Sampling Log
Project No. -E1r.Jironm,mt11l Com11lta11ts-Site Locction CNA/Tlcona -Shelby, NC
Field Personnel ._J Y J:"
Weil I Somple ID ~=1--Lc-_--,q...------,,---Z,,b .-O l(--Weother Condition C lo'-, 91 :o/.,) Sample Dote ~ ./ Arrival lime / Si~ Sarr.pie Time i Z{: Z,,l>
DescripHoool Me.asurlogl 0' f I Casioglypel ',;;/:'., I· Lockio Co GJ .casing[Ll• . Point (MP) . \..,.,-' g P D1ame1e . ·· ,nci''!-1
Pu,ge Melhodl '?Zol·t 1X'1u-I -Sampliog Melhodl LO v ,. Pcotg>
Pucge Siad TTmel / '3 '. ~ ij . Purge Slop TTmel/ 4 •. -z..p1 Pucge Role I { Z5':= .. ,.I -JO•' · ,.,,,( /;....; '!-J Water-Level Measurements Field Parameters
lnl8f'IOI
0
I
2
3
4
5
6
7
8
9
10
II
12
13
"
15
16
17
18
19
20
Elapse Time
(mim)
D
s-
L t7
I 5~
Z,o
'2,~
?,o
3,~
4't>
'K
0TW (te~t) Interval
(S', ·-:;-,,. 0
(7-.i5' I
L'?.3:z.. 2
/'.}.'35 3
\l3Cc 4
t ·r-'.si 5
19 .. ~C/ 6
\t-. '-/-o 7
l't4t 8
9
10
II
12
13
"
15 "
16
17
18
19
20
Temperature
!'Ci --
2/.27
2o -&-"~
Z,Z. 3k
zz. '1 :5'
2;?.9.-,
2,2. 7'&
2-3 CJ 0
z:i, 3,
23.DI
Specific
Conductance
(µS/cm)
-
I 23.:../
{23i
I 2. <-1-
iZ~
c l'li'.1
( 2 't l-
[27-t>
lZ0'1
{ 2 '-(. C,
pH (sv)
-
C, -q c)
C, q . (.,
l:,_ 7 3
G,. ~-6
'0-'8?,
/,,.,,go
0.<;f 0
l,_ 9 I
/,. ,g ti
Samples Collec!ed Container Oescnption
'I UL
Remarks f)'"l£J
Parameter Conditions:
I 1</l-
pH +/-0.1 standard unit
Turbidity +/-10%obove lONTU
CON0/Temp +/-3fo
+/-1 NTU below 10 NTU
199
Turbidily
(NTU)
-
3z;
;_15
, 'Cj <.,
3~
30
~2-
3c
if.--
3:
Preservol1ve --
Dissolved
Oxygen
(mg/L)
-
0,Z'}
6,2o
o. 12-
<::J, I I
ORP (mV)
-
-/2ft, i. .. ,1 Z9, ·
-13~,:..
--/</-3,~
o. 09 f-!'ls. _j
C:J,oc; '"{'f(. ~
O,o 'II 1-(<//,:..1
0-07 -/3'7,C,
D-D~ 1% cJ -...
DO +/-10%
ORP +/-lOmV
CNA/Ticona
Low-FiowGroundwa!e< Sampling Log
I 11
I
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I
. I I
I,
I
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I
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I
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I
I
1131"5' -+-
I
I 3Ll5°
I ➔
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I
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I
I
Kubal-Furr & Associates
-E11viro11111t:1ital Cl111::1tltn11t~ -
low-Flow GrounCwater Sampling Log
Pro;ect r,o. -~-'"l=...c(;,~N~h-'-(--'1~7..,_ __ _
CNA/Tlcona -Shelby. NC
Field Personnel K ! .V ----'-'=-------
Site Location
We II I Somple 10 I T-1.. ~(=,~,, ~,.,,,-;:-,r, -----
. Weather C ondi.iion ---''-'''-+l--+....;.'-'u:;,__ ___ _
Sample Date S -2_ Cj ---D~ Arrival Time 1·2--4· 0 Sample Time
DescriplionofMeasu,ing1-~r /',c I Cosinglyoel r\trj L k;n C ~J ·1--..lcc.::l,:-',gp~===;---
Point (MP) U , · · \J ..._,, oc g apLJL___j Oicr.·e-ter
Water-Level Measurements
Interval
0
I
2
3
4
5
6
7
8
9
10
ff
f2
13
f4
15
16
17
Elapse Time orw (teetJ
(mins)
_ff '1'.L.½
c:; 1~. Qi.\
0 I . l~.1(~
IS i S-.1'<
7_f) I G. lJO
J._ ") 1:-s1
/J() i~ •.~c;
3S ( l ,}.~
v\() J.0. Q'A ~" :J..!J, 9()
50 '.L(. lf G
Sc, 12.oc
{,;() »-,--'f-
(::J; J2 ~&:.
lnter,ol
0
I
2
3
4
5
6
7
8
9
f0
ff
f2
13
f4
15
16
Scc,pling M~lhodl fug )<";JJ\ trr..l
Purge Stop Time! i ::,i:=, /~ sbs-PUrge .~:i:ei 150 ml/mini
' I .
'Temperature
l'CI
-
.-, ( . ., __... i) . ...., s
icl. CC)
::LrJ OR
\ Cj_ S2..,
1q_2~
19,bc
I Ct ")-·.:i-
l'1. '.f.:}-
1c1,cn
:w·io
20,'1,q
7.c ,I.\<;'
J.0.. ~(
I
I
Field Parameters
Specific
Conductance
(µStem)
-7..c I :i,
2c;'ll
.2C\·1,..
1-S'Rr;
·'? c::;·:::i Li
7(~('?
7{~09:
-;1: l'7
:::z.c... i ,::;-
;:2-G. ·-,i.j
2b'-\S
xq~
'?.J.1:.c
pH (su)
-· I
Turt:1c:r·1
(Ni~;
7-. ::i ·2-I q"'
7, \(, I ?n
1fri l•-=(J
1rr1 ?()
1.n+ B:'.:
r. oc...• I ° C • .· ) ' J ,
liO I n'S'
'.f-.11 ... 7,..,
1)1,1
-~ \ I 1i1
·1; iO l 0
::/·, \ \ I (., ◊
·-:r-11-C/()
:::,---_\l) qo
I
Dissolved
Oxygen
{mg/l)
I 1''1, ']. q
,'\ )1
f"'.1,7.S~
0, 11.
n I\ -,:") 1n
0, I fl
6.ccr
0, i ()
(),09'
(),()9
r'\ o9
I'\ II 9
ORP (mV)
··-·
-1-=n ~
i-1 O.r1 -I?-~IJ
i3(-J.G
-1·::,,r o
"\-:?;tl .<-i
C--' ~-.:=; I •.
1--f~{.c
-i ~r~ l
-/3S,0
-t:lii.1.
-j '.:3S', i
-1:Z.4-.<
-13·+,t,.
\_~T:
--::::,:30
rn5i IL 17
18 18 l 1/3 DILL(
19 19
20 20
., Samples Collected Container Description Preser,,c,, 1e
;\7 l"'""'/:.r,.--.,-c...u,:;cccs-,,-J.reo-'l-_____ --c7r-)<-l:--,-L------------~--lO-f°f'L
·--;c, <.. kl2<-~ if<. n nf,.'C-
-< ( t:w~'-1'-l cy. ut7r:-o (._
Kubal-Furr & Associates
-Em1irv1w1cirtal Co11s11/ta11t~ -
Low-Flow Groundwater Sampling Log ('}/
Pro/eel No. k?'V;t);,} f9 ----~-~--
Site loco lion CNA/Ticonc • Shelby, NC
Field Personnel {-ft_•c· ;:;.·,/J., 'J,I{, f,_,.1 ~~=---==-cc-'-----//!' Welt/ Somple ID .:..J--·r-3 ,~/'/.sf~, ~ Wea/her Condition _S~U~,v~•"~'-1-1-~>,=-0 __ · · __ SampleDa:e_~/-·,=="'-=---_ Arrivcliime )3t/{,.. SampleTi~e __ ----,,,..r__,,;--'=b~. ·=O __ _
Oe~cription o: MecsuringEu C"sing Typ+•~., 7 I ,. C "GJI CosingG=:J Po;n1 (MP) a'.'.'... _. -a 'c:cL--Loe ing Ci-;, io·· o· I ,v 1ome e ;~c,-e,
Purge Melhodl'?;:,t;.(/r[t. 'i7'-I Sampling Method~I -s-/~f,.1-1~-?---~1 rc-----:-----~r--,~,-----; Purge Start Timel (§1 ~( j Purge s:op Timel jf)'JO Purge Rotef.../ 2.~r:-.:im,r,I
Waler-Level Measuremenls Field Parameters
Interval
0
I
2
3
'
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
I
E'.cpse Tirr.e
(mins)
6
s
Ir.:·,
l.':f
to
2-,
~()
'5-5"
'fo
4.s
5o
SS"
bo
l,;s;
7o
7..1
cfu
JS
!'iv
?<
DTW (lee!)
c;, 3,1'
/t'./0
I /c1. ·5 L'
/0.,:fc!
/0,7.:5
.//.1~-
11,11_-r·
if. 7-J
j}.cJ)
I 1.).o
( 1,<(l.,
J/2,Jo
I 1:2.9f
1rs.13
I r'3. cl(
I l~?J--,,
,·1.<?c
{ t{.c·-'
;l/,10
ii./. '3J
· Samp,es Collected
Interval
0
I
2
3
'
5
6
7
8
9
10
II
12
13
14
15 ·
16
17
18
19
20
Temperc:ure
!'Ci
-~
01.73
',LO.I-~
1c,,l~f
Zo.ri I
1();-(7
/J(J, t/ &
Jo. !"I
;J-/) ,1st
1v,09
Jc, 7,(
,;,o,fs
:J./,r:o
l-1. c 3
JI. 1 I./
)Joi/
?-.u.tl-f
1-6. y (,
J/,i"lf
'J.o,f/
Specific
Conductance
(µStem) -&7c
[C-:7
In{:,</
. 7 ...... G -)
{:, 71
(,. 71
/pfv:;-
r., 77
07(
{,, 71'
(;?ff
1,,ftJ
f::fif
~f~
f;;J-.5,-
&f-2
l,77
{;frl(
(r,JJ
Conlc1ner Oescnpt1on
pH /su) -<'5./ (:,
-.'!; (, 7
.<s-1
t;,S-1
i /,,;,l\6
&o7
.{,<?o
r,.,;9
G,t/9
{;,,'('/
{P.t(9
&,,{;,J
6,W
(,,, 73
&.1,,7
6,77..
Turbidi:y
{NTUJ
I _____.,
I /1d
I /¼.)
I / 'L[J
I / Jo
I lie
I /(;,,,,
I Ibo
I !'S"'O
I /1/0
[ /~D
I /&o
I /f:ty,
\ J:fr,
I 1fo
I ;J:o
I i7o
fr, &2 I lfto
{p,(p').. I l7c1
· 70 (p, 1170
I
0 , reser.-otive
Dissolved
Oxygen
(mg/l)
-
CJ,/{
D./ J
0.!G
o.'( o
/,/{;,
6.67
t), '?{
0,)(
0,/(c
0./J
U,jo
0.<><Y
t?,<J7
6,d b
0,(),5
0.0-~
o.o'I
6,oJ
a.02.
ORP (mVJ
r1z1f
-;,,7.'(
-1s,t;)
-nt/.f
··/'lo,/
·-/'f</c,
-;,f·{, 3
-1 rd',?
-J19, 6
-.Z.JDr r
-·;..21, &
1-;/_i'( 0
-)31.3 .
-.J.37,{
1-Jfi/
~;¼r.,
~ ;lJ<-/,7
T 2$c,'i -f J37,o
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Re ?" 'J.,tfJ✓it/t
;L-VT1;-i) Tffa1Cl) I "''" tJ,.v,A -<,,t 11<,1.c"fJ ~Alce-;, ,.t -Tu;,e,0,11 !l/6/./ Eur l,i.,•i'-l
Parameter Conditions:
S4-,t,t 1tJ::-'o...,f1uC1rn.: ~D-..·t' !t:: ,,. pH +/• 0.1 s!andard unit
Turbidity +/-10% above 10 NTU +/• 1 NTU below 10 NTU
DO +/-10%
ORP +/. l0mV
CNA/Ticona
low-Fk>wGrounawo!e;< SompUng LO<;!
I
I
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I
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I .~
I
I
I
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I
I
Kubal-Furr & Associates
-E1winm11:mtal Co1151dtm1ts-
Low-flow Groundwcter Sampling Log
Projec I No. __ 2_c_-~N.,_.1 A_,_c....,,f-!1f-----
Sile location CNA/Tlcona -Shelby, NC
Field Personnel _k~v_J _____ _
Well/ Sample ID -.,...1 c'-1-_L\.__-,-___ _
Ci Weather Condition (-\6:~1 '.uJ 'S Sample Dc:e __ 5LJ\~2-::::s=:c::lc::::,\.::::\ =,---,..;;;,;~'.:.4."2:f::;>:..c5D :"--=--,_..::::So::'.:m'.'.'.ple:_:TI:::._,m:;e=-=--,..Lrn::,""',;;=~= ~=-= ~;=-, -_ -_ -_ -_ -_
Descriplicn ct Meosuringf L( U I Cosing Type ~/::f;T Locking Cop! ~ / Ccsingu:J Point [MP) 0 V Oicmet;:, . ~ ::======:::::....-----: ,nc"e' Pcc,e Melhodlfui1s:rt1,i-r1 c,,,. I Sampling Melhodl ,Pgz_t Sft'l\.11 (., I
Fur;e Start Timel I 0{ 6: le, G/G 7 Purge Slop Timel \ 1 C, "D I Purge Sc:el /,;b ml/m,I
Water-Le,el Measuremenls Field Parameters
lnter,al
0
I
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
:i::pse Time
(mins)
I ..£J
I s--
I In
Ii<·
I 1-0
I -? c;
'2.,Q
-::,c
l ()
Ci(""
c;o
'7~
r;. ,-,
I ,.,c;
DTW (ieet)
0. ,;,_::}
Io ,I 0,
i/.r,<"
I ,61
11,c;rJ
l '-L'.34
I y ?_?;
\4.°lo
1.s.0c;
I r;, .1,<.
\ t.12.
!~ ,1-1
·:,,c·o
B ,cl .
"
Semo.es Collected
lnl'.:fVOI
0
I
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
Temperature
!'Cl
IC/,7Co
19, <ol
(q_0l
14 11--
icf-,o
\9 1-1-,
\CJ' e:·::i--
( CJ.Lfc;
\CJ.<;<l)
1.l! ,li~
z..o ':'J l
2 O , 0;::;
7..o,'f'f,
Specific
Conductance
(µS/cm)
'-J 1 o
Sbq
c:;-<J-2-
c;-C1C.
S{,j½
t:j'l-']
<;~?,
c::;-1--, I
'7 1-&J s~n-
.. ,i\9-, '),
S92.
Seil
Container Descnpl1on
{'x/L
pH (Su)
~.23
?,.o~
C\ Jl
a,ns
'$-),,{)\
'-t.99
0.00
1--9(,
::l-9 0
9,01
0.CG
q_Oo
9, o~I
Turbidity +/· 10% above 10 NTU +/-1 NTUbelow lONTU
T'..:rbidity
(NTUI
/OD
11 m
(fV,
iln
irv,
i ').,!)
tw
\ i 0
\ 17'
\ ( D
lZ.O
ilD
(10
,·
i/c(
Dissolved
Oxygen
(mg/LI
O.oB
o.olf.
C) C4 '
f) nC,
0 .CJ--.\
0,01
0,0-:::/-
ll. f\C-,
ORP (mVJ
e-l RG.7
1-?cc ~ -;:, r p.c.1
-2[C/5
-22/.1-
-220. 7
-7-74S
-221-,1
o, os l-22,;.-,
o.oll ~27..2.'(
1·1 oL! ~ 22'-. ::/-
o ol.f ~ziq <r1
o.ut -z-z.,.c:;
DO +/· 10%
ORP +/· I0mV
I rv::N
TBT-c
7·50
/'VI €.1 IL.
202 •.. CNA/Tlcono
Low-flowGrovndwo!er Sompn~g Log
Kubal-Furr & Associates
-Envir,mm(11/al Co11srdt1mts-
low-Flow Groundwater Sampling Log
Project No d0 ,,JA-?9
Site location CNA/Ticono • Shelby, NC
Field Personnel (;-:£6Z, ,t ,,ef,4-,f>v --'==-~-"'-'--''----~ I. j, We/1/SannplelD --:f.I~T~-~£,,,,_ ___ _ S/~S ,; '{ /1 Weather Condition .f°J,v,v/ ~f SompleDc:e __________ ArrivalTime(;'Sc Sompleiirr,e /8/,{
Descrip!ion of M~osuring~/ . ~ C · [ZJ Point (MP', /c.r ':.' Cosing Type >r/.a~? Locking Cop tt.L> osin, g , ·\... ~...:.._ Oiotne er in:r.e,
Purge Method I 7K..:7l.1J·~77r:...._ I Sampling Melhodr=,:;.,,:::;Fi/7c°'~~-'--...;
Pu,ge Siad Timej /""h 0 I Pu,ge Slap Timel f't,'1( Pu,ge Rat•~·l/ ,1',?m<,.-.,1
Water-Level Measurements
lntervcl Elapse Time OTW (I e'I (mins) e _;_ "!. f-~ ;.,,;
Interval
0 C> /tJAfJ 0
I .,;-/{~ Iv I
2 le> /C . .f;( 2
3 /J il,{.s' 3
4 .J/0 /'uf.,OJ 4
s ¾ .il/Js 5
6 $6 ;J. 7'/ 6
7 '.S,:( tlli9 7
8 l(c, 1'5./~ 8
Tefnpera!ure
IOC)
/.&·
,; !f
f--f"T _. -I C:'
;91C,
·J,) J-lf
:}0.77
Jo,~6
Jc1.s3
*·f3
:JJJ, 3
:;,_;_ft,(
Field Parameters
Specific
Conductance
(µS/cm).......,
.1-m
;s?"l
f l,-S-
Ii ?--S'
/{cit/
;L,LO
/&a3
/,59,,
/.S-f-7
pH (Su)
-~~cj'""
,), y 2., .
-~Jllj
.s. 39
~,S-3
'S-.s1
,<, 79
-r-.J-c
s;.f 2
Turbidity
fNTUf
~"
7.r
--~-s_., ss
!co
fco
le
&:>/)
t~ .... 5...-
Dissolved
Oxygen
(mg/l)
ORP (mV)
A --i~r-<~ . ,,· ,c;r, :, r -

.

-
2. -~-( 1-&t'.o
I. I I f--c:;r;;
O.t/o 1--01,1.
d, ,,.r -(, '?.J'
a, I{ -(, 7,f'
0, l' (, hft.9
O.o,:,,~ !-f.;2, J
cl,a3 -fo,7
9 1/-S' 73,.s-c,, 9 :k.&? ! .';) 8/ s,t, I ~ 0,65 1·-J /.?
10 ,e; 0 (3.f:s✓
JI . .ss /3,'}9
12 ((if) /{/9
13 &~ ti/ 3 s,
14
IS
' 16
17
18
19
20
Samples Coll~cted
Poromeler Condi1ions: pH
10
II
12
13
1,
15
16
17
18
19
20
;}0.&3 ,,...,,-o 1~ br
fe.)9 I 1-s-s'2.
'JLJ if-'-/<-r-~(
fe,¾1 I s-'f7
I
'
Container Oescnpt1on
'V~VVlvJ(.,(.
.1)t'>) ro ..;<
+/-0.1 standard unit
.:;-, y '{
,s-; i)j
.:;;9'( ~c;0.-
Turbidity +/· 10% above 10 NTU
COND/Temp +/. 3%
•/· l NTU below 10 NTU
203
I ~< 0,0J 1-14. <f
I ·"'7,"> u.o3 hfa,f
I 7o {Jo']. -f/,o
1 ·70 O,o3 -%2,.s
Preser.-otive
r;,.unr,·f"'"'
DO +/. 10%
ORP +/-lOmV
CNA/Ticono
Low-FlowGroundwot_er Somplng log
I
I
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I
I
I
I
I
I
I
I
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I
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I
Kubal-Furr & Associates
-E1r<1in11111u11tnl Conrn{tanls-
LO\,-..•.Flow Groundwater Sampling Lbg
Project No. -----------
Site Loco lion _C~N-"A~/T'-'ic-'-o-'-n-"a"----'-S hc..eccl=-by".'--'N-'-C-'---
Field Personnel (:--,,t..-c;-{::,oU.'-{ ,f,-J
4 Well/Somple/0 J f -(::? /4 ~-✓ ·~ ,')/ I -x-'~_o:herCondifion f,l?L/t.7 C4.,v"i:>/ f'q,. Sample Dale ,) ~ O A,ri,al Time ~0 Sample Time (0/ ,J ' .
Description of Me_as~rin~ Cosing Type~ Locking Ccpl Casing~ Point tMP)~ -~ _ A..lti Dicn,ete~ ~====---_; •"C~., Purge Melhodl '0""Zr--J,,✓{L/Z Scn1pling Method I .~~.C.~; ,---,---:-----=~~--~~~~ Purge S\crl Tin·,e 'f:Yt/ O \
Water-Leve! Measurements
Interval
0
Elapse nme o:w (lee/)
(mim)
a /0 (0
Interval
0
Purge St:)p Tim-=\ /o I/ Pu1ge Ro1e{-'1:-/ t·~1::-:-.:rl
TemPerature
l'Ci -
Field Parameters
Specific
Conductance
(µS/cmJ --
Turbidity
/NTU/
-
Dissolved
Oxygen
lmg/L/
-
ORP {mV)
-I ,< I I, 1 o I /<f,'77 .soi.s-'s,97 90 J,9o V0t. <f 2 jO IZ.t/6 2 /k,9:< s7c6 ·'3_9'( l/0 /. '7"7 /,/7. :i.
3 ,~ (3,. '2,S 3 /'zc'). .'S'/3? Lf_, co 3'3 0, ef Cl /()/. (
4 -Jp (5. ')7 4 l?ci-:S--s/s3 l/.ciJ. 3'a 8_,]'j '!J':.-r
5 -9-S l '-l.7t> 5 19.fo _,;-1'7~ 'lf.C(_, '3~ CJ.;},)._ 9'1":3
6 $.? t.t'",.so 6 /'-1.1{ 5/'t'/ L(,of -3 ;,7_ 6, I "jl '?3.f
7 "S,r ,s. f',¥, 7 !CJ. 3'1_ ~,l_)S"' L.{, I'). '3'( a.,1 't{.·s'
8 L/C, IC, v.s-8 /C/._'3-7 ,::-21'1 i(.,,,r ·3,_r 0./'3 96./
9 <f< /&. '}9 9 /'?,1/J -s-Jbt ((j&, ·3,s O,r:3 ff,'l
10 ,<o i7.,So 10 /t1,r"1 ,)).?R Lf ,I 'r '3...r 0.1;1 J>7, (
II F~ ;c:5:s-s /f-.c,o II I 't. <,, ( sJ.?9 l{_ 'J..J :i.7 15,(3 fG.o
12 bo /t. <f/ 12 l't. '77 .s'3J'f tf. l-4 '.,S-tJ, / 3 !lf. </ 13 13
.
14 14
15 15 .
' 16 16
17 17 ' 18 18
19 19
20 20
Samples Collec!ed Container 0escnpt1on Preservative
Remarks " l:41, ll'i,,1 • J ._C iv A-f 'ti.SJ' ,,J (. -Ll,i> ·t)v'"'W Wt'-c..-✓1;c.lf ~r,,p:J.1tL-2.e", ·7c.,,li]/7J ~ ./tJa, &Zt..·l/f'f'll/ 0 qi .C1:f<'JlC-,ft<, f/x,l,N<.-7;,,,J §;rcct1-r a,0'-Vl)J'-,v ,S7;,p~<.c-'i:\:<:.,),--,) '7'-' .Sd,f(Pcc"
& ~-r-°' )if?J1JfL --,,,.MZ. Pv;<'(~ ~ 's G Parome1erConditions: pH +/·0.1 stondardunil COND/Temp +/-3% D +/-10%
Turbidity +/-10% above 10 NTU ..-/-1 NTU below 10 NTU
204
ORP +/-lOmV
CNA/Ticono
LOW•FlowGroundwo!~ Somping tog
Low.FJow Groundwo:er Sampfing Log
Project No. -~:J~b_A.c...._JA,__fJ-<-9_ Kubal-Furr & Associates
-E11;..1irrJ11111e:11tai Co11rnlt,mts-Site locotiori CNA/Tlcona -Shelby, NC
Field Personnel C::/4Le F , .. , ✓-~ ,r,·, ---='--'-~--'-'-'-'---
Well I Sample ID -~-=' =---~1_-_2~---s' / /4/ /4 WeotherCondition ___ ,(._,..,_'•_·"-~'7,,_,_~.:,.Cccc·J~----Samp:e Oa:e __ ' _/_ 22_6_'_('-----Arrival Time --.,J~l-/_'-+-/-"_S:_o_mp:_le:_J;:_,m___,e ----,;:;/:=.;J.::::/::::8'.=::::;----
Descriptio:1 or Measuring~ Ccsing Type~d· Lockin_g Copl N, I Casing~ Point (MP) .,,.., / 1£-ZL Diomete . Vl.--. ,net-~!
Purge Me:hodl "jf;-:;;Jl,,._S,n?'l'77L
Pu,ge Slort Orne j /OSS J
Water-level Measurements
:===='---~ Sampling Methodl J::"7>t1c,-:-
lntervcl
0
Elapse nme
(mins)
.D
orw (feet) lnlervol
!(,70 0
Temperature
('CJ
-
Field Parameters
Specific
Conductance
(µS/cm)
-·-
Turbidity
(NTUJ
I-
I _s-;2.)s I /';,ftJ 2'/73 lf,(JL( I /9
2 Ii> /3,~{) 2 11.f~ ;L'l-73 '3 g,f I ;,q,
3 tS /'{J6 3 /7'.~9 7ls3 1 .. S9 I-!"
' ).o l'i~ 4 /'-/_-Sf:f .J.'r't<J ,Y,9t/ (6
5 .1s· IS/JS 5 /9, ,S-,:< 7/J..7 ! '-( c?o /4
6 :3,:<, /&&7 6 /9,-.f '/ ..J.'1 rf 3.79 /<
7 1s-,~rf1 7 /l/.f'-{ -;;.7;11 i <' i I ill
8 lfc~ /t,o7 8 1,1{),0~ J_') J~ t/.o9 I Ji
9 ~cf !& .. tf' 9 '.l,, { 'r ~91~ L{{'L I /1/
10 ,,:;D /{;,,']<< 10 ¼J, )1 1-t<F'r' 1-f. I 7 I i'i
II .s.s ilc.t{Z II '.&:?, f c '} f~(; cf. 'Zf I /3
12 1£;() l&J(f 12 'J.C,, ~er ·-,) 2..fS-l-l{, ').t.f I !3
13 b~ /f::-rl-13 JC-,7(: '1-f'-/C> ~·. J.{, I 'I/ 14 '7a /<,,,·(),; ·~ 14 ;/f,i,§1 '}.e1;;--l '?'f ·1' . I I;;
IS 15
' I 16 16
17 17 I .
I 18 ,a
19 19 I n 20 I
Scnoples Collected Con101ner Description -neservotive
c'U<l ('(,:+ f c,~,~-,,1,;,r,4,,,,,,,.,. J, f';: zl,a,4 ( 3':e? ,VV~-ZK'(.;:~
I{ A)/) .J
Rema,ks pv.,1?•»& (!:5' J:Ccl·U 11.J Pc..JJ;at·-ti,t'VC()"w,,) ,i,v ,-,.,,-
Dissolved
Oxygen
(mg/L)
·-
t-{, tf{
i .. 3 6
0,7t(
0 .. <{3
qJ(
0, J.)
O,J,3'
CJ,,)i
{I, 27
t?, J.)
0,)f
c;,)J
0, )-<f
0, 2,f
ORP (mV)
--
IS[,o
/(-tJ, f
I~<(
r•S-,1
/,S'/, 7
I ,R,,J
t</7..(
/<(2. z_
13'? I
I J~,2.
i33, ;i
I 3/. 0
f''>t1,S
/3o..c
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
,'(f/',l• :w/L .rr0,c--i)c>-t,~,'1) ._(,jµo,,;-
~-,.,('(. PL..fL-6. ,-,-'\_, j_ ~~ I
Paromeler Conditions: pH +/. 0.1 standard vnil
Turbidity +/-10% above 10 NTU +/-1 NTU below 10 NTU
205
+/. 10%
ORP +/-10mV
CNA/TICOl'la
Low-FlowGroundwot~ Somping Log
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Low-Flow Grour,Cwcter Sampling Log
Kubal-Furr & Associates
-£11~•ira11mr:11ta{ Com11/fa11/s-
2C JJ ;';,-9? ProjectNo. _________ _
PC'geSlortnmel/2ss I Pu,geS!opfar,el zq«> \
Water-Level Measurements
!nlervcl
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
Elapse Time
(minsJ
D
.~
/l.,._,
,c.r
;,b
)S
3v
35'
lf(j
<-('{"
,<;"o
s:s-
'7t
l,:;-
7,:;
orw !feet)
_IL( J~
/'t._76
lt.•7?
i'i.9(
{,),( 3
J~')).
it:'Jt
. "3-..( I,!,,
•S:C/J.
Jo.i/t
iCSS'
tS;J'.J
'~ -..( /0.·S
/~<.11?
{,f', :,--y
Sarnples Collected
Interval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
ia
19
20
Tem~eroture
['Ci
--
f0,f{
7£;,s,<f
H-'.'{f
'Jo, (,.y
JL-J,::o
:Je,<( f
;J.;,r.r
JI/. 2C:
'J. o_ <f ;2
'.!.C\'7S-
;La 0.r-
'/_D, (,, 8
-'J.c,, Jo
Field Parameters
Specilic
Conductance
{µS/Cm]
--
1.$:; 2.
:2<t'l7
'J.'1?3
'JSc;).
l-5c)
?.'{9}
;t.do
;s-37
J_,:-;o
'j '-( 9 i"
'l-ttfS'
J_i{77
l·'(I,. (?
pH (Su)
~
~
,S":36
S-.J-?
,5-<(;l
!S,S-CJ
S': G,c,
6h:2
~.?,r
£k.f-
5. 'I (
.~f--;
-~<ff
t(,f.f,
S"-;("7
Con101ner Description
Turbidity
lNiUJ
--
:,sso!vec
:Jxygen
',mg/L) --
9~1 /,'t6
9o I o.7?
ORP (mV)
1-
1---
1-7),6
1&7. .;}
_,&~ I o,?-9 1-?J. J
9cJ I o.:J.o -7<{.7
f.s-c'.11c -:>2 s-
&-~ O,t'{ r-7.r...r-
P,s I C,( 3 1-t~'(
[s,S' I o: t/ l-9J.t.f
S.5' I Q;/Z 1-93,3
jf..{"' o, !I r 'rt.>
<f,c c,, I :1 1-?b:f
JLo a. tr 1-?C'{
f--o 0, {/ 1-'7'(.<)
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Preservative
-
P.emorks ___________________________ ~----
---~------------------"-f~-'-•--f_D'f_a"~>'-'(-'-+,·.2~'..fiH.,.,/-=L~-~za'-C:-~/t{<,J'.6rv<...~£2,_
Parameter Conditions: pH •!· 0.1 standard unit COND/Temp +/-3% " .,ltl/
Turbidilf +/· 10% above 10 NTU +/-1 NTU below 10 NTU ORP +/-iQmV
206 CNA/Ticono
.~w-!'IQwG·::undwot~ Sampling Log
Purged Well Sampling Log
Project.No. Kubal-Furr & Associates
-Enuiromnenfal Co11s11lt.1nts-Site Location
Field Personnel
Well I Sample ID
CNA Holdings/Tlcona, Shelby, NC
{'P2c6 /<f-wki>,__,
':; / /( Weather Condition ..(' u,v,vy Q'O'J Sc,-:-,ple Dale ' /Ztf/y <. Arrival Tirne /c('sS-Sample Time
7
/{:, 00
Descripiion oi Measuring\__,-\ C . E;J•, / , . 8 cas:ng[LJ Poinl IMP)! · / •'L _asing Type / vC::, loc<1ng Cop ,r,:, Diom~ler . .
1rcr,;;)I
,o,~I Depih oi V/eH Be1,lo1Pw?J . ,C-_ rL-/ ,-.,:I . 06. 0 4
_ _ Common Gallons oer Foot Corwersioos
,.,,\ Dep:.-, lo Waler Below MP?I S 1. 3~
Cciumn of Waler in Well?1:===.!:;·,;1=,=/=.7:;:) ====:1 ~-=~=====::::;''''
Gcl!ons of Water per Foot I O /; 3 I (see char!)? ·/( /;: gel/foe;
Gc!lons of Water in V'/eJJ?
Gci:ons of Water to be
Purged l3X)?
Purge Method?
I #-J.-Pry~_q(e,I
I ; {/, '3 _:;--.J
I 1&4tcl-~ I
Purge S:orl Time'-! __ ...c/_t.._/_3/,_· -!( _ __,[
Tempera lure
Speci~ic Conductance
Turbitidy
mv
1 1/4 in We/i Cosing= 0.064 gal/ foot
1 1/2 in We/I Cosing =·0.092 gal/ foot
2 in WeJJ Cosing= 0.163 gel/ foot
3 in \Ne!I Cosing= 0.367 gal/ fJot
3 1/i in Well Cosing= 0.500 gal/ foot
4 in Welt Cosing= 0.653 gal/ foot
6 in Well Cosing= \ .469 gel/ ioot
Total Gallons Purgedl O ,,---I
:=· ==·_::,=·• =--:,==g~ol
Purge Stop Time ~-------~ 2 3 4 5
rnu NTU NTU
mv mV mV mV
1 _ Samples Collected Container Description Preservative .
/)< IL t~A....
.5, oc
2. 3~
JlG
J-/,,f
. f...,,++,,,_ ),. 1/'!, L 7c57,LrvJ.(€h"'--3', < +/-0.l stondcird unit COND/Temp +/ 3% 00 +/-10% ··
Pcrome/er Condilions: pH
Turb'o'ly +/-10% above 10 NTU +/-I NTU belo·,1 JO flTU OR? +/-IOmV
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Kubal-Furr & Associates
-Em.!ironmental Con:;1tlta11ts-
Purged Well Sampling Log
Project No.
Site Location CNA HoldiJ!/TlcoQa, Shelby, NC
Field Personnel Z'i't' / _,,::7 f: l.t., .-1 Well/ Sample 10 CJcJ. ;2 Ip &, / <( Weather Condition -!~u ,v /\) 1/ ifof
Sample Dote "/(/tr Arr'·,clTime ///.3 Sample Time ;c/r(-("
Descrip,ion of Mecscri.sg\ / Ac I C T \ ?U, -I . . E Cosing[2] Point [.\\?) c., ,,. OS!ng ype L-,. Loc<:ng Cap v D. 1 rame er rr.c!"'.:;:
To:ol Depth of We!I ::eao,..,! 0 '7 / { ~ I . ::?;) ,:,<.,,;f., ' .J lee:) Common Gallons per Foot Conversions ~===::::::=:;
De.0th to Woier Below ,1??1 / 3, 9J I
::=· ~lee,
Column al Waler in Well?! . .J 6/, 2 C) 1 •• ,1 ~========:::::::::;
Gallons of \Voter pe,· Foctl / C, 3 I [see cr,ort) l U', . cc'I'°"'
Gallons of \Noter in Weil? I -1?.'J,. ·77 \ . __) gel
;:==I=/ {)=f =3 I ====:goll
Gallons of 1..Voter to be
Purged (3X)?
1 1/~ in \Nell Casing= 0.064 gal/ foot
1 1/i in Well Casing= 0.092 gal/ foot
2 in Well Cosing= 0.163 gel/ foot
3 in Well Cosing= 0.367 gal/ f~ot
3 1/i in Well Casing'=. 0.500 gal/ fooi
4 in Well Cosing= 0.653 gal/ root
6 in We!I Cosing= 1.469 gal/ foot
Purge Method'? I· {!.--;t.i:/.;,c:,fo J I fatal Gallons Purged! ~====~ ;::=:;;:;;;===== t/&,7 g~1I
Initial
Purge Start Ti.-nel i3c)<., \ . I Purge Stop Time\ &_}1
2
3 b,z?
3
~~-=--,~--/.32·?
4 5 Volume Purged
al :s cl L/ 1
Lal
Time
Temperature /t,_cf, .5 c /7,/0 •c /9,J7,c
Specific Conductance /(; 3 ,s /7t. ,s /f] ,s
p:-1 C, 7 :&, eoil, '7, ;2 'd cc;" '? :2 ]d uc,;:,
oo' .S, ;Jc>m IL J ~. 1,
Turbifidy /t( D mu J. <-5"'"
ORP t.(1, c,) mv J,P, ( mv
I
Samples Co!le~ted
Parameter Conditions: pH
Turbicf1ty
+/-0.1 standard unit
+/-10%obove IONTU
al
'C
µS
m /L m IL
NIU NTU NTU
mV ml/ mv
Preservative
COND/Temp +/. 3% DO
+/• I NfU below IO NTU ORP
G~~le
h.M
iYLfS-
i '1, 2. l')
tsY
(,,. c;-t
Cf,%
(10
'-t I
+/-10%
+/-IOmV
Revise 5/23/02
Purged Well Sampling Lag
Kubal-Furr & Associates
-Enviro/lmental Co11sultarits-
Project No.
Site Loco/ion CNA Holdings/Tlcon . Shelb , NC
Field Personnel 01 l-0 · 0,i Well I Sample ID CO -(' CO h; ell Weather Condition -..\ c,; '\.,' ,v 7;-st-, -Sample Dote _ _,:__;,______ Ar:iv:il Time // /3 Sample ii:-:--,e / \) /·~
Descri.ption of ~;;~!ul~~gll • J CC., I Casing Type I';/,/ /JC I Locking CaplY7 Casing';21 ~ Diameter~
Total Depth of Well Below\
,',tP? /-~ .J,~~ ,.J
Depth to Woter Below MP?!;:: ==2::::::::;::f::;,:::·=J:::::::f=:=,.:::J
Column of \.Voter in Well?I i }7
'-/ · 7 ) \ . I , •~ '•••
Gallons of \Voter per Foot! 0 f&-3 I {see chart/? ' go'ltoo: ~====:::'::::=:: Gallons of Water in \.VE:11?
Gallons of Water to be
Purged {3XJ?
g CJ' J7 goll
Co,11mon Gallons per Foot Conversions
l 1/~ in \Ve!l Cosing= 0.06-! gal/ foot
1 1/2 in Well Cosing= 0.C,92 gal/ foot
2 in Well Cosing= 0.1 63 gal/ foot
3 in Well Casing= 0.3::7 gal/ foot
3 1fi in Well Casing= 0.500 gal/ foot
4 in Well Casing= 0.653 gar/ foot
6 in Well Casing= l .4i9 gal/ foot
Tot::i! Gciions Purged\ '.:::======
s -;, gel! . (
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Initial
• ✓;, ,Purge Stop Timej Cd 1'1& o -., '---'---L--"--''----2 .e-.:., 3
It/CD I
4 5 0-s O,.n,,{' le I {i,v-Q., I
Turbitidy ,9~6,,ru
ORP-/. ~ mV
Samples Collected
=-
rHU
mV r..'I
Con fainer Description
o•
•c
µS
std,.mi1s
m /L
-I Ci l~ I
ll.1__1
·'67-c;
S.36
2-, c;;-
I
I
NTU > ll oo
m'I ~ y;,b
PreseNotive
Remo,'.<, -""""µ.....c...,~=--co------.:--------,--,---:,---------------7,)U,,(,1 ?t,\
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Parameter Conditions: pH
Turbidity
+/• 0.1 s!andcird ury·it · CONp!Terrip +J-3%
+/-JO%above'iONTU +/-1 NIU below IONTU
DO
ORP
+/-10%
+/. lOm'/
Revise 5/28/02
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Purged Well Sampling Log
Kubal-Furr & Associates Project No.
-Envirownentc.l Co11s11ltnnts-Site location Shelb , NC
Field Personnel lu
Well/ Sample ID C)O ~ J jt / Weather Condition -.:fu~;,,17 ,, sfqr
Sample Dale {,, / '£) I Arrival Time /113 Sc:nple Time mr
Description of Mecsuringr::::::::.-7 . l9.7 . ~ ca·ing~ Point (,\IP)~ Cos1ngType~Loc\c1ng Cap~ Oiam~te~
Total Depth of Well Berowl
/,I.:'?
Depth lo Water Below !v\P?
Column of Water in \Nell?
Gallons of Water in well?
Cf;_{; ·1,.J
/eel
Gallons of Water to be LI 1 D I Purged (3:<)? 1C-, <.f gol
Purge Method? I 3/¥,.) ~fi-,J I
Purge Start Time=:~::~::1:z:1:G~-:::::
Volume Purged
Time
Temperature
Specific Conductance
Common Gallons q.:::or Fog; Conversions
I 1/4 in Well Cosing= 0.06!.. gal/ foot
l 1/2 in Well Cosing= 0.092 gal/ foot
2 in Well Casing= 0.163 gel/ foot
3 in Well Cosing= 0.367 gi:il / fool
3 1/i in Well Cosing= 0.5CO gal/ foot
4 in Well Cosing= 0.653 gal/ foot
6 in Well Cosing= 1.469 gol / foot
I </., ,,, __ ) I T ol-:JI G::=!llom Purged c.. .....
~-==;::=;=:===g=:ol
Purge Stop Time(~ __ /~L-,,i~5c.,' ,,_J __ ~\
5C-Zli"?'
Samples Collected Container Description PreseNolive
-~ _......, Remorks 1. •
{(,/7-rv,'
Parameter Condi1ions: pH
Turbidity
I IL IX k~,,_
+/· 0.1 standard unit · COND/Temp +/-3% ·
+/-10% above IO NTU +/• I NTU below 10 NTU
DO
mP
/s'-/::-
1 c;, -'2--°I
CZ"{
i, I I
·z .cio
GD
'2-q,y
;2(, ?o ',-'l-1.,. Lz.·,.._
+/-10%
+/-IOmV
Revise S/2":C2
Purged We,! Sampling Lag I
Project Na. 26 ·'v'f.---z:z_ I
Site Location CNA Holdings/Ticono, Sh lb , NC I.
Kubal-Furr & Associates
-Enviro11mental Consultants-
-
__,,_6,=· ')-C-..,_· -""-'JF-'-"'-1"'""--'?t-__£.::..._c,.,._· _.L,-~/1'~. I\ f/,1-/ ~ . J,.;hf'"",-i)U -■
\
Weather Condition ff'(R, .. C1.t-1A(/y gts
Field Personnel
Weil/ Sample ID
Sample Dote G I \ oj Arrival Time /&,?le Sample Time // /,r' I Descriplionof,\\eosuringl /(' ; · IC_. T ~~L k" C \7 Cosing~ Point{,'v\P) ~ \.0"-"' a~ing yp .... ~ oc ing op~ Diameter~
I Total Deplh of Weil Below\
f-..·\.='? Jt2,K.J
Depth lo Water eelow ~1P?I 2_; / () 7 ,.J
Column of Waler in Well?\ .?l <{ 'j, (; f{ , ••. \
Ga:1oni of \Noter ~er Footl {) 1c I (see chart)? , / 3 ~==-=' =='-" :=::::':acl'::::::;/fool
GollonsofWoterin\'/ell? I ,5/, 72 gar)
Gallons of Water to be
Purged (3X)? I /9, /t:, gall
Common Gallons Of'r Foot Conversions
1 1/~ in \.'/e/1 Cosing= 0.064 go!/ foot
1 1/i in Well Cosing= 0.092 gal/ foot
2 in Wei/ Casing= 0.163 gel/ foot
3 in 1.'/ell Cosing= 0.3~7 Q·JI / foot
3 1/~ in \.Veil Co5ing = O.SCO gal/ foot
4 in Well Casing= 0.653 gel/ foot
6 in We/I Casing·= 1.469 gal/ fool
Purge l',\e/hod? U Q..\,U--1170;,-<; I T otaf Gallon; Purged '.:I ===· . .__,,;::C--=.J,:;:-===gC:::c')
Purge s:arl TimeLI _L/,_,,(i;;:.:'5:..,2=._ __ ....JI I Purge Slop Time(~-~/_)~/~(,;...,__ __ ~\ Initial 3 4 5 Volume Purged
~~'--..li.S:-l--.t......:::..-"'e'.W....J!.C..C::C..l<'"l------""'or-1--
__ _,,'4-__ __,,"".I
pH
.I-.L...-=r'-'1--....:..---""=c+=-=c+----""'-"'"'!,,C......--'1'
,,_e "'-""""'i:i'l----"""-d "'-""=/:> DO
r.: /L m /l
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(J I •. ·1"1'.1 l,:J;..,'f lk'.
'}..00
f7'2-
. .., r,O 7,vo
'3 ::w
1\
I
L....<""--..=J_-=.,_1..cm~VL-'.....;,7C....·7'-,(;/,,-"-" ~•, __ .:.::m.:.J.v __ ...cmc.:.J'l __ -"'-Cmv -[ L/1. lf
Cont~iner Descrip~ .;J..7/ ; fl,
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Samples CoJJected
Parameter Conditions: pH
Turbidity +/-10%obove iO.NTU
~-~reservative
.DO
+/-I NTU below 10 NTU OR?
+/-lOTo
+/-IOmV
Revisd/23/021
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Kubal-Furr & Associates
-Envircmnental Consultants-
Purged IV eil Sampling Log
Project No.
Site Location CNA Holdi1c=icona, Shelby, NC
Field Personnel G,.,_ \ Jf \ \-;.L.J
Well/ Sample ID
I \ Weot>y~ondilion -QM..."[ (L,iJ1-\.Q'{ £;.{s-Sample Dc:e (;,I\ c'-\ Arri,ol Time __ .c/_~~ __ 0 _· ___ Sample Time !fl()
/4):/-17()
Descdptic,·.ofMeosuring~· Ca T I ~,rr IL k' c [ZJ Cosing~ Point (,\1P) 0 (, sing Y;Je · \' •.j '-' oc ing op Diameter "--_
1r.Cr,sf-i
Total Dep:· of Well 2~1~~1 / / J, 91,.J
Depth to 1•1::·er Below M?ll 9 ? / 3 ,.J
Co\umn o: ':::::ter in \Ven?\ r7 7' J t> \ . /,';) , /<:1 , • .,
Goilons of \'.'::
1
r5::i~~~1o
1
;\ {J) ( I '] I . ' IP· aci/loor ~====::'::~ Gallons of 1,'.'oter in \'/'el!?
Gallons of ':.'oter to be
Purged {3X} l
J Z. 3-{" ga,I
Common Go!!ons oer Foof Conversions
! 1/i in Wei! Cosing= 0.064 gal/ foot
I 1/z in Well Cosing= 0.092 gal/ foot
2 in Well Cosing= 0.163 gal/ foot
3 in Well Cosing: 0.367 gal/ foot
3 1/i in Well Casing= 0.500 gal/ foot
4 in Well Cosing= 0.653 gal/ foot
6 in Well Casing= 1.469 gal/ foo\
Pur9e ,'.'=!hod? To~ol Gallons Purged(
;::=::::;;;;:~== :fo gall PL'r2e Start Time ~-------~ r Purge Stop Time\ I 0' '½f 3 '---'---J----
/)5? I
Sc.--:1ples Collected
Parameter Conditions: pH
Turbidity
4 5
g,:;I er
•c
m /L rrc/L
mV m'I
Container Description PreseNotive
tfr:1
r/c.
+/-0.1 siandord unit
+/-I 0% above JO NIU
COND/Temp+/3% DO
+/-I NTU below JO NIU O,P
/~:Sc>
J 7,'(f
/.f /
7, 9;{
l/,~0
;lftkJ
"7, (
+/-IO';o .
+/-JOmV
Revise 5/20/02
Purged Well Sampling Log
Kubal-Furr & Associates
-Environmental Cons1iltant:>-
Projec I No. 2 0 Q'l '2 'Z-,
Site Location CNA Holdin s/Ticona, Shelb , NC
Field Personnel J,
We/1/SomplelD VV\rv -i-2-,
\
Weaipy;_,~_ondition yf'GL"'T.(1 O)fp'{ '3:t\: Sample Dole (, I I o\.j Arri•,al Time ___ /.:.&~_:L--'~(.J'-----Sam;:•e Time If~
Descripli.cn of Measuring~, C _ 1 0 1 qJr I k' C G2J Cosing[±J2
. ' Point IM?J . Q1 CJ,ng YP-, v Loe ,ng op l, . ..--D. I ~ '-' 1 1ame er ,r.cr,-a-i
TololDepthofWellBe
0
io __ wl l'-J\. \O I ... Common Gallons p;_;,· Foot Conversions i ,1. ? le~t
Depth lo Waler Below MP?I~ ='t~b=•:::\:::1:::::::=='•~J
Column of Waler in \.'/ell?I /(\ \_ C ~~ j ~-:::::::1)':j::::\:,:::=· l'='~==='••·
Gallons ol \.'lal __ e-r per Foot! I (see chart}? 0 , l r '?, ~=:::::::::b::::"'=:=:'::'':::'/=foo=;r
Go/Ions of Y.loter in vveu?
Gallons of Water to be
Purged (3XJ?
Purge Method?
\ '.3, 5>1-l garl
I 1/~ in \.I/ell Cmir,g = 0.064 gal/ foot
1 1/2 in Well Cosing= 0.092 gal/ foot
2 in Well cm:ng = J.163 gal/ foot
3 in Well Cming = ·J.367 gal/ foot
3 1/i in Well Cosing= 0.500 go! I foot
4 in Well Cosing= 0.653 gal/ foot
6 in Well Cosing= i .469 gal/ foot
Total Gc!!ons Purged\ :}6_ ~ j
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I ;:· ===:::~===~g=ol
,-;, , Purge Slop Time I /7,::,-] <.',<IZ'l ~-~~~--.,....---~ 2 3 5 (?.>S.~~h4 ,.,:1::w,'-l.
Tempera lure _ .• c •c J-.:...':'.=-'=-+-~____::µ_::.:_:,_:_4 __ ____:::j,qH,,<C\-_::l,L.. __ .::J ----.) µS
Specific Conductance
µS
DO 5-70mc!'.
Turbi~idy f-J.~_';Z_-""'+-~~~=r<---"rl-,'-----''~""'+-----''~·ru'+-----'"='"
mV
Samples Co!!ecfed Container Description
Rem.:irks
/ I I
Parameter Conditions: pH + /· 0.1 standard uriit
Turbidity · +/-10% above 10 NTU
.cor:-iqJ:remp 7"/-.3%
+/-1 NTU below JO NTU
mV mV
Preservative
/f:c(
DO
ORP
l B.ifs
/ tl--:;~
[11
7-.G'8
l-1"2
(60
( ·~ . • , I
+/-10%
+/-JOm1/
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.· Revise 5/28/02 . I
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Kubal-Furr & Associates
Purged Well Sampling log
Project No,
-Em.:iro11mental Consultant;;-Sile location CNA Holdi~n :icpna, Shelby, NC
Field Personnel {,-k /~/t'lv
Well/ Sample ID L -;Jt),j" [pl. J WeatherConditioh ~,__ . ..,,L/ ,lbr
Sample Dale '(,;}./ O t/ Arrival Time OJ); Sample Time_
1
....,/ 0,,,'3:..L.S,s:.. ___ _
Descripi:on al Measuring~ , ~•• r , I ----1 Cosing[ZJ· Pein I (M?J ,:>L---Cosing Type 7 V C,_ Locking Cop ✓ Oiomeler .
Toicl Dep::1 al Weil Selowl
t.1,?? J9t,1(,.J
Depth lo Waler Below M0?1 .'Jf 7; to le..! ::========~ Column or Wo~e,· in Well?! D-~ ,,--I
;::c:· ====(J= ,, ,__)= ,--)=====;'•·'
Gol!onl of ','l::te; per Foot I ~ /, 3 I (see chart)? l,">,, (:; '.:=====::cgc=:1/b~ol
Gallons of Water in 1Nell?
Gallons of \.'later lo be
Purged (3X)1
Pt..:rge /'<,le~hod?
Time
/, 3CJ goll
gal
Common Gallons oer Foot Conversions
I 1/~ in We!! Casing= 0.064 gal/ foot
1 1/i '1n We\l Casing= 0.092 gal/ foot
2 in ...,., ell cm:ng = 0.163 gal/ foot
3 in \Veil Cosing = 0.367 gal/ foot
3 1/i in Well Casing= 0.500 gal/ foot
4 in We!I Casing= 0.653 gal/ fool
6 in Well Cosing= 1.469 go!/ foot
Total Gallons Purged[ -p 901!
Purge Stop Time\ , @k
2 3 4 5
Temperature o c ~ c cc ,---JL-+-~--.::J-----=1-~~-l.-----''+-..L----=+-----=-i
Specific Conductance ,s µS
pH
,f--+'="hf----'-==!---"-'=:+~-----'==i-----"="-'1----''c,'dc,O;;:nit~,
DO
rnc/L '(_ 7 7m /l
~;;,J Joo MTU
ORP
r:".'/ 3h m'I mV mv mV Samples Collecled Container Description Preservative
1r,cr,ei
~~"'fk
:z~),
jef5r;-
2-0, 2-,\,f·
c;J.-6
·7. lb
5.-23
r;i;o
3+.~
Remorks-~f;Z'J-1/ ?i,1,<-t?,-.-v'& ,1vf) \!1·\-Q"-,),,}/Lbi "f:>JC'lt/#fi! rfr.c1 LJ1if1-v'G•-k-A;,t c~:-ie~)IC, ..r!,.1{1/)(,;,:-(uJ✓'l)(j C/lc.lKl/.ttt.1.1~-.;.v f..,.,. k, )~ b,<. €,-n " 1 i3)-J ,. (Ull[V 1)ilA..Jc~ Iv -.' , e, c;i(_ Parameter Conditions: pH +/· 0.1 standard uni: · COND[Temp +/-3% DO +/-10%.
Turbidity +/· 10% above 10 NTU +/-I NTU below 10 NTU ORP +/-lOmV
Revise S/2:/02
Kubal-Furr & Associates
-E11vironmental Consultants-
Purged Weil Sampling Log
Project No.
Site location
Well I Sample ID
,NC
('i~1· WeotherCondition .S:.:,,1v~ ~J 02 ~c17 , Sample Date ~ Arrival Time ___ ~(]C-L.1:_~-~--~:-:::e Time_'-'j l'-·'a:i=-----
De,criplion of Meosurina~/ . 1 n / /-I . EJ Casing[L] • Point IMP~) ,,, <.....-Co. sing Type 1 /l1tJ L-Loct.::1ng Cop . ~
Diameter ir.c.~ei
Total Depl:o o: Well Be!owl I 1u· 3 I ~.\P? . l' {) / f,a9:
Depth lo Waler Below MP?I c·¥ J'/,{:2
10
.,I
Column o: Waler in Well?I )",\ ,). / J' , .• ,I '.:::===::====== Ga!!ons of Water per Foot!· 0 // ~ I I see chart)? ·, f 0,,)
~==~g=oll':::';oot
Gallons of 'Noter in well?
Gallons of Water to be
Pu,ged 13XJ?
Purge ,\\et66d?
Volume Purged
I S~SI 0,,\
Cornman Go/1:-~.s =:::y Foot Conversions
J 1/,. in we·11 C:~::-.;; = 0.064 gal/ foot
1 1h in \.'/e:I C:;:.--.;i = 0.092 gal/ foot
2 "it-1 \Veil C::·.~; = 0.163 gal/ foot
3 1h in \'le!! C:,·.-.;: = 0.5CO go!/ foot
4 in Well Cc:!'.c.; = 0.653 gal/ fool
6 in Well Cc:".-.;:= 1.469 got/ foot
oc
,s
s'.dunits std unit>
m /l m /l
MTU NTU NTU
mV mV m'I Samples Collected Container Description Pre3ervotive
lfc/
~meter Conditions: pH +/._0.1 stanp6rd unit· CONDfferrip +/• ~;; DO
Turbidity +/. I NTU belo-.-: 10 tiiU
I 1 Z-e>
1-.'2.J{')
-1-2-6
1 .CSLf
1-9
I ·71 (i'.50
1 '-{,i
+/-10%
+/· IOmV
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Kubal-Furr & Associates
Purged Well Sampling Log
Project No.
-Enviromnental Cons11ltant3-Sile Location CNA,Holdings(Tico~c, Shelby, NC
Field Personnel __JU.....:rf::,...._ . .,_/_,w~r-~/,_/c-,__'vJ..=.. __ ~ Well/ Sample ID 7:2. ✓//o (, /✓ WealherCondition _Q,,t.,,? ,f'o./
Sample Dole J-,U Arri•,ol Time cJ J)] Socnple Time //3--J
DescriptionotMeosuringr:::::;l C . T IQJ✓-1l k" C ~ Point {,\\P)~ OS1ng ype ( V '--oc ing op~ Cosingl07 Diamete.t__~:::S.~d
To:01 Depth a: Well Below!
1\IP? / / l,;f ,.J
3/✓]0 ,.J
Common Gallons oer Foot Conversions
Depth to Waler Below MP?I
Column of Water in We!l'?I 7 C), ("' 3 I ;::· ====/=<r==='··=-'
Gal!om of 'v'/cter per Footl C // 3 I (seecharf)? ··,. t./" :========ocr:::C:::/loor
Gallons of Water in 1dell? \ [ :) , 0 / \ ;::· =====::::::::::':g::'cr
Gallons of Weter to be
Purged {3X)? s ?.o 3 gJ
l{,;2L,~0foJ I
Purge Start Time\ /;;i.__r-J.-\
Initial 1
Volume Purged
Time /c1-l J. Io~&-// I-' .1
Temperature (J,S:. 'c /7_ft. 'c ;J, · 'c
Specific Conductance :)Jl ,s :):J.J s '.)l{1 ,s
pH 7, 3 9" ,.-,;,; '7,cJ,d cc,irs & •J'.;:~uoia;
DO l( Ii,\ /l OU () 't, .. L/lJr.-,c/L ;.., m ;L • m r~
Turbitidy r' ,.,...-c) T . ~( M
ORP /1' 9'
i 1/4 in Well Casing= 0.064 gal/ foot
11/2 in Well Cosing= 0.092 gal/ foot
2 in Wei! Casing= 0.163 GCI / foot
3 in Well Cosing= 0.367 gal/ foot
3 1/i in Well Cming = 0.500 gal/ foot
4 in Well Casing= 0.653 gal/ foot
6 in Well Cosing= l .469 gal/ foot
or ccr
'C
sld unir;
m /l
MiU
mV m'I mV Samples C_oltected Container Description Pre)ervotive
Parameter Conditions·. pH
Turb"idity
/J<;'L / l.,(VJt/
+/-0.1 standcird unit
+/· JO% obov~ 16 Niu
CON~/Temp +/-.3%
+/-t NTU below 10 NTU
DO
OR?
JI 3~
{<J. 7,')
;z.,11
1. 3 I
3.%
71((;0
[G. 9
+/. 10%
+/-IOrnV
Revise 5/28/02
Kubal-Furr & Associates
-E11viron/lle11tal Co11s11ltmtls-
Purged Well Sampling Log
Project No.
,NC Site Location
Field Personnel ---=--1--,,:-1;-1----4.-_____ _
Well I Sample ID
{; J.'.; / I Weather Condition _ .. _£_'-'...:.,.,,_"'~71-J'l:>:~2r:__~-~--
Somple Dote f,;2fJ1 Arrival Time / ✓/6 Sample Tir:-,e \ l{"-{<
Description oi Mecsuring[g] C T I 0·, 1 / I •-· [2]1 Cosing~ Point (MP) / C)(.__ osrng. ype · · C/ (_ _ L,.,,,_,<ing Cop V
I Diameter .
1~c-,;s
iota/ Depth of YVeil aebw
MP?
Depth to Y\loter Bei:JW MP?
Gallons of Water in 1/'lell?
Gallons of Water to be
Purged (3X}?
Purge Method?
Purge Sier: Time,__( _...Llc:-'?.c.,c"-J-'·?=-__ __JI
Initial
Time
Common Gallons per Foot Conversions
i 1/~ in \Nell Cosing= 0.06..:. ;ia! / bot
1 1h in Wei! Casing= 0.092 gal/ f::iot
2 in Well Cming = 0.163 ;::I/ foot
:: in We!I Cosing= 0.367 g:il / foot
3 :/2 in Well Casing= 0.5CO gal/ foot
4 in Well Casing= 0.653 gol / foot
? in We!J Cosing= 1.469 g.:::I / foot
Total Gallons Purged!~==,)~':::' :::~::::::==='g=":ol\
Purge s,op Time~l ___ (3~· ~T~:8::~-----'
2 3 4 5
Temperature · 3 , c iz_:::.i;c:-1--=1-L=~.<.....:::+-----"H':__-....:a;:µ_.qc_,,q. __ ___::_j "C
Specific Conductance ' Cl ,..:..--,.,-'4-'",--''----'r--=--'"'-ls ---'---"'"'+--+-,LJ'fl-,,.-<+--"'+----'-'J µ5
stdur.1tJ ;:.:;1 units
rr.g/L m ,J m /l
NIU Nru NIU
mv m'I m'I Samples Collected Preservative
\~~~
\C/.l"V
2-, '-l ~
'6,'--[<Z'
Lf.-s
S7;0
'3'-\-,i
Remor%s ,. .. ~ f't..yil''-IJ(r /....,iT/A-t. 1/oW/'1~~ .,,<J) .. ?v11/I.:?) Dt • C.~1'1 r (./ol t.,. •1 -: {tZ.:.'.4 'V/l,1,,v,~t· Tu1VJ6-,4-MY< p.-cc,,r/-pv, .. p' S4>•f'< ci\ "'-/ P12ctil
Parameter Conditions: pH
Turbidity
+/-0.1 standard unit
+/-10%above 10 NTU
COND/Temp +/-3%
+/-I NTU below ID NTU
DO
O,,P
+/-10%
+/· IOmV
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Revise 5/28/02
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Kubal-Furr & Associates
Purged Well Sampling Lag
Project No.
Total Deplh ol Well Below\
t,1P?
Gallons of Water in Well?
Gallons of Water to be I /2, ~ 3 '3 I Purged (3Xj; { ' , 901
Common Gallons oer Foot Conversions
1 1/~ in Well Casing= 0.06..: gal/ foot
1 1/2 in Well Cosing= 0.092 go!/ foot
2 in Well Cosing= 0.163 gal/ foot
3 in Well Cosing= 0.367 gal/ foot
3 1/i in \Veil Casing= 0.500 gal/ root
4 in Well Cosing= 0.653 gel/ fool
6 in Well Cosing= 1.469 gal/ foot
Purge Method? I liivv~~s \ Total Gallons Purged\ · r7) \ ;::· =='--"'== C/===::"g~o! Purge Start Time L..[ _ _,(_,3"--1'--'3:::_ ___ \ Purge Slop Time\ L -~/~'3~¾~0~ __ __,
Initial 3 4 5 3
'C
Specific Conducfance
,s ,s
std uni:s s:dunits
m /l mg/L
MiU NIU NTU
mv mv mV
Samples Collected Container Descri_Dtion Preservative
Porameler Conditions:
Turbidity +/. 10% above 10 NTU
218
COND/Temp +/-3%
+/-I NTU below JO NTU
DO
O.,P
+/-10%
+/-I0mV
Revise 5/28/02
Kubal-Furr & Associates
-Enviromnental Consultants-
Purged We ' Sampling Log
Project No.
lite location
Fie'd Personnel
helb .NC
-~~--"---'-+-''---~---
/2 We::/ Sample ID ~ > /,/ Weot.-.~.-Condition
Somple Dole t" 'l-Pr Arrival Time //); 0 Sample Time
De;cript'on of Meosuringf ~ I C . 1 ~ . ~ Point (MP) / ,,(__ osing ype~ Lock:ng Cop~
Total Depth of 'Nell 8e11,oIP,~I //ii~,· 3. _r'I .••• ,I ~. /l/ifl ~ . :::-:Jmmon Gallons oer Foot Conversions
Depth lo Woler Below MP?\ ~ l ,3 7 , . .,I
Column of \-Vo~er in Well?! ?9 .. 9~ re~~!
Gallons of \-1/o\er per Foot\ a• //J I (see chart)? 7i1 if ;:::===='.":'cc===:'l/oo:
Gallons of Wolec in Well? I / .3 ; 6'3 I
;=· =======~9cl
Gallons of Wot er to be
Purged (JX)? :s9cr9 gall
1 1/~ in Well Casing= 0.064 got/ foot
l 1/i in Well Cosing= 0.092 gal/ foot
2 in Well Casing= 0.163 gal/ foot
3 in Well Cosing= 0.367 gal/ foot
3 1/i in Well Cosing= 0.500 gal/ foot
4 in Well Cosing= 0.653 gal/ fool
6 in Well Cosing= 1.469 gal/ fool
Purge Method'? To,~, ::o,lons Purged I .;27
001j , ~-===;;;==::;==:"'=; @9: lk ,-:;: ,-/ c:ge Slop Time! 71//'7 I .'1-;-~ '-"!:/6,-> 1 -f-'\ lf\~ 2 3 4
Volume Purged f--:-C,"1--,,-'"'a'+--'-!--"'"'!-=-:;::._,_=~'\-l __ _:oeco"ti ----"'"1------'?',
Time / t?J
Temperature /7.&0,c f,o<.c 'c /f,9·
SpecificConduclonce JJ?J ,s J9(c ,s.s'°IS"'J
pH~~=-,._9-,,:.'.:.../f--"''"-'do~nH!J..' .:_:9':.'..~--"""-'"'".::.'"•·+J----'-"'"""f-,L---\--':=!\.-----.!.'~
f,,:5'{)m/l 0.7C'rcc.l DO m /L
Samples Collected
Parameter Conditions: · pH
Turbidiiy
mV
IK
+/·0.l stondcird.unit · CO!:JD/Temp +/._3% ·
+/-10%ob;v~ IONTU +/-1 NTU below IONTU
m'/ m'I
Pre5ervotive
DO
ORP
+/. 10%.
+/· JOmV
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Attachment 4
I Selected Water-Quality Plots
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Kubal-Furr & Associates
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-------------------
3000 ------------------
2500 ~ E ~
C .g 2000
~ ... C ~ C 0
u 1500
ITCI TOC Data
1 000 ---------------------------------------------------------------------
500 ---------------------------------------------------------------------------------------------------------
0+---------+---------+---------+--------,----------+--~
1 /1 /93 3/12/95 5/20/97 7/29/99 10/6/01 1 2/1 5/03
Date
-------------------
~ Cl E ~
C
(Unfilled data points represent qualified data
or values below the detection level.)
ITCI Ethylene Glycol Data
3500 - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - -- - - - -- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - -
3000 - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - -- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - -
2500 - - - - - --- - ---- - - ----- - ------------------------------------------------------
,3 2000 ~ C .,
u C
8 1500
1000 - - - - -
500
0+-----+------+----+-----+------+----+------+-----f-------+-----<
10/5/94 10/5/95 10/4/96 10/4/97 10/4/98 10/4/99 10/3/00 10/3/01 10/3/02 10/3/03 10/2/04
Date
-------------------V-23 TOC Data
14000 ,----------------------------------------------,
12000
10000
~C) E 8000
~
§ ·.:;
!! -C g 6000
0 u
4000
(Unfilled data points represent qualified data
or values below the detection level.)
2000 - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - -
0+------+--------+----......,~~---+------+--------+--------,-----+--~
1/1/85 6/20/87 12/6/89 5/24/92 11/10/94
Date
4/28/97 10/15/99 4/2/02 9/18/04
-------------------
C 0 . .,
~
V-23 Acetone Data
1.4~--------------------------------------------
1.2
(Unfilled data points represent qualified data
or values below the detection level.)
--------------------------------➔------------------------------------------------------------------
... C ., g 0.6
8
0.4 - - - --- - - - -
0.2 - - - - - - - - - - --- --
0 .j.._ __ __O___--+----~li__--I+-----+-~(__----'----111........i-----+-----tb,,,=1--.-_j
6/1/89 6/1/91 5/31/93 5/31/95 5/30/97
Date
5/30/99 5/29/01 5/29/03
-------------------V-23 2-Butanone (MEK) Data
(Unfilled data points represent qualified data
or values below the detection level.)
3.5 - - - - - - - - - - - - - - - - - - - - - - - - - --- - - - - - - - - - - - - - - - - - - - - - - - - ----- - --- - - - - - - --- - - - ------- ---- - --- - - - - --- - - - ----
3
C 0 -~ 2 ... C ~ C 0 u 1.5
0.5
0 +--'"--0--+-""=:..._--=-+-'"'0----l:l-+-----+-CJ'..-----+------f-------Hl---0--__J
6/1/89 6/1/91 5/31/93 5/31 /95 5/30/97
Date
5/30/99 5/29/01 5/29/03
-------------------
2 Cl
E ~
C:
V-23 Benzene Data
0.3 ~------------------------------------------
(Unfilled data points represent qualified data
or values below the detection level.)
0.25 - - - - - - - - · - - - - - - --- - - - - - ---
0.2 - - --- - - - - - - - - --- - - - - - - - - - - -
.g 0.15
I! ... C: Cl) u
C:
8
0. 1 - - - - - - - - - - - - - --- - - - - - - - - - - - - - - - --- - - - - - - - - - - --- - - - - - - - - - - - - - - - - - --- - - - - - - - - - - - - - - - - - - - - - --- - - - -
0.05
0+------+-----+=-----+-----1-------+-------'e----4:l----+---__J
6/1 /89 6/1/91 5/31/93 5/31 /95 5/30/97
Sample Date
5/30/99 5/29/01 5/29/03
-------------------
~
(Unfilled data points represent qualified data
or values below the detection level.)
8000 --- ---
7000 ------------------------ - --
K-28 TOC Data
6000 ------- -----------------------------------------------------------------------------------
S 5000
5 . .,
E ... ~ 4000
8
3000 ----- -- - --- -- --------------- ------- --------------------------------------------------------------
2000 --------
1 000 ---- ------------------------------------------
0 -l-a--_.._--+-----+-----+----_:__+--____::tJ-a ..... ~-~la-l.-.~~---+-llri--__J
8/14/81 8/18/84 8/23/87 8/27/90 8/31/93
Date
9/4/96 9/9/99 9/13/02
-------------------
(Unfilled data points represent qualified data
or values below the detection level.)
K-28 Benzene Data
0.03 - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - --- ----- - - - - - - - - - - - - - - - - - - - - -
0.025 -- -- --- ---- --
:;--;:,, E 0.02
~
C a -~
t: .,
g 0.015
8
0.01 ------------------------------------------
0.005 -- ---- -------- --- --- ------ --- --- -- - --- - --- ---- --- --
0-1-------1-------+-------+-------+-------+-------+--------+----~
6/1/89 6/1/91 5/31 /93 5/31/95 5/30/97
Date
5/30/99 5/29/01 5/29/03
-------------------HH-48 TCE Data
0.25 ,----------------------------------------------~
(Unfilled data points represent qualified data
or values below the detection level.)
0.2 --- - - - - ------- - --- - - - -
~ 0.15
C)
E ~
C 0 -~
t: ~ C 8 0.1
0.05 - - - - - - - - -------------------------------· -----
------------------------
0+-------+-------+---------+-------+---------+------f-------+----~
6/30/89 6/30/91 6/29/93 6/29/95 6/28/97
Date
6/28/99 6/27/01 6/27/03
-------------------HH-77 TCE Data
0.5 ~--------------------------------------------,
0.45
0.4
0.35
~ 0.3
E ~
C .g 0.25
e? t: ., u 8 0.2
0.15
0.1
(Unfilled data points represent qualified data
or values below the detection level.)
--------------------------------------------------------------------------------------------
0.05 - - - - - - - - - - - - - - - - - - - - - - - ------ - ---- - -----------------------------------· ---· · -· · -------------------
o~-----+------+-----1------------+------+------+-----+---__J
6/1/89 6/1 /91 5/31/93 5/31/95 5/30/97
Date
5/30/99 5/29/01 5/29/03
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Attachment (Back Cover)
I CD with pdf of Semiannual Report
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Kubal-Furr & Associates
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