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HomeMy WebLinkAboutNCG030548_MONITORING INFO_20170802f STORMWATER DIVISION CODING'SHEET NCG PERMITS,. PERMIT NO. /V C. DOC TYPE ❑ HISTORICAL FILE 9 MONITORING REPORTS DOC DATE I� YYYYM M DD 0 WEIL-McLAIN e tvso w6 a 2 wl o\NRRAL FILES S CY ON 523 New Street • Eden, NC 27288 Tel: (336) 627-6037 • Fax: (336) 627-6075p RECEIVED Division of Water Quality AUG 0 2 2017 Attn: Central Files 1617 Mail Service Center CENTRAL FILES Raleigh, North Carolina 27699-1617 DWR SECTION Dear Sir or Madam: " 3 0 S__q J In accordance with NPDES (NCG030000) Stormwater Permit Condition Part II Section B, the first of 2 semi-annual sampling events has been completed and is attached. The sampling was collected on 6/5/17, but we did not receive that report from Pace Analytical Services until 7/31 /17. Monitoring was conducted for Stormwater discharge 6-13 (SDO) as identified in the SWPPP, with 'NO FLOW' being reported in three of the outfalls. The DMR, Storm data (local onsite readings), and analytical data is attached. As indicated in the Stormwater Discharge Monitoring Report, there was one item that was outside of the benchmark. The following Stormwater Discharge Outfalls exhibited values measured outside of the benchmark limits: Outfall #8: pH of 5.9 below the benchmark of 6.0-9.0 Tier One actions have been implemented, and the SWPPP has been updated to include the following: Additional inspection with detailed observation of the outfalls Re -sampling of outfalls during the next qualifying rain event Collection of a Baseline Sample from 'Falling Rain' to establish a baseline of the rainfall The total rainfall recorded under Part A of the Stormwater Discharge Outfall (SDO) Monitoring Report is listed at 0.84" for the period. The sample was collected within 30 minutes of the discharge. If you have any questions or comments regarding the enclosed reports, please contact me at (336) 627-6015 Sincerely," - n . A L. {. u o Holly Si ens Compliance Manager Eden, NC Facility Permit Number: NCS Certificate of Coverage Number: NCG030548 STORMWATER DISCHARGE OUTFALL (SDO) MONITORING REPORT or SAMPLES COLLECTED DURING CALENDAR YEAR: 2017 (This monitoring report shall be received by the Division no later than 30 days from the date the facility receives the sampling results from the laboratory.) FACILITY NAME: Weil -McLain PERSON COLLECTING SAMPLE(S): Holly Siddens & Mike Moretz CER'rIFIED LABORATORY(S): Pace Analytical Services Inc., Lab # See Analytical Data Lab # Part A: Specific Monitoring Requirements COUNTY Rockingham PHONE NO. (336) 627-6015 SIGNATURE OF PERMITTEE OR DESIGNEE READ ON PAGE 2. Outfall No. Date Sample Collected, molddlyr 00530 00400 01051 00556 78141 Total Suspended Solids, mg/L pH, Standard Units Total Lead, mg/L Total Copper, mall, Total Zinc, mg/L Oil and Grease, mg/L Total Toxic Organics, mg/L Benchmark 100 Within 6.0-9.0 0.030 0.007 0.067 15 1 SDO #1 Combined with #6 SDO #2 Combined with #6 SDO #3 Combined with #6 SDO #4 Combined with #6 SDO #5 Combined with #6 SDO #6 06/05/17 <2.9 6.4 <0.005 <0.005 <0.010 <5.0 0.011 SDO #7 06/05/17 20.4 6.8 <0.005 <0.005 <0.010 <5.0 <0.05 SDO #8 06/05/17 17.9 5.9 <0.005 <0.005 0.061 <5.0 0.01 SDO #9 No Flow SDO #10 No Flow SDO #11 06/05/17 <2.8 8.6 <0.005 <0.005 0.019 <5.0 <0.05 SDO #12 No Flow sD0 #13 06/05/17 3.5 1 6.4 <0.005 1 0.0059 0.024 <5.0 1 <0.05 Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier i or Tier2 responses. See General Permit text. Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes _X_no (if yes, complete Part B) Page I of 2 Part B: Vehicle Maintenance Activity Monitoring Requirements Outfall No. Date Sample Collected, mo/dd/yr 00556 00530 00400 Oil and Grease, _ m IL Total Suspended Solids pl-1, Standard units New Motor Oil Usage, Annual average allmo 30 m /I Within 6.0-9.0 - Note: if you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier 1 or Tier2 responses. See General Permit text. STORM EVENT CHARACTERISTICS: Date: 06/05/2017 Total Event Precipitation (inches): 0.84" Mail Original and one copy to: Division of Water Quality Attn: Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, includin p"fil im "nes and imprisonment for knowing violations." (Signature 5dui 2-4� (Date) Page 2 of 2 TTO Certification Statement Period January 2017 — June 2017 Based on my inquiry of the person or persons directly responsible for managing compliance with the permit limitation for Total Toxic Organics (TTO), I certify to the best of my knowledge and belief, no leak, no spill, or no dumping of concentrated toxic organics into the stormwater or onto areas which are exposed to rainfall or stormwater runoff has occurred since filing of the last monitoring report. I further certify that this facility is implementing all of the provisions of the Solvent Management Plan included in the Stormwater Pollution Prevention Plan. Dates j-. it, 2-L91 Site Dire&/ Weil -McLain, Eden Operations laneAnalyfical" *WWpecela6soarr+ June 19, 2017 Mr. Michael Thomason Weil McLain 523 S. New St. Eden, NC 27288 RE: Project: 6117 STORMWATER Pace Project No.: 92342821 Dear Mr. Thomason: Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-a921 Enclosed are the analytical results for sample(s) received by the laboratory on June 05, 2017. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNIINELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kristi Dancy for Clayton McCrickard clayton.mccrickard@pacelabs.com (336)623-8921 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 48 lacmnalytical* "ftP celaha= Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 CERTIFICATIONS Project: 6/17 STORMWATER Pace Project No.: 92342821 Charlotte Certification IDS 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 South Carolina Certification #: 99006001 North Carolina Drinking Water Certification #: 37706 FloridalNELAP Certification #: E87627 North Carolina Field Services Certification #: 5342 Kentucky UST Certification #: 84 North Carolina Wastewater Certification #: 12 VirginiaNELAP Certification #: 460221 Asheville Certification IDS 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 Eden Certification IDS 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 09030001 VrginiaNELAP Certification #: 460222 North Carolina Wastewater Certification #: 633 VirginiaNELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 48 (/Ia'neAnalyfical wvw.pacakbs.cere SAMPLE ANALYTE COUNT Project: 6117 STORMWATER Pace Project No.: 92342821 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 272BB (336)623-8921 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92342821001 SDO #6 SM 2540D CTB 1 PASI-E SM 4500-H+B NMH 1 PASI-E EPA 1664B JMS 1 PASI-C EPA 608 RES 27 PASI-C EPA 200.7 SH1 3 PASI-A EPA625 BPJ 64 PASI-C EPA 624 GAW 72 PASI-C 92342821002 $DO #7 SM 2540D CTB 1 PASI-E SM 4500-H+B NMH 1 PASI-E EPA 1664B JMS 1 PASI-C EPA 608 RES 27 PASI-C EPA 200.7 SH1 3 PASI-A EPA 625 BPJ 64 PASI-C EPA 624 GAW 72 PASI-C 92342821003 SDO #8 S SM 2540D CTB 1 PASI-E SM 4500-H+B NMH 1 PASI-E EPA 16648 JMS 1 PASI-C EPA608 RES 27 PASI-C EPA 200.7 SH1 3 PASI-A EPA625 BPJ 64 PASI-C EPA 624 GAW 72 PASI-C 92342821006 SDO #11 SM 2540D CTB 1 PASI-E SM 4500-H+B NMH 1 PASI-E EPA 1664B JMS 1 PASI-C EPA608 RES 27 PASI-C EPA 200.7 SH1 3 PASI-A EPA625 BPJ 64 PASI-C EPA624 GAW 72 PASI-C 92342821008 SDO #13 SM 2540D CTB 1 PASI-E SM 4500-H+B NMH 1 PASI-E EPA1664B JMS 1 PASI-C EPA 608 RES 27 PAS1-C EPA 200.7 SH1 3 PASI-A EPA 625 BPJ 64 PASI-C EPA 624 GAW 72 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Anatytical Services, LLC. Page 3 of 48 acMnalytical www.pec&Wb&=n ANALYTICAL RESULTS Project: 6/17 STORMWATER Pace Project No.: 92342821 Pace Anatytical Services, LLC 205 East Meadow Road - Suite Eden, NC 27288 (336)623-8921 Sample: SDO #6 Lab ID: 92342821001 Collected: 05/05/17 07:30 Received: 06/05/17 10:53 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids ND mg1L 2.9 1 06/05/17 12:15 4500H+ pH, Etectrometric EDN Analytical Method: SM 4500-H+B pH at 25 Degrees C 6.4 Std. Units 1.0 1 06/05/17 13:25 1664 SGT-HEM, TPH Analytical Method: EPA 1664B Total Petroleum Hydrocarbons ND mg1L 5.0 1 06/07/17 Vi04 608 GCS Pesticides and PCBs Analytical Method: EPA608 Preparation Method: EPA 3510 Aldrin ND mg/L 0.000050 1 06/09/17 13:07 06/12/17 21:32 309-00-2 alpha-BHC NO mg1L 0.000050 1 06/09/17 13:07 06/12/17 21:32 319-84-6 beta-BHC ND mg/L 0,000050 1 06109/17 13:07 06/12/17 21:32 319-85-7 delta-BHC ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 21:32 319-86-8 gamma-BHC (Ltndane) ND mg/L 0.000050 1 06/09/17 13:07 06/12/17 21:32 58-89-9 Chlordane (Technical) ND mg/L 0,00050 1 06/09/17 13:07 06/12/17 21:32 57-74-9 4,4'-DDD ND mg/L 0.000050 1 06/09/17 13:07 06/12/17 21:32 72-54-8 4,4'-DDE ND mg/L 0.000050 1 06/09/17 13:07 06/12/17 21:32 72-55-9 4,4'-DDT ND mg/L 0.000050 1 06/09/17 13:07 06/12/17 21:32 50-29-3 Dieldrin ND mg/L 0.000050 1 06/09/17 13:07 06/12/17 21:32 60-57-1 Endosulfan I ND mg/L 0.000050 1 06/09/17 13:07 06/12/17 21:32 959-98-8 Endosulfan II ND mg/L 0.000050 1 06/09/17 13:07 06/12/17 21:32 33213-65-9 Endosulfan sulfate ND mg/L 0.000050 1 06/09/17 13:07 06/12/17 21:32 1031-07-8 Endrin ND mg/L 0.000050 1 06/09/17 13:07 06/12/17 21:32 72-20-8 Endrin aldehyde ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 21:32 7421-93-4 Heptachlor NO mg/L 0.000050 1 06/09/17 13:07 06/12/17 21:32 76-44-8 Heptachlor epoxide ND mg/L 0.000050 1 06/09/17 13:07 06/12/17 21:32 1024-57-3 PCB-1016 (Aroclor 1016) ND mg/L 0.00050 1 06/09/17 43:07 06/12/17 21:32 12674-11.2 PCB-1221 (Aroclor1221) ND mg1L 0.00050 1 06/09/17 13:07 0611211721:32 11104-28-2 PCB-1232 (Aroclor 1232) ND mglL 0.00050 1 06/09/17 13:07 06/12/17 21:32 11141-16-5 PCB-1242 (Aroclor 1242) ND mg1L 0.00050 1 06/09/17 13:07 06/12/17 21:32 53469-21-9 PCB-1248 (Aroclor 1248) ND mg1L 0.00050 1 06/09/17 13:07 06/12/17 21:32 12672-29-6 PCB-1254 (Aroclor 1254) ND mg/L 0.00050 1 06/09/17 13:07 06/12/17 21:32 11097-69-1 PCB-1260 (Aroclor 1260) ND mg1L 0.00050 1 06/09/17 13:07 06/12/17 21:32 11096-82-5 Toxaphene ND mg/L 0.00050 1 06/09/17 13:07 06/12/17 21:32 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 33 % 20-110 1 06/09/17 13:07 06/12/17 21:32 877-09-8 Decachlorobiphenyt (S) 30 % 20-138 1 06/09117 13:07 06/12/17 21:32 2051-24-3 200.7 MET 1CP Analytical Method: EPA 2007 Preparation Method: EPA 200.7 Copper ND mg1L 0.0050 1 06107/17 16:00 06/10/17 23:22 7440-50-8 Lead ND mg/L 0,0050 1 06/07/17 16:00 06/10/17 23:22 7439-92-1 Zinc ND mg1L 0.010 1 06/07/17 16:00 06/10/17 23:22 7440-66-6 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 Acenaphthene ND mglL 0.0050 1 06/09/17 11:45 06111/17 23:29 83-32-9 Acenaphthylene ND mg1L 0.0050 1 06/09/17 11:45 06/11/17 23:29 208-96-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/1912017 09:33 AM without the written consent of Pace Analytical Services, LLC. Qual H6 Page 4 of 48 laceAnalytical" www.peoelahsc= ANALYTICAL RESULTS Project: 6117 STORMWATER Pace Project No.: 92342821 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Sample: SDO #6 Parameters Lab ID: 92342821001 Results Units Collected: 06/05/17 07:30 Report Limit OF Received: 06/05/17 10:53 Matrix: Water Prepared Analyzed CAS No. Qual 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 Acetophenone ND mg1L 0.0050 1 06109/17 11:45 06/11/17 23:29 98-86-2 Aniline ND mg1L 0.010 1 06109/17 11:45 06/11/17 23:29 62-53-3 Anthracene ND mg1L 0.0050 1 06/09/17 11:45 06/11/17 23:29 120-12-7 Benzidine ND mg1L 0.050 1 06109/17 11:45 06/11/17 2329 92-87-5 L2 Benzo(a)anthracene ND mg1L 0.0050 1 05109/17 11:45 06/11/17 23:29 56-55-3 Benzo(a)pyrene ND mg1L 0,0050 1 06/09/17 11A5 06/11/17 23:29 50-32-8 Benzo(b)fluoranthene ND mg/L 0.0050 1 06/09117 11:45 06/11/17 23:29 205-99-2 Benzo(g,h,i)perylene NO mg1L 0.0050 1 06/09/17 11:45 06/11/17 23:29 191-24-2 Benzo(k)fluoranthene ND mg1L 0.0050 1 06/09/17 11A5 06/11/17 23:29 207-08.9 4-Bromophenylphenyl ether ND mglL 0,0050 1 06/09/17 11A5 06/11/17 23:29 101-55-3 Butyl benzylphthe late NO mg1L 0.0050 1 06/09/17 11:45 06/11/17 23:29 85-68-7 4-Chloro-3-methylphenol ND mg/L 0.0050 1 06/09/17 11A5 06/11/17 23:29 59-50-7 bis(2-Chloroethoxy)methane ND mg1L 0.010 1 06/0911711:45 0611111723:29 111-91-1 bis(2-Chloroethyl) ether ND mg/L 0.0050 1 06/09/17 11:45 06/11/17 23:29 111-44-4 2-Chloronaphthalene ND mg/L 0,0050 1 06/09/17 11:45 06/11/17 23:29 91-58-7 2-Chlorophenol ND mg1L 0.0050 1 06/09/17 11:45 06/11/17 23:29 95-57-8 4-Chlorophenylphenyl ether ND mg1L 0.0050 1 06/09/17 11:45 06/11/17 23:29 7005-72-3 Chrysene ND mg1L 0.0050 1 06/09/17 11:45 06/11/17 23:29 218-01-9 Dibenz(a,h)anthracene ND mg1L 0.0050 1 06/09/17 11:45 06/11/17 23:29 53-70-3 1,2-Dichlorobenzene ND mg1L 0.0050 1 06/09/17 11:45 06/11/17 23:29 95-50-1 1,3-Dichlorobenzene ND mg1L 0.0050 1 06/09/17 11:45 06/11/17 23:29 541-73.1 1,4-Dichloroben7ene NO mg1L 0.0050 1 06/09/17 11:45 06/11/17 23:29 106-46-7 3,3'-Dichlorobenzidine NO mg/L 0.025 1 06/09/17 11:45 06/11/17 23:29 91-94-1 2,4-Dichlorophenol NO mg1L 0.0050 1 06/09/17 11:45 06/11/17 23:29 120-83-2 Diethylphtha late NO mg1L 0.0050 1 06/09/17 11:45 06/11/17 23:29 84-66-2 2,4-Dimethylphenol NO mg1L 0.010 1 06/09/17 11:45 06/11/17 23:29 105-67-9 Dimethylphthalate NO mg1L 0.0050 1 06/09/17 11:45 06/11/17 23:29 131-11-3 Di-n-butylphthalate ND mg/L 0.0050 1 06/09/17 11:45 06/11/17 2129 84-74-2 4,6-Dinitro-2-methylphenol NO mg1L 0,020 1 06/09/17 11:45 06/11/17 23:29 534-52-1 2,4-Dinitrophenol ND mg1L 0.050 1 06/09/17 11:45 06/11/17 23:29 51-28-5 2,4-Dinitrotoluene NO mg/L 0.0050 1 06/09/17 11:45 06M1117 23:29 121-14-2 2,6-Dinitrotoluene ND mg1L 0.0050 1 06/09/17 11:45 06/11/17 23:29 606-20-2 Di-n-octylphthalate NO mg1L 0.0050 1 06/09/17 11:45 06/11/17 23:29 117-84-0 1,2-Diphenylhydrazine NO mg1L 0.0050 1 06/09/17 11:45 06/11/17 23:29 122-66-7 bis(2-Ethylhexyl)phthalate NO mg/L 0.0050 1 06/09/17 11:45 06/11/17 23:29 117-81-7 Fluoranthene NO mg/L 0.0050 1 06/09/17 11:45 06/11/17 23:29 20SA4-0 Fluorene NO mg/L 0.0050 1 06/09/17 11:45 06/11/17 23:29 86-73-7 Hexachloro-11,3-butadiene NO mg/L 0.0050 1 06/09/17 11:45 06/11/17 23:29 87-68-3 Hexachiorobenzene ND mg1L 0,0050 1 06/09/17 11:45 06/11/17 23:29 118-74-1 Hexachiorocyciopentadiene NO mg1L 0.010 1 06/09/17 11:45 06/11/17 23:29 77-47-4 Hexachloroethane NO mg1L 0.0050 1 06/09/17 11:45 06/11/17 23:29 67-72-1 Indeno(1,2,3-cd)pyrene ND mg1L 0.0050 1 06/09/17 11:45 06/11/17 23:29 193-39-5 Isophorone ND mg1L 0.010 1 06/09/17 11:45 06/11/17 23:29 78-59.1 Naphthalene NO mg1L 0.0050 1 06/09/17 11:45 06/11/17 23:29 91-20-3 Nitrobenzene NO mg1L 0.0050 1 06/09/17 11:45 06/11/17 23:29 98-95-3 2-Nitrophenol NO mg1L 0.0050 1 06/09/17 11:45 06/11/17 23:29 88-75-5 4-Nitrophenol NO mg1L 0,050 1 06/09/17 11:45 06/11/17 23:29 100-02-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 48 lacmnalytical *W..paaslabicorn ANALYTICAL RESULTS Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: 6117 STORMWATER Pace Project No.: 92342821 Sample: SDO #6 Lab ID: 92342821001 Collected: 06/05/17 07:30 Received: 06/05/17 10:53 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 N-Nitrosodi methyla mine ND mg1L 0.0050 1 06/09/17 11:45 06/11/17 23:29 62-75-9 N-Nitroso-di-n-propylamine ND mg1L 0.0050 1 06/09/17 11:45 06/11/17 23:29 621-64-7 N-Nitrosodiphenyiamine NO mg1L 0.010 1 06/09/17 11:45 06/11/17 23:29 86-30-6 Pentachlorophenol NO mg1L 0.010 1 06/09/17 11:45 06/11/17 23:29 87-86-5 Phenanthrene NO mglL 0.0050 1 06/09/17 11:45 06/11/17 23:29 85-01-8 Phenol NO mg1L 0.0050 1 06/09/17 11:45 06/11/17 23:29 108-95-2 Pyrene NO mg1L 0.0050 1 06/09/17 11:45 06/11/17 23:29 129-00-0 1,2,4-Trichlorobenzene NO mg1L 0.0050 1 06/09/17 11:45 06/11/17 23:29 120-82-1 2,4,6-Trichlorophenol NO mg1L 0.010 1 06/09/17 11:45 06/11/17 23:29 88-06-2 Surrogates Nitrobenzene-d5 (S) 57 % 10-120 1 06/09/17 11:45 06/11/17 23:29 4165-60-0 2-FIUDrobiphenyl (S) 74 % 15-120 1 06/09/17 11:45 06/11/17 23:29 321-60-8 Terphenyl-d14 (S) 78 % 11-131 1 06/09/17 11:45 06/11/17 23:29 1718-51-0 Phenol-d6(S) 21 % 10-120 1 06109/1711:45 06/11/17 23:29 13127-88-3 2-Fluorophenol (S) 35 % 10-120 1 06/09/17 11:45 06/11/17 23:29 367-12-4 2,4,6-Tribromophenol(S) 79 % 10-137 1 06/09/17 11:45 06/11/17 23:29 118-79-6 624 Volatile Organics Analytical Method: EPA 624 Acetone 0.011 mglL 0,010 1 06/0811719:40 67-64-1 Acrolein ND mg1L 0.0050 1 06/08/17 19:40 107-02-8 Acrylonitrile ND mg1L 0.050 1 06/08/17 19:40 107-13-1 Benzene NO mg1L 0,0020 1 06/0811719:40 71-43-2 Bromobenzene ND mglL 0.0020 1 06/0811719:40 108-86-1 Bromochloromethane NO mglL 0.0020 1 06/0811719!40 74-97-5 Bromodichloromethane NO mg1L 0.0020 1 06/0811719:40 75-27-4 Bromoform NO mglL 0.0020 1 0610811719:40 75-25-2 Bromomethane NO mg/L 0,0020 1 05/08/1719:40 74-83-9 2-Butanone (MEK) ND mg1L 0.0050 1 06/08/17 19:40 78-93-3 n-Butylbenzene NO mg1L 0.0050 1 0610811719:40 104-51-8 sec-Butylbenzene ND mg1L 0,0050 1 05/0811719:40 135-98-8 tert-Butylbenzene ND mg1L 0.0050 1 06/0811719:40 98-06-6 Carbon disulfide NO mg/L 0.0050 1 06/08/17 19:40 75-15-0 L1 Carbon tetrachloride ND mglL 0.0020 1 06/08/17 19:40 56-23-5 Chlorobenzene NO mg1L 0.0020 1 06/0811719:40 108-90-7 Chloroethane NO mg1L 0,0020 1 06/0811719:40 75-00-3 2-Chloroethylvinyl ether NO mg1L 0.0050 1 06/08/17 19:40 110-75-8 c2 Chloroform NO mg1L 0.0020 1 0610811719:40 67-66-3 Chloromethane NO mg1L 0.0020 1 06/08/1719:40 74-87-3 2-Chlorotoluene NO mg1L 0.0020 1 06/08/17 19:40 95-49-8 4-Chlorotoluene NO mg1L 0,0020 1 06/08/17 19:40 106-43-4 Dibromochloromethane NO mg1L 0.0020 1 06/08/17 19:40 124-48-1 1,2-Dibromoethane (EDB) NO mg1L 0.0020 1 06/08/17 19:40 106-93-4 Dibromomethane NO mg1L 0.0020 1 06/0811719:40 74-95-3 1,2-Dichlorobenzene NO mg1L 0.0020 1 06/08/17 19:40 95-50-1 1,3-Dichlorobenzene NO mg1L 0,0020 1 06/0811719:40 541-73-1 1,4-Dichlorobenzene NO mg1L 0.0020 1 06108/1719:40 106-46-7 1,1-Dichloroethane NO mg1L 0.0020 1 06/0811719:40 75-34-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2017 09:33 AM without the written consent of Pace Analytical Services. LLC. Page 6 of 48 aceAnalytical v"..pacdab&c= ANALYTICAL RESULTS Project: 6117 STORMWATER Pace Project No.: 92342821 Pace Analytical Services, LLC 205 East Meadow Road - Suite Eden, NC 27288 (336)623-8921 Sample: SOO #6 Lab ID: 92342821001 Collected: 06/05/17 07:30 Received: 061D5117 10:53 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 624 Volatile Organics Analytical Method: EPA 624 1,2-Dichioroethane ND mg1L 0.0020 1 06108/1719:40 107-06-2 1,1-Dichloroethene ND mg1L 0.0020 1 06108/1719:40 75-35-4 cis-1,2-Dichloroethene ND mg1L 0,0020 1 06108/1719:40 156-59-2 trans-1,2-Dichloroethene ND mg1L 0.0020 1 06108/1719:40 156-60-5 1,2-Dichloropropane ND mg1L 0.0020 1 06108/1719:40 78-87-5 1,3-Dichloropropane ND mg1L 0.0020 1 06108/1719:40 142-28-9 2,2-Dichloropropane ND mg1L 0,0050 1 0610811719A0 594-20-7 1,1-Dichloropropene ND mg1L 0.0020 1 0610811719:40 563-58-6 cis-1,3-Dichloropropene ND mg1L 0.0020 1 0610811719:40 10061-01-5 trans-1,3-Dichloropropene ND mg1L 0.0020 1 0610811719:40 10061-02-6 Ethylbenzene ND mg1L 0.0020 1 0610811719:40 100-41-4 Hexachloro-1,3-butadiene ND mg1L 0.0050 1 06/0811719:40 87-68-3 2-Hexanone ND mg1L 0.010 1 06/0811719740 591-78-6 lodomethane ND mg1L 0.010 1 0610811719:40 74-88-4 Isopropylbenzene (Cumene) ND mglL 0.0050 1 06/08/17 19A0 98-82-8 p-Isopropyltoluene ND mg1L 0.0050 1 0610811719740 99-87-6 Methylene Chloride ND mg1L 0.0020 1 06/08/17 19:40 75-09-2 4-Methyl-2-pentanone (MIBK) ND mg1L 0.010 1 06/08/17 19:40 108-10-1 Methyl-tert-butyl ether ND mg1L 0.0050 1 06/08/17 19A0 1634-04-4 Naphthalene ND mg1L 0.0050 1 06/08/17 19:40 91-20-3 n-Propylbenzene ND mg1L 0.0050 1 06/08/17 19:40 103-65-1 Styrene ND mg1L 0.0020 1 06/0811719:40 100.42-5 1,1,1,2-Tetrachloroethane ND mg1L 0.0020 1 06/08/17 19:40 630-20-6 1,1,2,2-Tetrachloroethane NO mg1L 0.0020 1 06/08/17 19:40 79-34-5 Tetrachloroethene ND mg1L 0.0020 1 06108/1719:40 127-18-4 Toluene NO mg1L 0.0020 1 0610811719:40 108-88-3 1,2,3-Trichlorobenzene NO mg1L 0.0020 1 06/0811719:40 87-61-6 1,2,4-Trichlorobenzene NO mg1L 0.0020 1 06/08/17 19:40 120-82-1 1,1,1-Trichloroethane NO mg1L 0.0020 1 06/08/17 19:40 71-55-6 1,1,2-Trichloroethane NO mg1L 0.0020 1 06/0811719:40 79-00-5 Trichloroethane NO mg1L 0.0020 1 06/08/17 19:40 79-01-6 Trichlorofluoromethane NO mg1L 0.0020 1 06/08/17 19:40 75-69-4 1,2,3-Trichloropropane NO mg1L 0.0020 1 06108/1719:40 96-18-4 1,12-Trichlorotrifluoroethane NO mg1L 0.0020 1 06108/1719:40 76-13-1 1,2,4-Trimethylbenzene NO mg1L 0.0020 1 06/08/17 19:40 95-63-6 1,3,5-Trimethylbenzene ND mg1L 0.0020 1 06/08/17 19:40 108-67-8 Vinyl acetate ND mg1L 0.0050 1 06/08/17 19:40 108-05-4 Vinyl chloride ND mg1L 0.0020 1 06/08/17 19:40 75-01-4 m&p-Xylene ND mg1L 0.0050 1 06108/1719:40 179601-23-1 o-Xylene ND mg1L 0.0050 1 06/08/1719:40 9547-6 Surrogates 4-Bromofluorobenzene (S) 100 % 70-130 1 06/08/17 19:40 460-00-4 Toluene-d8 (S) 104 % 70-130 1 06/08/17 19:40 2037-26-5 1,2-Dichloroethane-d4 (S) 89 % 70-130 1 06/08/17 19:40 17060-07-0 Date: 06/19/2017 09:33 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 48 (.�IaneAnalyfical wwwpecele6tcw ANALYTICAL RESULTS Pace Analytical Services,+LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: 6117 STORMWATER Pace Project No.: 92342821 Sample: SDO #7 Lab ID: 92342821002 Collected: 06105/17 07:45 Received: 06/05/17 10:53 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 2640D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 20.4 mg/L 5.0 1 06/05/17 12:16 4500H+ pH, Electrometric EDN Analytical Method: SM 4500-H+B pH at 25 Degrees C 6.8 Std. Units 1.0 1 06/05117 13:25 H6 1664 SGT-HEM, TPH Analytical Method: EPA 1664B Total Petroleum Hydrocarbons ND mg/L 5.0 1 06/07/17 07:05 608 GCS Pesticides and PCBs Analytical Method: EPA 608 Preparation Method: EPA 3510 Aldrin ND mg/L 0.000050 1 06109/17 13:07 06/12/17 21:50 309-00-2 alpha-BHC ND mg/L 0.000050 1 06109/17 13:07 06/12/17 21:50 319-84-6 beta-BHC ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 21:50 319-85-7 delta-BHC ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 21:50 319-86-8 gamma-BHC (Lindane) ND mg1L 0.000050 1 06109/17 13:07 06/12/17 21:50 58-89-9 Chlofdane (Technical) ND mg1L 0,00050 1 06/09117 13:07 06/12/17 21:50 57-74-9 4,4'-DDD ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 21:50 72-54-8 4,4'-DDE ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 21:50 72-55-9 4,4'-DDT NO mg1L 0.000050 1 06/09/17 13:07 06/12/17 21:50 50-29-3 Dieldrin NO mg/L 0.000050 1 06/09/17 13:07 06/12/17 21:50 60-57-1 Endosulfan I NO mg1L 0.000050 1 06/09/17 13:07 06/12/17 21:50 959.98-8 Endosulfan 11 NO mg1L 0.000050 1 06/09/17 13:07 06/12/17 21:50 33213-65-9 Endosulfan sulfate NO mg1L 0.000050 1 06/09/17 13:07 06/12/17 21:50 1031-07-8 Endrin NO mg1L 0.000050 1 06/09/17 13:07 06112I17 21:50 72-20-8 Endrin aldehyde NO mg1L 0.000050 1 06/09/17 13:07 06/12/17 21:50 7421-934 M1 Heptachlor NO mg1L 0.000050 1 06/09/17 13:07 06/12/17 21:50 76-44-8 Heptachlor epoxide NO mg1L 0.000050 1 06/09/17 13:07 06/12/17 21:50 1024-57-3 PCB- 1016 (Aroclor 1016) NO mg1L 0.00050 1 06/09/17 13:07 06/12/17 21:50 12674-il-2 PCB-1221 (Aroclor 1221) NO mg1L 0.00050 1 06/09/17 13:07 06/12/17 21:50 11104-28-2 PCB-1232 (Aroclor 1232) NO mg1L 0.00050 1 06/09/17 13:07 06/12/17 21:50 11141-16-5 PCB-1242 (Aroclor 1242) NO mg1L 0.00050 1 06/09/17 13:07 06/12/17 21:50 53469-21-9 PCB-1248 (Aroclor 1248) NO mg1L 0.00050 1 06/09/17 13:07 06/12/17 21:50 12672-29-6 PCB-1254 (Aroclor 1254) ND mg1L 0,00050 1 06/09/17 13:07 06/12/17 21:50 11097-69-1 PCB-1260 (Aroclor 1260) NO mg/L 0.00050 1 06/09/17 13:07 06/12/17 21:50 11096-82-5 Toxaphene ND mg1L 0.00050 1 06/09/17 13:07 06/12/17 21:50 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 9 % 20-110 1 06/09/17 13:07 06/12/17 21:50 877-09-8 1g,S0 Decachlorobiphenyl (S) 30 % 20-138 1 06/09/17 13:07 06/12/17 21:50 2051-24-3 200.7 MET ICP Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 Copper NO mg1L 0.0050 1 06/07/17 16:00 06/10/17 23:25 7440-50-8 Lead ND mg1L 0.0050 1 06/07/17 16:00 06/10/17 23:25 7439-92-1 Zinc ND mg1L 0,010 1 06/07/17 16700 06/10/17 23725 7440-66-6 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 525 Acenaphthene NO mg1L 0.0050 1 06/09/17 11:45 06112117 00:01 83-32-9 Acenaphthylene NO mg1L 0.0050 1 06/09/17 11:45 06112117 00:01 208-96-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 0611912017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 48 laceAnalyti+cal wwwpecele"cam ANALYTICAL RESULTS Project: 6117 STORMWATER Pace Project No.: 92342821 Pace Analytical Services, LLG 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Sample: SDO #7 Parameters Lab ID: 92342821002 Results Units Collected: 06/05/17 07:45 Report Limit DF Received: 06/05/17 10:53 Matrix: Water Prepared Analyzed CAS No. Qua] 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 Acetophenone ND mg/L 0.0050 1 06/09/17 11:45 06/12/17 00:01 98-86-2 Aniline ND mg1L 0.010 1 06/09/17 11:45 06/12/17 00:01 62-53-3 Anthracene ND mg/L 0,0050 1 06/09/17 11A5 06/12/17 00:01 120-12-7 Benzidine ND mg/L 0.050 1 06/09/17 11:45 06/12/17 00:01 92-87-5 L2 Benzo(a)anthracene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:01 56-55-3 Benzo(a)pyrene ND mg/L 0.0050 1 06/09/17 W45 06/12/17 00:01 50-32-8 Benzo(b)fluoranthene ND mg/L 0.0050 1 06/09/17 11:45 06/12/17 00:01 205-99-2 Benzo(g,h,i)perylene ND mg1L 0.0050 1 06109/1711A5 06112/1700:01 191-24-2 Benzo(k)fluoranthene ND mg1L 0.0050 1 0610911711A5 0611211700:01 207-08-9 4-Bromophenylphenyl ether ND mg/L 0.0050 1 06/09/17 11:45 06/12/17 00:01 101-55-3 Buty]benzylphthalate ND mg/L 0.0050 1 06/09/17 11A5 06/12/17 00:01 85-68-7 4-Chloro-3-methylphenol ND mg/L 0.0050 1 06/09/17 11:45 06/12/17 00:01 59-50-7 bis(2-Chloroethoxy)methene ND mg1L 0.010 1 06/09/17 11:45 06/12/17 00:01 111-91-1 bis(2-Chloroethyl) ether ND mg/L 0.0050 1 06/09/17 11A5 06/12/17 00:01 111-44-4 2-Chloronaphthalene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:01 91-58-7 2-Chlorophenol ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:01 95-57-8 4-Chlorophenylphenyl ether ND mg1L 0.0050 1 06/09/17 11:45 06/12117 00:01 7005-72-3 Chrysene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:01 218-01-9 Dibenz(a,h)anthracene ND mg/L 0.0050 1 06/09/17 11:45 06/12/17 00:01 53-70-3 1,2-Dichlorobenzene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:01 95-50-1 1,3-Dichlorobenzene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:01 541-73-1 1,4-Dichlorobenzene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:01 106-46-7 3,3'-Dichlorobenzidine ND mg1L 0,025 1 06/09/17 11:45 06MV17 00:01 91-94-1 2,4-Dichlorophenol ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:01 120-83-2 Diethylphthalate ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:01 84-66-2 2,4-Dimethylphenol ND mg1L 0.010 1 06/09/17 11:45 06/12/17 00:01 105-67-9 Dimethylphthalate ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:01 131-11-3 Di-n-butylphthalate ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:01 84-74-2 4,6-Dinitro-2-methylphenol ND mg1L 0.020 1 06/09/17 11:45 06/12/17 00:01 534-52-1 2,4-Dinitrophenol NO mg/L 0.050 1 06/09/17 11:45 06/12/17 00:01 51-28-5 2,4-Dinitrotoluene ND mg/L 0,0050 1 06/09/17 11:45 06/12/17 00:01 121-14-2 2,6-Dinitrotoluene ND mg/L 0.0050 1 06/09/17 11:45 06/12/17 00V 606-20-2 Di-n-octylphthalate ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:01 117-84-0 1,2-Diphenylhydrazine ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:01 122-66-7 bis(2-Ethylhexyl)phthalate ND mg/L 0.0050 1 06/09/17 11:45 06/12/17 00:01 117-81-7 Fluoranthene ND mg/L 0.0050 1 06/09/17 11:45 06/12/17 00:01 206-44-0 Fluorene ND mg1L 0,0050 1 06/09/17 11:45 06/12/17 00:01 86-73-7 Hexachloro-1,3-butadiene ND mg/L 0.0050 1 06/09/17 11:45 06/12/17 00:01 87-68-3 Hexachlorobenzene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:01 118-74-1 Hexachlorocyclopentadiene ND mg1L 0,010 1 06/09/17 11:45 06/12/17 00:01 77-47-4 Hexachloroethane ND mg1L 0.0050 1 06/09/1711A5 06/1211700:01 67-72-1 Indeno(1,2,3-cd)pyrene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:01 193-39-5 Isophorone ND mg1L 0.010 1 06/09/17 11:45 06/12/17 00:01 78-59-1 Naphthalene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:01 91-20-3 Nitrobenzene ND mg1L 0,0050 1 06/09/17 11:45 06/12/17 00:01 98-95-3 2-Nitrophenol ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:01 88-75-5 4-Nitrophenol ND mg/L 0.050 1 06/09/17 11:45 06/12/17 00:01 100-02-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/19/2017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 48 aceAnalytrcal *WWpecefabs.c= ANALYTICAL RESULTS Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: 6117 STORMWATER Pace Project No.: 92342821 Sample: SDO #7 Lab ID: 92342821002 Collected: 06/05117 07:45 Received: 06/05/17 10:53 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. C1uat 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 N-Nitrosodimethylamine NO mg1L 0.0050 1 06/09/17 11:45 06/12117 00:01 62-75-9 N-Nitroso-di-n-propylamine NO mglL 0,0050 1 06/09/17 11:45 06/12/17 00:01 621-64-7 N-Nitrosodiphenylamine NO mg1L 0.010 1 06/09/17 11:45 06/12/17 00:01 86-30-6 Pentachlorophenol NO mg1L 0.010 1 06/09/17 11:45 06/12/17 00:01 87-86-5 Phenanthrene NO mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:01 85-01-8 Phenol NO mglL 0.0050 1 06/09/17 11:45 06/12/17 00:01 108-95-2 Pyrene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:01 129-00-0 1,2,4-Trichlorobenzene NO mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:01 120-82-1 2,4,6-Trichlorophenol ND mg1L 0.010 1 06/09/17 11:45 06/12/17 00:01 88-06-2 Surrogates Nitrobenzene-d5 (S) 32 % 10-120 1 06109/17 11:45 06/12/17 00:01 4165-60-0 2-Fluorobiphenyl (S) 34 % 15-120 1 06/09/17 11:45 06/12/17 00:01 321-60.8 Terphenyl-d14(S) 58 % 11-131 1 06109117 11 :4 5 06/12/17 00:01 1718-51-0 Phenol-d6 (S) 9 % 10-120 1 06/09/17 11:45 06/12/17 00:01 13127-88-3 2-Fluorophenol (S) 16 % 10-120 1 06/09/17 11:45 06/12/17 00:01 367-12-4 2,4,6-Tdbromophenol(S) 55 % 10-137 1 06/0911711A5 06112/1700:01 118-79-6 624 Volatile Organics Analytical Method: EPA624 Acetone NO mg1L 0.010 1 0610811719:58 67-64-1 Acrolein NO mg1L 0.0050 1 0610811719:58 107-02-8 Acrylonitrile NO mg1L 0.050 1 06/08/1719:58 107-13-1 Benzene NO mg1L 0.0020 1 06/0811719:58 71-43-2 Bromobenzene NO mg1L 0.0020 1 06/0811719:58 108-86-1 Bromochloromethane NO mg1L 0.0020 1 06/08/1719:58 74-97-5 Bromodichloromethane NO mg1L 0.0020 1 06/08/1719:58 75-27-4 Bromoform NO mg1L 0.0020 1 06108/1719:58 75-25-2 Bromomethane NO mglL 0.0020 1 06/08/1719:58 74-83-9 2-Butenone (MEK) NO mg1L 0.0050 1 06/08/17 19:58 78-93-3 n-Butylbenzene NO mglL 0.0050 1 06/08/1719:58 104-51-8 sec-Butylbenzene NO mglL 0.0050 1 06/08/1719:58 135-98-8 tert-Butyl benzene NO mglL 0.0050 1 06108/1719:58 98-06-6 Carbon disulfide NO mg1L 0.0050 1 06/08/17 19:58 75-15-C Carbon tetrachloride NO mg1L 0.0020 1 06/08/17 19:58 56-23-5 Chlorobenzene NO mglL 0.0020 1 06108/1719:58 108-90-7 Chloroethane NO mglL 0.0020 1 06108/1719:58 75-00-3 2-Chloroethylvinyl ether NO mg1L 0.0050 1 06/08/17 19:58 110-75-8 Chloroform NO mg1L 0.0020 1 06108117 1 9:58 67-66-3 Chloromethane NO mglL 0.0020 1 06/0811719:58 74-87-3 2-Chlorotoluene NO mglL 0.0020 1 0610811719:58 95-49-8 4-Chlorotoluene NO mg1L 0.0020 1 06/0811719:58 106-43-4 Dibromochloromethane NO mg1L 0.0020 1 06/0811719:58 124-48-1 1,2-Dibromoethane (EDB) NO mg1L 0.0020 1 06108/17 19:58 106-93-4 Dibromomethane ND mg1L 0,0020 1 0610811719:58 74-95-3 1,2-Dichlorobenzene NO mg1L 0.0020 1 06108/1719:58 95-50-1 1,3-Dichlorobenzene NO mg1L 0.0020 1 06/08/1719:58 541-73-1 1,4-Dichlorobenzene NO mg1L 0.0020 1 061081W 19:58 106-46-7 1,1-Dichloroethane NO mg1L 0.0020 1 06108/1719:58 75-34-3 REPORT OF LABORATORY ANALYSIS SO L1 c2 This report shall not be reproduced, except in full, Date: 06119/2017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 48 aceAnalytical www.pacelab&=n ANALYTICAL RESULTS Project: 6/17 STORMWATER Pace Project No.: 92342821 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Sample: SOO #7 Lab ID: 92342821002 Collected: 06105/17 07:45 Received: 06/05117 10:53 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No, Qual 624 Volatile Organics Analytical Method: EPA 624 1,2-Dichloroethane ND mg/L 0.0020 1 06108/1719:58 107-06-2 1,1-Dichloroethene ND mglL 0.0020 1 06/08/17 19:58 75-35-4 cis-1,2-Dichloroethene ND rng1L 0,0020 1 06/08/17 19:58 156-59-2 trans-1,2-Dichloroethene ND mg/L 0.0020 1 06108/1719:58 156-60-5 1,2-Dichloropropane ND mg/L 0.0020 1 06/08/17 19:58 78-87-5 1,3-Dichloropropane ND mg1L 0,0020 1 06/08/17 19:58 142-28-9 2,2-Dichloropropane ND mg/L 0.0050 1 06/08/17 19:58 594-20-7 1,1-Dichloropropene ND mg/L 0.0020 1 0610811719:58 563-58-6 cis-1,3-Dichloropropene ND mg1L 0.0020 1 06/0811719:58 10061-01-5 trans-1,3-Dichloropropene ND mg/L 0.0020 1 0610811719:58 10061-02-6 Ethylbenzene ND mg/L 0,0020 1 06108/1719:58 100-41-4 Hexachloro-1,3-butadiene ND mg/L 0.0050 1 06108/1719:58 87-68-3 2-HexanOne NO mg/L 0.010 1 06/08/17 19:58 591-78-6 lodomethane ND mg/L 0,010 1 05/08/1719:58 74-88-4 Isopropylbenzene (Cumene) ND mg/L 0.0050 1 06/08/17 19:58 98-82-8 p-Isopropyltoluene ND mg/L 0.0050 1 06/08/17 19:58 99-87-6 Methylene Chloride ND mg/L 0.0020 1 06/08/17 19:58 75-09-2 4-Methyl-2-pentanone (MIBK) ND mg1L 0.010 1 06/08/17 19:58 108-10-1 Methyl-tert-butyl ether ND mg1L 0.0050 1 06/08/17 19:58 1634-04-4 Naphthalene ND mg1L 0.0050 1 06/0811719:58 91-20-3 n-Propylbenzene ND mg1L 0.0050 1 06/08/17 19:58 103-65-1 Styrene ND mg/L 0.0020 1 06/08/l719:58 100-42-5 1,1,1,2-Tetrachloroethane ND mg1L 0.0020 1 06108/1719:58 630-20-6 1,1,2,2-Tetrachloroethane ND mg1L 0.0020 1 06/08/17 19:58 79-34-5 Tetrachloroethene ND mg/L 0.0020 1 06/08/17 19:58 127-18-4 Toluene ND mg1L 0,0020 1 0610811719:58 108-88-3 1,2,3-Trichlorobenzene ND mg1L- 0.0020 1 0610811719:58 87-61-6 1,2,4-Trichlorobenzene ND mglL 0.0020 1 06/08/17 19:58 120-82-1 1, 1, 1 -Trichloroethane ND mg/L 0.0020 1 06/0811719:58 71-55-6 1,1,2-Trichloroethane ND mg/L 0,0020 1 0610811719:58 79-00-5 Trichloroethene NO mg/L 0.0020 1 06/0811719:58 79-01-6 Trichloroiluoromethane ND mg/L 0.0020 1 0610811719:58 75-69A 1,2,3-Tdchloropropane ND mg/L 0,0020 1 0610811719:58 96-18-4 1,1,2-Trichlorotrifluoroethane ND mg/L 0.0020 1 0610811719:58 76-13-1 1,2,4-Trimethylbenzene ND mg1L 0.0020 1 0610811719:58 95-63-6 1,3,5-Trimethylbenzene ND mg1L 0.0020 1 0610811719:58 108-67-8 Vinyl acetate ND mg/L 0.0050 1 06/08/17 19:58 108-05-4 Vinyl chloride ND mg/L 0.0020 1 06/08/17 19:58 75-01-4 m&p-Xylene ND mg1L 0.0050 1 0610811719:58 179601-23-1 o-Xylene ND mg1L 0.0050 1 06108/1719:58 95-47-6 Surrogates 4-Bromo{luorobenzene (S) 102 % 70-130 1 05/08/17 19:58 460-00-4 Toluene-d8 (S) 108 % 70-130 1 06/08/17 19:58 2037-26-5 1,2-Dichloroethane-d4 (S) 86 % 70-130 1 06/08/17 19:58 17060-07-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 48 aceAnalytical W"-Pscalebs.com ANALYTICAL RESULTS Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8925 Project: 6/17 STORMWATER Pace Project No.: 92342821 Sample: SDO #8 Lab ID: 92342821003 Collected: 06/05/17 0&00 Received: 06/05/17 10:53 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 17.9 mg/L 3A 1 06/05/17 12:17 4500H+ pH, Electrometric EDN Analytical Method: SM 4500-H+B pH at 25 Degrees C 5.9 Std. Units 1.0 1 06/05/17 13:25 H6 1664 SGT-HEM, TPH Analytical Method: EPA 16648 Total Petroleum Hydrocarbons ND mg/L 5.0 1 06/07/17 07:05 608 GCS Pesticides and PCBs Analytical Method: EPA 608 Preparation Method: EPA 3510 Aldrin ND mg/L 0.000050 1 06/09/17 13:07 06/12117 22:26 309-00-2 alpha-BHC ND mg/L 0.000050 1 06/09/17 13:07 06/12117 2226 319-84-5 beta-BHC ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 22:26 319-85-7 delta-BHC ND mg/L 0.000050 1 06/09/17 1107 06/12/17 2225 319-86-8 gamma-BHC (Lindane) ND mg1L 0.000050 1 06/09/17 13:07 06/12117 22726 58-89-9 Chlordane (Technical) ND mg1L 0.00050 1 06/09/17 13:07 06/12/17 22:26 57-74-9 4,4'-DDD ND mg1L 0.000050 1 06/09/17 1107 06/12/17 22:26 72-54-8 4,4'-DDE ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 22:26 72-55-9 4,4'-DDT ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 22:26 50-29-3 Dieldrin ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 22:26 60-57-1 Endosulfan I ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 22:26 959-98-8 Endosulfan II ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 22:26 33213-65-9 Endosulfan sulfate ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 22:26 1031-07-8 Endrin ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 22:26 72-20-8 Endrin aldehyde ND mg/L 0.000050 1 06/09/17 13:07 06/12/17 22:26 7421-93A Heptachlor ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 22:26 76-44-8 Heptachlor epoxide ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 22:26 1024-57-3 PCB-1016 (Aroclor 1015) ND mg1L 0.00050 1 06/09/17 13:07 06/12/17 22:26 12674-11-2 PCB-1221 (Aroclor 1221) ND mg1L 0.00050 1 06/09/17 13:07 06/12/17 22:26 11104-28-2 PCB-1232 (Aroclor 1232) ND mg1L 0.00050 1 06/09/17 13:07 06/12/17 22:26 11141-16-5 PCB-1242 (Aroclor 1242) ND mg/L 0.00050 1 06/09/17 13:07 06/12/17 22:26 53469-21-9 PCB-1248 (Aroclor 1248) ND mg1L 0.00050 1 06/09/17 13:07 06/12/17 22:26 12672-29.6 PCB-1254 (Aroclor 1254) NO mg1L 0.00050 1 06/09/17 13:07 06/12/17 22:26 11097-69-1 PCB-1260 (Aroclor 1260) ND mg1L 0.00050 1 06/09/17 13:07 06/12/17 22:26 11096-82-5 Toxaphene ND mg1L 0.00050 1 06/09/17 13:07 06/12/17 22:26 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 71 % 20-110 1 06/09/17 13:07 06/12/17 22:26 877-09-8 Decachlorobiphenyl (S) 40 % 20-138 1 06/09/17 13:07 06/12/17 22:26 2051-24-3 200.7 MET ICP Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 Copper ND mg1L 0.0050 1 06/07/17 16:00 06/10/17 23:29 7440-50-8 Lead ND mg1L 0.0050 1 06/07/17 16:00 06/10/17 23:29 7439-92-1 Zinc 0,061 mg/L 0.010 1 06/07/17 16:00 06/10/17 23:29 7440-66-6 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 Acenaphthene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:33 83-32-9 Acenaphthylene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:33 208-96-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 48 acMnalj cal www.pacelabsmm ANALYTICAL RESULTS Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: 6/17 STORMWATER Pace Project No.: 92342821 Sample: SDO #8 Lab ID: 92342821003 Collected: 06/05/17 08:00 Received: 06/05/17 10:53 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qua] 625 MSSV Analytical Method: EPA625 Preparation Method: EPA625 Acetophenone ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:33 98-86-2 Aniline ND mg/L 0.010 1 06/09/17 11:45 06/12/17 00:33 62-53-3 Anthracene NO mg/L 0.0050 1 06/09117 11:45 06/12/17 00:33 120-12-7 Benzidine ND mg1L 0.050 1 06/09/17 11:45 06/12/17 00:33 92-87-5 L2 Benzo(a)anthracene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:33 56-55-3 Benzo(a)pyrene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:33 50-32-8 Benzo(b)fluoranthene ND mg/L 0.0050 1 06/09/17 11:45 06/12/17 00:33 205-99-2 Denzo(g,h,i)perylene NO mg/L 0.0050 1 06/09/17 11:45 06/12/17 00:33 191-24-2 Benzo(k)fluoranthene NO mglL 0.0050 1 06/09/17 11:45 06/12/17 00:33 207-08-9 4-Bromopheny]phenyl ether ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:33 101-55-3 Butylbenzylphtha late NO mg/L 0.0050 1 06/09/17 11:45 06112/17 00:33 85-68-7 4-Chloro-3-methylphenol NO mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:33 59-50-7 bis(2-Chloroethoxy)methane NO mg1L 0.010 1 06/09/17 11:45 06/12/17 00:33 111-91-1 bis(2-Chloroethyl) ether NO mg1L 0.0050 1 06/09/17 11:45 06/12117 00:33 111-44-4 2-Chloronaphthalene NO mg1L 0.0050 1 06/09/17 11:45 06/12117 00:33 91-58-7 2-Chlorophenol NO mg/L 0.0050 1 06/09/17 11:45 06/12117 00:33 95.57-8 4-Chlorophenylphenyl ether ND mg1L 0.0050 1 06/09/17 11:45 06/12117 00:33 7005-72-3 Chrysene NO mg1L 0.0050 1 06/09/17 11:45 06/12117 00:33 218-01-9 Dibenz(a,h)anthracene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:33 53-70-3 1,2-Dichlorobenzene ND mg1L 0,0050 1 06/09/17 11:45 06/12117 00:33 95-50-1 1, 3-Dichloro benzene NO mg/L 0.0050 1 06/09/17 11:45 06/12117 00:33 541-73-1 1,4-Dichlorobenzene NO mg1L 0,0050 1 0610911711:45 06/1211700:33 106-46-7 3,3'-Dichlorobenzidine ND mg/L 0.025 1 06/09/17 11:45 06/12/17 00:33 91-94-1 2,4-Dichlorophenol NO mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:33 120-83-2 Diethylphthalate NO mg/L 0,0050 1 06/09/17 11:45 06/12/17 00:33 84-66-2 2,4-Dimethylphenol NO mg/L 0.010 1 06/09/17 11:45 06/12/17 00:33 105-67-9 Dimethylphthalate NO mg/L 0.0050 1 06/09/17 11:45 0611211700:33 131-li-3 Di-n-butyfphthalate NO mg/L 0.0050 1 06/09/17 11:45 06/12/17 00:33 84-74-2 4,6-Dinitro-2-methylphenol ND mg1L 0.020 1 06/09/17 11:45 06/12/17 00:33 534-52-1 2,4-Dinitrophenol NO mg/L 0,050 1 06/09/17 11:45 06/12/17 00:33 51-28-5 2,4-Dinitrotoluene ND mg1L 0.0050 1 06109117 11:45 06/12/17 00:33 121-14-2 2,6-Dinitrotofuene NO mg/L 0.0050 1 06/09/17 11:45 06/12/17 00:33 606-20-2 Di-n-octylphthalate NO mg/L 0,0050 1 06/09/17 11A5 06/12/17 00:33 117-84-0 1,2-Diphenylhydrazine NO mg1L 0.0050 1 06/09/17 11A5 06/12/17 00:33 122-66-7 bis(2-Ethylhexyl)phthalate NO mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:33 117-81-7 Fluoranthene NO mg1L 0.0050 1 06/09/17 11A5 06/12/17 00:33 206-44-0 Fluorene ND mg/L 0.0050 1 06/09/17 11:45 06/12/17 00:33 86-73-7 Hexachloro-1,3-butadiene ND mg/L 0,0050 1 06/09/17 11:45 06/12/17 00:33 87-58-3 Hexachlorobenzene NO mg/L 0.0050 1 0610911711A5 06/1211700:33 118-74-1 Hexachlorocyclopentadiene NO mg/L 0.010 1 06/09/17 11:45 06/12/17 00:33 77-47-4 Hexachloroethane NO mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:33 67-72-1 Indeno(1,2,3-cd)pyrene NO mg/L 0,0050 1 06/09/17 i1:45 06112/1700:33 193-39-5 fsophorone NO mg/L 0.010 1 06/09117 11:45 06/12/17 00:33 78-59-1 Naphthalene NO mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:33 91-20-3 Nitrobenzene NO mg/L 0.0050 1 06/09/17 11:45 06/12/17 00:33 98-95-3 2-Nitrophenol ND mg/L 0.0050 1 06/09/17 11:45 06/12/17 00:33 88-75-5 4-Nitrophenol NO mg/L 0.050 1 06/09/17 11:45 06/12/17 00:33 100-02-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 48 Pace Analytical Services, LLC 205 East Meadow Road - Suite A laneAnalytibal Eden, NC 27288 wwwpecelaEscm {33s}sz"sz1 ANALYTICAL RESULTS Project: 6117 STORMWATER Pace Project No.: 92342821 Sample: SDO #8 Lab lD: 92342821003 Collected: 06/05/17 08:00 Received: 06/05117 10:53 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No, Qua] 625 MSSV Analytical Method: EPA625 Preparation Method: EPA625 N-Nitrosodimethylamine ND mg1L 0.0050 1 06109/17 11:45 06/12/17 00:33 62-75-9 N-Nitroso-di-n-propylamine ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:33 621-64-7 N-Nitrosodiphenylamine ND mg1L 0.010 1 06109/17 11:45 06/12/17 00:33 86-30-6 Pentachlorophenol ND mg1L 0.010 1 06109/17 11:45 06/12/17 00:33 87-86-5 Phenanthrene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 00:33 85-01-8 Phenol ND mg1L 0.0050 1 06109/17 11:45 06/12/17 00:33 108-95-2 Pyrene ND mg1L 0,0050 1 061091W 11A5 06/12/17 00:33 129-00-0 1,2,4-Trichlorobenzene ND mg1L 0.0050 1 06/09/1711745 06/12/17 00:33 120-82-1 2,4,6-Trichlorophenol ND mg1L 0.010 1 06/09/17 11:45 06/12/17 00:33 88-06-2 Surrogates Nitrobenzene-d5 (S) 79 % 10-120 1 06/09/17 11:45 06/12/17 00:33 4165-60-0 2-Fluorobiphenyl (S) 89 % 15-120 1 06/09/17 11:45 06/12/17 00:33 321-60-8 Terphenyl-d14 (S) 83 % 11-131 1 06/09/17 11:45 06112117 00:33 1718-51-0 Phenol-d6 (S) 26 % 10.120 1 06/09/17 11:45 06112/17 00:33 13127-88-3 2-Fluorophenol (S) 38 % 10-120 1 06/09/17 11:45 06/12117 00:33 367-12-4 2,4,6-Tribromophenol (S) 93 % 10-137 1 06/09/17 11:45 06/12/17 00:33 118-79-6 624 Volatile Organics Analytical Method: EPA624 Acetone 0.010 mg1L 0.010 1 06/08117 20:16 67-64-1 Acrolein ND mg1L 0.0050 1 06/08117 20:16 107-02-8 Acrylonitrile ND mg1L 0.050 1 06/08/17 20:16 107-13-1 Benzene ND mg1L 0.0020 1 06/08117 20:16 71-43-2 Bromobenzene ND mg1L 0.0020 1 06/08117 20:16 108-86-1 Bromochloromethane ND mg1L 0.0020 1 06/08117 20:16 74-97-5 Bromodichloromethane ND mg1L 0.0020 1 06/08117 20:16 75-27-4 Bromoform ND mg1L 0.0020 1 06/08117 20:16 75-25-2 Bromomethane ND mg1L 0.0020 1 06/08/17 20:16 74-83-9 2-Butanone (MEK) ND mg1L 0.0050 1 06/08/17 20:16 78-93-3 n-Butylbenzene ND mg1L 0.0050 1 06/08/17 20:16 104-51-8 sec -Butyl benzene ND mg1L 0.0050 1 06/08/17 20:16 135-98.8 tent-Butylbenzene ND mg1L 0.0050 1 06/08/17 20:16 98-06-6 Carbon disulfde ND mg1L 0.0050 1 06/08/17 20:16 75-15-0 L1 Carbon tetrachloride ND mg1L 0.0020 1 06/08/17 20:16 56-23-5 Chlorobenzene ND mg1L 0.0020 1 06/08/17 20A6 108-90-7 Chloroethane ND mg1L 0.0020 1 06/08/17 20:16 75-00-3 2-Chloroethylvinyl ether ND mg1L 0.0050 1 06/08/17 20:16 110-75-8 c2 Chloroform ND mg1L 0.0020 1 06/08/17 20:16 67-66-3 Chloromelhane ND mg1L 0.0020 1 06/08/17 20:16 74-87-3 2-Chlorotoluene ND mg1L 0.0020 1 06/08/17 20:16 95-49-8 4-Chlorotoluene ND mg1L 0.0020 1 06/08/17 20:16 106-43-4 Dibromochloromethane ND mg1L 0.0020 1 06/08/17 20:16 124-48-1 1,2-Dibromoethane (EDB) ND mg1L 0.0020 1 06/08/17 20:15 106-93-4 Dibromomethane ND mg1L 0.0020 1 06/08/17 20:16 74-95-3 1,2-Dichlorobenzene ND mg1L 0.0020 1 06/08/17 20:16 95-50-1 1,3-Dichlorobenzene ND mg1L 0.0020 1 06108/1720:16 541-73-1 1,4-Dichlorobenzene ND mg1L 0.0020 1 0610811720:16 106-46-7 1,1-Dichloroethane ND mg1L 0.0020 1 0610811720:16 75-34-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 14 of 48 leAnalytical www.pacelabaoom Project: 6/17 STORMWATER Pace Project No.: 92342821 Sample: SDO #8 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 ANALYTICAL RESULTS Lab ID: 92342821003 Collected: 06/05/17 08:00 Received: 06/05/17 10:53 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 624 Volatile Organics Analytical Method: EPA624 1,2-Dichloroethane NO mg/L 0.0020 1 06/08/17 20:16 107-06-2 1,1-Dichloroethene ND mg/L 0.0020 1 0610811720:16 75-35-4 cis-1,2-Dichloroethene NO mg/L 0.0020 1 0610811720:16 156-59-2 trans-1,2-Dichloroethene NO mg/L 0.0020 1 06/08/17 20:16 156-60-5 1,2-Dichloropropane NO mg1L 0.0020 1 06/08/17 20:16 78-87-5 1,3-Dichloropropane NO mg1L 0.0020 1 06/08/17 20:16 142-28-9 2,2-Dichloropropane NO mg1L 0.0050 1 06/08/17 20:16 594-20-7 1,1-Dichloropropene NO mg1L 0.0020 1 06/08/17 20:16 563-58-6 cis- 1,3-Dichloropropene NO mg1L 0,0020 1 06/08/17 20:16 10061-01-5 trans- l,3-Dichloropropene NO mglL 0.0020 1 06108/1720:16 10061-02-6 Ethylbenzene ND mg/L 0.0020 1 06/08/17 20:16 100-41-4 Hexachloro-1,3-butadiene NO mg1L 0.0050 1 06/08/17 20:16 87-68-3 2-Hexanone ND mg1L 0.010 1 06/08/17 20:16 591-78-6 lodomethane ND mg1L 0.010 1 06/08/17 20:16 74-88-4 Isopropylbenzene (Cumene) NO mg1L 0.0050 1 06/08/17 20:16 98-82-8 p-Isopropyltoluene NO mg1L 0.0050 1 06/08/17 20:16 99-87-6 Methylene Chloride ND mg1L 0.0020 1 06/08/17 20:16 75-09-2 4-Methyi-2-pentanone (MIBK) NO mg/L 0.010 1 06/08/17 20:16 108-10-1 Methyl -tent -butyl ether NO mg1L 0.0050 1 06/08/17 20:16 1634-04-4 Naphthalene NO mg1L 0.0050 1 06/08/17 20:16 91-20-3 n-Propylbenzene NO mglL 0.0050 1 06/08/17 20:16 103-65-1 Styrene NO mglL 0.0020 1 06/08/17 20:16 100-42-5 1,1,1,2-Tetrachloroethane NO mglL 0.0020 1 06108/1720:16 630-20-6 1,1,2,2-Tetrachloroethane ND mglL 0.0020 1 06/08/17 20:16 79-34-5 Tetrachloroethene NO mg1L 0.0020 1 06/08/17 20:16 127-18-4 Toluene NO mg1L 0.0020 1 06/08/17 20:16 108-88-3 1,2,3-Trichlorobenzene NO mg/L 0.0020 1 06/08/17 20:16 87-61-6 1,2,4-Trichlorobenzene NO mg1L 0.0020 1 06/08/17 20:16 120-82-1 1,1,1-Trichloroelhane NO mg1L 0.0020 1 06108/17 20:16 71-55-6 1,1,2-Trichloroethene NO mg1L 0.0020 1 06/08/17 20:16 79-00-5 Tichloroethene NO mg1L 0.0020 1 06/08/17 20:16 79-01-6 Trichlorofluoromethane NO mg/L 0.0020 1 06/08/17 20:16 75-69-4 1,2,3-Trichloropropane NO mg/L. 0.0020 1 0610811720:16 96-18-4 1,1,2-TrichlorotMuoroethane NO mg/L 0,0020 1 0610811720:16 76-13-1 1,2,4-Trimethylbenzene NO mg1L 0.0020 1 0610811720:16 95-63-6 1,3,5-Trimethylbenzene NO mglL 0.0020 1 06/08/17 20:16 108-67-8 Vinyl acetate NO mglL 0.0050 1 06/08/17 20:16 108-05-4 Vinyl chloride , NO mglL 0.0020 1 06/0811720:16 75-01-4 m&p-Xylene NO mglL 0.0050 1 06/08/17 20:16 179601-23-1 o-Xylene NO mglL 0.0050 1 06/08/17 20:16 95-47-6 Surrogates 4-Bromofluorobenzene (S) 99 % 70-130 1 06/08/17 20:16 460-00-4 Toluene-d8 (S) 107 % 70-130 1 06/08/17 20:16 2037-26-5 1,2-Dichloroethane-d4 (S) 91 % 70-130 1 06/08/17 20:16 17060-07-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 15 of 48 lacmnalytical" wwwpecefabacom ANALYTICAL RESULTS Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: 6117 STORMWATER Pace Project No.: 92342821 Sample: SDO #11 Lab ID: 92342821006 Collected: 06/05/17 08:45 Received: 06/05/17 10:53 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No, Qual 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids NO mg1L 2.8 1 06/05/17 12:18 4500H+ pH, Electrometric EDN Analytical Method: SM 4500-H+B pH at 25 Degrees C 8.6 Std. Units 1.0 1 06/05/17 13:25 H6 1664 SGT HEM, TPH Analytical Method: EPA 1664B Total Petroleum Hydrocarbons NO mglL 5.0 1 06/07/17 07:05 608 GCS Pesticides and PCBs Analytical Method: EPA 608 Preparation Method: EPA 3510 Aldrin NO mg1L 0.000050 1 06/09/17 13:07 06/12/17 22:44 309-00-2 alpha-BHC ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 22:44 319-84-6 beta-BHC NO mg1L 0.000050 1 06/09/17 13:07 06/12/17 22:44 319-85-7 delta-BHC NO mg1L 0.000050 1 06/09/17 13:07 06/12/17 22:44 319-86-8 gamma-BHC (Lindane) ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 22:44 58-89-9 Chlordane (Technical) NO mglL 0.00050 1 06/09/17 13:07 06/12/17 22:44 57-74-9 4,4'-DDD NO mg1L 0.000050 1 06/09/17 13:07 06/12/17 22:44 72-54-8 4,4'-DDE NO mg1L 0.000050 1 06/09/17 13:07 06/12/17 22:44 72-55-9 4,4'-DDT ND mglL 0.000050 1 06/09/17 13:07 06/12/17 22:44 50-29-3 Dieldrin ND mglL 0.000050 1 06/09/17 13:07 06/12/17 22:44 60-57-1 Endosulfan I ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 22:44 959-98-8 Endosulfan II ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 22:44 33213-65-9 Endosulfan sulfate ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 22:44 1031-07-8 Endrin ND mg1L 0.000050 1 00/09/17 13:07 06/12/17 22:44 72-20-8 Endrin aldehyde ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 22:44 7421-93-4 Heptachlor ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 22:44 76-44-8 Heptachlor epoxide NO mg1L 0.000050 1 06/09/17 13:07 06/12/17 22:44 1024-57-3 PCB-1016 (Aroclor 1016) ND mg1L 0.00050 1 06/09/17 13:07 06/12/17 22:44 12674-11-2 PCB-1221 (Aroclor 1221) ND mg1L 0.00050 1 06/09/17 13:07 06/12/17 22:44 11104-28-2 PCB-1232 (Aroclor 1232) NO mg1L 0.00050 1 06/09117 13:07 06/12/17 22:44 11141-16-5 PCB-1242 (Aroclor 1242) ND mg1L 0.00050 1 06/09/17 13:07 06/12/17 22:44 53469-21-9 PCB-1248 (Aroclor 1248) ND mg1L 0.00050 1 06/09/17 13:07 06/12/17 22:44 12672-29-6 PC13-1254 (Aroclor 1254) ND mg1L 0.00050 1 06/09/17 13:07 06/12/17 22:44 11097-69-1 PCB-1260 (Aroclor 1260) NO mg1L 0.00051) 1 06/09/17 13:07 06/12/17 22:44 11096-82-5 Toxaphene NO mg1L 0.00050 1 06/09/17 13:07 06/12117 22:44 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 62 % 20-110 1 06/09/17 13:07 06/12117 22:44 877-09-8 Decachlorobiphenyl (S) 45 % 20-138 1 06/09/17 13:07 06/12/17 22:44 2051-24-3 200.7 MET ICP Analytical Method: EPA200.7 Preparation Method: EPA200.7 Copper NO mg1L 0.0050 1 06/07/17 16:00 06/10/17 23:32 744D-50-8 Lead NO mg1L 0.0050 1 06/07/17 16:00 06/10/17 23:32 7439-92-1 Zinc 0.019 mg1L 0.010 1 06/07/17 16:00 06/10/17 23:32 7440-66-6 625 MSSV Analytical Method: EPA625 Preparation Method: EPA625 Acenaphthene ND mg1L 0.0050 1 06/09/17 11:45 06/12J17 01:05 83-32-9 Acenaphthylene ND mg1L 0.0050 1 06/09/17 11:45 06112117 01:05 208-96-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 16 of 48 ace Analytical www.pacefebs.cam ANALYTICAL RESULTS Project: 6117 STORMWATER Pace Project No.: 92342821 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-B921 Sample: SDO #11 Parameters Lab ID: 92342821006 Results Units Collected: 06/05/17 08:45 Report Limit DF Received: 06/05/17 10:53 Matrix: Water Prepared Analyzed CAS No. Qual 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 Acetophenone ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 01:05 98-86-2 Aniline ND mg1L 0.010 1 06/09/17 11:45 06/12/17 01:05 62-53-3 Anthracene ND mg1L 0,0050 1 06/09/17 11:45 06/12/17 01:05 120-12-7 Senzidine ND mg/L 0.050 1 06/09/17 11:45 06/12/17 01:05 92-87-5 L2 Benzo(a)anthracene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 01:05 56-55-3 Benzo(a)pyrene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 01:05 50-32-8 Benzo(b)fluoranthene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 01:05 205-99-2 Benzo(g,h,i)perylene ND mg1L 0.0050 1 06/09/17 11:45 06/12117 01:05 191-24-2 Benzo(K)fluoranthene ND mglL 0.0050 1 06/09/17 11:45 06/12/17 01:05 207-08-9 4-Bromophenylphenyl ether ND mg/L 0,0050 1 06/09/17 11:45 06/12/17 01:05 101-55-3 6utylbenzylphthalate ND mglL 0.0050 1 06/09/17 11:45 06/12/17 01:05 65-68-7 4-Chloro-3-methylphenol ND mglL 0.0050 1 06/09/17 11:45 06/12/17 01:05 59-50-7 bis(2-Chloroethoxy)methane ND mglL 0.010 1 06/09/17 11:45 06/12/17 01:05 111-91-1 bis(2-Chloroethyl) ether ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 01:05 111-44-4 2-Chloronaphthalene ND mglL 0.0050 1 06109/1711:45 06/1211701:05 91-58-7 2-Chlorophenol ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 01:05 95-57-8 4-Chlorophenylphenyl ether ND mg/L 0.0050 1 06/09/17 11:45 06/12/17 01:05 7005-72-3 Chrysene ND mg1L 0.0050 1 06/09/17 11:45 06112/17 01:05 218-01-9 Dibenz(a,h)anthracene ND mg1L 0.0050 1 06109/1711:45 06112/17 01:05 53-70-3 1,2-Dichlorobenzene ND mg1L 0.0050 1 0610911711A5 0611211701:05 95-50-1 1,3-Dichlorobenzene ND mg1L 0,0050 1 06/09/17 11:45 06/12/17 01:05 541-73-1 1,4-Dichlorobenzene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 01:05 106-46-7 3,3'-Dichlorobenzidine ND mg1L 0.025 1 06/09/17 11:45 06/12/17 01:05 91-94-1 2,4-Dichlorophenol ND mg1L 0.0050 1 06/09/17 11:45 06/12117 01:05 120-83-2 Diethylphthalate ND mg1L 0.0050 1 06/09/17 11:45 06/12117 01:05 84-66-2 2,4-Dimethylphenol ND mg1L 0,010 1 06/09/1711A5 0611211701:05 105-67-9 Dimethylphthalate ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 01705 131-11-3 Di-n-butylphlhalate ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 01:05 84-74-2 4,6- Din itro-2-methylphenot ND mg/t_ 0.020 1 06/09/17 11:45 06/12/17 01:05 534-52-1 2,4-Dinitrophenol ND mglL 0.050 1 06/09/17 11:45 06/12117 01:05 51-28-5 2,4-1)initrotoluene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 01:05 121-14-2 2,6-Dinitrotoluene ND mglL 0,0050 1 06/09/17 11:45 06/12/17 01:05 606-20-2 Di-n-octylphthalate ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 01:05 117-84-0 1,2-Diphenylhydrazine ND mg1L 0,0050 1 06/09/17 11:45 06/12/17 01:05 122-66-7 bis(2-Ethylhexyl)phthalate ND mg1L 0.0050 1 06/09/17 11:45 06112/17 01:05 117-81-7 Fluoranthene ND mglL 0.0050 1 06/09/17 11:45 06/12/17 01:05 206-44-0 Fluorene ND mg1L 0.0050 1 06/09/17 11:45 06112/17 01:05 86-73-7 Hexachloro-1,3-butadiene ND mgIL 0.0050 1 06109/17 11:45 06112/17 01:05 87-68-3 Hexachlorobenzene ND mg1L 0.0050 1 06/09/17 11 A5 061121V 01:05 118-74-1 Hexachlorocyclopentadiene ND mg1L 0.010 1 06/09/17 11:45 06/12117 01:05 77-47-4 Hexachloroethane ND mg1L 0.0050 1 06/09/17 11:45 06112/17 01:05 67-72-1 Indeno(1,2,3-cd)pyrene ND mg1L 0,0050 1 06/09/17 11:45 06/12/17 01:05 193-39-5 Isophorone ND mg1L 0.010 1 06/09/17 11:45 06/12117 01:05 78-59-1 Naphthalene ND mg1L 0.0050 1 06/09/17 11:45 06/12117 01:05 91-20-3 Nitrobenzene ND mg1L 0.0050 1 06/09/17 11:45 06/12117 01:05 98-95-3 2-Nitrophenol ND mg1L 0.0050 1 06/09/17 11:45 06/12117 01:05 88-75-5 4-Nitrophenol ND mg1L 0,050 1 06/09/17 11:45 06/12117 01:05 100-02-7 REPORT OF LABORATORY ANALYSIS This report shell not be reproduced, except in full, Date: 06/19/2017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 47 of 48 aceAnalyticai` wwwpeasle68c= ANALYTICAL RESULTS Project: 6117 STORMWATER Pace Project No.: 92342821 Pace Analytical Services, LLC 205 East Meadow Road - SuiteA Eden, NC 27288 (336)623-8921 Sample: SDO #11 Parameters Lab ID: 92342821006 Results Units Collected: 06105/17 08:45 Report Limit DF Received: 06/05/17 10:53 Matrix: Water Prepared Analyzed CAS No. Qual 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 N-Nitrosodimethylamine ND mg1L 0.0050 1 06/09/17 11A5 06/12/17 01:05 62-75-9 N-Nitroso-di-n-propylamine ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 01:05 621-64-7 N-Nitrosod iphenyla mine ND mg1L 0.010 1 06/09/17 11A5 06/12/17 01:05 86-30-6 Pentachlorophenol ND mg1L 0.010 1 06/09/17 11:45 06/12/17 01:05 87-86-5 Phenanthrene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 01:05 85-01-8 Phenol ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 01:05 108-95-2 Pyrene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 01:05 129-00-0 1,2,4-Trichlorobenzene ND mglL 0.0050 1 06/0911711:45 06112/1701:05 120-82-1 2,4,6-Trichlorophenol ND mg1L 0,010 1 06/09/17 11;45 06/12/17 01:05 88-06-2 Surrogates Nitrobenzene-d5 (S) 77 % 10-120 1 06/09/17 11:45 06112/17 01:05 4165-60-0 2-Fluorobiphenyl (S) 89 % 15-120 1 06/09/17 11:45 06112117 01:05 321-60-8 Terphenyl-d14 (S) 96 % 11-131 1 06/09/17 11:45 06/12/17 01:05 1718-51-0 Phenol-d6 (S) 22 % 10-120 1 06/09/17 11:45 06/12/17 01:05 13127-88-3 2-Fluorophenol (S) 36 % 10-120 1 06/09/17 11:45 06/12/17 01:05 367-12-4 2,4,6-Tribromophenol (S) 92 % 10-137 1 06/09/17 11:45 06/12/17 01:05 118-79-6 624 Volatile Organics Analytical Method: EPA624 Acetone ND mglL 0.010 1 06/08/17 20:33 67-64-1 Acrolein ND mg1L 0,0050 1 06/08/17 20:33 107-02-8 Acrylonitrile ND mglL 0.050 1 06108/17 20:33 107-13-1 Benzene ND mg/t_ 0.0020 1 06/08/17 2033 71-43-2 Bromobenzene ND mglL 0,0020 1 06/08/17 20:33 108-86-1 Bromochloromethane ND mg1L 0.0020 1 06/08/17 20:33 74-97-5 Bromodichloromethane NO mg1L O.0020 1 06/08/17 20:33 75-27-4 Bromoform ND mglL 0,0020 1 06/08/17 20:33 75-25-2 Bromomethane ND mglL 0.0020 1 06/08/17 20:33 74-83-9 2-Butanone (MEK) ND mglL 0.0050 1 06/08/17 2033 78-93-3 n-Butylbenzene ND mglL 0.0050 1 06/08/17 20:33 104-51-8 sec-Butylbenzene ND mglL 0.0050 1 06/08/17 20:33 135-98-8 tent-Butylbenzene ND mg1L 0.0050 1 06/08/17 20:33 98-06-6 Carbon disulfide ND mg1L 0.0050 1 06/08/17 20:33 75-15-0 L1 Carbon tetrachloride ND mglL 0,0020 1 06/08/17 20;33 56-23-5 Chlorobenzene ND mglL 0.0020 1 06/08/17 20:33 108-90-7 Chloroethane ND mglL 0.0020 1 06/08/17 20:33 75-00-3 2-Chloroethylvinyl ether ND mg1L 0,0050 1 06/08/17 20:33 110-75-8 c2 Chloroform ND mg1L 0.0020 1 06/08/17 20:33 67-66-3 Chloromethane ND mglL 0.0020 1 06/08/17 20:33 74-87-3 2-Chlorotoluene ND mglL 0.0020 1 06/08/17 20:33 95-49-8 4-Chlorotoluene ND mg1L 0.0020 1 06/08/17 20:33 106-43-4 Dibromochloromethane ND mglL 0,0020 1 06/08/17 20:33 124-48-1 1,2-Dibromoethane (EDB) ND mg1L 0.0020 1 06/08/17 20:33 106-93-4 Dibromomethane ND mg1L 0.0020 1 06/08/17 20:33 74-95-3 1,2-Dichlorobenzene ND mg1L 0,0020 1 06/08/17 20:33 95-50-1 1,3-Dichlorobenzene ND mg1L 0.0020 1 06/08/17 20:33 541-73-1 1,4-Dichlorobenzene ND mglL 0.0020 1 06/08/17 20:33 106-46-7 1,1-Dichloroethane NO mg1L 0.0020 1 06/08/17 20:33 75-34-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date; 06/1912017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 18 of 48 aceAnalytical xww.peorlabscnrrr ANALYTICAL RESULTS Project: 6117 STORMWATER Pace Project No.: 92342821 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Sample: SDO #11 Lab ID: 92342821006 Collected: 06/05/17 08:45 Received: 06/05/17 10:53 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Oual 624 Volatile Organics 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1, 2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis- 1,3-D ichloroprope ne trans- l,3-Dichloropropene Ethylbenzene Hexa chloro-1,3-butadiene 2-Hexanone lodomethane Isopropylbenzene (Cumene) p-Isopropyltoluene Methylene Chloride 4-Methyl-2-pentanone (MIBK) Methyl-tert-butyl ether Naphthalene n-Propyibenzene Styrene 1, 1, 1,2-Tetrachloroethane 1,1,2, 2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichlo roethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,1,2-Trichlorothfluoroethane 1,2,4-Trimethylbenzene 1, 3,5-Trimethylbenzene Vinyl acetate Vinyl chloride m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) Toluene-d8 (S) 1,2-Dichloroethane-d4 (S) Dale: 06/19/2017 09:33 AM Analytical Method: EPA 624 ND mg1l_ 0.0020 1 06/08/17 20:33 107-06-2 ND mg1L 0.0020 1 06108/17 20:33 75-35-4 ND mg/L 0.0020 1 06/08/17 20:33 156-59-2 ND mg/L 0,0020 1 06/08/17 20:33 156-60-5 ND mg/L 0.0020 1 06/08/17 20:33 78-87-5 ND mg/L 0.0020 1 06/08/17 20:33 142-28-9 ND mg1L 0.0050 1 06/08/17 20:33 594-20-7 ND mg/L 0.0020 1 06/08/17 20:33 563-58-6 ND mglL 0,0020 1 06/08/17 20:33 10061-01-5 ND mg/L 0.0020 1 06/08/17 20:33 10061-02-6 ND mg/L 0.0020 1 06/08/17 20:33 100-41-4 ND mg/L 0,0050 1 06/08/17 20:33 87-68-3 ND mg/L 0.010 1 06/08/17 20:33 591-78-6 ND mg/L 0.010 1 06/08/17 20:33 74-88-4 ND mg/L 0,0050 1 06/08/17 20:33 98-82-8 ND mg/L 0.0050 1 06/08/17 20:33 99-87-6 ND mg/L 0.0020 1 06/08/17 20:33 75-09-2 ND mg/L 0,010 1 06/08/17 20:33 108-10-1 ND mg/L 0.0050 1 06/08/17 20:33 1634-04-4 ND mg/L 0.0050 1 06/08/17 20:33 91-20-3 ND mg/L 0,0050 1 06/08/17 20:33 103-65-1 ND mg1L 0.0020 1 06/08/17 20:33 100-42-5 NO mg/L 0A020 1 06/08/17 20:33 630-20-6 ND mg/L 0.0020 1 06/08/17 20:33 79-34-5 ND mg/L 0.0020 1 06/08/17 20:33 127-18-4 ND mg/L 0.0020 1 06/08/17 20:33 108-88-3 ND mg/L 0.0020 1 06/08/17 20:33 87-61-6 ND mg& 0.0020 1 06/08/17 20:33 120-82-1 ND mg/L 0.0020 1 06/08/17 20:33 71-55-6 ND mg/L 0.0020 1 06/08/17 20:33 79-00-5 ND mg/L 0.0020 1 06/08/17 20:33 79-01-6 ND mg1L 0.0020 1 06/08/17 20:33 75-69-4 ND mg/L 0.0020 1 06/08/17 20:33 96-18-4 ND mg1L 0,0020 1 06/08/17 20:33 76-13-1 ND mg/L 0.0020 1 06/08/17 20:33 95-63-6 ND mglL 0.0020 1 06/08/17 20:33 108-67-8 ND mg1L 0.0050 1 06/08/17 20:33 108-05-4 ND mg1L 0.0020 1 06/08/17 20:33 75-01-4 ND mg/L 0.0050 1 0610811720:33 179601-23-1 ND mglL 0.0050 1 06/08/17 20:33 95-47-6 103 % 70-130 1 06/08/17 20:33 460-00-4 110 % 70-130 1 06/08/17 20:33 2037-26-5 91 % 70-130 1 06/08/17 20:33 17060-07-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 48 D IacleAnalytical (�rpacefabs oom ANALYTICAL RESULTS Project: 6117 STORMWATER Pace Project No.: 92342821 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Sample: SDO013 Lab ID: 92342821008 Collected: 06/0511709:15 Received: 06/05/1710:53 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 3.5 mglL 2.5 1 06/05117 12:18 4500H+ pH, Electrometric EDN Analytical Method: SM 4500-H+B pH at 25 Degrees C 6.4 Std. Units 1.0 1 06/05/17 13:25 H6 1664 SGT-HEM, TPH Analytical Method: EPA 1664B Total Petroleum Hydrocarbons ND mg/L 5.0 1 06/07/17 07:06 608 GCS Pesticides and PCBs Analytical Method: EPA 608 Preparation Method: EPA 3510 Aldrin ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 23:20 309-00-2 alpha-BHC ND mglL 0.000050 1 06109/17 13:07 06/12/17 23:20 319-84-6 beta-BHC ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 23:20 319-85-7 delta-BHC ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 23:20 319-86-8 gamma-BHC (Lindane) ND mg1l. 0.000050 1 06/09/17 13:07 06/12/17 23:20 58-89.9 Chlordane (Technical) ND mg1L 0.00050 1 06/09/17 13:07 06/12/17 23:20 57-74-9 4,4'-DDD ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 23:20 72-54-8 4,4'-DDE ND mg1L 0,000050 1 06/09/17 13:07 05/12/17 23:20 72-55-9 4,4'-DDT ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 23:20 50-29-3 Dieldrin ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 23:20 60-57.1 Endosulfan I ND mg1L 0,000050 1 06/09/17 13:07 06/12/17 23:20 959-98-8 Endosulfan II ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 23:20 33213-65-9 Endosutfan sulfate ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 23:20 1031-07-8 Endrin ND mg1L 0.000050 1 06/09/17 13:07 06/12/17 23:20 72-20-8 Endrin aldehyde ND mg1L 0.000060 1 06/09117 13:07 06/12/17 23:20 7421-93-4 Heptachlor ND mg1L 0,000050 1 06/09/17 13:07 06/12/17 23:20 76-44-6 Heptachlor epoxide ND mglL 0.000050 1 06/09/17 13:07 06/12/17 23:20 1024-57-3 PCB-1016 (Aroclor 1016) ND mg1L 0.00050 1 06/09/17 13:07 06/12/17 23:20 12674-11-2 PCB-1221 (Aroclor1221) ND mg1L 0.00050 1 0610911713:07 06/12/17 23:20 11104-28-2 PCB-1232 (Aroclor 1232) ND mg1L 0.00050 1 06/09/17 13:07 06/12/17 23:20 11141-16-5 PCB-1242 (Aroclor 1242) ND mg1L 0.00050 1 06/09/17 13:07 06/12/17 23:20 53469-21-9 PCB-1248 (Aroclor 1248) ND mg1L 0.00050 1 06/09/17 13:07 06/12/17 23:20 12672-29-6 PCB-1254 (Aroclor 1254) ND mg1L 0.00050 1 06/09/17 13:07 06/12/17 23:20 11097.69-1 PCB-1260 (Aroclor 1260) ND mglL 0.00050 1 06/09/17 13:07 06/12117 23:20 11096-82-5 Toxaphene ND mg1L 0.00050 1 06/09/17 13:07 06/12/17 23:20 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 39 % 20-110 1 06/09/17 13:07 06/12/17 23:20 877-09-8 Decachlorobiphenyl (S) 32 % 20-138 1 06/09/17 13707 06/12/17 23:20 2051-24-3 200.7 MET ICP Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 Copper 0.0059 mg1L 0,0050 1 06/07/17 16:00 06/10/17 23:35 7440-50-8 Lead ND mg1L 0.0050 1 06/07/17 16:00 06/10/17 23:35 7439-92-1 Zinc 0.024 mg1L 0.010 1 06/07/17 16:00 06/10/17 23:35 744D-66-6 625 MSSV Analytical Method: EPA625 Preparation Method: EPA 625 Acenaphthene ND mg1L 0,0050 1 06/09/17 11:45 06/12/17 01:37 83-32-9 Acenaphthylene ND mg1L 0,0050 1 06/09/17 11:45 06/12/17 01:37 208-96-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date: 06/19/2017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 20 of 48 Pace Anatytical Services, LLC 205 East Meadow Road - Suite aceAnalytical ANALYTICAL RESULTS Project: 6117 STORMWATER Pace Project No.: 92342821 Eden, NC 27288 (3 36)623-892 1 Sample: SDO #13 Parameters Lab ID: 92342821008 Results Units Collected: 06/05/17 09:15 Report Limit DF Received: 06/05/17 10:53 Matrix: Water Prepared Analyzed CAS No. Qual 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 Acetophenone NO mg1L 0.0050 1 06/09/17 11:45 06/12/17 01:37 98-86-2 Aniline NO mg1L 0.010 1 06/09/17 11:45 06/12/17 01:37 62-53-3 Anthracene NO mglL 0.0050 1 06/09/17 11:45 06/12/17 01:37 120-12-7 Senzidine NO mglL 0,050 1 06/09/17 11A5 06/12/17 01:37 92-87-5 L2 Senzo(a)anthracene NO mg1L 0.0050 1 06/09/17 11:45 06/12/17 01:37 56-55-3 Benzo(a)pyrene ND mglL 0.0050 1 06/09/17 11:45 06/12/17 01:37 50-32-8 Benzo(b)fluoranthene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 01:37 205-99-2 Benzo(g,h,l)perylene ND mg1L 0,0050 1 06/09/17 11:45 06/12/17 01:37 191-24-2 Benzo(k)fluoranthene ND mg1L 0.0050 1 06109/17 11:45 06/12/17 01:37 207-08-9 4-Bromophenylphenyl ether ND mglL 0.0050 1 06109/17 11:45 06/12/17 01:37 101-55-3 Butylbenzylphthalate ND mg1L 0.0050 1 06/09/17 11;45 06/12/17 01:37 85-68-7 4-Chloro-3-methylphenol ND mglL 0.0050 1 06109/17 11:45 06/12/17 01:37 59.50-7 bis(2-Chloroethoxy)methane ND mg1L 0.010 1 06109/17 11:45 06/12/17 01:37 111-91-1 bis(2-Chloroethyl) ether ND mg1L 0.0050 1 06109/17 11:45 06/12/17 01:37 111-44-4 2-Chloronaphthalene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 01:37 91.58-7 2-Chlorophenol ND mg1L 0.0050 1 06/09/17 11A5 06/12/17 01:37 95-57-8 4-Chlorophenylphenyl ether ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 01:37 7005-72-3 Chrysene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 01:37 218-01-9 Dit)enz(a,h)anthracene ND m911- 0,0050 1 06/09/17 11:45 06/12/17 01:37 53-70-3 1,2-Dichlorobenzene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 01:37 95-50-1 1,3-Dichlorobenzene ND mg1L 0.0050 1 06/09117 11:45 06/12/17 01:37 541-73-1 1,4-Dichlorobenzene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 01:37 106-46-7 3,3'-Dichlorobenzidine ND mg1L 0.025 1 06/09/17 11A5 06/12/17 01:37 91-94-1 2,4-Dichlorophenol ND mglL 0.0050 1 06/09/17 11:45 06112W 01:37 120-83-2 Diethylphthalate ND mglL 0.0050 1 06/09/17 11:45 06/12/17 01:37 84-66-2 2,4-Dimethylphenol ND mg1L 0.010 1 06/09/17 11:45 06/12/17 01:37 105-67-9 Dimethylphthalate ND mglL 0.0050 1 06/09/17 11:45 06/12117 01:37 131-11-3 Di-n-butylphthalate ND mg1L 0.0050 1 06/09/17 11:45 06112/17 01:37 84-74-2 4,6-Dinitro-2-methylphenol ND mg1L 0.020 1 06/09/17 11:45 06/12/17 01:37 534-52-1 2,4-Dinitrophenol ND mg1L 0.050 1 06/09/17 11:45 06/12117 01:37 51-28-5 2,4-Dinitrotoluene ND mg1L 0.0050 1 06/09/17 11:45 06112117 01:37 121-14-2 2,6-Dinitrotoluene ND mglL 0.0050 1 06/09/17 11:45 06/12J17 01:37 606-20-2 Di-n-octylphthalate ND mg1L 0.0050 1 06/09/17 11;45 06/12117 01:37 117-84-0 1,2-Diphenylhydrazine ND mg1L 0.0050 1 06/09/17 11:45 06/12117 01:37 122-66-7 bis(2-Ethylhexyl)phthalate ND mg1L 0.0050 1 06/09/17 11:45 06/12117 01:37 117-81-7 Fluoranthene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 01:37 206-44-0 Fluorene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 01:37 86-73-7 Hexachloro-1,3-butadiene ND mgfL. 0.0050 1 06/09/17 11:45 06/12/17 01:37 87-68-3 Hexachlorobenzene ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 01:37 118-74-1 Hexachlorocyclopentadiene ND mglL 0.010 1 0610911711A5 06112/17 01:37 77-47-4 Hexachloroethane ND mg1L 0.0050 1 06/09/17 11:45 06/12117 01:37 67-72-1 Indeno(1,2,3-cd)pyrene ND mg1L 0.0050 1 06/09/17 11:45 06112117 01:37 193-39-5 Isophorone ND mglL 0.010 1 06/09/17 11A5 06112/17 01:37 78-59-1 Naphthalene NO mg1L 0.0050 1 0610911711:45 06/12/1701737 91-20-3 Nitrobenzene NO mg1L 0.0050 1 06/09/17 11:45 06/12/17 01:37 98-95-3 2-Nitrophenol ND mglL 0.0050 1 06/09/17 11;45 06/12/17 01:37 88-75-5 4-Nitrophenol ND mg/L 0.050 1 06/09/17 11:45 06/12/17 01:37 100-02-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 21 of 48 (�IacleAnalytical www.pacefab&c= ANALYTICAL RESULTS Project: 6117 STORMWATER Pace Project No.: 92342821 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Sample: SDO #13 Lab ID: 92342821008 Collected: 06/05/17 09:15 Received: 06/06/17 10:53 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 625 MSSV Analytical Method: EPA625 Preparation Method: EPA625 N-Nitrosodimethylamine ND mg1L 0.0050 1 0610911711A5 0611211701:37 62-75-9 N-Nitroso-di-n-propylamine ND mg1L 0.0050 1 06/09/17 11:45 06/12/17 01:37 621-64-7 N-Nitrosodiphenylamine ND mgk 0.010 1 06109/17 11:45 06/12/17 01:37 86-30-6 Pentachlorophenol ND mglL 0.010 1 06109/17 11 A5 06/12/17 01:37 87-86-5 Phenanthrene ND mg1L 0.0050 1 06109/17 11:45 06/12/17 01:37 85-01-8 Phenol ND mg1L 0.0050 1 06109/17 11:45 06/12/17 01:37 108-95-2 Pyrene ND mglL 0.0050 1 06109/17 11 A5 06/12/17 01:37 129-00-0 1,2,4-Trichlorobenzene ND mg1L 0.0050 1 0610911711:45 06/1211701:37 120-82-1 2,4,6-Trichlorophenol ND mg1L 0.010 1 06/09117 11:45 06/12/17 01:37 88-06-2 Surrogates Nitrobenzene-d5 (S) 78 % 10-120 1 06/09/17 11:45 06/12/17 01:37 4165-60-0 2-Fluorobiphenyl (S) 88 % 15-120 1 06/09/17 11:45 06/12/17 01:37 321-60.8 Terphenyl-d14(S) 76 % 11-131 1 0610911711:45 06/12/17 01:37 1718-51-0 Phenol-d6 (S) 22 % 10-120 1 06/09/17 11:45 06/12/17 01:37 13127-88-3 2-Fluorophenol (S) 36 % 10-120 1 06/09/17 11:45 06/12/17 01:37 367-12-4 2,4,6-Tribromophenol (S) 86 % 10-137 1 06/09/17 11:45 06/12/17 01:37 118-79-6 624 Volatile Organics Analytical Method: EPA624 Acetone ND mglL 0.010 1 06/08/17 21:09 67-64-1 M1 ACrolein ND mglL 0.0050 1 06/08/17 21:09 107-02-8 Acrylonitrile ND mg1L 0.050 1 06/08/17 21:09 107-13-1 Benzene ND mg1L 0.0020 1 06/08/17 21:09 71-43-2 Bromobenzene NO mglL 0.0020 1 06/08/17 21:09 108-86-1 Bromochloromethane ND mg1L 0.0020 1 06/08/17 21:09 74-97-5 Bromodichloromethane ND mglL 0.0020 1 06/08/17 21:09 75-27-4 Bromoform NO mg1L 0.0020 1 06/08/17 21:09 75-25-2 Bromomethane ND mglL 0.0020 1 06/08/17 21:09 74-83-9 2-Butanone (MEK) ND mg1L 0.0050 1 06/08/17 21:09 78-93-3 n-Butylbenzene ND mg1L 0,0050 1 06/08/17 21:09 104-51-8 sec-Butylbenzene ND mglL 0.0050 1 06/08/17 21:09 135-98-8 tert-Butylbenzene NO mg1L 0.0050 1 06/08/17 21:09 98-06-6 Carbon disulfide ND mg1L 0.0050 1 06/08/17 21:09 75-15-0 L1,M0 Carbon tetrachloride ND mglL 0.0020 1 06/08/17 21:09 56-23-5 Chlorobenzene ND mg1L 0,0020 1 06/08/17 21:09 108-90-7 Chloroethane ND mg/L 0.0020 1 06/08/17 21:09 75-00-3 2-Chloroethyivinylether ND mg1L 0.0050 1 06/08/17 21:09 110-75-8 M1,c2 Chloroform ND mg1L 0.0020 1 06/08/17 21:09 67-66-3 Chloromethane ND mg1L 0.0020 1 06/08/17 21:09 74-87-3 2-Chlorotoluene ND mg1L 0.0020 1 06/08/17 21:09 95-49-8 4-Chlorotoluene ND mg1L 0.0020 1 06/08/17 21:09 10643-4 Dibromochloromethane ND mg1L 0.0020 1 06/08/17 21:09 124-48.1 1,2-Dibromoethane (EDB) ND mg1L 0.0020 1 06/08/17 21:09 106-93-4 Dibromomethane ND mg1L 0.0020 1 06/08/17 21:09 74-95-3 1,2-Dichlorobenzene ND mg1L 0.0020 1 06/0811721:09 95-50-1 1,3-Dichlor6benzene ND mg1L 0.0020 1 0610811721:09 541-73-1 1,4-Dichlorobenzene ND mg1L 0,0020 1 06108/1721:09 106-46.7 1,1-Dichloroethane ND mg1L 0.0020 1 06/0811721:09 75-34-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 22 of 48 laneAnalytkalo WffW-Paoalabs.= ANALYTICAL RESULTS Project: 6117 STORMWATER Pace Project No 92342821 Pace Ana "cal Services, LLC 205 East Meadow Road - Suite A Eden, NC 272a8 (336)623-8921 Sample: SDO #13 Lab ID: 92342821008 Collected: 06/05/17 09:15 Received: 06/05/17 10:53 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 624 Volatile Organics Analytical Method: EPA624 1,2-Dichloroethane ND mg/L 0.0020 1 06/0811721:09 107-06-2 1,1-Dichloroethene ND mg/L 0.0020 1 06/08/17 21:09 75-35-4 cis-1,2-Dichloroethene ND mg/L 0.0020 1 06/08/17 21:09 156-59-2 trans- l,2-Dichloroethene ND mg1L 0.0020 1 06/08/17 21:09 156-60-5 1,2-Dichloropropane ND mg/L 0.0020 1 06/08/17 21:09 78-87-5 1,3-Dichloropropane ND mg/L 0.0020 1 06/08/17 21:09 142-28-9 2,2-Dichloropropane ND mglL 0.4050 1 06/08/17 21:09 594-20-7 1,1-Dichloropropene ND mg/L 0=20 1 06/08/17 21:09 563-58-6 cis-1,3-Dichloropropene ND mglL 0.0020 1 06/08/17 21:09 10061-01-5 trans- 1,3-Dichloropropene ND mg/L 0.0020 1 06/08/17 21:09 10061-02-6 Ethylbenzene ND mg/L 0,0020 1 06/08/17 21:09 100-41-4 Hexachloro-1,3-butadiene ND mglL 0.0050 1 06/08/17 21:09 87-68-3 2-Hexanone ND mg/L 0.010 1 06/08/17 21:09 591-78-6 Iodomethane ND mg/L 0.010 1 06/08/17 21:09 74-88-4 Isopropylbenzene (Cumene) ND mg/L 0.0050 1 06/08/17 21:09 98-82-8 p-Isopropyltoluene ND mg/L 0.0050 1 06/08/17 21:09 99-87-6 Methylene Chloride ND mg/L 0.0020 1 06/08/17 21:09 75-09-2 4-Mothyt-2-pentanone (MIBK) ND mg/L 0.010 1 06/08/17 21:09 108-10-1 Methyl-tert-butyl ether ND mg/L 0.0050 1 06/08/17 21:09 1634-04-4 Naphthalene ND mg/L 0.0050 1 06/08/17 21:09 91-20-3 n-Propylbenzene ND mg/L 0.0050 1 06/08/17 21:09 103-65-1 Styrene ND mg/L 0.0020 1 06/08/17 21:09 100-42-5 1,1,1,2-Tetrachloroethane ND mg/L 0.0020 1 06/0811721:09 630-20-6 1,1,2,2-Tetrachloroethane ND mg/L 0.0020 1 06/08/17 21:09 79-34-5 Tetrachloroethene ND mg/L 0.0020 1 06/08/17 21:09 127-18-4 Toluene ND mg/L 0.0020 1 06/08/17 21:09 108-88-3 1,2,3-Trichlorobenzene ND mg/L 0.0020 1 06/08/17 21:09 87-61-6 1,2,4-Trichlorobenzene ND mglL 0.0020 1 06/08/17 21:09 120-82-1 1,1,1-Trichloroethane ND mg/L 0.0020 1 0610811721:09 71-55-6 1,1,2-Trichloroethane ND mg/L 0.0020 1 06108/1721:09 79-00-5 Trichloroethene ND mg/L 0.0020 1 06/08/17 21:09 79-01-6 Trichlorofluoromethane ND mg/L 0.0020 1 06/08/17 21:09 75-69-4 1,2,3-Trichloropropane ND mg/L 0,0020 1 06108/1721:09 96-18-4 1,1,2-Trichlorotrfluoroethane ND mg/L 0.0020 1 06108/1721:09 76-13-1 1,2,4-Trimethylbenzene ND mg/L 0,0020 1 06/08/17 21:09 95-63-6 1,3,5-Trimethylbenzene ND mglL 0.0020 1 06108/1721:09 108-67.8 Vinyl acetate ND mg/L 0.0050 1 06/08/17 21:09 108-05-4 Vinyl chloride ND mg/L 0,0020 1 06/08/17 21:09 75-01-4 m&p-Xylene ND mglL 0.0050 1 06/08/17 21:09 179601-23-1 o-Xylene ND mg/L 0.0050 1 06/08/17 21:09 95-47-6 Surrogates 4-Bromofluorobenzene (S) 102 % 70-130 1 06/08/17 21:09 460-00-4 Toluene-d8 (S) 104 % 70-130 1 06/08/17 21:09 2037-25-5 1,2-Dichloroethane-d4 (S) 87 % 70-130 1 06/08/17 21:09 17060-07-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Dale: 06/19/2017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 23 of 48 aceAnalytical'o ttww.pacelahs.txxn QUALITY CONTROL DATA Project: 6/17 STORMWATER Pace Project No.: 92342821 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623.8921 QC Batch: 363382 Analysis Method: SM 2540D QC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 92342821001, 92342821002, 92342821003, 92342821006, 92342821008 METHOD BLANK: 2014542 Matrix: Water Associated Lab Samples: 92342821001, 92342821002, 92342821003, 92342821006, 92342821008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg1L ND 2.5 06/05/17 11:10 LABORATORY CONTROL SAMPLE: 2014543 Spike LCS LCS % Rec Parameter Units Cone Result % Rec Limits Qualifiers Total Suspended Solids mg1L 250 252 101 90-110 SAMPLE DUPLICATE: 2014544 92342537001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg1L 26.4 5.8 128 D6 SAMPLE DUPLICATE: 2014581 92342821002 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg1L 20.4 21.4 5 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2017 09:33 AM without the written consent of Pace Analytical Services, LLC, Page 24 of 48 aceAnalytical www.pecefehs.c= QUALITY CONTROL DATA Project: 6117 STORMWATER Pace Project No.: 92342821 QC Batch: 363400 Analysis Method: SM 4500-H+B QC Batch Method: SM 4500-H+B Analysis Description: 4500H+B pH EDEN Associated Lab Samples: 92342821001, 92342821002, 92342821003, 92342821006, 92342821008 SAMPLE DUPLICATE: 2014615 92342821001 Dup Parameter Units Result Result pH at 25 Degrees C Std. Units 6.4 6.4 RPD Qualifiers 0 H5 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NO 27288 (336)623-8921 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 25 of 48 aceAnalytical xww.pacefabscam QUALITY CONTROL DATA Project: 6/17 STORMWATER Pace Project No.: 92342821 QC Batch: 363680 Analysis Method: EPA 1664B QC Batch Method: EPA 1664B Analysis Description: 1664 SGT-HEM, TPH Associated Lab Samples., 92342821001, 92342821002, 92342821003, 92342821006, 92342821008 METHOD BLANK: 2016259 Matrix: Water Associated Lab Samples: 92342821001, 92342821002, 92342821003, 92342821006, 92342821008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Petroleum Hydrocarbons mg/L ND 5.0 06/07/17 06:50 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 272a8 (336)623-8921 LABORATORY CONTROL SAMPLE & LCSD: 2016260 2016261 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Cone. Result Result % Rec % Rec. Limits RPD RPD Qualifiers Total Petroleum Hydrocarbons mg/L 20 19.9 19.8 100 99 64-132 1 30 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2017 09:33 AM without the written consent of Pace Analytical Services, LLG. Page 26 of 48 Pace Analytical Services, LLC aceAnaprcal @ 205 East Meadow Road - Suite Eden, NC 27288 ww paaelabs.mm (336)623-8921 QUALITY CONTROL DATA Project: 6117 STORMWATER Pace Project No.: 92342821 QC Batch: 363657 Analysis Method: EPA200.7 QC Batch Method: EPA 200.7 Analysis Description: 200.7 MET Associated Lab Samples: 92342821001, 92342821002, 92342821003, 92342821006, 92342821008 METHOD BLANK: 2016157 Matrix: Water Associated Lab Samples: 92342821001, 92342821002, 92342621003, 92342821006, 92342821008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Copper mg1L ND 0,0050 06/10/17 22:27 Lead mg1L ND 0.0050 06/10/17 22:27 Zinc mg1L ND 0.010 06/10/17 22:30 LABORATORY CONTROL SAMPLE: 2015158 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Copper mg/L .5 0,51 103 65-115 Lead mg1L .5 0.50 99 85-115 Zinc mglL .5 0.50 100 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2016159 2016160 MS MSD 92343067002 Spike Spike MS MSD M$ MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Copper mg1L ND .5 .5 0.52 0.50 102 99 70-130 3 Lead mg1L ND ,5 .5 0.47 0.45 94 90 70-130 4 Zinc mg1L ND .5 .5 0,49 0,47 97 94 70-130 3 MATRIX SPIKE R MATRIX SPIKE DUPLICATE: 2016161 2016162 MS MSD 92342970001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Copper mg1L 5.7 ug/L .5 .5 0.52 0.53 103 104 70-130 1 Lead mg1L ND .5 .5 0.46 0.47 92 93 70-130 1 Zinc mglL 28.3 .5 .5 0.53 0.54 101 102 70-130 1 ug/L Results presented on this page are In the units Indicated by the "Units" column except where an ahemate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 27 of 48 LgC1 alytical www.pacefabs.com QUALITY CONTROL DATA Project: 6117 STORMWATER Pace Project No.: 92342821 OC Batch: 364069 Analysis Method: EPA 624 QC Batch Method: EPA624 Analysis Description: 624 MSV Associated Lab Samples: 92342821001, 92342821002, 92342821003, 92342821006, 92342821008 METHOD BLANK: 2018775 Matrix: Water Associated Lab Samples: 92342821001, 92342821002, 92342821003, 92342821006, 92342821008 Blank Reporting Parameter Units Result Limit Analyzed 1,1,1,2-Tetrachloroethane mg1L ND 0.0020 0610811714:38 1,1,1-Trichloroethane rng/L ND 0.0020 06108/1714:38 1,1,2,2-Tetrachloroethane mg1L ND 0,0020 0610811714:38 1,1,2-Trichloroethane mg1L ND 0.0020 06/0811714:38 1.1,2-Tdchlorotrifluoroethene mg1L ND 0.0020 06/0811714:38 1,1-Dichloroethane mg1L ND 0.0020 0610811714:38 1,1-Dichloroethene mg/L ND 0.0020 06/08/1714:38 1,1-Dichloropropene mg/L ND 0,0020 06/08/1714:38 1,2,3-Trichlorobenzene mg/L ND 0.0020 06/08/1714:38 1,2,3-Trichloropropane mg/L ND 0.0020 06108/1714:38 1,2,4-Trichlorobenzene mg/L ND 0,0020 06108/1714:38 1,2,4-Trimethylbenzene mg/L ND 0.0020 06108/1714:38 1,2-Dibromoethane (EDB) mg/L ND 0.0020 06/08/17 14:38 1,2-Dichlorobenzene mg/L ND 0.0020 06/0811714:38 1,2-Dichloroethane mg/L ND 0.0020 06/0811714:38 1,2-Dichloropropane mg/L ND 0.0020 06/0911714:38 1,3,5-Trimethylbenzene mg/L ND 0.0020 06/0811714:38 1,3-Dichlorobenzene mg/L ND 0.0020 06/08/1714:38 1,3-Dichloropropane mg/L ND 0.0020 06/08/1714:38 1,4-Dichlorobenzene mg/L ND 0.0026 06108/1714:38 2,2-Dichloropropane mg1L ND 0.0050 06/08/1714:38 2-Butanone (MEK) mg/L ND 0.0050 06/08/17 14:38 2-Chloroethylvinyl ether mg/L ND 0.0050 06/08/17 14:38 2-Chlorololuene mg/L ND 0.0020 06/08/1714:38 2-Hexanone mg/L ND 0.010 0610811714:38 4-Chlorotoluene mg/L ND 0.0020 06/08/1714:38 4-Methyl-2-pentanone (MIBK) mg/L ND 0.010 06/08/17 14:38 Acetone mg/L ND 0.010 0610811714:38 Acrolein mg/L ND 0.0050 0610811714:38 Acrylonitrile mg1L ND 0.050 0610811714:38 Benzene mg/L ND 0.0020 0610811714:38 Bromobenzene mg/L ND 0.0020 0610811714:38 Bromochloromethane mg1L ND 0.0020 0610811714:38 Bromodichloromethane mg1L ND 0.0020 0610811714:38 Bromoform mg/L ND 0.0020 0610811714:38 Bromomethane mg/L ND 0.0020 06/0811714:38 Carbon disulfide mg/L ND 0.0050 06108117 14:38 Carbon tetrachloride mg/L ND 0.0020 06108/17 14:38 Chlorobenzene mg/L ND 0.0020 06/0811714:38 Chloroethane mg/L ND 0.0020 06/0811714:38 Chloroform mg/L ND 0.0020 0610811714:38 Qualifiers Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Results presented on this page are In the units Indicated Gy the "Units" column except where an aitemate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 28 of 48 lacieAnalyfical ttrww.pace7aD.i.com QUALITY CONTROL DATA Project: 6117 STORMWATER Pace Project No.: 92342821 METHOD BLANK: 2018775 Matrix: Water Associated Lab Samples: 92342821001, 92342821002, 92342821003, 92342821006, 92342821008 Parameter Units Blank Result Reporting Limit Analyzed Chloromethane mglL ND 0.0020 06/08/17 14:38 cis-1,2-Dichloroethene mglL ND 0.0020 0610811714:38 cis-1,3-Dichloropropene mg1L ND 0.0020 06/0811714:38. Dibromochloromethane mglL ND 0.0020 06/08/17 14:38 Dibromomethane mglL ND 0.0020 06/08/17 14:38 Ethylbenzene mg1L ND 0.0020 06/08/17 14:38 Hexachloro-1,3-butadiene mg1L ND 0.0050 06108/1714:38 lodomethane mg1L ND 0.010 0610911714:38 Isopropylbenzene (Cumene) mglL ND 0.0050 06/08/17 14:38 m&p-Xylene mg1L ND 0.0050 06108/1714:38 Methyl-tert-butyl ether mglL ND 0.0050 06/08/17 14:38 Methylene Chloride mg1L NO 0.0020 06/08/17 14:38 n-Butylbenzene mglL ND 0.0050 06/08/17 14:38 n-Pfopylbenzene mg1L ND 0.0050 06/08/17 14:38 Naphthalene mg1L ND 0.0050 06108/1714:38 o-Xylene mglL ND 0.0050 06/08/17 14:38 p-lsopropyltoluene mglL ND 0.0050 06/08/17 14:38 sec-Butylbenzene mglL ND 0.0050 06/0811714:38 Styrene mg1L ND 0.0020 06/08/17 14:38 tert-Butyl benzene mglL ND 0.0050 0610811714:38 Tetra chloroethene mglL ND 0.0020 06/08/17 14:38 Toluene mglL ND 0.0020 06/08/17 14:38 trans- l,2-Dichloroethene mglL ND 0.0020 06108/1714:38 trans-1,3-Dichloropropene mglL ND 0.0020 06/08/17 14:38 Trichloroethene mglL ND 0.0020 06/08/17 14:38 Trichlorofluoromethane mglL ND 0.0020 06/08/17 14:38 Vinyl acetate mglL ND 0.0050 06/08/17 14:38 Vinyl chloride mglL ND 0.0020 06/08/17 14:38 1,2-Dichloroethan"4 (S) % 92 70-130 06/08/17 14:38 4-Bromofluorobenzene (S) % 101 70-130 06/08/17 14:38 Toluene-d8 (S) % 105 70-130 06/08/17 14:38 Qualifiers Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 LABORATORY CONTROL SAMPLE: 2018776 Spike LCS LCS % ReC Parameter Units Cone. Result % Rec. Limits Qualifiers 1,1,1,2-Tetrachloroethane mg1L .02 0.019 93 70-130 1,1,1-Tdchloroelhane mg1L .02 0.019 96 52-162 1,1,2,2-Tetrachloroethane mg1L .02 0,020 101 46-157 1,1,2-Trchloroethane mg1L .02 0.020 100 52-150 1,1,2-Tdchlorotrifluoroethane mg1L .02 0.019 96 70-130 1,1-Dichloroethane mg1L .02 0.018 92 59-155 1,1-Dichloroethene mg1L .02 0.018 91 1-234 1,1-Dichloropropene mglL .02 0.022 108 70-130 1,2,3-Trichlorobenzene mg1L .02 0.023 114 70-130 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result, REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/1912017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 29 of 48 aceAnalytical. anvwpaoefabs cm QUALITY CONTROL DATA Project: 6117 STORMWATER Pace Project No.: 92342821 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 LABORATORY CONTROL SAMPLE: Parameter 2018776 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,2,3-Trichloropropane mg1L .02 0.018 92 70-130 1,2,4-Trichlorobenzene mg1L .02 0.023 114 70-130 1,2,4-Trimethylbenzene mg/L .02 0.019 97 70-130 1,2-Dibromoethane(EDB) mg1L .02 0.022 109 70-130 1,2-Dichlorobenzene mg/L .02 0.020 102 18-190 1,2-Dichloroethane mg/L .02 0.018 90 49-155 1,2-Dichloropropane mg/L .02 0.022 108 1-210 1,3,5-Trimethyibenzene mg/L .02 0.019 97 70-130 1,3-Dichlorobenzene mg1L .02 0.019 96 59-156 1,3-Dichloropropane mg/L .02 0.021 103 70-130 1,4-Dichlorobenzene mg1L .02 0,020 101 18-190 2,2-Dichloropropane mg/L .02 0.020 98 70-130 2-Butanone (MEK) mg/L .04 0.049 121 50-127 2-Chloroethylvinyi ether mg1L .04 0.043 107 1-305 2-Chlorotoluene mg/L .02 0.019 97 70-130 2-Hexanone mg/L .04 0,047 117 70-130 4-Chlorotoluene mg/L .02 0.019 94 70-130 4-Methyl-2-pentanone (MIBK) mg/L .04 0.041 103 70-130 Acetone mg/L .04 0.047 117 70-130 Acrolein mg/L .1 0.11 112 15-152 Acrylonitrile mg/L .1 0.10 104 75-132 Benzene mg1L .02 0.020 102 37-151 Bromobenzene mg/L .02 0.021 103 70-130 Bromochloromethane mg/L .02 0,018 68 70-130 Bromodichloromethane mg/L .02 0.019 96 35-155 Bromoform mg/L .02 0.017 87 45-169 Bromomethane mg/L A2 0,015 73 1-242 Carbon disulfide mg1L .02 0.038 190 70-130 L1 Carbon tetrachloride mg/L .02 0.018 92 70-140 Chlorobenzene mg1L .02 0.020 101 37-160 Chloroethane mg1L .02 0.016 78 14-230 Chloroform mg1L .02 0.019 97 51-138 Chloromethane mg1L .02 0.021 103 1-273 cis-1,2-Dichloroethene mg/L .02 0.020 101 68-146 cis-1,3-Dichloropropene mg/L .02 0.022 108 1-227 Dibromochloromethane mg/L .02 0.020 100 53-149 Dibromomethane mg/L 02 0.019 97 70-130 Ethylbenzene mg/L .02 0.020 102 37-162 Hexachloro-4,3-butadiene mg/L .02 0.023 114 70-130 lodomethane mg/L .04 0,031 78 70-130 Isopropylbenzene (Cumene) mg/L .02 0.019 95 70-130 m&p-Xylene mg/L 04 0.039 98 70-130 Methyl-tert-butyl ether mg/L .02 0.020 101 70-130 Methylene Chloride mg/L .02 0.016 79 1-221 n-Butylbenzene mg1L .02 0.022 108 70-130 n-Propylbenzene mg1L .02 0.020 98 70-130 Naphthalene mg1L .02 0.023 115 70-130 Results presented on this page are In the units Indicated by the -Chita" column except where an altamate unit is presented to the right of the resulL REPORT OF LABORATORY ANALYSIS .. This report shall not be reproduced, except in full, Date: 06/19/2017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 30 of 48 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (�55'ne,Analyticalo wmpsWabs-com (336)623-892 1 QUALITY CONTROL DATA Project: 6/17 STORMWATER Pace Project No.: 92342821 LABORATORY CONTROL SAMPLE: 2018776 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers o-Xylene mg/L .02 0.018 92 70-130 p-Isopropyltoluene mg/L .02 0.021 104 70-130 sec -Butyl benzene mg/L .02 0.021 106 70-130 Styrene mg/L .02 0.020 98 70-130 tert-Butylbenzene mg/L .02 0.019 94 70-130 Tetrachloroethene mg/L .02 0.019 94 64-148 Toluene mglL 02 0.019 97 47-150 trans-1,2-Dichloroethene mg/L .02 0.019 97 54-156 trans- l,3-Dichloropropene mg1L .02 0.021 105 17-183 Trichloroethene mg/L 02 0.019 97 71-157 Trichlorofluoromethane mg/L .02 0,017 87 17-181 Vinyl acetate mg/L .04 0.042 104 70-130 Vinyl chloride mg/L .02 0.017 86 1-251 1,2-Dichloroethane-d4 (S) % 100 70-130 4-Bromofluorobenzene (S) % 101 70-130 Toluene-d8 (S) % 101 70-130 MATRIX SPIKE SAMPLE: 2018778 92342821008 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane mg/L NO .02 0.019 93 70-130 1,1,1-Trichloroethane mg/L ND .02 0.021 107 46-171 1,1,2,2-Tetrachloroethane mg/L NO 02 0.020 102 73-159 1,1,2-Trichloroethane mg/L NO .02 0.022 112 64-152 1,1,2-Trichlorotrifluoroethane mg/L ND 02 0.023 113 59-168 1,1-Dichloroethane mg/L NO .02 0.022 108 43-172 1,1-Dichloroethene mg/L NO .02 0.021 106 48-189 1,1-Dichloropropene mg/L NO 02 0.023 116 70-130 1,2,3-Trichlorobenzene mg/L NO .02 0.018 92 70-130 1,2,3-Trichloropropane mg/L ND .02 0.019 95 70-130 1,2,4-Trichlorobenzene mg/L NO .02 0,020 98 70-130 1,2,4-Trimethylbenzene mg/L NO .02 0.020 98 70-130 1,2-Dibromoethane (EDB) mg/L NO 02 0.023 117 70-130 1,2-Dichlorobenzene mg/L NO .02 0.020 99 54-154 1,2-Dichloroethane mg/L NO .02 0.021 104 42-171 1,2-Dichloropropane mg/L NO .02 0.021 105 55-157 1,3,5-Trimethylbenzene mg/L NO .02 0.020 98 70-130 1,3-Dichlorobenzene mg/L NO .02 0.020 100 57-148 1,3-Dichloropropane mg/L ND .02 0.024 118 70-430 1,4-Dichlorobenzene mg/L NO .02 0.020 100 58-149 2,2-Dichloropropane mg/L NO .02 0.021 106 70-130 2-9utanone (MEK) mg/L NO 04 0.043 107 70-130 2-Chloroethylvinyl ether mg/L NO .04 ND 0 70-130 M1,c2 2-Chlorotoluene mg/L NO .02 0.022 108 70-130 2-Hexanone mg/L NO 04 0.043 106 70-130 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the resuh. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 31 of 48 leftlytical wwwpaaawmcorn QUALITY CONTROL DATA Project: 6117 STORMWATER Pace Project No.: 92342821 MATRIX SPIKE SAMPLE: 2018778 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 92342821008 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 4-Chlorotoluene mglL ND 02 0.019 97 70-130 4-Methyl-2-pentanone (MIRK) mglL ND .04 0.043 107 70-130 Acetone mglL ND .04 0,083 190 70-130 M1 Acrolein mglL ND .1 0.12 118 70-130 Acrylonitrile mglL ND .1 0,11 112 70-130 Benzene mglL ND 02 0.021 106 54-163 Bromobenzene mglL ND .02 0.022 110 70-130 Bromochloromethane mglL ND .02 0.020 99 70-130 Bromodichloromethane mglL ND .02 0-021 104 56-152 Bromoform mg1L ND 02 0.016 82 53-151 Bromomethane mglL ND .02 0.016 81 10-200 Carbon disulfide mg1L ND .02 0.042 211 70-130 MO Carbon tetrachloride mglL ND .02 0.020 98 41-175 Chlorobenzene mglL ND .02 0.021 104 67.152 Chloroethane mg1L ND .02 0.018 90 23-200 Chloroform mglL ND .02 0.022 109 51-166 Chloromethane mg1L ND .02 0.018 92 40.175 cis- 1,2-Dichlo roethene mglL ND .02 0,022 111 45-174 cis- 1,3-Dichlo ropropene mg1L ND 02 0.023 114 38-146 Dibromochloromethane mg1L ND .02 0.023 114 65-144 Dibromomethane mg1L ND .02 0,019 96 70-130 Ethylbenzene mglL ND .02 0,022 109 57-152 Hexachloro-1,3-butadiene mglL ND .02 0.021 103 70-130 lodomethane mg1L ND .04 0.035 86 70-130 Isopropylbenzene (Cumene) mglL ND .02 0.021 107 70-130 m&p-Xylene mg1L ND .04 0.042 106 70-130 Methyl-tert-butyl ether mglL ND .02 0.020 98 70-130 Methylene Chloride mglL ND .02 0.019 90 40-167 n-Butylbenzene mg1L ND .02 0,021 104 70-130 n-Propylbenzene mglL ND .02 0.021 104 70-130 Naphthalene mg1L ND .02 0.020 100 70-130 o-Xylene mg1L ND .02 0,021 104 70-130 p-Isopropyltoluene mg1L ND .02 0.021 103 70-130 sec-Butylbenzene mglL ND .02 0.021 103 70-130 Styrene mglL ND .02 0.021 106 70-130 tert-Butylbenzene mg1L ND .02 0.018 89 70-130 Tetrachloroethene mglL ND .02 0,022 111 59-155 Toluene mglL ND 02 0.024 118 47-162 trans- l,2-Dichloroethene mg1L ND .02 0.021 107 47-178 trans-1,3-Dichloropropene mg1L ND .02 0,022 112 39-148 Trichloroethene mg1L ND .02 0.022 109 60-153 Trichlorofluoromethane mglL ND .02 0.019 97 42-199 Vinyl acetate mg1L ND .04 0.036 91 70-130 Vinyl chloride mg1L ND .02 0.016 80 46-176 1,2-Dichloroethane-d4 (S) % 96 70-130 4-Bromofluorobenzene (S) % 103 70-130 Toluene-d8 (S) % 106 70-130 Results presented on this page are in the unite indicated by the "Units" column except where on alternate unit Is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06119/2017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 32 of 48 laneAnalytical *v pecelabscom QUALITY CONTROL DATA Project: 6/17 STORMWATER Pace Project No.: 92342821 SAMPLE DUPLICATE: 2018777 Parameter Units 92342821006 Result Dup Result 1,1,1,2-Tetrachloroethane mglL NO ND 1,1,1-Trichloroethane mg/L ND NO 1,1,2,2-Tetrachloroethane mg1L ND NO 1,1,2-Trichloroethane mg1L ND ND 1,1,2-Trichlorotrifluoroethane mg1L NO NO 1,1-Dichloroethane mg/t_ NO NO 1,1-Dichloroethene mg1L ND NO 1,1-Dichloropropene mg1L NO ND 1,2,3-Trichlorobenzene mg1L NO ND 1,2,3-Trichooropropane mg1L NO NO 1,2,4-Trichlorobenzene mglL NO NO 1,2,4-Trimethylbenzene mglL NO NO 1,2-Dibromoethane (EDB) mglL NO NO 1,2-Dichlorobenzene mglL NO NO 1,2-Dichloroethane mglL NO ND 1,2-Dichloropropane mglL NO NO 1,3,5-Trimethylbenzene mglL NO NO 1,3-Dichlorobenzene mglL ND NO 1,3-Dichloropropane mglL NO NO 1,4-Dichlorobenzene mglL NO NO 2,2-Dichloropropane mglL NO NO 2-Butanone (MEK) mglL NO ND 2-Chloroethylvinyl ether mglL NO ND 2-Chlorotoluene mglL ND ND 2-Hexanone mg1L NO NO 4-Chlorotoluene mg1L ND NO 4-Methyl-2-pentanone (MIBK) mg1L NO NO Acetone mglL NO .00951 Acrolein mg1L NO .0015J Acrylonitrile mglL NO NO Benzene mg1L NO NO Bromobenzene mg1L NO ND Bromochloromethane mglL NO NO Bromodichloromethane mg1L NO NO Bromoform mglL NO NO Bromomethane mg/L NO NO Carbon disulfide mg1L ND ND Carbon tetrachloride mglL NO NO Chlorobenzene mglL ND NO Chloroethane mglL NO ND Chloroform mglL NO NO Chloromethane mglL NO NO cis-1,2-Dichloroethene mglL NO NO cis-1,3-Dichloropropene mg1L ND NO Dibromochloromethane mglL ND NO Dibromomethane mglL NO NO Ethylbenzene mglL ND NO RPD Qualifiers Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Results presented on this page are In the units Indicated by the "tlnits" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 33 of 48 laceAnalytical www.pecel b&= QUALITY CONTROL DATA Project: 6/17 STORMWATER Pace Project No.: 92342821 SAMPLE DUPLICATE: 2018777 Parameter Units 92342821006 Result Dup Result Hexachloro-1,3-butadiene mg1L ND ND lodomethane mg1L ND ND Isopropylbenzene (Cumene) mglL ND ND m&p-Xylene mg/L NO ND Methyl-tert-butyl ether mg/L ND ND Methylene Chloride mglL ND ND n-Butylbenzene mg/L ND ND n-Propylbenzene mg/L ND ND Naphthalene mg/L ND ND o-Xylene mg/L ND ND p-Isopropyltoluene mg/L ND ND sec -Butyl benzene mg/L ND ND Styrene mg/L ND ND tert-Butylbenzene mg1L ND ND Tetrachloroethene mg/L ND ND Toluene mg1L ND ND trans-1,2-Dichloroethene mg1L ND ND trans- 1,3-Dichloropropene mg/L ND ND Trichloroethene mg/L ND ND Trichlorofluoromethane mg1L ND ND Vinyl acetate mg/L ND ND Vinyl chloride mg/L ND ND 1,2-Dichloroethane-d4 (S) % 91 88 4-Bromofluorobenzene (S) % 103 99 Toluene-d8 (S) % 110 111 RPD Qualifiers 3 4 1 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Results presented on this page are In the unite indicated by the "units" column except where an alternate unit is presented to the right or the result. REPORT OF LABORATORY ANALYSIS This report shall, not be reproduced, except in full, Date: 06/19/2017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 34 of 48 IRC, lytical www.pete7abs oam QUALITY CONTROL DATA Project: 6117 STORMWATER Pace Project No.: 92342821 QC Batch: 364183 Analysis Method: EPA608 QC Batch Method: EPA 3510 Analysis Description: 608 GCS Pest PCB Associated Lab Samples: 92342821001, 92342821002, 92342821003, 92342821006, 92342821008 METHOD BLANK: 2019325 Matrix: Water Associated Lab Samples: 92342821001, 92342821002, 92342821003, 92342821006, 92342821008 Blank Reporting Parameter Units Result Limit Analyzed 4,4'-DDD mg1L ND 0,000050 06/12/17 23:55 4,4'-DDE mglL ND 0.000050 06/12/17 23:55 4,4'-DDT mg1L ND 0.000050 06/12/17 23:55 Aldrin mglL ND 0.000050 06/12/17 23:55 alpha-BHC mg1L ND 0,000050 06/12/17 23:55 beta-BHC mg1L ND 0.000050 06/12/17 23:55 Chlordane (Technical) mg/L ND 0.00050 06/12/17 23:55 delta-BHC mg/L ND 0.000050 06/12/17 23755 Dieldrin mg1L ND 0.000050 06/12/17 23:55 Endosulfan I mglL ND 0,000050 06/12/17 23:55 Endosulfan II mg1L ND 0.000050 06/12/17 23:55 Endosulfan sulfate mg/L ND 0.000050 06/12/17 23:55 Endrin mg1L ND 0.000050 06/12/17 23:55 Endrin aldehyde mg1L ND 0.000050 06/12/17 23:55 gamma-BHC (Lindane) mg1L ND 0.000050 06/12/17 23:55 Heptachlor mg/L ND 0.000050 06/12/17 23:55 Heptachlor epoxide mg1L ND 0.000050 06/12/17 23:55 PCB-1016 (Aroclor 1016) mg1L ND 0.00050 06/12/17 23:55 PCB-1221 (Aroclor 1221) mg1L ND 0,00050 06/12/17 23:55 PCB-1232 (Aroclor 1232) mg/t_ ND 0.00050 06/12/17 23:55 PCB-1242 (Aroclor 1242) mg1L ND 0.00050 06/12/17 23:55 PCB-1248 (Aroclor 1248) mglL ND 0,00050 06/12/17 23:55 PCB-1254 (Aroclor 1254) mg1L ND 0.00050 06/12/17 23:55 PCB-1260 (Aroclor 1260) mg1L ND 0.00050 06/12/17 23:55 Toxaphene mg1L ND 0.00050 06/12/17 23:55 Decachlorobiphenyl (S) % 71 20-138 06/12/17 23:55 Tetrachloro-m-xylene (S) % 82 20-110 06/12/17 23:55 Qualifiers Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 LABORATORY CONTROL SAMPLE: 2019326 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 4,4'-DDD mg1L .00025 0.00023 95 31-141 4,4'-DDE mg1L .00025 0.00022 88 30-145 4,4'-DDT mg/L .00025 0,00023 94 25-160 Aldrin mg1L .00025 0.00019 77 42-122 alpha-BHC mg1L .00025 0.00022 90 37-134 beta-BHC mg1L .00025 0.00019 77 17-147 delta-BHC mg1L .00025 0.00024 98 19-140 Dieldrin mg/L .00025 0.00022 89 36-146 Endosulfan I mg/L .00025 0.00023 92 45-153 Results presented on this page are In the units Indicated by the "Unite" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2017 09:33 AM without the wntten consent of Pace Analytical Services, LLC. Page 35 of 48 aceAnalytical QUALITY CONTROL DATA Project: 6117 STORMWATER Pace Project No.: 92342821 LABORATORY CONTROL SAMPLE: 2019326 Pace Analytical Services, LLC 205 East Meadow Road -Suite A Eden, NC 27288 (336)623-8921 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Endosulfan 11 mglL .00025 0.00023 93 1-202 Endosulfan sulfate mglL .00025 0.00024 97 26-144 Endrin mglL 00025 0.00024 96 30-147 Endrin aldehyde mglL .00025 0.00020 82 50-150 gamma-BHC (Lindane) mglL .00025 0.00023 92 32-127 Heptachlor mglL .00025 0.00022 91 34-111 Heptachlor epoxide mglL .00025 0.00023 93 41-126 Decachlorobiphenyl (S) % 78 20-138 Tetrachloro-m-xylene (S) % 95 20-110 MATRIX SPIKE SAMPLE: 2019327 92342821002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 4,4'-DDD mg1L ND .00025 0.00014 55 31-141 4,4'-DDE mg1L ND .00025 0.00017 68 30-145 4,4'-DDT mglL ND .00025 O.OD016 63 25-160 Aldrin mg1L ND .00025 0.00011 46 42-122 alpha-BHC mg1L ND .00025 0.00011 43 37-134 beta-BHC mglL ND .00025 0.00011 45 17-147 delta-BHC mg1L ND .00025 0.00011 45 19-140 Dieldrin mglL ND .00025 0.00020 82 36-146 Endosulfan I mglL ND .00025 0.00013 54 45-153 Endosulfan II mg1L ND 00025 0.00014 55 1-202 Endosulfan sulfate mg1L ND .00025 0.00016 66 26-144 Endrin mg1L ND .00025 0.00015 61 30-147 Endrin aldehyde mg1L ND .00025 0A0012 49 50-150 M1 gamma-BHC (Lindane) mg/L ND .00025 0.00011 43 32-127 Heptachlor mg1L ND .00025 0.00010 42 34-111 Heptachlor epoxide mg1L ND .00025 0,00012 49 41-126 Decachlorobiphenyl (S) % 29 20-138 Tetrachloro-m-xylene (S) % 43 20-110 SAMPLE DUPLICATE: 2019328 92342821006 Dup Parameter Units Result Result RPD Qualifiers 4,4'-DDD mg1L ND ND 4,4'-DDE mglL ND ND 4,4'-DDT mglL ND ND Aldrin mg1L ND ND alpha-BHC mg1L ND ND beta-BHC mg/L ND ND Chlordane (Technical) mg/L ND ND delta-BHC mg1L ND ND Dieldrin mg/L ND ND Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right or the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 36 of 48 laneAnalytical w *w.p8CWahs.cam QUALITY CONTROL DATA Project: 6117 STORMWATER Pace Project No.: 92342821 SAMPLE DUPLICATE: 2019328 Parameter Units 92342821006 Result Dup Result Endosulfan I mg/L ND ND Endosulfan II mg1L ND ND Endosulfan sulfate mg1L ND ND Endrin mg1L ND ND Endrin aldehyde mg1L ND ND gamma-BHC (Lindane) mg1L ND ND Heptachlor mg1L ND ND Heptachlor epoxide mg1L ND ND PCB-1016 (Aroclor 1016) mg1L ND ND PCB-1221 (Aroclor 1221) mg1L ND ND PCB-1232 (Aroclor 1232) mg1L ND ND PCB-1242 (Aroclor 1242) mg1L ND ND PCBA248 (Aroclor 1248) mg/L ND ND PCB-1254 (Aroclor 1254) mg1L ND ND PCB-1260 (Aroclor 1260) mg/L ND ND Toxaphene mg1L ND ND RPD Qualifiers Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Hate: 06/19/2017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 37 of 48 (�5aoeAnalyfical www.pacalabs.com QUALITY CONTROL DATA Project: 6117 STORMWATER Pace Project No.: 92342821 QC Batch: 364136 Analysis Method: EPA 625 QC Batch Method: EPA 625 Analysis Description: 625 MSS Associated Lab Samples: 92342821001, 92342821002, 92342821003, 92342821006, 92342821008 METHOD BLANK: 2018986 Matrix: Water Associated Lab Samples: 92342821001, 92342821002, 92342821003, 92342821006, 92342821008 Blank Reporting Parameter Units Result Limit Analyzed 1,2,4-Trichlorobenzene mglL ND 0,0050 06/1111721:55 1,2-Dichlorobenzene mglL ND 0.0050 06111/1721:55 1,2-Diphenylhydrazine mglL ND 0.0050 06111/1721:55 1,3-Dichlorobenzene mglL ND 0.0050 0611111721:55 1,4-Dichlorobenzene mglL ND 0.0050 0611111721:55 2,4,6-Tdchlorophenol mglL ND 0.010 06/11/17 21:55 2,4-Dichlorophenol mg1L ND 0.0050 06/11/17 21:55 2,4-Dimethylphenol mg1L ND 0.010 06111/1721:55 2,4-Dinitrophenol mg1L ND 0,050 06/11/17 21:55 2,4-Dinitrotoluene mglL ND 0.0050 06/11/17 21:55 2,6-Dinitrotoluene mg1L ND 0.0050 06/11/17 21:55 2-Chloronaphthalene mg1L ND 0.0050 06/11/17 21:55 2-Chlorophenol mg1L ND 0.0050 06/11/17 21:55 2-Nitrophenol mglL ND 0,0050 06/11/17 21:55 3,3`-Dichlorobenzidine mg1L ND 0.025 06/11/17 21:55 4,6-Dinitro-2-methylphenol mg1L NO 0.020 06./11/17 21:55 4-Bromophenylphenyl ether mg1L ND 0,0050 06/11/17 21:55 4-Chloro-3-methylphenol mg1L ND 0.0050 06/11/17 21:55 4-Chlorophenylphenyl ether mglL ND 0.0050 06/11/17 21:55 4-Nitrophenol mg1L NO 0.050 06/11/17 21:55 Acenaphthene mg1L NO 0.0050 06/11/17 21:55 Acenaphthylene mglL NO 0.0050 0611 Ili 21:55 Acetophenone mg/L NO 0.0050 06/11/17 21:55 Aniline mglL ND 0.010 06/11/17 21:55 Anthracene mglL NO 0,0050 06/11/17 21:55 Benzidine mglL NO 0.050 06/11/17 21:55 Senzo(a)anthracene mglL NO 0.0050 06/11/17 21:55 Benzo(a)pyrene mg1L NO 0.0050 06/11/17 21:55 Benzo(b)ftuoranthene mglL NO 0.0050 06/11/17 21:55 Benzo(g,h,i)perylene mglL NO 0.0050 06/11117 21:55 Benzo(k)fluoranthene mg1L NO 0,0050 06/11/17 21:55 bis(2-Chloroethoxy)methane mg1L ND 0.010 06/11/17 21:55 bis(2-Chloroethyl) ether mg1L NO 0.0050 06/11/17 21:55 bis(2-Ethylhexyl)phthalate mglL ND 0.0050 06/11/17 21:55 Butylbenzylphthalate mg1L NO 0.0050 06/11/17 21:55 Chrysene mg1L NO 0.0050 06/11/17 21:55 Di-n-butyl phtha late mg/L ND 0.0050 06/11/17 21:55 Di-n-octylphthalate mg1L ND 0.0050 0611111721;55 Dibenz(a,h)anthracene mg/L ND 0,0050 06/11/17 21:55 Diethylphthalate mg/L ND 0.0050 06/11/17 21:55 Dimethylphthalate mglL N❑ 0.0050 06/11/17 21:55 Qualifiers Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 38 of 48 aceAnalytrcal. ttaew.pacelabicom QUALITY CONTROL DATA Project: 6117 STORMWATER Pace Project No.: 92342821 METHOD BLANK: 2018986 Matrix: Water Associated Lab Samples: 92342821001, 92342821002, 92342821003, 92342821006, 92342821008 Blank Reporting Parameter Units Result Limit Analyzed Fluoranthene mg/L ND 0.0050 06/11/17 21:55 Fluorene mg/L ND 0.0050 06/11/17 21:55 Hexachloro-1,3-butadiene mglL ND 0.0050 06/11/17 21:55 Hexachlorobenzene mg1L ND 0.0050 06/11/17 21:55 Hexachlorocyclopentadiene mg/L ND 0.010 06/11/17 21:55 Hexachloroethane mg/L ND 0,0050 06/11/17 21:55 Indeno(1,2,3-cd)pyrene mg/L ND 0.0050 06/11/17 21:55 Isophorone mg/L ND 0.010 06/11/17 21:55 N-Nitroso-di-n-propylamine mg/L ND 0.0050 06/11/17 21:55 N-Nitrosod imethyla mine mg/L ND 0.0050 06/11/17 21:55 N-Nitrosodiphenylamine mg/L ND 0.010 06/11/17 21:55 Naphthalene mg/L ND 0,0050 06/11/17 21:55 Nitrobenzene mg/L ND 0.0050 06/11/17 21:55 Pentachlorophenol mg/L ND 0.010 06/11/17 21:55 Phenanthrene mg/L ND 0.0050 06/11/17 21:55 Phenol mg/L ND 0.0050 06/11/17 21:55 Pyrene mg/L ND 0,0050 06/11/17 21:55 2,4,6-Tribromophenol(S) % 57 10-137 0611ill 721:55 2-Fiuorobiphenyl (S) % 52 15-120 06/11/17 21:55 2-Fluorophenol (S) % 27 10-120 06/11/17 21:55 Nitrobenzene-d5 (S) % 49 10-120 06/11/17 21:55 Phenol-d6 (S) % 17 10-120 06/11/17 21:55 Terphenyl-d14 (S) % 65 11-131 06/11/17 21:55 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 2018987 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,2,4-Trichlorobenzene mg/L .05 0.029 57 44-142 1,2-Dichlorobenzene mg/L .05 0.027 53 32-129 1,2-Diphenylhydrazine mg/L .05 0,031 62 25-150 1,3-Dichlorobenzene mglL .05 0.025 51 1-172 1,4-Dichlorobenzene mg/L .05 0.026 52 20-124 2,4,6-Trichlorophenol mg/L .05 0.044 88 37-144 2,4-Dichlorophenol mg1L .05 0,037 73 1-191 2,4-D imethyl phenol mg/L .05 0.036 72 32-119 2,4-Dinitrophenol mg/L .25 0.20 80 1-181 2,4-Dinitrotoluene mg/L .05 0.042 83 39-139 2,6-Dinitrotoluene mg/L .05 0.041 83 50-158 2-Ctlloronaphthalene mg/L .05 0,035 70 60-118 2-Chlorophenol mg/L .05 0.034 67 23-134 2-Nitrophenol mg/L .05 0.038 76 29-182 3,3'-Dichlorobenzidine mg/L .1 0,075 75 1-262 4,6-Dinitro-2-methylphenol mg/L .1 0.072 72 1-181 4-Bromophenylphenyl ether mg/L I .05 0.028 56 53-127 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Qualifiers Results presented on this page are In the units Indicated by the "Units- column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2017 09:33 AM without the written consent of Pace Analytical Services, LLC, Page 39 of 48 laneAnalytical www.pece1gU Wm QUALITY CONTROL DATA Project: 6117 STORMWATER Pace Project No.: 92342821 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 LABORATORY CONTROL SAMPLE: Parameter 2018987 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 4-Chloro-3-methylphenol mg1L .1 0.070 70 22-147 4-Chlorophenylphenyl ether mg1L .05 0.038 75 25-158 4-Nitrophenol mg1L 25 0.081 32 1-132 Acenaphthene mg1L 05 0.038 77 47-145 Acenaphthylene mg1L .05 0.037 74 33-145 ACetophenone mg/L A 0.037 37 25-150 Aniline mg1L .05 0.022 45 25-150 Anthracene mg/L .05 0.035 70 1-166 Benzidine mg/L .1 ND 2 25-150 L2 Benzo(a)anthracene mg/L .05 0.036 71 33-143 Benzo(a)pyrene mg/L .05 0.036 72 17-163 Benzo(b)fluoranthene mg/L .05 0.036 71 24-159 Benzo(g,h,i)perylene mg/L .05 0.034 67 1-219 Benzo(b)fluoranthene mg/L .05 0.036 72 11-162 bis(2-Ch loroethoxy) methane mg/L .05 0.029 58 33-184 bis(2-Chloroethyl) ether mg/L .05 0.030 59 12-158 bis(2-Ethylhexyl)phthalate mg1L .05 0.040 80 8-158 B utylbenzylphtha late mg/L .05 0.040 80 1-152 Chrysene mg1L .05 0.035 70 17-168 Di-n-butylphthalate mg1L .05 0.040 80 1-118 Di-n-octylphthalate mg1L .05 0.043 87 4-146 Dibenz(a,h)anthracene mg1L .05 0.035 71 1-227 Diethylphtha late mg1L .05 0.042 84 1-114 Dimethylphtha late mg1L .05 0.041 82 1-112 Fluoranthene mg/L .05 0.038 75 26-137 Fluorene mg/L .05 0.040 80 59-121 Hexachloro-1,3-butadiene mg/L .05 0.026 53 24-116 Hexachlorobenzene mg/L .05 0.035 71 1-152 Hexachlorocyclopentadiene mg/L .05 0.024 49 25-150 Hexachloroethane mg1L .05 0.023 46 40-113 Indeno(1,2,3-cd)pyrene mg1L .05 0.037 74 1-171 Isophorone mg1L .05 0.035 69 21-196 N-Nitroso-di-n-propylamine mg1L .05 0.035 71 1-230 N-Nitrosodimethylemine mg1L .05 0.021 41 25-150 N-Nitrosodiphenylamine mg1L .05 0.035 70 25-150 Naphthalene mg1L .05 0.032 53 21-133 Nitrobenzene mg/L .05 0.033 66 35-180 Pentachlorophenol mg/L .1 0.078 78 14-176 Phenanthrene mg/L .05 0.035 70 54-120 Phenol mg/L .05 0.014 28 5-112 Pyrene mg/L .05 0.033 57 52-115 2,4,6-Thbromophenol (S) % 85 10-137 2-Fluorobiphenyi (S) % 78 15-120 2-Fluorophenol (S) % 40 10-120 Nitrobenzene-d5 (S) % 70 10-120 Phenol-d6 (S) % 27 10-120 Terphenyl-d14 (S) % 75 11-131 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 40 of 48 aceAnalytrcal wrw.pacefabs.eom QUALITY CONTROL DATA Project: 6117 STORMWATER Pace Project No.: 92342821 MATRIX SPIKE SAMPLE: 2018988 60245WO01 Spike MS Parameter Units Result Conc. Result Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 MS % Rec % Rec Limits Qualifiers 1,2,4-Trichlorobenzene mg1L NO .05 0.025 50 44-142 1,2-Dichlorobenzene mg1L NO .05 0.024 48 32-129 1,2-Diphenylhydrazine mg/L ND .05 0.028 56 25-150 1,3-Dichlorobenzene mg1L NO .05 0.023 46 1-172 1,4-Dichlorobenzene mg/L ND .05 0.023 46 20-124 2,4,6-Trichlorophenol mg/L ND .05 0.038 76 37-144 2,4-Dichlorophenol mg1L ND .05 0.032 64 1-191 2,4-Dimethylphenol mg/L ND .05 0.030 60 32-119 2,4-Dinitrophenol mg1L ND .25 0.17 66 1-181 2,4-Dinitrotoluene mglL ND .05 0.036 72 39-139 2,6-Dinitrotoluene mg/L ND .05 0.037 73 50-158 2-Chloronaphthatene mg1L ND .05 0.031 61 60-118 2-Chlorophenol mg1L NO .05 0.028 56 23-134 2-Nitrophenol mg1L NO .05 0.032 63 29-182 3,3'-Dichlorobenzidine mg1L NO .1 .0181 18 1-262 4,6-Dinitro-2-methylphenol mg1L ND .1 0.066 66 1-181 4-Bromophenylphenyl ether mglL ND .05 0.026 52 53-127 M1 4-Chloro-3-methylphenol mg1L ND .1 0.062 62 22-147 4-Chlorophenylphenyl ether mglL ND .05 0.032 64 25-158 4-Nitrophenol mglL ND .25 0.076 30 1-132 Acenaphthene mg/L ND .05 0.033 66 47-145 Acenaphthylene mg1L ND .05 0.032 63 33-145 Acetophenone mglL ND .1 0.030 30 25-150 Aniline mglL ND .05 0.021 41 25-150 Anthracene mglL ND .05 0.03D 61 1-166 Benzidine mg1L ND A NO 0 25-150 MO Benzo(a)anthracene mglL ND .05 0.031 63 33-143 Benzo(a)pyrene mglL ND .05 0.032 65 17-163 Benzo(b)fluoranthene mg1L ND .05 0.031 63 24-159 Benzo(g,h,i)perylene mgll- ND .05 0.029 59 1-219 Benzo(k)fluoranthene mg1L ND .05 0.031 62 11-162 bis(2-Chloroethoxy)methane mg1L ND .05 0.024 48 33-184 bis(2-Chloroethyl) ether mg1L ND .05 0.025 50 12-158 bis(2-Ethylhexyt)phthalate mg1L NO .05 0.035 70 8-158 Butytbenzylphthalate mglL NO .05 0.035 71 1-152 Chrysene mglL NO .05 0.031 63 17-168 Di-n-butylphthalate mg1L NO .05 0.034 68 1-118 Di-n-octylphthalate mg1L ND .05 0.040 80 4-146 Dibenz(a,h)anthracene mg]L NO .05 0.031 62 1-227 Diethylphthalate mg1L ND .05 0.036 72 1-114 Dimethylphthalate mg/L ND .05 0.036 73 1-112 Ftuoranthene mg/L ND .05 0.030 60 26-137 Fluorene mg1L ND .05 0.033 66 59-121 Hexachloro-1,3-butadiene mg/L NO 05 0.023 46 24-116 Hexachtorobenzene mg1L ND .05 0.030 60 1-152 Hexachlorocyclopentadiene mg1L NO .05 0.020 41 25-150 Hexachloroethane mg1L NO .05 0.021 43 40-113 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06119/2017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 41 of 48 aceAnalytrcal wrw.pecewmcom QUALITY CONTROL DATA Project: 6/17 STORMWATER Pace Project No.: 92342821 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 MATRIX SPIKE SAMPLE: 2018988 60245648001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Indeno(1,2,3-cd)pyrene mg/L ND .05 0.031 62 1-171 Isophorone mg/L ND .05 0,029 57 21-196 N-N itroso-d i-n-propyla mine mg/L ND .05 0.029 57 1-230 N-Nitrosodimethylamine mg/L NO .05 0.018 36 25-150 N-Nitrosodiphenylamine mg1L ND .05 0.030 61 25-150 Naphthalene mg/L NO .05 0.028 55 21-133 Nitrobenzene mg/L NO .05 0.029 57 35-180 Pentachlorophenol mg1L NO .1 0.075 75 14-176 Phenanthrene mg/L NO .05 0.030 60 54-120 Phenol mg1L NO .05 0.011 22 5-112 Pyrene mg1L NO .05 0.029 58 52-115 2,4,6-Tribromophenol (S) % 70 10-137 2-Fluorobiphenyl (S) % 64 15-120 2-Fluorophenol (S) % 32 10-126 Nitrobenzene-d5 (S) % 58 10-120 Phenol-d6 (S) % 21 10-120 Terphenyl-d14 (S) % 44 11-131 SAMPLE DUPLICATE: 2018989 Parameter Units 92343414001 Result Dup Result RPD Qualifiers 1,2,4-Trichlorobenzene mglL ND NO 1,2-Dichlorobenzene mg/L ND NO 1,2-Diphenylhydrazine mg/L NO NO 1,3-Dichlorobenzene mg1L NO NO 1,4-Dichlorobenzene mg1L ND NO 2,4,6-Trichlorophenol mg1L NO NO 2,4-Dichlorophenol mg/L NO NO 2,4-Dimethylphenol mg/L ND .0029J 2,4-Dinitrophenol mg1L NO NO 2,4-Dinitrotoluene mg1L NO ND 2,6-Dinitrotoluene mg/L NO ND 2-Chloronaphthalene mg1L NO ND 2-Chlorophenol mg1L NO ND 2-Nitrophenol mg/L NO ND 3,3'-Dichiorobenzidine mg/L NO ND 4,6-Dinitro-2-methyiphenol mg/L NO ND 4-Bromophenylphenyl ether mg1L NO ND 4-Chloro-3-methylphenol mg1L NO ND 4-Chlorophenylphenyl ether mg1L NO ND 4-Nitrophenol mg1L NO ND Acenaphthene mg1L NO ND Acenaphthylene mg1L NO NO Acetophenone mg1L NO ND Aniline mg1L NO ND Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06119/2017 09:33 AM without the written consent of Pace Analytical Services, LLC, Page 42 of 48 laaeAnalytical ~..pacelaUcom QUALITY CONTROL DATA Project: 6117 STORMWATER Pace Project No.: 92342821 SAMPLE DUPLICATE: 2018989 Parameter Units 92343414001 Result Dup Result RPD Anthracene mg1L ND N❑ Benzidine mg1L ND ND Benzo(a)anthracene mg1L ND ND Benzo(a)pyrene mg1L ND ND Benzo(b)fluoranthene mg1L ND ND Benzo(g,h,i)perylene mg1L ND ND Benzo(k)fluoranthene mg1L ND ND bis(2-Chloroethoxy)methane mg1L ND ND bis(2-Chloroethyl) ether mg1L ND ND bis(2-Ethylhexyl) phthe late mg1L ND ND Butylbenzylphtha late mg1L ND ND Chrysene mg1L ND IVD Di-n-butylphthalate mg1L ND ND Di-n-octylphthalate mg1L ND ND Dibenz(a,h)anthracene mg1L ND ND Diethylphtha late mglL ND ND Dimethylphthalate mg1L ND ND Fluoranthene mglL ND ND Fluorene mglL ND ND Hexachloro-1,3-butadiene mglL ND ND Hexachlorobenzene mglL ND ND Hexachlorocyclopentadiene mg1L NO ND Hexachloroethane mglL ND ND lndeno(1,2,3-cd)pyrene rng1L ND ND lsophorone mg1L ND ND N-Nitroso-di-n-propylamine mglL ND ND N-Nitrosodimethyla mine mglL ND ND N-Nitrosodiphenyla mine mglL ND ND Naphthalene mglL ND ND Nitrobenzene mg/t_ ND ND Pentachlorophenol mglL ND ND Phenanthrene mglL ND ND Phenol mglL ND ND Pyrene mglL ND ND X 2,4,6-Tribromophenol (S) % 100 66 41 2-Fluorobiphenyl (S) % 87 37 80 2-Fluorophenol (S) % 42 18 79 Nitrobenzene-d5 (S) % 77 33 81 Phenol-d6 (S) % 26 11 84 Terphenyl-d14 (S) % 89 54 49 Qualifiers Pace Ana tytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 43 of 48 Pace Analytical Services, LLC aceAnalytical� 205 East Meadow Road - Suite Eden, NC 27288 w'wpacelabscom (336)623.8921 QUALIFIERS Project: 6117 STORMWATER Pace Project No.: 92342821 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate %recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) li - Matrix Spike (Duplicate) DU - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is Ti accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PAS I -A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte PASI-E Pace Analytical Services - Eden ANALYTE QUALIFIERS 1g Sample re -extracted outside method hold time. Results of re -analysis confirmed original analysis performed within hold time. 06 The precision between the sample and sample duplicate exceeded laboratory control limits. H6 Analysis initiated outside of the 15 minute EPA required holding time. Li Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. L2 Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated samples may be biased low. MO Matrix spike recovery andlor matrix spike duplicate recovery was outside laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. So Surrogate recovery outside laboratory control limits. c2 Acid preservation may not be appropriate for the analysis of 2-Chloroethylvinyl ether. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 44 of 48 aceAnalytical www.pacefsb&WM QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 6117 STORMWATER Pace Project No.: 92342821 Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92342821001 SDO #6 SM 2540D 363382 92342821002 SDO #7 SM 2540D 363382 92342821003 SDO #8 SM 2540D 363382 92342821006 SDO #11 SM 2540D 363382 92342821008 SDO #13 SM 2540D 363382 92342821001 SDO #6 SM 4500-H+B 363400 92342821002 SDO #7 SM 4500-H+B 363400 92342821003 SDO #8 SM 4500-H+B 363400 92342821006 S00 #11 SM 4500-H+B 363400 92342821008 SDO #13 SM 4500-H+8 363400 92342821001 SDO #6 EPA 1664B 363680 92342821002 SDO #7 EPA 1664B 363680 92342821003 SDO #8 EPA 1664B 363680 92342821006 SDO #11 EPA 1664B 363680 92342821008 SDO #13 EPA 1664B 363680 92342821001 SDO #6 EPA 3510 364183 EPA 608 364454 92342821002 SDO #7 EPA 3510 364183 EPA 608 364454 92342821003 SDO #8 EPA 3510 364183 EPA 608 364454 92342821006 SDO #11 EPA 3510 364183 EPA 608 364454 92342821008 SDO #13 EPA 3510 364183 EPA 608 364454 92342821001 SDO #6 EPA 200.7 363657 EPA 200.7 364247 92342821002 SDO #7 EPA 200.7 363657 EPA 200.7 364247 92342821003 SDO #8 EPA 200.7 363657 EPA 200.7 364247 92342821006 SDO #11 EPA 200,7 363657 EPA 200.7 364247 92342821008 SDO #13 EPA 200.7 363657 EPA 200.7 364247 92342821001 SDO #6 EPA 625 364136 EPA 625 364327 92342821002 SDO #7 EPA 625 364136 EPA 625 364327 92342821003 SDO #8 EPA 625 364136 EPA 625 364327 92342821006 SDO #11 EPA 625 364136 EPA 625 364327 92342821008 SDO #13 EPA 625 364136 EPA 625 364327 92342821001 SDO 06 EPA 624 364069 92342821002 SDO #7 EPA 624 364069 92342821003 SDO #8 EPA 624 364069 92342821006 SDO #11 EPA 624 364069 92342821008 SDO #13 EPA 624 364069 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2017 09:33 AM without the written consent of Pace Analytical Services, LLC. Page 45 of 48 Document Name: Document Revised: Sept. 21, 2016 aceAnNxical- Sample Condition Upoh Recei t(SCUR) Page 1 of 2 Document No.: issuing Authority: F-CAR-CS-033-Rev.01 Pace Quality Office Laboratory receiving samples: Asheville ❑ Eden Greenwood ❑ Huntersville [] Raleigh❑ Mechanicsville[] Client Name, Project Courier: ❑Fed Ex ❑UPS ❑LISPS Ciient ❑ Commercial ❑Pate ❑Other: Custody Seal Present? QYes �No Seals Intact? ❑Yes ❑No Date/initials Person Examining Contents: t' `� S - Y Packing Material: []Bubble Wrap Bubble Bags ❑None ❑0ther. Thermometer, Gun ID: [�O 01 Type of ice: QWet , ❑Blue ❑None QSamples on ice, cooling process has begun Correction Factor: Cooler Temp Corrected ('Cl.- _3, Biological Tissue Frozen? []Yes []Na ON/A Tem p shoufd be above freezing to 6°C USDA Regulated Soil ( iE NIA, water sample) Did samples originate Ina quarantine zone within the United States: CA, NY, or SC (check maps)? . Did samples originate from a foreign source (internationally, WOW-92342824 92342821 111111 I'll Yes LJNo Including Hawaii and Puerto Ricoi? UYes LJNo Comments/Discre anc .. Chain of 6stod Present? QYes QNo ❑NIA 1. 5ampies Arrived within Hold Tlme? DYes 13No N/A 2. Short Hold Time Analysis 102 hr.)? IgYes • No N/A 3. Rush Turn Around Time Requested? ❑Yes idNo ❑N/A 4, SufficlentVolume? gYes []NO ❑N/A 5. Correct[ontalners Used? -Pace Containers Used? j]Yes I]Yes ❑No No '❑N/A N/A 6. Containers Intact? VJYes [:?No ONA 7. Samples Field Filtered? Dyes - Ono N/A S. Note If sediment Is visible in the dissolved container Sample Labels Match COC? -Includes Date/nme/10 Anai sis Matrix: ` Q'Kes ❑No ❑N/A 9• ' Headspace in VOA Vials (>5-6mm)? ❑Yes ❑No . ;E N/A 10, Trip Blank Present? Trip Blank Custody Seals Present? [_-]Yes ©No ❑Yes.. El -No 1211/A 06 11. CLIENT NOTIFICATION/RESOLUTION Person Contacted: Comments/Sample Discrepancy: Date/Time. Field Data Required? ❑Yes❑No i Project Manager SCURF Review: Date: l i Project Manager SRF Review: _ Date: - Note: Whenever there Is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Cerdfi tlon Office (Le. I Out of hold, incorrect preservative, out of temp, Incorrect cantalners) page 46 of 48 rv� / : PaceAnalytical . rrulvr.preslaEs.con CHAIN -OF -CUSTODY If Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. Al[ relevant fields must be completed accurately. +r ` GO o r Section A Section 8 • (. Saction C ^ >,,. Pago: of a) Roqulrod Client Information: Required Pro}act Information: • _ Invoice Information: , >� Company; } '� Report 70: �jd J_ j� Mien[ f/� R 1 5 tr .. J fI , an: �U IC i< j '^ " Address - e• Copy 5`�3 . S� Nr�CtJ .•7� To: Company Name: r �� - REGUeATQRY AGENCY ' {y e.,1%'': '/�%;•� ' a'�p�.p ice t'; . .. Address: _ , ... ." ,. '.I NPDES7 -r .zGROUNE)WATER' •("',.,' DRINKING WATER r UST r RCRA r OTHER Email To'Aih1UfC r j ` ncrA�./•Purchase Cr Order No.: Ppca Quota Rulcrenca: �[,.,77. 6,00-7 Fa : Projact -6A-)-G d " Name: fa 5 f A+,! � Paw Project - - Sike Location - jG; 3% / of,tit C t�sla9ac. '.DuctDalplfAT:' "STATE: ' •; -•- -''-• -� Raquaslad Du ProjerlNumber, - + ' Faw Profile a: • - - •.• I Requested Analysis,Filtered"(YIN) • ' - . •' ' Saction D Matrix Codes � Roqulrod Clivntrnfurnawn 1 C-nnF 'a •s f "' COLLECTED' "' - � PreS@Nat VBS'`•'- • ~ x; ,y, °'ig ' f DrinkingOW Water U zr- - I WaterWT. Waste Water WW Product P SSEE v C STARI E DGRADE Z y q�. . ' S0111Sotfd SL " .a c� O r 'r y SAMPLE ID Oil OL _ V � a, t r 'r Wipe WP fA-Z,'0.91,1 Air.. ARi.'ct, of rw 4 a z�.� c Sample•IDs MUST BE UNIQUE Tissue TS Other .. OT OLU U+ + m.,a, �, �t' , r .' '' -'i .l, •a' Sri. Iv C O "r' = O to .� t9 r $ ' � a • to i . +DATE�N - TIME,- 1 -DATE r rw . HTIME-� . a- ''O O -*i. O N = Z � f.? Y. cc Z ry Z v M O 'a,. � >l,. - w a - Pace Project No.! Lab I.D. �hL s.' S •s. `g',. 2 ��//--� S 110 •r �h •59- 3, 5 od U! S• i>A 5a .U. G 6IS11719:00 a S 3©=##":'-��--NG' ,F� ri G' s r) S ,'l3 1 • ,,, 3 ;r, t • �: y_ Ct 7.:.5-•� v� H-,. � ��,.-.' � I�1%��.� � iC.I" � { �.T Jr 11 � ° LiG =.. t - :.1 + _ ra _ , 8 _y.,j.,.f-1- y s D l 9- 10 11 ,2 ADDITIONAL CQMMENTS�' RELINpU17HED BY 7 AFFILIATION DATE • , TIMELL � ' ACCEPTED BY i AFFILIATION , DATE. � [, .TIME.` • SAMPLE CONDITIONS %', j' ct/s/r;7- ire `53 / .mow s; ORIGINAL SAMPLER NAME'AND SIGNATURE _- A ' _ " - '- • " � U o ..- T PRINT Name of SAMPLER:�Hr�A Vy1t.tF�- 'E y m g } Q r SIGNATURE of SAMPLER.%. f 11 _ [ATE Signed � %6- A -7 r N r CC UU rGsrTY� MM1DDlYY ; rE 'Important Note: By signin91hla farm you arc, acwpl.n9 Wme:'s NET 30 day payment terms and ageeig to late ehargas 011,5%Per month Iw any imoiCus not paid within 30 days. F-ALL-Q-020rev.07, 15-May-2007 ..... .......... - - ---- . .. ............... o ob '13 CL zzzz BP4U?,JZS ML PIOSUC UnP-S&"d Wi A) (CI-) SP3U-250 ML Plasur, unpresi.wed (WA) BPZU-Soo m served (N/A) 4 PlastIc unpr.4� a pixj-lriterMutic unpreserved (N/A) 13P3S.250 ML Plastic H2SO4 (poi -< 2) (Cl-) I§MI-250 ml. pfiwUc HNO3 (phi < 2) • BP3Z-250 mL F>IaslticZN Acetate t& NaOH (>9) SM-250 ml. Pt=lc NaOH (pH > 1.2) Cl.) • -woku-Wide-mouthed Glass Jar Unpresewed AGIU-.1 tlter�Amber Unpreserved ON (CO z z z z AGIH-Irjter-AmberHCk(pH <2) AG3U-250 mL Amber Unpreserved (NIA) (a-) AG2S-IlIterAmbe.rH2SO4(pkf<2) AWS-250 rnLAMber H2SO4 (PM < 2) AG.3A(D63A)-250 rnLAmber NH4Cl (WA)(C-I-) DG9H-40rnLVOA Na.N/A) V"T-4DmLVOA Na=03(NjN Vr.S,U-40rnLVQAunp.(N/A) 1�" D69P.40MLVOA H3PO4 (N/A) VOAK (SvIals per WO-S03S ldt.,(4/A) V/GK (a I Vial$ per Idt)-VPfi/Gas kit (NIA) SPST-125-ML . SteiT OPIaWoc(WA�Iab) SM-250 ..mL Sterite Pks6r- (t.4/A— 12b) -SM4A-2SOmLPfa sdc (NHZ)2SO4 (9.3-9.7) -Cubitainer VSGU620 mLScInWjaUon vials; (N/A) GN IZ 0- CL =r o W n) 0 CID z In X .7 c O Im z OD STORMWATER DISCHARGE OUTFALL (SDO) MONITORING REPORT Permit Number NCS Certificate of Coverage Number: NCG030548 ` SAMPLES COLLECTED DURING CALENDAR YEAR: 2016 (This monitoring report shall be received by the Division no later than 30 days from the date the facility receives the sampling results from the laboratory.) FACILITY NAME _Weil -McLain PERSON COLLECTING SAMPLE(S) CERTIFIED LABORATORY(S) Lab # Lab # Part A: Specific Monitoring Requirements COUNTY Rockingham_ PHONE NO. (336) 627-6015 F ATURE OF PERMITTEE OR DESIGNEE IRED ON PAGE 2. Outfall No. Date Sample Collected 50050 Total Flow if app.) Total Rainfall molddl r MG inches SDO#6 NO FLOW SDO#7 NO FLOW SDO#8 NO FLOW SDO#9 NO FLOW �j> %_' j V I - j SDO#10 NO FLOW SDO#ll NO FLOW -51 SDO#12 NO FLOW - -j� r_ t _ SDO#13 NO FLOW UW13 Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes _X_no (if yes, complete Part B) Part B: Vehicle Maintenance Activity Monitoring Requirements Outfall Date 50050 00556 00530 00400 No. Sample Total Flow Total Oil & Grease Non -polar Total pH New Motor Collected (if applicable) Rainfall (if appl.) O&GITPH Suspended Oil Usage (Method 1664 Solids SGT-HEM), if appl. molddl r MG linches m 1 I mg/1 unit I gal/mo Form SWU-247, last revised 21212012 Page 1 of 2 STORM EVENT CHARACTERISTICS: Mail Original and one copy to: Division of Water Quality Date Attn: Central Files Total Event Precipitation (inches): 1617 Mail Service Center Event Duration (hours): (only if applicable — see permit.) Raleigh, North Carolina 27699-1617 (if more than one storm event was sampled) Date y +� Total Event Precipitation (inches): Event Duration (hours): (only if applicable — see permit.) All storm Events for the 2Id half of the year did not meet the definition of 'measurable event', did not occur during normal business hours, or posed a hazard to our employees (ice or lightening) "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 0 ,A&I-2TI& (Date) Form SWU-247, last revised 21212012 Page 2 of 2 TTO Certification Statement Period July 2016 — December 2016 Based on my inquiry of the person or persons directly responsible for managing compliance with the permit limitation for Total Toxic Organics (TTO), I certify to the best of my knowledge and belief, no leak, no spill, or no dumping of concentrated toxic organics into the stormwater or onto areas which are exposed to rainfall or stormwater runoff has occurred since filing of the last monitoring report. I further certify that this facility is implementing all of the provisions of the Solvent Management Plan included in the Stormwater Pollution, Prevention Plan. Date.-0Qt (i Site Director V Weil -McLain, Eden Operations 1.1 WEWRLAIN� December 29, 2016 Central Files Division of Water Quality 1617 Mail Service Center Raleigh, NC 27699-1617 RE: Explanation of Stormwater Monitoring Report Dear Sir or Madam: 523 S. New Street Eden, NC 27288 P: 336-627-6000 F:336-627-6065 N0110�3S �JMa S�31I=1 �V2JIN30 1lOZ t 0 NVf COA1303�1 In accordance with NPDES (NCG030000) Stormwater Permit Condition Part II Section B, the completed Stormwater Discharge Monitoring Report. We were unable to collect samples as required for the second half of the year. All storm events either did not meet the definition of measurable, occurred outside normal business hours, or posed additional hazard to our employees (ice or lightning). Therefore NO FLOW was reported for all outfalls. Weil -McLain did attempt to contact Glen White at the Winston Salem Regional Office on 12/29/2016 to review, but we were unable to make contact. We will discuss the situation with him as soon as we are able to make contact. Also enclosed is the TTO verification statement as required. If you have any questions regarding the enclosed reports, please contact Holly Siddens (336) 627-6015. Weil -McLain iM STORMWATER DISCHARGE OUTFALL (SDO) MONITORING REPORT Permit Number: NCS or SAMPLES COLLECTED DURING CALENDAR YEAR: 2016 Certificate of Coverage Number: NCG030548 (This monitoring report shall be received by the Division no later than 30 days from the date the facility receives the sampling results from the laboratory.) REC FACILITY NAME: Weil -McLain J�QU Rn`cki ghamy PERSON COLLECTING SAMPLE(S) Mir F PHONE NO. (336) 627-6037 or (336)-627-6000 CERTIFIED LABORATORY(S) Lab # u n CENTRAI; #(=ILE DWR SECTION SIGNATURE OF PERMITTEE OR DESIGNEE /REQUIRED ON PAGE 2. Part A: Specific Monitoring Requirements Outfall No. Date Sample Collected 50050 Total Flow (if app.) Total Rainfall moldd/ r MG inches SDO#6 NO FLOW 7 SDO#7 NO FLOW 7 SDO#S NO FLOW SDO#9 NO FLOW SDO#10 NO FLOW SDO#11 NO FLOW SDO#12 NO FLOW SD0413 NO FLOW 5 Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?_ yes x no (if yes, complete Part B) Part B: Vehicle Maintenance Activity Monitoring Requirements Outfall Date 50050 00556 00530 00400 No. Sample Total Flow Total Rainfall Oil & Grease Non -polar Total pH New Motor Oil Collected (if applicable) (if appl.) O&G/TPH Suspended Usage (Method 1664 Solids SGT-HEM), if appl. molddl r MG inches mg/1 m /l Units al/mo NIA Form SWU-246, last revised 21212012 Page l of 2 STORM EVENT CHARACTERISTICS: All storm events for the first either did not meet the definition of "measurable event", did not occur during normal business hours or posed a hazard to our employees (ice, or lightning) Mail Original and one copy to: Division of Water Quality Attn: Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 "I certify, under penalty of law, thattthis document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the po of fines and imprisonment for knowing violations." X---- Aco� l �e_s �16 (Signature of Permit (Date) r Form SWU-246, last revised 21212012 Page 2 of 2 TTO Certification Statement "Based on my inquiry of the person or persons directly responsible for managing compliance with the permit limitation for Total Toxic Organics (TTO), I certify to the best of my knowledge and belief, no leak, no spill, or dumping of concentrated toxic organics into the stormwater or onto areas which are exposed to rainfall or stormwater runoff has occurred since filing the last discharge monitoring report. 1 further certify that this facility is implementing all the provisions of the Solvent Management Plan included in the Stormwater Pollution Prevention Plan." zo/& Mark Dafilaine Site Director, Weil -McLain, Eden, NC RECEIVED AUG 0 9 a;. - CENTRAL FILES `VVR SECTION WEWRLAIN' July 29, 2016 Central Files Division of Water Quality 1617 Mail Service Center Raleigh, NC 27699-1617 RE: Explanation of Stormwater Monitoring Report Dear Sir or Madam: 523 S. New Street Eden, NC 27288 P: 336-627-6000 F: 336-627-6065 RECEIVED AUG 0 9 2016 CENTRAL FILES DVVR SECTION In accordance with NPDES (NCG030000) Stormwater Permit Condition Part II Section B, please see completed Stormwater Discharge Monitoring Report. For the first half of the year we were unable to collect samples as required. All storm event either did not meet the definition of measurable, occurred outside normal business hours, or posed additional hazard to our employees (ice or lightning). Therefore, NO FLOW was reported for all outfalls. Weil -McLain did contact Glen White at the Winston Salem Regional Office on 7/28/16 to discuss this, and also scheduled a site visit to review our current outfalls. Also enclosed is TTO verification statement as required. If you have any questions regarding the enclosed reports, please contact Melinda Smith (336)627-6037 Mark Dill ne Site Dir or Weil -McLain Permit Number: NCS Certificate of Coverage Number: NCG030548 STORMWATER DISCHARGE OUTFALL (SDO) MONITORING REPORT or SAMPLES COLLECTED DURING CALENDAR YEAR: 2015 (This monitoring report shall he received by the Division no later than 30 days from the date the facility receives the sampling results from the laboratory.) FACILITY NAME: Weil -McLain PERSON COLLECTING SAMPLE(S): Paul Smith & Mike Moretz CERTIFIED LABORATORY(S): Pace Analytical Services Inc., Lab # See Analytical Data Lab # JQU.0 S NMCI S311- I"J.N30 Part A: Specific Monitoring Requirements 9W 0.9 AON COUNTY Rockingham PHONE NO. (336) 627-6024 SIGNATURE OF PERMITTEE OR DESIGNEE REQUIRED ON PAGE 2. Outfall No. Date Sample Collected, molddlyr 00530 1 051 00556 78141 Total Suspended Solids, mg/L pH, Standard Units Total Lead, mg/L Total Copper, mglL Total Zinc, mglL Oil and Grease, mg/L Total Toxic Organics, mglL Benchmark 100 Within 6.0-9.0 0.030 0.007 0.067 15 I Baseline 10/27/15 5.1 SDO #6 10/27/15 6.2 6.0 <0.0050 0.0052 0..017 <5.0 <0.05 SDO #7 10/27/15 6.8 5.9 <0.005 0.051 0.19 <5.0 <0.05 SDO #8 10/27/15 5.2 5.5 <0.005 0.0067 0.053 <5.0 <0.05 SDO #9 No Flow No Flow No Flow No Flow No Flow No Flow No Flow No Flow SDO #10 No Flow No Flow No Flow No Flow No Flow No Flow No Flow No Flow SDO #11 10/27/15 21.6 7.9 <0.005 0.095 0.072 <5.0 <0.05 SDO #12 10/27/15 <2.5 6.0 <0.005 0.0059 0.037 <5.0 <0.05 SDO #13 No Flow No Flow No Flow No Flow No Flow No Flow No Flow No Flow Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier I or Tier2 responses. See General Permit text. Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _yes _X_no (if yes, complete Part B) Cj so WA Page 1 of 2 Part B: Vehicle Maintenance Activity Monitoring Requirements Outfall No. Date Sample Collected, moldd/ r 00556 00530 00400 Oil and Grease, m /L Total Suspended Solids pH, Standard units New Motor Oil Usage, Annual averse al/mo 30 m Il Within 6.0-9.0 - NIA Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier I or Tier2 responses. See General Permit text. STORM EVENT CHARACTERISTICS: Date: 10/27/15 Total Event Precipitation (inches): 1.13" Mail Original and one copy to: Division of Water Quality Attn: Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." (Signature of Permittee) (Date) Page 2 of 2 M LAIN® 9JER ■ 523 S. New Street Eden, NC 27288 P: 336-627-6000 F. 336-627-6065 November 23, 2015 Central Files Division of Water Quality 1617 Mail Service Center Raleigh, NC 27699-1617 RE: Explanation of Stormwater Monitoring Report Dear Sir or Madam: In accordance with NPDES (NCG030000) Stormwater Permit Condition Part II Section B, the second of two semi—annual sampling events has been completed and is attached. Monitoring was conducted for Stormwater discharge outfalls 6-13 (SDO) as identified in the SWPPP, with "NO FLOW" being reported for three of the outfalls. The DMR, Storm data (local onsite readings), and analytical data is attached. As indicated in the enclosed Stormwater Monitoring Report, there were six that were outside the benchmarks. Tier One actions have been implemented, and the SWPPP has been updated to include the following: • Additional inspection with detailed observation of the outfalls. Investigation and root cause analysis and corrective actions on SD#7 and #11. The total rainfall recorded under Part A of the Stormwater Discharge Outfall (SDO) Monitoring Report is listed as 1.13" and Stormwater samples were pulled within the first 30 minutes of discharge. If you have any questions regarding the enclosed reports, please contact Michael Thomason at (336)627- 6024. Sincerely, Eric Chack Vice President of Operations Weil -McLain (�55'cmnalytical" www.pm*%ba.c= November 09, 2015 Mr. Paul Smith Weil McLain 523 S. New St. Eden, NC 27288 RE: Project: Storm Water Testing Pace Project No.: 92273535 Dear Mr. Smith: Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 2728E (336)623-8321 Enclosed are the analytical results for sample(s) received by the laboratory on October 27, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, r Brittany Gibson brittany.gibson@pacelabs.com Project Coordinator Enclosures ACCREG 2 �O `9eORAt� REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 1 of 50 lac6Analytical" wimpacelabacam Project: Storm Water Testing Pace Project No.: 92273535 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Charlotte Certification IDs 9800 Kincey Ave, Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Certification #: 99006001 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 Eden Certification IDs 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #; 37738 CERTIFICATIONS Florid a1N ELAP Certification #: E87627 Kentucky UST Certification #: 84 West Virginia Certification #: 357 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification At: 99030001 West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 North Carolina Wastewater Certification #: 633 Virginia/VELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 50 lacmnalyfical' www.pecalah&=n SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. 205 East Meadow Road - Suite Eden, NC 27288 (336)623-8921 Project: Pace Project No.: Storm Water Testing 92273535 Analytes Lab lD Sample ID Method Analysts Reported Laboratory 92273535001 SDO 96 SM 2540D KCE 1 PASI-E SM 4500-H+B KCE 1 PASI-E EPA 1664B JMS 1 PASi-C EPA 608 SWB 27 PASI-C EPA 200.7 CDF 3 PASI-A EPA 625 BPJ 65 PASI-C EPA 624 GAW 72 PASI-C 92273535002 SDO #7 SM 2540D KCE 1 PASI-E SM 4500-H+B KCE 1 PASI-E EPA 1664B JMS 1 PASI-C EPA 608 SWB 27 PASI-C EPA 200.7 CDF 3 PASI-A EPA 625 BPJ 65 PASI-C EPA 624 GAW 72 PASI-C 92273535003 SDO #8 SM 2540D KCE 1 PASI-E SM 4500-H+B KCE 1 PASI-E EPA 1664B JMS 1 PASI-C EPA 608 SWB 27 PASI-C EPA 200.7 CDF 3 PASI-A EPA 625 BPJ 65 PASI-C EPA 624 GAW 72 PASI-C 92273535004 SDO #11 SM 2540D KCE 1 PASI-E SM 4500-H+B KCE 1 PASI-E EPA 1664B JMS 1 PASI-C EPA 608 SWB 27 PASI-C EPA 2007 CDF 3 PASI-A EPA 625 BPJ 65 PASI-C EPA 624 GAW 72 PASI-C 92273535005 SDO #12 SM 2540D KCE 1 PASI-E SM 4500-H+B KCE 1 PASI-E EPA 1664E JMS 1 PASI-C EPA 608 SWB 27 PASI-C EPA 200.7 CDF 3 PASI-A EPA 625 BPJ 65 PASI-C EPA 624 GAW 72 PASI-C 92273535006 FALLING SAMPLE SM 4500-H+B KCE 1 PASI-E REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 50 i lce Analytical " "w.pecelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: Storm Water Testing Pace Project No.: 92273535 Sample: SOO #6 Lab ID: 92273535001 Collected: 10/27/15 00:00 Received: 10/27/15 15:15 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 25400 Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 6.2 mglL 2,5 1 10/28/15 13:06 4500H+ pH, Electrometric EDN Analytical Method: SM 4500-H+B pH at 25 Degrees C 6.0 Std. Units 1.0 1 10/27/15 16:25 H6 1664 SGT-HEM, TPH Analytical Method: EPA 1664B Total Petroleum Hydrocarbons ND mg1L 5.0 1 11/05/15 08:07 608 GCS Pesticldes and PCBs Analytical Method: EPA 608 Preparation Method: EPA 3510 Aldrin NO mg1L 0.000050 1 40/29/15 11:00 10/31/15 00:34 309-00-2 alpha-BHC NO mg1L 0.000050 1 10/29/15 11:00 10/31/15 00:34 319-84-6 beta-BHC NO mg1L 0,000050 1 10/29/15 11:00 10/31/15 00:34 319-85-7 deita-BHC NO mglL 0.000050 1 10/29/15 11:00 10/31/15 00:34 319-86-8 gamma-BHC (Lindane) NO mglL 0.000050 1 10/29/15 11:00 10/31/15 00:34 58-89-9 Chlordane (Technical) NO mg1L 0.00050 1 10/29/15 11:00 10/31/15 00:34 57-74-9 4,4'-DDD NO mg1L 0.000050 1 10/29/15 11:00 10/31/15 00:34 72-54-8 4,4'-DDE NO mglL 0.000050 1 10129/1511:00 10/31/15 00:34 72-55-9 4,4'-DDT NO mg1L 0.000050 1 10/29/15 11:00 10131/1500:34 50-29-3 Dieldrin NO mg1L 0.000050 1 10/29/15 11:00 10/31/15 00:34 60-57-1 Endosulfan I NO mglL 0.000060 1 10/29/15 11:00 10/31/15 00:34 959-98-8 Endosulfan II NO mg1L 0.000050 1 10/29/15 11:00 10/31/15 00:34 33213-65-9 Endosulfan sulfate NO mg1L 0.000050 1 10/29/15 11:00 10/31/15 00:34 1031-07-8 Endrin NO mg1L 0.000050 1 10/29/15 11:00 10/31/15 00:34 72-20-8 Endrin aldehyde NO mg1L 0.000050 1 10/29/15 11:00 10/31/15 00:34 7421-93-4 Heptachlor NO mg1L 0.000050 1 10129/1511:00 10/31/15 00:34 76-44-8 Heptachlor epoxide NO mg1L 0.000050 1 10/29/15 11:00 10/31/15 00:34 1024-57-3 PCB-1016 (Aroclor 1016) ND mg1L 0.00050 1 10/29/15 11:00 10/31/15 00:34 12674-11-2 PCB-1221 (Aroclor 1221) ND mg1L 0.00050 1 10129/1511:00 10/31/15 00:34 11104-28-2 PCB-1232 (Aroclor 1232) NO mg1L 0.00050 1 10/29/15 11:00 10/31/15 00:34 11141-16-5 PCB-1242 (Aroclor 1242) NO mg1L 0.00050 1 10/29/15 11:00 10/31/15 00:34 53469-21-9 PCB-1248 (Aroclor 1248) NO mg11- 0.00050 1 10/29/15 11:00 10/31/15 00:34 12672-29-6 PCB-1254 (Aroclor 1254) NO mg1L 0.00050 1 10/29/15 11:00 10/31/15 00:34 11097-69-1 PCB-1260 (Aroclor 1260) ND mg1L 0.00050 1 10/29/15 11:00 10/31/15 00:34 1109"2-5 Toxaphene ND mglL 0.00050 1 10/29/15 11:00 10131/1500:34 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 58 % 20-110 1 10/29/15 11:00 10/31/15 00:34 877-09-8 Decachlorobiphenyl (S) 38 % 20-138 1 10/29/15 11:00 10/31/15 00:34 2051-24-3 200.7 MET ICP Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 Copper 0.0052 mg1L 0.0050 1 10/30/15 20:30 11/03/15 23:48 7440-50-8 Lead ND mg1L 0.0050 1 10/30/15 20:30 11/03/15 23:48 7439-92-1 Zinc 0.017 mg1L 0.010 1 10/30/15 20:30 11/03/15 23:48 7440-66-6 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 Acenaphthene ND mg1L 0.0050 1 10/29/15 15:33 11/03/15 00:42 83-32-9 Acenaphthylene NO mg1L 0.0050 1 10/29/15 15:33 11/03/15 00:42 208-96-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/09/2015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 4 of 50 aceAnalytical www.pecelabsc= ANALYTICAL RESULTS Project: Storm Water Testing Pace Project No.: 92273535 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Sample: SOO #6 Parameters Lab ID: 92273535001 Results Units Collected: 10/27115 00:00 Report Limit OF Received: 10/27/15 15:15 Matrix: Water Prepared Analyzed CAS No. Quaff 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 Acetophenone ND mg1L 0.0050 1 10/29/15 15:33 11/03/15 00:42 98-86-2 Aniline ND mg1L 0.010 1 10/29/15 15:33 11/03/15 00742 62-53-3 Anthracene ND mg1L 0.0050 1 10/29/15 15:33 11/03/15 00:42 120-12-7 Benzidine NO mg1L 0.050 1 10/29/15 15:33 11/03/15 00:42 92-87-5 L2 Benzo(a)anthracene ND mg1L 0.0050 1 10/29/15 15:33 11/03/15 00A2 56-55-3 Benzo(a)pyrene NO mg1L 0.0050 1 10/29/15 15:33 11/03/15 00:42 50-32-8 Benzo(b)fluoranthene NO mg1L 0.0050 1 10/29/15 15:33 11/03/15 00:42 205-99-2 Benzo(g,h,i)perylene NO mg/L 0.0050 1 10/29/15 15:33 11/03/15 00:42 191-24-2 Benzo(k)fluoranthene NO mg1L 0.0050 1 10/29/15 15:33 11/03/15 00:42 207-08-9 4-Bromophenylphenyl ether NO mg/L 0.0050 1 10/29/15 15:33 11/03/15 00A2 101-55-3 Butylbenzylphthalate NO mg/L 0.0050 1 10/29/15 15:33 11/03/15 00:42 85-68-7 4-Chloro-3-methylphenol NO mg/L 0.0050 1 10/29/15 15:33 11/03/15 00:42 59-50-7 bis(2-Chloroethoxy)methane ND mg/L 0.010 1 10/29/15 15:33 11/03/15 00:42 111-91-1 bis(2-Chloroethyl) ether ND mg/L 0.0050 1 10/29/15 15:33 11/03/15 00:42 111-44-4 bis(2-Chloroisopropyl) ether ND mg/L 0.0050 1 10/29/15 15:33 11/03/15 00:42 108-60-1 2-Chloronaphthalene NO mg/L 0.0050 1 10/29/15 15:33 11/03/15 00:42 91-58-7 2-Chlorophenol NO mg/L 0.0050 1 10/29/15 15:33 11/03/15 00:42 95-57-8 4-Chlorophenylphenyl ether NO mg/L 0.0050 1 10/29/15 15:33 11/03/15 00:42 7005-72-3 Chrysene ND mg/L 0.0050 1 10/29/15 15:33 11/03/15 00:42 218-01-9 Dibenz(a,h)anthracene NO mg/L 0.0050 1 10/29/15 15:33 11/03/15 00:42 53-70-3 1,2-Dichlorobenzene NO mg/L 0,0050 1 10/29/15 15:33 11/03/15 00:42 95-50-1 1,3-Dichlorobenzene ND mglL 0.0050 1 10/29/15 15:33 11/03/15 00:42 541-73-1 1,4-Dichlorobenzene NO mg/L 0.0050 1 10/29/15 15:33 11/03/15 00:42 106-46-7 3,3'-Dichlorobenzidine NO mglL 0.025 1 10/29/15 15:33 11/03/15 00:42 91-94-1 2,4-Dichlorophenol NO mglL 0.0050 1 10/29/15 15:33 11/03/15 00:42 120-83-2 Diethylphthalate ND mg/L 0.0050 1 10/29/15 15:33 11/03/15 00:42 84-66-2 2,4-Dimethylphenol NO mg/L 0.010 1 10/2911515:33 11/0311500:42 105-67-9 Dimethylphtha late NO mg/L 0.0050 1 10/29/15 15:33 11/0311500:42 131-11-3 Di-n-butylphthalate NO mglL 0.0050 1 10/29/15 15:33 11/03/15 00:42 84-74-2 4,6-Dinitro-2-methylphenol NO mglL 0.020 1 10/2911515:33 11/0311500:42 534-52-1 2,4-Dinitrophenol NO mg/L 0.050 1 10/29/15 15:33 11/0311500:42 51-28-5 2,4-Dinitrotoluene NO mglL 0,0050 1 10129/1515:33 11/0311500:42 121-14-2 2,6-Dinitrotoluene NO mg/L 0.0050 1 10/29/15 15:33 11/03/15 00:42 606-20-2 Di-n-octylphthalate NO mg/L 0.0050 1 10/29/15 15:33 11/03/15 00:42 117-84-0 1,2-Diphenylhydrazine NO mg/L 0.0050 1 10/29/1515:33 11/0311500:42 122-66-7 bis(2-Ethylhexyl)phthalate NO mg/L 0.0050 1 10/29/15 15:33 11/03/15 00:42 117-81-7 Fluoranthene NO mg/L 0.0050 1 10/29/15 15:33 11/0311500:42 206-44-0 Fluorene NO mg/L 0.0050 1 10/29/15 15:33 11/03/15 00:42 86-73-7 Hexachloro-1,3-butadiene NO mg/L 0.0050 1 10/29/15 15:33 11/0311500:42 87-68-3 Hexachloroberizene NO mg/L 0.0050 1 10/2911515:33 11/03/15 00:42 118-74-1 Hexachlorocyclopentadiene NO mg/L 0.010 1 10129/1515:33 11/0311500:42 77-47-4 Hexachloroethane NO mg/L 0.0050 1 10/29/15 15:33 11/0311500:42 67-72-1 Indeno(1,2,3-cd)pyrene ND mg/L 0.0050 1 10/29/15 15:33 11/0311500:42 193-39-5 Isophorone NO mg/L 0.010 1 10/29/15 15:33 11/0311500:42 78-59-1 Naphthalene NO mg/L 0.0050 1 10129/1515:33 11/0311500:42 91-20-3 Nitrobenzene NO mg/L 0.0050 1 10/29/15 15:33 11/03/15 00:42 98-95-3 2-Nitrophenoi NO mg/L 0.0050 1 10/29/15 15:33 11/03/15 00:42 88-75-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/09/2015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 5 o150 (�IaneAnalytical' www.pe ;d&bS'=n ANALYTICAL RESULTS Pace Analytical Services, Inc. 205 East Meadow Road - Suite Eden, NC 27288 (336)623-8921 Project: Storm Water Testing Pace Project No.: 92273535 Sample: SDQ #6 Lab ID: 92273535001 Collected: 10/27/15 00:00 Received: 10/27/16 15:15 Matrix: Water. Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 4-Nitrophenol N❑ mg1L 0.050 1 10/29/15 15:33 11/03/15 00A2 100-02-7 N-Nitrosodimethylamine NO mg1L 0.0050 1 10/29/15 15:33 11/03/15 00:42 62-75-9 . N-Nitroso-di-n-propylamine NO mg1L 0.0050 1 10/29/15 15;33 11/03/15 00:42 621-64-7 N-Nitrosodiphenylamine NO mg1L 0.010 1 10/29/15 15:33 11/03/15 00:42 86-30-6 Pentachlorophenot NO mg1L 0.010 1 10/29/15 15:33 11/03/15 00:42 87.86-5 Phenanthrene NO mg1L 0.0050 1 10/29/15 15:33 11/03/15 00:42 85-01-8 Phenol NO mg1L 0.0050 1 10/29/15 15:33 11/03/15 00742 108-95-2 Pyrene ND mg1L 0.0050 1 10/29/15 15:33 11/03/15 00:42 129-00-0 1,2,4-Trcchoorobenzene NO mg1L 0.0050 1 10/29/15 15:33 1110311500:42 120-82-1 2,4,6-Trichlorophenol NO mglL 0.010 1 10/29/15 15:33 11/03/15 00:42 88-06-2 Surrogates Nitrobenzene-d5 (S) 48 % 10-120 1 10/29/15 15:33 11/03/15 00:42 4165-60-0 2-Fluorobiphenyl (S) 48 % 15-120 1 10/29/15 15:33 11/03/15 00A2 321-60-8 Terphenyl-d14 (S) 69 % 11-131 1 10/29/15 15:33 11/03/15 00:42 1718-51-0 Phenol-d6 (S) 18 % 10-120 1 10/29/15 15:33 11/03/15 00:42 13127-88-3 2-Fluorophenol (S) 25 % 10-120 1 10/29/15 15:33 11/03/15 00A2 367-12-4 2,4,6-Tribromophenol (S) 69 % 10-137 1 10/29/15 15:33 11/03/15 00:42 118-79-6 624 Volatile Organics Analytical Method: EPA624 Acetone NO mg/t_ 0.010 1 10/3111512:39 67-64-1 Acrolein NO mg1L 0.0050 1 10/3111512:39 107-02-8 Acrylonitrile NO mg/1- 0.050 1 1013111512:39 107-13-1 Benzene NO mglL 0.0020 1 1013111512:39 71-43-2 Bromobenzene NO mglL 0.0020 1 10/3111512:39 108-86-1 Bromochloromethane ND mg1L 0.0020 1 1013111512:39 74-97-5 Bromodichloromethane ND mglL 0,0020 1 10/31/1512:39 75-274 Bromoform ND mg1L 0.0020 1 1013111512:39 75-25-2 Bromomethane ND mglL 0.0020 1 1013111512:39 74-83-9 2-Butanone (MEK) NO mglL 0.0050 1 10/31/15 12:39 78-93-3 n-Butylbenzene NO mglL 0.0050 1 10/3111512:39 104-51-8 sec -Butyl benzene NO mgfL 0.0050 1 1013111512:39 135-98-8 tert-Butylbenzene NO mglL 0.0050 1 10/3111512:39 98-06-6 Carbon disulfide NO mg1L 0.0050 1 10/31/15 12:39 75-15-0 L3 Carbon tetrachloride NO mglL 0,0020 1 10/31/15 12:39 56-23-5 Chlorobenzene NO mglL 0.0020 1 10/3111512:39 108-90-7 Chloroethane ND mglL 0.0020 1 10/31/1512:39 75-00-3 2-Chloroethylvinyl ether NO mglL U050 1 10/31/15 12:39 110-75-8 c2 Chloroform NO mglL 0.0020 1 10/31/1512:39 67-66-3 Chloromethane NO mg/L 0,0020 1 10/31/1512:39 74-87-3 2-Chlorotoluene NO mg1L 0.0020 1 10/31/1512:39 95-49-8 4-Chlorotoluene NO mglL U020 1 10131/1512:39 106-43-4 Dibromochloromethane NO mglL 0.0020 1 10/3111512:39 12448-1 1,2-Dibromoethane (EDB) NO mglL 0.0020 1 10/31/15 12:39 106-93-4 Dibromomethane NO mglL 0,0020 1 10/31/1512:39 74-95-3 1,2-Dichlorobenzene NO mglL 0.0020 1 10/3111512:39 95-50-1 1,3-Dichlorobenzene NO mglL 0.0020 1 1013111512:39 541-73-1 1,4-Dichlorobenzene NO mg1L 0,0020 1 10/3111512:39 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/09/2015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 6 of 50 leAnalytical wwwpacelehsc= ANALYTICAL RESULTS Pace Analytical Services, Inc. 205 East Meadow Road - Suite Eden, NC 27288 (336)623-8921 Project: Storm Water Testing Pace Project No.: 92273535 Sample: SDO #6 Lab ID: 92273535001 Collected: 10/27/15 00:00 Received: 10/27/15 15:15 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 624 Volatile Organics Analytical Method: EPA624 1,1-Dichloroethane ND mg1L 0.0020 1 1013111512:39 75-34-3 1,2-Dichloroethane ND mg1L 0,0020 1 10/3111512:39 107-06-2 1,1-Dichloroethene ND mg1L 0.0020 i 10131/1512:39 75-35-4 cis-1,2-Dichloroethene . ND mg/L 0.0020 1 10/31115 12:39 156-59-2 trans- l,2-Dichloroethene ND mg1L 0.0020 1 1013111512:39 156-60-5 1,2-Dichicropropane ND mg1L 0.0020 1 10/31/1512:39 78-87-5 1,3-Dichloropropane ND mg1L 0,0020 1 10/3111512:39 142-28-9 2,2-Dichloropropane ND mg1L 0.0050 1 1013111512:39 594-20.7 1, 1 -Dichloropropene ND mg/L 0.0020 1 10/3111512:39 563-%6 cis-1,3-Dichloropropene ND mg/L 0,0020 1 10/3l/1512:39 10061-01-5 trans-1,3-Dichloropropene ND mg1L 0.0020 1 10/3111512:39 10061-02-6 Ethylbenzene ND mg/L 0.0020 1 1013111512:39 100-41-4 Hexachloro-1,3-butadfene ND mg/i_ 0.0050 1 1013111512:39 87-68-3 2-Hexanone ND mgli 0.010 1 1013111512:39 591-78-6 lodomethane ND mg1L 0.010 1 1013111512:39 74-88-4 Isopropylbenzene (Cumene) ND mg1L 0,0050 1 10/31/15 12:39 98-82-8 p-Isopropyltoluene ND mg1L 0.0050 1 1013111512:39 99-87-6 Methylene Chloride ND mg1L 0.0020 1 10/31/15 12:39 75-09-2 4-Methyl-2-pentanone (MIRK) ND mg1L 0.010 1 10/31115 12:39 108-10-1 Methyl-tert-butyl ether ND mg1L 0.0050 1 10/31115 12:39 1634-04-4 Naphthalene ND mg1L 0.0050 1 101310512:39 91-20-3 n-Propylbenzene ND mg1L 0.0050 1 10/3111512:39 103-65-1 Styrene ND mg1L 0.0020 1 10/3111512:39 100-42-5 1,1,1,2-Tetrachloroethane ND mg1L 0,0020 1 1013111512:39 630-20-6 1,1,2,2-Tetrachloroethane ND mg1L 0.0020 1 10/3111512:39 79-34-5 Tetrachloroethene ND mg1L 0.0020 1 1013111512:39 127-18-4 Toluene ND mg/L 0,0020 1 1013111512:39 108-88-3 1,2,3-Trichlorobenzene ND mg1L 0.0020 1 1013111512:39 87-61-6 1,2,4-Trichlorobenzene ND mg1L 0.0020 1 10/3111512:39 120-82-1 1,1,1-Trichioroethane ND mg1L 0.0020 1 10/3111512:39 71-55-6 1.1,2-Trichloroethane ND mg1L 0.0020 1 1013111512:39 79-00-5 Trichloroethene ND mg/L 0,0020 1 1013111512:39 79-01-6 Trichlorofluoromethane ND mg1L 0.0020 1 1013111512:39 75-69-4 1,2,3-Trichloropropane ND mg1L 0.0020 1 1013111512:39 96-18-4 1, 1,2-Tdchlorotrifluoroethe ne ND mg1L 0.0020 1 1013111512:39 76-13-1 1,2,4-Trimethylbenzene ND mg1L 0.0020 1 1013111512:39 95-63-6 1,3,5-Trimethyibenzene ND mg1L 0.0020 1 1013111512:39 108-67-8 Vinyl acetate ND mg1L 0.0050 1 10/31/15 12:39 108-06-4 Vinyl chloride ND mg1L 0.0020 1 10131/15 12:39 75-01-4 m&p-Xylene ND mg1L 0.0050 1 10131/1512:39 179601-23-1 o-Xylene ND mg1L 0.0050 1 1013111512:39 95-47-6 Surrogates 4-BromoFluorobenzene (S) 103 % 70-130 1 10/31/15 12:39 460-00-4 Toluene-d8 (S) 100 % 70-130 1 10/31/15 12:39 2037-26-5 1,2-Dichloroethane-d4 (S) 88 % 70-130 1 10/31/15 12:39 17060-07-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/09/2015 08:46 AM without the written consent of Pace Analytical Services, Inc- Page 7 of 50 (�Ia'cmnalytical" www.pacelab&wm ANALYTICAL RESULTS Project: Storm Water Testing Pace Project No.: 92273535 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Sample: SDO 97 Lab ID: 92273535002 Collected: 10/27/15 00:00 Received: 10/27/15 15:15 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 254DD Total Suspended Solids Total Suspended Solids 4500H+ pH, Electrometric EDN pH at 25 Degrees C 1664 SGT-HEM, TPH Total Petroleum Hydrocarbons 608 GCS Pesticides and PCBs Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC (Lindane) Chlordane (Technical) 4,4'-DDD 4,4'-DDE 4,4'-DDT Dieldrin Endosulfan I Endosulfan 11 Endosulfan sulfate Endrin Endrin aldehyde Heptachlor Heptachlor epoxide PCB-1016 (Aroclor 1016) PCB-1221 (Aroclor 1221) PCB-1232 (Aroclor 1232) PCB-1242 (Aroclor 1242) PCB-1248 (Aroclor 1248) PCB-1254 (Aroclor 1254) PCB-1260 (Aroclor 1260) Toxaphene Surrogates Tetrachloro-m-xylene (S) Decachlorobiphenyl (S) 200.7 MET ICP Copper Lead Zinc 625 MSSV Acenaphthene Acenaphthylene Date: 11 /09/2015 08:46 AM Analytical Method: SM 2540D 6.8 mg1L 2.5 1 10/2811513:07 Analytical Method: SM 4500-H+B 5.9 Std. Units 1.0 1 10/27/15 16:25 Analytical Method: EPA 1664B ND mg1L 5.0 1 11/05/15 08:08 Analytical Method: EPA608 Preparation Method: EPA3510 ND mglL 0.000050 1 10/29/15 11:00 10/31/15 00:52 309-00.2 N❑ mg1L 0.000050 1 10/2911511:00 1013 Ili 5 00:52 319-84-6 ND mg1L 0.000050 1 10/29/15 11:00 10/31/15 00:52 319-85-7 ND mg1L 0.000050 1 10/29/15 11:00 10/31/15 00:52 319-86-8 ND mg1L 0.000050 1 10/29/15 11:00 10/31/15 00:52 58-89-9 ND mg/L 0.00050 1 10/29/15 11:00 10/31115 00:52 57-74-9 ND mg1L 0.000050 1 10/29/15 11:00 10/31/15 00:52 72-54-8 ND mg1L 0.000050 1 10/29/15 11:00 10131li5 00:52 72-55-9 ND mg1L 0,000050 1 10/29/15 11:00 10131/15 00:52 50-29-3 ND mg1L 0.000050 1 10/29/15 11:00 10131/15 00:52 60-57-1 ND mg1L 0.000050 1 10/29/15 11:00 10/31115 00:52 959-98-8 ND mg1L 0.000050 1 10/29/15 11:00 10131/15 00:52 33213-65-9 ND mg1L 0.000050 1 10/29/15 11:00 10131/15 00:52 1031-07-8 ND mglL 0.000050 1 10/29/15 11:00 10/31/15 00:52 72-20-8 ND mg1L 0.000050 1 10/29/15 11:00 10131/15 00:52 7421-93-4 ND mg1L 0.000050 1 10/29/15 11:00 10131/15 00:52 76-44-8 ND mg1L 0.000050 1 10/29/15 11:00 10/31/15 00:52 1024-57-3 ND mg1L 0.00050 1 10/29/15 11:00 10/31/15 00:52 12674-11-2 ND mg1L 0.00050 1 10/29/15 11:00 10/31115 00:52 11104-28-2 ND mg1L 0.00050 1 10/29/15 11:00 10/31/15 00:52 11141-16-5 ND mg1L 0.00050 1 10/29/15 11:00 10/31/15 00:52 53469-21-9 ND mglL 0.00050 1 10/29/15 11:00 10/31/15 00:52 12672-29-6 ND mg1L 0.00050 1 10/29/15 11:00 10/31/15 00752 11097-69-1 ND mg1L 0.00050 1 10129/15 11:00 10/31/15 00:52 11096-82-5 ND mg1L 0.00050 1 10/29/15 11:00 10/31/15 00:52 8001-35-2 56 % 20-110 1 10129/15 11:00 10/31/15 00:52 877-09-8 60 % 20-138 1 10129/15 11:00 10/31/15 00:52 2051-24-3 Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 0.0D51 mg1L 0.0050 1 10/30/15 20:30 11/05/15 18:03 7440-50-8 ND mg1L 0.0050 1 10130/15 20:30 11/05/15 18:03 7439-92-1 0.19 mg/L 0.010 1 10130/15 20:30 11/05/15 18703 7440-66-6 Analytical Method: EPA625 Preparation Method: EPA625 ND mg/L 0.0050 1 10/29/15 15:33 10/31/15 03:49 83-32-9 ND mg1L 0.0050 1 10/29/15 15:33 10/31115 03A9 208-96-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. H6 Page 8 of 50 Pace Analytical Services, Inc. (�55'&eAnalytica! 205 East Meadow Road - Suite A Eden, NC 27288 www.perelaLscam {336}623-8921 ANALYTICAL RESULTS Project: Storm Water Testing Pace Project No.: 92273535 Sample: SDO #7 Lab ID: 92273535002 Collected: 10/27/15 00:00 Received: 10/27/15 15:15 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 Acetophenone ND mg1L 0.0050 1 10129/15 15:33 10/31/15 03:49 98-86-2 Aniline ND mg1L 0.010 1 10/2911515:33 10131/15 03:49 62-53-3 Anthracene ND mg1L 0.0050 1 10/29115 15:33 10/31/15 03:49 120-12-7 Benzidine ND mg1L 0.050 1 10/29/15 15:33 10/31/15 03:49 92-87-5 L2 Benzo(a)anthracene ND mg1L 0.0050 1 10129/1515:33 10/31/15 03:49 56-55-3 Benzo(a)pyrene ND mg1L 0.0050 1 10/29/15 15:33 10/31/15 03:49 50-32-8 Benzo(b)fluoranthene NO mg/L 0.0050 1 1012911515:33 10131/15 03:49 205-99-2 Benzo(g,h,i)perylene ND mg1L 0.0050 1 10/29/15 15:33 10/31/15 03:49 191-24-2 Benzo(k)fluoranthene ND mg1L 0.0050 1 10/29/15 15:33 10/31/15 03:49 207-08-9 4-Bromophenylphenyl ether ND mg/L 0.0050 1 10/29/15 15:33 10131/15 03:49 101-55-3 Butylbenzylphihalate ND mg/L 0.0050 1 10/29/15 15:33 10131/15 03:49 85-68-7 4-Chloro-3-methylphenol ND mg1L 0.0050 1 10/29/15 15:33 10/31/15 03:49 59-50-7 bis(2-Chloroethoxy)methane ND mg1L 0.010 1 10/29/15 15:33 10/31/15 03:49 111-91-1 bis(2-Chloroethyl) ether ND mg/L 0.0050 1 10/29/15 15:33 10/31M5 03:49 111-44-4 bis(2-Chloroisopropyl) ether ND mg/L 0.0050 1 10/29/15 15:33 10/31/15 03:49 108-60-1 2-Chloronaphthalene ND mg1L 0.0050 1 10/29/15 15:33 10/31/15 03A9 91-58-7 2-Chlorophenol ND mg/L 0.0050 1 10/29/15 15:33 10/31/15 03:49 95.57-8 4-Chlorophenylphenyi ether ND mg/L 0.0050 1 10/29/15 15:33 10/31/15 03A9 7005-72-3 Chrysene ND mg/L 0.0050 1 10/29/15 15:33 10/31/15 03A9 218-01-9 Dibenz(a,h)anthracene ND mg/L 0.0050 1 10/29/15 15:33 10/31/15 03:49 53.70-3 1,2-Dichlorobenzene ND mglL 0.0050 1 10/2911515:33 10131/15 03:49 95-50-1 1,3-Dichlorobenzene ND mg/L 0.0050 1 10/29/15 15:33 1013111503749 541-73-1 1,4-Dichlorobenzene ND mg/L 0.0050 1 10/29/15 15:33 1013111503:49 106-46-7 3,3'-Dichlorobenzidine ND mg/L 0,025 1 10/2911515:33 1013111503A9 91-94-1 2,4-Dichlorophenol ND mg/L 0.0050 1 10/29/15 15:33 10/31/15 03A9 120-83-2 Diethylphthalate ND mg/L 0.0050 1 10/29/15 15:33 10/31/15 03:49 84-66-2 2,4-Dimethylphenol ND mg/L 0.010 1 10/29/15 15:33 10/31/15 03:49 105-67-9 Dimethylphthalate ND mg/L 0.0050 1 10/29/15 15:33 10/31/15 03:49 131-11-3 Di-n-butylphthalate ND mg/L 0.0050 1 10/29/15 15:33 10/31/15 03:49 84-74-2 4,6- Din itro-2-methylphenol ND mg1L 0.020 1 10/29/15 15:33 10/31/15 03A9 534-52-1 2,4-Dinitrophenol ND mg/L 0.050 1 10/29/15 15:33 1013111503:49 51-28-5 2,4-Dinitrotoluene ND mg/L 0.0050 1 10/29/15 15:33 10/31/15 03:49 121-14-2 2,6-Dinitrotoluene ND mg/L 0.0050 1 10/29/15 15:33 10/31/15 03:49 606-20-2 Di-n-octylphthalate ND mg/L 0.0050 1 10/29/15 15:33 10/31/15 03:49 117-84-0 1,2-Diphenylhydrazine ND mg/L 0.0050 1 10129/1515:33 10/31/1503749 122-66-7 bis(2- Ethylhexyl)phtha late ND mg/L 0.0050 1 10/29/15 15:33 10/31/15 03:49 117-81-7 Fluoranthene ND mg/L 0.0050 1 10/29/15 15:33 10/31/15 03A9 206-44-0 Fluorene ND mg/L 0.0050 1 10/29/15 15:33 10/31/15 03:49 86-73-7 Hexachloro-1,3-butadiene ND mg/L 0.0050 1 10/29/15 15:33 10/31/15 03:49 87-68-3 Hexachlorobenzene ND mglL 0.0050 1 10/29/15 15:33 10/31/15 03:49 118-74-1 Hexachlorocyclopentadiene ND mg/L 0.010 1 10/29/15 15:33 10/31/15 03:49 77-47-4 Hexachloroethane ND mg1L 0.0050 1 10/29/15 15:33 10/31/15 03:49 67-72-1 Indeno(1,2,3-cd)pyrene ND mg/L 0.0050 1 10/29/15 15:33 10/31/15 03:49 193-39-5 Isophorone ND mg/L 0.010 1 10/29/15 15:33 10/31/15 03:49 78-59-1 Naphthalene ND mg/L 0.0050 1 10/29/15 15:33 10/31/15 03:49 91-20-3 Nitrobenzene ND mg/L 0.0050 1 10/29/15 15:33 10/31/15 03:49 98-95-3 2-Nitrophenol ND mg1L 0.0050 1 10/29/15 15:33 10/31/15 03:49 88-75-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/09/2015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 9 of 50 1aceAnalyfcal e www.pacelahs corn ANALYTICAL. RESULTS Project: Storm Water Testing Pace Project No.: 92273535 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Sample: SDO #7 Parameters Lab ID: 92273535002 Results Units Collected: 10127/15 00:00 Report Limit OF Received: 10/27/15 15:15 Matrix: Water Prepared Analyzed GAS No. Qual 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 4-Nitrophenol NO mg1L 0.050 1 10/29/15 15:33 10/31/15 03:49 100-02-7 N-Nitrosodimethylamine NO mg1L 0.0050 1 10/29/15 15:33 10/31/15 03:49 62-75-9 N-Nitroso-di-n-propyl a mine NO mglL 0.0050 1 10129/1515:33 1013111503:49 621-64-7 N-Nitrosodiphenylamine NO mglL 0.010 1 10/29/15 15:33 10/31/15 03:49 86-30-6 Pentachtorophenot ND mglL 0.010 1 10/29/15 15:33 10/31/15 03:49 87-86-5 Phenanthrene NO mg1L 0.0050 1 1012911515:33 1013111503:49 85-01-8 Phenol NO mg1L 0.0050 1 10/29/15 15:33 10/31/15 03:49 108-95-2 Pyrene ND mg1L 0,0050 1 10/29/15 15:33 10/31/15 03:49 129-00-0 1,2,4-Trichoorobenzene NO mg1L 0.0050 1 1012911515:33 10/31/15 03:49 120-82-1 2,4,6-Trichlorophenol ND mg1L 0.010 1 1012911515:33 10131/1503:49 88-06-2 Surrogates Nitrobenzene-d5(S) 26 % 10-120 1 10129/1515:33 10/31/15 03:49 4165-60-0 2-Fluorobiphenyl (S) 26 % 15-120 1 10/29/15 15:33 10/31/15 03:49 321-60-8 Terphenyl-d14(S) 48 % 11-131 1 1012911515:33 10131/1503:49 1718-51-0 Phenol-d6 (S) 8 % 10-120 1 10/29/15 15:33 10/31/15 03:49 13127-88.3 S0 2-Fluorophenol (S) 13 % 10-120 1 10/29/15 15:33 10/31/15 03:49 367-12-4 2,4,6-Tribromophenol(S) 43 % 10-137 1 1012911515:33 10/31/15 03:49 118-79-6 624 Volatile Organics Analytical Method: EPA 624 Acetone ND mg1L 0.010 1 10/3111512:55 67-64-1 Acrolein NO mglL 0.0050 1 10/3111512:55 107-02-8 Acrylonitrile NO mg1L 0.050 1 10/3111512:55 107-13-1 Benzene ND mg1L 0.0020 1 10/3111512:55 7143-2 Bromobenzene ND mg1L 0.0020 1 10/3111512:55 108-86-1 Bromochloromethane NO mg1L 0.0020 1 10/3111512:55 74-97-5 Bromodichloromethane ND mg1L 0.0020 1 1013111512:55 75-27-4 Bromoform NO mg1L 0.0020 1 10/31/15 12:55 75-25-2 Bromomethane NO mg1L 0.0020 1 10/3111512:55 74-83-9 2-Butanone (MEK) NO mg1L 0.0050 1 10/31/15 12:55 78-93-3 n-Butylbenzene NO mg1L 0.0050 1 10/31/15 12:55 104-51-8 sec-Butylbenzene ND mg/L 0.0050 1 1013111512:55 135-98-8 tert-Butyl benzene NO mglL 0.0050 1 10/31/15 12:55 98-06-6 Carbon disulfide ND mg1L 0.0050 1 10/31/15 12:55 75-15-0 L3 Carbon tetrachloride NO mglL 0.0020 1 10/31/15 12:55 56-23-5 Chlorobenzene NO mg1L 0.0020 1 10131/1512:55 108-90-7 Chloroethane NO mg1L 0.0020 1 10/3111512:55 75-00-3 2-Chloroethylvinyl ether ND mg1L 0.0050 1 10/31/15 12:55 110-75-8 c2 Chloroform NO mglL 0.0020 1 10/31/15 12:55 67-66-3 Chloromethane NO mg1L 0.0020 1 1013111512:55 74-87-3 2-Chlorololuene NO mglL 0.0020 1 1013111512:55 95-49-8 4-Chlorotoluene NO mg1L 0.0020 1 10131/1512:55 1106413A Dibromochloromethane NO mg/L 0.0020 1 10/3111512:55 124-48-1 1,2-Dibromoethane (EDB) NO mg1L 0.0020 1 10/31/15 12:55 106-93A Dibromomethane NO mg1L 0.0020 1 10131/1512:55 74-95-3 1,2-Dichlorobenzene ND mglL 0.0020 1 10/31/15 12:55 95-50-1 1,3-Dichlorobenzene NO mglL 0.0020 1 1013111512:55 541-73-1 1,4-Dichlorobenzene NO mg1L 0.0020 1 1013111512:55 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not tae reproduced, except in full, Date: 11/09/2015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 10 of 50 (�IaneAnalytical" www.pecefebscom ANALYTICAL RESULTS Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: Storm Water Testing Pace Project No.: 92273535 Sample: SDO #7 Lab ID: 92273535002 Collected: 10/27/15 00:00 Received: 10127/15 15:15 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 624 Volatile Organics Analytical Method: EPA624 1,1-Dichloroethane ND mg/L 0.0020 1 10131/1512:55 75-34-3 1,2-Dichloroethane ND mg/L 0.0020 1 10/31/15 12:55 107-06-2 1, 1 -Dichloroethene ND mg1L 0.0020 1 10/3111512:55 75-354 cis- 1,2-Dichloroethene ND mg/L 0.0020 1 1013111512:55 156-59-2 trans-1,2-Dichloroethene ND mg/L 0.0020 1 10/31/15 12:55 156-60-5 1,2-Dichloropropane NO mg1L 0.0020 1 1013111512:55 78-87-5 1,3-Dichloropropane ND mg/L 0.0020 1 10/3111512:55 142-28-9 2,2-Dichloropropane ND mg/L 0.0050 1 10/31/15 12:55 594-20-7 1,1-Dichloropropene ND mg/L 0.0020 1 10/31/15 12:55 563-58-6 cis-1,3-Dichloropropene ND mg1L 0.0020 1 10/31/15 12:55 10061-01-5 trans- l,3-Dichloropropene ND mg/L 0.0020 1 10/31/15 12:55 10061-02-6 Ethylbenzene ND mg/L 0.0020 1 10/31/15 12:55 10041-4 Hexachloro-1,3-butadiene ND mg/L 0.0050 1 10/3111512:55 87-68-3 2-Hexanone ND mg/L 0.010 1 10/3111512:55 591-78-6 lodomethane ND mg/L 0,010 1 1013111512:55 74-88-4 Isopropylbenzene (Cumene) ND mglL 0.0050 1 10/31/15 12:55 98-82-8 p-lsopropyltoluene ND mg/L 0.0050 1 10131/1512:55 99-87-6 Methylene Chloride ND mg/L 0.0020 1 10/31/15 12:55 75-09-2 4-Methyl-2-pentanone (MIBK) ND mglL 0.010 1 10/31/15 12:55 108-10-1 Methyl-tert-butyl ether N❑ mg/L 0.0050 1 10/31/15 12:55 1634-04-4 Naphthalene ND mg1L 0.0050 1 10/31/15 12:55 91-20-3 n-Propylbenzene ND mg/L 0.0050 1 1013111512:55 103-65-1 Styrene ND mg/L 0.0020 1 10/3111512:55 10042-5 1.1,1,2-Tetrachloroethane ND mg/L 0.0020 1 1013111512:55 630-20-6 1,1,2,2-Tetrachloroethane ND mg/L 0.0020 1 10/3111512:55 79-34-5 Tetrachloroethene NO mg/L 0.0020 1 10/31/15 12:55 127-18-4 Toluene ND mg/L 0.0020 1 10/31/15 12:55 108-88-3 1,2,3-Trichlorobenzene NO mg/L 0.0020 1 10/31/15 12:55 87-61-6 1,2,4-Trichlorobenzene ND mg/L 0.0020 1 10/31/15 12:55 120-82-1 1,1.1-Trichloroethane ND mg/L 0.0020 1 1013111512:55 71-55-6 1,1,2-Trichloroethane ND mg/L 0.0020 1 10/31/15 12:55 79-00-5 Trichloroethene NO mg/L 0.0020 1 10/31/15 12:55 79-01-6 Trichlorofluoromethane ND mg/L 0.0020 1 10/31/15 12:55 75-69-4 1,2,3-Thchloropropane NO mg1L 0.0020 1 10/31/15 12:55 96-18-4 1,12-Trichlorotrifluoroethane ND mg/L 0.0020 1 10/3111512:55 76-13-1 1,2,4-Trimethylbenzene ND mg/L 0.0020 1 10/31/15 12:55 95-63-6 1,3,5-Trimethylbenzene ND mg/L 0.0020 1 10/31/15 12:55 108-67-8 Vinyl acetate NO mg/L 0.0050 1 10/31/15 12:55 108-05-4 Vnyl chloride NO mg/L 0.0020 1 10/31/15 12:55 75-01-4 m&p-Xylene NO mg/L 0.0050 1 10131/1512:55 179601-23-1 o-Xylene NO mg/L 0.0050 1 10/31/15 12:55 95-47-6 Surrogates 4-Bromofluorobenzene (S) 96 % 70-130 1 10/31/15 12:55 460-00-4 Toluene-d8 (S) 98 % 70-130 1 10/31/15 12:55 2037-26-5 1,2-Dichloroethane-d4 (S) 85 % 70-130 1 10/31/15 12:55 17060-07-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/09/2015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 11 of 50 aceAnalytical wwwpeosla6xcom ANALYTICAL RESULTS Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: Storm Water Testing Pace Project No.: 92273535 Sample: SDO #8 Lab ID: 92273535003 Collected: 10/27115 00:00 Received: 10/27/15 16:15 Matrix: Water Parameters Results , Units Report Limit DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Total Suspended Solids 4500H+ pH, Electrometric EDN pH at 25 Degrees C 1664 SGT-HEM, TPH Total Petroleum Hydrocarbons 608 GCS Pesticides and PCBs Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC (Lindane) Chlordane (Technical) 4,4'-DDD 4,4'-DDE 4,4'-DDT Dieldrin Endosulfan I Endosulfan It Endosulfan sulfate Endrin Endrin aldehyde Heptachlor Heptachlor epoxide PCB-1016 (Aroclor 1016) PCB-1221 (Aroclor 1221) PCB-1232 (Aroclor 1232) PCB-1242 (Aroclor 1242) PCB-1248 (Aroclor 1248) PCB-1254 (Aroclor 1254) PCB-1260 (Aroclor 1260) Toxaphene Surrogates Tetrachloro-m-xylene (S) Decachlorobiphenyl (S) 200.7 MET ICP Copper Lead Zinc 625 MSSV Acenaphthene Acenaphthylene Date: 11/09/2015 08:46 AM Analytical Method: SM 2540D 6.2 mg1L 2.5 1 10/2811513:07 Analytical Method: SM 4500-H+B 5.5 Std. Units 1.0 1 10/27/15 16:25 H6 Analytical Method: EPA 1664B ND mg1L 5.0 1 11/05/15 08:08 Analytical Method: EPA 608 Preparation Method: EPA 3510 ND mg1L 0.000050 1 10/29/15 11:00 10/31/15 01:10 309.00-2 ND mg1L 0.000050 1 10/29/15 11:00 10/31/15 01:10 319-84-6 ND mg1L 0.000050 1 10/29/15 11:00 10/31/15 01710 319-85-7 ND mg1L 0.000050 1 10/29/15 11:00 10/31/15 01:10 319-86-8 ND mg1L 0.000050 1 10/29/15 11:00 10/31/15 01:10 58-89-9 ND mg1L 0.00050 1 10/29/15 11:00 10/31/15 01:10 57-74-9 ND mg1L 0.000050 1 10/29/15 11:00 10/31/15 01:10 72-54-8 ND mg1L 0.000050 1 10/29/15 11:00 10131/15 01710 72-55-9 ND mg1L 0,000050 1 10/29/15 11:00 10/31/15 01:10 50-29-3 ND mg1L 0.000050 1 10/29/15 11:00 10/31/15 01:10 60-57-1 ND mg1L 0.000050 1 10/29/15 11:00 10/31/15 01:10 959-98-8 ND mg1L 0.000050 1 10/29/15 11:00 10/31/15 01:10 33213.65-9 ND mg1L 0.000050 1 10/2911511:00 10/31115 01:10 1031-07-8 ND mgfL 0,000050 1 10/29/15 11:00 10/31/15 01710 72-20-8 ND mg1L 0.000050 1 10/29/15 11:00 10/31/15 01:10 7421-93-4 ND mg1L 0.000050 1 10/29/15 11:00 10/31115 01:10 76-44-8 ND mg1L 0,000050 1 10/29/15 11:00 10/31115 01 A 0 1024-57-3 ND mg1L 0.00050 1 10/29/15 11:00 10/31/15 01:10 12674-11-2 ND mg1L 0.00050 1 10/29/15 11:00 10/31115 01:10 11104-28-2 ND mg1L 0,00050 1 10/29/15 11:00 10/31115 01710 11.141-16-5 ND mg1L 0.00050 1 10/29/15 11:00 10/31/15 01:10 53469-21-9 ND mg1L 0.00050 1 10/29/15 11;00 10/31/15 01:10 12672-29-6 N❑ mg1L 0.00050 1 10/29/15 11:00 10131/15 01:10 11097-69-1 ND mg1L 0.00050 1 10/29/15 11:00 10/31/15 01:10 11096-82-5 ND mg1L 0,00050 1 10/29/15 11:00 10/31/15 01:10 8001-35-2 102 % 20-110 1 10/29/15 11:00 10/31115 01:10 877-09-8 101 % 20-138 1 10/29/15 11:00 10/31/15 01:10 2051-24-3 Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 0.0067 mg1L 0.0050 1 10/30/15 20730 11/05/15 18:21 7440-50-8 ND mg1L 0.0050 1 10/30/15 20:30 11/05/15 18:21 7439-92-1 0,053 mg1L 0.010 1 10/30/15 20:30 11/06/16 18:21 7440-66-6 Analytical Method: EPA 625 Preparation Method: EPA 625 ND mg1L 0.0050 1 10/29/15 15:33 10131/15 04:19 83-32-9 ND mg1L 0,0050 1 10/29/15 115:33 10/31/15 04:19 208-96-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc., Page 12 of 50 Pace Analytical Services, Inc. 205 East Meadow - Suite A laneAnalyticalo {336}623-8921 ANALYTICAL RESULTS Project: Storm Water Testing Pace Project No.: 92273535 Sample: SDO #8 Lab ID: 92273535003 Collected: 10/27/15 00:00 Received: 10127115 15:15 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 Acetophenone NO mg1L 0.0050 1 10129/15 15:33 10/31/15 04:19 98-86-2 Aniline NO mg1L 0.010 1 10/29/15 15:33 10/31/15 04:19 62-53-3 Anthracene NO mg1L 0.0050 1 10/29/15 15:33 10/31/15 04:19 120-12-7 Benzidine NO mg1L 0,050 1 1012911515733 10131/15 04:19 92-87-5 L2 Benzo(a)anthracene NO mg1L 0.0050 1 1012911515:33 10/31/15 04:19 56-55-3 Benzo(a)pyrene NO mg1L 0.0050 1 10/29/15 15:33 10131/15 04:19 50-32-8 Benzo(b)fluoranthene NO mg/L 0.0050 1 10/29/15 15:33 10131/15 04:19 205-99-2 Benzo(g,h,i)perylene NO mg1L 0.0050 1 10/29/15 15:33 10/31/15 04:19 191-24-2 Benzo(k)fluoranthene NO mg1L 0.0050 1 10/29/15 15733 10/31/15 04719 207-08-9 4-Bromophenylphenyl ether NO mg1L 0.0050 1 10/29/15 15:33 10131/15 04:19 101-55-3 Butylbenzylphihalate NO mg1L 0.0050 1 10/29/15 15:33 10/31/15 04:19 85-68-7 4-Chloro-3-methylphenol NO mg1L 0.0050 1 10/29/15 15:33 10/31/15 04:19 59-50-7 bis(2-Chloroethoxy)methane NO mg1L 0.010 1 10/29/15 15:33 10/31/15 04:19 111-91-1 bis(2-Chloroethyl) ether NO mg1L 0.0050 1 10/29/15 15:33 10131/15 04A 9 111-44-4 his(2-Chloroisopropyl) ether NO mg1L 0.0050 1 10/29/15 15:33 10/31/15 04:19 108-60-1 2-Chloronaphthalene NO mg/L 0.0050 1 10129/1515:33 1013111504:19 91-58-7 2-Chlorophenot ND mg1L 0.0050 1 10/29115 15:33 10/31/15 04:19 95-57-8 4-Chlorophenylphenyl ether NO mg1L 0.0050 1 10/29/15 15:33 10/31/15 04:19 7005-72-3 Chrysene NO mg1L 0.0050 1 10/29/15 15:33 10/31115 04:19 218-01-9 Dibenz(a,h)anthracene ND mg1L 0.0050 1 10/29/15 15:33 10/31/15 04:19 53-70-3 1,2-Dichlorobenzene ND mg1L 0.0050 1 10/29/15 15:33 10/31/15 04:19 95-50-1 1,3-Dichlorobenzene ND mg1L 0.0050 1 10129/1515:33 10131/1504:19 541-73-1 1,4-Dichlorobenzene NO mg1L 0.0050 1 10/29/15 15:33 1013111504:19 106A6-7 3,3'-Dichlo robenzid ine NO mg1L 0.025 1 10/29/15 15:33 10/31/15 04:19 91-94-1 2,4-Dichlorophenol NO mg1L 0.0050 1 10/29/15 15:33 10/31/15 04:19 120-83-2 Diethylphthalate ND mg1L 0.0050 1 10/29/15 15:33 10/31/15 04:19 84-66-2 2,4-Dimethylphenol ND mg1L 0.010 1 10/29/15 15:33 10/31/15 04:19 105-67-9 Dimethylphthalate ND mg1L 0.0050 1 10/29/15 15:33 10/31/15 04:19 131-11-3 Di-n-butylphthalate ND mg/L 0.0050 1 10/29/15 15:33 10/31/15 04:19 84-74-2 4,6- Din itro-2-methylphenol ND mg/L 0.020 1 10/29/15 15:33 10/31/15 04:19 534-52-1 2,4-Dinitrophenol ND mg1L 0.050 1 10/29/1515:33 1013111504719 51-28-5 2,4-Dinitrotoluene NO mg1L 0.0050 1 10/29/15 15:33 1013111504:19 121-14-2 2,6-Dinitrotoluene NO mg1L 0.0050 1 10/29/15 15:33 10/31/15 04:19 605-20-2 Di-n-octylphthalate NO mg/L 0.0050 1 10/29/15 15:33 10/31/15 04:19 117-84-0 1,2-Diphenylhydrazine NO mg1L 0.0050 1 10/29/15 15:33 1013111504:49 122-66-7 bis(2-Ethylhexyl)phthalate ND mg1L 0.0050 1 10/29/15 15:33 10/31/15 04719 117-81-7 Fluoranthene NO mg1L 0.0050 1 10/29/15 15:33 10/31/15 04:19 206-44-0 Fluorene NO mg1L 0.0050 1 10/29/15 15:33 10/31/15 04:19 86-73-7 Hexachloro-1,3-butadiene NO mg1L 0.0050 1 10/29/15 15:33 10/31/15 04:19 87-68-3 Hexachiorobenzene NO mg1L 0.0050 1 10/29/15 15:33 10/31/15 04:19 118-74-1 Hexachlorocyclopentadiene NO mg1L 0.010 1 10/29/15 15:33 10/31/15 04:19 77-47-4 Hexachloroethene NO mg1L 0.0050 1 10/29/15 15:33 10/31/15 04:19 67-72-1 Indeno(1,2,3-cd)pyrene ND mg1L 0.0050 1 10/29/15 15:33 10/31/15 04:19 193-39-5 Isophorone ND mg1L 0.010 1 10/29/15 15:33 10/31/15 04719 78-59-1 Naphthalene NO mg/L 0.0050 1 1012911515:33 1013111504:19 91-20-3 Nitrobenzene NO mg/L 0.0050 1 10/29/15 15:33 10/31/15 04:19 98-95-3 2-Nitrophenol NO mg/L 0.0050 1 10/29/15 15:33 10/31/15 04:19 88.75-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 1110912015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 13 of 50 16 aceAnalytical www.patelabamro ANALYTICAL RESULTS Project: Storm Water Testing Pace Project No.: 92273535 Pace Analytical Services, InC. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Sample: SDO #8 Lab ID: 92273535003 Collected: 10/27/15 00:00 Received: 10/27/15 15:15 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 625 MSSV Analytical Method: EPA625 Preparation Method: EPA625 4-Nitrophenol NO mg1L 0.050 1 10/29/15 15:33 10/31/15 04:19 100-02-7 N-Nitrosodimethylamine ND mg/L 0.0050 1 10/29/15 15:33 10/31/15 04:19 62-75-9 N-Nitroso-di-n-propylamine NO mg/L 0.0050 1 10/29/16 15:33 10131/15 04:19 621-64-7 N-Nitrosodiphenylamine ND mg1L 0.010 1 10/29/15 15:33 10/31/15 04:19 86-30-6 Pentachlorophenol ND mglL 0.010 1 10/29/15 15:33 10/31/15 04:19 87-86-5 Phenanthrene ND mglL 0.0050 1 10/29/15 15:33 10/31/15 04:19 85-01-8 Phenol ND mg/L 0.0050 1 10/29/15 15:33 10/31/15 04:19 108-95-2 Pyrene ND mg/L 0.0050 1 10/29/15 15:33 10131/15 04:19 129-00-0 1,2,4-Trichlorobenzene ND mg/L 0.0050 1 10/29/15 15:33 10/31/15 04:19 120-82-1 2,4,6-Trichlorophenol NO mg/L 0.010 1 10/29/15 15:33 10/31/15 04:19 88-06-2 Surrogates Nitrobenzene-d5 (S) 62 % 10-120 1 10/29/15 15:33 10/31/15 04:19 4165-60-0 2-Fluorobiphenyl(S) 68 % 15-120 1 10/2911515:33 1013111504:19 321-60-8 Terphenyl-d14 (S) 70 % 11-131 1 10/29/15 15:33 10/31/15 04:19 1718-51-0 Phenol-d6 (S) 24 % 10-120 1 10/29/15 15:33 10/31/15 04:19 13127-88-3 2-Fluorophenol (S) 36 % 10-120 1 10/29/15 15:33 10/31/15 04:19 367-12-4 2,4,6-Tribromophenol (S) 80 % 10-137 1 10/29/15 15:33 10/31/15 04:19 118-79-6 624 Volatile Organics Analytical Method: EPA624 Acetone NO mg/L 0.010 1 10/31115 13: 10 67-64-1 Acrolein ND mg/L 0.0050 1 10/3111513:10 107-02-8 Acrylonitrile ND mg/L 0.050 1 10/3111513:10 107-13-1 Benzene ND mglL 0.0020 1 1013111513:10 71-43-2 Bromobenzene ND mglL 0.0020 1 1013111513:10 108-86-1 Bromochloromethane ND mg/L 0.0020 1 1013111513:10 74-97-5 Bromodichloromethane NO mg/L 0.0020 1 1013111513:10 75-27-4 Bromoform ND mg/L 0.0020 1 1013111513:10 75-25-2 Bromomethane ND mg/L 0.0020 1 101311151110 74-83-9 2-Butanone (MEK) ND mg/L 0,0050 1 10/31/15 13:10 78-93-3 n-Butylbenzene ND mg/L 0.0050 1 10131/1513:10 104-51-8 sec-Butylbenzene NO mg/L 0.0050 1 10/3111513:10 135-98-8 tert-Butyl benzene NO mg/L 0.0050 1 10/3111513:10 98-06-6 Carbon disulfide NO mg/L 0.0050 1 10/31/15 13:10 75-15-0 Carbon tetrachloride NO mg/L 0.0020 1 10/31/15 13:10 56-23-5 Chlorobenzene NO mg/L 0.0020 1 10/31/15 13:10 108-90-7 Chloroethane NO mg/L 0.0020 1 1013111513:10 75-00-3 2-Chloroethylvinyl ether NO mg/L 0.0050 1 10/31/15 13:10 110-75-8 Chloroform NO mg/L 0.0020 1 10/3111513:10 67-66-3 Chloromethane NO mg/L 0.0020 1 1013111513:10 74-87-3 2-Chlorotoluene NO mg/L 0.0020 1 10/3111513:10 9549-8 4-Chlorotoluene NO mg/L 0.0020 1 10/3111513:10 106-43-4 Dibromochloromethane NO mglL 0.0020 1 10/3111513:10 12448-1 1,2-Dibromoethane (EDB) ND mg1L 0.0020 1 10/31/15 13:10 106-93-4 Dibromomethane NO mg/L 0.0020 1 1013111513:10 74-95-3 1,2-Dichlorobenzene ND mg/L 0.0020 1 1013111513:10 95-50-1 1,3-Dichlorobenzene NO mg/L 0.0020 1 1013111513:10 541-73-1 1,4-Dichlorobenzene ND mg/L 0.0020 1 1013111513:10 106-46-7 REPORT OF LABORATORY ANALYSIS ;his report shall not be reproduced, except in full, Date: 11/09/2015 08:46 AM without the written consent of Pace Analytical Services, Inc„ L3 c2 Page 14 of 50 lacieAnalyticalo www.pscerabs+nm ANALYTICAL RESULTS Project: Storm Water Testing Pace Project No.: 92273535 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Sample: SDO #8 Lab ID: 92273535003 Collected: 10127115 00:00 Received: 10127/15 15:15 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 624 Volatile Organics 1,1-Dichloroethane 1,2-Dichtoroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dich loroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Diehl oropropene cis-1,3-Dichloropropene trans- 1,3-Dich loropropene Ethylbenzene Hexachloro-1,3-butadiene 2-Hexanone lodomethane Isopropylbenzene (Cumene) p-Isopropyltoluene Methylene Chloride 4-Methyl-2-pentanone (MIRK) Methyl-tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Tri chlorobenzene 1,1,1-Trichloroethane 1, 1,2-Trichlo roetha ne Trichloroethene Trichlorofluoromethane 1,2,3-Trichlaropropane 1,1,2-Tdchlorotrifluoroethane 1,2,4-Trimethylbenzene 1,35-Trimethylbenzene Vinyl acetate Vinyl chloride m&p-Xylene o-Xylene Surrogates 4-BromoflUOrobenzene (S) Toluene-d8 (S) 1,2-Dichloroethane-d4 (S) Date: 11 /09/2015 08:46 AM Analytical Method: EPA 624 ND mg1L 0.0020 1 10/3111513:10 75-34-3 NO mg1L 0.0020 1 1013111513:10 107-06-2 ND mg1L 0.0020 1 10/31/1513:10 75-35-4 ND mg1L 0.0020 1 10/31/1513:10 156-59-2 ND mg1L 0.0020 1 10/31/1513:10 156-60-5 ND mg/L 0.0020 1 10/3111513:10 78-87-5 NO mg1L 0.0020 1 10131/1513:10 142-28-9 NO mg1L 0.0050 1 10131/1513:10 594-20-7 ND mg/L 0.0020 1 1013111513:10 563-58-6 NO mg1L 0.0020 1 10131/1513:10 10061-01-5 ND mg1L 0.0020 1 10131/1513:10 10061-02-6 ND mg1L 0.0020 1 10/31/15 13:10 100-41-4 NO mg1L 0.0050 1 10/3111513:10 87-68-3 NO mg1L 0.010 1 10/31/1513:10 591-78-6 ND mg1L 0.010 1 10131/1513:10 74-88-4 ND mg1L 0.0050 1 10/3111513:10 98-82-8 NO mg1L 0.0050 1 10/3111513:10 99-87-6 ND mg1L 0.0020 1 10/3111513:10 75-09-2 ND mg/L 0.010 1 10/31/1513:10 108-10-1 NO mg1L 0.0050 1 10/31/1513:10 1634-04-4 NO mg1L 0.0050 1 10/31/1513:10 91-20-3 N❑ mg[L 0.0050 1 10/31/1513:10 103-65-1 ND mg1L 0.0020 1 10/3111513:10 100-42-5 NO mg1L 0.0020 1 10/3111513:10 630-20-6 ND mg1L 0.0020 1 10/31/1513:10 79-34-5 ND mg/L 0.0020 1 10/3111513:10 127-18-4 ND mg1L 0.0020 1 1013111513:10 108-88-3 ND mg1L 0.0020 1 10/3111513:10 87-61-6 NO mg/L 0.0020 1 1013111513:10 120-82-1 ND mgfL 0.0020 1 1013111513:10 71-55-6 ND mg1L 0.0020 1 10/31/1513:10 79-00-5 ND mg1L 0.0020 1 10/31115 13: 10 79-01-6 ND mglL 0,0020 1 10131/1513:10 75-69-4 ND mg1L 0.0020 1 10/3111513:10 96-18-4 ND mg(L 0.0020 1 10131/1513:10 76-13-1 NO mg/L 0.0020 1 10/3111513:10 95-63-6 ND mg1L 0.0020 1 1013111513:10 108-67-8 ND mg1L 0.0050 1 10131/1513:10 108-05-4 ND mg/L 0.0020 1 10/31/1513:10 75-01-4 ND mg1L 0.0050 1 10/31/1513:10 179601-23-1 ND mg1L 0,0050 1 10/31/1513:10 95-47-6 99 % 70-130 1 10/31/1513:10 460-00-4 100 % 70-130 1 10/31/1513:10 2037-26-5 89 % 70-130 1 10/31/1513:10 17050-07-0 REPORT OF LABORATORY ANALYSIS This report shall not 5e reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 50 laneAnalytical" * w.peodab&mn ANALYTICAL RESULTS Pace Analytical Services, Inc. 205 East Meadow Road - Suite Eden. NC 27288 (336)623-8921 Project: Storm Water Testing Pace Project No.: 92273535 Sample: SDO #11 Lab ID: 92273535004 Collected: 10/27/15 00:00 Received: 10/27/15 15:15 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No, Qual 2640D Total Suspended Solids Analytical Method: SM 25400 Total Suspended Solids 21.6 mg/L 5.0 1 10/28/15 13:08 4500H+ pH, Electrometric EDN Analytical Method: SM 4500-H+B pH at 25 Degrees C 7.9 Std. Units 1.0 1 10/27/15 16:25 H6 1664 SGT-HEM, TPH Analytical Method: EPA 16648 Total Petroleum Hydrocarbons ND mg1L 5.0 1 11/05/15 08:08 608 GCS Pesticides and PCEIs Analytical Method: EPA 608 Preparation Method: EPA 3510 Aldrin ND mg1L 0,000050 1 10/29/15 11:00 10/31/15 01:27 309-00-2 alpha-BHC ND mg1L 0.000050 1 10/29/15 11:00 10/31/15 01:27 319-84-6 beta-BHC 0.000080 mg1L 0.000050 1 10/29/151i:00 10/31/15 01:27 319-85-7 delta-BHC ND mg1L 0.000050 1 10/29/15 11:00 10/31/15 01:27 319-86-8 gamma-BHC (Lindane) ND mg/L 0.000050 1 10/29/15 11:00 10/31/15 01:27 58-89-9 Chlordane (Technical) ND mg1L 0.00050 1 10/29/15 11:00 10/31/15 01:27 57-74-9 4,4'-DDD ND mg1L 0.000050 1 10/29/15 11:00 10/31/15 01:27 72-54-8 4,4'-DDE ND mg/L 0.000050 1 10/29/15 11:00 10/31/15 01:27 72-55-9 4,4'-DDT ND mg1L 0.000050 1 10/29/15 11:00 10/31/15 01:27 50-29-3 Dieldrin ND mg1L 0.000050 1 10/29/15 11:00 10/31/15 01:27 60-57-1 Endosulfan I ND mg1L 0.000050 1 10/29/15 11:00 10/31/15 01:27 959-98-8 Endosulfan II ND mg1L 0.000050 1 10/29/15 11:00 10/31/15 01:27 33213-65-9 Endosulfan sulfate ND mg1L 0.000050 1 10/29/15 11:00 10/31/15 01:27 1031-07-8 Endrin ND mg1L 0.000050 1 10/29/15 11:00 10/31/15 01:27 72-20-8 Endrin aldehyde ND mg1L 0.000050 1 10/29/15 11:00 10/31/15 01:27 7421-93-4 Heptachlor ND mg1L 0.000050 1 10/29/15 11:00 10/31/15 01:27 76-44-8 Heptachlor epoxide ND mg1L 0.000050 1 10/29/15 11:00 10/31/15 01:27 1024-57-3 PCB-1016 (Aroclor 1016) ND mg1L 0.00050 1 10/29/15 11:00 10/31/15 01:27 12674-11-2 PCB-1221 (Aroclor1221) ND mg/L 0.00050 1 10/29/15 11:00 10/31/15 01:27 11104-28-2 PCB-1232 (Aroclor 1232) ND mg1L 0.00050 1 10/29/15 11:00 10/31/15 01:27 11141-16-5 PCB-1242 (Aroclor 1242) ND mg1L 0.00050 1 10/29/15 11:00 10/31/15 01:27 53469-21-9 PCB-1248 (Aroclor 1248) ND mg1L 0.00050 1 10/29/15 11:00 10/31/16 01:27 12672-29-6 PCB-1254 (Aroclor 1254) ND mg1L 0.00050 1 10/29/15 11:00 10/31/15 01:27 11097-69-1 PCB-1260 (Aroclor 1260) ND mg1L 0.00050 1 10/29/15 11:00 10/31/15 01:27 11096-82-5 Toxaphene ND mg1L 0.00050 1 10/29/15 11:00 10/31/15 01:27 8001-35-2 Surrogates Tetrachloro-m-xylene(S) 42 % 20-110 1 10/29/15 11:00 10/31/15 01:27 877-09-8 Decachlorobiphenyl (S) 60 % 20-138 1 10/29/15 11:00 10/31/15 01:27 2051-24-3 200.7 MET ICP Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 Copper 0.0095 mg/L 0.0050 1 10/30/15 20:30 11/05/15 18:24 7440-50-8 Lead NO mg1L 0.0050 1 10/30/15 20:30 11/05/15 118:24 7439-92-1 Zinc D.D72 mg/L 0,010 1 10/30/15 20:30 11/05/15 18:24 7440-66-6 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 Acenaphthene ND mg1L 0.0050 1 10/2911515:33 11/0311519:04 83-32-9 Acenaphthylene ND mg/L 0.0050 1 10/2911515:33 11/0311519:04 208-96-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/09/2015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 16 of 50 0 acmnalytrcal www.paoelabs.00m ANALYTICAL RESULTS Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: Storm Water Testing Pace Project No.: 92273535 Sample: SDO #11 Lab ID: 92273535004 Collected: 10/27/15 00:00 Received: 10/27/15 15:15 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Cual 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 Acetophenone NO mg1L 0.0050 1 10/2911515:33 11103/1519:04 98-86-2 Aniline NO mg1L 0.010 1 1012911515:33 11/03/1519704 62-53-3 Anthracene NO mg1L 0.0050 1 10129/1515:33 11/0311519:04 120-12-7 Benzidine NO mg1L 0.050 1 1012911515:33 11/0311519:04 92-87-5 L2 Benzo(a)anthracene NO mg1L 0.0050 1 1012911515:33 11/0311519:04 56-55-3 Benzo(a)pyrene NO mg1L 0.0050 1 1012911515:33 11/0311519:04 50.32-8 Benzo(b)ftuoranthene NO mg1L 0.0050 1 1012911515:33 1110311519:04 205-99-2 Benzo(g,h,i)perylene NO mg/L 0.0050 1 1012911515:33 11/0311519:04 191-24-2 Benzo(k)fluoranthene ND mg/L 0.0050 1 10/2911515:33 11/0311519:04 207-08-9 4-Bromophenylphenyl ether NO mg1L 0.0050 1 10/29/15 15;33 11/03/15 19:04 101-55-3 Butylbenzylphthalate NO mg1L 0.0050 1 10129/1515:33 1110311519:04 85-68-7 4-Chloro-3-methylphenol NO mg/L 0.0050 1 10129/1515:33 1110311519:04 59-50-7 bis(2-Chloroethoxy)methane NO mg/L 0.010 1 10/29/1515:33 11/03/1519:04 111-91-1 bis(2-Chloroethyl) ether NO mg/L 0.0050 1 10/29/15 15:33 11/03/15 19:04 111-44A bis(2-Chloroisopropyl) ether NO, mg/L 0.0050 1 10/29/15 15:33 11/03/15 19:04 108-60-1 2-Chloronaphthalene NO mg/L 0.0050 1 10129/1515:33 11/03/1519:04 91-58-7 2-Chlorophenol ND mg/L 0.0050 1 10/29/1515:33 1110311519:04 95-57-8 4-Chlorophenylphenyl ether NO mglL 0.0050 1 10/29/15 15:33 11/03/15 19:04 7005-72-3 Chrysene NO mg/L 0.0050 1 10/29/1515:33 11/03/1519:04 218-01-9 Dibenz(a,h)anthraoene NO mg/L 0.0050 1 10/29/1515:33 11/03/1519:04 53-70-3 1,2-Dichlorobenzene NO mg/L 0.0050 1 10/2911515:33 11/03/1519:04 95-50-1 1,3-Dichlorobenzene NO mg/L 0.0050 1 10129/1515:33 11/03/1519:04 541-73-1 1,4-Dichlorobenzene NO mg/L 0.0050 1 10/2911515:33 11/03/1519:04 106-46-7 3,3'-Dichlorobenzidine NO mg/L 0.025 1 10129/1515:33 11/03/1519:04 91-94-1 2,4-Dichlorophenol NO mg1L 0.0050 1 10/2911515:33 11/03/1519:04 120-83.2 Diethylphthalate NO mg1L 0.0050 1 10/29/1515:33 1110311519:04 84-66-2 2,4-Dimethylphenol NO mg/L 0.010 1 10/29/1515:33 1110311519:04 105-67-9 Dimethylphtha late NO mg/L 0.0050 1 10/29/1515:33 1110311519:04 131-11-3 Di-n-butylphthalate NO mg/L 0.0050 1 10129/1515:33 1110311519:04 84-74-2 4,6-Dinitro-2-methylphenol NO mg/L 0.020 1 10/2911515:33 1110311519:04 534-52.1 2,4-Dinitrophenol NO mglL 0.050 1 10129/1515:33 1110311519:04 51-28-5 2,4-Dinitrotoluene NO mg/L 0.0050 1 10/29/1515:33 1110311519:04 121-14-2 2,6-Dinitrotoluene NO mg/L 0.0050 1 10/29/1515:33 1110311519:04 606-20-2 Di-n-octylphthalate NO mg/L 0.0050 1 10129/1515:33 1110311519:04 117-84-0 1,2-Diphenylhydrazine NO mg/L 0.0050 1 10/29/1515:33 1110311519:04 122-66-7 bis(2-Ethylhexyl)phthalate NO mg/L 0.0050 1 10/29/1515:33 11/03/1519:04 117-81-7 Fluoranthene NO mg/L 0.0050 1 10/29/1515:33 1110311519:04 206-44-0 Fluorene NO mg/L 0.0050 1 10129/1515:33 1110311519:04 86-73-7 Hexachloro-1,3-butadiene NO mg/L 0.0050 1 10129/1515:33 1110311519:04 87-68-3 Hexachlorobenzene NO mg1L 0.0050 1 10/29/1515:33 1110311519:04 118-74-1 Hexachlorocyclopentadiene NO mg/L 0.010 1 10129/1515:33 1110311519:04 77-47-4 Hexachloroethane NO mg/L 0.0050 1 10/2911515:33 11/03/1519:04 67-72-1 Indeno(1,2,3-od)pyrene NO mg/L 0.0050 1 10/29/1515:33 11103/1519:04 193-39-5 Isophorone NO mg/L 0.010 1 10/29/1515:33 11/03/1519:04 78-59-1 Naphthalene NO mg/L 0.0050 1 10/29/1515:33 1110311519:04 91-20-3 Nitrobenzene NO mg1L 0.0050 1 10129/1515:33 1110311519:04 98-95-3 2-Nitrophenal NO mg/L 0.0050 1 10/29/1515:33 1110311519:04 88-75-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/09/2015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 17 of 50 Pace Analytical Services, Inc. 205 East Meadow Road - Suite lacmnalyficalo Eden, NC 27288 WWW.p°Wabacom (336)623-8921 ANALYTICAL RESULTS Project: Storm Water Testing Pace Project No.: 92273535 Sample: SDO #11 Lab ID: 92273535004 Collected: 10/27/15 00:00 Received: 10/27115 15:15 Matrix: Water Parameters Results units Report Limit DF Prepared Analyzed CAS No. Qual 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 4-Nitrophenol ND mg/L 0.050 1 10129/1515:33 11/0311519:04 100-02-7 N-Nitrosodimethylamine ND mg/L 0.0050 1 10/2911515:33 11/0311519:04 62-75-9 N-Nitroso-di-n-propylamine ND mg1L 0.0050 1 10/29/15 15:33 11103/1519:04 621-64-7 N-Nitrosodiphenylamine ND mg/L 0.010 1 1012911515:33 11103/1519:04 86-30-6 Pentachlorophenol ND mg/L 0.010 1 1012911515:33 1110311519:04 87-86-5 Phenanthrene ND mg/L 0.0050 1 10129/1515:33 11103/1519:04 85-01-8 Phenol ND mg/L 0.0050 1 10/29/15 15:33 11/03/1519:04 108-95-2 Pyrene ND mg/L 0.0050 1 10/2911515:33 11/03/15 19:04 129-00-0 1,2,4-Trichlorobenzene ND mg/L 0.0050 1 10/29/15 15:33 11103/1519:04 120-82-1 2,4,6-Trichlorophenol ND mg/L 0.010 1 10/2911515:33 11/03/15 19:04 88-06-2 Surrogates Nitrobenzene-d5 (S) 36 % 10-120 1 10/29/16 15:33 11/03/15 19:04 4165-60-0 2-Fluorobiphenyl (S) 39 % 15-120 1 10/29/15 15:33 11/03/15 19:04 321-60-8 Te rphenyl-d 14 (S) 40 % 11-131 1 10/29/15 15:33 11/03/15 19:04 1718-51-0 Phenol-d6 (S) 13 % 10-120 1 10/29/15 15:33 11/03/15 19:04 13127-88-3 2-Fluorophenol (S) 20 % 10-120 1 10/29/15 15:33 11/03/15 19:04 367-12-4 2,4,6-Thbromophenol (S) 39 % 10-137 1 10/29/15 15:33 11/03/15 19:04 118-79-6 624 Volatile Organics Analytical Method: EPA 624 N Acetone ND mg/L 0.010 1 10131/1513:26 67-64-1 Acrolein ND mg/L 0.0050 1 10/3111513:26 107-02-8 Acrylonitrile NO mg/L 0,050 1 10/3111513:26 107-13-1 Benzene ND mg/L 0.0020 1 10/31/15 13:26 71-43-2 Bromobenzene ND mg/L 0.0020 1 10/31/15 13:26 108-86-1 Bromochloromethane ND mg/L 0,0020 1 10/3111513:26 74-97-5 Bromodichloromethane ND mg/L 0.0020 1 10/31/15 13:26 75-27-4 Bromoform ND mg/L 0.0020 1 1013111513:26 75-25-2 Bfomomelhane ND mg/L 0.0020 1 10/3111513:26 74-83-9 2-Butanone (MEK) ND mg/L 0.0050 1 10/31/15 13:26 78-93-3 n-Butylbenzene ND mg/L 0.0050 1 10/3111513:26 104-51-8 sec-Butylbenzene ND mg/L 0.0050 1 10/31/15 13:26 135-98-8 tert-Butyl benzene ND mg/L 0.0050 1 10/31/15 13:26 98-06-6 Carbon disulfide ND mg/L 0,0050 1 10/31/15 13:26 75-15-0 L3 Carbon tetrachloride ND mg/L 0.0020 1 10/31/15 13:26 56-23-5 Chlorobenzene ND mg/L 0,0020 1 10131/1513:26 108-90-7 Chloroethane ND mg/L 0.0020 1 10/3111513:26 75-00-3 2-Chloroethylvinyl ether ND mg/L 0.0050 1 10/31/15 13:26 110-75-8 c2 Chloroform NO mg/L 0,0020 1 10/31/15 13:26 67-66-3 Chloromethane ND mg/L 0.0020 1 10/31/15 13:26 74-87-3 2-Chlorotoluene ND mg/L, 0.0020 1 10/31/1513:26 95-49-8 4-Chlorotoluene ND mg/L 0.0020 1 10/3111513:26 106-43-4 Dibromochloromethane ND mg/L 0.0020 1 10/31/15 13:26 124-48-1 1,2-Dibromoethane (EDB) ND mg/L 0.0020 1 10/31/15 13:26 106-93-4 Dibromomethane ND mg/L 0.0020 1 1013111513:26 74-95-3 1,2-Dichlorobenzene ND mg/L 0.0020 1 10/31/15 13:26 95-50-1 1,3-Dichlorobenzene ND mg/L 0,0020 1 10/3111513:26 541-73-1 1,4-Dichlorobenzene ND mg/L 0.0020 1 10131/1513:26 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/0912015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 18 of 50 acmnalytrcal o wxwpace+eds.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: Storm Water Testing Pace Project No.: 92273535 Sample: SDO #11 Lab ID: 92273535004 Collected: 10/27/15 00:00 Received: 10127115 15:15 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 624 Volatile Organics Analytical Method: EPA 624 1,1-Dichloroethane ND mg/L 0.0020 1 10/3111513:26 75-34-3 1,2-Dichloroethane ND mg/L 0.0020 1 10/31/15 13:26 107-06-2 1,1-Dichloroethene ND mg/L 0,0020 1 10/3111513:26 75-35-4 cis-1,2-Dichloroethene ND mg/L 0.0020 1 10131/1513:26 156-59-2 trans- l,2-Dichloroethene ND mg/L 0.0020 1 10131/1513:26 156-60-5 1,2-Dichloropropane ND mg/L 0,0020 1 10/31/15 13:26 78-87-5 1,3-Dichloropropane ND mg/L 0.0020 1 10131/1513:26 142-28-9 2,2-Dichloropropane ND mg/L 0.0050 1 10131/1513:26 594-20-7 1,1-Dichloropropene ND mg/L 0,0020 1 10/31/15 13:26 563-58-6 cis- 1,3-Dichloropropene ND mg/L 0.0020 1 10131/1513:26 10061-01-5 trans- 1.3-Dichloropropene ND mg/L 0.0020 1 10/31/15 13:26 10061-02-6 Ethyibenzene ND mg/L 0.0020 1 10/3111513:26 100-41-4 Hexachloro-1,3-butadiene ND mg/L 0.0050 1 10/3111513:26 87-68-3 2-Hexanone ND mg/L 0,010 1 10131/1513:26 591-78-6 lodomethane ND mg/L 0.010 1 10/31/15 13:26 74-88-4 Isopropylbenzene (Cumene) ND mg/L 0.0050 1 10/31/15 13:26 98-82-8 p-Isopropyltoluene ND mg/L 0.0050 1 10/31/15 13:26 99-87-6 Methylene Chloride ND mg/L 0.0020 1 10/31/15 13:26 75-09-2 4-Methyl-2-pentanone (MIBK) ND mg/L 0.010 1 10/31/16 13:26 108-10-1 Methyl-tert-butyl ether ND mg1L 0.0050 1 10/31/15 13:26 1634-04-4 Naphthalene ND mg/L 0.0050 1 10/31/15 13:26 91-20-3 n-Propylbenzene ND mg/L 0.0050 1 10/3111513:26 103-65-1 Styrene ND mg/L 0.0020 1 10/31/15 13:26 100-42-5 1,1,1,2-Tetrachloroethane ND mglL 0.0020 1 10/31/1513:26 630-20-6 1,1,2,2-Tetrachloroethane ND mg/L 0.0020 1 1013111513726 79-34-5 Tetrachloroethene ND mg1L 0.0020 1 1013111513:26 127-18-4 Toluene ND mglL 0.0020 1 1013111513:26 108-88-3 1,2,3-Trichlorobenzene ND mg1L 0.0020 1 10131/1513:26 87-61-6 1,44-Trichlorobenzene ND mg/L 0.0020 1 10/311i5 43:26 120-82-1 1,1,1-Trichloroethane ND mglL 0.0020 1 101311151326 71-55-6 1,1,2-Trichloroethane ND mg/L 0.0020 1 1013111513:26 79-00-5 Trchloroethene ND mg/L 0.0020 1 1013111513:26 79-01-6 Trichlorofluoromethane ND mg1L 0.0020 1 10/3111513726 75-69-4 1,2,3-Trichloropropane ND mglL 0.0020 1 10131/1513:26 96-18A 1,1,2-Trichlorotrifluoroethane ND mg1L 0.0020 1 1013111513:26 76-13-1 1,2,4-Trimethylbenzene ND mglL 0.0020 1 1013111513:26 95-63-6 1,3,5-Trimethyibenzene ND mg1L 0.0020 1 10/3111513:26 108-67-8 Vinyl acetate ND mglL 0.0050 1 10/31/15 13:26 108-05-4 Vinyl chloride ND mg/L 0.0020 1 10/31/15 13:26 75-01-4 m&p-Xylene ND mg1L 0.0050 1 10131/151126 179601-23-1 o-Xylene ND mg1L 0.0050 1 101311151126 95-47-6 Surrogates 4-Bromofluorobenzene (S) 101 % 70-130 1 10/31/15 13:26 460-00-4 Toluene -dB (S) 100 % 70-130 1 10131115 13:26 2037-26-5 1,2-Dichloroethane-d4 (S) 90 % 70-130 1 10/31/15 13:26 17060-07-0 REPORT OF LABORATORY ANALYSIS This report shaft not be reproduced, except in full, Date: 11/09/2015 08:46 AM without the written consent of Pace Analytical, Services, Inc.. Page 19 of 50 (�IacieAnalytical" wwwpacele6smm ANALYTICAL RESULTS Project: Storm Water Testing Pace Project No.: 92273635 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27268 (336)623-8921 Sample: SDO #12 Parameters Lab ID: 92273535005 Collected: 10/27/15 00:00 Results Units Report Limit OF Received: 10/27115 15:15 Matrix: Water Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids ND mg1L 2.5 1 10/28/15 13:09 4500H+ pH, Electrometric EDN Analytical Method: SM 4500-H+B pH at 25 Degrees C 6.0 Std. Units 1.0 1 10/27/15 16:25 H6 1664 SGT-HEM, TPH Analytical Method: EPA 1664B Total Petroleum Hydrocarbons NO mg1L 5.0 1 11105/15 08:09 608 GCS Pesticides and PCBs Analytical Method: EPA 608 Preparation Method: EPA 3510 Aldrin NO mg1L 0.000050 1 10/2911511:00 10/31/15 01:45 309-00-2 alpha-BHC NO mg1L 0.000050 1 10/29/15 11:00 10/31/15 01:45 319-84-5 beta-BHC NO mg1L 0.00D050 1 10/29/15 11:00 10131/15 01:45 319-85-7 delta-BHC NO mg1L 0.000050 1 10/29/15 11:00 10/31/15 01:45 319-86-8 gamma-BHC(Lindane) NO mg1L 0.000050 1 10129/1511:00 10131/1501:45 58-89-9 Chlordane(Technical) NO mg1L 0.00050 1 1012911511:00 10/31/15 01:45 57-74-9 4,4'-DDD NO mg1L 0.000050 1 10/2911511:00 10131/1501:45 72-54-8 4,4'-DDE ND mgfL 0.000050 1 1012911511:00 10131/1501:45 72-55-9 4,4'-DDT NO mg1L 0.000050 1 10/29/15 11:00 10/31/15 01:45 50-29-3 Dieldrin ND mg1L 0.000050 1 10/29/15 11:00 10/31/15 01:45 60-57-1 Endosulfan I NO mg1L 0.000050 1 10/29/15 11:00 10/31/15 01:45 959-98-8 Endosulfan 11 NO mg1L 0.000050 1 10/29/15 11:00 10/31/15 01:45 33213-65-9 Endosulfan sulfate NO mg1L 0.000050 1 1012911511:00 10131/1501:45 1031-07-8 Endrin NO mg1L 0.000050 1 1012911511:00 10131/1501:45 72-20-8 Endrin aldehyde NO mg1L 0.000050 1 10/29/15 11:00 10/31/15 01:45 7421-934 Heptachlor NO mg1L 0.000050 1 10/29/15 11:00 10131/15 01:45 76-44-8 Heptachlor epoxide NO mg1L 0.000050 1 10/29/15 11:00 10/31/15 01:45 1024-57-3 PCB-1016 (Aroclor 1016) NO mg1L 0.00050 1 10/29/15 11:00 10/31/15 01:45 12674-11-2 PCB-1221 (Aroclor 1221) NO mg1L 0.00050 1 10/29/15 11:00 10131/15 01:45 11104.28-2 PCB-1232 (Aroclor 1232) NO mg1L 0.00050 1 10/29/15 11:00 10/31/15 01:45 11141-16-5 PCB-1242 (Aroclor 1242) NO mg1L 0.00050 1 10/29/15 11:00 10/31/15 01:45 53469-21-9 PCB-1248 (Aroclor 1248) ND mg1L 0.00050 1 10/29/15 11:00 10/31/15 01:45 12672-29-6 PCB-1254 (Aroclor 1254) NO mg1L 0.00050 1 10/29/15 11:00 10/31/15 01:45 11097-69-1 PCB-1260 (Aroclor 1260) NO mg1L 0.00050 1 10/29/15 11:00 10/31/15 01:45 11096-82.5 Toxaphene NO mg1L 0.00050 1 10/29/15 11:00 10/31/15 01:45 6001-35-2 Surrogates Tetrachloro-m-xylene (S) 55 % 20-110 1 10/29/15 11:00 10/31/15 01:45 877-09-8 Decachlorobiphenyl (S) 47 % 20-138 1 10/29/15 11:00 10/31/15 01:45 2051-24-3 200.7 MET ICP Analytical Method: EPA200.7 Preparation Method: EPA200.7 Copper 0.0069 mg1L 0.0050 1 10/30/15 20:30 11/05/15 18:27 7440-50-8 Lead ND mg1L 0.0050 1 10/30115 20:30 11/05/15 18727 7439-92-1 Zinc 0.037 mglL 0.010 1 10/30/15 20730 11/05/15 18:27 7440-66-6 625 MSSV Analytical Method: EPA625 Preparation Method: EPA625 Acenaphthene ND mg1L 0.0050 1 10/29/15 15:33 10/31/15 05:20 83-32-9 Acenaphthylene ND mglL 0.0050 1 10/29/15 15:33 10/31/l5 05:20 208-96-8 REPORT Of LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 1110912015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 20 of 50 (�Iacmnalytical" www.paoelabs.com ANALYTICAL RESULTS Project: Storm Water Testing Pace Project No.: 92273536 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Sample: SDO #12 Parameters Lab ID: 92273535005 Results Units Collected: 10/27/15 00:00 Report Limit DF Received: 10127115 15:15 Matrix: Water Prepared Analyzed CAS No. Qual 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 Acetophenone NO mg1L 0.0050 1 10129/15 15:33 10/31/15 05:20 98-86-2 Aniline NO mg1L 0.010 1 10/29/15 15:33 10/31/15 05:20 62-53-3 Anthracene NO mg1L 0.0050 1 10/29/15 i5:33 10/3111505:20 120-12-7 Benzidine NO mg1L 0.050 1 10/29/15 15:33 10/31/15 05:20 92-87-5 L2 Benzo(a)anthracene NO mglL 0.0050 1 10/29/15 15:33 10/31/15 05:20 56-55-3 Benzo(a)pyrene NO mg1L 0.0050 1 10/29/15 15:33 10/31/15 05:20 50-32-8 Benzo(b)fluoranthene NO mg/L 0.0050 1 10/29115 15:33 10/31/15 05:20 205-99-2 8enzo(g,h,i)perylene NO mg/L 0.0050 1 1012911515:33 10/31/15 05:20 191-24-2 Benzo(k)fluoranthene NO mg1L 0.0050 1 10/29/15 15:33 10/31/15 05:20 207-08-9 4-Bromophenylphenyl ether ND mg/L 0.0050 1 10/29/15 15:33 10/31/15 05:20 101-55-3 Butylbenzylphthalate NO mg1L 0.0050 1 10/29/15 15:33 10/31/15 05:20 85-68-7 4-Chloro-3-methyl phenol NO mg/L 0.0050 1 10/29/15 15:33 10/31/15 05:20 59-50-7 bis(2-Chloroethoxy)methane NO mg/L 0.010 1 10/29/15 15:33 10/31/15 05:20 111-91-1 bis(2-Chloroethyl)ether NO mg1L 0.0050 1 1012911515:33 10/3111505:20 111-44-4 bis(2-Chloroisopropyl)ether ND mg1L 0,0050 1 1012911515:33 10/31/15 05:20 108-60-1 2-Chloronaphthalene NO mg/L 0.0050 1 1012911515:33 10/31/15 05:20 91-58-7 2-Chlorophenol NO mg1L 0.0050 1 1012911515:33 10/31/15 05:20 95-57-8 4-Chlorophenylphenyl ether ND mg1L 0.0050 1 10/29/15 15733 10/31/15 05:20 7005-72-3 Chrysene NO mg1L 0.0050 1 10129/15 15:33 10/31/15 05:20 218-01-9 Dibenz(a,h)anthracene NO mg/L 0.0050 1 10/29/15 15:33 10/31/15 05:20 53-70-3 1,2-Dichlorobenzene ND mg/L 0.0050 1 10/29/15 15733 10/31/15 05:20 95-50-1 1,3-Dichlorobenzene NO mg1L 0.0050 1 10/29/15 15:33 10/31/15 05:20 541-73-1 1,4-Dichlorobenzene NO mg/L 0.0050 1 10/29/15 15:33 10/31/15 05:20 105-45-7 3,3'-Dichlorobenzidine NO mglL 0.025 1 10/29/15 15:33 10/31/15 05:20 91.94-1 2,4-Dichlorophenol ND mg1L 0.0050 1 1012911515:33 10/31/15 05:20 120-83-2 Diethylphthalate ND mg/L 0.0050 1 10/29/15 15:33 10/31/15 05:20 84-66-2 2,4-Dimethylphenol NO mg1L 0.010 1 10/29/15 15:33 10/31/15 05:20 105-67-9 Dimethylphtha late NO mg/L 0.0050 1 10/29/15 15:33 10131/15 05:20 131-11-3 Di-n-butylphthalate NO mg1L 0.0050 1 10/29/15 15:33 10/31/15 05:20 84-74-2 4,6- Din itro-2-methylphenol NO mg/L 0.020 1 10/29/15 15:33 10/31/15 05:20 534-52-1 2,4-Dinitrophenol NO mg1L 0.050 1 10/29/15 15:33 10/31/15 05:20 51-28-5 2,4-Dinitrotoluene NO mg/L 0.0050 1 10/29/15 15:33 10/31/15 05:20 121-14-2 2,6-Dinitrotoluene NO mg1L 0.0050 1 10/29/15 15:33 10/31/15 05:20 606-20-2 Di-n-octylphthalate ND mg1L 0.0050 1 10/29/15 15:33 10/31/15 05:20 117-84-0 1,2-Diphenylhydrazine NO mg1L 0.0050 1 10/29/15 15:33 10131/15 05:20 122-66-7 bis(2-Ethylhexyl)phthalate ND mg1L 0.0050 1 10/29/15 15:33 10131/16 05:20 117-81-7 Fluoranthene NO mg1L 0.0050 1 10/29/15 15:33 10/31/15 05:20 206-44-0 Fluorene ND mg1L 0.0050 1 10/29/15 15:33 10131/15 05:20 86-73-7 Hexachloro-1,3-butadiene NO mg1L 0.0050 1 10/29/15 15:33 10/31/15 05:20 87-68-3 Hexachlorobenzene NO mg1L 0.0050 1 10/29/15 15:33 10/31/15 05:20 118-74-1 Hexachlorocyclopentadiene NO mglL 0.010 1 10/29/15 15:33 10/31/15 05:20 77.47-4 Hexachloroethane NO mg1L 0.0050 1 10/29/15 15:33 10/31/15 05:20 67-72-1 Indeno(1,2,3-cd)pyrene NO mg1L 0.0050 1 10/29/15 15733 10/31/15 05:20 193-39-5 lsophorone NO mg1L 0.010 1 10/29/15 15:33 10/31/15 05:20 78-59-1 Naphthalene NO mglL 0.0050 1 10/29/15 15733 10/31/15 05:20 91-20-3 Nitrobenzene NO mg1L 0.0050 1 10/29/15 15:33 10/31/15 05:20 98.95-3 2-Nitrophenol NO mglL 0.0050 1 10/29/15 15:33 10/31/15 05:20 88-75-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /09/2015 08746 AM without the written consent of Pace Analytical Services, Inc,. Page 21 of 50 Pace Analytical Services, Me. aceAnalytrca! 205 East Meadow Road - Suite A Eden, NC 27288 K'" wp&CWeb.i-com t336)623-8921 ANALYTICAL RESULTS Project: Storm Water Testing Pace Project No.: 92273535 Sample: WO #12 Lab ID: 92273535005 Collected: 10/27/15 00:00 Received: 10/27/15 15:15 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No, Qual 625 MSSV Analytical Method: EPA625 Preparation Method: EPA625 4-Nitrophenol ND mglL 0.050 1 10/29/15 15:33 10/31/15 05:20 100-02-7 N-Nitrosodimethylamine ND mglL 0.0050 1 10/29/15 15:33 10/31/15 05:20 62-75-9 N-Nitroso-di-n-propylamine ND mglL 0.0050 1 10/29/15 15:33 10/31/15 05:20 621-64-7 N-Nitrosodiphenylamine ND mg1L 0.010 1 10/29/15 15:33 10/31/15 05:20 86-30-6 Pentachlorophenol ND mglL 0.010 1 10/29/15 15:33 10/31/15 05:20 87-86-5 Phenanthrene ND mglL 0.0050 1 10/29/15 15:33 10/31/15 05:20 85-01.8 Phenol ND mg1L 0,0050 1 10/29/15 15:33 10/31/15 05:20 108-95-2 Pyrene ND mg1L 0.0050 1 10/29/15 15:33 10/31/15 05:20 129-00-0 1,2,4-Trichlorobenzene ND mg1L 0.0050 1 10/29/15 15:33 10/3111505:20 120-82-1 2,4,6-Trichlorophenol ND mg/L 0,010 1 10/29/15 15:33 10/31/15 05:20 88-06-2 Surrogates Nitrobenzene-d5 (S) 73 % 10-120 1 10/29/15 15:33 10/31/15 05:20 4165-60-0 2-Fluorobiphenyl (S) 72 % 15-120 1 10/29/15 15:33 10/31/15 05:20 321-60-8 Terphenyl-d14 (S) 89 % 11-131 1 10/29/15 15:33 10/31/15 05:20 1718-51-0 Phenol-d6 (S) 24 % 10-120 1 10/29/15 15:33 10/31/15 05:20 13127-88-3 2-Fluorophenol (S) 37 % 10-120 1 10/29/15 15:33 10/31/15 05:20 367-12-4 2,4,6-Tribromophenol (S) 79 % 10-137 1 10/29/15 15:33 10/31/15 05:20 118.79-6 624 Volatile Organics Analytical Method: EPA 624 Acetone ND mg1L 0.010 1 10/31/15 13:42 67-64-1 Acrolein ND mg1L 0.0050 1 10/3111513:42 107-02-8 Acrylonitrile ND mg1L 0.050 1 10/3111513:42 107-13-1 Benzene ND mg1L 0.0020 1 10/31/15 13:42 71-43-2 Bromobenzene ND mg1L 0.0020 1 10/31/15 13:42 108-86-1 Bromochloromethane ND mg1L 0.0020 1 10/31/15 13:42 74-97-5 Bromodichloromethane ND mg1L 0.0020 1 10131/1513A2 75-27-4 Bromoform ND mg1L 0.0020 1 10/31/15 13:42 75-25-2 Bromomethane ND mg1L 0.0020 1 10/31/15 13:42 74-83-9 2-Butanone (MEI) ND mg/L 0.0050 1 10/31/15 13:42 78-93-3 n-Butylbenzene ND mg1L 0.0050 1 10/31/15 13:42 104-51-8 sec-Butylbenzene ND mg1L 0,0050 1 10131/1513:42 135-98-8 tert-Butyl benzene N❑ mg1L 0.0050 1 10131/1513:42 98-06-6 Carbon disulfide ND mg1L 0.0050 1 10/31/15 13:42 75-15-0 L3 Carbon tetrachloride ND mg1L 0.0020 1 10/31/15 13A2 56-23-5 Chlorobenzene ND mg1L 0.0020 1 1013111513:42 108-90-7 Chloroethane ND mg1L 0.0020 1 10/3111513:42 75-00-3 2-Chloroethylvinyl ether ND mg1L 0.0050 1 10/31/15 13A2 110-75-8 c2 Chloroform ND mglL 0.0020 1 1013111513:42 67.66-3 Chloromethane ND mg/L 0.0020 1 1013111513A2 74-87-3 2-Chlorotoluene ND mg1L 0.0020 1 1013111513A2 95-49-8 4-Chlorotoluene ND mg1L 0.0020 1 10/3111513:42 106-43-4 Dibromochloromethane ND mg1L 0.0020 1 1013111513A2 124-48-1 1,2-Dibromoethane (EDB) ND mg1L 0.0020 1 10/31/15 13:42 106-93-4 Dibromomethane ND mg1L 0,0020 1 10131IM513A2 74-95-3 1,2-Dichlorobenzene ND mg1L 0.0020 1 1013111513:42 95-50-1 1,3-Dichlorobenzene ND mg1L 0.0020 1 10/3111513:42 541-73-1 1,4-Dichlorobenzene ND mg1L 0.0020 1 1013111513:42 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/09/2015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 22 of 50 aceAnaVical www.pacelaftmn ANALYTICAL RESULTS Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: Storm Water Testing Pace Project No.: 92273535 Sample: SDO #12 Lab ID: 92273535005 Collected: 10/27/15 00:00 Received: 101271151515 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 624 Volatile Organics Analytical Method: EPA624 1,1-Dichloroethane NO mg1L 0.0020 1 10/31/15 13:42 75-34-3 1,2-Dichloroethane NO mg/L 0.0020 1 1013111513:42 107-06-2 1,1-Dichloroethene NO mglL 0.0020 1 1013111513:42 75-35-4 cis- 1,2-Dichloroethene ND mg/L 0.0020 1 1013111513:42 156-59-2 trans-1,2-Dichloroethene NO mg/L 0.0020 1 1013111513A2 156-60-5 1,2-Dichloropropane NO mg/L 0.0020 1 1013111513:42 78-87-5 1,3-Dichloropropane NO mg/L 0.0020 1 1013111513:42 142-28-9 2,2-Dichloropropane ND mg/L 0.0050 1 10131/1513:42 594-20-7 1,1-Dichloropropene NO mg/L 0.0020 1 10131/1513742 563-58-6 cis- 1,3-Dichloropro pene NO mg/L 0.0020 1 1013111513:42 10061-01-5 trans-1,3-Dichloropropene NO mg/L 0,0020 1 10/31/1513A2 10061-02-6 Ethylbenzene NO mg/L 0.0020 1 1013111513742 100-41-4 Hexachloro-1,3-butadiene NO mg/L 0.0050 1 10/3111513:42 87-68-3 2-Hexanone NO mglL 0,010 1 1013111513A2 591-78-6 lodomethane NO mg/L 0,010 1 1013111513:42 74-88-4 Isopropylbenzene (Cumene) NO mg/L 0.0050 1 10/31/15 13:42 98-82-8 p-Isopropyltoluene NO mg/L 0.0050 1 10/3111513:42 99-87-6 Methylene Chloride NO mg/L 0.0020 1 10/31/15 13:42 75-09-2 4-Methyl-2-pentanone (M18K) NO mg/L 0.010 1 10/31/15 13:42 108-10-1 Methyl-tert-butyl ether NO mg/L 0.0050 1 10/31/15 13:42 1634-04-4 Naphthalene NO mg/L 0.0050 1 1013111513:42 91-20-3 n-Propylbenzene ND mg/L 0.0050 1 1013111513:42 103-65-1 Styrene NO mg/L 0.0020 1 10/3111513:42 100-42-5 1,1,1,2-Tetrachloroethane NO mg/L 0.0020 1 10/3111513:42 630-20-6 1,1,2,2-Tetrachloroethane ND mg/L 0.0020 1 10/31/15 13:42 79-34-5 Tetrachloroethene ND mg/L 0.0020 1 10/31/15 13:42 127-18-4 Toluene ND mg/L 0.0020 1 10/31/15 13:42 108-88-3 1,2,3-Trichlorobenzene ND mg/L 0.0020 1 10/31/15 13:42 87-61-6 1,2,4-Trichlorobenzene ND mg/L 0.0020 1 10/31/15 13:42 120-82-1 1,1,1-Trichloroethane NO mg/L 0.0020 1 10/31/15 13:42 71-55-6 1,1,2-Trichloroethane ND mg/L 0.0020 1 10131/1513:42 79-00-5 Trichloroethene ND mg/L 0.0020 1 10/31/15 13:42 79-01-6 Trichlorofluoromethane ND mg/L 0.0020 1 10/31/15 13:42 75-694 1,2,3-Trichloropropane ND mg/L 0.0020 1 10/31/15 13:42 96-18.4 1,1,2-Trichlorotrifluoroethane ND mg/L 0.0020 1 10/31/15 13:42 76-13-1 1,2,4-Trimethylbenzene ND mg/L 0.0020 1 10/31/15 13:42 95-63-6 1,3,5-Trimethylbenzene ND mg/L 0.0020 1 10/31/15 13:42 108-67-8 Vinyl acetate NO mg/L 0,0050 1 10/31/15 13:42 108-05-4 Vinyl Chloride NO mg/L 0.0020 1 10/31/15 13:42 75-01-4 m&p-Xylene NO mg/L 0.0050 1 10/31/15 13:42 179601-23-1 o-Xylene NO mg/L 0.0050 1 10/31/15 13:42 95-47-6 Surrogates 4-Bromofluorobenzene (S) 101 % 70-130 1 10/31/15 13:42 460-00-4 Toluene-d8 (S) 99 % 70-130 1 10/31/15 13:42 2037-26-5 1,2-Dichloroethane-d4 (S) 94 % 70-130 1 10/31/15 13:42 17060-07-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, ❑ate: 11/09/2015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 23 of 50 (�IaneAnalytical * W*WP&cdabac= ANALYTICAL RESULTS Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-6921 Project: Storm Water Testing Pace Project No.: 92273535 Sample: FALLING SAMPLE Lab ID: 92273535006 Collected: 10/27/15 00:00 Received: 10/27/15 15:15 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 4500H+ pH, Electrometric EDN pH at 25 Degrees C Date: 11/09/2016 08:46 AM Analytical Method: SM 4500-H+B 5.1 ' Std. Units 1.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. 10/27/15 16:25 H6 Page 24 of 50 aceAnalylfical wwwcpacelaftem QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92273535 QC Batch: EDEN120516 Analysis Method: SM 2540D QC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 92273535001, 92273535002, 92273535003, 92273535004, 92273535005 METHOD BLANK: 1593375 Matrix: Water Associated Lab Samples: 92273535001, 92273535002, 92273535003, 92273535004, 92273535005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 10/28/15 13:01 LABORATORY CONTROL SAMPLE: 1593376 Parameter Units Total Suspended Solids mg/L SAMPLE DUPLICATE: 1593377 Parameter Units Total Suspended Solids mg/L SAMPLE DUPLICATE: 1593378 Parameter Units Total Suspended Solids mg/L Spike Cone. 250 92273480001 Result 41.8 LCS LCS Result % Rec 258 103 Dup Result 42.5 92273535004 Dup Result Result 21.6 21.6 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 % Rec Limits Qualifiers 90-110 RPD Qualifiers 2 RPD Qualifiers 0 Results presented on this page are In the units Indicated by the "Units" column except where an altemate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/09/2015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 25 of 50 acmnalytical6 wwwpar&ra6l.o5,m QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92273535 QC Batch: EDEN120513 Analysis Method: SM 4500-H+B QC Batch Method: SM 4500-H+B Analysis Description: 4500H+B pH EDEN Associated Lab Samples: 92273535001, 92273535002, 92273535003, 92273535004, 92273535005, 92273535006 SAMPLE DUPLICATE: 1593131 92273535006 Dup Parameter Units Result Result RPD Qualifiers pH at 25 Degrees C Sid. Units 5.1 5.1 0 H6 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27208 (336)623-8921 Results presented on this page are in the units Indicated by the "Units" column except where an attemate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shag not be reproduced, except in full, Date: 11109I2015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 26 of 50 (�5a'cmnalyficaf' wtvw pecelabscom QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92273535 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 QC Batch: GCSv123115 Analysis Method: EPA 1664E QC Batch Method: EPA 1664E Analysis Description: 1664 SGT-HEM, TPH Associated Lab Samples: 92273535001, 92273535002, 92273535003, 92273535004, 92273535005 METHOD BLANK: 1599310 Matrix: Water Associated Lab Samples: 92273535001, 92273535002, 92273535003, 92273535004, 92273535005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Petroleum Hydrocarbons mg/L ND 5.0 11/05/15 07:44 LABORATORY CONTROL SAMPLE: 1599311 Spike LCS LCS % Rec Parameter Units Colic. Result % Rec Limits Qualifiers Total Petroleum Hydrocarbons mg1L 20 14,3 72 64-132 MATRIX SPIKE SAMPLE: 1599312 92273900001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Total Petroleum Hydrocarbons mg1L ND 20 14.3 72 64-132 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/09/2015 08A6 AM without the written Consent of PaceAnatytical Services, Inc.. Page 27 of 50 laneAnalytical" www.paaahs.com Project: Storm Water Testing Pace Project No.: 92273535 QC Batch: MPRP119932 QC Batch Method: EPA 200.7 Associated Lab Samples: 92273535001 METHOD BLANK: 1596280 Associated Lab Samples: 92273535001 Parameter Copper Lead Zinc QUALITY CONTROL DATA Analysis Method: EPA 200.7 Analysis Description: 200.7 MET Matrix: Water Blank Reporting Units Result Limit Analyzed mg/L ND 0.0050 11/03/15 22:28 mg/L ND 0.0050 11/03/15 22:28 mg/L ND 0.010 11/03/15 22:28 Qualifiers Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 LABORATORY CONTROL SAMPLE: 1596281 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Copper mg/L .5 0.49 98 85-115 Lead mg/L .5 0.49 98 85-115 Zinc mg1L .5 0.48 97 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1596282 1596283 MS MSD 92273718005 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Copper mg/L 75.3 .5 .5 0.54 0.53 93 91 70-130 2 ug1L Lead mg1L ND .5 .5 0,49 0.47 98 94 70-130 5 Zinc mg1L ND .5 .5 0.53 0.52 96 94 70-130 2 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1596284 1596285 MS MSD 92273918003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Copper mg/L 27.2 .5 .5 0.50 0.48 95 91 70-130 4 ug/L Lead mg1L ND .5 .5 0.44 0.41 88 83 70-130 - 6 Zinc mg/L 17.6 .5 .5 0.50 0.49 97 94 70-130 4 ug1L Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/09/2015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 28 of 50 (� aceAnalytical www.pecdebs.cam QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92273535 QC Batch: MPRP/19933 Analysis Method: EPA 200.7 QC Batch Method: EPA200.7 Analysis Description:` 2003 MET Associated Lab Samples: 92273535002, 92273535003, 92273535004, 92273535005 METHOD BLANK: 1596290 Matrix: Water Associated Lab Samples: 92273535002, 92273535003, 92273535004, 92273535005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Copper mg1L ND 0.0050 11105/1517:57 Lead mg1L ND 0.0050 1110511517:57 Zinc mg1L ND 0.010 1110511517:57 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 LABORATORY CONTROL SAMPLE: 1596291 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Copper mg1L .5 0.50 101 85-115 Lead mg1L .5 0.49 98 85-115 Zinc mg1L .5 0.49 98 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1595292 1596293 MS MSD 92273535002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Copper mg1L 0.0051 .5 .5 0.49 0.48 97 96 70-130 1 Lead mg1L ND .5 .5 0.47 0.47 94 93 70-130 1 Zinc mg1L 0.19 .5 .5 0.66 0.66 94 93 70-130 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1596294 1596295 MS MSD 92273764001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Copper mg1L ND 5 .5 0.099 0.084 20 17 70-130 16 M1 Lead mg1L ND .5 .5 0.10 0.084 20 17 70-130 19 M1 Zinc mg1L ND .5 .5 0.12 0.10 23 19 70-130 17 M1 Results presented on this page are In the units Indicated by the "Units" column except where an atternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/09/2015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 29 of 50 ac6Analytical w"..paaekbscom QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92273535 QC Batch: MSV134091 Analysis Method: EPA624 QC Batch Method: EPA624 Analysis Description: 624 MSV Associated Lab Samples: 92273535001, 92273535002, 92273535003, 92273535004, 92273535005 METHOD BLANK: 1596375 Matrix: Water Associated Lab Samples: 92273535001, 92273535002, 92273535003, 92273535004, 92273535005 Blank Reporting Parameter Units Result Limit Analyzed 1,1,1,2-Tetrachloroethane mg1L ND 0.0020 10/31115 00:45 1,1,1-Trichloroethane mglL NO 0.0020 10/31/15 00:45 1,1,2,2-Tetrachloroethane mg1L NO 0.0020 10/31115 00:45 1,1,2-Trichloroethane mg1L NO 0.0020 10/31115 00:45 1,1,2-Trichlorotriftuoroethane mg1L ND 0.0020 10/31/15 00:45 1,1-Dichloroethane mg1L NO 0,0020 10/31/15 00:45 1,1-Dichloroethene mg1L NO 0.0020 10/31/15 00:45 1,1-Dichloropropane mg1L NO 0.0020 10/31/15 00:45 1,2,3-Trichlorobenzene mg1L NO 0.0020 10/31/15 00:45 1,2,3-Trichloropropane mg/L NO 0.0020 10/31/15 00:45 1,2,4-Trichlorobenzene mg1L NO 0.0020 10/31115 00:45 1,2,4-Trimethylbenzene mg1L NO 0.0020 10131/15 00:45 1,2-Dibromoethane (EDB) mg1L NO 0.0020 10131/15 00:45 1,2-Dichlorobenzene mg1L NO 0.0020 10/31/15 00A5 1,2-Dichloroethane mg1L NO 0.0020 10/31115 00:45 1,2-Dichloropropane mg1L NO 0.0020 10131/15 00:45 1,3,5-Trimethylbenzene mg1L NO 0.0020 10/31/15 00:45 1,3-Dichlorobenzene mg1L NO 0.0020 10/31/15 00:45 1,3-Dichloropropane mg1L NO 0.0020 10/31/15 00:45 1,4-Dichlorobenzene mg1L NO 0.0020 10131/1500:45 2,2-Dichloropropane mg/L NO 0.0050 10/31/15 00:45 2-Butanone (MEK) mg1L NO 0.0050 10/31/15 00A5 2-Chloroethylvinyl ether mg1L NO 0.0050 10/31/15 00:45 2-Chlorotoluene mg/L NO 0.0020 10/31/15 00:45 2-Hexanone mg/L ND 0.010 10/31/15 00:45 4-Chlorotoluene mg/L NO 0.0020 10/31/15 00A5 4-Methyl-2-pentanone (MIBK) mg/L NO 0.010 10/31/15 00:45 Acetone mg/L NO 0.010 10/31/15 00:45 Acrolein mg/L NO 0.0050 10/31/15 00:45 Acrylonitrile mg/L NO 0.050 10/31/15 00:45 Benzene mg1L NO 0,0020 10/31/15 00:45 Bromobenzene mg/L NO 0.0020 10/31/15 00:45 Bromochloromethane mg1L ND 0.0020 10/31/15 00:45 Bromodichloromethane mg/L ND 0.0020 10/31/15 00:45 Bromoform mg/L ND 0.0020 10/31/15 00:45 Bromomethane mg/L NO 0,0020 10/31/15 00A5 Carbon disulfide mg/L NO 0.0050 10/31/15 00:45 Carbon tetrachloride mg/L NO 0.0020 10/31/15 00A5 Chlorobenzene mg/L NO 0.0020 10/31/15 00A5 Chloroethane mg/L ND 0.0020 10/31/15 00:45 Chloroform mg/L ND 0.0020 10/31/15 00:45 Qualifiers Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /09/2015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 30 of 50 aceAnalytrcal www.pacelabs.com QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92273535 METHOD BLANK: 1596375 Matrix: Water Associated Lab Samples: 92273535001, 92273535002, 92273535003, 92273535004, 92273535005 Blank Reporting Parameter Units Result Limit Analyzed Chloromethane mglL NO 0.0020 10/31/15 00:45 cis-1,2-Dichloroethene mglL NO 0.0020 10/31/15 00:45 cis- 1,3-Dichloropropene mglL NO 0.0020 10/31/15 00:45 Dibromochloromethane mg1L NO 0.0020 10/31115 00:45 Dibromomethane mg1L ND 0.0020 10/31/15 00:45 Ethylbenzene mg1L NO 0.0020 10/31/15 00:45 Hexachloro-1,3-butadiene mg1L ND 0.0050 1013111500A5 lodomethane mg1L NO 0.010 10/31/15 00:45 Isopropylbenzene (Cumene) mg1L NO 0.0050 10/31/15 00:45 m&p-Xylene mg1L NO 0.0050 10/31/15 00A5 Methyl-tert-butyl ether mg1L NO 0.0050 10/31/15 00:45 Methylene Chloride mg1L NO 0.0020 10/31/15 00:45 n-Butylbenzene mg1L NO 0,0050 10/31/15 00:45 n-Propylbenzene mg1L ND 0.0050 10/31/15 00:45 Naphthalene mg1L ND 0.0050 10/31/15 00:45 o-Xylene mg1L NO 0,0050 10/31/15 00A5 p-Isopropyltoluene mg1L NO 0.0050 10/31/15 00:45 sec -Butyl benzene mg/L NO 0.0050 10/31/15 00:45 Styrene mg/L NO 0.0020 10/31/15 00:45 tert-Butylbenzene mg1L NO 0,0050 10/31/15 00:45 Tetrachloroethane mg1L NO 0.0020 10/31/15 00:45 Toluene mg1L NO 0.0020 10/31/15 00:45 trans- 1,2-Dichloroethene mg1L NO 0,0020 10/31/15 00:45 trans- 1,3-Dichloropropene mg1L NO 0,0020 10/31/15 00A5 Trichloroethene mg/L NO 0.0020 10/31/15 00:45 Tdchlorofluoromethane mg/L ND 0.0020 10/31/15 00:45 Vinyl acetate mg/L NO 0.0050 10/31/15 00:45 Vinyl chloride mg1L NO 0.0020 10/31/15 00:45 1,2-Dichloroethane-d4(S) % 98 70-130 10131/1500:45 4-Bromofluorobenzene (S) % 99 70-130 10/31/15 00:45. Toluene-d8 (S) % 102 70-130 10/31/15 00:45 Qualifiers Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 LABORATORY CONTROL SAMPLE: 1596376 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane mg1L .02 0.018 88 70-130 1, 1, 1 -Trichloroethane mg/L .02 0.018 89 52-162 1,1,2,2-Tetrachloroethane mg1L .02 0.017 87 46-157 1,1,2-Trichloroethane mg/L .02 0.017 83 52-150 1.1,2-Trichlorotrifluoroethane mg/L .02 0,018 91 70-130 1,1-Dichloroethane mg1L .02 0.018 90 59-155 1,1-Diehl oroethene mg1L 02 0.018 92 1-234 1,1-Dichloropropene mg1L .02 0.018 90 70-130 1,2,3-Trichlorobenzene mg1L .02 0.021 103 70-130 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/09/2015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 31 of 50 laneAnalytical" ~pacdaba.c= Project: Storm water Testing Pace Project No.: 92273535 LABORATORY CONTROL SAMPLE: 1596376 Parameter Units 1,2,3-Trichloropropane mg1L 1,2,4-Trichlorobenzene mg1L 1,2,4-Trimethylbenzene mg1L 1,2-Dibromoethane (EDB) mg1L 1,2-Dichlorobenzene mg1L 1,2-Dichloroethane mg1L 1,2-Dichloropropane mg1L 1,3,5-Trimethylbenzene mg1L 1,3-Dichlorobenzene mg1L 1,3-Dichloropropane mglL 1,4-Dichlorobenzene mg1L 2,2-Dichloropropane mg1L 2-Butanone (MEK) mg1L 2-Chloroethylvinyl ether mg1L 2-Chlorotoluene mg1L 2-Hexanone mg1L 4-Chlorotoluene mg1L 4-Methyl-2-pentanone (MIBK) mg1L Acetone mg1L Acrolein mg1L Acrylonitrile mg1L Benzene mg1L Bromobenzene mg1L Bromochloromethane mglL Bromodichloromethane mg1L Bromoform mg/L Bromomethane mg1L Carbon disulfide mg1L Carbon tetrachloride mg1L Chlorobenzene mg1L Chtoroethane mg1L Chloroform mg1L Chloromethane mglL cis- 1,2-Dich loroethene mg1L cis- 1,3-Dich loropropene mg1L Dibromochloromethane mglL Dibromomethane mglL Ethylbenzene mg1L Hexachloro-1,3-butadiene mg1L lodomethane mg1L Isopropylbenzene (Cumene) mg1L m&p-Xylene mg1L Methyl-tert-butyl ether mg1L Methylene Chloride mg1L n-Butylbenzene mg/L n-Propylbenzene mg1L Naphthalene mg1L Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 QUALITY CONTROL DATA Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers .02 0.017 85 70-430 .02 0.019 97 70-130 .02 0.021 104 70-130 .02 0.019 94 70-130 .02 0,017 85 18-190 .02 0.016 81 49-155 .02 0.018 92 1-210 02 0.018 89 70-130 .02 0.018 89 59-156 .02 0.018 89 70-130 .02 0.017 86 18-190 .02 0.016 81 70-130 .04 0.037 92 50-127 .04 0.040 99 1-305 .02 0.017 86 70-130 .04 0.039 98 70-130 .02 0.017 86 70-130 .04 0.038 94 70-130 .04 0.036 89 70-130 .1 0.098 98 15-152 .1 0.093 93 75-132 .02 0.019 93 37-151 .02 0.017 84 7D-130 .02 0.018 92 70-130 .02 0.017 83 35-155 .02 0.015 77 45-169 .02 0.021 104 1-242 .02 0.037 483 70-130 LO .02 0,017 86 70-140 .02 0.018 89 37-160 .02 0.017 87 14-230 .02 0.017 87 51-138 .02 0.016 82 1-273 .02 0.018 90 68-146 .02 0.018 92 1-227 .02 0.017 84 53-149 .02 0.018 91 70-130 .02 0.018 89 37-162 .02 0.022 109 70-130 .04 0.033 82 70-130 .02 0.018 91 70-130 .04 0.035 88 70-130 .02 0.019 97 70-130 .02 0.018 91 1-221 .02 0.019 94 70-130 .02 0.018 88 70-130 .02 0.022 108 70-130 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/09/2015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 32 of 50 laneAnalyticalo W*Wpeoetabscorn QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92273535 LABORATORY CONTROL SAMPLE: 1596376 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers o-Xylene mg1L .02 0.018 90 70-130 p-Isopropyltoluene mg1L .02 0.018 92 70-130 sec-Butylbenzene mg1L .02 0.018 92 70-130 Styrene mg1L .02 0.018 92 70-130 tent -Butyl benzene mg1L .02 0.015 76 70-130 Tetrachloroethane mg1L 02 0.018 91 64-148 Toluene mg1L .02 0.018 89 47-150 trans-1,2-Dichloroethene mg1L .02 0.019 93 54-156 trans-1,3-Dichloropropene mg/L .02 0.019 94 17-183 Trichloroethene mg/L .02 0.017 87 71-157 Trichlorotluoromethane mg1L .02 0.017 85 17-181 Vinyl acetate mg/L .04 0.037 93 70-130 Vinyl chloride mg/L .02 0.018 89 1-251 1,2-Dichloroethane-d4(S) % 92 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 100 70-130 MATRIX SPIKE SAMPLE: 1596378 92273798002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane mg/L <2.0 ug/L 02 0.021 104 70-130 1.1,1-Trichloroethane mg/L <2.0 ug/L .02 0.023 116 46-171 1,1,2,2-Tetrachloroethane mg/L <2.0 ug/L .02 0.020 102 73-159 1,1,2-Trichloroethane mg/L <2.0 ug/L 02 0.020 100 64-152 1,1,2-Trichlorotrifluoroethane mg/L <2.0 ug/L .02 0,023 117 59-168 1,1-Dichloroethane mg/L <2.0 ug/L .02 0.022 108 43-172 1,1-Dichloroethene mg/L <2.0 ug/L .02 0.023 117 48-189 1,1-Dichloropropene mg/L <2.0 ug/L .02 0.024 119 70-130 1,25-Trichlorobenzene mg/L <2.0 ug1L 02 0.021 107 70-130 1,2,3-Trichloropropane mg/L <2.0 ugJL .02 0.019 96 70-130 1,2,4-Trichlorobenzene mg/L <2.0 uglL .02 0.021 107 70-130 1,2,4-Trimethylbenzene mg/L <2.0 uglL .02 0,020 102 70-130 1,2-Dibromoethane (EDB) mg/L <2.0 ug/L .02 0.023 114 70-130 1,2-Dichlorobenzene mg/L <2.0 ug/L .02 0.020 100 54-154 1,2-Dichloroethane mg/L <2.0 ug/L .02 0,019 96 42-171 1,2-Dichloropropane mg/L <2.0 ug/L 02 0.022 112 55-157 1,3,5-Trimethylbenzene mg/L <2.0 ug/L .02 0.021 106 70-430 1,3-Dichlorobenzene mg/L <2.0 ug/L .02 0.020 100 57-148 1,3-Dichloropropane mg/L <2.0 ug/L .02 0.022 110 70-130 1,4-Dichlorobenzene mg/L <2.0 ug/L .02 0.020 98 58-149 2,2-Dichloropropane mg/L <5.0 uglL 02 0.024 120 70-130 2-Butanone (MEK) mg/L <5.0 uglL .04 0.043 107 70-130 2-Chloroethylvinyl ether mg/L <5.0 uglL .04 ND 0 70-130 M1 2-Chlorotoluene mg/L <2.0 tag/L .02 0.020 101 70-130 2-Hexanone mg/L <10.0 ug/L .04 0.045 112 70-130 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /09/2015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 33 of 50 (�55'cieAnalyticalo www,pecelebs.com QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92273535 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 MATRIX SPIKE SAMPLE: Parameter 1596378 Units 92273798002 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 4-Chlorotoluene mg/1- <2.0 ug/L 02 0,020 99 70-130 4-Methyl-2-pentanone (MIBK) mg/L <10.0 ug/L .04 0.046 114 70-130 Acetone mg/L 14.0 ug/L .04 0.053 98 70-130 Acrolein mg1L <5.0 ug1L .1 0,11 112 70-130 Acrylonitrile mg/L <50.0 ug1L .1 0.11 107 70-130 Benzene mg/L <2.0 uglL .02 0.023 114 54-163 Bromobenzene mg1L <2.0 ug1L .02 0.020 99 70-130 Bromochloromethane mg/L <2.0 ug/L .02 0.022 112 70-130 BromodichlOTOmethane mg1L <2.0 uglL .02 0.020 102 56-152 Bromoform mg/L <2.0 ug1L .02 0.018 90 53-151 Bromomethane mg/L <2.0 uglL .02 0.011 57 10-200 Carbon disulfide mglL <5.0 ug1L .02 0.047 234 70-130 MO Carbon tetrachloride mg/L <2.0 uglL .02 0.022 109 41-175 Chlorobenzene mg/L <2.0 ug1L .02 0.021 103 67-152 Chloroethane mg/L <2.0 ug1L .02 0.022 109 23-200 Chloroform mg/L <2.0 ug/L .02 0.021 107 51-166 Chloromethane mg/L <2.0 ug1L .02 0.019 97 40-175 cis-1,2-Dichloroethene mg1L <2.0 ug/L .02 0.023 113 45-174 cis-1,3-Dichloropropene mg1L <2.0 ug/L .02 0.022 112 38-146 Dibromochloromethane mglL <2.0 ug/L .02 0.020 99 65-144 Dibromomethane mg1L <2.0 ug/L .02 0.023 114 70-130 Ethylbenzene mg1L <2.0 ug/L .02 0.021 103 57-152 Hexachloro-1,3-butadiene mg1L <5.0ug/L .02 0.025 126 70-130 lodomethane mg/L <10.0 ug/L .04 0.023 58 70-130 M1 Isopropylbenzene (Cumene) mg/L <5.0 ug/L .02 0.020 102 70-130 m&p-Xylene mg1L <5.0 ug/L .04 0.041 102 70-130 Methyl-tert-butyl ether mg1L <5.0 ug/L .02 0.023 115 70-130 Methylene Chloride mg1L <2.0 ug1L .02 0.023 113 40-167 n-Butylbenzene mg/L <5.0 ug/L .02 0.021 107 70-130 n-Propylbenzene mg/L <5.0 ug/L .02 0.020 99 70-130 Naphthalene mg/L <5.0 ug/L .02 0.022 110 70-130 o-Xylene mg1L <5.0 ug/L .02 0.021 105 70-130 p-Isopropyltoluene mg1L <5.0 ug1L .02 0.021 104 70-130 sec-Butylbenzene mg1L <5.0 ug/L .02 0.021 105 70-130 Styrene mg1L <2.0 ug/L .02 0.021 103 70-130 tert-Butylbenzene mg1L <5.0 ug/L .02 0.017 86 70-130 Tetrachloroethene mglL <2.0 ug/L .02 0.022 108 59-155 Toluene mg1L <2.0 ug/L 02 0.023 Ill 47-162 trans-1,2-Dichloroethene mg/L <2.0 ug/L .02 0.022 110 47-178 trans-1,3-Dichloropropene mg/L <2.0 ug/L .02 0.023 113 39-148 Trichloroethene mg1L <2.0 ug/L .02 0.021 107 60-153 Trichlorofluoromethane mg/L <2.0 ug/L .02 0.022 Ill 42-199 Vinyl acetate mg1L <5.0 ug1L .04 0.043 107 70-130 Vinyl chloride mg/L <2.0 ug1L .02 0.024 121 46-176 1,2-Dichloroethane-d4 (S) % 90 70-130 4-Bromofluorobenzene (S) % 98 70-130 Toluene-d8 (S) % 99 70-130 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/09/2015 08A6 AM without the written consent of Pace Analytical Services, Inc.. Page 34 of 50 leAnalytical * wwvpatatab&C" Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92273535 SAMPLE DUPLICATE: 1596377 Parameter Units 92273798001 Result Dup Result 1,1,1,2-Tetrachloroethane mglL <2.0 uglL NO 1,1,1-Trichloroethane mglL <2.0 uglL ND 1,1,2,2-Tetrachloroethane mglL <2.0 ug1L NO 1,1,2-Trichloroethane mglL <2.0 ug1L NO 1,1,2-Trichlorotrifluoroethane mglL <2.0 uglL NO 1,1-Dichloroethane mglL <2.0 uglL NO 1,1-Dichloroethene mglL <2,0 ug1L NO 1,1-0ichloropropene mg1L <2.0 ug1L NO 1,2,3-Trichlorobenzene mglL <2.0 ug1L NO 1,2,3-Trichloropropane mglL <2.0 ug1L NO 1,2,4-Trichlorobenzene mglL <2.0 ug1L NO 1,2,4-Trimethylbenzene mg1L <2.0 uglL ND 1,2-Dibromoethane (EDB) mg1L <2.0 ug1L NO 1,2-Dichlorobenzene mglL <2.0 ug1L NO 1,2-Dichloroethane mg1L <2.0 uglL ND 1,2-Dichloropropane mglL <2.0 uglL NO 1,3,5-Trimethylbenzene mg1L <2.0 ug/t_ NO 1,3-Dichlorobenzene mg1L <2.0 uglL NO 1,3-Dichloropropane mglL <2.0 ug1L ND 1,4-Dichlorobenzene mg1L <2.0 uglL ND 2,2-Dichloropropane mg1L <5.0 uglL NO 2-Butanone (MEK) mg1L <5.0 uglL ND 2-Chloroethylvinyl ether mg1L <5.0 ug1L ND 2-Chlorotoluene mg1L <2.0 ug/L ND 2-Hexanone mg1L <10.0 uglL ND 4-Chlorotoluene mg1L <2.0 ug/L ND 4-Methyl-2-pentanone (MIBK) mglL <10.0 uglL ND Acetone mglL 42.3 uglL 0.037 Acrolein mg1L <5.0 uglL ND AMIonitrile mg1L <50.0 uglL ND Benzene mg1L <2.0 uglL ND Bromoberizene mg1L <2.0 uglL ND Bromochloromethane mg1L <2.0 ug/L NO BromodichlDromethane mg1L <2.0 uglL ND Bromoform mglL <2.0 uglL ND Bromomethane mglL <2.0 uglL NO Carbon disulfide mglL <5.0 uglL NO Carbon tetrachloride mg1L <2.0 uglL ND Chlorobenzene mg1L <2.0 uglL ND Chloroethane mg1L <2.0 uglL ND Chloroform mg1L <2.0 uglL NO Chloromethane mglL <2.0 uglL ND cis-1,2-Dichloroethene mg1L <2.0 uglL ND cis-1,3-Dichloropropene mg1L <2.0 uglL ND Dibromochloromethane mg1L <2.0 ug1L ND Dibromomethane mglL <2.0 ug1L NO Ethylbenzene mg1L <2.0 uglL ND RPD Qualifiers 13 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/09/2015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 35 of 50 laneAnalyticalo wwwpacaw a.com QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92273535 SAMPLE DUPLICATE: 1596377 Parameter Units 92273798001 Result Dup Result RPD Hexachloro-1,3-butadiene mg1L <5.0 ug1L ND lodomethane mg1L <10.0 ug1L ND Isopropylbenzene (Cumene) mg1L <5.0 ug1L ND m&p-Xylene mg1L <5.0 ug1L ND Methyl-tert-butyl ether mg1L <5.0 ug1L ND Methylene Chloride mg1L <2.0 ug1L ND n-Butylbenzene mg1L <5.0 ug1L ND n-Propylbenzene mg/l_ <5.0 ug1L ND Naphthalene mg1L <5.0 ug1L ND o-Xylene mg1L <5.0 ug1L ND p-Isopropyltoluene mg1L <5.0 ug1L ND sec -Butyl benzene mg1L <5.0 ug1L ND Styrene mg1L <2.0 ug1L ND tert-Butylbenzene mg1L <5.0 uglL ND Tetrachloroethene mglL <2.0 uglL ND Toluene mg1L <2.0 uglL ND trans-1,2-Dichloroethene mglL <2.0 uglL ND trans-1,3-Dichloropropene mglL <2.0 uglL ND Trichloroethene mglL <2.0 ug1L ND Trichlorofluoromethane mglL <2.0 uglL ND Vinyl acetate mglL <5.0 ug1L ND Vinyl chloride mglL <2.0 uglL ND 1,2-Dichloroethane-d4 (S) % 105 109 3 4-Bromofluorobenzene (S) % 100 100 0 Toluene-d8 (S) % 98 114 15 Qualifiers Pace Analytical Services, Inc. 205 East Meadow Road - Suite Eden, NC 27288 (336)623-8921 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result, REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 1110912015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 36 of 50 (�IaneAnalytica!6 *W..pacelalmawn QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92273535 QC Batch: OEXT138712 Analysis Method: EPA 608 QC Batch Method: EPA 3510 Analysis Description: 608 GCS Pest PCB Associated Lab Samples: 92273535001, 92273535002, 92273535003, 92273535004, 92273535005 METHOD BLANK: 1594572 Matrix: Water Associated Lab Samples: 92273535001, 92273535002, 92273535003, 92273535004, 92273535005 Blank Reporting Parameter Units Result Limit Analyzed 4,4'-DDD mg1L NO 0.000050 10131/15 04:08 4,4'-DDE mglL NO 0.000050 10131/15 04:08 4,4'-DDT mg1L NO 0.000050 10131/15 04:08 Aldrin mg1L NO 0.000050 10/31/15 04:08 alpha-BHC mg1L NO 0.000050 10/31/15 04:08 beta-BHC mg1L NO 0.000050 10/31/15 04:08 Chlordane (Technical) mg1L NO 0.00050 10/31/15 04:08 delta-BHC mg1L NO 0.000050 10/31/15 04:08 Dieldrin mg1L NO 0.000050 10/31/15 04:08 Endosulfan I mg1L NO 0.000050 10/31/15 04:08 Endosulfan II mg1L NO 0.000050 10/31/15 04:08 Endosulfan sulfate mg1L NO 0.000050 10/31/15 04:08 Endrin mg1L NO 0.000050 10/31/15 04:08 Endrin aldehyde mg1L NO 0.000050 10/31/15 04:08 gamma-BHC (Lindane) mg1L NO 0.000050 10/31/15 04:08 Heptachlor mg1L NO 0.000050 10/31/15 04:08 Heptachlor epoxide mg1L NO 0.000050 10/31/15 04:08 PCB-1016 (Aroclor 1016) mg1L NO 0.00050 10/31/15 04:08 PCB-1221 (Aroclor 1221) mg1L NO 0,00050 10/31/15 04:08 PCB-1232 (Aroclor 1232) mg1L NO 0.00050 10/31/15 04:08 PCB-1242 (Aroclor 1242) mg1L NO 0.00050 10/31/15 04:08 PCB-1248 (Aroclor 1248) mg/L NO 0,00050 10/31/15 04:08 PCB-1254 (Aroclor 1254) mg1L NO 0.00050 10/31/15 04:08 PCB-1260 (Aroclor 1260) mg1L NO 0.00050 10/31/15 04:08 Toxaphene mg1L NO 0.00050 10/31/15 04:08 Decachlorobiphenyl (S) % 70 20-138 10/31/15 04:08 Tetrachloro-m-xylene IS) % 91 20-110 10/31/15 04:08 Qualifiers Pace Analytical Services, Inc. 205 East Meadow Road - Suite Eden, NC 27288 (336)623-8921 LABORATORY CONTROL SAMPLE: 1594573 Spike LCS LCS % Rec. Parameter Units Conc. Result % Rec Limits Qualifiers 4,4'-DDD mg1L .00025 0.00023 95 31-141 4,4'-DDE mg1L .00025 0.00022 89 30-145 4,4'-DDT mg1L .00025 0.00022 89 25-160 Aldrin mg1L .00025 0.00020 80 42-122 alpha-BHC mg1L .00025 0.00023 92 37-134 beta-SHC mglL .00025 0.00024 97 17-147 delta-BHC mg1L .00025 0.00023 93 19-140 Dieldrin mg1L .00025 0.00024 96 36-146 Endosulfan I mg1L .00025 0.00023 93 45-153 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shatl not be reproduced, except in full, Date: 11/09/2015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 37 of 50 (�55'cmnalyfical* %Ww.pecelam.com QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92273535 LABORATORY CONTROL SAMPLE: Parameter 1594573 Units Spike Canc. LCS Result LCS % Rec % Rec Limits Endosulfan II mg1L 00025 0.00024 98 1-202 Endosulfan sulfate mglL .00025 0.00024 97 26-144 Endrin mglL .00025 0.00024 96 30-147 Endrin aldehyde mg1L 00025 0.00021 84 50-150 gamma-BHC (Lindane) mg1L .00025 0.00023 92 32-127 Heptachlor mglL .00025 0.00020 82 34-111 Heptachlor epoxide mglL .00025 0.00023 92 41-126 Decachlorobiphenyl (S) % 71 20-138 Tetrachloro-m-xylene (S) % 95 20-110 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Qualifiers MATRIX SPIKE SAMPLE: Parameter 1594574 Units 92273805001 Result Spike Canc. MS Result MS % Rec % Rec Limits Qualifiers 4,4'-DDD mglL ND .00025 0.00029 116 31-141 4,4'-DDE mglL ND 00025 0,00025 99 30-145 4,4'-DDT mg/L ND .00025 0.00035 141 25-160 Aldrin mglL ND .00025 0.00022 90 42-122 alpha-BHC mglL ND 00025 0,00019 78 37-134 beta-BHC mg/L ND .00025 0.00051 204 17-147 M3 delta-BHC mglL ND .00025 0.00023 93 19-140 Dieldrin mglL ND .00025 0.00024 96 36-146 Endosulfan I mglL ND .00025 0.00031 124 45-153 Endosulfan II mg/L ND 00025 0.00027 108 1-202 Endosulfan sulfate mglL ND .00025 0.00032 131 26-144 Endrin mg/1- ND .00025 0.00027 110 30-147 Endrin aldehyde mglL ND 00025 0.00032 128 50-150 gamma-BHC (Lindane) mglL ND .00025 0.00019 78 32-127 Heptachlor mglL ND .00025 0.00019 77 34-111 Heptachlor epoxide mglL ND .00025 0.00020 82 41-126 Decachlorobiphenyl (S) % 54 20-138 Tetrachloro-m-xylene (S) % 81 20-110 SAMPLE DUPLICATE: 1594575 92273805002 Dup Parameter Units Result Result RPD Qualifiers 4,4'-DDD mglL ND ND 4,4'-DDE mg/L ND ND 4,4'-DDT mg/L ND ND Aldrin mg1L ND ND alpha-BHC mglL ND ND beta-BHC mg1L ND ND Chlordane (Technical) mglL ND ND delta-BHC mglL ND ND Dieldrin mglL ND ND Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the resuft. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/09/2015 08:46 AM without the written consent of Pace Analytical Services, Inc„ Page 38 of 50 laneAnalytical mmpecelabs.corn Project: Storm Water Testing Pace Project No.: 92273535 SAMPLE DUPLICATE: 1594575 Parameter Endosulfan Endosulfan II Endosulfan sulfate Endrin Endrin aldehyde gamma-BHC (Lindane) Heptachlor Heptachlor epoxide Toxaphene QUALITY CONTROL DATA Units 92273805002 Result Dup Result mg/L ND ND mg/L ND ND mg/L ND ND mg/L ND ND mg/L ND ND mglL ND ND mg/L ND ND mg/L ND ND mg/L ND ND RPD Qualifiers Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Results presented, on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/09/2015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 39 of 50 (�55'neAnalyfica( wnwvpaceMb&com QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92273535 QC Batch: OEXT138721 Analysis Method: EPA 625 QC Batch Method: EPA 625 Analysis Description: 625 MSS Associated Lab Samples: 92273535001, 92273535002, 92273535003, 92273535004, 92273535005 METHOD BLANK: 1595072 Matrix: Water Associated Lab Samples: 92273535001, 92273535002, 92273535003, 92273535004, 92273535005 Blank Reporting Parameter Units Result Limit Analyzed 1,2,4-Trichlorobenzene mglL ND 0.0050 10/3011522:45 1,2-Dichlorobenzene mglL ND 0.0050 1013011522:45 1,2-Diphenylhydrazine mglL ND 0.0050 10130/1522:45 1,3-Dichlorobenzene mglL ND 0.0050 10/3011522;45 1,4-Dichlorobenzene mg1L ND 0.0050 10/30/15 22:45 2,4,6-Trichlorophenol mg1L ND 0.010 10/30/15 22:45 2,4-Dichlorophenol mg1L ND 0.0050 10/30/15 22:45 2,4-Dimethylphenol mg1L ND 0.010 10/30/15 22:45 2,4-Dinitrophenol mg1L ND 0.050 10/30/15 22:45 2,4-Dinitrotoluene mg1L ND 0.0050 10/30/15 22:45 2,6-Dinitrotoluene mg1L ND 0.0050 10/30/15 22:45 2-Chloronaphthalene mg1L ND 0,0050 10/30/15 22:45 2-Chlorophenol mg1L ND 0.0050 10/30/15 22:45 2-Nitrophenol mglL ND 0.0050 10/30/15 22:45 3,3'-Dichlorobenzidine mglL ND 0.025 10/30/15 22:45 4,6-Dinitro-2-methylphenol mg1L ND 0.020 10/30/15 22:45 4-Bromophenylphenyl ether mg1L ND 0.0050 10/30/15 22:45 4-Chloro-3-methylphenol mg1L ND 0,0050 10/30/15 22:45 4-Chlorophenylphenyl ether mg1L ND 0.0050 10/30/15 22:45 4-Nitrophenol mg1L ND 0.050 10/30/15 22:45 Acenaphthene mg1L ND 0.0050 10/30/15 22:45 Acenaphthylene mg1L ND 0.0050 10/30/15 22:45 Acetophenone mg1L ND 0.0050 10/30/15 22:45 Aniline mglL ND 0.010 10/30/15 22:45 Anthracerie mg1L ND 0.0050 10/30/15 22:45 Benzidine mg1L ND 0,050 10/30/15 22:45 Benzo(a)anthracene mglL ND 0.0050 10/30/15 22:45 Benzo(a)pyrene mg/L ND 0.0050 10/30/15 22:45 Benzo(b)ftuoranthene mg1L ND 0.0050 10/30/15 22:45 Benzo(g,h,i)perylene mglL ND 0.0050 10/30/15 22:45 Benzo(k)fluoranthene mg1L ND 0.0050 10/30/15 22:45 bis(2-Chloroethoxy)methane mg1L ND 0.010 10/30/15 22:45 bis(2-Chloroethyl) ether mglL ND 0.0050 10/30/15 22:45 bis(2-Chloroisopropyl) ether mglL ND 0.0050 10/30/15 22:45 bis(2-Ethyl hexyl)phthal ate mglL ND 0.0050 10/30/15 22:45 Butylbenzylphthalate mg1L ND 0.0050 10/30/15 22:45 Chrysene mg1L ND 0.0050 10/30/15 22:45 Di-n-butylphthalate mg1L ND 0.0050 10/30/15 22:45 Di-n-octylphthalate mg1L ND 0.0050 10/30/15 22:45 Dibenz(a,h)anth racene mg1L ND 0.0050 10/30/15 22:45 Diethylphthalate mglL ND 0.0050 10/30/15 22:45 Qualifiers Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Results presented on this page are in the units Indicated by the" Units" column except where an alternate unit is presented to the right of the resurf. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/09/2015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 40 of 50 aceAnalytrcal www.pecela1mcam QUALITY CONTROL DATA Project: Storm water Testing Pace Project No.: 92273535 METHOD BLANK: 1595072 Matrix: Water Associated Lab Samples: 92273535001, 92273535002, 92273535003, 92273535004, 92273535005 Blank Reporting Parameter Units Result Limit Analyzed Dimethylphthalate mglL ND 0.0050 10/30/15 22:45 Fluoranthene mg1L ND 0.0050 10/30/15 22:45 Fluorene mglL ND 0.0050 10/30/15 22:45 Hexachloro-1,3-butadiene mglL ND 0.0050 10130/15 22:45 Hexachlorobenzene mglL ND 0.0050 10/30/15 22:45 Hexachlorocyclopentad iene mglL ND 0.010 10/30/15 22:45 Hexachloroethane mglL ND 0.0050 10/30/15 22:45 Indeno(1,2,3-cd)pyrene mg1L ND 0,0050 10130/15 22:45 Isophorone mglL ND 0.010 10/30/15 22:45 N-Nitroso-di-n-propylamine mglL NO 0.0050 10/30/15 22:45 N-Nitrosodimethylamine mglL ND 0,0050 10/30/15 22:45 N-Nitrosodiphenylamine mg/L ND 0,010 10/30/15 22:45 Naphthalene mg1L ND 0.0050 10/30/15 22:45 Nitrobenzene mg1L ND 0,0050 10/30115 22:45 Pentachlorophenol mg1L ND 0.010 10/30/15 22:45 Phenanthrene mg1L ND 0.0050 10/30115 22:45 Phenol mglL ND 0.0050 10/30/15 22:45 Pyrene mg1L ND 0.0050 10/30/15 22:45 2,4,6-Tribromophenol (S) % 82 10-137 10/30/15 22:45 2-Fluorobiphenyl (S) % 64 15-120 10/30/15 22:45 2-Fluorophenol (S) % 35 10-120 10/30/15 22:45 Nitrobenzene-d5 (S) % 58 10-120 10/30/15 22:45 Phenol-d6 (S) % 21 10-120 10/30/15 22:45 Terphenyl-d14 (S) % 76 11-131 10/30/15 22:45 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1595073 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,2,4-Trichlorobenzene mg1L .05 0.035 71 44-142 1,2-Dichlorobenzene mg1L .05 0.031 63 32-129 1,2-Diphenylhydrazine mg1L .05 0.033 66 25-150 1,3-Dichlorobenzene mg1L .05 0.031 62 1-172 1,4-Dichlorobenzene mg1L .05 0.031 62 20-124 2,4,6-Trichlorophenol mg1L .05 0.044 88 37-144 2,4-Dichlorophenol mglL .05 0.037 73 1-191 2,4-Dimethylphenol mg1L .05 0.035 71 32-119 2,4-Dinitrophenoi mg1L .25 .033J 13 1-181 2,4-Dinitrotoluene mglL .05 0.041 81 39-139 2,6-Dinitrotoluene mg1L .05 0.040 80 50-158 2-Chloronaphthalene mglL .05 0.040 81 60-118 2-Chtorophenol mg1L .05 0.031 62 23-134 2-Nitrophenol mg1L .05 0.035 69 29-182 3,3'-Dichlorobenzidine mg1L .1 0.072 72 1-262 4,6-Dinitro-2-methylphenol mg1L .1 0.026 26 1-181 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Qualifiers Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/09/2015 08:46 AM without the written consent of Pace Analytical Services, Inc- Page 41 of 50 6 acmnalytical wwwptrcwacom QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92273535 Pace Analytical Services, inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 LABORATORY CONTROL SAMPLE: Parameter 1595073 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 4-Bromophenylphenyl ether mg1L .05 0,039 78 53-127 4-Chloro-3-methylphenol mg/L .1 0.068 68 22-147 4-Chlorophenylphenyl ether mg1L .05 0.040 80 25-158 4-Nitrophenol mg/L .25 0,082 33 1-132 Acenaphthene mg/L .05 0.040 79 47-145 Acenaphthylene mg1L .05 0.042 85 33-145 Acetophenone mg1L .1 0.030 30 25-150 Aniline mg/L .05 0.022 44 25-150 Anthracene mg/L .05 0,043 85 1-166 Benzidine mg/L .1 .00611 6 25-150 LO Benzo(a)anthracene mg/L .05 0.044 87 33-143 Benzo(a)pyrene mg/L .05 0.038 77 17-163 Benzo(b)fluoranthene mg/L .05 0.041 81 24-159 Benzo(g,h,i)perylene mglL .05 0.036 71 1-219 Benzo(k)fluoranthene mg1L .05 0.046 93 11-162 bis(2-Chloroethoxy)methane mg/L .05 0.032 65 33-184 bis(2-Chloroethyl) ether mg1L .05 0.033 67 12-158 bis(2-Chloroisopropyl) ether mg/L .05 0.021 42 36-166 bis(2-Ethylhexyl)phthalate mg/L .05 0.043 86 8-158 Butylbenzylphthalate mg/L .05 0,044 87 1-152 Chrysene mg/L .05 0.042 85 17-168 Di-n-butylphthalate mg/L .05 0.043 85 1-118 Di-n-octylphthalate mg/L .05 0,045 90 4-146 Dibenz(a,h)anthracene mg/L .05 0.036 71 1-227 Diethylphthatate mg/L .05 0.042 84 1-114 Dimethylphthalate mg/L .05 0.042 83 1-112 Fluoranthene mg/L .05 0.044 89 26-137 Fluorene mg/L .05 0.044 88 59-121 Hexachloro-1,3-butadiene mg/L .05 0.035 71 24-116 Hexachlorobenzene mg/L .05 0.045 90 1-152 Hexachlorocyclopentadiene mg/L .05 0,028 57 25-150 Hexachloroethane mg/L .05 0.032 64 40-113 Indeno(1,2,3-cd)pyrene mg1L .05 0.036 73 1-171 Isophorone mg/L .05 0.032 65 21-196 N-Nitroso-di-n-propylamine mg/L .05 0.028 56 1-230 N-N itrosod imethyla mine mg1L .05 0.020 39 25-150 N-N itrosod iphenyla mine mg1L .05 0.037 74 25-150 Naphthalene mg/L .05 0.035 70 21-133 Nitrobenzene mg/L .05 0.034 68 35-180 Pentachlorophenol mg1L .1 0.062 62 14-176 Phenanthrene mg/L .05 0.040 80 54-120 Phenol mg/L .05 0.015 29 5-112 Pyrene mg1L .05 0.041 83 52-115 2,4,6-Tribromophenol (S) % 92 10-137 2-Fluorobiphenyl (S) % 81 15-120 2-Fluorophenol (S) % 37 10-120 Nitrobenzene-d5 (S) % 70 10-120 Results presented on this page are in the units Indicated by the "Units- column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /09/2015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 42 of 50 aceAnalyflcal e tvww pacelabs-mm QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92273535 Pace Analytical Services, Inc. 205 East Meadow Road - Suite Eden, NC 27288 (336)623-8921 LABORATORY CONTROL SAMPLE: 1595073 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phenol-d6 (S) % 24 10-120 Terphenyl-d14 (S) % 77 11-131 MATRIX SPIKE SAMPLE: Parameter 1595074 Units 92273801001 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,2,4-Trichiorobenzene mg/L ND .05 0.017 35 44-142 M1 1,2-Dichlorobenzene mg1L ND .05 0,018 36 32-129 1,2-Diphenylhydrazine mg/L ND .05 0.030 60 25-150 1,3-Dichlorobenzene mglL ND .05 0.018 35 1-172 1,4-Dichlorobenzene mg/L ND .05 0,018 36 20-124 2,4,6-Trichlorophenol mg/L ND .05 0.032 65 37-144 2,4-Dichlorophenol mglL ND .05 0.018 36 1-191 2,4-Dimethylphenol mg/L ND .05 0.017 34 32-119 2,4-Dinitrophenol mg/L ND .25 .047J 19 1-181 2,4-Dinitrotoluene mglL ND .05 0.041 81 39-139 2,6-Dinitrotoluene mg/L ND .05 0.037 74 50-158 2-Chloronaphthalene mg/L ND .05 0.022 45 60-118 M1 2-Chlorophenol mglL ND .05 0.015 30 23-134 2-Nitrophenol mg/L ND .05 0.016 32 29-182 3,3'-Dichlorobenzidine mg/L ND .1 0.078 78 1-262 4,6-Dinitro-2-methylphenol mg1L ND .1 0.044 44 1-181 4-Bromophenylphenyl ether mg/L ND .05 0.033 65 53-127 4-Chloro-3-methylphenol mglL ND .1 0.066 66 22-147 4-Chlorophenylphenyl ether mg/L ND .05 0,034 67 25-158 4-Nitrophenol mg/L ND .25 0.086 35 1-132 Acenaphthene mglL ND .05 0.027 55 47-145 Acenaphthylene mg/L ND .05 0.029 57 33-145 Acetophenone mg/L ND .1 0.016 16 25-150 M1 Aniline mglL ND .05 0.014 29 25-150 Anthracene mg/L ND .05 0.039 78 1-166 Benzidine mglL ND .1 .025J 25 25-150 Benzo(a)anthracene mg/L ND .05 0.043 87 33-143 Benzo(a)pyrene mg/L ND .05 0.036 72 17-163 Benzo(b)fluoranthene mglL ND .05 0.037 74 24-159 Benzo(g,hJ)perylene mg/L ND .05 0.036 71 1-219 Benzo(k)fluoranthene mg1L ND .05 0,043 86 11-162 bis(2-Chloroethoxy)methane mg/L ND .05 0.015 29 33-184 M1 bis(2-Chloroethyl) ether mg/L ND .05 0.016 32 12-158 bis(2-Chloroisopropyl) ether mglL ND .05 0.010 21 36-166 M1 bis(2-Ethylhexyl)phthalate mg/L ND .05 0,041 82 8-158 Butylbenzylphthalate mglL ND .05 0.040 80 1-152 Chrysene mg/L ND .05 0.041 83 17-168 Di-n-butylphthalate mg/L ND .05 0.039 78 1-118 Di-n-octylphthalate mg1L ND .05 0.042 84 4-146 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result, REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in f4. Date: 11109I2015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 43 of 50 aceAnalytical www.pac0ab&c= QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92273535 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 MATRIX SPIKE SAMPLE: Parameter 1595074 Units 92273801001 Result Spike Conc. MS Result M5 % Rec % Rec Limits Qualifiers Dibenz(a,h)anthracene mg1L NO .05 0.037 74 1-227 Diethyl phthalate mg1L NO .05 0.042 84 1-114 Dimethylphthalate mg1L ND .05 0.039 78 1-112 Fluoranthene mg1L ND .05 0,044 89 26-137 Fluorene mg/L NO '05 0.038 76 59-121 Hexachloro-1,3-butadiene mg/L NO .05 0.017 33 24-116 Hexachlorobenzene mg/L ND .05 0,038 76 1-152 Hexachlorocyclopentadiene mg/L ND '05 0.012 23 25-150 M1 Hexachloroethane mg/L NO .05 0.017 34 40-113 M1 Indeno(1,2,3-cd)pyrene mg/L NO .05 0.037 75 1-171 Isophorone mg/L NO .05 0.016 32 21-196 N- Nitroso-di-n-propyla mine mg/L NO .05 0.014 29 1-230 N-Nitrosodimethylamine mg/L NO .05 0.0094 19 25-150 Mi N-Nitrosodiphenylamine mg1L ND .05 0.033 66 25-150 Naphthalene mg/L NO .05 0.017 34 21-133 Nitrobenzene mg/L NO .05 0.016 32 35-180 M1 Pentachlorophenol mg/L NO .1 0.070 70 14-176 Phenanthrene mg1L NO .05 0,038 77 54-120 Phenol mg1L ND .05 .0041J 8 5-112 Pyrene mg1L NO .05 0.038 76 52-115 2,4,6-Tribromophenol (S) % 80 10-137 2-Fluorobiphenyl (S) % 43 15-120 2-Fluorophenol(S) % 17 10-120 Nitrobenzene-d5 (S) % 31 10-120 Phenol-d6 (S) % 11 10-120 Terphenyl-d14 (S) % 68 11-131 SAMPLE DUPLICATE: 1595076 92273784001 Dup Parameter Units Result Result RPD Qualifiers 12,4-Trichlorobenzene mg/L ND NO 1,2-Dichlorobenzene mg/L ND NO 1,2-Diphenylhydrazine mg/L ND ND 1,3-Dichlorobenzene mg/L ND ND 1,4-Dichlorobenzene mg/L ND ND 2,4,6-Trichlorophenol mg/L NO NO 2,4-Dichlorophenol mg1L NO N❑ 2,4-Dimethylphenol mg/L NO ND 2,4-Dinitrophenol mg/L NO NO 2,4-Dinitrotoluene mg/L ND NO 2,6-Dinitrotoluene mg/L ND NO 2-Chloronaphthalene mg1L NO ND 2-Chlorophenol mg/L ND NO 2-Nitrophenol mg/L ND NO 3,3'-Dichlorobenzidine mg1L ND NO Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/09/2015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 44 of 50 laneAnayicalo www.pecdabs.c= QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92273535 SAMPLE DUPLICATE: 1595076 Parameter Units 92273784001 Result Dup Result 4,6-Dinitro-2-methylphenol mg/L ND ND 4-Bromophenylphenyl ether mg/L ND ND 4-Chloro-3-methylphenol mg/L ND ND 4-Chlorophenylphenyl ether mg/L ND . ND 4-Nitrophenol mg/L ND ND Acenaphthene mg/L ND ND Acenaphthylene mg/L ND ND Acetophenone mg/L ND ND Aniline mg1L ND ND Anthracene mg1L ND ND Benzidine mg/L ND ND Benzo(a)anthrace ne mg1L ND ND Benzo(a)pyrene m91L ND ND Benzo(b)fluoranthene mg1L ND ND Benzo(g,h,i)perylene mg1L ND ND Benzo(k)fluoranthene mg1L ND ND bis(2-Chloroethoxy)methane mg1L ND ND bis(2-Chloroethyl) ether mg]L ND ND bis(2-Chloroisopropyl) ether mg1L ND ND bis(2-Ethylhexyl)phthalate mg1L ND ND Butylbenzylphthalate mg/L ND ND Chrysene mg/L ND ND Di-n-butylphthalate mg/L ND ND Di-n-octylphthalate mgfL ND ND Dibenz(a, h)a nth racene mg1L ND ND Diethylphtha late mg/L ND ND Dimethylphthalate mg1L ND ND Fluoranthene mg/L ND ND Fluorene mg/L ND ND Hexachloro-1,3-butadiene mg1L ND ND Hexachlorobenzene mg/L ND ND Hexachlorocyclopentadiene mg/L ND ND Hexachloroethane mg]L ND ND Indeno(1,2,3-cd)pyrene mg/L ND ND Isophorone mg1L ND ND N-Nitroso-di-n-propylamine mg1L ND ND N-Nitrosodimethylamine mg/L ND ND N-Nitrosodiphenylamine mg1L ND ND Naphthalene mg1L ND ND Nitrobenzene mg/L ND ND Pentachlorophenol mg/L ND ND Phenanthrene mg1L ND ND Phenol mg1L ND ND Pyrene mg/L ND ND 2,4,6-Tribromophenol (S) % 68 87 2-Fluorobiphenyl (S) % 31 72 2•Fluorophenol (S) % 15 30 RPD Qualifiers 24 78 69 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/09/2015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 45 of 50 (�IaceAnalytical wwwpscelahs.com QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92273535 SAMPLE DUPLICATE: 1595076 92273784001 Dup Parameter Units Result Result RPD Qualifiers Nitrobenzene-d5 (S) % 27 59 75 Phenol-d6 (S) % 9 22 81 Terphenyl-d14 (S) % 62 78 23 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/09/2015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 46 of 50 Pace Analytical Services, Inc. (� Iacmnalyticalo 205 East MeadowdRoad n, NC 27288 www,> (336)623-8921 QUALIFIERS Project: Storm Water Testing Pace Project No.: 92273535 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL- Practical Quantitation Limit. RL- Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services -Asheville PASI-C Pace Analytical Services - Charlotte PASI-E Pace Analytical Services - Eden ANALYTE QUALIFIERS HIS Analysis initiated outside of the 15 minute EPArecommended holding time. Lo Analyte recovery in the laboratory control sample (LCS) was outside QC limits. L2 Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this anatyte in associated samples may be biased low. L3 Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in associated samples. Results unaffected by high bias. Mo Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M3 Matrix spike recovery was outside laboratory control limits due to matrix interferences. So Surrogate recovery outside laboratory control limits. c2 Acid preservation may not be appropriate for the analysis of 2-Chloroethylvinyl ether. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/09/2015 08:46 AM without the written consent of Pace Analytical Services, Inc.. Page 47 of 50 (�5a'&Mnayical" QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Storm Water Testing Pace Project No.: 92273535 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 2728E (336)623-8921 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92273535001 SDO #6 SM 2540D EDEN120516 92273535002 SDO #7 SM 2540D EDEN120516 92273535003 SDO #8 SM 2540D EDEN/20516 92273535004 SDO #11 SM 2540D EDEN120516 92273535005 SDO #12 SM 2540D EDEN120516 92273535001 SDO #6 SM 4500-H+B EDEN120513 92273635002 SDO #7 SM 4500-H+B EDEN120513 92273535003 SDO #8 SM 4500-H+B EDEN120513 92273535004 SDO #11 SM 4500-H+B EDEN120513 92273535005 SDO #12 SM 4500-H+B EDEN/20513 92273535006 FALLING SAMPLE SM 4500-H+B EDEN120513 92273535001 SDO 96 EPA 1664B GCSV123115 92273535002 SDO #7 EPA 1664B GCSVJ23115 92273535003 SDO #8 EPA 1664B GCSV/23115 92273635004 SDO #11 EPA 1664B GCSV/23115 92273535005 SDO #12 EPA 1664B GCSV123115 92273535001 SDO #6 EPA 3510 OEXT138712 EPA 608 92273535002 SDO #7 EPA 3510 0EXT138712 EPA 608 92273535003 SDO #8 EPA 3510 0EXT138712 EPA 608 92273535004 SDO #11 EPA 3510 OEXT/38712 EPA 608 92273535005 SDO #12 EPA 3510 0EXT/38712 EPA 608 92273535001 SDO #6 EPA 200.7 MPRP119932 EPA 200.7 92273535002 SDO #7 EPA 200.7 MPRP/19933 EPA 200.7 92273535003 SDO #8 EPA 200.7 MPRP119933 EPA 200.7 92273535004 SDO #11 EPA 2007 MPRP119933 EPA 2007 92273635005 SDO #12 EPA 200.7 MPRP119933 EPA 200.7 92273535001 SDO #6 EPA625 0EXT138721 EPA625 92273535002 SDO #7 EPA625 OEXT138721 EPA 625 92273535003 SDO#8 EPA625 OEXT138721 EPA625 92273535004 SDO#11 EPA625 0EXT138721 EPA625 92273535005 SD0#12 EPA625 OEXT138721 EPA625 92273535001 SDO#6 EPA624 MSV134091 92273535002 SDO#7 EPA624 MSV134091 92273535003 SDO#8 EPA624 MSV134091 92273535004 SDO#11 EPA624 MSV134091 92273535005 SDO#12 EPA624 MSV134091 Date: 11/09/2015 08:46 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Batch GCSV/23074 GCSV/23074 GCSV/23074 GCSV/23074 GCSV/23074 ICP117976 ICP117975 ICP117975 ICP117975 ICP117975 M SSVI11456 MSSV/11456 MSSV/ 11456 MSSV111456 M SSV111456 Page 48 of 50 aceAnalytical- CHAIN-OF-CUSTODY 1 Analytical Request Document C) The Chain -of -Custody Is a LEGAL DOCUMENT. All relevant fields must be completed accurately. o rn • ww....,.......,.x,,, Page: of m Sectlan A Section IS Section C a Required Cfienl Informatom Required Project Informatiom Invalce information: Company,,- Report To: Attention. 1942867 41r4,�1 M, �h,,, TJ1oyn s o.J b e Address: 5..IVL Copy To: =- Company Name: - REGULA70RY AG_ ENCY`,, 5 Stii�ec Of e r Address: I NPDES 'r GROUND WATER f DRINKING WATER j UST F RCRA C— OTHER Email To: _ Purchase Order No.: Pace Quote Reference: Phone: 7•cpon7 Fax- 6 6.27'dfsGr Project Name: `.$ �Pr+IJA Pose Project Manager:. -- Site Location t: Requested Due Date(TAT: Project Number: Pace Profile rk 14 t' Requested Analysis Filtuii)d (YIN)" :r r, Section Matrix Codes Required Gent lnimmallon MATRIX r CODE "� COLLECTED (y PmServative$ ,z Drinking Water DW Water WT O - Waste Water WW Product P SoIYSold - SL 3 m t' corre Art7 START cCMppBI ENOVGIL4B LU i j p CO • �.,r. _ /� �' L+. r JI SAMPLE ID QII oL cc .. PD Wpo WP (A-z, o-g r,-) Air AR Sample IDS MUST BE UNIQUE Tissue TS W O M a a 2 w z F w 2 m r �-ta E Q U Other OT U� ?G W Z rN 75 cc n, O 9 y O `- Q m` p ~ C N Z = 2 Z Z 2 � y W PaCO Pro•ect No./ Lab I.D. DATE TIME DATE TIME ;µ ,s b �� �y•d° G roe z s o 6 S 1 G a •a�• 15' �Y >- y _ AID 'F10 Id '] 16 ,B; a •�� IY•�°` G M�J7•r3 'i;, S D d A 13 No F/o L) e A H SSA iL C7 au ' °" ai yS1�'pDDITIONAI.'COMMENTSayyr"� i"y ,_ `�i i J ;RELINQUISHED BYIAFFII:IATION ` yy,r-_, #'�Y-iDATE`%s,:_E� %F. TIMEr F -` - ACC$PTED6YlAFFILIATION'. TIMEi�; SAMPLE CONDITIONS `.1 -� - •.L _•s4.��:%-.1�: -^': ff'.. - n�H:.Y.l: iy F ek-.. _tt? I..aY.cx-i.e1s.�a.i,. -�4FA4 I'i�: DP IS /57r 1.1AA ,SAMPLER NAME AND SIGNATU1tE�'��,�;�N�,� �� __,,F����N�,.�`_�.{_,�G �'�ti`�-'?���,.i�. gti'-• o m � . ORIGINAL c � ,, $ c �^ PRINT Name of SAMPLER. rn a� e a z. SIGNATURE of SAMPLER: //�� r�]] �/ /1 ' b l s ~ {MNUDDlYY)a tj -•Oc l /` .Important Note: By signing Mks form you are accepting Paw's NEY 3a day payrr nt terms end a7wkV to late etiaMas of 1-5% per month ror any MWms not paid Ml h4, 30 days. F-ALL-0-020rev.07, 15-May-2007 Document Name;,,Samoo 1; tndttlon Upon Document Revised: May 15, 2015 aCl;alirl' Recei t (SCUR)' Page 1 of 2' Document No.. Issuing Authorities: F-EDN-CS-003-rev.4 4 .. : - Pace Eden Quality Office *Page 2 of 21s"for Intemaf Llse Only Client Name! r (11,z/- Courier (circle): Fed Ex UPS U$PS CEient Commercial mace Other �- Custody Seal on Cooler/Box Present: ❑yes no Seals intact" ❑ �,❑ no Packing Maltedal: bubble Wrap Drubble Bags ❑ None Other Thermometer used: IR Gun ED007 Tune of Ine: -/Wet J ahia Nona i 1-1 samnles on Ica: cooling nrocass has begun TempCo : f ~J traction Factor. Add / ubtract C Rate and Initfao,of person examining 'nts " �coii rase ,tioa _ Corrected CoolerTeirtp.•" C Biological Tissue is Frozen: Yes':iVo. WA; . '. check ,. Temp should be abomfreazing to VC .. :. :. ...: ;. ,Comments:" _ ,.....: Chaln of'Custogy Present ram: CINq ., Qt�A 1.....":;.:_ . _ ..::.... .: . . .. . .... .:. _:.. . , Chain of Custody Filled Out s;.❑No ..E]NIA 2.. ' Chain of Custody Relin ulshed: es. EINa ,: 3WA. 3-.1,... Sampler Name & Signature on.COC:.. �s ©Nu ©wq 4.:.... ;..- Samp les Arrived within Hold Time: .. ❑(; EiNo : OWA 6.:...., .: . Short Ffolt1 Tirne' Ana is (<72hr): Cives. o " ON/A 6.1. , . .. ,. Rush Turn Around Time Re nested: � ,. ,C7Yes. Na :.13NG4 7...... 86frrclent Volurrie:" es' ,l�No :Own 8. Correct Containers Used:, - es ❑No -.. Clji A 9,, .. > . -Pace.Contalners Used. ❑No:.©nuA . ',. "......... ✓/ee' Containers Intact: t!lYes: CINo OnitA 1.0 , _ Filtered volume'recel �e for Dlsso'ved tests e9 ©No " WA 11: Sample labels match COO: Zrye,s ©No ❑NrA 12. -Includes datamefID/Anal [s Matrix All containers needing preservation have been checked. DYes ❑NO jtriNlA ,. 13. All containers needing preservation are found to be In ❑Yes ONO" �N/A . -. compliance with EPA recommendation. VOA, e0f3farm0OC, O&G, Wt-DRO ❑Yes ❑No Sam le§ checked for dechlodnailon: Dyes 13No 6: 14 . Heads ace In VOA Vials. >6mm :. ' .:" es ONo ❑NIA 15. Trip Blank Present - pyes PfNo ONA 16. Trip Blank Custody Seals .Present Dyes , BNo. Ot*A Pace Trip "Blank Lot #(qpurchased), Client Notification/ Resolution: Field Data Required? Y ! N " Person Contacted: Date/Time: Comments! Resolution: " Place label here SCURF 1 SRF late: Review: 013 Note: Whenever there Is a discrepancy affecting North Carolina compliance samples, a copy of this form wlif be sent to the North Carofna DEHNR Certification Office ( Le. out of hold, Incorrect preservative, out of temp,-. Handwrite project number. Incorrect containers) (if no label available) Page 50 of 50 Permit Number: NCS Certificate of Coverage Number: NCG030548 STORMWATER DISCHARGE OUTFALL (SDO) MONITORING REPORT' or SAMPLES COLLECTED DURING CALENDAR YEAR: 2015 (This monitoring report shall be received by the Division no later than 30 days from RECEI Q t'the facility receives the sampling results from,the laboratory.) wn� FACILITY NAME: Weil -McLain SEi j g . 15 COUNTY Rockingham r PERSON COLLECTING SAMPLE(S): Paul Smith & Mike Moretz PHONE NO. (336) 627-6024 CERTIFIED LABORATORY(S): Pace Analytical Services Inc., Lab # St PRAEOP- Lab # D_�AIR SECTION �7 SIGNATURE OF PERMITTEE OR DESIGNEE REQUIRED ON PAGE 2. �D Part A: Specific Monitoring Requirements .� I Outfall No. Date Sam Collected, Zdd/yr 00530 00400 01051 00556 78141 Total Suspended Solids, mg/L pH, Standard Units Total Lead, mg/l., Total Copper, mg/L Total Zinc, mg/L Oil and Grease, mg/L Total Toxic Organics, mg/L Benchmark 100 Within 6.0-9.0 0.030 0.007 0.067 15 1 SDO #6 6/27/15 8.6 5.3 <0,005 <0.005 0.020 <5.0 <0.05 SDO #7 6/27/15 20.3 5.6 <0.005 0.010 0.096 <5.0 <0.05 SDO #8 6/27/15 6.0 5.6 <0.005 0.0085 0.046 <5.0 <0.05 SDO #9 No Flow No Flow No Flow No Flow No Flow No Flow No Flow No Flow SDO #10 No Flow No Flow No Flow No Flow No Flow No Flow No Flow No Flow SDO #11 6/27/15 28.5 11.6 <0.005 0.091 0.022 <5.0 0.047 SDO #12 6/27/15 7.8 6.3 <0.005 0.018 0.042 <5.0 0.031 SDO #13 6/27/15 13.7 6.4 <0.005 0.020 0.036 <5.0 0.024 Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier i or Tier2 responses. See General Permit text. Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _yes _X_no (if yes, complete Part B) Page l of 2 Part B: Vehicle Maintenance Activity Monitoring Requirements Outfall No. Date Sample Collected, molddl r 00556 00530 00400 Oil and Grease, m /L Total Suspended Solids pH, Standard units New Motor Oil Usage, Annual average al/mo - 30 m Il Within 6.0-9.0 - N/A Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier 1 or Tier2 responses. See General Permit text. STORM EVENT CHARACTERISTICS: Date: 6/27/15 Total Event Precipitation (inches): D.54" Mail Original and one copy to: Division of Water Quality Attn: Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." � quo-15 (Signature of Permittee) (Date) w. Page 2 of 2 Street WEILmMiLAIN' 523 Eden,, Neva NC 27288 Eden, R 336-627-6000 F:336-627-6065 September 10, 2015 Central Files Division of Water Quality 1617 Mail Service Center Raleigh, NC 27699-1617 RE: Explanation of Stormwater Monitoring Report Dear Sir or Madam: In accordance with NPDES (NCG030000) Stormwater Permit Condition Part It Section B, the first of two semi—annual sampling events has been completed and is attached. Monitoring was conducted for Stormwater discharge outfalls 6-13 (SDO) as identified in the SWPPP, with "NO FLOW" being reported for two of the outfalls. The DMR, Storm data (local onsite readings), and analytical data is attached. As indicated in the enclosed Stormwater Monitoring Report, there were six that were outside the benchmarks. Tier One actions have been implemented, and the SWPPP has been updated to include the following: • Additional inspection with detailed observation of outfalls. • Investigation and root cause analysis. • Re -sampling of outfalls during next qualifying rain event. The total rainfall recorded under Part A of the Stormwater Discharge Outfall (SDO) Monitoring Report is listed as 0.54" which occurred within the first 30 minutes of discharge. If you have any questions regarding the enclosed reports, please contact Michael Thomason at (336)627- 6024. Sincerely, Eric Chack Vice President of Operations Weil -McLain STORMWATER DISCHARGE OUTFALL (SDO) MONITORING REPORT Permit Number: NCS or Certificate of Coverage Number: NCG030548 FACILITY NAME Weil -McLain PERSON COLLECTING SAMPLE(S) Paul Smith & Rick Mebane CERTIFIED LABORATORY(S) Pace Analytical Services Inc. Lab #633 Lab # Part A: Specific Monitoring Requirements SAMPLES COLLECTED DURING CALENDAR YEAR: 2014 (This monitoring report shall be received by the Division no later than 30 days from the date the facility receives the sampling results from the laboratory.) COUNTY Rockingham PHONE NO. (336) 627-6037 SIGNATURE OF PERMITTEE OR DESIGNEE Cz REQUIRED ON PAGE 2. C..* Outfall Date No. Sample Collected, (moldd/yr) Total Rainfall, inches pH, Standard Units Total Suspended Solids, mg/L Lead, mg/L Copper, mg/L Zinc, mg/L Non -Polar Oil and Grease, mg/L Total Toxic Organics, L mg/L Benchmarks 6.0-9.0 100 mg/L 0.030mg/L 0.007mg/L 0.067mg/L 15mg/L Img/L SDO #6 12/22/2014 0.11, 7.1 4.6 <0.005 <0.0083 <0.0480 <5,0 < (Reporting Limit) SDO #7 12/22/2014 0.1" NO FLOW NO FLOW NO FLOW NO FLOW NO FLOW NO FLOW NO FLOW SDO #8 12/22/2014 0.1" NO FLOW NO FLOW NO FLOW NO FLOW NO FLOW NO FLOW NO FLOW SDO #9 12/22/2014 0.1" NO FLOW NO FLOW NO FLOW NO FLOW NO FLOW NO FLOW NO FLOW SDO #10 12/22/2014 0.1" NO FLOW NO FLOW NO FLOW NO FLOW NO FLOW NO FLOW NO FLOW SDO #11 12/22/2014 0.1" 6.8 45.0 <0.005 0.0072 0.11 <5.0 < (Reporting Limit) SDO #12 12/22/2014 0.1" 6.0 4.3 <0.005 <0.0062 0.032 <5.0 < (Reporting Limit SDO #13 12/22/2014 0.1" NO FLOW NO FLOW 1 NO FLOW NO FLOW NO FLOW NO FLOW NO FLOW Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes X no (if yes, complete Pan 13) R `-+OVED AN 13 2015 Ann CENTR4L FILES DWR SECTION Form SWU-246, last revised 21212012 Page 1 of 2 Part B: Vehicle Maintenance Activity Monitoring Requirements Outfall No. Date Sample Collected 50050 00556 00530 00400 Total Flow (if applicable) Total Rainfall Oil & Grease (if appl.) Non -polar O&G/TPH (Method 1664 SGT-HEM), if a 1. Total Suspended Solids pH New Motor Oil_ Usage mo/dd/ r MG inches m l mg/1 Units al/mo STORM EVENT CHARACTERISTICS: Date 12/22/2014 Total Event Precipitation (inches): 0. V Event Duration (hours): (only if applicable — see permit.) (if more than one storm event was sampled) Date Total Event Precipitation (inches): Event Duration (hours): (only if applicable — see permit.) Mail Original and one copy to: Division of Water Quality Attn: Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. i am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." (Signature of Permittee) V, (s-- (Date) Form SWU-246,.1ast revised 212112012 Page 2 of 2 aceAnalytical" wwwpacelab C= January 05, 2015 Mr. Jim H Miller Weil McLain 523 S. New St. Eden, NC 27288 RE: Project: Storm Water 12/22/2014 Pace Project No.: 92230650 Dear Mr. Miller: Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Enclosed are the analytical results for sample(s) received by the laboratory on December 22, 2014. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Of, 6C 4 V Brittany Gibson for Terri Page terri.page@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pagel of 46 acmnalytkal *W.Pffealeftcarn Pace Analytical Services, Inc. 205 East Meadow Road - Suite Eden, NC27268 (336)623-8921 CERTIFICATIONS Project: Storm Water 12/22/2014 Pace Project No.: 92230650 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Florida/NELAP Certification #: E87627 North Carolina Drinking Water Certification #: 37706 Kentucky UST Certification #: 84 North Carolina Field Services Certification #: 5342 West Virginia Certification #: 357 North Carolina Wastewater Certification #: 12 VirginiafVELAP Certification #: 460221 South Carolina Certification #: 99006001 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 North Carolina Wastewater Certification #: 40 FloridalNELAP Certification #: E87648 South Carolina Certification #: 99030001 Massachusetts Certification #: M-NC030 West Virginia Certification #: 356 North Carolina Drinking Water Certification #: 37712 VirginiatVELAP Certification #: 460222 Eden Certification IDs 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Wastewater Certification #: 633 North Carolina Drinking Water Certification #: 37738 VirginiaNELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 46 • aceAnalytical" ~pecefebsc= SAMPLE ANALYTE COUNT Project: Storm Water 12/22/2014 Pace Project No.: 92230650 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92230650001 006 SM 2540D CHM 1 PASI-E SM 4500-H+B CHM 1 PASI-E EPA 1664B CLW 1 PASI-C EPA608 RES 27 PASI-C EPA200.7 JMW 3 PASI-A EPA625 RES 65 PASI-C EPA624 GAW 72 PASI-C 92230650002 011 SM 2540D CHM 1 PASI-E SM 4500-H+B CHM 1 PASI-E EPA 1664B CLW 1 PASI-C EPA608 RES 27 PASI-C EPA 200.7 JMW 3 PASI-A EPA625 RES 65 PASI-C EPA624 GAW 72 PASI-C 92230650003 012 SM 2540D CHM i PASI-E SM 4500-H+B CHM 1 PASI-E EPA 1664B CLW 1 PASI-C EPA608 RES 27 PASI-C EPA200.7 JMW 3 PASI-A EPA625 RES 65 PASI-C EPA624 GAW 72 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 46 lacmnalyficalo *%Wpecefeb&WM ANALYTICAL RESULTS Project: Storm Water 1212212014 Pace Project No.: 92230650 Pace Analytical Services, Inc. 2Q5 East Meadow Road - Suite A Eden, MC 27268 (336)623-6921 Sample: 006 Parameters Lab ID: 92230650001 Collected: 1212211410:40 Results Units Report Limit OF Received: 1212211413A9 Matrix: Water Prepared Analyzed CAS No. Qua] 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 4.6 mg/L 2.8 1 12/24/14 08:24 L2 4500H+ pH, Electrometric EDN Analytical Method: SM 4500-H+B pH at 25 Degrees C 7.1 Std. Units 1.0 1 12/23/14 09:55 H6 1664 SGT-HEM, TPH Analytical Method: EPA 1664E Total Petroleum Hydrocarbons NO mg1L 5.0 1 12/24/14 08:15 608 GCS Pesticides and PCBs Analytical Method: EPA 608 Preparation Method: EPA 3510 Aldrin NO mg/L 0A00050 1 12/29/14 17:45 01/01/15 21:46 309-00-2 alpha-BHC NO mg1L 0,000050 1 12/29/14 17:45 01/01/15 21:46 319-84-6 beta-BHC NO mg/L 0.000050 1 12/29/14 17:45 01/01/15 21:46 319-85-7 delta-BHC NO mg1L 0,000050 1 12/29/14 17:45 01/01/15 21:46 319-86-8 gamma-BHC (Lindane) NO mg1L 0.000050 1 12/29/14 17:45 01/01/15 21:46 58-89-9 Chlordane (Technical) NO mg1L 0.00050 1 12/29/14 17:45 01/01/15 21:46 57-74-9 4,4'-DO0 NO mg/L 0.000050 1 12/29/14 17:45 01/01/15 21:46 72-54-8 4,4'-DDE NO mg/L 0.000050 1 12/29/14 17:45 01/01/15 21:46 72-55-9 4A-DOT NO mg/L 0.000050 1 12/29/14 17:45 01/01/15 21:46 50-29-3 Dieldrin NO mglL 0.000050 1 1212911417:45 01101/1521:46 60-57-1 Endosulfan I NO mg1L 0.000050 1 12/29/14 17:45 01/01/15 21:46 959-98-8 Endosulfanll NO mg1L 0.000050 1 1212911417:45 01/0111521:46 33213-65-9 Endosulfan sulfate NO mglL 0.000050 1 12/29/14 17:45 01/01/15 21:46 1031-07-8 Endrin ND mglL 0.000050 1 12/29/14 17:45 01/01/15 21:46 72-20-8 Endrinaldehyde NO mg/L 0.000050 1 1212911417:45 01/01/15 21:46 7421-93-4 Heptachlor NO mg/L 0.000050 1 12129/1417:45 01/0111521:46 76-44-8 Heptachlor epoxide NO mg1L 0.000050 1 12/29/14 17:45 01 /01115 21:46 1024-57-3 PCB-1016 (Aroclor 10%) NO mg1L 0.00050 1 12/29/14 17:45 01/01/15 21:46 12674-11-2 PCB-1221 (Aroclor1221) NO mg1L 0.00050 1 1212911417:45 01/0111521:46 11104-28-2 PCB-1232 (Aroc]or 1232) NO mg1L 0.00050 1 12/29/14 17:45 01/01/15 21:46 11141-16-5 PCB-1242 (Aroclor 1242) NO mg1L 0.00050 1 12/29/14 17:45 01/01/15 21:46 53469-21-9 PCB-1248 (Aroclor 1248) NO mg/L 0,00050 1 12/29/14 17:45 01/01/15 21:46 12672-29-6 PCB-1254 (Aroclor 1254) NO mg/L 0.00050 1 12/29/14 17:45 01/01/15 21:46 11097-69-1 PCB-1260 (Aroclor 1260) NO mg/L 0.00050 1 12/29M4 17:45 01/01/15 21:46 11096-82-5 Toxaphene NO mg/L 0.00050 1 12/29/14 17:45 01/01/15 21:46 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 213 % 20-110 1 12/29/14 17A5 01/01/15 21:46 877-09-8 S5 Decachlorobiphenyl (S) 91 % 20-138 1 12/29/14 17A5 01/01/15 21:46 2051-24-3 200.7 MET IC Analytical Method: EPA 200.7 Preparation Method: EPA 2003 Copper 0.0083 mg1L 0.0050 1 12/24/14 11:25 12/29/14 14:09 7440-50-8 Lead ND mg/L 0.0050 1 12/24/14 11:25 12/29/14 14:09 7439-92-1 Zinc 0.048 mg/L 0.010 1 1212411411:25 12/29/14 14:09 7440-66-6 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 Acenaphthene ND mg1L 0.0050 1 12/29/14 14:12 01/01/15 07:14 83-32-9 Acenaphthylene ND mg1L 0.0050 1 12/29/14 14:12 01/01/15 07:14 208-96-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 4 of 46 aceAnalytical Ww.pecd8bxcem ANALYTICAL RESULTS Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: Storm Water 12/22/2014 Pace Project No.: 92230650 Sample: 006 Lab II): 92230650001 Collected: 12/22/14 10:40 Received: 12/22/14 13:19 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No, Qual 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 Acetophenone ND mg/L 0.0050 1 12/29/14 14A2 01/01/15 07A4 98-86-2 Aniline ND mg1L 0.010 1 12/29/14 14:12 01/01/15 07:14 62-53-3 Anthracene ND mg1L 0.0050 1 12/29/14 14:12 01/01/15 07:14 120-12-7 Benzidine ND mg1L 0.050 1 12129/14 1412 01/01115 0714 92-87-5 Benzo(a)anthracene ND mg/L 0,0050 1 12129/14 14:12 01/01/15 07:14 56-55-3 Benzo(a)pyrene ND mg1L 0.0050 1 12/29/14 14:12 01/01/15 07A4 50-32-8 Benzo(b)fluoranthene ND mg/L 0,0050 1 12/29/14 14:12 01/01/15 07:14 205-99-2 Benzo(g,h,i)perylene ND mg1L 0,0050 1 12/29114 14:12 01/01/15 07:14 191-24-2 Benzo(k)fluoranthene NO mg1L 0,0050 1 12/29/14 14:12 01/01/15 07:14 207-08-9 4-Bromophenylphenyl ether ND mg1L 0.0050 1 12/29/14 14:12 01/01/15 07:14 101-55-3 Butylbenzyiphthalate ND mg/L 0.0050 1 12/29/14 14:12 01/01/15 07:14 85-08-7 4-Chloro-3-methylphenol ND mg/L 0.0050 1 12/29/14 14:12 01/01/15 07;14 59-50-7 bis(2-Chloroethoxy)methane ND mg/L 0.010 1 12/29/14 14:12 01101/15 07:14 111-91-1 bis(2-Chloroethyl) ether ND na IL 0.0050 1 12/29/14 14:12 01/01/15 07:14 111-44-4 bis(2-Chloroisopropyl) ether ND mg/L 0.0050 1 12/29/14 14:12 01/01/15 07:14 108-60-1 2-Chloronaphthalene ND mg/L 0.0050 1 12/29/14 14:12 01/01/15 07:14 91-58-7 2-Chlorophenol ND mg/L 0.0050 1 12/29/14 14:12 01/01/15 07:14 95-57-8 4-Chlorophenylphenyl ether ND mg/L 0.0050 1 12/29/14 14:12 01/01/15 07:14 7005.72-3 Chrysene ND mg/L 0.0050 1 12/29/14 14:12 01/01/15 07:14 218-01-9 Dibenz(a,h)anthracene ND mg/L 0.0050 1 12/29/14 14:12 01/01/15 07:14 53-70-3 1,2-Dichlorobenzene ND mg/L 0.0050 1 12/29/14 14:12 01/0111507:14 95-50-1 1,3-Dichlorobenzene ND mg/L 0,0050 1 1212911414:12 01/0111507:14 541-73-1 1,4-Dichlorobenzene ND mg/L 0.0050 1 12/29/14 14:12 01/01/15 07:14 106-46-7 3,3'-Dichlorobenzidine ND mg/L 0.025 1 12/29/14 14:12 01/01/15 07:14 91-94-1 2,4-Dichlorophenol ND mg/L 0.0050 1 12/29/14 14:12 01/01/15 07:14 120-83-2 Diethylphthalate ND mg/L 0.0050 1 12/29/14 14:12 01/01/15 07:14 84-66-2 2,4-Dimethylphenol ND mg/L 0.010 1 12/29/14 14:12 01/01/15 07:14 105-67-9 Dimethylphtha late ND mg/L 0.0050 1 12129/1414:12 01/01/15 07:14 131-11-3 Di-n-butylphthalate ND mg/L 0.0050 1 1212911414:12 01/01/15 07:14 84-74-2 4,6- Din itro-2-methyl phenol ND mg/L 0.020 1 12/29/14 14:12 01/01/15 07:14 534-52-1 2,4-Dinitrophenol ND mg/L 0.050 1 12/29/14 14:12 01/01/15 07:14 51-28-5 2,4-Dinitrotoluene ND mg/L 0.0050 1 12129/1414:12 01/0111507:14 121-14-2 2,6-Dinitrotoluene ND mg/L 0.0050 1 1212911414:12 01101/1507:14 606-20-2 Di-n-octylphthalate ND mg/L 0.0050 1 12129/1414:12 01/0111507:14 117-84-0 1,2-Diphenylhydrazine ND mg/L 0.0050 1 12/29/14 14:12 0110111507:14 122-66-7 bis(2-Ethylhexyl)phthalate ND mg/L 0,0050 1 12/29/14 14:12 01/01/15 07:14 117-81-7 Fluoranthene ND mg/L 0.0050 1 12129/1414:12 01101/1507:14 206-44-0 Fluorene ND mg/L 0.0050 1 12129/1414:12 01/0111507:14 86-73-7 Hexachloro-1,3-butadiene ND mg/L 0.0050 1 12129/1414:12 01/01/15 07:14 87-68-3 Hexachlorobenzene ND mg/L 0.0050 1 12/29/14 14:12 01/01/15 07:14 118-74-1 Hexachlorocyclopentadiene ND mg/L 0.010 1 12/29/14 14:12 01/01/15 07:14 77-47-4 Hexachloroethane ND mg/L 0.0050 1 12/29/14 14:12 01/01/15 07:14 67-72-1 Indeno(1,2,3-cd)pyrene ND mg/L 0.0050 1 12/29/14 14:12 01/01/15 07:14 193-39-5 Isophorone ND mg/L 0.010 1 12/29/14 14:12 01/01/15 07:14 78-59-1 Naphthalene ND mg/L 0.0050 1 12/29/14 14:12 01/01/15 07:14 91-20-3 Nitrobenzene ND mg/L 0,0050 1 12/29/14 14:12 01/01/15 07:14 98-95-3 2-Nitrophenoi ND mg/L 0.0050 1 12/29/14 14:12 01/01/15 07:14 88-75-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 5 of 46 lacmnalytical wwwpacerabs.corrr ANALYTICAL RESULTS Pace Analytical Services, Inc, 205 East Meadow Road - Suite A Eden, NC+27268 (336)623-8921 Project: Storm Water 12/22/2014 Pace Project No.: 92230650 Sample: 006 Lab ID: 92230650001 Collected: 12/22/14 10:40 Received: 12122/14 13:19 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 4-Nitrophenol ND mg/L 0.050 1 12/29/14 14:12 01/01/16 07:14 100-02-7 N-Nitrosodimethylamine NO mg/L 0,0050 1 12/29/14 14:12 01/01/15 07:14 62-75-9 N-Nitroso-di-n-propylamine NO mg/L 0.0050 1 12/29/14 14:12 01101/1507:14 621-64-7 N-Nitrosodiphenylamine NO mg/L 0.010 1 12/29/14 14:12 01/01/15 07:14 86-30-6 Pentachlorophenol NO mg/L 0,010 1 12/29/14 14:12 01/01/15 07:14 87-86-5 Phenanthrene NO mg/L 0.0050 1 12/29/14 14:12 01/01/15 07:14 85-01-8 Phenol NO mg/L 0.0050 1 12/29/14 14:12 01/01/15 07:14 108-95-2 Pyrene NO mg/L 0.0050 1 12/29/14 14:12 01/01/15 07:14 129-00-C 1,2,4-Trichlorobenzene ND mg/L 0.0050 1 12/29/14 14:12 01/01/15 07:14 120-82-1 2,4,6-Trichlorophenol NO mg/L 0,010 1 12/29/14 14:12 01/01/15 07:14 88-06-2 Surrogates Nitrobenzene-d5 (S) 46 % 10-120 1 12/29/14 14:12 01/01/15 07:14 4165-60-0 2-Fluorobiphenyl (S) 41 % 15-120 1 12/29/14 14:12 01/01/15 07:14 321-60-8 Terphenyl-d14 (S) 79 % 11-131 1 12/29/14 14:12 01/01/15 07:14 1718-51-0 Phenol-d6 (S) 20 % 10-120 1 12/29/14 14:12 01/01/15 07:14 13127-88-3 2-Fluorophenol(S) 26 % 10-120 1 1212911414:12 01/0111507:14 367-12-4 2,4,6-Tribromophenol (S) 66 % 10-137 1 12/29/14 14:12 01/01/15 07:14 118-79-6 624 Volatile Organics Analytical Method: EPA624 Acetone NO mg1L 0.010 1 01/02/15 23:59 67-64-1 Acrolein NO mg1L 0.0050 1 01/02/15 23:59 107-02-8 Acrylonitrile NO mg1L 0.050 1 01/02/15 23:59 107-13-1 Benzene NO mg1L 0.0020 1 01/02/15 23:59 71-43-2 Bromobenzene NO mg1L 0.0020 1 01/02/15 23:59 108-86-1 Bromochloromethane NO mg/L 0,0020 1 01/02/15 23:59 74-97-5 Bromodichloromethane NO mg1L 0.0020 1 01/02/15 23:59 75-27-4 Bromoform NO mg1L 0.0020 1 01/02/15 23:59 75-25-2 Bromomethane NO mg1L 0.0020 1 01/02/15 23:59 74-83-9 2-Butanone (MEK) NO mg1L 0.0050 1 01/02/15 23:59 78-93-3 n-Butyibenzene NO mg1L 0.0050 1 01/02/15 23:59 104-51-8 sec-Butylbenzene NO mg/L 0.0050 1 01/02/15 23:59 135-98-8 tert-Butyl benzene ND mg1L 0.0050 1 01/02/15 23:59 98-06-6 Carbon disulfide NO mg1L 0.0050 1 01/02/15 23:59 75-15-0 Carbon tetrachloride NO mg1L 0.0020 1 01/02/15 23:59 56-23-5 Chlorobenzene NO mg/L 0.0020 1 01/02/15 23:59 108-90-7 Chloroethane NO mglL 0.0020 1 01/02/15 23:59 75-00-3 2-Chloroelhylvinyl ether NO mglL 0.0050 1 01/02/15 23:59 110-75-8 Chloroform ND mg1L 0.0020 1 01/02/15 23:59 67-66.3 Chloromethane NO mg/L 0,0020 1 01/02/15 23:59 74-87-3 2-Chlorotoluene NO mg/L 0.0020 1 01/02/15 23:59 95-49-8 4-Chlorotoluene NO mg/L 0.0020 1 01/02/15 23:59 10643-4 Dibromochloromethane NO mg1L 0,0020 1 01/02/15 23:59 124-48-1 1,2-Dibromoethane (EDB) ND mg/L 0.0020 1 01/02/15 23:59 106-93-4 Dibromomethane ND mg1L 0,0020 1 01/02/15 23:59 74-95-3 1,2-Dichlorobenzene ND mg1L 0,0020 1 01/02/15 23:59 95-50-1 1,3-Dichlorobenzene NO mg1L 0,0020 1 01/02/15 23:59 541-73-1 1,4-Dichlorobenzene NO mg/L 0.0020 1 01/02/15 23:59 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 6 of 46 aceARalytical o I—pecefab&c= ANALYTICAL RESULTS Project: Storm Water 1212212014 Pace Project No.: 92230650 Pace Analytical Services, Inc. 205 East Meadow Road - Suite Eden, NC 27288 t336)623-8921 Sample: 006 Parameters Lab ID: 92230650001 Results Units Collected: 12/22/14 10:40 Report Limit OF Received: 12/22/14 13:19 Matrix: Water Prepared Analyzed GAS No. Qual 624 Volatile Organics Analytical Method: EPA 624 1,1-Dichloroethane NO mg/L 0.0020 1 0110211523:59 75-34-3 1,2-Dichloroethane NO mg/L 0,0020 1 01/02/15 23:59 107-06-2 1,1-Dichloroethene NO mg/L 0.0020 1 01/02/15 23:59 75-35-4 cis-1,2-Dichloroethene NO mg/L 0.0020 1 0110211523:59 156-59-2 trans- l,2-Dichloroethene NO mg/L 0.0020 1 0110211523:59 156-60-5 1,2-Dichloropropane NO mg/L 0.0020 1 01/02/15 23:59 78-87-5 1,3-Dichloropropane NO mg/L 0,0020 1 01/02/15 23:59 142-28-9 2,2-Dichloropropane NO mg/L 0.0050 1 01/02/15 23:59 594-20-7 1,1-Dichloropropene NO mg/L 0.0020 1 01/02/15 23:59 563-58-6 cis-1,3-Dichloropropene NO mg/L 0.0020 1 01/02/15 23:59 10061-01-5 trans- 1,3-Dichloropropene NO mg1L 0.0020 1 01102/1523:59 10061-02-6 Ethylbenzene ND mg1L 0.0020 1 01/02/15 23:59 100-41-4 Hexachloro-1,3-butadiene ND mg1L 0.0050 1 01102/i523:59 87-68-3 2-Hexanone ND mg1L 0.010 1 01/02/15 23:59 591-78-6 iodomethane NO mg1L 0.010 1 01/02/15 23:59 74-88-4 Isopropylbenzene (Cumene) NO mg1L 0.0050 1 01/02/15 23:59 98-82-8 p-Isopropyltoluene NO mg1L 0,0050 1 01/02/15 23:59 99-87-6 Methylene Chloride NO mglL 0.0020 1 01/02/15 23:59 75-09-2 4-Methyl-2-pentanone (MIBK) NO mg1L 0.010 1 01/02/15 23:59 108-10-1 Methyl-tert-butyl ether NO mg/L 0.0050 1 01/02/15 23:59 1634-04-4 Naphthalene NO mg/L 0.0050 1 01/02/15 23:59 91-20-3 n-Propylbenzene NO mg1L 0.0050 1 01/02/15 23:59 103-65-1 Styrene NO mg/L 0.0020 1 01/02/15 23:59 100-42-5 1,1,1,2-Tetrachloroethene ND mg/L . 0.0020 1 0110211523:59 630-20-6 1,1,2,2-Tetrachloroethane NO mg/L 0.0020 1 01102/1523:59 79-34-5 Tetrachloroethene NO mg1L 0.0020 1 01/02/15 23:59 127-18-4 Toluene NO mg1L 0.0020 1 01/02/15 23:59 108-88-3 1,2,3-Trichlorobenzene ND mg/L 0.0020 1 01/02/15 23:59 87-61-6 1,2,4-Trichlorobenzene NO mg1L 0.0020 1 01/0211523:59 120-82-1 1,1,1-Trichloroethane NO mg/L 0.0020 1 01/02/15 23:59 71-55-6 1,1,2-Trichloroethane ND mg1L 0.0020 1 01/02/15 23:59 79-00-5 Trichloroethene ND mg1L 0.0020 1 01/02/15 23:59 79-01-6 Trichlorofluoromethane ND mg1L 0,0020 1 01/02/15 23:59 75-69-4 1,2,3-Trichloropropane ND mg1L 0.0020 1 01/02/15 23:59 96-18-4 1,1,2-TrichlorotriFluoroethane ND mg/L 0.0020 1 01/02/15 23:59 76-13-1 1,2,4-Trimethylbenzene ND mg/L 0.0020 1 01/02/15 23:59 95-63-6 1,3,5-Trimethylbenzene ND mg1L 0.0020 1 01102/1523:59 108-67-8 Vinyl acetate ND mg1L 0A050 1 01/02/15 23:59 108-05-4 Vinyl chloride ND mg/L 0.0020 1 01/02/15 23:59 75-01-4 m&p-Xylene ND mg1L 0.0050 1 01/02/15 23:59 179601-23-1 o-Xylene ND mg/L 0.0050 1 01/02115 23:59 95-47-6 Surrogates 4-Bromotluorobenzene (S) 90 % 70-130 1 01/02/15 23:59 460-00-4 Toluene-d8 (S) 96 % 70-130 1 01/02115 23:59 2037-26-5 1,2-Dichloroethane-d4 (S) 107 % 70-130 1 01/02/15 23:59 17060-07-0 Date: 01/05/2015 10:32 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 46 acmnalytical wwwpacelahaeom ' ANALYTICAL RESULTS Paco Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27268 (338)623-8921 Project: Storm Water 12/22/2014 Pace Project No.: 92230650 Sample: 011 Lab ID: 92230650002 Collected: 12/22/14 10:40 Received: 12/22/14 13:19 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 45.0 mg1L 8.3 1 12/24/14 08:24 D6,L2 4500H+ pH, Electrometric EDN Analytical Method: SM 4500-H+B pH at 25 Degrees C 6.8 Std. Units 1.0 1 12123/14 09:55 H6 1664 SGT-HEM, TPH Analytical Method: EPA 1564B Total Petroleum Hydrocarbons ND mg/L 5.0 1 12/24/14 08:15 608 GCS Pesticides and PCBs Analytical Method: EPA 608 Preparation Method: EPA 3510 Aldrin NO mg/L 0.00050 5 12/31/14 11:04 01/01/15 20:18 309-00-2 alpha-BHC NO mg/L 0.00050 5 12/31/14 11:04 01/01/15 20:18 319-84-6 beta-BHC NO mg/L 0.00050 5 12/31/14 11:04 01/01/15 20:18 319-85-7 delta-BHC NO mg/L 0.00050 5 12/31/14 11:04 01/01/15 20:18 319-86-8 gamma-BHC (Lindane) NO mg/L 0.00050 5 12/31/14 11:04 01/01/15 20:18 58-89-9 Chlordane (Technical) NO mg/L 0.0050 5 12/31/14 11:04 01/01/15 20:18 57-74-9 4,4'-DDD NO mg/L 0.00050 5 12/31/14 11:04 01/01/15 20:18 72-54-8 4,4'-DDE NO mg/L 0.00050 5 12/31/14 11:04 01/01/15 2018 72-55-9 4,4'-DDT NO mg/L 0.00050 5 12/31/14 11:04 01/01/15 20:18 50-29-3 Dieldrin NO mg/L 0.00050 5 1213111411:04 01/0111520:18 60-57-1 Endosulfan I NO mg/L 0.00050 5 12/31/14 11:04 01/011152018 959-98-8 Endosulfan II NO mg/L 0.00050 5 12/31114 11:04 01101/1520:18 33213-65-9 Endosulfan sulfate NO mg1L 0.00050 5 12/31/14 11:04 01/01/15 20:18 1031-07-8 Endrin NO mg1L 0.00050 5 12/31/14 11:04 01/01/15 20:18 72-20-8 Endrin aldehyde ND mg/L 0.00050 5 12/31/14 11:04 01/01/15 20:18 7421-93-4 Heptachlor ND mg/L 0.00050 5 12/31/1411:04 01/01/15 20:18 76-44-8 Heptachlor epoxide ND mg1L 0.00050 5 12/31/14 11:04 01/01/15 20:18 1024-57-3 PCB- 1016 (Aroclor 1016) ND mg1L 0.0050 5 12/31/14 11:04 01/01/15 20:18 12674-11-2 PCB-1221 (Aroclor1221) ND mg1L 0.0050 5 12131114 11 :04 01101/1520:18 11104-28-2 PCB-1232 (Aroclor 1232) ND mg1L 0.0050 5 12/31/14 11704 01/01/15 20:18 11141-16-5 PCB-1242 (Aroclor 1242) ND mg1L 0.0050 5 12/31/14 11:04 01/01/15 20:18 53469-21-9 PCB-1248 (Aroclor 1248) ND mg1L 0.0050 5 12/31/14 11:04 01/01/15 20:18 12672-29-6 PCB-1254 (Aroclor 1254) ND mg/L 0.0050 5 12/31/14 11:04 01/01/15 20:18 11097-69-1 PCB-1260 (Aroclor 1260) ND mg1L 0.0050 5 12131/14 11:04 01/01/15 20:18 11096-82-5 Toxaphene ND mg1L 0.0050 5 12131/1411:04 01/0111520:18 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 245 % 20-110 5 12/31/14 11:04 01/01/15 20:18 877-09-8 H2,S5 Decachlorobiphenyl (S) 79 % 20-138 5 12/31/14 11:04 01/01/15 20:18 2051-24-3 200.7 MET ICP Analytical Method: EPA 200.7 Preparation Method: EPA 2007 Copper 0.0072 mg1L 0.0050 1 12/24/14 11:25 12/29/14 1412 7440-50-8 Lead NO mg1L 0,0050 1 12/24/14 11:25 12/29/14 14:12 7439-92-1 Zinc 0.11 mg1L 0.010 1 12/2411411:25 12/2911414:12 7440-66-6 625 MSSV Analytical Method: EPA625 Preparation Method: EPA625 Acenaphthene NO mg1L 0.10 10 12/29/14 14:12 01/01/15 07:41 83-32-9 Acenaphthylene NO mg/L 0.10 10 12/29/14 14:12 01/01115 07:41 208-96-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 8 of 46 5aceAnalytical * /-paaelabsm n Project: Pace Project No. Sample: 011 Storm Water 12/22/2014 92230650 Parameters Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 ANALYTICAL RESULTS Lab Id: 92230650002 Collected: 12/22/14 10:40 Received: 12122114 13:19 Matrix: Water Results Units Report Limit OF Prepared Analyzed CAS No. Qual 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 Acetophenone ND mg1L 0.10 10 12/29/14 14:12 01/01/15 07:41 98-86-2 Aniline NO mg1L 0.20 10 12/29/14 14:12 01/01/15 07:41 62-53-3 Anthracene NO mg1L 0.10 10 1212911414:12 01/0111507:41 120-12-7 Benzidine NO mg1L 1.0 10 1212911414:12 01/0111507:41 92-87-5 Benzo(a)anthracene NO mg1L 0.10 10 1212911414:12 0110111507:41 56.55-3 Benzo(a)pyrene ND mglL 0.10 10 12/29/14 14:12 01/01/15 07:41 50-32-8 Benzo(b)fluoranthene NO mg1L 0.10 10 1212911414:12 01/0111507:41 205-99-2 Benzo(g,h,i)perylene NO mg1L 0.10 10 12/29/14 14:12 01/01/15 07:41 191-24-2 Benzo(k)fluoranthene NO mglL 0.10 10 12/29/14 14:12 01/01/15 07:41 207-08-9 4-13romophenylphenyl ether NO mglL 0.10 10 12/29/14 14:12 01/01/15 07:41 101-55-3 Butylbenzylphthalate NO mglL 0.10 10 12/29/14 14:12 01/01/15 07:41 85-68-7 4-Chloro-3-methylphenol NO mg1L 0.10 10 12/29/14 14:12 01/01/15 07:41 59-50-7 bis(2-Chloroethoxy)methane NO mg1L 0.20 10 12/29/14 14:12 01/01/15 07A1 111-91-1 bis(2-Chloroethyl) ether NO mg1L 0.10 10 12/29/14 14:12 01/01/15 07:41 111-44-4 bis(2-Chloroisopropyl) ether NO mg1L 0.10 10 12/29/14 14:12 01/01/15 07:41 108-60-1 2-Chloronaphthalene NO mglL 0.10 10 12/29/14 14:12 01/01115 07:41 91-58-7 2-Chlorophenol NO mg1L 0.10 10 12/29/14 14:12 01/01/15 07:41 95-57-8 4-Chlorophenylphenyl ether NO mg1L 0.10 10 12/29/14 14:12 01/01/15 07:41 7005-72-3 Chrysene NO mg1L 0.10 10 12/29/14 14:12 01101M5 07:41 218-01-9 Dibenz(a,h)anthracene NO mg1L 0.10 10 12/29/14 14:12 01/01/15 07:41 53-70-3 1,2-Dichlorobenzene NO mg1L 0.10 10 12/2911414:12 01101M507:41 95-50-1 1,3-Dichlorobenzene NO mg1L 0.10 10 12/2911414:12 01/0111507:41 541-73-1 1,4-Dichlorobenzene NO mg1L 0.10 10 12/2911414:12 01/0111507:41 106-46-7 3,3'-Dichlorobenzidine NO mg1L 0.50 10 12/29/14 14:12 01/01/15 07AI 91-94-1 2,4-Dichlorophenol ND mg1L 0.10 10 12/29/14 14:12 01/01/15 07:41 120-83-2 Dielhylphthalate ND mg1L 0.10 10 12/29/14 14A2 01/01/15 07:41 84-66-2 2,4-Dimethylphenol NO mg1L 0.20 10 12/29/14 44:12 01/01/15 07:41 105-67-9 Dimethylphthalate NO mg1L 0.10 10 12/29/14 14A2 01/01/15 07:41 131-11-3 Di-n-butylphthalate NO mg1L 0A0 10 12/29/14 14:12 01/01/15 07:41 84-74-2 4,6-Dinitro-2-methylphenoi NO mglL 0.40 W 12/29/14 14:12 01/01/15 07:41 534-52-1 2,4-Dinitrophenol NO mg1L 1.0 10 12/29/14 14A2 01/01/15 07:41 51-28-5 2,4-Dinitrotoluene NO mg1L 0A0 10 12/29/14 14:12 01/01/15 07:41 121-14-2 2,6-Dinitrotoluene NO mg1L 0.10 10 12/29/14 14:12 01/01/15 07:41 606-20-2 Di-n-octylphthalate NO mg/L 0,10 10 12/29/14 14:12 0110111507:41 117-84-0 1,2-Diphenylhydrazine NO mglL 0A0 10 12129/1414:12 0110111507:41 122-66-7 bis(2-Ethylhexyl)phthalate NO mg1L 0.1p 10 12129/1414:12 0110111507:41 117-81-7 Fluoranthene NO mg1L 0.10 10 12/29/14 14:12 01/01/15 07:41 206-44-0 Fluorene NO mglL 0A0 10 12129/1414:12 0110111507:41 86-73-7 Hexachloro-1,3-butadiene NO mg/L 0,10 10 12/29/1414712 0110111507:41 87-68-3 Hexachlorobenzene NO mglL 0A0 10 12129/1414:12 0110111507:41 118-74-1 Hexachlorocyclopentadiene NO mg1L 0.20 10 12/29/14 14:12 01/01/15 07:41 77-47-4 Hexachloroethane NO mg1L 0.10 10 12/29/14 14:12 01/01/15 07:41 67-72-1 Indeno(1,2,3-cd)pyrene NO mg1L 0.10 10 12129/1414A2 01/0111507:41 193-39-5 Isophorone NO mg1L 0,20 10 12/29/14 14:12 01/01/15 07:41 78-59-1 Naphthalene NO mg1L 0.10 10 12/29/14 14:12 01/01/15 07:41 91-20-3 Nitrobenzene NO mglL 0.10 10 12/29/14 14:12 01/01/15 07:41 98-95-3 2-Nitrophenol NO mg1L 0A 0 10 12/29/14 14:12 01/01/15 07:41 88-75-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 9 of 46 15'c ie A na ly fica I www.pacelabaowrr Project: Storm Water 12/22/2014 Pace Project No.: 92230650 Sample: 011 Parameters 625 MSSV 4-Nitrophenol N-N itrosodimethylamine N-N itroso-d i-n-propylamine N-Nitrosodiphenyiamine Pentachlorophenol Phenanthrene Phenol Pyrene 1, 2,4-Trichlorobenzene 2,4,6-Trichlorophenol Surrogates Nitrobenzene-d5 (S) 2-Fluorobiphenyl (S) Terphenyl-d14 (S) Phenol-d6 (S) 2-Fluorophenol (S) 2,4,6-Tribromophenol (S) Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 ANALYTICAL RESULTS Lab ID: 92230650002 Collected: 12/22/14 10:40 Received: 12/22/14 13:19 Matrix: Water Results Units Report Limit DF Prepared Analyzed CAS No Qual Analytical Method: EPA 625 Preparation Method: EPA 625 ND mg1L 1.0 10 12/29/14 14:12 01101M5 07:41 100-02-7 ND mg1L 0.10 10 12/29/14 14;12 01/01/15 07;41 62-75-9 ND mglL 0.10 10 12/2911414:12 01101/1507:41 621-64-7 ND mg1L 0.20 10 12/29/14 14:12 01/01/15 07:41 86-30-6 ND mglL 0.20 10 12/29/14 14:12 01/01/15 07:41 87-86-5 ND mglL 0.10 10 12/29/14 14:12 01/01/15 07:41 85-01-8 ND mg1L 0.10 10 12/29/14 14:12 01/01/15 07:41 108-95-2 ND mglL 0.10 10 12/29/14 14:12 01/01/15 07:41 129-00-0 ND mglL 0.10 10 12/29/14 14;12 01/01/15 07:41 120-82-1 ND mg1L 0.20 10 12/29/14 14:12 01/01/15 07:41 88-06-2 0 % 10-120 10 12/29/14 14:12 01/01/15 07:41 4165-60-0 D3,S4 0 % 15-120 10 12/29/14 14:12 01/01/15 07:41 321-60-8 0 % 11-131 10 12/29/14 14:12 0110111507:41 1718-51-0 0 % 10-120 10 12/29/1414;12 01/0111507:41 13127-88-3 0 % 10-120 10 12/29/14 14:12 01/01/15 07:41 367-12-4 0 % 10-137 10 12/29/14 14:12 01/01/15 07Al 118-79-6 624 Volatile Organics Analytical Method: EPA 624 Acetone ND mglL 0.010 1 12/30/14 11:30 67-64-1 Acrolein ND mg1L 0.0050 1 12/30/14 11:30 107-02-8 Acrylonitrile ND mg1L 0.050 1 12/30/14 11;30 107-13-1 Benzene ND mg1L 0.0020 1 12/30/14 11:30 71-43-2 Bromobenzene ND mg1L 0.0020 1 12/30/14 11:30 108-86-1 Bromochloromethane ND mglL 0.0020 1 12/30/14 11:30 74-97-5 Bromodichloromethane ND mg1L 0.0020 1 12/30/14 11:30 75.27-4 Bromoform ND mg1L 0.0020 1 12/30/14 1110 75-25-2 Bromomethane ND mg1L 0.0020 1 12/30/14 11:30 74-83-9 2-Butanone (MEK) N❑ mg1L 0.0050 1 12/30/14 11:30 78-93-3 n-Butylbenzene ND mg1L 0,0050 1 12/30/14 11:30 104-51-8 sec-Butylbenzene ND mg1L 0.0050 1 12/30/14 11:30 135-98-8 tert-Butyl benzene ND mg1L 0.0050 1 12/30/14 11:30 98-06-6 Carbon disulfide NO mg1L 0.0050 1 12/30/14 11:30 75-15-0 Carbon tetrachloride ND mg1L 0.0020 1 12/30/14 11:30 56-23-5 Chlorobenzene ND mg1L 0.0020 1 12/30/14 11:30 108-90-7 Chloroethane ND mg1L 0.0020 1 12/30/14 11:30 75-00-3 2-Chloroethylvinyl ether ND mg1L 0.0050 1 12/30/14 11:30 110-75-8 Chloroform ND mg1L 0.0020 1 1213011411730 67-66-3 Chloromethane ND mg1L 0.0020 1 1213011411:30 74-87-3 2-Chlorotoluene ND mg1L 0.0020 1 12/30/14 11:30 95-49-8 4-Chlorotoluene ND mg1L 0.0020 1 1213011411:30 106-43-4 Dibromochloromethane ND mglL 0.0020 1 1213011411:30 124-48-1 1,2-Dibromoethane (EDB) ND mg1L 0.0020 1 12/30/14 11;30 106-93-4 Dibromomethane ND mg1L 0.0020 1 12130/14 11:30 74-95-3 1,2-Dichlorobenzene ND mg& 0.0020 1 12130/1411:30 95-50-1 1,3-Dichlorobenzene ND mg1L 0.0020 1 1213011411:30 541-73-1 1,4-Dichlorobertzene NO mg1L 0,0020 1 12/30/1411:30 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date: 01105/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 10 of 46 aceAnalyt cal ~parara6scom ANALYTICAL RESULTS Project: Storm Water 1212212014 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Project No.: 92230650 Sample: 011 Lab ID: 92230650002 Collected: 12/22/14 10:40 Received: 12/22/14 13:19 Matrix: Water Parameters Results Units 624 Volatile Organics Analytical Method; EPA624 1,1-Dichloroethane ND mg/L 12-Dichloroethane ND mg1L 1,1-Dichloroethene ND mg1L cis- 1,2-Dichl oroethene ND mg/L trans- 1.2-Dichloroethene ND mg/L 1,2-Dichloropropane ND mg/L 1,3-Dichloropropane ND mglL 2,2-Dichloropropane ND mg/L 1,1-Dichloropropene ND mg1L cis-1,3-Dichloropropene ND mg1L trans- 1,3-Dichloropropene ND mg1L Ethylbenzene ND mg/L Hexachloro-1,3-butadiene ND mg1L 2-Hexanone ND mg1L lodomethane ND mg1L Isopropylbenzene (Cumene) ND mg1L p-Isopropyltoluene ND mg/L Methylene Chloride ND mg1L 4-Methyl-2-pentanone (MIRK) ND mg1L Methyl-tert-butyl ether ND mg1L Naphthalene ND mg1L n-Propylbenzene ND mg1L Styrene NO mg1L 1,1,1,2-Tetrachloroethane ND mg1L 1,1,2,2-Tetrachloroethane ND mg1L Tetrachloroethene ND mg1L Toluene ND mg1L 1,2,3-Trichlorobenzene ND mg1L 1,2,4-Trichlorobenzene ND mg1L 1. 1, 1 -Trichloroethane ND mg/L 1,1,2-Trichloroethane ND mg1L Trichloroethene ND mg1L Trichlorofluoromethane ND mg1L 1,2,3-Thchloropropane ND mg1L 1,12-Trichlorotauoroethane ND mg1L 12,4-Trimethylbenzene ND mg1L 1,3,5-Trimethylbenzene ND mg/L Vinyl acetate ND mg/L Vinyl chloride ND mg1L m&p-Xylene ND mg/L o-Xylene ND mg1L Surrogates 4-Bromofluorobenzene (S) 87 % Toluene-d8 (S) 98 % 1,2-Dichloroethane-d4 (S) 105 % Report Limit DF Prepared Analyzed CAS No. Qual 0.0020 1 0.0020 1 0.0020 1 0.0020 1 0,0020 1 0.0020 1 0.0020 1 0,0050 1 0.0020 1 0.0020 1 0.0020 1 0.0020 1 0,0050 1 0.010 1 0,010 1 0.0050 1 0.0050 1 0.0020 1 0.010 1 0.0050 1 0.0050 1 0.0050 1 0.0020 1 0.0020 1 0.0020 1 0.0020 1 0.0020 1 0.0020 1 0.0020 1 0.0020 1 0.0020 1 0.0020 1 0,0020 1 0.0020 1 0.0020 1 0.0020 1 0.0020 1 0.0050 1 0.0020 1 0.0050 1 0.0050 1 70-130 1 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS 12/301i411:30 75-34-3 12/30/14 11:30 107-06-2 12/3011411:30 75-354 12/30114 11:30 156-59-2 12/30114 11:30 156-60-5 1213011411:30 78-87-5 12130/ 14 11:30 142-28-9 1213011411:30 594-20-7 1213011411:30 563-58-6 12/30/14 11:30 10061-01-5 12/30/14 11:30 10061-02-6 12/30/14 11:30 10041-4 1213011411:30 87-68-3 1213011411:30 591-78-6 1213011411:30 74-884 1213011411:30 98-82-8 12130/1411:30 99-87-6 12130/1411:30 75-09-2 1213 0114 11:30 108-10 -1 12/30/14 11:30 1634-04-4 1213011411:30 91-20-3 12/30/14 11:30 103-65-1 12/30/14 11:30 10042-5 1213011411:30 630-20-6 12/30/14 11:30 79-34-5 1213 0114 11:30 12 7-18-4 12/30/14 11:30 108-88-3 12/30/14 11:30 87-61-6 12/30/14 11:30 120.82-1 12/30/14 11:30 71-55-6 1213011411:30 79-00-5 12/30/14 11:30 79-01-6 1213011411:30 75-69-4 12/3011411:30 96-18-4 12/3011411:30 76-13-1 1213011411:30 95-63-6 12/30/14 11:30 108-67-8 12/30/14 11:30 108-05-4 12/30/1411:30 75-01-4 12/30/14 11:30 179601-23-1 12130/1411:30 9547-6 1213011411:30 460-00-4 12/30/14 11:30 2037-26-5 12/30/14 11:30 17060-07-0 This report shall not be reproduced, except in full, Date: 01/05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc. Page 11 of 46 Pace Analytical Services_ Inc. 205 East Meadow Road - Suite lace,Analjtical Eden, NC 27288 www.PacefaUcom (336)623-8921 ANALYTICAL RESULTS Project: Storm Water 12/22/2014 Pace Project No.: 92230650 Sample: 012 Lab ID: 92230650003 Collected: 12/22/14 10:40 Received: 12/22/14 13:19 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Total Suspended Solids 4500H+ pH, Electrometric EDN pH at 25 Degrees C 1664 SGT-HEM, TPH Total Petroleum Hydrocarbons 608 GCS Pesticides and PCBs Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC (Undane) Chlordane (Technical) 4,4'-DDD 4,4'-DDE 4,4'-DDT Dieldrin Endosulfan I Endosulfan it Endosulfan sulfate Endrin Endrin aldehyde Heptachlor Heptachlor epoxide PC13-1016 (Aroclor 1016) PCB-1221 (Aroclor 1221) PCB-1232 (Aroclor 1232) PCB-1242 (Aroclor 1242) PCB-1248 (Aroclor 1248) PCB-1254 (Aroclor 1254) PCB-1260 (Aroclor 1260) Toxaphene Surrogates Tetrachloro-m-xylene (S) Decachlorobiphenyl (S) 200.7 MET ICP Copper Lead Zinc 625 MSSV Acenaphthene Acenaphthyiene Date: 01105/2015 10:32 AM Analytical Method: SM 2540D 4.3 mg/L 3.6 1 12/24/14 0825 L2 Analytical Method: SM 4500-H+B 6.0 Std. Units 1.0 1 12/23/14 09:55 H6 Analytical Method: EPA 16646 ND mg/L 5.0 1 12/24/14 08:16 Analytical Method: EPA608 Preparation Method: EPA3510 NO mg/L 0.000071 1 12/29/14 17:45 01/01/15 22:04 309-W2 NO mg/L 0.000071 1 12/29/14 17:45 01/01/15 22:04 319-84-6 ND mg1L 0.000071 1 12/29/14 17:45 01/01/15 22:04 319-85-7 ND mg/L 0.000071 1 12/29/14 17:45 01/01/15 22:04 319-86-8 ND mg1L 0.000071 1 12/29/14 17:45 01/01/15 22:04 58-89-9 ND mg1L 0,00071 1 12/29/14 17:45 01 /01 /15 22:04 57-74-9 ND mg/L 0.000071 1 12/29/14 17:45 01/01/15 22:04 72.54-8 ND mg1L 0.000071 1 12/29/14 17:45 01/01/15 22:04 72-55-9 NO mg1L 0.000071 1 12/29/14 17:45 01101/1522:04 50-29-3 NO mg1L 0.000071 1 12/29/14 17:45 01/01/15 22:04 60-57-1 NO mg1L 0.000071 1 12/29/14 17:45 01/01/15 22:04 959-98-8 NO mg1L 0.000071 1 12/29/14 17:45 01/01/15 22:04 33213-65-9 NO mg1L 0.000071 1 12/29/14 17:45 01/01/15 22:04 1031-07-8 NO mg1L 0.000071 1 12/29/14 17:45 01101/1522:04 72-20-8 NO mg/L 0.000071 1 12/2911417:45 01/01/15 22:04 7421-93-4 NO mg/L 0.000071 1 12/29/14 17:45 01/01/15 22:04 76-44-8 NO mg1L 0,000071 1 12/29/14 17:45 01/01/15 22:04 1024-57-3 NO mg/L 0.00071 1 12/29/14 17:45 01/01/15 22:04 12674-11-2 NO mg/L 0.00071 1 12/29/14 17:45 01/01/15 22:04 11104-28-2 ND mg1L 0,00071 1 12/29/14 17:45 01/01/15 22:04 11141-16-5 NO mg1L 0.00071 1 12/29/14 17:45 01/01/15 22:04 53469-21-9 NO mg1L 0.00071 1 12/29/14 17:45 01/01/15 22:04 12672-29-6 NO mg1L 0.00071 1 12/29/14 17:45 01/01/15 22:04 11097-69-1 NO mg/L 0.00071 1 12/29/14 17:45 01/01/15 22:04 11096-82-5 NO mg/L 0,00071 1 12/29/14 17:45 01/01/15 22:04 8001-35-2 192 % 20-110 1 12/29/14 17:45 01/01/15 22:04 877-09-8 S5 84 % 20-138 1 12/29/14 17:45 01/01/15 22:04 2051-24-3 Analytical Method: EPA200.7 Preparation Method: EPA200.7 0.0062 mg/L 0.0050 1 12/24/14 11:25 12/29/14 14:15 7440-50-8 NO mg/L 0.0050 1 12/24/14 11:25 12/29/14 14:15 7439-92-1 0.032 mg/L 0.010 1 12/24/'14 11:25 12/29/14 1415 7440-66-6 Analytical Method: EPA 625 Preparation Method: EPA 625 NO mg/L 0.071 10 12/29/14 14:12 01/01/15 08:08 83-32-9 NO mg/L 0.071 10 12/29/14 14:12 01/01/15 08:08 208-96-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 46 aceAnalytrcal. w*wpecelab&=n ANALYTICAL RESULTS Project: Storm Water 12/2212014 Pace Project No.: 92230650 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Sample: 012 Lab ID: 92230650003 Collected: 12/22/14 10:40 Received: 12/22/14 13:19 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 Acetophenone NO mglL 0.071 10 12/29/14 14:12 01/01/15 08:08 98-86-2 Aniline NO mg1L 0.14 10 12/29/14 14:12 01/01/15 08:08 62-53-3 Anthracene NO mg1L 0.071 10 12/29/14 14:12 01/01/15 08:08 120-12-7 Benzidine NO mg1L 0.71 10 12/29/14 14:12 01/01/15 08:08 92-87-5 Benzo(a)anthracene NO mg1L 0,071 10 12/29/14 14:12 01/01/15 08:08 56-55-3 Benzo(a)pyrene NO mg1L 0.071 10 12/29/14 14:12 01/01/15 08:08 50-32-8 Benzo(b)fluoranthene ND mg1L 0.071 10 12/29/14 14:12 01/01/15 08:08 205-99-2 Benzo(g,h,i)perylene NO mg1L 0.071 10 12/29/14 14:12 01/01/15 08:08 191-24-2 Benzo(k)fluoranthene NO mg1L 0.071 10 12/29/14 14:12 01/01/15 08:08 207.08-9 4-Bromophenylphenylether NO mglL 0.071 10 12/29/14 14:12 01/01/15 08:08 101-55-3 Butylbenzyiphthalate NO mg1L 0.071 10 12/29/14 14:12 01/01/15 08:08 85-68-7 4-Chloro-3-methylphenol NO mg1L 0.071 10 12/29/14 14:12 01/01/15 08:08 59-50-7 bis(2-Chloroethoxy)methane NO mg1L 0,14 10 12129/1414:12 01/01/15 08:08 111-91-1 bis(2-Chloroethyl)ether NO mg1L 0.071 10 12/29/14 14:12 01101/1508:08 111-44-4 bis(2-Chloroisopropyl) ether NO mglL 0.071 10 12/29/14 14:12 01/01/15 08:08 108-60-1 2-Chloronaphthalene NO mg1L 0,071 10 12129/1414:12 01/0111508:08 91-58-7 2-Chlorophenol NO mglL 0.071 10 12/29/14 14:12 01/01/15 08:08 95-57-8 4-Chlorophenylphenylether NO mg1L 0,071 10 1212911414:12 01101/1508:08 7005-72-3 Chrysene NO mg1L 0.071 10 12129/14 14:12 01/01/15 08:08 218-01-9 Dibenz(a,h)anthracene NO mglL 0.071 10 12/29/14 14:12 01/01/15 08:08 53-70-3 1,2-Dichlorobenzene NO mg/L 0,071 10 12/29/14 14;12 01/01/15 08:08 95-50-1 1,3-Dichlorobenzene NO mg1L 0.071 10 12/29/14 14:12 01/01/15 08:08 541-73-1 1,4-Dichlorobenzene NO mg1L 0.071 10 12129/14 14:12 01/01/15 08:08 106-46-7 3,3'-Dichlorobenzidine ND mg1L 0.36 10 12/29/14 14:12 01/01/15 08:08 91-94-1 2,4-Dichlorophencl NO mg1L 0.071 10 12129/14 14:12 01/01/15 08:08 120-83-2 Diethylphthalate NO mg1L 0,071 10 121291141*12 01101/1608:08 84-66-2 2,4-Dimethylphenol NO mg1L 0.14 10 12/29/14 14:12 01/01/15 08:08 105-67-9 Dimethylphthalate NO mg1L 0.071 10 12/29/14 14A2 01/01/15 0&08 131-11-3 Di-n-butylphthalate ND mg1L 0.071 10 12/29/14 14:12 01/01/15 08708 84-74-2 4,6-Dinitro-2-methylphenol NO mg1L 0.29 10 12/29/14 14:12 01/01/15 08:08 534-52-1 2,4-Dinitro phenol NO mg1L 0,71 10 12/29/14 14:12 01/01/15 08:08 51-28-5 2,4-Dinitrotoluene NO mg1L 0,071 10 12/29/14 14:12 01/01/15 08:08 121-14-2 2,6-Dinitrotoluene NO mglL 0.071 10 12/29/14 14:12 01/01/15 08:08 606-20-2 Di-n-octylphthalate NO mg1L 0.071 10 12/29/14 14:12 01/01/15 08:08 117-84-0 1,2-Diphenylhydrazine NO mg1L 0.071 10 12129/14 14712 01/01/15 08:08 122-66-7 bis(2-Ethyihexyl)phthalate ND mglL 0.071 10 12/29/14 14:12 01/01/15 08:08 117-81-7 Fluoranthene NO mg1L 0.071 10 12/29/14 14:12 01/01/15 08:08 20644-0 Fluorene NO mg1L 0.071 10 12/29/14 14:12 01/01/15 08:08 86-73-7 Hexachloro-1,3-butadiene NO mg1L 0.071 10 12/29/14 14:12 01/01/15 08:08 87-68-3 Hexachlorobenzene NO mg1L 0.071 10 12/29/14 14:12 01/01/15 08:08 118-74-1 Hexachlorocyclopentadiene NO mglL 0.14 10 12/29/14 14:12 01/01/15 08:08 7747-4 Hexachloroethane NO mg1L 0.071 10 12/29/14 14A2 01/01/15 08:08 67-72-1 Indeno(1,2,3-cd)pyrene NO mg1L 0.071 10 1212911414:12 0110111508:08 193-39-5 Isophorone ND mg1L 0.14 10 12/29/14 14:12 01/01115 08:08 78-59-1 Naphthalene NO mg1L 0,071 10 12/29/14 14:12 01/01/15 08:08 91-20-3 Nitrobenzene NO mg1L 0.071 10 12/29/14 14:12 01/01/15 08:08 98-95-3 2-Nitrophenol NO mg1L 0.071 10 12/29/14 14:12 01/01/15 08:08 88-75-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 13 of 46 lacieAnalytical" W"PacelaWom ANALYTICAL RESULTS Project: Storm Water 12122/2014 Pace Project No.: 92230650 Pace Analytical Services, Inc. 205 East Meadow Read- SuiteA Eden, NC 27288 ' (336)623-8921 Sample: 012 -• ; Lab ID: 92230660003 Collected: 12/22/14 10:40 Received: 12/22/14 1119 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 4-Nilrophenol N-N itrosodimethylamine N-N itroso-di-n-propylamine N-N itrosodiphenylamine Pentachlorophenol Phenanthrene Phenol Pyrene 1,2,4-Trichlorobenzene 2,4,6-Trichlorophenol Surrogates Nitrobenzene-d5 (S) 2-Fluorobiphenyl (S) Terpheny1-d14 (S) Phenol-d6 (S) 2-Fluorophenol (S) 2,4,6-Thbromophenol(S) NO mg1L 0.71 10 12/2911414A2 0110111508:08 100-02-7 NO mg1L 0.071 10 12/29/14 14:12 01/01/15 08:08 62-75-9 ND mg1L 0.071 10 12/29/14 14:12 01/01/15 08:08 621-64-7 NO mg1L 0,14 10 1212911414:12 01/0111508:08 85-30-6 NO mg1L 0.14 10 12/29/14 14:12 01/01/15 08:08 87-86-5 ND mg1L 0.071 10 12/29/14 1412 01/01/15 08:08 85-01-8 NO mg1L 0.071 10 12/29/14 1412 01/01/15 08:08 108-95-2 NO mg/L 0.071 10 12/29/14 14:12 01/01/15 08:08 129-00-0 ND mg/L 0.071 10 12/29/14 14:12 01/01/15 08:08 120-82-1 NO mg1L 0.14 10 12/29/14 14:12 01/01/15 08:08 88-06-2 0 % 10-120 10 12/29/14 14:12 01/01/15 08:08 4165-60-0 D3,S4 0 % 15-120 10 12/29/14 1412 01/01/15 08:08 321-60-8 0 % 11-131 10 12/29/14 14:12 01/01/15 08:08 1718-51-0 0 % 10-120 10 12/29/14 1412 01/01/15 08:08 13127-88-3 0 % 10-120 10 12/29/14 14:12 01/01/15 08:08 367-12-4 0 % 10-137 10 12/29/14 1412 01/01/15 08:08 118-79-6 624 Volatile Organics Analytical Method: EPA 624 Acetone 0.012 mg1L 0,010 1 01103/15 00:32 67-64-1 Acrolein NO mg1L 0.0050 1 01/03/15 00:32 107-02-8 Acrylonitrile NO mg1L 0,050 1 01/03/15 00:32 107-13-1 Benzene NO mg1L 0.0020 1 01/03/15 00:32 71-43-2 Bromobenzene NO mg1L 0.0020 1 01/03/15 00:32 108-86-1 Bromochloromethane NO mg/L 0.0020 1 01/03/15 00:32 74-97-5 Bromodichloromethane NO mg1L 0.0020 1 01/03/15 00:32 75-27-4 Bromoform NO mg1L 0.0020 1 01/03/15 00:32 75-25-2 Bromomethane NO mg1L 0,0020 1 01/03/15 00:32 74-83-9 2-Butanone (MEK) ND mg1L 0.0050 1 01/03/15 00:32 78-93-3 n-Butylbenzene NO mg1L 0.0050 1 01/03/15 00:32 104-51-8 sec-Butylbenzene NO mg1L 0.0050 1 01/03/15 00:32 135-98-8 tert-Butyl benzene ND mg/L 0.0050 1 01/03/15 00:32 98-06-6 Carbon disulfide NO mg1L 0.0050 1 01/03/15 00:32 75-15-0 Carbon tetrachloride NO mg1L 0.0020 1 01/03/15 00:32 56-23-5 Chlorobenzene NO rnglL 0.0020 1 01/03/15 00:32 108-90-7 Chloroethane NO mg1L 0.0020 1 01/03/15 00:32 75-00-3 2-Chloroethylvinyl ether NO mg1L 0.0050 1 01/03/15 00:32 110-75-8 Chloroform NO mg1L 0.0020 1 01/03/15 00:32 67-66-3 Chloromethane NO mg/L 0.0020 1 01/03/15 00732 74-87-3 2-Chlorotoluene NO mg/L 0.0020 1 01/03/15 00:32 95-49-8 4-Chlorotoluene NO mg/L 0.0020 1 01/03/15 00:32 106-43-4 Dibromochloromethane NO mg1L 0.0020 1 01/03/15 00:32 124-48-1 1,2-Dibromoethane (EDB) ND mg1L 0.0020 1 01/03/15 00:32 106-93-4 Dibromomethane NO mg1L 0.0020 1 01/03/15 00:32 74-95-3 1,2-Dichlorobenzene NO mg1L 0.0020 1 01/03/15 00:32 95-50-1 1,3-Dichlorobenzene ND mg1L 0,0020 1 01/03/15 00:32 541-73-1 1,4-Dichlorobenzene NO mg/L 0.0020 1 01/0311500:32 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 14 of 46 aceAnalytical6 www.pacdab&=n ANALYTICAL RESULTS Project: Storm Water 12/2212014 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Project No.: 92230650 Sample: 012 Lab ID: 92230650003 Collected: 12/22/14 10A0 Received: 12122114 13719 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 624 Volatile Organics Analytical Method: EPA 624 1,1-Dichloroethane NO mg1L 0.0020 1 0110311500:32 75-34-3 1,2-Dichloroethene NO mg1L 0.0020 1 01/03/15 00:32 107-06-2 1,1-Dichloroethene NO mg/L 0.0020 1 0110311500:32 75-35-4 cis-1,2-Dichloroethene NO mg/L 0.0020 1 01/03/15 00:32 156-59-2 trans-1,2-Dichloroethene NO mg/L 0.0020 1 0110311500:32 156-60-5 1,2-Dichloropropane NO mg/L 0.0020 1 01/03/15 00:32 78-87-5 1,3-Dichloropropane ND mg1L 0.0020 1 01/03/15 00:32 142-28-9 2,2-Dichloropropane ND mg/L 0.0050 1 01/03/15 00:32 594-20-7 1,1-Dichloropropene NO mg/L 0.0020 1 01/03/15 00:32 563-58-6 cis- 1,3-Dichloropropene NO mg1L 0.0020 1 01/03/15 00:32 10061-01-5 trans-1,3-Dichloropropene NO mg/L 0.0020 1 0110311500:32 10061-02-6 Ethylbenzene ND mg/L 0.0020 1 01/03/15 00:32 100-41-4 Hexachloro-1,3-butadiene ND mg/L 0,0050 1 01/03/15 00:32 87-68-3 2-Hexanone ND mg1L 0.010 1 01/03/15 00:32 591-78-6 lodomethane NO mg1L 0.010 1 01/03/15 00:32 74-88-4 Isopropylbenzene (Cumene) ND mg/L 0.0050 1 01/03/15 00:32 98-82-8 p-Isopropylioluene ND mg1L 0.0050 1 01/03/15 00:32 99-87-6 Methylene Chloride ND mglL 0A020 1 01/03/15 00:32 75-09-2 4-Methyl-2-pentanone (MIBK) NO mg/L 0.010 1 01/03/15 00:32 108-10-1 Methyl-tert-butyl ether ND mg1L 0.0050 1 01/03/15 00:32 1634-04-4 Naphthalene ND mg1L 0.0050 1 01/03/15 00:32 91-20-3 n-Propylbenzene NO mg1L 0.0050 1 01/03/15 00:32 103-65-1 Styrene NO mg1L 0.0020 1 01/03/15 00:32 100-42-5 1,1,1,2-Tetrachloroethane NO mg1L 0.0020 1 01/0311500:32 630-20-6 1,1,2,2-Tetrachloroethane NO mg/L 0.0020 1 01/03/15 00:32 79-34-5 Tetrachloroethene NO mg1L 0.0020 1 01/03/15 00:32 127-18-4 Toluene NO mglL 0.0020 1 01/03/15 00:32 108-88-3 1,2,3-Tdchlorobenzene NO mg1L 0.0020 1 01/03/15 00:32 87-61-6 1,2,4-Trichlorobenzene NO mg1L 0.0020 1 01103/1500:32 120-82-1 1. 1. 1 -Trichloroethane NO mg/L 0.0020 1 01103/1500:32 71-55-6 1,1,2-Trichloroethane NO mglL 0.0020 1 01/03/15 00:32 79-00-5 Trichloroethene NO mg1L 0.0020 1 01/03/15 00:32 79-01-6 Trichlorofluoromethane ND mg1L 0,0020 1 01/03/15 00:32 75-69-4 1,2,3-Trichloropropane NO mg/L 0.0020 1 01/03/15 00:32 96-18-4 1,1,2-Trichlorotrifluoroethane NO mg1L 0.0020 1 01103/1500:32 76-13-1 1,2,4-Trimethylbenzene NO mg/L 0.0020 1 01103/1500:32 95-63-6 1,3,5-Trimethylbenzene NO mg/L 0.0020 1 01/03/15 00:32 108-67-8 Vinyl acetate NO mglL 0.0050 1 01/03/15 00:32 108-05-4 Vinyl chloride NO mg/L 0.0020 1 01/03/15 00:32 75-01-4 m&p-Xylene NO mg/L 0.0050 1 01/03/15 00:32 179601-23-1 o-Xylene NO mg1L 0.0050 1 01/0311500:32 95-47-6 Surrogates 4-Bromofluorobenzene (S) 93 % 70-130 1 01/03/15 00:32 460-00-4 Toluene -dB (S) 96 % 70-130 1 01/03/15 00:32 2037-26-5 1,2-Dichloroethene-d4(S) 104 % 70-130 1 01103/1500:32 17060-07-0 Date: 01/05/2015 10:32 AM REPORT OF LABORATORY ANALYSIS This report shall not he reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 46 aceAnalytical w%WPacW8bs.=n QUALITY CONTROL DATA Project: Storm Water 12/22/2014 Pace Project No.: 92230650 QC Batch: EDEN116806 Analysis Method: SM 2540D QC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 92230650001, 92230650002, 92230650003 Pace Analytical Services, Inc. 205 East Meadow Road = Suite -A Eden, NC 27288 (336)623-8921 METHOD BLANK: 1359451 Matrix: Water Associated Lab Samples: 92230650001, 92230650002, 92230650003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg1L ND 2.5 12/24/14 08:22 LABORATORY CONTROL SAMPLE: 1359452 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Total Suspended Solids mg1L 250 112 45 90-110 LO SAMPLE DUPLICATE: 1359836 92230650002 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg1L 45.0 52.3 15 D6 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 16 of 46 aceAnalytical ioww.peaafaftwm QUALITY CONTROL DATA Project: Storm Water 12/22/2014 Pace Project No.: 92230650 QC Batch: EDEN116790 Analysis Method: SM 4500-H+B QC Batch Method: SM 4500-H+B Analysis Description: 4500H+B pH EDEN Associated Lab Samples: 92230650001, 92230650002, 92230650003 SAMPLE DUPLICATE: 1358318 92230650001 Dup Parameter Units Result Result RPD Qualifiers pH at 25 Degrees C Std, Units 7.1 7.1 0 H6 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 17 of 46 acmnalytical. ~..Peaera6scom QUALITY CONTROL DATA Project: Storm Water 12/2212014 Pace Project No.: 92230650 QC Batch: GCSVI19910 Analysis Method: EPA 1664B QC Batch Method: EPA 1664B Analysis Description: 1664 SGT-HEM, TPH Associated Lab Samples: 92230650001, 92230650002, 92230650003 METHOD BLANK: 1359442 Matrix: Water Associated Lab Samples: 92230650001, 92230650002, 92230650003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Petroleum Hydrocarbons mg1L ND 5.0 12/24/14 08:04 Pace Analytical Services, Inc. 205 East Meadow Road -Suite A Eden, NC 27288 (336)623-8921 LABORATORY CONTROL SAMPLE: 1359443 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Total Petroleum Hydrocarbons mg/L 20 18.5 92 64-132 MATRIX SPIKE SAMPLE: 1359444 35168525001 Spike MS MS % Rec Parameter Units Result Cone. Result % Rec Limits Qualifiers Total Petroleum Hydrocarbons mg/L 6.2 20 23.6 87 64-132 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 18 of 46 1ceAnalytical. w wM PfioWft=n QUALITY CONTROL DATA Project: Storm Water 12122/2014 Pace Project No.: 92230650 QC Batch: MPRPl17629 Analysis Method: EPA 200.7 QC Batch Method: EPA200.7 Analysis Description: 200.7 MET Associated Lab Samples: 92230650001, 92230650002, 92230650003 METHOD BLANK: 1359613 Matrix: Water Associated Lab Samples: 92230650001, 92230650002, 92230650003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Copper mg1L NO 0.0050 12/29/1412:55 Lead mg1L ND 0.0050 12/29/1412:55 Zinc mg1L ND 0.010 12/2911412:55 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 LABORATORY CONTROL SAMPLE: 1359614 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Copper mg1L .5 0.54 108 85-115 Lead mg1L .5 0.51 102 85-115 Zinc mglL .5 0.48 95 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1359615 1359616 MS MSD 92230692001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Copper mglL 0.0079 .5 .5 0.55 0.55 109 108 70-130 1 Lead mg1L ND .5 .5 0.52 0.51 103 101 70-130 2 Zinc mg1L 0.074 ,5 .5 0.54 0.54 94 92 70-130 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1359617 1359618 MS MSD 92230930005 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cana Conc. Result Result % Rec % Rec Limits RPD Qual Copper mg1L 6.6 ug1L .5 .5 0.53 0.54 104 106 70-130 2 Lead mg1L NO .5 .5 0.49 0.50 98 99 70-130 1 Zinc mg1L NO .5 .5 0.47 0.47 91 93 70-130 1 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 19 of 46 Pace Analytical Se rvices,'Inc. �r� aceAnalytica! 205 East Meadow Road -Suite A Eden, NC 27288 www.PowaDacom (336)623-8921 QUALITY CONTROL DATA Project: Storm Water 12/22/2014 Pace Project No.: 92230650 QC Batch: MSV129852 Analysis Method: EPA624 QC Batch Method: EPA 624 Analysis Description: 624 MSV Associated Lab Samples: 92230650002 METHOD BLANK: 1360901 Matrix: Water Associated Lab Samples: 92230650002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,1,1,2-Tetrachloroethane mg1L ND 0.0020 12130/1400:34 1,1,1-Trichloroethane mg1L ND 0.0020 12/3011400:34 1,1,2,2-Tetrachloroethane mg1L ND 0.0020 ,12/3011400:34 1,1,2-Trichloroethane mg1L ND 0.0020 12/30/14 00:34 1,1,2-Trichlorotrifluoroelhane mg1L ND 0.0020 12/30/14 00:34 1,1-Dichloroethane mg1L ND 0.0020 12/30/14 00:34 1,1-Dichloroethene mg/L ND 0.0020 12/30/14 00:34 1,1-Dichloropropene mg1L ND 0.0020 12/30/14 00:34 1,2,3-Trichlorobenzene mg1L ND 0.0020 1213011400:34 1,2,3-Trichloropropane mg1L ND 0.0020 12130/1400:34 1,2,4-Trichlorobenzene mg/L ND 0.0020 12/30/14 00:34 1,2,4-Trimethylbenzene mg/L ND 0.0020 12/30/14 00:34 1,2-Dibromoethane (EDB) mg/L ND 0.0020 12/30/14 00:34 1,2-Dichlorobenzene mg1L ND 0.0020 12/30/14 00:34 1,2-Dichloroethane mg1L ND 0.0020 12/30/14 00:34 1,2-Dichloropropane mg/L ND 0.0020 12/30/14 00:34 1,3,5-Trimethylbenzene mg1L ND 0.0020 12/30/14 00:34 1,3-Dichlorobenzene mg1L ND 0.0020 12/30/14 00:34 1,3-Dichloropropane mg/L ND 0.0020 12/30/14 00:34 1,4-Dichlorobenzene mg/L ND 0.0020 12/30/14 00:34 2,2-Dichloropropane mg/L ND 0.0050 12/30/14 00:34 2-Butanone (MEK) mg/L ND 0.0050 12/30/14 00:34 2-Chloroethylvinyl ether mg/L ND 0.0050 12/30/14 00:34 2-Chlorotoluene mg/L ND 0.0020 12/30/14 00:34 2-Hexanone mg/L ND 0.010 12/30/14 00:34 4-Chlorotoluene mg/L ND 0.0020 12/30/14 00:34 4-Methyl-2-pentanone (MIBK) mg/L ND 0.010 12/30/14 00:34 Acetone mg/L ND 0,010 12/30/14 00:34 Acrolein mg/L ND 0.0050 12/30/14 00:34 Acrylonitrile mg/L ND 0.050 12/30/14 00:34 Benzene mg/L ND 0.0020 12/30/14 00:34 Bromobenzene mg1L ND 0.0020 12/30114 00:34 Bromochloromethane mg1L ND 0.0020 12/30/14 00:34 Bromodichloromethane mg1L NO 0,0020 12/30/14 00:34 Bromoform mg/L ND 0.0020 12/30/14 00:34 Bromomethane mg1L ND 0.0020 12/30/14 00:34 Carbon disulfide mg1L ND 0.0050 12/30/14 00:34 Carbon tetrachloride mg1L ND 0.0020 12/30/14 00:34 Chlorobenzene mg1L ND 0.0020 12/30/14 00:34 Chloroethane mg1L ND 0.0020 12/30/14 00:34 Chloroform mg1L ND 0.0020 12/30/14 00:34 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 20 of 46 aceAnalytical wwwpacefebs Darn QUALITY CONTROL DATA Project: Storm Water 12/22/2014 Pace Project No.: 92230650 METHOD BLANK: 1360901 Associated Lab Samples: 92230650002 Parameter Units Matrix: Water Blank Reporting Result Limit Analyzed Chloromethane mg/L ND 0.0020 12/30/14 00:34 cis-1,2-Dichloroethene mg/L ND 0.0020 12/30/14 00:34 cis-1,3-Dichloropropene mg/L ND 0.0020 12/30/14 00:34 Dibromochloromethane mg1L ND 0.0020 12/30/14 00:34 Dibromomethane mg1L ND 0.0020 12/30/14 00:34 Ethylbenzene mg/L ND 0.0020 12/30/14 00:34 Hexachloro-1,3-butadiene mg/L ND 0.0050 12/30/14 00:34 lodomethane mg/L ND 0,010 12/30/14 00:34 Isopropylbenzene (Cumene) mg/L ND 0.0050 12/30/14 00:34 m&p-Xylene mg/L ND 0.0050 12/30/14 00:34 Methyl-tert-butyl ether mg/L ND 0.0050 12/30/14 00:34 Methylene Chloride mglL ND 0.0020 12/30/14 00:34 n-Butylbenzene mg/L ND 0,0050 12/30/14 00:34 n-Propylbenzene mg/L ND 0.0050 12/30/14 00:34 Naphthalene mg/L ND 0.0050 12/30/14 00:34 o-Xylene mg/L ND 0.0050 12/30/14 00:34 p-Isopropyltoluene mg/L ND 0.0050 12/30/14 00:34 sec-Butylbenzene mg/L ND 0.0050 12/30/14 00:34 Styrene mg/L ND 0.0020 12/30/14 00:34 tert-Butylbenzene mg/L ND 0.0050 12/30/14 00:34 Tetrachloroethene mg/L ND 0.0020 12/30/14 00:34 Toluene mg/L ND 0.0020 12/30/14 00:34 trans-1,2-Dichloroethene mg/L ND 0.0020 12/30/14 00:34 trans-1,3-Dichloropropene mg/L ND 0.0020 12/30/14 00:34 Trichloroethene mg/L ND 0.0020 12/30/14 00:34 Trichlorofluoromethane mg/L ND 0.0020 12/30/14 00:34 Vinyl acetate mg/L ND 0.0050 12/30/14 00:34 Vinyl chloride mg/L ND 0.0020 12/30/14 00:34 1,2-Dichloroethane-d4(S) % 107 70-130 1213011400:34 4-Bromofluorobenzene (S) % 95 70-130 12/30/14 00:34 Toluene-d8 (S) % 96 70-130 12/30/14 00:34 Qualifiers Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 LABORATORY CONTROL SAMPLE: 1360902 Spike LCS LCS % Rec Parameter Units Coric. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane mg/L .02 0.020 102 7D-130 1.1.1-Trichloroethane mg/L .02 0.023 113 52-162 1, 1, 2,2-Tetra chloroetha ne mg/L .02 0.021 105 46-157 1,1,2-Trichloroethane mg1L 02 0.021 104 52-150 1,1,2-Trichiorotrifluoroethane mg/L .02 0.025 124 70-130 1,1-Dichloroethane mg/L 02 0.023 115 59-155 1,1-Dichloroethene mg1L .02 0.025 124 1-234 1,1-Dichloropropene mg1L .02 0.023 115 70-130 1,2,3-Trichlorobenzene mg1L .02 0.019 95 70-130 Resutts presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the resuk. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in lull, Date: 01 /05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 21 of 46 acmnalytical trww.pacelabs.com QUALITY CONTROL DATA Project: Storm Water 1212212014 Pace Project No.: 92230650 LABORATORY CONTROL SAMPLE: 1360902 Pace Analytical Services,lnc. 205 East Meadow Road --Suite A Eden, NC 2728E (336)623-8921 Parameter Units Spike Cone. LCS. Result LCS % Rec % Rec Limits Qualifiers 1,2,3-Trichloropropane mglL .02 0.021 104 70-130 1,2,4-Trichlorobenzene mg1L .02 0.019 97 70-130 1,2,4-Trimethylbenzene mglL .02 0.021 107 70-130 1,2-Dibromoethane (EDB) mglL .02 0.022 110 70-130 1,2-Dichlorobenzene mg1L .02 0.022 108 18-190 1,2-Dichloroethane mglL .02 0,022 111 49-155 1,2-Dichloropropane mg1L .02 0.021 105 1-210 1,3,5-Trimelhylbenzene mg1L .02 0.022 109 70-130 1,3-Dichlorobenzene mg1L .02 0.022 109 59-156 1,3-Dichloropropane mglL .02 0.023 113 70-130 1,4-Dichlorobenzene mg1L .02 0.022 111 18-190 2,2-Dichloropropane mg1L .02 0.022 110 70-130 2-Butanone (MEK) mg1L .04 0.038 96 50-127 2-Chloroethylvinyl ether mg1L .04 0,036 90 1-305 2-Chlorotoluene mg1L .02 0.021 103 70.130 2-Hexanone mg1L .04 0.037 94 70-130 4-Chlorotoluene mg1L .02 0,023 113 70-130 4-Methyl-2-pentanone (MIBK) mg1L .04 0.038 94 70-130 Acetone mg1L .04 0.040 101 70-130 Acrolein mg1L .1 0.14 140 15-152 Acrylonitrile mg1L .1 0.11 106 75-132 Benzene mg1L .02 0.022 108 37-151 Bromobenzene mg1L .02 0.023 115 70-130 Bromochloromethane mg1L .02 0.022 108 70-130 8romodichloromethane mg1L .02 0.019 96 35-155 Bromoform. mg1L .02 0.017 86 45-169 Bromomethane mg1L .02 0.020 102 1-242 Carbon disulfide mg1L .02 0.040 200 70-130 L3 Carbon tetrachloride mg1L .02 0.021 103 70-140 Chlorobenzene mg1L .02 0,022 109 37-160 Chloroethane mg1L .02 0.027 134 14-230 Chloroform mg1L .02 0.024 121 51-138 Chloromethane mg1L .02 D.021 105 1-273 cis-1,2-Dichloroethene mg1L .02 0.022 111 68A46 cis-1,3-Dichloropropene mg1L .02 0.020 101 1-227 Dibromochloromethane mg1L .02 0.020 99 53-149 Dibromomethane mg1L .02 0.020 101 10-130 Ethylbenzene mglL .02 0.022 109 37-162 Hexachloro-1,3-butadiene mg1L .02 0.016 81 70-130 lodomethane mglL .04 0.025 63 70-130 LO I sopropyl benzene (Cumene) mg1L 02 0.021 103 70-130 m&p-Xylene mg1L .04 0.043 108 70-130 Methyl-tert-butyl ether mg1L .02 0.020 100 70-130 Methylene Chloride mg1L .02 0.022 108 1-221 n-Butylbenzene mg1L .02 0.021 104 70-130 n-Propylbenzene mg1L 02 0,022 110 70-130 Naphthalene mg1L .02 0.018 90 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 22 of 46 Pace Analytical Services, Inc. laneAnalytical m w Road - Suite A 205 East MesdoEden, NC 27288 www.pacefabs.com (336)623-8921 QUALITY CONTROL DATA Project: Storm Water 12/22/2014 Pace Project No.: 92230650 LABORATORY CONTROL SAMPLE: 1360902 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers o-Xylene mg1L .02 0.020 101 70-130 p-Isopropyltoluene mg1L .02 0-020 100 70-130 sec-Butylbenzene mg/L .02 0.021 103 70-130 Styrene mgfL .02 0.021 103 70-130 tent-Butylbenzene mg1L .02 0.017 87 70-130 Tetrachloroethene mg1L .02 0,020 102 64-148 Toluene mg1L .02 0.021 106 47-150 trans-1,2-Dichloroethene mg1L .02 0.023 115 54-156 trans-1,3-Dichloropropane mg1L .02 0.020 100 17-183 TriChloroethene mg1L .02 0,021 103 71-157 Trichlorofluoromethane mg1L .02 0.026 131 17-181 Vinyl acetate mg1L .04 0.042 105 70-130 Vinyl chloride mg1L 02 0.020 99 1-251 1,2-0ichloroethane-d4 (S) % 106 70-130 4-Bromofluorobenzene (S) % 96 70-130 Toluene-d8 (S) % 99 70-130 MATRIX SPIKE SAMPLE: 1360904 92230484001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane mg1L NO .02 0.023 113 70-130 1,11,1-Trichloroethane mglL ND .02 0,028 139 46-171 1,1,2,2-Tetrachloroethane mglL NO .02 0.022 112 73-159 1,1,2-Trichloroethane mglL ND .02 0.022 111 64-152 1,1,2-Trichlorotrifluoroethane mglL NO .02 0.028 140 59-168 1,1-Dichloroethane mg/L ND .02 0.028 142 43.172 1,1-Dichloroethene mg1L NO .02 0,031 154 48-189 1,1-Dichloropropane mglL ND .02 0.027 137 70-130 MO 1,2,3-Trichlorobenzene mg1L ND .02 0.016 82 70-130 1,2,3-Trichloropropane mg1L ND .02 0,023 114 70-130 1,2,4-Trichlorobenzene mg1L ND .02 0.018 88 70-130 1,2,4-Tri methyl benzene mg1L NO .02 0.022 11i 70-130 1,2-Dibromoethane (ED6) mg1L NO .02 0.024 121 70-130 1,2-Dichlorobenzene mg1L ND .02 0.022 109 54-154 1,2-Dichloroethane mg1L NO .02 0.025 124 42-171 1,2-Dichloropropane mglL NO .02 0.025 123 55-157 1,3,5-Trimethylbenzene mglL NO .02 0.021 107 70-130 1,3-Dichlorobenzene mglL NO .02 0.023 113 57-148 1,3-Dichloropropane mglL ND .02 0.024 120 70-130 1,4-Dichlorobenzene mglL NO .02 0,024 116 58-149 2,2-Dichloropropane mglL ND .02 0,022 110 70-130 2-Butanone (MEK) mg1L NO .04 0.051 117 70-130 2-Chloroethylvinyl ether mglL NO .04 NO 0 70-130 P5 2-Chlorotoluene mg1L NO .02 0.022 108 70-130 2-Hexanone mglL NO .04 0.042 104 70-130 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 23 of 46 (�Iacmnalytiloal" www.pacelabs.com QUALITY CONTROL DATA Project: Storm Water 12/22/2014 Pace Project No.: 92230650 MATRIX SPIKE SAMPLE: 1360904 92230484001 Spike MS Parameter Units Result Conc. Result Pace Anatytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Ms % Rec % Rec Limits Qualifiers 4-Chlorotoluene mg/L ND .02 0.024 119 70-130 4-Methyl-2-pentanone (MIRK) mg1L ND 04 0.042 104 70-130 Acetone mg/L 913 ug/L .04 0.88 -76 70-130 E Acrolein mg/L ND .1 0,14 136 70-130 MO Acrylonitrile mg/L ND A 0.12 121 70-130 Benzene mg/L ND .02 0.026 130 54.163 Bromobenzene mg/L ND 02 0.024 120 70-130 Bromochloromethane mg/L ND .02 0.025 126 70-130 Bromodichloromethane mg/L ND A2 0.023 113 56-152 Bromoform mg/L ND .02 0.018 91 53-151 Bromomethane mg/L ND .02 0.019 95 10-200 Carbon disulfide mg/L ND .02 0.050 252 70-130 MO Carbon tetrachloride mg/L ND .02 0.025 127 41-175 Chlorobenzene mg1L ND .02 0.025 125 67-152 Chloroethane mg/L ND .02 0.033 167 23-200 Chloroform mg1L 2.6 ug/L .02 0.031 140 51-166 Chloromethane mg1L ND .02 0.025 125 40-175 cis-1,2-Dichloroethene mg1L ND .02 0.027 134 45-174 cis- 1, 3-Dichloropropene mg1L NO .02 0.022 109 38-146 Dibromochtoromethane mg1L ND .02 0.023 114 65-144 Dibromomethane mg1L ND .02 0.022 111 70-130 Ethylbenzene mg1L ND .02 0.025 123 57-152 Hexachloro-1,3-butadiene mg1L ND .02 0.017 85 70-130 lodomethane mg/L ND .04 0.030 74 70-130 Isopropylbenzene (Cumene) mg/L ND .02 0.021 107 70-130 m&p-Xylene mg1L ND .04 0.048 119 70-130 Methyl-tert-butyl ether mg/L ND .02 0.022 110 70-130 Methylene Chloride mg1L ND .02 0.026 129 40-167 n-Butylbenzene mglL ND .02 0,018 90 70-130 n-Propytbenzene mg1L ND .02 0.022 109 70-130 Naphthalene mg/L ND .02 0.019 94 70-130 o-Xylene mg/L ND .02 0.022 111 70-130 p-Isopropyltoluene mg1L ND .02 0.019 92 70-130 sec-Butylbenzene mg/L ND .02 0.019 94 70-130 Styrene mg/L ND .02 0.022 111 70-130 tert-Butylbenzene mglL ND .02 0.017 83 70-130 Tetrachloroethene mg1L ND .02 0.022 112 59-155 Toluene mg/L ND .02 0.025 124 47-162 trans-1,2-Dichloroethene mg/L ND .02 0.028 141 47-178 trans-1,3-Dichloropropene mg/L ND .02 0.021 107 39-148 Trichloroethene mg/L ND .02 0.024 121 60-153 Trichlorofluoromethane mg/L ND 02 0,033 165 42-199 Vinyl acetate mg/L ND .04 0.038 95 70-130 Vinyl chloride mg/L ND .02 0.025 127 46-176 1,2-Dichloroethane-d4 (S) % 101 70-130 4-Bromofluorobenzene (S) % 88 70-130 Toluene-d8 (S) % 97 70-130 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 24 of 46 aceAnalyfir'cal www.paa�absmm QUALITY CONTROL DATA Project: Storm Water 12/22/2014 Pace Project No.: 92230650 SAMPLE DUPLICATE: 1360903 Parameter Units 92230484002 Result Dup Result 1,1,1,2-Tetrachloroethane mg1L NO ND 1,1,1-Trich1oroethane mg1L ND NO 1,1,2,2-Tetrachloroethane mg1L ND NO 1,1,2-Tdchloroethane mg1L NO NO 1,1,2-Tdchlorotrifluoroethane mg1L NO ND 1,1-Dichloroethane mg1L NO ND 1,1-Dichloroethene mg1L ND ND 1,1-Dichloropropene mg1L ND NO 1,2,3-Trichlorobenzene mg1L NO ND 1, 2,3-Trich loropropane mg1L ND ND 1,2,4-Trichlorobenzene mg1L ND NO 1,2,4-Tdmethylbenzene mg1L ND NO 1,2-Dibromoethene (ED8) mg1L NO ND 1,2-Dichlorobenzene mglL NO NO 1,2-Dichloroethane mglL ND ND 1,2-Dichloropropane mglL ND NO 1,3,5-Tdmethylbenzene mglL ND ND 1,3-Dichlorobenzene mg/L NO NO 1,3-Dichloropropane mg1L NO ND 1,4-Dichlorobenzene mg1L ND ND 2,2-Dichloropropane mg1L ND NO 2-Butanone (MEK) mg/L NO NO 2-Chloroethylvinyl ether mg1L NO ND 2-Chlorotoluene mg1L ND ND 2-Hexanone mg1L ND NO 4-Chlorotoluene mg1L NO NO 4-Methyl-2-pentanone (MIBK) mg1L NO ND Acetone mg1L ND NO Acrolein mg1L ND NO Acrylonitrile mglL ND NO Benzene mglL NO ND Bromobenzene mglL NO ND Bromochloromethane mg1L ND ND Bromodichloromethane mg1L ND NO Bromoform mg1L ND NO Bromomethane mg1L NO ND Carbon disulfide mg1L ND ND Carbon tetrachloride mg1L ND NO Chlorobenzene mg1L ND NO Chloroethane mg1L ND NO Chloroform mg1L ND NO Cfiloromethane mg1L NO ND cis-1,2-Dichloroethene mg1L ND ND cis-1,3-Dichloropropene mglL ND NO Dibromochloromethane mglL NO ND Dibromomethane mglL NO ND Ethylbenzene mg1L NO NO RPD Qualifiers Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Results presented on this page are In the units Indicated by the "Unite" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in lull, Date: 01/05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 25 of 46 laneAnalytical" wwwpaorlabscom QUALITY CONTROL DATA Project: Storm Water 12/22/2014 Pace Project No.: 92230650 SAMPLE DUPLICATE: 1360903 Parameter Units 92230484002 Result Dup Result Hexachloro-1,3-butadiene mg/L ND ND lodomethane mg/L ND NO Isopropylbenzene (Cumene) mg/L ND NO m&p-Xylene mglL ND NO Methyl•tert-butyl ether mglL ND NO Methylene Chloride mg/L NO NO n-Butylbenzene mg/L ND NO n-Propylbenzene mg1L ND NO Naphthalene mg/L ND NO o-Xylene mg1L ND NO p-Isopropyltoluene mg1L ND NO sec-Butylbenzene mg1L ND NO Styrene mg/L ND NO tert-Butylbenzene mg/L ND NO Tetrachloroethene mg1L NO NO Toluene mg/L NO NO trans-1,2-Dichloroethene mg/L NO ND trans-1,3-Dichloropropene mg/L NO NO Trichloroethene mglL ND ND Trichlorofluoromethane mg/L ND ND Vinyl acetate mg1L NO ND Vinyl chloride mg/L ND ND 1,2-Dichloroethane-d4 (S) % 108 112 4-Bromotluorobenzene (S) % 86 86 Toluene-d8 (S) % 99 97 RPD Qualifiers 4 0 2 Pace Analytical Services; Inc. 205 East Meadow Road -Suite A Eden, NC 27288 (336)623-8921 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 0110512015 10:32 AM REPORT OF LABORATORY ANALYSIS This report shatl not be reproduced, except in fun, without the written consent of Pace Analytical Services, Inc.. Page 26 of 46 aceAnalytical a�ww.pacerabseyrt QUALITY CONTROL DATA Project: Storm Water 1212212014 Pace Project No.: 92230650 QC Batch: MSV129900 QC Batch Method: EPA 624 Associated Lab Samples: 92230650001, 92230650003 Analysis Method: Analysis Description: EPA 624 624 MSV METHOD BLANK: 1362963 Matrix: Water Associated Lab Samples: 92230650001, 92230650003 Blank Reporting Parameter Units Result Limit Analyzed 1,1,1,2-Tetrachloroethane mglL ND 0.0020 0110211523:25 1,1,1-Trichloroethane mg1L ND 0.0020 01/0211523:25 1,1,2,2-Tetrachloroethane mg/L NO 0.0020 01/0211523:25 1,1,2-Trichloroethane mg1L ND 0.0020 01/0211523:25 1,1,2-TdchlorotriSuoroethane mg1L ND 0.0020 01/0211523:25 1,1-Dichloroethane mg1L NO 0.0020 01102/1523:25 1,1-Dichloroethene mglL NO 0.0020 01/02/15 23:25 1,1-Dichloropropane mg/L NO 0.0020 01/02/15 23:25 1,2,3-Trichlorobenzene mg1L NO 0.0020 01/02/15 23:25 1,2,3-Tichooropropane mg1L NO 0.0020 01/02/15 23:25 1,2,4-Trichlorobenzene mg1L NO 0.0020 01/02/15 23:25 1,2,4-Trimethylbenzene mg1L ND 0.0020 01/02/15 23:25 1,2-Dibromoethane (EDB) mg/L NO 0.0020 01/02/15 23:25 12-Dichlorobenzene mg/L ND 0.0020 01/02/15 23:25 1,2-Dichloroethane mg1L NO 0.0020 01/02/15 23:25 1,2-Dichloropropane mg1L NO 0.0020 01/02/15 23:25 1,3,5-Trimethylbenzene mg1L NO 0.0020 01/02/15 23:25 1,3-Dichlorobenzene mg1L NO 0.0020 01/02/15 23:25 1,3-Dichloropropane mglL NO 0.0020 01/02/15 23:25 1,4-Dichlorobenzene mg/L NO 0.0020 01/02/15 23:25 2,2-Dichloropropane mg/L NO 0.0050 01/02/15 23:25 2-Butanone (MEK) mg1L NO 0.0050 01/02/15 23:25 2-Chloroethylvinyl ether mg1L NO 0.0050 01/02/15 23:25 2-Chlorotoluene mg1L NO 0.0020 01/02/15 23:25 2-Hexanone mg1L NO 0.010 01/02/15 23:25 4-Chlorotoluene mg1L NO 0.0020 01/02/15 23:25 4-Methyl-2-pentanone (MIBK) mg/L NO 0.010 01/02/15 23:25 Acetone mg1L NO 0.010 01/02/15 23:25 Acrolein mg1L NO 0.0050 01/02/15 23:25 Acrylonitrile mg/L NO 0.050 01/02/15 23:25 Benzene mg1L NO 0.0020 01/02/15 23:25 Bromobenzene mg/L NO 0.0020 01/02/15 23:25 Bromochloromethane mg1L NO 0.0020 01/02/15 23:25 Bromodichloromethane mglL NO 0.0020 01/02/15 23:25 Bromoform mg/L NO 0.0020 01/02/15 23:25 Bromomethane mg/L NO 0.0020 01/02/15 23:25 Carbon disulfide mg1L NO 0.0050 01/0211523:25 Carbon tetrachloride mg1L NO 0.0020 01/02/15 23:25 Chlorobenzene mglL NO 0.0020 01/02/15 23:25 Chloroethane mg/L ND 0.0020 01/02/15 23:25 Chloroform mg1L NO 0.0020 01/02/15 23:25 Qualifiers Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Results presented on this page are In the units Indicated by the "units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 27 of 46 lacmnalytical wwwpecelahs.com QUALITY CONTROL DATA Project: Storm Water 12/22/2014 Pace Project No.: 92230650 METHOD BLANK: 1362963 Associated Lab Samples: 92230650001, 92230650003 Parameter Units Matrix: Water Blank Reporting Result Limit Analyzed Chloromethane mg1L ND 0,0020 01/02/15 23:25 cis-1,2-Dichloroethene mg/L ND 0.0020 01102/1523:25 cis-1,3-Dichloropropene mg1L NO 0.0020 01102/1523:25 Dibromochloromethane mg1L ND 0,0020 01/02/15 23:25 Dibromomethane mglL NO 0.0020 01/02/15 23:25 Ethylbenzene mg1L NO 0.0020 01102/15 23:25 Hexachloro-1,3-butadiene mg/L NO 0.0050 01102/15 23:25 lodomethane mg/L ND 0.010 01/02/15 23:25 Isopropyl benzene (Cumene) mg1L NO 0,0050 01102/l5 23:25 m&p-Xylene mg/L ND 0,0050 01/02/15 23:25 Methyl-tert-butyl ether mgIL ND 0.0050 01/02/15 23:25 Methylene Chloride mglL NO 0.0020 01/02/15 23:25 n-Butylbenzene mg/L NO 0.0050 01/02/15 23:25 n-Propylbenzene mg/L NO 0.0050 01/02/15 23:25 Naphthalene mg/L NO 0.0050 01/02/1523:25 o-Xylene mg/L NO 0.0050 01/0211523:25 p-Isopropyltoluene mg/L NO 0.0050 01/02/15 23:25 sec-Butyibenzene mg/L NO 0.0050 01/02/15 23:25 Styrene mg1L NO 0.0020 01/02/15 23:25 tert-Butyl benzene mg1L NO 0.0050 01/02/15 23:25 Tetrachloroethene mg/L NO 0.0020 01/02/15 23:25 Toluene mg/L NO 0.0020 01/02/15 23:25 trans- 1,2-Dichloroethene mglL NO 0.0020 01/02/15 23:25 trans- 1.3-Dichloropropene mg/L NO 0.0020 01/02/15 23:25 Trichloroethene mg/L NO 0.0020 01/02/15 23:25 Trichlorofluoromethane mg1L NO 0.0020 01/02/15 23:25 Vinyl acetate mg/L NO 0.0050 01/02/15 23:25 Vinyl chloride mg/L ND 0.0020 01/02/15 2125 1,2-Dichloroethane-d4 (S) % 104 70.130 01/02/15 23:25 4-Bromofluorobenzene (S) % 99 70-130 01/02/15 23:25 Toluene-d8 (S) % 96 70-130 01/02/15 23:25 Qualifiers Pace Analytical Se►vicespinc. 205 East Meadow Road-Suite.A Eden, NC 27288 (336)623-8921 LABORATORY CONTROL. SAMPLE: 1362964 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane mg/L .02 0.021 103 70-130 1,1,1-Trichloroethane mg/L .02 0.020 100 52-162 1, 1,2,2-Tetrachloroetha ne mg/L .02 0.021 105 46-157 1,1,2-Trichloroethane mg/L .02 0.020 102 52-150 1,1,2-Trichlorotrifluoroethane mg/L .02 0.020 102 70-130 1,1-Dichloroethane mg/L .02 0.021 103 59-155 1,1-Dichloroethene mg/L 02 0,020 102 1-234 1,1-Dichloropropene mg/L .02 0.020 100 70-130 1,2,3-Trichlorobenzene mg1L .02 0,020 102 70-130 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc,. Page 28 of 46 aceAnalytli�al wwwpacelahacorrr Project: Storm Water 12122/2014 Pace Project No.: 92230650 QUALITY CONTROL DATA Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 LABORATORY CONTROL SAMPLE: 1362964 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,2,3-Trichloropropane mglL .02 0.019 97 70-130 1,2,4-Trichlorobenzene mg/L .02 • 0.021 104 70-130 1. 2,4-Tri methyl benzene mglL .02 0.021 105 70-130 1,2-Dibromoethane(EDB) mg/L .02 0.021 105 70-130 1,2-Dichlorobenzene mg/L .02 0.020 100 18-190 1,2-Dichloroethene mg/L .02 0.019 97 49-155 1,2-Dichloropropane mg/L .02 0.019 97 1-210 1,3,5-Trimethylbenzene mg1L .02 0.021 103 70-130 1,3-Dichlorobenzene mg/L .02 0.020 100 59-156 1,3-Dichtoropropane mg/L .02 0.021 105 70-130 1,4-Dichlorobenzene mg/L .02 0.020 100 18-190 2,2-Dichloropropane mg/L .02 0.018 90 70-130 2-Butanone (MEK) mg/L .04 0.038 95 50-127 2-Chloroethylvinyl ether mg/L .04 0,039 98 1-305 2-Chlorotoluene mg/L .02 0.018 92 70-130 2-Hexanone mg/L .04 0.042 104 70-130 4-Chlorotoluene mg/L .02 0,020 101 70-130 4-Methyl-2-pentanone (MiBK) mg/L .04 0.042 106 70-130 Acetone mg/L .04 0.038 94 70-130 Acrolein mg1L .1 0.11 107 15-152 Acrylonitrile mg1L .1 0.11 105 75-132 Benzene mg1L .02 0,021 106 37-151 Bromobenzene mg1L .02 0.020 100 70-130 Bromochloromethane mg1L .02 0.022 108 70-130 Bromodichloromethane mg1L .02 0,020 99 35-155 Bromoform mg/L .02 0.020 99 45-169 Bromomethane mg/L .02 0.0091 45 1-242 Carbon disulfide mg/L .02 0.035 173 70-130 L3 Carbon tetrachloride mg/L .02 0.020 99 70-140 Chlorobenzene mg/L .02 0,021 103 37-160 Chloroethane mg/L .02 0.018 91 14-230 Chloroform mg/L .02 0.020 102 51-138 Chloromethane mg/L .02 0.016 81 1-273 cis- 1,2-Dichloroethene mg/L .02 0.021 104 68-146 cis- 1,3-Dichloropropene mg1L .02 0,020 100 1-227 Dibromochloromethane mglL .02 0.021 103 53-149 Dibromomethane mg1L .02 0,020 99 70-130 Ethylbenzene mg/L .02 0.021 104 37-162 Hexachloro-1,3-butadiene mg/L .02 0.020 98 70-130 lodomethane mg/L .04 0,029 72 70-130 Isopropylbenzene (Cumene) mg/L .02 0.020 102 70-130 m&p-Xylene mg/L .04 0.041 104 70-130 Methyl-tert-butyl ether mg/L .02 0.018 90 70-130 Methylene Chloride mg/L .02 0.019 94 1-221 n-Butylbenzene mg/L .02 0,020 98 70-130 n-Propylbenzene mg/L .02 0.019 97 70-130 Naphthalene mg1L .02 0.020 100 70-130 Results presented on this page are in the units indicated by the "Units" column except where an ahemate unit Is presented to the right of the result, REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 29 of 46 laneAnalytical" trwwpaWab&cote QUALITY CONTROL DATA Project: Storm Water 12/22/2014 Pace Project No.: 92230650 701IiUTTIV&P.Weril.tr;Ti1II&I u11>I Pace Analytical Services, Inc. 2U5 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers o-Xylene mg1L .02 0.020 101 70-130 p-Isopropyltoluene mg1L .02 0.020 100 70-130 sec-Butylbenzene mg1L .02 0.020 99 70-130 Styrene mg1L .02 0.022 108 70-130 tert-Butylbenzene mg1L .02 0.016 82 70-130 Tetrachloroethene mg1L .02 0.020 100 64-148 Toluene mg1L .02 0.020 99 47-150 trans- 1,2-Dichloroethene mglL .02 0.021 106 54-156 trans- 1,3-Dichloropropene mg1L .02 0.020 101 17-183 Trichloroethene mg1L .02 0.020 102 71-157 Trichlorofluoromethane mg1L .02 0.020 99 17-181 Vinyl acetate mg/L .04 0.041 102 70-130 Vinyl chloride mg/L .02 0.018 88 1-251 1,2-Dichloroethane-d4 (S) % 97 70-130 4-Bromotluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 99 70-130 MATRIX SPIKE SAMPLE: 1362966 92230650003 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 1, 1, 1,2-Tetrachloroethane mg1L ND .02 0.025 124 70-130 1, 1, 1 -Trichloroethane mg1L ND .02 0.023 117 46-171 1,1,2,2-Tetrachloroethane mg1L ND .02 0.024 121 73-159 1,11,2-Trichloroethane mg1L ND .02 0.024 122 64-152 1,1,2-Trichlorotrifluoroethane mg1L ND .02 0.018 91 59-168 1I J-Dichloroethane mg1L ND .02 0.025 126 43-172 1,1-Dichloroethene mg1L ND .02 0.023 116 48-189 1,1-Dichloropropene mg1L ND .02 0.023 117 70-130 1,2,3-Trichlorobenzene mg1L ND .02 0.018 90 70-130 1,2,3-Trichloropropane mg1L ND .02 0.023 114 70A30 1,2,4-Trichlorobenzene mg1L ND .02 0.019 94 70-130 1,2,4-Trimelhylbenzene mg1L ND .02 0.022 112 70-130 1,2-Dibromoethane (EDB) mg1L ND 02 0,024 122 70-130 1,2-Dichlorobenzene mg1L ND 02 0.023 113 54-154 1,2-Dichloroethane mg1L ND .02 0,023 115 42-171 1,2-Dichloropropane mg1L ND .02 0.024 118 55-157 1,3,5-Trimethylbenzene mg1L ND .02 0,022 109 70-130 1,3-Dichlorobenzene mg1L ND .02 0.022 110 57-148 1,3-Dichloropropane mglL ND .02 0.024 120 70-130 1,4-Dichlorobenzene mglL ND .02 0.022 110 58-149 2,2-Dichloropropane mg1L ND .02 0.021 104 70-130 2-Butanone (MEK) mg1L ND .04 0.046 114 70-130 2-Chloroethylvinyl ether mg1L ND .04 ND 0 70-130 MO 2-Chlorotoluene mg1L ND .02 0.020 102 70-130 2-Hexanone mglL ND .04 0.046 115 70-130 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 30 of 46 aceAnalytical� www.pacelaftimm QUALITY CONTROL DATA Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: Storm Water 12122/2014 Pace Project No.: 92230650 MATRIX SPIKE SAMPLE: 1362966 92230650003 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 4-Chlorotoluene mg/L ND .02 0.023 113 70-130 4-Methyl-2-pentanone (MIBK) mg1L ND .04 0.051 121 70-130 Acetone mg1L 0,012 .04 0,055 107 70-130 Acrolein mg/L ND .1 0.10 99 70-130 Acrylonitrile mg1L NO A 0.12 122 70-130 Benzene mg1L ND .02 0.026 129 54-163 Bromobenzene mg1L ND .02 0.022 112 70-130 Bromochloromethane mg/L ND .02 0,026 128 70-130 Bromodichloromethane mg/L ND .02 0.024 119 56-152 Bromoform mg1L ND .02 0.022 111 53-151 Bromomethane mg/L ND .02 0.013 67 10-200 Carbon disulfide mg/L ND .02 0.040 198 70-130 MO Carbon tetrachloride mg/L ND .02 0.022 112 41-175 Chlorobenzene mg1L ND .02 0.024 120 67-152 Chloroethane mglL ND .02 0.022 109 23-200 Chloroform mg1L ND .02 0.025 123 51-166 Chloromethane mglL ND .02 0.016 81 40-175 cis- 1,2-Dichloroethene mglL ND .02 OA25 125 45-174 cis- 1,3-Dichloropropene mglL ND .02 0.022 112 38-146 Dibromochloromethane mglL ND .02 0.023 117 65-144 Dibromomethane mglL ND .02 0.024 118 70-130 Ethylbenzene mg1L ND .02 0.023 114 57-152 Hexachloro-1,3-butadiene mg1L ND .02 0.014 72 70-130 lodomethane mg/L ND .04 0.026 65 70-130 MO Isopropylbenzene (Cumene) mg/L ND .02 0.021 107 70-130 m&p-Xyiene mg/L ND .04 0.046 114 70-130 Methyl-tert-butyl ether mg/L ND .02 0.021 106 70-130 Methylene Chloride mg1L ND .02 0.023 109 40-167 n-Butylbenzene mg1L ND .02 0,018 89 70-130 n-Propylbenzene mg1L ND .02 0.020 101 70-130 Naphthalene mg1L ND .02 0.022 110 70-130 o-Xylene mg1L ND .02 0.022 112 70-130 p-Isopropyitoluene mg1L ND .02 0.019 97 70-130 sec -Butyl benzene mg/L ND .02 0.019 93 70-130 Styrene mg1L ND .02 0.024 118 70-130 tert-Butylbenzene mg1L ND .02 0.017 83 70-130 Tetrachloroethene mg1L ND .02 0.022 108 59-155 Toluene mg1L ND .02 0.023 117 47-162 trans-1,2-Dichloroethene mg1L ND .02 0.025 125 47-178 trans- 1,3-Dichloropropene mg1L ND .02 0.024 118 39-148 Trichloroethene mg/L ND .02 0.023 117 60-153 Trichlorofluoromethane mg/L ND .02 0.020 102 42-199 Vinyl acetate mg1L ND .04 0.036 91 70-130 Vinyl chloride mg1L ND .02 0.018 91 46-176 1,2-Dichloroethane-d4 (S) % 101 70-130 4-Bromofluorobenzene (S) % 93 70-130 Toluene-d8 (S) % 99 70-130 Results presented on this page are In the units indicated by the "units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 31 of 46 acmnalytical www,pecala6stom QUALITY CONTROL DATA Project: Storm Water 12/22/2014 Pace Project No.: 92230650 SAMPLE DUPLICATE: 1362965 Parameter Units 92230650001 Result Dup Result 1,1,1,2-Tetrachloroethane mg/L ND ND 1,1,1-Tdchloroelhane mg/L ND ND 1,1,2,2-Tetrachloroethane mg1L ND ND 1,1,2-Tdchloroethane mg/L ND ND 1,1,2-Trichlorotrifluoroethane mg/L ND ND 1,1-Dichloroethane mg/L ND ND 1,1-Dichloroethene mg/L ND NO 1,1-Dichloropropene mg/L ND ND 12,3-Trichlorobenzene mg/L ND ND 1,2,3-Tdchloropropane mg/L ND ND 1,2,4-Trichlorobenzene mg/L ND ND 1,2,4-Trimethylbenzene mg/L ND ND 1,2-Dibromoethane (EDB) mg/L ND ND 1,2-Dichlorobenzene mg/L ND ND 1,2-Dichloroethane rnglL ND ND 1,2-Dichloropropane mg/L ND ND 1,3,5-Trimethylbenzene mg/L ND ND 1,3-Dichlorobenzene mg/L ND ND 1,3-Dichloropropane mg/L ND ND 1,4-Dichlorobenzene mg/L ND ND 2,2-Dichloropropane mg/L ND ND 2-8trtanone (MEK) mg/L ND ND 2-Chloroethylvinyl ether mg/L ND ND 2-Chlorotoluene mg/L ND ND 2-Hexanone mg/L ND ND 4-Chlorotoluene mg/L ND ND 4-Methyl-2-pentanone (MIBK) mg/L ND ND Acetone mg/L ND .006J Acrolein mg/L ND ND Acrylonitrile mg/L ND ND Benzene mg/L ND ND Bromobenzene mg/L ND ND Bromochloromethane mg/L ND ND Bromodichloromethane mg/L ND ND Bromoform mg/L ND ND Bromomethane mglL ND ND Carbon disulfide mgll_ ND ND Carbon tetrachloride mg/L ND ND Chlorobenzene mg1L ND ND Chloroethane mg1L ND ND Chloroform mg1L ND ND Chloromethane mg/L ND ND cis-1,2-Dichloroethene mg/L ND ND cis-1,3-Dichloropropene mg/L ND ND Dibromochloromethane mg/L ND ND Dibromomethane mg/L ND ND Ethylbenzene mg/L ND ND RPD Qualifiers Pace Analytical Services,41nc. 205 East Meadow Road --Suite A Eden, NC 27288 (336)623-8921 Results presented on this page are In the units indicated by the "Unite" column except where an attemate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 32 of 46 (.�IacieAnalytical' wwwpaarlabsc= QUALITY CONTROL DATA Project: Storm Water 12/22/2014 Pace Project No.: 92230650 SAMPLE DUPLICATE: 1362965 Parameter Units 92230650001 Result Dup Result Hexachloro-1,3-butadiene mg/L ND NO lodomethane mg/L ND NO Isopropylbenzene (Cumene) mg/L ND ND m&p-Xylene mg/L ND ND Methyl-tert-butyl ether mg/L ND ND Methylene Chloride mg/L ND ND n-Butylbenzene mg/L ND ND n-Propylbenzene mg/L NO ND Naphthalene mg/L ND ND o-Xylene mg/L ND ND p-Isopropyltoluene mg/L ND ND sec-Butylbenzene mg/L N❑ ND Styrene mg1L ND ND tert-Butylbenzene mg/L NO NO Tetrachloroethene mg/L ND ND Toluene mg/L ND NO trans-1,2-Dichloroethene mg/L NO NO trans-1,3-Dichloropropene mg/L ND ND Trichloroethene mg/L NO ND Trichlorofluoromethane mg/L NO NO Vinyl acetate mg1L NO ND Vinyl chloride mg/L ND NO 1,2-Dichloroethane-d4 (S) % 107 101 4-Bromofluorobenzene (S) % 90 92 Toluene-d8 (S) % 96 95 RPD Qualifiers 5 1 1 Pace Analytical Services, Inc. 205 East Meadow Road - Suite Eden, HC 27288 (336)623-8921 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/05/2015 10:32 AM without the written consent of Pace Analytical Services, inc.. Page 33 of 46 aceAnalyticaI iYww..pKetabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 205 East Meadow Road - Suite t1 Eden, NC 27288 (336)623-8921 Project: Storm Water 1212212014 Pace Project No.: 92230650 QC Batch: 0EXT131992 - - Analysis Method: EPA608 QC Batch Method: EPA 3510 Analysis Description: 608 GCS Pest PCB Associated Lab Samples: 92230650001, 92230650003 METHOD BLANK: 1360873 Matrix: Water Associated Lab Samples: 92230650001, 92230650003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 4,4'-DDD mglL ND 0.000050 01/01/15 18:33 4,4'-DDE mg/L ND 0.000050 01/01/15 18:33 4,4'-DDT mg1L ND 0,000050 01/01/15 18:33 Aldrin mg/L ND 0.000050 01/01/15 18:33 alpha-BHC mg/L ND 0.000050 01/01/15 18:33 beta-BHC mg/L ND 0.000050 01/01/15 18:33 Chlordane (Technical) mg/L ND 0.00050 01/01/15 18:33 delta-BHC mg/L ND 0.000050 01/0111518:33 Dieldrin mg/L ND 0.000050 01/01/15 18:33 Endosulfan I mg/L ND 0.000050 01/01/15 18:33 Endosulfan 11 mg/L ND 0.000050 01/01/15 18:33 Endosulfan sulfate mg1L ND 0.000050 01/01/15 1&33 Endrin mg/L ND 0.000050 01/0111518:33 Endrin aldehyde mg/L ND 0.000050 01/01/15 18:33 gamma-BHC (Lindane) mg/L ND 0.000050 01/01/15 18:33 Heptachlor mg/L ND 0=0050 01/0111518:33 Heptachlor epoxide mg1L ND 0,000050 01/01/15 18:33 PCB-1016 (Aroclor 1016) mg1L ND 0.00050 01/01/15 18:33 PCB-1221 (Aroclor 1221) mg/L ND 0.00050 01/01/15 18:33 PCB-1232 (Aroclor 1232) mg/L ND 0.00050 01/01/15 18:33 PCB-1242 (Aroclor 1242) mg1L ND 0.00050 01/01/15 1&33 PCB-1248 (Aroclor 1248) mg/L ND 0.00050 01/01/15 18:33 PCB-1254 (Aroclor 1254) mg1L ND 0.00050 01/01/15 18:33 PCB-1260 (Aroclor 1260) mg/L ND 0.00050 01/01/15 18:33 Toxaphene mg/L ND 0.00050 01/0111518:33 Decachlorobiphenyl (S) % 83 20-138 01/01/15 18:33 Tetrachloro-m-xylene (S) % 84 20-110 01/01/15 18:33 LABORATORY CONTROL SAMPLE: 1360874 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 4,4'-DDD mg1L 00025 0,00021 85 31-141 4,4'-DDE mg1L .00025 0.00018 73 30-145 4,4'-DDT mg/L .00025 0.00020 79 25-160 Aldrin mg1L .00025 0.00016 64 42-122 alpha-BHC mg1L .00025 0.00021 86 37-134 beta-BHC mg1L 00025 0.00024 95 17-147 delta-BHC mg1L .00025 0.00024 97 19-140 Dieldrin mg1L .00025 0.00021 84 36-146 Endosulfan I mg1L .00025 0,00021 83 45-153 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the resutt. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 34 of 46 aceAnalytrcal wwacpocalabs.com QUALITY CONTROL DATA Project: Storm Water 12/22/2014 Pace Project No.: 92230650 LABORATORY CONTROL SAMPLE: 1360874 Spike Parameter Units Cone. Endosulfan 11 mg/L .00025 Endosulfan sulfate mg1L .00025 Endrin mg1L .00025 Endrin aldehyde mg1L .00025 gamma-BHC (Lindane) mg1L 00025 Heptachlor mg1L .00025 Heptachlor epoxide mg1L 00025 Decachlorobiphenyl (S) % Tetrachloro-m-xylene (S) % Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 LCS Result LCS % Rec % Rec Limits Qualifiers 0.00022 89 1-202 0.00022 89 25-144 0.00021 84 30-147 0.00019 77 50-150 0.00022 89 32-127 0.00017 70 34-111 0.00021 84 41-126 45 20-138 84 20-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1360875 MS 92231061001 Spike Parameter Units Result Cone. MSD Spike Cone. 1360876 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Qual 4,4'-DDD mg1L ND .0005 .0005 0.00040 0.00040 81 81 31-141 1 4,4'-DDE mg1L NO .0005 .0005 0.00035 0,00035 71 71 30-145 0 4,4'-DDT mg1L NO .0005 .0005 0.00042 o.b004i 86 83 25-160 3 Aldrin mg1L NO .0005 .0005 0.00034 0.00033 69 66 42-122 5 alpha-BHC mg1L NO .0005 .0005 0.00041 0,00038 83 77 37-134 7 beta-BHC mg1L NO .0005 .0005 0.00047 0.00044 95 89 17-147 7 delta-BHC mg1L NO .0005 .0005 0.00049 0,00045 98 91 19-140 7 Dieldrin mg1L NO .0005 .0005 0.00042 0.00041 84 82 36-146 2 Endosulfan I mg1L ND .0005 .0005 0.00039 0.00038 79 76 45-153 4 Endosulfan II mg1L NO .0005 .0005 0.00044 0,00041 89 83 1-202 8 Endosulfan sulfate mg1L NO .0005 .0005 0.00048 0.00043 96 88 26-144 9 Endrin mg1L NO .0005 .0005 0.00046 0.00045 92 90 30-147 2 Endrin aldehyde mg1L ND .0005 .0005 0.00044 0.00044 88 88 50-150 0 gamma-BHC (Lindane) mg1L ND '0005 .0005 0.00045 0.00042 92 85 32-127 8 Heptachlor mg1L NO .0005 .0005 0.00039 0.00039 79 79 34-111 1 Heptachlor epoxide mg1L ND .0005 .0005 0.00041 0,00039 83 79 41-126 5 Decachlorobiphenyl (S) % 64 58 20-138 Tetrachloro-m-xylene (S) % 127 116 20-110 S5 Results presented on this page are In the units Indicated by the "Units" column except where an alternate untt is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 35 of 46 aceftlyticall9 W".. paceiabimn QUALITY CONTROL DATA Project: Storm Water 12/22/2014 Pace Project No.: 92230650 QC Batch: OEXT/32023 Analysis Method: EPA 608 QC Batch Method: EPA3510 Analysis Description: 608 GCS Pest PCB Associated Lab Samples: 92230650002 METHOD BLANK: 1362056 Associated Lab Samples: 92230650002 Parameter Units Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers 4,4'-DDD mg/L ND 0.000050 01/01/15 17:58 4,4'-ODE mg/L ND 0.000050 0110111517:58 4,4'-DDT mg1L ND 0.000050 01/0111517:58 Aldrin mg/L ND 0.000050 01101/1517:58 alpha-BHC mg/L ND 0.000050 01/01/15 17:58 beta-BHC mg/L ND 0.000050 01/0111517:58 Chlordane (Technical) mg/L ND 0.00050 01/01/15 17:58 delta-BHC mg/L ND 0.000050 01/0111517:58 Dieldrin mg/L ND 0.000050 01/0111517:58 Endosulfan I mg/L ND 0.000050 01/01/15 17:58 Endosulfan II mg/L ND 0.000050 01/01/15 17;58 Endosulfan sulfate mg/L ND 0.000050 01/01/15 17:58 Endrin mg1L ND 0,000050 01/0111517:58 Endrin aldehyde mglL ND 0.000050 01/01/15 17:58 gamma-BHC (Lindane) mg1L ND 0.000050 01/01/15 17:58 Heptachlor mg1L NO 0,000050 01/0111517:58 Heptachlor epoxide mg1L ND 0.000050 01/01/15 17:58 PCB-1016 (Aroclor 1016) mg1L ND 0.00050 01/01/15 17:58 PCB-1221 (AroGor 1221) mg1L ND 0.00050 01/01/15 17:58 PCB-1232 (Aroclor 1232) mg1L ND 0.00050 01/01/15 17:58 PCB-1242 (Aroclor 1242) mg1L ND 0,00050 01/01/15 17:58 PCB-1248 (AroGor 1248) mg1L ND 0.00050 01/01/15 17:58 PCB-1254 (Aroclor 1254) mg1L ND 0.00050 01/01/15 17:58 PCB-1260 (Aroclor 1260) mg1L NO 0,00050 01/01/15 17:58 Toxaphene mg/L ND 0.00050 01101/1517:58 Decachlorobiphenyl (S) % 74 20-138 01/01/15 17:58 Tetrachloro-m-xylene (S) % 83 20-110 01/01/15 17:58 Pace Analytical Services, htc. 205 East Meadow Road - Suite Al Eden, NC 27288 (336)623-8921 LABORATORY CONTROL SAMPLE: Parameter 1362057 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 4,4'-DDD mg1L .00025 0.00023 93 31-141 4,4'-DDE mg/L .00025 0.00020 79 30-145 4,4'-DDT mg/L .00025 0.00021 86 25-160 Aldrin mg/L .00025 0.00017 68 42-122 alpha-BHC mg/L .00025 0.00022 88 37-134 beta-BHC mg/L .00025 0.00025 99 17-147 delta-BHC mg1L .00025 0,00025 103 19-140 Dieldrin mg/L .00025 0.00023 91 36-146 Endosulfan I mg/L .00025 0.00022 88 45-153 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 36 of 46 aceAnalytica! WW.pacelaba.cam QUALITY CONTROL DATA Project: Storm Water 12/22/2014 Pace Project No.: 92230650 LABORATORY CONTROL SAMPLE: 1362057 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)923-8921 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Endosulfan II mg1L .00025 0.00024 96 1-202 Endosulfan sulfate mg1L .00025 0,00024 96 26-144 Endrin mg1L .00025 0.00023 92 30-147 Endrin aldehyde mg1L .00025 0=020 81 50-150 gamma-BHC (Lindane) mg1L .00025 0.00023 93 32-127 Heptachlor mg1L .00025 0.00019 76 34-111 Heptachlor epoxide mg1L .00025 0.00022 89 41-126 Decachlorobiphenyl (S) % 69 20-138 Tetrachloro-m-xylene (S) % 87 20-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1362058 1362059 MS MSD 92231253002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual 4,4'-DDD mg/L ND .00062 .00062 0.00053 0.00059 86 96 31-141 11 4,4'-DDE mg/L ND .00062 .00062 0.00046 0.00050 75 80 30-145 7 4,4'-DDT mg1L ND .00062 .00062 0.00053 0.00056 85 91 25-160 7 Aldrin mg1L ND .00062 .00062 0.00047 0.00046 76 75 42-122 1 alpha-BHC mg1L ND .00062 .00062 0.00050 0.00044 80 72 37-134 12 beta-BHC mg1L ND .00062 .00062 0.00057 0.00055 92 89 17-147 3 delta-BHC mg1L ND .00062 .00062 0.00059 0,00057 95 92 19-140 4 Dieldrin mg1L ND .00062 .00062 0.00053 0.00057 86 92 36-146 7 Endosulfan I mg/L ND .00062 .00062 0.00048 0.00049 78 79 45-153 1 Endosulfan II mg1L ND .00062 .00062 0.00055 0.00057 89 93 1-202 4 Endosulfan sulfate mg1L ND .00062 .00062 0.00060 0.00061 97 98 26-144 2 Endrin mg1L ND 00062 .00062 0.00058 0.00060 94 98 30-147 4 Endrin aldehyde mg1L ND .00062 .00062 0.00051 0.00049 83 79 50-150 5 gamma-BHC (Lindane) mg1L ND 00062 .00062 0.00053 0.00048 85 77 32-127 10 Heptachlor mg/L ND .00062 .00062 0.00052 0,00054 84 88 34-111 4 Heptachlor epoxide mg1L ND .00062 .00062 0.00051 0.00054 83 87 41-126 5 Decachlorobiphenyl (S) % 87 77 20-138 Tetrachloro-m-xylene (S) % 89 81 20-110 Results presented on thla page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the tight of the recruit. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 37 of 46 lacmnalytical" MW..peoefabs.com QUALITY CONTROL DATA Project: Storm Water 12/22/2014 Pace Project No.: 92230650 QC Batch: OEXT/31985 Analysis Method: EPA625 QC Batch Method: EPA625 Analysis Description: 625 MSS Associated Lab Samples: 92230650001, 92230650002, 92230650003 METHOD BLANK: 1360573 Matrix: Water Associated Lab Samples: 92230650001, 92230650002, 92230650003 Blank Reporting Parameter Units Result Limit Analyzed 1,2,4-Tdchlorobenzene mg/L ND 0.0050 12/30/14 22:35 1,2-Dichlorobenzene mg1L NO 0.0050 12/30/14 22:35 1,2-Diphenylhydrazine mg/L NO 0,0050 12/30/14 22:35 1,3-Dichlorobenzene mg1L NO 0.0050 12/30/14 22:35 1,4-Dichlorobenzene mg/L ND 0.0050 12/30/14 22:35 2,4,6-Trlchlorophenol mg/L NO 0,010 12/30/14 22:35 2,4-Dichlorophenol mg1L NO 0.0050 12/30/14 22:35 2,4-Dimethylphenol mg/L NO 0.010 12/30/14 22:35 2,4-Dinitrophenol mg/L NO 0,050 12/30/14 22:35 2,4-Dinitrotoluene mg/L ND 0.0050 12/30/14 22:35 2,6-Dinitrotoluene mg/L NO 0.0050 12/30/14 22:35 2-Chloronaphthalene mg/L NO 0.0050 12/30/14 22:35 2-Chlorophenol mg/L ND 0.0050 12/30/14 22:35 2-Nitrophenol mg/L NO 0.0050 12/30/14 22:35 3,3'-Dichlorobenzidine mg/L NO 0.025 12/30/14 22:35 4,6-Dinitro-2-methylphenol mg/L NO 0.020 12/30/14 22:35 4-Bromophenylphenyl ether mg/L NO 0.0050 12/30114 22:35 4-Chloro-3-methylphenol mg/L NO 0.0050 12/30114 22i35 4-Chlorophenylphenyl ether mg1L NO 0.0050 12/30/14 22:35 4-Nitrophenol mg1L NO 0.050 12/30/14 22:35 Acenaphthene mg/L NO 0.0050 12/30/14 22:35 Acenaphthylene mg1L NO 0.0050 12/30/14 22:35 Acetophenone mglL NO 0.0050 12/30/14 22:35 Aniline mg/L NO 0,010 12/30/14 22:35 Anthracene mg/L NO 0.0050 12/30/14 22:35 Benzidine mglL ND 0.050 12/30/14 22:35 Benzo(a)anthracene mg1L NO 0.0050 12/30/14 22:35 Benzo(a)pyrene mg/L NO 0.0050 12/30/14 22:35 Benzo(b)fluoranthene mg1L ND 0.0050 12/30/14 22:35 Benzo(g,h,i)perylene mg1L NO 0.0050 12/30/14 22:35 Senzo(k)fluoranthene mg/L NO 0.0050 12/30/14 22:35 bis(2-Chloroethoxy)methane mg1L NO 0.010 12/30/14 22:35 bis(2-Chloroelhyl) ether mg1L NO 0.0050 12/30/14 22:35 bis(2-Chloroisopropyl) ether mg1L NO 0.0050 12130/14 22:35 bis(2-Ethylhexyl)phthalate mg/L NO 0:0050 12/30/14 22:35 Butylbenzylphthalate mg/L NO 0.0050 12/30/14 22:35 Chrysene mg1L NO 0.0050 12/30/14 22:35 Di-n-butylphthalate mglL NO 0.0050 12/30/14 22:35 Di-n-octylphthalate mglL NO 0.0050 12/30/14 22:35 Dibenz(a,h)anthracene mg1L NO 0.0050 12/30/14 22:35 Diethylphthalate mglL NO 0.0050 12/30/14 22:35 Qualifiers Pace Analytical Services, Inc. 205 East Meadow Road - Suite,;, Eden, NC 27288 (336)623-8921 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date: 0 1105/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 38 of 46 aceAnapical wwwrpacefabscom QUALITY CONTROL DATA Project: Storm Water 1212212014 Pace Project No.: 92230650 METHOD BLANK: 1360573 Matrix: Water Associated Lab Samples: 92230650001, 92230650002. 92230650003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Dimethylphthalate mg/L ND 0.0050 12/30/14 22:35 Fluoranthene mg/L ND 0.0050 12/30/14 22:35 Fluorene mg/L ND 0.0050 12/30/14 22:35 Hexachloro-1,3-butadiene mg/L ND 0.0050 12/30/14 22:35 Hexachlorobenzene mg/L ND 0.0050 12/30/14 22:35 Hexachlorocyclopentadiene mg1L ND 0,010 12/30/14 22:35 Hexachloroethane mg/L ND 0.0050 12/30/14 22:35 Indeno(1,2,3-od)pyrene mglL ND 0.0050 12/30/14 22:35 Isophorone mg/L ND 0.010 12/30/14 22:35 N-N itroso-di-n-propyla mine mg1L ND 0,0050 12/30/14 22:35 N-Nitrosodimethylamine mg1L ND 0.0050 12/30/14 22:35 N-Nitrosodiphenylamine mg1L ND 0.010 12/30/14 22:35 Naphthalene mg1L ND 0.0050 12/30/14 22:35 Nitrobenzene mg1L ND 0.0050 12/30/14 22:35 Pentachlorophenot mg1L ND 0,010 12/30/14 22:35 Phenanthrene mg1L ND 0.0050 12/30/14 22:35 Phenol mg/L ND 0.0050 12/30/14 22:35 Pyrene mg/L ND 0.0050 12/30/14 22:35 2,4,6-Tribromophenol (S) % 26 10-137 12/30/14 22:35 2-Fluorobiphenyl (S) % 78 15-120 12/30/14 22:35 2-Fluorophenol (S) % 12 10-120 12/30/14 22:35 Nitrobenzene-d5 (S) % 81 10-120 12/30/14 22:35 Phenol-d6 (S) % 14 10-120 12/30/14 22:35 Terphenyl-d14 (S) % 103 11-131 12/30/14 22:35 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 LABORATORY CONTROL SAMPLE 8, LCSD: 1360574 Parameter Units Spike Conc. 1360712 LCS LCSD Result Result LCS % Rec LCSD % Rec % Rec Limits RPD Max RPD Qualifiers 1,2,4-Trichlorobenzene mg1L .05 0.036 0,036 73 72 44-142 1 30 1,2-Dichlorobenzene mg/L .05 0.036 0.035 71 71 32-129 1 30 1,2-Diphenylhydrazine mg1L .05 0.043 0.046 87 91 25-150 5 30 1,3-Dichlorobenzene mg1L .05 0.033 0.033 66 66 1-172 1 30 1,4-Dichlorobenzene mg1L .05 0.035 0.035 70 69 20-124 2 30 2,4,6-Trichlorophenol mg/L .05 0.039 0.040 78 80 37-144 2 30 2,4-Dichlorophenol mg/L .05 0.041 0.041 82 82 1-191 0 30 2,4-Dimethylphenol mg1L .05 0.040 0.041 80 81 32-119 1 30 2,4-Dinitrophenol mg1L .25 0.22 0.24 87 94 1-181 7 30 2,4-Dinitrotoluene mg1L .05 0.043 0.045 86 91 39-139 5 30 2,6-Dinitrotoluene mg/L .05 0.044 0.046 89 92 50-158 4 30 2-Chloronaphthalene mg1L .05 0.039 0.040 79 80 50-118 2 30 2-Chlorophenol mg1L .05 0.039 0.039 78 78 23-134 1 30 2-Nitrophenol mg/L 05 0.045 0.044 90 88 29-182 2 30 3,3'-Dichlorobenzidine mg/L .1 0.081 0.086 81 86 1-262 6 30 4,6-Dinitro-2-methylphenol mg1L .1 0.092 0.099 92 99 1-181 7 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the rfght of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/05/2015 10:32 AM without the written consent of Pare Analytical Services, Inc.. Page 39 of 46 laneAnalytical" anvecperrfabacom QUALITY CONTROL DATA Pace Analytical S"ces, lnc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: Storm Water 12/22/2014 Pace Project No.: 92230650 LABORATORY CONTROL SAMPLE & LCSD: 1350574 1360712 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers 4-Bromophenylphenyl ether mg/L .05 0.043 0.042 86 85 53-127 2 30 4-Chloro-3-methylphenol mg/L .1 0,079 0.079 79 79 22-147 0 30 4-Chlorophenylphenyl ether mg1L .05 0.041 0.042 83 84 25-158 1 30 4-Nitrophenol mg/L .25 0.083 0,097 33 39 1-132 16 30 Acenaphthene mg1L 05 0.042 0.042 83 84 47-145 1 30 Acenaphthylene mg1L .05 0.042 0.042 84 84 33-145 0 30 Acetophenone mg1L .1 0,043 0.043 43 43 25.150 1 30 Aniline mg/L .05 0.030 0.034 61 67 25-150 10 30 Anthraoene mg1L 05 0.043 0.044 87 87 1-166 1 30 Benzidine mg1L .1 ND .044J 3 44 25-150 30 L2 Benzo(a)anthracene mg1L .05 0.045 0.046 91 92 33-143 2 30 Benzo(a)pyrene mg1L .05 0.048 0.049 96 98 17-163 2 30 Benzo(b)fluoranthene mg1L .05 0.047 0.050 93 99 24-159 6 30 Benzo(g,hJ)perylene mg1L .05 0,045 0.048 91 97 1-219 6 30 Senzo(k)fluoranthene mg1L .05 0.046 0.044 92 88 11-162 4 30 bis(2-Chloroethoxy)melhane mg1L .05 0.041 0,042 83 84 33-184 1 30 bis(2-Chloroethyl) ether mg/L .05 0,042 0.042 84 85 12-158 1 30 bis(2-Chloroisopropyl) ether mg1L .05 0.038 0.040 77 81 36-166 5 30 bis(2-Ethylhexyl)phthalate mglL .05 0,048 0,050 96 101 8-158 5 30 Butylbenzylphtha late mg1L .05 0.048 0.050 96 100 1-152 4 30 Chrysene mg/L .05 0.046 0.047 93 94 17-168 1 30 Di-n-butylphthalate mglL .05 0,046 0.048 92 96 1-118 4 30 Di-n-octylphthaiate mg1L .05 0.048 0.051 96 102 4-146 6 30 Dibenz(a,h)anthraoene mglL .05 0.047 0,048 94 97 1-227 3 30 Diethylphthalate mglL 05 0.044 0.046 88 91 1-114 3 30 Dimethylphthalate mglL .05 0.043 0.044 85 88 1-112 3 30 Fluoranthene mglL .05 0.044 0,046 89 92 26-137 4 30 Fluorene mglL .05 0.043 0.044 87 88 59-121 2 30 Hexachloro-1,3-butadiene mg1L .05 0.035 0.035 70 69 24-116 1 30 Hexachlorobenzene mglL .05 0,043 0,042 85 84 1-152 2 30 Hexachiorocyclopentadiene mg1L .05 0.040 0.042 81 83 25-150 3 30 Hexachloroethane mg1L .05 0.033 0.033 66 66 40-113 1 30 lndeno(1,2,3-cd)pyrene mg1L .05 0.048 0.051 96 101 1-171 5 30 Isophorone mg1L .05 0.042 0.043 84 86 21-196 2 30 N-Nilroso-di-n-propylamine mg1L 05 0.042 0.043 84 86 1-230 3 30 N-Nitrosodimethylamine mg/L .05 0.026 0.027 52 54 25-150 3 30 N-Nitrosodi phenyla mine mg/L .05 0.044 0.045 88 90 25-150 1 30 Naphthalene mg1L .05 0.039 0.039 78 77 21-133 1 30 Nitrobenzene mg/L .05 0.043 0.044 86 88 35-180 2 30 Pentachlorophenol mglL .1 0.091 0.095 91 95 14-176 4 30 Phenanthrene mg1L .05 0.042 0.043 84 85 54-120 1 30 Phenol mg/L .05 0.016 0.016 32 33 5-112 3 30 Pyrene mg/L .05 0.045 0.045 90 90 52-115 0 30 2,4,6-Tribromophenol (S) % 92 94 10-137 2-Fluorobiphenyl (S) % 82 83 15-120 2-Fluorophenol (S) % 47 48 10-120 Nitrobenzene-d5 (S) % 86 86 10-120 Results presented an this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 40 of 46 aceAnalytrcal www.paoefffftcom QUALITY CONTROL DATA Project: Storm Water 1212212014 Pace Project No.: 92230650 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 LABORATORY CONTROL SAMPLE & LCSD: 1360574 1360712 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers Phenol-d6 (S) % 33 33 10-120 Terphenyl-d14 (S) % 98 96 11-131 Results presented on this page are In the untts indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 0 of 46 Pace Analytical Seirvices, Inc. 205 East Meadow Road - SuiteA ,�aoeMalXimle Eden, NC 27288 www.peoarabs.com (336)623-8921 QUALIFIERS Project: Storm Water 12/22/2014 Pace Project No.: 92230650 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenyla mine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services -Asheville PASI-C Pace Analytical Services - Charlotte PASI-E Pace Analytical Services - Eden ANALYTE QUALIFIERS D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. E Analyte concentration exceeded the calibration range. The reported result is estimated. H2 Extraction or preparation conducted outside EPA method holding time. H6 Analysis initialed outside of the 15 minute EPA recommended holding time. LO Analyte recovery in the laboratory control sample (LCS) was outside QC limits. L2 Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated samples may be biased low. L3 Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in associated samples. Results unaffected by high bias. MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits. P5 The EPA or method required sample preservation degrades this compound, therefore acceptable recoveries may not be achieved in sample matrix spikes. S4 Surrogate recovery not evaluated against control limits due to sample dilution. S5 Surrogate recovery outside control limits due to matrix interferences (not confirmed by re -analysis). REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, i Date: 01/05/2015 10:32 AM without the written consent of Pace Analytical Services, Inc.. Page 42 of 46 0 �aceAnaljftal wmvpacela&o= QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Storm Water 12/22/2014 Pace Project No.: 92230650 Pace Anatytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623.8921 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92230650001 006 SM 2540D EDEN116806 92230650002 011 SM 2540D EDEN/16806 92230650003 012 SM 2540D EDEN/16806 92230650001 006 SM 4500-H+B EDEN116790 92230650002 011 SM 4500-H+B EDEN/16790 92230650003 012 SM 4500-H+B EDEN/16790 92230650001 006 EPA 1664E GCSV119910 92230650002 011 EPA 1664B GCSV119910 92230650003 012 EPA 1664E GCSV119910 92230650001 006 EPA 3510 OEXT131992 EPA 608 GCSW19974 92230650002 011 EPA 3510 OEXT/32023 EPA 608 GCSV/19975 92230650003 012 EPA 3510 0EXT131992 EPA 608 GCSV119974 92230650001 006 EPA 200.7 MPRP/17629 EPA 200.7 ICP/15875 92230650002 011 EPA 200.7 MPRP/17629 EPA 200.7 ICP/15875 92230660003 012 EPA 200.7 MPRP/17629 EPA 2003 ICP/15875 92230650001 006 EPA 625 OEXT/31985 EPA 625 MSSV/10135 92230650002 011 EPA 625 0EXT/31985 EPA 625 MSSV/10135 92230650003 012 EPA 625 OEXT/31985 EPA 625 MSSV110135 92230650001 006 EPA 624 M SV/29900 92230660002 011 EPA 624 MSV129852 92230650003 012 EPA 624. MSV129900 Date: 01/05/2015 10:32 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 43 of 46 2aceAnatJT1- wwo.pate. CHAIN -OF -CUSTODY 1 Analytical Request Document The Chaln-of-Custody is a LEGAL DOCUMENT. All releyant ffelds must be completed accurately, Page: of a Section A Section B Section C .Required Client Information; Required Pro}ect Information: - Invoice Information:La t Report To: Attention: A '2 Pt Add Copy To; Company Name, 12EGUI f6i&176198 AGENCY�W,-'a"�y'�h , dj,-Azy -r , - r'• 3 IV .W , AM a Address. F NPDES F GROUNDWATER r DRINKING WATER r UST r RCRA r OTHER F_maii To: e f Purchase Order No.: Pace Quote Rareran�: no: Fax: Project �. 07 -6a - 0�7 Name: Pete Project Manepar, =$Ica LOCatIOn y^ _l Y., jCr �' l� c� "�°l - '� '•` .li�i '`�LYtit 44 �}f Y✓� •,e'�:� -ice-.'rt Requested Due DaterTAT: Pro q � ect Number: Pepe Prod: i�;f,�;iSTA '}�'�a4,•'•°.Gfitf:�t4=. � ,.tip Fe'gdoted Anatysfs'F.iltered'(YM} g+� A « t�: JhkMatr1x 't Section D COdea —s Z Rectulmdpuntln(ormabon Q COLLECTED PrsservaNvas �•4V1 . rLt�* LT �,..+t-VT Drinking Water DW g 11 o k Water WT Waste Water WW I ;R*duct eo m � MPCS e w e r U Z Pr p srAOS r r•3 Soil(80c! SL I � o �I}� SAMPLE ID ell W Wipe ¢ w z ;:.. 1e�1y /11 j�/��� , (AZ,O.9lr) Air AR, AR Sample IDS MUST BE UNIQUE Tissue TS p O w aLu a r ?itrgr� U Other OT X tu t~u 0 mU. O C s `.,'a* — DATE., TIME OATS TIME O 2 = Z ZE9n Pace Project NoJ Lab I.D. Ilk- z �- U �- ! 0�- F f I 0 La. •B. T�' Y 12 `� i4DDITIONALCQMMENT9 ?•K - `# �+•ti: a^FDATE '. T1i11E R,t �;F ACGEPTEDBYIAFFlLIATION SAMPLECONDfilON3 t*YT_`RELJNQUISHEDBY/AFFiLIATiON�a 4J7-4 /320 '22 / -s�— AJ SAMPLER NAME AND SIGNATURE` r ftir��=�i4 ,.=,;54 5 tr .._* EYf : r i�.,s•=`Ks `A -'I d r a`,o c� o m PRINT Name of SAMPLER: ! f, AORIGINAL ` o 8 DATE Signed A SIGNATURE of SAMPLER: 7D (MMDlYY): to c 'Important Noto: By Si4�9 this fonn you are accaptlrrp Paces NET 30 day payment u=mu ana agreelrq to late Cra:ges of 1.b% per money ror arty Invokwe rut peM wlth'.n 30 eaye. r F-ALL-0-029reV.07, 15-May-2007 /�� // CHAIN -OF -CUSTODY 1 Analytical Request Document /•�G 8 A.,,, yfi al * The Chaln-d-Custody Is a LEGAL DOCUMENT. All relevant fields must he Completed accurately. ///����aa I"1llQiyar ! � www.pactimbs.com .. , Section A Section B section C Page: C of o[ Required diem irrfonnedon: Required Protect lnfonrtaflon: invoice Information: PAY'{ r , yyt L+ t� RaportTa. Attention: - p� . O fir W f! 1 /r v Address: Copy To: Company No 0: c_ .,.,..r:�..,.__._:...�.._y. .t tvyr. r%r-fi5¢, 'fix:'.= REG4lLATORY3'AtiENCY3 . Address: r NPDES IW GROUND WATER iW 'DRINKING WATER j UST r RCRA, r OTHER Jom[�i Email To: r r {[� co Purchase Order No.: Para Quota R„re,e aa; Phone:' Project Nanre: Ma Protect 481te t vcatton fi,"iy Requested Due Dete1TAT: PreJacl Number. Paco P �e�5iAiEr�x R utasted'ArialYela L SeCtIOd D Matrix Codes RagatradCaeetlnfortnatlon tYwTRIx r coDt: COLLECTED Preservetives . prinldap wemr Waterpw WT � � � Waste Water 4VYV Product P aUp Q T - sT,tRr � EJIt?reltAa i} SAMPLE !D WIp d WP W a tu Zb66 C (A-Z, ll-9l;) Air AR O Sample IDs MUST BE UMIOUE lusLie TS Other OT o C11 0. m f.� a = w DATE TIME DATE TIME # x z z z Pace Pro act NoJ let) I.D. G r a; Ito t 1 r X 'ano Wr G —r t lo."40 fl i X UO O G t0;40 cl u ys, o —S s GJ zz !'OS firVs sa cur a iras' I r a r�a7 irr 1 x �- F�'ADDtTIONAL`COMMENTS�',t13� g'�"`��iyi`'' -:F-%�`+k1,.�' :'�RELINQUISHEDBYlAFF1L:IJ1710N`5"-°t'r"� -:;4 - i..1,'-- ti �DATE''�71ME,^ -es`=..eJ1. .'13 .. � +�•'{'.;. •{5,`ACGE?TE:p,8Y1i1FflUATtON1_F NOT1}*,:Y-y. c_wl.�-� r..91.t. �-^'� y���DATE� pair. �+aTldtE+ '- =.- -._+A1. SAMPLE CONDITIONS PRINT Name of SAMPLER. L� AORIGINAL rM s 91 $ SIGNAYURE of SAMPLE DATE Signed MMIDD ch p B a) •Impatam Note: By e9 ning ims farm yw areas perq Pac % NET C day payment tamm and egroaing to late t:hwgea of 1.5% per month for my inwfoaa not paid within 30 days. 1=-ALL-0-02OrBV.07, i rJMay-2dDi Document Name: -.Sample .Condition Upon Document ReA§ed: March 13; 2013 Receipt SGUR :. r. - .:.. _ .. .::.. Page f of 2 ... . Document No.:. ::. ` ...: Issuing Authoritles: F-EDN-CS-003-rev.09 :.. Pace. Eden Qualfty Offilce Client Name; � � f ,;i Where Received: [j Huntersville ❑ 'Asheville Eden Raleigh Courier (circle): Fed Ex LIPS US.P,(,�, Commercial Pace Other Custody Seal on CooledBox Present: ❑yes . 1kno `. 'Seals intact - ❑ yes' * : ❑ no . Packing Material: .EWbble.Wrap ❑Bubble Bags . Nona ❑ Other Thermometer Used: IR Gun E15007 rN ype of.Ice: Wet , Blue None ❑ Samples on lea,'000nng process has begun Temp Correction Factor. Add I Subtract t 0. Correctsd,CoolerTamp.: Z ' C Temp should be above freezing to 6•0 . Blolaglcal Tisstre is Frozen: Yes No W4 Comments; .. Date.and Initials of person examining . Chain of Us" Present: es. ONO . OINA 1: Chain of Custod Filled Out: Wes ❑No '11WA 2. Chain of Custody Relinquished: es ❑Na: ❑WA 3: Sampler Name & Signature on COC: XYess []No .❑WA 4. Samples Arrived within Hold Time: es ' []NO ❑Min 5. Short Hold Time Anal is <T2hr : YeS ON6, : [2WA 6.: .. Rush Turn Around Time Requested: ❑Yes' o ❑WA 7. Sufficient Volume: jWes. ❑No QNrA 8. Correct Contalners Used: -Pace Containers Used: -- [(e& ONO - es, ❑HO .❑NrA ❑WA 9. Containers Intact .: es' dNo ❑WA 10. . Filtered volume received.far Dissolved tests fives ONo WA 11. - Sample Labels match 6= -Includes dateAlmeAD/Anal Is Matrix: ❑Yes No ❑WA 12. All containers needing pre&ervailon have been checked. All oontalnens needing presemilon are found to be In compliance with EPA recommendation. ors VOA, aord M TOo. o&a, w"o y�e& ONo , —t: Yes []No 0Yes ❑No ❑ WA ❑WA 13. Ink W when ompletod Samples checked for dechlodnation: -. ❑Na . CJWA 14. Head&paoe In VOA Vials >6min : ❑Yes, _❑No., wa 15'. Trip Blank Present: Trip Blank -Custody Seals Present Pace jdj Blank Lot f irrchas ❑Yes ❑nro ❑Yoa ©No OWA A i8. Client Notification/ Resolution: Field Data Required? Y I N Person Contacted: Dat. me: Comments/ Resolution: SCURF Review bete: Place label here SRF Review: bate: OR Note: Whenever there Is a discrepancy affecting North p€ianoe samples, a copy of this form will be sent to the North Carolina DEHNR Handwrite protect number. Cer0cation Office (€ a out of hold, incorrect preservative, out of temp, (rf no label available) Incorrect containers) Page 46 of 46 ❑�o WERoMiLAIN Weil -McLain Company • 523 New Street • Eden, NC 27288 Tel: (919) 627-6037 • Fax: (919) 627-6067 January 8, 2015 Central Files Division of Water Quality 1617 Mail Service Center Raleigh, NC 27699-1617 RE: Explanation of Stormwater Monitoring Report Dear Sir or Madam: In accordance with NPDES (NCG030000) Stormwater Permit Condition Part II Section B, the first of two semi-annual sampling events has been completed and is attached. Monitoring was conducted for stormwater discharge outfalls 6-13 (SDO) as identified in the SWPPP, with "NO FLOW" being reported for five of the outfalls. The DMR, storm data (local on onsite readings), and analytical data is attached. As indicated in the enclosed Stormwater Monitoring Report, there were two outfall values that exceeded the benchmarks. The following Stormwater Discharge Outfalls exhibited values measured outside of the benchmark limits: Outfall6: Copper Outfall 11: Copper & Zinc The increased Copper and Zinc at SDO# 11 can be contributed to a fairly new galvanized steel fence and guardrail barrier that was added to the property, just above the outfall areas. The low flow may affected the concentration levels. Tier One actions have been implemented, and the SWPPP has been updated. The total rainfall recorded under Part A of the Stormwater Discharge Outfall (SDO) Monitoring Report is listed as 0.01" which occurred within the first 30 minutes of discharge. If you have any questions or comments regarding the enclosed reports, please contact me at (336) 627-6037. Sincerely, Paul Smith EHS Specialist Weil -McLain t , cav ENF-0 3AN13W5 CENTRAL- FILES DWR SECTION WEWRLAIN Weil -McLain Company • 523 New Street - Eden. NC 27288 Tel: (919) 627-6011 - Fax: (919) 627-6067 RECEIVED .tune 11, 2014 JUN 17 2014 Central Files CENTRAL~ FILES Division of Water Quality DWOBOG 1617 Mail Service Center Raleigh, NC 27699-1617 RE: Stormwater Analytical Monitoring Dear Sir or Madam: In accordance with NPDES (NCG030000) Stormwater Permit Condition Part II Section B, the first of two semi-annual sampling events has been completed and is attached. Monitoring was conducted for stormwater discharge outfalls 6-13 (SDO) as identified in the SWPPP, with "NO FLOW' being reported for one of the outfalls. The DMR, storm data (local on onsite readings), and analytical data is attached. All of the Stormwater Discharge Outfalls exhibited values measured within of the benchmark limits. ;The totai`rainfaii 'recorded with an onsite gage` recorded': i'.50""for the pefiod. The PH meter(s) was confirmed to be in calibration prior to testing'Using buffer solutions certified at 4, 7, and 10 pH. If you have any questions or comments regarding the enclosed reports, please contact me at (336) 627-6037. Sincerely, Weil -McLain Aryn Hicks EHS Coordinator Enclosure Permit Number: NCS Certificate of Coverage Number: NCG030548 STORMWATER DISCHARGE OUTFALL (SDO) MONITORING REPORT or SAMPLES COLLECTED DURING CALENDAR YEAR: 2014 (This monitoring; report shall be received by the Division no later than 30 days from the date the facility receives the sampling results from the laboratory.) FACILITY NAME Weil -McLain PERSON COLLECTING SAMPLE(S) Ar yn Hicks Rick Mebane Ron Jones CERTIFIED LABORATORY(S) Pace Analytical Services Inc. Lab # Lab # Part A: Specific Monitoring Requirements COUNTY Rockingham PHONE NO. (336) 627-6037 SIGNATURE OF PERMITTEE OR DESIGNEE REOU_IRED ON PAGE 2. Outfall Date .... Total pH, Total Lead; mg/L Copper, Zinc, mg/L Note -Polar Oil 'Total Toxic No. Sample Collected, Rainfall, Standard Units '.Suspended mg;/L and Grease, Organics, (mo/dd/yr) inchesSolids, mg/L mg/L " ' mglL Benchmarks 6.0-9.0 • '100 mg/L 0.033mg/L 0.007mgIL • 0.067mg/L'' '' "15mg/L,- 1mg/L - SOO #6 5/15/2014 1.50" 6.82 7.9 <0.005 <0.005 <0.010 <5.0 < (Reporting Limit SOO #7 5/15/2014 1.50" 6.11 21.5 <0.005 <0.005 0.044 <5.0 < (Reporting Limit SDO #8 5/15/2014 1.50" 6.18 19.4 <0.005 <0.005 0.028 <5.0 < (Reporting Limit SDO #9 5/15/2014 1.50" 6.37 35.3 <0.005 <0.005 0.031 <5.0 < (Reporting Limit SDO #10 5/15/2014 1.50" NO FLOW NO FLOW NO FLOW NO FLOW NO FLOW NO FLOW NO FLOW SOO #11 5/15/2014 1.50" 6.91 3.5 <0.005 0.0052 0.025 <5.0 < (Reporting; Limit SOO #12 5/15/2014 1.50" 7.11 4.1 �01005 <0.005 0.017 <5.0 < (Reporting Limit SDO 413 5/15/2014 I.50" 6.94 7.5 <0.005 <0.005 0.017 <5.0 :�:17 Reporting Limit Does this facility perform Vehicle Maintenance Activities using more than��lras of Inew ��toorr oil per month? _ yes X no (if yes, complete fart B) (U JUN 17; 2014 CENTRAL -FILES DWQ/BOG Form SWU-246, lust revised 21212012 Page 1 of 2 Part B: Vehicle Maintenance Activity Monitoring Requirements Outfall Date 50050 00556 00530 00400 No. Sample Collected 'Total Flow (if applicable) Total Rainfall Oil & Grease (if appl.) Nbn-polar O&GITPH (lllethod 1664 if a pl. Total Suspended- Solids pH New Alotor.Oil Usage-7 nio/dd/ r MG inches m /i m /l Units allmo, STORM I:V1,N'I' CIIAltAC7'F,RIS'I'1CS: Mail Original and one copy to: Division of Water Quality Date 5/15/2014 Attn: Central Files Total Event Precipitation (inches): 1.50" 1617 Mail Service Center Event Duration (hours): (only if applicable — see permit.) Raleigh, North Carolina 27699-1617 (if more than one storm event was sampled) Date Total Event Precipitation (inches): Event Diu•alion(hours): (only if applicable — see permit.) "I certify, under penalty of law, that this document and all attachments were prepared wider my direction or supervision in accordance with a System designed to assure that qualified personnel properly gather and evahlate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible fur, gathering the information, the information submitted is, to tire best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including tli ,ossibility fines and imprisonment for knowing violations.": (Signature. of Permittee) (Date Form SWU-246, last revised 21212012 Page 2 of 2 aceAnalyical vrvnvp. celaDs.cpn. May 28, 2014 Mr. Jim H Miller Weil McLain 523 S. New St. Eden, NC 27288 RE: Project: Storm Water Testing Pace Project No.: 92201481 Pace Analytical Services, Inc. 205 East Meadow Road - SUite A Eden, NC 27288 (336)623-8921 Dear Mr. Miller: Enclosed are the analytical results for sample(s) received by the laboratory on May 15, 2014. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body_of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sinc rely, Terri Page terri.page@pacelabs.corn Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shaft not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 1 of 51 - aceAnalX cal wwzvpacefa5s.com; I Project: Storm: Water Testing Pace Project No.: 92201481 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersvilie, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Certification #: 99006001 Asheville Certification IDs 2225 Riverside Dr., Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 Eden Certification IDs 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 West Virginia Certification #: 357 VirginialVELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 VirginiaiVELAP Certification #. 460222 North Carolina Wastewater Certification #: 633 VirginialVELAP Certification #: 460025 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 2728E (336)623-8921 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 51 aceAnafytreal wrw.Pacefabs.com, i SAMPLE ANALYTE COUNT Project: Storm Water Testing Pace Project No.: 92201481 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92201481001 SDO 7 SM 2540D CHM 1 PASI-E EPA 1664B CLW 1 PASI-C EPA 608 RES 27 PASI-C EPA 200.7 JMW 3 PASI-A EPA 625 RES 65 PASI-C EPA 624 GAW 72 PASI-C 92201481002 SDO 8 SM 2540D CHM 1 PASI-E EPA 1664B CLW 1 PASI-C EPA 608 RES 27 PASi-C EPA 200.7 JMW 3 PASI-A EPA 625 RES 65 PAS!-C EPA 624 GAW 72 PASI-C 92201481003 SDO 9 SM 2540D CHM 1 PASI-E EPA 1664B CLW 1 PASI-C EPA 608 RES 27 PASI-C - EPA 200.7 JMW 3 PAsl-A EPA 625 RES 65 PASI-C EPA 624 GAW 72 PASI-C 92201481004 SDO 6 SM 2540D' CHM 1 PASI-E EPA 1664B CLW 1 PASI-C EPA 608 RES 27 PASI-C EPA 200.7 JMW 3 PASI-A EPA 625 RES 65 PASI-C EPA 624 GAW 72 PASI-C 92201481005 SDO 11 SM 2540D CHM 1 PASI-E EPA 1664B CLW 1 PASI-C EPA 608 RES 27 PASI-C EPA 200.7 JMW 3 PASI-A EPA 625 RES 65 PASI-C EPA 624 GAW 72 PASI-C 92201481006 SDO 12 SM 2540D CHM 1 PAS[-E EPA 1664E CLW 1 PASI-C EPA 608 RES 27 PASI-C EPA 200.7 JMW 3 PASI-A EPA 625 RES 65 PASI-C EPA 624 GAW 72 PASI-C 92201431007 $DO 13 SM 2540D CHM 1 PASI-E REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3of51 aceAnalytical v�x:paeelabs.axm. SAMPLE ANALYTE COUNT Project: Storm Water Testing Pace Project No.: 92201481 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336 )623-8921 Lab ID Sample ID Method Analysts Analytes Reported Laboratory EPA 1664B CLW 1 PAS;-C EPA 608 RES 27 PASI-C EPA 200.7 JMW 3 PAS[ -A EPA 625 RES 65 PASI-C EPA 624 GAW 72 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4of51 aceAnalXical wrnvpacobbs.com ANALYTICAL RESULTS Project: Storm Water Testing Pace Project No..' 92201481 Pace Analytical Services, Inc. 205 East Meacow Road - Suite A Eden, NC 27288 (336)623.8321 Sample: SDO 7 Lab ID: 92201481001 Collected: 05/15/14 11:50 Received: 05/15/14 13:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Total Suspended Solids 1664 SGT-HEM, TPH Total Petroleum Hydrocarbons 608 GCS Pesticides and PCBs Aldrin alpha-BHC beta-BHC delta-BHC gamma-SHC (Lindane) Chlordane (Technical) 4,4'-DDD 4,4'-DDE 4,4'-DDT Dieldrin Endosulfan I Endosulfan II Endosulfan sulfate Endrin Endrin aldehyde Heptachlor Heptachlor epoxide PCB-1016 (Aroclor 1016) PCB-1221 (Aroclor 1221) PCB-1232 (Aroclor 1232) PCB-1242 (Aroclor 1242) PCB-1248 (Aroclor 1248)- PCB-1254 (Aroclor 1254) PC3-1260 (Aroclor 1260) Toxaphene Surrogates Tetrachloro-m-xylene (S) Decachlorobiphenyl (S) 200.7 MET ICP Copper Lead Zinc 625 MSSV Acenaphthene Acenaphthylene Acetophenone Aniline Anthracene Analytical Method: SM 2540D 21.5 mg/L 2.5 1 05/19/14 09:48 Analytical Method: EPA 1664B NO mg/L 5.0 1 0512011410:07 Analytical Method: EPA 608 Preparation Method: EPA 3510 NO mg/L 0.000050 1 05/21/14 17:55 05/27/14 20:09 309-00-2 NO mg/L 0,000050 1 05/21/14 17:55 05/27/14 20:09 319-84-6 NO mg/L 0.000050 1 05/21/14 17:55 05/27/14 20:09 319-85-7 ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 20:09 319-86-8 ND mg/L 0,000050 1 05/21/14 17:55 05/27/14 20:09 58-89-9 NO mg/L 0.00050 1 05/21/14 17:55 05/27/14 20:09 57-74-9 NO mg/L 0,000050 1 05/21/14 17:55 05/27/14 20:09 72-54-8 ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 20:09 72-55-9 ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 20:09 50-29-3 NO mg/L 0.000050 1 05/21/14 17:55 05/27/14 20:09 60-57-1 ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 20:09 959-98-8 ND mg/L 0.000050 1 05/21/14 17:55 05/27/1.420:09.33213-6.5-9.,- ND mg/L 0,000050 1 05/21/14 17:55 05/27/14 20:09 1031-07-3 ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 20:09 72-20-8 ND mg1L 0.000050 1 05/21/14 17:55 05/27/14 20:09 7421-93-4 ND mglL 0.000050 1 05/21/14 17:55 05/27/14 20:09 76-44-8 NO mg/L 0.000050 1 05/21/14 17:55 05/27/14 20:09 1024-57-3 NO mg/L 0.00050 1 0512111417:55 05/27/14 20:09 12674-11-2 NO mg/L 0.00050 1 05/21/14 17:55 05/27/14 20:09 11104-28-2 ND mg/L 0.00050 1 05/21/14 17:55 05/27/14 20:09 11141-16-5 ND mg/L 0.00050 1 05/21/14 17:55 05/27/14 20:09 53469-21-9 ND mg/L 0,00050 1 05/21/14 17:55 05/27/14 20:09 12672-29-6 ND mg/L 0.00050 1 05/21/14 17:55 05/27/14 20:09 11097-69-1 ND mg/L 0.00050 1 05/21/14 17:55 05/27/14 20:09 11096-82-5 NO mg/L 0.00050 1 05/21/14 17:55 05/27/14 20:09 8001-35-2 44 % 20-110 1 05/21/14 17:55 05/27/14 20:09 877-09-8 40 % 20-138 1 05/21/14 17:55 05/27/14 20:09 2051-24-3 Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 NO mg/L 0.0050 1 05/19/14 18:00 05/22/14 22:37 7440-50-8 NO mg/L 0.0050 1 05/19/14 18:00 05/22/14 22:37 7439-92-1 0.044 mg/L 0.010 1 05/19/14 18:00 05/22/14 22:37 7440-66-6 Analytical Method: EPA 625 Preparation Method: EPA 625 ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 05:07 83-32-9 ND mg/L 0,0050 1 05/19/14 13:35 05/21/14 05:07 208-96-8 NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 05:07 98-86-2 ND mg/L 0.010 1 05/19/14 13:35 05/21/14 05:07 62-53-3 ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 05.07 120-12-7 Date: 05/28/2014 01:18 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in fult, without the written consent of Pace Analytical Services, Inc.. Page 5 of 51 aceAnalyiical wrrn!p2Lr1a55.C'om- I ANALYTICAL RESULTS Project: Storm Water Testing Pace Project No.: 92201481 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Sampfe: $DO 7 Lab fD: 92201481001 Collected: 05/15/14 11:50 Received: 05/15/14 13:46 Matrix! Water Parameters Results knits Report Limit DF Prepared Analyzed CAS No. Qua] 625 MSSV Anaiytical Method: EPA 625 Preparation Method: EPA 625 Benzidine ND mg/L 0,050 1 05/19/14 13:35 05/21/14 05:07 92-87-5 Senzo(a)anthracene ND mg/L 0,0050 1 05/19/14 13:35 05/21/14 05:07 56-55-3 Benxo(a)pyrene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 05:07 50-32-8 Benzo(k)fluoranthene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 05:07 205-99-2 Benzo(g,h,i)perylene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 05:07 191-24-2 Benzo(k)fluoranthene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 05:07 207-08-9 4-Bromophenylphenyiether ND mg/L 0.0050 1 05119/1413:35 05/21/14 05:07 101-55-3 Butylbenzylphthalate ND mg/L 0.0050 1 05119/14 13:35 05/21/14 05:07 85-68-7 4-Chloro-3-methylphenol ND mg1L 0.0050 1 05/19/14 13:35 05/21/14 05:07 59-50-7 bis(2-Chloroethoxy)methane ND mg1L 0.010 1 05/19/14 13:35 05/21/14 05:07 111-91-1 bis(2-Chloroethyl) ether ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 05:07 111-44-4 bis(2-Chlorcisopro pyl) ether ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 05:07 108-60-1 2-Chloronaphthalene ND mglL 0.0050 1 05/19/14 13:35 05/21/14 05:07 91-58-7 2-Chlorophenol ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 05:07 95-57-8 4-ChIorophenylphenyl ether ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 05:07 7005-72-3 Chrysene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 05:07 218-01-9 Dibenz(a,h)anthracene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 05:07 53-70-3 1,2-Dichlorobenzene NO mg1L 0.0050 - - -1 051l 9114 13.35 0512 U 14 05: V / 95-50-1 - 1,3-Dichlorobenzene ND mgIC". 0.0050 1 05/19/14 13:35 05/21/14 05:07 541-73-1 1,4-Dichlorobenzene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 05:07 106-46-7 3,3'-Dichlorobenzidine - ND mg1L 0,025 1 05/19/14 13:35 05/21/14 05:07 91-94-1 2,4-Dichlorophenol ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 05:07 120-83-2 Diethyl phthalate ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 05:07 84-66-2 2,4-Dimethylphenol ND mg/L 0.010 1 05/19/14 13:35 05/21/14 05:07 105-67-9 Dimethylphthalate ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 05:07 131-11-3 Di-n-butylphthalate ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 05:07 84-74-2 4,6-Dinitro-2-methyl pheno; ND mg/L 0.020 1 05/19/14 13:35 05/21/14 05:07 534-52-1 2,4-D in itro phenol ND mg/L 0.050 1 05/19/14 13:35 05/21/14 05:07 51-23-5 2,4-Dinitrotoluene ND mg/L 0,0050 1 05/19/14 13:35 05/21/14 05:07 121-14-2 2,6-Dinitrotoluene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 05:07 606-20-2 Di-n-octylphthalate ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 05:07 117-84-0 1,2-Diphenylhydrazine ND mg/L 0,0050 1 05/1911413:35 05/21/14 05:07 122-66-7 b is(2-Ethylhexyl)phtha late ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 05:07 117-31-7 Fluoranthene ND mg1L 0.0050 1 05/19/14 13:35 05/21/14 05:07 206-44-0 Fluorene ND mg1L 0,0050 1 05/19/14 13:35 05/21/14 05:07 86-73-7 Hexachloro-1,3-butadiene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 05:07 87-68-3 Hexachlorobenzene ND mg/L 0.0050 1 0511911413:35 05121 f1 4 05:07 113-74-1 Hexachlorocyclo pentad ie n e ND mg1L 0.010 1 05/19/14 13:35 05/21/14 05:07 77-47-4 Hexachloroethane ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 05:07 67-72-1 Indeno(1,2,3-cd)pyrene ND mg1L 0.0050 1 05/19/14 13:35 05/21/14 05:07 193-39-5 Isophorone ND mglL 0.010 1 05/19/14 13:35 05/21/14 05:07 78-59-1 Naphthalene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 05:07 91-20-3 Nitrobenzene ND mg1L 0.0050 1 05/19/14 13:35 05/21/14 05:07 98-95-3 2-Nitrophenol ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 05:07 88-75-5 4-Nitrophenof ND mg/L 0.050 1 05/19/14 13:35 05/21/14 05:07 100-02-7 N-Nitrosodimethyfamine ND mg/L 0,0050 1 05/19/14 13:35 05/21/14 05:07 62-75-9 N-N itroso-di-n-pro pyla mine ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 05:07 621-64-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Face Analytical Services, Inc.. Page 6 of 51 ace Analytical (J wrmpacelaSS.com- f ANALYTICAL RESULTS Project: Storm Water Testing Pace Project No.: 92201431 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Sample: SDO 7 Parameters Lab 0: 92201431001 Collected: 05/15/14 11:50 Results. Units Report Limit DF Received: 05/15/14 13:45 Matrix: Water Prepared Analyzed CAS No. Qual 625 MSSV Analytical Method: EPA 625. Preparation Method: EPA 625 N-Nitrosodiphenylamine NO mg/L 0.010 1 05/ 19114 13:35 05/21/14 05:07 86-30-6 Pentachlorophenol NO mg/L 0.010 1 05/19/14 13:35 05/21/14 05:07 87-86-5 Phenanthrene NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 05:07 85-01-8 Phenol NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 05:07 108-95-2 Pyrene NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 05:07 129-00-0 1,2,4-Trichlorobenzene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 05:07 120-82-1 2,4,6-Trichlorophenol NO mg/L 0.010 1 05/19/14 13:35 05/21/14 05:07 88-06-2 Surrogates Nitrobenzene-d5 (S) 41 % 10-120 1 05/19/14 13:35 05/21/14 05:07 4165-60-0 2-Fluorobiphenyl (S) 41 % 15-120 1 05/19/14 13:35 05/21/14 05:07 321-60-8 Terphenyl-dl 4 (S) 79 % 11-131 1 0511911413:35 05121/1405:07 1718-51-0 Phenol-d6 (S) 17 % 10-120 1 05/19114 13:35 05/21/14 05:07 13127-88-3 2-Fluorophenol (S) 25 % 10-120 1 05/19/14 13:35 05/21/14 05:07 367-12-4 2,4,6-Tribromophenol (S) 76 % 10-137 1 05/19/14 13:35 05/21/14 05:07 118-79-6 624 Volatile Organics Analytical Method: EPA 624 Acetone NO mg/L 0.010 1 05/20/14 02:54 67-64-1 Acrolein "ND mg/L", 0.0050 1 ---?05120114 02:54 107-02.5 Acrylonitrile ND mglL 0.050 1 05/20/14 02:54 107-13-1 Benzene ND mg/L 0.0020 1 05/20/14 02:54 71-4312 Bromobenzene NO mg1L 0.0020 1 05/20/14 02:54 108-86-1 Bromochloromethane NO mg1L 0.0020 1 05/20/14 02:54 74-97-5 Bromodichloromethane NO mg1L 0.0020 1 06/20/1402:54 75-27-4 Bromoform NO mg/L 0.0020 1 05/20/14 02:54 75-25-2 Bromomethane ND mg1L 0,0020 1 05/20/14 02:54 74-83-9 2-Butanone (MEK) ND mg1L 0.0050 1 05/20/14 02:54 78-93-3 n-Butylbenzene NO mg/L 0.0050 1 05/20/14 02:54 104-51-8 sec-Bu tyl benzene ND mg/L 0.0050 1 05/20/14 02:54 135-98-8 tert-Butylbenzene NO mg/L 0.0050 1 05/20/14 02:54 98-06-6 Carbon disulfide NO mg/L 0.0050 1 05/20/14 02:54 75-15-0 L3 Carbon tetrachloride NO mg/L 0.0020 1 05/20/14 02:54 56-23-5 Chlorobenzene NO mg/L 0.0020 1 05/20/14 02:54 108-90-7 Chloroethane NO mg/L 0.0020 1 05/20/14 02:54 75-00-3 2-Chloroethylvinyl ether ND mg/L 0.0050 1 0512011402:54 110-75-8 Chloroform ND mg/L 0.0020 1 05/20/14 02:54 67-66-3 Chloromethane NO mg1L 0,0020 1 05/20/14 02:54 74-87-3 2-Chlorotoluene NO mg/L 0.0020 1 05/20/14 02:54 95-49-8 4-Chlorotoluene NO mg/L 0.0020 1 05/20/14 02:54 106-43-4 Dibromochloromethane NO mg/L 0.0020 1 05/20/14 02:54 124-48-1 1,2-Dibromoethane (EDB) NO mg/L 0.0020 1 05/20/14 02:54 106-93-4 Dibromomethane NO mg/L 0.0020 1 05/20/14 02:54 74-95-3 1,2-Dichlorobenzene NO mg/L 0.0020 1 05/20/14 02:54 95-50-1 1,3-Dichlorobenzene NO mg/L 0,0020 1 05/20/14 02:54 541-73-1 1,4-Dichlorobenzene ND mg/L O,0020 1 05/20/14 02:54 106-46-7 1,1-Dichloroethane NO mg/L 0.0020 1 05/20/14 02:54 75-34-3 1,27Dichloroethane ND mg/L 0.0020 1 05/20/14 02:54 107-06-2 1.1-Dichloroethene ND mg/L 0.0020 1 05/20/14 02:54 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. Page 7 of 51 aceAnalytical I 'wrrnpatelab5.com; ANALYTICAL RESULTS Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: Storm Water Testing Pace Project No.: 92201481 Sample: SOO 7 Lab 10: 92201481001 Collected! 05/15/14 11:50 Received: 05/15/14 13:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 624 Volatile Organics Analytical Method: EPA 624 cis-1,2-Dichloroethene ND mg/L 0.0020 1 05/20/14 02:54 156-59-2 trans- 1, 2- D ichlo roethe ne ND mg/L 0.0020 1 05/20/14 02:54 156-60-5 1,2-Dichloropropane ND mg/L 0.0020 1 05/20/14 02:54 78-87-5 1,3-Dichloropropane ND me/L 0.0020 1 05/20/14 02!54 142-28-9 2,2-Dichloropropane ND mg1L 0.0050 1 05/20/14 02:54 594-20-7 1,1-Dichloropropene NO mg/L 0.0020 1 0512011402:54 563-53-6 cis-1,3-Dichloropro pene NO mg/L 0.0020 1 05/20/14 02:54 10061-01-5 trans-1,3-Dichloropropene ND mg/L 0.0020 1 05/20/14 02:54 10061-02-6 Ethylbenzene ND mg/L 0.0020 1 0512011402:54 100-41-4 Hexachloro-1,3-butadiene ND mg/L 0.0050 1 05/20/14 02:54 87-68-3 2-Hexanone ND mglL 0.010 1 05/20/14 02:54 591-78-6 lodomethane ND mg/L 0.010 1 05/20/14 02:54 74-88-4 L2 isopropyl benzene (Cumene) NO mg/L 0.0050 1 0512011402:54 98-82-8 p-Isopropyltoiuene ND mg/L 0.0050 1 05/20/14 02:54 99-87-6 Methylene Chloride ND mg/L 0.0020 1 05/20/14 02:54 75-09-2 4-Methyl-2-pentanone (MIBK) ND mg1L 0.010 1 05/20/14 02:54 108-10-1 Methyl-tert-butyl ether ND mg/L 0.0050 1 05/20/14 02:54 1634-04-4 Naphthalene "ND rnglL 0:0050- I 05r2011402:54 91-20-3 n-Propylbenzene ND mg/L 0.0050 1 05/20/14 02:54 103-65-1 Styrene ND mg/L 0.0020 1 05/20/14 02:54 100-42-5 1,1,1,2-Tetrachloroethane ND mg/L 0.0020 1 05/20/14 02:54 630-20-6 1,1,2,2-Tetrachloroethane ND mg/L 0.0020 1 05/2011402:54 79-34-5 Tetra chloroeth ene NO ma/L 0.0020 1 05/20/14 02:54 127-18-4 Toluene NO mg/L 0.0020 1 05/20/14 02:54 108-88-3 1,2.3-Trichlorobenzene NO mg/L 0.0020 1 05/20/14 02:54 87-61-6 1,2,4-Trichlorobenzene NO mg/L 0.0020 1 05/20/14 02:54 120-82-1 1,1,1-Trichloroethane ND mg/L 0.0020 1 05/20/14 02:54 71-55-6 1,1,2-Trichloroethane ND mg/l_ 0.0020 1 05/20/14 02:54 79-00-5 Trichloroethene ND mg/L 0.0020 1 05/20/14 02:54 79-01-6 Trich loroRuoromethane ND mg/L 0.0020 1 05/20/14 02:54 75-69-4 1,2,3-Trichloropropane ND mg/L 0.0020 1 0512011402:54 96-18-4 1,1,2-Trichlorotrifluoroeth2ne ND mg1L 0.0020 1 05/20/14 02:54 76-13-1 1,2,4-Trimethylbenzene NO mg/L 0.0020 1 05/20/14 02:54 95.63-6 1,3,5-Trime thy] benzene ND mg/L 0.0020 1 05/20/14 02:54 108-67-8 Vinyl acetate ND mg1L 0.0050 1 05/20/14 02:54 108-05-4 Vinyl chloride ND mg1L 0.0020 1 05/20/14 02:54 75-01-4 m&p-Xylene ND mg/L 0.0050 1 05/20/14 02:54 179601-23-1 o-Xylene NO mg/L 0.0050 1 05/20/14 02:54 95-47-6 Surrogates 4-Bromofluorobenzene (S) 89 % 70-130 1 05/20/14 02:54 460-00-4 Toluene-d8 (S) 98 % 70-130 1 05/20/14 02:54 2037-26-5 1,2-Dichloroethane-d4 (S) 104 % 70-130 1 05/20/14 02:54 17060-07-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. Page 8 of 51 aceAnalytical .vwwpacerabs.mm: ANALYTICAL RESULTS Project: Storm Water Testing Pace Project No.: 92201481 Pace Analytical Services, Inc. 2G5 East Meadow Road - Suite A Eden, NC 27288 (336)623-,'921 Sample: SDO 8 Lab 117; 92201481002 Coilected: 05/15/14 12:00 Received: 05/15/14 13:45 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Dual 2540D Total Suspended Solids Total Suspended Solids 1664 SGT-HEM, TPH Total Petroleum Hydrocarbons 608 GCS Pesticides and PCBs Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC (Lindane) Chlordane (Technical) 4,4'-DDD 4,4'-DDE 4,4'-DDT Dieldrin Endosuifan i Endosulfah sulfate- Endrin Endrin aldehyde Heptachlor Heptachlor epoxide PCB-1016 (Aroclor 1016) PCB-1221 (Aroclor 1221) PCB-1232 (Aroclor 1232) PCB-1242 (Aroclor 1242) PCB-1248 (Aroclor 1248) PCB-1254 (Aroclor 1254) PCB-1260 (Aroclor 1260) Toxaphene Surrogates Tetra chloro-m-xylen e (S) Decachlorobiphenyl (S) 200.7 MET ICP Copper Lead Zinc 625 MSSV Acenaphthene Acenaphthylene Acetophenone Aniline Anthracene Analytical Method: SM 2540D 19.4 mg/L 2.5 1 Analytical Method: EPA 1664E 05/19/14 09:49 ND mg/L 5.0 1 05/2011410:07 Analytical Method: EPA 608 Preparation Method: EPA 3510 NO mg/L 0.000050 1 05/21/14 17:55 05/27/14 20:27 309-00-2 NO mg/L 0.000050 1 05/21/14 17:56 05/27/14 20:27 319-84-6 NO mg/L 0.000050 1 05/21/14 17:55 05/27/14 20:27 319-85-7 NO mg/L 0.000050 1 05/21/14 17:55 05/27/14 20:27 319-86-8 NO mg/L 0.000050 1 05/21/14 17:55 05/27/14 20:27 58-89-9 ND mg/L 0.00050 1 05/21/14 17:55 05/2711420:27 57-74-9 NO mg/L 0.000050 1 05/21/14 17:55 05/27/14 20:27 72-54-8 NO mg/L 0.000050 1 05/21/14 17:55 05/27/14 20:27 72-55-9 NO mg1L 0.000050 1 05/21/14 17:55 05/27/14 20:27 50-29-3 NO mg/L 0.000050 1 05/21/14 17:55 05/27/14 20:27 60-57-1 ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 20:27 959-98-8 NO mglL 0.000056 - '051211'14.17:55 05/27/14 20:27 33213-65-9 -. NO mg/L 0.000050 1 05/21/14 17:55 05/27/14 20:27 1031-07-8 ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 20:27 72-20-8 0.000052 mg/L 0,000050 1 05/21/14 17:55 05/27/14 20:27 7421-93-4 NO mg/L 0,000050 1 05/21/14 17:55 05/27/14 20:27 76-44-8 NO mg1L 0.000050 1 05/21/14 17:55 05/27/14 20:27 1024-57-3 NO mg/L 0.00050 1 05/21/14 17:55 05/27/14 20:27 12674-11-2 NO mg/L 0.00050 1 05/21/14 17:55 05/27/14 20:27 11104-28-2 NO mg/L 0.00050 1 05/21/14 17:55 05/27/14 20:27 11141-16-5 NO mg/L 0.00050 1 05/21/14 17:55 05/27/14 20:27 53469-21-9 NO mg/L 0.00050 1 05/21/14 17:55 05/27/14 20:27 12672-29-6 ND mg/L O.00050 1 05/21/14 17:55 05/27/14 20:27 11097-69-1 ND mg/L 0.00050 1 05/21/14 17:55 05/27/14 20:27 11096-82-5 NO mg1L 0.00050 1 05/21/14 17!55 05/27/14 20:27 8001-35-2 46 % 20-110 1 05/21/14 17:55 05/27/14 20:27 877-09-8 32 % 20-133 1 05/21/14 17:55 05/27/14 20:27 2051-24-3 Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 ND mg/L 0.0050 1 05/19/14 18:00 05/22/14 22:41 7440-50-8 NO mg/L 0.0050 1 05/19/14 18:00 05/22/14 22:41 7439-92-1 0.028 mg/L 0.010 1 05/19/14 18:00 05/22/14 22:41 7440-66-6 Analytical Method: EPA 625 Preparation Method: EPA 625 NO mg/L 0.0053 1 05/19/14 13:35 05/21/14 05:35 83-32-9 ND mg/L 0.0053 1 05/19/14 13:35 05/21/14 05:35 208-96-8 ND mg/L 0.0053 1 05/19/14 13:35 05/21/14 05:35 98-86-2 ND mg1L 0.011 1 05/19/14 13:35 05/21/14 05:35 62-53-3 NO mg(L 0.0053 1 05/19/14 13:35 05/21/14 05:35 120-12-7 Date: 05/28/2014 01:18 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Face Analytical Services, Inc.. Page 9 of 51 d aC6Analytical www.Pac&.7bs.cck",- ANALYTICAL RESULTS Project: Storm Water Testing Pace Project No.: 92201481 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (338)623-8921 Sample: SDO 8 Parameters Lab lD: 92201481002 Results Units Collected: 05/15/14 12:00 Report Limit DF Received: 05115/14 13:45 Matrix: Water Prepared Analyzed CAS No. Qual 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 Benzidine ND ma/L 0.053 1 0511911413!35 05121/1405:35 92-87-5 Benzo(a)anthracene ND ma/L 0.0053 1 0511911413:35 05/2111405:35 56-55-3 Benzo(a)pyrene ND mg/L 0.0053 1 05/19/14 1135 05/21/14 05:35 50-32-8 Benzo(b)fluoranthene ND mg/L 0.0053 1 05/19/14 13:35 05/21/14 05:35 205-99-2 Benzo(g,h,i)perylene ND mg/L 0,0053 1 05/19/14 13:35 05/21/14 05:35 191-24-2 Benzo(k)fluoranthene ND mg1L 0.0053 1 05/19/14 13:35 05/21/14 05:35 207-08-9 4-Bromophenylphenylether ND mg/L 0,0053 1 05/19/141135 0512111405:35 101-55-3 Butyibenzyiphthalate ND mg/L 0,0053 1 05/19/14 13:35 05/21/14 05:35 85-68-7 4-Chloro-3-methylphenol ND mg/L 0.0053 1 05/19/14 13:35 05/21/14 05:35 59-50-7 bis(2-Chloroethoxy)methane ND mg/L 0.011 1 05/1911413:35 05/21/14 05:35 111-91-1 bis(2-Chloroethyl) ether ND mg/L 0.0053 1 05/19/14 13:35 05/21/14 05:35 111-44-4 bis(2-Chloroisopropyl) ether ND mg/L 0.0053 1 05/19/14 13:35 05/21/14 05:35 108-60-1 2-Chloronaphthalene ND mg/L 0.0053 1 o5/19114 13:35 05/21/14 05:35 91-58-7 2-CNorophenol ND mg/L 0.0053 1 05/19/14 13:35 05/21/14 05:35 95-57-8 4-Chlorophenylphenyl ether ND mg/L 0.0053 1 05/19/14 13:35 05/21/14 05:35 7005-72-3 Chrysene ND mg/L 0.0053 1 05/19/14 13:35 05/21/14 05:35 218-01-9 Dibenz(a,h)anthracene ND mg/L 0.0053 1 05/19/14 13:35 05/21/14 05:35 53-70-3 -.,1,2:Dichlorobenzene ND mg/L 0.0053 -1- • 05/19/14 13:35 05/21/14 05:35 95-50-1 - - 1,3-Dichlorobenzene ND mg/L 0,0053 1 05119/14 13:35 05/21/14 05:35' 541-73-1" 1,4-Dichlorobe nzene ND mg/L 0.0053 1 05/19/14 13:35 05/21/14 05:35 106-46-7 3,3'-Dichlorobenzidine ND mg/L 0.026 1 05/19/14 13:35 05/21/14 05:35 91-94-1 2,4-Dichlorophenol ND mg/L 0.0053 1 05/19/14 13:35 05/21/14 05:35 120-83-2 Diethyiphthalate ND mglL 0.0053 1 05/19/14 13:35 05/21/14 05.35 84-66-2 2,4-Dimethylphenol ND mg/L 0.011 1 05/19/14 13.35 05/21/14 05:35 105-67-9 Dimethylphthalate ND mg/L 0.0053 1 05/19/14 13:35 05/21/14 05:35 131-11-3 Di-n-butyiphthalate ND mg/L 0.0053 1 05/19/14 13:35 05/21/14 05:35 84-74-2 4,6-Dinitro-2-methylphenol ND mg/L 0.021 1 05/19/14 13:35 05/21/14 05:35 534-52-1 2,4-Dinitrophenol ND mg/L 0.053 1 05/19/14 13:35 05/21/14 05:35 51-28-5 2,4-Dinitrotoiuene ND mg/L 0.0053 1 05/19/14 13:35 05/21/14 05:35 121-14-2 2,6-Dinitrotoluene ND mg/L 0.0053 1 05/19/14 13:35 05/21/14 05:35 606-20-2 Di-n-octylphthalate ND mg/L 0.0053 1 05/19/14 13:35 05/21/14 05:35 117-84-0 1,2-Diphenylhydrazine ND mg/L 0.0053 1 05/19/14 13:35 05/21/14 05:35 122-66-7 bis(2-E thyl hexyl) phtha late ND mg/L 0.0053 1 05/19/14 13:35 05/21/14 05:35 117-81-7 Fluoranthene ND mg/L 0.0053 1 05/19/14 13:35 05/21/14 05:35 206-44-0 Fluorene ND mg/L 0.0053 1 05/19/14 13:35 05/21/14 05:35 86-73-7 Hexachloro-1,3-butadiene ND mg/L 0.0053 1 05/19/14 13:35 05/21/14 05:35 87-68-3 Hexachlorobenzene ND mg/L 0.0053 1 05/19/14 13:35 05/21/14 05:35 118-74-1 H exa chlorocyclo pentad iene ND mg1L 0.011 1 05/19/14 13:35 05/21/14 05:35 77-47-4 Hexachloroethane ND mglL 0.0053 1 05/19/14 13.35 05/21/14 05:35 67-72-1 Indeno(1,2,3-cd)pyrene ND mg/L 0,0053 1 05/19/14 13:35 05/21/14 05:35 193-39-5 Isophorone ND mg/L 0.011 1 05/19/14 13:35 05/21/14 05:35 78-59-1 Naphthalene ND mg/L 0.0053 1 05/19/14 13:35 05/21/14 05:35 91-20-3 Nitrobenzene NO mg/L 0.0053 1 05/19/14 13:35 05/21/14 05:35 98-95-3 2-Nitrophenol ND mg1L 0.0053 1 05/19/14 13:35 05/21/14 05:35 88-75-5 4-Nitrophenol ND mg/L 0,053 1 05/19/14 13:35 05/21/14 05:35 100-02-7 N-Nitrosodimethylamine ND mg/L 0.0053 1 05/19/14 13:35 05/21/14 05:35 62-75-9 N-Nitroso-di-n-propylamine ND mg/L 0.0053 1 05/19/14 13:35 05/21114 05:35 621-64-7 REPORT OF LABORATORY ANALYSIS This report shali not be reproduced, except in full, Date: 05/28/2014 0 1: 18 PM without the written consent of Pace Analytical Services, Inc.. Page 10 of 51 aceAnalytical www.AacelaSs.ron_ ANALYTICAL RESULTS Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-g921 Project: Storm Water Testing Pace Project No.: 92201481 Sample: SDO 8 Lab 1D: 92201481002 Collected: 05/15/14 12:00 Received: 05/15/14 13:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 N-Nitrosodiphenyiamine ND mg/L 0.011 1 05/19/14 13:35 05/21/14 05:35 86-30-6 Pentachlorophenol ND mg/L 0.011 1 05/19/14 13:35 05/21/14 05:35 87-86-5 Phenanthrene ND mg/L 0.0053 1 05/19/14 13:35 05/21/14 05:35 85-01-8 Phenol ND mg/L 0.0053 1 05/19/14 13:35 05/21/14 05:35 108-95-2 Pyrene ND mg/L 0.0053 1 05/19/14 13:35 05/21/14 05:35 129-00-0 1,2,4-Trichlorobenzene ND mg/L 0.0053 1 05119/14 13:35 05/21/14 05:35 120-82-1 2,4.6-Trichlorophenol ND mg/L 0.011 1 05/19/14 13:35 05/21/14 05:35 88-06-2 Surrogates Nitrobenzene-d5 (S) 62 % 10-120 1 05/19/14 13:35 05/21/14 05:35 4165-60-0 2-Fluorobiphenyl (S) 65 % 15-120 1 05/19/14 13:35 05/21/14 05:35 321-60-8 Terphenyl-d14 (S) 80 % 11-131 1 05/19/14 13:35 05/21/14 05:35 1718-51-0 Phenol-d6 (S) 25 % 10-120 1 05/19114 13:35 05/21/14 05:35 13127-85-3 2-Fiuorophenol (S) 39 % 10-120 1 05/19/14 13:35 05/21/14 05:35 367-12-4 2,4,6-Tribromophenol (S) 103 % 10-137 1 05/19/14 13:35 05/21/14 05:35 118-79-6 624 Volatile Organics Analytical Method: EPA 624 Acetone ND mg/L 0.010 1 05/20/14 03:11 67-64-1 -Acrolein - -ND rng/L -0.0050 i 05120/14 03:11 107-02-$ Acrylonitrile NO rrig/1. 0.050 1 05/20/14 03:11 107-13-1 Benzene ND mg/L 0.0020 1 05/201/4 03:11 71-43-2 Bromobenzene ND mg/L 0.0020 1 05/20/14 03:11 108-86-1 BromocNoromethane ND mg/L 0.0020 1 05/20/14 03:11 74-97-5 Bromod ichloro methane ND mg/L 0.0020 1 05/20/14 03:11 75-27-4 Bromoform ND mg/L 0.0020 1 05/20/14 03:11 75-25-2 Bromomethane ND mg1L 0.0020 1 05/20/14 03:11 74-83-9 2-Butanone (MEK) ND mglL 0.0050 1 05/20/14 03:11 78-93-3 n-Butylbenzene ND mg/L 0.0050 1 05/20/14 03:11 104-51-8 sec-Butylbenzene ND mg/L 0.0050 1 05/20/14 03:11 135-98-8 te rt-B utyl benzene ND mg/L 0.0050 1 05/20/14 03:11 98-06-6 Carbon disulfide ND mg/L 0.0050 1 05/20/14 03:11 75-15-0 Carbon tetrachloride ND mg/L 0.0020 1 05/20/14 03:11 56-23-5 Chiorobenzene ND mg/L 0.0020 1 05/20/14 03:11 108-90-7 Chloroethane ND mg/L 0.0020 1 05/20/14 03:11 75-00-3 2-Chloroethylvinyl ether ND mg1L 0.0050 1 05/20/14 03:11 110-75-8 Chloroform ND mg1L 0.0020 1 05/20/14 03:11 67-66-3 Chloromethane ND mg/L 0.0020 1 05/20/14 03:11 74-87-3 2-Chlorotoluene ND mg/L 0.0020 1 05/20/14 03:11 95-49-8 4-Chlorotoluene ND mg1L 0.0020 1 05/20/14 03:11 106-43-4 Dbromochloromethane ND mg/L 0.0020 1 05/20/14 03:11 124-48-1 1,2-Dibromoethane (EDB) ND mg/L 0,0020 1 05/20/14 03:11 106-93-4 Dibromomethane ND mg/L 0.0020 1 05/20/14 03:11 74-95-3 1.2-Dichlorobenzene ND mg/L 0.0020 1 05/20/14 03:11 .95-50-1 1,3-Dichlorobenzene ND mg1L 0.0020 1 05/20/14 03:11 541-73-1 1,4-Dichlorobenzene ND mg1L 0.0020 1 05/20/14 03:11 106-46-7 1,1-Dichloroethane ND mg/L 0.0020 1 05/20/14 03:11 75-34-3 1,2-Dichloroethane ND mglL 0.0020 1 05/20/14 03:11 107-06-2 1,1-Dichloroethene ND mg/L 0.0020 1 05/20/14 03:11 75-35-4 L3 REPORT OF LABORATORY ANALYSIS This report shaii not be reproduced, except in full, Date: 05/28/2014 01:18 PM _ without the written corsent of Pace Analytical Services, Inc.. Page 11 of 51 aceAnalytical ".w.AacelabS.cGn ANALYTICAL RESULTS Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: Storm Water Testing Pace Project No.: 92201481 Sample: SDO 8 Lab 1D: 92201481002 Collected: 05/15/14 12:00 Received: 05/15/14 13:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[ 624 Volatile Organics Analytical Method: EPA 624 cis- 1,2-Dichloroethene NO mg/L 0.0020 1 0512011403:11 156-59-2 trans-1,2-Dichloroethene NO mg1L 0.0020 1 0512011403:11 156-60-5 1,2-Dichloropropane NO mg/L 0.0020 1 05120/1403:11 78-87-5 1,3-Dichloropropane NO mg/L 0.0020 1 05/20/14 03:11 142-28-9 2,2-Dichloropropane NO mg/L 0.0050 1 05/20/14 03:11 594-20-7 1,1-Dichloropropene ND mg/L 0.0020 1 05120/1403:11 563-58-6 cis-1,3-Dichloropropene ND mg1L 0.0020 1 05/20/14 03:11 10061-01-5 trans- 1, 3-Dichloroprope ne ND mg/L 0.0020 1 05/20/14 03:11 10061-02-6 I*thylbenzene ND mg/L 0.0020 1 05/20114 03:11 100-41-4 Hexachloro-1,3-butadiene ND mg/L 0.0050 1 05/20/14 03:11 87-68-3 2-Hexanone ND mg/L 0.010 1 05/20/14 03:11 591-78-6 lodomethane ND mg/L 0.010 1 05/20/14 03:11 74-88-4 L2 Isopropylbenzene (Cumene) ND mg/L 0.0050 1 05/20/14 03:11 98-82-8 p-lsopropyltoluene ND mg/L 0,0050 1 05/20/14 03:11 99-87-6 Methylene Chloride ND mg/L 0,0020 1 05/20/14 03:11 75-09-2 4-Methyl-2-pentanone (MIBK) ND mg/L 0.010 1 05/20/14 03:11 108-10-1 Methyl -tent -butyl ether NO mg/L 0.0050 1 05/20/14 03:11 1634-04-4 _ Naphthalene ... NO'_mo/C ' 0,0050 1 ._'.05120114 03:11 91-20-3 n-Propylbenzene 'ND mg1L 0.0050 1 05/20i1403:11 103-65-1 Styrene ND mg/L 0.0020 1 05/20/14 03:11 100-42-5 1,1,1,2-Tetrachloroethane ND mg/L 0.0020 1 05/20/14 0111 630-20-6 1,1,2,2-Tetrachloroethane ND mg/L 0.0020 1 05/20/14 03:11 79-34-5 Tetrachloroethene ND mg/L 0.0020 1 05/20/14 03:11 127-18-4 Toluene NO mg/L 0.0020 1 05/20/14 03:11 108-88-3 1,2,3-Trichlorobenzene NO mg/L 0,0020 1 05/20/14 03:11 87-61-6 1,2,4-Trichlorobe nzene ND mg1L 0.0020 1 05/20/14 03:11 120-82-1 1,1,1-Trichlorcethane ND mg/L 0.0020 1 05/20/14 03:11 71-55-6 1,1,2-Trichlorcethane ND mg/L .0.0020 1 05/20/14 03:11 79-00-5 Trichloroethene ND mg/L 0.0020 1 05/20/14 03,11 79-01-6 Trichlorofluoromethane ND mg/L 0.0020 1 05/20/14 03:11 75-69-4 1,2,3-Trichloropropane NO mg/L 0.0020 1 05120/14 03:11 96-18-4 1, 1, 2-Trichlorotrifluoroethane NO mg/L 0.0020 t 0512011403:11 76-13-1 1,2,4-Trimethylbenzene NO mg/L 0,0020 1 05/20/14 03:11 95-63-6 1,3,5-Trimethylbenzene NO mg/L 0.0020 1 05/20/14 03:11 108-67-8 Vinyl acetate NO mg/L 0.0050 1 05/20/14 03:11 108-05-4 Vinyl chloride NO mg/L 0.0020 1 05/20/14 03:11 75-01-4 m&p-Xyiene ND mg/L 0.0050 1 05/20/14 03:11 179601-23-1 o-Xylene ND mg/L 0.0050 1 05/20/14 03:11 95-47-6 Surrogates 4-Bromvfluorobenzene (S) 88 % 70-130 1 05/20/14 03:11 460-00-4 Toluene-d8 (5) 97 % 70-130 1 05/20/14 03:11 2037-26-5 1,2-Dichloroethane-d4 (S) 103 % 70-130 1 05I20114 03:11 17060-07-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. Page 12 of 51 O aceAnalylical vrww.paselaSs.rom; f ANALYTICAL RESULTS Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: Storm Water Testing Pace Project No.: 92201481 Sample: SDO 9 Lab fD: 922014E1003 Coliected: 05/15/14 12:15 Received: 05/15/14 13:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 35.3 mg/L 3.6 1 05/19/14 09:49 1664 SGT-HEM, TPH Analytical Method: EPA 1664B Total Petroleum Hydrocarbons ND mg/L 5.0 1 05/20/14 10:08 608 GCS Pesticides and PCBs Analytical Method: EPA 608 Preparation Method: EPA 3510 Aldrin ND mg/L 0.000050 1 05121114 17:55 O5/27/14 20:46 309-00-2 alpha-BHC ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 20:46 319-84-6 beta-BHC ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 20:46 319-85-7 delta-BHC ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 20:46 319-36-8 gamma-BHC (Lindane) ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 20:46 58-89-9 Chiordane (Technical) ND mg/L 0.00050 1 05/21/14 17:55 05/27/14 20:46 57-74-9 4,4'-DDD ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 20:46 72-54-8 4,4'-DDE ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 20:46 72-55-9 4,4'-DDT ND mg/L 0,000050 1 05/21/14 17:55 05/27/14 20:46 50-29-3 Dieldrin ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 20A6 60-57-1 Endost�lfan ! ND ma/L 0.000050 1 05/21/14 17:55 05/27/14 20:46 969-98-8 Endosu:`a.^. !! ND mg/L 0.000050 . 1 05/211.14 17:55 05/27/14 20:46 33213-65-9 Endosulfan sulfate ND mg/L 0,000050 1 05/21114 17.:55 05/27/14 20:46 1031-07-8 Endrin ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 20:46 72-20-8 Endrin aldehyde ND mglL 0.000050 1 05/21/14 17:55 05/27/14 20:46 7421-93-4 Heptachlor ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 20:46 76-44-8 Heptachlor epoxide ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 20:46 1024-57-3 PCB-1016 (Aroclor 1016) ND mg/L 0.00050 1 05/21/14 17:55 05/27/14 20:46 12674-11-2 PCB-1221 (Aroclor 1221) ND mg/L 0.00050 1 05/21/14 17:55 05/27/14 20:46 11104-28-2 PCB-1232 (Aroclor 1232) ND mg/L 0.00050 1 05/21/14 17:55 05/27/14 20:46 11141-16-5 PCB-1242 (Aroclor 1242) ND mg/L 0.00050 1 05/21/14 17:55 05/27/14 20:46 53469-21-9 PCB-1248 (Aroclor 1248) ND mg/L 0.00050 1 05/21/14 17:55 05/27/14 20:46 12672-29-6 PCB-1254 (Aroclor 1254) ND mg/L 0.00050 1 05/21/14 17:55 05/27/14 20:46 11097-69-1 PCB-1260 (Aroclor 1260) ND mg/L 0.00050 1 05/21/14 17:55 05/27/14 20:46 11096-82-5 Toxaphene ND mg/L 0.00050 1 05/21/14 17:55 05/27/14 20:46 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 56 % 20-110 1 05/21/14 17:55 05/27/14 20:46 877-09-8 Decachlorobiphenyl (S) 50 % 20-133 1 05/21/14 17:55 05/27/14 20:46 2051-24-3 200.7 MET ICP Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 Copper ND mg/L 0.0050 1 05/19/14 18:00 05/22/14 22:44 7440-50-8 Lead ND mg/L 0.0050 1 05/19/14 18:00 05/22/14 22:44 7439-92-1 Zinc 0.031 mg/L 0.010 1 05/19/14 18:00 05/22/14 22:44 7440-66-6 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 Acenaphthene ND mg/L 0,0050 1 05/19/14 13:35 06/21/14 06:04 83-32-9 Acenaphthylene ND me/L 0.0050 1 05/19/1413:35 0512111406:04 208-96-8 Acetophenone Nil mg/L 0.0050 1 05/19/14 13:35 05/21/14 06:04 98-86-2 Aniline ND mg/L 0.010 1 05/19/14 13:35 05/21/14 06:04 62-53-3 Anthracene NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 06:04 120-12-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. Page 13 of 51 Anal ical � ace yi wvw.�cela65.cnm: 1 1 ANALYTICAL RESULTS Project: Storm Water Testing Pace Project No.: 92201481 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336 )623-8921 Sample: SDO 9 Parameters Lab 10: 92201481003 Results Units Collected: 05115/14 12:15 Report Limit DF Received: 05/15/14 13:45 Matrix: Water Prepared Analyzed CAS No. Qua! 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 Benzidine ND mg/L 0.050 1 05119/1413:35 05121/1406:04 92-87-5 Benzo(a)anthracene ND mg/L 0.0050 1 05/1911413:35 05/21/14 06:04 56-55-3 Benzo(a)pyrene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 06:04 50-32-8 Benzo(b)fluoranthene ND mg/L o.0050 1 05/19/1413:35 05121/1406:04 205-99-2 Benzo(g,h,i)perylene ND mglL 0.0050 1 05/19/14 13:35 05/21/14 06:04 191-24-2 Benzo(k)fluoranthene ND mg/L 0.0050 1 05119/1413:35 05121/1406:04 207-08-9 4-Bromophenylphenyl ether ND mglL 0.0050 1 05/19/14 13:35 05/21/14 06:04 101-55-3 Butylbenzylphthalate ND mg/L 0.0050 1 05119/1413:35 05/21/14 06:04 85-68-7 4-Chloro-3-methylphenol ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 06:04 59-60-7 bis(2-Chloroethoxy)methane ND mg1L 0.010 1 05119/1413:35 05/21/14 06:04 111-91-1 bis(2-Chloroethyl) ether ND mg1L 0.0050 1 05/19/14 13:35 05/21/14 06:04 111-44-4 bis(2-Chloroisopropyl)ether ND mg/L 0.0050 1 05119/1413:35 05/21/14 06:04 108-60-1 2-Chloronaphthalene ND mg1L 0.0050 1 05/19/14 13:35 05/21/14 06:04 91-58-7 2-Chiorophenol ND mg/L 0.0050 1 0511911413:35 05/21/14 06:04 95-57-8 4-Chlorophenylphenylether ND malL 0,0050 1 05/1911413:35 05/2111406:04 7005-72-3 Chrysene ND mg/L 0,0050 1 05/19/14 13:35 05/21/14 06:04 218-01-9 Dibenz(a,h)anthracene ND mg/L 0.0050 1 05/19/14 13:35 05/2111406:04 53-70-3 1,2-0ichlorobenzene ND mg/L 0.0050,_.."'T" - 05/1911413:35 05/2111406:04 95-50-1 1,3-Dich lo robe nzene ND mg/L 0.0050, 1 05119/1413:35 05121/1406:04 541-73-1 1,4-Dichlorobe nzene ND mg/L 0.0050 1 05/19/14 13:35 05121/1406:04 106-46-7 3,3'-Dichlorobenzidine ND mg/L 0.025 1 05/19/14 13:35 05/21/14 06:04 91-94-1 2,4-Dichlorophenol ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 06:04 120-83-2 Diethylphthalate ND mg/L 0.0050 1 05119/1413:35 05121/1406:04 84-66-2 2,4-Dimethylphenol ND mg/L 0.010 1 05/19/14 13:35 05/21/14 06:04 105-67-9 Dimethylphthalate ND mg/L 0.0050 1 05119/1413:35 05/2111406:04 131-11-3 Di-n-butylphthalate ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 06:04 84-74-2 4,6-D initro-2-methyl phenol ND mg/L 0.020 1 05/19/14 13:35 05/21/14 06:04 534-52-1 2,4-Dinitro phenoI ND mg/L 0.050 1 05/19/14 13:35 05/21/14 06:04 51-28-5 2,4-Dinitro toluene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 06:04 121-14-2 2,6-Dinitrctoluene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 06:04 606-20-2 Di-n-o ctylphtha late ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 06:04 117-84-0 1,2-Diphenylhydrazine ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 06:04 122-66-7 bis(2-Ethylhexy1)phthala1e ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 06:04 117-81-7 Fluoranthene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 06:04 206-44-0 Fluorene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 06:04 86-73-7 Hexachloro-1,3-butadiene ND mg/L 0.0050 1 05/19/14 13:35 0512VI4 06:04 87-68-3 Hexachlorobenzene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 06:04 118-74-1 H exa chlorocyclope ntadiene ND mg/1- 0,010 1 05/19/14 13:35 05/21/14 06:04 77-47-4 Hexachloroethane ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 06:04 67-72-1 1ndeno(1,2,3-cd)pyre ne ND mg/L 0,0050 1 05/19/14 13:35 05/21/14 06:04 193-39-5 isophorone ND mg/L 0.010 1 05/19/14 13:35 05/21/14 06:04 78-59-1 Naphthalene ND mg1L 0.0050 1 05/19/14 13:35 06/21/14 06:04 91-20-3 Nitrobenzene ND mg/L 0.0050 1 05/19/14 1135 05/21/14 06:04 98-95-3 2-Nitrophenol ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 06:04 88-75-5 4-Nitrophenol ND mg/L 0.050 1 0511911413:35 05121/1406:04 100-02-7 N-Nitrosodimethylamine ND mg1L 0,0050 1 0511911413:35 05121/1406:04 62-75-9 N-Nitroso-di-n-propylamine ND mg1L 0.0050 1 05119/1413:35 05/21/14 06:04 621-64-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the wri-tten consent of Pace Analytical Services, Inc.. Page 14 of 51 Analytical' Ymw.p3�lab5:CCY:+_ 1 ANALYTICAL RESULTS Project: Storm Water Testing Pace Project No.: 92201481 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336 )623-8?21 Sample: SOO 9 Parameters Lab ID: 92201481003 Collected: 05/15/14 12:15 Results Units Report Limit DF Received: 05/15/14 13:45 Matrix: Water Prepared Analyzed CAS No. Qual 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 N-Nitrosodiphenylamine NO mg/L 0.010 1 05/19/14 13:35 05/21/14 06:04 86-30-6 Pentachlorophenol ND mg1L 0.010 1 05/19/14 13:35 05/21/14 06:04 87-86-5 Phenanthrene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 06:04 85-01-8 Phenol NO mg1L 0.0050 1 05/19/14 13:35 05/21/14 06:04 108-95-2 Pyrene NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 06:04 129-00-D 1,2,4-Trichlorobenzene ND mg/L 0.0050 1 05119/1413:35 05/2111406:04 120-82-1 2,4,6-Trichlorophenol NO mg/L 0.010 1 05/19/14 13:35 05/21/14 06:04 88-06-2 Surrogates Nitrobenzene-d5 (S) 61 % 10-120 1 05/19/14 13:35 05121/1406:04 4165-6C-0 2-Fluorobiphenyl(S) 65 % 15-120 1 0511911413:35 05/21/14 06:04 321-60-8 Terphenyi-d14 (S) 82 % 11-131 1 05/19114 13:35 05/21/14 06:04 1718-51-0 Phenol-d6 (S) 25 % 10-120 1 05/19/14 13:35 05/21/14 06:04 13127-88-3 2-Fluorophenol (S) 35 % 10-120 1 05/19/14 13:35 05/21/14 06:04 367-12-4 2,4,6-Tribromophenol (S) 95 % 10-137 1 05/19/14 13:35 05/21/14 06:04 118-79-6 624 Volatile Organics Analytical Method: EPA 624 Acetone ND mg/L 0.010 1 05/20/14 03:27 67-64-1 --,Acrolein^ ....... - -ND -rg/L 0,0050, -.1. 05/20/14 03:27 107-02-8 Ac, y lonitrile ND mg1L 0.050' ' 1 05/20/14 03:27 i 07-13-1 Benzene ND mg/L 0.0020 1 05/20/14 03:27 71-43-2 Bromobenzene NO mg/L 0.0020 1 05/20/14 03:27 108-86-1 Bromochloromethane ND mg/L 0.0020 1 05/20/14 03:27 74-97-5 Bromodichloromethane ND mg/L 0.0020 1 05/20/14 03:27 75-27-4 Bromoform NO mg/L 0.0020 1 05/20/14 03:27 75-25-2 Bromomethane NO mg1L 0.0020 1 05/20/14 03:27 74-83-9 2-Butanone (MEK) NO mg/L 0.0050 1 05/20114 03:27 78-93-3 n-Butylbenzene NO mg/L 0.0050 1 05/20/14 03:27 104-51-8 sec-Butylbenzene NO mg1L 0.0050 1 05/20/14 03:27 135-98-8 tert-Butylbenzene ND mg/L 0.0050 1 05/20/14 03:27 98-06-6 Carbon disulfide NO mg/L 0.0050 1 05I20/14 03:27 75-15-0 L3 Carbon tetrachloride ND mg/L 0.0020 1 05/20/14 03:27 56-23-5 Chlorobenzene NO mglL 0.0020 1 05/20/14 03:27 108-90-7 Chloroethane ND mg/L 0.0020 1 05/20/14 03:27 75-00-3 2-Chloroethylvinyl ether ND mg1L. 0.0050 1 05/20/14 03:27 110-75-8 Chloroform ND mg/L 0.0020 1 05/20/14 03:27 67-66-3 Chloromethane ND mg/L 0.0020 1 05/20/14 03:27 74-87-3 2-Chlorotoluene NO mg/L 0.0020 1 05/20/14 03:27 95-49-8 4-Chlorotoluene NO mg/L 0.0020 1 05/20/14 03:27 106-434 Dibromochloromethane NO mg/L 0.0020 1 05/20/14 03:27 124-48-1 1,2-Dibromoethane (EDB) ND mg/L 0.0020 1 05/20/14 03:27 106-93-4 Dibromomethane NO mg/L 0.0020 1 05/20/14 03:27 74-95-3 1,2-Dichlorobenzene ND mg1L 0.0020 1 05/20/14 03:27 95-50-1 1,3-Dichlorobenzene ND mg1L 0.0020 1 05/20/14 03:27 541-73-1 1,4-Dichlorobenzene ND mg1L 0.0020 1 05/20/14 03:27 106-46-7 1,1-Dichloroethane ND mg/L 0.0020 1 05/20/14 03:27 75-34-3 1,2-DicNoroethane NO mg/L 0.0020 1 05/20/14 03:27 107-06-2 1,1-Dichloroethene ND mg/L 0,0020 1 05120/1403:27 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. Page 15 of 51 aceAnafytical ";W..pace7abszom I ANALYTICAL RESULTS Project: Storm Water Testing Pace Project No.: 92201481 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (-36 )623-8921 Sample: SDO 9 Parameters Lab ID: 92201481003 Collected: 05115/14 12:15 Results Units Report Limit DF Received: 05/15/14 13:45 Matrix: Water Prepared Analyzed CAS No. Qua[ 624 Volatile Organics Analytical Method: EPA 624 cis-1,2-Dichloroethene ND mg/L 0.0020 1 05/20/14 03:27 156-59-2 trans-1,2-Dichloroethene NO mg1L 0.0020 1 05/20/14 03:27 156-60-5 1,2-Dichloropropane NO mg/L 0.0020 1 05/20/14 03,27 78-87-5 1,3-Dichloropropane ND mg/L 0.0020 1 05/20/14 03:27 142-28-9 2,2-Dichloropropene ND mg/L 0.0050 1 05/20/14 03:27 594-20-7 1,1-Dichloropropene NO mg1L 0.0020 1 05/20/14 03:27 563-58-6 cis-1,3-Dichloropropene NO mg1L 0.0020 1 05/20/14 03:27 10061-01-5 tr2ns-1,3-Dichloropropene NO mg/L 0.0020 1 05/20/14 03:27 10061-02-6 Ethylbenzene NO mg/L 0.0020 1 05/20/14 03:27 100-41-4 Hexachloro-1,3-butadiene NO mg/L 0.0050 1 0512011403:27 87-68-3 2-Hexanone NO mg/L 0.010 1 05/20/14 03:27 591-78-6 lodomethane NO mg/L 0.010 1 05/20/14 03:27 74-88-4 L2 Isopropylbenzene (Cumene) NO mg/L 0.0050 1 05/20/14 03:27 98-82-8 p-isopropyltoluene NO mg/L 0.0050 1 05/20/14 03:27 99-87-6 Methylene Chloride ND mg/L 0.0020 1 05/20/14 03:27 75-09-2 4-Methyl-2-pentanone (MIBK) ND mg1L 0.010 1 05/20/14 03:27 108-10-1 Methyl-tert-butyl ether ND mglL 0.0050 1 05/20/14 03:27 1634-04-4 --Naphthalene ND mg/L. 0.0050 1 05!2W14 03:27 n-Propylbenzene ND mg11- 0.0050 1 05i20/14 03:27 103-65.1. Styrene ND mg/L 0,0020 1 05/20/14 03:27 100-42-5 1,1,1,2-Tetrachloroethane NO mg/L 0.0020 1 0512011403:27 630-20-6 1,1,2,2-Tetrachloroethane NO mg1L 0.0020 1 05/2011403:27 79-34-5 Tetra chloroetheno NO mg1L 0.0020 1 05/20/14 03:27 127-18-4 Toluene NO mg/L 0.0020 1 05/20/14 03:27 108-88-3 1,2,3-Trichlorobe nzene NO mg1L 0.0020 1 05/20/14 03:27 87-61-6 1,2,4-Trichlorobenzene ND mg1L 0.0020 1 05/20/14 03:27 120-82-1 1,1,1-Trichloroethane NO mg/L 0.0020 1 05/20/14 03:27 71-55-6 1,1,2-Trichloroethane NO mg/L 0.0020 1 05/20/14 03:27 79-00-5 Trichloroethene NO mg/L 0.0020 1 05/20/14 03:27 79-01-6 Trichloro#luoromethane NO mg/L 0.0020 1 05/20/14 03:27 75-69-4 1,2,3-TricMoropropane NO mg/L 0.0020 1 05/20/14 03:27 96-18-4 1,1,2-Trichlorotrif€uoroethane NO mg/L 0.0020 1 05120/1403:27 76-13-1 1,2,4-Tiimethylbenzene NO mg/L 0.0020 1 05/20/14 03:27 95-63-6 1,3,5-Trimethylbenzene ND mg/L 0.0020 1 05/20/14 03:27 108-67-8 Vinyl acetate NO mg/L 0.0050 1 05/20/1403:27 108-05-4 Vinyl chloride ND mg/L 0.0020 1 05/20/14 03:27 75-01-4 map-Xylene NO mg1L 0.0050 1 05/2011403:27 179601-23-1 o-Xylene NO mg/L 0.0050 1 05/20/14 03:27 95-47-6 Surrogates 4-Bromofluorobenzene (S) 88 % 70-130 1 05/20/14 03:27 460-00-4 Toluene-d8 (S) 98 % 70-130 1 05/20/14 03:27 2037-26-5 1,2-Dichloroethene-d4 (S) 101 % 70-130 1 05/20/14 03:27 17060-07-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. Page 16 of 51 W Analytical wr�vrpacrfabs.crom; I ANALYTICAL RESULTS Project: Storm Water Testing Pace Project No.: 92201481 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Sample: SDO 6 Parameters Lab ID: 92201431004 Collected: 05115/14 13:00 Results Units Report Limit OF Received: 05/15/14 13:45 Matrix: Water Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 7.9 mg/L 2.6 1 06/19/14 09:50 1664 SGT-HEM, TPH Analytical Method: EPA 1664E Total Petroleum Hydrocarbons ND mg1L 5.0 1 05/20/14 10:08 608 GCS Pesticides and PCBs Analytical Method: EPA 608 Preparation Method: EPA 3510 Aldrin NO mg/L 0.000050 1, 06/21/14 17:55 05/27/14 21 iO4 309-00-2 alph2-3HC ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 21:04 319-84-6 beta-BHC NO mg/L 0.000050 1 05/21/14 17:55 05/27114 21:04 319-85-7 delta-BHC ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 21:04 319-86-8 gamma-BHC (Lindane) NO mg1L 0.000060 1 05/21/14 17:55 05/27/14 21:04 58-89-9 Chlordane (Technical) NO mg/L 0.00050 1 05/21/14 17:55 05/27/14 21:04 57-74-9 4,4'-DDD ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 21:04 72-54-8 4,4'-DDE ND mg1t_ 0.000050 1 05I21/14 17:55 05/27/14 21:04 72-55-9 4,4'-DDT ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 21:04 50-29-3 Dieldrin ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 21:04 60-57-1 ._.. --_.Endosulfan 1 ._ -ND mg1L 0.000050 1 05/2/114 17:55 05/27/14 21!04 959-98-8 .-Endosulfan if - ND,,r.n./L 0,000050 1 -.05/21114 17:55 '0 127114 21:04 33213-65-9 , Endosulfan sulfate ND me/L O.000050 1 05/21/14 17:55 05/27/14 21:04 1031-07-8 Endrin ND mg1L 0.000050 1 05/21/14 17:55 05/27/14 21:04 72-20-8 Endrin aldehyde ND mg1L 0,000050 1 05/21/14 17:55 05/27/14 21:04 7421-93-4 Heptachlor ND mg1L 0.000050 1 05/21/14 17:55 05/27/14 21:04 76-44-8 Heptachlor epoxide ND mglL 0.000050 1 05/21/14 17:55 05/27/14 21:04 1024-57-3 PCB-1016 (Aroclor 1016) ND mg/L 0.00050 1 05/21/14 17:55 05/27/14 21:04 12674-11-2 PCB-1221 (Aroclor 1221) ND mg/L 0,00050 1 05/21/14 17:55 05/27/14 21:04 11104-28-2 PCB-1232 (Aroclor 1232) ND mg/L 0.00050 1 05/21/14 17:55 05/27/14 21:04 11141-16-5 PCB-1242 (Aroclor 1242) ND mg/L 0.00050 1 05/21/14 17:55 05/27/14 21:04 53469-21-9 PCB-1248 (Aroclor 1248) ND mg1L 0.00050 1 05/21/14 17:55 05/27/14 21:04 12672-29-6 PCB-1254 (Aroclor 1254) ND mg1L 0.00050 1 05/21/14 17:55 05/27/14 21:04 11097-69-1 PCB-1260 (Aroclor 1260) NO mg/L 0.00050 1 05/21/14 17:55 05/27/14 21:04 11096-82-5 Toxaphene NO mg/L 0.00050 1 05/21/14 17:55 05/27/14 21:04 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 35 % 20-110 1 05/21/14 17:55 05/27/14 21:04 877-09-8 Decachlorobiphenyl (S) 41 % 20-138 1 05/21/14 17:55 05/27/14 21:04 2051-24-3 200.7 MET ICP Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 Copper NO mg/L 0.0050 1 05/19/14 18:00 05/22/14 22:47 7440-50-8 Lead ND mg/L 0.0050 1 05/19/14 18:00 05/22/14 22:47 7439-92-1 Zinc ND mg/L 0.010 1 05/19/14 18:00 05/22/14 22:47 7440-66-6 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 Acenaphthene ND mg1L 0,0050 1 0511911413:35 05/2111406:32 83-32-9 Acenaphthylene ND mg1L 0.0050 1 0511911413:35 05/21/1406:32 208-96-8 Acetophenone ND mg/L 0.0050 1 05119/1413:35 05/21/1406:32 98-86-2 Aniline ND mg/L 0.010 1 05/19/1413:35 05/21/1406:32 62-53-3 Anthracene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 06:32 120-12-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. Page 17 of 51 aceAnalytical ,w�w.nacelabs.rnn ANALYTICAL RESULTS Project: Storm Water Testing Pace Project No.: 92201431 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27286 (336)623-8921 Sample: SDO 6 Lab ID: 92201481004 Collected! 05115114 13:00 Received: 05/15/14 13:45 Matrix: Water . Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 Benzidine NO mg/L 0.050 1 05119/1413:35 05/21/14 06:32 92-87-5 Benzo(a)anthracene ND mglL 0.0050 1 05119/1413:35 05/21/14 06:32 56-55-3 Benze(a)pyrene ND mglL 0.0050 1 05119/1413:35 05/21/14 06:32 50-32-8 Benzo(b)fiuoranthene ND mglL 0.0050 1 05119/1413:35 0612111406:32 205-99-2 Benzo(g,h,i)perylene ND mglL 0.0050 1 0511911413:35 0512111406:32 191-24-2 Benzo(k)fluoranthene NO mglL 0.0050 1 05119/1413:35 05121/1406:32 207-08-9 4-Bromophenylphenyl ether NO mglL 0.0050 1 05/19/14 13:35 05/21/14 06:32 101-55-3 Butylbenzyl phtha late ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 06:32 85-68-7 4-Chloro-3-methylphenol NO mg/L 0.0050 1 D5119/14 13:35 05/21/14 06:32 59-50-7 bis(2-Chloroethoxy)methane ND mglL 0,010 1 05/19/14 13:35 05/21/14 06:32 111-91-1 bis(2-Chloroethyl) ether ND mg1L 0.0050 1 05/19/14 13:35 05/21/14 06:32 111-44-4 bis(2-Chloroisopropyl) ether ND mg/L 0.0050 1 05/19/14 13!35 05/21/14 06:32 108-60-1 2-Chloro naphthalene NO mglL O.p050 1 05/19/14 13:35 05/21/14 06:32 91-58-7 2-Chlorophenol ND mglL 0.0050 1 05/19/14 13:35 05/21/14 06:32 95-57-8 4-Chlorophenylphenyl ether ND mglL 0.0050 1 05/19/14 13:35 05/2111406:32 7005-72-3 Chrysene NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 06:32 213-01-9 Dibenz(a,h)anthracene ND mg1L 0.0050 1 05/19/14 13:35 05/21/14 06:32 53-70-3 1.2-Dichlorobenzene - " ND mg1L 0.vG50 • -• 1 _' �� 05112114" IJ:J:J 05121I34 06:32 - - 113-Dichlorobenzene ND mglL 0.0050 1 05119/1413:35 05121I1406:32 541-73-1 1,4-Dichlorobenzene ND mglL 0,0050 1 05/19/14 13:35 05/21/14 06:32 106-46-7 3,3'-Dichlorobenzidine ND mglL 0.025 1 05/1911413:35 05121/1406:32 91-94-1 2,4-Dichlorophenol ND mglL 0.0050 1 05119/1413:35 05121/1406:32 120-83-2 Diethylphthalate ND mglL 0.0050 1 05119/141135 05121/1406:32 84-66-2 2,4-Di methyl phenol ND mglL 0.010 1 05/19/14 13:35 05/21/14 06:32 105-67-9 Dimethylphthalate ND mg/L 0.0050 1 05/19/14 13:35 05/21114 06:32 131-11-3 Di-n-butylphthalate ND mg1L 0.0050 1 05/19/14 13:35 05/21/14 06:32 84-74-2 4,6-Dinitro-2-methylphenol NO mg1L 0.020 1 05/19/14 13:35 05/21/14 06:32 534-52-1 2,4-Dinitrophenol ND mg1L 0,050 1 05/19/14 13:35 05/21/14 06:32 51-28-5 2,4-Dinitrotvluene ND mglL 0,0050 1 05/19/14 13:35 05/21/14 06:32 121-14-2 2,6-Dinitrotoluene ND mg1L 0.0050 1 05/19/14 13:35 05/21/14 06:32 606-20-2 Di-n-octylphthalate ND mg1L 0.0050 1 05/19/14 13:35 05/21/14 06:32 117-84-0 1,2-Diphenylhydrazine NO mglL 0.0050 1 0511911413:35 05/2111406:32 122-66-7 bis(2- Ethyl hexyl)phthalate ND mglL 0.0050 1 05/19/14 13:35 05/21/14 06:32 117-81-7 Fluoranthene NO mg/L 0.0050 1 05/19/14 13:35 05/24/14 06:32 206-44-0 Fluorene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 06:32 86-73-7 Hexachloro-1,3-butadiene NO mglL 0.0050 1 05/19/14 13:35 05/21/14 06:32 87-63-3 Hexachlorobenzene ND mglL 0.0050 1 05/19/14 13:35 05/21/14 06:32 118-74-1 Hexachlorocycloperitadiene ND mg/L 0.010 1 05/19/14 13:35 05/21/14 06:32 77-47-4 H exachloro ethane ND mglL 0.0050 1 05/19/14 13:35 05/21/14 06:32 67-72-1 Indenc(1,2,3-cd)pyrene_ ND mglL 0.0050 1 05/19/14 13:35 05/21/14 06:32 193-39-5 Isophorone ND mglL 0.010 1 05/19/14 13:35 05/21/14 06:32 78-59-1 Naphthalene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 06:32 91-20-3 Nitrobenzene NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 06:32 98-95-3 2-Nitrophenol NO mglL 0.0050 1 05/19/14 13:35 05/21/14 06:32 88-75-5 4-Nitrophenol ND mg/L 0.050 1 05/19/14 13:35 05/21/14 06:32 100-02-7 N-Nitrosodimethylamine ND mglL 0,0050 1 05/19/14 13:35 05/21/14 06:32 62-75-9 N-Nitroso-di-n-propylamine NO mg1L 0.0050 1 05/19/14 13:35 05/21/14 06:32 621-64-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. Page 13 of 51 aceAnalytical f www.Pacelabs.,= 1 ANALYTICAL RESULTS Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: Storm Water Testing Pace Project No.: 92201481 Sample: SDO 6 Lab ID: 92201481004 Collected: 05/15/14 13:00 Received: 05/15/14 13:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Oual 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 N-Nitrosodiphenylamine ND mg/L 0.010 1 05/19/14 13:35 05/21/14 06:32 86-30-6 Pentachlorophenol ND mg/L 0.010 1 05/19/14 13:35 05/21/14 06:32 87-36-5 Phenanthrene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 06:32 85-01-8 Phenol ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 06:32 108-95-2 Pyrene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 06:32 129-00-0 1,2,4-Trichlorobenzene ND mg/L 0.0050 1 05/19/14 13:35 05/21114 06:32 120-82-1 2,4,6-Trichlorophenol ND mg/L 0,010 1 05/19/14 13:35 05/21/14 06:32 88-06-2 Surrogates Nitrobenzene-d5 (S) 39 % 10-120 1 05/19/14 13:35 05/21/14 06:32 4165-60-0 2-Fluorobiphenyl (S) 39 % 15-120 1 05/19/14 13:35 05/21/14 06:32 321-60-8 Terphenyl-d14 (S) 66 % 11-131 1 05/19/14 13:35 05/21/14 06:32 1718-51-0 Phenol-d6 (S) 15 % 10-120 1 05/19/14 13:35 05/21/14 06:32 13127-88-3 2-Fluorophenol (S) 24 % 10-120 1 05/19/14 13:35 05/21/14 06:32 367-12-4 2,4,6-Tribromophenol (S) 75 % 10-137 1 05/19/14 13:35 05/21/14 06:32 118-79-6 624 Volatile Organics Analytical Method: EPA 624 Acetone ND mg/L 0.010 1 05/20/14 03:44 67-64-1 -.,4crclein . ND mg/L 0.0050 1 '05i2Oil 4 03:44 1074 -8 Acrylonitrile ND mg/L 0.050 1 05/20114 03:44 107-13-1 Benzene ND mg/L 0.0020 1 05/20/14 03:44 71-43-2 Bromobenzene ND mg/L 0.0020 1 05/20/14 03:44 108-86-1 Bromochloromethane ND mg/L 0.0020 1 05/20/14 03:44 74-97-5 Bromodichloromethane ND mg/L 0.0020 1 05/20/14 03:44 75-27-4 Bromoform ND mg/L 0.0020 1 05/20/14 03:44 75-25-2 Bromomethane ND mg/L 0.0020 1 05/20/14 03:44 74-83-9 2-Butanone (ME14) ND mg/L 0.0050 1 05/20/14 03:44 78-93-3 n-Butylbenzene ND mg/L 0.0050 1 0512011403:44 104-51-8 sec-Butylbenzene ND mg/L 0.0050 1 05/20/14 03:44 135-98-8 tert-Butylbenzene ND mg/L 0.0050 1 05/20/14 03:44 98-06-6 Carbon disulfide ND mg/L 0,0050 1 05/20/14 03:44 75-15-0 Carbon tetrachloride ND mg/L 0,0020 1 05/20/14 03:44 56-23-5 Chlorobenzene ND mg/L 0.0020 1 05/20/14 03:44 108-90-7 Chloroethane ND mg1L 0.0020 1 05/20/14 03:44 75-00-3 2-Chloroethylvinyl ether ND mg/L 0.0050 1 05/20/14 03:44 110-75-8 Chloroform ND mg/L 0.0020 1 05/20/14 03:44 67-66-3 Chloromethane ND mg/L 0.0020 1 05/20/14 03:44 74-87-3 2-Chlorotoluene ND mg/L 0.0020 1 05/20/14 03:44 95-49-8 4-ChlorotoIuene ND mg/L 0.0020 1 05/20/14 03:44 106-43-4 Dibromochloromethane NO mg/L 0,0020 1 05/20/14 0144 124-48-1 1,2-Dibromcethane (EDB) ND mg1L 0.0020 1 05/20/14 03:44 106-93-4 Dibromomethane ND mg/L 0.0020 1 05/20/14 03:44 74-95-3 1,2-Dichlorobenzene ND mg/L 0.0020 1 05/20/14 03:44 95-50-1 113-Dichlorobenzene ND mg/L 0.0020 1 05/20/14 03:44 541-73-1 1,4-Dichlorobenzene ND mg/L 0.0020 1 05/20/1403:44 106-46-7 1,1-Dichloroethane ND mg/L 0,0020 1 0512011403:44 75-34-3 1,2-Dichloroethane ND mg/L 0.0020 1 05120/1403:44 107-06-2 1,1-Dichloroethene ND mg/L 0.0020' 1 05/20/14 03:44 75-35-4 L3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. Page 19 of 51 aceAnalXical .w�w.pacela6s.con. . f ANALYTICAL RESULTS Project: Storm Water Testing Pace Project No.: 92201481 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Sample: SDO 6 Lab ID: 92201481004 Collected: 05/15/14 13:00 Received: 05/15/14 13:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 624 Volatile Organics cis- 1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1, 3-Dichloro propene trans-1,3-Dichloropropene Ethylbenzene Hexachloro-1, 3-butadiene 2-Hexanone lodomethane Isopropyl benzene (Cumene) p-Isopropyltoluene Methylene Chloride 4-M ethyl-2-penta none (MIBK) Methyl-tert-butyl ether 'Naohthaiene - n-Prupylbenzene Styrene 1,1,1,2-Tetrachloroetha ne 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroetha ne 1,1,2-Trichloroetha ne Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,1,2-Trichlorotrifluoroethane 1,2,4-7rimethylbenzene 1, 3,5-Trimethylbenzene Vinyl acetate Vinyl chloride m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) Toluene -dB (S) 1,2-Dichloroethane-d4 (S) Analytical Method: EPA 624 NO mg/L NO mg/L NO mg/L NO mg/L NO mg/L ND mg/L NO mg/L NO mg/L ND mg/L ND mglL NO mg/L NO mg1L ND mg/L ND mg1L NO mg/L NO mg/L NO mg/L Nt) 'mglL ND mg/L NO mg/L ND mg/L ND mg/L NO mg1L NO mg/L N D mg/L N D mg/L ND mg/L ND mg1L ND mg/L ND mg1L NO mg1L NO mg/L NO mg/L ND mg/L ND mg/L ND mg/L ND mg1L ND rnglL 89 % 97 % 103 % 0,0020 1 0.0020 1 0.0020 1 0.0020 1 0.0050 1 0.0020 1 0.0020 1 0.0020 1 0.0020 1 0.0050 1 0.010 1 0.010 1 0.0050 1 0.0050 1 0.0020 1 0.010 1 0.0050 1 u.uv5v i 0.0050 1 0.0020 1 0.0020 1 0.0020 1 0.0020 1 0.0020 1 0.0020 1 0.0020 1 0.0020 1 0.0020 1 0.0020 1 0.0020 1 0.0020 1 0.0020 1 0.0020 1- 0.0020 1 0.0050 1 0.0020 1 0.0050 1 0,0050 1 70-130 1 70-130 1 70-130 1 05/20/14 03:44 156-59-2 05/20/14 03:44 156-60-5 05/20/14 03:44 78-87-5 05/20/14 03:44 142-28-9 05/20/14 03:44 594-20-7 05/20/14 03:44 563-58-6 05/20/14 03:44 10061-01-5 05/20/14 03:44 10061-02-6 05/20/14 03:44 100-41-4 05/20/14 03:44 87-68-3 05/20/14 03:44 591-78-6 05/20114 03!44 74-88-4 L2 05/20/14 03:44 98-82-8 05/20/14 03:44 99-87-6 05/20/14 03:44 75-09-2 05/20/14 03:44 108-10-1 05/20/14 03:44 1634-04-4 05/20/14 03:44 9'i-20-3 05/20/14 03:44 103-65-1 05/20/14 03:44 100-42-5 05/20/14 03:44 630-20-6 05/20/14 03:44 79-34-5 05/20/14 03:44 127-18-4 05/20/14 03:44 108-88-3 05/20/14 03:44 87-61-6 05/20/14 03:44 120-82-1 05/20/14 03:44 71-55-6 05/20/14 03A4 79-00-5 05/20/14 03A4 79-01-6 05/20/14 03.44 75-69-4 05/20/14 03:44 96-18-4 05/20/14 03:44 76-13-1 05/20/14 03:44 95-63-6 05/20/14 03:44 108-67-8 05/20/14 03:44 108-05-4 05/20/14 03:44 75-01-4 05/20/14 03:44 179601-23-1 05/20/14 03:44 95-47-6 05/20/14 03:44 460-00-4 05/20/14 03:44 2037-26-5 05/20/14 03:44 17060-07-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. Page 20 of 51 aceAnalytica!® wwsv.,73VY12: SCP?�, ANALYTICAL RESULTS Project: Storm Water Testing Pace Project No.: 92201481 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Sample: SDO 11 Lab ID: 92201481005 Collected: 05/15/14 12:25 Received: 05/15/14 13:45 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D TotaF Suspended Solids 3.5 mg/L 2.5 1 05/19/14 09:51 1664 SGT-HEM, TPH Analytical Method: EPA 1664E Total Petroleum Hydrocarbons ND mglL 5.0 1 05/20/14 10:09 608 GCS Pesticides and PCBs Analytical Method: EPA 608 Preparation Method: EPA 3510 Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC (Lindane) Chlordane (Technical) 4,4'-DDD 4,4'-DDE 4, 4'-DDT Dieldrin _..._Endossilfan I _ Endv$ulfan fl _ Endcsulfan sulfate Endrin Endrin aldehyde Heptachlor Heptachlor epoxide PCB-1016 (Aroclor 1016) PCB-1221 (Aroclor 1221) PCB-1232 (Aroclor 1232) PCB-1242 (Aroclor 1242) PCB-1248 (Aroclor 1248) PCB-1254 (Aroclor 1254) PCB-1260 (Aroclor 1260) Toxaphene Surrogates Tetra chlo ro-m-xyle ne (S) Decachlorobiphenyl (S) 200.7 MET 1CP Copper Lead Zinc 625 MSSV Acenaphthene Acenaphthylene Acetophenone Aniline Anthracene NO mg/L 0.000050 1 05/21/14 17!55 05/27/14 21:23 309-00-2 NO mg/L 0.000050 1 05/21/14 17i55 05/27/14 21:23 319-84-6 NO mg/L 0.000050 1 05/21/14 17:55 05/27/14 21:23 319-85-7 NO mg/L 0.000050 1 05/21/14 17:55 05/27/14 21:23 319-86-8 ND mg1L 0.000050 1 05/21/14 17:55 05/27/14 21:23 58-89-9 NO mg1L 0,00050 1 05/21/14 17:55 05/27/14 21:23 57-74-9 NO mg1L 0.000050 1 05/21/14 17:55 05/27/14 21:23 72-54-8 ND mg/L 0,000050 1 05/21/14 17:55 05/27/14 21:23 72-55-9 ND mg/L 0.000050 1 05121/14 17:55 05/27/14 21:23 50-29-3 NO mg/L 0.000050 1 05/21/14 17:55 05/27/14 21:23 60-57-1 NO mglL . _ _ 0:00005Q 1 05/21/14 17:55 05/27/14 21:23 959-98-8 NO Moll-0.000050 1 05/21/14 17!55 05/27/14 21:23 33213765-9 NO mg1L 0.000050 1 05/21/14 17:55 05/27/14 21:23 1031-07-8 ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 21:23 72-20-8 NO mo/L 0.000060 1 05/21/14 17:55 05/27/14 21:23 7421-93-4 NO mg/L 0.000050 1 05/2111417:55 05127/1421.23 76-44-8 NO mg/L 0,000050 1 05/21/14 17:55 05/27/14 21:23 1024-57-3 NO mg/L 0.00050 1 05/21/14 17:55 05/27/14 21:23 12674-11-2 NO mg/L 0.00050 1 05/21/14 17:55 05/27/14 21:23 11104-23-2 NO mg/L 0.00050 1 05/21/14 17:55 05/27/14 21:23 11141-16-5 ND mg/L 0.00050 1 05/21/14 17:55 05/27/14 21:23 53469-21-9 ND mg1L 0.00050 1 05121/1417:55 05127/1421:23 12672-29-6 NO mg/L 0.00050 1 05121/1417:55 05127/1421:23 11097-69-1 ND mg/L 0.00050 1 05/21/14 17:55 05/27/14 21:23 11096-82-5 NO mg/L 0.00050 1 05/21/14 17:55 05/27/14 21:23 8001-35-2 57 % 20-110 1 05/21/14 17:55 05/27/14 21:23 877-09-8 40 % 20-138 1 0512104 17:55 05/27/14 21:23 2051-24-3 Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 0.0052 mg/L 0.0050 1 05/19/14 18:00 05/22/14 22:50 7440-50-8 NO mg/L 0.0050 1 05/19/14 18:00 05/22/14 22:50 7439-92-1 0.025 mg/L 0.010 1 05/19/14 18:00 05/22/14 22:50 7440-66-6 Analytical Method: EPA 625 Preparation Method: EPA 625 NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:01 83-32-9 ND mg/L 0.0050 1 05119/1413:35 05/21/1407:01 208-96-8 NO mg/L 0.0050 1 05/191141135 05/21/1407:01 98-86-2 NO mg/L 0.010 1 05/19/14 13:35 05/21/14 07:01 62-53-3 NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:01 120-12-7 Date: 05128l2014 01:18 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 51 ZAnalytical rrmv,pacelabs.rnm, r ANALYTICAL RESULTS Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27286 (336)623-8921 Project: Storm Water Testing Pace Project No.: 92201481 Sample: SDO 11 Lab 1D: 92201481005 Collected: 05/15/14 12:25 Received: 05/15/14 13:45 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 625 IVISSV Analytical Method: EPA 625 Preparation Method: EPA 625 Benzidine ND mg/L 0.050 1 05119/14 13:35 05/21/14 07:01 92-87-5 Benzo(a)anthracene NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:01 56-55-3 Senzo(a)pyrene NO mg1L 0,0050 1 05/19/14 13:35 05/21/14 07:01 50-32-8 Benzo(b)f, uoranthene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:01 205-99-2 Senzo(g,h,i)perylene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:01 191-24-2 Benzo(k)fiuoranthene NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:01 207-08-9 4-Bromophenylphenyl ether ND rng1L 0.0050 1 05/19/14 13:35 05/21/14 07:01 101-55-3 Butylbenzylphthalate ND mg1L 0.0050 1 05/19/14 13:35 05/21/14 07:01 85-68-7 4-CWoro-3-methylphenol ND mg1L 0.0050 1 05/19/14 13:35 05/21/14 07:01 59-50-7 b1s(2-Chioroethoxy)methane NO mg/L 0.010 1 05/19114 13:35 05/21/14 07:01 111-91-1 bis(2-Chioroethyl) ether NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:01 111-44-4 bis(2-Chloroisopropyl) ether NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:01 108-60-1 2-Chloronaphthalene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:01 91-58-7 2-Chlorophenol ND mg/L 0,0050 1 05/19/14 13:35 05/21/14 07:01 95-57-8 4-Chlorophenylphenyl ether ND mg/L 0,0050 1 05/19/14 13:35 05/21/14 07:01 7005-72-3 Chrysene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:01 218-01-9 Dibenz(a,h)anthracene NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:01 53-70-3 1,2-Dichlorobenze6e _ - -'NU mglt- 0.0050 1 "05/19114J3.35-05/2-1/1407:01 95-50-1 1,3-Dichlorobenzene ND mg/L 6.0050 1 05119/ 14 13.35 0512V14 07:01 541-73-1 1,4-Dichlorobenzene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:01 106-46-7 3,3'-Dichlorobenzidine NO mg/L 0,025 1 05/19/14 13:35 05/21/14 07:01 91-94-1 2,4-Dichlorophenol NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:01 120-83-2 D iethylphth a late ND mg1L 0.0050 1 05/19/14 13:35 05/21/14 07:01 84-66-2 2,4-Di methyl phenol ND mg/L 0.010 1 05/19114 13:35 05/21/14 07:01 105-67-9 Dimethylphthalate ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:01 131-11-3 Di-n-butylphthalate NO mg/L 0.0050 1 05119/1413:35 05/2111407:01 84-74-2 4,6-Dinitro-2-methylphenol NO mg1L 0.020 1 05119/1413735 0512111407:01 534-52-1 2,4-Dinitrophenol ND mg1L 0.050 1 05/19/14 13:35 05/21/14 07:01 51-28-5 2,4-Dinitrotoluene ND mg1L 0.0050 1 05/19/14 13:35 05/21/14 07!01 121-14-2 2,6-Dinitrotoluene NO mg/L 0-0050 1 05/19/14 13-,35 05/21/14 07:01 606-20-2 Di-n-octylphthalate ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:01 117-84-0 1,2-Diphenylhydrazine ND mg/L 0,0050 1 05/19/14 13:35 05/21/14 07:01 122-66-7 bis(2-Ethylhexyl)phthalate ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:01 117-81-7 Fluoranthene NO mg1L 0.0050 1 05/19/14 13:35 05/21/14 07:01 206-44-0 Fluorene ND mg1L 0.0050 1 05/19/14 13:35 05/21/14 07:01 86-73-7 Hexachloro-1,3-butad iene ND mg1L 0.0050 1 0511911413:35 05/2111407:01 87-68-3 Hexachlorobenzene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:01 118-74-1 Hexachlorocyclopentadiene NO mg/L 0.010 1 05/19/14 13:35 05/21/14 07:01 77-47-4 Hexachloroethane ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:01 67-72-1 1ndeno(1,2,3-cd)pyre ne ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:01 193-39-5 Isophorone ND mg/L 0.010 1 05/19/14 13:35 05/21/14 07:01 78-59-1 Naphthalene NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:01 91-20-3 Nitrobenzene NO mg/L 0.0050 1 65/19/14 13:35 05/21/14 07:01 98-95-3 2-Nitrophenol NO mg1L 0.0050 1 05/19/14 13:35 05/21/14 07:01 88-75-5 4-Nitrophenol ND mg/L 0,050 1 05/19/14 13:35 05//21/14 07:01 100-02-7 N-Nitrosodimethyla mine ND mg/L 0.0050 1 05119/1413:35 05/21/14 07:01 62-75-9 N-Nitroso-di-n-propylamine ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:01 621-64-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced• except in full, Date: 05/28/2014 01.18 PM without the written consent of Pace Analytical Services, Inc.. Page 22 of 51 I aceAnalyt`fcal www.pacefabs.com l ANALYTICAL RESULTS Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: Storm Water Testing - Pace Project No.: 92201481 Sample: SOO 11 Lab ID: 92201481005 Collected: 05/15/14 12:25 Received: 0511504 13:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No, Qual 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 N-Nitrosodiphenylamine ND mg/L 0.010 1 05/19/14 13:35 05/21/14 07:01 86-30-6 Pentachlorophenol ND mg/L 0.010 1 05119/1413:35 05/21/14 07:01 87-86-5 Phenanthrene NO mg/L 0.0050 1 05119/1413:35 05121/1407:01 85-01-8 Phenol ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:01 108-95-2 Pyrene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:01 129-00-0 1,2,4-Trichlorobenzene NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:01 120-82-1 2,4,6-Trichlorophenol NO mg/L 0.010 1 05/19/14 13:35 05/21/14 07:01 88-06-2 Surrogates Nitrobenzene-d5 (S) 42 % 10-120 1 05/19/14 13.35 05/21/14 07:01 4165-60-0 2-Fluorobiphenyl (S) 43 % 15-120 1 05/19/14 13:35 05121 /14 07:01 321-60-8 Terphenyl-d14 (3) 70 % 11-131 1 05/19/14 13:35 05/21/14 07:01 1718-51-0 Phenol-d6 (S) 16 % 10-120 1 05/19/14 13:35 05/21/14 07:01 13127-88-3 2-Fluorophenol (S) 25 % 10-120 1 05/19/14 13:35 05/21/14 07:01 367-12-4 2,4,6-Tribromophenol (S) 86 % 10-137 1 05/19/14 13:35 05/21/14 07:01 118-79-6 624 Volatile Organics Analytical Method: EPA 624 Acetone NO mg/L 0.010 1 05/20/14 04:00 67-64-1 Acrolein _-t . ` " " -ND mglL -0.0050 1 051201/4 04:00 107-02-8 Acryionitrile ND mg/L 0.050 1 .05120114 04:00 107-13-1 Benzene ND mg/L 0.0020 1 05/20/14 04:00 71-43-2 Bromobenzene NO mg/L 0.0020 1 05/20/14 04:0Q 108-86-1 Bromochloromethane NO mg/L 0.0020 1 05/20/14 04:00 74-97-5 BromodicNoromethane NO mg/L 0.0020 1 05/20/14 04:00 75-27-4 Bromoform ND mg/L 0.0020 1 05/20/14 04:00 75-25-2 Bromomethane ND mg/L 0.0020 1 06/20114 04:00 74-83-9 2-Butanone (MEK) ND mg/L 0.0050 1 05/20/14 04:00 78-93-3 n-Butylbenzene NO mg/L 0.0050 1 05/20/14 04:00 104-51-8 sec-Butylbenzene NO mg/L 0.0050 1 05/20/14 04:00 135-98-8 tent-Butylbenzene ND mg/L 0.0050 1 05/20/14 04:00 98-06-6 Carbon disulfide NO mg1L 0.0050 1 05/20/14 04:00 75-15-0 Carbon tetrachloride ND mg1L 0.0020 1 05/20/14 04:00 56-23-5 Chlorobenzene NO mg/L 0.0020 1 05/20/14 04:00 108-90-7 Chloroethane NO mg/L 0.0020 1 05/20/14 04:00 75-00-3 2-Chloroethylvinyt ether NO mg/L 0.0050 1 05/20/14 04:00 110-75-8 Chloroform ND mg/L 0.0020 1 05/20/14 04:00 67-66-3 Chloromethane NO mg/L 0-0020 1 05/20/14 04:00 74-87-3 2-Chlorotoluene ND mg1L 0.0020 1 05/20/14 04:00 95-49-8 4-Chlorotoluene ND mglL 0.0020 1 05/20/14 04:00 106-43-4 Dibromochloromethane NO mg/L 0.0020 1 05/20/14 04:00 124-48-1 1,2-Dibromoethane (EDS) NO mg/L 0.0020 1 05/20/14 04:00 106-93-4 Dibromomethane ND mg/L 0.0020 1 . 05/20/14 04:00 74-95-3 1,2-Dichlorobenzene ND mg/L 0.0020 1 05/20/14 04:00 95-50-1 1,3-Dichlorobenzene ND mg/L 0,0020 1 05/20/14 04:00 541-73-1 1,4-Dichlorobenzene NO mg/L 0.0020 1 05/20/14 04:00 106-46-7 1,1-Dichloroethane NO mg/L 0,0020 1 05/20/14 04:00 75-34-3 1,2-Dichloroethane NO mg/L 0,0020 1 05/20/14 04:00 107-06-2 1,1-DicNoroethene NO mg1L 0.0020 1 05/20/14 04:00 75-35-4 L3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. Page 23 of 51 aceAnalyical www.,�.urnlabs.mm- ANALYTICAL RESULTS Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-0921 Project: Storm Water Testing Pace Project No.: 92201481 Sample: SDO 11 Lab fD: 92201481005 Collected: 05/15/14 12:25 Received: 05/15/14 13:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 624 Volatile Organics Analytical Method: EPA 624 cis-1,2-Dichloroethene NO mg/L 0.0020 1 05/20/14 04:00 156-59-2 trans- 1, 2-Dichloroethe n e ND mg/L 0.0020 1 05/20/14 04:00 156-60-5 1,2-Dichloropropane ND mg/L 0.0020 1 05/2011404:00 78-87-5 1,3-Dichloropropane ND mg/L 0.0020 1 05/20/14 04:00 142-28-9 2,2-D ichlo ro propane NO mg/L 0.0050 1 05/20/14 04:00 594-20-7 1,1-Dichloropropene NO mg1L 0.0020 1 0512011404:00 563-58-6 cis-1,3-Dichloropropene ND mg/L 0.0020 1 05/20/14 04:00 10061-01-5 trans- 1,3-Dichloropropen e NO mg/L 0.0020 1 05/20/14 04:00 10061-02-6 Ethylbenzene NO mg/L 0,0020 1 05/20/14 04:00 100-41-4 Hexachloro-1,3-butadiene ND mg/L 0,0050 1 05/20/14 04:00 87-68-3 2-Hexanone NO mg/L 0.010 1 05/20/14 04:00 591-78-6 lodomethane NO mg/L 0.010 1 05/20/14 04:00 74-88-4 L2 Isopropylbenzene (Cumene) NO mg/L 0.0050 1 05/20/14 04:00 98-82-8 p-Isopropyltoluene ND mg/L 0.0050 1 05/20/14 04:00 99-87-6 Methylene Chloride NO mg/L 0.0020 1 05/20/14 04:00 75-09-2 4-Methyl-2-pentanone (MIBK) ND mg/L 0.010 1 05/20/14 04:00 108-10-1 Methyl-tert-butyl ether NO mg/L 0.0050 1 05/20/14 04:00 1634-04-4 Napninalene ' NO mg1L 0.0050" ' 1 05/20/14 04:00 91-20-3 n-Propylbenzene ND mg/L 0.00E0, 1 05/20/14 04:00 103-65-1 Styrene ND mg/L 0.0020 1 05/20/14 04:00 100-42-5 1,1,1,2-Tetrachioroethane ND mg/L 0.0020 1 05/20/14 04:00 630-20-6 1,1,2,2-Tetrachloroethane NO mo/L 0.0020 1 05/20/14 04:00 79-34-5 Tetrachloroethene NO mg1L 0.0020 1 05/20/14 04:00 127-18-4 Toluene ND mg/L 0.0020 1 05/20/14 04:00 108-88-3 1,2,3-Trichlorobenzene ND mg/L 0.0020 1 05/20/14 04:00 87-61-6 1,2,4-Trichlorobenzene ND mg/L 0,0020 1 05/20/14 04:00 120-82-1 1,1,1-Trichloroethane NO mg1L -0.0020 1 05/20/14 04:00 71-55-6 1,1,2-Trichloroethane NO mg/L 0.0020 1 05/20/14 04:00 79-00-5 Trichloroethene ND mg/L 0,0020 1 05/20/14 04:00 79-01-6 Trichlorofluoromethane NO mg/L 0,0020 1 05/20/14 04:00 75-69-4 1,2,3-Trichloropropane ND mg/L 0.0020 1 05/20/14 04:00 96-18-4 1,1,2-Trichlorotrifluoroethane ND mg/L 0.0020 1 05/20/14 04:00 76-13-1 1,2,4-Trimethylbenzene ND mg1L 0.0020 1 05/20/14 04:00 95-63-6 1,3,5-Trimethylbenzene ND mg1L 0.0020 1 05/20/14 04:00 108-67-8 Vinyl acetate ND mg/L 0.0050 1 05/20/14 04:00 108-05-4 Vinyl chloride NO mg1L 0.0020 1 05/20/14 04:00 75-01-4 m&p-Xylene ND mg/L 0.0050 1 05/20/14 04:00 179601-23-1 o-Xyfene ND mg/L 0.0050 1 05/20/14 04:00 95-47-6 Surrogates 4-Bromofluorobenzene (S) 87 % 70-130 1 05/20/14 04:00 460-00-4 Toluene-1d8 (S) 98 % 70-130 1 05/20/14 04:00 2037-26-5 1,2-Dichloroethene-d4 (S) 102 % 70-130 1 05/20/14 04:00 17060-07-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. Page 24 of 51 ace Analytical wrrn:F�='�labs.ca'� ANALYTICAL RESULTS Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27238 (s36)623-8921 Project: Storm Water Testing Pace Project No.: 92201481 Sample: SDO 12 Lab fD: 92201481006 Collected: 05/15/14 12:35 Received: 05/15/14 13:45 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Total Suspended Solids 1664 SGT-HEM, TPH Total Petroleum Hydrocarbons 608 GCS Pesticides and PCBs Aidrin alpha-BHC beta-BHC delta-BHC gamma-BHC (Lindane) Chlordane (Technical) 4,4'-DDD 4,4'-D DE 4,4'-DDT Dieldrin R., End^Sulfan I Endosulfan sulfate Endrin Endrin aldehyde Heptachlor Heptachlor epoxide PCB-1016 (Aroclor 1016) PCB-1221 (Aroclor 1221) PCB-1232 (Aroclor 1232) PCB-1242 (Aroclor 1242) PCB-1248 (Aroclor 1248) PCB-1254 (Aroclor 1254) PCB-1260 (Aroclor 1260) Toxaphene Surrogates Tetrachloro-m-xylene (S) Decachlorobiphenyl (S) 200.7 MET ICP Copper Lead Zinc 625 MSSV Acenaphthene Acenaphthylene Acetophenone Aniline Anthracene Analytical Method: SM 2540D 4.1 mg/L 2.5 1 05/19/14 09!52 Analytical Method: EPA 1664E NO mg/L 5.0 1 05/20/14 10:10 Analytical Method: EPA 608 Preparation Method: EPA 3510 NO mg/L 0.000050 1 05/21/14 17:55 05/27/14 21:41 309-00-2 NO mg/L 0,000050 1 05/21/14 17:55 05/27/14 21:41 319-84-6 ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 21:41 319-85-7 ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 21:41 319-86-8 ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 21:41 58-89-9 ND mg/L 0.00050 1 05/21/14 17:55 05/27/14 21:41 57-74-9 NO mg/L 0,000050 1 05/21/14 17:55 05/27/14 21:41 72-54-8 ND mg/L 0,000050 1 05/21/14 17:55 05/27/14 21:41 72-55-9 ND mg/L 0.000050 1 05/21/14 17.55 05/27/14 21:41 50-29-3 ND mg/L 0,000050 1 05/21/14 17:55 05/27/14 21:41 60-57-1 ND mall- 0.000050 1 05/21/14 17:55 05/27/14 21:41 959-98-8 ND rng/L .0.000050 1 05/21/14 17:55 05/27/14 21:41 33213-65-9 NO mg/L 0.000050 1 05/21/14 17:55 05/27/14 21:41 1031-07-6 ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 21:41 72-20-8 ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 21:41 7421-93-4 ND mg/L 0.000050 1 06/21/14 17:55 05/27/14 21:41 76-44-8 ND mg/L 0.000050 1 05/21114 17:55 05/27/14 21:41 1024-57-3 NO mg/L 0.00050 1 05/21/14 17:55 05/27/14 21:41 12674-11-2 NO mg/L 0.00050 1 05121/1417:55 0512711421:41 11104-28-2 NO mg1L 0.00050 1 05121/1417:55 0512711421.41 11141-16-5 NO mg1L 0.00050 1 05/21/14 17:55 05/27/14 21:41 53469-21-9 ND mg/L 0.00050 1 05/21/14 17:55 05/27/14 21:41 12672-29-6 ND mg/L 0.00050 1 05/21/14 17:55 05/27/14 21:41 11097-69-1 ND mg/L 0.00050 1 05/21/14 17:55 05/27/14 21:41 11096-82-5 NO mg/L 0.00050 1 05/21/14 17:55 05/27/14 21:41 8001-35-2 56 % 20-110 1 05/21/14 17:55 05/27/14 21:41 877-09-8 44 % 20-138 1 05/21/14 17:55 05/27/14 21:41 2051-24-3 Analytica! Method: EPA 200.7 Preparation Method: EPA 200.7 NO mg/L 0,0050 1 05/19/14 18:00 05/22/14 22:53 7440-50-8 ND mglL 0,0050 1 05/19/14 18:00 05/22/14 22!53 7439-92-1 0,017 mg/L 0,010 11 05/19/14 18:00 05/22/14 22:53 7440-66-6 Analytical Method: EPA 625 Preparation Method: EPA 625 ND mg1L 0.0050 1 05/19/14 13:35 05/21/14 07:30 83-32-9 ND mglL 0.0050 1 05119/1413:35 05/21/14 07:30 208-96-8 ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:30 98-86-2 ND mg/L 0,010 1 05/19/14 13:35 05/21/14 07:30 62-53-3 ND mg/L 0.0050 1 05119/1413:35 05121/1407:30 120-12-7 Date: 05/23/2014 01:18 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 51 ace Analytical wwwpacelabs.com� I ANALYTICAL RESULTS Project: Storm Water Testing Pace Project No.: 92201481 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Sample: SDO 12 Parameters Lab ID: 92201481006 Results Units Collected! 05/15/14 12:35 Received: 05/15/14 13A5 Matrix: Water Report Limit DF Prepared Analyzed CAS No. Qual 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 Senzidine ND mg/L 0.050 1 05/19/14 13:35 05/21/14 07:30 92-87-5 Benzo(a)anthracene NO mg1L 0,0050 1 05/19/14 13:35 05/21/14 07:30 56-65-3 Senzo(a)pyrene NO mg/L 0,0050 1 05/19/14 13:35 05/21/14 07:30 50-32-8 Benzo(b)fluoranthene NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07!30 205-99-2 Benzo(g,hJ)perylene NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:30 191-24-2 Benzo(k)fluoranthene ND mg1L 0.0050 1 05/19/14 13:35 05/21/14 07:30 207-08-9 4-Bromophenylphenyl ether NO mg1L 0.0050 1 05/19/14 13:35 05/21/14 07:30 101-55-3 Butylbenzylphthalate ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:30 85-68-7 4-Chioro-3-methyl phenol NO mg1L 0.0050 1 05/19/14 13:35 05/21/14 07:30 59-50-7 bis(2-Chloroethoxy)methane NO mg/L 0.010 1 05/19/14 13:35 05/21/14 07:30 111-91-1 bis(2-Chloroethyl) ether NO mg/L 0.0050 1 05/19/14 13`35 05/21/14 07:30 111-44-4 bis(2-Chloroisopropyl) ether ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:30 108-60-1 2-C hlo ro naphthalene ND mg1L 0,0050 1 05/19/14 13!35 05/21/14 07:30 91-58-7 2-Chlorophenoi ND mg1L 0.0050 1 05/19/14 13:35 05/21/14 07:30 95-57-8 4-Chlorophenylphenyl ether NO mg/L 0.0050 1 05/19/14 13.35 05/21/14 07:30 7005-72-3 Chrysene NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:30 218-01-9 Dibenz(a,h)anthracene NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:30 53-70-3 -;-_,-1,2-Dichlorobenzene NrJ'mglL 0.0050 1 051i9i'i4-i3:55 O5i2t/1407:30 95-50-1 _ 1,3-Dichlorobenzene NO mg/L 0.0060 1 05/19/14 13:35 05/21/14 07:30 541-?3-1 1,4-Dichlorobenzene ND mg/L 0,0050 1 05/19/14 13:35 05/2111407:30 106-46-7 3,3'-Dichlorobenzidine ND mg/L 0,025 1 05119/1413:35 05/2111407:30 91-94-1 2,4-Dichlorophenol NO mg1L 0.0050 1 05/19/14 13:35 05/21/14 07:30 120-83-2 Diethylphthalate ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:30 84-66-2 2,4-Dimethylphenol ND mg/L 0.010 1 05/19/14 13:35 05/21/14 07:30 105-67-9 Dimethyl phthalate ND mg1L 0.0050 1 05/19/14 13:35 05121/1407:30 131-11-3 Di-n-butylphthalate NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:30 84-74-2 4,6-Dinitro-2-methylphenol NO mg1L 0.020 1 05/19/14 13:35 05/21/14 07:30 534-52-1 2,4-Dinitrophenol NO mg/L 0.050 1 05/19/14 13:35 05/21/14 07:30 51-28-5 2,4-Dinitrotoluene NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:30 121-14-2 2,6-Dinitrotoluene NO mg/L 0.0050 1 05119/1413:35 05/21/14 07:30 606-20-2 Di-n-octylphthalate NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:30 117-84-0 1,2-Diphenylhydrazine NO mg1L 0.0050 1 05/19/14 13:35 05/21/14 07:30 122-66-7 bis(2-Ethylhexyl)phthalate ND mg1L 0.0050 1 05/19/14 13!35 05/21/14 07:30 117-81-7 Fluoranthene ND mg1L 0.0050 1 05/19/14 13:35 05/21/14 07:30 206-44-0 Fluorene - NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:30 86-73-7 Hexachloro-1,3-butadiene NO mg/L 0.0050 1 05/1911413:35 05/21/14 07:30 87-68-3 Hexachlorobenzene NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:30 118-74-1 Hexachlorocyclopentadiene NO mg/L 0.010 1 05/19/14 13:35 05/21/14 07:30 77-47-4 Hexachloroethane NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:30 67-72-1 1ndeno(1,2,3-cd)pyre ne NO mg1L 0.0050 1 05/19/14 13!35 05/21/14 07:30 193-39-5 Isophorone NO mg/L 0.010 1 05/19/14 13:35 05/21/14 07:30 78-59-1 Naphthalene NO mg/L 0,0050 1 05/19/14 13.35 05/21/14 07:30 91-20-3 Nitrobenzene NO mg/L- 0,0050 1 05/19/14 13:35 05/21/14 07:30 98-95-3 2-Nitrophenol NO mg/L 0,0050 1 06/19/14 13:35 05/21/14 07:30 88-75-5 4-Nitrophenol ND mg/L 0.050 1 05/19/14 13:35 05/21/14 07:30 100-02-7 N-Nitrosodimethylamine NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:30 62-75-9 N-Nitroso-di-n-propylamine ND mg1L 0.0050 1 05/19/14 13:35 05/21/14 07:30 621-64-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2014 01:13 PM without the written consent of Pace Analytical Services, Inc.. Page 26 of 51 8CMnaly4ical wwwpacerzbs.cah: ANALYTICAL RESULTS Project: Storm Water Testing Pace Project No.: 92201481 Pace Analytical Services; Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (33"23-8921 Sample: SDO 12 Lab ID: 92201481006 Collected: 05115/1412:35 Received: 06/16/14 13:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 N-Nitrosodiphenyla mine ND mg/L 0.010 1 05/19/14 13:35 05/21/14 07:30 86-30-6 Pentachlorophenol ND mg1L 0.010 1 05/19/14 13:35 05/21/14 07:30 87-86-5 Phenanthrene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:30 85-01-8 Phenol NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:30 108-95-2 Pyrene ND mglL 0.0050 1 05/19/14 13:35 05/21/14 07:30 129-00-0 1,2,4-Trich loro benzene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:30 120-82-1 2,4,6-Trichlorophenol ND mg/L 0.010 1 05/19/14 13:35 05/21/14 07:30 88-06-2 Surrogates Nitrobenzene-d5 (S) 71 % 10-120 1 05/19/14 13:35 05/21/14 07:30 4165-60-0 2-Fluorobiphenyl (S) 76 % 15-120 1 05/19/14 13:35 05/21/14 07:30 321-60-8 Terphenyl-d14 (S) 91 % 11-131 1 05/19/14 13:35 05/21/14 07:30 1718-51-0 Phenol-d6 (S) 27 % 10-120 1 05/19/14 13:35 05/21/14 07:30 13127-83-3 2-Fluorophenol (S) 42 % 10-120 1 05/19/14 13:35 05/21/14 07:30 367-12-4 2,4,6-Tribromophenol (S) 105 % 10-137 1 05/19/14 13:35 05/21/14 07:30 118-79-6 624 Volatile Organics Analytical Method: EPA 624 Acetone ND mg1L 0.010 1 05/20/14 04:16 67-64-1 '-"ACroiein Nu mg/L 0.0050 1 �05120/14 04:16 107-02-3 Acrylonitrile ND 'mg/L 0.050 1 v5/204 04:16 107-13-1 Benzene ND mg/L 0.0020 1 05/20/14 04:16 71-43-2 Bromobenzene NO mg/L 0.0020 1 05/20/14 04:16 .108-86-1 Bromochloromethane ND mg/L 0.0020 1 05/20/14 04:16 74-97-5 Bromodichloromethane ND mg/L 0.0020 1 05/20/14 04:16 75-27-4 Bromoform NO mglL 0.0020 1 0512011404:16 75-25-2 Bromomethane ND mg/L 0.0020 1 05/20/14 04,16 74-83-9 2-Butanone (MEK) NO mg/L 0.0050 1 05/20/14 04:16 78-93-3 n-Butylbenzene ND mg/L 0.0050 1 05/20/14 04:16 104-51-8 sec -Butyl benzene NO mg/L 0.0050 1 05/20/14 04:16 135-98-8 tert-Butylbenzene ND mg/L 0.0050 1 05/20/14 04:16 98-06-6 Carbon disulfide ND mo/L 0.0050 1 05/20/14 04:16 75-15-0 Carbon tetrachloride ND mg/L 0.0020 1 05/20/14 04:16 56-23-5 Chlorobenzene ND mg1L 0.0020 1 05/20/14 04:16 108-90-7 Chloroethane NO mg1L 0.0020 1 05/20/14 04:16 75-00-3 2-Chloroethylvinyl ether NO mg1L 0.0050 1 05/20/14 04:16 110-75-8 Chloroform NO mg/L 0.0020 1 05/20/14 04:16 67-66-3 Chtoromethane ND mg1L 0.0020 1 05/20/14 04:16 74-87-3 2-Chlorotoluene NO mg/L 0.0020 1 05/20/14 04:16 95-49-8 4-Chlorotoluene NO mg/L 0.0020 1 05/20/14 04:16 106-43-4 Dibromochloromethane NO mg/L 0.0020 1 05/20/14 04:16 124-48-1 1,2-Dibromoethane (EDB) NO mg/L 0.0020 1 05/20/14 04:16 106-93-4 Dibromomethane ND mg1L 0.0020 1 05/20/14 04:16 74-95-3 1,2-Dichlorobenzene ND mg/L 0.0020 1 05/20/14 04:16 95-50-1 1,3-Dichlorobenzene NO mglL 0.0020 1 05/20/14 04:16 541-73-1 1,4-Dichlorobenzene NO mg/L 0.0020 1 05/20/14 04:16 106-46-7 1,1-Dichloroethane ND mg/L 0.0020 1 05/20/14 04:16 75-34-3 1,2-Dichloroethane ND mg/L 0.0020 1 05/20/14 04:16 107-06-2 1,1-Dichloroethene ND mg/L 0.0020 1 05/20/14 04:16 75-35-4 L3,M0 M1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. Page 27 of 51 m aceQrialyfical wr .Pacefa5s.mm. ANALYTICAL RESULTS Project: Storm Water Testing Pace Project No.: 92201481 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Sample: SDO 12 Parameters Lab ID: 92201481006 Collected: 05/15/14 12:35 Results Units Report Limit DF Received: 05115114 13:45 Matrix: Water Prepared Analyzed CAS No. Qua[ 624 Volatile Organics Analytical Method: EPA 624 cis-1,2-Dichloroethene ND mg/L 0.0020 1 05/20/14 04:16 156-59-2 trans-1,2-Dichloroethene ND mg/L 0.0020 1 05/2011404:16 156-60-5 1,2-Dichloropropane ND mg/L 0.0020 1 05/20/14 04:16 78-87-5 1, 3-Dichloro propane ND mg/L 0.0020 1 05/20/14 04:16 142-28-9 2,2-Dichloropropane NO mg/L 0.0050 1 05/20/14 04:16 594-20-7 111-Dichloropropene ND mg/L 0.0020 1 05/20/14 04:16 563-58-6 cis-1,3-Dichloropropene ND mg/L 0,0020 1 05/20/14 04:16 10061-01-5 trans- l,3-Dichloropropene ND mg/L 0.0020 1 05/20/14 04:16 10061-C2-6 Ethylbenzene ND mg/L 0.0020 1 05/20/14 04:16 100-41-4 Hexachloro-1,3-butadiene ND mg/L 0.0050 1 05/20/14 04:16 87-68-3 2-Hexanone ND mg/L 0.010 1 05/20/14 04:16 591-78-6 lodomethane ND mg/L 0.010 1 05/20/14 04:16 74-88-4 L2 Isopropylbenzene (Cunene) ND mg/L 0.0050 1 05/20/14 04:16 98-82-8 p4sopropyltoluene ND mg/L 0.0050 1 05/20/14 04:16 99-87-6 Methylene Chloride ND mg/L 0.0020 1 05/20/14 04:16 75-09-2 4-Methyl-2-pentanone (MIBK) ND mg/L 0.010 1 05/20/14 04:16 108-10-1 Methyl-tert-butyl ether ND mg/L 0.0050 1 05/20/14 04:16 1634-04-4 Naphthalene - JD-mg/L- - 0.00150 _ 05120/14 04:16 91-20-3 n-Propylbanzene ND mg/L 0.0050 1 05/20/14 04:16 103-65-1 Styrene NO mg/L 0.0020 1 05/20/14 04:16 100-42-5 1,1,1,2-Tetrachloroethane ND mg/L 0.0020 1 05/20/14 04:16 630-20-6 1,1,2,2-Tetrachloroethane ND mg/L 0.0020 1 05/20/14 04:16 79-34-5 Tetrachloroethene ND mg/L 0.0020 1 05/20/14 04:16 127-18-4 Toluene ND mg/L 0.0020 1 05/20/14 04:16 108-88-3 1,2,3-Trichlorobe nzene ND mg/L 0.0020 1 05/20/14 04:16 87-61-6 1,2, 4-Trichloro benzene ND mg/L 0,0020 1 05/20/14 04:16 120-82-1 1,1,1-Trichloroethane ND mg/L 0.0020 1 05/20/14 04;16 71-55-6 1,1,2-Trichloroethane ND mg/L 0.0020 1 05/20/14 04:16 79-00-5 Trichloroethene ND mg/L 0.0020 1 05/20/14 04:16 79-01-6 Trichlorofluoromethane ND mg/L 0.0020 1 05/20/14 04:16 75-69-4 1,2,3-Trichloropropane ND mg1L 0.0020 1 05/20/14 04:16 96-18-4 1,12-Tfth[orctrifluoroethane ND mg/L 0.0020 1 05/20/14 04:16 76-13-1 1,2,4-Trimethyibenzene ND mg/L 0.0020 1 05/20/14 04:16 95-63-6 1,3,5-Trimethy[benzene ND mg/L 0.0020 1 05/20/14 04:16 103-67-8 Vinyl acetate ND mg/L 0.0050 1 05/20/14 04:16 108-05-4 Vinyl chloride ND mg/L 0.0020 1 05/20/14 0416 75-01-4 m&p-Xylene ND mg/L 0.0050 1 05/20/14 04:16 179601-23-1 o-Xylene ND mg/L 0.0050 1 05/20/14 04:16 95-47-6 Surrogates 4-Bromofluorobenzene (S) 88 % 70-130 1 05/20/14 04:16 460-00-4 Toluene-d8 (S) 98 % 70-130 1 05/20/14 04:16 2037-26-5 1,2-Dichloroethene-d4 (S) 103 % 70-130 1 05/20/14 04:16 17060-07-0 REPORT OF LABORATORY ANALYSIS This report shalr not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. Page 28 of 51 acMnalytical wwvrpaeelabs.com, Project: Storm Water Testing Pace Project No.: 922014S1 Sample: SDO 13 Parameters 2540D Total Suspended Solids Total Suspended Solids 1664 SGT-HEM, TPH Total Petroleum Hydrocarbons 608 GCS Pesticides and PCBs Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC (Lindane) Chlordane (Technical) 4,4'-DDD 4,4'-DDE 4,4'-DDT Dieldrin Endosulfan I Endosulfan suifate Endrin Endrin aldehyde Heptachlor Heptachlor epoxide PCB-1016 (Aroclor 1016) PCB-1221 (Aroclor 1221) PCB-1232 (Aroclor 1232) PCB-1242 (Aroclor 1242) PC13-1248 (Aroclor 1248) PCB-1254 (Aroclor 1254) PCB-1260 (Aroclor 1260) Toxaphene Surrogates Tetra chloro-m-xyl ene (S) Decachlorobiphenyl (S) 200.7 MET ICP Copper Lead Zinc 625 MSSV Acenaphthene Acenaphthylene Acetophenone Aniline Anthracene Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 ANALYTICAL RESULTS Lab ID: 92201481007 Coilected: 05/15/ 14 12:45 Received: 05/15/14 13:45 Matrix: Water Results Units Report Limit DF Prepared Analyzed CAS No. Qual Analytical Method: SM 2540D 7.5 mg/L 2.5 1 Analytical Method: EPA 16646 05119/14 09:52 ND mg/L 5.0 1 05/20/1410:10 Analytical Method: EPA 608 Preparation Method: EPA 3510 ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 21:59 309-00-2 ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 21:59 319-84-6 ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 21:59 319-85-7 ND mg/L 0.000050 1 05/21/14 17.55 05/27/14 21:59 319-86-8 ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 21:59 58-89-9 ND mg/L 0.00050 1 05/21/14 17:55 05/27/14 21:59 57-74-9 ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 21:59 72-54-8 ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 21:59 72-55-9 ND mg1L 0.000050 1 05/21/14 17:55 05/27114 21:59 50-29-3 ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 21:59 60-57-1 ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 21:59 959-98-8 ND mg/L 0.000050 - 1 05/21/14 17:5505127/14 21:59 33213-65-9 NO mg/L 0.000050 1 05/21/14 17:55 05/27/14 21:59 1031-07-8 ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 21:59 72-20-8 ND mg1L 0.000050 1 05/21/14 17:55 05/27/14 21:59 7421-93-4 ND mg/L 0.000050 1 05/21/14 17:55 05/27/14 21:59 76-44-8 ND mg1L 0.000050 1 05/21/14 17:55 05/27/14 21:59 1024-57-3 ND mg/L 0.00050 1 05/21/14 17:55 05/27/14 21:59 12674-11-2 ND mg/L 0.00050 1 05/21/14 17i55 05/27/14 21:59 11104-28-2 ND mg/L 0.00050 1 05/21/14 17:55 05/27/14 21:59 11141-16-5 ND mg/L 0.00050 1 05/21/14 17:55 05/27/14 21:59 53469-21-9 ND mg1L 0.00050 1 05/21/14 17:55 05/27/14 21:59 12672-29-6 ND mg/L 0.00050 1 05/21/14 17:55 05/27/14 21:59 11097-69-1 ND mg/L 0.00050 1 05/21/14 17:55 05/27/14 21:59 11096-82-5 ND mg/L 0.00050 1 05/21/14 17:55 05/27/14 21:59 8001-35-2 35 % 20-110 1 05/21/14 17:55 05/27/14 21:59 877-09-8 39 % 20-138 1 ' 05/21/14 17:55 05/27/14 21:59 2051-24-3 Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 ND mg/L 0.0050 1 05/19/14 18:00 05/22/14 22:56 7440-50-8 ND mg/L 0.0050 1 05/19/14 18!00 05/22/14 22:56 7439-92-1 0.017 mg/L 0.010 1 05/19/14 18:00 05/22/14 22:56 7440-66-6 Analytical Method: EPA 625 Preparation Method: EPA 625 ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:58 83-32-9 ND mg1L 0,0050 1 05/19/14 13:35 05/21/14 07:58 208-96-8 ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:58 98-86-2 ND mg/L 0.010 1 05/19/14 13:35 05/21/14 07:58 62-53-3 ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:58 120-12-7 Date: 05/28/2014 01:18 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 29 of 51 /�57 aceAnaiytical.® w 'Pacoabsxom. 1 ANALYTICAL RESULTS Project: Storm Water Testing Pace Project No.: 92201481 Pace Analytical Services, Inc. 205 East Meadow Road - Surte A Eden, NC 27288 (336)623-8921 sample: SDO 13 Parameters Lab ID: 92201481007 Results Units Collected: 05/15/14 12:45 Report Limit DF Received: 05/15/14 13:45 Matrix: Water Prepared Analyzed CAS No. Qual 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 Senzidine NO mg/L 0.050 1 05119/1413:35 05/21/14 07:58 92-87-5 Benzo(a)anthracene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:58 56-55-3 Benzo(a)pyrene NO mg/L 0,0050 1 05119/1413:35 05/21/14 07:58 50-32-8 Benzo(b)fiuoranthene NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:58 205-99-2 Benzo(g,h,i)perylene NO mglL 0,0050 1 05/19/14 13:35 05/21/14 07:58 191-24-2 Benzo(k)fluoranthen e ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:58 207-08-9 4-Bromophenylphenylether NO mg/L 0.0050 1 05/19/14 13:35 05/2111407:58 101-55-3 Butylbenzylphthalate ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:58 85-68-7 4-Chloro-3-methylphenoi ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:58 59-50-7 bis(2-Chloroethoxy)methane ND mg/L 0.010 1 05/19/14 13:35 05/21/14 07:58 111-91-1 bis(2-Chloroethyl) ether ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:58 111-44-4 bis(2-Chloroisopropyt) ether ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07!58 108-60-1 2-Chloronaphthalene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07i58 91-58-7 2-Chlorophenol ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:58 95-57-8 4-Chlorophenylphenyl ether NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:58 7005-72-3 Chrysene NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:58 218-01-9 Dibenz(a,h)anthracene NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:58 53-70-3 r .- .,....._ 1,2-Dichlorobenzerse" " NO mglL - � T" 05/19/14 13:35 05/21/14 07:58 5-5'-1' 1, s-Dichlorobenzere ND mglt _""U.Uu50 0.0050 1 05/19/14 13:35 05/21/14 07:53 541-73-1 1,4-Dichlorobenzene ND mg/L 0,0050 1 05/1911413:35 05/21/14 07:58 106-46-7 3,3'-Dichlorobenzidine ND mg/L 0.025 1 05/19/14 13:35 05/2111407:58 91-94-1 2,4-Dichlorophenol ND mg/L 0,0050 1 05/19/14 13:35 05/21/14 07:58 120-83-2 Diethytphthalate ND mg/L 0,0050 1 05/19/1413:36 05/21/1407.58 84-66-2 2,4-Dimethylphenol ND mg/L 0.010 1 05/19114 13:35 05/21/14 07:58 105-67-9 Dimethylphthalate ND mglt 0.0050 1 05/19/14 13:35 05121/1407:58 131-11-3 Di-n-butylphthalate ND mg/L. 0.0050 1 05/19/14 13:35 05/21/14 07:58 84-74-2 4,6-Dinitro-2-methylphenol ND mg/L 0.020 1 05/19/14 13:35 05/21/14 07:58 534-52-1 2,4-Dinitro phenol ND mg/L 0.050 1 0511911413:35 0512111407:58 51-28-5 2,4-Dinitrotoluene ND mg/L 0.0050 1 05/19/14 13.35 05/21/14 07:58 121-14-2 2,6-Dinitrotoluene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:58 606-20-2 Di-n-octylp hth a late ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:58 117-84-0 1,2-Diphenylhydrazine ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:58 122-66-7 bis(2- Ethyl hexyl)p hthala te NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:58 117-81-7 Fluoranthene NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:58 206-44-0 Fluorene NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:58 86-73-7 Hexachloro-1,3-butadiene NO mg/L 0,0050 1 05/19/14 13:35 05/21/14 07:58 87-68-3 Hexachlorobenzene NO mg/L 0,0050 1 05/19/14 13:35 05/21/14 07:58 118-74-1 Hexachlorocyclo pentad ie ne NO mg1L 0.010 1 05/19/14 13:35 05/21/14 07:58 77-47-4 Hexachloroethane ND mg/L 0.0050 1 05/19114 13:35 05/21/14 07:58 67-72-1 Indeno(1,2,3-cd)pyrene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:58 193-39-5 Isophorone ND mg/L 0.010 1 05/19/14 13:35 05/21/14 07:58 78-59-1 Naphthalene ND mg/L 0.0050 1 0511911413:35 05121/1407:58 91-20-3 Nitrobenzene ND mg/L 0"0050 1 05/19114 13:35 05/21/14 07:58 98-95-3 2-Nitrophenol ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07.58 88-75-5 4-Nitrophenol ND mg/L 0.050 1 05/19/14 13:35 05/21/14 07:58 100-02-7 N-Nitrosodimethylamine ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:58 62-75-9 N-Nitroso-di-n-propylamine NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:58 621-64-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Pace Analytical Services, Inc- Page 30 of 51 m aceAnalytical. wriw pacelabs com. ANALYTICAL RESULTS Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: Storm Water Testing Pace Project No.: 92201481 Sample: SDO 13 Lab ID: 92201481007 Collected: 05/15/14 12:45 Received: 05/15/14 13:45 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 N-Nitrosodiphenylamine ND mg/L 0.010 1 05/19/14 13:35 05/21/14 07:53 86-30-6 Pentachlorophenol ND mg/L 0.010 1 05/19/14 13:35 05/21/14 07:58 87-86-5 Phenanthrene NO mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:58 85-01-B Phenol NO mg/L 0-0050 1 05/19/14 13:35 05/21/14 07:58 108-95-2 Pyrene ND mg/L 0.0050 1 05/19/14 13:35 05/21/14 07:58 129-00-0 1,2,4-Trichlorobenzene NO mg1L 0.0050 1 05/19/14 13:35 05/21/14 07:58 120-82-1 2,4,6-Trich lorophenol NO mg/L 0.010 1 05/19/14 13:35 05/21/14 07:58 88-06-2 Surrogates Nitrobenzene-d5 (S) 58 % 10-120 1 05/19/14 13:35 05/21/14 07:58 4165-60-0 2-Fluorobiphenyl (S) 60 % 15-120 1 05/19/14 13:35 05/21/14 07:58 321-60-8 Terphenyl-d14 (S) 80 % 11-131 1 05/19/14 13:35 05/21/14 07:58 1718-51-0 Phenol-d6 (S) 20 % 10-120 1 05119114 13:35 05/21/14 07:58 13127-88-3 2-Fluorophenol (S) 32 % 10-120 1 05/19/14 13:35 05/21/14 07:58 367-12-4 2,4,6-Tribromophenol (S) 102 % 10-137 1 05/19/14 13:35 05/21/14 07:58 118-79-6 624 Volatile Organics Analytical Method. EPA 624 Acetone NO mgfL 0.010 1 05/20/14 04:33 67-64-1 .Acrolein NO mall_'. .0.0 50 1 05120/14'04:33 107-02-8_ ._ --• Acrylonitrile NO mg1L 0.050 1 05/210/14 04:33 107-13-1. Benzene NO mg/L 0.0020 1 05/20/14 04:33 71-43-2 Bromobenzene ND mg/L 0.0020 1 05/20/14 04:33 108-86-1 Bro mochloro methane ND mg/L 0.0020 1 05/20/14 04:33 74-97-5 Bro mod ichlorom ethane ND mg/L 0.0020 1 05/20/14 04:33 75-27-4 Bromoform NO mg/L 0.0020 1 05/20/14 04.33 75-25-2 Bromomethane ND mg/L 0.0020 1 05/20/14 04:33 74-83-9 2-Butanone (MEK) NO mg/L 0.0050 1 05/20/14 04:33 78-93-3 n-Butylbenzene ND mg1L 0.0050 1 05/20/14 04:33 104-51-8 sec-Butylbenzene NO mg1L 0.0050 1 05/20/14 04:33 135-98-8 tert-Butylbenzene NO mg/L 0,0050 1 05/20/14 04:33 98-06-6 Carbon disulfide NO mg/L 0,0050 1 05/20/14 04:33 75-15-0 Carbon tetrachloride NO mg/L 0.0020 1 06/20/14 04:33 56-23-5 Chlorobenzene ND mg/L 0.0020 1 05/20/14 04:33 108-90-7 Chloroethane ND mg/L 0.0020 1 05/20/14 04:33 75-00-3 2-CNoroethylvinyl ether ND mg/L 0,0050 1 05/20/14 04:33 110-75-8 Chloroform ND mg/L 0,0020 1 05/20/14 04:33 67-66-3 Chloromethane ND mg/L 0.0020 1 05/20/14 04:33 74-37-3 2-Chlorotoluene NO mg1L 0.0020 1 05/20/14 04:33 95-49-8 4-Chlorotoluene NO mg1L 0.0020 1 06/20/14 04:33 106-43.4 Dibromochloromethane ND mg/L 0.0020 1 05/20/14 04:33 124-48.1 1,2-Dibromoethene (EDS) NO mg/L 0.0020 1 05/20/14 04:33 106-93-4 Dibromomethane NO mg/L 0.0020 1 05/20/14 04:33 74-95-3 1,2-Dichlorobenzene ND mg/L 0.0020 1 05/20/14 04:33 95-50-1 1,3-Dichlorobenzene ND mg/L 0.0020 1 05/20/14 04:33 541-73-1 1,4-Dichlorobenzene NO mg/L 0.0020 1 05/20/14 04:33 106-46-7 1,1-Dichloroethane NO mg/L 0.0020 1 05/20114 04:33 75-34-3 1,2-Dichloroethane NO mg/L 0.0020 1 05/20/14 04:33 107-06-2 1,1-Dichloroethene ND mg/L 0.0020 1 05/20/14 04:33 75-35-4 L3 Qua] REPORT OF LABORATORY ANALYSIS This report shag not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. Page 31 of 51 e aceAnalylical wwVrpacefjftcom; ANALYTICAL RESULTS Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: Storm Water Testing Pace Project No.: 92201481 Sample: SOO 13 Lab ID: 92201481007 Collected: 05115/1 4 12:45 Received: 05/15/14 13!45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 624 Volatile Organics Analytical Method: EPA 624 cis-1,2-Dichloroethene NO mg/L 0.0020 1 05/20/14 04:33 156-59-2 trans-1,2-Dichioroethene ND mg/L 0,0020 1 05/20/14 04:33 156-60-5 1,2-Dichloropropane ND mg/L 0.0020 1 05/20/14 04:33 78-87-5 1,3-Dichloropropane NO mg/L 0.0020 1 05/20/14 04.33 142-28-9 2,2-Dichloropropane NO mg/L 0.0050 1 05/20/14 04:33 594-20-7 1,1-Dichloropropene NO mg/L 0.0020 1 05/20/14 04:33 563-58-6 cis-1,3-Dichloropropene ND mg/L 0.0020 1 05/20/14 04:33 10061-01-5 trans- 1,3-Dichloropropene ND mg/L 0.0020 1 05120/1404:33 10061-02-6 Ethylbenzene NO mg/L 0.0020 1 05/20/14 04:33 100-41-4 Hexachloro-1,3-butadiene NO mg/L 0.0050 1 05/20/14 04:33 87-68-3 2-Hexanone ND mg/L 0.010 1 05/20/14 04:33 591-78-6 lodomethane ND mg/L 0.010 1 05/20/14 04:33 74-88-4 L2 Isopropylbenzene (Cumene) NO mg/L 0.0050 1 05/20/14 04:33 98-82-8 p-lsopropyltoluene NO mg1L 0,0050 1 05/20/14 04:33 99-87-6 Methylene Chloride ND mg1L 0.0020 1 05/20/14 04:33 75-09-2 4-Methyl-2-pentanone (MIBK) ND mg/L 0.010 1 05/20/14 04:33 108-10-1 Methyl-tert-butyl ether NO mg/L 0.0050 1 05/20/14 04:33 1634-04-4 -'Naphthalene NO mg/L 0.0050 1 05/20 i404:33'91-20-3- r:-Propylbenzene -ND-,mg/L 0,0050 1 05120/14 04:33 103-65-1 Styrene ND mg/L 0,0020 1 05/20/14 04!33 100-42-5 1,1,1,2-Tetrachloroethane ND mg/L 0.0020 1 05/20/14 04:33 630-20-6 1,1,2,2-Tetrachloroethane ND mg/L 0.0020 1 05/20/14 04:33 79-34-5 Tetrachioroethene NO mg/L 0.0020 1 05/20/14 04:33 127-18-4 Toluene ND mg/L 0.0020 1 05/20/14 04:33 108-88-3 1,2,3-Trichlorobenzene ND mg/L 0.0020 1 05/20/14 04:33 87-61-6 1,2,4-Trichlorobenzene NO mg/L 0.0020 1 05/20/14 04:33 120-82.1 1,1,1-Trichloroethane ND mg/L 0.0020 1 05/20/14 04:33 71-55-6 1,1,2-Trichloroethane ND mg/L 0.0020 1 05/20/14 04:33 79-00-5 Trichloroethene ND mg/L 0,0020 1 05/20/14 04:33 79-01-6 Trichlorofluoromethane NO mg/L 0.0020 1 05/20/14 04:33 75-69-4 1,2,3-Trichloropropene NO mg/L 0.0020 1 05/20/14 04:33 96-18-4 1,1,2-Trichlorotrifluoroethane ND mg/L 0.0020 1 05/20/14 04:33 76-13-1 1,2,4-Trim ethyl benzene NO mg/L 0.0020 1 05/20/14 04:33 95-63-6 1,3,5-Trimethylbenzene NO mg/L 0.0020 1 05/20/14 04:33 108-67-8 Vinyl acetate ND mg/L 0.0050 1 05/20/14 04:33 108-05-4 Vinyl chloride ND mg/L 0.0020 1 05/20/14 04:33 75-01-4 m&p-Xylene ND mg/L 0.0050 .1 05/20/14 04:33 179601-23-1 o-Xylene NO mg/L 0.0050 1 05/20/14 04:33 95-47-6 Surrogates 4-Bromofluorobenzene (S) 88 % 70-130 1 06/20/14 04:33 460-00-4 Toluene-d8 (S) 97 %, 70-130 1 05/20/14 04:33 2037-26-5 1,2-Dichloroethane-d4 (S) 104 % 70-130 1 05/20/14 04:33 17060-07-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. Page 32 of 51 aceAnalytical www pacdlabs.rnm; QUALITY CONTROL -DATA Project: Storm Water Testing Pace Project No.: 92201481 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 OC Batch: EDEN114591 Analysis Method: SM 2540D QC Batch Method: SM 2540D Anaiysis Description: 25400 Total Suspended Solids Associated Lab Samples: 92201481001, 92201481002, 92201481003, 92201481004, 922014810057 92201481006, 92201481007 METHOD BLANK: 1201825 Matrix: Water Associated Lab Samples: 92201481001, 92201481002, 92201481003, 92201481004, 92201481005, 92201481006, 92201481007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 05/1211409:45 LABORATORY CONTROL SAMPLE: 1201826 Spike LCS LCS %fl Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg/L 250 238 95 80-120 SAMPLE DUPLICATE: 1201827 92201421001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids ~ mg/L 18.4 20.0 8 SAMPLE DUPLICATE: 1202196 Parameter Total Suspended Solids 92201422001 Dup Units Result Result mg/L 40.7 37.0 RPD Qualifiers 9 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. Page 33 of 51 aceAnalytical wrm!pacelaSs.rnm: QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92201481 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 OC Batch: GCSV/17656 Analysis Method: EPA 1664B OC Batch Method: EPA 1664B Analysis Description: 1664 SGT-HEM, TPH Associated Lab Samples: 92201481001, 92201431002, 92201481003, 92201481004, 92201481005, 92201481006, 92201481007 METHOD BLANK: 1202375 Matrix: Water Associated Lab S2mples: 92201481001, 92201481002, 92201481003, 92201481004, 92201481005, 92201481006, 92201481007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Petroleum Hydrocarbons mg/L ND 5.0 05/20/14 09:43 LABORATORY CONTROL SAMPLE: 1202376 Parameter Units Total Petroleum Hydrocarbons mg/L MATRIX SPIKE SAMPLE: 1202377 Parameter Units T,:�•ai Petroleumn Hydrocarbons ma/L Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 20 17.3 86 64-132 92201829002 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers NU _22:2 18.9 t35 64-132 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. Page 34 of 51 ateAnalytical wmrpaoe/abs.com: QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92201481 Pace Analytical Services, Inc. 265 East Meadow Road - Suite A Eden, NC 27288 (336)62M921 QC Batch: MPRP115990 Anaiysis Method: EPA 200.7 QC Batch Method: EPA 200.7 Analysis Description: 200.7 MET Associated Lab Samples: 92201481001, 92201481002, 92201481003, 92201481004, 92201481005, 92201481006, 92201481007 METHOD BLANK: 1202179 Matrix: Water Associated Lab Samples: 92201481001, 92201481002, 92201481003, 92201481004, 92201481005, 92201481006, 92201481007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Copper mg/L ND 0.0050 05/22/14 22:07 Lead mg/L ND 0,0050 05/22/14 22:07 Zinc mg/L ND 0.010 05/22/14 22:07 LABORATORY CONTROL SAMPLE: 1202180 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Copper mglL .5 0.46 92 85-115 Lead mglL .5 0.47 93 85-115 Zinc mglL .5 0.46 91 85-115 k4AIRIX SPiKE & MA I RIX SPIKE DUPLICATE: 1202131 12021K MS MSD 92201465001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Copper mglL ND .5 .5 0.46 0.46 92 92 70-130 0 Lead mglL ND .5 .5 0.46 0.46 93 92 70-130 0 Zinc mg/L ND .5 .5 0,46 0.46 91 91 70-130 0 Qua] MATRIX SPIKE S MATRIX SPIKE DUPLICATE: 1202183 1202184 MS MSD 92201604001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua] Copper mg/L ND 5 .5 0,46 0.46 91 91 70-130 1 Lead mg/L ND .5 .5 0.46 0.46 93 92 70-130 1 Zinc mg/L 66.2 .5 .5 0.52 0.52 90 90 70-130 0 uglL Results presented on this page are in the units indicated by the "Units- column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shaft not be reproduced, except in full, Date: 05/23/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. Page 35 of 51 .aceAnalytical ' www.paceJa6s.com: QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92201481 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336}623-8421 QC Batch: MSV/26871 Analysis Method: EPA 624 QC Batch Method: EPA 624 Analysis Description: 624 MSV Associated Lab S2mples: 92201481001, 92201481002, 92201481003, 92201481004, 92201481005, 92201481006, 92201481007 METHOD BLANK: 1202218 Matrix: Water Associated Lab Samples: 92201481001, 92201481002, 92201431003, 92201481004, 92201481005, 92201481006, 92201481007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,1,1,2-Tetrachloroethane mglL ND 0.0020 05/20/14 00:27 1,1,1-Trichioroethane mg/L ND 0.0020 05/20/14 00:27 1,1,2,2-Tetrachloroethane mg/L ND 0.0020 05/20/14 00:27 1,1,2-Trichooroethane mg/L ND 0.0020 05/20/14 00:27 1,1,2-Trichlorotrifluoroethane mg/L NO 0.0020 05/20/14 00:27 1,1-Dichloroethane mg/L ND 00020 05/20/14 00:27 1,1-Dichloroethene mg/L ND O.0020 05/20/14 00:27 1,1-Dichloropropene mg/L ND 0.0020 05/20/14 00:27 1,2,3-Trichlorobenzene mg/L ND O,0020 05/20/14 00:27 1,2,3-Trichloropropane mg/L ND 0.0020 05/2011400:27 1,2,4-Trichlorobenzene mg/L ND 0.0020 05/20/14 00:27 1,2,4-Trimethyibenzene mg1L ND 0.0020 05/20/14 00:27 1.2-Dibromoethane (EDB) - mg/L "mg/L ND 0.0020 05/20/14 00:27 .1,7. Dsrhlorobenzene -" -- :._:_ ND _ .._':. 0:0020` 05/20/14 00:27 1.2-Dichloroethane mg/L ND 0.0020 05/20/14 00:27 1,2-Dichloropropane mg/L ND 0.0020 05/20/14 00:27 1,3,5-Trimethylbenzene mg/L ND 0.0020 05/20/14 00:27 1,3-Dichlorobenzene mg/L ND 0.0020 05/20/14 00:27 1,3-Dichloropropane mg1L ND 0.0020 05/20/14 00:27 1,4-Dichlorobenzene mg/L ND 0.0020 05/20/14 00:27 2,2-D ichloro propane mglL ND 0.0050 05/20/14 00:27 2-Butanone (MEK) mg1L ND 0.0050 05/20/14 00:27 2-Chloroethylvinyl ether mg/L ND 0.0050 05/20/14 00:27 2-Chlorotoluene mg/L ND 0.0020 05/20/14 00:27 2-Hexanone mg/L ND 0.010 05/20/14 00:27 4-Chlorotoluene mg/L ND 0.0020 05/20/14 00:27 4-Methyl-2-pentanone (MIBK) mg/L ND 0.010 05/20/14 00:27 Acetone mg/L NO 0.010 05/20/14 00:27 Acrolein mg1L ND 0.0050 05/20/14 00:27 Acrylonitriie mg1L NO 0.050 05/20/14 00:27 Benzene mg/L NO 0.0020 05/20/14 00:27 Bromobenzene mg/L NO 0.0020 05/20/14 00:27 Bromochloromethane mg/L ND 0,0020 05/20/14 00:27 Bromodichloromethane mg/L ND 0,0020 05/20/14 00:27 Bromoform mg1L ND 0.0020 05/20/14 00:27 Bromomethane mg/L ND O,0020 05/20/14 00:27 Carbon disulfide mg/L ND 0.0050 05/20/14 00:27 Carbon tetrachloride mg/L ND 0.0020 05/20/14 00:27 Chlorobenzene mg/L ND 0.0020 05/20/14 00:27 Chloroethane mg1L ND 0.0020 05/20/14 00:27 Chloroform mglL ND 0.0020 05/20/14 00:27 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Pace Analytical Services, Inc." Page 36 of 51 d aceAnalytical wrm.�labs.conr QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92201481 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8421 METHOD BLANK: 1202218 Matrix: Water Associated Lab Samples: 92201481001, 92201481002, 92201481003, 92201481004, 92201481005, 92201481006, 92201481007 Blank Reporting Parameter Units Result Limit Analyzed Quaiifiers Chloromethane mg/L ND 0.0020 05/20/14 00:27 cis- 1,2-Dichloroethene mg1L NO 0.0020 05120/1400:27 cis-1,3-Dichloropropene mg/L NO 0.0020 05/20/14 00:27 Dibromochloromethane mg/L ND 0.0020 0512011400:27 Dibromomethane mg/L ND 0.0020 05/20/14 00:27 Ethylbenzene mg/L NO 0.0020 05/20/14 00:27 Hexachloro-1,3-butadiene mg/L ND 0.0050 05/20114 00:27 lodomethane mg/L NO 0.010 05/20/14 00:27 Isopropyl benzene (Cumene) mg/L ND 0,0050 05/20/14 00:27 m&p-Xylene mg/L ND 0.0050 05/20/14 00:27 Methyl-tert-butyl ether mg/L ND 0.0050 05/20/14 00:27 Methylene Chloride mg/L ND 0.0020 05/20/14 00:27 n-Butylbenzene mg/L ND 0,0050 05/20/14 00:27 n-Propylbenzene mg/L ND 0.0050 05/20/14 00:27 Naphthalene mg/L ND 0.0050 05/20/14 00:27 o-Xylene mg/L ND 0.0050 05/20/14 00:27 p-Isopropyltoluene mg/L ND 0.0050 05/20/14 00:27 se-Putylbenzene mg1L ND 0.0050 06/20/14 00:27 Styrene mglL NO 0.0020 05/20/14 00:27 tert-Butylbenzene mg1L ND 0.0050 05/20/14 00:27 Tetra chloroethene mg/L ND 0.0020 05/20114 00:27 Toluene mg/L ND 0.0020 05/20/14 00:27 trans-1,2-Dichloroethene mg1L ND 0.0020 05/20/14 00:27 trans- 1,3-Dichloropro pene mg/L ND 0.0020 05/20/14 00:27 Trichloroethene mg1L ND 0.0020 05/20/14 00:27 Trichlorofluo ro methane mg/L ND 0.0020 05/20/14 00:27 Vinyl acetate mg/L ND 0.0060 05/20/14 00.27 Vinyl chloride mg/L ND 0.0020 05/20/14 00:27 1,2-Dichloroethane-d4 (S) % 103 70-130 05/20/14 00:27 4-Bromofluorobenzene (S) % 98 70-130 05/20/14 00:27 Toluene-d8 (S) % 98 70-130 05/20/14 00:27 LABORATORY CONTROL SAMPLE: 1202219 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1.2-Tetrachloroethane mg/L .02 0.021 106 70-130 1,1,1-Trichloroethane mg/L .02 0.021 104 52-162 1,1,2,2-Tetrachloroethane mg/L .02 0.022 109 46-157 1,1,2-Trichloroethane mg/L .02 0.022 110 52-150 1,1,2-Trichlorotrifiuoroethane mg/L .02 0.016 80 70-130 1,1-Dichloroethane mg/L .02 0.021 103 59-155 1.1-Dichloroethene mg/L .02 0.021 106 1-234 1,1-Dichloropropene mg/L .02 0.022 109 70-130 1,2,3-Trichlorobenzene mg/L .02 0.022 108 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. Page 37 of 51 aceAnalytical www, pacelabs cram, I QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92201481 LABORATORY CONTROL SAMPLE: 1202219 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Parameter Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,2,3-Trichloropropane mg/L .02 0.021 104 70-130 1,2,4-Trichlorobe nzene mg/L .02 0.021 105 70-130 1,2,4-Trimethylbenzene mg/L .02 0.022 111 70-130 1,2-Dibromoethane (EDB) mg/L .02 0.021 107 70-130 1,2-Dichlorobenzene mg/L .02 0.022 108 18-190 1,2-Dichloroethane mg/L .02 0.021 106 49-155 1,2-Dichloropropane mg/L .02 0.022 108 1-210 1,3,5-Trim ethyl benzene mglL .02 0.022 108 70-130 1,3-Dichlorobenzene mg/L .02 0.021 105 59-156 1,3-Dichloropropane mg/L .02 0.022 109 70-130 1,4-Dichlorobenzene mg/L .02 0.021 107 18-190 2,2-Dichloropropane mg/L .02 0.019 94 70-130 2-Butanone (MEK) mg/L .04 0.030 74 50-127 2-Chloroethylvinyl ether mg/L .04 0.041 103 1-305 2-Chlorotoluene mg/L .02 0.021 107 70-130 2-Hexanone mg/L .04 0.036 89 70-130 4-Chlorotoluene mg/L .02 0.020 101 70-130 4-Methyl-2-pentanone (MIBK) mg/L .04 0.035 87 70-130 Acetone :.... _. -. ing/L - 0.033 83 7C-' 30 Acroiei mg/L 1 0.099 99 16a:l52 Acrylonitrile mg/L 1 0.11 110 75-132 Benzene mg/L :02 0.023 116 37-151 Bromobenzene mg/L .02 0.021 106 70-130 Bromochloromethane mg/L .02 0.022 112 70-130 Bromodichioromethane mg/L .02 0.021 103 35-155 Bromoform mg/L .02 0.019 97 45-169 Bromomethane mg1L .02 0.011 56 1-242 Carbon disuifide mg1L .02 0.033 166 70-130 LO Carbon tetrachloride mg/L 02 0.020 99 70-140 Chlorobenzene mg/L .02 0.020 102 37-160 Chloroethane mg/L .02 0.024 118 14-230 Chloroform mg/L .02 0.021 107 51-138 Chloromethane mg/L .02 0.016 80 1-273 cis- 1, 2-D ichloroethene mg/L .02 0.021 105 68-146 cis-1,3-Dichloropropene mglL .02 0,021 107 1-227 Dibromochloromethane mg1L .02 0,019 97 53-149 Dibromomethane mg/L .02 0.021 105 70-130 Ethylbenzene mg/L .02 0.021 103 37-162 Hexachloro-1,3-butadiene mg/L .02 0.020 98 70-130 lodomethane mg/L .04 0,023 57 70-130 LO Isopropylbenzene (Cumene) mg/L .02 0.021 107 70-130 m&p-Xylene mg1L .04 0.043 107 70-130 Methyl-tert-butyl ether mg1L .02 0.018 91 70-130 Methylene Chloride mg/L .02 0.023 114 1-221 n-Butylbenzene mg/L .02 0.021 106 70-130 n-Propylbenzene mg/L .02 0.021 107 70-130 Naphthalene mg/L .02 0.022 112 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/23/2014 01:18 PM without the written consent of Pace Analytical Services, inc.. Page 38 of 51 aceAnalytical www.pacelabAcprr QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92201481 LABORATORY CONTROL SAMPLE: 1202219 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623.5921 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers o-Xylene mg/L .02 0.021 105 70-130 p-Isopropyltoluene mg/L .02 0.021 105 70-130 sec-Butylbenzene mg/L .02 0.021 104 70-130 Styrene mg/L .02 0.022 111 70-130 tent-Butylbenzene mg/L .02 0.021 104 70-130 Tetrachloroethene mg/L .02 0.021 107 64-148 Toluene mg/L .02 0.021 105 47-150 trans-1,2-Dichloroethene mg/L .02 0.022 108 54-156 trans-1,3-Dichloropropene mg/L .02 0.021 103 17-183 Trichloroethene mg/L .02 0.023 113 71-157 Trichlorofluoromethane mg/L .02 0,020 100 17-181 Vinyl acetate mg1L .04 0.047 119 70-130 Vinyl chloride mg/L .02 0.022 111 1-251 1,2-Dichloroethane-d4 (S) % 105 70-130 4-Bromofluorobenzene (S) % 98 70-130 Toluene-d8 (S) % 100 70-130 ' NiP I Rik SPIKE SAMPLE:-- "' 1202412 92201431006 SYilce ' lti1S " Ms. % Rec Parameter Units Result Conc. Result % Rec Limits 1,1,1,2-Tetrachloroethane mg/L ND .05 0.056 112 70-130 1,1,1-Trichloroethane mg/L NO .05 0.057 113 46-171 1,1,2,2-Tetrachloroethane mg/L NO .05 0.053 106 73-159 1,1,2-Trichloroethane mg/L NO .05 0.054 109 64-152 1,1,2-Trichlorotrifluoroethane mg/L NO .05 0.047 94 59-168 1,1-Dichloroeth2ne mg1L NO .05 0.054 107 43-172 1,1-Dichloroethene mg/L NO '05 0.058 116 48-189 1,1-Dichloropropene mg/L NO .05 0.060 120 70-130 1,2,3-Trichlorobenzene mg/L NO .05 0.050 99 70-130 1,2,3-Trichloropropane mg/L NO .05 0.052 104 70-130 1,2,4-Trichlorobenzene mg/L NO .05 0.051 102 70-130 1, 2,4-Tri methyl benzene mg/L NO .05 0.054 108 70-130 1,2-Dibromoethane (EDB) mg/L NO .05 0.053 107 70-130 1,2-Dichlorobenzene mg/L NO .05 0.054 107 54-154 1,2-Dichloroethane mg/L NO .05 0.056 113 42-171 1,2-Dichloropropane mg/L NO .05 0.054 109 55-157 1,3,5-Trimethylbenzene mg/L NO .05 0.053 106 70-130 1,3-Dichlorobenzene mg/L NO .05 0.052 105 57-148 1,3-Dichloropropane mg/L NO .05 0.054 107 70-130 1,4-Dichlorobenzene mg/L NO .05 0.053 107 58-149 2,2-Dichloropropane mg/L ND .05 0.058 117 70-130 2-Butanone (MEK) mg/L NO .1 0.079 79 70-130 2-Chloroethylvinyl ether mg/L NO .1 NO 0 70-130 M1 2-Chlorotoluene mg/L NO .05- 0.054 108 70-130 2-Hexanone mg/L NO .1 0.084 84 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Quaiifiers REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date: 05/28/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. Page 39 of 51 aceAnalytical www.pdceraSs_cvm: 1 QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92201481 MATRIX SPIKE SAMPLE: 1202412 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 92201481006 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 4-Chlorotoluene mg/L NO .05 0.052 104 70-130 4-Methyl-2-pentanone (MIBK) mg/L NO .1 0.084 84 70-130 Acetone mg/L ND A 0.076 71 70-130 Acrolein mg/L ND .25 0.26 103 70-130 Acrylonitrile mg1L ND .25 0.27 108 70-130 Benzene mg1L ND .05 0.059 118 54-163 Bromobenzene mg/L NO .05 0.053 106 70-130 Bromochloromethane mg/L NO 05 0.056 112 70-130 Bromodichloromethane mg/L ND .05 0.054 109 56-152 Bromoform mg1L NO .05 0.052 104 53-151 Bromomethane mg1L ND .05 0.056 112 10-200 Carbon disulfide mg/L ND .05 0.093 185 70-130 MO Carbon tetrachloride mg1L ND .05 0,056 112 41-175 Chlorobenzene mg/L ND .05 0.051 103 67-152 Chloroethane mglL ND .05 0.054 109 23-200 Chloroform mg/L ND .05 0.055 110 51-166 Chloromethane mg/L ND .05 0.045 91 40-175 cis- 1,2-D ichloroethene mg1L NO .05 0.055 110 45-174 -v ,Dihloropropc e . yl "5.cis 0.055 111 3S-146 Dibromcl chioromethane mg/L ND .05 0.053 106 65-' ' Dibromomethane mg/L ND .05 0.053 105 70-130 Ethylbenzene mg/L ND .05 0.052 103 57-152 Hexachloro-1,3-butadiene mg/L NO .05 0.057 115 70-130 lodomethane mg/L ND A 0.088 88 70-130 Isopropyl benzene (Cumene) mg/L ND .05 0.054 108 70-130 m&p-Xylene mg/L ND .1 0.10 104 70-130 Methyl-tert-butyl ether mg/L ND .05 0.044 88 70-130 Methylene Chloride mg/L ND .05 0.049 98 40-167 n-Butylbenzene mg/L NO .05 0.055 109 70-130 n-Propylbenzene mg/L ND .05 0.054 108 70-130 Naphthalene mg/L NO .05 0.051 102 70-130 o-Xylene mg/L NO .05 0.053 105 70-130 p-Isopropyltoluene mg1L NO .05 0.053 105 70-130 sec-Butylbenzene mg/L NO 05 0.053 105 70-130 Styrene mg/L ND .05 0.054 108 70-130 tent-Butylbenzene mg/L NO .05 0.053 106 70-130 Tetra chloroethene mg/L NO .05 0.057 113 59-155 Toluene mg/L NO .05 0.054 108 47-162 trans-1,2-Dichloroethene mg/L ND .05 0.057 114 47-178 trans-1.3-Dichloropropene mg/L ND .05 0.053 106 39-148 Trcchloroethene mg/L ND .05 0.058 117 60-153 Trich lorofluoromethane mg/L ND .05 0.058 115 42-199 Vinyl acetate mg/L ND .1 0.11 114 70-130 Vinyl chloride mg1L NO .05 0.064 127 46-176 1,2-Dichloroethane-d4 (S) % 108 70-130 4-Bromofluorobenzene (S) % 93 70-130 Toluene-d8 (S) % 100 70-130 Results presented on this page are in the units indicated by the "Units- column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. Page 40 of 51 aceAnalytical wwwpacelab&=m. I QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92201481 SAMPLE DUPLICATE: 1202415 Parameter Units 92201481007 Result Dup Result 1,11,2-Tetrachloroethane mg/L NO NO 1,1,1-Trichloroethane mg/L NO NO 1,1,2,2-Tetrachloroethane mg/L NO NO 1,1,2-Trichloroethane mg/L NO NO 1,1,2-Trichlorotrifiuoroethane mg/L ND NO 1,1-Dichloroethane mg/L NO NO 1,1-Dichloroethene mg/L NO NO 1,1-Dichloropropene mg/L NO NO 1,2,3-Trichlorobenzene mg/L NO NO 1,2,3-Trichloropropane mg/L NO NO 1,2,4-Trichlorobe nzene mg1L NO NO 1,2,4-Trimethylbenzene mg/L NO NO 1,2-Dibromoethane (EDB) mg/L NO NO 1,2-Dichlorobenzene mg/L NO NO 1,2-Dichloroethane mg/L NO NO 1,2-Dichloropropane mg/l_ NO NO 1,3,5-Trimethylbenzene mg/L NO NO 1,3-Dichlorobenzene mg/L NO NO 1.3-Dichloropropane t'r191L•• ,.= _ __ND........._ ... NO: - 1';4-Dichlorobenzene mglL' Nii NO 2,2-Dichloropropane mg/L NO NO 2-Butanone (MEK) mg1L NO NO 2-Chloroethylvinyl ether mg/L NO NO 2-Chlorotoluene mg/L NO NO 2-Hex2none mg/L NO NO 4-Chlorotoluene mg/L NO NO 4-Methyl-2-pent2none (MIBK) mg/L NO NO Acetone mg1L NO .0051 Acrolein mg1L NO NO Ao ylonitrile mg1L NO NO Benzene mg/L NO NO Bromobenzene mg/L NO NO Bromochioromethane mg/L NO NO Bromodichloromethane mg/L NO ND Bromoform mg/L NO NO Bromomethane mg/L NO NO Carbon disulfide mg/L NO NO Carbon tetrachloride mg/L NO NO Chlorobenzene mg/L NO NO Chloroethane mglL NO NO Chloroform mg1L NO NO Chloromethane mg/L NO NO cis- 1,2-D ichloroethene mg/L NO NO cis- 1,3-Dichloropropene mg1L NO NO Dibromochloromethane mg/L NO NO Dibromomethane mg/L NO ND, Ethylbenzene mg/L NO NO RPD Qualifiers Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. Page 41 of 51 qo aceAnalytical .vww.pacefabs.crom: i QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92201481 SAMPLE DUPLICATE: 1202415 Parameter Units 92201481007 Dup Result Result Nexachloro-1,3-butadiene mg/L ND iodomethane mg/L ND Isopropylbenzene (Cumene) mg/L ND m&p-Xylene mg/L ND Methyl-tert-butyl ether mg/L ND Methylene Chloride mg/L ND n-Butylbenzene mg/L ND n-Propylbenzene mg/L ND Naphthalene mg/L ND o-Xylene mg/L ND p-Isopropyltoluene mg/L NO sec-Butylbenzene mg/L NO Styrene mg/L ND tert-Butyl benzene mg/L ND Tetrachioroethene mg/L ND Toluene mg/L ND trans- 1, 2-Dichloroethene mg/L NO trans- 1, 3-Dichloropropene mg/L ND T i idh;uToeihene ND '-Trichloroflucromethane mg/L ND Vinyl acetate mg/L NO Vinyl chloride mg/L ND 1,2-Dichloroethane-d4 (S) % 104 4-Bromofluorobenzene (S) %, 88 Toluene-d8 (S) % 97 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 RPD Qualifiers NO NO NO NO NO NO ND NO NO NO NO NO NO NO NO NO ND NO NO NO , NO ND 102 2 86 2 98 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Face Analytical Services, Inc.. Page 42 of 51 aceAnalytical wrm!pacefaDs.cortt: QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92201431 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 QC Batch: OEXT/27835 Analysis Method: EPA 608 QC Batch Method: EPA 3510 Analysis Description: 608 GCS Pest PCB Associated Lab Samples: 92201481001, 92201481002, 92201481003, 92201481004, 92201481005, 92201481006, 92201481007 METHOD BLANK: 1204226 Matrix: Water Associated Lab Samples: 92201481001, 92201481002, 92201481003, 92201481004, 92201481005, 92201481006, 92201481007 Blank Reporting Parameter Units Result •Limit Analyzed Qualifiers 4,4'-DDD mg/L ND 0.000050 0512711416:47 4,4'-ODE mg1L ND 0,000050 0512711416:47 4,4'-DDT mg/L ND 0.000050 05127/1416:47 Aldrin mg/L NO 0.000050 05127/1416:47 alpha-BHC mg/L ND 0.000050 0512711416:47 beta-BHC mg/L ND 0,000050 05/27/14 16:47 Chlordane (Technical) mg/L ND 0.00050 05/27/14 16:47 delta-BHC mg/L ND 0.000050 05127/1416:47 Dieldrin mg/L NO 0.000050 0512711416:47 Endosulfan I mg/L ND 0.000050 05/27/14 16.47 Endosulfan II mg/L NO 0.000050 05/27/14 16:47 Endosulfan sulfate mg/L ND 0.000050 05/27/14 16:47 Endrin mgfL ND 0.000050 05127/1416:47 Endrin 3ldrh..,de meIL 0.000050 05/27/14 1,6:47 gamma-BHC (Lindane) mg1L ND 0.000050 05/27/14 16:47 Heptachlor mg1L NO 0.000050 05/2711416:47 Heptachlor epoxide mg/L NO 0.000050 05/27/14 16:47 PCB- 1016 (Aroclor 1016) mg/L ND 0.00050 05/27/14 16:47 PCB-1221 (Aroclor 1221) mg/L NO 0.00050 05/27/14 16:47 PCB-1232 (Aroclor 1232) mg/L ND 0.00050 05/27/14 16:47 PCB-1242 (Aroclor 1242) mg1L NO 0.00050 05/27/14 16:47 PCB-1248 (Aroclor 1248) mg/L NO 0.00050 05/27/14 16:47 PCB-1254 (Aroclor 1254) mg/L ND 0.00050 05/27/14 16:47 PCB-1260 (Aroclor 1260) mg/L ND 0,00050 05/27/14 16:47 Toxaphene mg/L ND 0,00050 05/2711416:47 Decachlorobiphenyl (S) % 75 20-138 05/27/14 16:47 Tetrachloro-m-xylene (S) % 50 20-110 05/27/14 16:47 LABORATORY CONTROL SAMPLE: 1204227 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 4,4'-DDD mg/L. .00025 0.00018 75 31-141 4,4'-DDE mg/L .00025 0.00017 69 30-145 4,4'-DDT mg/L .00025 0.00018 74 25-160 Aldrin mg/L .00025 0.00011 43 42-122 alpha-BHC mg/L .00025 0.00018 73 37-134 beta-BHC mg/L .00025 0.00018 72 17-147 delta-BHC mg1L .00025 0.00019 75 19-140 Dieldrin mg/L .00025 0.00018 72 36-146 Endosulfan I mg1L .00025 0.00018 74 45-153 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. Page 43 of 51 aceAnalytical www.pacclabs.cvm. Project: Storm Water Testing Pace Project No.: 92201481 LABORATORY CONTROL SAMPLE: 1204227 Parameter Units Endosulfan II mg/L Endosulfan sulfate mg/L Endrin mg/L Endrin aldehyde mg/L gamma-BFiC (Lindane) mg/L Heptachlor mg/L Heptachlor epoxide mg/L Decachlorobiphenyl (S) % Tetra chloro-m-xylene (S) % QUALITY CONTROL DATA Spike Conc. LCS Result LCS °Io ReC % Rec Limits .00025 0.00019 77 1-202 .00025 0.00020 81 26-144 .00025 0,00019 75 30-147 .00025 0.00017 67 50-150 .00025 0.00018 72 32-127 .00025 0,00012 49 34-111 .00025 0.00017 68 41-126 76 20-138 71 20-110 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. Page 44 of 51 aceAnalytical wwrvpacclaAs.com� I QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92201451 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336 )623-8921 QC Batch: OEXT/27764 Analysis Method: EPA 625 QC Batch Method: EPA 625 Analysis Description: 625 MSS Associated Lab Samples: 92201481001, 92201481002, 92201481003, 92201481004, 92201481005, 92201481006, 92201481007 METHOD BLANK: 1202026 Matrix: Water Associated Lab Samples: 92201481001, 92201481002, 92201481003, 92201481004, 92201481005, 92201481006, 92201481007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,2,4-Trichoorobenzene mg/L ND 0.0050 05/20/14 21:54 1,2-Dichlorobenzene mg/L ND 0.0050 05/20/14 21:54 1,2-Diphenylhydrazine mg/L NO 0.0050 05/20/14 21:54 1,3-Dichlorobenzene mg1L ND 0.0050 05/20/14 21:54 1,4-Dichlorobenzene mg/L ND 0.0050 05/20/14 21:54 2,4,6-Trichlorophenol mg1L ND 0.010 05/20/14 21:54 2,4-Dichlorophenol mg/L ND 0,0050 05/20/14 21:54 2,4-Dimethylphenol mg/L ND 0.010 05/20/14 21:54 2,4-Dinitrophenol mg/L ND 0,050 05/20/14 21:54 2,4-D'initrotoluene mg1L NO 0.0050 05/20/14 21:54 2,6-Dinitrotoluene mg/L NO 0.0050 05/20/14 21:54 2-Chloronaphthalene mg/L ND 0.0050 05/20/14 21:54 —2,Chlorophengl_ .., .,._ .. mglL ND 0.0050 05120/1421:54 2--Niirophenoi. mg/L ND, _ 0.0050. 05/20/14 21:54 3,3'-Dichlorobenzidine mg/L ND- - 0,025 05/20/14 21:54 4,6-D initro-2-m ethyl phenol mg/L ND 0.020 05/20/14 21:54 4-Bromophenylphenyl ether mg/L NO 0.0050 05/20/14 21:54 4-Chloro-3-methyl phenol mg/L ND 0.0050 05/20/14 21:54 4-Chlorophenylphenyl ether mg/L ND 0,0050 05/20/14 21:54 4-Nitrophenol mg/L ND 0.050 05/20/14 21:54 Acenaphthene mg/L ND 0.0050 05/20/14 21:54 Acenaphthylene mg/L ND 0.0050 05/20/14 21:54 Acetophenone mg/L NO 0.0050 05/20/14 21:54 Aniline mg/L NO 0.010 05/20/14 21:54 Anthracene mg/L NO 0.0050 05/20/14 21:54 Benzidine mg/L NO 0.050 05/20/14 21:54 Benzo(a)anthracene mg/L NO 0.0050 05/20/14 21:54 Benzo(a)pyrene mg/L NO 0.0050 05/20/14 21:54 Benzo(b)Fluoranthene mg/L NO 0.0050 05/20/14 21:54 Benzo(g,h,i)perylene mg/L ND 0.0050 05/20/14 21:54 Benzo(k)#iuoranthene mg/L NO 0.0050 05/20/14 21:54 bis(2-Chloroethoxy)methane mg1L ND 0.010 05/20/14 21:54 bis(2-Chloroethyl) ether mg/L NO 0.0050 05/20/14 21:54 bis(2-Chloroisopropyl) ether mg1L ND 0.0050 05/20/14 21:54 bis(2-Ethylhexyl)phthalate mg/L ND 0.0050 05/20/14 21:54 Butylbenzylphthalate mg/L ND 0.0050 05/20/14 21:54 Chrysene mg/L ND 0.0050 05/20/14 21:54 Di-n-butylphthalate mg/L ND 0.0050 05/20/14 21:54 Di-n-octylphthalate mg1L ND 0.0050 05/20/14 21:54 Dibenz(a,h)anthracene mg1L ND 0.0050 05/20/14 21:54 Diethylphthaiate mg/L ND 0.0050 05/20/14 21:54 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. Page 45 of 51 (5a'oAnalytical' nww.patelab com; QUALITY CONTROL DATA Project Storm Water Testing Pace Project No.: 92201481 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 METHOD BLANK: 1202026 Matrix: Water Associated Lab Samples: 92201481001, 92201481002, 92201481003, 92201481004, 92201481005, 92201481006, 92201481007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers D imethylphtha late mg/L NO 0.0050 05/20/14 21:54 Fluoranthene mg/L NO 0.0050 05/20/14 21:54 Fluorene mg/L ND 0.0050 05/20/14 21:54 Hexachloro-1,3-butadiene mg/L ND 0.0050 05/20/14 21:54 Hexachlorobenzene mg/L ND 0.0050 05/20/14 21:54 Hexachlorocyclopentadiene mg/L ND 0.010 05/20/14 21:54 Hexachloroethane mg/L ND 0.0050 05/20/14 21:54 Indeno(1,2,3-cd)pyrene mg/L ND 0.0050 05/20/14 21:54 Isophorone mglL ND 0.010 05/20/14 21:54 N-Nitroso-di-n-propylamine mg/L ND 0.0050 05/20/14 21:54 N-Nitrosodimethylamine mg/L NO 0.0050 05I20/14 21:54 N-Nitrosodiphenylamine mg/L ND 0.010 05/20/14 21:54 Naphthalene mg/L ND 0.0050 05/20/14 21:54 Nitrobenzene mg/L ND 0.0050 05/20/14 21:54 Pentachiorophenol mg/L NO 0.010 05/20/14 21:54 Phenanthrene mg/L ND 0.0050 05/20/14 21:54 Phenol mg/L ND 0.0050 05/20/14 21:54 -Pyrf ne mg/L ND- u,W50 05720/14 21:54 2,4,6-Trib omophenol (S) % 89 10-137 05/20/14 21:54 2-Fluorobiphenyl (S) % 75 15-120 05/20/14 21:54 2-Fluorophenol (S) % 47 10-120 05/20/14 21:54 Nitrobenzene-d5 (S) % 70 10-120 05/20/14 21:54 Phenol-d6 (S) % 32 10-120 05/20/14 21:54 Terphenyl-d14 (S) % 91 11-131 05/20/14 21:54 LABORATORY CONTROL SAMPLE! 1202027 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,2,4-Tfthlorobenzene mg/L .05 0.040 81 44-142 1,2-Dichlorobenzene mg/L .05 0.039 78 32-129 1,2-Diphenylhydrazine mg1L .05 0.033 67 25-150 1,3-Dichlorobenzene mg/L .05 0.038 75 1-172 1,4-Dichlorobenzene mg/L .05 0.040 80 20-124 2,4,6-Trich lorophenol mg/L .05 0.042 85 37-144 2,4-D ichloro phenol mg/L .05 0.044 87 1-191 2,4-Dimethylphenol mg/L .05 0,043 86 32-119 2,4-Dinitrophenol mg/L .25 0.15 60 1-181 2,4-Dinitrotoluene mg/L .05 0.053 106 39-139 2,6-Dinitrotoluene mg/L .05 0.050 99 50-158 2-Chloronaphthalene mg/L .05 0.043 86 60-118 2-Chlorophenol mg/L .05 0.040 80 23-134 2-Nitrophenol mg/L .05 0.046 93 29-182 3,3'-Dichlorobenzidine mg/L .1 0.080 80 1-262 4,6-Dinitro-2-methylphenol mg/L .1 0.084 84 1-181 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05128/2014 01:18 PM without the written consent of Pace Analyticai Services, Inc.. Page 46 of 51 aceAnalytical rrrw.pacc*bs.com QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92201481 LABORATORY CONTROL SAMPLE: Parameter 1202027 Units Spike Conc. LCS Result LCS % Rec 4-Bromophenylphenyl ether rrg/L .05 0.043 86 4-Chlorc-3-methylphenol rig/L .1 0.087 87 4-Chlorophenylphenyl ether mg/L .05 0.044 89 4-Nitrophenol mg/L .25 0.081 32 Acenaphthene mg/L .05 0.041 82 Acenaphthylene n-g/L .05 0,042 83 Acetophenone mg/L .1 0,041 41 Aniline mg/L .05 0.030 61 Anthracene mg/L .05 0.043 87 Benzidine mg/L .1 .04J 40 Benzo(a)anthrace ne mg/L .05 0.041 83 Benzo(a)pyrene mg/L .05 0.044 88 Benzo(b)fluoranthene mg/L .05 0.042 84 Benzo(g,h,i)perylene mg/L .05 0.042 84 Benzo(k)fluoranthene mg/L .05 0.041 82 bis(2-Chloroethoxy)methane mg1L .05 0.040 79 bis(2-Chlcroethyi) ether mg1L .05 0.040 80 bis(2-Chloroisopropyl) ether mg/L '05 0.041 82 l is(2-E:hyl±•exyl); ` il'3!c`.e - T ,/L .05 0.042 ?4 Butyl benzylphthalate mg/L .05 0.044 88 Chrysene rng/L 05 0.042 85 Di-n-butylphthalate mg/L .05 0.043 86 Di-n-octylphthalate mg/L .05 0.044 88 Dibenz(a,h)anthracene mg/L .05 0.044 88 Diethylphthalate mg/L '05 0,043 85 Dimethylphthaiate mg/L '05 0,042 84 Fluoranthene mg/L .05 0.045 90 Fluorene mglL 05 0,045 90 Hexachloro-1,3-butadiene mg/L _05 0.041 81 Hexachlorobenzene mg/L .05 0.046 91 Hexa chic rocyclo pentad iene mg/L .05 0,029 58 Hexachlorcethane mg/L .05 0.036 73 Indeno(1,2,3-cd)pyrene mg/L .05 0.033 67 Isophorone mg/L .05 0.045 89 N-Nitroso-di-n-propylamine mg/L .05 0.033 66 N-Nitrosodimethylamine mg/L .05 0.024 49 N-Nitrosodiphenylamine mg/L .05 0.035 71 Naphthalene mg/L .05 0.040 80 Nitrobenzene mg/L .05 0.045 89 Penta chic rophenol mg1L .1 0.063 63 Phenanthrene mg/L .05 0.042 84 Phenol mg/L .05 0.023 46 Pyrene mg/L .05 0.043 87 2,4,6-Tribromophenol (S) % 110 2-Fluorobiphenyl (S) % 87 2-Fluorophenol(S) % 54 Nitrobenzene-d5 (S) % 82 Pace Analytical Services, tnc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 % Rec Limits Qualiflers 53-127 22-147 25-158 1-132 47-145 33-145 25-150 25-150 1-166 25-150 33-143 17-163 24-159 1-219 11-162 33-184 12-158 36-166 8-158 . I -1 J2 17-168 1-118 4-146 1-227 1-114 1-112 26-137 59-121 24-116 1-152 25-150 40-113 1-171 21-196 1-230 25-150 25-150 21-133 35-180 14-176 54-120 5-112 52-115 10-137 15-120 10-120 10-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/23/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. Page 47 of 51 aOAnalytical www.paeelaSs.tom. I QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92201481 LABORATORY CONTROL SAMPLE: 1202027 Spike Parameter Units Conc. Phenol-d6 (S) % Terphenyl-d14 (S) % MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1202028 MS Parameter 1,2,4-Trichlorobenzene 1,2-Dichlorobenzene 1,2-Diphenylhydra7ine 1,3-Dichlorobenzene 1,4-Dichlorobenzene 2,4,6-Trichiorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,6-17initrotril_uene : 2-Chloronaphthalenc 2-Chlorophenol 2-Nitrophenol 3,3'-Dichlorobenzidine 4,6-Dinitro-2-methylphenol 4-Bromophenylphenyl ether 4-Chloro-3-methylphenol 4-Chlorophenylphenyl ether 4-Nitrophenol Acenaphthene Acenaphthylene Acetophenone Aniline Anthracene Benzidine Benzo(a)anthracene Benzo(a)�yrene Benzo(b)iluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene bis(2-Chloroethoxy)methane bis(2-Chloroethyl) ether bis(2-Chloroisopro pyl) ether bis(2- Ethyl hexyl)phthalate Butylbenzylphthalate Chrysene Di-n-butylphthalate 92201352001 Spike Units Result Conc. Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336 )623-8921 LCS LCS % Rec Result % Rec Limits Qualifiers 36 10-120 99 11-131 MSD Spike Conc. mglL NO .1 .1 mg/L ND _1 .1 mg/L NO .1 .1 mg/L ND .1 .1 mg/L NO .1 .1 mg/L ND .1 .1 mg/L ND .1 .1 mg/L ND .1 .1 mglL ND .5 .5 mg/L ND .1 .1 mq/L. ND 1 .1. mg/L ND .1 .1 mg/L NO .1 .1 mg/L ND .1 .1 mg/L ND .2 .2 mg/L ND .2 .2 mg/L ND .1 .1 mg/L ND 2 .2 mg/L ND .1 .1 mg/L ND .5 .5 mg/L NO .1 .1 mg/L NO .1 .1 mg/L NO .2 .2 mg/L NO .1 .1 mg/L NO .1 .1 mg1L NO .2 .2 mg/L NO .1 .1 mg/L NO .1 .1 mg1L NO .1 .1 mg/L ND .1 .1 mg/L ND .1 .1 rng/L ND .1 .1 mg/L ND .1 .1 mg/L ND .1 .1 mg/L ND .1 .1 mg/L NO .1 .1 mg/L NO .1 .1 mg/L NO .1 .1 1202029 MS Result 0.045 0.045 0.045 0.044 0.047 0.045 0.045 0.040 0.31 0.079 0.068 0.046 0.045 0.047 0.077 0.14 0.058 0.10 0.053 0.17 0.044 0.046 0.045 .0081 J 0.066 ND 0.064 0.067 0.063 0.065 0.064 0.040 0.042 0.045 0.065 0.066 0.066 0.068 MSD MS Result % Rec 0.045 45 0,045 45 0.044 45 0.044 44 0.046 47 0.045 45 0,046 45 0,042 40 0.39 63 0.095 79 0.076 63 0.044 46 0,044 45 0.048 47 0,095 39 0.16 69 0.060 58 0.11 51 0.057 53 0.25 35 0,046 44 0,046 46 0.044 23 .0089J 8 0.070 66 ND 0 0.073 64 0.075 67 0.076 63 0.077 65 0.073 64 0,040 40 0.041 42 0.042 45 0.074 65 0.078 66 0.075 66 0.077 68 MSD % Rec % Rec Limits 45 44-142 45 32-129 44 25-150 44 1-172 46 20-124 45 37-144 46 1-191 42 32-119 79 1-181 95 39-139 76 50-158 44 60-118 44 23-134 48 29-182 48 1-262 82 1-181 60 53-127 56 22-147 57 25-158 50 1-132 46 47-145 46 33-145 22 25-150 9 25-150 70 1-166 0 25-150 73 33-143 75 17-163 76 24-159 77 1-219 73 11-162 40 33-184 41 12-158 42 36-166 74 8-158 78 1-152 75 17-168 77 1-118 006 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. 0 1 2 0 1 1 2 4 22 18 12 3 M1 1 2 21 17 4 8 6 37 R1 3 M1 0 3 M1 M1 7 M1 13 12 18 16 13 1 3 6 -14 17 13 13 Qual REPORT OF LABORATORY ANALYSIS This report shalt riot be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. Page 48 of 51 aCeAnaIXical r w w.pacMabs.com- I QUALITY CONTROL DATA Project: Storm Water Testing Pace Project No.: 92201481 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1202028 MS MSD 92201352001 Spike Spike Parameter Units Result Conc. Conc. Di-n-octylphthalate mg/L ND .1 Dibenz(a,h)anthracene mg/L NO .1 Diethylphthalate mg/L ND A D imethyl phtha late mg/L ND .1 Fluoranthene mg/L NO .1 %orene mg/L ND .1 Hexachloro-1,3-butadiene mg1L NO .1 Hexachlorobenzene mg/L NO .1 Hexachlorocyclopentadiene mg/L ND .1 Hexachloroethane mg1L ND .1 indeno(1,2,3-cd)pyrene mg/L NO .1 Isophorone mg/L ND .1 N-Nitroso-di-n-propylamine mg/L ND .1 N-Nitrosodimethylamine mg/L ND .1 N-Nitrosodiphenylamine mg1L NO .1 Naphthalene mg1L ND .1 Nitrobenzene mg/L NO .1 Pentachloro phenol mg/L NO .2 P're; ant`rere ... mg/L NO Phenol mg/L ND 1 Pyrene mg/L ND 1 2,4,6-Tribromophenol (S) % 2-Fluorobiphenyl (S) % 2-Fluorophenol(S) % Nitrobenzene-d5 (S) Phenol-d6 (S) % Terphenyl-d14 (5) % 1202029 MS Result .1 0.067 .1 0.068 1 0.064 1 0.059 .1 0.069 .1 0.056 1 0.045 1 0.066 1 0.031 1 0.043 1 0.051 1 0.046 .1 0.036 1 0.033 1 0.051 1 0.045 .1 0.050 .2 0.11 O.M4.. 1 0.027 1 0.066 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NO 27288 (336)623-8921 MSD MS MSD % Rec Result % Rec % Rec Limits RPD Qual 0.077 67 77 4-146 14 0.078 68 78 1-227 13 0.074 64 74 1-114 14 0.065 59 65 1-112 9 0.080 69 80 26-137 14 0.060 56 60 59-121 8 M1 0,045 45 45 24-116 1 0.069 66 69 1-152 5 0.030 31 30 25-150 5 0.042 43 42 40-113 2 0.059 51 59 1-171 16 0.045 46 45 21-196 0 0.035 36 35 1-230 1 0.033 33 33 25-150 2 0.054 51 54 25-150 5 0.045 45 45 21-133 1 0.049 50 49 35-180 2 0.13 55 66 14-176 17 07n. 64' ' 70 " 54-120-.. 8 0.032 27 32 5-112 17 0.075 66 75 52-115 13 77 89 10-137 44 42 15-120 33 35 10-120 44 43 10-120 24 28 10-120 71 81 11-131 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in `,un, Date: 05/23/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. Page 49 of 51 ace .Analytical w+m.pacrfabs.com: QUALIFIERS Project: Storm Water Testing Pace Project No.: 92201481 DEFINITIONS Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PRL - Pace Reporting Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for ' Each anaiyte iS a -combo'; ed Acid preservation may not be appropriate for 2-C' Ioroethylvinyl eth§r, Styrene, and Viny! chloride. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte PAST-E Pace Analytical Services - Eden ANALYTE QUALIFIERS LO Analyte recovery in the laboratory control sample (LCS) was outside QC limits. L2 Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated samples may be biased low. L3 Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in associated samples. Results unaffected by high Was, M0 Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sampie (LCS) recovery. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. Page 50 of 51 aceAnalXical ..Pace1a65.C= QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Storm Water Testing Pace Project No.: 92201481 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336 )623-892 1 Analytical Lab ID Sample 1D QC Batch Method QC Batch Analytical Method Batch 92201481001 SDO 7 SM 2540D EDEN114591 92201481002 SDO 8 SM 2540D EDEN/14591 92201481003 SDO 9 SM 2540D EDEN114591 92201481004 SDO 6 SM 2540D EDEN/14591 92201481005 SDO 11 SM 2540D EDEN/14591 92201481006 SDO 12 SM 2540D EOEN/14591 92201481007 SDO 13 SM 2540D EDEN/14591 92201481001 SDO 7 EPA 1664E GCSV117656 92201481002 SDO 8 EPA 1664B GCSV117656 92201481003 SDO 9 EPA 1664B GCSV/17656 92201481004 SDO 6 EPA 1664B GCSV117656 92201481005 SDO 11 EPA 1664B GCSV117656 92201481006 SDO 12 EPA 16648 GCSV/17656 92201481007 SDO 13 EPA 16646 GCSV/17656 92201481001 SDO 7 EPA 3510 0EXT/27835 EPA 608 GCSV/17718 92201481002 SDO 8 EPA 3510 OEXT/27835 EPA 608 GCSV/17718 92201481003 SDO 9 EPA 3510 OEXT/27835 EPA 608 GCSV/17718 92201481004 SDO 6 EPA 3510 OEX7/27835 EPA 608 GCSV117718 92201481005 SDO 11 EPA 3510 OEXT/27835 EPA 608 GCSV/17718 922u14a±OG+i' SDG _., .._. ...... c " ""^ SFr. _J �v - _....0 1=XT/27835 EPi:,603 ..• ., . ti 92201481007 - SDO 13 EPA 3510 0EXT127835 EPA 508 GCSW17718 92201481001 SDO 7 EPA 200.7 MPRP/15990 EPA 200.7 ICP/14463 92201481002 SDO 8 EPA 200.7 MPRP/15990 EPA 200.7 ICP114463 92201481003 SDO 9 EPA 200.7 MPRP/15990 EPA 200.7 ICP114463 92201481004 SDO 6 EPA 200.7 MPRP115990 EPA 200.7 1CP114463 92201481005 SDO 11 EPA 200.7 MPRP/15990 EPA 200.7 ICP114463 92201481006 SDO 12 EPA 2003 MPRP/15990 EPA 200.7 ICP114463 92201481007 SDO 13 EPA 200.7 MPRP/15990 EPA 200.7 ICP/14463 92201481001 S00 7 EPA 625 OEXT/27764 EPA 625 MSSV/9138 92201481002 SDO 8 EPA 625 OEXT/27764 EPA 625 MSSV/9138 92201481003 SDO 9 EPA 625 OEXT/27764 EPA 625 MSSV19138 92201481004 SDO 6 EPA 625 OEXT/27764 EPA 625 MSSV/9138 92201481005 SDO 11 EPA 625 OEXT/27764 EPA 625 MSSW9138 92201481006 SDO 12 EPA 625 OEXT/27764 EPA 625 MSSV/9138 92201481007 SDO 13 EPA 625 OEXT/27764 EPA 625 MSSV/9138 92201481001 SDO 7 EPA 624 MSV/26871 92201481002 SDO 8 EPA 624 MSW26871 92201481003 SDO 9 EPA 624 MSW26371 92201481004 SDO 6 EPA 624 MSV/26871 92201481005 SDO 11 EPA 624 MSV/26871 92201481006 SDO 12 EPA 624 MSV/26871 92201481007 S00 13 EPA 624 MSV/26871 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2014 01:18 PM without the written consent of Pace Analytical Services, Inc.. 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(A-Z,"1 ,-j Alr AR- Sampla iDs MUST BE UNIQUE Tissue TS p p w Q- 4 Z F m 1^-, •tn o U V1�I r, 1 ' . .Other OT. 0 x W, r- d, z o Z V o ru 5.Wo i/ w , p CL�� I— DATE TiME GATE TIME 0 � � = T = Z z M C) � CC Paco Project Nod Lab I,D. 1 Styy �p• 11 /Q tl - %• iR G 0 -4 oil � -L I 6 5���T 5 4 I 10I f s — I TiMti ADDITIONAL COMMENTS RCLINQUISRED BY r AFFILIATION DATE AGCEPTEO BY f AFFILIATION DATE TIME SAMPLE CONDITIONS In SAMPLER NAME AND SIGNATURE ORIGINAL v ° z `m a � PRINT Name of SAMPLER:DATE � v? 8$z — z t- U U � SIGNATURE of SAMPLER: �( r IrytM ODtIYYya /Lf cr rn N 'Important Note: By signing this fain yeu are accepling Pace's NET 30 day payman( (arms and agreaing to 1910 charges of 1.5% per month for anyRlN�dices not paid within 30 days, r. All