Buck Steam Station

Duke
Energy,,
October 19, 2011
Mr. Bradley Bennett
Division of Water Quality
Stormwater Permitting Unit
North Carolina Department of Environment
and Natural Resources
1617 Mail Service Center
Raleigh, NC 27699 -1617
!�C DOU �jS Lo
DUKE ENERGY CORPORAI•ION
526 South Church St.
Charlotte, NC 28202
Subject: NPDES Stormwater Permit Application
Buck Steam Station
Dear Mr. Bennett:
Mailing Address:
PO Box 1006
Charlotte, NC 28201 -1006
ocr �
2 4 2011
�,r 5
Duke Energy requests a stormwater discharge permit for the Buck Steam Station located in
Rowan County, North Carolina. Enclosed is a check from Duke Energy in the amount of
$860.00 for the subject stormwater permitting fee; and three sets of the following documents
related to this permit request:
a. EPA Form 1;
b. EPA Form 2F;
C. EPA Form 2F Supplemental Information;
d. Available stormwater analytical data;
e. DWQ ROS Request Form;
f. ROS Form Supplemental Information,
g. Site Location Map;
h. Site Stormwater Plan Drawing
The Buck Steam Station was originally placed into service in 1926, and is now scheduled for
retirement by December 2014. The accompanying stormwater analytical data was obtained
from samples collected at outfalls SWO02 and SWO03 during the period March through April of
2008. No additional sampling was performed in association with this permit application.
Numerous historical stormwater outfalls are located at the station. Duke Energy requests that
any permit monitoring requirements, including qualitative monitoring, be limited to the proposed
representative outfalls.
Please contact me at Mark.McGary @duke- energy.com or at 704- 634 -7098 if you have any
questions or need any additional information.
Sincerely,
Mark McGary, P.E.
Environmental, Health & Safety
www.duke-energy.com

.attachments
Cc w /att- Nob Zalme
Cc w/o att' Mr Robert Krebbs,
Dayna Herrick
John Velte
Stephen Townsend
File Number 8 -6
Record` Number 248464
NCDENR MRO
Certified Mail 7009 14110 0000 0602'8480

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Check Date: 11 Oct 2011
Vendor Number: 0000071960
Name: NCDENR - NORTH CAROLINA DEPARTMENT OF
Check Number:
1000068873
Invoice Number
Invoice Date
Voucher ID Gross Amount
Discounts'Taken
Late Charge
PaidAmount
10051186000NC 05 Oct 2011
SW PERMIT APPLICATON FOR BUCK
J
10473994 86000
000
i
000
86000
Check Number:
Date
Total,
Gross Amount
Total
Discounts
Total
Late.Charges
Total
Paid Amount
1000068873
11 Oct 2011
$86000
$000
$000
$86000
Duke�Ene�gy'BusioessServices, _ :, � � ,4000068873
400 South Tryon Street ''JPMORGAN CHASE B'ANK,'N.A.
Energy® Charlotte NC 28285 -_ > _ 50. - 937/213
Syracuse, NY
rpoTate Accounts Payable - _ - � ry _ � � � � - , � -~ - _ --
iI Code ST25B 'C- b C� us 5 U"
I South Tryon Street
iarktte; NC 28285 Date -.10 /11/11'
Pay Bight hundred saty and xx / 100 Dollar's $ 860:00
TiThe --
Order Of NCDENR - NORTH CAROLINA DEPARTMENT OF
ENVIRONMENT AND NATURALRESOURCES ;
STORMWATER PERMITTING UNIT
1,617 MAIL SERVICE CENTER_
Raleiah. NC 27699 - 16,17 = -
= y, - Autfib i id,Signiture
!►' - ''

r\lP C nr-� r- ,Sc,in
FORM
U.S. ENVIRONMENTAL PROTECTION AGENCY
1. EPA I.D. NUMBER
F
TA
r
GENERAL INFORMATION
,R
D NC0004774
� FEPA
Consolidated Permits Program
GENERAL
(Read the "General Instructions" before starting.)
1
2 13 14 15
GENERAL INSTRUCTIONS
LABEL ITEMS
If a preprinted label has been provided. affix it in the
designated space. Review the information carefully,
I. EPA I.D. NUMBER
f any of it is incorrect, cross through it and enter the
correct data in the appropriate fill -in area below.
11. FACILITY NAME
Also. if any of the preprinted data is absent (the
area to the left of the label space lists the
PLEASE
PLACE LABEL IN THIS SPACE information that should aelow.Ifte labelivideitm
If label is
III. FACILITY MAILING
the proper fill -in area(s) below. the
ADDRESS
complete and correct, you need not complete Items
I: 111. V. and VI(except VI -B which must be
completed regardless). Complete all items if no
IV. FACILITY LOCATION
label has been proved. Refer to the instructions for
detailed item descriptions and for the legal
authorization under which this data is collected.
II. POLLUTANT CHARACTERISTICS
INSTRUCTIONS: Complete A through J to determine whether you need to submit any permit application forms to the EPA. If you answer "yes" to any questions, you must submit
listed in following the Mark "X" in the box in the third column if the supplemental form is attached. If you answer "no" to
this form and the supplemental from the parenthesis question
each question, you need not submit any of these forms. You may answer "no" if your activity is excluded from permit requirements; see Section C of the instructions. See also. Section D
of the instructions for definitions of bold -faced terms.
SPECIFIC QUESTIONS
MARK "X" MARK
FORM SPECIFIC QUESTIONS FORM
YES NO
YES NO ATTACHED ATTACHED
A. Is this facility a publicly owned treatment
works which results in a discharge to waters of
❑
®
❑
B. Does or will this facility (either existing or
proposed) include a concentrated animal
❑
M
❑
the U.S.? (FORM 2A)
feeding operation or aquatic animal
production facility which results in a discharge
16
17
18
to waters of the U.S.? (FORM 2B)
19
20
21
C. Is this facility which currently results in
discharges to waters of the U.S. other than
®
E]
D. Is this proposal facility (other than those
described in A or 8 above) which will result in a
El
1:1
22
23
24
25
26
27
those described in A or B above? (FORM 2C)
discharge to waters of the U.S.? (FORM 2D)
E. Does or will this facility treat, store. or dispose of
F. Do you or will you inject at this facility industrial or
effluent below the lowermost stratum
❑
®
❑
hazardous wastes? (FORM 3)
❑
®
municipal
containing, within one quarter mile of the well bore.
underground sources of drinking water? (FORM 4)
29
30
31
32
33
G. Do you or will you inject at this facility any produced
water other fluids which are brought to the surface
H. Do you or will you inject at this facility fluids for
special processes such as mining of suffer by the
in
❑
®
❑
in connection with conventional oil or natural gas
production, inject fluids used for enhanced recovery
L28
®
❑
Frasch process, solution mining of minerals.
situ combustion of fossil fuel, or recovery of
of oil or natural gas. or inject fluids for storage of
geothermal energy? (FORM 4)
35
36
37
38
39
liquid hydrocarbons? (FORM 4)
I. Is this facility a proposed stationary source
which is one of the 28 industrial categories listed
❑
M
El
J. Is this facility a proposed stationary source
which is NOT one of the 28 industrial categories
1:1
®
❑
in the instructions and which will potentially emit
100 tons per year of any air pollutant regulated
in the instructions and which will potentially
emit 250 tons per year of any air pollutant
under the Clean Air Act and may affect or be
located in an attainment area? FORM 5
regulated under the Clean Air Act and may affect
or be located in an attainment are? FORM 5
40
41
42
43
44
45
III. NAME OF FACILITY
C SKIP Buck Steam Station
1
15
1 16 -29
30
69
IV. FACILITY CONTACT
A. NAME & TITLE last. first. & title)
B. PHONE (area code & no.)
c McGary, Mark / Sr. Engineer
980
15 16
"3737898
45 46 48 55
V. FACILITY MAILING ADDRESS
A. STREET OR P.O. BOX
C P.O. Box 1006, Mail Code EC13K
3
15 1 16
45
B. CITY OR TOWN
C. STATE D. ZIP CODE
C Charlotte
NC 28201
4
15 1 16
40 1 41 42 1 47 51
VI. FACILITY LOCATION
A. STREET. ROUTE NO. OR OTHER SPECIFIC IDENTIFIER
1555 Dukeville Rd.
5
1s 1 16
45
B. COUNTY NAME
Rowan
46
70
C. CITY OR TOWN
D. STATE
E. ZIP
F. COUNTY CODE
CODE
C
Salisbury
NC
28146
6
15
16
40
41 42
47 51
52 54

vv.
VII. SIC CODES (4- digit, in order of priority)
A. FIRST B. SECOND
c
4911
(specify)
Electric Services
'
( specify)
15
is n
15 16 is
C. THIRD D. FOURTH
c (specify) 7 (specify)
7 7
1s 16 17 15 1 16 19
VIII. OPERATOR INFORMATION
A. NAME B. Is the name listed in Item
c
Duke Energy Carolinas, LLC (Attention: Mark McGary)
VIII -A also the owner?
EYES []NO
8
to
is 55
C. STATUS OF OPERATOR (Enter the appropriate letter into the answer box. if "Other. "specify.)
D. PHONE (area code & no.)
F = FEDERAL M = PUBLIC (other than federal or state)
P
(specify)
c
373
7898
S =STATE O =OTHER (specify)
Electric Utility
�80
1s 21
zz 25
P = PRIVATE
56
E. STREET OR PO BOX
P.O. Box 1006, Mail Code EC13K
26 55
F. CITY OR TOWN
G. STATE H. ZIP CODE IX. INDIAN LAND
c
Charlotte
NC 28201 Is the facility located on Indian lands?
❑ YES ® NO
1 42 42 47 51
B
15 16 40
X. EXISTING ENVIRONMENTAL PERMITS
A. NPDES (Discharges to Surface Water)
D. PSD (Air Emissions from Proposed Sources)
c T a
9 P
15 16 1 17 1 18 30
C
T
'
NC0004774
9
N
15
16
17
18 30
B. UIC (Underground Injection of Fluids
E. OTHER (specify)
(Specify)
Air permit
C
T
6
03786 T27
9
U
9
15 1
16
1 17
1 18 30
15
16
17
18 30
C. RCRA Hazardous Wastes E. OTHER (specify) (Specify)
a W00000452 Distr. of residual solids
' NCD043678929
s
17 18 30 15 16 17 18 30 permit / Ind. landfill permit
P1.
AP
Attach to this application a topographic map of the area extending to at least one mile beyond property boundaries. The map must
show the outline of the facility, the location of each of its existing and proposed intake and discharge structures, each of its
hazardous waste treatment, storage, or disposal facilities, and each well where it injects fluids underground. Include all springs,
rivers and other surface water bodies in the map area. See instructions for precise requirements.
XII. NATURE OF BUSINESS (provide a brief description)
Coal -fired electric generation
XIiI. CERTIFICATION (see instructions)
I certify under penalty of law that I have personally examined and am familiar with the information submitted in this application and
all attachments and that. based on my inquiry of those persons immediately responsible for obtaining the information contained in
the application, i believe that the information is true. accurate and complete. I am aware that there are significant penalties for
submitting false information, including the possibM4 of fine and imprisonment.
A. NAME & OFFICIAL TITLE (type or print) B. SIGN R&
C. DATE SIGNED
Stephen A. Townsend - General Manager II
COMMENTS FOR OFFICIAL USE ONLY
EC]
15
16 55

EPA ID Number (copy fromaltem 1 of Form 1) Form Approved OMB No 2040 -0086
01—cia nrvd nr }Vno In }hP IlnShadwi arpnS,nnlV NC0004774 I Approval expires 5 -31 -92
FORM
2F
NPDES
,U S .Environmental Protection Agency
Washington, DC 20460
Application for Permit to Discharge Storm Water
EPA Discharges Associated with Industrial Activity
Paperwork Reduction Act Notice
Public reporting burden for this application is estimated to average 28 6 hours per application, including time for reviewing instructions, searching existing data sources,
gathering, andfmaintaining,the data needed, and, completing and reviewing the collection of information Send comments regarding the burden estimate, any other aspect
of'this collection of information, or suggestions'for improving this form, including suggestions which ,may increase or reduce this burden to Chief, Information Policy
Branch, PM -223, U S Environmental Protection Agency, 1200 Pennsylvania Avenue, NW, Washington, DC 20460, or Director, Office of Information and Regulatory
Affairs, Office of Management and Budget „Washington, DC,20503
I. Outfall Location
For each outfall, list the latitude and longitude of'its location to the nearest 15 seconds and'the,name of the,receiving water
A Outfall Number
(list)
B Latitude
C Longitude
D Receiving Water
(name)
See attached
See attached supplemental information
11. Improvements
A Are you now required by any Federal, State, or local authonty'to meet any implementation schedule for the construction, upgrading,or operation of wastewater
treatment equipment or practices or any other environmental programs which may affect the discharges described in this application? This includes, but is not limited
to,.permd conditions, administrative or enforcement orders, ,enforcement compliance schedule'letters, stipulations, court orders, and grantor loan conditions
1 Identification of Conditions,
Agreements; Etc
2 Affected Outfalls
3 Brief Descnption, of' Project
4 Final
Compliance Date
number
source of discharge
a req
b prof
N/A
B You may attach additional sheets describing any additional water pollution (or other environmental projects which may affect your discharges) you now' have,under
way or which you plan Indicate whether each program is now under wajor planned, and indicate your actual or planned schedules for construction
III 'Site Drainage Map
Attach a sde,map showing topography (or indicating the outline of drainage,areas served by the outfalls(s) covered imthe application if a topographic map is unavailable)
depicting the facility including each of its intake and discharge structures, `the,drainage,area of each storm wateroutfall, paved, areas 'and Ibuildings withimthe drainage
area of each storm water outfall, each known past or present areas used for outdoor storage of,disposal of significant materials, each existing structural control measure
to reduce pollutants,in storm water runoff, materials loading and access areas, areas where pesticides, herbicides, soil conditioners and fertilizers are applied, each of
its hazardous waste treatment, storage or disposal units (including each area,not regwred'to have a RCRA',permrt which is used for accumulating hazardous waste
under 40 CFR -262 34), each well where fluids from the facdity'are injected underground, springs, and other surface water bodies which received storm water discharges
from, the facility
EPA Form 3510 -2F (1 -92) Page 1 of 3 Continue on Page 2

"-ins A from fhc Frnnf
IV. Narrative Description of Pollutant Sources
A. For each outfall, provide an estimate of the area (include units) of imperious surfaces (including paved areas and building roofs) drained to the outfah, and an estimate of the total surface area
drained by the outfall.
Outfall
Area of Impervious Surface
Total Area Drained
Outfall
Area of Impervious Surface
Total Area Drained
Number
(provide units)
(provide units)
Number
(provide units)
(provide units)
See attached supplemental
information.
B. Provide a narrative description of significant materials that are currently or in the past three years have been treated, stored or disposed in a manner to allow exposure
to storm water; method of treatment, storage, or disposal, past and present materials management practices employed to minimize contact by these materials with
storm water runoff, materials loading and access areas, and the location, manner, and frequency in which pesticides, herbicides, soil conditioners, and fertilizers are
applied.
See attached supplemental information
C. For each outfall, provide the location and a description of existing structural and nonstructural control measures to reduce pollutants in storm water runoff, and a
description of the treatment the storm water receives, including the schedule and type of maintenance for control and treatment measures and the ultimate disposal
of any solid or fluid wastes other than by discharge.
Outfall
List Codes from
Number
Treatment
Table 2F -1
See attached supplemental information
V. Nonstormwater Discharges
A I certify under penalty of law hat the outfall(s) covered by this application have been tested or evaluated for the presence of nonstormwater discharges, and that all
nonstormwater discharged from these outfall(s) are identified in either an accompanying Form 2C or From 2E application for the outfall.
Name and Official Title (type or pant)
Signature
Date Signed
Stephen A. Townsend - GM II
� C� Iy�
'f
B. Provide a description of the method used, the date of any testing, and the onsite drainage points that were directly observed during a test.
Visual inspection was performed on November 12, 2010. Stormwater outfalls were inspected following a period of dry weather of
at least 72 hours duration to determine if any process water was discharging. With the exception of those outfalls permitted as
NPDES discharges of process water and outfall SW002, there were no non - stormwater discharge flows observed. SWO02 had minimal
flow of clear water, which is believed to be either groundwater or fire protection water infiltration.
VI. Significant Leaks or Spills
Provide existing information regarding the history of significant leaks or spills of toxic or hazardous pollutants at the facility in the last three years, including the
approximate date and location of the spill or leak, and the type and amount of material released.
Within the past three years there have been no significant spills or leaks of hazardous substances in excess of reportable
quantities set forth by Section 311 of the Clean Water Act or Section 102 of CERCLA.
EPA Form 3510 -2F (1 -92) Page 2 of 3 Continue on Page 3

EPA ID Number (copy from Item 1 of Form 1)
rnnfiniand from Pnno 7 NC0004774
EPA Form 3510 -21F (1 -92) Page 3 of 3
VII. Discharge Information
A, B, C, & D. See instructions before proceeding. Complete one set of tables for each outfall. Annotate the outfall number in the space provided
Table VII -A, VII -B, VII -C are included on separate sheets numbers VII -1 and VII -2.
E. Potential discharges not covered by analysis - is any toxic pollutant listed in table 2F -2, 2F -3, or 2F -4, a substance or a component of a substance which you
currently use or manufacture as an intermediate or final product or byproduct?
❑ Yes (list all such pollutants below) ❑✓ No (go to Section I?)
Vlll. Biological Toxicity Testing Data
Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in
relation to your discharge within the last 3 years?
❑ Yes (list all such pollutants below) ✓❑ No (go to Section IX)
IX. Contract Analysis Information
Were any of the analyses reported in Item VII performed by a contract laboratory or consulting firm?
© Yes (list the name, address, and telephone number of, and pollutants
❑ No (go to Section X)
analyzed by, each such laboratory or firm below)
A. Name
B. Address
C. Area Code & Phone No.
D. Pollutants Analyzed
Pace Analytical Services, Inc.
9800 Kincey Ave, Suite 100
704- 875 -9092
Oil and Grease
Huntersville, NC 28078
Pace Analytical Services, Inc.
2225 Riverside Drive
828 - 254 -7176
Wet chemistry and metals
Asheville, NC 28804
X. Certification
1 certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure
that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that
there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations.
A. Name & Official Title (Type Or Print)
B. Area Code and Phone No.
Stephen A. Townsend - General Manager II
(704) 645 -2735
C. Signat
D. Date Signed
I
EPA Form 3510 -21F (1 -92) Page 3 of 3

EPA ID Number (copy from Item 1 of Form 1) Form Approved OMB No 2040 -0086
C0004774 I Approval expires,5 -31 -92
VII Discharge information (Continued from page 3 of Form 2F)
Part A — You must provide the results of at least one analysis for every pollutant in this table Complete one table for each outfall See instructions for additional details
Pollutant
and
CAS Number
(ifavadable)
Maximum Values
(include units)
Average Values
(include unr(s)
Number
of
Storm
Events
Sampled
Sources of Pollutants
Grab Sample
Taken During
First 20
Minutes
Flow- Weighted
Composite
Grab Sample
Taken During
First 20
Minutes
Flow- Weighted
Composite
Oiland.Grease
N/A
2 00
Outfalls SWO02 and SWO03
Biological Oxygen
Demand (BOD5)
(see other attached Forms 2F
Chemical Oxygen
Demand (COD)
for SWO02 and SWO03 analytical
Total Suspended
Solids�(TSS)
results)
Total Nitrogen
Total Phosphorus
pH
I Minimum
Maximum
Minimum
Maximum
Part B — List each pollutant that is limited in an effluent guideline which the facility is 6ub)ectdo or any pollutant hsted,in the facility's NPDES permit for its process
wastewater (if the facility is operating under an,existing NPDES permit) Complete one table for each outfall See the instructions for additional details and
requirements
Pollutant
and
CAS Number
(ifavailable)
Maximum Values
(include units)
Average Values
(include units)
Number
of
Storm
Events,
Sampled
Sources of Pollutants
Grab Sample
Taken During
First 20
Minutes
Flow- Weighted
Composite
Grab Sample
Taken During
First 20
Minutes
Flow - Weighted
Composite
t
2 00
Outfalls SWO02 and SWO03
(see other attached Forms 2F
for SWO02 ana SWO03 analytical
results)
EPA Form 3510 -2F (1 -92) Page VII -1 Continue on Reverse

Continued from the Front
Part C - List each pollutant shown in Table 2F -2, 2F -3, and 2F-4 that you know or have reason to believe is present See theflristructions for additional details and
requirements Complete one table for each outfall
Pollutant
and
CAS Number
(if available)
Maximum Values
(include units)
Average Values
(include units)
Number
of
Storm
Events
Sampled
Sources of Pollutants
Grab Sample
Ta_ken,Dunng
First 20
Minutes
Flow= Weighted
Composite
Grab Sample
Taken During
First 20
Minutes
Flow- Weighted
Composite
2 00
Outfalls SW002 and SW003
(see other attached Forms 2F
for SW002 and SW003 analytical
results)
Part D — Provide data for the storm event(s) which resulted_ in the maximum values for the flow weighted composite sample
1
Date of
Storm
Event
2
Duration
of Storm Event
(in )nutes)
3
Total rainfall
during storm,event
(in inches)
4
Number of hours between
beginning of storm measured
and,end'ofprevious
measurable rain event
5
Maximum flow rate during
rain event
(gallonslminute or
specify units)
6
Total flow from
rain event
(gallons or specify units)
3/16/2008
4/3/2008
220
360
1 83
1 26
> 72 hours
> 72 hours
Data not available
Data not available
0 14 MG
at Outfall SW002
0 02 MG
at Outfall SW003
7 Provide a description of the method of flow measurement or estimate
Flow data derived from a theoretical runoff calculation using local meteorological data and drainage area characteristics for
Outfalls Sw002 and SW003
EPA Form 3510- 2F'(1 -92) Page VII -2

'BUCK STEAM STATION
Stormwater Discharge Permit Application
Form 2F Supplemental Information

GENERAL SITE INFORMATION
Buck Steam Station is a fossil- fueled, electric generation plant located in Rowan County
approximately three miles east of Spencer, North Carolina The station property
encompasses 643 acres that border the southern shore of the Yadkin River in the upper
reaches of High Rock Lake The station is accessed from Dukeville Road off of Long
Ferry Road
The station has two active coal -fired generation units''(Units .5 and 6) and four retired,
out -of- service coal -fired generation units (Units 1 through 4) The original two coal -fired
units (Units 1 and 2) were put into service in 1926 Units 5 and 6 are scheduled for
retirement in December- 2014 The station also has three active oil or gas -fired
combustion turbine units also scheduled for retirement prior to December 2014 The
primary' station generation area encompasses,approximately 50 acres
The facility includes the Powerhouse, a coal storage yard encompassing approximately
4 acres and located south of the Powerhouse; the'Units 3 and 4 Switchyard
encompassing 1 acre and located immediately east of the Powerhouse, and the Units 5
and 6 Switchyard encompassing 1 3 acres and located immediately southwest of the
Powerhouse The facility also contains a coal unloading and handling operation, two
warehouses, a fuel oil storage tank and associated fuel oil unloading station, paved
parking areas, rail lines, paved roadways, and gravel surfaced roadways.
The facility also includes three active ash settling basins (the new primary cell, the old`
primary cell, and the secondary cell) located generally southeast of the station
Powerhouse These three basins are interconnected and have a combined total natural
drainage area of approximately 372 acres An additional approximately 73 acres of
stormwater runoff from certain station yard areas is also routed to the yard sump and
subsequently pumped to, this ash basin system.
The Buck Tie Station is a ,large 230 kV and 11;0 kV regional substation facility located
within the Buck Steam Station property boundaries approximately 1,500 south and
upgradient of the Powerhouse This tie station is a separate facility unassociated with
the Buck Steam Station, and is neither inspected nor maintained by Buck Steam Station
personnel
The Buck Combustion Turbine Combined Cycle (CTCC) station is a new generation
facility under construction, and ,located south of the Buck Tie Station within the Buck
Steam Station property boundaries: Construction is scheduled for completion in
December 2011 Upon completion, the CTCC station will be a separate facility from the
Buck Steam Station from a stormwater permitting standpoint
The Buck Steam Station maintains an up -to -date Spill Prevention Control and
Countermeasure (SPCC) Plan in place in accordance with the USEPA Oil Pollution
Prevention, Regulation 40 CFR Part 112
1

NPDES PERMITTED DISCHARGES SUMMARY
Buck Steam Station has five N.PDES process water outfalls The NPDES discharges are
summarized as'follows
NPDES Outfall 001 — Once - Through Cooling Water,
This discharge is a once - through non - contact cooling water (CCW) system which
condenses steam from the plant condensers This discharge occurs directly to the
Yadkin River
NPDES Outfall 002 - Ash Basin
This is the outflow from the ash settling basin system The ash settling basins are the
repositories for waste' ash sluiced from 'the station Stormwater runoff from the coal
storage pile and from industrial use. areas surrounding the Powerhouse is routed into the
station yard sump that subsequently pumps to the ash, basins. The ash basin system is
also the repository for various wastewater streams including effluent from the sanitary
system, filter backwashes, boiler blowdown wastes, demineralizer regeneration wastes,
boiler cleaning wastes, interior floor'drain discharges, and various other minor waste
streams
NPDES Outfall 002A — Yard Sump Overflow
Should the pumps in the Yard Sump lose power, experience, a mechanical failure, or
become inundated during a large storm event, the sump would overflow through a pipe
into the Yadkin River Overflow from this sump'is not,a normal occurrence
NPDES Outfall 003 — Transformer Cooling Water
This outfall has been eliminated.
NPDES Outfall 004 — Jntake Screen Backwash
This discharge is a river water backwash of the station intake screens to remove the
typical river water debris that collects on the screens
NPDES ` Outfall 005 — Miscellaneous Equipment Cooling, Water
These discharges are once - through non - contact cooling water from the Units 5 and 6
turbine lube oil coolers, condensate coolers, induced draft fans, forced draft fans and
dewatenng pumps These discharges occur though various, outfalls including one roof
drain outfall (SW007),that discharge into the station intake area These discharges are
then drawn into the station CCW system and. subsequently discharged through NPDES
Outfall 001
E

STORMWATER OUTFALLS AND DRAINAGE AREA DESCRIPTIONS
The Buck Steam Station has 27'identified active stormwater outfalls (21 of which are
roof drains) that discharge to surface waters The outfall locations and contributing
drainage area delineations are shown on the accompanying site plan drawing All
identified stormwater outfalls either discharge directly into the Yadkin River, or discharge
onto the ground in close proximity to the river
A description of the contributing drainage area for each outfall is provided below
Included with the description is the approximate location coordinates of the outfalls, the
approximate amount of impervious surface area within the drainage areas, a description
of any significant materials and activities located within the drainage areas, the type of
discharge conveyances, and a description of any discharge control measures
In addition to any °significant materials particular to each drainage basin, herbicides are
applied to selected areas at the Buck Steam Station to eliminate undesirable vegetation
Herbicides are generally used along railways; ash pipelines, and the perimeter fence
Herbicides are also applied, as needed, in the gravel parking lots, switchyard, and
laydown areas Herbicides are sprayed around the fuel oil bulk storage tanks, yard
sumps, transformers; trailers, and the intake structure All herbicides used at Buck
Steam Station are approved by the company and considered safeJo ,the environment
when used according to directions Records are available documenting the areas
treated, and the type and amount of herbicides used
Certain stormwater outfall drainage areas share similarities regarding the presence of
significant materials and /or activities Based on these similarities, stormwater
discharges from certain groups of outfalls can be represented by the discharge of a
designated representative outfall within the group Proposed representative outfalls are
,indicated on the accompanying, ROS request Form, with supporting information provided
on the Representative Outfalls Supplemental Information Table Proposed
representative outfalls are SW002, SW073 and SW005 SW003 is proposed as a stand
alone outfall
3

Outfall SW001 (Drainage Area 1)
Discharge Structure: 12 inch diameter CMP
Location:
West of Units 5 and 6 Switchyard, outside of station fence.
Discharges onto vegetated riverbank.
Coordinates:
350 42'44" N 800 22'46"W
Drainage Area:
3.4 acres
Impervious Area:
15%
Accessibility:
Accessible.
Area Description
The drainage area for SW001 is comprised primarily of grassed yard areas southwest of
the Units 5 and 6 Switchyard. Approximately 1/3 acre of the Units 5 and 6 Switchyard
also lies within this drainage area. The Switchyard is gravel surfaced and contains
various mineral oil- filled transformers and circuit breakers. The largest container in this
Switchyard is a transformer containing 5,250 gallons of mineral oil. The total mineral oil
capacity contained in all electrical equipment in the Switchyard is approximately 55,700
gallons. Approximately 112 acre of paved parking is also located within Drainage Area 1.
All stormwater runoff from Drainage Area 1 is processed through an 8,000 gallon
capacity oil trap tank. The tank is located west of the station access road.
Significant Materials /Activities
Mineral Oil: Mineral oil is stored in various transformers and circuit breakers located in
the Units 5 and 6 Switchyard. Circuit breakers are located within
concrete containments with open drains to the oil trap tank. Transformers
are provided containment by nearby yard drains that discharge into the oil
trap tank.
Discharge Controls
8,000 gallon capacity oil trap tank.

Outfall SW002 (Drainage Area 2)
Discharge Structure: 21 inch diameter CMP
Location: West of Units 5 and 6 Switchyard, outside of station fence.
Discharges onto vegetated riverbank.
Coordinates: 350 42' 47" N 800 22'45" W
Drainage Area: 2.6 acres
Impervious Area: 20%
Accessibility: Outlet inaccessible. Sample collection possible at pipe cutout.
Area Description
The drainage area for SW002 is comprised of approximately 1 acre of the Units 5 and 6
Switchyard. The drainage area also includes a small paved area beneath the Units 8
and 9 Precipitators located north of the Switchyard, and approximately 1/3 acre of paved
parking located west of the Switchyard. The remainder of the drainage area is grassed
yard.
The Units 5 and 6 Switchyard is gravel surfaced and contains various mineral oil- filled
transformers and circuit breakers. The largest container in this Switchyard is a
transformer containing 5,250 gallons of mineral oil. The total mineral oil capacity
contained in all electrical equipment in the Switchyard is approximately 55,700 gallons.
Six small transformers are located on the Units 8 and 9 Precipitators structure. These
six transformers have a total mineral oil storage capacity of 1,776 gallons.
All stormwater runoff from Drainage Area 2 is processed through a 15,000 gallon
capacity oil trap tank. Most electrical equipment containing mineral oil located in the
Units 5 and 6 Switchyard is within curbed concrete containment pads with open drains to
the oil trap tank. The tank is located west of the station access road.
Sianificant Materials /Activities
Mineral Oil: Mineral oil is stored in various transformers and circuit breakers located in
the Units 5 and 6 Switchyard. Most electrical equipment containing
mineral oil is located within curbed concrete containment pads with open
5

drains to the oil trap tank Mineral oil is also stored in six small
transformers on the Units 8 and 9 Precipitator structure
Discharge Controls
15,000 gallon capacity oil trap tank
I

Outfall SW003 (Drainage Area 3)
Discharge Structure: 10 inch diameter CMP
Location:
West end of Powerhouse. Discharges onto vegetated riverbank.
Coordinates:
350 42' 50" N 800 22'40"W
Drainage Area:
0.5 acres
Impervious Area:
50%
Accessibility:
Accessible.
Area Description
The drainage area for SW003 encompasses the Service Building roof, a small storage
shed roof, and paved driveways and landscaped areas on the west side of the Service
Building.
The drainage area also includes a covered compressed gas storage pad, and a vapor
extraction tank. The vapor extraction tank has the capacity to store 150 gallons of
extracted oil, and is located within a concrete containment basin adjacent to the
Powerhouse wall. The containment is fitted with a manually operated drain valve.
Containment contents are inspected prior to containment drainage in accordance with
the facility SPCC Plan.
Significant Materials /Activities
Used Oil: Used oil is captured and stored in the 150 gallon capacity vapor
extraction tank. The tank is located within a concrete containment basin
with a closed and locked drain valve. The containment contents are
inspected prior to draining.
Discharge Controls
None.

Outfall SW048 (Drainage Area 48)
Discharge Structure: 15 inch diameter steel pipe
Location: North of Units 3 and 4 Switchyard, outside of station fence.
Discharges onto vegetated riverbank.
Coordinates: 350 42' 50" N 800 22'29"W
Drainage Area: 0.4 acres
Impervious Area: 0%
Accessibility: Inaccessible due to steepness of riverbank and dense vegetation.
Area Description
The drainage area for SW048 is comprised entirely of the western half of the Units 3 and
4 Switchyard. The entire drainage area is gravel - surfaced. Located within the drainage
area are four large transformers containing a total of 18,081 gallons of mineral oil, and
nine circuit breakers containing a total of 765 gallons of mineral oil. This electrical
equipment is located within curbed concrete containment pads with manually operated
drain valves. Containment contents are inspected prior to containment drainage in
accordance with the facility SPCC Plan.
Significant Materials /Activities
Mineral Oil: A total of 18,846 gallons of mineral oil is stored inside 4 large
transformers and 9 circuit breakers in the Units 3 and 4 Switchyard. All
this electrical equipment is located within concrete containments with
closed and locked drain valves. Containment contents are inspected prior
to draining.
Discharge Controls
None.

Outfall SW056 (Drainage Area 56)
Discharge Structure: 36 inch diameter CMP
Location: Between Units 3 and 4 Switchyard and the yard sump, outside of
station fence. Discharges directly to surface water.
Coordinates: 35° 42' 50" N 800 22' 27" W
Drainage Area: 47 acres
Impervious Area: 5%
Accessibility: Outlet inaccessible due to partial or complete submergence.
Sample collection possible upstream at manway in below -grade
concrete diversion structure. Sample collection possible only
during extreme storm events (reference area description below).
Area Description
The drainage area for SW056 is comprised of a large, primarily vegetated area located
southeast of the Powerhouse. The new primary cell and the old primary cell ash basins
border this drainage area to the south and east, respectively. Located within Drainage
Area 56 are the combustion turbine units, the Main Fuel Oil Storage Tank, the tanker
truck fuel oil unloading station, and approximately 1,400 linear feet of aboveground fuel
oil piping. The Main Fuel Oil Storage Tank has a modified storage capacity of 649,000
gallons and is located within an earthen containment dike. The tank and containment
dike cover approximately 2.5 acres. The tanker truck unloading station is a paved area
covering approximately 1/4 acre located northeast of the tank. Fuel oil transfer piping
runs from this unloading station to the tank. Fuel oil delivery piping runs from the tank to
the combustion turbine units, and extends on to the Powerhouse.
The combustion turbine area covers approximately 2.5 acres and includes the three
combustion turbine units, one control room building, one maintenance shed, one boat
house, and a tanker truck loading station. The units are surrounded by a paved
perimeter access road. Each combustion turbine unit contains an enclosed 175 gallon
capacity lube oil tank and a 50 gallon trap tank. A 1,000 gallon capacity, normally
empty, concrete fuel oil abort tank is located below -grade adjacent to each unit. All

external areas within the perimeter road surrounding the units are paved or gravel -
surfaced, External areas outside of the perimeter road are grassed
Approximately 1,300 linear feet of ash sluice lines pass through Drainage Area 56 from
the Powerhouse to the new primary cell of•the ash basins The drainage area also
includes approximately 3;500 linear feet of paved roadway, and approximately 2,000
linear feet of gravel roadway
All stormwater runoff from Drainage Area 56 is processed through two, in series, oil trap
tanks, located on the northern end of the drainage area. The upper gradient tank has ,a
capacity of 30,000 gallons This tank discharges into a 60,000 gallon capacity oil trap
tank Stormwate.r�runoff from some portions of the drainage area is routed into the
30,000 gallon oil trap tank, while runoff from other, portions of the area is routed directly
into the 60;000 gallon oil trap tank. Runoff from the paved tanker truck, unloading station
is routed directly into the 60,000 gallon tank. Runoff from most,of the combustion
turbine area and the tanker loading station is routed into the 30;000' gallon tank Open
drains in the floor of the combustion turbine abort'tank vaults also discharge into the
30,000 gallon tank
Aboveground fuel oil piping located within Drainage Area 56 is typically under constant
static pressure due to an open -valve condition at the Main Fuel Oil Storage Tank
Although any release from this piping would, route to the aforementioned oil trap tanks,
these tanks do not have the storage capacity to contain the full contents of an
undetected system release Consequently, Outfall 56 was modified to provide
secondary containment for this potential fuel oil release scenario to comply with the most
recent requirements of the station SPCC Plan. Formally, the 60,000 gallon oil trap tank
discharged directly'into the Yadkin River'through Outfall 56 This drainage system was
modified and a below - grade concrete diversion structure,was,in "stalled that now routes
most of the discharge from the 60,000 gallon oil trap tank to the station yard sump The
sump subsequently pumps this discharge to the rash basin system.
Considering the existing capacity of the yard sump pumps, the diversion structure was
designed to allow runoff in excess of a 2 year design storm event to bypass the sump
and discharge through Outfall 56. The outfall was fitted with a rubber flapper outlet to
prevent any backflow from occurring to the sump during high river levels The-outlet is
typically partially submerged
Stormwater discharges will not normally occur through Outfall 56. Most-stormwater
runoff from Drainage Area 56 will discharge to the yard sump and be pumped to the ash
basin system Stormwater discharges will only occur through Outfall 56 during unusually
intense storm events Considering the partially, or likely completely„ submerged
conditions of the outlet during such events, no stormwater sample collection is possible
at the outlet Sample collection is only possible at the upstream manway in the concrete
diversion structure, and only possible during the, extreme storm event
Significant Materials /Activities
'Fuel Oil- Fuel oil is stored in the 649,000 gallon Main Fuel' Oil Storage Tank
located within an earthen containment dike Fuel oil transfer piping runs
from this unloading station to the tank. Fuel oil delivery piping runs from
the tank to the combustion turbine units, and extends on to the
Powerhouse. Fuel oil is unloaded by tanker trucks at the Main Fuel Oil
Storage Tank unloading station. Fuel oil.is loaded into tanker trucks at
10

the fuel oil loading station Small quantities of fuel oil may be temporarily
stored inside the three 1,000 gallon capacity, normally empty, concrete
fuel oil abort tanks located below -grade adjacent,to each combustion
turbine unit This would typically occur only during a unit malfunction
Lube Oil- Lube oil is stored ir%ide three 175 gallon capacity turbine lube oil tanks
located inside the enclosures for the three combustion turbine units
Miscellaneous Oils Miscellaneous oils are stored in 55 gallon drums inside the
combustion turbine maintenance shed (typically4 drums), and
adjacent to each combustion turbine unit (typically, 2 drums at
each unit).
Ash Waste ash is transported through ash sluice piping that runs through the
drainage area
Battery Acid: Battery acid is present in batteries stored inside the combustion turbine
control room building
Discharge Controls
30,,000 gallon and 65,000 gallon capacity oil trap tanks, diversion structure, and yard
sump
11

Outfall SW073 (Drainage Area 73)
Discharge Structure: 36 inch diameter CMP
Location: Approximately 400 feet east of yard sump, outside of station
fence. Discharges directly to surface water.
Coordinates: 350 42' 50" N 80° 22' 17" W
Drainage Area: 16 acres
Impervious Area: 0%
Accessibility: Accessible except during high river levels
Area Description
The drainage area for SW073 is comprised of a large, primarily vegetated area located
east of Drainage Area 56. The drainage area contains approximately 1000 linear feet of
rail lines and approximately 2000 linear feet of gravel roadway.
Significant Materials /Activities
Coal: Train cars carrying coal use the rail lines that pass through the drainage
area.
Discharae Controls
None.
12

Outfall SW075 (Drainage Area 75)
Discharge Structure: 30 inch diameter CMP
Location: Approximately 150 feet east of yard sump, outside of station
fence. Discharges onto ground, then overland approximately 50'
to surface water.
Coordinates: 350 42' 49" N 80° 22'22" W
Drainage Area: 0.25 acres
Impervious Area: 0%
Accessibility: Accessible.
Area Description
The drainage area for SW075 is comprised entirely of a gravel roadway and gravel -
surfaced areas surrounding rail lines near the yard sump. The drainage area contains
approximately 500 linear feet of rail lines and approximately 250 linear feet of gravel
roadway.
Significant Materials /Activities
Coal: Train cars carrying coal use the rail lines that pass through the drainage
area.
Discharge Controls
None.
13

Outfall SW077 (Drainage Area 77)
Discharge Structure: 36 inch diameter CMP
Location: Between Units 3 and 4 Switchyard and the yard sump, outside of
station fence. Discharges onto rip rap slope, then to surface
water.
Coordinates: 350 42' 50" N 800 22' 25" W
Drainage Area: 0.8 acres
Impervious Area: 0%
Accessibility: Inaccessible due to steepness of riprap bank.
Area Description
The drainage area for SW077 is comprised primarily of gravel- surfaced areas
surrounding rail lines near the yard sump. The drainage area also includes portions of a
grassed embankment north of the combustion turbine units. Approximately 1,200 linear
feet of rail lines is located within the drainage area.
Significant Materials /Activities
Coal: Train cars carrying coal use the rail lines that pass through the drainage
area.
Discharge Controls
None.
14

Powerhouse Roof Drain Outfalls
( Outfalls SW005, SW007, SW011, SW015, SW016, SW023, SW025, SW027, SW032,
SW034, SW035, SW038, SW039, SW058, SW065, SW066, SW067, �SWO69, 'SW070,
SW071 and SW072)
(reference following pages for outfall pictures)
Discharge Structure Small diameter steel pipes
Location North face of Powerhouse Discharge directly into the station
intake area
Coordinates 350 42'50" N 80° 22' 32" W (general area)
Drainage Area 1 9 acres (total)
Impervious Area: 100%
Accessibility All inaccessible with the exception of SW005.
Area Description
The drainage areas for these, outfalls are comprised entirely of various sections of'the,
Powerhouse roof All of these outfalls discharge directly into the station intake area
These outfalls ,are mounted on the, north face of the Powerhouse wall and discharge
directly into the station intake area With the exception of SW005, all of these outfalls
are inaccessible (reference pictures on following pages)
Outfall SWO07 is also the discharge for NPDES Outfall 005 that includes non - contact
cooling water from the Units 5 and 6 pre- heaters and ID ,fan bearings and couplings.
This non = contact cooling water discharges into the station intake area, and is then drawn
into the station CCW system and subsequently discharged through NPDES Outfall Q01
Outfall SW034 was also formally the discharge for NPDES Outfall 005 that included non -
contact cooling water from the Unit 3 pre- heaters, ID fans and FD fans This non -
contact cooling water discharged' into the station intake area and was then drawn into
the station CCW system and subsequently discharged through NPDES Outfall 001
Unit 3 was retired from service on May' 14, 2011.
Outfall SW058 was also formally the discharge for NPDES Outfal1 005 that included non-
contact, cooling water from the'Unit 4 pre- heaters, ID fans and FD fans. This non -
contact cooling water discharged into the station intake area and Was then drawn into
the station CCW system and "subsequently discharged through NPDES Outfall 001.
Unit 4 was retired from service on May 14, 2011.
Significant Materials /Activities
None
Discharge Controls
None
15

iii tl
SWO05
swoll
-A
W016
SW025
.. �,��irii�i�l3�1
SWOO 7
SWO1 5
SW027 -0' ^'
��SW023

SW032
SW035
T-i -
SW058
SW072
SW071
►�� •a i ♦`� SW070
SW069
SW034
SW038 __--►
All
Rot
SW0655

REMAINING DRAINAGE AREA DESCRIPTIONS
The Buck Steam Station has additional stormwater runoff areas that discharge into the
Yadkin River These remaining areas are described as follows
Non-point source runoff from eastern portion,of Units 3 and 4 Switchyard:
This area comprises the eastern half of the Units 3 and 4 Switchyard. The entire area is
gravel - surfaced and there are no significant materials or activities contained within this
area The majority of any precipitation falling �on this area will soak into the gravel bed of
the Switchyard.
Non -point runoff area east of Units 3 and 4 Switchyard:
This area comprises approximately 1 acre and is located east of the Un1ts'3 and 4
Switchyard The, area is primarily gravel- surfaced and contains the yard, sump and the
yard sump service transformer The transformer contains 188 gallons of mineral oil, and
is located inside a concrete containment pit with an open drain to the yard sump
Stormwater runoff flows northerly overland to the Yadkin River
Station paved parking lot and landscaped areas northwest of Units 5 and 6
Switchyard:
This area is comprised of non - industrial use areas containing portions of the station
paved parking lot, grassed lawn areas and landscaped areas located northwest of the
Units 5 and 6 Switchyard Some stormwater runoff from these areas enters catch basins
that discharge through either a 12 inch diameter CMP or a 4 inch diameter plastic pipe
into the Yadkin `River northwest of the areas Other stormwater runoff discharges to
northwest into the Yadkin River as non -point source runoff. 'There are no significant
materials or activities contained within these areas.
Station access road:
Several culverts beneath the station access road direct stormwater toward the Yadkin
River from non - industrial use yard areas located east of the road The exterior
vegetated embankment slopes of-the new primary ash basin is located within this area.

YARD SUMP DRAINAGE AREAS
The Buck Steam Station has one yard sump that receives stormwater runoff from
approximately 73 acres of the station and subsequently pumps this runoff to the ash
basin system Rarely occurring emergency sump overflows will discharge directly to the
Yadkin River as NPDES Outfall 002A — Yard Sump Overflow.
Located within the yard sump stormwater drainage area are the following
• The coal storage pile located south of the Powerhouse,
• The approximately 46 acre drainage area of Outfall SW056 that includes the
combustion turbine units and the Main Fuel Oil Storage Tank;
• Paved and gravel- surfaced areas located generally southeast of the
Powerhouse,
• All coal handling buildings, maintenance sheds, conveyors and equipment,
• Two warehouses, the Office /Shop Building, and the Units 5 through 7
Precipitators,
• Approximately 4000 linear feet of rail lines
Included within the yard sump drainage area are the combustion turbine units and the
600,000 gallon capacity Main Fuel Oil Storage Tank located within the Outfall SW056
drainage area Stormwater runoff from this drainage area is processed through two oil
trap tanks located east of the combustion turbine units The outlet from these oil trap
tanks formally discharged through Outfall SW056 This system has been modified and
the discharge rerouted to now direct Drainage Area 56 stormwater runoff to the yard
sump (reference Drainage Area 56 description)
J
19

, PIMA
iA
T Dnew
-
NCDENR
N'"M Cis Ilk Derwmmrt o
E.1WFi0nwexr — N� RE --
FOR AGENCY USE ONLY
Date Received
Division of Water Quality / Surface Water Protection Yew Month Day
National Pollutant Discharge Elimination System
REPRESENTATIVE OUTFALL STATUS (ROS)
REQUEST FORM
if a facility is,required to sample multiple discharge locations with very similorstormwater discharges, the
pernOttee-moypetition the Director for, Representative Outfall Status (ROS). DWQ may grant Representative
Outfall Status if stormwater discharges from a single outfall'are representative of discharges from multiple
outfalls. Approved "ROS will reduce the number of outfalls where an ical sampling requirements apply.
if Representative Outfall StgtusJs granted, ALL outfalls are still subject t&the- qualitative monitoring
requirements of the, facility'spermrt— unless otherwise allowed by,the permit (such as IVCGO20000) and DWQ
approval. The approval letter from DWQ must be kept on site with the facility's Stormwater Pollution
Prevention Plan. The facility must notiify DWQ in writing if any changes affect representative status.
For questions, please contact the DWQ Regional Office for your area (see page 3).
1) Enter the permit number to- which'this ROS request applies:
Individual Permit (or) Certificate of Coverage
N1 f .jC, „5 =°
2) Facility Information:
Owner /Facility Name Duke Energy �Carol inas, LLC
Buck Steam Station 1555 Dukeville,Road, Salisbury, NC 28146
Facility Contact
Street Address
City
E -mail Address
Telephone No.
Mark' McGary
PO Box 1006 Mail Code EC13K
Charlotte _ State NC ZIP Code 28201 _
Mark. McGary@duke - energy.com
980 - 373 -7898 Fax-
3) List the,representative,outfall(s) information (attach additional sheets if necessary):
Outfall(s) SWO02 isfrepresentative of Outfall(s) SWO01 and SWO02 _
Outfalls' drainage areas have'the same or similar activities? 'Yes 0 No
Outfalls' drainage areas contain the same, or similar materials? )(Yes 0 No
Outfalls have similar monitoring results,?
0,Yes 0 No XNo data*
Outfall(s), SWO73 is,representative of Outfall(s) SW073, SW075,and SW077
Outfalls' drainage areas have the same or similar activities? )'Yes 0 No
Outfalls' drainage areas,contain the same or similar materials? XYes 0 No
Outfalls have similar monitoring results? 0 Yes 0 No XNo °data*
Outfall(s) SWO05 is representative of Outfall(s)
,SW071 and SW072
Outfalls' drainage areas have the same or similar activities? 'Yes 0 No
Outfalls' drainage areas contain the same or similar materials? Yes 0 No
Outfalls have similar monitoring - results? 0 Yes 9 No XNo data*

Representative Outfall Status Request
*Non - compliance with analytical monitoring prior to this request may prevent ROS approval. Specific
circumstances will be considered by the Regional Office responsible for review.
4) Detailed explanation about why the outfalls above should be granted Representative Status:
(Or, attach a letter or narrative to discuss this information.) For example, describe how activities and /or
materials are similar.
See attached Representative Outfalls Supplemental Information table.
5) Certification:
North Carolina General Statute 143 -215.6 B(i) provides that:
Any person who knowingly makes any false statement, representation, or certification in any application, record,
report, plan, or other document filed or required to be maintained under this Article or a rule implementing this
Article; or who knowingly makes a false statement of a material fact in a rulemaking proceeding or contested case
under this Article; or who falsifies, tampers with, or knowingly renders inaccurate any recording or monitoring device
or method required to be operated or maintained under this Article or rules of the [Environmental Management]
Commission implementing this Article shall be guilty of a Class 2 misdemeanor which may include a fine not to exceed
ten thousand dollars ($10,000).
1 hereby request Representative Outfall Status for my NPDES Permit. I understand that ALL outfalls are still
subject to the qualitative monitoring requirements of the permit, unless otherwise allowed by the permit
and regional office approval. I must notify DWQ in writing if any changes to the facility or its operations take
place after ROS is granted that may affect this status. If ROS no longer applies, I understand I must resume
monitoring of all outfalls as specified in my NPDES permit.
I certify that I am familiar with the information contained in this application and that to the best of my
knowledge and belief such information is true, complete, and accurate.
Printed Name of Person Signing: Stephen A. Townsend
Title: General Manager II
of Applicant)
(Date Signed)
Please note: This application for Representative Outfall Status is subject to approval by the
NCDENR Regional Office. The Regional Office may inspect your facility for compliance with the
conditions of the permit prior to that approval.
Final Checklist for ROS Request
This application should include the following items:
0 This completed form.
0 Letter or narrative elaborating on the reasons why specified outfalls should be granted representative
status, unless all information can be included in Question 4.
0 Two (2) copies of a site map of the facility with the location of all outfalls clearly marked, including the
drainage areas, industrial activities, and raw materials /finished products within each drainage area.
0 Summary of results from monitoring conducted at the outfalls listed in Question 3.
Any other supporting documentation.
Mail the entire package to:

Representative Outfall Status Request
NC DENR Division of Water Quality
Surface Water Protection Section
at the appropriate Regional Office (See map and addresses below)
Notes
The submission of this document does not guarantee Representative Outfall Status (ROS) will be granted as
requested. Analytical monitoring as per your current permit must be continued, at all outfalls, until written
approval of this request is granted by DWQ. Non - compliance with analytical monitoring prior to this request
may prevent ROS approval. Specific circumstances will be considered by the Regional Office responsible for
review.
For questions, please contact the DWQ Regional Office for your area.
Asheville Regional Office
2090 U-S. Highway 70
Swannanoa, NC 28778
Phone [phone]
FAX [phone]
Fayetteville Regional Office
Systel Building,
225 Green St., Suite 714
Fayetteville, NC 28301 -5094
Phone [phone]
FAX [phone]
Mooresville Regional Office
610 East Center Ave.
Mooresville, NC 28115
Phone [phone]
FAX [phone]
Raleigh Regional Office
1628 Mail Service Center
Raleigh, NC 27699 -1628
Phone [phone]
FAX [phone]
Washington Regional Office
943 Washington Square Mall
Washington, NC 27889
Phone [phone]
FAX [phone]
Wilmington Regional Office
127 Cardinal Drive Extension
Wilmington, NC 28405
Phone [phone]
FAX [phone]
Winston -Salem Regional Office
585 Waughtown Street
Winston- Salem, NC 27107
Phone [phone]
Water Quality Main FAX [phone]
Central Office
1617 Mail Service Center
Raleigh, NC 27699 -1617
Phone [phone]
FAX [phone]

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Please print or type in the, unshaded, area s
EPA ID Number (copy from item I of Form 1)
Form Approved'sOMB No 2040 -0086
Approval expires 5 -31 -92
Form
21F
NPDES
United States Environmental Protection Agency
Washington, DC 20460
r�ir E Application for Permit to Discharge Storm Water
PA Discharges Associated with Industrial Activity
Paperwork Reduction Act Notice
Public reporting "burden for this application is estimated to ; average 286 hours per applicahon,'induding time for reviewing instruchons,,searchrng existing data
sources, gathering and maintaining the dataaneeded, and completing and reviewing the oollllecfoh of inforination Send oomments regarding the burden estimate,
any other aspect of this eollechon of informahon,or suggestons,for improvwng,this form „mdudng suggestions whichImay increase or reduce this burden to Chief,
Information Policy Branch, PM -223, US Enwronmental,Protechon Agency, 401'M,St, SW,' Washing_ tong DC 20460, or Director,, Office of Information and'Regulatory
Affairs, Office ofMana ement and BudgeUWashington, DC 20503
I. Outfall Location
For each outfall, list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving, water
A Outfall Number
list
B Latitude
C Longitude
D Receiving Water
name
SW 002
II. Improvements
A Are you now required by any Federal, State, or local authority to meet any implementation schedule for the construction, upgrading or
operation of wastewater treatment equipment or °practices or any other environmental programs which may affect,the•discharges described
in this application? This includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance
schedule letters, sti ulations, court orders, and grant or loan conditions
1 Identification of Conditions,
Agreements, Etc
2 ,Affected Outfalls
3 Brief Description of Project
4 Final
Com liance Date
number
source,of dischar e
a req
b , ro
B You may attach additional sheets describing any additional water pollution (or other environmental projects'which may affect your discharges)
you now have under way or which you plan Indicate whether each program is now under way or planned, and indicate your actual or planned
schedules for construction
III. Site Drainage Ma
Attach a site -map showing topography (or indicating the outline. of drainage areas served by ,the outfall(s) covered in the application if a
topographic map Is unavailable) depicting the facility jncluding each of its intake and discharge structures, the drainage area of,each storm
water outfall, paved areas and buildings Within the drainage area, of each storm water outfall, each known past or present areas used for
outdoor storage or disposal of, significant materials, each existing structure control measure to reduce pollutants in storm water runoff,
materials loading and access areas, areas where pesticides, herbicides, sod conditioners and fertilizers are applied, each of its hazardous
waste treatment,,storage or disposal units (including each are not required to'have a RCRA permit which is, used for accumulating hazardous
waste under 40 CFR 262 34), each well where fluids from the facility are, injected' underground, springs, and other surface water'bodies which
receive storm water discharges from the facility
EPA Form 3510 -2F (Rev 1 -92) Page 1 of 3 Continued on Page 2

Continued from the Front
IV. Narrative Description of Pollutant Sources
A Foneach outfall, provide an estimate of the area (include units) of impervious�surfaces,(including paved areas and budding' roofs) drained
to the,outfall, and an estimate of the total surface area drained by the outfall
Outfall
Number
Area of Impervious Surface
ro "vide units
a Total'Area, Drained
(provide units
Outfall
Number
Area of Impervious Surface
(provide units
Total Area Drained
rovide�urnts
SW002
B Provide•a narrative descrnption,of significant materials that,are currently or in the past three years have been treated, stored or disposed
in a manner to allow exposure to storm water, method of treatment, storage, or disposal, past and present materials management
practices employed to minimize contact by these materials with storm water runoff, materials loading and access,areas, and the location,
mariner, andirequency in which pesticides, herbicides, sod conditioners, and fertilizers are applied
C For each outfall, provide the location and a description of existing structural and nonstructural control measures to reduce pollutants in
storm water runoff, and a description of the treatment' the storm water receives, including the schedule and type of maintenance for
control and treatment measures and ,the ultimate disposal of an solid or flwd'wastes other than b discharge
Outfall
List Codes from
Number
Treatment
Table 2F -1
S W002'
V. Non Stormwater Discharges
A I certify under penalty of law that the outfall(s) covered by this application have been tested or evaluated for the presence of
nonstormwater discharges, and that all- nonstormwater discharges from these outfall(s) are identified in either an accompanying Form 2C
or Form 2E application for the outfall
Name of Official Title (type or pant)
Signature
Date Signed
B provide a,descri tion of the method used, the date of any testing, and the onsite drainage points that were directly observed during a test
VI. Significant Leaks or Spills
Provide existing information regarding the history of significant leaks or spills of toxic or hazardous pollutants at the facility in the last three
ears, including the approximate date and, location of the spill or leak, and the type and amount of material released
EPA,Form 3510 -21F (Rev 1 -92) Page 2 of 3 Continued on Page 3

EPA ID Number (copy from Item I of Form 1)
Continued from Page 2
VII. Discharge Information
A,B,C, & D: See instruction before proceeding. Complete one set of tables for each outfall. Annotate the outfall number in the space provided.
Tables Vii -A, VII -B, and VII -C are included on separate sheets numbered VII -1 and VII -2.
E. Potential discharges not covered by analysis - is any toxic pollutant listed in table 2F -2, 2F -3, or 2F -4, a substance or a component of a
substance which you currently use or manufacture as an intermediate or final product or byproduct?
❑ Yes (list all such pollutants below) ❑ No (go to Section IX)
VIII. Biological Toxicity Testing Data
Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or
on a receiving water in relation to your discharge within the last 3 years?
❑ Yes (list all such pollutants below) ❑ No (go to Section IX)
IX. Contact analysis Information
Were any of the analysis reported in item VII performed by a contact laboratory or consulting firm?
® Yes (list the name, address, and telephone number of, and pollutants ❑ No (go to Section X)
analyzed by, each such laboratory or firm below
A. Name
B. Address
C. Area Code & Phone No.
D. Pollutants Analyzed
Pace Analytical Services, Inc 9800 Kincey Ave Suite 100 704 - 875 -9092 Oil& Grease
Huntersville, NC 28078
Pace Analytical Services, Inc 2225 Riverside Dr 828 - 254 -7176 Wet chemistry &
Asheville, NC 28804 metals
Pace Analytical Services, Inc 1700 Elm St 612 - 607 -1700 Thallium
Minneapolis, MN 55414
Florida Radiochemistry Services 5456 Hoffner Ave Suite 201 407 - 382 -7733 Radiochemistry
Orlando, FL 32812
X. Certification
1 certify under penalty of law that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and
belief, true, accurate, and complete. 1 am aware that there are significant penalties for submitting false information,
including the possibility of fine and imprisonment for knowing violations.
A. Name & Official Title (type or print)
B. Area Code and Phone No.
C. Signature
D. Date Signed
EPA Form 3510 -2F (Rev. 1 -92) Page 3 of 3

EPA ID Number (copy from Item / of Form 1)
Form Approved OMB No 2040 -0086
Approval expires 5 -31 =92
VII. Discharge Information Conttnued'from page 3 of Fofm 2F
,Part A - You must provide the results of at least one,analysis for every pollutant in, this table Complete one table for, each outfall See
instructions for additional details
Maximum Values
Average Values
Number
Pollutant
include `units
include -units
Of
And,
Storm
Grab Sample
Grab Sample
CAS Number
Taken During
Flow- weighted
Taken During
Flow - weighted
Events
(if available)
First 30
Composite
First 30
Composite
Sampled
Minutes
Minutes
Sources',of Pollutants
Oil & Grease,
<5.0 ,mg/L
N/A
1
Biological Oxygen
3 8 mg/L
2.0 mg /L
1
Demand BOD5
Chemical Oxygen
54 0 mg /L
1
Demand COD
Total Suspended
64 2 mg/L
48.5 mg /L
1
Solids TSS
Total Organic
0°99 mg /L
0.84 mg /L
1
Nitrogen
Total'
0 16 mg /L
0:18 mg /L
1
Phosphorus
pH
Mmxmum
Maximum
Minimum
Maximum
1
8,5
Part B - List each pollutant that °is limited in an effluent guideline which the facility is subject to,or any pollutant listed in the facility's NPDES
permit for its process�wastewater (if the facility is operating under an existing NPDES permit) Complete one table for each outfall
See the instructions for additional details and requirements
Maximum Values
Average,Values
Number
Pollutant
include units
include units
Of
And
Storm
Grab Sample
Grab Sample
CAS Number
Taken During
Flow- weighted
Taken During
Flow- weighted
Events
(if available)
First'30
Composite
First 30
Composite
Sampled
Minutes
Minutes
Sources of Pollutants
Bromide (_24959 -67 -9)
Chlorine, Total
residual
Ammonia (as N)
0.41 mg/L
0.46 mg/L
0.39 mg/L
0.46 m /L
2 __
Chloride
Color _ -
30 0 units
32.0 units
30.0 units
-16 units
2
Fluoride, (16984-48-8)
0 25 mg/L
0.24 mg/L
1
Nitrate - Nitrite (as N)
0 99 mg/L
1.2 mg/L
0.79 mg/L-
0.96 m /L
2
Radioactivity, alpha
1
total
Radioactivity, beta
3.87 pCWL
1
total
+1-1.38
Radioactivity, radium
1
total
Radioactivity,, radium
0.313 pCi /L
1
226 total
+1-0.321
Sulfate (as SO4)
15 1,mg /L
15.9 mg /L
1
14808 -79 -8
Sulfite,(as SOa)
1
14265 -45 -3
Aluminum, Total
2330 ug /L
1920 ug /L
1
7429 -90 -5
,Barium, Total
32 5 ug /L
27.6 ug /L
1
7440 -39 -3
'Boron, Total (7440=
70 8 ug /L
63.3 ug /L,
1
42 -8
Cobalt, Total (7440_-
1
48 -4
Iron,'Total (7439 -89 -6)
3040 ug /L
2590 u /L
1
_
Magnesium, Total
1590 ug /L
1560 ug /L
1
'(7439-95-4)
',Molybdenum, Total
<5 0 ug /L
<5.0 ug /L
1
-98 -7
_
17439
Manganese, Total
76 5 ug /L
73.1 ug /L
1
,(7439-96-5)
EPA Form 3510 -2F (Rev 1 -92) Page VII -I Continue on Reverse

'Tin, Total
1
(7440 -31 -5 )
Titanium, Total
1
7440 -32 -6
Antimony, Total
<5 O,ug /L
<5.0 Ug /L
1
7440 -36 -0
Arsenic, Total
<5 0 ug /L
5.0 ug /L
1
7440 -38 -2
_
Beryllium, Total
1
7440 -41 -7
Cadmium, Total
1
7440 -43 -9
Chromium, Total
<5 O ug /L
<5.0 ug /L
1
7440 -47 -3
Copper, Total
149 ug /L
141 ug /L
1
7440 -50 -8
Lead, Total
1
7439 -92 -1
Mercury, Total
1
7439 -97 -6
Nickel, Total
8 3 ug /L
7.6 Ug /L
1
7440 -02 -0
Selenium, Total
25 0 ug /L
19.6 Ug /L
1
7, 782 -49 -2
_
Silver, Total
1
7440 -22 -4
Thallium, Total
<10 ug /L
<10.0 ug /L
1
7440 -28 -0
Zinc, Total
1
7440 -66 -6
EPA Form 3510 -2F (Rev 1 -92) Page VII -1 Continue on Reverse

Continued from the Front
Part C - List each pollutant shown in Tables 2F -2, 2F -3,, and 2F-4-that you know or have,reason to believe is present See`the'mstructions for
additional detads,and requirements Complete one table for each outfall
Pollutant
And
CAS Number
(if available)
Maximum °Values'
Include units
Average Values
include, units
Number
Of
Storm
Events
Sampled
Sources of Pollutants
Grab Sample
Taken During
First 30
Minutes
Flow- weighted
Composite
Grab Sample
Taken During
First 30
Minutes
Flow- weighted
Composite
Cyanide, Total
57 -12 -6
Phenols, Total
Surfactants (MBAs)
Fecal',Cohform CHT
29 CFU/
100 mL
Part D - Provide,data
for the storm events which resulted in the maximum ,values,for the flow Weighted composite sample
1
Date,of
Storm
Event
2
Duration
of Storm Event
(in minutes)
3
Total rainfall
during storm event
(in inches)
4
Number of hours between
beginning +of'storm measured
and urable'prev_i -e-vent
measurable rain event
5
Total flow from
(gallons oar specify units)
3116108
220
1.83
>72 hrs
135163 gallons
7 Provide,a description �of the method'of flow measurement or estimate
EPA,Form 3510 -2F (Rev 142) Page VII -2

Flows were determined using a run -off coefficient along with drainage area, total rainfall and duration of the
event.
EPA,Form 3510 -2F (Rev 1 -92) Page VII -2

Please print or type in the unshaded areas
;EPA ID Number (copy from,rtem I of Form 1)
Form Approved OMB'No 2040 -0086
Approval expires 5 -31 -92
Form
2F
WDES,
United States Environmental Protection Agency
Washington, DC 20460
Application for Permit to Discharge Storm Water
EPA, . Discharges Associated with Industrial Activity
Paperwork Reduction Act Notice
Public reporting burden for this application is estimated to average �286 hours per application, inducting time for reviewng rnstucbons, searching existing data
sources, gathering and maintaining the data,needed, and completing and reviewing the oollecbon of information Send comments regarding the burden estimate,
any other aspect,of this, collection, of information or suggestons,for improving this form, induding�suggesbons which may increase or, reduce this burden to Chief,
Information Policy Branch, PM -223; U S Environmental Protection Agency, 401 M St, SW, Washington, DC 20460, or Director, Office of Informaton and,Regulatory
Affairs, Office of Management and Budget,,WasGhgton, DC 20503
I. Outfall Location
For each outfall, list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water
A Ou_tfall Number
list
B Latitude
C Longitude
D Receiving Water
name
SW' 003
II. Improvements
A Are, you now required by any Federal', State, or local ,authority to meet any limplementation schedule for the construction, upgrading ,or
operation of, wastewater - treatment equipment or practices,or any other environmental programs`which may affect the discharges described
in this application? This includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance
schedule letters, str ulations, court orders, and grant or loan conditions
1 Identification of Conditions,
Agreements, Etc
2 Affected Outfalls
3 Brief Description of Project
4 Final
Com fiance Date
number
source,of discharge
a req
b prol
i
B You may attach additional sheets describing any,additional water pollution (or other environmental protects which may affect your discharges)
you now have -under way or which you plan Indicate whether each program is now under way or. planned, and indicate your actual or planned
schedules +for construction
III. Site Drainage Map
Attach a site map showing topography (or indicating the outline of drainage areas served by the outfall(s) covered in the application if a
topographic map Is unavailable) depicting the facility including each of its intake and discharge structures, the drainage area of each storm
water outfall, paved areas and buildings within the drainage area of each storm water outfall, each known past or present areas used for
outdoor storage or disposal of significant materials; each existing structure control measure to reduce pollutants in storm water runoff,
materials loading and access areas, areas where pesticides, herbicides, sod conditioners and fertilizers are, applied, each of its ;hazardous
waste, treatment, storage or disposal'umts (including each are not required to have a RCRA permit which is used for accumulating hazardous
waste'und'er 40 CFR 262 34), each well where fluids from ,the.facility are intecied underground, springs, and other surface,water bodies which
receive storm water discharges from the f'ad-ility
EPA Form 3510- 2F,(Rev 1 -92) Page l .of 31 Continued on Page 2

Continued from the Front
IV. Narrative Description of Pollutant Sources
A For each outfall, provide an estimate of the,area (include units) of impervious surfaces (including paved areas and budding roofs) drained
to the outfall, and an estimate,of the total,surface_area drained by the outfall ,
Outfall
Area of Impervious Surface
Total Area Drained
Outfall
Area of Impervious Surface
Total Area Drained
Number
(provide units
(provide units
Number
rovide units
(provide units
SW003
B Provide a narrative description of significant materials that are currently orim the past,three years have been treated, stored or disposed
in a manner to allow exposure to storm water, method of treatment, storage, or disposal, past and present materials management
practices employed to minimize contact by these materials with storm water runoff, materials loading and access areas, and the location,
manner, and frequency in which pesticides, herbicides, soil conditioners, and fertilizers are applied
�C Forleach outfall, provide the location and a description of existing structural and nonstructural control measures'to, reduce pollutants in
storm water - runoff, and a description of the treatment the storm water receives, including the schedule and type of maintenance -for
control and treatment measures and the ultimate disposal of'any solid or fluid wastes other than by discharge
Outfall
List Codes from
Number
Treatment
Table 217-1
S W003
V. Non Stormwater Discharges
A I certify under penalty of law that the outfall(s) covered by this application have been tested or evaluated for the presence of
nonstormwater,discharges, and that all nonstormwater discharges from these outfall(s) are identifed'in either an accompanying Form 2C
or Form,2E a lication',for the,outfall
Name of Official'Title (type or print)
Signature
Date Signed
B provide a description of the method used, the date of any testing, and the onsite drainage points that were directly observed during a test
VI. Significant Leaks or Spills
Provide existing information regairdingi the history of significant leaks or,spols of toxic,or °hazardous pollutants-at the facility in the lasf three
ears, including th-e,approxij mate,date,and location of the spill or leak, and the type and amount of material released
EPA Form 3510 -2F (Rev 1 -92) Page 2 of 3 Continued on'Page 3

EPA ID Number (copy from Item I of Form 11
Continued from Page 2
VII. Discharge Information
A,B,C, & D: See instruction before proceeding. Complete one set of tables for each outfall. Annotate the outfall number in the space provided.
Tables Vii -A, VII -B, and VII -C are included on separate sheets numbered VII -1 and VII -2.
E. Potential discharges not covered by analysis - is any toxic pollutant listed in table 2F -2, 2F -3, or 2F -4, a substance or a component of a
substance which you currently use or manufacture as an intermediate or final product or byproduct?
❑ Yes (list all such pollutants below) ❑ No (go to Section iX)
VIII. Biological Toxicity Testing Data
Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or
on a receiving water in relation to your discharge within the last 3 years?
❑ Yes (list all such pollutants below) ❑ No (go to Section IX)
IX. Contact analysis Information
Were any of the analysis reported in item VII performed by a contact laboratory or consulting firm?
® Yes (list the name, address, and telephone number of, and pollutants ❑ No (go to Section X)
analyzed by, each such laboratory or firm below
A. Name
B. Address
C. Area Code & Phone No.
D. Pollutants Analyzed
Pace Analytical Services, Inc 9800 Kincey Ave Suite 100 704 - 875 -9092 Oil& Grease
Huntersville, NC 28078
Pace Analytical Services, Inc 2225 Riverside Dr 828 - 254 -7176 Wet chemistry &
Asheville, NC 28804 metals
Pace Analytical Services, Inc 1700 Elm St 612- 607 -1700 Thallium
Minneapolis, MN 55414
Florida Radiochemistry Services 5456 Hoffner Ave Suite 201 407 - 382 -7733 Radiochemistry
Orlando, FL 32812
X. Certification
l certify under penalty of law that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and
belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fine and imprisonment for knowing violations.
A. Name & Official Title (type or print)
B. Area Code and Phone No.
C. Signature
D. Date Signed
EPA Form 3510 -2F (Rev. 1 -92) Page 3 of 3

EPA ID Number (copy from Item / of Form 1) Form Approved OMB No 2040 -0086
Approval expires 5 -31 -92
VII. Discharge Information Contlnued from page 3 of Form 2F
Part A - You must provide the results of at least one analysis for every pollutant in this table Complete one table for each outfall , See
mstructions,for additional details
Maximum Values
Average Values
Number
Pollutant
include units
_ include units
Of
And
Grab Sample
`Grab Sample
`Storm
CAS Number
Taken During
Flow- weighted
Taken During
Flow- weighted
Events
(If available)
First,30
Composite
First 30
Composite
Sampled
Minutes
Minutes
Sources,of Pollutants
Oil ,& Grease
<5.O,mg /L
N/A
1
Biological Oxygen
10 8 mg /L
3.3 mg1L
1
Demand BOD5
Chemical Oxygen
1.42 mg /L
68.3 mg1L
1
_Demand COD
Total Suspended
159 mg /L
104 mg1L
1
Solids TSS
Total Organic
2-8 mg /L
1.3 mg1L
1
Nitrogen
Total
0 32 mg /L
0.21 mg /L
1
Phosphorus
pH
Minimum
I Maximum
Minimum
Maximum _
1
8.5
Part B - List each pollutant that is limited in,an effluent guideline which the facility is subject to or any pollutant listed in the facility's NPDES
permit for its process wastewater (if the facihty,is operatmg,undee an existing NPDES permit) Complete one table'forleach outfall
See the instructions for additional details and re ui�ements
Maximum Values
Average Values
Number
Pollutant
include units
Include units _
Of
And
Storm
Grab Sample
Grab Sample
CAS Number
Taken During
Flow- weighted
Taken During
Flow- weighted
Events
(if available)
First 30
Composite
First 30
Composite
Sampled
Minutes
Minutes
Sources of Pollutants
'Bromide (24959 -67 -9)
Chlorine, Total
residual
Ammonia,(as N)
1.4 mg1L
1.2 mg1L
_
Chlonde
Color
40 0 units
10 units
1
Fluoride (16984 -48 -8)
0 53 mg /L
0 40 mg/L
1
Nitrate - Nitrite (as N)
3 8 mg/L
13 8 mg /L
1
Radioactivity, alpha
1
total
Radioactivity, beta
12 5 pCdL +/-
5 64 pCi /L
total
3115
1 96
Radioactivity, radium
1
total
Radioactivity, radium
0 157 pCi /L
0 287 pCi /L
226 total _ _
41-0309
0 294
Sulfate,(as SO4)
12 9 mg /L
13.0 rh91L
1
14808 -79 -8
Sulfite (as SO3)
1
14265 -45 -3
Aluminum, Total
5850 ug /L
3530 ug /L
_
1
7429 -90 -5
Barium, Total
62 3 ug /L
40.8 ug /L
1
7440 -39 -3
Boron, Total (7440 -
70 1 ug /L
47.6 ug /L
1
42 -8
Cobalt, Total (7440-
1
48 -4
Iron, Total (7439 -89 -6)
3230 ug /L
1750 u /L
Magnesium, Total
790 ug /L
525 ug /L
1
7439 -95 -4
Molybdenum, Total
5 9 ug /L
<5.0 ug /L-
1
7439 -98 -7
Manganese, Total
63 6 ug /L
42.4 ug /L
1
7439 -96 -5
Tin, Total
1
7440 -31 -5
EPA Form 3510 -2F (Rev 142) Page VII -1 Continue on Reverse

Titanium, Total'
1
7440 -32 -6 _
Antimony, Total
<5 0 ug /L
<5.0 ug /L
1
7440 -36 -0
Arsenic, Total
13 0 ug /L
8.0 ug /L
1
7440 -38 -2
Beryllium, Total,
1
7440- _4,1 -7
Cadmium; Total
1
(7440-43-9)-
Chromiu6, Total
6 9ug /L
<5.0 ug /L
1
,7440-47 -3
Copper, Total
52 2,ug /L
28.3 ug /L
1
7,440 -50 -8
Lead, Total
1
(7439-92-1)
Mercury, Total
1
7439 -97 -6
Nickel, Total
19 3 ug /L
13.1 ug /L
1
7440 -02 -0
Selenium, Total
157 ug /L
93.8 ug /L
1
(778249-2)
Silver; Total
1
7.440 =22 -4
Thallium, Total
<10 ug /L
<10 ug /L
1
(7-440-2810), _
Zinc, Total
1
7440 -66 -6
EPA Form 3510 -2F (Rev 1 -92) Page VII -I Continue on Reverse

Cnnhnnarl from tha Frnnt
Part C - List each pollutant shown in Tables 2F -2, 2F -3, and 2F -4 that you know or have reason to believe,is, present See the instructions for
additional details and requirements Complete one table for each outfall
Pollutant
And
CAS Number
(if available)
Maximum Values
include units
Average Values
include units
Number
Of
Storm
Events
Sampled
Sources of Pollutants
Grab Sample
Taken During
First 30
Minutes
Flow- weighted
Composite
Grab Sample
Taken During
First 30
Minutes
Flow- weighted
Composite
Cyanide, Total
57 -12 -5
Phenols, Total
Surfactants (MBAs)
Fecal Coliform�CHT
200 CFU1
100 mL
Part D - Provide data for the storm events which resulted in the maxurium
values foe theAdvi wei hted composite,sample
1
Date of
Storm
Event
2
Duration
of Storm Event
(in minutes)
3
Total rainfall
during storm event
(in inches)
4,
Number of,hours between
begmnm storm measured
en
and end measurablle e previous rain event
5
Total flow from
rain event
(gallons or specify units)
41,312008
360
1.26
>72 hrs
21426 gallons
7 Provide a description of the method of flow measurement onestimate
EPA Form 3510 -21F (Rev 1 -92) Page VII -2

Flows were determined using; run -off coefficient along with drainage area, total rainfall ,and duration of the
event:
EPA Form 3510 -2F (Rev 1 -92) Page VII -2

i
f
MOM
WPM
sh,Duke
iEner
A" 07 -09 -07
Analytical, Laboratory'
13339 Hagers Ferry'Road
Huntersvdle,.NC 28078 -7929
McGuire Nuclear Complex — M003A2
Phone 704 - 875 =5245 Fax. [phone]
Job Summary Report
Job Numbcr: Buck.gtorm Water
08 -MAR -0300
Project Name:
Customer Name:
Copy To:
Customer Address:
Buck Storm Water
Brandy Starnes
Knob Zalme
MG03A3
Buck Steam Station
Lab Contact: I Perkins
Lab Contact Phone: [phone]
Report Authorized,By:
(Printed Name)
I Perkins
Page 1 of 29
Adobe Compiled Document
Report Authorized By:
(Signature) Date: 1-1-11-63
Data Package
This data package includes analytical results that are applicable only to the samples
described in this narrative. An estimation of the uncertainty of measurement for the
results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the.Analytical Laboratory. Please contact the
Analytical Laboratory with any, questions. The order of individual sections within,this
report is as follows:
Job Summary Report
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Reports (if applicable)
Sub - contracted Laboratory Results
Customer Specific Data Sheets, Reports ,& Documentation (if applicable)
Customer Database Entries
Test Case Narratives
Chain of Custody (COC)

Page 2 of 29
Adobe Compiled Document
MEM Emm
Duke, Analytical Laboratory
IL W- 13339 Hagers Ferry Road
L QV ® Huntersville, NC 28078 -7929
Rw07-03 -07 McGuire Nuclear Complex — MG03A2
Phone- 704- 875 -5245 Fax- 704 - 875 75038
Job Summary Report
Certification
The Analytical Laboratory holds the following Certifications:
New York State Department of Health Certification # 11717,(NELAC)
North Carolina Department of Health & Human Services Certification # 37804
South Carolina (DHEC) Laboratory ID # 99005
North Carolina (DENR) Certification # 248
Analytical results,listed in this report may not be certified by the authorities referenced above.
Contact the Analytical Laboratory for definitive information about the certification status of
specific methods. The results meet all requirements of NBLAC except where deviations are
noted in this report.
Data Flags
Any analytical tests,or individual analytes within a test-flagged with an "X" or a "1" indicate a
deviation from the method quality system or quality control requirement.
Calculations
All results are reported on a wet weight basis unless otherwise,noted.
Sample ID's &.Descriations:
Collection Sample
Sample ID Plant /Station Date Collected By Description
--- - - - - -- ------- - - - - -- ---- - - - - -- ------ - - - - -- ----- -- - - --
28007140 FOSSIL 03/15/2008 B. STARNES BUCK SW 02 GRAB
28007141 FOSSIL 03/15/2008 B. STARNES BUCK SW 02 COMPOSITE
2 TOTAL SAMPLES

®iJ�C� Analytical Laboratory
PM- lnergy® H13339 Hagers Ferry Road
IL untersvdle, NC 28078 -7929
P- 07 -OS-07 McGuire,Nuclear Complex — M603A2
Phone 704 - 875 -5245 Pax. 704 =875 -5038
Job Summary Report
Validation of Analytical Data Package
COC and ,pdf report are in.agreement with sample totals
and analyses (compliance programs and procedures).
ii) All results are less than the laboratory reporting limits.
iii) All laboratory QA/QC requirements are,acceptable.
NP )tS and TCLP results are below permit or regulatory
iv) limits respectively.
Page 3 of 29
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If iv) above is No, document below:
Permit
Variable Result, Limit Notes
V) Components of the Job Summary,geport arranged in order Yes
No
siiptdated,on page one.
Indicate components included:
Job4Sumrimary Report (trihouse)
1-
j- Yes
' No
Analytical Laboratory Certificate
Customer Database Entries (inhouse)
No
If iv) above is No, document below:
Permit
Variable Result, Limit Notes
V) Components of the Job Summary,geport arranged in order Yes
No
siiptdated,on page one.
Indicate components included:
A) Notes and Additional Information.
NA= Not - applicable s/PROCREV /Job Summary (07 -09 -07 -revl) doc
Job4Sumrimary Report (trihouse)
1-
Customer Specific Data Sheets, Reports
& Documeritation (inhouse -if applicable)
F
Analytical Laboratory Certificate
Customer Database Entries (inhouse)
of,Analysis ( mhouse),
r
Analytical Laboratory QC Report
1 y
Test Case Narratives ( inhouse)
(inhouse -if applicable)
jv
Sub - contracted Laboratory Results
1✓'
Chain of Custody
A) Notes and Additional Information.
NA= Not - applicable s/PROCREV /Job Summary (07 -09 -07 -revl) doc

rill, 1
axMalytical
ww pao442b .conr
April 11, 2008
Mr, Jay Perkins
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville; NO 28078,
RE: Project, 08- MAR -0300
Pace Project No:. 9215521
PaceAnalytical Services, Inc
2225 Riverside Or
Asheville, NC 28804
(828)254 -7176
Page 4 of 29
Adobe Compiled Document
Pace Analytical Services, Inc.
9800 Kincey Ave Sude 100
Huntersville, NC 28078
(704)875 -9092
Dear Mr Perkins
Enclosed are the analytical results for sampl'e(s) received by the laboratory on March 17, 2008 The
results relate only to the samples included in this report. Results reported herein conform to the
most current NELAC standards,,where applicable, :unless,ofherw ise,narrated in the body of the
report.
Inorganic Wet Chemistry and Metals analyses were performed-at our Pace,Asheville laboratory and
Organic testing was performed ,af our Pace Huntersville laboratory unless otherwise footnoted. All
Microbiological analyses were,performed at the laboratory where the samples were received:
'If you have any questions concerning this report, please feel,free to contact me.
Sincerely,
Kevin Herring
kevin. herring@pacel abs com
Project Manager
Enclosures
cc Accounts Payable DPEHS, Duke Energy Carolinas, LLC
REPORT OF LABORATORY ANALYSIS
This report'shall not be reproduced, except In full,
vnthout the written consent of Pace Analytical Services, Inc
y •<ap�e
Page 1 of 21

Page 5 of 29
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e Pace Analytical Services, Inc. Pace Analytical Services, Inc
aceAnal ical 2225 Riverside Dr 9800 Kincey Ave Surte 100
Asheville, NC 28804 Hunlersvtile, NC 28078
r' wwwpaeetabs CNli
(828)254 -7176 (704)875 -9092
f
CERTIFICATIONS
Project' 08- MAR =0300
Pace Project No 9215521
Charlotte Certification IDs
Florida1NELAP Ce-dificatiom Number E87627
North Carolina Field Services �Certification Number 5342
Kansas Certification Number E -10364
South Carolina CerOficaton Number, 990060001
Louisiana/LELAP Certification Number,04034
South Carolina Bioassay Certification Number 990060003
North Carolina Drinking Water Certification, Number ,37706
Tennessee Certification Number 04610
North Carolina Wastewater.Certiflcation Number 12
Virginia Certification Number ,00213
Asheville Certification IDs
Flonda/NELAP Certification Number E87648
Pennsylvania Certification Number 68 -03578
L'ouisIana/LELAP CeNficabon Number. 03095
South Carolina Certification Number- 99030001
New Jersey Certifcation Number NC011
South Carolina Bioassay Certification Number 99030002
North Carolina Dnnking Water Certification Number 37712
Tennessee Certification Number 2980
North Carolina Wastewater Certification Number 40
Virginia Certification Number 00072
North Carolina,,Bioassay Certification Number 9
Eden Certification IDs
North Carolina Driking Water Certification Number 37738
North Carolina Wastewater Certification Number 633
Vrginia Drinking WalerCertification Number_00424
REPORT OF LABORATORY ANALYSIS Page 2 of 21
This report shall,nol be'repTduced, exceptiln full,
without the written consent of Pace Analytical Services „Inc

111!4 a
r wwwpxelabsc m
I
Project 08- MAR -0300
Pace Project No, 9215521
Pace Analytical`Services, Inc
2225 Riverside Or
Asheville,'NC 28804'
[phone]
SAMPLE SUMMARY
LabJD Sample ID Matrix Date Collected DateiReceived
9215521001 28007140 Water 03/16/08 09 30 03/17/08 10 50
9215521002 28007141 Water 03/16108 09 30 03/,17108'10 50
Page 6 of 29
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'Pace Anatytical Services, Inc
9800 Kfncey Ave Sude 100
Huntersvdle, NC 28078
(704)875 -9092
REPORT OF LABORATORY ANALYSIS Page 3 of 21
This repot shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc

Ar
e
7WeAnalytipi
wwwpftwabsccm
Project 08- MAR -0300
Pace ProjectlNo 9215521
Lab ID
9215521001 28007140
9215621002 28007141
Pace Analytical Services;,lnc
2225 Riverside Dr
Asheviffe,-NC,28804
(828)254 -7176
SAMPLE ANALYTE COUNT
Page 7 of 29
Adobe,Complled Document
Pace Analytical Services. Inc
9800 KlnceyAve Suite 100
HuntersvlQe, NC 28078
(704)875 -9082
Sample ID Method
Analysts
Analytes
Reported
ASTM D516 -90,02
SER
1
EPA4664A
EAJ
1
EPA 200 7
SHB
14
EPA 3501
EWS
1
EPA 3512
EWS
1
EPA 353'2
RAB
2
EPA 365 1
JDA
1
SM 2120B
EWS
1
SM 2540D
DMN
1
SM 450OF /C
WWB
1
SM 5220D
MJR
1
ASTM D516 -90,02
SER
1
EPA 200 7
SHB
14
EPA 3501
EWS
1
EPA 351,2
EWS
1
EPA 353 2
RAB
2
EPA 365 1
JDA
1
SM 21206
EWS
1
SM 2540D
DMN
1
SM 450OF /C
WWB
1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc
19p
Page 4 of 21

aceAnalydcal
1, wwwpacelabsc=
I
Page 8 of,29
Adobe Compiled Document
Pace Analytical Services, Inc
Pace Analytical Services, Inc
2225 - Riverside Dr
9800 Klncey Ave Sude,100
Asheville, NC 28804
Hurdersville, NC 28078
(828)2547176
(704)875 -9092
ANALYTICAL RESULTS
Project 08- MAR -0300
Pace Project No 9215521
Sample. 28007140 Lab'ID: 9216521001 Collected 03/16168,09:36 Received 03117/08 10 50 Matrix Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No Qual
HEM,`Oil�and Grease
Analytical Method EPA 1664A
Oil and Grease
ND mg/L
50
1 1
1
03/25/08 17 57
200:7,MET ICP
Analytical Method EPA 2007
Preparation Method:'EPA
200 7
Aluminum
2330 ug/L
100
25.0
1 03/21/0815 55
03/24/08 15 44 7429 -90 -5
Antimony
ND ,ug /L
50,
26
1 03121/0815.55
03/24/08 15 44 7440 -36 -0
Arsenic
ND ug/L
50
27
1 03/21/0815 55
03124/08,1544 7446 -38 -2
Barium
32.6 ug /L
50
020
1 03/21/0815 55
03/24/0815 44 7440 -39 -3
Boron
70.8 ug /L
1010
47
1 03/21/0815 55
03/24/08 15 44 7440 - 424
Chromium
ND ug/L
5`0
040
1 03/21/0815.55
03/24/081544 7440 -47 -3
Copper
149 ug /L
50
0'30
1 03/21/0815 55
03124/08 15 44 7440 -50-8
Iron
3040 ug/L
500
14'0
1 03121108'115 55
03/24/08 15 44 7439 -89 -6
Magnesium
1590 ug/L
100
30
1 03/21/0815 55
03/24/08 15 44 7439 -95-4
,Manganese
75.5 ug/L
510
030
1 03/21/0815 55
03124/08 1.5 44 7439 -96-5
Molybdenum
ND ug/L
50
1 1
1 03/21/08 15 55
03/24/08 15 44 7439 -98 -7
Nickel
8.3 ug/L
50
1-7
1 03/21108 15.55
03/24/08 15 44 7440-02-0
Selenium
25.0 ug/L
100
38
1 03/21108 15:55
03%24/08 15 44 7782 -49 -2
Thallium
ND ug/L
10.0
30
1 03/21/08 15 55
03/24/08 15.44 7440 -28-0
2120121V Apparent Color
Analytical Method ,SM 2120B
Apparent Color
30.0 units,
50
1
03/18/08 15 30 H1
ZS40D Total Suspended Solids
Analytical Method SM 2640D
Total Suspended'Sollds,
6,41 mg /L
25
1
03/19/08 23.52
4500FC Fluoride
Analytical Method SM 450OF /C
Fluonde�
0.25 mg/L
010
0,10
1
03/26/081426 16984 -48-8
360.1,Ammonia
Analytical Method ,EPA 3501
Nitrogen, Ammonia
0 41' mg/L
010
0.10
1
03/21/0815 46 7764 -41 -7
3512 TotaM4eldahl Nitrogen
Analytical Method EPA 351 2
Nitrogen, Kjeldahl, Total
1.4 mg1L
050
050
1
04/08/08 15.59 7727 -37 -9
353 2 Nitrogen, NO2 NO3,unpres
Analytical Method- EPA 353 2
Nitrogen, Nitrate
0 58 mg/L
010
010
1
03/18/08 2121
Nitrogen, Nitrite
NO mg/L
010
010
1
03/18/08 21.21
365.1 Phosphorus, Total
Analytical Method EPA 365 1
Phosphorus
0.16 mg /L
010
010
1
04/08108 10 02 7723 -14 -0
5220D COD
AnalyBcal!Method SM 5220D
Chemical Oxygen Demand
64 0 mg/L
25.0
250
1
03/22/08 15 30
Date 04/11/2008 09 06 AM REPORT OF LABORATORY ANALYSIS Page 5 of 21
This report shall not be reproduced,�except in full,
without the written consent of Pace Analytical Services„Inc_
� a

aceAnalytical e
wiwxpacOMCGM
Pace Analytical Services, Inc.
2225 Riverside Dr
Asheville, NC 28804
(828)254 -7176
ANALYTICAL RESULTS
Page 9 of 29
Adobe Complled'Zocument
Pace Analytical Services, Inc
9800 Kincey Ave Sulle 100
Hunlersville. NC 28078
(704)875 -9092
'Project. 08- MAR -0300
Pace,Project No 9215521
Sample: 28007140 Lab ID: 9215521001 Collected 03/16/080930 Received* 0311710810-5O Matnx_ Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No Qual
ASTM D516 -9002 Sulfate Water Analytical Method. ASTM 0516 -90,02
Sulfate 15.1 mg /L 5,0 50 1 03122/08;21 15 14808 -7918
Date 04/11/2008 09 06 AM REPORT OF LABORATORY ANALYSIS Page 6'of 21
This report shag not be reproduced, except In full,
without the written consent of Pace Analytical Services, Inc
,,

Arl
xAnalytical e
www.pacerabs tali
r`
Pace Analytical Servlces,`Inc.
2225 Riverside Dr
Asheville, NC 28804
(828)254 -7176
ANALYTICAL RESULTS
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Pace Analytical'Services, Inc
9800 KlnceyAve Suite 100
Huntersville, NC 28078
(704)875 -9092
Project 08 -MAR -0300
Pace Project,No 9215521
Sample: 28007141 Lab ID: 9215521002 Collected 03/16/0809:30 Received 03/17/081050 Matrix Water
Report
Parameters Results Units Limit MDL OF Prepared Analyzed CAS No Qual
200.7 MET ICP
Aluminum
Antimony
Arsenic
Barium
Boron
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Seleruum
Thallium
2120B,W Apparent Color
Apparent Color
2640D Total Suspended'Solids
Total Suspended Solids
4500FC Fluoride
Fluoride
350.1 Ammonia
Nitrogen, Ammonia
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total
353 2 Nitrogen, N021NO3 unpres
Nitrogen, Nitrate
Nitrogen, Nitrite
366.1 Phosphorus, Total
Phosphorus
ASTM D616 -9002 Sulfate Water
Sulfate
Analytical Method EPA 200 7 Preparation Method EPA 200 7
1920 ug /L
100
2510
1
03/21/08 15 55
0312410815.47 7429 -90 -5
NO ug /L
50
26
1
03/21/0815 55
03/24/08 15.47 7440 -36-0
ND ug/L
50
2,7
1
03/21/08 15 55
03/24/08 15 47 7440 -38 -2
27:6 ug/L
so
0120
1
03/21/08 15 55
03/2408 15 47 7440 -39 -3
633 ug/L
100
47
1
03/21 /0815 55
03/24/08 15 47 744042 -8
ND ug /L
50
0'40
1
03/21/08 15 55
03/24/08,15 47 7440147 -3
141 ug /L
50
030
1
0341108 15 55
'03/24/08'15 47 7440 -50-8
2690 ug /L
50:0
14'0
1
03/21/08 15 55
03124/08 15 47 7439 -89 -6
1560 ug/L
100
30
1
03121/08 15 55
03/24108 15 47 7439 -95-4
73.1 ug /L
510
030
1
03/21/08 15 55
`03124/08 15 47 7439 -96 -5
ND ug/L
50
1.1
1
03/21/0815 55
03/24/0815 47 7439 -98 -7
7.6 99/1-
50
17
1
03121/08 15 55
03/24/08 15 47 7440 -02 -0
19.6 ug /L
10`0
38
1
03/21/08 15'55.
03/24/0815 47 7782 -49-2
ND ug /L
100
3'0
1
03/21/08 15 55
03/2410815 47 7440 -28-0
Analytical Method tSM 21206
32.0 units
50
1
03/18/0815 30 H1
Analytical Method SM 2540D
48.5 mg/L
2'5
1
03119/08 23 53
Analyhcal Method ,SM 450OF /C
0.24 mg /L
010
010
1
03/26/0814 26 16984 -48-8
Analytical Method_ EPA 3501
0:46 mg/L
010
010
1
03/21/081546 7764141 -7
Analytical Method `EPA 351 2
1.3 mg /L
050
050
1
0410810816.01 7727 -37 -9
Analytical Method- EPA 353 2
0.72 mg/L
010
.0 10
1
03/18/08 21 21
ND mg/L
010
0.10
1
03/18/08 2121
Analytical Method EPA -3651
018 mg/L
010
010
1
04 /08/08 10.02 7723 -14-0
Analytical aMethod ASTM D516
-90,02
15.9 mg /L
50
5 0
1
03/22/08 21.18 14808 -79-8
Date 04111/20080906 AM REPORT OF "LABORATORY ANALYSIS Page 7 of 21
This report'shall not be reproduced, except In full,
without the written consent jof Pace Analytical Servkes,'Inc

/!.IaneAnslytical
wwwpacafabs com
Pace Analytical Services, Inc.
2225 Riverside Dr
Asheville, NC 28804,
(828)254 -7176
QUALITY CONTROL,DATA
Page 1,1 of 29
Adobe Compiled Document
Pace Analytical Services, Inc
9800 Kincey Ave Suite 100
Huntersvllle, NC 28078
(704)875 -9092
Project 08-MAR -0300
Pace Project No 9215521
QC Batch* WET 13406
Analysis,Method SM -2120B
QC Batch Method SM 2120B
Analysis Description, 21206 Color
Associated Lab Samples. 9215521001, 9215521002
METHOD BLANK 90199
Assoclated'Lab Samples 92f5521001-,9215521002
Blank Reporting
Parameter Units
Result Limit Qualifiers
Apparent Color units
IVD 5 0
SAMPLE DUPLICATE 90200
9215521001 Dup Max
Parameter Units
Result Result RPD RPD Qualifiers
Apparent Color units
300 300 0 20 H1
0
Date 04111/2008 09 06 AM REPORT OF LABORATORY ANALYSIS Page 8 of 21
This report shall not be reproduced, except in Tull,
without the written consent of Pace`Analylical Services,; Inc
ocogo

Page 12 of 29
Adobe`Compiled Document
e Pace Analytical Services, Inc Pace Analytical Services, Inc
aceAnalj4ical 2225 Riverside Dr 9800 IQnceyAve Suite 100
sheville, NC 28804 Huntersvllle, NC.28078
wtvwpecelebscam A
(828)254 -7176 (704)875 -9092
i
QUALITY CONTROL DATA
Project- 08- MAR -0300
Pace Project No 9215521
QC Batch WETA/2300 Analysis Method EPA 353 2
QC Batch Method EPA 353,2 Analysis Description 353 2 Nitrate + Nitrite, Unpres
Associated,Lab Samples 9215521001, 9215521002
METHODiBLANK 90329
Associated Lab'Samples 9215521001, 9215521002
Blank Reporting
Parameter Units Result Limit Qualifiers
Nitrogen, Nitrate mg /L NO 010
Nitrogen, Nitrite mg /L NO 010
LABORATORY CONTROL SAMPLE
90330
Parameter
Units
Nitrogen, Nitrate
mg/L
Nitrogen, Nitrite
mg /L
MATRIX SPIKE SAMPLE
90331
Parameter
Units
Nitrogen, Nitrate
mg/L
Ndrogen,,Nitnte
mg/L
Spike LCS LCS % Rec
Cones Result % Rec Limits Qualifiers
5 52 104 90 -110
1 10 103 90 -110
9215521001 Spike MS MS % Rec
Result Conc Result %,Rec Limits Qualifiers,
058 5 56 100 90-110
NO 1 0.97 97 90-110
SAMPLE DUPLICATE' 90332
9215521002 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Nitrogen, Nitrate mg/L 072 071 2 20
Nitrogen, Nitrite mg /L NO NO 15 20
Date' 04/11/2008 09 06 AM REPORT OF LABORATORY ANALYSIS Page 9 of 21
This report'shall nibs reproduced, except In full,
wdhoul the written consent of Pace Analytical Services, Inc

o Pace Analytical Services, Inc
eAnalydbal 2225 Riverside Dr
1171-3C
www.Pacefab.torn Asheville, NC 28804
i (828)254 -7176
QUALITY CONTROL DATA
Project 08- MAR -0300
Pace,Project No . 9215521
QC'Batch WET /3432 Analysls'Method- SM 25400
QG Batch Method. SM 2540D Analysts Description 2540D ToW'Suspended Solids
Associated Lab Samples 9215521001,`9215521002
METHOD BLANK 90950
Associated Lab Samples 9215521001, 9215521002
Blank Reporting
,Parameter Units Result Limit Qualifiers
TotallSuspended Solids mg /L ND 10
Page 13 of 29
Adobe Compiled Document
Pace Analytical Services, Inc
9800 KinceyAve Suite 100
Huntersviffe, NC 28078
(704)875 -9092
LABORATORY CONTROL SAMPLE 90951
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total�Suspended Solids mg /L 250 246 98 80 -120
SAMPLE DUPLICATE 90952
9215380002 Dup
Parameter Units Result Result RPD
Total Suspended Solids mg /L NO , ND 0
Date- 04/11/2008 09 06 AM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
'without the written consent of Pace Analytical Services „Inc
(' C�M� ♦CCC\1
Max
RPD Qualifiers
20
Page 10 of 21
1

Page 14of 29
Adobe' Com piled, Document
a Pace Analytical Services, Inc. Pace Analytical Services,,lnc
6,PakeAna1Xioa1 2225 Riverside Ili 9800 KinceyAve Suite 100
wvx;pa IaMcan Asheville, N0,28804 Huntersville, NC 28078
(828)254 -7176 (704 )875 -9092
QUALITY CONTROL DATA
Project, 08 -MAR -0300
Pace Project No ' 9215521
QC Batch WETA%2314
Analyses Method
EPA 3501
QC Batch Method EPA 3501
Analysis Description
3501 Ammonia
Associated lab Samples 9215521001, 9215521002
9215271002'
METHOD BLANK 91640
MS MS
% Rec
Associated Lab Samples 9215521001, 9215521002
Units
Result
Conc
Blank Reporting
Limits Qualifiers
Parameter Units
Result Limit
Qualifiers
Nitrogen, Ammonia mg /L
ND 0110
9U -110
LABORATORY CONTROUSAMPLE '91641
Spike LCS
LCS % Rec
Parameter Units
Conc Result
% Rec Limits Qualifiers
Nitrogen, Ammonia mg/L
5 ,51
102 90-,110
MATRIX,SPIKE SAMPLE'
91642
9215271002'
Spike
MS MS
% Rec
Parameter
Units
Result
Conc
Result % Rec
Limits Qualifiers
Nitrogen, Ammonia
mg1L
155
5
205 10(l
9U -110
SAM_ PLE�DUPLICATE 91643
9215273001
Dup
Max
Parameter
Units
Result
Result
RPD RPD
Qualifiers
Nitrogen, Ammonia
mg/L
023
022
5 20
Date 04/1112008709 06 AM REPORT -OF LABORATORY ANALYSIS Page 11 of 21
This report shall not be reproduced, except in full;
without the written consent of Pace Analytical Services, Inc
coca

Page 15 of 29,
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oar ® Pace Analytical'Servicos, Inc Pace Analytical Services, Inc
i aceAnalytical 2225 Riverside Dr 9800 KinceyAve Suae 100
vnxvpacefabxcnm Asheville, NC 28804 Huntersviile, NC 28078
7 (928)254 -7178 (704)875 -9092
QUALITY CONTROL DATA
Project 08- MAR -0300
Pace Project No 9215521
QC Batch MPRP /2055 Analysis, Method EPA 200 7
QC Batch Method EPA200 7 Analysis Description 200 7 MET
Associated Lab Samples 9215521001, 9215521002
METHOD; BLANK. 91879
Associated Lab,Samples 9215521001,9215521002
Parameter
Units
Blank
Result
Reporting
Limit Qualifiers
Aluminum
ug /L
ND
100
Antimony
ug/L
ND
510
Arsenic
ug/L
ND
50
Barium
ug/L
ND
5`0
Boron
ug/L"
ND
100
Chromium
ug/L
ND
so
Copper
ug/L
ND
50
Iron-
ug/L
ND
500
Magnesium
ug/L
ND
100
Manganese
ug/L
ND
'50
Molybdenum
ug/L
ND
so
Nickel
ug/L
ND
5,0
Selenium
ug/L
ND
16.0
Thallium
ug/L
ND
100
LABORATORY'CONTROL SAMPLE 91880
Parameter
Units
Spike
Conc
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Aluminum
ug /L
5000
5340
107
85 -115
Antimony
ug /L
500
554
rail
85-115
Arsenic
ug/L
500
570
114
85 -115
Barium
ug/L
500
538
108
857115
Boron
ug/L
500
550
110
85-115
Chromium
ug/L
500
574
115,
85 -115
Copper
ug/L
500
559
-112
85-115
Iron
ug/L
5000
5630
113
85-115
Magnesium
ug/L
5000
5590
112
85 -115
Manganese
ug /L
500
564
113
85 -115
Molybdenum
ug /L
500
557
111
85 -115
Nickel
ug /L
500
574
115
95 -115
Selenium
ug/L
500
563
113
85 -115
Thallium,
ug /L
500
540
108
85 -115
MATRIX SPIKE,SAMPLE
91881
9215384001
Spike
MS
'M8
% Rec
Parameter
Units
Result
Conc
Result
%Rec
Limits Qualifiers
Aluminum
ug/L
4190
5000
14300
202
70-130 MO
Antimony
ug/L
ND
500
612
122
70-130
Arsenic
ug/L
ND
50b
636
127
70-130
Barium
ug/L
465
500
627
116
70-130
Date 04/11/2008 09 06 AM
REPORT OF LABORATORY ANALYSIS
Page 12,of 21
This repot shall not beireproduced, except in full,
without the written consent of Pace Analytcal Services, Inc .

I
Date 04/11/2008 09 06 AM
REPORT OF LABORATORY ANALYSIS
This- report'shall not be reproduced, exceptin full,
without the written consent of Pace Analytical Services, Inc
.ceu,e
Page 13 of 21
Page 16 of 29
Adobe Compiled Document
®
Pace
Analytical Services, Inc.
Pace Analytical Services, Inc
aceMalytkal
2225 Riverside Dr
9800 Kincey Ave Suite `100
Asheville, NC,28804,
Huntersville, NC 28078
wwwpacelabs can
t
(828)254 -7178
(704)875 -9092
QUALITY CONTROL DATA
Project- 08-MAR -0300
Pace Project No 9215521
MATRIX SPIKE SAMPLE
9.1881-
9215384001
Spike
MS MS
% Rec
Parameter
Units
Result
Conc
Result % Rec
Limits Qualifiers
Boron,
ug/L
132
500
620
121
70 -130
Chromium
ug/L
114
500
640
126
70-130
Copper,
ug/L
155
500
645
126
70-130
Iron
ug/L
3280
5000
10060
135
70 -130 MO
Magnesium
ug /L
18600
5000
24900
127
70 -130
Manganese
ug/L
253
500
642
123
70 -130
Molybdenum
ug/L
58
500
623,
123
70-130
Nickel
u6/1-
7 8'
560
634
125
70 -130
Selenium
ug/L
NO
500
626
125
70 -130
Thailium
ug %L
NO
500
565
112
70-130
,SAMPLE DUPLICATE 91882
9215388001
Dup
Max
Parameter
Units
Result
Result
RPD RPD
Qualifiers
Aluminum
ug /L
250
248
81
20
Antimony
ug /L
NO
NO
200
26
Arsenic
ug/L
NO
ND
171
20
Banum
ug /L
ISO
163
2
20
Boron
ug/L
134
11 5
15
20
Chromium
ug/L
NO
NO
27
20
Copper
ug/L
ND
4 3J
1
20
,Iron
ug/L
ND
45 9J
9
20
Magnesium
ug/L
1630
1620
7
20
Manganese'
ug/L
512
50:7
1
20
Molybdenum
ug/L
NO
191
73
20
Nickel
ug/L
ND
ND
39
20
Selenium
ug/L
ND
ND
64
20
Thallium
ug /L
NO
ND
142
20
Date 04/11/2008 09 06 AM
REPORT OF LABORATORY ANALYSIS
This- report'shall not be reproduced, exceptin full,
without the written consent of Pace Analytical Services, Inc
.ceu,e
Page 13 of 21

Page 17 of 29
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/� ,,,, J e Pace Analydcal'Servlces, Inc Pace Analytical Services, Inc
aceAnalytical 2225 Riverside or 9800 KlnceyAve Suite 100
,, _ ' ' Asheville, NC,28804 Huntersville, NC 28078
Pacobs (828)254 -7178 (704)875 -9092
QUALITY CONTROL DATA
Project: 08 -MAR -0300
Pace Project No 9215521
QC Batch WETA/2322
Analysis Method
SM 5220D
QC Batch Method SM 5220D,
Analysis Description,
5220D COD
Associated Lab Samples 9215521001
METHOD BLANK 92264
Associated Lab Samples 9215521001
Blank Reporting
Parameter
Units
Result Limit
Qualifiers
Chemical Oxygen Demand
mg /L
ND 25,0
LgBORATORY`CONTROL SAMPLE
`92265
Spike LCS
LCS
% Rea
Parameter
Units
Conc Result
% Rea
Limits
Qualifiers
Chemical Oxygen Demand
mg/L
750 784
105
90 -110
MATRIX'SPIKE SAMPLE
92266
921552,1001 Spike
MS
MS
%'Rec
Parameter
Units
Result Conc.
Result
% Rea
Limits Qualifiers
Chemicel'Oxygen;Derriand
mg/t.
540 750
823
103
75-125
SAMPLE DUPLICATE' 92267
9215338001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Chemlcal'Oxygen Demand mg1L 713 715 3' 20
r'
Date 04111/2008 09 O6 AM
REPORT OF LABORATORY ANALYSIS
This report shall'not be,reproduced „except In full,
without the written consent of Pace Analytical Services, Inc
rll�c
Page 14 of 21

'Page 18;of 29
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Pace Analytical Services; Inc Pace Analytical Services, Inc:
aceMalydcal o 2225 Riverslde Dr 9800IOnceyAve. Suite 100
-
wwwpacefabscom Asheville, NC 28804 Huntersville, NC 28078
(828)254 -7176 (704)875 -9092
QUALITY CONTROL DATA
Project 08- MAR -0300
Pace Prolect,No , 9215521
QC Batch WETA12328 Analysts Method ASTM D516 -90,02
QC Batch'Method ASTM D516 -90,02 Analysis` Description ASTM D516 -9002 Sulfate Water
Associated Lab Samples 9215521001, 9215521002
METHOD�BLANK 92314
Associated Lab,Samples 9215521001, 9215521002
Blank Reporting
Parameter Units Result Limit Qualifiers
Sulfate mg1L ND 50
LABORATORY CONTROL SAMPLE 92315
Spike LCS LCS, % Rec
Parameter Units Cone Result % Rec Limits Qualifiers
Sulfate mg%L 20 193 96 90 -1101
MATRIX SPIKE SAMPLE-
Parameter
92316
Units
921552101
Result
Spike
Cone
MS MS
Result % Rec
% Rec
Limits- Qualifiers
Sulfate
mglL
151
20
333 91
75-125
SAMPLE DUPLICATE 92317
9215521002
Dup
Max
Parameter
Units
Result
.Result
RPD RPD
Qualifiers
Sulfate
mg /L
159
158
6 20
Date 0411 M008 09 06 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace'Analytical services, Inc.
Page 15 of 21

1acceAnalytical
( w»wpacaritil "
i
Project: 08 -MAR -0300
Pace Project'No 9215521
Pace Analytical' Services, Inc
2225 Riverside Dr
Asheville, NC 28804
(828)2547176
QUALITY CONTROL DATA
QC Batch GCSV/2474 Analysis Method EPA 1664A
QC Batch Method EPA 1664A Analysis Description 1664 HEM, Oil and Grease
Associated Lab Samples 9215521001
METHOD BLANK 93175
Associated Lab Samples 921 5 52 1 0 01
Blank Reporting
Parameter Units Result Limit Qualifiers
Oil and Grease mg /L ND 50
Page 19 of 29
Adobe Compiled Document
Pate Analytical Services,`Inc.
9800 Kincey Ave Sutte 100
Huntersville. NC 28078
(704)875 -9092
LABORATORY CONTROL SAMPLE 93176
Spike L'CS LCS 1W Rec
Parameter Units Conc Result % Rec Limits Qualifiers
Oi6and,Grease mg/L 40 386 96 78 -114
MATRIX SPIKE SAMPLE 93177
9215250005 Spike MS MS %Rec
Parameter Units Result Conc Result % Rec Limits Qualifiers
Oil,and Grease mg/L ND 40 391 94 78 -114
Date 04111/2008'09 06 AM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,,except in full,
without the written consent of Pace Analytical Services, Inc.
Page 16 of,21

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I
®
Pace Anatyt222 u ry
5 R verside Dr 9800 K ncey AveSuite 100
aceAnalytical
wiswpace(abzcorn Asheville, NC 28804 Huntersviile, NC 28078
(828)2547176 (704)875 -9092
QUALITY CONTROL,DATA,
Project 08- MAR -0300
Pace Project'No 9215521
QC Batch. WET /3487 Analysis Method* SM 450OF /C
QC Batch Method SM 4506F /C Analysis DescnpGon. SM4500FC Fluorde*ater
Associated Lab Samples 921 5521 0 01, 9215521002
METHOD BLANK '93266
Associated,Lab Samples 9215521001, 9215521002
Blank 'Reporting
Parameter Units Result Limit Qualifiers
Fluoride mg /L NO 010
LABORATORY CONTROL SAMPLE 93267
Parameter Units
Fluoride mg /L
MATRIX SPIKE SAMPLE- 93268
Parameter Units
Fluoride mg/L
Spike LCS
Conc Result
25 25
9215521001 Spike
Result Conc.
025 2'5
LCS % Rec
% Rec Limits Qualifiers
100 9D-910
MS MS % Rec
Result % Rec Limits Qualifiers
27 98 75 -125
MATRIX SPIKE SAMPLE
93271
9215521002
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc
Result
% Rec
Limits Qualifiers
Fluoride
mg /L
024
25
36
134 75 -125 MO
SAMPLE,DUPLICATE 93.269
9215521601
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Fluoride
mg/L
0'25
0,22
13
20
SAMPLE,DUPLICATE 93270
9215521002
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Fluoride
mg /L
024
076
104
20 06
Date. 04/1112008 09:06 AM REPORT OF LABORATORY ANALYSIS Page 17 of 21
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without the written consent of Pace Analytical Services, Ina

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S Pace Analytical Services, Inc.- PaceAnalytical Services, Inc
dceAnalytical 2225 Riverside,Dr, , 9aoo'KlnceyAve Suite 100,
awivPacelabatxun Asheville, NC 28804 Huntersville, NC 28078
j (828)254 -7176 (704)875 -9092
QUALITY CONTROL DATA
Project: 08 -MAR -0300
Pace Project No 9215521
QC,Batch WETA/2403 Analysis Method, EPA 365.1
QC'Batch Method EPA 3651 Analysis Description 3651 Phosphorus, Total
Associated Lab Samples 921 5 521 001, 9215521002
METHOD'BLANK 97776
Associated'Lab Samples 9215521001, 921552,1002
Blank ;Reporting
Parameter Units Result Limit Qualifiers
Phosphorus mg/L NO 010
LABORATORY CONTROL SAMPLE 97777
Spike LCS LCS' % Rec
Parameter Units Conc Result % Rec Limits Qualifiers
Phosphorus mg /L 1 10 101 90 -110
MATRIX SPIKE SAMPLE_ 97778
9216778001 Spike MS MS % Rec
Parameter Units Result Cone. Result % Rec Limits Qualifiers
Phosphorus mg /L 67 1 7 9 126 90 -110 M3
MATRIX SPIKE SAMPLE 97780
9216487013 Spike MS MS % Rec
Parameter Units Result Conc Result % Rec Limits Qualifiers
,Phosphorus mg %L 10 1 23 128 90-110 M3
SAMPLE DUPLICATE 97779
9216778002 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Phosphorus mg/L 12 1 1 1 20
SAMPLE DUPLICATE 97781
9216487014 Dup
Parameter Units Result Result RPD
Phosphorus mg/L 098 098 08
Date. 04 /11/2008 09 06 AM REPORT OF LABORATORY ANALYSIS
This feport shelf not be reproduced, except In full,
without the written consent of Pace Analytical Services, Inc
Max
RPD Qualifiers
20
Page 18 of 21

® Pace Analytical Services, Inc.
I, aceMalytical 2225 Riverside Ix.
wwwpaceiabs.com Asheville, NC 28804
(828)254 -7176
I
QUALITY'CONTROL DATA
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Pace Analytical Services, Inc
9800 Kincey Ave Suite 100
Huntersvllle „NC 28078
(704)675 -9092
ti
'Project 08'MAR -0300
98083
Pace Project No 9215521
9215521001
Spike
MS
QC Batch WETA/2414
% Rec
Analysis,Method
EPA351 2
Result
Conc
QC Batch,Method EPA 3512
% Rec
Analysis Description'
3512 TKN
mg/L
14
Associated,Lab`Samples 8215521001,
9215521002
88
90 -110 M3
SAMPLE DUPLICATE 97935
METHOD BLANK 97932
Associated Lab Samples 9215521001,
9215521002
Dup
Max
Parameter
Units
Blank Reporting
Result
RPD
RPD
Parameter
Units
Result Limit
Qualifiers
704
6
Nitrogen, Kjeldahl, Total
mg /L
ND 0150
LABORATORY CONTROL SAMPLE
97933
9216739005
Dup
Spike LCS
LCS
% Rec
- Parameter
Parameter
Units
Conc Result
% Rec
Limits
Qualifiers
Nitrogen, Kjeldahl, Total
mglL
5 . 51
102
90 -110
20
MATRIX SPIKE SAMPLE
97937
9216739006 Spike
MS
MS
%'Rec
Parameter
Units
Result Conc
Result
% Rec
Llmits Qualifiers
Nitrogen, Kjeldahl, Total
mg /L
12 5Y
158
93 90 -110
'MATRIX SPIKE,SAMPLE
98083
9215521001
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc
Result
% Rec
Limits Qualifiers
Nitrogen, Kjeldahl, Total
mg/L
14
5
5t8
88
90 -110 M3
SAMPLE DUPLICATE 97935
9216560001
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Nitrogen, Kjeldahl, Total
mg /L
749
704
6
20
SAMPLE DUPLICATE 97936
9216739005
Dup
Max
- Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Nitrogen, Kjeldahl, Total
mg/I
"19
16
20
20
Date '04111/2008 09 06 AM REPORT OF LABORATORY ANALYSIS Page %of 21
ThisIreport shall not be- reproduced, except In'full,
without,the written consent or Pace Analytical Services, Inc
:i��=

®, Pace Analytical Services, Inc
aceMagical 2225 Riverside' Dr
rwnvpacelabxcom Asheville, NC 28804
! (828)254 -7176
i
QUALIFIERS
Project 08- MAR -0300
Pace Project No 9215521
Page 23 of 29
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Pace Analytical Services, Inc
9800 KinceyAve Sude 100
Huntersville, NC 28078
(704)875 -9092
DEFINITIONS
DF - Dilution Factor, if reported,, represents the factor applied to the reported data due to changes In sample preparation, dilution of
the sample;aliquot, or moisture'content
ND�z Not Detected,at or above adjusted reporting limit
J -Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
MDL -Adjusted Method Detechon Limit
S - Surrogate
1,2-'Diphenylhydrazine (8270 listed anaiyte) decomposes to Azobenzene
Consistent with, EPA gurdelines,,unrourided datarate displayed an&have been used to calculate % recovery and RPD values
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative'Percent Difference
NC - NotlCalculable
Pace Analytical is NELAP accredited Contact your Pace PM for the,current list of accredited analytes
SAMPLE QUALIFIERS
Sample 9215521001
[1j Run ndrate,and color outside of hold time,per,dlent request
Sample 9215521002
[1] Run nitrate and color outside of hold time per client request
ANALYTE QUALIFIERS
'D6 The relative percent, drfference (RPD) between the sample and sample duplicate exceeded laboratory control limits
H1 Analysis conducted outside the EPA method holding time
MO Matrix spike recovery was outside laboratory control limits
M3 Matrix spike recovery was outside laboratory, control Iimrts,due to matdxwinterferences
e
Date 04/11/2008 09.06 AM
REPORT'OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of'Pace Arialytical Services, Inc..
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® Pace Analytical Services, Inc. Pace Analytical Services, Inc
i - ,aceA nalXical 2225 Riverside Dr 9800 Klncey,Ave Suite 100
wrvwpaeekb1com Asheville. NC 28804 Huntersvllle, NC 28078
(828)254 -7176 (704)875 -9092
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project 08- MAR,0300
Pace,Prolect No 9215521
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
9215521001
28007140
SM 2120B
WET /3406
9215521002
28007141
SM 2120B
WET /3406
9215521001
28007140
EPA 353 2
WETA/2300
9215621002
28007141
EPA 353 2
WETA/2300
9215521001
28007140
SM 2540D
WET13432
,9215521007
28007141
SM 2540D
WET/3432
9215521001
28007140
EPA 3501
WETA/2314
9215621002
28007141
EPA 350 1
WETAY2314
,9215521001
28007140
EPA 200 7
MPRP /2055 EPA 200 7
9215521002
28007141
EPA 200 7
MPRP /2055 EPX200 7
9215521001
28007140
SM 52200
WETA/2322
9215_521001
28007140
ASTM D516 -90,02
WETA/2328
,9215521002
28007141'
ASTM'D516 -90,02
WETA12328
9215521001
28007140
EPA 1664A
GCSV /2474
9216621001
28007140
SM 450CF /C
WET/3487
9215521002
28007141
SM 4500F /C
WET/3487
9215521001
28007i40
EPA 3651
WETA/2403
9215521002
28007141
EPA 365,1
WETA/2403
9216521001
28007140
EPA 3512
WETA/2414
9215521002
28007141
EPA 351 2
WETA/2414
Date, 04/11/2008 09 06 AM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of, Pace Analytical Services, Inc
Analytical
Batch
ICP/1995
ICP/1995
Page 21 of 21

Sample,Admowledgement Recipients
Duke Energy
Mr..Jay Perkins
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersvllle, NC 28078
Phone. [phone]
Email labcustomer @duke - energy com
Duke Energy
Mr. Terry Whitner
13339 Hagers Ferry Road
Bldg 7405 MG30A2
Huntersville, NC 28078
Phone: [phone]
Email' labcustoiner @duke- energy.com
Line Item Descriptions*
(13] Mill 'Creek NPDES
Sample Receipt Form
Pace,Analytical Services, Inc.
Charlotte
Bill to.
Duke Energy Carolinas, LLC
Accounts Payable DPEHS
PO Box 37929
DPEHS
Charlotte, NC 28201
Final Report Recipients
'Duke Energy Carolinas, LLC
Accounts Payable DPEHS (Primary)
PO Box 37929
DPEHS
Charlotte, NC 28201
Phone: [phone]
Duke Energy
Mr Jay ^Perkins
13339,Hagersfery Road
Bldg. 7405 MG30A2
Hunt&sviile, NC 28078
Phone- (704)875 -5348
Email.,labcustomer @duke - energy corn
�Page,25 of, '29
Adobe Compiled Document
ace,nalyiical
'�.mcwabsc
3Ar�
Client P O No: iSW01 0000000341 Lab ProlecfNo: 9215521
Phone. [phone] Project Deliverables Type: Standard Report
Project Manager: Kevin Herring Project Report Due Date 03/26/08
Cbent,Project ID• Sampling 3/,15- Profile: 827
Lab Smp ID; 9215521001 CilentSmp1D: 280071140 (% 0�l Collectsd,Datw03116 /0&0930'
Pro] Smp No. 1 Matrix Water Smp Type PS Line Item: 13 Received:Date.`03/17 /08 10.50
Comments (1] c
Auxiliary Data. NOTE
Subout info: SOWET =Color 5001= Bromide Notes'for Login: Color /MBAs- >Statesviije $2514
S002= Sulfite S003 =MBAS Bromide /Sulfite- >Envirochem$
PARAMETER METHOD UNIT PRICE WR SPL %
2540D W —25400 Total Suspended Solids _ SM 2540D $1200
3501 W - 350.1 Ammonia EPA 350.1 $2100
2007 W - 200 7 MET ICP EPA 200 7 $10000
COMPOUND
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel'
Silver
Zinc
PQL UNITS
100 ug1L
5 ug /L
5 ug /L
5 ug /L
1 ug/L
10 ug/L
1 ug/L
5 ug/L
5 ug/L
5 ug/L
50 ug/L
5 ug /L
100 ug /L
5 ug /L
5 ug/L,
`5 ug/L
5 ug/L
10 ug/L
Monrinv Marrh 17 20r)A 1.16 5I PM n n n n°i, Page 1 -of 4'

PARAMETER
Sample Receipt Form
Pace Analytical Services, Inc.
Charlotte
METHOD
Page 26, of 29
Adobe Compiled Document
8C$AllalytiC!®
UNIT'PRICE WR SPL
COMPOUND PQL UNITS
Thallium 10 ug/L
Titanium 5 ug/L
Tin 5 ug /L
Selenium 10 ug/L
2451 W92 - 245.1 Mercury
EPA 245.1
$20.00
4500FC W - 4500FC Fluoride
SM 4500F /C
$12:00
1664 W92 - HEM, Oil and Grease
EPA 1664A
$45.00
SI =38RAD - Subbed work within PASI,RAD
$165.00
IR38 20
2120B W - 2120B W Apparent Color
SM 21206
$2500
3532 W - 353.2,Nitrogen, NO2IN03 unpres
EPA 353 2
$2400
COMPOUND PQL UNITS
Nitrogen,,Ndnte 01 mg /L
Nitrogen:, Nitrate 01 mg /L
D516SO4 W -ASTM 0516 -9002 Sulfate Water
ASTM 13516 =90,02
$2200
Sub Total - Sample 89590
$,446 00
Lab Smp ID: 9215521002 Client Smp,ID: 28007141
Collected Date:;03 118/08 09.30
Proj Smp No 2 Matrix: Water
Smp Type PS
Line Item. 13
Received Date* 03/17/08 10:50
Auxiliary Data: NOTE
Subout info, SOWET =Color 5001= Bromide
_
Notes for Login
Color /MBAS- States, $2514
S002= Sulfite SO03 =MBAS
PARAMETER
2540D W - 2540D Total Suspended Solids
3501'W-,3501 Ammonia
2007 W = 200 T MET ICP
COMPOUND _
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
,Nickel
Silver
Zinc
Thallium
Titanium
Tin
Selenium
2'451 W92 - 245.1 Mercury
4500FC W - 4500FC Fluoride
2120B W - 21209 W Apparent Color
3532,W'= 353.2 Nitrogen, NO21NO3,unpres
PQL UNITS
100 ug /L
5 ug /L
5 ug /L
5 ug/L
1 ug /L
10 ug/L
1 ug/L
5 ug /L
5 ug/L
5 ug /L
50 ug /L
5 ug/L
100 ug/L
5 ug/L
5 ug/L
5 ug /L
5 ug/L
10 ug /L
10 ug /L
5 ug /L
,5 ug /L
10 ug/L
Bromide /Sulfite- >E
METHOD UNIT PRICE WR SPL
SM 2540D $1200
EPA 350.1 $2100
EPA 200 7' $100 00
EPA 245 1
SM 450OF /C
SM 2120B
EPA,353.2
n
$2000
$12:00;
$2500
$2400
Page 2 of 4
nnr,n,42w March 17 WR 1 1 R 94 PM n AM n n n P

Sample Receipt Form
Pace Analytical Services, Inc.
Charlotte
PARAMETER
COMPOUND PQL UNITS
Nitrogen, Nitnte 0.1 mg/L
'Nitrogen, Nitrate 0 1 mg/L
METHOD
Page 27 -of 29
obe Compiled Document
aceAnalyfical
wwwpec'eaeacom
C� I -" 1 f
UNIT PRICE WR SPL %
D516SO4 W- ASTM "D516 -9002, Sulfate Water ASTM10516 -90,02 $2200
5310B W - 5310B TOC SM 53106 $3700
Sub Total - LSample 69591 $27300
m6-- ctfiO3
Grand Total - Project 9215521 $719.00
Unit Pricing above does not reflect associated shipping, bottle, sample disposal and other miscellaneous charges Prices
are,sublect,to change without,notice Contact your`Project Manager for further Information
Monday, March 17. 2008 Page 3 of,
1 16 54 PM n n n n n n 7 4

Page 28 of 29
Adobe Compiled Document
I--," MEMUMIMMUMM-322=
�aceAralytical
Client Name_._OuKG ,6Ly_,1 Proiect #
Courier: 'E] Fed Ex 0 UPS ❑ USPS ❑, bent ❑ Commercial O P Op �yc� r.•,� �` y,; �`
ace Othe? flog f a r
- N'lY <Date. ! K
Custody Seal on.Cooler /Box Present yes ❑ no Seals Intact ❑yes [�no�P",w�, `Y
Packing Material ❑ Bubble Wrap ❑Bubble Bags ❑ None 90ther
Thermometer Used T060 Type of Ice. 6(4e Blue None rvl samples,on'rce, coolmgiprocess has begun
Cooler Temperatur
Temp should be above freezing to 6'C
Biological Tissue is Frozen" Yes No NIA
Comments'
Date and Initia o ,person mining
contentsWEZ
Chain of Custody Present
Y ONo
ONIA
1
Chain of Custody Filled-Out
E& ❑No
ONIA
2"
Chain of Custody Relinquished
Yes ❑No
❑NIA
3
Sampler,Name & Si nature on COO
Oyes ,U Mo
ONJA
4
Samples Arrived within Hold Time
Oyes 9110
ON /A
5 &0
Short °Hold Time Analysis ( <72hr)
' s 0 N
ON /A
6
Rush Turn Around Time Requested
OYes b o
❑N /A
7
Sufficient Volume
Oyes No
ON/A
�1
8 �S �u 0 ZS6 1
Correct Containers Used
-Pace Containers -Used
Dyes 1�;Ko
Dyes IIIJNo
ON /A
❑NIA
1r
9 COJO/- L S' �1-'f M 1
j SS L'
Contai nets 1ntact
Yes ONo
ON! A
10
Filtered volume received for Dissolved tests
Oyes ONo
N /A,
11 Gr,(tb
Sample Labels match COC_
❑yes
ON /A''12
�,IJV Q' co -� L� ov �{ '
i
c i k aN '
All containersmeeding p(eservalion have been checked,.
All containers needing preservation are found to be in
compliance with EPA,recommendabon
exceptions VOA, coldorm TOC, O &G, W60RO (water)
��,{(
,YJYes ONo
Yes ONo
Dyes ONo
❑N!A
ON /A
13
initial when completed
Samples,checked for,dechlodnation
Yes ONO
ONI&
14
Headspace;in VOA Vials >6mm)
OYes ONo
56,11A
15
Trip Blank Present
Trip Blank Custody Seals Present
Pace Trip Blank Lot`# (if purchased)- N/A
Dyes ONo
Oyes ONo
,J1j,�/A
tLr1N /A
r16
Client Notification/ Resolution: Field Data Required? Y / N / NIA
Person Contacted �Qd' DatelTime' e lai(
Comments/ Resolution � f �f S� � and _
% f 4 b e � rS,d'1 e,(,1? �2_ 9 0 0 W
Project Manager Review Date. i3i J7 f O
Note Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR
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Page 1 of 36
Analytical Laboratory
fimm
DiliC@ Analytical Laboratory
Fw
FnCI'��/® H 13339 Hagers Ferry Road
untersville, NC 28078=7929
Rev07-09-07 McGuire Nuclear Complex — MG03A2
Phone: [phone] Fax 704 - 875 -5038
Job Summary Deport
Job Number: 08- APR -0113
Project Name:
Customer Name:
Copy To:
Customer Address:
Storm Water
Nob Zalme
Brandy Starnes
Buck
MG03A3
Lab Contact: Mary Ann Ogle
Lab Contact - Phone:. [phone]
Report Authorized By:
(Printed Name)
MARY ANN OGLE
Report Authorized By:
(Signature) Date: 5 i O $
,Data Package
This data package includes analytical, results that are applicabl'e onlyAq the samples
described in this narrative. An estimation of the uncertainty of measurement for the
results in the report, is available upon request. This report°shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the
Analytical Laboratory with any questions. The order of individual, sections within this
report is,as follows:
Job Summary Report
Analytical Laboratory Certificate of Analysis
Analytical Laboratory,QC Reports (if applicable)
Sub - contracted Laboratory Results
Customer, Specific Data Sheets, Reports & Documentation rif applicable)
Customer Database Entries
Test, Case Narratives
Chain of Custody,(COC)
r

Job Summary Report
Certification
The Analytical Laboratory holds the following Certifications:
New York State Department of Health Cerl f cation # 1171,7(NELAC)
North Carolina Department of Health, & Human Services Certification # 37804
South, Carolina,(D& Q Laboratory ID #99005
North, Carolina (DENI) Certification # 248
Analytical results listed in this report may not be certified by the authorities referenced above.
Contact the Analytical Laboratory,fordefnttive information about the certification status of
specific methods. The results meet all requirements of NELAC except where deviations are
noted in this report.
Data Flags
Any analytical tests or individual analytes within a test flagged with an "X" or a "1" indicate a
deviation from the method quality system,or quality control requirement.
Calculations
All results'are,reported on a wet weight basis unless�otherwise noted.
Sammie ID's & Descriations:
Page.2 of 36
Collection
Analytical Laboratory
i ,Dake
Analytical Laboratory
dfEnergy�
Hagers Ferry Road
Plant /Station
H13339
untersvdle, NC 28078 -7929
Rw07 -03 07
McGuire Nuclear Complex— MG03A2
i
Phone: [phone] Fax, 704 -875 -5038
Job Summary Report
Certification
The Analytical Laboratory holds the following Certifications:
New York State Department of Health Cerl f cation # 1171,7(NELAC)
North Carolina Department of Health, & Human Services Certification # 37804
South, Carolina,(D& Q Laboratory ID #99005
North, Carolina (DENI) Certification # 248
Analytical results listed in this report may not be certified by the authorities referenced above.
Contact the Analytical Laboratory,fordefnttive information about the certification status of
specific methods. The results meet all requirements of NELAC except where deviations are
noted in this report.
Data Flags
Any analytical tests or individual analytes within a test flagged with an "X" or a "1" indicate a
deviation from the method quality system,or quality control requirement.
Calculations
All results'are,reported on a wet weight basis unless�otherwise noted.
Sammie ID's & Descriations:
Collection
Sample
Sample ID
Plant /Station
Date
Collected By
Description
28009011
FOSSIL
04/04/2008
B.
STARNES
BUCK SW 02
(GRAB)
28009012
FOSSIL
04/04/2008
B.
STARNES
BUCK SW 02
(COMP)
28009013
FOSSIL
04/04/2008
B.
STARNES
BUCK SW 03
(GRAB)
28009014
FOSSIL
04/04/2008
B.
STARNES
BUCK SW 03
(COMP)
-----------------
4 TOTAL SAMPLES

?6"Energy.
Duke
Pa 07 -03-07
Analytical Laboratory
13339 Hagers Ferry Road
Huntersville, NC 28078 -7929
McGuire Nuclear Complex — MG03A2
Phone: 704 - 875 -5245 Fax: 704 - 875 4038
Job Summary Report
Validation of Analytical Data Package
COC and .pdf report are in agreement with sample totals
i and analyses (compliance programs and,procedures).
ii) All,results are less than the laboratory reporting limits.
iii) All laboratory QA/QC requirements are acceptable.
NPDES and TCLP results are below permit or regulatory
iv) limits respectively.
If iv above,is No, document below:
Petmlt
Variable Result Limit Notes
Page 3 of36
Analytical1aboratory
Id• Yes
r. "No
Yes
ffNo
Yes
Eo
� Yes
1W No
Components of the Job Summary Report arranged in order
v) stipulated on page one. Yes EE
Indicate components included:
1✓
Job °Sununary Report
(--
Customer,Specific Data Sheets, Reports &
Documentation (if applicable)
1"
Analytical Laboratory Certificate of
r
Customer Database Entries
Analysis
Analytical Laboratory QC Report
(if applicable)
r
Test Case Narratives
Iv,
Sub - contracted Laboratory Results
fv—o I
Chain of Custody
vi) Notes and Additional Information
The Laboratory Control Sample (Glucose /Glutamic Acid) recovery (76 %) for BOD analysis, was
outside acceptable QC limits (84- 115 %). A corrective action was started to�investigatelhe
failure. All results for BOD should be considered estimates. The fecal coliform result for SW02
was flagged because the lab was unable to filter an adequate sample volume. Fecal Coliform
results,for SW02 should be considered estimates.
Mary Ann Ogle
Duke Energy Analytical Lab
NPDES Contact
'7A A 017C C'1 ^7 A
NA =Not applicable

aceAnalyikal
i
wwwaacW8bs.c0m
May 02, 2008
Mr. Jay °Perkins
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
RE Project 08- APR -0113
Pace Project No.: 9216758
Pace Analytical Services, Inc
2226 Riverside Dr
Asheville, NC 28804
(828)2547176
Page4 of 36
Analytical Laboratory
Pace Analytical'Services, Inc
9800 Kincey Ave Suite 100 -
Huntersville, NC 28078
(704)875 -9092
.Dear Mr. Perkins. -
Enclosed are the,analytical results for sample(i) received by the laboratory on April 04, 2008. The
results relate only to the samples included In this report. Results reported herein conform to the
most current, NELAC standards, where applicable, unless otherwise narrated In the bodyof the
report.
Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and
Organic,testing was performed at our Pace Huntersville laboratory unless,otherwise footnoted. All
Microbiological analyses were performed at the laboratory where the samples were received.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
kevin hernng @pacelabs.com
Project Manager
Enclosures
cc Accounts Payable DPEHS, Duke Energy Carolinas; LLC
REPORT'OF LABORATORY ANALYSIS Page 1 of 26
This report shall not be'reproduced, except in full,
without the written oonsent of Pace Analyhcal`Services, Inc
ceo„

-- - -- - - - -- - --
- — - - --- - --- -�_ -- -- - -- - -
- - - .... —Page 5 of 36
Analytical Laboratory
e
Pace Analytical Services, Inc Pace Analytical
Servlae`, Inc.
aceAna"ca!
2225 Riverside Dr 98001(incey Ave Sude 100
wWWpaC*W &com
Asheville, NC,28804
Huntersville, NC 28078
I
[phone]
(704)8759092
CERTIFICATIONS
Project 08-APR -0113
Pace;Project No 9216758
Charlotte Certification IDs
Flonda/NELAP Certification Number.'E87627
North,Carolina,Field Servlces Certification Number 5342
Kansas Cerbficab6n,Nurribei-'.E40364
South Carolina Certification Number 990060001
Lonlsana /LELAP Cerbfrcatlon Number 04034
South Carolina 13roassay'Certifrcation Number 990060003
North Carolina Drinking Water Certtficabon Number 37706
Tennessee Certification Number 04010
North Carolina Wastewater Cerbficatran Number 12
Yrginla Certification Number 00213
Asheville`Certification, IDs
Flond_a/NELAP Certification NumberE87648
Pennsytvama Certification NumberB8-03578
Louisiana/LELAP Certification Number 03095
South Carollna CerdficatiomNumber 99030001
New Jersey Certification Number NC011
South Carolina Bioassay Certification Number 99030002
North Carolina Drinking Water Certification Number 37712
Tennessee,, Certification Number 2980
North Carolina Wastewater Certification Number 40
\Argmia Certification Number,00072
'North Carolina Bioassay Certification Number 9
,Eden Certification IOs
North Carolina Drinking'Water,Certdication Number 37738
North,Carolma Wastewater Certificatiom Number 633
Virginia Drinking Water Certification Number 00424'
REPORT OF LABORATORY ANALYSIS Page 2 of,26
This report shall not be reproduced, exoW In full,
wilhout the wnttan consent of Pace Analytical Services, Inc

I
laceAnalytkat'
wtwrpecelahscbm
t
Project 08- APR -0113
Pace Project No • 9216758
PaceAna"cah Services, Inc.
2225 Riverside Or
Asheville, NC 28804
(828)2547178
SAMPLE SUMMARY
Lab'ID
Sample,ID
Matiiit
Date Collected
Date Received
9216768001
28009011
Water
04/04/08 09 00
04/04/08 13 32
9216758002
28009012
Water
04/04/08 d9 00
04/04/0813 32
9216758003
28009013
Water
04/04108 09 OU
04/04/0813 32
9216758004
28009014
Water
04/04/08 09.00
04/04/08 13:32
REPORT OF LABORATORY ANALYSIS
This report-shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Ina•
�11L- L�i7aS.l
Page.6 of 36
Analytica I' Laboratory
Pace Analytical Services, Inc.
9800,KmceyAve Suite 100
Hunteraville, NC 28078
(704)e75 -9092
Page 3 of 26

1
I
_ 1 aceAnalyiical
WWW- 00e10bsccrn
i f
SAMPLE ANALYTE,COUNT
Project
Pace Project No
Pp%07 of 36
Analytical ' Laboratory
Pace Analytical Services, Inc
Pace Analytical Services, Inc.
2225 Wverside Dr
9800 KrnceyAve Suite 100
Asheville; NC 28804
Huntersvrlle, NC 28078
(828)254 -7176
(704)87619692
SAMPLE ANALYTE,COUNT
Project
Pace Project No
08- APR -0113
9216758
Analytes
Lab11D
Sample ID
Method
Analysts,
Reported
9216758001
28009011
EPA 3501
EWS
1
EPA 353'2
RAB
1
SM,2120B,
JDA
1
SM,5210B
MJR
1
SM 9222D
KDF
1
9216758002
28009012
EPA 350 -1
EWS
1
EPA 353 2
RAB
1
SM 21206
JDA
1
SM 5210B
MJR
1
9216758003
28009013
ASTM D516 -90
SER
1
EPA 1664A
DVS
1
EPA 200 7
SAJ
14
EPA 3501
EWS
1
EPA 3512
EWS
1
EPA,353 2
RAB
1
EPA 365 1
'EWS
1
SM 2120B
JDA
1
SM'2540D
DMN
1
SM 4500F/C
RAB
1
SM,5210B
MJR
1
SM 5220D
MJR
1
i
SM 9222D
KDF
1
9216758004
28009014
ASTM D516 -90
SER
1
EPA 200.7
SAJ
14
EPA 3501
EWS
1
EPA 351 2
EWS
1
EPA 353'2
RAB
1
EPA 3651
EWS
1
SM 2120B
JDA
1
SM 2540D
DMN
1
SM 450OF /C
RAB
1
SM 5216B
MJR
1
SM 5220D
MJR
1
REPORT OF LABORATORY'ANALYSIS, Page 4 of 26
This report shall not be reproduced, except in full,
without the written oonsent of Pace Analytical Services, Inc,
°UC��1

e Pace Analytical Services, Inc.
a MaiXical 2225 Riverside Dr
wwwpscemsccm Asheville. NC 28804
(828)254 -7176
ANALYTICAL RESULTS
Page 8 of,36
Analytical �La boratory
Pace Analytical Services, Inc.
9800 Kinoey Ave 'Suite 100
Huntersvills. NC 28078
[phone]
Project 08- APR -0113
Pace Project, No 9216758
Sample: 28009011
Lab ID: 9216758001 Collected
04/04/08 09 00.
Received 04/04/0813 32 Matnx'Water
Report
Parameters
Results Units Limit
MDL DF
Prepared Analyzed CAS;No. Qual
MBIO 9222D Fecal Collform CHT
Analytical Method. SM 9222D
Fecal Coliforms
29.0 CFU /100'mL 10
1
04/04/0814 21 ul '
2120B W Apparent Color
Analytical Method SM 2120B
Apparent,Color
30.0 units 5'0
1
04/06/08 08 45
52108 SOD, Low Level
Analytical Method SM5210B
BOD, 5 day
3.8 mg /L 20
1
04/05/08 07 30 04/10%08 11 25 B4
350.1,Ammonia
Ana"cal,Method EPA 3501
Nitrogen, Ammonia
0.37 mg /l- 010
010 1
041,15/08 13 03 7784 -41 -7
353.2 Nitrogen, NO2/NO3 pros.
Analytical Method EPA 3632
Nitrogen; NO2 plus NO3
0.99 mg /L 010
0 110 1
041,11/0817 00
►i
Date' 05/02/2008 12 48 PM REPORT OF LABORATORY ANALYSIS Page 5 of 26
This'repart shall not be reproduced, except In full,
Wnthout the written consent of Pace Analytical Services, Inc.
�ppyy���z

ANALYTICAL RESULTS
Project 08- APR -0113
Page 9 of 36
i
Analytical Laboratory
® PaceAna"cal Services, Inc
Pace AnalyNeal'Services, Inc
aceAnalXicaf 2225 Riverside Or
9800 IQnceyAve Suite 100
wwwpec 18bScom -Asheville, NC 28804
Hunterswlle,,NC 28078'
(828)2547178
(704)875 -9092
ANALYTICAL RESULTS
Project 08- APR -0113
Pace Project No 9216758
Sample: 28009012
Lab ID: 9216758002 Collected
041041086900
Recerved.� 04/04/081332 Matrix Water
Report
Parameters
Results Units Limit
MDL DF
Prepared Analyzed CAS No Qual
2120B W Apparent Color
Analytical Method SM 2120B
Apparent Color
ND units 50
1
04/06/08 08 45
5210B SOD, Low Level
Analytical Method* SM 5210B
80D „5 day
2.0 mg/L 2 0
1
04/05/08 07 30 04/10%08 1125 84
360.1 Ammonia
Analytical Method EPA 350 1
Nitrogen, Ammonia
0.45 mg /L 0110
010 .1
04/15/0813 04 7764141 -7
353.2 Nitrogen, NO2/NO3 pros.
Analytical Method EPA 353 2
Nitrogen, NO2 plus NO3
1.2'mg /L 010,
010 1
04/11/08 17 00
Date. 05102/200812 48 PM REPORT OF LABORATORY ANALYSIS
This,report shall not be reproduced, except In,full,
without the written consent of Pace Analytical Services, Ina
°act;
Page 6 of 26

fl
aceAnalytical
I wwr�.pacela(rs com
r
ANALYTICAL RESULTS
Project: 08- APR -0113
Pace Project No 9216758
Page 10 of 36
Analytical Laboratory
Pace Analytical Services, Inc
Pace Analytical Services, Inc
2225 Riverside Dr
9800 Kincey Ave, Suite 100
Asheville, NC 28804
tiuntersville, NC 28078
(828)254 -7178
(704)875 -9092
ANALYTICAL RESULTS
Project: 08- APR -0113
Pace Project No 9216758
Sample: 28009013
Lab ID: 9216758003 Collected` 04/04/080900
Received 04/04/08,13,32 Matmr-Water
Report
Parameters
Results Units Limit'
li
OF
Prepared
Analyzed CAS,No Qual
HEM, Oil and Grease
Analytical Method EPA 1664A
016and Grease
ND mg /L 5 0
1 1
1
04/17/0816 56
200.7 MET ICP
Analytical Method EPA 200 7 Preparation
Method EPA 200 7
Aluminum
5850 ug /L 100
250
1
04/07/08 11 56
04/10/08 13 56 7429-90 -5
Antimony
ND ug/L 5 0
2 6
1
04/0710811.56
04/10108 13 56 7440136 -0
Arsenic
13.0 ug/L 510
2.7
1
04/07/0811 56
04/10/0813.56 7440 -38-2
Banum
62.3 ug/L 5 0
020
1
04/07/0811 56
04/10/0813 56 7440 =39 -3
Boron
7,0'.1 ug /L 100
4.7
1
04107/0811 56
04/10/0813 56 7440 -42 -8 ,
Chromium
6.9 ug/L 5 0
040
1
04/0710811 56
04110/08'13 56 7440 -47 -3
Copper
52.2 ug/L 5 0
0 30
1,
04/07/08 11 56
04/10/0813 56 7440 -50 -8
Iron
3230 ug /L 50 0
140
1
04/07/0811 56
04/10/08 13 56 7439 -89 -6
Magnesium,
790 ug/L 100
30
1
04/07/0811 56
04/10/08 13 56 ,7439 -95-4
Manganese
616 uglL 50
030
1
04/07/08 11 56
04/10/08 13 56 7439 -96 -5
Molybdenum
5.9 ug/L so
1,1
1
04/07/08 11 56
04/10/08 "13.56 7439 -98 -7
Nickel
19.3 ug/L 50
1.7
1
04/07/08''11 56
04/10/08'13 56 7440 -02 -0
Selenium
157 ug/L 100
38
1
04/0710811 56
04/10/0813 56 7782 -49 -2
Thallium
ND ug /L 10.0
30
1
'04107108.1156
041,10/0813 56 7440 -28-0
MBIO 9222D Fecal Collform CHT
Analytical Melhod'�SM 9222D
Fecal Coliforms
200 CFU /100 mL 10
1
04/04108 14 21
21208 W Apparent Color
Analytical Method ,SM 2120B
Apparent Color
40.0 units 50
1
04/06108'08 45
2640D Total'Suspended Solids
Analytical Method- SM 2540D
Total Suspended Solids
159 mg /L 40
1
04/10/08 17 39
45WFC Fluoride
Analytical Method. SM 450OF /C
Fluoride
0:53 mg/L 0.10
010
1
04/08/0818.00 16984 -48-8
6210B BOD, Low Level
Analytical Method' SM 52106
BOD, 5-day
10.8 mg/L 20
1
04/05/08 07 30
04/10/08 1126 B4
350.1 Ammonia
Analytical Method -EPA 350 1
Nitrogen, Ammonia
1.4 mg/L 0'10
0110
1
04/15/081305, 7764 -41 -7
351.2 Total KjeldahLNitrogen
Analytical Method ,EPA 3512
Nitrogen, Kjeldahl, Total
4.2 mg/L 0 50
050
1
04/16/08 15 18 7727 -37 -9
i
353.2 Nitrogen, NO2/NO3 pros.
Analytical Method EPA,353 2
Nitrogen, N021plus NO3
3.8 mg /L 0,10
010
1
04/11/081,7 00
365.1 Phosphorus, Total
Analytical Method EPA 3651
Phosphorus
0.32 mg /L 010
010
1
04/15/0815 33 7723 -14 -0
Date, 05/02/2008 12 48 PM REPORT OF LABORATORY ANALYSIS Page 7 of 26
This report shall not be reproduced, except In full,
without the written, consent of Pace Analytical Services, Inc.

ace Analytical
vmvwpacefab&WM
r
t
Paco Analytical Services, Inc.
2225 Riverside Dr
Asheville, NC 28804
(828)254 -7178
ANALYTICAL RESULTS
Page 11 of 36
Analytical Laboratory
PaceAnalyflcal Services, Inc.
9800 Kincey Ave Suite 100
Huntersville. NC'28078
(704)875 -9092
Date-05 /0212008 12 48 PM REPORT OF LABORATORY ANALYSIS Page 8 of 26
This report shell not be reproduced, except in full,
without the written consent of Pace Analytical Services Inc
Project 08-APR -0113
Pace Project No 9216758
Sample. 28009013 Lab ID: 9215768003 Collected 04/04/08 09.00
Received 04104/08 13 32 Matrix Water
Report
Parameters
Results Units Limit
MDL DF
Prepared Analyzed CAS No Qual
5220D COD
Analytical Method SM 5220D
Chemical Oxygen Demand
142 mg /L 250
250 1
04/10/0817 23
,ASTM 0516 -90 Sulfate.Water
Analytical Method ASTMD516 -90
Sulfate
12.9 mg1L 50
50 1
04108/08 15 20 14808 -79-8
Date-05 /0212008 12 48 PM REPORT OF LABORATORY ANALYSIS Page 8 of 26
This report shell not be reproduced, except in full,
without the written consent of Pace Analytical Services Inc

e
1�acek7a"Ml
/ - wwripw"Moom
i
Project 08- APR -0113
Pace Project'No 9216758
Page 12 of,36
Analytical Laboratory
Pace Analytical Services,'lnc. Pace Analytical Services, Inc
2225 Riverside Dr 9800 IOncey Ave Suite 100
Asheville, NC 28804 Huntersville, NC 28078
" (828)254 -7176 (704)875 -9092
ANALYTICAL RESULTS
Sample: 28009014
Lab ID: 9216768004 Collected 04/04/08 09 00
Received 04/04/08`13 32 Matrix Water
Report
Parameters
Results Units Limit
MDL
DF
Prepared
Analyzed CAS No- Qual
200.7'MET ICP
Analytical Method EPA 200 7 Preparation Method EPA 200 7
Aluminum
3530 ug/L 100
250
1
04/07/08,1156
04/10/0813 59 7429 -90 -5
Antimony
ND ug/L 5.0
26
1
04/07/08 1156
04/10/0813 59 7440 -36-0
Arsenic
18.0 ug /L 5.0
2.7
1
04/07/08,11 56
04/10/0813.59 7440 -38-2
Barium
40.8 ug /L 50
020
1
04/07/0811 56
04/10/08 13 59 7440 -39-3
Boron
476 ug/L 100
47
1
04/07/08 11 56
04/10/08 13 59 7440 -42 -8
Chromium
ND ug/L 50
040
1
04107108 1156
04/10/0813 59 7440 -47 -3
Copper
283 ug /L 50
0 30
1
04/07/08 1156
04110/08 13 59 7440 -50 -'8
Iron
1750 ug /L 500
140
1
04/07/0811 56
04/10/0813 59 7439 -89-6
Magnesium
525 ug/L 100
30
1
04/07/0811 56
04/10/08 13 59 7439 -95-4
Manganese
42.4 ug/L 5 -0
030
1
04/07/0811 56
04/10/08 13 59 7439 -96 -5
Molybdenum
ND ug/L 5`0
1 1
1
04/07 /0811 56
04110 /08 13 59 7439 -98=7
Nickel
13.1 ug/L 5.0
1 7
1
04 /0710811 56
04110/08 13 59 7440-02 -0
Selenium
93 8 ug/L 100
38
1
04/07/08 1166
04/10/0813 59 7782 -49 -2
Thallium
ND ug/L 100
30
1
04 /07/0811 56
04/10/08 13 59 7440 -28 -0
21208 W Apparent Color
Analytical Method ,SM 2120B
Apparent Color
10.0 units 510
1
04/06/08 08 45
2640D Total'Suspended Solids
Analytical Method 'SM 2540D
Total Suspended Solids
104 mg /L 4 0
1
04/10/0817.40
4600FC Fluoride
Analytical Method SM 450OF /C
Fluoride
0.40 mg /L 010
010
1
04 /08 /08 18 00 16984 -48-8
6210B 800, Low Level
Analytical, Methodf,SM 52108
BOD, 5 day
3.3 mg /L 2 0
1
04/05/08 07 30
04/10/0811 25 B4
330.1 Ammonia
Analytical Method., EPA 350 1
Nitrogen, Ammonia
1.2 mg /L 010
010
1
04!1510813.07 7,764 -41 -7
351.2 Total Kjeldahl Nitrogen
Analytical Method ,EPA 351 2
Nitrogen, Kjeldahl, Total
2.5 mg/L 0:50
050
1
04/16/0815 20 7727 -37-0
353.2,Nitrogen, N021NO3 pros.
Analytical Method EPA 353 2
Nitrogen, NO2 plus NO3
13.8 mg/L 050
050
5
04/11/08 17 00
366.1 Phosphorus,'Total
Analytical Method !EPA 3651
Phosphorus
0.21 mg /L 010
010'
1
04/15/08 15 33 7723 -14-0
5220D COD
Analytical Method.'SM 5220D
Chemical Oxygen Demand
68.3 mg/L 250,
250
1
04110/0817.23
ASTM 0516 -90 Sulfate Water
Analytical Method ASTMlD516 -90
Sulfate
13.0 mg/L 5.0
50
1
04/08/08 15 20 14808 -79 -8
Date 05/02/2008 12.48 PM REPORT OF LABORATORY ANALYSIS Page 9 of 26
TNS report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc,
a y .aeo
il���i

o Pace Analytical Services, Inc.
aceMalXical 2225 kiveiside Dr
wiywpecolabmoom Asheville, NC 28804
(828)254 -7176
i
QUALITY CONTROL DATA
Page 13,of 36
Analytical Laboratory
Pace Analytical Services, Inc:
9800 KOnceyAve Suite 100
HuntersvIle, NC 28078
(704)875 -9092
Project 08- APR -0113
Pace Project No 9216758
QC Batch WET/3611
Analysis Method SM ,52106
QC Balch,Method SM`5210B
Analysis Description 52106 BOD, Low'Level
Associated'Lab Samples• 9216758001, 9216758002,
9216758003 „9216758004
METHOD BLANK 97710
Associated Lab Samples. 9216758001, 9216758002,
9216758003, 9216758004,
Blank Reporting
Parameter Units
Result Limit Qualifiers
BOD, 5 day mg /L
ND 20
LABORATORY CONTROL SAMPLE 97711
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limds Qualifiers
BOD „5 day mg /L
198 150 76 84,115 B4 ;
SAMPLE DUPLICATE: 97712
9216632001 Dup Max
Parameter Units
Result Result RPD RPD Qualifiers
BOD, 5 day mg/L
600 690 14 20 B4
Date 05/02/200812 48 PM REPORT OF LABORATORY ANALYSIS Page 10 of 26
This report shall not be reproduced, except mdu8,
Nnthout the written conserit of Pace Analytical Services, Inc..
M •��0�
u�` a'ni1

QUALITY•CONTROL DATA
Project 08- APR -0113
Pace Project No • 9216758
QC Batch WET /3612 Analysis Method SM 2120B
QC Batch Method SM 2120B Analysis Description 21208 Color
Associated Lab Samples 9216758001;92f6758002,9216758003.9216758004
METHOD BLANK 97713
Associated Lab Samples 9216758001-,,9216758002,92167,58003,9216758004
Blank Reporting
Parameter Units Result Limit Qualifiers
Apparent Color units ND 50
SAMPLE DUPLICATE: 97714
9216758601 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Apparent Color units 30 0 300 0 20
Date 05/02/2608 12 48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except Iri full,
without the written consent'of PaceAnalyllcel SeMoes, Inc
Page 11 of 26
Page 14,of 36
Analytical Laboratory
m Pace Analytical Services, Inc.
;aceWytical
Pace Analytical Services, Inc.
2225 Riverside Or
9800 KlnceyAve Suite 100
wwwpecelab&=n Asheville, NC 28804
Huntersvdle, NC'28076
! (828)254 -7176
(704)8759092
QUALITY•CONTROL DATA
Project 08- APR -0113
Pace Project No • 9216758
QC Batch WET /3612 Analysis Method SM 2120B
QC Batch Method SM 2120B Analysis Description 21208 Color
Associated Lab Samples 9216758001;92f6758002,9216758003.9216758004
METHOD BLANK 97713
Associated Lab Samples 9216758001-,,9216758002,92167,58003,9216758004
Blank Reporting
Parameter Units Result Limit Qualifiers
Apparent Color units ND 50
SAMPLE DUPLICATE: 97714
9216758601 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Apparent Color units 30 0 300 0 20
Date 05/02/2608 12 48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except Iri full,
without the written consent'of PaceAnalyllcel SeMoes, Inc
Page 11 of 26

/5a'ceAna1j&caf
} www;acofabscom
i
Pace Analytical Services, Inc.
2225 Riverside Or
Asheville, NC 28804
(828)254 -7176
QUALITY CONTROL DATA
Page 15 of 36
Analytical Laboratory
Pace Analytical Services, Inc.
9800 KlnceyAve- Suite 100
Huntersville, NC 28078
,[phone]
Project 08- APR -0113
Pace Project No 9216758
QC Batch WETA/2408
Analysis Method
ASTM D516 =90
QC'Satch Method ASTM D516 -90
Analysis Description
ASTMPD516 =90 Sulfate Water -
Associated Lab Samples. 9216758003, 9216758004
METHOD BLANK 97827
Associated Lab Samples 9216758003, 9216758004
Blank Reporting
Parameter
Units
Result Limit
Qualifiers
Sulfate
mg/L
ND 50
LABORATORY CONTROL SAMPLE
97828
Spike LCS
LCS
% Rec
Parameter
Units
Conc Result
% Rec
Limits Qualifiers
Sulfate
mgFL
20 20,0,
100
90 -110
MATRlk,SPIKE SAMPLE-
97829
9216500007 Spike
MS
MS
% Rec
Parameter
Units
Result Conc
Result
% Rec
Limits Qualifiers
Sulfate
mo /L
ND 20
201
95
75 -125
SAMPLEDUPLIcATE 97830
9216500007 Dup
Max
Parameter
Units
Result Result
RPD
RPD
Qualifiers
Sulfate
mg/L
NO ND 3
20
Date 05/021200812 48 PM
REPORT`OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
o�a.e
Page 12 of 26

aeeAnalytical0
! wwwpacela6s.com
7
Project 08-APR -0113
Pace Project No 9216758
QC Batch MBCH /1503
QC Batch Method Sfv1,9222D
Associated Lab Samples• 9216758001, 9216758003
METHOD BLANK 97853`
Assoclated'Lab'Samples 9216758001, 9216758003
Parameter Units
Fecal Coliforms CFU /100 mL
SAMPLE DUPLICATE 97854
Parameter
Fecal Coliforms
Units
CFU /100 mL
Pace Analytical Services, Inc.
2225 Riverside Or
Asheville, NC 28844
(828)254 -7.176
QUALITY CONTROL DATA
Analysis Method* SM 9222D
Analysis Description 9222D MBIO Feral Coliform - CHT
Page 16 of 36
Analytical Laboratory
Pace Analytical Services, Inc
9B00 Kincey Ave Swte 100
Huntersville, NC'28078
(704)875 -9092
Blank Reporting
Result Limit Qualifiers
ND 10
9216758003 Dup Max
Result Result RPD RPD Qualifiers
200 145 32 20,R1
Date 05/021200812 48 PM REPORT OF LABORATORY ANALYSIS Page 13 of 26
This report shall not be reproduced, except In full,
without the written consent of Pace Anal"cal Services„ Inc

MATRIX SPIKE SAMPLE
Parameter
97966
Units
Page 1.7 of 36
MS
% Rec
Reporting
Analytical Laboratory
e,
Pace Analytical Services, Inc.
Pace Analytical Services, Inc
aceAnalytical
2225 PJverslde Or'
980010ncey'Ave Suite'100
/ wwwpawebscom
Asheville, NC 28804
Huntereville, NC 28078
t
(828)2547178
(704)875 -9092
NO
QUALITY CONTROL DATA
100
Project 08- APR -0113
660 500 502
Antimony
Pace Project No 9216758
Boron
NO
QC,Batch MPRP /2148
Analysis Method EPA 200 7
70 -130
QC Batch,Method EPA 200 7
Analysis, Description 200 7 MET
ug/L
Associated`Lab Samples 9216758003, 9216758004
NO
Date 05/02/2008 12.48 PM
METHOD BLANK 97864
'REPORT OF LABORATORY ANALYSIS
Associated LatiZamples 9216758003;,9216758004
ug/L
MATRIX SPIKE SAMPLE
Parameter
97966
Units
Blank
MS
% Rec
Reporting
Aluminum
ug/L
Parameter
Units
Result
Antimony
Limit
NO 500 500
Qualifiers
70 -130
Aluminum
ug/L
NO 500 521
NO
70 -130
100
'ug/L
660 500 502
Antimony
ug/L
Boron
NO
60.8 500 573
do
70 -130
Chromium
Arsenic
ug/L
97
NO
Date 05/02/2008 12.48 PM
50
'REPORT OF LABORATORY ANALYSIS
Barium
ug/L
ND
50
Boron
ug /L
NO
100
Chromium
ug/L
NO
50
Copper
ug/L
NO
60
Iron
ug/L
NO
5b 0
Magnesium
ug/L
NO
100
Manganese
ug /L ^
ND
5'0
Molybdenum
ug /L
NO
1510
Nickel
ug /L
NO
5,0
Selenium
ug /L
NO
100
LABORATORY CONTROL SAMPLE
97,965
Spike
LCS
LCS
% Rec
Parameter
Units
Conc
Result
% Rec
Limits Qualifiers
Aluminum
ug/L
5000
4760
95
85-115
Antimony
ug/L
500
516
103
85 =115
Arsenic
ug/L
500
518
104
85-115
Barium
ug/L
500
-485
97
85-115
Boron
ug/L
500
499
100
85-115
Chromium
ug/L
500
509
102
85 -115'
Copper
ug/L,
500
490
98
85-115
Iron
ug /L
5000
4880
98'
85 -115
Magnesium
ug/L
5000
5,150
103
�85 -115
Manganese
ug /L
500
503
101
85-115
Molybdenum
ug/L
500
479
96
85 -115
Nickel
ug/L
500
523
105
85-115
Selenium
ug/L
500
514
103
85 -115
MATRIX SPIKE SAMPLE
Parameter
97966
Units
9216780001 Spike MS
Result Conc Result
MS
% Rec
% Rec
Limits Qualifiers
Aluminum
ug/L
NO 5000 4980
98
70-130
Antimony
ug/L
NO 500 500
100
70 -130
,Arsenic
ug /L
NO 500 521
104
70 -130
Barium
'ug/L
660 500 502
89
70 -130
Boron
ug` /L
60.8 500 573
102
70 -130
Chromium
ug/L
89 500 494
97
70-130
Date 05/02/2008 12.48 PM
'REPORT OF LABORATORY ANALYSIS
Page 14 of 26
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Semees, Inc.

/ "' aceAnalytical '
PaceAnalytical'Services, Inc.
2225 Riverside Or
Asheville. NC 28804
(828)2547176
QUALITY CONTROL DATA
Page 18 of 36
Analytical Laboratory
Pace Analytical Services, Inc.
9800 Kinsey Ave Suite 100
Huntersville, NC 28078
(704)875 -9092
Project 08 -APR -0113
Pace Project No 9216758
9216780002
Dbp
Max
Parameter
Units
MATRIX SPIKE SAMPLE,
97966
RPO
RPD Qualifiers,
Aluminum
ug /L
ND
ND
0
9216780001
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc
Result
% Rec
Limits Qualifiers
Copper
ug/L
ND
500
491
97
70'130
Iron,
ug/L
56.9
5000
4840
96
70 -130
Magnesium
ug /L
12300
5000
17100
97
70-130
Manganese
ug /L
117
500
575
92
70 =130
Molybdenum
ug /L
156
500
505
98
70=130
Nickel
ug /L
NO
500
478
95
70 -130
Selenium
ug /L
ND
500
508
102
70=130
SAMPLEIDUPLICATE - 97967
9216780002
Dbp
Max
Parameter
Units
Result
Result
RPO
RPD Qualifiers,
Aluminum
ug /L
ND
ND
0
20
Antimony
ug/L
ND
NO
0
20
Arsenic
ug/L
ND
ND
2.00
20
Barium
ug/L
105
104
1
20
Boron
ug/L
487-
47, 5
2
20
Chromium
ug1L
ND
ND
0
20,
Copper
ug/L
5 7
57
4
20
Iron
ug/L
ND
NO
0
20
Magnesium
ug/L
14600
14500
1
20
Manganese
ug /L
714
704
1
20
Molybdenum
ug/L
73
ND
200
20
Nickel
ug/L
ND
2,11
22
20
Selenium
ug/L
NO
ND
200
20
Date. 05/02/2008 12 48 PM REPORT OF LABORATORY ANALYSIS Page 15, of 26
This report shalllnot be'reproduced, except in full,
without the'w?itten consent of Pace'Analytical Services,, Inc.
�i

Page 1,9 of 36
Analytical Laboratory
i Pace Analytical Services, Inc. Pace Anatytical,Services, Inc.
e
aceA, nalytical 2225 Riverside Or 9800 Kincey Ave Sate 100
wwwPMkysC" Asheville, NC 28804 Huntensville, NC 28078
(828)254- 7176 (704)875 -9092
QUALITY CONTROL DATA
Project. 08 -APR -0113
Pace Project No - 9216758
QC Batch WET13621
Analysis Method
SM 460OF /C
QC 'Batch Method SM 4500F /C
Analysis Description ,
SM4500FC Fluonde,Water
Associated Lab Samples 9216758003;92116758004
METHOD BLANK 98551'
Associated Lab Samples 92167581)03, 9216758004
Blank Reporting
Parameter
Units
Result Limit
Qualifiers
Fluoride
mglL
ND 010
LABORATORY CONTROL SAMPLE
98552
Spike LCS
LCS
% Rec,
Parameter
Units
Conc Result
% Rec
Limits
Qualifiers
Fluoride
mg/L
25 23
92
90 -110
MATRIX,SPIKE�SAMPLE
98553
9216086001 Spike
MS
MS
% Rec
Parameter
Units
Result Conc
Result,
% Rec
Limits Qualifiers
Fluoride
mg /L
17 2 5
41
96
75 -125
MATRIX_ SPIKE`SAMPLE
985_55
9216758003 Spike
MS
MS
°h Rec
- Parameter
Units
Result Conc.
Result
% Rec
limits Qualifiers
Fluoride
mg/L
053 2.5
31
103
75-125
SAMPLE DUPLICATE 98554
Parameter
Fluoride,
SAMPLE DUPLICATE 98556
Parameter
Fluoride
Date, 05/02/2008 12 48 PM
9216086002 cup Max
Units Result Result RPD RPD Qualifiers
mg/L 032 031 3 20
9215758004 Dup Max
Units Result Result RPD RPD Qualifiers
mg /L 046 041 2 20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pecs Analytical Services, Inc.
coo,e
Page 16 of 26

aceAnalyt aW
www.pacefebstom
r -
i
Pace Analocal Services,,inc.
'2225 Riverside Dr
Asheville, NC 28804
(828)2547176
QUALITY CONTROL DATA
Page 20 of 36
Analytical Laboratory
Pace AnafyHcatServices, Inc
98001GnoeyAve Suite 100
Huntersville, NC 28078
(704)875 -9092
Project 08- APR -0113
Pace Project No 9216758
QC'Batch• WETA/2438
Analysis Method
SM 5220D
QC Batch Method- SM 5220D
Analysts Description.
5220D'COD
Associated Lab Samples, 9216758003, 9216758004
METHOD BLANK. 100047
Associated Lab Samples 9216758003, 9216758004
Blank 'Reporting
Parameter
Units
Result Limit
Qualifiers
Chemical Oxygen Demand
mg /L
ND 250
LABORATORY CONTROL SAMPLE
100048
Spike LCS
LCS
% Rec
Parameter
Units
Conc Result
% Rec
Limits
Qualifiers
Chemical Oxygen Demand'
mg /L
750 751
100
90-110
MATRIX SPIKE SAMPLE
100049
9216708001 Spike
MS
MS
% Rec
Parameter
Units
Result_ Conc.
Result
%)Rec
Limits Qualifiers
ChemlcatOxygen Demand
mg /L
4180 3000
4450
9
75 -125
MATRIX SPIKE SAMPLE
100052
9216925003 Spike
MS
MS
% Rec
Parameter
Units
Result Conc
Result
% Rec
Limits Qualifiers
i
,Chemical Oxygen Demand
mg /L
600 750
856
105
75-125
SAMPLE DUPLICATE 100051
Parameter
Chemical Oxygen Demand
SAMPLE DUPLICATE 102852
Parameter
Chemical Oxygen Demand
9217020601 Dup
Units Result Result
mg /L 25900 26000
9216909001 Dup
Units Result Result
mg/L 133 138
Max
RPD RPD Qualifiers
5 20
Max,
RPD 'RPD Qualifiers
4 20
Date 05/02/200612 48'PM REPORT OF L'A`BORATORY ANALYSIS Page 17 of 26
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.

Page 21 of 36
Analytical Laboratory
® Pace Analytical Services, Inc Pace Analytical Services, Inc.
acBAllalytical 2225 Riverside Dr 9800 FOnceyAve Sude,100
imwpacela6�com Asheville, NC 28804 Huntersville, NC 28078
(828)254- 7176 (704)875 -9092
QUALITY CONTROL DATA
Project 08 -APR -0113
Pace - Project No • 9216758
QC Batch VVET /3654
Analysis Method
SM 25400
QC Batch Method SM2540D
Analysis Description
2540D,T6tal,Suspende&Solids
Associated Lab Samples 9216758003, 9216758004
Max
Parameter Units
METHOD'BLANK 100164
Result
RPD RPD Qualifiers
Assoclated,Lab Samples 9216758003, 9216758004
255
25 0
2 20
Blank Reporting
Parameter Units
Result Limit
Qualifiers
Total Suspended Solids mg/L
ND 10
LABORATORY CONTROL SAMPLE. 100165
9216839001
Dup
Spike 'LCS
LCS WRec
Parameter Units
Conc Result
% Rec Limits Qualifiers
Total Suspended Solids mg/L
250 232
93 80 -120
SAMPLE DUPLICATE 100166
9216717002
Dup
Max
Parameter Units
Result
Result
RPD RPD Qualifiers
Total Suspended Solids mg/L
255
25 0
2 20
SAMPLE DUPLICATE 100167
9216839001
Dup
Max
Parameter Units
Result
Result
RPD RPD Qualifiers
TWASuspended Solids mg/L
ND
ND
0 20
Date 05/021200812 48 "PM REPORT OF LABORATORY ANALYSIS Page 18 of 26
This report shall not be reproduced „except In full,
without the written consent of Pace Analytical Services, Inc
C Tie.`
/i

l
Analytical
wwrapacelabs corn
Project 08- APR -0113
Pace Project'No ' 9216758
Pace Analytical Services, Inc.
2225 Riverside Dr
Asheville, NC 28804
(828)2547176
QUALITY CONTROL DATA
QC Batch WETA/2443 - Analysis Method EPA 365 1
QC Batch Method EPA 3651 Analysis Description 3651 "Phosphorus, Total
Associated LabfSamples 9216758003, 9216758004
METHOD BLANK 100220
Associated Lab-Samples 9216758003, 9216758004
Blank Reporting
Parameter Units Result Limit Qualifiers
Phosphorus mg/L ND 010
'Page 22 of 36
Analytical Laboratory
Pace Analytical Services, Inc
9800 Kmcey Ave Suite 100
Huntersville, NC 28078
(704)875 -9092
LABORATORY CONTROL SAMPLE 100221
Spike LCS LCS % Rec
Parameter Units Cone Result % Rec Limits Qualifiers
Phosphorus mg/L 1 10 102 90 -110
MATRIX SPIKE SAMPLE. 100222
9218839001, Spike MS MS % Rec
Parameter Units Result Cone. Result % Rea 'Limits Qualifiers
Phosphorus mg /L 034 1 13 94 90 -110
MATRIX SPIKE SAMPLE 100225
9215758004 Spike MS MS % Rec
Parameter Units Result Cone Result % Rec Limits Qualifiers
Phosphorus mg/L 0 21 1 1 3 108 90-110
SAMPLEDUPL'ICATE' 100223
9216997001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Phosphorus mg /L 19 19 1 20
SAMPLE DUPLICATE 100224
92167,58003 Dup Max
Parameter Units Result Result RPD RPD `Qualifiers
Phosphorus mg/L 0132 032 7 20
Date 05102/2008 12.48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc
Page 19 of 26

M
I
Page 23 o06
Analytical Laboratory
o Pace Ana"cal Services, Inc.
Pace Analytical Services, Inc
a ceiA ayicQ! 2225 Riverside Or
9800 IGncey Ave Suite 100
-/ wwx!paoefetrscom Asheville, NC 28804
Huntersville, NC'28078
(828)254- 7176
(704)875 -9092
QUALITY CONTROL DATA
Project, 08- APR -0113
Pace Project No 9216758
QC Batch WET'A/2446
Analysis Method EPA 3512
QC,Batch Method EPA 3512
Analysis Description 351 2 TKN
Associated Lab Samples 9216758003, 9216758004
METHOD BLANK 100453
Associated Lab Samples 9216758003, 9216758004
Blank
Reporting
Parameter
Units -
Result
Limit
Qualifiers
Nitrogen, Kjeldahl, Total
mg/L
ND
050
LABORATORY CONTROL SAMPLE
100454
Spike LCS
LCS
% Rae
Parameter
Units
Cone Result
% Rae
Limits Qualifiers
Nitrogen, Kleldatil, Total
mg/L
5
52
104
90 -110
MATRIX SPIKE SAMPLE
100455
9216997001
Spike
MS
MS
% Rae
Parameter,
Units
Result
,Cone
Result
41. Rae
Limits Qualifiers
Ntrogen „Kjeldahl, Total
mg/L
16
10
164,
93
90 -110
MATRIX'SPIKE SAMPLE
100458
9216758003
Spike
MS
MS
% Rec
Parameter
Units
Result
Cone
Result
% Rae
Limits Qualifiers
Nitrogen, KJeldahj, Total
mg1L
42
10
14-3
101
X90 -110
SAMPLE DUPLICATE 100456
9216460001
Duo
Max
Parameter
Units
Result
Result,
RPD
RPD
Qualifiers
Nitrogen, Kjeldahl, Total,
mglL
59
67
11
20
SAMPLE DUPLICATE 100457
9216759005
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Nitrogen, K)eldahl, Total
mg/L
320
34 6
8
20
Date 05/02/2008 12 48 PM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc,
0
Page 20 of 26

Ice Analj6dat"
wwwpscefabs Coln
i
Pace Analytical Services, Inc.
2225 Riverside Dr
Asheville, NO 28804
(828)254 -7176
QUALITY CONTROL DATA
Page 24 of 36
Analytical Laboratory
Pace Analytical Services, Inc.
9800 KJnceyAve Suite 100
Huntersville, NO 28078
(704)875 -9092
Project 08- APR -0113
9216829002,
Pace Project No 9216758
Max
Parameter Units
Result
Result
RPD RPD Qualifiers
QC!Batch WETA12448
ND
Analysis Method
EPA 353 2
SAMPLE DUPLICATE: 100577
QC Batch Method, EPA 353 2
Analysis Description
353 2,Nitratei +Nitrite, preserved
Dup
Associated Lab Samples 9216758001, 9216758002,
9216758003, 9216758004
Result
Result
RPD RPD Qualifiers
METHOD BLANK 100572
025
626
6 20
Associated Lab,Samples 9216758001,§216758002,9216758003,9216758004
Blank Reporting
Parameter
Units
Result Limit
Qualifiers
Nitroden,,NO2 plu§,NO3
mg /L
FND 010
LABORATORY CONTROL SAMPLE
100573
Spike 'LCS
LCS
% Rec
Parameter
''Units
Cone Result
% Rec
Limits Qualifiers
Nitrogen, NO2 plus NO3
mg /L
5 5.2
104
90-110
MATRIX SPIKE SAMPLE
100574
9216829001 Spike
MS
MS
% Rec
Parameter
Units
Result Cone
Result
% Rec
Limits Qualifiers
Nitrogen, NO2 plus NO3
mg/L-
ND 5
5 9
118
75 -125
MATRIX SPIKE SAMPLE
100576
9216829011 Spike
MS
MS
% Rec
Parameter
Units
Result Cone.
Result
% Rec
Limits Qualifiers
Nitrogen, NW plus NO3
mg/L
ND 5
53
106
75 -125
SAMPLE DUPLICATE 100575
9216829002,
Dup
Max
Parameter Units
Result
Result
RPD RPD Qualifiers
Nitrogen, NO2 plus NO3 mg/L
ND
ND
0 20
SAMPLE DUPLICATE: 100577
9216909001
Dup
Max
Parameter Units
Result
Result
RPD RPD Qualifiers
Nitrogen, NO2 plus NO3 mg /L
025
626
6 20
r
Date 05/02/200812 48 PM
REPORT OF LABORATORY ANALYSIS'
This report shall not be reproduced „except in full,
without the written consent of Pace Analytical Services, Inc.
Page 21 of 26

I -
I e Pace Analytical Services, Inc.
aceAnalytical 2225 Riverside Dr
— pecetabs=" Ashowlte, NC 28804
(828)254 -7176
J'
QUALITY CONTROL DATA
Page,25 of 36
Analytical Laboratory
Pace Analytical Services, Inc
9800 KinceyAve Suite 100
Hunterswfla, NC 28078
(704)875 -9092
Project 08-APR-1011 13
Pace Prrject No 9216758
QC)Batch WETA12466
Anatysis'Method EPA 3501
QC Batch Method EPA 3501
Analysis Description, 3501 Ammonia,
Associated Lab Samples 9216758001, 9216758002, 9216758003
METHOD BLANK 101245
Associated Lab Samples 9216758001,9216758002 „9216758003
Blank Reporting
Parameter
Units
Result Limit
Qualifiers
Nitrogen, Ammonia
mg/L
ND 010
LABORATORY CONTROL SAMPLE
101246
Spike LCS,
LCS
% Roc
Parameter
Units
Conc Result
% Rec
Limits
Qualifiers
Nitrogen, Ammonia
mg /L
5 50
101
90-110
MATRIX SPIKEZAMPLE
101247
9216839001 Spike
MS
MS
% Rec
Parameter
Units
Result Conc.
Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia
mg/L
88 5
8 5
-6 90-110 M3
MATRIXSPIK&SAMPLE
101250
'9216818002 Spike
MS
MS
% Rec
Parameter
Units
Result Conc
Result
% Rec
Limits Qualifiers
Nitrogen. Ammonia
mg/L
036 5
4,3
80 90 -110 M3
SAMPLEiDUPLI CATIE 1,01248;
9216997001 Dup
Max
Parameter
Units
Resuft Result
RPD
RPD
Qualifiers
Nitrogen, Ammonia
mg/L
0.60 054
10
20
'SAMPLE DUPLICATE 1012.49
9216909001 Dup
Max
Parameter
Units
Result Result
RPD
RPD
Qualifiers
Nitrogen, Ammonia
mg/L
059 062
5
20
Date. 05/02/2008 12 48 PM
REPORT'OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
`o lo,
Page 22 of 26

ace Analytical
twrw- Pacela6scom
Project 08- APR -0113
Pace Project No, 9216758
QC Batch WETA/2467
QC Batch,Method EPA 3501
Associated Lab Samples- '9216758004
METHOD BLANK. 101257
Associated Lab Samples 9216758004
Parameter Units
Nitrogen, Ammonia mg /L
Pace Analytical Services, Inc
2225'Riverside Or
Asheville, NC,28804
(828)2547176
QUALITY CONTROL DATA
Analysis Method EPA 350 1
Analysis Description 3501 Ammonia
Blank Reporting
Result Limit Qualiflers
ND 010
Page 26 of 36
Analytical. Laboratory
Pace Analytical Services, Inc
980014nceyAve Suite000
Huntersville, NC 28078
(704 )875 -9092
LABORATORY'CONTROL SAMPLE
101258
Spike LCS
LCS
% Rec
Parameter
Units
Conc Result
% Rec
Limits
Qualifiers
Nitrogen, Ammonia
mg/L
5
54
108
90-110
MATRIX SPIKE SAMPLE-
101259
9216758004
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc
Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia
mg /L
12
5
5 8
92 90 -110
MATRIX SPIKE SAMPLE
101262
9216549001
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc
Result
% Rec
Limits Qualifiers,
Nitrogen, Ammonia
mg/L
ND
5
4.5
90 90-110
SAMPLE bUPLICATE. 101260
9216897001
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Nitrogen, Ammonia
mg/L
ND
ND
59
20 R3
SAMPLE'DUPLICATE: 101261
9216501001
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Nitrogen, Ammonia
mg /L
37
3''7
6
r
20
Date 05/62/200812.48 PM REPORT OF LABORATORY ANALYSIS Page 23 of 26
Ttds report shall not be reproduced; exoept In full,
without the written consent of Pace Analytical Services, Inc.

aceAnalytical e
/ emkpaeelaftcom
Pace Analytical Services, Inc.
2225 Riverside Dr
Asheville, NC 28804
(828)254 -7176
QUALITY`CONTROL DATA
Project* 08- APR -0113
Pace,Pro)ect No 9216758
QC Batch. GGSV 12634 Analysis Method, EPA 1664A
QC Batch Method EPA 1664A Analysis, Description 1664 HEM, Oil and Grease
Associated`Lab Samples. 9216758003
METHOD BLANK 102920
Associated Lab Samples 9216758003
Blank Reporting
Parameter Units Result Limit Qualifiers
Oil;and,Grease mg /L ND so
Page 27 of 36
Analytical Laboratory
Pace Analytical Services, Inc.
9800 Pitney Ave Sulte 100
Huntersvills, NC 28078
(704)875 -9092
LABORATORY CONTROL SAMPLE & LCSD 102921 102922
Spike L'CS 1-6 §13 L'CS LCSD % Rec Max
Parameter Units Conc Result Result % Rec % Rec Limits RPD RPD Qualifiers
Oil and Grease mg /L 40 408 416 102 104 78 -114 2 30
Date 05/02/200812 48 PM REPORT OF LABORATORY ANALYSIS
This report shell not be reproduced, except in full,
without the written consent of Pace AnalyBcal Services, Inc..
Page`24 of 26

II Page 28 °of 36
Analytical Laboratory
Pace Analytical Services, Inc. Pace Analytical Services, Inc.
Analytical' 2225 Riverside Dr 9800 Kmcey Ave .Suite 100
mwpa vfaDscom Ashevi8e, NC 26804 Huntersville, NC,28078
(828)254- 7176 (704)875 -9092
QUALIFIERS
Project. 08- APR -0113
Pace Project No 9216758
DEFINITIONS
DF - 'Dilution Factor; if reported, represents the factor applied to,the,reported data due,to)changes in sample,preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted I reporting, limit
J - Estimated, concentration, above the adjusted method detection limit and below,the adjusted reporting,limit
MDL - Adjusted Method Detection Limit
S - Surrogate
1,2- Diphenylhydrazme (8270 Iisted,analyte) decomposes to Azobenzene
Consistent with EPA guidelines, unrounded data are,displayed and'have been used to calculate % recovery,and+RPD values
LCS(D) - Laboratory Control Sample � (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable
Pace Analybcal,is NELAP accredited Contact your Pace PM for the, current list of accredited analytes
ANALYTE QUALIFIERS
B4
The glucose/glutamic acid standard exceeded the,range,of 198 plus,or minus 30 5 mg/L.
M3
Matrix spike recovery was, outside laboratory control limits due to matrix mtetferences
R1
RPD value,was outside control limits
R3
RPD value was outside control limits due to uncertainty of values at or near the PRL-
ui
Results based upon colony counts outside acceptable range,
Date 05/0212008 12.48 PM REPORT OF LABORATORY ANALYSIS Page 25 of 26
This report shall not be reproduced, except In full,
,wlttrout the written consent or Pace Analytical Services, Ina
f
"o � &:

Page 29 of 36
Analytical Laboratory
Pace'Anatytical Services, Inc. Pace Analytical Services, Inc,
ac 9*alytical 2225 Riverside Dr 98001Gncey Ave Suite 100
/ mnv.Pa ftcarn Asheville, NC 28804 Huntersvdle „NC 28078
I [phone] [phone]
QUALITY CONTROL DATA CROSS REFERENCE'TABL' E
Project 08- APR -0113
Pace Project No • 9216758
9216758001
28009011
SM 2120B
WET13612
9216758002
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
9216758001
28009011
SM 5210B
WET/3611
SM 52108
WETt3642
9216758002
28009012
SM 5210B
WET/3611
SM 5210B
WET/3642
9216758003
28009013
SM 5210B
WET/3611
SM,5210B
WET %3642
9216758004
28009014
SM 5216B
WET13611
SM 52108
WET/3642
9216758001
28009011
SM 2120B
WET13612
9216758002
28009012
SM 21208
WET /3612
9216758003
28009013
SM,2120B
WET /3612
9216758004
28009014
SM�2120B
WET13612
9216758003
28009013
ASTM D516 -90
WETA/2408
9216758004
28009014
ASTM D516 -90
WETA/2408
9216758001
28009011
SM,9222D
MBCH /1503
9216768003
28009013
SM'9222D
MBCH /1503
9216758003
28009013
EPA 200 7
MPRP /2148 EPA 200 7
9216758004
28009014
EPA 200 -7
MPRP/2148 EPA 200 -7
9216758003
28009013
SM 450OF /C
WET /3621
9216758004
28009014
SM 450OF /C
WET/3621
9216758003
28009013
SM 5220D
WETA/2438
9216758004
28009014
SM 5220D
WETA/2438
9216758003
28009013
SM 2540D
WET/3654
9216758004
28009014
SM 25400
WET/3654
'9216758003'
28009013,
EPA 365.1
WETA/2443
9216758004
28009014
EPA 3651
WETA/2443
9216758003
28009013
EPA 3512
WETA/2446
9216758004
28009014
EPA 3512
WETA12446
9216758001
28009011
EPA'353 2
WETA/2448
9216758002
28009012
EPA 353 2
WETA/2448
9216758003
28009013
EPA 353 2
WETA/2448
9216758004
28009014
EPA 353 2
WETA12448
9216768001
28009011
EPA 350 1
WETA/2466
9216758002
28009012
EPA 350 1
WETA/2466
9216758003
28009013
EPA 3501
WETA/2466'
9216768004
28009014
EPA,350 1
WETAd467
9216768003
28009013
EPA 1664A
GCSV /2634
Date 05102/200812.48
PM
f
REPORT OF LABORATORY ANALYSIS,
This report shall not be reproduced, except in,full.
without the written consent of Pace Anidyhcal Services, Inc.
ICP/2077-
ICP/2077
Page 26 of 26

aceAn,alytical e
www.paceiabs.com
April 21, 2008
Mr. Kevin Herring
Pace Analytical Services, Inc
980.0 Kincey Ave
Suite 100
Huntersville, NC 28078
Page 30 of 36
Analytical Laboratory
Waltz Mill Radiochemistry Lab,
PO_ Box 158
G
Bldg , M/S 62
Madison, PA 15663
Phone, 724 722 5214
Fax' 729 722.5208
NPDES Water Characterization; Purchase Order No. 9216758
9216758, Duke Power NPDRSI Huntersville
Pace Project No. 08 -1585
Dear Mr. Herring.
Enclosed are analytical results for samples submitted by Pace Analytical
Services„ Inc. Samples were,received,bn April 7, 2008 and logged in for analysis
on April 8, 2,008.
Methods used are indicated on the attached data table. Appropriate quality
assurance /quality control analyses were performed in accordance with Pace, Waltz
Mill Site Quality Assurance Plan,. The results reported in this project meet the
requirements as specified in Chapter 5 of the NELAC Standards'. Any deviations
or discrepancies from the NELAC standards are documented in the case
narrative(sl of this report. If you have any questions, please call me at
7,24 -7,22 -5219.
i ce ly
Richard Kinney
Radiochemistry Laboratory Supervisor
RMK:tew
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except,ln full,
Page 1 of without the,written consent of Pace Analytical Services, Inc.

Page13l, of 36
Analytical Laboratory
PACE ANALYTICAL SERVICES, INC.
CASE NARRATIVE
I. PROJECT LOGIN INFORMATION:
A: PROJECT NUMBERS:
PACE: 08 -1585
CLIENT: Purchase Order Number:
9216758
B: SAMPLE IDENTIFICATIONS:
Pace ID Client ID
Pace ID
Client ID
0804 -0269 9216758002 (28009012
0804 -0270
9216758003 (28009013
0804 -0271 9216758004 (28009014
'C: SHIPPING /RECEIVING COMMENTS:
Final Report 04- 21 -08.
II. PREPARATION /ANALYSIS COMMENTS:
A: RADIOLOGICAL:
NONE
III. GENERAL COMMENTS,:
Trailing zeroes and decimal places
appearing
on the data 'should not
be interpreted as precision of the
analytical
procedure, but rather
as a result of reporting format.
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an as- received basis.
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Analytical' Laboratory
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Page 34,of 36
Analytical Laboratory
e • • o • •
1,-FaceArralytical' r�
Client Name- o c0V-,(-_ Project
Courier Fed Ex UPS ❑ Pace Other Opbociaf- �+3 =r�,
❑ ❑ ❑ USPS Client ❑ Commercial
Custody Seal on Cooler /Box Present. Q yes no Seals intact ❑ yes no
Packing Material. ❑ Bubble Wrap ❑Bubble Bags .None ❑Other
Thermometer Used T060 Type of'lce ft, Blue None Samples on ice. cootino orocess has beaun
Cooler Temperature,
Temp should be above freezing to 6 °C
A Biological Tissue is Frozen, Yes No N
Comments-
Date and In ial of per examining
contents
Chain of Cuslody'Present-
.&S es ONO
ON /Ai
,1
Chain of Custod 'Filled Out
eYes ONO
❑NIA,
2
a
Chain of Custody Relinquished
;;kts ONO
ONIa
3
'Sampler'Name & Signature on COC
t!Yes 0 N
ONIa
4
G
eo
Samples Arrived within Hold Time
J;�Tes ONO
ONIA'
5
Short Hold Time Analysis ( <72hr )
Ai Yes ONO
ON /A
6 dl
Rush Turn Around Time Requested
Oyes ONO
❑N/A
7
Sufficient Volume
OYes .0No
❑NIA
8W-01) Colors
T n
Correct Containers Used
=Pace Containers Used
OYes JB'No
OYes 2No
❑N /A
ON /A
gq�p Oil 1 F( �,� t,a$ {�lC}�
+Np21} o,i C^t �A `
Containers Intact
Oil es ,ONo
❑NIA
/� n ,,�.L{f+
"10caso Yolr
P4.-J,-e,
Ql'a Veto a P►a.J,-e. 2 &d
Filtered volume received'for`Dissolved tests _
OYes ONO .em/A
1'1
gQl`3 t t l A
Sample Labels match COC
- Includes date /time /ID /Analysis Matnx
CiK?es ONo
'ON /A
12
n °�
(1 u'(4 ' PEAK &4&4c,
.�}�
All containers needing preservation have been checked
All containers needing preservation are found to be in
compliance with EPA recommendation
exceptions VOA, colirorm, TOC, O$G, vo -ORo (water)
IM ONO
.2Yes ONo
OYes, ONO
ON /A
❑N /A
13
Inilial when completed
Sampfes„checked for dechlorinahon
es ONo
❑NIA
14
Headspa"ce In VOA Vials ( >6mm)
OYes ONO
01A
15
Tnp Blank Present,
Trip Blank Custody Seals Present
Pace Tri , "Blank Lot # (if purchased) NIA
OYes ONo �XIA
OYes ONo �AJA
16
Client Notification/ Resolution:
Person Contacted
Comments/ Resolution
Date/Time
Field Data Required? Y / N / N/A
Project Manager Review: Date:��'�
Note Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of lhis,form will be sent to the North Carolina DEHNR
Certification Office Qs s out of hold, incorrect preservative, out of temp, incorrect containers)
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